ML18017A272

Forwards NPDES Permit Application for Susquehanna Steam Electric Station,Salem Township,Luzerne County,Pa

ML18017A272
Person / Time
Site:	Susquehanna
Issue date:	07/15/1994
From:	Fields J PENNSYLVANIA POWER & LIGHT CO.
To:	Crowley K PENNSYLVANIA, COMMONWEALTH OF
References
PLE-17914, NUDOCS 9407250212
Download: ML18017A272 (272)

Text

P'R.IC3R.l I "V (ACCELERATED RIDS PROCESSING)

REGULATORY INFORMATION DISTRIBUTION SYSTEM (RIDS)

NBR: 9407250212 DOC. DATE: 94/07/15 NOTARIZED: NO DOCKET FACIL:50-387 Susquehanna Steam Electric Station, Unit 1, Pennsylva 05000387 50-388 Susquehanna Steam Electric Station, Unit 2, Pennsylva 05000388 AUTH. NAME FXELDS,J.S.

'UTHOR AFFILIATION Pennsylvania Power 6 Light Co.

RECXP.NAME RECIPIENT AFFILIATION CROWLEY,K.

NOTES'CCESSION Pennsylvania, Commonwealth of wp-W+

SUBJECT:

Forwards NPDES permit application for Susquehanna Steam Electric Station, Salem Township,Luzerne County,PA.

DISTRIBUTION CODE: IE23D COPIES RECEIVED:LTR TITLE: Environmental Event Report (per Tech Specs) f ENCL g SIZE:

RECIPIENT COPIES RECXPIENT COPIES ID CODE/NAME LTTR ENCL ID CODE/NAME LTTR ENCL PD1-2 PD 1 1 POSLUSNY,C 1 1 INTERNAL: ACRS 5 5 9 ILRB 1 1 OGC/HDS2 1 1 REG FILE 01 1 1 RGN1 1 1 EXTERNAL: NRC PDR 1 1 NSIC 1 1 NOTE TO ALL"RIDS" RECIPIENTS:

PLEASE HELP US TO REDUCE WASTE! CONTACT THE DOCUMENT CONTROL DESK, ROOM PI-37 (EXT. 504-2083 ) TO ELIMINATEYOUR NAME FROM DISTRIBUTIONLISTS FOR DOCUMENTS YOU DON'T NEED!

TOTAL NUMBER OF COPIES REQUIRED: LTTR 13 ENCL 13

0' 0 II ~

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Pennsylvania Power 8 Light Company Two North Ninth Street ~ Allentown, PA 18101-1179 ~ 610/774-5151 July 15, 1994 Ms. Kate Crowley Regional Water Quality Manager Pennsylvania Department of Environmental Resources 90 East Union Street, 2nd Floor Wilkes-Barre, PA 18701-3296 SUSQUEHANNA STEAM ELECTRIC STATION RENEWAL APPLICATION FOR NATIONALPOLLUTION DISCHARGE ELIMINATIONPERMIT PERMIT NO. 0047325 CCN 741326 FILE R9-8A PLE- 17914

Dear IVls. Crowley:

Pennsylvania Power & Light Company is submitting a National Pollutant Elimination System (NPDES) permit application for the Susquehanna Steam Electric Station (SES),

Salem Township, Luzerne County, PA. The present Susquehanna SES permit No.

PA 0047325 expires in January 1995.

Enclosed are original and two copies of the application, two copies of the Preparedness Prevention and Contingency Plan, and an application payment check of

$ 500. Also, attached to this letter are requests to update the present NPDES permit, some additional sampling data, and information about an ongoing evaluation of water treatment chemicals.

If you have any questions, please contact me at (610) 774-7889.

Sincerely, erome S. Fields Sr. Environmental Scientist - Nuclear Enclosures

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.,'407250212 P407lg PDR ADOCK 05000387 R .. PDR ti

July 15, 1994 CCN 741326 FILE R9-8A PLE- 17914 To: Ms. Kate Crowley Copy to with Renewal Application:

LNRC Document Control. DeslP NRC Region I Mr. C. Polusny, NRC Project Manager

REQUESTED PERMIT CHANGES

1. Remove internal Outfall 271, Waste Filter Bypass from the permit since it is no longer being used.

2. Remove internal Outfall 471, Waste Filter from the permit since filter is not operational and will not be used in the future.

3. Remove internal Outfall 571, Circulating Water Pumphouse Building Sump, since it collects primarily river water used for cooling and not low volume wastes.

4. Reduce sampling frequency of Outfalls 073, and 074, Units 1 and 2 Turbine Building Low Volume Waste Sumps from monthly to one to two times per year.

These sump discharges are directly related to rainfall and not station operation.

5. Reduce the sampling frequency for total zinc in Cooling Tower blowdown (Outfall 071) to once per year like total chromium. We no longer use zinc as a water treatment chemical.

6. Additional grab samples were taken at the River Intake and from the Cooling Tower blowdown (Outfall 071) for arsenic, total phenols, and bis (2-Ethylhexyl) Phthlate.

Initial results of Outfall 071 samples for arsenic were between 65 and <0.01 ug/I; for total phenols between 42 and <0.015 ug/I; and for bis (2-Ethylhexyl) Phthlate between 23 and <6 ug/I. Since we don't generate these three chemicals at the Susquehanna SES we decided to take four grab samples from the 1) River Intake and 2) Outfall 071 to see if these results were sampling/analysis anomalies or actually present in the blowdown. Table 1 below compares sample data from the River Intake and Ouffall 071 for four sampling events. These data show that river water and blowdown results are essentially the same and are not produced from operational activities at the station. Samples were collected from May 19, 1994 through IVlay 26, 1994.

COMPARISON OF RIVER INTAKEAND BLOWDOWN SAMPLES (OUTFALL 071) conc.(ug/I)

ARSENIC River Intake <10 <10 <10 <10 Outfall 071 18 <10 <10 <10

TOTAL PHENOLS River Intake <5 <10 <10 Outfall 071 <5 <5 <7 16 BIS (2-ETHYL-HEXYL)PHTHALATE River Intake <2 <2 <2 <2 Outfall 071 <2 <2 <2 <2

7. Every four years the station evaluates its water treatment program and determines if changes are required. At this time proposals from several chemical companies are being reviewed. Results of this evaluation, revised permit application information and effluent quality data (Sec. C-IV, page 24), and Material Safety Data sheets will be provided as a permit application amendment to the PaDER in November 1994.

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SUSQUEHANNA STEAM ELECTRIC STATION NATIONALPOLLUTANT DISCHARGE ELIMINATIONSYSTEM (NP DES)

RENEWAL APPLICATION PERMIT NO. PA 0047325 PENNSYLVANIAPOWER 5 LIGHT COMPANY JULY 15, 1994

' ....9407250212

ER-BWQ.288. l0: Rev. 6/93 NATIONALPOLLUTANT DISCHARGE ELIMINATIONSYSTEM (NPDES)

Application for NPDES Permit New and Existing Industrial Dischargers Application'for discharge permit is:

C] New Q Renewal Q Modification/Amendment for:

gl IndustrialWastewater C3 Stormwater 0 Other Applicant Name: Penns lvania Power & Light Company Name of Facility: Sus uehanna Steam Electric Station NPDES Number: PA 0047325 (ifknown)

Facility Location: Salem Townshi Luzerne tmunicipality) (county)

Facility Address: Sus uehanna Steam Electric Station 8 x 467 03 Date of Submittal July 15, 1994 Pennsylvania Department of Environmental Resources Water Management Program Recycled Pei)el'

ER-BWQ-288.l0: Rev. 6$ 3 Before Proceeding, Refer to

.INSTRUCTIONS FOR COMPLETING FORM ER-BW -288.10 NPDES PERMIT APPLICATIONS FOR NEW AND EXISTING INDUSTRIAL DISCHARGERS

EB-BWQ.288.10: Rev. 6I93 "APPLICATION COMPLETION AND SUBMITTAL CHECKLIST Included? Item Three (3) copies of application package submitted Original copy of application notarized Application Pee Proper evidence of Act 14 municipality, county no tiTzcation

~~tt Proof of local newspaper public notice (for new and substantially changed discharges only)

SECTION A- PHYSICAL LOCATION AND GENERAL, INFORMATION (To be completed by AllApplicants)

1. Name ofFacility

2. Facility Location

3. Facility Operator and Ownership Information

4. SIC Codes

5. General Description and Nature of Business-

6. Past and Current NPDES and WQM Part II Permits

7. Topographic Map X

'. 8.

10.

Outfall Location (submit copy ofTopo i%lap with discharge location)

Preparedness, Prevention, and Contingency (PPC) Plans Line Drawing

11. Site Plan and Stormwater RunoE for outfalls discharging BOTH stormwater and process wastewater SECTION B - NEW SOURCE DETERMINATION (To be Completed by AllApplicantsif Applicable) it/A SECTION C- DATA REQUIREMENTS FOR PROCESS, NCCW, AND DISCHARGES SANITARY'ASTEWATER I. OUTFALLS AND ASSOCIATED WASTEWATER TREATiXEiVT TECHNOLOGIES X II. SOURCES OF WASTEWATER CONTRIBUTING TO OUTFALLS

1. Process Wastewater

2. Other Wastewater

3. Total Process, Miscellaneous, NCCW and Sanitary Wastewater 4., Process Wastewater Combined with Storm Water 9 III. REQUIRED AND OPTIONAL ANALYSES 9 X 1. Optional Site-Specific Toxics Data 10 X 2. Summary of Required Analyses Worksheet 11-23 3. Analyses Results IV. INFOR4VIATION ON CihER POTENTIALLY TOXIC POLLUTANTS KNOWN OR EXPECTED TO BE PRESEAV1'N THE DISCHARGE

'X 24 1. Chemical Additives ll 2,3 Other Potentially Toxic Pollutants 4a. GCINS Five Peaks Pollutants 4b. Other Chemicals

ER.BWQ-288.10: Rev. 6$ 3 APPLICATION COMPLETION AND SUBMITTAL CHECKLIST (continued SECTION C - (continued) 28 II/A V RASARDOUS SUBSTANCE SPILL REPORTING REQUIREMENT EXEMPTION 29 X VI. ANTICIPATED ENVIRONMENTALPROTECTION IMPROVEMENTS

'29 I VU. BIOLOGICAL TOXICITY TEST DATA SECTION D- "STORM WATER DISCHARGES ASSOCIATED WITH INDUSTRIAL ACTIVITY" 3P =

N/A I. IF REQUIRED TO COMPLETE THIS SECTION, ALL PARTS ARE COMPLETE SECTION E - MISC. INFORMATION SUBMISSION (To be Completed hy AllApplicants) 36 X I. CONTRACTED ANALYTICALASSISTANCE

~

37 ~~ II. OTHER INFORMATION SECTION F - CERTIFICATION AND SIGNATURES OF APPLICANT (To Be Completed by AllApplicants) 38

~ Pennayivania Power 8 Light Company Veo North Noah SaeoteAlle~, pA QttN-1)7QeRSI7744tN CertiGed Mail PP514 542 463 April 13, 1994 Mr. Erqgae Kkin, Chief Cleric Qmnre County Cotrrthxrse North River Street.

WiBm-Baze, PA 18702 SUSQUEHANNA STEAhf ELZCIRIC STATION NATIONALPOLLUTANTDXSCH'ARGB RUMINATION SYS1'EM PERMIT RENEVFAI 'UMBZRPA0047325 CCN 74l326 HER R94h

- 17694

Dear Mr XJem:

In accordaree with Act No. 14, PL. 834, this letter is to nosy you that Pennsylvania Powers Light Company willbe submitting an application m Suao 1994 to the Peaasyivama Depaztama of Environmental Resources to renew the existiag National Polhrtaat Discharge Himiuuion System-Permit for the Susquehanna Steam Electric Station(SES) located in Salem Township, Lrueme-Couaty, Peaasyivania The Susttudumaa SES is a nuclear generating station with two boiTiag.

water reactors, each with a geaeratmg capacity of 1,130 megawatts.

Ifyou have any questions coaceraiag this perzmt renewal, please call me at (610) 774-7889.

Sincerety, eaior Scientist - Nuclear Copy to:

EPA Region III NRC Documart Control Deslr, NRC Region I Mr.R.J. Qark, NRC Sr. Project Manager Mr.P.M. Swezzlon, PA DER.

Pennsylvania Power & Light Company

'Avo kotttt kinttt Street'AlWtQewn, PA fetN-t170e2t5m44tst Caged MaB April 13, 1994 ML Sandy ShuIaan Secretary, Salem Township Salem Townsiiip MtmicipalBuiltimg Bell Bend Road, RD. 1 Berwidc, PA, 18603 SUSQUEHANNA STEUEEKZCTRIC STATION NATIONALPOLLUTANTDISCEhiRGE EUhtINATION SYSTEM PERMT RENEWAL: NUMBERPA0047325 CCN 741326 HLER94h

- 17693

Dear Ms. Shtrman:

In accordance with Act No. 14, PL. 834, this letter is to notdy you that PemeybrgiiaPower Light Company willbe submitting an apphcationin June 1994 to the Permsyivania Depanmerrt.of Etrviromnental Resotrrces to reams the existittg NationalPoltutant Discharge Elimination Systenr Permit for the Susquehanna Steam Hectric Station(SES) located in Salem Township, Luxerrw" County, Pertrtayivania The Susqudtanna SES is a nuclear getM:rating station with two boiTing.

water reactor3, each with a genertting capacity of 1,130 megavattL Ifyou have any questions concerning this permit rertewai, please call me at (610) 774-78&9.

Sincereiy,

'or S' .N~

Copy to:

EPh Region IH NRC Doctirrterrt Control Desk NRC Region I Mr. R J; Qark, NRC Sr. Project Manager Mr.P.M. Swerdon, PA DER

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ER-BNQ-28$ .1Q: Rev. 683 NPDESNumber PA 0047325 I I S 'I SECTION A - PHYSICAL LOCATION AND GENERAL INFORMATION I S<<I IS I II.S. R II City or Town Berwi c k Zjp Code -18603 County L zerne

• RI application review and permit action).

Operator (PERMIT APPLICANT) Name Penns lvania Power 8 Li ht Company Phone ( 6 1 0 ) 774 ~ - 7889 Street N Ninth Street City or Town State PA ZipCode 18101-1179 Does the Operator own the facility? yes Q no Q Status of Operator: Federal Gov't. Q State Gov't. Q Private g Local Gov't. Q Other

4. SIC Codes Corresponding SIC Description 4 9 1 1 Electric Services 2'nd 3rd 4th

5. General Descri tion and Nature of Business Generation of Electricity. The Susquehanna Steam Electric Station is a nuclear with two Boi in Water Reactors each with an e ectrica enerating ca cit of a roximatel 1 100 Mwe er reactor

6. List all NPDES and Part II Water ualit Mana ement Permits resentl held for this facilit

1. NPDES ermit no. PA 0047325, January 18, 1990 Wa r alit ermit no. 4085411 October 7 1985 mit no 4076203 Ma 25 1977 1 Se tember ll 1974

ER BNQ-288.IOC Rev. 6/93 SECTION A (continued) NPDES Number PA 0047325

7. AttachTo hicMa . Seeinstructions.'ee Figures A-7.1, A-7.2, and A-7.3

8. Outfall Location: For each outfall, list the latitude and longitude of its location to the nearest second and the name of the receiving water. VFhere available, the receiving stream width and depth should also be provided using actual measurements or topographic map and navigational charts.

FINAL LONGITUDE Low Floe OUTFALL RECEIVING WATER Stream NUMBER <Name)

(list) S SEC L DECL Ft. Ft.

Width Depth 070 41 5 15 76 8 45 Lake Took-a-while 160 3 071 41 5 30 76 7 45 Susquehanna River 1000 13 072 41 5 30 76 8 45 Lake Took-a-while 160 3 073 41' 30 76 8 45 Lake Took-a-while 160 3 074 41 5 30 76 8 45 Lake Took-a-while 160 3 075 41 5 30 76 8 45 Lake Took-a-while 160 3 077 41 5 30 76 8 45 Lake Took-a-while 160 '

078 5 3n 76 8'5 Lake Took-a-while 160 3 079 41 5 30 76 8 45 Susquehanna River 1000 10 080 41 5 30 76 8 45 Lake Took-a-while 160 3

9. Pre aredness Prevention and Contin encv PPC Plannin Does the facility have a PPC plan which has been reviewed and approved by the Department?

iQ Yes Date of Approval No (attach 2 copies for review and approval)

Does the facility have any ocher related plans, such as a Pollution Incident Prevention (PIP) Plan or a Spill Prevention Control and @Yes @No Counter Measure (SPCC) Plan?

Ifyes, identify and indicate date(s) approved by the Department or EPA.

The PPC plan includes PIP, SPCC, Best Management Practices (BMP), Contingency and Spill Prevention Response (SPR) plans.

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SECTION A (continued) NPDES Number pA 0047325 Saasquaharrna Rbrer (07])

7.74 MGD Evapora6ora and DriS lab MOD 0.065 MGD Saon Weaer Took-A-VQk Spray Pood Zsslsora6oea Earalsora&ca (080)

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Area Wale Ural Weaer Tee easer sr 8 O~e Oeeseeea eaaseos Osrea OSS vlcreacrees Leee csee e lees Jeeaeeeea ee eeeeeg, aseeeeea oeess a eesleale er

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however, this option is available if necessary.

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ER.BWQ.288.10: Rcv. 6I93 SECTION A (continued) NPDES Number PA 00473~~

11. Site Plan and Stormwater RunofF- Use space below or an attachment. See instructions.

Complete this part for outfalls discharging process, non-contact cooling or sanitary wastewater in combination with stormwater.

The Department strongly recommends the separation of stormwater and other wastewaters.

However, if this is impossible, complete this part. Section C must be completed for the other wastewater contribution. Complete Section D for the stormwater coritribution. If the stormwater can be separated, complete Section D for the stormwater outfall, and Section C for any other wastewater outfalls.'ee'igure A-11 4

PERIMETER FENCE SECURITY FENCE f

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• FIGURE A-11 Hajor Drainage Areas and Flowpaths Susquehanna SE~

LIST OF CODES (FIGURE A-15)

SITE PLAN AND STORMWATER RUNOFF NORTH DRAINAGE AREA 1N - Unit 1 Condensate Storage Tank 2N - Discharge of Storm Drain Near North Gatehouse Parking Lot 3N - Peach Stand (Outfall 075) 4N - Entrance to Lake Took-A-While 5 - Exit from Lake Took-A-While CENTRAL DRAINAGE AREA 1C - Waste Accumulation Area 2C - Entrance to C-1 Pond 3C - Exit from C-1 Pond (Outfall 080) 4C - Entrance to Lake Took-A-While 5 - Exit from Lake Took-A-While SOUTH DRAINAGE AREA 1S - Acid/Chlorine Building (no longer stores acid or chlorine) 2S - Entrance to S-2 Pond 3S - Exit of S-2 Pond 4S - Entrance to Lake Took-A-While 5 - Exit from Lake Took-A-While isf/msf3663 c(26)

ER.BVFQ.288.10: Rev. $ 93 NPDES Number PA 0047325 SECTION B - NEWSOURCE DETERMINATION N/A Referring to the instructions for this question, indicate when "construction" (as defined by EPA) and discharge began for the facilities causing each discharge? If"construction" has not begun, state when it willbegin.

Do not complete this table for outfalls which only discharge sanitary wastewater or stormwater runoff (unless considered "process wastewater" under an EPA eQluent guideline regulation).

~Be an'ate Date "Construction" Discharge

~Be an~>> Facilities Causin Dischar e Outfall s

'f "construction" began on diiferent dates for facilities which contribute to the same outfall, list these dates separately (use additional sheets ifnecessary).

~~ Ifnot yet discharging, indicate date on which discharge is expected'to begin.

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R-BWQ 288.10: Rev. 6/93 1of2 NPDES Number PA 0047325 SECTION C - DATA REQUIREMENTS FOR PROCESS, NCCW, AND SANITARY WASTEWATER DISCHARGES I. OUTFALLS AND ASSOCIATED WASTEWATER TREATMENT TECHNOLOGIES Treatment Treatment Method for Handling and Disposal Handling Outfall . Treatment Unit Description Unit Code Unit Design of Solid or Liquid Residue and Number (list in sequence) (See Hoer Rate Resulting froin Treatment Disposal Table 1) (10 gal/day) (list in sequence) Code, 070 Discharge to Surface 4-A Rain" Not applicable Water Dependent Sedimentation (settling) 1-U Rain Not applicable Dependent 071 Discharge to Surface 4-A 20 Not appl.icable Water Disinfection (other) 20 Not applicable Sedimentation (settl ing) 1-U 20 Landfill 5-Q Disinfection (chlorine) 20 Not applicable (optional)

Dechlorination (other) 2-E 20 Not applicable (optional)

Neutralization 2-K 20 Not appl icable 171 Diatomaceous Earth 1-C 0.28 Radioactive waste 5-Q (internal) Filtration landfill Ion Exchange 2-J 0.28 Radioactive waste 5-Q landfill Neutralization 2-K 0.28 Not applicable Evaporation (optional) 1-F 0.28 Radioactive .waste 5-Q landfill Nicrostraining 0.002 Radioactive waste 5-Q landfill 3?1 Neutralization 2-K 0.04 Not applicable internal (1 aundry on iv) 4-H 0.023 Reuse or sale 4-E 072 Oil and Grease Removal Discharge to Surface 4-A 0.023 Not applicable Water via Storm Drains 4-H 0.018 Reuse or sale 4-E 073 Oil and Grease Removal Discharge to Surface 4-A 0.018 Not applicable Water via Storm Drains

2of2 ER-BWQ.288.10: Rev. 6/93 NPDES Number PA 0047325 j

SECTION C - DATA REQUIREMENTS FOR PROCESS, NCCW, AND SANITARY WASTEWATER DISCHARGES I. OUTFALLS AND ASSOCIATED WASTEWATER TREATMENT TECHNOLOGIES Treatment Treatment Method lor Handling and Disposal Handli Outfall . Treatment Unit Description Unit Code Unit Design of Solid or Liquid Residue and Number (list ln sequence) (See Fio>> Rate Resulting from Treatment Dispo Table 1) (104 gal/day) Oist in sequence) Cod 074 Oil 5 Grease Removal 0.018 or sale 'euse 4-E Discharge to Surface 4-A 0. 018 Not applicable Water via Storm Drains 075 Discharge to Surface 4-A Rain Not applicable Water via Storm Drains Dependent Sedimentation (settling) 1-U Rain Not applicable Dependent 077 Discharge to Surface 4-A 0.024 Not applicable Water via Storm Drains 078 Discharge to Surface 4-A 0.019 Not applicable Water via Storm Drains 079 Grinding (comminutors) 0. 08 Not applicable Screening 0.08 Incineration, 5-0 Equalization 1-Y 0.08 Not Applicable Pre-aeration 3-E 0.08 Not applicable Activated Sludge 3-A 0.08 Belt filtration; 5-6; incineration 5-0 Neutralization 2-K 0.08 Not applicable Disinfection (chlorine) 2-F 0.08 Not applicable Dechlori'nation 2-E 0.08 Not applicable Not applicable (other)'isinfection (other)- 2-H 0. 08 Discharge to Surface 4-A 0.08 Not applicable Water 080 Discharge to Surface 4-A Rain Not applicable Water via Storm Drains Dependen

. Sedimentation (settling) 1-Y Rain Not applicab e Dependent ADDITIONALINFORMATION FOR SECTION C-I ADDITIONALOUTFALL DESCRIPTIONS 070- The S-2 Pond, located on the South side of the Susquehanna SES site, is a storm water runoff outfall (SWRO) . This SWRO outfall may contain occasional discharges of clarified water, demineralized water, well water, and fire protection water. These discharges may contain small amounts of chlorine'which will dissipate upon mixing with storm water in the pond, before the discharge

. reaches Lake Took-a-while. Due to the similarity of this outfall with Outfall 080, only Outfalls 075 and 080 was sampled for this NPDES permit application.

071 - Cooling Tower Blowdown includes input from both Unit 1 and Unit 2 Cooling Towers, internal discharges, and Emergency Spray Pond (Spray Pond) overflow.

The Cooling Towers and Spray Pond contain river water used for cooling station main condensers and other heat exchangers throughout the station.

Evaporative losses in the towers generally result in cooling water being cycled up to 3 to 5 times the concentration of river water. Cooling Tower Basins each contain approximately 7 million gallons (MG) of water and the Spray Pond about 25 MG. Discharges to the Susquehanna River generally range between 2,000-

, 6,000 gpm from each tower and approximately 100 - 800 gpm from the Spray Pond. The combined station discharge is approximately 7,000 gpm or 10 MGD.

In order to reduce fouling and corrosion in the Service Water and Circulating Water Systems, PP8L utilizes a chemical treatment program. The treatment currently includes the injection of a copolymeric dispersant and a phophonate-based scale inhibitor, 1-hydroxyethylidene diphosphonic acid (HEDP). These chemicals are fed into the suction of the service water pumps at the feedrates

, and concentrations speciTied in Table 1. The range of concentrations indicated are the concentrations presently being used in the treatment program. Since the Cooling Tower Basins discharge directly to the Cooling Tower Blowdown Line, the concentrations listed in Table 1 are those expected to be present in Outfall 071.

TABLE 1 COOLING WATER TREATMENT CHEMICALS

~0<<

Normal Concentration Chemical Use Concentration Maximum Range (ppm) (ppm)

Acrylate Copolymer Dispersion of Mud, Silt 1.5 - 2.5 5.0 or and Iron normally Active Copolymer Active Copolymer Propcnoid Sulfonic found in River Water Acid'Co l er Hydroxyethylidene Scale Inhibitor 0.2-1.5 2.5 Diphosphonic Acid as HEDP as HEDP DP AlkylDimethyl Broad Spectrum Non- 5-20 30 BenzylAmmonium Oxidizing Biocide As Productor As Productor Chloride (ADBAC) and and Molluscicide 0.6-2.6 3.9 Dodecyl Guanidine As Total Actives As Total Active H drochloride G AlkylDimethyl General Biocide and 0.5 -5.0 10.0 BenzylAmmonium Algaecide As ADBAC As ADBAC Chloride ADBAC Sulfuric Acid H Control 0-800 1,000 Methylbenzotriazole Copper Corrosion 1.2-1.8 2.5 or Inhibitor Active Azole Active Azole Bu Ibenzotriazole ot Presentl Used ot Presentl Used A broad spectrum non-oxidizing biocide is added to each Cooling Tower on a weekly basis to control microbiological fouling in the Main Condenser and Service Water Heat Exchangers. Additionally, the algicide is added to the cooling towers to reduce algae growth and augment the microbiological control of the Main Condenser. The non-oxidizing biocide is a blend of 2 cationic surfactants - Alkyl Dimethyl Benzyl Ammonium Chloride (ADBAC) and Dodecyl Guanidine Hydrochloride (DGH). The algicide consists primarily of ADBAC.

During each weekly biocide treatment, Cooling Tower Blowdown is initially isolated to contain the biocide until the actual concentration in the tower is measured. This also maximizes the contact time of the biocide with the system components. Once the tower concentration of the biocide is known, a bentonite

'clay slurry feed is initiated to the blowdown line'. Cooling Tower Blowdown is then re-established. Biocide concentration is then measured at the effluent composite sample station to determine the effectiveness of the detoxification.

r Non-indigenous mollusks such as the Asiatic clam and the Zebra mussel are not presently found in the Susquehanna River near the Susquehanna SES.

Research indicates that they may some day be present and could create problems. If such species do migrate to the vicinity of the plant, PP8L plans to

utilize the same non-oxidizing biocide to periodically eliminate these mollusks from the plant intake piping as well as the Cooling Towers and Spray Pond.

This material will be'added over a 12-24 hr. period at a frequency of 2-4 times annually. This biocide will be detoxified with bentonite clay which will be continuously added to the Cooling Tower Blowdown Line. The bentonite clay adsorbs the biocide, deactivating the biocide. Extensive studies of the biocide and its detoxified by-products have been conducted by the vendor and are attached to Section C-VI.

The algicide is also used on a periodic basis to control algae in the Spray Pond.

Approximately twice per month or less frequently in colder months, this algicide is sprayed along the edge of the pond to kill algae. This edge treatment adds less than the theoretical volume required to achieve a measurable residual in the pond itself.

Approximately twice a year, a larger volume of algicide is added to the Spray Pond to control algae in the entire pond. During these treatments, a bentonite slurry is injected into the Cooling Tower Blowdown line during and after the treatment until such time that the pond effluent contains a less-than-detectable algicide concentration. During any periods that the Spray Pond has a measurable algicide residual, station blowdown (Outfall 071) will be analyzed for

, the algicide at the composite sampler on a weekly basis to ensure detoxification.

Special permitting for use of this product has been obtained from the PA Fish Commission and the PaDER. (Permit attached after Section C-IV.)

As an alternative to the algicide, PP&L may also add sodium hypochlorite to the edges of the pond to control algae. The sodium hypochlorite will be manually sprayed along the edges of the pond in the same manner as the algicide. The treatment frequency will be the same as that used for the algicide.

Additional weed and fish control chemicals are also used periodically in the '.,

Spray Pond. Rotenone (Nusyn-Noxfish) is used as a fish pesticide Spray Pond and Fluridone (Sonar) is used as a herbicide. Special permitting of these chemicals will be requested from the PA Fish and Boat Commission and the PaDER on an as-needed basis.

At present, pH control of the Cooling Tower is accomplished by Cooling Tower blowdown flow control. If additional pH control becomes necessary, sulfuric acid addition to the Cooling Towers can be initiated.

Because the cooling tower is normally operated at a pH above 8.0, corrosion of much of the system metals copper alloys and various steels is minimized by the alkaline water. Consequently, no copper or steel corrosion inhibitors are presently used. Azole-based copper corrosion inhibitors and zinc-based steel corrosion inhibitors have been used in the past. PPB L no longer intends to

utilize zinc compounds due to their environmental impact; however, azole-base copper corrosion inhibitors are still used in some closed components of the power plant and may be used in the larger cooling systems at a later date.

During refueling and other maintenance'utage periods, cleaning of the main condensers and/or various heat exchangers is usually performed. Usually this cleaning involves only the use of high pressure water jets at a flow up to 50 gpm.

Occasionally, dispersants and surfactants such as those listed in Table 1 may be added to the water jets. The daily usage rate of the chemical'cleaning agents will be at or below normal operational usage rates for the chemicals stated.

Additional cleaning agents are listed in Section C-IV.

Also, during refueling outages Cooling Tower basin sediment is removed and dewatered by belt filter press. A flocculant is used to enhance the dewatering process. The filtrate from the dewatering process is discharged to the Cooling Tower blowdown line. The dewatered sediment is transported offsite for disposal.

In past outages, the use of a proprietary scale removal agent was found to be effective at lo'osening and removing hard calcium carbonate scale which may form in the main condenser and heat exchangers depending upon the chemistry

.. of the river. This descaling chemical is not typically found in the blowdown.

When it is used, it is added to a tower while the Cooling Tower Blowdown is closed. The chemical reduces the pH of the water in the tower below 6.0, but this water is not discharged to the river during the cleaning. At the completion of the cleaning period, Cooling Tower pH is adjustedbetween 6.0 and 9.0 prior to re-opening the Cooling Tower Blowdown Valve. Information on this cleaning chemical is provided in Section C-VI.

The Standby Liquid Control System provides an emergency reactor shutdown mechanism which floods the reactor with a solution containing neutron-absorbing boron. This system is tested and flushed twice per quarter, resulting in the discharge of up to 1,000 gallons of a sodium pentaborate solution (Na2B10016) to the Cooling Tower Basin.

This sodium pentaborate solution contains 15,000 - 35,000 mg/I boron, with total quantities of boron between 100- 300 Ibs per flush. These flushes are between a pH of 6-9 and contain negligible amounts of other suspended or dissolved material. The maximum boron concentration predicted in the blowdown following each flush is less than 10 mg/I.

The closed cooling water systems listed in Table 2, Systems, contain demineralized water treated with corrosion and microbiological control chemicals. These chemicals are listed in Table 3, Closed Cooling Water

Treatment Chemicals. These chemicals may be purchased as a preblended product or added independently to maintain recommended concentrations.

By definition closed cooling systems are not routinely discharged to the environment. When maintenance is performed on these systems, batch discharges are directed to the Cooling Tower basins (Outfall 071) or the Sewage Treatment Plant (Outfall 079).

TABLE 2 SYSTEMS SYSTEM SYSTEM NO. OF SYSTEMS VOLUME al Units1 &2 4,300 Reactor Building Closed Cooling Water Units 1 & 2 1,150 Turbine Building Closed Cooling Water

~

~ Units1 &2and Common Gaseous 3,100 Radwaste Recombiner Closed Cooling Water Units 1 & 2 4,750 Reactor Building Chilled Water Units 1 & 2 6,200 Turbine Building Chilled Water Control Structure 1,200 Chilled Water Radwaste Building 860 Chilled Water A-D Emergency Diesel 4 385 General Jacket Cooling Water e E Emergency Diesel Generator Jacket Cooling Water 1,500

TABLE 3 CLOSED COOLING WATER TREATMENT CHEMICALS CONCENTRATION CONCENTRATION CHEMICAL USE - ~t'MAXMUM Sodium Nitrite Mild Steel 500 - 1500 2,000 Corrosion Inhibitor as NO2 Methylbenzo Copper Corrosion 5-20 50 Triazole (Toly Tri Inhibitor Azole)

Isothiazoline Microbiological 35-200 250 Control Agent Borate Salt pH BufFering Agent 50-150 300 (Diesels only)

INTERNAL OUTFALLS 171 - Liquid Radwaste discharge includes leakage and wastewater from the radiologically controlled area and also the Condensate Storage Tank bermed areas (Outfalls 077- 8 078). Prior to combining with Outfall 071, this wastewater is passed through various treatment processes to reduce the concentration of radioactive materials. Approximately 99% of liquid radwaste is treated by one of two processes: filtration followed by ion-exchange demineralization, or ion-exchange demineralization followed by microstraining. The remaining 1% of liquid radwaste is the laundiy drainage system, which receives drainage from equipment washdown stations and personnel decontamination facilities in the radiologically controlled area.

This liquid is passed through a cartridge filter to remove solids prior to discharge. Currently, all laundry is sent to an outside contractor for cleaning Miscellaneous wastes discharged through this system include service water leakage, mop water from cleaning in the radiologically controlled area, and leakage from. various pumps and valves.

271 - Waste Filter Bypass is no longer used and PP&L requests that this internal outfall be eliminated.

371 - Neutralization Basin internal discharge includes inputs from the demineralizer rinse water and chemical waste inputs from the Water

Treatment Building equipment and floor drains. There are two basins each with a capacity of approximately 20,000 gallons. The basins are used alternately and the contents are air sparged, recirculated, and pH adjusted prior to being directed to the suction side of the circulating water'umps.

471 - Waste Filter is no longer used and PPB L requests that this internal outfall be eliminated.

571 - Circulating Water Pumphoupe Building sump receives leakage from the Circulating Water System (Outfall 071) including circulating water, seal water and Circulating Water System equipment and drains. PP8L requests that this internal discharge be eliminated since it is mainly river water and not low volume wastes.

072 - The Service and Administration (S8A) Building Low Volume Waste Sump receives inputs from the diesel generator oil unloading areas and building floor drains, the emergency start-up transformer bermed areas and the SBA Building floor drains. The sump contains two cells, each with approximately 10,500 gallon capacity. An oil and grease separator is provided to remove any fuel or transformer fluid leakage. Diesel Jacket Closed Cooling Water System leakage may also enter this sump.

073- Outfall 073, Unit 1 Turbine Building Low Volume Waste sump is similar to Outfall 074, only this outfall collects runoff from Unit 1 while Outfall 074 collects runoff from Unit 2. Due to their similarity only Outfall 074 was sampled for this NPDES permit application.

074 - The Unit 2 Turbine Building Low Volume Waste Sump collects storm water drainage from the transformer, turbine lube oil and oil circuit breaker bermed

'areas. This sump, like Outfall 073, has two cells of approximately 8,700 gallons each. The water passes through an oil and grease separator prior to discharge.

Both Outfall 073 and 074 currently are sampled monthly. Analyses to date consistently show minimal levels of oil and grease and total suspended solids in Outfall 073 and 074 discharges. Because these discharges are directly related to rain fall events and not station operation, PP&L requests reduced sampling frequency to once per year.

075 - The Peach Stand Pond is a SWRO which discharges through a drainage ditch located on the North side of the site. This outfall may contain occasional discharges of clarified water, demineralized water, well water, and fire protection water. Discharge from this outfall goes into Lake Took-a-while. Due to the similarity of this outfall and Outfalls 070 and 080, only Outfall 080 was sampled for this NPDES permit application. These discharges may contain small

amounts of chlorine which will dissipate upon mixing with stormwater before discharge into Lake Took-a-while.

077 - The Unit 1 Condensate Storage Tank bermed area runoff is dependent on rainfall events and miscellaneous waste streams. Currently, flow from this outfall has been directed to Liquid Radwaste, Outfall 171. To date there has been no discharge from this outfall to the storm drains; however, PPB L would like to keep this option available.

078- Outfall 078 is similar to Outfall 077, only this discharge collects rainfall and miscellaneous waste streams from Unit 2. PPBL would also like to keep this discharge option available. Only Outfall 077 was sampled for this NPDES permit application.

079 - The Sewage Treatment Plant (STP) is designed to treat 80,000 gallons per day of sanitary wastes from the collection system onsite and from grinder pump stations at the Training Center, Riverlands, and Environmental Lab. These sources may contain small amounts of cleaning agents and other chemicals recommended for disposal at a sewage treatment plant and other process wastes such as those described for Outfall 071.

080-.. The C-1 Pond is a SWRO outfall located in the central drainage area just East of the station. This outfall may contain occasional discharges of clarified water, demineralized water, well water, and fire protection water. These discharges may contain small amounts of chlorine which will dissipate upon mixing with storm water before discharge to Lake Took-a-while.

)sf/mse3606c(26)

ER-BWQv288.10: Rev. 6/93 lof3 SECTION C (continued) NPDES Number PA 0047325 IL SOURCES OF WASTEWATER CONTRIBUTING TO OUTFALL NUMBER

1. Process Wastewater (S-2 Pond)

a. Describe process and type of wastewater: N//I

b. Applicable EPA EQluent Limitation Guideline: 40 CFR Category/Subcategory

c. Maximum Monthly Production Rate:

e OfProduct Month When Representative Produetion Occurs Days/Month Production Occurs

d. Discharge Occurs: 'rs/say; daysort; says/yn moouu/yr.

During which months?

For continuous discharges report:

The ~ayers e discharge rate associate'd with'the month of maximum production. -

MGD For intermittent or seasonal discharges report:

The ion -term avera e discharge rate iMGD The maximum dailv discharge rate iMGD For batch discharges report:

No. of decant cycles CYCLES/DAY Length of each "decant cycle MIN.

Average decant discharge rate GPM Process Wastewater

a. Describe process and type of wastewater: N/A

b. Applicable EPA Effluent Limitation Guideline: 40 CFR Category/Subcategory

c. Maximum Monthly Production Rate:

Of Product Month When Representative Days/Month Quanutir Units of Measure (or rassy material used) Production Occurs Production Oeeurs

d. DiSCharge OCCura:

During whish months?

For continuous discharges report:

Ors/Say:

'ays/yr, aayv/et; months/yr.

The ~ayers e discharge rate associated with the month of maximum production. MGD For intermittent or seasonal discharges report:

The lon -term avera e discharge rate MGD MGD

ER.BRQ-288.1Lv RCV. 8/83 2of3 SECTION C (continued) NPDES Numbet PA 004'7325 For batch discharges report:

No. of decant cycles CYCLES/DAY Length of each decant cycle iMIN.

Average decant discharge rate GPM II. SOURCES OF WASTEWATER FOR OUTFALL 070

2. OtherWastewaterContributin tothisOutfall See No. 3 Below (Description)

a. Source(s):

h. Discharge Occurs: ererssr: direct; deserve months/yr During which months?

For continuous discharges report:

The a~vera e discharge rate associated with the month of maximum production. MGD For intermittent or seasonal discharges report:

The ion -term avera e discharge rate iMGD For batch discharges report:

No. of decant cycles CYCLES/DAY Length of each decant cycle i%IN.

Average decant discharge flow rate GPM

3. Total Process Miscellaneous Non-Contact Coolin and Sanitary Wastewater

a. Source(s): Runoff from paved roads, roof drains h... Discharge Occurs: seeress; days/tvk; days/yr. months/yr During which months? Rain de endent I

For co'ntinuous discharges report:

The a~vera e discharge rate associated with the month of maximum production. MGD r

For intermittent or seasonal discharges report:

The ion -term avera e discharge rate iMGD The maximum dail discharge rate MGD 3of3 ER.B%Q-388.10: Rev. 683 SECTION C (continued) NPDES Number PA 0047325

4. St'ormwater Runoff (Only if in combination with any of the above wastewaters. li'utfall consists of only storm@rater, complete Section D) otherwise complete Section D for the stormvrater contribution and Section C for contributions from other vrastevraters.

Drainage Ana Sire Fts X Conversion Factor

. 0823 ~

Volume 7'nitsGallons 4.7 x 5.55 x 105 va x 541 ~. 1.46 x 10 GaHous X hoes X 2T.152 Gallons II. REQUIRED AND OPTIONAL ANALYSES,

1. tionalSite-S 'c Toxics Data Use the space below (attach additional sheets if necessary) to provide any of the optional site-specinc information discussed in Appendix2. (The Analyses Results Table should be use6 to report intake water quality, upstream backgroun6 or ambient water quality, and parameter specLnc coeGicient of e6luent variability. Space is provi6e6 at the top of the table to provide description of sampling points usecL)

Optional Toxics Data is attached to Application +YES g NO ER-BWQv288.10: Rev. 6/93 1of 3 SECTION C (continued) NPDES Number PA 0047325 IL SOURCES OF WASTEWATER CONTRIBUTING TO OUTFALL NUMBER 071 (Cool ing 'Water Bl owdown)

1. Process Wastewater

a. Describeprocessandtypeofwastcwater: No. 4A (Oischarge to Surface Water)

b. Applicable EPA EQluent Limitation Guideline: 40 CFR 423 Category/Subcategory Steam El ectri c Power

c. Maximum Monthly Production Rate: (1993'),,

Of Product Month When Representative Days/Month s Production Occurs Production Occurs 1.53 x 106 mwh (net) electricity March 31

d. Discharge Occurs: 24 tnysey: 7 dessert: gg5 days(ye ig moouvvyr.

Durtngwhichmonths? a11 tooritlis For continuous discharges report:

The ~ayers e discharge rate associated with'the month of maximum production. 7.66 MGD For intermittent or seasonal discharges report:

The ion -term avet'a e discharge rate MGD The maximum dailv discharge rate MGD For batch discharges report:

No. of decant cycles N A CYCLES/DAY Length of each decant cycle MIN.

Average decant discharge rate GPM Process Wastewater N/A r

a. Describe process and type of wastewater:

b. ApplicableEPAEIIluentLimitationGuideline: 40CFR Category/Subcategory

c. Maximum Monthly Production Rate:

Of Product Month When Representative - Days/Month Quantittr. Units of Measure /or ratty material used) "

Production Occurs 'Production Occurs

d. Discharge Occurs:

During which months?

For continuous discharges report:

arstdey:

'ays/yr:

days/tv months/yr.

The ~ayers e discharge rate associated with the month of maximum production. MGD For intermittent or seasonal discharges report:

The ion -term avera e discharge rate MGD MGD ER-BNQ-288.10: Rev. 663 2of3 SECTION C (continued) NPDES Number PA For batch'discharges report:

No. of decant cycles CYCLESIDAY Length of each decant cycle MIN.

Average decant discharge rate GPM II. SOURCES OF WASTEWATER FOR OUTFALL 071

2. Other Wastewater Contributin to this Outfall See No. 3 Bel ow (Description)

a. Source(s):

h. Discharge Occurs: cassava: 'eyrlyr, wccucyyr During which months?

For continuous discharges report:

The a~vera e discharge rate assaciated with the month of maximum production. MGD For intermittent or seasonal discharges report:

The ion -term avera e discharge rate MGD e MGD For batch discharges report:

No. of decant cycles CYCLES/DAY Length of each decant cycle MIN.

Average decant dischar'ge flow rate GPM

3. Total Process Miscellaneous Non-Contact Coolin and Sanitary Wastewater

a. Source(s): Internal discharges: Outfall 171," Liquid Radioactive Waste and-Outfall 371, Neutralization Basin

h. Discharge Occurs: hersey: ceyrrvt; scyeryr 12 woc.rcryyr During which months? Al 1 months; intermi ttent For continuous discharges report:

The a~vera e discharge rate asscciatert with the month of maximum production. ~NA MGD ForintermittentotYNXONARNdischargesreport:

~2 (1993'utfall 171 MGD MGD Outfall O.Q18 0.051 3? 1 NGO NGD ER BWQ-288.10: Rev. 6I93 3of3 SECTION C (continued) NPDES Number PA0047325 4, Stormwater Runoff'Only if in'combination with any of the above wastewaters.

consists of only stormwater, complete. Section D) otherwise complete Section D for the

'f outfall stormwater contribution and Section C for contributions from other wastewaters.

Drainage Area

~Raiafaii iaehes) Sire Units Conversion Factor Volume Units Fts X 0.623 GaQons X Yas X 6.61 GaQons 4.7 x 8 A X 27 162 1,021 Gallons (Emergency Spray Pond)

IIL REQUIRED AND OPTIONAL ANALYSES

1. tional Site-S cific Toxics Data Use the space below (attach additional sheets if necessary) to provide anyHAYESof the optional site-speciffc information discussed in Appendix 2. (The Analyses Results Table should be used to report intake water quality, upstream background or ambient water quality, and parameter specific coefficient of effluent variability. Space is provided at the top of the table to provide description of sampling points used.)

Optional Toxics Data is attached to Application g NO

ER.BWQv288.10: Rev. 6/93 1 0$ 3 SECTION C (continued) NPDES Number PA 0047325 II. SOURCES OF WASTEWATER CONTRIBUTING TO OUTFALL NUMBER

.- (Service and Admin. Bldg. Low Volume Waste Sump)

1. Process Wastewater v

a. Describe process and type of wastewater: N/A

b. Applicable EPA EGluent Limitation Guideline: 40 CFR Category/Subcategory

c. Maximum Monthly Production Rate:

Of Product Month When Representative, Days/Month e Production Occurs Production Occurs

d. Discharge Occurs: turrder; days/gt? months/yr.

During whish months?

For continuous discharges report:

The ~overs e discharge rate aisociated with'the month of maximum production. MGD For intermittent or seasonal discharges report:

The ion -term avera e discharge rate MiGD The maximum dailv discharge rate iMGD For batch discharges report:

No. of decant cycles CYCLES/DAY Length of each decant cycle MIN.

'verage decant discharge rate GPM Process Wastewater N/A

a. Describe process and type of wastewater:

b. Applicable EPA EIIluent Limitation Guideline: 40 CFR Category/Subcategory

c. Maximum Monthly Production Rate:

Of Product Month When Representative Days/Month Quantiti Units of Measure (or raw material used) Production Occurs Production Occurs

d. Discharge Occurs: hrs/day; days/w days/yr; months/yr.

During which months?

For continuous discharges report:

The ~overs e discharge rate associated with the month of maximum production. MGD For intermittent or seasonal discharges report:

The ion -term avera e discharge rate MGD maximum dail discharge rate 'he MGD ER.BVPQ-288.10: Rev. 6I93 2of 3 SECTION C (continued) NPDES Number PA 0047325 For batch discharges report:

No. of decant cycles CYCLES/DAY Length of each decant cycle MIN.

Average decant discharge rate 'PM II. SOURCES OF WASTEWATER FOR OUTFALL 072

2. Other WastewaterContributin tothisOutfall See No. 3 Below (Description)

a. Source(s):

h. Discharge Occurs: srs/ccy: ccycers: 'cysrru mecthayr During which months?

c For continuous discharges report:

The a~vera e discharge rate asseciated with the l

month of maximum production. MGD For intermittent or seasonal discharges report:

. The ion -term avera e discharge rate . MGD MGD For batch discharges report:

No. of decant cycles CYCLES/DAY Length of each decant cycle iVIIN.

Average decant discharge flow rate GPM

3. Total Process Miscellaneous iNon-Contact Coolin and Sanitary Wastewater Misce aneous wastewater - iese genera or drains, oil storage a., Source(s): area, and parking lot runoff

h. Discharge Occurs: 1 smrcey; ceyerck: 29 ceycryr. 12 mccravyr (iggg )

During which months?

For continuous discharges report:

The a~vera e discharge rate asscciated with the month of maximum production. N/A MGD For intermittent or seasonal discharges report:

The ion -term avera e discharge rate 0.0105 MGD MGD ER.BRQ-288.10: Rev. 6I93 30f 3 SECTION C (continued) NPDES Number PA 0047325

4. Stormwater Runoff', (Only if in'combination with any of the above wastewaters. If outfall consists of only stormwater, complete.Section D) otherwise complete Section D for the stormwater contribution and Section C for contributions from other wastewaters. N/A Drainage Area

~llaiafall iaehea) Size Units Conversion Factor Volume Units Fts X 0.623 Gallons YP X 6.61 X Acres X, 27.162 Gallons III. REQUIRED AND OPTIONAL ANALYSES

1. tional Site-S cific Toxics Data Use the space below (attach additional sheets if necessary) to provide any of the optional site-specific information discussed in Appendix 2. (The Analyses Results Table should be used to report intake water quality, upstream background or ambient water quality, and parameter specific coefficient of effluent variability. Space is provided at the top of the table to provide description of sampling points used.)

Optional Toxics Data is attached to Application HAYES @NO ER.BWQ-288.10: Rev. 683 1of 3 SECTION C (continued) NPDES Number PA 0047325 II. SOURCES OF WASTEWATER CONTRIBUTING TO OUTFALL NUMBER

1. Process Wastewater (Unit 1'Turbine Bldg. Low Volume Waste Sump)

a. Describe process and type of wastewater: N/A

b. Applicable EPA EEuent Limitation Guideline: 40 CFR Category/Subcategory

c. Maximum Monthly Production Rate:

Of Product Month When Representative Days/Month Production Occurs Production Occurs

d. Discharge Occurs: knssey: seysyek; sayaryn mootksryr During which months?

For continuous discharges report:

The ~overs e discharge rate associated with'the month of maximum production. MGD

. For intermittent or seasonal discharges report:

Thelon -termavera edischargerate NGD The maximum dailv discharge rate MGD For batch discharges report:

No. of decant cycles CYCLES/DAY Length of each decant cycle MIN.

Average decant discharge rate GPM Process Wastewater N/A a.. Describe process and type of wastewater:

b. Applicable EPA EQluent Limitation Guideline: 40 CFR Category/Subcategory

c. Maximum Monthly Production Rate:

OfProduct Month When Representative Days/Month Quantity Units of Measure (or ra?sy material used) Production Occurs Production Occurs

d. Discharge occurs: toucan cayryeh sess/ye. moctkeso During which months?

For continuous discharges report,:

The ~svera e discharge rate associated with the month of maximum production. MGD For intermittent or seasonal discharges report:

The ion -term avera e discharge rate MGD MGD

'7-

ER-BNQ-288,10: Rdtv. 6/93 20f3 NPDES Number PA 0047'325 For batch discharges report:

No. of decant cycles CYCLES/DAY Length of each decant cycle i%IN.

Average decant discharge rate GPM II. SOURCES OF WASTEWATER FOR OUTFALL 073

2. Other Wastewater Contributin to this Outfall See No. 3 Below (Description)

a. Source(s):

'GD

h. Discharge Occurs: arsrcsy, aeysret; 'sysryu nogtthsly'r During which months?

For continuous disc)1arges report:

The ~overs e discharge rate associated with the month of maximum production.

For intermittent or seasonal discharges report:

The ion -term avera e discharge rate MGD MGD For batch discharges report:

No. of decant cycles CYCLES/DAY Length of each decant cycle MIN.

Average decant discharge flow rate GPM

3. Total Process Vfiscellaneous iVonmContact Coolin and Sanitary Wastewater Miscellaneous wastewater - transformer area and parking area

a. Source(s): run o ff.

h. Discharge Occurs: 1 arstcsy: csystwtc git csyslyr. i msmeslyr ~ 1993)

Duringwhichmonths? Can occur. in all months; dependent on parking lot area runoff For continuous discharges report:

a~vera e discharge rate associated with the

'he month of maximum production. H/A VIGD For intermittent or seasonal discharges report:

Thelon -termavera edischarge rate 0.0087 MGD 0.01?4 MGD ER.BHQ-288.10t Rev. 6I93 3 of 3 SECTION C (continued) NPDES Number PA 0047325

4. Stormwater Runoff (Only if in combination with any of the above wastewaters. If outfall consists of only stormwater, complete Section D) otherwise complete Section D for the stormwater contribution and Section C foi contributions from other wastewaters. N/A Drainage Area

~R'nfall inches) Size Units Conversion Factor Volume Units X Fts X 0.623 Gallons YV X 6.61 Gallons X Acres X 27.162 Gallons IIL REQUIRED AND OPTIONAL ANALYSES

1. tional Site-S cific Toxics Data Use the space below (attach additional sheets if necessary) to provide any of the optional site-speciTic information discussed in Appendix 2. (The Analyses Results Table should be used'o report intake water quality, upstream background or ambient water quality, and parameter specific'coeQicient of eGluent variability. Space is provided at the top of the table to provide description of sampling points used.)

Optional Toxics Data is attached to Application P YES Gtj NO ER-BWQa288.10: Rev. 6/93 lof 3 SECTION C (continued) NPDES Number PA 0047325 IL SOURCES OF WASTEWATER CONTRIBUTING TO OUTFALL NUMBER~07

1. Process Wastewater (Unit 2 Turbine Bldg., Low Volume Waste Sump)

a. Describe process and type of wastewater: N/A

b. Applicable EPA EGluent Limitation Guideline: 40 CFR Category/Subcategory

c. 'Maximum Monthly Production Rate:

Of Product Month%hen Representative Days/Month s " Production Occurs Production Occurs

d. Discharge Occurs: emlsay; Csysask; Sayslys: mnnlaalyr.

During which months?

For continuous discharges report:

Tiie ~seers e discharge rate associated with'the month of maximum production. MGD For intermittent or seasonal discharges report:

The ion -term avera e discharge rate MGD The maximum dail v discharge rate- MGD For batch discharges report:

No. of decant cycles CYCLES/DAY Length of each decant cycle MIN.

Average decant discharge rate GPM Process Wastewater N/A

a. Describe process and type of wastewater:

b. Applicable EPA Effluent Limitation Guideline: 40 CFR Category/Subcategory

c. Maximum Monthly Production Rate:

Of Product Month When Representative Days/Month Quantiti Units of Measure (or ratv material used) Production Occurs Production Occurs

d. Discharge Occurs:

During which months'?

hrs/day; For continuous discharges report:

'ayslyr; days/vg man shslyr.

The ~avera e discharge rate associated with the month of maximum production. MGD For intermittent or seasonal discharges report:

The ion -term avera e discharge rate sVGD MGD ER.B%FQ-288.10: Rev. 6I93 2of3 SECTION C (continued) NPDES Number PA 0047325 For batch discharges report:

. No. of decant cycles CYCLES/DAY

, Length of each decant cycle iMIN.

Average decant discharge rate GPM II. SOURCES OF WASTEWATER FOR OUTFALL 074

2. Other Wastewater Contributin to this Outfall See NO. 3 Bel OW (Description)

a. Source(s):

h. Discharge Occurs: tucrdcy: dcycartc monuig/yg During which months' For continuous discharges report:

The a~vere e discharge rate assoeiated with the month of maximum production. MGD For intermittent or seasonal discharges report:

The ion -term avera e discharge rate MGD MGD For batch discharges report:

No. of decant cycles CYCLES/DAY I.ength of each decant cycle MIN.

Average decant discharge flow rate GPM

3. Total Process Miscellaneous Non-Contact Coolin and Sanitary Wastewater Miscellaneous Wastewater-transformer area, parking area runoff a.

h.

Source(s):

DiSChargeOCCura: 1 tuerde .. Ceyevt; Ã Ceyeyu i mcmaoyr ~iggg I Duringwhichmonths? Can occur in all months, de endent on parking area runoff For continuous discharges report:

The a~vera e discharge rate associated with the month of maximum production. N A MGD For intermittent or seasonal discharges report:

The ion -term avera e discharge rate 0.0087 MGD MGD ER.BNQ-288.10: Rev. 6I93 3of3 SECTION C (continued) NPDES Number PA 0047325

4. Stormwater Runoff (Only if in combination with any of the above wastewaters. If outfall consists of only stormwater, complete Section D) othervrise complete Section D for the stormwater contribution and Section C for contributions from other wastewaters. N/g Drainage Area l~lfall inehesl Site Units Conversion Factor Uolume Units Fts X 0.623 X Y6t X 6.61 heres X 27.162 a IIL REQUIRED AND OPTIONAL'NALYSES

1. tional Site-S cific Toxics Data Use the space below (attach additional sheets if necessary) to provide any of the optional site-specific information discussed in Appendix 2. (The Analyses Results Table should be used to report intake water quality, upstream background or ambient water quality, and parameter specific coeQicient of eQluent variability. Space is provided at the top of the table to provide description of sampling points used.)

Optional Toxics Data is attached to Application gYES g NO

-9<<

ER.BWQv288.10: Rev. 6/93 lof3 SECTION C (continued) NPDES Number PA 0047325 IL SOURCES OF WASTEWATER CONTRIBUTING TO OUTFALL NUMBER (Peach Stand Pond)

1. Process Wastewater a.'escribe process and type of wastewater: N/A

b. Applicable EPA EQluent Limitation Guideline: 40 CFR Category/Subcategory

c. Maximum Monthly Production Rate:

Of Product Month When Representative Days/Month e Production Occurs Production Occurs d; Dhcimrge Occurs: hrryeen os?wet: oeysryr. mccuuryr.

During which months?

For continuous discharges report:

The ~ayers e discharge rate associated with'the month of maximum production. MGD For intermittent or seasonal discharges report:

The ion -term avera e discharge rate MGD The maximum dailv discharge rate MGD For batch discharges report:

No. of decant cycles CYCLES/DAY Length of each decant cycle MIN.

Average decant dischar'ge rate GPM Process Wastewater N/A

a. Describe process and type of wastewater:

b. Applicable EPA Effluent Limitation Guideline: 40 CFR Category/Subcategory c.'aximum Mionthly Production Rate:

Of Product Month When Representative Days/Month Qusn~ti Units of Measure tor raw material used) Production Occurs Production Occurs v

d. Discharge Occurs: enycsn days/wk; days/yr, months/yr.

During which months?

For continuous discharges report:

The ~ayers e discharge rate associated with the month of maximum production., MGD For intermittent or seasonal discharges report:

The ion -term aver a e discharge rate MGD The maximum dail discharge rate MGD ER-BWQ-288.lo: Rev. 6/93 2of3 NPDES Number PA 325 For batch discharges report:

No. of decant cycles CYCLES/DAY Length of each decant cycle i%IN.

Average decant discharge rate GPM II. SOURCES OF WASTEWATER FOR OUTFALL

2. Other Wastewater Contributin to this Outfall See No. 3 Below (Description)

a. Source(s):

h, Discharge Occurs: tawdey. dayeevk; 'eyeyya months/yr During which months?

For continuous discharges report:

The a~vera e discharge rate associated with the month of maximum production. MGD For intermittent or seasonal discharges report:

The ion -term avera e discharge rate iVGD v iVIGD For batch discharges report:

No. of decant cycles CYCLES/DAY Length of each decant cycle i%IN.

Average decant discharge flow rate GPM

3. Total Process Miscellaneous Non-Contact Coolin and Sanitary Wastewater Runoff from paved roads, roof drains; Discharges from Outfalls 072, 073, 074 Oh>scharge Oscars: krwday; deyeivk; deywyr., monthslyr During which months? Rain de endent For continuous discharges report:

The a~vera e discharge rate associated with the month of maximum production. 'MGD For intermittent or seasonal discharges report:

The ion -term avera e discharge rate iXGD iMGD ER BVFQ-288.10: Rev. 683 30f 3 SECTION C (continued) NPDES Number PA 0047325

4. Stormwater Runoff (Only if in combination with any of the above wastewaters. If outfall consists of only stormwater, complete Section D) otherwise complete Section D for the stormwater contribution and Section C for contributions from other wastewaters.

Drainage Area

~Rainfall inches) Sire , Units Conversion Factor Volume Units Fts X 0.623 1.92 x 107 Gauons X Acres X 27.162 a IIL REQUIRED AND OPTIONAL ANALYSES

1. tional Site-S cific Toxics Data Use the space below (attach additional sheets if necessary) to provide any of the optional site-specific information discussed in Appendix2. (The Analyses Results Table should be used to report intake water quality, upstream background or ambient water quality, and parameter specUic coefficient of effluent variability. Space is provided at the top of the table to provide description of sampling points used.)

Optional Toxics Data is attached to Application @YES Q NO ER-BWQ.288.10: Rev. 6/93 lof3 SECTION C (continued) NPDES Number PA 0047325 II. SOURCES OF WASTEWATER CONTRIBUTING TO OUTFALL NUMBER 077

1. Process Wastewater (Un j tl Condensate Storage Tank Bermed Area)

a. Describe process and type of wastewater: "/A

b. ApplicableEPAEQluentLimitationGuideline: 40CFR Category/Subcategory

c. Maximum Monthly Production Rate:,

OfProduct Month When Representative Days/Month Production Occurs Production Occurs

d. Discharge occurs: tuereen cerrroto darcrrn mcoucrrr.

During widch months?

For continuous discharges report:

The ~overs e discharge rate associated with'the month of maximum production. MGD For intermittent or seasonal discharges report:

The ion -term avera e discharge rate MGD The maximum dailv discharge rate MGD For batch discharges report:

No. of decant cycles CYCLES/DAY Length of each decant cycle MIN.

Average decant discharge rate GPM Process Wastewater N/A

a. Describe process and type of wastewater.

b. Applicable EPA EQluent Limitation Guideline: 40 CFR Category/Subcategory

c. Maximum Monthly Production Rate:

Of Product Month%hen Representative Days/Month Quantiti Units of Measure ter raw material usedl Production Occurs Production Occurs During which months?

For continuous discharges report:

The ~avera e discharge rate associated with the month of maximum production. MGD For intermittent or seasonal discharges report:

The ion -term avera edischarge rate MGD MGD

'7-

2of3 ER BR@-288,lo: Rev. $ 83 SECTION C (continued) NPDES Number PA 0047325 For'batch discharges report:

No. of decant cycles CYCLES/DAY Length of each decant cycle iVfIN.

Average decant discharge rate GPM II. SOURCES OF WASTEWATER FOR OUTFAI.L 077

2. OtherWastewater Contributin to this Outfall See No. 3 Below (Description)

a. Source(s):

h. Discilarge Occurs: tusldsy; dsysertu dsysryu mcctaslyr During which months?

For continuous discharges report:

The a~seta e discharge rate associated with the month of maximum production. MGD For intermittent or seasonal discharges report:

'helon -termavera edischargerate MGD iMGD For batch discharges report:

'o. of decant cycles CYCLES/DAY Length of each decant cycle iaaf lN.

Average decant discharge flow rate GPM

3. Total Process Miscellaneous Non-Contact Coolin and Sanitary Wastewater Area draiins, storm water, and Condensate Storage Tank drains

a. Source(s):

Dhcharge Occurs: ersfdsy; y dsssrs deyslyr. mcmaoy During whichmonths? Discharges can be sent either to Liquid Radwaste or s orm rains. ere as never ee o storm For continuous discharges report: drains.

The a~sera e discharge rate associated with yhe month of maximum production. N/A MGD For intermittent or seasonal discharges report:

The ion -term avera e discharge rate 0.0083 iMGD MGD"

• Design flow 30f 3 EB BWQ-288.10: Bev. 6I93 SECTION C (continued) NPDES Number PA 0047325

4. Stormwater Runoff (Only if in combination with any of the above wastewaters. If outfall consists of only stormwater, complete. Section D) otherwise complete Section D for the stormwater contribution and Section C for contributions from other wastewaters. ti/A Drainase Area

~Rainfall inches> Slee Units Conversion Factor Volume Units 0.623 Gallons 6.61 GaDons X Acres X 27.162 Gallons IIL REQUIRED AND OPTIONAL ANALYSES L tional Site-S cific Toxics Data Use the space below (attach additional sheets if necessary) to provide any of the optional site-specific information discussed in Appendix 2. (The Analyses Results Table should be used to report intake water quality, upstream background or ambient water quality, and parameter specific coeQicient of eQluent variability. Space is provided at the top of the table to provide description of sampling points used.)

