ML20027E468

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to Steam Generator Water Chemistry Monitoring - Unit 1.
ML20027E468
Person / Time
Site: Arkansas Nuclear Entergy icon.png
Issue date: 02/18/1982
From: James M. Levine
ARKANSAS POWER & LIGHT CO.
To:
Shared Package
ML20027E467 List:
References
1000.42, NUDOCS 8211150360
Download: ML20027E468 (18)


Text

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I ATTACHMENT 1 i

i OVERALL PLANT ADMI

N. PROCEDURE

STEAM GENERATOR WATER CHEMISTRY MONITORING

- UNIT ONE

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I Pt. ANT MANUAL SECTION: PROCEDUREN/ORK PLAN TITLE: R'O:

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CHEMISTRY MONITORING - UNIT ONE 1000.42

  1. 1 PAGE Is EC- 1 of 13 ARKANSAS NUCLEAR ONE _aEvisiON 0 oATE 2/ises2 L l CHANGE DATE 1.0 PURPOSE i

I The purpose of this procedure is to identify a secondary water chemistry monitoring program to maximize the availability and operating life of ma-jor components such as the steam generators and the turbine.

,i 2.0 SCOPE The scope of .s program is limited to:

2.1 Unit One-2.2 Identifica; ion of a sampking schedule for the mininal critical para-meters and control points for these parameters; 2.3 Identification of the procedures used to measure the values of the critical parameters;j 2.4 Identification of sampling procedures and process sampling points, 2.5 Procedure for the recording and management of data; I

(\ 2.6 Procedure defining corrective actions for chemistry conditions out-side normal ranges; and ,

2.7 A procedure identifying the authority responsible for the interpreta-tion of the data, and the sequence and timing of administrative events required to initiate corrective action.

3.0 REFERENCES

3.1 References Used in Developing this Procedure 3.1.1 PWR Secondary Water Chemistry Guidelines Sept. 1981-EPHI 3.1.2 . Babecek & Wilcox sAW1385 Water Chemistry Manual 3.2 References to be Used in Implementing this Procedure 3.2.1 1605.03, " Determination of Ammonia" 3.2.2 1605.07B, " Determination of Chloride Specific Ion Electrode Method" 3.2.3 1605.10A, " Determination of Cation Conductivity of Water" '

3.2.4 1605.llA, " Determination of Copper (AA Method)"

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PLANT MANUAt SECTION: PROCEDURElWORK PLAN TITLE: NO:

OVERALL PLANT STEAM GENERATOR WATER AD*f T N _ PROFFDirRF CIIFMTSTRY MOVTTORTNn - INTT ONU InOO.47

  1. m PAGE 9 of 11 ARKANSAS NUCLEAR ONE aevision n o^te 2/ia/R2 CHANGE DATE 3.2.5 1605.15, " Determination of Hydrazine - Low Range" 3.2.6 1605.15A, " Determination of Hydrazine - High Range" 3.2.7 1605.16B, " Determination of Iron (AA Method)"
J 3.2.8 l'605.22,'" Determination of Dissolved Oxygen" 3.2.9 1605.23, " Determination of pH of an Aqueous Solution" 3.2.10 1605.25, " Determination of Silica Photometric Method" b

1.2.11 1605.27, " Determination of Solids Membrane Comparison Method" 3.2.12 1606.08, " Atomic Absorption Unit - Startup, Shutdown, and Calibration in the Emmission Mode (Sodium Analysis)"

1 3.2.13 1618.05, " Sampling the Steam Generators - Unit 1" 3.2.14 1618.04, " Sampling the Condensate"  ;

,, 3.2.15 1618.03, " Sampling the Feedwater" 3.2.16 1618.02, " Sampling the Condensate Demineralizer System" 4.0 DEFINITIONS 4.1 Action Response - Remedial actions to be taken when measured values for parameters are observed and confirmed to be outside normal values.

Parameters outside of their normal values represent conditions which could lead to corrosion. The action responses are designed to pro-vide a response in proportion to the severity of the situation en-countered.

4.2 Corporate Management - Utility management responsible for nuclear power plant operation but with offices which may be remote from the ~

plant site.

4.3 Plant MainEenance Staff - Plant personnel responsible for repair and modification of plant equipment.

4.4 Sample Sources - Those points in the system from which a sa.nple is drawn for analysis.

i 4.5 Station Management / Operating Staf f - On-site management responsible for overall station performance and plant personnel responsible for the day-to-day operation of a nuclear unit.

4.6 frended Chemistry Data - Chemistry data plotted vs time. Provides a rapid visual method of assessing plant chemistry.

