Text

Rev 4 to Oil,Hazardous Substances & Hazardous Wastes Spill Prevention,Control & Countermeasures Plan
	ML20079G724
Person / Time
Site:	West Valley Demonstration Project
Issue date:	09/30/1991
From:	Keller K; WEST VALLEY NUCLEAR SERVICES CO., INC.
To:	;
Shared Package
ML20079G712	List: ML20079G710; ML20079G724;
References
	REF-PROJ-M-32 WVDP-043, WVDP-043-R04, WVDP-43, WVDP-43-R4, NUDOCS 9110090261
	Download: ML20079G724 (186)
	v • d • e

{{#Wiki_filter:. l l C) West Valley Demonstration Project Doc. Number WVDP-043 Revision Number 4 Revision Date 09-30-91 Controlled Copy No. 48 OIL, HA"ARDOUS SUBSTANCES, MID HA*ARDOUS WASTES SPILL PREVENTION, CONTROL, AND COUNTERMEASURES PLAN /M O.[/M/ - PREPARED BY K. Keller Cogni:: ant Engineer APPROVED BY C b G. G. Baker s CogniSQjy System Design Manager l / j/ / ../ u -[4 APPROVED BY 't / J. L. Knabenschuh [6gni:: ant'Systeri Staf f Manager West Valley Nuclear Services Co., Inc. P.O. Box 191 O West Valley, NY 14171-0191 h-1k ke'v 9110000261 010930 PDR PROJ M-32 PDR

.~ U WEST VALLEY DEMONSTRATION PROJECT OIL, HAZARDOUS SUBSTANCES, AND HAZARDOUS WASTES SPILL PREVENTION, CONTROL, AND COUNTERMEASURES PLAN WVDP-043 Rev. 4 i PREPARED BY: 1 ENVIRONMENTAL COMPLIANCE O"' WEST VALLEY DEMONS"' RATION PROJECT REISSUED NOVEMBER 1989 REISSUED SEPTEMBER 1991 EXPIRES SEPTEMBER 1994 NOTE: This plan is-an adjunct to WVDP-022, the Emergency Plan. The Oil, Hazardous Substance, and Hazardous Waste Spill Prevention, Control, and Countermeasures Plan must be reviewed and updated within three years of date of. issue or revision. AU LEWO204.WP6 L

WVDP-043 p/ Rev. 4 .y. CERTIFICATION - OF THE WVDP SPILL PREVENTION, _ CONTROL, AND COUNTER-MEASURES PLAN FOR OIL, HAZARDOUS SUBSTANCES, AND HAZARDCUS WASTES l I hereby certify that I have reviewed the WVDP Spill Prevention, Control, and Countermeasures (SPCC) Plan as revised June 30, 1991;-that I am familiar with the requirements specified in 40 CFR Parts 110, 112, 116, 117, 125, 302, 355, 761, and 6 NYCRR l 597,2; that I am familiar with the facilities described; and that the SPCC Plan has been prepared in accordance with good engineering practices. I cm [ ~ ~ P.E. 03520S 4 kFESS\\oW l l [ l l I l l. l O LEWO204.WP6 l

.. _. _.. _. -.~- gy WVDP-043 %) - Rev. 4 RECORD OF REVISION PROCEDURE If there'are changes to the procedure, the revision number increases by one. These changes are indicated by placing a heavy vertical ~ black line located in_the right-hand margin adjacent to the sentence or paragraph which was revised. Examole: The vertical line in the margin indicates a :hange. l Revision On Rev. No. Description of Changes Page(s) Dated 0-Original Issue All . (~ 1 Complete Issue All 11-88 5 2 Complete Issue All 01-90 3 Complete Issue All 07-91 4 Complete Issue All 09-91 l l -- l WV-1807A, Rev. O i -LEWO204.WP6 0

4 [. , -t WVDP-043 Rev. 4 RECORD OF REVISION (CONTINUATION SHEET) Revi:31on On Rev. No. Description of Changes Page(s) . Dated j 1 i 1 g l 1 j i i i .\\ i j 1 W-18 07A', Rev. O 11 ) IEWO204.WP6 c. ~_...

~-- 4 '^ x WVDP-043

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Rev. 4 CALL LIST for NON-RADIOACTIVE HAZARDOUS MATERIALS RELEASES / SPILLS (Reportable Quantities) ILLE NOTIFICATION REOylAEMENT PHONE U.S. DOE 24 hour Notification 202-586-8100 or HEADQUARTERS FTS-7-896-8100 Emergency Operations Ctr .o *4

a.

DOE-ID WARNING 24 hour 208-526-1515 or COMMUNICATIONS FTS-7-583-1515 or CENTER (WCC) 173-37 (speed dial) /b /3 y EPA National 24 h tification 800-424-8802 or Response Ctr 202-267-2675 or FTS-7-267-2675 EPA REGION II 24 hour Notification 908-548-8730 Emergency Response Team 'NEW YORK STATE 24 hour Notification 518-457-2200 or l Emergency 518-457-6811 or Management Office 173-41 (speed dial) l CATTARAUGUS COUNTY 24 hour Notification 716-938-9191 or Emergency Management 173-50 (speed dial) Warning Point l l f ERIE COUNTY 24 hour Notification 716-858-6578 l 'V] Department of Emergency Services LEWO204.WP6 iil n

^ (\\ >, \\ WVDP-043 Rev. 4 WESTINGHOUSE CORP. 24 hour Notification 412-642-3444 ENVIRONMENTAL AFFAIRS RESPONSE GROUP WESTINGHOUSE CORP. 24 hour ific 412-374-4019 or ENERGY CENTER

j 412-374-4020 SECURITY STATION O

f l l LEWO204.WP6 iv ~ l-

(~ WVDP-043 U} Rev. 4 CALL LIST for RADIOACTIVE RELEASES / SPILLS (Reportable Quantities) TITLE NOTIFICATION REOUIREMENT PflONE U.S. DOE 24 hour tiotification 202-586-8500 or HEADQUARTERS FTS-7-896-8500 Emergency Operations Center ) k w/ DOE-ID WARNING 24 hour ca 208-526-1515 or COMMUNICATIONS FTS-7-583-1515 or CENTER (WCC) N/ gv EPA National 24 hou ification 800-424-8802 or Response Center 202-267-2675 or FTS-7-26~>-2675 EPA REGION II hour Notification 908-548-8730 Energency Response Team NUCLEAR 24 hour Notification 202-951-0550 REGULATORY COMMISSION l Emergency Operations Center (- STATE 24 hour Notification 518-457-2200 or Emergency 518-457-6811 Management Office lh (l l LEWO204.WP6 v

l WVDP-043 - O Rev. 4 CATTARAUGUS COUNTY 24 hour Notification 716-938-9191 Emergency Management Warning Point A ERIE COUNTY 24 ho to ation 716-858-6578 Department of Emergency Services A WESTINGHOUSE CORP 4 h r Notification 412-642-3444 ENV. AFFAIRS RESPONSE GROUP h WESTINGilOUSE CO 24 hour Notification 412-374-4019 or ENERGY CENTER 412-374-4020 SECURITY STAT 9' O T2WO204.WP6 vi

(~T WVDP-043 (,) Rev. 4 WVDP EMERGENCY ORGANIZATION EMERGENCY TELEPHONE LISTING (Strict Order of Call) TITLE NAME PHONE EMERGENCY OPERATIONS J.J. BUGGY 648-4710 or CENTER DIPECTOR 861-1500 or 14 (speed dial) First Alternate R. A. Humphrey 592-9498 or 13 (speed dial) Second Alternate R. F. Gessner 663-1767 or 34 (speed dial) / Third Alternate J. ab uh 662-2598 or 06 (speed dial) gh. ASSISTANT EMERGENCY NCE 662-6618 or DIRF,0 TOR V 35 (cpeed dial) First Alternate R. Gessner 662-1767 or () Ik) 34 (speed dial) Second Alternate L. Knabenschuh 662-2598 or 06 (speed dial) DOE ON-SITE T. J. ROWLAND-592-4945 or REPRESENTATIVE 866-5862 First Alternate P. A. VanLoan 662-2620 or 02 (speed dial) Second Alternate J. A. Yeazel 648-2511 ASSISTANT DOE ON-SITE R. B. PROVENCHER 627-7099 or REPRESENTATIVE 861-5860 First Alternate J. A. Yeazel 648-2511 DOE-WCC COMMUNICATOR S. KETOLA 353-4743 First Alternate P. S. VanLoan 662-2620 Second Alternate R. B. Provencher 627-7099 or 861-5860 Ov LEWO204.WP6 vii

r'T WVDP-043 U. Rev. 4 WVDP EMERGENCY ORGANIZATION EMERGENCY TELEPHONE LISTING (Strict Order of Call)- IIILE NAME PHONE NYSERDA REPRESENTATIVE T. L. Sonntag 649-2005 First Alternate P. J. Bembia 649-2019 LIAISON MANAGER L. L. HOWARD 662-1643 or 07 (speed dial) First Alternate M. J. g'in 688-4469 10 (speed dial) RADIOLOGICAL AND J. KN SCHUH 662-2598 or ENVIRONMENTAL ACCIDENT 06 (speed dial) ASSESSMENT MANAGER or 886-5853 First Alternate Harward 992-4950 or 40 (speed dial) b V Second Alternate J. Roberts 662-2537 or 77 (speed dial) OPERATIONAL ACCIDEN R. P. GESSNER 662-1767 or ' ASSESSMENT MANAGER 34 (speed dial) First Alternate P. J. Valenti 649-3058 or' 80 (speed dial) Second Alternate D. J. Sawyer 257-3105 or 23 (dpeed dial) ENVIRONMENTAL CONTROL G. G. BAKER 649-8254 or OFFICER 866-5855 L First Alternate M. K. Lincoln 592-7429 SECURITY MANAGER W. J. CZYZ 941-5074 or l 07 (speed dial) L or 861-3894' First Alternate R. D. Love 676-2611 I (Off-Duty Lieutenant) D. J. Gilman 938-9825 i D. B. Hammond 938-9164 lP N '. A. Wright 699-4538 l( R. L. Frentz 938-6732 LEWO204.WP6 viii i

O WVDP-043 Rev. 4 WVDP EMERGENCY ORGANIZATION EMERGENCY TELEPHONE LISTING (Strict Ordor of Call) TITLE EhME PHONE COMMUNITY RELATIONS M. W. DAMEROW 537-9773 or MANAGER 05 (speed dial) First Alternate J. D. Chamberlain 257-9205 SAFETY & ENVIRONMENTAL C. J. ROBERT 662-2537 or ASSESSMENT MANAGER 77 (speed dial) First Alternate P 9. N 662-5464 or 87 (speed dial) EMERGENCY PLANNING AND NZALEZ 823-7976 or PREPAREDNESS COORDIN 33 (speed dial) First Alternate M. Vann 648-3181 O COMMUNICATIONS J. F. MILLER 353-9941 or COORDINATOR 67 (speed dial) DRAFTING BUPERVI J. R. HORTON 592-7957 First Alternate C. Gerwitz 942-6578 Second Alternate J. Lexer 257-9437 DATA RECORDER M. N. LAKER 649-5636 or (Operations) 09 (speed dial) First Alternate D. F. Pozzimenti 372-5829 19 (speed dial) DATA RECORDER T. M. CONLIN 941-6289 (Radiological and Environmental) First Alternate W. V. Schaper 492-1906 O LEWO204.WP6 ix

T WVDP-043 Rev. 4 WVDP EMERGENCY ORGANIZATION EMERGENCY TELEPHONE LISTING (Strict Order of call) TITLE HMig PHONE SECRETARIES W. L. ALLEN 532-4689 M. C. Wilcox 592-2484 l First Alternate L. A. Przystal 592-2998 ) FAX OPERATOR E. C. W1 r 592-5052 First Alternate 4 M. iffhauer 648-2598 Second Alternate W. lleman 532-9148 TECHNICAL SUPPORT CdlFTER <v r ' V) [ TECHNICAL SUPPOR D. K. PLOETZ 592-7735 CENTER MANAGER V First Alternate T. Hughes 897-2195 or 74 (speed dial) Second Alte J. C. Cwynar 662-7658 or 51 (speed dial) ON-SCENE COMMAND GROUP DOE ON-SCENE E. A. MATTHEWS 699-4083 COORDINATOR First Alternate C. Leek 699-2645 RADIOLOGICAL CONTROL D. J. HARWARD 992-4950 or t TEAM LEADER 40 (speed dial) or 866-5854 First Alternate P. A. Szalinski 662-6948 or 91 (speed dial) A Second Alternate G. H. Metzler 945-2737 or ) 16 (speed dial) i LEWO204.WP6 x l l c

p WVDP-043 i f Rev. 4 WVDP EMERGENCY ORGANIZATION EMERGENCY TELEPHONE LISTING (STRICT ORDER OF CALL) TITLE NAME PHONE OPERATIONAL SUPPORT R. D. KEEL 941-5300 or MANAGER 11 (speed dial) First Alternate D. K. Ploetz 592-7735 or 26 (speed dial) Second Alternate D. H. Garland 649-2749 IRTS OPERATIONS MANAGER P. J. VALE 649-305S or 80 (speed dial) First Alternate J ar 662-7658 or 92 (speed dial) Second Alternate V H. Sbaffner 942-3904 ON WASTE MANAGEMENT H. GARLAND 649-2749 OPERATIONS MANAGE (Including Hazardous Waste Management) First Alternate P. M. Vlad 662-3054 Second Alter D. G. Feldman 257-3060 MAIN PLANT D. J. SAWYER 257-3105 or OPERATIONS MANAGER 23 (speed dial) First Alternate S. A. MacVean 652-8914 Second Alternate W. P. Freaney 945-5689 or 26 (speed dial) VITRIFICATION TEST P. S. KLANIAN 662-9515 or GROUP MANAGER 59 (speed dial) First Alternate J. Paul 941-5653 or 72 (speed dial) ASSEMBLY AREA J. R. GREENQUIST 649-5672 COORDINATOR O LEWO204.WP6 xi

i ,y WVDP-043 - (j _ Rev. 4 AUTODIALER LIST R. A. Humphrey 592-9498 R. E. Lawrence, Jr. 662-6618 R. F. Gessner 662-1767 J. L. Knabenschuh 6 598 G. G. Baker 254 T. J. Rowland ~4945 E. A. Matthews 9-4083 S. Ketola 353-4743 J. A. Yeazel 648-2511 R. B. Prov r 627-7099 L. L. Ho 662-1643 D. J. Ha 992-4950 C. J. Robert 662-2537 R. B. Keel 941-5300 W. J. Czyz 941-5074 M. W. Da w 537-9773 D. K. z 592-7735 R. A. zalez 823-7976 J. ller 353-9941 J. R Horton 592-7957 (~ M. N. Baker 649-5636 (j] T. M. Conlin 941-6289 W. L. Allen 532-4689 ) M. C. Wilcox 592-2484 4 E. C. Wilber 592-5052 (O _/ j LEWO204.WP6 xii

WVDP-043 Q Rev. 4 \\J OIL, ILAZ ARDOUS SUBSTANCES, AND HAZARDOUS WASTES SPILL PREVENTION, CONTROL, AND COUNTERMEASURES PLAN TABLE OF CONTENTS 1.0 StiMMARY 1

2.6 BACKGROUND

INFORMATION 3 2.1 Site Topography and Drainage 5 2.2 Hydrosphere 7 2.4 Floods 9 2.5 Probable Maximum Flood 9 2.6 Ice Flooding 10 2.7 Flooding Protection Requirements 10 2.8 Sanitary Sewer System. 10 2.9 Storm Sewer System 10 2.10 Spill History 10 3.0 Storage Facility Construction, Instrumentation, and Spill Containment 12 -w 3.1 Fuel Oil Tank 31D-2 12 g q,/ 3.1.1 Construction. 12 3.1.2 Instrumentation 12 3.1.3 Operation 12 3.1.4 Spill Containment 33 3.2 Tank 14D-1 33 3.2.1 Construction;. 33 3.2.2 Instrumentation 33 3.2.3 Operation 34 3.2.4 Spill Containment 34 3.3 Caustic Tank 14D-2 and Caustic Day Tank 14D-2A 34 3.3.1 Construction. 34 3.3.2 Instrumentation 34-3.3.3 operation 34 3.3.4 Spill Containment 35 3.4 Gasoline Storage Tanks 35 3.4.1 Construction. 35 3.4.2 Instrumentation 36 3.4.3 Operation 36 3.4.4 Spill Containment 36 3.5 Sulfuric Acid Tank 35157 36 3.5.1 Construction. 36 3.5.2 Instrumentation 37 3.5.3 Operation 37 3.5.4 Spill Containment 37 3.6 STS Bulk Underground Fuel Oil Tank 37 [,_

3.6.1 Construction.

37 \\~- 3.6.2 Instrumentation 37 LEWO204.WP6 xiii

WVDP-043 . p] ; } Rev. 4 3.6.3 Operation 37 3.6.4 Spill Control 37 3.7 High Level Waste Tanks 8D-1 and 80-2 38 3.7.1 Construction. 38 3.7.2 Instrumentation 38 3.7.3 Operation 38 3.7.4 ' Spill Containment 38 3.8 Tanks 8D-3 and 8D-4 41 3.8.1 Construction. 41 3.8.2 Instrumentation 41 3.8.3 Opuration. 41 3.8.4 Spill Containment 43 3.9 Interceptors and Neutralization Pit 43 3.9.1 Construction. 43 3.9.2 Instrumentation 43 3.9.3 Operation 43 3 9.4 Spill Containment 44 3.10 Manipulator Repair Shop Waste Catch Tank 15D-6 44 3.10.1 Construction 44 3.10.2 Instrumentation. 44 3.10.3 Operation. 44 3.10.4 Spill Containment 44 3.11 Low-Level Waste Catch Tank 7D-13 44 (i 3.11.1 Construction 44 \\s,/ 3.11.2 Instrumentation. 45 3.11.3 Operation. 45 3.11.4 Spill Containment 45 3.12-Low-Level Waste Treatment Facility Outside Tanks 45 3.12.1 construction 45 3.12.2 Instrumentation. 45 3.12.3 Operation. 46 3.12.4 Spill Containment 46 3.13 Waste 011 Collection Tank 46 3.13.1 Construction 46 3.13.2 Instrumentation. 46 3.13.3 Operation. 46 3.13.4 Spill Containment 46 3.14 Future Vitrification Facility Tanks 47 3.14 1 Tanks to be Located Within the Vitrification Facility Pit 47 3.14.2 Tanks and Vessels in 01-14 Building Containment Cell 47 3.14.3 Diesel Fuel Storage Tanks Located in the 01-14 Building. 49 3.14.4 Generator Diesel Fuel Tank and Day Tank. 50 3.14.5 Additional Vitrification System Tanks 50 3.14.6 Scaled Vitrification System Tanks 50 3.14.7 Cold Chemical System Tanks 51

g-3,15 Supernatant Treatment System Tanks 51 l T 3.15.1 Tanks and Vessels in Tank 8D-1 51 l

3.15.2 Tanks and Vessels in the Valve Aisle 52 LEWO204.WP6 xiv l

WVDP-043 g j Rev. 4 v 3.35.3 Tanks and vessels in the Operating Aisle 52 3.16 Liquid Waste ~ Treatment System (including Cement Solidification System)_ 52 3.16.1 Tank 35104 52 3.16.2 Tanks Located Within the Liquid Waste Cell. 53 3.16.3 Tanks Located in the Vessel Off-Gas Cell 53 3.16.4 Sodium Silicate Bulk Storage and Day Tank 53 3.16.5 Tanks Located in the Uranium Process Cell (UPC). 54 3.16.6 Tanks and Vessels Located Within Extraction Cell 3 54 3.16.7 Tanks Located Within the Lower Extraction Aisle 55 3.16.8 Waste Dispensing Vessel (70D-001) 55 3.16.9 Roof Top Evaporator (31008) 55 3.16.10 Tank 5V 55 3.17 Tanks Located Within the Low-Level Waste-Treatment Facility 56 3.17.1 Acid Hold Tank (33013) and Two Potassium Ferrate Tanks 56 3.17.2 Ion Exchange Columns 101 and 102 56 3.18 Trench Interceptor Project Pretreatment Tanks 57 /~' 3.19 Miscellaneous Facilities. 58-(_)N 3.19.1 Transfer Tanks 58 3.19.2 Portable Diesel Fuel Tank. 58 3.19.3 Utility Room Diesel Day Tank (48066-A) 58 3.19.4 Vessel Off-Gas Condensate Catch Tank (6D-3) 58 3.19.5 Tanks Located Within the Waste Tank Farm Shelter 59 3.15.6 Zinc Bromide Shield Windows 59 3.19.7 Fire Pump Day Tank 59 3.19.8 STS Day Tank-60 3.19.9 Receiving Warehouse Storage Cabinets for Flammable Liquids 60 3.19.10 New Main Warehouse 60 3.19.11 Cargo Unit Trailer Body 60 3.20' Hazardous Waste Satellite Accumulation Areas. 61 3.21 Interim Waste Storage Facil-ity (IWSF) 61 3.22 Four Hazardous Waste Lockers. 61 3.23 Portable Holding Tanks 63 3.24 Mineral Oil Windows 63 3.25 Waste Tank 8D-2 Caustic Transfer Staging Area 63 3.26 Ram Equipment Room. 63 4.0 Potential Oil, Hazardous Substance, or Hazardous Waste Release Scenarios 64 7-w 4.1 Sources. 64 ( j 4.2 Migration Pathways 64 LEWO204.WP6 xv

WVDP-043 /~}j Rev. 4 y 68 5.0 Spill Prevention Program 5.1 Training Program 68 5.2 General Training 69

5. 3 - Plant Operator Training.

69 5.4 Safety Training. 69 5.5 Emergency Spill Response Training. 69 5.6 Hazardous Waste Management Training. 70-5.7 Retraining Program 70 5.8 Administration and Records 70 5.9 Inspections and Recordkeeping. 70 5.10 Site Security. 72 73 6.0 Contingency Plan 6.1 -Spill Response Equipment 73 6.2 Spill Prevention and Emergency Preparednesa. 73 6.3 Notifications. 78 6.4 Storage and Handling 80 O LIWO204.WP6 xvi

O WVDP-043 Rev. 4 LIST OF FIGURES Fioure Egga 2-1 WNYNSC and WVDP Locations........................... 4 2-2 Site Plan and Sitewide Spill Migration Pathways...... 6 2-3 Probable Subsurface Spill Migration Pathways......... 8 3-1 Tank Storage and-Process Area Locations.............. 31 3-1A Tank Storage and Process Area Locations............. 32 Storm Water System, Local Spill Migration Pathwa 4-1 and Diversion Basins............................ys, 65 6-1 Placards and Applicarle Response Guide............... 74 6-2 Substance Release Report Form........................ 79 l l- ' t^) L LEWO204.WP6 xvii L

4 T WVDP-043 ./ Rev. 4 LIST OF TABLES, i ). Table Pace t-3-1 WVDP Oil,-llazardous Substance, }{a.~_ardous Waste Storage Facilities................................... 13 1

j 3-2 PUREX Supernatant Chemical Composition...............

39 g 3-3 PUREX Sludge Chemical Composition.................... 40 3-4 Til0 REX Wasto A6mical Composition.................... 42 i l, 3-5 Typical -.o.1 . < /eed !!ydroxide Clurry................. 48 l 3-6 Hazardous Wa.s e Satellite Accumulation Arean......... 62 1 1 I a l O LEWO204.WPG. xviii

i WDP-04 3 Rev. 4 APPEl/ DICES A Emergency Guides for Substances Used at the WDP B Distribution Sheet l t t l' L l l l l l l l l I l LEWO204.WP6 xix

O WVDP-043 Rev. 4 ACRONYMS BMPs Ugst Management Practicos CB Catch basin CERCLA comprehensive Environmental Response, Compensation and Liability Act CFR Code of Federal Regulations CllEMTREC Chemical Transportation Emergoncy Centor CHRIS Coast Guard Chemical Response Information System CWA Clean Water Act CSS Cement Solidification System DCS Distributive Control System DOE United States Department of Energy DOT United States Department of Transportation EOC Emergency Operations Contor EMT-Emergency Medical Technician EPA United States Environmental Protection Agency FWPCA Federal Water Pollution Control Act HLW High-Level Waste HWSF Hazardous Waste Storage Facility IWSF Interim Waste Storage Facility LLW Low-Level Radioactive Waste LLWTF Low-Level Waste Treatment Facility (O2 Plant) O-LWTS-Liquid Waste Treatment System MH-Manhole MSDS Material Safety Data Sheet MSIi Mean Sea Level NDA Nuclear Regulatory Commission Licensed Disposal Area NFPA-National Fire Protection Association NFS Nuclear Fuel-- Services company, Inc. (original site operator) NYCRR New York Code of Rules and Regulations NYSDEC New York State Department of Environmental Conservation NYSERDA New York State Energy Research and Development Authority OHMT/.DS 011 and Hazardous Material Technical Assistance Data System OSHA Occupational Safety and Health Administration PCB Polychlorinated Biphenyl PVS l'ermanent Ventilation System RCRA Resource Conservation and Recovery Act RDA Radiation Detection Alarm RQ Reportable Quantity SAA Satellite Accumulation Area SARA Superfund Amendments and Roauthorization Act SOP Standard Operating Procedure SPCC Spill Prevention Control and Countermeasure STS Supernatant Treatment System l SPDES State Pollutant Discharge Elimination System s TRU Transuranic TSCA Toxic Substance Control Act LEWO204.WP6 - xx ~

4 WVDP-043 Rev. 4 TSDF Treatnant, Storage and Disposal Facility UPC tiranium Product cell UR Utility Room VF. Vitrification Facility WVDP West Valley _ Demonstration Project WVNs West Valley Nuclear Services company Incorporated I i .s c v i l LEWO204.WP6 xxi v-t-r, r om w,m m -.,,, ec --. -. - -,,, < -, -, ~ --n--.w=+ ..n.. +.-, --w-.--.-w,rva-,m.,- -..,,.m-,.w-,-,-e,,..v.mn,-n, ,+,mm,r ~.w -e n,..,. m.w. w...r w.em,m g o m, n w we. w w-

O WVDP-043 Rev. 1 DEFINITIONS Technical terms used or referred to in the Spill Prevention, control, and Countermeasures plan are defined as follows: 1. Best ManaE2msnt Practices (BMPst - Schedules of activities, maintenance proceduros, prohibitions, and other management practices to provent or reduce pollution of U.S. waters. DMPs also include treatment requirements, operating procedures, end practicos to control plant site runoff, spillage or leaks, sludge and wasta disposal, or drainage from raw materials storage. 2. Combus_tible Liould - A liquid having a flash point at or above 100'F (37.B'C) and below 200'F (93.3'C) 3. Container - Any portable device in which a matorial is stored, transported, treated, disposed of, or otherwiso handled. 4. Containment - An enclosure or enttapment that provents further spread of a spilled matorial. 5. Containment Volung - The volume of a diked or curbed area minus the displacement volume of structures within the diked or curbed area. 6. Contincency Plan --A document setting out an organized, planned, and coordinated course of action to be followed in case of a fire, explosion, or release of oil or hazardoua waste or hazardous wasto constituents which could throaten l human health or the environment. 7. Diha - An embankment or ridge of either natural or man-mado materials used to prevent the movement of liquids, sludges, solids, or other materials. 8. Discharco - Any spill, leak, emission, pumping, pouring, emptying, or dumping from a container, vessel, or diko. l 9. Discosal and Transnortation of the Snilled substance - Cleanup of a material from a spill site and transportation of the spilled substance to approved disposal facilities. 10. Environmental Incident - Any accident or occurrence that involves uncontrolled release or has the potential for uncontrolled release of oil or hazardous materials to the environment. O This includes violations of a dischargo permit. LEWO204.WP6 xxii

WVDP-043 Rev. 4 11. Flammable Liauld - A liquid having a flash point below 100'F ( 3 7. 8'C) and a vapor pressure not exceeding 40 psia (absolute) at 100'F. i 12. Harmful Oil Discharaes - Defined in 40 CFR 110.3 (in compliance with Statute Sect. 311(6)(3) of the Clean Water Act), as discharges that "(a) violate applicable water quality standards or (b) cause a film or sheen upon or discoloration of the surface of the water or adjoining shorelines or cause a sludge or emulsion to be deposited beneath the surface of the water or upon adjoining shorelines." 13. Hazard Lah21 " A visual indicator consisting of easily recognized and understood markings which identify tank and process equipment contents and indicate the degree of hazard. 14. Hazardous Material on Substance - 1) Any substance that may pose a threat to safety, health, environment,-or property;

2) any substance designated pursuant to Statuto Sect.

311(b) (2) (a) of the Federal Water Pollution control Act (FWPCA); 3) any hazardous wanto having the characteristics t under or lis-J pursuant to Statute Sect. 3001 of the Solid Waste Dispos 1 Act; 4) any toxic pollutant listed under Statuto Sect. 307(a) of the FWPCA; and 5) any imminently hazardous chemical substance or mixture of substances set forth in the Toxic Substances Control Act (TSCA). 15. Hazardous Waste (HW1 - A solid wants that meets the criteria listed in 40 CFR 261.3. 16. Hazardous Waste Storace Facility (HWS11 - a facility designated for the interim storage (<90 days) of hazardous wastes prior to off-site shipment to a permitted Treatment, Storage, or Disposal Facility (TSDF). 17. Material Safety Data Sheet (MSDS) - Description of the physical properties and hazards of a chemical, prepared in accordance with paragraph (9)(g) of 29 CFR 1910.1200, Occupational Safety and Health Administration (OSHA). 18. Mixture - Any combination of two or more elements and/or compounds in solid, liquid, or gaseous form, except where such substances have undergone a-chemical reaction so as to become inseparable by physical means. 19. Naviaable Waters - Defined in section 502(7) of the Clean Water Act.(CWA) to mean " waters of the United States, () including the territorial seas," and including, but is not l limited to (1) All waters which are presently used, or were LEWO204.WP6 xxiii

l l l WVDP-043 (~) Rev. 4 s_- used in the past, or may be susceptible to use as a means to transport interstate or froight commerce, including all waters which are subject to the obb and flow of the tido, and including adjacent wetlands. The term "wotlands" an used in this ragulation shall include those areas that are inundated or saturated by surface or groundwater at a frequency and duration sufficient to support, and that under normal circumstances do support, a prevalence of vogotation typically adapted for life in saturated soil conditions. Watlands generally include swamps, marshes, bogs and similar areas. The term " adjacent" means bordering, contiguous, or neighboring. (2) Tributarios of navigable waters of the United States such as interstato lakes, rivers, streams, mudflats, sandflats and votlands, the uso, degradation or destruction of which affect interstato commerce including, but not limited to: (1) Interstato lakes, rivers, streams, and votlands which are utili:od by interstate travelers for recreational or other purposos; (ii) Interstato lakes, rivers, streams, and wetlands from which fish or shellfish are or could be taken and sold (~) in interstato commerce; and 's J (iii) Interstato lakes, rivers, streams, and wetlands which are utilized for industrial purposes by industries in interstate commerco. 20. Q11 - 011 of any kind or in any form including but not limited to petroleum, fuel oil, sludge, oil refuso, and oil mixed with vastos other than dredged spoil. 21. PCB-Contaminated Electrical Ecuinment - Any electrical equipment, including but not limited to transformers, capacitors, circuit breakers, reclosures, voltage regulators, switches, electromagnets, and cable that contain 50 ppm or greater PCBs but loss than 500 ppm PCBs. Oil-filled electrical equipment other than circuit breakers, reclosures, and cable whose PCB concentration is unknown must be assumed to be PCB-contaminated electrical equipment. 22. PCB Transformer - Any transformer containing 500 ppm of PCBs or greator. 23. Primary Containment - The tank or container for holding hazardous materials, hazardous wastos, or oils. r-24. Renortable Ouantity (RO) - Quantity of a substance that may (,}/ be harmful as set forth in 40 CFR 117.3 and 40 CFR 302. The LEWO204.WP6 xxiv

O WVDP-043 Rev. 4 dischargo of an RQ is a violation of the FWPCA and must be reported to EPA. 25. Satellito Accumulation Area (SAA) - An area where hazardous waste is accumulated, located at the point of initial generation of the hazardous wasto. 26. Secondary containment - A containment system which is capable of holding and collecting any spills, leaks, rainuater, and/or fire protection water (e.g., sprinkler system discharge) originating from primary containment vossolo and other process equipment. 27. Steen - An iridescent appearance on the surface of water. 28. Sludae - An aggregate of oil or oil and other matter of any kind, in any form other than dredged soil, having a ccn hined specific gravity equivalent to or greater than that of water. 29. SPDES Perniit - Stato Pollutant Discharge Elimination System Permit required by the Environmental Protection.*.gency (EPA). 30. Transfer St.ation - Location or facility whero nazardous materials / wastes are transferred to and from portable containers or tankers into tanks and/or process equipment. O LEWO214.WP6 xxv

WVDP-043 O Rev. 4 OIL, MAZARDOUS SUDSTANCES, AND HAZARDOUS WASTES SPILL PREVENTION CONTROL, AND COUNTERMEASURES PLAN 1.0

SUMMARY

The U.S. Department of Energy (DOE) specifically mandates Spill Prevention Control and Countermeasures (SPCC) Plans in ID Order 5480.1, Chap. V,c.d., which states that DOE sitec must comply with regulations presented in Code of Federal Regulations (CFR) 40 112.7, for owners and operators of facilities having a potential for discharge of harmful quantities of oils to navigable waters. Following discovery of a discharge or potential discharge, the sequence of follow-up actions should comply with 40 CFR 1510.e. Similar provisions mandated by 40 CFR 761 apply to the discharge of matorials contaminated with polychlorinated biphenyls (PCBs). Similar provisions mandated by 40 CFR 302 and 355 and by 6 NYCRR 597.2 apply to the release of hazardous and extremely hazardous substances. This document addresses the requirements set forth in the above regulations. Regulations also mandate that this plan be reviewed and updated every three years. The SPCC Plan consists of two parts: 1) owner / operator plans for preventing unintentional discharges oil or hazardous materials; i and 2) owner / operator plans for response in the event of an unintentional discharge of oil or hazardous materials. Spill prevention and control is achieved through a comprehensive program of planning, design, operations, inspection,-and-training, all directed towards spill avoidance and quick response for containment, mitigation, and cleanup should a spill occur. The plan describes the engineered features and administrative controls used to preclude spills of oil, hazardous substances, and hazardous wastes, and response procedures developed to minimize deleterious effects of a spill. Section 2 provides background information on the West Valley Demonstration Project (WVDP) in West Valley, New York. Included are de=criptions of process waste streams, site drainage, sanitary and storm sewer systems, and a spill history. Section 3 presents information on oil, hazardous substances, and hazardous vaste storage facilities on the site, including information on secondary containment and tertiary containment provisions. Section 4 presents information on potential releases, including idantification of sources and migration pathways in the event of a spill. LEWO204.WP6 1

O WVDP-043 Rev. 4 2.0 BACKGPOUND INFORMATION This SPCC plan has been developed in accordance with 40 CFR 112, which has been defined as the applicable regulation by DOE Order 5480.1. According to 40 CFR 112, spill containment can be provided by secondary containment systems including dikes, be rms, retaining walls, or. curbing (CFR 112.7(c)(1)), or by culverting, gutters, or other drainage systems (CFR 112.7 (c)(iii)). As outlined in this.SPCC Plan and as demonstrated in the few major spil.1 events that have occurred in the past at the WVDP, all oil ann hazardous materials storage facilities at the WVDP are provided with secondary containment through one or both of these methods of containment. This containment system also would provide containment in the event of a release during transportation or material transfer operations. The WVDP is an activity of the DOE Idaho operations office and is being operated pursuant to the West Valley Demonstration Projnct Act (P.L. 96-368). The operating centractor for the DOE Idaho operations Office is the West valley Nuclear Services Co., Inc. (WVNS), a wholly owned subsidiary of the Westinghouse Electric Corporation. The Western New York Nuclear Services Center (WNYNFC) is a 1,335-hectare reservation owned by the State of New York. The WVDP is located on a 64-hectare parcel within the WNYNSC (see Figure 2-1). The WVDP includes a process building and support facilities that were formerly operated by Nuclear Fuel Services Co. (NFS) for reprocessing fuel but have not been used for reprocessing nuclear fuel since 1972. The objectives of the Project ares to solidify 2.2 million liters of high-level radioactive waste (HLW) stored at the WNYNSC; to dispose of the low-level radioactive waste (LLW) and transuranic (TRU) waste generated in conjunction with the Project; and then to decontaminate and dacommission the facilities used during the Project. The facilities were maintained in a. shut-down condition from 1972 to 1982, when the WVDP began decontamination of the facilities in preparation for their reuse in the Vitrification and Integrated Radioactive Waste Treatment systems. Other facilities at the WVDP were specifically constructed for the Project. In February 1975, NFS prepared and submitted an SPCC Plan for the reprocessing facility. The 1975 plan was amended in April 1977 when two existing boiler steam condensate tanks were refitted for use as oil storage tanks. These two tanks were drained and (~ removed from service in 1984. In June of 1985, an update and ( expansion of the NFS SPCC plan was issued by WVDP as WVDP-043. The WVDP plan covered hazardous materials (as identified in LEWO204.WP6 3

