Text

Informs That Util Enlisted Betz Industrial to Perform Chemical Cleaning of Main Condenser in Circulation Water Sys.Info Required in Accordance W/Oh EPA Procedures Encl
	ML20083A792
Person / Time
Site:	Perry
Issue date:	05/05/1995
From:	Shelton D; CENTERIOR ENERGY
To:	Kenneth Jones; OHIO, STATE OF
References
	NUDOCS 9505110138
	Download: ML20083A792 (22)
	v • d • e

.

GNTERCOR ENERGY PERRY NUCLEAR POWER PLANT Mail Address:

Donald C. SheltOn hi[44081 0

M@ M EN m oH o u 081 g

NUCLEAR (216) 259-3737 May 5, 1995 PY-CEI/0 EPA-0221L Attention:

Ms. Kathryn Lyn Jones Environmental Specialist Ohio Environmental Protection Agency, Division o.E Surface Water P.O. Box 163669 Columbus, Ohio 43216-3669 Perry Nuclear Power Plant NPDES Permit No. 3IB0016DD Cooling Vater Additive for Nonroutine Heat Exchanger Cleaning Ladies and Gentlemen:

The Perry Nuclear Power Plant has enlisted Betz Industrial to perform a chemical cleaning of the main condenser in the circulation water system.

Deposi-trol 860D vill be used as a calcium carbonate scale remover. This vill be applied as needed, typically less than once per year for a maximum of seventy-two hours.

Foam-trol 144 vill be used as necessary as an anti foaming agent. The duration of this application vill be the same as that of the Deposi-trol.

Sulfuric acid may be needed to maintain the pH of the system to ensure maximum efficiency of this treatment.

Attachments 1, 2 and 3 contain the information required in accordance with the Ohio EPA procedures. The first condenser cleaning is to be.

performed within the next several weeks.

If you have questions or require additional information, please contact Donna Tizzano at (216) 280-5514.

Very u

yours, w

DGT:sc Attachments cc: NRC Document Control Desk (Docket Number 50-440)

NRC Project Manager NRC Resident Inspector Office NRC Region III B. Hall OEPA - Northeast District Office i

overoting companies 9505110139 950505 ceveiano tiecenc muminath eDR ADOCK 05000440 g1 w m sen e

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f Attachment.1 i

PRODDCT DIPOMULTI0tt FOR THE OHIO EPA

[

. 1. 'Name of the additive to be used and. general product information.

l Additive Name - Betz DEPOSI-TROL-860D a.

MSDS attached

b. & c. Trade Secret Ingredient (E195)

Trade Secret Ingredient (122)

Additional information may be obtained through Ray i

Post, Product Manager (215)674-9200 x532 on an as needed basis.

i d.

The product, DEPOSI-TROL 860D, will be removed to remove calcium scale.

5 2.

The concentration of.the additive to be used is 1100 mg/L.

i a.

The addition frequency will be made on an "As i

needed" basis. Application frequency will typically be less than 1 time per year.

b.

The treatment application will last a maximum of j

72 hours8.333333e-4 days 0.02 hours 1.190476e-4 weeks 2.7396e-5 months .

t c.

The product is gravity fed based on theoretical calculations. Three individual additions are made with a verification test after each addition before the desired concentration is reached.

l 3.

It is estimated that a maximum of 75 ppm of Betz DEPOSI-TROL would discharge through the main plant outfall.

~

a.

The average discharge from the cooling tower =4,000 gpm that is combined with the average plant discharge of 55,000 gpm.

b.

Detoxification is not required.

4.

The average flow rate at the outfall is 84.96 NGD at the main plant outfall.

See #3 for circulating water system flow rates.

5.

Lake Erie receives the discharge from the plant through outfall-3IB00016004.

6.

Toxicity and environmental information.

a.

48-hour LC50 - Daphnia Magna 0% mortality - 1000 mg/L 96-hour Fathead Minnow I

0% Mortality - 1000 mg/L b.

Not applicable.

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PRODUCTINFORMATION FOR the Ohio EPA For:

CEI Perry Nuclear Power Plant -- Circulating Water System l

l Submitted by:

Betz PowerIndustry Diriaion l

1. Additive Name -- DEPOSI TROL 860D t

Manufacturer Infonnation:

Betz WaterManagement Group j

One Quality Way

'nevose, PA 19053 Phone: 215 355-3300 Fax: 215-953-5501

a. MSDS attached '

b. & C. Trade Secret Ings,k. i(E195) l Trade SecretIngredient(122)

Additional information may be obtained through Ray Post, Product Manager l

(215)674 9200X532 on an as necded basis.

d.'!he product. DEPOSI-TROL 860D, is a calcium carbonate scale remover.

2. The concentration of the additive to be used is 1100 mg/L.

l

a. 'Ihe addition frequency wiB be made on an "As needed" basis. Applicanon frequency wiB typicauy be less thari I thne per year.

b.'Ihe treannent application win last a maximum of 72 hours8.333333e-4 days 0.02 hours 1.190476e-4 weeks 2.7396e-5 months .

c. The product is gravity fed based on theoretical calculations."Ihree individual additions are made with a verification tem after each addition before the desired concentrationis reacled.

f i

3. It is estimated that a maximum of 75 ppm of Bet: DEPOSI TROL 860D i

would discharge through the main plant outfall.

a. The average discharge frtan the coohng tower = 4,000 gym that is combined wish the average plant disdiarge of $5,000 gym.

l

b. Detoxi6cationis not required.

I

4. The average Gow rate at the outfallis 84.96 MGD at the main plant outfall. See #3 for circulating water system flow rates.

