Text

Forwards Responses to 891212 Questionnaire Re Release of Sodium Hypochlorite (Spill 10-43-4117) from Plant on 891025. Caused by Improper Shutdown of Svc Water Chlorination Sys. On-the-job & Classroom Training Will Be Provided
	ML20005G170
Person / Time
Site:	Perry
Issue date:	01/10/1990
From:	Kaplan A; CLEVELAND ELECTRIC ILLUMINATING CO.
To:	; OHIO, STATE OF
References
	PY-CEI-OEPA-009, PY-CEI-OEPA-9, NUDOCS 9001180237
	Download: ML20005G170 (27)
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-T.HE CLEVELAND ELECTRIC.ILLUMINATINGLCOMPANY

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P.O. BOX 97 ;

E- PERRE, OHIO 44001 .W . TELEPHONE :(118) 256 3787 :3_

FROM CLEVELAND: 479 1200 . 3 ADDRE8s 10 CENTER ROAD '

TELEX: 241600 l

I O 7 g [' - ANSWEmeACK: CEIPRYO

( .'Al Kaolani , Serving The Best location in the Nation

PERRY NUCLEAR POWER PLANT wa maaote -

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"Y . January 10,L 1990 PY-CEI/0 EPA-0097L s

0hio EPA, Office of Energency Response .

s , ;P.O. Box 1049;

._1800 Watermark Drive 4 '

' Columbus,; Ohio- 43266-01491 s

M Re Spill #10-43-4117

'/D Gentlemen:-

J' '

, -' Attached are:our responses to'your questionnaire, which was submitted to us in your' letter dated 12/12/89. .This concerns' the. sodium hypochlorite release

< which occurred at the Perry Nuclear Power Plant'on 10/25/89,(spill .

.# 10-43-4117). . Additional documents are also provided, as' requested by R questions-.9"and 11 of.your questionnaire. Please contact us if you have any

further questions.

I Sincerely, -

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Al Kaplan

'Vice President Nuclear Group V' ' '

AK/sc.

Attachment:

cc:1 Document Control Desk, USNRC T. Colburn

~P. Riland. [

Region III Mr. R. 'Retzler (Lake County Emergency Planning Committee) i; l

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PY-CEI/CEPA-0097L.

!> 'I Efi January 10, 1990

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, 1. ' Reporting- F

-(a) Time and date of discharge / release.

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l Response: 1 The release. occurred on 10/25/89[between10:10a.m.and .

, 9:35 p.m.

(b) Time'and'date of discovery that the discharge had occurred.

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. Response: :The release was discovered'on 10/25/89 at 10:45'p.m.

t /~ J(c)'When andito who was the release first reported?- '

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' Responses The release.vas first reported to the Ohio EPA on 10/25/89 '

W at 11:59 p.m.

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, -(d).Indicatei hefidentification t number referenced in the cover letter. j

'b Response: -Spill 9 10-43-4117 1

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3- (e) Who notified OHIO EPA /U.S. EPA?

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Response: ' CEI - L. Lowery, ' Dispatcher, Eastern District- Distribution y Dispatching Office.

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f 2. Location i

E (a) Mailing address.

Response:' Perry Nuclear Power Plant i 10 Center Road (

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. North. Perry, Ohio' 44081 (b). Location"of. discharge: LCounty, Township and City.

Response: -Lake County, North Perry Village a

h -(c) Longitude and latitude if source ves non-transportation. (or enclose.

copy of a portion of:a U.S. GS map showing location).

s Response: West Longitude 81 degrees 08 minutes North Latitude 41 degrees 48 minutes !

NOTE: see attached map for specific location of release (plant discharge structure)

(d) Distance and direction from nearest intersection (or milepoint) if transportation related. .

Response N/A - not transportation related x

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PY-CEI/0 EPA-0097L-6

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3. Product Release Li (a) Please give the common:and technical name(s) of the material (s)

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r released and CAS Number (s).

L Response: Sodium Hypochlorite P> CAS No.-7681529, r ,

.(b)'I':the s product listed under Section 302 (s) of-SARA Title III or

CERCLA 102(a); (If yes, than a' copy of your response to these

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< questions.should be sent to your LEPC).- .

. - Response: Yes 1;n .

& f(c) What vas' the' quantity,and duration of the discharge. Indicate. volume. -)

'in gallons >or pounds. j 1

l' L Responsen Quantity - approximately 3750 gallons e 0.8% concentration' Duration - approximately 9 hours1.041667e-4 days 0.0025 hours 1.488095e-5 weeks 3.4245e-6 months 4.- ' Environmental Impact. ,

.l (a) Did the~ product reach "Vaters of the States?

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. Provide the. name of the vater course. .(Underground waters are waters y l,> '

tof the_ State.)=

L' . Responses! Yes, Lake' Erie 1

L(b) What vas the length or area of the water affected?

Response Area immediately adjacent to plant-discharge structure.

(c) If no water was.'affected, what was the surface area and depth of soil {

contamination; Please provide area of soil contamination even when waters are affected.

