Text

Requests Approval for Replacement of Several Water Conditioning Chemicals Used at Facility W/Equivalent or Similar Chemicals.List of Equivalent Water Conditioning Chemicals Encl
	ML18026A241
Person / Time
Site:	Susquehanna
Issue date:	09/30/1991
From:	Fields J; PENNSYLVANIA POWER & LIGHT CO.
To:	Swerdon P; PENNSYLVANIA, COMMONWEALTH OF
References
	PLE-14736, NUDOCS 9110080317
	Download: ML18026A241 (100)
	v • d • e

,'CC~ELERATED DI BUTION DEMONS TION SYSTEM REGULATORY INFORMATION DISTRIBUTION SYSTEM (RIDS)

ACCESSXON NBR:9110080317 DOC.DATE: 91/09/30 NOTARIZED: NO DOCKET FACIL:50-387 Susquehanna Steam Electric Station, Unit 1, Pennsylva 05000387 50-388 Susquehanna Steam Electric Station, Unit 2, Pennsylva 05000388 AUTH. NAME AUTHOR AFFILIATION FIELDS,J.S. Pennsylvania Power & Light Co.

RECIP.NAME RECIPIENT AFFXLIATION R SWERDON,P.M. Pennsylvania, Commonwealth of

SUBJECT:

Requests approval for replacement of several water conditioning chemicals used at facility w/equivalent or similar chemicals. List of equivalent water conditioning D chemicals encl.

S DISTRIBUTION CODE: C001D COPIES RECEIVED:LTR ENCL SIZE:

TITLE: Licensing Submittal: Environmental Rept Amdt & Related Correspondence /

NOTES:LPDR 1 cy Transcripts. 05000387 A LPDR 1 cy Transcripts. 05000388

~+~ <~P4'~~S(S~Viim D RECIPIENT COPI S RECXPIENT COPIES D ID CODE/NAME LTTR ENCL ID CODE/NAME LTTR ENCL PD1-2 LA 3 3 PD1-2 PD 1 1 RALEIGH,J. 1 1 INTERNAL: ACRS 6 6 NRR/DET/ESGB 8D 1 1 OC/LF 1 0 OGC/HDS2 1 0 RE FXLE 01 1 1 RGN1 DRSS/RPB 1 1 EXTERNAL G&G SXMPSON g F 2 2 NRC PDR 1 1 NSIC 1 1 NOTES:

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TOTAL NUMBER OF COPIES REQUIRED: LTTR 22 ENCL 20 I p

Pennsylvania Power &, Light Company Two North Ninth Street~Allentown, PA 18101-1179 ~ 215/774-5151 September 30, 1991 Hr. Paul H. Swerdon Chief, Facilities and Construction Grants Section Water Quality Management Pennsylvania Department of Environmental Resources 90 E. Union Street, 2nd Floor Wilkes-Barre, PA 18701-3296 SUSQUEHANNA STEAN ELECTRIC STATION NPDES PERHIT NO. PA 0047325 REQUEST FOR APPROVAL OF EQUIVALENT WATER CONDITIONING CHEMICALS CCN 741326 FILE R9-8A PL E-14736

Dear Hr. Swerdon:

The Pennsylvania Power and Light Company (PP&L) requests approval for the replacement of several water conditioning chemicals used at the Susquehanna

'Steam Electric Station (SES) with equivalent or similar chemicals. Chemicals currently approved for use by the Pennsylvania Department of Environmental Resources (PaDER) are listed in Part C of NPDES permit no. PA 0047325.

Specific chemicals, use rates, concentrations, and product facts are listed in Section VI of the June 23, 1989, NPDES permit application.

Selection of new water conditioning chemicals is a result of corporate requirements for rebidding of major contracts along with the effort to select the best chemicals available to minimize pipe corrosion, scaling, and settling of river solids in the cooling system. Testing of these chemicals began in June 1991 and will be completed in October 1991. A letter was sent to Hr.

Stanley J. Lehman. of your office (PLE-14354, June 7, 1991) discussing the testing. strategy for these chemicals. PP&L plans to select the successful bidder by mid-November and begin using the chemicals by the end of 1991.

As we discussed at our August 26, 1991 meeting, it was unclear if an amendment to the NPDES permit was required for use of these equivalent water conditioning chemicals. Certain corrosion inhibitors discussed at this meeting were included in the analytical data provided in Section V of the permit application and need not require additional approvals. For example, zinc-sulfate, a carbon steel corrosion inhibitor, has already been approved in this manner. Other water conditioning chemicals not specifically included in Section V sampling data were previously included in Section VI of the original application.

In telephone conversations with you and Hr. Stuart Gansell, Acting Chief, Division of Permits and Compliance, PaDER Harrisburg office on September 3, 1991, the question of whether or not an amendment is necessary every time an equivalent water conditioning chemical is to be used was addressed. Since

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PLE-14736 September 30, 1991 CCN 741326 FILE R9-8A PP&L will continue to use chemicals with the same main chemical constituents to be discharged to permitted NPDES outfalls, in essence there is no change to the PaDER approved water conditioning chemicals listed in permit number PA 0047325. The only changes would be in manufact'urer and trade names.

Based on our meeting and subsequent telephone conversations, PP&L is submitting a list of equivalent water conditioning chemicals following permit application Section VI format for your review and approval. Also, attached are Haterial Safety Data Sheets for these equivalent chemicals.

If you have any questions or comments, please call me at (215) 774-7889.

Sincerely, Jer me S. Fields Sr. Environmental Scientist-Nuclear js f/1 ti 918c(25) cc: S,Gansell- PaDER, Harrisburg PRC Document Control Desk NRC Region I Hr. J. J. Raleigh, NRC Project Hanager

ER-BWG-288. {Rev. 12/82) NPDES Number PA 0047325 Vl. INFORMATIONAND ANALYSIS OF EFFLUENT QUALITYFOR OTHER POTENTIALLYTOXIC POLLUTANTS i KNOWN OR EXPECTED TO BE PRESENT IN THE DISCHARGE

..9110080317 IRead instructions carefully and use the tabular format and additional pages, where necessary, to present the required information)

Average Analytical Effluent Detection Outfall Chemical Substance or Compound Reason for Presence in Discharge Concentration Level Iugf)) Iugn)

APPROVED 071 Betz Powerline 3451 This product is used as an alternate calcium 500 to 1500 ug/I as 200 ug/I carbonate scale inhibitor and cooling water HEDP, as HEDP using field Blend of the copolymer in Betz Powerline dispersant. 7000 to 20,000 ug/I test 3450 and a scale inhibitor phosphonic As product acid, (1-hydroxyethylidene), Bis-. The phosphonic acid is also known as HEDP.

EQUIVALENT CHEMICALS 071 Calgon QCL-2000 This product will be used as a calcium 1000 ug/I as HEDP, 200 ug/I as HEDP (1-Hydroxyethylidene) Bisphosphonic Acid carbonate scale inhibitor. 8500 ug/I as product using field test Cas ¹2809-21-4 I

071 Drew WRICO CTP 888 This product will be used as a calcium 1000 ug/I as HEDP, 200 ug/I as HEDP (1-Hydroxyethylidene) Bisphosphonic Acid carbonate scale inhibitor. 8300 ug/I as product using field test Cas ¹2809-21-4 071 Betz PPL09 This product will be used as a calcium 1000 ug/I as HEDP, 200 ug/I as HEDP (1-Hydroxyethylidene) Bisphosphonic Acid carbonate scale inhibitor. 3200 ug/I as product using field test Cas ¹2809-21-4

.071 Nalco DYNACOOL 1383 This product will be used as a calcium 600 ug/I as HEDP, 200 ug/I as HEDP Potassium Phosphonate and Polyacrylates carbonate scale inhibitor. 600 ug/I as polymer, using field test 6000 ug/I as product NOTE: PaDER Form ER-BWG-288.10 (Rev. 12/82) was reproduced for this report.

ER-BWG-288.10 (Rev. 12/82) NPDES Number PA 0047325 Vl. INFORMATION AND ANALYSIS OF EFFLUENT QUALITYFOR OTHER POTENTIALLYTOXIC POLLUTANTS KNOWN OR EXPECTED TO BE PRESENT IN THE DISCHARGE (Read instructions carefully and use the tabular format and additional pages, where necessary, to present the required information)

Average Analytical Effluent Detection Outfall Chemical Substance or Compound Reason for Presence In Discharge Concentration Level Iugn) Iugnl APPROVED 071 Betz Powerline PPL-04 This product is used as a copper and 1200 to 2500 ug/I 200 ug/I copper alloy corrosion inhibitor as TTA, as TTA using field Benzotriazole, Methyl, Sodium salt. Also 2800 to 5800 ug/I test known as TTA (tolytriazole) as product EQUIVALENT CHEMICALS 071 Calgon Triazole PCL-50 This product is used as a copper and 1000-1200 ug/I as 200 ug/I as TIA Sodium tolytriazole copper alloy corrosion inhibitor. TTA, using field test Cas ¹64665-57-2 2600 ug/I as product.

071 Drew WPD11-166 This product is used as a copper and, 1000-1500 ug/I as 200 ug/I as TTA Sodium tolytriazole copper alloy corrosion inhibitor. TTA, using field test Cas ¹64665-57-2 2300 ug/I-3500 ug/I as product 071 Nalco 1326 This product is used as a copper and 1000-1200 ug/I as 200 ug/I as TIA Sodium tolytriazole copper alloy corrosion inhibitor. TTA, using field test Cas ¹64665-57-2 2500 ug/I as product

ER-BWG-2 0 IRev. 12/82) NPDES Number PA<<0047325 VI. INFORIVIATIONAND ANALYSIS OF EFFLUENT QUALITYFOR OTHER POTENTIALLYTOXIC POLLUTANTS KNOWN OR EXPECTED TO BE PRESENT IN THE DISCHARGE IRead instructions carefully and use the tabular format and additional pages, where necessary, to present the required information)

Average Analytical Effluent Detection Outfall Chemical Substance or Compound Reason for Presence ln Discharge Concentration Level lugni Iugni APPROVED 071 Betz Powerline 3450 This product is used as a cooling water 1250-5000 ug/I as 1250 ug/I dispersant for the maintenance of clean polymer, as polymer Copolymer of 2-propenoic acid and 1,2- heat transfer surfaces. 7000 to 20,000 ug/I propanediol mono 2-proenoate and water as product EQUIVALENT CHEMICALS 071 Betz PPL08 This pioduct is used to facilitate silt, 2200-3000 ug/I as 1750 ug/I as Polymer sediment, iron and magnesium dispersion. polymer, polymer 7300-10,000 ug/I as product 071 Calgon PCL-401 This product is used to facilitate silt, 2000-2500 ug/I as 1750 ug/I as Polymer sediment, iron, and magnesium dispersion. polymer, polymer 8000 ug/I as product 071 Nalco 8356D Dispersant This product is used to facilitate silt, 3400 ug/I as 1750 ug/I as Acrylate Polymer Cas ¹7631-90-5 sediment, iron and magnesium dispersion. polymer, polymer 10000 ug/I as product 071 Drew WPD 11-136 Antiscalant This product is used to facilitate silt, 2000 ug/I as 1750 ug/I Sodium Polyacrylate sediment, iron and magnesium dispersion. polymer, as polymer Cas ¹9003-04-7 5600 ug/I as product 071 J-POLY 101 C This product is used to facilitate silt, 500-1000 ug/I as 200 ug/I as Sodium Polyacrylate sediment, iron and magnesium dispersion. polymer, polymer Cas ¹9003-04-7 1000-2000 ug/I as product

ER-BWG-288.10 (Rev. 12/82) NPDES Number PA 0047325 VI. INFORMATION AND ANALYSIS OF EFFLUENT QUALITY FOR OTHER POTENTIALLYTOXIC POLLUTANTS KNOWN OR EXPECTED TO BE PRESENT IN THE DISCHARGE 4

(Read instructions carefully and use the tabular format and additional pages, where necessary, to present the required information)

Average Analytical Effluent Detection Outfall Chemical Substance or Compound Reason for Presence in Discharge Concentration Level Iugiil (ugll)

APPROVED 071 Betz Clam-Trol CT 1 Molluscide used for Asiatic Clam control <200 ug/I as 200 ug/I Alkyl dimethyl benzylammonium and as a cooling tower biocide. biocide, as biocide using chloride Cas ¹68424-85-1 10,000-50,000 ug/I field test Isopropyl Alcohol Cas ¹67-63-0 as product Dodecylguanide Hydrochloride Cas ¹13590-97-1 Ethyl Alcohol Cas ¹64-17-5 EQUIVALENT CHEMICALS 071 Calgon H-130 Microbiocide Molluscide used for Asiatic Clam control <200 ug/I as 200 ug/I as biocide Didecyl Dimenthyl Ammonium Chloride and as a cooling tower biocide. biocide, using field test Cas ¹7173-51-5 2500 ug/I as product Ethyl Alcohol Cas ¹64-1 7-5 071 Drew Biospherse 3204 Molluscide used for Asiatic Clam control <200 ug/I as 200 ug/I as biocide Quartenary Ammonium Compd and as a cooling tower biocide biocide, using field test Polyethoxylate 8000-80,000 ug/I as product

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- ---SECTION 5- -- -FIRST AID'NSTRUCTIONS SKIN CONTACT+*+

REMOVE CONTAMINATED CLOTHINQ.WASH EXPOSED AREA 'WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MINUTES EYE CONTACT*+*

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MANUFACTURER'S NAME EMERGENCY Calgon Corporation TELEPHONE NO. 412/777-8000 ADDRESS P. O. Box 1346, Pittsburgh, Pennsylvania 15230 CHEMICAL NAME FORMULA AND SYNONYMS IV)ulticomponent Liquid r, Q rr

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Chemical Name Common Name Chemical Name Cor'nrnon Name Chemical Name Common Name Chemical Name Common Name I t ~ ~ s' el 4-Similar to Water 1.062 - 1.072 BOILING POINT I F) SPECIFIC GRAVITY.lHsO>>I)

PERCENT VOLATILE VAPOR PRESSURE lmmHg.) Similar to Water BY VOLUME (%)

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B. SKIN Not Applicable.

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WASTE DISPOSAL METHOD Dispose in accordance with local, state and federal regulations.

PROTECTIVE GLOVES EYE PROTECTION Not required Chemical splash goggles

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AI'R-89-1991 87: 48 FROM DREW BOONTON SALES ADMIN. TO VALLEY FORGE PA P,P4 Drew AQLJV industrialIg, Division Emergency MATERIAl SAFETY One Drew Plass, Boonton,'Mow Jereey 0700$ Telephone OATA SHEET PIsone (201) 263"7600/TeIex 136444 I (800) 274 $ 263 or 1(800) ASHLAND WRICO CTP 888 CORROSION INHIBITOR Page: 2 CONTAMINATED CLOIHIHG. LAUNDER CONTAMINATED CLOTHIHG BEFORE RE%SR.

RECEIVE CONTAMINATED $ ?OES PACNWrTLY. DISCARD 9%ES SATURATED WITH 'IHIS PRODUCT.

IF IH EYESs I~IATELYFLUSH WiTH LARGE AMOVNTSOF WATER FOR AT LEAST IS MINUTES, LIFTING UPPER AHD LOWER L10$

OCCASIONALLY. GET ilesEDIATE INDICAL ATTEM'ION~

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IF SWALL'OWEDs 00 HOT iteUCE V(NITING. VQMITIHG WILL CAUSE FURLER DAMAGE TO THE THEAT. DILUTE SY GIVING WATER. GIVE MILK OF IAGNESIA. KEEP WARN. (<<VIET~ GET IKOICAL ATTENTION IIHCDIATELY.

IF BREATl+Ds IF AFFECTED REMOVE IIOIVIDUALTQ FRESH.AIR. IF BREA'l?IING IS DIFFICULT, ACNINISTER OXYGEN. IF BREAT?IING HAS STQPP00. GIVE ARTIFICIAL RESPIRATIO¹ KEEP PERSON WARM<<QUIETs AHO GET AE<<OICAL ATTEHTIOH.

PAWLRY ROUTE(S) OF EHTRYs I ttIALATICH, SKIN COHTACT EFFECTS OF CHROIC OVEREXPOSUREs OVEREXPQSURF. TQ THIS MATERIAL (OR ITS CCMPONENTS) HAS APPARENTLY BEEN FOUND TO CAUSE THE FOLLOWING EFFECTS IH LABORATORY AHIMlLSs ~ BLOOD ABNORMALI TIES HAZAAOQVS POLYMERIZATION? CANNOT OCCVR STABII.ITYs STABLE IN~ATIBILITYs AVOiD CONTACT WITH:. STRONG ALKALIES.~ STROHG OXIDIZIHG AGEHTS.

t ~oS M

TO SR TAKEN Ik CASE MATERIAL IS RELEASED OR SPII.LEDs SPILLs COVER Tl% CONTAMINATED SURPACE Wl's?I SODIUM BICARB(%ATE OR A SODA ASH/SLAKED LIME MIXIUAE <50"50) ~

MIX AND ADD WATER IF NECESSARY TO FORM A SLURRY. SCOOP UP SLURRY AHD lEASH $ 1TE WITH SODA ASH SOLOTION.

LARGE SPILLs PERSONS HOT WEARING PROTECTIVE EQUIPNEHT SICVLD BE EXCLUDED FACM AREA OF SPiLL. $ 1OP SPILL AT SOURCE. DIKE TQ PREVENT SPREADING.

RESIDUES FOR DISPOSAL.

WASTE DISPOSAI. MRT?CDs CAREFULLY ADD LIME OR SODIW CARBONATE TO NEUTRALIZE ACID. CONTAINERIZE SMlLL SPILLs DISPOSE QF IH ACCORDANCE WITH ALL LOCAL~ STATE Ate FEDERAL REGULATIQHS.

LARGE SPILLs DISPOSE OF IN ACCOIDAHCR WITH ALL LOCAL, STATE AHD FEOERAI. REGULATIONS.

RESPIRATORY PROTECTIOHs IF WORKPLACE EXPOSVAE LIMIT(S) OF PRODUCT OR ANY CO6@HENT IS EXCEEDED (SEE A HIOSH/MSHA APPAOVEO AlR SUPPLIED RESPlRATOR IS ADVISED IH ABSENCE OF PROPER ENVIR(Ã44ENTAL SE~'ll),

CONTROL OSHl REGULATIOHS ALSO PERMIT CARR NIOQVICiHk RESPiRATORS EGATIVE PRESSURE TYPE) UNDER SPECIFIED CONDITIONS SEE YQVR SAFETY EGUIPIRNT SUPPLIER) ~ ENGINEERING CR IHISTRATIVE CQITROLS g%ULO BE IIBsLEhKHTED TQ EDUCE EXPOSURE.

VENTILATIONs PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHlVST) VENTILATION.TQ.MAINTAINEXPOSVRE LEVEL OF OVEAEXPOSVAC.<<(HKN<<IQCfS=SUSPECTED OR'APPARENT"ADVERSE~ EFFECTS)') ' <<- = << 's BELOW PROTECTIVE GLOVE$ s WEAR RESISTANT GLOVES SUCH AS:. NEOPRENE EYE PROTECTIOHs 0%MlCAI SPLASH G(XIGLES AHD FACE SHIELD (8'IH.) IH COIPLIAHCE WITH OSHA REGULATIONS ARE ADVISEDS fOWEVER<<OSHA REGULATIONS ALSO PERMIT OT?KR TYPE SAFETY GLASSES<<(CONSULT YOVR SAFETY SVPPLid) EOIIPMEHT OPER PROTECTIVE EQUIPIHtTs -TQ PREVENT SKiN CONTACT, WEAR IlesRRVIOUS CLOT?IING AMt B(OT$ ,

~

CQHTA/HERS OF ~S MLTERIAL MAY BE HAZARDOUS %%N EtisTIED.SINCE EMPTIED CKI'AIHERS RETAIH PRODUCT RESIDUES (VAPOR, LIQUID<<AND/OR SOLID) ~ ALL HhZARD PRECAUTIONS GIVEN IN T3% DATA 9%ET MUST BE OBSERVED, Tl% INFORILlTIOH ACCUCIIATED I%REIN IS BELIEVED TO BE ACCURATE BUT IS HOT WARRANTED TO BE seIH?Kit ORIGINATING WITH TlC C(MSPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED lHAT T?IE INFORMATION IS CURRENT, APPLICABLE, AIO SUITABLE TO Tt%IR CIRCLAsISTANCES.

~'f<<,,> <<s ~ <<7>> ~

,"V; APR-O9-1991 G7:48 FROM DREW BOONTON SALES ADMIN. TO VALLEY FORGE PA P.23 24-HOUR Drew (ndustrial Division ccHtLAlso ctttlcICJL WC.