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- ~ WVDP-043 Rev. 4 40 CFR 116) in addition to oil and other patroleum products. This revision updatos the 1985 plan to cover tan' s added since that time and existing tanks that.have been usod since that time for storage. of materials covered in 40 CFR 112, and 116, 302.4, 355 and 6 N7CRR 597.2, or may be used for such purposes. The l current revision includes identification of Gate 111to Accumulation Areas (SAAs), the Interim Wasto Storago Facility i (IWSP), and the Hazardous Wasto Storago Lockers. 2.1 Sito Topography and Drainage Figure 2-1 shows major drainage pathways for the WNYNSC and the WVDP. The Project area is drained by throo creeks, namely, Erdman Brook, Quarry Crook, and Frank's Creek. The WNYNSC in drained by those throo crooks, as well as Buttermilk Crook, and Cattaraugus Creek. Erdman Brook and Quarry Crook are tributarios to Frank's Creekt Frank's Creek is a tributary of Buttormilk Crook; Buttermilk Creek is a tributary of cattaraugus Crook. Buttermilk Crook originatos south of the town of West Valley, New York, entors the WNYNSC at Ricaville Station and flows through O the site in a generally northwesterly direction until it joins cattaraugus Crook some eight stream kilomotors later. The WVDP facilities are at an olevation of slightly over 431.3 m above mean sea level (MSL). The elevation of Buttormilk Crook at its entrance to the sito is about 365.8 m, and the elevation at the confluence with Cattaraugus Crook is slightly.over 335.3 m. The total drainage area of Buttermilk Crook is estimated to be 48,215 hectares (ha), with an average flow rato of 46.5 f t?/ soc. Cattaraugus Crook flows in a genorally westerly direction from the site to Lako Eric somo 63 km away. The total drainage area of Cattaraugus Creek is estimated to be 877,350 ha. The drainage area of the Cattaraugua above the-confluence with Buttermilk Creek is estimated to be 344,600 ha. Thus, the average flow in Cattaraugus Creek past the sito may be estimated to be fifty percent of the average flow rato, or 354 ft?/sec. No public water supplies use Buttermilk or cattaraugus Creeks as a sourco of potable water. The Village of Springville operatos a dam / hydroelectric generating station on Cattaraugus Crook approximately 4 km below the confluence of Buttermilk and Cattaraugus Creeks. Figuro 2-2 shows site topography and additional drainage details, and identifies major Project facilities involved in storage of oil, hazardous substancos, or hazardous waston. No significant O Project construction beyond the facilities shown in this figura is currently envisioned. LEWO204.WP6 5 r

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WVDP-043 Rev. 4 2.2 Hydrosphere The West Valley site is underlain by at least two water regimes, neither of which is considered highly permeable. The upper regime consists of the saturated portion of the surficial sand, silt, gravel, clay, and weathered till, ranging in thickness from about 1.5 m to 6.0 m. The upper regime is underlain by unweathered glacial ti.1 that ranges in thickness up to about 30 m. The unweathered till is underlain by a lower water regime a few meters thick, consisting of decomposed shale and bedrock. The lower water regime is underlain by bedrock. The upper water region is involved in the surface hydrologic cycle. The approximate direction of groundwater flow in the surficial unit, based upon water level measurements, is easterly or northeasterly from the western boundary of the site. Most of the water in this unit drains into Frank's Crook, either :lirectly or via olie of its tributaries. Figure 2-3 depicts groundwater flow patterns on the site as constructed by Yager (1987). The arrows indicate the pathways along which groundwater might be expected to flow within the D water table upper aquifer. Much of the groundwater from the upper aquifier discharges at the seeps indicated on the figure. The surface water regime of the WVDP includes several small tributaries of Buttormilk Creek, the onsite LLW treatment lagoons, and the two water supply reservoirs, in addition to the Buttermilk Creek tributaries of Frank's Creek, Quarry Creek, and Erdman Brook. The plateau on which the Preject facilities are located is dissected by the steep-walled valleys of these streams. Surface runoff from plant areas is directed into those channels via drainage ditches and culverts. The onsite low-level waste water treatment facility ( LLWTF) includes four lagoons (numbers 2, 3, 4 and 5), the largest of which contains a controllable discharge pipe to Erdman Brook. Of thcoe four lagoons, numbers 4 and 5 are small feed and effluent holding basins. Lagoon 2 can hold 12.2 million liters and Lagoon 3 can hold 13.4 million liters. Two onsite reservoirs, (see Figure 2-1), were created by damming branches of Buttermilk Creek to an elevation of 414.5 m above 3 seal level (MIG) impounding a24,100 m of water. l 2.3 Effects of Local Intense Precipitation Probable Maximum Precipitation (PMP) events have been estimated 9 for the plant site, Buttermilk Creek, and the plant reservoirs, LEWO204.WP6 7

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) WVDP-043 () Rev. 4 based upon Hydrometeorological Report 31 and the following drainage basin areast Buttermilk Creek 7,903 hectares Plant Site 606 hectares Plant Reservoirs 1,257 hectares The water levels in Buttermilk Creek for the PMP event were at least 50 meters below the plant elevation and therefore could not influence the plant area. The plant site was evaluated in a similar manner. With the PMP increased by 50 percent, water levels in Frank's Creek would reach a maximum elevation of 53 meters below plant grade. T'ae winter PMP (snow and liquid) for the WVDP was estimated in Nicholas and Eagan (1983) using 100-year snowpack depths from Syracuse, New York, and the snowpack density conversion method of Bilallo (1969), using a density of 0.25 with watar equivalent snowpack depths of 44.5 and 36.8 cm for February and March, 3 3 corresponding to snowloads of 444.3 kg/m and 368.6 kg/m respectively. 2.4 Floods Because Buttermilk and Cattaraugus Creeks lie in deup valleys, f little area is available for farming or housing; thus the effects of any flooding of the flood plain have been minimal and no history of floods in the area is available. The Chief, Flood Plain Management Services, Buffalo District, corps of Engineers, stated in a letter to NFS, quoted in the NFS 1973 Safety Appraisal Report: We do not feel that the 100-year flood stage of Buttermilk Creek will affect your proposed plant as it is at least 120 feet above the creek. The drainage area of Buttermilk Creek, upstream of your plant, is too small to be able to provide enough water to raise the creek stage the necessary 120 feet. In addition, before the creek stage could rise even 110 feet, it would spill over the divide on the west bank and flow down the valley of a tributary. 2.5 Probable Maximum Flood As indicated above, flooding of the plant area is not a possibility because of the deep valleys of Buttermilk and ( Cattaraugus Creeks. LEWO204.WP6 9 g

WVDP-043 ( Rov. 4 I June 1984, when the underground caustic transfer pipe between caustic storage Tank 14D-2 and the LLWTF released up to 3,800 liters of a 50 percent sodium hydroxide solution. This spilled material was routed into the LLWTF lagoon system, where it was neutralized prior to discharge via SPDES Outfall 001. The leaking pipe was excavated, ropaired, and pressure-tested prior to being returned to service. A spill of radioactivc wastewater occurred on March 15, 1985. This incident involved thn release of approximately 500 gallons of radioactive condensate. The spill occurred during the transfer of HLW tank farm of f-gas condensate from Tank 8D-1 to HLW storage tank 8D-2. It resulted from a corroded flango in the transfer line. The release was largely contained within the waste tank farm by erecting dams over drainago culverts to contain runoff and divert run-on. The affected area was decontaminated and the lines-repaired and tested. As a result of this incident, operations policy was changed to provide testing and repair prior to use of all underground transfer lines that had not been used within the previo s three months. In July 1986, a small spill of diesel fuel in a construction laydown area occurred approximately JO meters northeast of the waste water treatment lagoons. This spill consisted of a release i of 30 to 50 gallons of fuel from a parked dump truck. The cause of the leak was a perforated fuel line on the truck. Corrective action consisted of collecting the spilled fuel in buckets and on clay absorbent and securing the leaking fuel line. This event was confined to the immediate area and resulted in no release to surface waters. There have been no reportable spills (as defined by 40 CFR 110) f. at the WVDP within the past year. Monthly spill reporting [ requirements to the DEC are detailed in Section 6.2 of this document. l l O LEWO204.WP6 11 l

WVDP-043 O Rev. 4 V 3.0 STORAGE FACILITY CONSTRUCTION, INSTRUMENTATION, AND SPILL CONTAINMENT The following sections describe the major outdoor storage tanks, underground tanks and other sources with a potential for environmental releases of oil, hazardous substances or hazardous wastes. These installations are summarized in Table 3.'. The locations of these tanks (or buildings containing tanks) are shown on figures 3-1 and 3-1A. 3.1 Fuel Oil Tank 31D-2 3.1.1 Construction Tank 310-2 is a 38,000-liter carbon steel vessel, 2.8 m in diameter by 6.1 m long. It is used to store No. 2 fuel oil for emergency operation of the boilers and is steam-hcated to allow the oil to flow freely upon demand. The tank in clovated above a diked earthen spill basin by two reinforcad concrete piers. The basin is equipped with a six-inch drain which is controlled by a manually operated gate valve. 3.1.2 Instrumentation Tank 31D-2 is equipped with level indicator and temperature instrumentation. Sight glasses, which are on the east side of the vessel, allow direct readout of the level in the vessel. More accurate-level indication is provided by an air-purged instrument mounted _off the lower connection of the sight glasses. A temperature gauge displays the temperature inside the vessel. 3.1.3 Operation This tank is normally filled via a hose from a tank trucX into the top of the tank, which places everything but the tank truck inside the diked area. An alternative fill method is via a line to an elevated platform on the west side of the tank alongside railroad tracks. Valves are located at the top of this line and the point where the line enters the tank. This line is outside the diked area. Instructions for receiving fuel in Tank 31D-2 are presented in Project Standard Operating Procedure (SOP) 31-2, " Steam Generation." This procedure requires the operator to observe the level in the tank before and after material transfer and provides a detailed sequence of instructions to minimize the likelihood of spills or overflows during transfer. Tank filling is a manual operation requiring operator attendance throughout the entire [ procedure. Thus, any spills during the transfer should be \\ immediately identified and corrective action implemented. LEWO204.WP6 12 -. =

\\ o WDP-04 3 l Rev. 4 l TABLE 3-1 WDP OIL. HAIAFDOUS SUBSTANCE. HA!ARDOUS WASTE STORAGE FACILITIFS Nominal Cc.pacity Ccntents l (liters) and/or Spill Instrumentation Associated l i Tank / vessel Construction foallonsi Location Function Contairment with Spill Control F01 2.8 m diameter 38,000 Yard East of Fuel Oil No. 2 Spill basin, Slght glasses and level 31-D-2 (see x 6.1 m long; 10,000 UR 84,700 L indicator capacity section 3.1) elevated above basin by 2 reinforced concrete piers, steam coil heated, carbon steel 14-D-1 (see Stainless steel 45,500 Yard east of eepty;, Spill pad with Level indicator Section 3.2) 4.1 m diameter 12,000 UR formerly drain line to contained 14M interceptors x 3.7 m high nitric acid 14-D-2 (see Carbon steel 45,500 Yard east of Empty; formerly Spill pad with Level indicator Section 3.3) 4.1 m diameter 12,000 UR contained 504 drain lines to sodium interceptors x 3.7 m high steam coil hydroxide heated spray insulated exterior 14-D-2A (see Carbon steel, 1,900 Yard east of eepty (formerly Spill pad with Level indicator Section 3.3) steam coil 500 UR contained) 25% drain lines to sodium interceptors heated; spray insulated hydroxide exterior G01-GO3 Carbon steel 7,500 South and (1) unleaded + Silty till Periodic leak testing. Gasoline 2,000 west of gas Storage (each) warehouse (1) unleaded Tanks (3) gas (1) diesel (see Section fuel 3.4) SPCCT31C.WP6 13

m L 1 L WVDP-043 Rev. 4 i TABLE 3-1 WVDP OIL, HAZARDOUS SUBSTANCE. HAYAPDOUS WASTE STORAGE FACILITIES [ Nominal f Capacity contents l (liters) and/or Spill Instrumentation Associated Tank / vessel Construction (callons) Location Function Containment with Spill control .t i 35157 Polyethylene 11,000 Adjacent Sulfuric acid Curbed concrete Level gauge j ' Sulfuric 3,000 (south) to 934 spill pad i Acid Tank LLWTF r (see Section 3.5) i I C04 Steel double-' 2,100 Underground Diesel Fuel Double-walled Leak detection senscr with I STS bulk walled under-550 northeast of construction air, water, and hydrocarbon . fuel oil-ground tank STS building indic m rs in PVS. Alarm tank (see with bitumastic in STS control room j Section 3.6) coating I BD-1 (see Carbon steel 2.8 Waste tank Housea STS Carbon steel Pan has moisture sump; tank i Section 3.7) tank million farm process tanks pan; concrete has level and pressure [ i 740,000 vault; silty indicators and alarma till ? E 8D-2 (see Carbon steel 2.e Waste tank Neutralized Carbon steel ?an has moisture surp; tank j i Section 3.7) tank million farm high level pan; concrete has level and pressure i j 740,000 radioactive vault; silty indicators and alara.s [ i waste see till f j Tables 3-2 and 3-3 i 8D-3 (see Stainless steel 57,000 Waste tank STS processed Stainless steel Pan is equipped with an l Section 3.8) tank 15,000 farm supernatant pan and alarmed sump; tank has j storage tank concrete vaalt level and pressure l Table 3-2 less (shares with indicators and alarms cesium 8D-4); silty I till i I i i l L SPCCT31C.WP6 14

O O WVDP-043 Rev. 4 TABLE 3-1 WVDP OIL. HAZAPDOUS SUBSTANCE. HAZARDOUS WASTE STORAGE FACILITIES Nominal Capacity contents (liters) and/or Spill Instrumentation Associated Tank / Vessel construct Qrl reallons) Location Function containment _ with Spill control i 8D-4 (see Stainless steel 57,000 Waste tank Acidic waste Stainless steel Pan is equipped with an Section 3.8) tank 15,000 farm produced from pan and alarmed sump; tank has THOREX process concrete vault level and pressure (Table 3-4) (shared with indicators and alarms 8D-3); silty till North Concrete, lined 87,000 East of main Collects liquid Silty till, High level alarm j Interceptor w/SS 23,000 process from plant overflow to old l (see Sect on building drains and intercaptor 3.9) sumps. (radioactive ] wastewater) South Concrete, lined 87,000 East of main Collects liquid Silty till, High level alarms Interceptor w/SS 23,000 process from plant overflow to old l (sea Section building drains and interceptor 3.9) sumps j, (radioact8' i wastewate4 i Neutraliza-Concrete, lined 1,900 East of main Adjusts pH of Silty till None tion Pit w/SS 500 process incoming wastes l (see section building (radioactive 3.9) wastewater) i Old Concrete 56,850 East of main Temporary Silty till ho..e Interceptor 15,000 process storage of off-(see Section building spec effluent 3.9) i 15-D-6 (see 1.8 m diameter 5,700 Underground HEV and decon None Monitoring well, level Section x 2.4 m high 1,500 adjacent to shop waste recorder, high level alarm 3.10) stainless steel east side of catch tank contact size (radioactive i reduction wastewater) i facility SPCCT31C.WP6 15

r WD P-04 3 Rev. 4 i S F J-1 WDP OIL. HAZARDOUS SUBSTANCE, HAIARDOUS WA$TE STOFAGE FACILITIES i Nominal I capacity contents (liters) and/or Spill Instrumentation Aesc,ciated Tank / Vessel Construction foallons) Location Function Containment with Spill Control 7-D-13 (see SA 240/307 L SS 7,500 Underground Low level waste None Level recorder, high level Section 1.4 m diameter 2,000 adjacent to catch tank drum alarm 3.11) x 4.1 m long east side of flush from CSS contact size (radioactive reduction wastewater)- j facility i 33012 Stainless steel 29,000 concrete pad Low-level

Concrete, High, low alarm level Recycle Tank 7,650 south of radioactive curbed pad indicator I.

(see Section LLWTF wastewater i 3.12) 48070 Staininas steel 64,450 Concrete pad pH adjusted low

Concrete, Auto system overflow Flocculator 17,000 south of level curbed pad j

Clarifier) LLWIF wastewater (see Section 3.1~. ) 35105 Stainless steel 3,500 Concrete pad Clarified

Concrete, High, low alarm, level Clarified 950 south of low-level curbed pad indicator, recorder, auto Water LLWTF wastewater system overflow j

Surge Tank '3 (see Section 3.1"c ) l 48091 Stainless steel-18,950 concrete pad Clarified

Concrete, Ievel indicator, recorder, 4

Clarified 5,000 south of low-level curbed pad level alarm, auto system Water Filter LLWTF wastewater overflow (see Section l 3.12) i Wacte Oil Carbon steel 660 NDA container Waste engine Carbon steel Nor.t Collection 175 storage area lubricating oil box with Tank (see herculite Section liner, ' 2120 L 3.13) spill capacity SPCCT31C.WP6 16

O ( O WVDP-043 Rev. 4 L TABLE 3-1 WVDP OIL. HAZARDOUS SUBSTANCE. HAZAFDOUS WASTE STORAGE FACILITIES i Nominal l Capacity Contents (liters) .and/or Spill Instrumentation Associated Trnk/ Vessel Constructict f oallonjlQ, . Incation Function Containment with Soill Control r Future Vitrification Facility Tanks l j Additional Vit Systen Tanks and VIT " Pit" Tanks (See Section 3.14.1 and 3.14.4) 1 63-V-11 304 SS 22,237 VF

Pit
Helter Feed VIT " Pit" Level and density j

6,000 Hold Tank i_ cators and high, low i al. as 63-V-01 Haste 11oy 32,930 VF

Pit" Concentrator

'iT

Pit" Level and density

[ j 9,000 Feed Makeup indicators and high, low } Tank alarms k i SbS Receiver 304 SS 5,488 VF " Pit" Helter Off-gas VIT " Pit" Level and density i 63-V-031 1,500 Scrub Solution indicators and high, low i-alarme VIT Vessels in 0-14 Bu11dino containment cell (See Section 3.14.2) 64-D-01 304 SS 1,722 0-14 Dilute HNO 01-14 Cell Level and density [ 3 Primary 500 Containment Solution indicators and high/ low Surge Tank Cell level clarms j 3 64-D-03 304 SS 1,722 01-14 Dilute HNO 01-14 Cell Level and density f Secondary 500 Containment Solution indicators and high/ low Surge Tank Cell alarms 3 64-D-05 304 SS 1,987 01-14 Dilute HNO 01-14 Cell Level an:t density Primary 500 Contai.wnt Solution indicators and high/lcw Storage Tank Cell alarms 64-D-09 304 SS 1,987 01-14 Dilute HNO3 01-14 Cell Level and density Secondary 500 Containment Solution indicators and hign/ low Storage Tank Cell level alarms SPCCT31C.WP6 17,_

^ WVDP-043 Rev. 4 4 TABLE 3-1 WVDP OIL. HAZAPDOUS SUBSTANCE. HAZARDOUS WASTE STORAGE FACILITIES Nominal i Capacity Contents-(liters) and/or spill Instrumentation Associated i Tenk/ Vessel Construction foallons) Location Function Containment with S0111 Control 6 I (2) DTI, DT2 Carbon Steel 121 01-14 Bldg. Diesel Fuel Overflows back Field a:ocated level j t Diesel Fuel 32 144 ft level to supply tank indf ators j Day Tanks (each) (4th floor) (see Section ) 3.14.3). j. VIT Carbon steel' 28,200 Northwest of Diesel F'zel Concrete berm Hign level alarm Generator 7,450 VIT Building and pad Diesel Fuel i l Tank and Day Carbon steel 758 In VIT diesel In VIT diesel High level elarm ) . Tank-(See 200 generator generator room Section room 3.14.4) j Additional VIT System Tanks and VIT

Pit
Tanks (See Section 3.14.1 and 3.14.5) 61-D-08 304 SS 1,628 VIT Test off-Gas Vit Building None 430 Facility Scrubber Floor I

61-D-07 304 SS 22,710 Outside of West of VF Concrete berm Level gauge ) 6,000 VFT Test and pad ] Facility 1 4 Sca?ed Vitrification System (SVS) III Future Tanks (See Section 3.14.6) l j 61-D-01 304 SS 4.180 VIT Test Melter Feeder In VlT Test High and low level alarm 1,100 Facility Facility i 1 j 61-D-02 Fiberglass 1,722 ' 2 Test Test Slurry In VIT Test High level indicator and j reinforced 450 ,acility Facility alarm i l 61-D-03; and 304L SS 1,900 VIT Test . Nitric Acid for In VIT Test High level indicator and i Day Te-k 304L SS 500 Facility slurry a:akeup Facility alarm j 950 l 250 ? j SPCCT31C.WP6 1R

WVDP-043 Fev. 4 TABLE 3-1 WVDP OIL, HAIAPDOUS SUBSTANCE, HAIAFDOUS WASTE STORAGE FACILITIES Nominal Capacity contents (liters) and/or Spill Instrumentation Associated Tank /Veesel Construction fca11ons1 Locatien_ Function Centain~ nt with Sol 11 Control a 61-D-04 304L SS 950 VIT Test Slurry Feed In VIT Test High and low level 250 Facility Hold Tank Facility indicators, alarms; automatic shutoff VO44T Titanirm 1,672 VIT Test Acidic Solution In VIT Test Level indicator 450 Facility Facility 61-D-06 304L SS 210 VIT Test Slurry Teed In VIT Test High and low level 55 Facility Hold Tank Facility indicators alarms; automatic shutoff Cold chemical Systeg Tanks (see section 3.14.7) 65-D-01 304L SS 41,365 Cold Chem Off-spec Cold Chem Sump alarm l 11,000 Building chemical hold Building Tank 65-D-02 304L SS 21,000 Cold Chem Slurry Hold Cold Chem High level alarm 5,500 Building Tank Building 65-D-03 304L SS 21,000 Cold Chem Slurry Hold Cold Chem High level alarm 5,500 Building Tank Building 65-D-04 304L SS 1,900 Cold Chem Slurry Hold Cold Chem High level alarm 500 Building Tank Buidits 65-D-05 304L SS 5,700 Cold Chem Nitric Acid Day Cold Chem High level alare, visual, I 1,500 Building Tank Building audio 65-D-06 316 SS 1,900 Cold Chem Caustic Day Cold Chem High level alarm, visual, 500 Building Tank Building audio 65-D-07 304L SS 3,790 Cold Chets Decontamination Cold Chem High level alarm, vtsual, 1,000 Building Tank Building audio SPCCT31C.WP6 o

i 1 ~ WDP-04 3 Rew 4 TABLE 3-1 WDP OIL. HAZAFDOUS SUBSTANCE. HAZARDOUS WASTE STOFME FACILITIi3 Nominal capacity Contents (liters) and/or Spill Itetrumentation Associated T*nk/ vessel Construction (callons) Location Function Containment with Spill control 65-D-08 304L SS 950 Cold Chem Decontamination Cold Chesa Wigh level alt.rm, visual, 250 Building Tank Building audio 65-D-09 -304L SS 950 Cold Chere Decontamination Cold Chem High level alarm, visual 250 Building Tank Building audio 65-D-10 304L SS 380 Cold chem Scrub solution Cold Chem High level alarm, visual, 100 Building Tank Building audio Supernatant Treatmenc Svetem (see section 3.15) 50-C-001 - Stainless eteel SD-1 Zeolite II 8D-1, carbon Temperature, pressure 50-C-004 columns steel pon indicators low, high level concrete vault alarms 50-F-001 316 L and 300 SD-1 Prefilter BD-1, carbon Pressure indicators stainless steel steel pan concrete vault 50-F-002 Stainless steel BD-1 Sand postfilter 8D-1, carbon Pressure indicators high steel pan alarm concrete vault 50-E-OO1 Stainless steel 8D-1 Supernatant SD-1, carbon High alarm cooler steel pan concrete vault 50-D-001 Stainless steel 6,435 8D-1 Supernatant 8D-1, carbon Level, density, pH, 1,700 feed tank steel pan conductivity, pressure conrete vault indicatore, high, high alarm 50-D-004 Stainless steel 8,110 8D-1 Supernat.ct CD-1, carbon High, high and low level 2,150 sluice lift steel pan alarms tank concrete vault SPCCT31C.WP6 20

n U U WVDP-043 Rev. 4 TABLE 3-1 WVDP OIL, HAZARDGUS SUBSTANCE. HAZARDOUS WASTE STORAGE FACILITIES Nominal Capacity Contents (liters) and/or Spill Instrumentation Associated Tank / vessel _ Construction foallons) Location Function containment _ with Spill Control 50-D-00S Stainless steel STS Valve Process upset STS Valve AislS High ad low level alarms Aisle safeguard tank sump; drains to 8D-? 50-D-006 Stainless steel STS Valve process upset STS Valve Aisle sight gauge Aisle aafeguard tank ' sump; drains to BD-2 50-0-008 Stainless steel 57 STS OperatinJ Brine solution Concrete berm, Sight gauge 15 Aisle of Sodium operating aisie Nitrate sump; drains to BD-1 50-E-00 Stainless steel 220 STS Operating Brine solution Concrete berm; Pressure gauges 58 Aisle of sodium operating aisle Nitrate sunsp; drains to tank 83-1 35104 (see SA 240/304 L SS 22,000 GCR extension Lcw level waste LWC; sump Level recorder, high and Section 6,000 collection _ tank low level alarms, sump has 3.16.1) high level alarm 70-2 (see S?$ 240/304 L SS 32,220 L1?C Low level waste LWC; sump Level recorder, high and 'ection 8,500 cotlection tank low level alarms, sump has 3.16.2) high level alarm 13-D-8 (see SA 240/304 L SS 2,500 LWC Cell sump LWC; sump Level recorder, indicator Section 660 reciever and high level alarm 3.16.2) I 3-D-2 (see 304 L SS 3,785 LWC St.mple LWC; sump Level recorder, high and Section 1,000 collection tank low le sel alarms 3.16.2) SPCCT31C.WP6 II

WVDP-043 Rev. 4 TABLE 3-1 WVDP OIL, HAZARD 3US SUBSTANCE. HAYARDOUS WASTE STORAGE FACILIT?lS Nominal capacity Contente (liters) and/or Spill Instrumentation Associated Tank / Vessel Construction (callons) Location __ Function Contairment with Sol 11 Control 4-D-8 (see 304 L ss 2,278 LWC Rad. waste LWC; sump Level recorder Section 600 catch tank l 3.16.2) 4-D-10 (see 304 L SS 10,540 LWC PMC and GPC LWC; eump Level recorder Section 3,000 sump collector 3.16.2) l 4-D-13 (see 304 L SS 10,760 LWL Rad waste catch LWC; sump Level recorder Section 3,000 tank 3.16.2) 7-D-8 (see 304 L SS 11,580 LWC Rework LWC; sump ~ avel recorder Section 3,000 evaporator feed tank 3.16.2) Level recorder, alarm 7-D-14 (see 304 L SF 1,979 LWC Hot analytical LWC; sump Section 500 drain tank 3.16.2) 13-D-7 (see 304 L SS 2,599 LWC Rad. waste LWC; sump Level recorder Section 700 catch tank 3.16.2) Tanks with the Vessel off Gas Cell (See Section 3.16.3) 6D-3 304 L SS 858 OGC VOG condensate Leak to OGC None 225 catch tank sump; overflows to 7D-8 6C-3 304 L SS 1577 OGC Demineralizer Leaks to OGC Level indicator 400 rectreulator sump; overflows to 7D-8 SPCCT31C.WP6

o o O WVDP-043 Rev. 4 TABLE 3-1 WVDP OIL. HAZARDOUS SUBSTANCE. HAZARDOUS WASTE STORAGE FACILITIES Nominal Capacity Contents. (liters) and/or Spill Instrumentation Associated Tank / Vessel Construction foallons) Location Function Containment with Solli Control Codium Polyethylene' 5,685 CSS' change Sodium Silicate berm Level indicator Silicate 1,500 room Bulk Storage and Day, Tank Carbon Steel 1,043 None Low level alarm on day tank (see-section 275 3.16.4) e Licuid Waste Treatment System Tanks within the Uranium Process Cell (UPC) (See Section 3.16.5) 5-D-15Al SA 240/304 L SS 38,150 UPC Evaporator UPC, sump Level recorder, indicator, 10,000 concentrates low and high alarms, UPC sump high level alarm, 5-D-15A2 SA 240/304 L SS 18,990 UFC Evaporator UPC, sump Level recorder, indicator, 5,000 Concentrates low and high alarms, UPC sump high level alarm 5-D-15B SA 240/304 L SS 56,950 UPC Evaporator Feed UPC, sump Level recorder, indicator, 15,000 Tank low and high alarms, UPC sump high level alarm i Tanks and Vessels within Extraction Cell fXC3) (See Section 3.16.6) 71-D-001 SA 240/304 L SS XC3 Or snic IX (low XC3; sump Sump high level alarm TLd) 71-D-002 SA 240/304 L SS XC3 Zeolite IX.(low XC3; sump Sump high level a TDS) 71-D-003 SA 240/304 L SS 'XC3 Zeolite IX XC3; sump Sump high level alarm j (high TDS) 71-D-005 SA 240/304 L SS 3,785 XC3 Distillate XC3; sump Sump high level alarm, 1,000 surge level indicators SPCCT31C.WP6 i

O O D WVDP-043 Rev. 4 TABLE 3-1 WVDP OIL. HAZARDOUS SUBSTANCE. HAZARDOUS WASTE STOPAGE FACILITIES Nominal Capacity Contents (lit.ers ) and/or Spill Instrumentation Associated Tank / Vessel Construction (callonel Location Function Containment with Solli Control 71-D-006 SA 240/304 L SS 4,650 XC3 Spent resin XC3; sump Level indicator,' sump high 1,200 receiver . level alaos 71-D-OO7 SA 240/304 L SS' '4,650 XC3 Spent zeolite XC3; sump Level indicator, sump high 1,200 receiver level alarm 71-D-008 SA 240/304 L SS 2,950 XC3 Filter back XC3;. sump Level indicator, high level 800 wash receiver alarm, sump hihg level i alarm 71-D-009 SA 240/304 L SS 380 XC3 Feed sample XC3; sump Level indicator, high fevel 100 tank alarm, sump high level alarm 71-V-010 SA 240/304 ',SS 400 XC3 Low TDS filter XC3; sump Sump high level alarm r ICO 71-D-011 SA 240/304 L SS 380 XC3 Low TDS feed XC3; sump Level indicator high/ low 100 tank alarms, sump high level alarm 31017 SA 240/304 L SS 5,680 XCJ High TDS IC3; sump Level recorder, indicating 1,500 evaporator controller, high/ low alarms, sump high level alarm 14-D-7 (see SA 240/304 L SS 375 LXA Nitric Acid LXA, drains to Level indicator, high level Section 100 interceptor alarm 3.16.7) 14-D-18 (see ~ SA 240/304 L.SS 375 LKA Sodium LIA, drains to Level indicator, high level Section 100 hydroxide interceptor alarm 3.16.7) 4 SPCCT31C.WP6

m, f) (_. WVDP-043 Rev. 4 5 TABLE 3-1 WVDP OIL. HAEARDOUS SUBSTANCE. HATARDOUS WASTE STORAGE FACILITIES i Nominal capacity Contents (liters) and/or spill Instrumentation Associated Tank / Vessel Construction foallons) Location -Function containment with Spill control 70-D-001 304 stainless 1,900 WDC Waete WDC; sump Level recorder,, indicator, (sea section steel (usable) dispensing low, high, high alarms, 3.16.8) 500 vessel temperature indicator, sump has high level alarm 31008 (see SA 240/304 L SS 510 PCR Roof top XC3; sump Level recorder, indicating Section 130 evaporator controller, high/ low 3.16.9) alarms, sump high level alarm SV-1 (see Stainless steel 19,GOG ULO Presently ULO floor Liquid level detection in Section 5,000 contains ULO floor 3.16.10) residual simulated supernatant Low Level Waste Treatme Pacilij;y (See Section 3.17) Pctassium Polyethylene 210 ' .WTF Potassium LLWTF Basilding Level indicator Ferrate Mix 55 Ferrate sump Tanks (2) 33013 Stainless steel 910 LLWTP Acid hold tank LLWTF; building None 250 30% nitric aump Ion Exchange Carbon steel 3,525 In LLWTF Ion excnange LLC F; Building cressure gauges Columns 101 polylined each Building co'*_- es for sump; and 102 1,000 psocess wastewater Trench Interceptor Proiect (TIP) Pretreatment Tanks (See Section 3.18) 82-D-01 Carbon steel 3,790 TIP Bldg. Physical Containment Low and high level 1,000 separation basin alarms indicators, (remote and tanks of local, visual and audio) recovered automatic shutoff switches groundwater SPCCT31C.WP6 .. E.. J

f .f^. .f\\. WDP-04 3 Rev. 4 TABLE 3-1 WDP OIL, ifAZARDOUO SUBSTANCE. HAZARDOUS WASTE S_TORAGE FACILITIES Nomir.al Capacity Contents (liters) and/or Spill Instrumentation Associated Tank / vessel Construction foallons) Location Function Containment with Spill Control 82-D-02 Carbon steel 3,790 TIP Bldg. Physical containtent Low and high level 1,000 separation basin alarms indicators, (remote and tanks of local, visual and audio) recovered. automatic shutoff switches groundwater 82-D-03 Carbon steel 18,950 TIP Bldg. Pretreatment Containment Low and high level 5,000 Feed Tank basin alarms indicators, (remote and local, visual and audio) automatic ehutoff switches 82-D-04 Carbon steel 3,790 TIP Bldg. Post Treatment Containment Low and high level 1,000 Hold Tank basin alarms indicators, (remote and i local, visual and audio) l automatic shutoff switches 82-D-05 Carbon steel 3,790 TIP Bldg. Post Treatment containment Low and high 72 vel i 1,000 Hold Tank basin alarms indicators, (rtmate and local, visual and audio) automatic shutoff switches 82-C-01 Carbon steel 2,653 TIP Bldg. GAC Filter Containment Pressure gauge 700 basin i 82-C-02 Carbon steel 3,790 TIP Bldg. GAC Filter containment Pressure gauge j l 1,000 ba sir. I f Transfer (2) poly-757 Portable Temporary None, used only Visual level indicator i tanks (3) ethylene 200 transfer of for transfers (see Section (each) niecellaneous I 3.19.1) (1) 304 1900 liquids stainless 500 steel l l l l SPCCT31C.WP6 n

MMMI Jm O O O WVDP-043 Fev. 4 i TABLE 3-1 WVDP OIL, HAZARDOUS SUBSTANCE, HAIARDOUS WASTE STORAGE FACILITIES Nominal Capacity. Contents (liters) and/or Spill Instrumentation Associated Tank / Vessel Const ruct ion toallons) Location Function Containment with Spill Cont rol Diesel fuel carbon steel 1,136 Portable Diesel fuel, Carbon steel None tank 300 (filled from refuels air pan constructed (portable) underground compresseor and around tank tank; trans-fire pump (see section 3.19.2) ported to area south of UR) URF Carbon steel, 1,098 Utility room Fuel oil No. 2 UR floor drains Float level gauge l 48066-A (see on concrete 300 (to interceptors) Section saddles 1 3.19.3) l l 7C-5 (See 304 L SS 7580 Acid recovery Low level ARC cells; sump Level indicator and j recorde_ Section 2000 cell wastewater J 3.19.4) 7D-1 (See 304 L SS 6876 Extraction empty; formerly XC1 cell; sump Tagged out of service Section 1800 Cell I contained high level 3.19.5) wastewater Tanks Located Within the Waste Tank Farm Shelter (See Section 3.19.6) BC-1 Carbon Steel 2,650 WTF shelter Con. Ed. off-WTF shelter High, low level alarms l 700 gas caustic overflow to scrubber Tanks 8D-6 SD-6 Carbon Steel 1,893 WTF shelter Off-gas KO pot WTF shelter Hich level alarm overflow to 500 Tanks BD-1 or BD-2 SPCCT31C.WP6

O WVDP-043 I Rev. 4 i i TABLE 3-1 WVDP OIL, HAZARDOUS S*JBSTANCE. HAZARDOUS WASTE STOFAGE FACILITIES Nominal Capacity Contents (liters) and/or Spill Instrumentation Assoclated Tank / Vessel Construction LClallons) Location Function containment with Spill control 1 4' l l BD-7 Carbon Steel 950 WTF shelter Off-gas relief WTF shelter Level indicator l l 250 tank overflow to Tanks BD-2 Zine Bromide Shield Windows (See Section 3.19.7) Scrap Rectangular 360 SR Zinc bromide WHOA floor to N/A (level visible) removal glass plates 100 pit for condensate window gasketed into carbon steel pumps frames Mechanical Rectangular 340 Analytical Zine bromide Down stairs to N/A (level visible) l crane room glass plates 100 aisle GOA floor, to GOA sump window gasketed into carbon steel frames (5) Analy-Rectangular 340 Analytical Zine bromide ANA floor N/A (level visible) tical cell glass plates 100 aisle (floor drains covered) Windows gasketed into carbon steel frames FPH Carbon steel 1040 Fire pump Fuel oil No. 2 Pump house Float level indicator Fire puep 275 house floor day tank (see Section 3.19.8) SDT Carbon steel 380 STS generator Diesel Fual Generator room Float level indicator floor STS day tank 100 room (see Section 3.19.9) SPCCTJlC.WP6 28

m '~ - WVDP-043 Rev. 4 TABLE 3-1 WVDP OIL, ifAZARDOUS SUBSTANCE, HAEAPDOUS WASTE STORAGE FACILITIES Nominal Capacity Contents (liters) and/or Spill Instrumentation Associated Tr.nk/Ves1el ConJtruction-foallonel Locatico Function containment with Soill Control Rsceiving Steel 170 Receiving Segregated Built-in spill None Warchouse '45 Warehouse cabinets of basin - 2* sill Flcmmable

paints, Storage thinners, acide Cabinets _(7)