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. Responses Not applicable.

L (d) Did any evacuation result?

Responses No (e) Vas any animal or vegetation damage observed?

Responses No

.(f) Vere any health effects reported? How many humans' vere exposed / injured?

l-Responses No health effects, exposures, or injuries were reported.

(g) Vas medical advice provided for exposed individuals?

Responses Not applicable ,

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January 10, 1990l Page-3 a 1

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5[ Monitoring and Detection. ;i p f(a) Cascribe how the release was detected and monitored to determine 5 -off-site concentration. (Be specific as to'any monitoring system

in place at your facility.) .

^^ Response l See-letter PY-CEI/0 EPA-0091L, dated 10/30/89 and condition Report 69-381 which are attached..

,' '(b) If the release was airborne,- how was the wind' direction and speed

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determined? :.

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~ Responses Not applicable, liquid release.

p' . (c) Vas the public warned and if so, how?

Response: Public varning was not considered necessary.

6 .' - Mitigation,- Containment-Action ;

(a) How auch product or vaste was recovered or neutralized. -

. Response:. No waste vas recovered.

(b)'How was the material recovered or neutralized?

Response - Free available chlorine was neutralized by the plant service vater discharge flow-(avg flovrate 60,000 gpm).

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(c) Where was the cleanup waste taken?

Response: 'Not applicable 7 (d)' Vere any other actions taken to reduce the impact of the discharge (boom, siphon dams. sorbent)?

l Response: Service Vater De-chlorination System was manually started.

Service Water Chlorination System timers were returned to their-normal positions.

7. Please provide plans to eliminate any future spills discharges or emissions which may occur at this specific source. This may include; ;

' employee training, replacement of equipment, construction, or i csecurity measures such as lighting, fencing or locks.

If this is the second oil spill at this location, or a spillage of over !

'1,000 gallons which has reached water, then you-must snbeit copies of your Spill Prevention Control and Countermeasure Plan (SPCC) to the USEPA Regional Administrator and to this Agency within 60 days from the time of the discharge as provlTe'd by 40 CFR 112.4. Your SPCC plan should be submitted with your response to this letter.

Response: See letter PY-CEI/0 EPA-0091L, dated 10/30/89 and also Condition Report 89-381 which are attached.

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i. iN y '8.- Health Risks (a)'What protective precautions vere taken as-a resu.'.t' of the release?- d Responset= No protective precautions were necessary since free ,

available chlorine was neutralised through contact with r

service water system flow (avg. flow rate 60,000 gpm).

'i (b) List known or anticipated acute and chronic-health risks of exposure ;

to the-substance which are released.- Site source of information provided.-

Responses- Sodium hypochlorite is a corrosive irritant to skin, eyes,

.v~' . , 'and mucous membranes on contact (Ref. U.S. Department of=- >

Transportation /U.S. Coast Guard Chemical Hazard Response

,.j p Information System (CHRIS) Manual).

9. Indicate any air,~ vater, or other permit numbers which may be pertinent to this' incident.- Please indicate. type of permit (s).

Responses; NPDES Vastevater Discharge Permit No. 3IB00016*CD.

'(a) If this is an' NPDES / air permit, please enclose a copy of your current ,

effluent / emission limitations. ,

Response: -See attached. effluent limits for plant discharge tunnel.

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. 10. Provide a Ehronological' review of the incident.. Include a chronology of' communications'vith atate and local government agencies.

Responses- For a chronological review of the incident see letter PY-CEI/0EFA-0091L, dated 10/30/89 and Condition Report 381 which are attached. The following notifications '

were made as a result:of this incident.

Date Time Agency u

10/25/89 11:59 p.m. Ohio EPA 10/26/89 12:02 a.m. National Response Center 10/26/89 1:02 a.m. U.S. Nuclear Regulatory Agency 10/26/89 10:30 a.m. Perry Township Pire Department NOTE: Lake County Emergency Planning Committee was also notified on the morning of 10/26/89. However, no record is available.

11. Provide any. photographs, reports or other documents whether generated by your company or outside entities which are germane to the incident (e.g. accident reports, manifest, bills of lading laboratory analyses?)

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.c' Responsess' Copies of the following documents are provided:

< < Attachment 1~.: Letter'PY-CEI/0 EPA-0091L, dated 10/30/89 i w Attachment 2.iCondition Report 89-381- i

. Attachment 3. Discharge Report, dated 10/25/89: .

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' Attachment 4. Telephone Conference Memorandum fron P. Stead, dated .

10/26/89

, . Attachment 5.) Chemistry Sample Logs for Plant Discharge Tunnel dates 10/25-26/89 and Service Water Weir Structure, dated'

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ul0/25-26/89 Attachsent-6.~ Site. Topographic Map showing discharge point P . Attachment'7. NPDES Permit Limitations for the Plant. Discharge Tunnel ;

7 , (Structure) 1

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, 12. Describe any extenuating.circu,astances vhich caused the discharge.

Response LSee letter PY-CEI/0 EPA-0091L, dated 10/30/89 and Condition Raport which are attached, m .

