ML18003B042

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Part 08 Enclosures (Rev. 1) - Part 8 - Enclosures - Geotechnical Exploration and Testing Data Report Appendix H.2 Test Reports from Testamerica Part 01 Pages H.2-1 Thru H.2-30
ML18003B042
Person / Time
Site: Clinch River
Issue date: 12/15/2017
From: James Shea
Tennessee Valley Authority
To:
Office of New Reactors
Fetter A
References
TVACLINCHRIVERESP, TVACLINCHRIVERESP.SUBMISSION.4, CRN.P.PART08, CRN.P.PART08.1
Download: ML18003B042 (30)
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APPENDIX H.2-Test America Reports-No Change for Rev. 4 Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-1 of 111

a me DOCUMENTATION OF TECHNICAL REVIEW SUBCONTRACTOR WORK PRODUCT Project Name: Clinch River SMR Project Project Number:

6468-13-1072 Project Manager: Steve Criscenzo Project Technical Leads: AI Tice, Carl Tockstein The repmts described below have been prepared by the named subcontractor retained in accordance with the AMEC.QAPD. The work and reports have been reviewed by an AMEC technically qualified person. Comments on the work or reports, if any, have been satisfactorily addressed by the subcontractor. The reports are approved in accordance with section QS-7 of AMEC's QAPD REPORTS:

14584-l USD Level 2 Report Rev( l) Final Repmt 14584-2 USD Level 2 Report Final Report 14600-1 USD Level 2 Report Rev( I) Final Report 14600-2 USD Level 2 Report Final Report 14625-1 USD Level 2 Report Rev(l) Final Report 14625-2 USD Level 2 Report Final Report 14643-1 USD Level 2 Report Final Report SUBCONTRACTOR: Test America DATE OF ACCEPTANCE: 2/20/14 TECHNICAL REVIEWER'

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.............. LINKS............

Review your project results through TotdAccess Have a Question?

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www.testa merica i nc.com Page H.2-3 of 111 Test America THE LEADER IN ENVIRONMENTAL TESTING ANALYTICAL REPORT TestAmerica Laboratories, Inc.

TestAmerica St. Louis 13715 Rider Trail North Earth City, MO 63045 Tel: (314)298-8566 TestAmerica Job ID: 160-4584-1 Client Project/Site: Clinch River-6468-13-1072 Revision: 1 For:

AMEC Environment & Infrastructure, Inc.

4021 Stirrup Creek Drive Suite 100 Durham, North Carolina 27703 Attn: Mr. Allan Tice Authorized for release by:

211412014 4:08:50 PM Ivan Vania, Project Manager II (314 )298-8566 ivan. van ia@testam ericainc. com This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.

Results relate only to the items tested and the sample(s) as received by the laboratory.

. 4 CRP-1112.16 RCN : CRP-1 070.1 Page 1 of 32 II

Client: AMEC Environment & Infrastructure, Inc.

Project/Site: Clinch River-6468-13-1072 Table of Contents TestAmerica Job I D: 160-4584-1 Cover Page.............................................. 1 Table of Contents.........................................

2 Case Narrative...........................................

3 Chain of Custody.......................................... 5 Receipt Checklists......................................... 7 Definitions/Glossary.......................................

8 Method Summary.........................................

9 Sample Summary.........................................

1 o Client Sample Results...................................... 11 QC Sample Results........................................ 16 QC Association Summary................................... 20 Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-4 of 111 Page 2 of 21 RCN: CRP-1 070.1 Page 2 of32

Client: AMEC Environment & Infrastructure, Inc.

Project/Site: Clinch River-6468-13-1072 Job ID: 160-4584-1 Laboratory: TestAmerica St. Louis Narrative Case Narrative CASE NARRATIVE Client: AMEC Environment & Infrastructure, Inc.

Project: Clinch River Report Number: 160-4584 Revision 1 TestAmerica Job 10: 160-4584-1 With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.

TestAmerica St. Louis attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmerica's operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.

The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory.

Calculations are performed before rounding to avoid round-off errors in calculated results.

All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.

All solid sample results for Chemistry analyses are reported on an "as received" basis unless otherwise indicated by the presence of a %

solids value in the method header. All soil/sediment sample results for radiochemistry analyses are based upon sample as dried and disaggregated with the exception of tritium, carbon-14, and iodine-129 by gamma spectroscopy unless requested as wet weight by the client."

This laboratory report is confidential and is intended for the sole use of TestAmerica and its client. This revision removes the LCS results for carbonate and bicarbonate alkalinity as they do not actually exist. In addition, an unnecessary note for a qualifier for ammonia results was removed. The CoC was added to the report. Finally, the cation/anion balance results were removed from this report. They will be reported in job 160-4584-2 due to the structure of the LIMS system and correction of the formula used to arrive at the results. See corrective action 01152014-1 sent apart from this deliverable.

RECEIPT The samples were received on 11 /20/2013; the samples arrived in good condition, properly preserved and on ice. The temperature of the coolers at receipt was 2.7 C.

METALS (ICPMSl Samples OW 409-L-CC (160-4584-3), OW 409-U-C (160-4584-7), OW 423-U-C (160-4584-11 ), OW 1 01-L-CC (160-4584-15) and OW 1 01-L-C (160-4584-19) were analyzed for Metals (ICPMS) in accordance with EPA SW-846 Methods 6020A. The samples were prepared on 11/26/2013 and analyzed on 12/06/2013.

Preparation Batch 88197, Analytical Batch 90128:

The following samples were diluted to bring the concentration of target analytes within the calibration range: OW 1 01-L-CC (160-4584-15),

Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-5 of 111 Page 3 of 21 TestAmerica St. Louis RCN: CRP-1 070.1 Page 3 of32

Case Narrative Client: AMEC Environment & Infrastructure, Inc.

Project/Site: Clinch River-6468-13-1072 TestAmerica Job 10: 160-4584-1 Job ID: 160-4584-1 (Continued)

Laboratory: TestAmerica St. Louis (Continued)

OW 409-U-C (160-4584-7), OW 423-U-C (160-4584-11 ). Elevated reporting limits (Rls) are provided.

No other difficulties were encountered during the metals analysis. All quality control parameters were within the acceptance limits.

TOTAL DISSOLVED SOLIDS Samples OW 409-L-AA (160-4584-1 ), OW 409-U-A (160-4584-5), OW 423-U-A (160-4584-9), OW 1 01-L-AA (160-4584-13) and OW 1 01-L-A (160-4584-17) were analyzed for total dissolved solids in accordance with EPA Method 160.1. The samples were analyzed on 11/27/2013.

No difficulties were encountered during the TDS analysis. All quality control parameters were within the acceptance limits.

ANIONS Samples OW 409-L-AA (160-4584-1 ), OW 409-U-A (160-4584-5), OW 423-U-A (160-4584-9), OW 1 01-L-AA (160-4584-13) and OW 1 01-L-A (160-4584-17) were analyzed for anions in accordance with EPA Method 300.0. The samples were analyzed on 11/20/2013.

Batch 88825:

The following samples were diluted to bring the concentrations of Sulfate within the calibration range in IC batch 88825: OW 1 01-L-A (160-4584-17), OW 1 01-L-AA (160-4584-13), OW 409-L-AA (160-4584-1 ), OW 409-U-A (160-4584-5), OW 423-U-A (160-4584-9). Elevated reporting limits (Rls) are provided.

The matrix spike I matrix spike duplicate (MS/MSD) recoveries were outside control limits for Nitrite in IC batch 88825. (160-4584-5 MS),

(160-4584-5 MSD) The associated laboratory control sample (LCS) recovery met acceptance criteria, as did the MS/MSD recoveries for all other reported anions.