(son Section 3.19.10)- New Main Concrete 6537 West of 5 segregated Containment None Warehouse 1800 ea. Receiving rooms for basins beneath (see Secticn room's Warehouse oxidizers, steel grate 3.19.11) spill flammables, floors contain-' corrocives, ment acids amid volume health hazards Cargo Unit Wood and Steel South and 55 gal drums, 8' x 40' cargo None Trailer Body west of 5 gal palls of trailer (see Section Warehouse oils and 3.19.12) greases Hazardous Various Temporary Various methods None Waste locctions storage of satellite hazardous Accumulation wastes at or Areas (see near the point Section of generation 3.20) Interim Pre-engineered 21,650 at the NDA, Temporary Bermed concrete None Waste metal b1dg. 34' 5,700 of southeast of storage of floor Storege x 34'

bermed, the Hain wastes prior to Facility secondary Plant

chemical, (IWSF) (see contain-radilogical Section ment characteriza-3.21) capacity tion SPCCT31C.WP6

't@

I WVDP-043 Rev. 4 TABLE 3-1 WVDP OIL, HAZARDOUS SUBSTANCE. HAZARDOUS WASTE STORAGE FACILITIES Nominal Capacity Contents (liters) and/or Spill Instrumentation Aseociated Tank / Vessel Con st ruct ion faallonel Location _ Function Containment with Spill Control Hazardous 4758 East of STS 4 separate Built-in spill Audio, visual alarms l 1265 each Building locker basin 10% of Waste Lockers locker containing total volume 2-Non-contain-hazardous and non-hazardous flarimable, ment solid and 2-Flammable liquid wastes (see Section 3.22) I Portable Carbon steel 3790 Various Tereporary Contained in None Holding 1,000 locations storage steel boxes when necessary Tanks (see Sec.t ion 3 '!3 ; l l U neral Oil 3ectangular 285-417 Various Mineral oil Witnin main N/A Level visible l l Windows (See Glass Plates 75-110 loca* tons plant building l Section gasketed into 3.24) carbon steel frames Waste Tank Vendor tank 17,000-North of the caustic soda 10' x 10' port-None 8D-2 Caustic 18,500 high level a-berm, 7000 Trancter 4500-5000 waste tanks gallon capacity inflatable berm Staging Area if necessary (See Section 3.25) First floor Special nuclear REM room floor None RAM Equiprnent of main plant materials drains to west of FRS interceptcre Rocs (REM) (See Section 3.2E) SPCCT31C.WP6 3D

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} WVDP-043 g t 5 Rev. 4 LJ The fuel oil tank supplies fuel to the boilers in the Utility Room (UR) via underground pipes and the diesel blower fuel tank in the 01-14 Building via hard piping. (The boilers are normally fueled by natural gas.) In normal operations, the spill basin collects rainwater and discharge from the internal steam heating system. The basin cate valve is closed except wnen collected water is being drained from the basin. Before the basin is drained, standing liquids are first examined for surface sheen to make sure they do not contain oil. The liquid (rainwate 7 sampled and released per SOP 15-51, allowing the collected to drain into the Utility Room (UR) drainage ditch. 3.1.4 Spill Containment The fuel oil tank is mounted on concrete pedestals within a diked earthon spill basin. This basin is a depression in the ground surface capable of holding a volume of 84,740 liters. Upgrades to this basin completed in FY 1989 included excavating and berming to provide a containment capacity of approximately 110 percent of the tank capacity. ( ('N 3., 2 Tank 14D-1 L) 3.2.1 Construction Tank 14D-1 is a stainless steel vessel 4.1 m in diameter by 3.7 m high, with a capacity of 45,300 liters. It 19 situated on a concrete pad and is enclosed within a " pill basin that drains to the interceptors in the LLWTF system. All' piping and fittings are welded stainless steel with stainless steel nuts and bolts. The pumn connection flanges contain stainless steel-wound teflon gaskets with stainless steel nuts and bolts. The pump is a stainless steel wetted surfaces pump suitable for high concentrations of nitric acid. Its electrical service is conduit that is outside the spill basin, with an acid resistant rubber electrical cord from the bottom of the switch to the pump. The switch is mounted on a painted steel pedestal three feet above the floor of the spill basin. 3.2.2 Instrumentation Tank 14D-1 is equipped with a level indicator, which consists of a float connected by a cable to an indicator bar that reads out against a calibrated gauge. (~N b LEWO234.WP6 33

l WVDP-043 Rev. 4 3.2.3 Operation Tank 140-1 is currently out of service. There is no existing discharge line from the discharge pump and the tank is empty. 3.2.4 Spill Containment Sse section 3.3.4. 3.3 Caustic Tank 14D-2 and Caustic Day Tank 14D-2A 3.3.1 Construction The caustic storage tank (14D-2) was formerly used for the storage and distribution of concentrated (50 percent) sodium hydroxide. The cauntic day tank (14D-2A) was formerly used to make up dilute (25 percent) caustic that was used for pH control in the interceptor. Tank 14D-2 has a capacity of 45,500 liters, and Tank 14D-2A has a capacity of 1,900 liters. Both tanks are of carbon steel and were provided with steam heat via internal coils to maintain the viscosity of the solution. 3.3.2 Instrumentation Tank 14D-2 is equipped with level indicator and temperature gauges. A temperature gauge capable of measuring from 0 to 250 degrees F is mounted approximately 30 cm up from the base of the tank. Tank 14D-2 is also equipped with an automatic control valve that controls the flow of steam through the internal steam coil to maintain the vessel temperature at 100 F. Tank 14D-2A is also equipped with level and temperature indicators. The level indicator is an air-purged dial instrument mounted on top of the tank. The temperature indicator its identical to the one on Tank 14D-2. Tank 14D-2A is also equipped with a temperature control valve. 3.3.3 Operation Both these tanks are out of service. The filling of Tank 14D-2 was conducted in accordance with SOP 14-1, "Recaipt and Distribution of Bulk Liquid Chemicals." This is the same procedure mentioned in section 3.2 for the nitric acid storage tank. The transfer of material to Tank 14D-2A, to the neutralizer pit, and to the LLWTF are described in SOP 02-1, " Low-Ievel Waste Treatment Cold Chemical Makeup," and SOP 15-13, " Interceptor Operation." O LEWO204.WP6 34

4_]/ ( WVDP-043 Rev. 4 3.3.4 Spill Containment Tanks 140-1, 14D-2, and 14D-2A are located in close proximity to each other and utilized a common transfer station but separate lines for filling. These tanks were originally on a common spill pad, consisting of a concrete mat surrounded by a concrete curb 15 cm high. Separate drains were provided for_the two halves of the pad. The drains are routed to the LLW basins. The tanks were elevated several inches above the pad on concrete pedestals. The pad has been refurbished and upgraded to provide separate epill basins, one for 140-1, and one for 14D2 and 140-2A. Currently, the caustic tanks are separated from the 14D-1 tank by a concrete curb and splash barrier. The separate spill basins are each capable of retaining approximately 2,000 liters, which would be sufficient to contain small spills or slow leaks. (These basins would not be adequate to contain the volume of either tank in the event of a rapid release of material from a major leak.or catastrophic failure of the tank.) Larger -containment capacity is provided by the interceptors, which receive all runoff and rainwater from these basins via the floor drains and sump drains in each basin. ' [] Fill lines to the storage tanks (140-1 and 14D-2) are located N outside the containment area. There is one line for each tank from the elevated platform alongside the rail"ond, and one for each tank.for unloading frcm a truck. The fill lines enter the tank at a point above the over. flow line. The caustic day tank is filled from the caustic storage tank, with all piping inside the containment. Each of these vessels also has an overflow line that is routed l into a concrete enclosure at the base of the tank. Splash-control concrete curbing is provided at the bane of 14D-1 for that tank and at the base of 14D-2 for that tank and 14D-2A. The caustic tanks are equipped with internal steam coils. o Condensate from the steam is discharged to the overflow drains, which are routed to the interceptors. If any leaks were to occur in'the-heating coils, the caustic could become contaminated with water, but would be contained within the LLWTF system. 3.4 Gasoline Storage Tanks 3.4.1 Construction Two underground gasoline storage-tanks and one underground diesel l storage tank are located at the haristand across from the ("] warehouse. Each tank has a capacity of 7,500 liters and is made \\_/ of carbon steel. These tanks were installed in January 1985. The tanks are strapped to a concrete ballast, and are provided I LEWO204.WP6 35 9

WVDP-043 i Rev. 4 with a bitumastic coating. All excavation around the tanks was backfilled with sand. Pumps for each tank are installed directly above the tanks, and fill pipes are located at grade. The fill pipes are color-coded to indicate the contents of the associated tank. 3.4.2 Instrumentation Thes2 tanks are not equipped with instrumentation. Inventory records are maintained by warehouse personnel to track current volumes. A monitoring well installed in the backfill is sampled quarterly for petroleum contamination. 3.4.3 Operation Gasoline and diesel fuel are supplied to these tanks by an off-site vendor. The fuel delivery person refills the storage tanks using valves and hoses which are part of the vendor tank truck equipment. The tanks are refilled usually every two to three weeks, depending on usage. Fuel is pumpcd from the tanks through a metered dispensing pump with a standard hose and nozzle. Access to the pumps is limited. Keys to locks are controlled by warehouse personnel and the security force. 3.4.4 Spill Containment The gasoline and diesel fuel tanks are buried within silty till below alluvial fan surface material. The silty till is ver impermeable (hydraulic conductivity on the order of 1 x 10'y cm/sec) and is acceptable as a containment barrier for underground petroleilm storage tanks, per criteria listed in 6 NYCRR 613, "Undergtvund Petroleum Etorage Facilities and Minimum Standards." The alluvial fan material, although more permeable than the till, is sufficiently " tight" to retard fuel migration long enough to allow its detection (via inventory and monitoring data) and effect its recovery. 3.5 Sulfuric Acid Tank 35157 3.5.1 Construction The concentrated sulfuric acid tank is a molded polyethylene tank with chlorinated polyvinyl chloride or stainless steel piping and fittings. The tank has a capacity of 11,000 liters. It is located on a concrete pad within the concrete spill basin immediately south of the LLUTF (02) t,uilding. The tank is held in place by cables anchored with eye bolts into the spill basin pad. LEWO204.WP6 36

(~ WVDP-043 (_,g )- Rev. 4 3.5.2 . Instrumentation The sulfuric acid tank is equipped with a calibrated level gauge strip adhered.to the side of the tank. The tank walls are translucent and the level of the contents is readily observable. 3.5.3 Operation The sulfuric acid storage tank is operated in accordance with SOP 02-2, " Ion Exchange Bed Operation," and SOP 1441, Receipt and Distribution of Bulk Liquid Chemicals." 3.5.4 Spill Containment The concentrated sulfuric acid storage tank is located on a curbed concrete spill containment pad adjacent to the LLWTF building. The capacity of this spill basin is epproximately one third that of the tank, but the basin is equipped with a drain to the LLWTF process sump, which overflows to Lagoon 2. This would prevent an off-site discharge. 3.6 STS Bulk Underground Fuel 01.'. Tank !O 3.6.1 Construction V The STS bulk fuel oil tank is a carbon steel, double walled undarground tank with a bituminous coating. The tank is located to tae northwest of the Supernatant-Treatment System Ventilation Building. It has a capacity of 2,100 liters. The tank is used to store diosel fuel for emergency power. ~ 3.6.2 Instrumentation This tank is equipped with a leak detection conductivity probe in the annular space between the tank walls. The sensor indicators are located in the Perma int Ventilation System Building and an alarm annunciates in the TS control room if the sensor detects hydrocarbons. The monitoring system is checked annually by WVNS maintenance. 3.6.3 Operation The' diesel _ fuel is only needed in emergency conditions. The level is routinely checked by Operations personnel prior to use. The tank is supplied and refilled by an off-site vendor. 3.6.4 Spill Control (")% The tank is stamped with the manufacturer's confirmation that it (_ conforms with "6 NYCRR Part 615", thus indicating that the tank, welds, seams, and connecting fittings have been factory tested LEWO204.WP6 37

WVDP-043 Rev. 4 for tightness using standard engineering practices. It also requires that the tank is sufficiently protected against corrosion, and has some means of secondary containment (in this case the double-walled structure of the tank serves as secondary containment). ~ 3.7 High Level Waste Tanks 80-1 and 8D-2 3.7.1 Construction High level waste (HLW) tanks 8D-1 and 8D-2 are carbon steel and located in adjacent waterproofed, reinforced, underground concrete vaults (the tops of the vaults are 2.4 m underground) in the highly impermeable silty till characteristic of the area. Each tank has a capacity of 2.8 million liters and rests on a 30 cm layer of perlite blocks, which is on 7.6 cm layer of pea gravel in a carbon steel pan 23 m in diameter and 1.6 m in height, within the concrete vault. The pan reuts on a second 7.6 cm layer of pea gravel on the vault floor. The vault pad is 69 cm thick, with a thicker ring under the columns that support the vault roof. The vault pad rests on a 10 cm leveling slab. Under the concrete vault is a 1.2 m layer of pea gravel that is kept saturated with water to prevent effects of distortion of the silty till. 3.7.2 Instrumentation Tanks-8D-1 and 8D-2 are equipped with level, pressure, and temperature indicators. Pressure indicators are located in the tanks, and level indicaters are in the pan. 3.7.3 Operation Operation of the HLW tanks system is governed by SOP 8-01. Various SOPS govern the operation cf waste tank farm support systems. Tank 8D-2 contains approximately 2.3 million liters of neutralized HLW sludge and supernatant that resulted from the PUREX process that NFS used (the composition of the PUREX supernatant is provided in Table 3-2 and the composition of the PUREX sludge is provided in Table 3-3). Measured variables are monitored and recorded once per shift. Tank 8D-1 contains zeolite columns used in stripping radioactive cesium from the supernatant. All interconnecting pipes and support systems are double contained. 3.7.4 Spill Containment The HLN tanks are provided with secondary containment consisting of a carbon steel pan celow each tank, a reinforced concrete vault surrounding each tank and pan, and highly permeable, h LEWO204.WP6 38

-l WVDP-043 Rev. 4 Table 3-2 PUREX Supernatant Chemical Composition -i Total kg. Comnound in suoernatant t NANO 602,659 3 NANO 311,326 2 Na2SO 76,261 4 NaHCO 42,557 3 3 KNO 36,274 Na2CO 25,249 3 NaOH 17,537 K CrO 5,113 2 4 Nacl 4,684 Na3PO 3,799 4 'Na2Mo 691 a f-Na3 SO 597 3 ( CsNO. 534 3 NaF 503 Sn (NO ) 4 245 3 Na2U 07 231 2 Si(NO )4 -230 3 NaTcO 177 4 RbNO 119 3 Na2TeO 82 4 AlF 77 3 Fe(NO )3 43 3 Na2SC0 15 4 LINO 14 3 H CO 9 2 3 Cu(NO )2 6 g Sr(NO )2 4 Mg (NO ) 2 -lil 3 TOTAL 1,129,038 HO (by difference) 1,727,164 2 NOTE: pH = 10 39

WVDP-043 Rev. 4 Table 3-3 PUREX HIGH-LEVEL SLUDGE SOLIDS CHEMICAL COMPOSITION Comoonent Reference (> sat Fe(OH)3 66,040 FePO 6,351 4 Al(OH)3 5,852 AlF 536 3 Mno 4,581 p CACO 3,208 3 UO (OH)2 3,087 2 Ni(CH)2 1,088 ~i 1,263 2 2,_- ( OH ) 4 159(a) MgCO3 826 Cu(OH)2 376 Zn(OH)2 128 Cr(OH)3 65 Hg(OH)2 23 Fission PI,oducts F.P. hydroxide 1,485 R.E. hydroxide 1,484 F.P. hydroxides 520 Transuranics NpO2 42 Puo 37 2 AmO 27 2 CmO 0.3 2 Total 97,178 (a) Excludes fission product zirconium 40 0

WVDP-043 ( Rev. 4 saturated silty till surrounding the vaults. The pan under each tank contains a-level indicator and high-level alarm that would detect leakage from groundwater, the storage tank, or the transfer piping. Each tank vault complex includes five 20 cm diameter standpipes positioned around the outside of the vault. These standpipes extend into a layer of gravel which is below the vault foundation, and can be used to monitor groundwater around -the vaults. In addition, the gravel around the vaults is saturated with water so that any leakage through the vault would be into rather than out of the vault. 3.8 Tanks 8D-3 and SD-4 3.8.1 Construction Tanks BD-3 and 8D-4 are located in a single reinforced underground concrete vault with outside dimensions of 9.8 m by 5.8 m by 7.7 m high. The vault is surrounded by silty till and covered with an earth layer approximately 2.4 m thick. The vault is lined to a height of 46 cm with stainless steel, which forms a pan, which is equipped with a sump. The storage tank (8D-4) and its spare (BD-3) are similar in construction and instrumentation. The tanks are composed of 304 and 304L stainless steel and have a fs nominal capacity of 57,000 liters. They were designed for a (j working volume of 51,000 liters (90 percent of nominal capacity). Tank 8D-4 presently contains about 45,000 liters of acidic thorium-bearing waste called THOREX. The componition of the THOREX waste is provided in Table 3-4. To maintain the solution temperature below 60 degrees C, each tank has two side-mounted cooling coils and one bottom cooling coil, with a total heat removal capacity of about 600,000 Btu /hr. l The coils are 3.8 cm, seamless stainless steel. The temperature l of the-stored THOREX waste is controlled nianually by adjusting l the cooling water flow.to the cooling coils. At present, partial flow through the bottom coil alone is adequate to maintain the i temperature at 37.8 to 48.9 degrees C. l 3.8.2-Instrumentation Each tank is equipped with pressure and level indicators and alarms, and the stainless steel pan in which both tanks are situated is equipped with an alarmed sump. The level in Tank l BD-3 can be read in the STS Control Room and the Waste Tank Farm j (WTF) shelter. l l 3.8.3 Operation Tank 8D-3 is used as a holding tank for supernatant that has been (_ processed through the zeolite system in the neolite system in l s Tank 8D-1, prior.to being transferred to Tank 35104. The l l I2WO204.WP6 41 l l

WVDP-043 Rev. 4 Table 3-4 -THOREX Waste Chemical Composition A. Solution Comoound Maris (kal Comoound Mass (kol Th(NO ) 4 11,633 NaTcO 12 3 4 Fe(NO )3 8,462 Sm(NO )3 14 3 3 Al(NO )3 4,175 Zr(NO )3 12 3 3 HNO 2,129 Y (NO ) 4 11 3 3 Cr (NO ) 3 1,918 Rh (NO ) 4 11 3 3 Ni(NO )2 791 Zn(NO )2 10 3 3 H B0 480 Pd (NO ) 2 8 3 3 3 NANO 227 UO (NO ) 2 6 3 2 3 Na2SO 180 RbNO 6 4 3 KNO 128 NaTeO 5 3 4 Na2SiO 126 Co(NO )2 3 3 3 KMnO 122 Na2SeO 1 4 4 Mg (NO ) 2 57 NaF 1 3 Na2 moo 54 Eu(NO ) 3 1 4 3 Nacl 50 Sn(NO )3 0.9 3 Nd(NO )3 46 Cu (NO ) 2 0.8 3 3 Ce(NO )4 43 Pu(NO ) 3 0.7 3 3 Ru(NO )4 42 Gd (NO ) 3 0.3 3 3 Ca (NO ) 2 30 X* (NO ) 4 0.3 3 3 CsNO 28 Cd(NO ) 2 0.3 3 3 Ba(NO )2 27 Sb(NO )3 0.1 3 3 La (NO ) 3 22 AgNO3 0,1 3 Pr(NO )3 21 In(NO )3 0.04 3 3 Sr(NO )2 16 Pm (NO ) 2 0.02 3 3 Na3PO 12 4 TOTAL 43,587 H 0(by diff) 12,663 2 B. Solids Th (NO ) 4 19,421 3 INsolubles 35

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i WVDP-043 ( Rev. 4 transfers are performed by Operations personnel according to S ope.. Measured variLbles are monitored and recorded once each shi... 3.8.4 Spill Containment If a spill or leak were to occur in either tank, the contents would enter the stainless steel pan, which is equipped with an alarmed sump. In addition, the concrete vault provides tertiary containment of the pan and tank. In addition, the vault is surrounded by highly impermeable saturated silty till, which would prevent leakage out of the vault. 3.9 Interceptors and Neutralization Pit 3.9.1 Construction The north and south interceptors and the neutralization pit are each constructed of reinforced concrete lined with stainless steel. The neutralization pit has a capacity of 1,900 liters; the north and south interceptors each have a capacity of 87,000 liters. ("] In addition, the old interceptor is constructed of reinforced (_j concrete. It has a capacity of 56,850 liters. All these facilities are located to the east of the process building. 3.9.2 Instrumentation The north and south interceptors are equipped with high-level alarms that signal in the UR. 3.9.3 Operation The neutralization pit is used to measure the pH of low level waste from plant drains, sumps, etc., before transfer to one of the two new interceptors, there it is held for sampling. From the interceptors, the waste is transferred to Lagoon 2. From Lagoon 2 it is pumped to the Low Level Waste Treatment (LLWT) plant, where it is treated. SOP 15-1 and 15-13 contain the procedures for the operation of this system. Waste streams which may be over the specified limit for release from the interceptor are diverted directly to the old interceptor. From there they are sampled and transferred, in batches, to one of the new interceptors. A/ l LEWO204.WP6 43 1

WVDP-043 Rev. 4 The old interceptor effluent volume is normally checked once a shift (three times a day). Records of volume measurements are maintained by Main Plant Operations. 3.9.4 Spill Containment There is an overflow connection between the north and south interceptors. Should one become too full, it would overflow into the other. In addition, if one of the intercoptors became full, the high-level alarm would sound in the UR. 3.10 Manipulator Repair Shop Waste Catch Tank 15D-6 3.10.1 Construction Tank 15D-6, the waste catch tank for the manipulator repair shop, is a 5,700-liter underground stainless steel tank. It measures 1.8 m in diameter by 2.4 m high. It is located directly to the east of the contact size reduction facility. 3.10.2 Instrumentation Tank 15D-6 is equipped with a level recorder and a high-level alarm. A stainless steel monitoring well is installed adjacent to the tank. 3.10.3 Operation Tank 15D-6 receives radioactive waste waters from the manipulator repair shop, contact size reduction facility, and head end ventilation system. Wastewater collected in this tank is sampled via an installed sampler. Transfer of wastewater to Tank 8D-2 is possible, if necessary. Main Plant Operations is responsible for monitoring and operation of this tank. Operations are control. led by SOP 7-08. 3.10.4 Spill Containment This _s an underground tank, but otherwise has no associated spill containment provisions. 3.11 Low-Level Waste Catch Tank 7D-13 3.11.1 Construction Tank 7D-13 is an underground tank located southwest of the process building. The tank is constructed of 304L stainless steel and has a 7,500-liter capacity. It measures 1.4 m in diameter by 4.1 m long. O l LEWO204.WP6 44

.(~] WVDP-043 (,j Rev. 4 3.11.2 Instrumentation Tank 7D-13 is equipped with a level recorder and high-level alarm. 3.11.3 Operation Tank 70-13 receives low-level radioactive solutions from the Analytical and Process Chemistry Laboratories drains and drum flush solutions from the Cement Solidification System (CSS). Waste waters collected in this tank are routed to the LLWTF interceptors. 3.11.4 Spill Containment Tank 7D-13 has no associated spill containment provisions. However, it is located within a confined area bounded on two sides by the-process building, on the third by Building 01-14, and on the fourth by the off-ga; trench. Thus, any leak would be contained in a relatively small area long enough to offect a cleanup. 3.12 Low-Level Waste Treatment Facility Outside Tanks There are four LLWTF outside tanks, namely: 48070 -- Flocculator/ Clarifier 48091 - Clarified Water Filter l 35105 - Clarified Water Surge Tank 33012 - Recycle Tank These tanks _ range in size from 3,500 liters to 64,500 liters. 3.12.1 Construction l These tanks are constructed of stainless steel and are supported i either on concrete pedestals or carbon steel legs. Each of these tanks is' located within a-curbed spill pad. 3.12.2 Instrumentation Automated instrumentation controls plant flow rates to these tanks, appropriate influent and offluent pH adjustmer.ts, tank levels, and line pressure. Alarms are installed on these process L tanks to indicate high or low levels. These alarms signal at the l LLWTF. LEWO204.WP6 45

WVDP-043 Rev. 4 l O 3.12.3 Operation The operation of the LLWTF is the responsibility of Main Plant Operations. These operations are conducted in accordance with SOPS 02-01 through 02-08 and 02-11. The flocculator/ clarifier receives LLW water from Lagoon 2 and potassium ferrate solution, caustic, and polyalectrolyte. These additives form a floc with particulates in the wastewater and the floc settles to the tank bottom where it is extracted for dewatering in the centrifuge: The clarified water is transferred to Tank 35105 and then to the clarified water filter (48091) for additional cleanup prior to ion exchange. Off-specification treated wastewater and other waste solutions from the treatment process are routed to Tank 33012, the recycle tank, for reintroduction to the system. 3.12.4 Spill containment All four of these tanks are located on a curbed concrete pad. This pad has a sump which overflows to Lagoon 2; thus, if any tank were to spill or leak, the spilled material would be collected in Lagoon 2. 3.13 Waste Oil Collection Tank 3.13.1 Construction The Waste 011 Collection tank is 660 liters in capacity and is constructed of carbon steel. 3.13.2 Instrumentation l l This tank is not equipped with any level indication instrumentation, j 3.13.3 Operation Waste lubricating oils are temporarily stored in the IWSF, pending chemical (TCLP) and radiological release limit analyses. Following determination that they meet chemical and radiological regulatory limits, they are placed in the collection tank. Waste Management Operations arranges with a spent-oil recycling company to collect the contents of this tank on an as-needed basis. 3.13.4 Spill Containment The waste oil accumulation tank is completely contained inside a steel box that is lined with Herculite. The box is covered to preclude accumulation of rainfall. LEWO204.WP6 46

WVDP-043 Rev. 4 3.14 Future Vitrification Facility Tanks l 3.14.1 Tanks to be Located Within the Vit"itication Facility Pit fi The Vitrification Facility (VF) pit measures 15.2 m x 11.6 m x 4.3 m deep. It is constructed of concrete, lined with stainless steel, and is equipped with a sump with level indicator and alarm. The sump level indicator is located on Instrument Rack 1C in the VF nor*:'a aisle, 100 ft level. In addition, an audible high levul al 'ra is located on the alarm panel on Instrument Rack 6 in the norta aisle, 110 ft level. This elarm is also tied into the VF trouble alarm located on the alars p;11 in the East Mechanical operating Aisle of the process '+.,lding. Tanks to bu located within the VF pit include: o Molter Feed Hold Tank (63V-11) o Concertrotor Food Makeup Tank (63V-01) o Submerged Bed Scrubber /Roceiver (63V-031) Tanks 63V-11 and 63V-01 will hold simulated HLW and various glass formers of the goveral composition identified in Table 3-5. Tank 63V-031 collects solution from the aqueous quenching / scrubbing of G the molter off-gas. This is primarily a nitric acid solution with minor amounts of particulato. If any of these tanks should overfill, the contents would be conta ir.ad within the pit and the pit sump high-level alarm would activate. If the pit sump high-level alarm activated, the audible alarms on the north aisle 110 ft level in the VF and the VF trouble Alerm in the East Mechanical operating Aisle of the process building would sound and cause operations personnel to respond and investigate. If the pit sump should become full, a portable pump and hose would be ucci to empty the surp into a tank or vessel that would be designatti by the Vitrification operations supervisor. 3.14.1 Tanks ar.d Vessels in 01-14 Building Containment Cell The 01-14 Building Containmer.t Cell is constructed of concrete walls lined with stainless steel and has a capacity of 9,700 liters. The cell houses the following vessels: o Primary Surge Tank (64D-01), o Primary storage Tank (64D-05), o Secondary Surge Tank (64D-03), and o Secc ndary Storage Tank (64D-09). O LFWO204.WP6 47

WVDP-043 Roy. 4 Table 3-5 gr?! CAL MELT Q _ TEED H'CROXIDE SL"RPf Chemicals _t__in Feed Mixture Aluminum Hydroxide 5.92 Sodium Tetraborate 20.82 Barium Hydroxide 0.06 Calcium Carbonate 0.18 Carium Hydroxide 0.66 Chromium oxide 0.13 Cesium Hydroxide 0.09 Terrie Hydroxide 12.24 Potassium Hydrexide 3.36 Lanthanum to 0.03 Lithium Hyo.z ide 6.88 Magnesium Hydroxide 0.91 h Man 6anese Dioxide 0.94 Sodium Pydroxide 5 30 Neodymium oxide 0.13 Nickel Hydroxide 0.24 Sodium Phosphace 3.11 Sodium Sulphace 0 32 Silicon Dioxide 29.17 Strontium Hydroxide 0.02 Titanium Dicxide 0.60 Y::: 2m oxide 0.02 Zir ilum Nitrace 3.89 So ium Molybdace 0.05 l Copi ir Hydroxide 0.06 Zinc xide 0.02 Zoolice (IE.95) 4.84 RLC3404: ENG-47 48

O WVDP-043 Rev. 4 These tanke are currently empty and are scheduled for removal. They are not scheduled for reuse. However, these tanks ara hard-piped and potentially functional. These tanks formerly contained the vaste solutions from aqueous scrubbing of NOx-laden off-gas from the Vitrification System. The solution was primarily composed of dilute nitric acid and s.nall amounts of hydrogen peroxide. All four tanks are equipped with lovel and density indicators, wnich are located on the south wal) of the second floor cf the 01-14 Building. Level and temperature indicators can also be accessed-from the Distributed Control System (DCS). If a tank overfilled, tne contents would back up into the vent line to either the primary or secondary scrubber column. The primary column has a capacity of 4,920 liters, and the secondary column has a capacity of 3,255 liters. A high levn1 in any of the tanks would activate an audible and visual alar 1 on the DCS. If_the containment cell sump became full, the conteats vould be sampled. The sump in equipped with a steam eductor to jet the contents to the interceptors. 3.14.3 Diesel Fuel Storage Tanks T,cated in the 01-14 Duilding Two 121-liter diesel fuel day tanks are located in the 01-14 Building-on the 144 ft level. Both tanka are of carbon steel and measure 0.4 m in diameter by 0.9 m long, and are. equipped with level indicators. One supplies fuel to the CSS blower. The other supplied fuel to the vitrification blower, but is now drained and isolated. It.will function as originally designea when vitrification operations resume. The CSS tank operation is controlled by CSS operating procedures. The blower system is tested gaarterly for operability per Operational Safety Requiremvat OSR/TR-GP-5. Fi)' 'ag of the vitrification tank _is governed by the "Intag"sted Opetawien of component Test Stand and off-Gas Equipment Run Plan." The level of the tank is recorded in the vitrificatiu. l operations logbook and associated data sheets. During blower operations, the tank level is checked every four hours and recorded on the appropriate data sheet. The tanks are designed so that if overfilling occurred, the fuel vould recycle back to the diesel fuel supply tank. LEWO204.Wl'6 49

WVDP-043 3.14.4 Generator Diesel Fuel Tank and Day Tank A 28,200-litor fuel tank (FoD-11) will be located aboveground northwest of the Vitrification Building. It will supply diesel fuel to the 758-liter day tank (FOD-12) within the diesel generator room of the Vitrification Building. The diosul fuel will be used to operate the generator as a backup source of power to the Vitrification Duilding in the event of an electrical power outage. Tank FOD-11 will be constructed of carbon steel and situated on a concreto pad within a concreto berm capable of contining greater than 110 percent of the volume of the tank. The tank will be equipped with a high-level alarm to prevent overfilling. Tank FOD-12 will be constructed of carbon stoel and located within a spill basin in the generator room. The generator room contains a sump to collect liyulds in the event of a spill. The tank and the sump are equipped with high-level alarms that signal in the Vitrification Building control room. 3.14.5 Additional Vitrification System Tanks Two tanks used during vitrification cold testing, the 1,628-11ter Condenuate Collection Tank, now designated Tank 61-D-08, and the 22,710-litar tank now designated Tank 61-D-07, will be used in the Vitrification Test Facility. The Vitrification Tost Facility W has a concrete floor with a three-inch high born, and the floor is sloped toward the north wall, providing a temporary storage capacity of approximately 11,370 liters. The tanks are currently located in the Hardstand trea, a temporary outdoor staging area for tanks, equipment, and other hardware. 3.14.6 Scaled Vitrification System Tanks The Scaled Vitrification System is currently in the design phase. The following tanks are planned for use in the Scaled Vitrification System: o Molter Feed Tank (in design) (61-D-01) o Test Slurry Hold Tank (existing) (61-D-02) o Acid Slurry Makeup Tank (in design) (61-D-03) o Dilute Acid Tank (existing) (V044T) o Anhydrous Ammonia Tank (outside Vitrification Test racility - in design) (61-D-13) o Slurry Food Hold Tank (in design) (61-D-04) o Slurry Feed Hold Tank (existing) (61-D-06) The Scaled Vitrification System and all the above tanks except the Anhydrous Ammonia Tank will be contained in the Vitrification Test Facility. LEWO204.WP6 50

i 9 i WVDP-043 ( Rev. 4 Cold Chemical System Tanks 3.14.7 The Cold Chemical Building is a 37.6 ft x 36 ft building with a concrete foundation and concrete walls extending to un averagt4 height of two feet, above which the construction is uteel frr.co and aluminum siding. 'iho floor is coated with a chemical-resistant covering. The following tanks are in the Cold Chemical Buildings Chemical Waste Hold Tank (65-D-01) o o Slurry Hold Tank (65-D-02) o Slurry Hold Tank (65-D-03) o - Slurry Hold Tank (65-D-04) o Nitric Acid Day Tank (65-D-05) o Caustic Day Tank '55-D-06) o Decontamination Tank (65-D-07) o Decontamination Tank (65-D-08) o Decontamination Tank (65-D-09) o -Scrub Solution Tank (65-D-10) The two-foot concrete walls provide a berm capacity of approximately 65,450 liters, exceeding the capacity of the O largest single tank of 41,365 liters (additional tank capacities are provided in Table 3-1). In addition, the Nitric Acid Day Tank and the caustic Day Tank are individually bermed. These berms have a capacity of 5,640 liters each. The floor is sloped so that any liquid would flow to a central catch drain, and then would flow to a sump that is equipped with an alarm. Liquids i accumulated in the sump would be pumped to Tank 65-D-01. 3.15 Supernatant Treatment System Tanks i 3.15.1 Tanks and Vessels in Tank 8D-1 The following Supernatant Treatment System (STS) tanks and L l Vessels are located in Tank 80-1: o Ion exchange columns (50-C-001, 50-C-002, 50-C-003, and j 50-C-004) o Prefilter (50-F-001) I o Poctfilter-(50-F-002) o Supernatant Cooler (50-E-001) o Supernatant Feed Tank (50-D-001)- Sluice Lift Tank (50-D-004) o l STS operations are closely controlled by a series of SOPS prepared specifically for STS operations (SOPS in the 50-xxx i series), and STS systems are monitored by a programmable logic 0 l controller. The contents of those vessels are filter media and zeolite ion exchange media used to remove cesium from the PUREX LEWO204.WP6 51 a w-ervyve--- e.i,-7ve7myge.w..-77-y-g y33g,-_-yny.yy.-. _y.my. ,g ymam. ,.y De e e4-Pw== m e pr vre-d 1-

WVDP-043 Rev. 4 supernatant. The containment for thase vessels is Tank BD-1 and its previously described layers of containment. The cesium-loaded zeolite is stored underwater at the bottom of Tank BD-1. 3.15.2 Tanks and Vessels in the Valve Aisle Tanks 50-D-005 and 50-D-006, which are stainless steel, are located in the STS Valve Aisle. They function as backflow prevention vessels in the event of process upsets. In the event of a spill, any liquid would drain to the valve aisle sump, which in turn drains to Tank aD-2. 3.15.3 Tanks and Vessels in the Operating Aisle The brine Chiller Expansion Tank (50-D-008) and the Brine / Heat Exchanger (50-E-002) are stainless steel tanks located in the STS Operating Aisle within a 2,250-liter capacity concrete berm. The berm is equipped with a sump that drains to the Operating Aisle sump, then to 8D-1. 3.16 Liquid Waste Treatment System (including Cement Solidification System) The LWTS consists of two subsystemst a water treatment system utilizing filtration, ion exchange, and evaporation; and the Cement Solidification System (CSS). LWTS treatment is performed W on decontaminated supernatant (constituents listed in Table 3-2, minus cesium) and will ba performed on other radioactive wastewaters now being treated in the LLWTF or 02 Plant. The LWTS includes the tanks and vessels listed below. 3.16.1 Tank 35104 Tank 35104 is a 22,000-liter tank made of 304 L stainless uteel in a vault att4ched to the General Crane Room (GCR) in the process building. It receives liquid waste which has been -processed through the STS (constituents listed in Table 3-2, minus cesium). A spill or leak ir. the tank would be revealed by the tank level indicator and cell sump level indicator. Released materials would be contained within tne GCR sump. Tank level is indicated on the STS control panel and recorded on the LWTS control panel. A tank high level would signal in the STS and LWTS control rooms. In addition, on high level, the STS waste inlet valve automatically closes, stopping the STS waste inflow. A tank low level would signal in the LWTS control room. A high level in the pump pit would activate an alarm in the LWTS control room. Prior to transfer of decontaminated and diluted supernatant, STS operators check the indicated level of 35104 to assure that sufficient volume is available to transfer the desired batch. LEWO204.WP6 52

