ML20070D694

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Forwards WCGS NPDES Renewal Application,Including Subsequent Ltrs & 0524 to Ks Dept of Health & Environ W/Addl Permit Renewal Info
ML20070D694
Person / Time
Site: Wolf Creek 
Issue date: 07/06/1994
From: Maynard O
WOLF CREEK NUCLEAR OPERATING CORP.
To:
NRC OFFICE OF INFORMATION RESOURCES MANAGEMENT (IRM)
References
WO-94-0082, WO-94-82, NUDOCS 9407120051
Download: ML20070D694 (189)
v • d • e


Text

{{#Wiki_filter:i W9LF CREEK NUCLEAR OPERATING CORPORATION Otto L. Maynard July 6, 1994 Vice President Piant Operations WO 94-0002 U. S. Nuclear Regulatory Commission ATTN: Document Control Desk Mail Station Pl-137 Washington, D. C. 20555

Reference:

1) Letter NA 93-0216 dated November 15, 1993, from R. C. Hagan, WCNOC, to D. Carlson, KDHE 2) Letter NA 94-0012, dated January 25, 1994, from R. C. Hagan, WCNOC, to K. Finn, KDHE 3) Letter NA 94-0094, dated May 24, 1994, from R. C. Hagan, WCNOC to K. Finn KDHE

Subject:

Docket No. 50-482: Transmittal of National Pollutant Discharge Elimination System (NPDES) Permit Renewal Application Gentlemen: copy of the WCGS National Pollutant Discharge Elimination System Enclosed is a Permit (NPDES) tenewal application, reference 1, as submitted to the Kansas Depc ztmerit of Health and Environment (KDHE) in November, 1993. Also, enclosed <d are copies of subsequent letters, references 2 and 3, from Wolf Creek Nuclear

Operaffng Corporation (WCNOC) to the KDHE with additional permit renewal in f ormation',

In the past, WCNOC has submitted the NPDES application for renewal and the approved permit to the Nuclear Regulatory Commission at the same. time. Upon review of the WCGS Environmental Protection Plan, Section 3.2, it came to our attention that the permit renewal application should be sent to the Nuclear Regulatory Commission at the same time it is submitted to the State of Kansas. This is the procedure that WCNOC will ' follow for future NPDES application renewal submittals. We regret any inconvenience this might have caused. 'If you have any questions or concerns please contact me at (316) 364-8831, ext. 4450, or Mr. Richard D. Flannigan at ext. 4500. Very-truly

urs, M_

V /0l4 }</b5 Otto L. Maynard OLM/jad Enclosures (3) cc: L. J. Callan (NRC), w/a M. A. Miller (NRC), w/a G. A. Pick (N RC ), w/a -W. D. Reckley (NRC), w/a ll 9407120051 940706 PDR ADOCK 05000482 P PDR PO. Box 411/ Burlington, KS 66839 / Pflone: (316) 364-8831 An Equal Opportunity Ernployer MT/HC/ VET

I LF CREEK W@ NUCLEAR OPERATING COR Robert C. Hagan Vice Presedent Nuclear Assurance NA 94-0094 Kansas Department of Health and Environment 4 Bureau of Water Industrial Programs Section Forbes Field, Building 283 Topeka, Kansas 66620 Attention: Mr. Kelly Finn, environmental engineer

Subject:

Additional Outfall Analysis Results

Dear Mr. Finn:

Please find attached the additional analysis results for outfalls 002,003, and 005 requested in your letter of March 1,1994. No pollutants were detected in these samples. Please contact Reece Hobby at (316) 364-4168, if you need more information. -3 i Very truly yours, z ff W / obert C. Hagan RCH/jad Attachments i PO. Box 411/ Burbngton. KS 66839 / Phone; (316) 364 8831 An Ecual Opportunity Employer M.'F/HCNET

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l 23t5. 3.3' Olchsoro tsenaldine. (91941l - E 24ts. Otethya Phth11ete (84-66-2) E 25 tl. Otrnethyt Phthalate (131-11 3) 5 260. D6-N Outyi PhtNiste (84742) - N P 27 8. 2,4-Olnitro-tituene (121-14-2) X 28 5. 2.6 Olnitro. tolueno (606-20 2) X 298. DI-N-Octyi PhtMtete (11744-0) N 308.1,2 Diphenyl-hydermine (as Aro. bessene) (122-6 6-7, y 318. Flucranthene (206 44-0). X 328. Fluorene (83 73-7) X a 338.14euscrdorobenrene' 111 A7 Lit 3X c .31;B. Home- ~ chlorobutodiene (87683) y 358. Henachloro. f-cyclopentadiene y ( (7 7.4 7-4) - a 368. Homechloto-Etherts (67 72-1), X 378.Indeno ,(1,2,3-ed) Pyreno (193-39-6): y '3 383. Isophotone

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X t .393.' N ephthetene (21 20-3),, X ,40B' Nitrobenzene - (D8 95 3),. o, X 4 -C13. N-Nitro.. !sodimethyteming y ,(62 75-9) ^ ,-423. N-Nitrosodl-N-Propylamine X (121-64 75 EPA Form 3510 2C [f tev. 2 85) PACC V-7 .;t-CONTINUE ON Itf VE

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1 11P. G-E ndosultan (115 29 7)1 y
" g 12P. $-E ndosultan (115 29-7) 4 y
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Es A s.D. NUMut.H (cogsy fruses jfersa / of For:#e JJ UU ) 8' ALL. N UM uk &# foran Atywerel. OMB No. 2040 00SG ^ ' " * " ' " ' * ' " " coNTiNurn rROM PAGE 3 nF FOf1M 2 e KS 0079057 003 PART C - tf vou are a priman y inatustry and ihis outf ati c6ntams process wastewater. refer to Table 2c-2 in the instructions io ttetes mt.ie which of the GC/MS iractions you must iest f( r. Mark "X"in column 2 a for all such GC/MS fract.ons that apply to your industry anet for Alt, toxic metals, cyamdes, and total phenots. If yo. are not requu ed to mark column 2-a (secondary e-edustines, rwnprorcsr wastewater oestfat/s, arNf tforfrequired 6C/M8 fidclions), inark "X"in Column 2-D for each pollutant you know or have reason to beheve es present. Mark "X" to column 2 t f or eacti pottutant you beheve es atisent. If you mas k Column 2a for any pollutant, you must provide the results of at least one analysis foi thJt poliulant. If you marl column 2b for any pollutant. You tr US!(HoVNIe lhe resu)]s - of at least one analyses for that gmilutant sf you know or have reasost to believe it wdl be diseturgeef in concentrattons of 10 ppb or greater. If you mark column 2b for act denn actylonitute. 2.4 ' demerophertol, or 2. methyl.4. G eterntrophenol, you must provide the results of at least one analysts for each of these pollutants wtuch you know or have reason to twhevt that you d setoetje en concentrattons of 100 ppb or ureater. Otherwise, for pollutants f or which you mark Column 2b. you must either subnut at least one avulysis or be actly descr die the e easons the ;>o!!utant as expected to be discharged. Note that thesu are 7 pages to thes part; please review each caref ully Complete one talito(a// /parjes/ for each outf alt. Seu instroctions for addmonal det.ats and requnements.

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r. Tot.:

044o2241. X ND (0.01) 3 mg/l. 3 1 12M. Thetiturwi j To o 044o 26-ot X ND (0.002 j mg g iau. zine. Tot.: in40ss4i., X-ND (0.02) j mg/l .f U"iN*."$d's* X ND (0.01) 1 mg/1- ~ I, 35M. Phenols' Toia N ND (0.005) 1 mg/l DIOXtN ~* 2.3.7.8 - T otr o. pe:.sciasuc utsutvs 13> . chlorodibento-P-y ?* Otonin (1764 0161 A ~.y. EPA Form 3510-2C (Hev. 2.US) PACC V-3 CONTir:UE ON ItEVEf tSE t IM/U

CONTINUED FROM THE FRONT KS 0079057 Outfall 003 I. POLLUTANT

2. M A N M
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4. UNITS S I N T Al< C g.spreversif NUMULI Q** [,*,"**,

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NOT AP )LICABLE (NOT 4 PRIORITY POLLUTANT) NA NA SV. Bromoform ers-2s-2: X ND (5.0) 1 ug/l 6V. Carbon A [lf2NI"d* X ND (5.0) 1 ug/l 7V. Chlorobenzene sto8407, X ND (5.0) 1 ug/l SV. Chlorodl-U*T13 X ND (5.0) 1 ug/l 9V. CMoroethane. 875 *-3). X ND (5.0) 1 ug/l 10v. 2-Chloro. $7,'"',',' '"*'. X ND (5.0) 1 ug/1 S t V. Chloroform 1 (s? es 3). X ND (5.0) 1 ug/l 12V, Dichloro-- N "2W'"*"* X ND (5.0) 1 ug/l 13V.Olchioro. daflucromethane ~ NO" API LIC/ BLE (NOT n PRIORITY POLLUTANTi NA NA (75-71 81 14V.1,1-Dichloro. Ethane (75-34-3) X ND (5.0) 1 ug/l 15V,1,2-Dichloro- ,.ih.no<1o70s2>. X ND (5.0) 1 ug/l 16V.1,1.Dichloro-ethynne (7s-3s-4: X ND (5.0) 1 ug/l 17V.1,2-Dichloro. j c'a<=a't?847-5' X ND (5.0) 1 ug/l e; iw. u oics.re.,- l N '-- *2*ei ' X ND (5.0) 1 ug/l 19V. E thyIbenzene tin-414:. X ND (5.0) 1 ug/l 20V. M5thyl [: praa'd' 87443-38 X ND (5.0) 1 ug/l 21V. MLthyl [ C.hio,io. (7487 3' X ND (5.0) 1 ug/l E PA Form 3510-2C [Rev. 2-85) PACC V-4 CUN IINUL UN PAGE V g (d E ,h-A

.-r t.e A e.U. Nuuut.es tesmy frusn frenet i est Yewm 8) Uu e a A L.L NUM asL u _ a n, yow ogxqn j CONTINUFO FROM PACF V4 KS 0079057 003 ^~~d-='>'=

t. f*01 LUT Afd T
2. M A N at
  • m -
3. CFf LUENT
4. U NITS
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X ND (5.0) 1 ug/l chior=then. 24v. T.1r.chioro-ND (5*0) 1 ug/l ethylene (12 7 18-41 y } 25V. Teluone ( 1 c'*8-'i p X ND (5.0) 1 ug/l 2SV.1.2 Trans-06chfoeoethytene 1ss4o si X ND (5.0) 1 ug/l 27V.1.1.1 Tal-f chloro 0 thane X ND (5.0 j ug } i71-ss4 23V.1.1.2-TeI-chloroethane its-o a si X ND (5.0) 1 ug/l 23V. Trichloro-r athy12ne (79-01-6 X ND (5.0) 1 ug/l 30V. Trichloro. tiuoronathene t 7 s-e>4> N0' APF LICf BLE (MOT 1 PRIORITY POLLUTANT) l NA NA 31 V. Vinyt Chlorlds (75-014 X ND (5.0) 1 ug/l f o 11 GC/MS FRACTION - ACID COMPOUNDS i j I A. 2 Chlorophenol j -t (95-s7 8) - - ND (5.0) 1 ug/l i 2A. 7.4 Olchtovo. phenol (120 83-2) E (5 A) 1 ug/1 3 A. 2.4 Dimethyl-pheaoi tios-et si ND (5.0) 1 ug/l f 4 A. 4.5 Olnitro-o. [ '**"5 *

  • 2 "

ND (50) 1 ug/l = I lt s A. 2.4-Dinitro-(; phone n si 28 si ND (50) 1 ug/l

la CA. 2-Nitrophenot i

[; (857s-si : ND (5.0) I ug/l 7A. 4 Nitrophenol fj tico o2 75-ND (5.0) I 1 ug/l i i 8 A. P-Chloro-M-1 Cre.aiise sS7 - ND (5.0) 1 ug/l l.> 9A. Pentechloro- ) pheaou m e-si-ND (5.0) 1 ug/l 10 A. Phr.e: nos es 23, ND (5.0) 1 ug/l 11 A. 2.9.8-Trt- '"s*o'72i" ND (5.0) 1 ug/1 1 EPA forni 3510-2C (Rarv 2 05) PACC V-S 8.- mam _ _ _ __ CONV_0muE WMEMrdrs#.

e.,L O *

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3. c 0

.e 5 ne .l y7 .ne st - a 8 8 e5 y1 u P ( / 0 2 2 Bn8 3y 8u2 Br1 0eh 8t 8p1 8eh 8 t n3 0n 0n y t 3 r9 u0 h1 h1 8op 1 r C 8 8 8 8 Re1 8l 0t1 3e1 4ht 5h 6e9 7ht 82, S 5 0o 1 e O 1 8 2 1 9 5 l c G 1( 2( 3( 4( 5A( 6P 7f( 8P( 9 F (2 8 1 e( 1te(1 p 1h( 1 pE 1P 1n1 1pE 1( I.A( 2t. 2I 1 2r i s t Il m ity >j,.!)j i, i l .] form Agnusest a;a a e,o nuuuEen teupy from itens 2 of Forne 1) uu s a:ALL nuuuten l Ogg Na futu.cosc cOnnnurD rnou Pace v s KS 0079057 003 e a a' * ~s'3'

  • n
8. POLLUTANT
a. u a n n x-
3. Errt.UCNT
4. UNITS
  • i. ! N T A M C f. a rn = sara";

^"

b. n,s a x.gQ,,,s,,y,,gv v 4 Lu e; c.Lonc vgre,u,g(eg, v atua-HU s

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=.

.=,,,,,,,, t.j,,,,,,, l 94 ,,,,,,, t.4,,,,,,,, l ,,.,j,,i,,,,,., 'aanoa i tr,,;.- i.i... 1 GC/MS F RACTION - DASE/ NEUTRAL COMPOONDS (contenased* 223.1,40lchtoro. t>ensene (106-46-7: X 23tl. 3.3' Dkhlovo benaldtne y (31941) ^ 243. D6 ethyl Pnthalate 2 y (84662) ^ 252. DemethyI f Phthelete v (131 11 3) ^ 260. De-N Outyt Phthetate. y G4 74-2) ^ 273. 2.4 Dinitro. - tituana (121 14-2) X 28 2.' 2.G-Dinitro. 19ueno (606-20-2) X 218. Dl-N Octyl. + Phtheilte ;. < y (117,B 6-01 300.1.2 Diphenyl-hydrtaine (es Aso-y bearsKc) (122-66-7' 318. Fluorenthene (206-45-0) - X 323. Fluorene (16-73-7),.,, X gg. IllLtLil. X .318. Hona-chlorotsutedlene X (1!7 68-3) a 35 0. Hem achloro-

cyclopentadiene X

(77 47-4). ~ + 6 36 B. Hex ochloro- ,stthene (67-721) i X 376 Indono.. l (2.2.3-esil Pyrene, (193 39-6)' y I

  • 38 8. Isophorone y

-f( 78 6 9,1),,. v,. X j 39fNephthalene 1 .[(91-20-3),.x y,, X MO3) Nttrobenrene 7,(D8-95-31., g X 410. N Nitro-..,. 5 sod tmethylamine. K ,.(62 75 01 < - lj C22. N-Nitrosodl-N-Pr'opylamine X (*.214t4-7 ) EPA Form 3510-2C (Rev. 2-85) PAGE V-7 h____.

ON TtNUC ON HEVE n:;_

CONT Nuco rnoM ynE rnoNr KS 0079057 Outfall 003

1. D*O t.t.U T A N T i, ein A n n * * *
3. Cf Ft.U CNY
4. U NITS 5 ' N T A M C r.. pre.m.st)

I'* " A* '$ ,,,3,,f,,Np c.t.oreG Ygeu je.VAtut vVAs.ug NJ t LI

  • i* * /,*, U,
  • , * ", *, m. M A XIMUM D ABLY V ALUE
  • g*

e o t. <.i-,uuo - yg. =; .=,,,,,,, et,,,,_ j i.... , _, ej,,,,,,,,, i.... ,,,,,, ni,,,,,,,,, .us 'aama i u,-- - i..... C.C/M3 FR ACTION - BASE /NEUTH AI. COMPOUNDS (continued) 438. N-Nitro-diPh.nviemin. X (83 30-6) C48. Phenanthrone (35-014) X 438. Pyrene. (129-00-0) X 460.1.2.4 Tel-chlorotaensene (120 82 1) X GC/MS FRACTION - PESTICIDES 1P. Aldrin - (309 00 2), X 2P. G. B HC (319 84-6) X 3P.$ DttC (319 85 7) X l 4P. *y.DHC (5849-9). X 5P. S.e nc [: 8319 88 8) X 6P. Chlordane (37 74-9)- X b 7 P. 4.4*-00T (5029-3) X EP. 4,4*-DD E - (72-55 9), X 9P. 4,4*.000 (72-54-8) -. X 10P. Dieldeln - (5057-1) X 11P.G Endosulfan l (115 29 7). X I ..;t 12P. h-E ndosulf en j (115 29 7)s X 13P. Endosutten 'j Suttste v (1031-074). ^ .3 '{ 14P. Endrin s s (72-204) g, X 1BP. Endrsn' Ahhhyde y (7421934) ^ 16P. Heprechter g (7s-4441 1 X . EPA Form 3510-2C filev. 2-85) PAGE V-8 CONTINUE ON PAGE V jg _. __ g. -^ - ' _. :r -. ' - +. -? e tra s.s2 eeusauass4 grosey fasane dwua 1 c/ t; ors = JJ uur s'as.L n"uuu"kee - - - - - - -i--~ -m-"* - OAuth it>40401c,,.. ' cowTiwuco rnW PACE v-a KS 0079057 003

1. POLt.U TANT z.sannot'm' L CFf1.UCNT AN E) C AS
4. UNITS
5. INT AKC 4..f+e==urff -

r t m A Asui' u 30 O Av V ALus; c.a.onu Y(o nu e v oc. V A' CITE't ""(( - NU M UC3#

  • 'f,* ' [,*,***,j,* *,*,
a. M AMtMUM DARLY V ALUE pha*pdaMe) i/ ** eda b3c) o
c. ten t. i t uw -

., "j-

m. coteCE n-g yagg.

av.t. tfu, L v A Lv t' ftf e***feMe) - e".IE. I.".*. s e'.". 's ., [3 tej===se ,,,,,[,I,,,,,, i s I ** = = = ,,,,,,,,3,*I,,,,,, tei maa ** m5

  • D" M,*[*,C*

Iel wa =* m. GC/ hts FRACTION - PESTICIDES (continacef) 17P. Heptschsor i. E pozide 1 (1024-57-31 X 1%P.PCB-1242 (53429 21-9) X 1XP. PC81254 - (11097-69 1) y 20P. PCS.1221 (11104-28-2) X l 21P. PC8-1232 (11141-16-5). y. 22P. PC8-1248 ' X D. (12672-29 4) 23P. PC B-1250 (1109e42-5) - y 2&. PCB-1016 r { (12374 11 2) y 25P. Tom aphone (1001-35-2) X iy PAGE V-9 r. 4 3 +. 4 A. F .I 1 1 .i t i 1

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  • l

.;; ' EPA Fcam 3510-2C (Rev. 2-85) ~'? !7 L n ts..n. cuvi te:Myrst l>nttrrtrac orrics: lassic o - 491-t e1 4 4611r.) CouTinuto rnou Tne rnouT KS 0079057-Outfall 005

t. pot t.UTANT
3. m A se et A-
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NUMULt d f ' M;,,C,", * ; . M AXfMUM DAst.Y V ALUE

4. UNITS A

C i IN T A Ki. ( spruere sip I$f [f,gh'[p C.R.ONG 1/;) M U, * ^ ' at NO tst e** fwM. f 1 !*'s .*.",.r , 8lJ,,, _ tit... , jt f,,,,, (.l J.,l,,,,_ t.1 =... vsts as F g gg re O '""T' GC/MS FRACTION - VOLATILE COMPOUNDS l' 8 f,T * "- s.t... ~ v se tv. Acrosein

742 si X

ND (25) 1 ug/l 2V. Acrytonitris. n or is-is X ND (25) 1 ug/l j av. c.ar 1 L 871 *s-2: X ND (5.0) 1 ug/l 4v. els (Chloro-IsNES.'i X NOT APPL CABLE (fl0 A PRIORITY POLLUTAE T) NA NA sv. "s'.*2) ND (5 0) nis-2 x 1 ug/1 6 V. Carbon 1 Tur.chimia. f' (36.23-5) X ND (5.0) 1 ug/l ! ?V. Chlorob.nr.n. X ND (5.0) tics.oo '8 I-1 ug/l SV. Chlovode-t uro=om ah.a. n 24-4a-u X HD (5.0) 1 ug/l 9V. Chloroethan. iisco-ai. X 1 ov. 2-Chloro-1 ug/l na eiavneih-v (11o-754) X ND (5.0) 1 ug/l 11V. Chloroform x ND (5.0) es7-es-ai. 12V. 06 chloro-1 ug/l t bromom.then. ers 21-4: x ND (5.0) 1 ug/l 1 IE!=N.Yh7a., (75-7141 5 NOT APPL: CABLE (N0" PRIORITY POLLUTANT NA NA 14V.1 i ch.n.1-olchloro, <75-34-ai X ND (5.0) 1 ug/l isv.. $ ch 2-oichioco. n o7.os-2). X ND ( 5._0._). 1 ug/l isv. s.t.o ch a p .thvian. t r's a'ss'a-i X ND (5.0) il 1 ug/1

f. !

$7v. s.2 oich$ ara-p Pron.ne tre-e7 se X ND (5.0) il 1 ug/l inv.ty o.chior ~ g or4,u isu.7s-ei, X ND (5.0) h j m inv.sthyid.or. ug/1 p n oo-4 3 4i. -'r X ND (5.0) h, - 1 2ov. una i -4 uqfy v prpmida (74-83-91 y. ND (5.0) 1 ug/l 21V. MIthyl - Chi m t7447 a) X ND (5.0) j i EPA Form 3510 2C (Rev. 2-85) ug/l P A G E V.4 IA. CONIINUL UN PAGL V ' + - ..______.___a __.____m. ___._s__._-_.____m______m___._._ te A S.83. mum taLH (rugey fruso. f fesea J.*/ Fearest fJ Ou e F Ast. Nuktatas ,r. coNTiNuro rnOM PAGF v4 KS'0079057 005 w.g ne,.*(MO Odys, Av - ie w r a 31 o I. pot.LU T Ard Y

2. M A N u
  • A*
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4. UNITS
5. IN T A K C festeriora.ntt U 138 I
  • '. * '.ill1 $'.",l'
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,,NpWVAL c.1.ONG Tj;/, f,)l, VALuL u ~.t as opj. ::: c....,,,, i9,,,_ l ee e g, .i.... ,,,,,, i v,,,,,,,, i.i... ,,,,,,,19,,,,,,,.

t. i...

v su mama GC/MS FFIACTION - VOLATILE COMPOUNDS (conrinuest) i !:,- :2-. i. i... w 22v. M.tnyiene Chloride (75-09-2l X ND (5.0) ( ', 23V,1.1.2.2 Tetra. 1 ag/l ) -i 7",'"3%*"* X 1 ND (5.0) 1 ug/l 24V. Tetrachlore-p. thylene (127 18-4 } X ND (5.0) 1 ug/1 h* 2sv.To n. (1os 48-31 X ND (5.0) 28V. 1,2.Trans. 1 ug/l Dichloroethylene '

g..

risa-so-si -ND (5.03; Ll 2 7V.- 1,1,1-Tri - 1 ug g h iMM*"* - X -ND (5.0 28 V.1,1,2-Tel-1 ug/l chloroethane i7s-oo si X ND (5.0) 21V. Trichloro-1 ug/l L. ethvizae (79-01 e1 X ND (5.0; 30V, Tr6 chloro-1 ug/l I h "is"e7/>'"*"* X NOT APPL.ICABLE (NC T A PRIORI TY POLLUTtNT) NA NA ' i. 3iv. viay' Chlorkse (75-of-4), X. ND (5*0'; l GC/MS FRACTION - ACID COMPOUNDS 1 ug/l 1 A. 2-Chlorophenol-res.s7 a> - X ND (5.0; , /l 2A. 2.4 Dichloro-1 ug nh.noi ti20 e3-2 X ND (5.0; 1 ug/l 3 A. 2.4-D imeth yl. phenst (10547 9) X ND (5.0: 1 cre. 4.6-D! nitro-O. ,,9f i-4A .< -C .oi ts3+s2.it X ND $0) ' S A. 2.4Dintero. 1 uq/1 j pu.a ssi 28-si X ND (5 0 ~.', 6A. 2 Nitrophenot 1 uc/l l M 888 75 58, X ND (5.0 l f 7 A. 4 Nitrophenol 1 ua/l , 1 8'

  • 78< -

X ND (5.01 SA. P Chloro-M.- 1 uq/1 I ,i cre.oi ess-so n - X ND (5.0 l 1

  • SA. Pentechloro-1 uq/1

'"?"*' (8 7**-53 3 X ND (5.0 l 16A. Phrynol - 1 uq/1 [ t osos.23 - X ND (5.0 ) E t t A. 2.4,6 Tri-1 ug/l I clitordph, enol X ND (5.0 ) <se-os.2 1 f EPA foten 3510-2C (new. 2-85) 1 ug/l \\ P AGC V-5 .m.en<%w., ......... CONE 08_UN OR9_DEVE9E__ y l CONTINUED FROM TitC FRONT KS 0079057 Outfal1 005 I

t. pot t.U T AN T
2. u n se es x'
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N T A M C f.. rest.wsoff 4 "^=l(* S.i,S(ci a e.,..,l < _... e. uax euuu onsty vatusc Yv^tuc

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  • tot...
  • u GC/MS F ftACYlON - BASE /NEUTHA L COMPOUNDS V
10. Acenophthone (33329),

X 2B.- Actnephrytone (208-93 8) X

33. Anthracene (120-12 7)-

X

42. Ben Idene (9247-5),

X n

58. Bento (e) i Anthrecone y

(56-55 39 A i C2. Esnro (e). Pyrene (50-324). X 7 8. 3,4Benro-fluoronthene - N (205-99-2)- ~ '

83. Eento (thi)

Perylene (131242) N C D. Senso (41 Fluorenthene.' - (207-08 9). N l I 103. Bt3 (2 Chlorr> ethory) Methane - (111 91-1) X 110. Bis (2-Chloro-4 ethyl) Ether. (111-44-4). X i28 Bi (2 Cfd . s - arme-prom Ethor(102W1) X s 138. Ola (2-Ethyl-A hery!) Phthalete (11741-7) X 140. 4-tsromo.. phenytPhenyl Ether (10155-3) ' X 152. Butyl Denryl PhthsAte (85-68 7) y t*' Ite. T-Chloro-i nephthilene (111 58-7) X 178. 4-Chloro-phenylPhenyl~ Ether (7005 72-3) X 18 8. Chry sene (218 C19). '198. Dbenso (m.h) Antheacene (53 70-3) X 203.1.2 Olchloro-

  • tzenzene (95-50-1) 210.1.3 Dichloro.

teenises (541 73-1] y 4 5 i E m V. if t t.- i I t a.e N r O_ p e 1 E t U-N _- e a I K e i I A N T a O N 7 C I o E ~ m^3' c 1 m0* t 4o* awg - s. A x '- sa= S m7g T r u a" o . Fod I N U 4 "^ s m t. u. n t. us A V u i. u i n uL A5 M_ u T s. s y v0 r0 o G y, 7 n ) V a o E m L. .a r c o G f A-s., 2 N au. P. f o T A m C v U_ e v o t p k t e M t n F o F r C f, t p p.

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1. PO L t.U T A r4 T
2. u n n et m'
3. E rFt.U CNT
4. U NITS S. IN T A K C (.epshuself ha f shf'*a"e a.b'-

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( ist -easa8det .}* t. T H AT BON ,,,m p,s,,,,, g.g ,,,,, c, g,s,,,,,,,,,

g. g....

,,,,,,,,,),,,,,,,, e.g.... v.. s gg (elesmoe Th GC/MS FRACTION - PESTICIDES frontdamedJ 17P. Hepischsor E pozide v (102457-3) ^ II P. PC B-1242 (53429 21-9) X 19P. PC B-1254 (11097 69 12 X 20P. PCO-1221 (11104-28-2) X 21P. PCB 1232 (11141 16-6). X I-22P. PCD-1248 (12372 29-6) X 23P. PCB-1260 (11096 62-5) X 2"P. PC 81016 (12374-11.2) X 23P. Tom ophone (8001-35-2) X PAGC V-9 4 e 1-1 a ...l I I' a ' -l EPA Form 3510-2C (Rev. 2-85) W u.c. covi:te:Mrmt Prtircrnic orrIct: 19:16 o - 4 #1-19 1 t 46i 16:

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~- ,.') i W4pLF CREEK NUCLEAR OPERATING CORPORAT10N Robert C. Hagan Vice President Nuclear Assurance January 25, 1994 NA 94-0012 Kansas Department of Health and Environment Industrial Programs Section, Bureau of Water Forbes Field, Building 740 Topeka, Kansas 66620 Attention: Mr. Kelly Finn, Environmental Engineer ' q-

Subject:

Additional NPDES Permit Renewal Data

Dear Mr. Finn:

The additional monitoring of outfalls 001-006 required to complete part V-A and part V-C of the NPDES permit renewal forms has been completed and the appropriate forms are enclosed. Please contact Brad Loveless or Reece Hobby at 316-364-4168, if more information or additional monitoring is necessary. Very truly yours, obert C. Hagan Vice President Nuclear Assurance RCH/tir Enclosures ,.O. Bcx 411/ Burlington, KS 66639 / Phone: (316) 364-6831 An Equal Opportumty Ernployer INF/HC/ VET

'y ,.. ~.... Sewage-Y EPA 8.0. NUMDER (copy from Steers 2 of form 1) - PLEASE PRINT On TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of [, NMMN r .gggg thei ia'armeiion aa se;ura'= sheets tuse '^e same tormer> iasiead of como etino these paces-KS 0079057 4,,, ue,,e,i.2,.ss. P1 ant srr INSTiu sCTtON! V. IN TAKL AND E F t.ULNT CilAft ACT EfttSTICS (cmstinutv/ from pay J o/ Torm 2-C) 1 ft A j l'AllT A You enest provitle the results of at Icast one analysis for every pollutant in this table. Compfcte one table for each outfall. See instructions for athlitional details.

2. CFFLUCNT
3. UNITS
4. I N T A K C (espriemoff (8f'#fil' II M*"h)
    • M ^ ^ '

Y V A Lu L c LONG Tg g .VALUE I. POLLUTANT

m. M A xsuuM O AaLY V ALuE f" 3,N1 a LON r. T r' HM
d. N O. O fr AV E H acer V A t u r-h N O. O sr I'I*****

telseate ANAWM ^ c,, g, h,.,,,, td mass T r4 A T N eger .. v. e,. conce s ee m een.e cn=ce

a. *siochec ucal Owvoen D ernand -

moni 3.3 317.3 28.0 2,120 9.4 423 58 mg/L g

b. Chem 6 :al.,,.

Omvcan Demand - 32 3,076 1 ppm g <com 1 - c'.. Total Organic ; ca, dor goc)f:7 -8 769 1 mg/L g 1 rL'T'atal S uspended 5 '!.d'! ' 'E - 4.4 423 9.5 719 3.8 171 58 mg/L g o.*A mmonia (as N) .. > -.s

'e 0.2 19 1

mg/L g sALuc vaLuE VALuc VALUE .e, t g.. .,y @f$*iE9 'Ji,' O.0254 0.0200 0.0119 58 MGD sAtuE VALuE vALuC vAtuE c',Tems>eratura, (='!a29:M 21 18 17 25

  • c

% A LUE VALuE VALuE VALuE h Temram e ; r.ummeri ~ 28 26 24 27

  • c OINtMUM MAMSMuM MANIMuM MAA8 mum 6.7 8.1 7.2 7.7 57 ST^"

^" ""'TS PARTU. Mark "X" in column 2-a for each portutant you know or have reason to believe is present. Mark "X"in column 2-b for each pollutant you believe to be absent. lf you mark column 2a for any pollutant which is ? mitad eather directly. orindirectly but expressly. in an effluent limitations guidelann. you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column ' a. you must provide quantitative data or on explanation of their presence in your dischargo.Completo ono table for each outf all. See the instructions for additional dotails and rcquirements. 1.POLLUT.

2. u a u n x -
3. CFFLU CNT
4. U NITS
5. INT A K C ( priencedf)
b. Maxagg3}glgv V ALUE Mp

.VALuE c.Lu M G T .*.U,+ la. w'.***;

s. M AxiMuu ABLY VALUE

<1 N O. O F C ". N O* a LON CEN., A E A vALuE tk N O. 0 F ANAL

  • It M ASS ANAL.

(If et elleMc) s. a. - seest (3) somse ,['f la) *s a tt. g,,y f,h - (a) me mes. YSES

  • ^

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  • VRES ac nromi.M.

124959-G7 01 s tdChlorine,",.'t To,..tal Flesidual'.u -.<~J .. u % w?. escolor 'd2'fn L : d, Fecal Ti -!;. w.lif orm, p...', :, Co ma- 'ef FIUorIde: M. (1698,4-48-8)O. 4 f.' N itrat h 4. Nitrito (as N) EPA Form 3510-2C (Rev. 2-85) PAGC V.I CONTINUE ON REVERSE J l as g

--..-w_, Site EPA .D. NUMSErt (copy from item J of Form J) ' ' ' " ' " d Pt. EASE PRINT OR iYPE IN THE UNSHADED AREAS ONLY. You may report some or a!! of 04fs no,*o"4o.oogg Oil / Water -( ir s i..rmination on sn.arme sheeis tuse the same torrnarl instead of compieiina these paacs. KS 0079057 emmi .pe, tar.ss Separator ' ] Sf r (NSTnt #CTIONS V. IN T AKC AND ri.< LilENT CHAR ACTE HISTtCS terwr6nucef Iroen pane J of Fruerre 2 C) ( 002 PAlt T A - You mn.t provnfo the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for acklitional tictails.

2. Cf FLUCN T
3. U NITS
4. INT AK C (oforumal)

(*M/' If 8'I*"O _. M AMsMuu o A Lv V ALuc

b. M AM sg,sjM,,,3,,y, y v ALu c c.LONc Tgayg.. V ALur.

I. POLLUTANT r o

r. v r n M I'I""**

co-cab)..no= I'I " * * * ' co=ech.. vee. I'I " * *

  • H ATS N l8I Matt

^" g,,,,, c.me e

n. nom
a. u sochern.cas. <,

Ouvoen Demand'. (5.0 (7,703 1 mg/L g mom.,n -

b. Chemicalew s Osvoen Demandt" reoor.wM 10 15,505 19 73,497 12 18,940 58 ppm g

c.'.Totst' Organic.S C*'t*" ("C1 @ 2 308 1 mg/L g ) dlTotal Suspended S 'B'E8!'M 41.0 <1,541 10.0 38,683 3.7 5,840 58 mg/L g , _..s,_. e.: Ammoniafas N) ND(0.1) (154' 1 mg/L g -t.w..; ;.w

4. ut %.M
a.
  • VALUE VALUE VALUE VALUE hE'.'~@E 0.407 1.022 0.417 58 MGD vALuE VALUE VALUE VALUE gaTamperature.

C o inrarJ.n.n 6 1 v A tu ai VALUE VALUE VALUE g (summer). C ssHtMUM ~ M A ARMUM MtHtMUM M AM BM UM ["" 7.1 8.3 7.6 8.1 57 ST^" ^""""ITS PART 0 - Mark "X in column 2-a for each pollutant you know or have reason to bettove is present. Mark "X"in column 2-b for each pollutant you believe to be obsent. If you mark column 2a for any pollutant which is I mited either directly, or indirectly but expressly. in an effluent limitations Guidelino.you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column i a. you must provide quantitative data or an explanation of their presence in your dischargo. Complete ono table for each outfall. See the instructions for additional details and requirements.

1. PO LLU T.
2. M ^ n M ' A -
3. CFFLUCNT
4. UNITS
5. I N T A K C (opfsoesdif l' M^^ % ",,,3, @ j c.LoHG Tge,M gg. V ALUE,t N O. O F vvaLuE O'**=7 UA
  • I=';
a. M A xlMuu O AILv V AttJE
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];),,,,,, gag um , {),,,_ g)... , {gl,,,,_ .q,3 a., ygg[

  1. ^
  • MAUON (if availabic)

]ee n tene. !'I " " YSE s==t e nsec a

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(24950.G7-9), ~, b3 Chlorine.*.Wt T.otal Residual * .a ~ w " [Co'ioNb w : c;;.7 d Fecal C' %' Cofiform, ;. e? Fluoride.. (1 GD84-434)

f. Nitrato-.

