ML101440291
| ML101440291 | |
| Person / Time | |
|---|---|
| Site: | Salem, Hope Creek  |
| Issue date: | 04/29/2010 |
| From: | ARCADIS G&M, Public Service Enterprise Group |
| To: | Office of Nuclear Reactor Regulation, PSEG Services Corp |
| References | |
| LR-N10-0152, NP000603.0001 04-08-02-2350-16 | |
| Download: ML101440291 (486) | |
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{{#Wiki_filter:Remedial Investigation and Interim Remedial Action Report PSEG Nuclear, LLC Salem Generating Station Hancock's Bridge, New Jersey Incident No. 04-08-02-2350-16 June 2005 PREPARED FOR PSEG Services Corporation 80 Park Plaza Newark, NJ 07102 Remedial Investigation and Interim Remedial Action Report PSEG Nuclear, LLC Salem Generating Station Hancock's Bridge, New Jersey Incident No. 04-08-02-2350-16 Deric T. Kearns Scientist 11 Prepared for:PSEG Services Corporation 80 Park Plaza Newark, NJ 07102 Prepared by: ARCADIS G&M, Inc.6 Terry Drive, Suite 300 New town, Pennsylvania 18940 Tel 267 685 1800 Fax 267 685 1801 Bradley D. Pierce Project Scientist Our Ref.NP000603.0001 Peter N. Milionis, PG Project Manager Date: June 2005 This document is intended only for the use of the individual or entity for which it wasprepared and may contain information that is privileged, confidential, and exempt from disclosure under applicable law. Any dissemination, distribution, or copying ofthis document is strictly prohibited. Table of Contents 1 Introduction 1 1.1 Project Background 1 1.2 Report Organization 2 2 Station History 3 2.1 Operating History 4 2.2 Regulatory Review 4 3 Station Setting 4 3.1 Land Use 5 3.2 Environmental Setting 5 3.3 Topography and Station Drainage 5 3.4 Climate and Precipitation 5 3.5 Regional Geology 6 3.6 Regional Hydrogeology 7 4 Facility Construction Details and Local Geology and Hydrogeology 8 4.1 Pre-Facility Construction 8 4.2 Facility Construction 9 4.3 Local Geology and Hydrogeology 10 5 Remedial Investigation 11 5.1 Soil Investigation 11 5.2 Groundwater Investigation 12 5.2.1 Monitoring Well Installation 12 5.2.2 Groundwater Monitoring 14 5.2.2.1 Water Level and Separate-Phase Product Measurements 14 5.2.2.2 Monitoring Well Sampling 15 6 Interim Remedial Actions 16 6.1 Product Recovery Details 16 Table of Contents 6.2 Product Recovery Results 17 7 Baseline Ecological Evaluation 17 8 Conclusions 18 9 Proposed Actions 19 10 Request for Variance 20 11 References 21 Tables 1 Summary of Soil Analytical Results2 Monitoring Well Construction Details 3 Groundwater Elevations and Product Thickness 4 Groundwater Biogeochemical Parameters 5 Summary of VOC Groundwater Analytical Results 6 Summary of SVOC Groundwater Analytical Results 7 Proposed Sampling and Reporting Schedule Figures 1 Station Location 2 Station Layout 3 Groundwater Elevation Contour Map, Ambient Conditions 4 Facility Cross-section A-A'5 Facility Cross-section B-B'6 Soil Investigation Details and Results 7 Groundwater Elevation Contour Map, Pumping Conditions 8 Groundwater Investigation Details and Results 9 Cumulative Product Recovered from Well AU Appendices A Excavated Soil and Recovered Separate-Phase Diesel Disposal Manifests, B Soil Analytical Results C NJDEP Bureau of Water Allocation Monitoring Well Records, Monitoring Well Construction Logs, and Soil Boring Logs.D Monitoring Well Certification Form Bs ii Table of Contents E Groundwater Low-flow Sampling Logs F Groundwater Analytical Results (December 2004 and March 2005)G Baseline Ecological Evaluation Report iii Remedial Investigation and Interim Remedial Action Report PSEG Nuclear, LLC Salem Generating Station Hancock's Bridge, New Jersey I Introduction ARCADIS, on behalf of PSEG Services Corporation (PSEG), has prepared this Remedial Investigation (RI) and Interim Remedial Action Report (RAR) to present the details and results of soil and groundwater investigation activities conducted in association with the release of diesel fuel (Incident Number 04-08-02-2350-16) at the PSEG Nuclear, LLC Salem Generating Station (the Station). The Site is located on Artificial Island in Lower Alloways Creek Township, Salem County, New Jersey. The Station location and layout are depicted on Figures 1 and 2, respectively. The remedial investigation was conducted in accordance with the Remedial Investigation Work Plan (RIWP) that was submitted to the New Jersey Department of Environmental Protection (NJDEP) in January 2005. The scope of work outlined in the RIWP was designed to investigate the extent of diesel fuel constituents in the shallow, water-bearing unit at the Station.This report has been prepared in accordance with New Jersey Administrative Code (N.J.A.C.) Chapter 26E -Technical Requirements for Site Remediation (Technical Requirements).
1.1 Project
Background On August 2, 2004, PSEG personnel observed a diesel fuel odor in a catch basin associated with the stormwater collection system just to the south of the Salem Unit I Fuel Handling Building. Investigation of the catch basin, which is identified as "Catch Basin 27" on Figure 2, revealed the presence of a red-dyed diesel fuel (the red-dye is more typical of a recent release of diesel fuel). At this time, PSEG notified the NJDEP through its spill hotline.To prevent the migration of diesel fuel within the stormwater collection system, the storm drains upstream and downstream of Catch Basin 27 were temporarily blocked to isolate the affected section of piping. Further, a cover was placed over Catch Basin 27 to prevent rain water from entering. Investigations of the remainder of the stormwater system indicated that the diesel fuel had not migrated beyond Catch Basin 27, no diesel fuel was released to the Delaware River, and the diesel fuel in the catch basin was removed.Investigations into the source of the diesel fuel focused on the underground piping adjacent to Catch Basin 27 that supplies diesel fuel from the bulk storage tanks to diesel/generator storage tanks located within the Auxiliary Building and to the service water and circulating water boilers. The location of the underground piping is shown on Figure 2. PSEG performed a pressure test on this underground piping. The results revealed the leak was in an approximate 300-foot section of the piping extending south from the Auxiliary Building.To pinpoint the location of the leak along this 300-foot section of piping, PSEG subcontracted Praxair Services, Inc. to perform a "Tracer Tight" gas analysis. The results of this test showed that the location of the leak was directly adjacent to Catch Basin 27.I Remedial Investigation and Interim Remedial Action Report PSEG Nuclear, LLC Salem Generating Station Hancock's Bridge, New JerseyThe results of the Tracer Tight gas analysis indicated that there were no other, leaks along the 300-foot section of piping.Excavation in the area of the leaking underground piping was initiated on August 23, 2004 by PSEG with the support of Clean Harbors, Inc. to repair the piping. During theexcavation process, residual diesel fuel was observed on soil excavated from below thepiping (approximately six feet below ground surface (bgs)). Soil excavated from the piping area was stockpiled by PSEG pending waste characterization. Following characterization, the soil was disposed of by Clean Harbors. The soil disposal manifests are included as Appendix A. Separate-phase diesel fuel was observed on standing water within the excavation. Prior to backfilling, approximately 150 gallons of diesel fuel were recovered from the excavation. Disposal manifests for the diesel fuel are also included in Appendix A.In November 2004, PSEG initiated remedial investigation and interim product recovery actions. In accordance with the scope of work presented within the RIWP, soil borings were advanced at locations downgradient of the source area to delineate the horizontal extent of diesel related constituents of concern in soil. The soil borings were convertedto monitoring/product recovery wells to facilitate the collection of groundwater samples and for the recovery of separate-phase diesel, if present. Interim remedial actions completed todate include the installation of a Spill Buster Product Recovery System, a passive product skimmer, and the use of absorbent socks. The sections of this report present. relevant facility information, the details and results of the soil and groundwater investigation activities completed to date, and the details and results of product recovery efforts completed to date. These sections are followed by conclusions and proposed investigation and product recovery activities.
1.2 Report
OrganizationThis report contains eleven sections including this introduction: " Section 2 -Station History;" Section 3 -Station Setting;" Section 4 -Facility Construction Details and Local Geology and Hydrogeology;" Section 5 -Remedial Investigation;" Section 6 -Interim Remedial Actions;" Section 7 -Baseline Ecological Evaluation;" Section 8 -Conclusions" Section 9 -Proposed Actions;2 Remedial Investigation and InterimRemedial Action Report PSEG Nuclear, LLCSalem Generating Station Hancock's Bridge, New Jersey" Section 10- Request for Variance; and,* Section II -References The Station History Section (Section 2) provides an overview of the operating history of the Station and applicable regulations gdverning'these operations; The Station Setting section (Section 3) provides a detailed description of the environmental setting of the Station including topography, surface water features, climate, soil, and regional geology and hydrogeology;The Facility Construction Details and Local Geology and Hydrogeology section (Section 4)provides a detailed description of the construction of the facility and the resulting influence on local geology and hydrogeology; The Remedial Investigation section (Section 5) provides the details and results of soil and groundwater investigation activities completed to date;The Interim Remedial Action section (Section 6) presents the details of interim remedial actions completed to date: The Baseline Ecological Evaluation section (Section 7) provides the details and results of abaseline ecological evaluation conducted in accordance with N.J.A.C. 7:26E-3.1 1;The Conclusions section (Section 8) presents a summary of the findings of the remedial investigation; and, The Proposed Actions section (Section 9) presents recommendations for further actions based on the investigation findings;The Request for Variance section (Section
- 10) presents a request for variance from the Technical Requirements for Site Remediation (N.J.A.C.
7:26E); and, The References section (Section 11) provides publications referenced during the preparation of this report.2 Station History The following sections provide relevant site information regarding the facility's operating history and a review of applicable regulations relating to operations at the Station. Remedial Investigation and Interim Remedial Action Report PSEG Nuclear, LLCSalem Generating Station Hancock's Bridge, New Jersey 2.1 Operating History PSEG Nuclear LLC operates and is part owner of the Salem Generating Station located on Artificial Island in Lower Alloways Creek Township, Salem County, New Jersey. PSEGNuclear LLC (57.41%) and Exelon (42.59%) jointly own the Salem Generating Station.The Salem Generating Station is situated adjacent to the Hope Creek Generating Station, also located on Artificial Island. Both the Salem and Hope Creek Generating Stations (the Stations) are located on the eastern bank of the Delaware River. The Salem Generating Station encompasses an approximate 26-acre portion of Artificial Island.The Salem Generating Station is composed of two nuclear generating units (Units I and 2)and one distillate oil fueled combustion turbine unit (Unit 3). Commercial operations of Units 1 and 2 commenced in 1976 and 1981, respectively. The combustion turbine unitcommenced operations in 1972. The nuclear generating units operate as base load units and the combustion turbine unit operates as a peaking unit. The Salem Generating Station has a combined generating capacity of approximately 2,400 MW. Over its operational life, the Salem Generating Station has experienced no significant changes in its operation.
2.2 Regulatory
Review Regulatory oversight for the Salem Generating Station, and other nuclear generating stations, is provided by both federal and state agencies. These agencies ensure that the stations are designed, constructed, licensed and operate in a matter that maximizes the safe containment and management of radioactive materials. These agencies also ensure thatsufficient funding mechanisms have been established, are adequately funded, and will beavailable to decommission the nuclear generating stations at the end of their life cycle.On the federal and state levels, the United States Nuclear Regulatory Commission (USNRC) and the New Jersey Department of Environmental Protection Bureau of Nuclear Engineering (NJDEP-BNE) conduct licensing and oversight of the Station. Oversight by the NJDEP-BNE and USNRC includes periodic inspections and conducting environmental radiological monitoring. 3 Station Setting The following sections provide information regarding the environmental setting of the Salem Generating Station, including land use, the environmental setting, precipitation and drainage, local geology and local hydrogeology. 4 Remedial Investigation and Interim Remedial Action Report PSEG Nuclear, LLC Salem Generating Station Hancock's Bridge, New Jersey 3.1 Land Use PSEG Nuclear LLC owns and/or controls an approximately 740-acre area of Artificial Island that is situated adjacent to and surrounds the Salem and Hope Creek Generating Stations. This area contains administrative and support facilities used by the Stations, the Hope Creek Switch Yard, the Salem Switch Yard, and undeveloped vacant land. With the exception of the Salem Generating Stations (Units I through 3) and the Salem Switchyard, the remaining acreage is considered to be the Hope Creek Generating Station.The zoning classification for the Salem Generating Station is industrial. The land adjacent to the Salem Generating Station is zoned for industrial and residential or agricultural use.3.2 Environmental Setting The Salem Generating Station is located on a portion of Artificial Island that borders theDelaware Estuary. The Estuary, in the location of the Salem Generating Station, is a tidal, brackish river, located in an area designated as Zone 5 by the Delaware River Basin Commission. The United States Army Corps of Engineers, beginning in the early twentieth century, created Artificial Island by depositing hydraulic dredging spoils within a diked area established around a natural sand bar that projected into the Delaware River. Prior to construction of the Salem Generating Station, the property was vacant, undeveloped, low-lying land.3.3 Topography and Station Drainage The topography at the Salem Generating Station is relatively flat with limited local relief.Topographic contours for the Station are included on Figure 2. Stormwater is managed in accordance with the Salem Generating Station New Jersey Pollution Discharge Elimination System (NJPDES) permit and Stormwater Pollution Prevention Plan. Stormwater is collected in storm drains and routed to the Delaware River for discharge. Stormwater from the major petroleum storage and handling areas is routed to the oil/water separator prior to discharge.
3.4 Climate
and Precipitation Salem County is located in southwestern New Jersey. The county's climate is considered to be humid and temperate, as the climate in this county is readily influenced by itsproximity to the Delaware Bay. Coastal storms are not uncommon in this region and can produce high winds and heavy rainfall, which can cause wind damage and flooding in low-lying areas.5 Remedial Investigation and Interim Remedial Action Report PSEG Nuclear, LLC Salem Generating Station Hancock's Bridge, New Jersey Wind direction in this region is dependent upon the season; during the summer, winds are typically from the southwest while during the winter winds are commonly from the northwest. Temperatures vary by season and the maximum expected high temperature for a given year is 96 degrees Fahrenheit, while the minimum expected yearly low temperature is minus 2 degrees Fahrenheit. The average annual precipitation total is 39.9 inches.3.5 Regional GeologyThe Station is located in the Atlantic Coastal Plain Physiographic Province. This area is characterized by relatively flat to gently undulating terrain, underlain by unconsolidated sediments that increase in thickness to the southeast. These sediments range in age from Holocene to Cretaceous (0 to 146 million years old), are primarily comprised of clay, silt, sand, and gravel, and are generally classified as continental, coastal, or marine in nature.Published geologic mapping indicates that the basement rock beneath these sediments (in the area of the Station) is metamorphic schist of the Wissahickon Formation, which is Pre-Cambrian in age (570 to 900 million years old).The unconsolidated overburden at the Salem and Hope Creek Generating Stations consists of approximately 25 to 40 feet of dredge spoils, engineered fill material (cofferdam), tidal marsh deposits and riverbed deposits. The engineered fill, composed mainly of silt, silty clay, sand, and gravel, replaced the dredge spoils within the cofferdam during the construction of the Station. Due to the composition and nature of the engineered fill, the hydraulic conductivity of this material is very low, thus limiting the extent and rate of groundwater movement. Below the engineered fill there is an approximate five-foot layer of tidal marsh deposits consisting of silty peat and organic silt and meadow mat. The tidal marsh deposits are semi-confining. Beneath the tidal marsh deposits are approximately ten feet of discontinuous Quaternary Age riverbed deposits consisting of sand and gravel. The engineered fill, the tidal marsh deposits and the riverbed deposits, combine to form the water table aquifer (see Section 3.6). Beneath the surface water aquifer, in order of increasing depth, are the following geologic formations: Clay, Confining Unit -Beneath the shallow, riverbed and other deposits is a clay, confining unit that separates the shallow unit from the deeper Vincentown Formation. Conflicting geologic reports suggest that the clay, confining unit is either the Miocene Kirkwood Formation or the Pleistocene Van Sciver Lake Bed deposits (USGS 1979 and 1999).Previous investigations conducted at the facility indicate that the clay, confining unit is laterally extensive beneath the Station.Vincentown Formation -The Vincentown Formation occurs from a depth of approximately 55 feet bgs to a depth of 135 feet bgs and consists of a competent, greenish-gray, fine to medium sand with some silt, shell fragments, feldspar and glauconite. 6 Remedial Investigation and Interim Remedial Action Report PSEG Nuclear, LLC Salem Generating Station Hancock's Bridge, New Jersey Homerstown Formation-The Homerstown Formation is a highly glauconitic, clayey, dark green sand that contains small percentages of quartz grains and apatite pellets. The Homerstown Formation unconformably overlies the Navesink Formation and is unconformably overlain by the Vincentown Formation. The Homerstown Formationoccurs from approximately 135 to 145 feet bgs.Navesink Formation -The Navesink Formation is characteristically a glauconitic sand with varying amounts of silt and clay. It is brown or dark green to blue-black and has a shell bed at its base. The upper part of the formation is less glauconitic, more clayey, more micaceous, and lighter in color. The Navesink Formation conformably overlies the Mount Laurel Sand (USGS 1969). The contact with the overlying Homerstown Formation is gradational. The Navesink Formation is encountered from approximately 145 to 170 feet bgs.Mount Laurel-Wenonah Formation -The Mount Laurel-Wenonah Formation consists of a clayey, medium-grained sand with some gravel, feldspar and glauconite. In the vicinity ofthe Station, the Mount Laurel-Wenonah Formation is approximately 100 hundred feet thick and occurs from 170 to 270 feet bgs.Beneath the Mount Laurel-Wenonah Formation, more than 1,000 feet of Upper Cretaceous sediments overlie the crystalline bedrock. The Upper Cretaceous sediments include in descending order: the Marshalltown Formation (gray, fine sand); the Englishtown Formation (yellow-brown, fine sand); the Woodbury Clay (dark gray, stiff, silty clay); the Merchantville Formation (dark green clay); the Magothy Formation (coarse to fine silt with little fine sand); and the Raritan and Potomac Formations (interbedded sand, gravelly sand and clay).3.6 Regional Hydrogeology There are four primary water bearing formations (aquifers) underlying the Station: 1) the shallow, water-bearing unit; 2) the Vincentown Formation;
- 3) the Mount Laurel-Wenonah Formations; and, 4) the Potomac-Raritan-Magothy Formations. The shallow, water-bearing unit, which consists of the dredge spoils, engineered fill, tidal marsh deposits and the discontinuous Quaternary riverbed deposits, occurs between approximately 10 to 40 feet bgs. In general, the dredge spoils, engineered fill and tidal marsh deposits are characterized by low permeability.