Emergency MATERIAL SAFETY One Grew Plaza, 8oonton, New Jersey 07005 Tolophono DATA SHEET Phone (201) 283-7800/Tetocc 136444 1(800) 274-5263 Oz i (800) ASHLAND 008372 NRICO CTP ees CORROSION INHIBITOR Page:

THIS MSDS CCMPLIES WITH 29 CFR IQI0.1200 (THE HIZARD CCeljtINICATICN STANDARD)

>~ etcoeslcIIO Jcc ~ cIoceccoet ~ 000Itcc ~ ecol ~ I ~ 00eci ~ c ~ cecoEccctccccclccccc00ccI ~ I ~ eo ~ oocccoocciio ~ I ~ 00 ~ 00 ~ oeiecsgyc ProcccCt Names WRICO CIP 888 CORROSICN INHIBITOR Data Sheet Hot 0218590-002 00 10 988 Preparectc 06/05/90 OLIN DREW WATER SERVICES DIVISION IHDUSTRIAt. DIVISION Ger eoecec 08/18/88 ONE DREW PLAZA PRODUCT c 8200008 8OONTDH IIAO CEc 07005 IHVO CE DATE TOs OLIN WATER SERVICES DIVISION DREW INDUSTRIAL DIVISION DISTIIICT MIHAGER BOQNTON General or Genertc IDc CORROSION IteIIBITOR OOT Hazard Ctaestftcatfonc CORROSIVE MATERIA!. (173.240) c c ~

IF PRESENT IARC, HTP AHD OSHA CARCIHOGENS AHD 0%MICALS SUBJECT TO 15% REPORT ING REQUIREMENTS OP SARA TITLE 111 SECTION 313 ARE IDENTIFIED IH THIS SECTION.

SEE DEFINITION PAGE FOR CLARIFICATION IHGREOI EHT It (by WT) PEL TI.V Note'

( I ~XYETIIYLIDEHE)BISAOSPICNIC ACID 10"2$ 1)

CAS P! 2809 2I~A Notoa

( 1) PEL/TLV NOT ESTABLISH FOR THIS MATERIAL Botttno Potnt for CCMPONEHT( 85" 100%) 212.00 Deg P 100.00 Dey C) 760.00 nm Hy Vapor Pressure fOr CCeecOHENT( 85-10010 e Q:PD R,0 20.00 Deo C)

(

Spectf tc Vapor Oenstty HOT APPLICABLE Spectflc Grovtty 1,071 B 77.00 Dent F

( 25.00 0'eo C)

Percent Vo I at 1 leo 85-100%

E>>raporatton Rate SLDWet 17tAN Ktt%R Ptl 1.0 - 2.0 Appearance CLEAR, COLORLESS State LIOIID FLASH POINT HOT APPLICABLK r EXPLOSIVE LIMIT HOT APPLI CABLE EXTIt4ÃIISHIHG MEDIAc CARSON DIOXIDE OR DRY Cte9lICAL HAZARDOUS DECCaecOSITII& PROOUCTSc MAY FORM TOXIC IQTERIALSc ~ PHISPHIHE>> CARPI DIOXIDE AHO CARBON lDIOXIDE>>

NITROGEN CCMPIXINDS, ACID VAPORS FIREFIGHTIHG PROCKDURESc WEAR SELF~AIHED BREATHING APPARATUS WITH A FULL FACKPIECK OPERATED IN Tl% POSITIVE PRESSURE DEMAIID MQOK AND PULt BODY PROTECTION IeetN FIGHTIHQ FIRES>>

WATER OR FOAM MAY CAUSE FR(flHIHQ teIIOI CAN BK VIOLENT AHD POSSIBLY EICANGER 'P% LIFE OP IHE FIREFIGHTER>>

ESPECIALLY IF SPRAYED INTA CONTAINERS OF l%T>> BURHIHG LIQUID~

WATER Iety BE USED TO KEEP PIRE EXPOSED CONTAINERS COOL UNTIL FIRE IS OUT.

PERMISSIBLE EXPOSURE LEVELc NOT ESTABLISH FOR PRODUCT SEK SECTION II ~

EFFECTS OP ACLflla DYEREXPOSUREs EYES ~ CAUSES BURHS SKiN - CAUSES BURtcs.

BREATHING MIST CAH CAUSE DAMAGE TO NASAL Ate RESPIRATORY PASSAGES SccALLCcclNG CAN RESULT IN DAMAGE TQ TtecOAT AHD KSOPHIGUS FIRST AIDc IF ON SKIHs IIOKOIATELY FLUSH EXPOSED AREA WITH WATER FOR AT LEAST 18 MINUTES>> GET IKDICAL ATIENTION~ REMOVE COPYRIGHT 1990 CONTINUED ON PAGE: 2

\

BETZ IABORATORIES,INC.

4636 SOMERTON ROADS TREVOSEi PA. 19053 BETZ MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE (HEALTH/ACCIDENT) 800 877-1940 (PAGE 1 OF 3)

EFFECTIVE DATE 05 16-91 PRINTED: 3-Jun-1991 REVISIONS TO SECTIONS'g4J7~APP/9/EDe5(8 PRODUCT APPLICATION : WATER-BASED DEPOSIT CONTROL AGENT.

--SECTION 1---- ----HAZARDOUS INGREDIENTS INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD IS LISTED'EFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHRONIC HAZARDS OF THIS FORMULATION+

PHOSPHONIC ACID~ ( 1 HYDROXYETHYLZDINE)BXS (HEDP) +**CAS)2809 2 1 4 p EYE IRRITANTg PEL NONE j TLV NONE ~

---SECTION 2---- - -.TYPXCAL PHYSZCAL DATA -., -.- 0 ~

PH! AS ZS (APPROX.,) 2s0 ODORS SLIGHT FL.PT. (DEG.F)! >200 P-M(CC) SP.GR. (70F) OR DENSITY: 1.219 VAPOR PRESSURE (ItCnHG) $ 18 VAPOR DENSITY (AIR~1): <1 VXSC cps70F: 19 %SOLUBILITY(WATER): 100 EVAP.RATE: ND'ATER~1 , APPEARANCES COLORLESS PHYSICAL STATE! XIIQUXD FREEZE,APPOINT(DEG.F),$ '20 SECTION 3---- - REACTIVITY DATA--

~ ) I 1 ~

~

STABLE.MAY REACT WITH STRONG OXXDXZERS.DO NOT CONTAMINATEoBETZ TANK CLEAN"OUT CATEGORY 'Bi THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES'

BETS MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3)

POWERLINE PPL09 PRODUCT

SECTION 4 -- HEALTH HAZARD EFFECTS

'SCUTE SKIN EFFECTS +++ PRIMARY ROUTE OF EXPOSURE MODERATELY IRRITATING TO THE SKIN ACUTE EYE EFFECTS ***

SEVERE IRRXTANT TO THE EYES ACUTE RESPIRATORY EFFECTS >**

MISTS/AEROSOLS MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT CHRONIC RFFECTS OF OVEREXPOSURE***

NO EVIDENCE OF POTENTIAL CHRONIC CONDITIONS AGGRAVATED *** EFFECTS'EDICAL NOT KNOWN SYMPTOMS OF EXPOSURE ***

MAY CAUSE REDNESS OR ITCHING OF SKXN,IRRITATION AND/OR TEARXNG OF EYES(DIRECT CONTACT) .

-SECTXON 5 -- -F1RST AID XNSTRUCTZONS-- -------

SKIN CONTACT***

REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MXNUTES EYE CONTACT++*

IMMEDXATELY FLUSH EYES WITH WATER FOR 15 MXNUTES ~ IMMEDIATELY CONTACT A vl Q PHYSICIAN FOR ADDITIONAL TREATMENT INHALATZON EXPOSURE+**

REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIRoAPPLY APPROPRIATE FIRST AXD TREATMENT AS NECESSARY INGESTION><+

DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DILUTE CONTENTS OF STOMACH. INDUCE VOMXTING BY ONE OF THE STANDARD

SECTION 6 --SPILL(DISPOSAL'ND FIRE METHODS ZMMEDXATELY CONTACT A PHYSXCXAN INSTRUCTXONS-SPILL XNSTRUCTIONS***

VENTILATE AREA USE SPECIFIED PROTECTIVE EQUIPMENT CONTAIN AND ABSORB ON ABSORBENT MATERIAL+PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED 'ATERIAL(OR ANY CONTAMINATED SOI L(

SHOULD BE DETERMINED XN ACCORDANCE'ITH RCRA AREA WITH WATER+'WET AREA MAY BE SLIPPERY'PREAD REGULATIONS'LUSH SAND/GRIT.

DISPOSAL XNSTRUCTIONS***

WATER CONTAMINATED WITH THIS PRODUCT IMPROPER MAY BE SENT TO A SANXTARY SEWER TREATMENT FACILITY,IN ACCORDANCE WXTH ANY LOCAL AGREEMENT(A PERMITTED WASTE TREATMENT FACILITY OR DXSCHARGED UNDER A NPDES PERMZT PRODUCT(AS IS)-

XNCINERATE OR BURY IN APPROVED LANDFILL PIRE EXTXNGUISHING INSTRUCTIONS***

FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAXNED BREATHING APPARATUS(FULL FACE PIECE TYPE) FIRE EXTXNGUXSHING MEDIA:

FOAM OR WATER CREATE A SLIPPERY CONDITION SPREAD SAND OR GRIT.

C,<

Cp LI

BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3)

PRODUCT POWERLXNE PPL09 SECTION 7---- ~ SPECIAL PROTECTIVE EQUIPMENT USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE

'SPIRATORS WITHIN USE hlMlTATIONS OR ELSE USE SUPPLIED AXR RESPIRATORS ~

VENTILATION PROTECTION***.

ADEQUATE VENTZLATION RECOMMENDED RESPXRATORY PROTECTION***

IF VENTILATION IS INADEQUATE OR SXGNIFXCANT PRODUCT EXPOSURE XS LXKELY, USE A RESPIRATOR WITH DUST/MIST FILTERS.

RECOMMENDED SKIN PROTECTION***

RUBBER GLOVES WASH OFF AFTER EACH USE.REPLACE AS NECESSARY RECOMMEN DED EYE PROTECTION***

SPLASH PROOF CHEMICAL GOGGLES USERS

SECTION 8----- ----STORAGE AND HANDLING PRECAUTZONS-STORAGE INSTRUCTIONS**k KEEP DRUMS & PAILS CLOSED WHEN NOT IN REASONABLE AND SAFE CHEMICAL STORAGE HANDLING INSTRUCTIONS***

ACIDIC,DO NOT MIX WITH ALKALINE MATERZAL.

- - - - k*************kkkkkk***kk*************kkkk*****kk*******k***

THIS MSDS WAS WRITTEN TO COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD

- - - k******kkk***k*********k*k*****kkkkk**k****k********k***k*k*k APPENDIX: REGULATORY INFORMATION THE CONTENT OF THXS APPENDIX REPRESENTS INFORMATION KNOWÃ TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS ~ THIS INFORMATION IS BELIEVED TO BE ACCURATE>

ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT.

..TSCA:! ALL COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY

..REPORTABLE QUANTXTY(RQ} FOR UNDILUTED PRODUCT:

NOT APPLICABLE

. ~ .RCRA! ZF THIS PRODUCT IS DISCARDED AS A WASTEqTHE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS! D002~CORROSZVE(PH)

. ~ +DOT HAZARD/UN//ER GUIDE/ IS: NOT APPLICABLE

...CALIFORNIA SAFE DRINKING WATER ACT (PROPOSITION 65) MATERIALS! NONE

.eoSARA SECTION 302 CHEMICALS! NONE

...SARA SECTION 313 CHEMXCALS: NONE

,SARA SECTION 312 HAZARD CLASS: IMMEDIATE(ACUTE} AND DELAYED(CHRONIC}

...MICHIGAN CRXTXCAL MATERIALS! NONE NFPA/HMIS : HEALTH 2 ; FIRE -' -

j REACTIVXTY - 0 i SPECIAL ACXD t PE - B

p

'I

MATERIAL SAFETY DATA SHEET PRODUCT DYNACOOL 1383 SCALE INHIBIT)

NALCO Emergency Telephone Number Medical P08) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 1 PRODUCT IDENTIFICATION TRADE NAME: DYNACXGL 1383 SCALE INHIBZIOR DESCRIPZlON: An aqueous solution of potassium phosphonate and polyacrylates OVd: lWlight

/ '

2~crate 3=High 4=EMmte

/'=Insignificant SECTION 2 HAZARDOUS INGREDIENTS Our hazard eva1uation of the ingredient(s) under OSHA.'s Hazard Communication Rule, 29 CFR 1910.1200 has found none of the ingredient(s) hazardous.

SECTION 3 PRECAUTIONARY LABEL INFORMATION CM3TION: May cause irritation to skin- and eyes. Avoid contact with skin, eyes and clothing. Do not take internally.

EInpty containers may contain residual product. Do nat reuse container unless pro)arly reconditioned.

SECTION 4 FIRST AID INFORMATION EYES: Flush with water for 15 minutes. Call a physician.

SKIN: Wash thoroughly with soap and rinse with water. Ca11 a physician.

Do not induce vomiting. Give water. Call a physician.

Reniave to fresh air. Treat synIptanis.

INGESTION'NHAIATION:

Ca11 a physician.

NAZE 'IO PHYSICIAN: No specific antidote is known. ~

Based on the, individual reactions of the patient, the physician s judgment should be used to control syniptains and clini.cal corxKtion.

CAVZION: If unconscious,or having trouble breathing do nat induce vamiting or in corrvulsions, give water.

SECTION 5 HEALTH EFFECTS INFORMATION ...

PRIH76K ELVIS(S) OF ZZR3SURE: Eye, Skin EYE CONZACI" cause transient irritation.

SKIN CONTACT'an May cause irritation with prolonged contact.

I SYMPICMS OF EXPOSURE: A review of available data does nat identify any synIptanIs fram exposure.

PAGE 1 OF 7 NALCO CHEMICAL COMPANY QNE NALCQ CENTER ~ NAPERVILLE. ILLINOIS 60563-1 196 AREA 708-305-1 OOO

MATERlAL SAFETY DATA SHEET PROOUCT DYNACCOL 1383 SCALE INHZBZTO NALCO Emergency Telephone Number Medical (708) 920.1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 5 HEALTH EFFECTS INFORMATION ( CONTINUED )

AGGRAVATION OF E)(ISTING CONDITIONS: A review of available data does nat identify any worsening of existing conditions.

SECTION 6 TOXICOLOGY INZORMATION ACVZE IOXICZTY 8IUDIES: No taxicity stixU.es have been conctucted on this product.

SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES CDZQR: Clear FORM: Liquid SOIIJBILZTY IN Completely GRAVITY:

NAT1%'PECIFIC 1.17 6 68 Degrees F AKM D-1298 pH (NFAT) = 3.6 - 4.5 A%M E-70 FEKZ2Z 25 Degrees F ASIA D-1177 POINT'LASH POINT: None (BKC) AKH ~3 NOIR: 'Ihese physical properties are typical values for this product.

SECTION 8 FIRE AND EXPLOSION INFORMATION FIASH POINT: None (PKCC) AKH D-93 EXTINGUISHING MEDIA: Not applicable UNUSUAL FIRE AND EZPIUKION HAZ2GK): Nat applicable,.-.

SECTION 9 REACTIVITY INFORMATION.

INCCMPATZBIZZK: Avoid contact with strung acids (eg. sulfuric, phosphoric, nitric, hydrochloric, chramic, sulfonic) which can generate heat, splatter~ oz boiling and the release of taxic fumes.

'IHERMAL DEXXNKQSITZGN PROIXJCIS: In the event of callibustion CD, CO2 may be formed. Do not breathe smoke or fumes. Wear suitable protective equipment.

SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRAZORY PROTECTION: Respiratory protection is nat normally needed.

For large spills, entry into lazge tan)cs, vessels or enclosed small f1 PAGE 2 OF 7 NALCO CHEMICAI COMPANY ONE NALCO CENTER ~ NAPERVILLE. ILLINOIS 60663-1 196 AREA 708-305-1 OOO

MATERIAL SAFETY DATA SHEET PROD UCT DEGCCOL 1383 SCALE ZNHIBZIO NALCO Emergency Telephone Number Medical (705) 920-1 510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 10 PERSONAL PROTECTION EQUIPMENT ( CONTINUED )

VENTIIATXON: General ventilation is recommended.

PMZECIIUE EQUXPMEHTI Use impexmeable gloves and chemical splash goggles (ANSI Z 87.1 requirements and selection of gloves, goggles, shoes, etc.)

when attaching feeding equipment, doing maintenance or hardling product.

The availability of an eye wash fountain and safety shower is mcalimended.

If clothing is contzuninated, remove clothing and thoroughly wash the affect~ area. Iaurxler contaminated clathing before reuse.

SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATION ACCID)WZS, CALL 'IHE FOLQNING 24-HOUR TZXZZSONE NUMHER (708-920-1510)

SPILL CONSOL AND RIXGVEK:

Snail liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drulns for dispo.ml. Refer to CERCIA in Section 14.

Large liquid spills: Dike to prevent further maveIIIent and reclaim into recovery or salvage drums or tank truck for disposal. Refer to CERCIA in Section 14.

DISH%M'. If this product bonnes a wa.M, it does nat meet the criteria of a hazardous waste as defined under the Rescue~ Conservation and Kxnmg Act (RCRA) 40 CFR 261, since it. does nat have the characteristics of Subp.~ C, (i.e. D001 through D017) nor is it listed under Subpart D.

As a non-hazaxdaus liquid waste, it should be solidified with stabilizing agents (such as sand, fly ash, or.ceiIIent) so that no free liquid remains before disposal to an izxhlstrial waste landfill. A non-hazardous liquid waste can also be deep-well injected in accordance with loca1, state and federal recpxlations.

SECTION 12 ENVIRONMENTAL INFORMATION AQUATIC DATA,I 96 hour0.00111 days 0.0267 hours 1.587302e-4 weeks 3.6528e-5 months static acute ZC50 to Rainbow Traut = Greater than 1,000 ppm 96 hour no observed effect concentration is 1,000 pgm based on no mortality PAGE 3 OF 7 NALCO CHEIVIICAI COMPANY ONE NALCO CENTER ~ NAPERVILLE, II LINQIS 60563-1 166 AREA 708-305-1 Ooo

MATERlAl SAFETY DATA SHEET PRODUCT DYEACCOL 1383 SCALE ZBELBZIO NALCO Emergency Telephone Number Medical (708) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 12 ENVIRONMENTAL INFORMATION ( CONTINUED )

or abnormal effects.

96 hour0.00111 days 0.0267 hours 1.587302e-4 weeks 3.6528e-5 months static acute IC50 to Sheepshead Minnmr = Greater than 1,000 pgm 96 hour0.00111 days 0.0267 hours 1.587302e-4 weeks 3.6528e-5 months no observed effect concentration is 1,000 pgm based on no mortality or abnormal effects.

48 hour static acute IC50 to Daphnia Magna = Greater than 1,000 pgm 48 hour5.555556e-4 days 0.0133 hours 7.936508e-5 weeks 1.8264e-5 months no observed effect concentration is 1,000 pgm based on no mortality or abnormal ef fects.

Xf released inta the enviranInent, see CEXKXA in Section 14.

SECTION 13 TRANSPORTATION XNFORMATION IXII'ROPER SHIPPING NAME/HAZARD (X)DE PROIXJCI'S NOZ REGUIAIKD IXJBING TRANSPOEKLTXON SECTION 14 REGULATORY INFORMATION

'Ihe folloving regulations apply to this prcduct.

FEDERAL REGULATIONS I OSHA HAZARD CCNMUNICATION RULE, 29 CFR 1910.1200:

Based on our hazard evaluatian, this product is nat hazardous.

CERCI~SUPEZKUND, 40 CFR 117, 302:

Notification of spills of this praI9uct is nat recphM.

S~SUPERFUND AMENEHENIS AND REAIJIRZKZATXON ACT OF 1986 (TITIZ III) SECTIONS 302 r 3 11 i 3 12 AND 3 13 SECTION 302 - E)(TREMELY HAZARDOUS SUE83IRNCES (40 CFR 355):

'Ibis product does not contain incIredients listed in Appendix A and B as an ExtrenIely Hazardous Substance.

Our hazard evaluation has fcauxl that this product is nat hazardous under 29 CFR 1910.1200.

Under Section 311, suhmittal of MSD 's or a list of pmchmt nanes to the local eInergency planning commission, state ene~ency response camInission and local PAGE 4 OF 7 NALCO CHEMICAL COMPANY ONE NALCO CENTER ~ NAPERVILLE, ILLINOIS 60563-1 196 AREA 708-305-1 oao

MATER1AL SAFETY DATA SHEET

-4 PROP UC7 DYNAM 1383 SCALE INHIBITO WALCO Emergency Telephone Number INedlcel (708) 920.1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 14 REGULATORY INFORMATION ( CONTINUED )

fire de)mrtnlent is rec~~ after October 17, 1987 if you have:

10,000 pounds or more of a hazazdous substance, or 500 pounds or the threshold planning quantity, whichever is less, of an extremely hazardous substance.

SECTION 313 - IZST OF TOXIC CHBGCAIS (40 CFR 372):

This pzlxhxct does not contain incp~iients (at a level of 1% or greater) on the List of Toxic Chenlicals.

TOXIC SUBSTANCES CONTROL ACT (TSCA,):

The chemical ingredients in this product are on the 8(b) Inventozy List (40 CFR 710) ~

itACI.'RCRA), 40 CFR 261 SUBPART C & D:

RESOURCE CONSERVATION AND REKX3VEK If this pzoduct becomes a waste, does not meet the criteria of a hazardous waste.

FED)XAL WATER POLIDTION CXRZROL ACI I CLZAN WATER ACI g 40 CFR 401 15/

fozmerly Sec. 307, 40 CFR 116/formerly Sec. 311:

None of the ingredients are specifically listed.

~

CUBAN ll AIR ACI r 40 CFR 60 i SECTION 1 I 40 CFR 6 1 r SKTION 1 12 ynxkuct does not contain irxpxdients covered by the Clean Air Act.

