ML19224A925
| ML19224A925 | |
| Person / Time | |
|---|---|
| Site: | Crane  |
| Issue date: | 06/28/1978 |
| From: | Metropolitan Edison Co |
| To: | Mullinix W NRC/IE |
| References | |
| 1810.1, TM-0183, TM-183, NUDOCS 7906130241 | |
| Download: ML19224A925 (11) | |
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l, TMI DOCUMENTS DCCUFENT NO-
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CO L"t' I'ADE ON __ J, OF DOCUSENT PROVIDED BY METROPOLITAN EDISON COMPANY.
iii:da R. Mullinix, NRC 175 09h5
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V 1810.1
,l Revision 1 06/28/78 THREE MILE ISLAND NUCLEAR STATION STATICN CHEMISTRY PROCEDURE 1810.1 NPCES PERMIT - CHEMISTRY REQUIREMENTS '
DO NOT REMoyg Table of. Effective Pages Paoe Date Revision Page Date Revision Page Date Revision 1.0 06/23/78 1
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Date I.,[nf7E ri 5-Approval '
,i Ccgnizant Dept. Head Cognizant Dept. Head Unit 1 PORC R m eods Approval Unit 2 PORC R om. er s Approval
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Date Chairma A of'PO RC Chairmin oIPORC Unit 1 Superintendent Approval Unit 2 Superintendent Apprcval 0
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Manager Generatico Quality Anurance Approval Date 175 0 9 E- --
1810.1 Revision 1 06/28/78 THREE MILE ISLAND NUCLEAR STATION PLANT CHEMISTRY PROCEDURE 1810.1 NPDES Permit - Chemistry Requirements 1.0 PURPOSE The purpose of this procedure is to outline the chemistry requirements f
for compliance with the National Pollutant Discharge Elimination Sys tem (NPDES) Permit.
2.0 DISCUSSION, TF.is procedure identifies sampling points and frequencies, parameters ta be measured both at Three Mile Island and outside labs, allowable limits for the measured parameters, and reporting requirements.
3.0 REFERENCE _5 3.1 GP 0025 -- Reportir.g NPDES Non Ccmplianct 3.2 GP 0028 -- NP3ES_ Routine Reports 3.3 SCP 1900 -- Detcrmination of pH 3.4 SCP 1916 -- Determination of Copper
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3.5 SCP 1918 -- Determination of Iron 3.6 SCP 1929 -- Determination of total suspended solids 3.7 SCP 1940 -- Cetermination of free and total available chlorine 3.8 NPDES Permit 0009920 4.0 EQUIPMENT As described in applicable procedures.
5.0 PROCEDURE 5.1 TMI Responsibilities.
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Revision 1 06/28/78 5.1.1 Sample Points NUMBER NAME 001 a)
Ccmbined Mechanical Draft Cooling Tcwer Blowdown--
Sample obtained from discharge of pump for RML-7 (SR-P4).
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Mechanical Draf t Cooling Tower basin (If SR-P4 is out of service) - Grab Sample.
002 Unit 1 Mechanical Craf t Cooling Tower Emergency Dump--Grab Sample 003 Uni t 2 Mechanical DrL(t Ccoling Tower Emergency Dump--Grab San.pla 004
- ast Dike Emergency Discharge--Grab Sample 10:
Treated Sewage Effluent--Sample point will be designated later.
1:3 Pre Cp Cleaning and Flushing Settling Basins--Sample frcm disch3rge of recirc pump CC-P3 a t CCV-69 104 Industrial Waste Treatment Discharge (Matz)--Sample.. -.
effluent from IWV 105
' us ce Neutralization Tank--Sample at CE 56 (Unit I)
.i 107 Waste Treatment Facility-Eample at Valve IW-V-106 108 Waste Neutralization T nk WT-T-9--Sample at WT-PV-3 a
5.1.2 Sampling Frequency.
5.1.2.1 Figure 1810.1-1 indicates the m.nimum sac.pling and analysis frequency for compliance with the NPDES Permit.
5.1.2.2 It does not alter our requirements for sampling and analyzing for ccmpliance with technical specifications or other permits.
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1810.1 Revision 1 06/28/78 5.1.3 Parameter Limits 5.1.3.1 Figure 1810.1-2 contains the applicable parameter limits.
5.1. 4 Recording of Results.
5.1.4.1 The following data will be placed on teh NPDES Chamistry Data Sheet (Form 1810.1-1) and in the Chemistry Lab Log Book.
1.
The exact place, discharge number, and time of sampling.
2.
The person (s) wF obtained the sample.
3.
The dates the an.yses were performed.
4.