Nttrite (as N) i EPA Form 3510-2C (Rev. 2-85) PAGE V-1 CONTINt)E ON REVERSE e~ .;~m-- m -. m

Site Oil / Water Separator y EPA S.D. NUM BErt (copy from flem J ef home JJ OUTFALL NUMoER farm A xpresed t KS 0079057 CONTINUED FI' TOM PAGE 3 OF FOrtM 2.C PART C - If you are a primary industry and this outfall contains process wastewater, refer to Table 2c-2 in the instructions todetermine which of the GC/MS fractions you must test for. Mask **X"in coturnn 2 a for att such GC/MS f ractions that apply to your industry and Ior ALL tonic metals, cyanides, and total phenols. If you are not required to mark column 2.a (secondaryindustrict. nonprocess wasrew sfer outtaf/s. and nonrequircef GC/MS fractions /, mark **X~ in column 2 b for each pollutant you know or have reason to believe is present. Mark "X"irt column 2.c for each pottutant you beheve i 5 absent _ if you mark column 2a for any pollutant,you must provido the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results nt at lea st one analysis for that pollutant of you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrotein, acrytonetnic. 2.4 demtrophenot, of 2-methyl.4. 6 dmitrophenol, you must provido the results of at least one analysis for each of these pollutants wtuch you know or have reason to bcIneve that you discharge in. Concent atcons of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b. you must esther submit at least one analysis or bnefly describe the reasons the pollutant is expected to be disch ArDed. Note that theio ato 7 pages to this part; please review each carefully. Complete one table (all 7pages) for each outfall. See instructions for additional details and requirements.

1. POLLUTANT
z. M a nn x'
3. EFFLtJ CNT
4. UNITS 5,, IN TA K C (oprimselJ N M i
    • "u** uew*eess. = = -a. M AxlMUM O AtLY V A LUE IA "^^$,If,,$Ny ts a c

vVALUE i C.LON G T fM .VALUE eves d NO.OF e. ,,T,' fg),, g,g... ,,, )_ej,,, _ g,) ),,,,, g,) ysgs aCONCEN. ANAL. tg M Ass AVE I AG [ V ALUE (J/ esasila bic) ,,M ANAL

  • TR ADOM tog,7, g,y...

yggs =. METALS, CYANIDE. AND TOTAL PHENOLS r 1 M. Antimony., ND Total (7440-3G 0) X (0.006) 1 mg/L d 4 au; Ar nie.. Tot r ND i!44xa.23- ). (0.01) 1 mg/L 3M. D.rvilium.- ! bD vo.t=t. 744o.4 i.7) : X (0.004) 1 mg/L ND AM/ Cadmium.- e Tot m44o.43.or (0.005) 1 mg/L 5 Ml Chromium.t ND Totaip44047 3> (0.01) 1 mq/L CM. Copper.' Total h ; ND U"O* 8M ' ' ) (0.02) 1 mq/L 7vi o mi; ND puisW ^ X (0.003) 1 mg/L eu: M reurv. Toi.: ND (7439 97-6); ) (0.0002) 1 mg/L oM; Niew.i. Totot. ND (?44op2 8 (0.04) 1 mg/L i cu. c..ntom. - ND . Tot.i t77a2 49 23 ) (0.005) 1 mg/L iiu suv.r. Toi.i ND .t 7.d 40;22.-E-X (0.01) 1 mg/L 12M3Th'aillums ND Totsi.c7440 28.oi X (0.002) I mg/L 13M. Zinc. Total. **?1 "? 4

  • 5 X

0.03 46 1 mg/L o

Gu!Cv.nw.y ND Totet is>.3 2.s' '

X (0.01) 1 mg/L 16M. Phenols. ND T* I*' X (0.005) 1 mq/L DIOXIN 2,3. 7.8. Te tr a. ouscenuE HEsutTs chlorooit.nro.P. Dionin (17G4-o t-G) EPA Form 3510-2C Plow. 2-05) J PAGCV.3 CONTINUE ON REVERSE .g; ---. n u-m - - -. -- -

m. I .,.-w. ~. g,, era..o. HUMoca econ from s,,- 4 w rorm er Circulating f,,,,, % Water. PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of "" "" # '#'c,, thig information on s 'parate sheets luse the same format) instead of completing these pages. OW9057 4yirevatrywres /.J7 33 Discharge ..fT INSTitt PFTIOP:9

v. int AK E AND i r F LUCNT C6 fAR ACTE nl5 TICS (crmtheuert / rom puge J of form 2-C t-0$

l'AllT A - You n ust provide the results of at least one analysis for every po!!utant in this tabic. Cnmplete one table for each outfall. See instructions for aciclitional details.

2. CFFLUCNT
3. U NITS
4. INT AK C (opritmd)

(specifv if blank)

1. POLLUT ANT I
a. M A xlMUM D AILY V ALUE
b. M A M EMpF a*y vVALUE
c. Lor 4G T IM py. V ALUE

( lM 3 J

d. N O. O F AVr n AG E V ALur 91 h 0. O F 4

' n AvQ"g ANALvses 11 M Ass e,.),,,,,,, g,y..., "" ^ 'Y S E S

n. u achemx.:, '

.'.'..,.og I' 3 " * *

  • c o-c dl '...

I' 3 " * *

  • c ome. U/..,.o l'I " * *
  • l w.

Omvoen Demand < 3.0 <68,700 1 mg/L kg enom - 1.<- ti. chemicas.y - g. Onycon Demsnd' 16 366,600 1 ppm kg rcom

e. TotsI' Organic 3 j

Corpon <Toci f 6 137,000 1 mg/L kg d.'Totat Suspended 5*'"" !"G 6.5 149,000 1 mg/L kg ND e ' Ammonia (as N) (0.1) 1 mg/L 3. VALuc vAtut vAtut VALuE f.. F low t 7'."'~ .w 605 844 708 379 MGD VALUE VALUE VALUE VALuE gfTemperature 'd".9'# C* 27 ~~ 1 ^ ^ ^ h.' Temperature i (summer) MINIMUM MAXtMUM MINIMUM M AX4 MUM ~ S'^" ^" " " ' '

  • 8.2 8.7 8.2 8.6 113 PAftT B - Mark in column 2.a for each pollutant you know or have reason to behove is present. Mark **X" in column 2-b for each pollutant you believe to be absent, if you mark column 2a for any pollutant which i, hmited either directly, or indirectly but expressly. in an offluent limitations Guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants Ior which you mark columr 2a. you must provide quantitative data or an explanation of their presence in your dischargo. Complete one table for each outfa!!. See the instructions for additional details and requirements.

I.POLLUT.

2. M A n n
  • x *
3. CFFLU CNT
4. U NITS
5. INT A K C (ortriemalf

'"^^ f l c.LONG Tga,Mgg. v ALu c et N o. Or A N* A"cc EA Lu t vVAtuL "M C SNO '* Y'

  • I **U
    • ""*'"""U"YV"'"U t1 N O. O p),,,_

a c t N-g)...., gl,,,_ g,3...._ "y"s^gI A ^ (f/ spanable') ,U ,,,,, j;),,,_ gn)....

  • 4 ATION e

e,, L.),, g, g,,,, ysc s/11romitteL 124359-G7 9)l,; tC Chlorine /#4 Total Resid.u.al.' = %.w - 4 ./ W w N ec c.',Colo wy M72}r V..p; dJFec'st C f4. C5f0.5%M b ruer'ideg), 'i-Q.6,98Q-8,

f. Nitrite-NItr,lteJas N)lg EPA Form 3510-2C (Rev. 2 85)

PAGE V-l CONTINUE ON REVERSE

Main Dam Discharge into Wolf Creek era s.o. nuMeEn scopy from 1sem 2 of Form 23 y,,,,,,,,,,,g PLEASC PRINT OR.'YPE IN THE UNSHADED AREAS ONLY. You may report some or all of O&f8No 20400036 ibis inIormation un s. urate sheeti tuse <^e same formar> insiead of compictino these paces. KS 0079057 e,y i o, , 72,.,, nrF tn5Tf stlCTs()W gfW Jg7W Cf ','Wh _ C {HW* ] L" yJ W ,,,q'A ' ' '<*e. FM em e e a s a. Nes f fu "gf' d f 004 V. INT AKI. AND C 'r t.UCNT Ce tAnACTCnISTICS (corethmert from pa<p J of rome 2-CJ J. l' Alt f A - Yote m at tuovnic thi results of at Icast one analysis for every pollutant in this table. Complete one table for each outf all. See instructions for additional details..

2. CFFLUCNT
3. U N ITS 4, I N T A K C (.+resseuwl)

(specify if blanid C,LO N ti Tg M , V A Lu t. . u,n,;,,,, l*"^^'$/",d,7,RpjvVALUE

1. POLLUTANT
a. M AxsMuu DAsLY V ALuE

<s. No. o r A.vinAG r v A t u r tsNo or S ON AN ALYsES t t) eaa.e f,,, y (3) ma a... {al ea a.. AN ALYSES t1 M ASS el g,g,,,, g $ N ,,,,,n u.oe-., ,,"E"%"!'"d 43.0 <11,582 1 mg/L g

b. Chemicalm g,-

rcom e.yym' 19 73,353 1 ppm g Osvoen Demarnt-*. e.".To t al' Organic N i cyb,aRS>@ 6 23,164 1 mg/L g ,_.) d.'. Total Suspended SafoM 17Yr 17.2 66,404 1 mg/L g -c;- m. m no

e. Ammonia (as NJ
    • me (0.1) 1 mg/L

,, ow VALUE VALUE VALUE VALUE er ove.by*y as @ Min.?lu 1.02 90.63 12.93 40 MGD VALUE VALUE VALUE VALUE OTemperaturg n C 0,'".'?T&" 12 7.5 6.7 40 g "^'"E "^'"E "^'UE VALuc g T e rature 1 ,C 29 27.5 25.2 40 i rilNIMUM ~M AXIMUM McMIM UM MAxtMUM "'^" ^" ""'" 8.2 8.7 8.3 8.6 N 40 PAllT fl - Mark "X

  • in column 2-a for each pollutant you know or have reason to behove is present. Mark "X"in column 2-b for each pot!utant you believe to be obsent. If you mark column 2a for any pottutant which is :imited either directly, or indirectly but exprossly. in an effluent limitations guidolino.you must provide the results of at least one analysis for that po!!utant. For other pollutants for which you mark column Oa. you rnust provide quantitative data or on explanation of their presence in your dischargo. Complete one table for each outf all. See the instructions for add +tional details and requirements.

t. PO Lt.U T.

2. M a se n x-
3. CFFLU CNT
4. U NITS
5. INT A K C /vereriesswif

"^^ %$d,7.$$[ h[a aske

  • ^

^ E 3 g * [.'.U..'s.[4 .[e' r1 N O. O F

e. M A x tM U M D Alt.Y V ALU E e LONCEN+

A E A V AL 8E A N A L-tx M a sS A N A La " ^ T '0 " ,,,,,,.!,*),,,,,,,,, tel = a.s vsEs y,,,. j'),,,,,, t:3 =... , j ');,,, I.3.... ,,,,, j,),,,,,,,, t.3...... vsEs (i/ evaile bic) we 4

m. nromhte.

(24959-G7 9)l;

b. Chlorine,N,

Totst.nu, iduelt ~..,. < > .%gge. ) * 'c ' Co lo r"'; 'Q ~ L'-/ N...

d. Fecs! W Co,i,iform], Q e' Fluoride A

(1 G98,4-48-8) E f/ Nitrate-- N.itettejas N)) PAGE V.I EPA Form 3510-2C (Rev. 2-85) CONTINUE ON REVERSE

..~.. -. ~.. ~.. l r. Wastewater Retention Pond Discharge EeA s.o. NuM aER (Cvisy [rons idem 8 of form A) y,,, ppp,,,,4 .PLEASE PrtINT Ort TYPE IN THE UNSHADED AREAS ONLY.You may report some or a!! of 0.4rB No. 2040 C036 ~ this information on separate sheets (use the same format) instead of completing these pages. KS 0079057 . wr-aie -s ms ST F INSTfttlCTION7 V. IN TAKt' AND E r r L tJENT CitAft ACTETtISTICS (ccmri, ment trewn p.mp J of form 2 Cl l'AllT A - You m.ast provitte the results of at least one analysis for every pollut. int in this tabic. Complete one tatste for each outf all. See instructions for additional details.

2. CFFLU CNT
3. U NITS
4. I N T A K C (esprkmarf

.VALuE l'r'P#II' II N""I'I c.LONG TgN p '# " ^ ^

  • l/"a=3 7,J,y1 VALuc am,mm
l. POLLUTANT
e. u A xeMuu D AILY V Atut fi ts. No. o r uf.nA.c. c v u u r h no. or co.ceN)...

l*l***** concrN...o. I'I "* ** c o-es N/Ja e.. I'I " * coe,NI..v... l'I " * HAT

e. niocham.cas onvoen Demand
mon, 4.3 1

mo/L

b. Chemicat w.n Omveen'Demandcg.

(CODINWT"dY i 29 1 ppC cJTotal Organic ? C.a_rbon.'tTUC. J.h. #d6 1 mg/L 1 d.' Total Suspended 8*"d' Irs,s; M 32.6 27.1 713 11.7 308 9 mg/L kg ,~ ...r...

e. Ammonia (a* N)
  1. e. e ew 13 1

mg/L f r <ALuc

  • ALuc watut vALuz c #,%

not vt ec no,,i m ' ND, 1. discharoina 6.940 6.015 8 MGD ' ^ Lu a. VALuc VALuE V A 4.u E i ofTemperature ; <-erna i^ 5 1 sALuE VALuc vAtuE vaLuc I S T e rature. (ru mmer) - C h41 NIM u M M A ARM uM MINIM uM M AA8 mum i t "" 57^"'^" """5 7.3 8.1 7.6 8.0 8 f l'AIIT D. Mark **) "in columrt 2 a for each po!!utant you know or have reason to believe is present. Mark **X** in column 2-b for each pollutant you believe to be absent. If you mark column 2a for any pollutant which idimited either directly, or indiroctly but expressly,in an offluent limitations guideline.you must provide the results of at least one analysis for that pollutant. For other po!!utants for which you man k column 2a.you must provide quantitativo data or an exp!anation of their presence in your discharDe Complete one table for each outfait. See the instructions for additionaldetails and requirements. t.POLLUT.

2. u a u n x -
3. CrFLU CNT
4. UNITS
5. INT A KC (vrirsewwlf ANT AND C,

g'. sao ,Ih,Mah) We"abe '1NO.Or A A* AL E ^*

    • ^
a. M A KIMuM D AILY V ALuE CASNO.
        • u****

a LONCE N-ANAL

  • th M ass ANAL *

(I/ oc. rile Nc) 37 I s'."i ,,,. j '). ta) naass y,,,,, h).,,,,,, Is) = ass c o,,., j,')..,. fel wass vsEs M ATson e o,,c, p),,,,,,,, g,3... ysgs

a. Bro.nide-(24959-G7-9)
b. Chic.rine..,

T.otal nesidual: ..y d.: Color,h, 4 t .m ti. Fecal ' Collform E

s. Fluoride ',

i f1G934 48-8)

f. Nitrate-
  • i Nitrite (as NJ P

EPA Form 3510-2C (Rev. 2-85) PAGC V.I CONTINUE ON REVERSE

y. s.,._.._~ Wastewater Retention Pond Discharge EPA s.D. NUME.ER (copy from Jfens j of Form J) OUTFALL NUMBER form Acproved KS 0079057 005 OM8ko 2040 Doss CONTINUED FROM PAGE 3 OF FOrtM 2-C up,o.,,,.g.,,s u s.ss PART C - tf youare aprimaryindustryandtbisoutfaticontainsprocess wastewater.refet totable 2c-2 in theins wastewe.ter outta//s. andnonrequired GC/AfS /ractions), mark "X"in column 2-b for each pollutant you know or have reason to beheve is present Mark "X"in column 2 c f. n o umn of at lea t one analves for that po!!utant of you know or have reason to beheve it will be discharged in co - or each po!!utant you dirutrophenot or 2 mothyl-4. G doitrophenol. you must provide the results of at least one analysis for each of these poitutants which you know or have reason to bebe be disch. rged. Nor a that there are 7 pages to this part; please review each carefully. Completn one table (all 7p you discharge m

l. POLLUTANT ie e s.
2. u A rt e x*
3. CFFLUCNT 4 UNITS
5. I N T A K C (<3prioneff

,f,1 %",,*,,ag

e. Maxsuuu D Asty V ALuc l'"^^'Tf,M.M3 NUMUCI vVALuE c.LohG Tyrujyjge.VALuE No r j DON ts. N o r (if sped 4McJ

. i."O ,."J, j(), g,3..., I, g,3... je),, (al was, v st:s TR ATION TE M g, 3 METALS. CYANIDE. -\\ND TOTAL PHENOt.S c,n=c e w. tal se e ts VsEs iu. Antimony. ND Tot. tu4o-3s-m : ( (0.006) j 1 mg/L 2M; Arnnic?. Total-ND (7440-38-2) Myg f gJj } j g/{ 3 urn.rymumc. ND Tat =47440-4 2 -7 @.004) 1 mg/L au. c.amium ND Totet744.o-43 9)' (0.005) 1 mg/L su. cn,omium.w ND T.*J'LP,*,do-d7-3) *: X @ A1) 1 md tu:c e e:ratal.- e ND !7440-50-8)l: <->f " (0.0o) 1 mg/L ,75Ais$f.Totala ND R'3S:S?fT (0.003) 1 mg/L culuircury. Tots: ND (7,439 97-C) f ',.- 1 (0.0G02) 1 mg/L ou. Nient. Toi.i,: ND (7440;02:0)g, X (0.00 g 1 mg/L 10MISElsntum' W bO .T?.tysmag49;2i:- X __ (0.005) 1 ng/L 1 t u7st:4r; Tot.t ND Rd'a2'i'Me. X (0.01) 1 mg/L 32u::Tremu,n7e ND 7stS(?d40:28;mi X (0.01) 1 mg/L 130.7 sac. T'o ritis. ND !%9Eol:M X (0.02) 1 mg/L 14urchns..e ND Toro.is712.s Ti X (0.01) 1 mg/L 15M Ptwnotsc Tate X 0.012 1 mg/L OtoXIN 9. ~ 2.3. 7.0-Ta tr e. DEsCatIEE HEsuLTs +.. entoroditwrnzo-P. Diozin (1764 01-6) EPA Fstm 3510-2C (R ev. 2-85) P AGE" V.3 CONTINUE ON REVERSE

Essential Service Water System Discharge CPA s.o. NuMoEn (copy from $lem 2 of form )) y,,m v,,oved PLEASE PitINT Oil TYPE IN THE UNSHADEO AREAS ONLY. You may report some or all of OAfR h 20,fo-rxMG ilus information on s -parate sheets (use the same format / insteast of completing these pages. KS 0079057 m, ,,,,,,,,, u, s, M r INSTittiCTION ' V. tNint;C AND t: F LUENT CalArt ACT[Ill5 TICS kontinucci(trun n.sy 3 01 form 2 C) ~ f l'All! A - Wu rF:st provitle the results of at least one analysis for every pollutant in this table. Complete one table for cach outf all. See instructions for additional details.

2. C F* FLU CNT
3. UNITS
4. I N T A K C (. apt.e rs.rt) a (stoMfy y Menk) a:N W udtjM 37,,j,*g#

c.LO N(. T. 4 M g.. V A LU L v V Atu t

m. LnNG TC tem
1. POLLUTANT
a. M A xIuuu O Asty vatisc O "*"

gl. N O. O sr Avigt.A1, L x.ALiar A NO. O p- "#Ar'E"- ^ " ^ ' ' ' ' ' m '!! ..m ' " ^ " m-a < -,. 91... M --a < ~.~ t1...,_ m --- ^ " ^ ' ' ' ' ' D!....- m-- u nochem.c.at ,l'JF," ***"" (3 4260 1 mg/L kg ~ Cu.na.,. CJy," '"'*"" - 18 1,600 1 ppm kg

c. Total Orga ile C.roon (roc >

6 520 1 mg/L kg )

d. Totai Suspended soud.fTssi; 5.2 450 1

mg/L kg i

e. Ammonia <(as N)

ND . ~ * (0.1) 1 mg/L w +%,s

  1. ALUE VALUE VALUE VALUE f.' F, tow, c-~

23 31 25 112 MGD eALuc VALuE VALUE vaLuc Temperature - C (,,in ter> g /ALUE VALUE VALUE VALUE (numm ers

  • C 1A t N I M UM M A AIMUM MSNRMUM MAA4 MUM 5'^"

^" " " ' ' ' 8.0 8.6 8.2 8.5 112 PAllTU-Mark "Y* sn column 2-a for each potiutint you know or have reason to boheve is present. Mark **X"in column 2-b for each pollutant you tielieve to be absent if you mark column 2a for any pollutant which is hmated etther directly.or indirectly but expressly,in an effluent limitations guidelinn,you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mar k column 2a. you must provido quantitative data or on explanation of their presence in your discharge. Complete one iable for each outfall. See the instructions for additional detasis and requirements.

1. PO L LU T-2

'd A H M ' A '

3. CFFLU CNT
4. U NITS
5. INT A K C (oprum.st/

A T AND Y V ALUE c.LONG T .VALUE ,%,ahnhy "^^8 //..,*,

a. M A XIMUM DALLY V ALUE c1 N O. Of 4 LONcEN-A EFA VALjg LA N O. OF ANAL.

It M ASS ANAL. (ef ereilafetc) .e.s.e. , _ {a),,,, M .n ,,,,, p,3,,,,, M uan , la),,,,,,, teg uan ysgs MATION ,,,,,,[,,,,,,,,, tr$nau VSE5 ue

e. nrnmide (24950-67 9)
b. Chlorine. --

Totst rtssiduet s..

c. Color l,
d. Fscal
  • ColiformN I

(

e. F euorio.

(1698448-0)

f. Nitrats-.

NItrtts (vs N) EPA Form 3510-2C (Flev. 2-35) P AGE V-8 CONTINUE CN REVERSE z.

S 4 k 2 LF CREEK Wt@ NUCLEAR OPERATING i Robert C. Hagan Vece President Nuclear Assurance November 15, 1993 ^ NA 93-0216 Kansas Department of Health and Environment Industrial Programs Section Bureau of Water Forbes Field, Building 740 Topeka, Kansas 66620 Attention: Mr. Don Carlson, P.E., Chief

Reference:

Correspondence from K. Finn (KDHE) to B. S. Loveless (WCNOC) dated August 12,1993 (93-01204)

Subject:

Renewal of the Wolf Creek Generating Station National Pollutant Discharge Elimination System (NPDES) Permit

Dear Mr. Carlson:

Please fimd enclosed the completed forms and information necessary to renew NPDES Permit KS 0079057/I-NE07-P002 for Wolf Creek Nuclear Operating Corporation (WCNOC). Material safety data sheets and aquatic toxicity data for water treatment chemical products used by WCNOC are included in accordance with Kelly Finn's request. Site geological information has also been provided to assist the Office of Science and Support in evaluating the potential for i groundwater infiltration from the Lime Sludge Pond. Please note that outfall 002a is listed as an internal outfall on the permit renewal forms as discussed by Kelly Finn in the referenced letter. We also request that the sulfate monitoring requirement for outfall 003 be removed upon revision of our NPDES permit. Sulfuric acid is no longer used as a neutralizing agent within the circulating water system and outfall 003 sulfate resuhs are similar to the main lake levels measured at outfall 004 (please see the enclosed comparison of sulfate analysis results). Sulfate levels at outfall 003 do not differ signiEcantly from background levels in the cooling lake and P O. Box 411/ Burlington, KS 6%39 / Phone: (316) 364-8831 j An Equal opportur.ity Empicyer M/F/HCNET I

t Page 2 l NA 93-0216 continued monitoring will not measure any significant sulfate effluent from industrial sources. Please contact Brad Loveless at 316-364-4168 for more information, if necessary, and direct any written response to this application to Kevin J. Moles with WCNOC. Very y yours, / F, bert C. Hagan Vice President Nuclear Assurance RCH/tir Enclosures

p-Enclosure I to NA 93-0216 1 \\ KDHE Water PoUution Control Permit Application l

I i

i 1 i i l

~ Exps 2/14/94 Kansas Permit Application Number Southeast. :: ' =- STATE OF KANSAS l-DEPARTMENT OF HEALTH AND ENVIRONMENT DIVISION OF ENVIRONMENT WATER POLLUTION CONTROL PERMIT APPLICATION L FOR INJECTION OR DISCHARGE TO SURFACE i di ~~ Novomhor~d 1Q41 Date { TO THE SECRETARY OF THE DEPARTMENT OF HEALTH AND ENVIRONMENT, TOPEKA, KS: In conformance with the provision of Kansas Statutes Annotaceo.(1973 Supl.'H i 65-164 and 65-165 the undersigned, representing Yolf Creek. Nuclear Operating Corporation l Name of mwticipality,. institution, compnty, corpora. tion c.1 potson applying 1 located at (List facility designation and mailing address of applicant) , Wolf Creek Gen'erating Station .- p, of-ho x -4 t w :- -~ l v { .~. Burlinoton. Kansas 66839 I g i hereby makes application to tg Department'of Health and'Enviroritent for i a permit to discharge. sewage into. (enter me of,tivot, s4 team, inke, etc) -Ne6sho' River via Wolf Creek'via Wolf Creek Cooling'Imrioundment i The undersigned authorizes the Division of Environcent to use the informaa tion contained in my Federal application as information on which to base isstance of a State permit. I understand that my Federal application is available to the Division of Environ ent and that unless otherwise notified by the Division to provide additional information, no other documents are r: quired pursuant to receiving a State permit. IIE (KSA 65-164 defines "wngt." as any substance that contaists any of the uste Freducts or excrcrenClins or otheit discharges f.tcm the bcdies of hw.an beings or animals, 01 chemicaz c.t othe,1 mste,s facm dc=Lstic, manufachtting o.1 othe<1 fcams of industig). .i 1 l {

a. m 3 .p'T.=': w.:.t.'..::.c.:.w..v,..c. m..it fea :in the amount. of. pot. g applicabl s att ached ~to' this ' - p~ -A sewageLpid....- f i. applicatioti? ;;-i !- y, .M-(Signed ) 2 .. h, i. / ice-oresidnnt "in 1, r acenr,nco State of Kansas County of Coffev ss. ( Sworn to and subscribed before ine, a notary pliblic in and for said cotutty 0 day af Anmkw 1993. and state this B (SEAL]. ~ (f? ' Y. '<f.. Q y ).bnut & $.r)9k, e\\6.ofAAy.-

  • e

,4 .. ~. ! ~ .P U 0 \\ \\.'... ~ Mc..c o e .. % : W.3:.- & @ b $ 5 & h k.._ W.____. &...._ _. R __ j : ...j:p ? -..-._....i. F. :.- 1 ._..~..s : .... ^ =. - Z,.,

  • .,l',.'s.*~

~ ^ o. ..+u. " j' ' &7 . w'..h' *g* *;.. e *."*'*A'a '," :: r..- ,,.,}b,?,..... i.* ;.,$)b.iYfd. M.. II$5N:Y,b.<bS.a,.$N.w;8.b I....... .N ih ;:. ;~~ '**~.'y= c.. Q + (. ' .-* y,2 o-

  • 5*

..,.. $,. P.u.blic.U_... N No .. ' ~ 5.* N. ...w.:. ...w.n......

9. : L..

.r .w... o.., ~.! f" <. v.:a.,s s * .p ... ~l:W. ff.\\ -.-......- -...........-..'-

s.?
;....w -.

~ ;.y ~..........._-. _....." _..... q,. si ' :*..,: . >.-...e_.-.. h*q;:.. ;g a l . - ~.. gSewage pen.it fee calcdated as fctLows: t Classification Unit Unit. Rate... Years -Fee No fee is recuired vith this bvplication. You uilt continue' to be billed at your annual billing ' time in conjunction.uith your expiration -date. ~ 7 .i \\ ?This application will be. 'igned by the. fclicwing: (a) ist XJte case of a corporation,. s by t);e. Ptincipat eiecdive of ficer of at Least the level of Vice Fre*siderA; (b) ~in the case of a par'tnership, by a general putneA; ic) ht the ca.se of a'scle FMpuetorship, by the. proprieAcr; and (d) ht the. case of publicly-c:c1ed treatrers' Mrks, by the. of ficial having re. span.sibility for the cueraLL cperation of the LAcatzent mr.ks. + i ~ 'y. e., A

j l 1 f i to NA 93-0216 l 1 i EPA Form 1 4 u l

p ~ ~ U.O. CM6bd@bC2GG3VM DDMGeVD@C3 48GN ~. EPA l.D. WUMB E R l b ^C GENERAL INFORMATION I i n %"$ L, consolidated Permits Progrcm F K. 5.0_O_7.9_O 6.7_ O GENERAL tread the "GeneralInstmerions before startine ) .. (w N A B L L IT E M 5 G E N E R AL INS T R UCTIONS \\\\\\ \\' If a preprinted lobo! has beon provided, af fix I' it in the designated space. Review the inform-stion carefully; if any of it is incorrect, cross .\\ Ft CIL TYM AM E \\ fi \\ through it and enter the correct data in the \\ \\ \\ \\ \\ appropriate fill-.in area below. Also, if any of \\\\\\\\\\\\ \\ the preprinted data iJ absent [the area to the FACILITY K \\ tett of the labet sexo lists the information

v. Mait.lNo AD DRcss P EASE PLACE L BE IN THIS SPACE that should appearl, presse provide it in the

\\\\\\\\\\\\s proper fill-in areals/ below. If the label is \\ complete and correct, you need not complete N s items 1, til, V, and Vi lascepr V/.B idich must be completed regard less). Complete all s Y3' FACILITY items if no label has been provided. Refer to LOC ATION the instructions for detailed item descrip- \\\\\\\\ tions and for the legal authorizations under y \\ which this data is collect *d. i INSTRUCTIONS: Complete A through J to determine whether you need to submit any permit application forms to the EPA. If you answer "yes"to any questions, you must submit this form and the supplemental form listed in the parenthesis following the question, Mark "X"In the box in the third calumn if the supplemental form is attached, if you answer "no" to each question, you need not submit any of these forms. You may answer "no"if your activity is excluded from permit requirements;see Section C of the instructions. See also, Section D of the instructions for definitions of bold-faced terms. u n a w *x* M a p.g r 5PECiric QUESTIONS ,f gpgggggg ggggygggg

  • l vss

,e gp vss ee ge l A. Is this facuity a publicly owned treatment work.s B. Does or will this facility (either ex/ sting or proposed / ' hich results in a discharge to wrters of the U.S.? Include a concentrated animal feeding operation or w (FORM 2A) X aquetiC animal production facility which results in a y discharge to waters of the U.S ? (FORM 28) C. Is tnis a f acihty which currently results in discharges D. Is this a proposed facihty (other than those described to waters of the U.S. other than those described in X in A or B abovel which will result in a discharge to X A or B above? (FORM 2Cl waters of the U.S.? (FORM 20) u n u n E. Does or will this facility treat, store, or dispose of F. Do you or will you inject at this facility industrial or hasardous wastes? (FORM 3) municipal effluent below the lowermost stratum con. y taining, within one quarter mile of the well bore, y underground sources of drinking water? (FORM 4) G. Do you or wea you inject at this f acihty any produced water or other fluids which are brought to the surface H. Do you or will you inject at this facility fluids for spe-in connection with conventional oil or natural gas pro-e al processes such as mining of sulfur by the Frosch duction, inject fluids used for enhanced recovery of rocess, solution mining of minerals, in situ combus-oil or natural gas, or,nject fluids for storage of liqu d )( tion of fossil fuel' or recovery of geothermal energy? i hydrocarbons? (FORM 4) (FORM 4) X n n n n n n I. Is this f acihty a proposed stationary source which is J. Is this f acility a proposed stationary source which is one of the 28 industrial categorie6 listed in the in. NOT one of the 28 industrial categories listed in the structions and which will potentially emit 100 tons instructions and which will potentially emit 250 tons per year of any air pollutant regulated under the per year of any air pollutant regulated under the Clean Clean Air Act and may affect or be located in an X Air Act and may affect or be located in an ottainment attainment area? (FORM $1 ares? (FORM 5) X.. o A i 6 I I a e e a e i s 1 Wolf. .C.r.e.e.k. .G.e.n.e.r.a.t i.n. o Station amu IV. FACILITY CONTACT 1 ;. - ?. A. N A M E a TITt.E tic.nt. first. & title)

n. 9N ON E tarea code & no.)

_t .....,,,,, i. . i, i,,,,,., i.. ,,3 i, ,. i 2 L o v. e.1. e. s. s.. B. r. a. d. .S.u.p.e.r v.i.s. o. r.Ein'v,M q.t3.1.6 3.6.4 4.1.6.8 't 9 FACILITY MAILING ADDRESS Gf. A. ST R E E T O R P.O. B OX 1 I i i i i i I i, 1

i i, i i s I

i i 3 ,, i i i 3 P.O. . b. o. x.. 4.1_1.

3. CITY OR TOWN C.ST A TE O. ZIP COD E 1

3 3 3 .I I a i i 4 i, a i a a i 6 i 4 4 4 l l l 4 s 4 R... m r. l. i. n _ o. t. n. n. K,,.,5.6.6 B.3.9 n tft. FACILITY LOCATION l A. STR E E T. R OUT E NO. O R OTH E R SP E CIFIC IDE N TIFIE R ,_c,,,, I i i i a i 3 i a a i i i e i i i i i a i a i, i i 5 1,q.g.0. . O. x. p. n. . l. a. n. p. .!L F. B. COUNTY N AM E i I 3 3 I I I I I i 1 1 4 I i iI I A i i i F...n.f f m.v. C. CITY OR Town O.5 TATE E. ZIP COD E F. cOUN T Y C ODE s ,,,,, i,, i,,,, i,,i, i,,,,, i, 6 B. U. r.1. i. n. o. t. o. n. <.S 6.6.8.3.9 u EPA Form 35101 (Rev.1580) CONTINUE ON REVERSE 1

,,gggono A. r an s? L (specsfy) (spectfyl 7 F- ' e > <7 4.9.1.1 Production of Electricity j D. rou M TH } w C. Thin D is i ggpecyfy; L (specify) 7 e e i C.L. (7 J te q a 4 i ...I i i i i i i i i i e i i i i i i i i i i i i e i i i i i i i i owner?

8 W.o.l.f..C.r.e.e.k.

.N.u.c.l.e a.r. 0 n 9. r. a t i. n a .C.o. r. o. o. r. a. t. i. o. n O.. Y Es Op NO l s

n. rHoN x (area code & no.)
c. si ATus or orn R ATon (Enter the appropriate letter into the answer tox;tfOther" specify.)