No other difficulties were encountered during the anions analysis. All other quality control parameters were within the acceptance limits.

ALKALINITY Samples OW 409-L-BB (160-4584-2), OW 409-U-B (160-4584-6), OW 423-U-B (160-4584-1 0), OW 1 01-L-BB (160-4584-14) and OW 1 01-L-B (160-4584-18) were analyzed for alkalinity in accordance with EPA Method 31 0.1. The samples were analyzed on 12/03/2013.

No other difficulties were encountered during the alkalinity analysis. All other quality control parameters were within the acceptance limits.

AMMONIA Samples OW 409-L-DD (160-4584-4), OW 409-U-D (160-4584-8), OW 423-U-D (160-4584-12), OW 1 01-L-DD (160-4584-16) and OW 1 01-L-D (160-4584-20) were analyzed for ammonia in accordance with EPA Method 350.1. The samples were analyzed on 12/23/2013.

Batch 84338:

The associated samples in NH3 Batch 94338 were analyzed outside of holding time, but within 2X hold: OW 1 01-L-D (160-4584-20), OW 1 01-L-DD (160-4584-16), OW 409-L-DD (160-4584-4), OW 409-U-D (160-4584-8), OW 423-U-D (160-4584-12)

The matrix spike (MS) recoveries for NH3 batch 94338 were outside control limits. Sample matrix interference is suspected because the associated laboratory control sample (LCS) recovery was within acceptance limits.

No other difficulties were encountered during the ammonia analysis. All other quality control parameters were within the acceptance limits.

Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-6 of 111 Page 4 of 21 TestAmerica St. Louis RCN: CRP-1 070.1 Page 4 of32

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AMEC Project Name AMEC Project Number COCDate AMEC Environment & Infrastructure, Inc. Chain of Custody Form CRP-22 Prepared By: Kim Charles-Smith ~

Clinch River SMR Project Checked By: Kristen Lloyd '/[ll!t.

11/19113 Transferred From: Site

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SAMPLE IDENTIFICATION OW 101-L-AA OW 101-L-BB OW 101-L-CC OW 101-L-DD OW 101-L-A OW 101-L-B.

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COLLECTION INTENDED USE REMARKS DATE 11/19/13 IDS, Anions ffir. Cl. F S04 N03. N02)

Unoreserved 11/19/13 Alkalinity Unpreserved 11119/13 Metals w/HN03 11119/13 NH3 w!H2S04 11119/13 TDS, Anions (Br, Cl, F, S04, N03, N02)

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Login Sample Receipt Checklist Client: AMEC Environment & Infrastructure, Inc.

Login Number: 4584 List Number: 1 Creator: Daniels, Brian J Question Radioactivity wasn't checked or is </= background as measured by a survey meter.

The cooler's custody seal, if present, is intact.

Sample custody seals, if present, are intact.

The cooler or samples do not appear to have been compromised or tampered with.

Samples were received on ice.

Cooler Temperature is acceptable.

Cooler Temperature is recorded.

COC is present.

COC is filled out in ink and legible.

COC is filled out with all pertinent information.

Is the Field Sampler's name present on COC?

There are no discrepancies between the containers received and the COC.

Samples are received within Holding Time.

Sample containers have legible labels.

Containers are not broken or leaking.

Sample collection date/times are provided.

Appropriate sample containers are used.

Sample bottles are completely filled.

Sample Preservation Verified.

There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs Containers requiring zero headspace have no headspace or bubble is

<6mm (1 /4").

Multiphasic samples are not present.

Samples do not require splitting or com positing.

Residual Chlorine Checked.

TestAmerica St. Louis Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-9 of 111 Page 7 of 21 Answer True True True N/A True True True True True True False True True True True True True True True True N/A True True N/A Comment Job Number: 160-4584-1 List Source: TestAmerica St. Louis RCN: CRP-1 070.1 Page 7 of32

Definitions/Glossary Client: AMEC Environment & Infrastructure, Inc.

Project/Site: Clinch River-6468-13-1072 Qualifiers General Chemistry Qualifier J

Qualifier Description Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

ICV,CCV,ICB,CCB, ISA, ISB, CRI, CRA, DLCK or MRL standard: Instrument related QC exceeds the control limits.

Sample was prepped or analyzed beyond the specified holding time TestAmerica Job 10: 160-4584-1 H

4 MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not applicable.

F Glossary Abbreviation

%R CNF DER Oil Fac DL, RA, RE, IN DLC MDA EDL MDC MDL ML NC ND POL QC RER RL RPD TEF TEO MS/MSD Recovery and/or RPD exceeds the control limits These commonly used abbreviations may or may not be present in this report.

Listed under the "D" column to designate that the result is reported on a dry weight basis Percent Recovery Contains no Free Liquid Duplicate error ratio (normalized absolute difference)

Dilution Factor Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample Decision level concentration Minimum detectable activity Estimated Detection Limit Minimum detectable concentration Method Detection Limit Minimum Level (Dioxin)

Not Calculated Not detected at the reporting limit (or MDL or EDL if shown)

Practical Quantitation Limit Quality Control Relative error ratio Reporting Limit or Requested Limit (Radiochemistry)

Relative Percent Difference, a measure of the relative difference between two points Toxicity Equivalent Factor (Dioxin)

Toxicity Equivalent Quotient (Dioxin)

Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-10 of 111 Page 8 of 21 TestAmerica St. Louis RCN: CRP-1 070.1 Page 8 of32

Client: AMEC Environment & Infrastructure, Inc.

Project/Site: Clinch River-6468-13-1072 Method 6020A 160.1 300.0 310.1 350.1 Method Description Metals (ICP/MS)

Solids, Total Dissolved (TDS)

Anions, ion Chromatography Alkalinity Nitrogen, Ammonia Protocol

References:

Method Summary TestAmerica Job 10: 160-4584-1 Protocol SW846 MCAWJV MCAWJV MCAWJV MCAWJV Laboratory TAL SL TAL SL TAL SL TAL SL TAL SL MCAWW ="Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And Subsequent Revisions.

SW846 ="Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.

Laboratory

References:

TAL SL = TestAmerica St. Louis, 13715 Rider Trail North, Earth City, MO 63045, TEL (314)298-8566 Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-11 of 111 Page 9 of 21 TestAmerica St. Louis RCN: CRP-1 070.1 Page 9 of32

Client: AMEC Environment & Infrastructure, Inc.

Project/Site: Clinch River-6468-13-1072 Lab Sample ID Client Sample ID 160-4584-1 160-4584-2 160-4584-3 160-4584-4 160-4584-5 160-4584-6 160-4584-7 160-4584-8 160-4584-9 160-4584-1 0 160-4584-11 160-4584-12 160-4584-13 160-4584-14 160-4584-15 160-4584-16 160-4584-17 160-4584-18 160-4584-19 160-4584-20 OW409-L-AA OW409-L-BB OW409-L-CC OW409-L-DD OW409-U-A OW409-U-B OW409-U-C OW409-U-D OW423-U-A OW423-U-B OW423-U-C OW423-U-D OW101-L-AA OW 101-L-BB OW101-L-CC OW 101-L-DD OW101-L-A OW 101-L-B OW101-L-C OW101-L-D Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-12 of 111 Sample Summary Page 10 of21 Matrix Water Water Water Water Water Water Water Water Water Water Water Water Water Water Water Water Water Water Water Water TestAmerica Job 10: 160-4584-1 Collected Received 11/19/13 00:00 11/20/13 09:20 11/19/13 00:00 11/20/13 09:20 11/19/13 00:00 11/20/13 09:20 11/19/13 00:00 11/20/13 09:20 11/19/13 00:00 11/20/13 09:20 11/19/13 00:00 11/20/13 09:20 11/19/13 00:00 11/20/13 09:20 11/19/13 00:00 11/20/13 09:20 11/19/13 00:00 11/20/13 09:20 11/19/13 00:00 11/20/13 09:20 11/19/13 00:00 11/20/13 09:20 11/19/13 00:00 11/20/13 09:20 11/19/13 00:00 11/20/13 09:20 11/19/13 00:00 11/20/13 09:20 11/19/13 00:00 11/20/13 09:20 11/19/13 00:00 11/20/13 09:20 11/19/13 00:00 11/20/13 09:20 11/19/13 00:00 11/20/13 09:20 11/19/13 00:00 11/20/13 09:20 11/19/13 00:00 11/20/13 09:20 TestAmerica St. Louis RCN: CRP-1 070.1 Page 10 of32 El

Client Sample Results Client: AMEC Environment & Infrastructure, Inc.