13. Economic Impact -(This question is voluntary) .

(a) What was the-dollar value if any of the spilled product? '

-(b) What was the equipment damage cost? . l

-(c) What were the costs of spill cleanup? I

4. - (d) What are the estimated costs'of spill prevention'to eliminate

. possible, reoccurrence of this event?

Response .The economic impact was not considered significant and no ,

actual dollar amount vas determined. i

, . 14; . Provide'the name and~ title of the environmental contact (s) at your

company and'their telephone number.

. Response: -A1.Lambacher -4 Licensing Engineer

' Telephone No. (216) 259-3737, ext. 5520-i r

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<7 g l a:mmwcumn tr M C O M I N R E D 1I, - l

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~, THE CLEVELAND ELECTRIC ILLUMINATING COMPANY l

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PT-Q1/CEPA-0091L '

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.armoundo 0-e- ;

Bavironeestal-Engineer NOMATION OHl.Y Divistoa of Water Pollution Centrol" ;

Obie EPA, Northeast District Of fice '

1110 East Aurora Road I hrimsburg, Ohio 44047 i

,' to: Noacompliance Notificatios

Dear Mr. Gomes:

'la accordance with Part 111, paragraph 12.A. of OEFA Permit No. 31500016*CD, l this. notification is hereby submitted for a reportable event which occurred on October 25, 1989. '

11'No. Plaat Discherme Location Paraaster Discherme 1.iait Date

' iT65T Perry Discherse Tunnel Free avail 9 hours1.041667e-4 days 0.0025 hours 1.488095e-5 weeks 3.4245e-6 months (2 hours2.314815e-5 days 5.555556e-4 hours 3.306878e-6 weeks 7.61e-7 months 10/25/89 Event Descristion The Perry Plant Discharge Tunnel released free available chlorine at as appreminate concentraties of 0.2 ag/l between the heers of 10:10 AM and 9:35 l PM (approsiaately 9 hours1.041667e-4 days 0.0025 hours 1.488095e-5 weeks 3.4245e-6 months of actual discharge oecarred daring this period) es L October 25. 1949. The event occurred because the Service Water Chlorinaties

[ System was inadvertently placed in a contineses addition mode without the l

P

. Deehlorisation System operating. The Service Water Chierisation Systen sormally injects sodies hypochlorite for a 1/2 hour period twice per day, '

' daring which time the Dochlorination System is automatically initiated.

The Service Water Chlorinaties Systes is aeraall) controlled by 2 timers which

. set the f requency of sodium hypochlorite addition (overy 12 hours1.388889e-4 days 0.00333 hours 1.984127e-5 weeks 4.566e-6 months ) and the ,

duration of each addition (1/2 hour). During a chlorination period, which started at 10:10 AN en October 25, 1949, the servica Water Weir Structare f(apetream of the Dochlorination Systes injection potat) was sampled at 10:30 AM and had a free available eklerine concentration of 0.45 as/1. At 10:35 AM it was discovered that the Dechlorination System had failed' to start per its autoastic function, des to a power outage. At 10:40 AM the Plant Discharge Ttammel was saepted and had a froe available chlorine concentration of 0.20 as/1. _ Af ter the sample was taken of the Plant Discharge Tuanel, the

. Dochlorisation System was massally started. At 11:00 AM the Plant Discharge i

! Ttssnel was. re-sampled and me free available eklorine was detected. After the chlorisation cycle was confirmed to have been completed, the dochlorisation pump was secured. At 11:15 AM the technician was directed to adjust the E &____________--------~ - -- -

Attachment 1 o.R p ler. % Comes Jetober NFOR 1989 $ATION DU PY-CE1/0gPA-0091 L

' Service Water Chlorination timers to prevent further chlorination cycles until the cause of the dochlorisation probles could be determined. However, the *-

timers were mistakenly placed'in a position which caused continuous chlorination. At 6:00 PM the sodium hypochlorite storage taak was found empty and was refilled. Later evaluatione determined that the tank was empty at approminately. 3:40 pH, based on sodium hypochlorite addition rate. At 9:30 pH the probles was discovered, and taasdiate actions were taken to mammally start t the Dechlorisation system (which was still in a power outage). The tiests A were also reset to their moraal position so that the chlorination cycle would be completed at 10:00 PM. At 9:35 the Plant Discharge Tunnel was stapled and ne f ree available chlorine was detseted. At 10:00 pH the Service Water Weir Structure was sampled and had a free available chlorine concentrattom of 0.40 mg/1.

The free available chloriae release through the plant discharge tunnel was stopped at 9:35 pH when the Dechterination System was confirmed operational.

The release duration was approximately 9 hours1.041667e-4 days 0.0025 hours 1.488095e-5 weeks 3.4245e-6 months based on the total time staus ,

the periods when the Dechterisation System was in operation and the sodium hypochlorite storage tank was empty. Sample results for free available ehlorine of the Discharge Tuamel (0.2 ag/l at 10:40 AM) and the Service Water Weir Structure (0.45 mg/l at 10:30 AM and 0.40 mg/l at 10:00 PM) indicate that the f ree available chlorine daily concentration limit of 0.3 ag/l was not esteeded during the event.