Occasional lenses of sand within the dredge spoils maycontain perched water within a few feet of the ground surface. The groundwater in the water table aquifer is generally brackish, with flow to the southeast and a gradient of approximately 0.007 feet/feet. A clay, confining unit identified as either the Miocene Kirkwood Formation or the Pleistocene Van Sciver Lake Bed deposits separates the shallow, water-bearing unit from 7 Remedial Investigation and Interim Remedial Action Report PSEG Nuclear, LLC Salem Generating Station Hancock's Bridge, New Jersey the deeper Vincentown Formation. As stated previously, investigations conducted at the facility indicate that the clay, confining unit is laterally extensive beneath the Station.The Vincentown Formation, which occurs from approximately 55 to 135 feet bgs, is a semi-confined to confined aquifer under artesian conditions. Groundwater in the Vincentown Formation generally flows from north to south with a gradient of approximately 0.003 feet/feet. Regionally, the Vincentown Formation is a water-producing aquifer, which supplies potable water to domestic wells in Salem County. Groundwater in the aquifer is moderately hard with high iron content. Saltwater-intrusions occur near the Delaware River, where water quality is brackish and non-potable. The Hornerstown and Navesink confining units separate the Vincentown Formation from.the Mount Laurel-Wenonah Formations. The Mount Laurel-Wenonah Formations occur from approximately 135 to 170 feet bgs. The Station has two potable and fire-water supply wells screened in this formation. The deepest of the water bearing formations is the Potomac-Raritan-Magothy Formation. In Salem County, the Potomac-Raritan-Magothy Formation occurs at depths in excess of 500 feet bgs. This is the primary water producing aquifer for New Jersey. Four potable and fire-water supply wells at the Station are screened in the Potomac-Raritan-Magothy. Formation at depths ranging from 800 to 1,100 feet bgs. The Potomac-Raritan-Magothy Formation is bounded by the Merchantville Formation above and below by the Wissahickon Schist basement rock. The crystalline basement rock of the Wissahickon Schist is not considered a productive aquifer and only locally transmits water from secondary porosity (i.e., fractures and faults).4 Facility Construction Details and Local Geology and HydrogeologyThe construction of the Salem Generating Station has caused significant changes to the local geology and hydrogeology. Within the footprint of the cofferdam surrounding Units I and 2 (see Figure 2), the majority of original Artificial Island materials were removed to a depth of 70 feet bgs. The following sections, which contain information presented in a Remedial Investigation Report (RIR) previously prepared for a separate investigation conducted at the Station (ARCADIS 2004), describe the conditions at Artificial Island prior to the construction of the Station, and detail how the construction of the Station has altered the local geology.4.1 Pre-Facility Construction The Station is located on the southern tip of what was once a natural sand bar projectinginto the Delaware River. The area between the sand bar and the mainland had been used as 8 Remedial Investigation and Interim Remedial Action Report PSEG Nuclear, LLCSalem Generating Station Hancock's Bridge, New Jersey a dredge spoil deposit area. In 1899, a timber sheetpile wall was installed around the perimeter of the sand bar. Over the next 50 or so years the area was used as a spoil deposit area for material collected during the dredging of the Delaware River. Riprap was added tothe perimeter when the timbers began to degrade. The area landward of Artificial Island has remained a tidal marsh.4.2 Facility Construction The construction of the Station has resulted in significant changes to the local geology. Itwas necessary to remove and rework much of the soil in the area of the Station in order to facilitate construction. For the purposes of this report, the description of the facility construction is limited to the area within the cofferdam; however, it should be noted that the local geology beyond the limits of the cofferdam was also significantly modified. The extent of the cofferdam is shown on Figure 2.The cellular cofferdam, which encircled the excavation for all the Class I structures (e.g., containment, fuel handling, and auxiliary buildings), was constructed of interlocking sheetpiling driven from an approximate depth of 23 feet below existing grade (approximately 77 feet plant datum [PD] or -12.92 feet above mean sea level [amsl NAVD 1988]). Thecofferdam consists of 24 circular cells, approximately 60.5 feet in diameter with connecting arcs, that were advanced from this depth to approximately 10 feet into the Vincentown Formation to an elevation of 17 feet PD (-72.92 feet amsl). The cofferdam sections are of two different heights, 50 feet and 60 feet. The elevation of the top of the cofferdam is 77 feet PD (-12.92 feet amsl) on the north, south and west sides. The elevation of the eastern side is 67 feet PD (-22.92 feet amsl) providing access and a foundation for the return circulating water pipes and associated thrust block. The inside area of the cofferdam sections were excavated to elevation 27 feet PD (-62.92 feet amsl). A vertical steel wall was added inside each individual cofferdam section to divide the sections approximately in half. The inner half of the individual cofferdamsections, or the section facing the building foundations, was then filled to the top with lean concrete. The area contained by the entire cofferdam structure was then excavatedto the Vincentown Formation for placement of a lean concrete mat that served as the foundation for the construction of the structures within the cofferdam. During this stage of the excavation, qualified personnel visually inspected the bottom of the excavation to verify that the excavation had reached the top of the Vincentown Formation prior to placing any lean concrete.Prior to the completion of the excavation, at approximately elevation 45 feet PD (-44.92 feet amsl), 15 exploratory borings were drilled through the remaining Kirkwood Formation and into the underlying Vincentown to verify the depth to the formation. These additional borings showed no measurable differences from the study borings.9 Remedial Investigation and Interim Remedial Action Report PSEG Nuclear, LLCSalem Generating Station Hancock's Bridge, New Jersey Based on a review of available documents, the top of the Vincentown Formation in the area of the cofferdam ranges between 27 and 30 feet PD (-62.92 to -65.92 feet amsl).When the surface of the Vincentown Formation was reached, the area was cleared of loose soil and lean concrete was poured directly onto the exposed Vincentown Formation. The station construction drawings indicate that the base of the first lean concrete pour was at 30 feet PD (-59.92).The cofferdam serves as a basin in which the Class I structures were constructed. Prior to construction of the primary structures, a lean concrete mat ranging in thickness from 5 to 50feet was placed on top of the Vincentown Formation for support of the structures. Following placement of the lean concrete, the Auxiliary Building, Fuel Handling Buildings and Reactor Containment Buildings were constructed. The remainder of the excavationwithin the cofferdam was then backfilled with structural fill meeting the design specifications of the Station.4.3 Local Geology and HydrogeologyThe soils removed from within the cofferdam were not used to backfill the completed structure because the hydraulically placed fill and other riverbed deposits underlying Artificial Island did not meet the building design specifications for the Station. Therefore, it was necessary to import construction or structural fill to build the facility. The structural fill was placed between and around the Auxiliary Building, Fuel Handling Buildings, Units I and 2, portions of the cofferdam, above the return circulating water pipes, and from the top of the clay, confining-unit to the land surface in the portions of the area between the cofferdam and the circulating water discharge pipes.The structural fill used at the station was obtained from a number of sources in New Jersey and Delaware. One fill source used in the area of this investigation was the Hinchner Pit. While the location of the borrow source was not identified, the material was described as yellowish-brown fine to medium sand with a trace of silt and clay.Details of groundwater investigation activities historically completed at the facility indicatethat groundwater elevations in the shallow, water-bearing unit within the limits of the cofferdam are generally higher than those outside the limits of the cofferdam. This is expected considering permeability differences that exist between the structural fill within the limits of the cofferdam and the hydraulic fill beyond the limits of the cofferdam, resulting in a groundwater mound. Due to the mound, groundwater flows radially outward from the cofferdam. The observed mounding effect dissipates quickly. A groundwater elevation contour map for the shallow, water-bearing unit under ambient (i.e., non-pumping) conditions is presented on Figure 3 (ARCADIS 2004). The groundwater elevation contour map was prepared using water level measurements obtained during a 10 Remedial Investigation and Interim Remedial Action Report PSEG Nuclear, LLCSalem Generating Station Hancock's Bridge, New Jersey previously completed and unrelated investigation at the facility. Beyond the limits of the cofferdam, groundwater flow is generally from the center of the island (northeast of the Salem Generating Station) towards the Delaware River.Facility construction details and local geology are highlighted on cross section diagrams through various Station features (Figures 4 and 5). The cross sections provide details obtained during the remedial investigation, which are discussed in the following sections.5 Remedial Investigation As presented in the RIWP, the remedial investigation conducted in association with the diesel release had the following four primary goals: 1) to characterize the vertical and horizontal extent of diesel-related constituents in soil; 2) to determine if separate-phase diesel fuel was present on the water table and to what extent; 3) to characterize the extent of dissolved-phase diesel-related constituents in groundwater downgradient of the release area; and, 4) to determine the need for further action. The scope of work developed toachieve these objectives included the advancement of four soil borings at various locations downgradient of the source of the diesel release for collecting soil samples, the installation of five monitoring wells, and the monitoring of water/product levels and the collection of groundwater samples from six monitoring wells (the five recently installed monitoring wells and one existing monitoring well. The following sections provide the details and results of these investigation activities. 5.1 Soil Investigation Soil investigation activities were completed between November 8"h and 9 th 2004 and consisted of the advancement of four soil borings (Borings D-2 through D-5) for the collection of soil samples. The locations of the soil borings relative to the source of the diesel release are identified on Figure 6. Due to the presence of diesel-fuel oil, soil samples were not taken from the source area soil boring (D- I). Prior to initiating soil sampling activities, a water level measurement was obtained from Well X, located adjacent to the northwest comer of the Fuel Handling Building (see Figure 6) to determine the appropriate depth for sample collection. Soil samples were obtained from the borings at a depth of six inches above the water table as measured in Well X. A second sample was obtained from Soil Boring D-4 to evaluate the vertical distribution of diesel related constituents of concern in soil.Due to the extensive, facility-critical infrastructure within the area of investigation, both the boring locations and advancement methods were limited. Soil Borings D-2 through D-5, advanced at accessible locations beyond the source area of the diesel release to the south and west, were advanced using vacuum excavation equipment to ensure that, if encountered, subsurface infrastructure would not be damaged. Soil samples were obtained 11 Remedial Investigation and Interim Remedial Action Report PSEG Nuclear, LLC-Salem Generating Station Hancock's Bridge, New Jerseyfrom each boring ahead of the vacuum excavation using a hand auger. The soil samples were submitted to Accutest Laboratories, of Dayton, New Jersey, and were analyzed for total petroleum hydrocarbons (TPHC). In accordance with N.J.A.C. 7:26E-2. 