I i

  • i e i i

~ F = FEDERAL M = PUBLIC (other shors federal or state) (spectfy ' P

3. 1 _6.. 3. 6. 4,,

4,,,1, 6, g A l s - STAT E O = OTHER (specify) 7 P = PRIV ATE i E. sT n r ET o n P.o. s o x lr iii i i iie i i i e i i e i e i i i i i iie i i i i ! P.. O. b. n. x. .4.1.1. 4 c, G. STATE H. 21P CO D E IX. INDIAN LAND I

r. civ v on TOWN f

is the f acihty located on Indian lands? 4 s i e i e i i i s i + a e i i i i e 4 i i ' ' ' KS 6.6,8.3,9 O YES 00NO I 1ie IB B. u. r.1.1. n, c. t. o. n, sa X, XISTING ENVIRONMENTAL PERMITS D. 950 (Air Emluion.s from Proposed Sources) A. Nrots (Dhcharges to Surface Water) ....... i.. i i i.. i e i i i i iii ju 1.n t a n n f. i. c. a h I.f ...S..0.0.7.9.0.5.7. 9 P 9 N K E. OTH En (specify) [

e. u ic (lJnderground injection of Fluids) e i s i o e s o

o n i i i s e n s e i i s s in i (,p my., air operating permit i 0.5.8.0O21 .n.o t a D D-] i c a b l.9 0 l9 U f,. E. OTH E R (specify) [

c. ncn A (Hasardous Wastes)

} (specxfy] ,, i,,, n, u e s a a e n s n i n i i u i s n (9 K 9 1.7 8 '1 2 ',. Dotable water sucoly Dermit i .. " S D 0 -0 0 6 8 6 9 5 6,. 1 R TL MA3 f c.. l Attach to this application a topographic map of the area extending to at least one mile beyond property bounderies.The map must show the outline of the facility, the location of each of its existing and proposed intake and discharge structures, each of its hazardous waste ' I treatment, storage, or disposal facil; ties, and each well where it injects fluids underground, include all springs, rivers and other surface water bodies in the map area. See instructions for precise requirements. ! XlL NATURE OF BUSENESS (provsde a brieidescription) Generation, transmission and distribution of electricity ] 1 i ~! l l l l l ~ l Xill, CE RTIFICATION /see instructions)...... l certify under penalty of law that I have personally examined and am familiar with the information submitted in this application and all l attachments and that, based on my inquiry of those persons immediately responsible for obtaining the information containedinthe j 40 plication, I believe that the information is true, accurate and complete. I am aware that there are significantpenalties for subm } false information, including the possibility of fine and imprisonment. [^

c. D AT E s ic, N t o a.siw 'Tunc
A. N A u r a o r rici A s., T iT L E (type or print)

\\ r /, i ///v/93 @-i g5VIA Robert C. Hagan vice-president [2g,* ; th,e f o n,- n e e .e n ne a o .m I

PA Form 35101 (Rev.10-80) Revene i

i 9

_= r e 7 I 4 to NA 93-0216 t EPA Form 2C i 0 1 I ) 1 .I 1 -j 1 1 l

form Ap eved I .,....+. .s.... y tP A e.O. Nu Mut e sopy from item ) of Iorm jj cs,g y, g;,43.oggg pg. 1 Of 7 I f

    1. "' '* 7 3 ' 8 8 j

Please print or type in the unshadad areas on?v. k5 007905~ .e+ l FORM u.s. EN VIR O N M E N T A L PR O T EC TIO N A G E N C Y..

qg

_ +., . APP lCATION FOR PERMIT T

  • 4 Ul Q EXISTING MANUFACY.URING,. COMMERCIAL,,O DISCHARGE WASTEWATERj.'., '.ee MINING 'AND SILV_ICULTUR AL OPER ATIONS

's' ' ' : D: Consolidated Permits Program' ' ' Ws > ..'r ^^ NPDES

t. OUTF ALL LOCATION,_ --

4 */;...':' ;;^. ;:: t ; *.. * '.:. J ' [..f. ' ~ : i'\\. - ',f?O 9.::. ' For each outf all. list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water.4 f..' ) ~ \\ /. OgT,F A,L L

s. L ATITU DE n C. LO N G B T U D E

..,s

c.,., -

g

navn

...u. ...u. ~ ~. 001 38 14 30 95 41 30 Wolf Creek Cooling Impodndment lI 002 38 14 00 95 41 15 Wolf Creek Cooling Impo6ndment f I 002 a 38 14 00 05 41 15 Wolf Creek Cooling Impocodment 003 38 14 30 95 41 30 Wolf Creek Cooling ImpoQadment 003 a 38 14 30 95 41 30 Wolf Creek Coolina Impoundment 003 h 38 14 30 95 41 30 Wolf Creek Coolino Imoodndment II. FLOWS, SOURCES OF POLLUTION. AND TREATMENT TECHNOLOGIES ]

; 1. ; ;.\\ -

1 . -.'? A. Attach a line drawing showing the water flow through the facility, Indicate sources of intake water, operationf contributing w1tstewater to the effluent,- and treatment units labeled to correspond to the more detailed descriptions in item 8. Construct a water ba!ance on the line drawing by' showing average. ' flows between intakes, operations, treatment. units, and outfalls..lf_a water balance cannot be determined (e.g., for certain mining activit/es), provide a - pictorial description of the nature and amount of any sources of water and any co!!ection or treatment measures:. Q yd W, W '. ~, - ' B. For each outfalt, provide a description of: (1) All operations contributing wastewater to the effluent, including process wastewater, sanitary wastewater, . cooling water, and storrn water runof f; (2) The average flow contributed by each operation; and (3) The treatment receind by the wastewater. Continue M' , 4/ 2r V ' ; M' .J,4 .,.c., on additional sheets if necessary. - 1.' j ' o g y.

a. OPE R ATIO N15) CO NTRIB UTIN G FLOW
  • 7

- 3. T R E A TM E N T +. -' -. g fc, ( s t) 8l OPE R ATION (lk!) ( n i de Un ts) 'W *\\' ~- DESCRIPTIO,.',', y - (; gg 001 nnmostic Waste Trnatmont 0.0119 MGD Sewage Treatment 3-A 4-A Sewa' e?siVdoel'olace'd Tin waste 5-T Plant a l stabil.ization pond l 002 sito oil / Water Discharge 0.417 MGD Gravity Oil Seoarator 1-H 4-A 002a -- Site Oil / Water Seoarator Oil Separation / Discharge 1-H 4-A -- 0!lv Waste System Includes: Filtered water overflow Discharae to lake 4-A stnrm run-nff Oil senaration/discharce to 1-H 4-A lake 003 Cirentating Water discharge 708 MGD Chlorination / discharge to 2-F 4-A (At nm ml water Invol and lake three-pump operation) inelndoc- - rireniating water screenhot se --0il Interceotor Oil separation /discharae 1-H 4-A - Servir9 Water Systen Chlorination /discharae 2-F 4-A NntA' Service water sucolies the reauired Essential Service Water System flow. I O r Pp.tru un E.O N u T canuanu s.,m,r. nc.uaor,< >...:my a.w.a, q - ~ :w w w.n .e+gc \\ r,; q n.- . 9,.'. s. .rh e . ' ;,,,+. he f .-M =u

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? E9/r s.o. NUM LE R tcopy tron item i of f arm O gy m y m yg ewwe*es Nf 83 po2of7 Please print or type in the unshaded areas on'v. KS 009057 FORM Je s. .. U.S. E N V nf 0 N M E N T A L P R O T E C TiO N A G E N C Y

k..,

g ... APPLICATION FOR PERMIT TO OlSCH ARGE WASTEWATER,,. ' g p'g :#%. EXISTING M ANUF ACTU RING l? Consolidated Permits ProgramCOMMERCI A L Ul ( NPOES x .. ~ MY' l.OUTFALL LOCATION EMMMW4MDbWMNLUE@EldEMffEMGP2dfddfMMMMW4IdMW65f428837F'6MMM@ For esch outfall, list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water, ~

  • ~-

A.QUTFALL B. L ATITU DE C. LO N cel T U D E.- (l ) ' t.eea.

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004 38 11 15 95 41 15 Nonshn River viaJnif cropk 005 38 14 45 95 41 15 Wolf Creek Coolino Imooundment 006 1A il 10 QR 40 4R Unif Prock Innlinn impn'mennt !!, FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIES]WHUdfMff@j$LMp1M}M$lgygw --- 'r A. Attach a,line drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing wastewater to the ef fluent, ^ c and treatment units labeled to correspond to the more detailed descriptions in item B. Construct a water ba'ance on the line drawing by showin'g average , flows between intakes, cperations, treatment units, and outfalls. If a water balance cannot be determined (e.g., for certs/n mining activities /, provide a' pictorial description of the nature and amount of any sources of.wate'r,'and any coMeetion or treatment measures.

8. For each outf all, provide a cescription ct: (1) All operations contribu.ing wastewater to the ef fluent, including process wastewater, sanitary wastewater,

, co'oling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment received by the wastewater. Continue on Edditional sheets if necessary. - g f. O'U T.

2. O PE R A TIO N [s] CO N T RIB U TIN G F LOW -
3. TREATMENT-T

( s t) $_l bl, s. O P E R A Tl O N (lis f} - (incl de sen ts)

8. D ESC R IP TIO N
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g. 003a Radiningical Waste System 104 gnm Strainina. filtpring dp_ 1-T 2-J Includos-ninorali7atinn. di schargo 1N an --Wasto Monitor Tank A 00tional--Evaooration/ 1-F 2-A --Waste Monitor Tank B Carbon Filtration / Reuse J-C --Steam Generator Blowdown --Secondarv Liould Waste Moni cor Tank A --Secondary Liould Waste Moni nor Tank B 003b Wastewater Treatment Facility discharge

  • back-up dischar ge Nout ra l i 7 atinn/di scha rgo 2 k' aA

_:Dily waste drainage system Oil senaration/ discharge 1-H 4A Oil interceptor Control Bldo. Olly waste suno Diesel Gen. Bldg. sumo Condenser oit sumos (E.W.N. M Lube Oil Room sumo Tendon Access Gallery sumo Turbine Bldo. sumos (E.W.N M NOTF-Flows from the oily w 3ste drainsce an i condensate 6clisher reaeneranion sy ;tems may be temporariiv re outed to outfal l 002 throuch the oi!/ water seoarator durino abnormal plant ocerat.ons. Auxiliary Boiler sump o v! '.c L*h@m.9."M. tatt;u<n t su mewu nu t< son <n + w ~ %~ a. ~ M,.t. & c. f.~ %. y./M.-w f -O !J nj +.e q' - s: A, - / a 6 - ~ n

m e.o. uw uwmu nu a num m,. m Amo+ewei nf-" Po. 3 of 7 Please orint or type in the unshaded areas onty. KS 0079057 FORM u.15. E N V I R O N M E N T A L P R O Y E C T IO N A G E N C Y q p~ t'h . APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER TLu (g EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURAL OPERATIONS

a ConsolidatedPermits Program -

s. NTDES

1. OUTFALL LOCATION ;. f.. ' l5 ',, '. ( S.. ;. ' :.-

M f - L "'. ~i :; '~ .9., :::.,. .l For each outf all. list the latitude' and longitude of its location to the nearest 15 seconds and tne name of the receiving water. A.ouT,r*

e. L ATsTvoE C. LoNoaTuoE gym ER

. vim 003b cont inued A. Attach a line drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing wastewater to the effluent, l and treatment units labeled to correspond to the more detailed descriptions in item B. Construct a water balance on the line drawing by showing everage < flows between intakes, operations, treatment units, and outfalls. If a water ba!ance cannot be determined (e.g., for certain mining activities /, provide a pictorial description of the nature and amount of any sources of water and any collection or treatment measures. B. For each outfall, provide a description of: (1) All operations contributing wastewater to the effluent, including process weitewater, sanstary wastewater,

cooling water, and storm water runof f; (2) The average flow contributed by each operation; and (3) The treatment received by the wastewater. Continue on additional sheets if necessary, s. o ur.
2. OPE R ATION($) CO N T R 4 s u TIN G FLOW -
3. T R E A T M E N T

($t)

a. o P E R A Tt o N (lis t).

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  • O KSC Rl*YION 003b (enntinnod)

Auxiliary Feed sump Condensate Poli 1 er Recenerat on System Neotralization/Dischargo 2;K 4A h Hiah TDS tank Low TDS tank Make-uo water treatment systen Demineralizer Recenerant Solucions Neutrali7atinn/nierhargo 2V dA Premix /Precipitator to Sand & Carbon Filters Fl occ. /Mi x i ng / Sod i ment at i nn / 1 4 1-n1n Di cc h a rgp / Doc hl ori n a t i nn / 4-A 1-L' 2F Spdimpntatinn/nitehargo d_A Miscellaneous Sources Sedimontation/Dischargo 1 -!! 4A 004 Main Dam Discharge 12 41 MGn nischarged in enmnlianco with ar niirahlo Vanene Uater nuali g i fritoria after miving vnno in Nonshn Rivpr d_A 005 Lime Sludae Pond 6.015 MGD Settlino/di sc harae 1-U 4-A (d 6 tir es/ year i O Fl4C 8.A L u s E o N L y g,ff:,,,,,,,e,im,,,,3.,,,,,o n,g, ,d % w,, r l x +. y q. c.9.,.. i, 5, EPA Ferm 3510 2C (Rev.2 85) PAGE 1 OF 4 CONTINvE ON REvEssE r..-._

y ,-,~~~ - - ---. m ,,,,,,,,,,,a l Er A s.o. N uML ER teopy frzm item 4 cf Form jj cygyaggn.ccgg Please prir.t or tyt>e in the unshaded areas only. KS 0079057 #*">'*"' 7 3' 38 pa ge 4 of 7 I FORM v; . Ua E N vi,.ON M E N T A L r OT E c TeO N A o E N c v a. 'n E-U. APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER r iIDEXISilNG MANUFACTURING l COMMERCIAL", MINING AND SILVICULTURAL OPERATl'ONS f.' ~ O.

  • r ::,..

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!f ConsolidatedPermits Program.
.m. ~.

4' NPDES m l.OUTFALL LOCATION M5 3"".iMM)'ESKKg For each outfalf, list the latitude a' d longitude of its location to the nes' rest 15 seconds and the name of the receiving water. n A.OUTFALL. B. L A T & T U D E '. C. LON GITUD E D. R E C'E IV IN G W AT E R [ndar) DUMBENJt llis t) - e. e.... - s.... ....e.

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11. FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIES }

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3. s 5G(5 A) (. D. /'@.i A. Attach.,a,line; drawing showing.the'v,ater flow through the f acility, Indicate sources of intake water,' operations contrib; ting wastewater to the' effluent, fand treatment un!ts labeled to correspond to the more detailed descriptions,in item B. Construct a water balance on the line drawing by ' showing everage i flows between,'lntakes,' operations, treatment units, and outfa11s.1,f,a water balance cannot be determined (e.g., for cerralit mining activitiesl, provide a i pictorial, description of,the nature and amount of any sources of water and any collection of treatment measures.:,i_ V B, For each outfall, provide a description cf: (1) All operations contributing wastewater to the effluent, including process wastewater, sanstary wastewater, cooling water, and storm water runoff;(2) The average flow contributed by each operation; and (3) The treatment received by the wastewater. Continue . on additional sheets if necessary?.t

48. -
1. O U T.
a. OPE R AT f O N tS) C O N TRIBUTIN G FLOW I-
3. T R E A T M E N T (YI)

~ - s.'O9E R ATi~ N (lis t) ' - - e '?(infl de n ts)

n. D E SC RIFTSO N '

y g c. ROM 006 . Essential Service Water Syste n 25 MGD Screeniaa, Chl Jination, (NOTE: receives water from th? Discharce 1-T 2-F service water system during 4-A routine olent ooeration.) 4 0 V fICI A L U S E O N LY (tlfiugn t guh!tbnts su b ca ttCO'84GE t ,.i.. rv *, b..e V*J.< Q

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i' Prae 5 of 7 CONTINUED FAOM THE FRONT l C. Esicept for sto,rm runotf, leaks, or spills, are any of the dischuges described in items ll A'or D intermittsnt or seasonal?TM-~9 Wi 6' W W A, '$~$WS l.'oN l*ta the $. llowing'thle')(*.gf&&& Q&K=}&{Q nojgo,'to seetton I_II)j,'~& (.(.s[.,'&.;;.y { & " ~ P o . 3. FR E QU ENCY.9 'i M ^ I' #9 f 4. FLOWi- ! t ' Q* o ;

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. causs: ,ilh den) - es.e 003a Radwaste System 3 12 0.02 0.11 0.02MG L 11MG 0.1 004 Main Dam Discharge 3 5 36.07 399.90 36.07 399.90 2-3 MG MG 4 7 005 Lime Sludge Pond 9-12 da./s/ year 7.21 10.80 7.21MG 10.80MG 3-4 ,)l. PRO D UCTIO 1 by EPA under Section 304 of the,, Clean Water Act apply to your facility??. 33 '.t u..p,,.a p,,G ~ A. Does an effluent guideline limitation promulgated,Dif e.,., $..kNh;KY.,( 'n b (to to Ye'e~tiSWlV).f-^f,A* r f N&&v Es' leomple te itsm 111.B) ' O Y.R* ~ B. Ars the limitations in t,he.applic.able etfluent. guideline,p yres.s.ed, in terms.g.g.t, ion (o/other.meau~re.o..f o.peratio.m ?.f .ryJ".=3,.. )\\'y $hff;5?.,,,,qu m of produ'c s.w : nJ ] $-$ t 4 S. N w.t.... exp su .e v. y .v..e wu m rs r~.. z. n a e-b. y mw:.n? KS, $f oM95el_t.5,le?k S.$$AE??hfa, W., $*.'Er hW*laL& s {$R., C '$5' h, surement of your levelof product.. ~,expressedirithe termla..d..,ts. ou answered "y... ltem !!!.B. list th.,., ~,ty wMeh re. - ~ ~ opresents an actualmea. --. ~.. . e s'. to.-- e quanti e - r- -a - ion .., n uni ..s Crify.os....s.. 0n'[< Me t';pM-77-Q Gy;y M. %,M' g,.4 y1 -? y> us.,ed,i.n.,'thirapplic.abli.efflu.e'nt.gu. id.e. line, a.n.d,in..dk.iate'th'e'affe.c.ted outfalls"M,Wt'*)Fpo. 4' .. J. i c 3, i... + u.....ww ~n~- -:ws

  • f MtWSMlW.W:.% cf 54m.'M E AVERAGE DAILY PAODUCTIONWI!3'M C ** EG WMG-MC l.yP'@[TFA1.LS @g,

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  • IV. !MPR OV EM ENTS]

O.W .d l '............., .6 , e e. A. Are you n.ow required by any Federat, State or local authority to meet any implernentation schedule for the construtlon,, upgrading or' operation of v' aste. c v WPterr treatment eq'uipment'or' practices or any other' environmental programs which may affect the. discharges described in this' application? This includes, bu(N Act. linshe'd to,' permit conditions, administrative or enforcement ordersfenfor' cement compliance schedule tetters, stipulations, court order's, and grant t og g$1?dit"#' '.*'V".i&~ " ',*

    • *&"Q v Es'("eb'mple"te th'e f'oll'o'wlyg toble)

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B. OPTIONAL: You may attach adddonal sheets describir g any additional water pol!ution control programs for or$er environments /profeers which ms/ affect Vov/ dI3CharpeJ) You now have underney or which you ptan. Ind;cate whet,her each program is now underway or p'anned. and indicate your actual or planned schedules for comtruction. @,n g.2.* IF DE sc RIPflC N O F ADDITION"A L con TR OL PROG R A M S 65 AT TA CH E D EPA Form 3510-2C (Rev. 2 85) PAGE 2 OF 4 CONTINUE ON PAGE 3

, ~.. ~... - rm y m..--.- .y fe,m y,,a lea : D. NUMggsw(eOSy from Jtem ) of f6PM 20 l-4p'scst**;ieur31 se Page 6 of 7 CMB NA 20404C86 Le 0n.1,0,057 - CONTlHt.JED FT.OM PACE 2 1 I A, B.& C:"h NOTEi Tables V.A', V.B,:ahd V.C ar's included 6n separa'te shest: numbered V.) through V.9.7 See In..structions befori^p'r*'ee... ding - Com,.......... f tables f or each outf all....... ~. he outfa!!. -+. ber in the sp....< -ace provided/ ert Af..,..: ". ....... - -.... Annotate t num . plete one set o cc f ' U.'js?$. ...,c,-Jg. J.S'- ...,~~<-... 4 p.n.~ ~,

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......,,...,....-~......,.,....a. n. t D.,Use the space below to list'any of the pollutants listed in Table 2c 3 of ' he Instructions, which you know or have resson to believe is discharged or rnay be ' - 7 dischar'g'ed from any outfall. For every pollutant you list, briefly describe the reasons you believe it to be present and report any analytical data in your I 3$ $ !.'".*h N O.'. lY 5 % hT'.9?[f E h M.h.)$ b/I N b*' b.7' N i Y h h:b,N $ $ b!O N b. i. N 'Y.- IE.Nch'$:h.h.IIY[h'S [E' i t.fl.W. PoWuT A N r i m .::% i%-

i. s o'u n c c 7.0.e.r.7

. /" / i.eettuvANri M. M* : ~1 '. : i. s o u n c e' -hN.m e not applicable 1 j i VI. P5fENTIAL, DISCHARGES NOT COVERED BY ANALYSIS M ~ ' , Is anypollutanttistedinltemV;E.gWh%'QWQ,'@'$$0E.- C a substance or a component of a substa nce which you currently ure or manufacture s s a n intermediate or final product or.*a- ' t5yp'oduit7 f-2i-4:& N i.56'#l M 'is ) 6. $ $hQ$kT* N f8. N. m. h, m f.z.2.. w(.r.., g

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0. u, - a w w!DfwMMth. W-i,M,m u'p3bk, W.wn n P0,:' 57i . %) fc W5 d. tWi ..n.n, .a6 ir mw. c.a., s i 1 j i o 4 EPA Form 3510 2C (Rev. 2 85) PAGE 3 Or 4 CONTINUE ON REVERSE 1

.m ~~wzm- - l ! couTtuuro rnou Tse rnour KS 0079057 Page 7 of 7 Vlf.. BIOLOGICAt. TOXICITY TESTaNO DATA- .3 ~ J'; D6 9o'O heve'eny knowiedge or ressori to beliew that any.blological test for neute or chronic toxicity hs been made on any of your discharges or on a ' ra wref'9- @,p). p,7 'redeMnjiwaid irrrelation to your'discharpe within th's f ast 3 sars?R,f;syggg?'gf f,q7pyNRn..w fj'yy PA*~ g.j g,f p d(e,i,*:*g '. ","'.',i' tit'.?/W75. V './*?( ?'.98:.%?I:f f.C.T yi. appr,

  • ~ '% l c* ~.Ur' *;L Q v xs (tdentify the tent (s) and desenb
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<? :l.< ?Y'a - ~ V- .) :., } Vill CONT 6 ACT ANAL.YSIS INFORMATION y ;-) M' j..f.:.. - c '...f. ' D i. L.. O.. I i'j,M d-if $ } [.' : 1 Dv ts (Ilst the name, oddress, and telephone number st; sad pollutants.'.f'@ i'.Mffg m m: gfjjj)p;i*

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Lw;y.w:n p a mAy :cM gg fjp?.. ~ QNo (so to Section IX): N'.ang}cf,th, q agysy,syp,pofj,ed,{&, item,V,pe,rgrmed,bf s' cohtract laboratory n oruuJt j

a1. h, s.

n.,?).p ys.m* . :. h o d.-T. r c cnolysed by, each such laborstory or(!rrn belowb. ; s.' ' * >b' .;f. ? v - Q 7?j ', C -;} _, FGLLUTA T ANALYZED 5

8. A D D R E s S ".

~ f,*,,\\E 'eg,[n",Ey. f A. N A M E g l Langston Laboratories, Inc. 2005 West 103rd Terrace 913-341-7800 BOD; COD; TON;TSS; Leawood, Kansas 66206 hmoniin(as:.N); : Color; Fluoride; flitrate/ Nitrite (as. 1). oillgrease;Phosphoro Js Chlorine;Surfactants I Iron; Molybdenum;Copp ar, Boron; Sulfate (as 504 )l Aluminum; Magnesium i I, -j E.A. Engineering, Science and 221 Oak Creek Drive 402-476-3766 Chlorine; Fecal Coll c! 4 Technology, Iric. Lincoln, Nebraska 63528 form i CoNinental' Analytic &lxSvcs. ~1804 Glendale Road 913-827-1273 VOCS by GC/MS;B0D;CO{ ; Salina, Kansasc 67401 TOC TSS Ammonia *CN-4 oxic m4tals Ph4nols 1 M <.n%::)'.i:.N: ... M.. l a .,..s 4._. .m..... ...g......... ,..... s 4.,. .m. fcertif under....-penskyollowthatthisclocumentendellettecements werepreparedun,.,. ;.. der my hection or,s up erw,sion in a cc ordance, with a, system de, sign edio t

  • ~

i as_sure that gi,tatifiedperdnnetpropcilygether shde'valua'te ths nformation submitted. Bosedorimying'vity of theper' son orpersons wfic'thanage th'e's'ystem or l those persons directly responsible for ga th ering the inform ation. tt.9 informa tion submittedis. to the best ofmy knowledge an'dbelief. Ituel accurate 'ahdtimplete. Ism sware that there are significantpenshies for submitting false informatien, including the possibility of fine andim)irisonment for knowing violati,ons. A* M A M E de O F Fic I A t. T g T L g (rp f e or print)

9. PH ON C N O. (grre code 4 no.)

l Robert C. Hagan, v$eypresiden}, NtJclgar Assurance 316-364-8831 I

c. sec N Ayu n c 7

o, o av c sic N eo / }6but n a/h ,/ I..... EPA Form 3510 2@gow6@$1_ //f' AGE 408d

f.: } l. q-Enclosure to NA 93-0216: Form 20 parts V-A, V-B and V-C for outfall 001. Maximum daily values for part V-A will be submitted when composite samples and grab samples are taken. l I \\

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E** A a.u. N u M u E se teupy (mm item i of I'ornt 2 y ny g PLEASE PRtNT Ort TYPE IN THE UNSHADED ArtEAS ONLY. You may report some or all of OMS N<a 20e0 oosc Area ment trees informatioca un segurate shirts tuw rtie s.wne forreurf snstea<t of completseig these twps. app,,,,,f,,y,,,1 j y f 33 plan $ KS00{0 St I trWilitM'TioNs V. IN T AKC AND LI'l 1.UCNY ClIAR AC TEItIST ICS (conseinunt from iu.je 3 of /~orm 2-Cf l'AltT A - You must provide the results of at least one analysis for every pollutant in this tabte. Complete one table for each outf all. See instructions for additiona! details.

2. C F F*t.U CN T
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Sewage Treatment Plant DicCharge ' " ' " ~ ~ ~ ~ ~ ' ~ ' ~ ' ' " ~ ~ ' ~ ~ .c- , Enclosure to NA 93-0216 EPA LD. NUM oEN (copy from f rem J of Form 1) OUTFALL NUM BEH l [} form Appveved. s' OMBNn 20404)CS6 Aprovet enpaes 7 3188 CONTINUED FROM PAGE 3 OF FOflM 7-C PART C - If you are a primary industry and this outfad contains process wastewater refer totable 2c-2 in the instructions to determine which of the CC/MO fractions you must test for. Mark X"in column 2-a for all such GC/MS tract +ons that apply to your moustry and for ALL toxic metals, cyanedes, and total phenots. if you aro not required to mark column 2.a (secondary industrn 5. nonprocess wasrewater out/a//s. crdoonicquired GC/MS fractions), mark "X"in column 2.b for each pollutant you know or have reason to beheve is present. Mark -~X"in column 2 c for each pollutant you tmtreve es absent. If you maeb *..'n.-*O for any po!!utant, you must ptovide the results of at ! cast one ana!ysis for that po!!utant. lf you mar k column 2b for any pottutant. you must prov.de the rasuits of at least one analysss for that pollu? ant if you know or have reason to believe it well be discharged m concentrations of 10 peu or greater. If you mark co:umn 2b for acrotein. acryton.trile 2.4 denitrophenol. or 2-methyl-4. G dinitrophenol, you must provido the results of at least one analysis for each of these polluttmts wtuch you know or have reason to beheve that you discharge m co ncenteations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b. you must either submit at least one analysis or brief f y describe the reasons the pollutant is expected to be o.schargud. Note that there are 7 pages to this part; please review each carefully. Completo one table ful/ 7 pages) for each outf all. See instructions for additsonal deta ls and requaements.

1. l'O L LU T A N Y l
2. M A u H *x*
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l f r + E' b ( Enclosure to NA 93-0216: Form 20 parts V-A and V-B for outfall 002. Maximum daily values for parts V-A and V-C will submitted when grab and composite samples I are taken. 1 1 j 1 l I I I l l l l I' I t p > +. ~- i L

r. .,.~.._,.c.y Site 011/ Water p t~s* A s.o. nuM uEse trogny from item 2 uf Forrea 2) $cparator ~* PLEASE P!1 TNT OR TYPE IN THE tJN581ADED AREAS,0NLY. You may report some or all of thes mlorrtuteoes oes separate sheets luse the nne formarf sentraal of comi ermg these pages. OMAN 04oooac d

  • 3 l' IN';Titt FCitr tNS KS 0079057 4-~e.w.>

.u u ! V. IN f AKE AND CI'l 4.UI'NT Ca tAttACTElli'.; TICS (contsruct/ hom puyr. J of Tom > 2 Cl 0 55 f, l' AIM A. You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details.

2. CFf'LU C N T
3. U NITS
4. I N T A K C foreti..n.ef t
t. POLLUTANT
e. Ma xeMuu pa sty v ALug I'* "^ ^ 'Tf",,3,,788;v V A Lu u c.LO N G T M

P.VALut (specif, if Mank) um usaM

d. no. or
  • t. i c s iG V 1

,,,,d'[,,,,,,,,, -183"*** 9 c, ',, h/,fd.., Isl " As*W 4 eg,,U U),*,,,,1 % ( * ) ** a.. ^"^ W E8 A.V1.itAu NL.u r h *e o. o r inav n' i* "^88? ;*, *,y, I,Y,%,,, tel u.. ^ " ^ 'N 8 s.s ts 6ocnemic.iqo-4

a 0 mygen:Demen (BOU)3VMsec4c

.g '4 d tr eChemical gy ~ j oave.co.m. nog L 19 12 57 mg/L <co m t:s >>, n. slTet'al,'Organte.'f.i., 1 4 C cb.o.n.m(TO.C.Jy;.. e 1 e T t.ise eno.d v> ~. 3 to o n sono. (rss)e,.>-> 37 57 mslL a .w. t '. }; c/ Ammonia'je?N A m e w) j erug VALuE vAtuE VALut ,;;l7pgg,+g$ v a Lu t. 1.022 . 0.417 57 ED vaLuE g.D emperature$. V A tu e; vaLuE ! l"MiiP.kd 'C vatut v a Lu t. vaLuE VALuE vALut (suwner)fg '*:_b

e M0NIMuM M A AGMuM M8HIMuM

'M An tMuM ~ 'I

l. pH 7.6 8.1 57 sTAN o A rco units l'Alli U.

Mask ~~X"in column 2.a for eacts pollutant you know or have reason to beheve is present. Mark X** in column 2-b fur each pollutant you bulieve to b which is limited either directly,or indirectly but expressly,in an effluent limitations guideline, you must provide the results of at least one analysis for tha column 2a.you must provide quantitative data or an explanation of theirpresence in your discha'ge. Complete one table for each outfalt. See the instru .i t.POLLUT.

2. M ^ 'm " M *
3. CITt.U CNT 4.UNtTS
5. I N T A K C (uterhan.iff C AS NO

'* Es i.'*h'.=j

e. M AxeMuM D AILY V ALuE

"^ 9 eNoaNaNOJ vVALut'. C. LO N G T (M p .vALUE 4 r 1 e, ,, nr n.we2:

2;

.. ^..,,,,,,19, a,,,.,..,i.:....,. s ,,;,,, e), a,;,, ci.i; ...e,yt g,,y,19,,,,,,, i.... ^",^Y .a y no = 1,$@; 3.,,,y,q,,,,,3,, i.,... ^",^t v, $1roMideW)* (24959 67 9) 4 X

n. ht..A**

tGChlortnefj y.e..to..;.n sou.al; x 0.05 service water rad monitor, discharge 1 mg/L i .s. ..., m. ~*.. c.: coo mc@rds x o n.c., m Coi n g muumf x 3 11 100 m1, e:roursmq titse42484N.s n .w. ?.* Nitrate-.;Mj Nhrits,(os NJM X

EPA Form 3510 2C (Rev. 2 85)

^J PAGE V-I Jr 'he 2,, , y. +- CONTINUE ON REVERSC e'- 4 ~ 6 .e. w. e

Ks 0079057 Outfall 002 ITFM V n CONTINUFO FROM FRONT

2. M ann x-
3. CFFLUENT
4. UNITS
5. IN T A K C (e.priosta!)
1. POLLU T-

,f; m. M AXIMUM D AtLY V ALUE ,y p, v ALU t, tM g y.VALUE (f. N O. O F y c.LONGT h O. M ^ ^

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e. m ve,.n, Tst's Orcan }*f, (ae N);.5 c+,~

x won.natpR v or=,-=vg, x 1.8 1.1 0,9 57 mg/L 1

1. Phosphorus,,

f.is PJ, Total ' y f 172 314-0)

  • tf0 G d M ' Y#2YNI'I' D *f N d.' */ ' ' ' * '

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[- 111'Alphs T ' 5.Mm7M;(T""-x\\ ~ (2}ssta,y,r s Rerulated by fGC(used an neennd ary ' fl ow pnth. 1-rme n< mar rl i I (3),R'adiumd% e-t x Tm..,4QMer ; u (4)inedium7' / } 2 h'. gTotalf8.d x/ - nm.w q j k, Sulfeteh3 &, (as 80 )4, x (14800 79 4)# t*Suffide V'fg Na x -l u.3).g)J. i i m, Sulfite J< 41M6545-3) U . ? i tasoh>ny x f t re e m k:weemn surfacteaty x (0.01 Dob.estic wash water a, 1 mg/L j ew Aluminume ,TXtaf Af4p,r;Q y ^y ' ' l -(7C29i945)LX I

p. Datium
T3 t el *g~t;j,%M-

) x 5- {' , 7440 39-3)ph ( j l u, Boro .S Totatg dn.. ,9g xx j (7440-424)< g ?

r. Cu belt, y

[Ib h} $$3@,$'51 x 0.10 Auxil..ary Boiler b] ou down(Hi AC system: 1 mg/L ~.w,, n E '+ .i. u.en h,m., .Tc a,n. x -(7<m.edm:> 4r e y

u. u., wt.o.num.

.Totsiwyw)?A.A x 4,,,0,01 Corrosior.inhibitodinclosec cooling tater system 1 mg/L (7:39-98 7 ...,u.ne.a. TitasMtqr, x ,7C39 96-R)(j[ .'N ( ,<e., 4,(7 *,40 315)[f *8 w:' Tin) Tota Q. 4' d 4 x ... =. s 4M4 A% c w.T itenlum. 'd Tot ti+Mm (7 540-32-6)W 'x . EPA Form 3510-2C (Rev. 2-85) eacc v-2 CONTINUE ON PAGC V-3 IJ $3MC1'd,[Ma _u n ~ - sw.. -.... --- L

7,7 w.,, g..,a a,_;,,,. L: 1 I 1 l Enclosure to NA 93-0216: Form 20 parts V-A, V-B and V-C for outfall 003 Maximum daily values for part V-A will be submitted when composite and grab samples have been taken. i ?

__. - ~ _. =. - A h. I~r ?- I I Ip I i L Enclosure to NA 93-0216: Form 20 parts V-A, V-B and V-C for outfall 003a. Maximum daily values for part V-A will be submitted when composite and grab samples have been taken. m J

Circulating Water Dischar( r-m--.m LYA e.D. NUM utu tcupy frorna iterre 1 of Form 2) PLEASE PRINT OR TYPE IN THE UNSHADED,VIEAS ONLY.You may report some or att of OUR No 20,r0 003C ilus mtuem.stion un separ.are sheets (use che sene formatJ insiemt of completing these pages. Ay,,, m,,.,,,,,,., 7 ;, 3,y se r iNmiticTmN : KS 0079057 L x g gq W((.m. F " V'*9{%lM %[Q'2 R T vf Q. RI' 003 M:/.+ s +, n - '. ~s gN [s f f y. V. IN T AKE AND E FF LUt N T CalAf t ACTEtttST tCS kontinunt from v.,y J of rome 2CJ l'AllT A - You must provide tlw results of at least one analysis for every pollutant in this tabte. Complete one t.ible for each outfall. See instructions for additional dctails.

2. CF*f LU CNT
3. U N I TS
4. IN T A K C (ortroseah Of"I/V If I'I"OI c'Lonc TgsM g hf.VALUC a. PO t.t.U T A N T
e. M A x eM UM Om s t.Y V A LUE fffh,fbN[I

^^3 vv^'Uh ,, t o w n y g,,, s1. N O. O F M LA!.i UULLur ik NO.OF e s._M+' N d '. E * ~, d e, ',,,,,,,

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  • e*

t. ~h m. & H i VALUE VALUE VALUE V A t.u r. es .3 I fWo h,,\\. M w.. v .. 708 379 MGD .j EATornpweture;. g ,C v a n.u k vAtum vAtue v A n.u e (winter)A,t.wvy *, n .. me v a s.u m vAtue w a s.u e vatut g 4 7g (asemmeripatm u tdduM - MAxtMUM MINtMUM M AXBMUM "~

t. im 8.2 8.6 113 ST A N D A R D U NITS N_

l'AllT U - Mark "X"in column 2.a for each pollutant you know or have reason to behov6 is present. Mark "X"in column 2.b f or each pollutant you believe to be absent. !! you mat k column 2a f or any pollutant which is limited either direct!y, or indirectly but expressty,in an effluent limitstions guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mar k column 2a.you must provide quantitative data or an explanation of their presence in your discharge. Complete one table for each out!all. See the instructions for additional details and requirements. t.POLLUT.

2. M A se n ' x'
3. EFFt.U ENT
4. UNITS
5. INT A K C (otersoetal)

I'* " ^ ^ 8 yf fa hj Mg YVALUt;

c. Lor 4 G T

. V A LU r. d d U'*C (E'("m. C SNO N* E5

e. M A XIM UM A rt.Y V ALU E 4NO.Of Q%w gg g

. (if ee'eff able), I."U .s'.*='t ( *)m,,,, .y., t e )..s a se ,,,,d*)g,g;, 9e gs) a.j.g g g,,; j'),,,,,,,, g,) a., ^"^I AN ~seATlON. ySg g, g,,,, v5C co cs aa.ow M M,(N x Brominattd/chlorinat.ed blocideJused;in ::irculatin; water system ( Betz 88P) m m.# ' 'F3,ts . o.1 379 ms/L nu x o.2 0.1 A ...,..~ ~ s d,rrec,tM.4. X Californigy u #de.t c)F fu~or'IdeQ ? X (12984248.-8,)i' ..m..

f. Nhreto-yn."