The cause of this incident was the improper shutdown of the Service Water Chlorination Systoa. A teehaitian used the wrong procedure. The procedure that was used addressed a study of chlorination doses needed to control sobra massel infestation. It did not provide direction for shutting down the systes. The techaittaa had not received training concerning system shutdowa

and did not know another procedure existed for this task. The power outage

.ubich prevented the start of the Dochlorination Sysi;t a was also a contribating taster. .

' To prevent recurrence all applicable technicians and supervisors will receive ,

On-The-Job and Classroom training to further espand systen knowledge and ensure the correct operation, using the proper procedures, of all chlorination and Dechlorisation Systees. la addition, applicable plaat procedures will be reviewed and revised to ensare that power outages that will affect the operation of the Chlorination or Dochlorisation systems are recognised and aeted upon to preerst any fatore recurrence of this event.

Please contact me if you have any questions.

o Al Kaplan Vice president Nuclear Group

&Kinj e -

ee: Document Control Desk, NRC' T. Colburn*

p. Miland' ,

j Region III*

Mr. R. Ratsler (Lake County Emergency Planning Committee) *

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l Attachment 2 I ' 1 CONDITION REPORT

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[ .99 IIGS (ihr esek of fase for self!Jael spew.) 8 CR - - 2 W Peps I of MENTDATE/T!* 015COVERY DATE/T14 etT*Em W D15Epsty loin M io3o 4414lt% M56 thserwee Q Sw ch.4ha.

EVENT DESCRIPTION

.At Etief p.4 tcjtih'l dvrig 4t NNd 4 84 N 64-O b * *\' ** d b 'wr W C w h h N 4 % l\ wist Isv.C 40 !

A i tac ..e cc.a b w ) 04,s e. d. 6 t,ytte. h pdv'w's (bu,. ba cylc w p, f,,w a 64b c4 adtflM.

.w e.p;~ W NA ueu cokAw.Amg,. s evSvA)lg,yeto.O. > mgewu..% -.3 m 46 4k<. bd **k4 UIM .Ot4%i N hh8 E4fus,rtQ pca64C0.

INFORMATION ONLY letEDIATE CORRECTIVE ACTION (INCLtcE SV1'5)

%cwit. Se Mce, v.=Aert C W .i.J A b .a l SYSTENICCDPONENTS AFFECTED (INCLtcE %) RE0tMD4NT EQUIPENT IN SAE SYSTEN AVAILABLE Sarw u. wenn c.Lu.n se i fr4% HCNt. '

3CTIVITIES AW CoelTIONS PRIOR TO EVENT k (PERATI M COWIT!0N: h2 3 A 5 EACTOR PouER (NwfM): 34*/7 MhwW C.W, ti a ** W* E ACTOR PRESSURE: ***e i

RX WATER TDP (IF NON5AftstATED):

INITIATION CRiiERIA ORIGIN 4 TOR g L.f DATE SECTION l.b ()kvt0 L htANh,., t olh*lvt WC0 l then. '

TECH SPEC INv0LvtD - LCO INITIATED (ATTACH COPY) WORK IN!!!ATED? (INCLUDE .)

ps) ' C ACTIVE ' POTENTIAL A' O=R =0 U5 REVIEW DATE STA DATE

\06 2 .- Id*2(e-89 NDTIFICATION(ICLtSE rurvhTING REQUIEENT) (ATTACH EW)

Q 100EDIAig REPORTS

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bfENilaL LDL (PGP-adB)

TECH SPEC V10LAT10N? O YEs 0 NO RENARKS O PoToiltat Ry (pap lain)

% Fast Est 3"O , *f2 . 2> , 2 // - O wi nEtInimir iEPaif O ta est (os.orcialles efiries)

REVitutD. E QUIRED T10 EN 55 DATE er/,/,,.r/N5T42 ,~2 /0 -M-59

CDP @ 1ANCE REVIEW DATE LER NO. ASSIGNED SECTI(Be r- _ t' . I u [8.n ~

Y, .s 88" VIEW // DATE PORC REviEstaPPROvEQ DATE CM On5 Om PORC REVIEW E ETING NO. APPROVED DATE APPIENED DATE CR CLOSED DATE REMARKS CAUSE CODE Pk

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Attachment 2

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. EVENT NOTIFICATION R...E N-1.., ,....

NmTION ONLY

1. '

re Cellet*s Nome: AGUAEL A>E*n1CGK T1tle: C A / / T E 6 /' fA'1/ K o A S

event Time: h40 te DM Zone: E est O cor event oste: /.-ar -Sf w- .