Project/Site: Clinch River-6468-13-1072 Client Sample ID: OW 409-L-AA Date Collected: 11/19/13 00:00 Date Received: 11/20/13 09:20 General Chemistry Analyte Result Qualifier Total Dissolved Solids (TDS) 520 Nitrate as N 0.12 Nitrite as N 0.0052 J Fluoride 0.37 Chloride 2.2 Bromide ND

~ Gene<al Cheml*t'Y-DL Analyte Result Qualifier Sulfate 150 Client Sample ID: OW 409-L-88 Date Collected: 11/19/13 00:00 Date Received: 11/20/13 09:20 General Chemistry Analyte Result Qualifier Alkalinity 300 Bicarbonate Alkalinity as CaC03 300 Carbonate Alkalinity as CaC03 ND Client Sample ID: OW 409-L-CC Date Collected: 11/19/13 00:00 Date Received: 11/20/13 09:20 Method: 6020A-Metals (ICP/MS)

Analyte Result Qualifier Calcium 46000 Iron 68 Potassium 8100 Magnesium 31000 Manganese 17 Sodium 99000 Silicon 4600 Si02, Silica 9900 Client Sample ID: OW 409-L-DD Date Collected: 11/19/13 00:00 Date Received: 11/20/13 09:20

[ Gene<al Cheml*t'Y Analyte Result Qualifier Ammonia 710 HA Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-13 of 111 RL MDL 5.0 3.5 0.020 0.0040 0.020 0.0030 0.10 0.010 0.20 0.020 0.25 0.025 RL MDL 10 1.0 RL MDL 5.0 0.54 5.0 0.54 5.0 0.54 RL MDL 100 68 50 20 100 42 50 5.6 2.0 0.25 50 15 250 18 540 38 RL MDL 50 9.2 Page 11 of 21 Unit D

mg/L mg/L mg/L mg/L mg/L mg/L Unit D

mg/L Unit D

mg/L mg/L mg/L Unit D

ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L Unit D

ug/L TestAmerica Job 10: 160-4584-1 Lab Sample ID: 160-4584-1 Matrix: Water Prepared Analyzed Oil Fac 11127/13 11:00 1

11120/1318:13 11120/1318:13 11120/1318:13 11120/1318:13 11120/1318:13 Prepared Analyzed Oil Fac 11120/13 18:28 20 Lab Sample ID: 160-4584-2 Matrix: Water Prepared Analyzed Oil Fac 12/03/13 10:55 1

12/03/13 10:55 12/03/13 10:55 Lab Sample ID: 160-4584-3 Matrix: Water Prepared Analyzed Oil Fac 11126/13 15:53 12/06/13 02:12 1

11126/13 15:53 12/06/13 02:12 11126/13 15:53 12/06/13 02:12 11126/13 15:53 12/06/13 02:12 11126/13 15:53 12/06/13 02:12 11126/13 15:53 12/06/13 02:12 11126/13 15:53 12/06/13 02:12 11126/13 15:53 12/06/13 02:12 Lab Sample ID: 160-4584-4 Matrix: Water Prepared Analyzed Oil Fac 12/23/13 17:52 1

TestAmerica St. Louis RCN: CRP-1 070.1 Page 11 of 32 D

Client Sample Results Client: AMEC Environment & Infrastructure, Inc.

TestAmerica Job 10: 160-4584-1 Project/Site: Clinch River-6468-13-1072 Client Sample ID: OW 409-U-A Lab Sample ID: 160-4584-5 Date Collected: 11/19/13 00:00 Matrix: Water Date Received: 11/20/13 09:20 General Chemistry Analyte Result Qualifier RL MDL Unit D

Prepared Analyzed Oil Fac Total Dissolved Solids (TDS) 410 5.0 3.5 mg/L 11127/13 11:00 1

Nitrate as N 0.88 0.020 0.0040 mg/L 11120/1316:13 Nitrite as N ND 0.020 0.0030 mg/L 11120/1316:13 Fluoride 0.25 0.10 0.010 mg/L 11120/1316:13 Chloride 1.8 0.20 0.020 mg/L 11120/1316:13 Bromide ND 0.25 0.025 mg/L 11120/1316:13

[ Gene<al Cheml*t'Y-DL D

Analyte Result Qualifier RL MDL Unit D

Prepared Analyzed Oil Fac Sulfate 83 10 1.0 mg/L 11120/13 16:28 20 Client Sample ID: OW 409-U-B Lab Sample ID: 160-4584-6 Date Collected: 11/19/13 00:00 Matrix: Water Date Received: 11/20/13 09:20 General Chemistry Analyte Result Qualifier RL MDL Unit D

Prepared Analyzed Oil Fac Alkalinity 270 5.0 0.54 mg/L 12/03/13 10:55 1

Bicarbonate Alkalinity as CaC03 270 5.0 0.54 mg/L 12/03/13 10:55 Carbonate Alkalinity as CaC03 ND 5.0 0.54 mg/L 12/03/13 10:55 Client Sample ID: OW 409-U-C Lab Sample ID: 160-4584-7 Date Collected: 11/19/13 00:00 Matrix: Water Date Received: 11/20/13 09:20 Method: 6020A-Metals (ICP/MS)

Analyte Result Qualifier RL MDL Unit D

Prepared Analyzed Oil Fac Calcium 140000 500 340 ug/L 11126/13 15:53 12/06/13 02:53 5

Iron 220 50 20 ug/L 11126/13 15:53 12/06/13 02:19 Potassium 1200 100 42 ug/L 11126/13 15:53 12/06/13 02:19 Magnesium 23000 50 5.6 ug/L 11126/13 15:53 12/06/13 02:19 Manganese 11 2.0 0.25 ug/L 11126/13 15:53 12/06/13 02:19 Sodium 4800 50 15 ug/L 11126/13 15:53 12/06/13 02:19 Silicon 7600 1300 89 ug/L 11126/13 15:53 12/06/13 02:53 5

Si02, Silica 16000 2700 190 ug/L 11126/13 15:53 12/06/13 02:53 5

Client Sample ID: OW 409-U-D Lab Sample ID: 160-4584-8 Date Collected: 11/19/13 00:00 Matrix: Water Date Received: 11/20/13 09:20

~ Gene<al Cheml*t'Y Analyte Result Qualifier RL MDL Unit D

Prepared Analyzed Oil Fac Ammonia 99 HA 50 9.2 ug/L 12/23/13 17:57 1

Client Sample ID: OW 423-U-A Lab Sample ID: 160-4584-9 Date Collected: 11/19/13 00:00 Matrix: Water Date Received: 11/20/13 09:20

~ Gene<al Cheml*t'Y Analyte Result Qualifier RL MDL Unit D

Prepared Analyzed Oil Fac Total Dissolved Solids (TDS) 340 5.0 3.5 mg/L 11127/13 11:00 1

TestAmerica St. Louis Clinch River Data Report Rev. 4 CRP-1112.16 Page 12 of21 RCN: CRP-1070.1 Page H.2-14 of 111 Page 12 of32

Client Sample Results Client: AMEC Environment & Infrastructure, Inc.