O WVDP-043 Rev. 4 Confirmation is required from the LWTS control room prior to initiating the transfer. On high tank level, the STS waste inlet valve closes automatically, stopping the waste inflow. The STS pump operates independently of this system. 3.16.2 Tanks Located Within the Liquid Waste cell The following tanks are located within the Liquid Waste cell (LWC): o Sample Collection Tank (3D-2) o Rework Evaporator Feed Tanh (7D-8) o PMC and GPC Sump Collector (4D-10) o Radioactive Waste Catch Tank (4D-13) o Low Level Waste Collection Tank (70-2) o Radioactive Waste Catch Tank (40-8) o Hot Analytical Drain Tank (7D-14) Radioactive Waste Catch Tank (13D-7) o o Cell Sump Receiver (13D-8) All these tanks are equipped with level indicators. Any tank overflow would discharge into Tank 6D-3 in the off-Gas cell (OGC). If a release should occur from Tank 6D-3, it would be O contained within the OGC, which is equipped with a sump. J. ty tank leak from the above tanks would be contained in the LWC sump. An eductor is used to transfer the sump contents to Tank 4D-10. The contents of Tank 4D-10 could then be transferred to tanks 7D-2 or 7D-8. l 3.16.3 Tanks Located in the Vessel off-Gas cell Condensate Catch Tank 60-3 and Scrubber Tank 6C-3 are located in the off-Gas cell (OGC). Tank 6D-3 is constructed of stainless I steel and has a capacity of 858 liters. It functions as a condensate collection tank. Tank 6C-3 is constructed of stainless steel and has a capacity of 1,577 liters. It was formerly used'as a neutralizing scrubber tank for scid vapors. .It currently is used as a recirculating tank for domineralizer water. Any leak from these tanks would be collected in the OGC sump This sump can be jetted to Tank 13D-8 in the LWC. The contents of Tank 13D-8 can be transferred to either Tank 7D-2 or Tank I 7D-8, both of which are located in the LWC, 3.16.4 Sodium Silicate Bulk Storage and Day Tank The Sodium Silicate Bulk Storage Tank (5,683 liters) and Day Tank (1,043 liters) are located in the CSS change room. They are constructed of carbon steel and contain sodium silicate, a cement ennancer utilized to maintain the cement recipe in a liquid LEWO204.WP6 53

RVDP-043 Rev. 4 state. In case of a release, the bulk Ltorage tank is surrounded by a spill containment barrier sufficient to hold its entire contents. 3.16.5 Tanks Located in the Uranium Procers cell (UPC) o Evaporator Concentrates Receiver (5D-15A1) o Evaporator Concentrates Receiver (5D-15A2) o Evaporator Feed Tank (5D-15B) These tanks are constructed of stainless steel. Tank 50-15A1 has a capacity of 38,150 litors; SD-15A2 has a capacity of 18,990 liters, and SD '.5B has a capacity of 56,950 liters. The tanks are equipped with level indicators and recorders and low and.tigh lovel alarms. The instrumentation is located on the LWTS control panel. The UPC has floor drains which drain to the interceptors. The UPC is also equipped with a sumpt however, the sump pump has not yet boon installed. It is intended to pump to the interceptors. Tuo sump will be equipped with a high level alarm on the LWTS control panel. 3.16.6 Tanks and Vessels Located Within Extraction Cell 3 o Organic Ion Exchange (Low TDS) (71D-001) o Zoolito Ion Exchango (Low TDS) (71D-002) o Zeolite Ion Exchange (High TDS) (71D-003) o Distillate Surge (71D-00E) o Spent Rosin Receiver (71D-006) o Spent Zeolite Receiver (71D-007) Filter Back Wash Receiver (71D-008) o o Feed Sample Tank (71D-009) o Low TDS Filter (71V-010) o Low TDS Feed Tank (71V-011) o High TDS Evaporator (31017) If a spill occurred from any of these tanks, the contents would be contained within Extraction Cell 3 (XC3). XC3 is equipped with a sump. When the sump is full, the contents are jetted to Tank 13D-8 in the LWC, In addition, the XC3 sump is equipped with a high-level alarm that signals in the LWTS control room. From Tank 13D-8, the contents can be transferred to to either Tanks 7D-2 or 70-8. Tanks associated with the Low TDS System have never contained hazardous product. The system was assembled and post checkout and testing was conducted. However, the system has not been l operated and is not scheduled for operation. O LEWO204.WP6 54 l l-l - - - ~

WVDP-043 () Rev. 4 3.16.7 Tanks Located Within the Lower Extraction Aisle Nitric Acid Day Tank (14D-7) o o Caustia Day Tank (140-18) Each of these tanks is constructed of 304 L stainless steel and has a capacity of 375 liters. The tanks are equipped with level indicators and alarms. If a spill or leak occurred from one of the tanks, the released material initially ^would be contained within a concrete bermed area (one for each tank) in the Lower Extraction Aisle (LXA). If the spilled material sverflowed the bermed area, it would flow to the floor of the l's, which is drained to the interceptors. The tanks rest on carbon steel supports, however, which could corrode over time if the tanks were to leak. Neither of these tanks has ever been used, but they are scheduled for future use. 3.16.8 Waste Dispensing Vessel (700-001) Tank 70D-001 is located in the Waste Dispensing Cell (WDC). It O is constructed of 304L stainless steel, and has a capacity of 1,900 liters. Any spill or leakage would flow to the cell sump. The sump is equipped with a high-level alarm, and its contents can be pumped to Tank 7D-13 (an LLW catch tank (see Section 3.11)) and from there to either Tank 5D-15B, in the UPC, or the interceptors. 3.16.9 Roof Top Evaporator (31008) Evaporator 31008 is located outside on the roof of the process building, near the process chemical Room (PCR). It is constructed of SA240/304L stainless steel, and has a capacity of 510 liters. This unit is not in operation. It is part of the LWTS Low TDS system, which has never been operated except for checkout and testing. 3.16.10 Tani SV-1 Tank SV-1 is a 1,900-liter stainless steel vessel located in ths uranium loadout-(UL4) area of the process building. The vessel contains residual simulated supernatant from testing of the LWTS and STS. The tank does not have any intended future use. A spill of residual material would flow to the ULO ficor and then towerds the entrance / exit doorway, where it would be deterted by a liquid detection instrument sus'- id above the doorway. This-detection device signals in the.' control room. In the event O-of a release, the released mater). would flow out the door of the ULO, into a hallway of the process building, and out a roer LEWO204.WP6 55

l WVDP-043 Rev. 4 door of the process building. From there it would flow into a nearby catch bauin and exit at an outfall north of the old j interceptor. It would then flow southeast to a surface drainage i swale north of the effluent mixing basin. The swale leads to n culvert. Secondary containment would be provided by diking this culvert, creating a temporary storage basin. 3.17 Tanks Located Within the Low-Level Waste Treatment Facility 3.17.1 Acid Hold Tank (33013) and Two Potassiuin Ferrato Tanks The Acid Hold Tank (33013) is constructed of stainless steel and contains 14 molar nitric acid for system line flush. The capacity of the tank is 910 liters. The tank is situated on the chemical tank platform in the southeast area of the second floor of the 02 building. The tank is equipped with a sight glass, rample tap, and drain line. All lines, valves, nuts and bolts, and the sight glass associated with this tank are stainless steel and gaskets are teflon in flanged connections. The valves to the sight glass are right angle valves. The valve retainer nuts and packing nuts are rusted slightly, indicating they are not stainless but a high grade steel. These valves have been in place for some time and no physical breaks or pits are evident in the nuts. The rust seems to be only surface rust. All wetted parts are welded stainless steel except for flange connections to the sight glass and the drain to decommissioned and nonfunctional Acid Mix Tank (33154), located within the bermed area outside the 02 Plant. The tank is placed within a stainless steel pan which is 14 cm larger than the tank radius and 5 cm deep. The pan is equipped with a 5 cm stainless steel drain to the process cump. A 5 cm floor drain is located approximately 120 cm east of the tank and the floor slopes to the drain. This drain also flows to the sump. The potassium ferrate mix tanks are located on the second floor of the LLWTF Building. They are molded polyethylene tanks with polyvinyl chloride or stainless steel fittings, and each tank has a capacity of 210 liters. Each tank is equipped with a calibrated level gauge built into the molded design of the tank. The tank walls are translucent and the level of the contents is readily observable. The tanks provide potassium ferrate to the clarifier /flocculator to expedite flocculation of solids within the LLWTF waste stream. 3.17.2 Ion Exchange Columns 101 and 102 Tho ion exchange columns within the LLWTF Building are carbon steel polylined vessels of 3,524-liter capacity each. They contain the ion exchange resins used te remove the radioactive LEWO204.WP6 56

O WVDP-043 Rev. 4 components of the process waste stream. They are equipped with individual pressure gauges. Any spills or leaks from these tanks would drain to and be contained in the building's sump. When the process is running, the sump contents are recir.cula-tod back into the process. When the process is not running, the sump overflows to Lagoon 2. 3.18 Trench Interceptor project Protreatment Tanks Tanks associated with the Trench Interceptor Project (TIP) Groundwater Treatment System include o Separat3cn Tank (82-D-01) { o Separation Tank (82-D-02) o Protreatment Feed Tank (82-D-03) j o Post Treatment Hold Tank (82-D-04) Post Treatment Hold Tank (82-D-05) o o Granulated Activated Charcoal (GAC) Filters (82-C-01) Granulated Activated Charcoal Filter (82-C-02) o The TIP is an engineered system to recover and pretreat groundwater from the NDA. This system is designed to remove ,e (through physical separation and GAC filtration) tributyl \\ phosphate (TDP), n-dodecane (a kerosene-type petroleum product), and radioactive contaminants from groundwater, prior to treatment at the LLWTF. Tanks 82-D-01 and 82-D-02 receive groundwater from a trench via c sump and function as physical separation tanks, separating the n-dodecane from the water. They have a capacity of 3,790 liters each and are constructed of carbon steel. Tank 82-D-03 is a carbon steel 18,950-liter tr.ed tank that holds 11gulds prior to GAC filtration. Tanks 82-C-01 and 82-C-02 are carbon steel 2,653-liter GAC filters. Wastewater is processed through tho filters and then l passed to tanks 02-D-04 and 82-D-05, which hcid the treated water l for sampling prior to discharge to the LLWTF. Tanks 82-D-04 and 82-D-05 have a capacity of 3,790 liters each and are constructed of carbon steel. l l Two separate berms exist to contain spills from those tanks. j Each berm is 24 feet x 24 fent x 1.5 feet high, providing l approximately 24,635 liters of spill containment capacity. Tanks l 82-C-01, 82-C-02, 82-D-04, and 82-D-05 are contained within one i of the berms, and tanks 82-D-01, 82-D-02, and 82-D-03 are in the other. O,- l LEWO204.WP6 57

WVDP-043 Rev. 4 O! Tanks 82-D-01, 82-D-02, 82-D-03, 82-D-04, and 82-D-05 are all equipped with low level indicators, local and remote audio and visual alarms, and automatic shutoff switches. Tanks 82-C-01 and 82-C-02 are equipped with local pressure gauges. 3.19 Miscellaneous Facilities 3.19.1 Transfer Tanks Two 757-liter cross-linked, high density polyethylene tanks and one 1,900-liter 304 stainless stool tank are in use at the VF for transfer of liquids on an as-needed basis. All pipe fittings used are stainless steel or VITON. These tanke are attached to a modified skid arrangement for stable transport by forklift. These tanks are not equipped with any instrumentation. The polyethlone tanks are translucent and the level of the contents Cdn be Viewed from the outside. 3.19.2 Portable Diesel Fuel Tank This tank has a capacity of 1,136 liters and is constructed of carbon steel. It is 1.8 m long and 0.9 m in diameter. This tank is not equipped with any instrumentation, and spill containment is provided by a carbon steel pan constructed around the tank. The tank is filled from the underground diesel fuel tank, located to the southeast of the new warehouse. It is then transferred by forklift to the area south of the UR. A hand pump is used to pump out the fuel. The funi is used to refuel the air compressor and fire pump. 3.19.3 Utility Room Diesel Day Tank (48066-A) The UR diesel tank is 1.5 m long and 0.9 m in diameter. It is constructed of carbon steel and rests on concrete saddles. It has a capacity of 1,098 liters and contains No. 2 fuel oil. Any leak would flow to the UR floor and drain to the interceptors. 3.19.4 Vessel Off-Gas Condensate Catch Tank (60-3) Tank 6D-3 is located in the Off-Cas Cell (OGC). It is constructed of stainless steel and has a capacity of 858 liters. If this tank were to leak, the contents would be collected in the OGC sump. This sump can be jetted to 13D-8 in the LWC. The contents of 13D-8 can be transferred to either tanks 70-2 or 7D-8, also in the LWC. O LEWO204.WP6 58

WVDT -04 3 () Rev. 4 3.19.5 Tanks Located Mithin the Waste Tank Farm Shelter The following tank are located within the Waste Tank Farm Shelters o Con. Ed. Off-Gas Scrubber (8C-1) Off-Gas Knock Out pot (8D-6) o o Off-Gas Relief Tank (DD-7)- These tanks are located in the waste tank farm shelter and collect mildly radioactivo condensate and acrub solutions from the HLW tank farm off-gas system. The drain on 8D-6 is normally open and drains to HLW Tank 8D-2. If the drain were to be closed and there were an overflow, the natorial would go to Tank 80-1. Tanh BC-1 overflows to Tank BD-6. 3.19.6 Zinc Bromide Shield Windows Shield windows in various cells in the procuss building consist of two thick layers of glass forming a tank tnat contains zine bromide, which.is a clear, dense, extremely corrosive liquid. The window tank includes an epoxy coated carbon stool framo. Gaskets are used to seal the framo. () The level of zinc bromido in the window is readily apparent. Any ~ leaks would also be apparent along the frame. Any spill or leaked material would be contained in process aisles or inside the cell where the window is installed. Any zine brom4de entering flocr drains would be collected in the cells or cell sumps. From the sumps it would be transferred to waste catch tanks. A summary of the locations of these windows and the volumes of zine bromide contained in them is provided in Table 3-1. l 3.19.7 Fire Pump Day Tank The firo pump day tunk is a 1,040-liter carbon steel tank located inside the pump house south of the UR. The tank contains No.-2 -fuel oil and is equipped with a levol indicator. No berm or r spill basin is provided for this tank. However, the tank is inspected on every shift, and if a leak occurred, it would be promptly discovered. Any.roloaac would flow from the pump house to the adjacent surface drainageway to the south, then east past l the yard tanks into the surface drainage swale north of the effluent mixing basin. The swale leads to a culvert. Secondary conteinment would be provided by diking this culvert, creating a i j temporary storage basin. () The tank is filled from a vendor tank truck through a fill nozzle located on the north side of the pump house. The fire pump LEWO204.WP6 59

I WVDP-043 Rev. 4 (using fuel from the day tank) is operated periodically to ensure that it wculd function properly in the event of a fire. For extended firefighting operations, fuel oil from Tank 31D-2 pould ba used to supply fuel for the fire punp. Aboveground hoses would be utilized in this event. 3.19.8 'TS Day Tank The STS day tank is a 380-liter carbon steel tank located in the STS generator room, which is in the STS ventilation systam building. The tank contains diesel fuel and is equipped with a level indicator. Tho tank is filled from the STS bulk fuel oil tank. A leak or spill from the day tank would be contained within the STS generator room. 3.19.9 Receiving Warehouse Storage Cab: 'ets for Flammable Liquids The Receiving Warehouse contains seven storage cabinets for flammable liquids. Paints, thinr. ors, chemicals and acids are segregated and contained within individual cabinets. Not all cabinets contain flammables. Five-gallon pails are the single largest type of container in any individual cabinet. Each cabinet is 43 inches x 18 inches x 65 inches in dimensions, with a2 inch deep sill at the bottom for spill containment. These cabinets will be noved to a ctorage area in the New Main Warchouse sometime in 1991. 3.19.10 New Main Warehouse The New Main Wareho me contains five engineered segregatad storage areas for c.crosives, acids, oxidizers, flammables, and health hazards (poisons). Each storage area is equipped with a 6-inch deep basin below a steel grate floor to contain spills. Each area also has a separate ventilation system and fire suppression system and alarm. The flammable storage area also contains explosion-proof doors and blowout panelu built into the walls. Matorials stored in these areas will be in their original shipping containers, and no container larger than 55 gallons in capacity will be stored in the building. 3.19.11 Cargo Unit Trailer Body The cargo unit trailer body is a 8' x 40' tractor trailer body functioning as a storage area for motor oils, hydraulic oils and greases. The body is constructed of steel and wood, with a panelled wooden floor. Fifty-five-gallon drums of motor oils and 97 ases, as well as smaller pails of lube oil and hydraulic oils are stored here. There is little or no partial removal of product'from these containers within the trailer. Entire O LEWO204.WP6 60 1

WVDP-043 Rev. 4 containers /and or drums are removed f rom the trailer and taken to the area of use prior to product removal. 3.20 Hazardous Waste Satellite Accumulation Arono As part of the WVDP Hazardous Waste Management Program, SAAs have baan established at the point of generation of identified hazardous wastes. SAAs are listed by location, material they contain, and type of concainor or containers in Table 3-6. Spills or leaks from containers in the SAAs will be confined to the immediate area of the containers. Each of these SAAs is located within or adjacent to an active work area and so is subject to constant observation by workers in the area. Moreover, all of the SAhs incorporate secondary containment measures. Such measures include an enclosed cabinet, tray, or box, or building curbing and the building drainage control system. 3.21 Ihterim Waste Storage Facility (IWST) The Interim Waste Storage Facility (INSF) functions as a temporary storage facility for wastes that require radiological <"x and/or chemical analysis. The IWSF is a pre-engineered metal ( ) structure measuring approximately 34 feet x 34 feet. It is supported by a clear span frame and anchored to a bermed, concrete slab foundation. An 8 inch high concrete curb encloses the inner perimeter, providing approximately 21,630 liters of secondary concainment capacity in the event of a spill or leak. Fif ty-five-gallon drums, 5-gallon pails, and smaller containers of wastes are contained within the building temporarily, pending the results of analycis. There are three cabinets dedicated for the storage of flammable wastes, two dedicated corrosives (one for caustics, one for acids), and a refrigerator to preserve samples within the structure. A complete invoutory and floor plan of wastes contained within the building is maintained and updated routinely by the Waste Managament Operations Department. 3.22 Four Hazardous Waste Lockers The Hazardous Waste Lockers are pre-engineered lockers containing segregated 55-gallon drums, 10- and 5-gallon pails of hazardous and nonhazardous wastes. Each locker is identical in size, with dimensions of 8 ft x 15 ft x 8 ft. Each contains a spill basin beneath a steel grate floor with a capacity of 474 liters or 10% of the volume of material stored in the locker. Two of the lock-ers are designed to contain flammable materials. They are equip-ped with fire suppression devices, remote and local fire alarm g-) systems, explosion-proof electrical components, and explosion-( j proof vents. Acids, oils, solvents and other industrial (nonhaz- \\/ ardous) and hazardous wastes are stored in appropriate lockers. LEWO204.WP6 61 -~

WV0P-043 Rev. 4 Table 3-6 Ilazardous Waste Satellite Accumulation Areas LOCAT1Q11 1RTERIAL CONTAINER Blueprint Area A 20-gal dru.n Develo ol 30-gal drum Hot Lab Pu t wante 1-11ter glass ( cottle one Sion du h,k u ntillation 1-gal glass or llot Lab (P-terphenyl, high density P, llPE!!P, poly bottle uene, PiQ Mai nc oily wipes 55-gal drum Da o Developer solution 1-gal poly jugs CTS Lab Acidic waste from 10-lit.or poly TCLP/EP Tox tests bottle s I LEWO204.WP6 62 O

l WVDP-043 - O) Rev. 4 q 3.23 Portable Holding Tanks i Twelve rkid-mountad carbon steel temporary holding tanks are found at varioua locations throughout the site and are frequently relocated depending on site requirements. These tanks have a capacity of 3,790 liters each. They are used on an as-needed basis, typically to contain accumulated water during construction activities. The contents of the tanks are sampled prior to discharge. If sacendary contr.inment is required in a particular application, the ttnks are placed in yellow carbon steel boxes. 3.24 Mineral Oil Windows There are a number of leaded glass shield window tanks that contain mineral oil to enhance clarity. These include four in the CPC (three containing 110 gallons of uineral oil, one I containing 75 gallons), seven the Process Mechanical Coll, five in the General Construction Aisle, and four in the Analytical Coll. Mineral oil is not a hazardous material. 3,25 Waste Tank 8D-2 Caustic Transfer Staging Area A 4,500- to 5,000-gallon vendor truck will be periodically staged (~' north of the HLW tanks to provide caustic additions to Tank BD-2 l during sludge wash operations. These operations are scheduled to i commence in October 1991. For routine transfer operations, the truck will enter-a staging area thac may include a 10 ft by 10 ft port-a-berm system. For non-routine operations in which the truck pould reside in tne staging area more than seven days, a 45 ft by 16 ft by 1.3 ft inflatable berm will be utilized, providing a spill containment capacity of approximately 7,000 gallons. Aboverground hard piping will be used to route the caustic to Tank 8D-2. I 3.2G Ram Equipment Room l The Ram Equipment Room (REM) is located west of the FRS on the first floor of the main plant. It is used to store special nuclear materials, e4g., drums of waste plutonium nitrate colutions and PU wastes. Approximately thirty lined 55-gallon overpack drums containing 30-gallon drums of the above materials y are contained in thin room. The room is equipped with floor drains that would route any spil),ed material to the LLWTF [ interceptots. l I LEWO204.WP6 63 l t I, ~

WVDP-043 Rev. 4 4.0 "OTENTIAL OIL, HAZARDOUS SUBSTANCE, CE HAZARDOUS WASTE RELEASE SCENARIOS 4.1 Sources Potential sources of releases of oil, hazardous substances, or hazardous waste include all the storage facilities listed in Section 3.0. However, no realistic potential exists for releases to the environment from facilitiro inside buildings. Therefore, thAs section will only consider facilities not enclosed in buildings. Some of these outdoor facilities are provided with secondary containment mechanisms such as containment basins and berms. However, in the citent of a release, all of the outdoor facilities would also be provided with containment by means of blockage of the spill migration pathway. The remairder of this section focuses on spill migration pathways (including available locations for blockage) in the event of a spill from one of the outdoor tanks. Underground tanks at the WVDP are maintained in compliance with state and federal underground stocage tank regulations, wh! h require leak prevention and detection by various means suca is regular monitoring, cathodic protecolon, double containmot.t, etc. T' However, this section will consider surface migration pathways (m,T due to spilla as the result of filling or dischsrging from these / tanks. In addition, the WVDP comprehensive groundwater monitoring program would also serve to identify ay subsurface spill migration. The monitoring includes collection of samples at regular intervals from areas that would be likely to be i.mpacted by site activities. The samples are analyzed for radioactivity as well as EPA drinking water standards and groundwater quality parameters. 4.2 Migration Pathways Releases in the majority of the plant area would flow east into surface depressions and eventually, if not blocked, to Erdman Brook or Franks Creek. These migration pathways and available blockage points, and the containment basin that would be formed in the event of blockage, are shown on Figure 4-1. A release in the northwest area of the site would flow northeast into a surface depression and eventually, if not blocked, into Quarry Creek. These nigraticn pathways and available blockage point, and the containment basin that would be fermed in the event of blockage, are also shown on Figure 4-1. r3 Figure 4-1 also shows paths of underground storm sewers (dashed ) lines). Storm sewer outlets generally lead to surface ditches, I through culverts, and to topographical depressions leading to l LEWO204.WP6 64

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O WV0P-043 Rev. 4 creeks. The storm newer system and continuing topographical drainageways represent a further containment system in the event of a release. The containment basins which could be developed by culvert or ditch closure range from extremely large (e.g., 7.5 million _ gallons, by blocking a culvert southeast of the warehouse) to several hundred gallons (e.g., some minor ditchos). In. addition, any surface spill would also scop into ground to some extent. However, soils in the plant area are of sufficiently low permeability (as discussed in Section 2.0) that the aboveground portion of the spill would be detected before seepage that would affect groundwater could occur, and thus the containment issue would primarily involve surface flow. The nitric acid tank (14D-1, permanently out-of-service as a hazardous substance storage tank): caustic tanks (14D-2 and 14D-2A, the latter which is permanently out-of-servico); and fuel oil tank (31D-2) are located in the yard southeast of the process building. These tanks are contained in borned areas. A spill or a leak that overflowed the berm containments would flow over the road and drain into the Utility Room drainage ditch. This ditch O leads to the southeast, crosses under the security road, runs into another drainage ditch and into Erdman Brook. Normal transport time for liquid to flow along this path is on the order of severa.1 minutes. Blocking this drainage path at the culvert under the security road would prevent off-site migration of spilled material. The north and south interceptors and the neutralization pit aro below grade concrete basins lined with stainless steel located across the road fron and to the east of the caustic tanks. Spills from these described in the previous paragraphs. Overflow from these f acilities would flow into Lagoon 2 or the same surface depression as. described for the caustic tanks, Blocking this drainage path at the culvert under the security i road would prevent off-site migration of spilled material. The underground gasoline and diesel fuel-tanks are located directly south of the process building and southwest of the warehouse. A substantial surface spill of material from these tanP.s would flow south several meters to a drainage ditch alongside a roadway, then flow in the ditch another 100 meters l south to a culvert under the road. On the other side of the road l it would flow south along a railroad bed another several hundred L meters to a culvert under the rails and to a topographical depression that leads into Erdman Brook. However, the ficw could O be blocked at either of the culverts. Blocking the drainage path would allow cleanup before the spill material could migrate off-site. The transit time for material to flow from the area of the L LEWO204.WP6 66 l-l L ~,.... _ _. - _..... m..-.

WVDP-043 Rev 4 fuel pumps to Erdman Brook is on the order of minutes to hours, depending on conditions. Located adjacent to the gasoline pump area is the new warehouse building. This facility is used to store packaged chemicals. Small spills would be contcincd within the building and the cement floor affords easy cleanup. In the event of a fire in the warehouse, however, resultant runoff (water or other fire suppression materials mixed with chemicals) would flow into the drainage pathway described for the fuel tanks, and could be blocked at the same points, allowing cleanup before the materialu could flow off-site. Spills from the hazardous waste storage lockers in the northwest part of the plant area would flow cast along a roadway and then northeast into a topographical depression leading toward Fru..ks Creek. However, the flow could ba blocked in the topographical depression, creating a containment basin that would permit cleanup of the spilled material before it could flow off-site. The sulfuric acid tank and tanks 48070 ( flocculator-cir.rifier), 35105 (clarified water surge tank), 48091 (clarified water filter), and 33012 (recycle tank) are located on a concrete spill pad adjacent to the LLWTF. Spills from this unit would be contained within the concrete spill basin, which has a drain system to the LLWTF feed sump, which flows to Lagoon 2. If a substantial spill were to occur within this basin, the spilled material might overflow the berm, whereupon it would flow cast to the drainage ditch alongside the lagoon system. This ditch runs several hundred meters toward Erdman Brook.

However, prior to the spilled material reaching the brook, the ditch could be blocked at a culvert unter the security road, and a trench could be cut to divert the material to Lagoon 2, preventing it from flowing off-site.

i i 0 LEWO204 WP6 67

WVDP-043 ( Rev. 4 \\_ 5.0 SPILL PREVENTION PROGRAM 5.1 Training Program Training at the WVDP is a formally organized and continuing program of employee indoctrination and instruction to ensure that personnel receive a level of training consistent with work assignments and responsibilities. Several training programs are provided, namelyt o For operating system supervisors and system operators (Main Plant, STS, CSS, Low-Level Waste Treatment System, and vitrification Operations); o For decontamination supervisors and operators; o For fissile material handlers; o For radiation and safety technicians; o For maintenance and custodial personnel; o For the general employee; and \\ o For other plant contractor and visitor personnel in areas where special restrictions are applied for safety reasons. Emphasis is placed on formal qualification in radiation protection of workers who may be occupationally exposed to radiation. Additional training requirements for personnel involved in various operation are developed based on the specific operations. All WVDP training programs meet the requirements of DOE Order 5480.lA, Chapter 5. Training programs are evaluated and upgraded based on management observations and appraisal of on-the-job performance of individuals and operating crews and teams. These evaluations include the use of written and oral examinations and the identification of deficiency areas that may require retraining / retesting. The total qualification training programs for the various departnants consist of: o Formal classroom training; o Plant orientation; o On-the-job training; o Proficiency testing; \\- o comprehensive oral and/or written examinations; and o continuing training. LEWO204.WP6 68

l l WVDP-043 Rav. 4 o Continuing training. 5.2 General Training All new eaployees are required to attend a general orientation program that consists of a combined safety and security orientation, and an introduction te the project scope, purpose, organizational responsibilities, and managemer.t. Radiation Worker Training is required for individuals working routinely in radiologically controlled areas. This training identifies basic initial spill response measures, identified by the acronym SWIMS, which stands fort Stop the spill at its source, Harn others of the spill, Isolate the area, Minimize personal exposure to the radiological and chemical hazards of the spilled material, and gecure ventilation to the affected plant area. 5.3 Plant Operator Training For staffing and training, all plant operations at WVDP are divided into organizational areas. These operational areas and the scope of training within each are revised as the scope of operations change. To operate in one of these areas, an operator must be trained and h certified. This certification requires completion of a comprehensive written examination (and attainment of a grade of at least 80 percent) on each relevant process or operation. In addition, plant systems operators and senior plant operators must complete a plant walk-through examination, including hands-on testing and demonstration and discuosion of the operator's responsibilities. 5.4 Safety Training The Training Department provides ongoing safety awareness training, worker right-to-know training, and selected safety equipment training. In addition, training programs are developed and conducted as new equipment is identified as requiring specific safety training, only individuals who have received appropriate training and demonstrated the ability (by written test or otherwise) to operate eqdipment are allowed to do so. 5.5 Emergency Spill Response Training Specific training is provided to the WVDp Fire Brigade on emergency response. This includes the use of videotaped

raining modules on spill response.

General training for spill responso is included in the Radiation Worker Training Program. O LEWO204.WP6 69 I s

l I g-WVDP-043 Rev. 4 5.6 Ilazardous Waste Management Training Specific training programs are provided on procedures for the management of hazardous waste. Topics included are identification of hazardous wastes, prnper labeling and marking of containers, safety concerns, recordkeeping, use of manifest documents, and overall management of the wastes. Specific training is also provided to the WVDP Fire Brigade for emergency response. This training includes modules addressing hazardous wastes concerns. 5.7 Retraining Program All nonradiation workers receive annual refresher training on safety and security topics, emergency signal response, and Project organizational recponsibilities. All plant systems operators are required to participate in an annual requalification program consisting of required reading (procedures and Unusual occurrence Reports), completion of a comprehensive written examination, walkthrough, and oral examination, as applicable. I~N 5.8 Administration and Records b The Training Department maintains a cource file in accordance with West Valley Procedure WV-730 for all approved training material and a central documentation file for employee / subcontractor records of implementation of training programs. The file is also used to schedule refresher or upgrading training for all WVDP personnel. Before releasing training materials for use, the Training Department reviews all the material for content to assure that it satisfies established training objectives. The material is then reviewed for technical accuracy and approved by the cognizant operations managers. 5.9 Inspections and Recordkceping All outdoor aboveground tanks and their associated spill containments are in frequented areas where leaks would be obvious to the normal traffic of operators. In addition, Tanks 14D-1, 14D-2, 14D-2A and 31D-2 are checked each shift. Levels are recorded on a form entitled " Chemical Process Data Sheet." This sheet is signed and dated by the operator taking the readings and is reviewed and initialed by the shif t supervisor. These chemical process data sheets (run sheets) are placed in the operations file by the shif t supervisor. LEWO204.WP6 70 ) . pg

RVDP-043 Rev. 4 In addi% ion to shift readings, the diesel fuel oil storage tank (31D-2) level is recorded once a week on operations tickle file card 10051P. If the boiler is operating on diesel fuel, a reading is required every four hours. The 10051P card is filed ~ with the Plant Operations Support Document Control Clerk. Operational Safety Requirement OSR/TR-GP-5 states that the quantity of diesel fuel in the oil storage tank (31D-2) shall be maintained at 30,300 litors or more during normal operations. 1: used during abnormal conditions, operations may continue as long as a volume of 15,000 liters or qreater is maintained. A volume less than this will require the commencement of plant shutdown, which shall continue unless the primary fuel (natural gas) service is restored or the fuel oil supply is replenished. As a result of leaks in underground transfer lines, operating procedure (SOP 7-08) has been changed to require pressure testing prior to use of transfer lines that have not been used within the preceding three months. The gasoline and diesel fuel storage tanks and pumps are under the control of the Warehouse. The Warehouse maintains an inventory log sheet for each tank, showing tank starting volume and amounts withdrawn at each use. Refills are ordered when the tank inventory falls below 3,400 liters. The gasoline storage tanks were installed in January 1985 in accordance with the requirements of 6 NYCRR 613 for Category C tanks. These tanks were tightness tested in February and March 1991. The testing revealed there was no loss of product. Most on-site tanks and vessels are contained within buildings or other structures. Many of these vessels are equipped with level indicator instrumentation. The operation of all these vessels is covered in SOPS, run plans, etc. Monitoring and inspectior. of this equipment is part of the procedures. Monitoring and inspection of the SAAs, hazardous waste storage lockers (HWSLs), and the IWSF are covered in SOPS addressing these specific matters. In addition, daily and weekly inventory logs and inspection logs are maintained for areas served by the SAAs. These logs allow for a continuous monitoring of the types and quantities of hazardous wastes generated and stored on-site and provido documentation of the physical integrity of containers in the SAAs. Also, the site security force performs routine inspections of all areas of th( site. These personnel are directed to report any unusual occurrences such as strange odors, leaking tanks or contaxners, etc., to the shift supervisors for follow-up investigation. f LEWO204.WP6 71

Oi WVDP-043 Rev. 4 5.10 Site Security The antire 1,335-hoctare WNYNSC is fenced, posted, and subject to routino patrols by the WVDP security force. In addition, the 64-hectare plant sito is a controlled-access facility surrounded by an 8 ft high chainlink fence topped with throa strands of barbed wire. The HLW, STS, PVS areas, where most of the tanks discussed in this plan are located, are well-lighted and are patrolled by officers on foot and in vehicles 24 hours a day. The controls and valves for the various tanks (14D-1, 14D-2A, and 31D-2) are operated under authorization of the Shif t Superv4 or in accordance with SOPS or run plans. The operations files, tickle cards, and warehouse inventory logs are all Project records that are archived in the Project's Master Record Contor in accordanco with DOE orders. Control switches for the gasolino and diesel fuel pumps are located in the Warehousa and are locked except during fuel pumping. The keys are maintained by Warehouse personnel. The security force is authorized to dispense fuel on off-shifts. O O LEWO204.WP6 72

O WVDP-043 Rev. 4 6.0 CONTINGENCY PLAN 6.1 Spill Response Equipment The warehouse maintains several types of spill recovery equipment as well as an inventory of general supplies useful in recovering spilled material. General supplies include *ubber gloves, boots, and chemical-resistant disposable suits, as w111 as respiratory protection equipment, goggles, and other perstnnel protective equipment. Lumber, plastic, and Herculite are available to construct temporary berms. Specific spill response equipment includes clay sorbent material (speedy dry) and absorbent socks and pillows. Several sizes and types of overpack and salvage drums are also maintained in inventory. In the event of a large spill or release to the environment, the on-sito excavation contractor can be directed to deploy his carth moving equipment to cut off drainage ditches and culverts to contain spilled material. The Project also has several different types of pumps and a variety of surplus tanks, including a 5,000-gal stainless steel tanker trailer, available for recovery of large quantity spills. The Project also maintains an on-site emergency response vehicle stocked with sufficient personnel protective equipment and initial spill response materials to initiata a respor.se to a large scale spill. 6.2 Spill Prevention and Emergency Preparedness The WVHS Plant Operations Manager is responsible for all spill prevention. Reporting to the Plant Operations Manager are: the Main Plant operations Manager, who is responsible for operation and maintenance of the storage tanks, and the Site Engineering Manager, who is responsible for the design and engineering of the storage and containment facilities described in this Plan. The-Training and Communications Manager is responsible for developing and implementing oil spill prevention and control training pro-grams. The Plant Operations Manager reports directly to the WVNS President (also identified below as the WVNS Emergency-Director). If a_ spill of oil or hazardous substance or waste is identified at the WVDP, the initial response will be to contain che material on-site, identify the source, and-isolate or eliminate the source. Notification of the spill will be provided to the DOE-WVPO using the " Substance Release Report Form" (see Section 6.3). If the source of a spill is from a vendor tank truck, the DOT O label will identify the material. The various dot labels are shown in Figure 6-1. Appendix A provides DOT safety guide LEWO204.WP6 73 .u -