Nitrite (os NJll XX a.t .w PAGIs V"I o EPA Form 3510-2C (Rev. 2 85) , m W;.. ** g CONTINUE ON REVERSE 'e,( .n.. b s

W 57 Outrall 003 . TrM v.n conTinuro rnou rnour

2. M A rt u
  • r
3. C rFLU CNT
4. U NITS
5. IN T A K C foptra wl)
1. Po t t.U T.
d. E.Or AMD (y'tYq b NO, M
c. LO N G T

.VALUE . NT AND e D' "^^'%%,jM.%v, v A Lu c, t ..- 1 /. *,,*

a. M A K tM UM r1 AILY-V A LU E ggg C AS N O.

anas. . i, u ass a,n a t. ,,,,,, PA s,,,, ,.,i.,..... ,,,,,, L 4, y,a m i,3... m,,,,,, tv,,,,_ t.,... Ys<s ,,_,, t J.,,,,,, i,,... r"^rio~ ga. nous;l su mm n.m* Tit:0 organle - raem w & x n:ots ensygg Groeseg yg.,- x

t. Phosphorue 4 x

0.01 Polyphosphate anti-ocale agenus 1 mg/L {783]!'o',' '

1. R edloactivttye*p h ;.. c e. g...v sic.

vg(j Apa.4;,5 WJa*a r,f'c. (,tg 7f-@'yhA c:.. yap y s.A - ,,,s .pp .. g; ?lL'K1GXhh" (1): Alptia.W (2lt eta.S IdNNO regulate-! bY'NRC ,TglMg'lQ?. cs., (3)iRadfu're x -m' ' (!):Redium% s 22ilsTotat..,3, -, A., 6-S x

k. a ulf a tsy.p 75/7h?,D x

104 90' 78 40 mg/L 78mg/L 40 %W.v,3i! x es e teid

m. Sulfits La* A0 0 *b 3

y (14265 45-3)J Q nMNi gg*,c't*g'4 f. 0.01 latindry nystem discharges' i mg/L x w Aksminum, Tot 0t y'WAY,41 y (7C29 90'5)$',

p. a., iu,n.

7.' O ') 3 o.aoron. '[jgpph... x 0.22 from radwaste systen discharges. 1 mg/L .r. C a b.It. WY:- x _'l (7,440-48, 's.*.t ro%T,otat h g-x 0.18 from ste:m generator. blowdown 1 mg/L 394.ed3yd .w ,s um ium., ^, Ql$%P4&ft

u. uuyno. nom.

.Tzinit e gl x / 0.01 molybdates used as corrosion inhi'oitor: 1 mg/L (7 *39-98 7),. N

y. u.no.n.

.h

[l$i9ie$)}

? x w.* Tin,*Totat m 17 4 'A315 ?f<,c4 x 4 t Pr.as co m..T itanium $1 t~_ lgC gk.t e t (7;'# 0-32-611 1.- X EPA Form 3510-2C (Rev. 2-85) s* A G arv-2 CoNTINUC ON PAGE V-3 ,M,- 44'@ w-. .,n ,, M,

Circulating Water System Discharge ,_.m _ _ m+ .+.,~,-----.3 Enclosure to NA 93-0216

m. A,.o. n u,,,,,,,,,o,,, f,,,m u,

, of yo,m,, our, A u n u. e. y g g__ y form Approved.' ^

  • " ^'* ***
  • KS 0079057 003 9'

. epprewe peremi-ss CONTINUED FROM PAGE 3 OF FORM 7-C - PART C - If you are a primaryindusery and this outf all contains process wastewater, refer to Tabte 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark **X"in column 2-a for att such GC/MS fractions that apply to your industry and for ALL toxic metals cyanides. and total phenols. If you are not required to mark column 2-a (secondary.Nustries, nonprocess wastewater ouffa!/s. andnonrequired GC/MS tractionsf. mark "X"in column 2-b for each pollutant you know or have reason to belseve is present. Mark **X"in column 2-c or each pollutant you betseve ss absent. If you mark column 2a for any pol'utant, you must provide the results of at least one analysis for that pollutant. If you mar k column 2b for any poilutant, you must provide the results of at least one analysis for that pollutant if you know or have reason to believe et will be discharged in concentrations of 10 pub or greater. If you mark column 2b for actotem, acrvtorutnie. 2.4 denstrophenot, or 2-methyl-4. G dmitrophenot, you must pmvide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge m concentratsorts of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b. you must either subrmt at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (aft 7pages) for each outtatt. See instructions for additionat details and requirements,

l. PO Lt.U T ANT
a. M A e4M *x*
3. CFFLU CNT
4. UNITS
5. INT A K C (oprismaff NUMDC

'l"*,1', M LJ =g

a. M Ax sMum D AILY v ALUE
    • "^^'y,((d,7Mj
    • 'O'"'" Wi" M Q.vALuE YV^'UE o

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vscs METALS. CYANIDE. AND TOTAL PHENOLS - 1 M. Antimony. - Totst (7 440-36-0) - y 2M/ Arsenic! Total (744,0-38 2)gn a y 3M.a.Beryttlum'JM Tot,s.if 7440-.41 7.) M. v-S- .w.,,. 1 A 4M.lcadmiumf,%f .T.etd (7.s.0.43-9. h. s - 44 v A SM' Chromium?$ .T.~otti (7440..4 7.-3). X .s 8M.' Capper.' Total % PWIIE M.? X ouMad,Totalfppf[* E.#h. INIM X E SM ? M srcur'y',.Totet q439;s7 sira.% X 7 ?' 9M/NI'cket;Totair (7440,-o2 oM;jn )( y v

10M2Silemum,'%

j ,T_a.t.d (77,82_-49-2. )y X f. 11M/Sf$er' Totat; / ^ s(7440.22 4))i>9V.n X .n. ~ (125tkTheblurn.%.r 7stil;(7 44')-28-01} X 13M.*Z8Ec3Toteld k J., ' (7440. nC6-616;-s. t.,,' X

o.. s.

G- '14M2C5e~nide.'M Tatil,(57;12 5) pj X g i l I15MIPkebis */d ] .Tatd hwr#Ji X j ) DIOXIN:. ~i::ww!W;i~ren.s'Mt,".virt4cu'A1.wsw t n.< ' -*'W'~<- .. v;~ n % 'J :::~ : - s, : ' m.n-s,~..sv. ~ - s -sa .c w 3 2.3.7.5 Tetro... uncscutueL HEsuLTS k chlorodit> ento-Ps D6omb (17G4-01-6) X EPA Form 3S10-2C (flev.2 85) PAGE V.3 CONTINUE ON HEVEllSE '7$ s

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3. POLLUTANT
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, NPdPEr'e h M ".2S-"hMw X 404.1,2.4.Tr6-4 chlort. benzene A ~I X (120-C2-1) '+# 8 GC/MS FRACTION - PESTICIDES *-WhW.MY.%r.t ~-N. t* s-A t w r - .e.'* +*' +;iw ^.v9 w V -." W -t J.* e". +* e' ~ w wa9 w %*'~- + - * 'v.' ** *+ 1P.'AidrIn'Ag!!b ISO 2.bf5 e 2PMILHC'KJ 'M (313444 9 X ..~.s 3Pi$.D HC($f" W'Nr 3 (319-85-7)h'm S Y 6r n ~ ~.. (P3"T.EH M."D (5849.-9..). ,m'*j X d SP.%DHCff.Q}. (31 N e)p w ; X EPl Ch'arda'ne'eV. 4 tYsY 't. s. 7P'4.'4'5COTf.M . q29;3ggg4j X f P! A.4* ODE L ^ ~' (72 55-9 . < e. u. X 9P"4!4<dD'D M *'e (72-54. 8)M ~ as. 10PdD121drini'9M IY.5y,)$,gh y 11Pf G-Ciuf Asulf en- ? I.k! d.,Il.dYb X b 12P.#$2EMo's'utf an. 1 (11s-29 7)ggf y 1 13PEndosultan.,; Sulfats-a,%.5 *$.4.; X (1031-07,II)Si#1 14P'/Endrtigt C l (! : ?.*LMES X e 15P.' E ndrin g AldehydW4,p y*O ra is (7421-93-4)D I'd X / 16Pl Heptsc'hlorM QS-44,4) gqQ,"[d y EPA Form 3510-2C (Rev. 2-85) PAGC V-8 CONTINUE ON PAGE V-9 r.. w - a

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e. A..O. MUM uE n tm., frmo sr,m s'of For,,

into Circulating iniater Sys form Apswowed r ' PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONI.Y. You may report some or att of ou,,,,,,,om,ctem Discharge teus mt<wnution un segurate dwets (use stee same formar1 instra.1 of completiemj timse pages. KS 0079057 ' " ' ' " ~ " ' " Mt t* INS 111tiCt TONS V. IN T AKE AND C f f LUENT ClIAfl ACTEItISTICS (corrrhwed frorn page J of Tonn 2 C/ PART A. You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outf all. See instructions for additional details.

2. EFf'LU ENT
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  • AN AUSES

^"^ J-m.uiochemicat i g 3 Okv9en'Oomend .g., 1 (BOUJ M%gthy.*& 3 tA;Chemicetpq , d. !8 Ouv9en'DemandM Y. (COD).rA9%se y - Y c(Tetal'OrsonicC8 ,3 l i C.er. bon}n..)e ).& C .~w d:r w S w g.d 16.6 . p'. 5.7 82 m-/L S.oikte (TSS> u.. os,* car-4Att o j.- ] s.ampwar* nmerw 3 ra Ammonia,fas N) y WMeafg*4vhW 'E s.p.-qp

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(""'mc'smiit:W C g MjNtMUM MAxtMUM MtNtMUM M AXIMUM I 8'H ST AN D A rt D U NITS PAllT U - Mark "X-' in column 2.a for each pollutant you know or have reason to believe is present. Mark "*X** in column 2-b for each pollutant you believe to be obsent. If you mas k column 2a for any pollutant 4 which is limited either directly, or indirectly but expressly. in an effluent limitations guideline, you must provide the results of a t least one analysis for that pollutant. I'or other pottutants f or which you mark l column 2a,you must provide quantitative data or an explanation of their presence in your discharDe, Complete one table f os each outf all. See the instructions for additional details and requirements. l.POLLUT.

2. M Anos x'
3. EFFLU ENT
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EPA Form 3510 2C (Rev. 2-85)
o *, PAGE V-1 CONTINUE ON REVERSE i, '.

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g Ks 0079057 outran 003a tTI'M V-n CONTINUED FROM FRONT

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    • +

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e. Alumisium,

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9. ser iom, Tett b

y a &t- -(7,44, sa. Boron,

rin X

used to control ac.ivity in.".he.. reactor. core (7440 42'8)

  • 1-r.,Cabelt, y

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P".~nuu"acn~teory from 1:<m 1 or #orm n ourratt nunuen~ ~ ~ P ~ ~'~~'" ~~q; R dw ste System discharge Enclosure t0 NA 93-0216 9 ci a t.o Y Form Approved. V ^i GMB No. 20MCO3G CONTINUED FROM PAGE 3 OF FORM 7-C PAR T C - If you are a primary industry and this outf all contains process wastewater, ref er to Table 2c-2 in the instructions to determine which of the GC/MS f ractions you must test f or. Mar k "Xin column 2-a for all such CC/MS fractions the t apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you aro not required to mark column 2-a (secondary industries, nonprocess wasrewater our/a//s. andnonrequired GC/MS fractions), mark "X'* in column 2-b for each pollutant you knou or have reason to beheve is present. Mark "X'* in column 2-c f or each polfutant you beheve es absent. If you mark column 2h for anypotiutant. you must provede the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant you must provide the results of at least one analysis for that pollutant if you know or have reason to believo et wdl be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrotem, acry!onstrile. 2.4 dinitrophenot. or 2-mothyl-4. G dimtropnenot, you must provido the results of at least ono analysis for each of theso pollutants which you know or have reason to beheve that you discharge m concentrations of 100 ppb or greater. Otherwise, f or pollutants f or which you mark column 2b. you must uither subemt at least onn analysis or briefly descrebe the rcasons the pollutant is empected to bo discharged. Note that there are 7 paDes to this part; please review each carefully. Completo cno table (alt 7 pages) for cach outfatt. See instructions for additional details and requiecmonts.

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t ag L t d en LE,, uod )., ri 3 d or a A a e V ). yo tt f e r r Ag E k fI. F. fo a p, o u u t rl o a, f ns e L L n an m t s ., + eu n A A ^ et o o e v v sui j .w t c it ao u z l t a r' bl c .s wi) c y m 2 u s epr ec t btas r s s t - m A r oh i S Q s L t n s so r ) wn e Se It yNi t t T J'. s ,M at o n k er e I p i u ie t v oh N f f e TM s ie U i o S If o lese O N p-b ly S. 2 . Ni C n uaf ue t lla .y 4 B - r n U, 'N A onf T ah m o a N" T r a kr t J. ft r yaf A 3r o s t et t ca u L N n n u a t "A L/g /g D a o o s C A tut h Bc o ( r h e r llo e e sc f m M c 1 a a s e a 'r S y m s e pl e r t r s e r hao v o cf f g, l t f r E' aoe r l o e e 7 le O* e tsb L 5 b 7 8 1 0 o l r a E ut t u 0 a O' 3 0 8 3 f se n U u b e n L N^ 1 1 1 - r 9 t o u 7 e N 0 n tS." 2e o A c . 0 o t V ^ nh e mt e 3, n o. e c el y udp {, g o t a S e u lovm i g i A K lp coo L s r t A r in p C. o i r 'E m V = a M r

  • tse g

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c. s r re k T 1 s uh p, V p le r ao c G M_ '., M. e,d j, { b s yi N r a o E S 4 O f G t r E / t n D. is niu L. J h s: 6 el o c a A Pw T T. ey 3 sd s No in G I,7, 1 1 1 r ui c p d P, t ein f E E e pGe n o N J 4 0 u. u ssc T u y i:. s O G u s l t 3 L0 L inn N y L y n ud la. f a L. J s A A ^ e oe A vis E e. ., ~ - i s r s C oe e t c 'J v v et e U 3 V s i s og 2 lo T t W ea lu a h r eip L y t vu mp m bmr r h gg j ~, ' .g l ert s s 'o N u V L i ie F m e r p oe ol L Y e l y C t t ,~ M h po rh r A n nt E 7 t e U v u o ef 1 t f n ot o M s luo 3 g e pg v L l a af n x en 7 e Y t p o F W, t MS efeo N hs r p f i ri r A e nt [ ti yti u r i g m r C ). + ap f a p f, M va n ^ ml m m p s 3,,, h i.l ^ e an a ol uo m is 2 t ff Yf f ly 7, i. r y p i ra oc o ot x r J. se A a / r f .o f n ws n u ] J M o t Yt -a a e Y, du L s. u e ^ e e r a t E u npr E i d e n n ^ u u M eo Nt d t L I u e U n k x o s c On n o J A A ^ N ot ta A /x a L M us i o t u Sf s y di Ar (c k 'c v v MI

t. b d V

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a. d r A

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e. g rp Yw f

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t. ^ N e iew s

i4 s e ea r t e Dr EoS r T T L ,t hr% r l r t to4m a o ma, r n e r h r e Sa r9 o e 'e. F. sin e c e) m mm C g, .,. m m. T O w o5 co d8 AsnI N e E s 'l I R O t f A,' ogU t o

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Ks 0079057 outfall 003b ITEM V-ft CoNTINUf D FRoM FRONT

1. PO t.,t.U T.
2. M A88M *A-
3. CFFLUCNT -
4. U NITS
5. INTA K C (,*piiewl/

C SNO

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=;, =.,,,,,, t,i,.,,,; ;,,,,,,,,,,

3,,,,, tqc, a.o, g,,,..,,.;.3,;;tv,,,a,, ^ ",^g g,%g.ag.,3,,,, t9,,,,,,, .,~,g-a vu Av.o-S Nitrogame, p,p TEtid Orsaale.( <= nrm.. e x h.* Ott anufg; g.] p cre gy x Oily was ;e drainage system and' oil interceptor

1. Phoephorus.,

tae Pl. Totet X 47723 14-0) ' uneesomets.rtsc v.s **::w. sao-+ mns9w' uw.*DwS* F4?sWMM@ WMuv37.' n d% * ' ^ > ' + n*^aWM %W!M WWW (ITAlph w.,t x Te + (2)SeteN O I N E} g t 8G regulated by 'NRC~ ( used as a Yadi616cica:. flow path only if necessriv due 1.o secontarv side c ontaminationi (3) R*dN'm e

et

. k?-i, ii. ;, - I r Tct x gJ. p

td

'd'" f,'. J, (4)'RedhimV gg 3 x .\\.. u:

kauffete, ye

. ;.y t s.,. i. x x 6,500 f= sos.794 '1,822 107 mg/L From:H, S04.and a]um additicn to' ~. -

a..

(t4ees r-t.*Suffide w sr + x r.i. ' mar.u-us nauux u.n vua. s -l" %Wu ,t. I m suirn. <= sos x ' y' (14205 4 DM %s%Mw-N .,.h.9 x domestic wash wate:.- o.<Awminum .Teto#*eo f x alum add Ltion.to make-up wator[s' stem!. y (7429 90 5) - 3., p.,Berham, Tatil X '. ~ {7440 39-3 7-

q. Boron,

'ratt x Nalco 135'5bo'rax/ni-. rite mixt'ue.'is used for corrosion control. (744 24).y , r. cobei 76tif qs4*g. s X 4

(7.440-4e.4 i

t.' tron."CTotet 1 (74394 X tro w :9-6) r.4. .t.. M,. a.tum,., ,Totdfarp ) X /., j g (7439-15-4 +

u. Molybdenum, Tatitm.my x

Molybdates are used as corrosion i'nhibitors in the closed z.nd cor ponent c ooling 5 f Maas re- .r. ' ater. systems., (7439 96 7)yd 6Y) 7 3i wr.W7FOtel57 y- ".J. 440 3g 7 x f.. ... a.- s. ! 't g. is.a.;Titnlum.g trivse e n-7440 32-6)dr. x a EPA Form 351o-2C (Rev. 2-85) P A G C* V-2 CONTINUE oN PACE V-3 z., .m. g. - = - - - - g- -~.-.W

Enc 1osure to NA 93-0216 r,>-------------*~'------- . A .o. n o m o c n, mpy,,um,,,,, corm,, oureAu nomomn s l form Approved. l. } OM3 No. 2040C385 i KS 0079057 003b 3 ,y,,,y,,,,,,,.,,, CONTtNUED FROM PACE 3 OF FORM 2-C PAHT C - If you ere a primary industry and this outf at! contains process wastewater, refer to Table 2c-2 in the instructions to determine which of the GC/MS f ractions you must test for. Mark "X~~ in column 2-a for att such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2 a / secondary industrict. nonprocess wastewater outla!/s. andnonrequired GC/MS tractions), mark X"in column 2-b for each pollutant you know or have reason to believe is present. Mark ~~X'* in cotumn 2-c for each po!!utant you beheve is absent. If you mark column 2a f or any pollutant, you must provide the results of at least one analysis f or that pollutant. If you mar k column 2b for any pollutant, you must provide the results of at feast one analysts for that po!!utant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for aciolem, acrytonitrete. 2.4 dmitrophenot, or 2-methyl-4. G dmitrophenot, you ruust provide the results of at least one analysis for each of these pollutants which you know or have reason to bebeve that you discharge m concentratsons of 100 ppb or or cater. Otherwise, for p attutants f or which you mar k column 2b. you must either submit at least one analysis or briefiy describe the reasons the pollutant is espected to be discharged. Note that there are 7 pages to this parq please :eview each carefully. Complete one table (a// 7 pages) for each outf all. See instructions for additional details and requirements.

t. POLLUTANT
2. M A H M x -
3. CFFLUCNT
4. tJ N I TS
5. INT A K C (oprionaff

,[,,,),M[j y vALUE (.Loh G T

  • M

"^ 4, VALuL a. O re T HM N DL1

  • 'A* ' [,*,. Cd,",*,*,
s. M Ax nM UM D AtLY V A LU E 4

,o y l m mnatari og

=;

.1.. _,, _ pt,,,,,,, i.i... ,,,,,,., 94,,,,,,,, io... _ m pj,,,,,_ to... vses T a ^ma sq,cy;= - to... vses kE't.%LS, CYANtOE, AND TOTAL PHENOt.S 1 M. Ant ' mony. T.etra (7440 36 0)' 2M.* A.entc} Total-1744r,'38gggp; y l 3MEBerittlum?%f .T.1t : tl4 440-414):, X- .~ m.,,a - ~ hM? cadmium.V.-! .Tc t.:1 (74. 40.:43 9)7,1 v m A 5'M5Ch'ro'mlum U 4 Ta.t:t,(7440-47 3)Z v .t_ w s.. u s. A 6M

  • Cooper.*Totat' R***8Eh[C/,

X h7uIt%s'd Total {.Q 29.L*2%HG X itM MS'rc$r*y','. Tots' PJ?;%8MiM X '9 M'.'N te k'[QTot' alii -(7640 0a-0) th. %m 2 V .e. .-1 A 11OM)S'ItedruM,% 4 V iTi.t E(77S2.49,213 A e.- L. s J > s. -l ,11M?Siber Totat.- w .'u -22,% a# v (71 0. -m A -4 412M.iTh' Itfum.??ri m-

p. t::t.(7. 440 28 0.)i X

f(1' @ Zinc 3 Total? 3 o.e.O..-6 3-6..) 48 M A.O X 7E .a hkAh!C[nYde.'4* U Gs. t.:1 (5,7.12-5)'d I .Y T z, e .sm ~ (15$4iPN:."not.~.M iTatJ_lM6%/ !;; X DIOXINQ,* W q rW%*>.w:u 3r3.Wi4N;%Wfaie x p.: - i a v =,...., ,f.y p m .m.

s. s

..m - %,.p;f.;m.; + +.;;w s. --. ; + c..., a ,..c c 2,3,7.8.h tr a.... uescnaus nesutTs c h L e od iben z o.P.. Dlor.in (1764-O t.C) E EPA Frrrn 3510-2C (Rev. 2-85) PAGC V-3 CONTINUE ON ItEVERSE a* o 0 9

) ) g ll kII-s V E E G lf \\v A e P nn N i O r a y f s (. U n E u U C "L l N A a I M V t T A E N T O N "A C I e 5. E.o, A g g 2 y ST I N U NN e E O 4. CI NT 6 .-v ^ 7 ~ a OA CH .T e f se O s Nl,v ( _c ^ 4 .s } 1 ko "ss 3, ] 4 V ^ E G A T P N C^ n U l L ) e Fh t f Fh a Cd . d. o 3 N. o 8, d' E U l A V = Y la L ( I ~ A D M U M I K )l' S s D A N M e. , U 7 ~ O P M

    • ,T O

,y y C y y y yA X y^ y yA X yA X y^ y^ y y y y X y 'x j, ^ r-E ) un L I 5 i O n T 8 '.O A n a 2 F M L O v c '., {d 2 V e s (R T u N ' r C e oT r O 4' y V. 4 y.- A? 4d s '.3 t. ? -) ej d g pgly, ?+vO

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4, ii U. la A ie). n9 3'e g. y & 'Mh toExo4'ihl C it h f .nf r oT Ca n.y e 5 e rt ra rh-t t c3 c-c5 c 2 i7 i 8 4 - b '; ly 4 4 a-rd4 b ;. dh7 ot' hA e l oh-h m )4 D 5, D0 D7, iD7 45 d )f,. f7 4.. ly) 'h ( 7 7 i t o) nf ht) niV o) ot9 e" I o r ) o ): he1 r - 7 21 '1, e '2 C (e h - tee. h(, m s F ut r C y 4 'l o-CE1 t Me F 7( - ( 4 tee o to4 ty-e1 r7 r e1 1 o) 'o,

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7 f u-e / y 7 p V0 Vo Vl r i 4 'V 5'7. Ve VI Vr1 v7 oh1 t 7 5 h h 6t 7r 8ro. 9 0r 1h A C 0 h Ve4 V O f 5 2r7 3i7 4t 5t 1 1 7 1 1 2 C, P 5 5

t. t 1o(

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~ ..,,,.-,.~.v. -m m< ma ,. ~ ~ -.. - 4 over Atu rsuenenet l OMB lVo.2040 4086 cpW.08g/$6$e ) copy from item E of form 1) 003b Awwevaes nr se s CONTINUFO FrtOM PACF V-4

1. POLLUTANT 2.umseet x-
3. CFFLU CNT
4. U N tTS
5. IN T A K C (oprional)

' AND CAS to. M A Asglyp,3, pan [);v V A LU E c.Lons ryeu pyg. v As.ue-- o on._ T r n u o NUMUCR

  • * ', ' '['.*l;j,* **.
e. M AxiMuu O AILv V ALuc Tn ATeoM (i/ e*eelabic)

." !.- W ., J, , t.),,,,,,,l g.3.., , {.),, v,,,, g,3.., c,,e jg,, ,,u g,3 yggs g, Le e,c,. (4)m. ate YSL5 g, c, GC/MS FRACTION - VOLATILE COMPOUNDS (continued) 22V. Mithyfene y l Chloride (75-09-2) .-a 23V.1.1,2,2-Tetre-chloroethene.3.Wffd m (73-34-5)M )( 24V)Tetts'c'hloro4 (th. ylene (127..18-4) g 25D.'.Tol0eneWU$ l (10848-3.)f., M/. X .. ~ -. wrs 26V 1,2-Trans.s.3 Dichlottethylene) (156-60-5344 FW * 'X 27V.$.1,1;1-Trl.yf4 chloroothene*We.g X (71-65-6)W A' N 2avs1.1.2-Tri '% i chloroethene N O (79-Oos W d i m X-2CV.*Trichloropd othyle..rrs.,(7,9.01.-6. ).' Y o - ~ A 30V. Trichloro-y,2, tluoe% methene t "... (7 549-4).us.fA X ' 31V.IVin'ylN P. Chlorida (75-01-4) X GC/MS FRACTION - ACID COMPOUNDS w *' t av.h-1-.- .< >w 2 v "E*-- 1 A2 2 Chlorophenol (05-57 013...Q X 2 A'. 2.'4.DiehloroA' phenol,(120-03-2); -v

u... -..

A 3 A.'2'4'Dir~n'e' thy 1 { Ph*"*'.Il0.ts7g); X 4 A'.*4,6-Olnitro-04 Cresol,(53p521),$ X 5AT2 4-Olnitro!* phenot..(51.-20..5)d.- V A ~ ~ 6'A*2-nit'r'opheMi'- O/,5 5)fygg5% X 704 sitrosh.noi: (100;O2,,7).gg.ip q X B AJ P-Chloro-M.'.!' - an -.ol f 59-5,0 7) I.A., Cra es - -e-a, Ya E.*

  • Ptnt ac hloro#.~:

. ~ + -o n 5.) % X 6 i phenot (87 8G. ~ 1'0APh7r7elpdQ ~ M -h-c.$..,, h I.{08jy-gg;?,,yjf ,y m.t r

  • - <- +

if, v 11 A. 2.4.6-Tri. ? chlirophenot.'^".*'. X l (!8 OG 2)O

d. h TL%fMyP174MSM'T41__

h WoT70GTNWLfeTNFEVEESI-

TK5'~0679057 outran 003b .--,-,,.d.-- t. - - ; _.. w..- CONTINUED FROM THE FRONT

3. POLLUTANT
2. M A H et *M'
3. CFFLUENT
4. UNITS
5. I N T A M C (oprimmif -

^"UEE

  • :. = 3,:::,pe:r

""" MMR7 ""' " ""Nk%& W ^"' taygy

  • "== = o ^ " ^ w e x "nPMWa"L u ay;g.'

e

e. concc..

u se-1.hro .=. .=..... !:,s.,, [ i.i -... '"ama e i.... i. i -... ...,i..,,, i. i.... vs s i.i... ve. CC/MS F8 TACTION - 1.tASE/NEUTIIAL COMPOUNDS

13. Acenophthene

,(83-32-El g.7, X iffAhanophtylene (206 % )g,g 3 X '3OAhh'r' acon's)f-N 312012 7)fgt.;,; X ke*li'e'nVidn' S.W '(9247-51iff.W[d X A,RL' E entsfal g{* nthracene - 'f67-55-3:%hgd.,f y, E ^d r-,...,.;.. SCO Dents'(s)v w 6 Pyrene.(5_O 32-8) $ X (7D.3ADenz g ,fluorenthone ( y T206-99-2 Wit A 4 2 n enro'(thf 'Perytene.Af T)m..' y I(121-248-2)hD4'; A 4%)Denso(h)py,f, IFluorinthene '(207-084W g gU y .n [1ts;4ls (2-Chloro-cithozyj Mothene. y i(111 C1-1)^ut4 A f11FJ Dia (2-Chlom 7(1_11-4*M)[Q.tW}1rl N-thyl) Ether i 4_ kS8Edd~a le~M 102 'girepyM~ther.(%..-60...1) K 133; tis (2-EthyI lApryl) Phthalotet.q y f(117-817)t0/dil A

1tD fsororno.yg

phenylPhenyiMs ! Ether (121-65-3)'.2 X }15I2utyt Dennyt L :ht.hil? ts (8.,5-G8.71 P ^Y

r. w 11C.2 Chloro-@
  • nephthetene VAN E

4(31-58 7)to.*J W. 1175.W. Chloro-4,*. gphenyt Phenyttidi y

  • E ther- (7005-72 A j(iM;Chrysene
i. 2.~18-01.9.) i A :-

X 1&O#Dabenzo (a.h; l fAnthracene92T; .; tt:3-70-3Hud?A X 4 BOB 11.2 D'ichloro; e tw4 ' benzene (96-60-1)' X >6"?

  • a-

+ O , eretw b.O c:-

    • g..,

= 5 (21[E61'.3-Dichloro'. (b._on..z. ers (641.,.73 1; X . w' ' 4 s. EPA Form 3510-2C (Rev. 2-85) PAGE V-6 CONTINUE ON PAGE V-7 ~ 4 . + .+v-94 G A r

v

m. mna em -.

e*, yyj [* EPA I.D. NUM5 Eft (cpFy frons Efem I of Form 19 OUTF ALL NUMDESI t OMS Ns, 2040-0036 t-KS 0079057 003b e-~' v-+> i-3r-as CONTINUED FROM PACE V *

t. PO t.t.U TA NT a.measeet x-
r. +
3. E FFt.U EN T h ->

u w = ^ 4. U N ITS.

5. IN T A K C (.sprirmelf
b. M Ax $sNesariaNJ "GThe.E..g g.vALuc V v A' L

[iM;,f.M..

a. M AxsMuM D AILY v r. Luc y AOg g Q'*y AUMlJf I o r u o r a

(el e***feblef .g. .W, I

  • 1,,,,]

teg... c,,, r, p),,,,,, g,3.... .,,,< p),,,,,, g,3.... ysgs 1NN tqf,*,7,7 gg.... ngs CC/MS FRACTION - BASEfNEUTRAL COMPOUNDS (continued

  • 228.1.4Dichtero-benssae (106-4G-7:

y ,233 3.3 -Olchloro.

benaidine9As *66 X

4.- 431041) FM. s24ADiethyl g. , u.a.

Phthelete

((84C3 2)

  • 8%

X

25as Dimethy8 sg

'Phthekte &p.fW 5(131 113). M K X ~ 26A D6-N-Sutyt... ,Phtheilte7-(. ',*'/d.h'- X

  • g/ *

'C4 74-2W.. A2720 2.'4-Dinitro T,- Is..&.tuon.o (.12.1.14 2.} X t t j I '28%'2%D'Inttro'8', L '.trluesta (60,6-2.,0-2) Y 4. m n [ 1293.'DI-N-Octyt$b hthekte.' ^% f(117.^tM)pM*.4f i y a-k A (- 3084.2-Olphenyh 1 l + hydraine (es'Aro-. bansmal(122-66-7; X 1310'fF[u'oIeAthan's U206-44;0lWJin X u

32MFhidene 9 d

l- . (86.-73-7) N. n..** * 'k

a > <

t .338.Hemocniorobenrene ill&I'fl.f 4Tif X i l '343.4 Heme ++ g I ichlorotxstadiene c-y t(T,7-68-3) *h4M4 A t t 35B; H1cmschloro l l? icyclopentediene2.' y l '(7747 4)iaevsMY ^ 436MI' eischtoro < 4 i S.e.t.h.a.n.e.'r(.67 72-11$ X p- ~. s37?.;Inoeno,vsay (((f;2.'3-ed) Pyrenek N 1 $3-394)h"& sat T383'l'e'oph'oronMe : ) t(73 53.1))Ws*9 f. W. v ~ s,. A 1 -39 S.oNephth'elene - 3191-20 3)p4*t,'d t X C$ Nl' r'o'be'nieAe t ~ ~ ' 48-95-3)fWW X i [l !41D&N-Nltro-Vire Ej PsodimethytemineT l; i(7.2 75-9)s%g*.hv's X st;23.* N-Nitrosodl.: '.N-Pr,opyte,miney,) X c62 4 7.. - EPA Form 3510-2C (Rev. 2-85) PAGE V-7 CONTINUE ON REVER

, a.: _ , ' KS 0079057." Outfall 003b CONTINUED FROM THE FRONT

l. pot.LU TAN T
a. u Ase n w-

- M.M % &. -. s - ' *f "3. CFFLUCNT % i 2: ' ' >'i-* . '34; U N ITS s

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  • l.*, [,*, 0
  • d,*,*,. a. M A xtuuM DAILY V ALUE 3gggY V A Lu tE c.LONG Yga_m g r.VALus; n

<,/ d.*, .=. := ,,,,,, e,,,,_ l ,,,,,,,t.,,,,,,., ,,,,,a.,i,,,,,,,, i..... vu, o e,; :,--- ,u, mama GC/MS FRACTION - DASE/ NEUTRAL COMPOUNDS (continued) 433. N Nitro-. omdiphenytamine,, tel.3041e u - X - 44 NPfietienthrone (15,-0,1y;jyyj X iS M *r'$e M M

  • e U39P.DTi$$$

X 468,.1.2.4 7 r chlorobenrene % . gaw (120-82 111*# ! X-GC/MS F RACTION - PESTICIDES *^- >%w rw-r. wt.. - ~. n e ~f - e . - u. w. 6 4. e?w.r - <a m a e + e +.-= w w %u s ~ .--u~- 1P7AldrinN'h WW (3094. 0.2..)A~ *?N.F X ~s1 2P.TEHC M (313.-844) w 4' X 4 l 3P.'h-EHC f( D (312-85.a.7) ff" M Y ~ .m.. wh

  • )

n AP7%DHCN(b'"4 A M 'f Y ~ (5843 9) *DN - w.. a SPf6IHC"I% a (319,4s.83.dse X 6P.dChisrdaneh*y. ek d 5 i 7P.?4'4'.DOTf.Q3 (ss29;3Qfy,Qg X l BPf 4l4*.DOEQ'M (72-65 9.). r'd.s,N;**' t me

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.r -.--mm-.m , e m.. -ww - - m ms - -- m, -Form Approved . p ne. -.~-. ' ' Es A s.o. reuune.se scopy from Jtem J of Form JJ OUTFALL NUMBEsa OMS Ns. 2040 0036 l KS 0079057 003b Mc=>!*=#cs ?-31-as ' CONTINUcD FROM PACE V-8 a'4.' U N ITS ' - 5. IN T A K C (.iptirmeff'

1. POLLUTANT
a. m a re n x-i e

u- "a< 3, CFFLUCNT - . u"u NCr ^ ^ a maximum onety vatur k "^ ^'*Nf 7 l?f3;" " ^'"'; ' ' "" TM'."J.W f " ^ '"' ngogy Ajg G"& te gogy ,am T " ^T *o" 3

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s.:.... v si. s '01===41 t.tcr .St;- !"t.; ,,,,,,,,88,,,,,,,, e,i-... v si.s ,,,,,,,tf,,,,,,, t.: -... ,,,, t f,,,,,,, s.-... j g GC/MS F RACTION - PESTICIDES (contimsed) 17P. H.pt.chtor., l 'Jpoulde WgrA, ". Y 1102647-3). 18P.TPCT.1242CM ,!?..34,69-214..);fjM;. y. '19P'tPCN1254 #.8} $.gD9,7f91),p,,' 1 y-3 dM.< PC B '1221%) !11n2s;2)Agn x 21P'fPCL 12'32 'lQ (d',141 1,.0-S.l#M. - 1 V ..t x A% A. 2'2N5PCfM1'248'#i". (12672-234)h$-H X 1 23PJPCS 1260 fD*: (1.,10944. 2.m)v_.*?8 X 5 24P$ PCi$1016 ?st 12281 % ';2 % 3 X 5. h...on.n. sP. 1* a 9 5:2) E X 5m PAGE V-9 E f = t i 'i 4 6 . 4 hrm 3510-2C (Rev. 2-851)-.

p-z :. i.a:. :. i, i Enc 1caure to NA 93-0216: Form 20 parts V-A, V-B and V-C for outfall 004. Maximum daily values for part V-A will be submitted when composite samples and 6rab samples have been taken.-- i i I i

g- ~.. n -n Main dan discharge er A s.o. Nuu ulu to,n gn,m iram s at rarm n ram Aps-a ed Lnto 'n'o1f Creek Pt. CASE PRINT 00 TYPE IN TitC UNSHADED AREAS ONI Y. You may report some or a!! of OMtk h ?o m 0036 stus msorm.stum on segurare sh.xis (use the s.we format) instemt of completim. these tops. KS 0079057 Si l' tN's t itt C t f(INS V. INTAKE AND Ef f LtJLNT CitAf tACTERISTICS kontmued / rom suge J ot fann 2 C) 0d!$ " ^ PAllT A - You must twovide the results of at least one analysis for every pollutmt in this table. Complete one table for each outf all. See instructions for additional details.