STATE RZGUIATIONS:

llag.

None of the chend.cals on the current Plxgosition 65 list are ]mown to be present in this product.

MICHIGAN CRITICAL MATERIALS:

This pzoduct does not contain in~ents listed, on the Michigan Critical Materials Register.

8GQZ RIGRP 'IQ ERN LANS:

This product does not contain incpxdients listed by State Right To Khow Laws.

INTERNATIONALREGULATIONS:

'Ibis is not a WHKIS controlled product under The House of Cclmmns of Canada Bill C-70.

PAGE 5 OF 7 NALCO CHEMICAI COMPANY QNE NALCQ CENTER ~ NAPERVILLE. ILLINOIS 60563-1 196 AREA 708-305-1 OOO

MATERlAL SAFETY DATA SHEET PRODUCT DYNACCOL 1383 SCAZE INHIBITO

~ j NALC0 Emergency Telephone Number MedIcal (708) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 15 ADDITIONAL INFORMATION None SECTION 16 USER'S RESPONSIBILITY

'Zhis product material safety data sheet provides health and safety information. The product is to be used in applications oonsistent with aur product literature. Individuals handling this product shauld be infoxmed of the recommended safety precautions and should have access to this information. For any ather uses, exposures should be eva1uated so that appropriate handling practices and training progrmIIS can be established to ensure safe workplace operations. Please consult your local sales representative for any further information.

SECTION 17 BIBLIOGRAPHY of Hea1th and Ehman Services, Public Hea1th Service, PB 33-135855, 1983.

CASAREZT AND DCUZL'S KOXZCOZOGY, KSE BASIC SCZENCE OF POISONS, Doull, J.,

Klaassen, C. D., arxl Admur, M. O., eds., Macmillian Publishinp Campany, Inc.,

N. Y., 2nd edition, 1980.

CHEMICAL HAZABDS OF ZHE WORKPZACE, Proctor, N. H., and Hughes, J. P., eds.,

J. P. Lipincott Campany, N.Y., 1981.

DANGERCUS PROPEZKHX OF INUJSZRIAL MAT(RIAZSr Saxr N Irv3LÃfr ed r Van Nostrand Reinhold Campanyr N Y r 6th editianr 1984.

IARC MDNOGRAPHS ON ZHE EVAZllATIONOF THE CA(KZNOGZÃZC RISK OF CSEMZQQS

'ZO MAN, Geneva: World Health Organization, Xntexnational Agency for Research on Cancer, 1972-1977.

PAZTY'S ItKUSZRIAL HYGI?~".AND 'ZOXECOZOGY, Clayton, G. D., Clayton, F. E.,

eds r Jo?ln Wiley and Sons r N Y r 3rd editionr Vol 2 ACr 198 1 .

Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983

~1 supplement of 1981-1982 editian, Vol. 3.-3, OH, 1984.

Tit1e 29 Code of Federal Re~julatians Part 1910, Sub'< Z, Toxic and W i tt GSEKSHOZD LDKZ VAZI3ES FOR CHEMICAL SUBS'XANCES AND PHYSICAL'GENZS IN ZHE PAGE 6 OF 7 NALCQ CHEMICAL COIVIPANY QNE NALCQ CENTER ~ NAPERVII LE. ILI INQIS 60563-1 166 AREA 7OMO5-1 OOO

~ e e

INSTR MEVOSE. PENNSYLvaNIa 19041 Product Facts BETZ POIEHLINE PPL04 Copper Corrosfon lnhfbftor Inhfbfts corrosfon of copper alloys EtYectfveness fs not 1~fred by chlor1natfon Extends condenser sarvfce lffe OESCRIPTl0N NN USK pOMERLlNK ppLOa Is a spec1al ly forml ated Nf1 4 steel tanks, paps, and pf p1 ng are corrosfon fnhfb1tor>>hfch 1s desfgned to satfsfactory for use >>1th poNERL?% ppLOa.

establfsh a protactfve ffla on copper alloy condansars fn ttw Power industry. PONERLIlC 66KRAL PNFNTlEStv PPL04 aftectfvely fnh1bfts the corros1on of .

copper alloy surfaces. [ndfrectly, ft also ~rance ......,......lfght to dark brown lfqufd reduCeS the COrrOS1On Of Steel Surf'aCeS when the corrosfon fs the result of a galvanfc reactfon Oenafty ................."""""...

Flash Po1nt (closed 9,9 1bS/gal c) "..;.". "....,......>200F between the steel surface and the products,~ of.

copper corros1on >>hfch have been daposf ted on the r- Freeze Pofnt Pour Pofnt

"."""".".".""..........-20F

-25F steele , Srekffeld YfscoR) tg (70F) e ~ "~........... Bocps TREA~NT ANO FEEDlNC REOUlRE%NTS (S% solutfon) ...~... ~; ~~~ . ~ .~...,...~....11.3 The noreal trea~nt level for PONERLl)C. PPL04 protec&frmdreeafng+ 'lf thfs product fs I'rozan rangeS f~ 1 requfred wfll depend tO S PIN. IIOWeVer, the on eany factors

~nt such as

~

durfPg ShfPeent Or Starage," oft"untf1 hOecgenecuS prfor to use.

operat1ng characterf stf cs of the syi~ and severfty or aw problem. Therefore, thfs prod QFETY PRKCNlTl01 uct shoul4 be used fn accordanCe wfth control-"-

paraeetars SETZ establfshes for ~ specfffc A Ikterfal Safety Data Sheet contafnfng detaf lad applfcatfon. .,,~ fntoraatfoe relatfve-to-.thfs product 1s ava1lable PtMRLlR PPLOa shoul4 be Pod to 4 pofnt fn the coolfng sys~ >>here turbulence and flow patteM - -

PINlQINt lltoN/lTNf;

>>1ll ensure adequate elafng of the product wf&'<:"

the COOlfng water. li reofreulatf1yi COelf1y>> POILEN PPLN., fa bloc&4"ia a lfqufdp and fS systeaa the product shwld be fH ceatfaeusly to supylfH fn 5%~lion bung type nonreturnable isafntafn consfsteat tesf4els .fi, ttW coolfng steel 4nasi ANroafmte net we1 ht - 535 pounds cater. tntarntttena pl%&cl peii ta appltcaa'ia tn certatn ence tatw+ ceeltnp tpetenp. "" per date in aaetttan, .

"-'"c-'atattapte ctntep tate.ICt paint,,pt pean terrace

~'='cprefyea- Por'oetrectH -qha8Cfes", fn cartafn tlE palea tt Thfs product fs stable Nfder erma chlerfnaths ='. geeynplffc'areas. =: ""

practfces. lt wfll not be adversely affected by sys~ aaployfng efther fntemlttent or contfnuous chlorfnatfon for the controf".'of cf "c afcroorganf sas. ~ ~

~a'4 pe E~ instr Xt y ~

PONERL(NK PPL04 cay be fed 41rectly face the Shfppfng COntafner Or 411uted wf.th water,, tO any convenient (eedfng strength.

BETZ INDUSTRIAL 4636 SOMERTON ROAD TREVQSEg Ph. 19047 BETZ MATERIAL SAFETY DATA SHEET

, 24 HOUR EMERGENCY TELEPHONE (HEALTH OR ACCIDENT) 215/355-3300 PRODUCT: POWERL ZNE PPLOi EFFECTIVE DATE 10-31-88 PRZNTED: 12/15/8 PRODUCT APPLICATION: WATER-BASED CORROSION INHZbITOR.

w~~SECTZON 1~~~wmm~mmm~HhgjggQUS INGREDIENTS~mmmmmmwwmwww~

INFORMATION ON PHYSICAL HAZAJtDSg HEALTH HAZARDS'EL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZAZU) CQSlUNICATZQNS STANDARD ARE LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHRONIC HARA')S OF THIS FORMULATION. THIS PRODUCT IS SUBJECT TO THE PENNSYLVANIA HORKER AND COMMtJNZTY RIGHT TO KNCN LAMo BENZOTRIAZOLE)METHYL'ODIUMSALT ~ CASN64665-57-2JCOJNOSIVE TO EYES AND SKINJTOXIC (ORAL INGESTION) JPELINONEtTVLSN(NEQ

>> ~ 's V

~

NONHAZQ

-SECTZN INGREDIENTS'lLTM'"'.wmz ". a R WP1CAL HBICIL NR

>>1 f e

-~ r<

~ ' I >>i PH! AS ZS QttCL'iR')

'OO QQgC).":

'3 o0 ='N(N! )lILD 7 >I FL PTo(DSOet) 0

" 5t QR (7(N')la ZNNNXTtf'.;- l'e101~>>">'~~'APCN PRRSStJRS(~) s X5>>>> s -V~DNNSZTY(MR.L)s ND VISC cpa70ts 7! = -'

%NOMbH XTY(1RHR) !-.4(N IMIM'S% Rl

PHYSICAL STATE! LIQUID STAbLE SECTZ(N 3 Feria POINT(INN.P) $ ~0:-

REACTIVITY DAT1 C

THEN(AL DECXNPOSZTION (DEST!RCTZVE FZiCS) YIELDS EL~WAL OXIDES ~

MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3)

PRODUCT: POWERLINE PPL04 EFFECTIVE DATE 10-3i-g8

-SECTION 4 - HEALTH HAZED EFFECTS-ACUTE SKIN EFFECTS>>>>>> PRIMARY ROUTE QF EXPOSURE CORROSIVE TO SKIN ACUTE EYE EFFECTS>>>>>>

CORROSIVE TO THE EYES ACUTE RESPIRATORY EFFECTS MISTS/AEROSOLS CAUSE IRRITATION TO UPPER RESPIRATORY TRACT CHRONIC EFFECTS QF OVEREXPOSURE PROLONGED OR REPEATED CONTACT MAY CAUSE TISSUE NEC$ NSIS.

MEDICAL CONDITIONS AGGRAVATED NOT KNOWN SYMPTOMS QF EXPOSURE CAUSES REDNESS OR ITCHING OF SKINPPOSSIBLY LEADING TO bURNSPDEPENDENT ON LENGTH OF EXPOSURE.

PRECAUTIONARY STATEMENT BASED ON TESTING RESULTS>>>>>>

MAY BE TOXIC IP ORALLY INGESTED.

-"-SECTION 5 -"FIRST AID INSTRUCTIONS SKIN CONTACT >>>>

REMOVE CLOTHING.WASH AREA WITH LARGE AMOUNTS OP SOAP SOLUTION OR WATER FOR 15 MIll.IMMEDIATELYCONTACT PHYSICIAN EYE CONTACT>>>>>>

IlilEDIATELYPLUSH EYES WITH WATER POR 15 MINUTES.IlelEDIATELYCONTACT h PHYSICIAN POR ADDITIONAL TREATNDlT ZNHALATIQN EXPOSURE>>>>>>

REkVE VZCTIM FAN CONTAMINATED AREA,APPLY NECESSARY FIRST AID TREATMENT. IlllEDIATELYCONTACT 1 PHYSICIAN.

INGESTION>>>>>>

DO NOT PEED ANYTHING BY MOUTH TO 1N UICON5CIOUS (R CIIVULSIVE VICTIM DO NOT INDUCE VOTING.IHCKD.CNITACT PHYSICIANoDIL~ CNITINTS OP STQQCH USING 3-4 GLASSES MILK OR WATER 5 ZZ6 ZC-N ZL SP L,-DZ5PDSAL 55D PZ55 ZDSZDDCZZZ>>5 SPILL INSTRUCTIONS>>>>>>

VENTILATI AREAPUSR SPECIFIED PIOTICTZVR ggISCIT.CONTAIN AND ABSORb ON hbSORbnlT MATERIAL.PLACE IN Nll?R DISPOSAL CQITAINIR. THI %ASTI FLUSH ~

SAND/GRIT+

NITS NATIRiWET ARIA MAY BI SLIPPIIYeIP DISPOSAL ZlsmaCTZMS>>>>>>

SOPSPREAD SEWIR TRIRRÃSIT P1CZLITY, IN JiCCQlDANCI NITS 1NY LOCAL MImlINT 1 PERMITTED I%I?I TRIATMIIT PlCZLZTY (R DISCIARRD QIDCR 1 NPDIS PERMIT PRODUCT(AS Zf)

INCINERATE (R bUIY ZN APPRQVID hLSDtILL PIRE EXTINGUISHING INSTRUCTIONS>>>>>>

PZREPIGHTE$ lS SKULD NEAR POSITIVE i%CSSURE SELP~ITAINID BR~HING APPARATUS(PULL PACE-PIECE TYPE) ~

DRY CHEMICALS CARBON DIOXIDE'OAN OR NATER

MATERIAL SAFETY DATA SHEET (PAGE 3 QF 3)

PRODUCT: PQWERLZNE PPL04 EFFECTIVE DATE 10-31-88

~

- "-SECTION 7 -"SPECIAL PROTECTIVE EQUZPMENT-USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-13i. USE

RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS.

VENTILATION PROTECTION ADEQUATE VENTILATION RECOMMENDED RESPIRATORY PROTECTION>>>>>>

IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LZKELYt USE h RESPIRATOR WITH DUST/MIST FILTERS ~

RECOMMENDED SKIN M@ECTION GAUNTLET-TYPE RUBBER GLOVES t CHEMICAL RESISTANT APRON MASH QFF AFTER EACH USE.REPLACE AS NECESSARY RECOSSNDED EYE PROTECTION>>>>>>

SPLASH PROOF CHEMICAL GOGGLES. FACE SHIELD

- SECTION 8 -STORAGE AND HANDLING PRECAUTIONS STORAGE INSTRUCTIONS>>

KEEP DRUMS C PAILS CLOSED WHEN NOT ZN USE.

REASONAbLE AND SAFE CHEMICAL STORAGE HANDLING INSTRUCTIONS>>>>>>

Il&EDZATELY REMOVE CONTAMINATED CIA7THINGgMASH bEFN RNUSC ALKALINE.CORROSIVE TO SKIN AND EYES DO NOT MIX NITS ACIDZC MATERIAL.

THIS MSDS CXNPLIES WITH THE OSHA HAXJU CCNIUXICATItN STANDARD HAROLD M. HERSH (ENVIRON%ITAL INFORMATION COCSOINATCS)

>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>1>>>>>>>>>>1>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>0>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>*>>>>>>>>>>

<:, THE CONT%IT OF THIS APPENDIX REPRESENTS ZNFOINATZCN lQIONN TO BC'N THE EFFECTIVE DATE OF TSIS MSDS. THIS INFCmaTZCe ZS m,man TO aa ACClamS.

~Z

~~

ANY CHANGES ZN REGULATIONS MILL $ CSQLT IN UPDLTN7 NS Ot THIS DOCXMEIIT.

IICl

~ ~ o REPORTABLE QUANTITY(RQ) PC% UNDILlÃHD PRMQCT t NOT APPLICABLE

...RCRAt XF THIS PRMQCT IS DI)ClRDED AS 1 KLSTR~RR NCNA 81XLRXXJS 1QSTE IDENTIFICATION NUHSRR IS t DO02MNNOSXVN

~ ~ oDOT HAXAND CLlSSIFICATIMt CmkRlSIVN TO SKIS

. ~ .DOT SHXPPINO DRSZNTQN ISt UN1760 CMRSIVB LIQUXOg NsOe5>>

~

~ ~ o THIS PRNX)CX'ÃILDS THESE CNICALS 1NOISI TO TSN ST1TR Ot CALZRSÃIA TO CAUSE CANC' MPRXXCTIVS TOXXCITYt %MR PlCSXNT IN SIINIFICAÃT NCXlNTS

..SARA SNCTXM SCR CMCCAL5t NWS WREST IÃ SIINXFICAN%'lNUNTS

~ ~ .SARA SN.'TXM 3'NSNZCAL5t NINN PRRS~ ZN SIGNIFICANT llNNNTS

~ ~ .SARA SECTS 312 SLXlRO CLASS t ZNIRDZATN(lCITN) AND M!kTRD(CIQINXC)

~ oMZCHIGAN CkITICAL ML~IALSt NN PNNSSÃT ZN 5ZONZF ICAL 1lQÃTS

~

NFPA/%IS t HQLTS - 3 l FIR - 1 ~ RRRCR'XVXTt - 0 ] QKQh - CNR g Pt - D

1179 IP/79 MATERIAL SAFETY DATA SHEET 6D32.02.18.86.643 CALG ON PRODUCT NAME PCL-50 suasloiisRv OF MERcK a co rric MANUFACTURER'S NAME EMERGENCY Calgon Corporation TELEPHONE NO. (412) 777.80M ADDRESS P. O. Box 1346, Pittsburgh, Pennsylvania 15230 CHEMICAL NAME FORMULA ANO SYNONYMS Triazole C7H6N3Na

~ ~

PRINCIPAL HAZARDOUS COMPONENT (S) ORAL LOgp DERMAL LDSp TLV )Units)

Sodium tolyltriazole (CAS No. 64665.57.21 50 675 mg/kg Unknown Unknown I'(%

~ ~ s BOII.ING POINT loF) > 212 SPECIFIC GRAVITY lH20%1) 1.18 PERCENT VOLATILE VAPOR PRCSSURE (mmHg.) Unknown BY VOLUME (SS) 508 VAPOR DENSITY IAIR%11 Unknown pH 1% 12.3 soLUBILITYIN wATER ',,-, . g.~ ~M)scib)e-<< '

AppEARANGE AND QDQR Dark red solution with slight aromatic odor

~ ~ ~

~ ~ ~ s %

~ ~ i FLASH POINT )Method Used) FLAMMABLELIMITS Lel Uel Not Flammable Not Applicable EXTINGUISHING MEDIA Product is not flammable.

SPECIAL FIRE FIGHTING PROCEDURES t

None re, UNUSUAL FIRE AND ~

EXPLOSION HAZARDS y g '

r

'r C None VVhife this information and recommendations sel forth herein are believed to be accurate as of the date hereof, CALGON CORPORATION MAKES NO WARRANTY WITH RESPECT HERETO AND OISCLAIMS ALL. LIABILITYFROM RELIAKICE THEREQN,

4 I

r~

r N/A ~ Not Applicable

~ a a ~ ~ a

" EFFECTS OF OVEREXPOSURE Causes burns. Harmful if swallowed.

EMERGENCY AND FIRST AIO PROCEDURES EYE: In case of contact, immediately flush with plenty of water for at least 15 minutes. Call a physician.

SKIN: In case of contact, immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing. If irritation develops, call a physician. Wash clothing before reuse.

INTERNAL: If swallowed, do not induce vomiting. Give large quantities of water. Give at least one ounce of vinegar in an equal amount of water. Never give anything by mouth to an unconscious person. Call a physician.

~ a STABILITY STABLE X CONDITIONS TO AVOID Unknown UNSTABLE INCOMPATABILITY (Materials to Avoid) Strong oxidizers HAZARDOUS DECOMPOSITION When heated to over 200 C., degassing will be observed. Carbon dioxide, carbon monoxide PRODUCTS nitro en oxides and h dr en c anide can be iven off.

HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID Unknown MAY OCCUR NO X a ~ 0 a

~ ~ ~

REPORTABLE QUANTITIES IRQ) NOTIFY EPA OF PRODUCT SPILLS IN LBS. OF EPA HAZARDOUS EQUAL TO OR EXCEEDING St >s)STANCES IN PRODUCT L N/A LSS.

2.

3. ~

STEPS TO BE TAKEN IN CASE MATERIALIS RELEASED Dispose of in accordance with local state and federal regulations Dike area to contain OR SPILLED as much spilled material as possible. Remove any remaining material by absorbing on vermiculite or other suitable absorbing material and,place in a sealed metal container for disposal.

WASTE DISPOSAL METHOD Dilute with water and neutralize with 6M-HCI. Flush with water to discharge.

-hali.

Dispose of in accordance with local, state and federal regulations.

~ e ~ ~ ~ '

RESPIRATORY PROTECTION ISpecify Type) A NIOSH-approved respirator for sodium hydroxide is recommended only if exposed to excessive mists.

LOCAL EXHAUST SPECIAL VENTILATION Adequate Not Required MECHANICAL OTHER Normal IGeneral) Not Required Not Required PROTECTIVE GLOVES EYE PROTECTION Rubber Eye goggles or full.face shield OTHER PROTECTIVE EQUIPMENT Protective clothing

~ ~ e

" 'AUTIONS 1 TO BE TAKEN IN 3LING ANO STORING Do not get in eyes, on skin or on clothing. Keep container closed.

Wash thoroughly after handling.

OTHER PRECAUTIONS None IMp.nod'.\ I a aa

~ 0 "1

%V

p QPR-89-1991 87: 38 FROM DREW BOONTON SALES ADMIN. TO VALLEY FORGE PA P.88

\~

~

r'"gg";.'~Lg' I:Iai 9'CVf>tQ i Emeraency 72-62-7830-01 Telephone Qnc g:zav plaza. Boon on, New Je'"av 0>>005 q (Bpp) at'i.gg03 or r,ir.,TE".(A.'l <=TY DA /I SHEET

~/P: P!ion. I20'ti-"G3 7(i"p T Ie" 3-Spp-ASHLp,t, 000067 11-166(TN) CORROSXON XNHXBITOR Page:

THIS tSDS COHP'LIES HZTH 29 CFR 1910.1200 (THE HAZARD COfSI41CATZON STANDARD)

IIWHl ProC)uct ttamet NPD 11 166(7t() CORROSION INHIBITOR CAS HUNBERI 64665-57 2 Data Sheet Ho: 0065195-003 0D 10 Dirt P repat ed: 08/16/89 DREH CKEHICAL CORPORATION SuperSedeS: 03/02/87 ONE DREH CHENZCAL PLAZA PRODUCT:

'PD D1597295 INVOICE!

