ML11193A133
ML11193A133 | |
Person / Time | |
---|---|
Site: | Davis Besse ![]() |
Issue date: | 05/27/2011 |
From: | FirstEnergy Nuclear Operating Co |
To: | Office of Nuclear Reactor Regulation |
References | |
L-11-165 | |
Download: ML11193A133 (760) | |
Text
{{#Wiki_filter:I Enclosure C -Binder 2 of 2 Davis-Besse Nuclear Power Station, Unit No. 1 (DBNPS)Letter L-1 1-165 References Page 1 of 3 Enclosure C -Binder 2 of 2 L-1 1-165 Page 2 of 3 Hydrology Browser-Morner Associates, Inc., 2002, letter J. Hewlett, Senior Geologist, to First H 1 Energy Service Co. c/o Toledo Edison Company, regarding Preliminary Wetland Evaluation, Proposed Temporary Containment Area, Davis-Besse Plant, July 19.Centerior Energy, 1994, letter from L.F. Storz, Vice-President -Nuclear, Davis-Besse, H 2 to T.O. Hickin, Division of Emergency and Remedial Response, Ohio Environmental Protection Agency, in, regarding Submittal of Information Regarding Spill of Gasoline, Identification Number 01-62-0180, February 22.Davis-Besse Nuclear Power Station, 2004, Periodic Test.Procedure DB-CN-04032, H 3 Wastewater Treatment Sludge Holding Tank Analysis, Revision 01, prepared by R. Edwards, October 28.Davis-Besse, 2004, National Pollutant Discharge Elimination System (NPDES) H 4 Program, Administrative Procedure DB-CN-00030, prepared by S. Chimo, June 21 Davis-Besse, 2007, Business Practice DBBP-CHEM-2005, Spill Prevention Control H 5 and Countermeasure (SPCC) Plan, approved by V. Capozziello, March 16.Davis-Besse, undated, Condition Report #04-01719, "In 20 04-05 Spent Fuel Pool H 6 Leakage to Onsite Groundwater," discovery date 3/5/2004 Davis-Besse, undated, Business Practice DBBP-CHEM-2009: Storm Water Pollution H 7 Prevention Plan, Rev. 00, 28 pages Environmental Resources Management, 2007, Groundwater Flow Characteristics Report, Davis-Besse Nuclear Power Station, Oak Harbor, Ohio: prepared for H 8 FirstEnergy Nuclear Operating Company, January 16.Environmental Resources Management, 2008, Groundwater Monitoring Well H 9 Installation & Monitoring Report, Davi s-Besse Nuclear Power Station, Oak Harbor, Ohio: prepared for FirstEnergy Nuclear Operating Company, March 18.First Energy, 1998, letter from J.H. Lash, Plant Manager, Davis-Besse Nuclear Power H 10 Station, to C. Zipp, State Fire Marshall Office, regarding Underground Storage Tank Overfill Release Report, Incident Num ber 6281145-00, September 18.FirstEnergy Nuclear Operating Company, 2007, letter from V.A. Kaminskas, H 11 Director-Site Operations, to A. Gall, Division of Surface Water, Ohio Environmental Protection Agency, regarding Submittal of 2006 Annual Sludge Disposal Report for the Davis-Besse Nuclear Power Station, January 29.FirstEnergy Nuclear Operating Company, 2008, letter from V.A. Kaminskas, H 12 Director-Site Operations, to R. Zuzik, Division of Surface Water, Ohio Environmental Protection Agency, regarding Submittal of 2007 Annual Sludge Disposal Report for the Davis-Besse Nuclear Power Station, January 18.FirstEnergy Nuclear Operating Com pany, 2009, letter from B. Allen, Vice President -H 13 Nuclear, to A. Gall, Sewage Sludge Coordinator, Ohio Environmental Protection Agency, regarding Submittal of the 2008 Annual S ludge Disposal Report for the Davis-Besse Nuclear Power Station, January 23. Enclosure C -Binder 2 of 2 L-1 1-165 Page 3 of 3 FirstEnergy Nuclear Operating Company, 2010, letter from P.M. Boissoneault, H 14 Manager, Site Chemistry, to A. Gall, Sewage Sludge Coordinator, Ohio Environmental Protection Agency, regarding Submittal of the 2009 Annual Sludge Disposal Report for the Davis-Besse Nuclear Power Station, January 21.FirstEnergy Nuclear Operating Company, 2011, letter from P.M. Boissoneault, H 15 Manager, Site Chemistry, to A. Gall, Sewage Sludge Coordinator, Ohio Environmental Protection Agency, regarding Submittal of the 2010 Annual Sludge Disposal Report for the Davis-Besse Nuclear Power Station, January 25.FirstEnergy, 2010, letter from S.F. Brown, Senior Engineer, to R. Zuzik, Division of H 16 Surface Water, Ohio Environmental Protection Agency, regarding National Pollutant Discharge Elimination System Permit Renewal Application, Davis-Besse Nuclear Power Station, EPA ID No. OH0003786, Permit No. 21B0001 1*D, October 21.OEPA, 2010, letter from E. Swindall, Division of Water, to FirstEnergy Nuclear Gen H 17 Corp -Davis-Besse, regarding Preliminary Compliance Review of Discharge Monitoring Report, Novem ber 20.OEPA, 2010, letter from E. Swindall, Division of Water, to FirstEnergy Nuclear Gen H 18 Corp -Davis-Besse, regarding Preliminary Compliance Review of Discharge Monitoring Report, Septem ber 21.Davis-Besse, undated, Graphs of tritium in wells H 19 Socioeconomics, Environmental Justice & Land Use EJS4, 5_Support Payments &Property Values S1 EJS3_Site Pop List_2-25-09 (county sort) S2 EJS3_ATTCH EJS-3 S3 EJS2_L10-120 2009 Annual Rad Effluent Release Rpt S4 All 3 U.S. Government Leases for Ottawa Wildlife Refuge S5 Formal documentation for land swap agreement does not exist --Cultural Copies of photographs (6, 7, 15, 18, and 19 on flash drive at audit) demonstrating the C 1 level of disturbance on the industrialized portions of the plant.Draft Final Preliminary Assessment Report: Locust Point Anti-Aircraft Artillery Firing C 2 Area, FUDS Property No. G050H0996, Nov 2010, 2 volum es, prepared by Shaw Environmental for Army Corps of Engineers. Request for Docket.NOTE: Volume 1 (Main Body) of C 2 is provided in hard copy.Volume 2 (Attachments) of C 2 is provided on Compact Disk due to the size (>2,000 pages) of Volume 2. FOR INTERNAL USE ONLY FileNet Information for Letter L-11-165 FileNet Keywords: Correspondence; License Renewal Application; Request for additional information; RAI response; environmental report; air and metrology; aquatic;terrestrial; hydrology; socioeconomics; environmental justice; land use I "S BOWSER-MORNER 1419 Miami Street
- P. 0. Box 838
- Toledo, Ohio 43697-0838 (419) 691-4800 Environmental Service Report Client: First Energy Service Co.c/o Toledo Edison Company Attention:
Mr. Peter Mainhardt Davis-Besse Plant Storeroom 5501 North State Route 2 Oak Harbor, Ohio 43449 Project: PRELhMINARY WETLAND EVALUATION, PROPOSED TEMPORARY CONTAINMENT AREA, Davis-Besse Plant, 5501 North State Route 2, Oak Harbor, Ottawa County, Ohio Job No.: 125959 Report No.: 125959-0702-420 Date of Report: July 19, 2002 Author: Julie K. Hewlett Report Consists of 3 Pages Ladies and Gentlemen: We are pleased to submit the following environmental service report documenting our preliminary wetland evaluation of the proposed temporary containment area. MVis. Julie K.Hewlett, Senior Geologist from Bowser-Morner, evaluated the study area on July 19, 2002. The weather was hot and cloudy at the time of the site visit. No significant precipitation had occurred for several weeks.The study area consisted of a narrow 2/10-mile long parcel. The attached First Energy drawing shows the general location of the study area. The study area was bounded on the south by a ditch and associated dike. Farther to the south was the open water edge of the Ottawa National Wildlife Refuge. The eastern terminus of the study area was the beach station pump house. The study area was bounded on the north by a service road and intake canal.The intake canal is scheduled for dredging. Temporary dikes are proposed to completely surround the study area perimeter. Dredge spoils pumped into the temporary containment area would be allowed to settle. Clear water would be pumped back into the intake canal and also be allowed to naturally decant. Dried spoils would be moved to a permanent storage location and the temporary dikes removed. It is our understanding that the roadway between the study area and intake canal would remain open for traffic.Study area observations indicate local topography is sloped from the roadway, in a southerly direction towards the ditch. The ditch and associated dike most strongly appear in the western portion of the study area, and fade away towards the east. Wetland hydrology (standing water)was noted only in the bottom of the ditch and in the open water edge of the Ottawa National Wildlife Refuge located nearby to the south of the study area.The vegetation community friom the roadway towards the ditch and dike appeared to consist of upland grasses and weeds. Shrubs and bushes consisted of willow, dogwood, and cottonwood. The ditch west end contained Phragmites, indicating wet conditions during part of the year.All Reports Remain The confidential Property Of Bowser-MomerAnd No Publication Or Distribution Of Reports May Be Made Without Our Express Witten Consent, Except As Authorized By Contract. Results Contained In This Report Are Reflective Only Of The Items Calibrated Or Tested. Vnless Otherwise Agreed, Samples Or Specimens Will Be Discarded Or Returned At Bowser-Morner's Discretion. Study area soils consist of cut and fill materials placed to raise the roadway and dikes above the W level of Lake Erie, when Davis-Besse was originally constructed. In our opinion, an upland community exists from the edge of the roadway across the study area towards the south to the dike arid associated ditch. The ditch appears to have been constructed to drain surface water form the roadway. Due to tile man-made character of the study area, lack of hydric soils and lack of near surface water, it does not appear to meet the requirements of a jurisdictional wetland.In our opinion, a temporary containment area could be constructed in the upland area between the roadway and the dike in the southwest portion of the study area. Where the ditch and dike appear to fade away in the southeastern portion of the study area, the upland community appears to extend all the way to the open water edge of the Ottawa National Wildlife Refuge.To facilitate settlement of suspended solids, temporary containment should offer sufficient volume and retention. Retention of suspended solids could be enhanced by configuration, deflector curtains, wing walls, and polymer injection. If additional engineering or scientific consultation is required, Bowser-Morner could provide these design services through a change order.We hope that this preliminary wetland evaluation of the proposed temporary containment area is sufficient for your project management needs. If you have any further questions, please contact our, office.¶Respectfully submitted,BOWSER-MORNER ASSOCIATES, INC.\ .' Julie K. Hewlett, CPG 6661 Senior Geologist JKH:ahltjk Attachments: Sketch 3-Client 0 BOWSER Report No. 125959-0702-420 MORNERo .I ell J-0 b It I ?- Sq S-1 IlowseF-- Mo(ý3,31eP-7-)q S'.3 CENTERIOR 14 ENER~GY 300 Madison Avenue Toledo, OH 43652-0001 419-249-2300 Louis F. Slorz Vice Piesident-Nucleor Dovis-Besse RAOG 94-09 February 22, 1994 Timothy 0. Hickin Emergency Response Unit Supervisor Emergency Response Section Division of Emergency and Remedial Response Ohio Environmental Protection Agency 1800 Watermark Drive P.O. Box 1049 Columbus, OH 43266-0149
Subject:
Submittal of Information Regarding Identification Number 01-62-0180 Spill of Gasoline
Dear Mr. Hickin:
In accordance with Section 3750.06(D) of the Ohio Revised Code and Rule 3750-25-25(A)(2) of the Ohio Administrative Code, enclosed is the information on the onsite release of unleaded gasoline at the Davis-Besse Nuclear Power Station reported on January 18, 1994; spill event identification number 01-62-0180. Should you be in need of any further information, please contact Mr. W. T. O'Connor, Manager -Regulatory Affairs at (419) 249-2366.Sincerely yours, JCS/lkg Attachments (FS cc: M. Gerber, Ohio Environmental Protection Agency Local Emergency Planning Committee (Ottawa County)Operoling Companies: Cleveland Eleclric Illuminating Toledo Edison RAOG 94-09 Enclosure Page 1 TOLEDO EDISON RESPONSE TO OHIO EPA SPILL EVENT I IDENTIFICATION NUMBER 01-62-0180 JANUARY 18, 1994 DAVIS-BESSE NUCLEAR POWER STATION 1. Reporting and Event Summary Question: a) Time, date and duration of release or discharge. b) Time and date of discovery of the release or discharge. c) Indicate the Ohio EPA spill number and the National Response Center case number.d) Provide an event summary.Response: a) The actual time, date and duration of the release is unknown. The release most likely occurred between approximately 0300 hours on January 16, 1994, (the last recorded vehicle refueling) and 1130 hours January 17, 1994 (the first recorded observation of pump malfunction). b) The actual time and date of discovery of the release of gasoline was approximately 1800 hours on January 18, 1994.c) The Ohio Environmental Protection Agency Spill Response Number is 01-62-0180. The National Response Center Number is 217385.d) On Monday, January 17, 1994, approximately 1300 gallons of gasoline were found missing from the above ground gasoline storage tank at Service Building 4. The gasoline is used to service site vehicles; pool cars, snow plows, etc. On the morning of January 17, the gasoline pump appeared to be malfunctioning. Gasoline was pumped from the tank and about eight gallons were pumped and the flow stopped. The storage tank level was checked and measured approximately 100 gallons. The measurement of the tank on Friday, January 14, indicated approximately 1470 gallons with 88 gallons being dispensed over the weekend. The last gasoline was pumped from the tank on January 16, 1994, at 0300 hours.Industrial Safety and Environmental were notified of the missing gasoline. The site was checked for indications of a gasoline spill.There was no evidence of gasoline in the concrete dike surrounding the tank, or of any amounts around the gasoline pump or inside the pump housing, or in any of the areas' storm water outfalls (i.e., marsh or ponds). No gasoline odors were present. Security was notified for potential theft investigation. On January 18, 1994, the tank and underground piping to the gasoline pump'were pressure tested with no evidence of any leaks. The gasoline tank was partially filled and the pump was tested by pumping gasoline through the pump. When the pump was stopped, gasoline was observed to be siphoning through the gasoline pump fire safety valve's atmospheric vent.This leak path was established when a diaphragm failed in the fire safety valve. This confirmed that the gasoline had been released to the environment, not stolen as was previously suspected. It is suspected that the fire safety valve's diaphragm failed due to the extremely cold RAOG 94-09 Enclosure Page 2 weather on January 16, 1994, and at 0300 hours, when the pump was last used, gasoline siphoned through the atmospheric vent until the pump's suction was uncovered (100-gallon tank level).At 1800 hours on January 18, 1994, notifications were made in the following sequence: the National Response Center, the State Emergency Response Center, and the Ottawa County Sheriff's Department as required for the local fire department and local emergency planning committee notifications. At approximately 2120 hours on January 18, 1994, the OEPA Division of Emergency and Remedial Response representative arrived onsite and inspected the spill area.Collection activities to date have recovered approximately 500 gallons of gasoline and determined how far the gasoline has spread. The gasoline is contained in the porous fill underneath the Service Building 4 parking lot and poses no environmental concerns as it has not entered the marsh area, and is confined within Toledo Edison's property. The leak has been isolated and repaired. See Attachment 2 for a sketch of the incident scene.2. Location Question: a) Location of the facility from which the release or discharge occurred.b) Location of the release or discharge. c) Longitude and latitude Response: a) Toledo Edison Company Davis-Besse Nuclear Power Station 5501 North State Route 2 Oak Harbor, Ohio 43449 b) Ottawa County Carroll Township Oak Harbor (nearest village)c) The longitude and latitude of the Davis-Besse-Nuclear Power Station is 410 36' N, 830 05' W. Attachment 1 contains a map showing the site location. The release was not transportation related. RAOG 94-09 Enclosure Page 3 3. Product Release Question: a) Chemical name (common name or technical name) and Chemical Abstracts Service (CAS) registry number of the substance involved in the discharge or release.Response: a) The material released was Gasoline, BP Super Unleaded (No CAS Number is available because the product is a mixture). The Material Safety Data Sheet (MSDS) is attached (Attachment 5). The material is not an extremely hazardous substance. The estimated release quantity was approximately 1300 gallons.4. Environmental Impact Question: a) Identify the environmental medium or media impacted and the extent of the impact.Response: a) The gasoline was released into the soil underneath the gasoline pump.The estimated area of contaminated subsurface soil is 2500 square feet.There appears to be a zone of gasoline-contaminated soil approximately six inches wide. This zone is approximately three feet below the ground just above the clay substrate. The spill is 400 feet from the nearest waterway, no navigable waterways have been or are anticipated to be affected.Collection activities to date have recovered approximately 500 gallons of the gasoline and determined how far the gasoline has spread. The gasoline is contained in the porous fill underneath the Service Building 4 parking lot and poses no environmental concerns as it did not enter the marsh area and was confined within Toledo Edison's property.Additionally, the soil beneath the porous fill material is composed of a clay substrate which is very dense and has prevented the gasoline from migrating deeper. Area storm water drains have been isolated to prevent the potential of the gasoline from being released off site.5. Monitoring and Detection Question: a) If the release or discharge was monitored, indicate the method of detection and concentrations. RAOG 94-09 Enclosure Page 4 Response: a) As described in Section 1.d., Event Summary, the gasoline leak is thought to have occurred during the weekend of January 15 and 16, 1994.The release path. to the ground is not a monitored pathway and was unnoticed by site personnel. For event detection specifics, refer to Section i.d., Event Summary.6. Mitigation and Containment Action Question: a) Amount recovered or neutralized. b) Describe any actions taken to reduce the impact of the release or discharge. c) Actions taken to respond and contain the release or discharge. Response: a) To date, approximately 500 gallons of gasoline have been recovered from the-gasoline recovery sumps that were dug to collect the gasoline, and storm water oil interceptors. These low collection points are being monitored and the material is being collected throughout the remediation process.b),Veather conditions (-IOF) predicted a low probability of migration at c) the time of the release. The storm water line oil interceptors were pumped out for initial recovery. Recovery sumps were dug to recover additional bulk gasoline which may be present and to determine how far the gasoline had spread. Attachment 2 contains a sketch of the incident scene. Approximately 500 gallons of gasoline has been recovered to date. Gasoline recovered from the recovery sumps has slowed. The remaining gasoline appears to be contained in the porous fill beneath the parking lot. Additionally, the storm water lines have been plugged to prevent any gasoline from leaving the site from this pathway. Further remediation activities to remove the residual gasoline contamination from the soil are currently being evaluated.
- 7. Preventive Actions Question: a) Provide plans to preventa recurrence of the release or discharge.
Response: a) The pump and above ground storage tank were taken out of service. The gasoline pump will be repaired and redesigned to ensure that any future pump failure would be captured in secondary containment. RAOG 94-09 Enclosure Page 5 8. Health Risks Question: a) Describe any known or anticipated acute or chronic health risks associated with the release or discharge. b) Advice regarding medical attention necessary for individuals exposed to the substance released or discharged. Response: a) No known or anticipated acute or chronic health risks are associated with the release as long as the plume is contained in the soil substrate and completely removed or remediated, and there is no migration into waterways or exposure to cleanup personnel. b) N/A 0 9.Question: a) Indicate any air, water or other permit numbers which may be pertinent to this incident.Response: a) The National Pollutant Discharge Elimination System (NPDES) permit number for the Davis-Besse Nuclear Power Station is 2IB00011*ED. The gasoline was contained to the Davis-Besse site. The gasoline did not enter into the "waters of the state" and posed no environmental concerns.Question: a) Provide a chronological summary of the incident. Include a chronology of communications with the state and local government agencies.Response;a) Chronological Review 10.Date Time Event January 17, 1994 ~1130 Measured tank level and noticed -1300 gallons of gasoline missing.0 RAOG 94-09 Enclosure Page 6 Date Time January 17, 1994 .1200 January 18, 1994 January 18, 1994 January 18, 1994 January 18, 1994 January 18, 1994 January 18, 1994 January 18, 1994 January 18, 1994-1000-1730-1830-1903-1918-1948 Event Environmental and Safety personnel responded to scene and commenced investigation. No evidence of spillage on ground or in marsh area, or site ponds. Pump housing inspected and no indication of gasoline. No gasoline present in concrete dike surrounding the tank. Theft of gasoline was suspected. Piping between tank and pump pressure tested. No indications of leak in pipe.Still no indication of gasoline spill at scene.Refilled tank and tested pump.Identified leak from fire safety valve in gasoline pump. Leak immediately isolated and capped, pump and tank were tagged out to prevent use and further release.Notified plant management of gasoline leak and spill. Commenced notification of regulatory agencies. Commenced product recovery. Recovered ~300 gallons of gasoline from oil separators. Notified National Response Center (Petty Officer Floyd) of the release of gasoline. No release to "waters of the State" occurred.Notified Ohio EPA.Ohio EPA Night Duty called and gasoline provided.officer (Tom Buchan)release information -1955-2010 Ohio EPA, Division of Emergency Response, Emergency Response Coordinator (Mike Gerber) called to get release details. Indicated he would come onsite to investigate. Ottawa County Sheriff (Deputy Sauvey)was notified of gasoline release.Ottawa County Sheriff is point of contact for Ottawa County Emergency Manageieent Agency (EMA) for local fire department and LEPC (local emergency planning committee). RAOG 94-09 Enclosure Page 7 Date Time-2120 Event January 18, 1994 Division of Emergency Response, Emergency Response Coordinator (Mike Gerber) arrived onsite for release investigation. 11.12.Question: a) Provide manifest, bills of lading, laboratory analyses which were generated which are germane to the incident.Response: a) See Attachments 3 and 4 for sample results and manifests. Question: a) Describe any extenuating circumstances which caused the discharge. Response: a) The cause of the failure of the gasoline pump fire protection valve diaphragm is believed to be the severe cold weather conditions that occurred during 'the weekend of January 15 and 16, 1994. 0 Io'* -a.Pr-I.--4 4- .4--~-*- -'S -*-----A 1- --4.. 4- -4 , ,.q ,,...T... ,vc.\. ---~-*- a-* NO Tff: ...AA'ALL CL(VATIONV. ARE FEFEIRAqE TO .,T.LL.i I t IIV x OG A;.Map Reproduced from Updated Safety Analysls Report Volume 3 ý TO MR%aLECTRI C INCH~TTH RAOC 94-09 Atcachmena 2 0 1PM nRa Del rw.tlm buod m~ i&wvatiwc of tint Its mly. koo MW b ro-&ffriod t 1= 91ri cItrvo (in =ancrts)WJNTIWE1 -AWGE FACILIfY MICHIGAN DEPARTMENT OF NATURAL RESOURCES A RAOG 94-09 1969"01- as a..enaeo ag ACt 1:e^ .I,,..Attachment 3 Failure to ilel Ispunishable under section M995.48 MCI or section 10 of DO NOT WRITE IN THIS SPACE Act 136, PA. 1969.ATT. ] DIS. F) REJ. [] PR. E]Form Approved. OMB No. 2050.0039 Expres 9.3Up4 erator's US EPA ID Noa 2 in the shaded areas ss not required by Foderal~ 6I7of ~o~ ~ of / law.Up leases prin or type.-- L WI ik UNIFORM HAZARDOUS 1.Gen.WASTE MANIFEST AO J]l.inerators Name and Mailing Address"OLF-Po -PIpA'l /- .,-r ,.TOP .5 O 4. Generator's Phone 1 &4?I :o, A. Stale Manifest Document Number MI *3078050.B..State Generator's ID-..........-...........................-........... "...!5.Traensporter I Company Name' 6. US EPA ID Number C.- State Transporters IIY!*1;,Oý:%w-r 7 ~ ~ ~ ~ ~ )j 10 COMP/1 CO&P. DO/DI¶ý$'h. Transportor's Phone o.fo Tr-nspotter 2 Company Name 8. US EPA ID Number -E.'.State Transporter's ID.Li-i I I I I I -I L-_ F. Transporter's Phone Facility Site 1o. US EPA ID Number G. Stlie Facility's ID g 0, i-A-0 LL I r K/...V / O H. FaciIlty's, hone -.1 I. US DOT Description (including Proper Shipping Name, Hazard Class, and 12.Containers
- 13. 1 .Waste Decitin(ncuigTotal Un " NO.H._ ID NUMBER). No. Type Quantity N/H_I -of u 0I0 (A I_ " C.IJ I- I ...1 d.ik.J<'.dditional Descriptions for.Materials Usted Above, ..K. ,adllng 9pdes.-for
ýstel at/ /..SC.... bl Ied Aboieb l15 ..Spcial Handling Instructions and Additional informationIL / f rM A o, rt 'u1 d C G. C4; M ' FF II?!, -.,W -Pp /5ob IO 1/' c Q 4PilibdLs bl Ifp.O6Lr, , r6A ., _, 16. GENERATOR'S CERTIFICATION: I hereby declare that the contents of this consignment are fully and accurately described above by proper shipping name and are classified, packed, marked, and labeled, and are in all respects In proper condition for transport by highway according to applicable international and national govemmenl regulations. If I am a large quantity generator, I certify that I have a program in place to reduce the volume and toxicity of waste generated to the degree I have determined to be economically practicable and that I have selected the practicable method of treatment, storage, or disposal currently available to me which minimizes the present and future threat to human health and the environment; OR; if I am a small quantity generator. I have made a good faith effort to minimize my waste generation and select the best waste management method that is available to me and that I can afford.I Date i Printod/Typed Name Signature "Month D Ye0 I -!S eP-k-e, M,~,;("A ,dýCLJ,10._I, 9 ý K 19 -031c/I /Piti4 T 17.Transporer I Acknowledgement of Receipt of Materials Date P 0 1S. Transporteo 2 Acknowledgement or Receipt of Materials Dole-T Printed/Typed Namemonth Day Year 19. Discrepancy Indication Spac5 ,, -71r-i 20. Facility Owner or Operator: Certification of receipt of hazardous materials covered by this manifest except tis noted in Item 19. Oai Printed/Typed Name Signature month Day Yea,/[ LLL -i I i EPA Form 8700-22 (Rev. 9188)To he mailed by Michigan DNR G,,imor to- Box 30038 PR SIl o Rev. 10,S2
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- -0-9922 ERM7- 1 :Ti.E IRS IS. Special Handling Inslrrctions and Additional Informalion P01* VERBAL "EL#USE GLOVES & GOGGLES: PLIMP TANK NEED 60' OF HOSE CALL 419-321-7149 AND STEVE WILL. MEET Y--OU TO LOAD AREA4 ACCEPT 0 (a) -(r0lr,-85 ALL SPILLS MUST BE REPORTED TO THE NATIONAL RESPONSE CENTER AT (800) 424.8802, 24 HOURS PER DAY. ~ X ,/ -.16. GENERATOR'S CERTIFICATION, I hereby declare that the contents of thIs consignment are fully and accurately described above by proper shipping name and are classified, packed, marked, and labeled, and are in all respects In proper conddlk>n to tforanspo by highway according to applicable international and nalionat government regulations.
Ill am a large quantity generator, I certify that I have a program in place to reduce the volume and toxicity of waste generaled to the degree I have determined to be ecoomically praclicable and that I have selected the practicable method oetrealment, storage, or disposal currently available to me which minimizes the present and future threat to human heallh and the environment; OR, if I am a small quanlity generator, I have made a good faith effot to minimize my waste generation and select the best waste management method that is available to me and that I can atford.PrintedfTyped Name Signature Month Day Year 17. Trandporter I Ackonwledgement or Receipt of Materials -Dale R Prinje'd--~y. esignatfe'I Monrh Oay year o l6. dn 2 Acknýledefen o(r ReceipI or Materials --Date iI Printed/Typed Name Signature Month Day Year E R 19. Discrepancy Indication Space F A C L 20. Facility Owner or Operator: Cenilhcalion ot receipt of hazardous materials covered by ihis manifest except as noted in Item 19.Dale y PrinledlTyped Name Signature Montr Day rear I I ! I ya 0 EPA Form 8700-22 (Rev. 9-88) Previous editions are obsolete. GENERATOR'S COPY I Please print or type. (F"nr ~dewýt, W'Veo asiar f;2.pvh) qP-Afer)1 Fc, Abam a No. 005000" &c&" O LINIUM H Generator's US EPA t0 No. Manifest 2. Page 1n Doc ent No.f ation in the shaded areas WASTE MANIFEST 1H is7 05 ...... ..09278 -t 1 i not required by Federat law.3 Generator's Name and Mailing Address A. State Manifest Document Number 1.iAK HARBOR, OH. B. State Generator's ID 4 344-.4. 419 ) ':;">'::'! 5. Transporter I Company Name 6. US EPA I0 Number C-St-7e'.reitsSorer'e. .RESEARCH OIL COMPANY CHDO04178612. O. .h...1 -.--83S3.7. Transpode-,2 Company Name 8. US EPA ID Number ,S-eii.- T' ." -rte. -0 F Zrasporter'a Phone n." S. Designated Facility Name and Site Address to. US EPA ID Number G.State Facility's 10 RESEARCH OIL CO.265'5 TRANSPORT RD. :_.CLEVELAND H. Facility's Phone -OH I OH;O(94178612 ..... .(216)623-8383
- 11. US DOT Description
((nctudinr, Proper Shrpp(ng Name, Hiazard Cfass, anr 10 Number) 12. Containers
- 13. Unit HM No, Type Total Ouantity WtJVoI Waste No.a. --7te Flaimrable Liqu.rid.
nr.r. rt.ocr.ain' t.so1 me)(101 TT _20 d, J, ddilo Decritfo~ioMaerilsEistd 2ove.- -.N artdlng Coe tar Wastes Listed Above .....S USn E ,REsPORTED TTE OA R1-8O0-ON-9 EC252 ERG#27 ?. E-,. ~ j~.JIhE OUT./,~t5. Speciat Handling instructions end Additional Information F-04 VERBAfL FiELi II5 3L.(ItES &. 60636L.F.S. pl-trrpw ti-nl. .6ic" c.1 hrse centac:t Steve: Chirnc' V l-'4 ALL SPILLS MUST BE REPORTED TO THE NATIONAL RESPONSE CENTER AT (800) 424-8802, m4 HOURS PER DAY. \2 .)/A/16. GENERATOR'S CERTIFICATION: I hereby declare that the contents of this consignment are fully and accurately described above by proper shipping name and are classilied, packed, marted, and labeled, end are in all respects in proper condition torlransport by highway according to applicable internationat and national government regulations. If I am a targe quantity generator. I certify that I have a program in place to reduce the volume and toxicity (t waste generated to the degree t have determined to be economically practicable and that I have selected the praclicable method of treatment, storage, or disposal currently available to me which minimizes the present arid future threat to human health end the environment; OR, if 1 am a small quantity generator. I have made a good faith effort to minimize my waste generation and sel-ct the best waste management method that Is available to me and that I can afford.PrintedfTyped Name iMonth Day teat 17. Transorter 1 Ackonwtedgement or Receipt of Materials --Date peSin Month Day Yea, , 4 /1X ).. ., I I 4/v o T8. YraislýD Ac"no~iMlgement or Receipt o Materials ' Date T PrintedrTyped Name Signature Month Day tear IS 5 19. Discrepancy Indication Space A 20. FaCtbly Owner or Operator: Certification ot receipt or hazardous rmaterals covered by this manifest except as noted in Item 19.T "Date Prinredftyped Name Signaltue Month Day Year EPA Form 8700.22 (Rev. 9.88) Previous editions ate obsolete. GENERATOR'S COPY RAOG 94-09 Attachment 4 JONES & HENRY LABORATORIES, INC. / 2567 TRACY ROAD, NORTHWOOD, OHIO 43619/(419) 666-0411 February 1, 1994 Toledo Edison Davis B1sse Nuclear Pwr. Sta.300 Madison Ave- MS 3360 Toledo, Ohio 43652 ATTN: Mr. Steve Chimo
Dear:
Mr- Chimo: Below are the results of analysis of 3 samples received for examination on January 28, 1994: Sample I.D. AC16141 Location code: TEDDBM Project account code: 285 Location
Description:
North interceptor Sample collector: RR Sample collection date: 01/28/94 Lab submittal date: 01/28/94 Time: 16:32 TEST UNITS TEST DETECTION PARAMETER RESULT LIMIT----------------
0 HYDROCARBONS (gasoline) by GO mg/L -5 (trace) -Multicomponent analysis: BTX BENZENE ug/L 210 5.0 ETHYLBENZENE ug/L 89 5.0 TOLUENE ug/L 550 5.0 o--XYLENE ug/L 130 5.0 rn+p-XYLENE ug/L 280 5.0 Sample ID. AC16142 Location code: TEDDBM Project account code: 285 Location
Description:
North catch basin Sample collector: RR Sample collection date: 01/28/94 Lab submittal date: 01/28/94 Tifme: 16:32 TEST UNITS TEST DETECTION PARAMETER RESULT LIMIT HYDROCARBONS (gasoline) by GC ing/L Not detected 5 Multicomponent analysis: ETX BENZENE ug/L 4.9 1.0 ETHYLBENZENE ug/L 6.0 1.0 TOLUENE ug/L 20 1_0 c-XYLENE ug/L 10 1.0 m+p-XYLENE ug/L 21 1.0 .Page: 2 February 1, 1994 Sample ID_ AC16143 Location code: TEDDBM Project account code: 285 Location
Description:
South interceptor Sample collector: RR Sample collection date: 01/28/94 Lab submittal date: 01/28/94 Time: 16:32 TEST UNITS TEST DETECTION PARAMETER RESULT LIMIT HYDROCARBONS (gasoline) by GC mg/L Not detected 5 Multicomponent analysis: BTX BENZENE ug/L Not detected 1.0 ETHYLBENZENE ug/L Not detected 1.0 TOLUENE ug/L Not detected 1.0 o-XYLENE ug/L Not detected 1.0 zn+p-XYLENE ug/L Not detected 1.0 Please advise should you have questions concerning these data.Respectfully submitted, Fred W- Doering President 1994 01 is,-37 #Ins P.03/09 ORMB IlL TECH4 RESEPtRCH TO S I7 INGESTION: M~ODERA.TELY TOXIC.. AA ol~a1 LDLO --10-30 gina. a"pixati-On Into 1=90I MAY 4COudA pxQqWT~it1i. m~ay calms* gnat-tointoutina']. disturbanoo. symptGýfll laY inoludo IN171tation, naugoa, vomiting andi diarrhea. Ma~y o~-% hafu central naXTvOUB system &ffe.~tg -92facta WaY iioclrdO Oditatl+/-Qn, BflPbori* hea~dmab, dizziness, drowu3.neahl, blux~od yVfliofl fatiguie, txnzr~ora conuligorn, loan of Oon~acionfne~s, c+/-oma, WOUPIX~toxy arroflt an4 doatb..SKIN: PRATICXLLY IfO1N-TOX140, Rabbhitz d~xua1 LDSO ->9 mi/kg. aLZICMY XXRIATIMt. 2a~eateUd Or 0:o1on~ged contact may result, ii dafattiag, 2adflana, itcliing, 3mflammzxtjon. o=ackino' and PoSgible VOCO~4ary Infafctimf. ff:gh pressuire alcim Wjcitions ara BFPRXOXB lEDICA4 MMOMCZ1ES. XAlury may not appeoa seriouna 4t fixntj Vithin a feow h~urna, tiague Will.fr-domea woqlo~n-, dLuooorod and e treine.y painful. (suo Mlotao tQ Pl3ya+/-ciaU uoction) .EYE;ILRY c" a light transient inritatio~a. INI-ALATIN: M~LY catIsa retopixatoay txact iritai~ton. nV03=61X )Udy CaUae Co~t-374 nerVOu9 "YasM B5P=tc s zimilt= to tjidoa :kiv~t*4 undoxr 0"2g~ata~.n (0** Mrigaffion aoetla) -M~AY 0 CELAG ano ~mia aVA +/-r'j-alam hoax¶t x-wt-bm. Ru&?aatad or prolo)ngod ftouat nay datlock baliaviore. lag.I SPEOIALTPXTC EFFECTS: VIY ay a dvarge ULVer and kidney nefooto baitud. on itesto wtth 1boaot nml.A rxof~tat'04 xLviýa composition lims ben ouv to bax.o Inogmran to x8 oraitoxy animale whe (giye by inhalation.' Aslo, a vArioty or nutagaziaity anosey havre b~ou ox. uitod that: bkve riblded conflict~jag resnltu.XUOba detozmiznd that thEex* ie limited evidaoxns for the caxcizo niotty of gavoline in ex~e-iaucntal AMAnIna and inLoqkUa~ta ey+/-~.oaoo for the Oax~inogeaicity of g~ao1+/-ne iaI hun~n. (IARC cleaaa--2M). TWAVfIdi Tbg ue cg.am .fy bzydocaranb fual In an. mvea. Witbout adnquata ven~tilation may xresvlt in hazardous 1eelaJ. Of combugtion pzoductoan~d inadeq~uate oxy-ge avolv 1AY1A- 1 bag d 3.eto~inuw1 tlaaz gavoline engine erxia'ttl is pouu;Wly csacixcgaj3Ac to hlumansl. (A Thia Product dontAini beUZQO.n luwozona isa Oaz'cinogenio to laboratoiy axdinala wbeno given by intubation or by inh~1ation. Thera :is an asnoajAtioXX betWeeia QOcupationAl OXpoDUrS to ben~zene and hum=ax la'Uceiia. Caraitoslania detoiminationt: 1ARC--RnmAX and, PAniaal BuffEiciOZht evidenlce of <do .cnogeuicj1ys (~MAO Clann--i); UTP--ftown cVXcinogQxL; Acute borjzeiA6 paimuning aaus-bfi central tbervouz Systle deprsagaon. Ox-4 eZPosvo attects Ltha hommtapohitic u)(stem camming blood diagordera incluibilaxf ifu pancpszi3?OW. JHntagunic an olanto~$2aiQ IJ mw~miz and noxx-MW=malAM teaft xymwtezW P-PxWdUUcTQ toricaant =lY atl dosdeS that &=a matornally taxts, based on tooto with ND -No Data NA = Not Appricable .149/Pag 2 of 8 .,VOK IB RP I1L TFC ESAC TO 2478 1834.01-18 XSt 8 #I1S P.04/09 INGES.TON: DO NIOT fllYCCM VOXXT22fl wmSAUSS OW DAMICR OF ASPIRATING LIQUID flMO .LN0$. Cet inmediate inodial Stenzt+/-Qn. XC sponcneoas omitting occurs, monitor for breathing difficulty. SKIN CONTACr;Wimova clothing immediatoly, Wash area of thoroughly wi-h 0oa0 azd water. cat rne4ical attention if irritatiou perzists. High pressurQ akin injactions axro SfZOI NZDICX. 3URQMENdIBS. Got mediate medical attention. EYE COHTACTI Flush imaediately with laarge monts of 1rater for at least i-s mitteo 1e. Eyelids ahoulqd b held nwy from the eyeball to ensure thorough rinsing- Cot me.ioal attention if irritation zucault4.INHALATIO*N: RACOVe affected parsoli £xom sourco of axpoannu-If not breathing, anflrm open aiti4 and insbitulo cardiopulmonary resuscitation. (CPR) .it breathing in &liffi AuXkuit, oxygent f Av'ai1bl,. cet immediate medical. attention. fl*QMflO2... via Mont inportant gink to "agses is theG extent of aspiration of the prodtldt nt:O the 3.tings sGinsa Ba Acute chemical pnmUmonitis can rapidly trooo its roapik-atory faiux'[ spnq~:qog~igAnd OholtSng arek presumptive evidwnpa oft usý+/-ratian. xt sgge9sted that all patioe.t suspected of bydrooatbch aspiration hare ba~s lIne chest'*--~y0 Iameiate hosrpital~xation shlould he considered for asymvipkmatio child~raz mitt an abnoXmAl chest x-ray, obt1=nd*c or byporxid patients, intentional or masdire ingest~ions, andl SPatients 'With abpozl, yhout. x.rays with clinically significant pulmonary disease.CantroiztestinAl syllptoana are usually uklur vnd pathological abangee of -the liver and kidney aei to bh un-ozn- in acute intoxications-. Dacohtazination (induced otin %5U is qontrovargial and should bh sonsidarod on the of each individual canej of aouxp& the usual precaution of an endotraoheal tube should be 0onsided p=ior to lzavao.Rydrocarbox s may incIroaoe the annsitivity of the myocax-diu to .ate!oholwinus; oleotrocardicgraphia m=ntoring my'be indicated and careful aonsidsration should be given to the selaction of bronchodilalAtors. Acute central huorous syatem signs £nd aymptoma my result from largo iugeastiona or a spiration-dued flWALLTION ?EUSEi aavoliuo ins one cC the solvants used by chemical substance ab oim, .Thofts Paientp my present .wth acute. anv/or chroniu cuntrAl nervous system zoian or zf)Lmtomes. They 1-Y Ma9 present With arrytlhmias. In c-aseUf o kin iuJAotion, ConMider prompt dCe0bridaat of the wound to iminizq n*crosid 44d tissue loss.NoD No Data" NA Not Applicable 109tPage , 8 of U8 FROM 9BP OIL TECH RESEPRCH TO I FRtIIB OL EC FESRRH O24713 1934.01I-is; 38 #10S PABS/09 EYE PROTECTION; Avoid 8Ya cozitect With~ thisa material. Wear safety gla~aaa or chm2iý'e'j goggeia. P=ovidea faciii+/-es in the work aren for irniedIately flughini the eyes.SKIN PROTE-T[ON: Avoid skin ooxibkct. Z-nadin contact in antci~atad, protective cl6thIM9, initeliMJg imp~erv'ious gloves, shotad be wozn. Wash hands if thay came in contact wi-th this, matexia1.Vous good varsan~. byg:ione. wE~n= regularly 010*4mned work Cloting-i. suv~zu anld C4aing into strQat clothing A~fter WZX) is degitab Ia. Product apilt on clo~thing' ma&y rol i daluiAyed evaporation a&cl a oubJsoquixta 91ru hatard. Wash acont12inat~d cl~oth1ing "B3atl It clothing~ in Lo be laundered by mc~ozzea olue, Wqa=,r lawxdvror of yropcw rocdr RESPIRATOR1Y PROTECTION: Xf exposure li.mits aria excadede or U~ irrita~tion in experieanced, RJOSH approved respiratory protec~tion should be worn. Vcentilatiozu and othJer f ozm Of engineer-flg oo~tro010 aze often the pref erred ihana for controAl~zg chemical ex-poaure .Anapiratpr Px-vtoction ma be needed for ni -routineor0 ema2~gnc~ny Situationz. ~O1ING POINT: 26,.670- 226.'700 C~ (80 -"0 7)SPEC!ICGCRAVITY:- 0.720ý-- 0.740 a 60 F'MEIJING POINT;*%VOLA11ILM.~ 100.000 G84347 9 VAPOR PRESSURE.' 760-000 MHa RG 0o 10 E~VAPORATION4 RATE (WATErt-1): >-l vAPO6I ub-mirr (AIR~i); 1.200 AS V?.OR OCTANOLIWA.TER PARTITION COEFFICIENT: ND POUR POINT; ~pH: APPEARANCEIODOR: CLEZHR LXPIDti W=~ 2L =sT1o~ upmO.YmO1 ODOR..I FLASH POINT! -37.000 C (-35 1 ) TOO AUT01GNMON TE.MPERAThRM: 444.000 a (8SS J?)FLAMMASHLITLIMITS IN AIR (%BY VOL) LOWER: 1.400 PLAA4MABIUT UMITS IN AIR (11 BY VOL.) UPPEFI! 7.600 13ASIC FIREFIGHTING PROCEDURES; Vise d)7y chaicml.i alcohol foa'm, all Puxpapa AmF or car'bon dioxida o nuali.Wa~ter vmy be ineffecti~ve 1at atkould be used to coal fire-ex~oLed cdontainars, arftulva~Mdc to prtect personznal. Xf La~k or $pill hA0 n~ot igni~ted, v'ozrilsat area and Use Watea't Bprw. to disee qe.5 or vapor and to protzeat poruonnel attempting to otop a leak4. U00 water t 4il. d3uzt npi~u# And( to 1¶ush thoa amWs frion aouxi-ee of jignitiont. Do bot fluxlxbcoiQ public newarx or ocher 4r2ainage ayotomg. gxgoge4 firefight~ers muot wea~r XiSHA(NO0 approva~d pooitiva pragaure volt -aont~jined breathingq appaxatiie wi~th ful~l face Mawk az~d full protect~ive o;lothJlng. I1W No Dat 1049/Page 4 of 8 NA Not A&Vpcmble FRO14 -BP 0 1 L_ TECH RESEPRCH TO I 2478 1994,01-M s: +/-:39 810S P,0'e UNUSUAL FIRE AND EXPLOSION HAZARDS: Dangorous whoa axpoui~d to boat or Clam. VapOrC -form fla~mable or oxplonivO mixturas with air at: room teanperatUrs-Vapor or gas may spread to distant igsnition aourciQ and flaflh back. may concentrzate in aouf.ine areas. Runloff to 0ewer etay cause or exploaion hbazad. Contatiders may explode in heat of firs. Zrritatingr or toxcio oubstanaes may be emitted upon thermal decomposition. STAB Stabla under normal .oonditiona of use. Avoid oontaot withb strong oxi<dizrs. HAZARDOUS REACTIONOMDEOOMPOSrnON PRODUCTS: cCinbuaeion may produca co, coZ and reaciva hydrocarbons. SPILL OR RELEASE TO THE ENVIRONMENT: If your facility or operation ban an wOOl or Hazardous Substance Continigeny Plan", a;timar its prooeuro0. T- ak inmedlets steps to atop and contain the flpll,- Cautioa be exaroisad ragardig 1ersnounal safety xpoaUzr to the spilled material.-- on b tehnical advise and a .alstance -elate4 to CdoZ1Vot C0MýTKC (80VA24-9300) an4 your lIcOl fi-e department. -- toify the National Response canter, if required. Also notify appipariata stat4s ad local =ogmlatory agtencies, the LEPO and thn G=UC. 'Contact tba local CoaIst Guard if the release is into a waterway. -EMeorgency Action: Yiap unnecessary people arw4y isolate huzard area and deny -qnt7 stay U" ; keep out de low ate"'. (Alao oea Pprwonal Protection ooctioa.) 1Isolaro for 342 mile in all .dizectiona if tank, rail car or tank truck is involvd ,in fixe.Spill or Leak Prooecfure: ShuL off ignition siourcas; no fluxes, swaliug or in hazard araa. stop leak. if you ca8n do It without risk.. Wuter spray my reduce vapuri but it may net ignition in cloase apaced .Small Spills: Takee Up with. sand or- other noncombuatibie a"sorbent material &nd place into containers for lat6r disposal. Larga Bpills: Dike-far ahoAd of ,liquid spillifor lator disponal.Notificatlon: Clean Water Act ((il u+/- p1s) a Any apill or ro1easa, or nubstnarjl. threat of releaso, of this material to navigable water (virtually any anfxr*ice wtoer) suutti£aut to cause a visibla sheen upon hha water must be r6e5rted I=ndiately to the National Response Conaer (00/424-A802), as d by U.S. Vederal Law. Failure to repo= my result in iubstantial civil and criminal panalties-Also Contact this Coast G4urd and appropriate state -nd 1oaI raeg-ulatory agoacias.CERCLA/SAKR1 (Cem;ýcAl spills);ThO reortalg quuntity for tDin mateirial in 333
- pouLCd(oý.
ND = No Data NA m Not Applicable 1049/Page 5 of 8 FR~OM 28P OIL TECH RESERRCH TO 2478 ISS4,01-18 Ls*.40 I0P.70 T~iv =atsrial conlta-ins one or ynora Couthj~tUO r Xs nlt~ed zBa hazardous ou~at=,uQ ulrder U7.S- Federal1 Law- AIW wpilX2 or other tuZG1#-g*' or subatan~tia]. throat of reiea.86i of this cmatorial to the air, water or 1ancd (lUnlood Gflt+/-rey corutalned in the workplace) equial to 0= ixA OXOOa3 of the 770ortn3,ie quantityl n=ue be reOVttad 5inmmdiately to th. Nationala IAQuPonse Cantor (000/424-8802). Alljo coutnot Appzopriate state zand local r6M91AtO+/-%Y a17encdan. Cotacnt the Coast gUard if xpilJled ýnb navigabije w-aerWAys %nder their jUriadlction. Failur~e to ropoxt may raault in qub ttiazii 4&vlvi and cr1 zzal Penalties-. Calcu-Iat*4 On th* bagis tor Whicheymq hazardoua compmonaft pro~v'dQa theL 10WA'et Value for.-RQ I %~ 13 MiiXtUX WASTE DISPOSAL:* higi Substance, Whol djiscarded or disposed 'ef im not szpacifiqa2.ly Uat04 ada hagad w-.ata in yedex-Al rou~i" hLOWaver it could b6 hroer o .hazardous If it: it,*Connid~ted tojo.ic coXsXVgoV, ignitabl.e, or zoati e~cordixng to Fds"I dafinJ+/-3-ona (40 CPR 261). AdditionaAly, it could be danignata&- a~n hnaXdot accoordinsV to stato reguleaiona. ~Th2is subitanco could aloo badcma a hazazdouo waoto if It La mixed with or cmnin contact -with a bkzwxdoua vast&. Mubck 40 COR 261 to dstermina whethie= It is 2%hazardous Waste. it it lo a. hagax.2ous waste, reqnlatiorts at 40 CPR 262, 26ý 26~A, 260, and*270 Apply. c~homical MaddIhIons, proceagingi or otjherWiseQ aMterlaag th~is iiatarpnL =*ay =mks.thO waste genaqo=fl. inforiation pressented in this RSpDS incomplete', inAcouxlt* or /otberw=4 ipr2rao.a The trazportation 4.istoraga, tieatneont, and dis~aal of this MAWt(d Mat8La1 MIugu be conucted. in aomp:liaiica with all app~licable Federal, utate, and local regul~iato2a. SARA 7lME 1U INFOF(MATION; Li-sted baloiw a+/-'e tlia bzazd catagorian for~ the ejxperftund IAmendmant'* Ax4 F"Vkthorizat461 Act (SMM)J Section 317,1312 (40 CFR 270J)r fmmedlate Hazrd: X -betsye4 Hard:L X Fim Kszrd: X Pressuire H~ard- AeaQcvtty Iaznrd: -~nQ Product coutaina the folljowing toxic chmnio& (s) ouxbject: to theQ ra~porting requirOZ-2nts of the Svparrutid Anandmcuts and RtauthOrizatiou Mit (SXAF)Saat5.on 313 (40 CFR 372): TeueO AS mtniberz .MWxlinw */%Coluipelal 108-~8". .12-000 Xylons 1380-20-7 V2.000 Beflzene 71-43-2 3.000 1,PZ4z-Thmhytlenzene 95M- 3.000 Fhibemnzre 10-142.000 Cyclohexans 110-82-7 1.000'ADDIMOcNAL ENVIRONMENTAL REGULATORY INFORMATION. Ohis 75AteXial cotains4i o uhbtancia listed an a hazarcdoit" 4ir pollutazt aundWr U.S. Podueral regulut~oSe e 40 cFRn part 6:i for! rastrictionn whicah mAy apply to its Unse.*Thiff mata"J. cuntaiua a 21xtu~ra of cabJtances, fffae -0f whiAch ~*an aisted an toxic Pcl11at~at0 pursuvr~t to 40 CF =~2.21, Apedidix D, Tsil-a~n XX/Zfl/V. A.ny tmusa).introductiokl of th$.x o'ihntanae 3zto tho fagilitY'a procefisS tbAW5A, StorMW'tvetr and/97Z v~t4%wAt&' dotld result ia tho voabion of 17*S. Fadaral. LAW. Fdllitias kniult XxOtify the2 Cr=IPA -3 soon. Ac thwo knowr, or hvay rse~sou to believe, that a.n3Y activity has ocourred. or will occur, wqbicb would rnsu.j~t in'the diacharge of a toxic pollu~tant which La hiot ro!Qlated in the facility-'s IPOM3 permit. iHotigication l.avela are dosribod in 40 CP~R 122.42 (a) Ui) and 122.42 (aH) (). Refer to spill. vection for additional raug toxsy reuironants. ND No Data 1049fPage 6 of NA -Not Applicable FrIOM ssnp OIL TECH RESEPJW" TO 2478 i34,081-18 IS41 010,S P.08/09 Thera Way ba specific regul1tiona at the local, rogionAl or 9tate level that pertain to this bintorivl.. This Product contaiks ingroadant (s) known to the State of CaJliforni4 to caUDO cancer, birth or other reproductiyo harm.continn Uanzenos .' Cosult Os0l Standard 1510.1028-Initial air initring should be conducted to datozmdne if exposures above 0.A ppm action mhit: or 1 pmn PHL. If'poattres are above, OSUA recquire1aenta apply for trainjtw, medical peiszonul/protect-ive equipment, regulatead areas, eta -The following Canadian Workplace Hazar4oun Materials Xnfonamtion System (JWnIS) aatagories app~ly to this k~rodaeti Compressed On5 -ai-nmable/Combu.tible x Oxidizer -Acutely Toxic -Othler Toxic Effects x BlofaHrduos -Corrosive -Dangerously Reactive Store gasolina only in approved, alaarly labeled containern. ayar sztore in glass or unapprovgd plastzc sltrihtihtl .loadcontainersj in cool, dry, isola~ted, woil-venti1;%ta4 aroa awvay =,or hfoat, sources o0 ig9itioln a.zd incantatiblas. Garund lines and oecdixmaint u.sd duriig Stranfe= to re21zg nho possibility of statica spa.rk-initiatd fi5 or eaplosion. U"t g004 PdlSO41 bW+/-iOU6 tz.actices. Wash hands ýbefare eati35gr drinking, Smoio~ng, or using facilities..
- amoyo contaminatud clothiug and clean bafore6 reute. shower"lter work usixag and water. Do not ciphon this product by mouth. U6e only as a lvOtor fuel.- Do not use for cleanixg, prossure appliance riel, or" other use. Do not store, in, zuxablled containers.
Seep out of reach-of children.* EMPTY CONTAINERS; Empty cotki s MVa oo1otatin toxic, floawzle/ombustible or eoxplnivo re4idme o"r vapors.DO .cut, grind, drill, wald,. 2:Iue or dt'spcnte containors unless adequate procautions rar tnkatn against those hazardn." D,O.T. PROPER SHIPPING NAME (49 CFR 172.101): D.O.T. HAZARD CLASS (49 CFR 172.101): UN/NA CODE (49 CFI1 172.101)!PACKING GROUP (411 O`13 172.101): BILL OF LADING DESCRIPT1ON (4.9 CFR 172.202): D.O.T. LABELSFIQUIRED.(49 CFR 172.101): D,O,.T PLACARDS REQUIRED (49 CFR 172L504).I G"Arl0E;XI, 3, UNI.203, PG XV 3 ON 12033,r MNL 1203, Wo IS LAM L LIGQUID FLMARLPý t'IQtID ND = No Data'NA Not Applicable 1049/Paog 7 o08 FROI 13P 0 1 L TVCH RESEPRCH POI d- EfcH TO 9 2478 1994.01-113 15:42 files P.09/09.CO-.-POnrW1 I 1O. I% I EXPOSURE buxMTTS -REF.Ga'soline gQ~g61-9 99.99-100 300 pprn (ago lngr/MA) =V; 500 PX=200 ppuk (900 ing'fl3) My 500 'PP (1,500 fZ/'nA STDZL losf&)Tolixwan 108-80-3 3.0-12 100 PP= (977 xw1W~) MV1. 150 PPM (55t00 /M 8MM ((ACGM&))~i IO p 100 pm~ (375 -gfR3) I10 -50~ PP (960 pplmi. (560 40s"A ) L(c 1330 1.01 -1.00 ppan (4375 mingi[) T1i-j15 pMY (651 mg/Zx3)1 STL (os!=)l00 prM (435 =rC/1431 PEL: x~0 Bezel ~71-43-2 0-3 10 pm (32 ,aQjJ13) Thy (ACGZIH)*I ppm PEL, 5 ppm STRt COSBA.)+/-,2,-T~y:Lbuzo~a95-63-6 0-3 25 ppm (1.23 Za4/M3) TLV (A.COM~2S pra (125 xa" ) (OS=100-41--4 0-2 .100 ppm (424 2zq/1=) WVAV,. X1 25 ppm 109 ppM (4&5 Mgqi2t2) I>,q 125 PPf4 (545 mgf3M1) 'STEL (0awi)c~yt1ohezimx=*0~- 0-:L 300 ppm (1,030 &ngf*L3 TLV (Ac=~)300 ppm (1,050 mg/Ur$) PEL (05HAL)hazardouu compoenats Proe=at lagsz t1~ii 1.0% (0.1%~ fox ,REVISION DATE! I7-apr-1992 REPLACES SHEET DATED: 21-jan-1991 COMPL-ETED BY: BP O1tL HSEQ DEPARTMENT"paep&on of ft¶ Mate~vi 6SIt Uaia sheetL 1owavr. noumfa o~nntr to enmmion,'exproas or bpip~ed. is rnsdaa to i th acwmay or camplaunMs of 010 fgwugclin data and safeti' Inbrnna6on\ not is any autwoizatin given ortffipt~ed W to pucv ay pwxf~tpd Iiwentlonwfi utal1aO, In ft&~on.no ro~ponsibflity can be assumed~ by vencbc for any datvg ot k~jur ras~ddnq fromi 6ýxrrnsd use, from any blutum to adkhare to recommentivd pm~4c-dm, or from any h~azartds MeInt in itra come of Wli pmduaL ND -No Data NA -Not Applicable 1049/Page 8 of 8 0 "S Page 1 of 6 Davis-Besse Nuclear Power Station PERIODIC TEST PROCEDURE DB-CN-04032 WASTEWATER TREATMENT SLUDGE HOLDING TANK ANALYSIS REVISION 01 Prepared by: Richard Edwards Procedure Owner: Effective Date: Supervisor -Nuclear Chemistry Services OCT 2 8 2OO4 Procedure Classification: Safety Related X Quality Related Non-Quality Related LEVEL OF USE: STEP-BY-STEP 2 DB-CN-04032 Revision 01 WASTEWATER TREATMENT SLUDGE HOLDING TANK ANALYSIS TABLE OF CONTENTS Page 1.0 PURPOSE AN D.. .......... ................................................................................................... 3 2.0 LIMP ITS AND PRECAUTIONS .......................................................................... ................ 3 3.0 PR E R E Q U ISITE S ........................................................................................................................ 3 4.0 PROCEDURE ............................................................................................ 4 5.0 A CCEPTAN CE CRITERIA ...................................................................................................... 6 6.0 R E FE R E N C E S ............................................................................................................................. 6 7.0 RE C O R D S .................................................................................................................................... 6 3 DB-CN-04032 Revision 01 1.0 PURPOSE 1.1 This procedure provides for the monitoring of sanitary wastewater sludge for the presence of radionuclides.
2.0 LIM1TS
AND PRECAUTIONS 2.1 None 3.0 PREREQUISITES INITIALS 3.1 Collect as a minimum a 1 (one) liter representative sample from the each sludge holding tank to be pumped.3.2 Record collection time and date.Time Date 3.3 Record holding tank number.Prerequisites completed by Date Prerequisites completed by Date 4 DB-CN-04032 Revision 01 NOTE 4.0 Section 4.0 is performed for each sludge holding tank to be pumped.4.0 PROCEDURE INITIALS 4.1 Label a 1 liter liquid marinelli with volume marks in 100 cc increments.
4.2 Weigh
the marinelli. Balance LI No.Check Due Date Tare Weight g.4.3 Obtain the sludge holding tank sample for analysis by: a. Shaking the sludge sample and filling the marinelli with sample to the 1000 cc mark.4.4 Weigh the filled marinelli. Balance Li No.Calibration Check Due Date Gross Weight g.Net Weight g.4.5 Analyze the sample for radionuclides in accordance with DB-HP-01 113 Countroom Analysis System (CAS) Operation, using the following:
- Volume of 1000 cc* Sample Time at time of counting 0 Minimum count time of 8000 seconds 0 Obtain a MDA (Minimum Detectable Activity) report.
5 DB-CN-04032 Revision 01 NOTE 4.6% sludge = cc sludge x 100 1000cc 4.6 Record the % sludge volume after analyzing the sample on the gamma spec printout and below.4.7 Attach a copy of the analysis with MDA report to this completed procedure.
4.8 Forward
this test to a Radiation Protection Supervisor for review and approval for release.4.9 IF the sludge can be released, THEN obtain Radiation Protection Supervisor's approval.Date Supervisor-Radiation Protection 4.10 IF the sludge is not approved for release, THEN notify Nuclear Chemistry Services personnel immediately. 4.11 Submit a copy of gamma spec analysis and MDA report to Nuclear Chemistry Services personnel. Section 4.0 completed by Date 6 DB-CN-04032 Revision 01 5.0 ACCEPTANCE CRITERIA 5.1 The analysis of the holding tank(s) content has been completed. Verified by Date
6.0 REFERENCES
6.1 Developmental
6.1.1 Nuclear
Regulatory Agency IE Notice 88-22, Disposal of Sludge from Onsite Sewage Treatment Facilities at Nuclear Power Stations.6.2 Implementation 6.2.1 DB-HP-01 113, Countroom Analysis System (CAS) Operation.
7.0 RECORDS
7.1 Following the requirements of NOP-WM-2003, Work Management Surveillance Process, for records capture and processing. x ADMINISTRATIVE PROCEDURE TITLE SHEET ED 7171-2 I TITLE NO. DB-CN-00030 National Pollutant Discharge REVISION Elimination System (NPDES) 00 S Program PAGE cI I OF 19 EFFECTIVE DATE 1,, JUN 2 12004 E C L ESUPERSEDES EXCELLENCE QUALITY TEAMWORK DB -CH-O0030 Rev 0 1 Prepared by: Stephen Chimo Procedure Owner: Manag Procedure Classification: Safety Related X Quality Related Non-Quality Related er -Environmental and Chemistry LEVEL OF USE: GENERAL REFERENCE REVISION LOG Revision Number Revision Summary Rev 00 Incorporated the contents of DB-CH-00030. National Pollutant Discharge Elimination System (NPDES) and ECG-10, National Pollutant Discharge Elimination System (NPDES) Permit Requirements, into DB-CN-00030 under new ownership. ED 7575A DAVIS-BESSE ADMINISTRATIVE PROCEDURE PAGE REVISION PROCEDURE NUMBER.National Pollutant Discharge Elimination System 3 00 DB-CN-00030 (NPDES) Program TABLE OF CONTENTS Page 1.0 P U R P O S E .................................................................................................................................... 4 2.0 APPLICABILITY/SCOPE ..................................................................................................... 4
3.0 REFERENCES
............................................................................................................................. 4 4.0 DEFINITIONS ............................................................................................................................. 5 5.0 RESPONSIBILITIES .......................................................................................................... 7 6.0 PROCEDURE .............................................................................................................................. 8 6.1 General Information ................................................................................................... 8 6.2 Conduct of the Program ............................................................................................... 8 6.3 Periodic Reports ................................................................................................ .............. 9 6.4 Change in Discharge ....................................................................................................... 11 0 6.5 Diversion or Bypass of Facilities ................................................................................. 12 6.6 Approval to Use Non-Contact Cooling W ater Additives ........................................... 13 6.7 S pill R esponse ................................................................................................................. 13 6.8 Non-Compliance Notification and Reporting Requirements ....................................... 14 6.9 Perm it R enew al ............................................................................................................... 15 7.0 RE C O R D S .................................................................................................................................... 15 ATTIACHMENT 1: OBSERVABLE NPDES PARAMETERS AND SAMPLING FREQUENCIES .............................................................................................. 16 ATTACHMENT 2: EXAMPLES OF NPDES REPORTABLE EVENTS .................................... 17 ATTACHMENT 3: OHIO EPA NPDES DATA CODES ............................................................. 18 ATTACHM ENT 4: NPDES SPILL RESPONSE FLOW CHART ................................................ 19 ED 7575A DAVIS-BESSE ADMINISTRATIVE PROCEDURE PAGE REVISION PROCEDURE NUMBER National Pollutant Discharge Elimination System 4 00 DB-CN-00030 (NPDES) Program 1.0 PURPOSE This procedure establishes the requirements, responsibilities, and processes for the administration of the Ohio Environmental Protection Agency (Ohio EPA) National Pollutant Discharge Elimination System (NPDES) Permit, No. 21B0001 1, for the Davis-Besse Nuclear Power Station (DBNPS), and implements the requirements of NG-DB-00501, Environmental Compliance Program, for NPDES activities. 2.0 APPLICABILITY/SCOPE This procedure applies to those Environmental and Chemistry personnel responsible for NPDES activities.
3.0 REFERENCES
3.1 Developmental
3.1.1 Clean
Water Act of 1987 3.1.2 40CFR 121-125 3.1.3 Ohio EPA OAC 3745-33-01 through OAC 3745-33-10, Ohio NPDES Permits 3.1.4 Ohio Environmental Protection Agency, National Pollutant Discharge Elimination System Permit No. 21B0001 1, for the Davis-Besse Nuclear Power Station 3.2 Implementation 3.2.1 NG-DB-00501, Environmental Compliance Program 3.2.2 NG-RA-00807, Regulatory Reports 3.2.3 NG-NS-00808, Regulatory Agency Communications 3.2.4 NOP-NL-2001, Condition Report Process 3.2.5 DB-CH-04028, NPDES Program 3.2.6 RA-EP-02850, Hazardous Chemical and Oil Spills 3.2.7 Environmental Compliance Guideline (ECG -05), Spill Prevention Control and Countermeasure (SPCC) Plan 3.2.8 ECG-04, SARA/CERCLA Hazardous Chemical Locations and Spill Event Notification Requirements. 3.2.9 ECG-09, Storm Water Pollution Prevention Plan.0 ED 7575A DAVIS-BESSE ADMINISTRATIVE PROCEDURE PAGE REVISION PROCEDURE NUMBER.National Pollutant Discharge Elimination System 5 00 DB-CN-00030 (NPDES) Program 4.0 DEFINITIONS
4.1 BIOCHEMICAL
OXYGEN DEMAND (BOD) -The amount of oxygen used by micro-organisms to metabolize the organics in wastewater.
4.2 BYPASS
-The intentional diversion of waste streams from any portion of the treatment system.4.3 DAILY -As used in this procedure, refers to workdays of Monday through Friday, excluding holidays.4.4 DISSOLVED OXYGEN -The amount of oxygen in the water, varying by the physical, chemical, and biochemical activities in the water body.4.5 HYDRAZINE -A colorless, fuming corrosive strongly reducing liquid which scavenges oxygen for corrosion control.4.6 NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) -A federal program administered by the Ohio Environmental Protection Agency that provides for the permitted discharge of pollutants to state or federal waterways.
4.7 NONCOMPLIANCE
-A failure to satisfy permit requirements regarding concentration limitation, designated sampling frequencies, or report submittal. 4.8 OIL AND GREASE (0 & G) -Any material recovered from the sample as a substance soluble in trichlorotrifluoroethane. ED 7575A DAVIS-BESSE ADMINISTRATIVE PROCEDURE PAGE REVISION PROCEDURE NUMBER National Pollutant Discharge Elimination System 6 00 DB-CN-00030 (NPDES) Program NOTE 4.9 Conditions may dictate that Station drains be routed through the settling basins (Outfall 602).4.9 OUTFALL -The location where an effluent is discharged into receiving waters. The permitted outfalls for DBNPS are as follows: Designation Description 001 BEACH STATION: At point representative of discharge to Lake Erie.SOURCE OF WASTES: Low volume wastes (Outfall 602), Wastewater Treatment (Outfall 601), circulation system blowdown, turbine building sumps and occasional service water.002 AREA RUNOFF: Discharge to Toussaint River.SOURCE OF WASTES: Stormwater runoff, turbine building drains, boiler drains, and circulating pump house sumps.003 SCREENWASH CATCH BASIN: Discharge to Navarre Marsh.SOURCE OF WASTES: Wash debris from water intake screens.004 COOLING TOWER BASIN POND: Discharge to State Route 2 Ditch.SOURCE OF WASTES: Drainage of Cooling Tower Basin.588 SEWAGE TREATMENT PLANT Sewage Treatment Plant Sludge shipped offsite for processing. 601 SEWAGE TREATMENT PLANT POND: Discharge from wastewater treatment system pond.SOURCE OF WASTES: Site sanitary system.602 LOW VOLUME WASTES: Discharge of settling basins.SOURCE OF WASTES: Water treatment residues, condensate polishing resins, condensate pit sumps.801 INTAKE TEMPERATURE: Intake water prior to cooling operation. Permit limitations, outfall parameters, and sampling frequencies are delineated on Attachment 1.4.10 pH -The negative logarithm of the hydrogen ion concentration used to express acidity and alkalinity on a scale of 0-14. 4.11 PROCESS WASTEWATER -Any water which, during manufacturing or processing, comes into direct contact with or results from the production or use of any raw material, intermediate product, finished product, by-product, or waste product.4.12 TOTAL RESIDUAL CHLORINE -Combination of free chlorine and combined chlorine. Free chlorine consists of aqueous molecular chlorine, hypochlorous acid, and hypochlorite ion. Free chlorine reacts readily with ammonia and certain nitrogenous compounds to form combined chlorine.4.13 TOTAL NONFILTERABLE RESIDUE (TNFL) -Method, described in "Standard Methods for the Examination of Water and Wastewater", of filtering a sample through a glass fiber filter and weighing the dried residue retained on the filter [also known as Total Suspended Solids (TSS)].4.14 TOTAL RESIDUAL OXIDANTS -Combination of Total Residual Chlorine and residual bromine compounds. 4.15 UNAUTHORIZED DISCHARGE -The release of unpermitted pollutants, including bypassing whether deliberate or accidental. 4.16 UPSET -An exceptional incident that results in unintentional and temporary noncompliance due to factors beyond reasonable operator control. This excludes operator error, improper design, lack of maintenance or careless or improper operation.
5.0 RESPONSIBILITIES
5.1 The Manager -Environmental and Chemistry shall 5.1.1 Provide overall administration of this procedure. 5.1.2 Make required onsite and offsite notifications.
5.1.3 Provide
technical assistance during NPDES permit unauthorized discharges and noncompliance events.5.1.4 Ensure submittal of any required regulatory reports.5.2 The Project Leader or designee shall be responsible for the implementation of this procedure.
5.3 Other
actions for the discharge of pollutants through NPDES outfalls as required by RA-EP-02850 may occur concurrently with implementation of this guideline. These actions may include: 5.3.1 The Shift Manager or designee may make required onsite notifications and determine if a spill or discharge has occurred which requires implementation of HAZWOPER.5.3.2 The Supervisor -Nuclear Chemistry Services in conjunction with the Supervisor -Safety may prescribe personnel protective equipment and practices during an emergency response. ED 7575A DAVIS-BESSE ADMINISTRATIVE PROCEDURE PAGE REVISION PROCEDURE NUMBER National Pollutant Discharge Elimination System 8 00 DB-CN-00030 (NPDES) Program 5.3.3 The Superintendent -Maintenance may isolate site discharge pathways and provide cleanup of spilled materials.
6.0 PROCEDURE
6.1 General Information
6.1.1 Under
the Clean Water Act, it is not permissible to discharge any pollutant to a state or federal waterway.6.1.2 In obtaining a NPDES permit, DBNPS is now allowed to discharge those industrial process wastewater pollutants specified by the permit (see Attachment 1, Observable NPDES Parameters and Sampling Frequencies). Those pollutants may only be discharged to the outfalls designated in the permit and discharge pathway may not be changed/diverted from the designated pathway unless first approved by the Director of the Ohio EPA.6.1.3 The following conditions constitute a violation of the NPDES permit and are reportable to the Ohio EPA: a. Any discharge of pollutants in excess of the limits specified in the permit (noncompliance).
- b. Any discharge of unpermitted pollutants (not specified in the permit) above the analytical detection limit (unauthorized discharge).
- c. Any flow changes/diversions that exceed permit limits and/or cause the discharge of any unpermitted pollutants (bypass).6.1.4 Examples of possible situations which are reportable are included as Attachment 2, Examples of NPDES Reportable Events. These are only examples and should not be considered an all inclusive list.6.2 Conduct of the Program 6.2.1 The NPDES Monitoring Program consists of: a. Taking measurements and representative samples of liquids as required by the permit.b. Analyzing these samples and evaluating measurements in accordance with station procedures.
- d. Reporting results to the Ohio EPA as discussed in this procedure.
ED 7575A DAVIS-BESSE ADMINISTRATIVE PROCEDURE PAGE REVISION PROCEDURE NUMBER National Pollutant Discharge Elimination System 9 00 DB-CN-00030 (NPDES) Program 6.3 Periodic Reports 6.3.1 General Requirements
- a. Data for Outfall 001, 002, 003, 004, 601, and 602 shall be provided to Environmental on a weekly basis as follows: 1. Chemistry Section performs DB-CH-04028, NPDES Program, weekly.2. A copy of the completed DB-CH-04028 is submitted by Chemistry for preparation of the monthly report.b. Samples or values for data analysis shall be collected from the following locations:
- 1. Outfall 001 samples shall be collected at the DBNPS beach sampling station.2. Outfall 002 samples shall be collected at the discharge of the Training Center pond.3. Outfall 003 samples shall be collected at the overflow of the screenwash catch basin, north of the settling basins.4. Outfall 004 samples shall be collected at the discharge of the Cooling Tower Pond, as applicable.
- 5. Outfall 588 samples shall be collected from the applicable operating Sewage Treatment Plant Sludge Holding Tank(s).6. Outfall 601 samples shall be collected at the overflow of the wastewater treatment basin.7. Outfall 602 samples shall be collected at the overflow of the North Settling basin.8. Outfall 801 water temperature values shall be obtained from a computer point located in the forebay.6.3.2 Data Collection
- a. Nuclear Chemistry Services may use the following forms to collect data and to transmit the finalized report to distribution:
- 1. NPDES Weekly Data Acquisition Form 2. NPDES Monthly Report Form (EPA-4500)
ED 7575A DAVIS-BESSE ADMINISTRATIVE PROCEDURE PAGE REVISION PROCEDURE NUMBER National Pollutant Discharge Elimination System 10 00 DB-CN-00030 (NPDES) Program b. If data values are unavailable or an analysis was not performed: NOTE 6.3.2.b. 1 The use of Ohio EPA NPDES data codes in lieu of data values should be avoided whenever possible, especially regarding the use of the "AH" code for outfall 001.I. Document the discrepancy appropriately using codes shown in Attachment 3, Ohio EPA NPDES Data Codes.2. Report the discrepancy as soon as practicable to the Project Leader.6.3.3 Determination of Flows and Water Temperatures for Outfall 001 NOTE 6.3.3.a Converting from thousand gallons per minute (KGM) to million gallons per day (MGD) can be accomplished by multiplying by 1440 then dividing by 1000.Example: 18.6645 KGM X 1440 + 1000 = 26.8769 MGD;to 3 significant figures = 26.9 MGD.a. Obtain value from computer program for point F201, Collection Box Flow.1. Convert KGM value to MGD Flow.2. Shorten value, if necessary, to three significant figures.b. Obtain value from computer program for point T190, Discharge Temperature.
- 1. Shorten value, if necessary, to three significant figures.c. Repeat 6.3.3.b for point T413.6.3.4 Determination of Flows for Outfall 002 a. Obtain the daily rainfall data for the reporting month from the Meteorology Project Leader and identify those days upon which precipitation was recorded.b. Enter data into computer program for flow calculations.
ED 7575A DAVIS-BESSE ADMINISTRATIVE PROCEDURE PAGE REVISION PROCEDURE NUMBER National Pollutant Discharge Elimination System I1 00 DB-CN-00030 (NPDES) Program 6.3.5 Determination of Flows for Outfall 003 a. The daily flow for Outfall 003 is constant at 0.222 MGD.6.3.6 Determination of Flows for Outfall 601 a. Obtain timer reading values from the Wastewater Treatment Plant Inspection forms (maintained by Nuclear Chemistry Services).
- b. Enter timer reading values into computer program for flow calculations.
6.3.7 Determination
of Flows for Outfall 602 a. Obtain station sump timer reading values for timers BE3162 and BF3163.b. Enter timer values into the computer program for flow calculations. 6.3.8 Data Entry into the "EPA" Monthly Reporting Computer Program a. Enter the collected NPDES reporting data to the appropriate EPA form on the computer.b. When all data is entered and correct, and sums are tabulated:
- 1. Print each form onto the NPDES forms supplied by the EPA.2. Ensure all information is legible.NOTE 6.3.9 The completed NPDES reporting data for the month, as printed on the Ohio EPA Forms and the attached cover memorandum are combined to make the Ohio EPA NPDES Monthly Wastewater Report.6.3.9 Report Review Process a. Submit report for review according to the Report Requirements Tracking Sheet (RRTS -PS) for the monthly NPDES report.b. All correspondence relating to the implementation of the NPDES program shall be retained for a minimum of three (3) years.6.4 Change in Discharge 6.4.1 Discharges shall remain consistent with the terms and conditions of the Permit.
ED 7575A DAVIS-BESSE ADMINISTRATIVE PROCEDURE PAGE REVISION PROCEDURE NUMBER National Pollutant Discharge Elimination System 12 00 DB-CN-00030 (NPDES) Program 6.4.2 When any pollutant is discharged more frequently than, or at a level in excess of, that which is authorized, or when any pollutant not described in the permit is discharged above the analytical detection limit, that discharge shall constitute a violation of the Permit and shall be reported to the Ohio EPA.6.4.3 Before any flow paths are changed, new chemicals are used in systems, treatment devices are installed, etc., the potential need for a permit modification must be considered. A permit modification is required for: a. Any anticipated facility expansion.
- b. Production increases.
- c. Process modifications that will result in new, different, or increased discharges of pollutants.
6.4.4 Following
such notice of facility or production changes, the Permit may be modified to specify and limit any pollutants not previously limited.6.5 Diversion or Bypass of Facilities 6.5.1 No diversion from or bypass of facilities necessary to maintain compliance with terms and conditions of the Permit shall be permitted, except: a. To prevent loss of life, personal injury, or severe property damage.b. There are no feasible alternatives to the bypass, such as the use of auxiliary treatment facilities, retention of untreated waste, or maintenance during normal periods of downtime. This condition is not satisfied if adequate back up equipment should have been installed in the exercise of reasonable engineering judgment to prevent a bypass which occurred during normal periods of equipment downtime or preventative maintenance.
- c. To allow essential maintenance to be performed according to a schedule approved in writing by the Ohio EPA Northwest district Office.d. When excessive storm drainage or runoff would damage any facilities necessary for compliance with the effluent limitations and/or prohibitions of the NPDES permit.6.5.2 Diversion from or bypass of facilities shall be reported according to the event and meet the requirements of Subsection 6.8.6.5.3 Unanticipated bypasses must be reported to the Ohio EPA Emergency Response Hotline within 24 hours.6.5.4 If the need for a bypass is known in advance, prior written notification to the Ohio EPA is required at lease ten days before the date of the bypass, if possible.
ED 7575A DAVIS-BESSE ADMINISTRATIVE PROCEDURE PAGE REVISION PROCEDURE NUMBER National Pollutant Discharge Elimination System 13 00 DB-CN-00030 (NPDES) Program 6.5.5 Bypasses which do not cause effluent limitations to be exceeded are permissible if they are for essential maintenance to assure efficient operation.
6.6 Approval
to Use Non-Contact Cooling Water Additives 6.6.1 When it is requested to use different non-contact cooling water additives than those currently allowed by our permit, such as alternative amines for pH control, prior Ohio EPA approval must first be obtained.6.6.2 The following information must be supplied to the Ohio EPA in writing;a. The name of the additives(s) to be used and general product information, including a copy of each material Safety Data Sheet (MSDS).b. The concentration(s) of the additive(s) to be used, including the frequency and duration of application.
- c. The expected concentration(s) of the additive(s) contained in the discharge or blowdown immediately prior to entering state surface waters (in mgfL).d. The average flowrate (MGD) and the outfall designation of each outfall containing the additive.e. The name of the state surface water receiving the discharge.
- f. Toxicity and environmental information, such as 48-hour and 96-hour LC50 or EC50 values from acute toxicity tests.6.6.3 This information should be complied and submitted by Nuclear Chemistry Services for approval as necessary.
NOTE 6.7 A simplified flow chart for NPDES spill actions and notifications is shown on Attachment 4, NPDES Spill Response Flow Chart.6.7 Spill Response 6.7.1 The discharge of pollutants through NPDES outfalls in excess of the concentration limits specified in Attachment 1, or the discharge of pollutants not listed on Attachment 1 in excess of the analytical detection limit is a violation of our NPDES permit.6.7.2 Reporting requirements for NPDES violations are described in Subsection 6.8. ED 7575A DAVIS-BESSE ADMINISTRATIVE PROCEDURE PAGE REVISION PROCEDURE NUMBER National Pollutant Discharge Elimination System 14 00 DB-CN-00030 (NPDES) Program 6.7.3 Although NPDES discharge violations are reported under Subsection 6.8, the required clean-up requirements are the same as for land spills and air releases. These requirements are detailed in the following locations:
- a. RA-EP-02850, Hazardous Chemical and Oil Spills, describes HAZWOPER activation requirements and small spill/discharge clean-up information.
- b. ECG-04, SARA/CERLA Hazardous Chemical Locations and Spill Event Guidelines, describes how to clean up chemical spills/discharges, such as hydrazine, sodium hypochlorite, sodium hydroxide, sulfuric acid, etc.c. ECG-05, Spill Prevention Control and Countermeasure (SPCC) Plan, describes how to clean up oil and diesel fuel spills/discharges.
6.8 Non-Compliance Notification and Reporting Requirements 6.8.1 The Ohio EPA must be notified in accordance with NG-NS-00808. NOTE 6.8.2 The Ohio Emergency Response Hotline number is 1-800-282-9378. 6.8.2 The Ohio EPA must be notified by telephone of the following items within twenty-four (24) hours of discovery:
- a. Any noncompliance or unauthorized discharge events.b. Any unanticipated bypass (no prior written approval) which exceeds any effluent limitation in the permit.c. Any upset which exceeds any effluent limitation in the permit.6.8.3 The Ohio EPA must be notified within 24 hours of any violation of any maximum daily discharge limitations as listed on Attachment 1.6.8.4 Telephone notifications must be confirmed in writing within 5 days of the discharge and submitted to the Ohio EPA Northwest District Office, including the following information, unless directed to do so otherwise by the agency: a. Limitation(s) exceeded b. Extent of the exceedence
- c. Cause of the exceedence
- d. Period of the exceedence ED 7575A DAVIS-BESSE ADMINISTRATIVE PROCEDURE PAGE REVISION PROCEDURE NUMBER National Pollutant Discharge Elimination System 15 00 DB-CN-00030 (NPDES) Program e. If uncorrected, the anticipated time to which the exceedence is expected to continue f. Steps to be taken to reduce, eliminate and/or prevent recurrence of the exceedence.
6.8.5 Instances
of noncompliance not detailed above are to be submitted with the monthly NPDES reports in accordance with Subsection 6.3, Periodic Reports.6.9 Permit Renewal The Manager -Environmental and Chemistry or designee shall ensure that the application for the renewal of the current version of DBNPS NPDES Permit No. 21B0001 1 is submitted at least six months prior to the expiration date.7T0 RECORDS 7.1 The following quality assurance records are completed by this procedure and shall be listed on the Nuclear Records List, captured, and submitted to Nuclear Records Management in accordance with NG-NA-00106:
7.1.1 NPDES
Permit 7.1.2 NPDES Permit Application 7.1.3 Ohio EPA NPDES Monthly Wastewater Report 7.1.4 Non-Periodic Reports, if generated 7.2 The following non-quality assurance records are completed by this procedure and maintained by the Environmental Unit: 7.2.1 NPDES Weekly Data Acquisition Checklist 7.2.2 Regulatory Reports -Review and Approval Report 7.2.3 NPDES Monthly Review Cover Memorandum ED 7575A DAVIS-BESSE ADMINISTRATIVE PROCEDURE PAGE REVISION PROCEDURE NUMBER National Pollutant Discharge Elimination System 16 00 DB-CN-00030 (NPDES) Program A* T- A C'-IP NIT I.fl1~I~PVAT~T 1~ NIPThI~ PAl AMT~T1~D'~ AIJTh ~AMPT ThJ( FRFO1TFNCW'~ Page 1 of 1 SITE PARAMETER TESTED OBSERVABLE PARAMETER FREQUENCY FOR 30 DAY AVG. MAX DAILY 001 Total Chlorine/ Oxidants NA 0.02 mgfL/0.05 mg/L Daily/Grab See Note 1 pH NA >6.5 & <9.0 Daily Grab Dissolved Oxygen NA 6.0 mg/L (Min) 2/Month Grab Copper NA NA Qtrly/24 hr. Comp.002 TSS 30 mg/L 100 mgfL Weekly/Grab Oil & Grease 15 mg/L 20 mg/L Weekly/Grab pH NA > 6.5 & < 9.0 Weekly/Grab Dissolved Oxygen NA 6.0 mg/L (Min) See Note 2 Silver NA NA Qtrly/24 hr. Comp.003 TSS No Limits No Limits 1/Month Grab 004 Total Chlorine/ Oxidants NA 0.02 mg/L/0.05 mg/L Daily Grab See Note I See pH NA >6.5 & <9.0 Daily Grab Note 3 588 Sludge Solids, % Total No Limits No Limits Each Sludge disposal Sludge Weight No Limits No Limits Each Sludge disposal 601 TSS 30 mg/L 45 mg/L Weekly/Grab BOD 5 30 mg/L 45 mgfL Weekly/Grab 602 TSS 30 mg/L 100 mg/L 2/Month Grab Oil & Grease 15 mg/L 20 mg/L 2/Month Grab 801 Temperature NA NA Daily NOTES 1. Collect samples for Total Residual Chlorine when system is being treated with only chlorine. Collect samples for Total Residue/Oxidants when system is being treated with bromine.2. Collect samples twice per month if hydrazine-containing water directed to Outfall 002..3. Sampling is required only during discharge from the circulating water system (i.e. Cooling Tower Basin Drain).GENERAL EFFLUENT LIMITATIONS:
- 1. There shall be no discharge of polychlorinated biphenol compounds.
- 2. The effluent shall, at all times, be free of substances:
- a. In amounts that will settle to form putrescent, or otherwise objectionable, sludge deposits or that will adversely affect aquatic life or water fowl. ;b. Of an oily, greasy, or surface-active nature, and of other floating debris, in amounts that will form noticeable accumulations of scum, foam, or sheen;c. In amounts that will alter the natural color of the receiving water to such degree as to create a nuisance;d. In amounts that either singly or in combination with other substances are toxic to human, animal, or aquatic life;e. In amounts that are conducive to the growth of aquatic weeds or algae to the extent that such growth growths become inimical to more desirable forms of aquatic life, or create conditions that are unsightly, or constitute a nuisance in any other fashion;f. In amounts that will impair designated instream or downstream water uses.
ATTACHMENT 2: EXAMPLES OF NPDES REPORTABLE EVENTS Page 1 of I A. NONCOMPLIANCE (Listed in Attachment 1, but discharged above specified limits)1. Oil drained through east and/or west condenser pit sumps to the settling basins and out Outfall 602 to the collection box in excess of 20 mglL or with a visible sheen.2. Shock chlorination activities resulting in the discharge of total chlorine at Outfall 001 (beach station) in excess of 0.2 mg/L or the discharge of any detectable amount (>0.05 mg/L) for more than two hours per day.B. UNAUTHORIZED DISCHARGE (Not listed on Attachment 1, but discharged above analytical detection limit)1. Inadvertently draining a system containing sodium hypochlorite to the Training Center Pond and out Outfall 002 in a detectable amount (>0.05 mg/L), since there is no chlorine limit listed for Outfall 002 on Attachment 1.C. UNANTICIPATED BYPASS (Unplanned)
- 1. Failure of the wastewater treatment plant effluent pumps, resulting in the discharge of raw sewage to the Navarre Marsh Pool 3.2. Failure of the North Settling Basin pumps, resulting in industrial process water overflowing the settling basins and discharging into the Navarre Marsh Pool 2.D. ANTICIPATED BYPASS (Planned drainage in a manner inconsistent with the NPDES permit.1. Draining the cooling tower basin to the cooling tower pond for outage work without obtaining prior Ohio EPA approval. (This water may contain chlorine, which may only be discharged via Outfall 001 beach station).E. UPSET (Unintentional and temporary noncompliance)
- 1. During the spring months, Outfall 601 (Wastewater settling basin) may become overgrown with algae. This is a natural part of tertiary sewage treatment, but it may result in the discharge of total suspended solids above the permit limit, which is reportable.
- 2. During the spring months, when intake water from Lake Erie has a high pH, the Outfall 001 pH may exceed the maximum daily limit of 9.0 S.U. which is reportable, even though the intake pH is also high.
ED 7575A DAVIS-BESSE ADMINISTRATIVE PROCEDURE National Pollutant Discharge Elimination System (NPDES) Program PAGE REVISION PROCEDURE NUMBER 18 00 DB-CN-00030 ATTACHMENT 3: OHIO EPA NPDES DATA CODES Page 1 of I CODE AA AB AC AD AE AF AG AH AJ AK AL AN COMMENT Below detectable limit Analytical Data lost Plant not operating Automatic analyzer out of service Analytical data not valid High stream water inundated sample site Trace Sample not taken, explanation in remark section Above range of automatic sampler Biological Sample -too numerous to count No discharge for the month Sample not taken, plant not normally staffed EO 7575A DAVIS-BESSE ADMINISTRATIVE PROCEDURE National Pollutant Discharge Elimination System (NPDES) Program PAGE 19 REVISION PROCEDURE NUMBER o0 DB-CN-00030 ATTACHMENT 4: NPDES SPILL RESPONSE FLOW CHART Page 1 of I 0 x cli DAVIS-BESSE BUSINESS PRACTICE Number *" DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 1 of 57 SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLANý'). L C2ý-Ti /i .AIL Approved: Date: s/__ _ _MAR 2 8 200h Effective Date DAVIS-BESSE BUSINESS PRACTICE Number:____________________________________ DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 2 of 57 TABLE OF CONTENTS Paqe 1.0 PURPOSE 3 2.0 APPLICABILITY/SCOPE 3 3.0 DEFINITIONS 4 4.0 RESPONSIBILITIES 7 5.0 OIL DISCHARGE INITIATING CONDITIONS AND NOTIFICATIONS 8 6.0 SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 12 6.1 General Information 12 6.2 Discussion of Oil Spill Containment 13 6.3 Oil Locations and Specific Oil Spill Situations 20 7.0 RECORDS 36
8.0 REFERENCES
36 ATTACHMENTS ATTACHMENT 1 -DISCHARGE NOTIFICATION TABLE ATTACHMENT 2 -DBNPS SITE AREA AND NEAREST TOWNS ATTACHMENT 3 -DBNPS FINISHED SITE TOPOGRAPHY ATTACHMENT 4 -DBNPS SITE MAP ATTACHMENT 5 -DBNPS OIL LOCATION ATTACHMENT 6 -CERTIFICATE OF THE APPLICABILITY OF NON-SUBSTANTIAL HARM CRITERIA ATTACHMENT 7 -RESPONSE EQUIPMENT / CONTRACTOR LIST ATTACHMENT 8 -CERTIFICATION OF THE SITE SPECIFIC SPCC PLAN ATTACHMENT 9 -SPCC COMPLETION OF REVIEW OF SITE SPCC PLAN ATTACHMENT 10 -SPCC REVISION RECORD ATTACHMENT 11 -SPCC OIL STORAGE LOCATIONS COMPLIANCE TABLE DAVIS-BESSE BUSINESS PRACTICE Number:___________________________________ DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 3 of 57 1.0 PURPOSE 1.1 The purpose of this business practice is to provide written documentation of compliance and countermeasures (such as equipment, workforce, and/or procedures) for minimizing the potential of discharges of oil or oil related products in harmful quantities into or upon navigational water of the United States, the adjoining shorelines or contiguous zones, or that may affect natural resources. 1.2 This business practice identifies all bulk containers of oil or oil related products and countermeasures to be taken in the event of oil discharges from non-transportation related incidents, such as activities from transferring, distributing, using, or consuming oil or oil products at DBNPS. Countermeasure contingencies for minimizing harmful discharges are required for both bulk storage containers and oil filled electrical equipment. 1.3 This business practice, in conjunction with RA-EP-02850, Hazardous Chemical and Oil Spills, the DBNPS Emergency (E) Plan, and requirements of the National Oil and Hazardous Substances Pollution Contingency (NPC) Plan, fulfills the requirements for the Spill Prevention, Control, and Countermeasure (SPCC) Plan.This plan is required for facilities storing greater than 1320 gallons in above ground storage containers or when greater than 42,000 gallons is stored in an underground storage container and the location provides potential for a harmful discharge of oil.2.0 APPLICABILITY/SCOPE
2.1 Adherence
to this Business Practice is Mandatory. Reference Section 5.0 for reporting, reference Section 6.2.5 for general oil clean-up actions, and reference Section 6.3 for specific system responses. 2.2 This business practice applies to personnel who may be responsible for implementation of the SPCC Plan. The scope of this business practice is to provide instructions and required information for oil spill prevention and mitigation from releases of all above ground containers greater than 55 gallons, which includes all bulk storage containers, all Underground Storage or Bunkered Tanks, and all oil containing electrical or operating equipment. 2.3 For Hazardous Waste Operations Emergency Response (HAZWOPER) implementation, activate RA-EP-02850. The Off-Normal Emergency Response Organization procedure provides detailed actions for immediate response to spills or discharges from oils and/or chemicals. DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 4 of 57 2.4 Oil discharges may require additional response and mitigation actions if mixed with other regulated constituents. NOTE 2.4.1 Hazardous substances 'inherent' to crude oil, gasoline, or oil products are not reportable under the Comprehensive Environmental Response Compensations Liability's Act (CERCLA) or Superfund Amendments Reauthorization Act (SARA).2.4.1 Consult the Resource Conservation and Recovery Act (RCRA) Contingency Plan/Spill Notification Requirements Business Practice (DBBP-CHEM-2003) for a listing of Reportable Quantities (RQs) for hazardous chemicals.
2.4.2 Consult
the CERCLA/SARA Hazardous Chemical Locations and Spill Event Guideline (ECG-04) for response plans and clean up of hazardous chemicals typically found at Davis-Besse. 2.4.3 For oil spills occurring from Polychlorinated Biphenyl (PCB) equipment, perform cleanup per required Toxic Substance Control Act (TSCA) standards found in the PCB Activities and Response Plan (ECG-07).3.0 DEFINITIONS 3.1 BULK STORAGE CONTAINER -Any container used to store oil (equal to or greater than 55 gallons), including prior to use, while being used, seasonal storage or temporary storage, stand-by storage, or prior to further distribution in commerce.Bunkered and completely buried tanks are considered bulk storage containers. Bulk storage containers require a regular schedule of integrity testing and when repairs are made as defined under the definition of "Repair" (such as tank repairs).3.1.1 Oil-filled electrical or operating equipment is not considered a "bulk container" per the SPCC regulations regarding secondary containment or integrity testing, however, countermeasures to prevent harmful discharges are required.3.2 DISCHARGE -Includes but is not limited to any spilling, leaking, pumping, pouring, emitting, emptying, or dumping, of oil no matter where it occurs. The discharge however may not be reportable if the oil never escapes secondary containment or is fully contained on site and is promptly cleaned up. A harmful discharge is reportable to the National Response Center (reference Section 5.0). Discharges greater than 25 gallons in a 24-hour period that originate from an Underground Storage Tank, and do not meet any other 'harmful discharge' criteria, are only reportable to the Bureau of Underground Storage Tanks (reference step 5.4.2). DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 5 of 57 3.3 EMERGENCY RESPONSE -A response effort by employees from outside the immediate release area or by other designated responders (i.e. local fire departments or contracted responder) to a spill event which results or is likely to result in an uncontrolled release of a hazardous chemical or oil. Responses to releases of oil (or hazardous chemicals) where no potential safety or health hazard exists or the potentials for harmful discharges are mitigated and no regulatory agency notifications are required, are not considered emergency responses.
3.4 ENVIRONMENT
-For the purpose of this business practice, means outside of the system or diversionary structures (drum, container, tank, pipeline, process vessel, etc.) intended/designed to contain a hazardous chemical or oil or prevent it's release such that it becomes a harmful discharge.
3.5 ENVIRONMENTALLY
EQUIVALENT METHOD -An alternate method for integrity testing that must effectively minimize the risk of container failure and allow detection of leaks before they become significant (reference (112.7(a)(2). Examples include: Elevated drums or shop built containers (shell capacity less than 30,000 gallons), when a frequent visual inspection is accompanied by additional actions to ensure containers do not come in contact with soil, such as, elevating the containers so all sides are visible during inspection, or placing on a barrier (synthetic liner) between the container and the ground.3.6 HARMFUL DISCHARGE -A 'harmful discharge' is a discharge that escapes secondary containment and can reasonably be expected to be discharged in harmful quantities into or upon navigational water of the United States, the adjoining shorelines or contiguous zones, or affect natural resources. Examples of harmful discharges include discharges that violate applicable water quality standards (causes a film, sheen or discoloration of water surface, or a sludge or emulsion deposited beneath water surface), or discharges which have migrated out of control of or off of company property.3.7 NAVIGABLE WATERWAYS -Indicates the following: 3.7.1 All navigable water of the United States (U.S.), and adjacent wetlands (for example, the marsh surrounding DBNPS).3.7.2 Tributaries of navigable waters of the U.S. (including adjacent wetlands). 3.7.3 All other waters of the U.S. such as intrastate lakes, rivers, streams, and wetlands which may be used for recreational or commercial (including commercial fishing)purposes. DAVIS-BESSE BUSINESS PRACTICE Number:___________________________________ DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 6 of 57 3.8 OIL -Includes petroleum; gasoline; fuel oil; oil refuse; and mixture of oil with wastes other than dredged oil.3.8.1 Oils contaminated with PCBs or hazardous chemicals, not inherent to the oil, shall also be considered hazardous chemicals. The RCRA Contingency Plan (DBBP-CHEM-2003), SARA/CERCLA Response Business Practice Guideline (ECG-04) or, the PCB Activities and Response Plan (ECG-07), as appropriate should also be consulted. 3.9 OIL BOOM -A floating device that confines oil spilled on the surface of a body of water.3.10 PERMANANTLY CLOSED -Containers are considered 'permanently closed' after all liquid or sludge is removed, connection line(s) and piping are disconnected and blanked off; all valves (except ventilation valves) have been closed and locked, and signs have been posted stating closure with a notation of the date of closure.3.11 REPAIR -Any work necessary to maintain or restore a container to a condition other than that necessary for ordinary day-to-day maintenance to maintain the functional integrity of the container and that does not weaken the container integrity. 3.12 SECONDARY CONTAINMENT -Countermeasures such as, cathodic protection of buried piping, double-walled pipes, earthen or natural structures or berming, oil interceptors, containment pallets, diversionary or drainage structure, employed to ensure containment of oil from breach of a container or piping, and is applied in accordance with good engineering practice and judgement. Secondary containment is required for all bulk storage containers. 3.13 SMALL SPILL OR DISCHARGE / INCIDENTAL RELEASE -Small spills or discharges (i.e. incidental releases of chemicals or oils) which can be absorbed, neutralized, or contained at the time of release by trained employees in the immediate release area or by maintenance personnel. An incidental release or discharge poses no safety or health hazard (i.e. fire, explosion, or chemical exposure), cannot be reasonably expected to be discharged in harmful quantities or pose a potential harmful discharge off-site, and do not require off-site notifications of the release. These spills/discharges/releases are not "spill events" and do not require "emergency responses. Note however, that in accordance with Attachment 5 of RA-EP-02850, even listed typical small or incidental releases must be reported to the Control Room. DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 7 of 57 4.0 RESPONSIBILITIES 4.1 The Supervisor -Nuclear Chemistry Services shall: 4.1.1 Provide overall administration of this business practice.4.1.2 Make required onsite and offsite notifications and prepare regulatory reports.4.1.3 Provide technical assistance during response and clean-up efforts to ensure timely mitigation of spill.4.1.4 Ensure that spill equipment or kits for use with potential oil discharges on site are stocked with emergency response equipment, or contractual arrangements are secured for emergency response.4.1.5 Designate site individual(s) as 'Emergency Coordinator'/'Oil Spill Response Coordinator' (primary and alternate).
4.1.6 Complete
a review and evaluation of the SPCC Plan at least once every five years and: 1. Amend within 6 months of changes in facility design, construction, operation, or maintenance, that materially affects the potential for oil discharge in harmful quantities of oil to into or upon navigable waters, adjoining shorelines shore-lines, contiguous zones, or that affect natural resources. Notifications may be made in accordance with Regulatory Applicability Determinations and Environmental Evaluations. Examples of activities potentially requiring amendments to the SPCC Plan include decommissioning of tanks or containers, replacement, reconstruction or movement of containers, reconstruction, replacement or installation of piping systems, and, changes in product or service or revision of standard operation or maintenance procedures affecting the plan.2. Amendments to the SPCC Plan must be implemented as soon as possible, but no later than 6 months following preparation of the plan amendment (no later than 12 months after the change or activity causing the amendment.)
- 3. The review shall include amendments to the plan within 6 months to include effective prevention and control technology if the technology has been field proven at the time of the review, and will significantly reduce the likelihood of a discharge in harmful quantities.
The reviews shall indicate if amendments are required, and if amended, certified by a licensed Professional Engineer (PE). DAVIS-BESSE BUSINESS PRACTICE Number:___________________________________ DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 8 of 57 4.2 Other actions for an oil spill response as required per RA-EP-02850 may occur concurrently with the SPCC Plan implementation. These actions may include: 4.2.1 The Shift Manager or designee may make required onsite notifications and determine if a spill event has occurred which requires implementation of HAZWOPER.4.2.2 Industrial Safety may prescribe personnel protective equipment and practices during an emergency response.4.2.3 The Superintendent -Nuclear Maintenance Services may direct isolation of site waterways during a spill event and provide clean up of spilled materials. 4.2.4 All DBNPS personnel shall immediately report oil spill events or observed oil discharges to the Shift Manager.4.3 All oil discharges shall be mitigated as soon as possible after discovery. 5.0 OIL DISCHARGE INITIATING CONDITIONS AND NOTIFICATIONS 5.1 If an 'incidental' release or discharge of oil does not meet conditions of reportable discharges listed under Step 5.2, and poses no threat of migration to the offsite environment or of becoming a "harmful discharge", then the SPCC Plan is not required to be implemented. Actions for immediate mitigation and cleanup of all oil discharges are still required. Reference RA-EP-02850, Attachment 5 for additional information for appropriate PPE or disposal information for incidental releases.5.1.1 Reportable NPDES violations which pose no threat of migration of oil or hazardous substance in harmful quantities or harmful discharges, do not require SPCC Plan implementation. Only the NPDES notification requirements as specified in the permit are imposed.5.2 The SPCC Plan notifications and appropriate mitigation responses shall be implemented as directed by the Supervisor -Nuclear Chemistry Services (or Emergency Coordinator designee) when one or more of the following conditions involving oil discharges has occurred: 5.2.1 Any oil release greater than 25 gallons within a 24-hour period originating from a registered Underground Storage Tank (UST) or associated piping.5.2.2 Any oil release greater than 25 gallons within a 24-hour period not solely contained within the facility.5.2.3 Any oil leakage which is suspected to be contaminated with a hazardous substance exceeding a Reportable Quantity, which is not solely contained within the facility. DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 9 of 57 5.2.4 A volume of oil in "harmful quantities" or designated as a "harmful discharge" has reached a navigable waterway, entered a National Pollutant Discharge Elimination System (NPDES) pathway, or discharged to affect natural resources (has migrated off of company property.) 5.3 If a discharge event as listed in Step 5.2 has occurred, the Supervisor -Nuclear Chemistry Services (or Emergency Coordinator designee) will perform the following Onsite/Company Notifications as necessary. These notifications may be documented, on the Spill Notification Form (ED 7892.) Additional phone numbers may be found in the DB or E Plan Telephone Directory (Section 2.2), or Attachment 1 (Discharge Notification Table) of this Business Practice.* Manager -Site Chemistry* Manager -Site Regulatory Compliance" Director -Site Engineering, as applicable
- Superintendent
-Nuclear Electrical Maintenance, Nuclear I&C Maintenance, Nuclear Mechanical Maintenance, or Nuclear Maintenance Services, as necessary, if the discharge originated from electrical or mechanical equipment, or for additional support" Director -Site Operations" FirstEnergy Environmental Permitting and Compliance (courtesy call)* Public Affairs (optional notification -this office will contact Governmental Affairs if required, reference E Plan Telephone Directory) 5.4 If a discharge event as listed in Step 5.2. has occurred, the Supervisor -Nuclear Chemistry Services (or Emergency Coordinator designee) will perform the following Offsite/Regulatory Notifications as necessary. These notifications may be documented on the Spill Notification Form (ED 7892.) Additional phone numbers may be found in the DB or E Plan Telephone Directory and either Attachment 1 (Discharge Notification Table) or Attachment 7 (Response Equipment/Contractor List) of this Business Practice.5.4.1 IF an oil release has occurred in accordance with Step 5.2.1 from any of the following registered underground storage tanks: 1. TA153-01 or TA153-02; 40,000 gallon Emergency Diesel Generator Fuel Oil Storage Tanks, or, 2. 8,000 gallon DBAB Emergency Diesel Generator Oil Storage Tank DAVIS-BESSE BUSINESS PRACTICE Number:___________________________________ DBB P-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 10 of 57 THEN within 24 hours notify the State Fire Marshal (1-800-686-2878) and Carroll Township Fire Department (419-898-4906). Ensure notifications listed under Step 5.4.2 are also performed if the release is a 'harmful discharge' (reference Step 3.6 for detailed description of a harmful discharge). 5.4.2 IF a discharge or release, as listed in Steps 5.2.2 or 5.2.3 has occurred, such as: 1. An oil or gasoline discharge greater than 25 gallons which poses a threat to personnel outside of the site boundary, or could possibly migrate outside of site boundaries "to become a harmful discharge", or, 2. Any amount of PCB oil (>50 ppm) or "harmful quantities" of gasoline, or non-PCB oil have spilled directly into a waterway or may become a "harmful discharge", or, 3. Oil mixed with a hazardous substance (which is not inherent to the crude oil, gasoline or oil product) greater than the reportable quantity, and is not contained within site boundaries (reference ECG-04 for 40 CFR 302 or 40 CFR 355 RQs of materials typically stored on site), THEN within 30 minutes notify the Ohio EPA Emergency Response Center (1-800-282-9378), the Ottawa County Sheriff to activate the Local Fire Department and Ottawa County Local Emergency Planning Committee (LEPC) notifications (419-734-4404), and the National Response Center (1-800-424-8802). 5.4.3 IF an oil or PCB event, has occurred in accordance with Step 5.2.4. which: 1. Affects NPDES water discharge pathways, or, 2. Is a bypass of the normal route of NPDES discharge, THEN within 24 hours notify the OEPA Emergency Response Center (1-800-282-9378) in accordance with DB-CN-00030. 5.4.4 IF the oil discharge affecting NPDES pathways is a PCB discharge, or discharges greater than the RQ, THEN they must additionally be reported within 30 minutes to agencies listed in Step 5.4.2. EPA may assign the same case number to discharges meeting criteria of 5.2.3 and 5.2.4.5.5 Contact the Supervisor -Nuclear Chemistry Services (or Emergency Coordinator designee) for determination of the required response for oil discharges not listed. DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 11 of 57 5.6 The following information shall be available for reports to offsite regulatory agencies:* Name and telephone number of facility's reporter* Name and phone number of the facility and owner" The exact address of the facility* The date and time of discharge* The name, source and type of material discharged, estimating the total quantity, and the estimates of quantities that are considered a "harmful discharge"* The source and cause of the discharge, to what medium the release occurred, and damages or injuries* Actions to stop, remove, or mitigate the effects of the discharge," Whether evacuation may be needed," The names of individuals or organizations contacted. 5.6.1 In addition to the required information to be reported, insure the following information is also provided for oil discharges involving hazardous substances (reference Step 5.2.3 and Note 2.4.2)Possible hazard to human health (known or anticipated, acute or chronic) or to the environment outside the facility, and* Where advice or medical attention may be obtained, if required 5.7 Follow-up reports should be submitted in accordance with NG-RA-00807 and NG-NS-00808 for the following: 5.7.1 In accordance with 40 CFR 280.62(a) and (b), written reports for reportable UST releases shall be submitted to the governing agency within 20 and 45 days, summarizing abatement, and corrective action plans, respectively. Ensure additional reports as required in steps 5.7.2 -5.7.4 are prepared if the release meets the conditions specified as a 'harmful discharge'. DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 12 of 57 5.7.2 In accordance with Environmental Compliance Guideline ECG-04, a written report as defined in OAC 3750 25-25 shall be submitted within 30 days of a reportable SARA/CERLA spill. The report must be submitted within 15 days if the reportable hazardous oil spill discharge originated from the Chemical Waste Storage Area or an accumulation area.5.7.3 In accordance with DB-CN-00030, a written report shall be submitted within 5 days for all NPDES violations. 5.7.4 A written report shall be submitted within 60 days for discharges more than 1000 gallons in a single discharge, or two discharges of more than 42 gallons each within a 12 month period that are considered a 'harmful discharge". The report shall be prepared in accordance with requirements of 40 CFR 112.4.6.0 SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 6.1 General Information 6.1.1 The plan shall be reviewed not less than every 5 years and: 1. Amended and certified within 6 months of facility changes which affects the potential for discharge of oil into or upon navigational waters of the U.S. or adjoining shore lines, or affecting natural resources (reference Step 4.1.6 for examples of facility changes that may affect the plan.)2. Amended and certified if control technology which reduces the likelihood of a discharge becomes available and is field proven.6.1.2 Name and location of facility: Name: Davis-Besse Nuclear Power Station Location: 5501 North S.R. 2, Oak Harbor, Ohio 43449-9760 Emergency Telephone Number: 419-321-7283 Direction and distance to nearest town -Oak Harbor (SW -6.5 miles)Township: Benton-Carroll County: Ottawa State: Ohio Nearest Major Roadway: State Route 2 (Contiguous on the West)Nearest Watershed: Navarre Marsh (Contiguous on the North, East, and South)Nearest River: Toussaint River (1 mile South)A site area and nearest towns diagram is provided in Attachment
- 2.
DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 13 of 57 6.1.3 Direction of Surface Flow and General Topographic
== Description:==
The natural substrate surrounding the facility and indigenous to the area is blue clay, limiting natural permeability. The facility drainage is installed such that oil interceptors and catch basins discharge via storm sewers or diversionary systems to site controlled basins or ponds. The natural substrate under the operating facilities was excavated during construction and replaced with a low permeable highly compacted crushed stone. The parking lots are asphalt covered, and limited areas have concrete covers (such as the Dry-Fuel Storage Pad.) There are no significantly treed areas and only sparse areas of shrubs or grasses on the operating premises. The contingent marsh is densely forested and maintained by the U. S. Wildlife Service.A site topographic diagram is provided in Attachment 3.6.1.4 Name, address, and phone number of owner or operator: Name: FirstEnergy Nuclear Generation Corporation County: Summit Address: 76 South Main St. State: Ohio City: Akron Zip: 44308-1890 Telephone Number: 800-633-4766 6.1.5 Name or title of person in charge of facility: Name or title: Director-Plant Operations 6.1.6 Name of person responsible for oil spill prevention/mitigation at facility: Name or title: Shift Manager 6.1.7 Certification The Plan requires certification to attest the information contained in the plan is true, complete, and accurate, and prepared in accordance with good engineering practices. The plan does not require re-certification for plan changes that do not require engineering judgment. Attestations for the PE certifications are included under Attachment
8.6.2 Discussion
of Oil Spill Containment
6.2.1 Security
Considerations All the oil tanks at the Davis-Besse Nuclear Power Station are located in an area that has a security lighting system and is patrolled 24 hours a day by security personnel. Most of the tanks are located behind the inner fence within the Protected Area. The possibility of vandalism and tampering is minimized through controlled access to the site via the Service Road and by virtue of the plant's distance from the highway. A site map is provided in Attachment
- 4.
DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 14 of 57 6.2.2 Personnel Training Designated Operations, Maintenance and HAZWOPER personnel responsible for responding to an oil spill are on site or on call continuously to ensure immediate response to site spills or contracting outside support if required. Site response personnel are trained in the following and receive annual refresher training.1. Known failures or equipment malfunctions, and prevention procedures, practices, and opportunities to improve compliance, 2. Proper operation and maintenance of equipment to prevent discharge of oil 3. The proper procedure to follow in the event of an oil spill situation 4. Applicable Spill Prevention Control and Countermeasures (SPCC) Pollution Laws, Rules and Regulations, and site procedures for implementation. NOTE 6.2.3 Oil-filled electrical, operating and manufacturing devices or equipment are not exempt from integrity testing requirements of 40 CFR 112.8 (c)(6).6.2.3 Discussion of Oil Tank and Piping Testing/Inspection/Protection
- 1. 40 CFR 112.8 (c) states bulk storage containers must be regularly integrity tested. Integrity testing is a combination of visual inspection plus one other testing technique and is required for all above ground bulk storage containers.
Testing techniques include visual inspections plus hydrostatic testing, Ultrasonic, Radiographic, Acoustical, or other non-destructive shell thickness testing. Integrity testing includes leak testing for valves and piping. Tank supports and foundations should be included in these inspections. Also, the tank exterior shall frequently be observed for signs of deterioration, leaks that might cause a spill, or accumulation of oil in diked areas. Acceptable documented methods include Hybrid Testing, Industry Standards, and Environmental Equivalent.
- a. The integrity testing applies to large field-constructed or field-erected welded metal above ground tanks (AST); name-plated as field-erected if less than 50 feet high and a 30 foot diameter (or without a name-plate if greater than 50,000 gallons), and small welded-metal shop fabricated AST not otherwise identified as field-erected with a volume less than 50,000 gallons.
DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page* SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 15 of 57 b. Industry Standards for containers built to specified design in accordance with recommended industry practices may be used for integrity testing by facility owners and operators and by the certifying PE as references of good engineering practice for assessing the fitness of service for containers, or evaluating the suitability of containers for continued service. Industry Standards for recommended practices for piping, valves and appurtenances, may also be applied. The PE may also implement "Hybrid" inspection programs based on professional judgment for unique circumstances, or when industry standards are not specific for a tank configuration. Examples of accepted Industry Standards include: API 653, STI SP-001, API 650, API 12C, API 12R1, API RP 575, API RP 12R1, API 570, API RP 574, API RP 1110, API RP 579, API 2610, ASME B31.2, ASME B31.4-2002, and DOT 49CFRParts 173.28, 178.803, or 180.605.c. The Environmental Equivalence provision applies to the inspection and appropriate integrity testing of bulk storage containers. The PE has the flexibility to offer environmental equivalent integrity testing options for all classes of tanks, including shop-built tanks above 30,000 gallon capacity and field-erected tanks, if the rationale is provided or appropriate industry standards are referenced.
- d. In cases where a regularly scheduled inspection and testing program is not currently identified, no baseline information is available, and no environmental equivalence or Industry Standard for integrity is documented, the Industry Standard or strategy for regular testing must be identified and collection of baseline information testing must be scheduled within 10 years from tank installation, or within the first five-year review cycle of the SPCC Plan (within 5 years from effective implementation date of August 18, 2006 and completed by August 18, 2011) in order to establish a regular integrity testing schedule based on current container conditions.
Testing is performed under the site Work Management Program, or tracked for completion under the site Corrective Action Program/SAP Activity Tracking Items for integrity or baseline testing to be initiated (reference Attachment 11 notes for individual ASTs).2. All areas (zones) containing operational equipment, oil storage tanks and storage containers at DBNPS are periodically visually inspected by various groups, i.e. Operations, Maintenance, and/or Engineering. Periodic Maintenance and Testing activities for specific tanks, such as the Emergency Diesel Generator Fuel Oil Storage Tanks (40,000 gallon capacity each), are periodically drained and inspected internally. The requirements for the inspections and testing are managed and documented through the Work ,hk Management Process. DAVIS-BESSE BUSINESS PRACTICE Number:___________________________________ DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 16 of 57 3. The oil storage tank transfer lines at DBNPS are wrapped and cathodically protected. Inspections are performed on a standard preventative maintenance program, or as excavation activities allow. Any storage tank transfer line leakage from offloading of bulk oil would discharge via the storm system and oil interceptors to onsite secondary containment. Leakage from onsite transfer lines would be identified as indicated in Step 6.2.4 discussion.
- 4. Protection is additionally provided by the use of monitoring controls and secondary containment.
Tank levels are monitored visually, and by use of gauges and high level alarms. Level devices are regularly tested. Effluents discharged into navigable waters are site monitored by a NPDES permit.Portable storage tanks are required to have sufficient secondary containment.
- 5. The concept and nature of nuclear operations, training and frequent zone walkdowns ensures above ground valves and pipe-lines are subjected to regular visual examinations.
Station drainage and discharge is procedurally controlled.
- 6. Vehicular traffic within the protected area is minimal. IF vendor vehicles are allowed access, THEN the vehicle is accompanied by Security personnel.
- 7. Integrity testing, secondary containment, or new requirements are verified against 40 CFR 112.8 criteria pursuant to the 5-year required review.Deficiencies are tracked under the site corrective action program for implementation of acceptable corrective actions or countermeasures in accordance with Step 4.1.6. (example:
tracking through completion of applicable corrective actions for addition of brittle failure evaluations when field-constructed tanks of shell thickness greater than 1/2 inches are repaired.)
6.2.4 Discussion
of Oil Interceptors
- 1. All drains in the plant, where oil contamination is postulated, discharge to the Storm Sewer System via a Josam Oil Interceptor (exception is the East and West Condenser Pit Sumps, which are redirected to the Settling Basins). There are six (6) Oil Interceptors (01) strategically located to accommodate the drains in the station. Oil Interceptors 1, 2, 3, 4, 5, and 7 drain to the Training Center Pond. There are two (2) Oil Interceptors 6A and 6B, which are located in the northeast parking lot and which drain to the marsh. The parking lot by the Personnel Access Facility (PAF) does not have Oil Interceptors.
The Oil Interceptors are located in the following areas: DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 17 of 57 Oil Interceptor
- 1: Oil Interceptor
- 2: Oil Interceptor
- 3: Oil Interceptor
- 4: Oil Interceptor
- 5: Oil Interceptor
- 6A: Oil Interceptor
- 6B: East of the Turbine Building Reference Drawings:
C-55 250 Gallon Capacity Influent Drain Source: Turbine Building Sump Pump Discharge North of Station Turbine Building Reference Drawings: C-55 250 Gallon Capacity Influent Drain Source: Turbine Building Sump Pump Discharge Near Station Valve Room No. 2 Reference Drawings: C-55 100 Gallon Capacity Influent Drain Source: Diesel Fire Pump Room Sump Pump Discharge Near the Diesel Fuel Oil Pump House Reference Drawings: C-55 100 Gallon Capacity Influent Drain Source: Diesel Oil Pump House Sump Pump Discharge, Diesel Oil Storage Tank North of the Auxiliary Building Reference Drawings: C-55 250 Gallon Capacity Influent Drain Source: Multiple Floor Drains in EDG Rooms Main Parking Lot by Service Building 4 Reference Drawings: C-55 100 Gallon Capacity Influent Drain Source: Parking Lot Storm Drains Total Capacity (including Storage Tank): 1300 gallons Main Parking Lot by Service Building 5 Reference Drawings: C-55 100 Gallon Capacity Influent Drain Source: Parking Lot Storm Drains Total Capacity (including Storage Tank): 1300 gallons DAVIS-BESSE BUSINESS PRACTICE Number:___________________________________ DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 18 of 57 Oil Interceptor
- 7: Service Building 6 Reference Drawing C-55 100-159 Gallon Capacity Influent Drain Source: Station Blackout Diesel Generator Fuel Storage Tank NOTE 6.2.4.2 Preventive Maintenance records are generated by maintenance services to document pumping activities.
Such records list, at a minimum, the date, area, and quantity of liquid pumped from the interceptor storage tanks.2. Each oil interceptor is equipped with an oil storage tank. These oil storage tanks collect and contain the oil accumulated from leaks, accidents or ruptures of oil systems, oil tanks and equipment containing oil. Levels in these tanks are periodically checked and pumped out in accordance with Work Management Process.3. If any of the oil interceptor storage tanks are overfilled in the event of oil spill, observe the south settling basin or Training Center pond for evidence of oil.Contain the oil by closing flapper gates in the Training Center Pond and/or turning off north settling basin pumps and using oil booms and absorbent material. Also, oil booms and absorbent material may be used at the spill source to contain and prevent more oil from entering, the oil interceptors. 6.2.5 Oil Discharge Cleanup -General Actions and Commitment of Manpower, Equipment and Materials 1. Symptoms a. Visible oil slick on surface of floor, ground, or water.b. Leaks from equipment containing oil such as pumps and lubricating lines.2. Specific Action a. Identify and mitigate fire, explosion or vapor hazards (implement RA-EP-02850 if HAZWOPER response is required).
- b. Isolate waterways if applicable.
- c. Visually inspect release site, monitor and mitigate further hazards.
DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page* SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 19of57 d. Use any equipment available, such as absorbents, oil booms, and sand bags, to minimize the leak, contain the released material, and prevent further release to the extent possible (Reference system specific responses listed in Section 6.3).e. Contact available vendors for supplies and equipment to control, contain, minimize, remove, and clean up the harmful discharge. If support in addition to the established contracted agreements are required, listings of supplemental Commercial firms may be located in the DBNPS Emergency Plan Telephone Directory.
- f. Remedy hazards posed by contaminated soils or waste, and determine presence of release and free product removal techniques if applicable.
Soils and wastes shall be disposed of in accordance with the site waste handling procedure for Hazardous and Non-hazardous wastes, NG-DB-00504.g. For PCB oil spills, or hazardous substance oil spills, refer to Environmental Compliance Guideline ECG-07, or ECG -04, as appropriate, for clean-up response.h. For Oil spills within the RRA, follow ALARA precautions and use appropriate Radiation Protection procedures in addition to the applicable requirements of this procedure.
- 3. Discussion
- a. The station is equipped with retention areas and oil interceptors to prevent any oil discharges and procedural controls (DP-OP-06272, Station Drainage and Discharge System) for Chemistry notification when drainage routing is altered. If an accident causes an oil spill on the roadways and parking lot, or the drainage system becomes contaminated with oil, every effort shall be made to determine the source and curtail any additional spillage.
Most of the storage containers have secondary containment by use of a containment dike, berm, or retaining structure, cathodic protection, or oil interceptors. The registered Underground Storage Tanks (UST) are not completely regulated under 40 CFR 280 Regulations due to exclusions for Nuclear Power Emergency Generator Status. The site-USTs are therefore regulated under both the SPCC Plan requirements and the UST regulations. Storage containers have been verified to be discharged to site controlled diversionary structures or ponds, which are monitored under the site NPDES permit, or contained within curbing or sumps inside the facility to prevent a harmful discharge. Countermeasures are required for the DBAB Emergency Diesel Generator Storage (and Day) tanks. The storage tank lines are not cathodic protected or wrapped, and the day tank does not have secondary containment. The tanks are designed to discharge to site DAVIS-BESSE BUSINESS PRACTICE Number:___________________________________ DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 20 of 57 Pond 19, located just west of the Cooling Tower. The pond does have a gate valve to prevent uncontrolled outflow and the out-fall is also a monitored release path under the site NPDES permit. For additional compensatory measures, outside contractor agreements are in place.Reference each specific discussion for a prediction of the direction, flow path, and total quantity of oil that may be discharged from each site container.
- b. Transfer operations are performed under strict security and controls.Fugitive overfills will discharge to site diversionary structures.
Reference the specific discussions for each container. Total containment from the largest tanker discharged is required.c. Portable containers must have sufficient secondary containment for the entire contents and appropriate precipitation freeboard.
- d. Precipitation will accumulate in the retention areas and is periodically pumped out by Maintenance Services.e. Various locations are equipped with oil spill pads, booms, or absorbants.
Water booms are used in conjunction with an oil weir at the discharge ponds from the oil interceptors. Contractual agreements ensure unnecessary delays are not encountered when outside support is required.Oil discharge response and cleanup are included in HAZWOPER personnel training. Reference the HAZWOPER procedure, RA-EP-02850 for additional site staged resources. 6.3 Oil Locations and Specific Oil Spill Situations
6.3.1 Diesel
Fuel Oil Storage Tank (DFOST) T45 Leak/Rupture (100,000 Gallons, Drawing 7749-C-34-18-5, Plant System 26-01)1. Symptoms Oil accumulation within the Diesel Fuel Oil Storage Tank retaining structure, or other evidence of tank leakage in the surrounding soils or down stream of catchbasin 31.2. Specific Action a. Utilize means available (drain covers, booms etc.) to keep oil away from catchbasin 31 (located just Northwest of the tank).b. Observe the Training Center pond for evidence of oil. Contain oil in the pond by closing flapper gates and using booms. Contact Environmental for additional support. DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 21 of 57 c. Isolate the tank or suspect lines from the system.3. Discussion The Diesel Oil Storage Tank is designed so that in the event of a leak or rupture, the retaining structure around the tank will contain the entire 100,000 gallon capacity of the tank, plus an additional 15,000 gallons of precipitation and fire water. Periodically, the retaining wall area is checked and any accumulated precipitation is drained to the Diesel Oil Pump House Sump, For the diesel oil storage tank, Computer Alarm L378 receives data from tank contents level transmitter LT 1441 (Foxboro Electronic Transmitter, DP Cell).LT 1441 is located in the southeast quadrant of the retaining moat, about 1.5 feet above the moat floor, near the moat floor access ladder. A local level indicator gauge is also located in the southeast quadrant of the moat area, about 6 feet above the moat floor under the tank access catwalk. This level gauge (LIS-1 102, Varec Figure #2500 Series, Model B) is used to determine amount stored and to monitor amount in tank during filling operations. Any oil leakage into the backfill/catchbasin 31 is routed via the storm sewer to the Training Center Pond. The pond has a weir at the influx and is able to be isolated.6.3.2 Diesel Fire Pump Day Tank T47 Leak/Rupture (350 Gallons, Drawing M-140-00028, Plant System 26-03, Intake Structure 575')1. Symptoms Oil accumulation within the Diesel Day Tank retaining curb.2. Specific Action a. IF the Diesel Oil (DO) Transfer Pumps, P8-1 and PB-2, are transferring oil to the Diesel Fire Pump Day Tank b. THEN stop the DO Transfer Pumps P8-1 and P8-2 1) P8-1 is powered from MCC E12B (BE 1257), control switch HIS105.2) P8-2 is powered from MCC F12B (BF 1257), control switch HIS1106.3) The control switches may be placed in lockout positions.
- 3. Discussion The Diesel Fire Pump is the backup fire safety system to the electric fire pump.The Diesel Fire Pump Day Tank may be filled with the use of the Diesel Oil Transfer Pumps P8-1 and P8-2. The Diesel Fire Pump Day Tank (capacity 350 DAVIS-BESSE BUSINESS PRACTICE Number:___________________________________{
DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 22 of 57 gallons) is designed so in the event of a leak or rupture the retaining curb around the tank will contain any accumulated oil.6.3.3 Emergency Diesel Generator (EDG) Day Tank(s); T46-1 and T46-2 Leak/Rupture (12,000 Gallons Each, Drawing 7749-M129-1-3, Plant System 26-02, Rooms 320A/321A)
- 1. Symptoms of Leakage Oil accumulation within a Diesel Generator Day Tank Area (Room 321A-Day Tank 1 / Room 320A-Day Tank 2)2. Specific Action a. In the event of a rupture in the Day Tank(s) 1-1 or 1-2, respectively:
- 1) Stop EDG Fuel Oil Storage Tank 1-1 Transfer Pump P195-1 with local breaker BE1298 (MCC E12F)2) Stop EDG Fuel Oil Storage Tank 1-2 Transfer Pump P195-2 with local breaker BF 1230 (MCC F12A)b. Use portable pumping equipment to pump the fuel oil from Oil Interceptor
- 5 directly into appropriate containers.
- 3. Discussion
- a. Due to special seismic construction in the area where the Diesel Generator Day Tanks are located, a rupture is very unlikely.
Any fuel oil accumulated from leaks in the Day Tanks (total capacity 12,000 gallons, 6000 gallons per tank), Diesel Generators, or associated piping, are removed by the floor drains to the station process drains/storm sewer system via Oil Interceptor (01) #5, and containment at Training Center Pond in the event of OE #5 overflow (250 gallon capacity). Also refer to Step 6.2.4.3 for further actions/discussions in the event the oil interceptor storage tank overfills.
- b. In the event of a rupture, oil may be pumped to the Transformer Collection Tank and removed to appropriate containers.
6.3.4 Emergency
Diesel Generator (EDG) Fuel Oil Storage Week Tanks T1 53-1, T1 53-2 Leak/Rupture (40,000 Gallons Each, Drawings 7749-M129A 8 and 7749-M129 A-1-6, Plant System 26-02)1. Symptoms Oil accumulation on the ground in the vicinity of the Emergency Diesel Generator Fuel Oil Storage Tanks.S1 0 0 DAVIS-BESSE BUSINESS PRACTICE Number:___________________________________ DBB P-OH EM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 23 of 57 2. Specific Action a. Utilize all means available (storm sewer drain covers, booms, etc.) to keep oil away from Catch Basin 17 (located just south of the tanks), and Collection Box 32 (located off the Northwest Corner of the tanks).b. Observe the pond by the Davis-Besse Training Center for evidence of oil.Contain oil in the pond by closing the flapper gates, and using oil booms.The 40K DFOST spill equipment: sewer covers, pads or booms, are located in Service Building 2. Contact Environmental for additional equipment.
- c. Isolate the tank from the system.3. Discussion Each tank has a 40,000 gallon capacity.
if a rupture or leak occurred below the level of liquid, the fuel oil would leak into the ground, requiring extensive cleanup. Local level indicators (analog meters) are located adjacent to the filling point for each tank. Input for each indicator is received from a capacitance probe that is located within the tank (Indicator LI 4891 receives input from probe in Tank T1 53-1; Indicator LI 4892 receives input from probe in Tank T1 53-2). The indicator registers from 30,000 gallons (0%) to 40,000 gallons (100%) on an inverse logarithmic scale, with a high level local alarm light setpoint of 39,850 gallons and a low level local alarm light setpoint of 38,000 gallons. Periodic monitoring of tank inventories and close monitoring of fuel oil levels during filling procedures should prevent overfills from occurring. The tanks are registered as Underground Storage Tanks.6.3.5 Miscellaneous Diesel Generator Day Tank T168 Leak/Rupture (750 Gallons, Drawing 7749-M-1 25-114, Plant System 99-06)1. Symptoms Oil accumulation in Room 331, Miscellaneous Diesel Generator Day Tank Room.2. Specific Action a. Operations is notified that a High/Low Oil Level Alarm has been received from the Miscellaneous Diesel Day Tank.b. Verify if there is (or is not) a tank leak/rupture. DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 24 of 57 c. IF a tank leak/rupture exists, close Isolation Valve DO 112, Miscellaneous Diesel Day Tank Isolation Valve, in the Miscellaneous Diesel Day Tank Room, d. THEN stop the Diesel Oil Transfer Pumps, P8-1 and P8-2, if they are running.1) P8-1 is powered from MCC E12B (BE 1257), control switch HIS 1105.2) P8-2 is powered from MCC F12B (BF 1257), control switch HIS 1107.3) The control switches may be placed in lockout positions.
- 3. Discussion
- a. The Miscellaneous Diesel Day Tank Room is a retaining structure with no floor drains that will easily contain the contents of the 740-gallon Capacity Tank.b. Valve DO 112 should be opened only when filling the Miscellaneous Diesel Day Tank.c. Normally the tank is gravity-filled from the Diesel Fuel Storage Tank.6.3.6 Turbine-Generator (T-G) Lube Oil (LO) Storage Tank T32 Leak/Rupture (2 Tanks;- 14, 0000 Gallons Each, Plant System 89-01, Room 432,)1. Symptoms Oil accumulation within the T-G Lube Oil Tank Room, or actuation of Annunciator, Computer Points 9-6-1 (ref OS-024A, SH 2)2. Specific Action If a temporary pump is in the sump, ensure the pump is also shut off.3. Discussion The tank is equipped with Annunciator (computer point 9-6-D) and Level Alarms (LSH 1165 and LSH 1250) tested per Maintenance Program (PM 1544).Visual inspections by periodic system walk downs are also performed.
Any oil accumulation from a leak or rupture in the T-G Lube Oil Tank Room or the Lube Oil Storage Tank Room will drain into the Lube Oil Storage Tank Room Sump. The Sump pumps for that sump have been permanently disabled, so the accumulated oil would be contained in the Lube Oil Storage Tank Room, thus preventing any oil from reaching the storm sewer system. In the event the oil interceptor storage tank is overfilled, refer to Step 6.2.4.3 for further actions.S 0 DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 25 of 57 6.3.7 Main Feed Pump Turbine (MFPT) Lubricating Oil (LO) Tanks (2) or MFPT Used LO Tank Leak/Rupture (MFPT-LO-1200 Gallons Each, MFPT Used LO is 2800 Gallons, Plant Systems 36-04, 565 Elevation)
- 1. Symptoms Oil accumulation in MFPT LO Tank pit or West Condenser Pit Sump (drains to sump via floor drains).2. Specific Action a. Stop Condenser Pit (west) Sump Pumps by, opening the breakers at MCC E32B (BE 3289) for Sump Pump P 33-A and F32B (BF 3289) for Sump Pump P 33-B.b. If there is a temporary sump pump installed in the West Condenser Pit used to pump to the East Condenser Pit, ensure the temporary pump is also shut off; it will be powered via a lead cord from a nearby 1 10V receptacle.
- 3. Discussion
- a. Some oil leaks from the MFPT LO Tanks #1 and/or #2 will accumulate in the MFPT LO Tank Pit. The Pit has drain plugs in place to prevent oil and liquid draining to the West Condenser Pit Sump through the floor drains.The West Condenser Pit Sump Level is automatically controlled by Sump Pumps P 33-A and P 33-B, which may either discharge to the Settling Basins if the redirect is in place or discharge to the storm sewer via Oil Interceptor
- 2, which has an oil storage tank capacity of 250 gallons.Normal discharge path is to the Settling Basin. Sump pump discharge flow to 01 may be approved by Chemistry (per DB-OP-06272, drainage line-up changes require Chemistry notification).
In the event the oil interceptor storage tank is overfilled, refer to Step 6.2.4.3 for further actions.b. In the event of a large rupture in the MFPT LO Tanks (1200 gallons each), or the MFPT Used LO Tank (2800 gallons), stopping Condenser Pit (West)Sump Pump 1-IA at MCC E32B (BE 3289) and for Sump Pump 1-1B, MCC F32B (BF 3289) will cause the following events to occur: 1) Oil level in the sump will reach a High level.2) High oil level will start the Condenser Pit Flood Pump P 174-1, which discharges to the settling basin. DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 26 of 57 6.3.8 Main Transformer Leak/Rupture (24,470 Gallons, Drawings C-78 through C-82)1. Symptoms Oil accumulation within the Main Transformer retaining structure and Transformer Collection Tank.2. Discussion In the event of a rupture in the ' Main Transformer, which contains 24,470 gallons of oil, the retaining structure will collect the leaking oil and drain into the Transformer Collection Tank, which has a capacity of 41,400 gallons. This will prevent oil from reaching any waterway.Station personnel should consider notifying TE Power Systems for possible reclaiming of oil from the Transformer Collection Tank.6.3.9 Auxiliary Transformer Leak/Rupture (4,600 Gallons, Drawings C-78 through C-82)1. Symptoms Oil accumulation within the Auxiliary Transformer retaining structure and Transformer Collection Tank.2. Discussion In the event of a rupture in the Auxiliary Transformer, which contains 4,600 gallons of oil, the retaining structure will collect the leaking oil and drain into the Transformer Collection Tank, which has a capacity of 41,400 gallons. This will prevent oil from reaching any waterway.Station personnel should consider notifying TE Power Systems for possible reclaiming of oil from the Transformer Collection Tank.6.3.10 Startup Transformer 01 Leak/Rupture (10,700 Gallons, Drawings C-78 through C-82)1. Symptoms Oil accumulation within the 01 Startup Transformer retaining structure and Transformer Collection Tank. S DAVIS-BESSE BUSINESS PRACTICE Number:__________________________________j DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 27 of 57 2. Discussion In the event of a rupture in the 01 Startup Transformer, which contains 10,700 gallons of oil, the retaining structure will collect the leaking oil and drain into the Transformer Collection Tank, which has a capacity of 41,400 gallons. This will prevent oil from reaching any waterway.Station personnel should consider notifying TE Power Systems for possible reclaiming of oil from the Transformer Collection Tank.6.3.11 Startup Transformer 02 Leak/Rupture (10,700 Gallons, Drawings C-78 through C-82)1. Symptoms Oil accumulation within the 02 Startup Transformer retaining structure.
- 2. Discussion In the event of a rupture in the 02 Startup Transformer, which contains 10,700 gallons of oil, the retaining structure will contain the leaking oil, preventing oil from reaching any waterway.
Station personnel should consider notifying TE Power Systems for possible reclaiming of oil from the Transformer Collection Tank.6.3.12 Bus Tie AC or BD Transformer Leak/Rupture (2,000 Gallons Each)1. Symptoms Oil accumulation within the affected Bus Tie Transformer Retaining Structure and Transformer Collection Tank.2. Discussion In the event of a rupture in the AC or BD Bus Tie Transformer, each of which contains 2,000 gallons of oil, the retaining structure will collect the leaking oil and drain into the Transformer Collection Tank, which has a capacity of 41,400 gallons. This will prevent oil from reaching any waterway. Station personnel should notify TE Power Systems for possible reclaiming of oil from the Transformer Collection Tank. DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 28 of 57 6.3.13 Spare Main Transformer (24,470 Gallons) and Spare Start-Up (16,865 Gallons)1. Symptoms Oil accumulation noted within the Spare Transformer retaining berm located outside of the Protected Area near Service Building 2.2. Discussion In the event of a rupture in either 'Spare' Transformer, an earthen berm retaining structure will collect the leaking oil. A rain run-off drain in the berm is able to be isolated with a temporary drain cover to prevent storm run-off of oil in the event of oil leakage, or during maintenance activities posing concerns for oil leakage.6.3.14 Electro-Hydraulic Control (EHC) System Leak or Tank T79 Leak/Failure (800 Gallon System, Plant System 93-01)1. Symptoms For a leak, perform a visual inspection.
- 2. Specific Actions a. Operations performs those actions required by alarm procedures.
- b. Identify and cover floor drains in the area of the spill.c. Dike and protect grating area near EHC Sump on 585 Level.d. Soak up spilled material with Absorbal, clay, sawdust, or fuller's earth.e. Flush spill area with detergent and water.3. Discussion The EHC system provides hydraulic fluid at sufficient pressure to operate the turbine valves; turbine stop and control valves, and combined intermediate valves. Because of the high temperature involved, normal hydraulic fluid would pose a fire hazard. To avoid this, the EHC system utilizes "Fyrquel EHC" as an operating medium. The EHC skid capacity is 800 gallons. Fyrquel -EHC has an open cup flash point of 4550 F and is a Tri-Aryl Phosphate Ester. The material is not corrosive to glass or metals, but will soften and deteriorate plastics and elastomers.
The product is not considered a hazardous waste and is not regulated by the EPA, however, hazardous by-products may be released when exposed to extremely high temperatures (i.e. steam). Wear S1 S DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 29 of 57 suitable protective clothing to prevent skin and eye contact. The floor drain in the vicinity of the EHC Skid flows to the West Condenser Pit Sump, ultimately draining to the South Settling Basin. The system is visually inspected through periodic walkdowns, and integrity tested under the Predictive Maintenance Program, PM 474 every 6 years. System level alarms are Annunciators 15-6-8 (3" from the top), 15-3-13 (24" from top), LSHH-2343 and LS2323.Reference OS-023-SH2. 6.3.15 Lubricating Oil Drum Storage Room (Room 337)1. Symptoms Oil accumulation within the Drum Storage Room.2. Specific Action Plug/patch or overpack the leaking container, if possible. The drain located in the room has been closed permanently, therefore, no actions are required to keep the oil away from the drain.3. Discussion A maximum of twenty-two (22) 55-gallon drums of oil can be stored on their sides in racks. Site glasses/tubes which can be used to determine drum contact level and an outlet are located at the bung openings. The room has a retaining curb located inside the door to prevent oil from spreading out of the room.6.3.16 Personal Shop Facility (PSF) 2000-Gallon Waste Oil Storage Tank Rupture 1. Symptoms a. Rapid lowering of tank level as indicated on Petrometer level indicator located on wall inside door 365B.b. Gradual lowering of tank level as indicated by inventory control methods.2. Specific Action a. Pump out waste oil remaining in tank.b. Excavate tank to determine condition and remedial action.3. Discussion Twenty-one floor drains throughout the PSF feed a gravity-fed cast iron oil interceptor located just inside and north of the roll-up door on the east wall of the PSF. Oil run-off from this oil interceptor goes to a 2000-gallon waste oil DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 30 of 57 storage tank located-just-outside the east wall of the PSF, online with the oil interceptor. The 2000-gallon tank is Underwriters Laboratories (UL) listed, constructed of Fiberglas, installed below-ground, and carries a 30 year warranty from the date of purchase (1987). Total failure is unlikely. See SSOE drawings M-1 550 and 1551 for SSOE project number 84816. Routine inspections of the level gauge have consistently indicated de minimus only amounts of oil accumulated in the tank. The tank has been deferred from registered UST status.6.3.17 Station Blackout Diesel Generator (SBODG) Fuel Storage Tank T210 Leak/Rupture (1977 Gallons, Drawing M-180-AN-8-2, Plant System 26-05, Service Building 6)1. Symptoms a. Rapid lowering of tank level as indicated by inventory or level indicator.
- b. Oil accumulation within containment dike.2. Discussion
- a. In the event of rupture of the 1977 gallon-tank, the retaining structure will contain the oil, preventing the oil from reaching any waterway.
If the oil does overflow, the oil would discharge to oil interceptor
- 7 which has an oil storage capacity of 100-159 gallons. (In the event the oil interceptor storage tank is overfilled, refer to Step 6.2.4.3 for further actions.)
Volume verified per Calculation
- CALC-ME-26.05-001.
NOTE 6.3.18 The containment vessel is not accessible during plant operation, therefore entry for inspection/verification purposes is not possible.6.3.18 Lubricating Oil Spill Within the Radiologically Restricted Area (RRA)1. Symptoms Oil accumulation on floor of containment or other locations within the Radiologically Restricted Areas (RRA), such as adjacent to reactor coolant pumps (RCP), oil drums, etc.S 0 0 DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 31 of 57 2. Specific Actions a. If abnormal conditions exist for the RRA, the appropriate abnormal operations procedures shall be initiated.
- b. For other oil leaks/spills within the RRA, contain with absorbent materials or booms.3. Discussion
- a. Each RCP has a lubricating oil reservoir consisting of two sumps, one upper (capacity 200 gallons) and one lower (capacity 25 gallons).RCP 1-1-1 (P36-1) and 1-1-2 (P36-2) oil drains into RCP Motor Oil Drain Tank 1-1-1 (T-156-1) (capacity 250 gallons).
RCP 1-2-1 (P36-3) and 1-2-2 (P36-4) oil drains into RCP Motor Oil Drain Tank 1-1-2 (T-156-2) (capacity 250 gallons). Both drain tanks are designed to completely contain both RCP oil reservoirs sumps and are equipped with a manual level indicator. The drain tank levels are checked when containment entry is possible.b. Various pumps and equipment located in the RRA may contain small amounts of lubricating oil. Any of this oil, if spilled, would accumulate in the area of the equipment or flow to a floor drain which is connected to the miscellaneous Liquid Radwaste System. ALARA precautions and RP procedures shall be followed in the RRA in addition to other stated cleanup methods of an oil spill.6.3.19 DBAB Emergency Diesel Generator (EDG) Day Tank Rupture (300 Gallons)1. Symptoms Oil accumulation within the Diesel Day Tank room or flow under building door to ground outside.2. Specific Actions a. Pump out the remaining diesel fuel to an appropriate storage container.
- b. Contain the oil using booms or other absorbent material.3. Discussion The DBAB EDG Day Tank (capacity 300 gallons) is constructed with an inlet/isolation valve (D-01) from the DBAB EDG Fuel Oil Storage Tank, an 8,000-gallon tank. The tank is equipped with a manual level gauge.
DAVIS-BESSE BUSINESS PRACTICE Number:____ ___ ___ ___ ___ ____ ___ ___ ___ ___ ___DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 32 of 57 6.3.20 DBAB Emergency Diesel Generator (EDG) Fuel Oil Storage Tank Rupture (8000 Gallons)1. Symptoms a. Loss of diesel fuel oil as indicated by manual tank gauge readings.b. Accumulation of oil on surface of Training Center Pond.2. Specific Actions a. Pump out the remaining diesel fuel to an appropriate storage container.
- b. Contain the oil using booms or other absorbent material.c. Notify contracted response organization for control, removal, and cleanup of discharge as appropriate.
- 3. Discussion The DBAB EDG Fuel Oil Storage Tank (Capacity 8,000 gallons) is an underground storage tank constructed of fiberglass reinforced plastic with no internal tank protection and piping is of bare steel (no cathodic protection).
