ML20058P288

Draft Ground-Water Quality Assessment Plan,Siemens Power Corp Richland,Wa

ML20058P288
Person / Time
Site:	Framatome ANP Richland
Issue date:	05/25/1993
From:	Bower J, Keith S, Roberts L GERAGHTY & MILLER, INC.
To:
Shared Package
ML20058P268	List: ML20058P264 ML20058P284 ML20058P288 ML20058P295
References
PROC-930525, NUDOCS 9310220197
Download: ML20058P288 (29)

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i GROUND-WATER QUALITY j

ASSESSMENT PLANA SIEMENS POWER CORPORATION RICHLAND, WASHINGTdN t

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PROJECT NO TVA183.08 i

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. s May ,1993 li Prepared by 1 Geraghty & Miller,Inc. Environmental Services 8330154th Avenue Northeast p Redmond, Washington 98052-3864 (206) 869-6321 t t l . r. k 9310220197 930927 p.L t PDR ADDCK 07001257 4 C. PDR ad

1 ] GROUND-WATER QUALITY ASSESSMENT PLAN SIEMENS POWER CORPORATION ] RICHLAND, WASHINGTON ] May 25,1993 Geraghty & Miller,Inc. is submitting this report to Siemens Power Corporation for work performed for their Richland, Washington facility. The report was prepared in conformance with Geraghty & Miller's strict qu ty surance/ quality control 7 ar in terms of the methods 3 procedures to ensure that the report meets indust used and the information presented. If you ha questi comments concerning ] this report, please contact one of the indivi u l'te below. es ectfully submitted, ERAGHTY & MILLER, INC. ) O 1 Larry E. Roberts Project Scientist Jay P. Bower Senior Engineer / Project Manager 4 Susan J. Keith Principal Scientist and Associate / Project Officer d ll GERAGHTY & M]LLER,INC.

i CONTENTS a .Eage. 1 ']' INTRO DU CTI ON............................................... 1 GROUND-WATER MONITORING SYSTEM......................... 2 ] MONITORING PARAMETERS AND FREQUENCY................... 2 ' ] SAMPLING AND ANALYSIS METHODS............................ 3 ~ 3 SAMPLING PREPARATION............... EQUIPMENT CALIBRATION.............................. 4 j WELL INSPECTION................ 5 GROUND-WATER LEVEL MEASURE 5 TOTAL DEI'rH MEASUREMENT 6 j WELL PURGING................. 7 SAMPLE COLLECTION................................. 8 EQUIPMENT DECONTAhflN4TIOR......................... 10 -] SAMPLE PRESERVATIO HIPM 10 SAMPLE ANALYSIS....... .....................10 ) QUALITY ASSURAN F,/Q1J . NTROL...................... 11 CHAIN-OF-CQSTOI)Y PRO. pURES........................ 11 DATA V . DATIO ROSEDURES......................... 12 DATA E OO D EPORTING.......................... 12 DATA VALp O 12 - l-REP 'Il y........................................... 13 1 sCnE D uLE.................................................. 13 ] RE FE REN CES................................................ 14 ] 1 ] 3 j .4 al ) GERAGHTY & MILLER.INC.

[] J r-TABLES 1. Monitoring Well Construction Summary l] 2. Ground-Water Sampling Equipment Checklist 3. Summary of Sample Preservatives, Holding Tunes, and Analytical Methods .) _ 4. Summary of Ground-Water Sampling Requirements D } t )' FIGURES ] 1. Site Location Map 2. Monitoring Well I.ncations 3. Water Sampling Log 4. Calibration Lo 5. Groun -Wat Level eas ent Form pl b 6. S-7. Chain- - Form 8. Chain-of-Custody Seal ] APPENDICES A. Quality Assurance Project Plan (QAPP) B. Imboratory Quality Assurance Plan d ] GERAGHTY & MILLER,1NC. 4