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4 WVDP-043 Rev. 4 numbers for such substances. A Chem-tox computer database is available on-site. This database provides more detailed information regarding hazardous substances. Multiple sources of information regarding chemical substances should be utilized in the event of a. spill. If the container or tank has a DOT hazardous material number (indicated by a "UN" or "NA" followed by four digits), the identity can be' determined by the Chem-Tox data base available on the WVDP S&EA Local Area Network. This information can be accessed by calling either the S&EA manager or the Environmental Lacoratory. If containment around a given source were to fail, the spill c:n still be contained within the site boundaries by cutting off surface drainage from the area. This can be done by placing earthen dams across drainage oitches or utilizing alternative spill containment devices. Eliminating the source of the splil may be performed by closing a valve on a transfer line or removing the material from the leaking tank.-_ Material removed from a tank would be transferred into a suitably equipped spare tank or tank truck. The Project gg has several spare tanks and a 5,000-gallon stainless steel tanker l ( ) trailer. This would also be the m3thod for recovering spilled l material retained in a spill pad or containment. basin. l l Responsibility for recovery from nonemergency :, pills (i.e., where there is no potential for off-site release or a threat to the safety of on-site personnel) resides with the WVHS Plant Service Manager. The manager will call upon the expertise of other WVNS management and staff as necessary to remediate the situation, and i will also notify the NVNS Environmental Control Officer, who will i determine if subsequent off-site notifications are required. {- l The Project Emergency Plan will be implemented if a spill of oil or hazardous material is of sufficient magnitude to threaten the safety of on-site personnel; or an off-sjte release of reportable quantities of hazardous materials (per 40 CFR 117); or harmful quantities of oil per (40 CFR 110). For the hazardous cubstances nitric acid, sulfuric acid, and sodium hydroxide, the reportable quantity (RQ) is 1,000 pounds..Other hazardous substances which are components of the slurry feed used by the VF are potassium hydroxide and nickel hydroxide, each with RQs of 1,000 pounds; I and sodium phosphate, zirconium nitrate, codium fluoride, and formic acid, each with RQs of 5,000 pounds. The petroleum product spill reporting procedures agreed to by the DEC-and the West Valley Project Office as of February 21, 1990, include the. following provisions: LEWO204.WP6 75

WVDP-043 Rev. 4 1. Spills of petroleum products less than five gallons that occur on pavement or other impervious material and do not enter any surface drainage must be entered into a monthly log. 2. Spills of petroleum products of any size that are fully contained within an enclosed structure must be entered into the monthly log. 3. Spills of pet.roleum products of any size that impact any environmental medium (e.g., soil, groundwater, air) or enter a drainage system must be immediately reported using the DEC Hotline 1-800-457-736 (if calling from outside New York State, 1-518-457-7362). During normal business hours, spills can be reported to DEC Regio 6 9 ct 716-847-4590. The monthly log must be submitted to DEC Region 9 by the 15th of the following month. The log must be available for inspection during normal business hours. If a release is imminent, the WVNS Environnental Control Officer (ECO) will notify the DOE-WVPO. The DOE Project Office will notify the Warning Communications Center (WCC) at DOE-ID, and the EPA, if necessary. The ECO will also notify Westinghouse Electric Corporation Environmental Affairs. f The P oject Emergency Plan (PEP) provides an organized plan of action that identifies authorities and responsibilities of emergency response personnel and organizations and identifies the manpswer and equipment resources available to cope with emergencies it the in/11P. The PEP applies to emergency actions relative to radiological, hazardous, industrial, safeguards and security (theft of Special Nuclear Materials, threats or acts of violence,'etc.), and natural phenomena emergencies at the WVDP. The primary purpose of the PEP is to minimize the impact of any emergency upon the health and safety of plant personnel and the general public. Appendix B provides a list of on-site individuals in pcssession of a controlled copy of WVDP-022, the PEP. The WVNS President has the ultimate responsibility for all WVNS activities. The WVNS President interacts with the DOE Project Director and off-site resources as appropriate for the mitigation of emergency conditions. The President will designate qualified Emergency Directors and associated Emergency Operations Center personnel. This list will be periodically updated and will be maintained in the Emergency Procedures Manunl contained in the PEP. The WVMS President will retain respcasibility and authority for assessment and mitigation of emergency conditions at WVDP unless relieved by higher authority. LEWO204.WP6 76

WVDP-043 Rev. 4 With regard to emergencies, the President or h, alternate shall: 1. Maintain executive control of all emergency situations affecting WVDP operations; 2. Activate the WVDP Emergency Operations Center and WVDP emergency response personnel, as needed; 3. Direct emergency response actions utilizing personnel and resources to mitigate consequences of the emergency; 4. Authorize cite-wide evacuation of personnel, if needed; 5. Activate WVNS personnel, as needed; 6. Maintain WVNS succession of authority; 7. Authorize obtaining assistanco from off-site organizations such as hospitals, health departments, highway departments, law enforcement agencies, fire departments, ambulance services, etc., as needed 8. Authorize mutual aid or other emergency assistance from () off-site agencies or organizations, as needed; and 9. Recommend to the DOE-WVPO Director notification of off-sita local, county, and state officials when WVDP-originated hazardous material releases to the environment may affect persons or property outside the site boundary. The WVPO will notify DOE-ID and DOE-HQ, and DOE-ID assistance will be requested, as needed. The DOE-WVPO will dete?!mine if *he' situation warrants notification of the EPA or National Response Center for spills of oil or hazardous materials. Whenever a major WVDP emorgency occurs, the Emergency Director shall activate Emergency Orccations Center personnel or their designated alternates. Th.s group provides administrati/e and technical assistance to the' Emergency Director, as needed, and consists cf the Emergency Operations Center staff Technical Support Center Staff, Operational Support Group, and On-Scene Commander Group. The composition and functions of these groups are described in the WVDP Eraergency Plan and Procedures Manual. On off-shifts, the responsibility for_ emergency direction for the WVDP rests'with the Main Plant Operations Supervisor until re-lieved by higher authority. The Main Plant Operatinns Supervisor is the Emergency Director during emergency evants where fire and r'"g health concerns are paramount, i.e., radiological, chemical, tox-(,f ic releas<. etc.; when natural emergencies, e.g., high winds, LEWO204.WP6 77

1 WVDP-043 Rev. 4 O blizzards, flooding, earthquaAas, tornados, etc., present actual or imminent thracts; or during security emergencies. Regardless of the size or severity of a spill, once the situation has been stabilized, recovery measures will be implemented. Equipment will be repaired or replaced and contaminated areas will be cleaned up. Contaminated wastes generated during these operations will be disposed of in accordance with applicable state and federal regulation 3. 6.3 Notifications In the event of a spill or other release of oil, hazardous substances, or hazardous wastes, the following notifications will be made: The individual discovering the release will notify the o Shif t Supervisor in charge of the affected area. The Shif t Supervisor of the affected area will notify the Main Plant Shift Supervisor (MPSO). The MPSO will notify the Environmental Control Officer (ECO) as soon as possible, If the release constitutes an emergency as determined o by the ECO, notification of the situation will be made via the 812 emergency all-page system. o For any spills resulting in a release to the environment, the DOE-PO will be notified as soon as possible by means of the Substance Release Report Form shown in Figure 6-2. o The Plant Operations Manager will initia.te spill contoinment measures, o The Emergency Director will determine if the situation warrants activation of the Emergency Operations Center. In a non-emergency, the ECO will notify the respective o DOE-WVPO representatives and Westinghouse Environmental Affairs (412-642-3444). I o The DOE-WVPO will notify the DOE-ID WCC (FTS-7-583-1515 l [1-208-526-1515]). The DOE-WVPO will notify EPA and appropriate New York o State agencies if needed. The notifications will include but necessarily be limited to the following: DOE Emergency Operations Center (EOC) (FTS-896-8100) EPA National Response Center (FRC) (1-800-424-8802) LEWO204.WP6 78

WD P-04 ') Rev. 4 Figure 6-2 Oh West Valley fluclear Services Substance Release Report Forrn Reported By: Date Times D e p ar t nient: Supervisors The following has been reported to Env.conmental Comp!!ance: Substance Released (Se specifich Date and time rolesse o< curred or was discovered { Fnvironmental Compilance person contacted: Probable source of discharge Location of discharges Amount released (be as accurate as poss6ble): Nearest location Of watet to discharge Responsible person / worm groups if aubcontractor is responsible, complete the following: Comosnv Names Addressa. Agent /

Contact:

Tel. s (Ve) If Eculament.1.0 nums er: Actions taken ano date resconoso to contain/ clean-up release : ( Possible naaith or fire nazaros resulting f rom disenarge7 i l lNO ( l YES (ex clain) l Substance Regulated by: I I N avigation Law /0N YCRR 613.8 (Petroleumi l 1 SARA i ! CERCLA l lRCHA Re porta 14e quan tit y: 1 1 Petroleum All o'te rs:

Reporteo to DOE-PO:

Names Oate. Time l l Reported to N YSOECi - 1 Names Date: Times I ( Report Completeo by: Dates ( .W V-173 4. Rev. 0 79

l WVDP-043 Rev. 4 DOE-ID (WCC) (FTS-583-1515) Region II EPA Energency Response Team (ERT) (1-201-548-8730) State Emergency Response Commission (SEMO) State Warning Point, Albany (1-518-457-2000) Local Emergency Planning Coordinator, Cattaraugus County (716-938-6631), and Erie County (716-846-6270) 6.4 Storage and Har.dling In addition to the oil and hazardous material or hazardous waste storage tanks or containetu discussed in the previous sections, a large number of containers and large amount of these materials are stored in various locations at the project. Storage in these cases will be according to the following guidelines and specifications: Materials shall be stored in such a manner as to prevent the occurrence of an extremely hazardous situation (fire, explosion, release of toxic fumes, etc.) in the event of a spill or a leak. Storage of hazardous materials must be in a designated area which meets requirements specified by the Radiation and Environmental Safety manager. These rem 11rements will be determined based on the magnitude and severity of the chemical hazards fo e s proposed facility. The following general requirements x.11 also apply for separation of incompatible chemicals. Flammables. Appendix A lists under Fire Hazards the degree of flammability of many of the chemicals stored at the WVDP. Highly flammable materials must be kept separated from explosives, powerful oxidizing agents, materials susceptible to spontaneous heating, or materials that react with moisture to evolve heat. Oxidizine Acents. The following classes of chemicals are known for their ability to supply oxygen, or in other words are strong ov.idizing agents: organic and inorganic peroxides, permanganates, perrhenates, chlorates, perchlorates, persulfates, organic and inorganic nitrites, organic and inorganic nitrates, iodates, periodates, bromates, perselenates, perbromater,, chromates, dichromates, azone, and perborates. In addition to storing these - materials separate from flammable / combustible materials, they should be kept separate from strong reducing agents, yater Sensitive Materials. Some materials react with water, vater solutions, or steam to evolve heat of flammable / explosive gases. Examples include lithium, sodium, potassium, calcium, rubidium, cesium, alloys and amalgams of f LEWO204.WP6 80 i

WVDP-043 _] Rev. 4 g the above, hydrides, nitrides, sulfides, carbidos, borides, silicides, and concentrated acids and alkalles. This should be taken into consideration in fighting fires involving these chemicals. Acid Sensitive Materials. Fire and explosive hazards exist from materials which react with acids and acid fumes to evolve heat, hydrogen, and flammable or explosive gases. These include lithium, sodium, potassium, cal.cium, rubidium, cesium, alloys and amalgams of the above, hydrides, nitrides, sulfides, carbides, borides, silicidos, tellurides, selenides, arsenides, phosphides, concentrated alkalies, cyanides, and metals, corrosives. Corrosive materials include acids, acid anhydrides, and alkalles. These have the ability to destroy their containers (if inappropriate containment vessels are used) and escape to the atmosphere. Some of these materials are volatile. Others may.eact violently with moisture. Corrosives.should be isolated from sulfides, sulfites, cyanidos, arsenides, tellurides, phosphides, borides, silicides, carbides, fluorides, and selenides. Reactions with these chemicals can produce toxic fumes. lf) In addition to' storing incompatible chemicals separately, other general safety practices are to be followed. For example, aduquate ventilation shall exist in all areas where chemicals are stored in appreciable quantities. Smoking shall be prohibited in areas where flammable and/or combustible materials are stored. In addition, storage areas should be equipped with adequate firefighting and spill response equipment. In all instances, storage of hazardous materials will be.in accordance with procedure WV-993, Storage and Usage of Chemicals. Appendix A lists many of the chemicals which_are used by the RVDP..This listing shall be used in emergency situations to determine-the degree of flammability of the material in question, health hazards, what to do in case of a spill or leak, extinguishing media to use in case of a fire, and general first aid in case of personnel exposure. LEWO204.WP6 81

WDP-043 Rev. 4 APPENDIX A .r i EMERCENCY CUIDES FOR SUBSTANCES USED AT Tile WDP Cuido Guido Name of_ Material No. Name of Materist No. Acetic Acid: 60 Barium Chloride: 42 Acetone: 26 Barium ~ llydroxide : 42 Ace tylene : 17 oarium Nitrate: 42 Alcohol: 26 Batteries: 60 Alkyl Polyether Alcohol: 26 Borax (Fused): 53 Aluminum Hydroxide: 60 Boric Acid: 59 Aluminum Nitrate: 35 Bromythmol Blue: 31 Aluminum Powder, Coated: 32 Buffer, 2.0 pH: 31 Alue.inua Powder, Uncoated: 40 Buffer, 4.0 pH: 31 Aluminum. Sulfate Solution: 60 Buffer, 10.0 pH: 31 Alurninurn Sulfate Solid: 31 Buf fer, 12.0 pH: 31 Amercoat Cleaner: 26 Cadinium, Shot: 57 Ammonia Solution w/>44% Ammonia: 15 Calcium carbonate: 31 Aminonia Solution w/Batween Calcium Chloride: 53 12 c. 44% Anunonia: 60 Calcium Fluoride: 53 Ammonium Acetate: 31 Calcium Hydroxide: 31 Ammonium Chloride: =J1 Calcian llypochlorite Dry,10 39% Amrnoniurn llydroxide: 60 Available Chlorine: 35 Amrnonium Meta-vanadate: 53 Calciuta Nitrato: 35 Amn. onium Moly #adate 4-Hydrate: 53 Carbtrol (Model L1) (Activated - Am:nonium Oxalate: 54 Charcoal): 32 l-Arnmonium Persulfate: 35 Caustic Boads: 60 1 L Ammonium 4. t' ate: 35 Caustic Potash (Koll): 60 l Antifre na. 26 Caustic Soda Flakes: 60 Argon, Compressed: 12 Corium llydroxide-60 -Argon, Compressed Liquid: 21 Costum Carbonate 54 Ascarite II: 60-Casiurn Chloride: 54 Barium: 40 Cesium Hydroxide: 60 l~ p LEWO204:6RM A-L l l I f L

WDP 043 l Rev. 4 l l l Cuide Guide Name of ffaterial No. Name of Material Nol Cesium Nitrate: 35 Hydrazine, <64% by Weight: 59 ) Chlorine: '!0 Hydtatine Sulfate: 28 Chloroform: 55 Hydrobromic Acid: 60 l Chromium: 31 Hydrochloric Acid, Anhydrous: 15 = Chromium, Powder: 31 Mydrochloric Acid, Solution: 60 Chromium Nitrate: 35 Hydrofluoric Acid, Anhydrous: 1; Chromium Oxide: 42 Ilydrefluoric Acid, Solution: 59 Citric Acid: 31 Hydrogen Peroxide, 35%: 45 Cobalt Nitrate: 35 Hydroxylamine Hydrochloride: 53 Copper Hydroxide: 60 Insolhote ET: 28 Copper: 35 Iron oxide: 37 Cupric Sulfate: 31 Iron Powder: 44 Cyclohexane; 16 Isopropyl Alcohol: 26

Dearborn Hardness Buffer:

31 Kodak Dektol Developer: 53 Diatomaceous Earth: 35 Kodak Indicator Stop Bath: 60 Diesel Fuel: 27 Lauthanum Nitrate, 6 Hydrate: 35 EDTA: 31 Lanthanum Oxide: 3 Ethyl Alcohol: 26 Lead: 42 Farric Chlorid.e: 31 Lead Oxide: 42 Ferric Hydroxide Slurry: 60 Lime (Hydrate 6): 31 Ferric Nitrate: 35 Lithium carbonate: 55 Ferric Phosphate: 31 Lithium Nitrate: 35 Ferrous Ammonium Sulfate: 31 Ludox Colloidal Silica: 35 Ferrous Chloride: 60 Magnes twn Carbonate : 31 Ferrous Sulfate: 31 Magnesium Chromate: 31 Formic Acid: 60 Magnesium Hydroxide: 31 Fuel Oil No. 2: 27 Magnesium Sulfate: 31 Casoline: 27 Manganese Dioxfde: 35 Clycerine: 26 Mercuric Iodide: 53 Hardness Buffer Code 521: 31 Mercureus Nitrate: 42 Heptane: 27 Mercury: 60 Hydrazine, Anhydrous: 28 Methanol: 28 LEW'J204:6RM A-2 I

VVDP-043

Rev, 4

Guide Guido Name of Material No. Name of Material No. Methylene Blue: 54 Potassium Hydroxide, Solution: 60 Methyl Isobutyl Ketone; 26 Potassium Hydroxide, Dry: 60 Methyl Orange: 54 Potassium Iodate: 56 Methyl Red: 31 Potassium Iodide: 60 Morton Pellets (NaC1): 35 Potassium Nitrate: 35 Naphalene: 32 Potassium Permanganate: 35 Nickel Hydroxide: 31 Potassium Phosphate: 31 Nickelous Nitrate, 6 H,"drate: 35 Povdine Iodine: 4? Nickel Powder: 42 Praseodymiur oxide: 31 Nitric Acid, Fuming: 44 Propane (LPC): 22 Nitric Acid, >40% Acid: 44 Pyridine: 26 Nitric Acid, <40% Acid: 60 RTV Protective Sealar 1890: 27 Nitrogen, Compressed: 12 Samarium oxide: 40 Nitrogen, Liquid: 21 Silica Cel: 35 Oakite Clearcoat: 26 Silicon Dioxide: 35 Oil: 27 Silver Nitrate: 45 0xalic Acid: 53 Silver oxide: 35 Perchloric Acid, <50% Acid, Soda Ash: 25 by weight: 45 Sodium Acetate: 35 Perchloric Acid, >$0%, but not Sodium Arsenate: 53 more than 72% acid by weight: 47 Sodium Bicarbonate: 60 1, 10 Phenanthroline: 31 Sodium Bisulfite: 60 Phosphoric Acid: 60 Sodium Borate: 53 Phosphorus Pentoxide: 39 Sodium Carbonato, Anhydrous: 35 Polyelph 975: 60 Sodium Chloride: 35 Potassium Bisulfate: 60 Sodium Fluoride: 54 Potassium Borate: 31 Sodium Hydroxide: 60 Potassium Bromate: 35 Sodium Meta Bisulfite: 60 Potassium Carbonate, Anhydrous: 31 Sodium Nitrate: 35 Potassium Chloride: 31 Sodium Nitrite: 35 Fotassium Chromate: 31 Sodium Phosphate: 31 Potassium Cyanide: 55 Sodium Sulfate: 35 LEWO204:6RM A-3

WDP 043 Rev. 4 Guide Guide Name of Material No. Name of, Material 2 Sodium Sulfide, Anhydrous: 34 Tannic Acid (Powder): 31 Sodium Sulfide, Hydrated: 60 Titanium Dioxide: 37 Sodium Sulfite: 31 Tributyl Phosphate: 60 Sodium Tetraborate: 53 Turco T 4368: 60 Sodium Thiosulfate: 42 Zine Brornide: 31 Strontium: 40 Zine Nktrate: 33 Strontium Carbonate: 31 Zine Powder, Nonpyrophoric: 32 j Strontium Hydroxide: 60 Zine Powder, Pyrophoric: 37 i Strontium Nitrate: 35 Zip Strip: 68 Sulfamic Acid: 60 Zirconium Dioxide: 37 Sulfuric Acid: 39 Zirconyl N'trate: 35 O l l LEWO204:6RM A-4 O l

WVDP-043 Rey, 4 l ~.N WYi?&A?Y,Q?~ NW?#, y,;; %.,, yh,.;z q 44 ", - y, y,.. c ,b; ("'?.. d*'s.\\.>l.' 'Qc? %.h n A u N $i.' N ..[ FIRt! OR EXPLOSION Flammable / combustible material; may be ignited by heat, soarks or flames. May ignite other combustible materials (wcod, cacer, oil, etc.). Container may exotode in heat of fire. R.t : ition with fuels may be violent. Ru..off to sewer may create fire or exotosion fiazard. HELALTH HAZAROS May be f atal!! Inhaled, swallowed or abscreed through skin. Contact may cause burns to skin and eyes, Fire may produce irritating or poisonous gaaes. Runotf from fire control or dilution water may cause pollution. 3 EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay uowine keep out of low areas. Wear self<l:ontained (positive pressure if available) breathing apparatus and full protective clothing. FCR EMERGENCY ASSISTANCE CALL CHEM 1Rt!C (800) 424 9300. if water octiuttr~ occurs, notify accroortate authorities. b FIRE Smett Fires: Ory ettemical, CO,, water spray or foam. Large F1ros: Water soray, fog oc fcam. Move container f rom fire area ll you can do Lt without risk. Cool containers that are exposed to llames with water from (ne side until well aflei fire is out. For massive fire in cargr., stea. uAe unmanned hr.,se holder or monitor noz:!as;if this is imoossnble. *? draw from area and tot fire burn. SPILL O R L*'.AK Shut of f ignittor, sources; no itai 3s, smokMg or flames in hanrd area. Keeo comoustibles (wood, cicer, oil, etc.) away f rom spillec material, (Jo not touch spilled matenal. t. Smelt Spitts: Take up witn sand or otner noncombustible aosortient material and place into containers for later disposal. Large Spills: Cike far anead of spilt for latei disposal. FiRST A10 Move victim to fresh air; calt emergency medical care. u If not breathing, give a.tificial respiration. g._ !! breathing is dlf ficult, give oxygen. E, in case of contact with material,immediately flush skin or eyes with runrung water f or at least 15 m:nutes. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normat body temperature. b:i 5 t6 b.o

WVDP-063 . C Rev. 4 O , ;, e.~ g%.?. ',.'*,tN; -, &> f.,'.x.f,.j,*:. ',._.,* ;*.. l,y.-- .r>> ,s>.'..%.:. 3 9, p,, .,, m. ..s 5 ~t "' ^ . Y.. ?. .3 GU ! k i.h/ ([, s.l '.,.3 E,' 4 k.e. r Sp ,. (,f,? #P,> S y' ~. ' -..,.e m, -e se y ~.... .. POTENTTAt.HAZAflD@j.ligffy#M. N', ', 'k,+y .i. FIRE OR EXPLOSION' ,J Some of these matertals may burn but none of thern Ignate readily. Container may explode in neat of fire. HEALTH HAZARDS Vapors may cause dizziness os suffocation. Contact with liquid may cause frostbits. Fife may produce irritating or poisonous gases. EMERGENCY ACTION Keep unnecessary pecole away; isolate nazard asoa and deny entry. -) Stay ugwing kano out of low assas. Wear self c*intained (posal.ve Deessure il availaDie) baeanning acDatatus and tuli y,totectne clothatiq. FOR EM EAGENCY AS$1STANCF, CALL CHEMTREC gaco) a2a.3:100. l FIRE Small Firgs: Cry encinical or CO,. Luge Fires: Water spray, tog or loam. Move contamor from live area if you can do it without nsk. Stay away from ends et tanas. Cool containets that 4:e encosed to llames with water from the side until well aftef fire is out, Wisharaw immediately m case of r sing sound from ventmg safety dev6ce or any discoloration of tanks due to fire. SPILL OR LEAK Stoo leak if you car co it witnout rism. FIRST AlD p Move victim to fresa air, cast emergency mecical care. Il not breatning. Qive artificial respiration. 11 Dreathing is dalf tcult, give oxygen d 4 ) O m A-6

WVDP-043 Roy, 4 0 4 ) !e . y pp.iw%d. 2 -- p', f '.j,'[' p ~ 3 ,~3 WDM*hygh;[(,*'gs,.'&yy.'&R k) 6.~; P HEAT.TH HAZARDS Poisory enttvtmely hazardous. May tia f atalif innaled or ~ Dsorted through skirt Vapors acepittttating but deaden sense of smell, Runof f from fire control or dltution water may cause collutton FIRE OR EXPLOSION Some of these matetials are extrerriety Itammabia. May be igniteo by ne at, sparks or flarmes. l" Vapors may travel to a source of ignitwn and flash bacA Contamer may osotodo in neat of fire. Vapor explof on and poison nazard indoors, outdoors or m sewers. i:t j EfAERGENCY ACTION, Keep unnecessary oecote away; isolate nazard a:ea and deny entry.

4tay uDmind; keep out of low areas, l

Ventstate closed Spaces Defore entering them, Wear positive pressute breatning accaratus and special protective cloinmq

9..)

Evacuate area endangered by gas.(Oce tsolation ana Evacuation Taole in back of guidebook; find the material by name.) Isolate for il2 mile in all directions ll t and car or truck is invoued in fire, {Q FCR EMERGE!4CY ASSISTANCE CALL CHEMTREC (800) 4;:4 9300. FIRE 't Small FItas: Let curq unless irik can be stooped immediately. 1 orge t lter Wster spray, tog or team. i Move contatrier from fire area st you can do it without risk. Star away from ends of tanns. Wilndraw immediately in case of rising sound from versting safety cevice ce any discoloration of tank due to fire. Coot container with wate' using unmanned device until well alter five is out Isolate ares until gas nas ciscersed. SPILL OR LEAK Do not toucn spilleo matstrial; stoo leak if you can do it withoul risk. $ nut of f ignitton source s' no itares, smommq or Itames in natard area. 4 Use water spray to reduce vapors. ~ b isolate area until gas nas disperseo. FIRST A10 9 Move victim to fresn air; cati emergency medical care If not breatnmg give artificial resoiratiert i ^ it brealning is e thcult,give osygen in care of contact with material, immeciately fluin skin or eyes witn runnmq I water for at least 1$ minutes. Keep victim quiei and maintain normal body temperature. Elf ects may be detayad. keep victim under ormtvation s,

_.~ - WVDP-043 Rev. 4 y. s.p 3. -e. q ;,.. 3.:.; g. -_ y. s;s p w 1.,e.% w g 4 y ,:. dett4W. P,ip/;:aw.nn;nbs.,a@ ..n mn 4; ut g m,,. g. ~ ~ HAZAR' W ),W M Ly.3. Q

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t FIRE OR EXPLOSION May ignite other comous:lble matei'os (wood, paper, oil, etc.). Mixture with fuels may explode. Container may explode in heat of fire. Vapor exDiosion nazard indoors, outdoors or in sewers. HEALTH HAZARDS Contact with tiquid may c.tuse f rosteile. Vapors may cause diz:inees or suf1ocation. Fire reay produce irntating or poisonous cases. JMERGENCY ACTION y I Keep unnecessary recole away; isolate hazard area a.id deny entry. Stay nowind: keep out of low areas. Ventilate closed spaces before entering them. Wear self. contained (positive pressure 11 availacle) breatning apparatus and full protective clotning. FOR EMERGENCY ASSISTANCECALLCHEMTREC(800)a::4 9300. - J FIRE Small Firec Ory chemical or CO,. Large Firec ater spray, fog or foam. Move container from fire area if you can do it without risk. Stay away from ends of tanxs. Coot contamers that are exposed to llames witn water from the side until weil j Mist fire is out. i Fer massive fire in cargo area. use unmanned hose noider or monitor ncates;if this is imposs.bts, witncrsw from area and let fire burn. l EMLL-OR LEAK Xeeo comaustibles (wood, cacer, oil, etc.) tway : rom spilted material. Sta taan if you can do it witnout rism. !toia.) sca until caa nas dispersed. F1837 Alc Mov6 Actice to fresh air; call emergency medical care. Keep victim Quiet and maintain normal body temperature. . i 3 e a e A-8

WV0P-043 Rev. 4 l I v f: gr* L i' ,. 7 4,. ;.%g.i9 7 Q6A. r i <,,7flQy 7 'Fw

y ;

C o Q',~3.._ Y .,9i.f'%.n,~~;' J., U itf.'.$sy.., -:.. .m :.yg.,,m(#0TENTfACHAZAR Y e h + HEALTH HAZARDS i.li Poisonous; may be f atal if inhaled. Contact may cause eurns to skin and eyes. Contact with liquid may cause Ircsteite. i Runoff from fire controt or dilution water may cause pollution. i FIRE OR EXPLOSION Some of these matettats may eurn bu4 none of them ignite roadily Container may explode m heat of fire. i EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry ,*: 4, Stay uowmd; keep osit of low areas. t. Ventilate closed spaces before entermq them. Weat positive pressure creathing apparatus and full protective clotning. Evacuate area a.snge ed by gas. (See isolation and Evacuation Tacte :: cack }<' of guideocon; find the matert:J by name.) FOR EMERGENCY ASSISyANCE CALL CHIEMTREC (800) 4:4 9300 J If water collution occurs, notify accrooriate autnottoes. 1 FIRE k Smail Fires: Ory enemical or CO,. Large Fires: Water spray, fog or foarn. Do not get water inside centamar. 0' Move contamer fr*3m fare area if you can do it without risk. Stay away from ends of tanks. Cool contamers that are esposed to Itamos witn water from ine side until well af ter fire is out. Isolate area uitti gas nas dispersed. {ff - ilj SPILL OR LEAK Stoo lesk if you can do it without risk. Use w stor sorsy to reduce vauor cut do not out *ater on teak or spill area. 4. (a i Sms.15pitis: Flush area witn itocomq amounts of water. large Soltis: 06ke f ar ar.4ad of sosit for later disposal. Du not get water inside container, isolate a.ea until gas nas dispersed. g !,[. Fit.aT A1D Move victim to fresh air; catt emergency medical care. if not breathing, give artif,cial resDiration. 3, f.4 If breathmg is dif ficult. Give o8y9en. Aemove ar.d isolate contaminated clotning and snoes :.4 the site. w In case of contact with material. immediately flusn skin or eyes witn rurming water for at least 15 mmutes. Keep victim quiet and (naintam normal body temocrature. Elf acts may be delayed; keep vv; tim under ooservation s a A-9

WVDP 043 ~ Rev 4 O 'YNf$"$5 }; G

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+- ~~ Mi.. A ..w, . e v .,Q Mk,POTENTTAEHAZARDSWh.;.k. Scy,1 ~, HEALTH HAZARDS 1f inh nied, may be harmful. Vapot exuemely irritating. Contact may cause burns to skin and eyes. Contact 'mith liquid may cause frostbit e. Runoff from fire C70 trol or dilution water may Cause pollution. FIRE OR EXPT,OSION Some of these materials may burn but do not ignite readity. Container may enolode in nest of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwmo; keep out of low areas. Ventilate closed spaces esfore entenng them. Wear self.casiaired (positive pressure if availaele) creathing accara'us and full protoc 'ive clothmg. FOR EMERGENCY ASSISTANCE CALL CHEMTREC (800) c4 9300, if water pottution occurs, notity accropriate authorities. FIRE Small Fires: Ory chemical or CO i p Large Fires: Wate< spray, tog or team. Move contamer from fire area if you can do it witt.out risk. Stay away fiom ends of tanks. Coot containers that are exposed to llames with water from the side until well af ter fire is out. Isolate area unti! gas nas dispersed. SPILL OR LEAK Sto i teak if you can do it without risk. Use water spray 'o recuce vaoor out do not out water on ieak or soill area. Isolate area until gac has dispersed. FIRST A10 Mcse victim to fresn air; call emergt :y medical care. If not breatning, give art'ficial resc;4ation. If Dreathing is delticult, give oxygen. ,j Remove and isciate contaminated clotning and snoes at the site. ] In case ni contact with matenal. iminediately flusn skin or eye wit 1 rutining water for at least 15 minutes. Keep victim quiet and maintam normal body temperature. 9 A-10

._m.. WVDP-043 Rev. 4 ((- ^^ f*' yy. ..,fmsffsp w.. ?.m. q u r AN -- >w'.w-., Vwqu[ ' ;; ' B', N.),j f1PUTENTTJttH FIRE OR EXPLOSION v.. E.stremely flammacte. M sy be ignited Dy heat, scarks of Itarnes. Vapors may travet to a source of ignitton and flasn back. CCalainer may explode violently in heat of fire. g Vapor explosion hazard iadoors. *utdoors or in sewers. HEALTH HAZARDS If Innaled, may be harmful: contact may cause burns to skm and eyes. Vacors may cause dimness or sulf ocation. L. Contact with flouid may cause l*<istDate. Fire may procuce irritating or poisonous gases. EMERGENCY ACTION ~~em.tes. Keep victim quiet ano, tain normal body temperature. ~ 1 A-13~~

WDP-04 3 Rev. 4 t cede zadigt M E TIMTP 5 "y ".j [.f . N pk3ThihA h N. E HEALTH HAZARDS l Poisonous; may be f atalllinhaled. Contact may cause burns to skin and syn. Contact with liqusd may cause frostbets Runoff from fire control of dilution water may cause pollution. FIRE OR EXPLOSION May ignite other combustible matettals (wood, papet, oil, etc.). Mixture with fuels may explode. j Contamer may esplode in heat of fire. Vapor expecsson and poison haaard indoors, ould, ors or in sewers. EMERGENCY ACTION -] Keep u.inecessary peccle away; isolate haaard area and deny entry. j Stay vow 6nd; keep out of low areas. Veutilate closed spaces before entering them. Wear positive pressure breathmg apoatatus and full protectivs clothing. Evacuate area endangered ey gas. (See isolation and Evacuation Tabte in baca of guidebook; find the material by named FC A EMEBCENCY ASSIST ANCE CALL CHEMTREC (soo) 424 9300, it water pottution occurs. notify aooropriate authorities. FIRE - Sanalt Fires: Ory enemical of CO, e Large Fires: Water spray, log or team. Move centamor from fire area il you can do it without nsk. Stay away from ends of tanks. Cool contamers that are eironted to flames with water from the. side until weil altet tire is out. For trassive fire in cargo area. use unmanned nosa noidet et moneter not.Ites;if tnis is impossitate, witnotaw from area and let fire burn. SPILL OR LEAK Keep comnustibles (wood, pacer, oil, etc.) away f rom spilled matettan. 5too leam il you can do it witnoui nsk. Use wa at spray to reduce var'or but do not out water on leak or spill area. Isolate area us