This tank is registered as an Underground Storage Tank. Leakage is routed to site Training Center Pond that is able to be isolated. Temporary Transportation Load Pad is available for use during loading/offloading fuel.6.3.21 Fuel Tanks Located At Service Building 4 (Diesel is 1,000 Gallons and Gasoline is 2,000 Gallons)1. Symptoms Diesel fuel and/or gasoline has accumulated within the concrete dike surrounding the fuel tanks.2. Discussion The diesel fuel storage tank (capacity 1,000 gallons) and gasoline storage tank (capacity 2,000 gallons) are contained in a concrete retaining structure. This structure is designed to contain the total volume of both tanks plus an additional 15% capacity for precipitation and fire water. Periodically, the diked area/structure is checked and any accumulated liquid is removed to the appropriate waste drum or rain/storm water is inspected to ensure compliance of no oil sheen or other water quality nonconformance prior to supervised drainage. In the event the tanks are taken out of service, two 500 gallon temporary storage tanks with secondary containment may be staged. DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 33 of 57 NOTE 6.3.22 a. The Chemical Waste Storage Area (CWSA)is located outside of the Protected Area northeast of the Switch Yard.b. Chemical Waste Accumulation Areas (CWAAS) may be located at the following areas: 1) Self-contained storage building adjacent to the north Train Bay Door of the Turbine Building, within the Protected Area 2) Self contained storage/containment pad outside the Mechanical Shop (oil/refuse only).3) Self contained storage outside Service Building (SB) 6, SB 4, and the 100K and 40K DFOST storage tanks.6.3.22 Waste Diesel Fuel/oil in Containers in Chemical waste Storage Area (CWSA), Chemical Waste Accumulation Areas (CWAA), or Warehouse Storage 1. Symptoms a. Oil accumulating within the curbed, concrete pad, self-contained building, or floors of the CWSA, the CWAAS, or warehouse.
- b. Oil overflowing the curb or containment part of the building and accumulating on the gravel, stone, asphalt, grass, or other ground surfaces surrounding the CWSA or CWAAS.2. Specific Action a. Use any equipment available, such as absorbents, oil booms, and sand bags, to minimize the leak and contain the spill.b. Contact the Supervisor
-Nuclear Chemistry Services if any leaking or spilled diesel fuel/oil drums are found at the CWSA or CWAAS. DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 34 of 57 3. Discussion
- a. The station is equipped with retention areas and oil interceptors to contain any oil spills. The oil interceptors may be utilized in the event of a large oil spill or leak from 55-gallon drums at the CWAAS.b. Any oil leak or spill from 55-gallon drums at the CWSA is contained in the curbed concrete pad. Oil should be removed, thus preventing eventual accumulation to a volume that could enter the nearby drainage ditch which drains to the Training Center Pond.c. Any oil leak or spill in the warehouse storage from 55 gallon drums would be contained within the building.
Oil should be removed preventing accumulation or storage hazard using absorbents and/or booms.6.3.23 Equipment Containing Dielectric Fluid 1. Substations containing transformers are located through the plant. All transformers on site have been either retrofilled or replaced with non-PCB units. However, some large pumps, such as the Condensate Water Pumps, have been found to contain PCB capacitors. The exception are the four Circulating Water Pumps; which have been replaced with non-PCB capacitors, and the four Reactor Coolant Pumps; which are Non-PCB -dry pumps.Currently, it is unknown if the other pumps of this size or larger contain PCB capacitors. Therefore, it is prudent to assume the capacitors are PCB in a spill situation until determined otherwise. This equipment includes the following:
- a. Condensate Pumps 1-2 and 1-3 motor capacitors (pump 1-1 has been replaced with non-PCB capacitors)
- b. Service Water Pump motor capacitors
- c. Component Cooling Pump motor capacitors
- 2. Other equipment which may contain PCB oil includes Cyberex inverter capacitors, and overhead lighting capacitors.
Is it therefore prudent to also assume the oil from these and/or unknown sources are PCB in a spill situation until determined otherwise. Reference Environmental Compliance Guideline-ECG-07 for currently known PCB containing equipment and mitigation instructions. DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 35 of 57 6.3.24 Seal Oil Tank T100 Leak/Rupture (410 Gallons, Plant System 90-01, Room 333)1. Symptoms Oil accumulation in the Seal Oil Tank Room (Room 333/Turbine Building Level 585').2. Specific Actions a. Dike or cover floor drain in seal oil room.b. Pump out the remaining seal oil to an appropriate storage container.
- c. Contain the oil using booms or other absorbent material.3. Discussion The Hydrogen (H2) seal oil tank (TI00), has a capacity of 410 gallons. The room is designed so that in the event of a leak the retaining curb will contain small amounts of accumulated oil. The two floor drains are connected to the East Condenser Pit Sump The system is visually inspected by periodic plant walkdowns, and is tested under the Plant Maintenance Program, PM 429, performed during odd numbered Refueling Outages. Level alarms installed are annunciators 16-4-H and LSHL 2454 (ref OS-025).
DAVIS-BESSE BUSINESS PRACTICE Number:___________________________________ DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 36 of 57 7.0 RECORDS 7.1 The following quality assurance records are completed by this business practice and shall be listed on the Nuclear Records List, captured, and submitted to Nuclear Records Management in accordance with NG-NA-00106. 7.1.1 None 7.2 The following non-quality assurance records are completed by this business practice and may be captured and submitted to Nuclear Records Management, in accordance with NG-NA-00106. 7.2.1 None
8.0 REFERENCES
8.1 Developmental
8.1.1 29 CFR 1910.1200, Hazard Communication 8.1.2 40 CFR 112, Oil Pollution Program 8.1.3 40 CFR 280, Subpart F, Release Response and Corrective Action for UST Systems Containing Petroleum or Hazardous Substances 8.1.4 40 CFR Subchapter J (Parts 300-373), Superfund, Emergency Planning and Community Right to Know 8.1.5 49 CFR Subchapter C (Parts 171-178), Hazardous Materials Regulations 8.1.6 Ohio Revised Code, Chapter 1301:7-9, Underground Storage Tanks 8.1.7 NG-DB-00501, Environmental Compliance Program 8.2 Implementation 8.2.1 40 CFR 112, Oil Pollution Program 8.2.2 Ohio Administrative Code, Ohio Environmental Protection Agency (OEPA)Regulations Chapter 3750-25, Emergency Release Notification
8.2.3 DBNPS
National Pollutant Discharge Elimination System (NPDES) Permit 8.2.4 DB-CN-00030, National Pollutant Discharge Elimination System (NPDES)Program 8.2.5 DB-OP-06272, Station Drainage and Discharge System DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 37 of 57 8.2.6 NG-RA-00807, Regulatory Reports 8.2.7 NG-NS-00808, Regulatory Agency Communications 8.2.8 NG-NA-00106, Nuclear Records Management 8.2.9 RA-EP-02850, Hazardous Chemical and Oil Spills 8.2.10 DBNPS Emergency Plan 8.2.11 DBNPS Emergency Plan Telephone Directory 8.2.12 DBBP-CHEM-2003, RCRA Contingency Plan/Spill Notification Requirements 8.2.13 Environmental Compliance Guideline ECG-04, CERCLA/SARA Hazardous Chemical Locations and Spill Event Guideline. 8.2.14 Environmental Compliance Guideline ECG-07, PCB Activities and Response Plan. DAVIS-BESSE BUSINESS PRACTICE Number:___________________________________ DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 38 of 57 ATTACHMENT 1: DISCHARGE NOTIFICATION TABLE Page 1 of 1 DISCHARGE TYPE: PCB Oil Discharge (>50 ppm) Non-PCB Oil Discharge amount >25 gallons UST Release Oil Mixed with in "harmful off co. prop >25 gal. Haz. Subs., any amount into >1 lb. PCB quantities Discharge NOTIFICATIONS: Phone Number: a waterway on land into waterway > RQ Government Agencies: w/i 30 mins. w/i 30 mins* w/i 30 mins. w/i 30 mins. no w/i 30 mins*1. Ohio EPA Emerg. Response 1-800-282-9378 2, Sheriff Dispatch 1-419-734-4404 w/i 30 mins. w/i 30 mins* w/i 30 mins. w/i 30 mins. contact w/i 30 mins*(Satisfies Ottawa County Carroll Town-LEPC and Carroll Town- ship Fire ship Fire Department Dept. (419-notifications) 898-4906)w/in 24 hrs.3. National Response Center 1-800-424-8802 w/i 30 mins. w/i 30 mins* w/i 30 mins. w/i 30 mins. no w/i 30 mins*4. U.S. Coast Guard 419-418-6050 + no + no no +5. NWDO & OEPA (NPDES 1-800-282-9378 w/i 24 hr. if no w/i 24 hr. if no no w/i 24 hr. if permit violation) NPDES violation NPDES NPDES violation violation 6. State Fire Marshall 1-800-686-2878 no no no no w/i 24 hrs. no Company Contacts: 419-321-7283 + + + + + +7. Control Room 8. Env. Department 330-384-5160 denotes make the notification only if not entirely contained within some type of structure, (i.e., building, tank, dike, etc.) which prevents the possibility of migration from the site or exposure to personnel outside of the site boundaries. UST = Underground Storage Tank.The information that must be reported to all agencies is the time, source, and location of the release, material and volume released, the pathway of the release, health risks, precautions, name and phone number of person to contact for further information. PCB (or other hazardous constituent) concentration is obtained via analysis by a vendor laboratory. The pounds of hazardous substance spilled are calculated as follows: pounds spilled = (gallons spilled) x (concentration in ppm) x (d)1,000,000 (d) Reference the MSDS for the density factor of the material.Examples: 1. d = 8.4 lbs/gal for water or low conc materials 2. d = 13.5 lbs/gal for Aroclor 1260 (i.e., worst case PCBs)+ Courtesy call -not required.0 0 0 0 A m z--i!Y 0 I m X mU m~m m f MC- m Cl)C.l)r-zoz CD Ln.3 0 C CD 0 0 z m m z 0 z m 70 C'0 z Cln 0 0C Ci o H CD C)0 cz z-H m rn C Cf)0 Z-u 0 z 0 z C)0 CD 0 m C13 m U,)m-D m z C)UD CD C)0 ft 0 0-~ m> jZ MO 2, 0Z Z3 -c 8 303~~ ~ Z-_ 0 *6- -.1 o ADN 0131 LM01508 AOC BMA IC ID F FORD -7POND(0_37 Nt (ED CIO 1 01 DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 42 of 57 ATTACHMENT 5: DBNPS OIL LOCATION Page 1 of 1 DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 43 of 57 ATTACHMENT 6: CERTIFICATE OF THE APPLICABILITY OF NON-SUBSTANTIAL HARM CRITERIA Page 1 of 1 CERTIFICATION OF SUBSTANTIAL HARM DETERMINATION FORM FACILITY NAME: Davis-Besse Nuclear Power Station FACILITY ADDRESS: 5501 North State Route 2 Oak Harbor, Ohio 43449 1. Does the facility have a maximum capacity greater than or equal to 42,000 gallons and do the operations include over water transfers of oil to or from vessels?YES NO x 2. Does the facility have a maximum storage capacity greater than or equal to one million (1,000,000) gallons and is the facility without secondary containment for each aboveground storage area sufficiently large to contain the capacity of the largest aboveground storage tank within the storage area?YES NO X 3. Does the facility have a maximum storage capacity greater than or equal to one million (1,000,000) gallons and is the facility located at a distance such that a discharge from the facility could cause injury to an environmentally sensitive area?YES NO X 4. Does the facility have a maximum storage capacity greater than or equal to one million (1,000,000) gallons and is the facility located at a distance such that a discharge from the facility would shut down a public drinking water intake?YES NO X 5. Does the facility have a maximum storage capacity greater than or equal to one million (1,000,000) gallons and within the past 5 years, has the facility experienced a reportable spill in an amount greater than or equal to 10,000 gallons?YES NO x If an alternative formula is used, documentation of the reliability and analytical soundness of the alternative formula must be attached to this form.CERTIFICATION I certify under penalty of law that I have personally examined and am familiar with the information submitted in this document, and that based on my inquiry of those individuals responsible for obtaining this information, I believe that the submitted information is true, accurate, and complete.Professional Engineer Signature Title Charles T. Daft .PE Name Date DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 44 of 57 ATTACHMENT 7: RESPONSE EQUIPMENT / CONTRACTOR LIST Page 1 of 2 WAREHOUSE SPILL EQUIPMENT (WAREHOUSE LOADING DOCK SPILL KIT)* SHOVEL" NYLON ROPE" FIRST AID KIT" SPILL RESPONSE SUIT" RUBBER GLOVES* BOOTS" BAGS OIL DRY" ABSORBENT BOOMS, PILLOWS, PADS* DISPOSABLE BAGS FOR WASTE 0 WIRE TIES STOREROOM / TOOL CRIB* SORBENT MEDIA, BAGS OF ABSORBANT, PADS" WINTER GLOVES* ROPE" PAPER TOWELS SERVICE BUILDING 2" SPILL KIT REPLENISHMENT MATERIALS" SUITS" WATER BOOMS" LARGE CONTAINMENT POOLS DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page* SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 45 of 57 ATTACHMENT 7: RESPONSE EQUIPMENT / CONTRACTOR LIST Page 2 of 2 OFF SITE SUPPLIES / RESPONSE 1. Cousins Waste Control (Emergency Response -Vac Trucks), (419) 726-1500, or, for transportation related spill response call (800) 567-7455 2. Clean Harbors (Emergency Response), (800) 645-8265 3. New Pig Corporation (Spill Response Equipment), (800) 468-4647 4. Columbus Steel Drum Company (Containers -Drums), (614) 864-1900 OTHER KITS -INSIDE PROTECTED AREA Turbine Building* 585' Main HAZWOPER General Spill Kit (located against the South Wall)OUTSIDE PROTECTED AREA -Chemical and Oil Spill Kits Warehouse* 585' General Spill Kit, Z-Building
- 3 (General Spill)INCIDENTAL CLEAN-UP MATERIAL -SMALL KITS FOR GLOVES AND ABSORBANT PADS Turbine Building* 603' Oil Spill Kit outside Room 428* 623' Oil Spill Kit (located in the feedwater heater bay area)Auxiliary Building* 585' Oil Spill Kit -EDG Room 321 (Enter through Turbine Building)* 585' Oil Spill Kit (40,000 gal. Diesel Fuel Tanks) -located in SB2 vestibule DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision:
Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 46 of 57 CERTIFICATION OF THE SITE SPECIFIC SPCC PLAN ATTACHMENT 8: Page 1 of 1 Certification of the Site Specific SPCC Plan In accordance with 40 CFR 112.3(d) and 112.5(c), this plan has been certified as follows: CERTIFICATION SPILL PREVENTION CONTROL AND COUNTERMEASURE PLAN I hereby attest that 1 (1) am familiar with the provisions of 40 CFR, Part 112 (2) have examined or agent has examined the facility (3) am of the opinion that this SPCC Plan has been prepared in accordance with good engineering practices, including consideration of applicable industry standards and with the requirements of 40 CFR, Part 112 (4) am of the opinion that procedures for required inspections and testing have been established and (5) am of the opinion that the Plan is adequate for the facility.Charles T. Daft Printed Name of Licensed Professional Engineer (Seal)Signature of Licensed Professional Engineer Date: Registration No. State DAVIS-BESSE BUSINESS PRACTICE Number:____________________________________ DBBP-.CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 47 of 57 ATTACHMENT 9: SPCC COMPLETION OF REVIEW OF SITE SPCC PLAN Page 1 of 1 COMPLETION OF REVIEW 40 CFR 112.5(b)In accordance with 40 CFR 112.5(b), this plan has been reviewed as follows: I have completed review and evaluation of the Davis-Besse SPCC plan and will / will not amend the Plan as a result.K. N. Mominee Printed Name of Reviewer Signature of Reviewer Date: DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 48 of 57 ATTACHMENT 10: SPCC REVISION RECORD Page 1 of 1 REVIEW & REVISION RECORD SITE SPECIFIC SPCC PLAN FACILITY NAME:Davis-Besse Nuclear Power Station Review Date Revision Number Revised Reviewer's Name Pages/Section 12/20/2005 0 Entire Procedure K.N. Mominee 12/20/2005 3/15/2007 1 Pg 32 Sec 6.3.20.1.b. S. M. Chimo Pg 32 Sec 6.3.20.3 3/15/2007 Pg 48 Att. 10 0 0 DAVIS-BESSE BUSINESS PRACTICE Number:____ ___ ____ ___ ___ ____ ___ ___ ____ ___ ___DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 49 of 57 ATTACHMENT 11 -SPCC OIL STORAGE LOCATIONS COMPLIANCE TABLE Page 1 of 9 I SPCC OIL STORAGE LOCATIONS I COMPLIANCE OIL LOCATION MAP NUMBER 1-2-3-4-5-6-8-7-10-DIESEL FUEL OIL STORAGE TANK DIESEL FIRE PUMP DAY TANK EMG DIESEL GENERATOR DAY TANKS EMG DIESEL GENERATOR WEEK TANKS BUNKERED STEEL USTs MISC DIESEL DAY TANK TG LUB OIL STORAGE TANK MAIN/AUX/SU TRANSFORMER/BUS TIES MFPT LO and USED LO STORAGE TANKS LO DRUM STORAGE ROOM (TURB BLDG)11-12-13-14-15-16-17-9-18-PSF FIBERGLASS WO TANK STATION BLACKOUT DIESEL GENERATOR DBAB EMG DIESEL GENERATOR DAY TANK DBAB EDG FOST FIBERGLASS TANK SB4 DIESEL TANK and SB4 GASOLINE TANK CWSA WASTE OIL STORAGE TG SEAL OIL TANK TG EHC FLUID STORAGE TANK MISC OIL FILLED EQUIPIWAREHOUSE STRG DBBP.CHEM-2005 Description 6.3.1 6.3.2 6.3.3 6.3.4 6.3.5 6.3.6 6.3.8- 6.3.7 6.3.15 6.3.16 6.3.17 6.3.19 6.3.20 6.3.21 6.3.22 6.3.24 6.3.14 6.3.23 Step 6.3.13 System Number 26-01 26-03 26402 26-02 99-06 89-01 87-1,3 36-04 25-01 25-01 26-05 25-01 25-01 19-01 NA 90-01 93-01 20-03 Tank Number (if Applicable) T45 T47 T46 T153 T168 T32 3-1-3 __T _ T210 T100 T79 Oil Location Map Number 1 2 3 4 5 6 8 7 10 11 12 13 14 15 16 17 9 18 b, Facility Drainage -Requirements in accordance with 40 CFR 112.8 (b) I Capacity of Container in Gallons 100K 350 6K 40K 740 14 K 24470 1200 55 gal 2000 1977 300 8000 1000 55 gal 410 800 RCP-Each Each Each 107004 (1&2) Drum 2000 Drum 225 (2) (2) (2) 600 2800 Tranf-2000 * (LO) Varies (1) Is the Storage area diked ? YES NO NO NO NO NO YES' NO NO NO YES NO NO YES NO NO NO NO 115K RC STP UST RC Sump only Part STP Demin Conlin Conlin 3450 RC STP STP Sump Sump Plan Plan Curb a. IF DIKED, are valves present to prevent No NA NA NA NA NA *No NA NA NA No NA NA YES NA NA NA NA discharge into drainage Valve Valve Valve system No J Drain b. Manual Pumps or Ejectors to Drain YES NA NA NA NA NA YES
- NA NA NA YES NA NA NO NA NA NA NA c. Visual Exam Required Before Discharge or YES F NA NA NA NA NA YES F NA NA NA YES F NA NA YES NA NA NA NA Disposal _ _ .
DAVIS-BESSE BUSINESS PRACTICE Number:____ ___ ____ ___ ____ ___ ____ ___ ____ ___DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 50 of 57 ATTACHMENT 11 -SPCC OIL STORAGE LOCATIONS COMPLIANCE TABLE Page 2 of 9 Oil Location Map Number 1 2 3 4 1 5 6 8 7 10 1 1 12 13 14 15 16 17 6 9 18 (2) Drain Valves for Dikes a. Manual Open and NA NA NA NA NA NA NA NA NA NA YES NA NA. YES NA NA NA NA Close Only ? " ___-__... ..__ __-._____ .._._..:__-_
- b. Flapper Valves ? "NA'(Not Allowed) NO NA NA NA NA NA NO NA NA NA NO NA NA NO NA NA NA c. To prevent harmful discharges, is drained NA NA NA NA NA NA NA NA :NA. NA NA- NA NA,: YES NA NA NA NA uncontaminated Dike Storm or Rainwater
-Inspected. Supervisd, Adequately Recorded &Valves Closed _._" ___ *_:.. ____(3)a. Are UNDIKED areas (with a potential for discharge-Piping off containment, walls or truck discharge YES YES- YES YES- NA NA- YES- YES- YES NA- YES- NO- NO- NA- NA NA NA' NA areas off pad.etc) designed Pad Vault STP Bitum Vault Vault Collcn Vault -STP De-min RC 01 Encls Fibergl Pipng RC RC Encls Encls to flow into Ponds/CB/ CB31/ RC- 015 Coatd Full Full Tank 012 01/2 UST -7 TCP Room UST -Encls ALL No ,SCP Roorir Room Lagoons/designed to retain or#4 STP TCP CB17 Cont- Cont- for all TCP I SSB Piping Bare in dike Drain SSB WCP, Tanks the oil? TCP O1#3 TCP No No WCP Wrap Piping SS.: S STP Piping TCP Piping Drains Drains SSB CB CB .TCP Cathd (DO Cathd Pipg Piping Pond Pond Cath) Cath Encls 19 19 b. Drainage System CBs in NO NO NO NO NA NA NO NO NO NA NO No No NO NO NO NO NO a Flood Plain ?(4) Final Discharge of facility ditches has diversion YES YES YES YES NA NA YES YES YES NA YES YES- YES- NA F YES YES YES system to retain oil in the TCP TCP TCP TCP TCP TCP I TCP/ TCP Gated Gated SSB SSB TCP facility I C II _Ionly SSB SSB I Pond Pond (5) Is drainage system engineered to prevent a YES YES YES YES- YES YES YES YES YES NO YES YES YES YES NA YES YES YES'harmful discharge' ? C E E 0 0 DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 51 of 57 ATTACHMENT 11 -SPCC OIL STORAGE LOCATIONS COMPLIANCE TABLE Page 3 of 9 Oil Location Map Number 1 1 2 1 3 I 4 I 5 1 6 I 8 I 7 1 10 I 11 I 12 1 13 I 14 I 15 I 16 I 17 I 9 1 18 c. Bulk Storage Requirements in arcordance with 40 CFR 112.8 (c)(1)Oil Storage Container Material and Conditions Compatible YES YES to Contents YES YES YES YES YES YES YES YES YES NA YES YES YES YES YES YES (2) REQUIRED Secondary Containment
- a. Entire capacity and freeboard impervious to NO NA contain discharged oils YES- NO NO NO YES- YES- YES- NO NO NA NO NO NO YES YES NO Dike Vault Vault Tanks I b. Alternate System (Drainage Trench enclosure)
YES -YES YES YES NA NA YES YES- YES NA YES- YES YES- NA .NA .YES-arranged so discharges Piping RC and RC CB17 TCP STP STP RC CB CB .RC terminate/are confined in a CB 31 01 #3 STP To only TCP/ TCP/ 017 POND POND STP catch-basin or holding pond TCP TCP O1#5 TCP WCP WCP TCP 19 19 , ECP STP NA TCP SSB SSB SSB WCP SSB (3) Diked Drainage to Storm drain: Valves NC. Water Quality Pre-inspected, NA NA NA NA NA NA YES NA NA NA No NA NA YES NA A :NA NA Drainage Supervised & Valve Recorded _ _ .____'_,_ :___.___(4) Buried Metallic Tank (Install post1974)) NA NA' NA NA NA NA :NA NA NA NA NA. NA NA NA NA NA NA a. Coatings/Cathodic ___.. ..._ ..... ... _ __, b, Regular Pressure Testing NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA (5)Partially Buried or Bunkered Tanks are Coated or NA NA NA YES NA NA NA NA NA NA NA NA NA NA NA NA NA NA Cathodic Protected Coat&compatible with local soil Cathd conditions (6) a. Containers Regularly Integrity Tested, and when repaired by Visual and one other method, such as Hydrostatic, Radiographic, G G G G G G G M NA M, G G NA M M PM NA NA Ultrasonic Acoustical, or No PM NA No PM NA Flbergl Raised Flberg9 NA NA. 429 Equip Equc other NDE Elec Raised No Oil Rack/ UST Raised DOT Odd Equip Equip Equip Racks/ Stored Full Racksl Regs RFO PM 474 DOT View Full 6 yrs Regs a I I View I I I I DAVIS-BESSE BUSINESS PRACTICE Number:____ ___ ___ ___ ___ ____ ___ ___ ___ ___ ___DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 52 of 57 ATTACHMENT 11 -SPCC OIL STORAGE LOCATIONS COMPLIANCE TABLE Page 4 of 9 Oil Location Map Number 1 [ 2 3 4 5 6 8 7 10 i11 12 [ 13 [ 14 15 16 [ 17 9 18 b. Comparison Records Are REQUIRED tobe YES I YES I YES I YES I NA YES I YES No NA NA YES I YES I YES I YES I NA YES I YES I NA Maintained only .._:__c. Inspect Containers Supports & Foundations G G G G G YES YES No NA NA G G NA M NA YES YES NA Period on*..Period Period Walk Walk Walk Down _ _ __*____ Down Down d, Frequently Inspect containereotenior for G G G G G YES YES No NA NA G G NA; M NA YES YES NA deterioration, discharges or Period G Period Period accumulation inside dike Walk Pony Walk Walki areas, Down
- Down Down e. Inspection Records Maintained for 3 years YES I YES I YES I YES I YES I YES I YES I No NA NA YES I YES I YES I YES I YES I YES I YES I INA Ionly I_.__(8) Good Engineering Practices to avoid discharges by at least one of the following (Engineered or update YES NA containers to satisfy) YES YES G YES G YES YES YES- NO No NA NA YES YES YES YES NA YES Annun a. High Level Alarms w/ Period Comp *only Annun 15-6-B audible, or visual signal if Walk Point 16-4-14 and constantly monitored Down 9-6-D 15-3-B b. High Liq Levi pump cut-off device to stop flow at predetermined container level No No No NA No No NA NA NA NA No NA G NA NA NA c. Direct audible or code signal between container guager and pumping station No No No YES No Annun NA NA NA NA No NA G NA NA NA NA NA S 0 DAVIS-BESSE BUSINESS PRACTICE Number:DBBP-CHEM_2005 Title: Revision:
Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 53 of 57 ATTACHMENT 11 -SPCC OIL STORAGE LOCATIONS COMPLIANCE TABLE Page 5 of 9 Oil Location Map Number [ 1 ] 2 3 4 5 [ 6 8 7 I10 11 12 13 J 14 1 15 16 17 9 18 d. Fast Response System to determine Liq Lvl of YES Yes G YES NA Annun NA No NA NA YES G YES YES INA Annun Yes NA each contnr (computers, and 1 6-4-H telepulse, direct vision Comp gauge) Requires a person Point I LSHH-monitor gauges and filling LSH- 2343 1165 LS-_2323 e. Regularly Tested liquid G YES G G G PM- NA No NA NA G G G M NA , LSHL PM NA level sensing devices 1544 " 2454 8 LSH- .PM 1250 3437 (9)Effluents Systems are Checked Frequently to detect system YES YES YES YES NA NA YES YES YES NA YES NA NA NA YES YES YES YES upsets causing a harmful TCP TCP TCP TCP No No TCP* SSB SSB No TCP No No No TCP SSB SSB TCP discharge (NPDES) STP STP Coll'n STP STP STP STP SSB Dischr Dischr Tanks Discr Dischr Dischr Dischr (10) Visible discharges which result in any loss of oil in YES B YES B YES B YES B YES B YES YES B YES NA NA YES B YES B YES YES B YES B YES B YES YES containers are Promptly B B B B B Corrected, including prompt removal of oil from dikes _: ._.d. Transfer Operations Requirements in accordance with 40 CFR 112.8 (d_(1) Buried Piping: a. All new or replaced piping is Protectively Wrapped YES YES NA YES YES NA NA NA NA NA NA YES YES NA NA- NA NA NA or Coated and provide Cathodic or other corrosion Protection
- b. Buried Piping is Examined for Deterioration if Exposed AND implement H H YES NA H H NA NA NA NA NA NA H H NA NA NA NA NA corrective actions YES YES YES YES YES indicated by the magnitude of the corrosion.
DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 54 of 57 ATTACHMENT 11 -SPCC OIL STORAGE LOCATIONS COMPLIANCE TABLE Page 6 of 9 Oil Location Map Number J 1 2 3 4 5 6 8 7 I 10 11 I 12 1 13 14 15 16 17 9 18 (2) Cap or blind flange Terminal Connection YES NA NA YES NA NA NA NA NA NA YES NA YES YES NA NA NA " NA b. Marked Origin when not in service YES NA NA YES NA NA NA NA INA NA YES NA YES YES NA NA :NA NA (3)Pipe Supports are designed to minimize abrasion and G G G G G NA NO No NA NA G NA NA NA NA NA NA NA corrosion and allow for expansion and contraction _____ : .."__-_. " (4) Regularly inspect and assess all above ground Valves, Piping & Appurtenances:
- a. Flange Joints, Period Period Expansion Joints Supr Supr Valve Glands Valve Bodies G G G G G Period NA No NA NA G G NA M NA Walk Walk NA Catch Pans Supr Dowm Dowm Pipeline Supports Walk Locking of Valves Dowm Metal Surfaces 2. Regular Integrity and leak testing of buried piping, at G G G G G NA NA NA NA NA- NA NA G NA NA NA %NA NA installation,-Demin modifications/construction , relocation, or replacement if drainage could lead to a Harmful Discharge
_______.... (5) Provide vehicle warnings for Aboveground Piping YES D YES NA YES D YES D NA NA NA .NA NA YES YES 0 YES D YES NA NA NA NA Protection I 0 DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2005 Title: SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN Revision: Page 01 55 of 57 ATTACHMENT 11 -SPCC OIL STORAGE LOCATIONS COMPLIANCE TABLE Page 7 of 9 Oil Location Map Number I 1 I 2 I 3 I 4 I 5 I 6 I 8 I 7 I 10 I 11 I 12 I 13 I 14 I 15 I 16 I 17 I 9 1 18 e. Additional Facility Tank Car and Tank Truck Loading and Unloadinl Rack (Requirements in accordance with 40 CFR 112.7 (h))(1) Where Loading / Unloading Drainage does not does not K -NA NA Temp NA NA NA NA NA NA K- NA K- NA NA NA NA NA flow into catch-basin or Load Load treatment facility designed Pad Pad LPad LPad unloaded Ref Ref Pad Ref Ref 112.7 112.7 * : ":112.7 ." 112.7" .i ( *.(c) .* _ _ c) (c) _ .. .* : :, : (2) Mechanisms (Interlocked u a shall a t sh warning light or physical 0 N A 0 N A N A N A 0 N A -N A N barrier system, wheel to fA fully chocks, or vehicle break f full interfock system) in Place to i. : 1'=: .Prevent Departure prior to Disconnect of lines ._"_:_ " "_ _*(3)Prior to filling or departure lowpermstoteles warheclsel D NA NA D NA NA NA NA NA NA D NA D D NA .NA NA NA inocspete for deischargesand orterepksytm) laced topren ensure tightened, adjusted,- onstruplcted aboprve 9ont dischargesr rpa dint transit.prv n :: " ;/ ; i"I:'f. New "Brittle Fracture" Failure Evaluation Requirements (Field Constructed Containers greater than W" thick) per 40 CFR 112.7 (j)Evaluate Container and G G G G G G NA " G N NA G GA NA NA .I GNA N take appropriate action for G.....G N A A G GNA N NA A N discharge/failure when field-constructed above ground .containers are repaired, altered, reconstructed, or service changed as to affect the risk of a discharge due to brittle fracture failure or catastrophe. DAVIS-BESSE BUSINESS PRACTICE Number: Title: Revision: Pag SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 56 of 57 ATTACHMENT 11 -SPCC OIL STORAGE LOCATIONS COMPLIANCE TABLE Page 8 of 9 Oil Location Map Number 1 I 2 I 3 I 4 I 5 1 6 I 8 7 1 10 1 11 1 12 1 13 1 14 I 15 I 16 17 I 9 1 18 g. Additional Security Requirements per 40 CFR 112.7 (a)(1) Storage Area is Fully Fenced wand Locked or Guarded YES YES YES YES YES YES YES YES YES YES YES YES NO D YES YES YES YES YES when Unattended (2) Master Tanks Flow and Drain Valves (which could allow flow to Surface) are Locked and NC not operating. YES YES YES YES YES NA YES NA : NA NA YES YES NA YES NA NA NA NA.(3) Starter Control for oil Pumps are locked and I only YES YES YES YES YES YES NA NO- NA NA YES YES YES YES NA ,NA NA NA Accessible to Authorized Flood Personnel Pump 174-1 " (4) Loading/Unloading Connectors of Pipelines are YES NA NA YES NA NA NA NA NA YES YES .NA YES YES NA .N NA NA either Capped or Flanged when not in use or on standby, including emptied pipelines........ '____ _.._-(5) Adequate Lighting is Available for: 1. Discovery of Spills in the YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES Dark I I I 1 1 2. Vandalism Deterrence YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES 0 0 DAVIS-BESSE BUSINESS PRACTICE Number:____ ___ ___ ____ ___ ___ ___ ____ ___ ___ ___DBBP-CHEM-2005 Title: Revision: Page SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 01 57 of 57 ATTACHMENT 11 -SPCC OIL STORAGE LOCATIONS COMPLIANCE TABLE Page 9 of 9 LEGENDS A. Due to storage of oil drums only, and discharge controls through station process drains, this is N/A.B. HAZWOPER Incident Commander and Technician level. Personnel receive training on applicable regulations and spill critiques in accordance with RA-EP-02850. HAZWOPER Awareness training for oil spills is provided site-wide in Hazard Communications Training. The Corrective Action Process may also be used for spill reporting. Spills may also be identified by housekeeping practices, and routine plant walk-downs. C. Although a drain system is not employed, the clay soils around the tank or catch basin, and flow or requirements to discharge via pumps or storm line to onsite ponds, ensure any spilled material does not enter navigable waters or natural resources as a harmful discharge. Regulatory Notifications may still be required however (example: UST overfill)D. Procedure checklists or signs are employed to ensure applicable containment, outlets and disconnects are checked, DOT regulations are employed, and Security maintains vehicle control at all times.E. The room contains the total contents.F. Oil drainage is to drums and records are maintained as disposal records for oil disposal (i.e. drum receipt at the CWSA).G. Engineering maintains testing documentation, or maintained in PM Program or Work Order documents. Each AST or container identified with this code shall be annotated with the description and frequency of the integrity testing requirements, or applicable industry standard citation or environmental equivalency documentation by the next five year review interval from the original regulatory 5-year review implementation date of August 18, 2006 (no later than August 18, 2011).H. Back-fill procedure requires inspections if excavated. I. Inspections are maintained with environmental files, Work Orders, or site records, Procedures and training records (i.e. cleanliness & housekeeping, HAZWOPER, PM inspections, excavations, operations walk-downs, etc.) are maintained in accordance with terms of the DBNPS Operating License and commitments (i.e. USAR, NQAM, etc)J. The Spare Main Transformer has an earthen dike to contain discharge. The equipment is not operating, but in stand-by.K. Periodic Plan or System Review requires initiation of a Condition Report for tracking or implementing system evaluations and/or upgrades.L. Review requires initiation of a Condition Report for tracking or implementing system evaluations and/or upgrades.M. Environmentally Equivalent method: Elevated drums or shop built containers (shell capacity less than 30.000 gallons), with frequent visual inspection, container does not come in contact with soil and is elevated so all sides are visible during inspection, or is placed on a barrier (such as a synthetic liner) between the container and the ground.UNK- UNKNOWN NA -NOT APPLICABLE STP -STATION PROCESS DRAIN WCP -WEST CONDENSER PIT CB- CATCH BASIN RC -RETAINING CURB TCP -TRAINING CENTER POND o0 -OIL INTERCEPTOR DEMIN- DEMINIMUS / NO OIL STORED SSB -SOUTH SETTLING BASIN UST- UNDERGROUND STORAGE TANK "I NOP-LP-2001-O1 Site: G201 CONDTIO REPRT R Number CONDIION RPORT04-01719 TITLE. IN 2004-05 SPENT FUEL POOL LEAKAGE TO ONSITE GROUNDWATER DISCOVERY DATE I TIME I EVENT DATE TIME SYSTEM I ASSET#31512004 N/A n/a N/A N/A N/A EQUIPMENT DESCRIPTION N/A System IFLOC JAP-913: DESCRIPTION OF CONDITION and PROBABLE CAUSE (if known) Summarize any attachments. Identify what, when, O where, why, how.R The U.S. Nuclear Regulatory Commission (NRC) is issuing this information notice to inform! addressees of the recent identification of a longstanding leak to onsite groundwater from the spent G 'fuel pool of an operating pressurized water reactor facility. It is expected that recipients will review the information for applicability to their facilities and consider actions, as appropriate, to avoid similar N problems.A This Condition Report will evaluate IN 2004-05 for similar concerns at Davis-Besse T IMMEDIATE ACTIONS TAKEN I SUPV COMMENTS (Discuss CORRECTIVE ACTIONS completed, basis for closure.)O Evaluate per NG-NA-00305 Attachment 4 N QUALITY ORGANIZATION USE ONLY IDENTIFIED BY (Check one) El Self-Revealed ATTACHMENTS EV Individual/Work Group El Internal Oversight Quality Org. Finding LI Yes EL Supervision/Management [] External Oversight EI Yes [] No ORIGINATOR ORGANIZATION IDATE ISUPERVISOR DATE PHONE EXT.SADLIER, D P1 315/2004 HENNESSY, B 3/5/2004 8592 SRO EQUIPMENT EP EQUIP OPERABILITY ORG. IMMED ORG. MODE CHANGE p REVIEW OPERABLE ASSESSMENT NOTIFIED INVEST NOTIFIED RESTRAINT REQUIRED REQUIRED L ETYes }No [EYes EllNo E]NW E-Yes E]No [-Yes I No N/A I EYes E] No N/A [E Yes No A MODE ASSOCIATED TECH SPEC NUMBER(S) ASSOCIATED LCO ACTION STATEMENT(S) N pA ;INI T #0 DECLARED INOPERABLE REPORTABLE? One Hour N/A APPLICABLE UNIT(S)P (Date / Time) ,.-es Hour No -IA aN/A e EIght Hour N/A W-ui EL U2 [: Both R El Eval Required Other -N/,A A T COMMENTS I N/A 0 N Current Mode -Unit I Power Level -Unit I Current Mode -Unit 2 Power LevelN- Unit 2 S N/A N/A NA N/A SRO -UNIT I SRO -UNIT 2 DATE Approved By Supv NIA 3/5/2004 Page 1 of 2 NOP-LP-2001-01 Site: G201 CONDITION REPORT CR Number 1 04-01719 TITLE: IN 2004-05 SPENT FUEL POOL LEAKAGE TO ONSITE GROUNDWATER CATEGORY! EVAL ASSIGNED ORGANIZATION DUE DATE R REPORTABLE? NF PES 514/2004 E El Yes E1 No El LER No.G CRPA TREND CODES Comp Type i ID Cause u REPORTABILITY REVIEWER I Process I ActivityI Cause Code(s) (if Cause T or W) Org A Wolf, G T SUPV LP2 3450 NA NONE o DATE I R MRB Y 03/09/04 INVESTIGATION OPTIONS CLOSED BY DATE El [EOE Evaluation [] Genedc implications LI Part 21 11/13/2004 Page 2 of 2 .2f1 CORRECTIVE ACTION CR Number: NOP-LP-2001-05 04-01719 CR Category: Action Type: Schedule Type: CA Number: NF ( ) I (A) Owner Assigned/Controlled 1 Corrective Action Type: Cause Code: Resp Org: ( ES ) Evaluation Support (NA) Not a Deficiency DBRC R
Description:
I Obtain approval of the completed (i.e., CARB approved) evaluation by the Senior Leadership Team.G I N A T 0 R Completed By: Organization: Date: Phone: Attachments: SADLIER, D PI 3/10/2004 7541 EV Yes [I No If a Refueling Outage Is required, Other Tracking # Corrective Action Due Date: ACC- Enter the Refueling Outage number: N/A N/A 3/31/2006 EPT Approval: (Enter Name and Sign) Section: Date: MCALLiSTER, A DBRC 4/23/2004 QUAL Quality Organization Approval: Date:-ITY I Response: (i) Completed as written 0 Revised/Alternate Solution 0 Not Performed M The Site Management Team (previously known as the Senior Leadership Team), approved the P completed evaluation with comments. In attendance were, B. Boles, S. Loehlein, M. Bezilla, R.L Schrauder, R. Hruby, M. Stevens, M. Murtha and C. Hengge. The comment did not require E incorporation into the evaluation. As a result, no follow-up Condition Report is required (See Step M 6.5.6 of NG-NA-00305). See attached agenda.E Alternate Corrective Action or Justification if Corrective Action not performed: N T I N G Corrective Action Implementation Date: 11/9/2004 j Signature indicates Corrective Action complete: 0 Completed By: JOHNSON, J Date: 11/9/2004 R j Signature indicates verification for SCAQ CRs: G Verified By: Date: j Enter Name and Sign: Implementing Organization Approval: HENNESSY, B Date: 1119/2004 Q v Comments: U E A R L I I F T I Y E R Approval: Date: Page 1 of 3 -qifo- ngni CORRECTIVE ACTION CR Number: NOP-LP-2001-05 04-01719 CR Category: Action Type: Schedule Type: CA Number: NF ( ) I (A) Owner Assigned/Controlled 2 Corrective Action Type: Cause Code: Resp Org: ( ES ) Evaluation Support (NA) Note Deficiency PI R
Description:
I After review by the Corrective Action Review Board (CARB), notify the Regulatory Commitment G Tracking System (RCTS) Administrator that the CR is completed N A T 0 R Completed By: Organization: Date: Phone: Attachments: SADLIER, 0 P1 3110/2004 7541 W] Yes El No If a Refueling Outage Is required, Other Tracking # Corrective Action Due Date: ACC- Enter the Refueling Outage number; N/A N/A 7/16/2004 EPT Approval: (Enter Name and Sign) Section: Date: HENNESSY, B P1 4/1912004 QUAL Quality Organization Approval: Date:-ITY I Response: (ýD Completed as written 0 Revised/Alternate Solution 0 Not Performed M The Corrective Action Review Board reviewed and approved the evaluation to this CR on June 8, P 2004. Following that date, R. Slyker, the Regulatory Commitment Tracking System Administrator, L was notified via email that the CR is complete.E M E Alternate Corrective Action or Justification if Corrective Action not performed: N T N Corrective Action Implementation Date; 6/2112004 G j Signature indicates Corrective Action complete: o Completed By: JOHNSON, J Date: 6/21/2004 R j Signature indicates verification for SCAQ CRs: G Verified By: Date: j- Enter Name and Sign: Implementing Organization Approval: HENNESSY, B Date: 6/21/2004 Q v Comments: U E A R L I I F T I Y E R Approval: Date: Page 2 of 3 Sitea G201 CORRECTIVE ACTION CR Number: NOP-LP-2001-05 04-01719 CR Category: Action Type: Schedule Type: CA Number: NF ( ) (A) Owner Assigned/Controlled 3 Corrective Action Type: Cause Code: Resp Org: ( ES ) Evaluation Support (NA) Not a Deficiency DBPE R
Description:
I Create an activity (PM) to implement the Site Management Team suggestion to periodically sample G the groundwater from the well nearest the Spent Fuel Pool for tritium concentration. I N A T 0 R Completed By: Organization: Date: Phone: Attachments: HENGGE, C DBPE 11/11/2004 7898 El Yes R No If a Refueling Outage is required, Other Tracking # Corrective Action Due Date: ACC- Enter the Refueling Outage number: N/A N/A 6/30/2005 EPT Approval: (Enter Name and Sign) Section: Date: HENGGE, C DBPE 11/11/2004 QUAL Quality Organization Approval: Date:.ITY I Response: Completed as written 0 Revised/Alternate Solution 0 Not Performed M DB-REV-05-0778 has been created to add a PM activity to periodically sample the groundwater P from the well nearest the Spent Fuel Pool for tritium concentration. L E M E Alternate Corrective Action or Justification if Corrective Action not performed: N T I N Corrective Action Implementation Date: 6/1612005 G.--J Signature indicates Corrective Action complete: 0 Completed By: HENGGE, C Date: 6116/2005 R 1 Signature Indicates verification for SCAQ CRs: G Verified By: Date: j Enter Name and Sign: Implementing Organization Approval: MARLEY, J Date: 6/16/2005 Q V Comments: U E AR L I I F T I Y E R Approval: Date: Page 3 of 3 Site: G201 INVESTIGATION
SUMMARY
CR Number: 04-01719 NOP-LP-2001-06 Category / Eval: NF Assigned Organization: PES Quality Finding: El Yes OV No For Fix irvestigations Only: --JHardware/IDegraded Condition Resolution Required? Ys No If Yes: ld*Repir UýiScrap S. IdRework U Use-As-Is.J Acceptance of the CR Investigation signifies acceptance of the following items, as applicable: Originator Identification Date Corrective Actions ( listed below) (listed below, if any) (listed below, if any)Cause Analysis Generic Implications 10 CFR 21 Decision Checklist Acceptance of Investigation: Date: Quality Approval: Date: MCALLISTER, A 4/23/2004 Site-VP Acceptance: Date: Closure Comments: Problem Statement: The U.S. Nuclear Regulatory Commission (NRC) is issuing Information Notice (IN) 2004-05 to Inform addressees of the recent identification of a longstanding leak to onsite groundwater from the spent fuel pool of an operating pressurized water reactor facility.Undetected leakage of radionuclides outside the facility could have potential health and safety consequences to workers and ultimately the public.Scope: The 5' thick south wall of the Spent Fuel Pool and Cask Pit which forms a portion of the outside wall of the Auxiliary Building.Evaluation: This IN describes the same incident that was described in INPO Operating Experience (OE) 15788. This OE resulted in CR 03-2360 being generated to evaluate the OE for Davis-Besse. OE 15788 described the condition at Salem where the leakage detected by their Spent Fuel Pool (SFP)leak detection system gradually diminished to zero over time. Salem uses a system of tell-tale drains similar to that used at Davis-Besse. After workers got contaminated on their shoes, investigation found a"calcium like substance" adhering to the wall of the room adjoining the Spent Fuel Pool. It was discovered that the leak detection system had plugged with boron over time and caused the water to accumulate until it migrated to other locations. Procedure DB-SP-04400, Spent Fuel Pool, Fuel Transfer Pit, and Cask Pit Leak Detection System Test, is performed monthly to quantify a leak rate from the 21 leak chases for those three pools/pit. Review of the results of the leak detection testing is performed by the SFP system engineer. Leakage outside the leak chase drains has been seen in several places over the years (ref. CR 02-01364, 01-02309 and 01-00253). The most extensive visible evidence of leakage was on the wall and ceiling of #1 ECCS Pump Room, Rm. 105 during the period 2000-2001 (note: this leakage has since been stopped and the area cleaned). The ceiling in this room is at 563' elev. which is the approximate level of the bottom of the pool (563.5'). Based on the evaluations associated with this past leak and the work done as part of the Containment Health there are no concerns regarding the strength or integrity of the concrete structure associated with these leaks.During the reracking of the SFP during Cycle 13, underwater divers used a vacuum box of the weld seams in the SFP to determine if there was any detectable leaks. None could be located.At the time that there was the very visible leakage in the #1 ECCS Pump Room, little leakage was being Page 1 of 3 Site: G201 INVESTIGATION
SUMMARY
CR Number: NOP-LP-2001-06 04-01719 seen in the leak chases. WO 00-5281 -00 was used to open/ verify open the 21 leak chase valves and piping in Feb 2001. Six of the chases were found to be totally blocked. A significant amount of trapped fluid was found in several of the blocked leak chases. As part of this the normal position of the leak chase valves was changed from OPEN to CLOSED. This should reduce the likelihood of the boric acid to solidify and block the valves and piping. To be certain this has not occurred again, an order to open/verify open the valves and piping has been initiated as CA 1 for CR 03-02360.While the zones with significant fluid were not the zones that cover the walls adjacent to the exterior (i.e.southern ends of the SFP or Cask Pit (CP)), several of these zones were shown to be blocked and these zones do show leakage during the monthly test. Based on this it is prudent to verify the soil does not show contamination which would be indicative of past and/or present leakage. This is being done by CA 2 to CR 03-02360.The 5' thick south wall of the SFP and CP form the outside wall of the Auxiliary Building. Much of the flooded portion of the SFP and CP are below grade and not visible. There Is a waterproof membrane on this outside wall (ref. DWG C-230 Section C) to keep outside groundwater from leaching into the Auxiliary Building. This membrane would also likely act to keep any potential fuel pool leakage from escaping into the soil.Thus while It Is unlikely that there would be leakage into the soil, without a some type of excavation or soil borings to gain access to the soil in this area it can not be conclusively determined that there has or has not been leakage.Should leakage be detected a further CR will be generated in accordance with, and required by, procedure NG-DB-00244, Radioactive Material Control Program, section 6.2.10. This section deals with contamination in and around the facility to ensure that the requirements of 1 OCFR50.75(g) are met.Contacts: None Source Information: IN 2004-05 CR 03-02360 DB-SP-04400, Spent Fuel Pool, Fuel Transfer Pit, and Cask Pit Leak Detection System Test Various site drawings including: C-230 and C-211 Most Probable Cause: This is an information notice and thus there is no most probable cause.Preventative/Corrective Action: No specific corrective actions are required by this CR as the corrective actions specified in CR 03-02360 adequately address the Issue.A copy of those are provided below.1. Implement Order 200057114 to verify the SFP, Cask Pit and Fuel Transfer Pit leak collection isolation valves, SF99A through SF99U (located on the 545' elev. of Aux Bid) are not clogged with boric acid. If necessary clean and/or replace the valves.2. PES to develop a plan and supporting actions (CAs, Orders, POs, etc.) necessary to obtain the appropriate number, size, location of soil samples to confirm there is or is not any evidence of contamination in the soil due to leakage of the SFP or CP. Should leakage be detected a further CR will be generated in accordance with procedure NG-DB-00244, Radioactive Material Control Program, section 6.2.10. This section deals with contamination in and around the facility to ensure that the requirements of 1OCFR50.75(g) are met.Quality Comments: CORRECTIVE ACTIONS Page 2 of 3 Site: G201 INVESTIGATION
SUMMARY
CR Number: 04-01719 NOP-LP-2001-06 Resp CA Sched CA Cause Org. Accept Due Completed Number: Type: Type: Code: Codes: CA Acceptance: Date: Date: Date: I A ES NA DBRC MCALLISTER, A 4/23104 3/31/2006 11/9/2004 2 A ES NA PJ HENNESSY, B 4119104 7/1612004 6/21/2004 3 A ES NA DBPE I HENGGE, C 11/11/04 6/30/2005 6/16/2005 Page 3 of 3 UNITED STATES NUCLEAR REGULATORY COMMISSION OFFICE OF NUCLEAR REACTOR REGULATION WASHINGTON, DC 20555-0001 March 3, 2004 NRC INFORMATION NOTICE 2004-05: SPENT FUEL POOL LEAKAGE TO ONSITE GROUNDWATER Addressees: All holders of operating licensees for nuclear power reactors (except those who have permanently ceased operations and have certified that fuel has been permanently removed from the reactor vessel) and for research and test reactors, and all holders of fuel storage licenses and construction permits.Purpose: The U.S. Nuclear Regulatory Commission (NRC) is issuing this information notice to inform addressees of the recent identification of a longstanding leak to onsite groundwater from the spent fuel pool of an operating pressurized water reactor facility. It is expected that recipients will review the information for applicability to their facilities and consider actions, as appropriate, to avoid similar problems. However, suggestions contained in this information notice are not NRC requirements; therefore, no specific action or written response is required.Description of Circumstances: On September 18, 2002, the licensee for the Salem Nuclear Generating Station identified evidence of radioactive water leakage through an interior wall located at the 24-meter (78-foot)elevation of the Unit 1 auxiliary building mechanical penetration room, a radiologically controlled area. The leak location, about 3 meters (10 feet) up a wall surface, was identified while the licensee was following up low-level shoe contamination of personnel who had traversed the room. The licensee established a comprehensive task action plan to identify and stop the source of the leakage and evaluate possibly undetected leakage outside building structures. The licensee did identify other locations where radioactive water was leaking through interior walls or penetrations into both the Unit 1 auxiliary building and the Unit I fuel handling building (FHB).On February 6, 2003, the licensee identified the radionuclide tritium (H-3) in groundwater in two test locations near the Unit 1 FHB. The test locations were within the licensee-controlled restricted area. The licensee identified other locations of groundwater contamination in the general vicinity of the Unit I FHB and within the restricted area. No other reactor-produced radionuclides were detected in the groundwater sampling test locations. ML040580454 04-01719 IN 2004-05 Page 2 of 4 The licensee obtained technical support and concluded (based on leak testing of suspect systems, chemical analysis of water samples, system and building configuration reviews, and a geohydrological evaluation) that the likely source of the tritium was the Unit 1 spent fuel pool (SFP). The licensee believes that the leakage was the result of the obstruction of the leakage detection and collection system of the SFP stainless steel liner.Discussion: The Salem Unit 1 FHB is a seismically qualified structure that contains the Unit 1 SFP. Unit 1 SFP support systems in the Unit 1 auxiliary building pass through adjacent building walls to the Unit I FHB. The walls are separated by a Styrofoam -filled 15-cm (6-inch) seismic gap and the support systems traverse the seismic gap.The Unit 1 SFP is a concrete structure with a stainless steel liner. The SFP includes an integral liner leakage detection and collection system, consisting of an extensive network of collection lines running both horizontally and vertically within the narrow gap between the SFP liner and the concrete SFP structure. The collected liner leakage is discharged to a collection trough through 17 drain lines (tell-tale drains). The tell-tale drains provide a means to detect, monitor, and quantify potential leakage from the SFP liner. The collected leakage is subsequently directed to the liquid radioactive waste system for processing. The licensee's reviews discovered that over the years since initial facility startup, materials such as boric acid residue and minerals accumulated within the leak collection and detection system and restricted the normal drainage of liquid. The reviews also found that a modification to the tell-tale drains in 1998 resulted in the inadvertent introduction of sealant into the tell-tale drains, further restricting the free drainage of leakage from the liner. As a result, through-liner leakage accumulated between the SFP liner and the concrete structure of the SFP. The accumulated water, containing tritium, subsequently migrated to other locations through penetrations, concrete construction joints, and cracks. The seismic gap was confirmed to contain water with radionuclides characteristic of Unit 1 SFP water. The water is believed by the licensee to have made its way to the groundwater in the restricted area via the seismic gap.The licensee cleaned the tell-tale drains, improving the drainage of the accumulated water between the liner and spent fuel pool concrete structure and stopping the through-wall and penetration leakage. After the cleaning effort, the leak rate from the tell-tale drains increased from about 19 liters per day (5 gallons per day) to about 380 liters per day (100 gpd). The leakage was properly collected. The NRC conducted a special inspection of this issue (NRC Inspection Report 50-272/2003-006; 50-311/2003-006, ADAMS Accession No. ML032890212). The NRC's and the licensee's reviews identified the following information about this situation. 0 IN 2004-05 Page 3 of 4 1. The licensee took actions to identify specific leak locations, repair and mitigate the leak, and assess potential health and safety impacts. A comprehensive groundwater sampling and analysis program was implemented. Although the licensee believes, with a high degree of confidence, that the leak originated from the SFP, the licensee is continuing evaluations to confirm this conclusion. The leakage itself was not accompanied by large fluctuations in SFP water levels and was likely masked by approximately equal volumes of evaporation from the SFP.2. The licensee stopped the identified through-wall leakage by cleaning the tell-tales and resumed controlled collection of SFP liner leakage via the installed leakage detection and collection system. Extent-of-condition reviews revealed no apparent accumulation of water between the SFP liner and concrete structure at Salem Unit 2.3. The licensee's evaluations did not identify any immediate health and safety consequences to onsite workers or members of the public. No radionuclides associated with the leakage were detected outside the onsite areas administered as access-controlled areas for purposes of radiation protection. The licensee did not detect any tritium associated with this leak in areas accessible to the public (i.e., the unrestricted area). The licensee subsequently developed and implemented an onsite groundwater remedial investigation work plan in conjunction with State of New Jersey representatives.
- 4. The Unit 1 SFP had exhibited detectable leakage from the tell-tales since initial plant operations.
To monitor leakage from the tell-tales, the licensee established a surveillance program. Over the years, the leakage from the tell-tales diminished but the licensee was not able to tell from leakage changes if they needed further evaluation. There was also a missed opportunity to evaluate earlier through-wall contaminated leakage for possible accumulation of water between the Unit I FSP liner and concrete structure.
- 5. There was no periodic maintenance of the SFP leakage detection and collection system to ensure that drainage channels remained free and clear so that the system could perform its design function of preventing water from accumulating behind the FHB walls.The licensee initiated actions to develop a cleaning and maintenance process.6. The licensee conducted evaluations of potential short-term adverse impacts to the SFP structure.
The preliminary evaluations did not identify any adverse effects that would impact the design bases of the SFP or FHB structure. Nonetheless, the licensee initiated laboratory testing of the effects of boric acid on concrete. The results of these tests are being evaluated by the licensee for potential long-term effects.The licensee developed numerous corrective action documents to track the review, evaluation, and correction of identified deficiencies. IN 2004-05 Page 4 of 4 This information notice requires no specific action or written response. If there are any questions about this notice, contact one of the persons listed below or the appropriate Office of Nuclear Reactor Regulation (NRR) project manager.IRA!William D. Beckner, Chief Reactor Operations Branch Division of Inspection Program Management Office of Nuclear Reactor Regulation Technical Contacts: Ronald Nimitz, Region I (610) 337-5267 E-mail: rlnc)nrc.gov Suresh Chaudhary, Region I (610) 337-5335 E-mail: skc0)nrc.qov Stephen Klementowicz, NRR (301) 415-1084 E-mail: sxk(@nrc.cqov Jason Jang, Region I 610-337-5220 E-mail ici(,nrc.qov
Attachment:
List of Recently Issued NRC Information Notices a Attachment IN 2004-05 Page 1 of 1 LIST OF RECENTLY ISSUED NRC INFORMATION NOTICES Information Date of Notice No. Subject Issuance Issued to 2004-04 Fuel Damage During Cleaning 02/24/2004 All holders of operating licenses fc)r at a Foreign Pressurized Water Reactor 2004-03 2004-02 2004-01 Note: Radiation Exposures to Members of the Public in Excess of Regulatory Limits Caused by Failures to Perform Appropriate Radiation Surveys During Well-logging Operations Strontium-90 Eye Applicators New Calibration Values and Use Auxiliary Feedwater Pump Recirculation Line Orifice Fouling -Potential Common Cause Failure 02/24/2004 02/0512004 01/21/2004 light-water reactors, except those who have permanently ceased operations and have certified that fuel has been permanently removed from the reactor.All well-logging licensees. All U.S. Nuclear Regulatory Commission (NRC) medical-use licensees and NRC master materials license medical-use Permittees. All holders of operating licenses or construction permits for nuclear power reactors, except those that have permanently ceased operations and have certified that fuel has been permanently removed from the reactor.NRC generic communications may be received in electronic format shortly after they are issued by subscribing to the NRC listserver as follows: To subscribe send an e-mail to <Iistprocp~nrc.,ov >, no subject, and the following command in the message portion: subscribe gc-nrr firstname lastname O OL = Operating License CP = Construction Permit x-4 STORM WATER POLLUTION PREVENTION PLAN Approved: Approved: Date: __________ Date: h Ak Effective Date MAR 1 0 2011 TABLE OF CONTENTS 1.0 2.0 3.0 4.0 5.0 5.2 5.3 5.4 5.5 6.0 7.0 8.0 PURPOSE SCOPE DEFINITIONS RESPONSIBILITI ES DETAILS Storm water Management Controls Site Storm Water Inspections Employee Training Storm Water Spill Response REFERENCES RECORDS SCOPE OF REVISION Page 4 4 4 5 6 7 8 8 9 9 10 11 ATTACHMENT 1: ATTACHMENT 2: ATTACHMENT 3: ATTACHMENT 4: ATTACHMENT 5: ATTACHMENT 6: ATTACHMENT 7: ATTACHMENT 8: ATTACHMENT 9: POLLUTION PREVENTION TEAM SITE MAP MATERIAL INVENTORY DESCRIPTION OF EXPOSED SIGNIFICANT MATERIAL LIST OF SIGNIFICANT SPILLS AND LEAKS NON-STORM WATER DISCHARGE ASSESSMENT AND CERTIFICATION EXISTING MONITORING DATA
SUMMARY
OF POLLUTANT SOURCES BEST MANAGEMENT PRACTICES 12 13 14 17 18 19 20 22 24 DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2009 Revision: 0 Page 00 3 of28 I Title Storm Water Pollution Prevention Plan TABLE OF CONTENTS (Continued) ATTACHMENT 10: ANNUAL SITE INSPECTION CHECKLIST ATTACHMENT 11: STORM WATER DISCHARGE FLOW CHART Page 27 28
1.0 PURPOSE
1.1 The purpose of this plan is to consolidate all storm water pollution prevention requirements into one location. This will meet the Ohio Environmental Protection Agency (EPA) requirements for a Storm Water Pollution Prevention Plan (SWP3), assure compliance with the site's storm water discharge permit, provide a quick reference in the event of an emergency situation, and ensure that all personnel involved in storm water activities are knowledgeable of these requirements as specified by the Ohio EPA.1.2 The specific objectives of the plan are to 1) identify potential sources of pollution which may reasonably be expected to affect the quality of storm water discharged from the facility and evaluate their significance and 2) describe and ensure the implementation of practices which are to be used to reduce pollutants in storm water discharges at the facility.2.0 SCOPE 2.1 Applicability
- 1. This guideline applies to all personnel who may be responsible for implementing the SWP3.2. Adherence to this Business Practice is mandatory.
3.0 DEFINITIONS
3.1 DISCHARGE
-Includes, but is not limited to, any spilling, leaking, pumping, pouring, emitting, emptying, or dumping, but excludes:* Discharges in compliance with a NPDES permit.Discharges resulting from circumstances identified and reviewed and made part of the public record with respect to a NPDES permit issued or modified and subject to the condition in such permit.Continuous or anticipated intermittent discharges from a point source, identified in a NPDES permit, which are caused by events occurring within the scope of relevant operating or treatment systems.3.2 NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) -A federal program administered by the Ohio Environmental Protection Agency that provides for the permitted discharge of pollutants to state or federal waterways.
3.3 OUTFALL
-The location where an effluent is discharged into the receiving waters by a discernible point source.
3.4 REPORTABLE
QUANTITY (RQ) -A minimum quantity that may be harmful to the environment and/or human health and requires notification to a regulatory agency when spilled/discharged.
3.5 SIGNIFICANT
MATERIALS -Substances associated with industrial activities which have the potential to be released with storm water discharges. These materials include: raw materials; fuels; materials such as solvents, detergents, and plastic pellets; finished materials such as metallic products, raw materials used in food processing or production; hazardous substances designated under Section 101 (14) of the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA); any material the facility is required to report pursuant to Section 313 of Title III of the Superfund Amendments and Reauthorization Act (SARA); fertilizers; pesticides; and waste products such as ashes, slag, and sludge that have a potential to be released with storm water discharges.
3.6 STORM
WATER -Storm water runoff, snow melt runoff, and surface runoff and drainage.3.7 STORM WATER DISCHARGE ASSOCIATED WITH INDUSTRIAL ACTIVITY -The discharge from any conveyance which is used for collecting and conveying storm water and which is directly related to manufacturing, processing or raw materials storage areas at an industrial plant.4.0 RESPONSIBILITIES 4.1 The Manager-Site Chemistry shall: 4.1.1 Provide overall administration of this guideline. 4.1.2 Make required onsite and offsite notifications.
4.1.3 Provide
technical assistance during storm water mitigation activities.
4.1.4 Ensure
submittal of any required regulatory reports.4.1.5 Ensure compliance with storm water permit requirements.
4.1.6 Ensure
SWP3 contents are up-to-date by conducting monthly and annual inspections and making changes as needed.4.2 The Storm Water Pollution Prevention Team (Attachment
- 1) shall: 4.2.1 Prepare required regulatory reports.4.2.2 Coordinate employee training programs.4.2.3 Conduct storm water pollution prevention inspections.
4.2.4 Update
SWP3 as storm water pollution sources. Locations. Or best management practices change.4.2.5 Continually evaluate best management practices and pollution prevention strategies to better prevent the discharge of pollutants through storm water outfalls.4.3 Other actions for the discharge of pollutants through storm water outfalls as required by RA-EP-02850 may occur concurrently with SWP3 implementation. These actions may include: 4.3.1 The Shift Manager or designee may make required onsite notifications and determine if a spill or discharge has occurred which requires implementation of HAZWOPER.4.3.2 The Manager-Site Chemistry may prescribe personnel protective equipment and practices during an emergency response.4.3.3 The Manager-Maintenance may isolate discharge pathways and provide clean-up of spilled materials. 4.4 All DBNPS personnel shall immediately report pollutant spills and discharges to the Shift Manager.5.0 DETAILS 5.1 Description of potential storm water pollution sources and pollution prevention practices. 5.1.1 A site map is included in Attachment 2, depicting storm water outfalls and materials which are or may be exposed to storm water.5.1.2 An inventory of all materials on site which are or may be exposed to storm water is included in Attachment
- 3. This material inventory is broken down to the following outfalls: a. Outfall 1-NPDES Outfall 002, which includes all of the Protected Area and most outlying Areas.b. Outfall 2-Wastewater Treatment Facility, which includes outdoor storage near the wastewater Treatment Facility.c. Outfall 3-Parking and Service Building 4, which includes the gasoline/diesel fuel dispensing area and materials stored outside north of Service Building 4.5.1.3 A description of significant materials exposed to storm water is included as Attachment
- 4.
0 DAVIS-BESSE BUSINESS PRACTICE Number.DBBP-CHEM-2009 Title: Revision: Page Storm Water Pollution Prevention Plan 00 1 7 of 28 5.1.4 A list and description of past spills and leaks related to storm water discharges is includes as Attachment 5.5.1.5 Storm water and non-storm water discharges fall under different regulatory requirements, with non-storm water discharges requiring a NPDES permit. Outfall 1 is a combined storm water and non-storm water discharge outfall, so it is included in this guideline and the NPDES permit. Outfall 2 and 3 contain only storm water discharges and are contained in this guideline. An attachment to verify these discharges was conducted as required and is included as Attachment 6.5.1.6 A summary of existing storm water monitoring data is included in Attachment
- 7. Monitoring data summaries for Outfall 1 and Outfall 3are provided.
Monitoring for Outfall 2 is not provided as there was no flow.Outfalls 1 and 3 monitoring data show no pollutants in levels of concern.5.2 Storm water Management Controls 5.2.1 A summary of pollutant sources and current practices to minimize the potential discharge of such pollutants to storm water outfalls is included in Attachment 8.5.2.2 A list and description of new Best Management Practices (BMPs)discovered during development of this SWP3 and subsequent inspections is include din Attachment
- 9. At a minimum, BMPs must include: a. Good housekeeping
- b. Preventative maintenance
- c. Inspections
- d. Spill prevention response e. Sediment and erosion control f. Management of runoff g. Employee training h. Record keeping and internal reporting 5.3 Site Storm Water Insr)ections 5.3.1 A detailed suite inspection will be conducted by the Storm water Pollution Prevention team on an annual basis to verify that the SWP3 contents are accurate.a. Attachment 10 includes a list of items to be included in the annual inspection.
- b. All incidents of noncompliance will be documented on the inspection report.c. If no noncompliance incidents are noted, the inspection will contain a certification that the site is in compliance with the plan.d. Annual inspection reports will be in memorandum format and signed by the Manager-Site Chemistry.
- e. A copy of the annual inspection will be maintained by Site Chemistry as part of the plan.f. Annual inspection reports will be maintained in records Management for at least three years.5.3.2 A visual inspection should be conducted by the Storm water Pollution Prevention Team on a monthly basis of all areas of potential storm eater contamination as identified in Attachment 3.a. Visual inspection should be documented on ED8028, Environmental Compliance inspection Form.b. A copy of the visual inspection form should be maintained by Environmental as part of the plan.c. Visual inspections forms will be maintained in records Management for at least three years.5.4 Employee Training 5.4.1 Employees attend site specific training for spill response and clean-up according to their specific job titles and functions.
Detailed training programs exist for HAZWOPER and Chemical waste management.
5.4.2 Employees
involved in storm water pollution prevention practices will be trained to these additional requirements by required reading of this plan.
5.4.3 Copies
of those employees completing required reading will be maintained by Site Chemistry as part of the plan as well as in Records management. NOTE 6.5 A simplified flow chart for storm water clean-up and notification requirements are shown on Attachment 11.5.5 Storm Water Spill Response 5.5.1 The discharge of pollutants through storm water Outfall 1 is covered by the site's NPDES permit. The allowed discharge limits, situations which may result in noncompliance, and notification and reporting requirements are detailed in DB-CN-00030.
5.5.2 Storm
water contamination by discharges to Outfalls 2 and 3 and the required clean-up and reporting requirements are detailed in the following locations:
- a. RA-EP-02850
-Describes HAZWOPER activation requirements and small spill/discharge clean-up information.
- b. ECG-04 -Describes how to clean up chemical spills/discharges and the associated reporting requirements. (For purposes of this plan, ECG-04 applies to gasoline, paints/solvents, sodium hypochlorite, and miscellaneous laboratory chemicals when expose dot storm water.)c. DBBP-CHEM-2005
-Describes how to clean-up oil/diesel fuel spills/discharges and the associated reporting requirements.
6.0 REFERENCES
6.1 Developmental
6.1.1 Clean
Water Act of 1987 6.1.2 Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) of 1980 6.1.3 Oil Pollution Act of 1990 6.1.4 40 CFR § 110, EPA Regulations on Discharge of Oil 6.1.5 40 CFR § 112, Oil Pollution Program 6.1.6 40 CFR § 116, EPA Regulations on designation of Hazardous Substances under the Federal water Pollution Control Act 6.1.7 40 CFR § 122, 123,and 124, National Pollutant Discharge Elimination System Permit Application regulations for Storm water Discharges 6.1.8 40 CFR § 117, EPA Regulations on determination of Reportable Quantities for Hazardous Substances 6.1.9 40 CFR § 302, EPA Designation, reportable Quantities, and Notification Requirements for Hazardous Substances under CERCLA 6.1.10 Ohio Administrative Code (OAC) Section 3750-1, State Emergency response Commission 6.1.11 OAC Section 3750-25, Emergency Release Notification 6.1.12 NG-DB-00501, Environmental Compliance Program 6.1.13 RA-EP-02850, hazardous Chemical and Oil Spills 6.1.14 Storm Water Permit Manual, Thompson Publishing Group 6.2 Implementation 6.2.1 DB-CN-00030, National Pollutant Discharge Elimination System (NPDES) Program 6.2.2 ECG-04, SARNCERCLA Hazardous Chemical Locations and Spill Event Guidelines 6.2.3 DBBP-CHEM-2005, Spill Prevention and Countermeasure (SPCC) Plan 7.0 RECORDS 7.1 The following quality assurance records are completed by this guideline and shall be listed on the Nuclear Records List, captured, and submitted to Nuclear Records Management in accordance with NG-NA-00106. 7.1.1 None 7.2 The following non-quality assurance records are completed by this guideline and may be captured and submitted to Nuclear Records Management in accordance with NG-NA-00106.
7.2.1 Pollution
Prevention Team 7.2.2 Material Inventory
7.2.3 Description
of Exposed Significant Materials 7.2.4 List of Significant Spills and Leaks 7.2.5 Non-Storm water Discharge Assessment
7.2.6 Existing
Monitoring data 7.2.7 Summary of Pollutant Sources 7.2.8 Best Management Practices 7.2.9 Annual Site Inspection Reports 7.2.10 Monthly Inspection Forms 7.2.11 Non-Periodic Reports, if generated.
8.0 SCOPE
OF REVISION Rev. 00 The Fleet Program Manager has concurred with the issuing of this site-specific business practice. DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2009 Revision: Page 4 I-Title: Storm Water Pollution Prevention Plan 00 I 12 of 28 ATTACHMENT 1: POLLUTION PREVENTION TEAM-Page 1 of 1 Leader: Responsibilities: POLLUTION PREVENTION TEAM MEMBER ROSTER V. N. Capozziello, Supervisor-Nuclear Chemistry Services Coordinate all stages of plan development and implementation, ensure required reports are submitted, and coordinate employee training programs.Members: 1) S.M. Chimo, Senior Nuclear Specialist Responsibilities: Conduct inspections, develop plan, and prepare required reports.2) A.M. Percival, Senior Nuclear Specialist Responsibilities: Help conduct inspections for plan development.
- 3) J.J. Eccleston, Nuclear Engineer Responsibilities:
Oversee inspections and plan development, verify discharge locations, oversee preventive maintenance.
- 4) Group Activities Responsibilities:
Developing the plan elements, choosing storm water management options. DAVIS-BESSE NUCLEAR POWER STATION-I-I c m o m< _0 0 (D zz CD --_L ro wi-=uulas~ o 0-- W"A"~ -ME Mý&si =5MIC 3Ma AL Lr 0"M M or ILso Dli=
- O-anc WL ~-- ~UCI.a)Snsm "Ea~U 0~I.DICIG -NG3 ~ 1 t Iw~ e ATTACHMENT 3: MATERIAL INVENTORY Page 1 of 3 Outfall 1 (NPDES Outfall 002)Quantity Likelihood of Purpose/ Exposed in Contact with Storm Past Significant Material Location Quantity Last 3 Years Water Spill or Leak Sodium Above ground 7,500 gal No Possibility during No hypochlorite tank with 115% chemical delivery 15% solution dike Sodium bromide Above ground 4,300 gal No Possibility during No 43% solution tank with 115% chemical delivery dike Warehouse New chemical Varies No No-area diked. No chemical bldg. storage Insufficient containment but gate for drainage ditch cdn be closed Chemical Waste Various Varies No Building has No Storage Area chemical containment curb.storage prior to Possibility during transfer off-site chemical transfer/shipment Storm Water Pollution Prevention Plan ATTACHMENT 3: MATERIAL INVENTORY Page 2 of 3 Outfall 1 (NPDES Outfall 002) (Continued)
Chemical waste accumulation:: Quantity Likelihood of Purpose/ Exposed in Contact with Storm Past Significant Material Location Quantity Last 3 Years Water Spill or Leak 1) Turbine Accumulation Varies (-5-8 No Possibility during No Bldg.(North): 55 gal chemical transfer.used oil, Unit has self-diesel fuel, containment. filters/debris'
- 2) Diesel Accumulation 2-55 gal No Possibility during No storage chemical transfer.tank: Unit has self-diesel fuel oil containment.
- 3) EDG diesel Accumulation 2-55 gal No Possibility during No fuel area: chemical transfer.diesel fuel oil Unit has self-containment.
- 4) PSF Mech Accumulation Varies (-3-5 No Possibility during No Maint.(used 55 gal chemical transfer.oil, filters/ Unit has self-debris containment.
- 5) SBODG Accumulation 1-55 gal No Drum is overpacked No Fuel: 1) Diesel oil Tank above 100,000 gal No Leaks/spills and No storage tank ground with delivery accidents dike would go through oil interceptor
- 2) Diesel fuel Underground 2-40,000 gal No Yes-no containment No storage tanks 3) DBAB Diesel Underground 8,000 gal No Yes-during fuel No fuel storage delivery tank Salt Pile De-icing 100-125 No Area is covered No roadways tons/year DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2009 Title: Revision:
Page Storm Water Pollution Prevention Plan 00 16 of 28 ATTACHMENT 3: MATERIAL INVENTORY Page 3 of 3 Outfall 2 (Wastewater Treatment Facility)Purpose/ Quantity Likelihood of Material Location Quantity Exposed in Contact with Storm Past Significant Last 3 Years Water Spill or Leak Sodium De-chlorination 900 gal No Yes-during No Bisulfite chemical transfer or tank /pipe leak.Spilled material would most likely enter soil rather than storm drain.Outfall 3 (Parking and Service Building #4)Purpose/ Quantity Likelihood of Material Location Quantity Exposed in Contact with Storm Past Significant Last 3 Years Water Spill or Leak Diesel fuel Fleet fueling. 1,000 gal No Possibility-during No tank Above ground fuel delivery tank w1115%dike Gasoline Fleet fueling. 2,000 gal No Possibility during Yes Above ground fuel delivery tank w/115%dike Chemical waste accumulation: Used oil Accumulation 2-55 gal No Possibility during chemical transfer.Unit has self-containment. ATTACHMENT 4: DESCRIPTION OF EXPOSED SIGNIFICANT MATERIAL*Page 1 of 1 Based on the material inventory, the following describes the significant materials that were exposed to storm water during the past three years and/or are currently exposed.Description of Exposed Method of Material Significant Period of Currently Storage or Management Material Exposure Exposed Location Disposal Practice*There have been no events of significant materials exposed to storm water within the past three years. DAVIS-BESSE BUSINESS PRACTICE Number:DBBP-CHEM_2009 Title: Revision: BPage Storm Water Pollution Prevention Plan 0 0 18 of 28 ATTACHMENT 5: LIST OF SIGNIFICANT SPILLS AND LEAKS Page 1 of 1 Record all significant spills and significant leaks of toxic or hazardous pollutants that have occurred in the past three years. Significant spills include, but are not limited to, releases of oil or hazardous substances in excess of reportable quantities. --* There have been no significant spills or significant leaks of toxic or hazardous pollutants that have occurred in the past three years.Previous significant spills and significant leaks of toxic or hazardous pollutants that have occurred.Material No Amount. Longer Preventative Date Spill/Leak Location Quantity Source Reason Recovered Exposed Measures to Storm Taken Water Gas Leaking Gas Dispensing 1,300 gal Gas Line True-in Put Pump in 1/15/94 Leak area Gasoline Tank Diaphragm 500 gal soil Dike Overfill Drum Diesel fuel during level staged Spill 40,000 gal calibration True-in during level 8/21/98 (overfill) tank 50 gal Overfill activities -25 gal soil calibrations ATTACHMENT 6: NON-STORM WATER DISCHARGE ASSESSMENT AND CERTIFICATION Page 1 of 1%Workshset
- 6 NON-STORM WATER DISCHARGE Completed by: S.H. Chimo ASSESSMENT AND CERTIFICATION Title: Environmental Special 1nr (Saction 2.2.41 Date: November 4. 1998 -_Outfall Directly Date of Observed During the Method Used to Describe Results from Teas for Name of Person Who Test or Test ows-0y .. thas..,d Tast or Evaluate the Presence of Non-Stolm Identify Potential Condbcted ithe Teast or SEvaluation Ole egg m.9t Discharge Water Discharge Significant Sources Evaluation Visual Discharge mixed with 10/91 Outfall I Inspection NPDES Outfall 002 NONE T.K. Wasch Visual 10/91 Outfall 2 Inspection qo diacharse obaerved NONE T.K. Wanch Drawing ao non-storm water 1/19/95 Outfall 3 Schematics .onnections observed NONE T.K. Weech CERTIFICATION 1, John K. Wood (reeponsible corporate ofliclall.
certify under penalty of law that this document and all atachmenta ware prepared under my direction or supervision In accordance with a system designed to assure that qualified personnel property gather and evaluate the Inlorrnation submitted. Bsaled on my Inquiry of the person or persona who manage the system or those persons directly responsible for gathering the.informatlon, the Information submitted Is, to the beat of my knowledge and belief, true, accurate, and comphdte. I am awore that there era of-nnihfiI nt for iume lttlnnt fals,-tiformation. Iniludino the posslblty of fine and Imorlsorment for knowing violatlons, A. Name & .OfficlafTitle (typb or prinli, B. Area Coda and Telephone No.Johil K. Wood. ViPe Pregidetr-Nuclaar 419-n249-2300
- c. Snatura .I Si,.gned., I il all O I I'; ." 7 DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2009 Title: Revisidn:
Page Storm Water Pollution Prevention Plan 00 20 of 28 ATTACHMENT 7: EXISTING MONITORING DATA Page 1 of 2 EIPA ID Nmi (OPY ftM Item I OtForro 1).. 03706-SW Outfali 002 Forn Approved. OM No. Approvul excis 5-31-92 VII. Discharge Information (Continued from page 3 ofForm 2F)Part A -You must oride the resulb of at least one analysis far very In this table. Cornptete one table for each cutt.a Saa Insbuotlns for addlonel deoal.Maximum Values Average Values J~ieU1919) JOnclude EsV/a) Numiber Polutant GrOb Sample b gm'eof and Taker) During Taken Dur, Storm CAS Number First 20 Flow-Wlgtrlad Fbt2O tow4WA)hted Ewnt*flfavaftblo) MIna Cornposofe Minutes Composlie Sampled Sourcas of Patutants 03 and OrG e <5 mg/i NWA Biological Oxygen Demand eDDS) 3.3 Cicemal Oxygen Demand (COD) 11..1 m Total Suspended SoW3 (TSS) 13 /Total Nitrogen .0.20 g/1 1 Total Phosphoras -0.05 mg/i I pH Minimum -7.'.7 Maximum 7.97 Mi Mamum trarnum i Pert 8 -Lst each podutant that Is Winiled In an effluent guldelne whiich the faaliy ts subject to or any pollutant listed In the fadity's NPOES Permit for tit process walawator (if the facilty It operating under an existing NPDES pernmt. Complete one tabMe for each oufialL. See the far addtional delaia and Maximum Vatues Average Values-m rud uns) OJickr do 1u1,11) Number Pollutant Grab Sample Grab Sampe of and Taken Du:ig Take DInt: Stoflr CA$ Number Firlt20 Fow-blighled " Flnt 20 Flow-Welghted Events (ifovailable) Minutes Composlit Minutes Composait Sampled -Sources of PollutantsOsygen 7.6 ppm 1 TOC .O.os mg/i fluorida 0.4 m9/i AlurlUosm 530 __l_Acaanla sin rlg/l Bariume 70 ug/1 Boron 112 ug/1 Copper <3 %g/1 Xron 471 ug/i Silver <1 u/g/1 Ammoia ý0.2 " T0 <0.2 EPA Form 3510-2F (1-92)Page V11-1I Continlue on Revoers DAVIS-BESSE BUSINESS PRACTICE Number: DBBP-CHEM-2009 Title: Revision: Page Storm Water Pollution Prevention Plan 00 21 of 28 ATTACHMENT 7: EXISTING MONITORING DATA Page 2 of 2 V. PA ID ombe-r.11 .l aIoF- 1n)Form AptPovod. OMB No. 2040-008 Approval exprs s-31.92 VIl. Discharge Information (Continued from page 3 of Form 2F)Part A -You must povde the results of M lenst one enaals fot er pollthant in Ohi tae. COplieta one Wa for each oulra0., See Inslbrlions for eddillonel details.Maximum Values Average Values Wifagmts) J uslrd. nhl) Number Polutant Grab Sample Grab Sample of and Taken During Taken During alom OAS Number First 20 Floo.-Wagsloed First 20 Filoiy-W hted EWtst OiflveleA4) Minutds Comt Minutas Compoale Sampled sources of Polutaets Oland Geaasi <5 Xe/1 WA Bohoaica" Oxygen Demand (BOG5) ~ a/Chemical Oxygen Demand (O) 54.9 rae/i Total Suspended soLIds (Trs) :s~ =m1/Total NItrogen 0.45 V3/1 I Total Phosphorus 0.27 ,g/i 1 pH Mnilmum ,.OO Maximum -.092 Wrnoum Maximum Part 8- List each pollutant tuat Is llmlltd Int a effluent putallrre BIch the tacilly Is subject io or any polutani lbted in the faclIyA NPDES permit for iu process westewaler t fIte faclity Is operamlr under an exiting NPDES permlll. Complete one table for each outf11. See the Instructons for Acd.ltioral deala aend teo lmrntn Maximumvalvee Avege Values M~l unb~) emin~de, un9t2) Nn Pollutant Grab Semple Grab Sample of end Taken Durn Duken Duringt CAS Number Firet 20 Flow-W6ted Fl120 Flow-Welhted Ewait (flavallable) Mlnutas Minutes Comoposite Smpled Souro, of Pollutaent Diae. ,Oxygen 4.5 ppm 1 TRC 0.1 i_/1 Fluoride 0,8 raq/i Alumi.umn 1377 U9/1 Arsenio <10 Um/1 Barium 98 ug/BOron 77 U9/1 Copper 14 U91/Iron 14706 UV/1 _________ ____Silver <3 ug/_TIOS 1.2 mn/1 EPA Form 3610-2F (1-92)Paes V11.11 Contin~ue on Revers ATTACHMENT 8:
SUMMARY
OF POLLUTANT SOURCES-Page 1 of 2 The following significant materials have been stored on-site within the last three years within the described storm water discharge areas: 1. Outfall 1 (NPDES Outfall 002)a. Chemical Waste Storage Areas (CWSA)The CWSA is an enclosed structure with a curbed concrete pad to contain any potential leaks. The pad is divided into three separate sections as follows: 1)hazardous waste, 2) waste oil and non-hazardous wastes, and 3) chemical identification. In the event of a large quantity leak, the flapper gates for the drainage ditch behind the facility can be closed to isolate the spill. Also, the CWSA is inspected on a weekly basis.b. Chemical Waste Accumulation Areas (CWAA)There are two CWAAs in this storm water discharge area. These two CWAAs are only for diesel fuel. They each consist of two 55-gallon drums contained in the water-tight plastic storage containers.
- c. Sodium Hypochlorite (NaOCI) Tank The NaOCI tank, which is located at the site water treatment plant, has a maximum capacity of 7,500 gallons and contains a 15% solution.
This tank has a dike structure designed to contain 115% of the tank capacity.d. Sodium Bromide (NaBr) Tank The NaBr tank, located at the Water Treatment Plant, has a 4,500 gallon capacity and contains a 43% solution. This tank has a dike structure designed to contain 110% of the tank capacity. ATTACHMENT 8: -
SUMMARY
OF POLLUTANT SOURCES Page 2 of 2 e. Oil Containment Oil Containment consists of the following: Maximum Tank/ Equipment Capacity (gallons)_ Physical Controls Diesel Oil Storage Tank 100,000 Diked Emergency Diesel Generator Collected in an Oil (EDG) Day Tanks 2-6,000 each Interceptor Emergency Diesel Generator 2-40,000 each None- Underground (EDG) Fuel Oil Storage Tanks There are five oil interceptors which service plant drains and sumps entering the Outfall 002 Discharge System. Those storage tanks or equipment whose containments are not directly associated with the interceptors, would ultimately be serviced by an interceptor via adjacent plant floor and service drains. The underground storage tanks listed are not serviced by oil interceptors.
- 2. Outfall 2 (Wastewater Treatment Plant)Sodium Bisulfite (NaHSO4) Tank The NaHSO4 tank, that is located near the station collection box, has a 900 gallon capacity and contains a 40% solution.
If any NaHSO4 is spilled during chemical delivery, it would be absorbed in the surrounding soil. Storm water contact is not likely from this location, since the area is not paved.3. Outfall 3 (Service Building 4)a. Diesel Fuel Storage Tank and Gasoline Storage Tank Used to service fleet vehicles, the diesel fuel storage tank has a 1,000 gallon capacity, and the gasoline tank has a 2,000 gallon capacity. They share the same concrete dike, which is designed to contain 115% of the total capacity.b. Chemical Waste Accumulation Area (CWAA)This outfall area has one accumulation area for automotive oils and antifreeze. This CWAA is a self-contained unit designed with a spill pan underneath. DAVIS-BESSE BUSINESS PRACTICE Number.DBBP-CHEM-2009 Title: Revision: lPage Storm Water Pollution Prevention Plan o: 0 0 24 of 28 ATTACHMENT 9: BEST MANAGEMENT PRACTICES Page 1 of 3 A. Good Housekeeping Weekly Chemical Waste Accumulation Areas (CWAAs) and Chemical waste Storage Area (CWSA) housekeeping inspections as conducted by the Environmental personnel. Problems are corrected as they are identified. Maintenance Supervisors are assigned as responsible for various areas throughout the site. This includes cleanliness of the area.B. Preventative Maintenance Various engineers on site are assigned specific systems. The engineers are then responsible for oversight of all aspects of the system, including preventative maintenance scheduling and tracking as well as conducting weekly visual inspections. Some "systems" in this program include various chemical and oil tanks, station drainage and the oil interceptors. All preventative and scheduled maintenance items are tracked in a site-wide database.Oil interceptors are checked periodically by pumping out the associated collection tanks. These tanks rarely contain any oil, which shows that the tanks are not discharging oil to the storm water system.Warehouse and Maintenance Services personnel are trained in loading/unloading procedures and must complete Chemical Waste management training. If a spill would occur as a result of these activities, these personnel; are also trained in cleanup measures.C. Visual Inspections In addition to the system inspection by the engineer and the weekly CWAA and CESA inspections previously mentioned, a visual inspection will now be conducted by the Pollution Prevention Team on a monthly basis of all potential storm water pollutants as listed on the materials inventory. A copy of the inspection form will be maintained with this plan by Environmental. A more detailed annual inspection will also be conducted by the Storm water Pollution Prevention Team. All problems identified and the corrective actions taken will be documented in memorandum format and signed by the Manager-Site Chemistry. A copy of each annual inspection may be maintained with this plan by Environmental. ATTACHMENT 9: BEST MANAGEMENT PRACTICES Page 2 of 3 D. Spill Prevention and Response/Management of Runoff Detailed spill response and cleanup, measures are described in RA-EP-02850, hazardous Chemical and Oil spills; ECG-04, SARA CERCLA Hazardous Chemical Locations and Spill Event Guidelines; and ECG-05, Spill Prevention Control and Countermeasure (SPCC) Plan. Items specific to storm water spill prevention are also describes below: 1. Outfall 1 (NPDES Outfall 002)The two chemical storage buildings are diked. Although this will not contain the entire contents of either building, both have a drainage ditch with a closable gate to contain any spills.The six CWAAs are all enclosed in either a building or a plastic containment structure. Small spills would be contained in the CWAA.The three bulk chemical storage tanks have diking sufficient to contain the entire tank contents, so storm water discharge is unlikely.The 100,000 gallon diesel oil storage tank has a dike structure sufficient to hold the entire tank contents. Also, deliveries occur on a concrete pad which drains to an oil interceptor prior to discharge. The 2-40,000 gallon diesel fuel storage tanks and the Davis-Besse Administration Building diesel fuel storage tanks are underground storage tanks, so they do not come directly in contact with storm water. They are included in this plan due to the potential for a spill during bulk fuel deliveries. Salt storage is contained inside a three-sided building.All storage tank bulk deliveries are performed in the presence of site personnel. If a spill would occur, these individuals would know the required actions for responding to the incident.At Outfall 1 drainage goes through the Training Center pond prior to discharge. This is a 12 million gallon holding pond. It has a discharge gate which can be closed for cleanup actions to prevent any discharge. All large tanks contain spill kits nearby for use during spill response procedures. Such kits contain oil and chemical absorbent booms and pads, drain covers and/or plugs, and protective clothing as necessary for cleanup. ATTACHMENT 9: BEST MANAGEMENT PRACTICES Page 3 of 3 D. Spill Prevention and Response/Management of Runoff (Continued)
- 2. Outfall 2 (Wastewater Treatment Plant)The sodium bisulfite tank has 900 gallon capacity and is stored in a metal building.
If any NaHSO4 is spilled during chemical delivery, it would be absorbed in the surrounding soil.3. Outfall 3 (Service Building 4)There is one CWAA in this area. It is a small plastic shed with a containment structure. Small spills would be contained in this area.There is a 1,000 gallon diesel fuel tank and a 2,000 gallon gasoline tank.These tanks and their associated pumps are contained inside a single dike structure, which is designed to contain the entire contents of these tanks. Spills are possible during fleet fueling from these tanks or during bulk deliveries. An outdoor telephone is installed nearby for contacting the control room should a spill occur. There is an oil interceptor which can contain up to 1,500 gallons.E. Sediment and Erosion Control Potential erosion areas are graded and grassy. The majority of the facility is paved or covered with gravel.F. Employee Training Applicable employees who may come in contact with spills and discharges are trained in HAZWOPER and chemical waste management. Training specific too storm water pollution prevention will also be conducted by required reading.G. Record Keeping and Reporting All information pertaining to any spill, follow-up actions, inspections, sampling and training is maintained by Environmental. I fA\/IS-RFSS 13RI INFES PRACTICEP Number: Title:-- DBBP-CHEM-2009 Revision: Page Storm Water Pollution Prevention Plan 00 27 of 28 ATTACHMENT 10: ANNUAL SITE INSPECTION CHECKLIST Page 1 of 1 1. Is there evidence of pollutants entering the drainage system?2. Are current BMPs sufficient to reduce pollutant loadings?a. Are additional BMPs needed/recommended?
- 3. Are structural measures (Ponds, dikes, curbing, discharge gates, etc.) in proper operatibn?
- 4. Is all spill response equipment properly staged as specified in the plan?5. Are there any new sources which may cause storm water contamination?
- 6. Have any storm water sources, drainage pathways, structural controls or BMPs changed/moved since last inspection?
Yes Yes Yes No No No NA NA NA Yes No NA Yes No NA Yes No NA Yes No NA ATTACHMENT 11: STORM WATER DISCHARGE FLOW CHART Page 1 of 1 SMTPWLOIMSAFESTFORMVrR.Cdr 1115M9 x Groundwater Flow Characteristics Report Davis-Besse Nuclear Power Station Oak Harbor, Ohio FirstEnergy Service Company 16 January 2007 www.erm.com -MOel ER~ERM Delivering sustainable solutions in a more competitive
- worl, I FINA REPOR Groundwater Flow Characteristics Report Davis-Besse Nuclear Power Station Oak Harbor, Ohio FirstEnergy Service Company 16 January 2007 ERM
Reference:
55194 J o h n W .M ~ g e A § ,, Principal-in-Charge VY~ I6~Matthew Daly, P.G.Project Manager Environmental Resources Management 399 Boylston Street, 6th Floor Boston, Massachusetts 02116 T: (617) 646-7800 F: (617) 267-6447 TABLE OF CONTENTS EXECUTIVE
SUMMARY
III
1.0 INTRODUCTION
1
1.1 BACKGROUND
1 1.2 PURPOSE & SCOPE 1 1.3 LIMITATIONS 2 2.0 SITE VISIT AND DATA REVIEW 3 3.0 FINDINGS 5 3.1 AREAS OF POTENTIAL CONCERN 5 3.1.1 Power Block 5 3.1.2 APCs Outside the Power Block 6 3.1.3 Non-radiological APCs 7 3.2 TRITIUM DATA 8 3.3 SITE GEOLOGY AND HYDROGEOLOGY 9 3.3.1 Site Geology 9 3.3.2 Site Hydrogeology 11 3.4 SURFACE WATER AND GROUNDWATER USAGE 12 3.5 CONCEPTUAL SITE MODEL 13 3.5.1 Overview 13 3.5.2 Plan View 14 3.5.3 Section View 15 3.5.4 Summary 16 4.0 RECOMMENDATIONS 17 ERM/DADE MOELLER 1 FIRSTENERGY -DAVIS-BESSE 55194 1/16/07 I TABLES Table 1 FIGURES Figure 1 Figure 2 Figure 3 Figure 4 Figure 5 Areas of Potential Concern 0 Site Locus Map with Hydrogeologic Features Areas of Potential Concern Existing Monitoring Wells and Grout Curtain Conceptual Site Model and Proposed Monitoring Locations Conceptual Site Model -Section View APPENDICES Appendix A Letter from Davis-Besse Engineering ERM/DADE MOELLER II FIRSTENERGY -DAVIS-BESSE 55194 1/16/07 EXECUTIVE
SUMMARY
On behalf of FirstEnergy Service Company (FirstEnergy), as agent for FirstEnergy Nuclear Operating Company (FENOC), Environmental Resources Management (ERM) and Dade Moeller & Associates (Dade Moeller) conducted a Groundwater Flow Characteristics Study for the Davis-Besse Nuclear Power Station (DBNPS) located in Oak Harbor, Ohio.The purpose of the Groundwater Flow Characteristics Study was to evaluate the geology and hydrogeology at DBNPS in order to gather information necessary to design a monitoring program to minimize the potential for an unmonitored and/or undetected radioactive release to groundwater due to plant operations. Activities completed included a review of DBNPS site files, physical features, plant operating infrastructure, identification of potential areas for inadvertent radiological release, available tritium data and the site hydrogeology. This Groundwater Flow Characteristics Study is a preliminary step in the process of complying with the Nuclear Energy Institute guidance titled "Industry Ground Water Protection," dated June 2006.Historic releases of tritium to ground have been documented at DBNPS.Groundwater samples collected from existing bedrock wells within the Power Block indicated tritium in groundwater at concentrations up to 2,410 pCi/L.Potential releases from DBNPS have the potential to migrate vertically or laterally within the fill (structural or earthen), Glaciolacustrine Deposit, Till and Dolomite Bedrock towards marshes and ultimately Lake Erie.Initial evaluation of site systems, geology and hydrogeology suggest a low potential for releases to groundwater at the site to adversely impact drinking water receptors given the likely up-gradient, distant location of potential receptors and the most probable migration pathway being from the site to marshes and Lake Erie. Once in the marshes and Lake Erie, the impacts would immediately be diluted due to the volume of the groundwater discharge relative to the volume of water in the lake.Based on ERM and Dade Moeller's review of the available site data, the following recommendations are presented to monitor for inadvertent releases to groundwater at DBNPS: 1. Inventory and Monitor the Existing Well Network ERM/DADE MOELLER III FIRSTENERGY-DAVIS-BESSE 55194 1/16/07
- 2. Develop an Integrated Monitoring Program 3. Install and Sample Monitoring Wells, including eight well triplets and 15 temporary grab groundwater samples.4. Develop a Quality Assurance Project Plan 5. Define Internal and External Reporting Requirements
- 6. Develop a Communication Plan ERM/DADE MOELLER FIRSTENERGY
-DAVIS-BESSE 55194 1/16/07 ERM/ DADE MOELLER IV FIRSTENERGY -DAVIS-BESSE 5519L4 1/16/07
1.0 INTRODUCTION
1.1 BACKGROUND
On behalf of FirstEnergy Service Company (FirstEnergy), as agent for FirstEnergy Nuclear Operating Company (FENOC), Environmental Resources Management (ERM) and Dade Moeller & Associates (Dade Moeller) conducted a Groundwater Flow Characteristics Study for the Davis-Besse Nuclear Power Station (DBNPS) located in Oak Harbor, Ohio (Figure 1). DBNPS contains one pressurized water reactor that was constructed in the 1970s and went on-line in November 1977.The Nuclear Energy Institute (NEI) initiated a voluntary policy in May 2006 to enhance detection, management and communication about inadvertent radiological releases in groundwater at nuclear power plants.As part of the initiative, nuclear power plants are expected to: "Put in place a company/site-specific action plan(s) to help assure timely detection and effective response to situations involving inadvertent radiological releases in groundwater to prevent migration of licensed radioactive material off-site and quantify impacts on decommissioning." This Groundwater Flow Characteristics Study for the DBNPS is a preliminary step in the process of complying with the NEI initiative.
1.2 PURPOSE
& SCOPE The purpose of the Groundwater Flow Characteristics Study was to evaluate the geology and hydrogeology at DBNPS in order to gather information necessary to design a monitoring program to minimize the potential for an unmonitored and/or undetected radioactive release to groundwater due to plant operations. The Study included a review of DBNPS site files, physical features, plant operating infrastructure, identification of potential areas for inadvertent radiological release, available tritium data and the site hydrogeology. The inter-relationship of plant operations, areas of potential concern (APCs) and estimated site groundwater flow patterns is used to develop a Conceptual Site Model (CSM) and initial groundwater monitoring strategy.ERM/DADE MOELLER 1 FIRSTENERGY -DAVIS-BESSE 55194 1/16/07 The groundwater monitoring recommendations outlined in this Groundwater Flow Characteristics Report follow NEI guidance titled"Industry Ground Water Protection," dated June 2006.1.3 LIMITATIONS This Groundwater Flow Characteristics Report (Report) provides a preliminary evaluation of site characteristics necessary to support the design of a groundwater well network for monitoring existing or potential releases of radioactivity to groundwater at the site. The professional opinions presented in this Report were developed under a limited scope, schedule and budget (ERM Proposal, 11 August 2006). This Report is intended to represent the first phase of a series of studies and activities that will be required to develop an effective groundwater monitoring program for the site. As such, the results, conclusions and recommendations in this report are subject to change as the results of successive, iterative phases of site investigation, sampling, data management, interpretation and stakeholder outreach progress.ERM/DADE MOELLER 2 FIRSTENERGY -DAVIS-BESSE 55194 1/16/07 2.0 SITE VISIT AND DATA REVIEW As part of this project, the team conducted the following activities:
- Conducted a site visit at DBNPS on 10 and 11 October 2006.* Reviewed the following documents:
- Updated Safety Analysis Report (Revision 25, June 2006), Sections 2.4 (Hydrology), 2.5 (Geology and Seismology) and Appendix 2C (Geology, Seismology, Subsurface Conditions and Geotechnical Design Criteria).
- Supplement to Environmental Report Operating License Stage (1970s).* Annual Radiological Environmental Operating Report (2005).* Technical Report 14 "Groundwater Injection Recharge Report Units 2 and 3 Construction Dewatering" (17 March 1980)." Potential Condition Adverse to Quality Report #90-0404"Discovery of Dye from the Condenser Dye Test in the Area South of the Intake Structure" (11 May 1990)." Intra-Company Memorandum titled "Meeting Minutes -Ruptured Condenser Backwash Receiver Tank Discharge Line" (29 October 1991).* Potential Condition Adverse to Quality Report #97-0628 "While Pumping North Settling Basin to Collection Box, the Hose Going into the Collection Box Dropped Out of Collection Box Pumping -12,000 gallons onto the Ground" (13 May 1997).* Condition Report (CR 04-01719) "Information Notice 2004-2005 Spent Fuel Pool Leakage to Onsite Groundwater" (5 March 2004)." Letter from Davis-Besse Engineering documenting the identity of DBNPS systems/components which are vulnerable to potentially initiating an unmonitored release to the environment (see Appendix A for the letter)." Letter titled Groundwater Protection
-Data Collection Questionnaire from FirstEnergy summarizing inadvertent releases of radioactive liquids documented in DBNPS 10 CFR 50.7 5(g) files (31 July 2006).ERM/DADE MOELLER 3 FIRSTENERGY-DAVIS-BESSE 55194 1/16/07 " Reviewed facility engineering drawings and aerial photos related to the facility layout.* Participated in a walking tour of portions of the interior and exterior of DBNPS.* Spoke with DBNPS representatives from Chemistry Department. In addition to the information provided by FirstEnergy, ERM obtained information from the following data sources:* Environmental Data Resources Inc. (EDR) reports including historic topographic maps, environmental records near DBNPS and physical setting.* Ohio Department of Natural Resources Geographic Information System (GIS) databases. ERM/DADE MOELLER FIRSTENERGY -DAVIS-BESSE 55194 1/16/07 ERM/DADE MOELLER 4 FIRSTENERGY -DAVIS-BESSE 55194 1/16/07
3.0 FINDINGS
3.1 AREAS OF POTENTIAL CONCERN APCs represent locations at the DBNPS where there is a possibility that a release of radionuclides and/or oil and hazardous pollutants (i.e., non-radioactive contaminants) to groundwater either has, or could occur. The APCs identified at the DBNPS are summarized in Table 1 and are shown in Figure 2. Each of the primary APCs are discussed below.3.1.1 Power Block The Power Block represents the area that contains the reactor vessel and associated primary and secondary water sources in a pressurized water reactor. The Power Block includes the following APCs as potential radiological sources:* Containment Building 0 Auxiliary Building o Miscellaneous Waste Drain Tank o Spent Fuel Pool o Cask Pit o Liquid Radwaste Treatment System o Clean Waste Receiver and Monitor Tanks o Spent Resin Storage Tank o Detergent Waste Drain Tank o Boric Acid Evaporators o Concentrates Storage Tank 0 Turbine Building o East and West Condenser Pits o Sumps o Condensate Demineralizer Tanks 0 Fuel Transfer Canal* Circulating Water Pump House* Borated Water Storage Tank ERM/DADE MOELLER 5 FIRSTENERGY -DAVIS-BESSE 55194 1/16/07 0 Nitrogen and Hydrogen Supply Area 3.1.2 APCs Outside the Power Block Several radiological APCs were identified outside the Power Block as summarized below (Figure 2):* Condensate Demineralizer Tank Discharge Line -In May 1990, a break in the discharge line exiting the Condensate Demineralizer Backwash Receiver Tank was discovered east of the Power Block. Contaminated resin was released to soil at the connection between the Condensate Demineralizer Backwash Receiver Tank discharge line and a ten inch pipe that conveys the resin to South Settling Pond.* Liquid Radwaste Discharge Line -This pipe conveys liquid radiological waste from the Power Block to the Collection Box for dilution prior to release.* Collection Box -The collection box receives tritiated water from the Liquid Radwaste Discharge Line, along with water pumped up from the North and South Settling Basins. In 1997, water pumped from North Settling Basin to the Collection Box was inadvertently spilled onto the ground surface adjacent to the Collection Box.* Collection Box Discharge Pipe -This pipe is the primary discharge line for release of permitted discharge of tritiated water to Lake Erie. The discharge pipe is 72-inches in diameter and constructed of concrete.Leakage of tritiated water from the Discharge Pipe to the subsurface could result in the inadvertent release of tritium to groundwater.
- South Settling Basin (Settling Basin No. 1) -This settling pond historically received radioactive resins from the Condensate Demineralizer Backwash Receiver Tank." North Settling Basin (Settling Basin No. 2) -This settling pond is connected to the South Settling Basin via piping and pumps, allowing radioactive effluents from the South Settling Basin to enter the North Settling Basin.* Low-Level Radwaste Storage Building -This building is identified as an APC based on the handling of low-level radiological wastes in and around the building.° Dry Fuel Storage Area -This area is identified as an APC based on the handling of wastes in and around the area.ERM/DADE MOELLER 6 FIRSTENERGY-DAVIS-BESSE 55194 1/16/07
- Secondary Demineralized Water Storage Tank -Steam used to heat this outdoor tank during winter months contains tritium. This tank is an APC based on the potential for leakage from the steam system.* Fire Water Storage Tank -Steam used to heat this outdoor tank during winter months contains tritium. This tank is an APC based on the potential for leakage from the steam system.* Sanitary Wastewater Plants and Lagoon -The historic and current sanitary sewage treatment plants, associated piping and wastewater lagoon are an APC due to the potential for inadvertent co-mingling of tritiated water with the sanitary wastewater.
- Stormwater Management Systems -Impacted water has the potential to enter the any one of the three stormwater management systems and leak into groundwater through the associated catch basins, manholes and oil interceptor tanks: o Training Center Pond (NPDES Outfall 002) -Stormwater from the Power Block, several parking lots, the transmission yard and on-site ponds is routed via subsurface piping into the Training Center Pond. A stormwater outfall (NPDES Outfall 002) exits the southeast corner of the Training Center Pond to the marsh and ultimately discharges into the Toussaint River o Wastewater Treatment Plant (NPDES Outfall 601) -Treated wastewater from the sanitary wastewater plants exits the Wastewater Treatment Lagoon at NPDES Outfall 601, and then flows into the sump of the North Settling Basin. This has the potential of mixing with the water in North Settling Basin and back flowing into the Sanitary Wastewater Lagoon during periods when the discharge pumps are out of service and the North Settling Basin water level becomes high.o Service Building 4 -Stormwater from Service Building No. 4 and surrounding parking lots discharges to the marsh and ultimately Lake Erie.3.1.3 Non-radiological APCs Although the focus of the study is on potential radiological releases, the following areas were also identified as APCs for non-radiological constituents to impact groundwater quality: ERM/DADE MOELLER 7 FIRSTENERGY-DAVIS-BESSE 55194 1/16/07
- Diesel Storage Tanks -Three areas of diesel tanks represent non-radiological APCs.o A historic release of diesel fuel to soil occurred adjacent to the 100,000 gallon aboveground storage tank. This release resulted in the contamination of soil and shallow groundwater adjacent to the storage tank. Remedial activities (bioremediation and free product recovery) were conducted in response to the release.o Emergency Diesel Generator Fuel Oil Storage Tanks -Two 40,000 gallon tanks are present northwest of the Power Block.o Diesel Tank -One 6,000 gallon diesel tank is located within the Station Blackout Diesel Generator Building." Service Building No. 4 -This building is considered an APC due to the presence of an above ground gasoline storage tank and historical remedial activities related to overfilling of the tank.* Transformer Oil Collection Tank -Located north of the Power Block, an underground storage tank collects transformer oils.* Chemical Waste Storage Area -This area includes the temporary storage of drums and containers that are used to store hazardous waste and used oils including waste oil, oil filters, paints, solvents, Mineral Spirits (parts cleaner) and asbestos.* Machine Shop -Mineral spirits are used in the machine shop located at the ground level of the Personnel Shop Facility 3.2 TRITIUM DATA Historic tritium samples have been collected from potential source areas and from miscellaneous groundwater monitoring wells. Site features that represent large potential source areas of tritium include the following:
- Spent Fuel Pool -Tritium has been detected in a water sample collected from the Spent Fuel Pool at a concentration of 0.0552 microcuries per milliliter (pCi/ml).
For comparison to Environmental Protection Agency (EPA) drinking water standard of 20,000 pCi/L, this detection of 0.0552 ýtCi/ml converts to 55,200,000 picoCuries per liter (pCi/L), above the EPA standard.ERM/DADE MOELLER 8 FIRSTENERGY -DAVIS-BESSE 55194 1/16/07
- Borated Water Storage Tank -Tritium has been detected in a water sample collected from the Borated Water Storage Tank at a concentration of 80,000,000 pCi/L.In addition to the above contained potential sources, a known release of tritium occurred in 1997, when water pumped from North Settling Basin to the Collection Box was inadvertently spilled onto the ground surface adjacent to the Collection Box. The estimated volume of water that leaked onto the ground surface was approximately 12,000 gallons. The concentration of tritium that would have been leaked to groundwater during this event can be estimated from a water sample collected in North Settling Basin on 12 May 1997, which detected tritium at 6,850 pCi/L.Groundwater monitoring efforts have included two distinct events consisting of collecting samples from existing wells. In November and January 1991, groundwater samples were collected from seven wells located near the Hydrogen Addition System near the Borated Water Storage Tank following leakage of tritiated water onto the ground surface.It is not known which seven wells were sampled, or whether the samples were collected in wells installed in the shallow or deep Dolomite Bedrock.Tritium concentrations in these seven samples ranged from 250 pCi/L to 2,410 pCi/L, with an average concentration of approximately 1,000 pCi/L.In 2004, a groundwater sample from well MW-18, located south of the Spent Fuel Pool, Cask Pit and Fuel Transfer Canal (all located within Power Block APC) was collected to evaluate tritium concentrations in groundwater nearby these potential sources. It is uncertain whether the groundwater sample was collected from the well installed in the shallow or deep Dolomite Bedrock. Tritium was detected in the groundwater sample at concentrations of 667 +/- 112 pCi/L and 728 +/- 104 pCi/L, which average to a concentration of 698 pCi/L.3.3 SITE GEOLOGY AND HYDROGEOLOGY 3.3.1 Site Geology The DBNPS site geology is primarily composed of three units, consisting of the Glaciolacustrine, Till and Dolomite Bedrock (Tymochtee Formation).
Monitoring wells, test borings and piezometers installed during construction of DBNPS indicate the relative thickness and elevation intervals for each unit in the area of the Power Block: ERM/DADE MOELLER 9 FIRSTENERGY -DAVIS-BESSE 55194 1/16/07 Unit Approximate Depth Approximate Elevation Interval(s) Below Ground Range (feet above mean sea Surface (feet below ground) level)Glaciolacustrine 0 -10 feet 574 feet -564 feet Till 10 feet -20 feet 564 feet -554 feet Dolomite Bedrock 20+ feet 554 feet and below The hydrogeologic description of each unit is described below: " Glaciolacustrine Deposit -the shallowest unit that occurs naturally at ground surface, this deposit contains inter-bedded fine sand, clayey silt and silty clay. The Glaciolacustrine Deposit represents sediments of a complex, unconsolidated nature that were deposited within a temporary lake during recession of glacial ice from Lake Erie.* Till -located beneath the Glaciolacustrine deposit, Till consists of grey, silty clay and some sand. The base of the Till is characterized by a boulder layer, which is comprised of silty sand and boulders.* Dolomite Bedrock -located beneath Till, the Dolomite Bedrock consists of argillaceous dolomite that has been subdivided into two rock types: a massive dolomite and a laminated dolomite. The massive dolomite is approximately 8-10 feet thick of hard, fine grained dolomite and is present approximately 10 feet below the top of the dolomite. Laminated dolomite occurs above and below the massive dolomite, and consists of thinly interbedded intervals of gypsum, anhydrite and shale. The upper surface of the dolomite bedrock was removed in the area of the Power Block during Unit #1 construction, and geologic mapping of the exposed bedrock surface determined jointing in bedrock with orientations to the northeast (N45°E) and northwest (N50°W). Dolomite beds within the bedrock naturally dip to the south, with the angle of dip less than one degree.The surfaces of the Glaciolacustrine, Till and Dolomite Bedrock deposits slope towards Lake Erie.' Several marshes are located between DBNPS and Lake Erie, including the Navarre Marsh section of the Ottawa National Wildlife Refuge. The marshes represent flooded areas of vegetation. The elevation of water in the marshes is generally consistent with Lake Erie, except when FirstEnergy operates pumps to control the water level on behalf of the Wildlife Refuge. The marshes are separated from Lake Erie by dikes and a barrier beach along the shoreline of Lake Erie.ERM/DADE MOELLER 10 FIRSTENERGY -DAVIS-BESSE 55194 1/16/07 3.3.2 Site Hydrogeo logy Groundwater flow in the Glaciolacustrine and Till deposits has historically been considered insignificant. Preconstruction monitoring wells were installed only in the Dolomite Bedrock, indicating that regional groundwater flow in the Dolomite Bedrock is towards Lake Erie.Groundwater flow within the Dolomite Bedrock occurs within bedding planes, joints, fractures, lineaments and solution cavities. In order to understand the direction of groundwater flow in the Dolomite Bedrock, it is critical to understand the orientation of these structural features. The predominant orientation of bedrock fractures trend from southwest to northeast. The dip of the beds within the Dolomite Bedrock is less than one percent to the south.A lineament analysis (Figure 1) depicts the orientation and/or expression of linear features at ground surface that often mimic structures in the bedrock. Such linear features in bedrock can act as preferred migration pathways for groundwater flow and contaminant transport. Figure 1 shows that the majority of surface lineaments are orientated southwest-northeast; however, additional lineaments identified beyond the limits of Figure 1 are oriented southeast-northwest. The orientation is consistent with one of the joint orientations mapped during the preconstruction excavation. Preconstruction groundwater elevation data indicated that the depth to groundwater in the Dolomite Bedrock is 2-3 feet above the elevation of water in Lake Erie.During ERM's site walk of the DBNPS, historic monitoring wells were discovered at the property (Figure 3). These monitoring wells were historically used to measure groundwater levels within shallow and deep intervals of the Dolomite Bedrock to assess the effectiveness of a dewatering system which operated during plant construction. The dewatering system included a series of pumping wells to dewater excavation areas, a grout curtain (extending 60 feet into the Dolomite Bedrock) and recharge wells to inject water back into the Dolomite Bedrock. The monitoring wells were within and outside the limits of the grout curtain to assess the effectiveness and impacts of the dewatering system during excavation activities. Static (i.e., non-pumping) groundwater elevation data from these monitoring wells were last collected in November 1979. The static measurements, which could be used to anticipate current flow conditions (i.e., no ongoing dewatering and the grout curtain presumably remain), indicate a localized mound of high groundwater elevation beneath the Power Block. The mound is present in both shallow and deep bedrock ERM/DADE MOELLER 11 FIRSTENERGY -DAVIS-BESSE 55194 1/16/07 wells. Groundwater flow directions would be orientated in a radial pattern away from the mound. 0 The presence of a mound may be related to recharge to the Dolomite Bedrock beneath the Power Block, and the presence of the grout curtain around the Power Block. The grout curtain would essentially act to retard the outer movement of groundwater flow from the Power Block. Leakage through or under the grout curtain is expected, as the average dewatering rate inside the excavation area (i.e., inside the limits of the grout curtain)during construction of Unit #1 was 350 gallons per minute.The 1979 groundwater elevation data also indicates a downward component of vertical groundwater flow (i.e., flow from shallow to deep bedrock) beneath the Power Block. South of the Power Block, the groundwater elevation data indicates a component of upward flow from deep to shallow bedrock. Given the hydrogeologic position of the DBNPS adjacent to the regional groundwater discharge body (marshes and Lake Erie), it would be anticipated that upward groundwater flow from deep to shallow bedrock would be present across DBNPS under natural conditions. The presence of downward flow conditions beneath the Power Block is likely a reflection of recharge to the Dolomite beneath the Power Block and the grout curtain around the Power Block.3.4 SURFACE WATER AND GROUNDWATER USAGE Marshes and both located east-norteafvt of the .tation, are the primary dischargelocation for grouindwater at, DBNPS. Stormwater and surface ater at D'BNPS are rouited through three different outfallsinrto tihiemarshes east of DBNPS. Lake Erie is the source of drinking water supply for communities and residents within five miles of DBNPS. The intake closest to DBNPS is Carroll Township Water Plant, located at Locus Point, approximately 3 miles northwest of the site. Lake Erie is also actively used for swimming, fishing, and other recreational activities. The Carroll Township Water Plant was activated in 1998, and offers residences near DBNPS a reliable source of quality drinking water. The intake for the Carroll Township Water Plant is approximately 1,100 feet off Locus Point, which is located approximately two miles northwest of DBNPS. Based on the most recent Radiological Environmental Operating Report, the Ottawa County Health Department has verified that there are no registered drinking water wells within five miles of DBNPS. One well located in Sand Beach (approximately
1.5 miles
NW of DBNPS) is seasonally used as a source for non-drinking water. Historically, approximately 50 percent of the houses along Sand Beach used private ERM/DADE MOELLER 12 FIRSTENERGY -DAVIS-BESSE 55194 1/16/07 wells to obtain domestic water. Other historical wells in the vicinity of DBNPS include 18 wells located within 2-3 miles of the site at the time of plant construction. Water usage from these wells was for sanitary and farm irrigation. Water quality from these wells was considered poor (i.e., high levels of carbonate, total dissolved solids and hydrogen sulfide gas)and not suitable as a source of drinking water.The areas closest to DBNPS where water supply wells were identified in the USAR are highlighted on Figure 1. The current status of these wells is not known. The areas shown on Figure 1 are located upgradient or cross-gradient from the DBNPS, with the exception of the southwestern end of Sand Beach. Water supply wells in the southwestern end of Sand Beach could potentially be downgradient of DBNPS; however, these wells are reportedly in the shallow beach sands, rather than the Dolomite Bedrock.Based on the geographic position (i.e., upgradient) of a majority of wells and shallow construction of wells at Sand Beach, releases to groundwater at the DBNPS are expected to maintain a low potential to impact nearby wells, if still in use.ERM also obtained information on registered wells from the State of Ohio Department of Natural Resources Geographic Information System (GIS)database. The only wells identified in that database included additional domestic use wells located more than one mile west of DBNPS (upgradient of the DBNPS; Figure 1).3.5 CONCEPTUAL SITE MODEL 3.5.1 Overview This section presents a CSM to describe how potential releases of contaminants at DBNPS could enter the groundwater, how they may be transported in groundwater and where transport could result in hypothetical exposure to humans or environmental receptors. The CSM acts as a working hypothesis of possible contaminant migration pathways to aid in designing an effective monitoring well network that will ultimately identify and monitor for actual groundwater impacts. Results of successive phases of field investigation conducted during well installation and subsequent monitoring are used to adjust or calibrate the CSM for site-specific conditions until the CSM is in reasonable agreement with field data. The CSM thereby validates the processes used, increasing confidence that the results obtained are a reasonable characterization of site conditions and acts as a valuable tool in stakeholder communication. ERM/DADE MOELLER 13 FIRSTENERGY -DAVIS-BESSE 55194 1/16/07 3.5.2 Plan View The CSM begins with a plan view of the DBNPS and the juxtaposition of groundwater flow paths with potential radiological and non-radiological APCs (Figure 4). Although groundwater flow in the Glaciolacustrine and Till deposits was historically believed to be minimal, there is likely a component of flow within each geologic unit. Flow within these shallow units would be largely controlled by the presence of surface water bodies (i.e., ponds, marshes and Lake Erie), as these features represent groundwater discharge bodies. Since a majority of the DBNPS is largely paved and covered by buildings, recharge to these deposits would be highest in areas west of the Power Block. The potential for leakage from plant piping and storm drains beneath paved areas could result in direct recharge of water to the Glaciolacustrine and Till deposits, or to the structural fill where native deposits were excavated during plant construction. A significant component of the plan view CSM is the regional direction of groundwater flow in the Dolomite Bedrock and localized flow influenced by the Grout Curtain. Regional flow is east-northeast towards the marshes and Lake Erie, while localized flow beneath the Power Block is represented in a radial pattern, largely controlled by the grout curtain surrounding the Power Block. Figure 4 shows there is a component of groundwater flow to the west from the Power Block; however, the ultimate discharge sink for groundwater is the marshes and Lake Erie to the east.Potential APCs falling outside the Grout Curtain and within the influence of the regional flow system include the Dry Fuel Storage Area, Wastewater Treatment Plants, Condensate Dernineralizer Backwash Receiver Tank Discharge Line, Collection Box and Discharge Pipe, Secondary Demineralized Water Storage Tank, Fire Water Storage Tank, North and South Settling Basins. Groundwater migration beneath these APCs would theoretically flow towards the closest marsh, and ultimately Lake Erie.The Discharge Pipe (72-inch concrete pipe) represents a linear APC, which is generally aligned parallel to the direction of regional groundwater flow.Potential leakage from the Discharge Pipe would likely migrate into the earthen fill surrounding the buried pipe, ultimately migrating towards the marshes south of the Discharge Pipe.ERM/DADE MOELLER 14 FIRSTENERGY -DAVIS-BESSE 55194 1/16/07
3.5.3 Section
View The CSM includes a representation of potential radiological APCs in the context of the vertical hydrogeologic environment. The path of the cross section (shown in Figure 5) begins west of the Power Block and is orientated eastward through the Power Block. To highlight the elevation changes between the Power Block, intake canal, marshes and Lake Erie, gaps in the section were included through stretches of continuous sections of the swamp. The cross-section was developed using a 2:1 vertical exaggeration, as the vertical scale (1 inch equals 20 feet) is two times smaller than the horizontal scale (1 inch equals 40 feet). Figure 5 shows the base elevation of the excavation area, station buildings, native geologic units, excavation backfill units, existing monitoring wells, wave protection dikes and DBNPS infrastructure. The cross-section indicates that the excavation for the Power Block extends into the Dolomite Bedrock. The elevations of groundwater in the Dolomite Bedrock and Lake Erie are higher than the base elevation of buildings within the Power Block.Although DBNPS construction reports indicate that the Glaciolacustrine and Till units are not water bearing, ERM/ Dade Moeller's experience indicates that till can support groundwater flow and transport of contaminants. This characterization has been observed at other sites where the migration of tritium in a till aquifer occurred in a boulder layer located within a till. Boulder layers represent discrete intervals of higher hydraulic conductivity and porosity over bulk sediments within a till. An additional migration pathway for contaminants in till includes fractures within the till, which could develop in response to the rebound of land surface following the retreat of glacial ice that was responsible for deposition of the Glaciolacustrine deposit.Analysis of DBNPS excavation depths and building components (Figure 5) yields important considerations regarding the potential for leakage of radionuclides to the structural fill, Till and Dolomite Bedrock. These observations are summarized as follows: 0 Vertical migration of tritiated water to the structural backfill is possible where radiological sources within the Power Block immediately overlie the structural fill. (Figure 5). For example, leakage of tritiated water from the Borated Water Storage Tank and Condensate Demineralizer Backwash Receiver Tank or 3-inch Radwaste Discharge Line (not shown in Figure 5) could release radionuclides to the structural fill. Once in the structural fill, migration from these sources ERM/DADE MOELLER 15 FIRSTENERGY -DAVIS-BESSE 55194 1/16/07 would be anticipated towards the east, or potentially downward to the Dolomite Bedrock.* Vertical leakage from the 72-inch Discharge Pipe could result in leakage to the earthen backfill surrounding the concrete pipe. A release through the Discharge Pipe would be anticipated to ultimately migrate in a southeast direction towards the marsh adjacent to the Discharge Pipe." Vertical leakage directly to the Dolomite Bedrock is possible through releases at sumps and floor drains within the Containment Building, Auxiliary Building and Turbine Building that are constructed directly over Dolomite Bedrock. Migration from these potential sources would be anticipated to be outward from the Power Block, and possibly to deeper bedrock. Once in the Dolomite Bedrock and outside the influence of the Power Block and grout curtains, tritium would likely migrate to the east towards Lake Erie, corresponding with the direction of regional groundwater flow.3.5.4 Summary Potential releases of tritium from DBNPS are anticipated to migrate vertically or laterally within the fill (structural and earthen), Glaciolacustrine Deposit, Till and Dolomite Bedrock. Migration within these units would be towards marshes that are located between the Power Block and Lake Erie, with Lake Erie representing the regional groundwater discharge point. Initial evaluation of site systems, geology and hydrogeology suggest a low potential for releases to groundwater at the site to adversely impact drinking water receptors given the likely up-gradient, distant location of potential receptors and the most probable migration pathway being from the site to marshes and Lake Erie. Once in marshes and/or Lake Erie, the impacts would immediately be diluted due to the volume and concentration of naturally-occurring tritium in the lake.ERM/DADE MOELLER 16 FIRSTENERGY -DAVIS-BESSE 55194 1/16/07
4.0 RECOMMENDATIONS
Based on ERM and Dade Moeller's review of the available site data, the following recommendations are provided to support development of an effective groundwater monitoring program at the DBNPS: 1. Inventory and Monitor the Existing Well Network DBNPS has an extensive network of monitoring wells outside the Power Block. The wells, installed during excavation of Unit #1 and planned Units #2 and #3, provide a starting point for the development of a groundwater monitoring well network at the site. The existing monitoring wells should be inspected to evaluate their current condition and suitability for use as groundwater monitoring wells.Wells that are deemed suitable should be surveyed and then incorporated into the groundwater monitoring program. This work should be conducted prior to installation of additional monitoring wells to further guide the selection and placement of new wells. This evaluation should also focus on the extent to which existing wells may act as preferential pathways for contaminant migration to identify those wells that should be properly abandoned.
- 2. Develop an Integrated Monitoring Program DBNPS should consider developing a program to collect groundwater level measurements from suitable existing wells. The program should include monitoring on a quarterly basis, to evaluate the seasonal effects on groundwater flow elevations and directions.
In addition, the program should incorporate measurements of surface water in nearby marshes to fully integrate the groundwater and surface water interactions at DBNPS. The sampling of the surface water within each marsh, on-site ponds, and Lake Erie and gauging surface water and groundwater elevations simultaneously should also be incorporated into the sampling program.In order to evaluate the potential contribution of gaseous emission washout on tritium levels, DBNPS should monitor tritium in atmospheric water vapor and/or precipitation at indicator and control locations. This data should be combined with the monitoring program to develop and integrate knowledge of tritium discharges to groundwater. ERM/DADE MOELLER 17 FIRSTENERGY-DAVIS-BESSE 55194 1/16/07
- 3. Install and Sample Monitoring Wells The following table summarizes recommended locations and target units for potential installation of new groundwater monitoring wells for the DBNPS site. The wells are shown in Figure 4. The number of these locations selected for installation should be re-evaluated based on the inventory of existing wells and sampling and gauging results obtained and the results of additional site source evaluation.
Monitoring locations may need to be added or deleted as results are obtained and the CSM is refined.Well Location Construction and Rationale A West of Well Triplet Power Block" Shallow -monitor background conditions" Mid -monitor background conditions
- Deep -monitor background conditions B West of Well Triplet Power Block" Shallow -monitor Power Block" Mid -monitor Power Block" Deep -monitor Power Block C North of Well Triplet Power Block" Shallow -monitor Power Block* Mid -monitor Power Block" Deep -monitor Power Block D Northeast of Well Triplet Power Block" Shallow -monitor Power Block* Mid -monitor Power Block" Deep -monitor Power Block E East of Well Triplet Power Block" Shallow -monitor Condensate Demineralizer Tank Discharge Line, Radwaste Discharge Line and Power Block" Mid -monitor Condensate Demineralizer Tank Discharge Line, Radwaste Discharge Line and Power Block" Deep -monitor Power Block 18 FIRSTENERGY
-DAVIS-BESSE 55194 1/16/07 ERM/DADE MOELLER 18 F1IRSTENERGY -DAV&SBESSE 55194 1/16/07 Well Location Construction and Rationale F South of Well Triplet Power Block P Shallow -monitor Low Level Radwaste Storage Area and Power Block" Mid -monitor Low Level Radwaste Storage Area and Power Block" Deep -monitor Power Block G Northeast of Well Triplet Power Block" Shallow -monitor Power Block" Mid -monitor Power Block" Deep -monitor Power Block H Southeast of Well Triplet Power Block P Shallow -monitor Power Block" Mid -monitor Power Block* Deep -monitor Power Block Note: Shallow = Fill (structural or earthen), Glaciolacustrine or Till Mid = Shallow Dolomite Bedrock Deep = Deep Dolomite Bedrock The methodology for installing and constructing the monitoring wells should incorporate the latest environmental drilling technologies to allow for the collection of representative groundwater samples and to prevent the drilling activities from exacerbating any potential impacts to groundwater. For example, drilling successively deeper into the subsurface can result in advertent communication of shallow and deep aquifers if precautions are not incorporated into the drilling program.This cross-communication is also referred to as cross-contamination in the event that shallow contamination is brought to deeper depths that were previously not impacted. There are a variety of drilling techniques that could be utilized at the site that should be evaluated with regard to time, cost, integrity of well, ability to collect soil and groundwater samples during installation, minimization of worker exposure and generation of wastes requiring management and disposal.In addition to the monitoring wells, the following temporary grab groundwater samples are recommended to allow field screening of groundwater quality at each location: ERM/DADE MOELLER 19 FIRSTENERGY -DAVIS-BESSE 55194 1/16/07 Temporary Grab Groundwater Description and Rationale Location East of Outfall 3 One shallow grab sample -monitor Outfall 3 South of Eight Shallow samples -monitor 72-inch Concrete Discharge Line Discharge Line (grab samples collected every 100 feet along the length of the Discharge Line)East of North One shallow sample -monitor North Settling Basin Settling Basin East of South One shallow sample -monitor South Settling Basin Settling Basin East of Sanitary One shallow sample -monitor Sanitary Lagoon Lagoon East of Current One shallow sample -monitor the Current Sewage Sewage Treatment Plant Treatment Plant Training Center Two shallow samples -monitor the Training Center Pond Pond Temporary grab groundwater samples are collected using a discrete interval drive point sampler to allow collection of shallow groundwater samples for laboratory analysis. The technology is very effective as a screening tool for evaluating groundwater quality in areas of low likelihood of groundwater impact and over a larger area (i.e. approximately 800 feet of Discharge Line). The screening data from the grab groundwater samples is used to focus later investigations, including the installation of permanent monitoring wells.During the field component of the groundwater investigation program, the intervals for monitoring well screens and depths for grab samples should be based on field observations and testing conducted during boring advancement. Since geologic deposits are inherently heterogeneous, the depth of well screens and sample depth should correspond with the most permeable intervals, rather than a predetermined depth. The ability to adapt and modify screen settings and target depths based on field data will allow for a representative well network for monitoring potential inadvertent releases.4. Develop a Quality Assurance Project Plan All the components of a groundwater monitoring program should be addressed in a Quality Assurance Project Plan (QAPP) specifically ERM/ DADE MOELLER 20 FIRSTENERGY-DAVIS-BESSE 55194 1/16/07 designed to address potential groundwater issues at the site. DBNPS monitoring programs (i.e., REMP and tritium tracking) should have consistent Lower Levels of Detection (LLDs) and reporting criteria.Consideration should be given to the required sensitivity for tritium monitoring in groundwater. DBNPS monitors to 330 pCi/L, and the State of Ohio monitors to 300 pCi/L. Looking forward to public communication of the new groundwater monitoring data, it would be prudent to coordinate the sensitivities of the measurements so as to make data comparable among the stakeholders. It may also be prudent to report some data in dual units (i.e., ptCi/ml and pCi/L) to facilitate comparisons and eliminate confusion.
- 5. Define Internal and External Reporting Requirements As data are collected, it is important that the thresholds and timeframes for internal and external reporting purposes be clearly defined. A written summary of the internal and external reporting requirements, including NRC, NEI and State of Ohio criteria, for all parameters that will be monitored should be developed to support the implementation of the groundwater monitoring program. The reporting requirements should be applied consistently across FirstEnergy's three nuclear power plants.6. Develop a Communication Plan Stakeholder communication is a key component of the NEI initiative.