5. Lake Erie receives the discharge trom the plant.

6. Toxicity and environmental information,

a. 48-hour LC 50 and 96-hour LC 50 for the additive is attached.

b. Not applicable.

04/07/95 FRI 08:40 FAI 412 788 2710 KINKO'S AIRPORT

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BETZ LABORATORIES.INC.

4636 soMERTCN ROAD. TREVOSE. PA. 19053 EETI MATERIAL SAFETY DATA SHEET EMERGENCY TELEPhCNE (MEALTH/ACCICENT) 800-BM -1940 PRODUCT : DEPOSI-TROL 660D (PAGE 1 CF 3)

EFFECTIVE DATE:08-23-93 PRINTED:' 08-23-93 REVISIONS TO SECTIONS: 1; EDIT: APP PRODUCT APPLICATION:CNEMICAL CLEANING COMPOUND.

SECTION 1-----------HAZARDOUS INGREDIENTS---------------------------

INFORMATION ON PHYSICAL HAZARDS,MEALTH HAZARDS, FEL*S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY TRE OSHA HAZARD COMMUNI LISTED. REFER TO SECTION 4 (PAGE 2)

AND CHRCNIC HAZARDS OF '"HIS FORMLUTICN.FCR OUR ASSES!MENI 0F THE PO TRADE SECRET INGREDIINT(E195); EYE IRRITANT; PEL:NpT DETERMINED *;TLV:NOT DETERMINED;TSRN 125434 - 5115P TRADE SECRET INGREDIENT (122):

PEL: NUISANCE DUST;TLV:NVISANCE DUST: NOTE: MANUFACTURER'S RECO EXPOSURE LIMIT:10MG/M3.'TSRN 125436 - 5214P TRADE' SECRET INGREDIENT (222): OXIDIZER: CORROSIVE; PULMONARY DAMAGE; DENTAL EROSION; PEL: 5MG/M3 (10MG/M3 -sTEL) : TLv: 5MG/M3 (2 0M /M3 -STEL) ;TSRN 5238P 125438 -

- - - - S ECTION 2 - - - - - - - - - - - TYPICAL PHYS I CAL. DATA- - - - - - - - - - - - - - - - - - --- - - -

PH: AS'IS(APPROX.)

1.4 CDOR: ACID FL. PT. (DEG. T) : ) 200 P-M(CC)

SP.GR (70F):

1.098 VAPCR PRESSURE (m:nMG) :

18.0

~

VISC cps 70F ND VAPOR DENSITY (AIR =1):.<.

1,00 4 SOLUBILITY (WATER):

200.0 EVAP RATL. (

1.00(ETHER =*)

APPEARANCE: YELLOW TO. DARK BROWN PHYSICAL STATE:LIC'JID TREEZE POINT (DEG.F):

2

---..SECTION 3-----------REACTIVITY DATA--------------------.-- 6.00 STABLE.MAY REACT WITH ORGANICS CR ALKALINE MATERIALS.DO NOT CONTAMINATE.BETZ TANK CLEAN-OUT CATEGORY

'D' THERMAL DECOMPOSITION (DESTRUCTIVE FIRES)'Y! ELDS ELEMENTAL OXIDES.

I

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-KINKO'S AIRPORT 0005-

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.FFoiiWas eca4 m fressmY cis 953 sess 1 % o4-05 12:02 ecs2 F.o4/es SETZ MATERIAL SAFETY DATA SHEET (PAGE 2 or 3)

' PRODUCT : DEPOSI TROL 860D

. ACUTE SKIN EFFECTS * " PRIMARY F.OUTE OF EXPOSURE......e ---.y

...........rI.'.'TH F.AEARD EFFECTS---- ----------------------

MAY CAUSE'SLICHT IRRITATION TO THE SKIN

' ACUTE EYE EFFECTS * "

SEVERE IRRITANT TO THE EYES

, ACUTE RESPIRATORY EFFECTS PRIMARY ROUTE OF EXPOSURE l

VAPORS, GASES, MISTS AND/OR AEROSOLS CAUSE IRRITATION TO UPPER RES}

TRACT.

CHRONIC EFFECTS OF OVEREXPOSURE"*

l i

-PRIMARY IRRITANT DERMATITIS. PROLONGED OR REPEATED MEDICAL CONDITIONS AGGRAVATED *"

l NOT KNOWN SYMPTOMS OF EXPOSURE "* -

t CAUSE ITCHING AND/OR REDNESS. INHALATION MAY CAUSE PRECAUTIONARY STATEMENT BASED ON TESTING RESULTS "*

MAY BE T0XIC IF ORALLY INGESTED OR INHALED.-

SECTION 5 -----------FIRST AID INS TRUCTIONS- ----- --- ------- ---

r-i SKIN CONTACT *'

SOAP SOLUTION OR WATER FOR 15 MINUTESaEMOVE CON EYE CONTACT ***

PHYSICIAN FOR ADDITICNAL TREAINENTIMMEDIATELY FLU INHALATION EXPOSURE"*

i REMOVE VICTIM FRION CONTAMINATED ARF.h TO FRESH AIR. APPL r

FIRST AID TREATNENT AS NECESSARY INGESTION * "

DO NOT TEED ANY"* MING BY MOUTM TO AN UNCONSCIOUS OR CO t

DO NOT INDUCE V0MITING.!MMEDIATELY CONTACT PHYSICIAN. D STOMACH USING 3-4 GLASSES MILK OR WATER t

SPILL INSTRUCTIONS * "**--sECTION 6-----------SPILL, DISPOSAL AND FIRE INSTRUCTIONS-----

l CN ABSOR8ENT MATERIAL PLACE IN WASTE D CHARACYERISTICS OF THE AECORBED MATERIAL,0R ANY CONTAMINATED SOIL SHOULD SE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS.