TestAmerica Job 10: 160-4584-1 Project/Site: Clinch River-6468-13-1072 Client Sample ID: OW 423-U-A Lab Sample ID: 160-4584-9 Date Collected: 11/19/13 00 :00 Matrix: Water Date Received: 11/20/13 09 :20 General Chemistry (Continued)

Analyte Result Qualifier RL MDL Unit D

Prepared Analyzed Oil Fac Nitrate as N 0.14 0.020 0.0040 mg/L 11120/13 18:43 1

Nitrite as N ND 0.020 0.0030 mg/L 11120/13 18:43 Fluoride 0.090 J 0.10 0.010 mg/L 11120/13 18:43 Chloride 2.7 0.20 0.020 mg/L 11120/13 18:43 Bromide ND 0.25 0.025 mg/L 11120/13 18:43

[ Gene<al Cheml*t'Y-DL Analyte Result Qualifier RL MDL Unit D

Prepared Analyzed Oil Fac D Sulfate 24 10 1.0 mg/L 11120/13 18:58 20 Client Sample ID: OW 423-U-B Lab Sample ID: 160-4584-10 Date Collected: 11/19/13 00 :00 Matrix: Water Date Received : 11/20/13 09 :20 General Chemistry Analyte Result Qualifier RL MDL Unit D

Prepared Analyzed Oil Fac Alkalinity 290 5.0 0.54 mg/L 12/03/13 10:55 1

Bicarbonate Alkalinity as CaC03 290 5.0 0.54 mg/L 12/03/13 10:55 Carbonate Alkalinity as CaC03 ND 5.0 0.54 mg/L 12/03/13 10:55 Client Sample ID: OW 423-U-C Lab Sample ID: 160-4584-11 Date Collected: 11/19/13 00 :00 Matrix: Water Date Received : 11/20/13 09 :20 Method: 6020A-Metals (ICP/MS)

Analyte Result Qualifier RL MDL Unit D

Prepared Analyzed Oil Fac Calcium 99000 100 68 ug/L 11126/13 15:53 12/06/13 02:26 1

Iron 76 50 20 ug/L 11126/13 15:53 12/06/13 02:26 Potassium 1300 100 42 ug/L 11126/13 15:53 12/06/13 02:26 Magnesium 19000 50 5.6 ug/L 11126/13 15:53 12/06/13 02:26 Manganese 51 2.0 0.25 ug/L 11126/13 15:53 12/06/13 02:26 Sodium 8700 50 15 ug/L 11126/13 15:53 12/06/13 02:26 Silicon 7200 1300 89 ug/L 11126/13 15:53 12/06/13 02:59 5

Si02, Silica 15000 2700 190 ug/L 11126/13 15:53 12/06/13 02:59 5

Client Sample ID: OW 423-U-D Lab Sample ID: 160-4584-12 Date Collected: 11/19/13 00 :00 Matrix: Water Date Received : 11/20/13 09 :20

~ Gene<al Cheml*t'Y Analyte Result Qualifier RL MDL Unit D

Prepared Analyzed Oil Fac Ammonia 83 HA 50 9.2 ug/L 12/23/13 17:59 1

Client Sample ID: OW 1 01-L-AA Lab Sample ID: 160-4584-13 Date Collected: 11/19/13 00 :00 Matrix: Water Date Received: 11/20/13 09 :20

~ Gene<al Cheml*t'Y Analyte Result Qualifier RL MDL Unit D

Prepared Analyzed Oil Fac Total Dissolved Solids (TDS) 370 5.0 3.5 mg/L 11127/13 11:00 1

Nitrate as N 0.0054 J 0.020 0.0040 mg/L 11120/13 19:42 TestAmerica St. Louis Clinch River Data Report Rev. 4 CRP-1112.16 Page 13 of21 RCN: CRP-1070.1 Page H.2-15 of 111 Page 13 of32

Client Sample Results Client: AMEC Environment & Infrastructure, Inc.

TestAmerica Job 10: 160-4584-1 Project/Site: Clinch River-6468-13-1072 Client Sample ID: OW 1 01-L-AA Lab Sample ID: 160-4584-13 Date Collected: 11/19/13 00:00 Matrix: Water Date Received: 11/20/13 09:20 General Chemistry (Continued)

Analyte Result Qualifier RL MDL Unit D

Prepared Analyzed Oil Fac Nitrite as N ND 0.020 0.0030 mg/L 11120/13 19:42 1

Fluoride 0.22 0.10 0.010 mg/L 11120/13 19:42 Chloride 2.1 0.20 0.020 mg/L 11120/13 19:42 Bromide 0.038 J 0.25 0.025 mg/L 11120/13 19:42

[ Gene<al Cheml*t'Y-DL Analyte Result Qualifier RL MDL Unit D

Prepared Analyzed Oil Fac Sulfate 42 10 1.0 mg/L 11120/13 19:57 20 D Client Sample ID: OW 1 01-L-88 Lab Sample ID: 160-4584-14 Date Collected: 11/19/13 00:00 Matrix: Water Date Received: 11/20/13 09:20 General Chemistry Analyte Result Qualifier RL MDL Unit D

Prepared Analyzed Oil Fac Alkalinity 300 5.0 0.54 mg/L 12/03/13 10:55 1

Bicarbonate Alkalinity as CaC03 300 5.0 0.54 mg/L 12/03/13 10:55 Carbonate Alkalinity as CaC03 ND 5.0 0.54 mg/L 12/03/13 10:55 Client Sample ID: OW 1 01-L-CC Lab Sample ID: 160-4584-15 Date Collected: 11/19/13 00:00 Matrix: Water Date Received: 11/20/13 09:20 Method: 6020A-Metals (ICP/MS)

Analyte Result Qualifier RL MDL Unit D

Prepared Analyzed Oil Fac Calcium 130000 500 340 ug/L 11126/13 15:53 12/06/13 03:20 5

Iron 330 50 20 ug/L 11126/13 15:53 12/06/13 02:32 Potassium 2100 100 42 ug/L 11126/13 15:53 12/06/13 02:32 Magnesium 23000 50 5.6 ug/L 11126/13 15:53 12/06/13 02:32 Manganese 50 2.0 0.25 ug/L 11126/13 15:53 12/06/13 02:32 Sodium 7800 50 15 ug/L 11126/13 15:53 12/06/13 02:32 Silicon 3900 250 18 ug/L 11126/13 15:53 12/06/13 02:32 Si02, Silica 8300 540 38 ug/L 11126/13 15:53 12/06/13 02:32 Client Sample ID: OW 1 01-L-DD Lab Sample ID: 160-4584-16 Date Collected: 11/19/13 00:00 Matrix: Water Date Received: 11/20/13 09:20

~ Gene<al Cheml*t'Y Analyte Result Qualifier RL MDL Unit D

Prepared Analyzed Oil Fac Ammonia 310 HA 50 9.2 ug/L 12/23/13 18:01 1

Client Sample ID: OW 1 01-L-A Lab Sample ID: 160-4584-17 Date Collected: 11/19/13 00:00 Matrix: Water Date Received: 11/20/13 09:20 General Chemistry Analyte Result Qualifier RL MDL Unit D

Prepared Analyzed Oil Fac Total Dissolved Solids (TDS) 370 5.0 3.5 mg/L 11127/13 11:00 1

Nitrate as N 0.0099 J 0.020 0.0040 mg/L 11120/1319:13 Nitrite as N ND 0.020 0.0030 mg/L 11120/1319:13 TestAmerica St. Louis Clinch River Data Report Rev. 4 CRP-1112.16 Page 14 of21 RCN: CRP-1070.1 Page H.2-16 of 111 Page 14 of32

Client Sample Results Client: AMEC Environment & Infrastructure, Inc.