Therefore, a communication plan should be developed to identify and define the stakeholders related to the tritium in groundwater issue and to determine who is responsible for the various types of communication and how the results will be communicated. As with the reporting requirements, the communication plan should be developed consistently across FirstEnergy's three nuclear power plants.ERM/DADE MOELLER FIRSTENERGY -DAVIS-BESSE 55194 1/16/07 ERM/DADE MOELLER 21 FIRSTENERGY -DAVIS- BESSE 55194 1/16/07 Tables Table 1 Areas of Potential Concern Davis-Besse Nuclear Power Station Oak Harbor, OH Category Area of Potential Concern Radiological -Power Block Containment Building Auxiliary Building Miscellaneous Waste Drain Tank Spent Fuel Pool Cask Pit Turbine Building East and West Condenser Pits Sumps Condensate Demineralizer Tanks Fuel Transfer Canal Circulating Water Pump House Borated Water Storage Tank Nitrogen and Hydrogen Supply Piping Radiologial -Outside Power Block Condensate Demineralizer Tank Discharge Line Liquid Radwaste Discharge Line Collection Box Collection Box Discharge Pipe South Settling Basin (Settling Basin No. 1)North Settling Basin (Settline Basin No. 2)Low-Level Radwaste Storage Building Dry Fuel Storage Area Secondary Water Demineralized Water Storage Tank Fire Water Storage Tank Sanitary Wastewater Plants Stormwater Management System NPDES Outfall 002 (Training Center Pond)NPDES Outfall 601 (Wastewater Treatment Plant)Service Building No. 4 Non-Radiological Diesel Storage Tanks Service Building No. 4 (Gasoline Tank)Transformer Oil Collection Tank Chemical Waste Storage Area Machine Shops 0 Tables 0 0 Table 1 Areas of Potential Concern Davis-Besse Nuclear Power Station Oak Harbor, OH Category Area of Potential Concern Radiological -Power Block Containment Building Auxiliary Building Miscellaneous Waste Drain Tank Spent Fuel Pool Cask Pit Turbine Building East and West Condenser Pits Sumps Condensate Demineralizer Tanks Fuel Transfer Canal Circulating Water Pump House Borated Water Storage Tank Nitrogen and Hydrogen Supply Piping Radiologial -Outside Power Block Condensate Demineralizer Tank Discharge Line Liquid Radwaste Discharge Line Collection Box Collection Box Discharge Pipe South Settling Basin (Settling Basin No. 1)North Settling Basin (Settline Basin No. 2)Low-Level Radwaste Storage Building Dry Fuel Storage Area Secondary Water Demineralized Water Storage Tank Fire Water Storage Tank Sanitary Wastewater Plants Stormwater Management System NPDES Outfall 002 (Training Center Pond)NPDES Outfall 601 (Wastewater Treatment Plant)Service Building No. 4 Non-Radiological Diesel Storage Tanks Service Building No. 4 (Gasoline Tank)Transformer Oil Collection Tank Chemical Waste Storage Area ,Machine Shops Figures 0 Legend Reside ntiallCom mercia I Wl11s Unknonm! Domestic () PubicWater Supply(non potable)Aea wth Private Wels Protected Area SSite Boundary Lneaments SOURCE: USGS Topographic Quadrangles (o41083e2, o41083el)1:24,000 0 2,000 4,000 ,m m IFeet Figure 1 -Site Locus Map with Hydrogeologic Features Davis-Besse Nucear Pover Station, Oak Harbor, OHw ERM I Emergency Diesel Fuel-il T.ank Se-ndary Demineralized Wae t aeTank Condensate Demineralze JTan k Dischargle Line Legend 71i Radiological Area of Potential Concern Non-Radiological Area of Potential Concern-Cross-section Ihe Low Leve I Rad Waste Storage Buildw c Collection Box Di.,rhwrae Pinee 1:3,000 bandc 0 125 250 500 750-ý Feet Tra ning Center Pond NPDES Outfall002 i C C Figure 2 -Areas of Potential Concern at Davis-Besse Nuclear Power Station Davis-Besse Nuclear Poer Statbn, Oak Harbor, 0 hR.\m 0 0 0 Legend Limits of Grout Curtain 4& Existing Monitoring Well Couplet (Shallow and Deep Bedrock)1:2,400 200 100 0 200 F= !Feet Figure 3 -Existing Monitoring Wels and Grout Curtain Davis-Besse Nuclear Power Station, Oak Harbor, OH i~.RM m I .0 "AlLegend SRadiological Area of Potential Concern Non-Radiological Area of Potential Concern Limits of Grout Curtain A "'Proposed Moni toring Wei 0 Proposed Grab Groundwater Sample Regional Groundwater Flow Direction in Dolomite Bedrock , Localized Groundwater Flow Direction Adjacent to Power Block 1:3,000 250 125 0 250 I Feet r ~Figure 4 -Conceptual Site Model and Proposed Monitoring Locations Davis-Besse Ntclear Power Station, Oak Harbor, OH
- 0 West East... ----- -, :-- ----------
Legend I G.nd fldWote evatio (Dolo. slle Bedrck)ExIsthig W Potontol atod of Treted Woter Fbw o.t Groud Wmlet P~psedMoohtodngWd .P p o*ee G rab G , = n d W a tb r S a rff l 1,W 0 fte Figure 5 -Conceptual Site Model -Section View 0e 2Davis-Besse Nuclear Power Station, Oak Harbor, OH ERM N Appendix A Letter from Davis-Besse Engineering Response to the prescribed questions and to identify those Davis-Besse systems/components which are vulnerable to initiating an unmonitored release to the environment: Question #1 -For those contaminated systems within structures, explain the design and operation of the sump/liquid waste system. This description should provide reasonable assurance that any system leakage will be properly contained and processed prior to its release to the environment. Response #1 Sumps in the Auxiliary building collect liquid from floor and equipment drains in rooms containing contaminated systems. All sumps discharge to the miscellaneous waste drain tank (MWDT). There are several areas with the auxiliary building that contain floor drains which discharge directly to the MWDT without going into a sump. These rooms in the auxiliary building contain systems that interface directly with the reactor coolant system. The systems are High Pressure Injection, Low Pressure Injection/Decay Heat, Decay Heat Coolers, Containment Spray, and the Makeup System. Leakage from any of these systems will therefore be contained in the MWDT. Liquids collected there are processed as described below.The detergent waste drain tank (DWDT) is also located within contaminated areas. It receives influent from the laundry facility and various other floor drains in the auxiliary building. This tank discharges to the miscellaneous waste monitor tank and is processed as described below.A past primary to secondary coolant leak has cause the station to conservatively declare all feedwater, condensate, and auxiliary steam systems in the turbine building as potentially contaminated. Therefore, all rooms containing these systems are considered potential sources of contaminated water leakage into the turbine building sumps and drains system.The Component Cooling Water (CCW) System Heat Exchangers are cooled by the Service Water (SW) System. Due to past leakage from the Letdown Coolers, the CCW system is considered to be contaminated. If a leak were to develop in the CCW Heat Exchangers, the contamination could reach Lake Erie through the discharge from the Collection Box. The Collection Box discharge line contains a radiation monitor. Any leakage from the CCW System would be identified by loss of inventory in the CCW Surge Tank.Question #2 -Describe the normal liquid effluent pathway, including the downstream discharge pathway such as circulating water or river water.Response #2 Question 2.a -Where does the liquid waste discharge to? Response 2.a -Sumps in located throughout the plant collect drainage from equipment and floor drains and discharge to one of several places: (1) Turbine Building East and West Condenser Pits -These sumps are routed to the settling basins. The settling basins are sampled and are released to the collection box outfall to Lake Erie. Weekly samples are taken using procedure DB-CN-04039 to insure radioactivity is within applicable limits including a tritium analysis. A list of potential tritium sources is attached.(2) Turbine Building -Sumps and drain risers discharge to the storm sewer system which goes to the training center pond, a marsh pond, and ultimately to the Touissaint River. The inlet to the training center pond and the marsh pond are sampled weekly for tritium and other radioactivity. A list of potential tritium sources is attached.(3) Auxiliary building -Sumps that are in contaminated/radioactive areas discharge to the miscellaneous waste drain tank (MWDT). This tank is processed to the miscellaneous waste monitor tank (MWMT) through a demineralizing skid. It is then recirculated in the MWMT and sampled in accordance with 1OCFR20, the Offsite Dose Calculation Manual, and Operations Procedure DB-OP-03011. When it is determined acceptable, the liquid is discharged to the collection box outfall to Lake Erie. A composite sample from each batch release is collected in accordance with DB-OP--0301 1, Radioactive Liquid Batch Release, Step 4.18.3 for monthly tritium analysis as required by DB-CN-03012, Liquid Releases, Monthly Monitoring Analysis. The monthly composite is analyzed in accordance with DB-CH-0 1804, Tritium Determination, to achieve a Lower Limit of Detection of I x 10-5 uCi/ml. The tritium activity from the composite sample is entered into the RETSCode program which calculates the tritium released for each batch release for the month.Question 2.b -Does the liquid waste discharge line traverse any non-license owned areas?Response 2.b -The liquid waste discharge line is contained on the licensee owned properties. Reference drawings: C-46, C-49 and C-52 Question 2.c -Are there any vacuum breakers or relief valves on the discharge piping and are they monitored for potential leakage?Response 2.c -There are no vacuum breakers or relief valves on the discharge piping.Question # 3 -Provide a description of the spent fuel pool, including liner construction and leakage monitoring. Identify any vulnerability to an unmonitored release. Response # 3 -A description of the spent fuel pool, including liner construction and leakage monitoring is as follows: The SFP stores irradiated fuel assemblies under water. The spent fuel racks are sized to store 1624 spent fuel assemblies. The SFP is connected to the Fuel Transfer Canal via an 80001b gate and gateway. An identical gate arrangement exists between the SFP and the Cask pit. The Fuel Transfer Canal is connected to the refueling canal via two 30-inch-outer diameter fuel transfer tubes. The SFP is flooded to 23 feet of water over the top of the irradiated fuel assemblies seated in the storage racks (pool surface Elevation 601' 6").The spent fuel pool, fuel transfer pit, cask pit, liners, and all supporting structures are designed for seismic loads.The 5' thick south wall of the Spent Fuel Pool (SFP) and Cask Pit (CP) form the outside wall of the Auxiliary Building. Much of the flooded portion of the SFP and CP are below grade and not visible. There is a waterproof membrane on this outside wall and under the building foundation (ref. DWG C-202 and C-230) to keep outside groundwater from leaching into the Auxiliary Building. This membrane would also likely act to keep any potential fuel pool leakage from escaping into the soil.The fuel pool, fuel transfer pit, and cask pit are lined with stainless steel and equipped with a leak chase system and tell-tale drain connections for leakage detection. Procedure DB-SP-04400, Spent Fuel Pool, Fuel Transfer Pit, and Cask Pit Leak Detection System Test, is performed monthly to quantify a leak rate from the 21 leak chases. Leakage is detected during this monthly test from several of the leak chases. The highest leak rate is approximately 1.5 ml/min.Tritium concentration in the SFP is 0.0552 uCi/mL based on the latest sample. A groundwater sample was obtained from an existing monitoring well located near the south wall of the SFP in 2004. The test results using site equipment were inconclusive as the values measured were at the minimum detectable levels of the site's equipment. A portion of this sample was sent off-site and tested by Environmental Inc. The values were 667 +/- 112 pCi/L and 728 +/- 104 pCi/L. These values are substantially below those measured at other plants with known fuel pool leakage. A PM activity was created to perform sampling from this monitoring well every 5 years.Question # 4 -Identify those contaminated tanks, below above and below grade, located outside of plant structures (i.e., outside of plant drainage/sump system). Identify the run-off pathway to the environment. Response # 4 -The following tanks are contaminated tanks, located outside of plant structures with the run-off pathways to the environment identified: The Borated Water Storage Tank (BWST) is a contaminated tank above grade and located outside of plant structures. The tank base is surrounded by gravel. Tank overflow is routed to the Miscellaneous Waste Drain Tank. Tank leakage would be onto to the gravel and into the ground surrounding the tank. Some tank leakage may be collected into the storm sewer system and directed to the Training Center pond and, ultimately, into the Touissaint River. Tritium concentration in the BWST is 0.08 uCi/mL based on the latest sample.The Demineralized Water Storage Tank and Fire Water Storage Tank are above grade and located outside of plant structures. Both are provided with steam heaters to maintain temperature during winter months. The steam provided to these heaters is contaminated. If a leak were to develop in the heater, the water in the tank could become contaminated. Tank overflow or leakage would be onto to the pavement or gravel and into the ground surrounding the tank. Some tank leakage may be collected into the storm sewer system and directed to the Training Center pond and, ultimately, into the Touissaint River.Several small pipes connect the nitrogen and hydrogen supply systems to various contaminated systems and components (P&ID M-0 19 and 044). The nitrogen and hydrogen supply tanks are located outside of plant structures. Back leakage through valves could result in contaminated water entering these pipes. Leakage of this contaminated water from these pipes would be onto the gravel or into the ground. Some pipe leakage may be collected into the storm sewer system and directed to the Training Center pond and, ultimately, into the Touissaint River. ERM has over 100 offices Across the following countries worldwide.Argentina Australia Azerbaijan Belgium Brazil Canada Chile China France Germany Hong Kong Hungary India Indonesia Ireland Italy Japan Kazakhstan Korea Malaysia Mexico The Netherlands Peru Poland Portugal Puerto Rico Russia Singapore South Africa Spain Sweden Taiwan Thailand UK US Vietnam Venezuela ERM's Boston Office 399 Boylston Street, 6th Floor Boston, MA 02116 (617) 646-7800 (617) 267-6447 (fax)ERM ERM consulting services worldwide www.erm.com x to FirstEnergy Groundwater Monitoring Well Installation & Monitoring Report Davis-Besse Nuclear Power Station Oak Harbor, Ohio FirstEnergy Nuclear Operating Company 18 March 2008 www.erm.com ERM Delivering sustainable solutions in a more competitive world I FINA REPOR FirstEnergy Nuclear Operating Company Groundwater Monitoring Well Installation & Monitoring Report Davis-Besse Nuclear Power Station Oak Harbor, Ohio 18 March 2008 ERM Reference 0065992.2 Gregg Demers, P.E., LSP Principal-in-Charge ~ ~1 k~$(~~Matthew Daly, P.G.Project Manager Environmental Resources Management 399 Boylston Street, 6th Floor Boston, Massachusetts 02116 T: (617) 646-7800 F: (617) 267-6447 TABLE OF CONTENTS EXECUTIVE
SUMMARY
1
1.0 INTRODUCTION
1
1.1 BACKGROUND
1 1.1.1 Site History 1 1.1.2 Prior Findings 2 1.2 PURPOSE & SCOPE 3 1.3 REPORT ORGANIZATION 4 2.0 METHODOLOGY 5 2.1 INVENTORY & MONITORING OF HISTORIC WELLS 5 2.1.1 Well Inventory & Gauging 5 2.1.2 June 2007 Groundwater Monitoring Event 5 2.2 JULY/AUGUST 2007 GROUNDWATER MONITORING EVENT 7 2.3 WELL INSTALLATION 8 2.3.1 Overview 8 2.3.2 Advancement of Soil Borings 9 2.3.3 Monitoring Well Construction 9 2.3.4 Monitoring Well Development 10 2.4 SEPTEMBER/OCTOBER 2007 GROUNDWATER MONITORING ACTIVITIES 10 2.5 SURVEYING 12 2.6 DATA USABILITY ASSESSMENT 13 3.0 RESULTS 14 3.1 SITE GEOLOGY 14 3.2 HISTORIC WELL INVENTORY 15 ERM/ DADE MOELLER i FIRSTENERGY -DAVIS-BESSE 65992.2 18 MARCH 08 3.3 NEW MONITORING WELLS 3.4 GROUNDWATER FLOW 3.5 GROUNDWATER QUALITY 3.5.1 Groundwater Field Parameters
3.5.2 Analytical
Results 3.5.3 Tritium Source Assessment UPDATED CONCEPTUAL SITE MODEL KEY FINDINGS 15 0 16 19 19 20 22 24 25 4.0 5.0 ERM/DADE MOELLER ii FIRSTENERGY -DAVIS-REESE 65992.2 18MARCH08 ERM/DADE MOELLER ii FIRSTENERGY -DAVIS-BESSE 65992.2 18 MARCH 08 LIST OF TABLES TABLE 1 MONITORING WELL LOCATION AND CONSTRUCTION
SUMMARY
TABLE 2
SUMMARY
OF SAMPLING PROGRAM -JUNE, JULY/AUGUST AND SEPTEMBER/OCTOBER 2007 TABLE 3
SUMMARY
OF ANALYTICAL PROGRAM -JUNE, JULY/AUGUST, AND SEPTEMBER/OCTOBER 2007 TABLE 4
SUMMARY
OF GROUNDWATER GAUGING DATA TABLE 5
SUMMARY
OF GROUNDWATER FIELD PARAMETERS TABLE 6
SUMMARY
OF GROUNDWATER ANALYTICAL RESULTS ERM/DADE MOELLER oo°FIRSTENERGY -DAVIS-BESSE 65992-2 18 MARCH 08 LIST OF FIGURES FIGURE 1 SITE LOCUS MAP FIGURE 2 FIGURE 3 FIGURE 4 FIGURE 5 FIGURE 6 FIGURE 7 FIGURE 8 SITE LAYOUT GROUNDWATER ELEVATIONS TILL UNIT- SEPTEMBER/OCTOBER 2007 GROUNDWATER ELEVATIONS UPPER DOLOMITE -SEPTEMBER/OCTOBER 2007 GROUNDWATER ELEVATIONS LOWER DOLOMITE -SEPTEMBER/OCTOBER 2007 GROUNDWATER SAMPLE ANALYTICAL RESULTS JUNE TO AUGUST 2007 GROUNDWATER SAMPLE ANALYTICAL RESULTS SEPTEMBER/OCTOBER 2007 CROSS-SECTION SHOWING GROUNDWATER ELEVATIONS AND SAMPLE ANALYTICAL RESULTS ERM/ DADE MOELLER iv FIRSTENERGY -DAVIS-BESSE 65992.2 18 MARCH 08 LIST OF APPENDICES APPENDIX A BORING LOGS APPENDIX B DATA ASSESSMENT -JUNE & JULY/AUGUST 2007 MONITORING EVENTS APPENDIX C DATA ASSESSMENT -SEPTEMBER/OCTOBER 2007 MONITORING EVENT APPENDIX D LABORATORY ANALYTICAL REPORTS V FIRSTENERGY -DAVIS-BESSE 659922 18 MARCH 08 ERM/DADE MOELLER V FIRSTENERGY -DAVIS-BESSE 65992 2 18 MARCH 08 LIST OF ACRONYMS APC radiological area of potential concern ASL above sea level CSM conceptual site model 0 C degrees Celsius DBNPS Davis-Besse Nuclear Power Station DO dissolved oxygen EPA United States Environmental Protection Agency ERM Environmental Resources Management FD field duplicate FENOC FirstEnergy Nuclear Operating Company FSP field sampling plan NEI Nuclear Energy Institute MDC minimum detectable concentration NTU nephelometric turbidity unit ORP oxidation-reduction potential PID photoionization detector pCi/L picoCuries per liter PVC polyvinyl chloride QA/QC quality assurance/quality control R rem REMP Radiological Environmental Monitoring Program us/cm microsiemens per centimeter ERM/DADE MOELLER vi FIRSTENERGY -DAViS-BESSE 65992.2 18MARCH08 ERM/ DADE MOELLER vi FIRSTENERGY -DAViS-BESSE 65992.2 18 MARCH 08 EXECUTIVE
SUMMARY
On behalf of FirstEnergy Nuclear Operating Company (FENOC), Environmental Resources Management (ERM) has prepared this Groundwater Monitoring Well Installation and Monitoring Report to document the development of a groundwater monitoring program at the Davis-Besse Nuclear Power Station (DBNPS) located in Oak Harbor, Ohio.The purpose of the groundwater program is to assess whether there have been any inadvertent radiological releases from the Power Block that may have impacted site groundwater or have the potential to migrate toward Lake Erie or any other human or environmental receptor.Activities completed included an inventory and assessment of existing site wells, the installation of five groundwater monitoring well triplets and a water table well (i.e., 16 new wells), the preparation of groundwater field sampling plans, the sampling of groundwater monitoring wells (three events), and the evaluation of groundwater monitoring results in the context of the hydrogeologic regime.The key findings from the groundwater investigation include the following: Geology* The surficial geology beneath the DBNPS consists of Glaciolacustrine and Till units. The Glaciolacustrine unit is characterized as cohesive, brown silt with some sand and clay. The Till is characterized as brown to dark-gray, silty clay.* Beneath the Till is Dolomite Bedrock, subdivided into a Laminated Dolomite and a Massive Dolomite. The Laminated Dolomite, which is encountered above and below the Massive Dolomite, contains thin layers of interbedded dolomite, gypsum, anhydrite and shale. The Massive Dolomite is approximately 10 feet thick, hard, finely grained, and located approximately 10 feet below the top of the Dolomite.Historic Well Inventory A total of 54 wells (27 couplets) were located and inspected during the well inventory and 24 wells (12 couplets) could not be found.Each well couplet consists of a shallow and deep well within the ERM/DADE MOELLER ES-1 FIRSTENERGY -DAV&BESSE 65992.2 18 MAR 08 Dolomite Bedrock. The shallow bedrock well is screened within the Upper Dolomite and the deeper bedrock well is screened in the Lower Dolomite. The Massive Dolomite unit separates wells screened within the Upper and Lower Dolomite.The historic wells, by themselves, were not sufficient to create an effective groundwater monitoring program at DBNPS because they did not provide adequate lateral and vertical coverage. In addition, due to the age of the wells, their construction quality and subsurface conditions are not known.Groundwoater Flow" The ability to develop groundwater elevation contours and flow patterns is complicated by several factors, including the presence of a grout curtain, the flow of groundwater within discrete fractures in bedrock, the large area of excavated bedrock beneath the Power Block and the high degree of mineralized groundwater and associated low yield observed in the new Lower Dolomite wells.An additional uncertainty is the usability of historic elevation survey data that were used to calculate groundwater elevations from the historic wells." Based on the distribution of groundwater elevations, groundwater flow in the Till, Upper Dolomite and Lower Dolomite units is from west to east across the site.* The ultimate discharge point for groundwater in the Till, Upper Dolomite and Lower Dolomite is the marshes and/or Lake Erie east of the Power Block.Groundwater Quality" Strong hydrogen sulfide odors were noted in site groundwater, particularly new Lower Dolomite wells MW-101C, MW-102C, MW-103C and MW-104C located east of the Power Block. The hydrogen sulfide is believed to be naturally occurring and caused by the weathering of gypsum and anhydrite minerals. Groundwater field parameters at these wells are characterized by high specific conductance, low ORP and high turbidity water." High hydrogen sulfide gas levels at wells MW-101C, MW-102C, MW-103C and MW-104C may be inadvertently trapped due to the use of expansion plugs at these wells. The sulfide gas may limit the ERM/DADE MOELLER ES-2 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08 ability for the well screen to communicate with the Lower Dolomite. Future modifications to the expansion plugs to allow venting of the sulfide gas will be evaluated in effort to obtain more accurate groundwater elevation data from these wells.Reported concentrations of tritium in groundwater between 178 pCi/L and 348 pCi/L represent statistically insignificant activity at the 95% confidence level and are considered representative of local background conditions. Factors influencing local background condition may include the historic atmospheric bomb testing program, cosmic ray interactions in the earth's atmosphere and localized washout from continuous and batch gaseous releases from DPNBS. Reported values above 348 pCi/L represent concentrations that are statistically greater than local background conditions." Tritium concentrations above the 348 pCi/L background value were located primarily in monitoring wells east of the Power Block.* Tritium concentrations in the wells screened in the Till ranged from less than the minimum detectable concentration (MDC; <193 pCi/L) to 1,832 pCi/L. The highest concentrations were detected down-gradient (northeast) of the Power Block, including MW-102A (387 pCi/L), MW-103A (495 pCi/L), and MW-105A (1,832 pCi/L)." Tritium concentrations in the wells screened in the Upper Dolomite ranged from less than the MDC (<193 pCi/L) to 7,535 pCi/L. The highest concentrations were detected down-gradient (east) of the Power Block, including MW-31S, MW-32S, MW-33S, MW-34S, MW-37S and MW-30S. Two detections above local background conditions were detected at well MW-30S (1,307 pCi/L) and well MW-37S (2,961 pCi/L), located north of the Power Block.* Tritium concentrations in the wells screened in the Lower Dolomite ranged from less than the MDC (<193 pCi/L) to 3,271 pCi/L. The highest detections were located east/southeast of the Power Block, including wells MW-33D, MW-34D and MW-12D.* No gamma emitting radionuclides were detected above MDC in any of the groundwater samples collected during the June, July/August 2007 or the September/October 2007 monitoring events.ERM/DADE MOELLER ES -3 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08
- Tritium concentrations in groundwater during the June, July and August and September/October 2007 monitoring events were below the Environmental Protection Agency's drinking water standard of 20,000 pCi/L.Updated CSM" Groundwater flow within the Till, Upper Dolomite and Lower Dolomite units at DBNPS is generally from west to east toward Lake Erie with groundwater discharge to the marshes and/or Lake Erie." Potential inadvertent releases from within the Power Block, including the Spent Fuel Pool, would migrate vertically down through the unsaturated zone to the water table. Potential releases from structures below ground could release tritium directly to the Upper or Lower Dolomite unit.* Elevated detections in Upper Dolomite wells MW-31S and MW-32S are located on reported southwest to northeast fractures that project back to the Power Block." Tritium in groundwater will ultimately migrate into Lake Erie, where the concentrations will be diluted due to the volume of groundwater discharge versus the volume of water in the lake." Historic monitoring of Lake Erie by DBNPS indicates that there have been very few detections of tritium above local background conditions, and they are not likely to have been caused by groundwater contributions.
Based upon the above findings, FirstEnergy should further evaluate the hydrogeology and influence of plant features on site groundwater flow.In addition, tritium detections above local background conditions should be evaluated to establish a reliable monitoring well network for long-term monitoring. ERM/DADE MOELLER ES-4 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08
1.0 INTRODUCTION
On behalf of FirstEnergy Nuclear Operating Company (FENOC), Environmental Resources Management (ERM) has prepared this Groundwater Monitoring Well Installation and Monitoring Report to document the development of a groundwater monitoring program at the Davis-Besse Nuclear Power Station (DBNPS) located in Oak Harbor, Ohio (Figure 1).The groundwater monitoring program was implemented to comply with the Nuclear Energy Institute's (NEI) Groundwater Protection Initiative, dated August 2007. The Groundwater Protection Initiative was developed to enhance the detection, management and communication of inadvertent radiological releases to groundwater at nuclear power plants. As part of the initiative, nuclear power plants are expected to: "Put in place a company/site-specific action plan(s) to help assure timely detection and effective response to situations involving inadvertent radiological releases in groundwater to prevent migration of licensed radioactive material off-site and quantify impacts on decommissioning." (NEI, May 2006).As a first step toward the completion of its action plan, FENOC hired ERM and Dade Moeller & Associates (Dade Moeller) in 2006 to conduct an evaluation of potential radiological sources and groundwater flow at DBNPS. Results of this study were presented in a report titled Groundwater Flow Characteristics Report -Davis-Besse Nuclear Power Station, Oak Harbor, Ohio (ERM, 16 January 2007). The January 2007 report provided an overview of DBNPS physical features, plant operating infrastructure, potential areas of radiological releases, available tritium data and site hydrogeology.
1.1 BACKGROUND
1.1.1 Site History DBNPS consists of a pressurized water reactor unit that was constructed in the 1970s and went on-line in November 1977. The facility is located on a 954-acre parcel of land that abuts a National Wildlife Refuge and Lake Erie. An intake canal, which provides cooling and process water to ERM/DADE MOELLER 1 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08 DBNPS, is located 250 feet east of the Power Block and is hydraulically connected to Lake Erie.1.1.2 Prior Findings The Groundwater Flow Characteristics Report presented a Conceptual Site Model (CSM) describing potential source areas, migration pathways and both human and environmental receptors at DBNPS. The CSM considered site physical features and included the following key findings: 1. Radiological areas of potential concern (APCs) at DBNPS, defined as locations where a release of radionuclides to groundwater has, or could occur, include the Power Block, Low Level Radiological Waste Storage Building, Dry Fuel Storage Area, Training Center Pond NPDES Outfall 002, Sewage Treatment Plants (abandoned and operating), NPDES Outfall 001, Sanitary Lagoon, North and South Settling Basins, Collection Box Discharge Pipe, Collection Box, Liquid Radwaste Discharge Line, Condensate Demineralized Water Storage Tank, Secondary Demineralized Water Storage Tank, Fire Storage Tank, and Service Building 4 Outfall (Figure 2).2. Inadvertent releases from DBNPS have the potential to migrate vertically through the fill (structural or earthen), Glaciolacustrine unit, Till unit and Dolomite Bedrock.3. The basement of buildings within the Power Block extends down into excavated portions of the Dolomite Bedrock. Potential inadvertent releases at depth from within the Power Block could discharge directly to the Dolomite Bedrock.4. Regional groundwater flow is from west to east-northeast towards the marshes and Lake Erie. The ultimate discharge sink for groundwater is the marshes and Lake Erie east of the property.5. Initial evaluation of site systems, geology and hydrogeology suggest a low potential for releases to groundwater at the site to adversely impact drinking water receptors given the likely up-gradient, distant location of potential receptors and the most probable migration pathway being from the Power Block to the marshes and Lake Erie.6. Concentrations of tritium in groundwater would be diluted at the marsh and Lake Erie due to the large volume of surface water relative to the volume of groundwater discharge. ERM/DADE MOELLER 2 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08
1.2 PURPOSE
& SCOPE The purpose of this Groundwater Monitoring Well Installation and Monitoring Report is to document the development of a groundwater monitoring program at DBNPS. The groundwater monitoring program is intended to assess whether any inadvertent release from the Power Block has the potential to migrate toward the adjacent marshes and/or Lake Erie or any other human or environmental receptor. The program was implemented using a phased approach, including the use of historic and new wells to collect groundwater samples. The intrusive investigations followed an outside-in, top-down approach to address gaps identified in the CSM.The following activities were completed during development of the groundwater monitoring program: " inventory of historic wells;" preparation of groundwater field sampling plans;" screening and confirmatory groundwater sampling of historic monitoring wells;* installation of five well triplets and a water table well (i.e., 16 new wells);" groundwater sampling of comprehensive monitoring well network (three rounds);* survey of well reference measuring points for determination of groundwater elevations;
- evaluating groundwater elevations and flow directions; and* evaluating groundwater monitoring results in the context of the hydrogeologic regime.The groundwater monitoring program was developed using a team of contractors, including the following:
- BETA Laboratory
-FirstEnergy's in-house provider of field personnel to collect groundwater samples;ERM/DADE MOELLER 3 FIRSTENERGY -DAVIS-BESSE 65992.2 18MAR08 ERM/DADE MOELLER 3 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08
- Bowser-Morner, Inc. -Well drilling service provider under contract 5 with FirstEnergy to advance, construct and develop groundwater monitoring wells;* ERM -FirstEnergy's provider of groundwater and hydrogeologic consulting services.
Dade Moeller provided data evaluation and technical support under subcontract to ERM; and" MidWest Laboratory -Laboratory analytical service provider under contract to FirstEnergy to analyze groundwater samples.1.3 REPORT ORGANIZATION The remainder of this report is divided into the following sections:* Section 2.0 -Methodology
- Section 3.0 -Results* Section 4.0 -Updated Conceptual Site Model* Section 5.0 -Key Findings* Section 6.0 -References For the purpose of this report, wells installed prior to 2007 will be referred to as "historic monitoring wells." Wells installed in 2007 will be referred to as "new monitoring wells." 0 ERM/DADEMOELLER 4 FIRSTENERGY-DAVIS-BESSE 65992.2 18 MAR 08
2.0 METHODOLOGY
2.1 INVENTORY
& MONITORING OF HISTORIC WELLS 2.1.1 Well Inventory & Gauging On 9 and 10 May 2007, ERM conducted a site visit to inspect historic monitoring wells at DBNPS and to determine if those wells were potentially suitable for use as part of the plant groundwater monitoring program. The well inventory included a site walk to locate the monitoring wells and conduct the following activities:
- confirm the well location and designation against historic documents;
- collect spatial coordinates using a hand-held global positioning system device;" assess the physical condition of the monitoring well;* establish a measuring point for future depth to groundwater measurements;" measure the well diameter, depth to groundwater and total depth;and" attach an identification tag to the monitoring well.Physical measurements and observations made during the well inventory were tabulated (Table 1) and compared to historic documentation.
Results of the well inventory were used to determine which historic monitoring wells were appropriate to use in future groundwater monitoring activities. 2.1.2 June 2007 Groundwater Monitoring Event Upon completion of the well inventory, a Groundwater Field Sampling Plan (FSP) (ERM, 8 June 2007) was prepared to outline procedures for groundwater sampling at select historic monitoring wells. The purpose of the FSP was to document the sampling locations, methodologies, analytical techniques and quality assurance/ quality control (QA/QC)measures for the collection of representative groundwater samples.ERM/ DADE MOELLER 5 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08 The purpose of the June 2007 monitoring event was to conduct a preliminary (or screening) round to evaluate the potential for tritium and gamma emitting radionuclides in groundwater and to support final selection of the new monitoring well locations. Sampling locations represented a subset of the historic monitoring wells at the property. The rationale for selecting the wells is included in Table 2.Groundwater samples were collected using low-flow methodologies as described in the FSP. Sampling depths were specified for each well as the mid point of the saturated screened interval. Quality Assurance/Quality Control (QA/QC) procedures were specified for both the field and analytical program.From 11 to 27 June 2007, BETA Laboratory personnel conducted groundwater monitoring at 17 historic monitoring wells: MW-1S, MW-1D, MW-7S, MW-12S, MW-15S, MW-15D, MW-18S, MW-18D, MW-20S, MW-20D, MW-26S, MW-26D, MW-30S, MW-32S, MW-32D, MW-33S, and MW-33D.On 11 June 2007, prior to sampling, the depth to groundwater was measured in each well using an electric water level meter. Low-flow samples were collected using a peristaltic pump with disposable tubing.During low-flow purging, geochemical field parameters were measured with an in-line flow-through-cell at regular intervals for stabilization criteria. Field parameters included temperature, specific conductivity, pH, dissolved oxygen (DO), and oxidation-reduction potential (ORP). The geochemical field parameters were recorded using a multi-parameter water quality instrument that was calibrated at the beginning of each day.Turbidity samples were collected upstream of the flow-through-cell and analyzed using a field turbidity meter. After stabilization of the field parameters, the flow-through-cell was disconnected and a groundwater sample was collected. All field information and parameters were recorded on Low-Flow Groundwater Sampling forms and observations were recorded in a log book.Water samples were collected in one-liter containers. No filtration or preservation was performed or required. All samples were packaged and shipped under chain-of-custody procedures to MidWest Laboratory of Northbrook, Illinois for analysis of Tritium (EPA Method 906.0) and gamma emitting radionuclides (EPA Method 901.1). Gamma isotopes included manganese-54 (Mn-54), iron-59 (Fe-59), cobalt-58 (Co-58), cobalt-ERM/ DADE MOELLER 6 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08 60 (Co-60), zinc-65 (Zn-65), zirconium-niobium-95 (Zr-Nb-95), cesium-134 (Cs-134), cesium-137 (Cs-137) and barium-lanthanum-140 (Ba-La-140). QA/QC procedures during the June 2007 monitoring event included field and laboratory methods to assess the overall analytical results. QA/QC procedures included collection of the following additional samples (Table 3): " Field duplicate (FD) -a QA/QC sample collected and analyzed to evaluate analytical precision. Two duplicate samples were collected in June 2007 (MW-12S and MW-20S). The duplicate samples were submitted for analysis; however, the duplicates were labelled with unique names (i.e., DBD-01 as a duplicate of sample MW-12S and DBD-02 as a duplicate of MW-20S), such that the laboratory was not aware of the sample's origin. (i.e., these were blind duplicate samples).* Matrix Spike/Matrix Spike Duplicate (MS/MSD) -a QA/QC sample collected and analyzed to evaluate the potential for matrix interferences on analytical accuracy. Matrix spike and matrix spike duplicate samples were collected at MW-26D by collecting two additional samples. The June 2007 samples were spiked at the laboratory with standards of 5,639 pCi/L of tritium, 59.3 pCi/L of cesium-134 and 66.3 pCi/L of cesium-137 and analyzed to compare the analytical results to the spike concentration. 2.2 JULY/AUGUST 2007 GROUNDWATER MONITORING EVENT Upon receipt of the June 2007 groundwater monitoring results, an additional round of groundwater monitoring was performed to confirm the June results and to aid in finalizing the location of the proposed monitoring wells.Groundwater samples were collected using low-flow methodologies as described in the June 2007 FSP. Sampling depths were specified for each well as the mid point of the saturated screened interval. QA/QC procedures developed for the June sampling event were followed.From 31 July to 6 August 2007, BETA Laboratory personnel conducted groundwater monitoring at 14 historic monitoring wells:* Re-sampled wells: MW-12S, MW-30S, MW-32S, MW-32D, MW-33S, MW-33D; and ERM/DADE MOELLER 7 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08
- Additional sampled wells: MW-12D, MW-30D, MW-31S, MW-31D MW-34S, MW-34D, MW-37S, and MW-37D.On 31 July 2007, prior to sampling, the depth to groundwater was measured in each well using an electric water level meter. Low-flow samples were collected using a peristaltic pump with disposable tubing.Purging, measurement of field parameters and sample collection for laboratory analysis in July/August 2007 were performed in a similar manner as during the June 2007 sampling event (see Section 2.1.2).Samples were packaged and shipped under chain-of-custody procedures to MidWest Laboratory of Northbrook, Illinois for analysis of tritium (EPA Method 906.0).QA/QC procedures during the July 2007 monitoring event included one field duplicate sample (MW-32S, see Table 3). The duplicate sample was submitted for analysis; however, it was labelled with a unique name, such that the laboratory was not aware of the sample origin (i.e., DBD-01 as a duplicate of sample MW-32S).2.3 WELL INSTALLATION
2.3.1 Overview
The purpose of the well installation program was to characterize and confirm existing documentation of site subsurface geology and hydrogeology and to establish a reliable monitoring well network capable of evaluating the potential for inadvertent releases of radioactivity from the Power Block.The new monitoring well network includes an up-gradient well triplet to represent background conditions and 13 wells located between the Power Block and Lake Erie to evaluate groundwater quality down-gradient and cross-gradient of the Power Block.Prior to initiating the drilling activities, DBNPS conducted utility clearance activities at each of the proposed drilling locations. A site walkover was completed with Bowser-Morner, Inc. to verify access to each location with the drilling equipment. In addition, a kick-off meeting was conducted on 7 August 2007 to address site-specific logistics and health and safety issues.ERM/DADE MOELLER 8 FIRSTENERGY -DAVIS-BESSE 65992.2 16MAR08 ERM/ DADE MOELLER 8 FIRSTENERGY -DAVIS-BFSSE 65992.2 18 MAR 08
2.3.2 Advancement
of Soil Borings From 8 to 29 August 2007, sixteen soil borings were advanced at DBNPS by Bowser-Morner, Inc. using a truck mounted Sonicor K-50 drill rig.Boring depths ranged from 28 to 90 feet below ground surface. The borings were advanced using sonic drilling technology, which is a dual-case drilling system that employs simultaneous high-frequency vibration and low speed rotation, coupled with down-pressure to advance the drill bit. The drilling method advances a uniform borehole while providing continuous, representative and relatively undisturbed core samples. The dual casing system was used at all locations and was advanced in 10-foot increments. Each 10-foot core sample was collected within polyethylene sleeves allowing for visual logging and field screening. The sleeves were cut lengthwise to allow visual logging of grain size, degree of sorting, color and relative moisture content of the recovered materials. Field screening for low level gamma emitting radiation was performed using a Ludlum micro R meter scanned over the core sample. Field screening for total volatile organics was performed using a MiniRAE 2000 photoionization detector (PID).Following completion of each soil boring, the inner and outer drill rods were thoroughly steam cleaned to remove residual solid and liquids from the drilling equipment. Drill cuttings were collected and containerized in 55-gallon drums and labeled to identify the origin and type of material (i.e., boring identification, soil and/or water). DBNPS managed the investigation derived waste by discharging the water into the South Settling Basin, an APC that has historically contained tritium, and placing the soil south of the Power Block. Borehole logs were prepared and are included in Appendix A.2.3.3 Monitoring Well Construction Each soil boring was completed as a monitoring well by installing two-inch inside diameter polyvinyl chloride (PVC) screen (0.010-inch slot) and riser. After installation of the PVC well materials, the outer casing of the sonic drilling system was slowly removed from the soil boring. The annular space between the PVC and the inner wall of the drill rod was filled as the drill rods were removed. The annular space around the PVC was filled as follows: 0 Sand filter pack -coarse grained silica sand around the PVC screen.ERM/ DADE MOELLER 9 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08 9 Bentonite seal -bentonite pellets above the silica sand.* Grout seal -bentonite/cement slurry to ground surface.Ten of the monitoring wells were capped with lockable expansion plugs and finished with flush mounted road boxes. The remaining six monitoring wells were capped either with a lockable expansion plug or a PVC slip cap and finished with a steel stick-up pipe secured in a concrete pad.2.3.4 Monitoring Well Development Following construction of the new wells, Bowser-Morner Inc. developed the wells to remove water and sediments introduced to the screen and riser during well construction. Well development was completed by removing groundwater using either a dedicated, disposable polyethylene bailer with nylon rope or a Whaler submersible pump. Non-dedicated equipment (pumps and tubing) was decontaminated between each well.Prior to development, the volume of water inside the well was calculated, with a goal of removing 10 well volumes. Lower Dolomite wells MW-101C, MW-102C, MW-103C, and MW-104C purged dry several times during the development activities, resulting in the removal of less than 10 well volumes from these wells. Strong hydrogen sulfide odors were noted from the development water pumped from these wells. The presence of sulfide is believed attributed to the dissolution of naturally occurring gypsum and anhydrite minerals within the Lower Dolomite. Regionally, the occurrence of these minerals within the Dolomite Bedrock is attributed to high concentrations of hydrogen sulfide in water wells (Water Resources of Ottawa County Fact Sheet, Graham et al., 1998).Groundwater from the development activities was containerized in either 55-gallon drums or 250-gallon totes and labeled to identify the origin of the water. Samples from the containers were collected and analyzed at DBNPS to support waste management. 2.4 SEPTEMBER/OCTOBER 2007 GROUNDWATER MONITORING ACTIVITIES Upon completion of the new monitoring wells, a Groundwater Field Sampling Plan (ERM, 20 September 2007) was prepared to outline procedures for groundwater sampling at the new monitoring wells, as well as select historic monitoring wells. The purpose of the FSP was to ERM/DADE MOELLER 10 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08 document the sampling locations, methodologies, analytical techniques, and QA/QC measures for the collection of representative groundwater samples.Sampling locations identified in the September 2007 FSP represented all the new monitoring wells and select historic monitoring wells. The rationale for selecting the wells is included in Table 2. The list included wells screened in the Glaciolacustrine, Till, Upper and Lower Dolomite Bedrock.Groundwater samples were collected using low-flow methodologies. Sampling depths were specified for each well as the mid point of the saturated screened interval. QA/QC procedures were implemented in both the field and analytical program.The purpose of the September/October 2007 monitoring event was to evaluate if tritium and gamma emitting radionuclides associated with inadvertent releases from plant operations had migrated into groundwater at DBNPS. From 24 September to 10 October 2007, BETA Laboratory personnel conducted groundwater monitoring at 32 monitoring wells: " Historic monitoring wells: MW-12S, MW-12D, MW-15S, MW-15D, MW-20S, MW-20D, MW-23S, MW-30S, MW-30D, MW-31S, MW-31D, MW-33S, MW-33D, MW-35S, MW-35D, and MW-37S;and* New monitoring wells: MW-100A, MW-100B, MW-100C, MW-101A, MW-101B, MW-101C, MW-102A, MW-102B, MW-102C, MW-103A, MW-103B, MW-103C, MW-104A, MW-104B, MW-104C, and MW-105A.On 24 September 2007, prior to sampling, the depth to groundwater was measured in each well using an electric water level meter. Low-flow samples were collected using a peristaltic pump with disposable tubing or a non-dedicated bladder pump.Purging, measurement of field parameters and sample collection for laboratory analysis in September/October 2007 were performed in a similar manner as during the June 2007 sampling event (see Section 2.1.2).Wells MW-101C and MW-103C were purged dry during low-flow pumping. Field parameters at these wells were collected during the purging activities and the groundwater sample was collected after the groundwater level had recovered to within 90 percent of the original level.ERM/ DADE MOELLER 11 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08 QA/QC procedures during the September/October 2007 monitoring event included field and laboratory methods to assess the overall analytical results. QA/QC procedures included collection of the following additional samples (Table 3):* Field Duplicate -duplicate samples were collected at four wells (MW-12D, MW20S, MW-31S, and MW-103B) to evaluate laboratory analytical precision. The duplicate samples were submitted for the same analysis as the actual samples with unique names such that the laboratory was not aware of the samples' origin. (i.e., DBD-01 as a duplicate of sample MW-12D, DBD-02 as a duplicate of sample MW-20S, DBD-03 as a duplicate of sample MW-31S, and DBD-04 as a duplicate of sample MW-103A).* Matrix Spike/Matrix Spike Duplicate -two additional samples were collected at MW-30S and MW-100A and spiked at the laboratory with a standard of 17,185 and 27,496 pCi/L of tritium and 65.6 and 98.4 pCi/L of cesium-137.
- Laboratory Duplicate
-outside of the FSP requirements, the laboratory collected and analyzed split samples to evaluate laboratory precision of tritium analysis. The laboratory duplicate samples (i.e., MW-33S duplicate and MW-102A duplicate) were collected by splitting samples from MW-33S and MW-102A, respectively.
- Equipment Blank -a rinseate sample was collected after decontaminating the bladder pump at MW-103C to evaluate the effectiveness of decontamination procedures and the potential for cross-contamination between wells introduced by the sampling equipment.
2.5 SURVEYING
Select historic wells (MW-14D, MW-18S/D, MW-19S/D, MW-21S/D, MW-30S/D, MW-38S/D and MW-39S/D) and all new monitoring wells were surveyed on 11 and 12 December 2007 by B.E.C. Associates, Inc., a professional survey company retained by ERM. Elevation data were collected relative to NAVD 1929 sea level vertical datum. Historic wells were selected for elevation surveying was based on observed physical alterations to the well casings during the initial inspection. Documented survey data in DBNPS files was used for the remainder of the historic wells.ERM/ DADE MOELLER 12 FIRSTENERCY -DAVIS-BESSE 65992.2 18 MAR 08 2.6 DATA USABILITY ASSESSMENT An assessment of the June, July/August 2007 and September/October 2007 analytical data was performed to determine the usability of the groundwater data for the intended purpose of the monitoring event. The usability of groundwater data was evaluated by initially conducting a review of the Low-Flow Groundwater Sampling Forms against methods outlined in the FSP in order to assess deviations from the original FSP.Secondly, the analytical results were evaluated in terms of data quality standards termed "PARCCs" parameters (i.e., precision, accuracy, representativeness, comparability and completeness of the data).Additional data review and verification included a statistical analysis of the radiological data reported by MidWest Laboratory to determine the range in the local background concentration of tritium in groundwater at Davis-Besse. The need for a statistical evaluation was based on the detection of low level tritium concentrations reported by the laboratory and follows industry guidance (EPRI, 2005).ERM/DADE MOELLER 13 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08
3.0 RESULTS
3.1 SITE GEOLOGY The surficial geology beneath the DBNPS property is characterized as Glaciolacustrine and Till units underlain by Dolomite Bedrock. Although not encountered in the new boreholes, a layer of fill is reportedly present within the area excavated during construction of the Power Block.Based on field observations during the recent drilling activities as well as information presented in historic reports, the relative thickness and elevation of geologic units encountered at DBNPS are summarized below.Summary of Geologic Units at DBNPS Unit Approximate Depth Approximate Elevation Interval(s) Below Ground Range (feet above mean sea Surface (feet below ground) level)Glaciolacustrine 0 -10 feet 574 feet -564 feet Till 10 feet -20 feet 564 feet -554 feet Dolomite Bedrock 20+ feet 554 feet and below The Glaciolacustrine unit is characterized as brown silt with some sand and clay. This formation consists of sediments of a complex, unconsolidated nature that were deposited within a temporary lake formed during the recession of glacial ice from Lake Erie. The underlying Till unit is defined as a brown to dark gray silty clay. The surfaces of the Glaciolacustrine and Till deposits slope towards Lake Erie.Beneath the Glaciolacustrine and Till units is the Dolomite Bedrock. This bedrock unit consists of argillaceous dolomite that has been subdivided into a Massive Dolomite and a Laminated Dolomite. The Massive Dolomite is approximately 10 feet in thickness, hard, finely grained, and present approximately 10 feet below the ceiling of the Dolomite. The Laminated Dolomite is encountered above and below the Massive Dolomite and includes thin layers of interbedded dolomite, gypsum, anhydrite and shale. Bedrock joints oriented to the northeast (N45°E) and northwest (N50°W) were reportedly observed in the bedrock during ERM/DADE MOELLER 14 FIRSTENERGY -DAVIS-BESSE 65992.2 18MAR08 ERM/ DADE MOELLER 14 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08 excavation of the Power Block. Beds within the Dolomite Bedrock have a natural dip of less than one degree to the south.3.2 HISTORIC WELL INVENTORY Table 1 and Figure 2 present a summary of historic monitoring wells evaluated during the well inventory. The monitoring wells were originally installed during construction of DBNPS to assess the effectiveness of a dewatering system that operated during plant construction. The historic wells were installed as couplets with screened in the Upper and Lower Dolomite and are located north, east, south and west of the Power Block. The historic wells consist of 3-inch diameter, 20-foot screen wells installed at depths varying between 29.37 and 49.65 feet (Upper Dolomite wells) and from 72 and 86 feet (Lower Dolomite wells).Based on historic documentation, the Upper and Lower Dolomite wells are separated by the Massive Dolomite unit.The following monitoring wells were not located during the well inventory and therefore were not evaluated further: MW-8S, MW-8D, MW-9S, MW-9D, MW-10S, MW-10D, MW-13S, MW-13D, MW-16S, MW-.16D, MW-17S, MW-17D, MW-24S, MW-24D, MW-25S, MW-25D, MW-27S, MW-27D, MW-28S, MW-28D, MW-29S, MW-29D, MW-36S, and MW-36D.3.3 NEW MONITORING WELLS A total of 16 monitoring wells were installed at five locations at DBNPS to assess existing data gaps and to increase the reliability of the historic well network (Figure 2). The new wells were located to characterize groundwater quality up-gradient and down-gradient of the Power Block.Five well triplets and a single well were installed. Each triplet is characterized by three individual monitoring wells that are screened across a specific target depth interval at each location: Base of Till, Upper Dolomite, and Lower Dolomite.The following table summarizes the newly installed monitoring wells and their location relative to the Power Block.ERM/DADE MOELLER 15 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08 Summary of New DBNPS Monitoring Wells S Well ID Location/Hydraulic Position Relative Target Depth of Well Screen the to Power Block MW-100A MW-100B MW-100C MW-101A MW-101B West/ Up-gradient Base of Till.Upper Dolomite Lower Dolomite Base of Till Uper Dolonmitte Lower Dolomite East/ Down-gradient MW-101C MW-102A MW-102B MW-102C Base of Till Northeast/Down and cross-gradient Upper Dolomite Lower Dolomite MW-103A Base of Till MW-103B Northeast/ Down and cross-gradient MW-103C Upper Dolomite Lower Dolomite Base of Till-..---..... Upper Dolomite MW-104A MW-104B Northeast/ Down and cross-gradient MW-104C Lower Dolomite MW-105A Northeast/ Down-gradient Glaciolacustrine / Base of Till Table 1 includes a summary of well construction details for the new and historic monitoring wells at DBNPS. Micro R and PID field meters did not yield any increased detections when scanned over the core samples during the drilling activities. Borehole logs and well construction diagrams for the new monitoring wells are included in Appendix A.GROUNDWATER FLOW Table 4 presents a summary of depth to groundwater measurements and calculated groundwater elevations during the well inventory and groundwater monitoring events. During each monitoring event, the elevation of groundwater was generally higher than the elevation of surface water in Lake Erie, indicating regional groundwater flow is from west to east at DBNPS.U 3.4 ERM/DADE MOELLER 16 DRSTENERGY -DAVIS-BESSE 65992.2 18MAR08 ERM/DADE MOELLER 16 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08 Surface Water 1 and Groundwater Elevations Date Range in Surface Water Range in Groundwater Elevation Lake Erie (feet above Elevations in the Site sea level) Monitoring Wells 9 May 2007 571.80 -572.48 570-54 -575.91 11 June 2007 571.72 -571.91 570.52 -574.79 31 July 2007 571.10 -571.42 569.97 -573.90 24 September 2007 570.87 -571.17 517.62 -573.96 1 National Oceanic and Atmospheric Administration station 9063079 in Marblehead, OH As indicated in the above table, groundwater elevations below the elevation of surface water in Lake Erie were observed during each monitoring event. The occurrence of low groundwater elevations likely reflects site-specific conditions at DBNPS that complicate the ability to evaluate groundwater elevations and precise flow directions. Complicating factors include the presence of a grout curtain, the flow of groundwater within discrete fractures in bedrock, the large area of excavated bedrock beneath the Power Block and the high degree of mineralized groundwater and associated low yield observed in the new Lower Dolomite wells. An additional source of uncertainty is the usability of historic elevation survey data that were used to calculate groundwater elevations from the historic wells.Low groundwater elevations were measured at Lower Dolomite wells MW-101C, MW-102C, MW-103C and MW-104C, located east and northeast of the Power Block. As previously indicted, each of these wells demonstrated a low yield during the well development activities and contained high levels of hydrogen sulfide gas. The use of expansion plugs may be inadvertently trapping sulfide gas inside the wells and around the well screen, thereby limiting the screens ability to communicate with the Lower Dolomite. Future modifications to the expansion plugs to allow venting of the sulfide gas will be evaluated in effort to obtain more accurate groundwater elevation data from these wells.Figures 3, 4, and 5 present groundwater elevations for the Till, Upper Dolomite and Lower Dolomite, respectively, during the September 2007 monitoring event. Groundwater elevation contours were not developed due to the complicating site-specific factors and their potential to impact groundwater flow. However, groundwater flow directions at DBNPS ERM/DADE MOELLER 17 FIRSTENERGY-DAVIS-BESSE 65992.2 18 MAR 08 within the Till, Upper Dolomite and Lower Dolomite can be evaluated by comparing groundwater elevations in new across the site.Groundwater elevations in Till wells MW-100A, MW-101A, MW-102A, MW-103A and MW-104A are presented in Figure 3. The highest groundwater elevation in the Till was 573.91 feet measured up-gradient (i.e., west) of the Power Block at MW-100A. The lowest groundwater elevation was measured at MW-105A at 568.73 feet, which is below the elevation of surface water in Lake Erie. Based on the distribution of groundwater elevations, groundwater flow in the Till is from west to east across the site. Approximate flow directions in the Till (Figure 3) are orientated perpendicular to the shoreline of Lake Erie.Groundwater elevations in the Upper Dolomite are presented in Figure 4.The highest groundwater elevation in the Upper Dolomite was 573.96 feet measured up-gradient (i.e. west) of the Power Block at MW-100B. The lowest groundwater elevations in the Upper Dolomite were located northeast of the Power Block (MW-31S at 571.08 feet) and southeast of the Power Block (MW-12S at 570.98 feet). Based on the distribution of groundwater elevations, groundwater flow in the Upper Dolomite is from west to east across the site. Approximate flow directions in the Upper Dolomite (Figure 4) are orientated perpendicular to the shoreline of Lake Erie.Groundwater elevations in the Lower Dolomite are presented in Figure 5.The highest groundwater elevation in the Lower Dolomite was 573.56 feet measured up-gradient (i.e. west) of the Power Block at MW-100C. In general, lower groundwater elevations in the Lower Dolomite were located east of the Power Block. Based on the distribution of groundwater elevations, groundwater flow in the Lower Dolomite is from west to east across the site. Approximate flow directions in the Lower Till (Figure 5)are orientated perpendicular to the shoreline of Lake Erie.Groundwater elevations decreased in site wells from May to July, and again from July to September. This trend mimics the decline in elevation of surface water in Lake Erie over the same period, signifying that the marshes and/or Lake Erie are the discharge boundary for groundwater. Comparison of groundwater elevations between the Till and Upper Dolomite allows for assessment of vertical groundwater flow gradients. Using data from the new monitoring wells, an upward flow gradient is observed from the Upper Dolomite to the Till unit. As previously indicated, the elevation of groundwater in all three units is higher than the elevation of surface water in Lake Erie (except where anomalies are noted)ERM/DADE MOELLER is FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08 further indicating that groundwater within all three units is ultimately discharging to the marshes and/or Lake Erie.3.5 GROUNDWATER QUALITY 3.5.1 Groundwater Field Parameters Groundwater field parameters collected at the time of groundwater sampling in June 2007, July/August 2007 and September/October 2007 are summarized in Table 5. A summary of the field parameter data is presented below." Temperature -Groundwater temperatures ranged from 13.6 to 25.6 degrees Celsius (°C). In general the highest temperatures were measured in wells located directly down-gradient of the Power Block. The highest temperatures were observed at MW-34S/D (25.6, 24.1oC), MW-33S/D (25.5, 25.20C), and MW-31S/D (24.5, 23.1oC). Groundwater temperatures in other areas were below 20oC.* Specific conductivity -Groundwater specific conductivity ranged from 113 uS/cm to values greater than 10,000 uS/cm. The highest specific conductance values (i.e., greater than 50,000 uS/cm) were measured in Lower Dolomite wells MW-101C, MW-102C, MW-103C and MW-104C. As indicated earlier, these wells were noted with high hydrogen sulfide gas, low yield and low groundwater elevations. The high specific conductance measured at these wells relative to other wells further suggests that the well screens at these four locations have limited connection to the Lower Dolomite.* Dissolved oxygen (DO) -Several DO measurements were rejected from the monitoring events due to probe interference with hydrogen sulfide. Accepted DO levels in groundwater ranged from 0.04 to 4.24 milligrams per liter (mg/L). The reported odors of sulfide are indicators of anaerobic and depleted oxygen conditions." pH -The pH of groundwater ranged from 6.0 to 8.8 standard pH units. The limited variations in pH values are most likely due to the influence of the Dolomite Bedrock. Dolomite is a carbonate rock and is anticipated to buffer pH changes in groundwater.
- Oxidation Reduction Potential
-ORP values ranged from -368 to 87 millivolts (mV). ORP values were generally below 50 mV in all of ERM/ DADE MOELLER 19 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08 the wells, indicating that site groundwater is subject to reducing conditions (anaerobic). A trend shows that values decrease with depths.Turbidity -With the exception of wells MW-101C (798), MW-102C (10) and MW-104C (38), the turbidity of groundwater was low (i.e., less than 10 nephelometric turbidity units). High turbidity values at MW-101C, MW-102C and MW-104C are consistent with the high specific conductance at these wells and the well screens limited ability to communicate with the Lower Dolomite.3.5.2 Analytical Results Data Summary Groundwater analytical results from the June, July/ August 2007, and the September/October 2007 groundwater monitoring event are summarized in Table 6. Figure 5 presents a summary of the June, July/August 2007 tritium results, while Figure 6 presents a summary of the September/October 2007 tritium results. Appendix C and Appendix D include an assessment of the usability of the groundwater analytical data for the June, July/August, and September/October 2007 monitoring events, respectively. As indicated in Appendices B and C, the analytical data presented in Table 6 meet the data quality objectives in the FSPs and are usable for the intended purpose of the groundwater monitoring program. Appendix D also includes a statistical evaluation to determine the range in local background concentrations. Laboratory analytical reports are included in Appendix E.Local Background Conditions As presented in Appendix C, reported tritium concentrations between 178 pCi/L and 348 pCi/L represent statistically insignificant activity at the.95% confidence level. Therefore, values at or below 348 pCi/L were considered to be representative of local background conditions. Factors influencing local background conditions may include the historic atmospheric bomb testing program, cosmic ray interactions in the earth's atmosphere and localized washout from continuous and batch gaseous releases from DBNPS.June and July/August 2007 Results Analytical results of tritium samples collected in June 2007 ranged from less than the minimum detectable concentration (MDC, i.e., <330 pCi/L)ERM/DADE MOELLER 20 FIRSTENERGY -DAVIS-BESSE 65992.2 18MAR08 ERM/DADE MOELLER 20 FI RSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08 to 5,838 pCi/L (MW-32S). Tritium detections during the July/August 2007 confirmation round ranged from 108 pCi/L (MW-31D) to 7,535 pCi/L (MW-32S). No gamma emitting radionuclides were detected above their respective MDCs.Tritium concentrations detected above the 348 pCi/L background value were located primarily in monitoring wells east of the Power Block. In the Upper Dolomite, the highest concentrations were present east of the Power Block, including MW-31S, MW-32S, MW-33S, and MW-34S.Elevated detections above local background were also measured in the Upper Dolomite north of the Power Block at well MW-30S (1,307 pCi/L)and well MW-37S (2,961 pCi/L).In the Lower Dolomite unit, the highest detections were located east/southeast of the Power Block, including wells MW-33D, MW-34D and MW-12D.September/October 2007 Results In September/October 2007, tritium concentrations ranged from less than the MDC (149 pCi/L) to 3,149 pCi/L (MW-31S). The concentrations of tritium in new wells MW-100A, MW-100B and MW-100C, which are located hydraulically up-gradient of the Power Block, were <193 pCi/l,<193 pCi/L and <149 pCi/l, respectively. No gamma emitting radionuclides were detected above their respective MDCs in any of the groundwater samples collected during the September/October 2007 sampling event.Concentrations above local background in the Till were detected down-gradient (i.e., northeast) of the Power Block, including MW-102A (387 pCi/L, Till Unit), MW-103A (495 pCi/L, Till Unit), and MW-105A (1,832 pCi/L, Glaciolacutrine/Till Unit).Tritium concentrations above local background in the Upper Dolomite were detected north of the Power Block in wells MW-30S and MW-37S, consistent with the June and July/August 2007 events. The highest concentrations in the Upper Dolomite were detected east/northeast of the Power Block including wells MW-31S and MW-33S. Elevated tritium in the Upper Dolomite was not detected in new monitoring wells MW-102B, MW-103B and MW-104B, located to the northeast of MW-31S/D.For the Lower Dolomite, the highest concentrations above local background were detected in wells MW-12D, MW-15D and MW-33D, located east/ southeast of the Power Block. Tritium was not detected ERM/DADE MO0ELLER 21 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08 above local background in any of the new monitoring wells east of the Power Block within the Lower Dolomite (i.e., MW-101C, MW-102C, MW-103C and MW-104C). As previously indicated, groundwater at these wells may not be connected to the Lower Dolomite due to the presence of hydrogen sulfide gas.Comparison to Drinking Water Standards Tritium concentrations in groundwater during the June, July and August and September/October 2007 monitoring events were below the Environmental Protection Agency's drinking water standard of 20,000 pCi/L.3.5.3 Tritium Source Assessment As indicated in the January 2007 Groundwater Flow Characteristics Report (ERM, 16 January 2007), potential sources of the elevated tritium detected in groundwater may be associated with plant operations in the following areas and/or documented historic liquid releases (Figure 2):* Power Block -consisting of potential sources within the Reactor Containment, Auxiliary Building, Circulating Water Pump House, Turbine Building and Borated Water Storage Tank.* Spent Fuel Pool, Fuel Transfer Canal and Cask Pit -as outlined in the investigation summary of DBNPS Condition Report # 04-01719, several instances of leakage from the Spent Fuel Pool have been recorded. Since the elevation of the pool is from 563.3 to 601.5 feet above sea level, leakage from the Spent Fuel Pool and/or interconnected Fuel Transfer Canal and Cask Pit could potentially release tritiated water to the structural backfill surrounding the Power Block or to the Upper Dolomite.* Condensate Demineralizer Tank Discharge Line -as documented in the DBNPS 10 CFR 50.7 5(g) file, in May 1990 a break in the discharge line exiting the Condensate Demineralizer Polisher Tank was discovered east of the Power Block. Contaminated resin was released to soil at the connection between the Condensate Demineralizer Backwash Receiver Tank discharge line and a 10-inch pipe that conveyed the resin to South Settling Pond.* Collection Box -as documented in the DBNPS 10 CFR 50.7 5 (g) file, approximately 12,000 gallons of water was spilled to the ground ERM/DADE MOELLER 22 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08 adjacent to the Collection Box in 1997. It was estimated that the concentration of tritium in the release water was 6,850 pCi/L.Hydrogen Addition System -as documented in the DBNPS 10 CFR 50.7 5(g) file, primary grade water was spilled onto the ground near the Borated Water Storage Tank while draining the Hydrogen Addition System in 1991.ERM/DADE MOELLER 23 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08
4.0 UPDATED
CONCEPTUAL SITE MODEL The spatial distribution of tritium in groundwater and groundwater flow patterns can be used to update the CSM regarding the potential inadvertent release, fate and transport of tritium at DBNPS. The CSM was originally presented in the Groundwater Flow Characteristics Report -Davis-Besse Nuclear Power Station, Oak Harbor, Ohio.Groundwater flow within the Till, Upper Dolomite and Lower Dolomite units at DBNPS is from west to east toward Lake Erie. Higher groundwater elevations within these units compared to the elevation of surface water in Lake Erie indicates that groundwater discharges to the marshes and/or Lake Erie.Potential inadvertent releases from within the Power Block, including the Spent Fuel Pool, would migrate vertically down through the unsaturated zone to the water table. Upon encountering the water table, tritium would be transported laterally through the Till in an easterly direction towards Lake Erie. Potential releases below the water table could release tritium directly to the Upper or Lower Dolomite unit.Reported mapping of jointing and fractures on the upper surface of the Dolomite Bedrock indicated orientations southwest to northeast and a secondary orientation from southeast to northwest. These fractures represent the direction of potential preferential migration pathways within the Dolomite Bedrock. Elevated detections in Upper Dolomite wells MW-31S and MW-32S are located on fracture projections that trace back (i.e., southwest) to the Power Block.Tritium in groundwater will ultimately migrate into Lake Erie, where the concentrations will be diluted due to the volume of groundwater discharge versus the volume of water in the lake. This is supported by DBNPS Radiological Effluent Monitoring Program (REMP) data that indicates tritium levels typically below 330 pCi/L in surface water samples from Lake Erie.ERM/ DADE MOELLER 24 FIRSTENERGY -DAVIS-BESSE 65992.2 18MAR08 ERM/ DADE MOELLER 24 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08 5.0 KEY FINDINGS The key findings from the groundwater investigation include the following: Geology The surficial geology beneath the DBNPS consists of Glaciolacustrine and Till units. The Glaciolacustrine unit is characterized as cohesive, brown silt with some sand and clay. The Till is characterized as brown to dark-gray, silty clay." Beneath the Till is Dolomite Bedrock, subdivided into a Laminated Dolomite and a Massive Dolomite. The Laminated Dolomite, which is encountered above and below the Massive Dolomite, contains thin layers of interbedded dolomite, gypsum, anhydrite and shale. The Massive Dolomite is approximately 10 feet thick, hard, finely grained, and located approximately 10 feet below the top of the Dolomite.Historic Well Inventory" A total of 54 wells (27 couplets) were located and inspected during the well inventory and 24 wells (12 couplets) could not be found.Each well couplet consists of a shallow and deep well within the Dolomite Bedrock. The shallow bedrock well is screened within the Upper Dolomite and the deeper bedrock well is screened in the Lower Dolomite. The Massive Dolomite unit separates wells screened within the Upper and Lower Dolomite.* The historic wells, by themselves, were not sufficient to create an effective groundwater monitoring program at DBNPS because they did not provide adequate lateral and vertical coverage. In addition, due to the age of the wells, their construction quality and subsurface conditions are not known.Groundwater Flow The ability to develop groundwater elevation contours and flow patterns is complicated by several factors, including the presence of a grout curtain, the flow of groundwater within discrete fractures in bedrock, the large area of excavated bedrock beneath the Power ERM/DADE MOELLER 25 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08 Block and the high degree of mineralized groundwater and associated low yield observed in the new Lower Dolomite wells.An additional uncertainty is the usability of historic elevation survey data that were used to calculate groundwater elevations from the historic wells.0 Based on the distribution of groundwater elevations, groundwater flow in the Till, Upper Dolomite and Lower Dolomite units is from west to east across the site.* The ultimate discharge point for groundwater in the Till, Upper Dolomite and Lower Dolomite is the marshes and/or Lake Erie east of the Power Block.Groundwater Quality* Strong hydrogen sulfide odors were noted in site groundwater, particularly new Lower Dolomite wells MW-101C, MW-102C, MW-103C and MW-104C located east of the Power Block. The hydrogen sulfide is believed to be naturally occurring and caused by the weathering of gypsum and anhydrite minerals. Groundwater field parameters at these wells are characterized by high specific conductance, low ORP and high turbidity water.* High hydrogen sulfide gas levels at wells MW-101C, MW-102C, MW-103C and MW-104C may be inadvertently trapped due to the use of expansion plugs at these wells. The sulfide gas may limit the ability for the well screen to communicate with the Lower Dolomite. Future modifications to the expansion plugs to allow venting of the sulfide gas will be evaluated in effort to obtain more accurate groundwater elevation data from these wells." Reported concentrations of tritium in groundwater between 178 pCi/L and 348 pCi/L represent statistically insignificant activity at the 95% confidence level and are considered representative of local background conditions. Factors influencing local background condition may include the historic atmospheric bomb testing program, cosmic ray interactions in the earth's atmosphere and localized washout from continuous and batch gaseous releases from DPNBS. Reported values above 348 pCi/L represent concentrations that are statistically greater than local background conditions. ERM/DADE MO0ELLER 26 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08 " Tritium concentrations above the 348 pCi/L background value were located primarily in monitoring wells east of the Power Block." Tritium concentrations in the wells screened in the Till ranged from less than the minimum detectable concentration (MDC; <193 pCi/L) to 1,832 pCi/L. The highest concentrations were detected down-gradient (northeast) of the Power Block, including MW-102A (387 pCi/L), MW-103A (495 pCi/L), and MW-105A (1,832 pCi/L)." Tritium concentrations in the wells screened in the Upper Dolomite ranged from less than the MDC (<193 pCi/L) to 7,535 pCi/L. The highest concentrations were detected down-gradient (east) of the Power Block, including MW-31S, MW-32S, MW-33S, MW-34S, MW-37S and MW-30S. Two detections above local background conditions were detected at well MW-30S (1,307 pCi/L) and well MW-37S (2,961 pCi/L), located north of the Power Block.* Tritium concentrations in the wells screened in the Lower Dolomite ranged from less than the MDC (<193 pCi/L) to 3,271 pCi/L. The highest detections were located east/southeast of the Power Block, including wells MW-33D, MW-34D and MW-12D." No gamma emitting radionuclides were detected above MDC in any of the groundwater samples collected during the June, July/August 2007 or the September/October 2007 monitoring events.* Tritium concentrations in groundwater during the June, July and August and September/October 2007 monitoring events were below the Environmental Protection Agency's drinking water standard of 20,000 pCi/L.Updated CSM" Groundwater flow within the Till, Upper Dolomite and Lower Dolomite units at DBNPS is generally from west to east toward Lake Erie with groundwater discharge to the marshes and/or Lake Erie.* Potential inadvertent releases from within the Power Block, including the Spent Fuel Pool, would migrate vertically down through the unsaturated zone to the water table. Potential releases from structures below ground could release tritium directly to the Upper or Lower Dolomite unit.ERM/DADE MOELLER 27 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08 " Elevated detections in Upper Dolomite wells MW-31S and MW-32S are located on reported southwest to northeast fractures that project back to the Power Block.* Tritium in groundwater will ultimately migrate into Lake Erie, where the concentrations will be diluted due to the volume of groundwater discharge versus the volume of water in the lake." Historic monitoring of Lake Erie by DBNPS indicates that there have been few detections of tritium above local background conditions, none of which are believed to be attributed to groundwater releases.Based upon the above findings, FirstEnergy should further evaluate the hydrogeology and influence of plant features on site groundwater flow.In addition, tritium detections above local background conditions should be evaluated to establish a reliable monitoring well network for long-term monitoring. ERM/DADE MOELLER 28 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08
6.0 REFERENCES
EPRI, 2005. Groundwater Monitoring Guidance for Nuclear Power Plants.Palo Alto, CA. 1011730.ERM, 16 January 2007. Final Report -Groundwater Flow Characteristics Report Davis-Besse Nuclear Power Station, Oak Harbor, Ohio.ERM, 8 June 2007. Final Report -June 2007 Groundwater Field Sampling Plan -Davis-Besse Nuclear Power Station, Oak Harbor, Ohio.ERM, 20 September 2007. Final Report -September 2007 Groundwater Field Sampling Plan -Davis-Besse Nuclear Power Station, Oak Harbor, Ohio, Pennsylvania. Graham, G.W., N'Jie, N., and Brown, L. Water Resources of Ottawa County. Ohio State University Fact Sheet. Available at: http://ohioline.osu.edu/aex-fact/0480_62.html NEI, August 2007. Industry Ground Water Protection Initiative -Final Guidance Document. NEI-07-07. ERM/DADE MOELLER 29 FIRSTENERGY -DAVIS-BESSE 65992.2 18 MAR 08 0 Tables S S Table I Monitoring Well Location and Construction Summary FirstEnergy Nuclear Operating Company Davis-Besse Power Station 5501 N. State Route 2 MS3085, Oak Harbor, OH 43449 Well Designation Date Installed Well Condition Hydrogeologk Position MP Elevation Well Diameter Screen Length Constructed Well Depth Screen Interval Elevation (feet) Getlogic Unit for Monitoring Relative to Power Btorks (feet ASL) (inches) (feet) (feet below gromnd) Top Bottom Monitored New Wells MW-iAIVA 9-Aug -2lX7 Funrlonl Up-gradient 586 3 2 10 28 569.33 559.33 Till MW-iI )B 9-Aug-21107 Fun"u ton: l Up-gradient 58674 2 10 45 552,24 54224 Upper Dolom-te MIW -IlF1C 9-Aug-2107 Funltiomnal Up-rlradient 586.27 2 10 85 511.77 501.77 Lower Dolomite MW-IllA 15-Aug-2l817 Functional Down-rgrado-ol 586.96 2 101 28 569.46 559.46 Till MW-lI IB l5-Aug-2 7 FuPo tiorrl Dowen-grado-n 586.89 2 10 45 552.39 542.39 Upper Dolomite K1W20IIC 15-Aur-2l)7 Pow Ioroal Dowg:n-grad2nl 587.18 2 10 811 517.68 507.68 Lower Dolomite MW.1i2A 16-Aug-2!)17 Fun, tlional Down-gradoent 585,12 2 10 29.5 566.12 556.12 Till MW-lI12B 16-Aug-X2107 Functional Down-gradient 585.04 2 10 44 551.54 541.54 Upper Dolomite MW-1I 2C 16-Auh,-2187 Fuowrwonal Downgradteon 595.31 2 15 78 3. .517.81 507.81 Lower Dolo-mtr , MW-1013A 21-Aug-2107 Fun, bronal Down-gradient 589.24 2 I0 M 55N 555.24 Till MW-103B 21-Aug-2(007 Fun, tonal Down-i'radrent 589.19 2 10 48.5 551,19 541.19 Upper Dolomire MW-1il3C 21-Aul,-2(17 FunP tr-Iol Down-pradient 588.87 2 10 78 521.37 511.37 Lower Dolomite MW-114A 24-Aug-21017 Funtol Down-grad t 2 10 32 5637 553.75 Till MW11841 24-Aug-21(17 Ponr lonal Dow"-gradren2 514.98 2 0 46 550.48 539.48 Upper D(rloolte MIW-1t84C 24-Aug-20087 Functional Doown-=radhn1 584.84 10 _T 775 517.84 .(17 Lower Dolomit MW-10G5A 28-Auii-21007 FuPo tioral Dows-gr-doen 585.46 10 27.5 568.46 558.46 Glaoiolarutrrlrwý / Till Historic Wr'ells MW-IS Prorr lt March 1979 Furoulroor Dotwn-gradrrnt 584102 3 20 41.7. 562.4 542.4 Upper Dolom ie MW- D Pre CMaeoh 197 P5w5M we, MW 1DProro Marnh_ 97'9 _ Fu.,om ... .... ... 3 .. ... .. 20 ..... .. .80,6 ....52,1 ................. 02 2 .... o e Dol___ ___ t M3V-2S Prior o Maech 1979 Functionri Down-gradient 584.46 3 20 40.5* 563.9 543.9 Upper Dolomite MW-2D Prior 1o Man h 1979 Pow tio.nal Dowo-gradient 584.55 3 20 80,5* 524.0 504.0 Lower Dolomite MW-3S Prior to March 1979 FunPlional Deown-gradrernt 584.81 3 20 41.7' 563,1 543.1 Upper Dolomite MW-3D Pr-or to Marrh 1979 FunPw ..o.. Doon--gradltl-t 584.73 3 20 79.4" 5.5 .. .. 53 505.3 Lower Dolomrte MW-4S Pr:or tor Marr'h 1979 Po n, -Ir-al Down-gradint 588.59 3 2D 46.3' 562.3 542.3 Upper Dolomite MW-4D Prro 1o Mar.ch 1979 Fuorooroal Down-gradi-1n 588.57 3 20 85.6' 525.0 50M 0 Lower DolomitLe MW-SS Priornlo Marrch 1979 FuPo tiorn Down-gradlnt 5384.85 3 210 42.3* 562.6 542.6 Upper Dolomite MW-3D Prior to March 1979 Functional Down-gradient 584.A6 3 211 81.6' 524.3 5014.3 Lower Dolomite MW-6S Prorr Mrorh 1979 Funrial Dt5o7-gradoon 379.86 3 211 34.4' 364.5 544.5 Upper Dolomole 6W-sD PrFor 1o Murrrh 197u9 Furoor-ral Droso-gradrenl 578.95 A3 211 72`4 526.6 586.6 Lower Doloorhl MW-7S Prior to Ma. h 1979 FPwr tionarl Croo.-gradirrnt 57769 3 20 34.4- 563.3 543.3 Upper Dolomite MW-7D Poror to, Mir. h 1979 FuP, tiornl Croso-gradient 577.62 3 25 72.9' 524.7 5(W.7 Lower Dolomite MlW-SS Pror lr Mrlarh 1979 Welo roulid ntool h1-,lvrle during the May 21537 well rvenory. Well most likely derstroyed Upper Dolomrte MW-8D Prortooe Manrh 1979 Well olrl ernr- he orxated duog the May 2(1X7 well mvenrtoWell most likely destroyred Lower.Dolomite MNW-_95 Prorr to Mar-.oh 1979 Well could not hr loroted during the May 2007 well inventory. Well most likely destroyed Upper Dolomite MW_ Z Prior to Marrh 1979 Vell rrould not hbe alted during the May 2807 well inventory. Well most likely derslroyed Lower Dolomite MW-1:l Prior to Mach 1979 Well r ould note hr wated during the May 2007 well inventory. Well most likely destroyed Upper Dolomite MW-1ID Prire, 1o Mach 1979 Well Crould not he located durir h- May 2157 well irmr tor.oWoilI mosl likely dtestroytd .Lower Dolomite MW-I IS Prrror- to March 1979 FPno Ionrl Dowo-gradient 586.31 3 20 -42.6*Uppee olrroi ..MW-iI D Pror to Marth 1979 unr lioal Dwn-gradient
- 5. 80.7 525.3 505.3 Lower Dolomite MlW-12S Prior to Manh 1979 FNo, tional Down-gradrlnr 585.96 3 20 42.10' 564.0 544.0 Upper Dolomite MW- I 2D Prro ro Ma'h 1979 FunP tional Down-grad-r~
e 85.98 3 20 81.1* 524.9 504.9 Lower Dolomite MW-r-1 Prrrr to Macsh 1979 We" 'otild not N. lohartd during the May 20(17 weoll worvetory. Well most likely destroyed Upper Dolonrte MW-13D Prior to March 1979 Well could ot o he located durrr the May 20(17 well vvrrntory._Well mostlikely destroyed Lower Dolooite MiW-145 Prror- o Mar h 1979 Fown tIroal Down-gradiont 586.24 3 J 20 , 42.2 36-1 544.1 Upper Dolomiter MW-14D Prror I. Macnh i979 oFu, .ional Down-gradint 385.¶ 3 2111 79.9' 526.1 5116.1 Lower Dolomite MW-1SD Prror to March 1979 Fur-tioal Down-gradienl 585,84 3 1 2111 42.6* 5&1,3 543.3 Upper Dolomite MW-I5D Pri5r V r March 1979 FPio nal D:own-gradtoet 38584 3 Ij 2 I.42.6' .5653 ...3 Upper D_ 20ote MW-165 Prior to March 1979 Well crould not be located during the May 2157 well inrentory. Well wool lirey destroyed Upper Dolomite MW-16D Prior to Manch 1979 Well could not hN lot aLed during the May 2()07 well inventory. Well most likely drtotroyed Lower Dolomite MW-I7S Priror lo March 1979 Well, ould not N, lotIated during the May 21017 well inventory. Well most likely drtroyed Upper Dolomite MW-17D PrNro br March 1979 Well 0ouad nr- he oared dlorr he May 21817well rn t 11o o st likely-I drstroyed Lower Doloirlte.......... 18 ii I -294.' [ -576.2 556.2UprDlmt MW-18D Prior to Mach 1979 Pun- ltonl Cr"" 58539 U51er Dolorre MIW-19D Prior-ro Mach 11979 Funoltornal Cross-gr0diunt 58539 3 20 77" 531.7 5.Lower Dolomiter MW-19S Prior- t Manh 1979 Funt tional Up-gradiento 585.77 3 41S564.0 544.0 Upper Dolomire MW-19D Prror tr Mach 1979 Fwiro t nal Up-gradien P 85.77 3 2 775: 328.3 508'.3 Lrwer Dolorole Table 1 Monitoring Well Location and Construction Summary FirstEnergy Nuclear Operating Company Davis-Besse Power Station 5501 N. State Route 2 MS3085, Oak Harbor, OH 43449 Well Designation Date Installed Well Condition Hydrogeologic Position MP Elevation Well Diameter Screen Length Constructed Well Depth Screen Interval Elevation (feet) Geologic Unit for Monitoring Relative to Power Blocks (feet ASL) (inches) (feet) (feet below ground) Top Bottom Monitored MW-21)S Prior to Man'h 1979 Fonthional Up-gradielt 586.06 3 20 42.4* 563.6 543.6 Upper Dolomite MW-20D Prior to March 1979 Functional Up-gradient 585.96 3 20 80.3* 525.7 505.7 Lower Dolomite MW-21S Prior to March 1979 Functional Up-gradient 585.40 3 20 43.2' 562.2 542.2 Upper Dolomite MW-21 D Prior to March 1979 Funtional Up-gradient 586.62 3 20 81.4' 525.3 505.3 Lower Dolomite MW-22S Prior to March 1979 Functional Up-gradient 585.51 3 20 42.1' 563.5 543.5 Upper Dolomite MW-22D Prior Io March 1979 Functional Up-gradient 585.59 3 20 81.2' 524.4 504.4 Lower Dolomite MW-23S Prior to March 1979 Functional Up-gradient 584.97 3 20 42.2* 562.8 542.8 Upper Dolomite MW-23D Prior to March 1979 Functional Up-gradient 585.34 3 20 80.8* 524.6 504.6 Lower Dolomite MW-24S Prior to March 1979 Well could not be located during the May 2007 well inventory. Well most likely destroyed Upper Dolomite MW-24D Prior to March 1979 Well could not be located during the May 2007 well inventory. Well most likely destroyed Lower Dolomite KIW-25S Prior I, Manrh 1979 Well tcold not he located during the May 2007 well inventory. Well most likely destroyed Upper Dolomite MW-25D Prior to March 1979 Well could not he located durine the May 2007 well inventory. Well most likely destroyed Lower Dolomite MW-26S Prior to March 1979 Functionat Up-gradient 585.68 3 20 42.3' 563.3 543.3 Upper Dolomite MW-26D Prior to March 1979 Functionat U -gradient 505.65 3 20 80.5' 525.2 505.2 Lower Dolomite MW-275 Prior to March 1979 Well could not be located during the May 2007 well inventory. Well most likely destroyed Upper Dolomite MW-27D Prior to Mlarh 1979 Well could not be located during the May 2007 well inventory. Well most likely destroyed Lower Dolomite MW-28S Prior to March 1979 Well could not he located during the May 2007 well inventory. Well most likely destroyed Upper Dolomite MW-28D Prior to March 1979 Well could not be located during the May 2007 well inventory. Well most likely destroyed Lower Dolomite MW-295 Prior to March 1979 Well could not be located during the May 2007 well inventory. Well most likely destroyed Upper Dolomite MW-29D Prior to Manrh 1979 Well could not be located dorm the May 2007 welI inventory. Well most likely destroyed Lower Dolomite MIW-305 Prior to March 1979 Functional Cross-gradient 587.20 3 20 40.9* 566.4 546.4 Upper Dolomite MW-301D Prior to March 1979 Functional Cross-gradient 587.20 3 20 81.0' 526.2 506.2 Lower Dolomite MW-315 Prior to March 1979 missing cap Down-gradient 586.11 3 20 42.9' 563.2 543.2 Upper Dolomite MW-31 D Prior to Manrh 1979 Functional Doon-gradient 586.39 3 20 81.2' 525.2 505.2 Lower Dolomite MW-325 Prior to Manrh 1979 Fu-ctional Dowg'radient 586.05 3 20 42.6* 563.5 543.5 Upper Dolomite MW-32D Prior to March 1979 Fuoctional Down-gradient 586,17 3 201 80.Ll 525.2 5(05.2 Lower Dolomite MW-33S Prior t1 March 1979 Functional Down-gradient 585.,5 3 20 42.2* 563.6 543.6 Upper Dolomite MW-33D Prior to March 1979 Functional Down-gradient 505.89 3 20 80.7* 525.2 505.2 Lower Dolomite MW-345 Prior to Martch 1979 Forctional Dosr--gradiwnt 586.01 3 20 42.8* 563.2 543.2 Upper Dolomite MW-34D Prior to March 1979 Functioal Down-yradient W55.87 3 1 20 80.7* 525.2 505.2 Lower Dolomite MW-35S Prior to March 1979 onctioral Crss-gradient 592.97 3 20 49.7' 563.3 543.3 Upper Dolomite MW-35D Prior to March 1979 Functional Crass tradient 592.05 3 20 86.3' 526.5 506.5 Lower Dolomite MW-36S Prior to Marnh 1979 Well could not he during the May 2007 well inventory. Well most likely destroyed Upper Dolomite MIW-36D Prior to Wtanh 1979 Well could not be lo(wated durino the May 2007 well inventory. Well most likely destroyed Lower Dolomite MlW-375 Prior to March 1979 Functional Cross-gradient 585.79 '3 20 42.7' 563.1 543.1 Upper Dolomite MIW-37D Prior to March 1979 Furctional Cross-5radient 505.77 3 20 80.6* 525.1 515.1 Lower Dolomite MW-318 Prior to March 1979 Functional Cross-gradient 586.00 3 20 40.3' 565.7 545.7 Upper Dolomite MW-38D Prior to March 1979 Functional Cross-gradienrt 586.16 3 20 79.0* 527.2 507.2 Lower Dolomite MW-395 Prior to March 1979 Functi:*ra Up-gradiet 585.38 3 2( 40.3* 565.1 545.1 Upper Dolomite MW-39D Prior to Mar:h 1979 FPon:oional Up-gradient 585.33 3 2(1 81 2' 524.3 504.3 Lower Dolomite No.es All -lesti*,o iore otnaiv t,, no,-ano level (ASL-ahonwoa leer-)KIP h MIeoriong P,,inI N= -- ' t, depth avalalle, VAl.-o n-,-,red -r, 9 ond 10 Mop 2007--Data nol ava ,or 2 ý,2 0 0 Table 2a OSummary of Sampling Program -June 2007 FirstEnergy Nuclear Operating Company Davis-Besse Nuclear Power Station 5501 N. State Route 2 MS3085, Oak Harbor, OH 43449 Well Groundwater Sampling Sampling Designation Sampling Well Selection Rationale Method Historic Well MW-1S X Yes -Down-gradient from Power Block Low-Flow MW-1D X Yes -Down-gradient from Power Block Low-Flow MW-2S No -Sample MW-1 Couplet NA MW-2D No -Sample MW-1 Couplet NA MW-3S No -Sample MW-1 Couplet NA MW-3D No -Sample MW-1 Couplet NA MW4S No -Sample MW-12S NA MW-4D No -Sample MW-12S NA MW-5S No -Sample MW-12S NA MW-5D No -Sample MW-12S NA MW-6S No -Sample MW-12S NA MW-6D No -Sample MW-12S NA MW-7S X Yes -Close to South Settling Pond Low-Flow MW-7D No -Sample MW-7S NA MW-11S No -Sample MW-12S NA MW-11D No -Sample MW-12S NA MW-12S X Yes -Close to inadvertent release in 50.75(g) Low-Flow MW-12D No -Sample MW-12S NA MW-14S No -Sample MW-15 Couplet NA MW-14D No -Sample MW-15 Couplet NA MW-15S X Yes -Down-gradient from Power Block Low-Flow MW-15D X Yes -Down-gradient from Power Block Low-Flow MW-18S X Yes -Previous tritium detection Low-Flow MW-18D X Yes -Previous tritium detection Low-Flow MW-19S No -Sample MW-20 Couplet NA MW-19D No -Sample MW-20 Couplet NA MW-20S X Yes -Previous tritium detection Low-Flow MW-20D X Yes -Previous tritium detection Low-Flow MW-21S No -Sample MW-20 Couplet NA MW-21D No -Sample MW-20 Couplet NA MW-22? No -Sample MW-20 Couplet NA MW-22D No -Sample MW-20 Couplet NA MW-23S No -Sample MW-26 Couplet NA MW-23D No -Sample MW-26 Couplet NA MW-26S X Yes -Upgradient of Power Block Low-Flow MW-26D X Yes -Upgradient of Power Block Low-Flow MW-30S X Yes -Cross-gradient of Power Block Low-Flow MW-30D No -Sample MW-30S NA MW-31S No -Sample MW-32 Couplet NA MW-31D No -Sample MW-32 Couplet NA MW-32S X Yes -Down-gradient of Power Block Low-Flow MW-32D x Yes -Down-gradient of Power Block Low-Flow MW-33S x Yes -Down-gradient of Power Block Low-Flow MW-33D X Yes -Down-gradient of Power Block Low-Flow MW-34S No -Sample MW-33 Couplet NA MW-34D No -Sample MW-33 Couplet NA MW-35S No -Sample MW-7S NA MW-35D No -Sample MW-7S NA MW-37S No -Sample MW-30S NA MW-37D No -Sample MW-30S NA MW-38S No -Sample MW-30S NA MW-38D No -Sample MW-30S NA MW-39S No -Sample MW-26 Couplet NA MW-39D No -Sample MW-26 Couplet NA Note NA = Not Applicable Page 1 of 4 Table 2b Summary of Sampling Program -July/August 2007 FirstEnergy Nuclear Operating Company Davis-Besse Nuclear Power Station 5501 N. State Route 2 MS3085, Oak Harbor, OH 43449 Well Groundwater Sampling Sampling Designation Sampling Well Selection Rationale Method Historic Well MW-12S X Confirm June 2007 sampling result Low-Flow MW-12D X Down-gradient from Power Block Low-Flow MW-30S X Confirm June 2007 sampling result Low-Flow MW-30D X Cross-gradient from Power Block Low-Flow MW-31S X Down-gradient from Power Block Low-Flow MW-31D X Down-gradient from Power Block Low-Flow MW-32S X Confirm June 2007 sampling result Low-Flow MW-32D X Confirm June 2007 sampling result Low-Flow MW-33S X Confirm June 2007 sampling result Low-Flow MW-33D X Confirm June 2007 sampling result Low-Flow MW-34S X Down-gradient from Power Block Low-Flow MW-34D X Down-gradient from Power Block Low-Flow MW-37S X Cross-gradient from Power Block Low-Flow MW-37D X Cross-gradient from Power Block Low-Flow Note NA = Not Applicable Page 2 of 4 Table 2c.Summary of Sampling Program -September/October 2007 FirstEnergy Nuclear Operating Company Davis-Besse Nuclear Power Station 5501 N. State Route 2 MS3085, Oak Harbor, OH 43449 Well Sampling Groundwater Sampling Sampling Designation Well Selection Rationale Method New Well MW-100A X Yes -New well for Groundwater Protection Initiative Low-Flow MW-100B X Yes -New well for Groundwater Protection Initiative Low-Flow MW-100C X Yes -New well for Groundwater Protection Initiative Low-Flow MW-101A X Yes -New well for Groundwater Protection Initiative Low-Flow MW-101B X Yes -New well for Groundwater Protection Initiative Low-Flow MW-101C X Yes -New well for Groundwater Protection Initiative Low-Flow MW-102A X Yes -New well for Groundwater Protection Initiative Low-Flow MW-102B X Yes -New well for Groundwater Protection Initiative Low-Flow MW-102C X Yes -New well for Groundwater Protection Initiative Low-Flow MW-103A X Yes -New well for Groundwater Protection Initiative Low-Flow MW-103B X Yes -New well for Groundwater Protection Initiative Low-Flow MW-103C X Yes -New well for Groundwater Protection Initiative Low-Flow MW-104A X Yes -New well for Groundwater Protection Initiative Low-Flow MW-104B X Yes -New well for Groundwater Protection Initiative Low-Flow MW-104C X Yes -New well for Groundwater Protection Initiative Low-Flow MW-105A X Yes -New well for Groundwater Protection Initiative Low-Flow Historic Well MW-1S No -Concentration below detection limit (June 2007) NA MW-1D No -Concentration below detection limit (June 2007) NA MW-2S No -Sample MW-101 Triplet NA MW-2D No -Sample MW-101 Triplet NA MW-3S No -Sample MW-101 Triplet NA MW-3D No -Sample MW-101 Triplet NA MW-4S No -Sample MW-12 Couplet NA MW-4D No -Sample MW-12 Couplet NA MW-5S No -Sample Couplet MW-35 and Triplet MW-101 NA MW-5D No -Sample Couplet MW-35 and Triplet MW-101 NA MW-6S No -Sample Couplet MW-35 and Triplet MW-101 NA MW-6D No -Sample Couplet MW-35 and Triplet MW-101 NA MW-7S No -Sample MW-35 Couplet NA MW-7D No -Sample MW-35 Couplet NA MW-11S No -Sample MW-12 Couplet NA MW-11D No -Sample MW-12 Couplet NA MW-12S X Yes -Previous tritium detection (860 pCi/L in July 2007) Low-Flow MW-12D X Yes -Previous tritium detection (1,155 pCi/L in July 2007) Low-Flow MW-14S No -Sample MW-15 Couplet NA MW-14D No -Sample MW-15 Couplet NA MW-15S X Yes -Up-gradient of tritium detections at MW-12 and MW-34 Low-Flow MW-15D X Yes -Up-gradient of tritium detections at MW-12 and MW-34 Low-Flow MW-18S No -Sample MW-15 Couplet NA MW-18D No -Sample MW-15 Couplet NA MW-19S No -Sample MW-20 Couplet NA MW-19D No -Sample MW-20 Couplet NA MW-20S X Yes -Up-gradient of tritium detections at MW-12, MW-33 and MW-34 Low-Flow MW-20D X Yes -Up-gradient of tritium detections at MW-12, MW-33 and MW-34 Low-Flow MW-21S No -Sample MW-20 Couplet NA MW-21D No -Sample MW-20 Couplet NA MW-22S No -Sample MW-20S and MW-23S NA MW-22D No -Sample MW-20 and MW-23 Couplets NA MW-23S X Yes -Up-gradient of tritium detection at MW-37S Low-Flow MW-23D No -Sample MW-20 Couplet NA Page 3 of 4 Table 2c Summary of Sampling Program -September/October 2007 FirstEnergy Nuclear Operating Company Davis-Besse Nuclear Power Station 5501 N. State Route 2 MS3085, Oak Harbor, OH 43449 Well Groundwater Sampling Sampling Designation Sampling Well Selection Rationale Method MW-26S No -Sample MW-20 Couplet NA MW-26D No -Sample MW-20 Couplet NA MW-30S X Yes -Previous tritium detection (1,149 pCi/L in July 2007) Low-Flow MW-30D X Yes -Previous tritium detection at MW-30S (1,149 pCi/L in August 2007) Low-Flow MW-31S X Yes -Previous tritium detection (7,322 pCi/L in July 2007) Low-Flow MW-31D X Yes -Cross-gradient of tritium detections at MW-32 Low-Flow MW-32S No -Sample MW-31 Couplet NA MW-32D No -Sample MW-31 Couplet NA MW-33S X Yes -Previous tritium detection (2,702pCi/L in July 07) Low-Flow MW-33D X Yes -Previous tritium detection (3,271pCi/L in July 07) Low-How MW-34S No -Sample MW-33 & MW-12 Couplets NA MW-34D No -Sample MW-33 & MW-12 Couplets NA MW-35S X Yes -Cross-gradient of tritium detections at MW-12 Low-Flow MW-35D X Yes -Cross-gradient of tritium detections at MW-12 Low-Flow MW-37S X Yes -Previous tritium detection (2,961 pCi/L in July 2007) Low-Flow MW-37D No -Relatively low tritium detection (135 pCi/L in July 2007) NA MW-38S No -Sample MW-37S NA MW-38D No -Relatively low tritium detection at MW-37D NA MW-39S No -Sample MW-20 Couplet NA MW-39D No -Sample MW-20 Couplet NA Note NA = Not Applicable Page 4 of 4 Table 3 Summary of Analytical Program -June, July/August, & September/October 2007 FirstEnergy Nuclear Operating Company Davis-Besse Nuclear Power Station 5501 N. State Route 2 MS3085, Oak Harbor, OH 43449 lone 2007 Sampling Event Well Tritium (EPA Method 906.0) Gamma (EPA Method S01.1)Designation N MS/MSD FD LD EB N MS/MSD FD LD EB MW-1S X X MW-ID X X MW-7S X x MW-12S X X X X MW-15S X x MW-15D X X MW-18S X X MW-18D X x MW-20S X X X X MW-20D X X MW-265 _ x MW-26D X X X X MW-30S X X MW-32S X X MW-32D X X MW-33S X X MW-3A X X MAW-EIB x xluly,/August 2007 Sampling Event well Tritiu (EPA Method 906.0) Gamma (EPA Method 91.1)Designation N MS/MSD FD LD EBl MS/MSD _FD LD EB MW-125 X MW-12D X MW-30S X MW-30D X MW-31S X MW -31 D X MW-32S X X MW-32D X MW-33S X MW-33D X MW-345 X MW-34D X MW-37S X MW-37D X September/October 2007 Sampling Event well Tritium (EPA Method 90.0) Camma (EPA Method 901.1)Designation N MS/MSD FD LD EBl N MS/MSD FD LD EBl MW-12S X X MW-12D X X X X MW-15S X X MW-15D X X MW-20S X X X X MW-20D X x MW-23S X X MvW-3OS X X X X MW-30D X X MW-31S X X X X MW-31 D X X MW-33S x x X X MW-33D x X MW-35S X X MW-35D X X MW-37S X X MW-100A X X X X MW-100B X X MW-100C X X MW-101A X X MW-101B X X MW-101C X X MW-102A X X X X MW-102B X X MW-102C X X MW-103A MW-103B MW-103C MW-104A x x x X x x X X7 X MW-104B x x MWE-104C X ____ _____ I MW-10'A _____ _____x x X -WdI- ..vldnd., gv..&t. FD -Eidd Dýplikt 5tS/NID -M-i. Spik,'/M-,i.Spkph,-c ID -bN1,Doy D~ph-,.N-No"`,-'s"vr' FH q.ip.- B h.vE Table 4 Summ.ry of Gro.ndwater Gauging Data FirstEnergy N-l-ar Operating Company Davis-Besse Noclear Power Station 5501 N. State Route 2 P053085, Oak Htrbor, OH 43449 Well Measring Measuring Geologic Unit Depth to Water (feet below MP Groundwater Elevation (feet ASL)Designation Point otee tion Monitored 11 June 2007 31 July 2007 24 September 2007 11 June 2007 31 July 2007 24 September 2007 toeet ASLI MW-10(B Top of PVC 586.4 Upper Dolnmoi' NA NA 12.78 NA NA 573.96 MW-IXIC To, of PVC 586.27 1Uoe Dolotite " NA NA 12.71 NA NA 573.56 MWl-I (A A 38VC ..56197. ..Til NA NA 1 5.15 Aý NA .1... 71192 MO250 ..T5SI1'f VC... 5869.0 .U0TDl nw NA NA 1ItO NA NA 572:00 MW-hlI1C ToPVC 58....587.18 LWooD1linit, NA NA 22.73 NA NA 54A5.m W. 02A ---. ý- Pv -T pT"Y ..5-.(,T. -Till ------N-A------- 13 "-NA 572-9 -M IT::-1:82 ............................. Tp -c VC .........585 ....... ... ....ni. NA NA i. 1A.8. NA ... .573.23.MP5.o ...N. ....1PV.t5.5. [...............NA...2....ANAt55 .. ................ A: NA 172.17pv 5151N:N 2.8N 5 W 3Tfl. .A. .........5..1.. ..T.l. ..NA .. NA ---NA .. 517.01 .17 MW0M T ;p i PVC q....592..2. ............... tii .N A .......... NA 1..27 A.... .NA.. NA: .mW-11tIC ., .. ..5....T, NA NA ,. ....A............ NA .....517.62 MW-104A Top ,i PVC 585.25 Till NA NA 12.73 NA NA 572.52 M115-1114B T!!pol! PVC. ..5841.98. ..Ipp, -ISSSiI, NA NA 11.91 NA NA 573.507- 'ltI,. NA. NA 51.6 A.NA.....1.37. 65191.1)5A 1 p5I ....5,55146. .Ca53i595 T NA: NA 116777 NA: NA 5875 .M W-t T15" MAC 58p7 t, OLii 1195 NM) NM5183 N M NM 61WIS. ...TpFP1C ...5.9. ...p .OS 1 N... NM N.. ..N NM NM 5.....Mt-ID T5~SPC ..97 MINOSSiiSN NM NM NM N NM MWI2S- T 'poIV 5,44.4 UpN~lol NM N M N M N M N M N M 6115-10 To PVVC r.rv.r9 ..o8 5 ........i~ NM NMrrN-.. ...N,,, NM NM-W S T o o P V C 8 .I 9i iDM M ............. ... ... ................ ...... N M N .... ...... ... ...... K M -N M ............. N m ............. ................. O T .PVCN. .8 6 .G Iii.;N N M .......................... ...... N7 m....... NM -- NM--. .. .NM M61 -lO .. .. 583.79. .4 m 7 80 ... ... .... ..M.N. .N.............. N M .K............ MIW-45.TI.. ..f PVC 588.69 Upperr Dloite. ...57 NM NM 571.M7 NM.NM NM.MI V- 0 0 Ti ;'f PV C 588.. ....7.. ..o......i ...N M N M N M N M.....N M N M.NRS-11S.....Tr,f 5PVC 5M-O88 Upps~ iDeM-ii NM NM NM NM NM NM M.....o. ............ 56 T. or 'ol ....NM NM W. NM ....................... NM NM S --------12 ...Top ýf o Ppvcc 58599 ...... ..Lo- e O D ,Iorni ...Nf14 91 7 N Mo 7.5 7 2..... ........... VC24..... ........ NM ' NM .NM.. -NM M W -4 S " T o ,n f P V C 5 88 .5 9 ..... .;:tp , D o lo:il 91 "9'r I I-... .rM 9.. .. ... [ -r N. I¢I: .... .............. .. .. ... ... ..M... .. ..... .... .....M .... .... .... ..N M .... ..... ... ......... .. ... ..... .... .. .MW-61)D To o PVC5 7 ....... ' .. ...o i NM..N............................ 37 .N NM NMM NM MIS-I.O T.....P.C... ..... .. ..... ....N ...13. .~1418........... 57M7 NM5 NJ0 -15 ....DV 16m i : 554.M147712 NM 57M5 6161210. ....pof PVC. .5775.62Upe D:oloini. ..27 NM NM 5747 NM NM S 59 110 .. .T. p PVC 5,46. ... , ...- ---..... ....NM..44.........................
- m. -.......................
I I. ............ ,.............. NM 54 4........ M ....................... .. ............................ MiS-S T,,p,,fPVC- ---5 -79toi~Ii NM NM NM NM ___ MN lnl -T,,pSPPVC 589 U r, O Di79O it, i7 ~ 1 4:1 -----------4.98-50 ------- 571.457 M.. W- 2D Tpi, ,f PVC 5.5.96........c..n.....1..41 M.14...5725. 1....6 D ..-. ...T 6pol50..... 4NN. ....................... N.. ...... ...N N M MW-7 I ...To ,f PVC 5S7.9 .....5... .. U D .olo.t... ...NM NM NM NM.N .. ... .... NM NM NM..MW1 5.5 ...fPVC .5&5p.. ... ..I ..-13... .. .MM ............ ... .. ........................... M .-2l ... .............. ... ...... .... 1. ........... -9 N M.. .. N M.. ............. N M ........................ MW.'35TopsI6fPVC 5m49."i.I~jjCO5-S 13M4 NM ._ _ .193 .M NMý2 57 571627"IMW- ...D .. ...T..PVC .5574. ..... oe Io.... ....... 1n ......................... .NM "NM .............. 7..... NMI .... NM 9 NM 619130 ...T,,pfif PVC. ..5847. ..6o Up t~. ...50 147N19M547538 75 M.......M............5.......... I .......... MN 17 .. ............................... 5-- -r .... ................ 616-11 Topol PVC 596.M9 U0- DO,06 ..N 1500 150- NM 571305709.5 ..-. ..NT f piIi.5 9.l. 1 9S.ToUp5 55$ 7 9 L ; ., .i 3 ... ...15...1 00.... ...... ... ... 1 4r1 N M 5 7 2 2 3 ............ 4 N M I I "I 6161-...T.....V 55.7 ..to .oo~ ...34 410 I 577 57 177 9N.1 ..2 Tio fPVC r.. ..575 ............... U iDI ............. ..ii .5 14 M 149. 57270 5 1 571..... 7215 ............. 0 TNM f 588M ..r9 ............ ........................ N1N85 ........... -N .- N .. NM MW-21 D Top of PVVC 588.58 m1 Up oiiOr5,mit NM N MN MN.. ..-.4. TT I PVC'581.97 -1 .................................. .NM -- ....... ......... W ................... .NM 5 2 .-. .. N NM M W -2 0 D ....T "hi~? P P V C 9 9 -.... 9 9 99 r 9 9 .5 8o 5, 9 ... .. ..... .. .......... -n i .d " D 1 i i t { ........... ..... ....... ................ .. ........ ...... .. .. ... .... ... .. .... ...m4 .M M .... .... .... .... ... ..... .... .... .... ............... ..... ... ... .... .............. .... .... .... .... ... ..... .... .... .... ............ .... ... .....6V-219-50 ..To -iPC529 per Ooý,tifNMNM2119N NM 518 6109-310 ...T:ýpi6f PVC ....- 59284. ...121,j. Di'lSt 66 NM 20.. ..N .... .. I NM '. 57211 ..1 .. ...70~Tp kl~~568.7 .~U 1 clPD ii. .~1323.... N14 N.. 5. .......NM 5.5751 MW61-21D T(p ,iPVC7555..7-... I Sw-D S N-15. .N ... ..NM 564 -. ..--....5.-.-r 55---- o Ti u ----2 -- -- NM- NM~ ~4o 616.-... T3p68 .V 58.2 ....e'~lo l NM.N NM ...NIN M MW-6959. T:p, " PV.V5. oNM ............................. M .NM NM 5. NMN..... M.M V-31D ......... .. T, ...00 .......N NM 5N ... ..... .W -1 .......... ....... .. ...1 ,: J rP V C -.. .. ...... .5 -8 8 12 0 -... .... ........U p r -i LI,7 L -.......... ................ 3 8- .. ... ....... ... ..-1 4 ý .. ..... ..... ...... .. .154 2 .. ....... .............. ..... N7 4 ---.. .. .........5 7 1 -6 g .. ..... .. .... .. ....ý%9 MW-32D T,,p,,f PVC ~~~586.17 U ý o -.21:052N M W -3 2 T I o.P... ................. T 5e'i D o l,~ 1 ... ... .... ............ ..13 .17 .. ....14 :5 ,1 ... .......... .. .. .. .. ......... 5.... ..... ... .. ........ ................ .. .... ......... ......... ......... ...... ...I S '-, ----A --o Applicabl 01 tMW-34 rSTo, V58.1U jM1 r N Ocalos Tolphet PV- b85.d. Po-oo Ds.16.oedt NMeo e 1405N ll718... fSV2 3 .... ... ... .. ......T f VC -... .. ..,58 -.. ...... .... .311 ia Do31 omih N M I""4 ........... "I""""' 13 20.... ... .............. N M1 ........ .571 15 ... ..M A 3 4 .1 S ....... TT- p 99V .. ... ... ... 95 8 6" ) 7q -. U ti'f~ b iij { .. ... .. ...... .. N M r .. ... .. .......... .. .. .......1.1 ........ ...... ... .... ..... .....i.......................... .. .....O R .. .. ............ ..... .................. N M1-3 .. .......... ............................. hi ......... .. ..MM W D ........T p V ... .....8 .7 .. ........a w } D i i ti .. ... .... ... .....N ..... .. ..... ... ... 4 0 .. ...... .. .. .... ... U , ............ ... .... ...... .. .. ..M .. .. .... ..... ... ... ......... 558:. .. .. ............................. ........... 1'6M ................ MW-55Ti of Pc 585.2. pe Dolnmilim NM NMM N11 i IA ..518-M -88..................NM N M-.................-..................- .....'.. ....I-...... .......r- ................ ........ .......... __ ...N- .. ..--- -- .....N te.Al h-~wtwvat , !I,fi -Ltl, t,, n h-m' ~ el(e -I -v .,lw)NA -No, A pp~wltb, NM I N".m, -e~nd MP -- Mis~ng PNin': Re...i1-.mighed b.- ,+,-d uN ,po oenig wel1 0 Table 5 Summary of Groundwater Field Parameter FirntEnergy Nuclear Operating Company Danis-Besse Nuclear Power Station 5581 N. State Route 2 MS3085, Oak Harbor, OH 43449 New Monitorina Wells Parmete Well ID MW-100A MW-100B MW-100C MW-101A MW-101BI MW-IOIC ,fW-102A MW-102B MW-102C MW-103A MW-103B MW-103C" MW-104A MW-104B MW-104C MW-105A Sampling Date 24-Sep-07 25-Sep-07 25-Sep-07 02-O0t-07 02-Oct-07 02-Oct-07 25-Sep-07 27-Sep-07 27-Sep-07 01-Oct-07 01-Oct-07 01-Oct-07 28-Sep-07 2 8-Sep-0 7 28-Sep-07 8-Oct-07 Temperature ("C 16,5 17.4 17.0 14.1 14.6 15.4 181 15.5 16.1 15.1 14.1 14.5 14.1 14.2 16.2 19.8 Specific Conductivity (uSfcmn) 2,958 2,746 8.883 1,980 2,091 161,500 2,635 2,482 140,700 2,421 2.458 121,000 2,506 2477 21,210 2,381 D1ssotved Oxyg-n (.g/1) 4.24 1313" 1.58 2.07 3.08 <.00 25.07" 3.47 <2.00 5.92 2.88 0.92 15.01" 971" 6.12" 1.74 H (-) 71 7 1 7.3 6.8 7.3 6.0 6.9 7.2 6.8 7.1 7.2 6.8 6.9 7.1 7.3 6.9 Oxidation Reduction Potential (mV) -127 -213 -322 -4 15 -315 -191 -213 -368 -196 -232 -259 -120 -288 108 Turbid~tv (NTU) 0.47 129 1.01 0.39 2.94 798 NM 1.3 104 1.8 1.2 9.b 22 24 384 3.8 Historic Monitoring Wells Parameter S el 151 MD W-IS MW-1 D MW-75 MW-12S MW-12D MW-ISS MW-15D MW-18S MW-18D MW-20S rSamtin Date 12-Jun-07 12- un-07 13-jun-07 14-juno07 06-Aug-07 4-ct-07 06-Au -07 04-Oct-07 26-jun-07 O 10-Oct-07 26-jun-07 108-Oct-07 14-jun-07 14-jun-07 _ _-jun-07 09-Oct__ 7 Temperature (C) 140 16.1 16.5 17.5 20.2 179 208 18,8 21.7 21.0 21.2 20.3 16.2 18.4 14.8 18.9 Spef. Conductivt (uS/cex) 2.696 6-2,57 1,982 2,187 2,185 2,101 3.762 3,633 2,434 2,327 5,168 4,790 1,260 6,997 1,901 2,233 Dissoced Oxygen (rg/l) 210 033 034 0.34 5.52" 38601 0.23 6 30" 041 1.68 0.46 13.68" 8.42" 0.27 0.78 1.71 rH (-) 70 70 72 72 73 73 7.2 7.1 7.3 7.2 7.2 7.0 8.8 7.7 7.3 72 Oxidation Reduction Potential (mV) -116 -67 4 19 -44 872 -307 -293 -161 42 -320 -321 53 -155 83 -31 Turbidity (NTU) 09 1 0 0.5 0.9 0.2 0.5 1.6 2 0 0.3 4 0 4.2 1.8 0.2 0.1 Well ID MW-20D MW-23S MW-265 MW-26D MW-3OS MhW-30D MW-31 S MW-31D MW-325 i Sampling Date 25-jun-07 10-Oct-07 10-Oct-07 13-jun-07 13-jun-07 27- jun.07 02-Aug-07 8-Oct-07 03-Aug-07 09-Oct-07 31-jul-07 5-Oct-07 31-jul-07 8-Oct-07 25-jun-07 31-jul-07 Terper-ture CC) 180 160 138 15.8 17.2 178 172 17.6 17.7 16.7 23.5 245 23.4 Z2.3 22.7 21 6 Specific Conduct ...ty (uS/era) 2,150 2,309 2,402 2,216 43,394 2Z224 2,529 2Z365 34,778 38,860 7,484 2,288 22,410 20,110 2.362 1-492 Dssolved Oxygen (.g/I) 024 1.26 1.51 0.43 0.04 071 NM 132 NM <200 0.66 4.52" 0.55 2.40 0.21 775" PH (-) 73 72 7.1 7.2 7.6 70 7.3 7.1 6.9 6.7 7.2 7.1 7.1 7.0 7.4 7.2 Oxidation Reduction Potential (mV) .28 -56 7 37 -303 105 366 -356 -116 -148 -287 -316 92 Turbiditv (NTU) 30 0.3 081 1.1 0.9 04 0.3 0 0.4 0.3 1.8 4.1 0.4 0.4 2.6 0.8 Parameter Well ID M17-32D3 MW-33S MW-33D MW-34S MW-34D MW-35S MW-35D MW-375 MW-37D I Sampling DOt 26-)un-07 I-Aug-07 27-jun-07 I -Aug-07 5-0,:t-07 27-jun-07 I2-Aug-07 5-Oct-07 2-Auga37 02-Aug,)7 03-Aug-07 03-Oct -07 3-Aug-07 9-Oct-07 6-Aug-if7 Temperature (TC) 20n 21.5 253 255 25.5 24.9 25.2 25.2 25ý6 24.2 19.1 18.4 177 15.2 198 Specific Conductivity (uS/cr) 15,235 15,050 2,615 2,554 2,325 7,471 6,337 6,600 2,589 11,031 2,776 6,564 2,477 2,255 113 DissoIved Oxygen (mg/ 1) 0.29 NM 1.00 NM 7.07" 0.42 NM 4.93" NM NM 3.24 1.70 NM NM 0.08 pH (-) 6,9 68 7T2 7T2 7 1 7= 0 6.6 69 7.2 7ý0 7.2 7.2 7.4 736 Oxidation Reduction Potential (mV) -338 -351 -I -96 37 -322 -298 -340 -125 -317 286 -134 -188 -256 Turbiditv (NTU) 03 04 1.8 07 059 0.3 04 0.25 04 0.4 86 1 5.6 0.4 33'c -,In,g, G 1, N U- -n,hl,m.,, 1, ,.NM -t..m....- -c,,,d, Table 6 Summary of Groundwater Analytical Results FirstEnergy Nuclear Operating Company Davis-Besse Nuclear Power Station 5501 N. State Route 2 MS3085, Oak Harbor, OH 43449 New Monitoring Wells ISamplee Location I MW-100A MW-10OB MW~v-10C MbAl~w l0A I 51W-1OI1B MW-101 C MWD-102A MW-502B MW-182G MW-103A MW-503B MWV-103C MW801-104AI MW-104B MW~-104G M cW-105A Date Sampled 24-SeL-O7 25-Sep-07 25-Se '-7 2-Oct-07 2-Oct-07 2-Oct-07 25-Sc -07 25-Sep-07 27-Sep-07 27-Sep-07 1-Oct-07 1-Oct-07 1-O-Oct-0 7-Oct-07 28-Sep-07 28-Se -07 28-Sep-07 8-Oct-07 SampleTe N N N N N N N LD N N N N FD (DBD-04) N N N N N Tritius <193 <193 <149 237 207 <193 344 387 394 <193 495 362 394 <149 237 250 <193 1832 Gamma IN D NO I ND I ND DI N I ND I N NO I ND I NO I NO I ND I ND DI NO I ND I ND N ND N Historic Monitoring Wells Sample Location IMtFb'-IS I MW-1D I MW-7S I MW-S 045-120 MW-15S I MW-OD I MW-I8S MW-I Date Sam Wled 12-jun-07 1 12-1 n-07 1 13-jun-07 1 14-Jun-07 14-oun-07 6-Aue-07 4-Oct-07 6-Au -07 4-Oct-07 4-Oct-07 26-jun-07 10-Oct-07 26-Jun-07 10-Oct-07 14-1on-07 14-jun-07 SampleT e e N N D (DBD-01) N N N N FD P DBD-01) N N N N N N TritiumL <330 <330 426 1 657 764 860 276 1,155 1 738 1 769 375 301 704 442 277 1 204 Gamma NO ND ND D ND NA ND NA ND ND ND ND ND ND ND ND Sample Location ItVW-20S MW-20D I MW-23S MW-26S MW-.26D MW-30S MW-30D MW-31S Sample Type N ED (0 -02) N ED (080-02) N N N N N N N N N N N N Tritium 255 279 189 218 328 <174 306 341 <330 1,307 1149 494 231 <174 7,322 3,149 Gamma J ND ND ND ND ND ND ND ND NO ND NA ND NA ND NA ND Sample Location MW-31S NTW-31D MW-32S MW-32D MW-33S MW-33D ] b41344S Date Sampled 5-Oct-0 7 jul-07 8-Oct-07 25- un-07 31-j <-07 31-jul-07 26-jun-07 I 1-Aug 7 27-un-07 I1-Aug-07 3-Oct-07 5-ct-07 27-Jun-07 2-Aug-07 5-Oct-07 2-Aug-07 Sample Type FD (DBD-03) N N FD (BD0-01 N N N N N LD N N N Tritium 3,012 108 183 -5838 7,535 7,185 466 507! [ 2,287 2,702 1,110 1,230 2,975 3,271 1,934 2,839 Gamma ND NA ND ND NA NA ND NA ND NA ND ND ND NA ND NA Sample Location MW-34D lstW-35S MW-35D MIA-37S MW-37D Date Sampled 2-Aug-07 3-Oct-07 3-Oct-07 3-Aug-07 9-Oct-07 6-Aus-07 Sample Type N N N N N N Tritiun, 1,076 227 368 2,961 1,231 135 Gamma NA ND NO NA ND NA NAtes Unt,ý are pC/L ( pii!us pl 51,1 Id ll nIni k ah Ios{n'hrlhn l}cl, eab*ciry di h i'tinimi t ND = N,- dnlintiii~ns aoy,-, lobirstiry hlu-. ]inst ni NA = N- i endly ed FD (DBDl) -Fi,-d Optint (Dininn it dupliexui 55-mph- in Iboratory n~pfrl)LD = LbonLry DiDpliisjDi i -mph! in leh'rat-y epir')Tritium, -nlysiý by EPA MWd-ld 906 (1 GDmma innung rdi,-nulides analyois by EPA Metbid 901.1 Acelyni prfenud by Midwest L.berte,,y G,,nn< imitting eadi nlclid-tsnalysis innluds: Mn-4, F4-59, C-,58, Co-60, Zn-65. Zr-Nt-95. C,134. C-137, Be-Le-140 0 Figures 7, Eý.0 Legend 1:24,000 EI- Protected Area E Site Boundary 0 1,000 2,000 4,000 I Feet Figure 1 -Site Locus Map Davis-Besse Nuclear Power Station Oak Harbor, OH Source: USGS Topographic Quadrangles (o41083e2, o41083e1) 0 Legend-Limits of Grout Curtain ,4 Monitoring Well Installed in August 2007 ,g Historic Monitoring Well A: Till Well Bis: Upper Dolomite Well CID: Lower Dolomite Well L Radiological Area of Potential Concern Radlologlcal Areas of Concern: Low Level Rad Waste Storage Building Dry Fuel Storage Area Training Center Pond NPDES Outfall 002 Sewage Treatment Plant (Abandoned) NPDES Outfall 001 Sewage Treatment Plant (Current)Sanitary Lagoon South Setting Basin North Setting Basin Collection Box Discharge Pipe Collection Box Liquid Radwaste Discharge Line Condensate Demineralized Water Storage Tank Secondary Demineralized Water Storage Tank Fire water Storage Tank Service Building 4 Outfall 1:3,000 0 125 250 500 750 Feet Figure 2 -Site Layout Davis-Besse Nuclear Power Station Oak Harbor. OH ERM Legend Limits of Grout Curtain-$ Monitoring Well Installed in August 2007Historic Monitoring Well A: Till Well Bas: Upper Dolomite Well C/o: Lower Dolomite Well E Groundwater Elevations 24 September 2007" Approximate Groundwater Flow Direction in Upper Dolomite Unit Note: Lake Erie surface water elevation on 24 September 2007 fluctuated between 570.87 and 571.17 (NOAA Marblehead Gauging Station, OH).1:2,400 200 100 0 200 Feet Figure 3 -Groundwater Elevations Till Unit -September/October 2007 Davis-Besse Nuclear Power Station, Oak Harbor, OH Legend-Limits of Grout Curtain 46ý Monitoring Well Installed in August 2007 5,' Historic Monitoring Well A: Till Well BaS: Upper Dolomite Well cio: Lower Dolomite Well Groundwater Elevations 24 September 2007 -Monitoring Wells B/S' Approximate Groundwater Flow Direction in Upper Dolomite Unit Note: Lake Erie surface water elevation on 24 September 2007 fluctuated between 570.87 and 571.17 (NOAA Marblehead Gauging Station, OH).1:2,400 200 100 0 200 Feet Figure 4. Groundwater Elevations Upper Dolomite -September/October 2007 Davis-Besse Nuclear Power Station, Oak Harbor, OH ERM.1 Legend Limits of Grout Curtain-Monitoring Well Installed in August 2007Historic Monitoring Well A: Till Well BIS: Upper Dolomite Well C/D: Lower Dolomite Well Groundwater Elevations 24 September 2007 -Monitoring Wells C/D\ Approximate Groundwater Flow Direction in the Lower Dolomite Unit Note: Lake Erie surface water elevation on 24 September 2007 fluctuated between 570.87 and 571'.17 (NOAA Marblehead Gauging Station, OH).1:2,400 200 100 0 200 IT Feet Figure 5 -Groundwater Elevations Lower Dolomite -September/October 2007 Davis-Besse Nuclear Power Station, O a k H a r b o r , O H , , ,, .ERM Legend Limits of Grout Curtain 4 Monitoring Well Installed in August 2007 S Historic Monitoring Well A: Till Well/ss: Upper Dolomite Well CID: Lower Dolomite Well Results: 46 Tritium Activity in pCVL F- Tritium Activity Below Laboratory Lower Limit of Detection (value indicated) pCi/L picoCuries per Liter Field Duplicate taken. Highest result shown-Confirmatory sample taken at the location in July/August. Analysis performed by Midwest Laboratory using EPA Method 906.0 Notes: Groundwater monitoring samples were taken between 12 and 27 June 2007 during the June sampling event.Groundwater monitoring samples were taken between 31 July and 6 August 2007 during the July/August sampling event (confirmatory sampling event).Highest results of the two sampling events are shown.1:2,400 200 100 0 200 Feet Figure 6 -Groundwater Sample Analytical Results June to August 2007 Davis-Besse Nuclear Power Station, Oak Harbor, OH ERM Legend Limits of Grout Curtain-Monitoring Well Installed in August 2007Historic Monitoring Well A: Till Well BiS: Upper Dolomite Well CID: Lower Dolomite Well Results: W Tritium Activity in pCV/L F Tritium Activity Below Laboratory Lower Limit of Detection (value indicated) pcL picoCuries per Liter Field Duplicate taken. Highest result shown Analysis performed by Midwest Laboratory using EPA Method 906.0 Notes: Groundwater monitoring samples were taken between 24 September and 10 October 2007.1:2,400 200 100 0 200 FIM Feet Figure 7 -Groundwater Sample Analytical Results September/October 2007 Davis-Besse Nuclear Power Station, Oak Harbor, OH ERM 0 F7 A A'6504 -584 -MW-i 52A.B&C 564 -oaIet I =10' 3 75 0 75 150 350 544-524-Legend Grou.nwator Elevation (Upper Dolornite I Potential Migration of Tdtiated Water Groundwater Flow Direction V Monitoring Wea Installed in August 2007 Weon projected on croso-oection Results (SepternmbanOctber 2007)Triiumr Ac00dt0In hr irng wels (pCIVL)picoCures per Liter Grourndwater Elevation FU' and Geologic Units 7' Concrete FI'General Backfil (Earthen)Sttuctrat Backlai (Crosned Rock)Wave PFrotacon Dlke FM (Topsoff Glacolacustrioe Uni T51 Utni Lamninated Dolomite MacsNve Dolomde 504 -Z, HitoDr Monitoring Wea' Weo projected on crors-neacon 484 -SGrout CurtainGap hr Section 464 -60 0 60 120 240 Horizontal Scale (11=120')15 0 15 30 Figure 8 -Cross-Section Showing Groundwater Elevations and Sample Analytical Results Davis-Besse Nuclear Power Station, Oak Harbor, OH Appendix A Boring Logs ERM MW-100A MW-100B MW-100C 399 Boylston St. 6th Floor Boston, MA 02116 PAGE 1 OF 2 Telephone: 617-646-7800 ER/ Fax: 617-267-6447 CLIENT First Energy -Davis-Besse Power Station PROJECT NAME Well Construction PROJECT NUMBER 0065992.02 PROJECT LOCATION Davis-Besse DATE STARTED 8/8/07 COMPLETED 8/9/07 GROUND ELEVATION WELL/BORING DIAMETER 2" DRILLING CONTRACTOR Bowser-Momer, Inc.DRILLING METHOD Sonic LOGGED BY G. Ayres CHECKED BY M. Daly NOTES Boring size is 6" in overburden and 4" in bedrock I W -- WELL DIAGRAM WELL DIAGRAM WELL DIAGRAM Q > 0 MATERIAL DESCRIPTION M AWOMo 0 _SILTY CLAY with some coarse sand and gravel, cohesive, firm, dry, brown with gray mottling.CL-ML 88< II z 1'C 0 7.0 10 CL-ML SILTY CLAY with some gravel, cohesive, gravel content decreases with depth, firm, brown.<a.z 11 18.0 SILTY CLAY with gravel, brown.20 CL-ML 80 23.0 Z II 0S II -CL-ML CLAY WITH SILT 25.0 and some sand, dark 26.0 graY.dolomite.laminated dolomite, light gray.Bentonite chips-Sand-Screen-End cap-Lement 0)Cd)W C-(-Xd a:-u.ement 30 40 50 100 38.0< 00 02< 00 z 1 IitO 0.-0-Bentonite chips-Sand-Screen-End cap-Native backfill E.2 0 0 laminated dolomite, becomes fractured at 42', light gray.i_-Cement-Bentonite chips 100 44.0 no recovery.(Continued Next Page) ERM MW-IOOA MW-1OOB MW-IOOC Boston, MA 02116 PAGE 2 OF 2 Telephone: 617-646-7800 ERM ] Fax: 617-267-6447 CLIENT First Energqy -Davis-Besse Power Station PROJECT NAME Well Construction PROJECT NUMBER 0065992.02 PROJECT LOCATION Davis-Besse Sn "-D M R .D WELL DIAGRAM WELL DIAGRAM WELL DIAGRAM 0j" MATERIAL DESCRIPTION Of MW-00A MW-100B MW-00C 00 _50 a-__ _ _ _ _ _ _ _ _ __ _ _ _ _ _I no recovery.(continued) 60 58.0 60 59.0 massive dolomite, highly fractured, light gray.laminated dolomite, fractured, dark gray.64.0<2" IC OC< I ZI 0 70 50 laminated dolomite, fractured, olive gray.73.0 laminated dolomite, fractured, dark gray.S82.0 C, E 02 0 E.2 0)E M 0j Z z I 80[Al 50 Z II-Sand-Screen-End cap-Bentonite chips-Native backfill 90 W wi CO CO CO U)X ICO 80 laminated dolomite, 89.5 dark gray.massive dolomite, light gray.Bottom of boring at 98.0 feet.= MATERIAL DESCRIPTION
- 0) ' MWll Oo < 2 W MW-101A MW-101B MW-101C 0 0 f __ 0 ý10 15 20 SILT with some sand and clay, firm, cohesive, dry, reddish brown.90 ML-C: Ci"C"U 9.0 SILTY CLAY with trace sand, firm, cohesive, tight, brown.100 CL EL{--0 20.0 0 LL 0)a-F-0)25 30 35 40 CLAY WITH SOME SILT and trace sand, firm, cohesive, tight, moist, dark gray.ME-Bentonite chips-Sand Screen-End cap-Cement-Cement CL-1001ML oLn*II-u O-Bentonite chips-Sand-Screen NOW-Cement 29 5 04-,"- -weathered dolomite and clay, very tight Eýand firm, light gray.laminated dolomite, light gray.10 C,-o2.E0 0 E0-Bentonite chips (Continued Next Page)
ERM MW-IOIA MW-101B MW-101C 399 Boylston St. 6th Floor Boston, MA 02116 PAGE 2 OF 2 Telephone: 617-646-7800 ERM Fax: 617-267-6447 CLIENT First Energy -Davis-Besse Power Station PROJECT NAME Well Construction PROJECT NUMBER 0065992.02 PROJECT LOCATION Davis-Besse L.w .2 MT L Ro WELL DIAGRAM WELL DIAGRAM WELL DIAGRAM w 6 < ",° MW-101A MW-101B MW-101C 0 ý of 0)0 z 40D U) Z a 40 FT I massive dolomite, fractured, light gray.45 50 55 60 65 70 75 80 85 0O-End cap 4. n 80 70 laminated dolomite, gray.48.0 laminated dolomite, light gray.57.0 laminated dolomite, light gray to dark gray.65.0 laminated dolomite, dark gray.79.0 0 C5 02 0 I 0 F0.2 E 0 a M E0 C)_j 0I 50 02 EL-W U)U)w (D 0ýw a a U)90 Ec-Sand-Screen-End cap Bottom of boring at 80.0 feet.0: ERM ERM 399 Boylston St. 6th Floor Boston, MA 02116 Telephone: 617-646-7800 Fax: 617-267-6447 CLIENT First Energy -Davis-Besse Power Station PROJECT NAME Well Construction PROJECT NUMBER 0065992.02 PROJECT LOCATION Davis-Besse DATE STARTED 6/16107 COMPLETED 8/16/07 GROUND ELEVATION -WELUBORING DIAMETER 2" DRILLING CONTRACTOR Bowser-Momer, Inc.DRILLING METHOD Sonic LOGGED BY G. Ayres CHECKED BY M. Daly NOTES Boring size is 6" in overburden and 4" in bedrock 0>-0 C, wu C6 b C)0-0 (D SILT AND SAND with trace clay, firm, CLAY WITH SILT and some sand, firm to hard, cohesive, tight, dry, brown.laminated Dolomite, fractured, gray.(Continued Next Page) ERM MW-102A MW-102B MW-102C 399 Boylston St. 6th Floor Boston, MA 02116 PAGE 2 OF 2 Telephone: 617-646-7800 EIM Fax: 617-267-6447 CLIENT First Energy -Davis-Besse Power Station PROJECT NAME Well Construction PROJECT NUMBER 0065992.02 PROJECT LOCATION Davis-Besse ~Ez--I~~C 'El) 0-L I- w j ._o WELL DIAGRAM WELL DIAGRAM WELL DIAGRAM (6 < 0 MATERIAL DESCRIPTION MW-102A MW-102B MW-102C 4D U_0 45 50 55 60 65 70 75 80 85 massive Dolomite with some fractures, light gray.45.0 90 90 laminated Dolomite, dark gray.49.0 laminated Dolomite, light gray to dark gray.59.0 laminated Dolomite, dark gray.69.0 laminated Dolomite, dark gray.78.0 Lfn Fo oI U., co E E 0 0 (0 E)-J-End cap aQ- Native backfill IA)90 oU.'0 1 02 FL .._-Sand-Screen-End cap-Native backfill U)LU 0-a-(If U)W 80 ZII 02 II r."___Bottom of boring at 80.0 feet. ERM MW-103A MW-103B MW-103C 399 Boylston St. 6th FloorBoston, MA 02116 PAGE 1 OF 2 Telephone: 617-646-7800 ERIN4 Fax: 617-267-6447 CUENT First Energqy -Davis-Besse Power Station PROJECT NAME Well Construction PROJECT NUMBER 0065992.02 PROJECT LOCATION Davis-Besse DATE STARTED 8/21/07 COMPLETED 8/21/07 GROUND ELEVATION -WELL/BORING DIAMETER 2" DRILLING CONTRACTOR Bowser-Momer, Inc.DRILLING METHOD Sonic LOGGED BY G. Ayres CHECKED BY M. Daly NOTES Boring size is 6" in overburden and 4" in bedrock 0E-C 'W C DSRPI .N2 WELL DIAGRAM WELL DIAGRAM WELL DIAGRAM u MATERIAMW-103A MW-103B MW-103C 0 No recovery.0<2 z 1i Z II II .r 0)C U 0 U 0 10.0 10 60 CL-ML SM CL-ML CL-ML SILT AND CLAY with some sand and 13.0 trace gravel, firm to 1 soft, cohesive, 14.0 brown.16.0 \ SILT AND SAND 1 6 .0 w-.wit h s o m e g r a v e l, firm, cohesive, gray.CLAY with silt, orange motteling, firm, cohesive, gray.and some sand, firm, cohesive, brown.---20 30 100 C 26.0-Cement-Bentonite chips-Sand-Screen-End cap CLS CLS-Cement V CLAY with some sand and cobble fragments, firm, 30.0 cohesive, tight, dark... gray.CLAY with some sand and cobble fragments, firm, 34.0 cohesive, dark gray.weathered dolomite, 36.0 white.laminated dolomite, gray.100 C II ac Bentonite chips-Sand-Screen-End cap-Native backfill-Cement-Bentonite chips 0.0 0 40 40.0 I laminated dolomite, gray.44 n 80 I massive dolomite, gray.0 0" C E 0o 48.0 50 (Continued Next Page) ERM MW-103A MW-103B MW-103C~4L. 399 Boylston St. 6th FloorPAE2O2 Boston, MA 02116 PAGE 2 OF 2 Telephone: 617-646-7800 ERM Fax: 617-267-6447 CLIENT First Energy -Davis-Besse Power Station PROJECT NAME Well Construction PROJECT NUMBER 0065992.02 PROJECT LOCATION Davis-Besse -E-c-~w D R I .WELL DIAGRAM WELL DIAGRAM WELL DIAGRAM w 0 V5 _< M MW-103A MW-103B MW-103C~ 2: 0" "J w 0 52.0 laminated dolomite,\dark gray.(continued) laminated dolomite, brown to white.90 03 0 02 58.0 60 8059.0 laminated dolomite,~laminated dolomite,__ 62.0 brown.laminated dolomite, dark gray.laminated dolomite, 1 79.0 dark gray.-o 0-E2 0_j 70 90 02 II 11 80 Bottom of boring at 80.0 feet.-Sand-Screen-End cap-Native backfill 11 0 ui V)Cr 90 100 P I~L.LJLL 1 4. ERM MW- 04A MW- 04B MW- 04C 39 Boston, MA 02116 Floor PAGE 1 OF 239Boyston, St. 016tFor Telephone: 617-646-7800 ER.4 Fax: 617-267-6447 CLIENT First Energy -Davis-Besse Power Station PROJECT NAME Well Construction PROJECT NUMBER 0065992.02 PROJECT LOCATION Davis-Besse DATE STARTED 8/23/07 COMPLETED 8/24/07 GROUND ELEVATION -WELL/BORING DIAMETER 2" DRILLING CONTRACTOR Bowser-Momer, Inc.DRILLING METHOD Sonic LOGGED BY G. Ayres CHECKED BY M. Daly NOTES Boring size is 6" in overburden and 4" in bedrock*MS WELL DIAGRAM WELL DIAGRAM WELL DIAGRAM W 0 <MW-104A I MW-104B MW-104C W 0 )0 F__ _ _ _ _ __ L __ _FILL M1.0 GRAVEL.5 10 15 20 25 30 35 4n 10 I2 II i DC Co Ui i_09 CL-ML SILTY CLAY with some sand, trace gravel and cobbles, cohesive, dry, brown.14.0 cc.55 U)U)0j 10 LU a-U.i (n LI-- II MC.LL 15. CLAY with trace silt _CL- and sand, soft, cohesive, black.CLAY with some silt CL- and sand, firm, ML cohesive, brown....23.0 CLAY with some silt C and trace sand and C:I gravel, soft, II cohesive, dark gray. 0 CL-ML M30.0CLAY with some CLS sand, wet at 32 ft, 32.0 firm, cohesive, dark weathered dolomite, light gray. 1 35.0 C n--Bentonite chips-Sand-Screen-End cap-Cement 100 100-Cement-Bentonite chips-Sand-Cement-Bentonite chips laminated dolomite, gray to light gray.01 02 0-j 4An n (Continued Next Page) ERM MW-1 04A MW-1 04B MW-1 04C 399 Boylston St. 6th Floor PAGE 2 OF 2 Boston, MA 02116 Telephone: 617-646-7800 ERMV Fax: 617-267-6447 CLIENT First Energy -Davis-Besse Power Station PROJECT NAME Well Construction PROJECT NUMBER 0065992.02 PROJECT LOCATION Davis-Besse MT ER I A ._2 WELL DIAGRAM WELL DIAGRAM WELL DIAGRAM 0.~ -- a) )MATERIAL DESCRIPTION o MW-104A MW-104B MW-104C 40 F.P 45 50 55 60 65 70 75 80 85 laminated dolomite, gray.-Screen 49 0 50 70 masisve dolomite, light gray... .45.0 laminated dolomite, dark gray to white.... 57.0 laminated dolomite, gray.69.0 laminated dolomite, gray to dark gray.' .79.0 0 I-0 E to"0 E 0 0-J-End cap-Native backfill Il)90 I-0 II C Eu-Sand-Screen-End cap-Native backfill C)co)CD 90 (C CL Bottom of boring at 80.0 feet.Il) ERM MW-105A 399 Boylston St. 6th Floor Boston, MA 02116 PAGE 1 OF 1 Telephone: 617-646-7800 E]RM Fax: 617-267-6447 CLIENT First Energy -Davis-Besse Power Station PROJECT NAME Well Construction PROJECT NUMBER 0065992.02 PROJECT LOCATION Davis-Besse DATE STARTED 8/28/07 COMPLETED 8/28/07 GROUND ELEVATION -WELL/BORING DIAMETER 2" DRILLING CONTRACTOR Bowser-Momer, Inc.DRILLING METHOD Sonic LOGGED BY G. Ayres CHECKED BY M. Daly NOTES Boring size is 6" in overburden and 4" in bedrocka U ý_ W ._o WELL DIAGRAM> o L 6 MATERIAL DESCRIPTION ) " o WELDAA WELL DIAGRAM WELL DIAGRAM (D 0 ___________________ _______________ 5 10 15 20 FILL SANDY SILTY Asphalt sub-base, 2.0 loose, dry.20 cZ 0_2 0J U 0 U m 0 CLAYEY SILT with some sand and trace gravel, gray mottling, moist, brown.100 ML 20.0 (D 0 U)a-U)25 30 35 40 CLAY WITH SILT and some gravel and sand, wet at 27 ft, weathered bedrock fragmetns starting at 6.5 ft, dark gray.Cement Bentonite chips Sand Screen-Native backfill CL-ML 100 28.0 weathered bedrock and clay, light gray.Bottom of boring at 28.5 feet. Appendix B Data Assessment June &July/August 2007 Monitoring Events 0
1.0 INTRODUCTION
This section presents a quality assurance and quality control (QA/QC)review of the Davis-Besse June and July/August 2007 well groundwater sampling events. This evaluation was conducted to assess and enhance the reliability and validity of the groundwater analytical data. The verification process was conducted to identify the most common sampling and analytical problems that could affect the quality of the results. In general, the results met the data quality objectives.
2.0 QUALITY
ASSURANCE Quality assurance involves planned and systematic actions necessary to provide confidence in the analytical results. The goal of the program is to have a program that is operating within acceptable criteria; thereby enhancing the representativeness and comparability of the results.Qualitative measures include items related to the field as well as the laboratory activities.
2.1 SAMPLING
PROGRAM The procedures used to collect the groundwater samples were detailed in a FSP (ERM, 8 June 2007). Specifications, such as well locations, well construction, sampling intervals, sampling and analysis techniques were items among others that were described to help collect a useful data set.A list of sampling locations and analytical program summary tables were provided for the July/August 2007 groundwater monitoring event.Groundwater samples were collected by personnel from BETA Laboratory. Field notes were reviewed to confirm that the procedures were executed properly. The following information reviews items that were included in the field sampling quality assurance program.Sampling documentation -The sample team maintained a field notebook (bound weatherproof logbooks) that was filled out at each location where a sample was collected. It contains the sample designation, collection time, description, and field instrument calibration log. The team also completed a Low-Flow Groundwater Sampling Form at each monitored location. The forms present information regarding location, weather, time, well construction, ERM/DADE MOELLER 1 FIRSTENERGY -DAVIS-BESSE 0065992.218 MARCH 08 sampling depths, sampling device, field parameters and sample containers. The completed Low-Flow Groundwater Sampling forms are included within Appendix B." Sample Identification -Well IDs were used to identify the groundwater samples. The same codes were used to complete the chain-of-custodies (COCs). Duplicate samples were recorded as blind samples. Actual duplicate sample IDs were recorded on each Low-Flow Groundwater Sampling Form. COC records are included within Appendix B." Decontamination -Dedicated high density polyethylene (HDPE)tubing was used at each location. Wells were sampled using a peristaltic pump (no decontamination required).
- Calibration and Preventive Maintenance of Field Instruments
-Sampling team personnel calibrated the geochemical parameters probe every day before starting the sampling. Calibration logs were maintained in the notebook. ORP readings did not stabilize during June sampling of well MW-20D. The ORP probe was cleaned after this sampling and the meter accuracy was successfully checked utilizing calibration solution. Dissolved Oxygen reading could not be taken for about 57% of the wells sampled in July/ August 2007 due to probe interference with hydrogen sulfide.* Sampling locations -All locations were sampled as planned in the FSP." Gauging -A synoptic water level gauging round, including all of the monitoring wells selected for the evaluation of tritium and gamma emitting radionuclides, was performed on 11 June 2007 prior to sampling.* Sampling Depths -Sampling depths were reported on the individual Low-Flow Groundwater Sampling Forms. Sampling depths were consistent with sampling depths recommended in the Field Sampling Plan." Field Duplicates -All duplicate samples were collected in accordance with the FSP.ERM/DADE MOELLER 2 FIRSTENERGY -DAVIS-BESSE 0065992.218 MARCH 08
2.2 ANALYTICAL
PROGRAM Groundwater samples were analyzed by MidWest Laboratory for analysis of tritium by EPA Method 906.0 and gamma emitting radionuclides by EPA Method 901.1 as specified within the FSP. MidWest Laboratory currently performs radiological environmental monitoring for over 20 nuclear power plants in 11 states. In addition, the laboratory is certified to perform analysis of drinking water for radionuclides in Illinois, Indiana, Wisconsin, and Kentucky. Midwest Laboratory maintains a Quality Assurance / Quality Control Program based on 10 CFR Part 50, Appendix B and Reg. Guide 4.15.3.0 QUALITY CONTROL The analytical data were assessed in terms of precision, accuracy, representativeness, comparability and completeness (PARCCs) to evaluate the usability of the results generated. Quality control items were evaluated through laboratory checks (e.g., matrix spikes, duplicate samples), and sampling method reviews (equipment blanks, trip blanks).In addition, MidWest Laboratory has participated in interlaboratory comparison (crosscheck) programs since the formulation of their quality control program in December 1971. Results of the interlaboratory program are presented at the end of this appendix.The following information provides background on the types of QC samples that were used to assess if the data quality objectives of the sampling program were met.Equipment Blanks -Equipment blanks are samples collected to evaluate the potential cross-contamination of samples due to the sampling equipment. They are collected by pouring deionized water over the sampling equipment which comes in contact with the groundwater sample. During the June and July/August 2007 sampling event, all monitoring wells were sampled with dedicated equipment. Therefore, no equipment blanks were collected. Field Duplicate Samples -Field duplicate samples are analyzed to check the accuracy and reproducibility of the laboratory analytical techniques. A field duplicate sample is taken from the same monitoring well, one immediately after the other using the same sampling device. Field duplicates are typically collected at locations where concentrations of COCs are expected to be present. As recommended in the field sampling plan, two duplicate samples were collected during the June 2007 sampling event (sampling ERM/DADE MOELLER 3 FIRSTENERGY -DAVIS-BESSE 0065992.218 MARCH 08 locations MW-12S and MW-20S), and one during the July/August sampling event (sampling location MW-32S).Laboratory (Split) Duplicate Samples -A laboratory duplicate sample is created when the laboratory splits a normal field sample.It is conducted to evaluate the precision of the laboratory. The laboratory conducted the analysis of one laboratory duplicate sample for the July/August sampling event (duplicate of field duplicate sample from location MW-32S)." Matrix Spike and Matrix Spike Duplicate samples -Matrix spike samples and matrix spike duplicate samples are normal field samples to which a known quantity of a chemical constituent is added in the laboratory. Spike samples are used to evaluate the precision of the laboratory and the effects of matrix interference on the analysis. MS/MSDs are typically collected in areas where concentrations of COCs are expected to be low. Spike samples were collected at MW-26D by collecting two additional samples as identified in Table 3. Samples were spiked by the laboratory with a tritium standard of 5,639 pCi/L and analyzed as actual samples.Assessment of data quality based on compliance with PARCCs criteria is presented below.* Precision -United States Environmental Protection Agency (EPA)guidance suggests that the Relative Percent Difference (RPD) of field duplicates should be less than 30 percent in water samples.The RPD is calculated as: RPD = I Sample -Duplicate I (Sample + Duplicate) / 2 Calculated RPD values for the tritium results were within guidelines, as presented in the following table.Field Duplicate RPD Calculations Sample Duplicate Sample Duplicate RPD ID ID Result Result MW-12S DBD-01 657 764 15 %MW-20S DBD-02 255 279 9 %MW-32S DBD-01 7,535 7,185 5 %FIRSTENERGY -DAVIS-BESSE 0065992.218 MARCH 08 ERM/DADE MOELLER 4 " Accuracy -Matrix spike/matrix spike duplicate (MS/MSD), and laboratory duplicate sample are documented in the attached laboratory reports. These indicators are used to assess if the matrix may be biasing the reported results high (generally based on greater than 130 percent recovery) or low (generally based on less than 70 percent recovery). RPDs are generally expected to be less than 30 percent between MS and MSD results.As shown in the following table, all RPDs for tritium and cesium were within acceptable ranges.Matrix Spike/Matrix Spike Duplicate RPD Calculations Sample Spike + Sample ID Compound Duplicate ID Initial Sample Result RPD Activities MW-26D Tritium MS01-MW-26D 5,639 5,000 12%MW-26D Tritium MSDO1-MW-26D 5,639 5,055 11%MW-26D Cs-134 MS01-MW-26D 59.3 62.9 6%MW-26D Cs-134 MSD01-MW-26D 59.3 59.1 0.3%MW-26D Cs-137 MS01-MW-26D 66.3 64.2 3%MW-26D Cs-137 MSDO1-MW-26D 66.3 70.0 5%No Cesium was detected in the actual samples. Values indicate actual spike activity." Representativeness and Comparability -The representativeness and comparability of analytical data was qualitatively evaluated by comparing samples from the same locations for the June 2007 and the July/August 2007 monitoring events.Groundwater Tritium Results Comparison -1st & 2n5d Sampling rounds Monitoring June 2007 lulv/August 2007 RPD Well MW-12S MW-30S MW-32S MW-32D MW-33S MW-33D H-3 Activity 764 1,307 5,838 466 2,287 2,965 H-3 Activity 860 1,149 7,535 507 2,702 3,271 12%13 %25 %8%17 %9%NA: Not Applicable Consistency between the monitoring events indicates that the sample results are representative of the site conditions. ERM/DADE MOELLER 5 FIRSTENERGY -DAVIS-BESSE 0065992.218 MARCH 08 " Completeness -Based on review of sampling and laboratory check-in procedures, as well as field and laboratory QA/QC results, the data is considered to be complete and useable.* Sensitivity -The MDCs were consistent with data quality objectives for the gamma emitting radionuclides as they ranged between 1.4 and 14.7 pCi/L. The MDCs were consistent with data quality objectives (at least 200 pCi/L) for tritium with the exception of detection limits of 330 pCi/L at 4 locations during the June 2007 sampling event (MW-1S, MW-1D, and MW-26D). The 200pCi/L value corresponds to an environmental level that would allow evaluating an eventual release of tritium to the environment.