) GROUND WATER QUALITY ASSESSMENT PIAN SIEMENS POWER CORPORATION RICHLAND, WASHINGTON j INTRODUCTION j j This Ground-Water Quality Assessment Plan (Plan) documents the procedures to be used for the ground-water monitoring program at the Siemens Power Corporation ] (SPC) facility in Richland, Washington (Figure 1). The Plan is designed to fulfill the interim status ground-water monitoring requirements of bo the Resource Conservation j and Recovery Act (RCRA; implementing regulatio fo d at 40 CFR 265.90 and e ad ement Act (HWMA; 265.93) and the Washington State Hazardou j implementing regulations at WAC 173-303 ) The focus of this ground-wa er rin p gram is to provide monitoring of the ground water downgrad'ent f th s face i ment area,which is located in the stili y (h 2). This area is identified in SPC's Part A } castern portion of the Permit Application. gqneral rec uiren ents for ground water monitoring are outlined at Th ' orgoing ground-water monitoring at the site has shown that 40 CFR 26 0 e-t the ground-wa er adient of the surface impoundments has been impacted, this Ground-Water Quality Assessment Plan has been prepared and will be implemented under 40 CFR 265.93, in lieu of the standard interim status ground-water monitoring program outlined at 40 CFR 265.91 and 265.92. A Ground-Water Quality Assessment Plan must specify the number, location, and depth of each monitoring well; sampling and analytical methods; data evaluation procedures, including any use of previously gathered SPC will be ground water quality information; and a schedule of implementation. responsible for implementation of this Plan. The following sections discuss the physical monitoring system, monitoring parameters and frequency, sampling and analysis methods, quality assurance / quality control, and data evaluation and reporting. 1 l GERAGHTY & MILLER,INC.

T' L 2 7 GROUND-WATER MONITORING SYSTEM The locations of the monitoring wells to be sampled under this Plan are shown on Figure 2. The monitoring wells will be used to provide ground-water level and water-quality data for delineation of ground-water flow patterns and constituent distributions. Wells GM-1 and GM-2 are located upgradient and cross-gradient, respectively, from the } surface impoundments and provide data indicative of background water quality relative to the surface impoundments. Wells GM-5, GM-6, GM-7,,6 1-8, and GM-16 provide data indicative of water quality downgradient of 11 e su ace impoundments. The construction details for the monitoring wells, in e inghir ocations and depth, are ~ provided in Table 1. ) m MONITORING PIR1dhiETERS AND FREOUENCY R 9 Ground-water s i be a yze m the field for pH, temperature, and specific conductance d he for the following analytes / parameters: hp nitrate phosphate arumonm lu'rgintIy sodium a chicium sulfate chloTde tributyl phosphate a fluoride trichloroethene (TCE) gross alpha zirconium = gross beta Ground-water samples will be collected from the seven monitoring wells and analyzed on a quarterly basis. A Water Sampling Log (Figure 3) will be completed for each sample and will document well evacuation procedures, field parameter measurement data, and sample collection data. GERAGHTY & MILLER,INC.

-l f ) SAMPLING AND ANALYSIS METHODS } -} The following procedures will be used by all field personnel when conducting sampling activities at the SPC site. All field activities will be documented in a bound ] field notebook using a permanent, water-proof pen. Information to be recorded in the notebook will include the following: ] Date i Weather conditions ) Names of the field team members Times of site arrival and departure Documentation of all field activi ' s '] Equipment malfunction Equipment calibration Odd or unusual occu es } Site visitors. = b ) The field noteb e, sign d the Field Supervisor at the end of each day of field work. SAMPLI 10 1 Prior to imp ing, field personnel will assemble the equipment identified in i ] Table 2. All equipment will be checked to ensure that it is in proper working order. t Equipment that will come into contact with ground water will be decontaminated before use (see Equipment Decontamination section below). Field testing equipment (pH 7 meter, conductivity meter, thermometer) will be tested and calibrated at the beginning of each day of sampling (see Equipment Calibration section). Sample containers will be provided by the laboratory and will contain the - appropriate preservatives (Table 3). To ensure preparedness in the field, sample bottles will be counted and labeled before the sampling event and extra sample bottles will be included in anticipation of possible breakage. } GERAGHTY & M]LLER,1NC.