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PLANT MANUAL SECTION: PROCEDUREN/ORK PLAN TITLE: NO:

7 OVERALL PLANT STEAM GENERATOR WATER 2

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(,_ CM "}g PAGE q ,c 39 ARKANSAS NUCLEAR ONE laEvisrON n DATE 2 ', , e i r CHANGE DATE 5.0 RESPONSIBILITIES 3 5.1 Corporate Management: Establishes the policies and provides the re-sources to support and enforce the guidelines. The roles of corpor-ate management may include, periodic restatement of commitment to the operating policy, maintain"ing a long-term perspective of the plant operation, maintaining an awareness of the real and potential oper-ating problems as affected by plant chemistry, and assuring periodic review of the operating policy.

5.2 Station Management / Operating Staff: Responsibilities include un-derstanding the impact of the chemistry control on major component performance, availability, and expected life; understanding the chemistry control program and the management support for the pro-gram; and establishment of corrective action priorities.

5.3 Plant Chemistry Staff: Responsibilities include understanding the corporate management goals for the program implementation of the chemistry control program, timely data review to identify problems quickly, initiation of any required corrective actions, and making i any necessary changes in the chemistry monitoring requirements to

,,, improve the chemistry control program.

6 5.4 Plant Maintenar ce Staff: Responsibilities include prompt and ef fective repair of plant equipment required to maintain chemistry specifications.

5.5 Planning & Scheduling Staff - Responsibilities include timely issuance of corrective maintenance required to maintain chemistry within specifications.

6.0 SAMPLING AND MONITORING INSTRUCTIONS 6.1 A secondary chemistry monitoring program to maximize steam generator availability and operating 1.ife shall be carried out on the samples, parameters, and frequencies ' listed on Attachments 1, 2 and 3 accor-ding to the status mode of t he unit.

6.2 Sampling and analysis of the concerned parameters will be carried out using current approved procedures.

6.3 Analysis results shall be recorded on the Daily Clean Lab Water Report for Unit One.

t 6.4 Each parameter concerned with maximizing steam generator availability anil c;.erating life should be trended as a means of rapid visual assessment of plant chemistry.

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FLANT M ANUAt SECTION: PROCEDUREMORK PLAN TITLE: NO:

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OVERALL PLANT STEAll GENERATOR WATER J . b AnyTe mnrrnime emirqTny MnvrTnnT*m - FNTT on 1000.49 I, O..L ARKANSAS NUCLEAR ONE PAGE aevision 4 nf 13 n oATE ,/>ain, CHANGE DATE 6.5 Daily Clean Lab k'ater Reports shall be reviewed, then compared to the normal }$arameter values listed on Attachments 1, 2, and 3, according to the status mode and sample source. If an out-of-spec condition is noted, request additional verification in the form of a confirmatory grab sample.

j 6.6 Any out-of-spec conditions or deleterious trends shall be promptly re-ported to the Chemistry and Environmental Supervisor or his assistant and also to the Shif t Supervisor. On a back shift, or in the absence of the Chemistry and Environmental Supervisor, the Shift Supervisor shall be promptly alerted of the findings by the Chemist.

i 6.7 The Chemistry and EnviroEmental Supervisor and/or the Shif t Supervi-sor shall proceed with a plan of corrective action to bring the parameter back into a normal value range. Typical corrective actions include:

  • 6.7.1 Compare relults of confirmatory analyses to readings from continuous monitors.

6.7.2 Increase steam generator blowdown to maximum levels for the removal of specific impurities. (This can be done f during certain startup periods only.)

6.7.3 Isolate and identify sources of impurity ingress.

6.7.4 Compare results of various analyses for internal consis-tency.

6.7.5 Increase sample and analysis frequencies for short-term trending of critical chemistry parameters.

6.7.6 Refer to Attachments 4, 5 and 6 for corrective action of specific parameters.

6.8 All values from analyses and instrument readings should be archived for long-term trending and review.

7.0 FORilS AND ATTACID1ENTS 7.1 Attachment 1 - Cold Shutdown / Wet Layup 7.2 Attachment 2 - Startup, Ifot Standby, and Steaming at ( 15% Full Power 7.3 Attachment 3 - Power Operation > 15% Full Power 7.4 .\ttachment '. - Cold Shutdown / Wet Layup Corrective Actions D

7.5 Attachment 5 - Startup, !!ot Standby, and Steaming at ( 15% Full Power

, Corrective Actions 7.6 Attachment 6 - Power Operations > 15% Full Power Corrective Actions