2. CFFLUCNT
3. UNITS
4. I N T A K C (opri.w<.f f (mily if blanO 3

vvALug C.LO N G T 4 Qpg.VALUE L* " ^ ^'"f[/"**a8,gg1 . Lonc n nM

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l ANALYSES [+> <Yrk b" **.'h a6,',04 6,, - 18)*^**

  • ' %4;M)a.4

,-s.(e)aamsey?Q (*g g ',I g,4 ,P ts)ammes AN ALYhES MA$ [i' ((;,,, (*l mas

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~ ' ' ' (BOU1h;gmt&'r s W Ctwmicalwwm 4 Oxvoen* Demand -. -- l gnoyyp4 4 -t e>Tattroisiniew 4 Cert >on[(TVQ ~ j - y dQitti Suwended 4 So. lids'(TSS)n*H;,an;, l -Aw. rh. wa.- M emmwim t e,' Ammonla (as NJ. $ itWWMJ.4 i i VALUE VALUE VALUE VALUL @v'wf$%@,.grg 90.63 12 93 40 MCD VALUE VALUE VALUE V A L U t-. ETNweture' (. tse,en.wrevs 75 67 40 ,C VALuE VALuE VALuE VAbut yg-p, reE==crip,, 27 5 25 2 40

  • c MINtMUM M AXtMUM A. t N I M U M MAA3 MUM I. pH 83 8.6 1+0 STANo^rtD uNtTs I* ART H - Mark "X** m column 2.a for each pollutant you know or have reasort to believe is present Mark "X"in column 2 b for each pottutant you believe to be absent. If you mark column 2a for any pottutant vvhich is limited either directly, or indirectly but expressly,in an offluent limitations guidelino, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a you must provide quentitatiYe data or an explanation of their presence in your discharge. Complete one table for each outfall. See the instructions for additional details a nd requirements.
1. PO t.LUT.
2. M A rm.x '
3. CFFt.U CNT
4. UN tTS
5. INT A K C (epnemaff Y V A W t.

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A E A E V A 4.U t" NO.OF d (if avaitsble") ' .e.n.e. A N A L-tk M A$s, ANAL. ..n o.,,,, {'),,g ,y tel,=a..-,,,,, ; ()..,,,,, 94(al.uassJfd e d.,, a l')..,,.., tal naass vsEs ^ T 8 0 ". 9 ,,,,,, D],,,,,, til-... vsEs dieroMMICQ (24939 67 9) 3 X . m. %7[,U"ig3.4 x-0.06 from circulating water dische rge (soutfc 11 003) 1 mg/L w M,. > rw c.*Celo X T=M bI d.' Fehl 4 y Cettf1 -. ~ - s g. A 6 FI55ildy),, y (1 E98.$'48-8 g

s..., an. s f; Nttiste :,Q X

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*, ;. EPA Form 3510-2C (Rev. 2-85) y
e...

Q. PAGE V-l CONTtNtJE ON REVERSE

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Ks 0079057 Outran 004 ITEM V.R CONTINUED FROM FRONT t.POLLUT. E M A H M *K' 3 EFFLUENT.

4. U NITS
5. I N T A K E (..priossaff A

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    • G.Jg *,*; s. M A xsuuu OAsty-v ALue l ta. 64 Ax,y yg/y7.;V ALU E; Mg

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  • ANAL-

,.m.e.,,,,,,,,,,1,,g,3; f, g.g.. 74. - ;[);gp3;,;q g,).w.e4% 7tJcT[VI;;;;;. .a,; - t al = a.. vses (* -v [" M.' "- 4'fe,w,M* E6.c.iV..v.. . s tat =a ,vses; = s.:N8trosen.c y Tat:5 O*penieg ..e (se NJ'AbW.: X h;iO A and s s..., X Oromes

4. Phosphorus g fee Pp. Tosat. :.

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m..A e

ss Titanium,k.s .titven;t. e X + ,p 7440 32-ofdie EPA Form 3510-2C (Rev. 2-85) P AGE *V-2 CONTINUC ON PAGE V.3 L M 4*;. ~ ^ ^ ^- -^^ ^ ^

Main Dam Discharge into Wolf Creek Enclosure to NA 93-0216 ...o. N o m e N,- f,,,,,y,,,,, m,,,, ,, o o r,m N o,, e N .,..,m..m,,-,_--.....,.., ( .{ form Approved r' KS 0079057 004 ecgro." ewe m tss C"8 " "

  • 88 s

CoNTiNuEo rnou pace 3 or rutM 2 C PART C - if you are a primary indus ry and this outfatt contains process wastewater, refer to Tabre 2c-2 in the instructions to determine which of the GC/MS f ractions you must test for. Mark "X"in cetumn 2.a for all such GC/MS f t actions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2-a (secondaryindustrser, nonprocess wastewater our/a//s. andnonret/urred GC/MS fractionsL mark "X"in column 2-b for each pollutant you know or have reason to beheve is present. Mark "X" en column 2-c f or each pot utant you tmheve is absent. If you raark colu nn 2a for any pcitutant you must provide the results of at least one analysis for that pcitutant. it you mar k column 2b for a ny pottutant. you must pr ovide the resu!!s of at least one archs.4 for that potiutant if you know or have reason to believe at wifi be d:scharged in concentrations of 10 ppb or greater. If you mark column 2b for acrotein. acrylonori'e. 2.4 dinstrophenol, or 2-methyl-4. G dimtrophenot, you must provide the results of at feast one analysis for each of these pollutants which you know er have reason to beheve that you discharge m concentrations of 100 ppb or creater. Otherwise, f or pollutants for which yo*e mar k column 2b, you must either submit at least one analysis or briefly describe the reasons the po!!utant is espected to be descharged. Note that there are 7 pages to this part; please review each cu 'efu !y. Complete one table (a// 7pages) for each outf all. See instructions for addstional detarts and requirements.

1. PO L t.U T A N T
2. M A H M 'X*
3. CFF LUCNT
4. U NITS
5. IN T A K C (opreorraf)

" M A A# [,h[h) N ^ 1.1 1 D C " I." * ' '[.". 0 Ed *w g

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g as

a. CONCEN-A eta t UC N

MMS (i/ petid Me) oE-3"s% s" a'r , d') (a)== = ss d') (a) saans I'),,,, la) sa a s s YSEs T R ATION (, co g,g,,,,, yggg og METALS, CYANIDE, ANr' TOTAL PHENOLS - 1M. Antimony, Total (74,40 36-0) - vA 2MIArminic) Total (7/A >33 2)Np s s v %%. o.., _ - -t A 3MEBerst:IumM, TT t 18,'6.,0.e 1.-7): - 744 4 v k$. t A 4MICadrniumhig .T..W.r (.7. w..:.4 3 -9.,) % 540 Av h' .SM7Chrimium.Mh TJ t.;.I (7440.c.3); 47 v asa t.c t.o .~ A 6MICM.* Tots!M F**"NW.t% X 77MIt eAf,'TotalM* M .4G.33.-921)6, 3. '- .N V . + A CNIIM*rcury[Totet 17439-97.-6) ww., V .... m.., A 7M7 Nick'el!Totati w(74. 40..02-0).N.... A V - w.n u. it'OM2S deniumMJ 7f tgt,(7{02 49;2)y X [11 MIS!lser} Total s w.#40-22..4) '*b y (7 M V ^ It'2'MbThilitum';.a W .Tet;I, (7440-28-0) :. X I '350Zir?c,5To' tat l' t 'n(.7#.4 0.66.-6.).'e A .=* Y i r.. i 514M.lCYanide,t.*M ,Tyt:l_(3712-5),j )( 4 15 M.* Ph I s. ' ~ ~ i ,Tital r: t-V.c X .D IO X1 N.' -'C, v.cr.My

  • M ' :.-,

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9. POLLUTANT 2 M a n n
  • A*
3. CFFLU CNT
4. UNITS
5. INT A K C (opri<mel)

^ l' "^^"j,W.,312Cp' V^"' "" '[/'" Gl,f V ^"' gMQ 73%

  • * * * ' ' h **-
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<1,n o or h,* o {,r nUMuCr ,j, ,. con c en. ,j (af e d ble; f.*7.i , p),,,,,,,l g.).... ,i,.),,,,,,,, g. ).... ,,,,,,,t,.),,,,,,,,, g,3.... ysts T H ATION g, ,e,,"- (,).n a s V5t 5 c,, GC/MS F RACTION ~ VOLATILE COMPOUNDS (conrinued) 22V.' MIthytene Chloride (7. 5.-09-2) 23v.1.1,2.2 T,etre-sAloroethenet jfi ( 79-34-51 %.Gr* *' X 24V3T'i[rs'chloroJ e .127 18.-4.) (t.h. yle.ne ( s, A -n 25'V$T[lde^n'e7r%rl (10808 3.),.;W* A@. # A v 2LV.-1.2.Trans-pw4 Dichloroethylene'=E (15?c60-3)J4 M C 'X 27V.'1st;1 Tri-he. (71-55-8) mal = $*jp i chloroettv.ne'hY X 21V.' t.1.2-T ri- >*ud chloroeths.no : 8.,# X-(73 00-5)ec_ Nil 2hV.fTrichloro(+.Y,j e.thyle,ne.-(7941..6)- AY 30VITrichforo.*r 2 fhsoromethane-D (75 69-4)xa.i?; X 31VJVin'yiTdW> Chlorkh (75-01 4) : X GC/MS FFtACTION - ACIO COMPOUNDS.wr.'.*wn *< +', ' *- 0 +*C T >+.w c -r 1 A' 2-Chloro' phenol (05-674));.gf X 2M2.*4 DichloroN pheno.t (120 8,3,-2)F .v - r.,% A 3A62.TDEsthylS phenot (,1,05;67-9)} X 4AJ4.6' Olnitro-Oh' ~ Crrsol,(53,4-52,1)r.g X 5'A'!2.4'Olnitro--(d phenot, ($ 1 28, 5)y.* X 8'A721NItrohiedoI! ~* (18-75-5)ph*(y:gg X 7 A}4-Nit'rophenot : 900;o2;7).,334 X B AP-Chi @ro-M *y{ ,C..re,so.o(.59.s5.,0.7) ^' l V . - cv A s SAIPsntechloro .*1 ~... - phe .~.no.t (87 86-5) %. X' '

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  • EPA Fo rm

'3510 - 2 C (flev. 2-851. CONTINUE ON HFVF 5tRI: P AG C V-5

KS ODfl9057 outra11 004 CONTINUED FROM THE FRONT

1. PO L t.U T A NT
2. u An n x-Ji
3. C rFt.U CNT
4. UNITS
5. IN T A K C (oprionaf f D M ^ ^ 8"gfy,fgjY V ALUE C. LO N G T 4M /

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a. M AxtuuM D AsLY vaLUE NUML El 3.'.*,, j,*Z
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  • !a'n't"o (A); Yf

~ 'Pyr,ene',(5,0-32 4 ) s X 73 - 3.4-Denr o-a flue; eenthene T r' 4(205-DA 2pnd-l.: X +4 8:Wienzo (ghi)*'D Perytenedyg., I(1 tt.242) e.vD n ~% Benzo (k):Sn IFluorinthene ;sg 4, y f(207-08-9) e1%LC A $12%.1.!Is (2 Chloro-Jthozy) Methane.- y f(11141 1).e. A (11.14 dis (2. Chloro-l thyfl EtherR q ) '(111-44-4)'J. sui X 7 -t 12H' Bis (2-CMarofse-s gr.apyt/.Eth. er (102-601) X 7.130 0ts (2 Eth yi.. 'h:xyl) Phthalate.i '(117-81-7)W.7.'"* E

1/,0. 4-Brorno-yp phenytPhenylb 92

' Ether (101-55 3)3 E k }15dDutyl'Benryt bz w...te_(85. 68 7) V Ptith i.. A p15 B 2-Chloro.p,'3 e nophttr iene:..'. -4, v 8(31 55-7)a*iN ^ g17B;4 Chloro ~ As phenytPhenyl.f ' N ) Ether (7005-72 3)

  • 1!B Chrysene-@

(2,10 01-9.)..$ ', M 'l X %s e 190. Ott>enzo (d.h) FAnthsecone *f.v3 l(53 70 3)tu.a. X f 20131.2-Dichloro-i.t>enzen.g(95-60-1) X a..m..'.. ,'21'DD1.3'OIchloro. .benr. n) (5417311 X EPA Fe rm 3510-2C (Ilev. 2-85) PAGC V-6 CONTINUE ON PAGE V.7 mi.. e s

ll l lji { lr E 5 V t E i R ff V m i, N e e O i E r t p U e s NI ( u C e a, T N M ( O Ry C T r Nee 3 I.o 5 = 1 o g3 m7 ) a g,, s [ e o d g p om j e l oa n e gr S p gp T = OA I M 1 U N h 4. 09 T A H T W A s t o s v g 'c; ~ e t u ~ L t = 5 1 h o = v

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'KS 0079057 outran 004 CONTINUED FROM THE FRONT

3. POLLUTANT
2. M A n M
  • x*

,-a.+4s.

3. CFFLUCNT _

-*1.

4. U NITS
5. IN T A M C (.mti<we.rff N MUCf
  • l*,,[.'. *Ej.* *.*., a. M Ax MUM D Att Y V ALuc dan)v V ALue. c.LONG Tgeu ggr. v AtuE
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  • 9 (31 W )

X r u n+*. H+ 5 3P7$4ftCWM/F ~ ---.'@dM X~ (31Na3 7) ~,s.m* X S) w 1 5 [P"NENC hM ii lys;agsj[ggeg p X '7' I ePfchtYrdTn's

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-h'~ 7.. ,~~~..r-e.-,- - m ~n -- ~ ~-~. ,y ,,,,m. EPA s.D. NUMEEN (copy from lfrart J of 4'Orrte JJ OUTFAlt NUM5ER 1 oms No. 2040-c03K KS 0079057 00l+ d Am-# *" 7 3' 38 CONTINUED FROM PAGE V.8

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  • *'d. UN ITS <

~ 5. IN T A K C t.sjerkmalj. '

3. POLLUTANT
z. M a ss u "x'-

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h. M A AtM M.

.vALUE C.LO N G T cuesg M 3 9 pow)Y V A LU E A V f'H AMW' E "I U F ' K NO.0F 0"G NUMUER

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  • vsEs GC/MS F RACTION - PESTICIDES teentiereseds,.

6 17P.t Heptochlort M Eponisse;e g+rS e. ,X (102#r67 3) x .1sP3PC41242 Y"p, ,(63469 2,1-9) ANf X' i 19P/PCS 1264 Alp 2 .Olo*7.53.133hw X iOP':PCax2i1 - (11104,.28..2..) w s r A 21P'.*PC7$1232 @ ( ib s ,,.11141 16,-6).t w %.s ~-e. w A 22P2PC61'2'48'5,'s-E (12872:21 Hug 4 x 23rdPC312604 110944. m-5,)d"=3 X. 2 ** (

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x 2'4Pj P'C'$1016IEi ~ (126. 7.*e.u a-2.)P.M'* X 11 rs - 25P.Wrse*oSm'e2 C001,.35-2 ) y,-8.' X PAGE V.9 h

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k s r, w ,s i lx_ EPA Form 3510 2C (flev._2-85);__

l t v l' c 1 I I i-Enclosure to NA 93-0216s Form 20 parts V-A and V-B for outfall.co5.. Maximum daily values for parts V-A and V-0 will be sutaitted when composite and grab samples have:been taken. e a / e 4 a ge;..

Line Sltxige Pond Discharge m. e-... elvA t.o. NuM utu lcwey from 2 tem 2 of Vuren 2y ' Pt. EASE PnINT OR TYPE IN THE LJNSHADED AREAS ONLY. You may report some or att of OMB No 20.ro on3C . teus uituem., tion on sep it.ite ste is (use rtre same fonnar/ irnteaal of completo=J these pays. KS 0070)057 m~ <. o = ';t i INS f t tt K t lON'i Oh V. IN TAKE AND Ef f' LUENT CtIARACTEntSTICS fctmrinued inwr p.me 3 of I'wm 2-C1 PAllT A - You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outf a!!. See instructions for additional details.

2. Errt UCNT
3. U NITS
4. IN T A M C /..fariu.w!)

(sr*ce if y if Idenk) Mp .VALuc

b. M A M W L M 3 Q Y v A Lu t-;

c.LON G T . Lo, c T, n a

1. POLLUTANT
a. M A x sM uM D Attv V As.u f is

=*a*** 1 st, N o o p-A v r es e e v a n..u e, hNo.or 'r N ATN"n* ti.M Assy ANALY%C$ h 55Nhi$Nd I, 8 ^"^'V5ES a ;,u, */,,y,,,,, *. Isl a * ** w

  • g4WD),lg,,g, %. tal =as* M) /M;;8l)g.,,g

. tal was. g,9,,,,, a.g e lochem4 cat.,, f s i.,.. L OzygerrO'ema (JEODIM$ . Y k tuchemicaeg. 3 02Veen'Oemand.-M i. F ~ (CODJhypu e%a.j w Tv-e- r b d(Tit 'tsuspen' ed d e .( soindrrrssiv. t . 27 1 a. -fi.7 8 mg/L --a n.es %"A'*mmo'MW) n. y'o =* esse s nlafsa N 4 t. vALue vAtue v ALue. vAtue i ,f- .a 10.800 6.940 a ~ 6.015 8 Mco

w. m :

"^'"E V^'"" "^'"E " ^ ' " ' - i sATem'peretdrees) i , T,T",/MN*i 5 e v A t.u.:. vALuc vALue v A i.u t. 4,g.g C (summnig=W y MtN4 mum M AXIMuM MINIMUM MAMIMuM 7.6 8.0 8 sr^no^i20 u Nits N PART 11 - Mark "X"in column 2-a for each po!!utant you know or have reason to believe is present. Mark "X"in column 2 b tur each pollutant you beliesve to be obsent. If you mark column 2a f os.iny pdtulant which is limited eather directly, or indirectly but expressly, in an ef fluent limitations ouideline.you must provide the results of at least one analysis for that poilutant. f or other potlutants for which you mark column 2a.you must provide quantitative data or an explanation of their presence in your discharge. Complete one table for each outf all. See the instructions for additional details and requirements.

1. pot.t.U T-
r. M A ne x x-
3. EFFt.UCNT
4. UNITS
5. t rJ T A K C (or.fionaff d N O. M AS Q

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  • A M ASS ANAL.

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f. NitrEte--M.

X Nttr.its (se NN s a - t.:- ~ j ) EPA Forrn 3510-2C (Flev. 2-85) .. ; y ;,g.PAGC V 1 , ~. s.. 7_y-s 4 4 "t ,gn {...=9*+m. y

KS 0079057. Outra11 005 tTEM V-B CONTINUED FROM FRONT t Mann *x-

3. EFFLU ENT 1
4. U NITS
5. IN T A K C (e A>>#all t. PO t.t.U T-

.VALuc ANTAND

b. M Ax4 C.LONG T Mg e@yy.
a. M ARBMUM D AILY V ALUE 3gg y V A Lu t.,

.Or 4 %1%(*((g 4 NRM g g C AS NO.. . A Mass - a n 4 L. a.n 4.L,. s . ; y..g.... r)..... i,i... us ra^m= ,,,,,,1.), x,,,,, 3 i,,... 3 ;,,,,,2!.. a., m i,i g.. e u,,,, r),,,,,,, .i..... su u.wis swam.m TetI4 Orsenk X fee NSWit'&ei, Egg @f x < i.o (1.0 a mg/t Ii

1. Phosphorus,

taa PA, Total ' x (772314-Oi ; ): Radioactivity.M"6%";** 's

  1. ' '*/.W'* *** t?kM/#fD YvNMDJ7ff' kt'T*ATDN f%*ttEI'd '

-t'.'* 'i M' '*? 'N#5N'T N 3 %"'"*' (1)'AlpheMT[ x, v ~- ~. gg yg (2) B.t; ' ~ - Tat; x id:= s (31'R edf0W'8.M .t f' T.a.tstgep. ' ' [ ' ' I X Jf (. (4)'Gadlem 2mTo.i X .e r+. Mu 5 f? MES$.D[?x. 1,498. 1,195 E.O.-J'... 936 11 mg/L g 04 sos.nai. H ..m:svid.g(eg ,,. p c n; Q;;l ~(dr 51 Re X f. ..g.. s M O.. s. q..- nwS 3 lfite tW, Wdo,s x y' - ,,iy a, i. P' (1C265 f g ?sT,1;:M s 7m x g g 3, -3. - . Abminum, x 5.1 (from alum coagulauion).. 1 mg/L [;..pfy,qfg [4 p.a.oum T&tti/+yh,hr. ~i ,.p x t (74(4 39-3) j - l.

n. Doran, t
Tuo s,

x C .(7440-42 4 yw.c. bei x t. a.: g44, ' y a m. ~: ['. c.trwcroNt 5 x 1,,- '.(74394 9;6) .- i.. s-M, m., & Y "' 1 mg/L x 57.4 (cancentrated from raw. waters. %+ q s. .y, . uayem.num. .Titrtq*Ays th x a (7439-98-7htn ?^ M engeneee,. It't%g3W x 7c39 96 61 ,g t w.TTinrTotal 3 ... '. 't 7 M&31-5) x7. ..s.. J /, ;.:... i. ~# M7F45 $8' . ?! - T etantum, t1:i.Im. 7460 32-6)TV EPA Form 3510-2C (Rev. 2-85) P A GE:'V.2 CONTINUC ON PACC V-3

g. +.eyew, - . - -, ~ ~ ~ ~ - r- + 4 Enclosure to NA 93-0216: Form 20 parts V-A,t.VfB and V-C for outfall 006. Maximum daily values for part V-A will be subnitted wh.en composite sampl6s; and grab samples have been taken. I i 1 e i l - I l )

Essential Service Water p.uvA s.o. nuuut.as teupy from item 2 of Evreue 1)7 System Discharge PLEASE PntNT Ort TYPE IN THE t>NSHADED AREAS ONLY. You may report some or all of o3,f,fu,g,oog3g stus memm ium im seturate shwis (uw rie same format) instut of comptesimi these tw-s. KS 007905'l 4.,....,......,, :o : < rrrr.inorriore: V. TNT AKC AND Cf F t.t3CN T Cs tAtt AC TCTtESTLCS (ctusthwed from p.me 3 of form 2-C) 5 PAflT A - You must provide the results of at least one analysis for every po!!urant in this table. Complete one table for each outfall. See instructions for additional details.

2. CFFLU CNT
3. U NITS
4. I N T A K C (of sn met!

.VALuC (sprcif y if blanH I'*"^^8)ffUjj,N[jv v A Lu t., c.LO N G T M p] I. pot.t.UTANT

e. u Ax1 mum O AILY VALut' N

M .$ N ',W-d/,,*,,, A, "radel***** %T 7,fe^i;h/,,'i,%;; d wl8) *'* * *VW. 7 * M d " *P. f a)..s s - nAv n Jh.M ASSU ^"^'"E8 ^ " ^ W S ES 4,' 7;;{};g,,, (n)... 4tilocrwmicetg (BOD)

  • v>

. d.- Oxyge Demahdy 6-WChemiceip j-oxyeen Dome (COU),'t,es%4:e > c1Tatit'orgeriteTrj Cerbon (TOC.)v* .>~ m u d2Tztil Suspended S4tids (TSS).otu 9 ns awf..l1:f a $EY555$N] m:sw& vAtut vAtue vAtue vALuz a p 4FI O.A$5 .. '.3 31 25 112 MGD + v^tuu vAtuu vAtue vALue g3To peretare %; ,C c.eu,rn> ~ A,t.t % :: e

  • -W VA1.uE VALuE vALue V A 4.u t-.

gggp C t='cmmrykmry __m Axeuuu unn Muu Maximuu utneuuu f PAI1T B - Mark "X"in column 2-a for each poffutant you know or have reason to believe is present. Mark "X"in column 2-b for each pottutant you believe to be obsent. If you mar k column 2a for any po!:utant which is limited either directly, or indirectly but expressly. in an etfluerst limitations guideline, you must provide the resuits of at least one analysis for that pollutant. For other po!!uta nts fcr which you mar k column 2a.you must provide quantitative date or an explanation of their presence in your dischar0s. Complete one table for each outf all. See the instructions for additional details and requirements. I.POLLUT.

2. u ann'x-
3. CFFLU CNT
4. UNITS
5. I N T A K C forerio wtj

/ 3aNdi c.Lonc Ygeu pgg. v ALuc v v ALue a r. C SNO ,a R. /,b fi

8. M A X 8M UM A88YVALUE

' ^' 4 go, o, j.." 055 3,,,, ej,,,,,,,, .t.... ^ ",^ r ref.=neere), := -.-.a,,,,,19,,,,,,,, .. i.i..... g,,,,, pja,,,,,,s i.i.... m 3,,,319,,,,,,,, i,,.... ^"s^# = Avion. v ads,vmidsp4 x (24953-67 9) ", -. u.w tMChlorine,4 tart T6til flesiduelt x 04 04 0A in mdL 1%=.%.us end hC5hYh X w.sth i; ct)FocdMfM C,*ltfirm h~ Jg X ,+.n.v-6 Flui.eIdeYigc! X ( t 198 4248,-8. ),", a.n.

f. Nitrate %O I NItrits (en N)'Q.

Xs ~.a-o ,i EPA Form 3S10-2C (Rev. 2-85) . -;,,,,,dri c PAGE V-I CONTINUE ON ftCVERSE t_ e . e..# t .s, _ i.___,_-_ _ _ _ _ _ _ _ _ _ _ _ _ _ __ _ - - - - - _ _ _ - - - - -

- Es 0079057 outran 006 tTEM V 8 CONTINUED FROM FRONT

2. M Asa n x.
3. EFFLUENT
4. U N ITS
5. INT AK C fufsti.eno!)
1. POLt.UT, d no.or,mg A ho y / A"g g h m.w JEE "'"^*'"""U^'**V^'"'

'"^X 5ff NO) vaLue, c.Loe4G Tgtujyg. v ALu c M ^ ^ C SNO. M'"A,oEt,,,,4,*),,,,,,, ,,,.g g,3...p, ,,g,, g),.,.,,,g.,4 g,g h,,,,,,,4,gc,p);;v;g,,.,,g,g,,,, ^ ",^ 7 . TH AMN is) ama se v5 h(t/ eyedhMejy y g . [" C ont e o m A Tsoas 1

g. Nitrogenfipp Tetal Orsenic fas Np;e., *Aw;.

X NOliandpge) Oressagg7s{ y

l. Phoephorus.,

(as PJ, Toast (7723-14 0) ' x fyA". w . w.$d.q ;4cs ' yW 99 p474s 44gyg/pg,eijn g4pf.c ;y,., ..g m. ,3, <w n g,.., s

j. R adioacttwityr f +;-ra t ?.M.

+- (1).%Ipha.hMT ' ' ' ' ~ Tsungqqrf y 'r 4 X (3)$nediump: D X (4)18tediu r-22QTatal y a s a.-nm kg Sulfite : .g, (ee bog [~R i, X (14eos.794)'. t.'Cufflde .c (du 3 %.a. m? X m,$ulfite (en'80,9 g (1423 4 )h X i ..__..,1 Q, _3Gifecteds nt .<at W" g X p saluminum. -! ~ -l, U:s x r p,Berium, % D {y* \\' x w e soron, E s 7ot. p X (7440 24

r. C.abelt, 3
  • Tar 4

h744,, D. X s*.froni. Total (743).09-6) x uhwa e e ,t. Magneetum.) b h X t y

u. M ikytxsonum.

Tatl #.LW'A I7439 98D)T<- X .. um-

  • 7 6

X ~ wUnn,vTotetg (7400-314)g %--un X m., Titanium, g, h*t7440-324h$' a tIIc nsk's X PAcev-z CONTtMUE ON PACE V-3 _ '_ EPA Form 3510-2C (Rev. 2-85) I~ -c -%._. t,...e c%.,,__________ _. _ _ _ _ _ _ _. _ _ _ _ _, _ _ _, _

y F~~ ~ ""~ ~ " " " " * - * - - " M1 Essential Service Yater System discharg( s -+: Enclosure to NA 93-0216 at Era s.o. NUMBEM (copy from liem ) of form JJ OUTf' ALL NUMEE H D* r. Form Approved 3 '. .t. 006 3

  • 8
  • mm88 CONT:NuEo rnOM PACE 3 OF FORM 7-C PART C - If you are a primary industry and this outf all contains process wastewater, refer to Teble 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark
  • X"in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals cyanides, and total phenots. If you are not required to mark column 2-a (secondaryindustries, nonprocess wastewater outta//s. andnonicqmred GC/AfS tractionsf, mark ~X"in column 2.b for each po!!utant you know or have reason to believe is present. Mark ~X""in column 2-c for each pollutant you believe is absent. If you mark column 2a for any potrutant. you must provide the results of at least one analysis for that postutant. If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant il you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrotem. acrylonitrile. 2.4 darutrophenot, or 2 methyl-4. 6 dinitrophenot, you must provide the results of at least one analysis for each of these pollutants wh ch you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mar k column 2b. you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that thoro are 7 pages to this part; please review each carefully. Complete one tablo fa// 7 pagesJ for each outfall. See instructions for additional details and requirements.
1. POLLUTANT
2. M a esu *x*
3. E FFIMNT
4. UNITS
5. I N T A M C (oferieuwff NUMDEI

" '!,' ' I, " * *,j,",",",

n. M AxlMUM D ABLY V ALUE I** " ^ ^ %$,dh '-
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vses METALS. CYANtDE, AND TOTAL PHENOLS 1M. Antimony,, C.t.,(7440-36. >0) ; Tau... - v A 2M7AYodn'lc)Totat: (

  • t a.7440-38 2.)/.+ML X

a. u. 3MiB'aryttlum*,F1 .Tatst.47440.4137)A. v- .g w A . w. s p. ~ '4M3Cadrniu'r'n%f5 3*W12.1333 X 5M2Chio'mlum% r v2 2.r.x.w.7 3,) s X. Tat a.(7440-4 *, 8M. Capper TatalS. .p444,668)p @Q X .s.-

7M'INTotal.QyW

-4 f$ ..(7.~439-921.)(U &. X 8MMarc5r7fTotot ^ J7439 97-6.)p++e. .s X W m a. YMYNEkTI,$Totat$ k$#.g;O,,2,gggg X liDM7AEIEI'u'm L.t.z.117722 49-2).J' X- -~- Tr . ews ' Yh's?st@er2 Tot'at; 440..22'4).*N' a rl X 7 y ao. as (1'25t.$Th'a$tlNn.W.'S Tatti;(74f.0-20-0)".i X t1'3El?Ztrki.iTotalI -. 440-66.-6. )'.;4 A.l'f (7 Y U n INMICy'entd',W i e rayg,7-22;s)i,Q X (155tifFEts,yy ?TetaR$4Wlp:. X O!O/'NO w w: 9 N e. %,; w e y W.r W u-s.m.a + o *. W ":Wf o.r.4.';W e.t. A s.9 ef .:.i, wp,,ws-p.vt.~s 2.3.V ' c a. oEscuouE utsutTs .chlorods - .-J Dionin (17i,3 ,-6) X EPA Form 3510-2C (Hev. 2-85) . P A G E V.3 CONTINUE ON Rt.VEftSE ____.._._?..-_.-. -.A.:.iv-2-mO-09=JL.-. OE-k E-1 d 8-2 a- - I - - mbmd e - - - _ =. - ~

CONTINUED FROM THE FF10NT I. POLLUTANT

2. M A n u *x*

s -* V-s

3. C FfLU CNT
4. UNITS
5. I N T A K C (optionof f b.w.m u,atyogg)

,gepay,jjf. V AN st.N o. o,.r 3 v VAwt noN' T***' t C 3 $ cy,0y;. T E " U 1 C s.k. a. s -..e... st MnxtuuM D Atty V ALUE t ,, co g g gg, .m 3- - y3LUE u, u,33 ,,,,t. ret e.ea tar) og. i."U .".L,,,,,,68....,,, til-a.. ,,,,,h8,,,,,,,,, M--.. ,,,,,, h8,,,,, o., t t -a.. vses ' " ^ * " l * !,'Tl *,",-- t>I--.. vus CC/MS F RACTION - VOLATILE COMPOUNDS 1V, AcroleM (to7 o2c)g y j 2V.9 Xcrytonitrite' ; (1,0,713;1gy.+, y y 38%enieneiin ** * (7.14@2)pppsw y / AVy t ts (CMoro-r.- m:thyl) Ether Q

  • X cs42 s ui)u.- s svfo/o' ofo'r;nu, *.

x m (?s:2H2ijggj,3 CV.Ccebon W : .htrechtJride 'a A ' y v (66-23-5) b -M' ^ 7V.' Chlorobenzene (108-90-7);.qs;{.l X TV. Chlorods-w., be : momethane T.- v = (12 '.-48 1) * ** A Ev.* Chloroethane (7,S-00..3) rg= s.. : X 3. 10V.-2-Chloro. eg : rthylvanyt Ether v v (110-75-31). A 11V.IChloroform ( 17,-66-3) ;f,y,,.'y' : X 12V Dichloro-g br;.momethene N' y^ (75 27-4)-' 13V. Dichloro-es., def broomethene U ~ y (,5-71-0) e%< + * ^ 4_ 14VM1l1'-Dichloro-wthene..(.7 5 34.-3) ;; y .15',f.' (2'-D ic ht'orol cth/ste,(1,07-OG-2); y (1XV3.1',17dichtdrol

- p g thylene',(75-35-4),*

y ,NN1'.SDich5r'o2 progne.(7847-5); y }1SV.1.3-DNV f i .prappena(542-75 6).g v .e. A '1 LV.t E t'h'y lbenz ene i .( 100-41 -4) p p.p g y ?,2 tVYM 'th'ylf6".I; . prom.td.%--.83,-9), )(74 V s.~u A 31V' M 'th$r'SiO i Chlorld ?,,(74-87-3)' y EPA Form 3510-2C (Rev. 2-85) PAGE V 4 CONTINUE ON PAGE V-5

.....n.. ...,.....a, - s 1 arm Approved i ~ ss"'kn.o.667907) copy frans item I of Foran s) meEen % e t'As.L uuu un n 0%iSNo 20404086 s 005 appr~1e+n 7 3i.ss CONTINUFO Ff10M PACF V4 6

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a. CONCEN-A E A VALUE a n a t.

ta u Ass A N a t.- T a ^T'o" M ff,-*, -- i.i-.. vsts. CC/MS FRACT ON - VOLATit.E COMPOUNDS (contiances) 22V. Mithytow - Chloride (7,5 09 2). y 23 V.s 1,1,2,2.T e tsa, chloroethane r m (78 34-51 taa.dMh X 24V.*Tgtrachloro4 e.th. ylen.e.(.127_..18.4) X r. 25'VATEI'usne %.'-d (108.C.. 3)etV.,,Y X ... 4 r 26V.,1.2-Trans.ics Olchlorosthylene 7 (156-60 5)M-@,C ~X 27V..1,1,1 Tal-t'en chloroethanegg4 X (71-554) s.u~ - L 2Avv 1.1,2,T ri-O% M chloretthone*dG X (73-COL 5 ) si,2( 29VdTrichloro-$$ e.thyl.e.n..e.+-(.794,31.-6..) ',. V' A 30V Trichloro-ttuoromethane '.. ' (75-634.) vJ4 d X 31V!Vinytt? Md Chlorlds,(75-01-4)

  • X CC/MS FRACTION - ACIO COMPOUNDS >w.h< > cw F-v.-

G- -a - w en-* N- - 7 1K 2-Chlorophenol (M,57,8) *g.@.g y 2hl2.4-Olchtoro-M ph.eno.L.(120.83-2)] .X 3AS2'4 OEethyl-2 ~ phe..n.ol (t,05-67 9. ),? 1 v ~ o .1 A 4AT4'.6-Olnit'r'o-OO C_.r.,i. sol..(.33.4. 52.t.).L. 1 v A 5M.2.'4' Olnit'roys" ph_en. ol,s(51-28 5. )1t CA72'-Nit $pE5M1I - ~ ~ (apyp:51,wrMi X 7#44Gsph'enoi; 1100:02 9 5 @ i0 X 2ATP Chloro-M 'P, -Cresol.(.39-50-7.) %-3 X- --~ e. $ALPentschforo.*f phenot (87. 86 5)di X r p.. itA*Ph'e' o'lY3/1Te dek& (i.o8.e-os,.2.)e M.? *R 11 A7 2,4,G-Tri-. -, chloropheot ;*Y (88-06-2) ' - X [_ EPA Form 3510-2C (Rev. 2-85) 3 PAGE V-5 CONTINUE ON 6tFVF st%F

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  • 220.1.4-Dichloro-

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3

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WATER TREATMENT CHEMICAL LIMITS TREATMENT CHEMICAL: BETZ C-74 System /Use Injection Point Injection Rate Discharge Point Approved Discharge Additional (Concentration) Concentration Information SW/ Molluscicide CWSH NA 003 s I ppm 24-hour treatments twice/ year ESW/ Molluscicide ESW Intake Bays 9 galsibay (50 ppm) 003/006 s 1 ppm from bay or 24-hour treatments outfall twice/ year CW/ Molluscicide CWSH Intake Bays 16.67 gals 1 bay 003 s I ppm from bay or 24-hour treatments (50 ppm) outfall twice/ eir 3 ESW/ Biocide . Heat Exchangers 5-20 galsiday 003 < 0.1 ppm Sample point in l (5-20 ppm) s I ppm Control Building 006 basement ESW/ Biocide Intake Bays 1-4 gals 115 min. 006 s I ppm Monthly pump tests (5-20 ppm) ESW/ Biocide Intake Bays 4-16 gals 11 hour / day 006 s I ppm Imng-term pump use (5-20 pprr0 ESW/ Biocide Control Building 0.7 - Le galsiday ESW Intake Bay s I ppm Lay-up conditions basement (5-10 ppm) l TREATMENT CHEMICAL: BETZ C '3P fBCDMH1 System /Use Injection Point Injection Rate Discharge Point Approved Discharge Additional (Concentration) Concentration Information SW/ Biocide CWSH 40 lbsiday 003 0.10 - 0.14 ppm TRO NPDES permit limits (0.20 ppm TRO) 006 0.20 ppm TRO are still 0.2 ppm TRO CW/ Biocide CWSH 66lbs/ day 003 s 0.06 ppm TRO for 003 and 1.0 ppm (0.06 ppm TRO) TRO for 006 TREATMENT CHEMICAL: BETZ 35-A System /Use Injection Point Injection Rate Discharge Point Approved Discharge Additional (Concentration) Concentration Information ESW Antiscalant ESW Heat Exchangers 6-12 gpd (10-20 ppm) 003 < 0.1 ppm Sampled in Control 006 s I pp'i Bldg. basement n ESW Antiscalant Control Building 0.9 - 1.7 gpd ESW Intake Bay 10-20 ppm Lay-up conditions (10-20 ppm) e

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2 TREATMENT CHEMICAL: BETZ WCNO4 System /Use Injection Point Injection Rate Discharge Point Approved Discharge Additional (Concentration) Concentration Information CW/Antiscalart CWSH 25-70 gpd (0.1 ppm) 003 NA Injection rate limited; no discharge limit applies SW/Antiscalant CWSH 3 gpd (0.05 ppm) 003 < 0.003 ppm 006 0.05 ppm TREATMENT CHEMICAL: BETZ COPPERTROL CU-l System /Use Injection Point Injection Rate Discharge Point Approved Discharge Additional (Concentration) Concentration Information SW/ Corrosion Inhibitor CWSH 30 galsfl5 minutes / day 003 2.4 - 3.3 ppm (60 ppm) OJG 50 ppm l { i l t~,.u_. .. s. i-

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1 i BETZ LABORATORIES,INC. 4636 SOMERTON ROAD, TREVOSE, PA. 19047 J BETZ MATERIAL SAFETY DATA SHEET 24 HOUR EMERGENCY TELEPHONE (HEALTH OR ACCIDENT) 215/355-3300 (PAGE 1 OF 3) PRODUCT : SLIMICIDE C-74 EFFECTIVE DATE 10-31-90 PRINTED: 27-Nov-1990 REVISIONS TO SECTIONS: 1; EDIT: APPENDIX /9 PRODUCT APPLICATION WATER-DASED MICROBIAL CONTROL AGENT.