1 i 4 If the field sampling team is arriving from offsite (i.e. non-SPC sampling team), } the Field Supervisor will make arrangements for site access prior to leaving for the SPC ) site. Upon arrival at the site, the field team will check in at the security gate and with a local SPC representative. At that time, field personnel can be apprised of site conditions. } { Samples will be collected first from upgradient Wells GM-1 and GM-2 to reduce the potential for cross-contamination between wells and s - es. Upon arrival at the o wind of the well. Field j sampling location, the field vehicle will be parked personnel will not smoke, drink, or eat during pling n will avoid handling any } objects not necessary for performing sampli p ce res. arl' nitrile or vinyl gloves will be worn when handling any field equip nt ples. Gloves will be changed or h decontaminated as necessary to pr ve t ss-c nt ' nation. f EQUIPMENT CALIBRA uirin calibration will be calibrated to known standards h All fieMp e r prior to u i the fi d. I ments and standards to be used while conducting field h work at the ar the.following: r Instrument Calibration Standard g pH meter pH 4.0,7.0, and 10.0 buffer solutions (a two-point calibration will be performed with two M standards which bracket the ground-water pH) l , II W Specific conductance meter Dry air to zero the instrument, 1,413 micrombos per centimeter (pmbos/cm) solution of potassium chloride for slope g adjustment (a similar standard potassium chloride solution, e.g.,2,000 pmhos/cm, may be substituted) ,g

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1 5 The manufacturer's instructions for calibration of the pH and specific conductance meters will be followed during calibration. An entry in the Calibration log (Figure 4) will be completed each time the instruments are calibrated. Readings on two thermometers will be compared to assess proper calibration; temperature readings made with a thermometer may also be compared with the temperature meter on the pH or specific conductance probe. If equipment cannot be calibrated or becomes inoperable due to damage, it*. sage will be discorainued until the necessary repairs are made. In the interim, a caliL ated replacement will be obtained andpsed. It is the responsibility o roperly maintained and in of the Field Supervisor to ensure that all instrumen re working order prior to use in the field. WELL INSPECTION y for damage due to maintenance All monitoring wells ill be i e r { vehicles or weathering. 'el-hea w'll be mspected for damage to security casing, lock, and identificatio n .r. Any age will be noted on the Water Sampling Log h (Figure 3). t e etion quired, if any, will be denoted on this form and carried o t by the p op personnel (see the Quality Assurance Project Plan ~ h [QAPP], A en J. lie completed forms will be maintained with the ground-water quality data an g e available for review by appropriate regulatory agencies. O t GROUND-WATER LEVEL MEASUREMENT The static water level in all monitoring wells will be measured with an electric-probe prior to sampling any wells. Water levels in all wells will be measured on the same day to obtain the most accurate representation of the water table. A minimum of two consistent measurements will be taken at each well to confirm the accuracy of the measurement. Measurements will be considered consistent if they are within 0.005 feet of each other. 0 h GERAGHTY & MILLER,1NC. a )

I 6 Each well has a clearly and permanently marked measuring point at the top of its casing. The measuring point on each well has been surveyed to determine its elevation with reference to an established datum. Depth to water measurements will be measured relative to this point. The proper operation of the electric probe will be verified prior to measurement j by inserting the probe into a container of water to ensure that contact is clearly indicated on the meter. The probe will then be lowered slowly into well. When the electric probe registers contact with the ground water, the rea ' g the tape at the measuring ( point will be noted to the nearest 0.01 feet. The.ctric ob will be decontaminated j before the first measurement and between es h labor grade, nonphosphate detergent and rinsed with deionized or disti d a. 1 rded on a Ground-Water level Each water-level measurement w I be e the the date and time of the measurement, the ] Measurement Form (F r r 5' type and serial numbe ur device, and the initials of the person taking the .\\ measuremen The a er-1 el me urement will also be recorded on the Water h3 3 Sampling \\ TOTAL DEPTHgEASUREMENT The total depth of each well will be measured prior to sampling. The total depth will be measured from the measuring point at the top of the casing by lowering a weighted steel tape or cable until the weight is felt resting on the bottom of the well. Appropriate weights will be available and used as necessary to provide accurcie definition of the total well depth. The sounding line will be decontaminated between each measurement with a laboratory-grade, nonphosphate detergent and rinsed with ) deionized or distilled water. 11 GERAGHTY & MILLER,INC. l