~~I gas nas osspersed.~~
FIRST A10 Move victim lo itesn air; call emergency medical care, if not breatning, give aristicial tesoitation. If breathmg is oilficult,give oxygen. Remove an# isolate contaminated clothmg and snoes at the site. i* case of contact with matenal,immediately ttush skm or eyes with tuntung tater for at least t$ mmutos. r} neep victim quiet and mamtam normal bocy temperatute. Etlects may be deiayed: keep victim unoet ooservation. x ) A-14
U WDP-043 J Pav. ?- ?' S Y .g 3 e i FIRE OR EXPLOSION CWloot Catch fire. 4 Cootainer may exotode in neat of fire. + HEALTH HAZARDS Vacors may cause damness or suf f ocatiott Contact with licuid may cause frostette. EMERGENCY ACTION Keep unnecessary oeople away; isolate hasard area and deny entry. Ventilate closed spaces before entesirig them. Stay ucwind; keep out ollow areas. West self contained (positive pressure il availac!s) creathing apparatus and full Drotective etething. FCA EMEBGENCY ASSGTANCE CALL CHEMTREC (600) 424 9300 r~ FIRE Move container from fire area if you can do it without risk. Stay away f rom ends of tanns. Cool containers that are escosed to flames with water from tne side until well I af ter fire is out. SPILL OR LEAK Oo not touch soilled material. Stoo leak if you can do it without nsa. FIRST A1D Move victim to fresn air, call emergency mecical care. il not treathing, give artificial respiration. ~' Il breathing is cilficult, give caygen. In case of frosteita, thaw trestaa parts with water. Keep victim quiet and maintain normat occy temperature. p I.I %? pk ?h Il} u .ti c; a IE
WDP-04 3 Rov, 4 0 ~ L / :'; :3J.*1wA NRK3ty pq. Q ' ._%eergsyy .i 4 hk , c. ; g if.;- O POTENTIAChAZA,R MTj<}Qh FIRE OR EXPT.OSION Extremely flammable; may be ignited by heat, sparks or ftames. Vagors may travel to a source of ignition and flash back. Containst may exolode in heat of fire. Vapor eapionion nazard Indoors. outdoors or in sewets. HEALTH HAZARDS Vapors may cause dizziness of suflocation. Contact will cause severe frostbite. Pka may produce irntating or poisonous gases. EME9GENCY ACTION Keep unaecessary people away; isolate na23rd area and deny entry. .i Stay uowind* heep out of low arena. Venttiste closed soaces before entermg them. Weat self<:entained (positive pressure il availablel breatning accaratus and full protectes e clotning. Isolete lot 112 mile in all directioris If tank car of truck is involved in tire. FOR EMERGENCY ASSISTANCECAlt.CHEMTREC(800)4:4 000. FIRE Let tank car, tank truck or storage tank burn unless lean can be stooped; with hmallet tanks or cylinders, extinguistuisolate from other flammables. Smell Fires: Oly enemical or CO,. Large Fires: Water spray, f og or f oam. Move container from fire area il you can do it without nsk. Stay away from ends of tanks. Coot contamers inat are exoosed to flames with water from tne side until well aflef fireis out. For massive fire in cargo area. use unmanned nose noicer or monitor noI2f es;il this is im; ossible, withdraw f rom area arid let fire burn. witndraw immediately in case of rising sound from venting safety avic or any discoloration of tank due to fire. SPILL OR LEAK Shut off iginition sources; no flares, smoking or flames in nazard area. Do not touc cilleo matertal; stoo lean il you can do it without risk. Use water soray to reduce vapors;isotate area until gas nas dispersed. FIRST A10 Move victim to f resa air; call emergency medical care, if not breatning, give artificial respiration, il breathing is dif ficult, give oxygen. In case of frostente, thaw frosted parts witn water. Keep victim quiet and mamtana normal body temperature. O A-16
q,cy 'M (O -s e o //. N<..A e tr t @'< gu' IMAGE EVALUATION P [Off %)he TEST TARGET (MT-3) / / [jfh (g \\syjV gr, @ (gp tg'%y;< 'WN ,.o w - 5 E e u. ele j,l e. mm ,,u = L25 1.4 I i.6 il =
=
4 150mm 4 6" h DI? $ $o\\ op; fy/ NNgf 4a ,p gg:a, ////4 v x yo of <p qe sp // 1
As ,;, i &e /t0 g+9q, c A ., Ajs , 0 1 V IMAGE EVALUATION A% s \\/,g///'i[' kf? TEST TARGET (MT-3) j(([],A, / jj //// / t'* q R'\\s$ 4 k O,, g p v\\ e 3 1.0 lta 52 u ta g 2.2 [_ g ine-m 2 'M llllh? 1.1 e i1 !!l 1.8 dires 1.25 ill I.4 P i.6 Ili lL= 15omm 6" %r ++ss+ &r%4k, +,, a,p/ + e ,<,.,n i, ms <.: ? 4Q?h \\ N>, o, et*e t +;4g
.yh l0 A , %s vv@.T'h IMAGE EVALUATION t [' ig N //o// TEST TARGET (MT-3) </ 4'[ 4 \\ N Rh9 Il[g y + v I.0 WM W m g:w1 1_ i g, Qle=2 1 ': n. l 1,l e l -- M8 B11.25 ' IIA i.6 !I l- . i== r-4 15 0 m m --- 4 S" b% + /A' y A + s %2sy,%y . A,93Q/4 'l l w g / Oy/7 9,y v blh.a j<
WVCP-043 ev. 4 j .f i[P _______nsam i % I FIRE OR EXPLCS!CN i May igruta other computtible matertais (wood, paper, cel, etc t j Mixture with fuels may exploom l Container may excioco in neat of fire. Vacor stolosion nazarc indoors, outcoors or in Sewers. Hl: ALTH HAZARDS Vapors r"ity Cause ci2Ziness or suf f CCatton. Contact will cause severe trosteite. Fire may croduce erntating or poisonous gases. EMERGENCY ACTION i Kro unnecessary cecote away; isolate nazara area and ceny entry. Stay uowine keep out of low areas. Wear self containec (positive cressure if available) Dreathing apparatus anc ! y' full protective ctotning. Isolate for it2 mile in all cirections il tank car or truck is involvec in fire. l FCR EMEAGENCY ASSISTANCE CALL CHEMTREC (800) 324 9000. '\\ FIRE [D Small Fires: Dry.nemical or CO,. Large Fires: Water scray, tog u foam. Move container from fire area if you can do it without nsn. Stay away from encs of tanks. ', i Coot containers that are exocsec to flames witn water irom the side until weil af %r fire is out, For marsive fire in cargo area. use unmannec hose noscer or monitor } noces:if tNs is impossacte, withcraw from area and let fire turn. SPILL OR LEAK Keep comousticles (wood, pacer, oil, etc.) away from scillec maternat. Do not toucn scellec matenat. Stoo lean it you can co it without tism. J.~ isolate area until gas nas ciscefsec. l j FIRST A!D .i-Move victim to tresh air' Call emergency medical care t.. Remove and isolate contaminalec Clothing and shoes at the site i l in case of f roataite, thaw frostec pa6ts with water. WMo victtm quiet and maantasa norman Docy temperature. { t I^)' e h J 6 =. 1 i %. / i A-17 i l
WVDP-043 Rev. 4 i O-eIid$$$3[$@A 'N[STYy% @3 1 hhh . 4,5'M$ vi ~ s -H- - ;-n. ~. i FIRE OR EXPLOS10N May be igruled lf carrter liquid la flammaale, i HEALTH HAZARDS '( I Contact with matenal may cause infection and disease. Runoff from fl<e control or cllution water may cause pollution. i _ EMERGENCY ACTION l-Keoo unnecessary cecole away, FOR EMEAGENCY AS$1 STANCE CALL CHEMTAEC(800) 4:a 93Co. 7 l tf water cottution occurs, notify accroonate autnorities. l FIRE s l Small Fires: Cry chemical, soca asn or time. Move coatamor from fire area if you can do it without risk. .} i SPILL OR LEAX l Do not touch damaged containers or spilled material Damage to outer container may not af fect crimary inner container. 11 inner container damaged or leaking, cover wim camp towet or #ag and seen i wet witn liquic tieacn (Ctoros. etc.) e Spills: Oike for later cisocsal. C!sanuo onsy under suoervision of an excert. FIRST A10 Move victim to f resh air *, call emergency mecical care. In case of contact witn material,immeciately tiusn eyes witn running water for at least tS minutes. Wash skin with scao and water. Remove anc isolate contaminated clothing and shoes at the site, l 1 l i 1 ( i I O A"18 1 a
WOP-043 Fev. 4 iiL f M.T?ln @ p4k%MtWtt.*:f & S; gl l. y & Q W~_ p - 9 a.-% +,t 4:j;-( [ ]i ;, C-C[gi.h.q., QNPOTENTTACHAZAR jEp[l.Q il-HEALTH HAZARDS ~ Possonous; may be f atal if inhaled. Vacor extremely irritatmg. Contact may cause burns to ymm an e res. Runoff from fire control or dilution water may cause collution. FIRE OR EXPT.OSION l May ignite otner comousticle matertals twcod, cacer, oil, etc4 l-j M6sture with fuets may exploce, Container may exotode in heat of fire. t Vapor exotosson and poison nazard indoors, outdoors or m sewers. t EMERGENCY ACTION Keep unnecessary pecote awsy; isolate Nazard area and deny entry. Stay upwmd; keep out of low areas. Wear positive pressure breathing accaratus and special protective clothmg. Evacuate area endangered by gas. lsee Isolation and Evacuation Table m cack of guidecook; find the material ey namea FCR EMEAGENCY ASSIST ANCE CALL CH EMTR EC (800) a:s.93od. _p if water collution occurs, notify acercoriate autnorities. ( I FIRE 't-Sm all Fires: Cry enemical, soda asn or time. Large Fires: Water soray, fog (ttoccing amountsk Oo not get solid stream of water on liquid occi. l Do not get w ater inside centamer. Move centamer from fire area if you can do it witnoul ask. For massive fire m cargo area, use unmannec nose noncer or monitor noz:les;il this is impossible, withdraw from area and let fire Durn. SPILL OR LEAK If you have not donned soe ial protective clothmg accroved for this material. do not expose yourself to any rism of Inis maternat toucning you Stoo leak if you can co it witnout risk Use water spray to reduce vapors out do not out water an ieam or soiti area. Isolaea area until gas nas ciscersec A fine water spray acolied to I,ne edge of tne spill or ol will start a not ttate fire whicn will burn the spilled maierial tuse entrem s caution 1 I FIRST AfD Move victim to fresh air; call emergency medical care Il not breathing, give artificial respiration. l Il breathmq is ditficult, give osygen Pemove and isolate contaminated clotnirig and snoes at the site. in case of contact with malettal,immediate6y ttusn skin or eyes witn tur iing water for at least 15 minutes. K eep victim quiet and maintam normal cody temperature. Elf ects may ee detayed; keep victim uncer ooservation 1 ( A-19 - - ~ -
l WVDP-043 SQV. 4 l l kh,,. w 1 -.,.c ~r r:" -e '1 u ' b -. a d3*e it.- 2 . j. M p'fp, f,',POTENTTACHAZAS@kM f l FIRE OR EXPLOSION FlammaDiescomeustible malettal; may be ignited by heat, sparks or flames. Vapors may travel to a source of ignition and flaan back. Containst may ezoloce in neat of fire. i. Vapor explosion hazard incoors, outcoors or in sewers. ..I I Runoff to sewer may create fire or explosion hazarc. l HEALTH HAZARDS y May be poisonous if Innaled or aesereed intougn skin. Vapors may Cause cluiness of suf focation. Contact may irntate or eurn skin and eyes. l Fire may procuce irntating or poisonous gases. Runoff from fire control or citution water may cause collution. EMERGENCY ACTICN Keep unnecessary pecole away; tsotate nazard area and ceny entry. Stay vowinc; keep out of low areas. Wear self<:entained (positive pressure il availante) creathing acoarttua and ,4 full protective clotning. Isolets for 112 mile in all directions if tant car of truck is involved in flie. FCR EMERGENCY ASSISTANCE CAi.L CHEMTAEC(800) 4:4 9300. 11 water pollution occurs, nohty accrocriate autnorities. 1' i FIRE Small Fires: Cry enemical, CC,, water spray of alconos foam. f Large Fires: Water spray, tog or alconce foam. Move container from fire area if you can do it witncut risk. Coot containers that are exposed to flames witn water from the side until nest af ter fire 63 out, l. For massive fire in cargo area, use unmanned nose noncer or monitor noutes;if tnis is impossicie, withcraw from area and let fire eurn. Witncraw immectately in case of rising souno from venting safety cevice or i any discoloration of tann due to fire. { SPILL OR LEAK I Shut off igniuon sources; no f!"es, smaning or riames in na:ard area. Stoo is ak if you can co it witncut risk. l Use ws>ter sotay to recuce vapors. Small Jolita: Take up with sand or otner noncemeustible absoreent material and place into containers for later disposal. Large Soills: Cike fat anead of spill for later ciscosal FIRST A1D Move vtctim to f resn air, call emergency medical care, if not efeathing, give artificial respiration, f tf ersatning is cilficult, give oxygon. l In case of contact witn material,immediately flush eyes with running water for l at least 15 minutes.Wasn sain with soao and water. I Remove and isolate contaminated clotning and snoes at the site. l A-20 l f
WVDP-Ca3 ?ev. 4 FIRE OR EXPLOSION Flammableicombustable matettal; may be ignited by neat, sparks or f tames. Vapors may travel to a Source of ignition and flash back. Contamor may explode in heat of fire. Vapor enDioenon na.tard todoors, outcoots or m sewers, Runotl to sewer may create tire of emplosion nazard. s HEALTH HA2.ARDS May be poisonous ilinnaled or absorbed througn sain. Vapors may cause dit:iness of sultocation. Contact may irritate or burn skin and eyes. Fira may produce irntating or poisonous gases. Runott from fire control or citution water may cause poetution, EMERGENCY ACTION Keep unnecessary oecote away; isolate nazard ates and ceny entry Stay uowind; keep out of Icw areas. Wear self-contamed (positive cressure it avai aole) breathing acoaratus and l i' full protective clothing, iscesi. "* tt: mite in all directions if tank c ar or truck It involved in fire. FOR EMERGCNCY ASSISTANCE CALL CHEMTREC (800) 4:a n00. It water cottution occurs, notif y accrooriate authorities. FIRE Sinait i tres: Cry enemical CO,, water seray or team Large Fires: Water spray, tog or team Move container from hre area il you can co it without nsa. 3 Coot containers that are eiioosed to flames with mater from the side until aeit af ter fire is cut. For massive fire m cargo area, use unmanned nose noicer or monitor noZ21es;il this is impossible, withdraw from area and let fire Qurn. Withdraw immediateiy m case of rismo sound from venting sately device or any discoloration of tana due to fire. SPtLL OR LEAK Shut off ignation sources; no flares, smoning or flames in nalard area Stoo team if you can do it witnout rism. Use water soray to reduce vapors. Smett Spills: Take up witn sand or otner noncomoustible aesorcent material and place into containers for later ciscosat. Large SMlls: Cike f ar anead of soint forlater disposat. FIRST A10 uove victim to tresa air; r att emergency medical care. Il not breatning, give artificial respiration. It breatnin 3 is dif ficutt, give ouygen. in case of contact witn material, immediatety flush eyes with running water for p3 i-et feest tS mmutes.Wasn skin with saao and water Remove and isolate Contammated Ciotning and snoef at the site. J s A-21 - - - - - ~ _ _ - _ _
WVDP-M 3 Rev. 4 e ' W ~=s %Vy.g: h%> ' '. ..g7.fgi4.g ~ ?,-
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w ' n HEALTH HAZARDS Poisonoua; may be f atalif Inhaled, swallowed or absorted through skin. Contact may cause turns to skin and eyes. Runoff from fire contros or dilution water may cause pollution. FIRE OR EXPLOSION Flammable /comaustible matenal: may be ignited ev neat, soarks or flarn Vapors may travel to a source of ignitim and flash Pack. Contamer may enciode in heat of fire. Vapor exoiosion and poison hazard Indoors, outdoors or in sewers. Runoff to sewer may create fire or esososion nazard. _ EMERGENCY ACTION Kee0 unnecessary DeoDie away; isolate nazard area and ceny entry. Stay uowind: keep out of low areas. Wear positive pressure Dreatnmg accaratus and spectat protect #ve clothmge isolete for 112 mile in all directiores il tank cat or truck is invoJwed in fire. FCR EMERCENCY ASSISTANCE CAL.L CHEMTREC 4800p:a.noo. 11 aater poltution occurs, notify apotopriate authorit es. i FIRE Small Ftres: Cry chemical. CC,, a-ter spray and roam. Large Fires: Water spray, fog or : cam. Move contamer from fire area if you can do it without risk. Dilie fire control water for later discosal; do act scatter the material. Coci contamers tnat are esposed to Itames witn water from the side until weit after fire is out. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to lire. SPILL OR LEAK Shut off ignition sourci.s: no flares, smoking or flames m nazard area. Do not touch spilled material; stop teak il you can do it without risk. Use water soray to reduce vapors. Small Spells: Take up with sand or other noncomoustible absoreent material and place into containers for later oiscosal. Large Scills: Oike f ar anead of spill for later disposal. FIRST AlD Move victim to tresn air; call emergency mecical care, if not creatnmg, g.,e artificialiespiration. If breatnmg is difficult, give cuygen. Remove and isolate contaminated clothing an<t shoes at the site. In case of contact with matenal, immediatety flusn skin or eyes with runnmg water for at least 15 minutes. Keep victim quiet and maintam normal body temoetature. Elf ects may be deiayed; keep victim under ooservation. O A-22
WCP-33 Rev. 4 i D Q? Eh$y hey.x8 V",, e.*ygg g h f FIRE OR EXPLOSION Flammaelercombusttele material; may be ignited by neat, sparks or flames, Vapors may travel to a source of Ignition and flash back. Contamor may explode in heat of fire. Vapor explosion nalard inocors, outocors or in sewers. Runoff to sewer may create fire or explosion hasard. HEALTH HAZARDS !! inhaled, may be harmful; contact may cause turns to skin and eyes. Fire may produce irritating or poisonous gases. Runof f from fire control or calution water may cavse coilution. EMERGENCY ACTION Keep unnecessary peoDie away; Isolate ha23rd area and deny entry, 'i ' Stay unwind; keep out of low areas. i-Wear sent contained (positive pressure af available) breathing apparatus and full pretsttive clothing. Isolate for 1/2 mile in all directions if tenk car of truck is irivolved in lire. FC A EMERGENCY ASSISTANCE CALL CHEMTREC (800) 4:4 9300. It water pollution occurs, notify approoriate authorities. FIRE li Some of these materiais may react violenoy with water, Small Fires: Cry enemical, CO,, water scray or foam. Large Fires: W ater spray, fog or f oam. Move container f rom fire area il you can co it witnout nsk. Oo not get water inside container. neil b. Coot containers that are exposed to flames with water from tne side until af ter fire is out. Withdraw immectatety in case of rising sound from venting salety cevice or r any discoloration of tanti cue to hre. l " SPILL OR LEAK Shut off ignition sources; no flaies, smowing or tiames in nsaard area. Do not touch soilled maleflat, stoo leat if you Can do it witnout rism, tb Vs4 watef sOray to reduce vaDors; do not get water inside Container Smeil Spills: Tame up witn sand at otner noncomcustiDie aosortent material and place into containers f or latef disDosal. r. Large spills: Oike f ar anead of sotil for later ciscosal. j, FtRST AlD Move victim to fresh air; cast emergency medical care. il not breatning, give atlificial respiration. If breathing is catticult, give cuygen Remove and isolate contaminated ctotning and snoes at tne site. In Case of Contact with material,immediately flusn skin or eyes witn running water for at least t$ minutes, Keep victim quiet and maintain normal; cy temperature. \\ A-23
WVDP-043 Rev, 4 1 9' eiiE4 M B % 5*ds@r 1 -] 'Q $' tPQ1EN(RACHAZARDS$$ gh %. g HEALTH HAZARDS J Poisonous: may be f aiat il innaled, swallowed or absorbed through skin, Contact may cause turns to skin and eyes. Runoff from fire control or dilution water may cause pollution. 1 FIRE OR EXPLOSION Eatremely flammaele; may be ignited by neat, spark's, or llames. Vapors may travet to a source of ignition and itasn back, y Contamer may expiece violently m neat of fire. Vaoor oclosion and poison nsaard indoors, outdoors or m sewers. Runoff to sewer may create fire or exo60sion hazard, EMERGENCY ACTION i Keep unnecesaary people away; isolate natard area and deny entry. i Stay uowind; keso out of low areas. Wear positive pressure creatnmg accaratus and special protective clothmg. Isolate for 1/2 mile in ett directions if Iank car or truct is involved in fire. ( FOR EMERGENCY AS$lSTANCE CALL CHEMTREC(800)a:a 9300, !! water pollution occurs, notify sopropriate autnorities. FIRE Small Fires: Ory enemical, CO,, water sotay or foam. 1.arge Fires: Water scray, fog or foam. Stay away from ends of tanks. I Do not get water maide contamer. Coot contamers that are esposed to itamos witn water from the side until weil af ter fire is out. For massive fire in cargo area, use unmanned nose noider or monitor noz:les;it tnis is impossiete, withdraw from area and let fire ourn. Withdraw immediately m case of rising sound from venting safety device or i any discoloration of tana due to fire. SPILL OR LEAK Shut of f ignition sources; no flares. smokmq ot !!ames m nazard area. Do not touch soitted material; stoo lean il you can do it without risk. Use water sotay to recuce vapors; do not get water mside contamer. Srnell Spills: Flusn atea witn floodmg amounts of water, Large Spills: Oike far anead of soill for later ciscosal. FIRST AfD klove v.ctim to fresn air, call emergency medical care. 11 not creatnmg, give artificial resoiration, il breatnmq is dif ficutt, give oxygen, Remove and isolate contammated clothing and shoes at the site. In case of contact with material. immediately ftusn skin or eyes with runnmq -i water for at least 15 mmutes. Keep victim cuiet and maintain normal body temoerature. Ef fects n 4y ee deiayed; keep victim under ooservation. O A-24
WCP-042 Rev. 4 / 4.,,,ti.:s,s.,>;.+,rp, ~ . [.. gs, v $ 3 4 4,( j p :3 Gut m n u m..m .7 t w e 4 r. - + ar;. y
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~~?,e,%,W gl. ifw POTENTTACHAZARDS:agdfdk, FIRE OR EXPLOSION Some of these matenals may turn but none of them iqmte readily.~~
HEALTH HA7ARDS 1 Contact may cause cuens to smin and eyes. Fire may produce irritatmg or poisonous gr.ses. Runof f from fire control or cilution water may cause pollution. .E. MERGENCY ACTION Kevo unnecessary pecote aw ay. Isolate na2ard area and deny entry. Weat sett contained (positive pressure it avaiiaele! Dreathing accaratus and tvil protective clotning. FCR EMEBGENCY ASS STANCE CALL CHEMTREC (800) 4:4 9300. If water pollution occurs. notify acoropriate authorities. FIRE Small Fires: Cry enemical, CO., water soray or foam ( Larga F1tes: Water sotay, f og or team. ( Move container from tire area it you can do it without risk. Do not scatter spilled meterial with more w.i:ar than needed f or fire conttof l ) Oike fire contret water for later discosal. SPILL OR LEAX Stop team if you can co it without tism. ( Taae up with sand or otner noncomoustible aosordent materiat i Small Spitta: j and place into containers for later disposal. Large Spdts: Oike f ar anead of spilt tot later disposaf. FIRST A10 in case of contact with material. immeciately flush eyes with running water for 4 at least 15 mmt:3s.Wasn skm with soao and water, Remcve and isolate contammated clotneng and snoes at the sale. l I l l t- ~ i i t a l 4 1. \\ A-25
WVDP-043 Rev. 4 O saideWEhiBRR2?!?%Wr%$ 1 '. Q/ ',4 - [POTENTTA H ijh?jpg FIRE OR EXPLOSION Flammable / combustible material: may be ignited by heat, sparks or flarnes, - May burn racidly with flare-burnmg elf eet. r l HEALTH HAZARDS l Fire may produce irntating or ooisonous gases. Contact may cause burns to skin and eyes, Runolf from fire control or dilution water may cause pollution. EMERGENCY ACTION I Keep unnecessary people away; isolate hazard area and deny entry. Stay vowmd; keep out of low areas. - ) l Wear sell. contained (positive pressure il available) ersathmg acoaratus and l l full protective clothmg. I FCR EM EBGENCY ASSISTANCE CALL CHEMTREC(800)3:4 9300, 11 water pollution occurs. notify acoropriate authonties. FIRE I l Small Fires: Cry chemical, sand, water Spray or foam. l Large Fires: Water spray, fog or foam. l Move container from fire area if you can do it without risk. i Coot contamers that are exposed to flarnes with water from the side until well i af tef fire is out. For massive fire in cargo area, use unmanned hose holder or moniter not:tes;if this is impossible, withdraw from area and let fire burn. Magnesium Fires: Use cry sand, Met L X powder or G.t graonite powder; } do not use water. SPILL OR LEAK Shut off ignition acurces; no flares, smoking or flarnes m hazard area, Co not teuen spilled material. Small Ory Spills: With clean snovel, place matenal into clean, cry contamer and cover; move contamers f rom spill are a. Large Spills: Wet down witn water and dike for later disposal. FIRST AID Move victim to fresh air; catt '
~~ency medical care, in Case of contact with mais tal, immediately flusn skin or eyes with tunning watef for at least t$ mmutes.~~
Remove and isolate contammated Clothing and snoes at the site. l I i i e' h A-26
WVDP-043 Rev. 4 I f#. b ,j M .q..c;.g 1p Agg.paremat;. FIRE OR EXPLOSION Flammable / combustible matertal; may be ignated Oy heat, soarks or flames. Oned out material may exotode il exposed to heat, llame or snock, Rursoft to sewer may create tire or enclosion hantd. HEALTH HAZ.ARDS Contact may cause burns to skin and eyes, Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause collution EMERGENCY ACTION _ Keep unnecessary people away; isolate nuard area ano deny entry. Stay vowino; keep out of low areas. Wear setf<ontained (positive pressu e il avaitaoist creatning apparatus and full protective clothing, FCR EMEFIGENCY ASS' STANCE CALL CH EMT AEC (300) 4:4.nco. j If water collution occurs, notify acoropriate authorities. FIRE Tire Fires: Flooo with water, il no water is availacle, use cry chemical or Oni-CAUTION: Tire fires may start again. Do not move cargo or veniete it cargo nas teen encosed to neat. Fo massive fire in cargo area, use unmanned nose noider or monitor ncz:tes;if this is impossible, withdraw from area and let hre ourn. ~ SPILL OR LEAK Shut ott ignition sources; r.o flares, smokmg or itames in nuard area. Uo not teuen soitted matenat. Small Spells: Flusn area witn tiooding amounts of water; Large Sputs: Wet down with water and oike for later mscosas. FIRST A10 . Move victim to tresn air, cast emergency medical care. In case of contact with matenal,immeciately flusn sain or eyes with running water 'or at least 15 minutes. Remove and tsolate Contaminated clothing and shoes at the sate. a e A-27
WVDP-043 Rev. 4 i sunres_a4;;arigsgigem eran--mmed38 FIRE OR EXPLOSION Flarnmacle# combustible material; may be ignited by heat, setsks or flames. usy burn rap 6dly with flate.ourning af tect. HEALTH HAZARDS Poisonous if swallowed. Skin contact pelsonous. Conta:t may cause burns to skin and eyes. Fire may produce irritating or poisonous cases. Runoff from fire controt or citution water may cause poilution. ' EMERGENCY ACTION Keep u.irtecasaary peools away; Isolate hazard area and deny entry. Stay upwind; keeo out of low areaa. Wear self<cntained (positive pressure il availaciel breatning apparatus and full protective clotning. FCR EMERGENCY ASSISTANCE CALL CHEMTREC(600)424-noo. 4 If water pollution occurs, notify apprognate authorities. FIRE Smal1 Firec Ory enemical, water spray or foam. Large Firac Water spray, tog or team. Wove container from fire area if you can do it without rtsm. Cool containers that are exposed to flames with water from the sace 6ntil well af ter fire is out. For massive fire in cargo area. use unmanned nose holder or monitor ,i nozzles;11 this la tmoossible, witneraw from area and let fire burn. i SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area. Do not touch spilled matenal. Small Ory Spille With clean snovel place material.nto clean, cry container and cover; move containers f rom spell area. Large Spille Wet down with water and dike for later disposal. FIRST AfD Move v6ctim to fresh air: call emergency medical care. In case of contact with material, immediately flusa smin of eyes with running water for at least 15 minutes. Remove end isolate corttaminated clotning and snoes at tne site. O 1 A-28
WVDP-043 Rev. 4 [ i f.Y 7 k ~hN$kM. +' - 1 @ $fgy&;seld:Guld 35 L. t w e mamm-FIRE OR EXPT,OSION P May ignite other corneustible materials (wood, paper, ost, etc ) Aeaction witn fuets may te violent. Aunoff to sewer may create fire or explosion nazarc. HE.ALTH HAZARDS Contact may cause burns to sam anc eyes. Vapors or cust may ee irntatmg. Fire may produce irritating or poisonous gases. I Aunorf from tire control or catution water may cause poinution. EMERGENCY ACTION Keep unnecessary pecote away: isolate hazard area and ceny entry. Wear self. contained (positive pressure if available) Creathmg aDearatus ano l 1 full protectiva clothing. FOR EhtERGENCY ASSISTANCE CALL CHiiMTREC (800) 4:4-97,00. If wator pollution occurs, notify aporeoriate authorities. [ FIRE \\. Smell Fires: Cry enemicas, CO,or water soray. Large Fires: Water spray or tog. T* Move contamer from fire area if you can co it without risk. l l Cool contamers tnat are esposed to itames with water from tne sica until weti af ter fire is out. For massive fire m cargo area, use unmannec nose noicer or momtor nea:1es;if this is impossiese, witnoraw from area and iet fire burn. ^{ SPILL OR LEAK Do not touCn scelled matettal. Kee0 comoustibles (wood, paper, oil. etc.) awav f rom sDilled material. Smais cry Spitis: witn clear, snovet coace matenai into etein, an contamer U: anc cover; move containers from soiel area. Smell Uguid Spills: Take up with sand, earth or other noncomousticle g1 absortent materiai. j, Large Spills: Oike far ahead of sci 44 for later discosal. l FIRST AfD Move victim to trash air call emergency mecical care. Remove and isolate contarmnated clotnmg and snoes at tne site. l s n in cate of contact witn material, immectately Ilush skm or eyes with runnmg water for at least 15 minutes. l m l 0, lC l( 1 ) i l I i* 1 S 74 j
WDP-04 3 Rov, 4 i G u i d e h 3 M:- e vN. e.gJOdthg s eg y s4, .e in - [ _[ I,. - 1,,' ' POTENTTACHAZA ,,,,[4f-FIRE OR EXPLO$lON Flammableicombustible matertal; may be lenited by heat, sparks or flames. Orted out material may explode tf exposed to heat, llame or stock. Runoff to sewer may create Ilre or explosion hazard. HEALTH HAZARDS Poisonous; may be f atat if innaled, swallowed of adsorbed through skin. ) Contact may cause burns to skin and eyes. Fire may produce irritatteg or poisonous cases. Runolf from fire control or dilution wator may cause postution. EMERGENCY ACTION _ Keep unnecessary secote away;laciate hazard area and deny entry. Stay ucwmd: keen out of low areas. Wear poestive pressure breathing apparatus and full protective clotning. FOR EMERGENCY ASSISTANCE CALL CH EMTREC r500) a:a 0300. If water pollution occurs.notsty appropriate auttsorities. FIRE Ttre Fires: Flood witn water; if no water is availacle, uso dry enemical or dirt. CAUTION: Tire fires may start agam, Co not move cargo or venicle if cargo nas eeen encosed to nest. For maassve fire in cargo area, use unmannec nose noider or monitor ~ nozzles;if tnis is impossible, withdraw from area and let tire burn. SPILL OR LEAK Snut off ignition sources; no flares, smoking or flames m nazard area. Do not toven soitted material. Small Sollts: Flush area with flooding amounts of water, Large Spille: Wet down with water and dike for latef disposal. FIRST A10 Move victim to fresh air; call emergency medic al care, l= In case of contact with material,immeciately !!ush skin or eyes with running water for alleast 15 minutes. Pemove and isolate contaminated clothing and shoes at the site. 1 l O A-30
WVCP-043 4ev. 4 m V s c guQ% Mi POTBETTACHAZAR Kh-f -f f5 e FIRE OR EXPLOSION FlatnmaDie/ combustible matstiat May lgnete itseil il exposed to ast. Way re*gnite aftet fire is extinguished. May burn taoidly with flate-burning etf act. J Runoff to sewer may create fire or enclosion Mala'd. HEALTH HAZ.ARDS If innaled, may be natmful. Contact may cause eutns to sum and eyes. Fire may produce irntatmq or poisonous gases. Aunoff : tom fLte control o< dilution watet may cause pollution. EMERGENCY ACTION c, ,s 4 Keep unnecessary people away; isolate na2&rd area and deny entry, Stay uowmd:lieep out of tow areas. West self-contained (positive pressure il availante) creathmg acoaratus arid 0' full protective clothmg. / FCA EMEAGENCY ASSISTANCE CALt.CHEMTAEC(sco) a:4.or,00. I If water collution occurs notify sporconate a'utnorities. l FIRE i Some of these materials may react viodently with water. I Smell Fires: Ory enemical. soda asn or time. Large Fires: Flood fire area with water from a distance.
~~~ -~~
Co not get water msede contamef- [ Move centamet from fire area <f you can do it without rism. Coot contamers inat are exposed to llames witn water from tne sice until weit atter fire is out. For massive fire m cargo area. use unmanned nose molcer or monitor nonfes;il this is impossicie. witndraw from area and let fire Durn. l l - SPILL OR LEAK Oc not toven spilled material; stoo team if you can do it witneut tism. p' L Co not get water inside contamer. l Small Soills: Flusn area witn flouding amounts of waler. l Large Spells: Dehe 30:H for later disposal. l FIRST A10 $j Move victim to fresn ast; call emergency mecical care. In case of contact with material, immediately flusn skin or eyes with running water for at least 15 minutes. O Remove a.id isciate contammated clotning and snoes at tne site. ,. f. l l n W i L 1
~~2 I~~
i A-31 e
WVDP-043 ROV. 4 M s F M..W FIRE OR EXPT.OSlON Flammable matenal: willignite itself if emocsed to air. Will re ignite itse:f af ter fire is extinguished. Burns rapicty, reteasing conse wnste fumes. Runoff to sewer may create fire or emotosion nazard. HEALTH HAZ.ARDS Poisonous il swsitowed or il f umes are innalec. Fire will procuce irritating or coisonous gases. Aunott from fire control or cinution water may cause collution. EMERGENCY ACTION Keep unnecessary occole away; isolate nazard area and deny entry. Stay upwmo; keep out of low areas. Wear positive pressure creathing accaratus and fuit protective ctoining. 4 FCA EMEAGENCY ASSISTANCE CALL CHEMTREC (500) 4:4 9305. It water pollution occurs. notify ac recriatw authorities. FIRE Small Fires-Cover with sand, eartn or water spray and keep it wet. Large Fires: Water spray, or fog. Do riot scatter spilled meterial with more water than neeced for tire control Move container from fire area if you can oo it witnout risk. Coot containers tnat are exposed to Itames witn water from the sice until weil af ter fire is out. For massive fire in cargo area, use unmannec nose noncer or moaitor nozzies:il tnis is imoossible, wictndraw from area ano let fite turn SPILL OR LEAK Do not toucn soitted material; stoo lean if you can co it witnout risk. Use water soray to reduce vapors. Small Spills: Cover with water, sand or earth; snowet into metal container and keep material under water, Larr e Saints: Oike ior tater ciscosai and cover witn wet sano or water Cleanuo only uncer suoervision of an encert. FIRST AfD Move victim to tresn air; call emergency medical care. Il not creathmq.give artificiai reso. ration 11 creatnmq is citticult, give oxygen. In case of contact with material keep encosed snm areas immersea m water or covered with wet cancages umil meoical attention is received. Remove and isolate contammated etoinmg and shoes at the site and place m metal container listed witn =ater - Fire nazard if allowed to cry. u4 /, A-32
WVDP-043 Rev, 4 ..p0 .JZ.Q T.% % 'MG,$.W $~f h .r' u w~4 m.rst r o w ,,r..,,e p%Q.. 7s,.z / &, C g, t%r, E G . '>. '. %, c. ~.. a s . s. . p. Ye + t,, { POTENTIRC, HEALTH HA2.ARDS Poisonous if innaled or swallowed, Contact causes seveee eurns to skin and eyes. Runoff from nre control or dilution water may cause pollution. FIRE OR EXPLOSION Some of these materials may burn but none of them ignite readily. May ignite other comt ustibie materials (wood, oacer, oil, etc.). Violent teaction with wster. Flammable poisonous gases may accumulate m tanks and hopper cars. Aunoff to sewer may create fire or enclosion nazard. EM.ERGENCY ACTION Keep unnecessary pecole away; isolate na23rd area and deny entry. 1 Stay vowind; keep out of low areas. Ventilate closec spaces cetore entermg them. Wear positive pressure creatning apparatus and special protective clothing. FOR EMEAGENCY AS$1 STANCE CALL CHEMT AEC (80(.4 a;:44300. ( if water cottution occurs,actity aoorcoriate authonties. FIRE Oc not get water inside centainer. ll_,' Small Fires: Cry enemical or CO,. Large Fires: Flood fire area with water from a distance. i Do not get solid stream of water on soittec matenas. Move contamer from fire area e' you can do it without risk Cool containers that are escased to ttames aim water from the side until weit af ter fire is out. SPILL OR LEAK Co not get water inside container *. Stoo lean if you can do it without risk. 4 Do not toucn spilled material. Use water soray to recuce vapors Out do not out water on team of sovil area F Keto comDustibles (wood, oaoer. oil, etc ) away from soilled material i S oitis: Oike spill for later disposat; do not apply =ator untess directed to do so. Ciean up only under supervision of an expert. FIRST A10 Move victim to fresn air. call emergency mocican care if not breathing, give artificial recoiration. Il breathing is dif ficult, give oxygen. l 1j Aemove and isosate contaminated clothing and shoes at the site Speed in removing rnaterial from skin is of eatteme importance. In case of contact witn material,.mmediately flusn skin or eyes with running water for at least 15 mmutes. l Keep victim auiet ano mamtam normat eady temocrature. O %. f 4 A-33