1(d), soilsamples were also placed on hold for volatile organic compounds (VOCs) analysis pending the TPHC results. Based on the results of the TPHC analysis, which are summarized in Table 1, analysis for VOCs was not required per N.J.A.C 7:26E-2. l(d). Copies of the laboratory reports and the associated HazSite deliverables for the soil samples are included in Appendix B. Further details regarding the analytical results are as follows: " Analytical results of the soil samples submitted for TPHC analysis did not indicate concentrations above laboratory detection limits. The method detection limits ranged from 26 to 32 milligrams per kilogram (mg/kg)." Results of the soil investigation indicate that the release of diesel fuel has not migrated a significant distance beyond the source area and that diesel related constituents of concern in soil are likely limited to the source area and the "smear-zone" where separate phase diesel has migrated.. The estimated extent to which separate-phase diesel has migrated is shown on Figure 8. Locations for advancing soil borings are limited due to the presence of extensive subsurface infrastructure. Due to these limitations, the extent of diesel-related constituents of concern in soil can not be further refined.5.2 Groundwater investigation The investigation of groundwater consisted of the installation of five monitoring wells within and downgradient of the source area to evaluate the extent of dissolved-phase and separate-phase diesel. Following installation, product gauging and groundwater samplingwere initiated, including the gauging and sampling of six monitoring wells (the five newlyinstalled wells, and one previously existing monitoring well). The following sections provide a summary of the groundwater investigation details and results.5.2.1 Monitoring Well InstallationFive groundwater monitoring wells (Well AU, Well AV, Well AW, Well AY, and Well AZ) were installed between November 8 and 9, 2004. The five monitoring wells wereinstalled using vacuum excavation techniques due to the extensive subsurface utilities and/or infrastructure described in the previous section. The locations and well construction details of the groundwater monitoring wells are shown on Figure 3 and are summarized in Table 2, respectively. NJDEP Bureau of Water Allocation Monitoring Well Records, well construction logs,, and boring logs are included in Appendix C. The purposes for the monitoring wells are as follows: 12 Remedial Investigation and InterimRemedial Action Report PSEG Nuclear, LLC Salem Generating Station Hancock's Bridge, New Jersey Well AU was installed within a temporary PVC sleeve that was placed within the excavation opened to expose the underground piping prior to backfilling. Due to the presence of extensive subsurface infrastructure encountered during the excavation, Well AU could not be installed beyond a depth of approximately seven feet below ground surface (bgs). Separate-phase diesel fuel was observed within the open excavation prior to backfilling and in Well AU after installation was completed. The primary purpose of Well AU has been to facilitate productrecovery using the Spill Buster active product recovery unit. Details regarding these product recovery efforts are presented in Section 6;" Monitoring Wells AV and AW were installed at the locations of Soil Borings D-3 and D-2, respectively. Using vacuum excavation equipment, the boreholes of D-2 and D-3 were advanced to approximately ten feet bgs and the monitoring wellswere installed within the borehole. Wells AV and AW were installed to delineate the extent of separate-phase diesel fuel downgradient of the source area based on knowledge of groundwater flow direction obtained from previously completed andunrelated investigations. Following installation, separate-phase diesel fuel was detected in Well AW. In response, a passive skimmer product recovery setup was installed within Well AW. Details regarding the product recovery efforts for this well are presented in Section 6;" Monitoring Wells AY and AZ were installed at the locations of Soil Borings D-4 and D-5, respectively. Using vacuum excavation equipment, the boreholes of D-4 and D-5 were advanced to approximately ten feet bgs and the monitoring wells were installed within the borehole. These wells were installed to delineate the extent of dissolved-phase diesel constituents in groundwater downgradient of the source area.Monitoring Well AU was designed for use as a product recovery well and is constructed ofsix-inch diameter Schedule 40 PVC well screen and riser. Well AV, Well AW, Well AY, and Well AZ were constructed of 4-inch diameter Schedule 40 PVC well screen and riser.A sand filter pack was placed in the annular space around the screen interval followed by an appropriate bentonite seal and grouting material. Well AU was completed at ground surface with a two-foot square flush-grade well vault to facilitate the installation of the Spill Buster unit. Well AV, Well AW, Well AY, and Well AZ were completed with 12-inchround flush-grade manways. A summary of the well completion details (i.e., total depth, screened interval) is presented in Table 2. The total depth and screen interval for the monitoring wells were field-constructed based on the facility-related subsurface infrastructure observed at each location.. Therefore, well construction details varied slightly from the specifications presented in the RIWP. In accordance with N.J.A.C. 7:26E-4.4(g) [8], the proposed monitoring wells were 13 Remedial Investigation and Interim Remedial Action Report PSEG Nuclear, LLCSalem Generating Station Hancock's Bridge, New Jersey developed to yield a non-turbid discharge following installation. The monitoring wells were developed using a combination of surging and pumping techniques. In the instances where separate-phase diesel fuel was observed following installation (Wells AU and AW), product was removed from the well using a disposable bailer prior to development. In accordance with N.J.A.C. 7:26E-4.4(g) [7], the Station monitoring wells were surveyed by a New Jersey-licensed surveyor. Monitoring Well Certification Form Bs are provided in Appendix D.5.2.2 Groundwater Monitoring Following the installation of the wells, quarterly groundwater monitoring was initiated with events completed in December 2004 and March 2005. Quarterly groundwater monitoring events consist of the gauging of water levels and separate-phase product and the collection and analysis of groundwater samples from Well AV, Well AW, Well AY, Well AZ, andWell X. The following sections provide details regarding these activities. 5.2.2.1 Water Level and Separate-Phase Product Measurements Prior to the initiation of groundwater sampling activities, water-level and separate phase product measurements were obtained from each monitoring well. Water-level and separate phase product measurements were also collected during routine maintenance of the Spill Bustere unit and the other product recovery methods discussed in Section 6. A summary of the product gauging and groundwater elevation data is presented in Table 3.With the exception of a one time detection of product in Well AZ, measurable product islimited to the area of Well AU and downgradient towards Well AW. On February 16, 2005, PSEG initiated the operation of a groundwater extraction system associated with an ongoing and unrelated groundwater remediation. The groundwater extraction system includes the use of Well AO located approximately five feet to the east of Well AZ. The location of Well AO, as well as groundwater elevation contours observed on March 23, 2005 during the operation of the groundwater extraction system, is shown on Figure 7.Due to the operation of the groundwater extraction system and the resulting groundwaterelevation contours, separate-phase product migrated in the direction of Well AO and 0.09 feet of product was observed in Well AZ. Immediately (i.e., same day) following the detection of separate-phase product in Well AZ, the operation of the groundwater extraction pump in Well AO ceased. An organophilic adsorbent sock was placed in Well AZ to recover any accumulated product. Since pumping from Well AO was, ceased, separate-phase product has not been detected in Well AZ. Sorbent socks have been deployed in Well AZ to recover any residual product that may still be present.The extent to which product has migrated to date has been controlled by the subsurface infrastructure located within the investigation area. As shown on the facility cross sections 14 Remedial Investigation and Interim Remedial Action Report PSEG Nuclear, LLC Salem Generating Station Hancock's Bridge, New Jersey (Figures 4 and 5), the foundation for the primary water storage tank located to the west of Well AU has limited the migration of separate phase product in this direction. Conversely,the service water piping that runs to the south from Well AU and the source area likely provided a preferential pathway for the migration of separate phase product towards Well AW. With the repair of the diesel fuel underground piping, the ongoing product recovery efforts being conducted in Well AU and Well AW will control further migration of product.Separate phase product measurements obtained from Well AY, located to the south and downgradient of Well AW along the service water pipes, provide delineation of the extent of separate phase product. 5.2.2.2 Monitoring Well Sampling Depth-to-water and separate-phase product thickness measurements were collected usingan electronic oil/water interface probe prior to initiating sampling activities. Groundwater samples were only collected from monitoring wells that did not indicate a measurable thickness (i.e., greater than 0.01 feet) of separate-phase product. Well AU and Well AW were not sampled during either sampling event due to the presence of separate phase product in these wells. In accordance with the Station's operating permit, a grab groundwater sample was also collected from wells being sampled prior to initiating sampling activities for radionuclide screening, which is required prior to releasing the samples from the facility for offsite analysis. Based on the results of the radionuclide screening the groundwater sample from Well AZ was not submitted for laboratory analysis during the March 2005 event. On April 18, 2005, ARCADIS personnel returned to the Site in an effort to obtain a groundwater sample from Well AZ for laboratory analysis and againthe sample could not be released from the facility based on the results of the radionuclide screening. Due to the sensitive nature of the analytes being monitored and to ensure the quality of the groundwater data, groundwater samples were collected utilizing the low-flow sampling methodology. Sample collection procedures, as well as quality control/quality assurance(QA/QC) sampling requirements, were outlined in the RIWP. The groundwater biogeochemical parameters and sampling logs are included in Table 4 and Appendix E, respectively. Groundwater samples were submitted to Accutest Laboratories of Dayton, New Jersey. The groundwater samples were analyzed for priority pollutant list semi-volatile organics (SVOCs) and VOCs including a library search. The laboratory report and HazSite deliverables for the groundwater monitoring events are included as Appendix F.The analytical results for the groundwater samples taken in December 2004 and March2005 are summarized in Tables 5 and 6, and indicate the following:
- The analytical results of the groundwater samples collected during the December 2004 and March 2005 sampling events indicated that concentrations of diesel, 15 Remedial Investigation and Interim Remedial Action Report PSEG Nuclear, LLC Salem Generating Station Hancock's Bridge, New Jerseyrelated constituents of concern (both VOC and SVOC) were below the New JerseyGroundwater Quality Criteria for Class 11A aquifers (GWQC).Of the VOCs, only tetrachloroethene was detected above the laboratory detection limit. The groundwater sample collected from Well X in December 2004 indicateda tetrachloroethene concentration of 0.87 jig/I (micrograms per liter, equivalent to parts per billion), which is below the GWQC for tetrachloroethene (1 jtg/L).Tetrachloroethene was below the laboratory detection limit in the groundwatersample collected from Well X in March 2005. The detection of tetrachloroethene in Well X appears to be an anomaly and may have been a result of laboratory contamination.
- With the exception of the groundwater samples collected from Well AV, which is located to the east of the service water pipes, the SVOC constituents were below laboratory detection limits. Analytical results of the groundwater samples collected from Well AV indicated concentrations of the following SVOCs above laboratory detection limits but below their respective GWQC: acenaphthalene, carbozole, fluorine, 2-methylnaphthalene, naphthalene, and phenanthrene.
