ML20083D328

Responds to Request for Items 1,2 & 3 of 910718 Closeout Meeting

ML20083D328
Person / Time
Site:	West Valley Demonstration Project
Issue date:	09/20/1991
From:	Rowland T ENERGY, DEPT. OF
To:	Gary Comfort NRC
References
REF-PROJ-M-32 NUDOCS 9109300180
Download: ML20083D328 (45)

Text

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(

Department of Energy N!/ i$/L 4

1 1

Idaho Operauons Office

'k h,[/ I 7

West Valley Project Office f

P O. Box 191 West Valley, NY 14171 September 20, 1991 Mr.

G.

C.

Comfort U.S.

Nuclear Regulatory Commission Headquarters Washington, DC 20555

SUBJECT:

HRC Request per July 18, 1991, Closcout Meeting REFERENCr*

Letter WD:91:0892 (0894:91:08),

M.

N.

Haas to T.

J.

Rowland, "NRC Requests Per July 18, 1991 Closcout Meeting." dated August 21, 1991

Dear Mr. Comfort:

Per your request during the July 18, 1991 closecut meeting, enclosed are items 1, 2,

and 3 as identified in the above referenced letter.

The enclosures are identified as the following items:

A (Item 1) - Letter CBL:010:89 - 0902:89:01, W.

W.

Bixby to R. A. Thomas, Status of Facilities Relative to DOE Order 6430.1A, dated July 17, 1989 B (1 tem 2) - Memorandum FB:91:0060, J.

J.

Prowse to D.

J.

Fauth,

" Criticality Control of an Ion Exchange Column Loaded with Ti-Coated Zeolite," dated March 14, 1991 C (Item 3) - Memorandum EK:89:0232, R.

L.

Crocker to Distribution,

" Vitrification Mass Balance Revision Number 7," dated October 10, 1989 If you have any questions, please contact me or Alan Yeazel of my staff.

Sincerely, V WW T.

J.

Rowland, Director West Valley Project Office Enclosures cc:

J.

L.

Lyle, DOE-ID AY:059:91 - 0894:91:08 AY/sl 9109300180 910920 Jij) hl PDR PROJ M-32 PDR y

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. Department of Energy Ae dent owinas yb

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Icano Ccerations Office tears

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p West Valley Fre ect Cffice Izd P.O. Box 191 "P

West Valley. NY 14171 M g.g.

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cmu mzn kly 17, 1989

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exems=

oct m.

..t ram Mr. R. A. Themas, President m' *

• West Valley Nuclear Services Co., Inc.

gug,_

P. O. cox 191 mamo West Valley, New York 14171 Syc esus.. :.,

ATTENTION:

D. X. Ploetz, Plant Engineering Manager Ef 5 P W

SUBJECT:

DOE Order 6430.1A r 7z=.:.

tr=.

a.s.

REFERENCE:

Letter, D. K. Ploet: to W. W. Bixby, WD:89:0447, same subject, nave dated July 12, 1989

""2""

gWL

Dear Sir:

"ailm FAAUM.M Based on the conference telecon betweer. D. K. Ploetz, WVNS; W. L. Williams,

_,00E ID;J. A..leazeLancLLl Laex WVPO the.WestJa,Usy-Jrojec.t,Of fice "

~

u=n (WVPO) concurs with the conclusion that DOE Order 6430.1A does not apply to est a. c.:.

existing facilities, but rather applies to new facilities, or modifications to E " "

existing fa;ilities, that are in design or planned to be designeo.

gj:

rnru.:ra. :

Please provide the WVPO, via the CCS process, an estimate including scope, cost and schedule for implementing COE Order 6430.1A based on the above sacz. n.a.

interpretation.

M s:x.wz:. i..

sauxm. :..

I?. arm K3 Sincerely, VALLitil R ;,.,

g am mc.z1 : :.

a).v F=" v (~

W. W. Bixby, Director /

West Valley Project Office s

vam,

um-cc:

J. E. Solecki, DOE-ID (w/ref.)

W. L. Williams, DOE ID (w/ref.)

~

CSL:010:89 - 0902:89:01 CSL:am 4

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Sa: sty 4 4.nyt ronmentat Assessment ATTACllMENT S Ext. 4270, MS-D trem FB:91:0060 March 14, 1991 Criticality Control of an Ion Exchange Column Loaded with Ti-coaced Zeolite D. J. Fauth, MS-41-A cc:

D. C. Burns, MS-54 D. E. Carl, MS-!

J. C. Cwynar, MS-W E. R. Faillace, MS-D D. J. Ha rva rd, MS-K R. J. Johnson, MS-D P. S. Klanian, MS-1 J. L. Knabenschuh. MS-41A J. A. Mahoney, MS-M D. C. Meess, MS-Z-26 L. E. K. McCarty, MS-D C. J. Roberts, MS-D P. J. Valenti, MS-W FB Letter Log File, MS-D

Reference:

" Receipt, Analysis and Blending of Actual West Valley Vitrification Feed Components," WVSP 89/011. L. A. Brag, Pacific Northwest Laboratory, October 30, 1988 The attachment presents proposed Pu ranges and corresponding volume limits for ion exchange column:, containing Ti-coated zeolite. These limits are expressed in units and nuclistes which the A&PC Laboratory routinely t eport.