DI$POSAL INETRUCTIONS""?'"SH ARTA WITH WATER. WET ARIA MAY BI WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANI SEWER TREATMENT FACILITY.IN ACCORDANCE WITH ANY I,0 CAL AGREEMENT, A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER

~

PRODUCT (AS IS)-

INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS'*

APPARATUS (TULL FACE-PIECE TYPE).PRCPER F i

DRY CHEMICAL. CARBON DIOXIDE FOAM OR VATER

.I l

c4/07N 6 FRI 06:41:FAI 4 788 2710 KINKO'S AIRFORT 0'

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yy tyy5,0.s.et 12tG3 M f* WM BETI MATERIAL SATETY DATA SHEET fPAGE 3 OF 3)

PRCOUCT. DEFOSI-TROL 860D

..- -sgc73oy 7...........SPECIAL PROTECTIVE ECUIPMENT-------------

USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITE 29CFR SECTION I910.132-IJ4.USE RESPIRATORS WITMIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS.

VENTILATION PROTECTION ***

ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOPEENDED RESPIRATORY PROTECTION"'

IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY.

USE A RESPIRATOR WITN DUST / MIST FILTERS.

RECOMMENDED SKIN PROTECTION"-

RUBSER GLOVES WASH OFF AFTER EACH USE REPLACE AS NECESSARY.

RECOMMENDED EYE PROTECTION ***

SPLASM PROOF CHEMICAL GOOGLES

SECTION 8-----------STORAGE AND HANDLING PRECAUTIONS- ------- -------

STORAGE INSTRUCTIONS"?

KEEP CONTAINERS CLOSED WHEN NOT IN USE.

USE APPROVED CONTAINERS'ONLY. STORE IN COOL,WELL-VENTED AREA. CONTACT WITX METALS MAY RELEASE FLAMMABLE HYDROGEN GAS.

HANDLING INSTRUCTIONS ***

CONTAINS AN OXIDIEER. AVOID ALL CONTACT WITH REDUCING AGENTS, CILS, GREAS

........ES, ORGANI

..........CS AND ACIDS.

......s...............................................*

THIS MSDS WAs WRITTEN TO COMPLY WITH THE OSHA EAIARD COMMUNICATION S APPENDIX: REGULATORY INFORMATION THE CONTDfT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETI ON T EFFECTIVE DATE OF TRIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE ANY CHANCES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DO

...TSCA:

...AEPORTABLE QUANTITY (RQI FOR UNDILUTED PRODUCT:ALL COM 9,111 GALLONS DUE TO (122);5,466 GALLONS DUE TO (222);

... RCRA:

IDENTIFICATION NUMBER IS:D002= CORROSIVE (PH, STEEL)IP THIS PRODUCT IS D

)

... DOT NAZARD/UN#/ER GUIDE # IS : CORROSIVE TO STEEL /UN1760/#

... CALIFORNIA SAFE DRINKING WATER ACT (PROPOSITION 65) MATERIALS:NONE

... SARA SECTION 302 CHEMICALS:; TRADE SECRET (222)--INORGANIC ACID

... SARA SECTION 313 CNEMICALS::

-5.04 TRADE SECRET (222)" INORGANIC ACID.

2.0-

... SARA SECTION 312 NAEARD CLASS:IMMEDIATE(ACUTE); DELAYED (CNRONIC)

...NICHIGAN CRITICAL NATERIALS:

NCNE

.NFPA/HMIS : MEALTH - 2: FIRE - I: REACTIVITY - 0: SPECIAL - CORR: PE - B.

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I BET 2 LABORATORIES. INO.

4636 SOMERTON ROAD. TRIVCSE FA 19053 PRODUCT: DEPOSI-TROL 860D AQ'JATIC T0XICOLOGY July 20. 1954

. Daphnia magna 48 Hour Screen i

, et Mortality: 1,000 NG/L Fathead Minnow"96' Hour Screen 0% Mortalaty: 1.500 Mg/L BIODEGRADATION C0D (ac 02/gm acttve): 1.51' TOC (r.g 02 gm active

" BODS (mg 0 /gn active)):: 1.40-3.40 Note:

This product has not been tested for blodegradation are calculations based on the molecular structure of the cornponents These valuaa KAMMALIAN TCXICOLOGY Oral LD50 RAT: 72,000 MG/KG I

. Note -

ESTIMATED VALUE l

Dermal. LDSD. RABBI 1*: >2,000 MG/KG '

.Noto - ESTIMATED.VALUE 1

Ir.halation LC50 RAT: 72,000 P'PM/HR 1,

Note - ESTIMATED VALUE 90 j

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l PRW)DCT INPGtMATICN FOR 11tE GII0 EPA

1. Name of the additive to be used and general product i

information.

l t

a.

Additive.Name - Betz FOAM-TROL 144

.j b.& c. Mineral oil CAS#64742-30-9 Additional information may be obtained through Ray i

Post, Product Manager (215)674-9200 x532 on an as l

needed basis.

d. FOAM-TROL 144 is an antifoam.

I 2.

The concentration of the additive to be used is less i

than 100 mg/L.

3.

It is estimated that a maximum of 1 ppm of Betz I

. FOAM-TROL would be discharged through the main plant l

outfall should this product be used in the application.

a. The average discharge from the cooling tower =

4,000 gpm that is combined with the average plant discharge of 55,000 gpm.

b. Detoxification is not required.

4.

The average flow rate at the outfall is 84.96 MGD at the main plant outfall.

See #3 for circulating water system flow rates.

5.

Lake Erie receives the discharge from this plant through outfall 3IB00016004.

6.