Optional Toxics Data is attached to Application @YES Q NO

ER BWQ 288.10: Rsv.6/83 1 of 3 NPDES Number PA '0047325 II. SOURCES OF WASTEWATER CONTRIBUTING TO OUTFALL NUMBER 078 (Unit 2 Condensate Storage Tank Bermed Area)

1. Process Wastewater

a. Describe process and type of wastewater: N/A

b. Applicable EPA EIIluent Limitation Guideline: 40 CFR Category/Subcategory

c. Maximum Monthly Production Rate:

OfProduct Month When Representative Days/Month Production Occurs Production Occurs

d. Discharge occurs: tus/cey: ceysart: caysryr. weeuuryr.

During which months?

For continuous discharges report:

The ~ayers e discharge rate associated with'the month of maximum production. MGD For intermittent or seasonal discharges report:

Thelon -termavera edischargerate MGD The maximum dailv discharge rate iVIGD For batch discharges report:

No. of decant cycles CYCLES/DAY Length of each decant cycle MIN.

Average decant discharge rate GPM Process Wastewater N/A

a. Describe process and type of wastewater:

b. Applicable EPA EIIluent Limitation Guideline: 40 CFR Category/Subcategory

c. Maximum Monthly Production Rate:

Of Product Month When Re prescntative Days/Month Quantity Units of Measure lorrassy matsrial used) Production Oeeurs Production Occurs

d. Discharge Occurs: envcay: cayaevt: Caysryn weeuvyyr.

During whish months?

For continuous discharges report:

The ~ayers e discharge rate associated with the month of maximum production. MGD For intermittent or seasonal discharges report:

The lon -term avera e discharge rate MGD MGD ER-Bw'Q-2B8.10: Rev. 693 2 of 3 SECTION C (continued) NPDES Number PA 0047325 For batch discharges report:

No. of decant cycles CYCLES/DAY Length of each decant cycle i%IN.

Average decant discharge rate GPM II. SOURCES OF WASTEWATER FOR OUTFALL 078

2. Other Wastewater Contributin to this Outfall See No. 3 Below v

(Description)

a. Source(s):

h. Discharge Occurs: tur/sey: Says/air. 'eyeryu gnonths/yg During which months?

For continuous discharges report:

The a~vera e discharge rate associated vath the month of maximum production. MGD For intermittent or seasonal discharges report:

The ion -term avera e discharge rate iVIGD MGD For batch discharges report:

No. of decant cycles CYCLESIDAY Length of each decant cycle MIN.

Average decant discharge flow rate GPM

3. Total Process Miscellaneous iVon-Contact Coolin and Sanitary Wastewater h

Source(s): Area drains, storm water, and Condensate Storage Tank, drains 12 d During which months?

For continuous discharges report:

The ~overs e discharge rate associated with the month of maximum production. MGD For intermittent or seasonal discharges report:

• The ion -term avera e discharge rate 0.0083 MGD 0.019 MGD **

• Estimated from Outfall 077

"*Design flow ER.BNQ-288.10t Rev. 6I93 30f 3 SECTION C (continued) NPDES Number PA 0047325

4. Stormwater Runoff (Only if in combination with any of the above wastewaters. If outfall consists of only stormwater, complete .Section D) otherwise complete Section D for the stormwater contribution and Section C for contributions from other wastewaters. N/A Drainage Area "

~Rainfall inches) Sire Units Conversion Factor Volume Units X Fts X 0.623 a Gallons Y6s X 5.61 Gallons Acres X 27.182 Gallons IIL REQUIRED AND OPTIONAL ANALYSES

1. tional Site-8 cific Toxics Data Use the space below (attach additional sheets if necessary) to provide any of the optional site-specific information discussed in Appendix 2. (The Analyses Results Table should be used to report intake water quality, upstream background or ambient water quality, and parameter specific coeHicient of effluent variability. Space is provided at the top of the table to provide description of sampling points used.)

Optional Toxics Data is attached to Application Q YES tIIj NO e

ER.BWQv288.10I Rev. 6/83 lof3 t SECTION C (continued)

IL 1.

SOURCES OF WASTEWATER CONTRIBUTING TO OUTFALL Process Wastewater iNPDES Number PA (Sewage Treatment 0047325 NUMBER~

Plant)

a. Describe process and type of wastewater: N/A

b. Applicable EPA EQluent Limitation Guideline: 40 CFR Category/Subcategory

c. Maximum Monthly Production Rate:

OfProduct Month%hen Representative Days/Month r Production Occurs Production Oeeurs

d. Discharge Occurs: hoyden Cayslok Caystyn mvolhslya .

During which months?

For continuous discharges report:

The ~overs e discharge rate associated with'the month of maximum production. MGD For intermittent or seasonal discharges report:

The ion -term avera e'discharge rate MGD MGD For batch discharges report:

No. of decant cycles CYCLES/DAY Length of each decant cycle MIN.

Average decant discharge rate GPM Process Wastewater

a. Describe process and type of wastewater: N/A

b. Applicable EPA EHluent Limitation Guideline: 40 CFR Category/Subcategory

c. Maximum Monthly Production Rate:

Of Product Month When Reprcscntative Days/Month Quan~ti Units of Measure (or rangy material used) Production Occurs Production Occurs

d. Discharge Occurs:

During which months?

tusrcsy:

For continuous discharges report:

'ays/yn days/w ?no nths/yr.

The ~ayers e discharge rate associated with the month of maximum production. MGD For intermittent or seasonal discharges report:

The ion -termavera edischargerate iVGD MGD ER-BVFQ-288. t0: Rev. $ 93 2of3 SECTION C (continued) NPDES Number PA 0047325 For batch discharges report:

No. of decant cycles CYCLES/DAY Length of each decant cycle iMIN.

Average decant discharge rate GPM II. SOURCES OF WASTEWATER FOR OUTFALL 079

2. Other Wastewater Contributin to this Outfall See No. 3 8elow (Description)

a. Source(s):

Djscharge Occurs: km/dsy; days/vtc 'ays/yr: mccrks/yr During which months?

For continuous disc)barges report:

The ~ayers e discharge rate associated with the month of maximum production. MGD For intermittent or seasonal discharges report:

The ion -term avera e discharge rate MGD MGD For batch discharges report:

No. of decant cycles CYCLES/DAY Length of each decant cycle MIN.

Average decant discharge flow rate GPM

3. Total Process Miscellaneous iVon-Contact Coolin and Sanitary Wastewater

a. Source(s): Sani tary WasteS

h. Discharge Occurs; 24 km/dsy: 7 dsys/vk; ggg drys/yr, mecres/yr During which months? Al 1 mOnthS For continuous discharges report:

The a~vera e discharge rate associated with the month of maximum production. 0.0280 MGD" For intermittent or seasonal discharges report:

The ion -term avera e discharge rate MGD iVIGD

• Average discharge rate from March 1993, month of highest electrical production in 1993.

ER BS'Q 288.10: Rev. 6I93 30f3 SECTION C (continued) NPDES Number PA 00'l73~5

4. Stormwater Runoff (Only if in. combination with any of the above wastewaters. If outfall consists of only stormwater, complete. Section D) otherwise complete Section D for the stormwater contribution and Section C for contributions from other wastewaters. N/A Drainage Area

~Rainfall ineh13) Size Units Conversion Factor Volume Units Fts X Q.623 Gallons Y6s X 6.61 X Acres X 27.162 Gallons III. REQUIRED AND OPTIONAL ANALYSES

1. tional Site-S cific Toxics Data Use the space below (attach additional sheets if necessary) to provide any of the optional site-specific information discussed in Appendix 2. (The Analyses Results Table should be used to report intake water quality, upstream background or ambient water quality, and parameter specific coeKcient of eQluent variability. Space is provided at the top of the table to provide description of sampling points used.)

Optional Toxics Data is attached to Application P YES Q NO

ER-BWQv288.10: Rev. 8/93 lof3 SECTION C (continued) iVPDES Number PA 0047325 II. SOURCES OF WASTEWATER CONTRIBUTING TO OUTFALL NUMBER 080

1. Process Wastevrater (C-1 Pond)

N/A

a. Describe process and type of wastewater:

b. Applicable EPA EQluent Limitation Guideline: 40 CFR Category/Subcategory

c. Maximum Monthly Production Rate:

Of Product Month When Representative Days/Month e Production Occurs Production Occurs

d. Discharge Occurs: harden days/gr months/yr.

During which mcnthsv For continuous discharges report:

The ~seers e discharge rate associated with'the month of maximum production. MGD For intermittent or seasonal discharges report:

The ion -term avera e discharge rate MGD The maximum dailv discharge rate NGD

. For batch discharges report; No. of decant cycles CYCLES/DAY

'ength of each decant cycle MIN.

Average decant discharge rate GPM Process Wastewater N/A

a. Describe process and type of wastewater:

b. Applicable EPAEQluentLimitationGuideline: 40CFR Category/Subcategory

c. Maximum Monthly Production Rate:

Of Product Month When Representative Days/Month Quantiti Units of Measure lor rett? material used) Production Occurs Production Occurs

d. Discharge Occurs: hrs?den dere/etc dsrrrrn Illoouulrr.

During which months?

For continuous discharges report:

The ~secre e discharge rate associated with the month of maximum production. NGD For intermittent or seasonal discharges report: '

The ion -term avera e discharge rate NGD MGD

ER.BWQ-288.10: Rev. 6/I 2of3 SECTION C (continued) NPDES Number PA 0047'325 For batch discharges report:

No. of decant cycles -CYCLES/DAY Length of each decant cycle MIN.

Average decant discharge rate GPM II. SOURCES OF WASTEWATER FOR OUTFALL '80

2. OtherWastewaterContributin tothisOutfall See No. 3 HeloW (Description)

a. Source(s):

r

h. Oischarge Occurs: scarce@: dsysart; 'ays/yu ntonths/yt During which months?

For continuous discharges report:

The ~ayers e discharge rate associated with the month of maximum production. MGD For intermittent or seasonal discharges report:

The ion -term avera e discharge rate MGD The maximum dailv discharge rate MGD For batch discharges report:

No. of decant cycles CYCLES/DAY Length of each decant cycle MIN.

Average decant discharge flow rate GPM r

3. Total Process Miscellaneous Non-Contact Coolin and Sanitary Wastewater

a. Source(s): RUnoff from paved roads, roof drains dayslvkr dayslyr: wsaualyr During which months? Rain dependent For continuous discharges report:

The a~vera e discharge rate associated with the month of maximum production. MGD For intermittent or seasonal discharges report:

The ion -term avera e discharge rate MGD MGD ER.BWQ-28$ .10: Rev. 6/93 30f 3 SECTION C (continued) NPDES Number PA 0047325

4. Stormwater RunoK (Only if in combination with any of the above wastewaters." If outfall consists of only stormwater, complete Section D) otherwise complete Section D for the stormwater contribution and Section C for contributions from other* wastewaters.

Drainage Area

~Rabd'all inehesl Site Units Conversion Factor Volume Fts X 0.623 106'nits Gallons 4.7 x 1.6 x 10 var x 6.61 ~ 4.2 x Gallons Acres X 27.152 IIL REQUIRED AND OPTIONAL ANALYSES

1. tional Site-S cific Toxics Data Use the space below (attach 'additional sheets if necessary) to provide any of the optional site-specific information discussed in Appendix 2. (The Analyses Results Table should be used to report intake water quality, upstream background or ambient water quality, and parameter specific coeQicient of eQIuent variability. Space is provided at'the top of the table to provide description of sampling points used.)

Optional Toxics Data is attached,to Application @YES gg NO ER-BWQ-288.10: Rev. 6/93 SECTION C (continued) NPDES Number PA 004 7325

'II. REQUIRED AND OPTIONAL ANALYSES

2. Summary of Re uired Analvseo Work~hect ALL DISCHARGERS SUBMIT THIS WORKSHEET WITH YOUR APPLICATION e e '

Discharge Contains (see Pollutantsor Pouutant Required No.

Outfall instructions for Section C, Part ID GW Storm- ol Sam pie Cleanup mater Groupings which must be Events.

Number Sampled ror and Analyzed Process Sanitary Misc. (see C JQ)

Waste Waste 'aste No e 070 See Note 1 071 Grou s 1,2,3,4,5,7,8 072 2C,3C,4C,5C,?C,12C, 16C 18M 073 See Note 2 2C 3C 4C 5c,jc 12C 16C ote 5 See Note 1

~ OT7 078 4C,7C,12C See Note 3 1C 4C 6C 9C 11C,12C 14C 16C 18C o e 5 1C,2C,4C,6c,jc,9C,12C 1 14C 16C 18C,Note 4 Np e Grou s 1 2 3 4 5 7 8 Notes: 1) 0 tfal 1 070, 75, a d 080 e simi ar 2} 0 tfal 1 073 a d 074 are si i lar 3 0 tfal1 077 a d 078 are si ilar 4 Ttal K eldahl Nitro en sam led 5 S e Sec ion C- for dditio 1 info mation

'UBMITTHIS TABLE WITH YOUR APPLICATION ee

i

)L

)LR LM RRR HEI EE RSEI RREI LWEE

older S.II uIIS( COO.su: ttuV.

SECTION C (con(inued) NPI)l:S Number l'A III. IIEQUIIIEI)ANI) Ol'I'IONAI. ANAIoYSES s

3. Anal ses llesults Q Outfall Sampling Results (I~cute Suntpling I'oint on Line l)rawing required by Question A.la)

Q Outfall Nuntber tip(I g Results-Optio a'l(Spectly Sou c Q Ups(roon( Background Sample Results - Optional (Specify Location of Sample Q Treatment Facility inliuent Sampling Results(Locate Sumpling Point on Line Drawing required by Question A.la Q New Discharge(Describe basis fur inforntotion presented,see Instructions for Section C, I'urt II S. Ifyou have any cesson tu espocl the puuutant tube Accept. 3. Lovel I'cosont 4, Un(to 5. auras otly presonl ln this dlschecg>>, check the eppcupclate

~ bl>> I. 2. CuoNcloat bloch or describe another cooson.

Pollutunt Dotec. Dotocuua UPA a. Mos Dally Value b. Avocaxo of Analyses of tlun Lovel Method affluent false.

Group2 Level o Used Nucoboc Cuncoa. Ceacon-Nuasboc uf Con ceo. Mass Vaclabtttty Raw Manu. Iaedlste Ily Intake other (itgn) (Itgn) Used tcatloa bless tcetlun Me ~ s Analysis teat!on tl:Vl Matoclsl lectured Product I'cuduct Water tUsplslnt 13C Color 110.2 17 N/A 1 Pt-Co N/A 14C Recul coli(onn 92220 875 8/100 15C Rluuritle 100 100 340.2 COo10 mg/1 16C Nitrute.Nitrite 353.2 0.8 (ns N) 1'IC Nitrogen, Total Organic (us NI CalCo 1.22 18C Phosphorus (oy P), Total 365. 1 4 0. 10 19C Sulfute los SO) 1,000 0 375e4 13.6 20C Sullide (as Sl l,aaa 1000 376.1 41 21C Sul lite (os SO) 2,000 1000 377.1

• 41 22C Sttrfuctsltts 25 (h(IIAS) 10 425.1 40.01

3. Ifother tlutu is available(i e. DMR data, elc ), the psst year of data tnay be used to detertnine 3a,3b,3c, and 5.

3a Maxintum l)uily Value- Report tho ~hi chest daily value or duily averuge value frohl the last year of data. Iieport bothmass and concentration.

3 b Average of Analyses. l)etermine the average of all samples taken within the past year. Report both mass and concentration.

3 c A ntinintutn of Lhree Suntpling Events required fur process wastewuter t(lschurges, uttd a ntininlum ol'one Sampling Event fur ull other discharges, (reat (nant I'ucility influertt, intake wuler uml background.

Moke copies ul'this Labia und check opprupriale box.

lt is in the upplicunt's interest to ucltieve u level ufdclectionut loust equal lo(or preferably ntore sensitive thunl those listed. This willtninimixuuncertainty and therefore the need fur <<dditional unulyscs or putontiul I'or estublishing a lurge number ol'cllluenL limits anti/or moniloring reqt rements in tlto finul Nl'DES permit.

v cot)tinued) NPI)ES Nunlbcl' A III. III'.QU 'I) ANIL Ol'I'IONAI. ANAI<YSII'S ',

3. Ani s Itcstlll.s Q Qutfull Sumpling Iles<<Its(Is<cute Sumpling Point on I.ine 'l)ruwing required by quostion A.IO)

Q Outfall Number l)ll I I k b n plingll its-()pti IISpe ifySourcuSque anna iVer Q U pstrcum lluckdro nod Sum pie lies wits - Optic nul (Specify Iaco tion of Sample Q 'I'reutmowt. I'u<ili:yI nilwent Sowipliiig Ilcsi<lts I Is<cute Sumpliwg I'oiwl ow I.ine I)ruwiwg required by (In<<etio>> A.10 Q New l)isclmrge Il)cscribu busis f<<r iiifurwiutiowpresented, seo Instructions fur Socliun C, Part II S. IIyuu buvs say rssvun iu especi ibu puUuiuni tubs Accepi. 3, tave< Proven< 4. Ifat<s d. our asuy proven< to <blc dhcbscev, cbscb ibs apprup<IMe sbie l. 2. Cueiflclea< bfocb or describe anu<ber res<on.

Pollutant Itv<ec. as<ection RPA a Mss <<say Vs<us ls Averecvor Ansiysvs c or Group 2 <ion Lave< Me<bud Nuaber FB)usa< In<sr.

<ave< U>>ed . Nuabsr Concea. Cuacen ul Cvncea. Mss ~ V sr Is bUI <y llaw Menu ~ aedtsis By In<ebs n<b.r (cunlinued) (pgll) (Iigj) ) Used irsdva Msvs <re<Ion Hsvs Aas<yvls <re<Ion iCV< Ms<sr)st <ac<aced 8<ared Pruduci Pcoduc< Wsivr Issp<sla<

IM Antimony.'I'otul 200 20 200. 7 ~20 N/A Ug Arsenic, Totul 60 10 3M lleryllium,Tolul 6 0.2 200.7 4:0.2 4hl Cudn<iu<w, Tolul C ~

Chr<ilwi<<In ~

Tutu) 60 200.7 IC,3 riiromiuwi, 5M I bib<<valent 218.4 dhl (;<<pper,'I'<<tul 20 200.7 7hI laud, 'I'otul 100 200.7 Shl Mercury,'I'ol wl 0.2 0.2 245.

9M Nickel, Tutul 40 200.7 d'3 IOM Sebi<i<i<I'ii Total 75 20 200.7 19 Silver, Totul 10 200.7 12M 'Iiiullium,'I'otal 100 200.7 13M Zinc, Total 200.7 36 14M (:yoni(ie, Totul 20 45CNC/E 14h( Cyunide, I"rce 2H

3. 11'utherdutu is uvsilublc ti e. !)hilldutu, etc), the post yeur of<lulu muy bc used to dctcrwiiwo 3o,3b,3c, sml 5.

3 u Muxiw<ul<w l)wily Vuli<c - uoport tile 1~11 I<os<doily vulwe or doily uveruge value froni the lust yeur ofdutu. Ihport both muss uiid concowtrution.

~

3 b Avi'rage el'Analyses- l)eterwiino lhe uveruge <<f wll suwiples token wilhiiitlie post year. Ilopurt boih iwuss uml cowcentrutiow.

3.c A wiinimum <>L for ull otlier discliurges, trcuuweiit'fiicilityi<iauewt, intuke water uwd buckgrouw J.

hluke copies of this tuble uml clierk upprupriute box.

IL is in the upplicunt's interest tu uchi eve u level uf detection ut least eqwul tu (or preferably wiore sensitive t liow) thuse listed. 'I'his willniiwiwiise uncertui>>ty u wd L herc l'on .'ie weed fur add itionuI unulyscsor the potentiul fiireslahiishiwg u largo nun<her of enluent liiwitsumllor nionitoring requirements in tlie final Ni'DES permit.

- l3-

~ ~ vv ~ ~ v~ vt ctuv.l tl ttviv, tvlti ~

SECTION C (cuntintted) Nl'l)ES Number I'A 0047325 III. IIEQUIRI<:I) ANI) Ol'I'IONAI. ANAlrYSES u

3. Anttl ses Results Q Outfall Sumpling Results(locate Ssnipling> Point on I.ine Drawing required by Question A.IO)

Q Outfull Number p} Intuk Suml ling Results Optional(Speci('y Source

~ USqUe GDDB 1VeP Q Upstream Iluc .ground Sample Iiesults - Optional (Specify Idtcntion of Sample Q 'I'routinent I"ucilityInAuent Sunipling Results tldtcate Sampling Point. on Line Drawing required by Question A.IO Q Ncw l)isclmrgo ll)ascribe basis lor infi>rmu lion presented, seu Instrucliuns fiirSection C, I'urt II S. Ir you bsvo any reason tosspoct tho pouutant tube Accop'bl 3. 1>>vel Prevent 4. Iinlts 5. nuinvsuy present In thts dlscbsreo, chocb the appropriate

~ 2. I;uomclent biucb ur describe ~ vvuther roasun.

I olltttllu't Iieiec. Iieteciien III'A ~. Mes Iiotty Value b. Average of Analyses c, or iten I>>vot ~ totivud Klnuent I(vier Group 2 I>>vol Used Nu tuber Concen Cancan.

Nuvstver oI Coacon. Mass Vsrlsbtoty Bsvv Manu. rsodtsto By. Intake Other (cotllitiuetl) (pg/I) (pgv/I) Used Irstlun ~ Iovs tvatton Mess Analysts ifation ICVI Motorist /ectured Sturod Pruduct Product Water tb'splslni 16M Phenols,'l'otui 420.2 N/A 1 Ug/1 N/A Aiuminmn, IGM TQLnl 100 40 200.7 427 I'/M Barium, Tutu) 0.3 200.7 25 18h( Huron, Tutu i 100 10 200.7 19hl Cobalt, Total 60 20M Iron, Total 30 200.7 1050 21 hl Iron, Dissolved 30 200.7 199 Mugnesiuin, Total 20 200.7 2780 23hl Mulybdenuin, 100 200.7 4.'5 Total hlunguncse.

24hl 10 0.3 200.7 59 Totul 26M 'I'in,'I'utul 800 282.1 d.'3 26M Tituniuni, Tutu) 400 200 283.1 c200

3. Ifothcr dutu is avaiisble ti e. DhIR data, etc I, the past yeur uf data mny be used to determine 3a,3b,3c, and 6.

3.a Maximum l)oily Value - Report the ~hl vhest daily vuiue rrduily average value from the last year ofduta. RepurL both moss and concentration.

v 3.b Averuge of Anulyscs. I)etennine the average of all sainpies taken within the psst year. Report both mass and concentration.

3 c A minimum of three Sampling Events required I'or process wastewater discharges, nnd a minimum of one Sampling Event for all other discharges, treatinent fucilityinfluent, intake water und background.

Make copies of this table und check appropriule bus.

It is in ilia nplilituint's interest to <<chicvu u level of tlctccliun ut least cipiol lu (or prel'crobly more sensitive thun) those listed. 'I'his will tttittitttiyouncertuinty u>>tl tltercforo tlio nucd liirudditionui uiiulyacs nr lliu pnteiitiul liireatublishliig u largo ininibcr ofcllluent liniits anil/or Inonitoring requirements in Lite linui NPDES perinit.

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SI'.C I'ION C (continuetl) NPDES Number PA III. RI:QUlltl"I)ANI) OI'I'IONAI. ANAIsYSES e

3. Anal ses Results Q Outr.ll Sampling Results tbocute Sutnpling Point on I ine Drawing required by Question A.l0)

Q Outl'ull Number KI ltttukcSuntpltng Results Ol ttonul tSpeclfy Source uSque anna i Ver )

Q Upstream Huckgrouttd Sample Results -Optional tSpecify location ofSample )

Q Treatment Facility ) nAuent Sant pling Results t )+cate Sampling Point on Line Drawing required by Question A.l0 )

Q New Discharge (Describe basis fur information presented, see instructions for Section C, Part ll )

d. Ifyuubave say reason tu aspect the puuutsnt tubs Pollutant Accept.

~ bl>> 1.

3. bevel Present 4. Untts 6.

Cuefucleat aurmauy preseat In th4 discharge, check use spproprtste block or descrtbe another ressua.

Group 3 Detec. Detectlua EPA a. Mas Dsuy Value Iu Average of Aasfysee c uf Uoa Level Method Number Efnueat Inter Votstue Or Ssnlcs Im eel Used Number Cancan Codcea of Coacea. Mass VartsbWty uaw M eau. mediate By. Intake Other tcunllnuedl ()tgn) ()Iglt) Used trotted Mass tretton Mass Analysts trauoa tCVI Material factored Pruduct Product Water IEsplelal

-20V Methyl Hrontidc lo 10 624 c10 N/A 1 ug N 21V Methy!Chloride 10 5. 624 4 5 22V Methylcnc lo 624 d.5 Cl) luride 23V 1,1,2,2.Tetra. 10 chh>rocthunc 624 45 24V Tetruchluro. lo 624 ethylene 25Y Tcht one lo 5 624 26V 1,2-Truns Di ~

lo 624 c5 chlorocthylcno 27V 1, 1, 1 -'1'rich laru. lo 5 624 c5 cthattc 28V l,l 2 Trichloro. lo 5 624 c5 CLlltttto 29V 'l'richlcru. lo ctllylcnc 624 c5 31V VinylChloride 10 624 <10

3. Ifuther Jutu Is uvuilablc ti c. DMR dutu, etc 1, tltc past your of dots ntay be used to determine 3u,3b,3c, snd 6.

3u Maritnunt Daily Yulue. RepurL the i~st hcst doily vuluu or duily uvcrugc value from the last your of datu. Rcport both mass snd concentrution.

3.b Average of Analyses. Detertninc the average ofull ttutttplcs token within the pasLyear. Report bothmass and concentration.

3 c A minimbun of three Sampling Events required for process wastewater discharges, and a minimunt of one Sampling Event for all other discharges, treatment Facility innuent, intake wuter und background.

Make copies of this table and check appropriate bt>x.

it, is in the applicant's interest to achieve u lovel of detection at least equal to ler preferubly morc sensitive than) those listed. This willInini tulane uncertainty and therefore the need for additional unulyscs or the potential for establishing a large nutnber of cllluent litnits and/or monitoring requirements in the linal NPDES permit.

~ ~

. 'I'lON C (continueti) NPDES Number PA 00473 ill. RE/:l)

3. An es ANI) Ol'l'lONAl. ANAI.YSl"S ltesttlts o

a Q OutfallSainpling Results(IA!cate Sainpling I'oinlonl.inc l)rowing requiredby(fttestlon A.10)

Q Oul('ull Nun!her

)Q Intake Santpling Results. Optional (Specify Source Q Upstream Ilackground Sample Results -Optional (Specify Location of Sample Q Treutment Facility lnRuent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 Q New 1)ischurge (Describe basis Iur information presented, see instructions for Section C, Part !1 S. Ilyonhsvasnyfeaaollto ~ apeclihspuUstsnitube Poilu tttn t Accept.

able l. 2.

tnvet prevent 4. l!nits 5.

(natant nurrsaUy protest In thlr discharge, c hoch the opproprlata C blush ur deacrlbe snutber rosrun.

Group@ Detec. Detectlun UVA ~. Msr DaUy Value h Average ur Anslyeea c or Uun tnvet hiethud Number Elf!nant Intef Acid Fraction Intake Invel Deed Num>her Cancan. uf Cancan. Varlsbuliy Rsw Mann. tsedlate By.

Orgunics (pg/I) (pg/I) Used irauon Maes Cancan trot!un Msea Ans!yale tfallan Maaa tev! Material tsctured ht>>fed prudnci pruduct Waist'ther tsapialn!

IA 2.('.blur upltunul 10 5 625 45 N/A 1 Ug/1 ill/A 2,4.1) ichluru.

pltuttul 10 5 625 45 3A 2,4 Ditnuthyl ~

10 5 625 c5 pit e itul 4,6 Dinilru.u.

10 25 625 @25 5A C rcsul 2,4 phenul Dinitru.

50 25 625 i 25 6A 2.Nilruphenol 10 5 625 c5 VA 4-Nitrophenol 50 25 d'-25 P.Chluru nt-BA Cresol 10 625 c 5 Pentuchloro. c25 SA phenol 50 25 625 10A Phcnul 10 5 IIA 2,4,6.Trichloro-10 625 c5 phunol

3. Ifuther data is availublc (i e. DMR data,utc.l, thu pust year ofdatn may be used to determine 3n,3b,3c, nnd 5.

3 a Mnxintutn Daily Ynluc- Rcport the I~ti ~hcstdoily vuluc or doily avcrnge value from thc lnstycar of data. Report both mass and concentration.

3.b Average of Analyses- l)etermine the average ofnH samples taken within the pustyear. Rcport bolhmass nnd concentration.

3 c A minimum oflhree Sampling Events required for process wastewater discharges, and a mini!num ofono Sampling Event for nil other discharges, treatment facility inAuent, intuke water andbnckground.

h1uke cupies of this tuble und check appropriate box.

ee It is in the applicant'S intercsllo uchicve u level ufdutectiunnt luusluquul lo(or preferably more sensitive thnnl those listed. This will tninimise uncertainty and therefore the need for uddiliutinl unulysus or tits putcntiul lur establishing u lurgu nut tiber uf cRlttett t limits u>>d/or monituring require!no!its in lhe iinnl NP DES perniil.

SECTION C (continuo(i) NPDES Number I'A O047325 III. REQVIIIEI) ANI) Ol"l'IONAI.ANAIsYSES '

3. Anal scs I(os(tits Q Outfall Scrupling Results(I+cate Sutnpling Point on I.ine Drawing required by Question A.IO)

Q Oulfull Number Q lntuke Sampling Results-Optional (Specify Source uSque anna ) Ver p Upstraum Background Sample Results-Optional(Specify Location ofSample Q Trcutn>ent Pacility lnnucnt Sampling Results(Locate Sampling Point on Line Drawing requiredby Question A.IO p New Discharge (Describe basis li>r information presented,see Instructions for Section C, I'urt II Pollutant Accept 3. 4vst Present 4. Volts 6.

s. >(you bove nay reason to aspect the puss>sat tube Group 5 able l. 2. C rrlctsnt aureaa>ly present tn thts dtscbarge, chsc>L Ihe sppruprtate De>ec. OstecUon EPA b>och or deter>be eau>her reason.

Base Neutral ~ . Msa t)asy Value b. Average ur Analyses c or Uun Level Method >(umber Eructiun Erauent tnter-Inset Used Nun>her Concon. or Coacea. Male Var(chatty Maau- reed>ate By. la>she Other Organlcs (pgn) lpgn) treed traUoa Moss Cancan'rat>un Mess Ans>ysl ~ traUoa ICV>

Ran'ater>a>

~ cturod Stured Product Product Water IEaplara>

Acct>uphthcna 10 625 c5 N/A 1 ug/1 N/A 28 Acanaphthylena 10 625 c5 38 Anthrucena 10 625 48 Banzidine 60 25 625 c25 Bc>>zo (Ii) 68 Anthruccnc IO 625 c5 OB Bcn10 ln) I yret>l.',4 10 625 c5 Bat>zu-Auoru>>that>e 625 i5 88 8 el>zu Igll I )

Pcry lena 10 625 i5 Bl:I>zo (/I )

Plucrunthcne 10 625 c5 8 is l'2 Chlurc-108 crhuxyt hlcthune 10 625 c5 Bis l2 Chlcru.

118 ethyl) Ether IO 625 8 is (2.Chluro-128 iac/>rut>yl) Ether 10 625 c5 Bis(2-Frhyl-138 10 hrzylt I'htlmlutc 625 c5 4 Ilrcmophanyl 148 I'hen I Ether 10 625 c5

3. Ifothcr data is uvuilsble (i e. DMR dutu, atc ), tl>e pea(year of tlutu may be used Lo determine 3u,3b,3c, and 6.

3.s hluximun> l)oily value RaporL the I~>i hest daily value or duily svcrugc value from the Isstyaur ofdata. Rcport

~

both mass and concentration.

3 b Average cl'Analyses Dclarminc tl>a uverugc of all scn>plea taken within the past year.

Report both muss und concentration.

3 c A n>inin><<m oflhrac Scrupling Events required fcr pn>cess wuslcwutardischargcs, and u mini>num ofona Scrupling Event for ull other discharges, traatn>ent facility jt>Rue>u, intake wutcr uml background.

Muka co ties of this table anixa uncertainty and there(i>ra lhc s J Jit unulyscsor Lhc pctcntiul lur cstublishing u large nmnber ofclnucnt limits at>tl/c~nitoring requirements in r the linul NpDES permiL

III.

Q Q

A g3 coll Outfull Oulfull Intake bill tte es Res>Ill,s

)

REQt:D AN I) Ol'I'IONAL ANAI.YSI<:S '.

Sampling llasults I ld>cute Sampling I'uint on I ine Drawing required by Question A.l0)

Number Sampling IIcsults-OptiunuIISpecifySuurce SUS Ue anna i Ve) i NPDES Number l'A 004 "325 Q Upstreum Buckground San>plo Results. Optional I Specify Iacution of Sample Q Treatment I'acility InBuent Sampling Results llacate Sumpling Point on Line Drawing required by Question A. I 0 Q New Discharge (Describe basis for inforn>ation presented,see Instructions for Section C, Part II S. Ifyuubsvo any roasun >u ospoc>> ho pollutant >o bo Accep> 3, I>>vel pro<en> 4~ Ual>s 5. nur<nsuy proven> In >hfs dhchar So, chocb >ho appruprfa>o P0 I IU tBIIt ab>e l. 2. CuoNclsa> blurb ur describe anu>hor roasun.

I>e>ec De>oc>tua evh c uf Group 5 >Ion I>>vol bfe>hud

s. Mas I'>cay Value b. Aversse uf Analyses No<aber emu an> In>or.

Buso.Neutral I>>ve> Used Nun<bar Cuncea Cuncen. uf Cuacoa. Mass Varlabul>y Ita<v bfsnu. <audie>o Uy In>abo O>bor Fraction ()rgunlcs (I>g/I) Ii>gn) Used >rs>tun >rs>fua Maes Ans>ysls Its>tun >CV> M a>ella'> far>used S>used Vruduc> f'ruduc> Ws>er >bsp>sin>

Butyl Benzyl I'hthulutu 10 5 625 c5= N/A ug/1 N/A IGB 2.(:hloronaphthalcna 10 5 625 4 Chiuruphcnyl 17B I'henyl Ether lo 5 625 c5 18B Ohrysane lo 5 625 c5 Dibc>>su to,/>I 19B hnthracane lo 5 625 c5 20B 1,2.Dichlurubenzene 10 5 625 I 3.Dichlorobcnzeno 10 625 22B 1,4-1)ichlurubanzene 10 5 625 3.3'.Dichloro.

23B benzidinc 10 625 cl0 24B Diethyl Phthalate 20 5 625 25B Dimethyl Phthulata 20 5 625 c5 D>.N-Butyl 26B Phthulute 20 5 625 27B 2 4 Dinitrutuluena lo 5 625 28B 2,6 Dinitrotoluana 10 625 c5 29B Di-N Octyl Phthalate 2o 5 625 1,2.Diphenylhydra-3OB zine fas Azubenzenet 10 5 625

3. Ifuther dotu is available Ii a. DhlR data, etc ), Lhe past year ufduta may ba used to deter>nine 3a,3b,3c, and 5.

3 a hlaximun> Daily Vu)ue. Haporf the I~>1 <hest daily value or daily average vulua fru>n tl>e last year ofdatu. Report both muss uml concentration.

3 b Averugeol'Analyses-Determine I'hauverogeufullsumples8>kan within tl>e pastyear. Reportbutl> n>ussundconcentrution.

3 c A n>inimum ol'Lhree Su>npling Events required lor process wastewater discharges,and a minimum ofono Sampling Event for all other dischurges, treatment fucility inlluent, intuka wuter uml background.

Muka copies of this table u>ul check upprupriuto box.

IL is in tha applicant's interest to uchiavu u level el detection ut leust equal to lor prof< rably more sensitive than) thusa listed. This willn>ini>nize uncertainty and therefore Lhc need for a>hlitional unulyscs or the potcntiul for estublishing u large i>un>bcr ofelllucnt limits and/ur monituring requirements in the final Nl'l)ES peru>IL.

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>> Inue Nl'l)ES Nutnber I'A 004732' III. RE/VI <<D ANI) OP'I'IONAL ANAI<<YSES c

3. An s Results N/A Q Outfull Sampling Results tlecate Sumpling Point on Line Drawing required by Question A.IO)

Q Outfall Number KI lntuke Sumpling Results Optiunul (Specify Source SuS Uehanna Ri Ver Q Vpstreum Buckground Sample Results- Optional ISpecify I+cation ofSample P Treutment Pacility InAuent Sampling Results llA>cate Sampling Point on I ine Drawing required by Question A.IO Q New Discharge IDescribe basis for inl'ornmtion presented, sce Instructions for Section C, Part 11 Accept 6. d. Ifyou hovu any r<<a<<on >us<<poet >hop<<su>ant to bo abl ~ I. 2. 3. Iov<<l I'rusunt Volts Co<<IACI<<at au<<<<cally prus<<nt In th>s dbchurdu, chuck thu appruprlatu I'ollutttnt I><<tuc. I><<>oct>un BPA c, of b>ucb ur du<<crib<<<<nutbar ruasun.

Iov<ally Value b. Avoraduof Ana>ysos Iato<<.

Croup 6 Uun lavu> o<< t><<ud Ifuu>b<<r - Cancan. Concun.

>fun>bur of Conc<<a. Muss BII>aunt Var>ah>II ty Haw M aau. raodrato By. In><<ho Othor I'csticitlcs ( >gn) Ipg/I) U<<ud trot>un Iratlua Anu>rsrs traUon >CV> Mat<<rla> facturud Star<<d Pruduct Product Wat<<r tssp>atn>

IP A i>I rin 10 2P Alpha BIIC ID 3P Beta Bl IC 10 4P Con>n>a BIIC 10 5P Delta Bl IC 10 GP Chlortlune IO 71',4'DDT 10 Sl'.4'-DDE 10 9P 4,4'DDD 10 101'iehlrin 10 Alpha.

I IP Entlosulfon IO 12P Iietu-Endosulfun 10 Endosull'un 13P Sulfate IO 14P Endrin IO Endrin 15P Ahleh de 10 I GP I leptachlor 10 17P lleptuchlor 10 E >xide 25P 'I'oxsphcne 10 2GP I)IOXIN: 2,3, 7,8.Tetruchluro.

dibcnzo P Dioxin

3. Ifuther dutu is avuilablo(i e. DhIR <lots, etc I, the past year ufdstu tnuy be used tu dutern>ine 3s,3b,3c, und 5.

3 a hlaxin>um Doily Volt>e Report the ~hl <hest doily value or duily average vuluu from the last your ofdatu. Report bothmass and concentration.

~

3.b Average of Anulyscs- Determine tho average ol'ull sun>plcs taken within the past year. Rcport both n>uss and concentration.

3c A minimun> of three Sun>pling Events rvquired for process wustowutcr discharges, und a minimum uf one Satnpling Ev>nt for sll other discharges, treatment facility inllu<<nt, intuke wutcr u>ul background.

hh>ke copies uf this table and check appropriate box.

<< ~ lt is in the upplicant's interest to achieve u level of detection at least equal tutor preferably >nore sensitive than) those listetl. This will n>initnize uncertainty and tl>erefore tl>e need for odditio>n>l analyses or the potential I'or cstublishing u large number of elllut'nt limits and/ur monitoring requirements in the linul Nl'DES peru>iL

~ N ~ vIvu SECTION C (continue(I) NPDES Number I'A 111. REQUIRED AND OI'I'IONA1 ANALYSES s

3. Anul ses Itesults Q Outfall Sampling Results (I~cute Sat ttpling Point on I ine Druwing required by (luestiun A.IO)

Q Ou(full Numl>er Q lntakeSumpllng Results-Optionul(Spccily Source uS ue anna I Ver Q Upstreum Background Sample Results- Optiunal (Specily IAtcatiun ofSample Q Treatment Focility Influent Sampling Results ()~cate Sampling Puin( on Lin'e Drawing required by Question A.IO Q New Discharge (Describe basis for information presented, see Instructions for Section C, Part II lfyou have say rossoa lo aspect tho pouutsnt to be Accept. 3, Iovet present 6. duchsrso, chech tho eppruprlste Units norm say proseat ln thfs

~ ble l. 2. CoeNclent bluch ur describe aauther ressua.

Pollutant Delve. Detecuun SPA s. Mss Dsuy Value b. Average of Analyses c, of Group '1 tlun (mvel Methud Number SNueot Inter.

l lee Used Number Cuncea. Cuncon. uf Coacon. Mass Varlabulty (tsw Maau- medlste By. Intshe Other PCI3's I)tgr/I) (Itgn) Used tratlun Mesc trot(on hlass Analysts tratlon ICVI M starlet lectured S<<red product Product Water tgsplslnt 18P 8.1242 20 0.1 N/A ug/1 N/A PC 0.1 608 1 19P PC B-1254 20 0.2 608 0.2 20P PCB 1221 20 0.1 608 0.1 21P PCB-1232 20 O.l 608 O.l 22P PCB.1248 20 0.1 608 0.

23P PCB-1260 20 0.2 608 0.2 24P PCB-1016 20 0.1 608 0.1 3: 'fo(herds(a is available (i e. DMR data, etc ), the past year ofduta ntuy be used to determine 3s,3b,3c, and 6.

3.u Muxitnum Duily Value- Report tits I~tl <has(daily vulue or daily averuge value from the lust year ofdstu. Report both mass und concentration.

.3.b Average of Analyses. Determine the average ofull samples tuken within the psst year. Report buthmuss and cuncentrutlun.

3 c A minimutn of three Sumpling Events required fur process wsstewuter discharges, and a minimunt ol'one Sampling Event for all other discharges, treatment fucility inlluunt, intake water and buckgruund.

Make copies of this table and check appropriate box. I It is in the applicant's interest to achieve a level ofdctcction at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need I'or adtlitional analyses or (he potential fur eslablishing a large number of ellluent limits and/or monitoring requirements in the final NP DES permit.

III. Ith:QUIItl'.I) ANI) Ol'I'IONAI. ANAI.YSh:S '.

At BB IICBIIILB Q ull Ssn)pling Results lls)cute Sampling I'oint un ldnc l)ruwillg railuiredby (question A.IO)

Q Outfull Number tel lntuke Sun)pling Results-Optional(Specify Source SuS uehanna Ri Ver Q Upstream I)sckground Sample Results - Optional ISpccify Iucctian of Suinplc Q Trcutment Facility lnlluent Sampling Results I lacutc Sum pling Point an Line Drawing required by Question A.10 Q New l)ischurgc I l)escribc basis for infcrmution presented, sce Instructions fi)r Section C, I'art II

e. It yuuhsvo any rossun iu ocpoct iho poiiulani tub>>

Ace<<pl. 3. Invol prooon) 4, t)at)o 6. nor>>>auy pr>>o>>n) tn)h4 dtrcb>>rg>>, chocliih>>>>ppruprioio ohio I. 2. Co<<fact<<ni biuch ur doser tho anu)hor roarun.

I ollttttltlI, Dri<<c. I)<<)<<enon BI'A s. Msx t)at)y Va)uo Ia Avorsgo ut Ansiycsr c, uf L<<vrl Mo)hud Itu)abor Binuonl In)or.

Group B )tun Inv<<lo tiv<<d Itu>shor Conc<<a. Cuncon ur Conc>>a. Msr ~ V sr Is LUI)y Raw Manu. isodlo)o By- In)oh<< O)h>>r Ituiliouctlvity (pgn) Ilign) Bord irsiiun itaUon Moos Analy)tc uadoa iCV) htaiortoi sciutod B)>>rod Pruduci I'ruduci Wsior )K<<pi>>tnt lhnlicuctivity:

IR III Alpliu, Not Note 1 s0.7 1 pCi/1 N/A Avail.

Tctul able tul'ote 2R I2) llctu, Total 1 .9+ >>8 1 pCi/1 N/A Jlt: I JI Radium, Note 1 N/A 1 pCi/1 N/A

'I'i) 4R I4) Rudhn'n 226,'I'ctul Note 1 d 0<<3 1 pCi/1

3. Ifother ilutu is uvuilublc ti.a. Dhf R dutu, etc.), thc post yeur ofdutu nmy bc used to determine 3u,3b,3c, and 6.

I u ) Iushnun) l)uily Vuluc- Itcpcrt tl)c 1~)i >hast duily vulua ur duily uveruge vulue fi om thc lust year of data. Rcport both n)ass and ccncentrutton.

!I I) Average of Anulyses ~ l)ctcrminc thc uv) rugc of all sunq)les token within the psst yca)'. Rcport both muss )ii)d conccnlrution.

lt e A )ninin)mn uf three Sun) pling Events required Icr process wcstcwutcr discharges, ands minimun) of cne Sumpling Event fcr ull other disci)urges, treatment facility inllucnt, intukc wutcr und buckgrcund.

Moke copies of this table und check upprcpriutc bcs.

lt is in tlie ut) plicunt's interest to uchicvc a level ofdctcctiunut lcust equal to tor preferubly more sensitive thun) those listed. This will ininimixe uncertainty and therefore tha need fcr iolditiuncl analyses or thc potential for estub'iishing u lnrgc nu)nbar of clouant lin)its und/cr inunitoring requirenients in the final Nl'l)ES peru)it.

Note 1- Procedures used are from Teledyr)e Isotopes. See attached procedures.

- 23-

~ ss ~ ~~ ~ ~ si <<ssss ~ I ss ~ >loss. Iss Js>

SI ("I'ION C'col>Li>ttt<<tI) NI I)ls.S Ntti>>bt.> I A 0047325 III. Itl"QUIIII".I')ANI) Ol'I'IONAI. ANAIsYSI"S

<< I s 4.16 su Q OutfiillSsnipling Ilosults (ll>cute Snail>ling I'oi>>ton I iiie l)rowing required l>y (location A.l0)

QI outfall Nun>l>er 071 Cool in Tower Bl owdown Q lntuke Sumpling Ilesults - Optiunul (Specify Source )

Q Upstrcuni lluckt rounil Ssinpls llesults - Optionul (Specify ll>cation of Sample )

Q Troutment I'ucilsty inlluent Ssnipling llcsults (I+cate Sanipling I'oint on I ine Drawing required by (Iuost(o>i A.IO )

Q Now Discharge I ')cscribo basis for information presented, sce Instructions for Section C, Part II )

2. I.lkYI:I.PItl:SIINT 3. UNITS POLI.U'I'A Coefficient

1. h. Muxiniun> Jo l)uy Yulue c. IA>ng'I'erin Avgu. Vuluo d.

u. Muxiniuin l)uily Vulue (lfavailable) of Ef liuent (I f u vui labia) No. of N'I'IIOUI' Vurlul>llity Anulysds Concentration hluss (CV)

> I > Canc<<a>ra>lan I'lH as a IIICssssc<<nirails n IS>Mas ~ In Canc<<a>ra>lan Fl>Ma>a IC Illus!IicniiculOxygen Dcn>und, IIOI) 5.40 261.12 4.76 199.16 3 mg/1 1 bs/d 2(s Chcinical Oxygen I) niuml, Col) 52.5 1050.40 39.37 1423.51 3 mg/1 1 bs/d

'fatal Orguliic (!urban,

'I'oc 10.0 500.65 10.0 394.76 mg/1 1 bs/d Ti>tul Suspcnileil Ss>l:>I I, 99.0 1980.76 54.67 1724.88 3 mg/1 lb s/d' TSS 5C 'I'otul l)issulved Suliils.

'I'l)S 484 24231.5 395.67 15666.5 3 mg/1 bs/d 6C Aminoniu us N c0.1 .01 COsl 3.95 mg/1 1 bs/d 7C Oil und Oreshc c2 c100 13 42 c 78. 95 mg/1 1bs/d SC lh amide F100. 13 c2 @. 78. 95 mg/1 1 b"./d 9('lilorll'ie I ulul Iles>o'.sul c0<<1 5.01 c 0.1 c3.95 mg/1 lbs IOC 'I'empcrsturo t'Cl ('C) ('C)

WliitI'r 24 Valua Valua

16. 25 IIC I('C) ('C) I'C)

Tcnlpcfsturi,'unin>er 30 Valua 26.6 Valua I 2C pil Minisa u as 7.9 9.0 Ma>>sauna standard ullits stundurd U i>I ta 2u hluxiinunl Daily Vuluc ll<<port lhe h~i<hcst daily vuluc ur sluily uvcrugo vuluc I'rani the lust y<<sr of dstu. I(cpurt buth muss und concentrution.

~

2 b hluxiinum.'ll) l)sy Vulu<< l)clcnnine the uvcrago ol'ull daily values iluring each cul<<nslur inc>>lhund rcport thv higlicst uveruge.

~

2c lusng Turn> Average Vuluc 'I'hs uvcrage of all values within the lust year snd report l>oth mass unde>>nrentrstiun.

2.d h(i>>iniun> ofllircc sampling events rcquircd lor process wastuwutcr discharges und u >ninimum ofono sampling ovont fi>r ull alber dischur'ges, trcutincnt fucility inilucnt und in>uk " ter.

0

SEC'VlON O (ctlnlintieti) Npl)LI'S Number l'A 00473 ill. ill<.'Q 'I) ANl) Ol'I'lONAl. ANAl.YSII-'S '.

Ani . Us llesillls Q Outfu)ISumpli .;; Ilcsult ll cute Su I lii g Puii t UJji l)ruwing r quirqd by Question A.IO)

Q Oulfull Nunil,:r 071 COOl i ng I OWer kl OWdOWn Q Intake Bumpling llesults-Optionul ISpecify Source Q Upstreuni lluckground Saniplo Itcsults- Optiunul tspecify I+cation of Sample Q Treutment Pacility Inlluent Sampling Itesults ILocate Sampling Point on I ine Drawing required by Question A.lo Q New l)ischurgo t Describe basis fur inforniotion presented, see Instructions for Section C, Part II

4. 'Ityonhavuanyceaaonlueapac'iihepuuuwltin be Accepi. 3. Level Pceceni 4. U nil ~ 5. auc4asy pcuc ant In ihle dbcb acge, cbach ihe eppcupc laic

~ bl>> I. 2. Cuemcleni bloch or doecctbo anoihac coacon.

l oil ututlt Iieiec. Oeiecilua UPA ~ . Haa naUy Value b. Average or Aaalycee c of Uun I@eel bi eihud IIU4 sec EUIueai )alee.

Group 2 Inset ee Used IIU4bec Cuncea. Cuacen. ul Cuncea. Hase Vactabuiiy Itaw H anu. 4edlaie Uy. Ialehe Uihec lug/I) ipg/I) Used icailoa ~ Ies ~ icadun Hase An aiyel ~ Icasoa ICVI Haleclel iaciUced Sluced Pcuducl Pcuducl Waiec Igaplalni l3C Color 110.2 56 N/A 5.33 /A 3 t-Co. N/A 14C Pccul Colilurw 92220 1275 N/A 27.3 3 /100 N/A

)5G Pliiii.ide Inc 100 340.2 0.29 14.52 .22 .75 3 g/1 1bs/d IGC Nitriite.Nitrito IosN) 353.2 4.3 215.28 3.77 149.63 3 g/1 1bs/d I7C Nitrogen, Tutul Orgunic lus N) CALC. 2.37 47.42 2.01 75.75 3 g/1 lb s/

IHC I'hospliorus los P), Totul 365.1 0.63 30.46 0.61 24.13 3 mg/1 1bs/

19C Sulfute Ios SOC) I,ooo 1000 375.4 126 2521 104.07 3898.6 3 mg/1 1bs/

39.48 lbs/

20C 2I G 22C Sumdo tos SI Sullito tos SO>I Surfuctonts I,oo'o 1000 1000 376.1 377.1 i cl.O 1.0 50.06 50.06 1.0 1.0 39.48 3 mg/1 mg/1 1bs/

lMIIAS) 10 425.1 0.02 1.00 0.017 .72 3 mg/1 1bs/

3. Ifother dutu is uvuiluble ti e. I)MIIdata, etc.), the post year i>fdstu muy be used to deterniine 3u,3b,3c, und 5.

3 4 Muximuni 1)uily Vulue- Ilepurt the ~hi <hest daily value or daily uveruge value frow Ihe lust year of data. Heport both insss and concentration.

3 b Averuge of Analyses l)etcrmine the average of all samples token within the pust year. Ilopurt both muss und concentrution.

~

3 c A niininiuin of three Sunipliiig I vents required for process wuatewulor dischurges, und u niiniinuni ufune Suinpling I)vent fiirull uthcr J iscliurges, treutinent fucility influent, intuke wuter und background.

h1uke copies ul'tliis tublu und check upprupriute bus.

It is in tlii'ulilllicunl's."iterestt<i achieve u level ofdetccliun ut leust cquul tutor prefi rsbly inure sensitive lhun) lliose listed. This will ininhnize uncerlainty siul therefore ti.e lliied fur additional miolyscs or potential I'Ur establishing a large number of Ul)luent liinits uiul/ur inonitoring requirements in tho finul Nl'DES pcrniit.

SI".O'I'ION C (cot)I)ttttctl) N pl)Es Nun)bcr pA 0047325 III. III"QUIIII"I)ANI) Ol'l'IONAI. ANAI<YSI"S a

3. Anol aos Itoatllts Q Ontfull Sun<pl ng ltesults t la<cata Suinpling I'oint on/ j<to I)towing rcquircd by (question h.l(l) 071,.Cooling lower I)iowaown Q Inluka Sun<pling Itasults- t)ptionul tSpecify Source Q Ilpstrcum ltuckgru<t>>d Sun<pic ltasults- 0ptionul tspacipy Is<cation of Sample Q 'I'rautn<<>><t I'neil.ty lnn<<ant Sumpling Itcsnltst la<cute Sun<pling I'oint on I ine l)ruwing required by (Inertia<< A.'IO Q Naw l)ischurga ll)cscribo 4usis for inforn<ution presented,aao Instructions Ior Section C, I'urt II S. Ifyuuhsvs say reasuo tu aspect Ihu putluleat tu be Accept 3. Is<eel I'reseat 4. to<Its 6. nuts<say prasest Iu Ibis discharge, check ihe appropriate sbte I. 2. Cu.<ncteot btuck or d<<scctbo south<<r res<os.

Pollutunt the<ac. ttelecaeu RPA s. Mas Oaay Value b. Average et Aaetyses c ot Group 2 <Iuu ta<vel h<e<bud I(u<sber h<oueat Islet.

tile@I Used I<u<aber Conceu. Cuucea. ut Cancan. hives Vs(lab<sty aaw hteau <uedta( ~ ny. In(ahe O(hec (contin(<a<I) lpg/l) Used Ira(les htass Ice(les Idaea As sty<la (ra(les (CVI his(eclat Iac(ured b<ored Produc( P<u lac< Water <E<pteta<

IM hntin<ony. Total 200 20 200. 7 d. 20 C ~ C ~ Ug 2M Arsenic, Tutul 20 Ug s/d 3hl Beryllium, Total 0.2 200.7 4 0.2 <0.01 40.2 3 ug/1 1bs d 4hI Cud<nium, Tutul 2 0.7 Ug s/d Chrontium, Tutul 50 200.7 0.12 44 0.14 3 ug/1 1 bs/d SM Chrumiunt, I laruvulcnf IO 218.4 42 XOe10 C2 c 0.08 3 ug/1 1bs/d 6hi Coil)<et'< Iutul 2t) 200.7 13 0.26 11 0.41 3 ug/1 1bs/d 7hi !A:ud, Totul IOO 200.7 35 0.70 16 . 0.45 3 ug/1 1bs/d Bhl Mercury, Tutul 0.2 0.20 245. 1 0.10 1.8 c 0.04 3 ug/1 lbs/d SM Nickel, Total 40 200.7 12 0.24 10 0.37 3 ug/1 1bs/d IOM Sah It<lust>> To<Ill 75 20 200.7 c20 4-0.40 413 0.46 3 ug/1 1 bs/d IIM Silver, Totul IO C 12M Thallium, Totul )00 200e9 C 1 d'.05 d'. 1 4 0.04 3 ug/1 1bs/d l3M Zinc, Total 200.7 1.26 42 1.45 3 ug/1 bs/d l4M (:yunide, Totul 20 4500CN/ ~5 ~0.25 45 c0,20 3 ug/1 1bs/d l4M Cyunida, I'rce 412H a5 d'-0. 25 d'-5 4'0.20 3 ug/1 lbs/

3. Ifutherdutu is uvailublc ti e. I)MIIdutu, etc ), tha pust yeur ofdutu<nuy bo used tu dcter<uine 3u,34,3c, und 5.

3 u Muximu<n l)uily Vulne- lluport tha i<i I<est doily vuh<e or duily uveroge vulua front the lust year of dut. Ilaport both n<uss und concentration.

3 4 Avarugo of Analyses ~ l)atennit<e the nveruge of all su<nplcs tnkcn wit hi>> the pust yeur. Ilcpnrt both n<uss and < oncentruti<n<.

3 c A <ninintum of tin <4<Sampling I vm<ts ruquired for process wastewater <1iscl<urgas, u<ul u n<initnun< of one S<(4<pling I':vot<t for ull other <lisclmrgcs, trauttncnt facility inl)nL<<t ~

it<tukc wutcr and buckgrotn<d.

hluke cop)I s of this tui. <a olid chLLk uppre pl'lute 4ox.

lt is in the et<)dieu(tt's interest touchicve u lovel of detcctiun ut )cost equal to tor. preferably mora sensitive thun) those listed. 'fhis will mini<nips uncertuinty uml therefore the need < udditionul uttulyscs or the potantiul fur establishing u large nuntber of cA)<<ant limits un<h<r munituring r

~ ~ ~

'tnonls in tho finul Nl'DES pcrmih

Sh:O'I'ION G (cot)i.ltlttotl) Nl l)lsS Ntttttber I A 00473 III. Ith'QU ) ANI) OI'I'IONAI. ANAIsYSh'S Anti ses Resull.s Q Outfall Snmplinv Rt.'sults ilecute Snntpling Point on I.ine Drawing required by Question A.IO) gotfIINn,b. 071, Cooling Tower Blowdown Q Intake Sampling Results- Optional ISpecify Source Q Upstream Background Sun>pie Results- Optional,Specify Location of Sample Q Treutment I ncility lnAucnt Sat ttpling Results (I+cate Sampling Point on I ine Drawing required by Question h.l 0 Q New l)ischurge IDcscriba benin for information presonted, see instructions Ior Section C, Part li Accept.

.S. Ifyoubsvs say roscoa Io aspect uts puuutsnl lube

3. Invel Present 4. Units 6. auratsuy present ln Ihla discharge, check Ihe sppruprlste

~ bls I. 2. Cuemclent Polltitullt lletac. l)etectlua bPA ~ . Msa Dally Value b. Average of Analyses c of blucb ur describe anulher restun.

Ilun 4svst htetbod Group 2 I arel Used ftuwber Coacen.

Nu >aber Ffnuenl Inter.

Coacs4. of Cuacea Mess Vsrbtblnty )tow Ms>tv tsedl ~ te By Intebe Other (contlnuctl) (iltn) Iitgn) Used tfslls4 Move >causa Maes Aaalyal ~ trauoa ICVI Material (ectured Stured Pruduct Product Water Ib;c pl sin>

16M Phenols,'I'otul 420.2 42.0 0.84 20.6 0.61 ug/1 1 bs/

Aluminum, 16M Total 100 40 200.7 2400 48.0 1280 39.7 17hf Barium, Total 100 0.3 200.7 79 3.96 75 2.98 ISA Boron, Total ~ 100 10 200.7 51 1.02 @21 19hl Cobalt, Total 60 200.7 0.06 c2 20M Iron,'I'utnl 30 200.7 98.0 4900 3000 99.6 21 M Iron, Dissolved 3O 200.7 410 19.8 360 14.0 Mugtlesluttl, 22M Total 30 20 200.7 1620 811. 5 1407 557. 4 hlulylnlcnutn, 23hl 'I'ulul 100 200.7 0.12 s5 z. 0.20 Manganese, 24M 10 0.3 200.7 250 5.00 189 6.88 Tt>tnl 26M 'I'itI,'I'ulu I 600 282.1 26 0.52 26 hi Titnniunt,'I'utul 40() 200 '83.1 4-200 al0 d'. 200 c,7.89

3. Ifother dutu is availnblo li e. DhiR data, etc ), the past year of tints may bc used to determine 3a,3b,3c, and 6.

3 a Muximum Doily Value- Report the ~hi ~hest daily value or daily average value I'rom the last yenrofdulu. Report both mass and concentration.

Average of Anulyses- Deter>nine the average of all sumples taken within the psst year. Rcport both mass and concentration.

'.b 3 c ' minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for ull other discharges, treatment fucility iniluent, intake wuterund background.

blake copies of this table and check appropriate bux.

It is in Iht; applicant's interest to achieve n level of detection ut lenht equal to Ior preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for ud Jitional analyses ur the putentir i fur estul>lishing n Inrgt> nun>I>or of eilluent limits nnd/or monitoring requirements in the linal NPDES permit.

w ~ ~ ~ ~ os ~ see use>l Sk:C'I'ION C (ccnlinllctl) NI'I)k.b Nttnll)cr I'h d(.47325 III. Itl:(}Ulill:I) ANl) OI'I'IONAI. ANAI.YSI"S hnttl scs Itcstllts Q ()utfull So>npling Ilcsults ll~cote Sun>pling Point on l,ine Drawing required by Question A.l 0)

DII Outfult Number 07 1 COOl in TOWer 8 1 OWdOWn Q Intuku Sampling Iiesults- Optional lSpecify Source Q Upstrcutn Buckgruund Sumple IIesttlts-Optional (Specify )~cation ol'Sample Q 'I'rcutment Eacility Inlluent Sampling llesults LlJ>cate Sampling Point on Line Drawing required by Question A.l0 Q New Dischurge lnescribo basis for information presented,seo Instructions Ior Section C, Port II Accvpt 5.

Ilyoubavo any roaaun to ovpoct tbs pouutant tubs

3. Is>vsl Present 4. Un>Is n>>rn>asy present In this discharge, choc'h ths appruprl ~ tu abl ~ I. 2. Coemcleat btuch ur descrtbs eau>bur rseeoa.

IbQIIL!ttt51 I, I>eruc- I>elec>lun RPA c, uf I~vol btetbud a Has t>asy Value Ia Average sf Ana>yses RIRusnt Inter.

GrQtlp 3 t>us Iev<<l Used Itu>aber Cancan. Cancan.

Ruse her Cancan. bless Varlsblaty Raw Manu. ~ eedl ~ te Uy. In>sbe O>her Vutsta>> Or Ssntcs Ipg/I) lpgh) Used tea>tun Mess trauen Mess Analysis trsUun >CV> btaterl ~ > ectured Pruduct I'>uducl Water nds plein>

IV Acruloin 10 10 603 C ~ U9 2V Acrylunilrille ln 5 <<c ~

3V I)enxcne lo 5 624 '~

n. Ug 5V Bran>ufurnt lo 5 C ~ U9 Carbon ov Tolruchlnride 10 5 624 c5 ~0.25 ~5 <<0.20 3 ug/1 c0.

lb'IV Chiort>bcnxetto lo 5 624 Chlnrndil>rumo.

ntcthunu lo 624 c0.25 ~5 <<0.20 3 ug/1 lb'g 9V Chlorocthune lo 10 624 c10 C ~ ~ 3g 2 Chion>ethy )vinyl Ether 10 624 <10 c0.50 <10 <<0.3B 3 ug/1 I I V Cidorolurm lo 5 624 c5 lb'g/1 Dtchlorubron>u.

methane Io 5 624 c5 ~

c0.25 c5 <<0.20 1bs/

14V I,I-Dichloruetlmne lo 5 624 r5 Ug .

15V 1,2.Dichloroellmne Io 5 624 c;5 c0.25 c5 U9 15V I I D>chloro eth lens lo ~0 25 c5 c0.20 3 ug/1 1 bi' 1,2 Dichluro.