The detection of these constituents is consistent with a diesel release. 6 Interim Remedial ActionsThe extent of product observed to date has been limited to Well AU, installed within thesource area, and Well AW, installed immediately downgradient of the source area along the service water piping. Separate phase product was detected during a single gauging event in Well AZ and migrated to this area under the influence of pumping in Well AO. Product recovery efforts completed to date have included the installation of the Spill Buster active product recovery system in Well AU and Well AW at different times, the installation and operation of a passive skimmer in Well AW, and the installation of sorbent socks within Well AZ. The following sections provide the details and results of product recovery efforts completed to date.6.1 Product Recovery Details Following installation of the monitoring wells, water-level and product gauging activitieswere initiated to evaluate the extent of separate phase product in the subsurface and toevaluate product recovery methods. As presented in the RIWP, a Spill Buster unit was installed in the source area well (Well AU) to facilitate product recovery. The Spill Buster system is designed to remove only product (i.e., no water) with a down-well conductivity sensor and pump apparatus, an adjustable depth, wellhead auto-seek unit, andintegrated control panel. Recovered product is conveyed to a nearby storage tank that isequipped with a high-level auto shut-off interfaced with the Spill Buster control panel.16 .' Remedial Investigation and Interim Remedial Action Report PSEG Nuclear, LLC Salem Generating Station Hancock's Bridge, New Jersey Based on the initial water-level and separate phase product measurements, the Spill Busterunit, was instead installed in Well AW due to the greater apparent thickness of separate-phase product. The Spill Buster unit was installed on December 22; 2004 and product.recovery efforts were initiated. Following the initial startup of the Spill Buster unit, product recovery rates were monitored and it became apparent that, although Well AW indicated a greater product thickness, the recovery rate of product from this 'well (less than 0.25 gallons per day) was limited.; On January 17, 2005, the'Spill Buster' unit was transferred to Wel AU'.: Operation of the Spill Buster Unit in Well AU was muth more effective than previous efforts in Well AW. Separate phase product recoveryirates from Well AU have been maintained at an approximately two gallons per day. Discuisions regarding the results of product. recovery rates (e.g., cumulative product recovered to date),are presented in Section 6.2. With the continued presence of separate phase product and the limited product recovery rate in Well AW, a passive skimmersetup was installed on April 8, 2005. ' .* ' ..As presented in section 5:2.2. 1, separate-phase product was detected in Well AZ following the initiation of pumnping in Well AO. Following this detection, pumping at Well AO was immediately discontinued. and,. since'then, product has not been observed in Well AZ.Sorbent socks have been deployed in Well AZ to recover any residual product that may still be present; however, there has been no indication of additional product (i.e., sheen, sock staining, etc.) in Well AZ since the cessation of pumping. -6.2 Product Recovery Results As presented in Section 6.1, product recovery efforts to date have consisted' of the ' 'installation and operation of a Spill Buster'in.Well AU and Well AW, the use'of a passive skimmer in Well AW, and the deployment of sorbent socks within Well AZ. Operation of the Spill Buster unit in.Well.AU hasresulted in the recovery of approximately 190 gallons of separate phase product through April 8, 2005 at a consistent rate of approximately twogallons per day. Figure 9 provides details regarding the cumulative product recovered with the Spill Buster unit through April 8, 2005. Operation of the passive skimmer in Well AW has resulted in the recovery'of approximately 0.5 to 0.75 gallons of separate phase'product per week. The skimmer is retrieved from the well two to three timesper week,'and the recovered product is transferred to the storage tank utilized by the Spill Buster unit.7 Baseline Ecological Evaluation In accordance with N.J.A.C. 7:26E-3. 11, a baseline ecological evaluation was performed to identify the following:
- 1) constituents of potential environmental, concern in soil and groundwater;
- 2) environmentally sensitive areas; and, 3) potential contaminant migration-, pathways.
The results of'the baseline ecological evaluation, which are presented in-Appendix G, concluded that no further ecological evaluation is warranted. 17 Remedial Investigation and Interim Remedial Action Report PSEG Nuclear, LLCSalem Generating Station Hancock's Bridge, New Jersey 8 Conclusions The following detailed conclusions are based on the results of investigation activities andinterim remedial actions completed to date: " On August 2, 2004, a diesel fuel odor was observed in Catch Basin 27 just to the. south of the Salem Unit 1 Fuel Handling Building. Investigation of the catch.basin, revealed the presence of a red-dyed diesel fuel., Investigations into the source of the diesel fuel.revealed the presence of underground piping adjacent to Catch Basin 27 that supplies diesel fuel from the bulk storage tank to diesel/generator, storage tanks located within the Auxiliary Building and to the. service water and circulating water.boilers;," PSEG performed a pressure test on the underground piping, which revealed the leak was in an approximate 300-foot section of the piping extending south from the Auxiliary Building. The location of the leak along the 300-foot section of piping was pinpointed using a "Tracer Tight" gas analysis.. After the location of the leak was pinpointed, an excavation was opened to expose and repair the leak. Soil excavated from adjacent to and around the piping and approximately 150 gallons of separate-phase product were removed and disposed;* Soil investigation activities consisted of the advancement of four soil borings. Due to the presence of extensive, facility-critical infrastructure within the area of investigation, the boring locations were limited. Soil samples were submitted for TPHC analysis. Analytical results of the soil samples submitted for TPHC analysis did not indicate concentrations above laboratory detection limits. The methoddetection limits ranged.from 26 to 32 milligrams per kilogram (mg/kg).* Results of the soil investigation indicate that the release of diesel fuel has not migrated a significant distance beyond the source area and thatdiesel related constituents of concern in soil are likely limited to thesource area and the "smear-zone" where separate phase diesel has migrated. The estimated extent to which separate phase diesel has migrated is shown on Figure 8. Due to the extensive subsurface, infrastructure, locations for advancing soil borings are limited. Due to theselimitations, the extent of diesel-relatedconstituents of concern in soil must be inferred with the existing groundwater monitoring well network;" The investigation of groundwater consisted of the installation of five monitoring wellswithin and downgradient of the source area to evaluate the extent of dissolved-phase and separate-phase diesel. Water-level and product gauging and groundwater , sampling were completed following installation of the wells. These activities utilized six monitoring wells (the five newly installed wells, and one-previously existing monitoring well);18 Remedial Investigation and Interim Remedial Action Report PSEG Nuclear, LLC Salem Generating Station Hancock's Bridge, New Jersey Water-level and productrmeasurements indicate that the extent of measurable product is limited to the area of Well AU, located at the source'area, andWell]AW,.located downgradient 'of the source area along the service water pipes. Measurable productwas detected during a single gauging event in Well AZ. Product migrated to this well under the influence of unrelated groundwater pumping in Well AO, which has -subsequently been discontinued; ,', , ' " ,* The extent to which product has migrated is controlled by the significant facility-,; related subsurface infrastructure. The foundation for the primary water storage tanklocated to the west of Well AU prevents the migration of separate phase product in this direction. Tlie service water piping that runs to the south from Well AU provided* a preferential pathway for the migration of separate phase product towards Well AW;* Product recovery efforts completed to date have included the installation of the Spill Buster in Well AU and initially in Well AW, the installation and.operation of apassive skimmer in Well AW, and the installation of sorbent socks within Well AZ.Operation of the Spill Buster unit in Well AU has resulted in the recovery of approximately i90 :gallons of separate phase product through April -8, 2005 at a consistent rate of approximately two gallons per day. Operation of the passive skimmer in Well AW has resulted irithe recovery of approximately 0.5 to0.75 gallons of separate phase product per week; -4 I," Grotndwater samples were collected from those wells not indicating the presence of separate phase product in December 2004 and March 2005. The groundwater samples were analyzed for VOCs and SVOCs. Analytical results of the groundwater samples did not indicate concentrations of cornstituents of concern above applicable.GWQC; .and,, .... ." Results of the baseline ecological evaluation concluded that no further ecological evaluation is warranted. ... , .. ., 9 Proposed Actions Based on the results of investigation activities and interim remedial actions:comoletedto,.-" date, the following actions are l5roposed:- "* Continue operation and maihtenance of the SpillBustet unit and passive skimmer in Well AU and Well AW, respectively, until measurable separate phase product is nolonger detected. Currently, routine maintenance of these systems is performed'to 'ensure the timely change out of the product storage tank and the proper operation of the units;19 Remedial Investigation and Interim Remedial Action Report PSEG Nuclear, LLC Salem Generating Station Hancock's Bridge, New Jersey Quarterly groundwater monitoring will be conducted concurrently with the product. recovery efforts., The quarterly groundwater sampling will consist of the collection and analysis of groundwater samples from those wells no~t indicating the presence ofseparate phase product. The-groundwater samples.will be analyzed for VOCs and SVOCs to evaluate the extent, if any, of dissolved phase constituents of concern.Semi-Annual Remedial Action Progress Reports will be prepared to update the NJDEP with the status of product recovery efforts and groundwater analytical results.A summary of the schedule forthe sampling and reporting activities is presented in Table 7; , .Following completion of the product recovery efforts (i.e., measurable separate phase product is no longer detected) eight consecutive rounds of quarterly sampling will be completed (assuming concentrations of constituents of concern are above applicable GWQC) as required by .the Mann-Whitney U-Test. The analytical-results from these sampling events will be evaluatedto determine if there are decreasing analytical trends;* Following completion of the eight consecutive rounds of quarterly sampling, PSEG will either: 1) propose no further action for groundwater if groundwater analytical results continue t.o.be below applicable GWQC; or, 2) establish a classificationexception area and prepare a Remedial Action Work Plan that proposes a groundwater remediation strategy.10 Request for Variance Results of soil investigation activities completed to date indicate that soil impacts are limited to the source area of the release and the "smear zone" where the separate phase product plume has migrated. The investigation and remediation of soil impacts is technically impracticable to.complete. due to the exýtensive subsurface infrastructure locatedwithin this area. As such, PSEG is requesting a variance from the Technical Requirements.for Site Remediation, specifically N.J.A.C. 7:26E-4. 1(b), and is proposing to base the need for future soil investigation and remediation on groundwater analytical data and.constituent-specific soil partition coefficients. Following the completion of productrecovery efforts and the eight quarterly groundwater sampling events associated with theMann-Whitney U-Test, PSEG will evaluate if decreasing trends for dissolved-phase constituents are observed. If such a trend is established, PSEG contends that groundwaterquality analytical data can be used to demonstrate that-residual mass is.not present within the subsurface and that no further action forsoil is warranted. If decreasing trends are not -.,observed, then PSEG will evaluate remedial.alternatives and prepare a Remedial Action W ork Plan. ., ,.. I.. .. ., 20 Remedial Investigation and Interim Remedial Action Report PSEG Nuclear, LLC Salem Generating Station Hancock's Bridge, New Jersey 11 References ARCADIS, 2004. Remedial Investigation Report, PSEG Nuclear, LLC Salem Generating Station. March 2004.ARCADIS, 2005. Remedial Investigation Work Plan, PSEG Nuclear, LLC Salem Generating Station. January 2005.New Jersey Department of Environmental Protection (NJDEP), 1990 -1994. Standard Operating Procedures for Analytical Data Validation. Bureau of Environmental Measurements and Quality Assurance. 5.a.3, Revision 2. 5.a.4, Revision 1. 5.a.16, Revision 0. 17 April 1990 and 4 October 1994.New Jersey Department of Environmental Protection (NJDEP), 1992. Field Sampling Procedures Manual. May 1992.State of New Jersey Department of Conservation and Economic Development, 1969.Geology and Ground-Water Resources of Salem County, New Jersey;, Division of Water Policy and Supply, Special Report No. 33.United States Department of Agriculture (USDA) Natural Resources Conservation Service National Water & Climate Center, 1998. Field Office Guide to Climatic Data, last revised 18 November 1998.21 ARCADIS Appendix A Disposal Manifests .UUb/IAAY/Ub/ThU UI:.i FM r u r, UU]Fax Transmittal Form To: Attention: 8rad Pierce Fax Number: 267-685-1801 From: Albert W. Fisher Company: PSE&GPhone Number: 856-224-9109 Fax Number: 856-224--1574 Comment: Brad the following shipping paper and scale ticket is for-the soil removed from the Salem fuel oil line leak. The soil (approximately 2 cu'yds) was placed into the 20-Cu/yd container utilized for minor on site spill cleanup, A total of 9.96 cu/yds was shipped to Casie Pro Tank for disposal. Of the 9.96 cubic yard shipped only 2 cu/yds was attributed to the fuel line leak. ZUU/ MA YJUb/ IThU UI :n I I r. Lluz 4V........ .... -KMPROTANK ENV I R 0 N MENTAL SRE-ARV/lC.E S*&so. fu-, orwlie hIn bok-lttrs. IFona-deazigned tor use on 014i r12-pltch) lypowsitir.) NONHAARDOUS 1 .Gnerator's US EPA ID No. .a 0'3.a~MANIFEST ~ 07 I I I 0 8 i I j¶~________
- 3. GanariArs Nome and almjug Axidree.S9'k.&i(i*ý4.eL