I 7 j Measurements will be recorded to the nearest 0.1 feet on the Water Sampling i Img (Figure 3). The total depth measurements will be used to confirm that the proper well has been identified and that the well has not filled with silt, and to accurately calculate the volume of water standing in the well. The silt will be removed if more h than 1 foot has accumulated in the bottom of the well. h WELL PURGING h The volume of water standing in the well wil be c. culated by subtracting the depth-to-water measurement from the total depth o te I a d multiplying the result h by the number of gallons per linear foot of te n11 well. le allonsperlinearfoot { is a function of the well casing diameter an s ined from values tabulated on the d Water Sampling Img (Figure 3). o to mp 'ng, s minimum of three well volumes dg submersible pump. All calculations will be purged from each w I gan, h After the well has been purged, the pump will be recorded on th ra will be removed fium e ,a contaminated (see Equipment Decontamination y section). T l The p, speci onductance, and temperature of the discharged water will be measured at le Uhree times during purging (after each well volume is removed). The - . 7 i. pH will be considered stable when two consecutive measurements agree within 0.2 standard units. Temperature will be considered stable when two consecutive 4 casurements agree within 0.2 degrees centigrade, and specific conductance will be wnsidered stable when two consecutive readings are within 10 percent of each other. If the pH, temperature, and specific conductance do not stabilize within the designated purging volume, then purging will continue until the readings have stabilized or until the Field Supervisor indicates that further purging is unnecessary. The purge water will be pumped into 55 gallon drums and held on-site pending g. analytical results to ensure proper disposition. The date, well identification, and drum h GERAGHTY & MILLER,INC.

I 1 8 identification number will be clearly marked on the outside of each drum using a I-permanent marker. A log of each drum, the volume and source (s) of purge water that. it contains, and its location will be maintained in the field notebook. A copy of this log will be maintained at the SPC facility. I SAMPLE COLLECTION 1 Samples willbe collected with a Teflon

• bailer on clepayylon cord. The Teflon bailer will be slowly lowered into the well, filled, and r ' sed the surface. Care will be taken to prevent agitation of ground-water in aucil.

e ground-water will be collected in the bailer and discarded two t' fore col cti a sample. On the tbgh a bottom-emptying Teflon second time, the ground-water will be disca e g spigot. Caps on the sam ntai rs il e le m place untiljust before filling. When the cap is removed frnm am leg tainer, care will be taken not to touch the lip of the bottle, heInil tir Teflon

• cap, or the mouth of the Teflon
• spigot. The sample b tie. be 9d ly by directing the stream of water, out of the spigot, at

] an angle so ha 't draib down the inner side of the sample bottle. This will help prevent the lo ervative and discourage air bubbles from becoming trapped in h the sample bottle. Care will be taken to avoid splashing or agitating the water while the bottle is being filled. Each bailer of water will be divided evenly between bottles of a h single type of analysis, to give representative samples. h For bottles requiring zero headspace (volatile organic analyses), the bottle will be filled completely so that h meniscus forms over the mouth. The bottle will be capped immediately, turned upside-down, and tapped at least twice to check for air bubbles in the sample. If a bubble exists, the sample will be discarded and the sampling procedure will be repeated until a bubble-free sample is obtained. O h GERAGHTY & MILLER,1NC.

1 1 9 After each sample bottle is filled and capped, the sample label identifymg the sample location, date and time of sampling, matrix, type of peservative, and initials of j sampling personnel will be completed with permanent, water-proof ink. (Alternatively, the sample will be collected in appropriately pre-labelled bottles.) An example of a j sample label is provided in Figure 6. Samples will be placed in a moler with double-bagged water ice or frozen reusable ice packs, and repacked with ice as necessary, for } storage and transport to the laboratory. co uctance) will be measured } Field parameters (pH, temperature, and speci by filling a cleanTeflon or glassbeakerwith apon b rs ple and placing the pH } and specific conductance meters and a thermometerin the b k. Measurements will be recorded on the Water Sampling Log ( The color, odor, and appearance \\ h of the sample, and other pertinen s obs ons will also be recorded on the Water Sampling Log. T 6 Quality contro a _e be ected in the field include equipment rinsate h blants,due , and trip nks. Rinsate blanks will be collected for each day mple\\ will be collected at a frequency of no less than 1 per 20 of samplin. ae h sample setske e duplicate sample will be collected if there are less than 20 sample sets, two will be qqlle ed if there are between 20 and 40 sample sets). Trip blanks will be included in coolers used to transport volatile organic samples. Equipment rinsate blanks will be collected by pouring analyte-free, deionized water through a decontaminated sampling bailer and filling a full set of sample bottles. J' Duplicate samples will be collected by filling two sets of sample bottles with ground water from a single well. Trip blanks will be prepared by the laboratory and will not be opened during sampling. (Trip blanks will be analyzed only for volatile organic constituents.) Quality control samples and procedures are discussed further in the QAPP (Appendix A). 1 l GERAGHTY & MILLER,1NC.