IgV I'0 >t t>e lo 5 624 <0. 25 c5 c0.20 ug/1 1bS/

1,3. Dichlo ru.

ru leno 10 5 624 %0.25 c5 c0.20 3 ug/1 1bg 19V Etl> Ibnuene lo 5 624 Ug

3. II other data is uvuiluble li e. DMIIdata,etc 1, Lhe psst yeurofdutu may he used to determine 3a,3b,3c, on>I 5.

3.u Mashntnn Duily Vuluc Ileport the I~>i l>estdaily value urdaily average value I'rom the lust your ufdsta. Rcportbolh n>use und concentrution.

~

3 b Average ul'Analyses - l)etern>ine Lhe average of all samples taken within Ll>u pusl year. IIeport both ntsss und concentration.

3 c A n>ini>nun> uf three.l;>n>piinb> Events required for process wustews ter discharges, und u >ninin>unt ot'une Su>npling EvenL for uli uther discharges, treatn>ent fuciiity inn ',><,

intuko water und background.

hlake copies of this tuble uml chrck uppropriuto box.

It is in tl>su pplicunt's interest Lo achieve u level of detection ut leusl equal to lor preferably >nore sensitive thun) lhose listed. This willmh>h>tice uncertainty und lherefore Lhe neer> " r udditiu >ulyscsor Lite pntentiul for establishing a large number of eAlt>cut limits un>Vor oring requiretne>>ls in Lhe Iinsl NPDES permit.

SI'.O'I'ION ('~ntintletl) Nl'l)l':S Nt)mbcr I'A 00473 III. IIIi:QUI~)ANI) Ol'I'IONAI. ANAIsYSES o Q Oulfu) I Su>>ipli>>g Ruutilts Ilaicittu Su>>iplii>>igI'ui>>t o>> I.iiiu l)ruwi>>g reit It(red by (luostiu>> A.I 0)

Q Out(>>I)Num)ter 071 COOl in 1OWer Bl OWdOWn Q I>>luke Sunipling Results Optioiiul (Specify Source

~

Q Upstreum l)uckground Sumplo Results. Optional (Specify i+cat(on of Sample Q Treatment I ucility l>>Ruent Sampling Resulls l I+cute Sanipling Point on Line Drawing required by Question A.IO Q New Discharge(Describe basis fur inlormation presented, see Instructions fur Section C, Part ll S. It you base sny reason lu aspect the potluisat tubs Pollutunt Accept

~ hie 1. 2.

3. I.svol Present , 4. Iinlts 5. nurssaily present to this dticbarxe. check tho appropriate CosNcleat Grottp 3 I)eioc- Deiscitoa MPA

s. Mss I)ally Value L AveraaeolAaalysos c ur blwh or describe another seasua.

VelsWe Osxsnlcs Uuo lAvol Method Ituabor Eltiueat Idler I~vol oo Used Itu tabor Csdcsd Coacen. ol Concea blare Vastabulty Ilaw Manu. atsdlste i'-:niobe Other icunlbiuedi (itgil) (pg/I) Used tts Meso Mess Usa tssUon Analyst ~ tsadoa iCVI Mslstlsl Ieclufod Stored Product I'ruduct Water igspletni 20V Methyl Bromide 10 10 624 (0.5 Ug 21V Methyl Chloritlo IO 624 <0.50 < Ug 22V hlethylene 10

( Ill el'tile 6 4 40.25 ~5 ~0.20 3 ug/1 1bs/

23V 1,1,2,2 Tetru. 10 chluroetliunu 24V Tet ruchluro. 10 etllylline 25V Toluene 10 2GV 1,2-Truns Di ~

IO chloroethyleno 27 V I, I, I-'I'richluro 10 i ethunu 28V 1,1,2 Trichluru. 10 ethane 'O 29V Tr ichluru.

etliylclle 31V Viiiyl('.Iiloride 10 624 ~ 10 ~ 0.5 ~ 10 <0.

3. Ifutherdutu is uvuiluble li e. DMR dutu, etc ), thu pust year ofdutu muy be used to deten>>ine 3u,3b,3c, und 6.

3 il Maxi>>lilt>> l)uily Vul>>e

• Report the h~i)tesltduily vulue or daily uvoruge vuluo fiem the lust your ofdutu. Report both>>iuss <<ml cuncentrution.

3 b Averugu ul'A>>ulyses- l)alert>>i>>e )lie uveruge ofull aui>>plus tuku>> witlii>>tlie pust your. Report botli >>iuss unil concentrution.

3.c h>>iinii>>um of three Su>>ipling Events ri.quired fiir process wustewuter dischurges, und a t>>ini>>iui>> of one Sampling Event for all other discharges, )realms>>t fucility inn>>mt, i>>tuke wu ter und buck gruund.

Moke copies oflliisluble und clieck upprupriute biix.

It is i>> )lie upplicunt's interest hi achieve u lovel ofiletection ut leust rqnul to lor prefi ruoly niore sensitive thun) tl>>ise listed. Tliis will >>iiniinise uncertuinty und tlierefiire lhe neetl for udditio>>uluiiulysesur the potential fur rstublishi>>g u lurge nu>>iberofellluent limits and/or nio>>itoring requirements in the line) NPI)ES permit.

SI:O'I'ION C (continue<I) N I'l)IPS Nutnbcr I'A III. RI':QUIRI"D AN I) Ol"I'IONAI.ANAI.YSI"S e Q Outfall Su<npling Results llh<cute Su<nplintg I'oint utl I.ine I)ra wing re<p<ired by (lucstion A.IO)

Q oulfullNuntl 071, Cooling Tower Blowdown Q Intake Sentpling Results. Optional (Specify Source Q Upstreum iluckground Sample Results-Optiunul (Specify id<cation of Sample Q Truuuncnt I'ucility I<<Aunt<( Sampling Iles<<Its (Is<cato Sampling I'oint on Lino Drawing re< p<ired by (location A.I 0 Q New l)ischurge Il)cscribe basis for information presented, sco instructions for Section (', I'urt II S. IIyou have say reason tuespect Uso poUutant tube I oilutttttL hccep<

sbt. I. 2.

3 Invel Prevent 4, tint<a 5. aurastty prssoat In <his discharge, choch tho oppruprlsto C Illa<en< btoch or doscrtbe eau<her reason.

Group 4 I)e<ec. Its<oct<us b'Ph

s. Has Oauy Valve ls. hvar ace ur hnatyoeo c, or Acid Fraction <lan tave< Method <<umber brnuont tater.

level <Ised r<uaber Concea. Conc os. ut Concoa Hss ~ Vsrlsbul<y Ilaw Meau. <nedlste By. Iatoho Other Orgunics (Itgi)) (Itg/I) ttsed trsuoa Mes ~ trsttua Mess h a sty sl ~ Iso<Isa <CV< Ms<or<st <ectured Stured Pruduct I'ruduc< Water <Bsplsla<

IA 2.('.hlorophc<tol 10 10 -

625 c-'6 < 0.30 c 5.34 Ug 2,4.I)ichiuru.

2h 10

<< 0.30 c'5.34 c 0.21 phenol 10 625 2,4 Di<nethyl-pl<ct'IUI 10 10 625 <<6 c 0.30 c 5.34 <<0.21 4,6 Di<ttt<'u u.

4A Crcsul 10 10 625 <<'30 ~1.5 <<'26.6 <<.1.07 2,4 Dinitru.

SA 50 phenol 30 625 <<30 c1.5 c26.7 <<1.07 OA 2-Nitruphunul IO 625 c 0.3 c5.34 ~0.21 7h 4.Nitrophcnol 50 30 625 c30 <<1.5 c,26.7 c1.07 P.Chloru m.

Bh (lrosol 10 625 c6 <<0.3 ( 5.34 c 0.21 Ponluchioro.

9h phenol 50 30 625 <30 . c 1.5 (26.6 <1.07 I OA I'henul 10 625 c6 <<.0.3 c,5.34 c0.21 I lb 2,4,6.Trlci<loro-pll<<'ol 10 6 625 c6 < 0.3 c5.34 <0,21

3. Ifuthcr datu is avuiiublc li.e. Ohkk date,ctc.l, thu pest year ofdutumuy be used to determine 3u,3b,3c, und 5.

3 a Maxintu<n Daily Value- Report the ~hI >hest daily value or duily average value from the last year of data. Report both ntuss and concentration.

3 b Average of Analyses - l)ctcrmine the average uf all samples taken within tho past year. Rcpurt both mass und concentration.

3.c A minhnum of three Sentpling Events required I'or process wustcwutcr discharges, and a minintum ofone San<pling Event for all other discharges, treatment facility inAucnt, intuke water and background.

h(uke copies of Lhis tubte und check appropriate bus.

lt is in Lhe app'licant's i <)crest to achieve u level uf detection at least equal to lor preferably moro sensitive than) those listed. 'I'his willt<tinimlxo uncertainty und thcrcl'ore the need For uddittunul unulysesor tits potcntiul fur cstublishing u lprgu nun<bcrof cinucttt limits und/ur nuntltoring requiren<ents in the linul NPI)ES porn<it.

SKO'I'ION t. (Contintletl) NP f)Li'S Nu)nber I'A VV%7325 III. III"QU ) ANI) Ol"I'IONAI. ANAIsYSI"S '.

Ano s flegulto Q Dotfull Suwipliwg Results llAicste Sawipling I'oi>>ton I.inc 1)ruwiwg required by Question A.1ol Q Dwtft(llNuinhor 071, Cool ing Tower Bl owdown Q Intake Sumpiing Results Optional (Specify Source

~

Q Upslreuni Background Sample Results- Optional(Specify Location of Sample Q Treat t went Puciiity Inllucnt Sampling Itcsults t locate Sanipling Point on I ine Druwing required by Question A.io Q New l)iscliurge t l)escribe busis fiiri>>for(nit tie(I presented, see Instructions fiirSection C, Perl II I'olio tan t llyuu have aay roe sun iu a!poet the puuuiani iu bs Accept ~

3. I.svsi Present 4. Unite 5. nor many present ln ibis discharge, cbscii ibs spprupi late (lrottP 6 ~ bi ~ l. 2. I'uoNclsnt bloc'h or describe situ(her reaiua.

iiolor. tiotocttsn UPA a Iias tinily Vaille b. Avsrezsut Analyses C. ur lluso Nowlrul tlun . Iuvot Method Number Uttiusni Inter.

I"rucliww Imvol Ihed Number Cancan. Co((colt ul Cuncen = Mllie Varlabtiliy llaw inodlsio Uy latshe Other Orgun'ics I lig/I) Iitgn) liood tra don Mass (ra(lit(i Mass Analyil~ (callas ICVI (ectured Stored Manu'aterial I'ruduct Produc( Water tgaptalni 18 Acenuphtheno 10 6 625 ~0.30 ~5.34 a 0.21 3 ug 1 lbs /

28 Acenuphthyiewe 10 6 <0.30 < 5.34 ~ 0.21 3 ug/l lbs /

38 Anllirucewe 10 6 c0.3 c- 5,34 ~ 0.21 48 Beitzidiile so 30 ~30 ~1.50 ~26.7 ~1.07 58 Bonzo inl AULhr i(et'.nt'8 Io 6 z 0.30 c 5.34 ~ 0.21 Benzo lnl I'yrene 10 3,4 Bciizo.

78 0 III)riitillit:Ile Benzo ighil I'erylewo Bellzo 1 k)

Plworuwthene Io Bis l2 Chlor(i ~

IOB 10 clhozyi hietlmne Bis l2.Chio( o.

118 10 cthy0 Ether Bis (2-Chloro-10 iaoprupyl) Ether Bisl2 Fihyl-138 hcxyB I'hthuiato 10 23 0.46 11.6 0.35 ELIII:I'O 148 4'Brlllwoplleiiyl I'IIew I 10 c 0.30 ~'5.34 Z0.21

3. Ifother dalu is uvuilaole ii e. DMR dutu, etc ), tlie pust year oi'datu iwsy be used to determine 3u,3b,3c, and 5.

3 u hlusiiwuwi l)uily Value. Report tlie h~l(hest duily vuiue or duily uveruge value from the lust your oi'dutu. Report both twuss uiwl concentration.

3 b Averugeof Analyses Dclcnnine ilia uverugeofuusewiplestukow witliiiithe pustyear. Reportbothmussundconcentration.

~

3.c - A iwiwiiwwwiol'Lhree Sampling Events required for process wwslowulcr discharges, uwd u minimum ofone Suwipiiwg EvuwL fur ull other discliarges, treutmeiit facility innwent, i>>hike water umi buckgrouiwl.

I Muke copies oflliistable unit clieck uppropriuie Iuiz.

It is iii Lhe upplicunt's iiilerest Lo achieve u level ofiletccliun ut lu(tst cipwil lulur prefi ruhly iwoio sciisilivu tliuiiltlwisu listed. 'I'Itis will wiiiiiniizowiicortuiiilyuiwl lliorofiiio till,'(ceil fiir oddilioiiul uiiulyscs or ilia potential f(tr estublishi<<g u large wow(bar <<I'clllwcwtlimits uwihir wwwiitori>>g reqmriniewls in the fiwul NPI)ES permit.

.ll~;( I'1() N (l (<<f>fttifttl<<fl) NI'l)I"8N I>Ital><<r I'A III. III':QUII(I':I)ANI) Ol'I'IONAL-ANAI.YSIi:S' Du(full Sampling Results lid>cute Sumpli>>gl'oint on I.ine l)ruwing required by (Ines(ion A.IO) 071, Cool ing l ower Blowdown Q Intake Sumpling llesults - Optionul (Specify Suurce )

Q Upstreum Buckground Su>>>pie Results-Optioaaul(Specify IA>cutioaa ol'Sample )

Q Treat>>tent Facility lnAuent Sampling Results(I+cate Sampling Point onLine Drawing requiredby Question A.IO )

Q New Discharge (Describe basis for information presented, see Instructions for Section C, Part II )

4. Ifyoubavo any rosvun aoorpa I ahu.ruuufana au ho Aesop> ~ 3. Iuvsf I covuaa 4. L>al>s 5. aura any prorsna In abls dirc> srdo. ch.sh ahs appruprlaao Poilu()(It t ab ~ I. 2."

Cosf ftc I ca I bauch or Jose> lbu aauahw rsssun.

t>uauc. I>saocalun UPA of (at 0(IP 5 ~. Marl>suy Vs>us b. Avsrasouf Aaaayrss alon IAvuf Mu>hud fausbw hfnusna Incur.

1)uso.Ncu(rul Iuvsl U aud fan%bur Cuacsa. Cuncua. of Cuacua. Mass Var>abls>y Roar Msnu- >audio>a Uy Inf~ hu O>bur Fructiun ()rgunlcs lpg/I) (pgn) Ussd ars>fun Ms jr ars>foa Mars Aaafysl>> ara>fon >CVI hlsasrls> facaurud 'lured Prado ca I'rudaaca Ws>sr agrpfsfn>

ISB linty l Bc>>syl c 0.30 w5.34 I'htl>slate 25 c6 0.21 3 ug/l 1bs/

1611 2-(!htoronuphthulcaae 10 4 Chlora>phe>ayi 17B IO I'henyl Ether 18B Chrysene IO Dibena> Iu,hl 19B 10 Aa>thrucene 20B 1,2 Die)>la>ra>be>ae>ae 10 2IB 1,3.niclalorobense>ae )3

?2B 1,4 Dichlurobe>>cene 13 3.3'-Dichluro- co 23B benxl>II>>a:

12 cQ.6Q ~ 10.7 c0.43 248 Diethyl phtholute 20 c6 c0.30 ~ 5.34 c, 0.21 25B Dimethyl I'htln>lute 20 Di-N Butyl 26B I la(la>>'a>to 20

?'I B 2,4 Dinitrutuluene 10 28B 2,6 Dinitrotuluene 10 29B Di-N Octyl Phthalute '>0

),2 Diphc>ayllayalru.

300 zine(os heobcneenrl 10

3. Ifothcrdutu is available li e. Dhllt dots,etc.l,the past year el'data may be used todeteranine 3u,3b,3c,and 5.

3 u htaaxinauna Daily Value- RcporL tlao I~a) ahest daily value or aluily average vulue from the lust year of>lute. Report butla nauss und concentration, 3 b Average ol Anulyses- I:a ter>nine the uveruga> ufull sumples tuka n wilhin tha: pest year. Report both n>uss und cuncentrution.

3.c A mininaumof three Sumpling Events required for process wustewuter dischurges, and u mininaum ofone Sampling Event for all other disclmrges, treatment fucilityinnuent, intuke wuter und buckgruuaad.

Muke cupies el'this tublu and check upprupriutu bus.

It is in tl>supplicant's haterest to uchieve u level of de(<<ctiunut leust equal tu(ur prcicrubly a>au~nuit(ve thun) those listed. 'I'his willa>ainimize uncertuinty und therefore the ne udalitian ulyses or the potcntiul for estublishing u large number ofeilluent limits and/or f>~rif>grequire>nents in the linul NPI)ES permih

>i>. I!SOU>>t '11 ANI) OPT>ONAI. ANALYSES r

3. An>t llcsulls Q Oul Sun>pling R<<salts LIA!cato Sai>lpli>>g I'oint on I.i>to l)ruwing required by Questit! I> A. I 0)

QO Lr IIN,U,I,U, 0?1, COOling TOWer BlOWdOWn Q Intuke Sun>pling Results Optional ISpecil'y Source

~

Q Upstrea>n Background Sample Results Optional (Specify Iacstiun of San>pie

~

Q 'freutment Facility lnnuent Sampling Results tlacate Sampling Point on I.ine Drawing required by Question A.IO Q New Discharge! Describe basis Ior information presentrd, see Instructions fur Section C, Part II S. Ifyuu hsva sny reason tu aspect tho pouu teat tu be I'ollutttnt Accep ~

a. Love> Present 4. llnlts '6. norm say present la this dl >charac, check the appruprlste Group 5 ~ b>e I. 2. C wc>en> bluch or describe snuthor resvun.

I le>ac. I)eIectlun EPA l)ssy Value c of Hase.Neutral o. Msc b. Average of A no>yves tlun lmvel Method Number Efnuent Inter.

Fraction I oval lhed Number Coucon. Concen. of Col>ceo Mats VarlsbUI>y Ilaw Manu. >sadists Uy la>ebs Otlter Orgunics ()>g/I! ll>g/I) lloed >rstlun Mate Its>loll ~ 'I st ~ Aaslyele > ra tlua ICVI Ma>orle> factored Stured Pruduct I'ruduct Water IE>plein>

318 Fluorunthene 10 6 6 a0.30 ~5.34 r Oe21 3 ug/1 lbs 328 Fluorene 10 Ilexochloro.

338 benzene I lexuchh>ro.

a48 butt>Ill>.'Ile 10 1lexechlart> ~

358 10 cycl ape>lit>tlicno I lexuchluro.

368 elhane 10 Indcno I/gg.ctll 378 I'yl'one 10 388 Isophorone 10 a98 Napluhuleno 10 408 Ntlrobcnxt!ne , IO N-Nilrosodi ~

418 20 melhylumino N-Nitrosutli.N-428 I'ropylamine 20 N-Nitrosodi.

4aH 20 phenylatnine 448 Phenanthrene IO 458 Pyrene IO 1,2,4-Trichloru.

468 bcnxene IO

3. Ifulherdutaisuvailobleli e.DMRduta,etc),thopustyeerofduta n>uybeused todetermine3u,3b,3c,und6.

3a hluximutnl)oily Value-Report though) hesldsilyvulueorduilyaveragevaluefrowlhelustyourufdutu. Ileportbothmusssndconcentration.

3 I> Averugeof A>tulyses- l)etermine the sverageofallsamples tailen within the pustyear. Reportbothmsssamlconcenlrution.

3 c. A mini>nun> uf three Su>apling Events required for process wustewutor discharges, und a mini>num ofone Su>npling Yvunt fur ull uther dischurges, Lreutment fucility innuent, inluke water un>i background.

htake copies uf this table >nnl check uppropriute box.

It is in the upplicunt's interest to achieve u level uf d<<lection ul I<<usl I.'quul to tor pre)'erubly more sensitive thun) lhoso listed. This will n>inimixe u>>certainly und therefore the t>eed Iur uddilionul unalyses or the pot<<nlial ior eslublishi>>g u large nun>ber of sill aent limits and/or monitoring requirements in the Iina1 Nl'DES pern>it.

~~ t aaaa,aar aaua,a>a J a SEC'I'ION C (continued) NI'l)ES Number I'A 111. REQUIIIHI) ANI) Ol'I'IONALANAIsYSES Anni ses ltesults N/A Q Outfall Sumpling Beau)tati~cata San>pliny Point un I jne Dfawing required by Question A.IO) iIg Outfall Number 07l C001 ing I Duel B I OWaOWn Q Iotuka Sunq>liog Rcsulls - Options)(Specil'y Saurce )

Q Upstreuo> Buckground Sample Results -Optional {Specify location ofSample )

Q Treatment Facility lnAueot Ssmpling Results tlacate Sampling Point on I.ine Drawing required by Question A.IO )

Q New Dischurge I Describe basis for informution presented, sea Instructians I'or Sectian C, Part ll )

hccept. 6. S. Ir you have any r<<soon lu ovpocl tho pouutant lo bo

2. 3, Iuv<<t I'r<<sent 4, Unit<< nuransuy pres<<nt In thb discharge, check the sppruprlsto

oil u tant ~ bio Uetoc.

1.

I>etectlun SPh Coefflclesl ol blucla ur describe another roc>un.

tlun Invel M<<thud ~ . hiss Ossy Value b. hvorszoolhnslyoos In>cr-Group 6 Invel Uaed Nuasb<<r Cancan Concen Nu >aber ol Concon ~ Mass SII>uont Varlsbalty Ilaw M snu. au<<dist<< By In>ebs Other Peslicidcs {ttgn) lug/I) Usaaal tr atlun lrstlun Mass hns>yale tr stion >CV> Mate>Is> Ssc>ured Slur<<a Pc<<due> Product %st<<C >sap>sin>

IP Ahlrin 10 2P Alpha 0l IC ID 3P Bats Bl IC 10 4P Go>no>u BI IC IO

'P Oeltu Bl IC IO OP Chlordane 10 71',4'Dl)T ~ 10 8P 4,4'-ODE 10 9P 4,4'-DDO IO IOP l)ialtlrin 10 Alpha-IIP Emlasulfan 10 12P Balu.Endasulfun 10 Entlosulfun 13r Sull'uta IO 14P Endrin 10 Endrin 15P IO Ahlel> Ja 16P 1 1aptachlor 10 I leptuchlur 10 E >oxide 251'I'axaphane IO I)IOXIN: 2,3, 7,8.Tetruchiuro.

dibaozo P l)ioxio

3. Ifuthar data is uvailubla li a. DMR data,atc ), tha past year ofdatu muy be used to determine 3u,3b,3c, und 5.

3 a hlaximum l)oily Vultte - Report the ~hi hast duily value or daily'veruga vulou fram the last your ofdutu. Report both mass and concentration.

3 b Average of Analyses Determine the average ofull samples taken within tha past year. Report bath otuss and concentration.

3.c A minin>u>o of three Sutopling Events required fur process wustawatar discharges, ands mioimumufone Sampling Event for all other discharges,treato>cnt facility inBuent, intake wutar und buckgrouml.

hluke co ties of this table and check appropriate bax.

lt is i> pplicant's interest to achieve u level ofdatecti>>n at least equal to lor preferably > ansitivc thun) those listed. This will minimize uncertainty und therefore tl>e n r otlditi oslyscs ur the patcntiul for t stub lishing u large ntoobor af allluaot lio>ils ut>ti/or~iturh>g rctluircmat>ts in tha lioal Nl'l)ES permit.

coo tiuuetl) NI'l)LPS Number I'A 0047325 III IIEQUI ANI) Ol'l'IONAI. ANAIeYSLS o

3. Am) Rest)Its Q OutFall sumpling Rss>>its ti~cuto Sui>>pliiq; I'oint on I.ins Druwing rcq>>ired by (l>>estion A.IO)

L)g Oulfull N>>>>ilier 071 COOl in TOWer 81OWdOWn Q IlitukoSlllllpllllgI'lttsillts. Optiullllltspecipy Source Q Upstream lluckgruu>>d Sompls Results - Optioiisl Specify i~cat)tin of Sample L

Q Trout mont Pucility l>>0 tie>>t Sui>>pli>>g Hua>>Its I I atcuto Snnipli>>g I'niiito>> I i>>u Druwi>>g roil>>irod by (IIisation A.l0 Q Now Discburgu lnuscribo bonis fur i>>fur'>>intiu>> prosuntod, seo l>>str>>etio>>s fur Section C, Part II tr you have sny reason lo oepocl the pouul ant io bo Accept.: 3. )uvet Prevent 4. Untie 5. nurasuy protest Ln iht ~ dtvchergo, check iho appropriate ohl ~ ~ I. 2 Coethclent btoch ur doeulbo anuther reseun.

I'oil u tttn t t)etec. Uelechun UPA s. M.a Dotty Value b. Average ol Analyses c. or tave) M ethud )uter.

Group 7 Uea Used Huaber Cunces Cuncon.

Nu tabor ut Conceit. Mate Rthu eat Varlablttiy Ilaw Maau. aedlele Uy Intake Outer I'CII'6 trovato'Pg/I) litg/I) liood iratien Met ~ trallun Mace An eiye la traUon iCV) Mater)et /ectured Siured Product Product Water igcpialni PCII l 242 20 0.1 608 <Oel <<0.005 <Oel ~0.004 3 ug/1 1 bs/

l9P PCO l254 20 0.2 608 ~0.2 c 0.01 <<0.02 c'0. 008 . 3 ug/1 1bs/

20P PCII. I 22l 20 0.1 608 c0e1 << 0.005 0.1 <<0.004 3 ug/1 1 bs/

2I P PCII l232 20 0.1 608 +Oui <<0.005 <<0e1 (0.004 ug/1 1bs/

22P I'CII.)248 20 0.1 608 c0e1 <<0.005 <0.1 <<0.004 3 ug/1 1bs/

23P I CII-I260 20 0.2 608 c0.2 <<0.01 <0.2 <<0.008 3 u/1 1bs/

24P PC II.I 016 20 0.1 608 c0.1 <<.0.005 <0.1 <<.0.004 3 ug/1 1bs/

3. Ifutherdutu is available li e. DMR data, etc l, tits psst year ufdutu i>>uy bs used to determine 3u,3b,3c, a>>d 5.

3 a Maxim>>in Daily Value ~ RepurLtl>>i I~tl Ihestdsily vulueor daily average value from the lsstyear ofdstu. Rsportbuth tnsss and concentratiun.

3 b Averugs of Analyses Detsrmi>>e Lhe uvsrags of all samples Luke>> within ths psst year. Report both niuss und concenlrutlo>>.

~

3 c A>>iiniinu>>iof three Su npling Events required for process wastewater dischur gas, und a minim>>)>> of one Sumpiing Event fur all uther discharges, treatment fucility i>>i!ue>>L, intuks waters>>dbsci:g:uuwl.

Muko copies uf this table and check appropriate bus. I It is in lhe applicant's interest to achieve a level of detection at least cqus I to lor preferably>>iors sensitive than) those listed. This willminimize uncertainty si>>l thsrsl'ors the need for addi tiunul u>>olyses or tits potential for establishing a Isrgs n>>>>ibsr of eln>>ent liinits anti/ur monitoring requirements in ths fina I Nl'I)ES pert>>it.

cII.(!'I'I()N (l (Ci>I>l i><<ti:il) NI'I)I':S N <<)>>I)i:i' 'A III. III:()VIIII"I) ANI) Ol'I'IONAI. ANAI.YSI"S '.

A!a~!I  !!:a ))n,<<)La Q t)>>trai)Si>>i)li >lit) i lt II r I)S > pli g)'>>I ))i< )I) i I <<l)i e)I ytl )c li >A.IO) gl()otr l)N>>,),e, 071, Cooling Tower Blowdown

[ I l>>tuko Sn>wpli>>g I:us>>Its I)ptioiwi)ISpecify Sa>>>>

~ ce Q t)psl)'cuo) IIUckgf >>ioa) Suo)pie Iles>>lts upi>a>>)UI ISpcc)ly Il<CUI)i>>)<ifSa>>)pie Q I'rout>>> vnt I'ucilily l>>n >>cot Su>>>pling Itesnil s I Id)oui o Su>>ipii>>g I'ui>>t o>> l.inc Drawing requ fred by (luestiun A. I 0 Q New I)ischi) rgo Il)<<scribe busis Ii)r inli>ro>ution prcseiilca), sec Iiist) oclin>>s Ii>r Section C, Port II

d. IIyuu b ave sny csseun iu scpeci ibe pu)>ui an> )u Le Accepi J. I eve> I'ye<en> 4 I>a<i< ~ 5. nua asuy pceaeni In ibl~ dlacbscge, cbec>a i>ae sppraa>ae I. !J I~>I>cia<a) blwb w deaccILe snunaec cesaun.

I'oil u t It<< I, l)e)a c- I)eiec)>un Vl'A

s. tdsa l)euy Value L. Average st Ass>yves c ut

) lan lave>  %)e>>aud Nuas bur b>nues) Iaaiev (cl oui) B )eve) ee I) aed Naasaber Cancan Cuncen ad Cuncen. l>see Vsr>ebony Osav S>eaau. ased>ele I)y >alas)ae <)a)aer Ituilioucllvily (pg/I) ()>ga/I) >teed >ra)lun Ideas uansn ~ Isae Ana>ya> ~ wsdun <CV> )als)erie) <sc)aced S<!a<ed Iquduci I'ruduci Water awcp>sLO Itoahouit)v)ly: Note 1 C2.0 N/A <1 e 67 N/A 3 pCi/ N/A I I I Alp)>><, Not

'I'otal Avui).

ubtc I')> Ilute,

'I'o>ul Note 1 17 N/A 14 N/A 3 pCi/ N/A J)t I!II It)id>i>>o

'I'olul

~

Note 1 d 3 N/A c 2.17 N/A 3 pCi/ H/A I

4)t l4 I ItU<liwo) 2') Ii, 'I'utu I Note 1 0.63 N/A 0.35 N/A 3 pCi/ H/A

'I Ifother dotu is uvuilublv li e. I)h)it dulu, elc ). I)ie pust yeur ofalaln muy bo>>scd Io de>arm))ie ah),34, Oc, i)i)a) 5.

I u hlai) iw)>>i>> l)oily Vuh)c ~ Ituport thvhighest i)wily vulueor aluily uvciuge vuiuo fiuio tlic lust yeurofdulu. Ikport but)i oiuss ui)d co>icc>>trutimi.

I,h Ava rugool'Aiwityscs- I)vtermi>>e ilia uverugeofu))su>>>li)a s luka>> wilhio lhe pust your. )Ieport both >>)ass u>wl concenlrutiuo.

I a A wiioii>>>>i>> uf three Saio)iling Evvots req>>irei) I'ur process waslcwatvr discharges, urn) u ioioiinu>>> ofune Suiopli>>g hive>>t I)or uii olhvr iiiscliurges, treatment fucility inl)u<<ot, ii)>uku WUIcr wi')>))<l.

hluk i copies of lliis I>>hie>> na) a:Iivck up prop riu to I>>is.

II is i>> the upplico>>t's interest lo uclii<<vo a level ufile)eclio>> ul 4 oat qiiul lo lor pref< rubly ow)re sensitive lhuol l)o)sc listoil. 'fliis will >>)ioio)ixe uncertuinty uoil liierefi>rc tiio iiecii liir ualaiilionul n>>uiysvs ur liie put votiu) fiircsta4)ishh)g u largv >>wiobvr of clnuvot lio>its uod/or ow>>iitoring rcqo>re>o<ts in the linu)NI'l)ES permit.

Note 1- Procedures used are from Teledyne Isotopes.

SRC,'I'ION ('cot)i,tttttotl) Nl>I)l".S Numl)ot I>A 004732 III. III':QVI ) AND Ol'I'IONAI. ANAI>YSRS

>.oloo ou Q Out t'ull Ss>npling Itesuitz P oocule Senti>lh>g I'chit ou li>>o l)ra wins reunire>U>v tluestion AQUI Q Intuke Sampling Ilesults -Optional {Specify Source Q Upstream lluckgoround Sample liosults - ()ptionul ISpecify loocution of Sample Q Treut>nl nt Yucltity lnlluent San>pling Ilesults tll>cate Sonlpling I'oint on I lne Drawing required by tluastion A.IO Q Naw Discharge I l)cscril>o basis for intern>ation presented, seo Instructions I'or Section C, Part II

2. I.RVEI. I'I(RSI<:NT 3, UNITS 4.

I. I'0 I.I.U'I'AN'I' h. hluxinlum 00!)uy Vuluo c. I.ong'I'am> Avgu. Value d.

Coaft)clout I(OUI' u. h)uxlnlum l)uily Vulue (it uvullable) (ifuvulluhle) u b. uf ENuent No. of V uriul >I I It y Anulysas Concentration h1uss I II Cunc en> re Ilun Ir>Hs>5 I I I Cooncenlrs>4>n I'l Mars I II Cuncenlrsllun lrl M 5 re (CV)

IC II>achcnncs)Orygan Dannlnd, IIOI) 2C Cl>co>ical Orygon Delnund, C() I) 24.0 3.00 mg/1 1bs/d ac 'I'otal Orgu>>ic Curbon,

'I'OC 3 0.38 mg/1 1bs/d 4C 'I'ate l Suspe>sled Solid 4

'I SS 5.2 0065 mg/1 1 bs/d SC 'I'atu!Dissolved Sulids TDS 137 17014 mg/1 1 bs/d GC An>nun>ious N 7C Oil und O<reusa 0.50 mg/1 lbs 8C I)ran>hie 9C Chlorine,Tutul llesidunl IOC Tenlpersturo I'C) I'C) I'C) winter Vs>us Vs'us V slue IIC Temperature I'C)

I I In'I or IC) I'C) su Vs>us V clue value l2C i>I I standard stundurrl Mtnl.. 7010 A >5.. units units 2 u hluximu>n Daily Vulva-'llcpu>t tha ~hi hast daily value or daily overage vulua fran> the last yaurufdatu. Ilcpurt bath >nuss m>J cancentrution.

2 b hlaxinlu>n 00 I)sy Vuloa- l)ctannine tha uvaragc ofull doily values dnlil'>0 each cuh>nduf alon>hand report tha highest uva>'uge.

2 c Il>ng'I'I rnl Avaruge Vulua-'I'ha average ufull values withid tha last year and report l>oth n>ass u>nl cl>ncantrstiun.

2d hlini>nu>n of three sun>pling events rcquircd fur process wastewater disclnlrgcs and u nlinimmn ofuna sampling avant li>r ull other discharges, trautn>ent lucilityinlluant und intukc wutcr.

~ ~~ ~~ ~~ Sf Cuu >u Ituv,u>UI SR( 1'lON C (conLintlef0 Nl l)l>S Nttntber l A 0047325 ill. llHQUlll!>:I)AN I) Ol'l'lONAI. ANAleYSES ses llesults '.,Anal Q Out!'ull Sampling Results (!+cute Suntpling I'oint on I.ino l)rawing required by Question A.IO)

L)g outfu)I Nun>be 072, Service and Administration Building Sump Q Intake Sumpling Results- Optional ISpecify Source Q Upstream Background Sumple Results-Optional(Specify lwcation of Sample p Treutm ant Facility IUAuent Sampling ltesu its I Locate Sampling Point on Line Dt swing required by Question A.IO Q New l)ischarge (Describe basis for information presented, see Instructions for Section C, Part II lfyou have aay rostoa Io espacl tha puUutant to he Accep'hl 3. lovel Pretest 4, Units 5. aw>sally precast hs Ibis dfscbarro, cbech tho appropriate

~ 2.

l'ollutant l)etec. I)etecuua KPA ~ . Mes Gaily Value b. Average uf Aaslyres c Pnsefflcfent uf hloclt or describe anuusw reason.

Group 2 tlun lnvet tave>

Used Me>bud ffua bur Coacea.

ffu asbw effluent later.

Cvscea uf Guncen. Mess VarlahUny Kaw Manu. rsedl ~ te Uy Intel>a (pg/I) (pg/I) Used IrsIIoa Moss Irslluh Mess Analysis Ice>ion Il)VI Materiel Iectured Stored Pruduct I'ruduct WaIo>'ther I Yspl In>

~

13C Cuh>r 14(l Fecal oulifi>rm Fluoride 100 I

16C Nilrute.Nitrite.

fasN) 353.2 0.7 0.09 mg/1 1bs'/d 17C Nilrogen, Total Organic(ar N)

ISC Phosphorus lac P), Totul

)9C Su)fute las SO<) 1,000 20C 8ullide (as S I 1,000 2IC Suliite lad SOU) 2,000 22C Surfuctunts 26 I M))AS)

3. Ifother dutu is uvuilubl< li.e. 1)hlR data, etc ), the pust year ofdutu may be used to deterntine 3u,3b,3c, snd 5.

3 a h(erin>urn l)oily Value- Report the ~hl hest daily value or daily averugt. valuo from the last year of data.

Report bulb mass and concentration.

3.b Averuge uf Analyses- l)ctermine the average of all samples taken within the past year.

Report both mass und concentration.

3 c A ntinimumuf three Sunq>ling Events required lur process wastewater tlirchurges,and u tninimum ofutuf Sampling Event fur ull other dischurges, treatntent fucility inAuent, intake wuter and background.

hluke copies of this tuble und check upprupriute bur.

It is in ll>supplicant's interest lo achieve a level of detcclion ut leust equul lulor prclerubly more sensitive thun) lhose listed.

This willtttinitttize uncertainty and therefore lite need fur additional anulyses or putcntiul for establishing a large number ofcAluenL limits ut>IVor monitoring requ'ents in the

~ .

final Nl'DES permit.

~

Sh:O'I'10 cnt )(,i Bt tctl) NI'l)lr'S Nttntl>er I'A 004 III. III<'.()UIIII:I)AN I) Ol'I'IONAI, ANAIrYSl<.'S s

3. Atlul sus llusttlts P Outfall Sampling Results (I+cate San<pling Point on I.ine Drawing required by Question A;10)

Kl outfull Nutn< cr 072 Servi ce and Admi ni strati on Bui 1 ding:Sump Q Intake Su<ttp!ing Results - Optional (Specify Source Q Upstream Bockground Sumple Results -Optional (Specify Iacatlon of Sample Q Trcattnent Encl lity l niluent Sampling Results '.~cate Sampling Point on Line Drawing requiro'd by Question A.10 p New Discharge (l)escribe basis for information presented,see Instructions Ior Section C, Pert II Accept. S. tr you have any reason to aspect the pollutant tobe

3. Invvt Present 4. Unt<s 5.

~ bte l. 2. nova<ally present tn <his dbcbargo, chech the appropriate POll tt lttlit ttotec. Ovtvcuen EPA ~. Mar Ustly Value c Cue<Bc<eat or btoch or describe another reason.

b. Average or Analyser tlvn Levot Group 2 t<<vst es Used Method No<aber Nu<abvr Etnuvnt Inter.

Concea. Cancan. ot Cancan Mass Vartabully Bsw Manu. a<edicts By. Intaho Other (continued) (I<811) (pg~) Used <rotten Mors IroUsn Mars traUon Matortal<scturod Stored Product Produc< Water Analyst r <CVI <Erplatn) 16M Phenols,'I'utul 16M Aluminunt, Total 100 17M Bariu<n, Total 100 18hl Boron, Total '00 10 200.7 43 0.005 1 ug/1 lbs/d 19M Cobalt, Total 60 Iron, Total '30 2IM Iron, Dissolved 30 Msgnesitun, 22hl 30 Total Mulybdclltll<l, 23M 100 Total Manganese, 24M Id Total 26M Tin,'I'utul 800 26hl Titnnium, Tutal 400

3. II'other <lutu is availublu ti e. DMR data, etc I, the past year of<late may bc used to dctcrmine 3a,3b,3c, an<I 6.

3 a Maximum Daily Value Report the ~hi hestdaily value or daily average value from the lastyearofdula. Report botlimass and concentration.

~

3.b Average of Anulyses. Determine the average ol'all samples taken within the past year. Rcport both mass and concentration.

3.c A minimum of thrcc Sampling Events required lor process wastewater discharges, and a mini<num of otte Sampling Event for all other discharges, treatment fucility inlluent, intake wuter uml bockgruuml.

Make copies of this table and check appropriate bux.

It is in the applicant's interest to achieve a level of detection at least equal to (or preferably ntore sensitive thanl those listed. This will minimixe uncertainty and therefore the need (or additional analyses or the potential for establishing a large nutnber uf cnluent limits andior monitoring requirements in tits linal NPDES permit.

r It llwtI 255.)rn Ite'v. ting SRC'I'ION C (continueti) NPI)ES Number I'A 0047325 III. Iti"QVlltEI>AND Ol'I'IONAI. ANAIUYSES

3. Ant)I ges ltesttlts 0.0087 NGD Q Outfull Sslnpling Aesults(lxlcute Solnpling I'ointon I.ine l)rowing required by (Iuestiun A.IO) g Oui('ull Number 074 Unit 2 Turbine Buil din Sum Q Intuke Sumpling Ilesults- Optional (Specify Source Q Upstreaml)uckgrnunllSsmplollosnlts-Optionul(Spocifyl~cutlonofSanlplo Q Treutmont I'ucility Innuent Ssnlpling llesults (locate Sulnpling I'oint on I.ino Ilrswing roquired by (fuostion A. IO Q Now Discharge (Describe basis for iniormotion presented, seo Instructions for Section C, Part il

1. POLI.U'I'A

2. I.EYEI.

b. h1uximuln 30 Duy Vuluo PltESEN'I'o.uf

c. I.ong Term h vga. Vuluo

3. UN I'I'S 4.

CuefAclent of E(Auent N'I'ltOVP

a. Muxlnlum l)uily Value (ifavailable) (ifuvuilublo) b.

I Vuriuhllity Analyses Cuncentratiun (CV)

I I I Canc>>airs ilun I5IHNI>> I I I Canc>>nor allan l2IHsc ~ IIICua csausllsn (5I Macs IC lllochenllcul Oxygen l)enlund, IIOI) 2C (:hcnlical Oxygen I)en ond, COI) 13.1 0.95 mg/1 1bs/d

'I'otal Orgu>>ic Curbon, 0.29 mg/1 1bs/d TOC 4C I otal Suspended Slhds, 1bs/d

'fSS 2.6 0.19 mg/1 5C 'I'rite! l)issulvod Solids.

'I'l)S 267 19.37 mg/]. 1 bs/d 6C Amnmniu ss N

'1 C Oil und (Ireuso 0.29 mg/1 lbs/d 8C Ilronlide 9C Chlorine, Total i(csidusl IOC Tenlilofutul'o I'C) ('C) ('C) winter Vslu>> Vslu>> Vslu>>

I IC Temperature 't.'C) I'C) ('C) sun'nnef Vslus Vslu>> Value 12C 7.4 8.13 standurd stundunl pl I Mlnnauas Music>>a>>I uolte uolte 2 u hfuxilnunl l)oily Volvo. I(spurt thc h~lrhest doily value or daily uvul ago value I'loni the hist your ofdatu. I(aport both nluss und cunccntrutiun.

2b hluxinlunl 301)ay Vuluo. 1)ctelmine the uverago ofull doily vulues during each culendar month und report tire highest uvoruge.

2c IAnlg'I'ural Av rugs Vsh:I. I he overage ofull vuhn'5 wlthln tho last youl'u I I rl'I el I Inlth nisse and cinlcentfstlon.

2.d hliniunlmufthroe sung lil.g events required tur process wustowater discharges and u minimum o one sampling ovont for ull other discharges, troutnlont fucility innuent >>u inluk " ter.

sRc'1'loN c (conlintlet0 NPI)RS Number 1'A 0047 ill. 1(EQV ) ANI) Ol'1'lONAl. ANAl>>YSES a

3. Anl) es Resulls Q Outfull Sampli Ig Results Il ucuto Sufnpling I'uiqt tfn I inft1)r)L)virlgreqqired by Question h.l0)

QOutfull Nufnber t 074, Uni 2 Turb)ne oui I a) ng SumP Q Intake Sunrpling Results-Optional ISpecify Source Q Upstreunr Background Sample Results- Optional lSpecify Localion ofSample Q Trsutment Psc>lit y Innuent Soinp)ing Results ILocato Sampling Point on Line Drawing required by Question A.IO Q New l)ischurgo Il)cscribo bonis for inlnrwation presented, see Instructions for Section C, Purt ll S. Ifyou have say rosroa Iuorpocf rbe puuuranrro bo Accopc 3. Ideal Prerenf I fall ~ 5. nursrauy presser ta u>ls dlrcb>>rgo, cbocb u>o oppruprlafo able l. I;usmc l ~ el blocb ur describe snu(her re>>sun.

I oIILItttn1 Ilofoc llolocdon RPA ~. Mss I)suy Value b. Average uf Anslyroe c uf (a I'O Ill) 2 rien I%vol Me>hud Mu>>>bur Kfnuonf Inlor I~vol ee Urod fru arbor Conc>>a Concoa uf Cuacon. Vsrtsbuny Raw M snu. ~ aodlaro uy. Inc>>be ~ Orbor

<Ifgn) Ipgn) Ur ed Iraflos Mars Iradun M>>1 ~ Analysts fr>>rien <CVI Material faclurod Stored producf product Wafer <gspl ~ In>

13C Color 14C I'ecul Coliforfn 15C I'luurids 100 16C Nitrute Nitrite 353.2 0.3 0.02 1 mg/1 lbs/d los NI 17C Nitrugo>>, Tulul Organic los Ati Iec Phosphorus Iaa P), Total

)9C Sulfute los SOI) 1,000 20C Sulfide Ios Sl 1,00'0 21C Suliito los SOs) 2,000 22C Surfuctsnts 25 IMIIASl

3. Ifother dutu is uvsiluble Ii e. 1)MR data, etc l, the psst yeur ufdsts Inay be used to deterntine 3s,3b,3c, aud 5.

3 a hlsxiwuInl)oilyValue-Report the~hi rhestdailyvalueordailyaveruge valuofrom the lastyearofdata. Reportbothmassandconcentration.

3b Averug>e uf Analyses. 1)otermine ths average of all samples taken within ths pssL year. Report both mass und concentration.

3c A InhIhnum of three Ssfni>IRIg Events required fur process wustswstcr discharges, undo winimuw of one Sampling EvenL fur all uther discharges, treatnrent fucility influent, intake wutsr and background.

Muko copies of this Lui>lo und check upprupriuts box.

It is in tho upplicunt's 1 Itsrest to achieve u level of detection ut least squul to lor preferably more sensitive thun) llu)so listed. This willnfininfiso uncsrtuinty and Lhsrsfurs the nssd for udditiunsl unulyhcs ur putontiul fur estubliahing a largo uuwbur ul'ollluonL liwits ufui/ur wonitbring requirements in tire linu'I Nl'DES permit.

ER ()W(l.288.10: 1\ev. 6/93 SRC'I'ION C (continueti) NPDES Number PA 0047325 III. IIRQUIRED ANI) Ol'TIONAL ANALYSES

3. Anul ses Results Q Outfall Sanlpling Results (Locate Sampling Point on I ine Drawing required by Question A.10)

Qj oulfall Number t 077 Uni 1 Condensate Stora e Tank Area . (Storm Water)

Q Intuke Sampling Results - Optional (Specify Source Q Upstream Background Sample Results. Optional (Specify Location of Sample Q Treatment Facility lnlluent Salnpl ing Resul la (Locate Sampling Point on Line Drawing required by (Iuestlon A.10 Q Ncw Discharge (Describe basis 1'or inforlnation presented, see Instructions for Section C, Part ll

2. LEVEL PRESENT 3. UNITS 4, I. POLI.UTANT CoeNclent

b. Msxlnlum 30 Dsy Value c. Long Tern> hvge. Value d.

a. Maximum Dally Vulue (ifavailable) (lfavuilable) uf E('nuent GIIOUP I No. of Variability Analyses Concentration Mass (CV)

IIIcunrenrruuen Isl Mere Illeuneenttnuun IXIMace illCencenunllen (MMnee

)C Biochenlical Oxygen Dcnmnd, BOD 2C ( henlicsl oxygen Demand, COD 3C Total organic Carbon, TOC 4C Total Suspended Solids, TSS 2.6 0.18 mg/1 Total Dissolve J Solids, TDS 6C Annnonia ss N 7C Oil andGreaxo 1b/d 0.70 0.048 mg/1 8C Bronlide 9C Chlorine, Total Residual 10C Temperature (C) ('C) ('C) winter Vnlue Vnlue Vnlue 11C Temperature ('C) (C) ('C) sunlnler Value Velue Vnlue 12C pll 7.15 7.15 standard standard Mlnlaua Mealaua units UnILI 2.a Maximum Daily Value- Report the ~h( rhestdsily value or daily average value from the lsxt year ofdota. Reportbothmsss and concentration.

2.b Maximum 30 Day Value Determine the average of all daily values during each calendar nlonth slid report the highest average.

~

2 c LongTernl Average Va'iue-The average ofall values within the Isstyesrsndreportbothmasxsinlconcentration.

2.d Minin fthree sampling events required fur process wastewaterdischarges and a minin one sampling evont for all other discharges, treatment facility influent and in ster.

SEC'I'I() N O (cot(i,it(wc(I) N I'l)l-'S Nu(0110r I'A 00473 III. IIEQU I> ANI) Ol'I'IONAI. ANAIsYSL"S

3. Anu ses llesults 0.01985 HGD Q Outfull Ssmplinl Results(lucute Sampling I'oint un I.ino Drawing required by (Iuestiun A.10) g ou(full Nuntber 079, Sewa e Treatment P1 ant Q lntuke Sampling Results Optional (Specify Source Q Upstreum Background Sample Results -Optional (Specify luce(ion of Sample Q Treatment Racility lnAuent Ss1npling Results(lucate Ss1npling Point on I.ine Drawing required by Question A.IO Q New Discharge (Describe basis for inforn1ation presented, sce Instructions for Section C, Port II

2. LEVEL PRESh:NT - 3. VN ITS Cuefnclent I. POLI.U'I'ANT b. Muxin1um 301)uy Value c. lung Ter(n Avgu. Vuluu d. of Efnuent

a. hluxin1um Daily Value (Ifavailable) Ilfuvulluhle) b.

GROUPI No. of Variability Anulyses Cuncentra(iun hines (CV)

<11C acvaccs<<va 1SI Mals ul Cva Casts alias unMass 111 Cls evan situs (S1Mass IC, lliuchcn1icul Oxygen Dc1nand. Ilt)D 16.2 2.68 mg/1 lbs/d 2C CllcnlIcul Oxygc1'I I)I.'11lulldi COD 3C 'I'otal Orgunic Curbun,

'I'OC 4C I otal Suspended Solldsi TSS 11.6 1. 92 mg/1 1bs/d 5C Tutul Dissolved Solids, Tl)S 6C Amnu1niu us N 63.6 10.53 mg/1 1bs/d 7C Oil und Orcase 8C llrun1ide 9C Chlorine, Total Residual 1.04 0.17 mg/1 lbs/d 10C Tcnlpcfuture ('C) t'C) ('C) winter Vsluv Vsluv Vs lus 0 IIC Temperature 12.41 24 .('C) ('C) ('C) sll11'I II'1 or 15.5 Yaluv Vs(us Vacua 25 standurd stundard 12C pl I M(abauea S(Xlkuw units un1(s 2 u hiaximum Doily Value'cport thc (~11 best daily value ur doily uvcrugc value from the last year uf dutu. Rcpurt both n1uss und cuncentrution.

2.b hluxi1nun1 301)sy Vulue Dctcnnine the uverageet'ull daily values during each calendar mon(hund report the higltest uverage.

~

2 c lung'I'crn1 Average Yui<<e- The average uf ull values within the Ios( year ond report both n1ass and concentration.

2 d hlinimu1n ul'three san1p ing eVen(S required fur process wastcwut<<r discharges ands 1ninin1un1ufune sampling ovunt fur ull other dischurgcs, treutment fucility inlluent und intuke water.

t'l ttwt( dttu.(U: l(ev. 4/Sg SEC'I'lON G (cnntint(e(0 Npl)RS Nun(her 1'A ~< 47325 ill. ill"(}Villi:1)ANl) Ol'I'lONAl. ANAleYSl"S '.

Anni ses liest(ll,s Q Outlull Sampling Results(latcutuSuntltlittg I'uinlunl.in'.gruwjttg roquiredby Question A.IO)

I ant Kl o (full Nn,).079, Sewage Treatment v Q Intuku Suntpling Results -Optiunul (Specify Source Q Upstream Buckground Sample l(usults. Optional (Specify I+cation of Sample Q Treuunent Facility lnnuent Sampling Results (Locate Sumpling Point on Line Drawing required by Question A.IO Q New I)ischurgo (Describe basis for info rotation presented, see Instructions Ior Section C, Part II S. (f you have any reason su aspect the pultutant tu be Accept 3. (bevel present 4. Bolts 5. nursaenyprossnt(a(hi ~ dtscbarge,cbech the spprupr(ete able I. 2. Cue(Ra(ent block or describe anuthsr reason.

I'ollutunt Uetec- Oetecttua UPA a Maa Dally Vates b. Average uf Anatysea c, of

(~vet Methud Heather R/nuent (uter.

Group 2 t(un Level Used Nussber Coacen. Cancan uf Cancan Mass Var(ab(ttty Raw Manu. seed(ate By. Inl she ether Ittgh) (Itg/I) Used trot(on Mass tratIiin Mesa Anatyet ~ uadun tUVt Mater(at (ectured product Product Water tgspts(nt

)3C Color

)4C Fecul coliform 92220 0 N/A /100m tj/A

)5C I"luuri de 100 IGC Nitro(u-Nitri(o (as Nl 353. 2 1. 7 0.27 Iig/1 lbs/

I'7C Nitrogen, Tolul

()rguniclus Nl Igc I'ltospllorus (as Pl, Total 365.1 8.02 1.33 g/1 ebs/d 19C Sulfuto (as SO, I I,OO(f 20C Sullide (as Sl I,OOO 2IC Sullilo (as SOs) 2,00n 22C Stlrfuctsttls 25 (Ml)AS)

3. !father dutu is available(i e. DMIIdata, etc l,the pust your el'dutu may be used to determine 3a,3b,3c, and 5.

3 a Meximtnn 1)oily Vultte- I(sport the ~hi sheet doily value or Juily uveruge value from the lus( yearofdatn. Report both ntsss and concentrulion.

3.b hveruge of Analyses- Determine the average of al) satttptes taken within the psst yeor. Report both mass and concentratiun.

3 c A ntinitnutn of three Ssntpling Events required for process wustewstel'tlischurges,undo tninit)tutu of one Suntpling Event fur ullulherdischurges, treut (nant fucility inll t<<t I, intake wuter uml bock(!round.

Muku copies uf this tuble und check u pprupriuto bus.

It is in tits upplicunt's inlerest tu achieve u level ofdetecliun ut leust equal (u (or preferably snore senti(ive thun) (hose listed. This will st tinimizu uncertainty and therefore the need fur additional anulyses totuntiul for establishing a iurge nuntber of einuett t limits und/or monitoring requ'ents in the linul Nl'DES permit.

SRC'I'ION C (con(,inttt.(') Nl'DRS Nutttbt.r I'A III. IIRQU 0 -ANI) Ol"I'IONAI. ANAIsYSRS

3. Ann og IIo>III(< 406 gallons per 150 min Rain Event (See Note)

Q Outful)Sam p ling itesults (lxico to So wipliwg I'oint on l.iwe I) rowing required liy (Iucstion A.I 0) g outfall Numlier 080, Stormwa ter Runof f Q lwtuko Suwipliwg ltcsults Optioiiul (Spocify Source

~

Q Ijpstreuni lluckground Sompto liosnlts -Optional (Specify Isicistiow of Sample Q 'I'root ssscist I ucility l>>tlucwt Sumpliwg ltesults I lsscato So>>ipling I'uiwt oii l.ina l)ruwi>>g roqwirosl Ly (]wcstioii A.IO Q Naw Discharge tl)cscribo basis I'or information presented, sco instructions I'or Section C, I'art II

2. I.HVRI. PIT RSRNT 3. UNITS Cucf(iclent I. POI.I.U'I'AN'I'IIOUP b. Muxinium JO I)uy Vuluo c. I.ong 'I'erin Avgo. Vuluo d. of Efnuent I ii. Maximum l)uily Vulue (Ifuvuiluble) (ifuvuilulilo) No. of Vurluhility Anulyses Concentration (CV) iiiCunssnlrsslssn iai M sss ilicuncsnlrsilun I'l Muss Ill Cuncsnirsslun IXI Mass IC lliocliciwiculoxygen l)eiliuild, IIOI) 1.22 mg/1 N/A 2C Chemico!Oxygen I)emend, Col) 12.3 N/A m 1 N/A 3C Total orguwic('urban,

'I'OC 4C Total Susticn(lail Solids,

'I".iS 2.0 N/A mg/1 N/A 5C 'I'otul ()isssitvcd Ssstids, Tl)S GC Awiwwwiiuus N c 0.10 mg/1 N/A 7C ()il unil Orcus<<

c2 m /1 N/A SC llroinide 9C Chlorine, Total iiesidusl c 0.10 mg/1 N/A sllllllllci'/A IOC 'I'empcruturu I'C) t'C) ('C)

Wl liter Vslus Vslua Vs lus IIC 'I'emperaturc I'C) I'CI I'C)

Vsius Vsius Vslus I2C stoililtlrd stundurd t)i I M In I sass as Msslasusa uiiito units 2 u hluxiwiwin l)oily Vuluo 'Iiclsurt tli<<higliest sicily value orsluily uvs rug<<vulwe Irsww tlic I sst yi ur of slate. I(aport butli nwiss unsl cowccwtrutiow.

'2 L hloxiinwwi:lnl)oy Vulwc ~ l)ct<<nniiic tlio uvi raga ofulliluilyvolucsilwriiig each culcwilur inowtliund report thc higlicst uvcrugc.

2 c luisg 'I'erwi Average Vis!sso -'I'lie overage ot'ull values within the lost, your sod report both inass uwd sksnccntretiun.

2 d hlinim<<nn of three sump!ing events rcquireil for process wastowut<<r ilischurges und u inininium ofonc sampling cvcwt iiirull otlicr dischurges, troutinent fucilityin()went und iiituke wutcr Note - Max flow 5.2 gpm above background during 3-hour sampling period; 0.14n of rain, greater than 72 hours8.333333e-4 days <br />0.02 hours <br />1.190476e-4 weeks <br />2.7396e-5 months <br /> since last rain event; 3-hour composite samples for all parametersexcept oil and grease, pH, and fecal coliforms.

~ o ~ ee ee et Cbb. Iu: Itl:V.IIIU.I SEC'l'lON C (cnnlinueIII NP1)ES Number l'A Ill. llEQUlllEl) ANlt OV'l'lONALANALYSES '.

Anal ses Besot(s Q Outfu) I Sampling Results ((~cute Sutnpling Point on I inc Drawing roquired by Question h.(0)

Q,onlf n Nu nb, 080, Stormwater Runoff Q Intake Sumpling Hcsults. Optional(Specify Source Q Ups(roust Background Santple Results - Optional (Specify Location of Sample Q Treatment Facility Innuenl Suntpling Results t lecstu Sum pling point on I inc Drawing required by Question h. IO Q New Discharge IDcscribe basis Ibr ittft>nttution presented,see Instructions lbr Section C, Pert Il LL(Lilt( ~. IC you have say rescoa tu eapect the puttutsnt tube Accept. 3 Invel Prevent 4. Units 5. nw0>>uy present In this dLchsrge, cbech the appropriate ebt I. 2 Coemcleut btoch or describe anon<sr rsacoa.

IaOI I l)>>tee. II>>teen>>a RPA a. Mss Dsuy VsIue b. Average ul Analyses c ol tlun lovel M >>thud Ituaber blaue nl later.

Group 2 level Used Itu0ber Coacea. Cuacea. ul Cue cea. Muse Var(chatty Ravr Msau- 0>>dist>> ay- I at>>h>> Other (Itgn) (pg/I) Used Iratlon Mots Its tlua Mesc Aaalyvls tr atlas ICVI Matsrlsl htctursd Product Product Water tha plaint l3C Color l4C Fecu)Culifornt 9222D 6 N/A N/A 2

'100m (See Note) 15C Fluoride IOO IGC Nitrate.Nitrile Organic (ug N) 353.2 2.0 N/A I'IC Nitrogen, Tulul (as N)

ISC Phosphorus (ag P), Total 365.1 <0>>10 N/A mg/l N/A I SC Sulfulu log Soc) I,OOO 20C Sulfide lag Sl I,OOO 21C Sullitu(ug SOg) 2,000 22C Surfuclsnts 25 (Mllhs)

3. II'other tiutu is uvuiluble ti.e. DMH data, etc.), the psst year ufdstu may be used to determine 3u,34,3c, and 5.

3.a Magitnuttt lhlilyValue. Report the ~hi <hest daily value or daily uveruge value from the lasL year of data. Report both mass and concentration.

3b hveruge ufhnalyses. Determine lhe average of all satnples taken within the pust year. Report bothmass and concentration.

3c h ntinintutnuf three Sat titling Evenls required fur process wusluwsler dischurges, und a ntinimunl ofune Ssntpling Event fur ull other dischurges,(reatntent fucililyinfluent, intake wuter und bsckg bund.

Make cupics uf this tttbls und check upprupriute bbg.

It is in Lite upplicunt's interest to achieve a level of detection ul )aust cquul tu lor preferubly ntore set Is(tive thun) (husu I(sled. This willminimigu uncertainty und lltercfure tile need fur uddiliunsl analyses or pulbntiul fur establishing a lurgu number of efllt tent limits und/or monitoring in Lhe finul Nl'DES perlnlt.

rcqu~in eats Note - A ond fecal col.iform sample was taken since first~pie analysis began after six hours, exceeding procedure holding time.

STANDARD METHODS Thirteenth Edition Procedure 302 Page 1 of 5 GROSS ALPHA AND GROSS BETA RADIOACTIVITY IN MATER TOTAL, SUSPENDED AND DISSOLVED INTRODUCTION This procedure is required for environmental water samples analy?ed under certification by the State of New Jersey Department of Environmental Protection.

Steps in the procedure listed below are taken directly from their source 'The Standards Methods for the Exam1nat1on of Mater and Mastewater, 13th Edition. Notes 11sted under the steps were wr1tten at Teledyne Isotopes to assist the analyst.

4a. PROCEDURE FOR GROSS ALPHA AND GROSS BETA ACTIVITY

1) For each 20 sq cm of counting pan area, take a volume of sample containing not more than 200 mg of residue for beta examination and not more than 100 mg of res1due for alpha examination. The specif1c conductance test helps to select the appropriate sam-ple volume.

NOTE: The 2-1nch diameter stainless steel planchet used for this analysis (stamped with a concentric ring pattern) has a counting pan area near 20 sq. cm. Therefore, sample volumes containing not more than 200 mg of residue for beta analysis and not more than 100 mg of residue for alpha analysis are required. A conductivity test of the sample, expressed in mg total dissolved solids (TDS) per liter, will ind1cate the approximate aliquot size which will meet these limits.

2) Evaporate by either of the following technics:

(a) Add the sample d1rectly to a tared count1ng pan in small in-crements, with evaporat1on gust below bo111ng temperature.

pprov y pprove y Issue or Effective Vice President Manager Revision Pa es Pre ared B Date Technical ualit Assurance Issue 5 04/18/88

8. I H. M. Jeter J. D. Martin B. I. Campb ll

STANDARD METHODS Thirteenth Edftfo Procedure 302 Page 2 of 5 (b) Place the sample fn a pyrex beaker or evaporating dish, add a few drops of methyl orange 1ndfcator solut1on, add IN HCl or 1N HNO3 dropwise to pH 4-6, and evaporate on a hot plate or steam bath to near dryness. Avoid baking solids on the..

evaporation vessel. Transfer the residue to .a tared counting pan with the aid of a rubber pol'iceman and distilled water--

from a wash bottle. Thoroughly wet the walls of the evaporat<<

wf th a few drops of acf d by means of a rubber- 'ng,vessel policeman and transfer the acid washings to the counting pan.

(Excess alkalinity or mineral acidfty is corrosive to alumfnum-counting pans.)

NOTE: Evaporation method (b) fs preferred. Use 1N HNO3 (not HC1) in order to avoid corrosion of planchets.