HJ07005 INVOICE DATE'-

TOI NARKETING PC I I,' I a'I " !lit ~ I I ~ 'IHt I I Ilail

~

r ~... ~ r". ~ )y.:.,~.>>,

Genetal or Gener io IDI CORROSION INHIBITOR DOT Hazard Classif icationt CORROSZVE HATERIAL (173.2r>>O). ~

- ~ ~ WC f I *I I I -I

~ ~ .I IF PRESENT IARC>> NTP AND OSHA CARCIHOGENS AND CHEHICALS SUBJECT TO THE REPORT ZNG REQUZRINENTS OF SARA TITLE III SECTION 313 ARK IDENTIFIED IN THIS SECTION>>

SEE DEFINITION PAGE FOR CLARIFICATION ZHGIi F~'trr SODZIPl TOLYLTRIAZOLE 50 CAS SI 64665-57 2

~O1~:

( 1) PEL/TLV HOT Boiling Point ESTABLZSHED FOR THZS NATERZAL for PRODUCT 4 Z>t'!I II'I It'l I, %'t"a tt i >>r ~ ', ~ '.. i'

(

212.00 100.00 Degi F Deg C) 0 760.00 II!I Hg Vapot Pressure for PRODUCT ( 17.50 I!I!I Ho

>>X D 68.00 Dog F 20.00 Dog C )

Speoif io Vapor Density UHAVAI(.ABl.E Specific Gravity 1. 190 0 77.00 Deg F I 25.00 Deg C)

Percent Volat iles 50.00/i Evaporation Rate SLOHER THAN ETHER pH ~ i(& ~ r 13.5 Appearance CLEAR>> YELLOH TO AYBER State LIQUID Form o< ~ II I

~ II I ~

I. !O>> '

I!at I: I Y. ~ I II'I FLASH POINT HOT APPl.ICABLE EXPLOSIVE LI)(IT HOT APPLICABLE EXTINGUISHING t(EDZAI NOT APPLICABLE HAZARDOUS DECOHPOSITIOH PRODUCTSt THERHAL DECOHPOSZTION O'R COt%VSTION HAY PROOUCEt CARBON DIOXIDE>> CARBON NQNOXZDE>> OXIDES OF NZTROGEHI HYDROGEN CYANIDE IH REDVCZNG ATMSPHERES FZREFIGHTIhS PROCEDURESI HEAR SELF-COHl'AINED BREATHIHG APPARATUS HZTH A FVLL FACEPZECE OPERATED ZN THE POSITIVE PRESSURE DENAND NODE AND FULL BODY PROTECTION HHEN FIGHTING FIRES.

HATER HAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL N(TIL FIRE IS OUT.

HFPA CODES I HEAl.TH 3 FLAlSABILITY"0 REACTIVITY 0 CLOSED CONTAINERS HAY RUPTURE OR EXPLODE DUE TO PRESSURE BUILD~ HHEN EXPOSED TO EXTREHE HEAT PC'VI ~ .

r/ ',I.>I

~ ~ ~ ~

IERNISSZBLE EXPOSURE LEVEL! HOT ESTABLISHED ~

F C OF A V FOR PRODUCT EYES CAUSES SEVERE DAHAGE ~

SKIN CAUSES BURNS SHALLOWIIIG RESULTS Itt SEVERE DAHAGE TO HUCOUS HEHBRANES AND DEEP TISSUE BREATHZNGt NAY CAUSE DZSCONFORT OR IRRITATION TO NASAI AHD RESI ZRATORY I ~SSAGES COPYRIGHT 1989, CONTINUED ON PAGE I 2

th

'/

i

HPR-8'9-1 J91 U >" 31 FROM DREW BOONTOll SALES ADMIN. TO VALLEY FORGE PA P.89 72-62-7850-01 Ll>

D'y ti t~i'~~V>>c-- Qik [St<>>" EITtetg0ncy pter PIC>>,. OOn!On, NeW JC>>aeYO7OOB Telephone f<'>>0TEI'ilO'AFETY 'rj) p>te l20') 2Gp 7G"0 TeleK )~G~A4

] (QGQ) 27t, 52)3 qhapp )) SQL>0,gD Qf 'l!000 DATP. SHE="T NPD 11-166 ( TN) CORROSION INHIBITOR Page I 2

">r.>t!t>s a<<> ~ ~ ~ t><<e ~

t;1 e ~ e >>tee>> <<ye ~ ~ r ~ C* ">>,.tqc << ', r', ~ ~ .

~)~ST >~ID ~

IF ON SKIN: I)IIIEDZATELY FLUSH KITH HATER FOR AT LEAST 15 NINVTES. RENOVE CONTAMINATED CLOTHING>> LAUNDER CONTA)IINATEO CI.OTHZNG BEFORE RE-VSE.

IF IH EYESt FLUSH HZTH l,ARGE A)NVMTS OF HATER>> LZFTIHG UPPER AND LONER LIDS OCCASIONALLY. GKT NEDZCAL ATTEMTIOM>> IF ZRRITATIOH PERSISTS.

ZF SNALLOHED: DO NOT INDUCE VOHITING. VONZTZNG HILL CAUSE FURTHER DAttAGE TO THE THROAT>> DILVTE BY GIVING HATER>> GIVK MILK OF NAGHKSZA KEEP HARN>> QUIET GET MEDICAL ATTENTION I~DZATELY~

ZF BREATHEDt REl%VE INDIVIDUALTO FRESH AIR.

ttIM>tRY S FEMTY ~

SKIN CONTACT

~ ~ re.. ~ ~

' ~ ', " '>> 1 1 1 ', ~ 1' 1 ~;t ~ ~ t ~

HAZARDDVS POLY)IERZZATIOHt CANNOT. OCCUR STABLE 'TABZl.ZTYt ZNCOttPATZBILITY) AVOID CONTACT HITH)>> STRONG OXIDIZING AGENTS>>>> STROHG NINERAI. ACIDS.

>t'0 t>>l 1 e

' ~ 1

~ t<< g,

~

~ ~

1 q

<< t >>>! ~ ~ . Z ...'. e, >> . ~ ~ >>'., ~

TE S TAKEN IM CAS A R A IS REL ASE O SP SHALL SPILLt ABSORB LIQUID ON PAPER>> VERNZCULZTK>> FLOOR ABSORBENT OR OTHER ABSORBENT NATKRIAL.

LARGE SPILL> PERSONS MOT HEARING PROTECTIVE EQVZPHKNT SHOULD BE EXCLVDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED. STOP SPZLL AT SOURCE DIKE AREA OF SPILl. TO PREVENT SPREADING PlPIP LIQUID TO SALVAGE TANK..

RENAIMING LIQUID NAY BE TAKEN UP ON 5AND>> CLAYS EARTH ~ FLOOR ABSORBENT>> OR OT)IKR ABSORBEMl )IATKRZAL AND SHOVELED INTO CONTAINF RS.

KAT DIPOAL 0 e SHALL LARGE SPILL: DISPOSE OF ZN ACCORDANCE HITH ALL LOCAL SPZLLt DISPOSE OF ZM ACCORDANCE HZTH P>t>>' !it; I 1 1 r>

STATE AND FEDERAL REGULATIONS.

Al.L LOCAl.>> STATE AND FEDERAL REGULATIONS>>

' >'1 . l:>> I << ':I: ' .I << ~ r >'" ~ ": ~ ~

RESPIRATORY PROTECTIONt ZF OVERKXPOSVRE HAS BEEN DETERHIHED OR DOCNIENTED>> A NZOSH/HSHA JOINTLY APPROVED AIR SUPPLZED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL ~ OSHA REGULATIONS ALSO PER)IZT OTHER NIOSH~XA RESPIRATORS UNDER SPECIFIED COMDZTICNS. ISEE YOUR SAFETY EQVZPNENT SUPPLIER)e KNGZNEFRING OR AO)IINISTRATIVK CONTROLS SHOULD BE I)IPLK)IEHTKD TO REDUCE EXPOSURE.

VENTZLATIONt PROVIDE SUFFICIENT tfECHAHICAL lGEMKRAL AMD/OR LOCAL EXHAVST) VENTZLATZOH'TO NAZNTAIM EXPOSVRE BELOH LEVEL, OF OVERKXPOSVRK I FROM KNOT>> SVSPECTED OR APPARENT ADVERSE EFFECTS) ~

PROTECTIVE CLOVES: NATURAL RUBBER EYE PROTECTION: CHEMICAL SPLASH GOGGLES AND FACE SHIELD l8" NIN. ) TM COHPLZANCE HITH OSHA RKN)LATZONS ARE ADVISED) HDHKVKR OSHA REGULATIONS ALSO PER)IIT OTHER TYPE SAFETY GI.ASSES, lCONSULT YOUR SAFETY EQUIP)IEMT SUPPLIER)

OTHER PROTECTIVE EQUIP)IENT 1 TO PREVENT SKIN CONTACT>> HEAR ZHPERVZOUS CLOTHING AND BOOTS.

t>> I I:l "

1 1 '>>C'.tl ~ ' tee tt 11-1 et ~ ~ 8 t . I hhhV>>>>ih>> ><< '>> t\>>>h ~ <<>> e>>>>a r>><<,,<<so a>>os <<a>>ar ~ ~ >><<<<a <<e ~ acre>> ~ hOCh>> AP bhlb

MATERIAL SAFETY DATA SHEET PRODUCT NA~ 1326 CORROSION ZNHIBITO NALCO Emergency Telephone Number Medical (70B) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 1 PRODUCT IDENTIFICATION NAME'AZCO 1326 en:

TRADE CORROSION INHIBITOR DESCRIPTION: An aqueous solution of sodium tolyltriazole

/

lWlight 2~crate

/ 3=High

/

4=Extreme 0=Insignificant SECTION 2 HAZARDOUS INGREDXENTS Our hazard evaluation has identified the follcaring chemical ingredient(s) as hazardous under OSHA's Hazard Cclmmunication Rule, 29 CFR 1910.1200. Consult Section 14 for the nature of the hazard(s) .

INGREDIENT(S) APPROX. 4 Sodium tolyltriazole 64665-57-2 40-70 SECTION 3 PRECAUTIONARY LABEL INFORMATION WARNZNG: Causes burns to skin and eyes. Do rIot get in eyes, on skin, or on clothing. Wear goggles or face shield when handling. Do not take internally.

Eillpty containers may contain residual product. Do not reuse container unless properly reconditioned.

SECTION 4 FIRST AID INFORMATION EYES: Zaanediately, flush for at least 15 minutes while eyelids open. Call a physician at once.

hol~

SKIN: ZrIImediately flush with water for at least 15 minutes.

For a large splash, flood body under a shcxrer. Call a physician at once.

INGESTION: Do not induce vomiting. Give water. Call a physician.

NCGE TO BKSXCIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judginent should be used to contxol symptcnls and clirlical condition.

CMTHON: If unIxescious, having trouble breathirlg or in convulsions, do not irduce vomiting or give water.

SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY EKVXE(S) OF EXPOSURE: Eye, Skin PAGE 1 OF 8 NALCO CHEMICAL COMPANY QNE NALCQ CENTER ~ NAPERVILLE. ILLINOIS 60563-1 196 AREA 7oe-305-1 ooo

MATERlAL SAFETY DATA SHEET

~~ >326 CORROSION ZNHIB

~ NALCO Emergency Telephone Number Medical (708) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

,I SECTION 5 HEALTH EFFECTS INFORMATION ( CONTINUED )

EYE Corrosive to the eyes with possible perIIIanent damage CONTACT'EEN depending on the length of exposure and on the first aid action given.

CONTACT: Can cause severe irritation. Corrosive to the skin, possibly resulting in thi~ degree burns depending on the length of exp~me and on the first aid action given.

INGESTION: Can be haxnlful.

SYMPICMS OF E)GQKHK: A review of available data does not identify any sylllptalIIs fram exposure not previously mentioned, or identified in Section 6 or 14.

AGGRAVATION OF EXISTING CONDITIONS: A review of available data does not identify any worsening of existing conditions.

SECTION 6 TOXXCOLOGY XNFORMATION.,

ACUTE 'IOXICITY SIUDIES: Acute toxicity studies have not been conduI:~

on this product, but acute studies have been conducted on a similar product. The results are shown below.

ACUTE ORAL TOXICITY (ALBINO RATS): ID50 = 675 Itq/lay ACUTE DERMAL 'IQXZCITY (AL'BINO RABBITS): ID50 = Greater than 2 glIy'kg ACUTE INHAlATIONTOXICITY (AU3XHO RATS): XC50 = Greater than 1.73 mp/L for 1 hour1.157407e-5 days 2.777778e-4 hours 1.653439e-6 weeks 3.805e-7 months exposure PRZKBY SEEN IRRITATION TEST (ALBINO RABBITS):

SKIN ZRBITXKON XÃKK DRAIZE RATING: Severely irritating PRZMARY EYE ZHR~ON TEST (AIBZNQ RABBITS):

EYE IRIKZRPZON INDI% DRAIZE RATl2C: Severely irritating (corrosive)

SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Deep brawn/black FOHN: Liquid ., ODOR: Slight DENSITY: 9. 9 lbs/gal.

SOIIJBZIZZY IN 0VZER: Campletely SPEXZFIC GRAVITY: 1.19 9 60 Degrees F , ASIN D-1298 pH (NEAT) = 13.5 ASIM E-70 FIKZZE POINT: -22 DeIprees F ASIA D-1177 BOILING POINT: 212 Degrees F 9 760 mm Hg ASIM D-86 FLASH POINT: Greater than 225 Degrees F (HKC) ASSAM ~3 PAGE 2 OF 8

/JAN QO OHE5nlCAl QOMpANY ONE NALCO CENTER ~ NAPERVILLE. ILLINOIS 60563-1 166 coen, dna one snnn

MATERIAL SAFETY DATA SHEET PRODUCT NMXO 1326 CDEGKGION INHIB NALCO Emergency Telephone Number Medical (708) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES ( CONTINUED )

NOTE: These physical properties are typical values'for this product.

SECTION 8 FIRE AND EXPLOSION INFORMATION FCASfk EOINT: Greater than 225 Degrees F (BKC) ASIA D-93 1MHNGUISHING MEDIA: Nat applicable UNUSUAL FIRE AND EG?XQSIGN HAZARD: May evolve NOx under fire conditions.

Cont~am exposed in a fixe shca&d be cooled with water to prevent vapor pressure buildup leading to a xupture.

SECTION 9 REACTIVITY INFORMATION INCXMPATIBILIZY: Avoid contact with stxong acids (eg. sulfuric, phosphoric, nitric, hydxIxM.oric, chxaIIIic, sulfonic) which can genexate heat, splattering or boiling ared the release of taxic fumes.

THKKALDFAXRIPOSITIGN PROIXJCIS: In the event of cambustion CO, CO2, NOx may be formed. Do not breathe smoke or fumes. Wear suitable pxotective equipment.

SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PRt3TECXXGN: Respiratoxy protection is not noxmally needed since the volatility and toxicity axe lmr. If significant or aerosols axe generated, wear a or ecpivalent vapors,'ists NIOSH approved For large spaces spills, entxy into large tanks, v~s or enclosed small with inadequate ventilation, a pressuxe-demand, self-contained hler ey VENZZ2ZIGN: General ventilatian is recommended. A9ditionally, local exhaust KPl glaves, goggles, shoes, etc.).

gross exposuxe is possible.

A full slicker suit is xeccmImended if

'Ihe availability of an eye wash fountain and safety shaImr is recxumIIended.

PAGE 3 OF 8 NALCO CHEMICAL COMPANY ONE NALCQ CENTER ~ NAPERVILLE. ILLINOIS 60563-1 196 AREA 708-305-1 OOO

l pt n,

IVIATERlALSAFETY DATA SHEET PRODUCT NAICO 1326 CORRCSION INHIB

~ WALCO Emergency Telephone Number Medical (708) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 10 PERSONAL PROTECTION EQUIPMENT ( CONTINUED )

Zf clothing is contaminated, reznave clothing and thoroughly wash the affected area. Iaum2er contaminated clathing before reuse.

SECTION 11 SPXLL AND DISPOSAL INFORMATION IN CASE OF TEINSPORGKION ACCIDENTS, CALL 'IHE FOLIQWZNG 24-HO()R TELEKKONE NUME3ER (708-920-1510)

SPILL CONTROL AND RECOVER:

Small liquid spills: Contain with absorbent material, such as clay, soil or any calnnIercially available absorbent. Shovel reclaimed liquid and absorbent into recavexy or salvage drums for disposal. Refer to CEZKXA in Section 14.

Iarge liquid spills: Dike to prevent further movement and reclaim into recovery or salvage dnnns or tank txuck for disposal. Refer to CERCIA in Section 14.

For large indoor spills, evacuate emplayees and ventilate area. Those responsible for contxol arxl recavexy should wear the protective equiplnent specified in Section 10.

DISPOSAL: Zf this product becames a wast~, it meets the criteria hazardous waste as defined under the Resources Conservation arxk of a Recavexy Act (RCRA) 40 CFR 261. Hazardous Waste D002.

As a hazaxdaus liquid waste, it must be solidified with stabilizing qgents (such as sand, fly ash, or cement) so that no free liquid remains beEore dispuM to a licensed industrial waste landfill (Hazardous Waste Treatment, Storage and Disposal facility) . A hazardous liquid waste can also be incinerated in accordance with local, state, and federal regulations.

SECTION 12 ENVIRONMENTAL INFORMATION AQKGXC DATA.:

96 hour0.00111 days 0.0267 hours 1.587302e-4 weeks 3.6528e-5 months static acute ZC50 to Bluegill Sunfish = 150 mp/L 96 haur no observed effect concentration is 56 pgIn based on no mortality or abnormal ef fects.

IOXZCITY RATING: Slightly toxic 96 hour static acute LC50 to Rainrxar Trout = 34 mg/L PAGE 4 OF 8 NALCO CHEIVIICAL COIVIPANY QNE NALCQ CENTER ~ NAPERVILLE. ILLINOIS 60563-1 196 7C)A-APER,-1 CYlh

MATERIAL SAFETY DATA SHEET PRODUCT NEO 1326 CORROSION INHI NALCQ Emergency Telephone hlumber Medical (708) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 12 ENVIRONMENTAL INFORMATION ( CONTINUED )

96 hour no observed effect concentration is 18 mp/L based on no mortality or abnormal ef fects.

'ZOXICITY RAT)XG: Moderately toxic 96 haur static acute IC50 to Fathead Minnow = 130 mp/L 96 hour no observed effect concentration is 56 mp/L based on no mortality or abnormal ef fects.

TOXICITY RATING: Slight1y toxic 48 hour static acute ZC50 to Daphnia Magna = 420 ng/L 48 hour no abserlred effect concentration is 100 uq/L based on no mortality or abnormal ef fects.

YOXECZTY EQZZNG: Slightly taxic If released into the envtronment, see CERCZA in Sectian 14.

SECTION 13 TRANSPORTATION INFORMATION IXT PROPER SHIPPING NAME/HAZtQKl CODE OCKKGIVE IZQUID, N.O.S.

CORROSIVE MATUALUN 1760 CONTAINS - SODIUM KOIZI)Z!RIAZOLZ SECTION 14 REGULATORY INFORMATION

'Ihe follcmizxy xegulatians apply to this product.

FED1XAL KXXJZATIGNS: r OSHA S HAZARD CXSMUNICATIGN RULE g 29 CFR 19 10 1200 Based an our hazard eva1uatian, the fallowing ingredient in this product is hazardous and the reason is shI:xm below.

Sodium tolyltriazole - Eye/skin irritant CERCZA/SUH~UNDI 40 CFR 117 I 302 Natification of spills of this product is not recuized.

AND REAUZBCRIZATIGN ACT OF 1986 PAGE 5 OF 8 NALCO CHEMICAL COMPANY QNE NALCQ CENTER ~ NAPERVILLE. ILLINOIS 60563-1198 VClS-SCIS-1 CPPl

g(

MATERIAL SAFETY DATA SHEET NADX) 1326 CGHBQSZON INHIB WALCO Emergency 7elephone Number Medical (708) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 14 REGULATORY INFORMATION ( CONTINUED )

(TZTIE IZI) SECTIONS 302 r 31lr 312 AND 313:

SECTION 302 - EZZREMELY HAZARDCUS SUBSTANCES (40 CFR 355):

This product does not contain ingredients listed in Appezxhx A and B as an I~mely Hazardous Substance.

(40 CFR 370):

Our hazard evaluation has found this product to be hazardous. 'Ihe product should be reported under the follcmitng EPA hazard categories:

XX Znmediate (acute) health hazard Delayed (chronic) health hazard Fire hazard Sudden release of pressure hazard Reactive hazard Under Section 311, submittal of MSDS's or a list of product names to the local emergency planning commission, state emergency response cananission and local fire departnIent is recp~d after October 17, 1987 '

if you have:

10,000 pounds or more of a hazardous substance, or 500 pounds or the threshold plannirg cgmntity, whichever is less, of an extremely hazardous substance.

After October 17, 1989, NSDS(sp., or a list of prochmt names for all

.P. "CX reported, must be submitted.