EVENT CLA$$1FICAT10N Y N EVENT CAftGORY INITIATION $10NAL' CAU$t 0F FAILURE EERAL DEMODCY REACTOR TRIPISO4AN ECNet1 CAL SITE AntA ENU W NCY ESF ACTUATION ELECTRICAL ALERT ECCS ACTUATION X PUt5 pest tRROR LMuluAL tytNT $4FETY INXCT!!M FLou P40tIBURE INADtgueCY k 30.72 Nth-tERENCY LCO ACTION $fAfDENT ONER:

(

SECLA!TYl$ArtouARDS y OTWR: , f,g, TRANSPORTATION EVENT r 7 OTER:

' .50,M M J V ; g CMPONENT: 3 gj g gg gg g gg7 f4M J EVENT Ot$CRI 10N (vee CR Jt conpleted) ( see CR) eA 57-3W

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L 2 PoutR PRIOR 70 EVENT ($): App /,, 010 ALL $YSTD6 FLMCTION A$ ESJ1REDT h Yt$ 01r NO NO . ExPtAIN Ae04 '

CLARENT POER tyt m: /.10 % ANYTNING *tD&lluRL' (pt WT L8ER$T(EDT Yt$ h 2 IF 'Yt$'. EXPLAIN AA04, Ouf$10E AGENCY OR PER$0NNEL CORRECT!vt ACTION ($

ZCCVA6A CJA3/Vft //)'/D CIVI.'W/ f STAft($): y[M {,y )

LOCAL E$10 TNT ) NO WILL tt 074R:

lPRESSRELEA$t // prgA(4 MODE OF (PULATION (MT!L COMECTION: /* an gg F

OTHER INFORMATION REQUESTED BY NRC: 7 C /.rc MAA q G t~ o .<pyg A 6 - cA<E 6A/E V/A SU

. D/Sc.Hs9A Gf

.][. . xiri & AT/A4 C /A c,u/n CMA/c SS . p/gn.g nyspg spot'!D T/k1En 1

1 i' 0)oe2 to /lg jf p CR m..

CR- $f - 38) l NAME OF !@!Y10uAL LCD"'ACito: ,gop 3,7p,,( p-CALLER'S

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ONIA: PAP-0806 I

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i Attachment 3 1 Sheets 1 of 2 I Spill / Unauthorized Discharge Lor _-

Place a checknark as applicable:

OIL $ PILL CREMICAL/ HAZARDOUS $USSTANCE $ PILL into Vatervey N UNAUTBORIZED DISCRARGE Reportable to EPA: Yes X No a

1. Name of reporting individual: Dm1 $ . br4 & [d #6 7 l

2. Name of Shif t Supervisor devu M f FCe[/ ,

3. Time and duration of the spill or unauthorized discharge-(as best i m

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determined): //e r- -tr 12 6 -

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4. Time at which spill or unauthorized discharge was discovered:

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5. Source and location of spill or unauthorized discharge: .

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. Type of material and amount (g ,gg ,g ,, pouses):'? "' "4'*"~""

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r. ... spill or unauthorised

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7'.*i 7. *,Nessures takaa to eentain spill or.unauthorises) discharge:

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$ag,,gW gy ri M. 'Q t i .:' g . g ;),,9 ..p yqg g;gg g.yg': er..g- ,, ,, , ; 4.,,,s..h ;

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.'l S. Probable flow path of the spill or unauthorized discharge ,

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_ TWP L,' t ONIA: PAP.0806 l 8 Page 11 PAGE tL OF.h ., Rev.: 0

.{ . Attacheent 3 (Cont.)

Sheets 3 of 2 t .

.. .treassn.e t nat -

INFORMATION ONLY

1) Northwest sedimentation impoundaeat 1 stated vest of the industrial vaste lagoons

2) Major stress sedimentation impoundaeat located farther vest of No.1 above

3) Minor stress sedissatation impoundment located east of the Cooling i i

.,- -Towers Lake ' Erit'

5) None

10. Cause or cirev. stances which created the spill or unauthorized discharge tw < e.s.y o k w ud: ., +.~ c > .:,..pa: c A !

4:. , h v ot...: a nu .

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l '11. 'deather Conditions: e /we r j

12. Notifications fjg, Perses contacted ,

cheatstry Unit 2W[ Drv[ L dm n /c Eastern District 233I b Ck 48te'f r/ ,

Distributies Dispstehtar / TC,;-

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For off-site release of.

hasardens sekstansas.

.netify Perry Teveship , f ]L Fire Dept. Chief IV F For Transmissies/

Transformer Yard spills, notify S.O.C. Systes Operator 4; ,

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inv. pas , CONDITION / EVENT INVESTIGATION CR- 89 38'l p.g. / g 2 INVESTIGAT!tst SMWty

='

'INFORMATBN ONLY .