4.0 CONCLUSION
Based on the review of the QA/QC information summarized above, the data meet the data quality objectives defined in the FSP and are usable for the intended purposes of supporting the final selection of locations for new monitoring wells at the site.ERM/DADE MOELLER 6 FIRSTENERGY -DAVIS-BESSE 0065992.2 18 MARCH 08 Site Name: n 0 Low-Flow Groundwater Sampling Form Wpflfl IT): Z Well ID, / -4Z'Date: to,/la 97 5amrilinePersclmiel: "",-, .-A~~ !f/,ttA Aiil~Weather Condition: S &- ,z-. .A-/,; Y" .. _- 4r rime: &~~~~C'OT File Name: Iotal Depth (I.D.): ... Screen Lenjh: Depth to Water (D.T.W): .'r<HKP Well Diameter: -" Total Volume Purged: 5' '. Casing Type: fC ;.Purge Rate: 17C,
- Sampling Device: /-#5(%-., Tubing Type: P --Measuring Point: c0 ef Le.Pump Intake (ftbelo;*
M.P.): color: odor: Time: DTW: Comments: Temp SpC DO pH ORP Turb (mlin) (feet) QC) (uS/cm) (mg/L) std units mV NIU Stabalization (see note +I- +1- +i- +1- +J- +A-Criteria 4 below)e 3% 3% 10% 0.1 unit 10 mV 10%, 0:00 /I, r 2.,, _. z ,/. 7 ,"/ .,k " ./, 7-5:00 13H 1 q ?i " "'-j % 1)-10:00 77 -5c- 72Z ,1175-u ix;o ~~15001 .5}?-:Th./a,/3 .47CPJ i "Z/ 15:00 1 I ;'"'25:00 i3 4/ 7 , 17.L 5/ &A5 7,,29 iih 30:00 , --,',, /-,. jiC., , 7,-2.. -79 / o,-35:00 &L Zt'iA ./si --7-a& -c?Z-33 1-57 65:00 ;12 L ";3 ....70:007 rSC 1/2~J~ 2,11 AZ7oI&. 7ý0Z e7 75:00 70 _ al 17' ..__.60:00 .2.L1 1/1-1,~sal .j r19 atC 85:00... ?q ;iv;c I q4g -7 O;z 90:00 iff) ~ iLi' C-1 q 1,7 /6, A), /C LOY1 -j' j e~100:00 _____ ___________ ___ ___ ___ ___ ___105:00 ____ __________ ___ ___ ___ ___ _ __110:00 ____ ___________ ____ ____ ____ ___ ___ _ __r 115:00 _ _ _ _ __________ _ _ _ _ _ _ _ _ _ ___ _ _ _ _ _ _120:00 ____ ________ __Sampling lime: ; ~ .~ $6 Samp~les Collected: Analysis Requested: Preservative: Holding lime: Lab: Notes: 01 :Do nsot ieaasuae depth to bottore of weH utslt after puarging Ind -ptrspig to reduce mesuspeedrlig fine, that array be resting on the wrell brottaom (2;. Starblitearor criteia hased -r three oustwl eoet Cseemrt,,e reneassn ere, ())- Total dar-dsssaiarraellto beteroatthan 01to rrrWnft) Purgingat, to belowered asenecsaryto keep d -arros below 0.lalo(032ftr) (4) -/- 10% ehear toahid it s ..e 10 lITI. Site Name: p Low-Flow Groundwater Sampling Forn Well ID: nfltJP --D)Date: /I lo, Ir'7-sampline P&sonnel: C., .LX1hxk Y rlCoc' LLr'-r t, A. P-_rc'i deS Weather Conditions.: ji.y A 'F-C-.0'File Name: M IU : I b lotal Depth (I.D.): Sci eeenggth: 7 C)Depth to Water (D.T.W): a ) .Well Diameter: .'" Total Volume Purged: ý q eQ, Casing Type: PV 'Purge Rate: g p,- n.L Sampling Device: '# Pitr-.Tubing Type: ff-"'A'J,-'As2, Measurin Point: C)- Pump Intake (ft below M..P.): -70' ,,"dor Time: DTW: Comments: Temp SpC DO pH ORP Turb (mir) (feet) M(C) (uS/cm) (mg/L) std units mV NTU Stabalization (see note +I-- +/_ +/- +I- +/. +/_Critefia, below)' 3% 3% 10% 0.1 unit 10 mV 10%, 0:00 2. ý13 Kir- (A/4S ,ý4 r -'0,,~-~ ., 5:00 19,A' j,.2 ,of7/,0 , / ,S -.' )70 -_12,G.10:00 -,3 1 .V jq/,/5,,.5, ILt.a i7 17 V.33 G& .' .-/3k? X.6_4 20:00 ]1 .fj I /1., 1 I-. /M&K- i2/5/11 .-4 1 .4 2-5:00 /,..q ,O, /n.,...,i." Azoq [A,:W e..ý -;,' ', 30:00 .15-.13 .../i=,33 t,-7 v-.3.5 1,,, 7 35:00 I5,L /2 ti.. Vie. Z qi,,i, V_:.5" ,,$" .7rI 55:00 /c.7 ,:~ ~n-' ~i/ ~ 7 _45:00 , _" ,,,. / //"a 63 4, q-5.-1 .e, X.-7 60:00 -_-65:00 70:00 75:00 80:00 85:00 90:00 95:00 100:00 105:00 110:00 115:00 120:00 Sampling Time: ]37- -3f9q Samples Collected: Analysis Requested: Preservative: Holding lime: Lab:-MfV.Ili I ') J.A-rIUIL, .AAPV.1A P3 c:,.-2.Notes: (1) -Do not -teatore depih to bottom of we-1 .ntit oe- po.rging and mmptig to rodooe -eou pntrding Fine that nay be rtMettfg oo ho wel- bottom (2) -Sbabilkat-oe rietceia b.tdon three none aecetý t co-oecvo ut (3) -Total dtawdown in elle to be ess thatO 8t )m(032 ft) Porging rote to be looened as noosntry to keep deowdo o below 0 tlm (03.2 it)(4) -/, 10% nbh-n totbidity in o-er 10 NTTU.ot Ot0..-, n 1 .t./. Ot-Site Name: L Low-Flow Groundwater Sampling Form Well ID: Ms i t- -*7-'Date: /-. I ).' 1 cs-i Sampling Persdnnel: C L6ieO-1./b,-u,-,, A .vo2lc/ , Weather Conditions: M-.- A)~r7 Time: 13"O-File Name: Ibf3fAW -7S Total Depth (I.D.): _?Y.' 413 Scren : Lnfg,-.Depth to Wate, (D.T.W): 5L. Well Diameter: 3" Total Volume Purged: , Casing Type: Purge Rate: ,21t1 o Sampling Device: 171-a 5 -td Rte *-;,4-%-0 Tubing Tye: Point. 7 oj tor f'C Pump Intake (ft ýJqif color: fdd,ý odor: d.t-g .Time: DTW: Comments: Temp SpC DO pH ORP Turb (min) (feet) (QC) (uS/cm) (mg/L) std units mV NIU Stabalization (see note +/.. +/- +1- +/- +/- +/-Criteria' below)" 3% 3% 10% 0.1 unit 10 mV 10%, 0:00 5.'76 Jl 70~ ote /"4 /117- M--,z-5:00 .5,-74o /6-.q -iJr17-7 4.5 7. 71- .-/,o i. 6-1 10:00 _4", -5.S f2 A,2,x f-7,V 00 ;?/ ~Y,3 73' 7. Y d: -IF 15:00 ,-.74 .2/0 A ,"ve-v )J79 q, 5fa 7-31 )o,7 o,'Y7 20:00 a#,5 ?04 &Ji / i7g/ !7 7,3i -, 25:00 .5I,7& 4 .qM ikJ.5. /7 7,ý 1 ii 6, " 30:00 S,7 -7 Z/ '.. j?.Y? /S641 %.N 7,3, 35:00 4 1 A b/t7 40:00 jj4A 16.93 / 7e 7 & -71 45:00 A 1 7L e 5At& V-7 60-5 7-AO 50:00 -7 65:00 ___ _ __ __70:00 -V, -7 b It qy 95:00 I00:00 75:00 80:00 85:00 90:00 95:00 ____ ______________ ___ _ __100:00 ____ ______________ ___ _ __105:00 ________110:00 ________ ___115:00 ____ ___ ___ __ __120.00 _____ ____________ _ __Sampling Time: /.3 / %.$-Samples Collected: Analysis Requested: Preservative: Holding Time: Lab:'75i giri ,,: , n-s'ji.Notes: (I) -Do not measore depth to bottom of well unti after purging and Sm'tpttg to reduce remsupending fines that may be restfig on the wett bottom (2), Stabillzation criler. bated,,n three 01St tere t otreouthve mteastrementst. (3) -lToet dmawdom ,o, wtel to be let dhano, lt m0.32 it). Purging rate totbe (owered a, setre.sary M keep detwdo-e below I m to(D.32 i0).(4) o/- 1 /0 when turbidity is over 10 NTUs Site Name. 1) Z25[ ow-Bow Groundwater Sampling Form'Well ID.: MI/., I -[Date: &II//WC 7 Sam-oling Personnel: rý ,~ R~r~~--i .1-L1%--1eb' Weasthmr Cooinins 7V 7,2 TileNme: 4'/,.Depth toWatez. (D.T.W): ' ,j ;15 WeU Diaete,: 3 Total Volume Purged: Sz, Type:. )0 Pump Intake (ft below 1VLP.): 3color: e,& -odor: /t"A e Time: DTW: Comments: Temp SpC DO pH ORP Turb (min) (feet) CC) (uS/cm (mg/L) std units mV NTU Stabalization (see note +/- +I- +1- +1- +1- +J-Criteria' belowf 3% 3% 10% 0.1 unit 10 mV 10%i 0:00 0 ,13- 16,£ ql / iO, 7 V--5:00 i,.. / Z .e,, , //,Y-0 I 10:00 , , / ,'fe{ a/Oi ', 7f/, ,'?'15:00 50:00 V44 7_0__ _ 3__ 0 25500 190___ A7__________ f___7,_P1 60:00 11L.4 P,&' -7,11 -L/,9 1-4,9 65:00 70:00 /7vk 75:00 80:00 85:00 90:00 95:00 100:00 105:00 110:00 [115:00 120:00 Sampling lime: 6 .'79 /VO 7 Samples Collected: Analysis Requested: Preservative: Holding lime: Lab: b6- -ra, 1m GMA Notes: (I) -Do -r neasre depth in bottoni O wri9 ..nil afien purging ared snmplineg to reduce resuspendlng fines that may he esting [n he well bod0nm (2). StnbBadton criteria bard n three ment recent eirernn.(3) Tetal drnwdonn in wel ito be lens tlina O]lm (032 ft) Purging rae to be inoered as necessary to keep drawdorn below 0 I o (0.32 It)(4) ,/- 10% niwhen turbidity in oner 10 NTUs Site Name: _ _ _ _ _ _£ ow-Flow Groundwater Sampling Form Well ID: n'l. i j 1 i. S-,S iDate: +/-&2 Sampling Personnel: (S., "?j)t4qb ietzf'rgr --, 'r , C-la Weather Conditions: -7 7" -.E Cah-v Time: jVL-, U File Name: jfdM Iota]l Depth (ID.): Screen ength: 3-.l Depth to Watei (D.T.W): 01 Well Diametei: =$ " Total Volume Purged: Al' W?,f.. Casing Type: P Vt-Purge Rate: 6215" ,aw-/u" Samplig Device., t-t-vY'Tubing Type: -Measuring Point: " O F Pump Intake (ftbelow-M.P.): ,. color: e,&d-e odor: AC1.-Time: DTW: Comments: Temp SpC DO pH ORP Turb (min) (feet) (Q) (uS/cm) (mg/L) std units mV NIU Stabalization (see note +1- +1- +/- +/- +/- +/-Citezia2 below)t 3% 3% 10% 0.1 tnail 10 mV 10%, 0:00 MAWA-V -,/. -7,0 , .-W 2 Zy ...Y 'W'/ a, A-,615-; 7.,311 .&!g 50:00 14/ ~ ~ A& ? 46C 15:00 4 1673 --/7162 R, 20:00 q, Y-6ft/t, ~ ~ 7 ~20:00 /,ý ____Id?_ __? j t2.7 ZZ '/ :P4Y 50:00 /3,k /,-'i .aM'S 0. 7.ge '0,'71 55:00 2 0,4-- -1117,7 60:00 44,;?60:00 al & /;-O-- a .014W, 75:00 4 .0,/9'80:00 /9-46 aqK 91 85:00 810:00 815:00 90:00 95:00 _____ ___________ ___ ___100:00 ________105:00 _____ ___________ ___110:0 _________D___ 115:00 ___________ ___120:00 1____ _______Sampling lime: -/4f." /936 SamplesCollected: Analysis Requested: Preservative: Holding Time: Lab: 1_ ) -J -15" 4z"7k 1 , 14 A Notes: (I).- Do rot measom depth to trottont Ot well tstti after purginrg ted nanmptig to reduce tenoopendlog foes thsal may Ire aretiog on the ro] ottIoflm (2)- Shbilimto criteria bated on three mos,- reent coecuftvte measurements. (3)- Tota drondore as welt to be et than 01 es (032 It) Psrging rate to he lotered -s recesooty to beep drowdowo belw III m (a 32 It).(4) t/- 10% shent trbidity Is ovet 10 NTUs. Site Name: X> .b L ow-Flow Groundwater Sampling Form Date: 4,Ic" Sampling Personnel:. 'o ,_7j~Y .(cC ,,z.r'+6i .___,__,____-_ Weather Conditions: I-E5 -" 'Time: i3 JCC rite Name: % %0t V IDphSScreen Length: 7 Depth to Water (D.T.W): (1) i3,.?;/" Well Diameter: , Tubing Type: [Jd 2"Measuring Point:"T,"- DPd.... : ,[Pump Intake (ft b ový-M.P.): '2,.color: ý ., odor: , U Time: DTW: Commnents: Temp SpC DO pH ORP Turb (rain) (feet) i'cQ (uS/cm) (rag/L) 'std units mV Nr'U Stabalization. (see note+- +- +- +- +- +-Criteria' below)'* 3% 3% 10l% 0.1 unit 10 mV 10%, 30:00 , , / __,_ __- _40:00 A 74Q/342 50:00 4a WO ., 7 Y .7,4S , 5 307,$ 3 75-00 wi A S/W 65:00 IgY v'7o~o qa
- I.j4 Q'/d q~#6 7,f/` --3t9 $.1Z-75:00 i -_j 4"71 80:00 TO5:00 90:00 95:00 100:00 105:00 110:00 115:00 120:00 1-Sampling lime: / -. " qj5 Samples Collected:
AnaLysis Requested: Preservative: Holding lime: Lab: Noteiss (1) Do not measure depth to botlom of well until alter purging and sampling to reduce -ennsprding Inmse that may be resting on the well bottom (2)- Stalllaatjon criteria based on hree most recent ronsectutive measurenotus (3)- Tol drawdown in well to be les that 0.l or (0.32 ft). purging raet to be lowered no ccesnry to keep lwdown below 0.1 m (0.32 flt (4) +-/ 10% when turbidity is oer 10t NWo Fite Name: -06 Low-e tlow Groundwater Sampling Form WeT otID; ed:- C an e Date: / IS D -Y Sapuing Personnel: eau. Point: r- ,,,,, -f Fle Name- (,tV9`74c11_f5 Total Depth (I.D.): ý,g at/ Sth: W)S5f Depth to Water (D.T.W): (') Diameter: Toa ouePurged: Casing Type: y'0 Purge Rate: Device: e.a Tubing ./-, Measurina Point: " oq : Pump Intake (ft belov M.P.): ,Z5' color: odor: Time: DTW: Comments' Temp SpC DO pH ORP Turb (rain) (feet) (`C) (uS/cm) (mg/L) std units mV NTU Stabalization (see note +- +1- +/ +1- +/-Criteria' belowla 3% 3% 10% 0.1 unit 10 mV 10%'0:00 /3.'1/ VaOV-/4,, )5.77 123q 12,50 -9,6 1 13,7 -:, D 5:00 /i,&O 16_ ht IA I5gl' / aljq i40 'r, 44 ig, I q,7 I 10:00 j4 1 J4 ji Qo / is.03 #. 22-7 t /I ' (".'7 3 ,. 5.70 200 ____/__(_,_ -_. 30:00 /Ph i& 0S 0 1t /oigtn .Y,,4.4 , ,, 27 1.3 7 4 30o0 :, /j3q g57 166 .40:00 /o,5 /5,O" , 0 -1.2..q. 7 .r, 35:00 7gj30j 777P / 7 ia57 g, Y '1;7 6 --7,, 55:00 -17 X, 7 60:00 !!rl 5.6, 75:00 I _____7_80:00 /A_ _ 3__3.2 85:00 90:00 95:00 100:00 805:00 110:00 915:00 115:00 _____ ______ ___120:00 Sampling lime: /".O0"- / -.30 Samples Collected: Analysis Requested: Preservative: Holding lime: Lab: m/r2.-/ z .Notes., (l .- Do not measure depth to bottom of well until after purrginn and amperling to reduce ronuopending fine thW otay be restingon the well bottomr (I) -Stabilization criteria ,ased o three moSt oecert coerecutive ,rcasurremei (3)- ol'tl drawdown in well to helw hanl or(032ft) Purtogratthbe lOwered as neressary to keep droawdowolobeloso
- 0. nm ((.32 It)(4)./- t( swheon turbidity Is twor 1 N'Ir.
Site Name: r26'3 Low-Flow Groundwater Sampling Form Well ID: -- 2?)z ell ID: lVbl,,e I -I VI)Date: 4//'/il07 Sampling Personne: C .4'0id J7,:Ar./ A. A r%'IVi Weather Conditions: 7' r, ' ..Y .Time: ,',Yf .File Name: Total Depth (I.D.): 74-,e'Z' /gth: Depth to Water (D.T.W): (1) /ý.q. 7 Well Diameter: 3" Total Volume Purged: _W1 Casing Type: N4 purge Rate: f[e0411?/Atd4 -Sampling Device: fi/VY/.U'i C i Pubing Tye: Of 4 Measuring Point: 51aW0" .Pump Intake (ft belo-w M.P.): 13 color: &,.1d, odor: A,/ai/]Time: DTW: Comments: Temp SpC DO pH ORPI Turb (min) (feet) ('C) (uS/cm) (mg/L) std units mV NIU Stabalizatdon (see note +/_ +/- +1- +/ ÷/- +/-Criteria4 below)' 3% 3% 10% 0.1 mnit 10 mV 10%, 0:00 ,3. -1 :a I a 7.L/o,1. 3 -,9 1,5 i0 7.- ( / qS.T o3 5:00 /3. P& , Ac-/7b /7.,56 A *"467,' -1=0 -. 62-10:00 1qz _,-o / 7.0Id9.T d,30... 7. &S -////0 -4.J 15:00 30 /r 17.g V 6 g~ 4' [ Y"l,1 7.&7 20:00 ',/-..S&n ' -. 17.76 Tq'Q Q05/ ., 25:00 _gq i___ý "A_;/7 7 30:007.& Rg* ) 7/,q '-5?,y? !,39 35:00 -/. q , i- Y aL lJab. 17,91 6,/.5 2q 71,q -46/ 0 40;00 76T I h%4' /9,30 bq,7 O,,A,-i 7.7-00, 45:00 &9,, (.0O O,2 7 7,70 A k./50:00 179 30 % __17 55:00 #,, 4, -f 31 7,70 -,, 60:00 /17. /-If 71 .7Ml3 oO 7,70 ..do1 L?65:00 17, / 23/0, 1707d r, , 1 70:00 77,__ /__,_____,__ /Y_.________ 7.71__'_._l 75:00".. .i-c 80-.00 85:00 90:00 95:00 100:00 105:00 110:00 115:00 120:00 Sampling lime: 1-/006 /Ii(7 Samples Collected: Analysis Rfequested: Preservative: Holding lime: Lab: 5AI6fL Notes;1) -Do not tea.ut. depth to bottoml owelt until after purgtng and sampling to reduce -pending ren; that may be tesing on the we-1 bottom (2) -Stbiliztion criteria based on theer most recent cousecutive mebucements. (3) -Toutu drandown in well en be lem than 0.1 m (OM 11). Puging rate to be luoered ., n-e-essry to keep druwdowe below 01 o 10.32 it).() 4/- 10% when turbiditlyls ver t0 NTIJs. Site Name.: L.13 Low-low Groundwater Sampling Form Well ID: IAW-2 1) Ibate: Id /2 5 102 Sampling Personnel: C.nl ,ei~ /70fpi/r .i.AAV4-.. d/Weather Conditions: 1.5 ..e C Time: a&File Name: J, /44/0.l, 5 Total Depth (I.D.): 4-2. j Screen Length: Depth to Water (D.T.W): (1) '/ Well Diameter: 3i Total Volume Purged: 5." .- Casing Type: Purge Rate: .DAIWIO,
- Sampling Device: /zr :/ -Tubing Type: 2W -Measuring Point: oF " .Pump Intake (ft below M.P.): .32 ' color: 9j,,jp odor: 464 <Time: DTW: Comments:
Temp SpC DO pH ORP Turb (min) (feet) (`c) (uS/m) /L std units mV NIU Stabalization (see note +/- +/- +/- +/- +/- +(-Criteria' below)' 3% 3% 10% 0.1 unit 10 mV 10%, 0:00 -2, ,L , ," 1.77 , i , 10:00 13141 215 I ./ ;.- !q.ý if I 6..1 ,/,.93 L b o .15:00 Jj 2--5 A4" 1 4,26 171 0. J-9 6-9 I.TT O.(a3 20:00 0311L 225" /,A" 14,q i -" .13 6ýS Z7 -¶,-1 i4-, 0,1'25:00 13,21 .235 ,-a i 8 (P{R O.9-1 ?,D(, M-, 9 .3c 30:00 13.t iiJ1 -2 35 Adn If" 145z Z _0,'r 0,~o~t 32 35:00 13.,i 2L 1444 ti.i'6 1?- 1 2-1 u. i -,.22.40:00 1. .qIS" ZzO AUo .6 egl 146 04 -a 6, 32 45:00 1-3.,01 ,2-5--_ i 4,5-(, 1 r< 91 .i.t 4im-s- ,3" 9 50:00 J3,AL" 2 ýV 4 j Z9 14fp 7 i~jy 6,'q ,L.55:00 13. Ii 1 9 i/k , 14.I I-R9 b-.<5 131-2 "-Q0 o'60:00 j,3?eJs- 25-o ,2- 2ts: q%-+/-. L..u o 65:00 I341 6- .14A,- 1418-. 1 S-2-a 7-? -4R. 2 -.7-Z 70:00 l.3.,4i ;26.r) ljýi t,161 0-7-9 2-,27I q2 N5 , 75:00 80:00 85:00 90:00 95:00 100:00 105:00 110:00 115:00 120:00 Sampling lime: Oq9/- /1i Samples Collected: Analysis Requested: Preservative: Holding Time: Lab:/<I-'4t "I A"t Notes: (1)- DO nasunre depth to bottom of telr "nti after pa-ngig and samping to redaese rtuspending Onet that may be restring ott the wenl botom (2) -Stabilln-oin criteria bated on three most recent coaenostive measurements. (3) -Total drawdown in well to be le-s thoa 0 1 m (0 32 fi). Purging rute to be lowered as -ncemary to keep dcrawdown below 0 I m (0.32 fl)(4) +/- 10m% when trbidity is oer 10 NT Site Name: .DJ Low-Hlow Groundwater Sampling Form Well ID:MW,.0.b. Date: 6,J4.: /a 7 Sampling flersct;Tel: 6c. Zsoi4 ,lA/,A A A-(. &6'O7sk Weather Conditions: ý7,K- AAq,ý Ala Zl-_5rfL" Time: /0:Z -5 4 File Name: D6Al~l lotal Depth (I.D.): .Screen Length: 70 Depth to Watei (D.T.W): 0) /3,73 Well Diameter: 3 "l Total Volume Purged: " Casing Type: ,/, Purge Rate: / 9 m' /X.//k.cý Sampling Device: V"'O.l,..C )Tubing Type: Measurin Point: 7)-1 9l PI/- , Pump Intake (ftbelUw M.P.): 70 ' color:`-/6j&e1dor: Time: DTW: Comments: Temp SpC DO pH ORP Turb (min) (feet) (°C) (uS/cm) (mg/L) std units mV NIU Slabalization (see note +/- +/- +1- +/- +/- +/-Custeria' below)' 3% 3% 10% 0.1 unit 10 mV 10%9 0:00 //._ q .,,0 7,3& /I5,; 4.7.lO:00 14,135 ) 7, 15:00 I'M, ,.,r -AY.OR iT d .,0-Y,., 5;2.-20:00 , 25:00 0.iZ O,' .7, '30:00 i ieeV 7 35:00 /osb A91f * -7,,9 ,/ ,, 40-00 BU MMAýV f-7 251f .50:00 __4/_ ,. 1_-_ 17- R 633 7__ 7,. , 55:00 Al 1 ~ ~ 1,~..L S 1 7,,// 2052 ,4 7,Y X;,/, I S .5-6i-4 60:00 Ad M 0.2016a/ U0 /q,7 r,79 65:00 1t-q5. S5 1,q 4-"Md AtA , A qb 7.-229 d , 7 -_fIl 70:00 /W.,%(17 ] /Z YS ,7, ,ýIx 75:00 1 Y, -547 D id-ZA1p7. /20 ,AM/l, D,J 3/7 80:oo -10 '2 qffA6 D/r. ,h/.. -! Z Z11 0il o,d5 7,60 52, 85:oo /p.S /M , t,10 M/ ,l"Id Od 6 1 L 90A00 / ,5 7z 7,../ ,/95:00 /11.I 41 -.7,Lq1 3, qff 105:00 qt t ~ J3 110:00 7, 120:00 /155 / j7, -3 ,Z -3 A3 Sampling lime: I 23O I-" Samples Collected: Analysis Requested: Preservative: Holding lime: Lab: Ma-a-r- I-~rI64 61,,&A U00 0 Notes, (1)- Do not meas.re depth to bottom of -el autil -fter pu gieg and esnpling to reduce reauspendotg tImes that may be resting on the well bottom (2). Stabltlltion criteria based on three most recent conseontive tnaeremnnts. (3) .Totot d-aodown in well to be nea than 01 o (0 32 ft) Pueging rate to be lowrered as ncesosr y to keep drewsdowo below 0.1 m (0.32 ft((4) ./- 10% wern torbidity a over 10 t"TUs Site Name: ._ _ t3 low-Flow Groundwater Sampling Form WeU ID 01 W 413v Sarn ling Prsonnel: Ci, Li,~.t~ nLr,,& A .Pe lVZ Weather Conditions. FhW-zt a Tinme- 03o- , Z File Name: . M~ao!Iotal Depth (1.D.): scre,. Depth to Water (D.T.W): [ .L Well Diametei: 3"i Total Volume Purg ed t , Casing Type: Ma PurgeRate: / ,_ .*U. Sampling Device: Tubing Type: Measuring Point: 9,,c OF .Pump Intake (ftber w M.P.):. color: C/lezZt- odor: Time: DTW: Comments: Temp SpC DO pH ORP Turb (Mrai) (feet) (°C) (uS/cm) (mg/L) std units mV NTU Stabalization (see note +1- +I- +I- +1- +I- +/-Criteria' below) 3% 3% 10% 0.1 unit 10 mV 10%, 5:00 /2,7.1
- ALI /___ A' 11..-57 7./Y afed .10:00 /,f v Qq,' 10/ 7 ~L_*7 15:0__!5-x_ -jgj 7, £5 ýL/ O,//15:00 i (I.& I 9_5,-S/¢rt 1/, 'IS /// 'ii07 3 1 .,) ; ,57 20:00 ,. l , 7,11 s 35:00 X.53 !,P /,Z ). 13.OO ,157 00 ,,)-, 0,l0 40:00 /d Z3 _77.3 1g1 45:00 1AV.7,3 i 1- -, 9/A o7 A2I7 /7 7.,7 1,3;50:00 52 q3 l ,i/ , 53/ ',.eb ,.6q " j3a, v57,3 60:00 1. 17-5 3-Y O.3' 7.hf ,.7/65:00 12-3 jA.4", 6W 0,;d a37 3 1 ¢,Oa 70:00 112q3 .! .5/,S1 .Aao 0,3 7.1,F ', I.80:00 1c2,,3 l'5 .Z/,L /5.13 .,L , 7,A / 4,6 Jl" 85:00 !; /75 -..i , aalk O.JI3 7."7 17 /J L7, 90:00 95:00 100:00 105:00 110:00 115:00 120:00 Sampling Tire: 09 q7-101"7 Samples Collected:
Analysis Requested: Preservative: Holding lime: Lab: 5bla4 I Notes!(1). DO not measure deptih to mom of sel unti} after parging and sampling to reduce resdSpenddg fines tist may be resting on the wele bottom 2)- Stabilization criteria based on three emos econsecutive measuerements. (31 deawdo ta eetotbe teuthan5 I nm)032 (t). Prgstgrate to b., uek-ede e as cen-ety to keep dea enbele 0o (0 32 It)(4) e/- i(n. when turbidity is ocee 10 Nfrus Site Name: 4Vt5 Low-Flow Groundwater Sampling Form WeallD- lL3- I'l. .b Date: A-1,41//0?7 SamplinePersonnel: (G.I, / W/'/,,LT A .4 t., Weather Conditions: 5"Sz Time: 10/03F 6/ __File Name.4M &P, Iotal Depth (I.D.): 4 & -Screen Legth 7,2 Depth to Water (D.T.W): (1 )7 -'70(dJ Well Diameter: .3"/Total Volume Purged: ,,_-, Casing Type: P v c.Purge Rate: j"'/ftYL,. Sampling Device: .ra AL62s TubinrType: Measuring Point: "/-7;lO 014' .Pump Intake (ft belovV M.P.): 7JO / color: k eI Jir) or: _-'r Time: DTW: Comments: Temp SpC DO I pH ORP Turb (mri) (feet) (M) (uS/c-m) (mg/L) std units mV NTU Stabali2ation (see note +/- +/- +1 +1- +/- +1-Criteria' 3% 3% 10% 0.1 unit 10 niv 10%, 0:00 Wq7. Ty .67"YT, , , 7 t.i 0 'O 367639ý 7. V-5 29. V 5:00 11,73 Z. W4. 8 3 +/-L 7;1' ,;f(.A _-77 40:00 110/j$ n.&5I 37u M41 64 50:00 4 L ~ ;~'73'~6;?2S _20,00 A79,3 1&0,, LP ../ V,- 32-1-1 -T1 P., fY 7,.5a- -.4 a-. -7q 25:00 /1, f 3b .,j 344/a./ , 7-,, -'ii.2 04.807 60:00 7.f,,, L1a,- , 0 3/ 1// ,, '5 --V9/ I 1.__35:00 i. .-7 1 3 66If G,.o z.0 .50- --A,-i71 --,71 40:00 7, ., j.S 'r , ýu / i6. i61 311a,5 G.iD -7.52 -Sv Q*.y,5", 5:on Time:oo .... ,/. / ,,13- ,_.55:o00 7 4; t 5,[5 r @ nZ t 11,95 11771 -.05 7 -5n '-53t.l i,0 '7 60:oo !.0g 1q.q 31S0101/ -;'IS I,5 -I£q1, 65: e Clctd d reer -at/ve: 7H55g T,m , 80:00 85:00 I 90:00 95:00 100:00 105:00 110:00 115:00,.120:00 Samping z Time: l "/3 Sam,!e~s Collected: Analysis Requested: Preservative: Holding Time: Lab: P-Wo -m -. 1>-(,)e, r5 01[ -mcLt,- ,_,Tý9,ntyg: Notea,-Doool -eure depth to bWft of -M -111 .-loaer purging and s-,mplig to reduce -pending F- that -y be resting -£ the .-9l bottom (a) -Stabilition critcria based on three -t reet -eoe.ofive eeas£ remnts.(3) -Toute drdown d 6 well to be bWm than 01 m (0 32 ftS Purging rate to be lowered as neces-ry to keep drawdown below D] l (0.32 f3 )(4) ./- 10% whe. turbidity in o.er 10 NTDk ii Site Name: Da L ow-flow Groundwater Sampling Form Well TID f/kiey -ýt 1.S Date: 7 Sampling Personnel' ý 1? ) vi,-V L.Weather Conditions: Time: /4r File Name: DA,610 J" , lotal Deth (I.D.). Screen Length: ,~Depth to Water (D.T.W): mt) -C Q3' Well Diameter: 02 Total Volume Purged: -A,!,i5-t~e CainTa: Tubing Type: Measuring Point: -7",, O (2 / --Pump Intake (ft beloi 7M.P.): .- ' -color: &4,j4- odor: A?-4-Time: DTW: Comments: Temp SpC DO pH ORP Turb (main) (feet) 0 C) (uS/cm) (mg/L) std units mV NTU Stabalization (see note 41- +/_ +1- +1- +1- +/-Criteria 0 below)' 3% 3% 10% 0.1 unit 10 mV 10%, 0:00 jf,4 2/O,-/?/6 /-AH? 9 3 Q.I./Q,77 ,-7 Z 7,i.T 406 10:00 ! ..6L 1,,5 _7,_,_ 44 7,_ _7,. .?Q 12.7" 15:00 141,.'3' 4,9,2 .__ / 7,, .7,/.Z.l -(,,,,q 1, 20:00 Z7f .-, ..40:00 ]'T a~l &. i7.' //O z.45:00 35:0, jf .Aý"," /5 6, 1, 1t/44 d,,?, 60:00 IAAS 249 elfii j 7,5fO ~.c2 MA -96f A /079 A-~45:00 Ud.' 5 i '051 .217b 7,," bc, -44 , 70:00 .41'232i~7~ jl 55:00 j&." 9;; q 7:,r: 0, &, 60:00oA- .. /?-".',Lg 12+- :7.604 __31H q q 65:00 7 70:00 d 7A4,q 75:00 7-80:00 0 V 805:00 910:00 115:00-120:00 stmpling Time: aql/O .../ V Samples Collected: Analysis Requested: Preservative: Holding Time: Lab: ,na) -)A&(1) -Do no measure depth to bottom of well ot! aflter pwriog and sampling to educ resuspending finea that may be resting on Oe well bottom (2)- a~b flatioo criteria based -three mt re-ent I tire mea .,met (3) -otaldrawdow in well less thanS I m (0 32 ft). P-rging rate to be lowered as ece-sary to keep drawdown lbelw 1 m (0.32 It).(4) 1/- 10% when turbidity t over 10 NTUs 0ýSite Name: _)/5 1 ow-Flow Groundwater Sampling Form Well ID: /)"Iz ._Date: Sampling Pers nnel: C>Lep AZp~~- 4L -d KOIe4 Weather Conditions: 3 5 , Time: I3/ -File Name: .'l Y,, lotal Depth (I.D.): Screen th: Legh Depth to Water (D.T.'At):() /43/. Well Diametez: Total Volume Purged: ,*,.-,40 Casing Type: P YC Purge Rate: , Sampling Device: ,L,ý .&&4 Tubing Type: Measuring Point: .LO Pump Intake (ft belo IvLMP.): W ,_:& " color:/ #_ odor: O Time: DTW: Comments: Temp SpC DO pH ORP Turb (min) (feet) (qc) (uS/cm) (mrg/L) std units mV NIU Stabalization (see note +/- +I- +/- +1- +/- +1-Criteria 0 below)' 3% 3% 10% 0.1 unit 10 mV 10%, 0:00 1.110 1U1 GM41 670 a?, o5 7.' Wb 4 >9 10:00 f~ A;U a? Zfd Q -0 7 72f 9'15:00 "//7 /0 U? I,4v -..37/ ,.3 -Z77 .20:00 j j t~ ,-25:00 7,y 30:00 Fig MPl /fO y 6-,37 35:00 /6 oI&"L-23 -- 7 40:00 {.J4 .'..#j., 5 i7, .e%/ .45:00 Jq47j 0 ~ I 50:00 -7 55:00 i-27 ,, ./ 7-3 60:00 Iq,j7 IA96 6_a Y ,3/ -1.65:00 1q,17 --7 o,,23 7,5. -97,7 ,7.70:00 1/,7 " , 1 -0 M , --A.? 09,aA1 75:00 1- R/ , 5 ole d , 1 80:00 77 5 9 7 85-00 4 5ý90:00 95:00 100:00 105:00 110:00 115:00 120:00 Samplingflime: Ijz/ -- )qs6 Samples Collected: Analysis Requested: Preservative: Holding Time: Lab: W3. 60 !E Notes: (I) -Do not meos- depth c bottot of o wen tol after p-rgieg and samplin g to reduce re- ppenditg ftoa thaot ay be rfessg on the well bottom (2)- Stabilization criteria based en three aost recent cottcetive measuremecnt (3) ToWl d-re, wdown in -e1 to be less thor0 1 er (0.02 ft) Prging rate to be lowered as nccessory to keep drawdown hlows 01 m (032 ft).t4) +/- 10% when torbidiryis cem- 10 MTtl. Site Name: D15 Low-Flow Groundwater Sampling Form WeIlID: rnw ,,k Date: (__I a- 1CI do7 Sampline Personnýl:C'. I tJ MYt-ryir4-k#4t M Weather Conditions: "7 -"i`'CGZ Time: .. ...File Name: "D~T- b rotal Depth (I.D.): ,,./ ScreenLength: Y7 Depth to Water (D.T.W): (1) I ' Well Diameter: .-3 Total Volume Purged: 3 , Casing Type: PVQ4, Purge Rate: e- -t Sampling Device:. .Tubing Type: -Measuring Point: -i.oy O(F Pif C-C Pump Intake (ft belown.P.); color: 4' It. odor: 4 Time: DTW: Comments: Temp SpC DO pH ORP Turb (min) (feet) (c) (uS/cm) (mg/L) std units mV NTU Stabalization (see note +/_ +/- +/- +/- +/- +/-Criteriax beiow)' 3% 3% 10% 0.1 unit 10 mV 10%°5:00 LI aOU _ .7L -ACZ -,17 42..85 -','3" 10:00 'a t 1s0 r"i T j E .JL.-U, i 'I,= o,'7c &,97 -3qI,& 1.-43 15:00 InJI , O.0l i3C&I Q,5"4 &E .20-00 ,I alA a.15 ,', .o.'1 ,CL o.qa Ora i.50.25:00 15,_ aQM h t -s m ~Q0,Io7 iall 0m,3e eif -361.3 0:7 30:00 _i___ .V.?0 fIi UA, .ja A 6,+b31W 5 bOi 6,qif 0.q7 40,_35:00 i J5 .4 3L0. IS.1, j 3 t, 0 j o.,fY 40:00 11C5 .3o5 P 7 &19,1 ,3'5. 1 nA 5 450:00 1~I V. L41 IiJ 55:00 a-k3 c30I &~%er i~ 35 Qi3S &.1 C ~-2078 _,5 60:00 -65:00 70:00 75:00 80:00 85:00 90:00 95:00 100:00 105:00 110:00 115:00 120:00 Sampling lime: Oi30 5-c)Samples Collected: Analysis Requested: Preservative: Holding Time: Lab: j ý j q,-p -py, Notes: (P)- Do not -oeasre depth to boltom of well ntil ther stp ieg nto rrsedue stsnding f-e that -sy be rnthing an the well bottom (2) -Stabilinlion criteria based on three most recent coosecutive measu-r ns.(3)- Tot.l drasdown in _el to be loss thon 0D1 o (0.32 ft) Purgog ral to bs towered .s neessory to keep dfaowlow, below 0t1 sm (032 It), (4) ÷/- 10% when furbtdity is over 10 NTUs. Site Name. _ A __ _-_tow-f-low Groundwater Sampling Form Well ID: 21 -_ Q ..Date: L_.;I. __-71, -7 Sampling Personnel: .z/Q Weather Conditions: ,_/- !i//YL, "L_.VCtIt. Time: l/" File Namer:/~Q~ Total Depth (T.D.): ,/.'Screen Length: _3Z Depth to Water (D.T.W):*1 j)34,) Well Diametei: .Total Volume Purged: -1t, I ." Casing Type: AMA Purge Rate: , , ,.. Sampling Device: A- " Tubing Type: Measuring Point: -/oil 6'/'Pump Intake (ft below M.P.): coIor: odor: Time: DTW: Comments: Temp SpC DO pH ORP Turb (min) (feet) M_) (uS/cm) (mg/L) std units mV NJIU Stabalization (see note +/- +/- +/_ +/- +/_ +I-CriteriaZ below)' 3% 3% 10% 0.1 unit 10 mV 10%5:00 ,2Qa',X -"Q5 .263 ,5 7. / 7.2,7 0:00 __ _2_;_2_/P 7 16 10:00 J?91 /15:00 1364.5 &O laIA4i -"qY 7,17 ,,- 7.0-r 20:00 jJ./l -.Z, r j, '7,/7 1 .,. V '6 25:00 /. /2/ .- 4, off 30:00 7./& 4 3d 35:00 40:00 lgý;77 /. 1 40:00 3 M6/ 7(850.45:00 tia 1 1160 7 has 5000 .3.L5.. O,&u/Y- 1, i 11- 07/ '~ Pi) .~ , 55:00 j3U- ~ atiS 7L 710 (%, KL 60:00 65:00 70:.00 ____75:400 ____80:00 85:00 90:00 95:00 ____ __________ ___ _ __100:00 _____ ___________ 105:00 110:00 115:00 _____120:00 ________________ Sampling lime: iND -Samples Collected: Analysis Requested: Preservative: Holding lime: Lab: Notes: (1) -Do notomeasure depth to bottom ot welt until after purging sod satrpling to redoet re-supeodiog frees that oay be restng so de wu[e (2) -Stabilzatfon citerna based -n th0-e most re-ent consecudve rneasoroeeo. (3). Toldra'daowt i, wetl to be loss than Ito (,33 it). t'oagiog rate she tonlred nonecesoary to keep dlrowdoosbelow 0.1 tm (0.32 ft)(4),-/- turbldity is -1o0er Ts. Site Name: ..D,8 Low-Flow Groundwater Sampling Form WeIIID: _______"_-3_ ___Date: 7 Sampling ersonnel: , , ., Weather Conditions: 4 A ., -c Time: File Name: Total Depth (l.D.): 0 ScreenLength: 740 Depth to Water (D.T.W: & 3,9 L7 Well Diametei: " Total Volume Purged: #/V4. tQ-V Casing Type: -Purge Rate: Sampling Device: Tubing Type: Measuring Point. 740 AO/'L'" Fun.p Intake (ft below M.P.): '7 color: £Cý odor: 0 Time: DTW: Comments: Temp SpC DO pH ORP Turb (mim) (feet) C) (uS/rcm) (mg/L) std units mV N'TU Stabalization (see note +/_ +I- +/- +/_ +/_ -t/-Critenia' below)' 3% 3% 10% 0.1 unit 10 mV 10%, 0:00 / /6 -o 1 i .t5 h 7 5:00 PI &lX 547,2 7,.. 0o -3W.2 15:00 ,Iq 7, H,5L _7 oY .-- 0-91Y 20:00 "1[0J 4QSV/ 0,4 0 0 , 25:00 g 2L, / ,_O ,2 ZOO V -34 e 0_ 70-20:00 At, OSO 7- U 35000 J[/j, ti iQg O I¢,q..33/A[ O, YLLS 45:00 BI-L ..-T. .7, , 4 0 : 0 0 Y / -,q " ,. -, 50:00 __ __ __ ___ jPýt 55:00 tLL&o Iq _g.6,7 tI, _y"I ..U/ 037 L 60:00 Ik. U0 7AIX TV e. K, 7 65:00 70:00 75:00 80:00 85:00 90:00 95:00 100:00 105:00 110:00 115:00 120:00 Sampling lime: 13'7...- ,9W Samples Collected: Analysis Requested: Preservative: Holding lime: Lab:--rPvau, Gonq J 0g ie Notes: (1)- Do not teas-re depth to bottom of well unitl a re pargingd saopling to redoce tesupending fares mat eay be reeting n the wnll bottom (2) -Sltebiautiot ceteria based an three moss recent consecutive measoremet. (3) Total drawd-wt in well to be les btehan1 m (0.32 Ar) Purging rate tube Int as necary t keep drewdorn betow 0. or (032/i).(4) ./- 10% -nnen ýItrbidity is -,e 10 NTUu. Site Name: Low-Flow Gromudwate-r Sampliig Form WeI1 W.".3 1"2D ,_-Date: -SamplingPersonnel Q:Movr AS A~ -(WeatherConditions: V ,. 9l. 1_ ,__L Time: DWCmet ep SC D H OT Tr File ' Sotab Depth (I.D.): n ; W Screen Length: -+.I Depth to Water (D.T.W) Well Diamete%: "i%Purge Rate: A-c " Sampling-Device: fe UA a.6D Irubin...T)2e: eo, 1Ph, e,. Measuring Point: -I-V: P c_Pump Intake (ft below M.P.)- ,1 3.1, color:_, .1--Time: DTW: Coixmaents: Temp SpC DOI pH IORP T-rb (mt) (fet)@C) (u/-)i (m-g/L) [std unitsl mV INrU Stabalization (seetnote +I- " +1- ft/- +- +- +-Criteria below)' 3% 3% 3% .. i 1 5:00 119'/ ' q / / -,; '.14--12a -a / W Y 1-7.a '7 4 -;r?. 0 10 .'_7 _10:00 / ../ a a.oý 7 3. a v 7.a--7 .6 0.q7 15___o .31 /* -5'.4 -{2b, --,, 75:00 4___ 1________ ft.- , , " , 7 -, W-601?9YI 3Y71-,W7-. 9,, 4 1 /7 20:00 1?361 1_0'__ i1-7..,7 e, i 4.<"- ,_,_ I_,__85:00 1Y. 45 QK 90:00 1 .6._k_09___________9_1_(;_,_1 95:00 _fc_ 19.661 -1 45:00 W I 1 2811S2 -ý7 --.100:00 kwi in 605:00 1__ _ _ _110:00 115:00 120:00 Samplig Time: / / 3sS" Samples Collected: Analysis Requested: Preservative: H-oldinge lime: Lab: (vM\) -e Pia), ,I/A Fit%- WT ýTl 4A tr, a-ncý L Notes;~(t> Do -ot -a.s- deopth ccbortnn of -11l otit after p ingio cnd -Tim.-n to roduon :cottensi-o dross that aye he reLn. on Lhoedwl botion, ()-S~bfitm tios -ite, based on thre momst tennt consecutive toes-otenrnts. (3; -lot,? dr-,d- in ic tonbe lobs sothan Odorm (0-32th) Poegiograte h to ber1n..d a ssr--ay to np &naodo rm treto, 0t Sn (0 32 h)(4) 1f- 10l c .hen -obid it i, eve, 10 m-t~s SiteName: D avllS bS-low-Flow Groundwater Sampling Form Wel .ID ..Date: Sampling Personnel: 1, c AAY-o, -o F , ? IOA .Weather Conditions: T im e : " ! ý ,f,-, -' / 4 4 ,File Name. ý J2.Iotal Depth (I.D.): 1., I .. Scrleen l "g K Depth to Water (D.T.W): t "4, l o Well Diameter: 3 Total Volume Purged: r' (0 Casing Type: t v C Purge Rate: 18 0 A .I h , Sampling Device: P\-V c. OOr., 0-c>Tubing Type: -.qo Measuring Point: -rT -c p.Pump Intake (ft belov M.P.ý: -1 / color:(Je. , odor: &L-- r- ,-n. 0 Time: DTW: Comments: Telnp SpC DO pH ORP Turb (man) (feet) _ (C) (uS/cm) (mg/L) 9td units mV NIU Stabalizatlon (see note +/- 0 +/- +/- +/- +/- +1-Criteria' below)' 3%fC 3% 10% 0.1 unit 10 mv 0:00 14/10 It-e~ :3 90"13; 5'1 -1 , ,) cl4 5:00 " 2 °&,0A 1 Cm .', & -k 2. -7. 1 G'2.t ,"A 10:00 14, 31 I I.Ii 1-2,69 .,'cý% it b+ -1,Ih -111 Al, ,.Z 25:00 14. 3 et t .,g"I,, 2Q -56A 12-4,,6'30:00 t4,, i£ wl A A J 3 _ LS k C." ..Q S3, 55:00 3S 'i 60:00 4_11AA4 65:00 7-0, 2-4 __&I&____1q 70:00 ____________._52 75:00 1-r34 o.2 :;,r+- -_3a__4 80:00 n, 85:00 90:00 95:00 100:00 105:00 110:00 115:00 120:00 Sampling lime: /s-3 .-. /10 7 Samples Collected: Analysis Requested: ,Tý,, + 4 j AA Preservative: Holding lime: Lab: 10 'f f, ! ,jC.k .4 f~ ~ s~ ~Notes: (1) -Do not -easur depih thboft of 'ell unitil rft purging -d -pliag to redc re pending fi-eotht iony bt resiag orn the well bottom, (2) -Sabi~i L~ioan criteria baed on three moost 0ecml0 ctst c onhve lfl-~re-nto (3)- Total drardo'n in wt Tclbeblekst thn 0 1 mt (0 32 fiL. Pt-giC, rate be aoweed aa. --ye.esy toke-p drtdon bMo., 01 n (0 32 1t)(4) +/- TOY. when trbidiry is o.-r 10 NrTU Site Name: -T Low-Flow Groundwater Sampling Form WellID: M~ Vp -_Z .S Date: a-- Oi--Sampling Personnel: JZ. (Mi~ Ac ,A IWT (iA A Weather Con tiction: -I. ..Jt L. 4 -4c Time: Oa, 71417-File Name: fL 2 g o lS Total Depth (f.D.):. q 2 z..' ZZ Screen Length: Depth to Water (D.T.WM: I Well Diameter: 2" Total Volume Purged: 3 j -Casing Type: ?IPC Purge Rate: 20R ,A-w Sampling Device: Tubing Type: , ld.t Measuring Point pfb q p ' _Pump Intake (ftWbelod M.P.4 f ' color: cAe- odor: 1 -, , Time: DTW: Comments: Temp SpC DO pH ORP Turb (min) (feet) (°C) (uS/cm) (mg/L) std units mV NTU Stabalization (see naote +/ +/_ +I/_ +/- +/-Cniteria2 below)' 3% 3% 10% 0.1 unit 10 mv 10%, 0:00 q,7..q2. i.49! 25-3 U9-3,1 95"-5 5:00 1.44 ZQ ]vX..r.,U"1 R-_1 I a?3E 10:00 --4'_J 194,4 2X26 15:00 1 1 !?,. --:J- Z2 O._I 20:00 ejJ- h4 il-LCs>t4. Z oo.z.25:00 I Z1O M Irvan I Zvn /_ 51X I 1 30:00 JqJA 2- eWJ/h vI 9 1 1_:21 s 35:00 , 1 -h-34 40:00 45:00 50:00 55:00 60:00 65:00 70:00 75:00 80:00 85:00 .......90:00 ...95:00 ____ ___ ___ _ __100:00 ____ ___ ___ ___105:00 _____ ___________ ____ _______110:00 _________________ ___115:00 _____ _______________ ___120:00 _____ _______________ SampLing lime: / -Samples Collected: Analysis Requested: Preservative: Holding Time: Lab: avWD31 1oA A-~ ft;ýr=t j-.',-4~Notes: l) -Do not memrc depdWs bottom of well phaterl to pouging-sd-~pling I. .edoce ,eoopodicg Fo- tlwmaocy to reciog- One -11ro' bottomo (2). isboto erjtsria bsoed on, Iloe, most rocent -.6-soiv osaooe- efltt (3).-To'. doocodocoin welt 1.lon loes tlooo 0 sm(0,32 ft) Poogio51sst to be lo,,eeso " --ceOto3keep diaw'- sbelow 0 1n 05.32 ft (4) +/- 10% otheo trobidloy 1, -c )0 oTMt., Site Name: IsA ý 9?&-2 L ow-Flow Groundwater Sampling Form Well]]: MB-U "-Date: ' B t.1%Sampling Personnel: l < MZ, _0 SZ'O A Weather Conditions: Fa; -, Lý-I S.)0 -M g¢Time: 1 4&ýAt ;he.-7 0 ?3,0 File Name: L% 30 D otal Depth (I.D.): ..Screen Length: Depth to Water (D.T.W): iA. Well Diameter: Total Volume Purged: ? r5 a -Casing Type: t'a.c.PurgeRate: 2.OOA !i s, Sampling Device: (r-s-V1I1 C. PJo-TubingType: eA!a , Ai 1 MeasuringPoint: -ton -C, eq- ' -Pomp Intake (ft below M.P.): "701 color: LT G;Aq odor' e. , o -Time: DTW: Comments: Temp SpC DO pH ORP Turb (mill) (feet) (MC) (uS/cm) (mon/L) std units mV NIU Stabalization (see note +1- 0 +/- +[- +/- +/- +/-COiteria 2 below)' 3% 10% 0.1 unit 10 mV 10%, 5:00 ie4-. Z..-wi , "t Yi. ,A. ff.-*.2. t 10:00 Al 25:00 4.. ".. 2 -41,9,4 1. 70 55:00 ________________ 60:00 65:00 70:00 j -f I0.75:00 f___80:00 85:00 90:00 95:00 100:00 105:00 110:00 115:00 120:00 SampLing lime: .)a 7,/ -Samples Collected: LA -`-- 3. .h Analysis Requested: Preservative: Holding Time: Lab: (-10 Ae- rt3A E ýC(,oA#r,-e lZAC,, F-Notes: () -Do notmeassr depth io bottomr of wct until fWer purging and rnmpUiegt.oedeen renn- pendtng tines that neoybbenotinegn & e-wettbottonm, (2) -Stabifiation criterin bosed on thrce moot recent coOseotive me-nremectt. 0)- Tot] in -e11 to be lens thn 0 1 o (0.32 It) Pungi.g rate to 1- -oweed --ynce, to keep dr.ndo.- bneo 0 1 o (0 32 ft)t4) -o" 10. hen I.trbidity i" one, 10 M.S j 0 Site Name:. iOL4 /3eSVg.*Low-Flow Groundwater Sampling Form lWell IH>- MY i Date: 713/ /07 sawtvlina Pers'onniel: C, -Lza)no6 VV, E"I/1440-0flt0SCA' , yl-'c L'/-CIV M in57 Weather Conditions: RD0" .- < .-An-Time: Y/D.'< -File Name: ) l3 , -'Iotal Depth (ID.): V L73. Screen Length: :3.-;L Depth to Water (D.T.W): 0) ,2q / Well Diamete: 3" Total Volume Purged: Casingr T pe 'V'--Purge Rate: iqe 0 1*e Sampling Device: Perd-51z~k-, a Tubing Type: U&Measuring Point 1V/,D P f'o !V(Z.(ft below M..): 3 , ,color:/4. " odor: 2 Time: DTW: Comments: Temp SpC DO pH ORP Turb (rain) (feet) (C) (uS/cm) (mg/L) std unitr mV NTIU Stabalization (see note -i-I +1- +/- +I- +1- +1-Criteria' below)t 3%(C[ 3% 10% 0.1 unit 10 mV 10%, 0:00 b mn 04 a3-3 ____ aq.:?e -7106. .Zq" 25:00 43, Y3 ,/,3 -qS03 0 ,9 -7,Jq -//gI 6,S 30:00 1/ 1/3 /__- _C._/ -Q 0,60 -,13 -15,, R,0 15:00 1 ./0 9/- , ?3 ,/ .-1 4-0!;2il / T, 20:00 ,.-, 6,411 25"00 1q, q q,, !2 f ,gN I3,3 0J Z -/W% ,," 3o:oo _I 4. 12 ,1AL,,, ,G--3 aZzO5-" /." -.I- q~ /. q3 35:oo00q /NV ,7.e///]ak -3 4,1¢0 AM , 7ol 60:00 it). 1;___ -0 65:00 //0 A A 0 70:00 40_/A&75:00 80:00 85:00 90:00 95:00 100:00 105:00 110:00 115:00 120:00 Sampleng Time: Lab: Samples Collected: Analysis Requested: Preservative: Hojldin~glie Lab: 0 Notes: (1)-Do not measore depth to bottost of wel tnIj alsor porging and ..attplosg to s~te d a-spendiag fsest tht ay h -sog tbewl1 boltom (2)- Stabiljoaiomtsn ont asd os th0re most recent morsscotits mcot.ermonts. 3)- Total dsasodoots trwll tohe loss thon m.1032 Is) Posurga rate to be lossed us--T)sso to keep drtdot below 0 1 m ( 5 32 ft)(4) +/.- lo.when sorbidiy is os-eI 10 NTL Site Namer Da.IIF) -t al-.L ow-rlow Groundwater SampfingFornz
- Trk. 21l I)Date: 7 13(10-7 fC7 , L Samp!ITn Personnel:
Cr; r 6tr Par Weather Conditions: S ct. r ,,,, -t, .! _.. ...iTime: f -File Name: 0 E _ 1 .0 .. .Iota] Depth(T.D): F Screen Length: 71 Depth to Water (D.T.W): ( 10/ Well Diametei: 2 Total Volume Purged: :;3 Casing Type:__Purge Rate: /&. 0,/, /," Sampling Device: .e3/] "'Tubing Type: P)I VL//Rs4e Measuring Point 'Tc, j .c i a-a-P 1 , Pump intake (ft Jelow M.P.): c -0, color: IVa.,- odor:' V'j,; -g Time: DTW: Comments: Temp SpC DO p14 ORP Turb (Min) (feet) (5 C) (uS/cm) (mg/L) std units mV NTU Stabalization (see note +/- 0 +/- +/- +/- +1- +/-Criteria' belowP 3%(r 3% 10% 0.1 utit 10 mV 10%, 15:00 -2. -t4.a! ,. , 72L 4 -3.-1} 7.1 7 25:00 17,73 /-.. , , .' 0.73 7.a-. ,1S, O 30:00 0Z' .k .67t 3. 9 q ,,0, LiL,.-' "-501'1 7 -St.35:00 1,,2 -1 JJ I z-O ý 7itA -4, 1.6 50:00 ___,__ A3._ I& _7../ -1%_,3 __'_40:00 '~~,5 . 1)/t Z3V .z.Ai', /2 A-- U3.?7 r,2.O 0.73 77,0 d-.4 , 55:00 17, 73 __ A _._ Q, 60:00 A.3.3o___ 061, 65:00 M___ V- 3 2/2 70:00 _____-_75:00 23.111 ___0W 4 80:00 ]#1 b2 105, 85:00 90:00 95:00 100:00 105:00 110:00 115:00 120:00 Sampling rime: i~a5 .-Y/Jq'Samples Collected: Analysis Requested: .Preservative: Holding; Time: Lab:_Notes (1)f- Pm not tmeasure depth to bottom of wct I utttf otter purg ng sod .namptittg to red oce rennnspending bites that nu' bc restingntr, the woel! bottom (2)f Stabilization stiteejo based on tftree roost tonncctstice meassotemen~ts. (3) -Totl drawdo.. in -11 t sbe Icm then 0. n, f0.3I- ft). Prgng r~tt to be too-red snes osty to keep d,-downn bosow t. 1 m (032 (tf (4) +/- ft .when turbidifo, i oer -O Ntrus 0* Site Name: D -J Low-Flow Form Well ID;: M U 3Q Date: 7 I Sampling Personel. C-1 't1 4 i -~ .Weather Condlitions: f p'!j Time:* " 1'2 (,e 1 -File Name: P 232S Total Depth (I.D.): s3 "creenoet-t " Depth to Watei (D.T.W): (1) /4/ / Well Diameter: .'Total Volume Purged: e ..Casing Type: C-,-'PurgeRate: Sampling Device: 1_-,,& x'-, Tubing Type: POi p-.a._J Measurin Point: -.Pump Intake (ftbelow M.P.): ! 2' ' color: -- /j odor: Time: DTW: Comments: Temp SpC DO pH ORP Turb (main) (feet) ('C) (uS/cm) (mg/L) std units mV NIU Stabolization (see note +1- o +1- +1- +I- +1- ÷/-Criteria below) 3- 3% 10% 0.1 unit 10 mV 10%, 0:00 Z "-. ,r?.r. .9 3 .."t A -. Q 1 7. aq -70 'q! ,. q 5:00 l42-j, z .2 IV *t f ,WA. 2.-19 2507, 16 .4-4 1-&&M. f. 12 10:00 Z, .Z7' 2i ,RALf,ýA -21,7 2SIO z 18 1t.2 1 7z_ -72o1o 1.'1 25:00 tf, '.e 22. z2Lj' I ...i .-o o 30:00 2 (A J,-/ 24 y In, ." 35:00 1 I A 2q ')I- 7,2 -q I::-30:00 aOR -,k,(q -7 2, 45:00 50:00 1 200 1 19 71 7 2z47( -¶a. 0 55:00 ____ ________ __60:00 ____2- 8_7- -- --I 0,12 65:00 70:00 75:00 80:00 85:00 110:00 115:00 120:00 Sa~mpling Time: IS /d 0.- /5'9,DL~Afj6t~Samples Collected: Analysis Requested: Preservative: Holding Time: Lab: aqw- 3-ý-To- I Tl cu}t bep-o t -rp IT I ill Notes: (1) -,Dorset oeass~e deptlh to bo:tor af well util terrporgingssd samplng o redoce resussprnding thai nay tre restmg o, th, werif bottoe.(2) .. Stahitira tiot eriteri, based on three moto receta consecotihe 3- Total drewdordsn i- 1el to he leos than 0.1 m t0 32 ft) Ptgting rawe to be lowered ms -reresary to koep drewd ovo bM-ars 0.1 m (0.32 ft)(4) .!" 10'X t-rbidi3y iseer _ 0 NTtLIk 0 Site Name: U-7f N --L ow-Flow Groundwater Sampling Form WellD: M \AJ--'AA D Samp Ling Personnel: St ,vzdc. YZVr OC , ,RSW E Weather Conditions: 7&' F', :,i f'ryf)Time: I -t4 --l;File Name: 0(3,3 3a. ...Can~er Total Depth (I.D.): g Screen Length: Depth to Water (D.T.W) m Well Diameter: Total Volume Purged: X. Casing Type: FN C.Purge Rate: I 2C- ..../ 'D , Sampling Device: r.;f,,i4 tI jL..fM Tubing Type: P-/ Measuring Point * +6 f iz I -Pump Intake (ff belofw M.PK): '7 t' color:a4e"r odor: jff.'r s&,,z, Time: DTW: Comments: Temp SpC DO pH FORP Turb (ain) (feet)() (uS/cm) (mg/L) std units mV NTU Stabalization (see note +/- +1- +/- +/_ +-" +1" Criteria' below)' 3%la- 3% 10% 0.1 unit 10 mV 10%4 10:00 11-.-4If 132 AriiL/n, 2-OZ3 I(,.4O J2 Ii2 336a2,-oO 5:00 5. 3' 7-i&4 Zio4 Itq"$fta Lo.4..f) -a#AL-4 n 21)10:00 f2..,-, 2,12,_ -nrQ 21-0 43Ub _!5. 1 -_iAf. 0 0.21.15:00 1.1-3 2-Co r,'.g, ..j A .. t-2.1 i0 jG2.C -ZL ,,1 t 250:00 15-V Z2 y L /L 2o.63 160110 l y..g (; -339,0 Z 30:00 / "eb4Ie..L~ 4.~L2.L .,f A 35:00 j 5 ~ Jw L~L eA9~40:00 35:00 5.5' &-.9979 55:00 22 zr4WA2 ..li~e f5I.20. &,_ 4 -9_3___QJ 45:00 600:00 5 4'A I lo(Ie .V t05:00 8I0:00 115:00"'120:00 Sampling Time: /7-'/-/Samples Collected: Analysis Requested: _Preservative: Holding time: Lab:.,- I t itl, Ik 6'I. t1n WM W/A 464dw~2sf Eý I Notes: (1) -Do not --easoe depth Io bottoo of dell coil Itie, purging ..d sampliog to ed-ce -eecpon gtne flos thaty tbe cottog oo the -11f botsom (2). Stbiliear-.t criteria based on three mee recet cenetiee .-en areo-enLs. (3) -Totl dtandowe it well to be 1er than 0 t (032 It) Pargtno rate to be tierted a. -e-etry to keep d,.aordonn below 01 or (0 32 fly (4) /.* 10% whet, 0 lutbdity Ls over 10 Nrr'Us. 0 Site Name:- Grnwae aplin j-gFor L ow-Flow Groundwater Sampling Form Wel ID: LO -.k , S Date: 02 sampling Personnel: t, (Ca. A-ct ~Weather Conditions: S LIP. rlV S6 I) 4y Time: * , '44,,---" File Name: '3 Total Depth (.D.): " 2.. S'Length: 3b Depth to Water (D.T.W): ) .Well Diameter:ype Total Volurne Purged: .0 r Casing T ye: PurgeRate: f'1 2, /j ,. Sampling Devi e: alA.,a MAJ t4n .Tubing Type: tXy ed/IA ... Measuring Point: Iip j a j2 104a-PumpIntake(ftbeloGvM.P4.: ,'.V color:n4,.A', odor: " Time: DTW: Comments: Temp SpC DO pH ORP Turb (rin) (feet) M(C) (uS/cm) (mg/L) std units mV NrU Stabalization (see note +/- 0 +/_ +/- +1- +/- +/-Criteria' below)' 3%IC. 3% 10% 0.1 unit 10 mV 10%, 0:00 /37,7, 9
- 4-, --6 7 -A/1` a 7,Q 45
- 00 /,-7
& '- ls/1.: f 2l l7e 10,,A.A... 10:00 17 .4 3,-0. I 1 "7.IC- A7. 3 1/a3 15:00 .2 " M#20:00 3 QJGOU Lut 3 4 25:00 W32 5ca1a P-1615. 09 30:00 105:00 '140:00 -95 Q jj vF 7 -_45:00 2__50:00 1 1-7-- 7. t 55:00 13-7 Ln A .J 1vV ~ ~ 3. .51' -~7,17_60:00 2S.L4 jW 1Ii165 -?-, I__t 65:00 ]i_7 ;;u___ ~-t 5 i +/-A -L~ -5, 70.00 S1 Z 2_5 L jp -4, :! -OeI,5 -1 80:00 _1.3-33 11--Mý1,AW 2S,531 2_5S- 0~~ 1 71 85:00__________ __90:00__________ __95:00 ___ ___________ ___ ___100:00 _____ ___________ 105:00 _____ ___________ ___110:00 _____ ___________ 115:00 ______ __________ __120:00 _____ __________ ____ ______ __Sampling Time: /'A7-/o-Samples Collected: Analysis Requested: Preservative: Holdini lime: Lab: r6fhnT tA--', ý-l r ~g --,&PUMIrAL LA7 C.I;ýNotes;(-)- Do snt ecas-ee depth to bors, of well until aicr purgin and sampling to reduce r- spe tding fines thatI may hS rsinag on the well bo]tus.(2)- Stabiliuahion based on 1ree mast recoat messurements. W-. oral d-aedowan in well to be les than 0 1 m (0.32 It) Puging .ae to ae lo.wered neeemars' to keep drswd0- trelo',0 1 .(032 11)44) I/- 10'hs-hes Iorbidity is o- 10 NrfltT s 0 Site Name: )ANIS, TSSf I ow-Flow Groundwater Sampling Form Sampling Personnel: F-.McL -'~5 ___Weather Conditions: File Name: 3) b M LQ 3 -T otal Depth (I.D.,: U .0 een n igth:_7L1 Depth to Water (D.T.W): (3) lie* jaI Well Diameter: ý, Total Volume Purged: 5. 0 Casing Tye: P -, Purge Rate: t b 5 Sampling Device: -.., Tubing Type: 0o t //I/e1 ae. ., Measuring Point t i. Jj,'V" pýAj Pump intake (ft elow'M.P.): -color: c,* tv odor: L L.F, r: t\I Time: DTW: Comments: Temp SpC DO pH ORP Turb (mim) (feet) (0 c) (uS/cm) (mg/L) std units mV NIU Stabalization (see note + +1 +1- +I.. +l-Criteria' below)' 3%lI& 3% 10% 0.1 unit i1 MV 10%0:00 ,1.4 , -3).¢d,/,9.,. Ob.'S 6,T3q q I. 6-90 ?u.3a.15:00 31 'to 94-4 -10:00 /z. 3% ,, ,. ',A. k f, 25:00 V4..2 -513 , ' :.io 4 -1 30:00 j,4.1 i"il " " ' ... .35:00 /.,3J,,, 64 6A,74 <JL! -V7 .- ..-7 40:00 A5ý16& 7CQ ~,(1 45:00 /. 3-_Y __j 3-50:00 /_/_ _______55:00 1Y. 12 , Y.. -7,,4 OL q 9z ;--2'.7r.s4 60:00 / iV 65:00 _iS e22:A- ,#, qq 4 /oIL, "-,9,??1X 5 70:00 /"1"-," / " _ __75:00 , , ... , 80:00 85:00 90:00 95:00 100:00 105:00 110:00 115:00 120:00 _Sampling lime: aP1 lveJ:iLm: a Samples Collected: Anayi~s Requested: Preservative: Holding- lime: Lab: A) FThk.~i ~c~a~g~az#4Li Notes: (1 -Do not mesanre depth to bottom of ell [l;]a frprginrg and .amrpling tedur .e.pe ndmr fin.n th.1 tay bh -estLgno the well botto.(2) .-Slabiliza ton criteria bated on three rort recent ce Innecer nmeatrecents. (3)1o3-1 danwdoc isn c ell 1o be lens than 0 1 (0.32 It) Purging rate to be lowered en necessary to keep drnwdoe. below s .1 ho (V 32 It)(4) r /- 101' when httltidity t noer 10 NTUn S Site-Name-Qrounwi -N, 5a4pin Form Low-Flow Groundwater Sampling Form Well b/i b'4 -" ..5 "CdCJ Date: Z(;/k7 -IA/Sam ling ersbn "k 7_ ... .M ,-, r Weather Conditions: k.flP , qvvý'Time: ~ ~ I4 -757 3 ________File Name: -sii Total Depth (I.D.): /ie-n Length: _" Depth to Wate (D.T.W): / 33 Well Diametei: '3 Total Volume Purged: Casing Type: £"fC..-Purge Rate: I ý Sampling Device: .,tG.r "-', *- 6")f Tubing Type: tb k e.,-idt-qfl*. Measuring Point) -I j n-" QA ,__ , (Pump Intake (ftbelod M.P.): 3 -.. color:,C[C & odor: I,, ,.Tine: DTW: Comments: Temp SpC DO pH ORP Turb (rain) (feet) ('C) (uS/cm) (mag/L) std units mV NIU Stabalization (see note +/- 0 +1- +/- +/- +/.. +/-Criteria' below)' 3% 10% 0.1 unit 10 MV 10%, 0:00 t5, ¢" 01 1, TA.. C1c 1 t£X.. '-I ,* A: -3, 12 4 5:00 1e...z f I., //l,' 2,j " ' "2OS .-20:00 7 oL5LM.', !.C1b "k,1 tW 1 1d4 2 , 25:00 2".7 2-cV 2 ,L/ro .,t --.Yr 'i'ji 4--> "i 25:00 15 Z2_L-.,1Ilj l., ýn A4.'Ar 3-(L3 Z. q 30:00 ",511/ ,o I. 26QI Jqq -7, I -10744' -22Zi, 35:00 (~i¶ 2 '.4.91- IG I-2[ _S R ,.ý i 14- "*t 01.r, 40:00 '1% j-ZAr f '15,o) 25cj4- 15 t4 A 45:00 x5, t ' .(15 154"6, 2-- 1 /L_ ' -7,.; c5 13. -I .Z. c , CI 50:00 ,s1!5.C 3 -5,578 -'1 , 7,t5- , 55:00 60:00 65:00 70:00 75:00 80:00 85:00 90:00 95:00 100:00 105:00 110:00 115:00 120:00 Sampling Time: /1¢/ I4 Samples Collected: Analysis Requested: Preservative: Holding Time: Lab: o. N-A LO i+ H 0 ict,_-P',ý,- -) kD ýOJ -r ý' uJm rkh i '~ n.i Pýi /Jr) .lvi idw~s1 Notes: -~0 r~i !)F D.) -Do ttot meusure depth -11 miott oltwell pnuil afterprgiing ad Umplintg Wt educe remaspending fiels h.,, maybs rettiog\tre well bo~om ((2) -Stobilinatino crilteia boed on three most recent consecutive measoemsnlo. (0)- Total-d1rdo d n inell ob1 le, s b than a I mt(032 ftl Porgintg r-to tmob 1ote-d snoetaty to keep drwdot.- belo 0 1 m (0 32 ft)(4)nI- 10 whee trtobdl iriover 10 N1TUs Site Name: [J ViL -xL Low-Flow Groundwater Sampling Form Sam pling Pe rs onnreF -AL Ei II',2 .7 ,,5 t Weather Conditions.:~ ~A '.Z~tiF ~ n/~~ A)WiA) i Time: -g 7(JR'7 /-File Nami: -- -6 " lotal Depth (I.D.): $0a7-.I Screen Length: Depth to Water (D.T.W): (1 ) -. Well Diameter: Total Volume Purged: " Type: Purge Rate: 1 ý.J" Sampling Device: r -¶s tf ao"' &-.Tubing Type:~ 0-(V MeasuringPoinr.t: a)trb Pump Intake (ft belovi M.P.): I color: .odor. C- I v L( -rsf Time: DTW: Comments: Temp SpC DO pH ORP Turb (rmin) (feet) MC) (uS/cm) (mg/L) std units mV NWU Stabalization (see note +/- 0 +1- +/- +/- +/- +/_Criteria2 below)' 3% 11 3% 10% 0.1 unit i0 mV 10%, 0:00 0 0"1 23-c -321. e) L 5:00 1 3 " _ "2 .1 ,, j--*3.,e j Iecrl .,.'1 .' 0 O.lt 1:00 /:030 3' , a iq 10.292 "1 "7. 73T le 0. 1-__T0_.0_ --V. Q`-'4 25:00 IiLl jI 4R /I3!&~ ~2k '3-a0 350 ll- _q. _ _ 32 40:00 /~ 4 ~ ~ Ji ? & L~~Q 45:00 ____ __________ __ __50:00 ___ ___ _ __55:00 60:00 _____ _____ ___65:00 ___ ___70:00 _____ ___ ___75:00 _____80:00 _____ ______________ 85:00 _____ _______________ ____ ____ ___90:00 ________95:00 _____ ___________ 100:00 ___________ ___105:00 ________110:00 _____115:00-j_____ 120:00-oo //. Sampling lime: ....Samples Collected: M: u) --ýql Analysis Requested: Preservative: Holdinge lime: Lab: A) 1A y , Notes) --Do not --tnenete depth to bottoe of -1ott -nit after purging aot saopling to tedtte resuspending fines that nay resting on the wnet bottomt (,)-tbitaon criteria W aned on three ..,e recent or-eacette oteonnreoenotn ( 3 ) +- T o o t e it at wd o tn n n w ell so b e t e h a t ] m ) 03 2 I t) P u rt in g t aL e to tt e lo wr e d en e e s e te k e e p d r wd o s n h e t lo w m ( 0 3 2 I t)(4)÷n/- 10% shon tttrbidiey noner 10 tJTUe 0 Site Name: GroundwteSa l low-Flow Groundwater Sampling Form Well ID: --I ": Date: :l1 n SaplngPdrsnne: EG 1 W* ae K --TP , Vr) TP Weather Conditions: OT F ,{O A~o'VL1 St) W- YJ Time: avfq lýý'File Name: IN P0 ;1.1otal Depth (I.D.): q2- J'2 Screen Length: " Depth to Watez (D.T.W): () ._ £f .' Well Diameter: 3" Total Volume Purged: 1., or,4 Casing Type: -Cif6 Purge Rate: m, -./ \ Sampling Device: -Stpi~i- *'JA..Tubing Type: -Measuring Point: -t% e-- .XC.Pump Intake (ftbbIow .LP.): '3 2 i" color: o,.'na:.e odor: r )Time: DTW: Comments: Temp SpC DO pH ORP Turb (min) (feet) (°C) (uS/cm) (mg/L) std units mV NIU Stabalization (see note +/-o * +/ +/- +/_ +/- +/-Criteria' below)' 3%IC. 3% 10% 0.1 unit 10 nMV 10%0:00 i,3-. qf'5:00 4~~3 -11 Y'ei I ~ ?Y31 'If~ C, j~ -7"1, %1 8>i~10:00 +3 1.{ 4 c" 1 q5 -7 345 --- :3 3'.r 15:00 13.43 -'o- i -/ rc i-7,2F Z4 1 7, 3" ' -I .20.00 .,,A 44- 24,4Imlra ,.i i -1y L*I '3V 1,3+ -0fl 3, /,C 25:00 ,3 .. -isIn/n,, ý , I Z477 e0 7. 31 3. fa 6,0Z 30:00 35:00 40:00 45:00 50:00 55:00 60:00 65:00 70:00 75:00 80:00 85:00 90:00 95:00 100:00 105:00 110:00 115:00 120:00 _Sampling Time: /4( -l'Samples Collected: Analysis Requested: Preservative: Holding Time: Lab: S(ii L 7, Lfvi.!'Notes: (1) Donut measure dep:h to bottom of wet until after purgitg and eceopting to reduce .e.,rpendmrg 6o-s tfat may be resting on the well botfonm) -Stabigiation criteria based on three most recent oonseonlive measurements. 3f 'Total dr-wdocot in eell 0 be I.. than 0 1 m e0 32 ft). Purgilng rite to be loweered s necessary to beep drawtdoen beelow 0.1 m (0.32 ft)(4) e/- 0M. whein turbidity is .-er 1O fTU. Site Naine: -5eASR..Low-Flow Groundwater 5amplingFonn WellJD: I -I3D _-_ _Date: ./ 01 Samnpling Pers'onnel: ~( .~ ~ -Weather Conditions: .4[-0 n~, Lse.,~' ~ ot~(4 r ~ ~ ! t Time: IQu t/yo File Name: _lotalDepth(I.D.): ScreenLength: 7 'Depth to Water (D.T.W): ( 4 ' Well Diameter: 2 Total Volume Purged: 4- , Casing Type: T-- ___-._Purge Rate:.. Sampling Device: Qfsn ~ ~ ~.Tubing Tye: # ) Measuring Point .' _, .'.Pump Intake(ffbelou M.P.5: -o color: &!Li -r, odor: I r*Cie i, r Time: DTW: Comments: Temp -SpC DO pH ORP Turb (-in) (feet) I C) (uS/cm) (mra/L) std units mV NIU Stabalization (see note 0 +/- +/- + -+/_- -Cxiteuia2 belowY 3%Ici 3% 10% 0.1 ýt 10 V1 10%, 0:00 %_ 1-4. A. I t3 4 1;, c-A 1 5:00 f t, ýqrdii _s ~ ~ ~ >fS 10:00 L-6,j O. -t/.a ' t9,<7 c4,ftc o 4 (0'f? 1.15 15:005 Z --a4e, '1 .6r,°l.-o ( _: 20_00 I: ,c r k---25:00 -z ! ' /, -I t 'I ý2,2 I llb_ mo I o. , i I I t-.-,4 ý 2si .(ý I J, s. I I H:2I L90;.P61 ') I, I I ft" .30:00i U Cm (1,A A I i~i~a~ ~ I e'. 4r~F 1 0 i ~( ,,)e;:4 ~.40:00 2LL. /iab 3 e 13 4 j 1 45:00 17 -ý 743 I.e<L A- kv -.'1 50:00 7ý ~ I/eri~~v4 ' ~ j. ~ e~7 o 55:00 Q2t"' ~ ~ ~ ~ ~ 7' 1~65:00 ~ re er/..i js~ i)'~70:00 j "-$:,o,-7., z Ul/3/ I* -ý j/. l ~tb?/7. o'. I I fDaI0*7;: f'_iS '-'- 1*75:00 I 1 I I I 80:00 _________ __85:00 __ __90:00 95:00 _ __100:00 _____ ___________ 105:00 ________ __110:00 ___________ 11-500 __ __120:00 _____ ___________ ___Samplnhg lime: Samples Collected: Analysis Requested: Preservative: Holdin Timre: Lab: Notes: (])- Do tot meatere dept, t bottom of wb[I 00th after ptu1 tnr ted -nplint to reduce erereihtg Sues that mey be ztsg on the te!] boson (2)- SýIailietion crheria bused on three mstoneceutoecutive mesurements. (3)- Tetel dt6edo-n i well to he le then 1 to (In i It) P.rging ate to bo uunend as tekenrary en ktep ds'dnnot hefoe 51 .(052 hf (4) T.v when h-th id h, e:or 10 NjTUe -Environmental, Inc./ Midwest Laboratory -an Allegheny Technologies Co.700 Landwehr Road -Norlhbrok, IL 60062-2310 ph. (847) 564-0700 -fax (847) 564-4517 APPENDIX A INTERLABORATORY COMPARISON PROGRAM RESULTS 0 NOTE: Environmental Inc., Midwest Laboratory participates in intercomparison studies administered by Environmental Resources Associates, and serves as a replacement for studies conducted previously by the U.S. EPA Environmental Monitoring Systems Laboratory, Las Vegas, Nevada. Results are reported in Appendix A. TLD Intercomparison results, in-house spikes, blanks, duplicates and mixed analyte performance evaluation program results are also reported. Appendix A is updated four times a year;, the complete Appendix is included in March, June, September and December monthly progress reports only.October, 2006 through September, 2007 Appendix A Interlaboratory Comparison Procgram Results Environmental, Inc., Midwest Laboratory has participated in interlaboratory comparison (crosscheck) programs since the formulation of it's quality control program in December 1971. These programs are operated by agencies which supply environmental type samples containing concentrations of radionuclides known to the issuing agency but not to participant laboratories. The purpose of such a program is to provide an independent check on a laboratory's analytical procedures and to alert it of any possible problems.Participant laboratories measure the concentration of specified radionuclides and report them to the issuing agency. Several months later, the agency reports the known values to the participant laboratories and specifies control limits. Results consistently higher or lower than the known values or outside the control limits indicate a need to check the instruments or procedures used.Results in Table A-1 were obtained through participation in the environmental sample crosscheck program administered by Environmental Resources Associates, serving as a replacement for studies conducted previously by the U.S. EPA Environmental Monitoring Systems Laboratory, Las Vegas, Nevada.The results in Table A-2 list results for thermoluminescent dosimeters (TLDs), via International Intercomparison of Environmental Dosimeters, when available, and internal laboratory testing.-Table -A-3-lists-results-of-the analyses-on-in-house-"spiked"-samples-forth e-pa st-telve-rnO-th-s.-All-pples are prepared using NIST traceable sources. Data for previous years available upon request.Table A-4 lists results of the analyses on in-house "blank" samples for the past twelve months. Data for previous years available upon request.Table A-5 list results of the in-house "duplicate" program for the past twelve months. Acceptance is based on the difference of the results being less than the sum of the errors. Data for previous years available upon request.The results in Table A-6 were obtained through participation in the Mixed Analyte Performance Evaluation Program.Results in Table A-7 were obtained through participation in the environmental sample crosscheck program administered by Environmental Resources Associates, serving as a replacement for studies conducted previously by the Environmental Measurement Laboratory Quality Assessment Program (EML).Attachment A lists acceptance criteria for "spiked" samples.Out-of-limit results are explained directly below the result.Al Attachment A W ACCEPTANCE CRITERIA FOR "SPIKED" SAMPLES LABORATORY PRECISION: ONE STANDARD DEVIATION VALUES FOR VARIOUS ANALYSESa One standard deviation Analysis Level for single determination Gamma Emitters 5 to 100 pCi/liter or kg 5.0 pCi/liter> 100 pCi/liter or kg 5% of known value Strontium-89b 5 to 50 pCi/liter or kg 5.0 pCi/liter> 50 pCi/liter or kg 10% of known value Strontium-90b 2 to 30 pCi/liter or kg 5.0 pCi/liter> 30 pCi/liter or kg 10% of known value Potassium-40 > 0.1 g/liter or kg 5% of known value Gross alpha < 20 pCi/liter 5.0 pCi/liter> 20 pCi/liter 25% of known value Gross beta < 100 pCi/liter 5.0 pCi/liter 5%/-otkiwrlue Tritium < 4,000 pCi/liter 1 la = (pCi/liter) =169.85 x (known)0°0 9 3 3> 4,000 pCi/liter 10% of known value Radium-226,-228 ? 0.1 pCi/liter 15% of known value Plutonium > 0.1 pCi/liter, gram, or sample 10% of known value Iodine-131, -< 55 pCi/liter 6.0 pCi/liter Iodine-1 2 9 b > 55 pCi/liter 10% of known value Uranium-238, s 35 pCi/liter 6.0 pCi/liter Nickel-63b > 35 pCi/liter 15% of known value TechnetiUM~99b Iron-55 b 50 to 100 pCi/liter> 100 pCi/liter 10 pCi/liter 10% of known value 20% of known value Othersb a From EPA publication, "Environmental Radioactivity Laboratory Intercomparison Studies Program, Fiscal Year, 1981-1982, EPA-600/4-81-004. b Laboratory limit.A2 TABLE A-1. Interlaboratory Comparison Crosscheck program, Environmental Resource Associates (ERA)a.Concentration (pCi/L)Lab Code Date Analysis Laboratory ERA Control Result Resultc Limits Acceptance STW-1 104 STW-1 104 STW-1105 STW-i 105 STW-1 105 STW-1105 STW-1 105 STW-1106 STW-1 106 STW-1 107 0 STW-1 108 STW-1 108 STW-1108 STW-1109 STW-1121 STW-1 121 STW-1 122 STW-1 122 STW-1 122 STW-1122 STW-1122 STW-1 123 STW-1 123 STW-1124 STW-1 125 STW-1 125 STW-1125 STW-1125 STW-1 127 STW-1 127 STW-1128 STW-1 128 STW-1 128 STW-1 128 STW-1 128 STW-1 129 STW-1129 STW-1 130 STW-1 130 STW-1130 10/06/06 10/06/06 10/06/06 10/06/06 10/06/06 10/06/06 10/06/06 10/06/06 10/06/06 10/06/06 10/06/06 10/06/06 10/06/06 10/06/06 04109/07 04/09/07 04/09/07 04/09/07 04/09/07 04/09/07 04/09/07 04/09/07 04/09/07 04/09/07 04/09/07 04/09/07 04/09/07 04/09/07 07/09/07 07/09/07 07/09/07 07/09/07 07/09107 07/09/07 07/09/07 07/09/07 07/09/07 07/09/07 07/09/07 07/09/07 Sr-89 Sr-90 Ba-133 Co-60 Cs-134 Cs-137 Zn-65 Gr. Alpha Gr. Beta 1-131 Ra-226 Ra-228 Uranium H-3 Sr-89 Sr-90 Ba-1 33 Co-60 Cs-134 Cs-137 Zn-65 Gr. Alpha Gr. Beta 1-131 H-3 Ra-226 Ra-228 Uranium Sr-89 Sr-90 Ba-133 Co-60 Cs-1 34 Cs-1 37 Zn-65 Gr. Alpha Gr. Beta Ra-226 Ra-228 Uranium 38.4 +/- 1.3 15.5 +/- 0.5 64.9 +/- 2.8 61.6 +/- 1.0 29.0 +/- 0.9 77.8 +/- 2.4 293.0 +/- 2.4 23.9 +/- 2.5 23.7 +/- 1.4 28.4 +/- 1.2 14.5 +/- 0.5 6.6 +/- 0.4 2.9 +/- 0.1 3000.0 +/- 142.0 30.7 +/- 4.3 39.3 +/- 1.8 30.0 +/- 2.4 118.5 +/- 3.9 52.6 +/- 2.3 49.5 +/- 3.8 91.7 +/- 6.3 33.8 +/- 3.5 24.2 +/- 2.3 19.2 +/- 1.2 7540.0 +/- 255.0 13.0 +/- 0.6 19.9 +/- 2.7 4.5 +/- 0.2 51.7 +/- 5.0 21.4 +/- 2.3 19.4 +/- 2.2 32.8 +/- 2.0 67.0 +/- 2.9 61.6 +/-3.8 55.6 +/- 7.5 19.2 +/- 1.6 9.1 +/- 0.9 7.0 +/- 0.5 9.2 +/- 2.3 23.9 +/- 1.1 39.9 16.0 70.2 62.3 29.9 78.2 277.0 28.7 20.9 22.1 14.4 5.9 3.2 3050.0 35.4 42.1 29.3 119.0 54.3 50.3 88.6 56.5 25.3 18.9 8060.0 13.4 18.2 4.6 58.2 19.0 19.4 33.5 68.9 61.3 54.6 27.1 11.5 7.7 9.1 25.1 31.2 -45.7 7.3 -24.7 58.1 -82.3 53.6 -71.0 21.2 -38.6 69.5 -86.9 229.0 -325.0 16.3 -41.1 12.2 -29.6 16.9 -27.3 10.7 -18.1 3.3 -8.4 0.0 -8.4 2430.0 -3670.0 Pass Pass Pass Pass Pass Pass Pass Pass Pass Fail Pass Pass Pass Pass 26.7 -44.1 33.4 -50.8 20.6 -38&0 109.0 -129.0 45.6 -63.0 41.6 -59.0 73.3 -104.0 32.0 -81.0 16.6 -34.0 13.7 -24.1 6660.0 -9450.0 9.9 -16.9 10.3 -26.1 0.0 -9.8 49.5 -66.9 10.3 -27.7 10.7 -28.1 24.8 -42.2 60.2 -77.6 52.6 -70.0 45.2 -64.0 15.4 -38.8 2.8 -20.2 5.7 -9.7 5.2 -13.1 19.9 -30.3 Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Results obtained by Environmental, Inc., Midwest Laboratory as a participant in the crosscheck program for proficiency testing in drinking water conducted by Environmental Resources Associates (ERA).b Unless otherwise indicated, the laboratory result is given as the mean +/- standard deviation for three determinations. Results are presented as the known values, expected laboratory precision (1 sigma, 1 determination) and control limits as provided by ERA.The reported result was an average of three analyses, results ranged from 25.36 to 29.23 pCi/L'A fourth analysis.was performed, result of analysis, 24.89 pCi/L.Al-1 S TABLE A-2. Crosscheck program results; Thermoluminescent Dosimetry, (TLD, CaSO 4: Dy Cards).mR Lab Code Date Known Lab Result Control Description Value +/- 2 sigma Limits Acceptance Environmental, Inc.2006-2 11/6/2006 2006-2 11/6/2006 2006-2 11/6/2006 2006-2 11/6/2006 2006-2 11/6/2006 2006-2 11/6/2006 2006-2 11/6/2006 2006-2 11/6/2006 2006-2 11/6/2006 30 cm.40 cm.50 cm.60 cm.75 cm.90 cm.120 cm.150 cm.180 cm.55.61 31.28 20.02 13.90 8.90 6.18 3.48 2.22 1.54 60.79 + 1.32 35.93 + 3.70 21.55 + 1.20 14.90 + 1.42 8.03 + 0.51 6.88 +/- 0.68 2.90 +/- 0.20 1.99 +/- 0.07 1.79 +/- 0.94 38.93 -72.29 21.90 -40.66 14.01 -26.03 9.73 -18.07 6.23-11.57 4.33 -8.03 2.44 -4.52 1.55 -2..89 1.08 -2.00 Pass Pass Pass Pass Pass Pass Pass Pass Pass'Environmental, Inc.2007-1 2007-1 2007-1 2007-1 2007-1 2007-1 2007-1 2007-1 2007-1 2007-1 2007-1 7/13/2007 7/13/2007 7/13/2007 7/13/2007 7/13/2007 7/13/2007 7/13/2007 7/13/2007 7/13/2007 7/13/2007 7/13/2007 30 cm.40 cm.50 cm.60 cm.70 cm.80 cm.90 cm.100 cm.110 cm.120 cm.150 cm.54.25 30.51 19.53 13.56 9.96 7.63 6.03 4.88 4.03 3.39 2.17 60.56 +/- 5.54 34.23 +/- 0.96 17.95 +/- 1.86 16.61 + 0.60 9.72 + 0.90 7.79 + 0.33 5.53 + 0.72 5.32 +/- 0.17 3.49 +/- 0.14 2.64 +/- 0.14 2.13 +/- 0.87 37.98 -70.53 21.36 -39.66 13.67 -25.39 9.49 -17.63 6.97 -12.95 5.34 -9.92 4.22 -7.84 3.42 -6.34 2.82 -5.24 2.37 -4.41 1.52 -2.82 Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass A2-1 TABLE A-3. In-House "Spike" Samples Concentration (pCi/L)8 Lab Code b Date Analysis Laboratory results Known Control 2s, n=1 c Activity Limits d Acceptance W-120106 W-120106 SPAP-9476 SPAP-9478 SPAP-9478 SPW-9480 SPW-9483 SPW-9486 SPW-9488 SPW-9488 SPMI-9490 SPMI-9490 SPF-9492 SPF-9492 W-30707 W-30707 S PAP-1566 SPAP-1566 SPW-1568 SPW-1678 SPW-1 595 SPW-1595 SPW-1595 SPW-1595A SPW-1595B SPMI-1597 SPMI-1597 SPMI-1597 SPMI-1597A SPMI-1597B SPCH-2839 SPW-2847 SPW-2847 SPW-2847 SPMI-2849 SPMI-2849 SPMI-2849 SPCH-2922 SPW-2847 SPW-2847 SPW-2847 SPMI-2849 12/1/2006 12/1/2006 12/29/2006 12/29/2006 12/29/2006 12/29/2006 12/29/2006 12/29/2006 12/29/2006 12/29/2006 12/29/2006 12/29/2006 12/29/2006 12/29/2006 3/7/2007 3/7/2007 3/23/2007 3/23/2007 3/23/2007 3/28/2007 4/5/2007 4/5/2007 4/5/2007 415/2007 4/5/2007 4/5/2007 4/5/2007 4/5/2007 4/5/2007 4/5/2007 5/17/2007 5/17/2007 5/17/2007 5/17/2007 5/17/2007 5/17/2007 5/17/2007 5/17/2007 5/18/2007 5/18/2007 5118/2007 5/18/2007 Gr. Alpha Gr. Beta Gr. Beta Cs-134 Cs-137 H-3 Tc-99 Fe-55 Cs-1 34 Cs-137 Cs-134 Cs-137 Cs-134 Cs-137 Gr. Alpha Gr. Beta Cs-134 Cs-1 37 H-3 Tc-99 Cs-134 Cs-137 1-131(G)1-131 1-131 Cs-134 Cs-137 1-131(G)1-131 1-131 1-131(G)Cs-1 34 Cs-137 1-131(G)Cs-1 34 Cs-137 1-131(G)1-131(G)1-131 Sr-89 Sr-89 1-131 22.40 +/- 1.03 63.70 +/- 1.14 57.51 +/- 0.14 26.84 +/- 1.23 110.54 +/- 3.12 68972.20 +/- 748.00 29.43 +/- 0.84 17168.00 +/- 410.00 61.35 +/- 1.65 60.30 +/- 2.76 58.99 +/- 5.43 54.16 +/- 7.85 0.64 +/- 0.01 2.61 +/- 0.03 19.51 +/- 0.40 67.45 +/- 0.49 25.35 +/- 1.31 107.52 +/- 3.02 65595.00 +/- 672.00 28.44 +/- 1.12 54.48 +/- 2.12 59.03 +/- 2.94 83.11 +/- 3.51 78.40 +/- 1.10 78.97 +/- 1.10 54.03 +/- 2.15 59.81 +/- 4.75 83.97 +/- 4.07 79.53 +/- 1.03 83.51 +/- 1.05 78.70 +/- 7.36 55.43 +/- 1.68 59.86 +/- 2.71 63.95 +/- 2.69 51.37 +/- 1.65 60.42 +/- 4.31 62.44 +/- 3.14 80.00 +/- 6.40 60.14 +/- 0.89 104.93 +/- 6.64 46.72 +/- 1.97 67.97 +/- 0.88 20.08 65.73 53.16 30.06 117.10 72051.60 32.98 19712.50 60.10 56.80 60.10 56.80 0.60 2.34 20.08 65.73 27.82 116.48 71118.00 32.35 54.99 58.19 82.07 82.07 82.07 54.99 58.19 82.07 82.07 82.07 70.40 52.85 58.03 70.87 52.85 58.03 70.87 70.40 70.87 121.90 46.08 70.87 10.04 -30.12 55.73 -75.73 42.53 -74.42 20.06 -40.06 105.39 -128.81 57641.28 -86461.92 20.98 -44.98 15770.00 -23655.00 50.10 -70.10 46.80 -66.80 50.10 -70.10 46.80 -66.80 0.36 -0.84 1.40 -3.28 10.04 -30.12 55.73 -75.73 17.82 -37.82 104.83 -128.13-56894.40 -85341.60 20.35 -44.35 44.99 -64.99 48.19 -68.19 72.07 -92.07 65.66 -98.48 65.66 -98.48 44.99 -64.99 48.19 -68.19 72.07 -92.07 65.66 -98.48 65.66 -98.48 60.40 -80.40 42.85 -62.85 48.03 -68.03 60.87 -80.87 42.85 -62.85 48.03 -68.03 60.87 -80.87 41.60 -99.20 56.70 -85.04 97.52 -146.28 36.08 -56.08 56.70 -85.04 Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass A3-1 TABLE A-4. In-House "Blank" Samples Concentration (pCi/L)a Lab Code Sample Date Analysisb Laboratory results (4.66a) Acceptance Type LLD Activityc Criteria (4.66 c)W-120106 water 12/1/2006 Gr. Alpha 0.11 0.066 +/- 0.072 1 W-120106 water 12/1/2006 Gr. Beta 0,30 0.093 +/- 0.16 3.2 SPAP-9477 Air Filter 12/29/2006 Gr. Beta 1.13 -0.37 +/- 0.66 3.2 SPAP-9479 Air Filter 12/29/2006 Cs-137 0.87 100.SPW-9481 water 12/29/2006 H-3 146.2 63.2 +/- 80.1 200 SPW-9483 water 12/29/2006 Tc-99 0.95 -1.20 +/- 0.56 10 SPW-9489 water 12/29/2006 Cs-1 34 2.30 10 SPMI-9491 Milk 12/29/2006 Cs-134 3.10 10 SPMI-9491 Milk 12/29/2006 Cs-1 37 2.90 10 SPMI-9491 Milk 12/29/2006 1-131(G) 8.00 20 SPF-9493 Fish 12/29/2006 Cs-134 7.6 100 SPF-9493 Fish 12/29/2006 Cs-137 7.9 100 W-30707 water 3/7/2007 Gr. Alpha 0.04 0.00 +/- 0.03 1 W-30707 water 3/7/2007 Gr. Beta 0.08 0.01 +/- 0.05 3.2 SPAP-1567 Air Filter 3/23/2007 Cs-134 0.79 100 SPW-1567 Air Filter 3/23/2007 Cs-137 1.01 100 SPW-1568 water 3/23/2007 H-3 176.10 -26.16 +/- 91.62 200 SPW-1596 water 4/5/2007 Cs-134 3.28 10 SPW-1 596 water 4/5/2007 Cs-1 37 3.45 10 SPW-1596 water 4/5/2007 1-131 0.27 0.02 +/- 0.18 0.5 SPW-1596 water. 4/5/2007 1-131(G) 2.91 20 SPMI-1598 Milk 4/5/2007 Cs-134 3.30 10 SPMI-1598 Milk 4/5/2007 Cs-137 5.08 10 SPMI-1598 Milk 4/5/2007 1-131 0.26 -0.10 +/- 0.17 0.5 SPMI-1598 Milk 4/5/2007 1-131(G) 4.10 20 SPCH-2839 Charcoal Canister 5/17/2007 1-131(G) 2.24 9.6 SPW-2848 water 5/17/2007 Cs-134 3.14 10 SPW-2848 water 5/17/2007 Cs-137 1.37 10 SPW-2848 water 5/17/2007 1-131 (G) 5.34 20 SPMI-2850 Milk 5/17/2007 Cs-134 3.32 10 SPMI-2850 Milk 5/17/2007 Cs-1 37 2.60 10 SPMI-2850 Milk 5/17/2007 1-131(G) 4.77 20 SPW-2848 water 5/18/2007 1-131 0.34 -0.06 +/- 0.19 0.5 SPW-2848 water 5/18/2007 Sr-89 0.81 -0.02 +/- 0.65 5 SPW-2848 water 5/18/2007 Sr-90 0.53 0.01 +/- 0.25 1 SPMI-2850 Milk 5/18/2007 1-131 0.45 0.20 +/- 0.26 0.5 SPMI-2850 Milk 5/18/2007 Sr-89 0.96 -0.73 +/- 1.02 5 SPMI-2850 d Milk 5/18/2007 Sr-90 0.58 0.96 +/- 0.38 1 A4-1 TABLE A-4. In-House "Blank" Samples Concentration (pCi/L)e Lab Code Sample Date Analysisb Laboratory results (4.66a) Acceptance Type LLD Activityc Criteria (4.66 a)SPAP-2914 Air Filter 5/22/2007 Gr. Beta 0.004 -0.002 + 0.002 3.2 SPAP-2916 Air Filter 5/22/2007 Cs-1 34 2.84 100 SPAP-2916 Air Filter 5/2212007 Cs-137 2.24 100 SPF-2923 Fish 5/22/2007 Cs-134 8.71 100 SPF-2923 Fish 5/22/2007 Cs-137 8.35 100 SPW-3224 water 5/24/2007 Ni-63 1.61 -0.30 +/- 0.84 20 W-60507 water 6/5/2007 Gr. Alpha 0.04 0.00 +/- 0.03 1 W-60507 water 6/5/2007 Gr. Beta 0.08 0.00 +/- 0.05 3.2 SPW-4328 water 7/18/2007 Tc-99 6.41 -3.12 +/- 3.84 10 SPW-5477 water 8/17/2007 Ni-63 0.00 4.38 +/- 1.01 20 W-92107 water 9/21/2007 Gr. Alpha 0.04 0.01 +/- 0.03 1 W-92107 water 9/21/2007 Gr. Beta 0.08 -0.03 +/- 0.05 3.2 a Liquid sample results are reported in pCi/Liter, air filters( pCi/filter), charcoal (pCi/charcoal canister), and solid samples (pCi/kg).b 1-131(G); iodine-131 as analyzed by gamma spectroscopy. c Activity reported is a net activity result, For gamma spectroscopic analysis, activity detected below the LLD value is not reported.d Low levels of Sr-90 are still detected in the environment. A concentration of (1-5 pCi/L) in milk is not unusual.A4-2 TABLE A-5. In-House "Duplicate" Samples Concentration (pCi/L)a Averaged Lab Code Date Analysis First Result Second Result Result Acceptance MI-6760, 6761 G-6797, 6798 G-6797, 6798 G-6797, 6798 b AP-7531, 7532 AP-7552, 7553 AP-7573, 7574 SO-7103, 7104 SO-7103, 7104 DW-60759, 60760 MI-7037, 7038 VE-7058, 7059 VE-7058, 7059 VE-7058, 7059 SS-7079, 7080 SS-7079, 7080 SS-7079, 7080 MI-7208, 7209 DW-60809, 60810 DW-60797, 60798 DW-60797, 60798 CF-7450, 7451 LW-7945, 7946 F-7971, 7972 SWU-8194, 8195 BS-8017, 8018 BS-8017, 8018 TD-8173, 8174 LW-8215, 8216 F-8345, 8346 BS-8366, 8367 MI-8083, 8084 WW-8259, 8260 VE-8149, 8150 VE-8149, 8150 DW-60877, 60878 DW-60990, 60991 MI-8484, 8485 DW-60925, 60926 SO-8619, 8620 SO-8619, 8620 SO-8619, 8620 SO-8619, 8620 10/2/2006 10/2/2006 10/2/2006 10/2/2006 10/3/2006 10/3/2006 10/3/2006 10/4/2006 10/4/2006 10/5/2006 10/10/2006 10/10/2006 10/10/2006 10/10/2006 10/10/2006 10/10/2006 10/10/2006 10/11/2006 10/16/2006 10/17/2006 10/17/2006 10/18/2006 10/26/2006 10/29/2006 10/31/2006 11/1/2006 11/1/2006 11/1/2006 11/1/2006 11/2/2006 11/2/2006 11/6/2006 11/7/2006 11/8/2006 11/8/2006 11/14/2006 11/20/2006 11/22/2006 11/22/2006 11/27/2006 11/27/2006 11/27/2006 11/27/2006 K-40 Be-7 Gr. Beta K-40 Be-7 Be-7 Be-7 Cs-1 37 K-40 Gr. Alpha K-40 Gr. Alpha Gr. Beta K-40 Cs-137 Gr. Beta K-40 K-40 Gr. Alpha Gr. Alpha Gr. Beta K-40 Gr. Beta K-40 Gr. Beta Gr. Beta K-40 H-3 Gr. Beta K-40 K-40 K-40 H-3 Be-7 K-40 Gr. Alpha Gr. Alpha K-40 Gr. Alpha Cs-1 37 Gr. Alpha Gr. Beta K-40 1413.10 +/- 113.20 4.70 +/- 0.31 6.89 +/- 0.26 5.39 +/- 0.35 0.07 +/- 0.01 0.08 +/- 0.02 0.08 +/- 0.02 0.25 +/- 0.05 12.95 +/- 1.12 4.93 +/- 0.97 1326.10 +/- 115.20 0.18 +/- 0.11 9.21 +/- 0.34 10.90 +/- 0.65 0.04 +/- 0.01 12.23 +/- 2.46 7.23 +/- 0.36 1295.20 +/- 116.90 1.44 +/- 1.06 0.84 +/- 0.70 0.86 +/- 0.56 20.40 +/- 0.84 1.30 +/- 0.37 3.63 +/- 0.54 1.84 +/- 0.28 10.54 +/- 1.72 10.00 +/- 0.53 580.00 +/- 110.00 2.23 +/- 0.61 2.84 +/- 0.42 13.69 +/- 0.66 1295.00 +/- 121.20 337.00 +/- 95.00 1.26 +/- 0.24 4.17 +/- 0.47 48.03 +/- 5.32 6.70 +/- 2.03 1405.80 +/- 87.06 3.87 +/- 1.13 0.74 +/- 0.08 16.54 +/- 5.65 24.99 +/- 3.88 12.21 +/- 1.11 1187.30 +/- 155.20 4.56 +/- 0.41 7.04 +/- 0.24 4.36 +/- 0.47 0.08 +/- 0.01 0.08 +/- 0.01 0.08 +/- 0.01 0.27 +/- 0.06 12.22 +/- 1.07 5.04 +/- 1.03 1251.40 +/- 115.70 0.32 +/- 0.14 8.83 +/- 0.36 10.42 +/- 0.80 0.04 +/- 0.02 11.76 +/- 2.23 7.37 +/- 0.40 1386.90 +/- 119.10 1.65 +/- 1.19 1.03 +/- 0.67 1.33 +/- 0.60 19.54 +/- 0.99 1.44 +/- 0.36 3.33 +/- 0.43 1.43 +/- 0.28 10.17 +/- 1.73 9.60 +/- 0.69 599.00 +/- 110.00 1.64 +/- 0.37 2.89 +/- 0.40 13.61 +/- 0.78 1374.80 +/- 162.80 295.00 +/- 93.00 1.25 +/- 0.22 4.49 +/- 0.45 47.26 +/- 6.77 3.41 +/- 1.34 1390.70 +/- 103.60 3.04 +/- 0.99 0.69 +/- 0.06 12.24 +/- 4.90 28.66 +/- 3.95 12.92 +/- 0.83 1300.20 +/- 96.05 4.63 +/- 0.26 6.97 +/- 0.18 4.88 +/- 0.29 0.08 +/- 0.01 0.08 +/- 0.01 0.08 +/- 0.01 0.26 +/- 0.04 12.58 +/- 0.77 4.99 +/- 0.71 1288.75 +/- 81.64 0.25 +/- 0.09 9.02 +/- 0.25 10.66 +/- 0.52 0.04 +/- 0.01 11.99 +/- 1.66 7.30 +/- 0.27 1341.05 +/- 83.44 1.54 + 0.80 0.94 +/- 0.48 1.10 +/-+0.41 19.97 +/- 0.65 1.37 +/- 0.26 3.48 +/- 0.34 1.64 +/- 0.20 10.36 +/- 1.22 9.80 +/- 0.44 589.50 + 77.78 1.93 +/- 0.35 2.86 +/- 0.29 13.65 +/- 0.51 1334.90 +/- 101.48 316.00 + 66.47 1.26 +/- 0.16 4.33 +/- 0.33 47.65 +/- 4.31 5.06 +/- 1.22 1398.25 +/- 67.66 3.46 +/- 0.75 0.71 +/- 0.05 14.39 +/- 3.74 26.82 + 2.77 12.57 +/- 0.69 Pass Pass Pass Fail Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass 0 A5-1 TABLE A-5. In-House "Duplicate" Samples Concentration (pCi/L)a Averaged Lab Code Date Analysis First Result Second Result Result Acceptance DW-60902, 60903 SWT-8641, 8642 DW-60937, 60938 S-3437,3438 S-3437,3438 S-3437, 3438 DW-8929, 8930 SWT-9436, 9437 E-20, 21 E-20, 21 CF-41, 42 CF-41, 42 CF-41, 42 P-9516, 9517 LW-9579, 9580 DW-70085, 70086 DW-70037, 70038.DW-70054, 70055 DW-70122, 70123 DW-70122, 70123 DW-70098, 70099 DW-70110, 70111 SWU-676,677 DW-70148, 70149 SW-600, 601 SW-601, 602 DW-1138,1139 MI-721, 722 SW-847, 848 SW-847, 848 DW-70175, 70176 DW-70187, 70188 SWU-1162,1163 DW-70205, 70206 PW-1117, 1118 PW-1117, 1118 W-2122,2123 W-2122,2123 W-2085,2086 W-2085,2086 DW-70232, 70233 11/28/2006 11/29/2006 11/30/2006 12/6/2006 12/6/2006 12/6/2006 12/8/2006 12/26/2006 1/2/2007 1/2/2007 1/2/2007 1/2/2007 1/2/2007 1/3/2007 1/4/2007 1/9/2007 1/11/2007 1/18/2007 1/18/2007 1/18/2007 1/25/2007 1/25/2007 1/30/2007 1/30/2007 2/1/2007 2/1/2007 2/9/2007 2/13/2007 2/13/2007 2/13/2007 2/14/2007 2/14/2007 2/27/2007 2/28/2007 3/1/2007 3/1/2007 3/5/2007 3/5/2007 3/6/2007 3/6/2007 3/8/2007 Gr. Alpha Gr. Beta Gr. Alpha Gr. Alpha Gr. Beta K-40 1-131 Gr. Beta Gr. Beta K-40 Gr. Beta K-40 Sr-90 H-3 Gr. Beta Gr. Alpha Gr. Alpha Gr. Alpha Gr. Alpha Gr. Beta Gr. Alpha Gr. Alpha Gr. Beta Gr. Alpha K-40 Gr. Beta H-3 K-40 Gr. Alpha Gr. Beta Gr. Alpha Gr. Alpha Gr. Beta Gr. Alpha Gr. Alpha Gr. Beta Gr. Alpha Gr. Beta Gr. Alpha Gr. Beta Gr. Alpha 5.06 +/- 1.10 2.83 +/- 0.47 2.65 +/- 0.92 1.77 +/- 0.90 3.98 +/- 1.10 2.83 +/- 0.21 0.58 +/- 0.27 2.39 +/- 0.64 3.70 +/- 1.05 2.89 +/- 0.45 1.59 +/- 0.88 2.33 +/- 0.90 3.21 +/- 1.03 2.98 +/- 0.22 0.42 +/- 0.26 2.25 +/- 0.60 4.38 +/- 0.76 2.86 +/- 0.33 2.12 +/- 0.64 2.05 +/- 0.64 3.60 +/- 0.76 2.91 +/- 0.15 0.50 +/- 0.19 2.32 +/- 0.44 1.76 +/- 0.07 1.49 +/- 0.24 18.02 +/- 0.41 11.68 +/- 1.12 0.04 +/- 0.01 270.78 +/- 91.74 0.91 +/- 0.31 7.95 +/- 1.20 55.47 +/- 3.99 2.68 +/- 0.88 4.30 +/- 1.14 4.22 +/- 0.70 3.27 +/- 0.90 2.19 +/- 0.92 1.77 +/- 0.39 4.65 +/- 1.37 1.24 +/- 0.12 0.89 +/- 0.37 2707.00 +/- 161.00 1330.40 +/- 117.60 3.82 +/- 1.67 7.33 +/- 1.37 11.72 +/- 1.68 6.79 +/- 1.18 3.63 +/- 0.69 0.88 +/- 0.80 3.79 +/- 1.91 7.12 +/- 1.40 6.10 +/- 4.16 10.65 +/- 2.15 2.51 +/- 2.29 11.02 +/- 1.85 4.75 +/- 1.28 1.70 +/- 0.06 1.57 +/- 0.27 18.81 +/- 0.42 12.67 +/- 0.97 0.03 +/- 0.01 301.18 +/- 92.99 0.93 +/-+0.30 7.92 +/- 1.42 52.87 +/- 4.02 1.88 +/- 0.78 6.25 +/- 1.16 5.33 +/- 0.75 1.97 +/- 0.92 1.69 +/- 0.79 2.11 +/-0.39 5.20 +/- 1.81 1.20 +/- 0.12 1.02 +/- 0.25 2700.00 +/- 161.00 1316.40 +/- 116.50 2.61 +/- 1.24 5.89 +/- 0.90 8.84 +/- 1.32 6.47 +/- 1.08 2.61 +/- 0.44 1.31 +/- 0.79 3.62 +/- 2.09 7.20 +/- 1.39 3.80 +/- 4.30 13.11 +/- 2.42 1.10 +/- 2.78 9.50 +/- 2.01 5.98 +/- 1.31 1.73 +/- 0.05 1.53 +/- 0.18 18.42 +/- 0.29 12.18 +/- 0.74 0.03 +/- 0.01 285.98 +/- 65.31 0.92 +/- 0.22 7.94 +/- 0.93 54.17 +/- 2.83 2.28 +/- 0.59 5.28 +/- 0.81 4.78 +/- 0.51 2.62 +/- 0.64 1.94 +/- 0.61 1.94 +/- 0.28 4.93 +/- 1.14 1.22 +/- 0.08 0.96 +/- 0.22 2703.50 +/- 113.84 1323.40 +/- 82.77 3.22 +/- 1.04 6.61 +/- 0.82 10.28 +/- 1.07 6.63 +/- 0.80 3.12 +/- 0.41 1.10 +/- 0.56 3.71 +/- 1.42 7.16 +/- 0.99 4.95 +/- 2.99 11.88 +/- 1.62 1.81 +/- 1.80 10.26 +/- 1.37 5.37 +/- 0.92 Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass A5-2 TABLE A-5. In-House "Duplicate" Samples Concentration (pCi/L)a Averaged.Lab Code Date Analysis First Result Second Result Result Acceptance WW-1477,1478 WW-1498,1499 W-2140, 2141 W-2140,2141 DW-1626,1627 MI-1647,1648 DW-70248, 70249 W-2150,2151 W-2150, 2151 LW-1941, 1942 MI-1824,1825 MI-1824, 1825 AP-2170, 2171 WW-1850, 1851 AP-2198, 2199 AP-2370, 2371 DW-70300, 70301 DW-70300, 70301 DW-70335, 70336 DW-70335, 70336 SW-1898,1899 SW-1898,1899 SW-1898,1899 DW-70346, 70347 DW-70346, 70347 DW-70376, 70377 DW-70376, 70377 DW-70311, 70312 WW-2349,2350 WW-2461, 2462 LW-2437, 2438 LW-2917, 2918 SO-2583,2584 SO-2583, 2584 SO-2583, 2584 SO-2583, 2584 SO-2583, 2584 S-2620,2621 MI-2610,2611 3/12/2007 3/15/2007 3/19/2007 3/19/2007 3/21/2007 3/21/2007 3/21/2007 3/26/2007 3/26/2007 3/31/2007 4/2/2007 4/2/2007 4/2/2007 4/3/2007 4/3/2007 4/3/2007 4/4/2007 4/4/2007 4/5/2007 4/5/2007 4/10/2007 4/10/2007 4/10/2007 4/11/2007 4/11/2007 4/11/2007 4/11/2007 4/12/2007 4/17/2007 4/25/2007 4/26/2007 4/30/2007 5/1/2007 5/1/2007 5/1/2007 5/1/2007 5/1/2007 5/2/2007 5/3/2007 Gr. Beta Gr. Beta Gr. Alpha Gr. Beta H-3 K-40 Gr. Alpha Gr. Alpha Gr. Beta Gr. Beta K-40 Sr-90 Be-7 H-3 Be-7 Be-7 Gr. Alpha Gr. Beta Gr. Alpha Gr. Beta Gr. Alpha Gr. Beta H-3 Gr. Alpha Gr. Beta Gr. Alpha Gr. Beta Gr. Alpha Gr. Alpha H-3 Gr. Beta Gr. Beta Be-7 Cs-137 K-40 Gr. Alpha Gr. Beta H-3 K-40 6.41 +/- 1.48 0.83 +/- 0.31 2.31 +/- 1.57 4.26 +/- 1.00 4973.00 +/- 209.00 1448.80 +/- 120.20 11.10 _ 1.18 3.56 + 2.20 9.26 + 1.00 1.35 -0.43 1316.10 _ 110.60 1.20 +/- 0.50 0.08 +/- 0.01-5.83 + 102.29 0.08 +/- 0.01 0.07 +/- 0.01 3.78 +/- 0.89 2.93 +/- 0.61 24.37 +/- 2.89 20.26 +/- 1.37 3.86 +/- 1.40 6.31 +/- 1.36 241.99 +/- 93.35 1.83 +/- 1.08 4.62 +/- 0.72 1.81 +/- 0.80 1.84 +/- 0.62 10.82 +/- 1.50 0.71 +/- 0.56 190.30 +/- 100.31 2.71 +/- 0.50 1.97 +/- 0.79 544.99 +/- 247.70 119.22 +/- 36.61 17825.00 +/- 749.90 11.49 +/- 3.96 31.02 +/- 3.74 277.90 +/- 126.70 1549.20 +/- 184.20 4.10 +/- 1.25 0.97 +/- 0.33 1.33 +/- 1.64 5.58 +/- 1.02 5190.00 +/- 213.00 1439.30 +/- 126.00 9.90 +/- 1.16 3.30 +/- 1.81 10.17 +/- 1.90 1.36 +/- 0.41 1229.80 +/- 110.50 1.10 +/- 0.36 0.08 +/- 0.01 150.05 +/- 80.14 0.08 +/- 0.01 0.07 +/- 0.01 3.66 +/- 0.96 2.91 +/- 0.64 22.72 +/- 2.91 18.33 +/- 1.34 4.78 +/- 1.51 7.03 +/- 1.42 318.10 +/- 96.48 2.54 +/- 1.04 4.01 +/- 0.71 1.66 +/- 0.86 2.24 +/- 0.61 13.20 +/- 1.56 0.62 +/- 0.52 115.95 +/- 97.65 2.15 +/- 0.45 2.78 +/- 0.81 601.13 +/- 192.20 87.46 +/- 23.97 17672.00 +/- 724.30 8.04 +/- 3.88 26.10 +/- 3.40 304.40 +/- 101.00 1388.80 +/- 128.20 5.26 +/- 0.97 0.90 +/- 0.22 1.82 +/- 1.14 4.92 +/- 0.71 5081.50 +/- 149.21 1444.05 +/- 87.07 10.50 +/-20.83 3.43 +/- 1.42 9.72 +/- 1.07 1.36 +/- 0.30 1272.95 +/- 78.17 1.15 +/- 0.31 0.08 +/- 0.01 72.11 +/- 64.97 0.08 +/- 0.01 0.07 +/- 0.01 3.72 +/- 0.65 2.92 +/- 0.44 23.55 +/- 2.05 19.30 +/- 0.96 4.32 +/- 1.03 6.67 +/- 0.98 280.04 +/- 67.12 2.19 +/- 0.75 4.32 +/- 0.51 1.74 +/- 0.59 2.04 +/- 0.44 12.01 +/- 1.08 0.66 +/- 0.38 153.13 +/- 70.00 2.43 +/- 0.34 2.38 +/- 0.57 573.06 +/- 156.76 103.34 +/- 21.88 17748.50 +/- 521.29 9.77 +/- 2.77 28.56 +/- 2.53 291.15 +/- 81.02 1469.00 +/- 112.21 Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass A5-3 TABLE A-5. In-House "Duplicate" Samples Concentration (pCi/L)a Averaged Lab Code Date Analysis First Result Second Result Result Acceptance W-4469, 4470 SS-2697, 2698 SS-2697, 2698 MI-2790, 2791 W-4505, 4506 DW-3219, 3220 SO-3416, 3417 SO-3416, 3417 SO-3416, 3417 F-3561, 3562 SL-3311, 3312 SL-3311, 3312 SL-3992, 3993 SL-3992, 3993 SL-3992, 3993 W-5087, 5088 SW-3710, 3711 W-4062, 4063 W-4062, 4063 AP-4448, 4449 SG-3735, 3736 SG-3735, 3736 SG-3735, 3736 SG-3735, 3736 LW-4175, 4176 SG-5422, 5423 SG-5422, 5423 AP-4656, 4657 AP-4763, 4764 WW-4298, 4299 DW-70612, 70613 WW-4918, 4919 MI-4742, 4743 VE-4939, 4940 VE-4939, 4940 VE-4939, 4940 SW-5218, 5219 WW-5310, 5311 SW-5393, 5394 SW-5393, 5394 W-5468, 5469 5/7/2007 5/8/2007 5/8/2007 5/14/2007 5/14/2007 5/26/2007 5/31/2007 5/31/2007 5/31/2007 5/31/2007 6/4/2007 6/4/2007 6/4/2007 6/4/2007 6/4/2007 6/11/2007 6/14/2007 6/28/2007 6/28/2007 6/28/2007 6/30/2007 6/30/2007 6/30/2007 6/30/2007 6/30/2007 7/2/2007 7/2/2007 7/3/2007 7/3/2007 7/12/2007 7/23/2007 7/25/2007 7/26/2007 8/1/2007 8/1/2007 8/1/2007 8/7/2007 8/9/2007 8/14/2007 8/14/2007 8/15/2007 Gr. Beta Cs-1 37 K-40 K-40 Gr. Beta 1-131 Cs-137 Gr. Beta K-40 K-40 Be-7 K-40 Be-7 Gr. Beta K-40 Gr. Beta H-3 Gr. Alpha Gr. Beta Be-7 Be-7 Cs-1 37 Gr. Beta K-40 Gr. Beta Gr. Alpha Gr. Beta Be-7 Be-7 Gr. Beta Gr. Alpha H-3 K-40 Be-7 Gr. Beta K-40 1-131 H-3 Gr. Beta H-3 H-3 10.60 +/- 1.90 0.06 +/- 0.02 8.03 +/- 0.57 1694.30 +/- 126.20 3.30 +/- 1.70 0.62 +/- 0.32 0.15 +/- 0.03 22.88 +/- 2.33 12.26 +/- 0.80 3.06 +/- 0.39 0.61 +/- 0.29 5.78 +/- 0.67 0.75 +/- 0.19 13.61 +/- 1.12 2.43 +/- 0.36 8.70 +/- 1.90 9571.51 +/- 287.22 0.76 +/- 0.63 0.97 +/- 0.53 0.10 +/- 0.02 0.84 +/- 0.12 0.07 +/- 0.01 29.51 +/- 2.22 9.41 +/- 0.31 2.18 +/- 0.60 10.31 +/- 1.98 18.59 +/- 1.46 0.09 +/- 0.02 0.11 +/- 0.02 1.74 +/- 0.74 4.54 +/- 1.11 240.43 +/- 111.12 1820.30 +/- 134.10 0.39 +/- 0.21 5.50 +/- 0.14 3.36 +/- 0.45 1.31 +/- 0.24 644.00 +/- 106.00 2.32 +/- 1.31 190.06 +/- 86.80 262.58 +/- 108.43 11.10 +/- 1.80 0.05 +/- 0.03 7.36 +/- 0.68 1627.60 +/- 128.80 3.90 +/- 1.50 0.69 +/- 0.31 0.15 +/- 0.03 22.46 +/- 2.37 12.36 +/- 0.65 3.37 +/- 0.45 0.55 +/- 0.25 4.87 +/- 0.25 0.74 +/- 0.32 14.06 +/- 1.08 2.29 +/- 0.40 7.70 +/- 1.90 9879.21 +/- 291.42 0.32 +/- 0.66 0.58 +/- 0.57 0.09 +/- 0.02 0.82 +/- 0.18 0.07 +/- 0.01 30.81 +/- 2.22 8.90 +/- 0.48 1.93 +/- 0.68 10.57 +/- 1.99 20.97 +/- 1.49 0.10 +/- 0.02 0.10 +/- 0.02 2.22 +/- 0.80 4.19 +/- 0.97 216.68 +/- 110.27 1802.90 +/- 199.50 0.45 +/- 0.20 5.76 +/- 0.13 3.36 +/- 0.21 1.42 +/- 0.24 831.00 +/- 113.00 1.71 +/- 1.27 69.05 +/- 80.88 346.53 +/- 111.42 10.85 +/- 1.31 0.05 +/- 0.02 7.70 +/- 0.44 1660.95 +/- 90.16 3.60 +/- 1.13 0.66 +/- 0.22 0.15 +/- 0.02 22.67 +/- 1.66 12.31 +/- 0.52 3.21 +/- 0.30 0.58 +/- 0.19 5.33 +/- 0.36 0.75 +/- 0.19 13.84 +/- 0.78 2.36 +/- 0.27 8.20 +/- 1.34 9725.36 +/- 204.59 0.54 +/- 0.45 0.78 +/- 0.39 0.10 +/- 0.01 0.83 +/- 0.11 0.07 +/- 0.01 30.16 +/- 1.57 9.16 +/- 0.29 2.06 +/- 0.45 10.44 +/- 1.40 19.78 +/- 1.04 0.10 +/- 0.01 0.11 +/- 0.01 1.98 +/- 0.55 4.37 +/- 0.74 228.56 +/- 78.27 1811.60 +/- 120.19 0.42 +/- 0.15 5.63 +/- 0.10 3.36 +/- 0.25 1.37 +/- 0.17 737.50 +/- 77.47 2.02 +/- 0.92 129.55 +/- 59.32 304.55 +/- 77.74 Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass A5-4 TABLE A-5. In-House "Duplicate" Samples Concentration (pCi/L)a Averaged Lab Code Date Analysis First Result Second Result Result Acceptance ve-5553, 5554 WW-5643,5644 SWU-5799, 5800 DW-70752, 70753 VE-5917, 5918 VE-5917, 5918 DW-70718, 70719 DW-70718, 70719 SO-6156, 6157 8/22/2007 8/22/2007 8/28/2007 8/31/2007 9/4/2007 9/4/2007 9/12/2007 9/12/2007 9/14/2007 K-40 H-3 Gr. Beta Gr. Alpha Be-7 K-40 Gr. Alpha Gr. Beta H-3 1.89 +/- 0.33 259.00 +/- 110.00 2.64 +/- 1.18 14.41 +/- 1.48 0.94 +/- 0.17 3.73 +/- 0.37 23.04 +/- 3.71 16.13 +/- 1.59 181.99 +/- 90.67 1.89 +/- 0.22 266.00 +/- 110.00 3.62 +/- 1.06 12.90 +/- 1.50 0.83 +/- 0.20 3.58 +/- 0.36 23.22 +/- 3.61 17.36 +/- 1.69 232.19 +/- 92.95 1.89 +/- 0.20 262.50 +/- 77.78 3.13 +/- 0.79 13.66 +/- 1.05 0.89 +/- 0.13 3.66 +/- 0.26 23.13 +/- 2.59 16.75 +/- 1.16 207.09 +/- 64.92 Pass Pass Pass Pass Pass Pass Pass Pass Pass Note: Duplicate analyses are performed on every twentieth sample received in-house. Results are not listed for those analyses with activities that measure below the LLD.a Results are reported in units of pCi/L, except for air filters (pCi/Filter), food products, vegetation, soil, sediment (pCi/g).b 200 minute count time or longer, resulting in lower error.A5-5 TABLE A-6. Department of Energy's Mixed Analyte Performance Evaluation Program (MAPEP)a.Concentration b Known Control Lab Codec Date Analysis Laboratory result Activity Limits d Acceptance STW-1110 01/01/07 Gr.Alpha STW-1110 01/01/07 Gr. Beta 0.45 +/- 0.08 0.90 +/- 0.14 0.33 0.85 0.00 -0.65 0.43-1.28 STW-1111 e STW-1111 STW-1111 STW-1111 STW-1111 STW-1111 STW-1111 STW-1111 STW-1111 STW-1111 STW-1111 STW-1111 STW-1111 STW-1111 STW-1111 STW-1111 STSO-1112' STSO-1112 STSO-1112 STSO-1 112 STSO-1112 STSO-1112 01/01/07 01/01/07 01/01/07 01/01/07 01/01/07 01/01/07 01/01/07 01/01/07 01/01/07 01/01/07 01/01/07 01/01/07 01/01/07 01/01/07 01/01/07 01/01/07 01/01/07 01101107 01/01/07 01/01/07 01/01/07 01/01/07 Am-241 Co-57 Cs-134 Cs-137 Fe-55 H-3 Mn-54 Ni-63 Ni-63 Pu-238 Pu-239/40 Sr-90 Tc-99 U-233/4 U-238 Zn-65 Am-241 Co-57 Co-60 Cs-134 Cs-I 37 Mn-54 2.80 +/- 0.21 151.60 +/- 10.00 79.20 +/- 8.00 168.70 +/- 12.10 130.30 +/- 19.90 262.20 +/- 9.10 130.60 +/- 11.50 127.80 +/- 3.60 127.80 +/- 3.60 2.03 +/- 0.17 2.27 +/- 0.17 9.60 +/- 1.40 8.80 +/- 1.50 2.44 +/- 0.21 2.44 +/- 0.21 123.70 +/- 17.00 46.40 +/- 9.00 501.20 +/- 2.90 285.90 +/- 2.10 325.90 +/- 7.40 855.70 +/- 4.60 750.90 +/- 4.70 0.27 +/-0.04 0.57 +/- 0.05 0.10 +/- 0.03 3.51 +/- 0.07 2.98 +/- 0.10 4.02 +/- 0.16 2,75 +/- 0.12 3.94 +/- 0.12 0.07 +/- 0.01 0.08 +/- 0.01 0.58 +/- 0.18 0.09 +/- 0.01 0.09 +/- 0.01 2.70 +/- 0.10 1.71 143.70 83.50 163.00 129.30 283.00 123.80 130.40 130.40 2.25 2.22 8.87 88.00 2.49 2.48 114.80 34.80 471.20 274.70 327.40 799.70 685.20 0.60 0.44 0.10 2.89 2.91 4.20 2.57 3.52 0.07 0.08 0.61 0.10 0.10 2.68 1.20 -2.22 100.60 -186.80 58.50 -108.60 114.10 -211.90 90.50 -168.10 198.10 -367.90 86.70 -160.90 91.30 -169.50 91.30 -169.50 1.58 -2.93 1.55 -2.89 6.21 -11.53 7.40 -13.70 1.74 -3.24 1.74 -3.22 80.40 -149.20 24.40 -45.20 329.80 -612.60 192.30 -357.10 229.20 -425.60 559.80 -1039.60 479.60 -890.80 0.00 -1.20 0.22 -0.66 0.07 -0.13 2.02 -3.75 2.03 -3.78 2.94 -5.45 1.80 -3.34 2.46 -4.57 0.05 -0.09 0.06 -0.11 0.43 -0.79 0.07 -0.13 0.07 -0.13 1.88 -3.49 Pass Pass Fail Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Fail Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass.Pass Pass Pass Pass Pass STAP-1113 01/01/07 Gr. Alpha STAP-1113 01/01/07 Gr. Beta STAP-1 114 STAP-1 114 STAP-1114 STAP-1 114 STAP-1114 STAP-1114 STAP-1 114 STAP-1 114 STAP-1 114 STAP-1 114 STAP-1 114 STAP-1114 01/01/07 01/01/07 01/01/07 01/01/07 01/01/07 01/01/07 01/01/07 01/01/07 01/01/07 01/01/07 01/01/07 01/01/07 Am-241 Co-57 Co-60 Cs-1 34 Cs-1 37 Mn-54 Pu-238 Pu-239/40 Sr-90 U-233/4 U-238 Zn-65 A6-1 S TABLE A-6. Department of Energy's Mixed Analyte Performance Evaluation Program (MAPEP)a.Concentration b Known Control Lab Codec Date Analysis Laboratory result Activity Limits d Acceptance STVE-1115 STVE-1115 STVE-1115 STVE-1 115 STVE-1115 01/01/07 01/01/07 01/01/07 01/01/07 01/01/07 Co-57 Co-60 Cs-134 Cs-137 Mn-54 8.90 +/- 0.20 6.50 +/- 0.20 6.90 +/- 0.30 8.20 +/- 0.30 10.10 +/- 0.30 8.19 5.82 6.21 6.99 8.46 5.73 -10.64 4.08 -7.57 4.35 -8.07 4.90 -9.09 5.91 -10.98 Pass Pass Pass Pass Pass O Results obtained by Environmental, Inc., Midwest Laboratory as a participant in the Department of Energy's Mixed Analyte Performance Evaluation Program, Idaho Operations office, Idaho Falls, Idaho b Results are reported in units of Bq/kg (soil), Bq/L (water) or Bq/total sample (filters, vegetation). c Laboratory codes as follows: STW (water), STAP (air filter), STSO (soil), STVE (vegetation). d MAPEP results are presented as the known values and expected laboratory precision (1 sigma, I determination) and control limits as defined by the MAPEP.e Result of reanalysis, 2.08 +/- 0.13 pCi/L.f The test samples were recounted on lower background detectors. Result of the recounts: 41.4 + 6.3 Bq/kg.A6-2 TABLE A-7. Interlaboratory Comparison Crosscheck program, Environmental Resource Associates (ERA)a.Concentration (pCi/L)Lab Code b Date Analysis Laboratory ERA Control Result c Result d Limits Acceptance STAP-1116 03/19/07 Gr. Alpha STAP-1116 03/19/07 Gr. Beta 34.64 +/- 2.56 93.41 +/- 3.20 25.8 79.5 12.4 -39 48.8 -116 STAP-1l117 STAP-1117 STAP-1117 STSO-1117 e STSO-1117 STSO-1117' STAP-1117 STAP-1l117 STAP-1l117 STAP-1 117 STAP-1 117 STAP-1117 STAP-1117 STSO-1 118 STSO-1118 STSO-1 118 STSO-1118 STSO-11 18 STSO-1 118 STSO-1 118 STSO-1118' STSO-1 118 STSO-11 18 STSO-1 118 STSO-1118 STSO-1118 STSO-1118 STSO-1118 STSO-1118 STSO-1118 STSO-1118 STSO-1118' 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 Am-241 Co-60 Cs-134 Cs-137 Fe-55 Mn-54 Pu-238 Pu-239/40 Sr-90 U-233/4 U-238 Uranium Zn-65 Ac-228 Am-241 Bi-212 Co-60 Cs-1 34 Cs-137 K-40 Mn-54 Pb-212 Pb-214 Pu-238 Pu-239/40 Sr-90 Th-234 U-233/4 U-238 Uranium Uranium Zn-65 56.04 +/- 3.90 1610.00 +/- 8.40 1340.40 +/- 48.84 345.30 +/- 8.20< 134.0< 5.0 43.32 +/- 2.28 35.23 +/- 2.24 156.10 +/- 6.60 42.22 +/- 1.84 42.00 +/- 1.84 85.79 +/- 3.60 363.80 +/- 11.90 3097.77 +/- 94.96 1000.70 +/- 156.10 2467.87 +/- 114.33 7847.40 +/- 86.60 7910.60 +/- 356.88 4635.00 +/- 99.10 12201.60 +/- 423.20< 34.0 2046.80 +/- 127.20 4142.80 +/- 110.40 1099.20 +/- 73.10 1586.10 +/- 82.00 6163.30 +/- 791.60 4329.40 +/- 569.10 3236.70 +/- 106.00 3425.20 +/- 134.00 6787.80 +/- 240.00 6787.80 +/- 240.00 0.00 +/- 0.00 57.5 1300.0 1120.0 255.0 0.0 0.0 37.4 31.6 156.0 47.8 47.4 97.3 245.0 2790.0 927.0 2500.0 7330.0 7560.0 4300.0 11100.0 0.0 1730.0 3330.0 857.0 1360.0 7500.0 3590.0 3620.0 3590.0 7380.0 7380.0 0.0 33.1 -80 1010.0 -1620 732.0 -1380 192.0 -336 25.7-49 22.9 -41 66.6 -246 30.1 -71 30.2 -68 49.5 -155 208.0-412 1790.0 -3930 548.0 -1200 658.0 -3730 5340.0 -9820 4850.0 -9070 3290.0 -5580 8050.0 -15000 1120.0 -2430 1980.0 -4980 490.0 -1200 928.0 -1810 2610.0 -12400 2190.0 -4560 2280.0 -4520 2190.0 -4560 4210.0 -9930 4210.0 -9930 0.0 -0 Pass Pass Pass Pass Pass Fail Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass A7-1 TABLE A-7. Interlaboratory Comparison Crosscheck program, Environmental Resource Associates (ERA)a.Concentration (pCi/L)Lab Code b Date Analysis Laboratory ERA Control Result c Result d Limits Acceptance STVE-1 119 STVE-1119 STVE-1 119 STVE-1 119 STVE-1119 STVE-1 119 STVE-1119' STVE-1119 STVE-1 119 STVE-1119 STVE-1119 STVE-1119 STVE-1 119 STVE-1 119 STW-1 120 STW-1120 STW-1120 STW-1 120 STW-1120 STW-1120'STW-1 120 STW-1120 STW-1 120 STW-1120 STW-1 120 STW-1120 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 03/19/07 Am-241 Cm-244 Co-60 Cs-134 Cs-1 37 K-40 Mn-54 Pu-238 Pu-239/40 Sr-90 U-233/4 U-238 Uranium Zn-65 Am-241 Co-60 Cs-134 Cs-1 37 Fe-55 Mn-54 Pu-238 Pu-239/40 Sr-90 U-233/4 U-238 Uranium 3249.60 +/- 150.30 1860.70 +/- 91.50 2827.90 +/- 62.40 654.80 +/- 48.40 3307.30 +/- 58.80 40814.20 +/- 618.80< 27.6 2762.00 +/- 251.10 2156.60 +/- 83.40 8999.70 +/- 580.90 2821.90 +/- 73.50 2896.10 +/- 50.70 5718.00 +/- 124.15 474.30 +/- 45.70 133.50 +/- 10.60 541.40 +/- 9.00 1623.80 +/- 66.10 1839.10 +/- 17.90 829.50 +/- 226.80<8.1 123.30 +/- 4.30 95.10 +/- 3.80 949.40 +/- 16.70 164.20 +/- 6.58 169.20 +/- 8.22 339.60 +/- 10.66 2009.00 +/- 36.40 3550.0 1840.0 2600.0 579.0 2920.0 37900.0 0.0 2430.0 1900.0 8890.0 2940.0 2910.0 5980.0 366.0 179.0 536.0 1750.0 1850.0 671.0 0.0 116.0 90.9 989.0 192.0 190.0 391.0 2020.0 -4890 905.0 -2870 1760.0 -3720 308.0 -822 2150.0 -4060 27200.0 -53600 1250.0 -3600 1180.0 -2600 4900.0 -11800 1930.0 -3920 2090.0 -3610 4110.0 -7770 267.0 -500 123.0 -243 467.0 -631 1290.0 -2020 1570.0 -2220 392.0 -896 87.6- 144 70.3 -113 630.0 -1320 145.0 -247 145.0 -236 282.0 -521 Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass 0 STW-1120 03/19/07 Zn-65 1910.0 1600.0 -2410 a Results obtained by Environmental, Inc., Midwest Laboratory as a participant in the crosscheck program for proficiency testing administered by Environmental Resources Associates, serving as a replacement for studies conducted previously by the Environmental Measurements Laboratory Quality Assessment Program (EML).b Laboratory codes as follows: STW (water), STAP (air filter), STSO (soil), STVE (vegetation). c Unless otherwise indicated, the laboratory result is given as the mean +/- standard deviation for three determinations. d Results are presented as the known values, expected laboratory precision (1 sigma, 1 determination) and control limits as provided by ERA.eA high bias (- 20%) was observed in gamma results for air filters. A composite filter geometry was used in the calculations vs. a single filter geometry. Result of recalculation. Cs-1 37, 305.8 +/- 6.0 pCi/filter. f Included in the testing series as a "false positive". No activity expected.A7-2 Appendix C Data Assessment September/October 2007 Monitoring Event RADIOCHEMICAL DATA REVIEW The purpose of the radiochemical data review is to determine the range of background concentrations of tritium in groundwater at Davis-Besse and to identify the concentration above which would signify detections above background in the data set. Since tritium was the only radiological compound detected in water samples above the MDC, the analysis is only performed for tritium.Low level concentrations reported by the laboratory may reflect 1.)uncertainty in the sample and laboratory analysis; 2.) tritium from historic atmospheric bomb testing; 3.) tritium from cosmic ray interactions in the earth's atmosphere; or 4.) localized tritium washout from continuous and batch gaseous releases. In order to assess these local background condition levels, a statistical approach was used following industry guidance (EPRI, 2005) to evaluate the significance of the low level detections. Local background concentrations can also be defined by comparing reported tritium values from wells upstream of potential radiological source(s) of release. For example, wells MW-100 is located hydraulically up-gradient of potential source(s) of liquid tritium released from the Power Block. The reported concentrations of tritium were: <193, <193 and<149 for MW-100-A, -B and -C, respectively. The mean value is <178 pCi/L. This low level concentration limit provides a reference at which to evaluate reported results from samples collected down-gradient and cross-gradient of the Power Block. It is noted that MW-100A, -B and -C were sampled once; therefore, the background reference may change if more up-gradient wells were available. Additional evaluation of background can be performed by evaluating the reported concentrations in groundwater against concentrations in surface water from Lake Erie.A statistical approach was also used to define local background conditions. The results reported by Midwest Laboratory were compared against 2-sigma (o) total propagated uncertainty (TPU) of the analysis, with a 95% confidence level. The 2-o TPU value combines counting uncertainty and any other factors that contribute to the overall uncertainty including uncertainties in the sample mass, chemical yield and determination of calibration factors.ERM/DADE MOELLER 1 FIRSTENERGY -DAVIS-BESSE 0065992.2 18 MARCH 08 The 2-a TPU was estimated by calculating a raw standard deviation using the field and laboratory duplicate data collected during both the June 2007 and September/October 2007 event (Table 7). Both sets of data were used to provide a sufficient number of comparisons (i.e., population statistics) that could not be achieved if only using the September /October 2007 data. The field duplicates and laboratory duplicates from both events were used to measure the total uncertainty and evaluate the quality of the TPU estimate.The raw 2-o standard deviation was calculated at 87.3 pCi/L. The raw 2-o standard deviation includes the effects of stochastic variations, volume measurements, calibration errors, and chemical factors. A Student's t correction factor was calculated (1.9432) because the sample size is less than 30 sample pairs. The correction factor was applied to calculate the upper 95% limit of the TPU, which was thereby established to be 170 pCi/L. Given the limited sample population, the 2-u TPU values are preliminary and their robustness will increase with future monitoring events as more duplicate sample pairs are included in the analysis. As the number of duplicate sample pairs increases, the correction factor will decrease.Statistical analysis and verification of the June and September/October 2007 results for tritium are summarized in the following table: Value Concentration (pCi/L) Comment Up-gradient well 178 mean LLD from well MW- 10 Typical MDC 183 Reported result from well MW-31D 2-G TPU 170 Upper 95% confidence level Statistical decision level Data reporting convention (EPRI, 2005);348 sum of background well and 2-G TPU The TPU and the sub components of the TPU were evaluated for reasonableness and internal consistency. The data satisfy all quality requirement considerations. For the data presented here, individual measurements between 178 and 348 pCi/L represent statistically insignificant activity at the 95% confidence level.Individual measurement results above the decision level (i.e., 348 pCi/L)represent concentrations that are statistically greater than background and likely warrant additional monitoring. Monitoring wells where the net concentration was detected above the action level included MW-12D (738 ERM/DADE MOELLER 2 FIRSTENERGY -DAVIS-BESSE 0065992.218 MARCH 08 pCi/L), MW-15D (442 pCi/L), MW-30S (494 pCi/L), MW-31S (3,149 pCi/L), MW-35D (368 pCi/L), MW-102A LD (387 pCi/L), MW-102B (394 pCi/L), MW-103A (495 pCi/L), MW-103B (362 pCi/L), and MW-105A (1,832 pCi/L), (Table 7).ERM/DADE MOELLER 3 FIRSTENERGY -DAVIS-BESSE 0065992.2 18 MARCH 08 QUALITY ASSURANCE -QUALITY CONTROL
1.0 INTRODUCTION
This section presents a quality assurance and quality control (QA/QC)review of the Davis-Besse September/October 2007 groundwater sampling event. This evaluation was conducted to assess and enhance the reliability and validity of the groundwater analytical data. The verification process was conducted to identify the most common sampling and analytical problems that could affect the quality of the results. In general the results met the data quality objectives.
2.0 QUALITY
ASSURANCE Quality assurance involves planned and systematic actions necessary to provide confidence in the analytical results. The goal of the QA program is to have a program that is operating within acceptable criteria; thereby enhancing the representativeness and comparability of the results.Qualitative measures include items related to the field as well as the laboratory activities.
2.1 SAMPLING
PROGRAM The procedures used to collect the groundwater samples were detailed in a FSP (ERM, 20 September 2007). Specifications, such as well locations, well construction, sampling intervals, sampling and analysis techniques were items among others that were described to evaluate the representativeness of the groundwater samples collected. Groundwater samples were collected by personnel from the BETA Laboratory. Field notes were reviewed to assess if the procedures were executed properly.The following information reviews items were included in the field sampling quality assurance program.* Sampling documentation -The sample team maintained a field notebook (bound weatherproof logbooks) that was filled out at ERM/DADE MOELLER 4 FIRSTENERGY -DAVIS-BESSE 0065992.2 18 MARCH 08 each location where a sample was collected. It contains the sample V designation, collection time, description, and field instrument calibration log. The team also completed a Low-Flow Groundwater Sampling Form at each monitored location. The forms present information regarding location, weather, time, well construction, sampling depth, sampling device, field parameters and sample containers. The completed Low-Flow Groundwater Sampling forms are included within Appendix C." Sample Identification -Well IDs were used to identify the groundwater samples. The same codes were used to complete the chain-of-custodies (COCs). Duplicate samples were recorded as blind samples. Actual duplicate sample IDs were recorded on each Low-Flow Groundwater Sampling Form. COC records are included within Appendix C.* Decontamination -Dedicated high density polyethylene (HDPE)tubing was used at each location. Wells were sampled using either a peristaltic pump (30 wells, no decontamination required) or a bladder pump (2 wells, pump decontaminated after each use). An equipment blank sample was collected from the bladder pump after sampling at monitoring well MW-101C.* Calibration and Preventive Maintenance of Field Instruments -Sampling team personnel calibrated the geochemical parameter probe every day before starting the sampling. Calibration logs were maintained in the notebook.* Sampling locations -All locations were sampled as planned in the FSP." Gauging -A synoptic water level gauging round including all of the monitoring wells selected for the evaluation of tritium and gamma emitting radionuclides was performed on 24 September 2007 prior to sampling.* Sampling Depths -Sampling depths were reported on the individual Low-Flow Groundwater Sampling Forms. Sampling depths were consistent with sampling depths recommended in the Field Sampling Plan." Field Duplicates -All duplicate samples were collected in accordance with the FSP with the exception of sample duplicate DBD-04 that was taken at monitoring well MW-103B and not MW-ERM/ DADE MOELLER 5 FIRSTENERGY -DAVIS-BESSE 0065992.2 18 MARCH 08 104B because of the unexpected low groundwater elevation at MW-104B. This change did not affect the data quality.2.2 ANALYTICAL PROGRAM Groundwater samples were analyzed by Midwest Laboratory for analysis of tritium by EPA Method 906.0 and gamma emitting radionuclides by EPA Method 901.1 as specified within the FSP. Midwest Laboratory currently performs radiological environmental monitoring for over 20 nuclear power plants in 11 states. In addition, the laboratory is certified to perform analysis of drinking water for radionuclides in Illinois, Indiana, Wisconsin, and Kentucky. Midwest Laboratory maintains a Quality Assurance / Quality Control Program based on 10 CFR Part 50, Appendix B and Reg. Guide 4.15.3.0 QUALITY CONTROL The analytical data were assessed in terms of precision, accuracy, representativeness, comparability and completeness (PARCCs) to evaluate the usability of the results generated. Quality control items were evaluated through laboratory checks (e.g., matrix spikes, duplicate samples), and sampling method reviews (equipment blanks, trip blanks).In addition, Midwest Laboratory has participated in interlaboratory comparison (crosscheck) programs since the formulation of their quality control program in December 1971. Results of the interlaboratory program are presented at the end of this appendix.The following information provides background on the types of QC samples that were used to evaluate if the data quality objectives of the sampling program were met. Assessment of data quality based on compliance with PARCCs criteria is presented in the following. 0 Precision -United States Environmental Protection Agency (EPA)guidance suggests that the Relative Percent Difference (RPD) of field duplicates should be less than 30 percent in water samples.The RPD is calculated as: RPD -I Sample -Duplicate I (Sample + Duplicate) / 2 ERM/DADE MOELLER 6 FIRSTENERGY -DAVIS-BESSE 0065992.2 18 MARCH 08 Calculated RPD values for the tritium results were within guidelines and are presented in the following table.Field Duplicate RPD Calculations Sample Duplicate Sample Duplicate RPD ID ID Result Result MW-12D DBD-01 738 769 4 %MW-20S DBD-02 189 218 14 %MW-31S DBD-03 3,149 3,012 4 %MW-103B DBD-04 362 394 9%0 Accuracy -Matrix spike/matrix spike duplicate (MS/MSD), and laboratory control/ laboratory control duplicate sample are documented in the attached laboratory reports. These indicators are used to assess if the matrix may be biasing the reported results high (generally based on greater than 130 percent recovery) or low (generally based on less than 70 percent recovery). RPDs are generally expected to be less than 30 percent between MS and MSD results. As shown in the following table, all RPDs for tritium and cesium were within acceptable ranges.Matrix Spike/Matrix Spike Duplicate RPD Calculations Sample ID Compound MS/MSD Spike + Initial Sample RPD ID Sample Activities Result MW-30S Tritium MS1-17,185 16,321 5%MW-100A MSD01-MW-30S Tritium MW-bOA 17,185 16,925 2 %MW-100A MW-30S Cs-137 65.6 68.6 4 %MW-100A MSD01-MW-30S Cs-137 MW-bOA 65.6 70.2 7 %MW-100A MS0O2-MW-100A Tritium MW- 27,990 26,895 4 %MW-30S MW-100A Tritium MS0-27,990 26,895 4 %MW-30S MW-bA Cs137 MS02-MW-100A Cs-137 98.4 109.1 10 %MW-30S MSD02-MW-100A Cs-137 MW-30S 98.4 108.4 10 %MW-30S No Cesium was detected in the actual samples. Values indicate actual spike activity.* Representativeness and Comparability -The representativeness and comparability of analytical data was qualitatively evaluated by 0 ERM/DADE MOELLER 7 F1 RSTE N ERGY -DAV IS- BESSE 0065992.2 18 MARCH 08 comparing sample results from the same locations between the September/October 2007 and the June and July/ August 2007 monitoring events.Groundwater Titrium Results Comparison -1st, 2"d & 3rdSampling rounds Monitoring June or lulv/August 2007 Sept/Oct 2007 RPD Well MW-12S MW-12D MW-15S MW-15D MW-20S MW-20D MW-30S MW-30D MW-31S MW-31D MW-33S MW-33D MW-37S NA: Not Applicable H-3 Activity 860 1,155 375 704 279 328 1,149 231 7,322 108 2,702 3,271 2,961 H-3 Activity 276 738 301 442 189<174 494<174 3,149 183 1,110 1,934 1,231 103 %44%22 %46 %39 %NA 80 %NA 80 %180 %84 %54 %44%Tritium activities decreased in average by 29% between the June/July/August and September/October sampling events.Additional monitoring will be necessary to evaluate if this trend is representative of long-term groundwater quality.Tritium was not detected in the equipment blank above the minimum detectable concentration (MDC), signifying that tritium was not cross-contaminated between samples. The absence of cross-contamination signifies that the reported results are most likely representative of groundwater quality at each monitoring well." Completeness -Based on review of sampling and laboratory check-in procedures, as well as field and laboratory QA/QC results, the data is considered to be complete and useable.* Sensitivity -The MDCs were consistent with data quality objectives (at least 200 pCi/L) as they ranged between 149 and 193 pCi/L for tritium and 1.4 and 14.4 pCi/L for the gamma emitting radionuclides, which allowed to establish if results were below site background. The 200 pCi/L value corresponds to an environmental level that would allow evaluating an eventual release of tritium to the environment. ERM/DADE MOELLER 8 FIRSTENERGY -DAVIS-BESSE 0065992.2 18 MARCH 08
4.0 CONCLUSION
Based on the review of the QA/QC information summarized above, the data meet the data quality objectives defined in the FSP.S ERM/DADE MOELLER 9 FIRSTENERGY -DAVIS-BESSE 0065992.2 18 MARCH 08 Site Name: "DA / 1-BE:S-yF Low-1-ow Groundwater Sampling Form Well ID: Date: WeatherConditions: -t .(,Xfl " Thne: OqR3o 0 1 -10 "A File Name: T5B -"2. S f IotalDepth(I.D.): -. ScreenLenth:. Total Volume Pursed: .Casing Type: Purge Rate: "OOPSamplin Device: tl ., Th Tubing TYe: oll, \a" Measu-ringnPoint. Pump Intake (ftbelowMP.): 3 '_, color: Qkc.Y-" odor:. orlu t Time: DTW: Comments: Temp SpC DO jYH ORP Turb (min) (feet) __ (C) (uS/cm) (mg/L) std units "mV NTU Stabalization (see note +/- +/_ t/- +/_ +/- +/-Criteriae below)Y 3% 3% 10% 0.1 uit 10 mV 10%V 5:00 1~j 5ý s (Onr A (A~,09 2,12 6 '2,8 0 1.2ja ii +/-~I II 10:00 i 'Loom% li/wn I' -" 1 2. 14..24 15:00 1t 'tOm rtA Ip. j0z-,1 S 3-41 2j2- 9 "2. a. rO 1.o o._S 20:00 VI'," Z05,-111 (T 2I A 'PI -3,44 -r,&-7 vi 2,oS5 25:00 1514 t o" P-01"7 i, 11% ZA.1 I R to -I. ZI
- Z,ZS 30:00 J9A+/- l 2-10 CA Q fn 1 .87 x'tt 1 3.(,g -.Z '1 't,3.3 lo'j-35:00 15. IA '407aM, p, 1, i7, 7X .Z. lt 3.,7 9 -' 7,2S J.. .3 1. .--7 40:90 7,00"-o elb ,,/ 7.,2_ o3 , i 45:.00 5_ , _ ,_ .,5 -7. 2 j3 Q,- , -50:00 ______ zog&Q-'-n i .j1Q Z,1O ct IS 1E2. j*I, 55:00 5.2-~00A-I" / /,hý W% -) los!iý -?% ' Ia ;IA -A. .60:00 z_,, ZO1,c- or, t ,c ,o3 3.0 "7,O 1 n o, 4" 65:00 13% %41 ~ j"A1112~ 3.Lo -Z -1.2 C,50 70:00 75:00 80:00 85:00 90:00 95:00 100:00 105:00 110:00 115:00 120:00 Sampling Time: 107,X .8 0-4 Samples Collected:
Analysis Requested: Preservative: Holding lime: Lab: Mv UJ -i Z G.-,M Ma h 6 n't-, Notes:"" (])- Do not -,e d&pth to bottom of well until after purging and saropling to reduce resuspendmg fmes thit may be reting on the weil bottom (2) 1- St1l0% wooion etiteea baoed on three 10 ost rocret oorecutive meaSotentr. "-"*(3( -Total drosodoset tn welt to he toe.s theeII 0,1ra (032 ft) Pureging rote. to be Ioae eeos ot necetoory to heep crawdose hetowe 15 .Im (0 32 It)(4)} /-1-10% wehen torbidity] is 13 NI~r.~&"": SiteName" A o L ow-flow Groundwater Sampling Form Well ID9: tvU 3- t ...Date: 1.01l4 010 WeatherConditions: , 4-°..ij 5 2 .FileName: .-2."D Iotal Depth (I.DG): 1 -.3 1 Sc"een Lengft ' .Deoth to Watea (D.T.W): Wel Diametex: -311 Total Volume Purged:- q, 7 "Casing Type: VC Purge Rate: .0 L.Z Sampling Device:- f iz-t-OZtl<ýo P __TubingType:: Measur a Poin; 4 o- eC n umpi Intake.(ftbelow M.P.):' color:rhqg+ ca,-odor:.