3) Complete the drying 1n an oven at 103-105 C, cool in a dessfcator, weigh, and keep the sample dry until counted.

NOTES: (a) The initial drying may be performed under heat lamps ff the drying 1s completed in an oven at 103-105 C.

Use fiber trays to hold planchets. The trays fft into the special dess1cator made for these sample (b) Record sample numbers, customer name, sample type, aliquot used, tare weights, final weights, residue we1ghts, date of analysis and analysts's initials in the laboratory data book as described in PRO-Q32-1.

Also complete a data sheet for each group of samples as descrfbed in that procedure.

(c) Instructions 4 and 5 from procedure 302 are not reproduced here because they apply to internal counters rather than window counters.

6) Store sample in a desiccator and count for decay Avo1d heat treatment ff if necessary.

ingrowth of gaseous daughter products is suspected.

NOTE: Store counted samples fn the special dessicator for several days unt11 the analysis results have been calculated and approved. Recounting may be performed to verify activity or to obtain . greater analytical sensitivity. Recounting for decay is generally not performed for gross alpha and beta analyses.

4b. PROCEDURE FOR GROSS ALPHA AND GROSS BETA OF DISSOLVED HATTER

1) peoceed requfs1te as in aa(1) above with maximum a tamp'le volume containing weight of dissolved matter.

thy

STANDARD METHODS Thirteenth Edition Procedure 302 Page 3 of 5

2) Filter to through be examined, a Gooch crucible a membrane filter.

or, if the suspended matter is NOTE: The membrane filter is preferred {millipore 0.45 um).

3) Process the filter as described in 4a(2)-(6) above, and report .

-the dissolved alpha act1vity and dissolved beta activity by 6ooch or by membrane filtration as the case may be.

4c. PROCEDURE FOR GROSS ALPHA AND GROSS BETA OF SUSPENDED MATTER I) For each,10 sq cm of membrane f11ter area, take a volume of sample not to exceed 50 mg of suspended matter for alpha assay and not to exceed 100 mg for beta assay.

NOTES: .

(a) The filter area on the m1111pore apparatus is ap-proximately 10 sq cm. Therefore, the filtrate mass must not exceed SO mg for alpha or 100 mg for beta.

(b) Shake the sample container to distribute particulate matter un1formly before decanting al i quot, Tri al-and-error may be required, to find an aliquot which meets the suspended mass requirements.

(c) Obtain and record tare weight of membr ane filter 1n pl anchet before f i 1 tration (see PRO-032-41) .

2) Filter sample through the membrane f11ter with suction; then wash sides of filter funnel with a few milliliters of distilled water.

3) Transfer filter to a tared counting pan and oven-dry.

NOTES: (a) Use fiber trays to hold planchets.

(b) Instruct1on 4.of applies to 1nternal the procedure 1s om1tted because it counters rather than window counters..

5) Cool, weigh, and count at the alpha and the beta plateaus.

NOTE: Record sample information and weights in the laboratory notebook and on a data sheet. See note (b) under pro-cedure 4a(3) above.

6) If sample particles tend to be airborne, treat the smnple with a few drops of Lucite solution, air-dry, and count.

NOTE: Instruction 7 of the procedure is omitted because 1t applies to internal counters r'ather than window counters.

STANDARD METHODS Thirteenth Edition Pr ocedure 302 Page 4 of 5

5. CALCULATION AND REPORTING

a. Countin errorr Determine the counting error, E (in p1cocuries per samp e , a e 95$ confidence l.evel from:

1.96 a R e

where a(R) is calculated from Eq 5 (Section 300F), using (in minutes); and e, the counter efficiency, is defined tI t2 cal-and culated as in Section 300C. 1f preceding.

b. Al ha act1vit of water,'biolo ic sam les, or silts: Report the-.

a p a ac v y o wa er, n p , y e equa on net cpm x 1 000 Al ha ~

2.22e v where:

e ca11brated overall counter efficiency (see Section 30K.1f),

and v ~ volume of sample counted, 1n ml.

The count1ng error must also be expressed fn terms of picocurie per liter by dividing the picocuries per sample by the sample volume-in liters. Similarly, calculate and report the alpha act1v1ty in-picocur1es or nanocuries per k11ogram of moist biologic material or per kilogram of mo1st and per kilogram of dry silt.

NOTE: The DEP suggests reporting detection limits when no activity is found. The 4.&6 sigma criter1on 1s most common when assigning detection limits.

c. Gross beta activ1t when al ha activit is insi nificant: For-samp es aving an a p a ac v y ess an one- a e eta count-ing error, calculate and report the gross beta activity and counting error in picocuries or nanocuries per liter of water or fluid, per k1logram of mo1st (11ve weight) biologic material, or per-kilogrm of moist and per kilogram of dry silt, according to a and b above, disregarding the slight amount of alpha activity.

For calculation of the p1cocur ies per liter of beta activity, the value of e in the above equation is determined as described in Sect1on 300C. lf preceding.

d. Beta activ1t when alpha activit is s1 nif1cant: In samples con aining an a p a ac v ty in cpm ic excee s one-half the-

STAKDARD HETHODS Thirteenth Edition Procedure 302 Page 5 'of 5 beta error 1n (cpm), deduct the net, alph'a cpm from the net'beta cpm-

, to give .the net corrected beta cpm.. Proceed as in c above to calculate and report the beta radfoact1vity in picocuries or nano-curies per liter of water, per kilogram of moist biologic sample, or-per kilogram of moist and per kilogren of dry silt. When the count of alpha activity at the beta plateau represents a small fraction of .

the acti v1ty, a rough'pproximation of the beta counting error cons1sts of the gross be'ta counting error. Where greater precision:..

is desired for example, when the count of alpha activity at the-beta plateau is a substantial fraction of the net cpm of cross beta activity,;- the beta counting error equals (Ea~ + Eb~)~/~, where ."'a is the alpha counting error and Eb the gross beta counting error;

e. Hiscellaneous information to be re rted: In reporting radio-ac ~vi y a a, s mpor an o entify adequately the saaple, smnpling stat1on, date of collection, volume of sample, type of test, type of activity, type of counting equipment, standard cali-brat1on solutions used (particul arly when standards other than-natural uraniua for alpha or cesium 137 for beta were used), time of counting (particularly if short-11ved isotopes are involved), weight of sample solids, and k1nd and amount of radioactivity. So far as.

possible, the data should be tabulated. for ease of interpretation and repetitious items should be incorporated in the table heading or in footnotes. Unless especially inconvenient, quantity units should not change within a given table. For low-level assays, where the counting error represents a significant fraction of the'measurement, it should be reported to assist in the interpretation of results.

300 F. Statistics

!n practice, all counting instruments have a background counting rate, 8, when no samp1e is present. When a sample 1s present, the counting rate increases to Ro. The counting rate R due to the sample then is:

R~Ro-B (4)

By propagation-of-error methods, the standard deviation of R can be 'calculated as follows:

(5) where ty and tp are the times at which the gross sample and back-ground counting rates were measured, respectively.

PRO-032-81

~TELEOYNE .

Page 1 of DETERMINATION OF TOTAL RADIUM e4- ~

IN MATER SAMPLES

1.0 INTRODUCTION

This procedure presents a radiometric method for determining total radium activity (.alpha) in water samples. Stable barium carrier is .added to the sample and radium is co-precipitated with barite sulfate. The precipitate is collected and mounted on a millipore filter. The precipitate mass is determined by weighing the filter before and after mounting the sample. The filter, mounted in a planchet, is counted on an automatic proportional counter. Results are calculated using an empirical self absorption curve which allows for the change in effective alpha counting efficiency caused by the precipitate mass. The calculation includes a factor to compensate for activity attributed to alpha anitting daughters of Ra-226 which are re-establishing secular equilibrium during the time period between the pre-cipitation and the midcount time.

This procedure is based on Method 900.1 of the Enviroanental Protection Agency, described in EPA-600/4-80-032, August 1980.

2.0 DETECTION CAPABILITY Detection capability depends upon sample size, chmical yield, the counting interval, the ingrowth factor for alpha daughters of Ra-226, and the efficiency and backgiound of the counting instrenent. The MDL for total radium activity (alpha) is nominally 0.5 picocurie per liter at the 4.66 sigma ssue an ec lve pprove Revision ~P ~Pp d B Date Date ~B Draft 4 J. D. Martin 10/17/83 07/Ol/83, . D. Mart Revs sion 4 H. Jeter 01/05/84 01/05/84

PRO-032-81 TELEDYNE Page 2 of 6 IBOIOPES.

~ level (0;3 pCi/S at the 2.83 sigma level). The MDL is based on a 5~inute counting time, a chemical yield of 0.90, an ingrowth factor of 1.5, a san-pie volte of 1$ , a detector background of 0.15 cpm and efficiency of 0.16 for" precipitate mass of 0.03 gram.

3.0 SAMPLE SELECTION PROCEDURE (a) Using the Sample Receipt Form with the Teledyne. Isotopes sample nunber, locate the sample (or sanple group) in the Sample'eceiving Storage Roan and transport thm to the Alpha-Beta Laboratory.

(b) Begin filling out the Radiochemical Work Sheet, entering .the customer name, the sanple nunber, total radim (as the analysis),

sample collection date, the sample preparation date and the initials of the analyst.

(c) Make an entry in the Laboratory Data Book showing customer name, sample nunbers, sample type, collection dates and desired analysis.

P 4.0 CHEMICAL SEPARATION PROCEDURES

~ .

(a) Write the Teledyne Isotopes sample nunber on a 2-liter beaker.

Shake the sample container and decant into the beaker, filling to the 1 liter mark.

(b) Adjust pH to 3 with HN03as follows: Using a dropping bottle, add conc HN03 to the sample while stirring with a clean glass rod. Withdraw the rod periodically and touch to pH paper. Continue until a pH 3 color indication is obtained.

(c) Allow beaker to stand approximately 10 minutes to settle any particulate matter.

(d) Gravity filter the sample through a 18.5 cm diameter fiberglass filter which is folded in quarters and inserted in the mouth of a glass funnel. Receive the filtrate in another 2-liter beaker which .

is marked with the sample nunber.

(e) Using a voluoetric pipet, add 2.00 ml standardized Ba carrier to the.

filtered sample (naoinally'8 mg Ba/ml). Stir with a glass rod.

(f) Place the filtered sample beaker (now containing Ba carrier) on a hotplate and bring to near boilirig.

(g) Using a disposable pipet, add 3 ml K2S04 reagent'(nominally 60 mgK2S04/ml) to the sample. Stir with a glass rod. Record the date and time of this addition in the laboratory data book.

PRO-032-81

~TELEOYNE. Page 3 of 6 (h) Allow the sample beaker to ranain on the hotplate another 30 minutes (at a tanperature slightly below the boiling point). A fine white BaS04 precipitate should form and fall to the bottom of the beaker. Ranove beaker from the hotplate and allow to cool.

5.0 MOUNTING THE PRECIPITATE (a) Prepare a new 2-inch stainless steel planchet for each sample by first wiping it clean with a kimwipe. Write customer name, sample nunber, and analysis (TOT Ra) on a gunmed label and stick to the back of the planchet.

(b) Place a 0.45um millipore filter in each labeled planchet. Weigh each (including its filter) on an analytical balance and record this tare weight beside the sample nsaber in the Laboratory Data Book.

(c) Set up a vacuun filter (millipore) apparatus for each sample by inserting a fritted glass filter holder in a I-liter sidearm flask.

Taking the samples in nunerical order, place the millipore filter on the vacua apparatus, add the specially designed funnel and fix in place with a clamp.

(d) Vacuun filter the sample into the correspondingly numbered millipore apparatus. Filtration is fastest if the precipitate is allowed to remain at the bottom of the beaker and is filtered last.

(e) In the last phases of filtration, rinse the sample beaker with deionized water from a wash bottle and add this rinse to the funnel.

Do not use a methanol rinse.

(f) Disconnect the vacua apparatus. Remove the filter gently with a spatula and transfer order of samples).

it to its planchet (observing the nsnerical (g) Place planchets (containing their filters with precipitates) in a fiber tray in a hot air oven (100'C), or under heat lamps, to dry.

(h) Take the tray containing dried samples to the analytical balance.

Weigh each planchet and record final weight next to the correspond-ing tare weight in the Laboratory Data Book.

Subtract the tare weight fran the final weight and record this mount weight in Laboratory Data Book and on the Radiochenical Work Sheet.

Divide mount weight by the carrier standardization value (written on the Ba carrier flask) to obtain chanical yield. Record yield on the Radiochanical Work Sheet and in Laboratory Data Book.-

Complete the entries on the Radiochemical Work Sheet, adding the sample aliquot used and the date and time of K2S04 addition.

Submit the Radiochemical Work Sheet and the tray of finished

PRO-032-81 Page 4 of 6.

planchets to the Radiochattistry Counting Roan for radioassay.

6.0 SAMPLE COUNTING PROCEDURE (a) Verify that the sample tray containing a group of sample planchets contains the same sample numbers as the accanpanying'Radiochaoical Work. Sheets.

(b) Write counting sequence numbers on the work sheets following the order that the sample numbers appear on the sheet. Begin with the nmnber 1 if starting a new sample counting group; otherwise use the nonber which follows the last sequence nunber assigned.

(c) Remove the sample planchets from the tray in sequence nunber order, verifying in each case that the sample nuaber on the back of the planchet matches the sequence nmber. Transfer each to a plastic planchet holder and then to the counting cassette in sequence noaber order.

(d) Write the counting start date and time, and the nunber of the automatic proportional counter on the first work sheet.

(e) Load the cassette into the counter and set the counting mode for alpha. Set the counting interval for 50 minutes unless a different interval is specified for greater sensitivity.

(f) After all samples in the group have been counted, copy the printed counts and counting interval for each sample onto the Radiochenical Work Sheet in the space provided. Also record the count date and time for each sample (certain automatic proportional counters print the count start time; others do not, requiring a smmation of counting intervals fran the first sample count).

(g) Unload the sample planchets fran the holders and store in the rack for processed alpha and beta samples.

7.0 CALCULATION OF THE SAMPLE ACTIVITY OR OF THE MDL (a) Sample activity and the 2 sigma counting error are calculated as fol lows:

~TELEOYNE PRO-032-81 ISQlOPES Page 5 of 6 7.0 CALCULATION OF THE SAMPLE ACTIVITY OR OF THE MOL (a) Sample activity and the 2 sigma counting error are calculated as follows:

.N 2 N +9 Net Ci XE H unit vo one

~ v p c 20 v p c net activity counting error where: N total counts fran sample (counts) counting time for sample (min) background rate of counter for alpha (cpm) 2.22 = ~d

~pl v volte of sample analyzed efficiency of the counter'or Ra-226 alpha, determined. empirical-ly as a function of precipitate mass.

Radim-226 alpha ingrowth factor:

p 1+3(l e )

decay constant of Rn-222, 0.007551 hr t = elapsed time (hrs) fran the time of BaS04 separation to the mid-point of the counting period.

(b) Establishing and reporting activities that are equal to or less than the detection limit:

N If the net activity ~t is equal to or is less than a

~ v p c designated multiple of the background counting error, the activity is

\

PRO-032-81 Page 6 of 6 below the limits of detection and is called "less than'L.T.) or "minimus detectable level" (HDL).

The L.T. value can be specified by stating only the counting error at a predetermined multiple (om) of the one sigma sta-tistics. A sigma multiple (am) of 4.66 i.s used for calculation of the L.T. values unless the custaaer requests another .value such as 2.83.

thus L.T. ,

v p c

PRO-022-65 TELEIÃNE .

Page 1 of 4 SQTOPES DETERMINATION OF RA-226 IN MATER

1.0 INTRODUCTION

The procedure describes the method of determining Ra-226 in water samples by the emanation technique. 'Radon-222 is equilibrated with the parent radionuclide, Ra-226, and then transferred through a closed system to..

an evacuated one-liter alpha chamber. The Rn-222 and daughters activities .,

are measured in successive counting periods for an eighteen hour period.

2.0 DETECTION CAPABILITY The minimwn detectable level (MDL) for water samples is nominally 0.1 pCi/S for Ra-226 at the 4.66 sigma confidence level. This figure is based upon a senple volume of 0.5$ , a counting time of 1000 minutes, and upop representative values of counting efficiency (for Rn-222 and two alp emitting daughters) and background of 2.45 and 2.3 cpm, respectively.

3.0 SAMPLE SELECTION PROCEDURE (a) Using the Sample Receipt Form with the Teledyne Isotopes sample number, locate the sample (or sample group) in the Sample Receiving and Storage Room. Transport the sample(s) to the Gas Analysis Laboratory.

(b) Begin filling out the Calculation Sheet Ra-226 Gas Counting form, entering the customer name, the sample number, sample collection date, the sample preparation date and the initials of the analyst.

4.0 SAMPLE PREPARATION PROCEDURES (a) Transfer 0.5$ of water to a labeled emanation flask and close the flask from the atmosphere through the tapered, ground seal. Different volumes of sample may be used in order to pprove y Issue or Effective Technical Manager Revision Paaes Prepared By Date Approval Ouality Assurance Issue (See original for 1976-1983 signatures)

Rev. 3 4 11/05/86 Q. D. Martin H. M. Jeter H. G. King

PR0-022-66.

Page 2 of 4 obtain different minimum detection levels and depending on availability of voltee.

IIyC'he sample (b) Connect flask to helios supply and pass helios for ten minutes through the frfted disk. The bubbling from the frit purges radon from the sanple.

(c) Close the two stopcocks on the emanation flask.

(d) Set flask aside for two. weeks to permit .the An-222 activity to equilibrate with the Ra-226, if any, in the water.

5.0 DETECTOR LOADING After two weeks, proceed with following steps.

(a) Attach the flask to an evacuated 1$ volume alpha counting chamber through the gas handling system.

(b) Open the stopcock on the flask which will permit Rn-222 (and any residual He) to pass into the 1$ counting chamber; (c) After ten minutes attach the He supply to the other stopcock and open stopcock and flow He through the frit, water sanple and into the 1$ counting chamber until a pressure of one atmosphere is reached on the vacuum gauqe. This step and step (b) transfers Rn-222 from the water sample to *the counting chamber.

(d) Close the vacuum valve attached to the I/ counting chamber.,

6.0 SAMPLE COUNTING (a) Turn on high voltage power supply and ad5ust voltage to pre-determined counting voltage.

(b) After two minutes, erase any counts on the sealer and push the start accumulation'button. Record the start time. IIIO5(86 (c) Record Count at 60 minute intervals until ingrowth of Rn-222 daughters is complete as indicated by a maximm count. If.

activity is indicated by the count, recount the following day

'or 60 minutes to verify the presence of Rn-222 by the decay.

7.0 STANDARDS AND CONTROL OF COUNTERS (a) A Ra-226 standard which is NBS traceable, is counted in the save manner as described above once per month. The efficiency of the combined radon extraction from the sample and the nuclear counting is determined with the standard. Record the results on a chart..

PRO-022-065='age 3 of 4

~TEUHKNE

'S(HOPES 8.0 CALCULATION OF Ra-226 ACTIVITY The Ra-226 activity is determined from the Rn-222 activity as follows:

N+5 K'

Net Ci e un t vo ume ~c 2.22(v) (c) (I-e y) 2.22(v) (c) (1-e y) net activity counting error where: N total counts from sample (counts) ht counting time for sample (min) 9 ~ background rate of counter (cpm) 2 22 v volume of sample analyzed c efficiency of the counter (I-e I) determines the "ingrowth" of Rn-222 from Ra-226 during the time lapse of ty tI the time lapse of the first helium purge to the second helium pur ge the decay constant for Rn-222 the correction for Rn-222 decay from the mid count time to the time it was transferred to the counting chamber t2 the time lapse from transfer to chamber to mid count time

PRO-022-065=

Page 4 of.4 Establishing and reporting activities that are equal to or less than the detection limit:

If the net activity is equal to or is less than a specified multiple of the background counting error, the activity is below the limits of detection and is called "less than" (L.T.) or "minimum detectable level" (NDL)..

The L.T. value can be specified by stating only the'ounting error at a predetermined multiple (am) of the one sigma statistics. A sigma multiple (em) of 4.66 is used for calculation of the L.T. values unless the customer requests another value such as 2;83.

Xt e 2 thus L.T.

2.22(v)( )(1-e I)

I ~ ~

~ ~

~ . ~ ~ II ~ ~, ~

~ ~ ~

~ I ~

~, ~ . ~

I~ I I~I I ~

~, ~

I

~ ..

~

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~ ~ ~

~ . ~ . ~ I~I I . ~

~ ~

~ ~ ~

~ ~ ~ ~ I . ~ ~ ~ . ~

I~

~ ~ ~ t ~ ~ ~ . ~

~ . ~ ~ ~ I . ~

~ ~

I tt II'Alt /N>> I>>

RECTION C tl'oullllllr'tll NI'III:,S Nuntbtr ItA 0047325 IV. INFORhlATION.AND hNALY919 OF FFFLUEN7 Ql)ALITV FOR OTHER POTFNTIALLY TO)(IC9 P()LLUTANTII I Infortttntiot on Cltcmicsl htltlitivee Known ut ~Ca ected ttt ltt Ptcsent in tht Oisch t t IRctttl ittsttuctions cst t fully sttd use lite 1>>bul>>t fot ttt>>t >>nd>>ddili>>ttttl puttee. whet t necessary, to prtscttt the ttqttlrtd ltlfortttatlortl It e ml c a I Avcrngt 4 l.owtst Whole Whol ~

C 9ttltslance or hl annfactttr tr hl>>s It>>It tn Collcttllratlutl Possible protlttct prot! ttcl Outfall Compountl i)sage Iiatt I I A n el y IIc a I 98 Ilr I.Cd(I 48 Ilr IA'6(I ts ~ to Hoaso et Namt anti Adtlrtsa Deltcllon (tttg/I) atlrl Imglll antI syeeNe lenetlesu I It alt l a y In.systtnt,' ffltttnl I Ilnlls I.evtl lltglll ~ pecltsl 1) ~ pecleetlI I I 071 Powetgnc 3625 Betz Laboratories Avg - 40 5,000 pgIL Fathead Mlreow Daphnis Magna AlkylDbnethyt Benzyl 4636 Somerton Road Max-5,000 I (0.73 mg/I) (0.04 rng/I)

Anmonlum Codde Trevose, PA 19053 ADBAC 071 NUSYN.Noxfhh Roussel Bh Corp. See Note 93 Rotenonc 1T0 Beavet Brook Road Llneotn Park NJ OT035 071 Sonar SRP Pellets SePRO See Note N3 11550 N. Merld n Sonar 5P Llquld Ca',IN 4i032 f-me5)f 3.phenyl 5-(3-(I/I/buromcthyg phenyl-4(fH)-

rtdnone 071/171 PowerHne PPL44 Betz Lsboratodes Sce Note 14 'I0,000 I 10,000 I pg/L Bbagt% Sunfhh Daphnis Magna I I Methyhcnzyf 4636 Somerlon Road I I (t09.3 mg/I) (311.2 mg/I)

I Tdazdr Trcvosc PA 19053 171 Cobratec TT-SOS- PMC Spechhies Group501 See Note 94 10,000 10,000 Rahbaw Trout Melhylbenzyf Murray RosdCInclnnall OH ( .Trng/I)

Tdazob 45217 071/079 Sodum HypoeVo/rt e Various 500 t 500 t pg/L Rainbow Trout" Ds phnh Magna Betz C-70 I 1.9 1.6 071 Slimkldc C.94 Bett Laboratories See Note NS I Rainbow Trout Daphnis hbgna t

Sodum B/o/rtlde 4636 Somerlon Road I I (0.23 mg/I) (0.71 mg/I) t I Trevosc PA 19053 I I 072 PawtNne 3200 Betz Laborat s See Note NS I I B glS Sung h Ds phnb Magna I t Sodum Mdybdate 4636 Somcrton Road I I (3255 mg/I) (5997 mg/I)

I I Sodum Hikes methyl Trevosc, PA 19053 I I t I henzotdazde I I I I f L('.50 Osl ~ for wltolc ltrotlttctis nol svsileltic. ri>>tu for the itttlivi uul nctivt'ittpttdicnts mny bc provided

~ ~ ~

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~ ~ ~

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SECTION C-IV NOTES r

NOTE ¹1 Betz Copper-trol CU-1 is not currently being used. It is included in the permit as an alternate copper/copper alloy corrosion inhibitor to the currently used inhibitor, methyl benzotriazole (TTA). Ifused, this product would be applied on an intermittent basis (once every two to four weeks) for a relatively short duration (15 to 30 minutes). Maximum concentration of the product during these applications would be near or below detection limit levels using a field test procedure.

NOTE ¹2 Betz Slimicide C-68 is injected into closed system cooling water to a recommended average e61uent concentration of 50 mg/1 of product or 0.75 mg/1'as active isothiazolin. No fields test exists for this product; however, ifused this product'would not be expected to be detected in Outfall 071. See Additional Information for Section C-I Outfall 072 for a discussion of product use.

NOTE ¹3 NUSYN - Noxfish and Sonar/Sonar SP are products used in the Spray Pond that have been permitted for use by the Pa Fish and Boat Commission and the Pa DER.

Neither product is routinely monitored in Outfall 071. See attached permit.

The Emergency Spray Pond is treated with NUSYN - Noxfish to a level of 5 mg/1; however, it is detoxified with potassium permanganate at a rate equal to this concentration prior to discharge and, therefore, is not expected to be present in Outfall 071.

NOTE ¹4 Copper corrosion inhibitors used in closed cooling systems at the station are not usually discharged to Outfall 071. During maintenance activities water may be collected and taken to the Cooling Tower Basin or Sewage Treatment Plant for discharge to the river.

NOTE ¹5 Possible substitute for chlorine as biocide.

NOTE ¹6 Chemicals not previously used at the Susquehanna Steam Electric Station.

NOTE ¹7 Based on past usage ofHennigan's HEPCO Formula 4E-50, the maximum concentration of solution entering the Susquehanna River, assuming no dilution from either the Cooling Tower Basin or blowdown line, would be approximately 1.45 mg/I. Although this product is not analyzed routinely, it is not expected to be present in the discharge.

NOTE ¹8 Miscellaneous - There are several chemicals used in very small quantities surfaces, cooling coils, decontamination of floors, walls, and equipment, for'leaning cleaning agents and liquid dye for flow tests. Some of these chemicals are:

Chemical E~st. al/ r

~ Geo-Guard 4813

~ Coil Rite

~ Bye as 220

~ Organic Orange 110

~ MSA/Cleaner/Sanitizer II 288~~

~ Rhodamine WT

~ Liquid Bleach 12

~ Spartan SD-'20

~ Touch It Up

~Not available

• • Ounces

~*~Only ifneeded Some of these chemicals may be disposed of in Cooling Tower Basin or Sewage Treatment Plant in accordance with Material Safety Data Sheets. Sheets are attached.

Note ¹9 At present bids are being reviewed to update water treatment program at the Susquehanna SES. An updated form C-IV will be provided to the PaDER in

~

C November 1994. A request for proposal for a water treatment program is usually conducted every four years or as needed.

jsflms0 663 c(26)

COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL RESOURCES E N N SYLVAN I A Street,'.

667 Nort~ River Plains, PA May 25 1994 . ',

18705-1099;,'t.;.

EIVED i < >a)4

~:.~a.sFnms (717) 826-2 Northeast Regional Office Pennsylvania Power 8 .Light Co.

Susquehanna Steam Electric Station P.O. Box 467 Berwick, PA 18603 RE: Herbicide Emergency Service Water Spray Pond for the Susquehanna Steam Electric Station Salem Township, Luzerne County

Dear Sirs:

C Enclosed is your permit for application of aquatic control chemicals. You should use extreme caution and follow the directions on the manufacturer's label when using these chemicals. It is your responsibility to conduct treatment operations in an environmentally safe manner.

Water treated with these chemicals should not be used for human consumption, irrigation, or livestock watering for a period of time as specified on the manufacturer's label. This time period will vary with the chemical used.

Some chemicals also require restricted recreational uses (i.e. swimming and fishing) for time pe iods as designated on the label. -

When these chemicals are used i n areas open to the public, you are responsible to assure that proper controls are implemented in the treated areas.

You are responsible for any damages incurred by the chemicals used.

If you have any questions, please feel free to contact me.

Sincerel Lawrence A. Pawlush Program Manager Water Supply and Community Health Program Enclosure Recycled Paper

ER-BCEC-CIOMMONWEALTH OF PENNSYLVANIA

¹-40 - I0-$ 4.

COMMISSION DEPARTMENT OF ENVIRONMENTAL ENVIRONMENTALQUALITY BOARD RESOUPfgc

~ re so,

~ -.-'~: ~ 4 AP TION AND PERMIT FOR USE OF AN ALGICIDE, HERBICIDE OR APR 2 1 3SS4 ONTROL CHEMICAL IN WATERS OF THE COMIVlONWEALTQ..

i=ISh 4 Bpat Camr;;;..;)

Sublttitf'one copy of t leted application to the Pennsylvania Fish Commisison, 450 FQQRRAt 1 6823'spells 9-5100.

Pennsylvania Power h. Light Co.

1. Name of applicant lowner) Susquehanna Steam Electric Stat~ephone No 717 542 3300 Address of applicant PO Box 467, Berwick, PA 18603 2: person or organization conducting treatment Of other than applicant)

Ecology III, Incog RR 1, Box 1795, Berwick, PA 18603 (717 542-2191 Emergency Service Mater Spray Pond for the

3. Name of water body to be treated Sus uehanna Steam Electric Station

4. Location of water body: County Luzerne Township or other municip Salem Nearest built-up area

~

5. Type of water body: Pond Lake Impoundment Canal e '

6. Uses of water body to be treated:

Water Supply: Municipal Industrial Livestock Irrigation Fire Protection Other Water Contact Sports: Swimming Skiing

~

7. Does water contain fish? Yes II No Warmwater species II Coldwater species ltroutl

8. Is water body open for public fishing? Yes No X

9. ?Ias water body ever been stocked with fish by a State Agency? Rtr Federal Agency?

10. Does water body have a discharge or overflow of water? Yes X No If YES, indicate time of year discharge or overflow will occur Intermittentl throu hout the ea

11. Name of receiving stream Susquehanna River

12. Total area of water body: Number of surface acres Treatment area: Number of surface acies Average depth ~

lanktonic 8 eri h ic

13. Indicate species of algae, plant(s) or fish to be controlled leafy pondweed.

algae, and various species of fishes native to the Susquehanna River which are inadvertentl introduce s Sonar SRP - weeds Powerline 3625 - algae, i 4. Commercial name(s) of chemical{s) Nus -Noxfish 2. 5X Rotenone - f1 sh Sonar - Elanco.Products Co., Indianapolis, IN

15. Manufacturer's name(s)

Nusyn-Noxfish - Roussel Bio Corporation, Englewood Cliff, NJ

Dosage of each chemical per treatment (specify in either pounds or gallons)

(see attached sheet fc-". ~) ~

(0.8 a)

• Powerline 3625 (0.2 a)~ Nusyn-Noxfish (8 a) 5'ntire SRP

-5'Vg

'onar (a) . per surface acre per surface acre 16.0 gal-AMg. shoreline, depth.: = shoreline depth = pond =

per acre foot 1.5 gal l0.5unds per, acre foot c) "Amount of each chemical .o be applied in each treatment (pounds or gallons) J

. Sonar = 32 =lbs, Pommel line 3625 = 23- al Nus -Noxf s Number of treatments to be made this year Sonar = 1, Pomrline 3625 = 32, Nusyn-Noxfish = 1 (d)

(e) Total amount of each chemical to be applied in all treatments (pounds or gallons)

Sonar = 32 lbs, Powerline 3625 = 80 gal, Nusyn-Noxfish = 128 gal' Sonar = 15 Jun 1994, Nusyn Nox ish = 3 Au 1994, Proposed date or dates of treatment (Fish Commission Waterways Conservation Officer MUST be contacted prior to treatment.)

see attached sheet Additional information Have all other potential users of the treated water been notified of the treatment7 Yes No " (This notice is required.)

'X (a) If so, has each of the other users approved your plans for treatment? Yes No (b) Has each potential user agreed to restrictions on his/her usage if such restrictions are t

necessary? Yes No (c) If your answer to (al or (b) ls no, please explain:

The subject water is tn an industrial basin. THere are no offsite users of this basin.

d) List other potential users and their uses:

APPLICANT CERTIFICATION a pplicant: (a) has notified all other potential users of the treated water as described in Number 19; (b) agrees to employ listed chemicals in conformance with the manufacturer's specifications and with all the conditions of the permit; (c) esponsible for all damages incurred by the chemicals used; (d) certifies the truth, of the above statements.

plicant's Signature w//a/~<

R REVIEWER'S USE ONLY APPLICATION AND PERMIT NO.

gency Reviewer Title Date Approve Disapprove h

mmission Fishrrfrs marks ~cr

~

c

~

• So SRP ac X Nu.s e- '

tn Pou er I wil aC tv Coolth tv~ O d P~hw s ts i tace uppre r/trr /tro pro onto y'e y%roa f marks is pp ication is approved pursuant to Section 101.5 of the De artment's egu a sons. rea ments ma e must be in strict accordance with manufacturer's recommendations. II(ill not affect ublic water su lie .

P APPLICATIONAND PERMIT FOR VSE OF AN ALGICIDE,HERBICIDE OR FISH CONTROL CHEMICALIN WATERS OF THE COMMONWFM~LTH A

APPLICANT: PP&L - Susquehanna Steam Electric Station (additional information)

16.

• perimeter treatment (circumference) is 3,350 ft x 10 ft out from shoreline = 0.8 a V

• • '/4 perin.o.ter treatment (840 ft x 10 ft = 0.2 a, twice/week for a 2-week period in each month, Apr-Nov 1994)

18. Powerline 3625 willnot have to be detoxified at the proposed rate of application.

Nusyn-Noxfish willbe detoxified at the Spray Pond outlet by "drip. feeding" potassium permanganate at a rate equal to the concentration of Nusyn-Noxfish in the overflow

, water.

BETZ LABORATORIES,INC.

4636 SOMERTON ROAD, TREVOSE, PA. 19053 BETZ MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE (HEALTH/ACCIDENT) 800-877-1940 (PAGE,1 OF 3)

RODUCT : POWERLINE PPL08 EFFECTIVE DATE:04-30-93 PRINTED: 04-30-93 RODUCT APPLICATION:WATER-BASED CORROSION INHIBITOR/DEPOSIT CONTROL AGENT.

---

SECTION 1-----------HAZARDOUS INGREDIENTS-NFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC RODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD'IS ISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE D CHRONIC HAZARDS OF THIS FORMULATION.THIS PRODUCT IS SUBJECT TO THE ENNSYLVANIA AND NEW JERSEY WORKER AND COMMUNITY. RIGHT TO KNOW LAW.

H1S PRODUCT IS NOT HAZARDOUS AS DEFINED BY OSHAi PENNSYLVANIA, OR EW JERSEY, RIGHT TO KNOW REGULATIONS NHAZARD INGREDIENTS: WATER(CASg 7732-18-5);2-PROPENOIC ACID POLYMER

-HYDROXY (2-PROPENYLOXY)-1-PROPANE SULFONIC ACID, SODIUM SALT(CASQ"WITH 8266-09-8)

---SECTION 2-----------TYPICAL PHYSICAL DATA-----

AS IS(APPROX.) 5.2 ODOR: SLIGHT

.PT.(DEG.F):> 200 P-M(CC) SP.GR.(70F): 1.169 POR PRESSURE(mmHG): 18.0 VAPOR DENSITY(AIR=1): < 1.00 SC cps70F: 42 RSOLUBILITY(WATER): 100.0 AP RATE: < 1.00(ETHER=1) APPEARANCE: YELLOW YSICAL STATE:LIQUID FREEZE POINT(DEG.F): 25.00

---SECTION 3-----------REACTIVITYDATA ABLE.MAY REACT WITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK EAN-OUT CATEGORY

'B'RMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES.

BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3)

PRODUCT  : POWERLINE PPL08

---

SECTION 4---------HEALTH HAZARD EFFECTS UTE SKIN EFFECTS ""* PRIMARY ROUTE OF EXPOSURE MAY CAUSE SLIGHT IRRITATION TO THE SKIN ACUTE EYE EFFECTS **

SLIGHTLY IRRITATING TO THE EYES ACUTE RESPIRATORY EFFECTS **

MISTS/AEROSOLS MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT CHRONIC EFFECTS OF OVEREXPOSURE*"*

NO EVIDENCE OF POTENTIAL CHRONIC EFFECTS; MEDICAL CONDITIONS AGGRAVATED ***

NOT KNOWN SYMPTOMS OF EXPOSURE ***

MAY CAUSE REDNESS OR ITCHING OF SKIN.

---

SECTION 5--'---------FIRST AID INSTRUCTIONS SKIN CONTACT REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER,FOR 15 MINUTES EYE CONTACT "*

IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELYCONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE"

• REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR.APPLY APPROPRIATE FIRST AZD TREATMENT AS NECESSARY INGESTION*""

DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DILUTE CONTENTS OF STOMACH. INDUCE VOMITING BY ONE OF THE STANDARD METHODS. IMMEDIATELY CONTACT A PHYSICIAN

---

SECTION 6-----------SPILL, DISPOSAL AND FIRE INSTRUCTIONS-----------

SPILL INSTRUCTIONS*""

VENTILATE,AREA,USE SPECIFIED PROTECTIVE EQUIPMENT. CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS.

FLUSH AREA WITH WATER. WET AREA MAY BE SLIPPERY. SPREAD SAND/GRIT.

DZSPOSAL INSTRUCTIONS*"**

WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS ZS)

INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS***

FZREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE). PROPER FIRE EXTINGUISHING MEDIA'RY CHEMICAL,CARBON DIOXIDE,FOAM OR WATER

BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3)

RODUCT 'OWERLINE PPLOS

-SECTION 7-----------SPECIAL PROTECTIVE EQUIPMENT-ROTECTIVE EQUIPMENT ZN ACCORDANCE WITH 29CFR SECTION 1910.132-134.USE RATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS.

ENTILATZON PROTECTION**"

ADEQUATE VENTILATION

.ECOMMENDED RESPIRATORY PROTECTION***

ZF VENTILATION IS INADEQUATE .OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH DUST/MIST FILTERS.

ECOMMENDED SKIN PROTECTION"**

RUBBER GLOVES WASH OFF AFTER EACH USE REPLACE AS NECESSARY.

ECOMMENDED EYE PROTECTION***

SPLASH PROOF CHEMICAL GOGGLES

---

SECTION 8-----------STORAGE AND HANDLING PRECAUTIONS TORAGE INSTRUCTIONS***

KEEP CONTAINERS CLOSED WHEN NOT IN USE.

STORE IN COOL VENTILATED LOCATION. STORE AWAY FROM OXIDIZERS DLING INSTRUCTIONS***

NORMAL CHEMICAL HANDLING

• • 40*400******0***%*Wc*0*****************************%'***********

HIS MSDS WAS WRITTEN TO COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD

• • • • • • • 0*******%**%*l******************************0%%%***%*****

APPENDIX: REGULATORY INFORMATION .

HE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE FFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE.

CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT.

CA'LL COMPONENTS OF THIS PRODUCT ARE LISTED ZN THE TSCA INVENTORY

~

...REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT:

~ ~

NOT APPLICABLE

...RCRA: IF THIS PRODUCT ZS DISCARDED AS A WASTE, THE RCRA HAZARDOUS WASTE DENTZFICATION NUMBER IS:NOT APPLICABLE

...DOT HAZARD/UNQ/ER GUIDES IS : NOT APPLICABLE

...CALIFORNIA SAFE DRINKING WATER ACT (PROPOSITION 65) MATERIALS:NONE

...SARA SECTION 302 CHEMICALS:NONE

...SARA SECTION 313 CHEMICALS:NONE

...SARA SECTION 312 HAZARD CLASS:PRODUCT IS NON-HAZARDOUS UNDER SECTION ll/312

...MICHIGAN CRITICAL- MATERIALS:- NONE NFPA/HMIS  : HEALTH 1'IRE 1; REACTIVITY - 0; SPECIAL - NONE; PE B

BETZ LABORATORIES, INC.

4636 SOMERTON ROAD, TREVOSE, PA 19053 PRODUCT: POWERLINE PPL08 May 17, 1994 AQUATIC TOXICOLOGY Fathead Minnow 96 Hour Static Renewal Bioassay pH of test, solutions were'adjusted to a level of 6-9.=

LC50: 1960 mg/L No Effect Level: 313 Daphnia magna'8 Hour Static Renewal Bioassay pH of test solutions were adjusted to a level of 6-9.

LC50: 1767 mg/L No Effect Level: 1250 BIODEGRADATION COD (mg/gm): 368 Calculated

'TOC (mg/gm): 144 Calculated BOD-5 (mg/gm): 10 Calculated BOD-28 (mg/gm): 32 Calculated Closed Bottle Test 4 Degradation in 28 days: 0 Calculated Zahn-Wellens Test 4 Degradation in 28 days: 8 Calculated MAMMALIANTOXICOLOGY Oral LD50 RAT: >2,000 MG/KG Note - ESTIMATED VALUE Dermal LD50 RABBIT: >2,000 MG/KG Note - ESTIMATED VALUE

BETZ LABORATORIES,INC.

4636 SOMERTON ROAD, TREVOSE, PA. 19053 BETZ MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE (HEALTH/ACCIDENT) 800-877-1940 (PAGE 1 OF 3)

RODUCT : POWERLINE PPL09, EFFECTIVE DATE'05-04-93 PRINTED'5-04-93 ODUCT APPLICATION:WATER-BASED DEPOSIT CONTROL AGENT.

---

SECTION 1-----------HAZARDOUS INGREDIENTS-FORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC ODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD IS STED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE CHRONIC HAZARDS OF THIS FORMULATION.THIS PRODUCT IS SUBJECT TO THE "NNSYLVANIAAND NEW JERSEY WORKER AND COMMUNITY RIGHT TO KNOW LAW.

PHOSPHONIC ACID,(1-HYDROXYETHYLIDINE)BIS-(HEDP)**CAS¹ 2809-21-4; EYE IRRITANT; PEL:NOT DETERMINED;TLV:NOT DETERMINED NHAZARD INGREDIENTS: WATER(CAS¹ 7732-18-5)

---SECTION 2-----------TYPICAL PHYSICAL DATA-AS IS(APPROX.) 2.1 ODOR:

200 P-M(CC) SP.GR. (70F): 1.219 SLIGHT'PT.(DEG.F):>

POR PRESSURE(mmHG): 18.0 VAPOR DENSITY(AIR=1): 1.00 SC cps70F:

AP RATE: <

19 1.00(ETHER=1)

%SOLUBILITY(WATER):

APPEARANCE: COLORLESS

'00.0 YSICAL STATE:LIQUID FREEZE POINT(DEG.F): 20.00

---SECTION 3-----------REACTIVITYDATA ABLE.MAY REACT WITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK EAN-OUT CATEGORY

'B'RMAL DECOMPOSITION (DESTRUCTIVE FiRES) YIELDS ELEMENTAL OXIDES.

BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3)

PRODUCT  : POWERLZNE PPL09

---

SECTION 4---------HEALTH HAZARD EFFECTS

'UTE SKIN EFFECTS *** PRIMARY ROUTE OF EXPOSURE MAY CAUSE MODERATE IRRITATiON TO THE SKIN ACUTE EYE EFFECTS SEVERE IRRITANT TO THE EYES ACUTE RESPIRATORY EFFECTS ***

MISTS/AEROSOLS MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT CHRONIC EFFECTS OF OVEREXPOSURE*** ~

NO EVIDENCE OF POTENTIAL CHRONIC EFFECTS.

MEDICAL CONDITIONS AGGRAVATED *"*

NOT KNOWN SYMPTOMS OF EXPOSURE ***

MAY CAUSE REDNESS OR ITCHING OF SKIN,IRRITATION AND/OR TEARING OF EYES(DIRECT CONTACT).

---

SECTION 5-----------FIRST AID INSTRUCTIONS-SKIN CONTACT <<**

REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MINUTES EYE CONTACT **

IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES. IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE*"*

REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR.APPLY APPROPRIATE FIRST AID TREATMENT AS NECESSARY INGESTION**"

DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DILUTE CONTENTS OF STOMACH.INDUCE VOMITING BY ONE OF THE STANDARD METHODS.IMMEDIATELY CONTACT A PHYSICIAN

---

SECTION 6-----------SPILL,DISPOSAL AND FIRE INSTRUCTIONS-----------

SPILL INSTRUCTIONS"**

VENTILATE,AREA,USE SPECIFIED PROTECTIVE EQUIPMENT. CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS.

FLUSH AREA WITH WATER. WET AREA MAY BE SLIPPERY. SPREAD SAND/GRIT.

DISPOSAL INSTRUCTIONS ***

WATER CONTAMINATED WITH THIS PRODUCT,MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,ZN ACCORDANCE WITH ANY LOCAL AGREEMENT A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS IS)

INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS***

FIREFIGHTERS SHOULD WEAR POSITiVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE). PROPER FIRE EXTINGUISHING MEDIA:

FOAM OR WATER CREATE A SLIPPERY CONDITION SPREAD SAND OR GRIT.

BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3)

RODUCT : POWERLINE PPL09

-SECTION 7-----------SPECIAL PROTECTIVE EQUIPMENT ROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134;-USE

-'S ZRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AZR RESPIRATORS.

"NTILATION PROTECTION**"

ADEQUATE VENTILATION ECOMMENDED RESPiRATORY PROTECTION***

IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH DUST/MIST FILTERS..

.ECOMMENDED SKIN PROTECTION***

RUBBER GLOVES WASH OFF AFTER EACH USE REPLACE AS NECESSARY.

ECOMMENDED EYE PROTECTION***,

SPLASH PROOF CHEMICAL GOGGLES

--SECTION 8-"---------.STORAGE AND HANDLING PRECAUTIONS TORAGE INSTRUCTIONS***

KEEP CONTAINERS CLOSED WHEN NOT IN'USE.

REASONABLE AND SAFE CHEMICAL STORAGE DLING INSTRUCTIONS*

ACIDIC.DO NOT MIX WITH ALKALINE MATERIAL.

W**4*a******a%******a*******a*******4*4***********4***4**********

HZS MSDS WAS WRITTEN TO COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD

<<%%**4***a****************0***************4**********4**********

APPENDIX: REGULATORY INFORMATION ~

HE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE FFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE.

CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT.

A: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY

~ .REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT:

NOT APPLICABLE

..RCRA: ZF THIS PRODUCT IS DISCARDED AS A WASTE, THE RCRA HAZARDOUS WASTE DENTIFICATION NUMBER IS'NOT APPLICABLE

..DOT HAZARD/UNg/ER GUIDES IS : NOT APPLICABLE

..CALIFORNIA SAFE DRINKING WATER ACT (PROPOSITION 65) MATERIALS'NONE

..SARA SECTION 302 CHEMICALS:NONE

..SARA SECTION 313 CHEMICALS:NONE

..SARA SECTION 312 HAZARD CLASS:IMMEDIATE(ACUTE)

..MICHIGAN CRITICAL MATERIALS: NONE NFPA/HMIS : HEALTH - 2; FIRE 1 REACTIVITY - 0; SPECIAL - NONE; PE - B

BETZ LABORATORIES, INC.

4636 SOMERTON ROAD, TREVOSE, PA 19053

,PRODUCT: POWERLINE PPL09 May 18, 1994 AQUATIC TOXICOLOGY Rainbow trout 96 Hour Static Acute Bioassay LC50: 610 MG/L MG/L'OEL'50 Daphnia magna 48 Hour Static'Acute Bioassay EC50: 870 MG/L NOEL: 660 MG/L Bluegill sunfish 96 Hour Static Acut Bioassay LC50: 1440 MG/L NOEL: 880 MG/L Note: This product has not been tested for aquatic toxicity. The data above was generated on tests conducted on the raw materials.

BIODEGRADATION COD (mg/gm): 217 Calculated TOC (mg/gm): 52 Calculated BOD'- 5 (mg/gm): 1 Calculated BOD-28 (mg/gm):, 1 Calculated Closed Bottle Test 0 Degradation in 28 days: 0 Calculated Zahn-Wellens Test 4 Degradation'in 28 days: 2 Calculated MAMMALIANTOXICOLOGY Oral LD50 RAT: >2,000 MG/KG Note - ESTIMATED VALUE Dermal LD50 RABBIT: >2,000 MG/KG Note ESTIMATED VALUE

V =  %'i7%

htdsrsf rinl BETZ CLAM-TROL CT-1 MOLLUSCIClDE

~ Extermlnates all life stages of common fouling mol- ~ fire protection systems lusks with short, 6-24 hr applications ~ Intake pump bays and intake screen areas

~ Effective on Asiatic clams, Zebra mussels, ribbed

~ storage tanks and associated piping mussels, blue mussels and most other fresh water and salt water mollusks ~ settling ponds or lagoons

~ Developed for use In a wide range of applications for ~ transport spillways or canals cooling and seivlce water systems Clam-Trol CT-1 is a blend of cationic surfactants-

~ Biodegradable low environmental impact, no Nwlkyidlmethylbenzylammonlum chloride (Quat) and t

heavy metals or EPA priority pollutants dodecylguanidlne hydrochloride (DGH). Both are

~ Photometric test method available for determining shortdived In plant systems and the environment because of their rapid absorption rate onto naturally product'concentration occurring anionlcally charged substrates and sedi-

~ Can be detoxified ments. Quat and DGH are readily neutralized by a number of materials, Including clays, slits, humlc acids,

~ A safe, more effective alternative to current treatment suspended solids and cooling system surfaces.

methods mr~ay DESCRIPTION AND USE 4F Clam-Trol CT-1 Is a unique blend of active Ingredients that control mollusk lnfestatlon In water systems.

Uncontrolled growth of clams and mussels within Industrial water systems blocks water lines, restrictsflow and heat transfer, damages equipment, and threatens the availability of fire protection systems and safetyre-lated cooling systems. The consequences are reduced plant safety, threatened water supplies, higher mainte-nance and production costs, and even plant outages.

Low levels of Clam-Trol CT-1, metered to a system for short 6-24 hr application periods, controls all life stages of fresh water and salt water mollusks. After the Initial application, the process must be repeated two to six times per year to inhibit recolonization of the systemby larvae and Juvenile clams and mussels.

Clam-Trol CT-1 Is registered with the U.S. Environmental Protection Agencyfor stat~f-the-ait control of mollusks s well as bacterial, fungal and algae sllmes In:

Figure 1. Aslatlc clams growing on the plant recirculating and once-through cooling systems side of Influent screens. Clam-trol

~ Influent cooling systems CT-1, unlike halogen or screening methods, controls both larval and

~ auxiliary water and wastewater systems adult clams.

PFP 083 9008 o1890 BElZ LABORATORIES INC ALL RIGHTS RESERVED

Clam-Trol CT-1 can be actively detoxified by a highly Clam-Trol CT-1 Is compatible with stainless steel, cop~

adsorbent, anionically charged material, such as Betz alloys, and most common plastics and rubbers. Av~

the use of mild steel, low-density polyethylene, nitrile DT-1.

(Buna N), polyurethane, or Viton in handling the Clam-Trol CT-1 is rapidly biodegradable and contains no concentrated product. A complete listing of compatible heavy metals or EPA priority pollutants. feed equipment is available from Betz.

TREATMENT AND FEEDING REQUIREMENTS Heavy Infestations of mollusks should be physically removed by vacuuming, dredging, or scraping prior to GENERAL PROPERTIES Appearance ........ colorless liquid Density at 70 'F (21 'C) ......; 8.5 Ib/gal (1.02 kg/L)

Clam-Trol CT-1 treatment. Removal of the bulk of the shells willhelp ensure that shells from the deadmollusks FlashPoint(closedcup)......... > 116'F(47'C) are not carried further into the system.

Freeze Point .. . <, -30 'F (-34 'C)

~

Your Betz Industrial representative willdesign a program for your system that controls the Infestation problem Initial Crystallization Point ........ ( 0 'F (-18 'C) while minimizing both-the cost of the treatment and pH (undiluted)................... 5.3 environmental concerns. (5% solution) ............. '...... 4.9 Warmer water temperatures and longer contact times Brookfield Viscosity at 70 'F (21 'C);....... 23 cP reduce the concentration of Clam-Trol CT-1 needed for EPA Registration No. . 3876-145 effective kills. Normally, recirculating or closed systems shouldbe laldupfor12-24hr after the system is charged with an effective amount of product. 7yplcal charge SAFETY PRECAUTIONS concentrat tons are 25-50 ppm. A Material Safety Data Sheet containing detailed Once-through systems can be effectively treated by information relative to this product ls available upon 10-25 ppm of product applied continuously over 6-24 hr request.

and repeated two to six times a year.

PACKAGING INFORMATION Segmenting plant-wide applications of Clam-Trol CT-1 reduces the amount of product that appears in plant Clam-Trol CT-1 Is blended as a liquid and is supplied In effluent. Clam-Trol CT-1 undergoes neutralization and 5&gal (208-L), bung-type, nonreturnable lined steel detoxification by natural routes. But your Betz Industrial drums. Approximate net weight Is 460 Ib (208 kg) per representative can provide products that accelerate this drum. In addition, Clam-Trol CT-1 Is available under BHZ process. An analytical test procedure ls available from Point Of Feed and BETZ Semi-Bulk Control programs Betz that monitors product use and plant outfall levels. for contracted quantities in certain geographic areas.

PFP 083 9008

BETZ LABORATORIES,ZNC.

4636 SOMERTON ROAD, TREVOSE, PA. 19053 BETZ MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE (HEALTH/ACCIDENT) 800-877-1940 (PAGE 1 OF 3)

RODUCT  : CLAM-TROL CT-1 EFFECTIVE DATE'05-14-93 PRINTED: 05-14-93 REVISIONS TO SECTIONS: 1 RODUCT APPLICATION:WATER-BASED MICROBIAL CONTROL AGENT.

---

SECTION 1--------"--HAZARDOUS INGREDZENTS-NFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC RODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD IS ZSTED. REFER TO SECTION .4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE' CHRONIC HAZARDS OF THIS FORMULATION.THIS PRODUCT IS SUBJECT TO THE ENNSYLVANIA AND NEW JERSEY WORKER AND COMMUNITY RIGHT TO KNOW LAW.

ETHYLENE GLYCOL*"*CAS¹ 107-21-1; LZVERi KIDNEY AND BLOOD TOXIN;CNS

'DEPRESSANT;ANIMAL TERATOGEN(HIGH ORAL DOSES)iPEL 50PPM-C TLV:50PPM-C (C12-16)ALKYL DIMETHYL BENZYL AMMONIUM CHLORIDE "*CAS¹ 68424-85-1; CORROSIVE(SKIN AND EYES) PEL:NOT DETERMINED;TLV NOT DETERMINED ZSOPROPYL ALCOHOL(ZPA) "*CAS¹ 67-63-0 FLAMMABLE LIQUID CHRONIC OVEREXPOSURE MAY CAUSE LIVER AND KIDNEY TOXICITY PEL 400PPM (500PPM-STEL);

TLV:400PPM (500PPM-STEL)

DODECYLGUANZDZNE HYDROCHLORIDE(DGH)*"*CAS¹ 13590-97-1l CORROSIVE; PEL:NOT ERMINED;TLV:NOT DETERMINED ETHYL ALCOHOL(ETHANOL)**"CAS¹ 64-17-5'FLAMMABLE'EYE IRRITANT;MAY CAUSE DEFATTING DERMATITIS,DIZZINESS AND HEADACHE;PEL:1000PPM;TLV:1000PPM NHAZARD INGREDIENTS: WATER(CAS¹ 7732-18-5)

---

SECTION 2-----------TYPICAL PHYSICAL DATA AS ZS(APPROX.) 3.6 ODOR: MILD

.PT.(DEG.F): 116 SETA(CC) SP.GR.(70F): 1.022 POR PRESSURE(mmHG): 23.0 VAPOR DENSITY(AIR=1)' 1.00 SC cps70F: 23 %SOLUBILITY(WATER) 100.0 AP RATE: < 1.00(ETHER=1) APPEARANCE'OLORLESS YSICAL STATE:LIQUID FREEZE POINT(DEG.F)' -30 00

--SECTION 3---'--------REACTIVITY DATA-ABLE.MAY REACT WITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK EAN-OUT CATEGORY

'B'RMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES.

BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3)

PRODUCT CLAM-TROL CT-1 1

--"---SECTION 4---------HEALTH HAZARD EFFECTS TE SKIN EFFECTS *"* PRIMARY ROUTE OF EXPOSURE, CORROSIVE TO SKIN ACUTE EYE EFFECTS *""

CORROSIVE TO THE EYES ACUTE RESPIRATORY EFFECTS *** PRIMARY ROUTE OF EXPOSURE VAPORS, GASES, MISTS AND/OR AEROSOLS CAUSE IRRITATION TO UPPER RESPIRATORY TRACT.

CHRONIC EFFECTS OF OVEREXPOSURE***

PROLONGED OR REPEATED OVEREXPOSURES MAY CAUSE'IVER AND KIDNEY TOXICITY,MAY CAUSE REPRODUCTIVE SYSTEM TOXICITY,MAY CAUSE'CNS DEPRESSION,AND/OR MAY CAUSE TISSUE NECROSIS.

MEDICAL CONDITIONS AGGRAVATED "**

NOT KNOWN SYMPTOMS OF EXPOSURE ***

INHALATZON OF VAPORS/MISTS/AEROSOLS MAY CAUSE EYEiNOSE,THROAT AND LUNG IRRITATION;SKIN CONTACT MAY CAUSE SEVERE IRRITATION OR BURNS.

PRECAUTIONARY STATEMENT BASED ON TESTING RESULTS *"*

MAY BE TOXIC IF ORALLY INGESTED.

---

SECTION 5--"---,-----FIRST AZD INSTRUCTIONS-SKIN CONTACT ***

REMOVE CLOTHING. WASH AREA WITH LARGE AMOUNTS OF SOAP SOLUTION OR WATER FOR 15 MZN.IMMEDIATELYCONTACT PHYSICIAN EYE CONTACT**+

IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELYCONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE*"*

REMOVE VICTIM FROM CONTAMINATED AREA. APPLY NECESSARY FIRST AZD TREATMENT. IMMEDIATELY CONTACT A PHYSICIAN.

ESTION"**

OO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING.IMMEDIATELYCONTACT PHYSICIAN. DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER

---SECTION 6---"-------SPILL,DISPOSAL AND FIRE INSTRUCTZONS-"---------

SPZLL INSTRUCTIONS"**

VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT. CONTAIN AND ABSORB ON ABSORBANT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE CONTAMINATED ABSORBANT SHOULD BE CONSIDERED A PESTICIDE AND DISPOSED OF IN AN APPROVED PESTICIDE LANDFILL.SEE PRODUCT LABEL STORAGE AND DISPOSAL INSTRUCTIONS.

REMOVE IGNITION SOURCES. FLUSH AREA WITH WATER. SPREAD SAND/GRIT.

DiSPOSAL INSTRUCTIONS"***

WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS IS)-

DISPOSE OF ZN APPROVED PESTICIDE FACILITY OR ACCORDING TO LABEL INSTRUCTIONS FIRE EXTINGUISHING INSTRUCTIONS**"

FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE). PROPER FIRE EXTINGUISHING MEDIA:

DRY CHEMICAL,CARBON DIOXIDE, FOAM OR WATER

BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3)

RODUCT 'LAM-TROL CT,-1.

--~ECTION 7-----------SPECIAL PROTECTIVE EQUIPMENT

~OTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134.USE r;~PIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS.

ENTILATZON PROTECTION***

ADEQUATE VENTILATION'TO MAINTAIN AIR CONTAMZNANTS BELOW EXPOSURE LIMITS ECOMMENDED RESPIRATORY PROTECTION***

IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE 6 DUST/MIST PREFILTER COMMENDED SKIN PROTECTION*",*

GAUNTLET-'TYPE RUBBER GLOVES, CHEMICAL RESISTANT APRON WASH OFF AFTER EACH USE REPLACE AS NECESSARY.

COMMENDED EYE PROTECTION***

SPLASH PROOF CHEMICAL GOGGLES. FACE SHIELD

---SECTION 8-----------STORAGE AND HANDLING PRECAUTIONS ORAGE INSTRUCTIONS*"*

KEEP CONTAINERS CLOSED WHEN NOT IN 'USE.

DO NOT STORE AT ELEVATED TEMPERATURES. KEEP AWAY FROM FLAME OR SPARKS DLING INSTRUCTIONS***

COMBUSTIBLE. DO NOT USE AROUND SPARKS OR FLAMES. BOND CONTAINERS DURING FILLING OR DISCHARGE WHEN PERFORMED AT TEMPERATURES AT OR ABOVE THE FLASH POINT.

• • • • • • 0'**%'4************4***************4*4'***4****************4*

'RODUCT IS MSDS WAS WRITTEN TO COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD

• • 4*****W*****0*********%*0********************0'***********A***

APPENDIX: REGULATORY INFORMATION RE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE FE TIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE.,

GES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT.

..TSCA': THIS IS AN EPA REGISTERED BIOCIDE AND IS EXEMPT FROM TSCA INVENTORY QU1REMENTS

..FIFRA(40CFR):EPA REG.NO.: 3876- 145

..REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT:

0.4 GALLONS DUE TO ETHYLENE GLYCOL;

..RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE, THE RCRA HAZARDOUS WASTE ENTIFZCATZON NUMBER ZS D001=IGNITABLE D002=CORROSIVE(SKIN)

.;DOT HAZARD/UNQ/ER GUZDEC IS :CORROSIVE TO SKIN.COMBUSTIBLE/UN1760/060

..CALIFORNIA SAFE DRINKZNG WATER ACT (PROPOSITION 65) MATERIALS:NONE

..SARA SECTION 302 CHEMICALS:NONE

..SARA SECTION 313 CHEMICALS: ETHYLENE GLYCOL(CASC 107-21-1), 21.0-30.04

..SARA SECTION 312 HAZARD CLASS:IMMEDIATE(ACUTE);DELAYED(CHRONIC);FIRE

..MICHIGAN CRITICAL MATERIALS: NONE FPA/HMZS : HEALTH - 3; FIRE 2'EACTIVITY - 0; SPECIAL CORR; PE D

BETZ LABORATORIES, INC.

4636 SOMERTON ROAD, TREVOSE, PA 19053 PRODUCT'LAM-TROL CT-1 May 17, 1994

'AQUATIC TOXICOLOGY Rainbow Trout 96 Hour Flow-Thru Bioassay LC50: 8.1 mg/L No Effect Level: 6.5 Fathead Minnow 96 Hour Flow-Thru Bioassay LC50: 3.7 mg/L No Effect Level: 2.1 Daphnia magna 48 Hour Flow-Thru Bioassay LC50: 0.2 mg/L No Effect Level: 0.135 Ceriodaphnia 48 Hour Flow-Thru Bioassay LC50: 0.14 mg/L No Effect Level: 0.05 Mysid Shrimp 96 Hour Flow-Thru Bioassay.

LC50: 0.34 mg/L No Effect Level: 0.1 BIODEGRADATION COD (mg/gm): 1095 Calculated TOC (mg/gm): 295 Calculated BOD-5 (mg/gm): 21 Calculated BOD-28 (mg/gm): 242 Calculated Closed Bottle Test 8 Degradation in 28 days: 45 Calculated Zahn-Wellens Test 4 Degradation in 28 days: 49 Calculated MAMMALIANTOXICOLOGY Oral LD50 RAT: 3,270 MG/KG Dermal LD50 RABBIT: )2,000 MG/KG Skin Irritation Score RABBIT: 5.13

Eye Irritation Score RABBIT: 103 Note MAX UNWASHED (DAY 14); NAX WASHED VALUE:101 (DAY 14)

BETZ LABORATORIES,INC.

4636 SOMERTON ROAD, TREVOSE, PA. 19053 BETZ MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE (HEALTH/ACCIDENT) 800-877-1940 (PAGE 1 OF 3)

PRODUCT 'ETZ DTS EFFECTIVE DATE 11-13-9 PRINTED: 13-Nov-1991 REVISIONS TO SECTIONS: 1 PRODUCT APPLICATION ' DETOXIFYING AGENT.

---

SECTION 1-----------HAZARDOUS INGREDIENTS INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD

~ZSTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE IS MVD CHRONIC HAZARDS OF THIS FORMULATION. THIS PRODUCT IS SUBJECT TO THE PENNSYLVANIA AND NEW JERSEY WORKER 'AND COMMUNITY RIGHT TO KNOW LAW.