The person (s) who performed the analyses.
5.
The analytical techniques or methods used.
6.
The results of all required analyses.
7.
'lhen applicable, the da*.e sarple is shipped off site.
8.
Record totalizer reading from recorder FM 342.
5.1.4.2 Additional F.onitoring results must also be recorded on a NPDES Chemistry Cata Sheet.
If the permittee monitors any pollutant designated herein, at the location designated herein more frequently than required by this permit, using approved analytical nethods as specified above, the results of such monitoring shall be included in the calculation and reporting of the values required in the Discharge Manitoring Report Form (EPA No. 3320-1).
Such increased frequency shall also be indicated.
5.1.4.3 Exceptions 1.
Results of Free Available Chlorine analyses at RML-7--
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Discharge #C01 will be reported on the normal Chlcrination i
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Chemistry data sheet instead of the NPCES Chemistry Cata ~
Sheet.
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1810.1 Revision 0 2.
Results of pH measurements on discharge point #001 will be recorded on the River Water Discharge Schedule data sheet of SP 1301-9.10,. as well as the normal Miscellaneous Water Analysis Report Data Sheet.
5.1.5 Storage of Data 5.1.5.1 NPDES Chemistry Data Sheets and the data sheets for discharge point #001 analyses will be retained in the chemistry office files for a minimum of three (3) years as stated by the permit.
5.1.5.2 Maintenance of Meter Calibration records for laboratory and online instrumentation will be maintained by the instrument department for a minimum of three (3) years.
5.?
GPU SYSTEMS LABORATORY REQUIREMENTS 5.2.1 Sample Scheduling
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5.2.1.1 All monthly samples to be analyzed by the GPU Lab for TMI should be taken and forwarded to the GPU Lab during the first week of each month.
5.2.1.2 All bi-weekly samples should be taken and forwarded to the GPU Lab during the first and third week of each month.
5.2.2 Sample Preparation 5.2.2.1 All samples sent to GPU for analysis should be clearly labeled with the folicwing information.
1.
Plant's name
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Sample Source: MPDES Permit discharge number and name of discharge point.
3.
Date sample was taken
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Sampler's name or initiais
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09-19-75 1810.1 Revision 0 5.
Sample type-grab or composite 6.
Time semple was taken or time interval, if composite 7.
Preservation--what preservative was added and how much was added to sample.
8.
Analysis to be performed.
3.2.2.2 Securely tape the lid of the contaner to prevent spillage during shipping.
5.2.2.3 Prepare labels for sending samples as follows:
GPU Service Corporation System Laboratory Environmental Division Reading, Pennsylvania 19601 5.2.2.4 Package the bottle and send to GPU System Lab via the Fet-Ed courier service.
5.2.3 Sample. Collection
- . 2. 3.1 0il and grease analysis NOTE:
Samples must be analyzed for oil and grease within 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> after sampling.
It is important that samples for oil and grease analysis be obtained just prior to 5:00 P.M. when tne courier service picks up the mail. Attempts should also be made to perform this sampling on Ponday, Tuesday, Wednesday or Thursday so that GPU System Lab can more conveniently per-form the analyses.
1.
Collect the required samples in specially cleaned one liter glass bottles provided by GPU Lab.
2.
Do not rinse bottle with the sample. After an appropriate 4
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line flush, fill to the shoulder and cap the bottle.
O 5.0 i
1810.1 Revision 1 06/28/78 3.
Add five milliliters of concentrated H SO to the sample 2 4 and mix prior to shipping.
4.
Send sample to GPU Lab as outlined above.
5.2.3.2 Total Phosphorus Analysis l.
Collect required samples in 500 ml poly bottles, 2.
Rinse three times with sample and add 1 al H 50.
2 4 3.
Forward samples to GPU Lab as outlined above.
5.2.4 QA/QC Program 5.2.4.1 Split Samples 1.
On a frequency of a least t.vice a year, TMI and System Laboratory will split samples for duplicate analysis.
2.
The samples may be taken at any discharge point for this purpose.
3.
Two. samples will be taken, one for TSS ccmparison analysis and one for iron and copper analysis.
4.
The sample volumes and preservation will be as listed
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Analysis Con tainer Volume Preservation TSS Plastic 1 liter None Fe & Cu Plastic 500 ml 5 ml conc. HNO3 5.
All samples will be grab samples.
5.2.4.2 Kncwn Standards 1.
On a frequency of once per 6 nonths, preparra iron and copper standards will be sent to TMI by System Laboratory for analysis.
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The iron and copper standards will be either EPA or or NBS traceable standards.