- Time: DTW: Comments:
Temp SpC DO 'pH ORP Turb (rmin) (feet) CC) (uS/cir) (img/L) std units mV NTU Stabalization (see note ++- +/- +1- +I- +1- +I-Criteria2 below)0 3% .3% .10% 0.1 tnit 10XmV 0:00 .. 4., 4i I. Ib IS-1S q .3 .7 3%Q 7-1R '. 3.-3 5:00 ,, -, iS " C.A 7. 1 # -"178.s 10:00 6 24,9. " %' 5. -2A2.1 3.10 15.00 .24,, 31 0 ,t 1/L ,. 18. -A.545 ,4-. 1, 7 5 -s0, 3.72 t 20:00 A# .i.,4 -i, &g34,3 25:00- _ _ 1 /. 5 ,, I,+c 3 12G 4,.n '7,.tI -ji_ , _ " 3,18 40:00 mb 1A I A-7 '3' 4411 7113 -m+.~ I.%4-z 45:00 4, q 1~~'c 4-6 40:00 ', IOIo, .3,7Y-1 4,4-7 -7,13 50i 4.Ots 45:00 14f.'L, 1Mgc8 f t9,12' "733 4,77 '. t 3 -2".5 .,08 50:00 AA,6 "1CI I, M IA iScz MUMjj 6,1'L t3 --1-19. 0~$755:00- j4'jj f-~ I8(t AJ~JA -v323, 3... :o_ , -I2 7 3.69 I. 5 "I, , .* -3. I i5 60:00 A4,9t zoo,,,([.f,,,, 18.44 -!N'(6 G.SO -7A1 q4 .1 241 65:00 14. %,, toc f fu ,7 , q ,Z( 7.U 1-A -1,7 3, 1Z 70:00 14,A6 7-5,l'-'M,,^ 19.(20 a.so -7,t3 .-'c,+ 3,g.75:00 i4MG M-_T.__16, (0,t__ -A 53 -7.13 -1 2 _ _. 132 80:00 14____ (2_1__. '_,, ,. -11.1 :-12.85:00 14.21 Iq5-L..,q1,, i ,t,5" s'tnz .{ tt z .o.95:00 100.00 105:00 110:00 115:00 S120:00 ... ... _.... .Sampling ime: i 2_5Z- 3'3 Samples Collected: Analysis Requested: Preservative: Holding Time: Lab: Notes-(1). Do- Io .oroo- depýbl bot 611 ofoot nal i, porgin$ ..d i-tpio sosdoor-oP-sd g fisor (tot sopbe t6negon Owe -e 1 I b--tse (2) Stsbilioation criteflabased o three most 10o-t t ortoeomufw oeOOufcment., (3) -Totl dra;-owd ' i.. -ll to be ke. td- 0 7 .(0-32 fIt) fort g rate to be 's, ece o-y to e or below tL 1 m (0,32 W (4) e/- 1fY,,*0 io.ilorftty is oser lb -J Site Name: jA Vi j Low-Flow Groundwater Sampling Form Wel ID= tV,, j 7 S, Date: /!,4VO 7 sam'ine P&rsnnel: C, .L,-, -l 1 n,,.r.4P' -.Alwkh,,'/k. J. Z).,'f/U Weather Conditions: %n/ PJ'--.Tacte: al. V File Name: /IotalDepth(I.D.): t2. S 63 92 Depth to Water (D.T.W) -n) iry, 7 1 Well Diameter: 3'1 Total Volume Purged: `* c2 q " Casing Tye: /IF-" Purge Rate: 2. ji *- Sampling Device: F~i,~k;/~Z Tubin Type: I-Measuin Point:- ~ c Pump Intake (ft below-M.P.): J, color- odor: g, n(7 Time: DTW: Comments: Temp SpC DO pH ORP Turb (-in) (feet) (TC) (uS/cm) (mg/L) std units mV NTLJ Stabalization (see note +/- +I- +/- +1- +I- +/-CriteriaZ below)' 3% 3% 10% 0.1 unit 10 mV 10%, 0:00 J-1f j &._ _ %g ,4 1 441 10:00 rL.ý1O X _15:00 143 ,,O ~Z 1i,3Z '1- X AL-1 25:00 ..ito7 "-,-7 Lt.7,,o.30:00 22./" 9,,0 LL7Z U ;. / A qzA1 _35:00 13 All Z4,LIMiAJ3I3.z 7.1 I7.16_________ -- -; ' 1~-0--~-0 0-t 00 I 45:00 50:00 55:00-.60:00 65:00 70:00 75:00 80:00 85:00 90:00 95:00 1M0.00 105:00 110:00 115MO 120:00 Sampling lime: i.J .14 1.Samples Collected: Analysis Requested: Preservative: Holding Time: Lab: 1-,' ' ...l ..ii , 1 .. .: * ./(... .-Notes: (3) -Do cot omeito r depth to bottoo of well ootil after purging and samopling to 1 rodeCsoopoadieg floe, that tay he rooog on the ro~l bottom (2) -StabliM UMc oflelt ba-ed Me three. met reeoet aoooeca tve M ttroMnts.(3)
- Total droedoto hI well to he toe the 52 1 (.325) Purging rote 0 be towo.d at ceoetry to kep dawdoon bo Dl -(532 ft).(4) 0/- 1O5 whoet'oihtlhy t oero 10 NTt~e 0 Site Name; b~j A. 4 eZ Low-flow Groundwater Sampling Form Well ID'. r'-1. .Date: / ýl 0/0 .Sa I- er~nehQýG--
0tArIr Ah 'n Al A~t ) g i V r- I I .9 =w 1--e 'Cy I.. v,..& ~ ~~~i.A ,l Timne: 1* 2-0 1'i6 File Name- 1A5 I .lotal Depth (I.D.): I Sreen tr 7n Depth to Water
- q. qq Well Diamete " Total Volume Purged: .. Casing Type;. (I'C Purge Rate: &'SmJn eie Tubirg Type: " .- Measuring Point: O -Pump Intake (ft beloWMl.'. )f color: I- ~- odor: (I., r Time: DTW: Comments:
Temp "SpC DO pH ORP Turb (min) (feet) (C) (uS/cm) (mg/L) std units mV NIU Stabalization (see note +/- +/- +/- +1- +/-C-"iteria' below~t 3% 3% 10% 0.1 untit 10 mV 10"/o 0:00 lq!:,4t j_?1.7 7-1. 1& 2115" q.*&., 7tIS -"21,.31 0, 5:00 1 qLt q4 ý;2_24 .?7,! -4,77-7,,A I ).OO I41q:ý" , q3 týl/ L4, NJ ~ q 42.-0 ..7.1,& --4/1,9 0. 65 15:00 I/ q04 .' ,.:1 /241 1 ,,i- 116-16 7. -, 013_20:00 /g5 -/ , -.k ) I-.52%Ls4oo it5- 4(ýIZ -2q Dd/u , M6~/. q7.' 3,172 -7, //-'-395 d,i a5:00 iz, 4q /*__ q0aO 7d,-r ,3 40.00 1j 42'~t~- ~ L4 45:00 1 41, Vtt --1 .12 t aMq P'A 1111 0 4 , 7 ,oT a o, z , 50.00 ,ý a6 & 3 Z --'Z , 55 ,0,.7o:.00. ',, IM& :5, ., a~T 9 ,-4V .a7, -Y.O i a .60:00 Z, W . g -- f.7&7195K:00 -~-~57~ .h~-Z 07 75:00 p .2O-.'/ r. ;o.St (9 %i0 7.o -&726,5M.80:.O0 1~.411 4 &'ad 3 -L/, a -410 .7,1 PLO 1 8o5:o00 -q, 0, 1' 6 I a -. , Y3 / 706 .-AU. 0.C, 1 1 920:00 q7 J c- /0 AL." -Z .. ' / --7. .3 Samples Collected: Analysis Requested: Preservative: Holding lime: Lab:-L -,619 7.06u, o 9: 0 -7 o ..N , 407,0:..:,.,;....:. .-.! _ ..: ..: : ..... ... ....;. .: Notes:{1) not noosote depth to hoeoor of .e.U ..61 alter prgiong and to rednoe Meoperufdng that may be on he ,11 boothot (2)- Stabohnk ro=ltrlo based on thre mott re Cent 0 o tofi eroeent.(3) Totol drootoonro 0 well to ho leo thon 0.1 0(.32 Ii) Porgiop to lobe loseered 00 tetary to kep do n below 0 in (0n2 tm)(4) T/- 10% when torbidity
- i. oor 10 NTUs.
ýsite Name: tA. s -~Lovw-llow Groundwater Sampling Form WellID: J1 t.,-IST Date: O Oitdt47 Sampling Personnel: C1,L1W 5:-7M A1. D.Weather Conditions: Time: File Name:. jD66 I j" IOtal Depth (1.D.): Screen Length.Depth to Water (D.T.W): Well Diameter.Total Volume Purged: f._ 4"- .# Casing Type: Purge Rate: I Sas n Device: Tubing Type: Measuring Point Pump Intake (ft below YP.): color: odor: Time: DTW: Comments: Temp SpC DO pH ORP Turb (main) (feet) ICM) (uS/cm) (mg/L) std units mV NTU Stabalization (see note +I- +1- +1- +/- +I- ÷/-Criteria 3 below)? 3% 3% 10% 0.1 unit 10 mV 10%0:00 11. a ALZ .~ %O ,'*- T0V :4f &2 5:00,, rs .id31 q' j,, #q 7l,6'1 O,tff 15:00 a a 20:00 25:00 30:00 35:00 40:00 45:00 55.00-60:00 65:00 70:00 75:00 80:00 85:00 90:00 95:00 100:00 105:00 110:00 115:00 120:00 Samplfing lime: Z ,j (~Samples Collected: Analysis Requested: Preservative: Holding lime: Lab: Notes: () -D.o -d~lloo epth 0boto WW oi -.0e end)f obePnobg -d -lxg tord-o -peoding boos th1 -7eob onestti.S. the weft bojto_(2) -5mbillotinot aitoeri boed con kIeen moot emot cooweneodo mooe-menl (3 -Toed datd. Loo n woell to be I los, 03o I.)o (0.32 %I P-gio 5 atelo lbe lowred wo nnontooy to keep drosedowo below D I m 0.32 ft). Site Name; rojnwae S)mJpin Fo Low-Flow Groundwater Sampling Form Well ID.- MI i I --I .Dlate:_ l,,\- 0 Date.-oIQ 1 0 1, Sampling-Personnel:
- f. I ay Ma~~rLt &C~(l ~cz... .O ~ 10 W Co.-Kx Weather Conditions:
" Time: 1. _ /.oy -Z File Name:- 67 f):;Iotal Depth (I.D.): Screen Length: 3,21 Depth to Water (D.T.W): o4 , gi Well Diameter: " Total Volume Purged: a. -C/ Casing Type: .Purge Rate: m91XIiIGf~~. Sampling Device: j ttLC0 W6 Tubng Type- ý4t-Qý Measurin Point: -o0- v, Pump Intake (ft below M.P.):' color. odor: I' *Time: DTW: Com.ments: Temp SpC DO pH ORP Turb (main) (feet) ('. (uS/cmr) (mg/L) std units mV NTU Stabalizafion (see note +1 +/- +1- +/- +/- +/-Cditeda' below)' 3% 3% 10% 0.1 unit 10 mV 10%, o0:00 R031 ,g, 5k --. 1-7fl 1,.,.-LI, 5:00 11.31 ,2 /I,7 A1-' .bf 7,1R -3YZ,,V 10:00 iq,31 137 A.95.. 1/7* *1PI,// 7,/f 15:00o Iti 3,,ny 1 Aej.A7 ,Yl 1~,,7 *7,11-3,? ,g 20-00 -315 0_10.25:00 ',3W "_ .0.-t3' 1 77, I .-3/,4 d, 35--00 i, * ,"/ 7g. i7230. l~ 2 7-,/ 1, , 40 i I- 30,3 ,A 45:00.iof&1 !;71 .I/, /I oIl 55:00 -....60-.00 65:00 70:00O 75:00 80:00 85:00 90.00 95:00 100:00 105:00 110:00 115:00 120:00 " Sampling lime: i/ O' (44ýSamples Collected: Analysis Requested: Preservative: Holding lime: Lab:-11 M~TIWV,~ &4PA.4AA A[0)-::i :- ., -r":i " -* ...e -:.. .- A 4, i .-.....-'V:.A , : .:'(1): Do Wst _oo~ dopth W botomo of well uni fer pugn aod aaopladi, to reduce re-edn finer, that inabe ,,kng on Ow -eoll heotoo (2)- StabiWolion aiterio batod won threoOSt rooeet ooeonseutb ,o04,roewoi (3)-. Total d""down in well tobe Imftho0 1 to (032 ft) Purgfotramt beltoweredcooo o o0keep jd or Ieohi .1 .o(03 2 ft).(4) -.1- 10% when toibidity is orer 10 NTU,. Site Name: h x k 1 klsr e-Low-Flow Groundwater Sampling Form Well HD. M'L -,10 -..Date: O0- ( " 01. P Sampling Personnel: gC,',. et , a 0,C54 A r ,l A%Weather Conditions:. 3 " -U tý K S Time: 00' / V .1io ,- /0/4/File Name: IotalDepth (I.D.): qCj Screen Length: "70 Depth to Water (D.T.W): " .34o -Well Diameter: I " Total VolumePurged: -.,.v 6Xt,," Casing Type: fVC, Purge Rate: ,-7 I t, Sampling Device: Pe'ar Tubing Type: f-- 4 P 4 le.Ae_ Measuring Point 'T,' f 0. 2 i , .Pump Intake (ft below R.P.): -1 o i color: 4f ej_4j odor: /I...a.Time: DTW: Comments: Temp SpC DO pH ORP Turb (rain) (feet) (t) (uS/cm) (mg/L) std units mV NTU Stabalization (see note +/- +4- +/- +/- +-/ +/-C-iteria below)' 3% 3% 10% 0.1 unit 10 mV 10%, 0:00 iT 7-7 6, 0 li .~26 q1 4,3 )... W~2 is- ."-5:00 Alqa, y A" &4t AL .,7 l -,7 7.2. 7d-/ & 2, /Zw, 10:00 j -, ;7 /6A4L/ _____3_/_3 15:00 "./ 7, -N V;5- A[20:00 1P ,W-10-A i1,11_ 3l A" 4 , 7,2 2/,* /A/I 25:00 .,Z.Z, ti,.1 LIZ 7Z._,27 fll.55:00 14- 23 Xdl, ._IiJ t-1j, IL 7,274, 4 70, 059-40:oo00 M.o/ .-:v 164,o 2, 7,,-2 99 ,i A, 6.60:00 /-3 7 /1), -6s~ ~ ~ WS I&%3 1Vo/ f/,. -/ ,&A"' :W;f JZI Z2,_5:o00 7"j .'_ ;,22 4,L Z,2 -. , _. .70:00 J41-1 ,4 -IOQ Y-.. I,: ,b~ --'7r-;.n c. ~;]'r) A 70.f/* ,X i .9 ')Y 7._1 4? /41 n, Wid'll qMA, 80:00 -85:00 90:00 [95:00 100:00 105:00 110:00 _115:00 120:00 Sampling I ime:/)5-' s 0 Samples Collected: Analysis Requested: Preservative: Holding Iime: Lab: Notes: (1)- Do not mea-rse depth obomr of wool w ounl alter parging anr .aropliog to red-ce muspendiag fiees that maybe restgon the well bottom.(2) -Stbifiwation criteria baed on three mot recent consecutive rroasmutents. (3) -- Total dowdotn at waefl to ho let thaai 0.1 an [.33 [, Par-ging late to be lowered as r'-oeary to keep ll. to (032 ft). 0 Site Name- 3) DO06~Low-Flow Gro-undwater Sampling Form well ED- M~A -ýDate:lo Irudae I apln For Saxnn~lne Pei'sonn~1: C1. /V e.~ 6IM A&,yUfit.1iOei. J" -), HetyIrf5 Weather Conditions: -1~A Z-J4' fS~J/AAi Time,,,,: iO' ,7 ? ...F?7e Name:.f IotalDepth(.D. Screen gt" -2o .Depth to Water (D.T.W): 13. ' Well Diameter: .Y" Total Volume Purged: ' .... ,Ca Type: A C.Pump Intake (ft beldiv Mhl.): color: odor: Time: DTW: Comments: Temp SpC DO pH ORP Turb (man) (feet) (CC) (uS/cm) (mg/L) std units mV NTU Stabalization (see note +/- +/.- +/- +1- +/- +!- below)' 3% 3% 10% 0.1 unit 10 mV 3D%'5:00 a-),. i 2 .2,1,7 7, 10:00 0I, W/4 2Qa-4. I/ 41 IV it 15:00 7A , q [Y O ;d/ .* -/..1[,73 2 , 2._Z. 7,0/1 -Z I-3-1 ,4- ,2 20-00 o 3 -. */b IH.'s 1 j3 Z .,o L 7,?, iL,42 .21 30:00 3.@ /¢,/,+ * :Q* i.3q7 1.o9 %L 35:00 13,_ ., 13+73 " 7-10" I,7 ,2 45:00 40:00 70 7 .L1 7 P 50:00 1 2 A /,ie 7 U L6ZZ 155:00. .6 4 7, 1h4' I 60:00 rl 01 ., j40 7,.~' e j 05:00 1* Y 7ýZ 2-'& 6~ 1.5 %,0 144 75:00 FA I/& Q IIAX 7,07 3' 1113 80:00 85:00 90:00 *95:00 _____ ___ ___100:00 _________________ 105:00 _____ ___________ ___ ___115:00 ________ ___ ___ ___ ___Samipling Time:j).O Samples Collected: Analysis Requested: Preservative: Holding Time: Lab:/1 k -' "7 ' -m: ...."e :::" ..." " " " .,:':'Notes.(2) -Denot rreý,ee e dtrpe). ole... wall -.bteiler p-0,g- d sampling ma .d-~ noepandiig fewiloC eo.y-be ef~i,,ee C).. well bcw., (2) -Stafliýdon crileel basdmn thnn, moet rewe,, -we.le Ov easme-ements. (3)- Tom) derowdeý in well to be lee Os. 0.1 m, (0 32 1) P'agieg raeO m be lowered as neseswy Co kseep deasedose below Q Ie n;a032 fC)(4) +./. 10% when nnbibdity tsowee 10 NTis. Site Name: PJRVLI L2 &6 Low-Flow Groundwater Sampling Form Wellif): .130 Date: ,D SaMplingfPesonýneL .r Weather Conditions: AlM Time: i q14- 0 FileName: 0jJ_ C JS I otal Depth (I.D.): 4-31)3' /cer egI Depth to Water (D.T.W): ( -- Well Diameter: .3 -, Total Volume Purged: ¢ Casing Type- P Purge Rate: I4p t 01% k J Sampling Device: Tubing Te: Measuring Point Pump Intake (ft belovV M.P.>/ go color: odor: Time: DTW: Comments: Temp SpC DO pH ORP Turb (rain) (feet) ,(QC) (uS/cm (mg/L) stcd udits mV NTU Stabalization (see note +I- +/- +I- +I. +I- +/-Criteria 3 below)ý' 3% 3% 10% 0.1 umit 10 mV 10%, 0:00 -,4 4 -.5:00 =,T K 15:00 Z.7- PLV~rAe- f, J?5 ý&Z? -4, j~ el2 -7,4 20:oo z744. " :. -,a,/ X,4,. ,-,.30:00 NAM:~- a?, ;1-90 6&77~O __ _35:00 1 1/ fl 0 ,x 9-11Y -7 '( 4 A 6 40:00 / I V Aa77 Z 7,Z2 , , IIIoo "I. E2- /2r3 -I.#5 5 , -7,7z-2-.15,f! 01.7#55.00. 7,24205 60:00 H.9L -~7,.20 -20 1/ 4),A0 70:00/4U. i72.1,:92- 17 /41- & 4 -~ --~ 4-~ 4- 4+/-~ 4~' .1. ...~L 4- ~ I 75:00 r -r -~ -t--1 4 4- 4 80:00-- r t f-------4--f 85:00 I t + 4 4 0 4 4 90:00-I -I----*----- 4-.----.---4 -4 I. 4 4 95:00+ + -I- S L~L ______ I _____100:00 105:00 110:00 115:00 120:00 Sampling Time: -" 15 I 5 Samples Collected: Analysis Requested: Preservative: Holding Iime: Lab: mfXot 1(h~ O 1rW TiCAvof 6,evA k1eWf' -I Notes (1) -0Do noit depth tohbotto of wee tetll .fte, purging e atphngse redtee re F."pendig firesthat -aybe e.rtotg on the " 11 bolom (2) -Sabiliatinr criteria baed on three nost recent -nutve -ieanrements. (3)- Totald-d-o in melt to be heen thn (.11 e (0,32f t Peepie rat to 1- 1r-de,e on nee e-1ry to keep dmwdoen beow L I .(0.32 it)(4)./- 10.Mnmhe-rbidityis, IoNtr 1 Site Name: ~s 6esSe-Low-Flow Groundwater Sampling Form Well ID- (At1l3) -3107 Date: 10 -"1 , .Sa-xnp.hK Personnel: h-g .o" , t MmL(Aekiy Weather Conditions: £w 4' t .),-ods ,o-,I N' Time: AF -3/File Name: 3Dd I'otalDepth(l.D.): 1 *4 I ScreenLengtfr: 10'Depth to Water (D.T.W):/ ~"?-A Wel Diameter 3 Total Volume Purged: , 'aA Casing Type: V/ L PurgeRate: .2 tSampling Device: f ertc-m6ti-ýc. _ &12 T ;Type: i -,Measurn Point "[e ct 9V "C P p!L Intak -e (ftb eok, UP ): -1 0 colo r. d /AOI_¢, odor:. '. n Time: DTW: Comments: Temp SpC DO pH ORP Turb (min) (feet) __C) (uS/n) (m,/L) std units mV NTU Stabalizalion (see note +1- +1- +1- +1- +1- +il-Cri~tria' 3% 3% 10% 0.1 unit 10 my 10%4 0:00 ' )_ , 1 9 .. ..7 j'-cO 16q .qO &W 4'7, i,0 200 S. 6L,5 -,:. 0 7]25:00 Ot, b,094, '1-*b&" .& .3¢SPm L 30:00 OlJf%% 1% 3Uit 0 1%35:00.60:00 is. 9 A 65:00 2 17 34 &NO #7&000 55:00 ___10:00 ______A_3 65:00 16,061 70:00 _ __75:00 _______85:00 P*__ It____30:00 00:00 70 Vc/IR.Samples Collected: Analysis Requested: Preservative: Holding lime: Lab: 450 .0 66 SAM.Noles: (1) -Donot meaue~ depth Io boamm of~o re nt~il a/ke ad sampling le redue Irees tht ea7be 6-eg an dhe well bo~tem.(2) -Su~bilization criteria hated on three riost recent conecuve rgea-nrmerr s.(3) -Tohl ddondown wel c.(05225) Pre~g at ekeedyan=aymkeepd d-eweowbelowS n t O (4)! v0'twhn tubidity is oser 10 NTUu 0 Site N~ame'- -ýAI I ow-flow Groundwzter Sampling Fonn Well ID: M( J, 3 1 .S, Date: o 150-7-Sampling Per§onnerl: 41 .a _ " Weather Codtos N, Time- -/File Name; .Z>A4!1, Iotal Depth (I.D.): Screen Length: 33 Depth to Water (D.T.W): O1 [ 1 1 Well Diamete: Total Volume Purged: 4, Z Casing Tye: Pvc Purge Rate: Samplinp Device: fe, t C 4,,o Tubing Type: go q ": n e .Measuring Point: "C o PC.Pump Intake (ft below M.P.): color:, odor: Time: DTW: Comments: Temp SpC DO pH ORP Turb (mmn) (feet) ..... (°C) (uS/cm) (mg/L) std units mV NIU Stabalisation (see note +1- +f. +/- +/- +/- +/-Criteria' belowp 3% 3% 10% 0.1 unit 10 mV 10%, 0:00 /5- 0, .&0 ta l0W) -441S,2 .2290 A ,W -716 -)., //,.D 10:00 '22A9~ 2 J ?R9 7 /-A,41-20:oo 40, g Lq ;'fJ .fa .l /0 = 9 3-,(4 74. ' -la 10 .Q 25:00 i',07 :2I_5 / n, -9.02. 7./Y 8,4-g 30:00 &4 o 7 __.__,g_4,- .' ,YY,¢. /W7 4.Y7 -7.11d -3 40 , ,3 , 6d 35:00 J '.T 7 zg /.- ,.l /40:00 0 50:00 I5,iD7 Jpf -A&5 ____'-.1f /,?10 & Q 55:00 0 nI37 / ,9 i9 60:00 i~al AF v- Q 7 ,f 7 75:00 1 _ 1_70:00 80:00 ____ __________ 85:00 90:00 " __95:00 _____ _________100:00 ________________ 105:00 ____ ___110:00 115:00- ___120:00 -___Sa ln ilm 331/ --/./Samples Collected: Analysis Requested: Preservative: Holding lime: Lab: Notes: (I) -Dote eeroe ea~rlepth to bottorr Until ,r orerduce ni ts-armry restieg (2)-- S1obiliznlknn eriterto booed not three moot recent consecut.ve emeasremeenet, (3) .- Todrorwdo.- ie -elt .o be I- It 1. (0.32 ft) Ptreg ramt. to he lowered Is uet ese ry to keep dor -doee bhlow 0 1 m (032 ft)(1) +/- Ott, whoc- turbidity is o-er 1W MN Site Name: j [A -J Low-Flow Groundwater Sampling Form wen HI Ik) td AI Date: 10g/-amliny _ersori-nel: E,~ P. MIWdCJ k .(i Weather Conditions: Time: 0 IR-:- a File Name: ,6-;3"n IoWa Depth (I.D.): 6 1 p4(,A Screen Length: 7/&Dpth toWae DTW:Wl imt: Total Volume Purged: / Casing T Purgee Rate: L-w,--_' .SamplingDevice: c ,.Si hc. pu-~'nP TubingType: poly eAh.Vlen-' Measurin Point- N." Pump Intake (ft 6elonM.P.): o7/' color: U odor:.' ,y Time: DTW: Comments: Temp SpC DO pH ORP Turb (WinL (feet) (*C) (uS/cn) (mg/L) std units mV NTLJ Stabalization (see note +/- +I- +1- +/- +/- +/-Criteria' below)' 3% 3% 10% 0.1 unit 10 mV 10%, 0:00 11 Z .-ý wx-; gagL A___1.5 5:00 /, -/ .10:00 156 14-7 419/, .,07._la_-_ V Y 15:00 1 r i 20:00 /-?,D-? 70 -il,, -7 25:00 7, .2 ,1// Q 7. 07 -319,.5 d. A-i 45:00 55:00 ___55-WO.-60:-00 65:00 70:00 ___ __________ 75:00 80-00 ____ __________ _85:00 90-00 95:00 100:00 105:00 110:00 115:00 120:00 Sampling lime: -69'/7 Samples Collected: Analysis Requested: Preservative: Holding lime: Lab: Notes: (I)- Donoto-ea.ere depth botm of we] uIe l ug r pae- .ad -opling to reedee , dendigfn es th,, be = eyIngeo .e -11 bottom (3)- Total deewdown well to Se lens de 01 n 532 It). Peg rate to be Inwornd as noee y to keep deoawdoee, bela 0s1 e (0o12 01r t (4) ÷1--10. then tubldityOi over 10 NTl~s. Site Ntnsc Vawls- 9?!r L ow-Flow Groundwater Sampling Form WeHl ID M '" Date: /1 ,5 0.77 Sampling Personniel C. 'arOe Weather Conditions: a,-trfwu5 aUn V-1 0-1 Time: ORD -; 9ý File Nane.: -3 3e, rowa Depth (1,.D): Sc-2.3p'Scr
- --0:2 Depth to Watex (D.T.W): o) /q( , Well Diameter.
C 3-4 Tbtal Volume Purged- Casing Type: Tubin.- Type: P .Measuring. Poin .PumpE Intake (ft below ..5_;, color: 14 odor. Time: DTW: Comments: Temp SpC DO pH, ORP Turb (min) (feet) _ (C) (uS/ca (mg/L) std units mV NIU Stabalization (see note 4-I- +1. +1.. +1- +1 -Criteria! 3% .3% *. unit 10mV 10%V.5:00 ,. -7. , A,7q-- 71i 9o , 10:00 0?I/ M11,.zA a d1 a4, 5 7,% A ?-2z _ ,-7.15:00_ _ -rs 451 ý" a%7,2- 71F ., 7, 10" amls Coo.lectd: Analsi.s Preservativ Hold 7,g lim e: Lab: 20:00 -3,q eero .,I/c, c,,5co -8e,60 7, /'t 1X " d,7bc217* ,oboI~jn, 5q o'(D2 -eneb lo-ndSS,e ,s .po kepdedee _bleo'5 ( 25:00 A 70:00. A5 21;?-W#96003 7.5:00 1,6 4 qftlmvtn 40:00 )1,0 aGk A.(A3%4.070
- 70,V 485:00 i nR 7v_-74 W7 50:00 -7,04 955:00 1 3 160:00 165:00 110:00 115:00 120:00 sa9in 05 100-C.00 e: .navi eqetd reevtve odn !m: Lb 105eS:0 Sam le Co.h l, l ec*' o,6xted:n ree nalr ercaulested:
Prsraie"o iglm .Lb f } 1 Il } llW¢IIlt b hl Im 03 f}Purpng 1.1k 1. N, Ioweed 1- e1-~ay 1. keep &dta eoW-0. I. (D.32 III[I -* -Z "Owl~1I ~~iy our] 0 TSiteNme: ]BEZ 1.l ow-Flow Groundwater Sampling Form ToawDet Scre.f5" '7'P ate: " IM O .S De Wthe: CondtioW: C7s To eCf , DO p S;;r Totl h( i.D):/# Seff h: 70 Depth to Watex (D.T.W): *Well Diametet: 'Tota Volume Purged: a 3 Casing Type- T-bing Type: ._ ,,Measuring-roit 7 .-F O v*c-_P um p I n (ta k h p~ o u M .P .T 7 0 ' c l o : ( I J ,A , o do r : Tun~e: DTW: Comments: Temp spC DO PH ORP Turb (rin) (feet) (C) (uS/cm) (mg/L) 'std units mV NIU Stabalization (see note +/- +/- +1- +/- +1- +/-Critexia" below)' 3% 3% 10% 0.1 unit 10 mV 10%'0:00 1__73 &.?-7 &AX , 5:00 1 17~ p$J~ ____nLIt~ 19 M 10:00 11179 j aO MGD 4 1.7 a.0 f , 15:00 i / Z jq,-7 s:; IVx4.__ o 20:oo 0 , 7q -t laOrD yUhi4. A 5, O T,7 6,5 25:00 V.1 -7 9_ aq__7 ,:,Zo0.3 o :o o0,0 P 7, i -T t Yk .MI %3 , I O N _5 & 6 k ; L ý3 0 , L % 4 3- 5 ,_6 6: , 7 7 35:00 L1 O 4,37 65,09 q4 40:00 LLL QO IV-I 45:00 ' 7 k 50:00 J6? jj O ?
- 4 5500:00& _ _60:00 ~I 65:00 70:00 75:00 80:00 ......_ _ " __85:00 _______ ___ __ _90.00 ____ ___ __95:00 ____ _________
___ ___ _____100:00 ____ _ __,105:00 ____ _ __110:00 _____ ___115:00 ____ __________ ___120:00 7____ _____s~ a p lin Ti m e ,, / 1 .3 3 Samples Collected: Analysis Requested: Preservative: Holding lime: Lab: Notes: fl) Do not oseosur deps0 to bo1on of wenl u-til 0t1er ptogng -od sampling to reduce htnnnrnending lie s th atee t es ting on to welt bottona (2)- Stabilibooslo crterla baoed on tiree moa re-et coenecutive mennumemelts. P3)l--tott-dra-down in ýt tbet e thn D 5.2 m (0 32 1t). Purging rtte Iolv lowered --7 tokepdrawdown bewaj]m(037 f.)(4) -Of 3W.V when trhbidity is o-r, I0tim )re "n" t p r o f Site Name: {T/4iJ A 4X6S L ow-Flow Groundwater Sampling Form Well ID: Yhi1'I Date: I 1 4e1e) Sa. h : SampingT Pe~nel: Mau on: Weather Conclitonsf & Time: D" W: C nT p " pT ToW Scee Length: .)Depth toWater (-.T,W): ( u)/c),tsm Well DiameteV.U STotalaVolume Purged .. Casing 1 ype: -.. ..Purge Rate: Sampling Device: 1 TtbinTye " ... .." MeasaEh&gPoint: n-+X ID: JbibkA YVlC--Pu~plna~k~ftelo~qMF* ..z- coor odr ....Time: DTW.- Comments: Temp SpC .DO Turb" .(rai) (feet), MI -° ( uB/on) Crag/L) std.units mV Stabalization '(see note +/- +1- , 4 .+1- +l Criteria' below), 3% 3% 10% 0.1 unit 1 mV 'i0%0o:00 &1 /. 9 .'7.¢ 1Y15,rV.L_ ./.1,60a !,1 ,,-l514 .q 5;00 1 74 , 0 10:00 7Z1 8 15:00 P1'.911-?, A2 .-,,7 7,,Q z, 20:00 7,' 7A0 540 ? /f__9_ no-W I7~q ~ 7.o 0 30:00 0L, /), .277/ A ,, /Q " 7,('t 35:00 I'?- A/ 2 Q6 3, Ar 7,;?, -2,,q 0 40:00 JL2 7y0t/;t, /gAl 2 7+,;..- 11,11/ A/z 45:00 50-00 A -~xm ~q 7 -Y0?d 60:00 65:00 ___ ____ _____ _75:00 80:00 85:00 90:00 95:00 100:00 105:00 110:00 115:00 120:00 ____ _______ __Sampling Iime: /)0- 12 /0)..Samples Collected: Analysis Requested: Preservative: Holding Time: Lab:.flcJ-L "; _ ._ *___. .Notes: (1)- DO -ot &easoe depth to bottom olsM aetu-l alter purgieg snd sanplitg to redost tersupetding fties trat mty be cee~ingeo the weet bottot (2) -Sta-bladon criterlo based on three most re-e-t co- 6-etive m--efubents. (3) Total drowdoe a mell be lest t 51 m (052 I) Ptgiei tale to be lowered S necesr, to keep drwddon below Tt 7m (0.32 it)(4) --I" tlt oc hee turbidity ti oce- 10 0Jrth - 0 Site Name: DA'JLA !S'_9 Low-Row Groundwater Sampling Form Well 11): MU/ Da -to / Wae .... W Sauping TPerote: AMA Mauin ont Weather Contons: .L 4-It' -7 c2 l , d- o.Time: D Comments: T C ." File Name D. .@., ..'/..Total izpth (TsDe) , , Sre +1- ' , _ + .+ 1 CD.epthto. Wate(DT.W): 3Well Diamete% :R % 0. ..Total Volume Purged: ."Casing Type, A , Purge Rabe: 1^-7 A L/.J 4 ,- Sampling Device:,- lpe,^,. 1 _-fj{Tubing Type: ]g,/ /L-Measuring Point:"TQ, ' 00mp Intake (ftbeoVM.P.)_,6"- color.. odor. ..Time: DTW: Comments: Temp SpC DO P.H" ORP Turb(feet) "("Q) (uSlq. (m) /L tstd untits mV NTFU Stabalization (see note +- +- +- +- .1 /Criteria below)" 3% i 3% 10% .0.1 ..uit u0 mv 1°0:00 4, 7,12, .6V 15:00 ___ f M. 9ý/ 7&?*. k1A --4 g 15:00 A32 fO~ 7t,0i2, e6.3 j. z 3000 I -i70 , ., /777. I02ý &ý 0 /" 3500o /d g7 ',. 47, ./.gg3 A, 40.00* .E-I~,_.7, 45.00 1"0 -1i.3. 1~,7j -( I,. Ii7-gg /), 60.00 eR:3.Zq i.70 7.2 i 7Vi0 7 L',A'65:00 7 a" 4 75:00 7S- 20MIS 7.03 80-00 1079& h d7 &Y1 &815.00 _ Qz 520:00 10 -it)______I ______'7 07 , 7t72. & 1,#-Samples Collected: Analys7is Requested: Preservative: Holding Tme: Lab: 65:0 -139 170. ~iV&AZAz~-i.2-, ,f1n,,04 85i:00 43. W7 ,-11f ,i7 I... 5 1,V "1 5 9:0. ...... ... ,. pl f L 70. -7.. .. ..* :!::. ., .. :. .... -,e .0 0 ....NDtes, (- Do net meas- depth 0o bottom~ of wellutld after purging and sampling to oeduce re- pending ti-~ tht maybe-ig the(05. woeoll bottomw (-I) Setbibzolion criterH. b-sd on three woo roconlcoo- .6-e noseoorcNns. -(3)-_ To",tdeoldwn me well to he 1010 t10n 0.1 w (0.32 hIj Purging at to01 be le-ered 00 0 C000m 0 hoo drenoel belýow 0.1 an (032 R)((4) /IOP305when turbidity is odr 10hffllo. Site Name-: Iwa'\r S l Ferm 1Low-Flow Grou n-doater Sampling Form Date: j 0 --. -0 a Sampling Personnel: ,-p., O I f N\T Y Weather Conditions: /,,t/.' , 4/ /s File Name: /J RA 3 7.Total
- 4. .- .? '" Depth to Water (D.T.W): C-~1. Well Diameter.
~Total Volume Purged:...5 .i. Casing Type: t"//C PurgeRate: -240^47 Sampling Device: Tubing Type: 1-14 a .Measurig Point: to~ I j-P/rl.Pump Intake (ft beIK,IvLP.Y. / color: or-:11Ukr
- 'AD/l Time: DTW: Comments:
Temp SpC DO pH ORP Turb (min) (feet) (Q) (uS/cm) (mrg/L) std units mV Nru Stabalization (see note +/- +/- +/- +/- +/- +]-Criteeia, below)' 3% 3% 10% 0.1 unit 10 mV 30%'5:00 _ATa w9 t7 ,0 20:00 '-. Xi).a aa35 2,30 z,.ao -16. ,. A 25:00 0,3j& .l , 7;U-& --/',9 z'&30:00 "1,i, -I, /5 O 24 37 T, 7-.410;1 35:00 .I -I / 0 /Yu i,7t .5 7,z.127 A Z5a 45:00 q[J 4,1 i* I'. q& /, 50:00 TiI .RUT /5,2. L 25~ -4 JL.2 .1A 55-00-- !r2 a-a,65L a- , 3iY, '7,3,2 -/7Z h I, 60:00 2 ' .- ,/.,, 65:00 -IMi ..tYYA'u -/? I .a,0 ,91 7,Iq.-/,17, /,. '2.z 70:00 -,XI4 /t d4~1 _2S__/5 __ 74.75:00 13 Jo23,7 -7 3 /9V., C W,, Y&90:00 ' I-.. /no.40 95:00 100:00 105:00 110:00 115:00 __________________ 120:00 " *_______________ Sampling lime: /v?29 L7 9'Samples Collected: Analysis Requested: Preservative: Holding Fime: Lab: Notes: (1) 00 Do not~0 dopi ro b ofs, 0 r -61 aft"~ pis'ng .d ý.5pinsg Iv redO -s 'pe"'"d io Io- l tht y b ist oOgs .. th -i b. ft.-(2) -S .ubwos, crilosi booed -o Ih-s wo -t00 --ti-, oanms (3) _ 7ouIdrsdoss' ita o e loe- 0-s 0s.1 .(132 ft) Poo&og teto ocloiwed 7 tsyo k~ej, d-~dosbel-a fI .() 32 f)(4) -.1- Kr. h" rbidjty is so., 10 NMl&s 6 Site Name: "AO) _5 Low-Flow Groundwater Sampling Form WellJID: MY 1Ii.Date: Weather Conditions: 7170 aSWiAtl -3a Time: j -)_- U File Name: iOO/q Total Depth (I.D.): 2,. cr in : -2 Depth to Water (D.T.W): 1 ,q, ( 1-, Well Diameter ý3 Total Volume Purged: , j Casing Type: PVC.Furge Rate: 9.MlldtSampling Device: Tubing Type: Pc-L Measuring Point: -7 b I' DA"V'C..Pump Intake (ftbelowWA.P.): _ color: & odor: V 'jj.!Time: DTW: Comments: Temp SpC DO pH ORP Turb (min) (feet) (0 C) (uS/cm) (mo/L) std units mV NTU Stabalization (see note +1- +/- +1- +I- +I- +1-Criteria 4 below)' 3% 3% 10% 0.1 unit 10 mV 10%, O:O0 ~ ~ _ 97 5-43fq, 7 W " 5:00 i/A Q.i IC 1 ktch, .7a533,6=10:00C 15:00 ,a 3 1nk 3v"/ --4 , S 1, 30:00..U3/ 25:00 ,L16.9 3035 .o,,S ý7.00 -00I 0 -130 7 35:00 w 0, ..I ,7 50:00 .. L _3 /.7 Y7,( 75,67 60:00 /3,; 10 j/d.l1' 3,8 7,O. a-a2, V, Il?65:00 Ia, 11 -29Z ,2t .,qI__ 7- " 7.06D -/2,9 býq 70:00 i ? k/ l 1.7 c 0 4 , 771, L -a,5 , e.75:00 acz 242 bV101, 165 AV57 A-01 '7. -1,,4A -7&80:00 J91 j.?/t9 /, iS/& i1 ý2!7k 2 aAo " ea -2,1.5 85:00 2,1_ _7 7, 17,i~ 0. jjq 95:00 __,__ 7/--17,30,'Y 100:00 '_ -/ .t_ _105:00 110:00 115:00 120:00 i,3m.3 "- i(t.)Samples CoUected: Analysis Requested: Preservative: Holding lime: Lab: ma.\L i 00A i -Ti &N6im tmAJ Note.(I) -Do tot masure depth Mo bonoe of welf ont1 a fier poglg aod sapu pigig to r-ede tr ,nsperding Irt. that ay be rrestig on well buotton Q) -StabilIzation criteria baed on three -oo teeet co-set tive c,rnesoeoets. (3)-Total drawdo-w inwell to be teo than 01w (032 fI) Porging rate to be lowered as neoeoary to keep dsowdowo below 0 1 m (032 t}(4) +/- 10% when torbidity is -'er 10 NTI~s Site Name: L)t, i S P-0 ow-]low Groundwater Sampling Form WlIDat: 24IV Sampling Personnel: (.,I-, .k,¶ fl]zrieN"i /L- ,1. k--p_/ec.- Weather Conditions: '2'-e ' I Tihne: ![2 -File Name. 4 1otal Depth (I.D.): 9Y. 7,qj SCf9*iSrth:3. Depth to Water (D.TW): Well Diameter: -!Total Volume Purged: , Casing Type: f./.ITubiri;fype: qJ/a4/ .-- Meas-urin~g Point: %'.# p FPu~m Intake (ft beloNv M.P.): " color-Time: IDTW: 'Comnments: Temp ISpC' DO pH ;ORP Turb (rrin) (feet) ('C) (uS/cm) (mg/L) stdwmnits rmV NIU Stabalization (see note +(- +/- +1- +I- -.Criteria' below)' 3% 3% 10% 0.1 uanit 10 mV 10%4 0o:00 Id. t- n -/~ "¢ ¢1 16,Y'/ 7, /__5 :00 J23 4 o213oQ 703 2:, 1'i -7, ___Z S 15:00 zl- ey 3_5_5 9 L i f -/ V ol e 1 0 :0 0 , ,. 4a- 7 6 1 7 5 , 1 0 ., -1 , 15:00 iJ9 - -- 0 7[ M , & , i/4 -4a/ L.2 7 ,i 20.00 i,.2 -.A 73" A L-eJ,14 ,q 7 -rd 7 17, / 4.6, 0-5'25:00 c 0 YI 77 6g0 30-.00 Jillilv~ ,?. /aDa 7 ni 35:00 0 JA 4 ma~sz. 1 /-9 -aa 40:00 50:00 112, V15 t_1___1 5355in li: e 0 ~ L 0- 13107/)S 00:rm 105:00 110:0 0 115:00 100:00 Sampling lime: /Z Samnples Collected: Analysis Requested: Preservative: Holding lime: Lab: 1>, k , .~,-.-w A :l .5~4Pe~Notes.I1I -Do 2ot t.onre depth a to bo"o o.e -nat.6 after prgiteg and ssaplirg to -spdiog Ia th -t -y be r-tig -n the we2 bottoa" (2)- Stabiliati.on criteria based on three roost reoent cosecutive measurements
- 0) .-Total drawdown in worl to be ess t1hn 0 1'm (0.32 ft). Purging behloered as ee- ary to keep drawdoe beeow 0 1 m(a.32 (t)M() ./- IM0. whe. torhidity it o.r- 10 INFtU, 6 Site Name: "]7,91/,.5
"'A$$L ow-F-low Grorndznater Sampling Form Well ID: i -C Date: -:?Samplin~ Personnel: A A RE<, -We ather Conditions: 7 I .,i .. / ,q4 Time: 6F7Y-3iD , /f~e File Name: D)A k/o...Total Depth (ID.): Sce-ngR 511,5 Depth to Water (D.T.W): () lz ? Well Diameter: a A Total Volume Purged: Casing Type: P2C,.Purge Rate: Sampling Device: XZ;k-.. _ 6 &'ee,'yZ, Tubing Type: ..V Measuring Point 0,0 F,'A1 ,,/ C Pump Intake (ft belowU.P.): , color: odbr: , Time: DTW: Comments: Temp SpC DO pH ORP Turb (mri) (feet) CC) (uS/cm) (..rg/L) std units mV NIU Stabalization (see note +/- +1- +/- +1- +/- +/-Criteria' below)' 3% 3% 10% 0.1 unit 10 mV 10%, 20:00 7,7/- ,.C 8 e/ -,'7, a I, 45:00 la.7k , I-Oz7 M 4 ..". gJY7 , 7 " 55:00 ia & .4t,4ý J.., A MI "-- .33, £,(15Mo 1,9,75 AN .. -,76ý 22,04l IF.qY '.-71 ya.-/1 .K; ,3Y 70:00 -76 q& i/r-'/ " Z Lz -34, , --3 95:00 I~ ~ R 1/~ '-7, ~ /i 15:00 ILL 6. f,. 46,A 9, ., V ,24 -, 10:00 a 2 ,7(- , t!,?I 910. W, 7312 4- ,3-g , 115:00 ____420:00 ______ --21 Sampling Time: / WA Samples Collected: Analysis Requested: Preservative: Holding. lime: Lab: Notes: .3 " " " (I) -Do not ceneu re depth ts battonc of te8 ntl soa etee purg~ig antI samepl 5 ing ett e~ue traesupendiog iene that ceay he g ontiso the wet)hll (2( .- Slabuislizion criter'ia b~a ed tcm three eost recent conseecutive ,neattt menntts.*(3) .*Total d raseooee in woll to be loes than 0 tto (0 32 it). Pursing r ate to he loicecedl tsneressary to keep cdrasedoon below 0Otto (0.32 It)*(4) +/- l5;, wohen srbidity it ever 10 ": Site Name: _ VqIJ--S 8IES5E.I ow-r-low Groundwater Sampling Form Well ID: r(Uj '-- 10 1 A Date: j ()-7 Seatepling
- /7e WSa" Devic:rho(/X TotaLl Depth (I.D.): .940,6 n a:;la-5 Depth-to Water (_ .T.W): (1) (q WeU Diametet:
a ,v Total Volume Purged: -': Type: eVC,.Tubing Type: Measuring Point: "rgnp, 0-:ý P Pump Intake (ft belowv M.I: ,'.$O' color: Z. odor: Time: DTW: Comments: Temp SpC DO pH ORP Turb (ain) (feet) (1c) (uS/cm) (mg/L) std units mV NTU Stabalization (see note +I- +1" +1- +/- +I- +1-Criterial belowr' 3% 3% 10% 0.1 unit 10 MV 10%, lO500 " i q1', '7 bA / -'40,00 &7,5 726_ Zi jW4.. i4b( 41, 45:00 17,, j __._ INA( ;z i 11 ,7g -7 1.34 50:00 4~~ A0A"L 119 V9L ,&ZR-~ L 15:00 i5,c / "" ; ., ;df 07 -4r" .i3 20:o00 ,q "lg cy /;z,5V ta af AV 6a.- q ,s7 ._ i.L,q " I Z_ '1 #3 1E1 05:00 f,,,7?nt-6_ _. t4_[ ,,,,Al ? 11521 -1,_ i7 6-_ ,61' ____ _&50o:00 __I___M. /__ __i , -A, .,_ 67 .a.9, zz_.,_15:00 P, N,0 V1_ ,_46/s, _10:00 L ,______-pli:00 lm q j .S C5:00 A iesd. Pva H m Lab: 175:00 " Yd '94 A s, ,u 815:00 120:00 95pin:i00 Samnples Clece: AayiReuse:Peevte: Hlig'ime: L Note,-1)- Dom -o'eeere depth tobottan, of o'eJ -folt attte por~iog otnd-osphoe~ mdo -eteesopending fines fhat omybe eesting on the Rbo~tt omo-)Stabittostion cri-to hosd on th-e -d- ee,,cneotv ~ot~oen (3)-Ttltode. toP,! h, notont u oO~ 0 niog t,, to~bo to,edit otssonoy toktosp deeodooýnheeo (t O).32(tO)(4).o/- 10% the. tobidity s ov- It Nflj S FSite Name; ph ylls- .6iS Low-Flow Groundwater Sampling Form Well1D. MO -1 i a.Date: iO/r/t? 7 Sampling Personnel: Weather Co-nd-itions: ii-/A<i4,e ji.. FI'~~-Wz Time: /) 1FileName: Dd /0.A Total Depth (1 .D.): Screen~:..A2 Depth to Water (D.T.W): (I) ill 0 7"[ Well Diameter: Total Volume Purged: 1"6 Casing Type: Purge Rate: K~tJ) Atn(//i% Sampling Device: jýv16ie iA~TubingT : Measurina Poin'~ j e Pump intake (ft oWM.P.).. 3% " color: 8&LVV odor:' .Time: DTW: Comments: Temp SpC DO pH ORP Turb (min) (feet) 0) (uS/cm) (mg/L) std units mV NTU Stabalization (see note +4- +/- +/- +/- +/- +/-CriteuiaZ below)' 3% 3% 10% 0.1 unit 10 mV 10%, 5:00 1 / , i .3,4. .23 /,£, 7.l3 10:00 J.4.. 1z3 I f40,77 20:00 !4,k3 17.g' q5/ /l. .7.2 1 3. Z4, Z, JiL 25:00 /N.1 , iq a ,t 4.-7 "].; J , 30:00 14,11- 17t,@ Qif ; ,9 7-257 R.,,31 .,, 35:00 N,. , i3 45 1.01 CY 7. 2 ._ _.; 6 V 40:00 45:00 50:00 55:00 60:00 65:00 70:00 75:00 -80:00 85:00 90:00 95:00 100:00 ' '105:00 .... .110:00 115:00 120:00 ________________ Sampling lime: .... /i¢q Samples Collected: Analysis Requested: Preservative: Holding lime: Lab: mtJL -/0/ 6 -71W1 ,14A 1~ 0 AS4 JOIA'6 Notes, (I) -Do -el et-u o depth to bot1om ol -o9 l a.6 er puogiesg -d saassplieg to redone r peodig fei tnl. may be -ectig a. the eel botton.(2)- Stlit Mcrt. based on three m oeoncoectine -,eeacmeeas. (3) Total d-adost. e in -e11 to be ke. ttan 0 1 e (032 fi) Purgeig rate L.be lweed .. --ceory to boyp detadortc belcW 0 1 .(03? It)(4) +1- 1T, when torbidity is over 10 NTUs S Site Name: JUVL', ýB&SAe Low-Flow Groundwater Sampling Form WeIIID: tAUV o i CIO Date: 0) 7 Sa Pn Personnel: 6 ajA tr4 Weathier Conditions: (q-2 0 2A Time: Jac; -File Name: JZ IO.,/i...otal Depth (..D.): Sc,,e .gth: Ncsio Depth to Water (D.T.W): ,, 1.9'. Wefl Diameter ;," Total Volume Purged: M 3tj-, Casing Type: .OVe Purge Rate: /sT) ,e1/ d Sampling Device:, ýid)cp. i4 Tubing Type:, -Measuring Point --I b.Pump Intake (ft belw M.P.): ..color. t odor' , ..Time: DTW: Comments: Temp SpC DO pH ORP Turb (min) (feet) ("C) (uS/cm) (mg/L) std units mV NIU Stabalization (see note +1- +/_ +f- +/- +/- +/_Criteria' below)' 3% 3% 10% 0.1 unit 10 mV 10%5:00 .jq5 '. ?4. iiZ .+/- _,__10:00 1243:0 _,W& __. -15:00 -f,66 ,(/.4., r:2 25:00 1,-6,,0'* 41 &Y;l?])T we "l3./ _W 5/" "f.b 4o~~~oof 2g/o .4Wti,h 14,q t.0~ c~ 5~¢ 5";.y t. 91 t,5 20:00 -,-I, ,.35:00 S.s-,O J 3Ot/'5ta& dlA"33 /25:00 30:00 7-,2 icYO IdW 950:00 IR10 AD1" ka LjS9 74 105:00 ox I 7 0r//n-7 60:00 7~i -_ .bf.5Z 60:00 4 4 80:00 Yi 0 2 /a~ki i-5 7o3133L 75:00 ;Ij54 U7_110 b7 3 85:00 90:00 95:00 _____ ___________ ___ ___100:00 ________________ 105:00 ____ ______________ 110:00 ____ ______115:00 ____ __________ 120:00 ____ __________ Sampling lime: /3'/i-'A ,L Samples Collected: Analysis Requested: Preservative: Holding lime: Lab: Notes: (1)- Do not eresur depth to bottom of wen until after purging and saepling to redoce r-supeenbdg fees that semy be ereing on thr well bottomStb l tizntioe Cruerin basd on rets. receot co-se cutive meresueree~tst. (3) -Tota dnrodo in well tobe eo bthar 0.1 em 0.32 it). Psrging orte to be loweesed s necemry to keep drairdsore beiuow 0 Jor z F532t)(4) ./- 1l% when trbidiiy none- In NTL a Site Name: "i9, V/i .Low-Flow Groundwater Sampling Form Well ID: -izni -,/ 4o Date: ylz/ý'llv 7 Sampling Personnel: 0'. /V:v-O- A.AL' /,0d_,-,0 Weather Conditin:, ... ~ Purge Rate: 13e2 9- Sampling Device: Tubing Type: i, _ ,.Measuring Point: R e Pum Intake (ftbelo. M.P.): , color: Lr odor: V....... {) .. ' , " .Time: DTW: Comments: Temp ISpC DO pH ORP Turb (min) (feet) M(t) (uS/cm) (mg/L) std units mV NIU stabalization (see note +/- +/- +1- +/- +/- +/-Criteta'. below)' 3% 3% 10% 0.1 unit 10 mv 10%'(o:00 T.3q, 4 ,.-? 4 , L,,'.', j7,77 -7..? LZo 7.10:00 14,-5 i.gW.4/0 .,4 -Z , A-& _,_ -.15:00 -L1~~ J&/) 6~ /V17 IZZ6 -i4l -677 35:00 li 95 /9,0- il ,/ .. l K&al, 9,9 t.,,'7 .f Z-4,90 65:00 f57 , ,25.'/a/',4s f,,7 ;2A' -.7,// i 157.S 65:00 _S, ',14 ,;9bO iqd, -/g, 7,$/2,.90:00 45j 95:00 _____Q6 g & i 100:00 105:00 110:00 QJ5 A&-45_____________1__2 115:00 133 1,17 120:00 Samples Collected: Analysis Requested: Preservative: Holding Time: Lab: 80:-'0 0 _____20 ____7_ 1, V /-A 85:00 4.. .....il 90.:: ..:-. 00:: .... .:i::-:. .:i.i!:!':
- : : : : i: .." .... :i ...: .Notes:i (1) Do tot -esre depth to bottom of oeti ooti fie- poegiog ond oamprng to redao rens pendteg fino that -y be .esting.o the s-el bottoto (2) .:
airiler.a bosed on ose t r -I -ecent conoecotive -fleaS-ementS .(3) -Totoa dotdo.- in t eot to be Ies than 0t1 o (032 it). Puorgiog rtte to be lo-reed s .necessry to keep draodno eow, 0 1 .(032 ft): (4) +/- 10% ,hte torbtidty is ovn 10 NTUS.0 Site Name:- _DAUJ.5' ~ 'L ow-Flow Groundwater Sampling Form Well ID: V1L() -iO,2A Date: 4 137 C 7.SamE ung Personnl Weather Conditionms:
- 'f , * $d a L.Time
- ol GO __File Name: Dj6/19Q Total Depth (I.D.): 9,2,9g ' Scr, A frh: 3 ,. .Depth to Water (D.T.W): / "72' Well Diameter:
d /Total Volume Purged:- Casing Type: PV.'Purge Rate: j-7~#t/Z. Sapn Devie r-I4 fQ Tubing Type: MeasuringPoint-6,k: P1.1" Pump Intake (ft below'V.P.): 53 CY.' color. ZIav oor:_, Time: DTW: Comments: Temp SpC DO pH ORP Turb (.min) (feet) CC) (uS/cm) (mg/L) std units mV NTU Stabalization (see note +I- +/- +I -+1 -+1- +l-Criteria' below)' 3% 3% 10% 0.1 unit 10 mV 10%, 0:00 P-J .41PnJmj /,4,1L. ? o 5:00 A !t -X43 7-,1I 10:00 o I, real R7 44(,iZ 1,,.' I/,- -1,2a, -igy I?20:00~25:0 a. q055al 30:00 OR -, .,01 -206. A, 3 340:00 1/1g !q d,, 06 zQ 4 g.i.9 '. , 45:00 ] ,P. (e2a /n !!h2 --! , ,q4 4,_5" 50:00 tgm I m. , 15,3,L a53 Q.q 55:00 il, am- a5// 9 -.zl .7,. ./, 60o00 ii, , iq.nja. --Z5 72,;2 , 7,a -Ib9,c L.0 O 65:00 q -,- -7 /) ivýeva I , 7L ]-/I*'D 1,IZ3-9 70:00 It7, -- ' aL zo.L IZL.4 i, 71 75:00 iT7,n i.5"I.I J ;2 7V , 7, .1/ .-t7R,5 1,06 80i~o "]l-70 jv"/.L -15,,Vb a.q-,I a,T7q ,.'80:00 .4 I7e _ 1gq a,-85:00 1, ..... /10 XS. Q W6-',76,0 1 ',S.95:00 j/. o653/4 "/.-/. /100:00 A L2- .14,9 A'/,IN, J-5-,60 a._WE 3,0 zal &105:00 i, '1/ 4517 A,.69 7.; 2 , 110:00 ,-7 /9 8 7 3,415,/ ,;1-al3 106 110:00 ts I6 120-00 !f1g 7,6A/ l// l .,ý. 1-1"=,o. IJ Sampling Tune: /'7- /O'5$Samples Collected: Analysis Requested: Preservative: Holding lime: Lab: 5 6 4'~A1L Notes;(1) -Do not tru-un, depth to bottom of wen until after purging ard atrnpLring to ndour re-punding fires that ray be restig on the weo bonom (2) -Stabiizaton criteria based .o three most recent consrcutive (3) -Total drowdocs hc sot to be [ec thao 0 1 (032 it) Prging rate to be lowered aso rcenary to keep drawdow- below1 aT m (032 f)(4) -/- 10/ whecn turbidity it ocre 1O NTU. S Site Name: DcY Low-Flow Groundwater Sampling Form we~ila "rw l -L, -c.o a- Date: C4 Ia-7 -...Sampl- Personnel: Mn tia t-4tr.zcA-c(Jc Weather Cond ti 9 gx .J Timne:~4/Isf File Name: DA M;-P Deth to Water (D.T.W: , Well Diameter: " Total Volume Purged: .Casing Type: P Purge Rate: /Ur AX Sampling Device: tf1 Tubing Type: j)* fý04k_._ Measurinj Point: 7 t + 12 Vj2-Pump Intake (ft below .P.): 7 -/ color: ,/ 0 odor: .., Time: DTW: Comments: Temp SpC DO pH ORP Turb (min) (feet) X.) (uS/cm) (mg/L) 'std units mV NIU Stabalization (see note +1- +1- +1- +1- +1- 4/-Criteria 5 -eow), 3% 3% 10% 0.1 unit 10 mV 10%, 0:00 .. 0 0,61 6,17 .6, 5:00 i_, 4-6 qAllL!;'4 1. 7/4.-, C/ Z,"-4 I V/0 10:00 3 / A/_ 3, ." .7;3 ,, 15:00 /" /A'Z, 11.30 -eijaj,08 A,7i:A-.340M , 20:00 ;q, " t A-'- 3 -6, -72 ,-S/.9_ _,_25:00 _,2 _q /Z~ 4q Iiica( le2 11~30:00 n4,{o .l3 fm S,4o1," -7 35:00 J1 -53 ,Q0 /6,701117,00 /,.27 ,7,2 -:;. e,, 40:00 a Y, q y P!.e' -l/, --be7. 65(a d .3,', 7. 4,,02 34. 1 q JAI?'45:00 ,n34A'- 3 50:00 , /%30 N73&00 67-.Z.65:00- 7 1 L i'65:00 l .--70:00 95 A-O W1460d S -,R L,, tZ5-O 7amp 00 Colcted Anlss euse d:- Preserva3ý tive Holin me I-,,77 -b , -c 0 80:00 r;/4 etIIA412 iZjf I1~ W7Z f -- 6/i_3 85:00 .k. b7,36 S2 95:00 A5 7e ; 47 ..a 94..5 100:00 AM A1htJ--6 / -14,M l-7 1,74 ---M "k 105:00 It 0 S14 /12~I &s, 3 72 1-7.115:00 01.(~~'YO__ Sampling lime: /9L 1 0 -/5COSamples Collected: Analysis Requested: Preservative: Holding Time: Lab:-s~ee46ky II U~Notes: (3)- Do rot oeasure depth to bottom of well utol after purging ad sxatpling to reduce -pending frees that my be teeting or the well bottom (2) S-abilisassto riteria based -o three .-at rec-st rsnertie -ete reemens.(3). Total drawdo- .well to be les thos 51 oI (0.32 ftt Pinging rate to be lowered as nee ry to keep drawdowno below 0 1 m (0.32 it).(4) +/- IM., when rerbidity is oer 10 Nfl)s Site Name- D)6hI-r. b;cst[ow-F low Groundwater Sampling Form Well ID: rn i )- jo;:)-(.Date: q ID7/-710-Sampling P~ersonnel.- O2. Laf %bk ( iojYan'. 1 i )Weather Conditions: b-': File Name: lO.C(Total Depth (T.D.): scr., r 9: Depth to Water (D.T.W): (1 POW" Well Diameter: Total Volume Purged: '4 v Casing Type: Purge Rate: Samplmg Device: Tubing Type: I Measuring Point: Pump Intake (ft below M.P.): color: odor.Time: DTW: Comments: Temp SpC DO pH ORP Turb (min) (feet) (°C) (uS/cm) (mg/L) std units mV NIU Stabalization (see note +/- +1- +/- +1- +/- +/-Criteria' below)' 3% 3% 10% 0.1 unit 10 mV 10%, 0:00 < /7 .;, / I 72M 6 5 7 -, , 5:00 & MI ,Y to_10:00 10 2_0__4Z, 0 20:00 ,,6 7 25:00 7_&__*Y,.30:00 , /9 1_3_ 7 .7 _ , , 35:00 -as 40:00 Ok o -77 /0 45:00 -;?,30o /2P7.z.l2 13, 100 Y,& 4,79' -349, f, 450:00 ~3h 9;6 q & ___i 55:00 60:00 65:00 70:00 75:00 80:00 85:00 90:00 95:00 100:00 105:00 110:00 115:00 120:00 Sampling Iime: /qqo -Samples Collected: Analysis Requested: Preservative: Holding lime: Lab:~4A1A~$Notms (1) Doe nor -me depth to bOom ofwlt unfit after puroge and sarplingt a mduee nnasprrrding fino that? ay be mafbr on the well bottom (2) -Stabil~izatoncriteria bavd Z hnrr moal -t .1,~o e me. .eOmrb.(3) -Toaaldrawdomn in l toI kw tmmban0 m (03 2 (t), P.'0 oýg r,. tobe loweemd~ -y to k..pdrmdow belaow0. m (032 f)(4) /1* I0% mhe. ourbidhly it over 10 NflJ a Site Name- _.A// /1 +/-.L ow-Flow Groundwater Sampling Form Well ID: 17/-9U lio'Date: 21/ý 7 Sampling Personnel: 01 4&L7&6 z"~,vt C (. ZT~c Weather Conditions. 1'7 V4ý ig Time: i1&05 -61 File Name: .b/ 3A4/Iotal Depth (I.D.): -Scr g8th,- :-5. 7.Depth to Watei (D.T.W): '; [ )7C! Well Diametei.Total Volume Purged:$ie3d-Casing Type: (2 Purge Rate: /7 ' Sampling Device: fr ,A,5 .e Jo7e Tubing Type: j44,4 .Measuring Point 1- '745 A .1F Pump Intake (ft below M.PVf: ,ý 7..' color: ý#-#tp odor: nt.d.Time: DTW: Comments: Temp SpC "DO pH ORP Turb (min) (feet) (*) (uS/cm) (mg/L) std units mV NIU Stabalization (see note +. +I- +- +I- +/- +1.CruteiaZ below)' 3% 3% 10% 0.1 unit 10 mV 10%0:00 43lJ'i~ tiq'6 2 -iz e. C)T a &;5:00 -f 17,fh0P N4-7 ~ At5'f 6 i MF. /I-//5 I 10:00 jjý75 -O~ ~7,6 -)d 'd.0~ 4(0 15:00 J,52 Iko~ 4%.0f25$ ~ ,t~ ~3~25:00 i7-,x. -I -,/ -S.:...,- /93 x t.7 ,. zo1/ .7' cq .1!3 r I 30:00 17, --W Y i7 , = 255h4 1, I -Q.6- 3240 40:00 J 37. ui. i -JL= I..__t___4-V i o 34:00 j7-5,9 -7 g rZl ,4,,7 _ q7 2,-51-3 /,6.0 7&5 350:00 *j. ii 2A& U t Aq ~550" 7rIvt, .Le/ AV" --IZ-.?40:00 tT7 jS- i ,-6Y" 1,.. .,q r" 45:00 ,. 7 -7 ir¢,. 3., L ' 13,4&70:00 i7,sZ$ -7" L' f L! /RI /. 6-3 T 713 Z 50:00 QQ5 I~217 4 'i .ii-3 -4V 1i~.73 -2 a'5 7KI 1__4__1 60:00 17,51__. _ _, _ _ _ _ ?, L'79 -7.6L -, , " 65:00 171--.. hldt -'T ti.Y!O., 24S6'& 1,qt~ M -70.5 -1 ,Q V ;,Y 10:00 i a7,56_ i7ZI__,_._. iY,76 ___ 1._ 2 0f"- '-1 :__ 3 105:00.810:00 ?7 4 49 115:00 120:00 Sampling Time: i'.*~//Samples Collected: Analysis Requested: Preservative: Holding lime: Lab: rc .W A 7 Notes: (I) -Do not meosure depth to bottom ol well unil alter .n 4 d tnpling to rede -e-uspndag 1me. that -yq be retng-on the -el I bottom.(2) .Suobilirton criteria hued on three moi recent conecutive OIS.(3) -Tote) 4ado. in well o be letos than 0 2 .(03 2 I) Pufgieg t. to be Ioow-ered .--ecesy to keep dr...doon below 1 m t032 Ill (,) +/. 0I whn thbn jedi soer 10 N71U.1 Site Name: ._.(4Vi5 ),Sja L ow-Flow Groundwater Sampling Form Well ID: MIAh -JW Date: 104 107 Sampling Perionndl: /f A~j',. L~~A/i~ &-4 Weather Conditions: h, 7'z i. ;_ ,AJ/AL4 .-: 10-x Time: iclt3 1-5,91 V File Name. -, t) 0i,'Iotal Depth (r.D.)Sc I4 Depth to Water (D.T.W): I 421..2 Well Diametei: .=." Total Volume Purged: _-,- ., C Casing Type: Purge Rate: / l 2 Sampling Device: Pump Intake (ft balov lM.'.):rJ Li .color: odor: -, Time: DTW: Comments: Temp SpC DO pH ORP Turb rn) (feet) CC) (uS/cm) (mg/L) std units mV NIU Stabalization (see note +1- +1- +/- +/- +1- +-Criteria.' below 3% 3% 10% 0.1 unit 10 mV 10%l 5:00 LL d. 4 R I ,L 7,c-'.2/,jA Lq.7 10:00 .. l..x, 7.3 2.., 15:00 41X/mc ,., 2 -.?,z Y _, 117 20:00 p --L 1l 'Z __-~~~ 7.// ...^6n, a 25:00 [q t.3,sJv j,75" ., .!5 7, Z J3-i4 I-j 30:00 A10 i_2 -h/16 ,q,i9 6 17,23 -, 35:00 4b.qL <2 q "7 1 q-7 I 7,99' 1 7,1,9 .. /," 55:00 ib,,/7 ,._-e~d,,, 2e./q ~* -#'/ oq *7 /,6 45:00 y 17 O V. q-1, 70:00 J4 " 1 /* 44__65:00 164 t7( A,.- j~80:00 ____ ___85:00 90:00 /'Rq I__95:00 100:00 105:00 110:00 115:00 120:00 Sampling lime: ,.. 5 2--Samples Collected: Analysis Requested: Preservative: Holding lime: Lab:-rim. PJr.LAJ,*ii'3 -.O o"z P.- 1', ,.4 jed Notes: (1)- Do =ot Ieoasue dcpth to botorm oftwell ontil aftar porging and ootophig to -cd ,e respending Frees hat mey be resting on the tell bottom (2) -Stabiliotion cilteiA ae.-d as three mon recent co-- octcive meaootemeos (3) -Total drnodon in -oell to be les thin 0 a I (0 32 ft), Porgin, rare to h. loweerttd ot ootocry to keep dratodoto b 0 1 m h 0t32 ft)(4) 1/- 107' whon ourbidity t o4er IB SNMJT a L ow-Flowt Groundwater Sampling Form Date: A 11 0 Sampling Personnel: Weather Conditions: Time: DW C T File Name. _ [> O -, ...(otal Depth (I.D t): (C) (uScm 7m-/L u Depth to Watei (D.T.WM : Qii 6 ,S Well Diameter. OfZ TotaliVolume Purged: + Casing Type: +1 +- , / +Purge Rate: -, Device 4l,;qg,, r Tubing Tye Measuring Point: c) If -/ VOLI 'Pump Intake color: odor: "Timne: DTW: Comments: Temp SpC DO pH ORP Turb (rmin) (feet)! ('Q (uS/-m) (rag/L) std units mV NTU Stabalization (see note / +/- +/- +I- +/- +/- +/-C0iteria. below)' 3% 3% 10% 0.1 unit 10 MV 10%, 0:00 -,a yo Z 13/73ýL el/lb -517 5:00 i__,v_ g.Y_ _.__3,z 14.9 25:00 7 ,eZ a , /k.,,., i#kZ1 LLZ z,,L 30:00 ____ __ ___ 1j,7 1 (ztcC z;;O 4%.,6 35:0o 4 ___ _ 40:00 ftid *1 __-__ .___ -45:00 ___&__50:00 55:00 7e, filoI'db_ _____60:00 65:00 ;.,L, a_9c .1_30:00 47 _______ 0v__1 kF 75:00 A A_1___80:00 85:00 90:00 95:00 ________________ ___105:00 110:00 115:00 820:00 Sampling lieced: Anlss- -Sape olctd nlssReq~uested: Preservative: Holding lime: Lab: Notess (1) -- Dto not mcsusore depth to hottom of weoO utstt aftet porging and tasamlog to teduce oetoopeodiog toot thot ott, ho teoting Ott ho weti botomoc (2) -Stanilization criteria hosed ott three most reocett consecutive teasureotents. (3)- Iotsl drossdossts itt sweP to ho foo than 0.1 to (0 32 It) Puoghog to ho scowred 's ssccreowcryo heep hbeow (51 t (i.32 it)(4) *-tI 0(5i whnit turbdshity ft over 10 N'TUt j~9 SiteName:. Th"Is- 'ýf3S-l Low-jlow Groundwater Sampling Form Well ID:-IZIf2 Date: ' I I .Sampling Personnel: ,-It -a Iv' (tý_~A QJA Weather Conditions: Mon*Time: O~.5-~) ,:, File Name: -0 toirC Total.Depth (I.D.): J..7 ' z%" n: 6-Depth to Water (D.T.W): M /g'p YO' Well Diameter: o 2, Total Volume Purged: Casing Type: Purge Rate: ,. ./ j , -Sampling Device: j r/ ,Y , Tubing Type: Measuring Point: ',O Pmnp Intake , / color: odor: ., Time: DTW: Comments: Temp SpC DO pH ORP Turb (min) (feet) Xc) (uS/cm) (mg/L). std units mV NTU Stabalization (see note +!- .1- +I- *+I +I- +I-Criteria' below)' 3% 3% 20% 0.1 unit 10 mV 10%, 5:00 1i1 d,- " 7 Z .f f, 50:00 /,1_ ; ll,,. , &) ,1i-/ .6".0F 6,9Y., 7k~gi,o0 10:00 =; xuizfZ91~S qb 29y Y1ý15:00 i,L~L 1~4~ /.tL _A9/ 'OS/ ý2_54 20:00 13,i2 ../ kr_, I .",/1 1.,,?9 -f-1 a 25:00 fi $f -30:00 /3EZUAZ/Zs ,7i? 4.L~ i3 MYI &? t1. 0 35:00 M-100 ;!/ 7/ 7S YZ #J&'~o 40:00 m / A1WIP__M_2_951____L, V.6 45:00 1Y.13 _,-1 iA ,o ,9s .1/,97 50:00 3,17 , .- ,- !,,1,o A ..55:00 -41, 11 -__79. r 6_, , 60: 1 ,/./! ,S7 1g,15, 65o 2,3 Q , '/,5? ]a, ~95:00 70:00 ___._M_75:00 10:00 85:00 100:00 105:00 11I0:00 115:00 120:00 Sampin, Time: '(00 1,V1 Samples Collected: Analysis Requested: Preservative: Holding Time: Lab:* .: ': ....Notes: (1)-D .nort otnoonre dept~h to bonhor ot eonellsunt)] ahter purgiotg aend osepltirg to reduce r ensspetelieg titso.s that snay he renting on the owel) bottom.(2),- Stohiiotion cirenia based on three rcns recent connecotine re-ast.oote eot.(3) -, ohtdr as doaonio e elitot be n er the 0- e (O32tt) P0 .we t obe neoweieds en0y to keepde -aedoeoobeoo wfl r , 0., 2 O t)(4).÷!-10 wO.hen enhisit1y is osee tO (dThe Site Name: -f .B EC Low-Flow Groundwater Sampling Form Well Ia.D 790E Date: W&ro" Samplink ersonniel: XL.te49 (WeatherConditions: 6 .Time: fi,'74 File Name: Total Depth (I.D.) Scee Le-th Depth to Water (D.T.W): m /1., Well Diameter: Total Volume Pur ed: 0, 4-A.Z. Casing Tye: 1O/c.Tubing Type'. Measuring Poin 00 Ir lf[Ti-me: DTW: Comments: Temp iSpC, DO pH ORP [ Turb (mn) _feet) (I) (uS/cm) (mg/L) std units mV NIU Stabalization Isee note +I- +/- +/- +/- +1- +/-Criterlia' below)' 3% 3% 10% 0.1 unit 10 mV 10%, 1:00 A -7. /D,. 7,9V -, ' -, .-5-05:00 AA07 ,l-.60' -l,4t. 2 Y541 --/,_7z _-_ 3,_ -a_10:00 1,,, a_./Z ,. 4, f* 7 M 15:00 ?..5IV,.-' 4 9,07 l"d -, 0 25:00 _____0 i'i 07 10// IWI& 1 3 30:00 i&o42 2 , i-/1 '/ g., 7/ 7-. .35:00 20,16 9_a__/__ I V,__ _2_41.67. q, f.Y -7, , "M 405:00 ddg___ ____________ ___ '7. ,? 7,I A-19 45o.00 aa a /,..,Vf,'TV q,-Q# -7, // '90 55:00 iaff ; 7¥/ R 17 , 71 -7,05? 60:00 65:00 70:00 75-.00 80.00 85:00 90:00 95:00 100:00 t.. ..105:00 110:00 115:00 120-.00 Sampling Time: 1/1/ i1141 Samples Collected: Analysis Requested: Preservative: Holding Time: Lab:/tfw- tO'k 0.W ~ tvi d~, 5,4&14*6 Note-~(1) -Do rot me-ooo depthi tobottoo of wroo orltil ofter poorgl 0 adoomolig to tocior roooopondio 5 k frthat o=y o tbe elioga hoý roet bftto (2)- S~tAiiotioo oritofo booed othrotmot octotcosoobntoOw ttoýf..3)-_ Totoldawcdocon lowel e Veto Coo 0 o(032 Vt). Poogirtg 00 lo be lo-roeod oooooocoy Cop dmwrdowbelowCL 01 t 12 ft).(4)4 lýfr 10-= n teridity b, -oo 10 Nr~lo 9--....CA~k:~-~iA;.~----. - Site Name: "' a% I L ow-Flow Groundwater Sampling Form Well ID: M tz) -V) W rý_Date: Q1-:0 C? cIL'7.. i Iv A ml L *Sampling PWsonnelý V,. 6deMh ffk3,-jOL/-jRj (4 Weather Conditions: Tune: 1/26cf L.ý, ý D i::4 !L
- J,1410 File Name: n j-fl/C Iotal Depth (T.D.): 2Zd? Screen Length7 -Depth to Water (D.T.W): ~ 3~Well Diameter:
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(4) ./. 102. noto toatdity i, oct 10 NTtUo Site Name: ~ls21E-sq Loaw-Flow Groundwater Sampling Form Wel HiD.: --I A Date: 1-12JO-7 Samp!Mn ersonel: C, .yj Weather Conditions: 5d e ký.Time: 1014, /,7 / ýTo tal Depth (I.D.): 7,61 , , S~cr een : enth Purge Rate: fv(./l Device: "I ,b Tubing Type: M QXIA 0 , .?'*e N[easu O ia~ k c Pump Intake
- a. '6 color. odor: '/rt , Y4 f.j~to,,a Time: DTW: Comments:
Temp SpC DO pH ORP Turb (min) (feet) (tC) (uS/cm) (mg/L) std units mV NTU Stabalization (see note +I- +/- +/- +/- +/- +/-C-iteria' below)r 3% 3% 10% 0.1 unit 10 mV 10%'0:00 _5:00 P7___10: 00 1 90 1AV,8 /' 1, aL, { *0; 7 R~ 75,-.:-:& 6.15:00 3 v/Z ., 90?, (A 20:00 -1 ,24 I, Pe) 0to /m gz.,. ! --9~ ,. -.2 ,q $ 41ý519 i? ,1 15000 20:00 .l, .25.00 144u, jZ750,IZ3 j/7 AJL ____40:00 / 1. q, 2431. 07 In A &. Z1,7 45:00 1 -;zi .,xO hný &-x 4 ,7V L,,ql-Y/,0 /1, q 45:00 .1,3 ;?. / ;411 1,,,Y , -q//J _55.L0 0 jql Iq i,. , 60:00 1. a ,,,, -7 2- -4 f-, q_5 65:00 19 -;oA 2a/Wt/0& -Z .,17 2J(1 /I'_A_ /7 70:00 yo 51 ._3171 AL , b,Y -3 A,5-75: 00 /:. -4 ý 2 w s u l ..o i, 5 .¢ -,a , /-I n 80:00 I3,.C) 0 Y 4q41 -I2b.0 95:00 1j,3 " -/ 1-A2.L 9 F -SY./-__90:00 _,3 1-.2 q3-I ý J.-7t b 95o:00 1g37 PA'- 4, T V3? i, 5 .17 5,q -! al -" 100:00 J LL.i S 3 /3 /105:.00 3,; .'49. ,d;ll& -'475! t,_ , 110:00 134 pl/7- : 120 00j, ;Z.:,1 T"T' j Samplinglime:W'/; /Samples Collected: Analysis Requested: Preservative: Holding Time: Lab: Notes: (1)- Do sto-re depth to s b otin f wel laft~or lugir and sampfing bo red une fmo thia ouyte restin on the well botton, (2) on three tosot ,eo.osemnmt. (3) -To ol d wt too -1 tobe h1.t th.. 0 1 .(0.32 ft). P.rgg r.a.e o be ed a. n--nboty to eeop drswdows below 0 1 o (0.2 It)..(4) .1- 10% when ithidity Is -ose 10 NTU.S 0 Appendix D Laboratory Analytical Reports S-~ Environmental, Inc.Midwest Laboratory on Allg heny Technologies Co.700 Landwehr Road " Northbrook, IL 60062-2310 ph. (847) 564-0700 -fax (847) 564-4517 Mr. Al Percival LABORATORY REPORT NO.: 8003-100-362 FirstEnergy Corporation DATE: 07-10-07 Mail Stop 1041 SAMPLES RECEIVED: 06-22-07 5501 North State Route 2 PURCHASE ORDER NO.: Oak Harbor, Ohio 43449 Dear Mr. Percival Enclosed are results of the analyses for tritium and gamma-emitting isotopes in five ground water samples, one matrix spike and one matrix spike duplicate. Should you have any questions or other concerns, please do not hesitate to call.Si ce ly, S.A. Coorlim, Quality Assurance roi o, M. S.SAMPLES RETAINED THIRTY DAYS AFTER ANALYSIS Report: 8003-100-362 Page 1 of 1 Table 1. Results of analyses for tritium and gamma-emitting isotopes in five ground water samples, matrix spike and matrix spike duplicate. Sample Location MW-IS MW-ID MW-26S MW-26D MSO1-MW-26D Date Collected 06-12-07 06-12-07 6/13/2007 6/13/2007 6/13/2007 Time Collected 10:49 13:09 10:17 13:13 13:13 Lab Code TXW-3910 TXW-391 1 TXW-3912 TXW-3913 TXW-3914 a Isotope Concentration (pCi/L)H-3 < 330 < 330 341 +/- 101 < 330 5000 +/-208 Mn-54 < 2.1 < 3.3 < 4.1 < 3.3 < 2.0 Fe-59 < 6.4 < 6.2 < 9.0 < 6.1 < 4.1 Co-58 < 3.1 < 2.7 < 5.7 < 3.1 < 2.3 Co-60 < 3.1 < 2.3 < 3.1 < 2.5 < 3.5 Zn-65 < 3.2 < 5.9 < 7.5 < 5.2 < 5.6 Zr-Nb-95 < 2.5 < 3.4 < 5.9 < 3.8 < 2.9 Cs-134 < 2.7 < 3.3 < 3.6 < 2.6 62.9 +/- 4.5 Cs-137 < 2.0 < 3.3 < 2.9 < 2.9 64.2 +/- 6.9 Ba-La-140 < 3.9 < 4.5 < 5.3 < 3.3 < 3.9 Sample Location ViSDO1-MW-26r MW-7S Date Collected 6/13/2007 06-13-07 Time Collected 13:13 14:53 Lab Code TXW-3915 a TXW-3916 Isotope Concentration (pCi/L)H-3 5055 +/-209 426 +/- 104 Mn-54 < 3.1 < 3.7 Fe-59 < 6.1 < 5.7 Co-58 < 2.9 < 2.0 Co-60 < 1.4 < 2.7 Zn-65 < 5.9 < 2.7 Zr-Nb-95 < 6.3 < 4.3 Cs-134 59.1 +/- 4.5 < 2.9 Cs-137 70.0 +/- 6.9 < 3.5 Ba-La-140 < 5.9 < 4.2 The error given is the probable counting error at the 95% confidence level.Less than (<), value is based on a 4.66 sigma counting error for the background sample.a Known spike activity (pCi/L): Cs-134.59.3 Cs-137.66.3 H-3, 5639 --Environmental, inc.Midwest Laboratory an Allegheny Technologies ro.PRG-33 Form LS-4 Vez. 10 TR1TLTM LSP-2000C-A []LSP-2?550TRI/AB E LSP-2800TR S Init. & CountDate: t 06 /9 /07.0.10032-STPD T-36 BKG .BKG Sample STD TD -STD Date Time Counts Time Time Counts Acbvity Issued I (pci) _qto i00 42o eLtGtIKOI1003.78 01/18/2001 Sainple EDi Volume Sample Remarks (nml) Counts Z q ,0 G al t-j66__ 14 607C__ ______ __ K_ ___ __ I0 0__ __ ..-.;vv .-X.... k Environmental, Inc.Midwest Laboratory an Allegheny Technologies Co.PRG-33 Version No. 1.0 06/17/97 Programmed by Rick Lesko Sample Count Time (min.): Background Count Time (rmin.): Background Counts: S TRITIUM RESULTS SHEET For any sample counted on the LSP-2550TRI/AB, LSP-2000CA or LSP-2800TR Reviewed and Approved by.2-ýDate approved: 100 200 912 Standard Count Time (min.): Standard Counts: 200 64469 0.205 Date Counted: 6/28/2007 Calculated by: Rick Counter Efficiency: Date Calculated: 7/5/2007 Sample Coll. Vol. Sample Corr. pCi/L 3.00 4.66 ID. Date (ml) Counts Factor Sigma Sigma TXW-3910 6/12/2007 13.0 495 0.998 66.176 + 91.250 91.693 108.702 168.851 TXW-3911 6/12/2007 13.0 465 0.998 15.271 +/- 89.337 89.361 108.702 168.851 TXW-3912 6/13/2007 13.0 657 0.998 341.007 +/- 100.941 111.085 108.685 168.825 TXW-3913 6/13/2007 13.0 496 0.998 67.862 +/- 91.299 91.764 108.685 .. 168.825 TXW-3914 6/13/2007 13.0 447 0.998 -15.269 +/- 88.156 88.180 108.685 168.825 TXW-3915 6/13/2007 13.0 481 0.998 42.414 +/- 90.348 90.532 108.685 168.825 TXW-3916 6/13/2007 13.0 707 0.998 : 425.835 +/- 103.754 118.823 108.685 168.825 1 =Best probable result. --., -Environmental, Inc.'Midwest Laboratory an Alleghany TechnO1DgieS Co.PRC-33 Form LS-4 Ver. 10*.0.10032g STD T-36 ThJTUM LSP-2000CA [-LSP-2?5501TRI/AB 9 S LSP-2800TR [Inlit. & Co~unt Date: PIfX2 M) (>/3 7/BKG BKG Sample STD
- STD Date Time Counts Time Time Counts Ac5vity Issued_ (pCi)boo -7q_5-- 100 ©bO 1003.78 01/182001 Sample ID Volume Sample Remarks-(ml) Counts&~.- 7JR~t~ ____ 4A-/ ýIPn_____. ______ 2% __________ ._.__________________._,_
% I ___________ ___,_____________-________,_-___. _____________________________________________________________ _ _ _ _ _ 1 _ _ _ __ _ 1 _ _ _ _
- .; :..,.... ........-.;...... Environmental, Inc.Midwest Laboratory an Allegheny Technologies Co.PRG-33 Version No. 1.0 06/17/97 Programmed by Rick Lesko Sample Count Time (min.): Background Count Time (min.): Background Counts: 0 TRITIUM RESULTS SHEET For any sample counted on the LSP-2550TRl/AB, LSP-2000CA or LSP-2800TR S Reviewed and Approved by.Date approved: 100 300 795 Standard Count Time (min.): Standard Counts: Counter Efficiency:
300 85421 0.182 Date Counted: 6/30/2007 Calculated by: Rick Date Calculated: 7/5/2007 Sample Coll. Vol. Sample Corr. pCi/L 3.00 4.66 ID. Date (ml) Counts Factor Activity Error T.P.U. Sigma Siga TXW-3914 6/13/2007 13.0 2881 0.997 4999.840 +/- 208.295 711.166 93.339 144.986 TXW-3915 6/13/2007 13.0 2910 0.997 5055.267 +/- 209.309 718.672 93.339 144.986=Best probable result. 0 EG&G ORTEC G V -I ( 175) WAN32 14W02.96 28-JUN-2007 15:39:30 Page Environmental Inc S nCpectrunm name. 17403. Ani I1 Sa)Ample description TXW--3916
3.5 LITER
13-JUN--2007 Ii4 53 PMS Spectrum Filenameg C:\Wser\17403.An1 -7 Acnqu..tisition in formation Start time, Live time Real time Dead time Detect or/Geo metry IDs.840C, 8417.13%0~Detector systemr MCB I Input :1.Cal ibrat ion Fi I ename: d I I. CIb Created: 14-Mar-2007 13W36-4-9 & 20-Mar.-2007 13:52:52 MG -23 Geometry #1 35 Lite-r water iTn MB.Zero offset Quadrat ic,-I.980 keV; Gai rn.120E-,0'7 k qc a n l'.501 eV / ch anne 1.Library Files Main analysis librtaryg Library Match Wii dth: Analysis pavr:ameters Start channel, Stop channel.P e a k rejection level Peak search sensitivity:v Sampl)e Size.Activity scaling factor 2.'-.. li b.5 00i 120 for an energy of 58° 13keV 4048 for an energy of 2@26.06keV
- 30. 000%3. 500 I1,21 OE+06/( I .2 r]01 E+0 0-x +)0).2, 657 1E-+--15 Detection limit method'RI S HO methodc)Addi.tional randrc:)m error.1 .0@00080E+N211 Additional systeSml-atic error: 1,,0000000El+00 Fraction L.. i 0 i. t 2,990%Background width: best Iethod (..based on spectvnum.
Correct ions Decay correct to date Decay during acquisition De-.:cay dluring collection Peaked background cor".rection st at us YES YES NO YES 13.S- Ju n -'200i,7 hkg.w -I. pbc-I.l7 '" A i:r -::l'lr:@ I -ii ,.. l1: 1 :5 h.I! " ll, ý. n CI 0 ii1 1-1 In III I. I I y I m k..SOEG&6 ORTEC G V -- I ( 175) WAN32 14W 28-JUN--2007 15:39:30 Paqe 2 EnT V 1 i T) Irnm en tal 1 Ci Sp [):..-t Iruli nam I 1 ,e2t7403, A-n1 1 Energy calibration normalized dif.ference:'o .1125***--'****-.- U N I D E N T I F I E D P E A K S U M M A R Y ********PEAK CENFROID NET AREA EFF.IC I ENCY UNCERT FWHM SUSPECTED CHANNEL. :-NERGY COUNTS COUNTS
- AREA 2 SIGMA % Ik<eV NUCLIDE f-I ... +...b-"+ F -- -f --+ ..I. .-+ --+ -- ---+. +-- --f -+ -- ..... --- -+" --- + --f-... .... I--" -...- 4'-"-"t--"+
... ....I,- - +-..--- +.... --++ --" +-- --.+ -... +706. 55 351.97 ,122, 0 10 609.,24 130.30i.93. 7.4.6Z4.E03 110. 1.275E4.4 55. 09 2.027 P9-214 ,2832 1.622 BI-214 sI::'De ak fails shape t e ; tsts D Peak area decoT-voloI .,ed I D E N T I: NUCLIDE PEAK CENa.R O ID CHANNEL ENERGY F I E D P BACKG ROUND COUNTS E A K NET AREA COUJNTS S. U. M IIl A R. Y, *******INTENSITY UNCERT FWWHI CTS/SEC 2 SIGMA %/ keV CE--144 CE-. 14 1 1-131 O B A'" --I --14 LA---1.401 I -.3 1 BE'-7 LA- 140 RU-103 BA- 140 CS- 134 RU-103 RUJ- 1 06 CI-.1 t211 Z R-" --),..-.,rJ .'i::-E.95 C---l1 34ZI CO0--- 5 8 MN-54 FEL...--... 110-6 K--40 rD Peak 271 .292.0Z9 571.3,:'5-- E, 14. 9.-4 C-,C-'l0 17.17 7-..30. Q7177 960,,45 976.0 993'. 85 31,-[1 : 107, .71 1 244. 09 12 E72.:, 00 1332. 05 L.5 1 , 3-8 1536... 71.1. 2 5 ! 3. L1;?I ".i I. -112 166L,1.35" 234. 00'-577-99 ,2.6E2:,:. 0 5 7120 35 133. 78 1 44, 34 284.24z!2546 L8 2 8 6 S, 3,CS3,. 7 5 4. 79,1. "7'486. 96 5-38. 1L5 604. 02.,1 621. 26 635.2;F5 7 2-3,." 4,"0 7 (7.86 17 9 0, 6C 8 .. 0, 26 830. 30 1115, ') 'i.i'1 1. 1. 1 " 1170 .8,1 1331.6!46t. 0 C.15 (7-, :1. 7 7.9 3320 E9.5a.50'.37.it.30, 35.32.32.7.a.23,, 6,20 7., 3.11.12.0.71.3.1 5.15.7.54,, 1.9.52.5.1, 0,.000.008 17210 0 2000 00 1 1201.000 0014" QI0 31 0012 (1310 13.003 00 1..2101 080 012,71..0 1.".2.I 12001:1 777. 64 1125. 36 F,74,, 54 12 2. 8 432. 60 191. 56 176. 1120 800 00 309. 19 1402.55 9.05 269.321 12 1. 01.565.69S I1.1. ii.69,, 12 4LIM. 901 61,1::.,, :12-16oo. 00 103.02 184. 7: 34E., 41:I 1 7.81 187.,08C 15....,::,,73 .71 200. D1 7835 1.31.4 443s 566s 1. 0124s 467s.740s 1. 845 1. 822D.646s.000s 423s.751 s 9"725s 501 s, 1 .046s 1. 00. 2s.000s 501s:1. 549s 000S f a i I. s h a Up es t ... S .t are' a A ,oSF1 '-- 1 ,.1t: e :. 0 EG&G ORTEC G V -I ( 175) WAN32 I4WO2.96 2B-JLUNJ-E:0117 15:39-30 Pacoe Environmernta.l Inc Spectrum name: 17403, PnI...*- S U M M A R Y 0 F N U C L I 1 E 3 I N TIME OF COUNT TIME CORRECTED UNCERTAINTY NUCLIDE ACTIVITY ACTI VITY COUNTING P S P L. E 9 1 I G M A"-- * * * ..BE-7 K-4121 MN--54 FE-59 C0-58 CD-SOZ Z 1\1-- E,5 ZR-95 N.,1B-95 RU- 103 RIU-1 616--131 CS- 134 CS-137 BA.-. 140 LA- 140 CE-- 1 41 CE- 144 2. 8662E+01 7. 70137E.+01
- 3. 5681 E+00 4,5100E+00 1., 764SE+X100
.1 7 1 4+ 0 62 4. 01 7SE+0Z02 3. "121 E+00 2"0927E+00 -.0885E+01.3.3945E+00
- 3.
- 9. B,193E:+00
- 1. 9567E+01 pCi/L I TER W° 482BE-Z1..
1% 70137E+0 1:1; 68 8 4E'IIIIW&. 6884E+00 2,5 64261+00'47 13 E66.0 Q. 7304E+00 1". 3154E+00'-" 0257E+0(11 3° 176SE+01 1.2339E+01 2%8570E+00 2, 4982E:-00 2. 1. 651 !--01.4,. 1761E+00 10. 914E+01 p C :i / L I TE R 0 ( v .a u e l:)r i n t e , A Activity printed, but acti'vity ( MDA,........... .... -.. ................. S i I P R Y ........... ....TOTAI. ACPTTIVTY C 53. 1 to 2026. 1 keV) 0. 0a210000010E+00 pCi/LITEIR OT"AL DECAYEO ACTI'VIIT]Y ( 58. 1 to 260.62. 1 k e V 1 ) 0. 0001700ZE"--06 0 pi Ci/LITER.********* 1 LJ U M N.- R Y 0 F D 1 9 C A R D E ) P E A K S I:t.:r2- 5,4 CE .-. 144 145.44 & CE--141 834. 30 %,, I. 1 304.834 BA-- 140 328.76 L L.A-.140 364.48 % 1-1.3:1 477.61 & BE-7 487.02 % L.A-.L.0 497,.8 RU-1.3 537.3 % BA'-140 610.33 & RU,103 .,I1I. % 1t-- OG', 636.97 1 -131. 661.- 6EI & CS-137 72418. :1 , 2 )R.-.95 75EC-! % Z R-.95 765.79 NB-95 795.84 % CS-134 810.77 % CO-58 834. 8/4 & tN%--54 1.099.25 % FE---59 1115. 55 % ZN--65 1173. 24 g CC -60 1291.610 & FE-659 1332. 50" % O.-60 '4:a0 ..., 81 % W--.420 159 I. 1B % : .40.-Peak is part of a .tiplet- and this area went n e d~luri ngD d ec:-o nv ,1.ut i ,.n.e -- a..k :i s to(:) n arI -'OV4.SPeak s " u wide at FW'51:,, bEmt ok at F.H.M,% ... F.:eak 'fails sensitivity tesi.t.$ .....: l.- 1i nt if ie , bLu.t first ot e I- of i n.c. itdhe f ail. ]. o e d ;" or more qc: u&a I fi" i cati :i. o ' ; e "ts.-Peak. activity hi g h t L harn count i ng ',rcorta .et 'a r,.o, EG&G; ORTFEC B~ V -.1 ( 17 WAN32 4 4102.96 0 ) 2--jUL.--:20'I7 14:36:2 0'Pae~1.Samplce diescriptio F X W I t_ 1 3 iT5 T Sp ct u F-ilIT' a-'k A, DteXt ~c'tor'/G~eometry !Ds; I a I .E: 5 CEP I inputI 1 Cr e t ed .Li n-MiT aHrji E2l:T1. 13:6 4 & Ma ;- ?!0 M C-3 11-5!3 ".3~'r e! 0 mie I.- ;, : 2_5 I'S it wzt el in M Zero offset: QuIa dra~t ic-1.980i k eV Gain 13 Ma ~ keY/chnn Main l Jibrary PI)o s p3 iar iam te-Strt channel, Sto channel Pek e jecstion 1level: Pea s* earTch sensrC it ivity:;I Sampl.e Siz, Ac ivitye scaling faciV..tor .1201 fcv-' anf Eon:r g 121 L fa'41/ ` -1') 4 C 0 "ne g " f f-11 1 -n n 2iF -1. ;C 3.. 500G 3.5@1IOO2Ei+00) Bakron wWLEEIEJ'~Iidth best method (baedi:v an spectir'iio Peke backgro '~lun co rr ecti4:1on SI r ;~ i:v c ;I iI S/ r 2 25 C / iIi i .V St atl- u s'I Y ES N7 C.' J1T 1 z'52; .1. "'D 1 "eI2 Mg I. I//, NOC]N..O EG&G ORTEC 13 V -I ( 175) WIAN,32 14W@2. 96 02-JUL--207 .436:2 Page Environmental Inc Spectrum name- 17+13 An1 2 0 Energy c alibr'ation normalized difference: .0913****.-'.,.'**U N \ D E N T I F I E D PEAK CENTROID BACKGRILJrND NET AREOA CHANINEL. Eh!FE'RGY COUNTS U:CLINTS P E A K EFF IC I ENCY* AREA U M M A R UNCET FWHM r-SIGMA1 % keNt SULSPECTED NUClI IDE f- -f f- -f-+ +- -+-+-+-+ +- -+-f + + f- -f f- --1 -1, 140. 5. ., 9. 7_1.00. 1. 106E-.-04 40.. SB ,, 2. 027 PA .4 s Peak fai 1. shape t e;tS 1) Peak area. deconvoluted. "::**** -:÷**** I D E N T 1 NUCLIDE PEAK CENTROID CHAWNNEL ENERGY F I E D BACKGROUNDF COUNT S P E P K NET AREA CO U NT"S S U 11 M P R Y ****..-,,-- I N'ENS ITY ULCERT FW H1M C S-.', EC ii:::! SIDGMA % k..e CE- 144 CE- 14.1-131 BA- 140 LA- 140 1-131 WB-7 L A-14 RU-103 ,A-140 CS- 134 RU- 103 RU-106 1-131 u.r, .3: --[, MB-95 CS-13 I.4 ZN--54 FE..-59 CO0-60 FF K --40 D. I, S[3 'ea[: 27 .00 294. 41 571 1 00 60"7.00 662 48 7,31. 56 955.79 9"75.72!2 It 03 1222. 27 1241 1272.',,21 13 24',; ,43 14 5 Q;L 120.1513. 94 1535.75 1592..26 1624.9:: 3 9.S668. 71 22~i:00.53 D.2;-26,. 16 234.7. 79 L2F*8&,. (" 5;: 2 Cz; .-1 292 .30 31 C)1.,.C2 1:34.,28! 45. 50 28 It.. 07 30-2..! 0 329. 89 36 4. 5 4i'7C.6. 83 4.86. BE!496. 78 53'8° 56 6S10. 33 620.0.5 635. ,, 35 661. 51 724. 42 756. 4E 76'7.3,8 795. 0:3 812 ;:.: 06 8'33. 99 1113.27! 1.74. 21.12:90. 87 ,.-i'-:3. , 9,41 140.58.116.9& , 169.106.48.90., 52.6.1.137, 63.53.10.11.:t :: .1.6.5'7.12.F.594, 14.7, 597.i.-, 16.28 454.14.7.6.5E,.1I. 5.001...00 001.001 ,,006." 00-: ,,1823.004 QKZI 0 8008 003: 001 2(J63 001 0:81 001 026 02H1 3,3. 39 523'. 15 304. 14.4,41. 70 235.70 58 117'. ,87 99. 57 204. 77 213;-i--o 7 7.51.i,., 6, 117.22;2 1. 57 2 5 B '1.35, F!. 7 7 G";.6.000s7 61'5 s e 44s 1. 4 6 8000s I.45D 1. 848D 7 23 s i.9s.1.97 01 S 5,'1 ,,:1.927 ,,734s:1. 920 1'. s 7 .1. &41Z 339 1-'7" 6- , " deic,- n ;ap .. te:.,se .,,U ' ,'z .T do o-, n (1 v' 1".V 1 ] , :;, e Ci EG&G ORTEC G V -. I i 175) WA-N32 14W 0 2. 96 02:--.JUL.--2i007 14.36:02. G, P-ae E'n v 1 -on m, ntec,. 1 a I nc. Sp ecti'um name- 17413,A nI.0**** S U M M A R Y 0 F N U C L I TIME OF COUNT TIME CORRECTED NUCL..IDE ACTI V ITY ACTIVI TY U El S I N UNCERTA t NGY C;OUNT IING S. A.: M P L. W 2- , 1...I F* .* .pCi/_ .TL TER pCi /LI TTER pC i L ITER B E-7 K- 40 MN -54 FE-59 CO""58 CO--60 ZN-65 ZR--95 NB--95 RU- i 01 RU-.- 1,6 1-131 CS- 131 CS- 137 BA-1 4, LA-. 1[ 4Q C E.- 141 C E-144 A I.< 4,. 6663E+0ZI1
- 3. 0185E+02 S 3. 00@36E+00 4 4.=
- 2. 4285E+0OO 1 .3740 (.E:+00~4.1 E + 00< '4. 3139E+00 Z"4 429! E+00 ,. ,s3. 294 5E+0 1 1 3. 951 .GE+00 5. 8056E+0 I1 S. 9929E+.0.
- I< 1. 0558E+-0 I* 2..1.S I 14E +. 00 6. 5223E"E+00i 7-,
5S 9746E+071 3.0185E+02 &. 1330E+ (.71.Q;, 1257E+01 2.9240E+00 1., 3.83,,4E,+OQI 5.9273F.-E+00Z &@441.4E+00 &. 2805E-+0 6" 1942E.÷-00 5.4414.5E+ 01.,2-. 0 06E+0.1 5 90Z79--E+01 '7. 0013E'+0 1 S. 92:61E'+00
- 9. 7807E+00 E'?, 437E+0 t 6. 067E-H-01 4Q =E-+00 6. 875E+00 Acrtfivity pr 1-inted, tut activ ity ( MDA..S ! M .i' l -: ! V TOTAL ACTIVITY ( 58. 1 to 2026. I. keV) 4. 2983080E+02 pi./LITER TO AL, I)ECAYED ACT'IVItTY ( .15.1 to 2026. 1kV) 4.. 30e9.274,0E+02 p'i.L.]:TE F 328.76 &4-97.08 %636. 97 &8:10. 77 &1[17,3.24
%S U M 1 CE- 144 LA"- 140 RU- 103 1-'131 CO0-5 B:.::-60 A R Y 0 14,5.4.4 364.4.8 724. 12.1 :.,. I +B3. 84 ~-1291.&/"%-D I S CE.-.1 41 1-131 B A- 1 MN-54 FE-.-59 C A R D E" 284. 30 610. 33 1099. 25 1332.50" D%/%"%-9"&.P E A:: 1- 131 BE-'-7 FIAl 1 3 Z [R'95 F1 -59'302.n 84 & BT-.!.40 4,B' 7'.~ 0;-- LPA-- 1 .4 r17 4-. 1. ,"- 4 1061 765 79 & N-.B--95 111I.5.55 & ZN-65.:1, 5 9 G :[8 & LA.-14.Peak i part of a ml].tiplet and this area i ent nega'trive during dec-onvolution. '? -pe'at.( is too no.-._..-'r".C1" '.,@ -Peak :is too widle at F:'2N:S, WA ..,.I. ok at[ F'HV,4HM% Peak fails sen.itivity test,$ Peak identif)i.ed: l,,, but fir-st" r.: iteak'.f t"i -uc d: failed one or more qualif~ication' test.Ls.Peak act ivit y h~i~gher ...than cou--t ing; un.:i:ra T'ty -angr-e,, E~n V J. tr h M it =,I I nc S EýpeC't r UI! na m c- 3742,E-5, fAn 1 CIip I e de sc cmi , T'XW L34 5 L.ITER 1-3 -~ IJI .-.217i7 12 7:17 l1 0 Sect:rumr F i enam e C:\Lie "\ 37425.Ani Live time 95011 Real1 time 3512 Deafd tim1 e .12%D:e t:ec.tor /Geomet ry IDs 3 5:1 DetectIor-syste MCB I1 Inrput 3 F~il enme: D3g I Cl U: Created:- 1 4--Ma--2)@7 1 4:21:31 & 1 4--Mar---5)7177 1.4,5 .42, MG 023 GEOMET~RY
- I 1 3. 5 Liter in MBIl Z..ero o)ffset: 110 liei I Gai( n .500)7 ke ch r 0 Li bra~ry Fil1es Min analys' eis; l.i bra--ys Libr.-zo-y 11..tt h W4idthi-Peakc r eject io flelIvelI Peak searc snitvityi:
Ac~ti1vit y scal-- 1ing factor 21:. 1 U I 120 for- an en ergyj of 59. 312IeV 40,6,8 for an)COeoj* of I2r4 173V'307. 000217%3. 5001!.@@@077E--06Z1/ ( 1 .17301I0 E'- +I e1 -x-1 3. 5AI00E00 2. P, 57 1 E 0 5 n, I -m i t II--* -mI) l et ld RIS m ;i ei thUodc Addi t i on ' -Ta- I II er-rOV t 1.0000000/I71e~~'E-l-00t Ad it o a nys.'*temat i.c error: 1.0000000l11I2i7E-+00717 Fra tio L:im rit- .0074 Baeckgrouv~-ndi wiLdths' best; method (e.! on sepcct-ruilr .1)~~ t'Deci q du ig : etjyýPeke bacgrun correction1 Nic YES--Comments~.f~ 4 12 Ci.,....1 1 2 Z / "." A .1. Zi ! EG&G ORTEC ( V -I ( 175) WAN323 14W2. 96 02--LJL-2007 11g55:12 Page Environmental Inc Spectrum name: 37425.Ani Energy calibration normal zeri :d differenc~e .,14 84 s**..***~*** U N I D E N T I F ! E D PEAK CENTROID BACKGROUND NET AREA CHA!NNEL. ENERGY COUNTS COUNTS P E A K EFFICIENCY
- AREA S U I M A R UNCERT FWHA 2 SIGMA % keV SUSPECTED NJUCL 1 DE 476,, 28 137. 720 238. 07 568, 85 609.39 180.67.6 1 171. 1. 001E+04 105 1. 175E+04 47. 5. 559E+03 51. 93 34. 36 5,4. G3it 1. 579 PBI-212.990 P4-234 1.3363 BI-214)s Peak fa il s shape tstS.D Pa;rek are deconvoluted.
- i**********
I D E N T I NUCLIDE PEAK CENTROID CHANNEL ENERGY F I E D P BACKGROUND COUNTS E A K NET AREA COUNTS S U M M A R Y ************* INTENSITY UNCERT FWHM CTS/SEC 2: SIGMNrA % keV....... i.- -+CE- 144 CE- 141 1-131 BA- 140 LA-140 il.E_ 7131 L.A- :L40 RU- 103 BA- 140 CS- 134 RU- 103 RU- 106 1-13!rCS.o 137 Z R-9 5 R N3-95 CS,-' ! 34.HF-5 k7-ý- 1 -4 iF[--59 Z~ 11. -S L A 1 267. 00 291.59.571.44 610.@0 655.40 727.84 956. 15 97.3.50 991. SQ 1073-39 1209-942
- 1220.68 1246.07 1271.98 132. 69 1/i,4*7. 0O 151,3. 223:':1529o*71 1591-30 i2 1 o 196'1997. ,55 247.725 2.9 2 .. 7 2,*:.- 5 12',B. f-,7 (33.42 145. 71 285.66 304.95 327.65 363. ,j7 478.05 4W6.72 495. B8 6!:04. 70 610.3.3 62Z. 03 S351 99 661.35 723-51 795.67 1113..62 1173.68 i;2.':1. 5 C 1460.93 110.385.153.53.93.its 53.18.43.198.51.113.030 .65.15.5.9,.1 a.71.43.11.30.15.28.0.19.18.1 9.4.541.0.I 6.,:440.7 11.s.13.007.005 001.003 002.3 1600 13002.057 0 34 6 012) 1 000.000 022 00W 501. 73 176.39 1 7 5.27 24G. n9 334 5.38 141% 5 848.53 236.99 192. '97 8. 47 313, 93 10. 76 600. 00 123.,76-11..1. 26 3 160. .'00 724. 19 24&. 37 177.95 447.21:92,.26 157.08 500s;.781 s.720s.5012s 1. 017 G 37 s.611Ts.583s, 1.333.526s 1. 3601D 00100 1.12181.576LsE 1. 4-46.167s.915s.642F 1 ° 599.535s.000s i. 105s.458s.438s.4,53s s Pe, k f i1S a r. e., shape ,ests E'C-o ORTEC s G V -'I ( i.-.,5, I.4WO2;' 96 02-JUL-;'2007 1 2 Pa e S U M M A R Y 0 F N U C L _ I:D E S I N TIME OF COUNT TIME CORRErCm ICERT "IN'YY NUICL I DJE ACT I V I TY ACT I V I TY COUNTI NG S A M1 P L. E;..S."IG'°iA" pCi /LITER BE'-7 K-40 MN-. 54CO- 58 CO:-60 ZN-6,.5 ZR- J NB'"95 RU-" 10¢3 RU L- 106 .:.CG-.. 13 CS-. 137 BA-I/+0 W..¢- 14.0 CE-: 141 CE-. !.44.NP 7 2. 7357E+01 2. 93998E+02 1 1,94.6,8E+q00 ( 3. 0231 E-t- 010< 1. ( '34 El .7 F:, + 21.i 21 , 5. 3479E-.'-'1
< 3. ":4661:.E+00 1 2. 0 1 212,OE+.,1 2 8. 99481:-+00t 2 .2 3800E.+0 1 G. 9 35E+@'- I Q, 4169E+01 1.I 5411. 1 .2800E+00.{ 7,670 4,E.'+DD 1 .939SE1.0 1:' A lu pl.i, nte~d.p C i / L I TE R 3.47,/97SE+~.8 9*, 4..:998E+02 EN 2594E+00 2. 5005E-+071 5.64,28E.+00 , 2525E+-2. 2.2.9286E+0@
- 4. ~IC:2OE-Fi21S EN 4661E+01.2!. 0,36-E-S01 6.2 877E+01 6. 42E46E.I-O l 4.2+,94E>H2
- I1 2L 5708E+-0.I0 1.1475E+0I1 2n 02U9E+01 pC'i. I I TER 5. 714E+01 4.,, 539E+00 6. 946E-.'00 A Activ:ity prin. 'ted, but activity -. MDA." ............
S U -MAR Y ....... ..... .......TOTAL. nr I V TY ( 59.9 to 2024. 1 k e ) .4, 25_ 2-- pC i .: r5 p TOTAL DECAYED ACTI V : Y( 59. 9 to 2 4 " e V 4. 27106 1 W.Z' p .. /I T-- 3.-."-. .--... :~S U M M A R Y 0: F D ! S C A R D E....54 % C 145.44 % CE- [ ...o14.1 2 4 328.::~ 76 & LA.'.-...4-0 3-64. 4.8 '% 1-.1.3.1 4.77.61,J 497.017'8 & RU}-10 IZ-5:37.3;..2 "%' BA..,14-0Z 636.97 & .-131 724.8 1% ZR-95 756.72 810,, '% C :58 83.B,4 % MN-54 I.99.25 i 1.73.,24. % CO.-60 1291.60 % FE.-5'.1 13$32.50 13 D.P E: BE.--7 R*1 UI. 1 -1 'I Z R-95 F" /I 5 L0--6 304. B4 % 13 A..-. 14 ;4- 21 7. % 1..R. 14.., 0 S21. 2' '7 & I-J 1. 'j C'..765. 7 .& N .-9 t5 _y-.,, y---- _-'---.--- P I :is part of a i , ,t ai ti Ll Ar'i.:. a wen:;negati ve.- durJYing dec~on;voluttion., 1-... .:, e +a k-' i : t o ,: -3 'Yow , i ...Peak :is_ too wide at t::W2:5M, but ok at I:W'HM."% -.. P:eak. fai:ls s:e'nsitiv~ity test.$ -. Pea!. ide t .tif'ied, but f:i st peak of thi.s n ,..ide fa,::.ilIed on,':, e orY more Y , q u.alif':i c._at io n S- Peak: act:i.ity highe than counting unirc:taiT'ty rang]e. O EG&G ORTEC G V -T ( 175) WAN32 14WO2.96 28-JUN-2007 35 35 D4 Page ron mvient al In c Spectr um name : 3741 F,- v1 I I Sample doecri pt ion TXW-3913 LITER 13-JUN-2007 13: 13* fMS Spectrum Filename: C \U ser,\374IS. PiAnl/ .-c)Acquisition information Start time Live time Real time Dead time Detectorv//Geometry IDs E-Jun-2007 13:.17:24-8251°33%0~Deotect or system MCB I Input 3 Calibration Filename-D3g,. Clb Created: 14-Mar-2007
- 1421:31 &. 34-Mar--2007 14:50:43'M-1G #23 GEOMETRY l 1.3.5 Litei- in DB Zero offset -.110 keV; Gai n Quadratic
-. 1250 7 4k- V / c h a n n e I ".Library Files Main anal ys is s ibrary 2 L.ib-braorry Match Wid dth:.500 keV/channel. 5 l VI Analysis parameters St art channel.Stop channel.Peak rejection level Peak search se'nsit ivity: Sampl e Siz ze.Activity scaling factor 1:l for an En erg y of 4042 for an energy of 30.000%2024.09keV
- 3. 507 .1 I. 0OO0E+06/( 1. 8000E+0010-3,, 5800 0-00)=2. 8?570E+05 Detection limit method RISO met~hod Additiona rand t i o n 0 )- '. Vdomi err)- or2 v,0 E+Additiona1 systematic error: 1i,0000000WiE+
Fra ctio Limit: .000%Background width: best method (based on sp.:trueK Corrections Decayd conrn reCt to date')a'r'eye during co llectiion Peaked backgraound cor'rect-ion St at us Y EF -," NOC 0- V --.- i23'07 1 !4 3 04 4 ~0 EG&G ORTEC G V -I ( 175) WAN32 14W02.96 28B-JUN-2007 15:35:04 Page Envi ronimenta;-il Inc Spectrui name- 37416. Ani Energy calibration normalized difference:
- ~i*****U N PEAK CENTROI D CHANNEL ENERGY 1 C E N T I F I E D BACKGROUND NET AREA COUNTS COUNTS P E A K EFFICIENCY
- AREA S U M M A R UNCERT FWHM 2 SIGMA % keV SU1. SPECTED NUCL IDE+-+- -+-+-+--++---
-+-+--+-+-+-+-+-+-+-+-+-+----
+--4--+--+--+-+----+--- 185.23 371. 29 703.96 1218. 45 2240. 05 92-52 185.57 351.93 609.22 1121/'. 08 196.136.99.33.15ý145.119.76.76.31.9% 531E+03 6. 045E+03 5. 921E+-03 8. 935E+0-l3 5. 705E+023 57.09 58. 39 55. 14 31. 31 50. 26 1.398 PB-214 1.853 U-235 1. 1057 PB-214 1.362 B1-214 1.650 BI-214 D D s Peak fails shape tests.D Pea.k ar-ea deconvoluted. M Peak is close to a library peak.***~****~..>:.**** D D E N T I NUCLIDE PEAK CENTROID CHANNEL ENERGY F I E D BACKGROUND COUNTS P E A K NET AREA COUNTS S U M M A R V ************** I NTENS ITY UNCERT FWHM CTS/SEC 2 SIGMAI% keV CE- 144 CE- 14.1 1-131 BA- 140 LA- 140 1-131 BE-7 LP.A- 140 RU-!103 SBA-140 CS- 134 RU- 103 RU-106 1 -131 CS-' 137 ZR-95 ZR-95 NB-95 COD5'MN--5z4 FE-59 ZN-65 FE-59 K-40 I. -1' 4- O 28. 66 290.64 5E7. 07 6019.39 657.03 730. 75 955.00 975. 17 992. 5'5 1076.39 1209.42 1220.68 1243.o16 12.74. 2C-1320. 78 1513. 11 1530.97 I 5.:'i9. 2:1 1622,,00~16821 220 '21 2230. 99 2-34,7. 2 7 2522.53f91 67-3192o812 134,25 145.24 283.4,8 304.64 328. 46 365.33 477.47 487. 56 496 538. 18 604.70 610.33 621.57 637. 13 66'I 39 756.S,57 765.50 811. 02 1100. 15 1.11.555 11.73. 99 1291.3 1331,I"oB 159j 4.49 154.204.I16.56.53.1-74.15.:3;2 36.26.2 .51.15, 110.10.71..t!.I1.47i MI.37.31.25./11 5, 17.21.5.0.16.5, G.12.14 .5.013 002 17.1014-Z 004 001 7i 021 001 t17102I 002-003 001 000 V00!0101 004 0101 I,.1 I 'I IZI2 142. 7 -.87.7 117.52 132.69 161.62, 289. 50 774.60 392.52! 31. 53 I.0. 73.00 1.23. 40 280.31 236.55.000 16,9.97 1,47. .52. 49 565. C9 139).00 I1E3. 43 790. 48 180.28 JI. (Z1. , 6 94950 187. 08 1. 459s 1. 579-;.977.942s.684s.860 o000s...436s 1., 746s 1. 28'!9s 1. 3601).294D 347 641s.,696-1* 4'1 :i4.82s 1.73s 2. 059:'s 545s 750,;.542s!.648D1 844s I. 79'3.725s 2. 057.676s E6&G ORTEC G V -I ( 175) WAN32 14WO2..96-' 28-JUN-2007 15:35-15:4 Page Env ironiment al Inc Spectrum, namieý 3741, fAn1 ePak fa-l. Pk shape tests.D Peak ar'ea leco-nvoluted.
- S U M A R Y 0 F N ULC L I D E S ]: N TIME OF COUNT TIME CORRECTED IJNCE"RTAIINTY NUCL IDE ACT I V I TY ACTI V ITY COUNTING S A t P I E 2: SOIIG MA* * * * *pCi/L.ITER BE-7 K--40 MN-54 F E-5,-9 CO-58 CO-.60 ZN-65 ZR-95 41R-1031 RU- 106 1-131 CS-134 CS- 137 DA- 140 LA- 14.0 CE- 141 CE- 144 if)( 1 82 I. 0E+0 1 2. 9357E+02< 3. 1890E+00< 4. 8372E+00< ;E2. 6415E+00< 2. 5234E+00 ( 4, 9611 E+00< 4. 07--76E+00
< :2. 7900E+00< 3. 1591E+00< ,,7467E'+01 < -, 454E+00 K 2. 5938E+00< 2. 9287E+00 1. 084.9E+01< 1. 44,S IE+0O< .6 4444E:'+00 -' .54, E. .E t -i I P vNalue privi.tei:,_ d, pCi/L ITER F. -I- . -+ -+ -.En213'4E+0121 EN 9557E+02 3, 970E+00 5, 1103E+00 3, 0593E+OC0 EN 5371 E + 0Q& 1772E'+00 1w, 7380E+v00 3.7534E-00 4, 1171EF£0.0 3: 8254E+-01'1 1.. 515.E 0 21.2" 6;-29E+0121 2h 9315E+00 2. 4509E+0 1& 2715E+00& 8"746E+01'4ý
- 2'. 6 37 8E +0!I~6. 117E+01 pCi/LITER A Activity printed, but activity K MDA..-----------------------------...........
.. .... .... .. .. .. S U M M A R Y ........ ..... .. .... ... ... .... .. .. .TOTAL ACTIVITY ( 59,9 to 2024. 1 keV) 2.9556950E+02! pCi!L.-ITFR ,TOTL DECAYED ACTIVITY ( 59.,9 tor 20224. 1 keY) W2. 9555-G95,'1E+/-"0... pCi LITER:*.****** S U M M A R Y 0 F 13. 54 & CE-.44 145.44 %P28.76 % LA-140 36'4.48 &4.97.0B &I' -RU-103 537.32 &621.84 % RU-106 E36.97 %7' , ,,.% ZR-95 F7-.. 7 79 %.834.84 % I-l54 1099°. 2i? &12:91.,60 "% F.E--59: :1.332. 50 %Y D I S 1.D ; F -P -3. * **CE- 4.1 2184.30 & 1-131 34. 84 % BA- 140-131 477. 61 % B4-7 ,.97. 02 ",% IA-.40 BA- 14.0 6C04. 70 % CS- 134 G10. .3 & RL- 103-1-31 681, 6E & CS- 17 724. IS % Z7R--95 NB-95 795.84. & C -; --13 Z!. 81,0. 7 7 % C:O---58.9 FrE-59 1.15.55 ' ZN-65 H73. 24 % CO.-6 SC-0-.. 10 1.5Egel % [ LA--1 ie-k is pay't of a mul.tiplet , and this area.- we'nt n ,ative durig deconvolut ion.;::', 1-4 iarroto Peak i-s tooat....... .-.... ... .'but.. ok at FWH .% ...Pea --f!. :a:il .:.s sens; ;i.t ivity t .e s ::, 0 EG&G ORTEC G V .- I( 175) WfAN32 14WO2.96 28]-JUN-2i007 14:22:20 Page Environmental Inc Spectrum narpm manes 47317,7,An1
- 1.Sample, d:ac r i pt i on TXW-3912 3.5 LITER
!PD!57 AMS Spectrutii Filenam e: C:\User\47317. An1 Acqis ait ion~ Infornmat i on Start time 28-Jun-2007 11.,'.28W2O Live time 10431 Re a t i m e., 10444 Dead time .Tn.Detector/M.3e!o inetry IDs 8" &/d 1 0~Detector s ys:t e MCB I Input 4 Cai brat i on Filename D),q. CIb Created: 14-Mar-2807 15056:023 & 6-Mar-2207 15 !2'31 MG 23 Geometry 4i41 3.5 Liter,, in ME, Zero offset -.130 kePU Gain uadratic -197 1 7 7E-17 eV / C /ch.nn T Il2 Library Files ain anaysistlibhrary, 2 LibaryMatch Width,:.50 0 k e V /ch anne 1 i t:1 5 li.bo Analysis par~amet ers,-Start channel.Stop channel Peak rejection level Peak search sensitivity, Sampl e tizet Activity scaling factor, 120 for an energy of 4048 for an energy of 30.000%59. g9koe1V 2121.4.14keV
- 3. 501,-1. 0000E+0G/ ( 1 o0000E+0-3E 50O1E+80)=7 2. 57E+05 Detectioion limit it method: RISO method tAdditionca1l random er r or 1.. 008000E+0 Additional systemtaatic erroro 1.000I0l0E+LOOl Fraction Limit- 11911%.Bac:
M U : M. bteh: be .-.st method (base-d 1ni spectIr.um)., Correction; Decay correct to date Decay duering acquisition Decay dhuring collection Peaked background correction St at us YES NO YES3 Comiment s 13-bur-207 1k: 4: w.Lik r '*wo
- bCt(2.0-Apr-287 1 42 Ohwn"nhinn lTntpvnAl'i
- EG&G ORTEC G V -I ( 175) WAN32 I4W02. 96 28-JUN--20.17 14:22:20 F.ae Env ironmental nt.1S Inect Srp ct rum nae, :, 47317. An I li:.Energy calibration normalized difference:
- 1. 000 0 uN PEAK CENNTROID CHANNEL ENERGY i D E N T I F I E D BACKGROUND NET AREA COUNTS COUNTS P E A It EFF TI C I ENCY* AREA S U M N A R~UNCERT FWlh 2 SIGMA % keV Y SUSPECTED NUCLIDE 1021.44 510.72 80, 139. 2.457E+04 31. 77 2.498 TL-208 : s Peak fails shape tests.D Peak, area deconvoluted
.**..******-. x** I D E N T tI NUCL. DE PE.AK CENTRO I D CHANNEL E"NERGY F I E D P BACKGROUND COUNTS E A K'NET AREA CO.UNTS S U M 11 Ar R Y ****y ., I NTENS I TY L.UN CE RT F:'WHM CTS/SEC 2 S1(..M. :/% keV 3 1.-~f+l...........+*--I---~+........I--I--A.++A.+--+--+--+--+--4--4-l---4---F-. CE"- 144 CE- 14 1 1.- 31 BA1402 S1 A il40 BE-7 L._A -1:.40 RU-- 103 B A- 140 CS- 134 RU-103 RIJ -. :[ 4 RUC- 1612 1-131 CS--137 SR--951 Tr-.95 CC---, 5 8 M N'-"54.C. ":, 1,.1 F"E-59J : CO-"tE,81 L -A -1 ....266. 75 292.24:L.4 5,7. 17 612. 8,3 E59. 00 730.,, 00 954.~<~00 973. ! 4 992.20 1078. 75 1.207. 46 1220. 62 1.242. 00[273,05 1.3 .ý I -,A .1322.00 1 450..57 1.514.00 1528. 54 1588. 96 1 (-.2 24..3 7 1669. 24'9 4. -.+4 2584. 00 2'9 2, 0. 1.i1, 00 133. 28 146.3" 2:83.53 306.36 364.97 476. 99 486.56 496. 10 539.38 603.75 610.33 621.0 2 636. 55 661. 03"72:5.3'"2 764.32 794.53 812.24 834.68"10Z97. '3"2 1113.88 1 2 2. 11 1. 3.3 32. 2 1 460.2 !159.J S3.. ..213.57.C8, 3&.1V 24, 64.33.55.31.1.7.G.-, 217.17.9.5.10.1&" , 14.12,, 0.16.1 4, 5.0..11.:1. 2:.1 5..:.0.1, 003 002 0 000 002 000 8000 1 00t 002 002 Qt 002 201 000 1210 :5 1000 000 001: 001.001;-001 001.000 216. 79 30'i. 35 1060,, 5 197. 72 1289.96, 9 24. 62 97.6 200, 17:I. 34= 05 1 6. 17 010 220.:E,,69
- L631. C,4 4"70Z.34 16 .. .3 !~,::,,1.4 P:1,6. 7 B.1.2"9.21 1 91. 1 4A7. 21-i, (3I I 7 254.71 i 0'5 .71..1210 1. 173.532s 367s 689!;,.000s 167s 713s I.861:, D.204s.6E51s ,333:-,.000s ,514-.: 1, 480.89; -2S:I..293s 1.t 14,75 1.67s 780s 1. 86"7s 0 00. .-e k , -ei d c o r 0 "t- e d.0 __ _ __ __ _... _ ...- _... -_ _.- _ __ _...
EG&G ORTEC G V -I ( 175) WAN32 I4WO2.96 28-JUN--2007 14:22:20 Page E ro nr inenta Inc Spectrum nam e: 47317. A)nI1 NUCL. I DE SUMMMARY OF NUCLIDES IN TIME OF COUNT TIME CORRECTED UJNCERTAINTY ACTI V I TY ACT I v I TY CO U NTING S A M P L. E 2 S)I GM1A pCi /I I TER pCi/L ITER pCi /1L I TER 4-- + -"- " + --+ -÷"-- --4 -÷ -- '- + + --.. --+ -------'.. -+ -" +---- ---+ " +"-- -+ -'++- " ---+'" -4. --÷ ---+ -+ .,+-- --+BE-7 K-. 40 biN--54 FE-59 CO-58.ZN--65 ZR--95 RU-- 103 RLJ-- 106 1-131 CS-- 134 CS- 137 BA-- 140 L A -14.2Q CE- 141 C E- : 1.44 2. 7630EW.0!1. 0076E+02 3.9634.E+00
- 7. 1148E+00 4. 9184E+00 3. 1199E+00 7. 1670E+00 9. 3722E+00 4,, 3607E+00 ,k. 472SE+00 E 79018E+01 3~. ":379E +020.1. 5985E+01 3. 349.3CE.+01 X. 3593E+0:1I
- 1. 0076E+M2iE:
4-,, 0979E+00 EN 9899E+O0 511 6973E-00 3. 1368E+00 7. 4796E"00 1. 1028E+01.5. 8687E+00 7. 1 349E-.00 Et 8709E+01 1. 2591E+0-1. it 607 1E+00 2'.923S7E+001 24 5922E+01.L
- 5. 3382E+00 1, t210E9E+11 1.z740E7+O 1< MDA va.kilute printed.A Activity printed, but act:iv vity < MD)l.TOT-ALe C ACTrVITY K 59. 9 t o 2024. 1. k e V) 02,. r211001271;IE41E+12N0 pCi /L I TER TOTAIL. DECAYED ACTI1VITY K 59.'9 to 202,4. 1 keV) 0.08010L4E-+.00 pC : /L.] I' :':..R******.*-**
S U! M M A.133. 54 % CE---I44 32a. 76 % LA-40 L7. 0 &.1I RU.-10 62:1.24 % RU-..106 75.6.72%ZR9% 12'91.60 % F:-E-59 R Y 0 F D I S+,J, -44 % C. E I. ,. 1 364..48 % 1--131 5.37.3'2 ,:& DAB -140 636.97 % I-131 75.79 & NB-.95 1.099. 25 & FE.-.,59 1332. 50 % CO.-.,.-0,. C A R D E 284-. 30 4 7 7.61 60.:. ,70 661.,,66 795. 84 1. 1 5.5 1460 81 D P E" ,.A K C S- 1 3 4%CS-"134 gZN-.65 K -..-. 48.304. f4 g BA-i1 4 497. L A L . 14.0 ,1. ' RmU- 10-3 73 24. 12 Z R'--95 F:l gn 77 &C0-528:11 .73. 24 % W0116 S-Peak :is pa'rt of a multiFlet. and this are.-,z- wenit negat:ive du{r~inrg dec-onvo]Uttion. P. ... P aik is- too n-a',rrow. S-Peak i~S 't~O, wide at F::W25M,j but ok at' PWHM.,% -.Peak fa il- s s e'--s:i.t i vi.t y t est.$ identified, but fir'st peak .of this nu$.-]i,:: fa-.iled o:,ne or more ion test .,-+ ....Peak' ac~tiv:ity higher thanm counting ,unrcer:t~ainty r'ange. 4 E0%&G TEC G V -I ( 175), WArN32 14W2.9 14I:00:26 Page Erviconmental Inc., ecr nmam ii ,,: :73:. Rn I.Sample deo(cripti-)n TXW--..391
- 1. 3.5 L.IT.ERF 12--JUN-W-207 1:3(1 ANMS Spectrum Fi]1ename.
C.\User\ g73E2.An1 A-cqui it i on inf-ormat i:on Start timle 28-Tr.3n-'. 7 1.376 Live time 10001.Real time 10015 Dead time ,, 14%Detector/Geometry IDs 8 &-q -~Dt et etor sy s.t em MCB 5 Inpiut 4 cal. ib rat i on Fi I ena. me : D E...1 I1. C I b Createcd: 14-Ma r-.2007 15:20:41 & 15-Mar-2.@7 12607.CO6 MG #23 Geomet rv y #1 3o5 L.it er water in ME Zero offset .105 keVq Gain Q uad rat i a .3...-.7 .<e / k -h an no .', Li brary Files Maivn ana].ysi lii 2 Libhra ry Match W4 idt h Anal.ysis paYram et ers Start channel 12;2) for ai St orp channe 1 4048 for Peak r, eject ion level 3. 0000%Pe-ak searc,::.h sensitivityit S Sample Size;A-ct-':ivity s.calin f torl: 1.00i0ilIF--IE+i .500 .l<e /c:hanne 1 I I i b.50 f2-energy of 60. 1ikeV en o: ne'gy of1 ;E.7l;L::>,3( 0 V<e W16 ( ! O002E+00*
- 3. 50riE+.00)
E], 5 7 1571 £E+-t5 Detecat ion limi i:t method : R : m S ethod Addit i onral ranc:om erro'r" I. @00000E+0@ Ad d it i onal , 1 v at em at i c ev-.rror: 1 0030300E+00 Fract i on Limit ,,000%Background width: best miet-hod (ba:ased ,on spec.atrum ), co o rrec t c:' 1. i on s Decay cov"-r"ect to date Dec:,v dur ing a Lqu:i, sit:ion Deca. v C :.N inn C '. .L e Ct i on Pea: ..ked backgr ound cor rect iconat-U Y! E_Y E!--, N. 01 YE C I in n'i e i t .-)A :.i .2312,Z7 1.3 33 0933 0 u ::u I: Cu Ti I ii t OuF I 2.0 EG&G ORTEC G V -I ( 175) WAN32 14W02.96 28-JUN-2007 14"00:26 Page Environmi ental Inc Spectrum namue: 87392. AnI Energy calibration normalized diffeorenc e: I 00121&**.**.****** JU N PEAK CENTROID CHANNEEL ENERGY I D E N T I F I E D BACKGROUND NET AREA COUNTS COUNTS P E A K EFFICIENCY
- AREA S UI WI M A R UNCERT FWHM 2 SIGMA % keV Y ***********
SUSPECTEDMi NUCL I DE 185.32 703.44 1021.30 17 :17 72E 92.76 351.80 510.73 608. 94 304.133.7 9.126. 9.517E+03 136. 1. 168E+04 222. 2. 531E+04 81. i. 061E+04 56. 08 43. 94 24.25 30.86 1.324 TH-234 1.51.0 PB-214 3,248 TL-208 1.793 BI-214 S s s Peak fails shape t ests D ):1eak area deconvoluted. NUCL.I DE EAK CH1AINNEL CE- 144 CE- 141 1-131 BA- 140 LA- 140 1-131 BE-7 LA- 140 RU- 103 BA- 140 CS- 134 RU- 103 1-131 CS-137 XR-95 ZR-95 NB-95 CS- 134 C0-58 MN-5-4 FE-59 ZN-65 FE-59 CO-6 K-40 1.-1, 4 265.98 293. 08 569. 99 657. 36 727.49"I51. l3 971.82 994.09 1073.,00 1209.24.1220.,50 I 4. 9 8 1272.67 1323.76 14"49. 55 i517-36 1531. 70 1592.83 1619. 85 I1E72. 9 2 29 5.8 9 2233.00 2584 IT!012 2920. 84 31 "'3J4, D E N T I F CENT.%JIRO'.'D BA ENERGY C 133.08 1%. 6.3 285.08 3728 76 363.83 475.79 485.99 497.12 536. 58 604.70 610.233 G621. .0 7 636.41 661.96 724.86 75a.77 7654 9A 796.50 810. 02 8i36. 56 11098 ý07 1116.63 1.73 -14 1292. W-, ,.3,J(, 1l 1460.61 I59r7 z56 I E D C0KG ROUN EL OUNTS-l----+--+--4.l----1----l----l~--+--~4........'-I---.-,-...+.--.+-~+.--..+.-.+ P E A K.NET AREA COUNTS U M M A R Y ************** INTENSITY UNCEERT FWHWM CTS/SEC 2 SIGMA % keV 161.183.130.30.681.53.53.2W.45.45.104.37.37.217.22.218.15.27.:1.0.15.3.7..7'3.16.7.17.0.0.15ý13.17.8.0.12.1.16.14.17.15.20.4.I 12,'7.a .)151.002j.001°@02 1000 000 12101.00 1..0011 002.001 002 001.001.002.000 12081.002 000-000.002 229. 81 609.139 264. 10 1039 .23.00 136. 03 217. 90 159. 39 1034.75.00 170. 49.388 44.175. 92 163. 0126 107.62 122. 015 i10.1. 960 E.73. -."33 134. 33 390. 90 145.75 1 ,,72 31,3,. *7;9, 14'. 4.!V 17. 03 29t 65 17. 76 63.6.663s.4/80 1 001.s 000s 000D 566s 713 s-7:1. 1.79OD.71 I 1. 794D 456s.67s 988S 98s f39..-.1 04. /1.376s7 417.s.4512s 1. 575s 1. 015 1s 1 .IZ'7 5j D F..,:. aresa Si 0cOOon o tt ed. I &G ORTEC G Y -I ( 175) WAN32 14W02.96 28-JUN-2007 14:00:26 Pq-kge n ,, iro Inc Spectrum name.. 8(7792. Ant-** .1 M RY 0 F N U CL I D E S I N TIME OF COUNT TIME CORRECTED U1NCERTAI NT Y NUCL IDE ACT I: A i Tr ACT IV I TY COUNT ING S A M P LIE 2SIGMA.Y... * .* *pCi /L I TER BE--"7 K--47.0 MN-154 FE-59 C00-58 CO-60 ZN--65 N B-95 RU- 106 1-131 CS- :1. 34 CS- 137 BA-- 14 0 LA- 1.4-0 CE-.,14.1 CE- 144 2. 7705E+01 4- 2.4204E+02
- 3. 1437E+00 4.8075E+00
- 2. 3375E+00 I2.,,2586E+00
.6792E.-00 5.6932E+00 2.4877E+00 ..3799EW00 29673E+01 3.5223E-+00
- 3. 2073E:+00Z
- 3. 2613E+OVI 1 1. 179 E..01 1 1.88479E+-00
- 5. 7065E+00 20. 4034E+01 pC i/L I "IER 4.1204E.I-0;.
it 575EvD1, E. 1595E+00 2.7343E+00
- 2. 2717E+00 5. 9437E+00.6.7714E+00
- 3. 414GE.+00 W 1577E+00.058E1+01 1. 40+60E+01 3. 254.9E+00j
- 3. 2646E+02.08165E5+01.
