ML20029E330

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NPDES Permit No. TN0026450 - Cy 2019 Biocide Corrosion Treatment Plan Annual Report
ML20029E330
Person / Time
Site: Sequoyah  Tennessee Valley Authority icon.png
Issue date: 01/24/2020
From: Rasmussen M
Tennessee Valley Authority
To: Hall A
Document Control Desk, Office of Nuclear Reactor Regulation, State of TN, Dept of Environment & Conservation, Div of Water Pollution Control
References
TN0026450
Download: ML20029E330 (5)


Text

TennesseeValleyAuthority, Post Office Box2000,SoddyDaisy,Tennessee37384-2000 January 24, 2020 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section William R. Snodgrass Tennessee Tower 312 Rosa L. Parks Avenue, 11th Floor Nashville, Tennessee 37243

Dear Ms. Angela Hall:

TENNESSEE VALLEY AUTHORITY (TVA) - SEQUOYAH NUCLEAR PLANT (SQN) - NPDES PERMIT NO. TN0026450 - CY 2019 BIOCIDE/CORROSION TREATMENT PLAN (B/CTP)

ANNUAL REPORT Enclosed is a copy ofthe CY 2019 B/CTP Annual report for SQN. Flogard MS 6237was notadded during CY 2019. All treatments in 2019 were conducted in accordance with the approved B/CTP.

If you have any questions or need additional information, please contact Millicent Garland at (423) 843-6714 or bye-mail at mrmoore@tva.gov ofSequoyah's Environmental staff.

/ certify underpenalty oflaw that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based onmy inquiry ofthe person or persons who manage the system, orthose persons directly responsible for gathering the information, the information submitted is, to the best ofmy knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment forknowing violations.

Sincerely Matthew Rasmussen Site Vice President Sequoyah Nuclear Plant Enclosures cc (Enclosures):

Mr. Vojin Janjic Chattanooga Environmental Field Office State of Tennessee Division of Water Pollution Control Dept. of Environment and Conservation State Office Building, Suite 550 Division of Water Pollution Control 540 McCallie Avenue 6th Floor, L&C Annex Chattanooga, Tennessee 37402-2013 401 Church Street Nashville, Tennessee 37243-1534 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, D.C. 20555

TN0026450 2019 Biocide/Corrosion Treatment Plan Annual Report Spectrus CT1300 SQN Quantity in Pounds (lbs/day)

Month Maximum Average Limit January February March April 320.45 240.33 855 May 483.18 322.12 855 June 483.18 295.31 855 July 320.45 215.30 855 August 483.18 322.12 855 September 483.18 266.77 855 October 483.18 308.70 855 November 483.18 322.12 855 December 220.31 185.26 855 Jan. - Dec.

Duration in Hours (hrs/day)

Maximum 16.00 15.50 15.17 16.00 24.00 24.00 24.00 15.50 11.00 Maximum 0.0330 0.0332 0.0332 0.0330 0.0332 0.0332 0.0332 0.0332 0.0343 Analytical Results mass balance calculations (mg/L)

  1. of Days in n

Average Limit Samples Service 0.0330 0.05 2

2 0.0332 0.05 6

6 0.0332 0.05 8

8 0.0330 0.05 4

4 0.0332 0.05 6

6 0.0331 0.05 7

7 0.0332 0.05 3

3 0.0332 0.05 3

3 0.0343 0.05 4

4 43 43 Per the B/CTP approval: "Whole Effluent toxicity testing (biomonitoring) ofOutfall 101 and Outali 110 shall be undertaken once per year when non-oxidizing biocides are being used."

Outfall 101: Toxicity was sampled August 4 - August 9, 2019, during the Spectrus CT1300 treatment.

Test Results: Pimephales promelas: IC25>100%

Ceriodaphnia dubia: IC25 > 100%

Outfall 110: There hasbeen nodischarge from Outfall 110 January - December 2019.

TN0026450 2019 Biocide/Corrosion Treatment Plan Annual Report Spectrus BD 1500 SQN Quantity in Pou (lbs/day)

Month Maximum Average January February March April 42.66 36.97 May 42.66 37.92 June 42.66 38.78 July 42.66 42.66 August 42.66 36.10 September 42.66 35.55 October 42.66 38.28 November 42.66 29.86 December 42.66 31.03 Jan. - Dec.