Project/Site: Clinch River-6468-13-1072 Client Sample ID: OW 1 01-L-A Date Collected: 11/19/13 00:00 Date Received: 11/20/13 09:20 General Chemistry (Continued)

Analyte Result Qualifier Fluoride 0.19 Chloride 2.1 Bromide 0.040 J

[ Gene<al Cheml*t'Y-DL Analyte Result Qualifier Sulfate 43 Client Sample ID: OW 1 01-L-B Date Collected: 11/19/13 00:00 Date Received: 11/20/13 09:20 General Chemistry Analyte Result Qualifier Alkalinity 290 Bicarbonate Alkalinity as CaC03 290 Carbonate Alkalinity as CaC03 ND Client Sample ID: OW 1 01-L-C Date Collected: 11/19/13 00:00 Date Received: 11/20/13 09:20 Method: 6020A-Metals (ICP/MS)

Analyte Result Qualifier Calcium 99000 Iron 310 Potassium 2100 Magnesium 22000 Manganese 48 Sodium 7600 Silicon 4200 Si02, Silica 9000 Client Sample ID: OW 1 01-L-D Date Collected: 11/19/13 00:00 Date Received: 11/20/13 09:20

~ Gene<al Cheml*t'Y Analyte Result Qualifier Ammonia 350 HA Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-17 of 111 RL MDL 0.10 0.010 0.20 0.020 0.25 0.025 RL MDL 10 1.0 RL MDL 5.0 0.54 5.0 0.54 5.0 0.54 RL MDL 100 68 50 20 100 42 50 5.6 2.0 0.25 50 15 250 18 540 38 RL MDL 50 9.2 Page 15 of21 Unit D

mg/L mg/L mg/L Unit D

mg/L Unit D

mg/L mg/L mg/L Unit D

ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L Unit D

ug/L TestAmerica Job 10: 160-4584-1 Lab Sample ID: 160-4584-17 Matrix: Water Prepared Analyzed Oil Fac 11120/1319:13 1

11120/1319:13 11120/1319:13 Prepared Analyzed Oil Fac 11120/13 19:27 20 Lab Sample ID: 160-4584-18 Matrix: Water Prepared Analyzed Oil Fac 12/03/13 10:55 1

12/03/13 10:55 12/03/13 10:55 Lab Sample ID: 160-4584-19 Matrix: Water Prepared Analyzed Oil Fac 11126/13 15:53 12/06/13 02:39 1

11126/13 15:53 12/06/13 02:39 11126/13 15:53 12/06/13 02:39 11126/13 15:53 12/06/13 02:39 11126/13 15:53 12/06/13 02:39 11126/13 15:53 12/06/13 02:39 11126/13 15:53 12/06/13 02:39 11126/13 15:53 12/06/13 02:39 Lab Sample ID: 160-4584-20 Matrix: Water Prepared Analyzed Oil Fac 12/23/13 18:03 1

TestAmerica St. Louis RCN: CRP-1 070.1 Page 15 of32 D

QC Sample Results Client: AMEC Environment & Infrastructure, Inc.

Project/Site: Clinch River-6468-13-1072 Method: 6020A-Metals (ICP/MS)

Lab Sample ID: MB 160-88197/1-A Matrix: Water Analysis Batch: 90128 Analyte Calcium Iron Potassium Magnesium Manganese Sodium Silicon Si02, Silica Lab Sample ID: LCS 160-88197/2-A Matrix: Water Analysis Batch: 90128 Analyte Calcium Iron Potassium Magnesium Manganese Sodium Silicon MB Result ND ND ND ND ND ND ND ND MB Qualifier Method: 160.1 -Solids, Total Dissolved (TDS)

Lab Sample ID: MB 160-87715/1 Matrix: Water Analysis Batch: 87715 MB MB Analyte Result Qualifier

=T~ot-a~ID~i-ss-o~lv-ed~S~ol~id~s~(T=o~S~)---------

~N=o Lab Sample ID: LCS 160-87715/2 Matrix: Water Analysis Batch: 87715 Analyte Total Dissolved Solids (TDS)

Lab Sample ID: 160-4584-1 DU Matrix: Water Analysis Batch: 87715 Sample Sample Analyte Result Qualifier Spike Added 10000 10000 10000 10000 1000 10000 5000 Spike Added 500 RL 100 50 100 50 2.0 50 250 540 RL 5.0 MDL Unit 68 ug/L 20 ug/L 42 ug/L 5.6 ug/L 0.25 ug/L 15 ug/L 18 ug/L 38 ug/L LCS LCS Result Qualifier Unit 10500 ug/L 10000 ug/L 10100 ug/L 9980 ug/L 1070 ug/L 10100 ug/L 4560 ug/L MDL Unit

~3~.5 -m-g/~L------

LCS LCS Result Qualifier Unit 486 mg/L DU DU Result Qualifier Unit D

D TestAmerica Job 10: 160-4584-1 Client Sample ID: Method Blank Prep Type: Totai/NA Prep Batch: 88197 Prepared Analyzed Oil Fac 11126/13 15:53 12/06/13 01 :59 11126/13 15:53 12/06/13 01 :59 11126/13 15:53 12/06/13 01 :59 11126/13 15:53 12/06/13 01 :59 11126/13 15:53 12/06/13 01 :59 11126/13 15:53 12/06/13 01 :59 11126/13 15:53 12/06/13 01 :59 11126/13 15:53 12/06/13 01 :59 Client Sample ID: Lab Control Sample Prep Type: Totai/NA Prep Batch: 88197

%Rec.

D

%Rec Limits 105 80-120 100 80-120 101 80-120 100 80-120 107 80-120 101 80-120 91 80-120 Client Sample ID: Method Blank Prep Type: Totai/NA Prepared Analyzed Oil Fac 11127/13 11:00 Client Sample ID: Lab Control Sample Prep Type: Totai/NA D

%Rec

%Rec.

Limits D

97 90- 110 Client Sample ID: OW 409-L-AA Prep Type: Totai/NA RPD RPD Limit

=T~ot-a~ID~i-ss-o~lv-ed~S~ol~id~s~(T=D~S~)------

~5=2~0

~5=2~6

-m-g/~L-----

0.6 20 Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-18 of 111 Page 16 of21 TestAmerica St. Louis RCN: CRP-1 070.1 Page 16 of32 I

QC Sample Results Client: AMEC Environment & Infrastructure, Inc.

