Text

Requests Approval for Replacement of Several Water Conditioning Chemicals Used at Facility W/Equivalent or Similar Chemicals.List of Equivalent Water Conditioning Chemicals Encl
	ML18026A241
Person / Time
Site:	Susquehanna
Issue date:	09/30/1991
From:	Fields J; PENNSYLVANIA POWER & LIGHT CO.
To:	Swerdon P; PENNSYLVANIA, COMMONWEALTH OF
References
	PLE-14736, NUDOCS 9110080317
	Download: ML18026A241 (100)
	v • d • e

,'CC~ELERATED DI BUTION DEMONS TION SYSTEM REGULATORY INFORMATION DISTRIBUTION SYSTEM (RIDS)

ACCESSXON NBR:9110080317 DOC.DATE: 91/09/30 NOTARIZED: NO FACIL:50-387 Susquehanna Steam Electric Station, Unit 1, Pennsylva 50-388 Susquehanna Steam Electric Station, Unit 2, Pennsylva AUTH.NAME AUTHOR AFFILIATION FIELDS,J.S.

Pennsylvania Power

& Light Co.

RECIP.NAME RECIPIENT AFFXLIATION SWERDON,P.M.

Pennsylvania, Commonwealth of DOCKET 05000387 05000388 R

D

SUBJECT:

Requests approval for replacement of several water conditioning chemicals used at facility w/equivalent or similar chemicals. List of equivalent water conditioning chemicals encl.

S DISTRIBUTION CODE:

C001D COPIES RECEIVED:LTR ENCL SIZE:

TITLE: Licensing Submittal: Environmental Rept Amdt

& Related Correspondence

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TOTAL NUMBER OF COPIES REQUIRED:

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Pennsylvania Power &, Light Company Two North Ninth Street~Allentown, PA 18101-1179 ~ 215/774-5151 September 30, 1991 Hr. Paul H. Swerdon Chief, Facilities and Construction Grants Section Water Quality Management Pennsylvania Department of Environmental Resources 90 E. Union Street, 2nd Floor Wilkes-Barre, PA 18701-3296 SUSQUEHANNA STEAN ELECTRIC STATION NPDES PERHIT NO.

PA 0047325 REQUEST FOR APPROVAL OF EQUIVALENT WATER CONDITIONING CHEMICALS CCN 741326 FILE R9-8A PL E-14736

Dear Hr. Swerdon:

The Pennsylvania Power and Light Company (PP&L) requests approval for the replacement of several water conditioning chemicals used at the Susquehanna

'Steam Electric Station (SES) with equivalent or similar chemicals.

Chemicals currently approved for use by the Pennsylvania Department of Environmental Resources (PaDER) are listed in Part C of NPDES permit no.

PA 0047325.

Specific chemicals, use rates, concentrations, and product facts are listed in Section VI of the June 23,

1989, NPDES permit application.

Selection of new water conditioning chemicals is a result of corporate requirements for rebidding of major contracts along with the effort to select the best chemicals available to minimize pipe corrosion,

scaling, and settling of river solids in the cooling system.

Testing of these chemicals began in June 1991 and will be completed in October 1991.

A letter was sent to Hr.

Stanley J.

Lehman. of your office (PLE-14354, June 7,

1991) discussing the testing. strategy for these chemicals.

PP&L plans to select the successful bidder by mid-November and begin using the chemicals by the end of 1991.

As we discussed at our August 26, 1991 meeting, it was unclear if an amendment to the NPDES permit was required for use of these equivalent water conditioning chemicals.

Certain corrosion inhibitors discussed at this meeting were included in the analytical data provided in Section V of the permit application and need not require additional approvals.

For example, zinc-sulfate, a carbon steel corrosion inhibitor, has already been approved in this manner.

Other water conditioning chemicals not specifically included in Section V sampling data were previously included in Section VI of the original application.

In telephone conversations with you and Hr. Stuart Gansell, Acting Chief, Division of Permits and Compliance, PaDER Harrisburg office on September 3,

1991, the question of whether or not an amendment is necessary every time an equivalent water conditioning chemical is to be used was addressed.

Since QQQQB 1 7 p5ppp387

--- --9j.p93Q PDP AOOCK p

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September 30, 1991 CCN 741326 PLE-14736 FILE R9-8A PP&L will continue to use chemicals with the same main chemical constituents to be discharged to permitted NPDES outfalls, in essence there is no change to the PaDER approved water conditioning chemicals listed in permit number PA 0047325.

The only changes would be in manufact'urer and trade names.

Based on our meeting and subsequent telephone conversations, PP&L is submitting a list of equivalent water conditioning chemicals following permit application Section VI format for your review and approval.

Also, attached are Haterial Safety Data Sheets for these equivalent chemicals.

If you have any questions or comments, please call me at (215) 774-7889.

Sincerely, Jer me S. Fields Sr. Environmental Scientist-Nuclear js f/1ti918c(25) cc:

S,Gansell-

PaDER, Harrisburg PRC Document Control Desk NRC Region I Hr. J. J. Raleigh, NRC Project Hanager

ER-BWG-288.

{Rev. 12/82) i

..9110080317 NPDES Number PA Vl. INFORMATIONAND ANALYSISOF EFFLUENT QUALITYFOR OTHER POTENTIALLYTOXIC POLLUTANTS KNOWN OR EXPECTED TO BE PRESENT IN THE DISCHARGE IRead instructions carefully and use the tabular format and additional pages, where necessary, to present the required information) 0047325 Outfall Chemical Substance or Compound Reason for Presence in Discharge Average Effluent Concentration Iugf))

Analytical Detection Level Iugn)

APPROVED 071 Betz Powerline 3451 Blend of the copolymer in Betz Powerline 3450 and a scale inhibitor phosphonic acid, (1-hydroxyethylidene), Bis-. The phosphonic acid is also known as HEDP.

EQUIVALENTCHEMICALS This product is used as an alternate calcium carbonate scale inhibitor and cooling water dispersant.

500 to 1500 ug/I as

HEDP, 7000 to 20,000 ug/I As product 200 ug/I as HEDP using field test 071 071 071

.071 Calgon QCL-2000 (1-Hydroxyethylidene) Bisphosphonic Acid Cas ¹2809-21-4 Drew WRICO CTP 888 (1-Hydroxyethylidene) Bisphosphonic Acid Cas ¹2809-21-4 Betz PPL09 (1-Hydroxyethylidene) Bisphosphonic Acid Cas ¹2809-21-4 Nalco DYNACOOL 1383 Potassium Phosphonate and Polyacrylates This product will be used as a calcium carbonate scale inhibitor.

This product will be used as a calcium carbonate scale inhibitor.

1000 ug/I as HEDP, 8500 ug/I as product I

1000 ug/I as HEDP, 8300 ug/I as product 1000 ug/I as HEDP, 3200 ug/I as product 600 ug/I as HEDP, 600 ug/I as polymer, 6000 ug/I as product 200 ug/I as HEDP using field test 200 ug/I as HEDP using field test 200 ug/I as HEDP using field test 200 ug/I as HEDP using field test NOTE:

PaDER Form ER-BWG-288.10 (Rev. 12/82) was reproduced for this report.

ER-BWG-288.10 (Rev. 12/82)

NPDES Number PA 0047325 Vl. INFORMATIONAND ANALYSIS OF EFFLUENT QUALITYFOR OTHER POTENTIALLYTOXIC POLLUTANTS KNOWN OR EXPECTED TO BE PRESENT IN THE DISCHARGE (Read instructions carefully and use the tabular format and additional pages, where necessary, to present the required information)

Outfall Chemical Substance or Compound Reason for Presence In Discharge Average Effluent Concentration Iugn)

Analytical Detection Level Iugnl APPROVED 071 Betz Powerline PPL-04 Benzotriazole, Methyl, Sodium salt.

Also known as TTA (tolytriazole)

This product is used as a copper and copper alloy corrosion inhibitor 1200 to 2500 ug/I as TTA, 2800 to 5800 ug/I as product 200 ug/I as TTA using field test EQUIVALENTCHEMICALS 071 071 071 Calgon Triazole PCL-50 Sodium tolytriazole Cas ¹64665-57-2 Drew WPD11-166 Sodium tolytriazole Cas ¹64665-57-2 Nalco 1326 Sodium tolytriazole Cas ¹64665-57-2 This product is used as a copper and copper alloy corrosion inhibitor.

This product is used as a copper and, copper alloy corrosion inhibitor.

This product is used as a copper and copper alloy corrosion inhibitor.

1000-1200 ug/I as

TTA, 2600 ug/I as product.

1000-1500 ug/I as

TTA, 2300 ug/I-3500 ug/I as product 1000-1200 ug/I as

TTA, 2500 ug/I as product 200 ug/I as TIA using field test 200 ug/I as TTA using field test 200 ug/I as TIA using field test

ER-BWG-2 0 IRev. 12/82)

NPDES Number PA<<0047325 VI. INFORIVIATIONAND ANALYSISOF EFFLUENT QUALITYFOR OTHER POTENTIALLYTOXIC POLLUTANTS KNOWN OR EXPECTED TO BE PRESENT IN THE DISCHARGE IRead instructions carefully and use the tabular format and additional pages, where necessary, to present the required information)

Outfall Chemical Substance or Compound Reason for Presence ln Discharge Average Effluent Concentration lugni Analytical Detection Level Iugni 071 071 071 071 071 071 APPROVED Betz Powerline 3450 Copolymer of 2-propenoic acid and 1,2-propanediol mono 2-proenoate and water EQUIVALENTCHEMICALS Betz PPL08 Polymer Calgon PCL-401 Polymer Nalco 8356D Dispersant Acrylate Polymer Cas ¹7631-90-5 Drew WPD 11-136 Antiscalant Sodium Polyacrylate Cas ¹9003-04-7 J-POLY 101 C Sodium Polyacrylate Cas ¹9003-04-7 This product is used as a cooling water dispersant for the maintenance of clean heat transfer surfaces.

This pioduct is used to facilitate silt, sediment, iron and magnesium dispersion.

This product is used to facilitate silt, sediment, iron, and magnesium dispersion.

This product is used to facilitate silt, sediment, iron and magnesium dispersion.

1250-5000 ug/I as

polymer, 7000 to 20,000 ug/I as product 2200-3000 ug/I as

polymer, 7300-10,000 ug/I as product 2000-2500 ug/I as

polymer, 8000 ug/I as product 3400 ug/I as

polymer, 10000 ug/I as product 2000 ug/I as

polymer, 5600 ug/I as product 500-1000 ug/I as

polymer, 1000-2000 ug/I as product 1250 ug/I as polymer 1750 ug/I as polymer 1750 ug/I as polymer 1750 ug/I as polymer 1750 ug/I as polymer 200 ug/I as polymer

ER-BWG-288.10 (Rev. 12/82)

NPDES Number PA 0047325 VI. INFORMATIONAND ANALYSIS OF EFFLUENT QUALITYFOR OTHER POTENTIALLYTOXIC POLLUTANTS KNOWN OR EXPECTED TO BE PRESENT IN THE DISCHARGE 4

(Read instructions carefully and use the tabular format and additional pages, where necessary, to present the required information)

Outfall Chemical Substance or Compound Reason for Presence in Discharge Average Effluent Concentration Iugiil Analytical Detection Level (ugll) 071 APPROVED Betz Clam-Trol CT 1 Alkyldimethyl benzylammonium chloride Cas ¹68424-85-1 Isopropyl Alcohol Cas ¹67-63-0 Dodecylguanide Hydrochloride Cas ¹13590-97-1 Ethyl Alcohol Cas ¹64-17-5 EQUIVALENTCHEMICALS Molluscide used for Asiatic Clam control and as a cooling tower biocide.

<200 ug/I as

biocide, 10,000-50,000 ug/I as product 200 ug/I as biocide using field test 071 071 Calgon H-130 Microbiocide Didecyl Dimenthyl Ammonium Chloride Cas ¹7173-51-5 Ethyl Alcohol Cas ¹64-1 7-5 Drew Biospherse 3204 Quartenary Ammonium Compd Polyethoxylate Molluscide used for Asiatic Clam control and as a cooling tower biocide.

Molluscide used for Asiatic Clam control and as a cooling tower biocide

<200 ug/I as

biocide, 2500 ug/I as product

<200 ug/I as

biocide, 8000-80,000 ug/I as product 200 ug/I as biocide using field test 200 ug/I as biocide using field test

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- ---SECTION 5- --

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REMOVE CONTAMINATED CLOTHINQ.WASH EXPOSED AREA 'WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MINUTES EYE CONTACT*+*

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PC%KG INE 3i51 EFFEQ'ZVE DATE 10-31-88 SECTION 7-SPECIAL PROTECTIVE EQUIPMENT -----

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MANUFACTURER'S NAME ADDRESS Calgon Corporation EMERGENCY TELEPHONE NO.

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Chemical 1-HydrOXyethylidene-1,1 ~

Di hos honic Acid HEDP Common Name.

Chemical Name Common Name Chemical Name Cor'nrnon Name Chemical Name Common Name Chemical Name Common Name CAS 2809-214 So BY WEIGHT ORAL LDso 2400 mg/kg DERMALLDs e

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PERCENT VOLATILE BY VOLUME (%)

PH OTHER 1.062 - 1.072 1.10 N/A APPEARANCE ANO ODOR Clear pale yellow liquid N/A Not applicable While this information and recommendations set forth herein are believed to be accurate as of the date hereof, CALGON CORPORATION MAKESNO WARRANTYWITHRESPECTHERETO AND DISCLAIMSALLLIABILITYFROM RELIANCE THEREON.

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b. IRRITATION This product is not expected to causa irritation to the skin.

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B.

SKIN Not Applicable.

C.

INGESTION Not Applicable.

D.

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Remove any remaining material by absorbing on vermiculite or other suitable absorbing material and place in a sealed container for disposal.

WASTE DISPOSAL METHOD Dispose in accordance with local, state and federal regulations.

PROTECTIVE GLOVES Not required EYE PROTECTION Chemical splash goggles

. rIER PROTECTIVE CLOTHING RESPIRATORY PROTECTION Not required VENTILATION STORAGE 5 HANDLING LOCALEXHAUSTNot required MECHANICAL (General)

Not required OTHER N/A WARNINGl May cause eye irritation.

Avoid contact with eyes.

Wear chemical splash goggles when handling.

Wash thoroughly after handling.

Keep container closed when not in use.

OTHER PRECAUTIONS None N/A ~ Not applicable Page 4 ot 4 PREPARED BY Brian T. Laplante iMP-0514 3/B/Bg

AI'R-89-1991 87: 48 FROM MATERIAlSAFETY OATA SHEET DREW BOONTON SALES ADMIN.

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PIsone (201) 263"7600/TeIex 136444 I (800) 274 $ 263 or 1(800)

ASHLAND WRICO CTP 888 CORROSION INHIBITOR CONTAMINATED CLOIHIHG. LAUNDER CONTAMINATED CLOTHIHG BEFORE RE%SR.

RECEIVE CONTAMINATED $?OES PACNWrTLY. DISCARD 9%ES SATURATED WITH 'IHIS PRODUCT.

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GIVE MILK OF IAGNESIA.

KEEP WARN. (<<VIET~

GET IKOICAL ATTENTION IIHCDIATELY.

IF BREATl+Ds IF AFFECTED REMOVE IIOIVIDUALTQ FRESH.AIR. IF BREA'l?IING IS DIFFICULT, ACNINISTER OXYGEN. IF BREAT?IING HAS STQPP00.

GIVE ARTIFICIALRESPIRATIO¹ KEEP PERSON WARM<<QUIETs AHO GET AE<<OICAL ATTEHTIOH.

PAWLRY ROUTE(S)

OF EHTRYs IttIALATICH, SKIN COHTACT Page:

2 EFFECTS OF CHROIC OVEREXPOSUREs OVEREXPQSURF. TQ THIS MATERIAL (OR ITS CCMPONENTS) HAS APPARENTLY BEEN FOUND TO CAUSE THE FOLLOWING EFFECTS IH LABORATORY AHIMlLSs ~

BLOOD ABNORMALITIES HAZAAOQVS POLYMERIZATION?

CANNOT OCCVR STABII.ITYs STABLE IN~ATIBILITYs AVOiD CONTACT WITH:. STRONG ALKALIES.~

STROHG OXIDIZIHG AGEHTS.

~oS TO SR TAKEN Ik CASE MATERIAL IS RELEASED OR SPII.LEDs t

M SPILLs COVER Tl% CONTAMINATED SURPACE Wl's?I SODIUM BICARB(%ATE OR A SODA ASH/SLAKED LIME MIXIUAE <50"50) ~

MIX AND ADD WATER IF NECESSARY TO FORM A SLURRY.

SCOOP UP SLURRY AHD lEASH $ 1TE WITH SODA ASH SOLOTION.

LARGE SPILLs PERSONS HOT WEARING PROTECTIVE EQUIPNEHT SICVLD BE EXCLUDED FACM AREA OF SPiLL.

$1OP SPILL AT RESIDUES FOR DISPOSAL.

SOURCE. DIKE TQ PREVENT SPREADING.

CAREFULLY ADD LIME OR SODIW CARBONATE TO NEUTRALIZE ACID. CONTAINERIZE WASTE DISPOSAI. MRT?CDs SMlLL SPILLs DISPOSE QF IH ACCORDANCE WITH ALL LOCAL~ STATE Ate FEDERAL REGULATIQHS.

LARGE SPILLs DISPOSE OF IN ACCOIDAHCR WITH ALL LOCAL, STATE AHD FEOERAI. REGULATIONS.

RESPIRATORY PROTECTIOHs IF WORKPLACE EXPOSVAE LIMIT(S) OF PRODUCT OR ANY CO6@HENT IS EXCEEDED (SEE SE~'ll),

A HIOSH/MSHA APPAOVEO AlR SUPPLIED RESPlRATOR IS ADVISED IH ABSENCE OF PROPER ENVIR(Ã44ENTAL CONTROL OSHl REGULATIOHS ALSO PERMIT CARR NIOQVICiHk RESPiRATORS EGATIVE PRESSURE TYPE) UNDER SPECIFIED CONDITIONS SEE YQVR SAFETY EGUIPIRNT SUPPLIER) ~ ENGINEERING CR IHISTRATIVE CQITROLS g%ULO BE IIBsLEhKHTED TQ EDUCE EXPOSURE.

VENTILATIONs PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHlVST) VENTILATION.TQ.MAINTAINEXPOSVRE BELOW LEVEL OF OVEAEXPOSVAC.<<(HKN<<IQCfS=SUSPECTED OR'APPARENT"ADVERSE~ EFFECTS)') '

<<- =

's PROTECTIVE GLOVE$s WEAR RESISTANT GLOVES SUCH AS:.

NEOPRENE EYE PROTECTIOHs 0%MlCAI SPLASH G(XIGLES AHD FACE SHIELD (8'IH.) IH COIPLIAHCE WITH OSHA REGULATIONS ARE ADVISEDS fOWEVER<<OSHA REGULATIONS ALSO PERMIT OT?KR TYPE SAFETY GLASSES<<(CONSULT YOVR SAFETY EOIIPMEHT SVPPLid)

OPER PROTECTIVE EQUIPIHtTs -TQ PREVENT SKiN CONTACT, WEAR IlesRRVIOUS CLOT?IING AMt B(OT$,

~ '

CQHTA/HERS OF ~S MLTERIAL MAY BE HAZARDOUS %%N EtisTIED.SINCE EMPTIED CKI'AIHERS RETAIH PRODUCT RESIDUES (VAPOR, LIQUID<<AND/OR SOLID) ~ ALL HhZARD PRECAUTIONS GIVEN IN T3% DATA 9%ET MUST BE OBSERVED, Tl% INFORILlTIOH ACCUCIIATED I%REIN IS BELIEVED TO BE ACCURATE BUT IS HOT WARRANTED TO BE seIH?Kit ORIGINATING WITH TlC C(MSPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED lHAT T?IE INFORMATION IS CURRENT, APPLICABLE, AIO SUITABLE TO Tt%IR CIRCLAsISTANCES.

~'f<<,,>

<<s ~

<<7>>

~

,"V;

VALLEY FORGE MATERIALSAFETY DATA SHEET Drew (ndustrial Division ccHtLAlso ctttlcICJL WC.

One Grew Plaza, 8oonton, New Jersey 07005 Phone (201) 283-7800/Tetocc 136444 APR-O9-1991 G7:48 FROM DREW BOONTON SALES ADMIN.

TO PA P.23 24-HOUR Emergency Tolophono 1(800) 274-5263 Oz i (800)

ASHLAND 008372 NRICO CTP ees CORROSION INHIBITOR THIS MSDS CCMPLIES WITH 29 CFR IQI0.1200 (THE HIZARD CCeljtINICATICN STANDARD)

Page:

> ~ etcoeslcIIO Jcc ~cIoceccoet ~000Itcc ~ecol ~I~00eci ~ c ~cecoEccctccccclccccc00ccI

~I~ eo ~oocccoocciio ~I~ 00 ~ 00 ~oeiecsgyc ProcccCt Names WRICO CIP 888 CORROSICN INHIBITOR OLIN WATER SERVICES DIVISION DREW IHDUSTRIAt. DIVISION ONE DREW PLAZA 8OONTDH 07005 DISTIIICT MIHAGER 00 10 988 PRODUCT c 8200008 IIAO CEc IHVO CE DATE TOs OLIN WATER SERVICES DIVISION DREW INDUSTRIAL DIVISION BOQNTON Data Sheet Hot 0218590-002 Preparectc 06/05/90 Ger eoecec 08/18/88 General or Genertc IDc CORROSION IteIIBITOR OOT Hazard Ctaestftcatfonc CORROSIVE MATERIA!. (173.240) c c

~

IHGREOI EHT

( I~XYETIIYLIDEHE)BISAOSPICNIC ACID CAS P! 2809 2I~A IF PRESENT IARC, HTP AHD OSHA CARCIHOGENS AHD 0%MICALS SUBJECT TO 15% REPORT ING REQUIREMENTS OP SARA TITLE 111 SECTION 313 ARE IDENTIFIED IH THIS SECTION.