SECTION 1---------

-HAZARDOUS INGREDIENTS--------------- INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD IS LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHRONIC HAZARDS OF THIS FORMULATION. ETHYLENE GLYCOL * * *CAS#107-21-1; LIVER, KIDNEY AND BLOOD TOXIN;CNS DEPRESSANT; ANIMAL TERATOGEN (HIGH ORAL DOSES) ;PEL/TLV:50 PPM-C. i ALKYL DIMETHYL BENZYL AMMONIUM CHLORIDE ***CAS#68424-85-1; CORROSIVE (EYES) ; .PEL:NONE;TLV:NONE. ISOPROPYL ALCOHOL (IPA)***CAS#67-63-0; FLAMMABLE LIQUID; CHRONIC OVEREXPOSURE MAY CAUSE LIVER AND KIDNEY TOXICITY;PEL/TLV:400 PPM (500 PPM-STEL). j DODECYLGUANIDINE HYDROCHLORIDE * * * ( DGH) ; CAS # 13590-97-1 ; CORROSIVE ; PEL: NONE ; TLV:NONE. j ETHYL ALCOHOL (ETHANOL) ** *CAS# 64-17-5: FLAMMABLE; EYE IRRITANT;MAY CAUSE DEFATTING DERMATITIS, DIZZINESS AND HEADACHE;PEL/TLV:1000 PPM.

S ECTION 2 -----------TY PI CA L PHYS I CAL DATA--------- ----------------

PH: AS IS (APPROX.) 5.3 ODOR: MILD FL.PT.(DEG.F): 116 SETA(CC) SP.GR. (70F)OR DENSITY: 1.022 . VAPOR PRESSURE (mmHG): 23 VAPOR DENSITY (AIR =1): >l VISC cps 70F: 23 % SOLUBILITY (WATER) : 100 EVAP. RATE: <1 ETHER =1 APPEARANCE: COLORLESS PHYSICAL STATE: LIQUID FREEZE POINT (DEG.F): <-30

SECTION.3-----------REACTIVITY DATA------------------------------

STABLE.MAY REACT WITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK CLEAN-OUT CATEGORY 'B' THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES.

7 BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3) l PRODUCT: SLIMICIDE C-74

SECTION 4-----------HEALTH HAZARD EFFECTS------------------------

ACUTE SKIN EFFECTS *** PRIMARY ROUTE OF EXPOSURE CORROSIVE TO SKIN. POTENTIAL SKIN SENSITIZER ACUTE EYE EFFECTS *** CORROSIVE TO THE EYES ACUTE RESPIRATORY EFFECTS *** PRIMARY ROUTE OF EXPOSURE VAPORS, GASES, MISTS AND/OR AEROSOLS CAUSE IRRITATION TO UPPER RESPIRATORY TRACT CHRONIC EFFECTS OF OVEREXPOSURE *** PROLONGED OR REPEATED OVEREXPOSURES MAY CAUSE: TISSUE NECROSIS; BLOOD CELL DAMAGE OR IMPAIR BLOOD CELL FUNCTION; REPRODUCTIVE SYSTEM TOXICITY; SKIN SENSITIZATION. MEDICAL CONDITIONS AGGRAVATED *** NOT KtK WN SYMPTOMS OF EXPOSURE *** INHALATION OF VAPORS / MISTS / AEROSOLS MAY CAUSE EYE, NOSE, THROAT AND LUNG IRRITATION; SKIN CONTACT MAY CAUSE SEVERE IRRITATION OR BURNS. PRECAUTIONARY STATEMENT BASED ON TESTING RESULTS *** MAY BE TOXIC IF ORALLY INGESTED.

SECTION 5------------FIRST AID INSTRUCTIONS----------------------

SKIN CONTACT *** REMOVE CLOTHING. WASH AREA WITH LARGE AMOUNTS OF SOAP SOLUTION OR WATER FOR 15 MIN.IMMEDIATELY CONTACT PHYSICIAN EYE CONTACT *** IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE *** REMOVE VICTIM FROM CONTAMINATED AREA. APPLY NECESSARY FIRST AID TREATMENT.IMMEDIATELY CONTACT A PHYSICIAN. INGESTION *** DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING.IMMED. CONTACT PHYSICIAN.DILUTF CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER

SECTION 6-----------SPILL, DISPOSAL AND FIRE INSTRUCTIONS---------

SPILL INSTRUCTIONS *** VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL. PLACE IN WASTE DISPOSAL CONTAINER.THE CONTAMINATED ABSORBENT SHOULD BE CONSIDERED A PESTICIDE AND DISPOSED OF IN AN APPROVED PESTICIDE LANDFILL.SEE PRODUCT LABEL STORAGE AND DISPOSAL INSTRUCTIONS. REMOVE IGNITION SOURCES. FLUSH AREA WITH WATER. SPREAD SAND / GRIT. DISPOSAL INSTRUCTIONS *** WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT (AS IS)- DISPOSE OF IN APPROVED PESTICIDE FACILITY OR ACCORDING TO LABEL INSTRUCTIONS FIRE EXTINGUISHING INSTRUCTIONS *** ~FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (FULL FACE-PIECE TYPE). PROPER FIRE EXTINGUISHING MEDIA: DRY CHEMICAL, CARBON DIOXIDE, FOAM OR WATER .i

n ~.. BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3) PRODUCT: SLIMICIDE C-74

SECTION 7-----------SPECIAL PROTECTIVE EQUIPMENT-----------------

i USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS. VENTILATION PROTECTION *** ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOMMENDED RESPIRATORY PROTECTION *** IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE & DUST / MIST PREFILTER RECOMMENDED SKIN PROTECTION *** GAUNTLET-TYPE RUBBER GLOVES, CHEMICAL RESISTANT APRON WASH OFF AFTER EACH USE. REPLACE AS NECESSARY RECOMMENDED EYE PROTECTION *** SPLASH PROOF CHEMICAL GOGGLES. FACE SHIELD i

SECTION 8-----------STORAGE AND HANDLING PRECAUTIONS-------------

STORAGE INSTRUCTIONS *** KEEP DRUMS & PAILS CLOSED WHEN NOT IN USE. STORE IN COOL VENTILATED LOCATION. STORE AWAY FROM OXIDIZERS HANDLING INSTRUCTIONS *** COMBUSTIBLE. DO NOT USE AROUND SPARKS OR FLAMES. BOND CONTAINERS DURING FILLING OR DISCHARGE WHEN PERFORMED AT TEMPERATURES AT OR ABOVE THE PRODUCT FLASH POINT. f THIS MSDS COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD l HAROLD M. HERSH (ENVIRONMENTAL INFORMATION COORDINATOR) APPENDIX: REGULATORY INFORMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE. ANY CHANGES'IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. ...TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY ...FIFRA(40CFR): EPA REG.NO. 3876-145 ... REPORTABLE QUANTITY (RQ) FOR UNDILUTED PRODUCT: NOT APPLICABLE ... RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE,THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS: D001= IGNITABLE;D002= CORROSIVE (SKIN) ... DOT HAZARD /UN#/ER GUIDE # IS: CORROSIVE TO SKIN. COMBUSTIBLE UN1760/#60 ...THIS PRODUCT CONTAINS THESE CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY: NONE PRESENT IN SIGNIFICANT AMOUNTS ... SARA SECTION 302 CHEMICALS: NONE PRESENT IN SIGNIFICANT AMOUNTS ... SARA SECTION 313 CHEMICALS: ETHYLENE GLYCOL (107-21-1) 21.0-30.0% ; ... SARA SECTION 312 HAZARD CLASS: IMMEDI ATE ( ACUTE ), DELAYED ( CHRONIC) AND FIRE ... MICHIGAN CRITICAL MATERIALS: NONE PRESENT IN SIGNIFICANT AMOUNTS NFPA/HMIS : HEALTH - 3 ; FIRE - 2 ; REACTIVITY - 0 ; SPECIAL - CORR ; PE - D

BETZ LABORATORIES,INC. 4636 SOMERTON ROAD,TREVOSE,PA.19047 PRODUCT: SLIMICIDE C-74 1/22/91 AQUATIC TOXICOLOGY l RAINBOW TROUT 0% MORTALITY: 10 MG/L 96 HR. LC50: 14.7 MG/L DAPHNIA MAGNA 0% MORTALITY: 0.16 MG/L 48 HR. LC50: 0.4 MG/L FATHEAD MINNOW 0% MORTALITY: 1.55 MG/L 96 HR. LC50: 3.0 MG/L 1/22/91 MAMMALIAN TOXICOLOGY ORAL LD50 - RAT 3270 MG/KG DERMAL LD50 - RAT 9999.0 MG/KG SKIN IRRITATION SCORE-RABBIT 5.1 EYE IRRITATION SCORE-RABBIT 103 INHALATION-NO DATA i l

~ BETZ LABORATORIES,INC. 4636 SOMERTON ROAD, TREVOSE, PA. 19047 BETZ MATERIAL SAFETY DATA SHEET 24 HOUR EMERGENCY TELEPHONE (HEALTH OR ACCIDENT) 215/355-3300 (PAGE 1 OF 3) PRODUCT : BETZ 35A EFFECTIVE DATE 01-10-90 PRINTED: 10-Jan-1990 REVISIONS TO SECTIONS: 4, APPENDIX /9 PRODUCT APPLICATION : WATER-BASED CORROSION INHIBITOR / DEPOSIT CONTROL AGENT.

SECTION 1-----------HAZARDOUS INGREDIENTS---------------

INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD IS LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHRONIC HAZARDS OF THIS FORMULATION. THIS PRODUCT IS NOT HAZARDOUS AS DEFINED BY OSHA REGULATIONS. i I i

SECTION 2---~~~~----TYPICAL PHYSICAL DATA-------------------------

PH: 5% SOL. (APPROX.) 13.0 ODOR: NONE FL.PT.(DEG.F): >200 SETA(CC) SP.GR. (70F)OR DENSITY: 1.729 VAPOR PRESSURE (mmHG): ND VAPOR DENSITY (AIR =1): ND VISC cps 70F: 78 % SOLUBILITY (WATER) : 100 EVAP. RATE: <1 ETHER =1 APPEARANCE: PALE YELLOW PHYSICAL STATE: LIQUID FREEZE POINT (DEG.F): <-30

SECTION 3-----------REACTIVITY DATA------------------------------

STABLE. BETZ TANK CLEAN-OUT CATEGORY 'A' THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES.

BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3) PRODUCT 2 BETZ 35A

SECTION 4-----------HEALTH HAZARD EFFECTS------------------------

ACUTE SKIN EFFECTS *** PRIMARY ROUTE OF EXPOSURE SLIGHTLY IRRITATING TO THE SKIN ACUTE EYE EFFECTS *** MODERATELY IRRITATING TO THE EYES ACUTE RESPIRATORY EFFECTS *** MISTS / AEROSOLS MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT CHRONIC EFFECTS OF OVEREXPOSURE *** NO EVIDENCE OF POTENTIAL CHRONIC EFFECTS. . MEDICAL CONDITIONS AGGRAVATED *** NOT KNOWN SYMPTOMS OF EXPOSURE *** MAY CAUSE REDNESS OR ITCHING OF SKIN.

SECTION 5------------FIRST AID INSTRUCTIONS----------------------

SKIN CONTACT *** REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MINUTES EYE CONTACT *** IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE *** REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR. APPLY APPROPRIATE FIRST AID TREATMENT AS NECESSARY INGESTION *** DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING.IMMED. CONTACT PHYSICIAN. DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER

SECTION 6-----------SPILL, DISPOSAL AND FIRE INSTRUCTIONS---------

SPILL INSTRUCTIONS *** VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL. PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATFRIAL,OR ANY CONTAMINATED SOIL,_ SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS. CONTAMINATED AREA MAY BE WASHED DOWN WITH WATER. DISPOSAL INSTRUCTIONS *** WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT, A l PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT (AS IS)- INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS *** FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (FULL FACE-PIECE TYPE). PROPER FIRE EXTINGUISHING MEDIA: DRY CHEMICAL, CARBON DIOXIDE, FOAM OR WATER

BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3) PRODUCT: BETZ 35A

SECTION 7-----------SPECIAL PROTECTIVE EQUIPMENT-----------------

USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS. VENTILATION PROTECTION *** ADEQUATE VENTILATION RECOMMENDED RESPIRATORY PROTECTION *** IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH DUST / MIST FILTERS. RECOMMENDED SKIN PROTECTION *** RUBBER GLOVES WASH OFF AFTER EACH USE. REPLACE AS NECESSARY RECOMMENDED EYE PROTECTION *** SPLASH PROOF CHEMICAL GOGGLES

S ECTION 8 --------- --STORAGE AN D HANDLING PRECAUTIONS-------------

STORAGE INSTRUCTIONS *** KEEP DRUMS & PAILS CLOSED WHEN NOT IN USE. PROTECT FROM FREEZING HANDLING INSTRUCTIONS *** ALKALINE.DO NOT MIX WITH ACIDIC MATERIAL. r THIS MSDS COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD HAROLD M. HERSH (ENVIRONMENTAL INFORMATION COORDINATOR) APPENDIX: REGULATORY INFORMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE. ' ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. ...TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY a ... CLEARANCE FOR POTABLE WATER USE: j EPA UP TO 28 PPM-ALSO OHIO-30 PPM & FLORIDA l ... REPORTABLE QUANTITY (RQ) FOR UNDILUTED PRODUCT: ) NOT APPLICABLE i ... RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE,THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS: D002= CORROSIVE (PH) { ... DOT HAZARD /UN#/ER GUIDE # IS: NOT APPLICABLE ...THIS PRODUCT CONTAINS THESE CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO l CAUSE CANCER OR REPRODUCTIVE TOXICITY: NONE PRESENT IN SIGNIFICANT AMOUNTS i ... SARA SECTION 302 CHEMICALS: NONE PRESENT IN SIGNIFICANT AMOUNTS l ... SARA SECTION 313 CHEMICALS: NONE PRESENT IN SIGNIFICANT AMOUNTS I ... SARA SECTION 312 HAZARD CLASS: PRODUCT IS NONHAZARDOUS UNDER SECTION 311/312 ... MICHIGAN CRITICAL MATERIALS: NONE PRESENT IN SIGNIFICANT AMOUNTS NFPA/HMIS : HEALTH - 1 ; FIRE - 1 ; REACTIVITY - 0 ; SPECIAL - ALK

PE - B l

I I h L

j ) BETZ LABORATORIES,INC. 4636 SOMERTON ROAD,TREVOSE,PA.19047 PRODUCT: BETZ 35A 1/22/91 AQUATIC TOXICOLOGY BLUEGILL SUNFISH i 0% MORTALITY: 500 MG/L 48 HR. SCR. l 1/22/91 IMMMALIAN TOXICOLOGY ORAL LD50 -NO DATA DERMAL LD50 -NO DATA SKIN IRRITATION SCORE-NO DATA EYE IRRITATION SCORE-NO DATA INHALATION-NO DATA OXYGEN DEMAND (ppm) PRODUCT CONCENTRATION (ppm) BOD COD TOC 1000 o o o l I

( BETZ LABORATORIES,INC. 4636 SOMERTON ROAD, TREVOSE, PA. 19053 BETZ MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE (HEALTH / ACCIDENT) 800-877-1940 (PAGE 1 OF 3) PRODUCT : BIO-TROL 88P EFFECTIVE DATE:08-26-93 PRINTED: 08-26-93 j PRODUCT APPLICATION: SOLID MICROBIAL CONTROL AGENT.

SECTION 1-----------HAZARDOUS INGREDIENTS---------------------------

l l INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC l PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD IS LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHRONIC HAZARDS OF THIS FORMULATION. 1-BROMO-3-CHLORO-5,5-DIMETHYLHYDANTOIN***CAS# 16079-88-2; OXIDIZER; EYE AND SKIN IRRITANT; PEL:NOT DETERMINED;TLV:NOT DETERMINED: NOTE-MANUFACTURER'S RECOMMENDED LIMIT:0.2MG/M3 l 1 i i l I l

SECTION 2-----------TYPICAL PHYSICAL DATA--------------------------

PH: 5%' DISP.(APPROX.) 4.7 ODOR: SLIGHT -FL.PT.(DEG.F):) 200 P-M(CC) DENSITY:NO DATA VAPOR PRESSURE (mmHG): < 1.0 VAPOR DENSITY (AIR =1): < 1.00 VISC cps 70F: NA % SOLUBILITY (WATER): 0.2 EVAP RATE: < 1.00(ETHER =1) APPEARANCE: WHITE PHYSICAL STATE: GRANULES FREEZE POINT (DEG.F): NA

SECTION 3-----------REACTIVITY DATA--------------------------------

STABLE. OXIDIZER. SLOWLY RELEASES HALOGEN GASF.S WHEN CONTAMINATED WITH MOISTURE. MAY REACT WITH ALKALIES, ACIDS, ORGA?1ICS OR REDUCING AGENTS. DO NOT CONTAMINATE. BETZ TANK CLEAN-OUT CATEGORY 'b'. l THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES.

BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3) PRODUCT : BIO-TROL 88P

SECTION 4---------HEALTH HAZARD EFFECTS---------------------------

PRIMARY ROUTE OF EXPOSURE ACUTE SKIN EFFECTS MODERATELY IRRITATING.MAY BE CORROSIVE IN CONTACT WITH MOIST SKIN. ACUTE EYE EFFECTS SEVERE IRRITANT TO THE EYES ACUTE RESPIRATORY EFFECTS DUSTS CAUSE IRRITATION TO UPPER RESPIRATORY TRACT CHRONIC EFFECTS OF OVEREXPOSURE *** NO EVIDENCE OF POTENTIAL CHRONIC EFFECTS. ' MEDICAL CONDITIONS AGGRAVATED NOT KNOWN SYMPTOMS OF EXPOSURE *** MAY CAUSE REDNESS OR ITCHING OF SKIN. PRECAUTIONARY STATEMENT BASED ON TESTING RESULTS MAY BE TOXIC IF ORALLY INGESTED.

SECTION 5-----------FIRST AID INSTRUCTIONS-----------------------------

SKIN CONTACT *** REMOVE CLOTHING WASH AREA WITH LARGE AMOUNTS OF SOAP SOLUTION OR WATER FOR 15 MIN.IMMEDIATELY CONTACT PHYSICIAN EYE CONTACT *** IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE *** REMOVE VICTIM FROM CONTAMINATED AREA. APPLY NECESSARY FIRST AID TREATMENT.IMMEDIATELY CONTACT A PHYSICIAN. INGESTION *** DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING.IMMEDIATELY CONTACT PHYSICIAN. DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER

SECTION 6-----------SP7LL, DISPOSAL AND FIRE INSTRUCTIONS-----------

SPILL INSTRUCTIONS *** VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT. SPILLED MATERIAL WHICH CAN NOT BE RECOVERED FOR RE-USE,SHOULD BE PLACED IN A WASTE DISPOSAL CONTAINER AND DISPOSED OF IN AN APPROVED PESTICIDE LANDFILL.SEE PRODUCT LABEL STORAGE AND DISPOSAL INSTRUCTIONS. PRODUCT RELEASES CHLORINE WHEN WET. SPILL RESIDUE MAY BE NEUTRALIZED WITH 3% HYDROGEN PEROXIDE SOLUTION. DISPOSAL INSTRUCTIONS **** WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT (AS IS)- DISPOSE OF IN APPROVED PESTICIDE FACILITY OR ACCORDING TO LABEL INSTRUCTIONS FIRE EXTINGUISHING INSTRUCTIONS *** FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (FULL FACE-PIECE TYPE). PROPER FIRE EXTINGUISHING MEDIA: FLOOD WITH WATER.USE OF CO2 OR FOAM MAY NOT DE EFFECTIVE.

BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3) PRODUCT : BIO-TROL 88P --- -SECTION 7-----------SPECIAL PROTECTIVE EQUIPMENT------------- USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134.USE RESPI'AATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS. VENTILATION PROTECTION *** ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOMMENDED RESPIRATORY PROTECTION *** IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE RESPIRATOR WITH ACID GASSES CARTRIDGES AND DUST / MIST PREFILTERS RECOMMENDED SKIN PROTFC210N*** GAUNTLET-TYPE RISBER GLOVES, CHEMICAL RESISTANT APRON WASH OFF AFTE". EACH USE REPLACE AS NECESSARY. RECOMMENDED EYE PROTECTION *** AIRTIGHT CHEMICAL GOGGLES

SECTION 8-----------STORAGE AND HANDLING PRECAUTIONS-----------------

STORAGE INSTRUCTIONS *** KEEP CONTAINERS CLOSED WHEN NOT IN USE. KEEP DRY. DO NOT STORE AT HIGH TEMPERATURE OR NEAR OXIDIZABLES OR COMBUSTIBLES HANDLING INSTRUCTIONS *** OXIDIZER. AVOID ALL CONTACT WITH REDUCING AGENTS, OILS, GREASES, ORGANICS AND ACIDS. THIS MSDS WAS WRITTEN TO COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD APPENDIX: REGULATORY INFORMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE. ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. ...TSCA: THIS IS AN EPA REGISTERED BIOCIDE AND IS EXEMPT FROM TSCA INVENTORY REQUIREMENTS ...FIFRA(40CFR): EPA REG.NO.: 5785-57-3876 ... REPORTABLE QUANTITY (RQ) FOR UNDILUTED PRODUCT: NOT APPLICABLE ... RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE,THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS:D001= IGNITABLE ... DOT HAZARD /UN#/ER GUIDE # IS :0XIDIZER/UN1479/#35 ... CALIFORNIA SAFE DRINKING WATER ACT (PROPOSITION 65) MATERIALS:NONE l ... SARA SECTION 302 CHEMICALS:NONE ... SARA SECTION 313 CHEMICALS:NONE ... SARA SECTION 312 HAZARD CLASS:IMMEDIATE(ACUTE); FIRE ... MICHIGAN CRITICAL MATERIALS: NONE NFPA/HMIS : HEALTH - 2; FIRE - 1; REACTIVITY - 1; SPECIAL - OXY ; PE - C i

B2 LES[l%$ M Industri'.I p. J~ ~ p. p l H I I I V vV V BETZ3 Bio-Trol" 88P MICROBIOCIDE EPA Reg No. 5785 57 3876 . brewery pasteurizers . Fast dissolving granular form . industrial air washer systems equipped with a mist eliminator under agitation . High concentration of actives . influent water systems, such as flow through filters . Rapidly generates effective halogen concentrations and lagoons . Effective on bacterial, fungal, and algal fouling , industrial water scrubbing systems . Long-lasting, controlled-protection biocide release TREATMENT AND FEEDING REQUIREMENTS DESCRIPTION A.ND USE In large r applications, a by-pass f e ede r is recomme nded to achieve consistent product residuals throughout the BetzBio-Trol 88Pisaneffective broad spectrummicro-biocide in a concentrated 9rar$ular form. The product system. Belz off ers a full range of feeder systems for ap-plying Bio-Trci 88P. For small systems, Betz Bio-Trol contains active bromine and chlorine.in a stabilized 88 P can be fed directly to the cooling water, pasteurizer, form; they are released into the water,n a controlled i or airwashe r by means ol a plastic or stainless ste el feed fashion as the granules dissolve. Bromine and chlorine device, such as a mesh bag or perforated container that work together to provide effective control for a broad rovides gradual dissolution. spectrum of slime forming organisms. By controlling slime accumulations, Bio Trol 8S P a!!ows cooling towe rs Proper treatment levels for Betz Bio-TrolB8P depend on and heat exchangers to cperate at peak efficiency and many f actors such as the nature and degree of severity reduces the tendency for microbiologically induced cf the microbial proble m, syste m rete ntion time, te mper-corrosion (MIC.) ature, and othe r ope rating conditions. Typically, e nough Betz Bio-Trol 88 P is added to t he system to achieve a 2-3 Bio Trol 88P is panicularly well-suited for applications mg/L total halogen residualin the water for 14 hr daily. that require shock desing. For example, the rapid disso-For best results, your Betz Industrial representative will lution rates typicalof this product make possible cost ef-determine the proper dosage forthe specific system and fective biofouling control of utility surface condensers the prcblem to be treated. without exceeding total residual oxidant discharge limits. In all cases, the product must be applied in accordance with the use instructions on the Betz Bio Trol 88P Betz Bio Trol 88P may be used alternately with other product label. BetzO Slimicides to improve overall program effective-ness by reducing the development of microorganism GENER AL PROPERTIES strains that become resistant to a single biocidal agent. Bio-Trol 88P is registered with the Environmental Pro. Bromo chloro hydanto.in ........ 9 6.0% tection Agency for the controlof bacterial, fungal, and al-Inert Ingredients . 4.0% gal slimes. Bio-Trol 88P can be used in: Appearance .. white granules 2 3 . commercial and industrial cooling towcrs Bulk Density 64.5 lb!!! (1033 kg/m ) . once through and closed-cycle fresh and sea water Solubility.. 1% cooling systems pH (5% dispersion). . 4.7 l l PFC s23 n0a O1903 EETZ INcOSTrUAL ALL TUGHTS riEsERVEo. O FRWTEDIN USA l

ENVIRONMENTAL INFORMATION Dehalogenated Product (5,5 dimethylhydantoln)- Aquatic Toxicology Information-Daphnia magna 48 hr LC 50: 1266 mg'L f Rainbow trout: 96 hr static acute bioassay-Fathead minnow: 96 hr LC50: 7890 mg'L l LC50: 0.85 mg'L Rainbow trout: 96 hr LC50: 5940 mgt Fathead minnow: 96 hr static acute bioassay-Grass shrimp: 96 hr LC50: 11,688 mgt LC50: 2.19 mg'L Sheephead minnow:96 hr LC50: 12,954 mg/L h Daphnia magna: 48 hr static acute bioassay-l LC50: 0.45 mg'L American cyster: 96 hr LC50: 13,830 mot Sheephead minnow: 96 hr static acute bicassay S AFETY PRECAUTIONS LC50:19.5 mgt Grass shrimp: 96 hr static acute bioassay-A Material Safety Data Sheet containing detailed infor-LC50: 12.66 mg'L mation relative to this product is available upon request. l American oyster: 96 hr static acute bioassay-PACK AGING INFORMATION LC50: >623 mg'L Two Hour Deily Applicatico Betz Bio-Trol 88P comes in granular form. It is available in a wide variety of customized containers and delivery 8 hr C50166 mg'L thods. Contact your Betz Industrial representative for T id o idi Rainbow trcot: 06 hr LC50: 1.17 mg'L Totai residual oxidizer: 0.50 mg/L /,,,......,'%, l$ 900) )' I I l l l 'PMo2 PFC 523 9%8

BETZ LABORATORIES,INC. 4636 SOMERTON ROAD, TREVOSE, PA. 19047 BETZ MATERIAL SAFETY DATA SHEET 24 HOUR EMERGENCY TELEPHONE (HEALTH OR ACCIDENT) 215/355-3300 (PAGE 1 OF 3) ) PRODUCT : COPPER-TROL CU '. EFFECTIVE DATE 05-25-90 PRINTED: 27-Nov-1990 REVISIONS TO SECTIONS: 4 PRODUCT APPLICATION : WATER-BASED CORROSION INHIBITOR.

SECTION 1-----------HAZARDOUS INGREDIENTS---------------

INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD IS LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHRONIC HAZARDS OF THIS FORMULATION. SODIUM HYDROXIDE ***(CAUSTIC SODA)***CAS#1310-73-2; CORROSIVE; TOXIC IF ORALLY INGESTED;PEL:2.0MG/M3;TLV:2.0MG/M3(CEILING). BUTYL BENZOTRIAZOLE, SODIUM SALT ***CAS#18685-34-0; POTENTIAL SKIN SENSITIZER; CORROSIVE TO SKIN AND EYES;PEL:NONE;TLV:NONE. NOTE-NOT ON ANY STATE RTK LIST. x

SECTION 2-----------TYPICAL PHYSICAL DATA-------------------------

PH: AS IS (APPROX.) 13.5 ODOR: MILD FL.PT.(DEG.F): >200 P-M(CC) SP.GR. (70F)OR DENSITY: 1.184 VAPOR PRESSURE (mmHG): 18 VAPOR DENSITY (AIR =1): <1 VISC cps 70F: 37 % SOLUBILITY (WATER) : 100 EVAP. RATE: <1 ETHER =1 APPEARANCE: BROWN-BLACK PHYSICAL STATE: LIQUID FREEZE POINT (DEG.F): -4

SECTION 3-----------REACTIVITY DATA------------------------------

STABLE.MAY REACT WITH ACIDS.DO NOT CONTAMINATE. BETZ TANK CLEAN-OUT CATEGORY 'C' THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES.

.. ~ BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3) PRODUCT: COPPER-TROL CU-1

S ECTION 4 -----------H E A LTH HA Z ARD E F FECTS --------- - --------------

ACUTE SKIN EFFECTS * *

  • PRIMARY ROUTE OF EXPOSURE CORROSIVE TO SKIN. SKIN SENSITIZER ACUTE EYE EFFECTS ***

CORROSIVE TO THE EYES ACUTE RESPIRATORY EFFECTS *** MISTS / AEROSOLS CAUSE IRRITATION TO UPPER RESPIRATORY TRACT CHRONIC EFFECTS OF OVEREXPOSURE *** PROLONGED OR REPEATED CONTACT MAY CAUSE TISSUE NECROSIS, DERMATITIS AND/OR SKIN SENSITIZATION. . MEDICAL CONDITIONS AGGRAVATED *** NOT KNOWN SYMPTOMS OF EXPOSURE *** ,CAUSES SEVERE IRRITATION, BURNS OR TISSUE ULCERATION WITH SUBSEQUENT SCARRING. PRECAUTIONARY STATEMENT BASED ON TESTING RESULTS *** KAY BE TOXIC IF ORALLY INGESTED.

SECTION 5------------FIRST AID INSTRUCTIONS----------------------

SKIN CONTACT *** REMOVE CLOTHING. WASH AREA WITH LARGE AMOUNTS OF SOAP SOLUTION OR WATER FOR 15 MIN.IMMEDIATELY CONTACT PHYSICIAN EYE CONTACT *** IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE *** REMOVE VICTIM FROM CONTAMINATED AREA. APPLY NECESSARY FIRST AID TREATMENT.IMMEDIATELY CONTACT A PHYSICIAN. INGESTION *** DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING.IMMED. CONTACT PHYSICIAN. DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER

SECTION 6-----------SPILL, DISPOSAL AND FIRE INSTRUCTIONS---------

SPILL INSTRUCTIONS *** VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL. PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL, SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS. FLUSH AREA WITH WATER. WET AREA MAY SE SLIPPERY. SPREAD SAND / GRIT. DISPOSAL INSTRUCTIONS * *

  • WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT (AS IS)-

INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS *** FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (FULL FACE-PIECE TYPE). PROPER FIRE EXTINGUISHING MEDIA: DRY CHEMICAL, CARBON DIOXIDE, FOAM OR WATER

a. BETZ MATERIAL SAFETY DATA SEEET (PAGE 3 OF 3) p PRODUCT: COPPER-TROL CU-1 iI -----SECTION 7-----------SPECIAL PROTECTIVE EQUIPMENT----------------- > USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS. VENTILATION PROTECTION *** ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINAN1S BELOW EXPOSURE LIMITS ' RECOMMENDED RESPIRATORY PROTECTION *** IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH DUST / MIST FILTERS. RECOMMENDED SKIN PROTECTION *** GAUNTLET-TYPE RUBBER GLOVES, CHEMICAL RESISTANT APRON WASH OFF AFTER EACH USE. REPLACE AS NECESSARY RECOMMENDED EYE PROTECTION *** SPLASH PROOF CHEMICAL GOGGLES. FACE SHIELD

S ECTION 8--- --------STORAGE AND HANDLING PRECAUTIONS-------------

STORAGE INSTRUCTIONS *** KEEP DRUMS & PAILS CLOSED WHEN NOT IN USE. DO NOT FREEZE.IF FROZEN, THAW AND MIX COMPLETELY PRIOR TO USE HANDLING INSTRUCTIONS *** ALKALINE. CORROSIVE (SKIN / EYES).DO NOT MIX WITH ACIDIC MATERIAL. THIS MSDS COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD HAROLD M. HERSH (ENVIRONMENTAL INFORMATION COORDINATOR) APPENDIX: REGULATORY INFORMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE. ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. ...TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY ... REPORTABLE QUANTITY (RQ) FOR UNDILUTED PRODUCT: 740 GALLONS DUE TO SODIUM HYDROXIDE ... RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE,THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS: D002= CORROSIVE (SKIN,PH) ... DOT HAZARD /UN#/ER GUIDE # IS: CORROSIVE TO SKIN UN1824/#60 ...THIS PRODUCT CONTAINS THESE CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY: NONE PRESENT IN SIGNIFICANT AMOUNTS ... SARA SECTION 302 CHEMICALS: NONE PRESENT IN SIGNIFICANT AMOUNTS ... SARA SECTION 313 CHEMICALS: NONE PRESENT IN SIGNIFICANT AMOUNTS ... SARA SECTION 312 HAZARD CLASS: IMMEDIATE(ACUTE) AND DELAYED (CHRONIC) ... MICHIGAN CRITICAL MATERIALS: NONE PRESENT IN SIGNIFICANT AMOUNTS NFPA/HMIS : HEALTH - 3 ; FIRE - 1 ; REACTIVITY - 0 ; SPECIAL - CORR ; PE - D

1 i I BETZ LABORATORIES,INC. 4636 SOMERTON ROAD,TREVOSE,PA.19047 PRODUCT: COPPER-TROL CU-1 i 1/22/91 AQUATIC TOXICOIDGY DAPHNIA MAGNA 0% MORTALITY: 65 MG/L L 48 HR. LC50: 112.5 MG/L RAINBOW TROUT 0% MORTALITY: 21 MG/L 96 HR. LC50: 28.1 MG/L FATHEAD MINNOW 0% MORTALITY: 49 MG/L 96 HR. LC50: 60.6 MG/L 1/22/91 MAMMALIAN TOXICOLOGY ORAL LD50 -NO DATA DERMAL LD50 -NO DATA SKIN IRRITATION SCORE-NO DATA EYE IRRITATION SCORE-NO DATA INHALATION-NO DATA l l l i L_

...~ BETZ LABORATORIES,INC. 4636 SOMERTON ROAD, TREVOSE, PA. 19047 BETZ MATERIAL SAFETY DATA SHEET 24 HOUR EMERGENCY TELEPHONE (HEALTH OR ACCIDENT) 215/355-3300 (PAGE 1 OF 3) PRODUCT : POWERLINE DEPOSIT CONTROL-WCN04 EFFECTIVE DATE 01-17-90 PRINTED: 21-Nov-1990 REVISIONS TO SECTIONS: APPENDIX PRODUCT APPLICATION : WATER-BASED DEPOSIT CONTROL AGENT.