/o1e creeK oen. -A.. NOfl ý&~niet:a~itn Number, A13.oway Creek Neck Rd ,T0 'BX NHZO20, I -8q3 EL~ncctsk B~ridge NJ 08038 .5.G Stl ereaoraI 4. Ganerator'sPhonle( 609 2952 S. Transporter 1 Comipany Name 6. US EPA (1) Number ---*-.--..C. SlaleTrans. ID.7. Tirianporter 2 Company Name US EPA IDt Number -.Tarh'1 11 .1 I 1 2- tale TrAns. lD '9. DaeIgnalod Eaolyilyama and Site Ardrteas 1 US EPA iD Number: F rreolr hn I2ftN.ilt1 Rd j "casle .1Protanik G. Stale~aciltty'eiDiu JA P P .6 K Fla .5t b1T-.11. us 0ODeBripio n.Iciud tftg proper shipping Name. Hazard Claeht.,dlD Num bor) Co.tainers .14. lNo no.__ I Type -Ciuanflty _______W_______No .. ... .0O C?0 M.O~ D 2 7 A b T dA A.______ _____~LL Jj1WL.~FAddlikrhIa Dapcptioitatnr'MatorigitLi~ted-Above ... .. iuii* Codeas trar l Linzed Above.4 : S$p~eial HandlngInstructions and Additional8 IflorQntfltof ......Pr~intedlfTypela Na .Signature.r...~~~~~~~~~~~~~ Prnetya ~ ~ ...- lntr oth DDY Year 0: 16. 'Tanspilorter rped .2,ck o flejd iaetion woelept.l caei alViwte 7 W pa otdIiIrt s Prne/ye NM Sig ()1ir Wnt Da I 9Ye~4ar 2005/MAY/Ob/THU 01:42 PM F, UH3*1 tv 2005/MAY/16/MON 02:00 PM* I Remit To: Claarborse RO. Box' 442 Boston, MA 02241-3442 ( 'INVOICE* Date: L k .P. 002 Clean Harbors, Inc.Oil Recycling Division Tel: 800-522-4645 SU11Mo: Pf ./P,, C.K-_t Job Site: Name: Address: Address: CityState 1 Zip: q~~~Ai ~ Cty, State,,._,. _ , 1- t... i,'saV Phone#: ~c~Phone #: Invoice Number sod'sy; C.O.D. chwaI. jP.o.4 .MW 2339'55 Quantity Service Description Price Amount Waste Oil Removal I Antifreeze Removal Oi Filter RemovalWaste Water Removal Oil Delivery Transporters Fee ._Transportation Charges _'...'.._ ..Demurrage Oharges , .,.. , ,_-*= , --,ZL -F 1 I£,-VL LL' C"L ,"! V.-9,b I" ! \ -'Y L: ./,q.. ; [ ,'.:. ,'A&L: 1.R*. e ... ". TaxDue _-.DETACH AND MAIL.Date:<',- .:" ., .. Amount. ...Due. .., I ....u t a CAR INFORATIO Customer-Code: ....._,_.Ap~ouflt Name: _____________________ Addlress:*" .invca Number .ERMS: Due UpW. R2C3ipt mviW, 233.955 (/) CHECK.ONE*" Account Number.-." Remit to:.. Clean Harbors, Inc.P.O. Box 3442.Boston, MA.02241-3442 1: l .1 1 1 1. 1 1LL L I I I I I...Expiration Date: _ _ "_.Amount Paid signature uv$ ARCADIS Appendix B Soil Analytical Results 1I New Jersey gACCUTEST. Laboratories 12/07/04 Technical Report for Arcadis Geraghty & Miller PSEG-Salem, Artificial Island, Salem, NJ NP000571 Accutest Job Number: N83004 Sampling Dates: 11/08/04 -11/09/04 Report to: Arcadis Geraghty & Miller 6 Terry Drive Newtown, PA 18940 ATTN: Brad Pierce Total number of pages in report: 39)W ~CCOO Test results contained within this data package meet the requirements of the National Environmental Laboratory Accreditation Conference and/or state specific certification programs as applicable. incent President Certifications: NJ(02129), NY(110983), CA, CT, DE. FL, IL, IN. KS, KY, LA, MA, MD, MI, MT, NC, PA,R], SC, TN, VA, WV This report shall not be reproduced, except in its entirely, without the written approval of Accutest Laboratories. New Jersey a 2235 Route 130 I Dayton. NJ 08810 a tel: 732-329-0200 " fax: 732-329-3499 a htrp://www.accutest.com Accutest Laboratories 0Sample Summary Arcadis Geraghty & Miller PSEG-Salem, Artificial Island, Salem, NJ Project No: NP000571 Job No: N83004 Sample Collected Matrix Client Number Date Time By Received N3004-3 N83,004754.NS3100473 11/08/04 10:15 DK 11/08/04 11/08104 11/08/04 11/09/04 11/09/04 11/09/04 11/09/04 11/09/04 11:30 DK 12:00 DK 13:00 DK 14:00 DK 14:00 DK 14:00 DK 11:00 DK 15:00 DK 11/10/04 11/10/04 11/10/04 11/10/04 11/10/04 11/10/04 11/10/04 11/10/04 11/10/04 Code Type SO Soil SO Soil SO Soil SO Soil SO Soil SO Soil Dup/MSD SO Soil Matrix Spike SO Soil AQ Field Blank Soil Sample ID.D- (3.-40) .Soil samples reported on a dry weight basis unless otherwise indicated on result page.2 SACCUTEST. 4Table Of Contents Reduced Laboratory Data Deliverables For Non-USEPAICLP Methods Title/Cover Pape Table Of Contents Section I General A. Resulis Summary B. Chain of CustodyC. Sample Tracking ClhroniclefMethod References Section 2 GCUMS Support Data (grouped by fraction)A- Contformance/Non-conformance Summary B. Method Blank Summary C. Blank Spike Summary D. Matrix Spike/Matrix Spike Duplicate Summary E. Tune Results Summary F. Internal Standard Summary G. Surrogate Recovery Results Summary H. Calibration Summary (sorted by lnstniment) I. Initial Calibration Check Summary Continuing Calibration Check'Summary J. Sample and Blank Chromatograms, Quant Reports, Mass Spectra, and Library Search Data Section 3 GC Support Data A. Conformance/Non-conformance Summary B. Method Blank Summary C. Blank Spike Summary D. Matrix SpikeMatrix Spike Duplicate Summary E. Surrogate Recovery Results SummaryF. Calibration Summary (sorted by Instrument) Initial Calibration Check Summary Continuing Calibration Check Summary G. Retention Time Shift Summary H. Sample, Blank and Multi-peak Standard Chromatograms and Quant Reports Section 4 Metals Support Data (sorted by Instrutnent Type-]CP, Furnace, Flame, and Mercury)A. Conformance/Non-conformance Summary B. Blank Results Summary Initial and Continuing Calibration Blank Summary Method Blank SummaryC. Batch Quality Control Summary Matrix Spike and Duplicate Results Summary Spike Blank and Lab Control Sample Summary Serial Dilution Results Summary D. Calibration Summary Calibration Check Standards Summary Interfering Elements Check Standard Summary Section 5 General Chemistry/Petroleum Hvdrocarbon Support Data A. Conformance/Non-Conformance Summary B. Batch Quality Control Summary Method Blank and Spike Blank Results SummaryMatrix Spike Results Summary Duplicate Results SummaryC. Raw Data and 1R Spectra (Petroleum Hydrocarbons) D. Raw' Data and Run Record (Hexavalent Chromium)New JerseyI Fresh Ponds Corporate Viltage I Building B 1 2235 Route 130 " Dayton, NJ 08810 Tet: 732.329.OZOO Fax: 732.329.3499 http:/Iwww.aeCutesLeom RESULTS GG'~ 4 Accutest Laboratories Report of Analysis Page 1 of I Client Sample ID: D-2 (3.5-4.0)Lab Sample ID: N83004-1 Date Sampled: 11/08/04 Matrix: SO -Soil Date Received: 11/10/04 Percent Solids: 92.7 Project: PSEG-Salem, Artificial Island, Salem, NJ General Chemistry Analyte Result RL Units DF Analyzed By MethodPetroleum Hydrocarbons Solids, Percent::<28. 28 mg/kg I% I 11/11/04 11/11/04 NR AK EPA 418.1 M ASTM 4643-00 RL = Reporting Limil r -~, ,-, Accutesi Laboratories Report of Analysis Page 1 of 3 4v Client Sample ID: D-4 (3.5-4.0)Lab Sample ID: N83004-2 Date Sampled: 11/08/04 Matrix: SO -Soil Date Received: 11110/04 Percent Solids: 80.0 Project: PSEG-Salem, Artificial Island, Salem, NJ General Chemistry Analyte Result RL Units DF Analyzed By MethodPetroleum HydrocarbonsSolids, Percent .<32 32 SO, mg/kg I% I 11/11/04 11/11/04 NR EPA 418.1 M AK ASTM 4643-00 RL = Reporting Limit Accutest Laboratories Report of Analysis Page 1 of 1 4wr Client Sample ID: D-4. (9.0-9.5)Lab Sample ID: N83004-3 Date Sampled: 11/08/04 Matrix: SO -Soil Date Received: 11/10/04 Percent Solids: 88.2 Project: PSEG-Salem, Artificial Island, Salem, NJ General Chemistry Analyte ResultRL Units DF Analyzed By MethodPetroleum Hydrocarbons Solids, Percent<29 ! 29 mg/kg I% I 1/111/04 11/11104 NR AK EPA 418.1 M ASTM 4643-00 RL = Reporting Limit Accutest Laboratories Report of Analysis Page 1 of 1Client Sample ID: D-3 (3.5-4.0)]Lab Sample ID: N83004-4 Date Sampled: 11./08/04 Matrix: SO -Soil Date Received: 11110/04 Percent Solids: 89.1 P'roj ect: PSEG-Salemn, Artificial Islanid, Salem, NJ Genera) Chemistry Analyte Result RL Units DF Analyzed By Method Petroleum Hydrocarbons Solids, Percent<2.9,Ji::i 29'89.1;ii::.,:.!:!ii!.:: mg/kg I%; I 11/11/04 11/11/04 NR AK EPA 418.1 M ASTM 4643-00 RL = Reporting Limit S Accutest Laboratories Report of Analysis Page 1 of 1 Client Sample ID: D-5 (3.5-4.0)Lab Sample ID: N83004-5 Date Sampled: 11/09/04 Matrix: SO -Soil Date Received: 11/10/04 Percent Solids: 94.4 Project: PSEG-Salem, Artificial Island, Salem, NJ General Chemistry Analyte Result RIL Units DF Analyzed By Method Petroleum HydrocarbonsSolids, Percent 27 : 27 mg/kg I% 1 11/12/04 11/15/04NR EPA 418.1 M ADP ASTM 4643-00 4$3-s RL = Reporting Limit Q Accutest Laboratories Report of Analysis Page 1 of 1Client Sample 11D: D-50 (3.5-4.0)Lab Sample ID: N83004-6 Date Sampled: 11/09104 Matrix: SO -Soil Date Received: 11/10/04Percent Solids: 94,6 Project: PSEG-Salem, Artificial Island, Salem, NJ Genera) Chemnistry Analyte Result RL Units DF Analyzed By Method Petroleum Hydrocarbons Solids, Percent<26 26 mg/kg I% 1 I 1/12104 11/15/04 NR EPA 43 .1M ADP ASTM 4643-00 RL = Reporting Limit iQ1 Accutest Laboratories Report of Analysis Page I of 1 Client Sample ID: FB-1 Lab Sample ID: N83004-7 Date Sampled: 11/09/04 Matrix: AQ -Field Blank Soil DaterReceived: 11/10/04 Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ General Chemistry AnalytePetroleum Hydrocarbons Result RL< :-.:5 .0.51 Units mg/l DF I Analyzed 11/12/04 By Method HBA EPA 418.1 tL=Rprtn ii~mv RL = Reporting Limit 12ACCUTEST. Laboratories /CHAIN: F CUSTODY" r..-2235 Rou., .30, Daylon NJ 08810 TEL 732-329-0200 FAX: 732-329-3499/3480 wWw.aclcutc$t.coTn FEC-EX Tracking 0 IBotttaleOrdrControl 0Quofe A Accutea!t Job A?C~orany Naxme Project Name__ _ __ _ __ _ '?5E r- _5 1e- AA Addes Street A-4 P j~1¶ ~ 5 Mi Renxested Arralvais Matri Codes City Slate Zio Itl (4 h City Stale A1.Project Conla~ E-mail Ptf*'L. £0 e.~~ ~, 0 0 00 003 Phone. I 2.47- Grs ~ob Fax #Samnler~s Na tJt Client Order 0 100 0 00 003 4..0-o 4 N*'0 a)OW -Orsuru WaterSwa- W;&" SW.- Smie Wate,SL -Sludr.~LI0 -Other 1:10d AIR -Ail SOL.- 05w Scrd WP- VADe LAB MS ONLY Acculesl Sample 0 Field ID/ Point of Colledion SIMtaAO Colecio Nubro pr s~jerved Bottles MarIne 6'0-, z 3'.s-q,o) Q?6 11111t twt WI-L P-1A4 T?.'11 t 0o g)5Y U 23 i 3.LI "o -;g~ oZ.tO S)~,~-.;-.1 3X 5.5-q 1 8 074 __ _-ý'( T-~ e-~ a-4,_ 6) ASio~M Ru W aloxod Time (Business Days) Dal Dererable Ixtormatton -r I R 1eoma~ElSId. IS Businesx Days Approved By: I Date: 0J Commerciai A 0 FtULL CL-P 1z Al .v.. -res-~4-s El10 Day RU1SH C____________ 1 Camrsercil C] 0 yASP Cxtegxcy A___________________________ CO SDaytfSi4 X ~NJ Reduced El NYASP Category PI8 T ~ ~ ( A~c 0 3 Day EMVtGENCY 0 NEJ Full 0 slate Ftormsx 0 2DxyEAlERGENCY other-______EDOFormal_(D T;.o3 1 Day EAERGENCY -t (3. S-'- LfA TC Emrec uhTI data avaitable VIALmsPkHtauFAST TRACK T2L L-UF Emergncy Ruei VI Labtnk ample mutbe 0oi*ne b eac 8h lime -samples cliasg ~nse inleding courler Oil 6NDl " eceiet bI, ox:y-. i I 0110 I IM 6Lf//. /".x 0 4/ .0"t-e>Dale Tme;Rece.to Dr Cus~x* Sue'Fteim d WhtM w vsWa e P nI j-m t Tesm.-3 1 _____Dale Tifne: RecewlJ byr I -lrýZI -I -- P1 _____ Accutest Laboratories Internal Sample Tracking Chronicle Arcadis Geraghty & Miller Job No: N83004 PSEG-Salem, Artificial Island, Salem, NJ Project No: NP000571 Sample Number Method Analyzed By Prepped By Test Codes............. .>: .: ~ .:.. ..... .N83004-1 EPA 418.1 M 11-NOV-04 NR II-NOV-04 NR PHCFT N83004-1 ASTM 4643-00 11-NOV-04 AK %SOLFT..... ........ ~.S ....... .. .......... N83004-2 EPA 418.1 M 1 I-NOV-04 NR 11-NOV-04 NR PHCFT N83004-2 ASTM 4643-00 11-NOV-04 AK %SOLFT D -4 ~9..0-.............* __ N83004-3 EPA 418.1 M I1-NOV-04 NR. II- NOV-04 NR PHCFT N83004-3 ASTM 4643-00 11-NOV-04 AK %SOLFT N83004-4 .olEctA 018-NO-0413:0 -NOV-04 NReivd 10NOV-04' NR MPHF.... ......... ........ .- ........ ...D-..... ....... ... ,~... , ...co:.o~~c~.. ..N83004-4 ASTM 4643-00 1 1-NOV-04 AK %SOLFT N83004-5 EPA 418.1 M 12-NOV-04 NR 11-NOV-04 AS PtHCFT N83004-5 ASTM 4643-00 15-NOV-04 ADP %SOLFT.............. ..w.N83004-6 EPA 418.1 M 12-NOV-04 NR I1-NOV-04 AS PHCFT N83004-6 ASTM 4643-00 15-NOV-04 ADP %SOLFT N83004-7 EPA 418.1 12-NOV-04 HBA 12-NOV-04 HBA PHCFT Page 1 of I GEN CHEM A.C.lILST General Chemistry Case Narrative/Conformance/Non-Conformance Summary NO YES 1. flank levels below reportinglimits? if no, list analytes above reporting limits: 2. Spike blank or lab control data within acceptable limits? _ _If no, list analytes outside of acceptable limits. Refer to QC summary for additional comments: 3. Matrix Spike data within acceptable limits? _ _/Ifno, list analytes outside of acceptable limits. Refer to QC summary for additional comments: 4.Matrix duplicate data within acceptable limits?If no, list analytes outside of acceptable limits. Refer to QC summary for additional comments:_ kw 5. Samples prepared and analyzed within holding time? __Ifholding times were not met, list anal'ytes where holding times were exceeded and explain: 6. All analytical riteri met(c if no, list affected samples and elements:___ ___/Additional Comments:/I2-- /PY /-, QC Review Signature: Date._r Form: RG07 Rev. Date: 2jI 0I0 METHOD BLANK AND SPIKE RESULTS
SUMMARY
GENERAL CHEMISTRY Login Number: N83004 Account: AGMPAL -Arcadis Geraghty & Miller Project; PSEG-Salem, Artificial Island, Salem, NJ 4 'I lt MB RL Result Spike BSP BSP QC Units Amount Result %Recov Limits Batch ID AnlyeBach3 Petroleum Hydrocarbons Petroleum Hydrocarbons Petroleum Hydrocarbons GP25960/GN73662 GP2S986/GN73706 GP26003/GN73732 25 25 0.50.! : rimg/kg.:. mg/kg..::.::.:. mg/l 130 105 130 112 1.30 1.1.LSf..8:..>:.:80-120% Associated Samples: Batch OP25960i N83004-1, N83004-2, N83004-3, NB3004-4 Batch GP25986: N83004-5, N83004-6 Batch GP26003: N83004-7 Page I MATRIX SPIKE RESULTS SUM4ARY GENERAL CHEMISTRY Login Number: N83004 Account: AGMPAL -Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ 4w QC Original Spike MS QC Analyte Batch ID Sample Units Result Amount Result %Rec Limits Petroleum Hydrocarbons Petroleum Hydrocarbons Petroleum Hydrocarbons GP25950/GN73991 GP25986/GN73706 GP26003/GN?3732 N82700-1 N83004 -5 9182903-1 mg/kg mg/kg mg/lI<27 335 107<27 133 120<0.53 2.40 1.7 52-132%:{8S...'S.: 52-132%I l-~l~;K~:. 59-137%Associated Samples: Batch GP25960: N83004-1, N83004-2, N83004-3, N83004-4 Batch GP25986i N83004-5, N83004-6 Batch GP26003: N83004-7 Page I DUPLICATE RESULTS