5.2.4.3 Spot Checks 1.
On a frequency of at least once per year System Laboratory will visit TMI to review their analytical tecnniques.
2.
This review will cover general laboratory procedure and any improper techniques used in performing routine analysis such as pH, chlorine and conductivity.
5.2.4.2 The System Laboratory will keep records of analysis results frcm split samples and the standards, which will be forwarded to TMI and the RS & EE representative.
5.2.4.5 The Chemistry Superviscr/ Foreman will review the results of each QA/QC chc:k no latar than one (1) gonth after receipt of results.
5.2.4.6 These results will be filed in the Chemistry Department file and stored for a minimum of three (3) years.
5.3 ANALYSES PERFORMED BY GILBERT'S LABORATORY 5.3.1 Fecal Coliform and BOD 5.3.1.1 These analyses will be performed on samples collected at discharge point number 101 (Treated Sewage -' fluent).
Methods for obtaining these samples will be established in the future when the system becomes operational.
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FICURE 1810.1-1 1810.1 Sampic Frequer.cy Revision 1 06/28/78 Oi l ti Fecal Free C/2 pH Total Fe
@u 002 (1) 1/ day 003 (1)
GPU 1/ day
'004 (1)
GPU 1/ day 4 hr. comp GPU GAI GAI 101 (2) 2/rontn 2/ month 2/ month 2/ month 2/ month 4 hr. comp GPU 10 3
( 1) 2/ronth 1/ month 2 / month 1/ month 2/ month GPU 10 4 2/r.on t7 2/ month 2/ month GPU 10 5 (3)
"r i-2/a onth 2/ month 2/ month GPU 107 2/ month 2/ month 2/ month 2/ month 2/ month GPU 108 (3) 2/aonth 2/ month 2/ month
_Unless otheniise noted, all samples are grab samples.
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UAll Oil & Grease and Total Phosphorus analyses will be performed by GPU Systems Lab.
g Tgi) Upon notification by operations that these discharge points are being used.
__g:, g2 ) When scuage treatment plant is operable.
~(3)~DURIt..iDISCHARGE.
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PARAMETER LIttITS 1810.1
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I Fiqure 1810.1-2 h$Y})f90 Free C/2 Total Fe Total Sus 7tMIi IctWP Oil & Grease 3ecal Coliform M
pil ppm _
ppm Solids ppm ppm ppm ppn per 100 ml poh Daily-Avg-Max 031 0.2 0.5 1aily-Avg-hax 002 NA 10 Iaily-Av0-liax 033 NA 10
')aily-AVE-!)ax 004 flA 10 Mth-Avg-30 Mth-Avg-2 Mth-Avg-200 Mth-Avg-3' 101 6-9 Uk.-Avg-45 Wk.-Avg-4 Uk.-Ava-400 ldk. - Avg-4 :
Daily-Avg-Max Dally-Avg-Max Daily-Avg-Max Daily-Avg-Max 103 6-9 1.0 1.0 30 100 1.0 1.0 15 20 Daily-Avg-Max Daily-Avg-Max 104 6-9 30 100 15 20 Daily-Avg-Max Daily-Avg '2x 105 6-9 llb) 12 73.4 (Ib) 6
'.4.7 Daily-Avg-Max Oaily-Avg-Hox ua l l y-Avg -FIIx-ually-nyg-Max 107 6-9 (lb) 1.2 2.4 flb) 36 240 (lb) 1.2 2.4 (lb) 18.1 48.1 Daily-Avg-Max 108 6-9 Daily-Avg-Max 30 100 15 20
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The " daily' average" concentration means the arithmetic average of all the daily determinations of concentration made during a calendar month.
Daily determinations of concentration made using a composite sample shall be the concentration of the composite sample.
When grab samples are used, the daily determination of concentration shall be the arithmetic average of all the samples collected during that calendar day.
1 2.
The " daily maximum" concentration means the daily determination of concentration for any calendar day.
flA - flot Applicable.
Limits util be applied after July 1,1977. Analyses must still be completed and results reported.
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Revision 1 flPDES CHEMISTP.Y CATA SHEET 06/28/78 Samp1e Point flame Sample Point Discharge fiumber Time Sampled Date Sampled Sarpled By Totalizer Reading s %
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Total (pom) Sus Solids
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Total Fe (ccm)
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Total Cu (com)
Oil & Grease Total Phoschorus 800 Fecal Caliform I
a Ccmpare values obtained by analysis with Parameter Limits on Figure 1810.1-2 of NPDES Procedure and circle any value exceeding the daily maximum.
NOTE: All this information must be placed im the Chemistry Lab Log Book.
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\\15-\\C0 10.0 Form 1810.1-1 i
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