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'f' F'LANT MANUAL SECTIOM. PROCEDURElWORK PLAM TITLE: NO:

i OVERALL PLANT STEAM GENERATOR WATER I

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( - nr 39 ARKANSAS NUCLEAR ONE aEvisiON n Da's ,,,ein, CHANGE DATE ATTACHMENT 1 i

COLD SHUTDOWN / WET LAYUP (RCS ( 200 F) si Value Prior to Pa ramete r Frequency

  • Normal Value Initiate Action Heatup Steam Generator Sample pH weekly 9.8-10.5 (9.8, >10.5 8.5-9.3 Hydrazine, ppm weekly 75-200 (75, >200 3x[02 l Sodium, ;'pb weekly) (1000 >1000 (2000 Cation Conductivity weekly (10.0 >10.0 (10.0 pmno/cm f'N *Every other day until stable, then weekly.

NOTE: "Value Prior to Heatup" shall be met prior to exceeding 200 F RCS Temperature.

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PLANT MANUAL SECTION: PROCEDURE / WORK PLAN T6TLE: NO:

OVERALL PLANT STEAM GENERATOR WATER

.. ADMTV PROFFnUR R CHFMISTRY MOMTTORTMn - UNTT ONE 1000.42

- S ARKANSAS NUCLEAR ONE PAGE aevision 6 of Il n o^Te 2/is/s2 CHANGE DATE ATTACHMENT 2 Page 1 of 2 i

STARTUP, HOT STANDBY, AND STEAMING AT (15% FULL POWER Initiate Pa ramet er Frequency V Normal Value Action ** Action Response Feedwater Sample pH 3/ day 8.5-9.3 (8.5 Return to normal value

>9.3 within 100 hours0.00116 days <br />0.0278 hours <br />1.653439e-4 weeks <br />3.805e-5 months <br /> or be

, in cold shutdown within additional 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

Hyd ra zi ne , Daily 23x [0,] (3x [0,] Return to normal value ppb ~

within 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

Dissolved I 0xygen, ppb RCS >200 F 3/ day (100 }100 Return to ( 100 with- 2 (525"F in 8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br /> or be in

(5 cold shutdown within additional 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

RCS > 525 F Daily (3 }3 Return to normal value

{15%F.P. within 8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br /> or be in cold shutdown within additional 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

Cation Conductivity -

pmho/cm RCS > 200 F Continuous (1.0

~ >l.0 Should be (1.0 before

( 525"F feeding OTSG's. After initiated, should be below 0.5 within 24 hrs.

RCS } 525 F Continuous (0.5 >0.5 Return to { 0.5 with-

{ 15% F.P. in 100 hours0.00116 days <br />0.0278 hours <br />1.653439e-4 weeks <br />3.805e-5 months <br /> or be in cold shutdown within additional 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

>1.0 Return to ( 1.0 with-in 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> or be in '

cold shutdown within additional 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

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>2.0 Return to ( 2.0 with-in 8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br /> or be in cold shutdown within additional 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

  • I PLANT MANUAL SECTION: ROCEDURE/ WORK PLAN TITLE:

(, ,

OVERALL PLANT STEAM GENERATOR WATER NO:

l } ADMTN_ PRnEEDURE CHFMTSTRY MONTTORTNn - t'NTT nNE G

1000.42 C = PAGE 7 of 13 ARKANSAS NUCLEAR ONE aevision n o*Te 2ris/82 CHANGEpp.1 DATE 5/5/82 NITACHMENT 2 Page 2 of 2 i

STARTUP, IIOT STANDBY, AND STEAMING AT <l5% FULL F0WER Initiete Parameter Frequency

  • No'rmal Value Action ** Action Response ***

Feedwater Sample Silica, ppb Daily <20 220 Should be returned to normal value within 3 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

Iron, ppb Daily <100 3100 Should be returned to normal value within 8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br />.

Steam Generator Sample Sod ium , ppb 3/ day <2000 32000 Return to normal value .

within 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> of reach-ing 3 520 F or be in cold

(5 shutdown within at addi-tional 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

Chloride, ppb 3/ day <1000 31000 Return to normal value within 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> of reach-ing 1 520 F or be in cold shutdown within an addi-tional 24. hours.

Cation 3/ day <10.0 310.0 Return to normal value Conductivity within 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> of reach-paho/cm '

ing 2 520 F or be in cold shutdown tthin an addi-tional 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

Silica, ppb 3/ day <2000 22000 Return to normal value within 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> of reach-ing 1 520 F or be in cold shutdown within an addi-tional 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

Daily samples will be analyzed for continuous frequency parameters to verify analyzer operation and/or insure that parameter is within normal value if analyzer is out of service.