Toxicity and environmental information.

i

a. 48 hour5.555556e-4 days 0.0133 hours 7.936508e-5 weeks 1.8264e-5 months LC50 - Daphnia Magna - 98.2 mg/L 96 hour0.00111 days 0.0267 hours 1.587302e-4 weeks 3.6528e-5 months static acute bioassay -

l kainbow trout - 100 mg/L

b. Not Applicable b

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l PRODUCTINFORMATION FOR the Ohio EPA t

I

. For:

CEI. Perry Nuclear Power Plant Circulating Water System j

Submitted by:

Betz PowerIndustry Division i

L Additive Name - FOAM-TROL 144 l

}

ManufacturerInformation:

Betz WaterManagement Group One Quality Way Trevose.PA 19053 i

Phone: 215-355-3300 Fax: 215-953 5501 f

a. MSDS attached

b. A c. Mineral oil CAS#64742-30-9 Additional information may bc obtained through Ray Post, Product Mana,ger (215)674 9200X532 on an as needed basis.

d.*Ihe product. IVAM TROL 144 is an antifoam.

2. The concentration of the additive to be used is less than 100 mg/L.

4

a. he addition frequency will be made on an As needed" basis. The treanaent

]

may not require any Foam. Trol and the application frequency will typically be less than 1 time per year.

b. The treatment application willlast a maximum of 72 hours8.333333e-4 days 0.02 hours 1.190476e-4 weeks 2.7396e-5 months .

c.The product will only be fed if the pH of the circulatmg water system should fall below the applicadon specification. The addition would be made via gravity feed based on the theoretical system volume of 6,000,000 gallons.

3. It is estimated that a maximum of 1 ppm of Betz FOAM. TROL 144 would be discharged through the main plant outfall should this product be used in the

[

application.

l i

s. The averag,e discharge from the cooling tower = 4,000 gpm that is combined with the average plant discharge of 55.000 gpm.

b. Detoxificationis not required.

I

4. The average flow rate at the outfall is 84.96 MGD at the main plant outrhlt. See #3 for circulating water system flow rates.

~

5. Lake Erie receives the discharge from this plant.

6.Toxidty and environmentalinformation.

a. 48 hour5.555556e-4 days 0.0133 hours 7.936508e-5 weeks 1.8264e-5 months LC 50 and 96-hour LC 50 for the additive is attached.

b. Not applicable.

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4636 SOMERTON ROAU. TREVOSE.PA. 19053 EMERGENCY TELEPHONEBETZ MATERIAL SAFETY DATA SHEET (HEALTH / ACCIDENT) 800-877-1540 PRODUCT : FOAM-TROL 144 (PAGE 1 OF 3)

EFFECTIVE DATE 02-14-31 PRINTED:

I-Mar 1971 REVISIONS TO SECTIONS:

i

EDIT: RPPENDIA PRODUCT APPLICATION : AN

gECTION 1--- --- - T!FCAN.

INFORMATION ON PHYSICAL HAEARDS, REALTH HATARDS-KAEARDOUS INC LISTED. REFER TO SECTION 4 PRODUCT INOREDIENTS AS (PAGE 2)

ICNS STANDARD I5 AND CHRONIC NAEARDS OF THIS FORMULATION.FOR QUE ASSESSMENT OF MINERAL CIL(MILDLY SOLVIl2fT-REFINED OR IfYDRO POTENTIAL SKI 3f TOMORIGEN(BASED ON CHRONIC ARI 43-30-S PELeSMG/M3;TLV 5MG/MS.

STUDIES):

~

S

)

SECTION 3-----------TYPICAL PHYSICAL DATA- ------------- -

is 50%' SOL-(AFPROX. )

5.6 ODOR: HYDROCARBON

'.PT.(DEG.F): 2200 SETA(CC)

SF.CR. (70F)OR DENSITY: 0.667 LPOR PRBS80RE(traEG): ND

'SC cps 70F: 10.7 VAPOR' DENSITY (AIR =1):ND

'AP. RATE: <1 ETHER =I

% SOLUBILITY (KATER) : 0 APPEARANCE: AMBER TSICAL STATE: LIQUID FREEZE POINT (DEG.F): ND

---RECTION 3----- -----REACTIVITY DATA------ - ----. --.

l WLE..MY REACT WITH STRONG OX2DIzzRS.DO NOT CCNTAMI FAN-OUT CATEGCRY

B' TANK UL%L DECOMPOSITION (DESTRUC* RIVE PTRES)

YIELDS ELEMENTAL OXIDES.

us/utvw) r:(1 ut to r#.A 417. JCe 2710 h!Natu ' b AIK1UH1' W.j ulu

, g w. s ecemy 2W W W g m,e..e5 10:05

- 50 P' "

m.m-n as s a w PRODUCT: FDAM TROL I44 BETE MATERIAL 8AFETY DATA ShTET (P ACUTC SXIN EFFECTS * *

PRIMARY ROUTE Or EX

----HEALTH HAZARD EFFECTS --

i SLIGHTLY IRRITATING 10 THE SEIN MAY CAUSE DER SURE ACUIE EYE EFFECTS ***

MATITIS.

ACUTE RESPIRATORY EFFECTS *** MODERATELY IRRITATING T l

MODERATE,FROIONGEC EXPOSURE MAY CAUSE READACHE M PFEUMONITIS IF ASPIRATED INTO LUFCS; AY CAUSE CEEMICAL CHRONIC EFFECTS OF OVEREXPOSURE ***

LIFETIME SKIN PAINTING STUDIES IN MICE H MEDICAL CONDITIONS AGGRAVATED ***

I

- YPE DERNATITIS:

D SRIN 19f0RS.