Project/Site: Clinch River-6468-13-1072 Method: 300.0- Anions, lon Chromatography Lab Sample ID: MB 160-88825/3 Matrix: Water Analysis Batch: 88825 MB MB Analyte Result Qualifier

~N~itr-a~te_a_s~N~------------------

~N=o Nitrite as N ND Fluoride ND Chloride ND Brom~e ND Sulfate ND Lab Sample ID: LCS 160-88825/4 Matrix: Water Analysis Batch: 88825 Analyte Nitrate as N Nitrite as N Fluoride Chloride Bromide Sulfate Lab Sample ID: 160-4584-5 MS Matrix: Water Analysis Batch: 88825 Sample Sample Analyte Result Qualifier

~N~itr-a-te_a_s~N~---------------

~0~

. 8~8 Nitrite as N ND Fluoride 0.25 Chloride 1.8 Brom~e ND Lab Sample ID: 160-4584-5 MSD Matrix: Water Analysis Batch: 88825 Analyte Sample Sample Result Qualifier Spike Added 0.400 0.160 1.00 2.00 2.00 8.00 Spike Added 0.400 0.100 2.00 2.00 2.00 Spike RL 0.020 0.020 0.10 0.20 0.25 0.50 MDL Unit

0~.~00~4~0 -m-g/~L------

0.0030 mg/L 0.010 mg/L 0.020 mg/L 0.025 mg/L 0.050 mg/L LCS LCS Result Qualifier Unit 0.397 0.164 0.980 1.93 1.99 7.74 MS MS mg/L mg/L mg/L mg/L mg/L mg/L Result Qualifier Unit 1.29 0.171 F

2.37 3.68 2.09 MSD MSD mg/L mg/L mg/L mg/L mg/L Added Result Qualifier Unit D

TestAmerica Job 10: 160-4584-1 Client Sample ID: Method Blank Prep Type: Totai/NA Prepared Analyzed 11120/13 15:29 11120/13 15:29 11120/13 15:29 11120/13 15:29 11120/13 15:29 11120/13 15:29 Oil Fac Client Sample ID: Lab Control Sample Prep Type: Totai/NA D

%Rec 99 102 98 97 100 97

%Rec.

Limits90-110 90-110 90-110 90- 110 90- 110 90- 110 Client Sample ID: OW 409-U-A Prep Type: Totai/NA D

%Rec 101 171 106 94 104

%Rec.

Limits 90- 110 90- 110 90- 110 90-110 90-110 Client Sample ID: OW 409-U-A Prep Type: Totai/NA

%Rec.

RPD D

%Rec Limits RPD Limit Nitrate as N Nitrite as N Fluoride Chloride Bromide 0.88 ND 0.25 1.8 ND Method: 300.0- Anions, lon Chromatography-DL Lab Sample ID: 160-4584-5 MS Matrix: Water Analysis Batch: 88825 Sample Sample Analyte Result Qualifier

~S-ul~fu-te--~D~L-----------------

~8~3 Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-19 of 111 0.400 1.30 mg/L 0.100 2.00 2.00 2.00 Spike Added 80.0 0.181 F

2.37 3.70 2.13 MS MS mg/L mg/L mg/L mg/L Result Qualifier Unit 164 mg/L Page 17 of21 103 181 106 94 106 90- 110 1

20 90-110 90-110 90-110 90-110 5

0 0

2 20 20 20 20 Client Sample ID: OW 409-U-A Prep Type: Totai/NA D

%Rec 101

%Rec.

Limits 90- 110 TestAmerica St. Louis RCN: CRP-1 070.1 Page 17 of32 I

QC Sample Results Client: AMEC Environment & Infrastructure, Inc.

Project/Site: Clinch River-6468-13-1072 Method: 300.0- Anions, lon Chromatography-DL (Continued)

Lab Sample ID: 160-4584-5 MSD Matrix: Water Analysis Batch: 88825 Sample Sample Analyte Result Qualifier Sulfate-DL 83 Method: 310.1 -Alkalinity Lab Sample ID: MB 160-89196/1 Matrix: Water Analysis Batch: 89196 MB MB Analyte Result Qualifier Alkalinity ND Bicarbonate Alkalinity as CaC03 ND Carbonate Alkalinity as CaC03 ND Lab Sample ID: LCS 160-89196/3 Matrix: Water Analysis Batch: 89196 Analyte Alkalinity Lab Sample ID: LLCS 160-89196/2 Matrix: Water Analysis Batch: 89196 Analyte Alkalinity Lab Sample ID: 160-4584-2 MS Matrix: Water Analysis Batch: 89196 Sample Sample Analyte Result Qualifier Alkalinity 300 Lab Sample ID: 160-4584-2 DU Matrix: Water Analysis Batch: 89196 Sample Sample Analyte Result Qualifier Alkalinity 300 Bicarbonate Alkalinity as CaC03 300 Carbonate Alkalinity as CaC03 ND Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-20 of 111 Spike MSD Added Result 80.0 163 RL 5.0 5.0 5.0 Spike LCS Added Result 400 369 Spike LLCS Added Result 200 184 Spike MS Added Result 20.0 316 DU Result 299 299 ND Page 18 of21 MSD Qualifier MDL Unit 0.54 mg/L 0.54 mg/L 0.54 mg/L LCS Qualifier LLCS Qualifier MS Qualifier 4

DU Qualifier Unit mg/L D

Unit mg/L Unit mg/L Unit mg/L Unit mg/L mg/L mg/L TestAmerica Job 10: 160-4584-1 Client Sample ID: OW 409-U-A Prep Type: Totai/NA 0/oRec.

RPD D

%Rec Limits RPD Limit 100 90-110 0

20 Client Sample ID: Method Blank Prep Type: Totai/NA Prepared Analyzed Oil Fac 12/03/13 10:55 1

12/03/13 10:55 12/03/13 10:55 Client Sample ID: Lab Control Sample Prep Type: Totai/NA

%Rec.

D

%Rec Limits 92 90- 110 Client Sample ID: Lab Control Sample D

D D

Prep Type: Totai/NA

%Rec.

%Rec Limits 92 90- 110 Client Sample ID: OW 409-L-BB Prep Type: Totai/NA

%Rec.

%Rec Limits 90 80-120 Client Sample ID: OW 409-L-BB Prep Type: Totai/NA RPD RPD Limit 0.3 20 0.3 20 NC 20 TestAmerica St. Louis RCN: CRP-1 070.1 Page 18 of32 I

QC Sample Results Client: AMEC Environment & Infrastructure, Inc.

Project/Site: Clinch River-6468-13-1072 Method: 350.1 -Nitrogen, Ammonia Lab Sample ID: MB 160-94338/12 Matrix: Water Analysis Batch: 94338 MB MB Analyte Result Qualifier

~A_m_m_o~ni_a ____________________

~N=o A Lab Sample ID: LCS 160-94338/13 Matrix: Water Analysis Batch: 94338 Analyte Ammonia Lab Sample ID: 160-4584-4 MS Matrix: Water Analysis Batch: 94338 Analyte Ammonia Lab Sample ID: 160-4643-C-1 MS Matrix: Water Analysis Batch: 94338 Analyte Ammonia Lab Sample ID: 160-4584-4 DU Matrix: Water Analysis Batch: 94338 Sample Sample Result Qualifier 710 HA Sample Sample Result Qualifier 110 A Sample Sample Analyte Result Qualifier

~A_m_m_o~ni_a ________________

~7~1~0 HA Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-21 of 111 Spike Added 500 Spike Added 500 Spike Added 500 RL 50 MDL Unit

~9~.2 -ug~/L~-----

LCS LCS Result Qualifier Unit 523 A

ug/L MS MS Result Qualifier Unit 1280 FA ug/L MS MS Result Qualifier Unit 709 A F ug/L DU DU Result Qualifier Unit D

TestAmerica Job 10: 160-4584-1 Client Sample ID: Method Blank Prep Type: Totai/NA Prepared Analyzed Oil Fac 12/23/13 17:48 1

Client Sample ID: Lab Control Sample Prep Type: Totai/NA D

%Rec

%Rec.