SUMMARY
GENERAL_ CHEMISTRY Login Number: N83004 Account: AGMPAL -Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, No I Analyte Batch ID SC Sample Original DUP Units Result Result RLC RPD Limits Petroleum Hydrocarbons Petroleum Hydrocarbons Petroleum Hydrocarbons GP25960/GN73662 GP25986/GN73106 GP26003/GN73732 N82?00-1 mg/kg N03004-5 mg/kp N82913-4A mg/i<27 <27 o-34%<0,7 <0, 5.O.:-0 0-34%<0. 63 <0. 54 :0:0 .i 0-33%Associated Samples: Batch GP25960: N63004-1, N83004-2, N83004-3, N83004-4 Batch GP25986: N83004-5, N83004-6 Batch GP26003: N83004-7 Page I Th. WACCUTEST. Prep L,,.- ' -,PH Test: Petroleum Hydrocarbons Product: PHC Method: EPA 418.1 Mod Matrix: Soil I Solid Analytical wavenumber: 2924 cm-1 Balance #: bil Freon Used: midatlantic 400280a Spike Lot #: gnel 1-7141-phc Analyst: GN Batch ID: GP Batch ID: Analysis Date: Prep Date: HA GP25960 11110(2004 17:07 Cell BOT# # Sample ID Samnle Wt (a)Dilution Dilution Pren Comments 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 Diluion renComments Al GP25960-MB1 10.0000 _A2 GP25960-B1 10.0000 ' 1.0 mL of 1.30 mglmL A3 I GP25960-S1(n82700-1) 9.8000 1.0 mL of 1.30 mg/mL A4 1 GP25960-D 1(n82700-1 9.9000 A5 1 N83004-1 9.8000 A6 1 N83004-2 9.8000 A7 1 N83004-3 9.8000 A8 1 N83004-4 9.8000 A9 1 N82700-1 XX 9.9000 ornage brwn, sand like, no odor A10 I N82700-2 9.7 All 1 N82700-3 9.8000 A12 1 N82700-4 9.7000 A13 1 N82700-5 -9.9000 A14 1 N82700-6 9.9000 "' _!A15 1 N82700-7 9.8000 '. .\ fa r-S,\ (.N-, A16 1 N82700-8,i 9.7 ... .,4- .-.t-S -l /A17 1 N82830-3 9.9 A18 1 N82830-4 9.8 , 0.,-, -5' -" f,-, ....A19 1 N82830-5 9.9000 I % 2_-__"_C d, I I__"-____,_,____, A20 I N82830-6 9.8000. 1 , 1 I .In I A21 1 N82830-7 9.8000 " -x\- -V " -S- .r A22 I N82593-1 5.0000 high moisture content A23 I N82593-2 5.6000 1 .'-"\ 1. , -high moisture content A24 1 N82593-3 5.2000 1 , .. -,cv, .high moisture content XX = QC Sample j3ýý " p-, Analyst: _4r Date: -_/tZjO .QC Reviewer: Date: 11//1/4 Test Title: PHC Analyst: NR Prep Date: 11/11/2004 GP Batch #: GP25960EPA 418.1 Mod Analysis Date: 11/11/2004 GN Batch: GN73662 Ch' C Li MB:.BS I. MS 10 Time Smple X Valuestabsi Y Value FinglVol. Sam.Wj. Dilution Corr. Coef: 0.999114 15:13 15:30 Cal Bli$TD01 .STO 2 STD 3 STD 4 STD 5 STO 6 14:40 ICY 14:41 CCV GP25960-MB1 GP25960-B1 GP25960-SI GP25960-D1 N82593-1 N82593-2 N82593-2 N82593-3 N82593-3 N82700-.CCV N82700-2 N82700-3 N82700-4 N82700-5 N82700-6 N82700-7 N82700-7 N82700-8conf N82830-3 N82830-4 CCV N82830-4 N82830-5 N82830-5 N82830-6 N82830-6 N82830-7 N82830-7 N83004-1 N83004.2 N83004-3 CCV N83004-4 15:44 CCV 0 0.047 0.082 0.155 0.336 0.465 0.617 0.33 0.337 0.016 0.33 0,134 0.009 0.025 OVR 0.316 OVR 0.164 0.012 0.335 0.028 0.085 0.136 0.076 0.017 OVR 0.164 0.417 OVR 0.338 0.212 OVR 0.236 OVR 0.216 OVR 0.134 0.018 0.028 0.016 0.339 0.045 Corrc imn/Ii 0.0 ALom 129.44438 5.00 10.00 intercet: -0.75919 20.00 40.00 60.00 FinalVol. SamWt 80.00 /imil j Dilution Final Conc Units D.L Factor 41.96 NA NA NA NA mg/I 0.5 NA 42.86 NA NA NA NA mg/I 0.5 NA 1.31 25.0 10.00 1 3.3 "y/'mglkg 25.0 141.96 25.0 10.00 1 104.9 mgfkg 25.0 1 16.59 25.0 9.80 1 42.3 mg/kg 25.0 1.020408 0.41 25.0 9.90 1 1.0 mg/kg 25.0 1.0101012.48 25.0 5.00 1 12.4 mg/kg. 25.0 2#VALUEI 25.0 5.60 1 25.0 1.785714 40.15 25.0 5.60 5 896.1 mg/kg 25.0 1.785714#VALUE! 25.0 5.20 1 25.0 1.923077 20.47 25.0 5.20 5 492.1 mg/kg 25.0 1.923077 0.79 25.0 9.90 .1 2.0 mg/kg 25.0 1.010101 42.60 /NA NA NA NA mg/I 0.5 NA 2.87 25.0 9,70 1 7.4 mg/kg 25.0 1.03092810.24 25.0 9.80. 1 26.1 mg/kg 25.0 1.020408 16.85 25.0 9.70 1 43.4 mg/kg 25.0 1.030928 9.08 25.0 9.90 1 22.9 mg/kg 25.0 1.010101 1.44 25.0 9.90 1 3.6 mg/kg 25.0 1.010101 '#VALUE! 25.0 9.80 1 25.0 1.020408 20.47 25.0 9.80 5 261.1 mgtkg 25.0 1.020408#VALUE! 25.0 1 25.0 #DIV/0!53.22 25.0 9.90 1 134.4 mglkg 25.0 .1.010101#VALUE!/25.0 9.80 1 25.0 1.020408 42.99 NA NA NA NA mg/I 0.5 NA 26.68 25.0 9.80 50 3403.4 mg/kg 25.0 1.020408
- VALUE! 25.0 9.90 1 25.0 1.01010129.79 25.0 9.90 250 18806.6 mg/kg 25.0 1.010101
- VALUE! 25.0 9.80 1 25.0' 1.020408 27.20 25.0 9.80 25 1734.7 mg/kg 25.0 1.020408#VALUEl 25.0 9.80 1 25.0 1.020408 16,59 25.0 9.80 25 1057,8 mg/kg 25.0 1.020408 1.57 25.0 9.80 1 4.0 mg/kg 25.0 1.020408 2.87 25.0 9.80 1 7.3 mg/kg 25.0 1.020408 1.31 /25.0 9.80 1 3.3 mg/kg 25.0 1.020408 43.12 NA NA NA NA mg/I 0.5 NA 5.07 25.0 9.80 1 12.9 mg/kg 25.0 1.020408#VALUE! 25.0 1 25.0 #DIV/0O#VALUE! 25.0 1 25.0 #DIV/0!21 22 23 24 25 26 27 28 29 30 15:42 31 32 33 34 35 36 37 38 39#VALUE! 25.0 1#VALUE! 25.0 1#VALUE! 25.0 1#VALUE! 25.0 1#VALUEI 25.0 1#VALUE! 25.0 1#VALUE!/25.0 1 0.338 42.99 " NA NA NA#VALUE! 25.0 01#VALUE! 25.0 27.00 1#VALUE! 25.0 28.00 1#VALUE! 25.0 29.00 1 25.0 #DIV/0!25.0 #OIV/0!25.0. #DIV/0!25.0 #DIV/0I 25.0 #DIV/01 25.0 #DIVIOI 25.0 #DIV/0!NA mg/I 0.5 NA 25.0 #DIVJO0 25.0 0.37037 25.0 0.357143 25.0 0.344828 20 SACCUTEST ( Test: Petroleum Hydrocarbons Product: PHC Method: EPA 418.1 Mod Analyst: (1 GNBatch ID: Ji ..GPBatch ID: -1 P,.j Date: 1i ] ,V-)Units: mglkg I.Preparation Batch QC Summary UnitsMethod Blank ID: 'z5-1 ' Al Date: j_/It/O. Result: Z' 25.U DL: ZC .<DL:i S Spike Blank ID: ' &( Date: Result: (0 57 Spike: 130 %Rec.:_jb /7 " Duplicate ID: Samp. Result: .~ c'Dup. Result: (2,S.c.', %RPD: O'0 MS ID: Y .Samp. Result: '-2S.O MS Result: Spike:_3.L
%Rec: -3Method Blank ID: Date: 0 Resilt: DL: <DL: Spike Blank ID: Date: Result: Spike: %Rec.:_ _Duplicate ID: Samp. Result: Dup. Result: %RPD:__MS ID: Samp. Result: MS Result:_ Spike:_ %Rec:_Analysis Batch QC Summary Units / .i z-ICV (Ext): 1 t,4 __ Result: '-.Z-) TV: 20 %Rec: /o.-5 ResuWt T.7- V: % /Rec.: lZo 7 Result: -- TV: [ %Rec.: 104%Result:" TV: % /07'Resu;,I: -TV:, l %Rec.:,. Result:-- TV: , C CCB: CCB: CCB: CCB: CCB: CCB'Result:______ DL: <DL: Result: DL:" <DL: Result: DL: <DL: Result: DL: <DL: Result: DL: <DL: Result: DL: <DL: Reagent Reference Numbers: I __* I Freon Manufacturer: Sodium Sulfate Manufacturer: Silica Gel Manufacturer: Lot Number: Lot Number: Lot Number: Analyst:k)' Comments: Date: Y_ i'C Form: GN-109-01 Rev. Date:2115!99 21 rI SACCUTEST GENERAL CHEMISTRY STANDARD PREPARATION LOG Product: T-Ptc GN r GP Number: "-'- ina@ Conc.Stock of Intermediate Stock used to Stock volume used Final Intermediate Expiration Standard Description prepare standard concentration in ml Diluent Volume (mgll) Date Analyst Date_bI. I L- r O _K, ,S-P9C (o ooo ,,,, 10 FFEON ¶Qo,1( 6 Wy Itl2 ,', ,"QcL- YE"-&TOcK glop' pp,\ I0 j FR0 4 ION iooo " I 7 7 i Intermediate Intermediate or Stock Intermediate or Stock Final Conc.used to prepare or Stock volume used Final of Standard Expiration Standard Description standard concentration in ml Diluent Volume (mg/i) Date Analyst Date S- .I~ G yOo- 0N z -4 IICDI JP 0 I /hi ST tI 3 ..._,_o ...STD ff40" ' a 'I I-I- t* -~ I l-t f-I--I I C,,..0 I I go.o 0 i~)4 F--1 t ~1.4-7..a"rr( it" ').l--JC-A u-;l j : X-LM I Id I I lio- () I Form: GN121 Rev. Date:9/14/01 1 ACCUTEST Reagent Information Log -PHC Reagent Fluorocarbon -113 Spike Solution Sodium Sulfate Hydromatrix Silica Gel ICV CCv Reagent # or Manufacturer/Lot V, Cu ?~~o-);xjý//- .-7,tlP t-xJAC/- 37Lh~b7AJiUO :$c>/ 3 fr4 f0 6 Io --7o /,p/Exp. Date A-),4-.... 2 -#~All standards and stocks were made as described in the SOP for this method (circle one): oY If no (N), see attached page for standards prep, Form: GN-087 1-45B Rev. Date:10/20/2004 or N 2-- cACCUTEST, Prep Log,- PH Test: Petroleum Hydrocarbons Product: PHC Method: EPA 418.1 Mod Matrix: Soil I Solid Analytical wavenumber: 2924 cm-1 Balance #: b-li Freon Used: VIRGIN 400280A Spike Lot #: gnell-7141-phc Analyst: AMINAS GN Batch ID: 7"3 706 GP Batch ID: GP259 6 Analysis Date: ""f1-"(Prep Date: 1111112004 15:49 Cell BOT Sample 10 Sameole Wt Ine)Dilution Dilution Prep Comments 1 2 3 4 5 6 7 8 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 A23 GP25986-MB1 A22 GP25986-B1 ......... I ml of 1.30mg/ml A3 5 GP25986-S1 10.'3000 .................. _ 1 m l of 1.30 m g/ml A6 5 GP25986-Dl 9.7000 A19 I N82152-10 9.8000 A13! I N82152-:11... 9.5000 ...A24 1 N82152-12 10.2000_'A21 1 N82152-13 9.9000 A4 5 N83004-5 XX 9.8000 A18 1 N83004-6 10.2 A2 1 N83011-1 10.1000_.. A15 I N83011-2 9.7000 _...A17 I N83011-3 9.7000 A9 I N83011-4 9.7000_.... A14 I N83011-5 9.9000 "'A 16 1 N 830 11-6 9.8 ...... ......Al 1 N83123-" 10.2 7.5, fv-.j .'- z-",-n? I (r-l,-e,.A7 1 N83123-2 9.8 , I .I --l frf , ..A5 I N83123-3 10.3000 " ) 0,5T, I --' ,s5'P! f r&'/\A12 1 N83123-4 10.0000 A10 I N83123-5 9.9000 f 2, 5" ,, .-, z-' i 1/,rV, A8 1 N83123-6.. 9.900,0 All 1 N83123-7 9.8000 XX = QC Sample Analyst: ae"vwr Da te: OC Reviewer. I ui.ai. r t:Lf 'JICU~ 1l 91 1 .u IVIf -" Test Title: PHC Analyst: NR Prep Date: 11/11/2004 GP Batch #: GP25986 EPA 418.1 Mod Analysis Date: 11/1212004 GN Batch: GN73706 2 7 2 Cl,-k QC_e Time Sample Cal Blk STD 1 STD 2 STD3 STO 4 STD 5 Sf05 15:27 icy 15:28 CCv MB GP25986-MB1 B, I. MS GP259B6-S1 DUP GP25986-D1 N82152-10 N82152-11 N82152-12 N82152-13 N83004-5 o N83004-6 15:45 CCV 1 N83011-1 2 N83011-2 3 N83011-3 4 N83011-4 5 N83011-5 N83011-6 N83123-1 N83123-1 9 N83123-2 0 N83123-2 16:02 CCV N83123-3 2 N83123-3 3 N83123-4 4 N83123-5 5 NB3123-5 N83123-6 N83123-7 10:19 CCY CCV 0 0.043 0.083 0.157 0.338 0.463 0.613 0.329 0.338 0.015 0.351 0.365 0.04 0.025 0.018 0.017 0.073 0.04 0.026 0.34 0.014 0.017 0.025 0.009 0.267 0.015 OVR 0.181 OVR 0.26 0:338 OVR 0.271 0.057 OVR 0.243 0.297 0.038 0.338 Conc Impill 0.0 slope: 129.92357 5.00 10.00 Intercept -0.782899 20.00 40.00 60.00 FinalVol Sam WI 80.00 ;' i l j Dilution Final Conc. Units DL Factor 41.96 NA NA NA NA mg/i 0.5 NA 43.13 NA NA NA NA mg/I 0.5 NA 1.17 25.0 10.00 1 2.9 mg/kg 25.0 1 44.82 25.0 10.00 1 112.1 mg/kg 26.0 1 46.64 25.0 10.30 1 113.2 mg/kg 25.0 0.970874 4.41 25.0 9.70 1 11.4 mg/kg 25.0 1.030928 2.47 25.0 9.80 1 6.3 mg/kg 25.0 1.020408 1.56 25.0 9.50 1 4.1 mg/kg 25.0 1.052632 1.43 25.0 10.20 1 3.5 mg/kg 25.0 0.980392 8.70 25.0 9.90 1 22.0 mg/kg 25.0 1.010101 4.41 25.0 9.80 1 11.3 mg/kg 25.0 1.020408 2.60 25.0 10.20 1 6.4 mg/kg 25.0 0.980392 43.39 NA NA NA NA mg/i 0.5 NA 1.04 25.0 10.10 1 2.6 mg/kg 25.0 0.990099 1.43 25.0 9.70 1 3.7 mg/kg 25.0 1.030928 2.47 25.0 9.70 1 6.4 mg/kg 25.0 1,030928 0.39 25.0 9.70 1 1.0 mg/kg 25.0 1.030928 33.91 25.0 9.90 1 85.6 mg/kg 25.0 1.010101 1.17 25.0 9.80 1 3.0 mg/kg 25.0 1.020408#VALUE! 25.0 10.20 1 25.0 0.980392 22.73 25.0 10.20 25 1393.0 mg/kg 25,0 0.980392
- VALUE! 25.0 9.80 1 25.0 1.020408 33.00 25.0 9,80 25 2104.4 mg/kg 25.0 1.020408 43.13 NA NA NA NA mg/I 0.5 NA#VALUE! 25.0 10.30 1 25.0 0,970874 34.43 25.0 10.30 50 4176.0 mg/kg 25.0 0.970874 6.62 25.0 10.00 1 16.6 mg/kg 25.0 1#VALUE! 25.0 9.90 1 25.0 1.010101 30.79 25.0 9.90 125 9718.6 mg/kg 25.0 1.01010137.80 25.0 9.90 1 95.5 mg/kg 25.0 1.010101 4.15 25.0 9.80 1 10.6 mg/kg 25.0 1.020408#VALUE! 25.0 1 25.0 #DIV/0!#VALUE! 25.0 1 25.0 #DIV/0O#VALUE! 25.0 1 25.0 #DIV/0!43.13 NA NA NA NA mg/I 0.5 NA#VALUE! 25.0 1 25.0 #DIV/01#VALUE! 25.0 1 25.0 #DIV/0I WVALUE! 25.0 1 25.0 #DIV/0I#VALUE! 25.0 1 25.0 #DIV/O!#VALUE! 25.0 1 25.0 #DIVI0!#VALUE! 25.0 1 25.0 #DIV/0!#VALUE! 25.0 1 25.0 #DIV/O0#VALUEr 25.0 1 25.0 #DIVOI#VALUE! 25.0 27.00 1 25.0 0.37037#VALUE! 25.0 28.00 1 25.0 0.357143
- VALUE! NA NA NA NA 0.5 NA#VALUE! 25.0 29.00 1 25.0 0.344828*VALUE! 25.0 30.00 1 25.0 0.333333#VALUE! 25.0 31.00 1 25.0 0.322581 '-' '-VVALUE! 25.0 1 25.0 #DIV/O!X VaiJeslabs)
YValug FinalVol. Sam. W. Dilution C Qrr con!: 0.9988857 2 2.2: 2.2 27 21 29 30 31 32 33 34 35 36 37 38 39 41 42 43 44 QACCUTEST ( Test: Petroleum Hydrocarbons Product: PHC Method: EPA 418.1 Mod Analyst: __,___ ", GNBatch ID: !nVI 322 0 GPBatch ID:.Date: VI l eiJ[...,f 'Units: mg/kg-i, .f f Preparation Batch QC Summary Units = ,,L'LA/ K MethodBlankID: -Date: l I '1 Result: & Z.() DL: Z5-.C <DL: Spike Blank ID: t -i Date: .Result: I 2-- %Rec.: E,,.8Duplicate ID: -Samp. Resul: 2 Dup. Result , %RPD: a 'C MS ID: 7,j SiSamp. Result: -2 7 zt MS Result:
- Spike: j °Re:_5Cj Method Blanlk ID: Date:_ _ Result: DL: <DL: Spike Blank ID: Date:_ Result:_ Spike:_ _ %Rec.:_ _Duplicate ID: Samp. Result: Dup. Result: %RPD:___MS ID: Samp. Result: MS Result: Spike:_ %Rec: Analysis Batch QC Summary Unjts = .i!I ICV (Ext): I( 1_ Result:. TV: 1 4c.,Od %Rec: tos 5 CCV: Result: TV: %Rec.:__i"'_Y%