RESPIRABLE QUARTZ(CRYSTALLINE SILICA)"**CASQ14808-60-7;SUSPECT HUMAN CARCINOGEN (ZARC=2A);MAY CAUSE LONG TERM LUNG DISEASE(SILICOSIS);

RESPIRATORY IRRITANT;PEL/TLV:0.1MG/M3.

RESPIRABLE CRISTOBALITE(CRYSTALLINE SILICA)***CASC14464-46-1;SUSPECT HUMAN CARCINOGEN(IARC=2A);MAY CAUSE LONG TERM LUNG DISEASE (SILICOSIS);

RESPIRATORY IRRITANT;PEL/TLV:0.05MG/M3.

RESPIRABLE TRIDYMITE(CRYSTALLINE SILICA)** CASN15468-32-3;SUSPECT HUMAN CARCINOGEN(IARC=2A);MAY CAUSE LONG TERM LUNG IRRITANT;PEL/TLV:0.05MG/M3. DISEASE(SILICOSIS)'ESPIRATORY TRZETHANOLAMZNE***CASQ102-71-6;IRRZTANTlPOTENTIALLIVER AND KIDNEY TOXIN; PEL/TLV:NONE.

I

'JONHAZARD INGREDIENTS: WATER (7732-18-5) BENTONITE (1302-78-9), 2-PROPENOZC ACID, HOMOPOLYMER(9003-01-4)

---

SECTION 2-----------TYPICAL PHYSICAL DATA-

?H: AS IS (APPROX.) 5.9 ODOR: SLIGHT

.=L.PT.(DEG.F): >200 P-M(CC) SP.GR.(70F)OR DENSITY: 1. 142 ZAPOR PRESSURE(mmHG): 18 VAPOR DENSITY(AIR=1): <1 v'ZSC cps70F: 2,000 %SOLUBILITY(WATER): 0

=VAP.RATE: ND WATER=1 APPEARANCE: GREEN-BROWN PHYSICAL STATE: LIQUID 3-----------REACTIVITYDATA POINT(DEG.F): 32 FREEZE

---

SECTION STABLE. BETZ TANK CLEAN-OUT CATEGORY

'BHERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES.

BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3)

DUCT: BETZ DTS

--SECTION 4-----------HEALTH HAZARD EFFECTS TE SKIN EFFECTS ** PRIMARY ROUTE OF EXPOSURE HTLY IRRITATING TO THE SKIN YE EFFECTS *"*

MODERATELY IRRITATING TO THE EYES TE RESPIRATORY EFFECTS ***

MISTS/AEROSOLS.MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT ONZC EFFECTS OF OVEREXPOSURE***

PROLONGED OR REPEATED EXPOSURES MAY CAUSE LIVER AND KIDNEY TOXICITY.

ICAL CONDITIONS AGGRAVATED ***

NOT KNOWN PTOMS OF EXPOSURE ***

MAY CAUSE REDNESS OR ITCHING OF SKIN.

---SECTION .5-.-,=..-."--.,-----FIRST AID INSTRUCTIONS IN CONTACT***

REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MINUTES E CONTACT*"*

IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES. IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT HALATION EXPOSURE"*"

REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR.APPLY APPROPRIATE FIRST AID TREATMENT AS ION"**

NECESSARY'E

~

OT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM TE CONTENTS OF STOMACH.1NDUCE VOM1TING BY ONE OF THE STANDARD

.METHODS.IMMEDIATELY CONTACT A PHYSICIAN

---SECTION 6-----------SPILL, DISPOSAL AND FIRE INSTRUCTIONS---------

ILL INSTRUCTIONS"**

VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT. CONTAIN. AND ABSORB ON ABSORBENT MATERIAL.PLACE 1N WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL, SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS.

FLUSH AREA WITH WATER. WET AREA MAY BE SLIPPERY.'PREAD SAND/GRIT.

SPOSAL INSTRUCTIONS***

WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN. ACCORDANCE WITH ANY LOCAL AGREEMENT,A, PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT {AS IS)

INCINERATE OR BURY IN APPROVED LANDFILL

RE EXTINGUISHING INSTRUCTIONS***

FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE). PROPER FIRE EXTINGUISHING MEDIA:

DRY CHEMICAL,CARBON DIOXIDE, FOAM OR WATER

BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3)

F IUCT BETZ DTS

-SECTION 7---"-------SPECIAL PROTECTIVE EQUIPMENT-

'SE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE

.ESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS.

ENTILATION PROTECTION"**

ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS

ECOMMENDED RESPIRATORY PROTECTION***

IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH DUST/MIST FILTERS.

'.ECOMMENDED SKIN PROTECTION***

RUBBER GLOVES WASH OFF AFTER EACH USE.REPLACE AS NECESSARY

'.ECOMMENDED EYE PROTECTION***

SPLASH PROOF CHEMICAL GOGGLES

---

SECTION 8-----------STORAGE AND HANDLING PRECAUTIONS---

'TORAGE INSTRUCTIONS**

KEEP DRUMS & PAILS CLOSED WHEN NOT IN USE.

DO NOT FREEZE. IF FROZEN, THAW AND MIX COMPLETELY PRIOR TO USE iANDLING INSTRUCTIONS"**

NORMAL CHEMICAL HANDLING

%*****%*4*****40****44*******0************************44*44%****

'HIS MSDS WAS WRITTEN TO COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD 44***********************************0'**********4***********

APPENDIX: REGULATORY INFORMATION ONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE

E'TIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE.

BEY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT.

..TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY

..REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT:

'REAT AS 01L SPILL

..RCRA,: IF THIS PRODUCT IS DISCARDED AS A WASTE, THE RCRA HAZARDOUS WASTE

DENTIFICATION NUMBER IS'OT APPLICABLE

..DOT HAZARD/UNQ/ER GUIDES IS: NOT APPLICABLE

..CALIFORNIA SAFE, DRINKING WATER ACT (PROPOSITION 65) MATERIALS: NONE

..SARA SECTION 302 CHEMICALS: NONE

..SARA SECTION 313 CHEMICALS:-NONE

..SARA SECTION 312 HAZARD CLASS: IMMEDIATE(ACUTE)

..MICHIGAN CRITICAL MATERIALS: NONE JFPA/HMIS : HEALTH - 1 ; FIRE " 1 REACTIVITY - 0 SPECIAL - NONE l PE B

BETZ LABORATORIES, INC.

4636 SOMERTON ROAD, TREVOSE, PA 19053 PRODUCT BETZ DTS May 17, 1994 AQUATIC TOXICOLOGY Fathead Minnow 96 Hour Static Screen 0% Mortality: 435 mg/L Daphnia magna 48 Hour Static Screen 0$ Mortality:- 435 mg/L BIODEGRADATION NO DATA AVAILABLE MAMMALIANTOXICOLOGY Oral LD50 RAT: >2,000 MG/KG Note - ESTIMATED VALUE Dermal LD50 RABBIT: >2,000 MG/KG Note - ESTIMATED VALUE

BETZ COPPER-TROL' Cu-1 INH,IBITOR

~ Inhibits corrosion of copper and copper alloys 'ilution. Betz Copper-Trol Cu-1 maybe fed directlyfrom the shipping container or diluted with good quality water

~ Provides long-lasting protection to a convenient feeding strength.

~ Applicable to once-through and recirculating Feed equipment. Mild steel, stainless steel, Polypro-cooling water systems pylene, Polyethylene, PVC, Teflon, and Hypalon tanks, pumps, and piping are compatible with this product.

Chlorine. This product is degraded by chlorine. The DESCRIPTION AND USE level of chlorination directly affects the persistence of the protective film. It should not be fed concurrently with Betz Copper-Trol Cu-1 is a cooling water corrosion in- chlorine. Between applications free chlorine residuals hibitor specifically designed to establish a long-lasting should not routinely exceed 0.4 ppm.

protective film on copper and copper alloys. The pur-chase of this product from Betz provides a license under U.S. Patent 4,744,950. GENERAL PROPERTIES Appearance .................

Density at 70 'F (21 'C)......

brown-black liquid TYPICAL APPLICATIONS 9.86 Ib/gal (1.18 kg/L)

Flash Point (closed cup).......... )200 'F (93 C)

Betz Copper-Trol Cu-1 Is designed for once-through and recirculating cooling water systems. It Is shot fed to es-tablish a film that protects the metal surface for two to six Freeze Point (ASTM))

pH (undilutetg ...............

Specific Gravity at 70'F (21 'C)

-4 'F (-20 '0

.............. 13.5 weeks. This product also indirectly inhibits the comosion of mild steel when that corrosion is due to a galvanic cell Viscosity at 70'F (21 'C) ............. 1.184 37 cP between the mild steel and products of copper corro- STORAGE sion.

Protect Copper-Trol Cu-1 from freezing. If it freezes dur-Ing shipping or storage, mix this product to ensure ho-TREATMENT AND FEEDING REQUIREMENTS mogeneity.

Dosage. Treatment levels of Betz Copper-Trol Cu-1 de- SAFETYPRECAUTIONS pend on many factors specific to each location. Your Betz Industrial representative will establish specific A Material Safety Data Sheet containing detailed infor-guidelines for your system. The normal dosage is 50 mation relative to this product is available upon request.

ppm, based on recirculation rate, applied every two to \

six weeks, depending on film persistence. Betz Copper- PACKAGING INFORMATION Trol Cu-1 should be shot fed to a circulating system or fed continuously for 10 to 15 minutes in a once-through Betz Copper-Trol Cu-1 Is blended as a liquid and is system. available in 55-gal (208-L) bung-type, nonreturnable drums. Approximate net weight is 520 Ib (236 kg) per Feed point. Betz Copper-Trol Cu-1 should be fed to a drum. In addition, Betz Copper-Trol Cu-1 is available un-point in the system where conditions (turbulence, flow der the Betz Point Of Feed and Betz Semi-Bulk Con-patterns, etc.) ensure good mixing of the product In the trol Service Programs for contracted quantities In cer-water to be treated. tain geographic areas.

PFC 487 8810 1988 BET2 IABORATORIES. INC. ALL RIGHTS RESERVED

BETZ LABORATORIES,INC.

4636 SOMERTON ROAD, TREVOSE, PA. 19053 BETZ MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE (HEALTH/ACCIDENT) 800-877-1940'PAGE 1 OF 3)

ODUCT 'OPPER-TROL CU-1 EFFECTIVE DATE 10-22-91 PRINTED: 4-Jun-1992 REVISIONS TO SECTIONS: 1 ODUCT APPLICATION : WATER-BASED CORROSION INHIBITOR.

---SECTION 1-----------HAZARDOUS INGREDIENTS-FORMATION ON PHYSICAL'HAZARDS HEALTH HAZARDS PEL'S 'AND TLV'S FOR SPECIFIC ODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD 1S STED.'REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE D CHRONIC HAZARDS OF THIS FORMULATION. THIS PRODUCT IS SUBJECT TO THE SYLVANIA AND NEW JERSEY WORKER AND COMMUNITY RIGHT TO KNOW LAW.

SODIUM HYDROXIDE(CAUSTIC SODA)".**CASg1310-73-2'CORROSIVE'TOXIC(IF ORALLY INGESTED);PEL:2.0MG/M3;TLV:2.0MG/M3(CEILING).

BUTYL BENZOTRIAZOLE,SODIUM SALT***CAS4118685-34-0;SKIN SENSITIZER; CORROSIVE TO SKIN AND EYES;PEL:NONE;TLV:NONE.

HAZARD INGREDIENTS: WATER (7732-18-5)

--SECTION 2-----------TYPICAL PHYSICAL DATA-------------------------

AS IS (APPROX.) 13.50DOR: MILD

.PT.(DEG.F): >200 P-M(CC) SP.GR.(70F)OR DENSITY: 1.184 OR PRESSURE(mmHG): 22 VAPOR DENSITY(AIR=1).: <1 C cps70F: 37 %SOLUBILITY(WATER)'00 P.RATE: <1 ETHER=1 APPEARANCE: BROWN-BLACK SICAL STATE'IQUID FREEZE POINT(DEG.F): -4

--SECTION 3-----------REACTIVITYDATA BLE.MAY REACT WITH ACIDS.DO NOT CONTAMINATE. BETZ TANK CLEAN-OUT EGORY

'C'MAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES.

BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3)

?RODUCT: COPPER-TROL CU-1

---

SECTION 4---------"-HEALTH HAZARD EFFECTS

%CUTE SKIN EFFECTS *** PRIMARY ROUTE OF EXPOSURE CORROSIVE TO SKIN.SKlN SENSZTIZER

'E EYE EFFECTS ***

CORROSIVE TO THE EYES

%CUTE RESPIRATORY EFFECTS ***

MISTS/AEROSOLS CAUSE IRRITATION TO UPPER RESPIRATORY TRACT HRONIC EFFECTS OF OVEREXPOSURE***

PROLONGED OR REPEATED CONTACT MAY CAUSE TISSUE NECROSIS,DERMATITIS AND/OR SKIN SENSITIZATION.

MEDICAL CONDITIONS AGGRAVATED "**

NOT KNOWN

>YMPTOMS OF EXPOSURE ***

CAUSES SEVERE IRRITATION,BURNS OR TISSUE ULCERATION 'WITH SUBSEQUENT SCARRING.

>RECAUTIONARY STATEMENT BASED ON TESTING RESULTS- ***

MAY BE TOXIC IF ORALLY INGESTED.

---

SECTION 5--"------"--FIRST AID INSTRUCTIONS

>KIN CONTACT*""

REMOVE CLOTHING. WASH AREA WITH LARGE AMOUNTS OF SOAP SOLUTION OR WATER FOR 15 MIN.IMMEDIATELYCONTACT PHYSICIAN

'YE CONTACT*

• IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES. IMMEDIATELY CONTACT A t

PHYSICIAN FOR ADDITIONAL TREATMENT

NHALATZON EXPOSURE*"*

REMOVE VICTIM FROM CONTAMINATED AREA. APPLY NECESSARY FIRST AID TREATMENT. IMMEDIATELY CONTACT A PHYSICXAN.

~STION***

iO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM dO NOT INDUCE VOMITING.IMMEDIATELYCONTACT PHYSICIAN. DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER

.----SECTION 6-----------SPILL, DISPOSAL AND FIRE INSTRUCTIONS---------

>PILL INSTRUCTIONS"**

VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE= ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL, SHOULD BE DETERMINED ZN ACCORDANCE WITH RCRA REGULATIONS.

FLUSH AREA WITH WATER. WET AREA MAY BE SLIPPERY. SPREAD SAND/GRIT.

)ZSPOSAL INSTRUCTIONS"**

WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILXTY OR DISCHARGED UNDER'A NPDES PERMXT PRODUCT(AS IS)-

INCINERATE OR BURY IN APPROVED LANDFILL

'XRE EXTINGUISHING INSTRUCTIONS***

FIREFIGHTERS SHOULD WEAR 'POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE). PROPER FIRE EXTINGUISHING MEDIA:

DRY CHEMICAL,CARBON DIOXIDE,FOAM OR WATER

BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3)

QU~ COPPER-TROL CU-1

-%%'.TION 7-------"---SPECIAL PROTECTIVE EQUIPMENT-PROTECTIVE EQUIPMENT, IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE SPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS.

TXLATION PROTECTION***

ADEQUATE VENTILATION TO 'MAINTAIN AIR CONTAMZNANTS BELOW EXPOSURE LIMITS OMMENDED RESPIRATORY PROTECTION"**

IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH DUST/MIST FILTERS.

OMMENDED SKIN PROTECTION**"

GAUNTLET-TYPE RUBBER GLOVES, CHEMICAL RESISTANT APRON WASH OFF AFTER EACH USE.REPLACE AS- NECESSARY OMMENDED EYE PROTECTION>>>>>>

SPLASH PROOF CHEMICAL GOGGLES. FACE SHIELD

--SECTION 8-----------STORAGE AND HANDLING PRECAUTIONS-RAGE INSTRUCTIONS***

KEEP DRUMS & PAILS CLOSED WHEN NOT IN USE.

DO NOT FREEZE.ZF FROZEN, THAW AND MZX COMPLETELY PRIOR TO USE DLZNG INSTRUCTIONS***

ALKALINE.CORROSIVE(SKIN/EYES).DO NOT MIX WITH ACIDIC MATERIAL.

S MSDS WAS WRITTEN TO COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD APPENDIX: REGULATORY INFORMATION C ENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE

.CTIVE DATE OF THIS MSDS. THIS INFORMATION ZS BELIEVED TO BE ACCURATE.

CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT.

TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT:

GALLONS DUE TO SODIUM HYDROXIDE RCRA: ZF THIS PRODUCT IS DISCARDED AS A WASTE, THE RCRA HAZARDOUS WASTE NTZFICATION NUMBER IS: D002=CORROSZVE(SKIN,PH)

DOT HAZARD/UNQ/ER GUIDEg ZS: CORROSIVE TO SKIN UN1824/060 CALIFORNIA SAFE DRINKING WATER ACT (PROPOSITION 65) MATERIALS'ONE SARA SECTION 302 CHEMICALS: NONE SARA SECTION 313 CHEMICALS: BOONE SARA SECTION 312 HAZARD CLASS: IMMEDIATE(ACUTE) AND DELAYED(CHRONIC)

MICHIGAN CRITICAL MATERIALS: NONE A/HMIS : HEALTH - 3 ; FIRE - 1 REACTIVITY 0 SPECIAL - CORR PE - D,

BETZ LABORATORIES, INC.

4636 SOMERTON ROAD, TREVOSE, PA 19053 PRODUCT'OPPER-TROL CU-1 May 17, 1994 AQUATIC TOXICOLOGY Rainbow Trout 96 Hour Static Acute Bioassay LC50: 28. 1 mg/L No Effect Level: 21 Fathead Minnow 96 Hour Static Acute Bioassay LC50: 60.6 mg/L No Effect Level: 49 Daphnia magna 48 Hour Static Acute Bioassay LC50: 112.5 mg/L No Effect Level: 65 BIODEGRADATION COD (mg/gm): 269 Calculated O'OC (mg/gm): 85 Calculated BOD-5 (mg/gm): 7 Calculated BOD-28 (mg/gm): 7 Calculated Closed Bottle Test 4 Degradation in 28 days: 1 Calculated Zahn-Wellens Test 4 Degradation in 28 days: 13 Calculated MAMMALIANTOXICOLOGY Oral LD50 RAT: 945 MG/KG Note ESTIMATED VALUE Dermal LD50 RABBIT: >5,000 MG/KG Note -. ESTIMATED VALUE

V CQEÃLI'%

Industrial BETZ SLIMICIDE C-68

~ Designed for Air Washers, Recirculating Cooling Slimicide C-68 should be dosed directly Into the sump or Towers and Brewery Pasteurlzers basin or any other location where good distribution can be

~ Effective Against Bacterial, Fungal, and assured.

Algal Fouling In treating air washer systems, BETZ Slimicide C-68 should be added to the air washer sump or chill water sump, to

~ Compatible with BETZ Corrosion Inhibitors insure uniform mixing.

DESCRIPTION AND USE FEED EQUIPMENT BETZ Slimicide C-68 is a liquid biocide that aids in the control Slimicide C-68 is compatible with most plastics. fiber glass.

of bacterial, fungal and algal slimes in evaporative condens-ceramic, and Teflon feed equipment. Also 316 stainless steel ers, heat exchange water systems, commercial and industrial is generally acceptable. Mild steel. copper, and brass lines cooling towers, industrial water scrubbing systems, brewery and equipment should be avoided.

pasteurizers, and air washers.

EATMENT AND FEEDING GENERAL PROPERTIES QUIREMENTS 5-Chio ro-2-Methyl'-Isothiazolin-3 -One ............ 1.15%

DOSAGE Proper treatment levels for BETZ Slimicide C-68 2-Methyl-4-lsothiazolin-3-One.

Inert Ingredients...

0.35%

depend on many factors such as the type of system being 98.50%

treated. the nature and degree of severity of the microbiologi- EPA Registration No.. .........'..... 3876-143 cal problem, system retention time, temperature, pH, and Appearance ................... light yellow to green liquid other operating conditions. Systems which are heavily con- Density (70 'F) ...............8.6 Ib/gal taminated should be cleaned first. BETZ Slimicide C-68 Flash Point (open cup) . ............ )200'F should be applied to the clean system or when slime growth Freeze Point .................. 28'F is first noticed, according to the following schedule. pH (undiluted) ............... 3.5 Specific Gravity (70 'F) . 1.033 For the initial dose, when the system is noticeably fouled, Solubility in Water.... ............... complete apply 148 to 883 ppm Slimicide C-68 (1.26 to 7.46 pounds or Viscosity (70 'F)............... ................. 3.1 cP 19 to 113 fluid ounces of Slimicide C-68 per 1000 gallons of water in the system). Repeat until control is achieved. SAFETYPRECAUTIONS For subsequent doses, when microbial control is evident, add A Material Safety Data Sheet containing detailed information 35 to 219 ppm Slimicide C-68 (0.3 to 1.86 pounds or 4.5 to 28 relative to this product is available upon request.

fluid ounces'of Slimicide C-68 per 1000 gallons of water in the system) weekly or as needed to maintain control. PACKAGING INFORMATION Badly fouled systems must be cleaned before treatment is BETZ Slimicide C-68 is blended as liquid, supplied in 55-begun. gallon, non-returnable white head low density polyethylene insert drums. Approximate net weight 460 lbs. per drum.

FEED POINT In addition, Slimicide C-68 is available under BETZ Point of BETZ Slimicide C-68 can be fed directly from the dfunl of Feed~ Service Program for contracted quantities in certain diluted with water and fed by any suitable feed system. BETZ geographic areas.

PFC 416 8701 iC1987 BETZ LABORATORIES. INC. ALL RIGHTS RESERVED

BETZ LABORATORIES,INC.

4636 SOMERTON ROAD, TREVOSE, PA. 19053 BETZ MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE (HEALTH/ACCIDENT) 800-877-1940 (PAGE 1 OF 3)

PRODUCT : SLIMXCIDE C-68 EFFECTIVE DATE'11-03-9 PRINTED'1-03-92 REVISIONS.TO SECTIONS: APPENDIX PRODUCT APPLICATION:WATER-BASED MICROBIAL CONTROL AGENT.

---

SECTION 1---"=------HAZARDOUS INGREDIENTS INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUT I

AND CHRONIC HAZARDS OF THIS FORMULATION;THIS PRODUCT IS SUBJECT TO THE PENNSYLVANIA AND NEW JERSEY WORKER AND COMMUNITY RIGHT TO KNOW LAW.

MAGNESIUM NITRATE***CASQ 10377-60-3;OXIDIZER;EYE AND SKIN IRRITANT; PEL:NONE;TLV:NONE; 5-CHLORO"2-METHYL-4-ISOTHIAZOLIN-3-ONE***CASO26172-55-4; CORROSIVE;SKIN SENSITIZER;TOXXC(ORAL AND DERMAL EXPOSURE) PEL:NONE TLV:NONE; NOTE-(MFG.SUGGESTED EXPOSURE LXMIT:0.1MG/M3 FOR TOTAL ISOTHIAZOLONES).

NONHAZARD INGREDIENTS: WATER(CASg 7732-18-5)

- ---SECTION 2-----------TYPICAL PHYSICAL DATA PH: AS IS(APPROX.) 3.5 ODOR: AROMATIC FL.PT.(DEG.F):> 200 P-M(CC) '

SP.GR.(70F): 1.033 VAPOR PRESSURE(mmHG):

VISC cps70F:

'0.0 VAPOR DENSITY(AIR=1):

RSOLUBILITY(WATER):

< 1.00 100.0

, 3 EVAP RATE: < 1.00(ETHER=1) APPEARANCE: LIGHT YELLOW TO GREEN PHYSICAL STATE:LIQUID FREEZE POINT(DEG.F): 28.00

---

SECTION 3---,-------"REACTIVITYDATA STABLE.MAY REACT WITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK CLEAN-OUT CATEGORY

'B'HERMAL DECOMPOSTION (DESTRUCTXVE FIRES) YIELDS ELEMENTAL OXIDES.

BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3)

RODUCT : SLIMICIDE C-68

--~SECTION 4---------HEALTH HAZARD EFFECTS J~SKIN EFFECTS *** PRIMARY ROUTE OF EXPOSURE CORROSIVE TO SKINlSKIN SENSITIZER WITH DELAYED ONSET OF SYMPTOMS.

CUTE EYE EFFECTS ***

CORROSIVE TO THE EYES CUTE RESPIRATORY EFFECTS ***

MISTS/AEROSOLS CAUSE IRRITATION TO UPPER RESPIRATORY TRACT HRONZC EFFECTS OF OVEREXPOSURE***

PROLONGED OR REPEATED CONTACT MAY CAUSE TISSUE NECROSIS AND SKIN SENSITIZATION.

EDICAL CONDITIONS AGGRAVATED ***

NOT KNOWN YMPTOMS OF EXPOSURE ***

DIRECT CONTACT WITH SKIN WELL CAUSE SEVERE DELAYED SKIN REACTIONS OR BURNS ZF NOT WASHED OFF IMMEDIATELY-FOLLOWFIRST AID INSTRUCTIONS.

---

SECTION 5-----------FIRST AID ZNSTRUCTIONS-KIN CONTACT ***

REMOVE CLOTHING.WASH AREA WITH LARGE, AMOUNTS OF SOAP SOLUTION OR 'WATER FOR 15 MZN.IMMEDIATELYCONTACT PHYSICIAN YE CONTACT"**

IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELYCONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT NHALATION EXPOSURE***

REMOVE VICTIM FROM CONTAMINATED AREA. APPLY NECESSARY FIRST AID TREATMENT.IMMEDIATELYCONTACT A PHYSICIAN.

NG ON**"

OT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING.IMMEDIATELYCONTACT PHYSICIAN. DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER

---SECTION 6-----------SPILL,DISPOSAL AND FIRE INSTRUCTIONS-----------

PELL INSTRUCTIONS**"

VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBANT MATERIAL.PLACE ZN WASTE DISPOSAL CONTAINER. THE CONTAMINATED ABSORBANT SHOULD BE CONSIDERED A PESTICIDE AND DISPOSED OF IN AN APPROVED PESTICIDE LANDFILL.SEE DECONTAMINATE WITH 104 SOD.BZSULFZTE.USE 15 PARTS TO 1 PART PRODUCT 1SPOSAL INSTRUCTIONS**"*

WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMiTTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS ZS)-

DISPOSE OF IN APPROVED PESTICIDE FACILITY OR ACCORDING TO LABEL

,INSTRUCTIONS IRE EXTINGUISHING INSTRUCTIONS***

FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE). PROPER FIRE EXTINGUISHING MEDIA:

DRY CHEMICAL,CARBON DIOXIDE,FOAM OR WATER

BETZ MATERIAL SAFETY, DATA SHEET (PAGE 3 OF 3)

PRODUCT  : SLIMICXDE C-68

---

SECTION 7-------,--"-SPECIAL PROTECTIVE EQUIPMENT-PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTlON 1910.132-134.

SPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS.

VENTILATiON PROTECTION"**

ADEQUATE VENTILATION TO MAINTAXN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOMMENDED'RESPIRATORY PROTECTION"**

IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE RESPIRATOR WITH ORGANIC VAPOR, ACID GASSES Sc DUST/MIST CARTRIDGES RECOMMENDED SKIN PROTECTION***

GAUNTLET-TYPE NEOPRENE GLOVES, CHEMICAL RESISTANT APRON WASH OFF AFTER EACH USE REPLACE AS NECESSARY.

RECOMMENDED EYE PROTECTION"**

SPLASH PROOF CHEMICAL GOGGLES. FACE SHIELD

---

SECTXON 8---------"-STORAGE AND HANDLING 'PRECAUTIONS-STORAGE INSTRUCTIONS**"

KEEP CONTAINERS CLOSED WHEN NOT IN USE.

DO NOT FREEZE. IF FROZEN, THAW AND Mix COMPLETELY PRIOR TO USE HANDLING INSTRUCTIONS*** ~

CORROSIVE TO SKIN. CORROSIVE TO EYES.

THIS MSDS WAS WRITTEN TO COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD APPENDIX: REGULATORY INFORMATION THE CONTENT OF 'THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE.

ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT.

TSCA: THIS IS AN EPA REGISTERED BIOCIDE AND IS EXEMPT FROM TSCA INVENT RY JIREMENTS

~ ..FIFRA(40CFR):EPA REG.NO.: 3876- 1'43

....USDA FEDERALLY INSPECTED MEAT AND POULTRY PLANTS-AUTHORIZED CAT.:

SEC.G7

...REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT:

NOT APPLICABLE

..:RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE, THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS'D002=CORROSIVE(SKIN)

...DOT 'HAZARD/UNg/ER GUIDEg IS :CORROSIVE TO SKIN/UN1760/560

...CALIFORNIA SAFE DRINKING WATER ACT (PROPOSITION 65) MATERIALS':NONE

...SARA SECTION 302 CHEMICALS:NONE

...SARA SECTION 313 CHEMICALSDJONE

...SARA SECTION 312 HAZARD CLASS:IMMEDIATE(ACUTE);DELAYED(CHRONIC)

...MICHIGAN CRITICAL MATERIALS: NONE NFPA/HMIS : HEALTH - 3; FIRE " 1'EACTIVITY --0; SPECIAL CORR PE D

BETZ LABORATORIES, INC.

4636 SOMERTON ROAD, TREVOSE, PA 19053 r

PRODUCT: SLIMICIDE C-68 May 17, 1994 AQUATIC TOXICOLOGY Rainbow Trout 96 Hour Static Acute Bioassay LC50: 8.7 mg/L No Effect Level: 6.5 Daphnia magna 48 Hour Static Acute Bioassay LC50: 6.6 mg/L No Effect Level: 4.9 Bluegill Sunfish 96 Hour Static Acute Bioassay LC50: 12.1 mg/L No Effect Level: 6.5 BIODEGRADATION COD (mg/gm): 14 Calculated

TOC (mg/gm): 9 Calculated BOD-5 (mg/gm): 0 Calculated BOD-28 (mg/gm): 0 Calculated Closed Bottle Test 8 Degradation in 28 days: 0 Calculated Zahn-Wellens Test 4 Degradation in 28 days: 0 Calculated MAMMALIANTOXICOLOGY Oral LD50 RAT: >5,000 MG/KG Skin Sensit. Patch HUMAN: POSITIVE Non-Ames Mutagenicity: NEGATIVE Teratology  : NEGATIVE Dermal LD50 RABBIT: >2,000 MG/KG Note - ESTIMATED VALUE

BETZ LABORATORIES,INC.

4636 SOMERTON ROAD, TREVOSE, PA. 19053 BETZ MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE (HEALTH/ACCIDENT) 800-877-1940 P

(PAGE 1 OF 3)

PRODUCT  : POWERLINE 3625 EFFECTIVE DATE'05-14-9 PRINTED: 05-14-93 REVISIONS TO SECTIONS: 1 PRODUCT APPLICATION:BIOCIDE

---

SECTION 1-----------HAZARDOUS INGREDIENTS INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT. INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUT I

AND CHRONIC HAZARDS OF THIS FORMULATION.THIS PRODUCT IS SUBJECT TO THE PENNSYLVANIA AND NEW JERSEY WORKER AND COMMUNITY RIGHT TO KNOW LAW.

(C12-16)ALKYL DIMETHYL BENZYL AMMONIUM CHLORIDE***CASO 68424-85-1; CORROSIVE(SKIN AND EYES); PEL:NOT DETERMINED;TLV:NOT DETERMINED ETHYL ALCOHOL(ETHANOL)"**CASO 64-17-5;FLAMMABLE;EYE IRRITANT;MAY CAUSE DEFATTING DERMATITIS, DIZZINESS AND HEADACHE;PEL:1000PPM;TLV:1000PPM NONHAZARD INGREDIENTS: WATER(CASC 7732-18-5)

---

SECTION 2-----------TYPICAL PHYSICAL DATA-PH: AS IS(APPROX.) 8.9 ODOR: MILD FL.PT.(DEG.F): 130 P-M(CC)

VAPOR PRESSURE(1MQHG):

VISC cps70F: 73

'4.0 SP.GR.(70F):

VAPOR 0.965 DENSITY(AIR=1):

%SOLUBILITY(WATER)'00 0

< 1.00 EVAP RATE: > 1.00(ETHER=1) APPKQVQJCE: COLORLESS TO YELLOW PHYSICAL STATE:LIQUID

---

SECTION 3-----------REACTIVITYDATA FREEZE POINT(DEG.F)'7 00 STABLE.MAY REACT WITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK CLEAN-OUT CATEGORY

'B'HERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES.

BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3)

RODUCT : POWERLINE 3625

-~ECTION 4---------HEALTH'HAZARD EFFECTS-A%hKIN EFFECTS *"* PRIMARY ROUTE OF EXPOSURE SEVERE IRRITANT TO THE SKIN. POTENTIAL SKIN SENSITIZER CUTE EYE EFFECTS ***

CORROSIVE TO THE EYES CUTE RESPIRATORY EFFECTS *"*

VAPORS, GASES, MISTS AND/OR AEROSOLS MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT.

RONIC EFFECTS OF OVEREXPOSURE***

REPEATED SKIN CONTACT MAY CAUSE SENSITIZATION.

DICAL CONDITIONS AGGRAVATED ***

NOT KNOWN PTOMS OF EXPOSURE ***

INHALATION OF VAPORS/MISTS/AEROSOLS MAY CAUSE EYE,NOSE, THROAT AND LUNG IRRITATION;SKIN CONTACT MAY CAUSE SEVERE IRRITATION OR BURNS.

ECAUTIONARY STATEMENT BASED ON TESTING RESULTS ***

.MAY BE TOXIC IF ORALLY INGESTED.

---

SECTION 5-----------FIRST AID INSTRUCTIONS----------------

IN CONTACT ***

REMOVE CLOTHING.WASH AREA WITH LARGE AMOUNTS OF SOAP SOLUTION OR WATER FQR 15 MIN.IMMEDIATELYCONTACT PHYSICIAN E CONTACT***

IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES. IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT ATION EXPOSURE***

REMOVE VICTIM FROM CONTAMINATED AREA. APPLY NECESSARY FIRST AZD TREATMENT. IMMEDIATELY CONTACT A PHYSICIAN.

GE QNwwk OT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM D OT INDUCE VOMITING.IMMEDIATELY CONTACT PHYSICIAN. DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER

--SECTION 6-----------SPILL,DISPOSAL AND FIRE INSTRUCTIONS-----------

ILL INSTRUCTIONS***

VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT. CONTAIN AND ABSORB ON ABSORBANT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE CONTAMINATED ABSORBANT SHOULD BE CONSIDERED A PESTICIDE AND DISPOSED OF IN AN APPROVED PESTICIDE LANDFILL.SEE PRODUCT LABEL STORAGE AND DISPOSAL INSTRUCTIONS.

REMOVE IGNITION SOURCES. FLUSH AREA WITH WATER. SPREAD SAND/GRIT, SPOSAL INSTRUCTIONS"***

WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS IS)-

DISPOSE OF IN APPROVED PESTICIDE FACILITY OR ACCORDING TO LABEL INSTRUCTIONS RE EXTINGUISHING INSTRUCTIONS***

FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE). PROPER FIRE EXTINGUISHING MEDIA:

DRY CHEMICAL, CARBON DIOXIDE, FOAM OR WATER

BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3)

L PRODUCT : POWERLZNE 3625

---SECTION 7"----------SPECIAL PROTECTIVE EQUIPMENT-PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134 WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AZR RESPIRATORS. 'ESPIRATORS VENTILATION PROTECTION"*<<

ADEQUATE VENTILATXON TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOMMENDED RESPIRATORY PROTECTION***

IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE 6( DUST/MIST 'PREFILTER RECOMMENDED SKXN PROTECTION**<<

RUBBER GLOVES WASH OFF AFTER EACH USE REPLACE AS NECESSARY.

RECOMMENDED EYE PROTECTION**"

SPLASH PROOF CHEMICAL GOGGLES

-SECTION 8---"-------STORAGE AND HANDLING PRECAUTIONS STORAGE INSTRUCTIONS***

KEEP CONTAINERS CLOSED WHEN NOT IN USE.

. KEEP AWAY FROM FLAMES OR SPARKS. BOND CONTAINERS DURING FILLING OR

- DISCHARGE WHEN PERFORMED AT TEMPERATURES AT OR ABOVE THE PRODUCT FLASH POINT.

HANDLING INSTRUCTIONS**<<

COMBUSTIBLE. DO NOT USE AROUND SPARKS OR FLAMES. BOND CONTAINERS DURING FILLING OR DISCHARGE WHEN PERFORMED AT TEMPERATURES AT OR ABOVE THE PRODUCT FLASH POINT.

THIS MSDS WAS WRITTEN TO COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD APPENDIX: REGULATORY INFORMATION T>P. CONTENT OF THIS APPENDIX REPRESENTS INFORMATXON KNOWN TO BETZ ON THE E ECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE.

Ax.r CHANGES IN REGULATIONS WILL RESULT ZN UPDATED VERSIONS OF THIS DOCUMENT.

..".TSCA: THIS IS AN EPA REGISTERED BIOCIDE AND IS EXEMPT FROM TSCA INVENTORY REQUIREMENTS

...FIFRA(40CFR):EPA REG.NO.: 10324-42-3876

...REPORTABLE QUANTITY(RQ) FOR UNDXLUTED PRODUCT:

NOT APPLICABLE

...RCRA: ZF THIS PRODUCT IS DISCARDED AS A WASTE, THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS:D001=IGNITABLE

...DOT HAZARD/UNC/ER GUIDES IS :COMBUSTIBLE LIQUID/NA1993/027

...CALIFORNIA SAFE DRINKING WATER ACT (PROPOSITION 65) MATERIALS:NONE

...SARA SECTION 302 CHEMICALS:NONE

...SARA SECTION 313 CHEMICALS:NONE

...SARA SECTION 312 HAZARD CLASS:IMMEDIATE(ACUTE);DELAYED(CHRONIC);FIRE

...MICHIGAN CRITICAL MATERIALS: NONE NFPA/HMIS : HEALTH - 3; FIRE - 2'EACTXVITY - O'PECIAL,- NONE; PE - B

ay 18, 1994 BETZ LABORATORIES, INC.

4636 SOMERTON ROAD, TREVOSE, PA. 19053 Product: Powerline 3625 AQUATICTOXICOLOGY Fresh Water'Or anisms S ecies Da hnia ma na 'S Test Conditions LC50*

Hour Flow-Throu h 0.04m No Effect Level 0.025 m Fathead Minnow 96 Hour Flow-Throu h 0.73 m 0.25 m Rainbow Trout 96 Hour Flow-Throu h 2.0 m 1.0 m

• These LC50 values represent analytically measured levels arine Or anisms ecies Test Conditions LC50*

M sid Sh'rim 96 Hour Flow-Throu h 0.16 m Inland Silverside 96 Hour Flow-Throu h 0.62 m Sheapshead 96 Hour Flow-Through 1.76 mg/l Minnow

• These LC50 values represent analytically measured levels MAMMALIANTOXICOLOGY Oral LD50 RAT: 445 mg/kg Note:=Estimated value based on test results on active ingredient Dermal LD50 Rabbit: >1,800 mg/kg Note: Estimated value based on test results on active ingredient

AOUSSELB CORPORATI

.5Q- h)

ROUSSEL BIO CORPORATION 170 BEAVER BROOK ROAD (ay) $

LINCOLN PARK, NZ 07035 Emergency Telephone 800-331-2867 FLAMMABILITY (RED)

NFPA Designation 704 DEGREE OF HAZARD 4=EXTREME .HEALTH 3=HIGH (BLUE) (YELLOW) 2=MODERATE 1=SLIGHT 0=INSIGNIFICANT SPECIAL HAZARD MATERIAL SAFETY DATA SHEET DATE May 15, 199 Section I- Product Identification Product Name: . Nusyn-Noxfish Fish Toxicant EPA Reg. No: 432-550 Chemical Name: (R)-1,2-dihydro-8,9-dimethoxy-2-(l-methylethenyl)[1 benzopyrano[3,4 b]furo[2,3-h][1]benzopyran-6,12 dione (9C1)

Common Name: Rotenone Molecular Formula: Cp3H~~06 Molecular Weight: 394.4 Section II - Precautionary Statement Health:

DANGER~ KEEP OUT OF REACH OF CHILDREN. Fatal if inhaled. Do not breathe spray mist. Wear an approved pesticide respirator wher.

mixing or applying as a spray. May be fatal if swallowed.

substantial but- temporary eye irritation. Do not get in eyes, Cause on skin or on clothing. Wear protective goggles, faceshield, oz safety glasses. Wash thoroughly with soap and water after handling.

Remove contaminated clothing and wash before reuse.

Environment:

This product is extremely toxic to fish. Fish kills are expected at recommended rates. Consult your State Fish and Game Agency befor~

applying this product to public waters to determine if a permit ic needed for such an application. Do not contaminate untreated water when disposing of equipment washwaters.

Page 1 of t

( XVI I

EPA Reg No.: 432-550 Date:May '16, 1990 Do not decontaminate personnel or equipment, or handle broken packages or containers without protective equipment as specified in the Exposure Control Section.

Decontaminate emergency personnel with soap and water before leaving the fire area.

Avoid'reathing dusts, vapors and fumes from burning materials. Control run-off water if water enters a drainage system, advise the authorities downstream.

Section VZ - Reactivity Data Stability: Stable Polymerization: Will not occur Conditions to avoid: Keep away from excessive heat and any sources of ignition.

Incompatible Materials: Strong oxidizing and reducing agents.

Hazardous Decomposition Products: Carbon monoxide and/or carbon dioxide.

Section VZZ - Health Hazard Information Eye contact: Moderately irritating to the eye Skin contact: Slightly irritating to the skin Skin Absorption: LD50 (rabbit) >2020 mg/kg Inhalat'n: 4 Hour LC50 (rat) - 0.049 mg/l Ingestion: LD50 (rat) 561 mg/kg TOXICITY DATA AND EFFECTS OF THE ACTZVE INGREDIENT:

Mutagenicity:

A battery o f mutagenicity studies designed to detect gene mutations, chromosomal aberrations and mitotic recombination or mitotic gene conversation were negative and revealed no potential for rotenone to induce mutagenic changes in vivo or in vitro.

Teratogenicity:

No teratogenic or fetotoxic effects were found when tested in both rats and mice.

Carcinogenicity:

No evidence of oncogenicity was observed in chronic feeding studies with mice, rats and hamsters.

Page 3 of 6

EPA Reg.No.: 432-550 Date: May 15,.1990 EMERGENCY AND FIRST AZD PROCEDURES:

If on skin: Wash with plenty of soap and water. Get medical attention if irritation persists.

If in eyes: Flush with plenty of water. Get medical attention if irritation persists.

If ingested: Call a physician or Poison Control Center. promptly drink a large quantity of milk, egg whites, or gelatin solution. If these are not available, drink large quantities of water. -Avoid alcohol. Do not induce vomiting. Get medical attention immediately. Never give anything by mouth .to an unconscious person.

Zf inhaled: Remove to fresh air. If breathing is difficult or if any discomfort persists, attention. If breathing has obtain stopped, medical give artifical respiration, preferably mouth to mouth.

Get medical attention immediately.

NOTES TO PHYSICIAN>>

This product is highly toxic when spray mist is inhaled, moderately toxic by the oral route and slightly toxic by the dermal route.

This product causes substantial but reversible eye irritation.

Initial treatment is -removal of exposure by 'washing, emesis or lavage and is followed by symptomatic and supportive care.

MEDICAL CONDITION AGGRAVATED BY OVEREXPOSURE>>

A knowledge of the available toxicology information and of the physical and chemical properties of the material" suggest that overexposure is unlikely to aggravate existing medical conditions.

Section VIII - Exposure Control Methods During formulation of this product, use the following recommended industrial hygiene practices:

Wear an approved pesticide respirator.

Wear chemical splash goggles or face shield to prevent contact with the eyes.

Page 4 of

ZPA Reg.No.: 432-550 Date: May 15, 1990 Wear rubber gloves and apron to prevent contact with the skin. Wash thoroughly with soap and water after handling. Remove contaminated clothing and wash before reuse.

For end-users, refer to product label for personal protective clothing/equipment.

Section IX - Spill or Leak Procedures Absorb with an inert material such as clay or sawdust. Place in an approved closed container for disposal.

Waste Disposal: Dispose in accord with local, state and federal regulations.

Section X - Special Precautions Handling and Storage: Do not contaminate water, food or feed by storage or disposal. Store in a secure, dry, well-ventilated separated room, building or covered area.

Not, for use or storage in or around the home.

Keep away from sources of ignition and protect from exposure to fire and heat.

Segregate from incompatible materials listed in the Reactivity Data Section.

Because of this material's flash point, areas containing this material should conform to the codes, such as NFPA 30 and NFPA 70, governing Class III for combustible liquids.

Section XZ - Additional Regulatory Information SARA Title IIZ Data Section 311 and.312 Hazard categories Immediate Health Hazard Y Delayed Health Hazard N Fire Hazard Y Reactive Hazard N Sudden pressure Release Hazard - N Page 5 of 6

ZM, Reg.No.: 432-550 Date: May 15, 1990 Section 302 Extremely Hazardous Substances None Section 313 Toxic Chemicals - None CERCLA Reportable Quantity: None This material is not listed as a carcinogen/potential carcinogen by XARC, OSHA or NTP.

Hazardous Materials Identification System (HMIS) Rating.

Health 3 Flammability 2 Reactivity 1 Personal Protection J This information and statements herein are believed to be reliab but are not to be construed as a warranty or representation for which we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular purpose of any information or products referred to iierein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE ZS HADE.

Page 6 of 6

NUSYN-NOXFISH' IJ7 SQ FISH TOXICANT gu sgv-4wFI58 SYNERGIZED ROTENONE LIQUID - EMUI.SIFIABLE ACTIVE INGREDIENTS: TIONARV STATEMENTS Rotenone ..........................".".."."" ". ... 2.5% w/w DS MANS 5 DOMESTIC ANIMAI.S Other cube extractlves.... ... 5.0% WARNING Plperonyl Butoxlde, Technical'....

INERT INGREDIENTS: .

. 2.5% I In, fatal n clo liow

.W r pr c

t e ey nlury. Causes skin lrrltatlon. Do not gel ln eyes, on glee, taceshleld, or safely glasses. Wash thoroughly

.. 90.0% I Ilh so a w e fte ~ move contaminated clothing and wash before reuse.

100.0% /g o fla,s YIRONMENTALHAZARDS ponds except under use condlllons. Oo not contamlnale water by cl e or disposal ol wastes.

'Equlffalent to 2.6% (Butylcarbltyl] IB-propylplparonyl) eth a d g PHYSICAL HAZARDS related compounds om bl xlure as oint of this formulallonle f f5'F. DO NOT USE OR STORE NEAR T R PE "Penlck-Blo UCI.AF Corporation T e ar T MENT OF PRACTICAl; TREATMENT

,A swell: o n t ce mltlng. Call a physlclan or Poison Control Center. Drink pr ly ala ~ ua It of ilk, hltes, gelatin solution, or IIthese are nof available drink Iar tldpgltle o at Avo alc . Get medical allenllon.

ttEEP ODT OF BEACH F gill D tt Itin eLAu I pie gf t r elmedlcalattenllon.

WARNI 8~ on n: W h h Ien Bp p and water. Get medical attention.

SEE SIDE PANEL FOR ADD PRECAUTIONARY STATENALNTC il A, ~ la I

DIRECTlONS fOR USE n of F deraf law to use this product!n a manner Inconsistent with Its labeling.

STORAGE 8EDISPOSAI.

Oo not contaminate water, food, or feed by slorage or disposal.

EPA Est.: See Lot No. For Correlation PESTICIDE DISPOSAL Pestlclde wastes are loxtc. Iniproper disposal of excess pestlclde, spray m'Ixture, or rlnsale ls ~ vlolatlon of Federal Law. If these wastes cannot be disposed of by use EPA Rey. No. 432-550 G 42545-MO-1 P-3/31/BB according to label Instructions, contact your State Pestlclde or Environmental Control Agency H'5905-AR-1 or Ihe Hassrdous Waste representative at the nearest EPA Regional Office for guidance.

NET CONTENTS: GALLONS CONTAINER DISPOSAL Triple rinse (or equivalent). Then offer for recycllng or recondltlonlng, or puncture and dispose ot ln a sanitary landfill, or by other procedures approved by State and Local authortttes.

PENlCK-810 UCLAF CQRPORATl0$ f DlRECTIONS OR tlSE Continued on reverse olde.

t P.O. Box 9059 1050 Wall Street West. Lyndhurst, New Jersey 07071 USA

DIRECTIONS FOB USE (Gontintted) EPA REG. No 432-550 GENERAL INFORMATION PBE-MIXING AND METHOD OF APPLICATION: Pre-mix with water at a rate of Nusyn-Noxflsh Is a specially formulated product containing synerglzed one gallon Nusyn-Noxflsh to 10 gal. of water. Uniformly apply over water rolenone, to be used ln fisheries management for the eradication of fish surface or bubble through underwater lines.

from takes, streams and reservoirs. Nusyn-Noxtlsh willnot solidify nor show DETOXIFICATION: Nusyn-Noxflsh treated waters detoxify under natural any separation at temperatures down to 40'F and Is stable for a minimum of conditions wlthln 1 week to 1 month depending upon temperatures, one year when stored In sealed drums at 70'F.-

alkalinity, etc. Rapid detoxltlcatlon can be accomplished by adding chlorine or potassium permanganate to the water at the same rate as Nusyn-Noxflsh DIRECTIONS FOB USE In parts per million, plus enough additional to meet the chlorine demand of Apply this product only as specified on this label. Nusyn-Noxflsh ls the untreated water.

registered for use by or under permit from and after consultation wllh State REMOVALOF TASTE AND ODOR: Nusyn-Nox fish treated waters do not retain and Federal Fish and Wildlife Agencies.

a detectable taste or odor for more than a few days to a maximum of one month. Taste and odor can be removed Immediately by treatment with FOR USE IN PONDS, LAKES AND RESERVOIRS activated charcoal at a rate of 30 ppm for each 1 ppm Nusyn-Noxfish SPECIAL INSTRUCTIONS: Water alkalinity, temperature, and turbidity are remaining. (NOTE: As Nusyn-Nox fish detoxlf les, less charcoal ls required.)

usually different ln each type water. Because these factors change the RESTOCKING AFTER TREATMENT: Walt 2 to 4 weeks after treatment. Place a effectiveness of plsclcldes, consult your State Game 8 Fish representative sample of fish to be stocked ln wire cages ln the coolest part of the treated before use to determine the correct concentration of this product needed for waters. It the fish are not killed within 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />, the water may be restocked.

the type killdesired. Nusyn-Noxflsh dlsperses readily In water both laterally FOR USE IN STREAMS, IMMEDIATELYABOVE PONDS, LAKES 08 RESERVOIRS:

and vertically, and will penetrate below the thermocllne ln thermally Allow Nusyn-'Noxflsh to drain from drum directly Into center of stream at a stratified bodies of water. rate of.S5-1.7cc per minute for each cubic foot ot water tlowlng per second COMPUTATION OF ACRE-FEET:AN,ACRE-FOOT ls a unit of volume of a ln the stream (0.5-1.0 part per million Nusyn-Noxflsh or.0.0125-0.025 ppm body ot water having the area of one acre and a depth of one foot. To rotenone).

determine acre feet tn a given body ot water, make a series of transects across lhe water body taking depths with a measured pole or weighted llne.

Add the soundings and divide by the number made to determine the average depth. Multiplythis average depth by the total surface to find the acre feet to be treated. If number of surface acres Is unknown, contact your local Soll Conservation Service, which can determine this from aerial photographs.

AMOUNTOF NUSYN-NOXFISII NEEDED FOH SPECIFIC USES: To determine the approximate number of gallons of Nusyn-Noxflsh (2.54/o Rotenone) needed, find your "Type of Use"In the first column of the Table below and IMPORTANT-HEADBEFORE PURCHASE 08 USE:

then divide the corresponding numbers In the third column, "Number of WARRANTYSTATEMENT Acre-Feet Covered by One Gallon", Into the number of acre-feet ln your Our recommendatlons for the use of this product are based upon tests body of water. believed to be reliable. The use of this product being beyond the control of the manufacturer, no guarantee, expressed or Implied, Is made as to the PARTS PER MILlloli Number of Acre-Feet SF. of 2.5% Rotenane Covered b One Ration eflects of such or the results to be obtained If not used In accordance with directions or established safe practice. The buyer tnust assume all t

Selective Treatment .20 lo d5 15 to 12 Normal pond uaa 1.0 to 2.0 S.o to 1.5 responslblllty, including InJury or damage, resulting from Its misuse as such, Remove bullhaada or carp 2.0 to i.o 1.5 to.75 or'Ih comblnatlon with other materials.'

Remove bullhea r carp In rich orphan de 4.0 to S.o .T5 to.3S Prelmpoundmen eatment above dam e.O to1O.O .50 to.30

MAY-28-1994 18: 25 SEPRO CG~RAT ION 317 5%I 8288 P.8M'ePAO Post-It brandfaxtransmittalmemo7671 ~orpaycs ~

5Q NCeh Men Jinn ~t. Svla a V Can4. tncl~ina 46032 CW P~<317)Nb82N iax:Ol7lM&<<ze>

SONXR"'RP Herbicide Dept.

(o -7744-7as 3/7-570 HAZARDOUS DECOMPOSITION PRODUCTS: Will emit toxic vapors as it burns.

]-Methyl-3-phenyl.5-(3-(trifluoromethyl)phenyl)-. HAZARDOUS POLYMERIZATION:Does not occur.

4(1H)-pyridinone (Fluridone)

GAS¹ 059756~4. "

. ~ ..........5% ~ ~ ~ ~ + ~ ~

Other Ingredients 95 This document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR ENVIRONNIENTAI DATA: Follow use directions 1910.1200). In addition, other substances not carefully so as to minimize adverse effects on nontar-

'Hazardous'er this OSHA Standard may be listed. get organisms. IN ORDER TO AVOID IMPACT ON Where proprietary ingredient shows. the identity may THREATENEO OR ENDANGERED AQUATIC PIANT be made available as provided in this standard. QR ANIMALSPECIES, USERS MUST CONSULT THEIR STATE FISH AND GAME AGENCY OR THE U.S. FISH AND WILDLIFESERVICE BEFORE MAK-ING APPLICATIONS. Oo not contaminate water by cleaning of equipment or disposal of wastes. Trees BOILING POINT: Not applicable and shrubs growing in water treated with SONAR VAP. PRESS: Not applicable be injured. Do not apply in tidewater or bractcish water.

may VAP. DENSITY: Not applicable

~

Do not apply in lakes. ponds, or other, bodies of water SOL IN WATER: Insoluble, but disintegrates in water where crayfish farming is performed.

~

SP. GRAVITY;Not applicable

~

ACTION TO TAKE FOR SPILLS: Contain and sweep up material of small spills and dispose as waste. Large APPEARANCE: Dark gray to dark brown pellet spills report to CHEMTREC and OowElanco for assis-ODOR: Faint musty odor tance. Prevent runoff.

pH: (aqueous 50/50) 3.5 DISPOSAL METHOD: Do not contaminate water, food or feed by storage or disposal. Wastes resulting from

~, s ( ~ 9 ~

the use of this product may be disposed of at an approved waste disposal facility in accordance with FLASH POINT: Not applicable applicable regulations.

METHOD USED: Not applicable FLAMMABLELIMITS:

LFL: Not applicable ACUTE EXPOSURE (SONAR SRP)

UFL: Not applicable Eyes - Rabbit. irritant AUTO.IGNITION TEMPERATURE: No ignition up to Skin - Rabbit, 2000 mgkg, no deaths or toxicity, nonir-1382'F. 750'C ritant EXTINGUISHING MEDIA: Use water, CO2 or dry inhalation - This formulation is not considered to be an chemicals. inhalation hazard due to pelleted nature of material Ingestion - Rat. 500 mgh<g, no deaths or toxicity FIRE AND EXPLOSION HAZARDS: Will emit toxic Sensitization - This formulation was not tested.

vaoors as it burns. Fluridone technical is not a contact sensilizer in guinea FIRE-FIGHTING EQUIPMENT: Wear full protective pigs.

clothing and use self~ontained breathing apparatus. CHRONIC EXPOSURE (Fluridone Technical) The fol-lowing effects were reported in chronic, teratogenic, and reproductive toxicity studies in laboratory animals where experimental dosage levels and durations of STABILITY:(CONDITIONS TO AVOID) None known exposure were far in excess of those likely to occur in NCOMPATIBILITY:(SPECIFIC MATERIALSTO 'umans.

VOID) None known Chronic Toxicity - Decreased survival in lifetime feed-ing study. Increased liver enzyme activity. liver weight, liver cell size, and microscopic liver cell changes.

,. NAY-28-1994 l8I 25 SEPRQ I.m~~t Iu~ ~ ~

$ 2..9(p . Emergarfcy Phone: 517-63~ ..

SsPAS General Phone: 1<00-352~

11550 North Meridian Street. Suite 00 EPA Beg. Number: 62719-123 Clnncf. Indftim <432 Effective Data: January 27, 1992 Pftt~ fal7I StttHQfr'aX GI 7) 5SIHQtta Product Code: 20169 SONAR" SRP Herbicide MSDS Number: 004001 DowElanco - Indianapolis, IN 46266 Increased kidney weights, and microscopic kidney cell SKIN PROTECTION: No precautions other than nor-changes. Increased serum enzyme levels. mal work clothing should be needed.

Teratology 8 Reproduction - Not teratogenic. Fetal EYE PROTECTION: Use safety glasses.

deaths at maternally toxic doses. No effects on repro-ductive performance.

Mutagenicity - Not mutagenic in either bacterial or mammalian cells.

SPECIAL PRECAUTIONS TO BE TAKEN IN HAN-Carcinogenicity - Not listed as a carcinogen or poten-tial carcinogen by IARC, NCI/NTP, OSHA. or ACGIH. DLING AND STORAGE: Keep out of reach of chil-Not considered to be carcinogenic in lifetime feeding dren. Harmful if swailowed, absorbed through skin, or if inhaled. Avoid breathing of dust or contact with skin, studies.

eyes, or clothing. Wash thoroughly with soap and SIGNS AND SYMPTOMS OF EXPOSURE: There are water after handling. Wash exposed clothing before no reports of significant exposure to SONAR SRP. In reuse.

two reports of children swimming in water treated with NATIONALFIRE PROTECTION ASSOCIATION (NFPA 704)

SONAR, no symptoms developed.

(4=Extreme; 3=High; 2=Moderate; 1&light;O=lnsignlTlcant)

PRIMARY ROUTES OF ENTRY: Skin and inhalation. Health: 2 Rammability: 1 Reactivity: 0 SHIPPING REQUIREMENTS DOT Hazard Class.

~ ~

Not regulated.

EYES: Flush eyes with plenty of water and call a MSDS STATUS: Revised 1/92, Section 8 physician if irritation develops.

SION: Wash exposed areas with plenty of soap and water. Wash all contaminated clothing before reuse.

(Nof meant Io be affqncfusiva Selected regulations rapresanfad).

Call a physician if irritation develops. NOTICE:-The information herein is presented in good faith and INGESTION: Do not Induce vomiting. Call a physician believed Io be accurate as of the effacbva date shown abovo.

However, no warranty, express or implied, is given. Ragulafaty or Poison Control Center. If available, administer acti- requiremants are subject to change and may differ from one loca-vated charcoal (6-8 heaping teaspoonfuls) with a large bon fo another, it is the buyer's responsibility to ensue that Its quantity of water. Do not give anything by mouth to an activities comply with federal, state or provincial, arid beat laws.

unconscious person. Immediately transport to a med- The following specific information is made for the purpose of corn ical care facility and see a physician. plying with numerous federal, state or provincial. and Iacal laws and regulations. See MSD Sheet for health and safety iffformatierf.

INHALATION:If discomfort occurs, move individual to fresh air. If breathing difficultyoccurs. get medical SARA HAZARD CATEGORY: This product has been attention. If not breathing, provide cardiopulmonary reviewed according to the EPA Hazard Categories" resuscitation assistance and get medical attention promulgated under Sections 311 and 312 of the immediately. Superfund Amendment and Reauthorization Act of 1986 (SARA Title ill) and is considered, under applica-MEDICALCONDITIONS GENERALLY AGGRAVAT- ble definitions, to meet the following categories:

ED BY EXPOSURE: No information available. An immediate health hazard EXPOSURE GUIDELINE(S): PEL and TLV not estab-lished.

VENTILATION:Good general ventilation should be sufficient for most conditions.

RESPIRATORY PROTECTION: No respiratory protec-,

tion should be'needed when used in accordance with The Ittfamtation Herein Is Given In Good Faith.

label instructions.

But Na Warranty. Expraaa Or Implied, Is Made.

Consult The Dowafattco Company For Fuffher Ittfotma&n.~

TOTA P. 82

BETZ LABORATORIES,INC.

4636 SOMERTON ROAD, TREVOSE, PA. 19053 BETZ MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE (HEALTH/ACCIDENT) 800-877-1940 (PAGE 1 OF 3)

ODUCT : POWERLINE PPL04 EFFECTIVE DATE:04-02-93 PRINTED'4-02-93 REVISIONS TO SECTIONS: ;EDIT:PROD.APP.

ODUCT APPLICATION:WATER-BASED CORROSION INHIBITOR.

---

SECTION 1-----""-"--HAZARDOUS INGREDIENTS-FORMATION ON PHYSICAL HAZARDSiHEALTH HAZARDS'EL'S AND TLV'S FOR SPECIFIC ODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD IS STED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE D CHRONIC HAZARDS OF THIS FORMULATION.THIS PRODUCT IS SUBJECT TO THE "NNSYLVANIAAND NEW JERSEY WORKER AND COMMUNITY RIGHT TO KNOW LAW.

BENZOTRIAZOLE,METHYL,SODIUM SALT***CASO 64665-57-2; CORROSIVE TO EYES AND SKIN;TOXIC(ORAL INGESTION); PEL:NOT DETERMINED;TLV:NOT DETERMINED NHAZARD INGREDIENTS 'ATER (CASO 7732-18-5)

- --SECTION 2-----------TYPICAL PHYSICAL DATA AS IS(APPROX.) 13.0 ODOR: MILD=

.PT.(DEG.F):> 200 SETA(CC) SP.GR.(70F): 1.192 POR PRESSURE(mmHG): ND VAPOR DENSITY(AIR=1): ND SC cps70F: 78 %SOLUBILITY(WATER): 100.0 u'AP RATE: < 1.00(ETHER=1) APPE2Q%NCE: AMBER

".YSICAL STATE:LIQUID FREEZE POINT(DEG.F): -25.00

- --SECTION 3-----------REACTIVITYDATA

<ABLE.MAY REACT WITH ACIDS.DO NOT CONTAMINATE. BETZ TANK CLEAN-OUT TEGORY

'C'RMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES.

BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3)

PRODUCT  : POWERLINE PPL04

---

SECTION 4---------HEALTH HAZARD EFFECTS-tTE SKIN EFFECTS *** PRIMARY ROUTE OF EXPOSURE CORROSIVE TO SKIN ACUTE EYE EFFECTS ***

CORROSIVE TO THE EYES ACUTE RESPIRATORY EFFECTS "*"

MISTS/AEROSOLS CAUSE IRRITATION TO UPPER RESPIRATORY TRACT CHRONIC EFFECTS OF OVEREXPOSURE***

PROLONGED OR REPEATED CONTACT MAY CAUSE TISSUE NECROSIS.

MEDICAL CONDITIONS AGGRAVATED ***

NOT KNOWN SYMPTOMS OF EXPOSURE ***

CAUSES REDNESS=OR ITCHING OF SKIN, POSSIBLY LEADING TO BURNS, DEPENDENT ON LENGTH OF EXPOSURE; PRECAUTIONARY STATEMENT BASED ON TESTING RESULTS ***

MAY BE TOXIC IF ORALLY INGESTED.

---

SECTION 5-----------FIRST AID INSTRUCTIONS SKIN CONTACT *~*

REMOVE CLOTHING. WASH AREA WITH LARGE AMOUNTS OF SOAP SOLUTION OR WATER FO 15 MZN.IMMEDIATELYCONTACT PHYSICIAN EYE CONTACT~**

IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES. IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE***

REMOVE VICTIM FROM CONTAMINATED AREA. APPLY NECESSARY FIRST AID TREATMENT. IMMEDIATELY CONTACT A PHYSICIAN.