I. 10 EQUIPMENT DECONTAMINATION Reusable sampling equipment, including the equipment used to measure field g parameters, will be decontaminated prior to use and after the collection of each sample set to avoid chemical cross-contamination of field samples. Equipment will be j decontaminated by washing with a laboratory-grade, nonphosphate detergent and rinsing with distilled or deionized water. Wash and rinse water will be retained with the purge ,g water pending analytical results to ensure proper disposal. ,h Interior and exterior surfaces of the subme s' lepu d associated power cord g and discharge tubing will be decontaminate 4 t each use s bbing and operating nonphosphate detergent solution the pump in a container filkd with a laborat - ra y and then in a container filled with isti or ionized water. D h All field perso e cla n m rile or vinyl gloves when conducting equipment decontami atmn } n SAMPLE 'RESERVAT O 4hD SHIPMENT The typ ofhottles and preservatives required for each type of ground water analysis are identified in Table 3. All water samples will be stored in a cooler with double-bagged water ice or frozen reusable ice packs immediately after collection. The ice will be distributed evenly so that all samples are in physical contact with the bagged ice. The cooler of filled sample containers will be transported by courier or a member of the sampling team to the laboratory for analysis. SAMPLE ANALYSIS h The analytical procedures to be conducted on ground-water samples are specified in Table 4. Temperature, pH, and specific conductance will be measured in the field GERAGHTY & MILLER,INC. e w

I 11 according to instrument manufacturers' instructions. Laboratory protocol, quality control procedures, and data reporting requirements are discussed in the QAPP (Appendix A). ^ A copy of the currently-contracted laboratory's Quality Assurance Plan is provided in Appendix B. OUALITY ASSURANCE /OUALITY CONTROL Tl CIIAIN OF-CUSTODY PROCEDURES g 0 Sample custody is a vital aspect of ground-aterf$n\\ ' g stu ito must be traceable from the time of sample I ton throu time of analysis. To { ensure this is the case for each sample collec. d PC site the following procedures will be observed. { { All samples wil e aini h ody of the sampling personnel during each ach san mg day and prior to the transfer of the samples sampling day. At the en q@/ \\ 4Eiiiimf-cust6qy en rie)s will be made for all samples using a Chain-of- { to the couri Custody e ) mples may also be transported to the laboratory by a 1 member of .e sam in team.) One Chain-of-Custody Form will be completed for each cooler of sam \\ples 11 information on the Chain-of-Custody Form and the sample r j container labels will be checked against the sampling log entries, and samples will be recounted before transferring custody. Upon transfer of custody to the courier, the h Chain-of-Custody Form will be signed by a member of the field team, sealed in plastic, and taped to the inside lid of the cooler. A signed, dated Custody Seal (Figure 8) will be placed over the lid opening of the h sample cooler to indicate if the cooler is opened during shipment. All Chain-of-Custody Forms received by the laboratory must be signed and dated by the laboratory's sample h custodian, 0 h GERAGHTY & MILLER,INC.

1 12 The sample receiving personnel at the laboratory will note the condition of each sample received as well as questions or observations concerning sample integrity. The laboratory personnel will also maintain a sample-tracking record that will follow each sample through all stages of laboratory processing. The sample tracking records will show the date of sample extraction and sample analysis. These records will be used to p determine compliance with holding time limits during laboratory audits and data validation. 7 DATA VALIDATION PROCEDURES L T' Analytical results willbe reviewed an y ed by a Assurance Manager. e tt se data for which quality control Appropriate data qualifier codes will be ap \\> ata quality acceptance criteria are parameters do not meet acceptab st ard ency (USEPA) Laboratory Data specified in the U.S. Environment b)htec io / ata validation procedures are discussed in } Functional Guideline U 988 di detail in the OAPP ( pe{3 x DAT EVALUATION AND REPORTING This section tlines the procedures to be used to evaluate the data collected under the Plan and the requirements for reporting this information to regulatory ] agencies. DATA EVALUATION 1 Water-level data will be evaluated spatially and temporally by preparing water-table contour maps and hydrographs. The water-table contour maps will be used to determine ground-water flow directions and horizontal gradients. The gradients will be used to estimate ground-water flow rates. The hydrographs will be examined for temporal trends in the water levels at each of the wells. l GERAGHTY & MILLER,1NC.