Limit 50 50 50 50 50 50 50 50 50 Duration in Hours (hrs/day)

Maximum 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Maximum Analytical Results mass balance calculations (mg/L)

  1. of Days in n

Average Limit Samples Service 0.047 2.00 5

5 0.047 2.00 12 12 0.047 2.00 11 11 0.047 2.00 14 14 0.047 2.00 13 13 0.047 2.00 12 12 0.064 2.00 13 13 0.084 2.00 10 10 0.049 2.00 11 11 101 101 0.047 0.047 0.047 0.047 0.047 0.047 0.084 0.084 0.049 Per the B/CTP approval: Spectrus BD1500 is asurfactant that is injected into the ERCW and RCW systems for approximately 30minutes prior initiating chlorination toenhance theeffectiveness ofthe chlorination.

TN0026450 Month January February March April May June July August September October November December Jan. - Dec.

2019 Biocide/Corrosion Treatment Plan Annual Report Towerbrom 960 Quantity in Pounds (lbs/day)

Maximum Average (based on days in service) 200 150 200 200 200 180 200 156 200 166 225 174 225 215 225 189 225 175 200 185 200 120 125 100 Duration unds in Hours (hrs/day)

Limit Maximum 1425 4.00 1425 4.00 1425 4.00 1425 4.00 1425 4.00 1425 4.00 1425 4.00 1425 4.00 1425 4.00 1425 4.00 1425 4.00 1425 4.00 Analytical Results mass balance calculation (mg/L)

  1. 0 Maximum Average Limit s amp 0.0326 0.0195 0.10 10 0.0317 0.0206 0.10 8

0.0248 0.0182 0.10 10 0.0232 0.0139 0.10 17 0.0298 0.0194 0.10 19 0.0258 0.0162 0.10 20 0.0315 0.0214 0.10 22 0.0305 0.0180 0.10 22 0.0378 0.0225 0.10 20 0.0347 0.0187 0.10 31 0.0392 0.0213 0.10 11 0.0288 0.0146 0.10 11 201 SQN Days in Service 10 8

10 17 19 20 22 22 20 20 11 11 190 Per the B/CTP approval: "Whole Effluent toxicity testing (biomonitoring) of Outfall 101 and Outali 110 shall be undertaken once peryearwhen oxidizing biocides are being used."

Outfall 101: Toxicity was sampled April 28 - May 3, 2019.

Test Results: Pimephales promelas: IC25 >100%

Ceriodaphnia dubia: IC25 > 100%

Outfall 110: There has been no discharge from Outfall 110 January -December 2019.

TN0026450 Month January February March April May June July August September October November December Jan. - Dec.

2019 Biocide/Corrosion Treatment Plan Annual Report Quantity in Pounds (lbs/day)

Maximum Average Limit 208.80 417.60 417.60 417.00 417.60 417.60 730.80 730.00 730.80 313.20 321.90 208.80 227.78 278.40 234.90 292.32 238.63 454.14 342.20 493.00 286.13 254.04 2275 2275 2275 2275 2275 2275 2275 2275 2275 2275 2275 Flogard MS6236 Duration in Hours (hrs/day)

Maximum 12.00 24.00 24.00 12.00 24.00 24.00 24.00 24.00 24.00 18.00 18.00 Analytical Results mass balance calculations (mg/L)

Maximum Average Limit 0.0296 0.0296 0.0296 0.0285 0.0285 0.0285 0.0285 0.0285 0.0513 0.0321 0.0296 0.0296 0.0296 0.0296 0.0285 0.0285 0.0285 0.0285 0.0285 0.0361 0.0321 0.0296

  1. of samples 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 11 11 12 8

5 14 20 18 18 9

10 136 SQN Days in Service 11 11 12 8

5 14 20 18 18 9

10 136 Per the B/CTP approval: "Flogard MS6236 is injected into the RCW system continuously, except during periods of other chemical injection due to common injection lines. Flogard MS6236 is injected into the ERCW Train A&B system intermittently."