INGESTION"**

DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING.IMMEDIATELYCONTACT PHYSICIAN. DILUTE CONTENT STOMACH USING 3-4 GLASSES MILK OR WATER

---

SECTION 6-----------SPILL,DISPOSAL AND FIRE INSTRUCTIONS-----------

SPILL INSTRUCTIONS***

VENTILATE,AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS.

FLUSH AREA WITH WATER. WET AREA MAY BE SLIPPERY. SPREAD SAND/GRIT.

DISPOSAL INSTRUCTIONS*",**

WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS ZS)-

INCINERATE OR BURY IN 'APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS***

FZREFZGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE). PROPER FIRE EXTINGUISHING MEDIA:.

DRY CHEMICAL,CARBON DIOXIDE,FOAM OR WATER

BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3)

ODUCT : POWERLINE PPL04 CTION 7-----------SPECIAL PROTECTIVE EQUIPMENT-TECTZVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134.USE

~P TORS WITHIN USE LIMITATIONS OR ELSE USE SUPPL1ED AIR RESPIRATORS.

"NTILATION PROTECTION***

ADEQUATE VENTILATION

-COMMENDED RESPIRATORY PROTECTION*"*

IF VENTILATION ZS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH DUST/MIST FILTERS.

"COMMENDED SKIN PROTECTION" GAUNTLET-TYPE RUBBER GLOVES, CHEMICAL RESISTANT APRON WASH OFF AFTER EACH USE REPLACE AS NECESSARY.

-COMMENDED EYE PROTECTION***

SPLASH PROOF CHEMICAL GOGGLES. FACE SHIELD

---

SECTION 8-----------STORAGE AND HANDLING PRECAUTIONS ORAGE INSTRUCTIONS**"

KEEP CONTAINERS CLOSED WHEN NOT ZN USE.

STORE IN COOL VENTZLATED LOCATION. STORE AWAY FROM OXIDIZERS DLING INSTRUCTIONS***

ALKALINE.CORROSIVE(SKIN/EYES).DO NOT MIX WITH ACIDIC MATERIAL.

• 4****%*%**g%******4*4*4'*%******************%***4***0'0'**4'**********

ZS MSDS WAS WRITTEN.TO COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD

• 4********%**************A**************4'*%**4*4*0'4'4******0'***4***

APPENDIX: REGULATORY INFORMATION E CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE FECTZVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE.

CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT.

ALL COMPONENTS OF THIS PRODUCT ARE LISTED ZN THE TSCA INVENTORY REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT:

NOT APPLICABLE

..RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE, THE RCRA HAZARDOUS WASTE ENTIFICATION NUMBER IS:D002=CORROSZVE(SKIN;PH)

..DOT HAZARD/UN5/ER GUIDEg IS :CORROSIVE TO SKIN/UN1760/060

..CALIFORNIA SAFE DRINKING WATER ACT (PROPOSITION 65) MATERIALS:NONE

..SARA SECTION 302 CHEMICALS:NONE

..SARA SECTION 313 CHEMICALS:NONE

..SARA SECTION 312 HAZARD CLASS:IMMEDIATE(ACUTE) DELAYED(CHRONIC)

-.MICHIGAN CRITICAL MATERIALS

- NONE FPA/HMIS : HEALTH 3; FIRE - 1; REACTIVITY - 0; SPECIAL CORR; PE D

BETZ LABORATORIES, INC.

4636 SOMERTON ROAD, TREVOSE, PA 19053 PRODUCT:'OWERLINE PPL04 May 17, 1994 AQUATIC TOXICOLOGY Daphnia magna 48 Hour Static Acute Bioassay LC50: 311. 2 mg/L No Effect Level: 210 Bluegill Sunfish 96 Hour Static Acute Bioassay LC50: 109.3 mg/L No Effect Level: 42 BIODEGRADATION COD (mg/gm): 790 TOC (mg/gm): 259 BOD-5 (mg/gm): 4 BOD-28 (mg/gm): 22 Closed Bottle Test 4 Degradation in 28 days: 6 Zahn-Wellens Test 4 Degradation in 28 days: 9 MAMMALIANTOXICOLOGY Oral LD50 RAT: >1,400 MG/KG Note ESTIMATED VALUE Dermal LD50 RABBIT: >4,500 MG/KG Note - ESTIMATED VALUE

lor2er92 14:20 3 482 7377 PMCSG KUUKTIYG Ql 003 MAmZrALSAFErr DATASHEET COBRATE~ ~-5~

0 MANVPACZKJRER: PMC SPECIALTIES GROUP ADDRESS: 50I Muxzay Road.

Cincinnati, OH 45217 EMERGENCY %%~HONE: (513) 242-3300 FOR 'IRAlNSPORTA'HON EMERGENCY: (800) 424-9300 CHEMICALNAhK AND SYNONYMS: Sodium Tolyltriazolc,50% Water Solution ABRADE NAMES AND SYNONYMS: COBRA'IEC'T-50S CHEMXCALFAhGLY: Tziazole FORM%A: QHg4;Na

'AS REGEXRY NUMBER: 64665-57-2 DOT SHIPPING: Caustic AlkaliLiquid N.OS - UN1719 PRODUCI'UMBEB. XISWT7440 SECIXON II Tolyltxiazole, sodium salt 50 None Established.

Sodium Hydrazide,'AS No. 1310-73-'2 <09 TWA=Zmg/m N P DA BOILINGPOINT: 100 C FREEZZNG POINT: -8' SPECIFIC GRAVXEY: 1.19 O25 C 20':

~

VAPOR PRESKilRE AX 0.04 mm VAPOR DEN')TKY: Not Applicable SOLUBIL'HTIN WAXER: Miscible in all proportions 9o VOLATiLESBY VOLUME 50% as water EVAPORATION RATE:

(Bntyl Acetate ~ I) Not Applicable APPEARANCE AND ODOR: Clear, yegg to amber solution, nearly odorless, pH= 130

10/2B/82 14:21 Q'513 482 7377 PPCSG KQKETING fibo SECTION IV FfRE AND ION DA EIASH POINT= Not Applicable AUTOIGNHION'XElhPERATURE: Not Applicable IIIIEIEINAIR: IOWER:N AIPA Ll UPPDL N APPDOI ~

EVCXBfGUISIEING MEDIA, Not Applicable SPECIAL PHRS FIGHIXNGPROCEDUBXS: Fullprotective ectuipmeut including self-containedbreathing apparatus should be used, when COBRATEC.TT-SOS is present duzmg a Grew Durmg.

emergency conditions overexposure to decomposition products may cause a health haz;~

Symptoms may not be immediately apparent. Obtain medical attention.

UNUSUAL PIRE AND EXPLOSION HAZARDS Closed containers may rupture or explode due to steam pressure build-up when exposed to extreme heat. Water may be used.

to cool closed contamczs.

SECTION V DA lXRESHOLD LIMIT VALUE: None Established. For Sodium Hydroxide TEA~ 2mg/m HPPHCRROPO~ E CARMAN ~ N. C irritant. Prolonged contact can be destructive to tissue. Coatactwith the eyes may damage delicate eye tissue. Exposure to large amounts is capable of producing serious injazy.

EMERGENCY AND HE~K AID PROCEDURES IF ON SK1N Wash affected. area thorou jQy with soap and water. Remove contaznin'~ clothing, zmgs, etc. IF IN EYES:

Hush eyes with. lazge amounts of. water far 15 minutes.. Get mccHcal.attentiou.. IF SWALLOWED: Never gme anything by mouth to an unconscious person. DO NOT INDUCE VOMITING. Give large amounts'of water, vinegar 1:4 or lemon juice. Foyer with zuilk. Seek medical attention. IP.INHALED: If affected, remove from exposure.

Restore breathmg. Keep wazzn and. ~t, TOXICITYDATA: The acute taxDHfy data for TI'-SOS aze as Mloes:

LD~ Oral (zat): 920 mg/kg (Male) 640 mgQcg (Female) .

Eye and Skm Irritant Can cause severe izzztation Due to free caustic content.