Limits 105

--9~0~-~1~1~0- ---- ----

Client Sample ID: OW 409-L-DD Prep Type: Totai/NA D

%Rec

%Rec.

Limits 115

--9~0~-~1~1~0- ---- ----

Client Sample ID: Matrix Spike Prep Type: Totai/NA D

%Rec

%Rec.

Limits D

119

--9~0~_~1~1~0- ---- ----

Client Sample ID: OW 409-L-DD Prep Type: Totai/NA RPD RPD Limit

~7~2~1 A

-ug~/~L-----

2 20 Page 19 of21 TestAmerica St. Louis RCN: CRP-1 070.1 Page 19 of32 I

QC Association Summary Client: AMEC Environment & Infrastructure, Inc.

Project/Site: Clinch River-6468-13-1072 Metals Prep Batch: 88197 Lab Sample ID Client Sample ID 160-4584-3 OW409-L-CC 160-4584-7 OW409-U-C 160-4584-11 OW423-U-C 160-4584-15 OW101-L-CC 160-4584-19 OW101-L-C LCS 160-88197/2-A Lab Control Sample MB 160-88197/1-A Method Blank Analysis Batch: 90128 Lab Sample ID Client Sample ID 160-4584-3 OW409-L-CC 160-4584-7 OW409-U-C 160-4584-7 OW409-U-C 160-4584-11 OW423-U-C 160-4584-11 OW423-U-C 160-4584-15 OW101-L-CC 160-4584-15 OW101-L-CC 160-4584-19 OW101-L-C LCS 160-88197/2-A Lab Control Sample MB 160-88197/1-A Method Blank General Chemistry Analysis Batch: 87715 Lab Sample ID Client Sample ID 160-4584-1 OW409-L-AA 160-4584-1 DU OW409-L-AA 160-4584-5 OW409-U-A 160-4584-9 OW423-U-A 160-4584-13 OW101-L-AA 160-4584-17 OW101-L-A LCS 160-87715/2 Lab Control Sample MB 160-87715/1 Method Blank Analysis Batch: 88825 Lab Sample ID Client Sample ID 160-4584-1 OW409-L-AA 160-4584 DL OW409-L-AA 160-4584-5 OW409-U-A 160-4584 DL OW409-U-A 160-4584-5 MS OW409-U-A 160-4584-5 MS-DL OW409-U-A 160-4584-5 MSD OW409-U-A 160-4584-5 MSD-DL OW409-U-A 160-4584-9 OW423-U-A 160-4584 DL OW423-U-A 160-4584-13 OW101-L-AA 160-4584 DL OW101-L-AA 160-4584-17 OW101-L-A 160-4584 DL OW101-L-A Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-22 of 111 Prep Type Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Prep Type Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Prep Type Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Prep Type Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Page 20 of 21 Matrix Water Water Water Water Water Water Water Matrix Water Water Water Water Water Water Water Water Water Water Matrix Water Water Water Water Water Water Water Water Matrix Water Water Water Water Water Water Water Water Water Water Water Water Water Water TestAmerica Job 10: 160-4584-1 Method Prep Batch 3010A 3010A 3010A 3010A 3010A 3010A 3010A Method Prep Batch 6020A 88197 6020A 88197 6020A 88197 6020A 88197 6020A 88197 6020A 88197 6020A 88197 6020A 88197 6020A 88197 6020A 88197 Method Prep Batch 160.1 160.1 160.1 160.1 160.1 160.1 160.1 160.1 Method Prep Batch 300.0 300.0 300.0 300.0 300.0 300.0 300.0 300.0 300.0 300.0 300.0 300.0 300.0 300.0 TestAmerica St. Louis RCN: CRP-1 070.1 Page 20 of32

QC Association Summary Client: AMEC Environment & Infrastructure, Inc.

Project/Site: Clinch River-6468-13-1072 General Chemistry (Continued)

Analysis Batch: 88825 (Continued)

I Co.Somp'""

Client Sample ID LCS 160-88825/4 Lab Control Sample MB 160-88825/3 Method Blank Analysis Batch: 89196 Lab Sample ID Client Sample ID 160-4584-2 OW409-L-BB 160-4584-2 DU OW409-L-BB 160-4584-2 MS OW409-L-BB 160-4584-6 OW409-U-B 160-4584-10 OW423-U-B 160-4584-14 OW101-L-BB 160-4584-18 OW101-L-B LCS 160-89196/3 Lab Control Sample LLCS 160-89196/2 Lab Control Sample MB 160-89196/1 Method Blank Analysis Batch: 94338 Lab Sample ID Client Sample ID 160-4584-4 OW409-L-DD 160-4584-4 DU OW409-L-DD 160-4584-4 MS OW409-L-DD 160-4584-8 OW409-U-D 160-4584-12 OW423-U-D 160-4584-16 OW101-L-DD 160-4584-20 OW101-L-D 160-4643-C-1 MS Matrix Spike LCS 160-94338/13 Lab Control Sample MB 160-94338/12 Method Blank Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-23 of 111 Prep Type Totai/NA Totai/NA Prep Type Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Prep Type Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Page 21 of 21 Matrix Water Water Matrix Water Water Water Water Water Water Water Water Water Water Matrix Water Water Water Water Water Water Water Water Water Water TestAmerica Job 10: 160-4584-1 Method Prep Batch 300.0 300.0 Method Prep Batch 310.1 310.1 310.1 310.1 310.1 310.1 310.1 310.1 310.1 310.1 Method Prep Batch 350.1 350.1 350.1 350.1 350.1 350.1 350.1 350.1 350.1 350.1 TestAmerica St. Louis RCN: CRP-1 070.1 Page 21 of32

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k The Ex ert Visit us at:

www.testa merica i nc.com Page H.2-24 of 111 Test America THE LEADER IN ENVIRONMENTAL TESTING ANALYTICAL REPORT TestAmerica Laboratories, Inc.

TestAmerica St. Louis 13715 Rider Trail North Earth City, MO 63045 Tel: (314)298-8566 TestAmerica Job ID: 160-4584-2 Client Project/Site: Clinch River-6468-13-1072 For:

AMEC Environment & Infrastructure, Inc.

4021 Stirrup Creek Drive Suite 100 Durham, North Carolina 27703 Attn: Mr. Allan Tice Authorized for release by:

211412014 5:07:14 PM Ivan Vania, Project Manager II (314 )298-8566 ivan. van ia@testam ericainc. com This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.

Results relate only to the items tested and the sample(s) as received by the laboratory.

. 4 CRP-1112.16 RCN : CRP-1 070.1 Page 22 of32 II

Client: AMEC Environment & Infrastructure, Inc.

Project/Site: Clinch River-6468-13-1072 Table of Contents TestAmerica Job I D: 160-4584-2 Cover Page.............................................. 1 Table of Contents.........................................

2 Case Narrative...........................................

3 Chain of Custody.......................................... 4 Receipt Checklists......................................... 6 Definitions/Glossary.......................................

7 Method Summary.........................................

8 Sample Summary.........................................

9 Client Sample Results...................................... 1 o QC Association Summary................................... 11 Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-25 of 111 Page 2 of 11 RCN: CRP-1 070.1 Page 23 of32

Client: AMEC Environment & Infrastructure, Inc.

Project/Site: Clinch River-6468-13-1072 Job ID: 160-4584-2 Laboratory: TestAmerica St. Louis Narrative Case Narrative CASE NARRATIVE Client: AMEC Environment & Infrastructure, Inc.

Project: Clinch River-6468-13-1072 Report Number: 160-4584-2 TestAmerica Job 10: 160-4584-2 With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.

TestAmerica St. Louis attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmerica's operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.