CCV: Result: 31. TV: ___%Rec.:L -0/ 17'1 CCV: Result: ' 3 TV: -%Rec.: [0 K !5 CCV: Result: ' 13 TV; %Rec.: 10 / rL CCV: Result: TV: %Rec.: CCV: Result: _ TV: _ %Rec.: CCB: CCB: CCB: CCB: CCB: CCI'Result: -Result: Result:_Result: Result:__Result:_DL: DL: DL: DL: DL: DL:<DL:<DL:<DL:<DL:<DL:<DL: Reagent Reference Numbers: §-.e..- 4" .. --......... ..Freon Manufacturer: Lot Number: Sodium Sulfate Manufacturer: Lot Number: Silica Gel Manufacturer: Lot Number: Analyst: ,J Dale: 11/2/Comments: Form: GN-109-01 Rev. Date:2/15199 "-'G r UACCU'TEST GENERAL CHEMISTRY STANDARD PREPARATION LOG-P Product: __I_2 --GN rGP Number: C-rK?.370,C --" Final Conc.Stock of Inlermediate Stock used to S~oc,: volume used Final Intermediate Expiraiion Standard Description prepare slandard concentration in m; Diluent Volume (mg/I) Date Analyst Date r) (L-E T-L cTo cK OM~C -7CDL4(-p(-c-1 0C w !ocPEI, { FRE6N (oomk I 100OPPfA -tM0 jIi cz Inlerrmediate Intermediate or Stock Intermediate or Stock Final Conc.used to prepare or Stock volume used Final of Standard. Expiration Standard Description standard concentration in ml Dituent Volume ((mg/1) Date Analyst Date jQ-TD I 03E LO -- 0 ~ E L- E--V 1o&001 ffiA 0-52~ !Sf ICSi t ....i~ .STD Q- f36,O -, ... C: ... ,0-0 ..,-F--)(T- ,,o ." ,,,,Ji--'7o q y-pHc- -A- 14o rr ...)£-".3 UACCUTEST Reagent Information Log -PHC IL F luarocarbon -1 13 Spike Solution Sodium Sulfate Hydronatrix sl lkca Gel:cc Re agt cn1l--LM a nuf acwiULCo.Lt (1 ,Q5/i71L(Ul g/10_C jz 70 A~~$~7 Y~25 Ex.QD~ajP All s %ve r c I i i ;v 1:; :1 n it i I( )r I i,.-, It I V. I Ic Oil FACCUTEST Prep Log I ,4H Test: Petroleum Hydrocarbons Product: PHC Method: EPA 418.1 Mod Matrx: Soil f Solid Analytical wavenumber: 2924 cm-1 Balance A: bil Freon Used: virgin 400280a Spike Lot #: gnell-7141-phc Analyst: GN Batch ID: GP Batch ID: Analysis Date: Prep Date: NR GP26097/1111912004 8:51 Cell BOT Sample_ 1i"~2mr~f~ Wf icr 1 rlhihtfnn fl'lihtinn Prr, n Comments 1 2 3 4 5 8 7 8 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 Til " GP26097-MB1 GP26097-BI _ " ...... ... 1ml of1.30 mnIml.I GP26097-S1(n82237-2, 10.3000 1 ml of 1.30 mg/mi I GP26097-D1(n82237-2' 10.3000 , 1 N82237-1 9.8000--1 N82237-2 XX 10.3000 .... " ... .. brown moist sand, few small pebbles, sit odor I I N82237-3 9.6000 1 N82237-4 10.3000 .... ....1 N82237-5 9.8000 ,A, I N82237-6 10.2000 I___ 1 N83561-10 9.9000 12. 1 N83561-3 9.7000 2- 2-5,r-% "-_--_ __2_ _.__-_,L, 11/2 N83561-4 _ '__5--A ll I N83561-5 /T.., T ... ...... ._....AIS 1 N83561-6 __,___'__....__-_________--_-___- 1 N83561-6 7,_ _ _ _ _I N83561-8______________ _____________ ____I N83561-9 I Z ,, I ........... _,'i I N83706-1 ,, , I/ __ .. ... , ..... l "_I I. .. " I f --N -.....,k.I Mall-Mr-A 4 C. t~ ___________ 4 I 1 NR37OlR-7 1 N30-7 -I 1 NN83827-1 __________________ --t 4 tDfle f.-,O17nflA i/.j-I.XX = QC Sample 6(C)Analrst.~~~~ Date: kfO C Reviewer:________ it Total Petroleum Hvdrocaroon zours Test Title: PHC Analyst: JAREDO Prep Date: 11/19(2004 GP Batch #: GP26097 EPA 416.1 Mod Analysis Date: 11/20/2004 GN Batch: GN73991 7 9 10 TI-e Sampale Cal 81k STD 1 STO 2 STO 3 STE 4 STO 5 STD 6'Cv CCv MB GP26097-MBI BS GP26097-B1 MS GP26097-SI OUP GP26097-DI N82237-1 N82237-2 N82237-3 N82237-4 N82237-5 N82237-6 CCV N53561-10 N83561-3 N83561-3 N83561-4 N83561-5 N83561-6 N83561-6 N83561-7 N83561-7 N83561-8 CCV N83561-9 N83706-1 N83706-2 N83706-2 N83706-6 N83706-7 N83827-1 GP25960-S2 CCV CCV X Valuestabs) Y Values FinglVol. Satn.VWI. Dilution CogrrCoel: 0,9987039 Conc Img/ll 0 0.0 S: 127.48608 0.041 5,00 0.08 10,00 Intercent -0.574441 0.16 20.000.345 40.00 0.47 60.00 Final Vol. Sam W 0.622 80.00 L. L Dilution FnalCon. Units DL Factor 0.329 41.37 NA NA NA NA mg/I 0.5 NA 0.34 42.77 NA .NA NA NA mg/I 0.5 NA0.011 0.83 25.0 10.00 1 2.1 mg/kg 25.0 1 0,356 44.81 25.0 10.00 1 112.0 mg/kg 25.0 1 0.329 41.37 25.0 10.30 1 100.4 mg/kg 25.0 0.970874 0.009 0.57 25.0 10.30 1 1.4 mg/kg 25.0 0.9708740.011 0.83 25.0 9.80 1 2.1 mg/kg 25.0 1.020408 0.007 0.32 25.0 10,30 1 0.8 mg/kg 25.0 0.970874 0,004 -0,06 25.0 9.60 1 -0.2 mg/kg 25.0 1.041667 0.026 2.74 25.0 10.30 1 6.7 mg/kg 25.0 0.970874 0.016 1.47 25,0 9.80 1 3.7 mg/kg 25.0 1.020408 0.011 0.83 25.0 10.20 1 2.0 mg/kg 25.0 0.980392 0.34 42.77 NA NA NA NA mg/I 0.5 NA 0.016 1,47 25.0 9.90 1 3.7 mg/kg 25.0 1,010101 OVR #VALUE! 25.0 9.70 1 25.0 1.0309280.343 43.15 25.0 9.70 250 27805.0 mg/kg 25.0 1.030928 0.117 14.34 25.0 9.50 1 37.7 mg/kg 25.0 1.052632 0.02 1.98 25.0 10.10 1 4.9 mg/kg 25.0 0.990099 OVR #VALUE! 25.0 9.70 1 25.0 1.030928 0.402 50.67 25.0 9.70 5 653.0 mg/kg 25.0 1.030928 OVR #VALUEI 25.0 9.70 1 25.0 1.030928 0.263 32.95 25.0 9.70 5 424.7 mg/kg 25.0 1.030928 0.003 -0.19 25.0 9.90 1 -0.5 mg/kg 25.0 1.0101010,34 42.77 NA NA NA NA mg/j 0.5 NA 0.073 8.73 25.0 10.10 1 21.6 mg/kg 25.0 0,990099 0.012 0.96 25.0 10.00 1 2.4 mg/kg 25.0. 1 OVR #VALUE! 25.0 9.80 1 25.0 1.020408 0.496 62.66 125.0 9.60 25 3996.1 mg/kg 25.0 1.020408 0.039 4.40 25.0 9.90 1 11.1 mg/kg 25.0 1.010101 0.009 0.57 25.0 10.20 1 1.4 mg/kg 25.0 0.980392 0.254 31.81 25.0 .10.10 1 78.7 mg/kg 25.0 0.990099 0.318 39.97 25.0 10.00 1 99.9 mg/kg 25.0 1#VALUE! 25.0 1 25.0 #DlVI0!#VALUEI 25.0 1 25.0 #DIV/01 0.341 42.90 NA NA NA NA mg/I 0.5 NA#VALUE! 25.0 1 25.0 #DIV/0I#VALUE! 25.0 1 25.0 #DIV/O!#VALUEI 25.0 1 25,0 #DIV/0!#VALUE! 25.0 1 25.0 #DIV/OI#VALUE! 25.0 1 25.0 #DIV/01#VALUE! 25.0 1 25.0 #DIV/0!#VALUE! 25.0 1 25.0 #DIVJ0!#VALUE! 25.0 1 25.0 #DIV/0!#VALUEI 25.0 27.00 1 25.0 0.37037#VALUE! 25.0 28.00 1 25.0 0.357143#VALUE! NA NA NA NA 0.5 NA 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 3Et 44 41 42 43 44#VALUE! 25.0 29.00 1 25.0 0,344828#VALUE! 25.0 30.00 1 25.0 0.333333'VALUE! 25.0 31.00 25.0 ,322581,: W-VALUE! 25.0 1 25.0 h#oIV/0! ACCUTESTs Test: Petroleum Hydrocarbons Analyst: _-____Product: PHC GNBatch ID: j Method: EPA 418.1 Mod Units: mg/kg GPBatch ID:. a 1:l , Date: I\ Preparation Batch QC Sum m ary Units = -8 ....Method Blank ID: )X' Date:j-L ' Result: DL: <DL:.l -Spike Blank lD:jiI:ii'ij .... Date: Result: i12 Spike: 130 %Rec.: _____Duplicate ID:. _ _ Samp. Result: <"." Dup. Result: 4-L51- %RPD:-MS ID: 5S- Samp. Result: _ej" MS Result: If.*j Spike: 1 -%Rec:.Method Blank iD: Date: Result: DL: <DL: Spike Blank ID: Date: Result: Spike:_ %Rec.:_'__ Duplicate ID: Samp. Result: Dup. Result: %RPD:__MS ID: SQ.. Samp. Result: MS Result: Spike: 1"5Z %Rec: Analysis Batch Q Summary Units = ! Re,: ICV (Ext):_ Result: '-11 TV:ii-L7-/oRec (03- SýCCV: _ Result:____ TV: -%Rec.: ___-CCV: Result:- 4 Z2' TV: M, ,- %Rec.: 10'? -CCV: Result:Jl. TV: L4 -%Rec.: (0'7-,'CCV: -NY _ Result:J. TV: Lý -0 %Rec.: 10-1-.7 CCV: Result: TV: %Rec.: CCV: Result:_ TV: %Rec.: CCB: Result: -DL: <DL: CCB: Result: DL:' <DL: CCB: Result: -DL:' <DL: CCB: Result: DL: <DL: CCB: Result:_ DL: <DL: CCB : Result: DL: <DL:[Reagent Reference Numbers: -Freon Manufacturer: Lot Number: Sodium Sulfate Manufacturer: Lot Number: Silica Gel Manufacturer: Lot Number: Analyst: Date: ..o 0 Comments: Form: GN-109-01Rev. Date:2/15/99 ACCUTEST, c- -73c i Reagent Information Log -PHC Fluorocarbon -11 3 Spike Solution Sodium Sulfate Hydrornatrix SdIca Gel:CCV Rc a a n uf a ciurrLot V4~6'jt C 1 -7oY7 -Yi'c Ir: 17 c) 76,v -#f A/. -II ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ .', .[i. .. :.h .)11: ..,. --..----'. -NI ( ii 4., I I LJA. UACCUYUEST GENERAL CHEMISTRY STANDARD PREPARATION LOG-P ro d u c t: N-um b (: r G P N um b er: ýý F,'7" _, -Final Conc.Stock of Intermediate Slock used to Stock- volume used Final Intermediale Expiration Standard Description prepare standard concen~ration in ml Diluent Volume (mg/f) Date Analyst Date.bIL. STb STock 69 E (0--70-4S-e-" ooo(0 M .... IA l (, Ic, ooopc it .. i0 FREON Iot4I ICOopp ,m Itm- I_.-q__ -Intermediate intermediate or Stock Intermediate or Stock Final Conc.used to prepare or Stock volume used Final of Standard Expiration Standard Description standard concentration in ml Diluenl Volume (m/Il) Date Analyst Date 60E IPX~-7 0 i N<- OM J VptJ Co.!S TV'fbN wt4L O iti STD q- __, -._.__ _ _ _ _ _...._ ~ .....C~)El/I L-MV~?it i-I~(,f\i~d cJ~dII~..- I J I 0 Form: GN121 12 A C.A .EST.Prep Log -TPH Test: Petroleum Hydrocarbons Product: PHC Method: EPA 418.1 Mod Matrix: Water Analytical wavenumber: 2924 cm-1 Freon Used: midatlantic 400280a Spike Lot #: gnell-7141-phc Analyst: HA GN Batch ID: GO1'-33"7 GP Batch ID: GP26003 Analysis Date: 1 -Prep Date: 1111212004 15:36 pH Check Sample Vol (Ml) Dilution SOT # Sample ID Dilution Prer Armearance Odor 21 21 2: 2;2'I __ GP26003-MBI 1 -2,_________ 1_________ O_________________ __________ 2 GP26003-81 ______3 -1' GP26003-SI(n82903-1) /I 9!'co r 0~ 16'ar=ICC 4 GP26003-DlI(n82913-4 ) 1,1 11W________ 5- N82692-1 A~- L71 99 0 --5 2,9 ,- 1,e"ra 5 N82903-1 XX zVj 9150 __________________ 8 N82gl3-4A XX/4 150 ri A__.6_ V~-r r.IaULAO tiaexiof 9 1 N82923-1 1%W ____________ '.civ -,eA lV~01__ N83004-7 r,- IML rnnvk 2 4 3_____4I 6I __________________ 7 __________________
- 8) _______________________________________________
____________________________________________ XX -QC.AP F~k~~~~~~~~v OCOA 1 A r* "01 j27(~.- ~ -Fve6*n CO~Spike Info: r.O rN,~ 0 ~ t6 Analyst: Date: QC Reviewer:D Date I orat f-retruleut it nyulul.d LjUv I. vv a LIO Test Title: Analyst: HA Prep Date: 11/1212004 GP Batch #: GP26003 EPA 418.1 Analysis Date: 11/1212004 GN Batch: GN73732 Time sampleli Cal BIk STD I STD 3 STD 4 STD 5 STO 6 22:39 Jcv 22:40 CCv GP26003-MBI GP26003-BI GP26003-S1 GP26003-Dl N82692-1 N62692-1 N82692-2 N82692-2 N82903-1 N82913-4A 20:55 CCV N82923-1 N83004-7 20:59 CCV X Value;labsl YValues Final Vol. SmVol. DIfution Crr. Coef: 0,9988857 Cone (mopll 0 0.0 m.ae 129.92357 0.043 5.00 0.083 10.00 intercept -0.782899 0.157 20.000.338 40.00 0.463 60.00 FinalVol Sam Vol 0.613 80.00 il Dilution Final Conc. Units 0.339 43.26 NA NA NA NA mg/0.332 42.35 NA NA NA NA mg/l 0.013 0.91 100.0 1000 1 0.09 mg/I 0.094 11.43 100.0 1000 1 1.14 mg/I 0.129 15.98 100.0 930 1 1.72 mg/I0.012 0.78 100.0 920 1 0.08 mg/I OVR #VALUEl 100.0 990 1 0.221 27.93 100.0 990 50 141.06 mg/I OVR #VALUEI 100.0 1 1 0,316 40.27 100.0 1 5 20136.47 mg/I 0.043 4.80 100.0 950 1 0.51 mg/I 0.014 1.04 100,0 790 1 0.13 mg/I 0.336 42.87 NA NA NA NA mg/I 0.036 3.89 100.0 820 1 0.47 mg/q 0.008 0.26 100.0 990 1 0.03 mg/l#VALUEI 100.0 100 1#VALUEI 100.0 1000 1#VALUE! 100.0 1000 1#VALUEI 100.0 1000 1#VALUE! 100.0 1000 1#VALUEI 100.0 1000 1#VALUE! 100.0 1000 1#VALUE! 100.0 1000 1 0.333 42.48 NA NA NA NA mg/l#VALUE! 100.0 1000 1#VALUE! 100.0 1000 1#VALUEI 100.0 1000 1#VALUEI 100.0 1000 1#VALUEI 100.0 1000 1#VALUEI 100.0 1000 1#VALUEl 100.0 1000 1#VALUE! 100.0 1000 1#VALUE! 100.0 1000 1#VALUEI 100.0 1000 1#VALUE! NA NA NA NA WVALUE! 100.0 1000 1#VALUE! 100.0 1000 1#VALUE! 100.0 1000 1#VALUE! 100.0 1000 1#VALUEI 100,0 1000 1#VALUEI 100.0 1000 1#VALUE! 100.0 1000 1#VALUE! 100.0 1000 1#VALUE! 100.0 1000 1#VALUE! 100.0 1000 1#VALUE! NA NA NA NA#VALUE! 100.0 1000 1#VALUE! 100.0 1000 1100.0 1000 1#VALUE! 100.0 1000 1 21 22 23 24 25 26 27 28 29 30 DL Factor 5.0 NA.5.0 NA 0.5 1 0.5 1 0.5 1.075269'. 0.5 1.086957 0.5 1,010101 0.5 1.010101 0.5 1000 0.5 1000 0.5 1.052632 0.5 1.265823 5.0 NA 0.5 1.219512 0.5 1.010101 0.5 10 0.5 1 0,5 1 0.5 1 0.6 1 0.5 1 0.5 1 0.5 1 5.0 NA 0.5 1 0.5 1 0.5 1 0.5 1 0.5 1 0.5 1 0.5 1 0.5 1 0.5 1 0.5 1 5.0 NA 0.5 1 05 1 0.5 1 0.5 1 0.5 1 0.5 1 0.5 1 0.5 1 0.5 1 0.5 1 5.0 NA 0.5 1 0.5 1 0.5 1 0.5 1 CCV 31 32 33 34 35 36 37 36 39 41 42 43 44 CCV 35 .UACCUTESTO Test: Petroleum Hydrocarbons Product: PHC'Method: EPA 418.1 Analyst: kh GNBatch ID: 15"1-GPBatch 1D: ')-4.x Date: k\ 1%'7- 1 Units: mg/I Preparation Batch QC Summary Units = IL Method Blank ID: &Pý,oo, mW Date: i\101-i* Result: L O..3 DL: 0.50 <DL-Spike Blank 10: -61 Date: 4 Result: I.A- Spike: %Rec.: S I D 10 Samp. Result:-' /L0-53 Dup. Result: .%RPD: o DuplicateD1: Samp. R l_-S u 1 -k __%MS ID:" -I Samp. Result: O.,5. MS Result: Spike: 1.~4o %Rec:, %.,,4-'I.. Method Blank ID: Date: Result: .DL: <DL: Spike Blank ID: Date: Result: Spike:_ %Rec.: Duplicate ID: Samp. Result: Dup. Result: %RPD: MS ID: Samp. Result: MS Result: Spike:_ %Rec: Analysis Batch QC Summary Units ICV (Ext): v\)v)ib4 Result: 4,SS TV: A.O) %Rec:i, .o ..itp, vjr,-jvA-CCV: Result:A-.-4-V4 TV: -%Rec.: 1D40.CCV: Result: 4. '9 TV: .. %Rec.: 1011I.CCV: Result: A- kJ TV: %Rec.: 1o0( -I CCV: Result: TV: %Rec.:_CCV: Result: _ TV: %Rec.: CCV: Result: TV:. %Rec.: CCB.: Result: CCB: Result: CCB: Result: CCB: Result:'CCB: Result: CCB: Result: DL: DL: DL: DL: DL: DL:<DL:<DL:<DL:<DL:<OL:<DL: IReagent Reference Numbers: Freon Manufacturer: Lot Number: Sodium Sulfate Manufacturer: Lot Number: Silica Gel Manufacturer: ___________Lot Number: Comments:. SForm: GN'-109 Rev. Date 2J15199 SACCUTEST DOCUMENTATION OF IMPROPER SAMPLE PRESERVATION Form: GN-175 Rev. date:2/10/04 QC. Review: C SACCUTEST GENERAL CHEMISTRY STANDARD PREPARATION LOG 0i Product: I t GNr GP__N~umb--er'. ".-i-:7 Final Conc.Stock of Intermediate Stock used to SIock volume used Final Intermediate Expiration Standard Description prepare standard concenration in mnl Diluent Volume (mg/l) Date Analyst Date 1:[L. "'STb *STocK C_-Eto-7A E -7To4.S- tP --"0...ooop J .. FEoN. co,,, ..... 0 j\, ____bl L.g'c"TOCK ' (O IQ FR6EON cob,, 1Oooppp tV2-4o W. _____Intermediate Intermediate or Stock Intermediate or Stock Final Conc.used to prepare or Stock volume used Final of Standard Expiration Standard Description standard concentration in ml Diluent Volume (mg/I) Date Analyst Date 60e k. --70Li7- r*C I JS6N lob-to L ST1:V :3 ,:0.S-TD 4 t..oa~I= -_________"_b __,D_ (e,o. OJGJ ... D. --7 qo~ , -piI qo 'r I ,~X( ~i>~t-7 ~-ii 7 r,- ,,0 r n w'ACCUTEST, G,4161!b72-Reagent Information Log -PHC Fluorocarbon -1 1'3 Spike Solution Sodiurm Sulfate Hydromatrix Sliia Gel IC':Cc'.Re aou-LoLM an uf achr.QriLD~t 1Nrc'- 70 Y2//Ex-D-aic 1 75%i... ....... 7iad ..~c ....: vr~ : ~ ~c c~ 'lilU C I~ I: 32 ) K ~W.* ( ;N.~j.' 1 -.3 Appendix C Well Records, Well Completion Details and Boring Logs ARCADIS Sample/Core Log Boring/Well Well AU Site Location Artificial Island, Hancock's Bridge, New Jersey Project/No. PSEG Nuclear, LLC Salem Generrating Station/NP000603.0001 Drilling Drilling Started 11/9/2004 Completed Type of Sample/inches Coring Device Page 1 of 1 11/9/2004 NA rval NA feet Total Depth Drilled Length and Diameter of Coring Device Land-Surface Elev.Drilling Fluid Used Drilling Contractor Prepared By 7.0 Feet Hole Diameter 1212 inch diameter vacuum extraction flex-pipe feet Water Sampling Inter DEstimated Datum Plant Datum rfSurveyed Drilling Method Vacuum Extraction Unitech Drilling and Jetline ServicesDeric Kearns Driller Rich Helper Jim Hammer Hammer Weight NA Drop NA inchesSample/Core Depth (feet below land surface)From To Core Blow Recovery Counts (feet)PID Reading (ppm)0.0 Sample/Core Description SAND, medium, tan, some silt, moist, loose.4.0 L 4.0 7.0 -- SAND, medium, tan, some silt, wet, stronq hydrocarbon odor.Description of cuttings based on visual observations during vacuum extraction. __Borehole completed as Monitoring Well AU.4 4-& 4 4 4 4
- 4 4 4 .4 4 4 4-4 4 4 4 .4 4 .4 4 App. C Soil Boring Logs Wells AU thru AZ, X.xls 2/15/2007 ARCADIS Sample/Core Log Boring/Well Well AV Site Location Artificial Island. Hancock's Bridae, New Jersey Project/No.