13 ~ Water-quality data will be evaluated qualitatively using areal plots of constituent distributions and temporal trend plots. The areal plots will be used to identify the spatial extent of elevated constituent concentrations. The trend plots will be evalua for temporal patterns in constituent concentrations at the monitoring wells to determin whether concentrations are increasing, decreasing, or stable through time. Water-quality data generated from the ongoing sampling of the wells identified in this plan will be us in constructing the trend plots to provide a sufficient quantity of data for trend evaluation. REPORTING Results of the ground-water sampling da s and the data evaluation process described above will be reported e W bi ; ton State Department of Ecology } a licat n and evaluation. The report will (Ecology) on a quarterly basis followin ], also include any reco a o iT ns to the Plan. Recommendations will be implemented following concurrene sti the proposed modifications from Ecology. ] SCHEDULE This Platqgli e implemented within 3 months after the date this document is 1 h finalized. Ground-water sampling and reporting will continue on a quarterly basis as j outlined in the Plan throughout the interim status period. Q 1 1 l h \\ GERAGHTY & MILLER,INC. i

I REFERENCES U.S. Environmental Protection Agency (USEPA).1988a. Laboratory Data Validation Functional Guidelines for Evaluating Organic Analyses, February 1988. .1988b. Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, July 1988. .D. 0 0 0 D 0 0 rL + 1 0 m e = I ,N I i y -0 h GERAGHTY & MILLER,INC.

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SUMMARY

SIEMENS POWER CORPORATION. RICHLAND. WASHING TON PROJECT NO. WA183.08 Well Date Screened Boring Measuring Point Concrete Pad North East Well10 Diameter installed Interval Depth Elevation Elevation Coordinate Coordinate Wolf Type (In) (ft bis) (ft bis) - (ft mis) + (ft mis) (ft)* (ft)* / GM-1 2 164ct-91 14.8 -34.8 d5.0, 375.44 374.04 371.320 2.303.233 StaWess steel screen /PVC riser GM-2 2 15-Oct-91 7.3-27.3 k 28.$ 370.09 368.49 371.746 2.302.437 StaWess steel screen /PVC riser GM-5 2 234ct-91 4.8 - 24.8 25.0 (,,/ 567.41 365.80 372.865 2.303.321 Stainless steel screen /PVC riser GM-6 2 234ct-91 20.0-40.0 40.2 380.07 'g\\ 379.47 372.776 2,303.864 Stainless steel screen /PVC riser - GM-7 2 224ct-91 20.4-40.4 40.6 33089,/ 379.61 373.030 2.303.807 StaWess steel screen /PVC riser h GM-8 2' 214ct-91 12.8-32.8 33.0 ,372.48 \\ 'g 370.92 373.145 2.303.534 Stainless steel screen /PVC riser (*375.e3. N / 374.31 372.866 2.303.593 Stalniess steel screen /FVC riser GM-18 2 30-Mar-92 15.0 35.0 42.0 ) 1 Updated to May 1992 data provided by Bob Stratton Surveyl ~, + North American Datum 1927 (NAD 27) 77 ft Feet ...q ,e /' / ft msi Feet above mean sea level \\ ? / ft bis Feet below land surface ( /,/ /\\ .3 In inches' s s H:\\SPC\\WA18306\\GWPLANTWELLCON.WQ2 \\ s ! [\\ D / b ~ GERAGHTY 6 MILLER,INC. 2 ._._-.m.um.. _.._a___ _.s.__ _m_____m_-_ -m_

TABLE 2 EQUIPMENT CHECKLIST FOR GROUND-WATER SAMPLING - AT SIEMENS POWER CORPORATION DATE DECONAMINATION WELL PURGING _2" submersible pump _decon tubs (2) _ pump control box _ purge water buckets (4) distilled water (@ SPC) discharge hose _ generator (Honda 5000) [liquinax ~ _DI water sorayer _ extension cord _ detergent spray bottle _solinst w.l. meter (@SPC) _ steel sounding tape _ scrub brushes (2-3) _ baiter brush , _cafculator i _ nitrile gtoves _ sump pump _ trash baga _25 ft hose _ aper towels p clean wat