SEE DEFINITION PAGE FOR CLARIFICATION It (by WT)

PEL TI.V 10"2$

Note' 1)

Notoa

( 1) PEL/TLV NOT ESTABLISH FOR THIS MATERIAL Botttno Potnt Vapor Pressure for CCMPONEHT(

85" 100%)

fOr CCeecOHENT(

85-10010 212.00 Deg P

100.00 Dey C) 760.00 nm Hy e

Q:PD R,0

(

20.00 Deo C)

Spectf tc Vapor Oenstty HOT APPLICABLE Spectflc Grovtty Percent Vo Iat 1 leo E>>raporatton Rate Ptl Appearance State 1,071 B

77.00 Dent F

(

25.00 0'eo C) 85-100%

SLDWet 17tAN Ktt%R 1.0 -

2.0 CLEAR, COLORLESS LIOIID FLASH POINT HOT APPLICABLK r

EXPLOSIVE LIMIT HOT APPLICABLE EXTIt4ÃIISHIHGMEDIAc CARSON DIOXIDE OR DRY Cte9lICAL HAZARDOUS DECCaecOSITII& PROOUCTSc MAY FORM TOXIC IQTERIALSc ~ PHISPHIHE>> CARPI DIOXIDE AHO CARBON lDIOXIDE>>

NITROGEN CCMPIXINDS, ACID VAPORS FIREFIGHTIHG PROCKDURESc WEAR SELF~AIHED BREATHING APPARATUS WITH A FULL FACKPIECK OPERATED IN Tl% POSITIVE PRESSURE DEMAIID MQOK AND PULt BODY PROTECTION IeetN FIGHTIHQ FIRES>>

WATER OR FOAM MAY CAUSE FR(flHIHQ teIIOI CAN BK VIOLENT AHD POSSIBLY EICANGER 'P% LIFE OP IHE FIREFIGHTER>>

ESPECIALLY IF SPRAYED INTA CONTAINERS OF l%T>> BURHIHG LIQUID~

WATER Iety BE USED TO KEEP PIRE EXPOSED CONTAINERS COOL UNTIL FIRE IS OUT.

PERMISSIBLE EXPOSURE LEVELc NOT ESTABLISH FOR PRODUCT SEK SECTION II~

EFFECTS OP ACLflla DYEREXPOSUREs EYES ~ CAUSES BURHS SKiN - CAUSES BURtcs.

BREATHING MIST CAH CAUSE DAMAGE TO NASAL Ate RESPIRATORY PASSAGES SccALLCcclNG CAN RESULT IN DAMAGE TQ TtecOAT AHD KSOPHIGUS FIRST AIDc IF ON SKIHs IIOKOIATELYFLUSH EXPOSED AREA WITH WATER FOR AT LEAST 18 MINUTES>> GET IKDICALATIENTION~ REMOVE COPYRIGHT 1990 CONTINUED ON PAGE:

2

\\

BETZ IABORATORIES,INC.

4636 SOMERTON ROADS TREVOSEi PA.

19053 BETZ MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE (HEALTH/ACCIDENT) 800 877-1940 (PAGE 1 OF 3)

EFFECTIVE DATE 05 16-91 PRINTED:

3-Jun-1991 REVISIONS TO SECTIONS'g4J7~APP/9/EDe5(8 PRODUCT APPLICATION :

WATER-BASED DEPOSIT CONTROL AGENT.

--SECTION 1----

HAZARDOUS INGREDIENTS INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD IS LISTED'EFER TO SECTION 4

(PAGE 2)

FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHRONIC HAZARDS OF THIS FORMULATION+

PHOSPHONIC ACID~ ( 1 HYDROXYETHYLZDINE)BXS (HEDP) +**CAS)2809 2 1 4 p EYE IRRITANTg PEL NONE jTLV NONE ~

---SECTION 2---- - -.TYPXCAL PHYSZCAL DATA -., -.-

0

~

PH!

AS ZS (APPROX.,)

2s0 ODORS SLIGHT FL.PT. (DEG.F)! >200 P-M(CC)

SP.GR. (70F) OR DENSITY: 1.219 VAPOR PRESSURE (ItCnHG) 18 VAPOR DENSITY(AIR~1): <1 VXSC cps70F:

19

%SOLUBILITY(WATER): 100 EVAP.RATE: ND'ATER~1 APPEARANCES COLORLESS PHYSICAL STATE!

XIIQUXD FREEZE,APPOINT(DEG.F),$ '20

~ ) I 1

~ '<

~

SECTION 3-----

REACTIVITY DATA---

STABLE.MAY REACT WITH STRONG OXXDXZERS.DO NOT CONTAMINATEoBETZ TANK CLEAN"OUT CATEGORY 'Bi THERMAL DECOMPOSITION (DESTRUCTIVE FIRES)

YIELDS ELEMENTAL OXIDES'

BETS MATERIAL SAFETY DATA SHEET (PAGE 2

OF 3)

PRODUCT POWERLINE PPL09

SECTION 4 HEALTH HAZARD EFFECTS

'SCUTE SKIN EFFECTS

+++ PRIMARY ROUTE OF EXPOSURE MODERATELY IRRITATING TO THE SKIN ACUTE EYE EFFECTS ***

SEVERE IRRXTANT TO THE EYES ACUTE RESPIRATORY EFFECTS >**

MISTS/AEROSOLS MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT CHRONIC RFFECTS OF OVEREXPOSURE***

NO EVIDENCE OF POTENTIAL CHRONIC EFFECTS'EDICAL CONDITIONS AGGRAVATED ***

NOT KNOWN SYMPTOMS OF EXPOSURE ***

MAY CAUSE REDNESS OR ITCHING OF SKXN,IRRITATION AND/OR TEARXNG OF EYES(DIRECT CONTACT).

-SECTXON 5

-F1RST AID XNSTRUCTZONS---------

SKIN CONTACT***

REMOVE CONTAMINATED CLOTHING.WASH EXPOSED AREA WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MXNUTES EYE CONTACT++*

IMMEDXATELY FLUSH EYES WITH WATER FOR 15 MXNUTES ~ IMMEDIATELYCONTACT A PHYSICIAN FOR ADDITIONALTREATMENT vlQ INHALATZON EXPOSURE+**

REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIRoAPPLY APPROPRIATE FIRST AXD TREATMENT AS NECESSARY INGESTION><+

DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DILUTE CONTENTS OF STOMACH. INDUCE VOMXTING BY ONE OF THE STANDARD METHODS ZMMEDXATELY CONTACT A PHYSXCXAN

SECTION 6

--SPILL(DISPOSAL'ND FIRE INSTRUCTXONS-SPILL XNSTRUCTIONS***

VENTILATE AREA USE SPECIFIED PROTECTIVE EQUIPMENT CONTAIN AND ABSORB ON ABSORBENT MATERIAL+PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED 'ATERIAL(OR ANY CONTAMINATED SOIL(

SHOULD BE DETERMINED XN ACCORDANCE'ITH RCRA REGULATIONS'LUSH AREA WITH WATER+'WET AREA MAY BE SLIPPERY'PREAD SAND/GRIT.

DISPOSAL XNSTRUCTIONS***

WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANXTARY SEWER TREATMENT FACILITY,IN ACCORDANCE WXTH ANY LOCAL AGREEMENT(A PERMITTED WASTE TREATMENT FACILITY OR DXSCHARGED UNDER A NPDES PERMZT PRODUCT(AS IS)-

XNCINERATE OR BURY IN APPROVED LANDFILL PIRE EXTXNGUISHING INSTRUCTIONS***

FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAXNED BREATHING APPARATUS(FULL FACE PIECE TYPE)

IMPROPER FIRE EXTXNGUXSHING MEDIA:

FOAM OR WATER CREATE A SLIPPERY CONDITION SPREAD SAND OR GRIT.

C,<

Cp LI

BETZ MATERIAL SAFETY DATA SHEET (PAGE 3

OF 3)

PRODUCT POWERLXNE PPL09 SECTION 7----

~

SPECIAL PROTECTIVE EQUIPMENT USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134.

USE

'SPIRATORS WITHIN USE hlMlTATIONS OR ELSE USE SUPPLIED AXR RESPIRATORS

~

VENTILATION PROTECTION***.

ADEQUATE VENTZLATION RECOMMENDED RESPXRATORY PROTECTION***

IF VENTILATION IS INADEQUATE OR SXGNIFXCANT PRODUCT EXPOSURE XS LXKELY, USE A RESPIRATOR WITH DUST/MIST FILTERS.

RECOMMENDED SKIN PROTECTION***

RUBBER GLOVES WASH OFF AFTER EACH USE.REPLACE AS NECESSARY RECOMMENDED EYE PROTECTION***

SPLASH PROOF CHEMICAL GOGGLES

SECTION 8---------STORAGE AND HANDLING PRECAUTZONS-STORAGE INSTRUCTIONS**k KEEP DRUMS

& PAILS CLOSED WHEN NOT IN USERS REASONABLE AND SAFE CHEMICAL STORAGE HANDLING INSTRUCTIONS***

ACIDIC,DO NOT MIX WITH ALKALINEMATERZAL.

- - - - k*************kkkkkk***kk*************kkkk*****kk*******k***

THIS MSDS WAS WRITTEN TO COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD

- - - k******kkk***k*********k*k*****kkkkk**k****k********k***k*k*

APPENDIX: REGULATORY INFORMATION THE CONTENT OF THXS APPENDIX REPRESENTS INFORMATION KNOWÃ TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS ~ THIS INFORMATION IS BELIEVED TO BE ACCURATE>

ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT.

..TSCA:

ALL COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY

..REPORTABLE QUANTXTY(RQ} FOR UNDILUTED PRODUCT:

NOT APPLICABLE

~.RCRA!

ZF THIS PRODUCT IS DISCARDED AS A WASTEqTHE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS!

D002~CORROSZVE(PH)

~ +DOT HAZARD/UN//ER GUIDE/ IS:

NOT APPLICABLE

...CALIFORNIA SAFE DRINKING WATER ACT (PROPOSITION 65)

MATERIALS! NONE

.eoSARA SECTION 302 CHEMICALS! NONE

...SARA SECTION 313 CHEMXCALS: NONE

,SARA SECTION 312 HAZARD CLASS:

IMMEDIATE(ACUTE} AND DELAYED(CHRONIC}

...MICHIGAN CRXTXCAL MATERIALS! NONE NFPA/HMIS :

HEALTH 2

FIRE -'

j REACTIVXTY - 0 i SPECIAL - ACXD t PE -

B

p

'I

MATERIALSAFETY DATA SHEET NALCO PRODUCT DYNACOOL 1383 SCALE INHIBIT)

Emergency Telephone Number Medical P08) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 1

PRODUCT IDENTIFICATION TRADE NAME:

DYNACXGL 1383 SCALE INHIBZIOR DESCRIPZlON:

An aqueous solution of potassium phosphonate and polyacrylates OVd: /

/'=Insignificant lWlight 2~crate 3=High 4=EMmte SECTION 2

HAZARDOUS INGREDIENTS Our hazard eva1uation of the ingredient(s) under OSHA.'s Hazard Communication

Rule, 29 CFR 1910.1200 has found none of the ingredient(s) hazardous.

SECTION 3

PRECAUTIONARY LABEL INFORMATION CM3TION:

May cause irritation to skin-and eyes.

Avoid contact with skin, eyes and clothing.

Do not take internally.

EInpty containers may contain residual product.

Do nat reuse container unless pro)arly reconditioned.

SECTION 4 FIRST AID INFORMATION EYES:

SKIN:

INGESTION'NHAIATION:

Flush with water for 15 minutes.

Call a physician.

Wash thoroughly with soap and rinse with water.

Ca11 a physician.

Do not induce vomiting.

Give water.

Call a physician.

Reniave to fresh air.

Treat synIptanis.

Ca11 a physician.

NAZE 'IO PHYSICIAN:

No specific antidote is known.

~ Based on the, individual reactions of the patient, the physician s judgment should be used to control syniptains and clini.cal corxKtion.

CAVZION: If unconscious, having trouble breathing or in corrvulsions, do nat induce vamiting or give water.

SECTION 5 HEALTH EFFECTS INFORMATION...

PRIH76K ELVIS(S) OF ZZR3SURE:

Eye, Skin EYE CONZACI" SKIN CONTACT'an cause transient irritation.

May cause irritation with prolonged contact.

I SYMPICMS OF EXPOSURE:

A review of available data does nat identify any synIptanIs fram exposure.

PAGE 1 OF 7

NALCO CHEMICAL COMPANY QNE NALCQ CENTER

~ NAPERVILLE. ILLINOIS 60563-1 196 AREA708-305-1 OOO

MATERlALSAFETY DATA SHEET NALCO PROOUCT DYNACCOL 1383 SCALE INHZBZTO Emergency Telephone Number Medical (708) 920.1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 5 HEALTH EFFECTS INFORMATION

(

CONTINUED )

AGGRAVATION OF E)(ISTING CONDITIONS:

A review of available data does nat identify any worsening of existing conditions.

SECTION 6 TOXICOLOGY INZORMATION ACVZE IOXICZTY 8IUDIES:

No taxicity stixU.es have been conctucted on this product.

SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES CDZQR:

Clear SOIIJBILZTY IN NAT1%'PECIFIC GRAVITY:

pH (NFAT) =

FEKZ2Z POINT'LASH POINT:

FORM:

Liquid Completely 1.17 6 68 Degrees F

3.6 - 4.5 25 Degrees F

None (BKC)

AKM D-1298 A%M E-70 ASIA D-1177 AKH~3 NOIR:

'Ihese physical properties are typical values for this product.

SECTION 8 FIRE AND EXPLOSION INFORMATION FIASH POINT:

None (PKCC)

AKH D-93 EXTINGUISHING MEDIA:

Not applicable UNUSUAL FIRE AND EZPIUKION HAZ2GK):

Nat applicable,.-.

SECTION 9 REACTIVITY INFORMATION.

INCCMPATZBIZZK: Avoid contact with strung acids (eg. sulfuric, phosphoric, nitric, hydrochloric, chramic, sulfonic) which can generate heat, splatter~

oz boiling and the release of taxic fumes.

'IHERMAL DEXXNKQSITZGN PROIXJCIS:

In the event of callibustion CD, CO2 may be formed.

Do not breathe smoke or fumes.

Wear suitable protective equipment.

SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRAZORY PROTECTION:

Respiratory protection is nat normally needed.

For large spills, entry into lazge tan)cs, vessels or enclosed small f1 PAGE 2 OF 7

NALCO CHEMICAI COMPANY ONE NALCO CENTER

~ NAPERVILLE. ILLINOIS 60663-1 196 AREA708-305-1 OOO

MATERIALSAFETY DATA SHEET NALCO PROD UCT DEGCCOL 1383 SCALE ZNHIBZIO Emergency Telephone Number Medical (705) 920-1 510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 10 PERSONAL PROTECTION EQUIPMENT VENTIIATXON: General ventilation is recommended.

(

CONTINUED

)

PMZECIIUE EQUXPMEHTI Use impexmeable gloves and chemical splash goggles (ANSI Z 87.1 requirements and selection of gloves, goggles,

shoes, etc.)

when attaching feeding equipment, doing maintenance or hardling product.

The availability of an eye wash fountain and safety shower is mcalimended.

If clothing is contzuninated, remove clothing and thoroughly wash the affect~ area.

Iaurxler contaminated clathing before reuse.

SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATION ACCID)WZS, CALL 'IHE FOLQNING 24-HOUR TZXZZSONE NUMHER (708-920-1510)

SPILL CONSOL AND RIXGVEK:

Snail liquid spills:

Contain with absorbent material, such as clay, soil or any commercially available absorbent.

Shovel reclaimed liquid and absorbent into recovery or salvage drulns for dispo.ml.

Refer to CERCIA in Section 14.

Large liquid spills: Dike to prevent further maveIIIent and reclaim into recovery or salvage drums or tank truck for disposal.

Refer to CERCIA in Section 14.

DISH%M'. Ifthis product bonnes a wa.M, it does nat meet the criteria of a hazardous waste as defined under the Rescue~

Conservation and Kxnmg Act (RCRA) 40 CFR 261, since it. does nat have the characteristics of Subp.~

C, (i.e.

D001 through D017) nor is it listed under Subpart D.

As a non-hazaxdaus liquid waste, it should be solidified with stabilizing agents (such as sand, fly ash, or.ceiIIent) so that no free liquid remains before disposal to an izxhlstrial waste landfill.

A non-hazardous liquid waste can also be deep-well injected in accordance with loca1, state and federal recpxlations.

SECTION 12 ENVIRONMENTAL INFORMATION AQUATIC DATA,I 96 hour0.00111 days 0.0267 hours 1.587302e-4 weeks 3.6528e-5 months static acute ZC50 to Rainbow Traut = Greater than 1,000 ppm 96 hour0.00111 days 0.0267 hours 1.587302e-4 weeks 3.6528e-5 months no observed effect concentration is 1,000 pgm based on no mortality PAGE 3 OF 7

NALCO CHEIVIICAI COMPANY ONE NALCO CENTER

~ NAPERVILLE, II LINQIS 60563-1 166 AREA708-305-1 Ooo

MATERlAl SAFETY DATA SHEET PRODUCT DYEACCOL 1383 SCALE ZBELBZIO NALCO Emergency Telephone Number Medical (708) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 12 ENVIRONMENTAL INFORMATION

(

CONTINUED

)

or abnormal effects.

96 hour0.00111 days 0.0267 hours 1.587302e-4 weeks 3.6528e-5 months static acute IC50 to Sheepshead Minnmr = Greater than 1,000 pgm 96 hour0.00111 days 0.0267 hours 1.587302e-4 weeks 3.6528e-5 months no observed effect concentration is 1,000 pgm based on no mortality or abnormal effects.

48 hour5.555556e-4 days 0.0133 hours 7.936508e-5 weeks 1.8264e-5 months static acute IC50 to Daphnia Magna = Greater than 1,000 pgm 48 hour5.555556e-4 days 0.0133 hours 7.936508e-5 weeks 1.8264e-5 months no observed effect concentration is 1,000 pgm based on no mortality or abnormal effects.

Xf released inta the enviranInent, see CEXKXA in Section 14.

SECTION 13 TRANSPORTATION XNFORMATION IXII'ROPER SHIPPING NAME/HAZARD (X)DE PROIXJCI'S NOZ REGUIAIKD IXJBING TRANSPOEKLTXON SECTION 14 REGULATORY INFORMATION

'Ihe folloving regulations apply to this prcduct.

FEDERAL REGULATIONSI OSHA HAZARD CCNMUNICATION RULE, 29 CFR 1910.1200:

Based on our hazard evaluatian, this product is nat hazardous.

CERCI~SUPEZKUND, 40 CFR 117, 302:

Notification of spills of this praI9uct is nat recphM.

S~SUPERFUND AMENEHENIS AND REAIJIRZKZATXONACT OF 1986 (TITIZIII)

SECTIONS 302 r 311i 312 AND 313 SECTION 302 - E)(TREMELY HAZARDOUS SUE83IRNCES (40 CFR 355):

'Ibis product does not contain incIredients listed in Appendix A and B as an ExtrenIely Hazardous Substance.

Our hazard evaluation has fcauxl that this product is nat hazardous under 29 CFR 1910.1200.

Under Section 311, suhmittal of MSD 's or a list of pmchmt nanes to the local eInergency planning commission, state ene~ency response camInission and local PAGE 4 OF 7

NALCO CHEMICAL COMPANY ONE NALCO CENTER

~ NAPERVILLE, ILLINOIS 60563-1 196 AREA708-305-1 oao

MATER1AL SAFETY DATA SHEET

-4 WALCO PROP UC7 DYNAM 1383 SCALE INHIBITO Emergency Telephone Number INedlcel (708) 920.1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 14 REGULATORY INFORMATION fire de)mrtnlent is rec~~ after October 17, 1987 if you have:

10,000 pounds or more of a hazazdous substance, or 500 pounds or the threshold planning quantity, whichever is less, of an extremely hazardous substance.

(

CONTINUED )

SECTION 313 - IZST OF TOXIC CHBGCAIS (40 CFR 372):

This pzlxhxct does not contain incp~iients (at a level of 1% or greater) on the List of Toxic Chenlicals.

TOXIC SUBSTANCES CONTROL ACT (TSCA,):

The chemical ingredients in this product are on the 8(b) Inventozy List (40 CFR 710)

~

RESOURCE CONSERVATION AND REKX3VEK ACI.'RCRA), 40 CFR 261 SUBPART C & D:

If this pzoduct becomes a waste, it does not meet the criteria of a hazardous waste.

FED)XAL WATER POLIDTION CXRZROL ACII CLZAN WATER ACIg 40 CFR 401 15/

fozmerly Sec.

307, 40 CFR 116/formerly Sec.

311:

None of the ingredients are specifically listed.

CUBAN AIR ACIr 40 CFR 60 i SECTION ll1I 40 CFR 61 r SKTION 112

~ ynxkuct does not contain irxpxdients covered by the Clean AirAct.