4, 5069E+00 8E 0304E+001. .4.989E+01. p Ci L. MI TER 60 196E+01,# Alll peaks for act iv it y Calcu I at i on h-ad 1.,-1d "-Ac:tiv ity omitted from total& Activ:ity omitteod from total .--and all pealk.s had bad shape MDA value pri. nt _ed.A Activity printed, but activity MDA.................................. .. SLJM A R ...........-. ....TOTAL ACTItITY 650. 1 to 2024.. 4 keV) 2. 4 ;2! 040"2-3E +02 pCi /LITER.TOTAL DECAYED ACTIVI'T'Y 6 03. 1 t o 20.2,4. 4 k e:.V) Z! 4 c*-' 0 -402-': '+'0 E0 pCi / LI Tf R S LU M M A R Y 0 F: D 1 c6 C A R D E D 713. 5 ' -C E..--- 1 4 14.5. 44 & CE-1.4I. 2 4. 30. %, 32:_8.,76" ? L,,A.-.14.0 364.4-8 X 1..-131 477, ..,1 497 08 % RU-103 537.32 % BA-140 6i4. 70 %62. 84 % RU-.10. 636.9 % -'I 1. :,.l66 %-, S-.. .. .' '_..= ?" 'I 7 "'Y NB....9 7c:jL fzi :/ , 75 6. & Zr- 95.. 76....7 ..NB-959.. .%,8'_,.'4 34.8 & MN-54 1;099.2.5 & FF.-59 1 115. 55 e: 1;-.91. 60 % FE-59 1. 33 2, 50 12 2 C 0--- (-,0 1.59 G, 8 I J P E A K C S- 134-r 137 CS-. 134,.ZN1\- ,5 1L. A -, '14(,02 L A-!140., .Z .._ ,.... 9- 0 724 i'8 ' ZR-95 f-:, 0.77 % C,0- 56:,1.7Z. '24 G% ID:..-62 Pr:eak is I:part of a mun.tip].et and this -area wetnt negative duri.r ng decornvolution. ? .- e i too rarrow.@ -Peak. is t. oo wtide at F "I:CM, hi-" bu k at FWHM. EGMG ORTEC G V -I ( 175) WAN32 14W02.96 28-JUN-2007 13:13:11 Page Environmental Inc Spectrum name: 37415. An1 J.Sa~mple deOcriptanOl TXW--7-S)10 -3.5 LITEr.H2.1-.JUN-~2007 1O.40-:49 fMS Spectrum F ile orfame,. C\ U;e r\374:1 5,fn 1 Al Ac q uisition information Start time Live time Real time Dead time Detector/Geometry IH 20-Jun-200I7 10i~:49c42 8601 SE12 0 ,Detector system MCB I Input 3 Calibration Filename: D3gl. Clb Created: 14-Mar-2007 14:21:31 & 14-Mar-2007 14:50:43 MG #:23 GEOMETRY -# I-..5 Liter in MB-t Zero offset -.110 keV; Gain Quadratic -.25E-07 k e V/chann e "2 Library Files Main analysis lry2i Library Match Width4 500 keV/channe 1.lib.500D Ainalyi s~;ac par'ame~t:ers.~ F uil-r c+- r,annel Stop channel.Peak reject~ion level Pea serch n..ensitivittv'a Sapl Size: Activit y scaling factor 120 for an energy of 41,)40 for nn energ y of 30. 000%59. 90keV 2'02-4. 0 91 k e 3. 500!.OOO0E+06,/ ( 1.0000EMM0 W 5716+05 Detection li mi:t inthod" RISO et h o d Additional random error- 1.0000000 o E+0O Additional systemattic error: 1.0000000E+00i Fraction Limit: .000%Background width: best m ethod (hased on cspectrum. Corrections Deccay corrrect to date Decay during acc:iuisition Decay during collectiion Peaked background correction St at us YES YE-S NO YES Commer I0nts: 1 2-Jun--20127 12:7 02 bkgc3wc. p bc-18-Apr- 0`1121".:,) H cý ri 1--, r! ý: i r; -f--! ý T 'n !-. -rn n ';. I )
- 0G&G ORTEC G Y -- I ( 175) WAN32 14W02, 96 28-.JL~jN%--2Q007 13., 13:11 Patqc, ErvirjrnmentAl Inc Spect rumi nae 74:1.5. 8n 1 En~e rgy cali brat ion normal ized di i.ffer ence: 02,05*~1********U N PEAIK CENTROID CHANNEL. ENERGY 1 D E N T I F I E D BAlCKGROUND NET AiREA COUNTS11 COUNTS P E 14 K EFFICIENCY
- AR EA S; U N M A UNCERT FWHN 2 SIGMA %" keV SUSPECTED NUCL i DE f-+--- --++ + +_ --f + _+ --+ +-+-+--I --+ +- + -f- +- + -+ --4++- +- +_-I. _--++ _+_+ _+__-+---v
_+ _..F--I-V 370. 66 589.57 703. 67 1218.58 185.25 294.73 351.79 609.28 230.132.74.38.125. 6. 346E+03 84. 5. 730E+03 98. 6.815E+03:106. 1. 249E+@A.51.72 58.90 36.79 25.34 1.265 U-235 1.,341 PB-21 'I.947 PB-21l4 1.362 BI`-2VF1 D s P e -k -f-al i ; -,ha pe t e .Ft .D Peah-1 areai deCOTIVOlIItOCd. M Peak. is cl ose to a li brary peak.**Fi******i~**I I) E N T I NUCLIDE PEAK CENTRO:ID CHANNEL. ENERGY F I E D BACKGROUND COUNTS P' E A K NET AREA COUNTS S U M N A R Y ************* INTENSITY UNCERT FWHM CTS/SEC 2 SIGMA % keV 1-131 BA8-140 LA140 I -1. 13 BE-7 LA140 RU- 103;CE-1.34 P.U _ 10,: RU-i I0f-*I-1314 CC' -j57 F E --5 9 26-5. 79 3190. 00 570. 8B 6 11.~00 657. 04 72.-'.8,81 955.83T 97. It 99.I Q17 2. 7 3 i 209. 42: 1. 2 .3G 28 1.3 23,L. -,;t1+ 447,. 0 0 1513. 00 115.3:1. 6 7 I 937 00 I ,16 .19, B8 1. 6 .."8. 0 0 2 J 19-, 2 22 1l 8 1-23,49) 2.5.10I 132.~,81 14 44. 321 305,45 364.36~4477. 89 497. WE 604.70 610.3 636.0 661. 71 723 51 7z, E- ..51 7I rý 5 7 L (',.5 It13 70 1 93.58 137 60.26.59, 10.1 140.-4.1 4.5.*.1 D..141 15 C006 12005 002.001 002 002 CIO) 1.1 Q1001 0 01 Q000 03C1210 ,000 1231.'17 2!006 1301)l~118, 75 16 12., 45 1. 34. 39:1 119, 810 107. 40 145. G9 159. 12 416'. 2E"-'312. 08 28.(h. 0121 111.126 678. 54 281. 88 149, 11 1319. 44 663.32 3346. 4 1.69. 61 346, 41.292. 62 653, 1/126 50 22'0e. 7 3 IL 2S. 603 246 !o ;l'27 5 ,, 6,-43.56 '-,2 84.600s 083s.869 ,000s. o643s I. 836s ,36_3 s 2 -E .1s, 706s 1 3601 432:s 493s 469s 1 i67-;394s 000, 1. 9.I. 38 1. 123s S0-s....... -... 4,. -. --- -,..4..al, 4 At.L it. a DC.. u0E ES&G ORT'EC G V -I ( 175) WAN32 144W02. 96 28-JUN-2007 13:: 13: 1 Page Envir, onmen.tal Inc Spectrum nameý 3741,. Avrl 3-U M M A R Y 0 F N U C L I D E S I N TIME OF COUNT TIME CORRECTED UNCERTAINTY NUJCL I AE ACT IVITY ACT I V II'Y COUNT I NG SAMPLE 2.-. S ISM A** * * *BE-7 K-.40 MN\- 54 FE-59 C0-58 CO-SQ12 ZN-65 ZR-95 NB-95 RU-' 103 RU- 10, 1-131 CS-134 CS- 137 BA-- 14.0 LA-140 CE-' 141 CE- 144 pCi/LITER 2. 4577E+01 G. I189E401 0: 00_-35E-+ 00 5.0262E+00
- 2. 6605E+00 3. 1. 2;E.6+00 3.0964E..-00
- 4. 0359E-00 1. 8261E+00 2.3752E+i00
- 2. 0464E+01 -.3. 331,E+00 2.6 357E+00 2... 0441E+00 1. 6390E+00 3. 5668E74 -i..2. 3 0 7 4 E_+ 0 pCi/LIITER 3.,, 0264E+01 b, 1189E+0!1 Q.07602)E+00 3.4484E+00
- 3. 1115E+00 3ý 1441E+@A0 3., 2405E-00
- 4. 7993,E5+00 2.5056E+00
- 3.
2.1089E+01 1 3279E-0. 1 2. 6747E+00'.0461E+00 2.348BE+0;. 3.9090E+00 5.0174E+00 9C- 99EO+01 pCi/LITER< MDA value pr'-inted. A c:tiv:. A ivty printed,, bat~ activity ( MDA.-.................... ........ ...... S U 11 M A R Y .-.....TOTAL ACTIV ITY 59 ( 5--' 2024. 1 k.V) 1. 000000 '0 pCi./LI TR TOTA:It DECAYED ACTIVITY' ( 59. 9 to 20I;24, 1 keV) 0. 0000000F:+00 pCi /LITER 133.54 &......8.76 %-%621,,84 %756.,72 %B34. 84 &1291.60 &8 U M Ml A CE-- 144 LA-. 140!03 RU!-.1.06 Z I-95 MN-54 FE-.59 R Y [1 F D I S!45.4.4 % CE-141 34. 48 % 1-131 5 37 "' & B'A- 1. Z.I 636.97 & 1-131 7",:,5.79 % N B- 95 1099.25 & FE-" 3...50 & CO-.60 C A R 1 E 284.30 477.E1 E04. 70 661., 66 795. 84 1.1.1.5,55 1460, 1.I)&.4 1-131 BE--7 CS- 134 C S -- 11 3,7 CS-- 1.3_4 ZN-65 KI-- 4 i'I K 3 304. 84 & BA-- 140 487102 % LA--140 310, 33 % RU-0..724. 18 % ZR-95 1U'K 77 & CO--58 11723. 24 & C0-60 1593, 18 % LA--140"Peak is art of a multip.e' and this area went ne ative dur'ing decon-,o 'ution, 9 -- eakl.< J:." too Ta-' W@ ... Peak is too w~idce at ..... , b-" ,k at "".~ -" ..,.]c .;:V 14 o CM b t o' k Ft:WHM,, ,....- .Pea k fa :i ls ."1..s SenTs":it .i.v i t y 't;e st.,-.. Peak :identifie-d, but first pealk, of thi- s nuclide failedl ore or more qu. if:i.cation test;s,; 6/20/07 Tony: Enclosed in two coolers are the first 3 well samples. They are all from outside the Protected Area of Davis-Besse. MW-IS MW-ID MW-26S MW-26D MSOI-MW-26D (for both tritium and gamma matrix spike)MSDOI -MW-26D (for both tritium and gamma matrix spike)MW-7S Please analyze to our normal REMP LLD of 330 pCi/liter. If you have any questions, we can discuss at REMP/RETS Conference. I will bring a copy of our sampling plan.Thanks.Al Percival Davis-Besse J U N 2 2 2007
1/1 , 4y BETA LABORATORY 6670 BETA DRIVE, MAYFIELD VILLAGE, OHIO 44143 SAMPLE ANALYSIS REQUEST / CHAIN OF CUSTODY 1-800-470-BETA 440-604-9802 FAX 440-604-9800 CHAIN OF CUSTODY REQUIRED?FORM X-2189 (REV- 05-07) El YES Fl NO PAGE / OF El NO COMPANY NAME ADDRESS I LOCATION BILLING ADDRESS TURN AROUND TIME (Surcharges May Apply)A; ESAME DAY:-"~' El 24 HOURS El 48 HOURS EWSTANDARD ANALYSIS REQUESTED SAMPLE MATRIX CITY STATE ZIP CODE i A = ASBESTOS AS = FILTER-ARSENIC F = FUEL OIL& COAL M = METAL 0 = OIL P = LEAD IN PAINT W = WATER OT= OTHER TELEPHONE NO. ,.'. FAX NO. RESULTS REPORT ATTENTION E-MAIL [0 MAIL PURCHASE ORDER__O._ ,_'_____ :_.____ , JFAX PURCHASE ORDER NO. lEr-MAIL P R E S E R V A T I V E SAMPLE REMARKS: (Conditions, Bottle Type, Etc.)LAB I.D.SAMPLE IDENTIFICATION COLLECTION MATRIX DATE COLLECTION TIME RELiNQUISHED BYý,Signature), .DATE TIME RECEIVED BY (Sn6 I e -DATE TIM ADDITIONAL COMMENTS!RELINQUISHED BY. S(SignBature) (SignatureW) I TIME C N/ I5ATou-"H' tTIM,-(,*ihaREre) VED BY DATE TIME RELINQUISHED BY (Signature) DATE'4;'1 TIME REIIE ,TVED BY (Signatur ' ATE .TIME._ __ __ _ __ __ __ _ __ _ _ _ _ _ _ _ _ _ _ _ _ / / -#9 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _CFLPY DISTRIBUTf'ION: WHVTE -ACCOMPANIES SAMPLES, YELLOW -LAB COPY, PINK -CUSTOMER WEBSITE FORM: ORIGINAL -ACCOMPANIES SAMPLES, CUSTOMER -RETAIN COPY F ..9..... <BETA LABORATORY 6670 BETA DRIVE, MAYFIELD VILLAGE, OHIO 44143 SAMPLE ANALYSIS REQUEST I CHAIN OF CUSTODY 1-800-470-BETA 440-604-9802 FAX 440-604-9800 CHAIN OF CUSTODY REQUIRED?FORM X-2189 (REV. 05-07) .... If YES [] NO S PAGE/1 OF/PAGE / OF /COMPANY NAME ADDRESS / LOCATION TURN AROUND TIME (Surcharges May Apply)E SAME DAY E 24 HOURS El48 HOURS ESTANDARD ANALYSIS REQUESTED BILLING ADDRESS A.SAMPLE MATRIX A = ASBESTOS AS = FILTER-ARSENIC F = FUEL OIL& COAL M = METAL O = OIL P = LEAD IN PAINT W= WATER OT= OTHER CITY',.~STATE ZIP CODE TELEPHONE NO. FAX NO.,] REPORT ATTENTION E-MAIL El MAIL PUCt O .i i .d'. E FAX PURCHASE ORDER NO. E-fE-MAIL P R E S E R V A V E SAMPLE REMARKS: (Conditions, Bottle Type, Etc.)LAB I.D.SAMPLE IDENTIFICATION MATRIX COLLECTION DATE COLLECTION TIME* ',L -T .} .... #.'.* ..... " 4. 'j vj -'4l~ x RELINQUISHED BY (Signature) DATE TIME RECEIVED BY (Signature) DATE TIME ADDITIONAL COMMENTS:-fýLINQUISHED WX (S-gtEe I (D TIME t,-/IlE... .... ...... ... .. .. ....... ..... .. .. .. ... -._...,y__- -,." (6.PY DISTRIBUTION: WHITE-',ACCOMPANIES SAMPLES, YELLOW -LAB COPY, PINk -CUSTOMER WEBSITE FORM: ORIGINAL -ACCOMPANIES SAMPLES, CUSTOMER -RETAIN COPY 0 S! .Environmental, Inc.-OMidwest Laboratory oý Aftgh.ny T.chnobop.e Co.700 Lndoehr Roa .Norhbrook, IL 60062-2310 ph. (847) 564-0700 f.x (847) 564-4517 Mr. Al Percival LABORATORY REPORT NO.: 8003-100-363 FirstEnergy Corporation DATE: 07-12-07 Mail Stop 1041 SAMPLES RECEIVED: 07-03-07 5501 North State Route 2 PURCHASE ORDER NO.: Oak Harbor, Ohio 43449 Dear Mr. Percival Enclosed are results of the analyses for tritium and gamma-emitting isotopes in fourteen ground water samples.Should you have any questions or other concerns, please do not hesitate to call.Quality Assurance M. S.SAMPLES RETAINED THIRTY DAYS AFTER ANALYSIS Report: 8003-100-363 Page 1 of 2 Table 1. Results of analyses for tritium and gamma-emitting isotopes in fourteen ground water samples.Sample Location MW-12S MW-18S MW-18D DBD-01 MW-20S Date Collected 06-14-07 06-14-07 06-14-07 06-14-07 6/25/2007 Time Collected 10:07 12:30 14:27 14:27 10:16 Lab Code TXW-4117 TXW-4118 TXW-4119 TXW-4120 TXW-4121 Isotope Concentration (pCi/L)H-3a 657 +/- 118 277 106 204 +/- 103 764 +/- 121 255 104 Mn-54 < 2.3 < 1.8 < 1.7 < 3.6 < 3.0 Fe-59 < 7.7 < 4.7 < 7.9 < 6.8 < 10.2 Co-58 < 2.7 < 3.1 < 2.1 < 2.2 < 6.4 Co-60 < 3.0 < 2.6 < 2.4 < 2.5 < 3.6 Zn-65 < 5.0 < 3.9 < 5.2 < 3.0 < 5.5 Zr-Nb-95 < 6.2 < 3.2 < 4.2 < 5.0 < 6.9 Cs-134 < 3.1 < 3.5 < 3.2 < 3.3 < 4.3 Cs-137 < 3.4 < 1.8 < 3.6 < 2.3 < 7.1 Ba-La-1 40 < 8.9 < 5.1 < 6.9 < 7.8 < 6.2 Sample Location MW-20D MW-32S DBD-02 MW-32D MW- 5S Date Collected 6/25/2007 6/25/2007 6/25/2007 6/26/2007 6/26/2007 Time Collected 12:50 12:00 14:58 9:50 12:00 Lab Code TXW-4122 TXW-4123 TXW-4124 TXW-4125 TXW-4126 Isotope Concentration (pCi/L)H-3 328 +/- 107 5838 +/-237 279 +/- 105 466 +/- 112 375 +/- 95 Mn-54 < 3.2 < 2.8 < 3.3 < 2.4 < 2.7 Fe-59 < 9.5 < 11.0 < 11.3 < 4.2 < 5.5 Co-58 < 3.2 < 3.9 < 2.6 < 1.7 < 3.5 Co-60 < 3.3 < 2.8 < 4.1 < 2.4 < 2.8 Zn-65 < 6.2 < 4.0 < 8.5 < 5.7 < 3.8 Zr-Nb-95 < 6.2 < 4.9 < 3.1 < 2.7 < 4.4 Cs-134 < 5.2 < 4.7 < 3.9 < 2.6 < 3.7 Cs-137 < 6.1 < 3.3 < 5.4 < 3.4 < 3.8 Ba-La-140 < 7.8 < 11.2 < 14.2 < 3.3 < 5.2 The error given is the probable counting error at the 95% confidence level.Less than (<), value is based on a 4.66 sigma counting error for the background sample. 0 Report: 8003-100-363 Page 2 of 2 Table 1. Results of analyses for tritium and gamma-emitting isotopes in fourteen ground water samples.Sample Location MW-15D MW-30S MW-33S MW-33D Date Collected 06-26-07 06-27-07 06-27-07 06-27-07 Time Collected 14:45 10:00 11:55 13:44 Lab Code TXW-4127 TXW-4128 TXW-4129 TXW-4130 Isotope Concentration (pCi/L)H-3 704 108 1307 +/- 128 2287 +/- 154 2975 +/- 171 Mn-54 <3.6 < 3.0 < 3.0 < 2.7 Fe-59 < 9.5 < 7.9 < 14.7 < 5.6 Co-58 < 3.6 < 3.8 < 5.1 < 2.8 Co-60 < 3.8 < 2.7 < 4.1 < 2.8 Zn-65 < 5.1 < 1.6 < 4.3 < 4.7 Zr-Nb-95 < 4.7 < 2.8 < 2.8 < 2.8 Cs-134 < 5.6 < 2.7 < 2.0 < 2.7 Cs-137 < 3.6 < 1.7 < 3.0 < 3.9 Ba-La-140 < 11.4 < 5.0 < 10.6 < 7.3 The error given is the probable counting error at the 95% confidence level.Less than (<), value is based on a 4.66 sigma counting error for the background sample. -...-. nvironmental, Inc.Midwest Laboratory an Aheaheny 7echnoflDpies Cc.PRG-33 Fom LS-4Vex. 10 TTR7TUM ,ounte- ID: LSP-20oDC-A LSP-25 800TRh/AB LSP-28007-R Init.& Count Date:<f) 0 7/ i1 /00.10032- STD T-36 BKG BKG Sample STD STD STD Date Time Counts Time Time Counts Acivity issued_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _C~i)Lo0 q79 g I0 X1.o0 0 1003.78 :01/18/2001 Sample ID Volume Sample Remarks (ml) Counts T/,( 7o_T? \ b.i /2 .Iq 1 _ ___ __ _ _ _ I _ __ _______________________I_____________________________ __________________ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ I4 .., ...- ... ..... .. *... ..:.:.. Environmental, Inc.Midwest Laboratory an Allegheny Technologies Co.PRG-33 Version No. 1.0 06/17/97 Programmed by Rick Lesko Sample Count Time (min.): Background Count Time (min.): Background Counts: TRITIUM RESULTS SHEET For any sample counted on the LSP-2550TRl/AB, LSP-2000CA or LSP-2800TR Reviewed and Approved b Date approved: 100 200 978 Standard Count Time (min.): Standard Counts: 200 61688 0.196 Date Counted: 7/11/2007 Calculated by: Rick Date Calculated: 7/12/2007 Counter Efficiency: Sample Coll. Vol. Sample Corr. pA i/L 3.00 4.66 ID. Date (ml) Counts Factor Activity Error T.U. Sigma Sigma TXW-4117 6/14/2007 13.0 859 0.996 657.061 + 117.983 148.004 117.809 182.997 TXW-4118 6/14/2007 13.0 645 0.996 277.031 + 105.927 112.428 117.809 182.997 TXW-4119 6/14/2007 13.0 604 0.996 204.222 +/- 103.457 107.120 117.809 182.997 TXW-4120 6/14/2007 13.0 919 0.996 763.611 +/- 121.148 159.568 117.809 182.997= =Best probable result. -: Environmental, Inc.Midwest Laboratory an Allepheny Technotogies Co.PRC- 33 Form L54- V'e. 10 0.1003 2 g STD T-36 Counter ID: LSP-250/TRI/AB TRITlIUM LSP-2800TR L uit. & Count Date: tb M 0o2 / II /0" BKG BKG Sample STD STD STD Date Time Counts Time Time Counts _kt-, Issued__________ )OC 100 9fO ! /1 1003.78 01/18/2001 Sample ID Volume Sample Remarks (n-d) CountsG /ttG T__lb I______ _____T~ 1-fl?~O I ______________________________________________________________________________ __________________________________________________________________________ ____ __ {____ I __________ ___ I ______ I ____________________________________________________ I _____________________ ______________________________________________ I ___________________________________________ _________________________________________________________________________________ ___________________________________ _______________________________________________________________________________ I __________________________________________________________________________ I __ T_____ I ____________ I ___ _______ ____________ ___ _____ _____ 1 ........ --- ..-. Environmental, Inc.Midwest Laboratory an Allegheny Technologies Co.PRG-33 Version No. 1.0 06/17/97 Programmed by Rick Lesko Sample Count Time (min.): Background Count Time (min.): Background Counts: TRITIUM RESULTS SHEET For any sample counted on the LSP-2550TRI/AB, LSP-2000CA or LSP-2800TR Reviewed and Approved bS * -Date approved: -Date Counted: 7/11/2007 Calculated by: Rick 100 200 552 Standard Count Time (min.): Standard Counts: 200 56219 0.180 Counter Efficiency: Date Calculated: 7/12/2007 Sample Coll. Vol. Sample Corr. pCito 3.00 4.66 ID. Date (ml) Counts Factor Activity Error TP.U. Sigma Sigma TXW-4126 6/26/2007 13.0 470 0.998 375.031 + 95.334 108.120 96.348 149.660 TXW-4127 6/26/2007 13.0 640 0.998 703.666 + 107.841 144.180 96.348 149.660 TXW-4128 6/27/2007 13.0 952 0.998 1306.608 +/- 127.627 218.782 96.333 149.637 TXW-4129 6/27/2007 13.0 1459 0.998 2286.564 +/- 154.483 347.231 96.333 149.637 TXW-4130 6/27/2007 13.0 1815 0.998 2974.659 +/- 170.836 439.145 96.333 149.637 ,j- ,=Best probable result. ---. z~Environmental. inc.Midwest Laboratory an Allegheny -echnolopies Co.PRG-33 Form L5.4 Ve. 10 0.1003 2 g STD T-36 Counter- ID: LSP-2000CA TRITIUM LSP-255UflRI/AB ID LSP-2800TR ED Init. & Count Date: b V) 07 / ) /0 /1 BKG BKG Sample STDh STD LTD Date Time Counts Time Time Counts Activity Issued__ (pCi)0707 100 c90 oO 10bL 1003.78 01//18/2001 Sample ID Volume Sample Remarks-(ml) Counts ThKL4.- 13i 99/1________O IQ 2/ J __ _____ 1476 W I. I I T___ I___J I I -Environmental, Inc.Midwest Laboratory an Allegheny Technologies Co.PRG-33 Version No. 1.0 06/17/97 Programmed by Rick Lesko Sample Count Time (min.): Background Count Time (min.): Background Counts: TRITIUM RESULTS SHEET For any sample counted on the LSP-2550TRI/AB, LSP-2000CA or LSP-2800TR Reviewed and Approved 11 Date approved: 100 200 707 Standard Count Time (min.): Standard Counts: 200 53734 0.171 Date Counted: 7/11/2007 Calculated by: Rick Date Calculated: 7/12/2007 Counter Efficiency: Sample Coil. Vol. Sample Corr. p- r. 3.00 4.66 ID. Date (ml) Counts Factor Acvi Error T.P.U. Sigma Sigma TXW-4122 6/25/2007 13.0 515 0.998 327.797 -106.767 115.701 114.485 177.833 TXW-4123 6/25/2007 13.0 3230 0.998 5838.446 + 236.937 828.626 114.485 177.833 TXW-4124 6/25/2007 13.0 491 0.998 279.084 +/- 104.899 111.554 114.485 177.833 TXW-4125 6/26/2007 13.0 583 0.998 465.746 +/- 111.875 128.562 114.467 177.806 TXW-4121 6/25/2007 13.0 479 0.998 254.728 +/- 103.952 109.572 114.485 177.833=Best probable result. &G ~ ~ ~ ~ ~ ~ ~ i ORE J 75 A3 4O.6 I..jJ-2i0t7 1:1. :3 Page floo viro ment l In nia e--.I ! ...... .. .,`?.4 I )I Spectrum-1k1 I Pij c- T., o 1Ca1, .Dtector/Geome~rtliry Is I---Ji tu E-E:C~207 D 9001 MOB I4 Inpu.1 t...1C.2HiT Calibra ion: i3~CI ,,> ~, fF Zer of se -.98 ke~i7 nC: Quadratic; Lib ar Filesdl b Starit channel.fo-1 an oi., 4: Cj*~' C 58 ko 1.0 00 WE I I!0C.; (I 'h 1.Ad it o a sy t ma i eroI 1. 0I -* 00,A4.0E. 4,2 .0 Fr cio CIi wit. .0 0Wv'14CIt. dat PeakeI~ id backr w y =.IIJ1:2rrc it...ioi-I 1.iiiý i s.CC iC F i~I. EMS ORE F. " 75) WAN3~: i 2 1 O. 967 1.w'.,T .'.'21171 ..2 5 ýE1':: v4 J . ( 11. IT[ C." Y. t 1 1", n i:,s p at , -u i Y i~i n i E.. ;i 1. 7 Q4 317 A n Energ~ v fy ca1libration n4 iormali. e diif fer- re nc::'4 ,, *.,'7 f2****w********U N I DE NT Ir F ED P:EAFK CENT ROD I C PlCREROUND) NET AREA 0-o " h9INN 1_ r-N E R GY COFU NT 'F, (- C) IN]" G P. E A FK EFFIr :iCI:.ENCY"-X All 9Ei 3 U] Mi rI'. A -, U N.c: C~ EF'.' FJ*.F....1:% 1-" (,.- I)4['V r4..4.444*4..4.k SUSPCTEID 1219.295 351.52:: 510.1 85 170 i.89 4 100.1, 152.941. 7.57E403 10. 94i 1 .854E. C-rf..I 62.. '7.1 48Es03 507.21 4', 1(3 AM49 PS-2'1 4 Ti,73 'F..2081 L9.47 Bl -21.4 D Di Periak ar'e a :1 c:'v 4o).ute 4: 1\1 LJI..' CLI Dr P:EAK CENT' 1ID: F~ I17:.D BA9CKG9ROFUN.D COUNTS r P7 E K NET AREA1~1 INTENITY N C(9 r" w 7M CTS 9/S9E C 2 SIM ke F'sV+ -f-f-f- f-f -f-f-f- f- f- f-f- f-f-f -f-f-f -f-f -f-f-f- f- f- f- f-f-f -f- +-,-I,, CE- 1 Vi'.F.E -1F41/LA-140 R- 1037 BA-140./E13 '4IC 10Y3 Z 5 1'414.474 271.52 295' 50 571.00 6,1 .]'"!, 454.. 0 73.7.357I ?, 9~761'.3 994.73'1027E.67 1 1.0 144.6"1 :51 f 034 '. 12 5" 9.' 2 2 284.0"i 7'.'.'7*7. 1i 4 487 12 /~496.34 537.3 1.7 EM43 7 G W'," 7 "'141 .16., 414 2: 14.4 5'.'25..7..4. '1741744 71 471 2 714719 1741741.474174/4.4'.,'4 174171 I7.II;~.4.1741741 ri r: 1.7173 1741741.174174471 474 .4.r~4 474 174 '~i"14 4~'.44"l''1 174 4/4 17r414 4.747 I1 742. 4 24'.54.4 k-,/. 77 :1.1.)1 .1'443. 7149 174. 9 4 01 1 7 t3 719].75'76'04s:.38&4s's Pmak 'are I .(: ~Amn'4:ols; s 3&G ORTEC G3 V -I ( 175) WFIN32 1 4WJ2. 96 11. -JUI 20-a07 Pag 1 3 -~qe 1s11 r nmentI; im .If1;:iitrn namnn , 1. 7347'.: ý( : S~ U~ M 1 AI F V 0 F N4 L C L 3E S I N TIME OI ~~r.rF :ricor COUNT TIM CRETED~ UN rEr F:A I 9: A~ M Pr.****-X-NUCL..IDED ACTIVITY pCi/LITER ACIVI~TY p5 i./LIT E P COUNTrr:~INGC fi:CI/L I "rE I.........-l....................1-~. 0 7I 11R-95 RU-~ 103':1:ý L .1 7i CS- F :1.37 BA-* 140/(I 4/I 7 c.5231941.5
- 5. s0.9G3E+0?I
- 2. .117sERZ 12. 95S~1Et12) 5.220337E+00s 41 397E4 1117 3. 413E+0 7.9133E+01
&S 214E+@Q717.i 1749G3fO.O7I? 14.21 4 ;3 1: 7 W71 S7EH3C.1 1L 1336137E+001 1,':.2714SE r0u1.4. ý -41 .- 4. .- + --I III ... .11 --.- .11-1 -.1 -+ -+ -1+A) Acti: 1,vi:t y pr~intend, Sot actUivit *I*;A,*FoTOTAL ACTI:EV ITY ( 5 8. 1 t o 2 2 S. 51 k o V )70. Q1;7.1 0 Q. +71 0 r:C i / 1. :1 Trs E s F :TOTAL D)E.CAYED ACTI.~V IT (/ 51, B. i; t 2 0 26.3 1 kA e V ) 0 ',Zif, 1+/- , ~'.!i -p QO , i/ LI- 11'EP 621. 8 %75.7 %f B34. 84 %1216 &S U IP CE 4 A 1 'r? , 14 .4 I64.4 537.3 F*f .9..CE-I 11 1-131140 1 .- 131 FE-59 CO-60Z 2B4 .307 C47~s7. 1.104.7 BE !. 66 CS-3 134, C -I 1 C .'i 30.8 %,,~ BA-14 487.0 %~ LA-i14/1.3 % IRK",7 P~ "' I?~ is k.,~J.1 7'X W -- 411 J.L-ý3. 5 1.. 'TEV* R SpectrumJ~1 Rea~ l tie73 Dea ti m .1 *1'Yý~MCB'14 I~nput; 3 Created; 1 4 Mar-2007 14:1 &.,~1 I. 4 4\r -2007 10500,"', 11G M23 E: INME 1 T. Y 41 1.3. 15 L. it1 e r i n; Y/'i 1 i... 1 ....) .AIry 1` al..' "h 1i.Anailyi parameters~li' Str channel.Stop hanne Pelak 2 rjcion lelC 3vel.Pea searc se113 iviF: 2:. 1i 1.)L 404 for an energ of' 'ii'*1 30.000% 1: -i~:'.1IV o.-N -eV 12 0114. 0 9 k e I:i243.:, 1.f~1'~111.1 3 2.857 1E3 05'De e t o li i et o : 1IS method':iI (t4.E2c~ i Dea (luin s"qu si ioi-Decay~~ duhq oletir Pake bakron correctio itatUf V EI Y03 1;,.1; 7 1 3 45 f" I-, 11ý ý 1 1".. , , 4- -ý ý-ý " ý' T -" 1 K r" &Gc~~ ORTEC G I ( 1.75) WAN32 ] 4WO29 1 --.JUL-00 .. .... ;-. V:YrZ! P E neprgyi calibLvat;i ci n ormai zed i i.F ~ rcc.1. :.* ~~ 1-1*** 1 13 Ii 14 T 1 F I E PEAK CENT R~OIi BACKGR OUND NET AREAF Ci*RNEI... ENE RGY COUNTS CQiJT EFEI C IENCY , A Ir- ,'.ýS i U i VI 11 A R Y ~ ~ .i UNiCE FT FWHMi' SUIJPEcTED 2 SIMI OiX1 1,c V NUl~c i.. 11 [.F-4, ... I.-ý"..-,.,.-Il...-ýi..'ý1--"!-.,ý.,-+.-+-+-+-+-+-+-+-+-f-f-f-f-f-f-f-f-f-f-f-+-"-+-+-+-"-"-"A-"-+-+-+--I.- 59i2,'3. 3 1 7121/,'i,. 2,3 1 021.0 12:18.0 1;?.Ti)5. 13.~2i .1. 0 39 30.13~ 9¶:I 53. 3.596EF+03 833. 6. 4E9F-i03.? 13.39. 1f.43!E3. 04 51. G. 2i30E+Q'.,,7 W9. 3.33 1t 4.*"3 9 r-,n -- 2 1 z.9: 5, r.:, B 4/75.1)ei r. e -cc ei c. C) ) v :: lit e d iiui * *~ i <~i*I D E N Tr a Nlt I- CL. 11:) CEhrT REIDI: C .- R L-F .ENE RGY F I E" D P F A 'K NET AREA0 COUNTi..i'Sr S L3 1.3 1 I'l Ai 0 -ZI -'.I ** l * * .* *'INTErSIT 112ry R i1!..i tf T Vl-I CTS,/31F: 2 33 R% V e V CE 14I66 5 133 2 I.1 .46 -1 .0 1. 4 r:.4 CE- 1 41 29 .7 146.28 149 01. f"?l I", t" :1.t 'i3 .It9*Si (Z" ry-3 50.p~i 1!100 1 B25 74 00-BA 4 6 9 4 304 M'", 32 37. .0 92 50: i111 f 33 1. 49,-, LA 14 Y'75 '1.5 y: 1 328 20o 50. 7 1. 7 7 f", .9,B ,M]---- F.154 ., 59 4 7.2 1( 0 20 1 ~ ~ 7 c) 70 LA -il40 ' .*'T;*ý.. in 1 f,1 .d .7li*1 .00,21 A 17.-)RU 10 139 .2 49 .0 2'. 00 1. 1 1.12k ('"1 1" 1j i*'lG ' 3 4. .2136.9 22 1 ti 3 8:1. 1. li.5 RI *. 12 1.* 2 12)1 t i 35. 03 1 N7 IN! 25 0. 1.4 158s 1: 1.3 1~ 7. 4,i;'ý fZ 3 4 .l-0 3. 1 .1. C cc Li a 1::: p 1:*Cv"cI.-IC c:IcEc;ci:.li1\!C
- 3. .1 1.;C'L2I..
ý'3 .0 EAS O~30RTE C S V -( 175) WAN~32 I 4WO2.9 11.-JUL-20 1:3003 Page'EnvironmUjen ta *& Inc Spe :r name-. m --?*S*~*~ IJ ii Mi A R r y ( ::) F` c11 t.) ..1 OF COUNT f~(~;ITIME~i CORREPC Tr.- C NUC:L IDE ACTIVT AC~i lT 1 VI I Y I~ E 3 1\IjINCETZ"1711I N4j17'Y CO0[JN T 'I N (3 Al M P' L E BE-7Z K-40 M '4--51 F:'[-- -- 5 9I 1\UB- 13 5I rt-1I 1 1. 0 (1:-1. 31 CS- 13 rCS- 137i BA- 140 2. 950E+0 G. 0769E+01 I.715EB VG72192 +I (t 16EE0 599 7E0.3.5'74j3 Sh 4. -727 .00 E 043GE.'6 --i/0 K 37 3E-H/00 a.4695 E+00 /I/1. 8360IIEEf-iD~4 /1 1.05 E12EE 0~:1.IN 3300EFO:'%
- I /L I TER A ctivit y p::r~i~nt:ed, bu A;,iott.v i.ty ( MDEF, TOTAL.. ACI) SVIT SY T I 59. 9r tT a 202 .1; k e333, V) 0 .( PC J 3 /IJI15/5A5/F i* I* *
- 13 U V' I M' A I 0 F'2.8 & 1 RU-F0 E36.97 %75.7 % R9 757 D V 1 6 C!C'E-141 28.30" 1-131 477.61 DA14 60.7 1-13 661.6/,'I"'I','a,, I .. 1 ..31 BE-C9 13 1/.33 &/: Rh 0 -Ii 1:1. 7 ("l',I -G 1159E. 18 10-0@- Pea is to ua -I1 Peak idnified, butl firstF peak wFt-snul faile 'ane or. mor qualification.tests
- &G f ORTfEC G V If ( :175) VP 3: ;i. 4Wf2 93 .11 JL.i)271 34 Paqf, 1T v i.ro met T i a i1 :1T Spocittr '- n~x~ 374 17,A7-n 1.F XW- 4!t119~ 3. 5 LITER 4 ?. I I, Spectru F iTTinm.Hi~rT.I~'347
'"T A I-', Start t IIime De tecito: r/Geomei~itry lID Deeco Sytem 1 1. ~J u If ~2iZii2V7 11 T 4 :f 33 (3 3. (3 1 (31(35;8,4.J. !-,i~T
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.2708, U N PEAK &'.CE: ROIr DI CI-. AINlJF E F.INERGY(3 TDF N 7 1F:I F BCKGR~OUN f-(L N ET AREA1 C 0 U N T MITS~P E l-'EFFICIENC* 1 AREAi-S ; _J M A1 FR!LJIN- C-rE Fl TI F't ,)FRI [- 3 LD. JF-:F: C-1 D 12 1.311A % ke. 1: DEUI..IS I@2.3.55 51 9. 78 1 '3. 203,., 2.09!1 +O914 21 .742 L--@1219.70 c-609'.0 32 0.106E0 s F:: (-? a !.,. f3A. 1., t7 !::Ix-t- eII s~~J4s 1.s s ~NULIC.:L1 DI E-f F-.j. .....-f-D E: N Tr 1 FT 1 E D P FE: A K CENT~FUM BAKRON N zr:F~ :fh- ET ARE E9:NERGYI ' COUNT COUNTS 5.1I~ 1.-f-f-f-f-f-f -f-f-f-I-- ---S U N i-i (** 1`t Yl \ 4i*FF.,.*.-... WlTNlSIT Y U.N1::EE-RT f 7 LflII CTS /SEC 11 SHMIA~I % Fk .'V..F-+--- II .--,-1 -.11 4 F--J I. ....Af f .f I 1L-140~RU- 10 V131 1 9, ):7 .. 3 (7L 59 E. -6.2r7, JS 13 7 5 07 9 7 B~I 078.72 1211.0 ~3-, 7 6 3.7 2GS5. 7it... .... *2H .318.7 1:317 0 4, t 7t G: 21 *73 7 53. 42: ", 11 :, 3 ".7 i itI 3.'7t 67.I..7 5~3 3 Cit:?' I I-, t7tti9-)2;~i;~t j.K.'-7 LA~ith~t I 'ti,'~i J ft ii~'t'i 8 At i ~t At ~ Ct 3 '1 I-.'iji.$ti ~~F1 7 8 F-- Z('774 -; f 1.".Q 258.20 0-r-137.4 324 4,fi 20.0 275.6 ON M 27.0 1. 922 ,,t 5Q., ,13s;.520 78-,71)1.24s: It I., 1 45t 11,-I-. '60,.i; EG13&G Oj:RflrC G3 V I C 1.75) WAN32~7 I4WO2.9 Ii I. -JUI --2.1.07 344 7Px~S*** S Ui M M A- RY 0CF N L.1 C L I TIM O:wsF~l: C01.31 TIM CORREsCTED D3 E !H3 I 1\1 1, \COUNTI :NG SIS I L f5C i/1..]:TER pCi/LITER p(~i /L ITER+ -. + + -+ .` + -.+ ...+``.+ ..... .... ......... ........ .. ....................... ....... -........ ....... .......BE-7 0, FE-59 C .3.3R-95 I" CS-.. 13.I- 144 4C. 467G[3 19.5'3SF-1- 1711 507.7 3 F ýu71 32.EW 5 ý,3 2'Eýf ý3.94117+0 4 .15 Zt 5 ., 1 4.1 11 IQI Ac ii ty p ,3A3.U3 ri te, but& acivty.. DA U M M A l~lR Y..... ...1 to ;; 1' 202. C 1. ke W 7, 71107l10L 01'5:./1.. i :1 1 V I T Y TWISI 11TC94YED ACTIVITV (5B- , .I t, o 202E. , -,, V , 0 .0......0..:....W ,XA L .Z.3TE'II%, 32B 7G 13325 %S 1 U ' 1 333 F1 Y 13 LA 14 36 .4 &~'I RU- 410 537.32 &+1-131 66333*NB9 795.84 3 FE-3 9 1 15.5...CE-41 [284,.303 BA 14 61.3 3(CE-13 7 3 24.19 CE-13 10.77 3 .3 33?.3/3,33 33/33/3 R- 103 C 0 3.IL A-1 K /3 ******x:W .3 4 BA-3 1 40% Ir A --1 Pea is par of a )3 mut pe ... thi ar a negai ve.~ durin L3IU 33.1 [.333@ -3ek .3t o ie t F% .. -3'33L' Peak fail Se si iv t t s .3 3f 3, 3.3.313:3$3 -Pe k i e t f e , but .,3I fi s p13,.th s u li e fa le one or3 mor qu l f c t o 3333 3, 3,Uf.i3..I.' 3 t'UiL
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- 2/( ; !.OOOOE+&D*1:.211 1: 21ý 2 .I5 D t cytion limi t it o ;F I -tý .-J o n L J1 1 t ,, 2.000212%Bacnkground' width::a best :1)ic mathad )1 (base an spctrumI. ) i,.eaked ackgoudcorcto St.c at: Us YES~I~~ ~ 5, 1V ac;.1. n11 t ~~:c~'aC N-,I.
EG&O ORTEC G V -I ( 175) WAN32 14W@2.96 11-JUL-209.7 1204:28 Page Environ.mental Inc, r Mf.i 47341nAn, Energy calibration normalized difference', 1.0000 A.*. .*".'7f.s"--
- U N PEAK C[ENTROID C7HA2NNELJ I. ENERGY I D N T I F :1 E" D BACKGROUND NET AREA COUNTSh i i~JI' CONS P 1,7' Ai K EFFICIENCY AREA Si U. V Mj A R UNCERT FWNl-id 2 `SIFG,'PA
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Pf P2B '3 3.5342E+0 24 4917E+00:1. 43-6-'A 1 3. -,`1373E01. I.- ZI 17 6.~~~ 393W"11 S2. 9077' W L W 3/4 1:1 S l I TOA DE1 ':CA~YIED 'ACTIVT 59. to-r 2 53 2 4. 15 k~s~ e V ) 0. 0 312.10 Q; 0 le."E -I- (71571 :: pCi. L11IT 32B.7 % L-140 64.4 % 21-71 477.6 &l" 49 .08 & IUd 0 1573 % BA14 604~ n' 1'.7 %1 83.4 N51 1092 &. FE5 1155 %1291.G0 % ~FE 5 9 1325 *G-016 8 II 13 7 CS-134~~1 --(S1 K-40:30 .8 &~* '5A5 -140 48 .0 % LI A -I14 61 C15 3 R ".810.7 CO J 1296. 8 L -14ji."?s Pe k s tocJss i l.-1s5,5 j-, Pe- k idntfid but fis peakn m t i u d faile one r mor qus-s0 o tes. s. EG[G ORTEC 0 V -75) WAJ~N32~ I *WO;2 96 :11.I-UL. (20?.7 1. 8.7 Page En~ ;viron~men a i. n:c-:I;vui ~ .'J4:,~ :*X44 2 3. 5 L. I EfP" 251 j*2'n' I.;f.5 APIS Lietim 7921nl Rea tim 79311.Dea time .13%Detector Syte MB1 input Ca I b a i r a -.-0 Sto chne 404 for A UU 'r~Ac ii t scal ring factor !.OOE0 / I.2rrOr+0 Fractio L imt. .00/ .Z i ) .WM~oO@.Peake bakrun oreto St at U y ýý]: V E S hf)YES bL,<g% .,! pbu,-i:-A -- 7 12 .,! :5 1 ;-UIII'I &G7 ORE G Vi -n r .i Sp tr1 ( 175 WA3 14 W7 0 2. 1 14-8 7 Ene g ca ir t o no m li e 1 d l1 55Y AI:.i.ffe sr' s Noa, uink1nown pak pa se snsii ;vity test,,.2433 1 D E N T Ir S111P11\NEL. F'EN! E R 0Y F I E D E'.A CK G RO U 1T[.COU..NTS CO:UNT S S U. M ("j A R Y A*~@*A*~~INTENSITYNC r r' ..". .RT F WI-I CTS / 3E 2 ~SIM X k e 1 f-f-f-f-f-f-f-f-f-f-f-f-f-f-f-f-f-f-f-f-f +-+-+-+-+- 1+ ---- 4 ...... ..CE- 144 CE~- 141,: P111 BA-140Z LA140.1Y 00 ,1l3a[Ba-7]c'P' L)-1 lZfIC." F1231.I .CS- a13 Z N a)", 411.5i3 1377. 10 I;0.71.673 1327.1 3. 1')ý'5.-,Q1 4 ZS 1595.6 211..1.,13 a .E 0~~ Qi*iJ., 5 :1.3.4.3 284.77 305.7 329 92 '52 3 5. '1. 0. r'3 7 6'1. 1. "al.*1J 5C) a 27.10" 41.'10 12.24.'67 25.18.17.13.4F .a'.1210 1.~0002/i 0210.0212 ..02' 2 0 021]C2 )7 143 W" 1. 7 .it!-379.9 12" M:1.19 5 1. a 74I.5 5 9a 71. 0 0 0'! 1) I'.4 2-) -.70 1.,"4 6, OQ) 10 al III a+/-i' a1 I" 12 C:: a:1 II a,, '1 1 1: 12 a aU ý --, !"I "tI F.YE; F %' i C, 1 a- *'I iM-- DIF Ca 'l-N TIM CDR i .D11{ E ACT 11 V I T'Y ACTIVITY.p C i / 1 T .S F a, a 112...'. II.. 1, a a '.. Y '8E+W i 1:1 .k,1 a 7 ~ ~ 4 5 Fý: 2.Un 1 '!C -Z ,*41 kI a1,'COUN1'aT ING i::'f3 lxi F'(1' ~I (2 Qi/LI:.-r p.I:::. I .I: ! ..1.1. ES&O (RTEC G V -I. ( 175) WAN32 I 4WO22. 96 11- JUL.--200'Z7 4:~38:47 Pageq En v:i.ro nmeonta 1:::ý G peoct I- u fit 4-734J 1n 3 U'O-60A7 ZN-65.R-95 NB-1 95 fR') 103i RU- 106 1-131.CS i- 134.'CS- 13 B -1( 4 0IJ LA 4 CE- 141 OE- :144/4..5/3. 31S.O 1. 22 G t I 35.167.9t3E+00' 6., 139E6917 3. 33J6CTiOi' 1.1224E+01. 6.2437E+01. M 22 '1656E +0 0 I 63912EW*711.216 21 MD ' V alu pvit- Inte Ac i.v it;y prin~tedct, W EuAivity ( MDR,.r .... ..... 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Hi, vfi I e,-0 7 2ii7: B '.F nnY 1 Energ calibra t i o I .n n ormai zed3 oc diff...I ' -rey 1ý 1. .f17i 17 0 01 A~0*;.4*I D E N~ T. -I F I E7 D2 P El A K ; G U V1 41 A R Y '1**0 NU CL..ID PEA7!~K C:E~NT ROD :i AEiCliCvsROU1N NE A:C~ REA I NT T N:- 1,1 j'*",' UN1\ C': [_ F' FWHN1,7 r:E3p3Jr\E N Ei:RICG.fY COUDLNTS COUNTS~r C'
- r / FE__C;I.. .[I+ -.+1_-. 11..f...,..............I , 4 F I~ A---..............
1* -+ -11. keV 1~-C 1. 3n21 1.13 I. 'I7 f LA1 403 /RU-103z 11 lii!'.ý'Z R, 95'~'I' Dt 5l r1.'0 r rtlk 5 F" 5C'Z.P. I 65.47 (I 7;)!. Oli 1 14.3 II I. i'_' 0 .f" .1.1 19 /. 91 9 1 ý'i`4 47 1."-,2 1 6*15 11 1 304.4 1'3'.`41 '7(-.:,?4837.0 541. 3".-67:7. (h9/4 I 7 17. 0IZ 13F 1 17.37.0.4 4t.171, 4.)17 217100.2112.11 011 012'11"!l17 01711i.002 ~44. 2, 111 .IG:U, 7. 3. J.1 V.35 7ý;:. 819.5. G'.- Et 5 1. 1:31 1V. 77 4 IC 12121 .49 8 8 .36 1.1001r3 52 7. SID 2 33 47/ !.'53.4 '.755s r.2 ' F/.4( fV~ a aF t S (9 P3903K 4~~*'0 :1. S 9K:~ ." 1k71: c.1/ 4.u NT 34 A~ R Y 2 1" NI U. C! L 1-1171[I t:): (.(.F ) 1,JNT TI MEi CORRE I~cCTEDI: NU..CLICDE. ACIVT ACTIn~VITY. f) F' U; ::: N 1.3I\ V[2 hI'i :~5 !,! .4 ý" L4 .ýpCi/LITER Q ii/L. I TERf-B E['IN -, F E-4 3022+1 3.7932E+031.417 EF&fG flRilC 0 V I ( 1 753) WAN~32. 141WO .11-3JUL-2007 12:27:461 Pagej c 1*12rviro.nment a I nci 5pct rs-n:rne 727!.AnlI ZN-65 <RIU- 103~~: RU-10.6 1-131~CB13 4 CB-137l BA- 140li LA-140 CE-14 E797E/j&b 3j.86? ii* F3EM I 2:1-,l t, 2. E -+ 0 1 Q~ Q7445 6F+ 21 6- 778~ :1 E4P00Z 4.52442MVLH I 1.0084E+01
- /.4621EN0 A Activ' ity prntd bu rt act ivit (. MOM-...-........
........ ........... .... -- IS M1i1 ,.'1 R Y. ....... ......TOTAL3 ACTIVITY 6 .9 t4 2. 0 3$ :1., 4-k V 4.) 0. 01 0, 424 0 1": -1 Q41: 1) p i / I_. I'1 YE FP TO:TA:L. DECA2YED AC IV T ( 6F]~ y i F,5.9~lI to 2031.; keV ~) ,,4237 (7l7444 i(K "I/ T Fý C 8 4.,4 Si U m m CE- 144 A 140 A~ R Y 145.4 FI BA- 14 1-4 1 3 NB-95~~'C ' A 1 )284.30V 47.6 604.7~11155 1 '460. 1 D"I I"~.1"I/1r '131. 84 % 1B A F-CS-r. 3~7 7 .l &' Z R-1k "" Peak is part oAI fj a.. jfult ji.41" and this I4 Fr~I I -I Peak idnife, but~ 113 frt ~ oF th44 4'fa led .1 I4 i one orfI3 mor qu l fi a ion t s .3 ( A34,.' ri ;>*) -~ Pea actvit highe thnE'Ycoutngue i yrag.-f4 j 1- Pea ac iyt lowe than.4 con ing un n o~t range.-.'. Pea waffd an ly h enryrn 1IS EG RT.6 1 ( .75 WAN3\2; i:4WOJi2.9
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200n~7' 1TWW I Page~ ~~En io mn a :.I X',--ý,.I'4,'?14 I-I ER Sftartm Liv time Rea time 10 5'Th71 3. '10 2 .5'1~,-. "J M 11 3. L Zero offsetc 1.ud a J .-E797 We~ Boa in T.49213. .3.cane Library.;*n e- .2. i 1;ý .3A'1` i-of"J for 1 I I~ F1 2237; 7,;~3K~33l: 000%,V W ¶: 23 W 32i: .3 O=1 2.8 5 12 E + V`rnnk 2rro11 13. OOV OEO'Adi tiona' l s ta ti:)/3; 3:'I :32 er or L3 1 .0000 00E:33 Decay/I durin wq istoi Deca Tiing Peke bakrudcreto St at U.71.III .1 .7 I:L;7;W23'333u &S; ORTC V -1 175) WA3 140102.9 'E *JL-~it ~ 2Pa-ej v i r c+/- n If en t;a 1. 1 iI S p~ t. -,- .ti i n -. 7 2' " P.) .Ene rg ca i .~ bra~t rion normal~.i
- i. chd. -f Fr*******U 1 DENT 1 F ED P! p F P. K, S U Ivl11. A! R ~*n~**PEAKP C R ID BACKGOUND ET AEA FY P PEPC Q',: .F~ w 11 flet 5 It. 'i r IFI CE c17,'1 P1 t ~~~~~~~~",, I J CtE~4 .7@, : 1: D(.h4 E~ N T 1 F 1 E D I'E- 14. 2 8 '2). 1/173 1157t,, LA-140F 64.00 3 2 .A- 7.( ... 7 7! 6 4 7 091 L- 14 97 .0 471CS1 R !.1 11 (" J Zi Z ..0:I,8 CB-13 1393 65.7 7*Fc',;..-z.
7 ;-z IR 1 3,,.18 2., -., P: E: A K.7 7,, Cr B, E C' I Gh11i~l % k eI.00 17.4 .01 0,i1 1.. C.J.II: 1 2', 0 Q~ ? 1 1 1.* 7*,YV) ,1 f I 1. 17 CO91 A~~7 *3.1 7/ ;'.002; 749 1.75/i .7I11 Ki 81 s J ( *~ 2. 1. ~ T ;5 T) 1:::1 c,~' c-. k.iII* 2 A ~ 5 ~ E(3&( ORTE:C Gi V. -I &. 175) WAiN32: 14W@Z2.96 1Ji i-JUL;-:0Q7 15:2008~ pag"IS Ci U M 'M A R. Y 0 F, N!U EDL. I B .E.i S I N 1-11 1'11--c~ COL.B\T T IME rz C RREC~TED IJNC:E: 4'Ty S: A 1P .2 :3 1 GM (1 NUJC.I DE": p i /L Ii3:n AICTI VITY p C i / L.. I TI E?+-+-+ .111.1 +-+BE7 A FE-59 RU 103 CS 1 34.~CS M137 S .4 145 E-t4'1ýN'4 176SEW 2.274E' 0 4.394B~1/&rr 976E 1-*-. .I. Q!2.7.59GEW. th 005*E+0 2 -i. 5 Q642E 1/4',, ,!3. 13 9 1'Z: 'I ' '9 'W -24 04 2EI " +05, ~ Ilf(4l~o F. i L. I.C.i 1iT 1 .( 1 .C Y .. .... .... 1 1. ........... ..~ i ... :2.- -335 & E 14 145.4 %53.3 % BA14 64.0'63 .9 % 4-3 6 1 7'579% N -9 109.2 & FE-39(1 1 1477.61*CS-13 72.4 K- /~40 15 .8 1)"/P. E~ A BE~w7'rUv 4.4 ZR-9 L A 4 1U" Un 4 %'A 1'72 % Z 4 14" 5 9-i Peak~~~~~l' is PatO amlipe n t re et neat v du in dein a4to .@ e k is .to ok al' [:::, (-fl11%1.~'
- I &zES ORTY S V -1 ( 1.7M ~WAN32 14WO2.95 1.. JI-L 20u0l7 :HOOK4: Page~vi .. e ta !nfc2trI Ti:::2 :374F4 1-A-Il: Spctu Fienme M ., 2 '.U e 37441.AW.
I k ( 1"0 1eetrGo~r 11 1.:1 *.~ 1-3 ' 17 3f;53026 7241.72507 1.(12 12 22 C 4 12 rA t ~.2;1 1 1;'n .A i Cre ted CA Al"-2i71717 1.02~1:31. ' i~ h~2@:2~7 I 4. 2 53 43 Zer offset *Quadratic; -. 1 k A GaIin.125hIE-027i( k V !chav&'nne ".500 keV/channel Li r r Filw.., c! "...kIA ej212 Pak reecio lee Pea lero seuiuit sapl S 1e Actvt scain Factor 1.P an7 A 2.. tI'*~ ..A.121 I~i f* .3, A IC JX/ i 2.57 1EM11+/-5 Detectli li i method,,,, Additonalsystsaticernw F r a c t i o L A i ' 0, , 0 0A V 1 1 Bakron wdth bes mehd (asi petu)17)I r C. c r , nA II c i J', L : i; o f-,~i To a Iu hn VJ mAit.Irti m i:( i~-Cft VIN Comments ,, :*!z!i!7!
- A 4A EG& ORTE G V Is ( 175)~; WA3 14W2.9 1-JUL. 00 1554:1.4 Page4 2 0 Energy~~/~41.i c lib ai o normalized C flOr differemoeu t~n ':1. 00 PEAR CE:NT R O I CFlif-) 111*11 .. El'! ESSRGV 1 f) ES Iq T :r1 E 1 MWGROL~j~
UIT) NET ARE COMT C:, EOUNTS7 P E A' it EF~F ICI ENiCY* ARE Bi U N1 11 A R Ui'. 1,4 C~ [1ý r EU 7*i 2 S .(3MYIA I-, iTV Y T*~ *i***i SLIC'"ECTfEI 1'1LJ(C!.TDIE, 703.37 315K 1. 4 GZ 9 .5., 7.397ES+03C 45,, Z'5 1. 1.,4.-5 PJ,-3 14 1218.10 609.0421. 126. 1.48ESS04-205 .6 -V41 tests. vo o 1 1 E N T/CE 14 26 .0 13 .W..:7);1 CE14 20. 30 145.071 1G.1-31 56.0', 28 .4 24.1 -* ,13 1 ~ 7 ':i t, j, 17' "1 o-',1.1 DA14 107.0 53691W)Cir,* C1j!..!011 B U Al M r;IT R. 'Y H.Q I Q!IQ 16 3 3 I i 0ý.'12!. 5,..4ýf'i F, -Ill" 9 .5 1 ,1l,'l01D Xi. 7.I" 0 I'll 7. ,9 : .'ID 1 , 7 1j~.1~ G'... .7~
- G ORr~CTE~C S: V~ I~ 175) WAN32 3:4iWO2, 95 1JL 07 55 4p 3 Si U N IA PRY: 0 F N U 0 L 1 1-11,1E c~: COUN 5 T TIME COR:RECTCED NI.CI Di E F1 T I V 1 T Y1 CrT IV I T V UNCEART4sI NiTY COULNTrCING S: A P! P: L.E 2 S C CS pCi/LITEl.- f ..f .. .....4. ... .4.4.........4..f
..,.,.4 .L.. ...BE.FE-591.3C44.58 CO-60~L ZR-9 CS- 137 1CR 14 12 .34691:1-47. 3..2. @14 'EI .EN R5SE+0 3 .2197E;01~KL 3 (742'.;.. !C+:C 7C: 41 5 -.`i'i'4-1 Q 54 8 00 1. ::? 49E,: V, 593 9 0P 331 3101.E 4- :50 1 2.5004+0011 G.2795E+@7'l.3 00749E3 +011.S A76E:;3:-,..C. A A c t v i t p r n t d b u t a ut (. .....TOTA A4H T 4 ,., 1,o Ci4' ./ 4. -I TOTAL~ DECAYE ACTII TY ( 5.9 o22.1 keV 1.69161GOWN p A>/ ITE 13 .5 & ' CE 4 45.44' %~3 2 8. 76. % L7k!4 36 .1 32 .4 U 1 OS 43.9 &1-13 477.6 FE -5 I I11 ...,", 1-13 Z ~ 8 4 & .4 CIC.BE7W7 .02 %I' L A- 1 IýPea is; par of: a 4.. multip..;l. t and4~~ &p,4 avm wen,.4'4'.21 a.4 EM RE 7 )WN2 1W2.6 1-.2271 0 :4Pg,.Environmenta C4 c~ I-J f4, re Live time 7 4 01.`r ('I LIseaetry DS 0~ &Crat& 4 Mar -2 0 07 15 41 `. -, M a 5~'4\-~217
- 1. 1,717 3.,5~:1 i .in ..J'. Hýi I Y 1 j i ** " !!*-kt C 1' , Ii, J in a I 'y i:)iA" A .ill0t .,V td C., a - 1 FwakI reeto ee an enrg of i Wi. 10k!.OOOOE+06/( 1.Z d. J i. t I i C Frc io *Li t I .000 Bacgrun width bet at Correction St: atv~ u
&S3 ORTETC 8 V -I:( 175) WAN372 1 4W@22.96 !,j.JL.-;T003Z7 16N022 14+F Pae il n c vi. vo:nmin c anc .i7nz : nc r'- ,cn :041.i Enec~rgy'~ cal :ibrav ~t ion n orma: i zed c c di :.f ferev~nce n 1.3AC 7 PEA:3K OENTROID1. 1; D N T1F I Ei 0: B3AF;FBROUND~Jj7 NRITE A ~RFEA 1C D, U Ill, .-r COL TDU 1 P: E: A F FF FCE:NIC Y xAcnREA 2Si~ly"ID % C/nY Yl : E FE 70.2 3513 65. 108 975$.2s79E+03~ 5:o, 1--s' i. DE.-' 42 1021.2 50.0 58. 1.50. 1.70GE:+0/ l.7. '-,7 :7.i- L 10 121 .0 'r: 0923 09 129 7101. 1. 2)1 5IEc+2W i.2.5 :1. .'7 BF 1 j 1. D Ann:-~~ D3 E3~,*.3 ~c *~; 3 :F N T 1 F: 1 E :) P NUCiLID PEA C E':' N~I:: T' C R OID r~2c~ I CV-IF) t1I'll IF. 'WENERGY C COUNH'TS.I .3 ,. ..ffl4 -+ --- -I --- -E- -..I COU F LNTS3 U3 LJ I"! 41 A R Y A 33'3*(OTS/SEC 2 0PA %33e V 32E-141 11731 DA- 141 CS 34 CSl I"37 CB134'I'E.3p 0 Pea 268.39 291.75'3 ",. ! e 970.43 3,:132.70 73.134.29..7'7. 3 [604.3 7;'.3 lil' " ".33 3 5" 63 T GI933 73 2Zi 795 36 II 3.3.3 3,3"-33".,:23 373 33 : I 13,33 33 II A.3'.3.3n3 3':~3 ('i 3333/:3.373 C'~2 7~3733;:):: 3;33 3;;33 373323'~'3333.333 33 33..333 3 3 373~:'3r3 3333333 33333333 3/33.333/3 33:33:3/2 3 33.3 733/3 33 3333,3 33* 3 3~333,3333, 33 3333 33 33'733~~33 .3 32373 3/33 33 3 3333 333)33 16 .3/ 1 j3.: .3 4.C 4 1. 790i3 44.1 0 0 03 179.17 9.332, 611 s3 ,2,/l / 17 3/K a J, J.37 3333': ': C33 2 area.'3,,.'..ed EGc~&G ORrEC G -1 ( 175) WAN13,2 i 4WO2.963~ 1.1-*J1L-200~Z7 160214 Pagej E~nvironmental in.-,.,~e~t u a'm (4 L inI S: SU M 01:(~3 FT 11U C:: T.11F'! C'(ZUIXFT I M CORR ::ECHD~:Do A CT IVITY AC1 VI~TY 1) E: S I N L\IC [-. 1- TiI N "" UMUIJI\V it A 41 L. E.: pCi / F..Ti. 1 pCi/LITER ,K:1U/ TEE Pývll"(... 1-Z+ ý,33, 5 :. 3 (.ý f," (::" (/'.j 3-./ I. *`' "; .5/11 7)- / Cý:Q r'S 1.'.;3 .e<R-953 t 5.3500E+0 1\1 B .3. 5 .3.3 +F",-1 j1 RU 10 1 '" 0:1 12 L 1 " Ft' .I 1- 4. 1 3 1Y LA-1 40 1 2.2 1 935E0 74,1~ SEit 5.5 1 W-137 1 K 41EW 6 E+0 E 07 1. 5 7 1.493E+01 W" 7247E001.10546EW1 to) :2024.4 .eV QI 17 ~.1 70 (0E-i (Z.10 i L -1..i I" 60.1t3o, 70 2 A .I-'.: k 3 e0 02 Vr I XI IZ 0, 0. F 1?1 3& *~ 54 3 328-76*497.08 13 U ~11" CE-14 L3 A3 1'53.32 &6.36.97 %,. 33 76.7 %.)"!1332 50%CE14 2430 &-~1-3 47 .6 373.4 604703 %~3~:33 1-131. 661 .66 N-S3 K3 1 Puak is part3' of a 3u e and-00; aea en negative~ ~ ~ ~ duig3cnvlto,$. Pea idetifed bu fis pea 3Ft faile one r mo test., S 0:.c R T E~ Cz S V -( 17 5 T ".4. 35' I4 G 11. -XULW N' I &, 47 .viron enta W .: c tI.Iii'l r ,' -1 1 W.---4127 1J'Spctu Fion me M 'd~w L Is. .3.Ar1C Star tim Liv t im 3 0 1.*- .14 :4.1.g 12: is `.-Deec o ys.4 1,1 !,'I 3.5 Liter in WE.Ze o o f et-10.e ; G i 5C1 K't !"I Stop channel -.".a Pea serc sesiivty;Sample Size-Actvi5 suain fatr 100E.EW keV/channel.s. 1.I IlK Of 3. 5 0 0 060 1.0000EWN:3:1 0 *, 2. 5~71E+01E -5a e t o limi t5' .o. .RS O methods 5 ,* .Is: ' ' , ,5 '5 ' .5,, ,5llI5?~i5..5.5I Additiona syseai eror 1.000000E+0;2.rct o Li.w,.iO.~. rs , corec io'Peaked bakron corcto W),5 YES.I' 555;'T ?f *.'b. k q4 pb.:,.. ' 5 .5.5' 5.5555 5. 5 ES: &G ac O RiEC G V. -1 ( IT75) ~ WA 3 QW: 2 96 11 ii.-. Ji JI.- 2 127 :[ !1 S:;t~: E v ironmental3 1w,1 473-.',*0 Energy calibration normalized differenceN 1 ° 2%002.1. i (,:,i q j I... ENERGY~: C;OUN.WJTS COU3:..NTS AREAP E-1 CM1P1 %l .V NUZL, I Df"C" 1 1. 3 .zi f.,:3 Ell 0 S3 .2 E,'4 4 '. 9..221E+03 47M1 1.66 L B'; I-214 C r-.Lj(ý..r .x1. D!:r ! '"? A ' NTR U,[1-C1%1NE ENE G F 1 r'E1D BA. 4GR A..CUNTS:(31 P; E A it NEI' AREA( : COUNTS 1 NI-1 +/- I -1'1-13 1 1] 'i -.-1.LA-1 40.2;13.CS- 13 RU- 10 CII10 4'I"4 'ZR-95'26. BA 29.0 370J .4 11,j 17 1 1. 4,,, C1 1446.7 D*i! 1 7 1 4., MR4 327.43 604. 7Q.1?61.3 622.904 63 .E,.724.4 I VI 255.1133 17.4 0.4 4...'1.4 7..1.00 1.1(21.1 17.7ID 0( 011-0 J.117;DFlI G "4 I 1 (88 68".32. 136 125.98 12.700,8...................................
- .a....4(4.448'4 o I 4e. 4s:1, .4~~~~~~~~s 1~I2;4'.4' 4;; 4. 4 EG&G6 OR*T(C G V T. ( .175) 1A)N2 VJ 4 2. 9 6 1:1. 1 JUL 1710 7 :1. 6, 5 6 U M [A.~ R 0F NULCL I DFE I N TIIT.(*"I t- :: C0L.pN T 1- 1 O CCI REo 1-'.ý1 R"cc I" f-i I N11 N A 11 P L. E;~. .~. .~. *NUCL I DE ATVITY p ~/ .I:: COUNT I NG;" C ,'i ....R.FE-59 <CO-58 K COI 0 ZN C-65 ZR-9 A~j RF..'0 10(tE 141 1 C -1 44 I. I'l 1 F W 4.881 ~1E-(1.';f".t.222E+0 j (1;:. W2 FEME!'9( :. 4~ 9IE + 0 OL¶5: 54EM141.1 1,36 2 + ,.t1 J. 37 1i ty 1MDA y. ... ..Ac iv'i.ty9 Fr II TO A CTFI VITY C 759 ).9 .to .,:11V5 51ICi 2024 1k V .0 0 0.4.IDD 5:. / L 1 T E. ~ F-*)I33.5 &328 M &49.0 %'I, U m CE 14 LA 141 RU-103. I RU10 ZR -95I ("1' 'to* to 11 0 145.44F 364..537.32D I SCA FT1 1-131' 477. 1 &DA-10 60.70 %i'F E A it S1 11-13 3M 8 A 4 BE747 0 1 QZi, B13 610 33&R-13% ' -7R .1.11 Peak is par of a1 ,'~. mlipltmiti rawm neative , t'oo ' ' iF~,@ ea i too wid ok F"1.1K:.
EGM ORT F) V -1 ( 1.75) WAN32 I 4 WD32: H-JULt 17 IM044 Pa e Eniomna lnc- t7ý3~~~in1 (i 1- .!-)t J rXUA 2 :3 1 LITE; 13Y1FZ J TU ,4, 0 I1 10 Dedtim DetetorGeoetr Ms:1 M I 1in u M I n m gd g1.ML Create 14-Mr-200 V 1 I. 1r~~~~14,5:2~7 I 3,4 .1 1+ w 3111 Zero offse-1.9 ')v; 7; n C :. C 7);~Y12@E-0 ke / hanneM":.501 keMhannsl Librar Fie-,, Start channel StopH1 chne Peakrejetio lvel 3 Peak~ ~ ~ serc senitviy;2apl Sz 2 .2) l F(:)I" an -' i1) ::7 5¶715 3. 501e .'ý; ;~ V C 0007I;,--1~ ~ .. 0 0 7; 2: 0 3 -F 0 Additioal systmatic erorg i 0700%0EO2. Pra:tio; LWO .000%&.Correction St at u,--,, Y E Y NI ;']Y ET.", 9 1. 7 -i:i 1:.I v --i" 0 " ;C*-.';.!. ", '.'5 i*ý*'I &VS\@ Rr .C .G V I (1. WFN32 I14 2. !2.; n 1m -Je L-207 17 1001,1 441- e ,2: Energy .caibration normal.ize ,, 1. ,'614 11.U N.. I r E .:t. N .T F 1 E r. P E.. A le, SOO IM A CI " ; I '" .., ! % I., I ' & I M L-' 1:.,I' ,: E-24. 79- 511. 4I 9A,. 157. t.6,, /Q), '1 .'-HI 4 .f i, ,-38: M E ' ?. a. 06 1 9 r', ... ..... 5. LIIE B1-214 D, a--re'-a 1-2 f.'( f~~*~ 1: i- ~-*-~ 1-1* In- D E N TC V I F ifE ) V CL, DE rPAi: K CENT ' O ID .,.,.,- ,. -,.2" /'~ IS xi U: 'r (.~ ri u.:o" : 7 '4 r7 U Il R 11- in-CI --IININEL..I EW. ROY F,.:NT 53-.......,.'. -...... ....... ...1................ -COUNTItiS CTFS I, T/ [:-:iC.S., .... .f ,- ..- -4 .. ... .41..FE- 144-I.I ,40. f 1.3' f,' ! -. I , I f~-' i " -t' :.S-. 34 6 -.. .i f ?3 " :' :14 N"0 .-CS",-134T 2 .0: 5 i'-.f,3 8 If:I.1477. 91" 73, S '.1,1. 0, 122S 21':i:;" ;f " ' I " ,'6i Z I Z ' 1 ,. ;. ..5 11. 0, .1." " 1. 59A.") 00:"" E,68. 57.IIA;5: 877 J.7!-'. 'Jr .. '. 9 , , ,h.62 5, ':§, ...C,., l , , 1 4' 4. 05 3 1 0 .O,.".* ,+7.L7. 9,t-.+,!-,3 5 .:-e.<.i- , I.610. 3.'""" " 7 6 Ii-7!: 7 81 En 3 2 I V i.J .; i r 1~3W 41.6/2M 7 ' ,Il.l", 7.3,6 l/'.1..'ilt!'.2 .,, 1 oo 12J~I,: S!#12t11f 71,1 ,, 1144!Z S1 >1 .'4.',4 012 i:1. t;"1;7-i.71;21121i C) 0.9:" i1' .17. ;7.. ...:= "1I ..7 ,, /F'/ ;'; I'.1 J 5`:`5, 3. 34j 2 "1'1 7 I:1'. 5 .6I.':07:',<'.36 !i-;'7 ;i Z. , .'7 7"e.85.1 !7 5 : ,°'5 !.5:':ii 17 , ::":.'e V 875s:1 (3.3 ),,!,, 4 7.... .I I'f ",6 380',B 71 :.. C "I s'71 I i~iI!3 ..;A0 I 1 ..:." '., J; '/73.: i. 1]'¢T I 1; Plat11. f-Win 00$3 4.:,i~ tests.2 [E:1 *oG G~v V -1 ( I 7¶5) WAN32;E QW0r2. 96 .1 ,TUL -20077 1700:1 44. P age Enviro m n a I nj~ c.,, .1-74i,,.2. ltl1'3 0 1 U, M -) !R Y D IF !' I Cý L. 1 1) E S 1 14.1A.M P L..'X, <7.- N U["; 1I DIMI*r,: " I V I "V"T ACI VITY p(.;i./L 1T R CXiUI\IT I C-58 1 (u-1 OG 4~CS 14 1 CB13 1 BA-140 <LA-' 140(CE- 44.1.578E.0 4.097E0 2.60!vD:1.67 !E+0&BB.7EW khE47E.r.5 4EoM T3.8637E+u 9 E, Q"34. N1~4&1 7803E? ;00 it 7064 E+04-!7 ,& 54 2 '1 E+021 X 808BEI(2 1.~. E1 I**'*962GE.02[S toL Aciiy rned ut act iv ity- MDCV, ,TOTL.. AC 4 4 TIVIT Y 587., 1 t :7 2021, .1 k e 1, V)77I~274 0.7 000 00 -fA /L .[1 T P+-,'R1 U D CKAYED ACTIVIT f 5~ B. I> t. 21 2724, G. 1 k e .V 7u ' I : -- !-21,71 ' .-K' i. / *:'1 1.". R 521.8 4 1'4-- -4 34.48 G36 37 76.7/, A,- I Zi17 N! 1'!." -.. "'3 5 FE-59..[O,. S 28,S4.. 4.77.6..-A,14. 70'.G, 1. ý7!1-131 BE-7 119 -1 ""ý 4 CS- 137:304.~~I 84& -.4," 4Ell 1 4 Peak I Fail sensti t tent.4 t" W.4,I 4 44 -S EG&G [3FT'EC S; V 1 (3.75) W3AN32 I 401021. 96 :11 .3L.-2f7'2,71D7 3 .5 (F"I,, U" F " ' F,-", ... ° I ' ...-: , ...' r U'" :K.U " , r _ -;.n]: in-! A ....I TXW-' 129 .5 LITER.... ' 1 ~ '5. "z'z'v "'= ....0 q.S'pe t 'um i: : ] iUI( CS \l..FF:iF rrh ,,5728'1 W !,': : L. i.ve t:i me 82'?41:I Re al t.;i me 2: Dead tim .F 0 3.F.r/ e me r 1% F FI> ., ;`]!:: 5 " N B ; 5 r' In:put;1 .:Lbr.at :i an Cre d:. .9..-.0-.:.7 100 29 &. 19 MGF Ii .G E IMETRY Mar-2007 10105-`'ýKPO 'fS'uadraticF 6.,79"7 keV... ; Gi:':i:.n , : , ' '- F " : I. F-'*'] 2 ::.022 WVuhanA.FLibr.ar F il PlIa:i.n a s ]_ i.b r'ary, t,... ...., A a ., parameter-,,. , ar.chann Stop hanne Pekreetinlee
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- 4. 2. ... ""Di. -r: 43.C Y A T1V1T C O U NT2 1 N !3 .33.2 131 SM11;W MI3TER pCi L..TER 3 ' 3 i 3 I 1 1 912M 3, ....3 1- 79 E 1 ii3 r.43697E'.
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- 10 ?U- ! I :I.i 1..:'- 3:1. ;A. -. i14 1" LA- 14 CE-14 ,i-, 401 E+0 zi,, .161,:L4 E +01 3. I. 5'.i, 4-.,9260 lE ".4'9~~hfl' t,! 'l ': a.'.', 4 ", E: I -4', 3099EM7 7: , ,939 E +O,:-3.1{,, t I, Z i * : 7E "1 Z.Q.2;:7:37 : F, ' & , 'j + I 1.2I0"'*I 4 Al pea:kssvi.;
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~ ~ ~ ~ ~ ~ .1 witnbs ehd(W n nseirm Decay durD11 anquisitio-i-i Decay durba collnctim.ý Peaked backgrow"! coromacUion S t at U Y Oi KTI, Y E E:*, aEB5 DOTEC GYV 1 ( 175) W1 !,i,!3E:-" I ,4W0a$. 2 11 JUL. 2j70 7 M52:51 Pae U 11 iF DYV EL IN F 1E 0P ,*_*! ilA I 1 A VA' ki FI_ L !...NER COUNTS COLVIT
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- Wvi-ACTIVIT p0 i/, i..TERr ACTIVITY pCi/LITER Qi/L E: K 4 Qt FE-59~ 1 0 "1 !!U :1 .f'11'-3 RU-10 CS-13J 7F F (14 LA-14 'F ICE-14I 4 CE-144~:j SI. ~ ....V..................F.-.'
1~S~ B222EF I--2'6SE+0*. 'I5 C 7 V, 1,!iF 04 F1E0 EN* 4457E+01 at W30.F I 7G~ O 63, ý I 3 3t3 .-3.034Bc ~2 , 1 E + 0 2.c:7CFF;: "E +C,1 6 E + 0'/,Fl 1.151E+1.W 811.-fN.in ' SWE.+01F.-. ! <l -K j. 2- 7L6 rzt,.. .. .. .. ... .... ..... ... ... ..' ...... ..... ... ,:" ' i ' 'YF ..F.. ... ..TOTL ATIVTY 9.9to202. 1k eV) .0959MOD 1(AnIn i a;TOF 59. 9 to 204 'I W) 'FFi)1.'~F 027460'0 QN.I ,F.l s1r(.~(F uvrivi. 'T' Fy- .~ ~ VF .c>.1 f.2.8 756.72 834.'4 1291.6 13 U 1 P F 1--' -'F' )"" AF R Y o..D.. CA RDED 109.2 FE50 1 '55 F-F7 ca-1 ..............................'"" r." ' " Pea is ' par ofF a~ F H iF V3.1.l.'.F negatie durng deonvoltion, iii .;, F: FF4.'oF ....oF .:V3; :.,I.i~' 7- E Environmental, Inc.Midwest Laboratory wn A~legkeny Technologies Co.Mr. Al Percival LABORATORY REPORT NO.: 8003-100-366 FirstEnergy Corporation DATE: 08-13-07 Mail Stop 1041 SAMPLES RECEIVED: 08-08-07 5501 North State Route 2 PURCHASE ORDER NO.: Oak Harbor, Ohio 43449 Sample ID Lab Code Collection Date H-3 (pCi/L) LLD MW-31S TXW-5194 07/31/07 7322 +/-262 < 176 MW-31D TXW-5195 07/31/07 108 +/- 97 < 176 MW-32S TXW-5196 07/31/07 7535 +/- 265 < 176 MW-32D TXW-5199 07/31/07 507 +/- 113 < 176 MW-33S TXW-5200 07/31/07 2702 +/- 175 < 176 MW-33D TXW-5201 07/31/07 3271 +/- 178 < 173 MW-34S TXW-5202 07/31/07 2839 +/- 169 < 173 MW-34D TXW-5203 07/31/07 1076 +/- 126 < 173 MW-30S TXW-5204 07/31/07 1149 +/- 128 < 173 MW-30D TXW-5205 07/31/07 231 +/- 100 < 173 MW-37S TXW-5206 07/31/07 2961 +/- 171 < 173 MW-37D TXW-5207 07/31/07 135 +/- 96 < 173 MW-12S TXW-5208 07/31/07 860 +/- 120 < 173 MW-12D TXW-5209 07/31/07 1155 +/- 128 < 173 DBD-01 TXW-5197 07/31/07 7185 +/- 260 < 176 DBD-01 (duplicate) TXW-5198 07/31/07 7734 +/- 268 < 176 The error given is the probable counting error at the 95% confidence level.Less than (<) vf are based on a 4.66 sigma counting error for the background sample./ SA Coorlim Grob Manager Quality Assurance .-- Iva#I ,JI IIII I ,al. Inlc.Midwest Laboratory an Ailegheny
- Technotogies Cc, PRC-S3 Form LS-4 V-. 10 0.10032g STD T-36 TRITIUM LSP-2000CA
/LSP-2350TPRJ/AB .LSP-2800TR L_init. & Count Date: 0 /0 1 BKG BKG Sample STD STD STD 1 Date Time Counts Time Time Counts Act-Vit7 issued.(p-)c%00 _________ 00 _O209 1o0 0o.78 S01/18/20D1 Sample ID Volume Sample Remarks (m1d) Counts 91q6 5o-51_ q_ 0__7 S,/o IGIq )_____ 1_____ ) ,cbqo 0 -4ECotAfl_ __ __ _ _ I1_ _ _ _ _ _ __ _ _ _ _ _ I ___ -nvironmental, Inc.Midwest Laboratory an Allegheny Technologies Co.PRG-33 Version No. 1.0 06/17/97 Programmed by Rick Lesko Sample Count Time (min.): Background Count Time (min.): Background Counts: 0 TRITIUM RESULTS SHEET For any sample counted on the LSP-2550TRI/AB, LSP-2000CA or LSP-2800TR Reviewed and Approved by Date approved: 100 200 681 Standard Count Time (min.): Standard Counts: 200 52906 0.169 Date Counted: 8/10/2007 Calculated by: Tony Date Calculated: 8/13/2007 Counter Efficiency: Sample Coil. Vol. Sample Corr. pci /L 3.00 4.66 ID. Date (ml) Counts Factor Activity. Sigma Sigma ID._ Vol. I_ I__ Fato Sigma S _ _ igma_TXW- 5194 TXW-5195 TXW-5196 TXW-5197 TXW-5198 TXW-5199 TXW-5200 TXW- 5194 7/31/2007 7/31/2007 7/31/2007 7/31/2007 7/31/2007 8/1/2007 8/1/2007 7/31/2007 13.0 13.0 13.0 13.0 13.0 13.0 13.0 13.0 3913 393 4017 3846 4114 588 1659 3908 0.998 0.998 0.998 0.998 0.998 0.999 0.999 0.998 7321.848 107.599 7534.996 7184.531 7733.798 507.174 2701.854 7311.600+/-r+/-++/-261.928 97.281 265.242 259.770 268.297 112.854 175.286 261.767 1029.644 98.376 1058.530 1011.038 1085.477 132.264 407.120 1028.255 113.456 113.456 113.456 113.456 113.456 113.439 113.439 113.456 176.235 176.235 176.235 176.235 176.235 176.208 176.208 176.235 Best probable result. L-uU/l'LTT 1t-: r-nvironmental, Inc.Midwest Laboratory an Allegheny Technologies Co.PRG--33 Form LS-4 VE. 10 LSP-2000CQk D TIIT1UM LSP-25850TR/AB LD LSP-2800TR --1 Irdt. & CountDate: b " 0e / 10 /Q7 0.10032g STD T-36 BKG BKG Sample STD STD) STD Date Time Counts Time Time Counts Ac9vity Issued c200 -7qO 0 IGO50 1003.78 01/18/2001.Sample ID Volume Sample Remarks (reil) Counts£C9Ao( _____ 5, 9o , 16 7)__ ___ 0. I00l%r/#-9aoq 1%/0 9 7b AO 967 10 a_ __ _ 9 0_ IV _ _ _ _ _ f________ I ___ ______ ________________________________________________________________________________________ ___________________________________ ________________________________________________________________________________ I ____________________________________________________________________________ S.-: Environmental, Inc.Midwest Laboratory an Allegheny Technologies Co.PRG-33 Version No. 1.0 06/17/97 Programmed by Rick Lesko Sample Count Time (rain.): Background Count Time (min.): Background Counts: TRITIUM RESULTS SHEET For any sample counted on the LSP-2550TRIIAB,'LSP-2000CA or LSP-2800TR Reviewed and Approved by: Date approved: 100 200 874 Standard Count Time (min.): Standard Counts: 200 61036 0.195 Date Counted: 8/10/2007 Calculated by: Tony Counter Efficiency: Date Calculated: 8/13/2007 pCi/L Sample Coll. Vol. Sample Corr. Actvity+/- Error T.P.U. 3.00 4.66 ID. Date (ml) Counts Factor Sigma Sigma TXW-5201 8/2/2007 13.0 2276 0.999 3270.792+/- 177.661 478.994 111.541 173.260 TXW-5202 8/2/2007 13.0 2033 0.999 2838.599 +/- 168.786 421.335 111.541 173.260 TXW-5203 8/2/2007 13.0 1042 0.999 1076.035 +/- 126.291 193.300 111.541 173.260 TXW-5204 8/2/2007 13.0 1083 0.999 1148.957 +/- 128.329 202.200 111.541 173.260 TXW-5205 8/3/2007 13.0 567 0.999 231.179 +/- 99.680 104.521 111.523 173.233 TXW-5206 8/3/2007 13.0 2102 0.999 2960.865 +/- 171.327 437.610 111.523 173.233 TXW-5207 8/6/2007 13.0 513 0.999 135.088 +/- 96.148 97.888 111.472 173.153 TXW-5208 8/6/2007 13.0 921 0.999 860.299 +/- 120.003 167.600 111.472 173.153 TXW-5209 8/6/2007 13.0 1087 0.999 1155.360 +/- 128.447 202.948 111.472 173.153=Best probable result. ,1.5,: I "=&--I "I ;BETA LABORATORY 6670 BETA DRIVE, MAYFIELD VILLAGE, OHIO 44143 SAMPLE ANALYSIS REQUEST i CHAIN OF CUSTODY 1-800-470-BETA 440-604-9802 FAX 440-604-9800 CHAIN OF FORM X-2189 (REV. 05-07) -vYES I- NO PAGE / OF/F-1 NO COMPANY NAME-.,,, ADDRESS / LOCATION BILLING ADDRESS * ..TURN AROUND TIME (Surcharges May Apply)[E SAME DAY[-124 HOURS[ 48 HOURS E STANDARD ANALYSIS REQUESTED SAMPLE MATRIX CITY TELEPHONE NO.7fV STATE.#-,,e ZIP CODE , D4 A = ASBESTOS AS = FILTER-ARSENIC F = FUEL OIL& COAL M= METAL O = OIL P = LEAD IN PAINT W= WATER OT= OTHER 1-IFAX NO.REýORT A.TTENTION E-MAIL RESULTS[MAIL El -FAX D-L-MAIL P R E S E R V A T I V E ZZ~N PURCHASE ORDER NO.SAMPLE REMARKS: (Conditions, Bottle Type, Etc.)LAB I.D. I SAMPLE IDENTIFICATION I COLLECTION MATRIX .DATE COLLECTION TIME.i: / ".7 u i ...f..... /.1 /RELINQUISHED BY (Signature)
- -, DATE TIME .,P VED BY (Sign d), r, e DATE TIME ADDITIONAL COMMENTS: REILINOWSHEb)"BY (Signatdreo, .-- DATE' ,TIME FqEQEIvED TM_!RELINQUISHED BYA(Signature)
DATE TIME -BYIVEy. (Signature) DATE .TIM"/.L 1 2 1 ' --h J .... < ,'.' "*. Q3.-7-d .__._ .COPY 01 RIYBUTION: WHITE -ACCOMPANIES SAMPLES, YELLOW -w.B COPY, PINK -CUSTOMER WEBS'fTE FORM: ORIGINAL -ACCOMPANIES SAMPLES, CUSTOMER -RETAIN COPY FirstEnergy/ BETA LABORATORY 6670 BETA DRIVE, MAYFIELD VILLAGE, OHIO 44143 SAMPLE ANALYSIS REQUEST / CHAIN OF CUSTODY 1-800-470-BETA 440-604-9802 FAX 440.604-9800 CHAIN OF CUSTODY REQUIRED?FORM X-2189 (REV. 05-07)' [VYES PAGE OF'iF' Mfl M NO COMPANY NAME ADDRESS i/ LOCATION.. .. , fk, , 'TURN AROUND TIME (Surcharges May Apply)E[ SAME DAY[3 24 HOURS El 48 HOURS 2ISTANDARD ANALYSIS REQUeSThD SAMPLE MATRIX BILLING ADDRESS CITY STATE r \... ., V " , 'ZIP CODE 4 TELEPHONE NO. FAX NO. [ RESULTS REPORT ATTENTION .. E-MAIL []MAIL PURCHASE ORDER NO. " , .R -MAIL P R E S E R V A T I V.E N It A = ASBESTOS AS = FILTER-ARSENIC F = FUEL OIL& COAL M = METAL 0 = OIL 'P = LEAD IN PAINT W= WATER OT= OTHER SAMPLE REMARKS: (Conditions, Bottle Type, Etc.)LAB I.D.SAMPLE IDENTIFICATION MATRIX COLLECTION DATE COLLECTION TIME ,c 2(.: :; NA. F~i. .. o"--- -i- -o-]-i-v" .- ._5o RELINQUISHE DtYA Signature) DATE ~TIME RECEIVED BY. (Sigihature), DAT ,E TIME ADDITIONAL COMMENTS:-L -7 C k).3 ~ ~ I ~ Ic y.I "/ATE TIME RECEIVED BýTgnature) .DATE TIME 0 J,": v"ý 91 *0".3.> 6.RELINQUISHED BY,-.ignature) DATE TIME .RE ED ' (Signature) DATE TIME ,-_,.2 APL, 7! _._._ _COPY 51§S-FIB13TION: WHITE -ACCOMPANIES SAMPLES, YELLOW -VIB COPYp, PiN -CUST6MER WEBWSITE FO4M: ORIGINAL -ACCOMPANIES SAMPLES. CUSTOMER -RETAIN COPY U 1 S -. .yBETA LABORATORY 6670 BETA DRIVE, MAYFIELD VILLAGE, OHIO 44143 SAMPLE ANALYSIS REQUEST / CHAIN OF CUSTODY 1-800-470-BETA 440-604-9802 FAX 440-604-9800 CHAIN OF CUSTODY REQUIRED?FORM X-2189 (REV. 05-07) " F- NO PAGE I OF COMPANY NAME ADDRESS / LOCATION TURN AROUND TIME (Surcharges May Apply)El SAME DAY El 24 HOURS El 48 HOURS* ý:TANDARD ANALYSIS REQU'EST"ED BILLING ADDRESS b. ý SX SAMPLE MATRIX A = ASBESTOS AS = FILTER-ARSENIC F = FUEL OIL& COAL M = METAL O = OIL P = LEAD IN PAINT W= WATER OT= OTHER CITY STATE ZIP CODE TELEPHONENO. FAX NO. RESULTS REPORT ATTENTION E-MAIL .1 MAIL PURCHAS OARDER ý 1 E FAX PURCHASE OR DER NO. .)9 L--E-ML P R E S E R V A T I V E SAMPLE REMARKS: (Conditions, Bottle Type, Etc.)LAB I.D.COLLECTION DATE SAMPLE IDENTIFICATION MATRIX COLLECTION TIME 2.t. -1~ .f 1 _5 rny 4- S vv .,., -I'Y\,Q V A/1 .1h /!7 )Lon__ __RELINqUISHED BY (Signature) DATE TIME RE, B tur DATE TIME ADDITIONAL COMMENTS:________________ !___-_-_, ___, _ ohi::) i1925 , ,,, ..,>.,/.J : ,V .'q -b "-RELANQYISHED BY (AT TIME R- DATE TIME RýENO'UISHE6DY4Signature) DATE T TE EIV-61"BY (Signature) DATE TIME..... _________.__"___-__,_,__ I .- ._ _- _ _, __. _ .. ._-_ _ __PIE, COP Y DISTRIBUTION: WHITE -ACCOMPANIES SAMPLES, YELLOW- ,PN1W --t0SF4-1TER*- --WEBSITE FORM: ORIGINAL -ACCOMPANIES SAMPLES, CUSTOMER -RETAIN COPY FýrstEnergqy SAMPLE ANALYSIS REQUEST I CHAIN OF CUSTODY FORM X-2189 (REV. 05-07)BETA LABORATORY 6670 BETA DRIVE, MAYFIELD VILLAGE; OHIO 44143 1-800-470-BETA 440-604-9802 FAX440-604-9800 CHAIN OF CUSTODY REQUIRED?I ~jýYES i-- NO PAGE f OF D NO COMPANY NAME -.., ,*ADDRESS I LOCATION TURN AROUND TIME (Surcharges May Apply)El SAME DAY El 24 HOURS El 48 HOURS ,9S"ANDARD ANALYSIS REQ6ES`TED SAMPLE MATRIX BILLING ADDRESS CITY STATE ZIP CODE A =AS=F=M=0=W=OT=ASBESTOS FILTER-ARSENIC FUEL OIL & COAL METAL OIL LEAD IN PAINT WATER OTHER TELEPHONE NO. FAX NO. RESULTS REPORT ATrENTION E-MAIL .El MAIL AL .-- I , .-... ... ",- " E] FAX PURCHASE ORDER NO. .-., , , -.' .!EMAIL P R E S E R V A T V E Q;_.-SAMPLE REMARKS: (Conditions, Bottle Type, Etc.)LAB I.D.SAMPLE IDENTIFICATION MATRIX COLLECTION COLLECTION DATE TIME 2r)yi1 .Y 1 Z W. \ _' _ _._ __s , * '! .-i"n .J_ A RELINQUISHED BY (Signature) DATE TIME R VED BY (Situ DATEi TIME ADDITIONAL COMMENTS: RE(9 i'OUISHED. BY ;Signature)) L DTE TIME RECEIVE,ý -ature)RE)LINQUISP-EDi BY/(Signature) DATE TIME R Eý'IVEV' BY (Signature)
- DATE TIME A 47 'J) " ---< _CqP'Y DrSTRIBUTION:
WHITE -ACCOMPANIES SAMPLES, YELLOW -LAB COPY, PINK- CUSTOMER VWEBSITE FORM: ORIGINAL -ACCOMPANIES SAMPLES, CUSTOMER -RETAIN COPY _,,...tne. gy. BETA LABORATORY 6670 BETA DRIVE, MAYFIELD VILLAGE, OHIO 44143 SAMPLE ANALYSIS REQUEST/ CHAIN OF CUSTODY 1-800-470-BETA 440-604-9802 FAX 440-604-9800 CHAIN OF CUSTODY REQUIRED?FORM X-2189 (REV. 05-07) EYES F-1 NO PAGE t OF )COMPANY NAME'-V.---.--,< &~, £TURN AROUND TIME (Surcharges May Apply)ANALYSIS REQUESTED ADDRESS I LOCATION[- SAME DAY El 24 HOURS[E 48 HOURS 9STANDARD BILLING ADDRESS SAMPLE MATRIX A = ASBESTOS AS = FILTER-ARSENIC F = FUEL OIL & COAL M = METAL 0 = OIL P =. LEAD IN PAINT W= WATER OT= OTHER CI TY STATE:. .ZIP CODE TELEPHONE NO. FAX NO. RESULTS REPORT ATTENTION E-MAIL *l MAIL PURCHASE ORDE. NO......... FAX PURCHASE ORDER NO. -.. .' ... P R E S E R V A T I V E r-SAMPLE REMARKS: (Conditions, Bottle Type, Etc.)LAB I.D.SAMPLE IDENTIFICATION MATRIX COLLECTION DATE COLLECTION TIME N V,../ -'-._______. ____..... ....__'____ _ -, -. .-D '7 ,, j . 7)RELINQUISHED BY (Signature) DATE TIME RECEIVED BYP(St nature) DATE TIME ADDITIONAL COMMENTS: RELINQUISHED B'Y(Sihature) -7 DATE TIME RECEIVED BY -nature) DATE TIME~~~~~~'~~~o I"?- C"Z6 2//7 ýd)" .~ u' ' J)~RELINOI6tSHEDOBEC(Signature) D1ATE' TIME
- ECEIVE,[ BY (Signature)
DATE TIME-.-____ &XJC)......... Xi >Y) .__,_-.___ ____.______,_ ____.. ...____COPY'DISTRIBUTION: WHITE -ACCOMPANIES SAMPLES. YELLOW -LAB COPY, PINK -CUSTOMER WEBSITE FORM: ORIGINAL -ACCOMPANIES SAMPLES, CUSTOMER-RETAIN COPYe 0 -'&-- Environmental, Inc..Midwest Laboratory SAlleghenyTeo og.ies Co.700 Lancwehr Road .Northbrook, L 00062-2310 ph. (847) 564-0700. fax (847) 514-4517 Mr. Al Percival LABORATORY REPORT NO.: 8003-100-370 FirstEnergy Corporation DATE: 11-06-07 Mail Stop 1041 SAMPLES RECEIVED: 10-06-07 5501 North State Route 2 PURCHASE ORDER NO.:__Oak Harbor, Ohio 43449 Dear Mr. Percival Enclosed are results of the analyses for tritium and gamma-emitting isotopes in twenty-two ground water samples.Should you have any questions or other concerns, please do not hesitate to call.S.A. Coorlim, Quality Assurance SAMPLES RETAINED THIRTY DAYS AFTER ANALYSIS Report: 8003-100-370 Page 1 of 3 Table 1. Results of analyses for tritium and gamma-emitting isotopes in fourteen ground water samples.Sample Location MW-102B MW-102C MW-IOOA MS02MW100A MSDO2MWI00A Date Collected 9/27/2007 9/27/2007 9/24/2007 9/24/2007 9/24/2007 Time Collected 10:59 15:05 14:50 14:50 14:50.Lab Code TWW- 6749 TWW- 6750 TWW- 6751 TWW- 6752 a TWW- 6753 a Isotope Concentration (pCi/L)H-3 394 1 114 < 193 < 193 16321 + 369 16925 8 375 Mn-54 < 2.2 < 3.8 < 2.5 .< 2.3 < 2.5 Fe-59 < 5.7 < 8.2 <. 3.3 < 4.7 < 3.7 Co-58 < 1.9 < 3.2 < 2.3 < 2.3 < 2.5 Co-60 < 1.6 < 3.6 < 2.3 < 2.1 < 1.1 Zn-65 < 3.9 < 7.2 < 2.9 < 1.9 < 4.1 Zr-Nb-95 < 2.7 < 3.5 < 2.3 < 3.3 < 3.4.Cs-134 < 2.5 < 3.2 < 2.0 < 3.0 < 2.6 Cs-137 < 2.8 < 3.8 < 2.3 68.6 +/- 7.6 70.2 +/- 7.5 Ba-La-140 < 5.8 < 7.2 < 4.1 <.4.1 < 2.1 Sample Location MW-101A MW-01B MW-101C RINSEATE BLANI MW-103C Date Collected 10/2/2007 10/2/2007 10/2/2007 10/2/2007 10/2/2007 Time Collected 10:23 11:49 14:20 14:40 15:07 Lab Code TWW- 6754 TWW- 6755 TWW- 6756 TWW- 6757 TWW- 6758 Isotope Concentration (pCi/L)H-3 237 89 207 108 < 193 < 149 < 149 Mn-54 < 3.9 < 3.1 < 6.8 < 3.1 < 5.8 Fe-59 < 7.3 < 5.8 < 8.7 < 4.5 < 6.7 Co-58 < 5.5 < 2.4 <ý 4.3 < 2.8 < 4.2 Co-60 < 2.9 < 3.3 < 3.8 < 1.8 < 5.6 Zn-65 < 5.0 < 3.5 < 11.8 < 2.4 < 7.7 Zr-Nb-95 < 4.4 < 4.0 < 4.3 < 3.5 < 2.7 Cs-134 < 5.3 < 2.9 < 4.3 <3.4 < 5.7 Cs-137 < 6.8 < 3.7 < 6.0 < 2.8 < 6.3 Ba-La-140 < 9.8 < 5.5 < 6.4 < 4.9 < 5.7 Known spike activ Cs-137, 65.6 pCi/L.* H-3, 17185 pCi/L.The error given is the probable counting error at the 95% confidence level.Less than (<), value is based on a 4.66 sigma counting error for the background sample.0 Report: 8003-100-370 Page 2 of 3 Table 1. Results of analyses for tritium and gamma-emitting isotopes in fourteen ground water samples.Sample Location MW-100C MW-100B MW-102A MW-102A MW-103A Date Collected 9125/2007 9/25/2007 9/25/2007 9/25/2007 10/1/2007 Time Collected 11:06 0:00 15:21 15:21 10:31 Lab Code TWW- 6759 TWW- 6760 TWW- 67.61 TWW- 6762 TWW- 6763 Isotope Concentration (pCi/L)H-3 < 149 < 193 344 +/- 113 387 +/- 114 495 +/- 117 Mn-54 < 2.9 < 3.9 < 2.3 < 1.8 < 3.4 Fe-59 < 2.0 < 5.6 < 4.9 < 5.2 < 9.0 Co-58 < 3.3 < 3.9 < 3.1 < 2.1 < 6.6 Co-60 < 2.4 < 3.6 < 2.9 < 2.2 < 1.8 Zn-65 < 4.2 < 8.4 < 5.5 < 2.8 < 7.8 Zr-Nb-95 < 2.8 < 5.2 < 4.7 < 3.1 < 5.7 Cs-134 < 2.9 < 3.6 < 3.1 < 2.5 < 4.8 Cs-I137 < 2.3 < 3.5 < 2.1 < 2.0 < 5.8 Ba-La-140 < 5.5 < 8.3 < 9.4 < 3.6 < 10.9.Sample Location MW-103B DBD-04 MW-104A MW-104B MW-104C Date Collected 10/1/2007 10/1/2007 9/28/2007 9/28/2007 9/28/2007. Time Collected 12:30 12:00 10:07 11:42 14:42 Lab Code .TWW- 6764 TWW- 6765 TWW- 6766 TWW- 6767 TWW- 6768 Isotope Concentration (pCi/L)H-3 362 +/- 113 394 +/- 95 237 +/- 89 250 +/- 89 < 193 Mn-54 < 3.3 < 4.5 < 1.6 < 2.4 < 2.5 Fe-59 < 5.8 < 7.7 < 5.0 < 6.4 < 6.6 Co-58 < 3.5 < 2.5 < 2.1 < 1.9 < 1.8 Co-60 < 3.5 < 3.6 < 2.6 < 2.1 < 1.4 Zn-65 < 4.9 < 4.4 < 3.1 < 2.0 < 3.8 Zr-Nb-95 < 5.0 < 4.9 < 3.8 < 2.8 < 3.5 Cs-134 < 4.8 < 5.4 < 2.9 < 3.2 < 3.3 Cs-137 < 3.8 < 4.8 < 3.3 < 2.6 < 3.6 Ba-La-1 40 < 8.2 < 8.6 < 6.6 < 4.4 < 2.5 The error given is the probable counting error at the 95% confidence level.Less than (<), value is based on a 4.66 sigma counting error for the background sample. 0 Report: 8003-100-370 Page 3 of 3 Table 1. Results of analyses for tritium and gamma-emitting isotopes in fourteen ground water samples.Sample Location MW-35S MW-35D'Date Collected 10/3/2007 10/3/2007 Time Collected 10:26 13:00 Lab Code TWW- 6769 TWVW- 6770 Isotope Concentration (pCi/L)H-3 227 +/- 88 368 +/- 94 Mn-54 < 2.9 < 1.8 Fe-59 < 4.4 < 5.0 Co-58 < 3.7 < 2.2 Co-60 < 3.3 < 1.6 Zn-65 < 3.5 < 5.6 Zr-Nb-95 < 3.9 < 3.1 Cs-1 34 < 4.5 < 3.9 Cs-137 < 4.7 < 2.0 Ba-La-140 < 5.0 < 2.5 The error given is the probable counting error at the 95% confidence level.Less than (<), value is based on a 4.66 sigma counting error for the background sample. -EEnvironmental, Inc.Midwest LabDratory ,* an Allegheny Technologies Co.PRC-33 Form LS-4 Ver. 10 ThUTIUM.ounter ID: LSP-2000CA " LSP-25501TR/AB L_LSP-2800TI I 0. 1003 2 g STID T-36_nit. & Count Date: -/BKG BKG Sample STD STD STD Date Time Counts Time Time Counts Activity Issued 200 72,2 (00 200 5!303 1003.78 01/18/2001 Sample ED Volume Sample Remarks (ml) Counts-t 7g2S 2 qo77-7{ f -Il 1,,( 7 7f~~2~~ l 1 1 4 7 S_ _ _ _ __ _ __. .._._ _ __.. ._ _ ___ _ ....__ __ __ _ I _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ I_ _ _ _ _ _ _ _ _ __ _ _ _ ii 1 _ __ _ 1 _ _ _ __ _ _ _ _ _ _ _ _ _ _ _ _ _ i ___' (UA/ 7S 2 4 6 7 ,S3 0 -)? 8 1ýý 4 '7 f 9 f 1 7, 1 1 c /UL 2 7, 14q ( L Environmental, Inc.Midwest Laboratory an Allegheny Technologies Co.PRG-33 Version No. 1.0 06/17/97 Programmed by Rick Lesko TRITIIJM RESULTS SHEET For any sample counted on the LSP-2550TRI/AB, LSP-2000CA or LSP-2800TR Reviewed and Anoroved bv: Date anoroved: Sample Count Time (min.): Background Count Time (min.): Background Counts: 100 200 732 Standard Count Time (min.): Standard Counts: 200 55038 0.178 Date Counted: Calculated by: Date Calculated: 11/3/2007 11/5/2007 Counter Efficiency: pCi!L Sample Coll. Vol. Sample Corr. Activity -TPU 3.00 4.66 ID. Date (ml) Counts ,Factor Siema Sigma TWW- 6752 9/24/2007 13.0 8717 0.994 : 16320.983 +/- 368.751 2250.075 112.168 174.235 TWW- 6753 9/24/2007 13.0 9026 0.994 2 16924.885 +/- 375.097 2332.147 112.168 174.235 TWW-7185 10-8-2007 13.0 14157 0.996 26894.847 +/- 467.066 3687.399 111.927 173.860 TWW-7186 10-8-2007 13.0 14595 0.996 27749.023 -474.145 3803.536 111.927 173.860= Best probable result. S :", C~:~ .:I::i C: cV1 ! T :i1 4' 4W@ '0J~1 ~ 2. 9~ C., i 1 1'E d2 .m :I ' escri p- :: 1 U :/71 Start time Liv time~Rea timeC: Dead time:1.12347.12,,,"'3 .5' 1 Zero offset -1.980 kevq Gai" Quadratic c'h Library File--:.ýI'll ai 2.5611 keU/Mayn-,e]. 5 0 (,`l Pea serh sensi. .ityn fcv. of 3 0. 0 0 0 *x*, 13 2 0 , I 3,. 50(.'.-C.OO111CCECcc0jK/( ., IJ.OOOOE+00$I*~C:( 'T*C C::...BacgrondC widt P betmto ,nI w ~arm Correcti: C.:.ýDC :.Ij c':CIC'.;:::.:v SWWýý.Y' E (, .3 Ci c, 1-.: 2 U 7J'e :.i:: 2c ('3*.-to A-; r -y (:.- o-f-- -f.. A.. J. ci o 11-1 s u 1-1-1 j-1-1 i I N 0 V -I ( 175) WAN3R 14WOR. 96 E. -I--1vJ. r oy-f T-nc.'2 EnerMy calibration normalized differenceu M A-4 tj N I D E N T I F 1 1) Ill. S 1:'ý" Y BACK(TOWND NET ARM EFFICIENCY UNCERT IRM SWSPECTED C01.314TS COMM3
- RRE11 2. 11.1 IJ C* 1". 'T D....... ..... .. ...... ..... .4--l-4 ..... .. f-f-f-f- f-f -+-I -+-+-1220.15 609.27 '13. 105. 1.2T8E+O,';;
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.......'" '" .C"" .'"""" " 1"" .. C.C.. C",."C÷'- 1"" Z 114 ZR-95 lu J~ <RU10 <RU:0 1-131 Cs-~ K3 CB-137 I.A:140 LA-14-4.I .i, .t I.4 7@85E :W it 1096E+0:1. (".10 2.6150E+00i i C: 2.770E+0:. 7.6249EI00 GL~ 2571E :1.A:: ACct.;iviy A C p C i. ?IX:ci , butu. Ca:~ctivit*'y < C'iC (---' .. .... ... ... ... ... ... .. ......... ... ... ....... ........ ý .3 CI I' ly C f.. :, y.. ..... .. ... .. .. .. .. ........ .. .. ....TOIS ACTVIT (1 58 .. .1 to 21~2026.1I
- C:tiC.:CC~i.C kev j)*.. T TOTAL.. D:E:!i:CAY:ED; A:CT IVITY : C5 .1 to 2026( S.1 ikeV) 0.0000E0 pIA/ 1: .ITER.CL 13 .t CE-14 364.48 X -13 T.'*33/4 .i 32 X A C4 63 .9 % 1-13 76.7 % i NB9 1099.2 C % FE-59 13 05 C CO-60 ("t ;. C ('. C 1) : S 108 .3 X 'C- 'C 47.6 & BE.S0C...0 %~ CS-13.661.66 & CS Ca 795.8 St
- CS-13-1.15.5 %. ZFi 1460.81 .610i. 33 7I4.1 81 7 CC!5 1 (4 1ý 4k.32 .7 L A) -' 144'f 497.08 ICii I 84 Fý! .. i'IC C Pea fal C mst t test, CPCak iet ifiedi biut fis peak, of C CC A fa'iledti one~ C or tCCI ,f iIt~~I~r ci &c [:OTTEf GICC V I1 ( 1,75I) WANf32 14W(O2C.9 29, COCT-RO0f7 M~44:39~ Pag T1,01,0 5 LA:Tf.',ýýR k" I ", ý /f- 4Ic l i I I 'i i i Str tim R i UW t "' ime Rea t ime Dead t Iime 1. I 1 1%Ca I I i iaio-IIIC, I. L Cr Ied 14Ma -20 M5 0 IIPIr2 511M I"IJ .Y1 aI *1,-I J, :. .r a II C.. f ..Pea rejecion lee Sapl Sii, Activity ~ I selig .jco f1 T.. 1o r- n V 30.000ILI%
,~, 1..~ ~ 3 5L~II / 1 .iifI i: W TWOOMOO Frc ti 1 Li it L',; ': I. 000% 5 i ici: tJ u I:-u s t o Decay. duig oleto St1t iii it: Y E c:~ ~::fYL I 7 I 2 :1.2 MU S (D~i Vi: -l Ii ( 175~:) WAN321/4~9 14 LO@:..96 LR9-OCT-RNO0'7 fO'944M3)i 2: Energy calibration normalized
- 1., f..?}7j} H-C'I- _I'liLý: ~I( E:j V~ii : V"1 3jY.Ii D E 4T I:F I IH 1:, Iii: :* K S lENJ I AMH Y : :: I- f f f f f f --f f f f_ f f f f f f f f f f..A... ._. .r ... + -4 ... .... .i 44.... ... .34 1 ... .1 .i 4 4 i ... --703. 3%; :1.1.44.'PC Us 04610 J-IM3 I D E N 1PEA CENTRI, i T 9..s :4 ý..` 4.* 7i~ 0 B~~iiii *..5 .P9 4 7 6 LA-140 974.9 48.4 CB137 1318 i'0.9 CB-14 M9 .67 '79.86[:Ti: 9 5. 1i 109 .0 120.174 Rio.:16 13.4 1) AR.Iiii-:14 51.13 U I11 IVI (", I;*. Y *f *34 fi* *, fy ~3.:1.f-I[1;I lii I~ I t I, ii ii Ill G(Cvi.3 [4 [J (I'll I ii ill"IL" I ii '1.1 ii 14 I. ' '3 44 124.46 2 8 .0,4 I Ii3 147.3 580 0 waT~nonuom Wjap WT4hak.01V 1.4) %3 !..'i'I1C..3
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2I. 0 764.1F:l- .-:1. l4 3I: 0 fi'. ", "J E i :i ENi' 7085;.. 1 1.i 5906:. 8 ,0 1";'13) " 01 1 .1, 1,,- -t 11. 11,):I:1. ,, tJi I,, ..:':.-} ti"'j.U4:: .:,,2 4 f4 ii t:-. ,::., ,, I9! E "".)?* ~ J -I-- t.At Aciv ityI1 pr inte~s.d, bu.t; actvit < I .M.. ........... .. ...... ... ............ ..... ............. ..... 11 11 F.1 Y... .....t ... .....t.. ... ... ........ ... ... ... ... ...-)( ,( ). X II--). ' '- U 11 NI r) F..' Y ~ **D F, D ~ I ý.-- C 11 F" E 1:1. IF 1-'t- 1. 284.30 49.0 % RU-10 53.2%B 411 64.7 12 1 6 & F -1 1 13 2. 1 'o' C 6 :1 4"' (. 0. a I %I JI ý;Z1 KI 14- ý1 .11 :.4 L 4 -:1. 4 'Peak is part of a negative du'fýi-nq Peak faih; sevylitivity test.1; F, a identified, but of uc.-IJ. d failed one or more T ( :1. 1;.) f: ) 1 -1 1: 4 1,4 C,".1 4.,ý C.11 C"." T' --2 (,.1 f..?s -7 J. ID A !jI e Wvironmental Inc.-in j I. T 1, ."F" yoI DeetrGoer IIIs s :i, J;I'll C', :1. T T.-. :1, CaIi a i wn ..I Ited 14Ma -20 1*3 :3 N4 & 0Mr20 N2 Library Ia':;I Aayis paraeter Pea reeto ee Pea sarh enitviy: 2. 1i. 1:-.3..Detection lWit method:;1 0 E: 14. (.,J Additional systematic eprors 1.000000011+00 Fraction Limit:: Background widthN lest method (based on spectrumKI Correct i Stti, Comments 22.W. I., 1 "T SUN T I.', 16' S T T I 1/T f. '*'I 3.) W 92 IM T 03 OW'..f T 0 ('D 200~f S13.'" Ti TOO 0003 TOO'i 000" MI r 0) j BOO"1 T3 010 3/00l (4,.T"ET"R 1 C 9'1.: liP!I?I I 1) '1' r 11 4.1 44 4'9 OT 61 S 0 .." C.3 Z .4, 0 tIIT i'., 1:3 JT q: 6:,"T 41:.I 4 I Ii 1 ('4' ' I 4, II 4..4 II I III'44' (4 3 4(I'l 4 I I 'I.44 I Ii I.11 I S., I 33ff I f1'I/I I'.3'I I)-ý I i --i" ............. I,.. .... 4. ..... .. V.- .41. -.1. + 1... 71 ....... 11 1 11 ...... i, ..... .4 ...... ...... 11, .- --f ..... .. 11.1 -e- .- 4. -.. .ý ...... Ir .... " -, 4. .- -I.- -I Jr ý I'. .... + -.I. I.,,- I.. I.,,.. .--. .e- .-I. 'A. .- Ir I.- -Ir I... .- .-ý .n'...443.3. 44 y... ~ ~4444 A4 .)ISN31N11>31 1*0.*:) 3 1 0'.I:11 1 A (1 .1. (37( 3 N I :'lk:JUiI'::1 3121 .1. 124(1 N J,~a F U , 4,WI 9FI. a::., 4 E , ROW1 E 1i)IO.(M "6.: "91 T Z:, T, VT'COME3 1: .1'.4 (",1 :. .'.; I 20 i 4 .. .... ..... .......... ..... .......... ():311iJ:l'::Isfl)34 4.444. 344~ .44.7.7.4.4 .4444.44 .~. 4.C ,*~ .~I'.4 4I'I'~lT;:j 14 I'] i.1 V.1 4,34 ( :ii 73A : (. .:.::: (I I .::I1 1. 1-j :A (I.,l Vi 44~ 44. 44 44.7.43.44.14. E1 abe M U PU 34.4,i.4'4 I.Oo a 2E1. (Sp 341~.:L........ ) Ij (I'z q ~ 31 1,10 E 01,1I~u. o 13 4 .3" (3) ~. 4'::: 3:4 '3~.j, 4 4434:4(34434 EG& ORTE G -1 175) WAN3 14WOR 96* :I 3 ::*4*** S U N M A R Y 0 17 11 U C L I D E 13 1: Iq (DF, fll"KK (:"*C)I:ýl:,,,Iýi:(:."Ilýiý'ý) HUC*1 1JAH: ACTIVITY ACTIVITY (TO U N T I N l~i pc';i /I f. f [J-1" 1: i. I... " E i ,"/ L ...FE-59 4_111 6F" RU 103'3 <Cs! 13 CB-r~13 4F BA14 <LA-14 <3E. 14 < 'CE 14 <i)~1..5824E+ 1.cc:. 7280E ' 00~.31 001 <E+0 2% 0646E+.11.328E0 4.4 .2E 0:1 EN3, 2797E 00 04 2557E+0(-'.- 3.4969E+00A2 A : 1.~ 890~: 3 E+0 5;** ::1.2.1 6.9989E+.00 5 f)2.0402E+01c~t A A1cti it 3k0. <. 11, A. t's.)~.i* 41, : ii~~~.......... ... ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ I. I ...... .......... .......... ..... .... ......1) 1 ii ,1 (_1 .Zi .....r.... .... ..... ....U S 51S 5 11 PI~13.5 X E1 44 14 FA ( F D 63 .9 1-31*~76.7 % NB9 1092 S FE-59A 1325 & f 6 61.t 6 &) CS' 13 79 .84 &U. 3 3 1.3,./' 5 .55 Rc 146.8. % K.40 60333 % Fabl W.3'Pea' is: par .5 ti of a1 mu ti le 4::'v thi area3;:1 ~negatives:: duin dcovoutoi.. Peak ..is too: w::d:: at:.': 4t: F:325M bu ok at* u,..H M EG&B ORTEC G V 1: ( 175) WAN32 14W02.96 26-OCT-2007.Jýi! ,.,IV i ýý*."I:)(-...,(:..-.t.....r-.k.ti-i-I n a m e :: 1 d c, ri !::CA F :~. ti o? V A e U .-I7 4 1 ~(/Y~1/V t C.****, ..ed.{7. 14-a10 7 1 N2 M A2 -', 3 i " '" .. .,J Ze : oiIffsetC I.k,.. I -f-a -ý,: i: ..105 kevg Gain.50 k ' cxh I x i ? : I I i (4i d Sto chne Pea reecio levelH Peakx\l x x::::. .c Sapl Size:::i R.:. I ::'fc-'1 an cxcx i f'* (.,'0, 1. F et) c 4048K~ 4f or o: 'xx x~ * :,f 2( IY124/..3GkeV~: L 30. ) x'50(..;jf I.OOOOE+06/3: I.'311.*MMOEB RISO method 1.0000000MOO Additional systematic ewNyrn 1.00000OOEfOO J-1.1i ýt.; t;Background widthv best methiodfor cion-,-,3 I I c 4 'x I I '-to ; 1 Ifdu I .I :IxI:f c*C i cxJx.ix::x Y. ME3.KIO Commen0i:: C3 ()r, I (. on -f% rm ci t J.]N F",air~:: 1 :.1 d suv.-- J. .1 ..j I p4 NO ~, :: ic:~ 7@ F 7 F.Energy cal~:i.bra ~t:i.on~ no rmn:. .aliz~ed c :i f feen e uv:a:. :11.6*3~~ 14 1: Da Ec 11 Ti I~. F" IE )F! : 1" -1 lýFI IENC:: UNCER 54] V1'Y *LISPECTE
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(., 0 ("'.) -.:,i ) .I V I TOMEc'1% >i 0 ,-U 1:21 ITI,-. a I.-I T :i,..i C( T I 1.D F1 1---I A 01 A -*ý:I tj W 41 Fl ý.i,5 F aMed TOWIT 400aMON-00 9600= WMMI (911: ) :I: -, Environmental, Inc.Midwest Laboratory ~ an Albohny TechnoogieO Co.700 Lzndwehr Road .Nodhbrnok. IL 60062-2310 ph. (847) 5064-0700 -fax (847) 504-4517 Mr. Al Percival FirstEnergy Corporation Mail Stop 1041 5501 North State Route 2 Oak Harbor, Ohio 43449 LABORATORY REPORT NO.: 8003-100-371 DATE: 11-06-07 SAMPLES RECEIVED: 10-19-07 PURCHASE ORDER NO.: Dear Mr. Percival Enclosed are results of the analyses for tritium and gamma-emitting isotopes in twenty-one ground water samples.Should you have any questions or other concerns, please do not hesitate to call.S.A. Coorlim, Quality Assurance LZý b t o y M ag e r SAMPLES RETAINED THIRTY DAYS AFTER ANALYSIS Report: 8003-100-371 Page 1 of 3 Table 1. Results of analyses for tritium and gamma-emitting isotopes in fourteen ground water samples.Sample Location MW-30D MW-37S MW-20S DBD-02 MW-33S Date Collected 10/9/2007 10/9/2007 10/9/2007 10/9/2007 10/5/2007 Time Collected 10:02 12:29 14:48 12:00 9:55 Lab Code TWW- 7166 TWW- 7167 TWW- 7168 TWW- 7169 TWW- 7170 Isotope Concentration (pCi/L)H-3 < 174 1231 +/- 130 189 +/- 94 218 +/- 95 1110 +/- 127 Mn-54 < 3.2 < 2.1 < 2.3 < 2.0 < 1.4 Fe-59 < 7.7 < 3.9 < 6.2 < 4.0 < 3.8 Co-58 < 3.4 < 1.8 < 3.0 < 1.9 < 2.1 Co-60 < 2.8 < 1.9 < 1.4 < 2.5 < 1.8 Zn-65 < 5.4 < 5.7 < 2.4 < 2.9 < 3.9 Zr-Nb-95 < 4.7 < 2.8 < 2.2 < 4.1 < 3.2 Cs-134 < 2.3 < 2.3 < 2.8 < 2.1 < 2.0 Cs-137 < 2.1 < 2.0 < 3.9 < 2.9 < 2.4 Ba-La-140 < 6.5 < 3.2 < 2.6 < 4.0 < 6.7 Sample Location MW-33S MW-33D MW-31S DBD-03 MW-20D Date Collected 10/5/2007 10/5/2007 10/5/2007 10/5/2007 10/10/2007 Time Collected 9:55 11:33 14:10 12:00 10:35 Lab Code TWW- 7171 TWW- 7172 TWW- 7173 TWW- 7174 TWW- 7175 Isotope Concentration (pCi/L)H-3 1230 + 130 1934 +/- 150 3149 + 178 3012 +/- 175 < 174 Mn-54 < 1.5 < 1.4 < 1.0 < 1.2 < 1.8 Fe-59 < 4.5 < 3.4 < 2.4 < 5.0 < 5.1 Co-58 < 2.7 < 1.2 < 1.7 < 1.6 < 2.1 Co-60 < 2.2 < 1.6 < 1.4 < 1.3 < 1.5 Zn-65 < 3.3 < 1.7 < 3.0 < 2.5 < 4.0 Zr-Nb-95 < 4.2 < 2.2 < 2.2 < 3.0 < 2.6 Cs-134 < 2.6 < 1.3 < 1.4 < 1.9 < 2.5 Cs-137 < 2.6 < 1.3 < 1.6 < 1.9 < 3.0 Ba-La-140 < 9.4 < 5.1 < 2.6 < 5.1 < 6.1 The error given is the probable counting error at the 95% confidence level.Less than (<), value is based on a 4.66 sigma counting error for the background sample. Report: 8003-100-371 Page 2 of 3 Table 1. Results of analyses for tritium and gamma-emitting isotopes in fourteen ground water samples.Sample Location MW-23S MW-1 5S MW-15D MW-1 2S MW-12D Date Collected 10/10/2007 10/10/2007 10/7/2007 10/4/2007 10/412007 Time Collected 12:50 14:12 16:52 10:48 13:38 Lab Code TWW- 7176 TWW- 7177 TWW- 7178 TWW- 7179 TWW- 7180 Isotope Concentration (pCi/L)H-3 306 +/- 99 301 +/- 99 442 +/- 104 276 + 98 738+/- 115 Mn-54 < 2.4 < 3.2 < 2.8 < 2.1 < 2.3 Fe-59 < 3.8 < 6.6 < 5.9 < 2.7 < 3.8 Co-58 < 1.6 < 3.2 < 3.5 < 1.8 < 1.0 Co-60 < 2.2 < 3.0 < 2.5 < 2.1 < 1.5 Zn-65 < 3.4 < 2.2 < 3.9 < 2.4 < 2.9 Zr-Nb-95 < 3.9 < 5.0 < 2.2 < 2.5 ..... < 3.3.Cs-134 < 2.3 < 2.6 < 2.7 < 2.0 < 1.9 Cs-137 < 2.9 < 3.5 < 2.6 < 2.5 < 2.0 Ba-La-140 < 5.1 < 7.6 < 7.8 < 6.2 < 5.4 Sample Location DBD-01 MW-31D MW-1 05A MW-30S MS01-MW-30S Date Collected 10/4/2007 10/8/2007 10/8/2007 10/8/2007 10/8/2007 Time Collected 12:00 9:47 12:41 15:25 15:25 Lab Code TWW- 7181 TWW- 7182 TWW- 7183 TWW- 7184 TWW- 7185 a Isotope Concentration (pCi/L)H-3 769 +/- 116 183 +/- 94 1832 +/- 147 494 +/- 106 26895 +/- 467 Mn-54 <1.1 < 3.3 < 4.8 < 4.0 < 2.7 Fe-59 < 3.9 < 8.6 < 5.9 < 5.7 < 5.4 Co-58 < 2.2 < 5.2 < 3.3 < 2.0 < 2.2 Co-60 < 1.4 < 5.3 < 3.8 < 1.8 < 2.8 Zn-65 < 2.1 < 7.1 < 5.0. < 1.9 < 4.3 Zr-Nb-95 < 2.3 < 5.1 < 4.0 < 4.1 < 4.1 Cs-134 < 1.4 < 4.2 < 1.8 < 3.8 < 3.4 Cs-137 < 2:0 < 3.8 < 5.0 < 2.8 109.1 +/- 9.7 Ba-La-140 < 2.8 < 12.7 < 14.4 < 4.9 < 3.6 a Known spike activ Cs-137, 98.4 pCi/L.H-3, 27,496 pCi/L.The error given is the probable counting error at the 95% confidence level.Less than (<), value is based on a 4.66 sigma counting error for the background sample.0 Report: 8003-100-371 Page 3 of 3 Table 1. Results of analyses for tritium and gamma-emitting isotopes in fourteen ground water samples.Sample Location MSDO1-MW-30S Date Collected 10/8/2007 Time Collected 12:00 Lab Code TWW- 7186 a Isotope Concentration (pCi/L)H-3 26895 +/- 467 Mn-54 < 3.7 Fe-59 < 2.5 Co-58 < 2.5 Co-60 < 3.0 Zn-65 < 5.1 Zr-Nb-95 < 1.9 Cs-i 34 < 2.9 Cs-i 37 108.4 +/- 8.6 Ba-La-1 40 < 2.2 The error given is the probable counting error at the 95% confidence level.Less than (<), value is based on a 4.66 sigma counting error for the background sample. -.. Environmental, Inc.Midwest Laboratory an Allegheny Terhnologies Co.PRG-33 Form LS-4 Ver. 10 0.10032g STD T-36 Counter iD: TRITIUM LSP-2000C,. LSP-2550TR1I/ AB Aj LSP-2800TR D o7 Iit. & Co=ttDate: 1 O /t BKG BKG Sample STD STD : STD Date Time Counts Time Time Counts Activity Issued ,)O0 5:f 00 c29 5-7905-_!003.78 01/18/2001 Sample ID Volume Sample Remarks (ml) Counts 277517 / C___ 5q\ C- 77O ___ __ _ _ _ _ -7_ _ _ __ _ _ _ _ _ _ __ i _ _ _ -, Environmental, Inc.Midwest Laboratory an Allegheny Technologies Co.PRG-33 Version No. 1.0 06/17/97 Programmed by Rick Lesko Sample Count Time (min.): Background Count Time (min.): Background Counts: S TRITIUM RESULTS SHEET For any sample counted on the LSP-2550TRI/AB, LSP-2000CA or LSP-2800TR Reviewed and Approved by:--Date approved: I 100 200 594 Standard Count Time (min.): Standard Counts: 200 57905 0.188 Date Counted: 10/21/2007 Calculated by: Rick Date Calculated: 10/22/2007 Counter Efficiency: Sample Coll. Vol. Sample Corr. pi/L 3.00 4.66 ID. Date (ml) Counts Factor A Error TPU. Sigma Sigma TWW- 6754 10/2/2007 13.0 425 0.997 236.752 +/- 88.589 94.259 95.628 148.541 TWW-6757 10/2/2007 13.0 322 0.997 46.241 + 80.240 80.487 95.628 148.541 TWW- 6758 10/2/2007 13.0 310 0.997 24.045 +/- 79.211 79.278 95.628 148.541 TWW-6759 9/25/2007 13.0 371 0.996 137.020 + 84.406 86.439 95.731 148.701 TWW-6765 10/1/2007 13.0 510 0.997 394.031 +/- 94.942 109.021 95.642 148.564 TWW- 6766 9/28/2007 13.0 425 0.996 236.898 +/- 88.644 94.317 95.686 148.633 TWW- 6767 9/28/2007 13.0 432 0.996 249.853 +/- 89.183 95.437 95.686 148.633 TWW- 6769 10/3/2007 13.0 420 0.997 227.469 +/- 88.189 93.457 95.613 148.519 TWW- 6770 10/3/2007 13.0 496 0.997 368.019 +/- 93.898 106.405 95.613 148.519 ci" =Best probable result. C-) V T. 1`1 T 4 w 9 CD 6 3, :1. cl -il f., -I.- -j'0 J.S to " t l. r -; Ji.:v~~~) e )I.-: Pfv :i 0 0 --ý E-'.' 0'1ý1 1 :1.19 -3 4 4 L :~' :: ~ (2 C-I: vjf.~ ;~.:3 1h,~ 2'2- Mar 1 0 2 I l'* A-' I I .4. arrr 1 c4 t:5.k P .-21. ED s J .n ..u4( .Plc l; i") .mis 1. J.2 I1-[5 c -f a r'I. 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4' t.58 7 ,.A , 0 S~ U m m~ A. R,: Y .C -3'. F.1 (2I U I C" .L@ .H ýTI1:1 F'W (:)I::' CO::: TIME CO RE TE ;i :owvc i::' UAi;ER:TAIN~Y A: I :'ll F 2 IG.-.33 ** 3' -:3. ..'l:.Ci. :i. Ei: :,/I. .i E : f f f -f f f f + f f f f --+ + +- -----3.......'+-43. .........3.3I33........ .... .........3 .... .... ........ .....CC C" (33 )N ' K? ..-31 (.33 -1 3 4 <CB-137 BA-140 LA-140 I.E-141 <3::EJ..14439: K 1. ;-"?IHk+ 'l 1.2707E+01p3 1!.-. -4 2;7: F: 4-:0 :1*..'5. 0315E+0031 1.1..203'130E+01: .:..98311. E+0 (1:1.H". U .Ir 1 II 3....0 D~lý: CIA1 Y :1:Y'9:, ACc:'IT ;9:tl3h 202"i: Y1 , &:'1. 3I@ @9I: :[TER.:3/I..: I1.3 111 111 333, LA-140 49.0 X3~ R Ii jj 62 .8 &33 RU-0I I 756.2 & R-0 S34.04X AN35 1216 ' & FE-59I 1 .45. 44 & 3.E-41 36 .4 %~'3 1-3 63 .9 % 1-131:1332.50 %' CO 60 Fý. 1) hi: 1 F, F R8 .3 % 3-1 'K ý. J(. ýI*). -j(- -XI .*.3.)*4*8 ..1 (.'i 2 'x, L.A: 1 .43;Colo 33, X, I U1 4.3 ,,v(3*33 81.7 A CO5 faile on '.33 (.33 qI1 u 3 it3,- .C. t;J )- L S v 0 :, U C Iiý II. .i.i C-3 V T: WAN3 14 O2 9 13-OCT:1.0 C.:"'T~ 200',"ii 11 :; .49~ (111%3N~0~'Stat t ..ime~Fcc~ .o Lvtime 7 .NCB I Input :1.Calibatio VJJ.t F. ..:i c 1. i'.? 0"',` k nc: t 2i~i I ti~l I I ~ Ii ~l'-Ctf~~ 2.Anlyi parameters Sto channe 4048for 0501 keU/MannXI., :1, :. I: (:if "'5 :1. '.3 1.!. e V 2026,, 3. 5 0 aG/ C I 2. 8571E+05 Ad ito a sysem t It'..' 1.00I~O Fr.Iiacti on ii~'I I t :l: Ft Sa:' 1..0rSi;:r:I0 1C3SS..eF Backroun widt betmho o, f7 a~ df u~ rs J. n quiJ:J Pekdbakrun -reto Y '.is.t: 1 5 EG&G ORTEC 0 V I ( 175) 4MI13E 141002.96 13-OCT 2007 r u I'll 1 .4-L I-,, :; :1.*,ý";."O (.ý'.!ý.f."I)-,:Iý 2 Energ c al 1ib~rat o no: 1.~ r mai zed.:.:~@ic c;iync:c fi3.0 (") .109: y~~~~ Ny 1:~ D E~ 14 T 1 17i 1r~2 E: 0 Pi E .Ai Ki 3 U: 41 PI A ~ R ~ Y ii ;iViii IT. FR.: ci..i BIKO N NET COREAQ 3 w*FFICIENC .r irY~k k r~u 706.18 351.*783 1,08.85.215.15. 1. 0 E-,0 4:1.6.32. ; 1.L"MM PB-R14 1. (.,24 TL-208 2,, Y-.']: 2 14 a a -f c o t; (....',d I D F: FIEW CENTROID F: I E: :f)P : A: , NE II .1Ii U M 1*11 A R y X., -X I'.,(- K.X. )(. M.INTENSITY MICERT RMI CE-14 CE-141 BA1.;:?LA14.:i.3 1-.l* :1-. 4`LA140 Z :1,1 S1. -11 'J tHr .1i .1,,'!'`1 ..CO s Pak D i ( 0 608 0 If 1.1 1. .1 0 4,I.! Q) 0 151 3. 50.1 .'A. i 6'" C:1 C,6 .143. 91.1 I9. 3(,-'j 53& 2'C.? 0 3Ca 2i t ,3 I i'i W-8i..,. 0)833.8 38 511.24..2 .*14 P4.2):1.4 Ci?(i" ( 00 (I 2 (IDL'.7.102.0 3 I~I U) Fl.A.i~i I *.I.:11 31).ii III I Ii I'fill c ~ c: If ~::I I. *I:; I' ci S EG&. OR:: B Vn -- I (3 175) W::.' 1410c:3:'.n2 .96 10 3 page ~~["IF N'3; :: :y:'.J. 1 F
- Ur 1'~~ 1::~3: :: 1)D EE333 3h : 1T : SI"!F .E 4.3...................~3......3.........I I.......................3.4.4.~.3.3.
3 .*. 444.B3 ' A;3 K-403 33 ,, ZR-95 i 333W'4:.34 BA-14 LA-14P CE- 141.:.; 11 3ý) .. 43 '1, 33[.3'. 43'38E+00.3 0 :I. 3E+0i):3. 0113[E+013 4..3.0560E+0 5094+0:1",7 I~ j E-3*. .2. 44(.33 3133 ON 5420E+3(3p3 (;j.734. (-?) Q)..0',789EM.< p i ---, (:I .3 A; Ac iv t prited I3..3 < 33 r' O'3 in.. r ~ ~ 1:,.. y:~ .3:F (:, F, D~ :I: ;,H; 2.1 F.. , :3 ) 3. ý 1) .3, Ii A>, 11"3333f3: .3.~ S d: 3...4.4 133 .~.54.1 4 % 3 CE 14s3 .33: :; : 3 14 .4 &: CE 14 28:: 3 &: 1-13:'3. 3 0 ~ 4 P4.8 4 3 & B 14 0 3287 % 3 LA14 364.48' % 3 1-131 477.61 &... BE-7 48MORI:3 %H LA'3 140 Al ' e"i 11i' 0 R'L' 1~ 537.3 S S 4 61 .3 RU I~3 1.*.- -. 21. ~ i:"4 63,9. %4 1-3::.33...3 % ( Ca 3'33 724.13 % 3:Zl!-9531: 36 7P4 Z' R3 -333 76 .7 % NB-93 795,8 % C 134 8 .7 % O588-3 4 .8, -1 y 1-1 4:1 IE 91 1 .5 % ZN 6 113.R %~~' C::::-611 I 1 .6 1332.50 CO-6 146 ,8 % K34 15 6 1 % LA-140 A '; :::3j3 ' ' 'F. a.d ,,.' id n i e , bu fist pe k f i 3 ~ ~~~ k, ,, J. y. !-- J. q 13 .1 L .1: ;3. I:':4n J. r: a 3 4 :: .:.33I oil EBRO ORTEC G V -- 11 ( 1705) WCM13E 14WOR. 96 :1.,*i."!,ý!.'.*.iý*.*-.-".,.ý:iý;.,ý',' IDi Environmental Inc Ard.Specrum ilenmei;C:\Qer\1702.n:. i0 Start3 time :1.Real ti.me Dead c time. ic'c 13': v'>:1.1.Cal i :3 " I:: i. 3 Cre ted 14.-R 0 IMMx &Is 2(.-' -.II .-: r: --2('.0 ci~ Offset.:: (".3 .1.LibraryFile~i I i l f 1-.r lei Pea reeto ee Peak ~ ~ ' searc :en i.iit SapeSie.2 I. 1i 1: 120foran nery~o 58131:':kek '14 fo'r an en3ergI~y Wl 2026:'.061,M)'3~.? .'3'.Detectio li i m *'ii I. !-.Iui o:" d. S&I(VWI'.'I RI S method'Li~~' "c 'c 1 2j13F' ' s Additioa sytmai error I ,, 00EM Fract ion 1 3 it: .000i';I 33.:l::3ccl c :sc;x D 'cayV c 3l 1 i s qui. xsi oI' t c:,'Y E .i `31:'YESI cx 3 'I.: f.:~~~..3'3,::: 'I::.2VI~3'?
- i. 3 2132~s [~J3~3 bk g I w. p bc:
Randat" summing g EGR. ORTE CA -Qo --1 I ( 175 WA3 14:-: 96 MOT00 10125R:12 .73 .2 Ene*:'~rgy: ca i r t o normal P 1k i zed 001 ::: ; j-45 :~34-41. ~4 --*~1 U4- ~ --i i 4 4 4-1i4 3 3 3 4:D E 1 T IF E 14sE4)K4U 7 '.* I 479.17!.5-6 , i ! .ý7.7.7 70.42 9 28 1 .j',9 9.21:4.1. 1 8 4 11 9 6 608.9 i21'.5 2I.-,1 1,5'7,, 81:1.*--,4 135 I I B..94.1. 'V8 E f..':1. 1. 585E+04 4. 444E+04-8 1.. 9 ;.12.3............................... .......14.32 I. (--3`1.847:496 R. 01j4 FPB-'14 EAT 152 AC-22 18 X)X)I.)I)s2: ;:i:n, 31-:-. U 3 (.*. ' L : *1) L -3:- I:41-4 CENTRO:) -- I- i F- 1k :: ATILT!.1-3 I: .iJ 1. (.) .R.1 RU- 10 CB-137 R[' '270.53 I 293. QM4")5. 93 1 i'.' ? 2' i.:1 2 2 144.80 364.92 476 4-'i 48. U'..:-5 3 6. M.62 27.,..1")8.3 21.1 1 / II ý 14 8 :,Ii 1. 4-' ,j I ~ ~ 8 111 i9'I 1~' -0 1,.13 1.- 4. ' -- .--.005 14.60- 570i ,ii!0' 4 I ,%-YJ4;:iI84F.J D41 (4 I.005I:I 112 8 , I.61 ri~ ~ I~. :i 175 WAM ni fl4:AlWiO t 2'.;~ 96A 13-OUP ic 77~3. i Nucl~~i fe.FIF 51.Chane Enerp Ba~ckgTC round Net~2 are 2:199 :1 ) 1. 0 .2Q IJ 6 2658.6 13995M 01.0:1. :4 9 0 " 31---,9 5 282., 8 I:: I*U~l f~ )..1.1.~ ii~ (~I~3. ~ ~m ~U 7 7 , Y 0 F:, .['l U :... I 1 ) F I H.)(. N. .I(- K )(-pCiiLITER p:i/ ITE.IF FA "I <' 4. P5 0 4.944+0.Ki i- 4~iI CD .i85 E *3 1.5 4E 0 1. 2i8'ii$).*-. VH-54~~ ~ ~ ~ < .74I00 40W FE5 7 '.3469E:+00I 8.04E0 EM-58 < 8523E+00 A" 2858M C O -6 0 < (.*.'1.'... 13 .H5,1*1,$3... %i ~ :1P.I.1473E+01 1.18 33E 01. f,,:;rY I*. $n fA .3___ I.4:v..9.4359 E 0 I. .05 1 EI4 +0 ' 1.~'V ~ *~~ZF ~iI V:</( 484E0 z" 36E 00 6~ ..I EG:*&G (JFT:CFW(4)3--*I ( 171~5) WAN3'*l~r2 14 W 0 2, 9 , :1*'1 1291.60 X FE5 325' C 1'; -Peak ~@ -Pea is too wid at IW5M but (to M I$ -I Pea idnie, bu fis pea cY thi IVA Iil. 1 file on or mor quaifia ion tests,,:r
- + -Pea acivt hihe than coutn u -I-- c. -f- Y ~~.-Pea acivt lowe tha contn uncertainty ran analys0 1 1:. (c:: Ci t: 7' (A: riI --,a111 .:1. C' (." TWIJtA.~!.7~
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- e'z L.Ij ::1 .3ý3 \U & ;\ ' 431 svý ()-l 10 A' C I UJ.s J. 1'..'J i Y): j f3 LC)i Y`3.1 k 1a Str time::12-TWC c:;2K-R0 CI? :14 3::.77:15 1:3 c~ 1: c*~ c I:; c:Y c:; ~:; C c*~ in FJ. T~~ ).-[-A 3 V 4 Ie Zero offset -1.980 kev; Gain Quadratic
- 1. L'.!.01iý:
.501 ket)/Marn-w]. I hPea reecio lee Peak J.3:I:lv;i:; 1 3 I'~r Samlevv lL s iz:;:I J1.c133 Activity s.1i(5 1 caing facto.R :. 1 i :1.20 for of 4t1. CI 2 ( 1. (I. l...,c -.4I ' :ý3i:c 4 -i).30.000%A d d J, J. 0 Y~ I a I :1. >31 0cc r -(.3 D0 E .7 1 J. I 3II @ IJ.i Bakron 311 1111 c bes: :c~ct; 33(5iJ-iCt I).hc;'c Dea wiqaqusto Y E N(.'I lii *.I..c:~133 33355) 1',AI 1k. U111 :, kAH13113 .1, 1 1.H I U.P Enrg cal~+ ib i :ra tionv normal izedi ci .f feremng :1.0000* (** f* .f *:** U N 1:i~:r :i) E 7 N T 1 i F I E, D~ P3 Iii (" K3~(.3~f S,33 U( IyI .f A PEAK ................................................ ICIENCY...............ECTE COUIITSý ff')RA 2 IGMA ko)::LG ID 0105 ~i*. 80 'i .3515 6.3E0 57 8 Sh CM P i.i.t214cic R13..3 2*. : 3. .T..13 09:2.3..3.. 11 4iu : '. :i 9.'~ r 1.0 0E 0 3 5I 1- -4 BIYI1 f:3 i (1 3:3 3333~( f..i.*(3 3.:3 )3 NW. ~E::FY3<cr~ uo ~ x~c~ :ou1 areaii::3
- 1 i 13 iCRT iiIi~I fD Ei Ni Ti I V'; I Ei 1) ID I :fI3: K. U~~ '\1 I'(" 3111: A Et3i 1A01 3~r T B AC G O N NE ARE .A 11 T E 3-- S1.( 'V j 1,1I'ý1" , I:1HT I ~ ~ ~ ~ ~ ~ ~ ~ ~ I31 % iIP':.~.h"I i '.)3 CE 14 271.6 13 .1' 18 .:1.I 0 001 4 1- 131 5 7 I 2. '33' 1 (i.,,,-BA 14i14 3 3330 .61 5 5 9 :1.~ (?) 6-I~f ". 37.*: " ~ ."f'VIJ 'A B l**.-.-/ :1 0 6 , 11 RU-1033 1122 12 110 3 3.6 4- 8 *1,:1.84 1 1:.. .3 1 CI .2 3 33 (71 003t 1314 8.C -34; 4 13' -3 .I'31i 3* :: p ~ N 9.3. .33-.3 :1.. 4'.
oil EMS ORTEC 0 V -I ( 175) WAN3R 14W@2.96 12-OCT-RO07 104105 Page Environmental We S U F 1 1 %I (ll i::OF COUN{Th T1. 1iti c.::r ;: : n;:' I.I. ::;,)" : *..**:..-.. -.-.. -. ....-...-..... -.-. -.-.. -... ... ..-- ...---.-..-..... 4-.. .. ..... ....... .... ........ ...11111 1 .I..I z 1 ." CS-13 C l , :. 3 Cili :. 6 S. 326E0 2.:1 2.: Q 68E01 XMM1-4. 91 t f@1 r~rni.. ~ i i: ~ j' * .:. ' ?c 2(.', :1. I..~V4 0.. 0 1-fER .. 4 I TOTAL DECAYED ACTIVIT 3'.). ( 1 to 2026. :1 kV)+ : 0. 10000 OlE /I0 I TF:1.133.5Iif444 1 497.0 62 .8 %/lI 756.7 If, 830 .1 129.60 S (1 .I'I A 1 6'I .f.",~ ~ ~ ~ F-.y 01 4. /. 8 I131 284.3 % 1-3:1 477 .(..,1 1-7 604 .70 % CS13 1061.66 795.84 1.1113.55 4 JA64.81 he 8 ~ , (jý " I' .1 610.3 % RU I WI I J.dentiied, ut~ firs pea W M EvM OR. E GD V I; (. 175)i WN P 14O29 06OC-R0 W49:3 Page 7 ~1@0*IA 6, 5 ' i,5,, 1- 1 1:: nV: Acquisition informatio-n Start time Live time Real time Dead time 06Ot20 1140..1:135 113T."%MDI Inpu .4I~Calbra ion I t'Zevoxd ...1 ofse .-.13 ke/ G a in U 1.500 keV/channe:l. Ac ivt scaing fato RI. Ii.l'in.-fC allP&'i :'*~iin : ~30 00OX7:1.i' I J. I. '..c i' 4n~r~ I. , Ba k ro n width bes method :r~~1: 4i14':I Kln..n~C'~Ir Correction,.;-, correct YE-i 3..0M: Me 't /0 PI 1-.) s o f.. o -[--I tý..- -f.. I-, a l.... ..... .