• oc SAMPLING

_ plastic sheeting S P RANSPOR drum liners in-f-o forms bailer cord lab sk or r latex surgical gloves teflon baifer (2) _ chain-f ct. tody seats F x ipp g icpe _ teflon spigot (2) ippi 1-is _ sampling caddy (2) _1000 ml glass beaker (2) MISCELLANEOUS _1000 mi na! gene beak 2) weli keys _pH/:. ad./ temp. meter - extra batteries: _ measuring tape y _ straps, bungie cords or extra rope M _ AA Durac _Ziploc bags (1 gal & 1qt size) _ 1.4v Ev re (EP 5H field file box thermom 'er l _ field notebook _sampfe be, s _sarhpie labels _t6o! box: _ utility knife / scissors _ coolers _ ice (@ SPC ) _ screwdrivers (assorted) _ aterproof pens _ hammer w pliers Sharpies ~ [ water sampling logs _ fishing hooks _ socket wrench & socket set _peristallic pump T-handle penta-key _ size 18 silicon tubing jA _ filters (#GD 045700) _ magnet _first aid kit OTHER _Brunton ecmpass ,,,,,,,pager #3 1] GERAGHTY & MILLER,INC.

H TADLE & BUMMAPfr OF SAMPLE PFESENATNES, HOLDNQ TWES, NC ANALYTICAL blETH008 OlEMENS POWER CCFFORATION, f4CKAND WASHNOTON PR3 JECT NO, WA18100 AMLYTE EPA COP (TAMER PPEBENATNE HOLDNQ METHOD (1) Tu4E TricNoroethene 824 C P44 b40 mL giese viel HQ h pH < R. eoal 4 C 14 days TritnJtyt Phospheie 8270 tut L amber glass Cool 4 C 7 dayo AikannAy 310.1 14 Polyethykne Cool 4 C 14 daye CNoride 300.0 14 Polyethytene Cual4 C as days Ammama se Nitrogen 350.2 14 amber giene H2SO4 e pH < R cool 4 C se dayo ) Fluoride 300 0 14 Polyethylene Cool 4 C 38 days 14 Po yethylene Coni 4 C de houre Nitreas as Nitrogen 300.0 s Phosphate 300.0 14 Poeyothytene H2904 b pH < 2 conf 4 C 35 simye euNano 300.0 14 Poeyethytene Cool 4 C as dayo Asurmnum soto 1400 mL Pe ethytene HNO3 e pH < 2, cool e C 0 months r Cawum a010 1400 mL Pofyethylene HNO3 b pH < 2, enci 4 C ' 4 monihe j Gosum soto 1400 mL Pofyemytene HNO3 to 4C 4 montre Zlroonien 0010 1400 mL Polyethytene HNO3 42, 4C e months l Grose alpha 930.0 14 Polytheylone HNO4a6 pH ecol 4 C e monthe J Graea beta e00.0 14 Polytwylene H)fC3 h pH c' esci 4 C 8 murehe Temperature NA NA NA j pH NA hA NA boscirk, a--A 6-94A AA NA NA s s (1) tool 4 C*indmares that sampie mud to oceed b 4 dea'*** N mL Mmiuier. L LJ6er NA Not me hcl Hy&oet.k:ric Acw H2so4 suituric Acw 4 H,a m,io Ace k ,,w..,sa m m t g. 1 I i 0 i l l3 i l GERAGHTY & MILLER,INC. l. I lJ m,w - w m -= ,,---m. 1 mm

e 4 i TABLE 4.

SUMMARY

Of MOUN4 WATER MMPUNG REQUIREMENTS f SIEMENS POER CORPORATION, RICHLAND, W GHtNGTON PRCMECT NO.WA183.08 - I Meeod CROL G&M QALevel Precinkan Accuracy Analyte (1) (2) Crseria(3) Cruerta p) 1 Trichloroethene 624-CLP-M (4) 2 og,1 B 25 75125 Tritanyt Phosphate a270(5) to up/L

• N 25 75 125 Armatinity 310.1 (6) 10000ogi N

20 75125 Chkalde 300.0 F) 10000 ugt il 20 75-125 i Asnmorda as Nitro 0en 350.3 (6)3 50 ug/L N 20 75 125 flucs6de ' 340.2 (B) 100 ug/L N 20 75-125 '~ ~ ~' ' Minste as Nitrogen 3XLD p) / 100 og/L M 20 75125 Ptesphate 300.0 F) 500 ug/L N 20 75125 ~ ~ ~ ~ Sulfate 300.0 F) 2000upt il 20 75 125 Aluminum 6010 (5) 200ug/L N 75 125 Calcium 6010 (5) 5000 ug/L 11 75 125 Sodium 8010 (5) 5000 upt 11 20 75 125 7;rconium 6010 (s) 10 ug/L