WDP-04 3 Rev. ' ?.s* .3 ~ h h'. N NN FIRE OR EXPLOSION May ignite itself if esposed to air. May re-ignite allef fire is eatinguished. May ignite in presence of moisture. Violent reaction with water orocuces flammable gas. Runoff to sewer may create fire or esplosan hazard, t HEALTH HAZARDS '.f inhaled, may De harmful. Contact may cause Ourns to skin and eyes. Fire may produce irntatmg or poisonous gases. EMERGENCY ACTION Keep *annocessary people away; isolate hazard area and deny votry. Stay upwint. keep out of low areas. Wear self contained (positsve pressure it available) treathing apparatus and full orelective clother"). FCR EMERGENCY ASSISTANCE CALL CHEMTREC(800) 4:s 830C. It wate* costution occurs, nottly acoropriate autnorities. FIRE Do not use water or loam. Small Fires:- Ory chemical, soca ash or time. Large Fires: Withdraw from area and iet fire curn Magnesiurn Fires: Use dry sand. Met L..x powder or G.t graonite powder: do not usa water. Move container from fire ues if you can do it without risk. SPILL OR LEAK Shut of f ignition sources; no itares, smoking nr f tames in nazard area. Qo not touch Soitted materia 4; stop leak il you can do it without risk. No water on Scilled material;do not get water inside container, Sinall Ory Spills: With clean shovet otace material into ctesn, dry container and cover; rnove containers from soill area. Small Spills: Tame up with sand or other rtoncomoustible aosorcent material and place into containers for later ciscosat Large Solits: - Dike spill for later oisposal. Cover powder soint with otastic sneet or tarp to mmimite soreading. FIRST AfD Move victim to fresh an; call emergency meoncal care. Remove aid isolate contaminated clothing and shoes at the site. Wice malertal from skm immediately; then llusn skin of eyes with runnmg wator for at least t$ minute 5. i i f i O 1 A-34 i i
WVDP-043 Rev. 4 + FIRE OR EXPLOSION Mayignite in presence of moisture. Contact with water proouces stammacie gas. ~ Runott to sewer may cf este fire or explosion na2ard. HEALTH HAZARDS Contact with water orcouces poisonous gas. Skin contact poisonous, Runoff from his Control of Qilution water may Cause collution EMERGENCY ACTION Keep unnecessary peocie away; isolate nazard area and deny entry Stay vowino: keep out of low areas. Wear positive psessure creatnmg accaratus and tuti protechve clotning. FOR EMERGENCY ASSIST ANCE CALL CHEMTREC (800) 4:4 9300. If water Dollul60n occurs, AClity appropriate authorities. FIRE Do not use watst or team, smati Fires: Cry enemical, soca aan or hme. Large Fires: Withcraw f rom area and let lif e ourn Move containee f rom tire area il you can do it without risk SPILL OR LEAK Shut ott ignahon sources; no flates. smoking or flames in nazard area 00 not touch soittec matenal. No water on scellec material: do not get water inside coniainer Small cry Soins: With clean snovet piace material into ciaan. cry container and cover; move containers from spilt area Large Spells: Oike spilt f or later cisocsal. Cover oowaet spill with plastic sneet or taso to mmimize spreading. Cleanuo only uncee supervision of an espert. FIRST AlO Move victim to fresn att: esti emergenc't mecical care lf not Dreatning, give artshcial resonation 11 breathing is ostlicult, give os ygen Aomove and isolate contammated cioinm, ano snoes at the satis in case el contact with material. immediately flush skin and eyes with running water for at teast 15 minutes Keep victim cuiet and maintain normai cody temoetature. s .g t s b.A A-35
_.=- WVDP-043-Rey, 4 q semeWahlB2?$ @ % .if h Y + f! h.\\ POTENTJAEHABLR I f HEALTH HAZARDS Poisonous if swallowed. In.islation of dust poisonous. Contact may cause Durns to skin and eyes. Are may produce inntating or coisonous gases. Runoff from fire controlor cilution wstor may cause collution. FIRE OR EXPLOSION May ignite otner combustible materials (wood, oaoer, oil, etc.). May Durn rapidly. Reaction with fuels may be violent. EMERGENCY ACTION _ Xeoo unnecessary people away; isolate nazara area and deny entry. Wear self contained (positive pressure if availaciel breatning acoaratus ano tual protective clottung. FCA EMERGENCY ASSISTANCE CALL CHEMTREC (200) 424 9300. If water pollution occurs,nottfy appropriate autnerit.es. j FIRE sm all Area: Ory enemical or CO,, water soray. j Large Fires: Water spray or tog. Move container from fire are a of you can do it witnout rism. Coci containers that are escased to flames with water from the sace until weil af ter fire is out ' For massive fire m cargo area. use unmanned nose nolcer or monitor f j not:tes. SPILL OR LEAK Co not touch spilled materia 6 Keep comoustitles twood, oaoer, oil, etc.) away f rom :oitted material Small Dry Spe;1s: With clean snovet otace material into crean, cry container and cover. move containers from sosis area i Large Spitis: Oike f ar ahead of spill tot later disposai l FIRST A10 Move victim to tresn air; casi emergency medical care, i Remove and isolate contaminateo clotning and snoes at the site. i in case of contact witn matenal, immeciately flusn skin or eyes witn running l water for at least 15 minutes. -( D l l A-36 a
i WCP-N3 I
~~ey, 4~~
( N. ,$g ". imimmai.dWJQgi;&ma sp FIRE OR EXPLOSION ~ May ignite ottier comDustible materials (wood, paper, oil, etc.). Mistufe with fusts may exploce. e Containst may explode in heat of fire. May espioce from friction, heat of contamination. Runott to sewer may create fire or emplosion nazard. HEALTH HAZARDS Contact may cause burns to skin and eyes. Fire may procuce irntater g or poisonous gsses. Runof f from fire cotitrol or dilution water may.tause pollution EMERGENCY ACTION i[ Keep unnecessary pocole away; isolate hazard area and deny entry. Stay upwinc keep out of low areas. Wear self<:entainec (positive pressure il availaciel Dreathirag apparatus anc full protective clotnmg. FCR EMERGENCY ASSISTANCE CALL CHEMTREC(800)4:4 9 00. If water pollution occurs, notify approofiale* authorities. FIRE Smest Fires: Dry enemical, CO,, water suray or team. t' Large Flies: Watef spray tog or foam. Co not move cargo or wenic:e if cargo nas eeen esposed to neat. Cool containers tilat are esposed to flames with water f rom tne side until *sil f" af ter fire is out. For massive fire m cargo area, use unmanned nose noider of monitot notates:if this is impossacte, withdraw from area and tai fire Durn. SPILL OR LEAK Keoo combustibles twood, paper, ce!, etc.) away f rom spilled material. -~ Co not toucn spilled material; stop tean il you can co it w inout rism. tJse water spray to recuce vapors. Small 5ptila: Take up with sand or otner noncomoustible accefbent material {' and place into containef s for latef disposal r Large Sp411s: Cike spilt for later disposal. FIRST AID Move victim to fresn air; call emergency medical care. Remove and isotale contammated clotning and snoes at ttle site. r-In case of contact witn matenal,immeosately ttush skm or eyes with running watef for at least 15 mmutes. y g.~ -~ \\ 'a l j r, u A-37 n
I WVDP-043 f Rev. 4 l N( M'{N;RS[. ~ ' pig.eMCNg'd>e --m msiti
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~~Dip :litiM*4 U?/dtie M[~~
SpM HEAL.TH HAZARDS Poesonous; may be f stalif inhaled, swallowed or rbsorbed through skin. Contact may cause turns to skin and eyes. Fire may produce Imtr.tng or poisonous gases. Runott from tire control or dilution water may cause pollution. FIRE OR EXPLOSION May ignite dttset comDustible materials (wood, pacer, oil, etc.). Violent reaction with wator. Aeaction with fuels may be violent. Flammaeselpoisonous gases may accumulate in tanks and nooper cars. Runoll to sewer may create fire or emotosion hazarc. EMERGENCY ACTION Keep unnecessary peccio away; isolate naaard area and deiny entry. Stay yowind; keen out of low areas. Ventilate closed spaces Defore entering them. Wear positive pressure Dreathing accaratus anc special protective clotning. FCR EMERGENCY ASSIST ANCE CALL CHEMTREC (80014:4.M00, 11 water pollution occurs, notif y accroortate authoritie s. FIRE Small Fire s: Water, dry chemicat or soda asn. Large Fires: Flood fire area with water. Move container from fire area if you can do it without rism. Coot containers that &te esposed to flames with water from the side until weil af ter fire is out. For massive lire in cargo area, use unmanned nose noider nr i.tomtor noi.:les;it this is imoossse, withdraw from area and ist fire turn. SPILL OR LEAK Keec comoustibies (wood, pacer oil, etc.) away from spilled material. Do not toucn soitted material; stco seak il you can do it without risk. Use water soray to recuce vaoots; do not get water insice contamer Smell Spills: Flusn area with ilooding amounts et water. Large Spills: Cike tar anead of soilt for later discosat. FIRST A10 Move victim to fresa air; call emergency mecical care. Il not creathing, give attiticial resoiration, if breathing is dif ficult, give oxygen, Remove and isolate contamsnated clotning and snoes at the stle in case of contact with material, immediately flush skin or eyes with running water for alleast 15 minutes. l'eep victim qwet and maintain r armat body temperature. Elfects may te celayed; keep victim under ooservation. O I A-38 l
WVCP-Ca3 Rev. 4 (( FIRE OR EXPLOSION May ignite other ComDustible materials (wood, cacef. oil, etc.). Reaction with fusts may ce viotecit. Flammacie ocesonous gases may accumulate in tanks anc nocoer cars. Runott to sewer may create fire or emotosion nazarc. HEALTH HAURCS !! innaled, may te harmlut. Contact may cause eurns to skin and eyes. Fire may Drocuce irntating or consonous gases. ~ Runoff from fire control or oilution water may cause cottution EMERGENCY ACTION Keep unnecessary people away;isciate nazard area and ceny entry Stay uowino: keep out of low areas. Wear sett contained (Dositive otessure if available) Dreathing accaratus anc full protective clotning. FOR EMERGENCY ASSISTANCE CALL CHEMTAEC(300H24 93co, it water gotiution occurs, notify accropriate autnorities. FIRE Small Fires: Water only; no dry cnemical or CO p j Large Fires: Flood fire area with water. Move container from fire area if you can do it without risk. Coot containers that are exposed to flames witn water from the side antil weil [ l alter fire is out. For massive fare in cargo area. use unmannec nose noncer or monitor noctes;if this is imcossitte, witncraw from area anc let tire curn i SPILL OR LEAK Keto combustibles (wood, oaoer, oil etc.) amau f rom spillec mater ai Do not toucn spilled materias; stop feak if you can do it aiinout nsn. Use water soray to reduce v apors, do not get water insice container Small Cry Saints: wiin clean snovei otace material into clean. cry con. tainef and cover; move Containers f rom spill.irea
~~.J Smal15 pills: Flusn area witn licocinq amounts of water.~~
Large Spills: Oike f ar anead or sodt 1or later disposci FIRST AlD Move victim to tresn air; casi emergency macican care. if not breathmq, give artificial respiration. it breathing is cillicult, give oxygen. in case of contact witn material, immeciately flusn skin or eyes wiin running j water for at least 15 minutes. Remove and isciate contaminatec clothing and snoes al the site Keep victim quiet and maintain normal body temocrature Ef f ects may te delayed; keep victim uncer ocservation. Y u as A-39
WVDP-043 l Rev, 4 I i O FIRE OR EXPLOSION May explode il fire reaches cargo area. HEALTH HAZARDS Fire may produce trTitating or poisonous gases. EMERGENCY ACBON $100 ait traf ue and cteat atos for 2*.00 f eet til: mile)in all directions. Keep unnecessary pecole away. Do not flgnt fire in cargo. Try to orevent a fire from reaching the emplosive cargo comJattment. West sell. contained (ocsitive pressure il availablel breathing accaratus and full crotective c:otning. FOR EMERGENCY ASSISTANCE CALL CHEMTREC(800H:4.s000. FIRE Truck and Equipment Fltes: Flood with water,if no watre available use cry enemical or dirt. CAUTION: Tire f ttes may start again. Unnonk and Seoarate tractor from traster il possicie.
~~argo Fires:~~
Do t move cargo or venicle if cargo nas oeen exooseo to he at. Do not fight fire when it reacnes cargo. Withdraw from area anc let fire turn. SPILL OR LEAK Shut oil tqnition sources; no flares, sincking or flames in hatard area. Do not toi en soitted material. FIRST A10 Call emergency meoncat care. Ute fltst aid treatment accorQing to the nature of the injury, O A-40
l WVCP-043 l
~~Rev, 4~~
t ws r s.. ~' .f g. w g - 4,% g $y& e ~e. [i CW. 9 N _H n FIRE OR EXPLOSION + May ignite other comeustible materials (wocd, cacer, oil, etc.). Mluture with fusts may esotocc. Flammaele poisonous gases may accumulate ici tanks and neoper cars 1 Co,itamer may excioce m nest of fire. May exploce from friction, neat et contamination. Aunoff to sewer may create fire or emotosion hazard. HEALTH HA7.ARDS 11innaled, may be natmful. Contact causes severe burns to skin and eyes. Fire may procuce irritating of poisonous gases. Runoff from fire control or dilution water may cause collution EMERGENCY ACTION Keep unnecessary pocole away;isotate nazard area ano ceny entry. Stay uowinc; keeo out of tow areas. Want sell.containec (posmve pressure il avaitaciet orestnmq acoaratus ano full protective clotning. FC A EMERGENCY AS$15TANCE CALL CHEMTREC (800) 4:4 93c0, If water collution occurs, notify accrootiate authorities. ) FIRE Small Fires: Water onty; no dry chemical or CO p Large Fires: Flood fire area witn water. Co not move cargo or wenic!e if cargo nas teen encoseo to neat, Coot containers that are exposed to flames witn water frem the sace until well atter fire is out. For massive fire in cargo area, use unmanned nose noicer or monitor nozzles;if this is impossicie, witndraw from area anc tot fire ourn .'~ SPILL OR LF.AK Keeo comousticles(wood, cacer, oil. etca away from scilled matenal i.; Oo not toucn soilled matenat; stoo lean if you can ao d witnous rism. ' j Use water soray f o recuce vaoors Small Spills: Flusn area wdn flooding amcunts of wate' Large Soi!!a: Oike spilt for later ciscosal. FIRST A10 ~ Move victim to fresn air casi emergency medical care h if not breathmg. give attiticial resotration M If treathmg is dif ficutt, give cuygen d Pemov* and isotale contaminated clothing and snoes at tne site. in case of contact with material, immediately flusn sam or eyes won running water tot at least 15 minutes. Keep victim coset and maintam normai cocy temoerature. W A-41
WVDP-043 Rev, 4 O E A & e u _$ $ $ W. 8l : 55 m FIRE OR EXPLCSION q May be ignited Dy neat, sparks or flan.es. Contaaner may explode in Deat of fire. I May explode from neat or contamination, AunotI to sewer may create fire or expiosion nazard. ~l H EALTH H A7.ARDS "i Contact may cause burns to skin and eyes. } - Fire may produce irntating or poisonous gases. Runoff from flte control or citution water may cause collut:on, EMERGENCY ACTION Keep unnecessary Deeple away; isolate natard area and deny entry. Stay unwind; keep out of low ateas. West self. contained (positive pressure if availaole) creatning aoparatus ano full protective clotning. FCH EMERGENCY ASSISTANCE CALL CHEMTREC(500)a24 93:4. It watet pollution occurs, nottfy apptooriate autnonties. FIRE Sme!I Ftre c Ory chemical. CO,, water spray or foam. j - Large Fires: Flood fire area with wattr, Cool containers that are exposed to flames with water from the side until weil af ter fire is out. For massive fire in cargo area, use unmanned nose noider or monitor . nozztes;if this is impossiele, witnotaw from area and let fire burn. l SPILL OR LEAK l-Shut of f ignition sources; no itares, smcking or flames in nazaid area. Do not touch scilled material; stop team if you can uo it without risk. Small Spills: Tane up with inert, camo noncomousticle material: move con. tainers from sonia area. Large Spills: Wet down witn w ater and dike f or later discosal. FIRST A10 I l Move victim to tresa air; casi emergency medical care. Pemove and isof ate contaminated clotning and snoes at the site. In case of contact with material,immeciately flusn eyes witn running water for at lesat 15 minutes.Wasn Skin witn soap and water, Keep victim quiet and ma6ntaan normal Dody temperature. t ,,_4 h 9 A-42
WVDP-043 j Rev. 4 l / 1C 4 i;t gg - n -... e. w kI M 1mm
~~le t t C i t M 4 9/diir%~~
~~FIRE OR EXPLOSION h May os igntled try nest, scarxs or Itames. May Durn racidly with itate-ournmg eff ect. Container may exotoco in neat of fire, May explode from triction nest or contamination.~~
~~f...~~
j Aunoff to sewer may create fire or encicston nazard. Ij HEALTH HAZARDS Contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases. Runott from tire control or dilution water may cause collution. 3 EMERGENCY ACTION Keep unnecessasy peocio away; isolate hazard area and deny entry. Stay upwmd; keep out of low areas. Wear sett. contained (positive crassure if available) creatning accaratus and full oretactive clotning. FOR EMERGENCY ASSISTANCE CALL CHEMTAEC(600)4:4 9300. If water ccitution occurs, notify accropriate authorities. FIRE Smelt Fires: Cry enemical, CC,, water spray or tosm, t,arge Fires: Flood fire area witn water. Do not move cargo or vehicle of cargo nas been exposec to neat. if fire can ce controllec, cool container *stn water from unmanned nose noicer l or momtot noules untti weil alter tire is out. If this is impossible withdraw from area and let fire Durr SPILL OR LEAK Shut off ignition sources; no flares, smoking or t1ames in nazard area. Do not touch spilled material; 3t00 leak if you can oo it without risk. Small Spille: Take up with inert, damp noncombustible material; move con. tainers from spill area. Large Splits: Wet cown with water and dike for later ctsoosat, FIRST AlD Move victim to fresn air; call emergency medical care, Aemove and isolate contaminated clotning and shoes at ine site. In case of contact with material, immediately flush eyes witn runrung water for. at least t$ minutes. Wash smin with soap ar'd water. Keep victim quiet anc maintain normal body temperatute. m ) L; t A-43
WVDP-043 Rev. 4 O\\ f ' ee yj mdt " L. ~,,., ,,,Q. %gj4 1 .. I 9y ' 3 ' " %'ih ST #1 lj FIRE OR EXPLOSION May explode il fire reaches cargo area. MEALTH HAZARDS Fire may produce irntating or poisQous gases. EMERGENCY ACTION Stoo all traf fic and clear area for 1500 feet (*I3 matelin all directiri it. Keep unnecessary gecoie away. Do not flgnt firt in cargo. Try is prevent a fire from teaching 'ne emplosive cargo compartment. Wear self<:entained (positive pressure if availacle) breathing apparatus and full protective c!othing. FOR EMERGENCY ASSISTANCE CALL CHEMTREC(800) 4:4 0000. FIRE Truck and Eaulpment Fires: Flood witn water, if no water is availacie, use dry enemical or dirt, CAUT CN: Tire ures may start again. Unnoon anci separate tractor from trailer il possible. Cargo Fires: Do not mcve cargo or venicle il cargo has even encased to ~ nest. Do not flgnt fire when it reacnes cargo. Withdraw from area &nd let fire curn. SPILL OR LEAK Shut off igmtion sources; no flares, smouing or flames le hazard area-Oc not touch spilled material. FIRST AfD Call emergency medical caro. Use first aid treatment ac:orcing to tne nature of the iniury. r i i I .s A-44
WV09-043 Tev. 4 I f\\ (v) I I Q~j397*P-
~~%(p.@S.- 745 "'gCO t'45.Q;4%y-Q kre' y m :f o. +.~~
,v % g. ,g ' <..MbMb[ POTENT 1ACHAZA FIRE OR EXPLOSION k]e May be ignited by heat. sparks or flattes. Cont 4.oer may esplode m heat of fire. May esploce from heal or contaminattert. Runoff to sewer may create fire or emplosion ha25td. n i HEALTH HAZARDS Vapor entremely irritatmg, Contact of matettal of its vaucr with eyes may cause oleMaess. is Poiscoous 40 swallowed. Fire may pr4 duce irritating of Wisonous gases. Runoff from fire centrol or Ollution water may cause pollution. f.7 EMERGENCY ACTION i ' i Keep unnecessary people away; tsolate Maiard arep and deny entry, $tay upwmd; keso out of low ateaa. [ Wear sell.contamed (positive pressure 61 availaole) Dreathmg 39paratus and fuit pretective clothmg. ( FCR EMERGENCY AS$1 STANCE CALL CHEMTAEC !800)a2a4MC. If water pollution occurs, notify appropriate autnoritics
~~c. ?~~
FIRE Small Fires: Ory chemical. CO,, water, pray or foam Large Fires: Floou les area with water, I: For massive fire ei. cargo area, use unmar ned nose Molder or monitor noutes. Il fire can ce controtted, coot container with water trem unmannec nose noncer of monitor noutes until weti af ter fire is out. 11 this is impossicto, withdraw from area and let fire Durn ~ ' SPILL OR LEAK 19 Co not touch spitted material Shut of f ignition sourc as: no f tares. smoiong or flames m natard area n Stop least if you can do it without risk. Small spills: Take u,. aith inert, camp nuncomousticie me crias, move con lainers from spill area. witn water and dike for later disposal Large $ pills: Wet sown i. FIRST AfD Move vtClim to fresn att; call emergericy medical care. in Case of contact with material,immediately flugn eyes witn runnmg water for nq M at least 15 mmutes. Wash skm with 5740 and water. Memove and isolate contammated clothmg and shoes at the site. k eep victim ouset and maintam normat body temperature. i 4 i v
~~.s l~~
4 A-45
WVDP-043 Rov. 4 ei y ; yw:y qL$cypqmy; W:k Guide 65 nmngunanomip%CQ:$g. 5
~~+ p M Q po ~ s iisA A~~
) FIRE OR EXPLOSION uav ignais,issini es,eo io ni,. u.y o. ign.ied e, nesi. spa,.. or iames. u ay eurn,so,oiy wiin fu,e. urning ofiact May emplode f rom heat, contamiriallon or loss of temperature control. Aunoti to sewer may create lire of suplosion Natard, HEALTH HAZARDS Contact may cause burns Io skin and eyes. Fire may produce irritat6ng or poisonous gases. AunotI from fire control or dilution water may cause postution. EMERGENCY ACTION < esp unnecessa,y peooie awayosoisie nm,c 8,ea and asey eni,y Stay upwmd; keep out of low steas. Wear self Contained (pos6tive pressure if availaDie) breathing apparatus and i I full protective clothing. FC A EMEAGENCY ASSISTANCE CALL CHEMTAEC (800)a24 0300. It water potiution c< curs, notify accropriate authorities, LOSS OF COOLING g speciesed coni,oi icm e,siv,e o, maierisi musi ot mainta,ned. Cme nouid n,. trogen. cry ic e of ice for coolme. Il none can ce cotamed. evacuate area. s FIRE Small Fires: Ory chemicat,CO, water soray or fosm. Large Fires: Flood fire area with wster. For massive fire m cargo area, use unmanned nose holder or monolor nol2ie s. If fire can es centroitec, cool contamer with water from unmanned hose hoicer of monitor noces unti, well af ter fire is out. Il this is impossible, witnotaw from area and let fire Durn. SPILL OR LEAK Do not touch soitted material; stoo teak if you can do it without risk. Shut off ignition sources; no flares, smoming of itames m hazard area. Small spills: Take up with sand, or other noncombustitle material; move containers from spill atea. Large $ pills: Oike spill for later cisposal. FIRST A1D i Move victim to fresh air; call emergency medical care. l-Aemove and isolate contammated clothing and shoes at tPt site. In case of contact with maternat,immediately flush eyes with runnmg water for l at feast 15 minutes. Wasn shm with soao and water. ( Keep victirn oviet and reaantam normal body temperature, i l l l O A-46
l l WDP-04 3 Rev. 4 V HEALTH HAZARDS Poisonousif swallowed inhalation of cust DC!si CUS. Ptre r ~ y produce irntst:ng or poisonous gases. Runo ' rom fire centrol or dilution water may cause pollution. FIRE OR v *LOS10N Some o' /ese materials may burn cut none of themignite reacity ,{ME AGENCY ACTION xeep unnecessary,ecoi. a..y:isoisi. hua,d ar...nc een, eniry. Stay upwma: keep out of low areas. Wear self contained (positive pressure if availaret breathing accaratus and full Dfotective clothing. FC A EMERGENCY ASSIST ANCE CALL CHEMTAEC (800) a:a 9300. It wstor pollution occurs, not.ly soorocriate authorities. FIFIE Small Fires: Cry chemican, CO,, water scray of team. Large ' Ires: Water soray, fog or foam. Move container from fire area if you can 00 it without rism. SPILL OR LEAK g Co not toven spiiled materist; stco leak il you can do it without rism, Smast $ptits: Tame up with sand or other noncomDustibie aosoreeni materias ...!'l and place mto containers for later ciscosal Smsil Ciry Souls: With clean showet place material into etean, cry container and cover *, move containers from spill area. Large Spills: Cike f ar anead of spiti for later disposal. FIRST AfD Move victim to fresh air; casi emergency mecical care Aomove and isolaie contaminated clothing and shoes at tne site in case of contact *itn maternt, immeciete6y flush skin or eyes witn runnir,g water for at least 15 minutes. t- .h II 1 -k Ie o i A-47
WDP-04 3 Rev. 4 O J HEALTH HAZARDS Poisonous il swallowed. Ilinhsled, may be harmful. Contact may cause burns to skm and eyes. Fire may produce irritating et 00 sonous gases. Runoll from fire control or dilution water may cause collution. FIRE OR EXPLOSION Some of these materials may turn but none of them ignite readily. EMERGENCY ACTION Keep unnecessary people away; isolate hazard ates and deny entry. -l 5tay vowinc; keep out of low areas. Weas self contained (positive pressure il available) breathing accaratus and 'l full prot ective clothing, I FCR EMERGtNCY A5!! STANCE CALL CHEMT AEC (800) a2a.9300. 11 wster sollution occurs, notif y appropriate authorities. FIRE Small F!tes: Cry chemical, CO,, walet spray or foam i Large Fires: Water spray, fog et f oam Move containst Irom fire area el you can do it without ris A. SPILL OR LEAK Do not touca sDalled material, stop leak if you can doit without risk. Smai! Spills: Tame up with sand. or other noncomoustiole 40sortent material and place into containers lot later disposal Small Ory Spills: With clean shovel place material into clean cr'y container and cover; move centaiaers from scial area Large $ pills: Oike f at ahead of spilt ter talet disposal FIRST A1D Move victim to tresh air; call emergency medical care. Aemove and isolate contaminated clotning and shoes at the site. In case of contact with material. immediately flush eyes with running asier for at fe* *t 15 minutes. Wash shn aith soap and watet. I I O A-48
WVCP.N 3 ev, 4 f% U HEALTH HAZARDS j Poisonous; may be f atalit inhaled, Swallowed or absorbed through skin. l Contact may cause burns to skm and eyes, i Fire may produce irntaling or possonous gases, Aunoff from fire control water may give of t poisonous gases. Aunoff from fire controlor dilution water may cause potiution. FIRE OR EXPLOSION Sorne of these materials may burn but none of them ignite readily. 1 Cy16ndet may emploos m heat of fate. EMERGENCY ACTION '9 Keep unnecessary people away*, isolate hazard atos and deny entry. Stay upwmd: keep out of tow areas. Ventstate closed spaces cefore enlermg them. West positive pressure breathmg apparatus and special protective clothing. Aemove and Isolate contammated clothing at the site. A) PCR EMERGENCY ASSISTANCE CALL CHEMTREC(800) a:a.930d. tV tf water pollution occurs. nolily appropriate a'uthorities, FIRE m Smell Fires: Ory chemical, CO,, water spray or roam. Large Fltes: Water spray, log or loam Move containst f rom tire area il you can do it without tism. [ Fight flee from maaimum cittance. 04ke lite control water for later disposal: oo not scatter the maierial. SPILL OR t.EAK Co not touen spilted material; stop teak if you can do it *ithout rism. Use watef spray to reduce vapots. Smsel Spills: Take up with sand er other noncomoustible absoteent material and place mio containers for later disposal. Smell Dry Spills: With etean shovel place materialinto ctean. dry contamer and covet; move contamers from spilt area. Large Splilt: Dilie f ar ahead of spilt for later disposal, FIRST A10 Move victim td fresh air; call emefgency medical Care. If not breathing, give artificial respiratiott !! breathing ts dif ficult, give osygert in case of contact aith material, immediately flush skm or eyes with tunnmg g,, water for at least 15 minutes. (" j Speed m removmg material from skin is of entreme importance, 4 Remove and Isolate contammated clothing and shoes at the site. Keep victim quiet and mamtam normal body temperature. 7, Eff ects may te de'*ved; keep victim under ooserv anori. U) f 4 A-49
WVDP-043 HOV. 4 i
~~' u =~~
A- . g, .g 4w . hh. S i 'i . w w n n.. n a n$. pp HEALTH HAZARDS Poisonous; may be f stal tilnhaled, swallowed or absorbed through skin. Contet may cause burns to skin and eyes. Runt lf from fire control or dilution water may cause pollut6on. FIRE OR EXPLCSION Some of these matwetais may eutn but none of them ignite readily, I May esploie from friction. Nest or contammation. EMERGENCY ACTION Keep unnecessary pecole away; isolate hazard area and deny entry. ~ Stay upwind; keep out of low stess, i Ventilate closs1 soscas before entermg them. West posallee pressure breathing acostatus and special protective clothmg. FCR EMEAGENCy ASSISTANCE CALL CHEMTPEC(800)a:4 9300. 3 11 wstor pollut6cn occurs, tiotify appropriate authorities. Small Fires: Dry chemical CO,. *atet sotsy ht team. Large Fires: Water sotay, tog or loam. Move contamer from tire area if you can do it without tism. I Cool contamers that are esposed to llames witn water from the side until weit af tot fire is out. For massive flee in cargo aves, use unmanned hose noidet et monitor j nozztes;il this is impossible *ithdraw from atoa and let fire burn. SPILL OR LEAK Do not touch spilled material; stop leak if you can do it without risk. t,!r,e wstar scray to reduce vapots. Small Sp6 tis: Take up with sand or other noncombustible absorbent materias and place into contamers for latst disposal. Small 0,y Spitis: With clean snovel place materialinto clean, dry centainst and cover; move contamets itom spiH are a. Large spills: Oike f ar anead of spill tot later disposal. FIRST AfD Move victim to fresh air; cail emergency mooical care. f .lf not breathing, give artificist rescitation. [ if breathmg is ditficult, give osygen. in case of contact aita material, immediately fluan smiri of eyes witn tunning l water for at least 15 minutes. Speed in removmg material from skin is of entreme importance. Remove and isolate contaminated clotning and shoes at lhe $414. Keep victim cuiet and mamtam normal body temperature. Ellects may be delayeo; n eep victim under ceservation. O A-50
WDP-04 3 Roy, 4 f% b ~~~-*E 'i i 's b'l8113 t' I s fiM I Ti /'_ li ri-t HEALTH HAZARDS Poisonous: may be f atti tilnhaled, swallowed of absorbed through skin. l Contact may cause turns to skin and eyes. Runott from flte control or dilution wstar may cause pollution. FIRE OR EXPLCSION May be ignited by heat, spartis of flames. Container may esotode in meat of Ste. Vapor espaosion and poison hazard indoors, outs oot or in sewers. EMERGENCY ACTIO,j, Keep unnecessary people away; isolate nazard :.rea and deny entry Stay upwind; keep out of low areas. {.. Ventilate closed spaces before entering them. West positive pressure breathing apparatus and special protective c!cthing. FOR EMERGENCY AS$1 STANCE CALL CHEMT AEC1800) 4:4 9::00. It water pollution occurs, notif y appropriate authorities. p', FIRE Small Fires: Cry creinical, CO,, water spray or loam, l Q Large Fires: Wai=# spray, tog or foam. l Move contamer from fire area il you can do it without f.sk. J .f. Cool containers that are esposed to flames with water from the side until et altet fire is out. Fignt fire from masimum distance. Dike fire control water for taler disposal; do not scatter the mater,as. SPILL OR LEAK Shut off ignificn sources; no f tares, smoking of flames in hazard area. I f' 00 not to,'ch spilled material; stop lean if you can do it without rism-Use water spray (*, reduce vaport, Small Splits: Tone up with sand or other noncomoustible ausoreent materias and place into containers for later disposal. Small Dry Spills: With clean showet place metettalinto clean. dry containet and cover: move containets f rom spill area. l large Spills: Oike f.st aNati of spilt for saf et disposal. e FIRST A10 i Move victim to fresh air: call emergency medical care. Il not Oreathing, give artificial resoiration. If Dreathing is dif ficult, give osygen. in case of contact with material, immediately flush skin or eyes with running f-water for at least 15 minutes. Speed in removing material from skin is of estreme importanc e. Aamove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperalute. Eff ects may be delayed, keep victim under ooservation. (V \\ I A-51
WVDP-043 Rev. 4 HEALTH HAZARDS Inhalasjon of vapor or dust is enttemely tentating. May cause burnmg of eyes and flow of tears. May cause cough 6ng dif ficult breathing and nauses. Bttet exposure ef f ects last only a few minutes. .1 Exposure in an enclosed ares may be very narmful. Runof f from lite control or dilution water may cause pollution. FIRE OR EXPLOSION Some of these materials may burn but none of them ignite readily EMERGENCY ACTION Keep unnecessary people away; isolate na2ard ares and deny entry. j Stay upwind; keep out of low stesa. Ventilate closed spaces before entering them. Wear positive prosaure breathing appatalus and special protective clothin J. i FOR EMERGENCY ASSISTANCE CALL CHEMT AEC(800)a:&t300. j 4 J I FIRE l Smell Fires: Cry chemical, CO,. water spray or foam. Large Fires: Water spray, fog or loam. i SPILL OR LEAK Oo not touen spilled material; stop teak il you can do it without risk. Small 3psite: Take up with sand or other noncombustible aosorcent material and place into containers for later disposal. l Large spilla: Oike f at ahead of spill for taler disposal. l FIRST AfD i Move victim to fresn ast, call emergency medical care. !! not breathing, give artificial resperallon. If breatnmg is citticult, give oxygen in case of contact with material,imrneciately flush skin or eyes with running water for at least 15 rniqu'es Hemove and isolate contammated clothing and snoes at the site. Effects should snappear aftet individual nas been esposed to f.esh ait for an-proximately 10 mmutes, j 9 &4 l A-52
_ =. ~ WCP.C43 E4V. 4 b \\ I r~ y ,nry er e .:.a,s u. m _ y HEALTH HAZARDS Poisonous ilinnaled or swallowed. Skin contact Dodsonous. Contact may cause burns to smin and eyes. Fire may proouca irritating or poisonous cases. Runof f from fire contret or dilution water may cause poilution. FIRE OR EXPLOSION Sorne of these matenats may ourn but nons of them ignite readily. Some of these materials may egnate combustibles twood. oncer. oil. etc.). EMERGENCY ACTIOf{ Keep unnecessary gecole awsy isolate naaard ar94 and deny entry. Stay vowmo: keep out of low areas. Wear posillye pressure breathing apparatus and special Jtotective clothinqJ FCR EM ERGENCY ASSISTANCE CALL CHEMTREC (800H:4 9300. j l If water pollution occurs. notify appropriate authorities. b) Some of these materlass may react violently'with water. FIAE ~b Small Fires: Cry enemical CC,. water spray or foam Large Fires: Water sor1y, f og of foam. Move container from fire area if you can 40 it without rish. Cool containers that are esposed to flames **th water. rom tee sace unot *ect af ter fire is on.t. 3 PILL OR LEAX Oo not touen spilled matsital; stoo leak if yoi,can co it without rest Use water spray to reduce vapors. Srnail Sputa: f ame up witn sand or other no'..:omtusticle aosorcent materias and piacc into coreainers f or later cispor a Large Sod!!a: Oike spos 'or later discosal. l*lRST AfD Mov e victim to frean air. cast emergency mecical care. il not breathing, give artificiai respiration. If breatning is clificult. ;ive on, gen. In case of contact with matenat immediainly flusn skin or eyes *stn running wstor for at least 15 minutes. Remove and Isolate contaminated cloining and snoe s at the site. Keep victim quiet and maintain normat ocoy temperatwre, Effects may to delayed; kees victim unoer ooservations [: 4 .i (v/ A-53
WVDP-043 Rev. 4 O ~ ~ - -. L m .u. 2.a.. ~.. . a HEALTH HAZARDS Contact causes burns to skin and eyes. If inhaled, may be harmf ul. s Fire may produce irritsting or poisonous gases, Runoif from fire control of dilution wstor may cause pollution. FIRE OR EXPLOSION Some of these materials may eurn but none of themignate reacity. Flammacle/ poisonous gases may accumulate in tanka and hoccer chts. Some of these materials may ignite comeustibles twood, paper. oil, etc.). EMERGENCY ACTION Keep unnecessary people away: Isolate haasto area and cany entry. Stay upwmd: keep out of low areas. Wear self contained (positive pressure if available) creathing apparatus and full protective clotNng, FCR EMEAGENCY ASSisTANCECALLCHEMTAEC(s00)a:a-o:od, i if wator pollution occurs, notify appropriate authortties, FIRE some of thess materials may react viciently with water. Small F1te a: Cry chemical, CO,, w eier sotay or foam. 4,arge Fires: Water sprey, tog or foam. Move contamef from flee area if you can do it without risk. Cool containers that are esposed to flames with water from the side uritti = ell af ter fire is out. SPILL OR LEAK Co not touch spilled matertal'stop leak if you can do it without risn. Small Splits: Tame up with sand or other noncomDustible absorbent material and place into corttamers to.' tater disposal. Sme1 Ory Spills: With clean shovel place malertal into clean, dry container and cover", move contamers f*om spill arca. Large spills: Cike iar ahead of sonillor later disposal. FIRST AlO Move v6ctim to fresh att' call emergency medical care. Remove and Isolate contaminated clotNng and Shoes at the site. In Case of contact with matertal, immeclately fluSn skin of eyes with running water for at least 15 mmutes. Keep victim quiet and maintam normal body 1omnerature. sec i A-54 i