Please review the Pu isotopic ratics and physical constants used in the calculations. Additionally, please noce that the volumt limits O

have been selected such that the product of the next higher interval's maximum concentration and the volume results in 750 g (Pu-239 + Pu.

241).

Your written concurrence on the isotopic ratios and the physical constants used is requested.

P v

w J. Prowse, Project Health Physi:ist s.

Safety and Environmental Assessment West Valley Nuclear Services Co., Inc.

JJP:dms At t a ch:nent s :

DMS0674: SEA-157 Q~,& If *A$$$,*f.m &f $$.7h ' *

• OSR-IRTS-10 Pu Limits for SMWS J. J. Prowse 3/12/91 Pu Isotopic-Ratios:

Pu Total Pu Total Pu Total Fu Alpha Isotcpe Ci/t Mass %.

Ci/g C1 %

Ci %

Pu-238 1.70E+01 1.19%

2.02E-01 7.36%

70.49%

Pu-239 6.10E-02 79.60%

4.86E-02 1.77%

16.92%

Pu-240 2.30E-01 15.70%

3.61E-02 1.31%

12.58%

Pu-241 1.00E+02 2.46%

2.46E+00 89.55%

N.A.

Pu-242 3.82E-03 1.09%

4.16E-05 0.00%

0.01%

Totill 100.04%

2.75E+00 100.00%

100.00%

Conversion Factor =:

g Pu-239+241 g/ Alpha Fu Ci =

2.86 Pu-239+241 g/Pu-239+240 Ci =

9.69 Gallens/ Liter =

0.26 Limit:

750 g on any column loaded with Ti-coated ::eolite Therefore:

LCO Gallons =

2.04E+04 /(Pu-239+240 uCi/mL)

Reported Maximum Pu-239+241 Pu-239+241 Conc.

Volume Column 1 Range Pu-239+240 Processed Accumulation Limits uCi/mL gals.

grams grams Min.

< Max.

Min.

< Max.

' O.000 0.005 1,022,105 0

188 750 0.005 0.020 408,842 75 300 750 0.020 0.050 204,421 150 375 750 0.050 0.100 136,281 250 500 750 0.100 0.150 102,211

-375 563 750 0.150 0.200 81,768 450 600 750 0.200 0.250 68,140 500 625 750 0.250 0.300 58,406 536 643 750 0.300 0.350 51A5 562 656 750 0.350 (T5,427) 583 667

.= Q x

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ATTACllMENT C 4

ie Vitrification Process Develocment

^**

1 EK:89:0232 1

October 10, 19R9 5#"' ' Vitrification Mass balance Revision Number 7 T'

V.

S.

Arakali D.

E.

Carl D.

K.

Ploot::

S. M.

Barnes D.

D.

Da ruwalla J. M.

Pope B.

P.

Bauer R.

W.

Devlin K. R.

Routt R.

R.

Borisch*

A.

Dr0 bet M.

A.

Schiffhauer B.

W.

Bowan J.

P.

Englert J. R.

Stimmel P.

Burn

• P.

S. Klaniana D. J.

Stroud D.

C.

Burns C.

W.

McVay R.

F.

Vance L.

H.

Cadoff L.

L.

Petkun cc:

J. J.

Buggy, Jr.

R.

F.

Gessner*

R.

E.

Lawrenc e, Jr.*

MRC VIP 1C01, 1C, 1K

Reference:

1) Lettur EK: 89:0020, Process Development to Distribution, " Vitrification Mass Balance (Rev. 6)," dated January 27, 1989.

2) Letter W.

A. Ross to J. M.

Pope, " West Valley Mass Balance Software Develcpment", dated 9/13/89 -

BW:89:0185 - WVSP 89-132.

SYNOPSIS:

The overall = ass balance for Vitrification is reissued periodically to maintain a current reference.

Revision 7, as documented by this letter and attachments, incorporates the combining of the Tank Farm and Vitrification spreadsheets into one Lotus file and a number of other changes in process parameters and spreadsheet format as detailed in Reference 2 and sum =arized in this letter.