NVI PZAEEIIY: PW I

, PtCOMPATXBKHY: gxuHzing Agents, strong acids 'I HAEABDOUP DHCOINPOPDION PROD UCHL BY NRP- IRW D CN Monoxide, Nitrogen oxides, HCN possible in. reducing atmospheres.

~~~a arvwm ~r v7u~lVATfON= WDI Not occur

LVIZe/SZ J4:gi . ~did adx I Jl I t'xt bb JHAKKh'rli~4 Ql oos MSDS COBRATEC IT-50S ON SPKL OR" P OCEDUPM SIKE TO BE TAKENIN CASEIHB MATEIUALIS SPKIZD OR = Pick up spill on suitable absorbent materiaL Flush spill area with water.

WASTE DISPOSAL METHOD: Sauitarv landQII or incinerate in approved faczrities h.

accordance with local, state, and federal regulations regarding pollution Do not heat. or-incinerate in dosed containers.

SPECIAL PR 0 ON RE%?IRATORY'ROTBCIXONt If pexsona1 exposure cannot be controlled beIow=

limits by ventQation, wear respiratory devices approve by-

~

applicable exposure NXOSHMSHA for protection against organic vapors, dust, funtes and mists.

VBNTaAaoN: h ~

GMVES: Necessary to avoid shn contact.

ad.'RCHKCZl%K EYE PROTECXION: Use safety glasses with unperforated side shields, or MIfitce shielcL when danger of splashing is great.

O'IHER PROIKCIXVBEQVIPMENT: Rubber apron or similar protective clothmg to prevent contact with st or clothes.

ONS CORROSIVEMATHUAL Avoid contactwith shn, eyes, aud clothing. DO NOT TARE INTERNALLY. Clean up spills immediately.

PRECAVIXONS TO BE TAKENIN HANDLINGAND SIORAGE: Keep coutaincxs tighdy closed when not in use. Store only in containers which axe resistant to caustic--

sotutions.

RXMSED = December 20, -1991 SUHHLCEDER December 19, 1990 ADDENDUM Rc Renew k

NaOH (1310-73-2) is cotttaincd on thc following chemical lists:

Qean Water Act Section 311 (40 CFR 116.4, $4 PR 93426)

Stxpcxfund. - CERCLA Hazardous Stthstances RQ - 1000 Ib as NaOH Thcmfoxmation contained herein js based on the data available to tts an4is believed to be coxrecxas of thc date=

ptepaxe4however, PMC SPECXALTIES GROUP mates no waxzanty, expressed or itttylictlxclmchugthe aecnrat7-.

of these data or the rcsnlts to bc obtamed from thc nse thereof.

~, ~ ~

SODIUM. TOLYLTRIAZQLESO'UTIO.N.

G~*

PMC '..CORRO'SION.':.iNHIBITOR a

..: FOR'OP.PER"AND.;COPP,ER ALLOYS IMPROVES PERFORMANCE 'OF. OTHER INHIBITORS FOR:OTHER 'IIET

.:. "". '," 7EGHNlCAt'BULLETlN..82f,O,':" .

'b ~

GENERAL DESCRIPTION DESCRIPTION COBRATEC TI~ is a corrosion inhibitor for copper and copper4ase alloys. It is verysimdarto COBRATEC'TT-Chemical Name Molecular WL Totyltriazate, sodium 155.14 100 In performance and mechanism of protection.ltdtffers only in that it is an aqueous solution of the sodium salt of totyitriazote. TMs permits faster make-up of treabng solutionsthraugh simple dilution to the desired concentra-Farmula Code Order. Entry No.

CAS Registry No.

C7H6N3Ma CO-TI X18WT7440 6466~-2

~

tion PROPERTIES COBRATEC TTM~ funcUons by reacUng with copper Appearance Clear, red brawn solutio oxide on the surface of copperarcopperalloys forming a Solution Density, sttang, insoluble polymeric complex. This complex !h/gal (24'C) 9.85 - 935 formation results in a protective layer ar film an the copper Crystal Point, 'C surface, a few molecules thick, that provides both a ph (10% solution) 12 mechanical and electrochemtcat bamer against corrosive Assay 50%

lack This protective layer has a high degree of thermal.

md oxidative stability and cannot be easily removed. TOXIC!TY COBRATEC TTW~ complexes copper in solution, The acute toxicity data for ZT-50-S are as follows:.

thereby preventing galvanic conasian of other metals.

ID50 Oral (rats) . 920 mglKg (Male)

SUGGESTED USES 640 m~Femate)

COBRATEC'TIMES can be used in most applications Eye and Sldn Irritant Can cause severe.

where COBRATEC 99 and COBRATEC TT-100 are irritaUon effecUve. Due to aslightiyhighercaiorand odor, compared Due to free caustic content to COBRATEC~ 99. it should be tested by the customer before use in any ap plicaUon where product acceptance The acute aquatic toxicity data for TM~ are may be effected. Otherwise funcUanal substitution Is 96 Hr. LCM:.

possible. Some specific uses are: Bluegill sunfish 191M mglL..

Rainbow trout 23.7 mg/I Circulating Caaling Systems such as cooling towers, air conditioning systems, cutting and grinding Chronic Toxicity of TTN(hS to Daphnia Magna:.

fluids. 14 day LC50 13% mg/L Functiaoal Fluids such as hydraulic fluids, specialty 21 day LC5p 5.8 mg/L lubricants and automotive caolants.

Corrosion Preventive Coatings such as water base S AFE HANDLING tacquers and waxes. Cotrasive solution. Store only In containers resistant t Cleaners such as soaps. detergents and strong alkali caustic soluUons. Wear proper protective equipment or acid cleaners. eye and skin protection.Avoid contactwlth skin, eyes an clothing. Adequate ventilation and other engineenn METHODS OF APPLICATION controls should be used to reduce employee exposur CQBRATEC~TI 60-S is incorporatedinaqueoussolutlons where necessaty.

at concentrations between 0~% and 4.6%. Where AVAILABIll1Y

'=OBRATEC TT-50-S replaces CQBRATEC~TI-100, the amount used should be increased by a factor of ~ Readily available fram stock In 5 gaL paHs end 65 g drums. Bulk quanUUes are also available.

~V ~ ~ C+nWOlard te &trCeeueelaaian Bet vthaacrs ~

Thb inlmaies b hctinet nSzslc-. harmrr. cgneywsraazaer ar gaagjtAoasgcggnpgw siaar&~efagtey ~ergeteLAll patwoetseQNQ++~

asaAc ehcir oem aecr go ~gvtge cary pggggg, w 4nrmanc nr ioabiTjy+aack pnachsas/er~paqsaes an4 de pii third oassaat 4'~ ~ ~~Np~ ~

PMC Specialties Group, Inc 501 Murray Road, Cfncinnatl, Ohio 45217

V = [Ãii'K 8 Ittdustrinl BETZ SLIMICIDE C-70

~ Eliminates the need to handle gaseous chlorine Dilution and Feedpoint BETZ Slimicide C-70 should be fed

~ Effective against bacterial, fungal, and algal slimes without dilution at a point in the cooling water system where turbulence, flow patterns, etc., will insure good mixing of the

~ Will not depress cooling water pH product with the cooling water.

DESCRIPTION AND USE Feed Equipment BETZ Slimicide C-70 is compatible with fIberglass, ceramic, Teflon, polyethylene, polyvinylchloride BETZ Slimicide C-70 is a liquid source of chlorine which aids -

(PVC), Viton, Kynar, Hastelloy, and rubber-lined steel feed in the control of bacterial, fungal, and algal slimes in cooling and storage equipment. The use of mild and stainless steel is tower water systems; influent systems, such as flow-through not recommended and should be avoided.

filters and lagoons, heat exchange water systems and indus-trial water scrubbing systems. It also controls slimes in brew-GENERAL PROPERTIES ery pasteurizers, industrial air washing systems equipped with mist eliminators, and once-through industrial cooling Appearance........................... green liquid ter systems. Sodium Hypochlorite. 12.5%

Inert Ingredients. 87 5%

EATMENT AND FEED EPA Reg. No. . 3876-142 REQUIREMENTS Density (70'F)...... . 10.2 Ib/gal Dosage Proper treatment levels for Slimicide C-70 depend Flash Point (closed cup). >200'F on many factors, such as the severity of the problem, age of Freeze Point . .. -14.0'F the product. and conditions particular to a given installation. Freeze/Thaw Stability (3 cycles)....:..... ..... stable pH (Neat) . 12.5 When the system is noticeably fouled, add 8 to 16 ounces of Pour Point (ASTM). ... -9.0'F Slimicide C-70 per each 1000 gallons of water in the system Specific Gravity (70 'F) . 1 21 to achieve 7.5 to 15.0 parts per million available chlorine by Viscosity (70 'F) ... 13.2 cP weight. Dosage should be repeated until control is achieved.

When microbiological control is evident apply 4 to 8 ounces . SAFETYPRECAUTIONS of Slimicide C-70 per each 1000 gallons of water in the A Material Safety Data Sheet containing detailed information system to achieve 3.75 to 7.5 parts per million available relative to this product is available upon request.

chlorine by weight. Apply treatment weekly or as needed to maintain control.

Since this product degrades with age, dosages may need to PACKAGING INFORMATION be increased to obtain the required level of available chlorine. BETZ Slimicide C-70 is blended as a liquid, and is supplied in A chlorine test kit should be used to determine the increase in bulk quantities only.

dosage rate.

PFC 414 8701 O1987 BETZ LABORATORIES. INC. ALL RIGHTS RESERVED

BETZ LABORATORIES,INC.

4636 SOMERTON ROAD, TREVOSE, PA. 19053 BETZ MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE (HEALTH/ACCIDENT) 800-877-1940 (PAGE 1 OF 3)

PRODUCT  : SLIMICIDE C-70 EFFECTIVE DATE 04-.19-9 PRINTED 20-Apr-1991 REVISIONS TO SECTIONS: 1,APPENDIX/9

'RODUCT APPLXCATION : WATER-BASED MICROBIAL CONTROL AGENT.

---

SECTION 1-----------HAZARDOUS INGREDIENTS NFORMATION ON PHYS ICAL HAZARDS 't HEALTH HAZARDS PEL S AND TLV S FOR SPECIFIC

~

'RODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD IS aISTED REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE WD CHRONIC, HAZARDS OF THIS FORMULATION. THIS PRODUCT IS SUBJECT TO THE

'ENNSYLVANIA AND NEW JERSEY WORKER AND COMMUNITY RIGHT TO KNOW LAW.

SODIUM,HYPOCHLORITE***CAS07681"52-.9;CORROSIVE;PEL:NONE;TLV:NONE.

SODIUM CHLORIDE"**CAS07647-14-5;EYE IRRITANT;PEL/TLV:NONE.

SODIUM HYDROXIDE(CAUSTIC SODA)**"CASQ1310-73-2;CORROSIVE;TOXIC IF ORALLY INGESTED;PEL:2.0MG/M3;TLV:2.0MG/M3(CEILING).

tONHAZARD INGREDIENTS: WATER (7732-18" 5)

---

SECTION 2-----------TYPICAL PHYSICAL DATA-

'H: AS IS (APPROX.) 12.5 ODOR: CHLORINE

'L.PT.(DEG.F): >200 SETA(CC) SP.GR.(70F)OR DENSITY: 1.217

'APOR PRESSURE(mmHG): 22 VAPOR DENSITY(AIR=1): ND

.'ISC cps70F: 13.2 %SOLUBILITY(WATER): 100

VAP.RATE: (1 ETHER=1 APPEPGV8JCE: YELLOW TO GREEN

'HYSXCAL STATE: LIQUID FREEZE POINT(DEG.F): -14

---

SECTION 3-------"---REACTIVITYDATA-

)TABLE.MAY REACT WITH ACIDS.DO NOT CONTAMINATE. BETZ TANK CLEAN-OUT

'.ATEGORY DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES.

'CHERMAL

BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3)

ODUCT: SLZMICZDE C-70

---SECTION 4--------"--HEALTH HAZARD EFFECTS-UTE SKIN EFFECTS **". PRIMARY ROUTE OF EXPOSURE C OSIVE TO SKIN YE EFFECTS ***

CO ROSIVE TO THE EYES UTE RESPIRATORY EFFECTS "**

VAPORS, GASES,MISTS AND/OR AEROSOLS CAUSE IRRITATION TO UPPER TRACT 'ESPIRATORY RONIC EFFECTS OF OVEREXPOSURE***

PROLONGED OR REPEATED CONTACT MAY CAUSE TISSUE NECROSIS.

DICAL CONDITIONS AGGRAVATED "**

NOT KNOWN MPTOMS OF EXPOSURE ***

CAUSES SEVERE IRRITATION,BURNS OR TISSUE ULCERATION WITH SUBSEQUENT SCARRING.

---SECTION 5------------FIRST AID INSTRUCTIONS-ZN CONTACT*"*

REMOVE CLOTHING. WASH AREA WITH LARGE AMOUNTS OF SOAP SOLUTION OR WATER FOR'15 MIN.IMMEDIATELYCONTACT PHYSICIAN E CONTACT*+*

IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES. IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT HALATION EXPOSURE***

REMOVE VICTIM FROM CONTAMINATED AREA. APPLY NECESSARY FIRST AID TREATMENT.IMMEDIATELYCONTACT A PHYSICIAN.

~E~N*"."

l~T 0

FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM NOT INDUCE VOMITING.IMMED.CONTACT PHYSICIAN. DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER

--SECTION 6-----------SPILL,DISPOSAL AND FIRE INSTRUCTIONS---------

ZLL INSTRUCTIONS**

VENTILATE "AREA,USE SPECIFIED PROTECTIVE EQUIPMENT. CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL, SHOULD BE DETERMINED ZN ACCORDANCE WITH RCRA REGULATIONS.

FLUSH AREA WITH WATER. WET AREA MAY BE SLIPPERY. SPREAD SAND/GRITS POSAL INSTRUCTIONS*""

WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,ZN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS IS)

PRODUCT OR RINSATES THAT CANNOT BE USED SHOULD BE DILUTED WITH WATER BEFORE DISPOSAL IN A SANITARY SEWER.

E EXTINGUISHING INSTRUCTIONS""*

FIREFZGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE). PROPER FIRE EXTINGUISHING MEDIA DRY CHEMICAL, CARBON DIOXIDE, FOAM OR WATER

BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3)

?RODUCT SLIMIC1DE C-70

--SECTION 7-----------SPECIAL PROTECTIVE EQUIPMENT PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS.

VENTILATION PROTECTION***

ADEQUATE VENTILATION RECOMMENDED RESPIRATORY PROTECTION***

IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE RESPIRATOR WITH ACID GASSES CARTRIDGES AND DUST/HIST PREFZLTERS RECOMMENDED SKIN PROTECTION***

GAUNTLET-TYPE RUBBER GLOVES, CHEMICAL RESISTANT APRON WASH OFF AFTER EACH USE.REPLACE AS NECESSARY RECOMMENDED EYE PROTECTION"**

SPLASH PROOF CHEMICAL GOGGLES.'FACE SHIELD .

---

SECTION 8--------"--STORAGE AND HANDLING PRECAUTIONS-STORAGE INSTRUCTIONS***

KEEP DRUMS 6 PAILS CLOSED WHEN NOT IN USE.

STORE AWAY FROM OXIDIZABLE AND COMBUSTIBLE MATERIALS GQlDLING INSTRUCTIONS***

ALKALINE. CORROSIVE(SKIN/EYES).DO NOT MZX WITH ACIDIC MATERIAL.

404%*%*A*%k%***0*i*A*%'44%*******t*******'0444'*ltd***%*%*%**%*St*%******%

."HIS MSDS WAS WRITTEN TO COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD

<*CP8*0'*%**i'*4*%**%*****i'i'*******44*4**0**44*****4*i'**4404*40*4*4*4**4 APPENDIX: REGULATORY INFORMATION CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE CTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE.

CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT.

..TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY

..FIFRA(40CFR):EPA REG.NO. 3876-20001

..REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT:

'9 GALLONS DUE TO SODIUM HYPOCHLORZTE;

,933 GALLONS DUE-TO SODIUM HYDROXIDE

..RCRA: IF THIS PRODUCT ZS DISCARDED AS A WASTE, THE RCRA HAZARDOUS WASTE

DENTZFICATION NUMBER ZS: D002=CORROSIVE(SKIN,PH)

..DOT HAZARD/UNO/ER GUIDES IS: CORROSIVE TO SKIN 'UN1791/560

..CALIFORNIA SAFE DRINKING WATER ACT (PROPOSITION 65) MATERIALS: NONE

..SARA SECTiON 302 CHEMICALS: NONE

..SARA SECTION 313 CHEMICALS: NONE

..SARA SECTION 312 HAZARD CLASS: IMMEDIATE(ACUTE) AND DELAYED(CHRONIC)

..MICHIGAN CRITICAL MATERIALS: SODIUM HYPOCHLORITE(7681.-52-9) tFPA/HMIS : HEALTH - 3 ; FIRE 0 ; REACTIVITY - 0 ; SPECIAL - CORR ; PE - D

BETZ LABORATORIES, INC.

4636 SOMERTON ROAD, TREVOSE, PA 19053 PRODUCT'LIMICIDE C-70 May 17, 1994 AQUATIC TOXICOLOGY Rainbow Trout 96 Hour Static Acute Bioassay LC50: 1.9 mg/L No Effect Level: 1.38

. Daphnia magna 48 Hour Static Acute Bioassay LC50: 1.6 mg/L No Effect Level: 0.51 Bluegill Sunfish 96 Hour Static Acute Bioassay LC50: 5.3 mg/L No Effect Level: 2.8 BIODEGRADATION NO DATA AVAILABLE LlAN TOXICOLOGY Dermal LD50 RABBIT: 3,000 MG/KG Skin Irritation Score RABBIT: 8 Eye Irritation Score RABBIT: 53 Oral LD50 RAT: 6,200 MG/KG

BETZ SLIMICIDE C-94 MiCrObiOCide

~ Economical source of bromine Plastic or Stainless are recommended. Pumps should have coIToslon resistant plastic heads. Feedlines and

~ Registered for once-through cooling mixers should be of Schedule 80 PVC or Kynar (PVDF).

The Initial crystallization Temperature may warrant heat

~ Liquid, easy to feed tracing and insulation in colder regions. Contact BES for

~ Use in CI2(g) replacement programs Information on pump feed or gravity feed packages.

DESCRIPTION AND USE GENERAL PROPERTIES BETZ Slimicide C-94 is a safe, easy to use source of bro- Appearance............ Colorless, Odorless Uquid mine in liquid form. The bromine in this product is present as inactive bromide ion. It must be oxidized to Br+ In or-der to exert a toxic effect on microorganisms. Conver-Brookfield Viscosity at 70 'F(21 C) ..........

sion of Br- to Br+ is usually achieved by co-feeding Flash Point...... ...." )200 F (P-m cc) (94 'C)

NaBr with chlorine [either CI2(g) or NaOCI(1)]. In water, oxidation of Br- to Br+ results in the formation of hypo-bromous acid (HOBr) which is superior to hypochlorous Freeze Point ............ <-30 'F (-34 'C) acid (HOCI) for control of microorganisms in high pH, Initial Crystallization Point .......... <0 'F (-18'C) once-through, or ammonia contaminated waters.

Percent Active ............. 40% NaBr (By Weight)

TREATMENT AND FEEDING REQUIREMENTS Activate bromide and generate hypobromous acid by co-feeding Slimicide C-94 with a'source of chlorine. By pH ...... ~ ............ 7.5 (Neat) controlling the ratio of chlorine to bromide lon, an all Specific Gravity 1A03 (70 'F)

HOBr acid stream or a mix of HOBr and HOCI canbe pro-duced in the discharge stream. PACKAGING INFORMATION Slimicide C-94 shouldbe fedneat, andmixed wlthundi- Slimicide C-94 Is available In bulk andbulk bin (270 gal) luted NaOCI or chlorinator discharge solution prior to F.O.B. El Dorado, Arkansas. Slimicide C-94 Is available application to tower basin or recirculating cooling water in 55 gal (208 L) drums out of Garland. The approximate lines. Use an in-line static mixer to ensure adequate net weight is 650 lb.(295 kg).

contact.

STORAGE AND FEED EQUIPMENT SAFETY PRECAUTIONS Slimicide C-94 storage vessels should be corrosion re- Material Safety Data Sheets containing detailedinforma-sistant materials. Polyethylene, Fiberglass Reinforced tion relative to this product are available upon request.

PFC 504 9012 O1990 BETZ lABORATORIES, INC. ALLRIGHTS RESERVED.

BETZ LABORATORIES,INC, 4636 SOMERTON ROAD, TREVOSE, PA. 19053 BETZ MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE (HEALTH/ACCIDENT) 800-877-1940 (PAGE 1 OF 3)

ODUCT : SLIMICIDE C-94 EFFECTIVE DATE 02-16-91 PRINTED: 26-Mar-1991 ODUCT APPLICATION : WATER-BASED MICROBIAL CONTROL AGENT.

---SECTION 1-----------.HAZARDOUS INGREDIENTS FORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC ODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD IS STED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE D CHRONIC HAZARDS OF THIS FORMULATION. THIS PRODUCT IS SUBJECT TO THE NNSYLVANIA AND NEW JERSEY WORKER AND COMMUNITY RIGHT TO KNOW LAW.

SODIUM BROMIDE* ".CASg7647-3.5-6;IRRITANT;PEL/TLV:NONE.

NHAZARD INGREDIENTS: WATER(7732-18-5)

---SECTION 2-----------TYPICAL PHYSICAL DATA------------

AS IS'APPROX.)

.PT.(DEG.F): >200 P-M(CC) 7.5 ODOR: SLIGHT SP.GR.(70F)OR DENSITY: 1.403 POR PRESSURE(mmHG): 18 VAPOR DENSITY(AIR=1): <1 SC cps70F: 12 %SOLUBILITY(WATER): 100 P.RATE: <1 ETHER=1 APPEARANCE: COLORLESS SICAL STATE: LIQUID <-30 3-----------REACTIVITYDATA POINT(DEG.F):

FREEZE

---SECTION BLE'. BETZ TANK CLEAN-OUT CATEGORY

'B'MAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES.

BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3)

'RODUCT'LIMICIDE C-94

,.----SECTION 4-----------HEALTH HAZARD EFFECTS kCUTE SKIN EFFECTS *"* PRIMARY ROUTE OF EXPOSURE NON-HAZARDOUS TO SKIN "E EYE EFFECTS **

MODERATELY IRRITATING TO THE EYES KCUTE RESPIRATORY EFFECTS "**

MISTS/AEROSOLS MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT

.'HRONIC EFFECTS OF OVEREXPOSURE"**

NO EVIDENCE OF POTENTIAL CHRONIC EFFECTS.

MEDICAL CONDITIONS AGGRAVATED ***

NOT KNOWN

)YMPTOMS OF EXPOSURE ***

MAY CAUSE REDNESS OR ITCHING OF SKIN.

---

SECTION.S------------FIRST AZD INSTRUCTZONS---

)KZN CONTACT*** 4 REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MINUTES

YE CONTACT*"*

IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES. IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT

NHALATION EXPOSURE**"

REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AZR.APPLY APPROPRIATE FIRST AID TREATMENT AS NECESSARY

NGESQION**"

DO NOT FEND ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE CONTENTS OF STOMACH. INDUCE VOMITING BY ONE OF THE STANDARD VICTIM'IZLUTE

.ETHODS.IMMEDIATELY CONTACT A PHYSICIAN

-.---SECTION 6-----------SPILL,DISPOSAL AND FIRE INSTRUCTIONS---------

)PILL INSTRUCTIONS"**

VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE CONTAMINATED ABSORBENT SHOULD BE CONSIDERED A PESTICIDE AND DISPOSED .OF ZN AN APPROVED PESTICIDE LANDFILL.SEE PRODUCT LABEL STORAGE AND DISPOSAL INSTRUCTIONS.

CONTAMINATED AREA MAY BE WASHED DOWN WITH WATER.

)ZSPOSAL INSTRUCTIONS***

WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,ZN.ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS IS)-

DISPOSE OF IN APPROVED PESTICIDE FACILITY OR ACCORDING TO LABEL INSTRUCTIONS

'ZRE EXTINGUISHING INSTRUCTIONS***

FIREFjGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE). PROPER FIRE EXTINGUISHING CHEMICAL, CARBON DIOXIDE, FOAM OR WATER MEDIA'RY

BETZ MATERIAL SAFETY DATA SHEET (PAGE 3.OF 3)

D  : SLIMICIDE C-94 TZON 7-----------SPECIAL PROTECT1VE EQUIPMENT P TECTZVE EQUIPMENT ZN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE PIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS.

TZLATZON PROTECTION*"*

ADEQUATE VENTILATION OMMENDED RESPIRATORY PROTECTION***

ZF VENTILATION ZS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE ZS LIKELY,

• USE A RESPIRATOR WITH DUST/MIST FILTERS.

OMMENDED SKIN PROTECTION"""

RUBBER GLOVES WASH OFF AFTER EACH USE.REPLACE AS NECESSARY OMMENDED EYE PROTECTION"":*

SPLASH PROOF CHEMICAL GOGGLES

'--SECTION 8-----------STORAGE AND HANDLING PRECAUTIONS------

R AGE INSTRUCTIONS***

KEEP DRUMS 6 PAILS. CLOSED WHEN NOT IN USE.

DO NOT FREEZE. IF FROZEN, THAW AND MIX COMPLETELY PRIOR TO USE DLZNG INSTRUCTIONS""*

NORMAL CHEMICAL HANDLING

++*0k***%**%A*k*******%%****4***%***%***A***********%A************

S MSDS WAS WRITTEN TO COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD

• %**0'*%****%%*4****%***444'****Sr*%***4***A'******t*********%*0*%*0'***

APPENDIX- REGULATORY INFORMATION ENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE

.CTIVE DATE OF THIS MSDS. THIS INFORMATION ZS BELIEVED TO BE ACCURATE.

CHANGES ZN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT.

TSCA: THIS ZS AN EPA REGISTERED BIOCIDE AND IS EXEMPT FROM TSCA INVENTORY UIREMENTS FZFRA(40CFR):EPA REG.NO. 5785-81-3876 REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT:

APPLICABLE RCRA: IF THIS PRODUCT ZS DISCARDED AS A WASTE, THE RCRA HAZARDOUS WASTE

'NTIFICATION NUMBER IS: NOT APPLICABLE DOT HAZARD/UN5/ER GUIDEO ZS: NOT APPLICABLE CALIFORNIA SAFE DRINKING,WATER ACT (PROPOSITION 65) MATERIALS: NONE SARA SECTION 302 CHEMICALS: NONE SARA SECTION 313 CHEMICALS: NONE SARA SECTION 312 HAZARD CLASS: IMMEDIATE(ACUTE)

MICHIGAN CRITICAL MATERIALS'ONE A/HMZS : HEALTH - 1 FiRE - O'; REACTIVITY - 0 SPECIAL - NONE PE - A .

BETZ LABORATORIES, INC.

4636 .SOMERTON ROAD, TREVOSE, PA 19053 PRODUCT'LIMICIDE C-94 May 17, 1994 AQUATIC TOXICOLOGY Daphnia magna 48 Hour Static Acute Bioassay Toxicity of hypobromous acid expressed as bromine.

LC50: 0.71 mg/L No Effect Level: 0.41 Bluegill Sunfish 96 Hour Static Acute Bioassay Toxicity of hypobromous acid expressed as bromine.

4 LC50: 0.52 mg/L No Effect Level: 0,.3-Rainbow Trout.96 Hour Static Acute Bioassay Toxicity of hypobromous acid expressed as bromine.

LC50: 0.23 mg/L Sheepshead Minnow 96 Hour Flow'-Thru Bioassay Toxicity of hypobromous acid expressed as bromine.

LC50: 0.19 mg/L No Effect Level: 0.11 Mysid Shrimp 96 Hour Flow-Thru Bioassay Toxicity of hypobromous acid expressed as bromine.

LC50: 0.17 mg/L Daphnia magna 48 Hour Static Acute Bioassay Toxicity of product as is.

LC50: 27500 mg/L BIODEGRADATION NO DATA AVAILABLE MAMMALIANTOXICOLOGY

, Oral LD50 RAT: >5,000 MG/KG Dermal LD50 RABBIT: >2,000 MG/KG

BETZ POWERLINE' 3200 Closed System Corrosion Inhibitor/Deposit Control Agent

~ A non-chromate treatment not environmentally the system and severity of the problem. Therefore, this prod-restricted uct should be used in accordance with control parameters BETZ establishes for a specific application.

~ Effective on steel, copper, solder, aluminum, and mixed metallurgy systems POWERLINE 3200 should be fed neat, at the level and frequency necessary to maintain the recommended concen-

~ Stable and effective at high temperatures and high tration, using a suitable shot-feeding device. Tanks, pumps, heat fluxes piping and valves may be constructed of steel or most com-

~ Compatible with antifreeze mon plastics.

The level of POWERLINE 3200 should be monitored with a DESCRIPTION AND USE colorimetric procedure available from BETZ using either a POWERLINE 3200 is a non-chromate, inorganic. based cor- visual comparator or a spectrophotometer.

rosion inhibitor formulated specifically for closed cooling sys-ems in the Power Industry. It is a highly effective corrosion nhibitor for steel, copper, solder, aluminum, and mixed met- GENERAL PROPERTIES allurgy systems, over a pH range of 6.0-9.5. POWERLINE Appearance .. ........... clear, yellow liquid 3200 also contains a broad spectrum dispersant to control deposition and scaling. In addition to its superior corrosion Density (70F) . .................. 9.9 Ibs/gal Flash Point (closed cup). )200F protection and dispersant properties, POWERLINE 3200 has Freeze Point ........................ 14F exceptional chemical and thermal stability. Unlike nitrites, it is Pour Point ...............'......... 19F not oxidized by aeration, soluble iron, or biological activity. Brookfield Viscosity (70F) ................ 4 cps POWERLINE 3200 has proven stable and effective in chilled water systems as well as pressurized hot water systems pH (undiluted). ....................... 12.8 (5% solution) . 11.6 operating at over 300F. Unlike chromate based inhibitors, POWERLINE 3200 is compatible with glycol and alcohol If product is frozen during shipment or storage, mix until antifreeze solutions. POWERLINE 3200 contains no silicates 'homogeneous prior to use.

or phosphates which can induce fouling in the presence of hardness.

SAFETYPRECAUTIONS POWERLINE 3200 is an environmentally acceptable altema-tive to chromates in the majority of applications. With its A Material Safety Data Sheet containing detailed information superior effectiveness on mixed metallurgies, dispersant relative to this product is available upon request.

properties, broad application range and inherent stability, POWERLINE 3200 offers significant performance advan-tages over nitrite-based programs. PACKAGING INFORMATION 3200 is blended as a liquid, and is supplied in

'OWERLINE TREATMENT AND FEEDING 55-gallon bung-type nonreturnable steel drums. Approximate REQUIREMENTS net weight 530 pounds per drum. In addition, POWERLINE The normal treatment level for POWERLINE 3200 ranges 3200 is available under the BETZ Point Of Feed Service from 1000 to 3500 ppm. However, the amount required will Program for contracted quantities in certain geographic depend on many factors such as operating characteristics of areas.

PFP023 8304 O BETZ LABORATORIES. INC. ALLRIGHTS RESERVED

BETZ LABORATORIES,ZNC.

4636'OMERTON ROAD, TREVOSE, PA'. 19053 BETZ MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE (HEALTH/ACCIDENT) 800-877-1940 (PAGE 1 OF 3)

PRODUCT 'OWERLZNE 3200 EFFECTIVE DATE'09-22-9 PRINTED'9-22-93 PRODUCT APPLICATION:WATER-BASED 'CORROSION'INHIBITOR.

'-----SECTION 1-----------HAZARDOUS INGREDIENTS INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS, AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUT I AND CHRONIC HAZARDS OF THIS FORMULATION.THIS PRODUCT IS SUBJECT TO THE PENNSYLVANIA AND NEW JERSEY WORKER AND COMMUNITY RIGHT TO KNOW LAW.

SODIUM MOLYBDATE(MOLYBDICACID,DISODZUM SALT)***CASQ 7631-95-0; POSSIBLE RESPIRATORY IRRITANTS PEL:5MG/M3(AS MO)lTLV:5MG/M3(AS MO)

SODIUM NITRITE***CASg 7632-00-0;OXIDIZER TOXIC(ORAL INGESTION) POTENTIAL BLOOD TOXIN;PEL:NOT DETERMINED;TLV:NOT DETERMINED NONHAZARD iNGREDIENTS: WATER(CASg 7732-18-5)

---

SECTION 2-----------TYPICAL PHYSICAL DATA PH: AS IS(APPROX.) 12.8 ODOR: MILD FL.PT.(DEG.F):> 200 SETA(CC) SP.GR.(70F): 1.184 VAPOR PRESSURE(mInHG): ND VAPOR DENSITY(AIR=1): ND VZSC cps70F: 4 %SOLUBILITY(WATER) 100.0 EVAP RATE: < 1.00(ETHER=1) APPEARANCE: YELLOW-PHYSZCAL STATE:LIQUID FREEZE POINT(DEG.F): 14.00

---

SECTION 3-----------REACTIVITY DATA STABLE.MAY REACT WITH STRONG OXIDZZERS.DO NOT CONTAMINATE.BETZ TANK CLEAN-OUT CATEGORY

'B'HERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES.

BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3)

RODUCT : POWERLZNE 3200

~

-~SECTION 4---------HEALTH HAZARD SKIN EFFECTS "** PRIMARY ROUTE OFEFFECTS "MAY CAUSE SLIGHT IRRITATION TO THE SKIN EXPOSURE CUTE EYE EFFECTS "** F SEVERE IRRITANT TO THE EYES CUTE RESPZRATORY EFFECTS ""*

MISTS/AEROSOLS MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT HRONIC EFFECTS OF OVEREXPOSURE"**

PROLONGED OR REPEATED EXPOSURES MAY CAUSE BLOOD CELL DAMAGE OR IMPAIR BLOOD CELL FUNCTION.

EDICAL CONDITIONS AGGRAVATED **"

NOT KNOWN YMPTOMS OF EXPOSURE "**

MAY CAUSE REDNESS OR ITCHING OF SKIN.

RECAUTIONARY STATEMENT BASED ON TESTING RESULTS ***

MAY BE TOXIC IF ORALLY INGESTED.

---

SECTION 5-------"---FIRST AID INSTRUCTIONS-KIN CONTACT <<**

REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MINUTES YE CONTACT*>>"

IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES. IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT NHALATZON EXPOSURE***

REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR.APPLY APPROPRIATE

'FIRST AID TREATMENT AS NECESSARY NGESTION""*

D NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE INDUCE VOMITING.IMMEDIATELYCONTACT PHYSICIAN. DILUTE CONTENTS OF VICTIM'OT MACH USING 3-4 GLASSES MILK OR WATER

---SECTION 6-----------SPILL, DISPOSAL AND FIRE INSTRUCTZONS-----------

PILL INSTRUCTIONS"*"

VENTILATE,AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS.

FLUSH AREA WITH WATER. WET AREA MAY BE SLIPPERY. SPREAD SAND/GRIT.

ISPOSAL INSTRUCTIONS****

WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS IS)-

INCINERATE OR BURY IN APPROVED LANDFILL IRE EXTINGUISHING INSTRUCTIONS*"*

FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE). PROPER FIRE EXTINGUISHING WITH WATER.USE OF C02 OR FOAM MAY NOT BE EFFECTIVE. MEDIA'LOOD

BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3)

PRODUCT  : POWERLINE 3200

---SECTION 7-----------SPECIAL PROTECTIVE EQUIPMENT-PROTECTIVE EQUIPMENT ZN ACCORDANCE WITH 29CFR SECTION 1910.132-134.

RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS.

VENTILATION PROTECTION***

ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOMMENDED RESPIRATORY PROTECTION*"*

IF VENTILATION ZS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH DUST/MIST FILTERS. ~

RECOMMENDED SKINPROTECTION**'UBBER GLOVES WASH OFF AFTER EACH USE REPLACE AS NECESSARY.

RECOMMENDED EYE PROTECTION***

SPLASH PROOF CHEMICAL GOGGLES

---

SECTION 8-----------STORAGE AND HANDLING PRECAUTIONS STORAGE INSTRUCTIONS***

KEEP CONTAINERS CLOSED WHEN NOT IN USE.

DO NOT FREEZE. IF FROZEN, THAW AND MIX COMPLETELY PRIOR TO USE HANDLING INSTRUCTIONS***

CONTAINS AN OXIDIZER. AVOID ALL CONTACT WITH REDUCING AGENTS,'ILS, GREASES, ORGANICS AND ACIDS. DO NOT ALLOW TO DRY.

~*%*4*a*****a*ai*A4***a*%a*4k**************%***a4****%***********

THIS MSDS WAS WRITTEN TO COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD

• %******4k*************%****0*4***%**0'*4***********4*4**4***4***

APPENDIX: REGULATORY INFORMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE.

ANY CHANGES..IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCU rT

...TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY

...REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT:

101 GALLONS DUE TO SODIUM NITRITE'

..RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE, THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS:D002=CORROSIVE(PH)

...DOT HAZARD/UN5/ER GUIDES IS :ORM-B(WHEN CONTAINER ) RQ)/NA1760/560

...CALIFORNIA SAFE DRINKING WATER ACT (PROPOSITION 65) MATERIALS:NONE

...SARA SECTION 302 CHEMICALS:NONE

...SARA SECTION 313 CHEMICALS:NONE

...SARA SECTION 312 HAZARD CLASS:IMMEDIATE(ACUTE);DELAYED(CHRONIC)

...MICHIGAN CRITICAL MATERIALS: NONE NFPA/HMIS : HEALTH - 2; FIRE-- 1'EACTIVITY - O'PECIAL - ALK ; PE B

tPRODUCT:

4636 PONERLINE 3200 BETZ LABORATORIES, ZNC.

SOMERTON ROAD, TREVOSE, PA 19053 May 17, 1994 AQUATIC TOXICOLOGY Rainbow Trout 48 Hour Static Screen 04 Mortality: 2000 mg/L Daphnia magna 48 Hour Static Acute Bioassay LC50: 5997 mg/L No Effect Level: 500 Bluegill Sunfish 96 Hour Static Acute Bioassay LC50: 3258 mg/L No Effect Level: 1800 BIODEGRADATION NO DATA AVAILABLE LIAN TOXICOLOGY Oral LD50 RAT: 825 MG/KG Note - ESTIMATED VALUE Dermal LD50 RABBIT: >2,000 MG/KG Note - ESTIMATED VALUE

BETZ LABORATORIES,INC.

4636 SOMERTON ROAD, TREVOSE, PA. 19053 BETZ MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE (HEALTH/ACCIDENT) 800-877-1940 (PAGE1 OF 3)

PRODUCT  : POWERLINE PPL10 EFFECTIVE DATE'06-22-9 PRINTED: 06-22-93 PRODUCT APPLICATION:WATER-BASED CORROSION INHIBITOR.

---

"SECTION 1-----------HAZARDOUS INGREDIENTS-INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUT I

AND CHRONIC HAZARDS OF THIS FORMULATION.THIS PRODUCT IS SUBJECT TO THE PENNSYLVANIA AND NEW JERSEY WORKER AND COMMUNITY RIGHT TO KNOW LAW.

SODIUM NITRITE***CASQ 7632-00-0;OXIDIZER;TOXIC(ORAL INGESTION);POTENTIAL BLOOD TOXIN;PEL:NOT DETERMINED TLV:NOT DETERMINED NONHAZARD INGREDIENTS: WATER(CASg 7732-18-5).

---

SECTION 2-----------TYPICAL PHYSICAL DATA PH: AS IS(APPROX.) 9.0 ODOR: MILD FL.PT.(DEG.F):> 200 P-M(CC) SP.GR.(70F): 1.107 VAPOR PRESSURE(mmHG): - 18.0 VAPOR DENSITY(AIR=1): < 1.00 VISC cps70F: 8 %SOLUBILITY(WATER): 100.0 EVAP RATE: < 1.00(ETHER=1) APPEARANCE: LIGHT YELLOW PHYSICAL STATE:LIQUID FREEZE POINT (DEG. F): 19. 00

---

SECTION 3--"-----"--REACTIVITYDATA-STABLE.MAY REACT WITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK CLEAN-OUT CATEGORY

'B'HERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES.

BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3)

RODUCT : POWERLINE PPL10

-SECTION 4----"----HEALTH HAZARD EFFECTS-J SKIN EFFECTS ""* PRIMARY ROUTE OF EXPOSURE CAUSE MODERATE IRRITATION TO THE SKIN UTE EYE EFFECTS ***

SEVERE IRRITANT TO THE EYES UTE RESPIRATORY EFFECTS ***

MISTS/AEROSOLS CAUSE IRRITATION TO UPPER RESPIRATORY'TRACT RONIC EFFECTS OF OVEREXPOSURE***

PROLONGED OR REPEATED EXPOSURES, MAY CAUSE BLOOD CELL DAMAGE OR IMPAIR BLOOD CELL FUNCTION; MAY CAUSE CNS DEPRESSION.

DICAL CONDITIONS AGGRAVATED ***

NOT'NOWN PTOMS OF EXPOSURE ***

CAUSES IRRITATION OF THE SKIN, EYES,AND/OR RESPIRATORY SYSTEM.

ECAUTIONARY STATEMENT BASED ON TESTING RESULTS ***

MAY BE TOXIC ZF ORALLY INGESTED.

---SECTION 5-----------FIRST AZD INSTRUCTIONS ZN CONTACT ~*"

REMOVE'ONTAMINATED CLOTHING. WASH EXPOSED AREA WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MINUTES E CONTACT***

IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MZBHJTES.IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT HALATION EXPOSURE"**

REMOVE VICTIM FROM CONTAMINATED'REA TO FRESH AIR.APPLY APPROPRZATE FIRST AID TREATMENT AS NECESSARY GESTZON***

DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM D TE CONTENTS OF STOMACH.INDUCE VOMITING BY ONE OF THE STANDARD ODS.IMMEDIATELY CONTACT A PHYSICIAN

--SECTION 6-----------SPILL,DISPOSAL AND FIRE INSTRUCTIONS---"-------

ILL ZNSTRUC'LIONS***

VENTILATE,AREA,USE SPECIFIED PROTECTIVE EQUIPMENT. CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS.

FLUSH AREA WITH WATER. WET AREA MAY BE SLIPPERY. SPREAD SAND/GRIT.

SPOSAL INSTRUCTIONS**"*

WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED, WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT (AS IS)-

INCiNERATE OR BURY ZN APPROVED LANDFILL RE EXTINGUISHING INSTRUCTIONS***

FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL PACE-PIECE TYPE). PROPER FIRE EXTINGUISHING MEDIA:

FLOOD WITH WATER.USE OF C02 OR FOAM MAY NOT BE EFFECTIVE.

BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3)

PRODUCT POWERLINE PPL10

---

SECTION 7-----------SPECIAL PROTECTIVE EQUIPMENT-PROTECTIVE EQUIPMENT ZN ACCORDANCE WITH 29CFR SECTION 1910.'132-134.

SPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS.

VENTILATION PROTECTION*"*

ADEQUATE VENTILATION RECOMMENDED RESPIRATORY PROTECTION**"

IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE ZS LIKELY, USE A RESPIRATOR WITH DUST/MIST FILTERS..

RECOMMENDED SKIN PROTECTION"**-

RUBBER GLOVES WASH OFF AFTER EACH USE REPLACE AS NECESSARY.

RECOMMENDED EYE PROTECTION***

SPLASH PROOF CHEMICAL GOGGLES

--"-"SECTION 8-------"---STORAGE'ND HANDLING PRECAUTIONS-STORAGE INSTRUCTIONS*<<*

KEEP CONTAINERS CLOSED WHEN NOT IN USE.

DO NOT FREEZE. IF FROZEN, THAW AND MIX COMPLETELY PRIOR TO USE HANDLING INSTRUCTIONS***

CONTAINS AN OXIDIZER. AVOID ALL CONTACT WITH REDUCING AGENTS, OXLS, GREASES, ORGANlCS AND ACIDS. DO NOT ALLOW TO DRY.

THIS MSDS WAS WRITTEN'TO COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD APPENDIX: REGULATORY INFORMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE.

ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUM T.

.TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED lN THE TSCA INVENTORY

...REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT 72 GALLONS DUE TO,SODIUM NITRITE

~ ..RCRA: ZF THIS PRODUCT "IS DISCARDED AS A WASTE, THE RCRA HAZARDOUS WASTE IDENTIFICATION, NUMBER IS:NOT APPLICABLE

...DOT HAZARD/UNg/ER GUIDEQ 'IS :ORM-E(WHEN CONTAINER > RQ)/NA9188/031

...CALIFORNIA SAFE DRINKING WATER ACT (PROPOSITION 65) MATERIALS:NONE

...SARA SECTION 302 CHEMICALS:NONE

...SARA SECTION 313 CHEMICALS:NONE

...SARA SECTION 312 HAZARD CLASS:IMMEDIATE(ACUTE);DELAYED(CHRONIC)

...MICHIGAN CRITICAL MATERIALS: NONE NFPA/HMIS : HEALTH - 2; FIRE " 1; REACTIVITY O'PECIAL - NONE'E - B

BETZ LABORATORIES, INC.

4636 SOMERTON ROAD, TREVOSE, PA 19053

/

PRODUCT POWERLINE PPL10 May 17, 1994 AQUATIC TOXICOLOGY NO DATA AVAILABLE BIODEGRADATION NO DATA AVAILABLE MAMMALIANTOXICOLOGY Oral LD50 RAT: 570 MG/KG Note - .ESTIMATED VALUE Dermal LD50 RABBIT: >5,000 MG/KG Note ESTIMATED VALUE

V = ERR'K 8 Industrial

,~ vVp~~b ~

Oq. ~

5>gr'+su'ETZ 860 DEPOSlT REMOVAL PRODUCT

~ Excellent for removal of calcium carbonate scale from volume. Betz willprovide control parameters andmonitor-cooling water. systems'. ing guklelines for specific applications.

~ Also effective on calcium phosphate deposits. Feed Point - Betz 860 should be fed to the cooling tower basin if being utilized in a recirculating cooling system

~ Can clean cooling systems of these deposits on-line or to the makeup or reciIculation pumps if dean eliminating production downtime. ing targe individual pieces of equipment (i.e.; power plant condenser).

DESCRIPTION AND USE 1 System Parameters - Betz 860 can be fed to all cooling water systems gZaeg those containing galvanized Betz 860 is a unique trade secreted material designed to material.

remove calcium carbonate and/or calcium phosphate de-posits from industrial and power cooling water systems. GENERAL PROPERTIES These deposits, which contribute to lost heat transfer or reduced water velocity, canbe removed safely and easily, Appearance........... yellow to dark brown liquid thus aiding in restoring a cooling system to its normal op- Density 70 'F(21 'C) ....... 9.14 pounds per gallon erating conditions. Flash Point (closed cup) .......... >200'F(93'C)

Betz 860 is designed as a one-time supplement to normal cooling water system treatment. It is not applicable as a Freeze Point ~...............:. 26 'F(-3 'C) continuous cooling system treatment product. Initial Crystallization ............... 80'F(27 C)

TREATMENT AND FEEDING REQUIREMENTS This product is designed to be used in two distinct manners:

pH (undiluted)

(5% solution)

PourPoint(ASTM)

~........... 31'F(-1 C) 1.4 2.3 Specific Gravity 70 'F(21 'C) .. ~...........

1.

2.

Recirculating through a cooling water system.

Fill and soak for large industrial and power Viscosity 100 'F(38 'C)........ 1.098 9.0 CPS equipment. PACKAGING INFORMATION The product is not.designed for small industrial heat ex- Betz 860 is a liquid material available only in bulk ship-changers due to packaging restrictions. ment quantities.

Dosage - Proper treatment levels of Betz 860 depend on the thickness of the calcium carbonate and/or calcium SAFETY PRECAUTIONS phosphate deposit and the size of the system. Feed of the Material Safety Data Sheets containing detailed informa-product is not based on system or equipment water tion relative to this product aie available upon request.

PFG 505 9204 1992 BETZ INDUSTRIALALL RIGHTS RESERVED. 4 PRINTED IN USA

BETZ LABORATORIES,INC.

4636 SOMERTON ROAD, TREVOSE, PA. 19053 BETZ MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE (HEALTH/ACCIDENT) 800-877-1940 (PAGE 1 OF 3)

ODUCT : DEPOSI-TROL 860D EFFECTIVE DATE:02-02-94 PRINTED: 02-02-94 ODUCT APPLICATION:CHEMICAL CLEANING COMPOUND.

---SECTION 1-----------HAZARDOUS INGREDIENTS FORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC ODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD IS STED. REFER TO SECTION '4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE D CHRONIC HAZARDS OF THIS FORMULATION.THIS PRODUCT IS SUBJECT TO THE NNSYLVANlA AND NEW JERSEY WORKER AND COMMUNITY RIGHT TO KNOW LAW.

TRADE SECRET INGREDIENT(E195)l EYE IRRITANT; PEL NOT DETERMINED TLV NOT DETERMINED;TSRN 125438 - 5118P TRADE SECRET INGREDIENT(122); POSSIBLE EYE IRRITANT PEL/TLV NUISANCE DUST; PEL:NUISANCE DUST;TLV:NUISANCE DUST;NOTE:MANUFACTURER'S RECOMMENDED EXPOSURE LIMIT:10MG/M3.;TSRN 125438 " 5214P TRADE SECRET INGREDIENT(222);OXIDIZER;CORROSIVE PULMONARY DAMAGE DENTAL EROSION;PEL:5MG/M3(10MG/M3-STEL);TLV:5MG/M3(10MG/M3-STEL);TSRN 125438 5238P NHAZARD INGREDIENTS: WATER(CASA 7732-18-5) TRADE SECRET (NK55) TSRN:

25438 - 5628P

---SECTION 2------"----TYPICAL PHYSICAL DATA AS IS(APPROX.) 1.4 ODOR: ACID

.PT.(DEG.F):> 200 P-M(CC) SP.GR.(70F): 1.098 POR PRESSURE(mmHG) 18.0. VAPOR DENSITY(AIR=1)' 1.00 SC cps70F: ND %SOLUBILITY(WATER): 100.0 AP RATE: < 1.00(ETHER=1) APPEARANCE'ELLOW TO DARK BROWN YSICAL STATE:LIQUID FREEZE POINT(DEG.F): 26.00

---SECTION 3-----------REACTIVITYDATA ABLE.MAY REACT WITH ORGANICS. OR ALKALINE MATERIALS.DO NOT NTAMINATE.BETZ TANK CLEAN-OUT CATEGORY

'D'RMAL DECOMPOSITION (DESTRUCTIVE FiRES) YIELDS ELEMENTAL OXIDES.

BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3)

PRODUCT  : DEPOSI-TROL 860D

---

SECTION 4---------HEALTH HAZARD EFFECTS

.TE SKIN EFFECTS ""* PRIMARY ROUTE OF EXPOSURE MAY CAUSE SLIGHT IRRITATION TO THE SKIN ACUTE'YE EFFECTS "**

SEVERE IRRITANT TO THE EYES ACUTE RESPIRATORY EFFECTS *** PRIMARY ROUTE OF EXPOSURE VAPORS, GASES,MISTS AND/OR AEROSOLS CAUSE IRRITATION TO UPPER RESPIRATORY TRACT.

CHRONIC EFFECTS OF OVEREXPOSURE"""

PROLONGED OR REPEATED EXPOSURE MAY CAUSE LUNG DAMAGE AND/OR MAY CAUSE PRIMARY IRRITANT DERMATITIS.

MEDICAL CONDITIONS AGGRAVATED "**

NOT KNOWN SYMPTOMS OF EXPOSURE **"

INHALATION MAY CAUSE IRRITATION OF RESPIRATORY TRACT;SKIN CONTACT,MAY CAUSE ITCHING AND/OR REDNESS.

PRECAUTIONARY STATEMENT BASED ON TESTING RESULTS ***

MAY, BE TOXIC IF ORALLY INGESTED OR INHALED.

-SECTION 5-------"---FIRST AID INSTRUCTIONS-SKIN CONTACT *",*

REMOVE CONTAMINATED CLOTHING.WASH EXPOSED AREA WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MINUTES EYE CONTACT***

IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES. IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE***

REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AZR.APPLY APPROPRIATE FIRST AID TREATMENT AS NECESSARY INGESTION***"

DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING.IMMEDIATELY CONTACT PHYSICIAN. DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER

'---SECTION 6-"-"-------SPILL;DISPOSAL AND FIRE INSTRUCTIONS------'----"

SPZLL INSTRUCTIONS*"*-

VENTILATE,.AREA,USE SPECIFIED PROTECTIVE EQUIPMENT. CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL SHOULD BE DETERMINED IN ACCORDANCE WITH RCRAREGULATIONS.

FLUSH AREA WITH WATER. WET AREA MAY BE SLIPPERY. SPREAD SAND/GRIT.

DISPOSAL INSTRUCTIONS *** ~

WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,ZN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS IS)

INCINERATE 'OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS**

FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE). PROPER FIRE EXTINGUISHING MEDIA:

DRY CHEMICAL,CARBON DIOXIDE,FOAM OR WATER

BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3)

ODUCT : DEPOSI-TROL 860D

~CTION 7-----------SPECIAL PROTECTIVE EQUIPMENT-

. DETECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134.USE SPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPiRATORS.

NTILATION PROTECTION*"*

ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS COMMENDED RESPIRATORY PROTECTION***

IF VENTILATION IS INADEQUATE OR. SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH DUST/MIST FILTERS.

COMMENDED SKIN PROTECTION"""

RUBBER GLOVES WASH OFF AFTER EACH USE REPLACE AS NECESSARY.

COMMENDED EYE PROTECTION***

SPLASH PROOF CHEMICAL GOGGLES

---SECTION 8-----------STORAGE AND HANDLING PRECAUTZONS-ORAGE INSTRUCTIONS***

KEEP CONTAINERS CLOSED WHEN NOT IN USE.

USE APPROVED CONTAINERS ONLY. STORE IN COOL, WELL-VENTED AREA. CONTACT WITH METALS MAY RELEASE FLAMMABLE HYDROGEN GAS.

DLING INSTRUCTIONS***

CONTAINS AN OXIDIZER. AVOID ALL CONTACT WITH REDUCING AGENTS, OILS, GREASES, ORGANICS AND ACIDS.

• • • 4**0'*******i%****%4**4'44******************4*4**********0'******

IS MSDS WAS WRITTEN TO COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD

• 0'4*4*****4****44%40*4***4*40'**4*********0***4*********************

APPENDIX: REGULATORY INFORMATION E CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE FE IVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE.

GES IN REGULATIONS WILL RESULT ZN UPDATED VERSIONS OF THIS DOCUMENT.

~ TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED ZN THE TSCA INVENTORY

~ REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT:

9,111 GALLONS DUE TO (122);5,466 GALLONS DUE TO (222);

.RCRA: IF THIS PRODUCT ZS DISCARDED AS A WASTE, THE RCRA HAZARDOUS WASTE ENTZFZCATZON NUMBER IS:D002=CORROSIVE(PH,STEEL)

.DOT HAZARD/UNC/ER GUIDES IS :CORROSIVE TO STEEL/UN1760/5

.CALIFORNIA SAFE DRINKING WATER ACT (PROPOSITION 65) MATERIALS:

REGULATED CONSTITUENT PRESENT AT OSHA THRESHOLDS

.SARA SECTION 302 CHEMICALS TRADE SECRET(222)--INORGANIC ACID

.SARA SECTION 313 CHEMICALS TRADE SECRET(222)--INORGANIC ACID , 2.0-

.04

.SARA SECTION 312 HAZARD CLASS:IMMEDIATE(ACUTE);DELAYED(CHRONIC)

.MICHIGAN CRITICAL MATERIALS:

REGULATED CONSTITUENT PRESENT AT OSHA THRESHOLDS FPA/HMIS  : HEALTH-- 2; FIRE - 1; REACTIVITY - 0; SPECIAL - CORR; PE - B

BETZ LABORATORIES, INC.

4636 SOMERTON ROAD, TREVOSE, PA 19053 PRODUCT: DEPOSI-TROL 860D May 18, 1994 AQUATIC TOXICOLOGY Daphnia magna 48 Hour Screen 04 Mortality. 1000 MG/L Fathead minnow 96 Hour Screen 04 Mortality: 1500 MG/L BIODEGRADATION NO DATA AVAILABLE MAMMALIANTOXICOLOGY Oral LD50 RAT: >2,000 MG/KG Note - ESTIMATED VALUE Dermal LD50 RABBIT: >2,000 MG/KG Note ESTIMATED VALUE Inhalation- LC50 RAT: >2,000 PPM/HR Note ESTIMATED VALUE

BETZ POWERLINE' 3680 DECHLORINATING AGENT

~ Eliminates both free and total chlorine residuals proximately 2 ppm of POWERLINE 3680 are required for

~ Enables compliance with new EPA regulations on each ppm reduction in total residual chlorine.

chlorine discharge from utility cooling systems POWERLINE 3680 should be added to the cooling water

~ Allows use of sufficient chlorine to control difficult discharge line in a manner which will provide adequate mix-ing prior to discharge. Systems designed for automatic feed biological fouling problems of POWERLINE 3680 are available from BHZ.

~ Liquid product Is safe and easy to handle Type 316L stainless steel and most common plastics are acceptable for handling POWERLINE 3680. Mild steel and DESCRIPTION AND USE copper are not recommended for use in feed system components.

POWERLINE 3680 is an aqueous solution designed to react with and destroy both free and total chlorine residuals in GENERAL PROPERTIES once-through and open recirculating cooling systems in the ower Industry. The product is intended for use in systems Appearance......................... yellow liquid ere adequate control of microorganism and macroorgan- Density (70F).......................... 11.7 Ibs/gal fouling cannot be achieved at the low chlorine levels Flash Point (closed cup)....................... >200F allowed by the recent EPA regulations. Freeze Point Pour Point

............................ 10F Dechlorination of the cooling water with POWERLINE 3680 prior to discharge enables the chlorine residuals and contact Brookfield Viscosity (70F)............ 15F 26 cps time in the cooling system to be adjusted to maximize biologi-cal control while still meeting permit limitations on the dis-pH (undiluted)................

(5%

(40F).

solution)...........................

36 cps 4.9 5.1 charge stream. Dechlorination of cooling water discharge is recognized as proven technology by the Federal Regula- If product becomes frozen during shipment or storage, thaw tions. Dechlorination costs are a fraction of the cost of chlor- completely and mix until homogeneous.

ination since only the chlorine residual remaining after the demand has been satisfied must be dechlorinated. SAFETY PRECAUTIONS The use of POWERLINE 3680 in conjunction with chlorine is A Material Safety Data Sheet containing detailed information generally a safer and less expensive option than the use of relative to this product is available upon request.

more costly alternative biocides.

STORAGE AND PACKAGING INFORMATION TREATMENT AND FEEDING I REQUIREMENTS POWERLINE 3680 is blended as a liquid and supplied in 55 gallon, bung-type nonreturnable lined steel drums. Approxi-The normal treatment levels for POWERLINE 3680 is depen-mate net weight 630 pounds per drum. POWERLINE 3680 dent on the required reduction in total chlorine residual. Ap- is also available in bulk quantities.

0 1984 BEtz LABORATORIES. INC. ALL RIGHTS RESERVED

BETZ LABORATORIES,INC.

4636 SOMERTON ROAD, TREVOSE, PA. 19053 BETZ MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE (HEALTH/ACCIDENT) 800-877-1940 (PAGE 1 OF 3)

PRODUCT  : POWERLINE 3680 EFFECTIVE DATE:04-13-9 PRINTED'4-13-93 REVISIONS TO SECTIONS: 1,APP PRODUCT APPLICATION:WATER-BASED DECHLORINATION AGENT.

---

SECTION 1-----------HAZARDOUS INGREDIENTS INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUT I

AND CHRONIC HAZARDS OF THIS FORMULATION.THIS PRODUCT IS SUBJECT TO THE PENNSYLVANIA AND NEW JERSEY WORKER AND COMMUNITY RIGHT TO KNOW BISULFITE* "CASQ 10192-30-0; CORROSIVE(EYES);IRRITANT(SKIN);

LAW.'MMONIUM PEL:NOT DETERMINED TLV:NOT DETERMINED AMMONIUM SULFITE***CASQ 10196-04-0; POTENTIAL RESPIRATORY IRRITANT; PEL:NOT DETERMINED;TLV:NOT DETERMINED.

AMMONIUM SULFATE*, *CASg 7783-20-2'YE AND SKIN IRRITANT; PEL'NOT DETERMINED TLV NOT DETERMINED NONHAZARD INGREDIENTS: WATER(CASO 7732-18-5)

---

SECTION 2-----------TYPICAL PHYSICAL DATA-PH: AS IS(APPROX.) 5.3 ODOR: MUSTY FL.PT.(DEG.F):> 200 P-M(CC) SP.GR.(70F): 1.329 VAPOR PRESSURE(mmHG): . 35.0 VAPOR DENSITY(AIR=1): < 1.00 VISC cps70F: 26 %SOLUBILITY(WATER): 100.0 EVAP RATE: < 1.00(ETHER=1) APPEARANCE: YELLOW TO GREEN PHYSICAL STATE:LIQUID FREEZE POINT(DEG.F): -22.00

---

SECTION 3-----------REACTIVITYDATA-STABLE. BETZ TANK CLEAN-OUT CATEGORY

'B'HERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES.

BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3)

'RODUCT 'OWERLINE 3680

--~-SECTION 4---------HEALTH HAZARD EFFECTS-SKIN EFFECTS """ PRIMARY ROUTE OF EXPOSURE CORROSIVE TO SKIN

.CUTE EYE EFFECTS *""

CORROSIVE TO-THE EYES CUTE RESPIRATORY EFFECTS ***

MISTS/AEROSOLS CAUSE IRRITATION TO UPPER RESPIRATORY TRACT HRONIC EFFECTS OF OVEREXPOSURE*

• PROLONGED OR REPEATED CONTACT MAY CAUSE TISSUE NECROSIS AND/OR DERMATITIS.

EDICAL. CONDITIONS AGGRAVATED *

• NOT KNOWN YMPTOMS OF EXPOSURE ***

CAUSES SEVERE IRRITATION,BURNS OR TISSUE ULCERATION WITH SUBSEQUENT SCARRING.

---

SECTION 5-----------FIRST AID INSTRUCTIONS KIN CONTACT ***

REMOVE CLOTHING. WASH AREA WITH LARGE AMOUNTS OF SOAP SOLUTION OR WATER FOR 15 MIN.IMMEDIATELYCONTACT PHYSICIAN YE CONTACT*~*

IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELYCONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT HALATION EXPOSURE**"

REMOVE VICTIM FROM CONTAMINATED AREA. APPLY NECESSARY FIRST AID TREATMENT. IMMEDIATELY CONTACT A PHYSICIAN.

GESTION"*";

OT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM UTE CONTENTS OF STOMACH. INDUCE VOMITING BY ONE OF THE STANDARD .

METHODS. IMMEDIATELY CONTACT A PHYSICIAN

-"-SECTION 6-----------SPILL,DISPOSAL AND FIRE INSTRUCTIONS----"------

ZLL INSTRUCTIONS*"".

VENTILATE,AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAXN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER.THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS.

FLUSH AREA WITH WATER. WET AREA MAY BE SLIPPERY. SPREAD SAND/GRIT.

SPOSAL INSTRUCTIONS*"*"

WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,ZN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS ZS)-

INCINERATE OR BURY ZN APPROVED LANDFILL RE EXTINGUISHING INSTRUCTIONS **

FZREFZGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE). PROPER FIRE EXTINGUISHING MEDIA:

DRY CHEMiCAL,CARBON DIOXIDE, FOAM OR WATER

BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3)

PRODUCT: POWERLINE 3680

---

SECTION 7------'-----SPECIAL PROTECTIVE EQUIPMENT-PROTECTIVE EQUIPMENT ZN ACCORDANCE WITH 29CFR SECTION 1910.132-134.U Kr;SPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS.

VENTILATION PROTECTION*",*

ADEQUATE VENTILATION RECOMMENDED RESPIRATORY PROTECTION***

IF VENTILATION ZS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE RESPIRATOR WITH ACID GASSES CARTRIDGES AND DUST/MIST PREFILTERS RECOMMENDED SKIN PROTECTION**"

GAUNTLET-TYPE RUBBER GLOVES, CHEMICAL RESISTANT APRON WASH OFF AFTER EACH USE REPLACE AS NECESSARY.

RECOMMENDED EYE PROTECTION***

SPLASH PROOF CHEMICAL GOGGLES. FACE SHIELD

---

SECTION 8-----------STORAGE AND HANDLING PRECAUTIONS-STORAGE INSTRUCTIONS***

KEEP CONTAINERS CLOSED WHEN NOT IN USE.

STORE ZN COOL,DRY LOCATION AWAY FROM ACIDS AND ALKALIES HANDLING INSTRUCTIONS***

CORROSIVE TO SKIN. CORROSIVE TO EYES.

%***4'*4'****0**%***A*********.*******44'**4*+****4******4***4'*******

~ THIS MSDS WAS WRITTEN TO COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD

%*%*%0****a***%*%a<<**%***************************A********4k***A*

APPENDIX: REGULATORY INFORMATION

'HE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE.

ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT.

TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED ZN THE TSCA INVENTORY

...REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT:

753 GALLONS DUE TO AMMONIUM BISULFZTE;9,033 GALLONS DUE TO AMMONIUM SULFITE'..RCRA:

IF THIS PRODUCT IS DISCARDED AS A WASTE, THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS:D002=CORROSZVE(SKIN)

...DOT HAZARD/UN¹/ER GUIDE¹ IS :CORROSIVE TO SKIN/NA2693/¹60

...CALIFORNIA SAFE DRINKING WATER ACT (PROPOSITION 65) MATERIALS:NONE

...SARA SECTION 302 CHEMICALS:NONE

...SARA SECTION 313 CHEMICALS:; AMMONIUM SULFATE(CAS¹ 7783-20-2), 0.1-1.0%

...SARA SECTION 312 HAZARD CLASS:IMMEDIATE(ACUTE);DELAYED(CHRONIC)

.;.MICHIGAN CRITICAL MATERIALS: NONE NFPA/HMIS : HEALTH - 3; FIRE - 0; REACTIVITY - 0; SPECIAL - CORR PE - D

e 4636 BETZ LABORATORIES, INC.

SOMERTON ROAD, TREVOSE, PA 19053 PRODUCT: POWERLINE 3680 May 17, 1994 AQUATIC TOXICOLOGY Fathead Minnow 96 Hour Static Renewal Bioassay Lowest Effect Level: 200 mg/L 0% Mortality: 100 Daphnia magna 48 Hour Static Screen 1008 Mortality: 250 mg/L 04 Mortality: 100 Bluegill Sunfish 48 Hour Static Screen 1008 Mortality: 500 mg/L 04 Mortality: 100 BIODEGRADATION COD (mg/gm): 83 TOC (mg/gm): Inorganic, N/A BOD-5 (mg/gm): Inorganic, N/A BOD-28 (mg/gm): Inorganic, N/A Closed Bottle Test 4 Degradation in 28 days: Inorganic, N/A Zahn-Wellens Test 4 Degradation in 28 days: Inorganic, N/A MAMMALIANTOXICOLOGY Oral LD50 RAT: >500 MG/KG Note - ESTIMATED VALUE Dermal LD50 RABBIT: >1,500 MG/KG Note - ESTIMATED VALUE

BETZ Bio-Trol'88P MICROBIOCIDE EPA Reg No. 5785-57-3876 ~ brewery pasteurizers

~ Fast-dissolving granular form ~ industrial air washer systems equipped with a mist eliminator under agitation

~ High concentration of actives

~

~ influent water systems, such as flow-through filters Rapidly generates effective halogen concentrations and lagoons

~ Effective on bacterial, fungal, and algal fouling ~ industrial water scrubbing systems

~ Long-lasting, controlled-protection biocide release TREATMENT AND FEEDING REQUIREMENTS DESCRIPTION AND USE In larger applications, a by-pass feeder is recommended Betz Bio-Trol88P is an effective, broad-spectrummicro- to achieve consistent product residuals throughout the biocide in a concentrated granular form. The product system. Betz offers a full range of feeder systems for ap-contains active bromine and chlorine in. a stabilized plying Bio-Trol 88P. For small systems, Betz Bio- I form; they are released into the water in a controlled 88P canbe fed directly to the cooling water, pasteu fashion as the granules dissolve. Bromine and chlorine orairwasherby means of a plasticor stainless steel d work together to provide effective control for a broad device, such as a mesh bag or perforated container that spectrum of slime-forming organisms. By controlling provides gradual dissolution.

slime accumulations, Bio-Trol 88P allows cooling towers and heat exchangers to operate at peak efficiency and Proper treatment levels for Betz Bio-Trol 88P depend on many factors such as the nature and degree of severity reduces the tendency for microbiologically induced of the microbial problem, systemretentiontime, temper-corrosion (MIC.)

ature, and other operating conditions. Typically, enough Bio-Trol 88P is particularly well-suited for applications Betz Bio-Trol 88P is added to the systemto achieve a2-3 that require shock dosing. For example, the rapid disso- mg/L total halogen residual in the water for 1-4 hr daily.

lution rates typical of this product make possible cost ef- For best results, your Betz Industrial representative will fective biofouling control of utility surface condensers determine the proper dosage for the specific system and without exceeding total residual oxidant discharge the problem to be treated.

limits. In all cases, the product must be applied in accordance with the use instructions on the Betz Bio-Trol 88P Betz Bio-Trol 88P may be used alternately with other product label.

Betz Slimicides to improve overall program effective-ness by reducing the development of microorganism GENERAL PROPERTIES strains that become resistant to a single biocidal agent.

. Bio-Trol 88P is registered with the Environmental Pro- Bromo-chloro hydantoi n 96.0%

tection Agency for the control of bacterial, fungal, and al- Inert Ingredients . .................. 4.0%

gal slimes. Bio-Trol 88P can be used in: Appearance ............ white grar1ules

~ commercial and industrial cooling towers Bulk Density ........ . ~... 64.5 Ib/ft (1033 kg/m3)

~ once-through and closed-cycle fresh and sea water Solubility . 1%

cooling systems pH (5% dispersion)

PPO 523 930S 1993 BETZ INDUSTRIALALL RIGHTS RESERVED. PRINTED IN USA

ENVIRONMENTALINFORMATION Dehalogenated Product (5,5 dlmethylhydantoin)

Aquatic Toxicology Information Daphnia magna: 48 hr LC 50: 1266 mg/L bow trout: 96 hr static acute bioassay- Fathead minnow: 96 hr LC50: 7890 mg/L LC50: 0.85 mg/L Rainbow trout: 96 hr LC50: 5940 mg/L Fathead minnow: 96 hr static acute bioassay-Grass shrimp: 96 hr LC50: 11,688 mg/L LC50: 2.19 mg/L Daphnia magna: 48 hr static acute bioassay- Sheephead minnow: 96 hr LC50: 12,954 mg/L LC50: 0.45 mg/L American oyster: 96 hr LC50: 13.830 mg/L Sheephead minnow: 96 hr static acute bioassay SAFETY PRECAUTIONS LC50:19.5 mg/L Grass shrimp: 96 hr static acute bioassay- A Material Safety Data Sheet containing detailed infor-LC50: 12.66 mg/L mation relative to this product is available upon request:

American oyster: 96 hr static acute bioassay-LC50: >623 mg/L PACKAGING INFORMATION Two Hour Dally Application Betz Bio-Trol 88P comes in granular form. It is available in a wide variety of customized containers and delivery Daphnia magna: 48 hr LC50: 1.66 mg/L Total residual oxidizer: 0.53 ppm methods. Contact your Betz Industrial representative for details.

Rainbow trout: 96 hr LC50: 1.17 mg/L Total residual oxidizer: 0.50 mg/L Page 2 PFC 523 9308

BETZ LABORATORIES,INC.

4636 SOMERTON ROAD, TREVOSE, PA. 19053 BETZ MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE (HEALTH/ACCIDENT) 800-877-1940 (PAGE 1 OF 3)

PRODUCT  : BIO-TROL 88P EFFECTIVE DATE'03-29-9 PRINTED: 03-29-94 REVISIONS TO SECTIONS: APP PRODUCT APPLICATION:SOLID MiCROBiAL CONTROL AGENT.

---.--SECTION 1-----------HAZARDOUS INGREDIENTS-INFORMATION ON PHYSICAL HAZARDS HEALTH HAZARDS PEL S AND TLV S FOR SPECIFIC

~ e PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL I AND CHRONIC HAZARDS OF THIS FORMULATION.THIS PRODUCT IS SUBJECT TO THE ACUT PENNSYLVANIA AND NEW JERSEY WORKER AND COMMUNITY RIGHT TO KNOW LAW.

1-BROMO-3-CHLORO-5,5-DIMETHYLHYDANTOIN***CASQ32718-18-6;OXIDlZER;EYE AND SKIN IRRITANT; PEL:NOT DETERMINED;TLV:NOT DETERMINED; NOTE-MANUFACTURER'S RECOMMENDED LIMIT:0.2MG/M3 NONHAZARD INGREDIENTS'MPURITY(CASO NOT ASSIGNED)

---

SECTION 2-----------TYPICAL PHYSICAL DATA PH: 5R DISP.(APPROX.) 4.7 ODOR: SLIGHT FL.PT.(DEG.F):> 200 P-M(CC) DENSITY:NO DATA VAPOR PRESSURE(mmHG): < 1.0 VAPOR DENSITY(AIR=1): 1. 00 VISC cps70F: NA %SOLUBILITY(WATER): 0.2 EVAP RATE: < 1.00(ETHER=1) APPEARANCE'HITE PHYSICAL STATE:GRANULES FREEZE POINT(DEG.F): NA

- ---SECTION'3-----------REACTIVITYDATA-STABLE. OXIDIZER. SLOWLY RELEASES HALOGEN GASES WHEN CONTAMINATED WITH MOISTURE. MAY REACT WITH ALKALIES, ACIDS, ORGANICS OR REDUCING AGENTS. DO NOT CONTAMINATE. BETZ TANK CLEAN-OUT CATEGORY 'B'.

THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES.

BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3)

RODUCT : BIO-TROL 88P

-SECTION 4---------HEALTH HAZARD EFFECTS.-

SKIN EFFECTS *"* PRIMARY ROUTE OF EXPOSURE DERATELY IRRITATING.MAY BE CORROSIVE IN CONTACT WITH MOIST SKIN.

CUTE EYE EFFECTS "** ~

SEVERE IRRITANT TO THE EYES CUTE RESPIRATORY EFFECTS ***

DUSTS CAUSE IRRITATION TO UPPER RESPIRATORY TRACT HRONIC EFFECTS OF OVEREXPOSURE**"

NO EVIDENCE OF POTENTIAL CHRONIC EFFECTS.

EDICAL CONDITIONS AGGRAVATED '<<**

NOT KNOWN PTOMS OF EXPOSURE ***

MAY CAUSE REDNESS OR ITCHING OF SKIN.

RECAUTIONARY STATEMENT BASED ON TESTING RESULTS "**

MAY BE TOXIC IF ORALLY INGESTED.

---SECTION 5--"--------FIRST AID INSTRUCTIONS IN CONTACT *+*

REMOVE-.CLOTHING;WASH AREA WITH LARGE AMOUNTS OF SOAP SOLUTION OR WATER FOR 15 MIN:IMMEDIATELYCONTACT PHYSICIAN E CONTACT***

IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES. IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT HALATION EXPOSURE***

REMOVE VICTIM FROM CONTAMINATED AREA. APPLY NECESSARY FIRST AZD TREATMENT. IMMEDIATELY CONTACT A PHYSICIAN.

GESTION**"

DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING.IMMEDIATELYCONTACT PHYSICIAN. DILUTE CONTENTS OF

~

CH USING 3-4 GLASSES MILK OR 'WATER

--SECTION 6-----------SPILL, DISPOSAL AND FIRE INSTRUCTZONS-----------

~

ZLL INSTRUCTIONS***

VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT. SPILLED MATERIAL WHICH CAN NOT BE RECOVERED FOR RE-USE ,SHOULD BE PLACED IN A. WASTE DISPOSAL CONTAINER AND DISPOSED OF IN AN APPROVED PESTICIDE LANDFILL.SEE PRODUCT LABEL STORAGE AND DISPOSAL INSTRUCTIONS.

PRODUCT RELEASES CHLORINE WHEN WET.SPILL RESIDUE MAY BE NEUTRALIZED WITH 3R HYDROGEN PEROXIDE SOLUTION.

SPOSAL INSTRUCTIONS****

WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS IS)-

DISPOSE OF IN APPROVED PESTICIDE FACILITY OR ACCORDING TO LABEL INSTRUCTIONS RE EXTINGUISHING INSTRUCTIONS*

FZREFZGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE). PROPER FIRE EXTINGUISHING WITH WATER.USE OF C02 OR FOAM MAY NOT BE EFFECTIVE. MEDIA'LOOD

BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3)

PRODUCT  : BZO-TROL 88P

---

SECTION 7--'---------SPECIAL PROTECTIVE EQUIPMENT E PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTiON 1910.132-134.

xx"SPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS.

VENTILATION PROTECTION***

ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOMMENDED RESPIRATORY PROTECTION**

ZF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE RESPIRATOR WITH ACID GASSES CARTRIDGES AND DUST/MIST PREFZLTERS RECOMMENDED SKIN PROTECTION***

GAUNTLET-TYPE RUBBER GLOVES,CHEMICAL RESISTANT APRON WASH OFF AFTER EACH USE REPLACE AS NECESSARY.

RECOMMENDED EYE PROTECTION***

AIRTIGHT CHEMICAL GOGGLES

---

SECTION 8-----------STORAGE AND HANDLING PRECAUTIONS--

STORAGE INSTRUCTIONS***

KEEP CONTAINERS CLOSED WHEN NOT IN USE.

KEEP DRY. DO NOT STORE AT HIGH .TEMPERATURE OR NEAR OXZDIZABLES OR COMBUSTIBLES HANDLING INSTRUCTIONS***

OXIDIZER.AVOID ALL CONTACT WITH .REDUCING AGENTS, OILS, GREASES, ORGANICS AND ACIDS.

k******4*4***4****4*44*****************4*0*********'0'***********

THIS MSDS WAS WRITTEN TO COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD

• 4***%%*k**************%%****************%***********%**A*****

APPENDIX: REGULATORY INFORMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE

~

& CHANGES ZN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUY

...TSCA: THIS IS AN EPA REGISTERED BIOCIDE AND IS EXEMPT FROM TSCA INVENTORY REQUIREMENTS

...FZFRA(40CFR):EPA REG.NO.: 3876- 150

...REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT:

NO REGULATED CONSTITUENT PRESENT AT OSHA THRESHOLDS

...RCRA". IF THIS PRODUCT IS DISCARDED AS A WASTE, THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS:D001=IGNITABLE

...DOT HAZARD/UNg/ER GUIDEg IS :OXIDIZER/UN1479/535

...CALIFORNIA SAFE DRINKING.WATER ACT (PROPOSITION 65) MATERIALS'O REGULATED CONSTITUENT PRESENT AT OSHA THRESHOLDS

...SARA SECTION 302 CHEMICALS:

NO REGULATED CONSTITUENT PRESENT AT OSHA THRESHOLDS

...SARA SECTION 313 CHEMICALS:

NO REGULATED CONSTITUENT PRESENT AT OSHA THRESHOLDS

...SARA SECTION 312 HAZARD CLASS:IMMEDIATE(ACUTE);FIRE

...MICHIGAN CRITICAL MATERIALS:

NO REGULATED CONSTITUENT PRESENT AT OSHA THRESHOLDS NFPA/HMIS : HEALTH 2; FIRE - 1'EACTIVITY - 1 SPECIAL - OXY PE - C

tPRODUCT'IO-TROL 88P 4636 BETZ LABORATORlES, INC.

SOMERTON ROAD, TREVOSE, PA 19053 May 17, 1994 AQUATIC TOXICOLOGY NO DATA AVAILABLE BIODEGRADATION NO DATA AVAILABLE MAMMALIANTOXICOLOGY Oral LDSO RAT: 578 MG/KG Note 600 MG/KG PER ALT. SOURCE; DEHALOGENATED BYPRODUCT RAT ORAL LD50: >4e000 MG/KG Dermal LD50 RABBIT: >2,000 MG/KG Note - ALTERNATE SOURCE CONCURS Inhalation- LC50 RAT: 1.88 MG/L/4HR Note >3.2 MG/L/4HR AT 100-PPM (NO DEATHS) PER ALTERNATE SOURCE Skin Irritation Score RABBIT:

6.98 PER ALTERNATE SOURCE; REVERSIBLE; 6.1'ote DEHALOGENATED BYPRODUCT SCORE: 0.8 Eye Irritation Score RABBIT: 103 Note - 14 DAY-IRREVERSIBLE-MAX.ATDAY 3 DEHALOGENATED BYPRODUCT SCORE: 12.8-REVERSIBLE 90 Day Feed Study RAT: NO DATA Note - DEHALOGENATED BYPRODUCT 90-DAY ORAL LD50: >2,000 MG/KG/DAY Skin Sensit. Patch G.PIG: POSITIVE Note - BUEHLER TEST; DEHALOGENATED BYPRODUCT WAS NEGATIVE IN BUEHLER TEST Ames Assay BACTERIA: NEGATIVE Note - +/- METABOLIC ACTIVATION; DEHALOGENATED BYPRODUCT:

NEGATIVE Non-Ames Mutagenicity YEAST: NEGATIVE Note - DEHALOGENATED BYPRODUCT NEGATIVE FOR: MOUSE LYMPHOMA, SCE, CELL TRANSFORMATION Teratology- RAT: NO DATA Note DEHALOGENATED BYPRODUCT STUDY HAD TERATA (SECONDARY) AT MATERNAL TOXIC DOSES

'eproductive Toxicity RAT: 4,500 MG/KG/DAY

Note - DEHALOGENATED BYPRODUCT STUDY HAD NO ADVERSE REPRODUCTIVE TOXICITY

fviaterial Safety Data Sheet Required under USDL salety and Health Regulatens U.s. oeparonentotLabor Occupational Salety ana Health Adminrstraten 3@i X (+-

tor Shioyara Employmem (29 CFR 1915)

OMB No. 12(8.0074 Exo ration Date 05/3) /86 Section I Manufacturer S Name Emergency Telephone Number Henniaan Aaaress (Number.

~neeri Co. mT c.

Street. city. state.ana ZIP Godet Chemical Name 86 Finnell Drive andSynonyms SOdiLI pol Traae Name Weynnuth, MA 02188 ana Synonyms 4E-$ 0 Section II - Hazardous Ingredients Chemical Carbo Formula lated ool electrol te Paints. Preservetlves. end Solvents TLV (Unitsl Alloys end Metallic Coatings  % . TLV (Units)

Pigments Base Metal Catalyst AIIOyS vehiole Metallic Coatings Solvents Filler Metal Plus Coating or Core Flux Additives Othera Others s Mixtures ol Other Llqulds, Solids or Oases I

Tiv (Units)

Section III - Physical Oats BOiang POint I F I Specific Gravity (H,ont)

About 212oF About vaoor pressure tmm rtg I Percent voialiie by volume (%)

Same as water About vapor Density (AIR*11 Evaporaten Rate N.A.

lubaity in Water

!'U.scible oH: About Appearance ana Odor Clear to oale ellow liquid N lon IV - Fire and Explosion Hazard Oats lash Point (Methoa Useol Flammable Limits Lel Uel

( F/ C): ) 212/100 Closed Cuo N.A. N.A.

Exlinguisning Meaia auid Droduct does not burn pecial Fire Fighting Procedures None nusual Fire ano Explosen Hazards

tone Page 0 (Continued on Reverse Side) Form OSHA.20 (Rev. 3/84)

Sect(on V - Health Hazard Data Tnresnoid Limit value Hone Established Eriocts or Overexposure To acute irritant.

adverse effects known. Test data indicates Chat oroduct i Any risk of ingestion injury would be related to pH range of 10 to 11. Swallo s

Emergency First Aid Procedures Eye contact-Plush irrtediately with large ar(ounts of water for 15 minutes hazard exoect repea e y no azng eye was open. a p ysician if an irritation persists.

Skin Contact Pat<<nt large Wash amounts an ~

with plenty of soap a e y a.

and. water.

sigru canc amounts have been swallowed.

of water or milk to drink for dilution effect. No Give t Section Vl - Aeacttv(ty Oala expected.

Stabi ty Unstable Conditions lo Avoid N.A.

Stable InCOmpalabikly (MateriatS lOAvOidl None HazardOuS Decomposition ProduCtS None Hazardous May Occur >

ConditicnS !O Avoid POlymenZauOn U

Will Not Occur xl Section Vll - Split or Leak Procedures Sieos to be Taken in Case Matenal is Released or Spitted "revent liquid from ente drinkin w ter su with absorbent local state re lations.

Waste Oisposat Method This product as sold within its H soecification ran is not according to EPA regulations 40 CFR 261. Dis ose of waste roduct in with state and loc Section Vill- S peclal Protection Information Respiratory Protection (Specity Typel Not no Ventsa eon Local Exnaust Special Mecnanical (Generail Other Typical systems are sufficient for simp e mixing.

Protecuve Gloves ye """'onChemical safety uomzles with side shiel Tmoerv io Generally-do not wear co@ t lenses when han Other Protective Eouipment chemicals.

None Sect(on IX - Spec(at Precautions Precautions to oe Taken in Hanoting ano Stonng None

'recautions None

'NSDS NUMBER 2711G S PRPDUCT TSCAr CAS NUMBER 54193-36-1 (ite .3/ t

~~Benz Rllxlimiilff/tfi//

BETZ POWERLINE' 3450 Deposit Control Agent

~ Patented calcium phosphate scale Inhibitor tinuously to maintain consistent residuals in the cooling wa-

~ Permits proper phosphate concentration for

, ter. Intermittent product feed is applicable in certain once-through cooling systems.

complete corrosion inhibition of mild steel

~ Effective general dispersant for slit, iron, and POWERLINE 3450 may be fed directly from the shipping calcium fouling container or diluted with water to any convenient feeding

~ Compatible with chlorination strength.

Tanks, pumps, piping and valves may be made of stainless steel or most common plastics. Avoid the use of mild steel and copper alloys.

DESCRIPTION AND USE WERLINE 3450 is a special organic deposit control agent gned to control calcium phosphate formation in open recirculating cooling water systems in the Power Industry.

The use of this product for the control of the formation and/or deposition of calcium and magnesium phosphates and sili-cates, iron oxide, clay, or mixtures thereof is covered by U.S.

Patent 4,029,577. Its use in conjunction with POWERLINE 3040 or POWERLINE 3080 is also covered by U.S. Patent 4,303,568. l00 0 PotNE R LINE 3450 TYPICAL APPLICATIONS 10 POWERLINE 3450 is a patented calcium phosphate scale 20 inhibitor, designed for Power Industry cooling systems with high concentrations of phosphate in the makeup water or to 50 be app'lied in conjunction with certain phosphate-based POWERLINE corrosion inhibitors. With POWERLINE 3450, Z 50 0 Polymorrs Dtspsrsonr phosphate concentrations can be carried high enough to S attain the desired mild steel corrosion protection formerly 40 produced only by effective chromate based programs. A erponro Phosphoro A 30 POWERLINE 3450 is also a highly effective general.disper-sant for silt, iron, and calcium fouling. Figures 1 and 2 illus- 'RO trate the deposit control capabilities of POWERLINE 3450.

to X erponis Phospholr 8 TREATMENT AND FEEDING REQUIREMENTS Active 0osope ippm) ~

POWERLINE 3450 should be fed to a point in the cooling FIGURE 1-The superior ability of POWERLINE 3450 to control system where turbulence and flow patterns will ensure orthophosphate deposition.'OWERV NE 3450 provided 96 to 98%

uate mixing of the product with the cooling water. In inhibition of calcium phosphate precipitation as compared to 13-rectrculating cooling systems the product should be fed con-- 43 jo by conventional cooling water dispersants.

PFP 039 8505 i5'985 BETZ LABORATORIES. INC. ALL RIGHTS RESERVED

GENERAL PROPERTIES lOO O POWERVHE 3dSO Appearance" .. light yello Density (70F). ..9.3lb gal Flash Point (closed cup) . ....... >200F Freeze Point. . 26F Pour Point (ASTM) . ............. 31F pH (undiluted) . .... 5.3 C

tt (5% solution) ... 5.9 Pottoerttote Specific Gravity (70F). ............. 1.12 SO (.OO MeteOrter Wereht 0 Pot(roe(ok Aohrdrido Viscosity (70F)............. 19.5 cps (40F). ... 35 cps Arothetrirhettrrt Freeze/Thaw Recovery (3 cycles) . ........... Stable Phetehohio ACid (A((pl 0 Pot(roe(odor(tete

'P Htdro t re ththdehe Oieheeeheoie Acid (HEOP)

Actiro Oeeeeo (hero(

PACKAGING INFORMATION POWERLINE 3450 is blended as a liquid, and is supplied in FIGURE2-The ability ol POWERVNE3450 to inhibit calcium ortho- 55gallon bung-type nonreturnable lined steel drums. Ap-phosphate deposition at normally recommended POWERVNE cor-proximate net weight 500 pounds per drum. In addition, rosion inhibitor control limits. Compared to other conventional cool- POWERLINE 3450 is available under the BHZ Point Of ing water deposit control agents, the perfonnance of POWERVNE Feed Service Program for contracted quantities in certain 3450is a significant improvement. geographic areas.

PFP 039 8505 PAGE 2

BETZ LABORATORIES,INC.

4636 SOMERTON ROAD, TREVOSE, PA.'19053 BETZ MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE (HEALTH/ACCIDENT) 800-877-1940 (PAGE 1 OF 3)

ODUCT : POWERLINE 3450 EFFECTIVE DATE 02-16-91 PRINTED 8-Apr-1991 ODUCT APPLICATION  : WATER-BASED DEPOSIT CONTROL AGENT.

---SECTION 1-----------HAZARDOUS INGREDIENTS-FORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC ODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD IS STED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE D CHRONIC HAZARDS OF THIS FORMULATION- THIS PRODUCT IS SUBJECT TO THE NNSYLVANIA AND NEW JERSEY WORKER AND COMMUNITY RIGHT TO KNOW LAW.

IS PRODUCT IS NOT HAZARDOUS AS DEFINED BY OSHA, PENNSYLVANIA, OR NEW JERSEY GHT TO KNOW REGULATIONS HAZARD INGREDIENTS: WATER(7732-18-5)  ; ACRYLIC ACID COPOLYMER WITH HYDROXY PYL ACRYLATE(39373-34-7)

--SECTION 2-----------TYPICAL PHYSICAL DATA AS IS (APPROX.) 5.3 ODOR: MILD PT.(DEG.F): )200 SETA(CC) "

SP.GR.(70F)OR DENSITY: 1.123 OR PRESSURE(mmHG): 20 VAPOR DENSITY(AIR=1): <1 C cps70F: 19.5 %SOLUBILITY(WATER): 100 P.RATE: <1 ETHER=1 APPEARANCE: LIGHT YELLOW SICAL STATE: LIQUID FREEZE POINT(DEG.F): 26

--SECTION 3-----------REACTIVITYDATA BLE.MAY REACT WITH'TRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK

-OUT CATEGORY

'A'MAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES.

BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3)

PRODUCT'OWERLZNE 3450

---

SECTION 4-----------HEALTH HAZARD EFFECTS ACUTE SKIN EFFECTS,*

• PRIMARY ROUTE OF EXPOSURE SLIGHTLY IRRITATING TO THE SKIN TE EYE EFFECTS "**

SLIGHTLY ZRR1TATING TO THE EYES ACUTE RESPIRATORY EFFECTS .**" 'I MISTS/AEROSOLS MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT CHRONIC EFFECTS'F OVEREXPOSURE*"*

NO EVIDENCE OF POTENTIAL CHRONIC EFFECTS.

MEDICAL CONDITIONS AGGRAVATED "**

NOT KNOWN SYMPTOMS OF EXPOSURE ***

MAY CAUSE REDNESS OR ITCHING OF SKIN, IRRITATION AND/OR TEARING OF EYES(DIRECT CONTACT).

---

SECTION 5------------FIRST AID INSTRUCTIONS SKIN CONTACT"**

REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MINUTES EYE CONTACT""*

IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELYCONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE***

REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR.APPLY, APPROPRIATE FIRST AID TREATMENT AS NECESSARY INGESTZON"-"":

DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM

')ILUTE CONTENTS OF STOMACH. INDUCE VOMITING BY ONE OF THE STANDARD METHODS.IMMEDIATELY CONTACT A PHYSICIAN

---

SECTION 6-----------SPILL, DISPOSAL AND FIRE INSTRUCTIONS---------

SPILL INSTRUCTIONS***

VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT. CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL, SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS.

FLUSH AREA WITH WATER. WET AREA MAY BE SLIPPERY. SPREAD SAND/GRIT.

DISPOSAL INSTRUCTIONS"**

WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO. A SANITARY SEWER TREATMENT FACILITY,IN-ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS IS)

INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS*"*

FZREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS'(FULL FACE-PIECE TYPE). PROPER FIRE EXTINGUISHING MEDIA:

DRY CHEMICAL/C02/FOAM OR WATER. SLIPPERY CONDITION. USE SAND/GRIT

BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3)

POWERLZNE 3450 CTZON 7-----------SPECIAL PROTECTIVE EQUIPMENT E PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE SPIRATORS WITHIN USE LIMITATIONS OR .ELSE USE SUPPLIED AIR RESPIRATORS.

NTILATION PROTECTION***

ADEQUATE VENTILATION COMMENDED RESPIRATORY PROTECTION***

IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE ZS LIKELY, USE A RESPIRATOR WITH DUST/MIST FILTERS.

COMMENDED SKIN PROTECTION***

RUBBER GLOVES WASH OFF AFTER EACH USE.REPLACE AS NECESSARY COMMENDED EYE PROTECTION***

SPLASH PROOF CHEMICAL GOGGLES

---SECTION 8-----------STORAGE AND HANDLING PRECAUTIONS-------------

O RAGE INSTRUCTIONS***

KEEP DRUMS S( PAILS CLOSED WHEN NOT ZN USE.

PROTECT FROM FREEZING DLING INSTRUCTIONS***

NORMAL CHEMICAL HANDLING

• 4'**%*4**A***********%*4*********A**************0***44*******A4t44 IS MSDS WAS WRITTEN TO COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD

• • • 4******44**%44****************4**4**0'*0**0***44*******%****A*4*

APPENDIX',REGULATORY INFORMATION TENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE

. 2CTIVE DATE OF TH1S MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE.

CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT.

.TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY

.REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT:

APPLICABLE

.RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE, THE RCRA HAZARDOUS WASTE "NTIFZCATION NUMBER IS'OT APPLICABLE

.DOT HAZARD/UN5/ER GUIDEC IS: NOT APPLICABLE

.CALIFORNIA SAFE DRINKING WATER ACT (PROPOSITION 65) MATERIALS: NONE.

.SARA SECTION 302 CHEMICALS: NONE

.SARA SECTION 313 CHEMICALS:-NONE

.SARA SECTION 312 HAZARD CLASS: PRODUCT IS NONHAZARDOUS UNDER SECTION 311/312

.MICHIGAN CRITICAL MATERIALS: NONE A/HMIS : HEALTH 1 ; FIRE 1 REACTIVITY 0  ; SPECIAL - NONE ; PE B

BETZ LABORATORIES, INC.

4636 SOMERTON ROAD, TREVOSE, PA 19053 II PRODUCT: POWERLINE 3450 May 17, 1994 AQUATIC TOXICOLOGY E

Fathead Minnow 96 Hour Static Acute Bioassay LC50: 19062 mg/L No Effect Level: 8700 Daphnia magna 48 Hour Static Acute Bioassay LC50: 3558 mg/L No Effect Level: 2400 Bluegill Sunfish 48 Hour Static Screen 08 Mortality: 4000 mg/L BIODEGRADATION NO DATA AVAILABLE MAMMAL'IANTOXICOLOGY Oral LD50 RAT: 16,000 MG/KG Dermal LD50 RABBIT: 2,000 MG/KG

BETZ LABORATORIES,INC.

4636 SOMERTON ROAD, TREVOSE, PA. 19053 BETZ MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE (HEALTH/ACCIDENT) 800-877-1940 (PAGE 1 OF 3)

RODUCT 'RE-FILM 108L EFFECTIVE DATE:09-17-92 PRINTED: 09-17-92 REVISIONS TO SECTIONS: 1 RODUCT APPLICATjON  : PRE-CLEANING/PRE-FILMING AGENT.

---

SECTION 1-----------HAZARDOUS INGREDIENTS FORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS'EL'S AND TLV'S FOR SPECIFIC ODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD IS ISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE CHRONIC HAZARDS OF THIS FORMULATION.THIS PRODUCT IS SUBJECT TO THE "NNSYLVANIAAND NEW JERSEY WORKER AND COMMUNITY RIGHT TO KNOW LAW.

SODIUM ACID PYROPHOSPHATE(SAPP)."**CASC 7758-16-9'YE IRRITANT; PEL:NONE; TLV:NONE; NHAZARD INGREDIENTS: WATER (CAS5 7732-18-5) TETRAPOTASSIUM PYROPHOSPHATE (CASQ 320-34-5)

---SECTION 2-----------TYPICAL PHYSICAL DATA-AS IS(APPROX.) 7.6 ODOR: NONE

.PT.(DEG.F):> 200 SETA(CC) SP.GR.(70F): 1.178 POR PRESSURE(mmHG):

SC cps70F: 13 ND VAPOR DENSITY(AIR=.

%SOLUBILITY(WATER):

1)'D100.0 AP RATE: ( "1.00(ETHER=1) APPEARANCE: COLORLESS YSICAL STATE:LIQUID FREEZE POINT(DEG.F):, 26.00

---SECTION 3-------;---REACTIVITYDATA ABLE.MAY REACT WITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK EAN-OUT CATEGORY

'B'RMAL DECOMPOSTION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES.

BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3)

PRODUCT : PRE-FILM 108L

---

SECTION 4---------HEALTH HAZARD EFFECTS-UTE SKIN EFFECTS *"* PRIMARY ROUTE OF EXPOSURE MAY CAUSE SLIGHT IRRITATION TQ THE SKIN ACUTE EYE EFFECTS "**

MODERATELY IRRITATING TQ THE EYES ACUTE RESPIRATORY EFFECTS *"*

MISTS/AEROSOLS'AY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT CHRONIC EFFECTS OF OVEREXPOSURE***

NO EVIDENCE OF POTENTIAL CHRONIC EFFECTS.

MEDICAL CONDITIONS AGGRAVATED ***

NOT KNOWN SYMPTOMS OF EXPOSURE ***

MAY CAUSE REDNESS OR 1TCHING OF SKIN.

---

SECTION 5-------"---FIRST AID INSTRUCTIONS-SKIN CONTACT "**

REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH A LARGE QUANTITY QF SOAP SOLUTION OR WATER FOR 15 MINUTES EYE CONTACT***

IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES. IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE"**

REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR.APPLY APPROPRIATE FIRST AZD TREATMENT AS NECESSARY INGESTION*"*

DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DILUTE CONTENTS OF STOMACH.INDUCE VOMITING BY ONE OF THE STANDARD METHODS.IMMEDIATELY CONTACT A PHYSICIAN

---

SECTION 6-----------SPILL,DISPOSAL AND FIRE INSTRUCTIONS-----------

SPZLL INSTRUCTIONS""*

VENTILATE,AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE ZN WASTE DISPOSAL CONTAINER.THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS.

FLUSH AREA WITH WATER. WET AREA MAY BE SLIPPERY. SPREAD SAND/GRIT.

DISPOSAL INSTRUCTIONS*"**

WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS ZS)-

INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS **

FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE). PROPER FIRE EXTINGUISHING MEDIA:

DRY CHEMICAL,CARBON DIOXIDE,FOAM OR WATER

BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3)

RODUCT : PRE-FILM 108L

---

SECTION 7-----------SPECIAL PROTECTIVE EQUIPMENT; OTECTZVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134.USE S TORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS.

"NTILATION PROTECTION"**

ADEQUATE VENTILATION ECOMMENDED RESPIRATORY PROTECTION***

IF VENTILATION IS INADEQUATE OR -SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH DUST/MIST FILTERS.

COMMENDED SKIN PROTECTION***

RUBBER GLOVES WASH OFF AFTER EACH USE REPLACE AS NECESSARY.

COMMENDED EYE PROTECTION***

SPLASH PROOF CHEMICAL GOGGLES

--SECTION 8-----------STORAGE AND HANDLING PRECAUTIONS ORAGE INSTRUCTIONS"**

KEEP CONTAINERS CLOSED WHEN NOT IN USE.

DO NOT FREEZE. IF FROZEN, THAW AND MIX COMPLETELY PRIOR TO USE DLING INSTRUCTIONS **

NORMAL CHEMICAL HANDLING

+*4k*********WW%*************kk***************%****************

IS MSDS WAS WRITTEN TO COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD

• • • 4'4*0**4********4*********************4**********************

APPENDIX: REGULATORY INFORMATION E CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE FECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE.

CHANGES ZN REGULATIONS WILL RESULT ZN UPDATED VERSIONS OF THIS DOCUMENT.

ALL COMPONENTS OF THZS PRODUCT ARE LISTED IN THE TSCA INVENTORY R ORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT:

NOT APPLICABLE

~ RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE, THE RCRA HAZARDOUS WASTE ENTIFZCATION NUMBER ZS:NOT APPLICABLE

.DOT HAZARD/UNQ/ER GUIDEQ ZS : NOT APPLICABLE

.CALIFORNIA SAFE DRINKING WATER ACT (PROPOSITION 65) MATERIALS:NONE

.SARA SECTION 302 CHEMICALS:NONE

.SARA SECTION 313 CHEMICALS:NONE

.SARA SECTION 312 HAZARD CLASS'PRODUCT IS NON-HAZARDOUS UNDER SECTION 1/312

.MICHIGAN CRITICAL MATERIALS: NONE FPA/HMIS : HEALTH 1; FIRE .- 1; REACTIVITY - 0; SPECIAL - NONE; PE - B

BETZ LABORATORIES, INC, 4636 SOMERTON ROAD, TREVOSE, PA 19053 PRODUCT PRE-FILM 108L May 17, 1994 AQUATIC TOXICOLOGY Rainbow Trout 48 Hour Static Screen 08 Mortality: 1000. mg/L Daphnia magna 48 Hour Static Screen 04 Mortality: 500-mg/L BIODEGRADATZON NO DATA AVAILABLE MAMMALIANTOXICOLOGY Oral LD50 RAT: >2,000 MG/KG Note - ESTIMATED VALUE Dermal LD50 RABBIT: >2,000 MG/KG, Note - ESTIMATED VALUE

8- i1;S t.

jOHNSTON POLYMER'OMPANY, INC; p.o, Sox 86 ~ Manvel, Texas 77878 ~ Phone (713) 489-9628 ~assoc 0 log x MATERIAL SAFETY DAT SH E SECTION I: PRODUCT INFORMATION PRODUCT NAME: J-POLY 101C CHEMICAL FAMILY: Sodium Polyacrylate CAS NUMBERS 9003-04-7 EMERGENCY TELEPHONE NUMBERS 713-489-9528 or 713-980-7524 CHEMTREC (for emergency invo1ving chemicals): 800-424-9300 EPA HOTLINE: 800-535-0202 SECTION IZj HAZARDOUS 'INGREDIENTS HAZARDOUS COMPONENTS: None SECTION ZIIi PHYSICAL DATA MOLECULAR WEIGHT! 1000 pH (as is); 7.0 PERCENT SOLIDS'0 VISCOSITY, Cp at 77 F i 1200 PERCENT VOLATILE (Water)i 50 SPe G. at 77 F: 1.36 SOLUBILITY IN WATER< Comp1ete APPEARANCE AND ODOR: Viscous 1iquidt clear to hazy No characteristic odor SECTION IV: FERE AND EXPLOSION HAZARDS FLASH POZNTs None EXPLOSIVE LIMITS~ None EXTINGUISHING MEDIA: Not applicable; product will not burn NFPA CODES'EALTH 08 FLAMMABILITY "

07 REACTIVITY 0 SECTION V: HEAITH HAZARD DATA Toxicologica1 Information (Range Finding Studies):-

Rat, Acute ora1 LD50 greater than 5g/kg Rabbit, .Acute, dermal LD50 greater than 5g/kg Rabbit< Eye irritation slight Rabbit, Skin irritation none Daphniai 48 hour5.555556e-4 days <br />0.0133 hours <br />7.936508e-5 weeks <br />1.8264e-5 months <br /> LC50 greater than 1000 ppm.

Sunfish, 96 hour0.00111 days <br />0.0267 hours <br />1.587302e-4 weeks <br />3.6528e-5 months <br /> LC 50 greater than 1000 ppm Trout, 96 hour0.00111 days <br />0.0267 hours <br />1.587302e-4 weeks <br />3.6528e-5 months <br /> LC50 greater than 1000 ppm Product does not contain carcinogens sub)ect to the reporting requirements of SARA TITLE IIZ-May cause irritation of skin and eyes. For eye contact, flush with water for 15 minutesg get medical attention if irritation persists. Mash skin with soap and water.

HMZS RATING HEALTH 0 8 FLAMMABILITY 0 P REACTIVITY 0

SECTION YXs REACTIVITY DATA Product is stable> vill not undergo hazardous polymerization.

SECTION VII: SPILL OR LEAK PROCEDURES Dilute spill with small amount of water and use absorbent. Tand fill in incinerate contaminated absorbent. Carry out disposal in accordance with federal, .state and local .regulations.

I SECTION YIII: PROTECTIVE EQUIPMENT REQUIRED Respiratory protection is not required- Use rubber gloves, boots and apron for direct handling. Use face shield or goggles for eye protection.

SECTXON IX: SHIPPING INFORMATION/OTHER COMMENTS DOT IDENTIFICATXON NUMBER: N/A DOT LABELS REQUIRED: None REPORTABLE QUANTITY! N/A BxLL QF LADING DEscRxpTxoNt cleaning/Mashing compound@ NoI PRECAUTIONARY MEASURES: Keep away from heat, or open flame. Use with adequate ventilation. Do not breath vapors. Avoid prolonged or repented contact with skf.n.

DEFINITIONS NFPA RATING: System adopted by National Pire Protection Association to identify hazards in a fire situation:

0 ~ No known hazard 3 ~ Severe hazard 1 = Slight hazard 4 = Extreme. hazard 2 = Moderate hazard HNxs RATING~ Hazardous Materials Identification system adopted by the National Paint S Coatings Associations 0 ~ Minimal hazard 3 ~ Serious hazard 1 ~ Slight hazard 4 = Severe hazard

~ = May be chronic 2 ~ Moderate hazard CAS NUMBER: Chemical Abstracts Service Number SARA: Superfund Amendments Reauthorization Act of 1986 (also referred to as the "Emergency planning and Community Right To Know Law of 1986")

DOT: Department of Transportation Revised Feb. 1< 1990 ..Supercedes May, 1985

86-89-94 18:29AM 41Z7778643+ 6187747337 u 2 MATERIAL SAFETY DATA SHEET ks aa +a~ P.O. Box 1346 Pittsburgh, PA 15230-1346 24 Hour Emergency Telephone-(412)777-8000 Section 1. PRODUCT IDENTIFICATION PRODUCT NAME: Qe~uard 4813 (formerly called RP-813)

CHEMICAL DESCIUPIION: Aqueous solution PRODUCT CLASS: Surface finishin MSDS CODE: OC42-0642-93 Section 2. HAZARDQUS INGREDIENYS AND EXPOSURE LIMA'S CAS  % by Rmical N N~u 3&RhL QS~~

Potassium carbonate 58448-7 20 None established None established Section 3. HAZARDS IDEN'rIPICAYION WAIVING!

May cause eye.!rritabon.

Repeated or prolonged contact may cause skin irritation.

• • • • • • • • • • • • • • • • • • • • • • • • • • • • • A**************************%

PRIMARY ROUTES OP ENTRY: Eye and skin contact TARGET ORGANS: Eye MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: No data available, POTENTIAL HEALTH EFPECIS:

EYE CONTACT: This product may produce irritation upon contact with the eye.

SKIN CONTACI: 'Prolonged or repeated exposure may cause slight skin irritation. No data ls avaoable to suggest that this product may produce an allergic skin reaction or be absorbed through the skin in haratful amounts.

MSDS Code: OC42~2-93 Page 1 Issue Date: 2/28/94 Continued on Page 2

86-89-9a <8i ZBCW 41277'78&I3e 6187'74"/33 /

MATFRIAI. SAFETY DATA SHEET INGESTION: Swallowing this product may irritate the gastrointesbnl tract and cause nausea ann Vommng.

INHALATION: This product is not expected to present an inhalation hazard.

SUBCHRONIC, CHRON':

No applicable informabon was found concerning any potential health effects resulting from subchronic or chronic exposure to the product.

CARCINOGENICXIY NTP:

No ingredients listed in this section" IARC.

"No ingredients listed in this section'SHA:

'No ingredients listed in tMs section'ection

4. FIRSY AID MEASUKBS EYE CO%I'ACT: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.

Seek medical aid.

SKIN CONTACf: Not expected to require first aid measures.

INGESTION: Not an expected route af overexposure.

INHALATION: Not an expected route of overexposure.

Section 5. FXRRMGKIING MEASURES PLASH POINT: None This product is not by deflnltion a "flammable )ibid" or a "combustible liquid".

LOV/ER FLAh9vhQ3LE LIMIT: Not availab1e UPPER FLAMMABLEUMT: Not available AUTO-IGNITIONTKh6%RATUREi Not ava0able HGTNGUISHING MEDIA'. Use extinguishing media appropriate for the surrounding fire.

FIRE-FIGHTING INSTRUCTIONS: Exercise caution when fighting any chemical fire. A self~ntained breathing apparatus and protective clothing are essential.

FIRE dc EXPLOSION HAZARDS; No unusual hazards.

DECOMPOSITION PRODUCISi Thermal decomposition or combustion may produce carbon monoxide, carbon dioxide, disodium oxide, dipotassium oxide and sulfur oxides.

NFPA RATINGS: Health 2 HammabQity ~ 0 Reactivity 0 Special Hazard None Hazard rating scalsi 0~ Minimal I Slight 2~Moderate 3 Serious 4~Severe MSDS Code: OC424642-93 Page 2 Issue Date: 2/28/94 Continued on Page 3

SENT BY- 86-89-94 18:38AM 4127778643+ '6187747337 ¹ 4 MATERIAL SAFETY DATA SHEET Sedion 6. ACCIDENTAL RELEASE MEASURES I

STEPS TO BE TAKEN IP MATERIALIS RIH3~ED OR SPILLED: Wearing appropriate personal pr5tective equipment, contain spill, collect onto inert absorbent and place into suitable container.

Section 7. HANQLING AND STORAGE HANDLING: Avoid contact with eyes.

Avoid prolonged or repeated contact with skin and clothing.

with adequate ventilation. 'se Wash-thoroughly after handling. Keep container closed when not in use.

STORAGE: No specific information.

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

. PERSONAL PROTECTIVE EQUIPMENT:

EYE/PACE PROTECTION: Chemical splash goggles SKIN PROTECTION: Chemical resistant gloves recommended as a good industrial hygiene practice.

RESPIRATORY PROTECIION: Normally not required.

GINEERING CONTROLS: No specific recommendafions.

WORK PRACIICES; An eye wash station should be accessible in the immediate area of use.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES BOILING POINT: v 230'P SOLUBILTIYIN WATER: Complete VAPOR PRESSURE: Not available SPECIPIC GRAVITY: 1.18 - 1.20 I 25'C VAPOR DENS1TY (air~ 1): Not available pH: 12.5

% VOLATILEBY WEIGHT: 80 (water) FREEZING POINT: Not available APPEARANCE AND ODOR Clear, brown liquid.

Section 10. STABILITYAND RHACITVITY CHEMICAL STABIUTY: Stable HAZARDOUS POLYMERIZATION:WOl not occur mONS TO AVOID: No specific information.

MSDS Code: 0C4246-02-93 Page 3 Issue Date: 2/28/94 Continued on Page 4

SENT BY- 86-89-94 18: 38At'1 4127728643+ 6187747337 MATERIAL SAFETY DATA SHEET INCOMPATIBIUTY: Strong acids DECOMPOSITION PRODUCING; Thermal decomposition or combustion may produce carbon monoxide, carbon dioxide, disodlum oxide, dipotassium oxide and sulfur oxides.

Section Il. TOXICOLOGICALINFORMATION ON PRODUCT:

No information avaQablc on the foxxnulated product.

ON INGREDIENIS:

Oral LDso Derxnal LDg) Inhalation LCso

~rabhlQ Potassium carbonate 1870 mg/kg Not available Not available Section 12. ECOLOGICAL INFORMATION ON PRODUCT:

No information ava0ablc on the formulated product ON INGREDIENTS;

'No ingredients listed in this section'ection

13. DISPOSAL CONSIDERATIONS RCRA STATUS: Discarded product, as sold, would be considered a RCRA Hazardous Waste based on the charactexistic of coxrosivity. The EPA Hazardous Waste Nuxnber is D002.

DISPOSAL: Dispose of in accordance with local, state and federal regulations.

Section 14. TRANSPORT INFORMATION DOT CLASSIFICATION:

Class/Division: Not restricted Proper Shipping Name; Not applicable Label: None, Pacldng Groupc Not applicable ID Number: Not applicable Section IS. REGULATORY INFORMATION OSHA 'Hazard Communication Status: Hazardous TSCA: The ingredients of this product are listed on the Toxic Substances Control Act ESCA) Chemical Substances Inventozy.

MSDS Code: OC424642-93 Page 4 Issue Date: 2/28/94 Continued on Page 5

SENT BY- 86-89-94 18I31AN 4127278643+ 618724'7337 n 6 MATERIAL SAFETY DATA SHEET I

CERCLA reportable quantity of EPA hazardous substances in product;

'No ingredients listed in this section'roduct RQ: Not applicable (Notify EPA of product spills exceeding this amount.)

SARA TITLE III Section 302 Extremely Hazardous Substances:

No ingredients listed in this section'ection 311 and 312 Health and Physical Hazards:

Immediate Delayed IIlre Pressure Reactivity

[yes] [no] [no] [no] [no]

Section 313 Toxic Chemicalsl Chemical N CAS S No ingredienbs listed in this section Section 16.. OTHER INPORMA'DON HMIS RATINGS: Health 2 Plammability ~ 0 Reactivity 0 Personal Protective Equipment A Hanud rating scale: 0-Minimal 1 Slight 2 Moderate 3-Serious 4 Severe MSDS REVISION

SUMMARY

Reason for reissue; Update to new format.

Mhlle thl ~ Inforeastlon and racoaeonchtlons sat forth herein are believed to be accurate aa of the date hereof, CALCOH CORPORATIOK HAKES HO MARRAKTT lllTH RESPECT HERETO AHO OISCLAIMS ALL LIASILITT fROH RELIAKCE THEREOK PREPARED BY: K.O. Martinelli MSDS Code: OC42-0642-93 Page S Issue Date: 2/28/94 Last Page

JUt,'-Ill-sh rr'l 1: la t'ki blLNAKl llhi,l l llttlllhL ri'... Jlv. Sic DOG id'"

C->o.339 laf page MhTERXAL 5A~-TY DATA SHEET Prinl.ad 821 oo/" 0,

) '9q For .oatinc-.=, Res's ano Pe'ate 'aterial awaaacaaaaaaaaaaaaaaaa~caaaaaaaaaaaaaa a~ acaaaaaaaaacraaaaaaaaaaaa-=aa Rev="ed

~

SECTION I PRODUCT IDENTEFXCA XON Manufacturer: STEWART-HALL CHEMICAL -'CORP. Enf orna Bmercency ti on Phone: 92 4-6 68-6 3(

Phone: 800-424-93~

222 WASHINGTON S REE. CHEMTREC Phone: 800-424-93a MT VERNON Nv 10553

! Hasard Rati,ngs! Health Product lass:  ! none -> extrcme Fire Trade Name: COIL-RITE 0 ---> 4 Reactiv tv

.Product Code  : CGSOBOGD  !

otect'n-0 C.A.S. Numbe  : MIXTURE  ! Person al P Prepar ed Title By: HARVK'Y GROD.7ESK

TECH¹CAL DXRECTOR D.O.T, Ha a d C'ass : N!OT HAZARDOUS lJN Proper chipoin+ Name; COMPOUND! CL ANXNG Technical Name;

~aaaaaaaaaacaaaaaaaaacaaaaaaacaacaaaaraaaaaaa--aaaaaa. aaaaac aaaaaa aaaaa<aai SECT ON I HAZARDOUS XNGR"DXENTS Weiaht Exposure Limits ---- V!

Xrg edier.ts GAS 4F ACGXH/TLV OSHA/PEL am SODIUM HETAS LXCA E I 3.01 mg/Ã3 2 mg/N3 0 SULFAMEC AC:D 2.84 0 ALCOHOL GLYCO1'UTyL =-THER 111- l6<<2

,1. 94 400 ppm STEL =a ~no pp~

2 24 N E 400 Soo PPM ppm o~m

>>.E.~~ 0 STEL a NA N.E.

ALL Enqredierts in th's product are li ted in hc T.S,C.A.

NA. N.ED Inventory.

N! ~ I,No~ Estab j i shed aaaaaaaa aacaaaaaaaaaaaaaaaaaccaaaaaaaaaaacaaaaaaaaaaa aaacaaaaccaaaaa-aaa~aa SECTION XXX PHYSICAL DA'A Bo.'ing Range: 212 Vapor D n ity! Heavier than Air.

Evap. Rate: aster thar. n-B tyl Acetate Licuid Density: Heavic than Wate Volatiles vol 4 80 Wgtb 89.2 Wgt per gallon: 8.66 Pounds.

Spec Gyavi t y, 1.03962 Appearance: GREEN LIQUID. PLEASAN ODOR.

V.O.C.-'.3 aaaa aaaaaaaaaacaaacaaa aaaa aaa caaca aaaac aaaa a caaa caaaaaaaaaa1caaa SECTION XV - VIRE AND EXP OSXObi HAZARD DATA c3.ammab 'ity Class: NA 8'lash Point: NONE F TCC LEL: 1.2.0>> UEL: '.'7

-EXTINGUISHING REDIA-NOT REQUIRED

-SPECEAL FEREFEGHTING PROCEDURES-NONE REQliXRED

JUtJ;lU-SS J'J',J i: I'i r~ >>J'.War,J JJJ'iJ.L t JJJ'.m! iAJ. J'A). tlV. Jl4 bbU /5b" t'.->o.339 Z.sl 3 Page: 2 STEWART-HAL'. CHEMICAL CORP. 82.8 Ma"eries Sa ety Data Sheet f nr i COt J;.-RITE~ CG5080GD >

ss aaaaasaasaaaaaaaaaaaaaaasasaass aaaasassssssa s e S sssassasaaassasaaassasssss SECTION IV - "~~~ hh".'XPLOSION HAZARD DATA (cont

-UNUSUAZ FIRE Kc EXPLOSION HAZARDS:

NQME FLL~BXLXTY'mOmE NQ) saasaasaaaaaaaaassssssssssaaaaaaaasaaaaaasssssssssssk aa aaassasassssaasassas SECTZQh! V TQ}(ZCOLOG CAL PROPERTIES

-PEFLGSSXBX E EXPOSURE EVEL: I NO."JE ESTABLISHED

-EFFECTS OF CHRONIC OVKEMXPOSURE-ZF SWALLQWED MAX CAUCs NAUSEA AND BURN MUCQUS MEMBRANE, KEEP QUT OF EYES. CON ENTRATED PRODUC IS CORROcIVE TQ EXES,

-FIRST AZD:

EYES.. FLUcH HZTH WATER FOR ~5 MINUTES. ZF IRRITATION PERSZSTc SEE PHYSICIAN.

SKIN: FLUSH HITH HATER.

INGESTION: CON ACT PHYSIC AN IMMED ATEL . COIL-R TE ZS ALKALINE.

-EFFECTS OF ACUTE OVEREXPOSJJBE:

MAY IRRITATE SKZiV. COR'ROSIVE TQ EYES.

-RQU E OF ENTRY SKIN CONTACT, EY CONTACT, ZNGEcTZON

-EX SU .E LIMITS NONE ESTABLISHED.

-I TANCY OF PRODU T J".I LD

-SENSITIZATION TO PRODUCT hJQh! f.

-CARCINOGENICITY NON~:

-TERATOGENICZTY hfQNE

-REPRODUCTIVE TOXICITY NONE mrrAGENZCZTY NONE

-SYNERGISTIC PRODUCTS UNKhJOHNJ ass aaasaasaasa ss saaa as aaaasaaaaaaasassaassaa asaaa s saa asaiiaas s ss s saassssss SECT Oh! V. PREVENTIVE MEASURE REACTVZTY DATA 5TABLZ"'X: [,'n ta HAZARDOUS PQLvMERIZATZQN:

e

[

fv> Ssqig1 May oc=ur e

[x] Will not occur

-ZNCQMPATXBZLXTX DO NQT MZ.( HZTH ACID ..

-CONDITIONS TO AVOID:

NONE

C- lO. EqQ 3oFQ Page! 3 S EWART-HALEs CHEM CAL COPP.

Mate i el Sa e v Data Shee cr: roE -!E-.E ( 0 5 08OGD )

QXS

<<<<a<<a<<a <<aaaaaaaa<<<<a<<<<a<<a<<a<<a<<<<a<<<<aa<<<<<<<< 1 SECTION VI - PREVENT VE MEASUR= BEACTIV TY DATA (con .)

-HAZARDOUS DECOMPOSITION PRODUCTS:

!!ON=

<<aa<<a<<a<<<<a<<a<<a<<<<a<<<<a<<<<<<a<<a<<a<<a<<a<<<<a<<a<<a<<a<<a<<a<<a<<a<<a<<a<<<<avant<< a4 4 <<<<

SECTION VII PREVENTIVE M ASURES SPILL CB :EAK PBOCEDUPES

-STEPS TO BE TAKEN XN CASE MATERIAL XS RELEASED OB SPXILED FLUSH WITH PLENTY OF WATFB.

-WASTE DISPOSAL IN ACCOPDANCE WITH LOCAL, STA.- OB . EDEBAL REGULATION YETHOD-'ESPOSE ssan<<<<<<aaa<<aaaaaaa<<aaaaaaaaaa<<aaaaaa<<a<<aa<<<<<<<<aaaaaaaaaaaaaaava<<aa<<aaaa<<

SECTION VIII PB V NTIVE M-A ' P CIAL . RO'EC-EON ... OBMA ION

-RESPIRATORY PROTECTZON-NIOSH APPROVED FOR OBGANICS IN ENCLOS D"AREA.

-VENTILATION WOBMAL VENTILATION.

-PROTECTXVE GLOVES:

BUBB-B OR NEOPRENE GLOVES.

-EYE PROTECTION!

GOGGLES.

~ER PROTECTIVE EQUIPMENT:

NONE

<<<<a<<a<<a<<a<<a<<a<<a<<aaa.aaaaaaaaaa<<aaaaaaaaaaaa<<aaaa<<<<<<a<<a<<aa<<<<<<aaa<<aaa<<aag a-<<a<<a SEC ION IX PREVENTIVE MEASU .ES SPECIAL PRECAUT ONS

-PRECAUTZONS TO BE TAKEN XN HANDLING AND STORING-KEEP OUT OF BEACH OF CHI'REN ~ KEEP FROM FBE..ZING.

-0TH~~ PBECAUTZONS-AVOID PROLONGED CONTACT WITH SK""!.

00 "!OT MIÃ WITH 0 HER CHEMICALS. aaaaaa<<a<<<<aaa<<<<<< '<<a<<<<

a<<a<<<<a<<<<D a<<aa<<a<<a<<a aaaaaaaaaa<<a<<aaaaaav<<<<<<aaa<<aaa<<

SECTION 2. ADDITIONAL B .GULATOBY INFORMATION

-SARA TITLE IXI SECTXON 313: s!! Sect tc the This pvoduct conta'ns the foow-'ng toxic chen'cals ieportirg equiremerts of sectioncf 3i3 of the Eme<<gency Plnnn ng nd Comms nity Right To Know Act 1986 an o 40 CFR 372:

Pe cent by CAS tl Cher!ical Name None

JU'i-lU-B4 i'i'i I." lO i'tl ~'ih>YAK'i iiPLL Viihthl u;".L i'A>. iiV. Pih Obb lv'6 g- to.394 age 5"EWART-HAr- -HEY.-CAL CORc ~ q.r4 Ov R TE,C0.980GD)

RRCSSS CSS Saaaa 4Rsg44g 44 RR sl C C h4 hhC FL SS+4 sg, 825'SSSDLsggg CCS4$ SO C %1, SECT ON X ADD TXONAL REGUlATOR ZN-"OBSTAT ON , 'nnt. )

PROP 65 ( CARClNOGEM'): r WARN:NG: .hi product, contains a chen:ical i:no~a to the oL'aliforn'- to .."se ancer.

CAS~ Chemical Naze None

-PROP 65 ~i TERATQGEN )-

WAR¹NG: Th. s p oduct con"ain a cher.ica':now".. Co he state cf California to cause bi th defects o o"he. eproductive harm, Che.-..i ca =

Name None

-P ~ 65 (BOTH CARClÃOSEN AND TERATOQEN3 T WARNING: This product may conta'n a che...'cal knom to the state of Califo=nia to cause cancer or birth defects or other reproductive har...

CASO Chemi cal Name None

Form Aoorcwea U.S. DEPARTMENT OF LA8OR OMB No. 44-Rlaa7 Occupational Safety and Health Administration

- r cl MATERlAL SAFETY DATA SHEET Re()uireo under USOL Safety and )iealth Regulations for Ship Repairing, Shiobuilding', and Shiohreat(ing (29 CFR 1915, 1916, 19171 I

SECTION MANUFACTURER'5 NAME EMERGKNCe I KLEPHONE NO BY+ PAS I IVTEP<VAT I CHAL CORPORAT I CN 616 875-723(I AooREss (tyumber, street. city, state, aaa zIP collej 6350. 76ih Avenue . iceland. Alichizan 49()64 CHKMICALNAME ANO SYNONYMS I TRAPEJRAME AblO SY,NSSNYMS BY+PAS DECONTAXIIIVATI CN CHEMICAL I BY~PAS ( F ) I 000 CLEANER I DEGREAS ER ( ALKALI iVE ) I PRQPR I ETARY SECTION ll - HAZARDOUS INGREDIENTS PAINTS, P RESERVATIVES. St SOLVENTS TLV ALLOYSAND META(.LICCOATINGS (Un(Is)

PIGMENTS BASE METAL I )

CATALYST I I AI LOYS VKHICI E l I I METALLICCOATtNGS 5OI VENTS FILLER METAL I I I Pt US COATING OR CORE FLUX AOOIT IVES I I OTHERS OTHERS TLV HAZAROOUS MIXTURES OF OTHER LIOUIDS, SOLIOS. OR GASES (Units)

SECTION III - PHYSICAL DATA BOILING POINT ( F.) 9 8 o {C) I SPECIFIC GRAVITY(H O~l) I .080 vApo R pRESSURE (mm H9.) I PKRCKNTI VOLATILE UNDET.

UVILIC I ~ I BY VOI.UMK( ~ )

VAPOR OENSITY (AIR~I)

EVA ORATION RATE UNDET ~

5OLUBII ITY IN WATER I CC(VPLE ItELY SOLUBLE APPEARANcE ANo oooR AOUA BLUE L!QJ I D 0/I TH MILD ODOR SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLAsH PoINT (Metnoo uteol FLAMMABLELIMIT5 Uet VC(VE EXTINGUISHING f.tKQIA t

5PECtAI FIRE FIGHTING PROCEDURES NONE UNUSUAL FIRE ANO KXP(.05IQN HAEAROS I't~ I (Continued on reverse side} Form OSHA-20 PAGE (1I Redo MOY ra MSDS&8 6/85

SECTION V - HEALTH HAZARD DATA THRESHOLD LIMITVALUE KFFKCTS OF OVKAEXPOSURE IRRITATING TO EYES KMERGKNCY AND FIRST AID PROCEDURES>

FLUSH WITH iVATER SECTION Vl - REACTIVITYDATA STABILITY

• CONDITIONS TO AVOID UNSTABI K STABLE INANE KIXOIVN INCOiYIPATABILITV.all4Mn>IIS rO >I>>OIdj INOiVE KNO'IVN HAZARDOUS DECOMPOSITION PRODUCTS CONDITIONS TO AVOID HAZARDOUS MAY OCCUR i POLYMERIZATION

> Wii L NOT OCCUR x SECTION Vll - SPILL OR LEAK PROCEDURES STEPS TO BE > KEN IN CASK MATERIALIS RELEASED OR SPILLKD FLUSH WITH WATER, WASTE DISPOSAL METHOD LOCAL S EiVER SECTION VI<I - SPEClAL PROTECTlON INFORMATION AKsPIRATDRv PRDTEc IDN (SPccI jP

~

rPPcJ SPECIAL vENTILATIDN ACCEPTP,BLE MECHANICAL(GCnenrif OTHEA PRoTEcTIvK GLovEs NOT NEEDED NORMAL SAFETY GLAS 5ES OTHER PAOTECTIVE EGUIPMENT SECTION IX - SPECIAL PRECAUTIONS'AECAUT!QNS TA BE TAKEN IN HANOI ING ANO STORING STORE UNDER 1(io'F) KEEP FROM FREEZING.

OTHER PAECAUTIONS PAGE (21 Form OSHA-20 Aey. May lZ

MATERlAL.SAFETY DATA SHEET

.SECTION I aRODUC. NAME QR NUMBER BY+PAS (F) 1000 VIANUFA~iRER'S NAME EMERGENCY TELEPHONE NQ.

o 4 S I NTERNAT I CNAL CCRP (616) 875-7230 ADDRESS INucneet. Street, Citv, 5 tare anti Zio Cartel 6350 t 76 t AVENUE;:EELAND. MICHIGAN 9 6~

.",AZAROOUS MATERIALS DESCRIPTION AND PROPER SHIPPING NAMEI48 CFR 172.101) i HAZARD CLASS (48 CFR 17Z.1O1)

ACNE I I%ONE "CHEMICAL FAMILY FORMULA LESS CL~4NER--DEGREASER (ALKALIS'E)  ! PPOPR I ETARY THAN SECTION II INGREDIENTS (Iist all ingredients) ~s. NQ.

ALKYL ARYL POLETHER ALCCHOL I 9036-19-5 I 1 PHOSPHATE ESTER POTTASSILIM SALT FORUM I I.O-R1387 IOF Tt<Po (TEIRAPOTASSIL%1 PYROPHOSPHATE) I 7320-3II-5 I

<C I L"".vl VIATAS I LCATE. ANHYDRCLtS I 6330-92-0 20%

~'iV - DPM (D I PROPYLENE GLYCOL METHYL ETHER) I 223~5 100%. more than 10'.O (WATER) ~

Less than !IIO,o I I I I PHYS ICAL DATA CN liNDIVIDUAL I I iNCREDI ENTS AVAILABLE UPON REOUEST.

PERCENTAGES SHC%N ABOVE ARE ONLY "BALL-PARK" PERCEiViAGES, BECAUSE BY+PAS IS A PROPRIETARY FORtviULA, EXACT PERCFNTAGES CPPWOT BE GIVEN.

MSDS-13 6/35

)'NEILL INDUSTRIES INC TEL No.2l5-535-6007 3un 6 94 9:40 No.005 P.02 MATERIAL SAFETY DATA SHEET ORGANIC ORANGE axxaxxaxxaaaaxxrra a a a aaaaaax "TION I a axxxaa a IDENTIFICATION aaaa aaaraaraaaaa ANY NAME ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ r r O'eill Xndustxies, Znc.

5101 Comly Str Phila., Pa. 19135 NE NUMBER............. (215) 333-5700 RGENCY PHONE NUMBER... 800-255<<3924 ECTIVE DATE.......+... 4/1/89 XSED DATE ~ ~ ~ ~ ~ ~ ~ ~ rr ~ r 3/31/94 I

M CAL NAME ~ ~ ~ ~ ~ ~ ~ ~ r ~ ~ r Orange Distillate E NAME ~ ~ ~ ~

aarrxxaa

~ s ~ ~ ~ ~ ~ ~ ~ r ~ ORGANXC ORANGE a aaaaaa ' -- = aaaaaaaaaaaaaaaaaaaaaaaxaaa TION II axxxxxra

- XNGREDIENTS a a a ONENTS PERCENT TLV (Units) PROD. CAS f (9)-p-Methadiene >95% Not 5989-27-5 established ylphenoxy- <5% Not 26027-38-3 yethoxyethanol established axxaaxxaaaa a rxaxxxxaaa raa aa aaaa a r aaa aaaaaa TXON XXI PHYSICAL DATA s rxaxa aaxxxa aaxxa aaaa s a'a a ax LING Point(F)....,,... 175.5' UBX ITY IN: H20........ Emulsifiable E CE/ODOR.......... Clear colorless liquid, citrus odor CI GRAVITY (H20al). .85

~ ~ ~ ~ ~ ~ ~ ~ ~

xaaa aaa axxaaa

~ ~ ~ ~ ~ ~ ~ I ~ ~ ~

rxxx a r ~

arxxa a ax aarraxrxxaa TION XV FIRE AND EXPLOSION HAZARD DATA aaasraxxxxaxaaa axaKxar axr a axxaxaaa SH POINT.........-.... 115' Close'd Cup INGUISH MEDIA......... Use foam, dry chemical, or CO~

FIRE.-.....--........ Minimize breathing vapor or fumes. Cool fire exposed containers. Do not enter confined fire-spaces without proper protective clothing, including self contained air supply.

sUAL PIRE HAzARD...... Burning liberates carbon monoxide, carbon dioxide and smoke.

aaa axxa aaa aaa r aaaa TION V - HEALTH HAZARD DATA arrxaa ra aa aaa a aaa arxar R EXPOSURE EFFECTS.... Liquid may be irritating to eyes and skin. Vapor is irritating to throat. and lungs.

ST AID PROCEDURES...-. EYES; Immediately flush eyes with water for at least

=15 minutes. Seek medical attention immediately. SKIN; Wash with water, If irritation develops or persists seek medical attention. INHALATION; Remove to fresh air. INGESTION: DO NOT INDUCE VOMITXNG. Give large quantities of water. Get medical attention iminediat:ely.

aa aaa aaaa aaa aa raa -a a a aaa aa IO~ aaa REACTXVITY DATA xaa a aa aaa -a a a a aa XCA'L STABILXTY....... Stable

O'EILL INDUSTRIES INC TEL No.215-535-6007 Gun 6>94 9:40 No.005 P.OS MATERXAL SAFETY DATA SHEET ORGANIC ORANGE CONDITIONS TO AVOID...... Excessive heat and flames. Avoid strong oxidizin agents.

INCOMPATIBLE MATERIALS... Strong acids/ strong oxidizers DECOMPOSITION PRODUCTS... Carbon dioxide, carbon monoxide HAZARDOUS POLYMERXZATION. Mill not occur POLYMERIZATION AVOID.....

aassasaaaaaaaaaaaaaaa aaaaaassaa aaaaaaaaaaaaaa =

SECTXON 'VXI - SPXLL OR LEAK PROCEDURE aa a a as aaa a aaaaaaaa aaaaaaaaaaaa FOR SPILL ,............. ~ Absorb with inert material and dispose of in accordance with applicable regulations.

HASTE DISPOSAL METHOD.... Dispose of according to all local, state, and federal