On 10/25/89 at 1010 a annual 1/2 hour chlorination cycle of the Service Vater -

(SV)' System was initiated per Chemistry Instruction ON11A CRI-39 Non-Program sample Analysis and Activites for SV Chlorination. At approximately 1040 a ,

ebenistry technician noticed that the sodium sulfite feedpump (dechlorination '

chemical) had not started. The technician lamediately sampled the plaat discharge tunnel and analysed it for Free Available chlorine (FAC). The result, 0.20 ppe was below the NPDES limit of <0.50 ppe. The technician then annually started the dochlorination pump and resampled the Plant Discharge Tunnel at 1100. The result was 0.0 ppe FAC. Af ter the chlorination cycle was complete .the dochlorination pump va.s secured. The technician then notified chemistry supervision of the failure of the dechlorination pump to start. At 1115, per direction of a chemistry supervisor, the technician adjusted the chlorination timers to prevent further chlorination cycles until the cause of the dochlorination probles could 1-be determined; however the timers were mistakenly placed in a position which l- caused continuous chlorination. Chemistry supervision investigated the pump start failure and discovered the power outage. At 1800 the sodium hypochlorite storage -

tank was found empty by operations and refilled to a level of 60%. Based on sodium hypochlorite addition rate the tank was empty at approximately 1540. At 2130 a chemistry technician reset the SV Chlorination System timers to their rN rmal position which ended the chlorination cycle at 2200 (Putting the timers in .

their normal positions stopped the Ma0CL addition 1/2 hour later). The chemistry technicias was aware of the power outage and at 2133 the Dochlorination System was manually started. At 2135 the Plant Discharge Tunnel was sampled and no FAC was detected. The Chemistry shif t Supervisor notified the Control Room of the }

situation. and this condition report was generated. The EPA and NRC vere properly I notified. The SV Chlorination System was shutdown by Operations a few hours later I -

to prevent any further chlorination cycles. .

l !

The FAC release through the plant discharge tur.nel was stopped at 2135 when the -

Dechlorination System was confirmed operational. The release duration was I approximately 9 hours1.041667e-4 days 0.0025 hours 1.488095e-5 weeks 3.4245e-6 months based on the total time minus the periods when the Dochlorination System was in operation and when the sodium hypochlorite storage tank was empty. The 9 hour1.041667e-4 days 0.0025 hours 1.488095e-5 weeks 3.4245e-6 months FAC release on 10/25/89 violated the NPDg8 permit which allows only 2 hours2.314815e-5 days 5.555556e-4 hours 3.306878e-6 weeks 7.61e-7 months of FAC (that is (0.5 ppe) discharge per day. Sample ,

results for free available chlorine of the Discharge Tunnel (0.2 ppe at 1040) and the Service Water Voir Structure (0.45 ppa at 1030 and 0.40 ppe at 2200) indicate .

that the FAC concentration limit of <0.5 ppe was not exceeded during the event. -

CAUSB:

1 l The root cause of the event was inadequate knowledge of system operation and associated training (A4 Cause code). The cause of this incident was the improper shutdown of the SV Chlorination Systes. A contract chesistry technician used the wrong procedure. The procedure that was used. Chemistry Procedure ON12A CRI-39 nere.sn se entwr) sect a (fC, hSkJJ C J &5 1

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Attachment 2

_.- A aW. uas W ' -CONDITION / EVENT INVESTIGATION CR- N - N/ p.,, J g ) ,

IWESTIGAfitM Stae44RY See-program 989-147 5W Chb riaation Data Acquisition, addren e;,

ehlorination deses needed to esterminate the sobra aussel. It did not provide .

direetten for shutting det a the system. The technicias had not received trainias -

esmeerning system shutdeve and did not know another procedure (0113& 301-P48) esisted for this task.

)

The er outage (F1005 da, energised) which protested the start of the erinaties Systes could have caused an immediate IEPDBS permit violaties. A consentration of > 0.5 ppa FAC at the Plant Discharge Strutture (as NFBBS posait ! j violation)' is possible while chlorinating SW or Esv vith dochlorination - ,

inoperable. Prior notificaties to the Cheatstry Shif t Superviser of power estages ;

that affect vital chlorinaties and dochlorinaties equipment will aller Chemistry '

to take appropriate actions necessary to prevent NPD88 permit violatieas.

1.

fEERECTIVE ACTICIIS: .

I I I All Chemistry Technicians vill receive On-The-Job training to ensure the correct ,

speration, using the proper procedures, of all Chlorination and Dochlorinaties Systems. Chemistry Technicians will not be allowed to perfore the SW &loriaation i evolution until they receive this OJT training. (CR 89-381-01) Responsible :

Section: RPS/CU Due Date 11-30-49. Manager RPS Concurrence C R L .

L All Chemistry Technicians and Supervisors vill attend a Classroom Session that vill provide an extensive review of t all PNPP Chlorination and Dochlorinaties Systems and their applicable procedures the NPDES permit; Zebra Mussel ;

I information: PNPP's method of dealing with the Zebra Mussel infestaties.

(CR-89-381-02) Res_ponsMle tion: RFS/CU Due Date 01-28-90. Manager RPS Concurrence V r -e - .