NOT KNOWN l

STMPTOMS OF EXPOSURE ***

J t

PROIONCED EXPOSURE MAY CAUSE DRYINC AND CRACXING i

I KIN.

I SKIN CONTACT * * *-----SECTION 5

-w---

- --FIRST AID INSTRUCTIONS -

{

EYE CONTACT *" SOAP SOLUIION OR WATER FOR 15 LARGE QUANTITY OF PHYSICIAN FOR ADDITIONAL TREATMENTDetEDIATEL t

'. MMEDIATELY CONTACT A j

INHAIATION EXPOSURE ***

}

FIRST AID TREATMENI A3 NECESSARYREMOVE VICTIM F LY APPROPRIATE INGESTION * * *

DO ND7 INDUCE VOMITINC.IMMED. CONTACT I

ONVOLSIVE VICTIM

)

SICMACH USING 3-4 G

- - -SECTION 6--------LASSES MILK OR WATER TE CONTENTS OF SPILL INSTRUCTIONS ***

--SPILL, DISPOSAL AND FIRE INSTRUCTIONS ------

i VENTILAtK AREA,0SE SPECIFIED PROTECTIVE BQU CHARACTERISTICS OF THE ABSORBED MAT l

R. THE WASTE l

SNOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULA SAND / CRIT.

AMINATED SOIL, FLUSH AREA WITH WATER. WET AREA MAY BE SLIPPERY IONS.

. SPREAD ISPOSAL IFSTRUCTIONS***

i WATER CONTAMINATED WI1W THIS FRODUCT MAY BE SEN PRODUCT (AS IS)-PERMITTED WASTE TREA*D4ENT FACIL T TO A SANITARY AGREEMENT,A

RE EKTINOUISHING INSTRUCTIONS *** INCINERATE OR BURT IN APPROVED IA DER A FPDES PERNIT

[

FIREFIGHTERS SHOULD NEAR POSITIVE PRESSURS SELF CON 1

APPARATUS (FDLL FACE-PIECE TYPE). PROPER PIRE EXTIFG AINED BREATRING DRY CHEMICAL.CAREON DIOXIDE, FOAM OR WATER

~ NG MEDIA:

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3999,ge.es 10:ts N719 P.64 DETZ MATERIAL SAFETY DATA SHEET - (PAGE 3 OF 3)

PRODUCT: FOAM-TROL 144

...--SECTION 7-----------SFZCIAL PROTECTIVE EQUT.PMENT-----------------

' USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CrR' SECTION 19I0 132-134 UsE RE5FIRAWKB WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR FESPIRATORS.

VENTIIATION PROTECTION ***

AD5QUATE VENTI 1ATION TO MAINTAIN AIR CONTAMINAlfr3 BELOW EKPost;RE LIMITS RscorOERCED RESPIRAICRY PROTECTION **

IF VENTI!ATION IS INADSQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH ORGANIC VAPOR CARTRIDGES.

RECOI9 TENDED SAIN PROTECTION ***

NEOPRENE GLOVES 3

NASN OFF AFTER EACK USE. REPLACE AS NECESSARY RECOfttRNDED EYE PROTECTION ***

$PIASH PROOF CNEMICAL GOGCLES

jiECTION 8--- --------STORAGE AND MANDLING PRECAITIIONS- ------- -----

STORAGE INSTRUCTIONS ***

REEP DRt2(S E PAIIA CLOSED WHEN NOT IN USE.

}

i STORE IN CO3L VENTIIATED LOCATION.sTORB ANAY FROM OXIDIZER 8 NANDLING INSTRUCTICgts***

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VENT CAREFUILY 3BFORE OPENING e.........eeeeeeeee ***eeeee..**ee******ee................... **..........

THIS MSDS NAS WRITTEN TO COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD oe e t.e e e e ee se.e e e e e e n e.e e e e e e e e s e e n....,.......ee.

..........n e..w e e e s e..e APPENDIX: REGULATORY INFORMATION IEE CONTENT OF THIS APPENDIR REPRESENTS INFORMATION KNONN TO RETE ON THE t

EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS. BELIEVED W BE ACCURATE.

uty CliANGIS IN REGU1ATIONS NILL RESULT IN UPDATED VERSIONS OF TMIS DOCUMENT.

...Tsch't ALL COMPONENTS OF THIS PRUDUCT ARE' LISTED ON THE TSCA INVENIORY

... REPORTABLE QUANTITY (RQ) FCR UNDILUTRD PRODUCT':

L'REAT A5 OIL SPILL

... RCRA: IF THIS PRODUCI IS D25CARDKD A5 A NASTE,THE RCRA HAZARDOUS WASTE

DENTIFICATION NUNBER IS: NOT APPLICABLE

.. DOT HA3ARD/UN#/BR GUIDEW IS: NOT APPLICABLE

.. CALIFORNIA SAFE DRINKING NATER ACT (PROPOSITION 65) MATERIALS:

'XIS PRODUCT CONTATK8 THESE CHEMICALS IQl0WN TO THE STATE OF CALIFORNIA TO

'ANCER OR REPRODUCTIVE T0XICITY: MINERAL CIL(64742-30 7)

.. SARA SECTION 302 CHINICALS: NONE

.. SARA SECTION 313 CHEMICALS: NONE

.. SARA SECTION 31I HAZARD CIASS : DEI 4Y3D (CHRONIC) i

.. MICHIGAN CRITICAL MATERIALS: NONE FPA/HNIS : MEALTH - I i FIRE - 1 ; REACTP/ITY. O ; SPECIAL - NONE ; PE - 3 4

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199s.rm.ac tzisc eras :.st SETZ LABCRATORIES, INC.