SECTION 1-----------HAZARDOUS INGREDIENTS---------------

INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC-PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD IS LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHRONIC HAZARDS OF THIS FORMULATION. SODIUM HYDROXIDE ***(CAUSTIC SODA)***CAS#1310-73-2; CORROSIVE; TOXIC IF ORALLY INGESTED;PEL:2.0MG/M3;TLV:2.0MG/M3(CEILING). PHOSPHONIC ACID, (1-HYDROXYETHYLIDINE) BIS-(HEDP) * * *CAS # 28 09-21-4 ; EYE IRRITANT;PEL:NONE;TLV:NONE.

SECTION 2-----------TYPICAL PHYSICAL DATA-------------------------

PH: AS IS (APPROX.) 12.8 ODOR: SLIGHT FL.PT.(DEG.F): >200 P-M(CC) SP.GR. (70F)OR DENSITY: 1.125 VAPOR PRESSURE (mmHG): 18 VAPOR DENSITY (AIR =1): ND i VISC cps 70F: 19 % SOLUBILITY (WATER): 100 EVAP. RATE: ND WATER =1 APPEARANCE: YELLOW PHYSICAL STATE: LIQUID FREEZE POINT (DEG.F) : 18

SECTION 3-----------REACTIVITY DATA------------------------------

STABLE.MAY REACT UITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK CLF "-OUT CATEGORY 'B'- { THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES. ?

BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3) PRODUCT: POWER's1NF. DEPOSIT CONTROL-WCN04

SECTION

.-----------HEALTH HAZARD EFFECTS------------------------ ACUTE SKIN E'/FECTS * *

  • PRIMARY ROUTE OF EXPOSURE SLIGHTLY IRRITATING TO THE SKIN d

ACUTE EYE EFFECTS *** MODERATELY IRRITATING TO THE EYES 'l ACUTE RESPIRATORY EFFECTS *** l MISTS / AEROSOLS MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT CHRONIC EFFECTS OF OVEREXPOSURE *** PROLONGED OR REPEATED CONTACT MAY CAUSE PRIMARY IRRITANT DERMATITIS. MEDICAL CONDITIONS AGGRAVATED *** NOT KNOWN SYMPTOMS OF EXPOSURE *** MAY CAUSE REDNESS OR ITCHING OF SKIN. PRECAUTIONARY STATEMENT BASED ON TESTING RESULTS *** MAY BE TOXIC IF ORALLY INGESTED.

SECTION 5------------FIRST AID '

H CT I O N S - -- - - - -- - - - - - - - - - - - - - SKIN CONTACT *** REMOVE CONTAMINATED CLOTHING. WASH marOSED AREA WITH A IARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MINUTES EYE CONTACT *** IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE *** REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR. APPLY APPROPRIATE FIRST AID TREATMENT AS NECESSARY INGESTION *** DO NOT FEED ANYTHING BY MOUTH TO UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING.IMMED. CON'1.. T PHYSICIAN. DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER

SECTION 6-----------SPILL, DISPOSAL AND FIRE INSTRUCTIONS---------

SPILL INSTRUCTIONS *** VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL. PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE l CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL, SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULAT7.ONS. i FLUSH AREA WITH WATER. WET AREA MAY BE SLIPPERY. SPREA-3 l SAND / GRIT. DISPOSAL INSTRUCTIONS *** WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT (AS IS)- INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS *** FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (FULL FACE-PIECE Tf PE). PROPER FIRE EXTINGUISHING MEDIA: DRY CHEMICAL, CARBON DIOXIDE, FOAM OR WATER l I

j l BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3) S PRODUCT: POWERLINE DEPOSIT CONTROL-WCN04

SECTION 7-----------SPECIAL PROTECTIVE EQUIPMENT-----------------

USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS. VENTILATION PROTECTION *** ADEQUATE VENTILATION TC MAIMTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS l l RECOMMENDED RESPIRATORY PROTECTION *** IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH DUST / MIST FILTERS. RECOMMENDED SKIN PROTECTION *** I RUBBER GLOVES WASH OFF AFTER EACH USE. REPLACE AS NECESSARY RECOMMENDED EYE PROTECTION *** SPLASH PROOF CHEMICAL GOGGLES

SECTION 8-----------STORAGE AND HANDLING PRECAUTIONS-------------

STORAGE INSTRUCTIONS *** KEEP DRUMS & PAILS CLOSED WHEN NOT IN USE. ~ DO NOT FREEZE.IF FROZEN, THAW AND MIX COMPLETELY PRIOR TO USE J HANDLING INSTRUCTIONS *** ALKALINE.DO NOT MIX WITH ACIDIC MATERIAL. THIS MSDS COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD HAROLD M. HERSH (ENVIRONMENTAL INFORMATION COORDINATOR) APPENDIX: REGULATORY INFORMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE. ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. ...TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY ... REPORTABLE QUANTITY (RQ) FOR UNDILUTED PRODUCT: 4851 GALLONS DUE TO SODIUM HYDROXIDE ... RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE,THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS: D002= CORROSIVE (PH) ... DOT HAZARD /UN#/ER GUIDE # IS: NOT APPLICABLE ...THIS PRODUCT CONTAINS THESE CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY: NONE PRESENT IN SIGNIFICANT AMOUNTS ... SARA SECTION 302 CHEMICALS: NONE PRESENT IN SIGNIFICANT AMOUNTS ... SARA SECTION 313 CHEMICALS: NONE PRESENT IN SIGNIFICANT AMOUNTS ... SARA SECTION 312 HAZARD CLASS: IMMEDIATE(ACUTE) AND DELAYED (CHRONIC) ... MICHIGAN CRITICAL MATERIALS: NONE PRESENT IN SIGNIFICANT AMOUNTS NFPA/HMIS : HEALTH - 1 ; FIRE - 1 ; REACTIVITY - 0 ; SPECIAL - ALK

PE - B

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fa es: I The water Ma.a;ernent ? won of Ee*.: Lat: stcr;e s,Inc. EETZ LABORATORIES, INC. 4636 SOMERTON RD., TREVOSE, PA 19053 PRODUCT: PCWERLINE WCN04 10/3/90 AQUATIC TOXICOLOGY DAPNNIA MAGNA 0% MORTALITY: >1000 MG/L 48 HR. SCR. FATHEAD MINNOW 0% MORTALITY: >1000 MG/L 48 HR. SCR. 10/3/90 MAMMALIAN TOXICOLOGY ORAL LD50 - NO DATA DERMAL LD50 -No DATA SKIN IRRITATION SCORE -NO DATA EYE IRRITATION SCORE -NO DATA INHALATION -NO DATA i

. to NA 93-0216 t KDHE Letter About Outfalls 002 and 002a l l I i l l 1 4

I State of Kansas Joan Finn::y, Goyemor -Q DY wt Department of Health and Environment M Robert C. Harder, Secretary 913/296-0086 Reply to: August 12, 1993 M @ M 0W/M % Mr. Brad Loveless m Mr. Reece Hobby Wolf Creek Nuclear Operating Station AUG l 61993 l P.O. Box 411 3 Burlington, KS 66839 a Re: Relocation of Outfall 002

Dear Mr. Loveless and Mr. Hobby:

This is in response to your request that the designated location of NPDES Outfa'll 002 be relocated downstream to the point of discharge to the Wolf Creek Cooling Lake. Outfall 002 is currently located at a metal weir in a concrete culvert. Flow is directed to the culvert through a large corrugated metal pipe. Downstream of the metal weir is a long earthen ditch which discharges to an earthen settling basin and then to the Wolf Creek Cooling Lake. Potential sources of water to Outfall 002 consist of the following: stormwater runoff from parking lots and other unpaved areas of the plant; excess filtered water storage tank discharge, j and discharges from sumps located in the maintenance shop, turbine buildmg, and auxiliary building. However, the sumps are typically connected to the wastewater treatment plant and discharged through Outfall 003b and not through Outfall 002. You indicate that you have an intensive problem to prevent the intentional disposal of oils and other residual fluids into the sumps. Flows through Outfall 002 are treated by an oil / water separator before discharge over the metal weir. Based on my inspection of GJfait 002 on June 2,1993 and discussions with you, KDHE understands the problem with the current location of Outfall 002 as follows. Several times a year after heavy rains, a limited number of small patches of oil sheen have been detected downstream of the current location of Outfall 002. Under current law, Wolf Creek Nuclear Operating Station (Wolf Creek) is required to report to KDHE and the National Response i Center that there has been a " release" of oil at the facility. You typically report that the quantity of oil released is less than 1 ounce. You indicate that there is no evidence of environmental Jegradation caused by these wisps of oil and they are removed by downstream oil booms in the ditch. You argue that the relocation of the Outfall 002 downstream to the in!ct of the Wolf Creek Cooling Lake would give proper credit to the additional downstream treatment systems consisting of oil booms and the setthng basin. Even if an additional oil / water separator is installed upstream of Outfall 002, there is no guarantee that these small wisps of oil would not be discharged during significant rain events. When I inspected the current Outfall 002 on June 2,1993, I did not detect any oil sheen downstream of the metal weir. I did not observe any evidence of oil contamination or scanng of the soil downstream of the metal weir along the banks of the ditch. There were two large ' fish directly downstream of the m:tal weir in the ditch. There was extensive vegetation along the sides of the ditch. I was info ~med that this vegetation is maintained by Wolf Creek in part Forbes Field

  • Building 74
  • Topeka. Kansas 66620-0001 * (913) 296-1500 Pnnted on Recycmt Paper

P 9 Mr. Brad Loveless Mr. Reece Hobby August 12, 1993 Page 2 - for wild life habitat and as a food source for the wild life. A review of the monthly Discharge Monitoring Reports submitted by Wolf Creek indicates that typically /L. Chemic the parameter Oil & Grease is undetected at Outfall 002 at a level of quantitation of 1 mg Demand is typically undetected at a level of quantitation of 10 mg/l. The Total Suspended Solids at Outfall 002 are typically less than 1 mg/L. On renewal of the Wolf Creek water pilution control permit in February 1994, KDHE proposes to redesignate the current Outfall 002 as an internal outfall, 002a, and maintain current 4 monitoring requirements and permit limits (subject to modification during the renewal process) at the metal weir. Outfall 002 would be designated as the location where the settling basin discharges to the Wolf Creek _ Cooling Lake. Outfall 002 would be subject to Kansas Water Quality Criteria which includes the requirement that there shall be no visible oil sheen in the discharge. At this time, it is contemplated that there will be additional supplemental conditions in the renewed permit requiring the regular inspection (including during high flow events) of Outfall 002 for any oil sheen in the discharge. In addition, Wolf Creek will be required to regularly inspect the ditch downstream from the metal weir for any evidence of oil contamination of the soil. Additional requirements may address the implementation of an oil removal schedule for the oil / water separator with more frequent inspection of the separator during high precipitation periods. However, maintenance of the oil / water separator may be more appropriately addressed in the stormwater pollution prevention plan for the Wolf Creek facility, which you are currently developing. j If you have any questions, please call me at (913) 296-0086. Please direct to me any comments you-have concerning KDHE's proposed modification to Outfall 002. Thank you_ for your i cooperation in this matter. Sincerely, h (( Kelly Finn j Environmental Engineer ~ Industrial Program Section . Bureau of Water c:SECO C 1

. to NA 93-0216 Sulfate Analysis Results for Outfalls 003 and 004 e t V9

Enclosure to NA 93-0216 Comparison of Sulfate Analysis Results for Outfalls 003 and 004 (September 1992 - September 1993) Date Outfall 003 (mg/L) Date Outfall 004 (mg/L) 09-07-92 73 09-08-92 82 09-21 92 76 09-22-92 64 11-23-92 77 11-24-92 70 12-03-92 70 12-01-92 70 12-14-92 64 12-15-92 79 12-21-92 75 12-22-92 88 12-29-92 71 12-29-92 88 01-05-93 62 01-05-93 74 01-11-93 73 01-12-93 92 01-18-93 93 01-19-93 90 01-25-93 82 01-26-93 77 02-01-93 77 02-02-93 75 02-04 93 70 02-09-93 95 02-15-93 104 02-16-93 99 j 02-22-93 97 02-23-93 81 j 03-01-93 88 03-02-93 90 l 03-08-93 89 03-09-93 85 03-15-93 82 03-16-93 86 1 03-22-93 90 03-23-93 85 l 03-29-93 79 03-30-93 85 04-05-93 86 04-06-93 98 04-08-93 83 04-13-93 82 04-20-93 92 04-20-93 81 04-26-93 77 04-27-93 74 I 05-03-93 70 05-04-93 65 05-11-93 82 05-11-93 65 05-17-93 95 05-18-93 85 05-25-93 67 05-25-93 58 05-31-93 79 06-01-93 66 06-07-93 69 06-08-93 68 1 l 07-05-93 76 07-06-93 98 1 07-12-93 85 07-13-93 70 07-19-93 65 07-20-93 70 07-26-93 59 07-27-93 80 08-02-93 80 08-03-93 5( 08-09-93 68 08-10-93 9(c 08-31 93 68 08-31-93 62 09-07-93 69 09-07-93 70 09-14-93 64 09-14-93 65 09 28-93 75 09-28 93 69 Total 3,101 3,127 Number of Results 40 40 i Annual Average 78 mg/L 75 mg/L

' l to NA 93-0216 l l 1 i l 1 i Cooling Water Analysis Results 1 1 i l l i l l i l i k t l r

e Enclosure to NA 93-0216 Cooling Water Analysis Results (Requested in Cover Letter) Parameter Outfall 003 Outfall 006-A Outfall 006-B pH 8.3 8.4 8.5 Temperature 22 C 13 C 16' C Oil and Grease < l.0 < l.0 < l.0 TSS 9.4 5.4 3.9 COD 11 12 10 NOTE: Both trains of the Essential Senice Water System that discharges at outfall 006 were sampled and this accounts for the two sets of results. i

-h, ',4 -. _\\ Enclosme 10 to NA 93-0216 l 1 GeologicalInformation Aboutthe Lime Sludge Pond ub + r .-r

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  • FACILITY DR AWING
  • WITH CENTER OF RE ACTOR LATlTUDE 36'14'20' NORTH. LONGITUDE 95'4T20' WEST.
2. L ANO USE OF WCGS SITE SHOWN ON *FACIL!TY ORAWING'IS FOR COMMERCIAL NUCLE AR POWER PRODUCTION. SURROUNDING La NO U$E IS AGRICULTUR AL.
3. SEE ' FACILITY ORAWING' FOR NPDES OUTFALLS 001. 002 AND 003, 4.

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UNIT NO.1 Anmwe e' ENVIRONMENTAL REPORT FIGURE 2.4-9 DETAILED SITE STRATIGRAPHIC COLUMN l

w 4 t Enclosure to NA 93-0216 Geological information to evaluate the potential for groundwater infiltration from the Lime Sludge Pond at Wolf Creek Generating Station The composition of geological layers within five miles of Wolf Creek Generating Station (WCGS) and local hydrological gradient reduce the potential for sulfate infiltration from the Lime Sludge Pond to significantly impact groundwater. A series of altemating shale and limestone layers underlie the WCGS site and these formations do not readily yield groundwater (see attached figures 2.4-7 and 2.4-9 and tables 2.4-6 and 2.4-7). Surface layers consist of weathered clays that crack from desiccation and soil creep and consequently allow water to initially infiltrate upper layers. Continued percolation into the weathered clays causes sediment to fill the cracks between clay particles, which also swell under saturated conditions to further restrict the movement of groundwater. Seepage rates calcu'ated for Wolf Creek Cooling Lake in the Wolf Creek Generating Station Emironmental Repcrt. Operating License Stage indicated that groundwater infiltration from the cooling lake to the shale and limestone layers would be very slow. Water was estimated to move at a rate of one to eight i feet a year. The slow movement of groundwater through these formations was the basis for concluding in the emironmental report that seepage from the cooling lake would not significantly degrade down-gradient groundwater with total dissolved solids. A copy of the sections of the emironmental report that evaluated site geology and hydrological characteristics is attached for your reference. i WCNOC believes that the Lime Sludge Pond exhibits a similarly reduced potential for J groundwater infiltration as the cooling lake. Please note on the attached topographic map and figure 2.4-6 that the Lime Sludge Pond is located between the 1100-foot contour shown faintly on both maps and the shoreline of the cooling lake, which has a normal elevation of 1,087 feet j above mean sea level. The supplemen'al NPDES outfall location diagram attached to the j - topographic map may also help place the location of the Lime Sludge Pond. Any groundwater -l infiltration that occurs would be directed toward the cooling lake. The potential for groundwater impact fram the Lime Sludge Pond was previously determined to be insignificant in surface water discharge assessment conducted by Marian Massoth with KDHE and a solid waste management unit evaluation sent to John Goetz with KDHE. A copy of a telephone call record documenting her determination is attached, as is a copy of the solid waste management unit evaluation. In summary, WCNOC believes that there is little potential for groundwater infiltration from sulfates in the Lime Sludge Pond. The geological characteristics of the WCGS site do not wanrant imposition of the 250 milligram / liter sulfate limit on discharges to the Lime Sludge Pond as a groundwater protection measure. .r-e v.-

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'Q . f~ ' .\\ ,y. e., .~ tIcIN0: W/00mTCPOGRAPHic CONTOUR $ (50 FOOT INTERVAL $) -/W-VATER TABLE ELEVATION CONTOURS (10 FVOT INTERVALS) FROM CATA GATHERED DURING VELL INVENTCRY. (SEE TAets 2.4-29). WOLF CREEK GENERATING STATION t ARROWS SHOV DIRECTICW OF GROUNO-VATER FLOV.

REFERENCE:

nCU3C C.4 C FIFTY-FOOT TCP0 GRAPHIC CONTOURS FROM U.S. GECLCGICAL sVRVtY QUADRM;ll$ FOR NEV STRAVN (1971); OTTimIA WATER TABLE CONTOURS (1970). WAVERLY SE (1971). ALICEVILLI (1971) eURLINGTON (1971) AND XNN PEDNNO DM (1966f; WITHIN A 5-MILE 7.5 MIN E,5EAlES. RADIUS OF THE SITE o w 3.,

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-b .q < .y Y _p FILES nATE: 1/12/89 LE: TDfE: 1025 TE: 42293-V Other TELEPHONE CALL RECORD TO: Marian Masseth FRCH: e B rado tove1~e s s==- _ _ - = _ CCHPANY: KDHE ADDRESS:., Forbes Field TELEPHONE N3

SUBJECT:

, Marian said she called to. follow up on our conversat' ion ' earlier in the week /el ' (telecon 1/9/89). 'p[,. c~ Concern c.ver Sulfates in the Lime Sludge Pond (LSP) [g .y s. Marian checked and said that her, records show the LSP to have a compact'ed;";'- natural clay bottom. She said that, as we had said, KDBE had given1 permission to have high sulfate concentrations in the pond. They gave this because she said that the sulfates had little chance of leaching through the pond bottom to contaminate the groundwater and that even if a small amount did, the groundwater use is very lov in the area. 1 Wastewater Treatment Option 2 Veto Next. Marian said she'd received our letter on the two options to reduce total suspended solids (TSS) to the lake. Upon review and discussion, KDHE concluded that discharges to the LSP with pH's outside of the 6-9 range would not be permitted so they didn't want us to try Option 2. I told her that we understood that hazardous vaste regulations required only that LSP influent pH be between 2 and 12.5. She said that since low pH makes heavy metals soluble, they would restrict our influent pH range to between 6 and 9 to prevent groundwater contamination. She said that even though there's no close groundwater usage, we still need to be cautious. I told her that.our Operations group has administrative controls which they can use to narrow; Option 2's LSP inputs to between 6 and 9. ' Just the same, she said,-

shef, ivould rather we avoid use of Option 2 unti1've can't. avoid it.

> c c.. 9 % 'i NPDES Permit Renewal Cournent s 'l Last, Marian asked if we had sent our NPDES corrnents yet. I told her that we were working on them currently She said that they'd received no coments thus far but that they'd gotten a request for a copy of the WCGS i permit from the KNRC (Kansas Natural Resource Council). i s

{., ' hV:' entw {' KANSAS GAC AND ELECTRIC COMPANV TW ELE CimC CMANY I' January 14, 1986 0 L E *e te L aoEstEa .c n n,..ca.. Mr. John P. Goetz Kansas Dept. of Health and Env. Hazardous Waste Section Bureau of Vaste Management l Forbes Field, Building 720 l< Topeka, KS 66620 1 ^

SUBJECT:

KMLKAN 86-0Ma RE: Wolf Creek Generating Station Nonhazardous Solid Waste Management Units

Dear Mr. Goetz:

. The purpose of this letter is to respond to the August 13, 1985 Environment-- ^ . Jal Protection Agency (EPA) request for.information in regard to Solid Waste l Management Units (SkHU's) operated at Wolf Creek Generating Station (WCCS). - The submittal provided to EPA on June 6 detailed ~ activities within the Tre at ment, Storage and. Disposal facility operated by KG6E (Ref. KMLKAN 85-

008).

This submittal describes only those activities associated with nonhazardous SWMU's. ) / Two such facilities functioned at WCGS through the period of plant construc-tion; the time Sludge Pond (LSP) and the burn pit. Due to the degree of detail requested, KG6E has chosen to respond in the form of two attachments. Attachment 1 provides permitting, construction, groundwater, geology and operational information on the LSP. Nucerous tables and figures are included with this attachment. Attachment 2 addresses the burn pit. It should be noted, however, historical information on this facility does not allow for a detailed summary of its use. Finally, through recognition of permit requireeents and the performance of operational surveillances ot' these SWMU's, KG6E =aintains that no impact on local groundwater has occurred. Additionally, present usage of the LSP within the NPDES program at WCCS, eliminated it as a SWMU. In closing, KG6E requests that the Kansas Dept. of Health & Environment consider the enclosed information and acknowledge that all permit actions necessary to terminate our interim status are complete. bour assistance in.the Department's completion.of this action will be 1 appreciated. If further information should be necessary, please contact

#1

' Greg R. Wedd ac (316) 364-8831, Ext. 3100.' Very truly yours, rfY Glenn L. Xoester Vice President Nuclear i s GI K /DLV/ rrv Enclosures xc: 'G. Wedd Records Mgm MS 2-03 w,,.,,,,,2,*

  • u u.a t wnt-ncansas - va,I Accress: PO. Box 2CS I Wochia.fantas 67201 - Tefechone: Ates Code 010 261 E4$ 8

. w. 1

o 7, l 'a L g ( LIMS SLUlr,B POO I. Facility Permit Chronology ( On May 4,1979 Kansas Gas and Electric Comoany (KG&E) applied for permission to construct and operate a " waste water treatment lime sludge pond" from the Kansas Department of Health and Environment (KDHE). Aoproval was granted, y and on June 19, 1979 Solid Waste Discosal Permit No. 341 was issaed for the facility. Daring the sumer of 1980 a pond, covering approximately 31 acres and having an average depth of 7.8 feet, was constructed. I. On February 18, 1982 a request was made to allow modification of Solid Waste Permit Ib. 341.. The moriification request asked for permission to incorpor-ate steam system pipe flushing, cleaning and conditioning solutions, as well f .as demineralizer regenerates and flushes, to the permitted influents of the . lime sludge pond (LSP). Kansas Gas & Electric received the requested modification approval on March 4, 1982 which stipulated that "all materials 4' frcm these sources shall be periodically tested and evaluated so as to insure that none of the wastes are hazardous wastes." Additional discussion of the chemicals and volumes of influents to the LSP are provided in the Facility Operation section of this report. Internal KG&E correspondence documents that in March of 1983 the water level of the LSP was hiqh ani that seecage was occurring through the discharge structure stop legs. At this time, an estimated 40,000 gallons per day of regenerative wastes were being contributed to the LSP frm the make-uo water treat:nent plant. 'Ihis volume of waste reflects the peak demand for demineralized water required during Wolf Creek Generatim Station (VCGS) start-up activities. As corrective measures for the level and seepage -prob 1ms, a request was made to design and install a sluice gate on the - discharge piping and discussions on LSP operations were initiated with the 'KDHE. ) -Page l- 'j 1 1 t-m.... -,.

, gg O  ? 7" - .s ~ Table 1 presents the LSP analytical data provided to the KDHE. % is same data was subsequently the main toolc of discussion during a meeting in Topeka on January 13, 1984. %is meeting was attended by KGLE as well as t KDHE Water Pollution Control and Engineering and Sanitation Section personnel. As a result of the neeting, the KDHE approved the draining of i the LSP to the Wolf Creek Cooling Lake. Additionally, KG&E acreed to allow th'e KORE to perform a review of the LSP geology. We curtose of this review ? was to confirm apprcval for continued coM operation and assess the adecuacy of the pond in preventing groundwater contamination. A report on specific test boring aM geotechnical data oerformed near the LSP, along with a statement of the ISP's long term expected influents were provided to the d KDHE on February 22 and March 6,

1984, respectively.

The information presented in the geological ~ report are sumarized in the celogv and ' Groundwater section of this subnittal. Finally, on June 22, 1984 the KDHE was informed that discharges. from the LSP l were being incorporated into the hCGS - National Pollutant Discharpe Elimination System (NPDES) permit application addendun. Kansas. Gas and Electric Canpany also recuested a variance of the financial recuirements of Kansas Aininistrative Regulation 28, Article 29. We KDHE granted the variance recuest on December 14, 1984, and after issuing the NPDES permit in April, canceled Solid Waste Discosal permit No. 341 or. June 13, 1985. l I l -Page 2- .1-.. c, ;. ~ s

(J ' *.] , + 3 l ) 9 LIME SLUDGE POND u II. Facility Construction [ Enclosed are the following site architectural drawings completed by Sargent - & Lurdy Ergineers of Chicago for the construction of the Lime Sludge Pond: i Drawina Number Title- ) i S-6 Lake Developnent j S-87 Lime Sludge Pond Plan j S-88 Lime Sludge Pond Section & Details r S-89 Lime Sludge Pond Outfall Structure Details _ 1 S-468 Lime Sludge Pond Sluice Structure Plan C 5-These drawings provide information on the location,. 's'ize, "and features of the LSP. Details on the slopes of the dikes, riprap coverirq and dischatye structure are also included. Please note that all elevations given are 900 l feet greater than U.S. Geological Survey Dattrns and are Standardized Nuclear - Unit Power Plant System (SNUPPS) Datums unique to NCGS and our sister unit, the Callaway Plant. Additionally, the SNUPPS grid coordinates given are also unique and reference such that State' Plane coordinates N SR4,670 and E. 2,807,250 correscond to N 100,000 and E 100,000, respectively. The construction specifications and soil testing procedures for the LSP were l also developed by Sargent and Lundy Ergineers. Table 2 irdicates the exact - 1 soil-tests which were ccrnpleted and their frequency. %e berms of the LSP were constructed of ccrnpacted cohesive clay, which had been' excavated' from - near the construction site. 'Ihe bottom of the LSP varies in. elevation, to a maximum depth near the outfall' structure, and was not lined. As noted --P . previously, ~ construction of the LSP was completed in 1980, and. initial discharges to the pond began during the fall of 1981. te LSP capacity was -Page 3-u 9 b /a g -r "d" 'YF

[ 3. engineered to allow for influents such that, after 30 vears of operation, no more than one fcot of slute would have been deoosited onto the cond k tottom. %e remaining cond frectoard was expected to give sufficient n' capacity to accomodate record wet years or 100 year-24 leur rainfall events and still prevent discharges. The actual construction of the Lso was performed by Clarkson Construction Co. of Kansas City, Missouri and all cuality control soil testing was completed by Daniels International Company. 'Ihe construction specification f recuired that subgrade areas, onto which the Lsp berms were constructed, be [ prepared by breaking and turning the soil to a depth of 6 inches. % is was A comoleted by discirn,

blading, or other suitable, means.

Bis same ' equipment, along with a sprinkling unit, was utilized for moisture conditioning of the soil. Backfill ooerations were canpleted using a sheep's foot packer, pnetrnatic tire or cylindrical roller. At no time were perishable materials such as brush,

roots, sod,-

ice or' frozen soil incorporated into a berm lift. It was standard cractice to avoid the development of rutted or uneven ccmoaction due to haulina eaui}: ment. Soil testing ccmolied with the frequencies soecified in Table 2. %is 1 testira prcqram documented soil moisture and density as well as lift thicknesses. Earthfill materials were ccenpacted b .imtrn dry density to achieve a density ecual to or creater than 95 ce c.. of the maxinum value. Moisture content of fill material was maintained at + 2 percent of the optimum value. In situ soil moisture and density values will be discussed l l later in the Geology and Groundwater Section. Finally, maximtrn 1cose lift thickness was not allowed to exceed 8 inches for any given laver of the i pond's berms. l 1 -Page a-

1 ., y LIME SUJDGE POND III. Geolcay and Groundwater sumation of reference information provided to KG5E by This section is a Drnes ard Moore on May 23, 1975. This 1975 report, titled "Geotechnical r. ~ Investigation, Proposed Switchyard; Wolf Creek Generating Station, Unit No. [ 1" describes the soil and groundwater characteristics frm an area Opproximately 50 yards south of the LSP. % is same recort, as previous 1v noted, was subnitted to the KDHE and served as their reference information in evaluating the LSP's ability to prevent groundwater contamination. Apolicable information presented in both the Construction and Operatirn License Stage, " Wolf Creek Generating Station, Unit No. 1, Environmental Reports" was also included. Plate 1 and Plates A-1 throuah A-3 are prcuided [ by reference frm the Dames and lbore report. Fiqure 2.4-14 " Location of Piezmeters" is prcnided frm the HCGS Environmental Reoort, Operating License Stage [ER(OLS)]. %is figure locates the L9P with reference to the cooling lake and the plant construction site. The location of piezameter B21, illustrated on Plate 1, is also identified on Figure 2.4-14. The results of the Dames and Moore report were based u@n subsurface soil, rock and groundwater conditions identified by drilling seven exploration test borirgs. An eighth boring, SY-3A, was located off the proposed switchyard site due to a survey error. Plate 1 shows the boring locations, a soil and bedrcck profile, and illustrates the gradual westerly change in surface elevation of the area. Wst borings ranged from 18.8 to 21.8 feet deen and bedrock was encountered at depths of five to seven feet. Soils in the area are variable in character and reflect the ecxrcosition of the urderlying bedrock. 'Ibpsoil was a brown organic ~ silty clay and was eight to twenty inches thick. Residual soil, overlying bedrock, gene' rally consisted of gray and brown silty clay with fine sand. Zones of clay silts -Page 5-

7. ' -.-

y.. ~.,..,.

  • .I i

4 5 i and silty sands existed due to differential weathering of bedrock. We f ] consistency of the residual soils were stiff to very stiff. Plates A-2A t through A-29 provide soil descriptions, profiles and test data on soil shear ~ it '} strength, moisture and density. l The bedrock identified by Dames and Moore's test borings are included in the i, Kanwaka Shale Formation. Two members of this formation were documented and l, i included Jackson Park sandstone over shale of the Heumader Member. Deeper ~E j \\ } geologic formations in the area of the LSP were recorded during the B-series test borings. %e geophysical soil and bedrock profile of boring B-21 is ' l l' J . I t

  1. E. '

j presented in Figure 2.5-34u frm the VCGS, Unit 1 " Final Safety Analysis s Report" (FSAR). Frm these test borings, it was determined that bedrock of ( the area sloped downward to the northwest. %e Jackson Park saMstone w'as

b..':. '

t gray, weathered to yellowish orange, and was considered silty; fine to I' [ medium grained and generally calcareous. Wis sandstone was weathered [ greatest at shallower depths and along the uoper surface. %e sandstone was mediumbedded and weathered along the fractures, which resulted in a Rock V ?U Ouality Designation (RQD) value normally ranging frm 0 - 40 percent. The effect of the fractures and RQ9 value on bedrock permability will be incorrorated into the discussion of groundwater. % e Heumader Member shale 1 was medium gray, calcareous and thinly laminated. Weathering was observed in the upper one foot only. % e Heumader shale is very fossiliferous and crops out in a band runnirq frm northeast to southwest through the plant site. 1 1 All test borings were completed using a truck-mounted rotary-wash drilling unit. Each soil sample was obtained by using a 2 3/8 inch I.D. Dames and Moore Type U Soil Sampler. Bedrock samoles were obtained with a NX-wireline r i core barrel. All samples were classified in accordance with terminolcqy 1 { defined in Plates A-1 and A-3. .~ 4 i Groundwater sources frm within the general area of the plant site can be divided into three types: alluvial deposits, soil and weathered bedrock, a and deep unweathered bedrock. DJe to a large relative distance frcrn the 1 -Page 6-l L .. -... I l.....

1,.

LSP, water drawn frm alluvial soils will not be discussed within the

~ context of this report. Additionally, aroundwater obtained from elevations f below 700 feet will receive little discussion. This is due to ntraerous shale units with low permeabilities and the fact that preoperational studies iMicated that these waters were of coor to unsuitable cuality. The deoth of the SY-series test torings did not penetrate into deeo bedrock. %ese borirgs, therefore, proiided information on grourdwater within the soil and weathered bedrock zone. Table 2.4-6 "Hydrcneologic Characteristics of ~[! Bedrcck within a 5-Mile Radius of Site" presents water yield character-ir istics and permeability data of various bedrock strata. L f Preoperational studies indicated that groundwater wells within the soil and i:;p. t. .weatherad bedrock zones could yield from 0.5 to 10 qallons per minute. This

p, I

water was hit.tdrically used dcmestically or for livestock. Water levels in wells and shallow piezcmeters closely resenbled surface to g raphy and increased with precipitation. Based uoon discussions ia the ER(OLS), presene groundwater levels are exoected to be higher than those documented prior to lake fillira with all strata exoeriencing recharge frcm the lake. Finally, the KGS radiological nonitoring program documents that the average distance to a grourdwater well, currently in use, is 2.78 miles with the closest well being 1.4 miles from the site. %e gradient towards each well varies with direction and location. Plate 1 shows the groundwater level identified by the SY-series piezcmeters Jnile Table 2.4-8 provides a log of the water levels fourd in borina B-21. .H l In situ permeability of the Jackson Park sandstone and Hetnader shale was directly dependent upon weathering ard fractures. Test borirqs doctrnented that weathering was limited to the sandstone and uoper one foot of shale. Bedrock fractures were noted to extend horizontally rather than vertically. ~' These fractures contributed to the sandstone Pm values previously presented and also resulted in~ vertical permeabilities being estimated at orders of magnitude less than horizontal permeabilities, mis perTneability variance -Page 7- ~

- 1

.m.1 ; y l i t sMwn in Table 2.4-7 "Perneability of Fock Units by Depth." with depth is however, due to These data primarily reeresent horizontal permeabilities, means to aporoximate the ratio of vertical to i the fact that no accurate horizontal permeability existed. Actual pressure and falling head proved that shales restricted water. flow in the vertical Water was shown to take the path of least resistance and move in "[ permeameter tests direction. 5 l n.s, a radial'and horizontal direction. Therefore, as present.ed in the ER(OLS) lake [ ". any seepage frcm the LSP would be expected to either enter the cooling or mcue horizontally through the Jackson Park sanistone at a rate of no more i;(( than 4.4 x 10-5 cm/sec. kN. 1< k,Y.'.. L rg"- i. .i..

  • 0 5.>.

-Ptsge 8-

r, o V 4 i LIME SLUDGE POND

i.
  • s IV.