Applicable plant p'rocedures shall be reviewed and revised to ensure that power outages that will affect the operation of the chlorination or Dochloriaaties systems require the immediate notification of Chemistry. This vill alert chemistry personnel to possible PAC releases to the lake and laitiate a tiaaly i response to secure the chlorinaties system when applicable. (CR-89-381-03) pensible S ti OPS Due Date 06-30-90. Manager 0PS Concurrence

.aw 1s & /2 4 -37 FOR M . W . GMR t.K Until applicable procedures can be revised power supplies that would impact the operation of P48 SV/ESV Chlorination or P848 Plant Discharge Dechlorination ,

Systen vill be ta ed t require notification of Chemistry prior to i de-energizing. ( 9- -f)40 Responsible Section: TS Due Date 12-31-89. Manager l TS Concurrence X6,c u * * : n o ued .,= *C* - 4 6n. co .-

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- The Clevolend Electric illuminating Campany 15.EPHONE AND CONFERENCE MEMORANDUM g [

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f.!f' NPORMATOW ONLY , .

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Page 65 Rev. 1 f ,

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3: Dip semple shall only be utilised it both Sohnersible semple Pumps are inoperable. ,.

Rarteved 97: w o2(.~ I a/,d/9 V "

4

&aties Notes ,

A. When a neraally ase-radioactive systen beoemas esatWanted, contact the Unit Sepervisor to request a Ceedities Report la asserdasee with the guidanse et PAF-4606, Ceedities Reports and Ismediate Natifications, and

,' PAP-4 % 1, Osadest of Operations.

L

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. i t ' A, , Attachment 5 i hh est14: P&P-1101 Pages lit Rev.: 1 ,

Attachment 65 Peres P&P-1102-59 Les Coettoestles Amet tag Sheet contimmed Forms PAP-1101- Si nat. /o ss M

== rwr sanele I.D. Parameter Ties E-!=* t Rasalta ha t wi, Init Plut 4555 h we 6 c.9 C. 2 wovan [_;

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Rev.: 1 Attaabsent 37 Pors: PAP-1101-31 Plant Discherme 1htspel ter ,

. Date/ Time <a/ts/H / o lh samples submersible sample Pump Discharge P640-PS55 C, M " Results' !ast NFL Init Parameter , g,, , ,g, ,

. Free Available D/- p.2 avee - 6 -

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Remarks: M 3: Dip sample shall only be utilised if both submersible Sample Pumps are inoperable. ,.

. Reviewed By: W ro/r6/D

&attoa Metes A. Na a moraally neo-radioactive system becomes contaminated, contact the Unit Superviser to request a condition Report la accordance with the guidamee of P&P-0606, Candition Baperts and Iaeediate Notifications, and f[ PAP-0201, Ceedest of Operatieas.

4

. ./ .. Attachment 5

NFORMATB0HCHLY .

00:14 PAP-1101 Pages lit Rev. 1 ,

Attaahment 65 Pers: P&P-1101-59 3.s m s c.atin edi r. ' pap-11on- J/ ontei *A>/a./n

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l Th]-thllowing should be performed every 12 hours1.388889e-4 days 0.00333 hours 1.984127e-5 weeks 4.566e-6 months . Please try to stay as close to this 12 hour1.388889e-4 days 0.00333 hours 1.984127e-5 weeks 4.566e-6 months . interval as possible. This test is being conducted to determine the required

- freq;ency of chemical addition and the Sodium Hypochlorite (Na0CL) dose that vill kill the class which are fouling our SV and CV systems.

~11 Ch ck the Service Water (SV) Sodium Sulfite (Na2 50 3 ) storage tank level. Ensure that

- i t is W. >3o "

p ,. * ,, j

'2. . R: cord the level of the Na0CL SV/DJ storage tank prior to start of chem add. Level .I Gauge is located on 620' elevation of SV Bld near southwest corner door.

3. -In 'the SW Pumphouse on the 587 foot elevation, located on the North vall you vill see tha SV4 Chlorination System Control Panel H51-P027. Turn the PROGRAM TIMER P48-N040 to '

th3 sero (0) hour position. This vill activate the TREATMENT TIMER and commence I Chlorination of the SV system. Note the setting of the TREATMENT TIMER.

~4 R :et the PROGRAM TIMER to the 14 hour1.62037e-4 days 0.00389 hours 2.314815e-5 weeks 5.327e-6 months position.

NOTE: IF TEE PROGRAN TINER IS NOT RESET TER SYSTEM VILL CELORINATE CONTINUOUSLY IBffIL >

TEE TIMER IS RESET. THIS COU12 RESULT IN AN NPDES PEEKIT VIOLATION IF t DECELORIMATION FAILED TO KEEP UP VITE TER ADDITIONAL 010RINE.

'f i Adjust and log the Na0CL Flow Control Valves (of the operable pumps) to get a total flew of Na0CL as directed on the Non-Program Logsheet. :

6.. V31t 20 minutes af ter the Program Timer is reset and then sample the SV Cooling Tower '

VOir (The 20 minutes is necessary to allow chlorine levels to stabilize prior to '

c:cpling). The siphon sample line should be used if available. Ensure that a 2 minute r comple purge of siphon line prior to sampling. If climbing the ladder is necessary to sample use the required safety gear (T-type ladder harness). This veir is located near th3 HP access point on- the east side of .the TB.