4E36 sOMERTON RCAD, TREVOSE, PA 19053 PRCDUCT:

FOAM-TROL 144 AQUATIC TOXICOLOGY Aprilh,2995 i

Daphnia magna 48 Nour Static Acute Bioassay'

LCSD, 98.2 reg /L No Effect Level 37 Rainbow 7mut 96 Hour Static Acute 31oassay LC50s 100 mg/L

[

No Effect Levels 75 r-BIODEGRADATION L

COD (mg/gm):

825 Calculated 2CC (mg/gn):

527 Calculated BOD-5 (mg/ge):

134 calculated DOD-28 (ttg/gm) :

285 calculated closed mottle Test Eahn-Wellens Test

Degradation in 29 days:

26 Calculated t Degradation in 28 days:

No Data Available MAPNdLIAN T0XICol4GY DeMal LD$0 RABBITS

>2,000 MG/KG Oral LD50 RAT: >2,000 MG/KG Note -

RSTIMATED VALUE I

\\

.~

g. _,',. _ '

J P

PRODUCT INFORMATION FOR THE_ORIO RFA

1. Name of'the additive to be used and general product information.

j Additive name - sulfuric acid l

a.-

MSDS attached H0 i

.b. & c. H SO Sulkurke+ackd vill' be used in'. conjunction with d.-

Betz DEPOSI-TROL 860D for pH control during calcium-carbonate scale removal.

e.

Not applicable.

2. The maximum. concentration of the additive to be used is 1.0 mg/L a.

The addition frequency will be made on an "as-needed" basis.

Application frequency will typically be less than 1 time per year.

b.

The treatment application vill last a maximum of 72 hours8.333333e-4 days 0.02 hours 1.190476e-4 weeks 2.7396e-5 months .

+

The product will be either pumped from drums or c.

gravity fed based on theoretical calculations.

circulating water acidity will be monitored during addition to control the total volume added.

j

3. It is estimated that a maximum of 0.2 ag/L of' sulfuric

}

't acid would discharge'through the main plant outfall; The average discharge from the cooling tower is 4

a.

4,000 gpm that is combined with the average plant dischstge of 55,000 gps.

4. The average flow rate at the main plant outfall'is 84.96 I

MGD.

See #3 for circulating water system flow rates.

l l

S. Lake Erie receives the discharge from the plant.

6. Toxicity and environmental information.

l

a. 168-hour - Daphnia Magne

.1 ag/L 64-hour * - Daphnia Magna - 88 mg/L l

48-hour mosquito fish - 42 mg?L i

48-hour - bluegill - 49 mg/L b.

Not applicable.

i

Based on a Canadian MSDS

g_

4, 04Y1,9/1995 08:29- '216-280-8033 TI RDS PAGE 03

~

o*Ro:9-1995~ 00804 A J1 K! It:WEIRTM C>410 T3 -

12162905033

p. 62 MATERIAL BAFETY DATA SHEET-PRODUCT: SULFURIC ACID

.SECTION 1'- MANUFACTURER INFORMATION MANUFACTURER / DISTRIBUTOR:

FVS CHEMICALS, INC. (OHIO) 3149 Copley ad.

Copley, Ohio 44321 telephones (216) 666-0888 (product information and emergencies)

Jax: (216) 666-5075

- - FOR TRANSPORTATION EMERGENCY ONLY, DAY OR NICHT, CALL ***

- - CMENTREC, 1-800-424-9300***

PREPARATION / REVISION DATE: 12-1-92 CONTACT: Manager of Environmental Affairs SECTION 2 -- PRODUCT IDENTITY /MAZARDOUS INGRF.DIENTS INFORMATION Product name: sulfuric Acid Chemical name/ synonyms: Sulfuric Acid, Oil of Vitrici Chemical formula: N,SO, CAs number: 7664-93-9 Product Code: N/A HAZARDOUS INOREDIENTS: Yes Carrponent CAS No.

& by we, Sulfuric Acid 7664-93-9 75-1006 Exposure limits:

OSHA FEL:

1 mg/m', 8-hr TWA ACGIN TLV:

1 mg/m*, 8-hr TNA 3 #4/m', sTEL 8

80 mg/m, IDLH OTHER: This is a toxic chemical subject to the reporting requiremente of Section 313 of Title III of the Superfund Amendments and Resuthorization Act of 1986 and 40 CFR Part 372.

NON-HAZARDOV'S INGREDIENTS: Yes Component.

QS No.

& by wt.

Water 7732-18-5 1-254 OSHA 29 CFR 1910.1200 EVALUATION: Hazardous t

i SULFURIC ACID MSDS, FACE I OF 5 l

.' 04718/19 % 08:2'3 216-080-8033 CEI N5 CA3E 04

::po.3 9-19% 33:04 FPCM JCI GMBE0TM 0H10 I?

12162933333 M3 SECTION 3 -- FHYSICAL/ CHEMICAL CHARACTERISTICS APPEARANCE AND ODOR: Clear to slightly cloudy, oily liquid; odorless to slightly pungent.

BOILING POINT:77.74 379. 5'r;934a535T:964-586*r; 984-6217; 994 = 590*F FREEZING FOINT:77.74 11. 5T;934=-21T;964-7*T;984-30'T;994 40*F VAPOR PRESSURE (REID): 93.2% = 0.0016 m Hg; 984 - 0.002 ' m:n Hg VAPOR DENSITY (AIR = 1): no infortsation SPECIFIC GRAVITY (WATER = 1): 77.74 = 1.706; 93.2% = 1.535 964 1,843; 984 - 1.844: 994 = 1.842 i

PERCENT VOLATILE NY WEICMT no infortsation EVAPORATION RATE (BUTYL ACETATE = 1): <1 pH: <1 SOLUBILITY IN WATER: Cosspletely miscibla 8ECTION 4 -- FIRE AND EKPLO5ICN MaZaRD DATA

~

TLASH POINT (CLOSED CUP METHOD): Not flamable.