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Time clock starts when sample results indicate outside normal value.

The Steam Generator normal value limits must be in compliance before going above 15% reactor power. * '

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PLANT M ANUAL SECTION: PROCECURE/ WORK PLAN TITLE: NO:

7M Tj OVERALL PLANT STEAM GENERATOR WATER J wfin ,)onernf T)r rurstic:ypv unvTTno rve _ Y n? T T AsT innn I. ,

f' dd, -g PAGE o n c yo ARKANSAS NUCLEAR ONE _aEvisiON n oArE e ,4 2 , o,

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CHANGE DATE ATTACIDfENT 3 Page 1 of 3 POWER OPERATION > 15% EULL POWER Initiate Parameter Frequency N'ormal Value Action

  • Action Response Final Feedwater pli Continuous 8.8-9.2 (8.8 Return to normal value

>9.2 within 8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br /> or be in 3 cold shutdown within additional 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />, llyd razine , ppb daily >3x [0 2 ]** >3x Return to normal value

- [ 02 ] ** within 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> or be

in cold shutdown within additional 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

Dissolved Continuous (3 >3 Return to normal value .

Oxygen, '

ppb within 8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br /> or reduce power to (30% until f source is identified and isolated.

Sodium, ppb Continuous (3 Return to normal value

}3 within 100 hours0.00116 days <br />0.0278 hours <br />1.653439e-4 weeks <br />3.805e-5 months <br /> or be in cold shutdown within additional 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

16 Return to ( 6 within 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> or be in cold shutdown within additional 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

>10 Be in cold shutdown within 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

Chloride, ppb Daily *** (5 15 Return to normal value within 100 hours0.00116 days <br />0.0278 hours <br />1.653439e-4 weeks <br />3.805e-5 months <br /> or be in cold shutdown within additional 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

}l0 Return to ( 10 with ,

in 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> or be in cold shutdo.n within additicual 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

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}20 Be in cold shutdown within 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

8 PLANT MANUAL SECTION: PROCEDURDWORK PLAN TITLE NO:

P l OVERALL PLANT STEN! GENERATOR WATER W

i m\DMI" "OCEDURE CIIEIIISTN "A"' " I" ""IT 0"U 'AAA 'd PAGE f., CL o mr 19 ARKANSAS NUCLEAR ONE _aEv>SioN e ~ o^tE ,,,,,,,

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CHANGE DATE ATTACHMENT 3 Page 2 of 3

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POWER OPERATION > 15% FULL POWER Initiate pa rame te r Frequency Normal Value Action

  • Action Response Final Feedwater Cation Continuous (0.2 Return to normal value Conductivity }0.2 within 100 hours0.00116 days <br />0.0278 hours <br />1.653439e-4 weeks <br />3.805e-5 months <br /> or be pmho/cm 3 in cold shutdown within '

additional 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

>0.5 Return to ( 0.5 with-in 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> or be in d

cold shutdown within additional 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

21.0 Be in cold shutdown within 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

{'- Silica, ppb Daily (20 }20 Return to normal value within 100 hours0.00116 days <br />0.0278 hours <br />1.653439e-4 weeks <br />3.805e-5 months <br /> or be in cold shutdown within additional 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

235 Return to (35 with-in 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> or be in cold shutdown within additional 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

}50 Be in cold shutdown within 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

Total Weekly (10 110 Should be returned to iron, ppb (integrated) normal value within 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

Suspended Daily (10 }l0 Should return to normal Solids, ppb range within 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.

Copper, ppb Weekly (2 12 Should be returned to normal range within 2,4 hours4.62963e-5 days <br />0.00111 hours <br />6.613757e-6 weeks <br />1.522e-6 months <br />, p

PLANT MANUAL SECTION: PROCEDUREN/ORK PLAN TITLE: NO:

i OVERALL PLANT STEA!! GENERATOR WATER M 2

_ A nM T *! ppnrrnffT)P PIIFMTGTpV Mn*ITTnR T *In - lait T ON'l;' 1000 47 4

m bj $ PAGE in nr il ARKANSAS NUCLEAR ONE aavisioN n o4Te geia/a, CHANGE DATE ATTACIDIENT 3 Page 2 of 3 i

POWER OPERATION > 15% FULL POWER Initiate Parameter Frequency Nbrmal Value Action

  • Action Response Condensate Pump Discharge Sample Dissolved Continuous {l0 >10 If >10 ppb for 100 0xygen, ppb hours, reduce power to y 30% until source is identified and isolo:ed.

All parameters must be below applicable action response level prior to power escalation above 30% full power. Time clock starts when sample results indicate outside normal values.