STATE RZGUIATIONS:

llag.

None of the chend.cals on the current Plxgosition 65 list are ]mown to be present in this product.

MICHIGAN CRITICALMATERIALS:

This pzoduct does not contain in~ents listed, on the Michigan Critical Materials Register.

8GQZ RIGRP 'IQ ERN LANS:

This product does not contain incpxdients listed by State Right To Khow Laws.

INTERNATIONALREGULATIONS:

'Ibis is not a WHKIS controlled product under The House of Cclmmns of Canada Bill C-70.

PAGE 5 OF 7

NALCO CHEMICAI COMPANY QNE NALCQ CENTER

~ NAPERVILLE. ILLINOIS 60563-1 196 AREA708-305-1 OOO

MATERlALSAFETY DATA SHEET

~j NALC0 PRODUCT DYNACCOL 1383 SCAZE INHIBITO Emergency Telephone Number MedIcal (708) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 15 ADDITIONAL INFORMATION None SECTION 16 USER'S RESPONSIBILITY

'Zhis product material safety data sheet provides health and safety information.

The product is to be used in applications oonsistent with aur product literature.

Individuals handling this product shauld be infoxmed of the recommended safety precautions and should have access to this information.

For any ather uses, exposures should be eva1uated so that appropriate handling practices and training progrmIIS can be established to ensure safe workplace operations.

Please consult your local sales representative for any further information.

SECTION 17 BIBLIOGRAPHY of Hea1th and Ehman Services, Public Hea1th Service, PB 33-135855, 1983.

CASAREZT AND DCUZL'S KOXZCOZOGY, KSE BASIC SCZENCE OF POISONS, Doull, J.,

Klaassen, C. D., arxl Admur, M. O., eds., Macmillian Publishinp Campany, Inc.,

N. Y., 2nd edition, 1980.

CHEMICAL HAZABDS OF ZHE WORKPZACE, Proctor, N. H., and Hughes, J. P., eds.,

J.

P. Lipincott Campany, N.Y., 1981.

DANGERCUS PROPEZKHX OF INUJSZRIAL MAT(RIAZSr Saxr N

Irv3LÃfr ed r Van Nostrand Reinhold Campanyr N Y r 6th editianr 1984.

IARC MDNOGRAPHS ON ZHE EVAZllATIONOF THE CA(KZNOGZÃZC RISK OF CSEMZQQS

'ZO MAN, Geneva:

World Health Organization, Xntexnational Agency for Research on Cancer, 1972-1977.

PAZTY'S ItKUSZRIALHYGI?~".AND 'ZOXECOZOGY, Clayton, G. D., Clayton, F. E.,

eds r Jo?ln Wiley and Sons r N Y r 3rd editionr Vol 2 ACr 198 1.

Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 editian, Vol. 3.-3, OH, 1984.

Tit1e 29 Code of Federal Re~julatians Part 1910, Sub'< Z, Toxic and W i tt

~1 GSEKSHOZD LDKZ VAZI3ES FOR CHEMICAL SUBS'XANCES AND PHYSICAL'GENZS IN ZHE PAGE 6 OF 7

NALCQ CHEMICAL COIVIPANY QNE NALCQ CENTER

~ NAPERVII LE. ILI INQIS 60563-1 166 AREA7OMO5-1 OOO

~ e e

INSTR MEVOSE. PENNSYLvaNIa 19041 Product Facts BETZ POIEHLINE PPL04 Copper Corrosfon lnhfbftor Inhfbfts corrosfon of copper alloys EtYectfveness fs not 1~fred by chlor1natfon Extends condenser sarvfce lffe OESCRIPTl0N NN USK pOMERLlNK ppLOa I s a

spec1al ly formlated Nf14 steel

tanks, paps, and pf p1 ng are corrosfon fnhfb1tor>>hfch 1s desfgned to satfsfactory for use >>1th poNERL?% ppLOa.

establfsh a

protactfve ffla on copper alloy condansars fn ttw Power industry.

PONERLIlC

,, 66KRAL PNFNTlEStv PPL04 aftectfvely fnh1bfts the corros1on of....

copper alloy surfaces.

[ndfrectly, ft also

~rance......,......lfght to dark brown lfqufd reduCeS the COrrOS1On Of Steel Surf'aCeS when the Oenafty................."""""... 9,9 1bS/gal corrosfon fs the result of a

galvanfc reactfon Flash Po1nt (closed c)

"..;.". "....,......>200F between the steel surface and the products,~ of. r-Freeze Pofnt "."""".".".""..........-25F copper corros1on >>hfch have been daposf ted on the Pour Pofnt..................................

-20F steele

, Srekffeld YfscoR) tg (70F) e ~ "~...........

Bocps TREA~NT ANO FEEDlNC REOUlRE%NTS (S% solutfon)...~... ~;

~ ~ ~. ~.~...,...~....11.3 The noreal trea~nt level for PONERLl)C. PPL04

~

protec&frmdreeafng+ 'lf thfs product fs I'rozan rangeS f~

1 tO S

PIN.

IIOWeVer, the ~nt durfPg ShfPeent Or Starage," oft"untf1 hOecgenecuS requfred wfll depend on eany factors such as prfor to use.

operat1ng characterf stfcs of the syi~

and severfty or aw problem.

Therefore, thfs prod QFETY PRKCNlTl01 uct shoul4 be used fn accordanCe wfth control-"-

paraeetars SETZ establfshes for

~

specfffc A Ikterfal Safety Data Sheet contafnfng detaf lad applfcatfon.

.,,~ fntoraatfoe relatfve-to-.thfs product 1s ava1lable PtMRLlR PPLOa shoul4 be Pod to 4 pofnt fn the coolfng sys~ >>here turbulence and flow patteM PINlQINt lltoN/lTNf;

>>1ll ensure adequate elafng of the product wf&'<:"

the COOlfng water.

li reofreulatf1yi COelf1y>>

POILEN PPLN., fa bloc&4"ia a lfqufdp and fS systeaa the product shwld be fH ceatfaeusly to supylfH fn 5%~lion bung type nonreturnable isafntafn consfsteat tesf4els.fi, ttW coolfng steel 4nasi ANroafmte net we1 ht - 535 pounds cater.

tntarntttena pl%&cl peii ta appltcaa'ia per date in

aaetttan, tlE palea tt tn certatn ence tatw+ ceeltnp tpetenp. ""

"-'"c-'atattapte ctntep tate.ICt paint,,pt pean terrace

~'='cprefyea-Por'oetrectH

-qha8Cfes",

fn cartafn Thfs product fs stable Nfder erma chlerfnaths

='.

geeynplffc'areas.

=: ""

practfces.

lt wfll not be adversely affected by sys~

aaployfng efther fntemlttent or contfnuous chlorfnatfon for the controf".'of afcroorganf sas.

~ cf "c ~

pe E~ instr Xt y

~ ~a'4 PONERL(NK PPL04 cay be fed 41rectly face the Shfppfng COntafner Or 411uted wf.th water,, tO any convenient (eedfng strength.

BETZ INDUSTRIAL 4636 SOMERTON ROAD TREVQSEg Ph.

19047 BETZ MATERIAL SAFETY DATA SHEET

, 24 HOUR EMERGENCY TELEPHONE (HEALTH OR ACCIDENT) 215/355-3300 PRODUCT: POWERL ZNE PPLOi EFFECTIVE DATE 10-31-88 PRZNTED: 12/15/8 PRODUCT APPLICATION: WATER-BASED CORROSION INHZbITOR.

w~~SECTZON 1~~~wmm~mmm~HhgjggQUS INGREDIENTS~mmmmmmwwmwww~

INFORMATION ON PHYSICAL HAZAJtDSg HEALTH HAZARDS'EL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZAZU) CQSlUNICATZQNS STANDARD ARE LISTED. REFER TO SECTION 4

(PAGE 2)

FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHRONIC HARA')S OF THIS FORMULATION. THIS PRODUCT IS SUBJECT TO THE PENNSYLVANIA HORKER AND COMMtJNZTY RIGHT TO KNCN LAMo BENZOTRIAZOLE)METHYL'ODIUMSALT ~ CASN64665-57-2JCOJNOSIVE TO EYES AND SKINJTOXIC (ORAL INGESTION) JPELINONEtTVLSN(NEQ

>> ~ 's

~V NONHAZQ INGREDIENTS'lLTM'"'.wmz".

a

-~ r<

>>1 f e

~

I >>i

-SECTZN R

WP1CAL HBICIL NR 7

>I PH! AS ZS QttCL'iR')'3 o0 ='N(N! )lILD FL PTo(DSOet) 0 'OO QQgC).":

5t QR (7(N')la ZNNNXTtf'.;-

l'e101~>>">'~~'APCN PRRSStJRS(~)

s X5>>>> " s

-V~DNNSZTY(MR.L)s ND VISC cpa70ts 7!

=

%NOMbH XTY(1RHR)!-.4(N IMIM'S%Rl PHYSICAL STATE! LIQUID Feria POINT(INN.P) C $~0:-

SECTZ(N 3

REACTIVITY DAT1 STAbLE THEN(AL DECXNPOSZTION (DEST!RCTZVE FZiCS) YIELDS EL~WAL OXIDES ~

MATERIAL SAFETY DATA SHEET (PAGE 2

OF 3)

PRODUCT:

POWERLINE PPL04 EFFECTIVE DATE 10-3i-g8

-SECTION 4-HEALTH HAZED EFFECTS-ACUTE SKIN EFFECTS>>>>>>

PRIMARY ROUTE QF EXPOSURE CORROSIVE TO SKIN ACUTE EYE EFFECTS>>>>>>

CORROSIVE TO THE EYES ACUTE RESPIRATORY EFFECTS MISTS/AEROSOLS CAUSE IRRITATION TO UPPER RESPIRATORY TRACT CHRONIC EFFECTS QF OVEREXPOSURE PROLONGED OR REPEATED CONTACT MAY CAUSE TISSUE NEC$NSIS.

MEDICAL CONDITIONS AGGRAVATED NOT KNOWN SYMPTOMS QF EXPOSURE CAUSES REDNESS OR ITCHING OF SKINPPOSSIBLY LEADING TO bURNSPDEPENDENT ON LENGTH OF EXPOSURE.

PRECAUTIONARY STATEMENT BASED ON TESTING RESULTS>>>>>>

MAY BE TOXIC IP ORALLY INGESTED.

-"-SECTION 5-"FIRST AID INSTRUCTIONS SKIN CONTACT >>>>

REMOVE CLOTHING.WASH AREA WITH LARGE AMOUNTS OP SOAP SOLUTION OR WATER FOR 15 MIll.IMMEDIATELYCONTACT PHYSICIAN EYE CONTACT>>>>>>

IlilEDIATELYPLUSH EYES WITH WATER POR 15 MINUTES.IlelEDIATELYCONTACT h PHYSICIAN POR ADDITIONALTREATNDlT ZNHALATIQN EXPOSURE>>>>>>

REkVE VZCTIM FAN CONTAMINATED AREA,APPLY NECESSARY FIRST AID TREATMENT.IlllEDIATELYCONTACT 1 PHYSICIAN.

INGESTION>>>>>>

DO NOT PEED ANYTHING BY MOUTH TO 1N UICON5CIOUS (R CIIVULSIVE VICTIM DO NOT INDUCE VOTING.IHCKD.CNITACTPHYSICIANoDIL~ CNITINTS OP STQQCH USING 3-4 GLASSES MILK OR WATER

5 ZC-N ZZ6

SP ZL L,-DZ5PDSAL 55D PZ55 ZDSZDDCZZZ>>5 SPILL INSTRUCTIONS>>>>>>

VENTILATIAREAPUSR SPECIFIED PIOTICTZVR ggISCIT.CONTAIN AND ABSORb ON hbSORbnlT MATERIAL.PLACE IN Nll?R DISPOSAL CQITAINIR. THI %ASTI FLUSH~ NITS NATIRiWET ARIA MAY BI SLIPPIIYeIP SOPSPREAD SAND/GRIT+

DISPOSAL ZlsmaCTZMS>>>>>>

SEWIR TRIRRÃSIT P1CZLITY,IN JiCCQlDANCI NITS 1NY LOCAL MImlINT1 PERMITTED I%I?I TRIATMIITPlCZLZTY (R DISCIARRD QIDCR 1 NPDIS PERMIT PRODUCT(AS Zf)

INCINERATE (R bUIY ZN APPRQVID hLSDtILL PIRE EXTINGUISHING INSTRUCTIONS>>>>>>

PZREPIGHTE$ lS SKULD NEAR POSITIVE i%CSSURE SELP~ITAINID BR~HING APPARATUS(PULL PACE-PIECE TYPE) ~

DRY CHEMICALSCARBON DIOXIDE'OAN OR NATER

MATERIAL SAFETY DATA SHEET (PAGE 3 QF 3)

PRODUCT:

PQWERLZNE

~

PPL04 EFFECTIVE DATE 10-31-88

-"-SECTION 7-"SPECIAL PROTECTIVE EQUZPMENT- -

USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-13i.

USE

RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS.

VENTILATION PROTECTION ADEQUATE VENTILATION RECOMMENDED RESPIRATORY PROTECTION>>>>>>

IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LZKELYt USE h RESPIRATOR WITH DUST/MIST FILTERS ~

RECOMMENDED SKIN M@ECTION GAUNTLET-TYPE RUBBER GLOVES t CHEMICAL RESISTANT APRON MASH QFF AFTER EACH USE.REPLACE AS NECESSARY RECOSSNDED EYE PROTECTION>>>>>>

SPLASH PROOF CHEMICAL GOGGLES. FACE SHIELD

-SECTION 8

-STORAGE AND HANDLING PRECAUTIONS STORAGE INSTRUCTIONS>>

KEEP DRUMS C PAILS CLOSED WHEN NOT ZN USE.

REASONAbLE AND SAFE CHEMICAL STORAGE HANDLING INSTRUCTIONS>>>>>>

Il&EDZATELYREMOVE CONTAMINATED CIA7THINGgMASH bEFN RNUSC ALKALINE.CORROSIVE TO SKIN AND EYES DO NOT MIX NITS ACIDZC MATERIAL.

THIS MSDS CXNPLIES WITH THE OSHA HAXJU CCNIUXICATItN STANDARD HAROLD M. HERSH (ENVIRON%ITAL INFORMATION COCSOINATCS)

>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>1>>>>>>>>>>1>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>0>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>*>>>>>>>>>>

<:, THE CONT%IT OF THIS APPENDIX REPRESENTS ZNFOINATZCN lQIONN TO BC'N THE

~~ EFFECTIVE DATE OF TSIS MSDS. THIS INFCmaTZCe ZS m,man TO aa ACClamS.

ANY CHANGES ZN REGULATIONS MILL $CSQLT IN UPDLTN7 ~Z NS Ot THIS DOCXMEIIT.

IICl

~ ~ o REPORTABLE QUANTITY(RQ) PC% UNDILlÃHD PRMQCT t NOT APPLICABLE

...RCRAt XF THIS PRMQCT IS DI)ClRDED AS 1 KLSTR~RR NCNA 81XLRXXJS 1QSTE IDENTIFICATION NUHSRR IS t DO02MNNOSXVN

~ ~ oDOT HAXAND CLlSSIFICATIMt CmkRlSIVN TO SKIS

. ~.DOT SHXPPINO DRSZNTQN ISt UN1760 CMRSIVB LIQUXOg NsOe5>>

~ ~ ~ oTHIS PRNX)CX'ÃILDS THESE CNICALS 1NOISI TO TSN ST1TR Ot CALZRSÃIA TO CAUSE CANC' MPRXXCTIVS TOXXCITYt %MR PlCSXNT IN SIINIFICAÃTNCXlNTS

..SARA SNCTXM SCR CMCCAL5t NWS WREST IÃ SIINXFICAN%'lNUNTS

~ ~.SARA SN.'TXM 3'NSNZCAL5t NINN PRRS~

ZN SIGNIFICANT llNNNTS

~ ~.SARA SECTS 312 SLXlRO CLASSt ZNIRDZATN(lCITN)AND M!kTRD(CIQINXC)

~ ~ oMZCHIGAN CkITICAL ML~IALSt NN PNNSSÃT ZN 5ZONZFICAL 1lQÃTS NFPA/%IS t HQLTS - 3 l FIR - 1

~ RRRCR'XVXTt - 0 ] QKQh - CNR g Pt - D

1179 IP/79 MATERIAL SAFETY DATA SHEET 6D32.02.18.86.643 PRODUCT NAME PCL-50 CALG ON suasloiisRv OF MERcK a co rric MANUFACTURER'S NAME ADDRESS Calgon Corporation EMERGENCY TELEPHONE NO.

(412) 777.80M P. O. Box 1346, Pittsburgh, Pennsylvania 15230 CHEMICALNAME ANO SYNONYMS Triazole FORMULA C7H6N3Na

~ ~

PRINCIPAL HAZARDOUS COMPONENT (S)

ORAL LOgp DERMAL LDSp TLV )Units)

Sodium tolyltriazole (CAS No. 64665.57.21 50 675 mg/kg Unknown Unknown I'(%

~

s BOII.ING POINT loF)

VAPOR PRCSSURE (mmHg.)

> 212 Unknown SPECIFIC GRAVITYlH20%1)

PERCENT VOLATILE BY VOLUME (SS) 1.18 508 VAPOR DENSITY IAIR%11 Unknown pH 1%

12.3 soLUBILITYIN wATER ',,-,

g.~ ~M)scib)e-<<

AppEARANGE AND QDQR Dark red solution with slight aromatic odor FLASH POINT )Method Used)

EXTINGUISHINGMEDIA Not Flammable

~

s

% ~

~ i FLAMMABLELIMITS Not Applicable Lel Uel SPECIAL FIRE FIGHTING PROCEDURES t

UNUSUAL FIRE AND ~

EXPLOSION HAZARDS Product is not flammable.

None re, y

g r

C

'r None VVhife this information and recommendations sel forth herein are believed to be accurate as of the date hereof, CALGON CORPORATION MAKES NO WARRANTY WITH RESPECT HERETO AND OISCLAIMS ALL. LIABILITYFROM RELIAKICE THEREQN,

4 I

r ~

r N/A ~ Not Applicable a

~ ~

~

a a

" EFFECTS OF OVEREXPOSURE Causes burns.

Harmful if swallowed.

EMERGENCY AND FIRST AIO PROCEDURES EYE:

In case of contact, immediately flush with plenty of water for at least 15 minutes.

Call a physician.

SKIN: In case of contact, immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing. If irritation develops, call a physician.

Wash clothing before reuse.

INTERNAL: Ifswallowed, do not induce vomiting. Give large quantities of water.

Give at least one ounce of vinegar in an equal amount of water.

Never give anything by mouth to an unconscious person.

Call a physician.

~

a STABILITY STABLE UNSTABLE INCOMPATABILITY (Materials to Avoid)

X CONDITIONS TO AVOID Strong oxidizers Unknown HAZARDOUS DECOMPOSITION PRODUCTS When heated to over 200 C., degassing will be observed.

Carbon dioxide, carbon monoxide nitro en oxides and h dr en c anide can be iven off.

HAZARDOUS POLYMERIZATION MAYOCCUR NO CONDITIONS X

TO AVOID Unknown

~ a

~ 0 ~

~

a REPORTABLE QUANTITIES IRQ)

IN LBS. OF EPA HAZARDOUS St >s)STANCES IN PRODUCT L

2.

3.

~

N/A NOTIFY EPA OF PRODUCT SPILLS EQUAL TO OR EXCEEDING LSS.

STEPS TO BE TAKEN IN CASE MATERIALIS RELEASED Dispose of in accordance with local state and federal regulations Dike area to contain OR SPILLED as much spilled material as possible.

Remove any remaining material by absorbing on vermiculite or other suitable absorbing material and,place in a sealed metal container for disposal.

WASTE DISPOSAL METHOD Dilute with water and neutralize with 6M-HCI. Flush with water to discharge.

Dispose of in accordance with local, state and federal regulations. -hali.

~ e ~

~

RESPIRATORY PROTECTION ISpecify Type)

A NIOSH-approved respirator for sodium hydroxide is recommended only if exposed to excessive mists.

VENTILATION Normal PROTECTIVE GLOVES LOCALEXHAUST Adequate MECHANICAL IGeneral)

Not Required Rubber SPECIAL Not Required OTHER Not Required EYE PROTECTION Eye goggles or full.face shield OTHER PROTECTIVE EQUIPMENT Protective clothing

~

~ e

" 'AUTIONS TO BE TAKEN IN 1

3LING ANO STORING OTHER PRECAUTIONS Do not get in eyes, on skin or on clothing.

Keep container closed.

Wash thoroughly after handling.

None IMp.nod'.\\

I a aa

~ 0 "1

%V

p QPR-89-1991 87: 38 FROM 72-62-7830-01 r,ir.,TE".(A.'l <=TY DA < /I SHEET DREW BOONTON

~ \\ ~

~/P:

SALES ADMIN.

TO VALLEY FORGE PA P.88 r'"gg";.'~Lg' I:Iai 9'CVf>tQ i Emeraency Telephone Qnc g:zav plaza. Boon on, New Je'"av 0>>005 q (Bpp) at'i.gg03 or P!ion. I20'ti-"G3 7(i"p T Ie" 3-Spp-ASHLp,t, Page:

000067 Data Sheet Ho:

0065195-003 P repat ed:

08/16/89 SuperSedeS:

03/02/87 0D 10 Dirt DREH CKEHICAL CORPORATION ONE DREH CHENZCAL PLAZA HJ07005 PRODUCT:

D1597295 INVOICE!