May ignite,,

combustible meterials, t

TLAMMABLE LIMITS IN AIR, 4 BY VOLUME: N/A 14WER: N/A UPPER: N/A EXTINGUISHING MEDIA:

Uso dry che: rical or Co base fire r

extinguishers to fight surrounding fire. Do not use water on acid itself.

Apply from farthest possible distance.

SPECIAL TIRE TIGHTING PROCEDURES: Naar snif-contained breathing apparatus and full protective clothing.

Cool exterior of storage tanks.

UNUSUAL FIRE AND EXPI4SION MAEARDS: Violent reaction with water.

Evolution of exploeive hydTogen gas on contact with most metals.

Will react with organic material with evolution of heat and dense white fumes.

SECTION 5 -- REACTIVITY DATA STABILITY: Stable e

HAZARDOUS POLYMERIZATION: will not occur INCOMPATIBILITY (CONDITIONS Ar*D MATERIALS TO AVOID): Naterial is stable when preparly handled.

Reactive with materials sceh as netals, metal oxides, hydroxides, nitrates, amines, carbonates and other alkaline materials.

Reactions can generate a great deal of heat as does the dilution of acid with water. Concentrated acid is i

a strong oxidising agent.

i natorials on contact with generation of sulfur dioxide fumes.

Avoid open flames or sparks.

SULFURIC ACID MSDS, PAGE 2 Olr 3 4

,., ! 04749't 995 ' 08:29 216-200-8033 ZI W

N,.sg.tiry5 es: 2 FR:yt JCI N RTOt4 CH1')

T3 12162 M 33 O

L HAZARoouS DECOMPOSITION PRODUCTS:

Explosive hydrogen gas is generated by the action of. acid on most metals and nay accumulate j

in metal containers. Feieases sulfur Dioxide at extremely high i

temperatures.

SECTION 6 -- HEALTH MAZERD DATA PRIMARY ROUTES OF ENTRY: Inhalation, ingestion, direct contact HEALTH ETTECTS (ACUTE AND CHRONIC):

INHALATION: Inhaletion of concentrated vapor or mist may damage respiratory tract.

2NGESTION: Swellowing may be fatal.

D.; RECT CONTACT: Ccntact with liquid, mist, or vapor can cause immediate irritation or corrosive burns to all human tissue..

Severity of the burn is generally determined by the concentretien of the solutien and duration of' exposure.

EYE CONTACT: Contact with eyes may result in permanent vi.sua; loss unless removed quickly by thorough irrigation with water.

TOXICITY DATA (ANIMAL):

Oral LD,,,

rat: 2140 mg/kg Skin and eye irritation (rebbit): (TH5A)

Corrosive Inhalation 2 heur LC,,,

rat: 347 ppm The International Agency of Research on Cancer (IARC ) has cisesified " strong inorganic acid mists containing sulfuric acid" as e Category 1 carcinogen, a substance that is *' carcinogenic to humans".

This classification is for inorganic acid mists only and does not opply to sulfuric acid or sulfuric acid solutions.

CARCINOGENS (NTP, IARC, OR OSHA): None of the components of this

[

material is listed by IARC, NTP, OSHA, or ACCIN as a carcinogen.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:

Repeated skin contact i

with dilute solutions may cause dermatitis.

May cause dental erosion.

SECTION 7 -- FIRST AID e

INHALATION: Remove victim to fresh ear.

If not bresthing, perform artificial respiration.

Get medical attention.

INGESTION: Drink copious enounts of water or milk.

Do not induce vomiting.

Get immediate medical attention. Never give anything by mouth to an unconscious person.

DIRECT CONTACT: Wipe off excess. Flush immediately with water for at least,15 minutes while removing contaminated clothing.

t Get t

contaminated shoes.

DIRECT EYE CONTACT: Flush immediately with water for at le4st 15 ma,nutes.

Forcibly hold eyelids apart to ensure complete i

irrigation of eye / lid tissue.

Get immediate medical attention.

t SUI.FURIC ACID MSDS, PAGE 3 Cr 5 i

1

ce19/1935 08:29 216-280-8033 OE I r".-

PAGE 06 1

. pvy. 5 9% 03:35 rem K! B;PBERTN Nio f3 12162339333 E D5 l

SECTION 8 -

PRECAUT2ONS FOR S&FE STORACE.

HANDLING AND USE PROCAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store away from cources of ignition.

Do not add water to concentrated acid.

When diluting, slowly add acid to water while stirring, to avoid spatterir.g, boiling, and eruption.

Keep container closed and protect from contact with water.

Protect container from physical damage.

Do not strike containers or fittings with tools.

Wash thoroughly after handling.

1 product residue.

Emptied container will retain vapor and STEP 5 TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:

Utilize

[

full protective clothing, including boots and protective equipment.

Contain spill in order to prevent contamination of sewege system or waterway.

If possible, neutralize on a dry bests: Pump into marked containers for reclamation or dis with ruitable alka).1 such as lime or soda ash: tnen flush with water in accorcance with l

applicable regulations.

WASTE DISPOSAL METHODS: Dispose of spilled, neutralized, or waste product, contaminated soil and other materials in accordance with all local, state and federal regulations.

i t

SECTION 9 -- EXPOSURE CONTROL INFORMATIoM VENTILATICN: Provide ventilation to control exposure levels below r

airborne exposure limits.