- i E r v 6 O R E G V Ii (. 1 7 5 W A N 3 R 1 4 O R 9 0 6 O T 2 0 1 0 4 9 : 3 P a pe:~ i 4 7 ~ i (~2:: En rg cal. ibra ~t1: io ~n vmc Cfli zedI i :cx ic .ff ~~st~c:i. ,, .0 U~ Ni 1: D E:1 T:cF E 1) P .E u1 Ki S U 1I 1 A R Y PEAK lC~lEN (:3 3.: BA:CK.~GI;ROUND~s3 NET AREAf '.Eir FFI:i::C iN:*.-`C UNCA'~l::ii:-
F I:hj.-~ IN 3I:~cl 476.68 676.59;703.67 12B 58 1589~4.3 1351.8 609.31 376.217.186.S&23.6I*~ 5 ~ Iý 1- ii:,0 45.4~37.:~ 913;1. :q'.3~ 4 1- B1 2: *~~1.4 f- C(--2.I)11pa fail shap tests., I D E N T I F I E D P E A 1-1 NUCA-1 DE PEAK CENTROID BACKGROUND NET AREA FJ-,IIH:R.GY (:."OUNTS 13 ii 11 VI ("I R Y .. s sisi s*s s.5 4 4 4 5 5 5 5 5 5 4 4 5 OE 14 CE-I 14 RU 10 (:1 1: fi : ..1 I 1 31 CS-137 5IS-134 C;0 L. A, 1.(1) 1fý(-' 1 1 (1-)I' :1.220.62 1245.0: 1. '- , ,.*~1321.4 2347 *I.13 25 f. ý 11 8V".2 92 60i 135.146.41 49. M.)£" -3*" , " -3 .26'.117.6 11 -4 ,I' 1 132.44, I (3-1111:19.III, 4,, 0 0f Will '.0 ?)(.7 (ý'Cd 4 1 1. '16R. 19:1~*, 5 2. 8:1. 0,'3&ý'01. 0' 0 MY.%1'J 0 0 517ki3 lii:C`j(&G OR-Hýý:C*1, C.3 V -I ( 175) WON3R 14WO2.96 W6-0C'T--2(.7j(?)7 IDage E -,-I v J. re. -.-I I .-I I I -I ý.*Z" I' I L.- :1, 1 1.1c !'.3 p c I.; -C, u 1-1-1 1*1,:1.f)-1**,ý
- 4*,7!.,..,.;68 " (41.) 1-0.1 --), iiO ape*:~: ~ 13 tJ j I 1* A) R. Y .: 0 F Al J C.: L.: )I D v. E S N 13 A V! P L E.2 SI('311()pCiiLITER pCi/LITER.S I.4.4.S.A.4.............I.4
'S C "I ) 5 CM-60 'FU 106 SC) :...40 CE141(~CE144<) .3 9187E+01 it 5.9943E+02< (f< ~ ~ I4 Q' .30 ifr J,< !...,; 6 0 (.*l If I.-< ? !'.'5 9 97 -1 I<~~ :1,0440E+01 <~ ~ 2.52B(<i<'l 6.0710< 11"76211+0 < ~ *3~. ~F 2 .3S Fý .", 0< 4.634+0 1.24E0 45:.2815E+01fJ a 7 ,*3 irý+-,)(ýj 5 ' 6:1. 4 *1Ii '1.90EW& 725E0 Q~~~; 4447E+00I& 99E+.1 4,. (?t 3I. 1 I. (66f+0 it All peaks for activity had Activity omitted from total omitted from total arld all A Activity printed, but <....... .... .I ................. ........ .... ........ .............. ....... ......... .... ........ FZ Y .... .... .... I~ ~ .............. ................... ................ ....... ................ ...3 ITI TOTAL CICT14JITY 59.9 to 2024. 1 keV) !.`.-5.TC)TrA. DECAYED ACTIUITY ( 59. 9 to 2024. 1 keV) 5.********* ýý'; L) 1*11 I'll () V11. `( C) 1:7 1) 1 ýH*; C: (1 R 1) IH: D V, li:: A 1133.054 of CE-144 145.44 & CE-141 284.30 R 1 1,31.328.76 % LA-140 364.48 % 1-13:1. 477.61 R BE-7 497.08 & WOW 537.32 % BA-140 604.70 % CS-134 621.84 % RU-106 636.97 % 1-131 6161.66 & C "I f.. ý) :1. '3-,'ý756.7p & ZR-95 765.79 X NB-95 795.84 9 Cfýý*.,--l '.ýi5,1 834.84 % MN-54 1099.25 % FE-59 1115.55 & ZN (.*,5 1291-60 % FE-59 1332.50 & CG (""10 1.5,ý.';?6. 18 1 (.4 :1. z:,, Q)! -Peak is part of a multiplet wwl this area went.: '1 4/ IX B(4 :. 4 (1 a', .*4. 11 4 C;C.. CVj E cuI 0 "H:~rEC:: V3 T, ( 1.75) WA 3 1:.'~4fZIO:.
- 96. 1. 1-OCl T J h :1. f<:('.*7:
.44 E I V .f, C) .1.fl C. 1- t '.. Z.-O.5p c:U I -1. i: .,I) ~ (~@1:1.ý1.. :;: il*. 13C F IA n : .1D. ... m :: \. i;e '\.1 (1 (0 IO.f.. (t:,I)-) m I. 3 ~ ~7 1 .:.Start C :: F C ( ti e ':i l:r *':: (:"1 MCB I Input '3 f.2reated.:ec .1L. i3 141. 4RO 31. .1. & 1.4 'w. @17 .4 53 4 ITICJ H2433 IC:lW i 1 Zer offse F:W ke, G1 I VF 3ai:.n Quad.rat1; ic.....2F(7I:e ha 1. ne.V "2.500 keWchannel I 1. i 11CC.1.2C-for' ;f) a n e': o~ff ,Ti3o*, I ~ ~ ~ ~ 44 fo' no- (eeg M;i P024.r09ke. V j ~iCK Pea reeto lwe 000 Peak searc Sapl S ~ize:;C~~I:~
- 3. 5@fCf:: : I)ActS.iv.
ity ::. .h sca ing.:l factorCi; m ~ ::'I.O O E 1 '3 aeci f) 4 .) V.,::.I..corretio.Peake backround coreto Statulii.YE,:G, Y E NO pb(::- R,-Wid CA-11 "HJAIM-1-1 J. n 0 EGRG O F:RTEC 0:-I: ( .175 WAN32~~:r 14W '.:9 :1- t .r ... 1?007 Energy calibration normalized difference:: 3,33344333U N4~4~ 1: .l) E4 Al T 1 F'. I Ei ))EFFICIENCY .2 ,xI I (;-v-'*V Y 34 *:444:34:3
- 1217. 70 2.38,:.13 p294.7 6.4(St .. 4'.762E+03
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"'J J.IJ I~~ ~ C0.~:.~C 1115 55 4 C10 I 0 a7 J44 3 .l::I I-. ci w :* J. d : a F 4C; , 1 b ..3: (3..I; I:FIAJ I- -I Y .......... .......":'.-...-..Envirbnmental, Inc.Midwest Laboratory an Allegneny Technoiogies Co.PRC-33 Form LS-4 Va-. 10 ThJTRLN4 Counter ID.LSP-2000C-A 1 LSP-2-350TRI/AB _LSP-2800TR !nit. & Count Date: P i (' / i / < /C 7 0.10032g STD T-36 BKG BKG Sample STD STD STD Date Time Counts Time Time Counts ActivitP Issued POg1 0 0 0o75? 1002.78 010/18/2001 Sample ED Volume Sample Remarks (ml) Counts C -756G- G s 7___ _. _ _ _, 67 6.... 61-0 CD0 I _C7v f -I j 71]9 TZ 6 Y- o7C~ ___ ______ __________________________________ ' _________________ _________ -___- _____T1 2 _ _ _ __. ./q~ Environmental, Inc.Midwest Laboratory an Allegheny Technologies Co.PRG-33 Version No. 1.0 06/17/97 Programmed by Rick Lesko Sample Count Time (min.): Background Count Time (min.): Background Counts: TRITIUM RESULTS SHEET For any sample counted on the LSP-2550TRI/AB, LSP-2000CA or LSP-2800TR Reviewed and Approved by t A Date approved: I , I Y I 100 200 1081 Standard Count Time (mmn.): Standard Counts: 200 60733 0.195 Date Counted: 10/19/2007 Calculated by: Rick Date Calculated: 10/22/2007 Counter Efficiency: Sample Coll. Vol. Sample Corr. pA i/L 3.00 4.66 ID. Date (ml) Counts Factor Activity Error TP.U. Sigma Sigma TWW-6760 9/25/2007 13.0 543 0.996 4.447 +/- 101.463 101.464 124.075 192.729 TWW-6761 9/25/2007 13.0 734 0.996 344.227 112.750 122.082 124.075 192.729 TWW-6762 9/25/2007 13.0 758 0.996 386.922 114.089 125.639 124.075 192.729 TWW-6763 10/1/2007 13.0 819 0.997 494.981 -117.316 135.258 123.960 192.552 TWW-6764 10/1/2007 13.0 744 0.997 361.683 +/- 113.205 123.430 123.960 192.552 TWW-6768 9/28/2007 13.0 494 0.997 -82.683 +/- 98.313 98.954 124.017 192.640__ =Best probable result. -..Environmental, Inc.Midwest Laboratory an Allegheny Technologies Co.PRG-33 Version No. 1.0 06/17/97 Programmed by Rick Lesko Sample Count Time (rmin.): Background Count Time (min.): Background Counts: TRITIUM RESULTS SHEET For any sample counted on the LSP-2550TRI/AB, LSP-2000CA or LSP-2800TR Date approved: 100 200 1081 Standard Count Time (min.): Standard Counts: 200 60733 0.195 Date Counted: 10/18/2007 Calculated by: Rick Date Calculated: 10/22/2007 Counter Efficiency: pCi/L Sample Coll. Vol. Sample Corr. c + TU. 3.00 4.66 ID. Date (ml) Counts Factor Actvity Error Sigma Sigma TWW- 6835 TWW- 6836 TWW- 6837 TWW- 6749 TWW- 6750 TWW- 6751 TWW- 6755 TWW- 6756 10/5/2007 10/5/2007 10/5/2007 9/27/2007 9/27/2007 9/24/2007 10/2/2007 10/2/2007 13.0 13.0 13.0 13.0 13.0 13.0 13.0 13.0 483 441 535 762 569 588 657 569 0.998 0.998 0.998 0.997 0.997 0.996 0.998 0.998-102.133 +/- 97.498-176.734 +/- 94.741-9.769 +/- 100.807 393.916 +/- 114.275 50.685 +/- 103.040 84.513 +/- 104.248 207.025 +/- 108.224 50.646 +/- 102.961 98.483 97.742 100.816 126.210 103.270 104.880 111.827 103.191 123.884 123.884 123.884 124.036 124.036 124.094 123.941 123.941 192.433 t" 192.433 c3 192.433 192.670 192.670 192.759 192.522192.522=Blest probable result. Environmental, inc.Mildwest Laboratory an Aileaheny Technolopies Co.PRC-33]Form S Ver. 10 TRITU7-Nm LýSP-29000C0A"ýZ LS?50OflIIABJ LSPI-28007R COUf~J~ri~it. & CounttDate: Z C- I I /I ,!-/ 07 0.10032- STDI T-36 -Environmental, Inc.Midwest Laboratory an Allegheny Technologies Co.PRG-33 Version No. 1.0 06/17/97 Programmed by Rick Lesko TRITIUM RESULTS SHEET For any sample counted on the LSP-2550TRI/AB, LSP-2000CA or LSP-2800TR Reviewed and Anoroved bv: Sample Count Time (min.): Background Count Time (min.): Background Counts: 100 300 1146 Standard Count Time (ruin.): Standard Counts: 100 Date aooroved: -Date Counted: Calculated by: Date Calculated: 28457 0.185 11/5/2007 11/6/2007 Counter Efficiency: pCi/L Sample Coll. Vol. Sample Corr. Activity Error T.P.U. 3.00 4.66 ID. Date (ml Counts Factor Sigma Si m TWW-6761 9/25/2007 13.0 632 0.994 472.475 +/- 104.156 122.382 110.813 172.130 TWW- 6762 9/25/2007 13.0 610 0.994 430.898 +/- 102.636 118.188 110.813 172.130 TWW-6763 10/1/2007 13.0 839 0.995 862.889 +/- 117.390 165.988 110.711 171.971 TWW-6764 10/1/2007 13.0 598 0.995 407.842 +/- 101.704 115.846 110.711 171.971 TWW-6836 10/5/2007 13.0 330 0.995 -98.124 +/- 80.708 81.804 110.643 171.866 TWW-6749 9/27/2007 13.0 582 0.994 377.864 +/- 100.638 112.999 110.779 172.077 TWW-6755 10/2/2007 13.0 460 0.995 147.254 +/- 91.505 93.671 110.694 171.945=BCst probable result.S.Q ERM has over 100 offices Across the following countries worldwide*Argentina Australia Azerbaijan Belgium Brazil Canada Chile China France Germany Hong Kong Hungary India Indonesia Ireland Italy Japan Kazakhstan Korea Malaysia Mexico The Netherlands Peru Poland Portugal Puerto Rico Russia Singapore South Africa Spain Sweden Taiwan Thailand UK US Vietnam Venezuela ERM's Boston Office 399 Boylston Street, 61h Floor Boston, MA 02116 (617) 646-7800 (617) 267-6447 (fax)ERM ERM consulting services worldwide www.erm.com "S Oavis-Besse Nuclear Power Slalion FirstEner5501 Noh Stae Rout 2 Oak Harbor, Ohio 43449.9760 September 18, 1998 State Fire Marshall Office Mr. Charles Zepp 6606 Tussing Road Reynoldsburg, Ohio 43065-9009
Dear Mr. Zepp,
Subject:
Underground Storage Tank Overfill Release Report; Incident Number 6281145-00 The attached 'Twenty-Day' report is submitted to the Ohio State Fire Marshall's Office in accordance with Code of Federal Regulations (CFR) Title 40, Subchapter I, Part 280, Subpart F-Release Response and Corrective Actions for Underground Storage Tank (UST) Systems Containing Petroleum or Hazardous Substances, Section 280.62, paragraph (b).The report is submitted in response to an August 21, 1998 notification provided to the State Fire Marshall's Office of an overfill release of ajproxrimately, 50 gallons of diesel fuel from a registered UST at the Davis-Besse Nuclear Power Station. The UST is unique in that the tank is actually an above ground tank, however, it is registered as a UST because the tank is totally enclosed in an earthen bunker for missile shielding protection. The UST is part of an emergency generator system at a nuclear power generation facility regulated by the Nuclear Regulatory Commission under 10 CFR Part 50.The written report is the twenty-day follow-up report required after a release confirmation from a UST in accordance with 40 CFR 280.60 (b). The initial response and reporting requirement in accordance with 40 CFR Part 280 was confirmed by the Duty Officer(s) of the Ohio State Fire Marshall's office upon the verbal release notification. The report is included as Attachment 1, Twenty-Day Written Release Notification. Additional correspondence from your office dated September 1, 1998, was received by the Davis-Besse Nuclear Power Station on September 9, 1998. The release response cited in the September 1, 1998 correspondence was for a %suspected release', as defined in accordance with OAC 1301:7-9-13(B)(3), however, the release was a confirmed 'release' under actions of petroleum product transfer specifically defined in OAC 1301:7-9-13(B)(2)(b). Furthermore, the release was from an emergency generator system at a nuclear power generation facility regulated by the Nuclear Regulatory Commission under 10 CFR 50. Due to the nature of the release and the tank system, the Davis-Besse Nuclear Power Station does not agree to perform the activities referenced in OAC 1301:7-9-13 (D) and (E). However, excavated soil from the UST upon remnediation or closure will be managed as S Page 2 petroleum contaminated soil (PCS) unless laboratory analysis indicates otherwise, and a "Soil Disposal/Treatment Notification Form" will be provided to your office for PCS disposal activities. Reference Attachment 2, Response to September 1, 1998 Correspondence, for information addressing the supplemental request for actions.The only remaining documents required in this matter are the twenty-day letter included as Attachment I, and an agreement to provide the proper documentation to your office upon PCS disposal activities. Per your request on September 15, 1998, a photograph of the tank bunker is enclosed-Should you be in need of any further information, please contact Mr. Greg W. Gillespie, Superintendent-Chemistry at (419) 321-7268.Sincerely yours, C mes H. Lash Plant Manager Davis-Besse Nuclear Power Station KNM/bkk Attacmunents cc: Lowell Johannsen, Carroll Township Fire Department D. F. Petersen, Ottawa County Local Emergency Planning Committee ATTACHMENT 1 TWENTY-DAY WRITTEN RELEASE NOTIFICATION This report is submitted to the Ohio State Fire Marshall's Office in accordance with 40 CFR, Part 280-Technical Standards and Corrective Action Requirements for Owners and Operators of Underground Storage Tanks (UST), Subpart F-Release Response and Corrective Actions for UST Systems Containing Petroleum or Hazardous Substances. The written report is the twenty-day follow-up report required after a release confirmation from a UST in accordance with 40 CFR 280.62(b). The initial response and reporting requirement in accordance with 40 CFR Part 280 was confirmed by the Duty Officer(s) of the Ohio State Fire Marshall's office upon the verbal release notification of an overfill spill of approximately fifty gallons of diesel fuel.The notification was provided to the State Fire Marshall's Office on August 21, 1998, in response to an overfill spill from a registered UST at the Davis-Besse Nuclear Power Station, Oak Harbor, Ohio.This tank is part of an emergency generator system at a nuclear power generation facility regulated by the Nuclear Regulatory Commission under 10 CFR 50. Typically, USTs are underground storage tanks, however, this particular tank is a forty thousand gallon aboveground tank which is registered with the Bureau of Underground Storage Tank Regulators because it is completely enclosed in an above ground earthen bunker. The earthen bunker is for missile shielding protection requirements of the emergency generator system.The release was an overfill as defined in accordance with OAC rule 1301:7-9-13(B)(2)(b). Although the release was not into any nearby surface water nor released into the environment, the notification was made in accordance with Ohio Administrative Code (OAC) 1301:7-9-13(C) because the release was greater than twenty-five gallons and due to the nature of the security and integrity requirements of the tank and earthen bunker, removal and clean up of the soil in the spill area would not occur within twenty-four hours.In accordance with requirements of the twenty-day report, the following initial response actions were performed in accordance with requirements of Part 280.61, paragraph (a), (b), and (c), respectively: (I) The release notification was provided to the implementing agency (State Fire Marshall Office and Local Fire Department) within twenty-four hours of the release confirmation. (2) The release originated from an inadvertent overfill spill occurring during transfer of fuel into the tank during performance of a High Level Alarm calibration activity. Once the overfill condition was identified/the pumping of fuel into the tank was immediately terminated. The overfill resulted in fuel spillage from a vent pipe into an overfill drum stationed under the vent pipe, and on the top of the tank bunker. The spill area was contained to the stone overlay and earthen bunker on the top and a small portion of one side of the bunker. Site emergency procedures for spills were immediately activated. The spill area was immediately investigated for spill assessment and extent of release. Visual inspections verified the release was a sole result of the overfill and no further release threat to the environment existed from the tank. No evidence of runoff to any other ground or water system was identified during the initial visual inspections and assessments. S (3) The overfill product drum was appropriately closed and the work was terminated. No runoff to any other ground, groundwater or storm water system was evident, and no other free product, fire explosion, or vapor hazard was present.The following initial abatement measures and site checks were performed in accordance with Part 280.62 (a): (1) The initial assessment and incident initiator of manual overfill verified that product removal from the UST was not a requirement necessary to prevent further release to the environment. Additionally, periodic tank integrity testing has verified tank tightness. No other threat of release was probable or identified. (2) The type of soil surrounding the tank back-fill is clay substrate prohibiting the threat of migration into the ground or ground water. Visual inspections of the storm system area drain and out-fall verified that the fuel overfill was not released or migrating into surrounding soils or ground water, therefore, actions for further prevention of migration were not applicable. (3) In accordance with physical characteristics as described in response to paragraph (2) above, no additional fire and safety hazards posed by free product migration exists, therefore, monitoring and mitigation are not applicable. (4) The drum of overfill fuel generated from the vent spill has been removed and properly disposed in accordance with station and local requirements. The top layer of contaminated compacted stone overlay of the earthen bunker which is not removed (due to tank shielding integrity) will be bioremediated and managed in place and properly managed at site closure in accordance with the applicable state and local requirements. (5) and (6) In accordance with the incident description in Part 280.62 (a), the location and amount of the release is confirmed. Noadditional measurements or free product removal activities were required.The initial site characterization information as required in Part 280.63 (a), is provided as follows: (1) The nature and estimated quantity of the release was approximately fifty gallons of Number Two Fuel Oil originating from an inadvertent overfill during a High Level Alarm calibration activity. Once the overfill condition was identified, the pumping of fuel into the tank was terminated. The overfill resulted in fuel spillage from a vent pipe into an overfill drum stationed under the vent pipe, and onto the top of the tank bunker. The spill area was contained to the stone overlay and earthen bunker on the top and a small portion of one side of the bunker.(2) The climatological conditions were clear and fair at the time of the release and are not considered a factor in the release occurrence. The site meteorological data indicated a wind speed and direction of 5.65 miles per hour from the SSW (219 degrees) with 0.00 inches precipitation. The Davis-Besse Annual Environmental Operating Report (ABOR) was consulted to determine the following land and use characteristics of the area: soil conditions, water quality, and surrounding population. The Davis-Besse Nuclear Power Station site is mainly comprised of back-filled clay substrate with a small portion previously used for farmland. The surrounding area is mainly farmland or marsh and is sparsely populated. As reported in the AEOR for the facility, the 1990 census indicates the population for incorporated cormnunities within a 10 mile radius of the site are: Port Clinton, 10 miles southeast, population 7,106; Oak Harbor, 7 miles south, population 2,637; and Rocky Ridge, 7 miles southwest, population 425. The type of soil underlying the site back-fill is clay substrate which southwest, population 425. The type of soil underlying the site back-fill is clay substrate which prohibits the threat of migration into the ground outside of the site by runoff other than storm or sewer systems. The on-site storm sewer run-off for this area drains to an on-site holding pond and is routinely monitored. Site investigations verified no run-off to surrounding lands or ground or water systems occurred as a result of this release, and no subsurface or local wells are potentially affected by this release.(3) and (4) Not applicable, reference response provided to Part 280.62 (a) (5) and (6).Part 280.64, Free product removal activities are not applicable, reference response provided to Part 280.62 (a) (5) and (6).Part 280.65, Investigations for soil and groundwater cleanup, gre not applicable. Because the bunker is missile shield for an emergency system at a nuclear power generating facility, no borings were taken of the earthen bunker. Initial assessments performed at the time of the overfill, and re-verification inspections performed prior to initiating the required 24 hour notification to the State Fire Marshall, validated that the spill area, ground and surface water storm runoff systems had no evidence of aboveground release, noi did a threat of release into surrounding soils and groundwater exist.Part 280.66, Corrective action plan, and Part 280.67, Public participation, are currently not applicable. Responses to these sections are not part of this report.In accordance with 40 CFR 280.62, the report is due September 21, 1998, or twenty working days after the incident occurred. ATTACHMENT 2 S RESPONSE TO SEPTEMBER 1, 1998 CORRESPONDENCE On September 9, 1998, the Davis-Besse Nuclear Power Station received correspondence from your office dated September 1, 1998 requesting response actions supplemental to the twenty-day report submittal in accordance with 40 CFR 280.62 required by the Duty Officer(s) at the time of notification: The response cited in the correspondence dated September 1, 1998 was for a 'suspected release', as defined in accordance with OAC 1301: 7-9-13(B)(3), which required tightness testing results within 10 days of the incident and site check results within 60 days of the incident in accordance with OAC 1301:7-9-13 (D).Actually, the release was a confirmed 'release' under actions specifically defined in accordance with OAC 1301:7-9-13(B)(2)(b). Furthermore, the release was from an emergency generator system at a Nuclear Power Station regulated by the Nuclear Regulatory Commission (NRC) under 10 CFR 50. Due to the nature of the spill and the maintenance and integrity requirements for the system, the Davis-Besse Nuclear Power Station does not agree to perform the activities referenced in OAC 1301:7-9-13 (D) and (E). However, a site assessment was performed in conjunction with the requested twenty-day written report in accordance with 40 CFR 280 (F) and is included in this correspondence (reference Attachment I).In addition to the written release response requested August 21, 1998, the following information is also provided for actions requested in your correspondence datedSeptember 1, 1998.(1) Regarding the tightness test referenced in OAC 1301: 7-9-13 (D) (1), due to the nature of the tank system, periodic integrity testing of the tank system includes tightness testing, .and.u.rent testing.._ results verify the tank is of sound integrity. In addition, the cause of the release was visually and positively identified as an overfill spill in accordance specified activities listed in 1301: 7-9-13 (B)(2)(b) and was not a function of the tank integrity, therefore, additional tank tightness testing was not warranted. (2) Regarding drinking water well analysis referenced in OAC 1301:7-9-13(D) (2), in consideration of the nature and extent of the release, visual inspections and assessments performed at the time of the release, and the physical characterizations and distance of the release site in relation to any surrounding property drinking water wells, more than sufficient evidence is provided to demonstrate that the release will not impact a drinking water well on a nearby property.(3) Regarding the site check in accordance with OAC 1301:7-9-13(D) (3), the nature and functional requirements of the tank system and inherent bunker shielding requirements prohibit borings on the tank earthen bunker. Additionally, site investigations and the nature and extent of the release demonstrated that migration of the spill did not occur.(4) Regarding action levels referenced in OAC 1301:7-9-13 (E)' (3), as described in response (3)above, no borings were performed, therefore, comparisons with the action levels based upon Site Feature Scoring System (SFSS) were not performed. The SFSS work sheet is not included, however, the SFSS is estimated as 70 based upon scoring system in section 1301:7-9-13(D) (3).Site details as listed in response to 40 CFR 280.63 (a) of Attachment I detail the site characteristics. (5) Ihe UST is part of an emergency generator system at a nuclear power generating facility regulated by the United States Nuclear Regulatory Commission, and is exempt from OAC 1301:7-9-07 (E).(6) Excavated soils will be managed as petroleum contaminated soils (PCS) unless laboratory analysis indicates otherwise, and the soil will be properly disposed in accordance with state and local regulations. A Soil Disposal/Treatment Notification form will be submitted to your~office as required for PCS disposal activities. S i!e~4-Y j4ZoVaJ~S -~ ie~~sr i J ,14 1S c'6/'ýeS4.~.,.~ ,'~, CENTERIOR ENER~GY 300 Madison Avenue Toledo% OH 43652-0001 419-249-2300 Louis F. Slorz Vice President-Nuclear Davis-Besse RAOG 94-09 February 22, 1994 Timothy 0. Hickin Emergency Response Unit Supervisor Emergency Response Section Division of Emergency and Remedial Response Ohio Environmental Protection Agency 1800 Watermark Drive P.O. Box 1049 Columbusy OH- 43266-0149 ........
Subject:
Submittal of Information Regarding Spill of Gasoline Identification Number 01-62-0180
Dear Mr. Hickin:
In accordance with Section 3750.06(D) of the Ohio Revised Code and Rule 3750-25-25(A)(2) of the Ohio Administrative Code, enclosed is the information on the onsite release of unleaded gasoline at the Davis-Besse Nuclear Power Station reported on January 18, 1994; spill event identification number 01-62-0180. Should you be in need of any further Information, please contact Mr. W. T. O'Connor, Manager -Regulatory Affairs at (419) 249-2366.Sincerely yours, JCS/lkg Attachments 5-S cc: M. Gerber, Ohio Environmental Protection Agency Local Emergency Planning Committee (Ottawa County)0 Operating Companies: Cleveland Electifc Illurninoting Toledo Edison RAOG 94-09 Enclosure Page 1 TOLEDO EDISON RESPONSE TO OHIO EPA SPILL EVENT IDENTIFICATION NUMBER 01-62-0180 JANUARY 18, 1994 DAVIS-BESSE NUCLEAR POWER STATION 1. Reporting and Event Summary Question: a) Time, date and duration of release or discharge. b) Time and date of discovery of the release or discharge. c) Indicate the Ohio EPA spill number and the National Response Center case number.d) Provide an event summary.Response: a) The actual time, date and duration of the release is unknown. The release most likely occurred between approximately 0300 hours on-....-January-16,-1994,- (the-last recorded-vehicle refueling) and.1130 hours-January 17, 1994 (the first recorded observation of pump malfunction). b) The actual time and date of discovery of the release of gasoline was approximately 1800 hours on January 18, 1994.c) The Ohio Environmental Protection Agency Spill Response Number is 01-62-0180. The National Response Center Number is 217385.d) On Monday, January 17, 1994, approximately 1300 gallons of gasoline were found missing from the above ground gasoline storage tank at Service Building 4. The gasoline is used to service site vehicles; pool cars, snow plows, etc. On the morning of January 17, the gasoline pump appeared to be malfunctioning. Gasoline was pumped from the tank and about eight gallons were pumped and the flow stopped. The storage tank level was checked and measured approximately 100 gallons. The measurement of the tank on Friday, January 14, indicated approximately 1470 gallons with 88 gallons being dispensed over the weekend. The last gasoline was pumped from the tank on January 16, 1994, at 0300 hours.Industrial Safety and Environmental were notified of the missing gasoline. The site was checked for indications of a gasoline spill.There was no evidence of gasoline in the concrete dike surrounding the tank, or of any amounts around the gasoline pump or inside the pump housing, or in any of the areas' storm water outfalls (i.e., marsh or ponds). No gasoline odors were present. Security was notified for potential theft investigation. On January 18, 1994, the tank and underground piping to the gasoline pump were pressure tested with no evidence of any leaks. The gasoline tank was partially filled and the pump was tested by pumping gasoline through the pump. When the pump was stopped, gasoline was observed to be siphoning through the gasoline pump fire safety valve's atmospheric vent.This leak path was established when a diaphragm failed in the fire safety valve. This confirmed that the gasoline had been released to the environment, not stolen as was previously suspected. It is suspected that the fire safety valve's diaphragm failed due to the extremely cold RAOG 94-09 Enclosure Page 2 weather on January 16, 1994, and at 0300 hours, when the pump was last used, gasoline siphoned through the atmospheric vent until the pump's suction was uncovered (100-gallon tank level).At 1800 hours on January 18, 1994, notifications were made in the following sequence: the National Response Center, the State Emergency Response Center, and the Ottawa County Sheriff's Department as required for the local fire department and local emergency planning committee notifications. At approximately 2120 hours on January 18, 1994, the OEPA Division of Emergency and Remedial Response representative arrived onsite and inspected the spill area.Collection activities to date have recovered approximately 500 gallons of gasoline and determined how far the gasoline has spread. The gasoline is contained in the porous fill underneath the Service Building 4 parking lot and poses no environmental concerns as it has not entered the marsh area, and is confined within Toledo Edison's property. The leak has been isolated and repaired. See Attachment 2 for a sketch of the incident scene .-- -...2. Location Question: a) Location of the facility from which the release or discharge occurred.b) Location of the release or discharge. c) Longitude and latitude Response: a) Toledo Edison Company Davis-Besse Nuclear Power Station 5501 North State Route 2 Oak Harbor, Ohio 43449 b) Ottawa County Carroll Township Oak Harbor (nearest village)c) The longitude and latitude of the Davis-Besse Nuclear Power Station is 410 36' N, 830 05' W. Attachment 1 contains a map showing the site location. The release was not transportation related.01 RAOG 94-09 Enclosure Page 3 3. Product Release Question: a) Chemical name (common name or technical name) and Chemical Abstracts Service (CAS) registry number of the substance involved in the discharge or release.Response: a) The material released was Gasoline, BP Super Unleaded (No CAS Number is available because the product is a mixture). The Material Safety Data Sheet (MSDS) is attached (Attachment 5). The material is not an extremely hazardous substance. The estimated release quantity was approximately 1300 gallons.4. Environmental Impact Question: a) Identify the environmental medium or media impacted an~dthe extent of_the impact.Response: a) The gasoline was released into the soil underneath the gasoline pump.The estimated area of contaminated subsurface soil is 2500 square feet.There appears to be a zone of gasoline-contaminated soil approximately.six inches wide. This zone is approximately three feet below the ground just above the clay substrate. The spill is 400 feet from the nearest waterway, no navigable waterways have been or are anticipated to be affected.Collection activities to date have recovered approximately 500 gallons of the gasoline and determined how far the gasoline has spread. The gasoline is contained in the porous fill underneath the Service Building 4 parking lot and poses no environmental concerns as it did not enter the marsh area and was confined within Toledo Edison's property.Additionally, the soil beneath the porous fill material is composed of a clay substrate which Is very dense and has prevented the gasoline from migrating deeper. Area storm water drains have been isolated to prevent the potential of the gasoline from being released off site.5. Monitoring and Detection Question: a) If the release or discharge was monitored, indicate the method of detection and concentrations. RAOG 94-09 Enclosure Page 4 Response: a) As described in Section l.d., Event Summary, the gasoline leak is thought to have occurred during the weekend of January 15 and 16, 1994.The release path to the ground is not a monitored pathway and was unnoticed by site personnel. For event detection specifies, refer to Section 1.d., Event Summary.6. Mitigation and Containment Action Question: a) Amount recovered or neutralized. b) Describe any actions taken to reduce the impact of the release or discharge. c) Actions taken to respond and contain the release or discharge. Response: a) To date, approximately 500 gallons of gasoline have been recovered from the gasoline recovery sumps that were dug to collect the gasoline, and storm water oil interceptors. These low collection points are being monitored and the material is being collected throughout the remediation process.b),Weather conditions (-IOF) predicted a low probability of migration at c) the time of the release. The storm water line oil interceptors were pumped out for initial recovery. Recovery sumps were dug to recover additional bulk gasoline which may be present and to determine how far the gasoline had spread. Attachment 2 contains a sketch of the incident scene. Approximately 500 gallons of gasoline has been recovered to date. Gasoline recovered from the recovery sumps has slowed. The remaining gasoline appears to be contained in the porous fill beneath the parking lot. Additionally, the storm water lines have been plugged to prevent any gasoline from leaving the site from this pathway. Further remediation activities to remove the residual gasoline contamination from the soil are currently being evaluated.
- 7. Preventive Actions Question: a) Provide plans to prevent a recurrence of the release or discharge.
Response: a) The pump and above ground storage tank were taken out of service. The gasoline pump will be repaired and redesigned to ensure that any future pump failure would be captured in secondary containment. I I 0 RAOG 94-09 Enclosure Page 5 8. Health Risks Question: a) Describe any known or anticipated acute or chronic health risks associated with the release or discharge. b) Advice regarding medical attention necessary for individuals exposed to the substance released or discharged. Response: a) No known or anticipated acute or chronic health risks are associated yith the release as long as the plume is contained in the soil substrate and completely removed or remediated, and there is no migration into waterways or exposure to cleanup personnel. b) N/A 9.Question: a) Indicate any air, water or other permit numbers which may be pertinent to this incident.Response: a) The National Pollutant Discharge Elimination System (NPDES) permit number for the Davis-Besse Nuclear Power Station is 21B00011*ED. The gasoline was contained to the Davis-Besse site. The gasoline did not enter into the "waters of the state" and posed no environmental concerns.Question: a) Provide a chronological summary of the incident. Include a chronology of communications with the state and local government agencies.Response: 10.a) Chronological Review Date Time Event January 17, 1994 -1130 Measured tank level and noticed -1300 gallons of gasoline missing. RAOG 94-09 Enclosure Page 6 Date Time Event January 17, 1994 ~1200 January 18, 1994 January 18, 1994 January 18, 1994 January 18, 1994 January 18, 1994 January 18, 1994 January 18, 1994 January 18, 1994-~1000-1730-1830-1903-1918-'1948-1955-2010 Environmental and Safety personnel responded to scene and commenced investigation. No evidence of spillage on ground or in marsh area, or site ponds. Pump housing inspected and no indication of gasoline. No gasoline present in concrete dike surrounding the tank. Theft of gasoline was suspected. Piping between tank and pump pressure tested. No indications of leak in pipe.Still no indication of gasoline spill at scene.Refilled tank and tested pump.Identified leak from fire safety valve in gasoline pump. Leak immediately Isolated and capped, pump and tank were tagged-out toprevent-use and further release.Notified plant management of gasoline leak and spill. Commenced notification of regulatory agencies. Commenced product recovery. Recovered -300 gallons of gasoline from oil separators. Notified National Response Center (Petty Officer Floyd) of the release of gasoline. No release to "waters of the State" occurred.Notified Ohio EPA.Ohio EPA Night Duty officer (Tom Buchan)called and gasoline release information provided.Ohio EPA, Division of Emergency Response, Emergency Response Coordinator (Mike Gerber) called to get release details. Indicated he would come onsite to investigate. Ottawa County Sheriff (Deputy Sauvey)was notified of gasoline release.Ottawa County Sheriff is point of contact for Ottawa County Emergency Management Agency (EMA) for local fire department and LEPC (local emergency planning committee). RAOG 94-09 Enclosure Page 7 Date Time Event January 18, 1994 -2120 Division of Emergency Response, Emergency Response Coordinator (Mike Gerber) arrived onsite for release investigation. !11.12.Question: a) Provide manifest, bills of lading, laboratory analyses which were generated which are germane to the incident.Response: a) See Attachments 3 and 4 for sample results and manifests. Question:--~- a) Describe any extenuating circumstances which caused the discharge. Response: a) The cause of the failure of the gasoline pump fire protection valve diaphragm is believed to be the severe cold weather conditions that occurred during the weekend of January 15 and 16, 1994. !I_ ----8~2 N S:: I***.%~ -'!ý NM I,-I 0 tdj Z4.133 00=0 b uQO LAKE 57A.* q,.£,~ ~A96A ARE OF STUD-poli / A/D2~', 1>. ~~ -~P 643>.*CDd* -.-ALL L~VAION. ARE ERA~ TO .6.L~..Al~7O SM/r? 0 Map Reproduced from Updated Safety Analyi Report Volume 3 RAOC 94-09 Attachment 2 oDqhV TO M-1 0I< SOLSrAINDC -rollbumy)RXR8 PC)Mirmdko bid on &wmvot$U m oftatPlb Mly. kua44 difawfolovt9ole Mof (in owets)MAINI'Ma?~ GWREFACILITY SDNRI&MICHIGAN DEPARTMENT OF NATURAL RESOURCES ,ltigfa as amaenoeo i31o ACt IJO. JA.RAOG 94-09 t19.Attachment 3 Failure to tile Is under/ -.,aOe 299.548 MCL osecti.¢on 10 of DO NOT WRITE IN THIS SPACE Act 136. PA. 1969.ATr .DIS. LI REJ. 0I PR.LI Please punt or 1-t Form Approved. OMB No. 2050.0039 Ex 5 Ies 9-30-94.Page I Informalion in 'he shaded areas f S not required by Federal of / law.3. Generator's Name-and Mailing Address-OL po EPwo7 -'.1 ,&^ 4 1-- sv -P "'k6 .4. Generator's Phone( 7-q I -A. State Manifest Document Number MI 307.8050.B..State Generator's I D --...S-, .: ' 73 U'r~',;V -- : " " 0. transporter 1 Company Name CO(IS/ al44f a (flA'Th c tw. A 6. US EPA It Number D.ETranspoorter's Phone /~~Zv.~-N E 0 7. Transporter 2 Company Name 8. US EPA ID Number E.State Transporter's ID I ( I ( I I I I I- -I [ Transporter's Phone 9. Designated Facility Name and Site Address 10. US EPA ID Number G. State Facility's ID a7/ 1" 0 1! P rL/c A VG. 8.Facility's hone, --1I. US DOT Description (including Proper Shipping Name, Hazard Class, and 12.Containers
- 13. 14. I. Waste HM ID NUMBER). No. Type Quantity U NIH a. UK.-nlc 1(4ACL (A Nri 0.ZE-2¢ ~ ~ ~ ~ ~ ~ ~~ i , -r-r 0i/1 1010o1) "I b.C.I..-' "___ __ __ ___ _. L. I..L JJ I -".I I J.:_? ýAddltlonal Desc" ptlons forMatedals Usted Above, ..K, HandIlpO ...Waqs a el ..--C'C5i W A -.. .m-bI ,,i_ _ _ _ _ _ _...... bl I* ~d//lb. bpecial Handling Instructions and Additional Information
' 'pF -I ItFX ' ý fpWz ro 6 CA.FotPAA +05 4P46L.9- 1-t Yrt5&-16. GENERATOR'S CERTIFICATION: I hereby declare that the contents of this conslgnment are fully and accurately described above by proper shipping name and are classified, packed, marked, and labeled, and are In all respects In proper condition for transport by highway according to applicable Inlemaltonal aM national govenmvent regulations. If I am a large quantity generator. I certify that I have a program in place to reduce the volume and toxicity of waste generated to the degree I have determined to be economically practicable and that I have selected the practicable method of treatment. storage, or .disposal currently ava,.able to me. whtii.h minimizes the present and future threat to human health end the environment: OR; if lam a small quantity generator. I have made a good ith effort to minimize my waste generation and select the best waste management method that is available to me and that I can afford.C 3£'3 a C 3 C 2 C C Printed/Typed Name Signature _ Month Da Y.Si-(r -f V\ i D T 17. Transporier 1 Acknowledgement of Receipt of Materials Date A Printed N a Sign M D a"*" .. l o 18. Transportef 2 Acknowledgement or Receipt of Materials " Date..T Printed/Typed Name signature Month Day' Year 19. Discrepancy Indication Space) " 'A c 1 20. Facility Owner or Operator: Certification of receipt of hazardous materials covered by this manifest except as noted in Item I9.Printed/Typed Name Signature Mono) Day Yea'IFýl 1 EPA Form 8700-22 (Rev. 9188)To he mnaled by Michigan ONR G "-.iio, Itr Box 30038 PH 5110 RHe. i0192 I1 please print or type. (friNM creslged Wa us.en ea #R (2jpkChj yPrewrdrr.) Pane A00e,. MV ~ W ie 205.0. ~&.2. Page I IInformation in hethade ern... .. ...... If=', .. i .... ..UNiHt-U..1 HALA.U.US_
- 1. Generato's US EPA ID No. Manifest I..1 7 .1*~'I WA),- It MANIFEST CHDOO0720508
.( " of j is no (Ia..byFeT, 3. Generator's Name and Maiting Address A. State Manifest Document Number A(.K H ;ARBOR, 0H. 8. State Generator's ID ...4344V 4.Generate'sPhon"( 419 ) 419i ' , " " 5. Transporter I Company Name 8. US EPA 10 Number Ci Atiknspý'ei Id ~ .'RESEARCH OIL COMPANY I GH0004178612 ..... ......( N 7. Transporter 2 Company Name 8. US EPA t0 Numnber spre_. ... .......-- :' .: 9. Designated Facility Name and Site Address t0. US EPA I Number G:Sft('aclty'a"ID
- r. .. II,.RESEARCH O3IL CO. .. '. '.'- .; ..' .2655 TRANSPORT RD. "-. ;,-,.".,;.
'--"-:-.:, CLEVELAND k H. Facilnt'a ." V , I OH4115041787.. .......... 1(216) 623_8383 ;._"Continer 1.4.It. US DOT Description (Including Proper Shipping Name, Hazard Class, and ID Number) 12. 3,ontaUne3 HM Type Total Ouantity WVO 'Waste No.'a. N ast* CoI b'.stible Liquid. n.o.s.Irs ,bitu iti bi e L i'oq d 't LIN 19 9 .. P.11 1 d. V.lions Ioe aledej Lsted Above ~ .HntlgCdelot OM W Wstes 4sb-~.tEGN~~R RESONS V18O-b9~95 ERij.:.s. ,T~EIN 5J Y.M........................_ I...........__ __ ___"_ __ __ __,_ __.4.;ý -W:.: "YT; : .".F '-- ..G I!A T 0 R 15. Special Handling Instructions and Additional Ino allon l-'U# V _.I4s L R -L .- I USE GLUVES & GOGGLESZ PUMP TANK NEED 60' OF HOSE CALL 419-321-7149 AND STEVE WILL MEET V-tlU TO LOIAD ARVEA ACCEPT .S (a)S 001E 485 T ALL SPILLS MUST BE REPORTED TO THE NATIONAL RESPONSE CENTER AT (WO0) 424-8802, 24 HOURS PER DAY. 16. GENERATOR'S CERTIFICATION: I hereby declaie that the contents of tis consignment are fully and accurately described above by proper name and are classified, packed, marked, and labeled, and are In at respt in proper condition for transport by highway according to applicable international and national govemmenl reguataions. I I am a Large quantity generator, I conify that I have a program in place to reduce the volume and toxicity of waste generated to the degree I have determined to be ecororicatly practicable and that I have selected the practicable method of treatment, storage, or disposal currently available to me which mlnimizes the present and future threat to human heaqlh and the envronment; OR if I an a arait quantity generator, I have made a good faith effort to minimIze my waste generation and Select the best waste management method that is available to me and that I can elflord.Printed/typed Name Signature Month Day Year T 17, Trantporer I Ackorwtedgement or Receipt Of Materials Date A Piecufy Signa , Month Day Year 1a .Ti1ns a!er 2 Acknwle ýefien or Raeeceri of Materials .at.T PrintedlTyped Name Signature Month Day year E R 1 9. Discrepancy Indication Space A c I 20. Facility Owner or Operator: Certificalion of receipt of hazardous materials covered by this manilest except as noted in item 19.T Date PrintedlTyped Name Signalure Month Oar Yea'Mot I I EPA Form 8700-22 (Rev. 9-88) Previous editions are obsolete. GENERATOR'S COPY 1 I I J.()Please print or type. deo0etdlo A uV Mn Re (I 21schi) Fom O9AB -.. -V,00" Ei,. 3[.N U HA"AR 5I-ju I. Generator's US EPA ID No. Manifest 2. Page I I lnomation in the shaded areas WASTE. MANIFEST (0Hn07? .",- 7 *, Is not reqsired by Federal law 3 Genefator's Name and Mailing Address A. Stale Maifti5 Document Number-," : :" ..a. t. +/-., r: ' : -.i-:-.: *; , r. *H .OAK HARBOEiR, OH. a. State Generatlors to 4344? .r'Z 4.Generator's Phone( 419 ) 321---14-0. , 5. Transporter I Company Name 6. US EPA If) Number -St:te'T-sot'a.to os -.RESEARCH OIL COMPANY CHDO04178612 .......- .7. Transpote?-o Company Name 8 US EPA 10 Number 715Staterno,"aO.-1.E'..:'.. -. ...ail Na. .& APi~rebso -iphone *.9. Designated Facilit Name and Site Address 10. US EPA I0 Number G(3State Facility's IDt RESEARCH OIL CO.2655 TRANSPORT RD. :" CLEVELAND H. Fadlilys Phone.OH 44115 I OH00,4178612 ...... (216)623-8,383
- 12. ontaners14.
1t. US DOT Description (Including Propei Shipping Name, Hazard Class. and ID 12 Containers
- 13. Unit HM No. Type Total Quantity WUVot Waste No.a. ffl',ýte Flammable.
Liwidt n,o.t- Iroptains rxioline)1. UN1993. FGIII. R0(0018,)0101 TT : E E T J.AddfIorW-E'- -WýI!alerlats;Listed Above:- -, "--. ' ...:K....- "' and(Ing Codes (orWastes Lsted Above emer #I -a00-969-9252 ERG#27 "A? TIM ?9 i ~~~~~ ~-TM ....,-15. Special Handling Instructions and Additional Informalki0 VERBL REL#I ISqF OL.OVES &. 6OGGLES. pLiflp t;:-nl: ni-e:e -1W,` hos-e contaect Steve" Chino t9 ,19-321--!149 a) 038 AL PLSMS ERPRE OTH AINLRSOS ETRA (0 242 4HUSPRDY-I4 i 16. GENERATOR'S CERTIFICATION: I hereby declare that the contents of this consignment are fulq and accurately desribed above by propee shipping name and are classified. packed, marked, end labeled, and are In all respects In proper concdion for transport by highway according to applicable international and nationat government regutations. If l am a large quanlty generaor. I certify that I have a progtam in place to reduce the volume and toxicity of waste generated to the degree I have determined to be economically practicable and that I have selected the practicable method oi treatment. storage, or disposa currently available to me which minimizes the present and future threat to human heatth and the environment; OR. if I am a small quantity generator. I have made a good laith effort to minImIze my waste generation and select the best waste management method that is available to me and thai I can atlord.PrintedfTyped Name -Signature Month Day Year T 17. Transiporler I Ackonwledgement or Receipt of Materials .Date' ,ntLnmffy 'Signaturs"j) -Month Day Year t 8.'ffarsporl&'; AhA'otedgemen or Reept o Materials .. ." Dale T PrIntedfTyped Name Signature Month Day Year R! {19. Discrepancy tndication Space A lrft -Corr -'d,4/ I"-,x; A'.. .. .,-. .,-_.Y L T 20. Facilty Owner of Operator: Cerititcation Of receipt of hazardous materats covered by this manifest except as noted in Item 19.lr Pfrnted/Typed Name ISignaitae Date Month Day year I i I EPA Form 8700-22 (Rev. 9-88) Previous editions are obsolete. GENERATOR'S COPY RAOG 94-09 Attachment 4'JONES & HENRY LABORATORIES, INC./ 2567 TRACY ROAD, NORTHWOOD, OHIO 43619/(419) 666-0411 February 1, 1994 Toledo Edison Davis Besse Nuclear Pwr. Sta.300 Madison Ave. MS 3360 Toledo, Ohio 43652 ATTN: Mr. Steve Chimo
Dear:
Mr- Chimo: Below are the results of analysis of 3 samples received for examination on January 28, 1994: Sample I.D_ AC16141 Location code: TEDDBM Project account code: 285 LocaEion Descr-ipti-on: North fnhtercept6-r ...Sample collector: RR Sample collection date: 01/28/94 Lab submittal date: 01/28/94 Time: 16:32------------------------------------
- ----------------------------------------
.TEST UNITS TEST DETECTION*PARAMETER RESULT LIMIT HYDROCARBONS (gasoline) by GC mg/L <5 (trace) 5.Multicomponent analysis: BTX BENZENE ug/L 210 5.0 ETHYLBENZENE ug/L 69 5.0 TOLUENE ug/L 550 .5.0 o-XYLENE ug/L 130 5.0 rn+p-XYLENE ug/L 280 5.0 Sample I_D_ AC16142 Location code: TEDDEM Project account code: 285 Location
Description:
North catch basin Sample collector: RR Sample collection date: 01/28/94 Lab submittal date: 01/28/94 Time: 16:32 TEST UNITS TEST DETECTION PARAMETER RESULT LIMIT HYDROCARBONS (gasoline) by GC mg/L Not detected 5 Multicomponent analysis: BTX BENZENE ug/L 4.9 1.0 ETHYLBENZENE ug/L 6.0 1.0 TOLUENE ug/L 20 LO o-XYLENE ug/L 10 1.0 j+ >-XYLENE ug/L 21 1.0 Page: 2 February 1, 1994 Sample I-D- AC16143 Location code: TEDDBM Project account code: 285 Location
Description:
South interceptor Sample collector: RR Sample collection date: 01/28/94 Lab submittal date: 01/28/94 Time: 16:32------------------------------------------------------------------------ TEST UNITS TEST DETECTION PARAMETER RESULT LIMIT------------------------------------------------------------------------ HYDROCARBONS (gasoline) by GC mg/L Not detected 5 Multicomponent-analysis: BTX BENZENE ug/L Not detected 1.0 ETHYLBENZENE ug/L Not detected 10 TOLUENE ug/L Not detected 1.0'o-XYLENE ug/L Not detected 1.0 mn+p-XYLENE ug/L Not detected 1.0--------------------------------------------------------------- Please advise should you have questions concerning these data.Respectfully submitted, Fred W. Doering President 2478 1994.01-18 15536 #10S P.02/03 FW)H I BP 0 1 L TECH REqEpRCH=%NMMM -To RAOG 94-09-Attachment 5.MATERIAL SAFETY DATA SHEET BP OIL 24-HOUR EMERGNCY ASSISTANCE_ GENERAL ASSISTANCE NFPA FIRE HAZARD SYMBOL BP Ameiica (1i Ohio): 800-362-6059 216-441-8124 A 4 .W (Outside Ohio): 800-321..642 .CHEMTREC Assist: 800-424-4300 MSDS Numiber> 104a MANUFACORERISUPPLIER: BP OH Company ADDRESS: 200 Public Square. Cleveland, OH 44114-2375 ° " ~ ~~~............. ..1...TRADE NAME;GASOLINE, HP SUPER UNLEADED CAS NUMBER.SYONYIM(s): -CHEMICAL FAMILY: MOLECULAR FORMULJ MOLECULAR WFjGHT: PRODUCT CODE.MIXTURE eASounE; MOTOR FUEL HYDROCARBON U MIXTURE MIXTURE P 1630 I'HIERARCHY: 040.040 , -w-r ,0,wx.g HEALYM nAai.orL OP. rATa :i 31aSVL 1 orn W-ALxASTh:nON HAZARD TIf SwAL~w9--CAN Ew=ti LUNGS MW a&usn DmhfGE VAPORS 1aW BE-HAmmUM MAY BE IRRZTATnG TO nhE SIM=, EIES AND RESPXPATORY TRACT LOMQ-TSRIU EfPOSflR% TO VAPORS HAS CA-USED CAICER In SOUS LABORATORY A)IWLS FLAMMABILITY DAHQZRI txxP= wzNwi"sz L1=U0 AND VAPORS VAPO )fl CAUSE 9=AS4 RRACTVITY
- STAýýopyTight
@ 1980. National Ptae Protectlon Assoc., MA 02269.rhis reprinted material is not the complete And official position of the NFPA on the referenced svuquect, which is repiýsented 3nly by the standard in its entirety. FROM I BP OIL. TECH4 RESSPAM4 TO 2478 1994.01-18 15337 fie P.03/09 INGEST10M: 2RODERPA2!E W=XC-. MM=a~ q3:4l LDE~o -3.0-30 0MR. Ajiat:1.0 +/-ntoQ 1utAn~ oMaY (Mf pnQimownOt~ia. MCY CAXnS' Vaztro0i~t*tizDel dj1gtuwbvanoe S~tCCM limy :Wd1Qda 17,LIatioa, Mus1ed, vomizting mnd diarrhien. may Oa~to% hagmiu1 central nnOXO1.Ud wsytoa 6ffoatS., Effactu tflaY Li28lude OX=L t4ati, supborii. heada~ohe, di~zziness, drowg~ieuoa, blurred Trigloni fativuex, tr.amorg, oowhvulujong, loan of oriooi~0~ o~,~ezpi t~omr azrret aMd doatlix.SKIN: P* C CAIrc~c~~ U=Q-T0XX. R~abbit d6=Al =a50 >5 ln1/kg. BL3!1EX~ XE IAMIH. ~61t6Pr4~ Or P1-oaffa cottact m~ rosal iL diatatti74, rednaga, itcbihgr, 3inflazw~ti.pn ioZacking1 ai~P906ible, PO-otnda infactioz. HighI prouv~a a~ici 1injectionsa ara 2SD=CrUS IEDIC2LX*RM=S Xa~uzy may not appq,= arieyosqu at firstly vjLtWA+/- a faw hoaixa' hosuue will.h-ACOMG SWol14,~ discolored and aztxaxs3ly painful (ao~ Notaot tc 3?yp+/-il eauction) .EYE;MAY ca 1 ew Slighit tranoidIit+/- i~ritý.tivi. INf1ALATMON: 'MYF c~auza xespix2ntoxy t=;.et irx~itatiLoji. 1Exzposu+/-~ 2=sy cause CQtLral Iaoxvoun nyto=OYtS1 mwa s~mi~llo to Ch1ajiifa IXiqata~ Unidoa~ ~goataLon* (a** Zzzgaatioo n sutAtn) .2ky ~a-Io CAUfAQ aflGSR1+/- aM4 LX~egidler heakit r1V~b. Relpai~td or p~o3.onged W~omz~xe i~y cwaxao beIbAVioral chanages.i SPEG1ALTPXID EEFE.Cr: Yh Cuo 4Varua 1+/-Vax and k.idZwy affacot liasad. on tastx Wi1thbr~~ Is A Dxauc 09X4,0 capo OA.14lift bas1een fouvA to b .gax.i1nogpszi to lal=Ato7xy akn4=1l Vhen giveA by 4 "1,~a fZ4,8 a~styo mtaoiiyi~y u.Vbei'~~oo ~a h*70 Y'ifilded Conflicting resulta.MW U daet&Ts13d that t1~o* Isu lijmitied ervidonon Car the coxinog.-nAoity of gasoeunii ini oX~e~r1=uta2. anima1.g aud SinV49quata eydfnoe for the C~cdinoglaniity of gApoJAino in hxumans. (X2Ec* Class--2B) -WUNfl00- 7Tho uxe og .vx hydjsooux2bn fuel liA an axea. without adagumtiA voxtntilaion may MOnrgt in hnZa~r4*Uf levala Of combrigbln prodacot eand iadequata ox-rgan 1&va1s. TU= ba.0 daQtoxmLd.u t~jt 04001ine ang-ize arbaait is pogaikay~ caxaiiuoffni to humans25. 1t. E4 Whin prodact dr'aw lua b~gfzQnqt. ]Uwzana $A O=c;LuOnEcjr to lab~ory' ani-Ina vhan givoxi bY 1=1ato or by inh~latiori. Thera is ah assoaiatioLo blatw~oa occupatdonal. 02:yOSIm to banzone and iu~mazk lostcoinia. Carcna~tenia detiariftnntioa: XARiC--Ruo=aa nd Animl~a ftufficidht "Videnca of darac3 oganicluy, (IMC Claan--.); EIp-ftown caxcijaogaa; AActuta b4=0a poisaning cauaes csantrl a*vouz systieka deQuroooion. Oho gouoI WCfacts btih hwnNtaoloatic stywtan caivaing blood diftordera includtIngif O1Land p~'nytgi~n
- k. ttagunic and dlastogonlc J.u mamma11an and non-um=Aliah taiat oysteuw IWP~o4uctlvs toxicanlt:
only at doneB that wce maternallyl toxic, based oA 4aoto With~ND -No Data 1049/Page 2of8 NA -Not Appricable FFWH cBP OIL- TECH RF-1ZDI TO " F~t'1IB OL ELH ESP ~ TO2478 13%4.01-10 I1S38 #10S P.04/09 INGE$TION: DO ITOT XkMfUCP9 VOX~XTXa= A=AUSE 011 DAMO)M OF ASPL& lATflf raQ17If ýi3Mr 'LOOS. (et; 'Mmne.Olte med~ica:l attVezntic. Xf gpon~t'zeoug Vomitding occura, zMon1t~or folr bremthiug diifficulIty. SMI CONTACT-;R&I 0oohtinM4nates clothiusg l+/- &-1tatoy. Wau2I. £J04 ct Contact thoroughlY WithI 90XV b~d Watur. Cat wdical attention if iwit~tiotz yersista. High prgazlura Sld 3.njactions u=SMZOU WflIMAZ W~IE~IS Got- 1jmioata zaadicaJ. atteitftnt0k
- EYE C 0 TAC~T: Fluab imodia".y With larget BanUnts of WAter for ait leasit 15 Mi~lzL90.
Eyelid" ahould ba held awvay froza tha aya~b.2 to erwure thortixgh rinfring. Caet ma~ioal attontiOn If 4=4Statiton xvenult.INI{ALAT[ONN: RO46VQ fttOCte'l Poll Xxc ~om uce of axpoaunre MEI not breathina, oeanfliw *Pon aifrv 'and ozin_4.fu~ carvvdio. Gzota raotl~ita~te ion CP) itenin 4rabnri IIf fii OXY911 itu a Lopzk "ta~ uim itatodi cal- ato~ion br.hn-i tfa L~K~4 VhfTtO~i =a ft- imVot-tanti Vlak to Mageso !S- thea axtont of- aopfration 09- th* Prauct in~to tbe l~ingn sino vA Aor chemical ~n~1m~o21+/-tjU can rapidly FPxog0wVto Gj4xr failugal 'asping,'congbIing, and 6ho~ing ax* r 3 tei~tve evide48 of ugjrttn ya ffuggoated that aLU XAh1Aw*u a gpected og wwiOZJO2 ahfaion haiav bas1 Uina cheat:X-zayP.
- Iwdlata hospitalizatlion x~iotad 23a conosidered for na~yuptomatio cb.Lld~r=
Witt an abnoxmaj couat x-ray, obt=W~e or b&eToxid patients, iiitantional or inavolv 1=g-azt;ionx, and P~ti~ualt 'With aibnoz=a 49hat x-:rayn witsh olinlicaliy significant V+/-lMoxwazy 4it'eavo.10 Ganoiu +/-tentina1 flyj~taens iar iujoually mltuor And pathological ahaxngea of -tho llla= and kiuar wo ruported to be unfc==ol iu acita inoxivitions. DaconaixiAtion (induced al-a~slz oxý Uevagre) i-a qanray eia. ;tnd shovidI ba 00311dere'd on the weli- of deach individual cazs; of cooxpa taie usuil pracaution of ani on.dotraollea.l tube nBhould ba oonsideed Ptior to lav*06..%ld-ocxbos ay +/-nocruwa~ the 0ansitivity of bao Pyoe riwum to catedbeliminev; eloatzooardigralphic moninom boy~be 1ndioated And careiul coný+/- oration a21ou14 be given to tho Selection o01 ch4l~aoa Xcu~to centr;Axxu2 ii~wa yeaem signa ind aymptaon =ny r~ault from lerge Itigeotiona or aspiatin-idx~e4 ypoxia.MM7~LhkTION ).HL13x G6azojun is one ýf thte solvents Uneld brZ chemicaa siibstanoe abqaeira.whefse pbatient M~AYr Present with 4tcute- and/or chronic cantral nervoýua system sig-ns or PYmp1toms. They uay aAxQ proee-I wtI~h arrythmias. Tn canaf of akin Injaction, condider promit dabri4oamvrt of the irouad to minfimiza ziedrosgif 4*d tissus lo~a.*ND.No Data' 10 4 9/page3CV8 NA Not APPr~cable FTWM 113P OrL T1FjU4 REnEPRCH TO F~ lP I TD- SRC-f TO2478 1994,131-18 JS138 ffI0s P.O5/0s EYE PROTETOMN: Avoid GYe contg~ct wi~th tia material'. wear sOfaty 91ftnean or chellic&l !709-9100 P=ovj.&a faaotlities £11 the woxk zmca for edLýýately fl-qshing the dyes.SKIN PROTECTIN: Avoid aknld cobat Xf akLin contaot is antioai~atud, protectiva clothingi inciuxinff lwazw~icau gloves, should ho worn. Wash bAdn if they comia in aoiitct with tb~iA =ita&rLal. Use good paruoun3. bygiene. daez xagiu&xly alotmied work clothing. showazirng and c~ning Into atraat clothing a~zor 1(O2X is desirable. Product apilt an clotbing' niy rvimlt Lu da1~ad~ evaporationcm en4 a-us sq~keit fire "zazIed. Wdat cnnt~mjnated Clothilng -eP;Vrt*1Y. If 91othing i La o be lAund~zr4 by iqromoJio eilsee iiPJqxm laundorer of proZ Porocladurdau. RE9SPIRATORY PR;OTECTION: xf 0=POffu=Q limits ate exOQcoloI or it frritAtion ia o3xporisnaed, tiZOSR appr~ovd reapiratt ry Proet@(ion abould be wrorn-. Ventilation and otMxa foxtw of *ng1zaatino QOOtZV20 a~XO ften the preferred nm6ann for contxro~Jl;xg chemical ea~poauxr. Xairatpxy Protection Ina~ be nnee4e f or n -toutjina oýC .=Q;geaao situatSionz. _f p.-., JOIUNG POINT: 26.670- 226.'700 Cl 00 -440 Pi)SPECIFIC GRAVITY; 0.720;- 0.740 G 160 P'MELTING ( pIT.' V% %VOLATUt:h( 100.aoo e 4A~ P I VAPOR PRES$URE 79060og I = el 100 1'.EVAPORAYIO ' RATE (WATER=1): >-3 VAPOR DEMMrY (A]R=I): a.200 AS VAPOR~VlsGosftYý- tiD% SOLU8IL1T IN WATEFL- Nm -, QCTANOLJWATEFI PARTITION COEMFC4Ea4T., ND POUR POINT;-~PH: q APPEARANCEIO DOR: cr-M -LXQUID W=~ 2L STaoDM R OCABOt ODOR..!NEEM FLASH POENT! -37.000 a (-3s p) C i I FIAMMABIUlY LITS IN AIR(% BY VOL)LOWER: 1.400-FLAIWMAOLMlT UMMT IN AIR (%/ BY VOL) UIPPER! 7.600 BASIO FIREFIGHTINGc PROCEDUREý): WAtur M&Y be izaeff agbAva but stxeld be used~ to caae iyceia.,aab7 oml fpi~o~ r oaxpollediid cotaiesobt;tx and to 'zvQtect P6170onnal. Xf LQAa Or sPill hA0 not ignitod, 'rennilmts arenan usewaet"Prky to cliap=4 Qae u or vapor A= to proect~ peraomine athemplting to stop a led%~. us*'WatOX t6 4iJ.i~tO OPillo a~d to IlUskn th6M a~ay froU OOU~eca of Ignition. Do not f1uzu
- down public sawarx or ot~her drajlpago Myetoen. EX-Poned firefighitern meat wear HSMA/I0S~App2r6Ve4 poa:Ltiva Preanura selt-contain~ed broAtbing 5aPPAratun WWIt ftll faca miaek an~d fu.1l protective Clothinug.
ND -No Data NA ý Not AUpaable 1049/Page 4 of 8 0 tl FROH ISP OIL TECH RESEARCH TO 1 2478 1994.01-18 jSS39 #10S P.06/09.UNUSUAL FIRE AND EXPLOSION HAZARDS;Daunarous when uxposud to hbat or Clagu. VApOrZ norm flammable or explosivO mtXturen with air at roemn Vapor or gas may apread to distant ignition UouaCeU and back. Vapors may concintrate in confied areas. Runoff tO '0sWer may vause fire or explosiorn hazard- contahiers may explode in heat of firse. Xrritating or toxic substances may be emitted upon, t:erwl decoMposition. STABILITYINCOOMPATIUILTY: atabla Under anOMal .conditions of use. Avoid contact with strong oxid-1tus. HAZAflDOUS READ-U1ONS1DECOMPOS1fJON PRODUCTS: CombUit+/-+/-on may produce CO, C02 end reactive hydroocrbonS. SPILL OR RELEASE TO THE ENVIRONMENT: Xf your facility or operation baa an bo0l or Hazardous Substance ConGtieUgay klan', activate its proceures. -- Ta Sxe4inte steps to atop and contain thea pii1. Caution s hould be axeXciedA regarding "reasonn1 safety and eXpQgare to the spilled material.--3or techu~ical advise and ek*istance rolate4 to ahemlos coutact ca~flTS (BoVJA2A-S3003 and your lo0"l f ire doptlrtmeat. -- totify the National Response Ceater, if raqzired. Also notilfy ap7icpriate abatell and local. rogUl~tory Aa~'ncien, the LEMO and tbil SM10. 'Contact the'local Coast Guard if the relemse is into a watOerly..mergency Acton: Keep unneceseazy peopl. Awy; Liolate hazard area and deonlyqntr 9.Stay k1Ud .eep oat 8f low are". (Xlso Pee Pqrounal Protcotion Xntormtaton section.) Isolare for 1/2 Mile in 411 .d1irctiozs if tank, :ail car or tank truck is involved Sn fire.Spil or Leak Procedure: Shut off ignition sources; no flares, gmoZiug or Zames iz hazard area. Stop leak. if you can do it rink.. Water svpra may reduce vapvor but it may not prevant ignition in closed spaces-. Small Spills: Take up with. sand or- other nonuccbustible absorbent material and place into containera for later disposal. Larg6 SDills: Dike- far ahead of'Iquid spill; for lator dlsponal.
- . 'Noliffcataon:
clean Water A't (oil spills),: Any spinl or rslease, or subtataatial threat oX release, of thin to navigable water (virtually any stirgAae wxter) sufficient to gause a visible sheen upon the water must be reportaid inealiately to the National RUsponse (200/A24-8802)# as required by U7.S. PederaL Law. Failure to report may result in substantial civil and oriminal penaltios. Also *ontact the Coast GcArd and appropriate state -and loal regulatory agoncias.CERCLA/SARX (Chemic&I Spills) .The reportable quantity for thins material id 333 A poutrd(u). ND = No Data .1049/Page 5 of 8 NA -Not Appficable FROM1 9381 CIL TECH RESE1PRCH- -to 2478 1994,01-18 j~s40 if10S P.07/09%1xis material contai~ns onia 021 =OrQ1 Conahtjetszlt ragalatad ng ha~ardougu ýU]b tnces tUnder VLS.. Federal I-kw. Aby BPill or other~ r.loaaO or osibst~ntial th~reat of release,. of thxio oAtorial to the a~ir, w.ater or land (unless OuF-lrely contadjad iin the workpli~ca) eqia2. to or J- oxcooo of the reportable qua~tity-much be reD0fttd immediately to th*o Netioflal 3 AQgpornu Ceutor (800/424-83802). Aloe contact Apropriate atatot andz local rga3lntoty JlganldOe. Co,~tACLt ha coast Guard if apilj~d ýti4 navi1gabla. watorways under their Ju~rindlition. Fai:luX6 to 3:ePort may roault in Raboautintal ciVil and crim.LnAJ 'penalties-.
- Calcula~tod on tbA basis foIr Whichaveaq bazatdoun coOroxiefl providaug t-ba lowest Value for: RQ/ 1+/- nixtiuzes WASTE DISPOSAL: TLhig aubsta~~ade 1w~n, dislcarded 01- dipCAo, ig not apaificually Xist*4 A0 a hasamdoniu waste in Fedealmi regu),~tjonal however it could be obracteriStically hazardous Le it: ;L0* CdlS dated toxic, coxgSu.ye, 1gajtabla, or toactijj accoxin to Fedornl dafinitioue (40 CPR~ 261). Addlie21uI3.y, it could be dosignated-A'A lintadofls According~
to atate regulAhioio. Tihi~s subxtta~nog cou.1A also becoome A hazardouo Waste if It it, -i-Ad With Or c~naa In cont~ct with a hkzardo~ij waste. Cheek 40 CPR 261 to det-mina. whether it ia Zt haWardou.5 Vests. Xg it is: a. baaxdouz 'waste, raonl*.tions at: 40 ca1n 262, 2 1ý, 264, 260. an4*270 *pPly. chemical addition~s, processing or othexwiaa Altaring this materinaL may nake the wastea managexeut-infor+/-matiorx presented in this msPCs incomiplete, inAnourireoOr Otherwie naprpite -UhG tZI.LU~portatioai, storage, tX-eAtment, and daposal of thia mWa~td =ntowial 82¶Ult be conucted in acmliatice Idifth all applicabla Rdowal, a tata, =nd local reg ilnt;Lonx SARA TMTE IQ INFOR~MATION; I4.stad~ balow axv the Mxaxd. categorla. ft t~ke gVnorfun4 .Aw~1edments And R~uthorizat4bna2&t (SAM~) Secticm 317.131.2 (40 CP 270) 1 Immefitre 9=W!rd X -Delayed Hazard:~ Y~r Flra Hard. X Pressure Hazard, -.Reacttvity Hazard: -ThU PXndalOt COntainsO the f-olewing toxic~ abminial(a) nubjeot to the raportingr Teqnix~unlalF of the Stpa2rund Aondm ants and ReauthOriZation-AXt (SAXR&)sedF-1.ou 313 (40 CW'R 372): Com~ponent: CAS Nwefler .Maximum %Tolugns 108-88-~3-. 12-0D0 Xylene 1=3-20-7 i2_000 B&nzene 71-43-s *oo l,2,4-Thmenhyfl~b61zene .95-63-6 .3.000 Eftljbeniene 100-41-4 2.000* Cyclohexane 110-82-7 1.000*ADDITONAL ENVIRONMENTAL REGULATORY INFORMATION; Olin material containse a ubtshunc% lisetd as a Iiazaxdotip aix'- polluta~t vmder U.S. Fedeala zvilatWne See 40 cxR Part 61 for restrictions which may applky to +/-ta use.*Thin mmnAmta~ia co22tain.5 a =inixt~uxa o ubatanees, name of which axe listed an t-oxic POX1Mtazits Pursuax~t to 40 ClER 122.21, A~etidix D, Tables XX/Ifl/V. A.ny qusurual i~t-rOdwiction. of tliSx oubutauca into the facility'a process streninz, xtoxtawter ansi/on W*At&W5~tme2 otild )Zaaqlt in. the Y$,olati.ou of U.S. Padaral yAW. raottitiagg rMut k1otify the VEAan soon. A~r they know, or ha.'r. roaaon to believe, that ally activity has ocaurred, Or will occur, Vhiebt Would reae41t im'ehe dischaxue of a taxia poll~utant whlich iA 21ot zeamlated in the facilityss ITrnmS permit. Notification lavela are '2ono2x+/-bod I2 40 CFR 12 2.42(at) (1) and 122.42 (a) (2). Refer to spill 0ection for a44itiona. -rogu2lAtOXY xequf~rexnents -NO = No Data NA -Not App~cable 1049/Page 6 of 8 FROH :8W DIL TECH WRES-fRCH TO t 2478 19S4,01-ia IS:41 #185 P.88/es TherQ bay be Seaoifia regUlations at the local, ragional o0 gtate level pertain to this lnaterival. Thii %roduot contains ingred3ent (a) known to the state ot California to Caro0 oancer, birth defects or other reproductive harm.conbans " Conaot OSl standard 1.910.1025. Initial air Wnijtorng should be conducted to deteoxine if exposures are above .- p1pm action lmit o= I pm mL. If 8xpoduXOU are &bov~o 1 OSHA requirements apply for trailnIf.Sr medical surveflianca, p xrsonal/provec6tiVe aqwiment, regulated areas, eta.The tolloving CanAdian Workplace Hazardo'tu X'torlulu Information System {EHaIS) catntrorion apply to thits Drodtce: CampressedGss -Nammtable/Combustible x ozidizer -Acutely Toxic -Other Toxic Effects X SbHazardous -Corrosive -Dangerously Reactive-FtAt4DUNGlSTORAGit: Store gasoline only in approved, claarly labeled containeru. Uever store in glano or UnapproV9d plastic containers. stoe ?tb~t~bty aloedcontainara in cool, dxy, isolAted, weit-ventdilAto4 area away =-oak hbat, souras o' lgltion aud ,InqoomatibLas. Ground lines and eqdipmant usaed uring"* tralnsfe to reQ~ j- tUhe possibility o- atatia nparc-iniviatod fire or axplosion. U86 good t'C94q hy~iQne Lflactices. Wasn ha-ds bofore aativg,' dzinkIna, smokipl, or using to53.et'facilities. ..Remove~ c~taxibate4 clothing and clean before reuse. Ohower after work using uoap and water. to not siphon this product by mouth. Use only as a mtor fuel. -Do not use for pressure appliance fuel, or* other use. Do not store, in uAlablcO contaianers. rep out of reach, of children.* EMPTY CONTAINERS; En~tty coatAaie!rB may contai toxic, flmmwtblefconbustible or explonire r.4jiauo or vap~ror.DO not .cut, gri=&, drill, Veld,. riuse o4 diopooe containers unleas a4oquate precautlona tnaen etgainst those haeardd."* ~ ~ ~ ~ ~ ~ ~ 1 1 WO pill__ _. ... K-..... ........ -- -............... D.O.T, PROPER SHIPPING NAME (49 CFOi 172.101): D.O.T. HAZARD CLA.SS (49 COl 172.101): UN/NA CODE (49 CF- 1724-01): PACKINQ GROUP (40 CFI 172.1011;BILL OF LADING DE8CRIPTION (49-CFR 172-202): D.O.T. LABEL.S IREQ, IRV,(4 CFR 172.101): D.o.T. PLACAfDS REQUIRED (49 COR 172.04): IAlSODrIf; 3, UN1203, PC X1 3 UN 1203 Xr GASOL*NK 1 5, UN 1203, PG 11 PLA~nOML LIQUID!I ND = No Data" NA -Not Applicable 1049/Page 7 ot 8 o I I I FRW 9 BP 0 1 L TEcH m-,WZýFRI A OL ~c-dREEfRC-( TO2478 1994.01.-16B 15942 #ie e f.es/os TO 9.~' ..'. ~. 4. I CAiS U10 -1% 1 ZVQSU1E L 1 X=rS -RF 8009-61-9 99.99-100 200 ppm (690 =9/m3) TLjVi 500 Vppm (J.'480 mg/m3) S¶P.P (Ac-GIU 200 ppm (900 mgIld3) PELi; 500 PVM (1,500 zMfJU) STME (0m.)CGaspli.1l my cont~iu teha following: T611~AI~a108-68-3 10-12 1.00 rpm (077 ,Mog11) 2Wt. Igo pm4 (565 knUIM3) 9T (ACG3X)1.00 ppm (375 mg/H3) PMt; 1-50 12pm (590 mg'/X3) STMT. .(OSEW l00 pp= (375 inr/H3) 104kou~r TL¶'7A 150 pma (!;Go mlwl3 S¶EL (=%O=H 1yai*:330-20--7 10-12 l00 ppm (43~ =/l ) IM)TLV1 S 150 p (651 mq/3) STFlL (AlCQIH)100 rpm (435 yma/M1i3 PElL: X.9 p I ppm PVlL; Sppsm BIlL (QBH&+/-,2~-ey~ewor~z95-63'-6 U-3 25 )ppm (123 M91113) TT47 (ACQOaW 3.~bf~~ 00-41-4 0-2 i.00 ppm C43d iwjI1m) MV: ' 125 pm (S43 naM/173) STPL CX8P:=)*1ohZ~zo 10-8-70-1L 300 ppm (1,030 wg/l3) TiV (Ac=Q)300 ppm (1,050 mg/193) PEL (09EC)Re~xn~i&.t cowponerms iot x detaltnined b.xc~dogx andIor bazaerdoum colnponento preac=~at Inao than 1.014 (04.:L* f~ox REVISION DATE, 17-apr.1992 REPLACES SHEET DATED: 21-lan-1991 COMPLE~TED BY: SP OIL HSEQ DEPARTMENT 1101108 The hlurrnadio6 preeained herein Is based on datx *x1dued IQ bu 2=r;a1 va of hgAt I FV~wmfan tl oft Ma%4 G~fWt V~at& Shut4 Hevr, no wnmnd or tap(mOeflaGofl .oprs o iimpflad. s ~made~ ~ IN aoumcy or datUef~w~q na an d fetVW=l2w~60c\ nor is any auffi-orba1n given or knrodi prc. ny patntid lawngun wlihout a ibmso. inaddodI50 mo roaponsibWMy cmn be asrumed by vendor for any duagse or kijuy rest4fing horn hbbnonr uso, bmm any ND -No Data NA -Not AWpicable 1049/Page 8 of 8 "-a Davis-Besse Nuclear Power Station 5501 North State Route 2 t Oak Harbor, Ohio 43449-9760 RAOG 07-0005 January 29, 2007 Mr. Andy Gall, Environmental Specialist Division of Surface Water Ohio Environmental Protection Agency Northwest District Office 347 North Dunbridge -Bowling Green, Ohio 43402
Dear Mr. Gall:
Subject:
Submittal of 2006 Annual Sludge Disposal Report Enclosed is the Annual Sludge Disposal Report for the Davis-Besse Nuclear Power Station Sewage Treatment Facility for the 2006 calendar year. This report is submitted in accordance with the requirements of the National Pollutant Discharge Elimination System (NPDES) Permit S #21B00011
- ID.If you have any questions on this matter, please contact Mr. Patrick J. McCloskey, Manager -Site Chemistry, at (419) 321-7274.Sincerely yours, Vito A. Kaminskas SMC/Attachments cc: Ohio EPA Central Office, Division of Surface Water RAOG 07-0005 Attachment I Page 1 of I 2006 ANNUAL SLUDGE DISPOSAL REPORT for the DAVIS-BESSE SEWAGE TREATMENT FACILITY NPDES Permit #Reporting Period: Sludge disposed of: Disposal Method: Analysis Summary: Problems Encountered/
Complaints Received: 21B0001 1*ID January 1 through December 31, 2006 129,700 gallons Transported to Sandusky, Ohio Sewage Treatment Plant for additional sludge processing None None "S I'0 Davis-Besse Nuclear Power Station 5501 North State Route 2 FOak Harbor, Ohio 43449-9760 January 18, 2008 L-08-0008 Mr. Rick Zuzik, Environmental Specialist Division of Surface Water Ohio Environmental Protection Agency Northwest District Office 347 North Dunbridge Bowling Green, Ohio 43402
SUBJECT:
Submittal of the 2007 Annual Sludge Disposal Report for Davis-Besse Nuclear Power Station Enclosed is the Annual Sludge Disposal Report for the Davis-Besse Nuclear Power Station Sewage Treatment Facility for the 2007 calendar year. This report is submitted in accordance with the requirements of the National Pollutant Discharge Elimination System (NPDES) Permit Number 21B00011*ID. There are no regulatory commitments contained in this letter. If there are any questions or if additional information is required, please contact Mr. Patrick J. McCloskey, Manager-Site Chemistry, at (419) 321-7274.Sincerely, Vito A. Kaminskas Director -Site Operations Davis-Besse Nuclear Power Station TSC/SMC Enclosure A. Annual Sludge Disposal Report for the Davis-Besse Sewage Treatment Facility cc: Ohio E P A Central Office, Division of Surface Water Enclosure A L-08-0008 Page 1 of 1 2007 ANNUAL SLUDGE DISPOSAL REPORT for the DAVIS-BESSE SEWAGE TREATMENT FACILITY 6 NPDES Permit #Reporting Period: Sludge disposed of: Disposal Method: Analysis Summary: Problem Encounter/ Complaints Received: 2IB00011 *ID January 1 through December 31, 2007 67,400 gallons Transported to Sandusky, Ohio Sewage Treatment Plant for additional sludge processing None 6 None 6
-FENOC 5501 North State Route 2 FirstEnergy Nuclear Operating Company Oak Harbor, Ohio 43449 Barty S. Allen 419-321-7676 Vice President -Nuclear Fax: 419-321-7582 January 23, 2009 L-09-006 Mr. Andrew Gall, Sewage Sludge Coordinator Ohio Environmental Protection Agency Northwest District Office 347 North Dunbridge Bowling Green, Ohio 43402
SUBJECT:
Submittal of the 2008 Annual Sludge Disposal Report for Davis-Besse Nuclear Power Station Enclosed is the Annual Sludge Disposal Report for the Davis-Besse Nuclear Power Station Sewage Treatment Facility for the 2008 calendar year. This report is submitted in accordance with the requirements of the National Pollutant Discharge Elimination System (NPDES) Permit Number 21B0001 1 *ID.There are no regulatory commitments contained in this letter. If there are any questions or if additional information is required, please contact Ms. Polly M. Boissoneault, Manager-Site Chemistry, at (419) 321-8549.Sincerely, Barry S. Allen TSC/SMC Enclosure Sewage Sludge Disposal Report 2008 for the Davis-Besse Sewage Treatment Facility (Ohio EPA Form 4229 -Two Applicable Pages)cc: Ohio E P A Central Office, Division of Surface Water Division of Surface Water Annual Sewage Sludge Report 2008 Facility name: Davis-Besse Nuclear Power Station Ohio NPDES permit #: 21B00011*ID County: Ottawa Mailing address: 5501 North State Route 2 city: Oak Harbor State: OH zip: 43449 El Mark box with an "X" if no sewage sludge has been removed from the facility for the year 2008 and proceed to instruction item No. 1, located on Page 8.Certification Statement A responsible individual* shall affix their signature to the following Certification Statement: "1 certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations".
- 5. /W ,/Z5-07 Signature i" Barry S. Allen Printed Name Site Vice President, Davis-Besse Nuclear Title Date 1.419.321.7676 Telephone* Title 40 of the Code of Federal Regulations, Part 122.22 signatory requirements:
For a corporation by a corporate officer or their duly authorized representative. For a partnership or sole proprietorship by a general partner or the proprietor or their duly authorized representative. For a municipality, State, Federal, or other public agency by either a principal executive officer or ranking elected official or their duly authorized representative. Were you inspected by U.S. EPA last year? YES__ NO X Date (if yes) / /Required to be attached if sewage sludge has been removed from the facility: o Pathogen Reduction and Vector Attraction Reduction monitoring results" Priority pollutant analysis, if performed during 2008." Summary of nuisance complaints received and corrective actions taken Ohio EPA 4229 (11/08) Page 1 of 10 Printed on Recycled Paper Click to clear all entered information (on all pages of this form) LEAR O C**EFA Division of Surface Water Annual Sewage Sludge Report 2008 Facility name: Davis-Besse Nuclear Power Station Ohio NPDES permit #: 21B0001 1 *ID County: Ottawa Table 3 -Stations 585, 586, 587, 588, and 589 Sewage Sludge Use or Disposal 70316 80991 Sewage Sludge Weight Volume (dry tons) (gallons)Incineration (Station 585)Landfill (Station 586)Other (Station 587)Transferred to Another NPDES Facility (Station 588) 109,200 PPG Lime Lakes (Station 589).Ohio EPA 4229 (11/08)Printed on Recycled Paper Page 4 of 10 "t FENOC Davis-Besse Nuclear Power Station' -501 N. State Route 2 FirstEnergy Nuclear Operating Company Oak Harbor. Ohio 43449 Januar 21, 2010 L-10-0D9 Mr. Andrew Gall, Sewage Sludge Coordinator Ohio, Environmental Protection Agency Northwest District Office 347 North Dunbridge Bowling Green, Ohio 43402 SUBJECT Submittal of the 2009 Annual Sludge Disposal Report for the Davis-Besse Nuclear Power Station Enclosed is the Annual Sludge Disposal Report for the Davis-Besse Nuclear Power Station Sewage Treatment Facility for the 2009 calendar year. This report is submitted in accordance with the requirements of the National Pollutant Discharge Elimination System (NPDES) Permit #21B00011*'ID.
- There are no regulatory commitments contained in this letter. If there are any questions or if additional information is required, please contact Mr. Stephen M. Chimo, Advanced Nuclear Specialist, at (419) 321-7149.Sincerely yours, Polly M. Boissoneault Manager, Site Chemistry KAS/SMC Enclosure Sewage Sludge Disposal Report 2009 for the Davis-Besse Sewage Treatment Facility (Ohio EPA Form 4229 -Two Applicable Pages)cc: Ohio EPA Central Office, Division of Surface Water
.JDivision of Surface Water Annual Sewage Sludge Report 2009 Facility name: Davis-Besse Nuclear Power Station Ohio NPDES permit#: 21B0001 1 *ID County: Ottawa Mailing-address: 5501 North State Route 2 city: Oak Harbor State: OH zip: 43449 El Mark box with an "X" if no sewage sludge has been removed from the facility for the year 2009.If no sewage sludge .was removed during 2009, on what date was sewage sludge last removed from the facility?Date I I If sewage sludge has never been removed from the facility, mark this box Li Certification Statement A responsible individual* shall affix their signature to the following Certification Statement: "I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete.. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations". signaturej .Date Polly M. Boissoneault 1419.321.8549 Printed Name Telephone Manager, Site Chemistry Title Title 40 of the Code of Federal Regulations, Part 122.22 signatory requirements: For a corporation by a corporate officer or their duly authorized representative. For a partnership or sole proprietorship by a general partner or the proprietor or their duly authorized representative. For a municipality, State, Federal, or other public agency by either a principal executive officer or ranking elected official or their duly authorized representative. Required to be attached if sewage sludge has been land applied/distributed: o Pathogen Reduction and Vector Attraction Reduction monitoring results o Summary of complaints received and corrective actions taken o Copies of all certification statements required by rule Ohio EPA 4229 (8/09) Page 1 of10 Printed on Recycled Paper Click to clear all entered information (on all pages of this form) CLEAR O~E~Division of Surface Water Annual Sewage Sludge Report 2009 Facility name:.. Davis-Besse Nuclear Power Stat% Ohio EPA NPDES # 21B00011 *ID Table 3 -Sewage Sludge Disposal (Alternatives to Land Appl cation)Sewage Sludge Fee Weight Dry Tons DMR Reporting Code 51129 Incineration Landfill PPG Lime Lakes If sent to landfill Name of licensed receiving landfill: Sewage Sludge Weight Sewage Sludge Volume Dry Tons Gallons ,,_ _ DMR Reporting Code 70316 DMR Reporting Code 80991 Transferred to Another NPDES Permit Holder 30,000 If transferred to another NPDES Permit Holder Name of receiving NPDES Permit Holder: Sandusky Waste Water Treatment Plant Receiving Facility's Ohio NPDES Permit Number: 2PFOOOO*MD If receiving facility is out of state, receiving facility's USEPA NDPES Number: Ohio EPA 4229 (8109)Printed on Recycled Paper Page 4 of 10 CA' FENOC Davis-Besse Nuclear Power Station5501 NV. State Roule 2 FiratEnergy Nuclear Operating Company Oak Harbor, Ohio 43449 January 25, 2011 L-11-009'Mr. Andrew Gall, Sewage Sludge Coordinator Ohio Environmental Protection Agency Northwest District Office 347 North Dunbridge Bowling Green, Ohio 43402 SUBJECT Submittal of the 2010 Annual Sludge Disposal Report for the Davis-Besse Nuclear Power Station Enclosed is the Annual Sludge Disposal Report for the Davis-Besse Nuclear Power Station Sewage Treatment Facility for the 2010 calendar year. This report is submitted in accordance with the requirements of the National Pollutant Discharge Elimination System (NPDES) Permit #211B0001 IID.There are no regulatory commitments contained in this letter. If there are any questions or if additional information is required, please contact Mr. Stephen M. Chimo, Senior Nuclear Specialist, at (419) 321-7149.Sincerely yours, Polly M. Boissoneault Manager, Site Chemistry SMC/KAS Enclosure Sewage Sludge Disposal Report 2010 for the Davis-Besse Sewage Treatment Facility (Ohio EPA Form 4229 -Two Applicable Pages)cc: Ohio EPA Central Office, Division of Surface Water PoetoEnvironmental j Protection Agency Division of Surface Water Annual Sewage Sludge Report 2010 General Information Facility name:Davis-Besse Nuclear Power Station Ohio NPDES permit No: 21B300011*ID) -[onyOtw Mailing address:5501 North State Route 2 City:Oak Harbor State:Ohio Zip:43449 DI Mark box with an "X" if no sewage sludge has been removed from the facility for the year 2010.If no sewage sludge was removed from the facility during 2010, on what date was sewage sludge last removed from the facility?Date: / I El Mark box with an "X" if sewage sludge has never been removed from the facility.Certification Statement"I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations". Sig Date Polly M. Boissoneault 1.419.321.8549 Printed Name Telephone Manager, Site Chemistry Title Form 1 EPA 4229 (10/10)Page 1 of 7 Division of Surface Water Annual Sewage Sludge Report 2010 Stations 585, 586, 588, and 589 -Sewage Sludge Disposal Facility name:Davis-Besse Nuclear Power Station Ohio NPDES permit #:21100011*ID Table 3 -Sewage Sludge Disposal Methods Sewage Sludge Fee Sewage Sludge Weight Sewage Sludge Volume Disposal Method Weight (Dry Tons) (Dry Tons) (Gallons)DMR Reporting Code DMR Reporting Code DMR Reporting Code 51129 70316 80991 Incineration (Station 585)Landfill (Station 586)Transferred to Another NPDES 35,400 Permit Holder (Station 588)PPG Lime Lakes (Station 589)If the facility is reporting with Station 586, provide the following information: Name of licensed receiving landfill: If the facility is reporting with Station 588, provide the following information: Sandusky Waste Water Treatment Plant Name of receiving NPDES permittee: 2PFOOOO*MD Receiving permittee's Ohio NPDES Permit #: If receiving permittee is located outside the State of Ohio, the receiving permittee's USEPA NPDES Permit #: Form 4 Page 4 of 7.EPA 4229 (10/10) S.0, Flrst~ner 6 othMinS AM.on Ohio 44308 1-800-646-0400 October 21, 2010 L-10-a287 Mr. Rick Zuzik Division of Surface Water Northwest District Office Ohio Environmental Protection Agency 347 North Dunbridge Road Bowling Green, Ohio 43402
Dear Mr. Rick Zuzik:
Re: National Pollutant Discharge Elimination System Permit Renewal Application Davis-Besse Nuclear Power Station, EPA ID No. OH0003786 Permit No. 21B0001 lID Enclosed are two copies of completed Form 1, Form 2C, and Form 2F applications for FirstEnergy Nuclear Generation Corp. (a subsidiary of FirstEnergy Corp.) Davis-Besse Nuclear Power Station's National Pollutant Discharge Elimination System (NPDES) permit renewal.These forms are submitted 180 days prior to expiration of the existing permit in accordance with OAC-3745-33-04. Also enclosed is check number 1374125 for $200.00 for payment of the application fee.The following are additional items pertinent to the application and/or permit renewal: 1. Samples for Storm Water Outfalls 002 and 006 have been collected and analyzed, with the results reported on Form 2F. The collection of the Outfall 005 sarnple has not occurred to date due to no flow conditions during the sampling event. Results for Outfall 005 will be reported on Form 2F Item VII when available.
- 2. The asbestos monitoring results have been below detection at Outfall 004 since quarterly sampling was initiated in September 2006. Therefore, it is requested that the monitoring for asbestos be removed from the renewal permit, and also, that the corresponding Item 0 in Part II, Other Requirements, be removed. It is also requested that the metals monitoring requirement at Outfall 004 be removed.3. Presently the pathway for the discharge of Outfall 004 is to the State Route 2 ditch, which is then pumped into the Navarre Marsh Pool #1, along with other local area storm water run-off. It is requested that the facility have the option to discharge Outfall 004 to the Navarre Marsh Pool #1. when flooding or pump maintenance is occurring to alleviate high water levels on neighboring properties.
Mr. Rick Zuzik Davis-Besse Nuclear Power Station Page 2 of 2 L-10-287 October 21, 2010 4. Sampling has indicated that dissolved oxygen is not an issue at Outfall 001. Therefore, it is requested that further sampling of dissolved oxygen be removed from the permit.If you have any questions, please contact me at (330) 384-4643.Sincerely, Scott F. Brown Senior Engineer Enclosure A: USEPA Form I for the Davis-Besse Nuclear Power Station NPDES Permit Renewal Enclosure B: USEPA Form 2C for the Davis-Besse Nuclear Power Station NPDES Permit Renewal Enclosure C: USEPA Form 2F for the Davis-Besse Nuclear Power Station NPDES Permit Renewal By UPS Ground cc w/enc: SMChimo MJJirousek KASadie DJWeber U:ACorp\EnvXEnv.OH\AII EnvXNPDES.K~mXDav~s Besse\Davis Besse CO*ver Lelter Ftnal.doa 1374125 FirstEnergy VOID IF rOT CASUMD WI1 90 DAYS Check NO. 1374125 PAY TO TREASURER STATE OF OHIO THE OHIO EPA ORDE.R OF PO BOX 1049 COLUMBUS, OH 43216-1049 JPMorgan Cbase Bank, Syracuse, NY 13206 CHECK DATE¶10Ij15oioI EXACTLY ********200 rir st~hergy Corp.50-937 213 AMOUNT 1* *****200.00)OLLARS 00 CENTS 1191371,4125sil ,:(32 L3093 791. 60 L a ?,4,8al" VENDOR ITO. 0140008749 DOC NO. 2000254364 PO NO INVOICE / RCPT # DATE DOCUMENT # VENDOR INV AMT 0H0003786 10/14/2010 1902212003 200,00 FirstEnergy NHclear -Davis-Besse NPDES Renewal REV-IEW INVOICE ACTIVITY AT 11TrPS://WWW.GPU.COM/APVWB. FOR ACCESS CALL 814-539-3200 DISCOUNT 0.00 NET AMOUNT 200.00 Hf) L-10-287 Enclosure A US EPA Form I for the Davis-Besse Nuclear Power Station NPDES Permit Renewal (3 pages follow) Please type. Do not complete by hand.FORM LAS. ENwtL4ON TA[ PROIEGTMON A YENPCy GENERAL INFORMATION 1RE P A ConsoPdaredPerýmis ram OH0003786 GENERAL tReod o iml loo" erc siarig)0 0 tA5t. rTV.S If a preprinted label has been provided, affix L EPA .D. NUMBER It In the designated space. Review the Inform-allen carefulty; It any of It Is Incorect, cross 7 -through It and enter the correct data in the ll. FACILITY NAME O oEPA does not appropriate fill-In below. Also, If any of Ohio EPtprovide labets, the preprinted data Is absent (the area to the V. FACILITY Enter this information in items 1, III, V left oflho ael space 11sis thet Inormatlon MAILING ADDRESS that should appear), please provide It in the and V1. proper fil-In area(s) below. It the label Is complele and correct, you need not complete ltems I, II1, V, and VI (except V1-B which VI. FACILITY mustbeconpletedregardless). Complet all LOCATION Items If no label has been provided. Refer to the Instructions fo, detailed item descsip-lions and for the legal authortzallons under which this data Is collected. INSTRUCTIONS: Complete A through G to determine whether you need to submit any permit application forms to tha EPA. If you answer 'yes" to any questions, you must submit this form and the supplemental form listed in the parenthesis following the queslion. Mark "X' In the box In the third column If the supplemental form Is attached. It you answer "no' to each question, you need not submit any of these forms. You may answer "no" If your activity is excluded from permit iequlcrements; see Section C of the Instructions. See also, Section D of the Instructions for deflnrt(ons of bold-faced terms.t.tARK 'X k'ARi( "X'SPECIFIC QUESTIONS MARK SPECIFIC QUESTIONS YES NO I T ", FORM A. Is this lacitity a publicly owned treatment works B. Does or will this facitity (either oxisting orpr'oposed) which results In a discharge to'waters of the U.S.? ' Include a concentrated animal feeding operation or (FORM 2A) aquatic anlantil production facility whtch results In discharge to waters of the U.S.? (FORM 2B)C. Is this a facility which currently results In discharges D. Is this a proposed tacllky (other than those desc'bedin to waters of the U.S. other than those described in A or 8 abovelwhlch will result In a discharge to Aor B above? (FORM 2C) X waters of the U.S.? (FORM 2D)E. Is this a facility which does not discharge process F. Is thIs a laclllty which o'ischarges stormwater wastoewter? (FORM 2E) X associated with Industrial activity? (FORM X X G. Do you generate sewage sludge that Is ultimately regulated by Part 503? Do you generate sewage sludge that Is sent to another facility for treatment or blending? Do you process or , derive material from sewage sludge that Is disposed In a manner subject to Part 503? (FORM 2S)I NAME OF FACILITY " Davis-Besse Nuclear Power S.tation IV. FACILITY CONTACT Chlmno, Stephen, Senior Nuclear Specialist (419) 321t -7149 V .FACILITY MAILINGADDRESS A. ST REET "OR P.O. sOX 5501 N. State Route 2 a. crf Y OR TOM 0. STATE , ZIP CODE Oak Harbor OH 43449 V1. FACILITY LOCATION15 A.. STREET, eeUTI! NO. OR 0OTHER S PECIFIC IDENTI 5501 N. State Route 2 S. COUllFrt HAJE Ottawa c. CRY on TOWN a .TY E.W11 ",ý.U Oak Harbor OH 43449 I 62 EPA Form 3510-1 (Rev. for Ohio EPA usa 2108)CONTINUE ON REVERSE Click to clear all entered Information (on both pages of this form).LE T CONTINUED FROM "[HE FRONT VIL SIC CODES (4-digat, in order..olprfofty) .P. M RST B, SECOND .. ._ '°: 0. THIIAD D. FOURTH Vill. OPERATOR INFORt A-nch NONE.. .A. B. Is the name listed In Item VIII-A also the owner?FirstEnergy Nuclear Operating Company owner? Dyes NNO 0. STATUS OF OPERATOR fwlh, .lnA, r .r.) PHONE gr od' A ID F = FEDERAL M.PUBLIC (otherthanfederalor, fate) olf)S = STATE 0= OTHER (spec6f) (800) 633 -4766 P = PRIVATE P E. STREET OR P.O. BOX 76 South Main Street -F. C TOWN l ..STAfE I. Ozip COD'E IX INDIAN LAND-F~Is facisla ity located on Indian lands?.A kron O H44 08Y .O- ]N ,, x. EXISTING ENVIRONM.ENTAL PERMITS 111 M 1 ;A NPDES D.~aac PSO todiionfto ,rpy d " s]21BOO01 I *ID 1R.UIO C ~ds E. OTHER fioafl,6)0362000091BOOl Auxiliary Boiler C. RCfA (lds m e) F. OTHER fUpetfir)0HD00 0720508~Attach to this application a topographical map of the area extending to at leas[ one mile beyond property boundaries, The map must show the outline of the facilily, the location of each of Its existing and proposed Intake and discharge structures, each of its hazardous waste treatment, .storage, or disposal faclilties, and each well where It Injects Ilulds underground. Include all springs, rivers, and other surface water bodies In the map area. See Instructions for precise requirements. XII. NATURE OF BUSINESS (provide abrief de~scrfptlon) The Davis-Besse Nuclear Power Station is a 908 (net) megawatt steam electric facility that generates electric power.XIII. CERTIFICATION .(see lnsirictions) I certify underpenally of law that I have personally examined and am famtmtlar with the Information submitted In this application and all attachments and that, based on my inquIry of those persons Immediately responsible for obtaining the Information contained In the application, I belive that the Information Is true, accurate, and complete. I am aware that there are significant penalties for submifling false Including the possibility of fine and Imprisonment, A. NAE OFFICIAL TreE (.piop.,) I.SIaNATURe C. DATE SIONED Barry S. Allen, Site V.P.- D.B. Nuclear 0 I /Y / 6 COMMENTS FOR OFFICIAL USE ONLY EPA Form 3510-1 (Rev. for Ohio EPA use 2106) la dl ,-o v 84 41'7T3C y'.7 FIrst nrgy Nuclear Operatn Copany Davis-Besse Nuclear Power Station: " I, ........................... ............ " .1.' :" ..:."':: ......... ....Refrece '~s SGS gmpohpic Maps-. Lacmmne; Ohio;.Quidranglt ,.Photo Revised 1980 S-- ..... , E Scale:,I = 2000, 35'...' .K 601%Tr:WLrlTxv rt E , 002 ,....V--~ ~ V-'--*.:.WI.N ,. ' .* 4 L-10-287 Enclosure B U.S EPA Form 20 for the Davis-Besse Nuclear Power Station NPDES Permit Renewal (69 pages follow) EPA I.D. NUMBER (copyftem Pten I of Form )0H10003786 I Form Approved.OMB No. 2040-0086. Approval expires 3-31-98.Please print or type In the unshaded areas only.FORM U.S. ENVIRONMENTAL PROTECTION AGENCY I FA EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURE OPERATIONS POESConhsofdate dPeriN/ts Program 1. OUTFALL LOCATION, A. OUTFALL NUMBER B. LATITUDE C. LONGITUDE (list) 1. DER. I MIN. 3. SEC. L DEC 2. PMI. 3. SEC. "D. RECEIVING WATER (nmne)-001 41 36 S 83' 4 10 Lake Erie 002 41 35 35 83 5 20 Pool 3-Navarre-Toussaint River 003 41 35 45 83 5 0 Pool 2-Navarre-Lake Erie 004 41 36 2 83 5 40 Pool 1-ditch-Navarre-Lake Erie 041 35 58 83 5 3 Internal to 001 1. FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIES A. Attach a line drawing showing the water flow Ihrough the facility. Indicate sources of intake water, operalions contributing wastewater to the effluent, and treatment units labeled to correspond to the more detailed descriptions In Item B. Construct a water balance on the line drawing by showing average Ifows between Intakes. operations, treatment units, and outfalls. If a water balance cannot be determined (e.g., for ceraeln mining acliilles), provide a pictorial description of thd nature and amount of any sources of water and any collection or treatment measures.B. For each outfall, provide a description of: (1) All operations contributing Wastewater to the effluent, including process wastewater, sanitary wastewater, cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment received by the wastewater. Continue on additional sheets If necessary.
- 1. OUT- 2. OPERATION(S)
CONTRIBUTING FLOW 3. TREATMENT FALL b. AVERAGE FLOW " b. UST CODES FROM NO. (/lan) a. OPERATION (list) (ircdude urtni) a. DESCRIPTION TABLE 2C-1 Cooling 7o-er elo'wdow, aritary and E33. vaporation G.eondary heat ex.chanSr.. Katen DOtinfectiOn tCheor-ne) tztmt make up demin bldg ourp, se2 I50 E-hcuane flow, dl]Utton flow, radwaste systen Discharge to suxrace Water A Area runoff, Station draing, sedicanataon (Settlng)1 002 0._______- C-ecutaden ontor ynea" d-rain tan.y Figoation H during ehutdont tiinýention (Chlorinet 2 Daicharge to Surface Water4--4-A Sc0eee S r.nh 0.22 Screeaneng SedtiNaetatinn Isettliaa 2 004 Circulating Water ayaten drain 0.0o a9d Disinfection (Chlorina) Discharge to Surface ater-A Saniary Canreacter ac Sedinentation lSettitevi 601 Sntr --e 0.02 .togalng 1-u Activated sludge 3-A Ponde 3.0 OFFICIAL USE ONLY (rift.EPA Form 3510.2C (8-90)tent guhlsdlnes j.b-cotegorlej) PAGE 1014 -CONTINUE ON REVERSE PAGE 1 0f 4-CONTINUE ON REVERSE EPA I.D. NUMBER (copyfrom ftem I ofForn 1)OH0003786 Form Approved.OMB No. 2040-0086. Approval expires 3-31-98.Please print or type In the unshaded areas only.FORM U.S. ENVIRONMENTAL PROTECTION AGENCY 2C EXISTING MANUFACTURING, COMMERCIAL, MINIOIG AND SILVICULTURE OPERATIONS NPDES Consorldialed'Permtls Program I. OUTFALL LOCATION For each outfall, list the latitude and longliude of its location to the nearest 15 seconds and the name of the receiving water.A. OUTFALL NUMBER B. LATITUDE C. LONGITUDE (list) 1. DEG. 2. MIN. 3. SEC. 1. DEG. 2.MaN. 13. SE0;. D. RECEMNG WATER (onme)602 41 35 59 83 5 5 Internal to 001 801 41 36 4 83 4 12 Intake from Lake Erie II. FLOWS. SOURCES OF POLLUTION. AND TREATMENT TECHNOLOGIES
- i. .....a ...a ...n orw, n w n a am 10 reu-lr aur. ..r..ca.e surces.or...a.e
........r..ron...n.n...n.wasrewa.. 10....r.......... ..... .. ..... ............. aun.. ..n.. unas I A. Att1ach a line dr~awig shonowg trhe water flow thiroug th~e facility, indicate sources of Intake water, operations controutung wastewater to the effuent, and treatmlent units labeled to correspond to the more detalied descriptions In Item 8, Construct a water balance on the line drawing by showing average flows between Intakes, operations, treatment units, and outlfalls. If a water balance cannot be determined (e.g,. for certaln ,mInIng activities), provide a pictorial description of the nature and amount of any sources of water end any collection or treatment measures.B. For each outfall, provide a descripon of: (1) All operations contributing wastewalter to the effluent, Including process wastewater, sanitary wastewater, cooling water, and storm water nrnoff; (2) The average flow contrIbuted by each operation; and (3) The treatment received by the wastewater. Continue on additional sheets if necessary.
- 1. OUT-FALL NO. (s,3r)2. OPERATION(S)
CONTRIBUTING FLOW I 3. TREATMENT a. OPERATION (i13t)4 .--4 602 Reneflrate Wactawate., Water Tntmt W-I~l-'tor, Station drain., Screen W. h b. LIST CODES FROM a. DESCRIPTION TABLE 2C-1 Platat ien s-Ht Sedimenrtation (Setting)1-2-K+ 4 I OdFFICIAL USE ONLY (rffluenrt gldhllnesrub.-oregortrs) EPA Form 3510O-2C (8-90)PAGE 1 of 4 CONTIINUE Ott REVERSE CONTINUED FROM THE FRONT C. Except for storm runoff, leaks, or spils, are any of the discharges described In Items II-A or B Intermltlent or seasonal?17 YES (coniptere rhe follou'ing roble) ] NO (go ro S&cnon i10)3. FREOUENCY
- 4. FLOW a. DAYS PER I... TOTAL VOLUME 2. OPERATION(s)
WEEK b. MONTHS & FLCWRATE {sagd) (sp., c.tlth wur,)1.OUTFALL CONTRIBUTING FLOW PERYEAR J. LONGTERM 2. MAXIMUM, 1, LONG TERM 2. MAXIMUM C. DURATION NUMBER fIts,) usee) (sPr'.4s1wMge) AVERAGE DAILY AVERAGE DAILY (i'seg,)002 Circulating water system drain 1 0.71 7 004 circulating water eystem drain I 0.86 7 Il.PODUCTION A. Does an effluent guideline limitation promulgated by EPA under SectIon 304 of the Clean WaterAct apply to your facility?W] YES (co,,,piere lrtem 1i/1) 0..] NO (go io Section IV)B. Are the limitations In the applicable effluent guideline expressed In terms of production (or other measure of operation)? [] YES (compfre lient 111-C) 1] NO (go to SrctI;on l)C. If you answered 'yes' to Item Ill-B, list the quantity which represents an actual measurement of your level of production, expressed In the terms and units used In the applicable effluenl guideline. and Indicate the affected outfallA.1. AVERAGE DAILY PRODUCTION
- a. QUANTITY PER DAY b. UNITS OF MEASURE c. OPERATION, PRODUCT, MATERIAL, ETC.2. AFFECTED OUTFALLS (Ilist orafoll iutsstarr)
IV. IMPROVEMENTS A. Are you novw required by any Federal, State or local authority to meet any Implementation schedule for the construction, upgrading or operations of wastewaler treatment equipment or pbacllces or any other environmental programs which may affect the discharges descn'bed In this application? ThIs includes, but is not limited to, permit conditlons, admlnlsirative or enforcement orders, enforcement compliance schedule leterm, stipulations, court orders, and grant or loan conditions. [] YES (com,,plete ltefotlorrlng table) [] NO (xo ta Iterm -B)1. IDENTIFICATION OF CONDITION.
- 2. AFFECTED OUTFALLS 4. FINAL COMPLIANCE DATE AGREEMENT, ETC. 3. BRIEF DESCRIPTION OF PROJECT a. NO. b. SOURCE OF DISCHARGE
- a. REQUIRED i PROJECTED B. OPTIONAL:
You may attach additional sheets describing any additional waler pollut~cn control programs (or other environmental projects which may affect your discharges) you now have underway or which you plan. Indicate whether each program Is now underway or planned, and indicate your actual or planned schedules for construction. E] MARK X IF DESýCRIPTION OF ADDITIONAL CONTSOL PROGRAMS IS ATTACHED EPA Form 3510-20 (8.90) PAGE 2 of 4 CONTINUE ON PAGE 3 EPA Form 3510-2C (8-90)PAGE 2 of 4 CONTINUE ON PAGE 3 I EPA I.D. NUMBER (copyfrom Item Iof Farmu 1)0 H0 003786I CONTINUED FROM PAGE 2 V. INTAKE AND EFFLUENT CHARACTERISTICS -AB, & C: See InstfUctIons before proceeding -Complete one s"ol tables for each outfall -Annotate the outfall number In the space provided.NOTE: Tables V-A. V-B. and V.C are Included on separale sheeats numbered V-1 throuoh V-9.D. Use the space below to list any of the pollutants listed In Table 2c-3 of the Instnctions, which you know or have reason to belilev Is discharged or may be discharged from any outfall. For every polutant you lIst, briefly describe the reasons you believe It to be present and report any analytical data in your possession, I. POLLUTANT
- 2. SOURCE 1. POLLUTANT
- 2. SOURCE VI. POTENTIAL DISCHARGES NOT COVERED BY ANALYSIS Is any pollutant hIsted In Item V-C a substance or a component of a substance which you currently use or manufacture as an intermedlate or final product or byproduct?
[i YES (tirall a'ch below) 17 NO (go 0o Iter W-B)EPA Form 35t0-2C (8-90)PAGE 3 of 4 CONTINUE ON REVERSE CONTINUED FROM THE FRONT VII. BIOLOGICAL TOXICITY TESTING DATA Do you have any knowledge or reason to believe that any biological tesa for acute or chronic toxIcity has been made on any of your discharges or on a receiving water In'relation to your discharge within the last 3 years?[] YES (Identif th teit(s) nd ddsc,ibe, their purposes belto) [] NO (go to Section WJL VIill.CONTRACT ANALYSIS INFORMATION-- Were any of the analyses reported In Item V performed by a contract laboratory or consulting firm?"7] YES (list the rCaere. ea e£s, ondrirleplrhone nrmrber of endppoelrorrts onalyzed by. [El NO (go to Serion LR)each such lbortoretory orfim] below)C. TELEPHONE D. POLLUTANTS ANALYZED Xe NAME B.ADDRESS (are code & no.) W(lOs)EA Group 7118 Industrial Park Blvd 440-951-3514 Organics Phenols Cyanide L, -CERTIFICATION I cerfify under penaiay of law that this document and all attachments were prepared under my cr~ectlon or supervisWon In accordance with a system designed to assure that quafilled personnel propedy gather and evaluate the Information submitted. Based on my Inquiy of the person or persons who manage the system or those persons directly responsible for gathering the Information, the Infotmation subritted Is, to the best of my knowledge and betleý true, accurate. and complete. I am aware that there are significant penaites for rubmitting false Information, Including the possib/tly of fine and ImprIsonment for knowing violations. AL NAMAE & OFFICIAL TITLE (type orprint) i B. PHONE NO. (area role & no.)Barry S. Allen, Site V.P.- D.B. Nuclear (419) 321-7676 C. SIGN D0. DATE SIGNED EPA Form 3 5 0O-24/(8-90) PAGE 4 of 4 Davis-Besse Nue. Power Station Unit No. 1 Ottawa County Oak Harbor, Ohio Intalke Crib Intake 00 MGGD NMI~ 602 M0Lake Erie Outfal ,501 Wast t Station Effluent..... (Outf 00)Toussoint River 9.PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of this Information EPA I.0. NUMBER (oa.J'from Item I I)Form 1)on,separate sheets (use the Same format) inStead of completing these pages. ]000 0003786 SEE INSTRUCTIONS. V. INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 of Form 2-C) -".-'.. " PART A -You must provide the results of at least one analysis for every pollutant in this table. Complete one table for eahloutFalL See instructions for additional Oetedil, 3. UNITS 4. INTAKE 2- EFFLUENT (sp .bfak) Copttonal).b. MAXIMUM 30 DAYVALUE c. LONG TERM AVRG. VALUE a. LONG TERM a. MAXIMUM DAILY VALUE ial able) NO. OF a. ONCEN- AVERAGEVALUE .NO."(1) " / (1)" A.NALSE TRAIO b. MASS EN- (1)b.N.F 1. POLLUTANT CONCENTRATION (2) MASS CONCENTRATION (21 MASS (1) CONCENTRATION (21 MASS ANALYSES TRATI MA SS MASS CONCENTRAT1ON I2) MASS ANALYSES a. Biochemicgl Oxygen 4.5 663.4 M5/1I kg/day x Demand (30D)b. Chemical Oxygen Demand (COD) 20.8 3066.6 1 mg/i kg/day 0. Total Organic Carbon 5.73 844.8 1 mg/l kg/day (TOC) 5.73_8__.8__
- d. Total Suspended Solds (7"$s) I 5m/1 k9/day x e. Ammonia (as N) e0.1 -- 1 Mg/i kg/day VALUE VALUE VALUE VALUE f. Flow 38.9 24 mgd kg/day g. Temperature VALUE VALUE VALUE VALUE (,iner)h. Temperature VALUE VALUE VALUE VALUF (smme) 25.4 4 "C MINIMUM 8.20 MAXIMUM .MINIMUM MAXIMUM ...... .LpN8.0 .27. '~~I STANDARDOUNITS PART B- Mork "X" in column 2-a for each pollutant you know or have reason to belicve is present Mark"X In column 2-b for each pollutant you believe to be absent If you mark column.2a for any potlutant'which'is limited either directly, or lindirectly but expressly, in an effluent limitations guldeline, you must provide the results of at least one analysis for that pollutant For other pollutants for whlch you mark column 20. you must provide t.ntltntitwh, n svmLn.ssftinn ,nf hoir I, unirr di~ch.-rrrt.
fmnltP nne" tabe for S'ep tire lrve;trum~ors for rrdditinnsl, derails and reaulrirnentr_ 2, MARKX" 3. EFFLUENT 4.,UNITS S. INTAKE (aploral 1. POLLUTANT
- b. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE a. LONG TERM AVERAGE AND 80.MAXIMUM DAILY VALUE W-M614dlI.O a.COe)N VALUE .OF CAS NO. BELIEVED SELIEVED -(. I d. NO. OF a. CONCEN- (t) b. NO. OF (Irf-,ailable)
PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION 121 MASS ANALYSES a. Bromide X 0.389 57.4-(24959-67-9) 1 Mg/1 kg/dy .b. Chlorine. Total .<0t0s -Mg/i kg/dy Residual " c-Color X 10 -- 1 Units d. Fecal Coltorr )X 19.5 -- 4 perlO0ml (.-Fluoride 0.252 36.6 1 mg/i kg/dy (698"4M.) X __262_38.r.Nitrate-Mt1.te 277.2 mg/i kg/dyM _Ls 9/ EPA Form 3510-2C (8-90)PAGE V-1 CONTINUE ON REVERSE ITEM V-3 CONTINUED FROM FRONT 2, MARK=X 3. EFFLUENT 4. UNITS 5. INTAKE (optlonol)
- 1. POLLUTANT
- b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM AND a. b. a. MAXIMUM DAILY VALUE (,'afoifoblh) vai-l able) AVERAGE VALUE GAS NO. BELIEVED BELIEVED (1) (1) (1) ri. NO. OF a. CONCEN- (1) b. NO. OF PRESENT ABSNNT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSES C. Nitrogen.Total Organic (as <0.2 I- -mg/i kg/dy x h-rOil and <5.0 -- 4 mg/i kg/dy Grease I. Phosphonu
., (as P). ToW 0.136 20.1 1ag/1 kg/dy (77W-14-0). .1 Radloactivity (1) Alpha, Total (2) Bota. Total (3) Radium, Total (4) Radium 226.Total Ik. Sulfate (.30.) 49.6 7312.6 mg/1 kg/dy (14808-79-8) L x <i0 -- 1 mg/i kg/dy m. Sulfilto (aS <15 -- 1 mg/i kg/dy (14265-45-3) x _ ____n. Surfactants x 0.006 0.885 1 mg/1 kg/dy o. Aluminum.Total342 5 41 Ug/1 kg/du x (7429-0-5)
- p. Barium, Total 447 (7440-30-3) x 41 6.04 1 ug/i kg/dy q. Boron, Total (7440-42-8) x <75 -- 1 ug/1 kg/dy r. CobalLt Total (744D4-4.4) x -<1.0 --I g k/l a. It X 397 58.5 .ug/1 kg/dy x t Magnesium.
Toal 17024 2509.9 1 ug/i kg/dy u. Motybdonum, Total <2.0 -- .ug/l kg/dy (7439-S,-7) x v. Manganese, Total X 1B 2.7 1 Ug/i. kg/dy X 0 -- 2. ug/2. kg/dy v.T"in, Total (7440-31-5) ______ <4.0__ _____ I___ ______ kci /x. Titanlum, Total 8 X 3.0 0.44 1 uS/1 kg/dy ('7440-32-6) EPA Form 3510-2C (8-90)PAGE V-2 CONTINUE ON PAGE V-3 0. 0.EPA I.D. NUMBER (copyfro,/;h-m I ofF,-r 1) OUTFALL NUMBER OH0003786 001 CONTINUED FROM PAGE 3 OF FORM 2-C PART C -if you are a primary industry and this outfall contains process wastewater, refer to Table 2-2 in the instructions to determine which of the GC/MS fractions you must testYor. Mark "Xý in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phendlls. If you are not required to mark column 2-a (secondary industries, nonprocess wastewateroufalls, and nonrequired GC/MS Ytsctions). mark "X' in column 2-b for each pollutant you know or have reason to believe Is present Mark "X7 in column 2-c for each pollutant you believe is absent. If you mark column 2a for any poautant. you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant you must provide the results of at least one analysis for that pollutant if you know or have reason to believe It wilt be discharged In concentrations of 10 ppb or greater. If you mark column 2b for acrolein. acrylonltr2e. 2,4 dinlfrophenol, or 2-rmethyl-". 6 dinitrophenol. you must provide the results of at least one anaeysia for each of these pollutants which you know or have reason to believe that you discharge In concentrations of 1 aD ppb or greater. Otherwise, for pollutants for which you mark column 2b, you must either submit at least one analysis or briefly describe the reasons the pollutant Is expected to be discharged. Note that there are 7 pages to this part'. please review each carefully. Complete one table (all 7 pages) for each outfall. See Instructions for additional details and requirements.
- 2. MARK"X 3. EFFLUENT I 4. UNiTS I 5. INTAKE (aorlanali
- 4. UNITS 1 5. INTAKE (oprlonaýI. POLLUTANT
- b. MAXIMUM 30 DAYVALUE c.LONG TERM AVRG. a. LONG TERM AND b. c a. MAXIMUM DAILY VALUE (1favailable)
VALUE (If aailable) AVERAGE VALUE CAS NUMBER TES'LNG BELUEVED BELIEVED .i) Ii) (1) d. NO. OF a. CONCEN- (t) b. NO. OF (if avilable) D REQUIRED PRESENT ABSENT CONCENTRATION
- 2) MASS CONCENTRATION (2) MASS CONCENTRATION
- 12) MASS ANALYSE TRATION b. S CONCENTRATION (2)2) MASS ANALYSES METALS, CYANIDE. AND TOTAL PHENOLS 1M.Antimony.Total
<8.0 - ,g/ kg/day (7440-36i-0) --8.0__ _____gda M" Arsenic Total <10 -- ug/1 kg/day (7440-38-2) _ I 3M. Beryllurn, Total < .0 --(7440-41-7) <1 Ug/. kg/day 4M. Cadmium, Total <I0 -- 1 Ug/1 kg/day (744N.43-9) , * ...... 0.......Ik 5M. Chromium, <1. 0 1 ug/ kg/da.r Total (7440-47-3) SM. Copper. Total0 (744D-50-8) X 6.0 O.88 i uS/ k9/day x 7M. Lead. Total 7 (7439-92-1) 7.0 1.03 1 ug/1 kg/day x SM. Mercury. Total 02 1 (7439-97-6) 0.2 -ug/1 kg/day 9M.ke.Tota ...K <40 -- o t./a kg/d (7440-02-0) X__ <4___ .___ 0__ US/)-k9/__ 'IOM. Selenium, 28 4.1 1 u9/. kg/day Total (7782-49-2)
- 2. I/ /I1IM. Silver. Total ...0.. .(7440-22-4)
X </. k -"/: g9/day 12M. Thallium, Total (7440-28-0) 27 2.98 13M. Zinc, Total 9.0 1.33 7440-65-6) X ug/1 kg/day 14M. Cyanide, Total (57-12-5) X <0.005 -4 m9/1 k/day 1SM. PhenoLs, Total <504Xgi k/a DIOXIN 2,3.7.8-Teira-DESCRIBE RESULTS chlorodibenz(-P-Doxain (11764-01-6) EPA Form 3510-20 (8-90).PAGEV-3 CON71NUE ON REVERSE CONTINUED FROM THE FRONT 2- MARK *X" 3. EFFLUENT 4. UNITS 5. INTAKE (opod ' I'1. POLLUTANT
- b. MAXIMUM 30 DAY VALUE Q. LONG TERM AVRG. a. LONG TERM AND .b. c, a. MAXIMUM DAILY VALUE (Wf-cJlabic)
VALUE (W-fa110abfe) AVERAGE VALUE CAS NUMBER TESTING BEUEVED 3F_,,./50 ( I (1) I "1) d. NO. OF a. CONCEN- (1) b. NO. OF (/f.avolablo) REQUIRED PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION
- 12) MASS CONCENTRA1ION
- 12) MASS ANALYSES TRATION b. MASS ANALYSES GCIMS FRACTION -VOLATILE COMPOUNDS (1.0 702-)x <25 -- 2 ug/h kg/day 2V. Acylonibile2 (107-13-1) x <25 -ug/l kg/dy 3V. Benzon¢(71-43-2) x <5.0 -- 3 ug/! kg/day 4V. Sla (Chor-".,.o-vM Elher <5.0 -.- ug/l kg/day (542-88-1)
........ ..... _5V. Bromoforn ugh kg/day (75-25.2) <5.0 WV. Carbon Tobochlodo <5.0 -- 2 ug/1 kg/day (56-23-5)7V. Chlorobenzene <5.0 -- 2 ug/2 kg/day (10-9C0.7) x BV. Chlorodi-bromomeIIha~ <5.0 -- 1 ug/l kg/day 9V. Chloroothane (75-00-3) x <5 .0 2. ug/I kg/day 0V. 2-Chloro-eWnyl Ether <5o 2. ug/2 kg/cay (110o-75") 11v.Chiooform i67-66-3) x -r<5.0 -- 2 ug/1 kg/day 12V. Dichloro-bromomethane <5.0 -- 2 ug/h kg/day (75-27-4) x 13V. Dichloro-drnuoromethane <5.0 -- 2 ug/1 kg/day (7&-71-8)x <14V. 1,1-0D1cloro-ethane (75-34-3) x <5.0 -- 2 ug/! kg/day 15V. 1 ,.2-Dlcloro-ethane (107.0&2) x <5.0 -- .ug/1 kg/day i6v.1 6V.<5.0 -- 1 ug/2 kg/day ethylene (75-35-4) _ <5_0_a.____________ i7V. 1.2-Dlchloro-propane (78-87-S) X <5.0 -- 2. ug/)l kg/day ISV. 1.3-Dichloro-propylen¢ <5.0 -- 1 ug/2. kg/day (542-75) -19v. Ethylbcnzene <5.0 -(100-41-4) x < ug/2 kg/day 20V. Methyl Bromide (74-83-9)21V. Methyl <5.0 I- ug'2/l kg/day Chlordde (74-87-31 ..0..-EPA Form 3510-2C (8-90)PAGE V-.4 CONTINUE ON PAGE V-5 0. 0:ONTINUED FROM PAGE V.-4 0.1 2- MARK X° I 3. EFFLUENT 4. UNITS 5. INTAKE (opijono) .1. POLLUTANT
- b. MAXIMUM 30 DAYVALUE .. LONG TERM AVRG. a. LONG TERM AND a. b .n. a.MAXIMUM DAILY VALUE (If , allobte) VALUE (If'-pJablbe)
AVERAGE VALUE..S.UM B..... ..... ..B U S Y O ( ) d N O , O F a .C O N C E N -" i) b .N O .O F CAS NUMBER "RSUIRNG BPRIVEDS ASEET EMNT(RATION SE TRATION .NCENT ALY REQUIRED PRE:SENT ABSENT ICONCEN(ITýAO (2 AS OO 2) MASS CONCENTA( INLSS RTO b. MASS (ONC)TPTION/ ANALY2E GC/MS FRACTION -VOLATILE COMPOUNDS (canthnned) ZZ.Methylene Mloie Xe < S. 0 1 ug/1 kg/day Chlo14e (7Z5-09-2) ___________ 23V. 1,1.2.2-TetChloethane .<5.0 1 ug/I kg/day 24V/. TetrachlOro- %ethylene (2I-.8-4)' <5.0 1 ug/1 kg/day etJhylene (127.-18-4) ___25V. Toluene <5. 0 1 Ug/l kg/day (108-88-3) x 26V. 1.2-Trans-Dl0chloroethylene x <5.0 1 Ug/! kg/day 27V. 1.1.1.TtChIoro-ethane ('71-5-6)_ x <5.0 1 Ug/h kg/day 8. 1.2-TacHoro-x A <5.0 1 ug/1 kg/day ZBVr1h~le.r.0-15 <5. 0 1 ug/1 kg/day 29V Trc"'0orO-30V. Trichloto-fluAete <5.0 I ug/l kg/day 31NW. Vinyl Chldore * <s. 01 Ug/1 k/(75ý0 1-4) k g / ....GC(MS FRACTION -ACID COMPOUNDS IA. 2-Chlorophenol X <10 1 ri/i kg/day 2A. 2-4-DIcbilo*. 2 ug/l kg/day phenmol (120-83-2) <10 3A. 2.4-Dlmethyl-phenol (105-67-9) <10 1 ug/1 kg/dy 4A. 4,6-DnlUo-O-l Cre301(534-52-1). <50 1 ug/1 kg/day 5A.X2,4Dfrmitrc-6 <50 1 ug/ kg/day p h e n o l (5 1- 2 S8 -5 ) .....6A. 2-Nitrophenol <10 1 ug/1 kg/day (88-75-5)7A._4-Nitrophenol \ <50 (1000-2-7) X <50 I ug/1 kg/day 8A. P-.ChorO-M-Cro) (5S-30-7) <i0 1 ug/1 kg/day 9A. Penachleto-X <50 1 ug/1 kg/day phenol (87..88-S) 10A.Phenol X <1 0 1 ughl kg/day X <10 1 ug/1 kg/day ph.nol (88-05-2) .....EPA Form 351 C-2C (8-90)PAGE V-5 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2. MARK "X" 3. EFFLUENT 4. UNITS 5. INTAKE (opfiol)1. POLLUTANT
- b. MAXIMUM 30 DAYVALUE c. LONG TERM AVRG. a. LONG TERM AND ). b. I. .MAXIMUM DAILY VALUE (if-,iliaJble)
-VALUE (Qf-,-1abkc) AVERAGEVALUE CAS NUMBER TESTING BEUEVED BELIEVED -I ' f (1) d. NO. OF a. CONCEN) b. NO. OF ({fivc/1iabf) REQUIRED PRESENT ASENT CONCENTRATION I CONCENTRAT ION (2) MASS -CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSES GO/MS FRACTION -BASE/NEUTRAL COMPOUNDS 19B. Acoaphtliere 2B. Aconaph-tylena
- 39. AAttvaoenc (120-12-7)
- 49. acnzlIdInc (92-87-5)
_ _SE. Eenzo (0)Anthracerie (565.553)_ _65t. Oen7c (al)Pyrenc (50-32-S) ____ ____TB. S,4E8etzo-fluorantlelie (205.90.2) _______ ____________ 8B. Eerizo (rfi,)perylene 11.42 6B. eenzo (k)Fluoraethene (207-08-9) ____108. 8i (-Ci/e cihoxy) Methane 1113. Ble (2-C/i/ore-(111-44-4) _____ __________________ _____________ 129. Eis (2.chlaoplsoprepyl Either (102-80-1) ___ ___ ___ _____________ 138. 9SS (2-Edn'I.149. 4-Eromophenyl Phenyl Ethier 1(101-55-3) 1_______ ____158. Buryl Beneyl Phlhalate (85-68.7)16S. 2-Chloro-naphthalene 178. 4-Chloro-phenyl Phenyl Ether (7005.72-3) ____________ I188. Chrysene (218-01-9) Antttracene (53-7".)208. 1 .Z-0chloro-bertzcrte (95.50-1) _______ ____ _______219B. 1 .3.OI1cAOf. benzene (541.73-1) ____________________________ EPA Form 3510-2C (8-90)PAGE V-6-CONTINIJE ON PAGE V-7'0 0 CONTINUED FROM PAGE V-6 0.2- MARKX. .3. EFFLUENT 4. UNITS 5. INTAKE (ophaowo)1. POLLUTANT
- b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. o. LONG TERM AND 0. b, C, a. MAXIMUM DAILY VALUE * (Ifailoie)
VALUE (If il able) AVERAGE VALUE GAS NUMBER TEsTnNG BESUEVED SEUSEVED (1) )1) d. NO. OF a. CONCEN- (1) b. NO. OF (iý/aflable) REQUIRED PRESENT ASSENT CONCENTRAION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CON cz MASS ANALYSES GCJMS FRACTION -BASEINEUTRAL COMPOUNDS (cowidae-) 226. 1,4-OIOhlI~ot benzene (10S-46-7) 23B. 3,3,-Dlchloro.- benzJdine (91-94-1)248. Olethyl Phthalato (84-66-2) _25B. Dimrethyl Phtholate (131-11.3) 26B. DI-N-Butyl Phthalate (84-74-2)276.2,4-Olnltro-toluene (121:-14.-2) 286. 2.6-DInltro-toluene (606&20-2) 298. Dl--Octyl Phthlatro (117-84-0) 30& 1.2-Dlphenyl-hydrazine (as AmO-benzene) (122-66-7) 318. (206-44-0) 32B. Fluoreno (8r-73.7)_____ __331. Hexachloro-benzene (118-74-1) 346. Hexachloro-butadiene (87-68-3)35B. H etachioer-cyclopentadleno (77-47-4)36B HeXachloro-ethane (67-72-1)37B. Indeno (l2.3-cd) Pyrone (193-39-S). 386. I3ophorone' Ct8-39-1) ____39S. Naphthalene 9(1-20.3)403. Nitrobonzene (98-95-3)41B. N-Nltio-oodlmethylamrrno (62-75-9) ______42B. N-Nitrosodi-N-PropyIamlne (621-64-7) EPA Form 3510-2C (8-20)PAGE V4-7 CONTINUE ON REVERSE CONTINUED FROM THE FRONT I 2. MARKWX" 3. EIFLUENT 4. UNITS I 5. INTAKE (o:kt,,,aII
- 4. UN 1 5. INTAKE (-tknol)1. POLLUTANT F b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a: LONG TERM AND .b. r- a. MAXIMUM C)/JLY VALUF.. (IfowIL~ble)
VALUE (Ifm~alloUL) AVE.RAGE.VALU I-CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d. NO. OF a. CONCEN- (2) b. NO. OF (I4frovaIh!z) REQUIRED PRESENT ABSENT CONCENTRATION 1 (2) MASS C2) MASS OON.0BNTRATIDN (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS IANALYSE GC/MS FRACTION -BASE/NEUTRAL COMPOUNDS (confinued) 4313. N-Nltro-sodliphenylarflifl 226-30-6) ________' 448. Phanathrene 45B. Pyrene (12-00-0)__ _ _ _ _ _ _ __ __ _ _46B. 1.2.4-TtI-chloroben-nol (120-a2-1) ___ ______ ___ ______ ____GC/MS FRACTION -PESTICIDES__________ I P. A~drin (:309-00-2) ___ _____2P. a-BHC (210-84.6) 3P. ý-BHC ,(3139-8-5-7) 4P. y-8HC 5?.&8BHC (3196-86) ________ ___ ____GOP. Chlordanle (57-74-9) ____________ ____7?. 4.4!-DDT (50-2&-2)SP'. 4.4'-DOE (72-55-9) ______ _______ ______9OP. 4.4'-DDD)(72-S4-8)1lOP. DiIdnidi li.m-EflosU26 (115-29-7) __ ___________ ____12P. ý-Endosulfan (115-29:-7) ____ ____________ ___________ 13P. Endosulfan Sulfate (1031-07-M)_______ 14P. Edrifti (72-20-8) ____ ____ ____ _____________ ____ ______________ 15?P. Enddr%(7421-83-4 A(742-93-4 16P. Heptochlor I 78-44-8)__________ ___ __EPA Form 3510-2C (8-90)PAGE V-8 CONTINUE ON PAGE V-9 0i 0 0.EPA .D. NUMBER (copyfroi,- lIofFon,, 1) OUTFALL NUMBER 0H0003786 001 CONTINUED FROM PAGE V-8 2. MARKIX" 3. EFFLUENT 4. UNITS 5. INTAKE (Wpik.no,)
- 1. POLLUTANT J .MAXIMUM 30 DAY VALUE Q. LONG TERM AVRG. a. LONG TERM AND a. a. .MAXJMUM DAILY VALUE (If available)
VALUE ((f availablc) AVERAGE VALUE CAS NUMBER TESTING BEUEVED BELIEVED (1)d. NO. OF a. CONCEN- b. NO. OF lab) RQUIRE RE ABSENT CONCENTRATON (2) MASS CONC RATION (2 MASS CONCENTRATION ( 2) A Y TRATON b. MASSI CONCENTRATION (Z) MASS ANALYSES GCJMS FRAcTION -PESTICIDES (eotI) _ _17P. Heptachior Epoxlda (1024-57-3) 18P. PCB-1242 (53469-21-,9) 1 9P. PCB-1 254 (11097-89-1) 20P. P C.3-A221 (11104-28-2) 21P. PCB-1232n (11141-16-5) 22P. PCB-1248 (12872-29-2) 23P. PCB-1260 (11096-82-5) 24P. PCB-1016 (12874-11-2) _______25P. Toxaphene (8001-35-2) EPA Form 3510-2C (Eý-90)PAGE V-9 PLEASEPRINTOR TYPE NTHEUNSHADEDAREbAS.ONLY. YmaXIou DrtsmeraY oVfthisLInf-atLonn EPAVI.. VNUMBER (ca..LNomGt TEoMFarm]) on separate sheeM (use the Lame forat instead of completing theLe paoges SEE( NSTRUaTIONS.
- . a. C*NE-NO 0 V. LNTAKE AND EFFLUENT CHARACTERISTNCS (conA1nued from page 3 of Form 2-CN) ONTAAL YSES PART A-You must provide the results of at least one analysls for every pollutant in thi table. Cornplete one table for e.ach outlaJI. See instbutdans for additional detalls. " 3. UNITS 4. INTAKE a. Bloc, hemical Oxcygen <30-1 m/i k/ y Demand (SOD)EFFLUENT 1 l (000-1y b. Chemical Oxygen 22.7 3. I mg/i kg/day Demand (COD)b.Deman I (Oxyge 22.7 33.7 1 rag/1 kg/day c. Total Organic Carbon 474 704 1 Mg/i kg/day (Too .4 70 /l k/ y Id. Total Suspended Solids (7" n 15 22.3 1 mg/i kg/day x e. Ammonia (asaM 0.3 0.45 1 mg/i kg/day VALUE VALUE VALUE VALUE f. Row 0.392 24 Uog/ kg/day S. Temperature VALUE VALUE VALUE VALUE (wi i ,) -0 h. Temperature M VALUE3D VLVRG. VAE a. LN E A GVALUE (245,5.) 234 mg" kgd MINIMUM MAXIMUM IM]INMUM IMAXIMUM L YT.pH 7 STANDARD UNITS 7. C.lor.....