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Based on oxygen value measured in the condensate sample. ,

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(, ,' Since cation conductivity can detect low levels of chloride, this is not con-sidered to be a required, routine analysis.

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PLANT MANUA6 SECTIOM: PROCEDUREMf0RK PLAN TITLE: NO:

C* ' '

OVERALL PLANT STEAtl GENERATOR WATER ansrin onorr nirnr enrnremnv unvTTnpTvc imTT nw i nno r<o Is l

PAGE e I- ARKANSAS NUCLEAR ONE aevisios 3, nc 1q n o^re ,,,2ine CHANGE - DATE ATTACHMENT 4 L

COLD SHUTDOWN / WET LAYUP CORRECTIVE ACTIONS Steam Generator Sample ,

a Parameter Out of Range Corrective Action pli 1. Cross-check with ammonia /hydrazine/ cation conductivity values for consistency.

2. y If pH is low, add ammonia to correct and mix contents of steam generator.

Sodium 1. Check make-up water purity.

2.

  • Feed and bleed until within range or drain and refill with deoxygenated make-up water of proper purity.

llydrazine 1. If low, add to range.

h 2. If high, feed and bleed until within range, or drain and refill with make-up water of proper purity.

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PLANT MANUAL SECTION: PROCEDURE / WORK PLAN TITLE: NO:

i, OVERALL PLANT STEAM GENERATOR WATER Ahnf TM PR A P PT)T m E e, rg CHFF11 RTRV hfAMTTOR TVe - FMTT OVF PAGE 1000 4, 19 nf ja f LL L ARKANSAS NUCLEAR ONE aevisioN n Date ei,ain, g

CHANGE DATE ATTACHMENT 5 t

STARTUP, HOT STANDBY AND STEAMING AT ( 15%

FULL POWER CORRECTIVE ACTIONS Parameter out of Range J Corrective Action pH 1. Adjust ammonia feed to increase pH if too low.

2. If pH is high, blow down and add deionized, deoxygenated makeup water.

Cation Conductivity 1. Maximum blowdown, and add deionized, de-oxygenated makeup water. Check makeup purity.

Dissolved Oxygen 1 Check hydrazine residual. Add hydrazine if required.

'Hydrazine 1. Add hydrazine if residual is low.

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  • f PLANT MANUAL SECTION: PROCEDUREN/ORK PLAN TITLE: .,I

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OVERALL PLANT STEAt! GENERATOR WATER

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PAGE L 39 cr 39 ARKANSAS NUCLEAR ONE aevisioN 0 o^1E ,,,e,2, CHANGE DATE ATTACHMENT 6 i

POWER OPERATION > 15% FULL POWER CORRECTIVE ACTIONS Final Feedwater

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Parameter Out of Range Corrective Action pH 1. Verify correct hydrazine feed.

2. Verify correct ammonia feed.
3. Verify absence of regenerant chemical in-leakage.

Ifyd razi ne 1. Adjust chemical addition.

t Oxygen f. Verify hydrazine residual.

2. Verify absence of significant air i~nleakage. .

,, Sodium 1. Check condensate polisher sodium leakage.

2. Request routing of MSR drains to condenser.
3. Identify source using other sample points and analytical techniques.

Cation Conductivity, 1. Request routing of MSR drains to condenser.

Chloride, Fluoride, 2.

and Silica Check condensate polisher for anion removal.

3. Identify source using other sample points and analytical techniques.

Iron, Suspended Solids, 1. Assure pH and oxygen are in specification.

Copper t

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ATTACHMENT 2 PROPOSED LICENSE AMENDMENT SECONDARY WATER CHEMISTRY MONITORING

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$ (7) Cecondary Water Chemistry Monitoring

& A secondary water chemistry monitoring program shall be implemented to minimize steam generator tube degradation.

.Tdis, program shall include: +

1. ' Identification of a sampling schedule for the critical parameters and control points for'these parameters;
2. Identification of the procedures used to measure the values of the critical parameters;
3. Identification of process sampling points; 4 4. Procedures for the. recording and management of data; T '\
5. Procedures defining corrective actions for off-control point chemistry conditions; and
6. A procedure identifying the authorit'y, responsible for the interpretation of the data and.the sequence and timing of administrative events requi, red to initiate a corrective action. * *
d. Thislicenseiseffectiveasofthedateoflidsuanceandshall expire at midnight, December 6, 2008.

FOR THE ATOMIC ENERGY COMMISSION ,

s s A. Giambusso, Deputy Director i .

Date of Issuance: May 21 1974 ,

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