• 20 75-125 J

75 125 Grone alpha 9000 p) 7.5 pCit On:ms beta 900.0 (9) 25 pCA I 75 125 NA fM NA NA Terrporature (10) NA pH (10) NA M4 Specific Conductance (10) ug/ Merograms per liter pCL/L Picoeuries per liter CROL Contract Required Detection Umit NA Not applicable Estimate d instrument det li pr by Pr L oratory be considered requirements tior's; values (1) CROLla the contract 4equirad qu _..b n y Geragp & feS% a sarnple avecific quality control de&nrab6es program 9) contrM Ma devek> ped under routine EPA analytical 6 ;Wien. representing a subset d quality $istent with the EPA Level lit data quanty objectives GersgSt)( Miller Level 11 f co (EPA /540/G /003 19 ) and requirements specif.ed by EPA SW446. Chapter 1. 9) Precision is expressed a relative percent difference between results d dupticate or replicato analyses,. curacy is expeessed as percent recovery d an analyte. These limits appy to sample resutts greater than five times the CROL and are to be considered requirements in the absence d known or suspected analyticalinterferencies. (4) Method described in 40 CFR 136, Appendix A, (5) Method described in Test Methods for Evaluating E Waste, EPA SW446. September 1966. Method described in Methode for Cherrdcal Anatyse d Wator and Wastes, EPA 600/479 020,1979. (6) Method described in Determination d inorganic Anbns 61 Aqueous and Solid Samples of p) lon Chromatography. EPA 400/4-84417,1984. Method described in Methods for Chemical Analysis of Water and Wastes. (B) EPA 600/4 79420,1979, Revised 1963. Method described in Prescribed Procedures for Measurement of RadioactMty in Drinidng @) Water EPA 400/444G32.1960. (10) Measured in the told acoording to Instrument manuf acturer's instructions. ,-w.__ f' GERAGHTY & M]LLER,INC.

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,cesse r AWGERAGHTY A P'6 Mr. <MII.LER. INC. i s,,,,'" WATER SAMPLING LOG Pro p 'No Papa d Site Locahon Coded / Site /Weg No Repicate No Date Tirne Sampling Trne Sarnpling Weather Began Completed EVACUAnON DATA Desenpoon d Measunng Point (MP) Heght d MP Abo +1EWow Land Surface MP Ekvabon i Tolal Sounded Depe d Wen Be% MP Waterhel Elevabon Heid Depth to Water Below MP Diarneter d Casing Ganons PumpedBa!ied Wet Water Column in Web Pnor to Sampling Gallons per Fact SamcAng Pump intaM Setbng Gallons in Well (leet beicw land surface) y Evacuadon Method SAMPUNG DATA / FIELD PARAMETERS Color Odor Appearanr# Temperature OF/'C Omer (specfc on. OVA: HNU. etc) k.{ Speer'c Conductance, umhos/cm pH g Samphng Method and Matenal Conta.'ner Desenpbon Const:tuents Sampied From Lab or G&M Preserva:ne k g Remane Samphng Penionnel 8 WELT. CASING VOLUuE5 N cm i.w . c es v. o ss v. c ar .. o ss g i.w . o os sw.ca w. os s.io u,- asa m ae f FIGURE e & GERAGHTY WATER SAMPLING LOG M & MITLER, INC. M rnwronmental Servw** Siemens Power Corporation 2101 Horn Rapids Road ~ Richland, Washington t

188188 F . 1 CALIBR ATION/M AINTEN ANCE LOG EQUIPMENT DESCRIPTION EQUIPMENT MANUFACTURER AND MODEL SERIAL NO. 1-Descripcon of Carltwatson MedLum Usedf Calibrason Data Maintenance Performed Readngs Sa m

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1-is.$e. r WATER LEVEL MEASUREMENT FORM Project No. Site / Location Date 3 GERAGHTY ""*"*** "'* d Leal Probe s eeYT p AF& MILLER,INC. ~ NEn viron m en tal Serviers Model/ Serial No. 1 Measured By: m )

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