...kg/d..PARTSB- Mark X" in column 2.-a for each pollutant you know or have reason to believe is present. Mark "X" in column 2-b for each pollutant you believe to be absent, If you mark col~mn 2a for any pollutant "qhlch is limited either directly. or indirectly but expressly, in an effluent Ilmitations guideline, you must provide the resuits of at least one analysis for that pollutant For other pollutants for which you mark coiumnn 2a, you must provide quantitative data or an explanation of their Presenc~e in your dftcharge. Complete one table for each outfall. See the instruct~ons,.for additional details and requirements. ., 1. 2. MARKX" 3. EFFLUENT 4. UNITS 5. INTAKE (optional) 1.PCLTN b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE I15LN TR VRAE ..AND a. b. a. MAXIMUM DAILYVALUE 6(anm~leb (i,/-nollabte) VALUE CAS'NO. SELIED BELIEVED 1 1)( d. NO. OF a. CONCEN- 0i) b. NO. OF.(Jfmv fbble) PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TPATION to, MASS CONCEN-fRATrION MS ANALYSES a. Br4mide (2495"7.9) X <X0. 03 01 1 Mg/1 kg/dy b. Chlorine, TotNIl 0 mg/i kg/dy Resdual <00 I-4 m/ c.Color X 5 1 unlits kg/dy d. Fecal Colfom X 147.8 --4 perlO Orl kg/dy e Fluoride 0.21. 0.31! 1 .mg/1 kg/dy f. Nl~trat-Nlitr i 1 (as v)I 0.36 0.53 1 kg/dy EPA Form 3510-2C (8-90) PAGE V-1 CONTINUE ON REVERSE 0 0.ITEM V-6 CONTINUED FROM FRONT 2, MARK1X' 3. EFFLUENT r 4. UNITS 5. INTAKE (oprion'l)
- i. POLLUTANT B 8b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM AND a. b, a. MAXIMUM DAILY VALUE (ifrailabir)
Qvtobk) AVERAGE VALUE CAS NO. BE 0 EIEVED(1)
- d. NO. OF a. CONCEN- -b. NO. OF (fovaI/c)
PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSES Tota Organlc (x 0.39 0.5B 1 rmg/! kqrdy x In. Oil and " Grease x <5.0 -- 4 mg/i kg/dy L Phosphorus (as P).Tolal 0.06 0.08 1 mg/i kg/dy x 1. Radioactivity (1) Alpha, Total (2) Beta. Total (4) Radium, Total (4) Radium 226, k. Sulfate (-.so) 76.8 114.1 1 mrg/i kg/dy (14-80&7"4)
- 7. 1x4.1. Sulfide (= S X <10 I mg/i kg/dy m. Sulfite (-s SO,) X <15 -- I mg/i kg/dy (14265-45-3) x n. Surfuctants x 0.005 0.0 07 1 mg/1 kg/dy x o. Aluminum, Total 275 041 ug/1 kg/dtz x (7429-90-5) 2 p. Barium. Total 34., (7440-39-3) 7v 3 0 0.04 1 ug/, kg/dy_q. Boron, Total (744D-42-8
<75 -- 1 ug/i kg/dy r. Cobalt, Total Ig/i kg/dy ,(7440-48-4) <1.0 -- _u ./S Iro 9 n, Total 278 0.41 1 ug/1 kg/dy x L Magno.sium, T n2713 18.89 1 ug/i kg/dy (743-9-95-4) 1 LL Molybdenium. Total X <2.0 -- 1 ug/i kg/dy (7439-98-7) x Manganese, X2 .Total X 6 0.04 1 ug/1 kg/dy 1(743&).-s
- x. Tiotai (7440-31-5)]
X 6 0.01 1 ug/ 1, kg/dy-Total 1.0 .C 0 1 ug/1 kg/dy x (744D-32-6) ...EPA Form 3510-2C (8-90)PAG EV-2 CONTINUE ON PAGE V-3 EPA LD. NUMBER (cop),fromf q 1 efFortn 1) OUTFALL NUMBER 0H0003786 002 I'CONTINUED FROM PAGE 3 OF FORM 2-C PART C -If you are a primary industry and this ouffall contains process wastewater, refer to Table 2c-2 In the Instructions to detenrine which of the GCIMS fractions you must test for. Mark 'X" in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals. cyanides, and total phenols. If you are not required to mark column 2-a (secondary lndustnies. wasewater ou'fa//s. and nonrequired GC/MS fractions), mark *X" in column 2-b for each pollutant you know or have reason to believe Is present. Mark X in column 2-c for each pollutant you believe is absent If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant if you know or have reason to believe It Will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrolein. acrylonitrile, 2,4 dinitrophenol, or 2-methyl-4. 6 dinitophenol, you must provide the results of st least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b, you must either submit at least one analysis or briefly deScribe the reasons the pollutant Is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table(a/l 7 pages) for each outfalL See Instructions for additional details and requirements. 2- MARK-X" 3. EFFLUENT I 4. UNITS 5. INTAKE rno'lonai)
- 4. UNIT$I. POLLUTANT
- b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND a. b. a. MAXIMUM DAILY VALUE (ifuailoblc)
VALUE (QovoiI able) AVERAGEVALUE GAS NUMBER TESTING BELUEVED BELIEVED (1) 11 I d. NO. OF a. CONCEN- bii I. NO. OF (fcvallabln) REQUIREC PRESENT ABSENT CONCENTRATION 1 12) MASS CONCENTRATION 1 (2) MASS CONCENTRATION 121 MASS ANALYSES TRATION b. MASS CONCINTRATION 121 MASS NALYSES NAFTAI 51 rtVANI[%I:: ANt' TflTAI PHFNrII 5;IM. Antimony, Total .8.1 1 kG/dy C7440-36-0) IIIIIII 2M.ANacalc. Total x<a:0 -.- 1 g kg/day (7440-36-2) _5___1_1_3-M. Bcnyrium, Total '-X <1.0 1 Ug/1 k9/day (7440.41-7) 1" -4M. Cadmium, Total X <i0 1 ,ug/1 kg/day (7 D-43,-9)SM. Chromiun. <1. 0 1 ug!1 kg/ day Total (7440-47-3) .6M. Copper. Total X4.0 1 u9/1 kg/day (7439.SO-9l-_) <_._ __--_ _ __ /_ k _/7M. Lead. To~al X 5.0 0.01 1 ug/l kg/day x.OK. Mercuy. Total <0.2 -- 1 'ug/1 kg/day (7430-97-6) SM. Nickel, Total <4. 0 -- 1' ug9/ kg/day (7440-02-0) X 1DM. Selenium, 17 0.03 x Ug/1 k9/day Total (7782-4.-2) X 0 .I 11 M. Sliver, Total <>. 0 -- 1 Ug/1 kg/day (7440-22-4) X__0 __Ik_12M. Thallium, 1 kg/day X Total=7440-280) 17 0.03 ug/1 13M. Zinc. Total 1 ug/2 kg/day X (7440-66-6) X14 0.02 14M. Cyanide.Total (57-12-5) X <0. 05 -- .mgl kg/day SMt Phenols. <.0 -- 4 Ug/1 kg/day Total..., DIOXIN 2.3.7,8-Tetra-. DESCRIBE RESULTS chllrodibenzo-P-Doioan (1764-01-6 EPA Form 3510-2C (8-90)PAGE V-3 CONTINUE ON REVERSE 0 0.CONTINUED FROM THE FRONT 2. MARK"X" 3. EFFLUENT 4. UNITS 5. INTAKE (opflonci" 1. POLLUTANT
- b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND a. b. e. a. MAXI MUM DAILY VALUE (if-0J1ob1c)
VALUE (i, avllao&,) AVERAGE VALUE CAS NUMBER TESTING BEUVEDVBEEUEVED " e1 e1 d. NO. OF a. CONCEN- ý ' b. NO. OF (f av&Aolbf) REQUIRED .PRESENT ABETCONCENTRA'iON (2) MASS CONcENTRAION (2) MASS CONCENTRATION (2) M AA LYS E TRTON b. MASS ICONCENTRATION (21 MASS NALYSE GC/MS FRACTION-VOLATILE COMPOUNDS iV. Accrolel5 (107-02-8) 1 1 g/ kg/dy 2V.Aryionlotrile (107-13-1) x<2 -- 1 ug/h kg/day 3V. Benzene (71-43-2) x <5.0 -- 1 ug/l ks/day 4V. 8Et (Chibe.-.cihy EthV <5.0 -- 1 Ug/1 kg/day (542$88-1) x SV, Bromofoarn 0 75-25-2) <5.0 -- 1 ug/1 kg/day 5V. Carbon TeO-achlorlde %Ttahrie<S.D0 -- 1 ug/1 kg/day (55-2:3-5) _____TV. Chlorobenazene (IO8Sg-7/ <5.0 1-l ug/1 kg/day 8v. Chlorodl-bromomethale 105.0 -- '1 0 u/1 kg/day (124-48-)9V. Chloroetr]ano (75-00-3) x <5.0 --_ug/1 kg/day ioV. 2-Chloro-(y11 (.lEO.)r x5.0 -- 1 ug/1 kg/day (110-75-8) ....... ....______________________ _______ _____11V. Chloroform (67-_6-3) x <5.0 -- 1 ug/1 kg/day 12V. Dichloro-bromomethane <5.0 -- 1 Ug/l kg/day (75-27-4)13V. Dichioro-diuoromthane <5.0 -- 1 u0/1 kg/day (75-71-8) x ______ ug/_______ 14V. I1,-Dlchlor-/ ethane (75-34-3) /N. 0S-D 1 U0/1 kg/day 15V, 1.2-Dlchioro-ethane (107-0452) x <5.0 -a- ug/1 kg/day 16V. 1.1-DIohloro-oiiylene (75-35-4) x <5, 0 -1 ug/ ky/d'ay 17V. 1,2-DI¢.,hioro-ppne (78-87-5)- <5.0 -- 1 ug/I kg/day 18V. 13-Dicrhloro- .g /propylenre <5.0 -- 1 ug/1 kg/day (542-75-6) -19V. Ethyibg nr, nt I 0 tý41-4) x <5 .0 -- 1 ug/1 kg/day 2OV. Methyl Bromlde (74-83-4) __ 5.0 , j 21V. Methyl 0 1 ug/I kg/day Chloride (74-87-3) 50 -EPA Form 351 Q-2C ("0)PAGE V.-4 CONTINUE ON PAGE V-5 cONwNUED FROM PAGEV.-4 2. MARKX" 3. EFFLUENT 4. UNITS 5. INTAKE (opilon.a)
- 1. POLLUTANT
- b. MAXIMUM 30 DAY VALUE c LONG TERM AVRG. a. LONG TERM AND a. b. -a. MAXIMUM DAILY VALUE VALUE (if AVERAGE VALUE CAS NUMBER TESiING BEUEVED BEUEV*ED (1) (i){(1) a. CONCEN- b. NO. OF (ifavafiable)
REQUIRED PRESENT ABSENT CONCENTRATION
- 2) MASS I CONCENTRATION 1 (2) MASSI CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATIONI (2 MA-S NALYSES GO/MS FRACTION -VOLATILE COMPOUNDS (coniwtid)
-ethylene <5.0 -- ug/1 kg/day Chlorda (75&09-2)23V. 1.1 a2-.2thane <5.0 -- 1 ug/! kg/day 24V. Tetrachloro-ethylene (127-18-4) -1 uql) kg/day 25V.Toluene 5 I (i OE-8&3) <5.0 -- 1 Ug/ kg/day 26V. 1,2-Trans-Oichitoethylene <5.0 -- 1 us/I kg/day (156-60-5) 1 x _____27V. 1,1.1-Trichlorc-kgd" ethane .\ <5.0 -- 1 uS/I kg/day 28V. 1.1.2.Trtchloro- <5.0 -- 1 U/ kg/day ethane (79-00-5) I 25V Tfthloro. <5.0 -- 1 ug/l kg/day ethylene (79-01-6) x 30V. Trichloro. lluommethznI ' < 5. -- 1 ug/1 kg/day 31V.\Aiyl Chliolde <5.0 -- "1 U/. k/ay C75-01-4)GC/MS FRACTION-ACID COMPOUNDS IA. 2-Chlorophenol. .k/9-Z-h7-8 x <10 -- I ug/1 kg/day.?A_ 2.4-Dichloro-phenol (12043.2) x <10 :L ug/1 kg/day 3A. 2.4-DimethyF- <10 -- 1 uq/1 kg/day phenol (105-67-9) x 4A.S-OInitro-X <50 -- 1 ug/1 kg/day Cresol (534-52-1) 12.5) <50 -- 1 ug/1 kg/day phenol (51-2.8-5) 6A. 2-Nrophnol --1 1 ug/h kg/day (88-75-5) I 7A. 4-Nltrophenol so -gh kg/day (100-02-7) x <S_- 1_____/a 8A. P-Chloro-M-D/esol (55-50-7)A. Pent<chloro- -- 1 ug/1 kg/day phenol (87-86-5) x 10A. Phenol <10 ug/1 kg/day (1 08-95t2) _____ I___ ___________________ _____il(2.4,8-95T-l2 o <10 -- 1 uS/1 kg/day phenol (88-05-2) ______________ EPA Form 3510-ZC (8-90)PAGE V-5 CONTINUE ON REVERSE 0 0 CONTINUED FROM THE FRONT 2. MARK "X" 3. EFFLUENT 4. UNITS 5: INTAKE (op lono71)1. POLLUTANT
- b. MAXIMUM 30 DAY VALUE c. LO.WG TERM AVRG. a. LONG TERM AND 0. b. c. a. MAXIMUM DAILY VALUE (fm'la, VALUE (/fooi bb)ý AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELlEVED ( I (I) (1). --d. NO. OF a. CONCEN- b. NO. OF (/.#vo,.blc)
REQUIRED PRESENT ASENT CONCENTRATION (21 MASS CONCENTRATION (2 MASS CONCENTRArTON I2IMASS ANALYSES TRATiON b. MASS CONCENTRATION
- 1) MASS ANALYSES GC/MS FRACTION -BASE/NEUTRAL COMPOUNDS (83_32_9)B cnptea-Ig/
k/,y 2B. Acenahylen -- 1 u'l k'day (208-96-8) x __0 -- ! ug/ k/ay 31nhr)cene x <10 1 ag/ 1 kg/day 48. Benzidine (92-87-5) x <SO 0 -- _ I kg /clay 5s. Benzo ()A(,lllacene X <10 -- 1 ug/ kg/day 158..55-3) ____ _______6P. Senezo (o-) x <iD -- 1 ug/ kg/day FPyrone (50.-32A8 78. 3,4-Benzo- 'uoznlhne -<10 ..1 ug/1 kg/day 88. Benzo (< x _10 1 ug k Peryle (191-24-Z) -lkg/day 98. Benzo (k)Fluolnthone <10 -- 1 ug/1 kg/day (207-08-9) _108. Els (3-C<ho,o-ahowy) Methane <10 a. 1 lg/l kg/day ,,.- g/ g/a 118. BEl (2-Chloro-r,"kI) Ether <0 -- 1 ug/1 k/day 12B. BIS (2- <10 -u/1 kg/daly Ether (102-80-1) A 139. BIa 12.&h,/-hery) Phthamtae " <10 -- 1 uday (1"7-81-T) g 148. 4-1-omophenyl Phonyl Ether <10 -- ug/l k/day (101-55-3) .kIa .15B., BtylBenzyl <10 -- 1 ug/ kg/day Phthalate (85-68-7)168. 2-Chloro-naphthalenre <10 -- 1 ug/1 kg/day 1(91-589-TI ________ _____ ______17B, 4-Chlor o-phonyl Phonyl Ether <10 --1 ug/ kg/day (7005-72-3) 111 18B. Chrysene <10 -- e ug/1 kg/day (211-9) kg/day 198. Diberzo (-.h), Anzecene (0<10 -- 1 ug/1 kg/day (53-70-.3) 208. 1.2-C)ichloro-1 g l k / a benzene(5-50-) <10 -- 1 ug/( kg/day ePA.Forn 3 510-27(-9) PAG< V---ONTINUE/O PAGE V-EPA Form 3510-2C (8-90)PAGE V-6 CONTINUE ON PAGE V-7 CON-flNUED FROM PAGE V-6 2. MARK1X" 3. EFFLUENT 4. UNITS 5. INTAKE (opliono 1. 'POLLUTANT Eb. MAXIMUM 30 DAY VALUE I. LONG TERM AVRG. a. LONG TERM AND a. b. I C. a. MAXIMUM DAILYVAI UE (!J-alaabk)j VALUE (/ oj,67blabe) OF a. COFE "AVEzRAGEVALUE
- b. NO. OF CAS NUMBER TESTING BELIEVED BEUEvE. (1) O. O a.
NI 2. NO.OEF (ifavalablc) REQUIRED PRESENT ABSENT CONCENTRATION 1 (21 MASS CONCENTRATION 1 (21 MASS. CONCENTRATON (2) MASS ANALYSES TRATION b. MASS NCENT GC/MS FRACTION -BASE/NEUTRAL COMPOUNDS (conlmr4d) 22B. ,4- r-Dchloro 10 -1 ug/! kg/day benzene (108-46-7) <10 1 1 238. 3.3-DichlorO-Ny benZldOn* (91-94-1) <20 --1 U/ kg/day 248. D1ethyi PhihalSte (&4-6r-2) <10 1 ugS/ kg/day 258. Dimethyl Phthalate <10 -- I ug/ kg/day (131 3) .26B. OI-N-ButyI x .0 ug/l ks/day Phthalate (84-74-Z)278. .4-Oilntro-toluene (121-14-2) <10 -- 1 ug/ kg/day 28. .,E-Olnitro-touueCiC x <10 I ug/! kg/day 298. DIN-Ocryl 0 PhthaIOe (117-84-0) <10 -ug/I kg/day 30B. 1.2-Dlphenyl-hydrazlne (OsAZD- <50 --ks/day benzene) (122-W7) xg 31B. Ruoranthene (206-44-0) x <10 -- ug/l kg/day 328. Fluorene N (8&-73-7) 1<0 --1 ug/1 kg/day 338. HexachlorO-benzene (118-74-1) <10 -- 1 u9/1 kg/day 34a. Hexachloro- <0U/1 k/a butadleno (87- __-3) .<10 -- 1 Ug/ kg/day 35a. HIma chloro-cydopentacuene r <10 -- 1 ug/l kg/day (77-47-4) .. .. .. .... .368 Hexa=&Ioro- <11 ug/1 kg/day ethane (67-72-1) <O-1__<_378. IndenO (1.z3-51) Pyrone x <10 -- 1 ug/l kg/day 388. Isophorone .<10 ug/ kg/day ('78-59-1) -I -1 US' s/a 39 Naph enekg/day (91-20-3) I <I0 -- 1 _/__k_/__408, Nitrobcnzene (98-97-2) x0 CIO I u_/l k/day 41 8, N-Nltro-soolmethylamn-fe <10 -- 1 Ug/l kg//day (82-7&091 42B. N-Nltrosodl-N-Propylamne <10 -- 1 ug/1 kg/day (621-14 ... ....EPA Form 3510-2C (8-90)PAGE V-7 CONTINUE ON REVERSE W 0 0.p CONTINUED FROM THE FRONT 2. MARK X" I 3. EFFLUENT 4. UNITS 1 5. INTA.KE (optiomat)
- 1. POLLUTANT
' I b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. I a. LONG TERM AND I , a. MAXIMUM DAILY VALUE I f W.'oiible) VALUE (0f, OF a.bleE) AVERAGEVALUE CAS NUMBER TFSTI1NG BELI8VED BUEVED (1) I (1) (1) ' d. NO. OF a. CONCEN- (1) b. NO. OF (i availal"e) REUIRBO PRESENT' ABSENT CONCENTRATION I (2) MASS CONCENTRAT ON I (2) MASS CONCENTRATION MA ANALYSES TRATION b. MASS CONCENTRATION (2) A PALYS GO/MS FRACTION -SASS/NEUTRAL COMPOUNDS (conlimied) ___________________ 438. N.N~trc-sodlPhenylallllfl <10 2. Ug/ kg/day (88-30-81 443.- phonanthIreno 1 45 , nox2.1 u g / 1 k g / d a y 2P9. Pyeoa 43P. 1.,-TB-(319-65-7) 4P. a-EHO (319-84-9) _ _6P. Ch-ordsC (58-74-9)7P. 4.4-DO)T (50-29-3) ______8P. 44-ODE (72-5-5-9) ________9P. 4.4'-00 10p. 0licdrIn (80-57_1)___________ 1 IP.ct-Enosulfafl (115.29.>7) _ ___12P. p-Enbosu~fan (11 5-2sl),___ ______ ____13P. Encdosuk1On (1031-07-6) ___________ ____ ______14P. Endenf (72-20-8) _________iSP, Endrin Aldehyda (7421.93-4) ____ ___________ ____(76-44-8) _ __EPA Form 3510-2C (8-9 0)PAGE V-8 CONTINUE ON PAGE V-9 EPA Form 3510-2C (8-90) PAGE V-9 0 -0 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of this Information EPA I.D. NUMBER (copyftom h.n / qfFa.r/ )on separate sheets (use the same forma) instead of completing these pages. OH0003786 SEE INSTRUCTIONS. V. INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 o Fnorm 2-C)OUTFALL NO.03 PART A-You must provide the results of at least one analysis for every pollutant In this table. Complete one table for each outfaIll. See lstructions for additional detal.s.3. UNITS 4. INTAKE 2. EFFLUENT (SpzciIý ltlank) (opuo-eea)
- b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE ' a. LONG TERM a. MAXIMUM DAILY VALUE (If-01a 10bc) (Wif eiot ) AVERAGEVALUE
- 1) (I) d. NO. OF a. CONCEN- () b. NO. OF 1. POLLUTANT CONCENTRATION (2) MASS CONCENTRATION (2) MASS (1) CONCENTRATION 121 MASS ANALYSES TRATION b. MASS CONCENTRATION
- 12) MASS ANALYSES a. BlochemicaJ Oxygen 6 5.04 1 m9//1 kg/day x Demand (BOD)b. Chemical Oxygen 24.6 20.7 1 t/1 kg/day Demand (COD)r- Total Organic Carbon (TOrP 4.26 3.58 1 mg/1 kg/day d. Total Suspended Solids (TSS) 16 13.5 1 mg/i kg/day x c. Ammonia (as N) 0.144 0.120 1 mg/i kg/day VALUE VALUE VALUE 24.... / VALUE f. Flew D. 222 24 mgd I kg/day g. Temperature VALUE VALUE VALUE VALUEC h. Temperature VALUE' VALUE VALUE VALUE (a,,me,) 22.9 4 C L. PH 1 .91 8.14 4MX U 4 1111'5 PART B- Mark *X In coIumn 2-a for each pollutant you know or have reason to believe is present. Mark *X" in column 2-b for each pollutant you believe to be absent If you mark column 2a for any pollutant which is limited either directy. or indirectly but expressly, in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant For other pollutants for which you mark column 2a, you must provide quantitative data oran explanation of their presence in your discharge.
Complete one table for each outfall. Seethe instructions for additional details and requirements.
- 2. MARKX* 3.EFFLUENT
- 4. UNITS S. INTAKE Cop.o ..1. POLLUTANT
- b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM AVERAGE AND a. b. a. MAXIMUM DAILY VALUE (if a0ailable) (iailable)
VALUE CAS NO. BUEVED BELIEVED (1) (1) d. NO. OF a. CONCEN b. NO. OF'(Ifoval/lable) PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION
- 12) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (1) MASS ANALYSES a. Bromide (24959-67-9)
X <0. 03 -1 Mg/ kg/dy b. ChloIneTo .al Residual c. polor d. Fecal Coliform e. Fluoride (16984-48") X 0.200 0.170 1 mg/i kg/dyý.Nsltret.mtrite X 0.631 .531 2. tog/I kg/dy x EPA. oe 351 -(-SO PAG v....CON..INU...ON..REVER..E EPA Form 3510-2C (8-90)PAGE V-1 CONTINUE ON REVERSE ITEM V-8 CONTINUED FROM FRONT 2..MARK " 3. EFFLUENT ...._4. UNITS S. INTAKE
- 1. POLLUTANT
' ...... b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG, VALUE a. LONG TERM AND a. b. a. MAXIMUM DAILY VALUE (ffo,,lloble) (QfoiLea.) .AVERAGEVALUE CAS NO. BELIEVED BELIEVED (1) (1) (1) d. NO. OF a. CONCEN- (1 b. NO. OF PRESENT ABSENT CO..NC.ENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b.MASS CONCENTRATION (2 MASS ANALYSES a. Nitrogen.Total Organic (os h. OIl end Grease L Phosphorus (as P). Total C1723-1 4-0)J. Radloactvity (1) Alpha, Total (2) Beta. Total (3) Radium, Total (4) Radium 226.Total%. Sulfate (14.6) 30279 1 mg/i kg/dy L Sulfide (*S)m. Sufite (142&--45-3)
- n. Surfactannt
- o. AJumInum, Total (7429-90-5)
- p. Barium. Total (7440-39-3)
- q. Boron. Total (7440-42-8)
- r. Cobalt, Total (7440-48-4)
____s. Iron. Total (743M9-69-) ___I Magnesium. Total a7439-95-4)
- u. Molybdenum, Total (7439-98-7)
- v. Manganese, Total (7439-9-)
__-s,,___w. Th. Toal C7440-31-5)
- x. TntanIum, (744D-32-6)
EPA Form 3510-2C (840)PAGE V-2 CONTINUE ON PAGE v-3 EPA I.D. NUMBER (copyframole I of Form 1) -OUTFALL NUMBER OH0003786 1 003 L CONT]NUED FROM PAGE 3 OF FORM 2.-C PART C -If you are a pimary industry and this outfall contains process wastewater, refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark -X- In column 2-a for all such GC/MS fractions that apply to your industry and for ALL foxlc metals, cyanides. and total phenols. If you are not required to mark column 2-a (secondary industries. vaoeswater outf al, and rronreqtred GC/MS fractions), mard "X In column 2-b for each pollutant you know or have reason to believe is present Mark WX in column 2-c for each pollutant you believe Is absent If you mnark column 28 for any pollutant, you must provide the results of at least one analysis for that pollutant If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant If you know or have reason to believe It will be discharged In concentrations of 10 ppb or greater. If you mark column 2b for acrolein, acrylonitrie, 2.4 dinltrophenol. or 2-methyl-4. 6 dlnitrophenol. you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you dlscharge In concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b. you must either Submit at least one analysis or briefly describe the reasons the pollutant Is expected to be ischarged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pages) for each ouffall. See instructions for additlonal details and reoufrernents.
- 2. MARK WX'3. EFFLUENT 1 4. UNITS 1 5. INTAKE (optriol)1. POLLUTANT b..MAXIMUM30DAYVALUE
- c. LONG TERM AVRG. a. LONG TERM AND a. b. a. MAXJMUM DAILY VALUE .AMM VALUE (tifvic) AVERAGEVALUVE CAS NUMBER TESTING BELEVED IBLIeVED (1) MS dI N NO. OF a. CONCEN- b b. NO. OF (t(owabalab)
REQUIRED PRESENT ASSENT I CONCENTRAIoNi 121 MASS tCONCENTRATION I2) MASSI CONCENTRATION 1 21 mASS ANALYSES TRATION b. MASS CON 'RATION 1(21) MSS JANALYSES METALS. CYANIDE. AND TOTAL PHENOLS I M. Antimony, Total (7440-36-0) 2M. Arsenic. Total (7440--2) , 3M. Beryllium, Total (7440-41-7) 1M. Cadmlum, Total (7440-43.9) SM, Chromrium. Total (744047-.,3) 6M. Copper, Total (7440-50-8) 7M. Lead, Total (743"Z52i) ____aM. Mercury, Total (743"..7--S) 9M. Nickel. Total (7440-02-0) 1DM. Selenium.Total (7782-49-2) I I M. Silver, Total (7440-22-4) 12M. Thallum, Total (7440-28-0) 13M. Zinc, Total (T440-66-6) 14M. Cyanide.Total (57-1 2-5)iSM. Phenols.Total DIOXIN 2.3.7.8-Tet-r -DESCRIBE RESULTS chlonodi..en.o-P-Dioxin 11784"1-6) EPA 3s1-2C (a-9)PAGE V-3 CONTINUE ON REVERSE ICIM11NI IFr FROM TI-E~ FRONT CONTINUED FROM THE FRONT 2. MARK X" 3. EFFLUENT I 4. UN)TS I 5. INTAE (oolionrat) 1 1 4. UN S 1 5. INTAKE abnaO 1. POLLUTANT
- b. ,MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND e. b. , .MAXIMUM DAILY VALUE (,fl ~ble) VALUE (Wfoal/able)
AVERAGE VALUE CASNNUMBER TESTING BEUEVED B(E\EE 1) (d) ...l. NO. OF a. CONCEN- ba. NO OF (i~f ,vailabe) R8CUIRE- PRESENT ABSENT CONCSNTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION
- 3) MS ANALYSES TRATION '. MASS CONCENTRATION I)FMASS ANALYSES Gu/ms FRACTION -VOLATILE COMPOUNDS lV. Accrolcln (107.02-a) 2V. Acryloleett~
(107-13-1) ____________ ____3V. Berzon*(71-43-2) _________ ____4v. alaS (Cbforo, mcikyO Ether 5V. Brrnioforrm (75-25-2) __ ____ ___6V, Carbon Tetrachloride 7V -Chlorobenzole, (108-90-7) ____ ____5V. Chlorodil-brornomnethamo (I12A48-41) RV. Chloroolarlo (75-00.3) ___________ I OV. 2-Chloro-ethyvlnyl Ether 1010-7-5-8) ______ ___I IV. Chloroform (87-85-3)12V. Dicliloro-bromomnethone (75-Z7-4) ____l3Vi Olcirloro-d turoehane (7&-71-8) __ ________ __ ___14V. 1.1-DIChIc~rO-ethane (7$,34-S) _ __Isv. 1.2.D1chlorO. ethrane (107-06-2) ___isv. 1 .i-DIchIoro-ethylene (75.35.4) _________ _______17V. 1 .2.0ithlpro_ propane (78-87-5)18V. 1.5-DiohlorO-propylene (542-75-6) i9V. Ethylberrefle (100-41-4) 20V. Methyl Bromide (74-83-9) ____21V. Methyl Chloride (473 ____________________________________ EPA Form 351 D-2C (8-90)PAGE V-4 CONTINUE ON PAGE V-5 CONTINUED FROM PAGE V-4 2. MARKX'X 3. EFFLUENT 4. UNITS 5. INTAKE (oplionol)
- 1. POLLUTANT'
- b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. -. LONG TERM AND a. b. c a. MAXIMUM DAILY VALUE (I. a'oobkI VALUE (afovoilobtc)
AVERAGE VALUE CAS NUMBER TESTING BFUEVEO BELIEVED (1) i I (1) d. NO. OF a. CONCEN- (II b. NO. OF (If avalaMek) REQUIREDý PRESENT ABSENT CONCENTRATION _(2) MASS CONCENTRRATION (2) MASS CONCETrRAT1ON 1(2 MASS ANALYSESý TRATION b. MASS CONCENTRA'lON (21 MASS ANALYSES GCJMS FRACTION -VOLAIlLE COMPOUNDS (conrh-ed) 22V. Methylene Chlorde (75409-2) .......23v. 1.1.22-Tetracnloroehane 24V. othyleno (127-18-4) " _25V. Toluene (105-05-3) __ ________ ____29V. 1.-Trans-DCahloroethyleno (15s.60- ......27V. 11,i.-Trichloro-ethJane (71-55-6)28V. 1,1.2-Trdchloro-ethane (7S-00-5)Z9V TrIchloro-ethylene (79-01-6)30V. Trichloro-fluorometh nn (7.,-69-4) , __31V. Vinyl Chltrode (75-01-4)GCIMS FRACTION -ACID COMPOUNDS 1A. 2-Chlorophenol (95-57-8)2A, 2.4-DichWro-phenol (120-83-2) 3A. 2,4.Dimethyl-phenol (105-67-9) 4A. 4,6-DInlto-O-Cresol (534-52.1) 5A 2,4-Dlnitro. phenol (51-28.5)SA. 2.Nitrophenol (M8875-5) ......7A .4-Nltrophenol (1 00-02-7)1A. P-Chleorc-M-CrLsol (59-50-7)9A. PentLchloro-phenol (87-86-5)10A. Phenol (108-95-2) 11 A. 2.4,6-Trchloro-phenol (588.5-2)EPA Form 351 0-2C (-0 PAG EV.-5 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2- MARKIX" 3. EFFLUENT 4. UNITS 5. INTAKE ({pdow) , 4.POLLUTANT
- b. MAXIMUM 30 DAY VALUE c LONG TERM AVRG. a. LONG TERM AND 1. a. MAXIM UM DAILY VALUE (i~~iolJVALUE
{IOr--,aJble) AVE RAG EVALUE CAS NUMBER TESTING BEU`VEDV ELIUEVEB (1) "). I d. NO. OF a. CONCEN- (1) b. NO. OF (J(avlkabh4) REQUIREDJ PRESENT ABSENT CONCENTRATION C2) MASS CONCENTRATION (2) MASS CONCENTRATION I (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSES GC(MS FRACTION -BASE/NEUTRAL COMPOUNDS .....' S. Acenaphthone (58-32.9) ____ ____218. AcenaphryIen e (208""8-8) , (12012.)1____ _______48. Benzidine (02-87-5)58. Senzo (W)Anthrcane Ba. Bermo (a)Pyrene (50-32)8)7B. 3,4-Benzo-fluoranthene (205-99-2)
- 88. Benzo (gl/)Porylene (191-24-2) 9B. Berzo (k),luoranthene (207.08-9) 10B. BIs (2-Chdoro-(flhoxy) Methane (11 1-91-1) ___________
418 .Bls (2..Chfawo- 'hy/) Ether (111-44-4) 128. BLs (p. thner (1 02-80-1)138. Bis(2EbJ],-Ay) Phthalate (117-81-7) 14B. 4-Bromophenyl Phenyl Ether'(101-55-3) _________15S8. Butyl Benwyi Phthalate (85.68-7)165. 27-Chloro-naphthalene (91-58.7) ___ ____179. 4-Chloro.phenyl Phenyl Ether (7005&72-3) 183. Chrysene (21"18.0.) ______19B. Dibenzo (,J.,)Anthracene (53-70-3)20B. 1.2-Dichloro-bensene (9.50)D-1) 21B. benzene (541-73-1) EPA Form 3510-2C (8-90)PAGE V-6 CONTINUE ON PAGE V-7 CONTINUED FROM PAGE V-.6 2- MARK X 3. EFFLUENT I 4. UNITR I _ INTAKR (a,I,,,,,,I
- 4. UNITS 5 1 NTAKE fppflonaA 1. POLLUTANT I /b. MAXIMUM 30 DAY VALUE I. .LONG TERM AVRG. a. LONG TERM AND b. a. MAXIMUM DAILY VALUE (Ifroallabfc)
VALUE (if oal/dbte) AVERAGE VALUE CAS NUMBER TESTING 8UEvSD BELEVED ) (1) (1) d. NO. OF a CONCEN- (1) b. NO. OF REQU-IRED RES-NT ABSENT CONCENTRATION 1(2) MASS CONCENPTRATION (2) MASS CONCEN'TRATION (2) MASS ANALYSES "TRATION t b. MASS CONCTRATION M SS NALYSE GD/MR FRACTION --BASE/NEUTRAL COMPOUNDS Icotd,('228.1lA-Olchloro-benzen~e (1 06-4&-7) ____________ 236. 3.3-Dichloof-beraldine (91-94-1)248- OleIIhyl Phthalate (84-66-2)259. Olsethyt Phthalate 268. 0t-N-Butyl Phthalate (84-74-2) ___276. 2,4-Drlnltro-toluen~e (121.14-2) _______286. ZS-Olnltro-toluene (606-20-2) 1_______ ____208. Dl-N-Octyl Phthalato (117-84-0) ____ _______ ____ __________ _______308. I.2-DlpheA* hydrazine (as AzO-benzene) (12-67 _______318B. Fluoronthene (20&-44_0) ___ _______328. Fluorerta 338. Hmxchloro-benzene (118-74-1) ____________ 34B. Hexochloro-hutadlene (87-68-3) ____356. Hexachloro-cyclopentadlonc (77-47-4)368 Hexachlorc-ethane (67-72-1)' 378. Indeno (1.2,3-cd) Pyrenc (1983-39-5) _______ _____388. Isophorco1e (78-58-1) ___ ____39B6- Naphihaleile (91-20_3) _______ _______40B. Nltrobonznefl 41 B. N-NItro-sodimethylarnirdl 428. N-Nitrosodi-N-Propylamine 1(621-64-7) _ _ _ ________ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ ________ ____EPA Form 3510-2C (8-90)PAGE V-7 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2. MARK "X 3. EFFLUENT 4. UNITS 5. INTAKE (oprioni)_*
- 1. POLLUTANT
- b. MAXIMUM 30 DAY VALUE ¢. LONG TERM AVRG. a. LONG TERM AND a. b. a .MAXIMUM DAILY VALUE (ifmoab/c)
VALUE ( AVERAGE VALUE CAS NUMBER TES-ING BEUIEVED BEUEVED (1) 1 (1) ". NO. OF o. CONCEN- (1) 1 b. NO. OF..f ovalable) REQUIRED PRESENT ABSENT CDNCENTRATI0N (2) MASS CONCENTR ON ,2)MSS ENTRANTRATION (2)MASS ANALYSES TRATION b. MASS CONCENTRATION r2) MAS ANALYSES GC-MS FRACTION -aSE/NEUTRAL COMPOUNDS (connimed) 438. N-NIl(O-s.dsphcen~amlnc (86-30-6) .... : 44B. Phananthrtefe 45B. Pyrene (129-00-0) 468" 1.24-.Tr6. GC/MS FRACTION -PESTICIDES I P. A/orn "'(309-00-2) 2P. ,-SHC (319-84-6) 3P. "H,-BHC (3198-85-7) _______4P. 7-BHC (58-8g-9)5P.6-BHC (311;-86-8) 6P. Chlordoane (57-74-9)7P. 4.4'-DDT (50-29-3)8P. 4.4'-0E)(72-5,5-9) _ __ _OP. 4.4'-DDO (60-57-1)11 P. -Eiosulforn 12P. ),-E.ndosulfan (1 10-29-7) I I I 13P. Sulfate (1031-07-8) 14P. Ezndrin (72-2U-8)15P. Endrin Aldehyde (7421-934) 16P. Heptacl/or (76-44-B)EPA Form 3510-2C (8-90)PAGE V-8 CONTINUE ON PAGE V-9 EPA I.D. NUMBER (copyfrom Item I o/Form n)OH0003786 OUTFALL NUMBER 003 CONTINUED FROM PAGE V-8 2. MARK 3. EFFLUENT 4. UNITS 5. INTAKE (opiono, 2. MOLLTAN *X b. MAXIMU 3. EAYFVLUENT .LONG TERM AVRG. a.LONG TERM b. o. c a. MAXIMUM DAILY VALUE (if-, avible) VALUE (I ova/labLe) AVERAGE VALUE CAS NUMBER TESTING BEUEVED IEUEVED (1) (1) d. NO. OF a. CONCEN- b. NO. OF ((o,.llable) REQUIRED PRESENT 1 ABSENT N RAON (2) MASS CONCENTRATION (2) MASS OCNTRATION (21mAss JANALYSES TRATION b. MASS CONCENTRATION (2 M ALYSES {MS OCNTRATGON N2) MASS CONCENTRATION PAL MASS GC/MS FRACTION -PESTICIDES (conThnr.d) 17P. HepItenlor (1024-5T-3)- C -18P. PCB-1242 (534S9-21-9) 19P. PCB-1 254 (11097-65-1) 20P. PCS-l 221 (11'04-28-2) 21P. PCB-1232 (11141-16&5) 22P. PCB,-1248 (12672-29g,.6) 23P. PCB-1260 24P. PC.-1016 (12874-11.2) " 1 25P.Toxaphent I (E001-35-2) EPA Form 3510-2C (8-90)PAGE V-9 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of this information EPA I.D. NUMBER (copyfmnlim o Form/)on separate sheets (use the same format) Instead of completing these pages. OE0 0 03 786 SEE INSTRUCTIONS. V. INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 of Form 2-C))UTFALL NO.D4 PART A -You must provide the results of at least one analysis for every pollutant In this table. Complete one table for each outfall. See instructions for additional details.3. UNITS 4. INTAKE 2. EFFLUENT (spect! (yfbLk) (opional0 b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM a. MAXIMUM. DAILY VALUE (if vi1abd) (a. COell hEN) AVERAGE VALUE (1) (1) d. NO. OF a. CONCEN- (1) b. NO. OF 1. POLLUTANT CONCENTRATION (2) MASS CONCENTRATION (2) MASS (1) CONCENTRATION (2)1 ASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSES 0. Blochemical Oxygen 5.4 .102 1 rat/1 k2./day Demand (DOD)b. Chemlcal Oxygen 24.6 0.47 1 mg/i kg/day Demand (COD)c. Total Organic Carbon 5.67 0.11. 1 mg/i kg/day (TO C)d. Total Suspended Solids (TSS) 68 1.3 1 mg/1 kg/day e. Ammonla ("A) <0.1 -- I mg/ kg/day VALUE VALUE VALUE VALUE f. Flow 0.005 24 mgd kg/day g. Temperature VALUE VALUE VALUE VALUE (win,,) " h. Temperature VALUE VALUE VALUE .VALUE (Swn.er) 22.2 4 MINIMUM MAXiMUM MINIMUM MAXIMUM LpH 7.65 ? 4 STANDARD UNITS PART B- Mark 'X" In column 2-a for each pollutnlt you know or have reason to believe is present. Mark I"C in column 2-b for each pollutant you believe to be absent. If you mark column 2a'for any pollutant which is limited eith&directly, or indirectly but expressly, in an effluent limahtions guideline, you must provide the results of at least one analysis for that pollutant For other poliutarts for which you mark column 23, you must provide a uantitalive data or an explanation of their oresenne in you r isn~horae lCemnlete one lable for each ouftfatL Ree the in tiutons fnr ordditimnnl 4etoiln -. 2. MARK -A, 3. EFFLUENT 1 4. UNITS S. INTAKE (..ioptofk',;)_
- 1. POLLUTANT
- b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM AVERAGE AND b. a. MAXIMUM DAILY VALUE fIf,,aila5le,) (If avilabl,)
VALUE CAS NO. BIBIEVED BELIEVED (1) (1)(1d. NO. OF a. CONCEN- V b. NO. OF PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION
- 12) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (22) MASS ANALYSES a. romide (24o59-57-9)
X <0.03 -- 1 tg/i kg/dy <O.OS -- 4 mg/i kg/dy c. Color X 20 -- 1 Units kg/dy d. Fecal Collform X 102.5 -- 4 perlO Ol kg/dy e. Fluoride 6,- 0.396 0. 0n0 1 mg/i kg/dy f.Virato-Nalmte X 0.154 .003 1 mg/i kg/dy x (as M EPA Form 3510-2C (8-90)PAG E V'-1-CONTI NU EON REVERSE ITEM V-B CONTINUED FROM FRONT 2. MARK"X" 3. EFFLUENT 4. UNITS 5. INTAKE (opijonol)
- 1. POLLUTANT
- b. MAXJMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE a. LONG TERM AND b. a. MAX)MUM DAILYVALUE ( ,ble) (/.(, )AVERAGEVALUE:
CA$ NO. BEUEVED BE1IEVED (1) (1) d. NO. OF a. CONCEN-. b NO. OF (Ofoildable) PRESENT ABSENT 0ONCENTRATON () MASS CONCENTRATION () MASS CONCENTRATION
- 12) MASS ANALYSES TRATION b. MASS CONCENTRATION
- 12) MASS ANALYSES g .N l -ro g e lwen , \Total Organic (as 0.95 0.02 tO h. on and GraeX <-5.0 -- mg/1. kq/dy Gre.aso L Phosphorus (asP.Tol0.06 0.01 mg/i kg/dy x.(77Z3-14-0)
/ ,..J. Rsdioecllvity _(I) Alpha, (2) Beta. Total (3) Radium.Total (4) Radium 228.Total k. Sulfate (ISO,) 356.6 6.76/(14808-7.) .mg/ kg/dy I. Suffide (= )x <10 _m_"/_ _ kg"/dy m. u1fitle* sq.) is1 -gl Sd (142565-45-3) x Mg/i kg/dy n. Suactants x 0.01.3 0.0. mg/, kq/dy o. AlumInum.Total T429-9a) / 2246 0.043 1 ug/ kg/du p. Barium. Total '.(7440-39-i) 2 94 0.002 1 Ug/. kg/dy q. Boron, Total (7440-42-8) x 262 0.005 1 ug/2. kg/dy r. CObaL. Total (7440.4864) x <1.0 -- 1 ug/1 kg/dy 3.. 1 (on, Total 17439-&9-q x 2485 0.047 -ug/3 kg/dy t. Magnesium, ( 20650 0.391. 2 ug/1 kg/dy 0u. Mogybdenum/ TX <2.0 -- ug/i kg/dy ,. Mznganose, Total 4119 .002 2. ug/l kg/dy w. n, Total (744D-31-5) x <4, --u9/1 k9/dy EATorm 35tanium,0- ' P (7A4u,0- I g- k/d EPA Form 3510-2C (840)PAGE V4-2 CONTINUE ON PAGE V-3 EPA I.D. NUMBER (copvfrom lIcm 1 of Formi) OUTFALL NUMBER 0H0003786 004 CONTINUED FROM PAGE 3 OF FORM 2-C PART C -if you are a primary industy and this outtafl contains process wastewater, refer to Table 2c-2 in the instructions to determine which of me GC/MS fractions you must test for. Mark X& in column 2-a for all such GC/MS fractions that apply to your industry ard.for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2-a (secondaryindusdes. nonprocess wastewater oulfats, and nonrequlred GC/MS fracdons), mark *X" in column 2-b for each pollutant you know or have reason to believe is present. Mark "XC in column 2-c for each pollutant you belIeve Is absent If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant If you know or have reason to believe It wtl be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrolein. acryloritrile, 2,4 dinitrophenol, or 2-methyl-4. 6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b, you must either submit at least one analysis or briefly desCribe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part: please review each carefully. Complete one table (all 7 pages) for each outfall. See InstructJons for additional details and requirements.
- 2. MARK"X" 3. EFFLUENT 4. UNITS 1 5. INTAK<E fopfibnal 1. POLLUTANT
---7' b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AAVER-- VALULE AND a.T b. .a. MAXI MUM DAJLY VALUE (if'obk) VALUE (ifIatalebtc)
- d. NOA OF L. CONCEN- "U E bNO. OF CAS NUMBER [IT1,1NG SELIEVED aEUsveo 1 I d (1) '0'
- b (ffovo/ob~.)
jRECUIRED PRESENT ABSENT CON.CENTRATON
- 12) MASS CONCENTRATION1 121 MASS CONC-NTRATION 121 MASS ANALYSES TRATION b. MASS CONCENTRATION 121 MASS LYSES METALS, CYANIDE, AND TOTAL PHENOLS'1M. Antimony, Total X <8.0 -- 1 .g/i kg/day (7440-36-0)
_____________ 2M. 2M.3Nea. X <<10 -- 1 ug/ kg/day (7440-38-2) ___3M. Beryllum, Total <i.0 -- 1 ug/1 kg/day (74.40-41-7) X <. U/1_ga 4M. Cadmium, Total <1.o -- 1 ug/ kg/day (7440-43-9) <.0g__5M. Chromium. 4 3.0 0.00 1 ug/1 kg/day Total (7440-47-3) X 3.0 001____6M. Copper, Total (744D.50-a)o .<4.0 --I U9/1 kg/day X 7M.Lead, Total 17 0.0003 1 ug/1 kg/day (7439.92-1) X 8M. Mercury.Total <0.2 -- 1 ug/T kg/day (7439-97-6) X 0_2_I_____ 9M. Mckel, Total 5 0.00 1 Ug/1 kg/day (7440-02-0) X 10M. Selnium, \1 TOMa lni82-4m-2) X 55 .001 1 ug/1 kg/day 11M. Silver, Total 2 0.00 1 ug/) kg/day (74-40-22-4) 12M. Thallium, Total (7440-28-0) X 33 0. 0006 1 ug/l k9/day 13M. Zinc, Total 201 uq/1 kg/day (7440-66-6) 21 0.000/14M. Cyanide, c 0.005 -- 4 Tg/1 kg/day Total (57-12-5) X 15M. Phenols. $< -- 4 ug/ kg/day Total <5.04k;da DIOXIN 2,3.7,B-Tesps.- DESCRIBE RESULTS chlrorodlberizo-P-0-ovin, (1764-01-6) EPA Form 3510--2C (8-90)PAGE V-CONTINUE ON REVERSE CONTINUED FROM THE FRONT____-- --2. MARK'X 3. EFFLUENT 4. UNITS 5. INTAKE (cpfionOI)
- 1. POLLUTANT
- b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM.AND 3. b. .a. MAXIMUM DAILY VALUE (if'ifa'bl.)
VALUE (eftabic) AVERAGE VALUE CAS NUMBER a. TF.NG ý BELIEED I.v; I(1)
- d. NO. OF a. CONCEN- i, Ib NO, OF , llle) REQUIREj PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION I (2) MASS CONCENIRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION.1 (2)IMASS IANALYSES GC/MS FRACTION -VOLATILE COMPOUNDS IV. Ac.roLeln (107-02_8) x 25 .ugI2 kg/day 2V. Acrylonitrile (107-13-1)
X <25 -- 1 ugI k/day 3V. BGenzno u.J 2.(71-43-2) x <5.0 -- ug/ kg/day 4v. Bl1 (Ch/ror-m-4) Ether <S.0 -- ug/l kg/day (542-88-i) x 5V. Brrnofor X <. -- 1 ug/l kg/day (75-25.2) x____GV. Carbon (5&23-5) x < 5.0 -- 1 lg/l kg/day 7V. Chlorobenzere 5k (1 O-0-7) x <5.0 I ug// kg/day BV. Chlorodl-bromomethane <5.0 -- 2 ug/l kg/day 1(124-48-1) _____DV. Chloroethane (75-00-3) X <5.0 ug/l kg/clay 1OV. 2-Chloro.llvylhnh1 Ether <5.0 -- 1 ugl kg/day (110-75-8) .11V. Chloroforrt (67-6.3) x <5.0 -- 1 ug/ kg/day 12V. Dlchloro-bromomethane <5.0 -- 1 ugh/1 kg/day 275 ) .. .. ....13V. Dichloro-(75-1-ethane ,- <5.0 -ug/l kg/day 14V. I,1 X <5.0 -- 1 ug/1 kg/day ethane (75-34-3)16V. 2ne-87.hloro- <5. -- ug/1 kg/day ,ethane (107,06-2) ____ ______ ___16V. 1 .1-DiOlhloro -\-g ethylene (7<.35-4) x Ug/1 kg/day 7V.1<. -- 1 ug/1 kg/day propane (78-87-5) gl g/a 18V. 1,2-DlchIoro-prpyee < <5.0 -u/ kg/day 1 SVEthtyIbernze < 5. 0 --1 ug/ 1 kg/day (100.41-4) 2oV. Methyl X 1 ug/1 kg/day Bromide (74-W-9) <5.0 21V.CMethyl ( <5. I US/ I kg//day Chordde('74..87.43) SC -EPA Form 3510-2C (8-90)PAGE V-4 CONTINUE ON PAGE V-5 CONTINUED FROM PAGE V-4 I. MARKIX 3. EFFLUENT 4. UNITS 5. INTAKE (optional)
- 1. POLLUTANT
.b. MAMIMUM10 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND a. a. -,AXIMUM DAILY VALUE (aifblblc) VALUE AVERAGEVALUE CAS NUMBER TESTING BELIEVED BELUEVE (1D .... (1) I d. NO. OF a. CONCEN- (1) b. NO. OF (OfovoilobJc) REQUIRED PRESENT ASSENT CONCENTRATION (2) MASS CONCENTRATION (21 MASS CONCENTRATION I t21 MASS ANALYSES TRATION b. MASS CONCENTRATION (21 MASS JANALYSES GC/MS FRACTI ON -VOLATILE COMPOUN(DS (conmted)22V. Methlylene <50 A ug/ I kg/day Ohloride (75.-05-2) x 23V. 1.122-l"etrchloroethane x <5.0 1 u1 kg/day 24V. Tetrachloro- <5 0 Uq/1 kg/day ethylene (127-18-4) g 25V. Toluene <5.0 1 ug/1 kg/day (080"e.3) ____________ 26V. 1,2-Trans.,. DichloroethyIene x ug/l kg/day M7V. 1.1.1-TrIchloro- <5. 0 1 ug/1 kglday otharl (71-55-6) j xg1 k/a 28V. 1.1 2-Trichloro- <5.1 0ugg/ kg/day ethane 29V Tnrihloro-<5.0 Ug/1 kg/day ethylene (78-0116)30V. Trtchioro-fluoom5-9n4 <5.01 ug/1 kg/day (7,1-69-4) ., 31V. VInyl ChloridX <5.0 ug/1 kg/day (75-01-4) _ ___GCIMS FRACTION -ACID COMPOUNDS'A. 2-Chloroplronol X1 ug/h kg/day (95-57-8)2k 2.4-DIchIlro-1<0 1 ug/1 kg/day phenol (120-83-2) x I 3k 2,4-Dimethyl- <10 1 ug/ kg/day phenol (105-7-6)4A. 4,-olimtro-O- ." <5 ugh kg/day Cresol (534-52-1) _5A 2.4-Ditro. <50 1 ug/ kg/day Phenol (51-28-5) -6A. 2-Nltrophenol <10 uq/1 kg/day (88-75-5) x 7A. 4-Nitrophenol (100-02-7) x <50 1 u/1 kg/day 8k P-Chlro-M- ' <10 1 ug/1 kg/day Cresol (59-50-7) x , I SA. Pentachloro-x <50 1 F/I kg/dlay phenol (B7-86-5)IOA Phenol .<I 1 ug/l kg/dayaI (108-95-2) x 11Ak 2,4,.Trlchoro" <10 1 ug/1 kg/day phenol (85-05-2) 1 ---EPA rorm 3510-2C (8-90)PAGE V-5 CONTINUE ON REVERSE CONTINUED FROM THE FRONT I -..... ----.,,-..- ----.- -~ --2-, X'--..3. EFFLU.NT 4. UNITS -5. INTAKE IeeIeaM. I 4. UNITS I S. INTAKE (opno-h 1. POLLUTANT I -b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND a. IR b. CR A .MAXIMUM DA)LY VALUE5 (CNTATIOI() M NAIA E T MASS CONAERAT 1 MAS AS CAS NUMBER TESTING BELIEVED SEUEVEJ/ O ) .. 1 d, NO. Fa CONCEN- .AV VALE O. OF (;fer al01 b06c) REQUIRED PRESENT ' ABSEN T MASS 'R1T)N-.-M I -.CNETAIN MMASICONCENTRA'nON 1(2) MASS CONCENTPRAT oN ý2) MASS ANAYE aTRATIOIN
- b.
N()MASS AN.A.YSES GCIMS FRACTION -BASEINEUTRAL COMPOUNDS 18. A~ena ph81eimo (83-32-0) ____ ________2B. Acenaphtylen f (208.96-8) 3B. Anthracene
- 48. Benrldlnc (92-87_S)5B. Berzmo (a)AnllhraCene (56-55-3)8B. Bearzo (a)Pyrene (50-32-8)78. 3,4-8enz=.-
nuoran0'ene (20,5-90-2)
- 88. Benzo (w4i)Peryiene (191-24-2) 9B. Bonzo (k)Fluoranthene Z207-08-9) 109. 813 (0-C(Uore-t'.,y) Methane (111.91-1)
,., 118. Bs (2-Chloro-eiI7,J athcr (l11-44-4) 128. B1s (2-ChlomlsoproyA Ether (102-80-1) 13B. gis (2-Ethvi-ho)I) Phthalate (117-91-7) 14B. 4-Bromophenyl Pmenyl Ether 158. Butyl Benzyl Phthal3te (85-68-7) .....168. 2-Chloro-.naphtholenf 178. 4-Chloro-phenyl Phenyl Ether (7005-72-3) 188. Chrysene (218-01-9) _____________________ 19B. Dlbonzo (a.h)Anhac.ene (53-70-3) I___________________ 208. 1.2-DIchloro-benzone (95-50-1)benizene (541-73-1) ____EPA Form 3510-2C (8--90)PAGE V-6 CONTINU E ON PAGE V-7 CONTINUED FROM PAGEV-6 2. MARK X" 3. EFFLUENT 4. UNITS 5. INTAKE (ophonO 1. POLLUTANT
- b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. N a. LONG TERM AND a. b. C. a. MAXIMUM DAILY VALUE (if-allabWe)
VALUE (1(,ailoble.) AVERAGE VALUE CAS NUMBER TETN SEUEVEO BEUJEVED (1) () (1) j .NO F(1) -b. a NO- OF (Iffailabl) REQUIRED PRESENT ABSENT CONCENTRATION CONCONTRATSS CONCENTRATION (2) MASS ANALYSES TRAI'ON b. CONCENTRA]iON (2) MASS ANALYSES GCMS FRACTION -BASE/NEUTRAL COMPOUNDS (cowniicd) 228. 1.4-Dichloro-beraene (1 06r4-7) ,, 23B. 3.3-Dicrhloro-bergJdlne (91-94-1)248,. Oethyl Phthadate (84-66-2)25.B Dimethyl Phtnalato (131 3)26B. DI-N-ButyI Phthalate (84-74-2)27B. 2.4--Dinivo. toluene (121-14-2) 28B. 2.6-Olnbt-o-toluene (E06-20-2) 29S. DI'-N-Octyl Phthalate (1 17-84-0)308. 1.2-Olphenyl-hydrazIne (as Azo-benz-ene) (122-88-7) 313. Fluoranthane (206-44-0) ____ __________________ 328. Fluoreno (86-73-7)33B. Hexactrlorc-benzene (118-74-)1) 348. Hexachloro-buladlotne (87-68-3)358. Hexachloro-cyclopentadioone (77-47-4)3B Hexachloro-etthane (57-72-1)37B.nlndeno (1,2,3-co) Pyrene (193-39-5) 388. IsophoronL (78-59-1)39B. Naphthalene (91-20.3) __ __ ____ ________ ___ ___ _ ___403. Nltrobonzene (984(5-,3) 41B. N-Nltro-3odlmcthylarmne (62-7&-9) .........42B. N-Nltrosodi-N-Propylamlne (621-64-7) ..EPA Form 3510-2C (8-90)PAGE V-7 CONIMNUE ON REVERSE CONTINUED FROM THE FRONT 2. MARKX 3. EFFLUENT 4. UNITS 5. INTAKE (ouono/1. POLLUTANT lb. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND a. b. c a. MAXIMUM DAILY VALUE .(W-a106labl) VALUE (.f available) AVERAGEVALUE CAS NUMBER TESTING BEUEVED BELIEVED (1) d. NO.OF a. CONCE('N-
- 1) b. NO. OF (Wodl.abl&)
REQUIRED PRESENT ABSENT CONCENTRATION 1(2) MASS lCONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION
- 12) MAS ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS (conhmed)439. N-Nit-ro soaiphenylbmln (86-30-6)1448. Phen3nthrene (8.0-01.8)
_______458. Pyrene (120-00-0) _______468. 1,2.4-Td-c.hloroben en (120.-82-1) _GC/MS FRACTION -PESTICIDES 1P. A/drtn (30o900-2) 2P. --BHC (31 90.) ___ __ __3P. "-EHC (319-8.5-7) 4P. 7-EHC (S8-8-09)5P. 6-BHC (319-8G-8) SP. Chlordane (57-74-G)7P. 4,4-DOT (50-.7-3)8P. 4.4-DOE'(7_2-55-9) 9P. 4.4'-ODD" ('72.S4-8) __ _ __ _loP. Dieldrin (60-.57-1) 1 1 P. a-Enosulfan (I158-2S-7) 12P. 1 -End°'ulfan (115-2-S-7) ____13P. Endosulfan Sulfate (1031-07-8) 14P. Endrln (72.2M-B)15P. EndrIn Aldehyde (7421-93-4) 16P. Heptachlor (76-44..8).... EPA Form 3510-2C (8-90)PAG E V-8 CONTINUE ON PAGE V-9) EPA .D. NUMBER (copyfron.mll I ofFom 1) OUTFALL NUMBER CR0003785 004 CONTINUED FROM PAGE V-8 S 2.' MARK "X 3. EFFLUE'NT'
- 4. UNITS 5. INT3AKE (opIlonoJ)
- i. POLLUTANT
- b. MAXJMUM 30 DAY'VALUE
- c. LONG TERM AVRG. -. LONG TERM AND 'L b. c. a. MAXIMUM-DAILY VALUE ("ifva//bde)
VALUE (I,)"vl/able) AVERAGE VALUE CAS NUMBER TESliNG BEUEVEO SEuEVED (1) (1) d. NO. OF 2. CONCEN (1) b. NO. OF (I fveihabi) REQUIRED PRESENT ABSENT CONCENSATION R 2) MASS CDNATION TION ( I2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. CONCENTRATION
- 12) MASS ANALYSES GC/MS FRACTION -PESTICIDES (conu,,rd) 17P. Heptachlor Epoxdde (1024-57-3) 18P. PCB-1242 (53469-21-9) 19P. PCB-1254 (11097-69-1) 20P. PCB-1221 (11104-28-2) ziP. PC D-1232 (11141-16.5) 22P. PCB-1248 (12672-29,.6_
Z3P. PCB-1 260 (11096-82-5) 24P. PCB-1016 (12674-1-2) 25P. Toxmphene EPA Form 3510,-2C (8-90)PAGE V-9 0 0 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of this information EPA I.D. NUMBER (copvlfrom 1cm, I OfForm'l)on separate sheets (use the same formao) Instead of completing these pages. 0H0C03786 SEE INSTRUCTIONS. I .... .I I V. INTAKE AND EFFLUENT CHARACTERISTICS (continued(rfromepage'3ofForm 2-C)OUTFALL NO.601.. .PART A -You must.provide the results of at least one analysis for every pollutant in thls table, Complete one table for each ouffall. See instructions for additional details.3. UNITS 4. INTAKE 2. EFFLUENT (sab5 f blak) (Opdioa))b. MAXIMUM $0 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM a. MAXIMUM DAILYVALUE (Q/maailable) (If avmilable) AVERAGE VALUE (I) (t) 'd. NO. OF a. CONCEN- (1) b. NO. OF 1. POLLUTANT DONCENTRATlON (2) MASS CONCENTRATION (2) MASS (1) CONCENTRATION (2) MASS ANALYSES TRAT1ON b. MASS CONCENTRA71ON C2Z MASS ANALYSES a. BiochemIcal Oxygen 8.6 0 .98 1 mg/L kg/day Demand (BOD)b. Chemical Oxygen 45.5 5.17 1 mg/i kg/day Demand (COD)c. Total Organic Carbon 9.52 1.08 1 mg/i kg/day (TO. 95 101_____d. Total Suspended Solids (TSS) 10 1. 14 1 Tg/1 kg/day X e. Ammonla (as N) 6.70 0.76 1 mg/i kg/day VALUE VALUE VALUE V VALUE f. Flow 0.03 24 mgd k/ay g. Temperature VALUE VALUE VALUE VALUE (winier)h. Temperture VALUE VALUE VALUE VALUE4 " MINIMUM MAXIMUM MINIMUM MAXIMUM .. ... 'L PH i.3 76 STANDARD UNITS PART B- Mark"X" in column 2-a for each pollutant you know or have reason to believe s present. Mark W("in column 2-b for each pollutant you believe to be absent If you mark columrn 2a for any pollutant which Is limited either directly, or indirectly but expressly, in an effluent limitation, guideline, you must provide the resuats of at least one analysis for that pollutant For other pollutants for which you mark column 2a., you must provide quantitative data or an explanation of their presence in your discharge. Complete oee tablefor each outfall. See the Instructions for additional details and requirements.
- 2. MARK"X" 3. EFFLUENT 4. UNITS S. INTAKE (opil) I 1. POLLUTANT
- b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM AVERAGE AND b. a. MAXIMUM DAJLY VALUE (f-.4aallable)
A(Uelabl)E CAS NO. BELIEVED BEUEVED () .1) (1) W. NO. OF a. CONCEN- M b. NO. OF (f/ar'ollobl) PR-ESENr ABSENT CONCENTRATION
- 12) MASS CONCENTRATION
- 12) MASS CONCENTRATION RATION b. MASS CONCENTRATION 121 MASS ANALYSES a. Bromide x <0.03 -- 1 mg/l kg/dy (24959-67-9)
- b. Chlorine, Total <0 .05 4 Residual <0X Mel 4 mg/ kg/dy c. Color 15 -- 1 units kg/dy d. Focal Collfp.om X 25.8 -- 4 perl00ml kg/dy e. Fluoride (16984-4-B) 0.233 0.026 1 1 mg/1 kg/dy f. Nitra-Niite 0.25 0.02 mg/i kg/dy x (sN)025 0.2 EPA Forrn 3510-2C (8-90)PAGE V-1 cownmuE ON REVERSE ITEM V-S CONTINUED FROM FRONT 2. MARK"X" 3. EFFLUENT 4. UNITS 5. INTAKE [oplaonal)
- 1. POLLUTANT b" .MAX1MUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM AND b.' a. MAXIMUM DAILYVALUE (Q'o, alkblc)
AVERAGEVALUE CAS NO. BELIEVED BEUEVED (1) 0() d. NO. OF a. CONCEN- () b. NO. OF (!fýodablc) PRESENT ASSENT CONCENTRATION (2) MASS CONCENTRATION
- 12) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION
- 12) MASS ANALYSES 0. Nitrogen, Total Organic (as 1.3 0.15 1 mg/1 kg/dy h. Oil and 5-Sr¢==/ -,. <5.0 -4ag"/i kg '/dy Grease I. Phosphorus1 (as P).Total 8.15 0.93 I mg/! kg/dy (7723-14-0)
X.Radoactivity (1) Alpha, Total (2) Beto, Total (3) Radlum, Total (4) Radium 226.Total k. Sulfate (-SO.) X 63.3 7.20 1 mg/1 kg/dy (14808-79-8) </I. Sulfide (_sS) x -. <0~ 2I mg/i kg/dy m. Su)lte 12 <15 -- 1 mg/i kg/dy ('14265-45-3)
- n. Surfactant x 0.006 .0007 1- mg/i kg/dy o. Auaminum.Total x 192 0.02 1 Ug/i kg/du x 1920.0.02 p. Barium, Total (7440.39.3) x20 0.05 1 tag/ I kg/dy X q. Boron, Total (7440-42-6)
X 78 0.01 2- ug/i kg/dy .r. Cobat, Toted <1.0 -- 1 Ug/i kg/dy (7440-48-4) _____s,. Iron, Total (7439-8s.-T) X 232 0.03 1 ug/1 kg/dy x L. Magnesium. Total 16404 1.8651 1 aug/1 kg/dy (7439.95-4) U. Molybdenumr. Total <2.0 -- 1 ug/1 kg/dy (7439-8-7)
- v. Manganese, Total X 127 0.01 2. ug/i kg/dy (7439-96-5)
(7440-31-,5) X <4 -- 1 ug/ I kg/dy w.Tin.anium, STotauml II I l-/ Y.9/d (7440-32 x) X i--1 tgi kg/dy x EPA Form 3510-2C (8-90)PAGE V-2 0 CONTINUE ON PAGE V-3 0 I EPA I.D. NUMBER (opýyfromfiem 1 ofFamnn) OUTFALL NUMBER OH0003786 601I CONTINUED FROM PAGE 3 OF FORM 2-C PART C -If you are a primary Industry and this outfall contains process wastewater. refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark "X In column 2-a for all such GC/MS fractions that apply to your industry and for'ALLtoxic metals, cyanides, and toal phenols. If you are no, rejulred to mark column 2-a (secondaq lndustrdes, nonprocess wastewateroutfalls, and nonrequiied GC1MS fractions), marx' X' in column 2-b for each pollutant you know or have reason to believe Is present Mark "X" In column 2-c for each pollutant you beliove Is absent. If you mark column 2z for any potutant. you must provide the resvlts of at least one analysis for that pollutanrt If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant W you know or have reason to believe It will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acroteln. acrylonitrlle. 2,4 dlnitrophenol, or2-methyl-4, 6 dinitrophenol. you must provide the results of at~least one anarlysIs for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b. you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pages) for each outfalL See instructions for additional details and requirements.
- 2. MARK "X" 3. EFFLUENT 4. UNITS I s. INTAKE (atioinatl
- 1. POLLUTANT BEUEVE b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND P U TN a. MAXIMUM DAILY VALUE (iovolebl VALUE (if'aveiabio)
AVERAGE VALUE b CAS NUMBER. TESTING U EVEeLtEaD Ci (1) I (1) d. NO. OF a. CONCEN- b. NO. OF (tfevailabo/) REDUIRED PRESENT ;ABSNT CONCENTRATION 1 (2) MASS CONCENTRATION 1N I(2 MASS ANALYSES TRATION b. MASS CONCENTRAT)ON 121 MSS ANALYSEE METALS, CYANIDE. AND TOTAL PHENOLS 1 M. Antimony, Total I0.0 0 O 1 ugl kg/day C7440-3"-0) 3M. Arsenli. Total X 0.0kd (7440-38-2) 12 0 .g/0 k/day 3M. Beryllum. Total <I. 0 -" ug/. kg/day (7440-41-7) 4M. Cerlalum, Total <10 --1 tg/i kg /day C74.40-43-9) ______5M. Chrormum, Total (7440-47-3) A < --2 Uo/. kg/day SM. Copper, Total e a. Ug/i kg/day X (7440-50-9) __<___0_--__ u_/__kS/day 7M. Lead. Total X9 .001 2I g/ I kg/day (7439-92-1) 9 aM. Mercury, Total .ce.2 -- I kg/day (7439-97-6) 9M. NIckel, Total X uq/1 kg/day (744C-02-0) tOM. Selenium. 33 0.004 1 Ug/1 kg/day Toal (7782-40-2) /IIM. Sliver, Total < 1 I 2g/I kg/day (7440-22-4) <--_/ k d 12MTo haliurn,7 29 0.004 1 ug/l kg/day 13M. Zinc. Total 0001 C7440-66-6) 2.2. .1 tog/1 kg/day no 14M. Cyanide.Total (57-12-5) X <0.005 -- 4 mg/l kg/day IBM. Phenols, .Total 0 DIOXIN 2.37ro-TeTlran DESCRIBE RESULTS chlorodibenzo-P [Dioxin 1174-0-S EPA Form 3510-2C (8-90)PAGE V-3 CONTIN UE ON REVERSE CONTINUED FROM THE FRONT 2. MARK"X" 3. EFLUENT 4. UNITS 5. INTAKk (oet/onal 1. POLLUTANT
- b. MAXIMUM 30 DAY VALUE r. LONG TERM AVRG. a. LONGTERM AND b ý. MAXIMUM DAILY VALUE (if oalvla/e)
VALUE (i.. ova/lb/e) AVERAGE VALUE GAS NUMOER TESTING BEUEVED BELIEVED (1) '2) (1) (1) NO. OP a. CONCEN- b. NO. OF (ifawoloMe RE2UIRED PRESENT ASSENT CONCENTRATIONJ (2) MASS 1CONCEN(TIRAT1ION (2) MASS , CCNCENTAIN(}MS ANLSSTAIN b AS OC.1fAIN )mS AAYE ((fovot/oblo) REDUIRED PRESENT ABSENT CONCENTF1AI1ON RI MASS CONCENTRATION (2) MASS ANALYSES TRXflON 5. MASS CONCENTRATION
- 12) MASS ANALYSES GC/MS FRACTION-VOLATILE COMPOUNDS IV. Accrotelrr (107.02-8)
_______2V. Acrylonitrille (107.13.1) 3V. Benzene (71-43-2) ____4V. BIs (hor/or-oýejhy/) Ether (542-88-1) 5V. Bromoronn (75-25-2)6V. Carbon Tetrachloride (56-23-5)7V. Chlortberaene (108-90-7) ____Sy. Chlorodl-bromometharte, OV. Ch~eetlo~r (75.00.3) ______ ____ ______I CV. 2-Otrloro-cthyinI4 Either lIV. ChrloroformO E(67-6ý6-3) ____ ____I2V. DIchloro-bromomethaefl 13V. DIcirlorp-dllluoromathofle 14V. I.1.D~chlrl~o-ethane C751-34-3) _____ ________________________ ISV. 1 ,2.DIrhI~r0-ethnare (107.06-2) ______I SV. 1 .1-D1chlrIoO-ethylene (75-35-4) _____ __17V. 1 .2.D1chIl=- propane (7&.87-5) ______18Vy. I ,3-DkNOto-propytene_(542-75-6) 19V. Ethylbarsone (100-41-4) 20V. Methyl BromIcie (74-63ý-9) ___ ____21V. Methyl Chloride (7A-87-3). El l]_ ______________ EPA Form 3510-2C (8-90)PAGE V-4 CONTINUE ON PAGE V-5 0 0, CONTINUED FROM PAGE V-4 2. MARK "X" 3. EFFLUENT 4. UNITS S. INTAKE (opJon..) .SPOLLUTANTD
- b. MAYJMUA 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND b. C.a. MAXIMUM DAILY VALUE Qrfaraoblk) vALUE (a.al CS/) A RGE VALUE CAS UMBR T~rIG BUEVD uu~vuý.. VLUEQ(ýllale)AVERAGE VALUE CAS NUMBER le TESTING BESEVEN BALBEVED .(1) CL1(1 ) NO. OF a. CONCEN- M (1) b. NO. OF (IoIa/,k)
REQUIRED PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION (21 MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION r MASS NALYSFS GO/MS FRACTION-VOLATILE COMPOUNDS (camnied)22V. Methylen[Chodde (75-09-2)23V. 1.1.2.2-TeaOc.lormetnann 24V.Tnetamehioto.-thyleno (1 27-18..-4) 25V. Toluene (108-88-3) 2EV. 1,2-Trans-DIchloroethylern, 27V. 1,1.1-TrIoNora-ethane (71-55-6)28V. 1.1 2-Trichloro-ethano (79-00-5)29V T-chloro-ethylene (79-01-.6) 30V. TrItchao-- fluoromethane 31V. Vinyl ChloridIe (75-01-4)GO/MS FRACTION-ACID COMPOUNDS 1Ak 2-ChIoropherilo 195&57-8)3A 2,4A. Dchioro-phenol (120-83-ý) 3A. 2,4Dimethyl-phienol (105--7-9) 4A. Crasol (534-52-1)
- 5. 2,4-Dinitfo-phenol (51-28-5)6A. 2-Nitroph cool (88-75-5)
_ ___7A. 4-Nltrophanol (100-02-7) B.k P-Chloro-M-Cresol (59-50-7)9A. Pentachloro-.Phenol 10M Phenol r (108-9&.2) 1 j ....ikA 2,4,S-Trichloro-ipnenol (88-05-o)EPA Form 3510-2C (B-90)PAGE V-5.CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2. MARK X" 3. EFFLUENT 4. UNITS S. INTAKE (oprnoW)i. POLLUTANT
- b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND a. b. , .MAXIMUM DAILY VALUE (if-ai/ble)
VALUE AVERAGE VALUE CAS NUMBER TESTING BELIEVED 0EUEVED ( (1) d. NO. OF a. CONCEN- b. NO. OF TESID BELIEVEDIMU BEAILYE VALU (1)noibc VAUtjaoJbc VRG AU REQUIRED PRESENT ABSENT CONCENTRATION (2Z MASS CONCENTRATION (12 MASS CONCENTRATiON (2) MASS ANALYSES TRATION bCON) MASS NALYSES oO/MS FRACMION-EASE/NEUTRAL COMPOUNDS 1B. Acenaphthono (B3-32-B) _28. Acenaphtylene (20"s-8-) ___ ____38. Anthra_.e.e (120-12-7)_....... 4B. Bert.idlne (92-87-5) ......,B. Bsnzo (q)Anthracene (56.55-3) _____6B. Boenzo (o)Pymne (50-32-8)78. 3,4-Berizo-,fluoranthene (205-99-2) 3B. Benzo (ghi)perylene (191-24-2) ,.99. Benno (A-)Fluormnthc e (207-08-9) 108. sts (2-C/rio,-Methane (111-91-1) 11 B. B~s (?-Chtorvo-,e.y,) Ether (111-44-4) 128. Bis (2-Ckbo'olsop.otpyd/) Ether(102-80-1) 13S, Bis (2-Et.hv-hu3't) Phthalate (1 IT-81-7)148. 4-Bromopheny! phenyl Ether (1 01-65-3) ____ _________158, Butyl Bentzyl Phthalate (85-M8-7)16B. 2-Chloro-naphtholono (91-58-7)171. 4-Chforo-phenyl Phenyl Ether (7005-72-3) 188. Chrysene (218.-Cl-9) ____ ___198. O0benzo (ah)Anthracene 953-70-3) ......208. 1,2-Dichloro-benzene (95-50-1)218. 1.3-DI-chloro-benzene (541-73-1) _____________ EPA Form 3510-20 (B-90)PAGE V-6 CON11NUE ON PAGE V-7 0 S CONTINUED FROM PAGE V-6 2. MARKW I" 3. EFFLUENT 1 4. UNITS 1 5. INTAKE (ovdofl)I. POLLUTANT
- b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND a b .a. MAXJMUM DAILY VALUE (ifamsilable)
VALUE AVERAGE VALUE CAS NUMBER TESING BELIEVEO BEL!EVED (1') (1) (1 d. NO. OF a. CONCEN- b. NO. OF...... ECUIRED PRESENT ABSENT COOCENTRATION1 NCENTRA'ION (2) MASS CONCENTRTION
- 12) MASS ANALYSES TRATION b. MASS CONCEITRAION
- 12) ,S ALYSES (I'~olbl)
I EURE REET BET (2) MASS CONTA1....TRT MS GCDMS FRACTION-BASE/N ELTRAL COMPOUNDS (conitinc-a) 22B. 1 ,4-ihD oro-benzene (106-46-71 238. 3,3-DIchloro-benrz1dino (91-94-1)248. Dlethyl Phthalate (84.66-2)25B. OIlmethyl Phtholate (131-11-3) 268. Di-N-Eutyl Phthalate (84-74-Z)278. 2.4-Dinitro-toluone (121-14-2) 288. 2.6-DInIto-toluene (606-20-2) 298. DI-N-Ocly Phlhalate (117.4-0)308.1 2-.Ophenyt-hydrazine (as Azo-benzene) (022-58-7) 31B. Fluoranthene (206-44-C) 32B. Fluorene (848-73-71 .... _33B. Hexac=rtoro-benzene (118-74-1) 348. Hexachloro-butadlene (87-68-3)358. Hexachloro-cyclopentadlene (7747-4)36B Hexachltoro-ethane (67.72-1)378. Indeno (1,2,3-.cd Pyrene 388. Isophorone 39B. (91-20-3)40B. Nltrobenzene (98.95.3)41B. N-Nitro-sodlrnethylamine (62-75-9)22. N-Nirosop -N-Propylarnlno 4(S21-64-7) EPA Form 3610-2C (8-90)PAG EV-7 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2..MARK "X* 3, EFFLUENT 4. UNITS 5:. INTAKE (opt/onrn)
- 1. POLLUTANT
- b. MAXIMUM 30 DAY VALUE a. LONG TERM AVRG. a. LONG TERM AND b. a. MAXIMUM DAILY VALUE (ifm-allab/e)
VALUE (Qf tvaIdabtc) AVERAGE VALUE CAS NUMBER TESTING BEUEVSD ]BELIEVE0 ) (1) d. NO. OF a. CONCEN- b. NO. OF ,f.vi~~bli) REQUIRED PRESENT ABSENT CONCENTTION. (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCEMTRATION (2)MASS ANALYSES GC/MS FRACTION -BASE/NEUTRAL COMPOUNDS (ýo,,imvd) 43B. N-Nttro-sodliphenylamine 448. Phenanthrone 458. Pyrene (129-00.0)
- _468.1.2,4-Tn-cnlorobenzene (120.82-1)
GC/MS FRACTION -PESTICIDES IP. Aldrdn (309-00-2) 2P. a-BHC (319-84-6) 3P. 1"-EHN (319 57)4P. y.BHC (58-89-B)5P. 5-HC (319-86-8) SP. Chlordane (57-74-9)7P. 4.4'-DT (50-29-3)8P. ,4.-DDE C72-5-5-9) ___ ______ _ ____9P. 4.4'-DoD (72-54-8)1OP. Dleldn"in (80-57.1)"____ 11P. a-Enosulfan (11 S-29-7)12?. p-E~n~osu95n 13P. Erndsulfzn Sulrate (1 c31-07-8)14P. Eddndn (72-20-8)15P. Endrin Aldehyde 1OP. Hept~chlor ('7E-44-E) EPA Form 3510-2.C (S-90)PAG E V--8 CONTINUE ON PAGE V-9 0.EPA I.D. NUMBER (copyfrom 1mmn I! oFormn 1) OUTFALL NUMBER 0H0003786 601 CONTINUED FROM PAGE V-8 I -2. MARKX "X 3. EFFLUENT 4. UNITS 1 5. INTAKE (opitowli 2. MARK'X* I 1. POLLUTANT I b. MAXIMUM 30 DAY VALUE _ LONG TERM AVRG.AND a. b. .a. MAXIMUM DAILY VALUE (i/failable) VALUE (ftvoltable) CAS NUMBER TESTING BELIEVED BEUE:VED (1) ` (2) MAS (1) i 12) S (ITRATION 1 (2)1MASS (0 ffvaJlcb) REQUIRED PRESENT ABSENT CONCENTRATION CONCENTRATION CONCEN a. LONG TERM AVERAGE VALUE d. NO. OF a. CONCEN- AV " b. NO. OF ANALYSES TRATION b. MASS CONCENTRATION ,2 MASS NALYSES GU/MS FRACTION -PESTICIDES (contlnc4 17P. Heplachlor Epodde 11024,,7-3) 18P. PCB-1242 (53469-21,,-s) 19P. PCS-12-4 (11097-69-1) 20P. P45-1221 21 P. p CB-1 232 (11141 -1 6-9)22P. PCB-1248 (12672-2M-) 23P. PCB-1260 (I1 ,0 9 -8 2 -5 )24P. PCS-1016 (12674-11-2) 25P. Toxaphen¢(6001-35-2) EPA Form 3510-2C (8-90)PAG E V-9 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of this informatIon EPA I.D. NUMBER (copv/fom/ 1)on separate sheets (use the same fornat) Instead of completing these pages. OR0 000378" SEE INSTRUCTIONS.I .I V. INTAKE AND EFFLUENT CHARACTERISTICS (contlnuedfrom page 3 of Form 2-C))-UTFALL NO.02 PART A -You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each ouffaiL See instructions for additiohal details.3. UNITS 4. INTAKE 2. EFFLUENT (ap~cifyiJ b/on/r (op0lonni)
- b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM a. MAXIMUM DAILY VALUE (if uoooblr) (d. Nvaiaable)
AVERAGE VALUE (1. (1) d. NO. OF a. CONCEN- ( I. b. NO. OF 1. POLLUTANT CONCENTRATION (2) MASS CONCENTRATION (2) MASS (1) CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSES a. Biochemical Oxygen 45 241 tgi k/a Demand (BOD) 4.5 2.4 -mg/1 kg/dey X b. ChemicaJ Oxygen Demand (COD) <20 -- I M9/1 kg/cay r. Total Organic Carbon (cTOr 2.89 1.53 1 m9g/ kg/day X d. Total Suspended Sollds.() 8 4.2 1 mg/i kg/day X e.Am'monia(asN) <0. , -- I Mg/i kg/day VALUE VALUE VALUE VALUE f.Flow 0.14 24 mgd kg/day.T.emperature VALUE VALUE VALUE VALUE (winte,) _h. Temperature VALUE VALUE VALUE VALUE (smmr) 2 .5C MINIMUM MAXIMUM MINIMUM MAXIMU 7.. 8.3 4 STANDARD UNITS PART B- Mark "X* in column 2-a for each pollutant you know or have reason to believe is present. Mark "X' in column'2-b for each pollutant you believe to be absent. If yoau mark column 2a for any pollutant which is limited. ether directly, or indirectly but expressly, in an effluent limitations guidefine, you must provide the results of at least one analysis for that pollutant For other pollutants for.which you mark column 2a. you must provide quantitative data or an explanation of their presence In your discharge. Complete one table for each ouffall. See the instructlons for additonal details'and requirements.
- 2. MARK "X" 3. EFFLUENT 4. UNITS 5. INTAKE
- 1. POLLUTANT
- b. MAXIMUM 30 DAY VALUE r. LONG TERM AVRG. VALUE a. LONG TERM AVERAGE AND .a. MAXIMUM DAILY VALUE (If ovailab/l)
VALUE CAS NO. BBELIEV ELIDEEVED ( li (1) d. NO. OF a. CONCEN- b. NO. OF (ffmalable) PRESENT ASSENT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSES a. Bromide X <0.03 -- 1 mg/1 kg/dy (24959.6T-D) X b. Chlorne. Total Residual / <0.05 -- 4 mg/lI kg/dy c- Color X5 -- I Units kg/dy d. Fecal Coliform X8 4 perlO ml kg/dy e. Fluoride S69u4-48-8) X 0.41 0.22 1 mg/i kg/dy (trate.Hlaito X 3.29 2.75 1 mg/l kg/dy (as N) x______EPA Form 3510-20 (8-S2)PAGEV-1 CONTI'NUE ON REVERSE S! 0 S ITEM V-S CONTINUED FROM FRONT S2. 3. EFFLUENT 4. UNITS 5, INTAKE (optional) 1, POLLUTANT
- b. MAXIMUM 30 DAY VALUE c- LONG TERM AVRG. VALUE a. LONG TERM AND b. a. MAXIMUM DAILY VALUE (If ava[able) (I, alable) AVERAGE VALUE CAS NO. BELIEVED BELVED d. NO. OF a. CONCEN- b. ND. OF PRESENT ABSENT CONCENTRATION
- 12) MASS CONCENTRATION
- 12) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION 121 MASS ANALYSES TO= Organic (n <0.2a 1 mg/i kg/dy x h, Oil Dnd Grease<S.
-- 4 mg/i kg/dy 1. Phosphorus g 7T23-.14-0) I )g/1 kg/dy x J. Radloactlvliy (1) Alpha, Total (2) Beta, Total C3) Radium, Total.(4) Radium 226, Total Y-¢ Sulfate I= SO,) -7) x 366.7 194.6 1 mg/ kg/dy (* SOul ide I.Sulfide X <' -- 1 mg/i kg/dy m. Sulflite (-, SO.,) X <15 -- 1 mg/i kg/dy (14265-45-3) -n. Surfacants x <0.005 -- 1 mg/i kg/dy x o. Aluminum, Total V1 g/ k/d (7429-93.5) x 347 0.18 1 ug/1 kgldu p. Barium. Total 72 (7440-39-372 0.04 1 ug/1 kg/dy q. Boron, Total (7440-42-8) x 118 0.06 1 ug/I kg/dy r. Cobalt, Total (7440-48-4). .<. 0 -- I uY/1 kg/dy s. Iron, Total Xk4i o u/ sd 3-89-) 441 0.23 1 Ug/1 kg/dy t. MagnesJum. Total X 15550 8.251 1 ug/i kg/dy U. Molybdenum, Tota7 x <2.0 -- 1 ug/1 kg/dy i V. Manganese, Total X 13 0.01 1 ug/l kg/dy (7439-96-5) w."nn, Totan TotaX <1.0 -- 1 ug/1 kg/dy x (7440-32-6) _U__ _ .EPA Form 3510-2C (S-90)PAGE V-2 CONTINUE ON PAGE V-3 EPA LD. NUMBER (cop"from'n fle.m of'Form J) OUTFALL NUMBER OH0003786 602 I CIONTINUED FROM PAGE 3 OF FORM 2-C PART C -if you are a primary industry and this outfall contains process wastewater, refer to Table 2c-2 in the instructions to determine which of the GCIMS fractions you must test for. Mark "X" in column 2-a for all such GO/MS fractions that apply to your industry and for ALL toxic metals, cyanides. and total phenols. If you are not required to mark column 2-a (secondary Industries. nonprocess wastewater ouffalls, and nonrequked GO/MS fractons). mark X in column 2-b for each pollutant you know or have Mason to believe is present Mark 'X* in column 2-c for each pollutant you believe is absent If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant If you mark column 2b for any pollutant, you Must provide the results of at least one analysis for that pollutant if you know or have reason to belleve it will be discharged In concentrations ot 10 ppb or greater. If you mark column 2b for acrolein. ZCrylonitrile, 2,4 dinitrophenol, or 2-melhyl-4, 6 dinltrophenol, you must provide the results of at least one analysis for each of these pollutnts which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b. you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pages) for each outfall. See Instructions for additional details and requirements..
- 2. MARK'X 3. EFFLUENT 4. UNITS 5. INTAKE (oprionar)
- 1. POLLUTANT
- b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM CAS NUMBFR TESTING BELIEVED UELIEVEDLJ ) i' I) d. NO. OF a. CONCEN- b.b. NO. OP AND QUIREDc a.EEN MAXIMUM DNTATILVAU baelk-VLE (lfo'ailo AENRAGEVAU (ffovoallable)
REQUIRED PRESENT ABSENT CONCENTRATION )21 MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION 121 MASS ANALYSES METALS, CYANIDE. AND TOTAL PHENOLS .......1M.Anllmony,Total <B.0 I ugh kg/day (7440.3M.) ____ ___2M. Arsenic. Total 10 1 1 X < 0 -- i ug/ kg/day 174.4D-38-21 __ __3M. Beryllium. Tot2s cn.0 -1 ug/I kg/day (7440-41-7) X <:_.. 0 -- ___/__"/_4M. Cadmium. Total <1. 0 3. ugh kg/day (7440-43-9) ____I __I 5M. Chtrornum, X -<1 .0 -1 us/i kg/day Tota (7440.47-3) SlM. copper. Total lX <4.0 1 ug/. kg/day (7440-50-a)_______ 7M. Lead,Total 1 0.01 I ug/ 1 kg/day (7439-92-1) SM. Mercury, Tots <0.2 -- 1g/ kg/day (743-0-97-il) SM. Nickel TotalX <4.0 1- 1 ug/1 kg/day (7440-02-0) , X IOM. seleium. 55 0.03 1 ug/1 kg/day Total 17782-49-2) _IIM. Silver, Total 1 00 1g (7440-22-4) / 1 0.00 clay 12M. Thallu.M, 35 0.02 1 Ug/i kg/day Total (7440-28-0) .I 13M. Zinc, Tctal 14 0.01 1 ug/1 kg/day (7440-,6-6) X 14M. Cyanid. <0.005 -- 4 mg/i kg/day Total (57-12-5) X _ .III 5M. Phenol$, <5. -- 4 ug/i kg/day Total DIOXIN 2,3.7,8-Tetra-DESCRIBE RESULTS olrorodlbenzo-P-Dioxin (17 4 6") T EPA Form 3510-20 (8-90)PAGE V-3 CONTINUE ON REVERSE S. S CONTINUED FROM THE FRONT 2. MARK"X" 3. EFFLUENT 4. UNITS 5. INTAKE (optional)
- 1. POLLUTANT
- b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND .b. C a. MAXIMUM DAILY VALUE (QfEavilabl.)
VALUE (Qfaviablc) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BEUEVED i) () ' d. NO. OF a. CONCEN- (1)b NO. OF Qtfvcllabte) RECUIRED PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATnCN (2),MASS CONCENTRATIONI (2) MASS ANALYSES TRATION b. MASS CONCENTRATION
- 12) MASS ANALYSES GC/MS FRACTION -VOLATILE COMPOUNDS IV. ACCroiefl
<25 g/i 1Ig kg/day (107-02.8) 2V. Acrylonrwle (107-1 3-1) x<25 -- 1 ug/l kg/'day 3V. Benze n (71-43-2) X <5.0 -- 1 ug/l kg/day 4V. SI (Chro,--ELher <5.0 ~- 1 ug/ kg/day (542-88-1) ____ ____SV. Bromoform (75-25-2) x 5,- ug/l kg/day 6V. Caroon .<.. .Tetrmchlodde <-C --/ g/day (56-23-5)7V. Chlorobenzene (10860-7) <5.0 --g BV. Chlorodl-bromromethaie, <5.0 -g/l kg/day SV. Chlimathnan (0.3) <5.0 -- 1 ug/l kg/day (75-00-3) ________ ___10V. 2-Chioo-etylnyllEther <5.D -- 1 ug/l kg/day ( 110-75-8)1 IV. Chloroform (67-66-3) x <5.0 -- 1 ug/ kg/day 12V. OlchlorO-bromomethae x <5.0 -- 1 ug/l kg/day ,( .DL,27 -.)1duoromehoone <5.0 -~ ug/1 kg/day 14V. 1,1-Dlchloro- <5.0 -- 1 ug/ kg/day ethone (75-34-3) x _s_0___________ 15JV. 1,2-D1Ieoro-x ugh kg/day ethane (10706-2) -0 _____1_/_16V. .1.-Ichloto- > <5.0 -- 1 ug/l kg/day ethylene (75-3&4)17V. 1.2-Dichloro-" prooane (78-B7-5) .' <5.0 -- 1 ug/! kg/day 18V. 1.3-DIchloro-propylane <5.0 "- 1 ug/1 kg/day (542-75-6) x 1EV. Ehtylbenzene <5.0 -- 1 ugl1 kg/ay (100-41_4) 20V. Methyl <5 kg/da Bronide (74-83-9) < I 21V. Methyl <5.0 -- 1 kg/la Chlodde (74-87.-3) < I I k EPA Form 3510-2C (8-9 0)PAGE V.-4 CONTINUE ON PAGE V-5 CONnNUED FROM PAGE V-2. MARK "X" 3. EFFLUENT 4. UNITS 5. INTAKE (optroncl)
- 1. POLLUTANT .b. MAXIIhUM 30 DAY. VALUE o. LONG TERM AVRG. a. LONG TERM AND a. b. a a. MAXIMUM DAlLY VALUE (0failablc)
VALUE AVERAGE VALUE CAS NUMBER TESTING BZUEVED SEUEVED (.) (1) (1) d. NO. OF a. CONCEN- b. NO.rflr~lble) REQUIRED PRESENT IASENT CONCENTRATION 213M MASS I CONCENTRATION (2 MASS CONCENpTsRATIN a"I MASS ANALYSES TRATION b. MASS P A ANALYSES.a-~~~~.IMS NC.--TON ------.--,,-,-,J--. GC/MS FRACTION -VOLATILE COMPOUNDS (conifimie Z2V. Methylnle <5.0 1 ug/ kg/day Chloride (75-09-2) ... .23V. 1.1,2.2-T(avl)Ioroeane <5.0 1 ug/l kg /day 24V. T eirachioro- <5.0 1 ug/ kg/day ethylene (127-1 8-4)25V. Tokleme <5.- 0 1 ug/1 -kg/day (108-88-3) x 26V. 1.2-Ttafl- <5.0 1 g/l kg/day (156.6"- -x ...... I.27V. 1.1.1-iTichlo <5.0 I ug/l kg/day ethane (715-55-6) x___ L_______28V .1.1 2 .T r tch lo rXg e <5.0 3. ug/ kg/day 29V Tfchlos)- X <5.0 u/1 k/y ethylene (7901-r) 1 uga /Iy 30V. Tdchloro.- fluorometane\/ X <5. 0 1 ucr/1 kcr/dav (7.1.rQ-A) I -. I 31V.VIrnyl Chlorie c<5.0 12 ug/1. kg/day GC/MS FRACTION -ACID COMPOUNDS 1 A. 2-ChlotoPhanol (95-57-8 I<10 1 ug/1 kg/day 2A. 2,4.Dlochloro- <10 1 ug/l kg/day phenol (120-83-2) _101_____3A. 2.4.Dileth)4-X <20 1 ug/2 kg/day phenol (105-87-9) x -_1______4A. 4,68-InltrO-0< Cresol (534-52-1) <50 ug/2 kg/day&k<50 1 ug/i kg/day phenol (51-28-5) x <50 u9/1 k9/day 6A. 2-Nittophenol Mk X N l<10 1 ug/1 kg/day 7A. 4-Ntrophenol <50 2 ug/I kg/day (10o.-o2-7) 8.Phl _r"-M- X <50 1 u9/1 kg/day ctesol (59-50.7) _-.9X Penc Or u- k/day phenol (87 < 2 -C kd IOA. Phonol.(1 08-95-2) .1. ug/. kg/day 1 IA. 2,4.8-Trlchloo- <10 1 phenol (88-05-2) ...g/1 kg/dy EPA Form 3510-20 (8-90)PAGE V-6 CONTINUE ON REVERSE 49 0 CONTINUED FROM THE FRONT S 2. MARK X" 3. EFFLUENT 4. UNITS 5. INTAKE (opionl)1.POLLUTANT
- b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM CrAS NUMBER TESTNG EUQEIVED BEUEVED C RION MS T 1 2 C T 1) 0 FA R.ACON bEN .O ION b. NO. OF W -110, h',cl) R R D ASESE RT / ýFN CONCENlT)RATION
/ t2) MASS ICONCENTRATION (2) MASS CONCF.NlT)RA 'TI.ON 1(2) MAS S SE (Q,"O b A S CN CENTR AT ON {* 2) MASS {kA.AUYSES GC/MS FRACTION -BASEINEUTRAL COMPOUNDS ....._ _I B.Ac(n)phtheneo X C I'O// k-/a/y1 ______(83-32-9) X_____ =1 28. Acenaphtylene (20B-96-8) .</1 lkg/day 381R A nth n I --I I .. ... I I I I 48. -8e.z ...2, <50 -- 1 ug/h kg/day 4,3. 8enzidine 1 19 1 k (92.974) L I_ -- _ _0 5B. Benzo (a)Anthracenc X <10 -- 1 ug/l kg/day (56-55-3) 0 -- kg/da 6E8. (,) <10 -- 1 Ug/h kg'/day 88. Senzo (V)I' <10 -- lg/iL kg/day Pyrein (50-32-2)TB. 3,B-enzo-flumranthene X <1O -- 1 ug/l kg/day (2O5-gS-2)x
- 8. Benzo ( lhh Peryene (191-242) x <10 -- 1 ug/1 kg/day 98. ranthy ne1 <)0 -- 1 ug/L kg/day (2 708-9)x (111-91-1)_
1 2s. Bal (2-x <10 -- I ug/! kg/day 138. Bis (2-Eukl 4.hO Phtholate <10 I g/. kg/day (111744-7) 148. 4-,Bromo(h2e.y Phenyl Ether (<I -- 1 ug/l kg/day (101-55-3) _ _153. Butyl -sBenz 1836. 2.-Chloro-flo; Phthaltene <0i -- 1 ug/l , kg/day (91158-7) x 17B. 4-Chioro-phenyl Phenyl Ether 10 ug/ k x_<____ _/__1 15B. ChByl en ___ X <10 -uSg/ kg/day 198. Dlberzo (r.,)Anthalcene <I0 -- 1 ug/l kg/day 1(91-5&-7) ______bhen IPhnri (Eth0e1 <10 1-1 ugJ kg/dlay x _216.Choro- <10 -- 1 ug/l kg/day 1 ber9ane (ad-73-1)2E8. 1.o-Drcho o- 1-0 PAGE VOI NP V EPA Form 3510-2C (8-90)PAGE V-6 CONTINUE ON PAGE V-7 CONTINUED FROM PAGE V-6 2. MARK "X" .3. EFFLUENT T 4. UNITS 5. INTAKE (optpoa,)" 1. POLLUTANT
- b. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. a. LONG TERM AND .b. .a. MAXIMUM DAILY VALUE (if'a,.iloble)
VALUE Qfowj"ibl/) AVERAGE VALUE CAS NUMEER *IES11NG BEUEVED BELIEVED (1) (1) (11 d. NO. OF a CONCEN- (1) b.TNO.MOP ((fccvlloa!b) REQUIRED PRESENT" ABSENT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION
- 12) MASS 1ANALYSES TRATION b. MASS CONCENTRATION (2) MASS NALYSES GC/MS FRACTION -EASENEUTRAL COMPOUNDS (contilm4' 223.1.4-Dichoro-
<10 -- 1 ug/1 kgday benzene (I06.4S4) 6-x-.7 )0 _____23B. 3.3-Dichloro- <20 F benzldlfne (91-94-1) <20 -- L1 ug/ kg/day 248. Doetyl Phthalate (84-86.-2) x <10 -1 ug/1 kg/day 258. DimethyI Phthalato .(13111-) x <10 -- ug/ kg/day 26B. 01-N-Butyl <10 -- a ug/I kg/day Phlhafate (84-74-2) x 278. 2,4-.01nltro 1 toluefne (121-14.2) 10 --1 dg/1 kg/ day 288. 2.6-DInltro-1 y toluene (606-20.2) <i0 -- 1 Ug/1 kg/day 298. DI-N-Octyl Phthalatc (117-84-0) x<1 -- 1 ug/1 kg/day 308. 1.2-Olphenyl-hydrazine (asAzO- <50 -- 1 Ug/1 kg/day benzene) (122-68-7) 31B. Ruoranthene (20644-0) x <1 0 -- 1 ug/1 kg/day 32,8. Plu or'ene--<10 -- 1 ug/1 kg/day 33B. HNnachloro-X benzene (118.74-1) <10 -- _U/ kg/day 346. Hexachloro-- butaiiene (8788-36) x <10 -- 1 ug/l kg/day 358. Hexachloro-cyclopontadleno <10 -- 1 ug/1 kg/day Cr7-47-4) x _368 Hexachloro- <10 1 u1/1 kg/day ethane (67-72-1)' <378. Indono (1, Z3-c Pyrene <10 -- 1 ug/i kg/day (193-.3.5) , ..388. IsophoroneX (785.1) <10 --I ug/_ _ kq/da 396. Naphthalene (91-20-3) x <10 -- 1 ug/1 kg/day 413 .Nitrobenzene 94B95Nb) < -- 1 ug/h kg/day 41B. N-Nizro-sod-me-hylamnan <10 -- 1 ug/l kg/dayý2-75-9) x____ ___ _______ _____________ 426. N-Propylamlno <10 -" 1 Ug/1 kg/day (621-64-7)0 EPA Fon'n 3510-2C (8-90)PAGE V-7 CONTINUE ON REVERSE S.1 0 CONTINUED FROM THE FRONT (2. MARK,)X" 3. EFFLUENT 4. UNITS 5. INTAKE 1. POLLUTANT
- b. MAXIMUM 30 DAYVALUE, c. LONG TERM AVRG. a. LONG TERM AND a. b. c. a. MAXIMUM DAILY VALUE (If v-alab/k)
VALUE (tfavailable) OF AVERAGE VALUE CAS NUMBER TESTINS BEUEVED BELIEVED (1) [() (11 d. .OF a. CONCEN- b1) -NO. OF (if oaable) REOuiRED PRESENT ABSENT CONCENTRATION 121MASS CONCENTRATION 12)MASS. CONCENTRATIONý () p LYSES ON b. MASS CONOCTRATION (2) MASS ANALYSES (ifa~aifabl..... ... .... L r-SESMSýGC/MS FRACTION -BASEINEUTRAL COMPOUNDS (c:ioviea) _38 N-11Nltro-socilprleylail Ix I<10 uglh Ikg/&ay I 448-. PheanhronC 10 -- 1 ug/l kg/day (65-.01-8) x _______ _____ _____45B. Pyrene (I 29-00-0) x <10 -- 1 ug/1 kg/day 468.1.2.4-Tr-chlorobenzene X <10 -- .ug/1 kg/day (120-82-1) GC/MS FRACTION -PESTICIDES 1 P. Aldrnn (309-00-2) 2P. a-BHC 121 9-84.8) _____3P. Pý-BHC (31 9-85-7)4P. y-BHC (5&-89-9)SP. ,-BHC (319-B"-B) 6P. Chlordane (57.74-9)7P. 4,4-.DT " (50-29-3)SP. 4.4!-DDE (72-55-9) _9P. 4,4-ODDO (7Z-54B)lOP. Olelddn 11P.a-Enosuc*an 12P. 1-Endosulfan (115-29-7) 1 1 1 _13P. Endosulfan Sulfate (1031-07-.8) .______14P. Endrin (72-20-8)15P. Ehdin Aldehyde (7421-93-4) _16P. Heptachlor (7-)44-8)EPA Form 3510-2C (5-90)PAGE V-8 CONTI N U E ON PAGE V-9 EPA 1.0. NUMBER (copyfrom Iti I of 1orm 1) OUTFALL NUMBER 01H0003786 602 CONTINUED FROM PAGE V-8 2- MARK'X" 3. EFFLUENT 4. UNITS S. INTAKE (opljoo)1. POLLUTANT
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a. LONG TERM AND Z. a MAXIMUM DAILY VALUE (ifallable)
VALUE Q(afolvblc) AVERAGE VALUE CAS NUMBER TESING BEUEV'ED BELIEVED (1) (1) I d. NO. OF a. CONCEN- (1) b. NO. OF (),fo.-a1Icb/e) RECUIREl PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATIONt (2) MASS CONCENTRATION MASS ANALYSES TRATION tb. MASS CONCE NTRATION 12 MASS ANALYES GCJMS FRACTION -PESTICIDES (conrlnua 17P. Heptachlor EpOxIde (1024-57-3) 1ISP. PC8-1242 (5349.21 -9)19P. PC0-1254 (11097-69-1) TOP. PCf-1221 (11104-28-2) 21P, P01-1232 (111 41-16-5) ___22P. PCSB-248 (12672-2&-s) 23P. PCE-1260 24P. PCB-101S (12674-11-2) 25P. Togaphornc (8001.35-2) ____________ ____ ___EPA Form 3510-2C (8-90)PAGE V-9 S 0 S PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of this information EPA I.D. NUMBER (ceolfram Iieam I ofForm I)on separate sheets (use the same foimat) Instead of completing these pages. 'R0 003786 SEE INSTRUCTIONS. V. INTAKE AND EFFLUENT CHARACTERISTICS (continuedfroom page 3 of Form 2-C)OUTFALL NO.,01.PART A -You must provide the result5 of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details.3. UNITS 4. INTAKE 2. EFFLUENT (Specfy 0fblan"k) (op1iono)b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a.LONGTERM
- a. MAXIMUM DAILY VALUE (iQf'-ilablb) (Wcvaileblc)
AVERAGE VALUE (1) Idl t. NO. OF a. CONCEN- Ill b. NO. OF 1. POLLUTANT CONCENTRATION 121 MASS CONCENTRATION (21 MASS (1,) CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION C21 MASS ANALYSES a. Biochemical Oxygen 8-7 1 Tog/i kg/day Demand (BOD)b. Chemical Oxygen Demand (COD) <20 1 Mg/1 kg/day r. Total Organic Carbon (TOn 4.06 Mg/1 kg/day d. Total Suspended 17..Solids ( &9') 17 1img/i kg/day e. Anmonia ( AN) <0.1 I mg/1 kg/day VALUE VALUE VALUE f. Fow 40 Mgd kg/day g,Ternperature VALUE VALUE VALUE VALUE h. Temperature VALUE VALUE VALUE VALUE (swmncr- 2 2.4 ," 63L pH 8M 1 M 4 STANDARD UNITS PART B -Mark "X" in column 2-a for each polluant you know or have reason to believe as present. Mark X" in column 2-b for each pollutant you believe to be absent If you mark column 2a for any pollutant wN6icl i1 limited either directly, or indirectly but expressly, in an effluent lim'itaftons gudeldne, you must provIde the resuts of at least one analysis for that pollutant For other pollutants for wh'ch you mark column 2z, you must provide quantitative data or an explanation of their presence in your discharge. Complete one tablefor eack, outrfall. See the Instructions for additional details and requirements.
- 2. MARK X" 3. EFFLUENT __4. UNITS 5. INTAKE (opilol)1. POLLUTANT
- b. MAXIMUM 30 DAY VALUE o. LONG TERM AVRG. VALUE a, LONG TERM AVERAGE AND a. b. a. MAXIMUM DAILY VALUE (falable (ifavalLable)
VALUE CAS NO. BEUEVED BELIEVED CL) NO. OF a. CONCEN-. b. NO. OF CONCENTRATION PREEN ASSES (O1)RTQ 2)MS ()MS ( llab)CONCENTRATION ) MASS CONCENTRATION 121 MASS CONCENTRATION (2 M ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSES a. Bromide (2495--9) <0.03 1 mg/i kg/dy b. Chlorine, Totla <0.0S 4 mg/l kg/dy Residual IiI c. Co"or X 10 1 units kg/dy d. Fecal Coliform X .3 4 perlOOtl kg/dy e. Fluoride (1t698"8-8) 0.198 1 rag/! kg/dy f. NItrate-Nitritre 1.23 1 g/i kg/dy 1(asm I EPA Form 3510-20 (8-90)PAGE V'-1 CONTINUE ON REVERSE ITEM V-B CONTINUED FROM FRONT 2. MARK "X" 3. EFFLUENT 4. UNITS 5. INTAKE (oprioralO
- 1. POLLUTANT
- b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM AND b. a. MAXIMUM DAILY VALUE (f/7aitable)
AVERAGEVALUE CAS NO. SEUEVED BELIEVED (1) d() (1) d. NO. OF a. CONCEN- (1) b. NO. OF (1fao cllable) PRESENT ABSENT CONCSNTRATION
- 12) MASS CONCENTRATION C2) MASS cONcENTRATION (2) MASS ANALYSES TRATO b. M .ONCENTRATION (2) MASS ANALYSES g. Nitrogen.Total OrganIc (a 0.5 1 mg/i kg/dy m x I I. ODI and <5.0 4 mg/i kg/dy Grooso 1. Phosphorus (as P). Total 0.078 1 mg/i kg/dy 7723-14-1)
J. Radloadvlty
- (1) Alpha, Total (2) Beto, Total (2) Radlum.Total (4) Radlumn 226, Tot k. Sulfate (Ay SO,) 'V 31.8 1 mg/1 kg/dy (I (4808-7M-)
...,....l.I d 45 <79.0/\ mg/i kg/dy LSuXllde <10 1 mg/1 kg/dy (a S) ____to. Sulfito (as SOJ) <i5 I mg/i kg/dy (14265-45-3) x n. Surfacants X 0.000 1. mg/i kg/dy o. Adutnlnurm, 308 1 ug/i kg/du p. Barium, Total/ d (7440-39-3) x 29 1 Ug/_ kg/dy c. Boron. Total (7440424-) X <75 1 ug/l k/dy r. Cobalt Toal.(7440-48-4) x <1. 0 1 ug/l kg/dy s. Iron. Total 374 !. Ug/1 kg/dy (7449-S-6_) _t. Magnesium. Total x 11854 ! U/' kg/dy (7439-9 -4g)uL Motybdenum. Total X <2.0 1 ug/i kg/dy (7439-98-7) .v. Total ~ Y-(7439-9T-o ) x 14 1 Ug/1 kg/dy w. Tin.Ttal X <4 1 Ug/I kg/dy[ýITin, Ton, x. Thtan~um.aTotal 3 1 Utg/i kg/dy'.40..32-6) .-EPA Form 3510-2C (8-90)PAGE V-2 CONTINUE ON PAGE V-3 S S 0 0 EPA I.D. NUMBER (cop.fromlitem I oqfFonn J) OUTFALL NUMBER OH0003786 801 CONTINUED FROM PAGE 3 OF FORM 2-C PART C -if you are a primary Industry and this outfall contains process wastewater, refer to Table 2c-2 in the instructions to determine which of the GCJMS fractions you must lest for. Mark 'X' in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2-a (secondary indutstes, nonprocess wastewater outfalls, and nonrequired GCIMS fractions), mark WX In column 2-b for each pollutant you know or have reason to believe is present Mark "X) in column 2-c for each pollutant you believe Is absent. If you mark column 2a for any pollutant, you must provide tie results of at least one analysis for that pollutant If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant if you know or have reason to believe It will be discharged In concentrations of 10 ppb or greater. If you mark column 2b for acrolein, acrylonitae, 2,4 dinitrophenol, or 2-methyl-4, 6 dlnltrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b, you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part: please review each carefully. Complete one table (all 7 pages) for each outfat.. See Instructions for additional details and requirements.
- 2. MARKX .. 3.EFFLUENT
- 4. UNITS 5. INTAKE (opiloni)" 1. POLLUTANT Ib. MAXIMUM 30 DAY VALUE c0. LONG TERM AVRG. a. LONS TERM AND ...a.MAXIMUJM DAILY VALUE (ff-, alea1) VALUE [ivai/abfc)
AVERAGEVLU CAS NUMBER TESTING BELIEVED BELIEVED ' d. NO. OF a. CONCEN- b. NO. OF (if.ovallable) REQUIRED PRESENT ABSENT CONCENTRATION (2ý MASS CONCENT)RATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION 121 MASS ANALYSES METALS, CYANIDE, AND TOTAL PHENOLS 1 M. Antimony. Total 1< 0 1 Ug/! kg/day (7440-36-0) 2M. Arsenli. Total (7440-13-2) 1 ug/ kg/day 3M. Beryllium, Total (7440-41-7) X <1.0 ug/l kg/day'4M. Cadmium, Total <1. 0 t Ug/i kg/day (7440-43-9) .5M. Chromium.Total (7440-47-3) X1 ug/9/ kg/day EM. Copper, Total (7440-50-) X1 ug/i kg/day 7M. Load. Total 7 1 ug/1 kg/day (7439-92-1) g 8M. Mercury, Total 1 Ua/i kg/day (7439-97-q) X _ <0. 2_ 1_ ________cla SM. Nlckcl, Total <4.0 1 ug/1' kg/day (7440-02-0) I0M. Sclenlum., 17 1 tg/i kg/day ToWl (7782-40-2) X IIM. Silvor, Total 1 ug/ kg/day (744 o-22-4) X ....12M. Thallium, 1 ta/i kg/day Total (7440-28-) _ X_ _. _ _ _u_/l_ _g/d-13M. Zinc, Total 12 ug/h kg/day (7440-66-6) 14M. Cyanldc, 4m i gd Total (57-12-5) X <0. 005 4 mg/l kg/day 15M. Phenols, 4 tg/i kg/day Total 0 g k/a DIOXIN 2,3.7,8-T eua- DESCRIBE RESULTS Dioxcin (1764-01-6.) EPA Form 3510-2C (8.-90)PAG EV-3 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2. MARK"X" 3. EFFLUENT 4. U NITS 5. INTAKE (apponoo)1. POLLUTANT ]b. MAIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND a. b. m a. MAXIMUM DAILY VALUE *(if/,iloabl) VALUE (.f avolable) AVERAGE VALUE CASNUMBER TESnNG BELIEVED BELEVED -1 (1I d. NO. OF a. CONCEN- .. NO. OF ((avallabl) REQuIREO, PRESENT ABSENT CONCENTRATION (2) MASS MASS CONCENTRTION
- 12) MASS ANALYSES TRATION b. MASS CONCETiON (2I MASS ANALYSES GC/MS FRACTION -VOLATILE COMPOUNDS lvA~~n<25 ug/2 kg/day (107-02-8)
........... 2V. Acrylonit rl"c (107-13-1) X <25 ug!/1 kg/day (0-7.13-Il , ___5.0__1__/lk/_a 3V. Benzene (71-43-2) x <5.0 I ug/h kg/day 4V. BIs (Cklaoro--tkv. E_.er <5.0 I ug/h kg/day (542-88-1) 5v. Bromoform <so 1 ug/ kg/day (75-25-2) x <5.0 ug/__ ______6V. Carbon Teatramhlodde A <50 1 ug/ kg/day (58-2z3-5) .....__ __7V. Chlorobenzene x <5 0 1 ug/ kg/day (108-60-7) __BV. Chlorodl-bromome.thae <5.0 ug/l k9/day (124-48-1) OV. Chloroethane (75-00-3) X <5.0 ug/l )sg/day 1oV. 2-Chloro-ihylrvnyt Ethmer A <5.0 1 ug/ kg/day (110-7"-) ____ _______1IV. Chlorolorm (67-66-3) x <5.0 1 ug/l kg/day 12V. DIchI.oro-bromometheno A <5.0 I ug/l kg/day (75-27-4)13V. Dlchloro-dmuorome8hane <5.0I 1 ug/l kg/day (75-7T-8) -.-14V. 1.1-Dlchloro- <5.0 1 ug/l kg/day thane (75-34-3) x <0_k/l 15V. 1.2-0lohloro-5 ethylene (75-35.4) x <5.0 1 ug/1 kg/day 1'7V. 1,1-D1¢hloro- <5.0 I ug/l kg/day propane (78-87-5) x I1SV. 1.3-DilchIoro-propylone <5.0 1 ug/1 kg/day (542-75-q) (100-41-4) X <. sl k/a 20V.MEtylb <5.0 1 ug/1 kg/day BromIdCle (74-83-9) _ _V " 21V. Methyl I ug/1 k9/day Chlode (7"7-3) X << L5.00 u_ k EPA Form 3510-2C (8-90)PAGE V.-4 CONTINUE ON PAGE V-5 S 0. 0 0-"CONTINUED FROM PAGE V-4 2. MARK'X" 3. EFFLUENT 4. UNITS 5. INTAKE (qpuional) i, POLLUTANT
- b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND b. a. MAXIMUM DAILY VALUE (Ifevailable)
VALUE ('waloable) AVERAGE VALUE GAS NUMBER TESTING 8EUEVED BEUEVED (1) (1) (1) d. NO. OF a. CONCEN- b. NO. OF ((ffaltoble) REQUIRED PRESENT ASSENT CONCENTRATION 1 (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS AZLYSES TRA71ON b. ASS CONCENTRATION MSS NALYSES GCIMS FRACTION -VOLATILE COMPOUNDS (conimird) Chlojde C75-09-2) _________________________ __ ____I 23V. 1.1.22,2-I-T2v ttahLy~¶Jalen <5 1 u9/1 k/a Teb-chloethne 50 1 9/1 kg/day 24V. ToatmcNloro-1<5 0 1 ug/1 kg/day(127-18-4) " ,,,.25V. Toluene 50 1 ug/h kg/day (108-88-3) 2-v. icdoroethylene x 15- 0 1 ugl/ kg/day (155-60-5) .... .....27V. 1,.11-Trichloro-k epane (71-55-6) x <s. 0 ug/I ks/day 28.%'. 1.1 2-TrIchloro-1 ug.g/ a einane (78-00-5) x <5. 0 _u9/1 k/day 29V T(chlorO-i(co- <5.0 1 ug/1 kg/day 3-v. Trichloro-fltJoromethane <5.0 1 ug/ kg/day (75-684 __________ _______31V. Vinyl (ýnjoddo 31Vr0.A4) x <5. 0 1 ug/1 kg/day GC/MS FRACTION-ACID COMPOUNDS 57_<10 1 ug/1 kg/day (9 1 .... I ..1 A .2 -C h lo r o p h e n o l X < 10 1 u S/ k g/ d a y phb1OAS.28.4. 1 1 Ug/1 kg/day)neno[ x10561-9 ZA. 2.-Oihoroph-re'.ij k /a.-1 ug/l kg/day(1ý2:-"z-2I)-Dnt- 1 x <50 ug/1 kg/day hcesoI (53-52-1) ,.. _______pheno OI5l-2IO(O-1 ug/1 kg/day 6A. 2-8,11trophonol (sA XP<n 1 Ug/1 kg/day 7A. 4-tNitrophenol (100-2-7) x <)0 ug/l ks/day 8A. 2-Chiaro-1 ug/1 kg/day Crosol ...../I g/da 091r, PelcIr"X <50 I u9/1 kg/dcay Phen ol (180-05-)EPA Fh mn 35<- C 1D uP/A kV/SN R IA. 1,-1rlhoo-X 'I0 1 us/l kg/day EPA Form 3510-2C (8-90)PAGE V-5 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2. MARK"X" 3. EFFLUENT 4. UNITS 5. INTAKE (aptionadj I. POLLUTANT [b. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. '. LONG TERM AND a .c.. MAXIMUM DAILY VALUE (fafloablt) VALUE (I6,(mvlable) AVERAGE VALUE CAS NUMBER TESTING SEUEVLD BEUOVED (1) (d.N.OF a.CONCEN-
- b. NO. OF GC/MS FRACTION -BASEfNEUTRAL COMPOUNDS I B. ACerwphthene11 (83-32-9) x -O0 1 us/1 Ik/day, 2B. Acenaphrlene
<10 -- 1 Ug/ kg/day (20C896-8)
- 38. Anthracene (12<12-7) x <10 -- 1 ug/ kg/day 4s. serzJdlne, (9-8-. xes~n <50 I- ugh)I kg/day 5B. Benzo (a)Anthracaeru (5th56.3x
<10' -- 1 ug/I kg/day 68. Benrzo ()x <10 -- 1 ug/l kg/day Pyrene (50-32-8) I uN. I ___ ___78. 3,4-Benzco-nluoranlhene <10 -- 1 ug/ kg/day (205.99-2) x I _______ ____83. Baezo 10h1k Peryiene (191-24-2) x <-0 -1 Uq/I kg/day 98. Senzo (k)Fluoranthene <10 --1 ug/1 kg/day (207-08-9) x ug/ 1 kg/d 108. Bis (2..lrlre c./hax) Methane 1 5-9-) Me~x <10 -- 1 ug/1 kg/day 11 .Bis (2.Chl/ro. v/*,h) Ether <10 -- 1 ug/l kg/day (1 11-4") __ 1 g I k/a 12B. Bis (2-hLV/,o,'lseopmfepl) V < 10 --1 ug / 1 k / day Ether (10240-1) x 10_____13B. Bis (2.-EIIkr-heayO Phthlate <10 -- 1 ug/1 kg/day (11741-7) _______148.4-Bromophenyi Phenyt Ether <10 -- 1 Ug/ kg/day (101-55-3) 158. Butyl Bonzyl Phthsatle (85-68-7) x <10 --_ ! /I ks/day 1 88. 2-Chloro-naphthalene <10 -- 1 ug/1 kg/day (91-.58-7) x_____ <10___ _____ _______17s. 4.-Chlora-phenyl Phenyt Ether <10 -- 1 ug/l kg/day (7006-72.0) -<10_________ I 8B. Chrysene <10 (218-01-9) x 0 --l ug/I kg/day 198. Dlbenzo (,h))<10 -- 1 ug/1 kg/day 20be.ene <0 -- 1 ug/1 kg/day 218. 1.3-D,-nhloro-bernzene (541-73-1) x <10 L ug/I kg/day EPA Form 3510-2C (a-90)E V-6 CONTINUE ON PAGE V-7 CONTINUED FROM PAGE V-6 2. MARK"X" 3. EFFLUENT 4. UNITS 5. INTAKE (opdlonJ)1. POLLUTANT
- b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND a. a. MAXIMUM DAILY VALUE ((l[aailable)
VALUE (QfavailabLe) AVERAGE VALUE CAS NUMBER TESTING BELIEVEDBEUEVED (1) I (I) d. NO. OF a. CONCEN- (1) b. NO. OF (If Joa~oltlaý) REQUIRED PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATiON (2) MASS JANALYSES TRATION b. MASS CONCETRrATION (2) MASS ANALYSES GCIMS FRACTION -BAS2JNEUTRAL COMPOUNDS (contiwael)
- 22. .-DaXoa <10 -- 1 ug/ kg/day 22.3. 4.3-01chloro-benzene (106-46-7) 20 ug/. kg/dy 238. 3.3-Olchloro-
<2 -1 ug/). kg/day'24B. Dletyl d(a4-66-2) <10 -- I kg/day 258. Dimehtlyl Phthaloto <10 -- ! ug/l kg/day (131 3) .268. DI-N-But14 <10 -1 ug/ Phthalate (84-74-2) x 0 I I 2713. 2,4-D)litro-10 1g US1 g/dlay tolue tc (121-14-2) x<0 --28a. 2.6-oCltfo- <10 1 ug/) kg/day toluene (606-20-2) X <_0 -- 1 US/1 ks/day 298. g Phithalate (117-84-0) <10 -- 1 ug/) kg/day 30B. 1 .2-Dlphenyl-hydrazInc (asAzo- > <s0 -1 ug/2 kg/day benzene) (122-66-7) 319. Fluoranthene (20-6"00) x <10 -- 1 ug/ kg/day 22. Fluorene 0 (66-73-7) <10 -- 1 UI/1 kg/day 338, Hexoachlorc-1 benzenE (118-74-1) <10 -- 1 Ug/1 kg/day 348. Hexacr.hcloro. butadleno (87-68-3) x <10 -- 1 ug/L kg/day 359. Hexochloro-cyclopontadtlne <10 -- 1 ugh/ kg/day (77-47.-4) .368 Hexachloro-k ehane (97-72-1) <101 ug/l kglday 37B. Indeno (1.2,3-cd Pyrono <10 -- 1 ug/l kg/day (193-39-5) 388. lsophorono 1(7-59-1) X < I ug/l kg/day 39B. Naphthlene <10 ugh kg/day (91-20-3) ' I -40B. Nitrobenzene X (98-95-3) <I0 --Ug/_ kg/day 41a. N-Nitry-sodlmethylanlne <10 -- 1 Ug/1 kg/day (62-75.6) x 42B. N-Nltrosool-N.Propylmhtne X <10 -- 1 ugll kg/day (621-64-7) ( P EPA Form 3510-2C (8-90)PAG E V-7 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2. MARK"X " 3. EFFLUENT ....... 4. UNITS S. INTAKE (optiona)'
- 1. POLLUTANT
- b. MAXIMUM 30 DAY VALUE r. LONG TERM AVRG. ' a. LONG TERM AND ab. I a. MAXIMUM DAILY VALUE (If aoailable)
VALUE [fava/lable) AVERAGE VALUE CAS NUMBEER TESTiNG BEEIEVED BEIUEVED (1) 1 ((1) 1) d. NO. OF a. CONCEN- () b. NO, OF (/avaitZabl) REQUIRED PRESENT j ABSENT CONCENTEATION (2) MASS CONCENTRATION (2) MASS CONCEN(TRATION (21 MAS ANALYSES TRATION b. MASS CONCENTRATION I (2) MASS JANALYSES GC/MS FRACTION -BASE'NEUTRAL COMPOUNDS 438. N-Nitro- 1 spe.n <10 -- ug/1 kg/day 448. Phananthrenfe <10 1g/ kg/day 458. P5yrt- <10 ug/l kg/day (129-00-0) <10 -- 2 ug/ kg/day_468. 1,2.4-TII-ahlomoberiet' <10 (120-82-1) <2.0 --k9. ug/GO/MS FRACTION -PESTICIDES IP.Aiddn (309-00-2) ....2P. a-BHC (319-84-8) __ ____3P. .-NHOC (319-85-7) _ __4P. 7-BHC (58-89-9)SP. HC (319-8"-) ______sP. Chlordan1e (57-74-9)7P. 4,4"-DDT (50-29-3)8P. 4.4"-0DD (72-55-9)SP. 4,4"-DD (732--8)lopP. Dieldrin (80-51-1) ____11P. a.Enosu~tan (I 15-29-7)12P. A-Erdosu fan (I 1I 7)13P. Endosulfan Sulfate (1031-07-8) 14P. Endrn (72-20-8)1 5P. Enrdrin Aidehyde (7421-93.4) 16P. Heptachlor (78-4-4-8) __________ ____EPA Form 3510-2C (8-90)PAGE V-8 CONTINUE ON PAGE V-9 0-0 0 0 I EPA I.D. NUMBER (copyfrom Item I ofFonm 1) O UTFALL NUMBER 0H0003786 801 I FROIM V-S 2. MARK X 3. EFFLUENT 4. UNITS 5. INTAKE (optional)
- 1. POLLUTANT'
- b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND a. b. .a. MAXIM U M DAILY VALU E (0f viZlable)
VALUE (If available) AVERAGE VALUE CAS NUMBER TESTING .EUEVFD BEUEVED (1) d. NO. OF a. CONCEN- b. NO. OF (2 avalrable) REDUIRED PRESENT AESENT CONCNTRATION (2) MASS CONCNTRATION (2) MASS CONCENTRATION 2)MASS ANALYSES TRATON .MASS CCNCERA'rl0,r" i)SS ANALYSES GCIMS FRACTION -PESTICIDES (condlnue.4 1TP. Heptachlr (1024-57-3) loP. P08-1242 (53469-21_9) TSP. PCB.- 254 (11097-69-1) 20P. PCB-1221 (11104.-28-2) 21P. PC8-1232 (11141-16-6) 22P'. PCE.-124, (12672-29-6)"_ 23P. PCB-1260 (1109r-82-5) 24P. PC0-1016 (12674-11-2) o;-5.-Toxaphcn. (6001-35-2) j____________-FPA Form 3510-2C (6w90)PAGE V-9 L-10-287 Enclosure C US EPA Form 2F for the Davis-Besse Nuclear Power Station NPDES Permit Renewal (13 pages follow) PAID(Number(copy fromlem I ofForfm 1)O0HO003786 'I Form Approved. OMB No. 2040-0086 Approv'al explires 5-31-92 Please orint or Wooe In the unshaded areas only.NPDES U.S. Environmental Protection Agency Washington, DC 20460 Application for Permit to Discharge Storm Water Discharges Associated with Industrial Activity Paperwork Reduction Act Notice Public reporting burden for this application Is estimated to average 28.6 hours per applicaton, Including time for reviewing Instructions, searching existing data sources, gathering end maintaining the data needed. and completing and reviewing the colection of Information, Send comments regarding the burden estimate, any other aspect of this cogection of Information, or suggestions for Improving this form, Including suggestions which may Increase or reduce this burden to: Chiel. Information Policy Branch, PM-223, U.S. Environmental Piotection Agency. 1200 Pennsylvania Avenue, NW, Washington, DC 20460, or Director, Office of Information and Regulatory Affairs, Oftice of Management and Budget, Washington, DQ 20503.I. Outfall Location For each outfall. list the latitude and lonoitude of Its location to the nearest 15 seconds and the name of the receiving water.A. Outfall Number D. Receiving Water (ist) B. Latitude C. Longitude (name)002 41 35 35 83 5 20 iPool 3 Navarre Marsh to Toussaint River 005 41 35 5 83 4 55 Pool 3 of Navarre Harsh ftTtITP)006 41 3S 50 83 5 5 Pool 1 of Navarre Marsh to Lake Erie IP&SG)IL. Improvements A. Are you now required by any Federal, State, or local authority to meat any Implementation schedule for the conslnrction, upgrading or operation of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described In this application? This Includes, but Is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters, stipulations, court orders, end grant or loan conditions.
- 2. Afected Outfalls 4. Finat 1. Identification of Condiltons, Compliance Date Agreements, Etc. number source of discharge
- 3. Brief Descdpti'on of Progeci a. req. b. proj.B: You may attach additional sheets describing any additional water pollution (or other environmental projects which may affect your discharges) you now have under way or which you plan. Indicate whether each program Is now under way or planned, and Indicate your actual or planned schedules for construction.
- 11. Site Drainage Map Attach a site map showing topography (or Indicating the outine of drainage areas served by the outfales(s) covered In the appirrcation it a topographic mapis unavailable) depicting the facility Including:
each of Its Intake and discharge structures; the drainage area of each storm water outfall; paved areas and buildings within the drainage area of each storm water outfall, each known past or present areas used for outdoor storage of disposal of significant materials, each existing structural control measure to reduce pollutants In storm water runoff, materials loading and access areas, areas where pesticides, herbicides, soil conditioners and fertilizers are applied; each of its hazardous waste treatmont, storage or disposal units (Including each area not required to have a RORA permit which Is used for accumulating hazardous waste under 40 CFR 262.34); each wen where fluids from the facility are Injected underground; springs, and other surface water bodies which received storm water discharges from the facility.EPA Form 3510-2F (1-92)Page 1 of 3 Continue on Page 2 I Continued from the Front[IV. Narrative Description of Pollutant Sources .A. For eads cuffell, potde an estimale d the area (include unIts) of imperious surfaces nctuinag paved areas and buiIdng roofs) drained to the oatl, and en e.Wimate of the total surface area drained by the outfall.Outran Area of Surface TotalAra Drahed Oueat Area of Imperlious Surface Total Area Orained NWuber (proVire Urs) (pronMe units) Nuanber proide un.ts) ,(rovide unis 002 -617,245 sq. ft. 5,120,478 sq.ft 005 88,000 sq. ft. 91,735 sq. ft.006 87,063 sq. ft. 155,886 sq. ft.B. Provide a narrative description of significant materials that are currently or In the past three years have been treated, stored or disposed In a manner to allow exposure to storm water-, method of treatment, storage, or disposal; past and present materials management practices employed to mintmlze contact by those matertals with storm waste runoff; materials loading and access areas, and the location, manner, and frequency In which pesticides, herbicides, soft conditioners, and fertilizers are applied.See Attachment A C. For each outfall. provide the location and a description of existing structural and nonstrucdural control measures to reduce pollutants In storm water runoff; and a description of the treatment the siorm water receives, Including the schedule and type of maintenance for control and treatment measures and the ultimate disposal of any solid or fluid wastes other than by discharge. Outtiall List Codes from Numbes Treatment Table 2F-1 002 Flotation/Sedimentation/Stabilization Pond L-H-Flotation 1-U-Sedimentation 3-O-Stabilizatlon 005 Discharge to Surfane Water 4-A-Discharge 006 Flotation/Sediaentstion 1-H-Flotation 1-U-Sedimentation V. Nonstornwater Discharges A. I certify under penally of law hat the outfall(s) covered by this application have been tested or evaluated for the presence of nonstormwater discharges, and that all nonstormyeater discharged from these outfall(s) are identified In etiher an accompanying Form 2C or From 2E application for the outfall.Name and official Tidea (type or pn'nt) "S~nature , Date Signed B. Provide a description ot the method used, the date of any testIng, and the onsite drainage points that were directly observed during a test.Ouctfall 002 has been evaluated for the presence of non-atorm water discharges based on observation of the outfall during dry weather conditions and examination of piping and site diagrams. No unidentified non-storm water sources were found for the WRTP (005) or P&SG (006) outfalls.f 1l. Significant Leaks or Spills Provide existing Iaformation regarding the history of significant leaks or spills of toxic or hazardous pellutants at the facility In the last three years, Including the date and location of the spill or leak and the type and amount of material released.rhere have been no significant leaks or spills of any toxic or hazardous pollutants at the Davis ensee Plantin the last three rears.EPA Form 3510-2F (1.92)Page 2 of 3 Continue on Page 3 Conflnued from Page 2 EPA 10 Number (copy from Item I of Form 1)OH0003766 I-VlI. Discharge Information -I ý .-A, B, C, & D: See Instructions before proceeding. Complete one set of tables for each oulfall. Annotate the outfall number In the space provided.Table VII-A, V1t-B; VIl-C are Included on separate sheets numbers VII-1 and VWl-2.E. Potential discharges not covered by analysts -Is any toxIc pollutant listed In table 2F-2, 2F-3, or 2F-4. a substance or a component of a substance whIch you currently use or manufacture as an Intermediate or final product or byproduct? [] Yes (list all such pollutants below) D- No (go to Section DO VIII. Biological Toxicity Testing Data Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water In relation to your discharge within the last 3 years?'[:] Yes (list ell such pollutants below) [] No (go to Section IX)IX, Contract Analysis Information ý iIOR 1; !!1,'1: Were any of the analyses reported In Item VII performed by a contract laboratory or consulting firm?El Yes (fist the name, address, end telephone number of, and pollulants No (go to Section X)analyzed by, each such laboratory orfimn below)A. Name B. Address C. Area Code & Phone No. 0. Pollutants Analyzed X. Certification I certify underpenally of law that this document and all attachments were prepared under my drectlon or supervision In accordance wnlh a system designed to assure that qualified personnel property gather and evaluate the Information submitted. Based on my Inquiry of the person or-persons who manage fhe system or those persons directly responsible for gathering the Information, the Informaifon submitted Is, to the best of my knowledge and befie!, true, accurate, end complete. 7 am aware that A. Name & Official Title (Type Of MnO ""B. Area Code and Phone No.Bar S. Ale, Sit V.P.- D.B. C'. Signature, 0 .Date Signed EPA Fr3502(1.92) Page 3 of 3 IoEPA ID Number (copy from Rlem 1 of Formn )10HO003786-SW Outfall 002 Form Approved. OMB No. 2040-0086 Approval expkies 56-31-92 VII. Discharge Information (Continued from page 3 of Form 2F)PartA -You must provide the msulls of at least one analysis for every pollutant In this table. Complete one tab!e for each oulfall. See Instructions for additional details.Maximum Values Arerage Values (enclude units) 17nclude units) Number Pollutant GiabSample Grob Sample of end Taken Durng Taken During Slorm CAS Number First 20 Flow-Waelghted First 20 Floiv-Welghted Events (if avallable) Minutes Composite Minutes Composite Sampled Sources of Pollutants Oi and Grease <s eq/! NA /A Biological Oxygen Demand (BOD5) 3.3 rrig/i Chemical Oxygen Demand (COD) 11.3 9'/1 Total Suspended Solids (TFS) 12 mg/l Total Nitrogen <0.20 rrg/ I Total Phosphorus <0.05 mg/I I pH blnlnmum 7.97 M3XImum 7. 97 Minimum Maximum I Pad B -List each pollutant that Is limited In an effluent guideline which the facility Is subject to or any pollutant listed in the facllily's NPDES permit for Its process wastewaler (if the facility Is operating under an existing NPDES permit). Complete one table far each outfall. See the Instructions for additional delails and requirements. Maximum Values Average Values (Include unils) (nctu do units) Number Pollutant Grab Sample Grab Sample of and Taken During Taken During Storm GAS Number First 20 Flow-Welghted First 20 Flow-Weighted Events (if avaMlable) Minutes Composite Minutes Composite Seampled Sources of Pollutanls Dies, Oxygen 7.6 ppm I TRC <0.0os g/i Fluoride 0.4 mg/l Aluminum 538 ug9/Arsenic <10 u9/l Barium 78 u9/i Boron 112 ug/l Copper <3 Ug/i Iron 471 ug/_Silver <5 ug/l AmnmOnia <0.2 mg/l<0.2 EPA Form 35`10-21' (1-92)Page VAi-1 Continue on Reverse I I EPA IO Number (copy [rom /loe I of Form 1) I PH0003786-SW Outfall 006 1 Form Approved. OMB No. 2040-0086 Approval expires 5-31-92 Vii. Discharge Information (Continued from pago 3 of Form 2F)Part A -You must provide the results of at least one analysis for every ootlutantIn this table. Complete one table for each outfall. See Instructions for additional details.Maximum Values " Average Values (laclude units) Jinclude units) Number Pollutant Grab Sample Grab Sample of and Taken During Taken During Storm CAS Number First 20 Flow-Weighted First 20 Flow-Weighted Events (if available) Minutas Composite Minutes Composite Sampled Sources of Polutants Oil and Grease <5 Mg/1 N/A I Biological Oxygen 9 ag/S..Demand (3005) 1.9 f/I Chemical Oxygen .' mg/l Demand (COD) 54 a/A Total Suspended Solids (SS) I57 ra/i Total Nitrogen 0.45 ag/I I Total Phosphorus 0.27 mrg/i pH Minimum 7.02 Maximum 7.02 Minimum Maximum Part 8 -List each pollulant that Is limited In an effluent guldeline which the facliuty Is subject to or any pollutant listed in the faclity's NPDES permit for Its process wastewaler (it the facility Is operating under an existing NPDES permit). Complete one table for each outfall. See the Instructions for additional details and Irequirements. Maximum Values Average Values flnc/udo units) (include units) Number Pollutant Grab Sample Grab Sample or and Taken During Taken During Steorm CAS Number First 20 FloW-Welghted First 20 Flow-Welghted Events (if available) Minutes Composite Minutes Composite Sampled Sources of Pofulants Dies. Oxygen 4.5 ppm 1 IRC 0.1 mrg/Fluoride 0.8 rg/I Alumrnum 1377 ug/l Arsenic <10 ug/l Bax. um 98 ug/l Boron 77 ug/l Copper 14 ug/_Iron 14706 ug/l Silver <1 ug/l ,nrreonia 0.8 mag/l TE o -1.2 Pog/l EPA Form 3510-217 (1-92)Page VIH-Continue on Reverse DAVIS-BESSE NUCLEAR POWER STATION 23 ?AA$9cKjdyAAlQt. UtE Jm(J1(ALL OVA OdIM'SIt AW4LX cAk~fI ~M. j-I SU1CEN UtEIIHIM dMIAd i-NpWIEW&alOLDaww S2. $MICE WILDIW4 -Z W?? WASM1 UflR nWWf~d KW31'SC USLDIC SrOWE TAW. (DIKEID)DIESE OIL.C W SIOdSSC lAXC W3XD)W "_ DJ..flED 6zrS um4 (lIKmn Fu I~I l I~L D4 dlS S1U V.535K No RUM= M135.104.95 OF JTFAL .5 STMd VATSS (OITFALLIII (MI8 -431 W= t ITM MADWC PLAY MM11 -~1AM 831F~AL IUT 13881 -KEIIS1TgJTd. PAMWd & S&G1CC J ATTACHMENT A Davis-Besse Nuclear Power Station EPA I.D.#: OH0003786 The following significant materials have been stored on-site within the last three years within the described stormwater discharge areas: 1. Outfall 002 (Training Center Pond Discharge)
- a. Chemnical Waste Storage Areas (CWSA)The CWSA is an enclosed structure with a curbed concrete pad to contain any potential leaks. The pad is divided into three separate sections as follows: 1)hazardous waste, 2) waste oil and non-hazardous wastes, and 3) chemical identification.
In the event of a large quantity leak, the flapper gates for the drainage ditch behind the facility can be closed to isolate the spill. Also, the CWSA is inspected on a weekly basis.b. Chemical Waste Accumulation Areas (CWAA)There are two CWAAs In this stormwater discharge area. These two CWAAs are only for diesel fuel. They each consist of two 55-gallon drums contained In the water-tight plastic storage containers.
- c. Sodium Hypochlorite (NaOCI) Tank The NaOCI tank, which Is located at the site water treatment plant, has a maximum capacity of 7,500 gallons and contains a 15% solution.
This tank has a dike structure designed to contain 115% of the tank capacity.d. Sodium Bromide (NaBr) Tank The NaBr tank, located at the Water Treatment Plant, has a 4,500 gallon capacity and contains a 43% solution. This tank has a dike structure designed to contain 110% of the tank capacity.Page .1 of 3 ATTACHMENT A Davis-Besse Nuclear Power Station EPA I.D.#: OH0003786 e, Oil Containment Oil Containment consists of the following: an I apacty Physical Cotrols Tank. Eqim n (g. ... ..Diesel Oil Storage Tank 100,000 Diked Emergency Diesel Generator 26000 each Collected in an Oil (EDG) Day Tanks I- Interceptor Emergency Diesel Generator 2-40,000 each None- Underground (EDG) Fuel Oil Storage Tanks I Miscellaneous Diesel Generator 750 Retaining Curb Day Tank I 5 _eaIningCurb Collected in Room Turbine-Generator (T-G) LubeColceinRm Tanks 2-14,000 each Sump and in an Oil TanksIi 6terceptor Main Feed Pump Turbine (MFPT) Collected In MFPT Lube Oil Tanks 2-1,200 Accumulation Pit MFPT Used Oil Tank 2,800 Collected in MFPT Accumulation Pit Drains to a 54,600 Main Transformer 24,000 Gallon Collection Tank Spare Main Transformer 24,000 Diked Station Blackout Generator Diesel Fuel Storage Tank 1,627 Diked Auxiliary Transformer 4,600 Drains to a 54,600 gallon collection tank Startup Transformer "10,700 Drains to a 54,600 gallon collection tank Spare Startup Transformer 16,500 Diked Bus Tie AC and BD Transformers 2-1,926 each Drains to a 54,600 gallon collection tank Lubricating Oil Drum Storage 22 55-gallon Retaining Curb Room drums Waste Oil Storage Tank 2,000 None-Underground Emergency Response Facility 8,000 None-Underground Diesel Generator Day Tank There are five oil interceptors which service plant drains and sumps entering the Outfall 002 Discharge System. Those storage tanks or equipment whose containments are not directly associated with the interceptors, would ultimately be serviced by an interceptor via adjacent plant floor and service drains. The underground storage tanks listed are not serviced by oil interceptors. Page 2 of 3 AT-ACHMENT R Davis-Besse Nuclear Power Station EPA I.D.#: OH0003786 2. Wastewater Treatment Plant (WWTP) Outfall Sodium Bisulfite (NaHS04) Tank The NaHSO4 tank, that is located near the station collection box, has a 900 gallon capacity and contains a 40% solution.3. Construction Parking and Service Building (P&SB) Outfall a. Diesel Fire Pump*Day Tank This tank has a 350 gallon maximum capacity and a retaining curb, which will contain any oil accumulations.
- b. Diesel Fuel Storage Tank and Gasoline Storage Tank Used to service fleet vehicles, the diesel fuel storage tank has a 1,000 gallon capacity, and the gasoline tank has a 2,000 gallon capacity.
They share the same concrete dike, which Is designed to contain 115% of the total capacity.c. Chemical Waste Accumulation Area (CWAA)This outfall area has one accumulation area for automotive oils and antifreeze. This CWAA is a self-contained unit designed with a spill pan underneath.
- 4. General Information In addition to the spill control methods mentioned above, the Site Spill Prevention Control and Countermeasure Plan, and Chemical Control Program are the primary directives for the control of significant materials.
Many personnel on site are HAZWOPER qualified to the technician level, which requires extensive training on spill prevention and mitigation. Also, in the event of a spill, spill kits are located at the designated areas throughout the site for easy access; these kits contain absorbent booms, pads, and personnel protective equipment. No pesticides, soil conditioners, or fertilizers are applied to any of these outfall areas.Page 3 of 3 I= Page 1 DIVISION OF SURFACE WATER Antidegradation Addendum In accordance with Ohio Administrative Code 3745-1-05 (Antidegradation), additional information may be required to complete your application for a permit to install or NPDES permit, For any application thrat may result in an increase in the level of pollutants being discharged (NPDES and/or PTI)or for which there might be activity taking place within a stream bed, the processing of the permit(s) may be required to go through procedures as outlined in the antidegradation rule. The rule outlines procedures for public notification and participation as well as procedures pertaining to the levels of review necessary. The levels of review necessary depend on the-degradation being considered/requested. The rule also outlines exclusions from portions of the application and review requirements and waivers that the Director may grant as specified in Section 3745-1-05(D) of the rule. Please complete the following questions. The answers provided will allow the Ohio EPA to determine if additional information is needed. All projects that require both an NPDES and PTI should submit both applications simultaneously to avoid going through the antidegradatibn process separately for each permit A. Applicant: Davis-Besse Nuclear Power Station Facility Owner: FirstEnergy Nuclear Generation Corp.Facility Location (city and county): Oak Harbor, Ottawa Application or Plans Prepared By: Scott F. Brown Project Name: Davis-Besse NPDES Permit Renewal NPDES Permit Number (if applicable): 21B00011 B. Antidegradation Applicability Is the application for? (check as many as apply): Application with no direct surface water discharge (Projects that do not meet the applicability section of 3745-1-05(B)I, i.e., on-site disposal, extensions of sanitary sewers, spray irrigation, indirect discharger to POTW, etc.). (Complete Section E)X Renewal NPDES application or PTI application with no requested increase in loading of currently permitted pollutants. (Complete Section E, Do not complete Sections C or D).PTI and NPDES application for a new wastewater treatment works that will discharge to a surface water. (Complete Sections C and E)An expansion/modification of an existing wastewater treatment works discharging to a surface water that will result in any of the following (PTI and NPDES):(Complete Sections C and E)addition of any pollutant not currently in the discharge, or an increase in mass or concentration of any pollutant currently in the discharge, or an increase in any current pollutant limitation in terms of mass or concentration. Click to clear all entered Information (on all 4 pages of this form) Page 2 PTI that involves placement of fill or installation of any portion of a sewerage system (i.e., sanitary sewers, pump stations, WWTP, etc,)within 150 feet of a stream bed. Please provide information requested on the stream evaluation addendum (i.e., number of stream crossings, fill placement, etc.) and complete Section E.Initial NPDES permit for an existing treatment works with a wastewater discharge prior to October 1, 1996. (Complete Sections D and E)Renewal NPDES permit or modification to an effective NPDES permit that will result in any of the following: (Complete Sections C and E)a new permit limitation for a pollutant that previously had no limitation, or an increase in any mass or concentration limitation of any pollutant that currently has a limitation. C. Antidegradation Information
- 1. Does the PTI and/or NPDES permit application meet an exclusion as outlined by OAC 3745-1-05(D)(1) of the Antidegradation rule?Yes (Complete Question C.2)No (Complete Questions C.3 and C.4)2. For projects that w6uld be eligible for exclusions provide the following information:
- a. Provide justification for the exclusion.
- b. Identify the substances to be discharged, including the amount of regulated pollutants to be discharged in terms of mass and concentration.
- c. A description of any cons truction work, fill or other structures to occur or be placed in or near a stream bed.3. Are you requesting a waiver as outlined by OAC 3745-1-05(D)
(2-7) of the Antidegradation rule?No Yes If you wish to pursue one of the waivers, please identify the waiver and submit the necessary information to support the request. Depending on the waiver requested, the information required under question C.4 may be required to complete the application.
- 4. For all projects that do not qualify for an exclusion a report must accompany this application evaluating the preferred design alternative, non-degradation alternatives, minimal degradation alternatives, and mitigative techniques/measures for the design and operation of the activity.
The information outlined below should be addressed in this report. If a waiver is requested, this section is still required.a. Describe the availability, cost effectiveness and technical feasibility of connecting to existing central or regional sewage collection and treatment facilities, including long range plans for Page 3 sewer service outlined in state or local water quality management planning documents and applicable facility planning documents.
- b. List and describe all government and/or privately sponsored conservation projects that may have been or will be specifically targeted to improve water quality or enhance recreational opportunities on the affected water resource.c. Provide a brief description below of all treatment/disposal alternatives evaluated for this application and their respective operational and maintenance needs. (If additional space is needed please attach additional sheets to the end of this addendum).
Preferred design alternative: Non-degradation alternative(s): Minimal degradation alternative(s): Mitigative technique/measure(s): At a minimum, the following information must be included in the report for each alternative evaluated.
- d. Outline of the treatment/disposal system evaluated, including the costs associated with the equipment, installation, and continued operation and maintenance.
- e. Identify the substances to be discharged, including the amount of regulated pollutants to be discharged in terms of mass and concentration.
- f. Describe the reliability of the treatment/disposal system, including but not limited to the possibility of recurring operation and maintenance difficulties that would lead to increased degradation.
- g. Describe any impacts to human health and the overall quality and value of the water resource.h. Describe and provide an estimate of the important social and economic benefits to be realized through this proposed project.Include the number and types of jobs created and tax revenues generated.
- i. Describe environmental benefits to be realized through this proposed project.j. Describe and provide an estimate of the social and economic benefits that may be lost as a result of this project. Include the impacts on commercial and recreational use of the water resource.)
Page 4 k. Describe the environmental benefits lost as a result of this project. Include the impact on the aquatic life, wildlife, threatened or endangered species.1. A description of any construction work, fill or other structures to occur or be placed in or near a stream bed.m. Provide any other information that may be useful in evaluating this application. D. Discharge Information
- 1. For treatment/disposal systems constructed pursuant to a previously issued Ohio EPA PTI, provide the following information:
PTI Number PTI Issuance Date Initial Date of Discharge 2. Has the appropriate NPDES permit application form been submitted including representative effluent data?Yes (go to E)No (see below)If no, submit the information as applicable under a OR b as follows: a. For entities discharging process wastewater attach a completed 2C form.*b. For entities discharging wastewater of domestic origin attach the results of at least one chemical analysis of the wastestream for all pollutants for which authorization to discharge is being requested and a measurement of the daily volume (gallons per day) of wastewaters being discharged. E. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief, true, accurate and complete.This section must be signedby the same responsible person who signed the accompanying permit application oir certification as per 40 CFR 122.22.Signature _______________ Date /dLa-If d/h;revtsed.,a' Jue 30, 1997 I View/Print Label 1. Print the label: Select the print icon in your PDF Reader window to print the label below.2.'Fold the printed label at the dotted line. Place the label in a UPS Shioing Pouch. If you do not have a pouch, affix the folded label using clear plastic shipping tape over the entire label.3. GETTING YOUR SHIPMENT TO UPS Customers without a Daily Pickup o Take this package to any location of The UPS Store, UPS Drop Box, UPS Customer Center, UPS Alliances (Office Depot or Staples) or Authorized Shipping Outlet near you or visit www.ups.com/content/us/en/index.jsx and select Drop Off.o Air shipments (including Worldwide Express and Expedited) can be picked up or dropped off. To schedule a pickup, or to find a drop-off location, select the Pickup or Drop-off icon from the UPS tool bar.Customers with a Daily Pickup o Your driver will pickup your shipment(s) as usual.FOLD HERE!}}