SECTION 313 - LIST OF 'IOXIC CHEZZCAIS (40'FR 372):

'Ihis product does not contain izxp~ents (at a level of 1% or greater) on the List of Tmic Chemicals.

'IOXZC SUB'.i~CES CONTROL ACT (TSCA,):

The chemical ingre:iients in this product are on the 8(b) Irwentory List (40 CFR 710).

RESCURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261 SUBPARC C & D:

If this product hazardous waste becclaes a wa.~,

as defined under it does40 meet 261the (consult RCRA CFR criteria of a Section ll) ..

FEEH~ %PEER EOLUJZXON CONZROL ACT r CU AN HATER ACT r 40 CFR 40 1 15 (formerly Sec. 307), 40 CFR 116 (formerly Sec. 311):

PAGE 6 OF 8 NAL.CO CHEIVIICAL COIVIPANY ONE NALCQ CENTER ~ NAPERVILLE. ILLINOIS 60563-1 166 nnv~ dna wns ~nnn

P II

~

O

MATERlAL SAFETY DATA SHEET PRODUCT NM~ 1326 CORROSION NALCO Emergency Telephone Number Medical P08) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 14 REGULATORY INFORMATION ( CONTINUED )

None of the ingredients are specifically listed.

CLEAN AIR ACTr 40 CFR 60 r SECTION 11 1 r 40 CER 61 r SECTION 112

'Ihis product does,not contain ingredients covered by the Clean Air Act.

STATE REGUZATIONS I Nane of the chemd.cals on the current Pxaposition 65 list are knawn to be present in this product.

MICHIGAN CRITICAL MATERIALSI

'Ibis product does not contain ingredients listed on the Michigan Critical Materials Register.

FGQZ RZGHZ'O ENN ITS:

%his product does nat contain irxpxdients listed by State Right To Znov Laws.

INZZPNATIONAL REGUZATIONS'his is a WHMIS controlled product under 'Ihe Haixse of Oalmnons of Canada Bill C-70. 'Ihe product contains the follcaring substance(s), fram the Ingredient Disclosure List or has been evaluated based an its taxicological properties, to contain the followiLng hazaxdaus.- ingredient(s):

I Chemical Name CAS I 4 Concentration Range Sodium tolyltriazole 64665-57-2 SECTION 15 ADDITIONAL INFORMATION None SECTION 16 USER'S RESPONSIBILITY Xhia pxoduct material safety data stMmt provides health and safety infoxmatian. 'Ihe product is to be used in applications cansistent with our product literature. Individuals handliap this pxoduIW shauld be to this infoxmatian. For any other uses, exposures should be evaluated so that appropriate handling practices and traimzg programs can be established to ensure safe workplace opmatians. Please cansult your local sales representative for any further information.

PAGE 7 OF 8 NALCQ CHEMICAL COIVIPANY QNE NALCQ CENTER ~ NAPERVILLE, fl LINQIS 6D563-1 198 AREA 708%05-1 oaa

I

~ice

MATER1AL SAFETY DATA SHEET NAICO 1326 CORROSION INHIB ('~

NALCO Emergency Telephone Number Medical (708) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 17 BIBLIOGRAPHY MUG REEORP ON CAMXHOG)XS, U.S. Departzllent of Health and Hum-In Services, Public Health Servicer PB 33 135855r 1983.

CASAREIT MD DOULL'S TOXICOICGY, IHE BASIC SCIENCE OF POISONS r Doullr J r KLaassen, C. D., and Admur, M. O., eds., Macmillian Publishing Calllpany, Inc.,

N. Y., 2nd edition, 1980.

CHEMICAL HAZARDS OF THE WORKPIACE r Proctorr N H I and Hughes r J P r eds J. P. Lipincott Caltlpany, N.Y., 1981.

DANGERCUS PROPS OF INIXJSTRIAL MATERIAIS Sax N Irv1Tlgr ed r Van Nostrand Reinhold Company, N.Y., 6th edition, 1984.

IARC MONOGRAPHS ON 1HE EVAIIJATION OF THE CARCINOGENIC RISK OF CHEMICAIS TO MAN, Geneva: World Health Organization, International Agency for Research on Cancer, 1972-1977.

PATTY'S IMXJSXRIAL HYGIENE AND KOXICOIDGY, Clayton, G. D., Clayton, F. E.,

eds I John Wiley and SoIls r N Y r 3rd editiong Uol 2 AMr 198 1 REGISTRY OF TOXIC IM'ZUNIS ON CHEMICAL SUBSTANCES, U.S. D@~oent of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupatianal Safety and Health, 1983 supplement of 1981-1982 edition, Uol. 1-3, OH, 1984.

Title 29 Code of Federal Regulations Part 1910, Subpart Z,', Taxia arxl ty TKKSHOXD LB'MUJES FOR CHEMICAL SUBSTANCES AND PHYSICAL AG)&IS IN THE Gavenmlental Industrial Hygienic~~, OH.

PREPARED BY: Ricky A. Stackhause PhD., Toxicologist DATE CHAN2K): 10/10/89 ~

DATE .PRINZED: 04/04/91 *~

PAGE 8 OF 8 NALCO CHEMICAL COMPANY ONE NALCO CENTER ~ NAPERVILLE. ILLINCllS 6CI563<<1 166 AREA 708-305-1 ooo

BETZ INDUSTRIAL 4636 SOMUCON ROAD TREVOSEg PA, 19047 MTZ MATERIAL SAFETY DATA SHEET 2i HOUR EMERGENCY TELEPHONE (HEALTH OR ACCIDENT) 215/355-3300'RODUCT:

POMERL INE 3450 EFFECTIVE DATE 10" 31-88 PRINTED! 12/15/8 PRODUCT

-"-SECTION 1 -HAZAJURUS INGREDIENTS---

APPLICATION: WATER-BASED DEPOSIT CONTROL AGENTS INFORMATION ON PHYSICAL HAZARDS'EALTH HAZARDS'KL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZAitD CCMCUXICATIONS STANDAJU) ARE LISTED. REFER TO SECTION i (PAGE 2) FOR OUR ASSESQCNT OF THE POTRITIAL ACUTE AND CHRONIC HAZARDS OF THIS FORKJLhTIONo THIS PltODUCT IS SUBJECT TO THE PENNSYLVANIA WORKER AND COHNAiITY RIGHT TO KCW LAN.

THIS PRODUCT IS NOT JRZhdtDOUS AS DEFINED bY OSHA RESJIATIONSo s e r eh speal ~r rs~ .->p t~' i

~ ~ I te NONHAZARD INGRIDI~c ILES lID CONAN %SR lg, 2-lSÃSNOZC lCZD 1ND 1r2g-1%tlNDIOL lCWQ 2 PRNSOLS

-SECTS 2 (393733l 7)

ICAL PIYSZCAL DLTL PH~ AS IS '1PPINN.).,5.3 OXS. M1LO FL.PT. (MO,t) S 200 SRXl(CC) ..

'. St AR (70t)te INNIRtc. 1 123..

Vase PRESSuaa(mM) s 20, Vaja MSSnr(aIR 1) c 1..

VISC cys70Ft 19 ~ 5 %50hQSZLZXT(ILK')0 100 EVAP.RATE! 1 ETC~1 IWau1CE aLaHII el

PHYSICAL STATI! LIOOD SECTION 3 SThbLE PIXIES POISE(MS.P)

IIACTIVITXMTL c RS THI14AL DECNPOSITItN (DESTRtJCTIVI meS) YIELDS ILSaITAL OXID!S.

MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3)

PRODUCT: POMERLINE 3450

-SECTION 4 HEALTH SLSUS EFFECTS - -EFFECTIVE DATE 10"31-8S ACUTE SKIN EPPECTS ~~~ PRIMARY ROUTE OP EXPOSURE iii SLIGHTLY IRRITATING TO THE SKIN ACUTE EYE EFFECTS SLIGHTLY IRRITATING TO THE EYES ACUTE RESPIRATORY EFFECTS MISTS/AEROSOLS MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT CHRONIC EFFECTS OP OVEREXPOSURE~~~

NO EVIDENCE OF POTENTIAL CHRONIC EFPECTS.

MEDICAL CONDITIONS AGGRAVATED ~~~

NOT KNOWN SmamS. OF EXPOSURE MAY CAUSE REDNESS OR ITCHING OP SKINgIRRITATION AND/OR TEARING OP EYES(DIRECT CONTACT) ~

-SECTION 5 -FIRST AID INSTRUCTIONS SKIN CONTACT~~~ C REN)VE CONTAMINATED CLOTHINQ.MASH EXPOSED AREl MZTH h LARGE QUAIITZTY OP SOAP SOLUTION OR MATER FOR 15 MINUTES EYE CONTACTiii IMMEDIATELY PLUSH EYES MZTH MATER P05FIS NINUTESeQSCDIATELY CONTACT A

. NSZCIAN FOR ADDITIONAL TREMRENT ZNHAIATION EXPOSURE REMOVE VICTIM PRCN CONTAMINATED hm TO PRESH AIR.APPLY APPROPRIATE FIRST AZD TREATMEIIT AS NECESSARY INGESTION~~~-

DO NOT FEED AIIYTHINQ BY MOUTH TO AN UNCONSCIOUS OR CCNIVULSZVE VICTIM DILUTE CONTENTS OF STCNACH.INDUCE VQlZTZNO bY CNE OP THE STA)IDARD SECTION 6 SPILL INSTRllCTIONS~~~

METINDS. QSKDIATELY CONTACT h PHYSICIAN

-SPILL,DISPOSAL AND PIRE ZXSTINCTZONS CSC, VENTILATE AREkgUSE SPECZPIED PINTECTZVE EQQZPICNT.CNITAIX AXD MSORb ON AbSORbEIIT NATERZALoPIACE ZX 1QSTE DISPOSAL CNITAINe IHR 1lLSTE IS IS CSSICSCW IC ICSSCISS PLUSH Aaaa MITE mm.MET AREA MAY aa SLZPPCar.IP SO,SPmaAO SAND/tRXTi>

. DISPOSAL aswarm~~~

SSSSSSS I M\ IC IS ICSSCSCC ICCS CS PRNZTTED NLSTm IRRLS{%IT flCZL~ Ca DI5CHiMRD UÃm 4 XSQCS PRNQT P!01NCT(AS 25)

INCINERATE Ca M%X ZX 1PPRÃIRO LANN'ZLL PZRE EXTINNISHZN3 ZXSTÃCTZCNS~~~

PZREFZOHTEZS SINUS) NEAR P05ZTZVE PRES5INE SELF~ITAZXED bREATHIM APPARATUS(PULL PACE PIECE TYPE),

CONICAL/CARSON DIOXIDE~POAÃ tR 1RTER.POAÃ tR 1IATNR CRADLES 1 SLIPPERY CONDITIONoSPREAD SAND OR QRZT

MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3)

PRODUCT: POMHV INE 3i50 EFFECTIVE DATE 10-31-88

- ECTION 7 -SPECIAL PROTECTIVE EQUIPMENT USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS.

VENTILATION PROTECTION>>~

ADEQUATE VENTILATION RECQHMENDED RESPIRATORY PROTECTION~~~

IF VENTILATION IS INADEQUATE QR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY/

USE A RESPIRATOR WITH DUST/MIST FILTERS.

RECQNENDED SKIN PROTECTION RUBBER GLOVES WASH QFF AFTER EACH USE.REPLACE AS NECESSARY RECCNMED EYE PROTECTION~~~

SPLASH PROOF CHEMICAL GOGGLES

-SECTION 8 -STORAGE AND HANDLING PIECAUTIONS -

STORAGE INSTRUCTIONS KEEP DRUMS Cs PAILS CLOSED WHEN NOT IN USE.

PlNTECT PRON FREEZING HANDLING INSTRUCTIONS>>

I%6RIATELY RKMVE CONTAMINATED CLOTHINGgWASH BEFORE REUSE NORMAL CHEMICAL HANDLING I

~011 1100101 II I I I 0 0 0 1 0 'N 1 0 0 1 0 0 1 0 0 1 0 0 0 1 1 1 0 0 0 1 1 1 0 0 1 1 'I 0 0 0 II1 III1 0 0 1 1 1 0 0 0 0 1 1 0 1 ~

THIS MSDS CXNPLIES WITH THE OSHA HIKE CQSSXICATION STANDhl 4 HAROLD M. HERSH (ENVIRMENTAL INFORIRTZM COORDQQTM)

I I t

~ 1 1 0 0 0 1 0 0 'P 1 1 1 0 1 1 0 0 0 0 0 0 0 0 1 0 0 1 1 0 0 0 0 0 1 0 P 0 0 0 0 0 0 0 0 1 1 1 0 0 0 0 0 0 0 0 t0 0 1 1 0 1 1 0 I1 0 1 0 0 APPENDIX! REGUIATORY IXPMNLTION THE CONTENT OF THIS APPENDIX REPRESENTS INtOITIM HNllN TO MTZ OI THE EFFECTIVE DATE Of THIS MSDS ~ THIS IXtMhaTIM Z5 bRLIEVED TO SC ACCUlRTE.

ANY CHANGES IN REGtllATIONS WILL RESULT ZN UPDATED VERSIONS Of THIS DOCUMENT.

~ ~ .TSCAt ALL CCNPCNlEllTS OF THIS PRODUCT ARE LISTRD IN THE TSC1 INVENTORY

~ ~ .REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT!

NOT APPLZChbLE

~ ~ .RCRA! IF THIS PItMQCT IS DISC1IDED 15 1 WLSTgi THE RCRA HAZARDOU5 KLSTE IDENTIFICATION NlMIRt IS s NOT APPLIClbLE

...IOT HAZARD CLASSIFICATIONS NOT APPLIChbLE

...DOT SHIPPING DESIGNATION IS< NOT 1PtLICAILX

..THIS PRMPCT CMXAZNS TIRE CIZCALS KIOMN TO TIE STATE Ot CALIFORNIA TO

~~

~

CAUSE CANCRR CR MlRSQCTZVB TOXZCITFc NWE PRESENT IN SIGNItIC1NT hiUNTS

...SARA SICZZlR 302 CHlNZCALSs PIEStlIT IN SIGIZtIClÃT llCXlNTS

".SARA SECTZM 813 I SR I!R CSOCCALS!

...MICHIGAN CRITZCAL MLT~AL5< NWR PIISINT IN SIGNIFICANT 1NXNTS PRESIFT IN 5IGNItZCANT 1NRNTS MSIRNOKI >>/>>

NtB/SOS i HEALTH - 1 l FIRE - 1; RRACTIVZTY - 0 g 5PICZAL - NK l PE - B

BETZ LABORATORIES i INC, 4636 SOMERTON ROAD p TREVOSEg PA 19047 PRODUCT: PONERLZNE 3450 2/22/89 AQUATIC TOXICOLOGY DARBY MAGNA 04 MORTALITY: <2400 MO/L 48 HR. LC50: 3558 ~ 0 MO/L, FATHEAD MINNOW 04 MORTALITY0 <8700 MO/L 96 HRo LC50: 19062+0 MQ/L BLUEOZLL SUNFISH 04 MORTALITYs 4000 MO/L 48 HR. SCRo 2/22/89 ORAL LD50 RAT: 16000 MO/IO D15%AL LD50 - RAIbZT 2000 ~ 00 lN/IO SKIN ZRRZTATZON SCORE NO DATA EYE IRRITATION SCORE NO DATA ZNKLZATZON NO DATA Oman Dime {yya)

PRODUCT CONC99iTRATZON (PQR) $ 00 COO TOC

~

1000 10 3LQ 113

BETZ LABORATORIES,ZNC.

4636 SOMERTON ROAD/ TREVOSEg PA 190S3 BETZ MATERIAL SAFETY DATA SHEET EMERGENCY 'TELEPHONE (HEALTH/ACCXDENT) 800-877-1940 (PAGE 1 OF 3)

PRODUCT : POWERLZNE PPL08 EFFECTIVE DATE 02-16-91 PRINTED: 8-APx'-1991 REVISIONS TO SECTIONS: -;EDIT:APPENDIX PRODUCT APPLZCATIQN : WATER-BASED CORROSION INHIBITOR/DEPOSIT CONTROL AGENT-

SECTION 1-----------HAZARDOUS ZNGREDXENTS-INFORMATXON ON PHYSICAL HAZARDS'EALTH HAZARDS'EL S AND TLV S FOR INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD ZS SPECIFIC'RODUCT LISTED. REFER TO,SECT1ON 4 (PAGE 2) FOR QUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHRONIC HAZARDS OF THIS FORMULATXQN ~

THIS PRODUCT ZS NOT HAZARDOUS AS DEFINED BY OSHA REGULATXQNS.

~ ~

If "

) ~

SECTION 2-----------7YPZCAf Pt'YSXCAL DATA 1

PH AS XS (A? PROX ~

) 5.2 ODOR: SLIGHT FL. PT. (DEG. F): >200 P-M(CC) S? CRo (70F) OR DENSITY: 1. 169

~

vA7QR ?RESSURE (mmHG): 18 VAPOR DENSITY (AIR~1): ~1 VZSC Cps70F: 42 %SOLUBILITY(WATER) ! 1 00 EVAP. RATE: ND WATER=1 APPEARANCE: YELLOW PHYSICAL STATE 'IQUID FREEZE POINT(DEAF): 25

SECTION 3 REACTZVITY DATA

$ y \g H STABLE MAY REACT WITH STRONG OXXDXZERS. DO NQT CONTAMINATE~ BETZ TANK

~

CLEAN-QUT CATEGORY DECOMPOSZTZON (DESTRUCTZV" FIRES) YIELDS ELEMENTAL OXIDES ~

HERMAL e

BETZ MATERIAL SAFETY DATA SHEET ~PAGE Z QF 3)

PRODUCT

---SECTION 4- - --

POWERLXNE PPL08

-HEALTH HAZARD EFFECTS JTE SKIN EFFECTS ~** PRIMARY ROUTE'F EXPOSURE SLIGHTLY IRRITATING TO THE SKIN ACUS.'E EYE EFFECTS ***

SLIGHTLY IRRITATING ZO THE EYES ACUTE RESPIRATORY EFFECTS MISTS/AEROSOLS MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT ~ ~em CHRONIC EFFECTS OF OVEREXPOSURE~~*

NO EVIDENCE OF POTENTIAL CHRONIC CONDITIONS AGGRAVATED *** EFFECTS'EDICAL NQT KNOWN SYMPTOMS OF EXPOSURE ***

MAY CAUSE REDNESS OR ITCHING OF SKIN,

- SECTXQN 5-- -- -- -FIRST AID INSTRUCTIONS-SKIN CONTACT***

REMOVE-CONTAMINATED CLOTHZNG ~ WASH EXPOSED AREA WITH A LARGE QUANTITY QF SOAP SOLUTION OR WATER FOR 15 MINUTES EYE CONTACT***

IMMEDIATELY FLUSH EYES WXTH WATER FQK 15 MI-"UTER . 1rQR DXATELY CONTACT A PHYSICIAN FOR ADDZTZONAL TREATMENT.

INHALATXON EXPOSURE***

REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR.APPLY APPROPRIATE FIRST AID TREATMENT AS NECESSARY EGESTION~**

DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DILUTE CONTENTS OF STOMACH INDUCE VOMITING BY ONE OF THE STANDARD METHODS.IMMEDIATELY CONTACT A PHYSICIAN

-- -SECTION 6 -SPILL DISPOSAL AND FXRE XNSTRUCTIONS---------

SPILL INSTRUCTIONS***

VENTILATE AREApUSE SPECZFXED PROTECTXVE,"EQUXPMEN'l'ONTAIN AND ABSORB

~

ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTXCS OF THE-ABSORBED MATERIAL~OR ANY CONTAMINATE~OIL, SHOULD BE DETERMINED XN, ACCORDANCE, WITH RCRA REGULATIONS.

FLUSH AREA WITH WATER WET AREA MAY Shl SLIPPERY SPREAD SAND/GRIT.

DISPOSAL INSTRUCTIONS+*+

WATER CONTAMINATED WXTH THXS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACZLZTYgZN ACCORDANCE WITH ANY LOCAL AGREEMENT~A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT

~

. PRODUCT(AS IS)

INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS~~~

FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (FULL FACE-PIECE TYPE) .PROPER FIRE EXTINGUISHING MEDIA:

DRY CHEMICAL,CARBON DIOXIDE,FOAM OR WATER

BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3)

DUCT -'OWERLXNE PPL08

--SECTION 7 --- -----SPECIAL PROTECTIVE EQUXPMENT U~c,'ROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910,132-134. USE RESPIRATORS WITHXN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS.

VENTXLATZON PROTECTION***

ADEQUATE VENT1LATXON RECOMMENDED RESPIRATORY PROTECTION***

IF VENTZLATXON IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY)

USE A RESPXRATOR WITH DUST/MIST FILTERS.

RECOMMENDED SKIN PROTECTION<+<

RUBBER GLOVES WASH OFF AFTER EACH USE.REPLACE AS NECESSARY FECOMMENDED EYE PROTECTION***

SPLASH PROOF CHEMICAL GOGGLES

SECTION 8-----------STORAGE AND HANDLING PRECAUTXONS-------

STORAGE INSTRUCTIONS**+

KEEP DRUMS 6 PAILS CLOSED WHEN NOT IN USE.