INVOICE DATE'-

TOI NARKETING PC I I,'

I a'I " !lit ~

I I

~ 'IHt I I Ilail

~r~... ~r". ~ )y.:.,~.>>,

Genetal or Gener io IDI CORROSION INHIBITOR DOT Hazard Classif icationt CORROSZVE HATERIAL (173.2r>>O).

~

'PD 11-166(TN)

CORROSXON XNHXBITOR THIS tSDS COHP'LIES HZTH 29 CFR 1910.1200 (THE HAZARD COfSI41CATZON STANDARD)

IIWHl ProC)uct ttamet NPD 11 166(7t()

CORROSION INHIBITOR CAS HUNBERI 64665-57 2

~ ~

WC f I *I I

I - ~I

~

.I ZHGIiF~'trr SODZIPl TOLYLTRIAZOLE CAS SI 64665-57 2

~O1~:

( 1) PEL/TLV HOT ESTABLZSHED FOR THZS NATERZAL 4 Z>t'!III'I It'lI,

%'t"a tt i >>r

~

', ~ '.. i' IF PRESENT IARC>> NTP AND OSHA CARCIHOGENS AND CHEHICALS SUBJECT TO THE REPORT ZNG REQUZRINENTS OF SARA TITLE III SECTION 313 ARK IDENTIFIED IN THIS SECTION>>

SEE DEFINITION PAGE FOR CLARIFICATION 50 Boiling Point Vapot Pressure for PRODUCT for PRODUCT

>>X 212.00 Degi F

(

100.00 Deg C) 0 760.00 II!I Hg

(

17.50 I!I!I Ho D

68.00 Dog F

20.00 Dog C )

Speoif io Vapor Density UHAVAI(.ABl.E Specific Gravity Percent Volatiles Evaporation Rate pH Appearance State Form

~i ( &

~ r

1. 190 0

77.00 Deg F I

25.00 Deg C) 50.00/i SLOHER THAN ETHER 13.5 CLEAR>> YELLOH TO AYBER LIQUID o< ~

II~I II I

~

I. !O>>

I!at I:

I Y.

~ I II'I FLASH POINT HOT APPl.ICABLE EXPLOSIVE LI)(IT HOT APPLICABLE EXTINGUISHING t(EDZAI NOT APPLICABLE HAZARDOUS DECOHPOSITIOH PRODUCTSt THERHAL DECOHPOSZTION O'R COt%VSTION HAY PROOUCEt CARBON DIOXIDE>> CARBON NQNOXZDE>> OXIDES OF NZTROGEHI HYDROGEN CYANIDE IH REDVCZNG ATMSPHERES FZREFIGHTIhS PROCEDURESI HEAR SELF-COHl'AINED BREATHIHG APPARATUS HZTH A FVLL FACEPZECE OPERATED ZN THE POSITIVE PRESSURE DENAND NODE AND FULL BODY PROTECTION HHEN FIGHTING FIRES.

HATER HAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL N(TIL FIRE IS OUT.

HFPA CODES I HEAl.TH 3

FLAlSABILITY"0 REACTIVITY 0

CLOSED CONTAINERS HAY RUPTURE OR EXPLODE DUE TO PRESSURE BUILD~ HHEN EXPOSED TO EXTREHE HEAT PC'VI

~

r/

~ ',I.>I

~

IERNISSZBLE EXPOSURE LEVEL! HOT ESTABLISHED~

F C

OF A

V FOR PRODUCT EYES CAUSES SEVERE DAHAGE~

SKIN CAUSES BURNS SHALLOWIIIG RESULTS Itt SEVERE DAHAGE TO HUCOUS HEHBRANES AND DEEP TISSUE BREATHZNGt NAY CAUSE DZSCONFORT OR IRRITATION TO NASAI AHD RESI ZRATORY I ~SSAGES COPYRIGHT 1989, CONTINUED ON PAGE I 2

th

'/

i

HPR-8'9-1 J91 U >" 31 FROM 72-62-7850-01 f<'>>0TEI'ilO'AFETY DATP. SHE="T DREW BOONTOll Ll>

'rj)

SALES ADMIN.

TO VALLEY FORGE PA P.89 D'y ti t~i'~~V>>c-- Qik [St<>>"

EITtetg0ncy Telephone p>te pter PIC>>,.

OOn!On, NeW JC>>aeYO7OOB

] (QGQ) 27t, 52)3 Qf

'l!000 l20') 2Gp 7G"0 TeleK )~G~A4 qhapp

)) SQL>0,gD NPD 11-166 ( TN)

CORROSION INHIBITOR Page I 2

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~

~ t><<e

~ t;1 e

~

e >>tee>>

<<ye ~ ~ r

~

C* ">>,.tqc

<< ', r',

~

~.

~)~ST

>~ID ~

IF ON SKIN: I)IIIEDZATELY FLUSH KITH HATER FOR AT LEAST 15 NINVTES.

RENOVE CONTAMINATED CLOTHING>>

LAUNDER CONTA)IINATEO CI.OTHZNG BEFORE RE-VSE.

IF IH EYESt FLUSH HZTH l,ARGE A)NVMTS OF HATER>> LZFTIHG UPPER AND LONER LIDS OCCASIONALLY.

GKT NEDZCAL ATTEMTIOM>> IF ZRRITATIOH PERSISTS.

ZF SNALLOHED: DO NOT INDUCE VOHITING.

VONZTZNG HILL CAUSE FURTHER DAttAGE TO THE THROAT>>

DILVTE BY GIVING HATER>>

GIVK MILK OF NAGHKSZA KEEP HARN>> QUIET GET MEDICAL ATTENTION I~DZATELY~

ZF BREATHEDt REl%VE INDIVIDUALTO FRESH AIR.

ttIM>tRY S

FEMTY~

SKIN CONTACT

~

~ re..

~

1 1

1 ',

~

1' 1 ~;t

~

~t

~

HAZARDDVS POLY)IERZZATIOHt CANNOT. OCCUR

'TABZl.ZTYt STABLE ZNCOttPATZBILITY)

AVOID CONTACT HITH)>> STRONG OXIDIZING AGENTS>>>>

STROHG NINERAI. ACIDS.

>t'0 t>>l 1

e

~ 1

~

t<<

~

g,

~

1 q << t

>>>! ~

~

Z

...'. e,

~

~ >>'.,

~

TE S

TAKEN IM CAS A

R A

IS REL ASE O

SP SHALL SPILLt ABSORB LIQUID ON PAPER>>

VERNZCULZTK>> FLOOR ABSORBENT OR OTHER ABSORBENT NATKRIAL.

LARGE SPILL>

PERSONS MOT HEARING PROTECTIVE EQVZPHKNT SHOULD BE EXCLVDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED.

STOP SPZLL AT SOURCE DIKE AREA OF SPILl. TO PREVENT SPREADING PlPIP LIQUID TO SALVAGE TANK..

RENAIMING LIQUID NAY BE TAKEN UP ON 5AND>> CLAYS EARTH ~

FLOOR ABSORBENT>>

OR OT)IKR ABSORBEMl )IATKRZAL AND SHOVELED INTO CONTAINFRS.

KAT DIPOAL 0

e SHALL SPILL: DISPOSE OF ZN ACCORDANCE HITH ALL LOCAL STATE AND FEDERAL REGULATIONS.

LARGE SPZLLt DISPOSE OF ZM ACCORDANCE HZTH Al.L LOCAl.>> STATE AND FEDERAL REGULATIONS>>

P>t>>' !it; I

1 1

r>

>'1

. l:>>

I

<< ':I:

.I

~ r >'"~": ~ ~

RESPIRATORY PROTECTIONt ZF OVERKXPOSVRE HAS BEEN DETERHIHED OR DOCNIENTED>> A NZOSH/HSHA JOINTLY APPROVED AIR SUPPLZED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL ~

OSHA REGULATIONS ALSO PER)IZT OTHER NIOSH~XA RESPIRATORS UNDER SPECIFIED COMDZTICNS.

ISEE YOUR SAFETY EQVZPNENT SUPPLIER)e KNGZNEFRING OR AO)IINISTRATIVKCONTROLS SHOULD BE I)IPLK)IEHTKD TO REDUCE EXPOSURE.

VENTZLATIONt PROVIDE SUFFICIENT tfECHAHICAL lGEMKRAL AMD/OR LOCAL EXHAVST) VENTZLATZOH'TO NAZNTAIM EXPOSVRE BELOH LEVEL, OF OVERKXPOSVRK I FROM KNOT>> SVSPECTED OR APPARENT ADVERSE EFFECTS)

~

PROTECTIVE CLOVES: NATURAL RUBBER EYE PROTECTION:

CHEMICAL SPLASH GOGGLES AND FACE SHIELD l8" NIN. ) TM COHPLZANCE HITH OSHA RKN)LATZONS ARE SUPPLIER)

ADVISED) HDHKVKR OSHA REGULATIONS ALSO PER)IIT OTHER TYPE SAFETY GI.ASSES, lCONSULT YOUR SAFETY EQUIP)IEMT OTHER PROTECTIVE EQUIP)IENT 1 TO PREVENT SKIN CONTACT>> HEAR ZHPERVZOUS CLOTHING AND BOOTS.

t>> I I:l 1

1

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MATERIALSAFETY DATA SHEET NALCO PRODUCT NA~ 1326 CORROSION ZNHIBITO Emergency Telephone Number Medical (70B) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 1

PRODUCT IDENTIFICATION TRADE NAME'AZCO 1326 CORROSION INHIBITOR DESCRIPTION:

An aqueous solution of sodium tolyltriazole en:

/

0=Insignificant lWlight 2~crate 3=High 4=Extreme SECTION 2

HAZARDOUS INGREDXENTS Our hazard evaluation has identified the follcaring chemical ingredient(s) as hazardous under OSHA's Hazard Cclmmunication Rule, 29 CFR 1910.1200.

Consult Section 14 for the nature of the hazard(s)

INGREDIENT(S)

Sodium tolyltriazole 64665-57-2 APPROX. 4 40-70 SECTION 3

PRECAUTIONARY LABEL INFORMATION WARNZNG:

Causes burns to skin and eyes.

Do rIot get in eyes, on skin, or on clothing.

Wear goggles or face shield when handling.

Do not take internally.

Eillpty containers may contain residual product.

Do not reuse container unless properly reconditioned.

SECTION 4 FIRST AID INFORMATION EYES:

SKIN:

INGESTION:

Zaanediately, flush for at least 15 minutes while hol~

eyelids open.

Call a physician at once.

ZrIImediately flush with water for at least 15 minutes.

For a large splash, flood body under a shcxrer.

Call a physician at once.

Do not induce vomiting.

Give water.

Call a physician.

NCGE TO BKSXCIAN:

No specific antidote is known.

Based on the individual reactions of the patient, the physician's judginent should be used to contxol symptcnls and clirlical condition.

CMTHON: If unIxescious, having trouble breathirlg or in convulsions, do not irduce vomiting or give water.

SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY EKVXE(S) OF EXPOSURE:

Eye, Skin PAGE 1 OF 8

NALCO CHEMICAL COMPANY QNE NALCQ CENTER

~ NAPERVILLE. ILLINOIS 60563-1 196 AREA7oe-305-1 ooo

MATERlALSAFETY DATA SHEET

~

NALCO

~~ >326 CORROSION ZNHIB

,I Emergency Telephone Number Medical (708) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 5 HEALTH EFFECTS INFORMATION

(

CONTINUED )

EYE CONTACT'EEN CONTACT:

INGESTION:

Corrosive to the eyes with possible perIIIanent damage depending on the length of exposure and on the first aid action given.

Can cause severe irritation.

Corrosive to the skin, possibly resulting in thi~ degree burns depending on the length of exp~me and on the first aid action given.

Can be haxnlful.

SYMPICMS OF E)GQKHK:

A review of available data does not identify any sylllptalIIs fram exposure not previously mentioned, or identified in Section 6 or 14.

AGGRAVATION OF EXISTING CONDITIONS:

A review of available data does not identify any worsening of existing conditions.

SECTION 6 TOXXCOLOGY XNFORMATION.,

ACUTE 'IOXICITY SIUDIES:

Acute toxicity studies have not been conduI:~

on this product, but acute studies have been conducted on a similar product.

The results are shown below.

ACUTE ORAL TOXICITY (ALBINO RATS):

ID50 = 675 Itq/lay ACUTE DERMAL 'IQXZCITY (AL'BINO RABBITS):

ID50 = Greater than 2 glIy'kg ACUTE INHAlATIONTOXICITY (AU3XHO RATS):

XC50 = Greater than 1.73 mp/L for 1 hour1.157407e-5 days 2.777778e-4 hours 1.653439e-6 weeks 3.805e-7 months exposure PRZKBY SEEN IRRITATION TEST (ALBINO RABBITS):

SKIN ZRBITXKON XÃKKDRAIZE RATING:

Severely irritating PRZMARY EYE ZHR~ON TEST (AIBZNQ RABBITS):

EYE IRIKZRPZON INDI% DRAIZE RATl2C:

Severely irritating (corrosive)

SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR:

Deep brawn/black FOHN:

Liquid DENSITY:

9. 9 lbs/gal.

SOIIJBZIZZY IN 0VZER:

Campletely SPEXZFIC GRAVITY:

1.19 9 60 Degrees F

pH (NEAT) =

13.5 FIKZZE POINT:

-22 DeIprees F

BOILING POINT:

212 Degrees F 9 760 mm Hg FLASH POINT:

Greater than 225 Degrees F

PAGE 2 OF 8

ODOR:

Slight

- ASIN D-1298 ASIM E-70 ASIA D-1177 ASIM D-86 (HKC)

ASSAM ~3

/JAN QO OHE5nlCAl QOMpANY ONE NALCO CENTER

~ NAPERVILLE. ILLINOIS 60563-1 166 coen, dna one snnn

MATERIALSAFETY DATA SHEET NALCO PRODUCT NMXO 1326 CDEGKGION INHIB Emergency Telephone Number Medical (708) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES

(

CONTINUED

)

NOTE:

These physical properties are typical values'for this product.

SECTION 8 FIRE AND EXPLOSION INFORMATION FCASfk EOINT:

Greater than 225 Degrees F (BKC)

ASIA D-93 1MHNGUISHING MEDIA:

Nat applicable UNUSUAL FIRE AND EG?XQSIGN HAZARD:

May evolve NOx under fire conditions.

Cont~am exposed in a fixe shca&d be cooled with water to prevent vapor pressure buildup leading to a xupture.

SECTION 9 REACTIVITY INFORMATION INCXMPATIBILIZY: Avoid contact with stxong acids (eg. sulfuric, phosphoric, nitric, hydxIxM.oric, chxaIIIic, sulfonic) which can genexate heat, splattering or boiling ared the release of taxic fumes.

THKKALDFAXRIPOSITIGN PROIXJCIS:

In the event of cambustion CO,

CO2, NOx may be formed.

Do not breathe smoke or fumes.

Wear suitable pxotective equipment.

SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PRt3TECXXGN:

Respiratoxy protection is not noxmally needed since the volatility and toxicity axe lmr. If significant vapors,'ists or aerosols axe generated, wear a NIOSH approved or ecpivalent For large spills, entxy into large tanks, v~s or enclosed small spaces with inadequate ventilation, a pressuxe-demand, self-contained hler ey VENZZ2ZIGN:

General ventilatian is recommended.

A9ditionally, local exhaust KPl

glaves, goggles, shoes, etc.).

A full slicker suit is xeccmImended if gross exposuxe is possible.

'Ihe availability of an eye wash fountain and safety shaImr is recxumIIended.

PAGE 3 OF 8

NALCO CHEMICAL COMPANY ONE NALCQ CENTER

~ NAPERVILLE. ILLINOIS 60563-1 196 AREA708-305-1 OOO

l pt n,

IVIATERlALSAFETY DATA SHEET

~

WALCO PRODUCT NAICO 1326 CORRCSION INHIB Emergency Telephone Number Medical (708) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 10 PERSONAL PROTECTION EQUIPMENT

(

CONTINUED )

Zf clothing is contaminated, reznave clothing and thoroughly wash the affected area.

Iaum2er contaminated clathing before reuse.

SECTION 11 SPXLL AND DISPOSAL INFORMATION IN CASE OF TEINSPORGKION ACCIDENTS, CALL 'IHE FOLIQWZNG 24-HO()R TELEKKONE NUME3ER (708-920-1510)

SPILL CONTROL AND RECOVER:

Small liquid spills:

Contain with absorbent material, such as clay, soil or any calnnIercially available absorbent.

Shovel reclaimed liquid and absorbent into recavexy or salvage drums for disposal.

Refer to CEZKXA in Section 14.

Iarge liquid spills:

Dike to prevent further movement and reclaim into recovery or salvage dnnns or tank txuck for disposal.

Refer to CERCIA in Section 14.

For large indoor spills, evacuate emplayees and ventilate area.

Those responsible for contxol arxl recavexy should wear the protective equiplnent specified in Section 10.

DISPOSAL:

Zf this product becames a wast~, it meets the criteria of a hazardous waste as defined under the Resources Conservation arxk Recavexy Act (RCRA) 40 CFR 261.

Hazardous Waste D002.

As a hazaxdaus liquid waste, it must be solidified with stabilizing qgents (such as sand, fly ash, or cement) so that no free liquid remains beEore dispuM to a licensed industrial waste landfill (Hazardous Waste Treatment, Storage and Disposal facility).

A hazardous liquid waste can also be incinerated in accordance with local, state, and federal regulations.

SECTION 12 ENVIRONMENTAL INFORMATION AQKGXC DATA.:

96 hour0.00111 days 0.0267 hours 1.587302e-4 weeks 3.6528e-5 months static acute ZC50 to Bluegill Sunfish = 150 mp/L 96 haur no observed effect concentration is 56 pgIn based on no mortality or abnormal effects.

IOXZCITY RATING: Slightly toxic 96 hour0.00111 days 0.0267 hours 1.587302e-4 weeks 3.6528e-5 months static acute LC50 to Rainrxar Trout = 34 mg/L PAGE 4 OF 8

NALCO CHEIVIICALCOIVIPANY QNE NALCQ CENTER

~ NAPERVILLE. ILLINOIS 60563-1 196 dRCA 7C)A-APER,-1 CYlh

MATERIALSAFETY DATA SHEET PRODUCT NEO 1326 CORROSION INHI NALCQ Emergency Telephone hlumber Medical (708) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 12 ENVIRONMENTAL INFORMATION

(

CONTINUED

)

96 hour0.00111 days 0.0267 hours 1.587302e-4 weeks 3.6528e-5 months no observed effect concentration is 18 mp/L based on no mortality or abnormal effects.

'ZOXICITY RAT)XG:

Moderately toxic 96 haur static acute IC50 to Fathead Minnow = 130 mp/L 96 hour0.00111 days 0.0267 hours 1.587302e-4 weeks 3.6528e-5 months no observed effect concentration is 56 mp/L based on no mortality or abnormal effects.

TOXICITY RATING:

Slight1y toxic 48 hour5.555556e-4 days 0.0133 hours 7.936508e-5 weeks 1.8264e-5 months static acute ZC50 to Daphnia Magna = 420 ng/L 48 hour5.555556e-4 days 0.0133 hours 7.936508e-5 weeks 1.8264e-5 months no abserlred effect concentration is 100 uq/L based on no mortality or abnormal effects.

YOXECZTY EQZZNG:

Slightly taxic If released into the envtronment, see CERCZA in Sectian 14.

SECTION 13 TRANSPORTATION INFORMATION IXT PROPER SHIPPING NAME/HAZtQKlCODE OCKKGIVE IZQUID, N.O.S.

CORROSIVE MATUALUN 1760 CONTAINS

- SODIUM KOIZI)Z!RIAZOLZ SECTION 14 REGULATORY INFORMATION

'Ihe follcmizxy xegulatians apply to this product.

FED1XAL KXXJZATIGNS:

r OSHA S HAZARD CXSMUNICATIGN RULEg 29 CFR 1910 1200 Based an our hazard eva1uatian, the fallowing ingredient in this product is hazardous and the reason is shI:xm below.

Sodium tolyltriazole - Eye/skin irritant CERCZA/SUH~UNDI 40 CFR 117 I 302 Natification of spills of this product is not recuized.

AND REAUZBCRIZATIGNACT OF 1986 PAGE 5 OF 8

NALCO CHEMICAL COMPANY QNE NALCQ CENTER

~ NAPERVILLE. ILLINOIS 60563-1198 AREA VClS-SCIS-1 CPPl

g(

MATERIALSAFETY DATA SHEET WALCO NADX) 1326 CGHBQSZON INHIB Emergency 7elephone Number Medical (708) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 14 REGULATORY INFORMATION (TZTIE IZI) SECTIONS 302 r 31lr 312 AND 313:

(

CONTINUED

)

SECTION 302 - EZZREMELY HAZARDCUS SUBSTANCES (40 CFR 355):

This product does not contain ingredients listed in Appezxhx A and B as an I~mely Hazardous Substance.

(40 CFR 370):

Our hazard evaluation has found this product to be hazardous.

'Ihe product should be reported under the follcmitng EPA hazard categories:

XX Znmediate (acute) health hazard Delayed (chronic) health hazard Fire hazard Sudden release of pressure hazard Reactive hazard Under Section 311, submittal of MSDS's or a list of product names to the local emergency planning commission, state emergency response cananission and local fire departnIent is recp~d after October 17, 1987 if you have:

10,000 pounds or more of a hazardous substance, or 500 pounds or the threshold plannirg cgmntity, whichever is less, of an extremely hazardous substance.