Use local exhaust ventilation.

i Reference NFPA Standard 91 for design of exhaust systems.

l i

i RE$pIRATORY PROTECTION:

Use N105M/MSHA

approved, full face respirator with canister approved for sulfuric acid vapor end mist.

i Consult respirator manufacturer to determine appropriate equipment.

If concentrations are high or unknown, use self-contained breathing apparatus.

PROTECTIVE GLOVES: Wear impervious rubber gloves.

EYE PROTECTION: Wear splashproof chemical safety goggic Eyewash fountains racjommerWed in eli storspo and handling areas.

Do not wear contact lenses, l

i OTHER FROTECTIVE EQUIPMENT: Wear protective clothing to prevent skin contact.

Full face shield and rubber footwear should be used.

Acid-resistant hood and full body suit recommended.

i Safety shower recommended in all storage and handling aress.

WORM / HYGIENIC PRACTICE 5: Avoid breathino funes.

Use clovese WP l

i

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... w...

.... w.

w. w...... w

....w.u...,.

THEn PRECAUTIONS: None StJLFURIC ACID HSDa, rAGC 4 OF 5 1

[f[

,,8,', 04/19/1995 08:29 216-280-8033 CEI RSS PAGE 07

8FH-1T-1995 08805 FR'Jr1 Jet trWEERTON CHIO TO 12162303033 e.05

~.

SECTION 10 -- REGUI.ATORY INFORMATION DOT:

Proper shipping nomes Sulfuric acid t

Hezird Cless: 8 UN Number: UN1830 Pecking Group: II SARA TITLE III HAIARD CLASSITICATICFS:

ACUTE:

Yes CHRONIC:

Yes FIRE:

No PRESSURS:

No REACTIVITY:

Yes Su)fueic Acid is

' toxic chemical sub.1ect to the reporting l

=

requirements of Section 313 of Title 111 of the Superfund Amendments and Reauthorization Act of 1966 and 40 CTR Part 37s' OTHER RAT 2NGS:

(hazard indes key 4-severe, 3-serious,

2. moderate, 2 s11ght, 0 minimal)

HMIS: Health =3, Flammability 0, Reactivity =2 NFPA:

Health =3, Flammability =0, Reactivity =2 OTHER INFORMATION:

SULFURIC ACID:

CERCLA: RQ 1000 lbs.

SARA TPQ: 1000 lbs.

WHMIS: 14 i

i f

i SULFURIC ACID MSDS, FAGE S OF S T r A a. N

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w. r. x t. s 1

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p,y toveronment Environnement Canada Canada e...:..

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Protection protection de l

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Servico l'environnement

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ENVIRO M

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echnical g

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February 1984 i

I l

jlllIKlt*8it

I PiHKbdLt. A

11) ; 1012-040

MOD HVK 1('M 10: 20 NO.U1/ P.02

.t 79 ENVIRONMENTAL DATA 6

6.i Suggested or Regulated Limits 6.1.1 Water.

Canada. Sulphuric acid in !cself is not regulated in Canada; however, there a i

6.1.1.1 guidelines for both sulphate and pH. Nationally, 500 mg/L sulphate preferred. For !!vestock, a limit of 1,000 mg/L sulphate is acceptable (W Ontario recommends that " alkalinity should not be decreased by more tha The pH should not go below 6.5 (Water 25 percent of the natural concentration".

Management <,oals 1978).

l Others. In the tinited States, 250 mg/L sulphate is the maxim 1971); 500 mg/L is acceptable for livestock 6.1.1.2 with a 30 mg/L objective (WQCDB-2 The World Health Organization recommended a limit of 250 mg/L I

(EPA-440/9-75-009).

sulphate in 1961 (WQCDB-21971).

For high levels of protection from acidity, a pH of not less than 6.515 f

recommended; pH 3.5 affords the minimum acceptable protection. The extreme range l

pH fluctuation should not exceed 2.0 units; total alkalinity should not be than 25 percent (WQC 1972).

Ontario limits airborne sulphuric acid to 100 pg/m3 (Ontario E.P. Act 6.1.2 Air.

i l

1971).

6.2 Aquatic Toxicity U.S. Toxicity Rating. Sulphuric acid and oleum have been assigned a TLm 6.2.1 l

(4-day median lethal toxicity rating) of 10 to 100 mg/L (RTECS 1979).

6.2.2 Freshwater Toxicity.

Water I

Conc.

Time (mg/L)

(hours)

Species Result Conditions Reference Fish Kill Da_ta 6.0 - 8.0 6

Minnows harmful 20*C, distilled WQC 1963 orlethal

10:1312-646-3366 APR 17'95' 13:28 16.017 P.03

- 1;etGRSULEX l

80 i

Water Conc.

Time Result Conditions Reference 4mg/L)

(hours)

Species 110 - 120 6

Minnows harmful 20'C, hard WQC 1963 or lethal 7.36 60 Bluegill harmful distilled WQC 1963 orlethal WQC 1963 harmful 6.25 24 Trout or lethat t

Fish Toxicity Tests 42 48 Mosquito firh TLm turbid WQC1%3 49 48 Bluegill TLm tap, 20*C

" WQC 1963 Microorganisms 0.1 168 Daphnfo magna lethal static-soft Ellis 1967 88 64 Daphnfa magna lethal Lake Erie WQC 1963 Invertebrates WQC 1963 33.1 not stated Bivalve larvae harmful 6.2.3 Saltwater Toxicity.

Water Cone.

Time Result Conditions Reference (mg/L)

(hours)

Species r

Fish Toxicity Tests aerated Portmar 100 to 330 48 Flounder LC30 1970 t

invertebrate _s 18% lethal WQC1%3 100 120 Oysters 80 to 90 68 Shrimp LC 0 aerated Portman 3

1970 l

.

ML20083A792

Text

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