The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory.

Calculations are performed before rounding to avoid round-off errors in calculated results.

All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.

All solid sample results for Chemistry analyses are reported on an "as received" basis unless otherwise indicated by the presence of a %

solids value in the method header. All soil/sediment sample results for radiochemistry analyses are based upon sample as dried and disaggregated with the exception of tritium, carbon-14, and iodine-129 by gamma spectroscopy unless requested as wet weight by the client."

This laboratory report is confidential and is intended for the sole use of TestAmerica and its client. This report is a supplement to the report for job 160-4584-1. The results for cation/anion balance analysis are reported in this job due to a limitation of the LIMS system and a correction of the calculation for the analysis.

RECEIPT The samples were received on 11 /20/2013; the samples arrived in good condition, properly preserved and on ice. The temperature of the coolers at receipt was 2.7 C.

CATION ANION BALANCE Samples OW 409-L-CC (160-4584-3), OW 409-U-C (160-4584-7), OW 423-U-C (160-4584-11 ), OW 1 01-L-CC (160-4584-15) and OW 1 01-L-C (160-4584-19) were analyzed for Cation Anion Balance in accordance with Cation Anion Balance. The samples were analyzed on 12/30/2013.

Refer to corrective action report 01152014-01 delivered separately for further information regarding this analysis.

No other difficulties were encountered during the Cation Anion Balance analysis. All quality control parameters were within the acceptance limits.

Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-26 of 111 Page 3 of 11 TestAmerica St. Louis RCN: CRP-1 070.1 Page 24 of32

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AMEC Project Name AMEC Project Number COCDate AMEC Environment & Infrastructure, Inc. Chain of Custody Form CRP-22 Prepared By: Kim Charles-Smith ~

Clinch River SMR Project Checked By: Kristen Lloyd '/[ll!t.

11/19113 Transferred To: Test America

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6468131072 Transferred From: Site

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IDENTIFICATION SAMPLE TYPE ORGANIZATION DATE INTENDED USE REMARKS

~ OW 409-L-AA Water-1000 ml AMEC 11/19/13 IDS~ Anions (Br, Cl, F, S04, N03~ N021 Unpreserved

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OW 409-L-BB Water-500 ml AMEC 11119/13 Alkalinity Unpreserved

'fi4-0W 409-L-CC Water - 250 ml AMEC 11/19/13 Metals w!HN03

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OW409-L-DD Water-500ml AMEC 11119/13 NH3 w/H2S04 OW 409-U-A Water-1000 ml AMEC 11/19/13 IDS, Anions (Br, Cl, F, S04, N03, N02)

Unpreserved iGft.

OW 409-U-It Water - 500 ml AMEC 11119/13 Alkalinity Unpreserved ~

OW409-U-C Water-250ml AMEC 11119/13 Metals w!HN03

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~ OW 423-U-A Water-1000 ml AMEC 11/19/13 TDS, Anions (Br, Cl, F, S04, N03, N02)

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Work to be performed in accordance with AMEC Work Instruction 64 Remarks/Freight Bill!fracking No:

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~~~~~~~----------------------------------------------------------

Recipient: After signing for receipt, copy the form and forward to the AMEC Project Manager,

  • Keep original form witb the samples.

Final sample disposition: ------ -------- - - - --- --- ------ -----------------

WTP Form ~-'1lA (Rev 0)

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Chain of Custody No.

AMEC Project Name AMEC Project Number COCDate CRP-22 AMEC Environment & Infrastructure, Inc. Chain of Custody Form

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Prepared By: Kim Charles-Smith

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SAMPLE IDENTIFICATION OW 101-L-AA OW 101-L-BB OW 101-L-CC OW 101-L-DD OW 101-L-A OW 101-L-B.

OW 101-L-C OW 101-L-D lYJJ!~~}'

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5. Relinquished by:

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Clinch River SMR Project 6468131072 11119/13 SAIVIPLE TYPE COLLECTED BY ORGANIZATION Water-1000 ml AMEC Water-500 ml AMEC Water-250 ml AMEC Water-500 ml AMEC Water-1000 m1 AMEC Water-500ml AMEC Water-250 m1 AMEC Water-500 m1 AMEC L Received by:

(signature).

3. Received by:

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. 5, Received by:

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Checked By: Kristen Lloyd

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Transferred From: Site Transferred To: Test America

--~~~~----------------------

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COLLECTION INTENDED USE REMARKS DATE 11/19/13 IDS, Anions ffir. Cl. F S04 N03. N02)

Unoreserved 11/19/13 Alkalinity Unpreserved 11119/13 Metals w/HN03 11119/13 NH3 w!H2S04 11119/13 TDS, Anions (Br, Cl, F, S04, N03, N02)

Unpreserved 11119/13 Alkalinity Unpreserved 11/19/13 Metals w/HN03 11/19113 NH3 w!H2S04 lr/iff!fime *..

2. Relinquished by:

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4. Relinquished by:

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c.v<:l N ~ Final sample disposition: --------------------------------------------------------------------------------

WTP Form 9 filA (Rev 0)

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Login Sample Receipt Checklist Client: AMEC Environment & Infrastructure, Inc.

Login Number: 4584 List Number: 1 Creator: Daniels, Brian J Question Radioactivity wasn't checked or is </= background as measured by a survey meter.

The cooler's custody seal, if present, is intact.

Sample custody seals, if present, are intact.

The cooler or samples do not appear to have been compromised or tampered with.

Samples were received on ice.

Cooler Temperature is acceptable.

Cooler Temperature is recorded.

COC is present.

COC is filled out in ink and legible.

COC is filled out with all pertinent information.

Is the Field Sampler's name present on COC?

There are no discrepancies between the containers received and the COC.

Samples are received within Holding Time.

Sample containers have legible labels.

Containers are not broken or leaking.

Sample collection date/times are provided.

Appropriate sample containers are used.

Sample bottles are completely filled.

Sample Preservation Verified.

There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs Containers requiring zero headspace have no headspace or bubble is

<6mm (1 /4").

Multiphasic samples are not present.

Samples do not require splitting or com positing.

Residual Chlorine Checked.

TestAmerica St. Louis Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-29 of 111 Page 6 of 11 Answer True True True N/A True True True True True True False True True True True True True True True True N/A True True N/A Comment Job Number: 160-4584-2 List Source: TestAmerica St. Louis RCN: CRP-1 070.1 Page 27 of32

Definitions/Glossary Client: AMEC Environment & Infrastructure, Inc.

Project/Site: Clinch River-6468-13-1072 Glossary Abbreviation

%R CNF DER Oil Fac DL, RA, RE, IN DLC MDA EDL MDC MDL ML NC ND POL QC RER RL RPD TEF TEO These commonly used abbreviations may or may not be present in this report.

Listed under the "D" column to designate that the result is reported on a dry weight basis Percent Recovery Contains no Free Liquid Duplicate error ratio (normalized absolute difference)

Dilution Factor Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample Decision level concentration Minimum detectable activity Estimated Detection Limit Minimum detectable concentration Method Detection Limit Minimum Level (Dioxin)

Not Calculated Not detected at the reporting limit (or MDL or EDL if shown)

Practical Quantitation Limit Quality Control Relative error ratio Reporting Limit or Requested Limit (Radiochemistry)

Relative Percent Difference, a measure of the relative difference between two points Toxicity Equivalent Factor (Dioxin)

Toxicity Equivalent Quotient (Dioxin)

Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-30 of 111 Page 7 of 11 TestAmerica Job 10: 160-4584-2 TestAmerica St. Louis RCN: CRP-1 070.1 Page 28 of32

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