After October 17, 1989, NSDS(sp., or a list of prochmt names for all

.P.

"CX

reported, must be submitted.

SECTION 313 - LIST OF 'IOXIC CHEZZCAIS (40'FR 372):

'Ihis product does not contain izxp~ents (at a level of 1% or greater) on the List of Tmic Chemicals.

'IOXZC SUB'.i~CES CONTROL ACT (TSCA,):

The chemical ingre:iients in this product are on the 8(b) Irwentory List (40 CFR 710).

RESCURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261 SUBPARC C & D:

Ifthis product becclaes a wa.~, it does meet the criteria of a hazardous waste as defined under RCRA 40 CFR 261 (consult Section ll)..

FEEH~ %PEER EOLUJZXON CONZROL ACTr CU AN HATER ACTr 40 CFR 401 15 (formerly Sec. 307),

40 CFR 116 (formerly Sec. 311):

PAGE 6 OF 8

NAL.CO CHEIVIICALCOIVIPANY ONE NALCQ CENTER

~ NAPERVILLE. ILLINOIS 60563-1 166 nnv~ dna wns ~nnn

P

~ II O

NALCO MATERlALSAFETY DATA SHEET PRODUCT NM~ 1326 CORROSION Emergency Telephone Number Medical P08) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 14 REGULATORY INFORMATION None of the ingredients are specifically listed.

(

CONTINUED

)

CLEAN AIR ACTr 40 CFR 60 r SECTION 111 r 40 CER 61 r SECTION 112

'Ihis product does,not contain ingredients covered by the Clean AirAct.

STATE REGUZATIONSI Nane of the chemd.cals on the current Pxaposition 65 list are knawn to be present in this product.

MICHIGAN CRITICAL MATERIALSI

'Ibis product does not contain ingredients listed on the Michigan Critical Materials Register.

FGQZ RZGHZ'O ENN ITS:

%his product does nat contain irxpxdients listed by State Right To Znov Laws.

INZZPNATIONAL REGUZATIONS'his is a WHMIS controlled product under 'Ihe Haixse of Oalmnons of Canada Bill C-70.

'Ihe product contains the follcaring substance(s),

fram the Ingredient Disclosure List or has been evaluated based an its taxicological properties, to contain the followiLng hazaxdaus.- ingredient(s):

I Chemical Name CAS I 4 Concentration Range Sodium tolyltriazole 64665-57-2 SECTION 15 ADDITIONAL INFORMATION None SECTION 16 USER'S RESPONSIBILITY Xhia pxoduct material safety data stMmt provides health and safety infoxmatian.

'Ihe product is to be used in applications cansistent with our product literature.

Individuals handliap this pxoduIW shauld be to this infoxmatian.

For any other uses, exposures should be evaluated so that appropriate handling practices and traimzg programs can be established to ensure safe workplace opmatians.

Please cansult your local sales representative for any further information.

PAGE 7 OF 8

NALCQ CHEMICAL COIVIPANY QNE NALCQ CENTER

~ NAPERVILLE, fl LINQIS 6D563-1 198 AREA708%05-1 oaa

I

~ice

MATER1AL SAFETY DATA SHEET NALCO NAICO 1326 CORROSION INHIB

('~

Emergency Telephone Number Medical (708) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 17 BIBLIOGRAPHY MUG REEORP ON CAMXHOG)XS, U.S. Departzllent of Health and Hum-In Services, Public Health Servicer PB 33 135855r 1983.

CASAREIT MD DOULL'S TOXICOICGY, IHE BASIC SCIENCE OF POISONS r Doullr J r

KLaassen, C. D., and Admur, M. O., eds., Macmillian Publishing Calllpany, Inc.,

N. Y., 2nd edition, 1980.

CHEMICAL HAZARDS OF THE WORKPIACEr Proctorr N

H I and Hughes r J P

r eds J. P. Lipincott Caltlpany, N.Y., 1981.

DANGERCUS PROPS OF INIXJSTRIALMATERIAIS Sax N

Irv1Tlgr ed r Van Nostrand Reinhold Company, N.Y., 6th edition, 1984.

IARC MONOGRAPHS ON 1HE EVAIIJATIONOF THE CARCINOGENIC RISK OF CHEMICAIS TO MAN, Geneva:

World Health Organization, International Agency for Research on Cancer, 1972-1977.

PATTY'S IMXJSXRIALHYGIENE AND KOXICOIDGY, Clayton, G. D., Clayton, F. E.,

eds I John Wiley and SoIls r N Y r 3rd editiong Uol 2 AMr 198 1 REGISTRY OF TOXIC IM'ZUNIS ON CHEMICAL SUBSTANCES, U.S. D@~oent of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupatianal Safety and Health, 1983 supplement of 1981-1982 edition, Uol. 1-3, OH, 1984.

Title 29 Code of Federal Regulations Part 1910, Subpart Z,', Taxia arxl ty TKKSHOXD LB'MUJES FOR CHEMICAL SUBSTANCES AND PHYSICAL AG)&IS IN THE Gavenmlental Industrial Hygienic~~,

OH.

PREPARED BY:

Ricky A. Stackhause PhD., Toxicologist DATE CHAN2K): 10/10/89

~

DATE.PRINZED: 04/04/91

~

PAGE 8 OF 8

NALCO CHEMICAL COMPANY ONE NALCO CENTER

~ NAPERVILLE. ILLINCllS 6CI563<<1 166 AREA708-305-1 ooo

BETZ INDUSTRIAL 4636 SOMUCON ROAD TREVOSEg PA, 19047 MTZ MATERIAL SAFETY DATA SHEET 2i HOUR EMERGENCY TELEPHONE (HEALTH OR ACCIDENT) 215/355-3300'RODUCT:

POMERL INE 3450 EFFECTIVE DATE 10"31-88 PRINTED! 12/15/8 PRODUCT APPLICATION: WATER-BASED DEPOSIT CONTROL AGENTS

-"-SECTION 1-HAZAJURUS INGREDIENTS---

INFORMATION ON PHYSICAL HAZARDS'EALTH HAZARDS'KL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZAitD CCMCUXICATIONS STANDAJU) ARE LISTED. REFER TO SECTION i (PAGE 2)

FOR OUR ASSESQCNT OF THE POTRITIAL ACUTE AND CHRONIC HAZARDS OF THIS FORKJLhTIONo THIS PltODUCT IS SUBJECT TO THE PENNSYLVANIA WORKER AND COHNAiITY RIGHT TO KCW LAN.

THIS PRODUCT IS NOT JRZhdtDOUS AS DEFINED bY OSHA RESJIATIONSo s

e r eh speal rs~

~r.->p t~' i

~

I te NONHAZARD INGRIDI~c ILES lID CONAN %SR lg, 2-lSÃSNOZC lCZD 1ND 1r2g-1%tlNDIOL lCWQ 2 PRNSOLS (393733l 7)

-SECTS 2 ICAL PIYSZCALDLTL PH~

AS IS

'1PPINN.).,5.3 OXS.

M1LO FL.PT. (MO,t) S 200 SRXl(CC)..

St AR (70t)te INNIRtc. 1 123..

Vase PRESSuaa(mM) s 20, '.

Vaja MSSnr(aIR 1) c 1..

VISC cys70Ft 19 ~ 5

%50hQSZLZXT(ILK')0 100 EVAP.RATE!

1 ETC~1 IWau1CE aLaHII el PHYSICAL STATI! LIOOD PIXIES POISE(MS.P) c RS

SECTION 3 IIACTIVITXMTL SThbLE THI14AL DECNPOSITItN (DESTRtJCTIVI meS)

YIELDS ILSaITAL OXID!S.

MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3)

PRODUCT:

POMERLINE 3450 EFFECTIVE DATE 10"31-8S

-SECTION 4 HEALTH SLSUS EFFECTS- -

ACUTE SKIN EPPECTS

~~~

PRIMARY ROUTE OP EXPOSURE SLIGHTLY IRRITATING TO THE SKIN ACUTE EYE EFFECTS iii SLIGHTLY IRRITATING TO THE EYES ACUTE RESPIRATORY EFFECTS MISTS/AEROSOLS MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT CHRONIC EFFECTS OP OVEREXPOSURE~~~

NO EVIDENCE OF POTENTIAL CHRONIC EFPECTS.

MEDICAL CONDITIONS AGGRAVATED ~~~

NOT KNOWN SmamS.

OF EXPOSURE MAY CAUSE REDNESS OR ITCHING OP SKINgIRRITATION AND/OR TEARING OP EYES(DIRECT CONTACT) ~

-SECTION 5-FIRST AID INSTRUCTIONS SKIN CONTACT~~~

C REN)VE CONTAMINATED CLOTHINQ.MASH EXPOSED AREl MZTH h LARGE QUAIITZTY OP SOAP SOLUTION OR MATER FOR 15 MINUTES EYE CONTACTiii IMMEDIATELYPLUSH EYES MZTH MATER P05FIS NINUTESeQSCDIATELY CONTACT A

. NSZCIAN FOR ADDITIONALTREMRENT ZNHAIATION EXPOSURE REMOVE VICTIM PRCN CONTAMINATEDhm TO PRESH AIR.APPLY APPROPRIATE FIRST AZD TREATMEIIT AS NECESSARY INGESTION~~~-

DO NOT FEED AIIYTHINQ BY MOUTH TO AN UNCONSCIOUS OR CCNIVULSZVE VICTIM DILUTE CONTENTS OF STCNACH.INDUCE VQlZTZNO bY CNE OP THE STA)IDARD METINDS.QSKDIATELY CONTACT h PHYSICIAN SECTION 6

-SPILL,DISPOSAL AND PIRE ZXSTINCTZONS SPILL INSTRllCTIONS~~~

VENTILATE AREkgUSE SPECZPIED PINTECTZVE EQQZPICNT.CNITAIX AXD MSORb ON AbSORbEIIT NATERZALoPIACE ZX 1QSTE DISPOSAL CNITAINe IHR 1lLSTE IS

CSC, IS CSSICSCW IC ICSSCISS PLUSH Aaaa MITE mm.MET AREA MAY aa SLZPPCar.IP SO,SPmaAO SAND/tRXTi>

. DISPOSAL aswarm~~~

SSSSSSS IM\\

IC IS ICSSCSCC ICCS CS PRNZTTED NLSTm IRRLS{%IT flCZL~ Ca DI5CHiMRD UÃm 4 XSQCS PRNQT P!01NCT(AS 25)

INCINERATE Ca M%X ZX 1PPRÃIRO LANN'ZLL PZRE EXTINNISHZN3 ZXSTÃCTZCNS~~~

PZREFZOHTEZS SINUS) NEAR P05ZTZVE PRES5INE SELF~ITAZXED bREATHIM APPARATUS(PULL PACE PIECE TYPE),

CONICAL/CARSON DIOXIDE~POAÃ tR 1RTER.POAÃ tR 1IATNR CRADLES 1 SLIPPERY CONDITIONoSPREAD SAND OR QRZT

MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3)

PRODUCT:

POMHV INE 3i50 EFFECTIVE DATE 10-31-88

- ECTION 7 -SPECIAL PROTECTIVE EQUIPMENT USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134.

USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS.

VENTILATION PROTECTION>>~

ADEQUATE VENTILATION RECQHMENDED RESPIRATORY PROTECTION~~~

IF VENTILATION IS INADEQUATE QR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY/

USE A RESPIRATOR WITH DUST/MIST FILTERS.

RECQNENDED SKIN PROTECTION RUBBER GLOVES WASH QFF AFTER EACH USE.REPLACE AS NECESSARY RECCNMED EYE PROTECTION~~~

SPLASH PROOF CHEMICAL GOGGLES

-SECTION 8

-STORAGE AND HANDLING PIECAUTIONS-STORAGE INSTRUCTIONS KEEP DRUMS Cs PAILS CLOSED WHEN NOT IN USE.

PlNTECT PRON FREEZING HANDLING INSTRUCTIONS>>

I%6RIATELY RKMVE CONTAMINATED CLOTHINGgWASH BEFORE REUSE NORMAL CHEMICAL HANDLING

~ 0 1 1I1 1 0 0 1 0 1II0 0 0 1 0 'N1 0 0 1 0 0 1 0 0 1 0 0 0I1 1I1 0 0 0 1 1 1I0 01 1'I0 0 0II1III1 0 0 1 11 0 0 0 0 1 10 1 ~

THIS MSDS CXNPLIES WITH THE OSHA HIKE CQSSXICATION STANDhl 4

HAROLD M. HERSH (ENVIRMENTAL INFORIRTZM COORDQQTM)

~ 1 1 00 0 1 0 0 'P 1 1 1 0 1 1 0 0 0 0I0 0 0 0 1 0 0 1 1 0 0 0 00 1I0 P 0t0 0 0000 0 111 0 0 0 0 0000t00 1 1 0 1 1 0I1 0 1 0 0 APPENDIX! REGUIATORY IXPMNLTION THE CONTENT OF THIS APPENDIX REPRESENTS INtOITIMHNllN TO MTZ OI THE EFFECTIVE DATE Of THIS MSDS ~ THIS IXtMhaTIM Z5 bRLIEVED TO SC ACCUlRTE.

ANY CHANGES IN REGtllATIONS WILL RESULT ZN UPDATED VERSIONS Of THIS DOCUMENT.

~ ~.TSCAt ALL CCNPCNlEllTS OF THIS PRODUCT ARE LISTRD IN THE TSC1 INVENTORY

~ ~.REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT!

NOT APPLZChbLE

~ ~.RCRA! IF THIS PItMQCT IS DISC1IDED 15 1 WLSTgiTHE RCRA HAZARDOU5 KLSTE IDENTIFICATIONNlMIRt IS s NOT APPLIClbLE

...IOT HAZARD CLASSIFICATIONS NOT APPLIChbLE

...DOT SHIPPING DESIGNATION IS< NOT 1PtLICAILX

~..THIS PRMPCT CMXAZNS TIRE CIZCALS KIOMN TO TIE STATE Ot CALIFORNIA TO CAUSE CANCRR CR MlRSQCTZVB TOXZCITFc NWE PRESENT IN SIGNItIC1NT hiUNTS

...SARA SICZZlR 302 CHlNZCALSs ~ PIEStlIT IN SIGIZtIClÃT llCXlNTS

".SARA SECTZM 813 CSOCCALS! ~ PRESIFT IN 5IGNItZCANT 1NRNTS I

SR I!R MSIRNOKI

>>/>>

...MICHIGAN CRITZCAL MLT~AL5< NWR PIISINT IN SIGNIFICANT 1NXNTS NtB/SOS i HEALTH - 1 l FIRE - 1; RRACTIVZTY - 0 g 5PICZAL - NK l PE - B

BETZ LABORATORIESi INC, 4636 SOMERTON ROAD p TREVOSEg PA 19047 2/22/89 DARBY MAGNA FATHEAD MINNOW BLUEOZLL SUNFISH 2/22/89 PRODUCT:

PONERLZNE 3450 AQUATIC TOXICOLOGY 04 MORTALITY: <2400 MO/L 48 HR. LC50:

3558 ~ 0 MO/L, 04 MORTALITY0 <8700 MO/L 96 HRo LC50: 19062+0 MQ/L 04 MORTALITYs 4000 MO/L 48 HR.

SCRo ORAL LD50 RAT: 16000 MO/IO D15%AL LD50 - RAIbZT 2000 ~ 00 lN/IO SKIN ZRRZTATZON SCORE NO DATA EYE IRRITATION SCORE NO DATA ZNKLZATZON NO DATA PRODUCT CONC99iTRATZON (PQR)

~

1000 Oman Dime {yya)

$00 COO 10 3LQ TOC 113

BETZ LABORATORIES,ZNC.

4636 SOMERTON ROAD/

TREVOSEg PA 190S3 BETZ MATERIAL SAFETY DATA SHEET EMERGENCY 'TELEPHONE (HEALTH/ACCXDENT) 800-877-1940 PRODUCT POWERLZNE PPL08 (PAGE 1 OF 3)

EFFECTIVE DATE 02-16-91 PRINTED:

8-APx'-1991 REVISIONS TO SECTIONS:

-;EDIT:APPENDIX PRODUCT APPLZCATIQN WATER-BASED CORROSION INHIBITOR/DEPOSIT CONTROL AGENT-

SECTION 1-----------HAZARDOUS ZNGREDXENTS-INFORMATXON ON PHYSICAL HAZARDS'EALTH HAZARDS'EL S AND TLV S FOR SPECIFIC'RODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD ZS LISTED.

REFER TO,SECT1ON 4

(PAGE 2)

FOR QUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHRONIC HAZARDS OF THIS FORMULATXQN~

THIS PRODUCT ZS NOT HAZARDOUS AS DEFINED BY OSHA REGULATXQNS.

~

If

)

~

SECTION 2-----------7YPZCAf Pt'YSXCAL DATA PH AS XS (A? PROX ~ )

FL. PT. (DEG. F):

>200 P-M(CC) vA7QR ?RESSURE (mmHG):

18 VZSC Cps70F:

42 EVAP. RATE:

ND WATER=1 PHYSICAL STATE'IQUID 1

5.2 ODOR:

SLIGHT S?

~ CRo (70F) OR DENSITY: 1. 169 VAPOR DENSITY(AIR~1): ~1

%SOLUBILITY(WATER) !

1 00 APPEARANCE:

YELLOW FREEZE POINT(DEAF):

25

SECTION 3

REACTZVITY DATA

$y \\g H STABLE ~ MAY REACT WITH STRONG OXXDXZERS. DO NQT CONTAMINATE~ BETZ TANK CLEAN-QUT CATEGORY

HERMAL DECOMPOSZTZON (DESTRUCTZV" FIRES)

YIELDS ELEMENTAL OXIDES ~

e

BETZ MATERIAL SAFETY DATA SHEET

~PAGE Z QF 3)

PRODUCT POWERLXNE PPL08

---SECTION 4-- -- -HEALTH HAZARD EFFECTS JTE SKIN EFFECTS ~** PRIMARY ROUTE'F EXPOSURE SLIGHTLY IRRITATING TO THE SKIN ACUS.'E EYE EFFECTS ***

SLIGHTLY IRRITATING ZO THE EYES ACUTE RESPIRATORY EFFECTS MISTS/AEROSOLS MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT CHRONIC EFFECTS OF OVEREXPOSURE~~*

NO EVIDENCE OF POTENTIAL CHRONIC EFFECTS'EDICAL CONDITIONS AGGRAVATED ***

NQT KNOWN

~

~em SYMPTOMS OF EXPOSURE ***

MAY CAUSE REDNESS OR ITCHING OF SKIN, SECTXQN 5------ -FIRST AID INSTRUCTIONS-SKIN CONTACT***

REMOVE-CONTAMINATED CLOTHZNG ~ WASH EXPOSED AREA WITH A LARGE QUANTITY QF SOAP SOLUTION OR WATER FOR 15 MINUTES EYE CONTACT***

IMMEDIATELY FLUSH EYES WXTH WATER FQK 15 MI-"UTER. 1rQR DXATELY CONTACT A PHYSICIAN FOR ADDZTZONAL TREATMENT.

INHALATXON EXPOSURE***

REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR.APPLY APPROPRIATE FIRST AID TREATMENT AS NECESSARY EGESTION~**

DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DILUTE CONTENTS OF STOMACH INDUCE VOMITING BY ONE OF THE STANDARD METHODS.IMMEDIATELY CONTACT A PHYSICIAN

---SECTION 6

-SPILL DISPOSAL AND FXRE XNSTRUCTIONS---------

SPILL INSTRUCTIONS***

VENTILATE AREApUSE SPECZFXED

~ PROTECTXVE,"EQUXPMEN'l'ONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTXCS OF THE-ABSORBED MATERIAL~OR ANY CONTAMINATE~OIL, SHOULD BE DETERMINED XN, ACCORDANCE, WITH RCRA REGULATIONS.

FLUSH AREA WITH WATER WET AREA MAY Shl SLIPPERY SPREAD SAND/GRIT.

DISPOSAL INSTRUCTIONS+*+

WATER CONTAMINATED WXTH THXS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACZLZTYgZN ACCORDANCE WITH ANY LOCAL AGREEMENT~A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT

~

. PRODUCT(AS IS)

INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS~~~

FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (FULL FACE-PIECE TYPE).PROPER FIRE EXTINGUISHING MEDIA:

DRY CHEMICAL,CARBON DIOXIDE,FOAM OR WATER

BETZ MATERIAL SAFETY DATA SHEET (PAGE 3

OF 3)

DUCT-'OWERLXNE PPL08

--SECTION 7 --------SPECIAL PROTECTIVE EQUXPMENT U~c,'ROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910,132-134.

USE RESPIRATORS WITHXN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS.

VENTXLATZON PROTECTION***

ADEQUATE VENT1LATXON RECOMMENDED RESPIRATORY PROTECTION***

IF VENTZLATXON IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY)

USE A RESPXRATOR WITH DUST/MIST FILTERS.

RECOMMENDED SKIN PROTECTION<+<

RUBBER GLOVES WASH OFF AFTER EACH USE.REPLACE AS NECESSARY FECOMMENDED EYE PROTECTION***

SPLASH PROOF CHEMICAL GOGGLES

SECTION 8-----------STORAGE AND HANDLING PRECAUTXONS-------

STORAGE INSTRUCTIONS**+

KEEP DRUMS 6 PAILS CLOSED WHEN NOT IN USE.

STORE IN COOL VENTILATED LOCATION.STORE AWAY FROM OXIDIZERS HANDLZNG INSTRUCTIONS***

NORMAL CHEMICAL HANDLING

- +**%*******%A%*********A'4'******A%%********4k*%*A********%**%'t%'g%%A%

THIS MSDS WAS WRITTEN TO'OMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD

- - - - 4******************4*+***4*********************

APPENDIX: REGULATORY XNFORMATZON THE CONTENT OF THXS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE

~V'FECTXVE DATE OF THIS MSDS.

THIS INFORMATION XS BELIEVED TO BE ACCURATE.

CHANGES ZN REGULATIONS WILL RESUZT ZN UPDATED VERSIONS OF THIS DOCUMENTS

~

~TSCA'LL COMPONENTS OF THIS PRODUCT ARE LZSTED ON THE TSCA XNV~'N'L'ORY

...REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT:

NOT APPLICABLE

~

~ RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE)THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS:

NOT APPLICABLE

~

~ DOT HAZARD/UN¹/ER GUIDE¹ ZS:

NOT APPLICABLE

~

~ CALZFORNIA SAFE DRINKING WATER ACT (PROPOSITION 65)

MATERIALS: NONE

...SARA SECTION 302 CHEMICALS: NONE

...SARA SECTION 313 CHEMICALS: NONE

...SARA SECTION 312 HAZARD CLASS:

PRODUCT IS NONHAZARDOUS UNDER SECTION 311/31

...MICHIGAN CRITICAL MATERIALS: NONE NFPA/HMTS:

HEALTH 1

t FIRE 1

g REACTIVITY 0

i SPECIAL - NONE; PE B

t" La

MATERIAL SAFETY DATA SHEET 6D25 01 07-85-544 DATE July 17, 1985 CALGQN-coi+01<<r<<e<<<<<<

PRODUCT NAME PCL401 suesioIARY 0F MSRCK a co..INC.

s<<<<c MANUFACTURER'S NAME Calgon Corporation r

EMERGENCY t412) 777.8000 TELEPHONE NO ADDRESS P.O. Box 1346, Pittsburgh, Pennsylvania 15230 CHEMICALNAME AND SYNONYMS Anionic Polymer FORMULA Multlcomponent Liquid

~<<<<<<<< ~ r PRINCIPAL HAZARDOUS COMPONENT (S)

CAS IT BY WEIGH ORAL LDse DERMALLOgo TLV (Unils)

ACG IH OSHA OTHE)

Chemical Name Common Name Chemical Nan'.e None Name Chemical Name Common Name Chemical Name Common Name Chemical Name Common Name

~

r tw

~ ~

<<n<<r

~~

~

~ I

<< ~

BOILINGPOINT ( F)

VAPOR PRESSURE (mmHg.)

VAPOR DENSITY (AIR~I)

> 212 Similar to Water Similar to Water SPECIFIC GRAVITY(HsO ))

PERCENT VOLATILE BY VOLUME (SS) 1.16 - 1.20 ra+ 70 4.6 N 0.2 SOLUBILITY IN WATER Complete OTHER APPEARANCE ANO ODOR Clear, slightly viscous solution While this information and recommendations set forth herein are I¹lieved to I¹ accurate as of the dare hereof, CALGON CORPORATION MAKESNO WARRANTYWITHRESPECTHERETO AND DISCLAIMSALL LIABILITYFROM RELIANCE THEREON.

r

F LASH POINT lMethod Used) o j

a Not Flammable g

~

F XTINGUISHINGMEOIA SPECIAL FIRE FIGHTING PROCEDURES Product is not flammable.

Exercise caution when fighting any chemical fire.

A self.contained breathing apparatus is essential.

UNUSUALFIRE ANO F XPLOSION HAZAROS None EFFECT OF OVEREXPOSURE A.

ACUTE ING E ST ION According to testing on the product, itwould not be considered hazardous through ingestion.

The acute oral LD50 (rats) is ) 5 g/kg.

2. INHALATION LC50 value

- not available.

The product is an aqueous solution which would not be considered hazardous through inhaiation.

3. OERMALEXPOSURE a.

TOXIC According to testing on the product, it would not be considered hazardous through dermal absorption.

The acute dermal LD50 (rabbits)~ 2 g/kg.

IAAI TAT ION Testing on the product has shown that it is not a primary skin irritant.

The primary skin irritation index (rabbits) is 0.09/8 and would be considered practically nonirritating.

c.

SENSITIZATION No cases of skin sensitization have been reported as a result of using the product.

Page 2 Of 4 IMP4544 7/17/85

4.

EYE IRRITATION The product would not be considered an eye'irritant. Testing on a 28% solution of the anionic polymer in the product produced no irritation when instilled in rabbit eyes [unwashed).

B.

SUBCHRONIC, CHRONIC, OTHER No applicable information was found concerning adverse health effects resulting from subchronic and chronic exposure to the Product.

F I RST AID A.

EYE Good'First Aid shoIIld'bIr'followed in all cases of exposure.

In case of eye contact, flush with plenty of water for at least 15 minutes. If irritation develops, call a physician.

B.

SKIN Not Applicable C.

INGESTION

~

. \\

Not Applicable

~

I

~

~ ~

O.

INHALATION Not Applicable IMP-0544 7/17/85

'7

'+

~i

,h 4

STABLE STABILITY UNSTABL ICOMPATABILITY IMaterials to Avoid)

CONDITIONS TO AVOID Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS Oxides of nitrogen a1s r'sM REPORTABLE QUANTITIES (RQ)

IN LBS OF EPA HAZARDOUS SUBSTANCES IN PRODUCT N/A 1.

2.

3.

NOTIFY EPA OF PRODUCT SPILLS EQUAL TO OR EXCEEDING N/A LBS STEPS TO BE TAKEN IN CASE MATERIALIS RELEASED OR SPILLED WASTE DISPOSAL METHOD Dispose of in accordanc~ with local, state and federal regulations.

Dike area to contain as much spilled material as possible.

Remove any remaining material by absorbing on vermiculite or other suitable absorbing material and place in a sealed metal container for disposal.

Hose spill area well since product can make floors slippery.

Dispose of in a landfill in accordance with local, state and federal regulations.

~@Q

's v.s+

ji&<<Lt.p~s~ i I i'+.(hy)~.~? Iris ~q>>)gjgg,%5K PROTECTIVE GLOVES

- Not Required t

OTHER P ROT ECTI VE CLOTHING Not Required RESPIRATORY PROTECTION Not Reqtllred EYE PROTECTION Not Required VENTILATION Normal LOCALEXHAUST MECHANICAL

{Gerterali Not Required Not Required OTHER None STORAGE & HANDLING Wash thoroughly after handling.

Keep container ciosetL Exercise caution tn the storage and handling of all chemical substances.

iTHER PRECAUTIONS Pace 4 or 4 PREPARED BY IMp~

7/17/85

VALLEY FORGE MATERIALSAFETY DATA SHEET Drew Industrial Division Asst.Arro ~QKJll One Grew lslaza, Boonton, New Jersey 07005 Phone (201) 263-7600/Telex 136444 0PR-89-1991.

87:32 FROM DREW BOONTON SALES ADNiN:

TO PA P. li 24-HOUR Emergency Telephone 1 (800) 274-5263 k 1 1 (800)

ASHLAND 008362 WPD ll-136(TM) ANTISCALANT Page:

THIS MSDS CO%PLIES WITH 29 CFR 1910.1200 (THE HAZARD CCseaJNICATIOH STANDARD) ttttttttt ~ tt ~ ttttttt ~ ttt ~ ttttttt ~ tt ~ ttt~ttttttt~ttttttttttt~t ~t ~tttttttttttttttttttttttttttttttttt

~t ~ttttttttttt Product Nrsrtes WPD ss 136(TM) ANTISCALAHT CAS HUSEJERs 9003<4-7 OLIN WATER SERVICES DIVISION DREW INDUSTRIAL DIV1$1ON OHE DREW PLAZA 800NTQN tLJ, 0700$

DISTRICT lhlNAGER 00 10 966 PRODUCT s 5520003 INVOICE~

INVO1CE DATE:

Tgs OLIN WATER SERVICES DIVISION DREW INDUSTRIAL DIVISION 80ONTTJH Data Sheet Has 0175928-002 Prepared:

03/03/87 Supersedes s

09/12/85 General or Gener{c IDs ANTISCALANT DOT Hasrard Class{f{cat{ons leT APPLICABLE

~

INQlEDIENT SODIUM POLYACRYLATE CAS Ps 9003 04 7 IF PRESENT.

IARC, NTP AND OSHA CARCIHOGEHS AND CHEMICALS SULJECT TO THE REPORT-ING REQUIREMENTS OF SARA TITLE ill SECTION 313 ARE IDENTIFIED IH THIS SECTION.

SEE DEFINITION PAGE FOR CLARIFICATION S (by WT)

PEL TLV 25-40 Note

( 1)

Notens'

1) PEl./TLV HOT ESTABLISt%0 FOR 11{IS NATERIAL Be{1{no Po{nt Vapor Pressure Spec{f{c Vapor Dens{ty Spec{f {c Grav{ty Percent Volat{les Evaporat {on Rate pH Appear ance State for PRODUCT, for PRODUCT s.

212.00 Deg F

760.00 rrssr HO 17.50 rrssr HII 68.00 Deg

(

20.00 Deg C)

LIGHTER lHAH AIR 1.150 -

1.290

{J 7/.DD Deg F

(.,25.00 Deo C) 55 70%

SLOWER THAN ETHER 5.3 5.7 CLEAR. COLORLESS TO PALE STRAW LIQUID FLASH POINT NOT APPl.i CABLE EXPLOSI VE LIMIT HOT APPLICABLE EXTINGUISHING MEDIAs HAZARDOUS DEC(XSSsOSITIOH PRODUCTS s NOT APPLICABLE FIREFIGHTIHG PROCEDURESs NOT APPLICABLK SPECIAL FIRE S EXPLOSIOH HAZARDSs HOT APPLICABLE NFPA COOESs HEALTH 1

FLAIESASILITY 0 REACTIVITY- 0 PERMISSISJ.E EXPOSURE LKVKLs HOT KSTASl.iSHEDS SEE SECTION VIII~

EFFECTS OF ACUTE OVEREXPOSVRKs EYES - CAN CAUSE IRRITATION.

SKIN CAN CAUSE SLIGHT ISNITATIOH.

SWALLOWING CAN CAUSE GASTROINTESTINAL IRRITATIOH. NAUSEA VCMITING AND DIARNXAo SREATHINGs MAY CAVSE DI~T OR IRRITATION TO NASAL ANtr RESPIRATORY PASSAGES.

FIRST AIDs IF ON SKIHs ~ROUGte.Y WASH EXPOSED AREA lriTH SOAP AND WATER.

REMOVE CONTAMINATED CLOTHING.

L V e)ER

'CDNT/oilHATED cLDTHING BEFORE RE vSE.

2

kl I*

et

~6 'l

P 4p.

Pj IVIATERIALSAFETY DATA SHEET Anxhl CtCINCAL NC.

One Drew Plaaa, Boonton, New Jersey 07005 Phone (201) 263-7600/Telex 136444 APR"89-1991 87: 33 FROM DREW BOONTON SALES ADM IN.

TO VALLEY Drew Industrial Division FORGE PA P. 12 JtVUJt Emergency

'elephone 1(800) 274-5263 or 1 (800)

ASHLAND 008362 NPD ll-136(TM) MnISCALANT Page:

2 IF IH EYES:

FLUSH WI'TH LARGE AAK)UHTS OF WATER, LIFTING VPPER ANO LOWER LIDS OCCASIONALLY.

IF SWALLOWBJr IIOEDIATELYDRINK TWO GLASSES OF WATER ANO INDUCE VCMITING BY El'IHER GIVING IPECAC SYRUP OR BY PLACING FIHGER AT BACK OF THIOAT. NEVER GIVE ANYTHING BY ICBM TO AH UNCONSCIOVS PERSON.

GET ~ICAL ATTENTIOH IPMEDIATELY.

IF BREATHEOJ REJJDVE INDIVIDUALTO FRESH AIR.

PRIMARY ROUTE($ ) OF ENTRY:

SKIN CONTACT WQAROQUS POLYlKRIZATIOHc CANNOT OCCUR STABILITY: STABLE IHCCMPATIBILITY$ AVOID CONTACT WITH), STRONG MINERAL ACIDS,

$TEPS TO BE TAKEN IH CASE MATERIAL IS RELEASED OR SPILLEOJ SMALL SPILLS ABSORB LIOJID ON PAPER. VERMICULITE, FLOOR ABSORBENT OR OTHER ABSORBENT MATHtIAL.

LARGE SPII.L: PERSONS IOT WEARIHG PROTECTIVE EOJIPMEHT SIe)ULD BE EXCLUDED FROM AREA OF SP1LL UNTIL CI.EAN UP HAS BEEN CCMPLETED.

STOP SPILL AT, SOURCE DIKE AREA OF SPII.L TO PREVENT SPREADIHG, PUMP LICVID TO SALVAGE TANK.

REMAINING LIQUID MAY BE TAKEN UP ON QND. CLAY, EARTH.

FLOOR ABSORBENT, OR OTRR ABSORBENT MATERIAL AND QOVELED INTO CONTAINERS.

WASTE DISPOSAL METHOD~

SMALL SPILLS DISPOSE OF IN ACCORDAHCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS.

LARGE SPILLs DISPOSE OF IN ACCOROAHCE WiTH hLL LOCAl, STATE Ne FEDERAL REGULATIONS.

RFSPIRATORV PROTECTIONS NOT REOJIRED UNDER NORMAL CONDITIONS OF VSE.

VENTILATION: NOT REOJIREO UNDER NORMAL COHDITION5 OF VSE.

PROTECTIVE GLOVESg WEAR RESISTANT GLOVES (CONSULT YOUR SAFETY EOJIPMEHT SUPPLIER) ~

EYE PROTECTIOH.'WEAR SAFETY GLJLSSES IH COIPLIANCE WITH OSHA REGULATIONS. (CONSULT YOUR SAFETY EOJIRKHT SVPPLIER) 00%R PROTECTIVE EOJIPMENTs NORMAL WORK CLOTHING COVERIHG ARMS AND LEGS.I' CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS %HAH EJOTIED.

SINCE Eh&TIED CONTAIHERS RETAIH PRODUCT RESIDVES (VhPOR, LIOJIO, ANO/OR SOI.IO) ~ ALL HAZARD PRECAVTION$ GIVEN IN THIS DATASHEET NJST BE OB$ERVEO.

~ INFORMATICN ACCUMJLA~i I%REIN IS BELIEVED TO BE ACCURATE BIJT IS HOT WAJIRANTED TO BE WETIKR ORIGINATING

'wITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TQ CONFIRM IH ADVANCE OF HEED THAT %% INFORMATIOH IS CURRENT APPLICABLE+ AND SUITABLE TO THEIR CIRCUMSTANCESr CAPVP Tl 'PT 1 q17 T,a CV VaCW:--CW'K'rear TaMP'.mV Taat I! RMCt.ARRO f.hCrP PAC R

MATERlALSAFETY OATA SHEET NALCO PRODUCT NA~ Q356D Emergency 7elephone Number Medical (708) 920-1510 (24 haurs)

SECTION' PRODUCT IDENTIFICATION TRADE NAME:

NAICO 8356D DISPERSAHZ DESCRZPTEONl Aqueous solution of an acxylate polymer W, ": /

/

0=Insignificant 1Mlight 2~crate 3~gh 4=E}ctrettle SECTION 2

HAZARDOUS INGREDIENTS Our hazard evaluati.on has identified the faluting chemical ident(s) as hazaxdaus under OSHA,'s Hazaxd Calmnunication Rule, 29 CFR 1910.1200.

Consult Section 14 for the nature of the hazaxd(s).

ZNGREDIENT (S)

CAS I AEPBDX.%

Sodium bisulfite 7631-90-5 1-5 SECTION 3

PRECAUTIONARY LABEL INFORMATION CAVVION:

May cause ixritatian to skin and eyes.

Avoid cca~ct with skin, eyes and cla8~p.

Do nat take internally.

unless p~mxly xeconditianed.

SECTION 4 FIRST AZD INFORMATION EYES:

SKIN:

INGESTZON:

INHM2ZZGN:

Flush with water far 15 mini;Ites.

Call a physician.

Flush with water for 15 minutes.

Do not irduce vanitiag. 'Give watex.

Call a physician.

Belnave to fresh air.

Treat synlptalns.

Call a physi.cian.

NCTE 'ZO PHYSICIAN:

No specific antiLdote is ]cnawn.

Based an the izxU.vidual reactians of the patient, the physician's judgment shard be used to cantml symptams and clinical canditian.

"CMJZION:

Zf uncansciaus, having trouble breathier or in convulsions, do nat iritucxa veal.tiTIg or give water.

SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY BQVZE(S) OF EXPOSURE:

Eye, SkiIl EYE CONIECT SKCH KRZLCZ:

May cause ixritatian with pmlanged,contact.

May cause irri.tatian with pmlanged cantact.

PRK 1 OF 7

NALCQ CHEMICAL COMPANY ONE NALCO CENTER

~ NAPERVILLE. ILLINOIS 60663-1 168 aaea one enweb nnn

"i

MATERlAI SAFETY DATA SHEET WALCO PROOUCT NA~ 8356D DISCI Emergency Telephone Number Medical (708) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION" 5

HEALTH EFFECTS INFORMATION

(

CONTINUED

}

SYMPIGHS OF ZZEGSUIK:

A reviev of available data does not. identify any synIptrzns fram exposure.

AGGRAVATION OF E}(ZSTING CONDITIONS:

A review of available data does not identify any worsening of existiag conditions.

SECTION 6 TOXICOLOGY INFORMATION ACUZE TOXICITY SIUDZES: E~a toxicity studies have been conducted an this pzadtcct:.

'Ihe results are shown belch.

ACUTE GRAL TOXICITY (AIBZNO RATS):

ID50 = Greater than 5,000 mg/kg SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COZQR Clear light green PCRN:

Liege.d -

DENSITY:

9. 6 1bs/gal.

SOIIIIKIZTYIN KZER:

Completely SHXXFZC GRAVITY:

1.16 6 76 Degrees F

pH (NEAT) =

5.7 VISCXSZTY

65 cps 6 76 Degrees F

I'REZ2Z PQZPI!:

5 Degrees F

FZASHMINI!'one ODOR:

Nane ASIM D-1298 ASIM E-70 ASIM D-2983

'SIM D-1177 NOTE:

Grese physical properties are typical values for this product.

SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH PQZNI'ane ~!

the water is boiled away.

'Ihe remainiIng organics may be-ignitable.

Use water UNUlKALFIRE AND E)tHQSZGN KQARD: May evolve NOx or SOx under fire conditions.

SECTION 9 BEACTIUITY INFORMATION

'd Mt!

which can generate heat, fires, explosions and the release of taxic fumes.

'M2%AL GEXX5tPQSITZGN PRDVJCIS: In the'vent of cambustian CO,

CO2, NOx, SOx PRK 2 OF 7