STORE IN COOL VENTILATED LOCATION. STORE AWAY FROM OXIDIZERS HANDLZNG INSTRUCTIONS***

NORMAL CHEMICAL HANDLING

- +**%*******%A%*********A'4'******A%%********4k*%*A********%**%'t%'g%%A%

THIS MSDS WAS WRITTEN TO'OMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD

- - - - 4******************4*+***4*********************

APPENDIX: REGULATORY XNFORMATZON THE CONTENT OF THXS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE

~V'FECTXVE DATE OF THIS MSDS. THIS INFORMATION XS BELIEVED TO BE ACCURATE.

CHANGES ZN REGULATIONS WILL RESUZT ZN UPDATED VERSIONS OF THIS DOCUMENTS

~ ~ ~ TSCA'LL COMPONENTS OF THIS PRODUCT ARE LZSTED ON THE TSCA XNV~'N'L'ORY

...REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT:

NOT APPLICABLE

~ ~ ~ RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE)THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS: NOT APPLICABLE

~ ~ ~ DOT HAZARD/UN¹/ER GUIDE¹ ZS: NOT APPLICABLE

~ ~ ~ CALZFORNIA SAFE DRINKING WATER ACT (PROPOSITION 65) MATERIALS: NONE

...SARA SECTION 302 CHEMICALS: NONE

...SARA SECTION 313 CHEMICALS: NONE

...SARA SECTION 312 HAZARD CLASS: PRODUCT IS NONHAZARDOUS UNDER SECTION 311/31

...MICHIGAN CRITICAL MATERIALS: NONE NFPA/HMTS: HEALTH 1 t FIRE 1 g REACTIVITY 0 i SPECIAL - NONE; PE B

t" La

MATERIAL SAFETY DATA SHEET DATE July 17, 1985 6D25 01 07-85-544 CALGQN-coi+01<<r<<e<<<<<<

PRODUCT NAME PCL401 suesioIARY 0F MSRCK a co..INC.

s<<<<c r MANUFACTURER'S NAME Calgon Corporation EMERGENCY t412) 777.8000 TELEPHONE NO ADDRESS P.O. Box 1346, Pittsburgh, Pennsylvania 15230 CHEMICALNAME Anionic Polymer FORMULA Multlcomponent Liquid AND SYNONYMS

~ <<<<<<<< ~r TLV (Unils)

PRINCIPAL HAZARDOUS COMPONENT (S) CAS ORAL LDse DERMAL LOgo ACG IH OSHA OTHE)

IT BY WEIGH Chemical Name None Common Name Chemical Nan'.e Name Chemical Name Common Name Chemical Name ~ r tw Common Name Chemical Name Common Name

~ ~ <<n<<r ~ ~ ~ ~ I

<<~

BOILING POINT ( F) > 212 SPECIFIC GRAVITY (HsO ))

1.16 - 1.20 PERCENT VOLATILE ra+

70 VAPOR PRESSURE (mmHg.) Similar to Water BY VOLUME (SS)

Similar to Water 4.6 N 0.2 VAPOR DENSITY (AIR~ I)

SOLUBILITY IN WATER Complete OTHER APPEARANCE ANO ODOR Clear, slightly viscous solution While this information and recommendations set forth herein are I¹lieved to I¹ accurate as of the dare hereof, CALGON CORPORATION MAKES NO WARRANTYWITH RESPECTHERETO AND DISCLAIMSALL LIABILITYFROM RELIANCE THEREON.

r o j a g ~ ~ ~ ~

F LASH POINT lMethod Used) Not Flammable F XTINGUISHING MEOIA Product is not flammable.

SPECIAL FIRE FIGHTING PROCEDURES Exercise caution when fighting any chemical fire.

A self. contained breathing apparatus is essential.

UNUSUAL FIRE ANO F XPLOSION HAZAROS None EFFECT OF OVEREXPOSURE A. ACUTE According to testing on the product, it would not be considered ING E ST ION hazardous through ingestion. The acute oral LD50 (rats) is ) 5 g/kg.

2. INHALATION LC50 value - not available. The product is an aqueous solution which would not be considered hazardous through inhaiation.

3. OERMAL EXPOSURE

a. TOXIC According to testing on the product, it would not be considered hazardous through dermal absorption. The acute dermal LD50 (rabbits)~ 2 g/kg.

I AA I TAT ION Testing on the product has shown that it is not a primary skin irritant.

The primary skin irritation index (rabbits) is 0.09/8 and would be considered practically nonirritating.

c. SENSITIZATION No cases of skin sensitization have been reported as a result of using the product.

IMP4544 . 7/17/85 Page 2 Of 4

4. EYE IRRITATION The product would not be considered an eye'irritant. Testing on a 28% solution of the anionic polymer in the product produced no irritation when instilled in rabbit eyes [unwashed).

B. SUBCHRONIC, CHRONIC, OTHER No applicable information was found concerning adverse health effects resulting from subchronic and chronic exposure to the Product.

F I RST AID A. EYE Good'First Aid shoIIld'bIr'followed in all cases of exposure.

In case of eye contact, flush with plenty of water for at least 15 minutes. If irritation develops, call a physician.

B. SKIN Not Applicable

~ . \

C. INGESTION Not Applicable

~ I ~ ~ ~

O. INHALATION Not Applicable IMP-0544 7/17/85 '7 '+ ~ i

,h 4

STABLE CONDITIONS STABILITY UNSTABL TO AVOID ICOMPATABILITY IMaterials to Avoid)

Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS of nitrogen Oxides r 'sM a1s REPORTABLE QUANTITIES (RQ) NOTIFY EPA OF PRODUCT SPILLS IN LBS OF EPA HAZARDOUS EQUAL TO OR EXCEEDING SUBSTANCES IN PRODUCT 1. N/A

2. N/A LBS 3.

STEPS TO BE TAKEN IN CASE Dispose of in accordanc~ with local, state and federal regulations. Dike area to contain as MATERIALIS RELEASED OR SPILLED much spilled material as possible. Remove any remaining material by absorbing on vermiculite or other suitable absorbing material and place in a sealed metal container for disposal. Hose spill area well since product can make floors slippery.

WASTE DISPOSAL METHOD Dispose of in a landfill in accordance with local, state and federal regulations.

~@Q 's v.s+

ji&<<Lt.p~s~ i I i'+.(hy)~.~? Iris ~q>>)gjgg,%5K t PROTECTIVE GLOVES OTHER P ROT ECTI CLOTHING VE RESPIRATORY PROTECTION Not Required Not Required EYE PROTECTION Not Required Not Reqtllred V ENTI LATION LOCAL EXHAUST OTHER Not Required Normal None MECHANICAL

{Gerterali Not Required STORAGE & HANDLING Wash thoroughly after handling.

Keep container ciosetL Exercise caution tn the storage and handling of all chemical substances.

iTHER PRECAUTIONS Pace 4 or 4 PREPARED BY IMp~ 7/17/85

0PR-89-1991. 87:32 FROM DREW BOONTON SALES ADNiN: TO VALLEY FORGE PA P. li 24-HOUR Drew Industrial Asst.Arro ~QKJll Division Emergency MATERIAL SAFETY One Grew lslaza, Boonton, New Jersey 07005 Telephone DATA SHEET Phone (201) 263-7600/Telex 136444 1 (800) 274-5263 k 1 1 (800) ASHLAND 008362 WPD ll-136(TM) ANTISCALANT Page:

THIS MSDS CO%PLIES WITH 29 CFR 1910.1200 (THE HAZARD CCseaJNICATIOH STANDARD) ttttttttt ~ tt ~ ttttttt ~ ttt ~ ttttttt ~ tt ~ ttt ttttttt ttttttttttt t t ttttttttttttttttttttttttttttttttttt ttttttttttt

~ ~ ~ ~ ~ ~ ~

Product Nrsrtes WPD ss 136(TM) ANTISCALAHT CAS HUSEJERs 9003<4-7 Data Sheet Has 0175928-002 00 10 966 Prepared: 03/03/87 OLIN WATER SERVICES DIVISION Supersedes s 09/12/85 DREW INDUSTRIAL DIV1$1ON OHE DREW PLAZA PRODUCT s 5520003 800NTQN INVOICE~

tLJ, 0700$ INVO1CE DATE:

Tgs OLIN WATER SERVICES DIVISION DREW INDUSTRIAL DIVISION DISTRICT lhlNAGER 80ONTTJH General or Gener{c IDs ANTISCALANT DOT Hasrard Class{f {cat{ons leT APPLICABLE

~

IF PRESENT. IARC, NTP AND OSHA CARCIHOGEHS AND CHEMICALS SULJECT TO THE REPORT-ING REQUIREMENTS OF SARA TITLE ill SECTION 313 ARE IDENTIFIED IH THIS SECTION.

SEE DEFINITION PAGE FOR CLARIFICATION I NQlEDIENT S (by WT) PEL TLV Note SODIUM POLYACRYLATE 25-40 ( 1)

CAS Ps 9003 04 7 Notens'

1) PEl./TLV HOT ESTABLISt%0 FOR 11{IS NATERIAL Be{1{no Po{nt for PRODUCT, s. 212.00 Deg F 760.00 rrssr HO Vapor Pressure for PRODUCT 17.50 rrssr 68.00 Deg HII

( 20.00 Deg C)

Spec{f{c Vapor Dens{ty LIGHTER lHAH AIR Spec{f {c Grav{ty 1.150 - 1.290

{J 7/.DD Deg F

( .,25.00 Deo C)

Percent Volat{les 55 70%

Evaporat {on Rate SLOWER THAN ETHER pH 5.3 5.7 Appear ance CLEAR. COLORLESS TO PALE STRAW State LIQUID FLASH POINT NOT APPl.i CABLE EXPLOSI VE LIMIT HOT APPLICABLE EXTINGUISHING MEDIAs HAZARDOUS DEC(XSSsOSITIOH PRODUCTS s NOT APPLI CABLE FIREFIGHTIHG PROCEDURESs NOT APPLICABLK SPECIAL FIRE S EXPLOSIOH HAZARDSs HOT APPLICABLE NFPA COOESs HEALTH 1 FLAIESASILITY 0 REACTIVITY- 0 PERMISSISJ.E EXPOSURE LKVKLs HOT KSTASl.iSHEDS SEE SECTION VIII ~

EFFECTS OF ACUTE OVEREXPOSVRKs EYES - CAN CAUSE IRRITATION.

SKIN CAN CAUSE SLIGHT ISNITATIOH.

SWALLOWING SREATHINGs MAY CAVSE DI~T CAN CAUSE GASTROINTESTINAL IRRITATIOH. NAUSEA VCMITING AND DIARNXAo OR IRRITATION TO NASAL ANtr RESPIRATORY PASSAGES.

FIRST AIDs IF ON SKIHs ~ROUGte.Y WASH EXPOSED AREA lriTH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. L V e)ER

'CDNT/oilHATED cLDTHING BEFORE RE vSE.

kl I*

et

~6 'l

P 4p.

Pj APR"89-1991 87: 33 FROM DREW BOONTON SALES ADM IN. TO VALLEY FORGE PA P. 12 JtVUJt Drew Anxhl Industrial Division CtCINCAL NC.

Emergency

'elephone IVIATERIALSAFETY One Drew Plaaa, Boonton, New Jersey 07005 Phone (201) 263-7600/Telex 136444 1(800) 274-5263 or DATA SHEET 1 (800) ASHLAND 008362 NPD ll-136(TM) MnISCALANT Page: 2 IF IH EYES: FLUSH WI'TH LARGE AAK)UHTS OF WATER, LIFTING VPPER ANO LOWER LIDS OCCASIONALLY.

IF SWALLOWBJr IIOEDIATELY DRINK TWO GLASSES OF WATER ANO INDUCE VCMITING BY El'IHER GIVING IPECAC SYRUP OR BY PLACING FIHGER AT BACK OF THIOAT. NEVER GIVE ANYTHING BY ICBM TO AH UNCONSCIOVS PERSON. GET ~ICAL ATTENTIOH IPMEDIATELY.

IF BREATHEOJ REJJDVE INDIVIDUALTO FRESH AIR.

PRIMARY ROUTE($ ) OF ENTRY:

SKIN CONTACT WQAROQUS POLYlKRI ZATIOHc CANNOT OCCUR STABILITY: STABLE IHCCMPATIBILITY$ AVOID CONTACT WITH), STRONG MINERAL ACIDS,

$ TEPS TO BE TAKEN IH CASE MATERIAL IS RELEASED OR SPILLEOJ SMALL SPILLS ABSORB LIOJID ON PAPER. VERMICULITE, FLOOR ABSORBENT OR OTHER ABSORBENT MATHtIAL.

LARGE SPII.L: PERSONS IOT WEARIHG PROTECTIVE EOJIPMEHT SIe)ULD BE EXCLUDED FROM AREA OF SP1LL UNTIL CI.EAN UP HAS BEEN CCMPLETED. STOP SPILL AT, SOURCE DIKE AREA OF SPII.L TO PREVENT SPREADIHG, PUMP LICVID TO SALVAGE TANK.

REMAINING LIQUID MAY BE TAKEN UP ON QND. CLAY, EARTH. FLOOR ABSORBENT, OR OTRR ABSORBENT MATERIAL AND QOVELED INTO CONTAINERS.

WASTE DISPOSAL METHOD~

SMALL SPILLS DISPOSE OF IN ACCORDAHCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS.

LARGE SPILLs DISPOSE OF IN ACCOROAHCE WiTH hLL LOCAl, STATE Ne FEDERAL REGULATIONS.

RFSPIRATORV PROTECTIONS NOT REOJIRED UNDER NORMAL CONDITIONS OF VSE.

VENTILATION: NOT REOJIREO UNDER NORMAL COHDITION5 OF VSE.

PROTECTIVE GLOVESg WEAR RESISTANT GLOVES (CONSULT YOUR SAFETY EOJIPMEHT SUPPLIER) ~

EYE PROTECTIOH.'WEAR SAFETY GLJLSSES IH COIPLIANCE WITH OSHA REGULATIONS. (CONSULT YOUR SAFETY EOJIRKHT SVPPLIER) 00%R PROTECTIVE EOJIPMENTs NORMAL WORK CLOTHING COVERIHG ARMS AND LEGS.

I' CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS %HAH EJOTIED. SINCE Eh&TIED CONTAIHERS RETAIH PRODUCT RESIDVES (VhPOR, LIOJIO, ANO/OR SOI.IO) ~ ALL HAZARD PRECAVTION$ GIVEN IN THIS DATASHEET NJST BE OB$ ERVEO.

~ INFORMATICN ACCUMJLA~i I%REIN IS BELIEVED TO BE ACCURATE BIJT IS HOT WAJIRANTED TO BE WETIKR ORIGINATING

'wITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TQ CONFIRM IH ADVANCE OF HEED THAT %% INFORMATIOH IS CURRENT APPLICABLE+ AND SUITABLE TO THEIR CIRCUMSTANCESr CAPVP Tl 'PT 1 q17 T,a CV VaCW:--CW'K'rear TaMP'.mV Taat I! RMCt.ARRO f.hCrP PAC R

MATERlAL SAFETY OATA SHEET PRODUCT NA~ Q356D NALCO Emergency 7elephone Number Medical (708) 920-1510 (24 haurs)

SECTION' PRODUCT IDENTIFICATION TRADE NAME: NAICO 8356D DISPERSAHZ DESCRZPTEONl Aqueous solution of an acxylate polymer W,

0=Insignificant

/ '

1Mlight 2~crate 3~gh

/

4=E}ctrettle SECTION 2 HAZARDOUS INGREDIENTS Our hazard evaluati.on has identified the faluting chemical hazaxdaus under OSHA,'s Hazaxd Calmnunication Rule, 29 CFR 1910.1200.

ident(s) as Consult Section 14 for the nature of the hazaxd(s) .

ZNGREDIENT (S) CAS I AEPBDX.%

Sodium bisulfite 7631-90-5 1-5 SECTION 3 PRECAUTIONARY LABEL INFORMATION CAVVION: May cause ixritatian to skin and eyes. Avoid cca~ct with skin, eyes and cla8~p. Do nat take internally.

unless p~mxly xeconditianed.

SECTION 4 FIRST AZD INFORMATION EYES: Flush with water far 15 mini;Ites. Call a physician.

SKIN: Flush with water for 15 minutes.

INGESTZON: Do not irduce vanitiag. 'Give watex. Call a physician.

INHM2ZZGN: Belnave to fresh air. Treat synlptalns. Call a physi.cian.

NCTE 'ZO PHYSICIAN: No specific antiLdote is ]cnawn. Based an the izxU.vidual reactians of the patient, the physician's judgment shard be used to cantml symptams and clinical canditian.

"CMJZION: Zf uncansciaus, having trouble breathier or in convulsions, do nat iritucxa veal.tiTIg or give water.

SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY BQVZE(S) OF EXPOSURE: Eye, SkiIl EYE CONIECT May cause ixritatian with pmlanged,contact.

SKCH KRZLCZ: May cause irri.tatian with pmlanged cantact.

PRK 1 OF 7 NALCQ CHEMICAL COMPANY ONE NALCO CENTER ~ NAPERVILLE. ILLINOIS 60663-1 168 enweb nnn

"i MATERlAI SAFETY DATA SHEET PROOUCT NA~ 8356D DISCI WALCO Emergency Telephone Number Medical (708) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION" 5 HEALTH EFFECTS INFORMATION ( CONTINUED }

SYMPIGHS OF ZZEGSUIK: A reviev of available data does not. identify any synIptrzns fram exposure.

AGGRAVATION OF E}(ZSTING CONDITIONS: A review of available data does not identify any worsening of existiag conditions.

SECTION 6 TOXICOLOGY INFORMATION ACUZE TOXICITY SIUDZES: E~a toxicity studies have been conducted an this pzadtcct:. 'Ihe results are shown belch.

ACUTE GRAL TOXICITY (AIBZNO RATS): ID50 = Greater than 5,000 mg/kg SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COZQR Clear light green PCRN: Liege.d - . ODOR: Nane DENSITY: 9. 6 1bs/gal.

SOIIIIKIZTY IN KZER: Completely SHXXFZC GRAVITY: 1.16 6 76 Degrees F ASIM D-1298 pH (NEAT) = 5.7 ASIM E-70 VISCXSZTY: 65 cps 6 76 Degrees F ASIM D-2983

'SIM D-1177 FZASH MINI!'one I'REZ2Z PQZPI!: 5 Degrees F NOTE: Grese physical properties are typical values for this product.

SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH PQZNI'ane the water is boiled

~!

away.

'Ihe remainiIng organics may be-ignitable. Use water UNUlKAL FIRE AND E)tHQSZGN KQARD: May evolve NOx or SOx under fire conditions.

SECTION 9 BEACTIUITY INFORMATION

'd Mt!

which can generate heat, fires, explosions and the release of taxic fumes.

'M2%AL GEXX5tPQSITZGN PRDVJCIS: In the'vent of cambustian CO, CO2, NOx, SOx PRK 2 OF 7 NALCO CHSMlCAL CQIVIPANY DNE NALCO CENTER ~ NAPERVILLE.,ILLINOIS60563-'1 196 NBA 791 3(i'9 1lXEC)

MATERIAL SAFETY DATA SHEET PRODUCT ~~ 8356D DISPERSAL e .

NALCn Emergency Telephone Number Medical (708) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION, 9 REACTIVITY INFORMATION ( CONTINUED )

may be formed. Da nat breathe smoke or fumes. Near suitable protective equipment e SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRRIURY HKKXXTICN: Respiratory prot~ion is nat normally needed since the volatility and taxicity are lear. If significant rid.~~ or aerosols are generated, wear a NIOSH approved or equivalent respirator.

For large spills, entry into large tardes, vessels or enclosed small d

breathinp apparatus is xeccmmended.

P~~

VENTXLIKXON: General ventilation is M i:fl Nil, ~ 1 1 wl.

llew Qml If Clathing iS Canta1ninatedr mumVe Clashing and tharaughly WaSh the affected area. Laurxler contaminated clothing before reuse.

SECTION 11 SPXLL AND DISPOSAL XNFORMATION IN CASE OF TRANSPORTATION ACCIDENTS, GAL %HE FOL'GASHING 24~R TE'ZZPHClNE NUMBER (708W20-1510)

SPILL CGÃZRDL AND RZXXM!RY:

Small liquid spills: Carrtain with absoxberrt material, such as clay, soil or any caamercially available absorbent. Shovel reclaizjled liquid arxi absoxhent into recavexy or salvage dxulns for disposal. Refer to CEKXA in Sectian 14.

Large liquid spills: Di3ce to prevent further navement and reclaim into recavexy or salvage dxums or tank txuck for dispos-Q.. Refer to CERCKA in Sectian 14.

DISPQStQi: If this product becxxmm a waste, it does nat meet the criteria of a hazardous waste as defined un'der the Rescau~ Conservation and Recavexy Act (RCRA) 40 CFR 261, since nor is it l~al under Subpart it does nat have the chmacteristics of Subpart C, D.

As a non-hazardous agents (such as liquid waste, sand, fly ash, or it should be solidi.fied with stabilizing cement) so that no free liquid remains before disposal to an industrial wa.~ landfill. A non-hazardous liquid waste can also be day~11 injected in accordance with local, 'state and PAGE 3 OF 7 NALCQ CHEM!CAI COMPANY ONE NALCO CENTER ~ NAPERVILLE. ILLINOIS BQ593-1199 AREA 708-305 1000.

MATERlAL SAFETY DATA SHEET PRODUCT NAY~ 8356D DZSFEZSANT ZALCP Emergency Telephone Number Medical (708) 920.1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION" 11 SPILL AND DISPOSAL INFORMATION ( CONTINUED )

federal regulations.