The vitrification mass balance is maintained using Lotus (Rev. 2) software.

All mass balance revisions are stored en High Density 3 1/2 inch f ormat diskettes.

The first five revisions are stored as Rev1FLST,..., Rev5 FLST.

Revision 6 is stored in two files labeled RVTFPR6 and WVVR6.

Revision 7 is stored in one file as CMB7.

• W/O Attachments DMS0102

• • EK:89:0232 Component concentrations are based on analytical work done in previous years and reported in earlier flowsheet versions.

one of the major upgrados to the Flowshoot was to combine all the input parameters into one range area for case of presentation.

The input parameter values used in Rev. 7 are as follows:

Year radionuclides decayed to 1990

=

Water 12 Vel in 8D-1 6 feet

=

Rust in 8D-1 and 8D-2 as Fe2O3

=

0 pounds Dirt in 8D-1 as SiO2 11,00 pounds

=

Cosium-137 activity as of 10/22/84 625 Curies

=

Strontium-90 activity as of 10/22/84 625 Curies

=

Supernatant punp heel 1 foot

=

Pre-washed sludge height 1.5 feed

=

Post wash sludge height 3.0 feet

=

Number of washes 4

=

Water volume per wash 632,000 liters

=

Wash supernatant heel 1 foot

=

8D-2 supernatant processed per cycle 36,000 liters

=

SD-Wash solution processed per cycle =

292,368 liters Water produced in 8D-1 per IX cycle 2,907 liters

=

Zeolite produced in BD-1 per 1X cycle =

1,200 liters Fraction of Cesium recovered 0.999

=

Total numbar of sand beds 1

=

8D-4 water flush 6,400

=

i Wasto oxide Loading 36.5 vt t i -

=

Melter feed concentration (oxide 450 g/l

=

basis)

Meltei-feed batch si::e in MTi!T 3250 gallons

=

DMS0102 1

.. ~.,. _..,..,,, - - - _ _ _ _ _,. _ _.. _ _.... -.... _ _. ~. _ _

.. - - i

3-EK:89:0232 Jet Dilution 10%

=

Feed water dilution factor 1.0

=

Glass per canister 1900 Kg

=

Glass production rate 45 kg/hr

=

THIS PARAMETER LISTING IS NOT ALL INCLUSIVE.

THESE ARE THE PARAMETERS MOST LIKELY TO CIANGE DURING DEVELOPMD{T AND TESTING OF THE MELTER SYSTEMS.

The primary advantage in isolating key input parameters in one table is for easy review and co-ordination with other support groups.

Tank farm and vitrification spreadsheets were co=bined in order to facilitate response to "what if" scenarios in regard to tank farm operations.

The combined spreadsheet allows for expedient evaluation of impact on vitrification processes, especially the total quantity of glass that will be produced.

Other modifications are detailed as follows:

A number of makeup chemicals have been changed and these changes have been incorporated into the spreadsheet.

Current values for feed concentration, production rate, and glass per canister are used.

A row showing the total sulfate as S03 and total sulfate as wtt oxide basis for each stream have been added to the bottom of the spreadsheet to provide more visibility to this key parameter.

t Total glass pro' duction is calculated three different ways.

As the sum of the components.

A total concentrated feed divided by the vaste loading fraction.

Ar.d as the sum of the glass for=ers and concentrated feed.

These are listed on last page of matrix and agree within 2%.

Decontamination factors have been organized into a su= mary table for easy reference.

Key glass components have been listed in table for= and provided for simple reference to current target glass composition.

This table is interactive with the spreadsheet.

The software is now capable of updating SVS parameters over a range of temperatures and determining the extent of steam condensation.

DMS0102 I

,-,.a

,-.-,-,e

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-.---,--,.,,,,.-w.,

r--.-_..,--r-,m

-~-,-n.n---n.

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2 EK 89 0232 Units were included at the top of each stream column for the chemical balance, radionuclido balance, and oxide i

I balance ranges.

The glass composition was changed from ATM-10 to reference 4, and the accompanying waste loading was also changed.

i Onceine Activities

~

Key components are being set up with individual mass balances to be used as an accuracy check and to support development of a simple flowsheet verification routino.

FY'1989 Sludge Sampling will be completed by the end of October.

This will provide the most extensive analytical-data to dats.

Characterization results should be available in early 1990 and will be used so support Rev. 8 uodate.

The benefits of integrating the mass balance spreadsheet with a data base program such as dBIV or R-Base are being evaluated.

The database format may provide for much simpler input / modification and verification of the gareadcheet.

/

R.

L.

Crocker, Principal Engineer West valley Nuclear Services Co., Inc.

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