NALCO CHSMlCAL CQIVIPANY DNE NALCO CENTER

~ NAPERVILLE.,ILLINOIS60563-'1 196 NBA791 3(i'9 1lXEC)

MATERIALSAFETY DATA SHEET e

NALCn PRODUCT ~~ 8356D DISPERSAL Emergency Telephone Number Medical (708) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION, 9 REACTIVITY INFORMATION

(

CONTINUED

)

may be formed.

Da nat breathe smoke or fumes.

Near suitable protective equipment e

SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRRIURY HKKXXTICN: Respiratory prot~ion is nat normally needed since the volatility and taxicity are lear. If significant rid.~~ or aerosols are generated, wear a NIOSH approved or equivalent respirator.

For large spills, entry into large tardes, vessels or enclosed small d

breathinp apparatus is xeccmmended.

VENTXLIKXON: General ventilation is M i:

~

1 1

~

wl.

Qml fl Nil, P~

llew If Clathing iS Canta1ninatedr mumVe Clashing and tharaughly WaSh the affected area.

Laurxler contaminated clothing before reuse.

SECTION 11 SPXLL AND DISPOSAL XNFORMATION IN CASE OF TRANSPORTATION ACCIDENTS, GAL %HE FOL'GASHING 24~R TE'ZZPHClNE NUMBER (708W20-1510)

SPILL CGÃZRDL AND RZXXM!RY:

Small liquid spills:

Carrtain with absoxberrt material, such as clay, soil or any caamercially available absorbent.

Shovel reclaizjled liquid arxi absoxhent into recavexy or salvage dxulns for disposal.

Refer to CEKXA in Sectian 14.

Large liquid spills: Di3ce to prevent further navement and reclaim into recavexy or salvage dxums or tank txuck for dispos-Q..

Refer to CERCKA in Sectian 14.

DISPQStQi: Ifthis product becxxmm a waste, it does nat meet the criteria of a hazardous waste as defined un'der the Rescau~

Conservation and Recavexy Act (RCRA) 40 CFR 261, since it does nat have the chmacteristics of Subpart C,

nor is it l~al under Subpart D.

As a non-hazardous liquid waste, it should be solidi.fied with stabilizing agents (such as sand, fly ash, or cement) so that no free liquid remains before disposal to an industrial wa.~ landfill.

A non-hazardous liquid waste can also be day~11 injected in accordance with local, 'state and PAGE 3 OF 7

NALCQ CHEM!CAI COMPANY ONE NALCO CENTER

~ NAPERVILLE. ILLINOIS BQ593-1199 AREA708-305 1000.

MATERlALSAFETY DATA SHEET PRODUCT NAY~ 8356D DZSFEZSANT ZALCP Emergency Telephone Number Medical (708) 920.1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION" 11 SPILL AND DISPOSAL INFORMATION federal regulations.

SECTION 12 ENVIRONMENTAL INFORMATION If released into the environment, see CEKIA in Section 14.

SECTION 13 TRANSPORTATION INFORMATXON DCf(! PROPER SHZPEIXNG NAME/HAZtQU) CODE - PROCUCZ IS %7'EGUIATKD D3RZNG TRANSPORGIITXON

(

CONTINUED )

SECTION 14 REGULATORY INFORMATION

'Qm fo11owing regulations apply to this product.

FEZERAL REGUIATXC58:

OSHA HAZARD CCIMMUNXCKTIONRULE, 29 CFR 1910.1200:

Based on our hazard evaluation, the follmrinp irrpxdient in this prochmt is hazardous and the reason is shan belier.

Sodium bisulfite THA, 5 m~3 ACGZH/TLV Sodium bisulfite ~ THE 5 mg/nl3 ~PEL CE~SUPERFUNDr 40 CFR 117, 302:

Notification of spills of this product is not requuxd.

Q/

(TZXM IZI)

SECZXGNS 302 r 3llr 312 AND 313 SECTION 302 - KERBGK'C HAZARDCUS SUBSTANCES (40 CFR 355):

'Ignis product does not contain irxpmU.ents listed in'Appendix A and B as an Extremely Hazarchms Substance.

Our hazard evaluation has found that this pnxh~ is not hazardaus

'under 29 CFR 1910.1200.

SECTION 313 LIST OF TOXIC (XKHZCAIS (40 CFR 372):

~ prochxct does not contain irrpx6ients (at a level'f 1% 'or greater) on the List of Tcad.c chealicals.

PAGE 4 OF 7

NALCP CHEMICALCPlVlPAgy ONE NALOO CENTER

~ NAPERVILLE. ILLINOIS 60563-1 198 AREA708-305-1 OOO

8 4-4

'I qAt'

MATERIALSAFETY DATA SHEET

~

NALC0 PRODUCT NA~ 8356D DISPERSANT Emergency 7elephone Number Medical (708) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION'4 REGULATORY INFORMATION

(

CONTINUED

)

'TOXIC SUBSTANCES CORAL ACT (ESCA):

'Ihe chemical izxpmU.ents in 'this product are on the 8(b) Irrventory List (40 CFR 710)

~

SOURCE CONSERVATION AND RECOVERY ACR (RCRA), 40 CFR 261 SUBPART C 6 D:

Consult Section ll for RCBA classification.

FEDERAL WATER POZXVPZCN CXKQK)LACT/

CLEAN KQKR ACZr 40 CFR 401 15/

formerly Sec.

307, 40 CER 116/formerly Sec.

311:

'Ibis product contains the following irlgredients covered by the Clean Water Act:

Sodium bisulfite - Section 311 CEZAN AIR ACVr 40 CFR 60 I SECZIGN 111 g 40 CFR'1 g SECTION 112 product does nat cantain inpmQents cavered by the Clean AirAct.

. STKZ REGUZATICNS:

None of the chlmicals an the current Proposition 65 list are known to be present in this prIxhmt.

MICHIGAN CRITICALMATERIALS:

~ product does nat cantain ingredients listed an the Michigan Critical Materials Register.

STATE RIGHT KO EKM IANS:

The following ingredient(s) are disclosed for compliance with State Bight To Engr Laws:

'".A%I'

>>'>>(>>l r

Acrylate polymer Trade secret Sodium bisulfite 763190-5

~

Water 7732-18-5..

IÃZZZNATIGHALREGUZATIQKS:

%his is nat a WHMIS controlled pnxh1ct urder The-House of Callnmns of Canada BQ.1 C-70.

SECTION 15 ADDITIONALINFORMATION Nalco internal rnnnher F 100309 PAGE 5 OF 7

NALCD CHSMICAL COMPANY ONE NALCO CENTEA ~ NAPERVILLE, ILLINOIS BOSB3-1 1BB AREA708-3as-1 aoa

MATER!AL SAFETY DATA S H E ET e

NALC0 PRODUCT N~ 8356D DISP)~ANT Emergency 7elephone Number Medtcal (708) 920-1510 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months )

SECTION 16 USER'S RESPONS1BILITY

'Ibis product material safety data sheet provides health and safety information.

The product is to be used in applications consistent with our product literature.

Individuals handling this product should be informed of the mmzmoended safety precautions and should have access to this information.

For any other uses, exposures should be evaluated so that. appropriate handling practices and training pzograllm can be

~ established to ensure safe workplace aperations.

Please consult your ii SECTION 17 B1BLIOGRAPHY Public Health Service, PB 33 135855'983.

CASABEXT AND IXUZL'S TOXKCOZCGY, 'IHE BASIC SCIENCE OF POISONS, Doull, J.,

KLaassen, C. D., arxt A9mur, M. O., eds., Macmillian Publishing CcIapany, Inc.,

N. Y., 2nd editian, 1980.

CK.:KECAL HAKQKS OF THE WORKPLACE, Proctor, N. H., and Rx3hes, J. P., eds.,

J.

P. Lipinoott Campany, N.Y., 1981.

Nostrand Reinhold ~?anyr N Y r 6th editictlg 1984 ~

TO MM, Geneva:

World Health Organization, International Agency for Research on CMlcI~w, 1972-1977.

t"'sea

~r f +

ii..

ii eds r Jckln Wiley and Sansr N

Y g 3rd editiong Vol 2 AMg 1981 REGIS'GK OF KCIXZC ITFEXIS ON CSEKECAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, Natianal Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, GH, 1984.

Title 29 Code of Federal Regulatians Part 1910, Subpart 2, Toxic and ii

'IHRESHDLD LB'AII3ES FOR CAECAL SUBSTANCES AND PHYSICAL AGENIS IN THE i

~ iblli PAGE 6 OF 7

NAL.CO CHEMICAL COIVIPANY ONE NALCO CENTER

~ NAPERVILLE. ILLINOIS 60563-1 196 AREA708-305-1 OOO

JOHNSTON POLYMER COMPANY,!NC.

P.o. Box 86

~ Manvel, Texas 77578

~ Phone (T13) 489-9528 MATERIAL SAFETY DAT S

E SECTION I:

PRODUCT INFORMATION PRODUCT NAME: J-POLY 101C CHEMICAL FAMILY: Sodium Polyacrylate CAS NUMBERS 9003-04-7 EMERGENCY TELEPHONE NUMBER> 713-489-9528 or 713-980-7524 CHEMTREC (for emergency involving chemicals):

800-424-9300 EPA HOTLINE: 800-535-0202 SECTION II! HAZARDOUS INGREDIENTS HAZARDOUS COMPONENTS:

None SECTION III'HYSICALDATA MOLECULAR NEIGHTI 1000 pH (as is):

7 '

PERCENT SOLIDS!

50 VISCOSITY< Cp at 77 Fi 1200 PERCENT VOLATILE (Mater)'c 50 Sp.

G, at 77 F:

1.36 SOLUBILITY IN MATER < Complete APPEARANCE AND ODOR~ Viscous liquidt clear to hazy No characteristi "o or 1

SECTION IV! FIRE AND EXPLOSION HAZARDS FLASH POINTs None EXPLOSIVE LIMITS~ None EXTINGUISHING MEDIA> Not applicable>

product vill not burn NFPA CODES'EALTH 0g FLAMMABILITY Og REACTIVITY 0

SECTION V! HEALTH HAZARD DATA Toxicological Information (Range Finding Studies):

Rati

- Acute oral LD50 greater than 5g/kg Rabbit>

Acute dermal LD50 greater than 5g/kg Rabbit's Eye irritation slight Rabbit<

Skin irritation none Daphni a r 48 hour5.555556e-4 days 0.0133 hours 7.936508e-5 weeks 1.8264e-5 months LC50 greater than Sunf ish, 96 hour0.00111 days 0.0267 hours 1.587302e-4 weeks 3.6528e-5 months LC 50 greater than

'Trout>

96 hour0.00111 days 0.0267 hours 1.587302e-4 weeks 3.6528e-5 months LC50 greater than Product does not contain carcinogens sub)act to the reporting requirements of SARA TITLE III.

1000 ppm 1000 ppm 1000 ppn1-HMXS RATING HEALTH 0 g FLAMMABILITY 0 g REACTIVITY -

0 May cause irritation of skin and eyes.

For eye contact, flush with water for 15 minutesy get medical attention if irritation persists.

Mash skin with soap and vater.

4

SECTION VZs REACTIVITY DATA product is stable; vill not undergo hazardous polymerization.

SECTION VZI: SPZLL OR LEAK PROCEDURES Dilute spill with small amount of water and use absorbent.

Land fill in incinerate contaminated absorbent.

Carry out disposal in accordance vith federal> state nnd local regulations.

SECTION VIII: PROTECTIVE EQUIPMENT REQUIRED Respiratory protection is not required.

Use rubber gloves<

boots and apron for direct handling.

Use face shield or goggles for eye protection.

SECTION IX! SHIPPING INFORMATION/OTHER COMMENTS Doi IDENTIFICATION NUMBER: N/A DOT LABELS REQUIRED:

None HEPORTABLE QUANTITY! N/A BILL OF LADING DESCRIPTION~ Cleaning/Hashinj

ComPound, NOZ PREGAUTZONARY MEAsUREss Keep avery from heat or open flame.

Use with adequate 'ventilation.

Do not breath vapors.

Avoid prolonged or repeated contact vith skin.

DEFINITIONS NFPA RATINGS System adopted by Nationa1 Fire Protection Association to identify hazards in a firy situations 0

~

No knovn hazard 3 '~ 'evere hazard 1

~ Slight hazard

. 4 = Extreme hazard 2

= Moderate hazard MIS RATINGs Hazardous Materials Identification System adopted by the National Paint S Coatings Associationi 0

~ Minimal hazard 3

~ Serious hazard 1

Slight hazard 4 = Severe hnznrd 2

~ Moderate hazard

= May be chronic cAs NUMBER< chemical Abstracts service Number

-SARA: Superfund Amendments Reauthorization Act of 1986 (also referred to as the "Emergency Planning and Community Right To Know Lav of 1986")

DOT: Department of Transportation Revised Feb.

1, 1990

.Supercedes Mayi 1985

BETZ INDUSTRIAL i63G 90t1ERTON ROAD TREVOSEi PA, 19047 BETZ t1A TER I AL SAFKTY DATA SHKKT HOUR Et1ERGENCY TELEPHONE

( HEALTH OR ACCIDENT ) 215/355-3300 PRODUCT

~ CLAt1'TRGL CT)

EFFECT IVE DATE 1 0-31 -88 PR INTED: 12/28/88 PRODUCT APPLICATION WATER-BASED HICROBIAL CONTROL ACKNT.

---SECTION 1-----------HAZARDOUS INGREDIENTS INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PKL'S AND TLV'S FOR SPKCIF IC PRODUCT INGREDIENTS AS REQU I RED BY THE OSHA HAZARD COt1t5UNI CAT IONS STANDARD ARE LISTED REFER YO SECTf04 4

(PAGE 2)

FOR OUR ASSKSStIKNT OF THK POTENTIAL ACUTE AND CHRONIC HAZARDS OF THIS FORHULATION.

4<<>>

ETHYLENE GLYCOl i~~CASe107-21-1)LIVER, KIDNKY AND bLOOD TOXIN;CNS DEPRESSANT; ANIttAL TERATOGEN(HIGH ORAL DOSES); PKL: NONE; Tl V: 50PPt5( CEILINC),

a ALKYL Dlt1ETHYL BKNZYL At1t)ONIUt1 CHLOR IDE1oeCAS0604t4 d5 5 'ORROSIVE(KYKS);

PKL NONE;TLV:NONE.

~

li'SOROB'YL ALCOHOL+

( IPA ); CASO&7 63.

0 SLAN5ASLK>> LlaVID;CHRONIC OVEREXPOSURE t)AY CAUSK LIVER AND KIDNKY TOX!CITYJ tKL/TLV:400PPN.

DODECYLCUANIDINK HYDROCHLORIDKepo(DQH).,;CISI535$ 0 $7 5; CORNOOIVK;PEL: NONE; TLV:NONE.

1<< 'P%

Ol! ~

~

e

~~'y~

~ <<g

"~" "~>>>>>>tp

"',> 4%>> s

',h>>rg

~ ~ >ax >>>>>

s h,>

<<>> ali)tl', c

~<~V

~

=4 ~

SECT ION 2

.~

TYP ICAL PH'fSICAL -QATAR'

~

la PH:

AS I S (APPRO)(i,)q S. 3 "ODOR: jlILD-;,

FL.PT. iDEG.F):

55C SKTA(CC)

SP.CR. (70K)OR DRHSITY: 5.0QR VAPOR PRESSURE

( ooHO 1>> 23,,

~

~ VAPOR DfNQY (AIR5,)>>,

> 5. r,.

>><<c VISC cps70F: 23,,

=

XSOLUSILITY(MATfk): 500 f"'VAP

. RATE:

(5 ETHER~1 APPKARANCa:

COI OILKSS PHYSICAL STATE: LIQUID FRffZm POiNT(DgQ,I',):

< 30 4

~

-" ~ 4 ~

-SKCTION 3 REACTIVITY,,DhTA..~.

~ >>

~

STABLE

'Rt5AL DKCOt(POSITION (DESTRUCTIVE FIRKS) YIKLDO CLK55KNTAL OXIDKS

MaTERTAL SAFETY OATA SHEET (PAGE g

OF g)

KFFKCTIVK OATK ROOVCT:

CLAM'TROL CT>

SECTION 4-- --------HEALTH MA2ARO EFFECTS CUTE SKIN EFFECTS PRIMARY ROUTE OF EXPOSURE CORROSIVE TO SK?N.l OTENTIAL SKIN SENSTTIZER CUTE EYE EFFECTS CORROS I VE 70 THE KYES CVTK RESP?RATORY EFFECTS

+++

PRIMARY ROVTE OF KXPOSURK VAPORS'ASKS MISTS ANO/OR AEROSOLS CAVSK IRRITATION TO VPPER RESP IRATOR Y TRACT HRON I C EFr 6'C TS OF OVER EXPOSURE + + +

PROLONGEO

~'..R REPEATED OVEREXPOSVRES MAY CAUSK: TISSUE NECROSIS)BLOOD CELL DAMAGE OP l.")PAIR BLOOD CELL FVNCTION'KPRODUCTIVK SYSTEM TOXICITY; SKIN SENSITIZATION.

EDICAL CONOITIQNS AGCRAVATEO >>>>>>

NOT KNOLJH YMPTOMS OF FXPOSVRE INHALATION OF VAPORS/MISTS/AKROSOLS MAY CAUSE EYEgNOSKgTHROAT AND LVNC TRRITATIOV;SKIN CONTACT MAY CAUSE SEVERE IRRIThTION OR BURNS.

'RKCAUTIONARY STATEMENT BASED ON TKSTINC RESULTS moo MAY BK TOXIC IF ORAI.LY INCKSTKD".

. -SECTION S-------- ---FIRST ATD INSTRUCTIONS

~KIN.CONTACT+>>>>

RKMQVK CLOTHINC.I>ASH AREA lJITH LARCK AM4UNTO QP'OAP'OI UTION ON MATER FOR t5 M!N.IMMEDIATELYCONTACT PHYSICThN

.YK CONTACT>>>>>>

IMMEDIATELYFLUSH EYKS WITH lJATKR fOR 1$ MINUTES. IMMEDIATELYCONTACT A PHYSICIAN FOR aOOITIONAL TREATMENT NHALATIQN EXPOSURE +>>

REMOVE VICTIM FROM,CONTAMINATED ARKA.APPLY NKCKSSARY FIRST AID TREATMENT. IMMEDIATELY CONTACT A PHYSICIAN.

NCKSTIQN>>>>i OO NQT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO,QQT It)OVCE VOMITING.IMMED.CONTACT I HYSICIAN.DILUTKCONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER

--SECTION 6- --->>------SP ILL,DISPOSAL AND FIRE INSTRUCTIONS

~PILl INSTRVCT TON= >>>>>>

VKNTTLATE AREA ~ USE SPECIFIED PROTKCTIVK KOUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE TN lJASTE DISPOSAL CONTAINER.THE CONTAMItlhl':O AQSORSENT SHOUI D BE CONSIDERED A PESTICIDE AND DISPOSED QF IN hl4 APPROVED PESTICIDE LANDPILl

~ SEC PRODUCT LASEI STORAGE AND OISPONAL INSTRUCTIONS.

REMOVE IGNITION SOURCES FLUSH AREA IJITH MhTER.SPREAD I

SANO/GRIT

) TSPOSAL INSTRU>.'T IOUS>>>>e MATER CONTAMINATED LJTTH THIS PRODUCT NAY IE SENT TO h SANITARY SEVER TREATME"IT FACILITY,IN ACCORDANCE QITH AliY LOCAL ACREEMENT A PKRMITTFO WASTE TREATMENT FACILITY OR DISCHARCKD UNDKR h NPDKS PKRtlIT PRODUCT(AS IS)-

BURY IN AH APPROVED PESTICIDE FACILITY QR DISPOSE OP IN ACCORDANCE 4 I TH LABEL INSTRUCTIONS IRE EXT'INGVt. HJ?JG INSTRUCTIONS>>>>>>

FIREFTGHT Q

=..)<OI>LO UKASE PQSITIVE PRKSSURK SELF CONThlNKD BREATHINC APPARATVS<<VLg PACE-PIECE TYPE).

ORY CHEMICAL, '. '"Bl)N DIOXIDK,FOAM OR WATKll

HATERIAL ShfETY DATA SHEET (PACE 3 OF 3) e

.ODVCT:

CLhN'TROL CT1 EFFECTIVE DATE 10 31-88

SECTION 7- -

- SPECIhL PROTECTIVE EQUII t1ENT

>SE PROTECTIVE EQUIP)(ENT IN ACCORDANCE WITH 29CFR SECTION 1910.132 13$.

USE ESP IRATORS lJITHIM USE LIHIThTIONS OR ELSK USK SUPP! IED hiR RESPIRATORS.

'KNTILhTION PROTECTION<<<<<<

ADEQUhTE VENTILATION TO tlhtNTAIN AIN CONTAHINANTS BKI Oll EXPOSURE Ltl1ITS

,'ECOHHKNDED RESP IRhTORY PROTECTION<<ee tf VENTILATION IS INADEQUhTE OR SICNIFIChNT PRODUCT EXPOSURK iS LIKELr, USK h RESPIRATOR l4ITH ORQANIC VAPOR CANTNIDCKS hND DUST/)IIST PREFILTKRS.

.'ECONtlENDKD SKIN PROTECTION<<ee QAUNTLET-TYPE nubbEN CLOVES.CHEHtCAL NKSISTANT htNON WhSH OFF AFTKN KhCH USE.REPLACE hS NECESSARY

.'ECOHtlKNDKD EYK PROTECTIONeee SPLhSH PROOF CHKHIChL QOCCLES.FACE SHIELD

SECTION 8-------STORACE AND HANDLINO tNKCAUTIONS-3TONACK INSTRUCTIONSeee KEEP DRUNKS I PAILS Cl.OSED IJHEN NOT IN USC.

STORK IN COOL VENTILATED LOCATION.STORK AMAY FNOll 4XIDIZKNS IhNDLiNC INSTRUCTIONSeee IH)(EDIATELY RKHOVK CONTAMINATED CLOTHINOg MASH IKFONg REUSE CONSUSTtbLK.

DO NOT USK AROUND SPARKS ON FLANKS. bOND C4NTAINKNS DUNINO FILl INO ON DISCHARQK IJHKN PKNFONt(KD AT TK)ltKNATVNKS AT ON t

ASOVK THK PRODUCT FI ASH POINT.

>oeeeeeeeeeeeeeeeeeoeee

~ e<<eeeeeoeeeeoeeeeoeeeeeoeeeeeeeeooooeeeeoeeeeeeee

.IS HSDS CO)ltLIKS MITH THK OSHA HAZAND CO)(IIUNICATION STANDAND

<ANOLD t(.

HKNSH

( ENVIRONMENTAL INFORMATION COONDINATON) seeoeee<<<<eeoc<<e<<eeoeeeeeeee<<<<eeeeeeoeeeeeooeeoooooooeeoeooeooooeoeeeeeeeee hPPKNDiX:.NKCVLATONY INFONNATION rHK CONTKNT OF THIS APPENDIX REINKSKNTS tNI ONi(ATION l(NOMN TO bKTZ ON THK

FFKCTIVK DATK OF THIS )(SDS.

THIS IKFONHATION IS SWLIKVKD T0 SC ACCVNATK.

INY CHANCES IN RKCULATIONS MILI NKSVLT IN VPDATKD VCNSIONS 4F THIS DOCV)IKNT.

... TSCA:

ALl COMPONENTS OF THIS tNODUCT ANR LISTRD IN TH% TSCA INVENTORY

~. FIFNA(AOCFN): Kl h NKO ~ NO. 307l 14$

.. REPORTABLE QUANTITY(NO) FON UNDILUTKD tNODUCT:

IOT APPLI CAQLK

..RCRA: IF THIS tN40UCT IS DISCANDKD AS A MASTmiTHm NCNA HAZANDOUS MASTE (DKNTIFICATION NUllSSN IS! D001otONITAILKiDOOa<CONNOSIVK

..DOT HAZARD CLASINDICATION:

CONNOSIVm TO SKIN.COllOUSTILLt

~ DOT SHIPPINO DROIONATION iS:

UN1740 CONNOSIVC LIQUID N.O.S.

THIS PRODUCT CONTAtNS THESE CHK)(ICALS 1(NOMN TO THE STATC'F CALIFORNIA TO

A SK CANCER ON NCtNODUCTIVK TOXICITY: NONa tNfSRNT IN SIONIFICANT hl(OUNTS

~.. SARA SECTION 302 CHK)(ICALS:

NON% tNRSfNT IN SIONIFICANT AMOUNTS

~

~ SARA SECTION 313 CHRNICALS: ETHYLKNa OLYCOL(107 at 1 )

p 21. 0 30. OX

...SANA SECTION 318 HAZAND CLASS:

l)(llKDIATC(ACUTE)i DCLAYKD(CHNONIC) AND l INK

~

~.NICHICAN CRITICAL NATKNIALS: NONE tNKSKNT iN SIONIFICANT Al(OUNTS Vfth/HUIS: HEALTH 3

3 FiRE 2

'g REACTIVITY 0

) StaCIAL CONN 3

PR D

BETE LABORATORZES, ZNC.

4636 SOMERTON ROAD, TREVOSE, PA. 19047 2/22/89 RAZNBOW TROUT DAPHNZA MAGNA FATE%AD MZNNOW 2/22/$ 9 ORAL LD50 NO DATA DERMAL LD50 NO DATA PRODUCT:

CLAM TROL CT 1 AQUATZC TOXZCOLOGY 0% MORTALZTY: 10 MO/L 96 HRo LC50:

14o7 MO/L 0\\ MORTALZTY: 0 ~ 16 MG/L 48 HR. LC50!

0.4,.MG/L 0\\ MORTALZTY: l.55 MO/L 96 HRe LC50c 3 ~ 0 lN/L MAMMALZANTOXICOLOGY SKIN ZRRZTATZON SCORE NO DATA EYE ZRRZTATZON SCORE NO DATA

'NHALATZON NO DATA

, ~

~ ii r

MATERIAL SAFETY DATA SHEET 6341-10-15-86-568 DATE March 13, 1990 PRODUCT NAME H-130 Microbiocide CALGQN c 0 II o 0 iio s I 0 a SUBSIDIARY OF MERCK S CO..INC.

MANUFACTURER'S NAME ADDRESS Calgon Corporation EMERGENCY TELEPHONE NO.

(412) 777 8000 CHEMICALNAME ANO SYNONYMS Microbiocide P.O. Box 1346, Pittsburgh, Pennsylvania 15230 FORMULA Multicomponent Liquid e

it r'

g PRINCIPAL HAZARDOUS COMPONENT (S) cr amicai Didecyl Dimethyl Ammonium Chloride Cornrnon-Nsrne CAS g 7173.51.5 BY WEIGHT 50 450 mg/kg Not

. Available ORAL LDso DERMALLDso Not Listed Not Listed N/A TLV (Units)

ACGIH OSHA OTHER Chemical F

Common Name Ethyl A(Cobol Chemical Noma

~

Common Name Chemical Name Common Nome Chemical Name Common Nsnio 64-17-5 10 14 g/kg Not Available TWA.

PEL -

N/A 1000 pp 1000 ppm r

Q s

s BOILINGPOINT I')

VAPOR PRESSURE (mmHg.)

VAPOR DENSITY (AIR~1) 212 Unknown Unknown SPECIFIC GRAVITY(Hs 0~1)

PERCENT VOLATILE BY VOLUME ('Yo) pH 0.9 50 7.3 - 9.0 SOLUBILITYIN WATER Complete OTHER N/A APPEARANCE AND ODOR Colorless to yellow, slightly viscous liquid N/A ~ Not applicable kVhile this information and recommendations set forth herein are believed to be accurate as of the date hereof, CALGON CORPORATION MAKESNO kVARRANTYlVITHRESPECTHERETO AND DISCLAIMSALLLIABILITVFROM RELIANCE THEREON.

Pago 1 of 4

~

I.ASH POINT Method Used

'ISHING MEDIA

- SPECIAL FIRE FIGHTING PROCEDURES 115oF (C.O.C); This product is combustible.

Use dry chemical, foam, CO2 Exercise caution when fighting any chemical fire. A selfwontained breathing apparatus and protective clothing are essential.

UNUSUALFIRE AND EXPLOSION HAZARDS None EFFECT OF OVEREXPOSURE A.

ACUTE I ~

IN G ESTION This product may be expected to be harmful or fatal if swallowed.

2. INHALATION This product is expected to present a Iow potential inhalation hazard.

3. DERMALEXPOSURE a.

TOXIC This product would not be expected to produce systemic toxicity ifit is absorbed through the skin.

b.

I R RI TAT ION This product may be expected to cause burns upon contact with the skin. The severity of the burn is generally determined by the concentration of the solution and the duration of the exposure.

c. SENSITIZATION No data were available to suggest that this product may produce an allergic skin reaction Page 2 of 4 IMP.0568 3/13/90

r, a

4. EYE IRRITATION This product may be expected to cause burns to the eye.

SUBCHRONIC, CHRONIC, OTHER No data were available to indicate that this product may produce adverse health effects followingsubchronic or chronic exposure.

F IRST AID

~gP+t<I@ ~6g quirk)

. ~

g %~aRa~gg%

0 A.

EYE In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.

Seek medical aid.

B.

SKIN In case of contact, immediately wash with soap and plenty of water for at least 15 minutes.

Seek medical aid.

Remove and wash contaminated clothing before reuse.

C.

INGESTION Ifswallowed, drink promptly a large quantity of milk, egg whites, gelatin solution: or ifthese are not available, drink large quantities of water. Avoid alcohol.

Call physician immediately.

NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage.

Measures against circulatory shock, respiratory depression and convulsions may be needed.

D.

INHALATION Not applicable IMP.0568 3/13/90 Page 3 of 4

gl k

r P

STABLE BILITY UNSTAB

'FATABILITY

'\\

.als to Avoid)

X CONDITIONS Store away from heat and flame. Do not contaminate water, food or feed TO AVOID by storage or disposal.

Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS During decomposition, NH3 may be released.

~I ~

~ k REPORTABLE QUANTITIES IRQ)

IN LES OF EPA HAZARDOUS SUBS

~ ANCES IN PRODUCT 1.

2 N/A NOTIFY EPA OF PRODUCT SPILLS EQUALTO OR EXCEEDING N/A LBS.

ST;?S TO BE TAKEN IN CASE M-I'ERIAL IS RELEASED Ch SPILLED Dispose of in accordance with local, state and federal regulations.

Pesticides are acutely hazardous.

Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal law.

WASTE DISPOSAL METHOD Dispose of in a landfill or incinerate in accordance with local, state and federal regulations.

This product is toxic to fish. Oo not discharge into lakes, streams, ponds, estuaries, oceans, or public waters unless in accordance with NPDES permit. Do not discharge effluent containing this product to sewer systems without previously notifying the sewage treatment plant authority.

For guidance, contact your State Water Board or Regional Office of the EPA. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency or hazardous waste representative at.the nearest, EPA,Regional.Office,fo~ruidance>