~~~a+ssaa'a ==ssaaaassssaassa regulations.

assaaa a c s SECTXON VIIX SPECIAL PROTECTION a'aa aa a%aa aaaa aaa RESPIRATORY PROTECTION... None needed under normal conditions VENTILATION.............. Local PROTECTIVE GLOVES........ Rubber EYE PROTECTION.......... Chemical goggles ~

DTHER PROTECTIVE EQUIPMENTS . ~ ~ ~ ~ a ~ s ~ ~ ~ ~ ~

HANDLING AND STORAGE.. ~ ~ . STORE IN A COOL, DRYS MELL 'VENTILATED AREA.

KEEP CONTAINER CLOSED WHEN NOT IN USE.

KEEP AWAY FROM HEAT AND FLAMES.

USE WITH ADEQUATE VENTILATXON KEEP OUT OP REACH OF CHILDREN WEAR SAFETY GOGGLES AND RUBBER GLOVES WHEN HANDLING THIS PRODUCT.

s aaaaa aa aaaa aaaaa a = aaaaaaaaaa aaa SECTION IX SPECIAL PRECAUTXONS

~ saa ass>sisaaaaaa assassaa aaaa aaa = aaaassaaaaaaaa DOT SHIPPING NAME'S' LABEL REQUZRED ~ ~ ~ ~

~ ~ ~ Combustible liquid, n.o.s., NA 1993, PG IZI DOT ~ ~ > None required REPORTABLE QUANTITY (RQ)> N/A

.lA NUMBER ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ > ~ > ~ s ~ NA 1993 3N NUMBER. ~ ~ .... ~ ~ ~ ~ ~ .... N/A OMMENTS The information contained herein is furnished without warranty of an

<S.nd. Employers should use this information only as a supplement to other Lnformation gathered by them to assure proper use of these matexiale, and the safety and health of employees.

MATER1AL SAr-.ai V L)~W. ~l-I~L-I 4ia~

~

(E.aaanll ~ lly Slmllar lo Corm OSHA-20) Z:k r-io

. < 5'Y g'oirn(

SECTION I NAME idSA CMAhrw-BANITIciER II Mine Safety Appliances Company FORMULA CODE 8 5+ 9~03 600 Penn Center Boulevard McLETED b L. P . Devrosk Pittsburg' A l5235 gr. ro uc a e y HCY FHONE NO. 41 2-273-'5500

~ SECTlON ll INGREDIENTS

@AS NUMBERS MEXQ

.ACTXVE XNGREDIENTSs 54 '

SODIUM CARBONATE 497-19-8 42.2 TRXSODXUM PBOSPHATE 7601>>54-9 10 0 ALKYL (C14~ 50gg-Cl2~ 405; Cl6, 10M)

DIMETHYL BENZYL AMMONIUM CHLORXDES 139-08-2 2 5 INERT INGREDIENTS s 45.3 SODIUM TRXPOLYPBOSPBLTE 7758-29M SODIUM BXCAEKONATE ~ 144-55-8 MATER 7732-18-5 XSOME~G;C LINES AIeOHOLS (Cll-C15)

POLYETHOXY ETEKHOLS 68131-40-8+

ETKLHOL 64-17-5 ISOJ3OEQfKEi ACETATE 12S-12-2 SECTION ill - PHYSICAl DATA I POINT I~ F.) SPECIFIC OAAVITY(HgOw 1) 0 8 CAESSUAE (mm HO ) %VOLATILE bY VOLUME OEkSITY (AIR m t) EVAPOAATION RATE f NA IUTY IN WATER 00 l A UEOVS SOLUTION 9.5 - -10.5 RANCE iDOA FRAGRANT BLEND OF %HITE POWDER/

SECTION lV FIRE AND EXPLOSION DATA POINT {MaIhod uaaII) 40 FLAMMABLE LIMITS Lel.

NA UISHINO MEDIA MATER SPRAY FOG FOAM DRY C ~CAL CARBON DIOXIDE L, FIRE 48 PROCEDURES BLANKET FIRE WXTH EXTXNGUXSHIHG MEDIUM kL FIRE AHD PRODUCT XS NONREACTIVE .AND DOES NOT EQADXL SUPPORT

'lOH HAZARDS WAlPI'llPelt

~ ~ SECTION Y - HEALTH HAZARD DATA

~ ~

SKIN CL'INTACT WITH POWDER MAY'AUSE BURNS. FLUSH AFFECTED AREA WI CLEAN HATER EYE CONTACT WXTH POWDER MAY CAUSE CORNEAL BURNS. AVOID RUBBING BECAUSE WATER INSOLUBLE PARTICLES MAY SCRATCH CORNEA. IMMEDIATELY FLUSH EYES WITH CLEAN WATER WHILE HOLDING EYELIDS APART CONTINUE FLUSHING FOR AT LEAST 15 MINUTES OR UNTIL IRRITATION SUBSIDES CONSULT PHYSICIAN AS SOON AS POSSIBLE.

XNHAIATZON OF A LARGE ENOUGH, QUANTITY TO POSE A SIGNIFICANT HP~LTH B2~RD XS XMPROBABLE.

INGESTION OP POWDER Xs EuuQGVL OR FATAL. SHOULD INGESTION OCCUR, g MILK, RAW EGG WHXTE OR GELATIN SOLUTION, OR LARGE QUANTZTXES OF WATER, AVOID ALCOHOL CONSULT PHYSICIAN AS SOON AS POSSIBLE.

SECTION VI REACTIVITY DATA UN8TASLE CONDITION8 rhbILITY TO STASLE AVOID MAY OCCUR CONDITIONS RXARDOVS TO DLYMERIXATION WILL NOT. OCCUR AVOID AZAIIDOU8 ECOM POSITION UNDETERMINED AODVCT5 ICOMPATlbILITY OXIDIZING AGENTS IATERIALS TO AVOID) SOAP AND ONI SECTION VII - SPILL OR LEAK PROCEDURES rEp5 To bE TAKEN I CASE MATERIAL RELEASED OR 8PILLKD SWEEP Up

• STE DISPOSAL REMOVE TO SANITARY LANDFILL AWAY PROM WATER SUPPLIES ETHOD DESTROY EMPTY CONT SECTION VIII-SPECIAL PROTECTION INFORMATION

'ECIAL

~~NATORY NOT REQVXRED lOTECTION ECIAL

'IOTECTION NOT REQUXRXH)

FACIAL rE lOTECnON NOT REQUIRED SECTION IX - SPECIAL PRECAUTIONS

<<EGA L INDLINQ NOT REQUIRED RECAUTIDN5

%CLAL" NOT REQUIRED MINIMUM SHELF LIFE 6 MONTHS FOR rORAOE MAXIMUM SHFXF LIFE AVOID HIGH HUMIDITY AND STORE IN AECAVTIONS

~ ~ iv c tt ~w Ii s s shl1 ~ < plh PRGE.882 CHAN YKS 4 ~ll CN S Dl VX 4 STION ECSi CQAP'tWAT

~I~KNVAL AFFAIRe DKPARYiNQCT PoQo 60% 841 NRIOIIISo '$% 49603 C2isk 682 785 Nat4%XAL SAFETY'UOTA SreÃT fo PRCNQCT -

IOENTifINTRACITY ICATICN TRADE NAI46~ s ~ sos ~ os I RHPOAIIZ l6 1T LIOJXD CKEtllCAL FAtlZ LY et so I XANTHENK I TBt FAMILYe e s s ~ ~ es4 15 P COLOR ZN)KX NNIKo so 4 Cs I ~ ACID ttKD BM REVISION QATKse se ~~ s 01/03/89 LAST RBVZSZON DATK4 06/03/SS Ile NXNO NRNINQ LA88.

NAttt4 ZNQ!

ltAY CAUSK KYE IRRITATION HANDLE WITH CAltKe AVOX CONTACT THI 5 PttDDUCT 15 t4lT HAZAttDOUS AS DEt" XNSD 8Y THF Q3KA HIZAf CQlNUNICATIDN STANOIADs HMEVERe AS WITH CHEMICALS! HANDLE NI TH Cotta ~ AVOID KYK AN) SX,IN CQNTJCTe AVOID It@ALA(ION, OF OUSTS OR VIP'S ~ SASH I

THOROUGHLY AFTCtt HANlL, N Gs KEEP CONT A INKRS CLOSKDe

~aalu@ IMCaHlISNT4 I NCiREDIEtlT SDDIVlt HYDAQXIDE C 1340 V3~R) 4BO GXPOSU% LltlITSse eel 2 NQ/lQ CKILINQ lACtoZHP H

MIPXN HIII8 Kt I tC 1 Rs PI C I Vs PIOVSXCN SABA APPKAttANCKs e e ODGRs see ~ es

~s s sesesesol t oe I 4 OINK RtsD LIQUID QQQC 5P 1L I l4 PGI Nf ss s s s s 4 AQUKOMS l4BLTIHQ POZt4ies s ~ s ~ 4 '~11 C PHs ~ ~ ~ s ~ ~ es SOLUS ILIVY

~

IN see ~ s ee l NAT4%s 3LMSLK SOo5 +/ Oof PKC XF IC GRAVITY~ oe 4 el9 f Fl~ Al.a~$ 4QN OAT1 LISH POINT ~ oeooooot N/A AQilNUS LIllNASLK UNITSee oct tl/A XT INGLJISHXNCs l0KOIAS NATSQo PRY CHEMI CALe CO2 PKCI I

L. PROCEDURE

S at t WCVINC FINCisl NKQt SCSA NU5UAt HiZARDSe s os l N% KXPKCTKD PA COOK t HI 1 Qs 8! N OOSOe: XNTRACID ltHQDAtllNK eT L.IOUID tare 1 CCONTINUKO)

acr 1> 'e < a: iw r cVPl Qt /K G l &RALTAR PAGE.883 ae $ %&fIVITY{NTA P

STABZLITYeooeooeooo>> STABLE COND I TIONS TQ AVOX Deer roe ~ oeooe eeC. NNK POLYJIKRIZATIDNrorer ~ 1ILL 'NOT OCCUR CONQZ TIONS TO IVOZDoeeo oooo oooo or! NONE I NCONPATZ SILITYeo o r I lQtCK KNQN HAZARQOUS DECO'QSZ TI ONe ~ ~ ~ oo e NOT DKTGRNINKD Vile IKALTN HAZED DATA KFFKCTS OF QVHtBXPOSURK LIQVID ZN CONTACT WITH KYKS NAY CAVSK ZRQZTATIONo INTRACIO RHQDANZNK 1T LIOUZD 1AS TESTED IN A SATTKRY OF ZN VITRO hND IN yIVO NAi00ALIAN ASSAYS RKSlA.TINS=IN NKQ.IQZQIK OR LO1 LK1HiELS OF CKNDTOXIC ACTIVITY KVKN AZ VERY HIGH CONCENTRATIONS ltO KVZDKNCK OF IN VZVO QKNKTIC ACTIVITY WAS OSSKRVKD KITNKR ZN ~

TERMS. QF 5QNK %AARON lOICQQNVCLKZ OR SPKRN ASNQNIILITZKSe CQoN oDQLtQLh5 Kf ILo 'COJIPARATI VK IIN0l4ALIAN ZM VZ TRQ AND ZN VZle STVDZKS ON THK NMV'AQKNIC ACTIVITY OF 8447DNCZPK 1T~r lNITATZQN RESEARCH+ 1 18r 1%No I I? 125)

ZNTRACZD RHODANI W NT 1AS POSITIVE IN A SALMONELLA/jg~LZAN lCZCRQSONK ASSAY <IKSTNANN AND KOW88Lr SamaKNCKD. STATSO TmT ZNPMRZTZSS f979) ~ CeDOttCiLAS AS IN THK JNTACENZC KFFKCTS SEEN OQ ALTERNATIVELY THK QYK NAYChuSKO TXK Dra NAY NAVE

'OINT NUTAQKNa DOU6LAS FURTHER REPORTED THAT TAK INS THR BK h kl TGQETHKR FROID'IS STUDY e DATA RHODANZtK 13 APPEARS NT TO REPRESENT h lM4OR %ElTOXIC HAZARDr~

ROUTES OF EXPOSURES I IOtALATZQNS SKI Nc X IlWiCSTZDNI KYKS4 X S ICONS AND SYIIPTOIIS OF OV ERKXPOSVRKee re o NT ICNON JCEDI CIL CONDI TION5 6BNKRILLY AQORAVATKO 8 Y KXPQQJHKeo oo ro oe i NOT KNO1H CARC NTP4 NQ Ilk'Z ITY4 C IARCI NQ OSHA RK4iQLATKDf NO TOXICITY (ANIMAL)err ~ ooi ALD 25 6/KC DATA'RAL ILLATION l ANIMAL)~i lCl NO DAN DERMAL CANEIIAL]oo eo DATA EFFKCTS TQ KYKS l ANIIIAL]~ oo ~ 0 oooo or e le DATA SKIN IRRI TATINoe or I AN ZEAL)o ee oo o moo or 4 04) DATA f'Ice C

LC50 CLKTHAL)4 AODIT IONAi. PATAoo oo 4 IIQ/L 96HA SKK OVKRKXPOSMRK ASOVK VII!e CNSNORNCY ANO $ 1SOT ASO ZNHALATIQNrr eoe ro oo 4 IP INALKDe CWK TQ RtKSH AIRr ZP NKATHIIS IS 00604, INTRACIO NHODANINK 13 PAQK 2 C LIOMZP CONT ZN!50)

SEP 19 'BB 16: 15 FRON NCiK GIBRALTAR PAGE.884 l

DIFF ICULT ~ GIVE OXYGEk Ala SET NEO!Ca. ATTENTION RI QHT AWAYo CONTACT ~ e or ~ e or e FLUSH EYIS SZTH FLOW INQ WATER FQR AT LEAST ! 5 kZNLAES ~ Hpl DING KYKLIOS APART TO IRRIQATF TNZROUGHLYe QGT IKDZCAL ATTENTION RI4HTIONA A'WAYo SK! k CONT ACTo or or oo e WASH AFPKTKD SKIN AREAS THOROUGHLY WITH SOAP AND WATERe l F ZRR ITATION OEVELOPSe CONSULT A PHYS!Cl AN ZNGESTEON ~ ~ ~ . --.. VOlllTING ~ 4ET I k~ lATE ICEDI CAL ATTAINT XF.SWALLOWEO. DILUTE WITH WATER AND INDUCE NEVER 6IVE FLUIDS OR ItVCE VONZTIhKi IF PATIENT IS i%CONSCIOUS OR HAS CONVULSIONSe ZXe St&JAL PRQfSCTICN RESPZQTOHYeo oooooo EXPOSURE LI klTSeo e e 4

'T REQUIRED I

NONE ESTAOL Sl%Q FOR TW LBOVID PRODUCT VENTZLATICN LOCALZ X l46CHANICAL I PROTECT IVE GLOVESoo o RU85ER 4LOVES EYE PROTECTIONeor or QSQLKS OTHER PROTECT IVK KChUZPNENi ocr e oooo oo a APRNe COVERALL TO NZNIIIIZK SKIN CONTACT Xe IPKCIAL PRKCNJTIQN4 IN ACCORD WITH 4OOQ INDUSTRI AL PRACTICKe HANQLE THIS PRODUCT CARE AND AVOID PERSONAL CONTACTo 'ITH TRAIISPENTATXCN  %~NATION DOT H AZARD CLASS ZF ZCATZONe oo oo fC/A DOT PMPER SHIPPZNC I

IVANEe oo ~ ~ ee re reer ore OOT 1ST lQULATKD DOT LA@ a o o o or o o os UN/NA hQBooooo ooo llfA i tA AoQoo oooooooooooo roe NlA XIEo SP~ AN7 LEAK REQUt ATORY WASTE DKSCRZPTICSoe eore er o NOT HAZARDOUS ACCOROikO TO 14 CFR PART 241 Ro Oo o oooo os oo oo oe or 4 ICNR WASTE DZSPOSALooo oo o SLATY OR INCINERATE ACClÃRDIN4 TO FEDERALe STATK AND LDCAL ~6ERATI ONSa 0 AUk 0 f SP OSALo o o o o r e CDNTAINERI SHOULD 5E TRIPLE RINSKO ACCORDIN4 TO STEPS TO 8K TAKEN IF I

FKDERA4. REQULAT ONS e WATER IAL RELEASED QR SPILLEDe ~ ere eeeo4 WEAR APPROPRIATE SAFETY EQUIPICNCTe CONTAIN Al&

CLEAN UP SPiLL llkKDZATKLYe PASVKNT FROID KNTKRIN4 FLOOR ORAZNSa CONTAIN LIQIZDS" USING AQSORSANTSe SWEEP POWDERS CAREFULLY IQNZ NIXIN4 DUST INQe 8IRVEL SPILL kATKRZALS iki DISPOSAL ORUke. FOLLOW .

DISPOSAL INSTRUC7ZONSe SCRUQ SPILL AREA WITH QCTSQQINTo FLUSH NZTN COPZOllS AMOUNTS ZI 1ATKRo Il RRStLA~ I~CNNA%'XII Chr cero eeooeooe or Z IN CONPLIANCKo ARA4 THIS PRODUCT ZS JClT REPORTASLK UNDER SARA SECTION 3Z3 OMOI INTRACID AIC)DAMINK N'IOUZP P14K 3 CCONTINLKOl

PAGE.GGS HAZARQ CLASSIFICATION'HRQk IC o ~ ~ NO FLAMMABLEo NQ REACT IVKe ~ MQ CNXQIZERo ~ NO STATE RIGHT TQ KNO1 l A%Sr PE NMSYLVAMZA Ters PROOuCT ZS

~MHAZARQOUS I NGREQIKNTS

~T lREGS.ATKQ ENCODER T~ Punch R-r-K ihe Cei ~ ACID REQ 388 NATER XlVe CfOKR I~CSNATION THIS PROCNCT ZS NOT h mON+RmJ BO PRODVCT AS QEFINEu SV THE CANAOIAN MRZSe 0 ISCLAINERt CRO4EPYCIM C KNWLES NARRANTS THhT THIS PRQQVCT CONFORJLS TO THE.

CHEMICAL QKSCRXPTZON ON THE L,A~L. ANQ LS REASQNABC Y FZT FOR NE SPECZFZC PURPOSES REFERREO TQ ZN XTS OIRKCTIONS FOR USEy 5UbQECT 30 THE ENHKRENT RZSK9 REFERRED TO XN 7% ltlTERIA4 SAFETY QATA SHEET FQR THZ S PROQUGTw CRCNPTQN S KNOCLKS IlhlCES NC OTHER EXPRESS OR XNPLIEQ WARRANTY QF FITNESS QR 4KRCHANTASIl TXZ OR ANY Of ~R EXPRESS OR ZNPLXEQ NARRANTYo XN NQ CASK SHALL CRONPTON Pi KNOW.ES SK LZASLE PQR CONSERVE/ENTI ALo SPECIAL. ~ QR RESUt.3 INC PROD THE VSE OR HANQLINQ OP 'A4ZS RRQQVCV+

INQ1RECT'ANAtKS 00804 INTRACIQ RfDANXNK NT LIOMID PA4iE 4 CLAST PACi57

INTRACIDoR Rhodamine WT Liquid Technical Data Bulletin

'PD N0.022 JULY 1988 GENERAL Intracid Rhodamine WT Liquid is a bright fluorescent red dye developed especially for water tracing. It exhibits excepuonally high tinctorial strength and a low tendency to stain silt, dirt, organic (plants) and other suspended matter in fresh and salt waters. It is designed for water tracing by fluoromeuy or visual methods and is detectable at 0.1 ppb by fluorometric techniques, A manufacturer of fluorometers such as Turner Designs'hould be consulted for detailed application information. For precise scientific work, the user should carry out his own measurements on the starting material since there viillbe some variation from lot to lot.

According to studies by the U.S. Army Corps of Engineers, Intracid Rhodamine WT Liquid poses no known environ-mental or health hazards when used in compliance with established dye concentrations, The suitability of this product for specific water tracing applications should be evaluated by qualified hydrologists.

PROPERTIES ppearance..........,.........,... Clear, very dark red aqueous solution, substantially free Wavelength................... About 556 nm.

from insoluble matter.

Optimum Analyzing Specific gravity................. Approximately 1.15 at 20/20'C. Wavelength.....,................. About 580 nm.

Gravity on speciTic lots willbe provided on request. pH sensitivity..................,. No signiTicant change in fluorescence between 5.5 PH oooeooo ooooo ooooooooo ooooo ooo 10.8 ~ 0.7 at 20'C. and 11.0.

Dispersion in sea water.. Shows complete dispersion Freezingpoint...,.....,.....,. Approximately -10'C.

when dropped into sea water.

Viscosity.....,........,........... Less than 25 centipoises Bleachability,.......,....,....... Bleachable with sodium at 25'C; hypochlorite.

Optimum Excitation Turner Designs. Mountfun View, CA 94043 . 415I965-9800 Crompton 8 Knowles Corporation industrial Products Division P. O. Box 33157 Charloite, NC 28233-3157 I 704I372-5890 I 800/323-4383 DISCIAIMER: To our best knowledge, the Information and recommen- by reason of Its following our recommendations or using the information dations contained herein are accurate, and reliable. However this lnfonnao given.

tion and our recommendations are furnished without warranty, represen-tation, inducement, or license of any kind, including, but not limifed fo the implied warranties oi marchen!ability and /itness ior a parficuiar use or CAtmON: Dyes and chemicals may cause Irritation It allowed to come purpose. Customers are encouraged to conduct their own tests and to ln contact with the skin. The use of gloves and protective goggles ls read the product labels carefully before using them. Furthermore, the recommended WhOA handling these Productao as Wlfh any Ofhef dye Of customer assunles sole liability for any patent infringement that occurs chemical.

~QO QR o+

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S ~O go+

y MNlTECl STATES KNVIRONMKNTALPROTECTlON AGENCY gfg I WASHINGTON. D.C. 20460 Oi>ICC OF WATCR

'Ms. Janice Marnquist Chemical Safety Manager I<cptyED Crouton and Knovles Corparatian P.O. box 341 (500 Pear Street)

Reading, tennsylvan'ia 19603

Dear Hs. Marnquist:

The Criteria and Standards Division {Office of Drinking Water) has reviered the available data on chemistry and taxicity of Rhodamine dyes. Ne rould not anticipate any adverse health effects resulting from the use af Rhadamine IT as a fluorescent tracer in eater flax studies shen used trith the folloving guidelines.

A maximum cancentration of 100 micrograms/liter khadamine WT is recommended for addition to raH Water in hydrological studies involving surface and ground eaters.

Dye concentration should be limited ta 10 aicra-aicragrams/liter in ra~ eater shen used as a tracer in or araund drinking eater intakes.

Cancentration in drinking eater shouldnot exceed O.l Iicrograms/liter. Studies Which result 5n actual human exposure to the dye via drinking eater must be brief and infrequent. This level is not acceptable for chronic human exposures r

Zn all of the above cases, the actual concentratian used should not exceed the amount required far reasanably certain detection of the dye as required to accomplish the intended purpose of the study.

Criteria and Standards Divisian recommends that khodamine l not Thebe used as ~ tracer dye in eater flow studies.

This advisory supersedes all earlier advisaries issued by EPA on the use of fluorescent dyes as tracers in eater flaw studies.

This a4visory is granted an a 'temporary basis only.

SPA as is terminating its voluntary additives advisory program announced in the ~edig3Q, ~ster (53 fR, 255! 6, duly 7, 1988) . 8 cony o! the ~derel Re~~Ltt Notice Se enclosed 8or l

your convenience. Ill SPA advisory opinions issued sithin the framework of the additives program sill expire on ipril 7, 1090.

Our opinion concerning the safety of this tracer dye does not constitute an endorsement, nor does it relate to its effectiveness for the intended use. Zf this letter is to be used Ln any ~ay, re require it.to be quoted in its entirety.

inc rel

, ('i.

hur H. Parlor, Chief Science and Technology Sranch Criteria and Standards Division Inclosure

RHODANINE WT TITLES AVAILABLE I

(1) ABIDI, S. L. DETECTION OF DIETHYLNITR05AMINE IN NITRITE-RICH WATER FOLLOW INB TREATMENT WITH RHODAMINE FLOW TRACERS. 2982 (2) RBIDI, S. L. et al POTENTIAL FOR NITROSAMINE FORMATION IN SEVEN FISHERY CHEMICALS. 198b

(~) RBIDI ) S. L. LETTER REFERENCING 1982 ABIDI STUDY. 1987 BENO IT-GUYODi J. L CORRELRT I ONS BETWEEN PHYSICOCHEMICAL et a,l PROPERTIES AND ECOTOXICITY OF FLUORESCENT XANTHENIC W4TER TRACERS (IN FRENCH>." 1979 (5) DOUGLAS, G. et al COMPARATIVE MAMMALIAN IN VITRO AND IN VIVO STUDIES ON THE MUTRGENIC RCTIVITY OF RHODA-MINE WT 2983

~

(b) EPA GUIDANCE MANUAL FOR COMPLIANCE WITH THE OFFICE OF WATER FILTRATION RND DISINFECTION REQUIREMENTS FOR PUBLIC WATER SYSTEMS USINB SURFACE WATER SOURCES DR4FT, OCTOBER 2987 e EPA A H.PERLER LETTER TO J ~ WARNQUIST, SETTING MAXIMUM DYE CONCENTRATIONS. 2988 (8) JOHNSON, M. C FLUOROMETRIC TECHNIQUES FOR TRACING RESERVOIR

'(US ARMY ENGRS) INFLOWS ~ p b-20+ 1984 (9) MEIER, P. G. et al APPLICATION OF TRACER TECHNIQUES TO CONTINUOUS-FLOW TOXICITY TESTING. 1987

( 10) NESTMANNg Ee MUTAGENICI TY IN SALMONELLR OF RHODAMINE WT.

et al 4 DYE USED IN W4TER TR4CINB STUDIES ~ 1979 (1 1) PARI(ER, GARALD TESTS OF RHOD4MINE WT DYE FOR TOXICITY TO OYSTERS AND FISH. 1973~i'

~

(12) SMART, P L R REVIEW OF THE TOXICITY OF TWELVE FLUORESCENT DYES USED FOR WATER TRACING 1984 (23) SRI INTERNATIONAL HEALTH AND ENVIRONMENTAL"ASPECTS OF RHODAMINE-BASED DYES 2983 (14) STEINHEIMER, T INVESTIGATION OF THE POSSIBLE-.FOR%4TXQN OF Cc JOHNSON, S DIETHYLNITROSAM'INE"RESULT4NS FRO~-THE USE OF RHODAMINE WT DYE AS .VfcACER lg RIVER WATERS.

1984 IP Gibraltar Library Aug. 1988. Rev. May 1989

I RHODAt1 INE WT T I LES 4 VA I LABLE APPLIC4T I ONS (15) ALDOUS, P. J. h TRACING GROUND-WATER MOVEMENT IN ABANDONED SMART, P. L. COAL MINED AQLIIFERS US I tVG FLUORESCENT D Vh.S.

1988 (30) BENCALA, K. et al RHODAMINE WT LOSSES IN A MOUNTAIN SlREAtl ENVIRONMENT. 1983 (16) DUPONT BULLETIN DYES FOR WATER TRACING STUDIES. 1969 OR LATER?

(17') GRASSO, D. 5 FLUORESCENT DYE AIDS DISTRIBUTION STUDIFS.

WILLIAMS, R. 1983

( 18) JOHNSON ~ Me Co FLUOROMETRIC TECHNIQUES FOR TRACING RESERVOIR

.(US ARMY ENGRS) ,I NFLOWS ~ 1984 (19) KILPATRICK, F. A. DOSAGE REQUIREMENTS FOR SLUG INJECTIONS OF RHOD4MINE B4 AND WT DYES. 1970 (21) NEUDERFER~ GARY N. PLAN FOR RHOD4MINE WT DYE STUDIES IN CATHARINE CREEK AND CAYUGA INLET AS'ART OF SEA LAMPREY CONTROL PROJECTS IN SENECA AND CAYUGA LAKES.

1983 (22) SMART, P.L. AND .AN EVALUATION QF SOME FLUORESCENT DYES FOR LAIDLAW, I. M. S. WATER TRACING. 1977 TURNER DESIGN, "FLUOROMETRIC FACTS" SERIESt

( .3A) CIRCULATION, DISPERSION e AND PLUME STUDIES.

1984 (?)

(23B) FLOW MEASUREMENTS IN SANITARY SEWERS BY DYE DILUTION,1980 (?)

(23C) FLOW MEASUREMENTS 1984(?)

(23D) FLUORESCEIN. 1983 (23E) FLUORESCENT TRACER DYES'981 IN

'23F

) FLUOROMETRY THE W4TER POLLUTION CONTROL PLANT 1982 TURNER DESIGN ~ OTHER PUBLI CAT IONSt (24A) FIELD FLUOROMETRY (24B) MEASURING WASTEWATER FLOW WITH DYE~ 1978 Gibraltar Library Aug 1988. Rev. May 1989

RHODAMINE WT TITLES AVA?LABLE PPL I CAT IONS, contd.

US DEPT. INTERIOR Techni ues of Water Resources Investigations of the U. S. Geol o i cal Surve . Book 3, "Applications of Hydraul i cs"

'I (25C ) Chapter A9: Measurement of time of travel and dispersion by dye tracing. 198/

(25D) Chapter 4125 Fluorometric Procedures f or 1986 Dye'racing.

BIBIOGRAPHIEB AND REFERENCE LISTS (27) PUBLICATIONS ON TECHNIQUES OF WATER-RESOUF(CES INVEST IGATIONB (Manuals published by the U.S. Geological Survey)

(28) REFERENCES CITED IN STEINHEIMER/JOHNSON REPORT ON THE "INVESTIGATION OF THE POSSIBLE FORMATION OF DIETHYLNITROBAMINE RESULTING FROM THE UBE OF RHODAMINE WT DYE AS A TRACER IN RIVER.

WATERS" (SEE TOXICITY) pp. 48 4 49 of Ref . (14) .

9) WA'TER TRACING WITH FLUORESCENT DYES, PART 1! FIELD EXPERIMENTS IN INTERGRANULAR FLOW AQUIFERB, An Annotated Bibliography.

P.L.Smart and F. Whitaker, Dept. of Geography, University of Bristol, 1987 C&K DOCUMENTS (31) C&K: IPD TECHNICAL DATA BULLETIN NO 022'2/86 raltar Library Aug. 1988 Rev May 1989

liNTRACI D RhodlDrthm FVT Liquid Crompton & Knowles Corporation Industrial Products Division '.

O. Box 33157 Charlotte, North Carolina 28233-3157 704/372-5890 . 800/323-4383

...Bright red fluorescent water tracing dye and other specialty dyes

<~Mid.LL.ir I', t~(. ('~ ~

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U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET Required under USDL Safety and.Heat!!I Fegulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CF R 1915, 1916, 1917)

SECTION I MANUFACTURER'5 NAME ElvlERGENCY TELEPHONE No.

The Chloramone Corporation 302-834-4558 aooRESS (ÃLlrnb<r. Srrrer. Ciry, Stare. and ZIP CoCk'J River Road tt Red Lion Creek. P.O. Box 294, Delaware City, Del. 19706 CHEMICAI NAME AND 5YNONYMS TRADE NAME AND SYNONYMS Sodium Hypochforite Solution 12.5% I 15% Bleach CHEMICAI F AMILY C12 + 2 NBOH ~ NaOCl + NBC1 f H20 SECTION II - HAZARDOUS INGREDIENTS PAINTS. PRESERVATIVES, SOLVENTS TLV TLV Er Iuniti ALLOYS ANO METALLICCOATINGS Iunits)

PIGMENTS BASE METAL caTALYST ALLOYS VEHICLE METALLICCOATINGS SOL VENTS FII LER METAI PLUS COATING OR CORE Ft-UX ADDITIVES OTHERS QS TLV HAZARDOUS MIXTURES OF OTHFR LIOUIOS. SOLIDS. OR GASES lunitsl by weight 12.5 HRO by weight 87.5 SECTION III - PHYSICAL DATA Boll 'lNG POINT I F,) decomposes spEciFIc GRaviTY IH>o~t) 60' 1.210 VAPOR PRESSURF. Irnrn Ha.) PE R CENT, VOLATILE BY VOLUME (%) NA VAPOR DENSITY IAIR+lt EV A PO R ATI 0 N R ATE NA I ~ ll SOLUall ITY Ir'I WATER completely APPEARANcE ar~o oooR Pale yellow liquid chlorine odor SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLA5H polNT (Mctnod Miedi FL,AMMABIE LIMITS Lel Uol none non-tlamrnable EXTINGUISHING MEDIA tog nozzle water SPECIAL FIRE FIGHTING PROCEDURES lt contained gas mask suitable tor chlorine gas UNUSUAL FIRE ANO EXPI OSION HAZARDS none PAGE I1) IContinued on reverse sidd Form OSHA 20 Rcv. May TZ

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SPARTAN QKHICAL CO ~

SAFETY DATA St%ET IM'ATERIAL SECTION I PRHXKT ICENTIFICATIDN FRMXKT NNK OR NJCKR (as it ~mrs on label) .

SD-20 (aalu)

HAMI.ACTLHER'S NQK B%3tGBKY TELEPHQK ND Spartan Chemical Co., Inc. (419) 531 5551 AMSESS (%%4KR STREET CITY, STATE AM) ZIP GXK) 110 N. Westwood Ave., Toledo, OH 43607 NAtaFnCrtSER'S 00-503-6728

~S Mj.

SECTION II HAZARDIJS INGREDIENTS I I I

- Table Z-1-A I I ICAS REGISIY M)..l m I CtENim, ceo(S) era I STEL I Ceu ~ I CARCIM)GEN I I I I I I I I NO HAZARDOUS INGREDIENTS AT lX OR GREATER COM:ENTRATICN SECTION III PHYSICAL DATA BDILItK POINT SPECIFIC GRAVITY (HZO = 1) 212 oF 1.074 VAIR PRESRSE - 18 PEKXNT SRJD BY 675 oF oC X mmHg Vmm DENSITY (AIR = 1)

~si EVARNATIDN RATE (but. ace. = 1) ttEIGHT (X) 15-17 Unknown <1 SB UBILITY IN 'MATER APPGSAMX AM) HXR Complete Blue, citrus odor pH IS NAmmu: (LlauiD) Sn ID Concentrate 11.0-11.5 C!G PASTE POWDER FLASH POINT - None EXTBCUISHIM l4DIA

~ 092 SECTION IV FIRE AM) EXPLOSION HAZARD DATA USED - ASTN - FUONAKE LINITS - n/a n/a SPECIAL FIRE FIGHTIM PRKHXBES n/a

%4XRlAL FIRE AM) EXPLOSION HAZARDS n/a

SECTION V - fEALTH HAZARD DATA EFRZTS OF OVEREXPORSE - CXH)ITIlNS TO AVOID MKSMLD LIHIT VALLE - Not established Avoid eye contact; may cause eye irritation.

PRIHARY RRlTES OF ENTRY ISOLATION SKIN GWTACT GPKR (SPECIFY)

GM)ITIQG AGGRAVAlED BY USE Unknown E %3KEtCY AM) FIRST AID PRKEDLSES - In case of contact immediately flush eyes with plenty of water for at least 15 minutes; call a physician. Flush skin with water. Wash clothing before reuse. If swallowed, give large quantities of water or fruit juice. Call a physician immediately.

SECTIRl VI '-'BZTIVITYDATA STABILITY: NSTAKE STABLE X ItCQ4 ATIBILITY(HATERI~ TO AVOID)

None HAZARORS DECL'OSITHN RAXETS None HAZARDOUS HAY SXNt IZATIW: WILL Wr OCON X SECTION VII - SPILL OR tEAK PROCHXÃKS STEPS lO BE TAKEN IN CASE HATERIAL IS RELEASED OR SPILLED Flush with water to sanitary sewer system.

WASTE DISPOSAL Same as above.

SECTION VIII - SPECIAL PROTECTION lmaeTI~

RESPIRAmer PROTECTlm (SPECIFY TYPE)

Nothing special VENTILATION - Good general ventilation should be sufficient for most conditions. Local exhaust ventilation may be necessary for some operations.

PROTECTIVE GLOVES;~IFY TYPE) EYE PROTECTION (SPECIFY TYPE)

If desired If desired OTHER PROlECTIVE GQIRENT n/a SECTION IX - SPECIAL PRECAUTION+

RKCAUTIOCS TO BE TAKEN IN HAtSLItC AM) STORING Nothing special OPER PRECAUTICNS Nothing special Qartan Chemical Co., Inc. NSK lhoeas t. Hitchell SD-20 (mX) TIRE Director of Research Ref: 29 CFR 1910:1200 (OSHA) DAlE tune 1, 1990 arear~ Sep~ 20. 1985 SCC6/90 Copyrighted= Spartan Chemical Coo., Inc. For Use Only, Dy Authorized Spartan Distrihutors.

l U, g

Syn Tech Products Corporation 520 E. Woodruff Avenue I gr- iicieQL)

Toledo, Ohio 43624 xaum.A (419) 241-1215 24 Hour - Call INFOTRAC 1-800-535-5035 Qqpic=8.= 4 lQ r <~e Material Safety Data Sheet Section I - Product Identification Product Name: TOUCH IT UP DE-CONTAMINANT Chemical Family:

Effective Date: 12-91 Formula: Prorietaty Mixture Section II - Material or Component Chemical Name CAS4 WT% PEL TLV STEL CARCIG Butyl Cellosolve 111-76-2 1-3% 50 50 NO Sodium Metasilicate 6834-92-0 1-3%%uo NO Octylphenol Polyehtoxylate 9002-93-1 1-3% ~

NO Hydrocarbon Propellant 68476-86-8 6-10% 1000 1000 NO Trisodium Phosphate 7601-54-9 NO Section IG - Physical Data Bo Point ( F) of Concentrate: N.D.

Va ressure (psig) In Can Q 75 Fi 65 Vapor Density: N.D.

Solubility in Water of Concentration: Complete Specific Gravity(H20=1)@75,F of Concentrate: 1.035 lo Volatile by Volume ln Can: 85 Flash Point of Spray: Noneup to 150 F Appearance and Odor Spray: White Foam perfume odor Section IV - Fire and Explosion Hazard Data Flammability as per CPSC Flame Extentsion Test: Non-Hammable Flammable Limits: Lower N/A Upper N/A Extinguishing Media: Water, Foam, dry chemical, carbon dioxide Special Fire Fighting Procedures: Keep containers cool. Use equipment or sheilding required to protect personnel against bursting, rupturing, or venting containers.

Unusual Fire and Explosion Hazards: At elevated temperatures (above 120 F) containers may vent, rupture, or burst.

Section V - Reactivity Data Chemical Stability: Stable Conditions to Avoid: Do not expose to temperatures above 120 F.

Incom atibility (Materials to Avoid): None H us Decomposition By-Products: Thermal decomposition in the presence of air may yield Carbon monoxide and/or carbon dioxide.

Hazardous Polymerization: WillNOT occur.

Conditions to avoid: None

Section VI - Health Hazard Data OSHA PERMISSIBLE EXPOSURE LIMIT: N.D.

THRESHOLD LIMITVALUE: (SEE SEC%ON II)

EFFECTS TO OVEREXPOSURE EYES: Minor irritation.

SKIN: No evidence of adverse effect from available information.

INGESTION: Can cause gastrointestinal irritation, nausea, vomiting and diarrhea.

INHALATION:Productexist as foam. Inhalation of foam could cause asphyxiation.

EMERGENCY AND FIRST AID PROCEDURES EYES: Hush with water for at least 15 minutes ..

SKIN: Wash exposed area with water and soap.

INGESTION: Do not induce vomiting. Get medical attention.

INHALATION:Treatfor asphyxiation VII- Spill or Leak Procedures STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIALIS RELEASED:

Clean up area by mopping or with absorbent materials and place in closed containers for dispos Consult+ederal, State or l.ocal disposal authorities for approved disposal procedures.

WASTE DISPOSAL METHOD:

When used properly aerosol products do not generate hazardous waste. Empty de-pressurized containers can not be reused and should be wrapped and put in trash collection. Cans which ar ressurized or contain liquid must be disposed of in a permitted waste management onsult Federal, State or Local disposal authorities for approved disposal procedures.

fa~

Section VIII- Special Protection Information Specific Personal Protective Equipment Respiratiory Protection: Under normal conditions, no respiratory protection is required.

Ventilation: ,Normal ventilation Skin: None required, protective gloves may be worn.

Eye Protection: None required, chemical splash goggles may be worn.

Section IX - Special Handling Information PRECAUTIONS TO BE TAKEN IN HANDLINGAND STORING: Do not store at temperatures above 120 F.

SPECIAL PRECAUTIONARY STATEMENTS: Please read and follow the directions on the product label, they are your best guide to using this product in the most effective way, and to give the necessary safety precautions to protect your health.

The above information pertains to this product as currently formulated, and is based on the information available at this time.

Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties, express or implied, and assume no liabilityin connection with any use of the information.

Prepared by J. Rose SSSDS - ssSSSSSD

NPDHS Number PA 00473 5 IY. ( tinued) 2,3 information and Anal sisofHNuent ualit forptherPotentiall ToxicPollutantsKnown or Ex ected to be Present in the Dischar e (Read instructions carelully and use the tabular format and additional pages, where necessary, to present the required information)

Average Analytical Effluent Detection Outfall Chemical Substance or Compound Reason for Presence ln Discharge 7 Concentration Level (pg/1) (pgll)

CR.BWQ-288.10: Rer. 8t93 NPDES Permit Number PA 0047325 SECTION C (continued)

IV. (Continued) Nt A

4. Any other toxic chemicals known or expected to be present in the discluLrge.

a. GC/MS "Five Peaks" pollutants (see instructions)

Outfall Number Analytical Average Maximum No. Samples Group Chemical Substance or Detectioa E81ueat EKuent Positive Number Compound Name Limit Concentration Concentration I (3-7) No. analyzed Use additional sheets for additional pollutants, and for each Outfall reported.

tfadditional in eke were not avattahte for one or more groups with the method used cheek hers ar attach an explanation of why the method was selected.

ER B%'Q-2$ L10: Bar. 683 NPDES Permit Number PA 00473~5 i

SECTION C (continued)

IV. (Continued) "/A 4.

b. Other Chemicals Outfall Number Average Indicate if Substance Reason for Presence in Discharge Concentration Presence is Known (K) or Suspected (S}

Provide additional sheets as necessary EK IIwI)-388.IO: Kev. 883 SECTION C (continued) NPl)ES Number PA 00473~5 V. IIA'lARI)OUS SUBSTANCE Sl'II.I. REI'OIITING REQUIREMENT EXEMPTION (Optional) N/A (See Instructions)

Amount I'er Outfall 3. Treatment

1. Name of'I'able 4 Substance Outfall 2. Origin and Source ProvIded quanIIIy l)urallon Ih/N hrs Frequency b c

ER.B WQ.288.10: Rev. 6I93.

SECTION C (continued) NPDESNumber PA VI. ANTICIPATED ENVIRONMENTAL PROTECTION IMPROVEMENTS OR RELATED CHANGES A. Are you now required by any Federal, State or local authority to meet any implementation schedule for the construction, upgrading or operation of wastewater treatment equipment or practices or any other environmental programs which ma afI'ect the disch es described in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters, stipulations, court orders, and grant or loan conditions.

Q YES (complete Dt's fofhwing axMc) g NO(go ta B)

l. IDEiVIICATION 2. AFFECTED OUTFALLS

4. ~AL COMPLIANCE OF CONDITION, 3. BRIEF DESCRIPTION OF PROJECT DATE I

AGREEMENT+ ETC. a. No i b. SoeteeetDbcharge I

I I

I I

I I

I I

I I

I I

I I

I I

I I

I I

I, I

I I

I I

I I

I OPTIONAL: You may attach additional sheets describing any additional environmental pollution control programs (or other production projects) which may affect your discharges which you now have underway or which you plan. Indicate whether each program is now underway or planned, and indicate your actual or planned schedules for construction.

Q MARK"X"IF DESCRIPTION OF ADDITIONALPROGRA VlS IS ATTACHED "/<

VII. BIOLOGICAL'OXICITYTEST DATA Do you know or have reason to believe that any acute or chronic biological toxicity tests were made in the last three (3) years on any of the facility's discharges, or on a receiving water in relation to a discharge?

g Yes g No Ifyes, attach an information which you have available on the purpose and nature of such testing, and the test results.

All dischargers are encouraged to perform biological toxicity testing. The Department may require biomonitoring testing be conducted after your application is received. The Department may be contacted for protocols, b

,'R-BWQ.288.10: Rev. 6/93 Npofs 4 pA: 0047325 SECTION D - Stormwater Discharges Associated with IndLIstrial Activity N/A I. utfall Location For each outfall. hst the latitude and longitude of its location to the nearest 15 seconds and the name of the rec dving water.'.

Outfall Number ~. Receiving Water list C Longitude name II. Improvements A. Are you now required by any Federal, State. or local authonty to meet any implementation schedule for the construction, upgrading or operation of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges descnbed in this applicaqon? This mcludes. but isnot limited to, permit conditions. admmistrative or enforcement orders, enforcement compliance schedule letters. stipulations. court orders. and grant or loan conditions. Q Yes Q No

2. Affected Outfalls 4. Final Compliance

1. Identification of Conditions, Date Agreements, Etc. 3. Srief Description of project nuinber source of discharge a. feq. b. proj.

affect 8, You may attacn additional sheets descnbing any additional water polluuon (or other environmental pro)ects which may you discharges) you now have under way or which you plan. Indicate whether each program is now under way or planned. and mdicate your actual or pianned schedules for construction.

III. Site Drainage Map Attach a site mao snowing topograi hy (or indicatmg the outline of drainage areas se~ ed by the outfall(s) covere J i the a pplication if a topo-graphic map is unavailable) depicting the facility including: each of its int ke and discharge structures; the drain=ge area of each storm water outfall; paved areas and buildings withm the drainage area of each storm water outfall, eachknown past or present areas used for outdoor

~

storage or dis posai of significant materials, each existing structural control measure to reduce pollutants m storm water runoff. materials loading access areas. areas where pesticides. herbicides, soil conditioners and fertilizers are apphed; each ot its hazardous waste treatment. storage or

~ ~

sal units (including each area not required to have a RCRA permit which is used for accumulating hazardous waste under 40 CFR 262.34):

e h well wheie fluids from the facility are in) ected underground; s pnngs. and other surface water bodies which receive storm water discharges from the facility.

ER.BVFQ.288.10: Rev. 6I93 NPDES Number PA 0047325 SECTION E - MISCELLANEOUS INFORMATION SUBMISSION I. CONTRACTED ANALYTICALASSISTANCE Did a contract laboratory or consulting firm perform any of the analyses required by this application?

Q Yes, their name(s), address(es) and list(s) of the Q No analyses performed are givenbelow: s Name SSN/Laboratori es f Types o Analyses Performed.

GrOuPs Address 30 Noble Street 1, 2, 3, 4, 5, 7 Readin, PA 19611-0527 Phone( 610 ) 376 4595 Attn: Steve Del p, CIH Teledyne Brown Eng. ( Isotopes) Types of Analyses Performed:

Address 50 Van Buren Avenue P.O. Box 1235 Westwood, NJ 07675-1235 Phone ( 201 ) 664 - 5586 Attn: Al Hogan Name PPSL Types of Armlyses Performed:

Sus uehanna Steam Electric Station 7C, 12C (Outfall 077) rlf'ddress Box 467 Berwick'A 18603 Phone (~17 ) 542 - 3996 Attn: Lenny Humpf ER BWQ-2B8.10: Rev. 683 SECTION E (continued) NPDES Number PA 00473~5 II. OTHER INFORMATION

1. For New Disch ers Onl g Check ifNot Applicable

a. Have there been any technical evaluations performed concerning your anticipated wastewater treatment or control facilities (including engineering reports or pilot plant studies)? Check the appropriate box below.

P Yes Q No

b. Ifyes, briefly describe such evaluations and the resulting reports which have been prepared.

c. Provide the name and location of any existing plant(s) which, to the best of your~

knowledge, resembles your planned operation with respect to items produced,~

production processes, wastewater constituents or wastewater treatment.

Name Location

2. For All Dischar ers: (Optional) tl/A Ifnecessary, use attached sheets to expand upon responses to any of the above Questions, or to call attention to an other information you feel should be considered in establishing permit limitations for the proposed or existing facility.

E)t B%Q48L1L Rev. SN NPDES Number PA 0047325 G GTI .CN C TIGN NDN GN Tll Q D IIC NT I certify under penalty of law that this doctnnent and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and.evaluated the information submittaL Based on my inquiry of the person or persons who nianage the, system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my ltnowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for ltnowing violations.

R. G. 8 ram Sr. V.P. - Nuclear Serorn and aabeeribed to before me this Print Name and TMe ofPeraon Signing say Gf .19~

( 610 ) 774-7502 Telephone Number of Petmn Signing, i NOTARIAL'EAL MT NII hpplicant A IontownG le') <'Un'y Commission Expires May 14,,19 6 I

Notary Seal.

Date Application Signed.

Please note below the name, address and telephone number of the individual that should be "contactedintheeventad ' I tin isrequired: (lfsameaslteml.C,inSectionA, please state):

Jerome S. Fields REM Penns lvania Power 8 Li ht Company.

Two N. 9th Street, Allentown, PA 18101-1179 Telephone: ( 610 ) 774-7889