7. Take a sample (approximately 25 minutes from the start of chlorination cycle) from the Discharge Structure dechlorination sample line and analyze for Free Available Chlorine. If any is detected immediately notify chemistry supervision.

8. .

Analyse the sample, using OM12A: CHI-79 Chlorine, Asperometric Titration Method, for frce available chlorine and record the result on the non-program logsheet.

4

9. . Ch:ck and log the post add level of the SV/ESV Na0CL storage tank.

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$y.D yg Service Vater Chlorination Data and Service Vater Weir Structure Sample Results P41 Dechlorination (Na 503) Storage .

I TankLevelcheckMdstbe ' #

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($ C5 Required Total Flav of Na0CL (see note below) (Sem) b c h i h.g) hg .g . !,

i Na0CL Flow Control Valve Setting For A Pump (gpa) Id' 2.5 3*0 2.5 z,9 9'o vffs)Na0CLFlowControlValve Setting For B Pump (gpe) ,

3'g % 3,0 Q0 Na0CL Flow Contrel Valve E y / [ g,,j Setting For C-Pump (gpe) ,, ,t I Na0CL Flow Control Valve Setting For D Pump (gps) #

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The desired total flow will be $4teraNed by chemistry supervision. If no total is indicated for the preserit sample date/ time use the previous required total flow.

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INFORMATION ONLY Page 4 of 14 !

DEPA 31800016'C0 '

~ f$ PART !, A - FINAL EFFLUENT LIMITATIONS AND MONITORING REQUfREMENTS

1. During the period beginning on the offective date of this permit and lasting :
-until the expiration date, the permittee is authorized to discharge in .
accordance with the following limitations and monitoring requirements from the ,
following outfall: 31800016004. $(E PART !!, OTHER REQUIREMENTS, for location ;
-of effluent sampling. '
EFFlufMT CHARACTERTSTIC OfSCHARGE LIMITATIONS MONITORING :
Concentration Leading REQUIREMENTS REPORTING Other Units (Specify) kg/ day Meas. Sample
{ggg UNITS PARAMETER 30 day Daily 30 day Baily Free. Tvoe l
50050 MG0 Flew - - -
- Daily Continuous ,
50064 og/l Free Available , 3 Chlorine" 0.2 (f.5 - - Daily Grab i
00011 #F Temperature * - - - - Daily Continuous .
There shall be no detectable amount in the discharge from this outfall of any priority pollutant, other than chromium and zine contained in chemicals added
. for cooling truer maintenance. As of the effective date of this permit, the permittee has stated it does not use chemicals for cooling tower maintenance ,
' that contain chromium or zine; therefore, this outfall does not centain
( chromium or zinc of fluent limitations as required by 40 CFR 423.15. If the permittee, in the future, uses chemicals for cooling tower maintenance which do ,
. contain chromium or zine the permittee shall apply, prior to the use of the '
chemicals, for a modification of this permit so as to include the appropriate '
offluent limitations and monitoring requirements for chromium and or zinc.
Requires intake (3!B00016800) monitoring'. Report intake /outfall temperature estimated to correspond to a maximum temperature differential sustained for one hour.
Neither free available chlorine nor total residual chlorine may be discharged
- from any unit for more than two hours in any one day and not more than one unit in any plant may discharge free available or total residual chlorine at any one time unless the utility can demonstrate to the State that the unit (s) in a particular location cannot operate at or below this level of chlorination.
Analyses are to be perfored by amperometric titration.
2. The pH (Reporting Code 00400) shall not be less than 6.0 5.U. nor greater than 9.0 5.U. and shall be monitored 2/ week by grab sample. '
t
3. Samples taken in compliance with monitoring requirements s'9ecified above shall be taken at Sampling Stations described in Part II, OTHER RE0VIREMENTS.
4. See PART II, OTHER REQUIREMENTS.
form EPA 4428
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. Attachment 7 bi - idbE D hr dI a i
(.c, . .
Page 7 of 14 i Q~ OEPA 31800016*CD .
l PART !!. OTHER REQUIREMENTS I
\
1 A. Description of the location of the required sampling stations are as i follows:
3
---line Station Descriotion of location !
31800016001 Discharge from regenerate neutra11 ration pits in the basement of water treatment building.
3!b00016002 Discharge from chemical cleaning lagoon, ' , ;
eastside of plant. *'
I 31800016004 At a point representative of discharge l prior to entry to the discharge tunnel.
l 31800016800 Intake water -- At inlet to plant from Lake Erie.
B. In the event the permittee's operation shall require the use of cooling -
l- water treatment additives, written permission must be obtained from the i
Ohio Environmental Protection Agency. The permittee shall demonstrate that the use of the additive in the concentrations expected will not be .
harmful or inimical to aquatic life as determined by acute static bioassays. ,
C. There shall be no discharge of polychlorinated biphenyl compounds, attributable to the permittee's operations.
D. The permittee's cooling water intake structure has been determined to reflect best technology available pursuant to Section 316(b) of the Clean Water Act (CWA).
h form EPA 4428
s. ..
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ML20005G170

Text

Attachment:

Dear Mr. Gomes:

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