- ~. - -. - --. -... _ = avDF 042 cev. 4 L O o 1 V N HEALTH HA::ARDS Fire may produce irritatmg or poisonous gases. Racloactive material; titt.e radiation hazard. FIRE OR EXPLOSION $ cme of these matetials may Durn but none Cf them ignste readily. EMERGENCY ACTION Keep unnecessary people away, isoitte batard area and dvny entry, Wear self<ontained (positive psessure if availaolet treathmg apparatus and full protective clothing. Delay cleanup until arrivalor instructton cf ovaciled Aaciation Authority. FOR (MERGENCY ASSIST ANCE CALL CHEV TREC(600) 4:49300. FIRE Move centamer from fire area if you car, do it without risk, Small Fires: Cry chemical,CO., water spray or foam Large Fires: Water spray or fog 'flocomg amounisi. SPILL OR LEAK 00 not touch damaged containers or spilled matertal. Small Liquid spills: Take up with sand, eartn or other noncombusticle ADsortent material, FIRST AfD Use first and treatment according to the nature of the mtury. ~ Advise medical care corsonnel that mtured persons may be contaminateg with radioac tve material, i i i i t i 4 { A-55
WDP-04 3 k@V. 4 O % alm % gp$p p(J. " E)a ~ r " Yh %lgJ ~ Q[ EOl*h Ii slit /M1941iekadiy + .1a-HEALTH HAZARCS Fire may produce irritating or poisonous gases. Raoloactive malettal; degree of naantd will vary from tittle to moderate, de-p+ndir.g on type and avantity of radioactive material. Reineff from fire control or ailution water may cause pollution. l FIRE OR EXPLOSION Some of these materiais may turn but none of tt em ignite readily. EMERGENCY ACTION xeep unnecessary peooie at least 150 feet upwmd of spill. Isotate nazard area and deny entry. t umit entry to soortest possicie time. wear seil<ontained ! positive pressure if availaciel breathmg apostatus and i fuit protective cloinmg. Celay cleanuo until arrival or mstruction of avalilled Radiation Authority. FCR EMEAGENCY ASSISTANCE CALL CHEMTRECisog)4:4 0300. l FIRE Do not move damaged containers; move undamaged contamers out of fire zone. Small Fire s: Cry chemical, CO,
~~ster spray or team.~~
Large Fires: Waist spray, fog or foam. SPILL O R '.EAK i Do not touen dameged containers or spilled meterlat. Large So6 tis: Cine iat aneed of spill for later disposal. Cover powder spill witn plastic sneet or taro to minimate spreading. 3 FIRST A10 i Use tarst aid treatment accoratng to the mature of the mtury Il not affectmg miury, remove and isolait contammatec clothmg and shoes; wrao victim m etanket tetore transportmg, 11 not insured, remove and isotale contammated clothmg and shoes; snower victim with soap and water Advise medical care personnes that mlured persons may De contammated witn radioactive material. i O A-56
WVDP-043 EeV. 4 Ya HEALTH HAZARDS Esternal radiatiori from unshielded radioactive matenal. r internal radiation from inhalattors, ingestion or skm aosorption. Radioactive material; degrew of nazard weit vary greatly, cepenoing on ryce and cuantity of taoicactive maternat. Aunoff from fire control or cliution water may cause pollution. FIRE OR EXPLOSION Some of these materials may burn but none of themignite readily. EMERGENCY ACTION Keep unnecessary people at least 150 feet upwmd; greater distances may te neCetaary if adytaed tsy Qualified Radiation AU'nority. Isolate ha2std area and deny entry. Eater spell afea only to save life; timet entry to s tortest Dossiele time. 4 Wear positive pressute creathing apostatus and full protective clotning. Cetain unmiured persons and vov6pment esposed to radioactive material Sntil arrtval of mstruction of cualilled Radiation Authority. O Celay cleanuo until arrival or instruction of Qualilled Aadiation Authority FCA EMERGENCY ASSISTANCE CALL CHEMTAECi800)a:4 9000, if walet ocliution occuts, notify sootooriate authorities. FIRE ^ 1;, Co not move damaged containers; move undamaged contamers out of fire zone. Small Fires: Cry chemical, CO,. ater sermy or Icam. Large Fires: Water spray. r,r fog (floodmg amountsl. For massive tire in cargo area. use unmanned nose noider or monitor noz2te s. Fignt tire from masimum distance. SPILL OR LEAK Ce not touch demaged contamers of spilled materiel. Camage to outer centamer may not af f ect primary mnet container. Smeil Liquid Spells: Tame up with sand, earth or other noncombustible aosor-bent material, Large Spills: Cike f ar anead of soill for later disposal. FIRST A10 Call emergency medical care. If not affecting tryury, remove and isolate contaminateo clothmg and shoes; wtag victim m olanket cetore transportmg. If not inluted, remove and isolate contaminated clothmg and SPnes; shower ,' If victim with soso and water. Escept for the mlured, detain persons a.-d ecuipment eroosed to radio.ctive material until atreval et mstruction of Radiation Authority. Adytte medical care personnel that anlured persons may os contammaled with radioaClive malarial. O 1 4 A-57
b'VDP-04 3 i Rev. 4 ) O w w y w Rf- -m q .,so m .~._ m =...a w...a HEALTH HAZARDS Radioactive material;little taolation hazard. Contact may cause burns to skin and eyes. It innaled, snay de narmfut, Fire may procuce erntating or poisonous gases. Runof f from fire control or datution water may cause pollution. FIRE OR EXPLOSION Some of these materials m ay ign to comcustiDies(wood, pacer, oil, etc.). Keep unnecessary people awsy;isolato hatard area and ceny entry, Wear self<:ontamed (positive pressure il availaDiel 5testning apparatus and full prottellve Clothing. Celay cleanup until arttwal of instruction of qualified Raolation Authority. FCR EMERGENCY ASSISTANCE CALL CHEMTAEC (800) a24-9300. if water pollution occurs, notify appropriate authorities. FIRE Move container from fire ares il you can do it withou't risk, Small Fires: Ory chemicas, CO,, wator spray or foam. Large Fltes: Water spiay, or f og (floooing amounts). SPILL OR LEAK Stop teak if you can do at without risk. Move undamaged packages from spill atoa. Do not touch damaged containets or spilled matanal Camage to outer container may not af f ect primary inner containet. Small Uguld Spitis: Taus up with sand, earth or other noncombustible 40-sortent mate *ial. Large Sp(Its: Cike f at anead of spilt for later cisposal. FIRST A1D Move victim to fresh air; call emergency medical care. In case of contact with material, immeciateiy flush skin or eyes with running water for at least 1$ minutes. If not affectmg iniury, remove and isolate contaminated ciothing arad snoes; wrap victim m Diankel Defore transporting. If not injured, remove and isotate contammated clothing and shoes: snower victim with soap and water. ACvise medical personnet that victim may be contaminated with radioactive materlat and may have Chemical Dufns, i 9 A-58
V W * ', ) xev. tv i ','._.m,, r g $ 4wM1-4GF 6 u.ii m tre rma.c.. hw?ish r. '., gLan b s I X a L FIRE OR EXPLOSION May ignate itself if esposed to att. May burtt rapidly with flate ourning eff ect. May re ignite af ter fire is eatinguished. HEALTH HAZARDS Pacloactive rnatorial;little raciation hazard. Aueoff item fire control of cllution watet may cause collution EMERGENCY ACTION Kee0 unnecessary people aw sy. 3 Isolate hasard area and deny entry. Stay vowmd keep out of low areas. Wear sell. contained (positive pressure if availablel breathing accaratus and full prottctive clothing. '~- Celay cleanuo untti arrivat or instruction of cualified Aadiation Authority. FCR EM ERGENCY AS$1 STANCE CALL CHEMTAEC(800) 424000. O FIRE k Move container from f ate area il you can db it without rism. Small Fires: Cry cSemical. soca ash of time. Large Fires: Flood fire area with water. Coot containers that are esocsed to flames with water from the side until wei6 i ; aller fire is out. SP!LL OR LEAK f~ Do not touch damaged containere or spilled material. Move undamageo packages from spill ates. Small Spilla: Sweep into metal containers and keep under water of mmeral oil. ) Latte Spills: Wet down with water and dike for later discosal. FIRST A!D Move victim to fresh air; call emergency medic al care Remove and isolate CDritammaled clothing and shoes' shower viCitm with soap and water. Adytte medlCal Care personnel that tnlured persons may be Contammated with radioactive material, E-N_ i 8-(m a i A-59
b'VDP- 0 4 3 Ite V. 4 O &W MM5$n$3299k man.-,_.m k HEALTH HAZARDS Radioactive malattat:little radiatiott ha.tard. i, inha,eo. me,,e,aiat. Vapots of white dust cloud may to esttemely stritating. Contact causes burns to skin and eyes. Runoff from fire control of dilution water may cause pouullott. FIRE CR EXPLOSION May 6gnite othat combustible materials (wood, paper.oit, etel Cont.inet may emplode in heat et fire. EMERGENCY ACTION Meep unnecessary people awsy; Isolate hatatd atos and deny entry. Stay upwind; keep out of low areas. West positive pressure breathing apparatus and special protective clothing. Delay cleanuo until attival of instruction of Quaufted Radiation Authority. FCR EMERGENCY ASSISTANCE CALL CHEMTAEC(A00)424 9300. It water po:lution occurs, notif y appropriale authoriues. FIRE Move contastier from fire ates el you can do 61 *sthout rtsk. Small Fir e s: Ory chemical or CO Large Flten: Water spray, tog of lo.am. Coot containets that are esposed to itames with *ater from the side until weil af tot flte le out. 18 this is impossible withdraw f rom atos and let tire Durn-Do not get water inside centainet. SPILL QR LEAK Co not touch spilled matseial. Try to freeze teamage by coonng at point of opening with carbon dionice (dry fe el. Use water spray to reduce vapor Dut do not put water on leak or spill area. Smell $ pills: Flush area with flooding amounts of *ater on a small part of the spill at a time. Large Spills: Dime f ar ahead of speillot later disposat. FIRST AlD uove victim to fresh air. Can emergency meatcal care. In case of contact wein material immecialsty tiuan snm or eyes with runmng welet for et least 1S mir.utes. Remove and Isr., late contaminated clothing and shoes; shower victim with soap and watet. Keep v6ctim quiet and mainisin normal body tempetsture. Adytee medical personnel thal vicum may be contaminated with raoicactive meterial and may have chemical Durns. O A-60
WVDP-043 Rev. 4 p .r y;.3 n.j r., A .n r, .m ap ap, _f m. [ ( h h r.. y Me lain iNUNmiM n HEALTH HA2.ARDS Poison; estremely hazardous. InhalatlOn estremely dangerous; may be f atal. Ccntact witn licuid may cause trostbite. Vapors nondtritating; but deaden sents of smell. FIRE OR EXPLOSlON Estremely llammable; may be igtuled by heat, sparks of flames. Flame may be invisible. Vaport may travel to a source of Igmt6on and flash back. Containet may esplode m heat of fire. Vapor emplosion and poison Matard mdoors, outdoors or m sowets. EMEMENCY ACTION 7 Xeep unnecess#* people My; isolate hatard stes and deny entry. Stay upwmd; keep out of v. 4:=as. West positive pressute D&Ng appatalus and f ull protective clothmg. Evacuate ates endangered by gas,(See isolation and Evacuation Taote m Dacu [3 of guidebook; find the material by name ), isolate for it2 mile in all citections 11 tant car or truck is involoud in lire. tg' FCR EME AGENCY ASSISTANCE CALL CH Eu TAEC S001 a:4 0 00. Let burn unless lean can be stopped 'mmecimiety. Small Fires: Cry chemical,CO, of walot spray. sm Large Fires: Water spray, fog or team, Move containst from fire area il you can do it without tism. Stay away from enos of tanks. i-Coot containers that are esposed to flattes aith watet from the sice untit aeli af tot tire is out. _1 For massive fire in cargo area, use unmanned Pose holder or monitot nomes;il this is impossible, niihdraw f rom area and iei live burn WithrJf aw immediately m case of rismg sound from ventmg saf et*, cevice or any discoloration of tann due to fire. SPILL OR LEAK Shut of f ignition sources; no fiares, smoning or flames in hazard. area, Stop leak if you can do it without rism, tsotate area untilgas nas discets 1 i FIRST AfD Move victim to fresh ant, cant emergency medical care, 11 not Ottathing, give artificial fespitation
~~3 11 breathing is dif ficult, yrve or ygen In Case of Itostbile, thaw frosted patts with walet.~~
Keep victim Quiet and maintain normal oody temperature. Ef f ects may be detayed; keep victim undet observation a l (3 L.) (! A-61
WVDP-04.1 Rov. 4 c w m v: y.n -3,;gcM y Me c-A Y Mf'8 'f&. 'llo t ti et.'"* 7 J h FIRE OR EXPLOSION Flammacle/ Combustible matettal; may be (gruled by host, sparks of flames. Vapots may travel to a scutte of ignatiott ano flath Dack. Contamat may espiooo in heat of fire. Vapot esplosion hataid indcots, outdoors or in sewers. Runoff to sewer may Croate flte c't emplosion hazard. HEALTH HAZAHOS Poisonous if inhaled or awallowed. Contact fany cause burns to skm and eyes. Flte may produce trellating of poisonous gases. Runoll frein fire sentrol or olluUon walor may cause pollution. EMERGENCY A CTION Meep unnecessary people away; isolate ha2ard atos and deny entry. Stay upwir d; neep out of law are as. Wear sell.cnntained (positive pressure.I avail 4 Dial breathmg apparatus and full protective clotring. Isolete f or it2 re ile tri all directions il tant e st or truch is involved in flte. FCA E A4ERGENCY ASSIS1 AtiCE CAL.L CHEMTAEC1600)424 00,00. Il vvster pollution occuts, notify apotopriate authotibes. i FIRE I Sm ell Flies: Ory chsmical, CO,, watet sotay or fosm. (sege Fires: Water spray, fog or foam. Mo S ccolamer fram fire area if you can do d without ttsk. Stay away from ent : of tanks. Cool c sntarers that are esposed to flames with walet from the side until weil sitet fire is out. Witro a.e immecialsty m case of tismg sound tecm ventmg safety device or sny FI stolosation of tank Que to hie. SPILL CR LEAK ' hut off ig intion sources; no flates, smoning or flames in hazard area. 00 t'ot touth spilled material, stop lean if you can do 4 withcut risk. Use w ater spray to reduce vapors < Small Spdts: f ake up with sand or other soncombushbie absornent material and place mio contamats f or later disposat large $3611s: Cibe f ar ahead of spilt for late disoceal. FIR $T A10 Move victim to ltesh ait: C all emerge 3cy meoical care. If not brealhing, Qive artsficial respiration, ll breathang is oif ficult, Qive osyQen. Pomove and. sol 3le Contaminaled Clothmg and shCes et the site til Case of Contact with material, immediately flush skirt or eyes with runnmg watet for at ledst if,ininules. Keep victim Quiet and maintain normal body temperature O A-62 ~
+ Wpp- 04 3 ROV. 4 ( \\ ~ G4 U J' LIMNHU*h: ?f FIRE CR EXPLC510N Estremely flammable; may be igruled by heat, sparks or flampa. Vapots may travel to a source of igmtion and f' ash Oscu, Containst may esplode in heat of f ate, 3 HEALTH HA2.ARDS If inhalJd, may be fatal. Vapor entremely tiritating; contact may cause Dutns 'o sh m and eyes. Contact with liquid may causa frostbite. Runoff from fire control or d!!ytic I water may cause pollution EMERGENCY ACTION neep unnecessary peopie away; isolate hasard area anc cerny entry. $ lay upwind; hen out of low areas, Wes.t positive pressure reesthmg separatus and tvil Drotective c Ginmg= Evacuate atos endangered i;y gas. lies isotr%n and Evacuation f able in SaCL of guidecook; find the meterial by name.) Isolete for 1 mile an all dltections if tank cat et truth is ihvolved in fire, FOR EMEAGENCY AS$107ANCE CALL CHEMTREC(600)4:4 9300. s If watet poilution occutt, notif y appropriate awthorities. FIRE Small F1tes: Cry chemical, CO,, water spray or ascehot foam Large Fires: Water spray, tog of alcoholIcam. Let buta uniess less can ce stopped immediately. Move container from flie ates if you can doit without tism. Stay away from ends of tanas. Fight fire from maximum distance. For massive hre in cargo area, use unmanned nose noncer or monitor hot 2tes;st this is lmposs Die, witharaw from area and let fire buen Withdraw immeciately m case of rismg loand ifom ventmg safety device of any discoioration of tana due to fire. SPILL OR LEAK $ hut of f ignition sources: no flates, smoking or flames in hazard area $100 leak ll you Can do it without rish Use watet sotay to reduce vapots; do not get w,siev inside container Sm all $ pills: Flush area with flooding amounts of *ater Large Sanlis: Olk e spill f or laine di sposat, FIRST AfD Move victim to fresh air; c all emergency medical case if not breathing, give artificial respleation It breathing is calficult, give on ygen in case of contact with mateeial, imrneciately flush sum or eyes *ith runnmg watet for at le ast 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep viClim Quiet and mamtam normal bocy temperature Effecta (ney De ceiayed, keep victim unoet observallon a ,V A-63
WVDP-043 Rev 4 0 x __..r ,_m,,_ __m &f <r 1 g Waa4 U9/mie M Q, jhg FIRE OR EXPLOSION Extremeiy flammacte. May ignite itself il control temperature is exceeceo. May erotoce from heat or toss of temcerature control. HEALTH HA:'.ARDS Contact may cause burns to skin and eyes. Fire may produce attitating of possenous gases, Runof f ffom fitt Control of gliulion walet may cause Dollution. EMERGENCY ACTION Keep unnecessary peocie away;.solate nazard area and ceny entry. Stay upwinc: keep out of low atsaa. Weaf sell 4;ontained (positive pressure il avastablel breathing aCCaratus and full Ofotective Clothing. FOR EMERGENCY ASS 6 STANCE CALL CHEMTRIC (800)a:4 9:00, if watef pollution occurs.60tily aDDroDetate authorillet. LOSS OF COOLING Scecified control temcetature of materist must te maintainec Cetsin novid ne trogen, cry ice of ice f or coating. If none can De octainec, evacuate area. FIRE Small Fires: Dry enemical, CO,, water sotsy or foam. Large Fires: I'lood fire atos with water. For massive fire in cargo area, use unmanned hose noncer or monilot noutes. Il fire can to con. toiled, cool container with water from unmanned nose hoicet or monitor noutes until weit attot f ue is out, 11 this is impossitie, w ineraw from area and let f6te Durn. SPILL OR LEAK Ce not touch spilled material, Shut of f ignation sources; no flaves. smoking or flames in hasara area spills: Meisten material with water and piece 4 into looseiv covered plastic of liberCoaf 0 contarnef s lot latef Cli Dosal. l FIRST AlD l Svlove victim to f resh air. Aemove and Isolate contaminateo Clotning and snoes at the sste in case of contact with material. immeciateiy riusn eyes with running = ster for at leest 15 minutes. Wash skin with soao and water. ( Keep victim Quiet and maintaan normal body temperature. I 1 l l l 6 A-64
wver-o43 Rev. 4 l 2.c. ye pg ( y, g, .... gy A E* h 114 IteW FIRE OR EXPLOSION May be ignited by heat, sparks of ftamos, May burn rapidly. Container may espioce violonuy in heat of fire. May explode from friction, heat of contamination. HEALTH HAZARDS Contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from life control or ollution *stor may cause podution EMEkGENCY ACTICt( Keep unnecessary pecole away; isolate hazard ates and deny entry Stsy uowind; keso out of fow areas. West self contained (positive pressure tf avadaciel treathing scograt es and I full otetective clothing. FCR EMERGENCY ASSIST ANCE CALL CHEMTAEC (800) 4:4 9300. If water pollullon occurs, notify sooropriate authorities. V FIRE Small Fires: Ory chemical.CO,, water seray or foam Large Fires: Flood fire area with water. Fight fits from masimum d stance. I,. if fles can ce enntrailed, cool container witn water from unmanned nose noider or monstr., sou:es until weit alter tire is out. if this is imposs Die,witndraw itom area and let fire Durn I SPILL OR LEAX Do not touch spilled material, Shut oilignition sources; no f tates, smoking or flames :n hazara area Spills: Moisten material with watet and place it.nto loosety covevec osastic Of fiberCoatd Containers for telef Qasposai. FIRST A10 Move victim to fresn air, Pemove and isolate contamarated Clothing und Snoes al the site In Case Of Contact with material, imtreciately flush eyes with running water for at least 15 minutes, Wash skin with soao and water Keep victim Quiet and maintain noemas tooy temcerature. t 9 i s.: C\\UL l> A-65
WVDP-043 Rsv. 4 G v+Wy$dC'#v%9,fh%A,W4s';ar ' ' ' V h2
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~~l. ley be Ignlied by heat, sparks or flames.~~
Container may enclode m heat of fire. HEALTH HAZARDS ) Contact may cause burns to skm and eyes. ,j Fire may produce attitating or poisonous gases. Aunoff t'om fire control or dilution waler may cause pollution. EME ACENCY ACTION Keep unnecessary coopte away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Wear self contained (positive pressure if available) breatning apparatus and full protective elething, f FCR EMEAGENCY AS$1 STANCE CALL CHEMTREC(800)4:a 8300. If wster pollution occurs, notify appropriate authorities. FIRE Small Firee: Cry chemical.CD,, water suray or foam. Large Fires: Flood fire area with water. Cool containers that are escased to flames with water from the side until weil af ter fire is out. For massive fire in cargo ases, use unmanned hose holder or monitor nomes;if this is impossible, eithcraw from area and let fire Durn. SPILL OR LEAX Shut off egnition sources; no flares, smoning or flames in hazard arsis, Do not touch spilled maleriai. Spills: Moisten material wim water and place i' mto loosely covered plastic or fiberboard containers for taler oisc 0 sal. FIRST AfD Move victim to fresh air, call smergency medical are. Aamove and isotale contaminated clothing and l' oss at the site, in case of contact with material,imrnediately f' is't eyes with runninQ water for at least 1$ minutes. Wash skin with 5030 and w,nter. Keep victim Quiet and mainiam normal Dody temocrature. 6 O A-66
WV09-04
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. MI $4dt) 1 c.maamhai.c y g y,p;l; FIRE OR EXPLOS10N May ignite other combustible materials (wood, papet, oil, etc.L Reaction with fuels may be violent. Flammaeletecesonous gases may occumulate m tanks and hopper cars. Runoff to sewer may cresie fits at e piosion nuard. HEALTH HA7.AR05 \\ Contact may cause D" ens to skin and eyes. F' ire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause collulion. EMERGENCY ACTION Keep unnecessary people away;Isolats huard ares and cony entry, Ventilate closed spaces Defore entering them. West positive peessure creathing separatus and special protective clothmg. FCR EMEAGENCY AS$1 STANCE CALL CHEMTREC(5001a:4 9300, if water pollution occuts, notify appropriate authorities. I FIRS ( Some of these materials may react vic.ently with water. Do not get wtier inside container. Small Fires: Water only; no oty chemical or CO,. ( ! ;i Large Fires: Flood f ate area w'th water. Move container from fire area if you can do it without ttst. Cool containers that are esposed to flames with water from the side until wen af ter fire is out, For masalve fire in cargo area, use unmanned hose hoider or monitor no:2tes; el this is ifnpassible, withoraw frorn are a and let fire Curn. SPILL OR LEAK Keep combustibles (wood, papet. oil, etcJ away from spilled material. 11 you have not donned special protective clothing approveJ for this malui.,1 do not espose yourieff to any risk of this materialtouchmg you. Use wate' 40tay to feduce vacors; do not get *ater inside container Sttsall Spells: Flush area witn floooing amounts of water l Large Spills: Dike f ar ahead of spot for later oiscosai FIRST A10 i. Move victim to fresh air; call emergency medical care. If not breathing, give artificial respiration, [ il Dreathing ts dif ficult, give osygen, i in case of contact with material,immediately flush skin or eyes with tunning l f' watet for at least t$ minutes. Pemove and isolate contammated clotning and shoes at the site. I keep victim Quiet and maintain normal Cody tornoerature. [ Effects may ee delayed, keep victim under observation \\ [, l f A-67 l
WVDP-043 Rev. 4 0 *m v,. a.., - r..w w%r, ;g. c : c
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~ _ tie ts W ia fd ad Ut* /tuie R-. ~,g { g HEALTH HAZARDS Vapors may cause cluiness of suf focattort Esposure in an enclosed area may t>e very harmful, Contact may Irntate of burn skin and eyes. Fire may produce irritating or polsonous gases. Runoff from fire control or diiutlon water raay cause pollution. FIRE OR EXPLOSION 'orne of these materials may burn but none of them ignite teadily. Most vaport are heavier than air. Container may esplode in heat of fire. EMERGENCY ACTION Keep unnecessary people away. 1 Stay upwine, keep out of low are as. West se.tl. contained (po;.itive pressure if availacle) treathing apparatus and full protective clothing. Isolete f or it: mile In all directions if tank cor or truck is involved in fire. Aomove and Leolate contaminated clothing at the site. FCR EMEAGENCY ASSISTANCE CALL CHEMT AEC(800) 4*4 9300, if water pealution occurs, notify apptcoriste authorities. FIRE Small Firea: Ory chemical or CO,. Large Firent Water soray, tog or f cam. Stay away from ends of tanks. Cool containars that are esposed to iames *iih aster from the sace until *eil r af ter fire is out. SPILL OR LEAK Stop leak il you can co it w6thout risk, Shut of f igrution sources; no fiares, smoking or ftames m huard area. Small Liquid Spells: Take up with sand, earth or other noncombustible absor. bent materiat. Large spills: 06he f ar ahead of spill f or tater ciscesat. FIRST AfD Move v etim to fresh air, call emergency mooical care. Il not treathing, give artificial respitation, 11 breathing is Celticult, give ony gen. Remove and isolate contaminated clothing and snoes at the site. In case of contact with material,immediately flush eyes with tunning water for at least 15 minutes. Wash skm with soap and water. Use first aid tsentment according to the nature of theinjury. O A-68
WVCP.0a3 Rev. 4 m w" 4rU IP'[,%
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g:ieisCinfM:f9M:t@;,.ip. p a qij j y -a._.~. FIRE OR EXPLOSION t.attemely flammaote; wolignite itseilif encesed to air. May Durn fspidly with fl&te-burning eff ect. Aunoff to sewer may create tire of emplosion hatard. HEALTH HAZAADS May be f atalilinhaled.gnallowed of absorbed thfough snin, i Contact may cause burns to skin and evt.s. Fif e may produce irritating of poisonous gstes. Aunof f from ilte controi et Cinution watei.nay cause pollution s EMERGENCY ACTION Keep unnecessary coogle away; isolate ha23rd atos and deny f atry. $tay upwind; keep out of low areas. Ventilate closed scaces tetore entermg them. Wear positive psessure breathmg accaratus and futi crotective c:othing. FCR EMERGENCY A$$l$7ANCE CALL CHEMTAEC (800) a:6 9300. 11 water Dollution occurs, notify sectooriate autnorities. r-I FIRE s Sm all Fire st Let cuan unless team can be stocceo immediatesy. Large Fires: Withcraw and let fire burn. Move container f rom fire are a if you can do it withot. risit Coot containets that are empcseo to fismes witn water from the sace untei asil af ter fire is out. For massive the m cargo area, use un:Nnned note noncer of monitor noules;if this is i.?toost,it.se withcraw from area t.no let fire corn. SPILL OR LEAK Co not touch spilled material; stop lean il you can co it aiinout rism. Spills: Cihe ior later disposal; do not apply wstet unless airected to do so. Cleanuo only undet supervision of 4 n escef t. FIAST A10 i Move victim to feesn ait; cait emergeney mecical care il not breathing, give astificial respiration tt breathing is dif fluit, give osygen. j In case of contact with material,imtreciately flusn smitt or eyes witn running j-water tot at least 15 minutes, Remove and isolate contaminalec clotning and tnces at the site. ica Keep vsClim Quiet yd ninintain normal DOcy tempef ature. e i~ l [ i i I N L., h! I i I,. A-69 i
l WDP-04 3 Rev. 4 @#GUlDE 76E *1-=3eR;EssisuvMsw. O BEni==Raef4 M*ermN + xww+=mmmmm DCTTNT1AL Wa*1p03 MRI CR CCPLCSICN Pammaciercarmoustible metenat: may te ignetes by Mest. scarsts er !!ames. May tum rsonaly with liars-cuming effeca., M4V ignate in artset*c3 of 'PleisNrt. Mostril PtsC!len with *4ter. HEALIN MAC. ARCS Mrs may cruoues imtatmq 1r :essonous ;sses. Cantact inav cause turns to siun anct eyes. Runort front are contrui er silution eier ma, cuse seniunon. t'A t s yf.ncv A c~'t* 4 Mets unnecessary pescia awev:isoisia na seg ares sne ceny emer. Etav unwine; sees out of 4* areas. Seif-etmaines treatamq scoarstus (305Al and er..cNess Srstignier's trasecuve cathing anti scavios simites erstecton. Cat.l. ON EMTR EO AT 1 400-414 5300 A3 fccN A4 8':3318L.E. escet1aily I nere a no accas nazareews matenas: team avasianse. PR3 Some of these meteests may reser visiemly with water. I Ce nos ease wesea er fearvt. o not get weier inside cantainer -{ smail Ares: Ory ener ocas. seca asa. urne er sana. Magnemaam 81 rest Use cry sano, wet *. 43 towcer or G.s trsonita powee*. Neove s=maieer 'r7m fire area if ynu en so t..teout naa. eer massrve ' Ire m : sets arva, ase antaannes 90se *.sicer or momtor acces: I this is smoos24cie, *etneraw. rom area ano et 'tre twen. 57'Ll. C R t.D K Oo not touc.9 spilles matereef. Shut off 'qnition sources: no ftart L smommq or iarnes n 'starc ares. Smaal Ory toonts: Nim cean snevet staca trateraas into cean. ary caratainer ana cover" move esntamers from soiti ares. No water en soilleo mater *as: so not get matet insies csntamer. Seedia Oike for later assoosas: se not mooir weier wruess aireces :s so so. Ma gn esium so ils: Caver geweer sciel. tfi sias:ic sneet or :ars to minimate screacing ano seen geweer ery. C*eanuo oniv uncer sucer nsion et an escort. Move unoamageo sacaages from soul area. MRE7 AfD Move vic:tm to fresn air ano ::41 erne"; enc t me iscss cart:.f not tresining, -.ve Jr. bac:41 respirassort: if treatnmq is carncuit. ;ive savven. Wine naterias frsm sain immeciatery; !!wsn tam or s'res witn rNeninq waste !ce at least 'S mirtures. 8 emove and isciate :umaminaies cetning ano srices at tne site. <ees vicm cuiet arta anaentam normal socy ferncersture. O O t l A-70 I l l t i
I WVDP-043 Rev. 4 G i APPENDIX 11 Distribution Shoot O I O 11-1
CONTROLLED DISTRIBUTION RECEIPT ACKNOWLEDGEMEN'I OIL HAZARDOUS SUBSTANCES. AND liA?.ARD005 VASTES fiPILL PREVENTION. CONTROL. AND COUNTERMIASURES PLAN WVDP 043 PAGE 1 OP 3 ( DATE COPY MAIL OF NUMBER STOP RECIPIENT DEPARTMENT RECEIPT 1. 07 J. J. Buggy. Jr. VVNS Phsident and General Manager ,_j j 90 3. 07 R. E. Lawrence Vitrification Project ,_/_f 90 4 D E. D. Picato Safety 6 Envirotmental Assessment _f,_/90 5. D C. J. Roberts Safety 6 Environmental Assessment ,_/_f 90 6. Z 26 R. B. F. eel Site Support _/ j 90 7 K T. M. Conlin Radiation 6 Safety Training _f_f 90 8. R6S D, Beila Radiological Controls _/,_/ 9 0 9. R6S D. Tharnish Radiological Controls ,,,,f_f 90 10. 1 P. S. Klanian Vit ification Test Group _f_/ 90 11. PSD P. S, Church ol Room _/ j 90 12. PSO P. S. Church S/S 0 ice _f_f90 1. A M. V. Damerow Community tations _f_f 90 14, 35A J. R. Greenquist th2 man - rees j_j90 15, 04 M. H. Sgroi Con-er _f j 90 16. 41B L. L. Howard { Astrative Services ,_/_/90 17. N V. J. Cr.y: mant Security _/_f 90 18. N W. J, .>ecurity Catchouse _f_f90 19. C S. nzie Training and Development _/_/90 20, 8 D. iugars Quality Assurance _,,j,_f 9 0 /~~ 21. DOE J. A. Yeazel DOE - VVPO ,_,f_/ 9 0 -23. 41A J. L. Knabe i Radiological & Envirornental Safety _/_/90 24 201 R. F. Ce Platt Operations _f_/90 25. I J. Pau Vitrification Test Engineering ,,.,f_f 90 26. K D. J vard Radiation and Safety _/_/90 27, 52 L. E. omes Records Management _/ j 90 28. K R. A. Conzale: Radiation 6 Safety _f_f 90 29. 205 D. J. Sawyer Main Plant Operations _/_/9J 30, 45 T. M. Gentner Emergency Operations Center _f,_f93 31. N'RSE M. V. Barrett Nurse j_f90 32. V R. J. Fussner LVTS/ CSS Control Room _j,_/ 90 33. R D. G. Feldman Waste Management Operations J_f90 34. D C. J. Roberts Safety 6 Environmental Assesstent ,_f_f 90 35. 61A J. R. Fox Safety 6 Environmental Assessment _f_f90 36. K G. H, Metzler Radiological Engineering _f_/90 38, VHSE M. L. Claramella Warehouse _/_f90 Signed: Date: Revision 3 HF:91:0844 07 19 91 FOLD, STAPLE, AND Pt. ACE IN MAIL PRC0095:12RM l H-2
WVDP-043 CONTROLLED DISTRIBUTION RECEIPT ACKNOWLEDGEMENT Rev. 4 OIL, HAZARDOUS SUBSTANCES, AND HAZARDOUS WASTES SPILL PREVENTIOE, CONTROL, AND COUNTERMEASliRES PLAN WDP 043 -t PACE 2 0F 3 V DATE COPY MAIL OF NUMBER STOP , RECIPIENT DEPARTMENT RECEIPT 39. R A, F. Russillo Drum Cell Operation- _f,_/90 1 40. W P. J. Valenti 1RTS Operations _/,,_/90 M. Gentner West Valley Volunteer Fire Co. _/_f90 41. Frank Noeson Springville Volunteer Fire Co. ,,j_/ 00 42. J. Johnston Catt. County Ofi'Jee of Emerg. Mgmt. _ /_/90 43. L. J. Callo Erie County Office of Disaster 44. i Preparedness _/_ j90 W. J. Clark State Emergency Management Office _/_f90 ] 45. T. Cermano State Emergency Management Office 46. State Warning Point _f _f 9 i J. Roth NRC Region I _f_f 90 47. R. D. Hurt NRC Headquartere _/_f90 48. W. D. Jensen DOE - Ida _/_/90 49. 50. DOE W. S. Ketola DOE. W _f_f90 52. W H. J. Shaffner STS , ol Room _f j 90 53. T. W. McIntomb .adquarter _f,_/90 54 DOE T. J. Rowland - WP0 _f_f90 55. Z 23 G. G. Baker vironmen mpliance _/_/90 n)56. NYSERDA T. Sonntag NYSERDA _/_f 90 57. NYSERDA T. K. Deboer NYSER ,_/_/90 V 58, 56 A. C. Feuz Ra mical Laboratory Operations _f_/90 59. DOE E. Matthews WPO _f_/90 60. DOE C. Leek WP0 _/_/90 61. 37 M. J. Ryan omponents and Services Purchasing _/_/90 62. 305 D. K. Ploetz Plant Engineering _/_f90 63. R D. H. Garland Waste Management Operations _/_/90 64. N W. J. Czyz Plant Security _/_f90 65. A J. D. Chamberla Community Relations _/_f90 66. 305 T. Hughes Site Engineering _f_/90 67. W J. C. Gwynar Process Control Engineering _f_/90 68. Z 26 J. F. Miller Site Support _f_/90 69. 57 R. L. Schatf Vitrification Operations _f_/ 90 70. T N. J. Armknecht FRS Operations j _/90 71. 41A M. N. Haas Process Chem.stry,abe atory _f_f90 72. 5" L. E. Domes Records Mansgement Audit File _f_f90 73. DOE R. B. Provencher DOE - WPO _/_/90 Signed: Date: Revision 3 HF:91:0844 [ ] 19-91 V FOLD, STAPLE, AND PLACE IN MAIL PRC0095:12RM B-3
WVDP-043 CONTROLLED DISTRIBUTION RECEIPT ACKNOWLEDGEMENT Rey, 4 OIL, HAZARDOUS SUBSTANCES. AND HAZARDOUS VASTES SPILL PREVENTION, CONTROL, AND COUNTERMEASURES PIAN WVDP-043 PAGE 3 0F 3 DATE COPY MAIL OF NUMBER STOP_ RECIPIENT DEPARTMENT RECEIPT 74. R P. M. Vlad Radiolagical Projects _f_/90 75. 45 T. M. Gentner Emergency Operations Center _f_f90 76. 45 T. M. Gentler Emergency Operations Center _j_f90 77. 45 T. M. Gentner Emergency Operations Center _j_/90 78. 45 T. M. Centner Emergency Operations Center _f_f90 79. 45 T. M. Gentner Emergency Operations Center _f_f90 60. 45 T. M. Gentner Emergency Operations Center _/_f90 81. DOE P. Van Loan DOE - WVPO _/_f90 82. 41A D. J. Fauch Analytica Environmental Lab, _f_j90 83. 2-24 R. Estep Radio 1 Engi ring _f_/90 84 M V. S. Arakali Vitr tion P s Development _f_f90 05. M S. M. Barnes VI cation ess Development _f_f90 86. 51 P. Burn ens En ing and Support _j_f 90 87. 54 D. C. Burns tr.i fica In-Cell Engineering Af90 88. I D. E. Carl Vitrifi on Test Engineering _f_j90 j 90. 2-18 J. E. Crumlish Eng ng _/,_/ 90 91. 48 V. A. Descamp Vi Facility Project Eng. _f j 90 92. 51 R. \\.. Devlin ems Engineering and Support _/_f90 93. Z 08
~~c. C. Gerwit::~~
fring _f_/90 <^s 94 BLPRT J. K. Lexer Drafting _f_,,j 9 0 15, 58 R. M. Mahany Vitrification Test Engineering _f_f90 96. 57 W. E. Mateer Vitrification Test Engineering _j_f90 98. M K. A. 0-Ahoofe Vitification Process Development _f_j90 99, 305 P. E. O'*rien Site Engineering _f_/90 100. 305 W. J., Potts Site Engineering _f_/90 101. 48 D. J. Rickettson Vitrif. Facility Project Eng. _f_f90 102. M K. R. Routt Vitrification Process Development _f_f90 103. 54 M. A. Schiffhauer Vitrification In-Cell Engineering _f_f90 104 MNT R. E. Vandervort Maintenance _f_f90 105. MNT L. J. Wiedemann Maintenance _f_f 90 106. Z 18 D. C. Meess IRTS Engineering _/_/90 107. L A. J. Huot Project Appraisals _f_/90 108. Z-08 J. R. Horton Drafting _/_f90 109. C B. C. Blakeley Training and Development _f_f90 110. NYSERDA P. J. Bembia NYSERDA Signed: Dated Revision 3 HF:91:0844 07-19-91 O FOLD, STAPLE, AND PLACE IN MAIL PRC0095:12RM ib4}}

ML20079G724

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2.6 BACKGROUND

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