Facility Operation During the inital design stages of the KG9 proiect the need for a facility

~.

to accept waste prcduced fran the water treatment processes was recognized. The Permit Chronology section of this report identifies that the LSP was constructed for this purpose. That same section reccanizes the change in g, the water treatment process that occurred in 1982 and the required 2.f.f. i my notification to the KDHE. This reoort section will detail the volumes and hg{.1 the chemical constituency of wastes added to the LSP. It should be noted that nearly all of the waste water cenerated was produced by the ?T c.~: { demineralization system. Potable water is presently supplied to WCGS on < (.yj

contract, anS will therefore not be discussed.

r !;> ' , i.a The water treatment olant (makeup demineralization system) at NCGS was designed by the Permutit Canoany. The system consists of two basic steos; a pretreatment portion and a demineralizer portion. The pretreatment process !g accepts suoplv vater frcm the Neosho River, and is capable of pro /idinq ~ ' water to the demineralizers or the cotable water system. This water receives chlorination, can be lime softened, pH adjusted and passes through sand and carbon filters. The actual demineralization system consists of two parallel trains each capable of prcducing 216,000 gallons of demineralized water in a 24-hour pericd. Tne pretreated water flows through four ion exchange resin demineralizers; a strong cation exchanaer, weak base anion exchanger and tien a strong base anion exchanger bed and finally a mixed bed demineralizer. The regeneration of these demineralizers and backwash of sand and carbon filters produces the waste water which enters the LSP. 9 7,.. . Table 3 presents the. chemicals utilized in the makeup demineralized water treatment process at WCGS. Information is also presented on dosages per regeneration, frecuency of use and annual totals. For the purpose of -Page 9-

~. ~.; Attachement 1 ~ estimating the total volume of waste water produced during a regeneration cycle, dilution water and backwash flow are also orcvided in Table 3. 'Ihe numbers presented in this table reflect the procedures soecified in Permutit's "Operatirq Instructions for Water Coniitionirn Ecuimient" i manual. Impurities which will be removed by the demineralizers are identified in Table 3.6-6. These substances are removed throtnh the ion exchange process and durina a system regeneration the bulk of the wastes are discharged in the form of sodiun sulfate arri sulfuric acid. During design operations the sulfuric acid contributed to the LSP was expected to be neutralized by reactina with discharged calcitra carbonate and minerals in [ the pond's bottom and sides. L During 'che WCGS plant startup activities some pipe cleaning and ' conditioning solutions were added to the LSP. 'These chemicals nainly consisted of I trisodium phosphate, discditra phosthate, sodium hydroxide and some annonitra T hydroxide and hydrazine. Conoliance with the KDIE's testing requirements for such wastes was acheived through the develonnent of a series of adttinistrative controls arri procedures. A pH testino program of the LSP was k instituted by the NCGS Chemistry staff to assure influents to the pond were-neutralized. Please note that because of the lack of an accropriate discharge piping configuration, no waste water fran steam system cipe flushes entered the LSP. ] i -Page 10-P 1* 'iA< 4 + .% =9 9, g 4 4F F 8

f, attachment 1 LIMS SLUDGE POND l i 1 v. Sumary s h In addressing the LSP and the disposal of solid waste within the pond, this q attachment prcuides a history of facility permittina, construction, aeolcoy l I and groundwater testing' and facility operation. Section I notes the KDHE apprcual of Solid Waste Disposal Permit Ib. 341 and its subsecraent modification i1 1982. Finally, upon the incorporation of the LSP discharge i into the ! CGS NPDES prcqram, permit No. 341 was cancelled.- Section II l ( details the LSP design engineering and construction methodology. soil testing racrairements during the pond's construction are presented in Table / 2. Section III sumarizes a 1975 Dames and tbore report titled "Geotechnical Investigation, Proposed Switchyard: Wolf Creek ~ Generatinq Station, Unit No. 1." Mditionally, numberous tables, which describe the l ) qeolcqy and groundwater in the area of the LSP, are orovided fraa the WCS f ER(OLS). Soil and bedrock permeabilities are discussed and present and historic grourdwater usaae described. Finally, Section IV notes the water 4 treatment processes at WCGS discharged to the LAP. Chemicals voltnes utilizei in demineralizer regeneration process are doctrnented in Table 3. t Based upon the information presented in this attachment, discharaes to the-f LSP will have no sianificant impact on aroundwater in the area. j Additionally, due to the minimal groundwater yields from local wells and their relative extended distances frcm the cond, there should be no effect on water quality. \\ j ) l I i l I l -Page 11-l i

j' g):@, j'

  • ?

WCGS-ER(ots) f-. [' 2.4.2 G R OUN D-WATER s. 4 i 2.4.2.1 Formational Hydrogeologic Characteristics Small quantities of ground-water are regionally available f rom three sources within a 50-mile radius of the site: 1. The alluvial deposits in the river valleys; 2. The shallow soils and weathered bedrock; and 3. The deep bedrock. ( 2.4.2.1.1 Alluvium The river alluvium in the region is composed of silt, sand, and gravel. The Neosho River flows southeast through Morris, chase, Lyon, Coffey, Anderson, Woodson, Allen and Neosho counties, and passes within 3 miles of the site. The width of the alluvium in the valley ranges from about 1 to 10 miles. Other alluvial aquifers are associated with the Marias des' f 'Cygnes River in Osage,. Franklin, Miami, Anderson, and Linn 't . counties; the Verdig ris River in Lyon., Greenwood, Woods ~on,r. Elk, and Wilson counties; and the Osage River in Bourbon County adjoining the state of Missout 1. I:.- 'th'e alluvium along the Neosho River in Coffey, Woodsoni and ) Allen counties is less than 20 feet thick, has a water pro-L ducing potential of less than 100 gallons per minute (gpm) l to wells. The alluvium receives recharge mainly from pre-cipitation and f rom bedrock discharge in areas where an ertesian head is higher than the river surface. The alluvium discharges ground-water to the Neosho River; the ground-water system contributes water to the Neosho, an effluent stream, from John Redmond Reservior to at least as far downstream as Iola, Kansas (the furthest downstream place studied). As there are no large withdrawals of ground-water to create water level declines in the alluvium, water from the Neosho River is not being artifically induced into the alluvium because of a gradient reversal. Other than the supply well of the city of New Strawn, located above the confluence of Wolf Creek and the Neosho River, there are no irrigation, industrial, commercial, or public supply wells tapping the alluvium along the Neosho River as far downstream as Iola, Kansas. Because the alluvium i does not yield sufficient quantities of water for irrigation, .it is unlikely that significant irrigation withdrawals.will be developed in the future. A detailed discussion of ground- ) water. use along the Neosho River is presented in Section 2.1.3.4. ) High-water conditions of the Neosho River are not likely to af fect g round-wa te r conditions significantly. Normal 2.4-10 n.

t h; ' ~ ~ y ,.m e WCGS-ER(OLS) ~. o [,(f)f seasonal increases of the river stage increases bank storage 'yg (water absorbed into the banks of the stream channel) in the alluvium. As the stage recedes, the water returns from. the banks to the river. The actual horizontal mig ration distance of river water back'into the alluvium under these conditions is on the order of up to 100 to 200 feet. The high h volume of runoff during high river stage would dilute any blowdown effluent that might recharge the shallow g round-water u during that period. There are probably no domestic or stock wells that would be affected by normal high seasonal stages of the Neosho River at least as'far downstream as Iola, Kansas. Therefore, the discharge of.any effluents to the.Neosho eg e River is not expected to contaminate,the shallow ground- -.r L water system. l The flood control dams at Council Grove, Marion, Cedar Point and John Redmond Reservoirs help reduce the severity.z of flooding. The July 1948 flood, selected as an inter- - mediate flood by the U.S. Army Corps of. Engineers (1965), would not have flooded Neosho Falls had the flood control, a dams been constructed. Th us, pr ivately-owned;.wa te r.- wells. i.n.. the community of Neosho Falls would.not now (1979)- be affec.ted" by a flood.of the July 1948'magnitud'e, and the're..are.few ej: residences and wells on the floodplain..of the Ne.osho, River;.;d In a small watershed such' as the Neosho River Basin, ' ground e 7-water levels in the floodplain will have already. risen and; the l,) soil will be saturated in response to precipit'ation so that, by the time a flood occurs, there will be little available, room for additional recharge from the flood waters. Most of the flood waters would retreat by runoff as the. stage falls.. High dilution of any blowdown effluent would preclude deter-ioration of ground-water quality by recharge of flood waters. 2.4.2.1.2 Soil and Weathered Bedrock The soil and weathered bedrock is composed of weathered shales, siltstones, sandstones, and limestones and the soils derived from them. The weathered materials usually retain some of the characteristics of the parent rock. Wells in the weathered zone yield up to 10 gallons per minute in the region (Bayne and Ward, 1967), and are gen.., erally.used domestically and for livestock. Recharge to the; weathered zone which may extend down to about 20 feet is.from loca1 ' prec ipi ta tio n. Discharge is into the alluvium,. streams, and local wells. .. F. Water levels in the wells and shal'Iow piezometers show tha't E the shallow g round-water table closely resembles the top-ography within a 5-mile radius' of the site area, as shown on . Figure 2.4-6. 2.4-11

- m &,- g -
_ ; c.

c

I-WCGS-ER(OLS) I {e The permeability values presented for the geologic strata c/

  • e in Tables 2.4-6 and 2.4-7 represent estimated horizontal si pe rm ea bili tie s.

The actual vertical permeabilities are probably several orders of magnitude less than the horizontal permeabilities shown. There are, however, no accurate means to approximate the ratio of the vertical to the horizontal i permeability using existing data. The vertical permeability { can best be determined from laboratory tests. Laboratory tests of samples will only be reliable if the samples are consolidated and relatively undisturbed. The methods and techniques utilized in the determination of - the in-situ permeabilities are erblined in Section 2.5.4~' l-of the Wolf Creek Generating Station, Unit No. 1 Final Safety Analysis Report (WCGS FSAR). Permeability of the surficial materials is primarily de-pendent upon the intensity of weathering of the parent rock'.' Near and at the surface, the weathered limestones are vuggy and exhibit a much higher permeability than do the weath - - 'ered shales. The sandy facies of the Jackson Park Shale ~5 4 Member commonly has an appreciably nigher permeability than 2 the snaley facies. The depth of the weathered zone on the,1 hill tops and upper hill slopes is less than the depth of 21 weathering in lower, flatter aress where ground-water is .I 1 3 closer to the ground surface. O d; Generally, the surficial weathered zone in the apper 5 to 10 feet is comprised of residual clayey soils (from shale t parent rocks) with numerous root holes, insect burrows, and animal burrows. Desiccation and soil creep have oponed j minute cracks. These openings provide water channels that i allow the rapid infiltration of water. As infiltration continues, internal scour produces detached partic3es that gradually clog the narrowest parts of the water passages, and swelling of the desiccated clay particles further re-duces the effective size of the openings. In response to recharge, the coeffcient of permeability decreases to a small fraction of its " dry" or initial value. Where it is saturated, the weathered bedrock (except lime-stone) has a g reater permeability than the overlying soil zone. Table 2.4-7 provides a summary of the permeabilities 'of the bedrock as related to depth. The permeability values ~

  • were broken down according to depth because of the variation

.with depth. The column labeled 0 to 20 feet provides a. tabulation' of the permeabilities (essentially horizontal permeabilities) of the weathered bedrock units. The pe rme-l abilities of the deeper bedrock (greater than 20 feet) are generally less and are representative of unweathered bedrock. I i 2.4-12 ~ l k

.,.c..

u

.;a.....

m q WCGS-ER (O LS ) i: N "; As indicated on Tables 2.4-6 and 2.4-7, the numerous un-1 weathered shale units in the area retard the vertical movement j '3 of water. In the site area, the in-situ permeabilities j obtained for the deeper bedrock strata are essentially hori-( zontal permeabilities. During the various in-situ tests, the i shales restricted water flow in the vertical direction and the 3 water, taking the path of least resistance, flowed radially } and horizontally out from the tested interval. \\ residual soils, because Briefly, the numerous shale units and of their horizontal bedding structure, have permeabilities in the' vertical direction of several orders of magnitude less than in the horizontal direction. The in-situ permeability. tests performed were adequate for measuring these values, and the: horizontal permeabilities obtained are presented in Tables 2,4-6 and 2.4-7. f ~ ~ p 2.4.2.1.3 Consolidated Bedrock f Thesandstbneandlimestonebedrockbelowthe:. weathered s zones in the region yield. small quantities.of; water. to. wells. E 3(Merriam', 1963; and Bayne and Ward, 1967).- Their strati - u g raphyf and.. lithology are described in Section. 2.5. 6.1;; a...u detailed. site stratigraphic. column. is presented. on Figure.,.;u 2.5-9. The strata, as determined from borehole. data. range. .u cs upwards from. the Lansing Group (Missourian stage). of the (- Pennsylvanian System. The yield of water from wells in Nu these rocks ranges from 1 to 10 gallons per minute (Bayne and Ward, 1967). Practically all recharge is from rainfall and runoff, and occurs where the formations crop out at the surface. In the subsurface, the bedrock is commonly over-lain by shales and siltstones which partly confine and retard the vertical movement of water. - Only a few of the deeper bedrock units have any appreciable permeability; four of them are described in the following pa r ag ra ph s. There are no published reports on aquifiers in co ffey County. A summary of the hydrogeologic characteristics of the bedrock strata is given in Table 2.4-6. The Plattsmouth Limestone Member of the Oread. Formation is a fine-grained, medium-bedded, fossiliferous, slightly f rac-tured limestone with thir. shale and silty clay. layers. It is from 11,to 14 feet thick. It generally yields less than 1-gallon per minute of water to wells and has vertical fractures near the surface when weathered. The Plattsmouth Limestone 'Membr r, 'which is semiconfined by ~ the overlying Heumader shale Member, exhibited a slight seasonal artesian head in piezometers located in the plant site area. Th e top of the Plattsmouth Limestone at the j plant site is at an elevation of about 1,065 feet. The / 2.4-13 i [ -Ep. .s

~ ?

:wmp 1

s:c*5- '. jf'f s ' WCGS-ER (OLS )' l

  • ;* f

~ ^ piezometric surface of ground-water in the Plattsmouth Limestone has ranged in elevation from 1,064 to 1,069 feet, 5 fluctuating with var'iations in rainfall. The undisturbed piezometric level is about 1,068 feet (Figure 2.4-9). The estimated (conservative) permeabglityofthe Plattsmouth ' Limestone is very low (2.3 x 10 cm/sec, Table 2.4-6). At the WCGS site the Plattsmouth Limestone Member is un-weathered underneath the Heumader Shale Member. Further to the south, where the Plattsmouth is overlain by only a thin layer of shale or is exposed at the surface, the Plattsmouthi may be weathered, and its permeability is slight 1{gr_ eater. '.The Toronto Limestone Member of the Oread Formation is'14U 'to 19 feet thick, and is a fine-grained, thin to thick-bedded ~ climestone with pinpoint vugs, thin shale layers, and fossil fragment beds. Yields to wells are estimated to be less than 2 gallons per minute. The Toronto Limestone crops out east and south of the plant., ._ site. Discharge from this formation occurs in the valley of-

6. - Wo l f Cr e e k.

The.relatively impermeable nature 'of(the over J ~ .C"?? lying shale units reta rds vertical-wate r movement" except'- wh'er'e '.s the depth of weathering has extended downward throughl the.s if ' r ' (fsh a l e. In the' vicinity of the: site the Toronto Limestone isi " t 'under semi-artesian conditions','and its potentiometric '~2 1-U C-surface is at about elevation 1,054 (Figure 2.4-10).

Q u

The Ireland Member of the Lawrence Formation is a fine-grained, calcareous sandstone with interbedded siltstone and' laminated with clayey shale layers. It has some fractured zones and coal seams and'is from 40 to 117 feet thick. It yields small quantities of water to wells, estimated to be less than 0.5 gallon per minute. The formation exhibits an .artesian head at about elevation 1,049 in the vicinity of the site (Figure 2.4-11). It does not crop out in the valleys of nearby drainage areas. Fost recharge into the Ireland occurs where it. is exposed to land surface, approximately 6 to 10 miles east of the site. 'l The Tonganoxie Sandstone Member of the Stranger Formation ranges from 42 to 142 feet thick, is a fine-grained, slightly calcareous, micaceous sandstone interbedded with shale and siltstone, and has some vertical fractures. 'The- - 1 . Tonganoxie Sandstone yields to wells small.to moderate rquantities of water estimated at about 3 gallons.per minute._ 2.4.2.2 Ground-Water Recharge and Discharge 2.4.2.2.1 Recharge and Discharge in Alluvium and Weathered Bed rock Recharge to the alluvium is'from rainfall and the rivers jI during periods of flooding. Discharge is to the rivers as _/ L 2,4-14 i ~ o

.7, WCGS-ER(OLS) x >s' a '7 the ground-water table in the alluvium is normally above the g river surface. Within a 20-mile radius, the towns of New Strawn and Hartford obtain water from an alluvial aquifer (Figure 2.4-12). Recharge to the weathered rock aquifer is from rainfall and vertical percolation through the soils. The rate of infiltration is high, as demonstrated by the high degree of correlation between rainfall and water levels (Figure 2.4-13). During periods of drought, water levels in the weathered rocks j drop significantly (Broeker and Fishel, 1961). ~ A well inventory (Table 2.1-24) shows that there are num-erous dug wells within a 5-mile radius. Withdrawal from these wells constitutes an artificial discharge from the weathered bedrock. 2.4.2.2.2 Recharge and Discharge in Consolidated Bedrock Strata There is some cross-bed. leakage and' recharge to tha. bedrock" 5 ' strata as deep as the Toronto at the plant site. In the deeper bedrock strata, recharge is essentially by rainfall. t i and runoff where the formations crop out at the surface east f of the site. Pressure tests show that the shale zones about:. 40 feet below land surface have very low permeability (Table 2.4-7). The semi-artesian heads measured in the Plattsmouth ~ Limestone below the weathered bedrock indicate that the shale beds partly confine and retard the vertical movement of water from and to the limestone beds. The g round water frequently discharges from units lying within 30 to 50 feet below the stream beds in the low-lying areas. During the boring program, none of the formations yielded more than 2 gallons per minute in a 3-inch test hole. The permeability was determined by falling head permeability tests in the piezometers having slotted intervals for the various formations (Table 2.4-7). 2.4.2.3 Ground-Water Hydraulic Gradients Potentiometric contour maps for the Plattsmouth Limestone, Toronto Limestone, and the Ireland Sandstone are shown on Figures 2. 4-9 thro ug h 2. 4-11, respectively. The locations ( of the B-series piezometers are shown on Figure 2,4-14. The locations of the P, HS, and ESW-series piezometers are i 'shown on Figure 2. 4-15. A summary of water levelt, of each L B-series piezometer is given in Table 2.4-8. A summary of the P, HS, ESW, and LK-piezometer water levels is given in Table 2.4-9. - Fluctuations in shallow piezometers (Figure 2.4-16, Tables 2.4-8 and 2.4-9) reficct residual boring and testing effects, 2,4-15 l 1 l v:

. ipp{/ WCGS-rR (O LS) , V; f s. seasonal variations and sometimes nearby drilling and testing In operations. Water levels in the deeper piezometers fluctuate s.- 'less than a few feet in response to natural seasonal changes. The wa ter-table contour map of the ground-wa ter in the weathered rock zone generally reflects the topographic sur-face. In the site vicinity, the gradients range from 20 to 160 feet per mile. The direction of ground-water flow in the weathered rock zone is perpendicular to the g round-water . elevation 3ontour lines (Fig ure 2.4-6). I The g radient of the potentiometric surface of ground-water in the Plattsmouth and Toronto limestones tends to follcw Lhe local and regional structure of those rock layers. The Plattsmouth Limestone is hydraulically connected to the weatbr. red rock zone at the site area. The Heebner Shale retsrds the vertical movement of water and the transmission of head be'. ween the Plattsmouth and the Toronto limestones. The Irelanc' Sandstone does not crop out in the site area. 2.4.2.4 Ground-Water Models - Seepage from the Cool?ng Lake 7

2. 4. 2. 4.1 Introduction Seepage f rom the cooling lake was analyzed to assess.its ability to degrade grouni-water in the downgradient area x

by increasing the concen: ration of total dissolved solids 1..) ~~ (TDS) and radionuclides. The analysis included the effects of both normal and drought conditions. 2.4.2.4.2 Seepage When the cooling lake area is flooded, the following bed-rock tmits, which are exposed in the Wolf Ct eek Valley, will be inundated: Stull Shale Member, Clay Creek Limestone Member, Jackson Park Shale Member, Heumader Shale Member, Plattsmouth Limestone Member, Heebner Shale Member, Leaven-worth Limestone Member, Snyderville Shale Member, Toronto Limestone Member, and part of the Lawrence Forma tion. These units are shown in the Detailed Site Stratig raphic column (Fig ure 2.5-9) described in Section 2.5.6. A description of the water-bearing characteristics of these units is pre-sentad in Section 2.4.13 of the WCGS FSAR and Section 2,4. 2.1. 3 of thi s r e po r t. Water from the cooling lake may migrate through either.the inundated bedrock units, which dip gently to the southwest, oor through the weathered bedrock that serves as the lateral confinement for the lake. The bedrock units may transmit water from their outcrops in the inundated valley to their outcrop on the hill slope opposite the lake. For the analysis, the eastern and western ridges bordering the lake were divided 2.4-16

p h y,{ di hg; WCGS-ER(OLS) 1-1 :- %f ji into 10 sectors which have similar. geologic and seepage f0%, characteristics. The sectors are shown in Figure 2.4-17. The amount of seepage through bedrock units in each sector can be calculated using tha Darcy equation (Ferris and others f 1962): q = kla, [2.4-1) t where: q = (uantity of g round-wa te r-seepihg; through-the' - '01 ~ bedrock in a gi'ven sector', taken at' an average 1 width, of the sector (cubic feet per second); k*= permeability of'the bedrock unit (foot per year);.. ~ 'v i =. hydraulic gradient of the head dif ference b'etween' the cooling: lake. surface and the bottom of-the '.r.: bedrock unit: outside of the cooling. lake: divided: by. _r <. " : J.r.theihorizont'alidistance betweenithemi-t - ' ' :0 *1c: - r,- :3.-it 3:'; ,anyv. 3, 54 c:

2. :w.

.:: le sci; y a = cross-sectionalJ area; or: outcrop width multi' lied 'r p by the bed thickness, the values used age average z.: values: fo rL thel pa rticulara secto r. (feet ).n: ' 1.2 , ~,.f Table 2.4-10 lists the results of the analysis and shows ~ that seepage: f rom the. cooling lake will be negligible, about ~ 0.014 cfs.(6.1 gpm). That value was obtained using aver-age permeability values obtained f rom pressure testing (Table 2.4-6). If the maximum known permeabilities are used (Table 2.4-7), the seepage is calculated to be about 0.029 cfs (13.0 gpm). For conservatism, seepage was cal-culated for the weathered portions of the Jackson Park Shale, Heumader Shale, and other bedrock units cropping out around the cooling lake, but the construction of saddle dams.will significantly reduce seepage in those areas.. Quarrying of portions of the Plattsmouth and Toronto limestones during construction will not significantly increase the rate of seepage after the filling of the cooling lake.

2. 4. 2. 4. 3 Ground-Water Movement The actual rate of ground-water movement in response to the cooling lake will be very slow.. The g round-wa te r velocity-can be calculated' by modifying the Darcy equation:

v= 31 (2.4-2) n s 2.4-17

g6 y- .c.c ; '. i WCGS:-ER (O LS) ~

@$g(.s.

x .;)*; n

  • C
f.

w h e r e :..c z :.c 2 5:.! 6.' ;: : : 37 u.11.-is :.c.' fn :..'::*: v. .71-+.C'uzurit :.': :re a '. +:S

4. x: : n. a. '
Y

.3 v = velocity'(feet per year); .:.u. r;:sc 'l vi:r; . :..w. ~; ::'-

  • a-7

-.k-=e average,permeabili.ty (feet p.er: year); ~ i = hydraulic g radient; ~ n = effective porosity (estimated to be 5 percent based on examination of core). .: :c ' Fo r theiP.la.ttsmguthy Limestone. in. Secto r 3, k.=; 2. 3.8 f e.et pe r . year'(2.3 x3 1 03 J cm/se c, Table: 2. 4.-6),I l =.' O. 02 2,e n = 5 pe r-3 cent, 'and v:=2 1.04 feet per year. :Similarly,,forithe Jackson Parg and Heumader' Shale Members, k = 24.8 feet per year (2.4 x 10 cm/sec),: i:_= 0.065, n: =. 20 pe rcent, and. v. =; 8.1 f eet per year. The outcrop of the Plattsmouth that is closest to the. cooling, lake: is. about 2,500: feett away,: and,. cccording to this analysis, the time of travel:forc groundewater. for that distance: is about,2',400 years. s Fort ground-water to move 800 -- feet through^ the] Jackson: Pa rk: Shalet and: Heumaderi shale, the time of travel'would'be about 100 years... The time of travel toiwells D-4 2.i and.,- C-50.:.is: several: thousand> yea rsu s = c opc:svf e:n terc I2cisv 9.i:.?ocansid3 isd. stij g'd

2. 4. 2. 4. 4..i To tall Di ssolved: Solids: and.: Rad ionuclidec Con-s centrations in Ground Water 7:

"*3 c,.r c f. a c z ? r.. r u e r : : ' M.e c u : i:

ti O! t.;

'ST ..Q Data.on. exis, ting g' ound-wate r. quality: in the: site.> area..- are '2 2 r presented.in.Section 2.4.3.. The totali dissolved. solids - (TDS) concentrations and radionuclide concentrations which-are ex - pected to' occur.in the cooling lake due to routine operations are presented in Sections 3.6 and 5.2,.respectively. Due to the negligible seepage from the cooling lake,.the .i seepage 'will not significantly degrade the ground-water in the downgradient area. ~ :: .1

+:

i t. : e v cyc. : u.

st e r.m;' ? '.o 7:s:

'tJ - .. ~ ~ . >; M a 4 'l n Y ': : -.li ?'!i V..*3 ', ' i d'. ! :: */ ) !? :*.".M - l '.. * ; ?: ~.

noi s n :p. '-

& yt':1 D 1b ~ \\- ht:. : :,. e, sd j2 1 a 2.4-18 1 l ~;p f.++-, y,_..,.. .. 9. ....n.

_ + .. - - 3 a .c,1..A a sq: 2

. /

1 .*)- M BL1t 2.4-6 .etM ' sheet 1 of 3 '

  • =-

"J' .ts .4* yypanrv<wrv'IC OtARACTERISTICS OF BEDROCK WITitIN A 5-MILE RADIUS OF SITE F %i - f,. - 41 ' ~ Apgwoulmate(b) Typical (d) Ty,1 cal Rock t) nits --Physical hickness unter vield Permeability Yield Wil Depth And age Properties (feet) Characteristics (cs/sec) ( effen ) (feet) A11uviime sitt, elay,' sand, and syrevel in 0-30 9 mall to moderate 50 10--30 river channels. yields fross sand ^- aquifers in valley .,e n,. .t..41 botton 2 s Doniphan nhly lam 1Nated shales ' inter- -4(e)

35+,

Megligible 1.0uto shale bed &d fine grained medium - e d'* '[ t beddsd sandstone. Spring Branch h ier-b dded"(11mentxrne with [ ' 8+. M'egligible -4(e) 1.0x10 <1 Limestone inter 6ddedflaminated' shale. L s ........ a a,, .s .s. A- . h~ sut stull Shale nin1r 1minated shales inter, 50+I very small yields 2.0x10 <t if -S te ) bed &d fine-Trained sandstone t from sand lenses g i & Jaminated's11tstone.* g t. e.a m - s

  • Lt t

Clay Creek

  • hin-to medine bedded, fine-Ts Megligible 6.1x10

<1 W -6(e) M 7.t se s tone grained limestone. m O Jact.,on Park Winly laminated shale with And 4 , 17-30 very small yields 4.4u10 <3 p Shale terbedded limestone & sandstone.

  • "
  • C tt) y.

1.1mestone nin-bedded [ fine grained lime " -- O c, Member of very small yields

  • 9 10 s

stone with ' mand's shale semes. -g'ed N . Jackson Park e l* t a. s O Shale ,+ e t Heumade r h inly las!Antad' shales line* i J"i Shale stone lenses at base. s E 19'-34' Meg'11gible 3.0x10' <3 ,. g. ' f y. Plattamouth h in~ to'thi'c -bedded,** fine- '?J g - --- .s 7 t 11-1'3 [, EhA11'ylelds ~ (1 10-4 0 'i 2.3x10 Limestone grained linentenes inter * 'L bedded thinly le=1 mated 33. shale. 1 *****No. *** * ..'M** c_ ~* 'x. '.. p.

d b...i.i

' ~ ,$[t%II - d.u..*... . ~

j. 4

, hysical properties from informations presented in Section.2.5.... M='*., 4 e ap p,shr- '-d* P g n.' b -r W Range of thickness encountered in Boringe D-1 throug"h,5-21.' A

  • J-) ;.

, Average permeabilities fron' pressure tests in Borinaps 9-1gthrough A-21. .,~.q, .w e. g ..,,, + ..s. A i TYP cal yield estimated from known well usage in dog and drilled wells. y' @ h y!' ' Measured from treasure testa'in borings in cooling lake area. *, ,/ ;. ..i, -.?t. g%~1' }' j/ 'j.. y- . _.... i.aAM 1 - Or ~ - ^ - - ~ r t

B . Y [s ;. a .ah f ** w*s498 16 t%.uS5

  • 4...

4....e s pr,., 4..v... ,s.a.s

a. w pm a o-Ts

^ % t a* aid. **'s M f ! 34,**'# 1 I C e . shee t 2 of 3 - v.u k pT M.2.4-61(continued) ..w . a t. p...,....*i.- I s s.' la se s.. s ;.q s e, .. o r . W.% J. s *. t.l. m. o i .o AEI* *i"*t*(b) Typical (d) Typical a .. 4s istoisu ev( m'T *" '8 Id ~# anck Unite. ....a M Physical - Wickness,' W ter Yield Permeabl?'.Q Yield neell Depth and Aspe Properties (feet) characteristice (cm/sev-l (errmal '(feet) -t. sneebner shale h inly laminated, fissile. 2.5-4 1segligible 1.0 x 1 r. ca rbonaceous' shal's."'

v.. %

. 3 4+ '4 e

  • Y s

7 Ja.3., - hgligible 3.7x10 1.eavennsorth Meditum-bedded',' fine-gralmed 0 Limestone limestone.

  • =...

.imagligible 1.1m10 -6 anyderwille faminatad-to'thim-bedded shale. '5-14 ~ shale .64' -6 j' goronto a Win ' to thick-Lhad, fine-

14-19 '

flaall yields 1.2x10 <2 10-75 L '. < h.... shale partings a lenses.' 1.ime stone grained limestonee rare

fY l

s. 6 Unnamed Winly laminated shale..s interZ. 18-30. - Possibly small 1.eut0 . Lawrence i bedded,.immtmated to' thin-bedded, . yields from ,dN sandstone 1 sandstone.. O ,3 .,, e.its i.t 1.0u10.,* .y a Amazoniaa Win-to mediwbedded, fine- - 2-18.. - W9 1 1ble 1 9 Limestome grained, shaley limestonet g g qi n interbedded," thinly laminated M-shal,.. .A.., + y-e r., 6o,. ...e. p s g.iws *..s *

  • s *
  • ec1* -

.% w ~ -6 O Ireland W inly imminated shales,crose- '340-108' Possibly very small 3.3x10 0.5 p Q Sandstone bedded,-lamishted to medissa yields from sand-m p. bedded, afine grained sand-stone layers stone. . o. s.m.., -7 sobbine ninly laminated shales' thin 14-90' ' niegligible 2.6u10 Shale-to meditan bedded, s'haley

  • i #= * -

p;. limestone. _ -.~4.......... Vs ~. 7 b'U.'[ *?.' c> stankell W in-to thick-beddeds fine-A ! 1-3.,. , inegligible

2. tut 0 Limestone grained limestone.

i [.U ' l **~ ; -

  • 85f + *.*

'..b-i;*'* 0-W. c. W. '.' /. . ' W' ' ' 3 f. > .;. e.

a. *s 5-

~ > -.. i i 6 .b y;}. .,v. Vinland. Winly lamin,sted.to' thin 1 bedded.; g Q y145( / .. Diegl g ble 3.00 0 /'p ' ,, Shale; _,, shales,interbedded, discontinuous,4' ' {8 ' O " -g p y g -*--- *-**g y j'.. M t%1n-to medium. bedded, very fine l s e.pg giudre. > ..<..s. V.e..- p"., 'f/ l. *,* A2-8 t. 9s* a to medtimm grained sandstone. .cwL'.abst.esu.u5*).

  • eu a v.a e.

s -

  • g

.g. 3, Wr,-. ,. 1 7 toestphalia - ."finin-to emeditsm-bedded shaley . 0-13 Possibly very 4.9x10 Limestone limestone. maall yields .: t se ttd'.\\.%t.'e@ V.. 'Q42 NYT**F "S'unall yields 2.8u10' 3 200-300

  • 1 J

Tonganorte %1aly lamin ed to thiss-bedded, V-. Sandstone clayey shalesiinterbedded with* f h} '. crose-bedded.jlaminated to - 3h '.' 'I;*# '

  • .3>(f h,,9 meditie-bedded. sandstone and c

i t e A:, y 2 siltstone. M... ' n.@ M - f e- . c. v s-

i., l <

..':s, w. g, as i64. / W-.

I

< *v, 4 .. = ' g'/.~i'[ r.'t.' I' .[ * .#,+ i.' f. e a .s' ' *, i.

G.

' G .. f ~ f%. i, s

e. r..a

.r n v,.c) .,) y: .s., . j 'YW* A k

., ; y, g g. ,g,,7 ..;. 2,,w=

g.

g4 g__ _ g y. 1 u {e,,... :-) - 1~., g taatz 2.4-6 teontinued) Sh**t3of3 Approminate(b) Typteal(d) Typteal mock tamits . Physical Thickness - mter Yield Permeability Yield Well Depth And Age Properties (feet) - Characteristica (cia /sec) (grun) (feet) si ..e. Weston Shale - h inly laminated shale. ~31-109 ,' toegligible' ' j 9.2x10 4.- 4 -s South Bend M ick-to thin-beddeds fine-4-6

  • toegligible' 3.8x10 Limestone

". grained limestonea sandy i - at base. 4 r .eO~ O e. 4 .4. c t.n. g t M c. y '+ m o-T, i M. cn ~ g v s e 1. i. - o i. .e t 4 4 }. a :. .. s n ,1 a e a w- .o 4 i - k 4 i O E k g4 q g 9 j v u. r, w 4t s t s -g g 'k. e n 2. . s- -.--.-+.--u-_----~,__em u2- , 3v v 4i m . + + '- - - - -

WCGS-ER (OLS)' I TABLE 2.4-7 FERr,EABILITIES CF ROCK UNITS (a,b) BY DEPTH Fermeability (cm/sec) 0 - 20 Feet Creater Than 20 Feet Weighted 'I Weighted Range I I f_ Rock Units (g) Average Rance Average -5 -5 -5 ,,(d) .,(d) Alluvium 3x10 2x10 to 4x10 6 ,,(d) ,,(d) Doniphan 5x10 Shale -6 -5 ,,(d) ,, ( d') ~ Spring Branch 4x10 3x10" to 7x10 Limestone -6 2x10~ 3x10 to 4x10 Stull Shale s Clay Creek Lime sto ne -5 ~7 -5 -6 ~ Jackson Park 4x10 5x10 to 5x10 4x10 9x10 to 1x10 ~ l Shale ~7 -5 ~7 -6 6x10'0 3x10 to 3x10 6x10" 5x10 to 8x10 Heucader Shale -5 -6 ~4 -6 ~7 -5 .Plattsmot.th 2x'.0 4x10 to 2x10 2x10 1x10 _to[3x10 l Limestone l ~0 -6 ~ ~7 Heebner 4x10 1x10 g to 2x10 Shale ~7 -6 9 to 4xly0 4x10~ 2x10" to 4x10 Leavenworth 1x10 Limestone ~7 ~0 ~0 ~ Snyderville 1x10 7 te., 4x'0 6x10 F to 9x10 Shale ~0 -6 -5 1x10 F to 5x10 Toronto 2x10 Limestone -5 -6 -5 Unnamed Lawrence 2x10 7 to 6x10~ 2x10 7 to 2x10 Shale -6 -5 3x10 g to 3x10 ~ Amazonia 2x10 Limestone ~0 -5 d ,,d 4d0 9 to 2x10 Ireland Sandstone ~7 d ,,d 1x10"

  1. to 1x10 Rotbins Shale 1
  • Typical permeab!!!ttes for units below the Robbins Shale are presented in Table 2.4-6.

bNumbers refer to the depths below ground surf ace for which the indicated per-meability values are valid.

  1. Lithologic descriptions are presented in Table 2.4-6.

Unit not penetrated at this depth in the test borings. ' Weighted averages were calculated f rom water pressure test data by summing over the thickness of each formation, the product of the permeability, and the thick-ness over knich it was applicable. Then the sum was divided by the formation ~ thickness.

  1. Fepresents 'no take* during test.

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