~~~~~~~

+w~'v'~r."=.'":<~"=~~;--'F-rggFi&Rg tG~

PROTECTIVE GLOVES HER PROTECTIVE CLOTHING Rubber Not required EYE PROTECTION Chemical splash goggles or face shield

~ RESPIRATORY PROTECTION Not required, however ifthe recommended ACGIH-TLVor OSHA-PEL for ethyl alcohol is exceeded, then a NIOSH/MSHA approved respirator should be used.

(See Section II)

VENTILATION LOCALEXHAUST Recommended MECHANICAL Recommended (General)

OTHER Use only in well.ventilated areas that will maintain air levels below limits established by local, state and federal re ulations.

STORAGE 8c HANDLING DANGERI Corrosive.

Causes severe eye and skin damage.

Harmful or fatal ifswallowed.

Do not get in eyes, on skin or clothing.

Wear chemical splash goggles or face shield and Avoid contamination witlkfo'od.'.'-'ubber gloves when handling.

kk Pk k

ER PRECAUTIONS k

For container disposal, triple rinse (or equivalent).

Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by other approved state and local procedures.

N/A ~ Not applicable Price 4 of 4 PREPARED BY Patricia A. Pacella IMP.0568 3/13/90

4~

I P'1

II ~

A 88/1S/1991 18:57 FRY CTS SNARKETING TQ VALLEY FORGE P.83 MATERIAI SAFETY DATA SHEET I

QFOQt IfldUStFIQl NVl8lOA Emergency A5MLAJ CAIQC4L IWC'.

Te)ephone one Dr ~

etc'on on'sleYe Jeteey o5 L(800) 274 5263 Phone 1201) 26S-7600/Telex l38444 000034 OLIN 3204 ALGICIDE Page; THIS IISOS COOLIES WITH 29 CFR 1010.1200 (9% HAZARD CONNHIICATIOH STAHOAAO)

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~Jilleeeeeletott Product Hans OI IN 3204 AIOICIOE DREW INDUSTRIAL DIVA eVI7 W.

110Tli ST, iI00 OVERLAND PARA. X4'S82 IO 0O 01 013. 0003883-404 PROOU)T:

IHVOI Ei~

REOST INVOICE DATE) 01/30/01 TOi Data Sheet HOr 0248054-002 prepareoi f1/I)/Ql Supereeoeei 1/0 /

General or Oenertc IOI ALOICIDd OOT Haeara Claeetf teat loni HOT APPLICASLP.

IHOAEOIEHT OUATEANAAYANIHILNCONl POLYE~XVLATS E

)NO AgJR54liTM OP SARA TITLE I)QSEQIOH 31+ARE fOEHIQ8lPPI4 llilSMR

% (by WT)

PEL TLV 10"25 Note (1)

HoieeI

(

1) PEL/TLV HOT L5TAQJQ%0 POR llIIS NTERIAL botlln0 Potnt vapor Preewre P

fOI'OPOHENT(

70-88%)

for COwOHEHT(

I ill:m QNcl

'3m~

Speotf te Vapcr Oenatty AIR ~

1 Specific Oravtty

> 1,0 Percent Vo 1at Ilee dvaporat ton Rate hppearaIce State 77,00%

SLOWER~ H)IER CLEAII LIOIT YELLOW LIQUID PLAN POINT NOT=APPLICQQ t ~

EXPLOSI Vm LiNT NOT APPLICMN I, EXTIHOUISHIH4 MQAI NTRN IKO P MmPQ QIWIIQOECQOQITIOHQR CSOUST)OH itIY PIIOOUCSI CARSON DIOXIDE AHO CAARON PIAgfyHggPlg~@Wfg +-ggAIHHO PKVlliliHIAPPAAATUQ /TH A FULL PACEPIECE OfmtATEO IH ll% POSITIVE WATlbt INY N U380 TO RXTIlCNISHfNt BY COOLINO, ANO OILUTIHO 1 IQUIO WI& teeTKRE SPECIAL PIRa 8E WOSION HAXMOSI HOT APPLICASLE HF PA CNESI WALllt. 1 PLiNNILITY-1 REACTIVITY- 0 PMCSSIKR aXPOSN%'SVLI HK ESTAN.IORD.

EFPaCrS Of ACUTa OVaR8XPOSURSI

)Nfii ~ CAN IOfT !

IAEAINIIO INetif@ VAICNLCAN CAUSE NELS ANU AEQRRAICRT [RRITATICN PIAST AIDE I P oH SRIHE TlcMRoe Y wAsH ExPosED AREA wITH soAP AND wATER REjevP. COHTAilIHATEo cUlT)IIN0A v4NDEA coaTAINHATwo QADI& iio eerote It~ac N

88/151991 11:81 FRY CTS &NARKETIHG TQ VALLEY FORGE NIATBRIALSAFETY DATA SHEET Drew Industrial Divisian hsNIue aweek', ec.

One Drew Plese,

boonton, New Jersey 07005 Phone (201) 263-7800/Telex 138444 PE 89 24-HOUR Emergency TeLephone 1(800) 274"5263 or L(800)

ASHLAND aaaa34 OLIN 3204 ALQICIDE Page:

2 ATTEHTIOH, IF IRRITATION PERSISTS.

IF SWALLOWED) DD NOT INDUCE VCMITING, IIbSKDIATELY DAINK TWO GLASSES OF WATER)

NEVER GIVE ANYTHING SY MOUTH TO AN UNCOISCIOUS PERSOHP CALL PHYSICIAN OR TRANSPORT TO AH PAJSENCY FAC!LITY.

IF BREATHED( IP AFPKCTED AE)IVE INDIVIDUALTO FRESH AIR, IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN 1F 8REAIHING HiS STOPPkl GIVE ARTIFlCIAL RESPIRATION ~

KEEP PERSON WARM, QUIET AND GKT MEDICAL ATTENTfOH, PRliMRY ROUTE(S) OI'NTRYI INHALATIONP SKIN COHTACT HAZARDOUS POL~IZATICHs CA)bK)T OCCUR STADILITY! STAbLE INCCWpATIblLDYI AVOID COHTACT Wl'IHr E EXCESSIVE %AT, STRONG OXIDIZING AGEHTSP E

STEPS TO KE TAKEN IN CASK MATERIAL IS RELEASED OR SPILLED:

SMiLL SPILLI PERSONS HOT WEARING PROPER PERSONAL PROTECTIVE EQUIPPIHT SKULD KK EXCLUDED PRON AREA OF SPIlL, hbSOIb lslQUID ON PAPER ~ VERMICULITE~

FLOOA AbSORKENT OR OTHER ASSORQENT MATERIAL~

BEEN IVNPLETR EVOP )PILL ATIOIIICE OIIK AREA OP EPII.L QTPRENT EPIFEQAI~ONPlkaiggAI TAI TANK.

PREVENT AUHMF TO SEWERS, STREAMS OR OTHER bODIES OF WATER, IF RUNOFF OCCURSP NOTIFY PROPER AUTHORITIES AS RKQUIRKDR TNT A SPILL Hib OCCUREDP E ~

WASTE DISPOSAL ial)KK)>

SMALL SPILLr DISPON OF IN ACCORDANCE W!TH ALI. LOCALE STATE AND FEDERAL RKGULATIOHS.

LARGE $PILL) DISPOSE OP IH ACCORDANCE WI1H ALL LOCAL, STATE AND FEDERAL RKGULATIOHS, E

RESP IRATOIY P OV HA SEEN DETERMlHED OA DOCUMEHTKDP h HIDSH/MSHi JOINTLY APPROVED AIR SUPPLIED R

1 OF PROPER KNVIRONMHTALCONTROLS OSHA REGULATIONS ALSO PKRMlT OTHER HIOSH/

SPECIFIED CONDITIONS, jSEK YOUR SAFETY KQUIPIKHT $UPPLIKR) ~ ENGINEERING Ql AMH1$TRATI bK Iib LBKÃfKDTO RKDUC EXPOSURE.

VKNTILATIONtPROVIDE SUFFICIENT %CNHICAL (GENERAL AHDIDA LOCAL EXHAUST) VENTILATION TO NIHTAIN EXPOSURE SELOW LKVKI.I OVEREXPOSURE ( RNI KNON, SUSPECTED DA APPAAENT ADVERSE EFFeCTS),

PROTECTIVE GLOVESI INAR RESISTlNT GLOVES SUCH ASIA NA'IlAIALRUMER KYK PROlKCTICNc CHEQ~QQlg+Kp IH CNOLIANQK WITH OP AEGULAT1ONS ARK ADVISED@HIIWKVER, OSHA OTHE'AOTECTIVE KQUIPSMBITs TD PREVENT SKIN CONTACTS WEAR IMPERVIOUS CLOIHIHG AND 800TSE EYEWASH STATION SSRGKNCY 5NNS.

COHTAINKRgOF Wg MATERIA Miy q HAZARDOU~INII~lg yIICE SOT)ED COHTAINKAS AETAIH PAIICT RESIDUES KEEP FR(EI FREEZING.

INFOAiMTIOH Ac554LATKD IRRHN 1$ bKLIKVKDTO bK ACCURATE bUT IS NOT wAARANTKD TO bK IbIKTHER'ORIGINATING wITH llew cINP Hg~ RQIPIKHTs ARE ADYIsKD T caHFIRM IN ADYANcK DF HKKD ~T. T$$ IHRNAITIIRIIs CURRENTS A I, TlbLK TO TlCIR CI lNCKS.

88i15i1991 18: 59 FROM CTS KMARKETING ygws-Fet0wl MstftItal Safety Data Sheet TO VALLEY FORGE IJi LtfV ItlLOLtOsslAI anwenearee A~ecKucaa ~pa% & A~o>.etc, One Dew Piete. Boenton. New Jeraey 070{5 Prewar iebn Ã4rbbbrreiew 1bt444 24 HOUA EMEAGENCY TELEPHONE go/324 It33 P. 86 0EFlNITIONS This definition oage Is Intended for use with Malarial Safety Data Sheets supplied by the Drew Chemical Corporation, Recipients of these data sheets should consult the OSHA Safety and Health standards Q9 CFR tatg}, particularly

~ubpart G ~ Occupational Health and Environmental Control and subpart I ~ Personal Protective Equipment, tor general guidance on control of potential Occupational Health and Safety Hazards.

OEXERAL OR OEXERIC ID: Chemical family or product description.

DOT HAZARDCLASSIFICATION.'roducl meals DOT criteria for hazards fisted.

Comoonents are listed ln this section Ifthey present a vs)cai or health hazard and are present at or above Yo in the mixture. If a component ls Identified as a RCINOGEN bv NTP, IARCor OSHA as of the date on the MSDS. It wiIIbe lltlad and,footnoted ln this teclion when present at or above O.t Ye In the product, Nega.

tive conclusions concerntntt carcinogenicity are not re-oorted. Additional health Iftformation may be found In Section V. Components sub}act to the reporting re-auirements of Sectlcn 3t3 of SARA Title ill are idenli ~

ed in the footnotes In this section, along with lyplcai percentages, Other components may be listed II deemed appropriate.

Exposure recommendallons are for components, OSHA Permissible Exposure Limits {PELs) and American Con.

4 ence of Governmentfi) Industrial Hyglenists (ACGIH}

reshold Limit Vaiues tTLVs}appear on the line with the component IdentifIcation. Other recommendatlons appear as footnotes.

8OIUNC PONT, Of product if known. The lowest value ol the components ls listed for mixtures.

'APOR PRESSUREI Of product If known. The highest value of the components ls listed for mixtures.

SPECIFIC VAPOR DENSITY; Compernd to AIR ~ f. If Specific Vapor Density of product is not known. the value Is expressed as lighter or heavier than air.

SPECIRC ORAVITY: Compared to WATER ~ f. If Specific Gravity ot product ls nol known. the value is expressed as less than or greater than water, pH. Ifapplicable, PERDENT voLATILEst Percentage of malarial with Ini-

'ial boiling point below 426 degrees Fahrenheit.

EVAPORATION RATit IntNcated as faster or Slower than ETHYl. ETHER, uniess otherwise stated.

FLASH POINTt Methotf Identifietf, EXPLONOX LIMITS'orproduct Ifknown. The lowest value of the corn ponen! s is titted for mixtures.

HAZARDOUS DECONIPOSITION PftODUCTS.'nown or expected hazardous products resWtlng from heat.

Ing, burning or other reactions, EXTIXQUISHINO

'ottowtng National Fire Protection crfterta.

FIREFIO 0 PROCtNfRES; Minimum ettutpment to orotect tee ttudc

~ of vapoNza-or tlon In fire situations, Other ttng htaarda may also be indicated.

SPEOAL FIRE ANO SIPLOSfON HAZARDS; States hazards not covered by other sections.

"".".iMKM~CC~W"'"

PERMISSIILE EXPOSURE LIMITS For product.

THRESHOLD LIMITVALUEl For product, EFFECTS OF ACIJTE OVEREXPOSURE.'otenllal local and systemic effects due to sinttle or shor l term overexposure to the eyes andPskln or through in.

haiallon or ingestlon-EFFECTS Or CHRONIC OVEREXPOSURE! Potential ocal and system}c effects due to repeated or long erm overexposure to the eyes and akin or through nhslatlon or Ingestion.

FIRST AID: Procedures to be followed when dealing with sacldantal oVerexposure.

PRIMARY ROUTE OF ENTRY.'ased on properties and expecte¹ use.

HAZARDOUS POLYMERIZATIONt Conditions to avoid to prevent hazardous polymerization resulting in a large release of energy STASILITY: Conditions to avoid lo prevent hazardous or violent decomposition.

INCDMPATISILITY: Materials and conditions to avoid to prevent hazardous reactions, S

Reasonabte pr to be taken and methods of oontalnmenL ~ <<nd dfsposat, Consult federal, state and loca! regutatlons lor accepted procedures and any reporttna or rotiftoatke rettulrements.

~ Protect}ve equipment wh)ch may be needed when han.

diing the product>

%EQRSU8 Covers any relevant points not previously mentioned.

ADDITIONALCOMMENTS containers should be either reconditloned by cERTIFIED firms or properly disposed of by AppRovED tIrmL Dtsposat of containers should be In accordance with applicable laws end reoutations,

'EMPTY'rums shoulci not aeglven to indi~

vldualL Serious accidents have resulted from the misuse of 'EMPTIED containers (drums, pails, etc.}. ~ear to Sect-ions IV end l)4

P

~ L A

ML18026A241

Contents

Text

SUBJECT:

Dear Hr. Swerdon:

5.7 VISCXSZTY

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ML18026A241

Text

SUBJECT:

Dear Hr. Swerdon:

5.7 VISCXSZTY

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