SECTION 12 ENVIRONMENTAL INFORMATION If released into the environment, see CEKIA in Section 14.

SECTION 13 TRANSPORTATION INFORMATXON DCf(! PROPER SHZPEIXNG NAME/HAZtQU) CODE - PROCUCZ IS %7'EGUIATKD D3RZNG TRANSPORGIITXON SECTION 14 REGULATORY INFORMATION

'Qm fo11owing regulations apply to this product.

FEZERAL REGUIATXC58:

OSHA HAZARD CCIMMUNXCKTION RULE, 29 CFR 1910.1200:

Based on our hazard evaluation, the follmrinp irrpxdient in this prochmt is hazardous and the reason is shan belier.

Sodium bisulfite THA, 5 m~3 ACGZH/TLV Sodium bisulfite ~ THE 5 mg/nl3 ~PEL CE~SUPERFUNDr 40 CFR 117, 302:

Notification of spills of this product is not requuxd.

Q/

(TZXM IZI) SECZXGNS 302 r 3 llr 3 12 AND 3 13 SECTION 302 - KERBGK'C HAZARDCUS SUBSTANCES (40 CFR 355):

'Ignis product does not contain irxpmU.ents listed in'Appendix A and B as an Extremely Hazarchms Substance.

Our hazard evaluation has found that this pnxh~ is not hazardaus 'under 29 CFR 1910.1200.

~SECTION 313 LIST OF TOXIC (XKHZCAIS (40 CFR on the prochxct does not contain irrpx6ients (at a List of Tcad.c chealicals.

372):

level'f 1% 'or greater)

PAGE 4 OF 7 NALCP CHEMICAL CPlVlPAgy ONE NALOO CENTER ~ NAPERVILLE. ILLINOIS 60563-1 198 AREA 708-305-1 OOO

8 4-4

'I t'

qA

MATERIAL SAFETY DATA SHEET PRODUCT NA~ 8356D DISPERSANT

~ NALC0 Emergency 7elephone Number Medical (708) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION'4 REGULATORY INFORMATION ( CONTINUED )

'TOXIC SUBSTANCES CORAL ACT (ESCA):

'Ihe chemical izxpmU.ents in 'this product are on the 8(b) Irrventory List (40 CFR 710) ~

SOURCE CONSERVATION AND RECOVERY ACR (RCRA), 40 CFR 261 SUBPART C 6 D:

Consult Section ll for RCBA classification.

FEDERAL WATER POZXVPZCN CXKQK)L ACT/ CLEAN KQKR ACZr 4 0 CFR 4 0 1 15/

formerly Sec. 307, 40 CER 116/formerly Sec. 311:

'Ibis product contains the following irlgredients covered by the Clean Water Act:

Sodium bisulfite - Section 311 CEZAN AIR ACVr 40 CFR 60 I SECZIGN 1 1 1 40 CFR'1 SECTION 1 12 g g product does nat cantain inpmQents cavered by the Clean Air Act.

. STKZ REGUZATICNS:

None of the chlmicals an the current Proposition 65 list are known to be present in this prIxhmt.

~

MICHIGAN CRITICAL MATERIALS:

product does nat cantain ingredients listed an the Michigan Critical Materials Register.

STATE RIGHT KO EKM IANS:

The following ingredient(s) are disclosed for compliance with State Bight To Engr Laws:

'".A%I' >>'>>(>>l r Acrylate polymer Trade secret Sodium bisulfite 763190-5 ~

Water 7732-18-5 ..

IÃZZZNATIGHALREGUZATIQKS:

%his is nat a WHMIS controlled pnxh1ct urder The- House of Callnmns of Canada BQ.1 C-70.

SECTION 15 ADDITIONAL INFORMATION Nalco internal rnnnher F 100309 PAGE 5 OF 7 NALCD CHSMICAL COMPANY ONE NALCO CENTEA ~ NAPERVILLE, ILLINOIS BOSB3-1 1BB AREA 708-3as-1 aoa

MATER!AL SAFETY DATA S H E ET PRODUCT N~ 8356D DISP)~ANT e NALC0 Emergency 7elephone Number Medtcal (708) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 16 USER'S RESPONS1BILITY

'Ibis product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the mmzmoended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that. appropriate handling practices and training pzograllm can be

~

established to ensure safe workplace aperations. Please consult your ii SECTION 17 B1BLIOGRAPHY Public Health Service, PB 33 135855'983.

CASABEXT AND IXUZL'S TOXKCOZCGY, 'IHE BASIC SCIENCE OF POISONS, Doull, J.,

KLaassen, C. D., arxt A9mur, M. O., eds., Macmillian Publishing CcIapany, Inc.,

N. Y., 2nd editian, 1980.

CK.:KECAL HAKQKS OF THE WORKPLACE, Proctor, N. H., and Rx3hes, J. P., eds.,

J. P. Lipinoott Campany, N.Y., 1981.

Nostrand Reinhold ~?anyr N Y r 6th editictlg 1984 ~

TO Research on CMlcI~w, 1972-1977.

eds r Jckln Wiley and Sansr N Y t "'seaii ..

MM, Geneva: World Health Organization, g

International Agency for 3rd editiong Vol

~r f+

2 AMg 1981 ii REGIS'GK OF KCIXZC ITFEXIS ON CSEKECAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, Natianal Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, GH, 1984.

~

Title 29 of Federal Regulatians Part 1910, Subpart 2, Toxic and Code ii

'IHRESHDLD LB'AII3ES FOR CAECAL SUBSTANCES AND PHYSICAL AGENIS IN i THE iblli PAGE 6 OF 7 NAL.CO CHEMICAL COIVIPANY ONE NALCO CENTER ~ NAPERVILLE. ILLINOIS 60563-1 196 AREA 708-305-1 OOO

JOHNSTON POLYMER COMPANY,!NC.

P.o. Box 86 ~ Manvel, Texas 77578 ~ Phone (T13) 489-9528 MATERIAL SAFETY DAT S E SECTION I: PRODUCT INFORMATION PRODUCT NAME: J-POLY 101C CHEMICAL FAMILY: Sodium Polyacrylate CAS NUMBERS 9003-04-7 EMERGENCY TELEPHONE NUMBER> 713-489-9528 or 713-980-7524 CHEMTREC (for emergency involving chemicals): 800-424-9300 EPA HOTLINE: 800-535-0202 SECTION II! HAZARDOUS INGREDIENTS HAZARDOUS COMPONENTS: None SECTION III'HYSICAL DATA MOLECULAR NEIGHTI 1000 pH (as is): 7 '

PERCENT SOLIDS! 50 VISCOSITY< Cp at 77 Fi 1200 PERCENT VOLATILE (Mater)'c 50 Sp. G, at 77 F: 1.36 SOLUBILITY IN MATER < Complete APPEARANCE AND ODOR~ Viscous liquidt clear to hazy No characteristi "o or 1 SECTION IV! FIRE AND EXPLOSION HAZARDS FLASH POINTs None EXPLOSIVE LIMITS~ None EXTINGUISHING MEDIA> Not CODES'EALTH applicable> product FLAMMABILITY vill not burn .

NFPA 0g Og REACTIVITY 0 SECTION V! HEALTH HAZARD DATA Toxicological Information (Range Finding Studies):

Rati Acute oral LD50 greater than 5g/kg Rabbit> Acute dermal LD50 greater than 5g/kg Rabbit's Eye irritation slight Rabbit< Skin irritation none Daphni a r 48 hour5.555556e-4 days 0.0133 hours 7.936508e-5 weeks 1.8264e-5 months LC50 greater than 1000 ppm Sunf i sh, 96 hour0.00111 days 0.0267 hours 1.587302e-4 weeks 3.6528e-5 months LC 50 greater than 1000 ppm

'Trout> 96 hour0.00111 days 0.0267 hours 1.587302e-4 weeks 3.6528e-5 months LC50 greater than 1000 ppn1-Product does not contain carcinogens sub)act to the reporting requirements of SARA TITLE III.

May cause irritation of skin and eyes. For eye contact, flush with water for 15 minutesy get medical attention if irritation persists. Mash skin with soap and vater.

4 HMXS RATING HEALTH 0 g FLAMMABILITY 0 g REACTIVITY - 0

SECTION VZs REACTIVITY DATA product is stable; vill not undergo hazardous polymerization.

SECTION VZI: SPZLL OR LEAK PROCEDURES Dilute spill with small amount of water and use absorbent. Land fill in incinerate contaminated absorbent. Carry out disposal in accordance vith federal> state nnd local regulations.

SECTION VIII: PROTECTIVE EQUIPMENT REQUIRED Respiratory protection is not required. Use rubber gloves<

boots and apron for direct handling. Use face shield or goggles for eye protection.

SECTION IX! SHIPPING INFORMATION/OTHER COMMENTS Doi IDENTIFICATION NUMBER: N/A DOT LABELS REQUIRED: None HEPORTABLE QUANTITY! N/A BILL OF LADING DESCRIPTION~ Cleaning/Hashinj ComPound, NOZ PREGAUTZONARY MEAsUREss Keep avery from heat or open flame. Use with adequate 'ventilation. Do not breath " vapors. Avoid prolonged or repeated contact vith skin.

DEFINITIONS NFPA RATINGS System adopted by Nationa1 Fire Protection Association to identify hazards in a

'~

firy situations

'evere 0 ~ No knovn hazard 3 hazard 1 ~ Slight hazard . 4 = Extreme hazard 2 = Moderate hazard MIS RATINGs Hazardous Materials Identification System adopted by the National Paint S Coatings Associationi 0 ~ Minimal hazard 3 ~ Serious hazard 1 Slight hazard 4 = Severe hnznrd 2 ~ Moderate hazard * = May be chronic cAs NUMBER< chemical Abstracts service Number

-SARA: Superfund Amendments Reauthorization Act of 1986 (also referred to as the "Emergency Planning and Community Right To Know Lav of 1986")

DOT: Department of Transportation Revised Feb. 1, 1990 ,, ......, .. :.Supercedes Mayi 1985

BETZ INDUSTRIAL i63G 90t1ERTON ROAD TREVOSEi PA, 19047 BETZ t1A TER I AL SAFKTY DATA SHKKT HOUR Et1ERGENCY TELEPHONE ( HEALTH OR ACCIDENT ) 215/355-3300 PRODUCT ~ CLAt1'TRGL CT) EFFECT I VE DATE 1 0-31 -88 PR INTED: 12/28/88 PRODUCT APPLICATION WATER-BASED HICROBIAL CONTROL ACKNT.

---SECTION 1-----------HAZARDOUS INGREDIENTS INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PKL'S AND TLV'S FOR SPKCIF IC PRODUCT INGREDIENTS AS REQU I RED BY THE OSHA HAZARD COt1t5UNI CAT IONS STANDARD ARE LISTED REFER YO SECTf04 4 (PAGE 2) FOR OUR ASSKSStIKNT OF THK POTENTIAL ACUTE AND CHRONIC HAZARDS OF THIS FORHULATION.

4<<>>

ETHYLENE GLYCOl i~~CASe107-21-1)LIVER, KIDNKY AND bLOOD TOXIN;CNS DEPRESSANT; ANI ttAL TERATOGEN(HIGH ORAL DOSES); PKL: NONE; Tl V: 50PPt5( CEILINC),

a ALKYL Dlt1ETHYL BKNZYL At1t)ONIUt1 CHLOR IDE1oeCAS0604t4 d5 5 'ORROSIVE(KYKS);

PKL NONE;TLV:NONE.

>> ~

ALCOHOL+ ( IPA ); CASO&7 63. 0 SLAN5ASLK>> LlaVID;CHRONIC li'SOROB'YL OVEREXPOSURE t)AY CAUSK LIVER AND KIDNKY TOX! CITY J tKL/TLV:400PPN.

DODECYLCUANIDINK HYDROCHLORIDKepo(DQH).,; CISI535$ 0 $ 7 5; CORNOOIVK; PEL: NONE; TLV:NONE.

' <<>> >> 1<< 'P%

Ol! ~ ~ >> e

~ ~'y~ <<g ~ "~" "~>>>>>>tp

"',> 4%>> s ',h>>rg

~ ~ >ax >>>>> s - h,> <<>> ali)tl', c PRESSURE

~

<~V ~ =4 ~

SECT ION 2 .~ TYP ICAL PH'fSICAL -QATAR'

~ la PH: AS I S (APPRO)(i,)q S. 3 "ODOR: jlILD-;,

FL.PT. iDEG.F): 55C SKTA(CC) SP.CR. (70K)OR DRHSITY: 5.0QR VAPOR VISC cps70F:

. RATE: (5 23,,23,,...

( ooHO 1>>

ETHER~1

~

=

~ VAPOR DfNQY (AIR5,)>>,

XSOLUSILITY(MATfk): 500 APPKARANCa: COI OILKSS

> 5. r,.

f"'VAP

>><<c PHYSICAL STATE: LIQUID FRffZm POiNT(DgQ,I',): < 30

-SKCTION 3 -- REACTIVITY,,DhTA.. ~. ~ >> ~ >>

4 ~ -" ~ 4~

STABLE

'Rt5AL DKCOt(POSITION (DESTRUCTIVE FIRKS) YIKLDO CLK55KNTAL OXIDKS

MaTERTAL SAFETY OATA SHEET (PAGE g OF g)

ROOVCT: CLAM'TROL CT> KFFKCTIVK OATK

SECTION 4-- --------HEALTH MA2ARO EFFECTS CUTE SKIN EFFECTS >>>>>> PRIMARY ROUTE OF EXPOSURE CORROSIVE TO SK?N.l OTENTIAL SKIN SENSTTIZER CUTE EYE EFFECTS CORROS I VE 70 THE KYES CVTK RESP?RATORY EFFECTS +++ PRIMARY ROVTE OF KXPOSURK VAPORS'ASKS MISTS ANO/OR AEROSOLS CAVSK IRRITATION TO VPPER RESP IRATOR Y TRACT HRON I C EFr 6'C TS OF OVER EXPOSURE + + +

PROLONGEO ~'..R REPEATED OVEREXPOSVRES MAY CAUSK: TISSUE NECROSIS)BLOOD CELL DAMAGE OP l.")PAIR BLOOD CELL FVNCTION'KPRODUCTIVK SYSTEM TOXICITY; SKIN SENSITIZATION.

EDICAL CONOITIQNS AGCRAVATEO >>>>>>

NOT KNOLJH YMPTOMS OF FXPOSVRE INHALATION OF VAPORS/MISTS/AKROSOLS MAY CAUSE EYEgNOSKgTHROAT AND LVNC TRRITATIOV;SKIN CONTACT MAY CAUSE SEVERE IRRIThTION OR BURNS.

'RKCAUTIONARY STATEMENT BASED ON TKSTINC RESULTS moo MAY BK TOXIC IF ORAI.LY INCKSTKD".

. -SECTION S-------- ---FIRST ATD INSTRUCTIONS

~

KIN .CONTACT+>>>>

RKMQVK CLOTHINC.I>ASH AREA lJITH LARCK AM4UNTO QP'OAP'OI UTION ON MATER FOR t5 M!N.IMMEDIATELYCONTACT PHYSICThN

.YK CONTACT>>>>>>

IMMEDIATELY FLUSH EYKS WITH lJATKR fOR 1$ MINUTES. IMMEDIATELY CONTACT A PHYSICIAN FOR aOOITIONAL TREATMENT NHALATIQN EXPOSURE +>>

REMOVE VICTIM FROM, CONTAMINATED ARKA.APPLY NKCKSSARY FIRST AID TREATMENT. IMMEDIATELY CONTACT A PHYSICIAN.

NCKSTIQN>>>>i OO NQT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO,QQT It)OVCE VOMITING. IMMED. CONTACT I HYSICIAN.DILUTK CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER

--SECTION 6- --->>------SP ILL,DISPOSAL AND FIRE INSTRUCTIONS

~ PILl INSTRVCT TON= >>>>>>

VKNTTLATE AREA USE SPECIFIED PROTKCTIVK KOUIPMENT.CONTAIN AND

~

ABSORB ON ABSORBENT MATERIAL.PLACE TN lJASTE DISPOSAL CONTAINER.THE CONTAMItlhl':O AQSORSENT SHOUI D BE CONSIDERED A PESTICIDE AND DISPOSED QF IN hl4 APPROVED PESTICIDE LANDPILl SEC PRODUCT LASEI

~

STORAGE AND OISPONAL INSTRUCTIONS.

I REMOVE IGNITION SOURCES FLUSH AREA IJITH MhTER.SPREAD SANO/GRIT

) TSPOSAL INSTRU>.'T IOUS>>>>e MATER CONTAMINATED LJTTH THIS PRODUCT NAY IE SENT TO h SANITARY SEVER TREATME"IT FACILITY,IN ACCORDANCE QITH AliY LOCAL ACREEMENT A PKRMITTFO WASTE TREATMENT FACILITY OR DISCHARCKD UNDKR h NPDKS PKRtlIT PRODUCT(AS IS)-

BURY IN AH APPROVED PESTICIDE FACILITY QR DISPOSE OP IN ACCORDANCE 4 I TH LABEL INSTRUCTIONS IRE EXT'INGVt . HJ?JG INSTRUCTIONS>>>>>>

FIREFTGHT Q =..)<OI>LO UKASE PQSITIVE PRKSSURK SELF CONThlNKD BREATHINC APPARATVS<<VLg PACE-PIECE TYPE).

ORY CHEMICAL, '. '"Bl)N DIOXIDK,FOAM OR WATKll

HATERIAL ShfETY DATA SHEET (PACE 3 OF 3) e .ODVCT: CLhN'TROL CT1

SECTION 7 - - - SPECIhL PROTECTIVE EQUII t1ENT EFFECTIVE DATE 10 31-88

>SE PROTECTIVE EQUIP)(ENT IN ACCORDANCE WITH 29CFR SECTION 1910.132 13$ . USE ESP IRATORS lJITHIM USE LIHIThTIONS OR ELSK USK SUPP! IED hiR RESPIRATORS.

'KNTILhTION PROTECTION<<<<<<

ADEQUhTE VENTILATION TO tlhtNTAIN AIN CONTAHINANTS BKI Oll EXPOSURE Ltl1ITS

,'ECOHHKNDED RESP IRhTORY PROTECTION<<ee tf VENTILATION IS INADEQUhTE OR SICNIFIChNT PRODUCT EXPOSURK iS LIKELr, USK h RESPIRATOR l4ITH ORQANIC VAPOR CANTNIDCKS hND DUST/)IIST PREFILTKRS.

.'ECONtlENDKD SKIN PROTECTION<<ee QAUNTLET-TYPE nubbEN CLOVES.CHEHtCAL NKSISTANT htNON WhSH OFF AFTKN KhCH USE.REPLACE hS NECESSARY

.'ECOHtlKNDKD EYK PROTECTIONeee SPLhSH PROOF CHKHIChL QOCCLES.FACE SHIELD SECTION 8- ------STORACE AND HANDLINO tNKCAUTIONS-3TONACK I NSTRUCTIONSeee KEEP DRUNKS I PAILS Cl.OSED IJHEN NOT IN USC.

STORK IN COOL VENT I LATED LOCATION. STORK AMAY FNOll 4XIDIZKNS IhNDLiNC INSTRUCT IONSeee IH)(ED I ATELY RKHOVK CONTAMINATED CLOTHINO g MASH IKFONg REUSE t

CONSUSTtbLK. DO NOT USK AROUND SPARKS ON FLANKS. bOND C4NTAINKNS DUNINO FILl INO ON DISCHARQK IJHKN PKNFONt(KD AT TK)ltKNATVNKS AT ON ASOVK THK PRODUCT FI ASH POINT.

>oeeeeeeeeeeeeeeeeeoeee ~ e<<eeeeeoeeeeoeeeeoeeeeeoeeeeeeeeooooeeeeoeeeeeeee

.IS HSDS CO)ltLIKS MITH THK OSHA HAZAND CO)(IIUNICATION STANDAND

<ANOLD t(. HKNSH ( ENVIRONMENTAL INFORMATION COONDINATON )

seeoeee<<<<eeoc<<e<<eeoeeeeeeee<<<<eeeeeeoeeeeeooeeoooooooeeoeooeooooeoeeeeeeeee hPPKNDiX: .NKCVLATONY INFONNATION rHK CONTKNT OF THIS APPENDIX REINKSKNTS tNI ONi(ATION l(NOMN TO bKTZ ON THK

FFKCTIVK DATK OF THIS )(SDS. THIS IKFONHATION IS SWLIKVKD T0 SC ACCVNATK.

INY CHANCES IN RKCULATIONS MILI NKSVLT IN VPDATKD VCNSIONS 4F THIS DOCV)IKNT.

... TSCA: ALl COMPONENTS OF THIS tNODUCT ANR LISTRD IN TH% TSCA INVENTORY

. ~ . FIFNA(AOCFN ): Kl h NKO NO. 307l

~ 14$

.. REPORTABLE QUANTITY(NO) FON UNDILUTKD tNODUCT:

IOT APPLI CAQLK

..RCRA: IF THIS tN40UCT IS DISCANDKD AS A MASTmiTHm NCNA HAZANDOUS MASTE (DKNTIFICATION NUllSSN IS! D001otONITAILKiDOOa<CONNOSIVK

..DOT HAZARD CLASINDICATION: CONNOSIVm TO SKIN.COllOUSTILLt

~ DOT SHIPPINO DROIONATION iS: UN1740 CONNOSIVC LIQUID N.O.S.

THIS PRODUCT CONTAtNS THESE CHK)(ICALS 1(NOMN TO THE STATC'F CALIFORNIA TO

A SK CANCER ON NCtNODUCTIVK TOXICITY: NONa tNfSRNT IN SIONIFICANT hl(OUNTS

~ .. SARA SECTION 302 CHK)(ICALS: NON% tNRSfNT IN SIONIFICANT AMOUNTS

~ ~ SARA SECTION 313 CHRNICALS: ETHYLKNa OLYCOL(107 at 1 ) p 21. 0 30. OX

...SANA SECTION 318 HAZAND CLASS: l)(llKDIATC(ACUTE)i DCLAYKD(CHNONIC) AND l INK

~ ~ .NICHICAN CRITICAL NATKNIALS: NONE tNKSKNT iN SIONIFICANT Al(OUNTS Vfth/HUIS: HEALTH 3 3 FiRE 2 REACTIVITY 0 ) StaCIAL CONN PR D

'g 3

BETE LABORATORZES, ZNC.

4636 SOMERTON ROAD, TREVOSE, PA. 19047 PRODUCT: CLAM TROL CT 1 2/22/89 AQUATZC TOXZCOLOGY RAZNBOW TROUT 0% MORTALZTY: 10 MO/L 96 HRo LC50: 14o7 MO/L DAPHNZA MAGNA 0\ MORTALZTY: 0 ~ 16 MG/L 48 HR. LC50! . 0.4,.MG/L FATE%AD MZNNOW 0\ MORTALZTY:

96 HRe LC50c

l. 553 MO/L

~ 0 lN/L 2/22/$ 9 MAMMALZANTOXICOLOGY ORAL LD50 NO DATA DERMAL LD50 NO DATA SKIN ZRRZTATZON SCORE NO DATA EYE ZRRZTATZON SCORE NO DATA NO DATA 'NHALATZON

, ~

~ ii r MATERIAL SAFETY DATA SHEET DATE March 13, 1990 6341-10-15-86-568 CALGQN c 0 II o 0 ii osI 0 a PRODUCT NAME H-130 Microbiocide SUBSIDIARY OF MERCK S CO..INC.

MANUFACTURER'S NAME EMERGENCY Calgon Corporation TELEPHONE NO. (412) 777 8000 ADDRESS P.O. Box 1346, Pittsburgh, Pennsylvania 15230 CHEMICALNAME FORMULA ANO SYNONYMS Microbiocide Multicomponent Liquid e it r' g TLV (Units)

PRINCIPAL HAZARDOUS COMPONENT (S) CAS g BY WEIGHT ORAL LDso DERMAL LDso ACG IH OSHA OTHER cr amicai Didecyl Dimethyl Ammonium Chloride 7173.51.5 50 450 mg/kg Not Not Not N/A Cornrnon- . Available Listed Listed Nsrne Chemical Not TWA. PEL -

F 64-17-5 10 14 g/kg N/A Common Available 1000 pp 1000 ppm Name Ethyl A(Cobol Chemical Noma ~

Common Name Chemical Name Common Nome Chemical Name Common Nsnio r Q s s BOILING POINT I') 212 SPECIFIC GRAVITY (Hs 0~1) 0.9 PERCENT VOLATILE VAPOR PRESSURE (mmHg.) Unknown BY VOLUME ('Yo) 50 VAPOR DENSITY (AIR~1) Unknown pH 7.3 - 9.0 SOLUBILITYIN WATER Complete OTHER N/A APPEARANCE AND ODOR Colorless to yellow, slightly viscous liquid N/A ~ Not applicable kVhile this information and recommendations set forth herein are believed to be accurate as of the date hereof, CALGON CORPORATION MAKES NO kVARRANTYlVITHRESPECTHERETO AND DISCLAIMSALL LIABILITVFROM RELIANCE THEREON. Pago 1 of 4

~

I.ASH POINT Method Used 115oF (C.O.C); This product is combustible.

'ISHING MEDIA Use dry chemical, foam, CO2

- SPECIAL FIRE FIGHTING PROCEDURES Exercise caution when fighting any chemical fire. A selfwontained breathing apparatus and protective clothing are essential.

UNUSUAL FIRE AND EXPLOSION HAZARDS None EFFECT OF OVEREXPOSURE A. ACUTE I IN G ESTION

~

This product may be expected to be harmful or fatal if swallowed.

2. INHALATION This product is expected to present a Iow potential inhalation hazard.

3. DERMAL EXPOSURE This product would not be expected to produce systemic toxicity

a. TOXIC if it is absorbed through the skin.

b. I R R I TAT ION This product may be expected to cause burns upon contact with the skin. The severity of the burn is generally determined by the concentration of the solution and the duration of the exposure.

c. SENSITIZATION No data were available to suggest that this product may produce an allergic skin reaction Page 2 of 4 IMP.0568 3/13/90

r, a

4. EYE IRRITATION This product may be expected to cause burns to the eye.

SUBCHRONIC, CHRONIC, OTHER No data were available to indicate that this product may produce adverse health effects following subchronic or chronic exposure.

~gP+t<I@ ~6g quirk) .~ g %~aRa~gg%

F I RST AID A. EYE In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Seek medical aid.

0 B. SKIN In case of contact, immediately wash with soap and plenty of water for at least 15 minutes. Seek medical aid. Remove and wash contaminated clothing before reuse.

C. INGESTION If swallowed, drink promptly a large quantity of milk, egg whites, gelatin solution: or if these are not available, drink large quantities of water. Avoid alcohol. Call physician immediately.

NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock, respiratory depression and convulsions may be needed.

D. INHALATION Not applicable IMP.0568 3/13/90 Page 3 of 4

gl k

r P

STABLE X CONDITIONS Store away from heat and flame. Do not contaminate water, food or feed BILITY UNSTAB TO AVOID by storage or disposal.

'FATABI LITY '\

.als to Avoid) Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS During decomposition, NH3 may be released.

~ ~ ~ k I

REPORTABLE QUANTITIES IRQ) NOTIFY EPA OF PRODUCT SPILLS IN LES OF EPA HAZARDOUS EQUAL TO OR EXCEEDING SUBS ANCES IN PRODUCT

~ 1. N/A 2

N/A LBS.

ST;?S TO BE TAKEN IN CASE M- I'ERIAL IS RELEASED Ch SPILLED Dispose of in accordance with local, state and federal regulations. Pesticides are acutely hazardous.

Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal law.

WASTE DISPOSAL METHOD Dispose of in a landfill or incinerate in accordance with local, state and federal regulations. This product is toxic to fish. Oo not discharge into lakes, streams, ponds, estuaries, oceans, or public waters unless in accordance with NPDES permit. Do not discharge effluent containing this product to sewer systems without previously notifying the sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. If these wastes cannot be disposed of at. the nearest, EPA,Regional. Office,fo~ruidance> ~~~~~~~

by use according to label instructions, contact your State Pesticide or Environmental Control Agency or hazardous waste representative

+w~'v'~r."=.'":<~"= ~~;--'F-rggFi&Rg tG~

PROTECTIVE GLOVES EYE PROTECTION Rubber Chemical splash goggles or face shield HER PROTECTIVE Not required CLOTHING

~ RESPIRATORY PROTECTION Not required, however if the recommended ACGIH-TLVor OSHA-PEL for ethyl alcohol is exceeded, then a NIOSH/MSHA approved respirator should be used. (See Section II)

VENTILATION LOCAL EXHAUST OTHER Recommended Use only in well. ventilated areas that will MECHANICAL maintain air levels below limits established by (General)

Recommended local, state and federal re ulations.

STORAGE 8c HANDLING DANGERI Corrosive.

Causes severe eye and skin damage.

Harmful or fatal if swallowed.

Do not get in eyes, on skin or clothing.

Avoid contamination witlkfo'od.'.'-

'ubber Wear chemical splash goggles or face shield and gloves when handling.

kk Pk k ER PRECAUTIONS k

For container disposal, triple rinse (or equivalent). Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by other approved state and local procedures.

N/A ~ Not applicable Patricia A. Pacella IMP.0568 3/13/90 Price 4 of 4 PREPARED BY

4~

I P'1

II ~ A 88/1S/1991 18:57 FRY CTS SNARKETING TQ VALLEY FORGE P.83 I

QFOQt A5MLAJ IfldUStFIQl NVl8lOA Emergency CAIQC4L IWC'.

Te)ephone MATERIAI SAFETY one Dr ~ etc'on on'sleYe Jeteey o5 L(800) 274 5263 DATA SHEET Phone 1201) 26S-7600/Telex l38444 000034 OLIN 3204 ALGICIDE Page; THIS IISOS COOLIES WITH 29 CFR 1010.1200 (9% HAZARD CONNHIICATIOH STAHOAAO)

~ JJeJi ~ eeeeeeeeeeeeee ~ Seeeeeeeeeeeeeeeo ~ 00010001$ 0010 ~ 0 ~ 00eleeeeeeOe ~ oieeeeoe0000eee ~ eeeeeee ~ Jilleeeeeletott Product Hans OI IN 3204 AIOICIOE Data Sheet HOr 0248054-002 0O 01 013. 0003883-404 prepareoi f1/ I)/Ql DREW INDUSTRIAL DIVA Supereeoeei 1/0 /

eVI7 W. 110Tli ST, iI00 OVERLAND PARA. X4'S82 IO PROOU)T:

IHVOI Ei~ REOST INVOICE DATE) 01/30/01 TOi General or Oenertc IOI ALOICIDd OOT Haeara Claeetf teat loni HOT APPLICASLP.

E

)NO AgJR54liTM OP SARA TITLE I)QSEQIOH 31+ARE fOEHIQ8lPPI4 llilSMR IHOAEOI EHT % (by WT) PEL TLV Note OUATEANAAY ANIHILNCONl POLYE~XVLATS 10"25 (1)

HoieeI

( 1) PEL/TLV HOT L5TAQJQ%0 POR llIIS NTERIAL P

botlln0 Potnt fOI'OPOHENT( 70-88%)

I ill:m QNcl vapor Preewre Speotf te Vapcr Oenatty for AIR ~

COwOHEHT(

1

'3m~ > 1,0 Specific Oravtty Percent Vo 1 at I lee dvaporat ton Rate hppearaIce SLOWER CLEAII

~

77,00%

H)IER LIOIT YELLOW State LIQUID t~

PLAN POINT NOT=APPLICQQ EXPLOSI Vm LiNT NOT APPLICMN I, EXTIHOUISHIH4 MQAI NTRN IKO QIWIIQOECQOQITIOHQR CSOUST)OH itIY PIIOOUCSI DIOXIDE AHO CAARON P MmPQ CARSON PIAgfyHgg Plg~@Wfg +-ggAIHHO PKVlliliHIAPPAAATUQ /TH A FULL PACEPIECE OfmtATEO IH ll% POSITIVE WATlbt INY N U380 TO RXTIlCNISH fNt BY COOLINO, ANO OILUTIHO 1 IQUIO WI& teeTKRE SPECIAL PIRa 8E WOSION HAXMOSI HOT APPLICASLE HF PA CNESI WALllt. 1 PLiNNILITY- 1 REACTIVITY- 0 PMCSSIKR aXPOSN%'SVLI HK ESTAN.IORD.

EFPaCrS Of ACUTa OVaR8XPOSURSI

)Nfii ~ CAN IOfT !

IAEAINIIO INetif@ VAICNLCAN CAUSE NELS ANU AEQRRAICRT [RRITATICN PIAST AIDE I P oH SRIHE TlcMRoe Y wAsH ExPosED AREA wITH soAP AND wATER REjevP. COHTAilIHATEo cUlT)IIN0A v4NDEA coaTAINHATwo QADI& iio eerote It~ac N

88/151991 11:81 FRY CTS &NARKETIHG TQ VALLEY FORGE PE 89 24-HOUR Drew hsNIue Industrial aweek', ec.

Divisian Emergency NIATBRIAL SAFETY One Drew Plese, boonton, New Jersey 07005 TeLephone DATA SHEET Phone (201) 263-7800/Telex 138444 1(800) 274"5263 or L(800) ASHLAND aaaa34 OLIN 3204 ALQICIDE Page: 2 ATTEHTIOH, IF IRRITATION PERSISTS.

IF SWALLOWED) DD NOT INDUCE VCMITING, IIbSKDIATELY DAINK TWO GLASSES OF WATER) NEVER GIVE ANYTHING SY MOUTH TO AN UNCOISCIOUS PERSOHP CALL PHYSICIAN OR TRANSPORT TO AH PAJSENCY FAC!LITY.

IF BREATHED( IP AFPKCTED AE)IVE INDIVIDUAL TO FRESH AIR, IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN 1F 8REAIHING HiS STOPPkl GIVE ARTIFlCIAL RESPIRATION ~ KEEP PERSON WARM, QUIET AND GKT MEDICAL ATTENTfOH, PRliMRY ROUTE(S) OI'NTRYI INHALATIONP SKIN COHTACT HAZARDOUS POL~IZATICHs CA)bK)T OCCUR STADILITY! STAbLE INCCWpATIblLDYI AVOID COHTACT Wl'IHr E EXCESSIVE %AT, STRONG OXIDIZING AGEHTSP E

STEPS TO KE TAKEN IN CASK MATERIAL IS RELEASED OR SPILLED:

SMiLL SPILLI PERSONS HOT WEARING PROPER PERSONAL PROTECTIVE EQUIPPIHT SKULD KK EXCLUDED PRON AREA OF SPIlL, hbSOIb lslQUID ON PAPER ~ VERMICULITE~ FLOOA AbSORKENT OR OTHER ASSORQENT MATERIAL~

BEEN IVNPLETR EVOP )PILL ATIOIIICE OIIK AREA OP EPII.L QTPRENT EPIFEQAI~ONPlkaiggAI TAI TANK.

PREVENT AUHMF TO SEWERS, STREAMS OR OTHER bODIES OF WATER, IF RUNOFF OCCURSP NOTIFY PROPER AUTHORITIES AS RKQUIRKDR TNT A SPILL Hib OCCUREDP E ~

WASTE DISPOSAL ial)KK)>

SMALL SPILLr DISPON OF IN ACCORDANCE W!TH ALI. LOCALE STATE AND FEDERAL RKGULATIOHS.

LARGE $ PILL) DISPOSE OP IH ACCORDANCE WI1H ALL LOCAL, STATE AND FEDERAL RKGULATIOHS, E

RESP IRATOIY P OV HA SEEN DETERMlHED OA DOCUMEHTKDP h HIDSH/MSHi JOINTLY APPROVED AIR SUPPLIED R 1 OF PROPER KNVIRONMHTAL CONTROLS OSHA REGULATIONS ALSO PKRMlT OTHER HIOSH/ SPECIFIED CONDITIONS, jSEK YOUR SAFETY KQUIPIKHT $ UPPLIKR) ~ ENGINEERING Ql AMH1$TRATI bK Iib LBKÃfKDTO RKDUC EXPOSURE.

LKVKI. I VKNTILATIONt PROVIDE SUFFICIENT %CNHICAL (GENERAL AHDIDA LOCAL EXHAUST) VENTILATION TO NIHTAIN EXPOSURE OVEREXPOSURE ( RNI KNON, SUSPECTED DA APPAAENT ADVERSE EFFeCTS),

SELOW PROTECTIVE GLOVESI INAR RESISTlNT GLOVES SUCH ASIA NA'IlAIALRUMER IH CNOLIANQK WITH KYK PROlKCTICNc CHEQ~QQlg+Kp OP AEGULAT1ONS ARK ADVISED@HIIWKVER, OSHA OTHE'AOTECTIVE KQUIPSMBITs TD PREVENT SKIN CONTACTS WEAR IMPERVIOUS CLOIHIHG AND 800TSE EYEWASH STATION SSRGKNCY 5NNS.

COHTAINKRgOF Wg MATERIA Miy q HAZARDOU~INII ~lg yIICE SOT)ED COHTAINKAS AETAIH PAIICT RESIDUES I,

KEEP FR(EI FREEZING.

INFOAiMTIOH Ac554LATKD IRRHN 1$ bKLIKVKD TO bK ACCURATE bUT IS NOT wAARANTKD TO bK IbIKTHER'ORIGINATING wITH llew cINP Hg~ RQIPIKHTs ARE ADYIsKD T caHFIRM IN ADYANcK DF HKKD ~T. T$ $ IHRNAITIIRI Is CURRENTS A TlbLK TO TlCIR CI lNCKS.

88i15i1991 18: 59 FROM CTS KMARKETING TO VALLEY FORGE IJi LtfV ItlLOLtOsslAI anwenearee P. 86 ygws-Fet0wl A~ecKucaa ~pa% & A~o>.etc, One Dew Piete. Boenton. New Jeraey 070{5 Prewar iebn Ã4 rbbbrreiew 1bt444 MstftItal Safety Data Sheet 24 HOUA EMEAGENCY TELEPHONE go/324 It33 0EFlNITIONS This definition oage Is Intended for use with Malarial Safety Data Sheets supplied by the Drew Chemical Corporation, Recipients of these data sheets should consult the OSHA Safety and Health standards Q9 CFR tatg}, particularly

~ ubpart G ~ Occupational Health and Environmental Control and subpart I ~ Personal Protective Equi pment, tor general guidance on control of potential Occupational Health and Safety Hazards.

EXTIXQUISHINO 'ottowtng National Fire OEXERAL OR OEXERIC ID: Chemical family or product Protection crfterta.

description.

FIREFIO 0 PROCtNfRES; Minimum ettutpment to DOT HAZARD CLASSIFICATION.'roducl meals DOT orotect tee ttudc ~ of vapoNza-criteria for hazards fisted. or tlon In fire situations, Other ttng htaarda may also be indicated.

SPEOAL FIRE ANO SIPLOSfON HAZARDS; States hazards not covered by other sections.

Comoonents are listed ln this section If they present a vs)cai or health hazard and are present at or above Yo in the mixture. If a component ls Identified as a

"".".iMKM~CC~W"'"

RCINOGEN bv NTP, IARC or OSHA as of the date on the MSDS. It wiII be lltlad and,footnoted ln this teclion when present at or above O.t Ye In the product, Nega.

tive conclusions concerntntt carcinogenicity are not re-oorted. Additional health Iftformation may be found In PERMISSIILE EXPOSURE LIMITS For product.

Section V. Components sub}act to the reporting re-auirements of Sectlcn 3t3 of SARA Title ill are idenli ~ THRESHOLD LIMITVALUEl For product, ed in the footnotes In this section, along with lyplcai percentages, Other components may be listed II EFFECTS OF ACIJTE OVEREXPOSURE.'otenllal local deemed appropriate. and systemic effects due to sinttle or shor l term overexposure to the eyes andPskln or through in.

Exposure recommendallons are for components, OSHA haiallon or ingestlon-Permissible Exposure Limits {PELs) and American Con.

ence of Governmentfi) Industrial Hyglenists (ACGIH} EFFECTS Or CHRONIC OVEREXPOSURE! Potential 4 reshold Limit Vaiues tTLVs} appear on the line with the component IdentifIcation. Other recommendatlons ocal and system}c effects due to repeated or long erm overexposure to the eyes and akin or through appear as footnotes. nhslatlon or Ingestion.

FIRST AID: Procedures to be followed when dealing with sacldantal oVerexposure.

PRIMARY ROUTE OF ENTRY.'ased on properties and 8OIUNC PONT, Of product if known. The lowest expecte¹ use.

value ol the components ls listed for mixtures.

PRESSUREI Of product If known. The highest 'APOR value of the components ls listed for mixtures.

SPECIFIC VAPOR DENSITY; Compernd to AIR ~ f. If HAZARDOUS POLYMERIZATIONt Conditions to avoid Specific Vapor Density of product is not known. the to prevent hazardous polymerization resulting in value Is expressed as lighter or heavier than air. a large release of energy SPECIRC ORAVITY: Compared to WATER ~ f. If STASILITY: Conditions to avoid lo prevent hazardous Specific Gravity ot product ls nol known. the value or violent decomposition.

is expressed as less than or greater than water, INCDMPATISILITY: Materials and conditions to avoid pH. If applicable, to prevent hazardous reactions, PERDENT voLATILEst Percentage of malarial with Ini-boiling point below 426 degrees Fahrenheit.

~

'ial S

EVAPORATION RATit IntNcated as faster or Slower Reasonabte pr to be taken and methods of than ETHYl. ETHER, uniess otherwise stated. oontalnmenL <<nd dfsposat, Consult federal, state and loca! regutatlons lor accepted procedures and any reporttna or rotiftoatke rettulrements.

FLASH POINTt Methotf Identifietf, EXPLONOX LIMITS'or product If known. The lowest value of the corn ponen! s is titted for mixtures. ~ Protect}ve equipment wh)ch may be needed when han.

diing the product>

HAZARDOUS DECONIPOSITION PftODUCTS.'nown or expected hazardous products resWtlng from heat. %EQRSU8 Ing, burning or other reactions, Covers any relevant points not previously mentioned.

ADDITIONALCOMMENTS containers should be either reconditloned by cERTIFIED firms or properly disposed of by AppRovED tIrmL Dtsposat of containers should be In accordance with applicable laws end reoutations, 'EMPTY'rums shoulci not aeglven to indi ~

vldualL Serious accidents have resulted from the misuse of 'EMPTIED containers (drums, pails, etc.}. ~ear to Sect-ions IV end l)4

P ~ L A

ML18026A241

Text

SUBJECT:

Dear Hr. Swerdon:

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