PSEG Nuclear, LLC Salem Generrating Station/NP000603.0001 Drilling Drilling Started 11/8/2004 Completed Type of Sample/inches Coring Device Page 1 of 1 11/8/2004 NA val 3.5 -4.0 feet Total Depth Drilled Length and Diameter of Coring Device Land-Surface Elev.Drilling Fluid Used Drilling Contractor Prepared By 10.0 Feet Hole Diameter 1212 inch diameter vacuum extraction flex-pipe feet Water Sampling Inter nEstimated Datum Plant Datum E]Surveyed Drilling Method Vacuum ExtractionUnitech Drilling and Jetline Services Dentc Kearns Driller Rich Helper Jim Hammer Hammer Weight NA Drop NA inches Sample/Core Depth (feet below land surface) Core Blow Recovery CountsFrom To (feet)plo Revading lppm)Sample/Core Description 0.0 1 4.0 1 -- I I-. I.- ISAND, medium, tan, some silt, moist, loose.4.0 10.0 ..... SAND, medium, tan, some silt, wet, moderate hydrocarbon odor. Description of cuttings based on visual observations during vacuum extraction. _Borehole completed as Monitoring Well AV.1. & I .& I+ 9-4 4 9 J. I-I .4. 1 4. 1 4 + 1 1* I I 1 4. 1 4 + 1 1* I I *I* 1 4. 1-4 4. 1 I 9 + I App. C Soil Boring Logs Wells AU thru AZ, X.xls 2/15/2007 < ARCADIS Sample/Core Log Boring/Well Well AW Site Location Artificial Island, Hancock's Bridge, New Jersey Project/No. PSEG Nuclear, LLC Salem Generrating Station/NP000603.0001 P.Total Depth Drilled Length and Diameterof Coring Device Land-Surface Elev.Drilling Fluid Used Drilling Contractor Prepared By 10.0 Feet Hole Diameter 12 Drilling Drilling Started 11/8/2004 Completed Type of Sample/inches Coring Device N Sampling Interval 1Estimated Datum Plant Datum age 1 of 1 11/8/2004 A 3.5 -4.0 feet12 inch diameter vacuum extraction flex-pipe feet Water ESurveyed FI Drilling Method Vacuum Extraction Unitech Drilling and iodline ServicesDeric Kearns Driller Rich Helper Jim Hammer Hammer Weight NA Drop NA inchesSample/Core Depth (feet below land surface) Core Blow Recovery Counts From To (feet)PID Reading (ppm)Sample/Core Description 0.0 SAND. medium. tan. some silt. moist. loose. 4.0 4.0 10.0 ...... SAND, medium, tan, some silt, wet, moderate hydrocarbon odor.Description of cuttings based on visual observations during vacuum extraction. Borehole completed as Monitoring Well AW.App. C Soil Boring Logs Wells AU thru AZ, X.xis 2/15/2007 O ARCADIS Sample/Core Log Boring/Well Well AY Project/No. PSEG Nuclear, LLC Salem Generrating Station/NP000603.0001 Site Location Artificial Island, Hancock's Bridge, New Jersey Drilling Drilling Started 11/8/2004 Completed Type of Sample/inches Coring Device Page 1 of 1 11/8/2004 NA Val 3.5-4.0 / 9.0-9.5 feet Total Depth Drilled Length and Diameterof Coring Device Land-Surface Elev.Drilling Fluid Used Drilling Contractor Prepared By 9.0 Feet Hole Diameter 12 12 inch diameter vacuum extraction flex-pipe feet Water Sampling Inter OlEstimated Datum Plant Datum ElSurveyed Drilling Method Vacuum ExtractionUnitech Drilling and Jetline Services Driller Rich Helper Jim Hammer Hammer Weight NA Drop NA inches Deric Kearns Sample/Core Depth (feet below sand surface) Core Blow Recovery CountsFrom To (feet)PID Reading moom)Sample/Core Description SAND, medium, tan, some silt, moist, loose.0.0 4.04.0 9.0 ...... SAND, medium, tan, some silt, wet, no hydrocarbon odor.Description of cuttings based on visual observations during vacuum extraction. Borehole completed as Monitoring Well AY._ _ I _ _ ~~~~ ~ ~~~I_ _i_ _ I_ _ I_ _ _ _ __ _ _ _4 4 I 4 4 t I 1 I.4 I J 1 4 4 I 4 I 4 4 I I I I.4 4 4 1 4_I_ _ ___ _ ____________ __ I __ I __ I ____ I __ __________________ App. C Soil Boring Logs Wells AU thru AZ, X.xls 2/15/2007 O ARCADIS Sample/Core Log Boring/Well Well AZ Site Location Artificial Island, Hancock's Bridge, New Jersey Project/No. PSEG Nuclear, LLC Salem Generrating Station/NP000603.0001 Drilling DrillingStarted 11/8/2004 Completed Type of Sample/inches Coring Device Page 1 of 1 11/8/2004 NA rval 3.5 -4.0 feet Total Depth Drilled Length and Diameter of Coring Device Land-Surface Elev.Drilling Fluid Used Drilling Contractor Prepared By 10.0 Feet Hole Diameter 12 12 inch diameter vacuum extraction flex-pipe feet Water Sampling Inter E Estimated Datum Plant Datum ESurveyed Drilling Method V Vacuum Extraction Unitech Drillinq and Jetline Services Driller Rich Helper Jim Hammer Hammer Weight NA Drop NA inches Deric Kearns Sample/Core Depth (feet below land surface) Core RecoveryFrom To (feet)Blow Counts PID Reading (ppm)Sample/Core Description 0.0 SAND. medium, tan. some silt. moist, loose.4.0 4.0 10.0 ...... SAND, medium, tan, some silt, wet, no hydrocarbon odor.Description of cuttings based on visual observations during vacuum extraction. Borehole completed as Monitoring Well AZ.App. C Soil Boring Logs Wells AU thru AZ, X.xls 2/15/2007 r ARCADIS Sample/Core Log Boring/Well Well X Site Location Artificial Island, Hancock's Bridqe, New Jersey Project/No. PSEG Nuclear, LLC Salem Generrating Station/NP000571.0002 Page 1 of 1 Drilling Drilling Started 6/11/2003 Completed 6/11/2003 Type of Sample/inches Coring Device NA Total Depth Drilled Length and Diameter of Coring Device Land-Surface Elev.Drilling Fluid Used Drilling Contractor Prepared By 10.0 Feet Hole Diameter B NA 9.39g None feet EjSurveyed Sampling Interval NA feet UEstimated Datum Plant Datum Drilling Method Vacuum Excavation CT&E Environmental Services, Inc.Jon Rutledge Driller Jeff Helper NA Hammer Hammer Weight NA Drop NA inches Sample/Core Depth (feet below land surface) Core Blow Recovery Counts From To (feet)PID Reading (pom)Samole/Core Description 0.0 10.0 Borehole advanced to 10.0 feet below ground surface using vacuum excavation. A sample/core desription was unable to be observed due to the nature of the vacuum excavation process.10.0 End of boring. Boring completed as Monitoring Well X.______ _____ 1 ____________
- 1. _______ .1 _____________________________________________________
4-4. 4 4. 4 I~I* 4 4- 4.4-4. 4 4. 4 I-I. 4 4. 4.I .1.App. C Soil Boring Logs Wells AU thru AZ, X.xls 2/15/2007 0 ARCADIS Well Construction Log (Unconsolidated) I'll Outer Protective Steel Well Casing Well Identification Well X Project/No. PSEG Nuclear, LLC -Salem Generating Station/NP000603.0001 Site Location Salem Generating Station -Artificial Island Town/City Hancock's Bridge County Salem State New Jersey Permit No. 3400007018 Land-Surface Elevation 9.17 feet E1 J Surveyed Top-of-Casing Elevation 8.82 feet Estimated Datum NAVD 1988 Installation Date(s) June11, 2003 Drilling Method Vacuum Ecavation Drilling Contractor CT&E Environmental Services, Inc Drilling Fluid Not Applicable (NA)Development Technique(s) and Date(s): Peristaltic pump on June 11, 2003.Development was considered complete when turbidity in discharge was reduced/eliminated. Fluid Loss During Drilling: 0 -gallons Water Removed During Development: 5 gallons Static Depth to Water: 8.7 feet below M.P.-Pumping Depth to Water: ". NA feet below M.P.Pumping Duration:
0.2 hours
Yieldo NA gpm Date: NA Specific Capacity: NA gpm/ft Well Purpose Well installed to monitor groundwater quality.Remarks. Due to extensive underground utilities within the location of the monitoring well, vacuum excavation equipment was used to advance the well boring.Prepared by:Jon Rutledqe M.P. Measuring Point. Top of 2-inch PVC well casing unless otherwise noted.* Depth Below Land Surface 9 ARCADIS Well Construction Log (Unconsolidated) Two foot by two foot steelwell vault Land Surface Well Identification Well AU Project/No. PSEG Nuclear, LLC -Salem Generating Station/NPO006 Site Location Salem Generating Station -Artificial Island Town/City Hancock's Bridge LU ---ly Well Casing County Salem State New Jersey 6 inch diameter Schedule 40 PVC Permit No. 3400007375 Bottom %h. Bentonite Grout Land-Surface Elevation 5.44 feet F7X Surveyed 3 o Top-of-Casing Elevation 8,46 feet = Estimated Bottom of Bentonite 4 Datum NAVD 1988 Top of Well Screen Installation Date(s) November 9, 2004 12 inch diameter vacuum excavation hole Drilling Method Vacuum Excavation Drilling Contractor Uni -Tech Drilling Co., Inc.Drilling Fluid Not Applicable (NA)Development Technique(s) and Date(s): Surge block and subm on November 10, 2004. Development was considered complete when t discharge was reduced/eliminated. Fluid Loss During Drilling: 0 Water Removed During Development: -10 Static Depth to Water: 5.21Pumping Depth to Water: NA Pro-packed Well Screen 6 inch diameter, 0.02 Slot Pumping Duration: 0.2 PVC V-wire Yield, NA gpm Date: Specific Capacity: NA gpm/ft LEGEND Well Purpose Well installed to facilitate separate phase pr recovery.= Overburden = No. 0 Morie Sand Remarks Due to extensive underground utilities withi of the monitoring well, vacuum excavation equipment was used to adv 5% Bentonite Grout boring.'Bentonite SCALE Prepared by: Deric Kearns Not to Scale.f* End of Boring M.P. Measuring Point. Top of 2-inch PVC well casing unless otherwise noted.Depth Below Land Surface 03.0001 erisble pump urbidity in gallons gallons feet below M.P.feet below M.P.-hours 11/10//04 oduct n the location ance the well e ARCADIS Well Construction Log (Unconsolidated) Well Identification Well AV Flushmount Protective Manhole LocKaole txpanoang menl riUg Well Casing 4 inch diameter Schedule 40 PVC 5% Bentonite Groot -Bentonite 3 I____ ft*Top of Well Screen 12 inch diametervacuum excavation hole 4 inch diameter, 0.02 Slot PVC V-wire Project/No. PSEG Nuclear, LLC -Salem Generating Station/NP000603.0001 Site Location Salem Generating Station -Artificial Island Town/City Hancock's Bridge County Salem State New Jersey Permit No.Land-Surface Elevation -feet rx Surveyed Top-of-Casing Elevation feet iEstimated Datum NAVD 1988 Installation Date(s) November 8, 2004 Drilling Method Vacuum Excavation Drilling Contractor Uni-Tech Drilling Co., Inc.Drilling Fluid Not Applicable (NA)Development Technique(s) and Date(s): Surge block and submerisble pump on November 10, 2004. Development was considered complete when turbidity in discharge was reduced/eliminated. Fluid Loss During Drilling: 0 gallons Water Removed During Development: 15 -gallons Static Depth to Water: 5.36 feet below M.P.Pumping Depth to Water: 9.0 feet below M.P.-Pumping Duration: 0.25 hours Yield: NA gpm Date: November 10, 2004 Specific Capacity: NA gpm/ft Well Purpose Well installed to monitor groundwater quality.Remarks Due to extensive underground utilities within the location of the monitoring well, vacuum excavation equipment was used to advance the well boring.LEGEND O Uverburden = No. 0 Morie Sand 5% Bentonite Grout Bentonite SCALE Not to Scale.ft. End of Boring Prepared by: Deric Kearns M.P. Measuring Point. Top of 2-inch PVC well casing unless otherwise noted, Depth Below Land Surface ARCADIS Well Construction Log (Unconsolidated) Well Identification Well AW Lan A Flushmount Protective Manhole Project/No. PSEG Nuclear, LLC -Salem Generating Station/NP0006 Site Location Salem Generating Station -Artificial Island Town/City Hancock's BridgeL P.ll-lll9 1-1I r1u'J Well Casing County Salem State New Jersey 4 inch diameter Schedule 40 PVC Permit No.5% Bentonite Grout Land-Surface Elevation -feet Surveyed Bentonite Top-of-Casing Elevation feet = Estimated 3 Datum NAVD 1988 Installation Date(s) November 8, 2004 Drilling Method Vacuum Excavation 4 ft* Drilling Contractor Uni-Tech Drilling Co., Inc.Top of Well Screen Drilling Fluid Not Applicable (NA)Development Technique(s) and Date(s): Surge block and subm on November 10, 2004. Development was considered complete when tdischarge was reduced/eliminated. 12 inch diameter vacuum excavation hole Fluid Loss During Drilling: 0 Water Removed During Development: -22 Static Depth to Water: 5.42 -Product / 6.60 -WaterPumping Depth to Water: 9.0 4 inch diameter, 0.02 Slot Pumping Duration: 0.25 PVC V-wire Yield: NA gpm Date: Nover Specific Capacity: NA gpm/ft LEGEND Well Purpose Well installed to monitor groundwater gual= Overburden No. 0 Morie Sand Remarks Due to extensive underground utilities with of the monitoring well, vacuum excavation eguipment was used to adv i = 5% Bentonite Grout boring, (= Bentonite SCALE Prepared by: Deric Kearns Not to Scale.9 End of Bodng M.P. Measuring Point. Top of 2-inch PVC well casing unless otherwise noted.Depth Below Land Surface 03.0001 erisbie pump urbidity in gallons gallons feet below M.P feet below M.P.**hours mber 10, 2004 ity.n the location ance the well ARCADIS Well Construction Log (Unconsolidated)Flushmount Protective Manhole Land Surface Well Identification Well AY Project/No. PSEG Nuclear, LLC -Salem Generating Station/NP000603.0001 Site Location Salem Generating Station -Artificial Island Town/City Hancock's Bridge County Salem State New Jersey Permit No.Land-Surface Elevation feet F Surveyed Top-of-Casing Elevation _ feet Estimated Datum NAVD 1988 Installation Date(s) November 8, 2004 Drilling Method Vacuum Excavation Drilling Contractor Uni-Tech Drilling Co., Inc.Drilling Fluid Not Applicable (NA)Development Technique(s) and Date(s): Surge block and submerisble pump on November 10, 2004. Development was considered complete when turbidity in discharge was reduced/eliminated. Fluid LossDuring Drilling: 0 gallons Water Removed During Development: -15 gallons Static Depth to Water: 5.51 feet below M.P.-Pumping Depth to Water: 9.0 feet below M.P.-Pumping Duration: 0.25 hours Yield: NA gpm Date: November 10, 2004 Specific Capacity: NA gpm/ft Well Purpose Well installed to monitor groundwater quality.Remarks Due to extensive underground utilities within the location of the monitoring well, vacuum excavation equipment was used to advance the well boring.Prepared by: Deric Kearns 4 inch diameter, 0.02 Slot PVC V-wire M.P. Measuring Point. Top of 2-inch PVC well casing unless otherwise noted.Depth Below Land Surface 0 ARCADIS Well Construction Log (Unconsolidated) Flushrnount Protective Manhole and Surface Well Identification Well AZ Well Casing 4 inch diameter Schedule 40 PVC 5% Bentonite Grout Bentonite 3 4 ft*Top of Well Screen 12 inch diameter vacuum excavation hole 4 inch diameter, 0.02 Slot PVC V-wire Project/No. PSEG Nuclear, LLC -Salem Generating Station/NP000603.0001 Site Location Salem Generating Station -Artificial Island Town/City Hancock's Bridge County Salem State New Jersey Permit No.Land-Surface Elevation feet h Surveyed Top-of-Casing Elevation feet r-DEstimated Datum NAVD 1988 Installation Date(s) November 8, 2004 Drilling Method Vacuum Excavation Drilling Contractor Uni-Tech Drilling Co., Inc.Drilling Fluid Not Applicable (NA)Development Technique(s) and Date(s): Surge block and submerisble pump on November 10, 2004. Development was considered complete when turbidity in discharge was reduced/eliminated. Fluid Loss During Drilling: 0 gallons Water Removed During Development: -20 gallons Static Depth to Water: 5.21 feet below M.P.-Pumping Depth to Water: 9.0 feet below M.P.-Pumping Duration:
0.5 hours
Yield: NA gpm Date: November 10, 2004 Specific Capacity: NA gpm/ft Well Purpose Well installed to monitor groundwater quality.Remarks Due to extensive underground utilities within the location of the monitoring well, vacuum excavation equipment was used to advance the well boring.Prepared by: Deric Kearns LEGEND= Overburden E = No. 0 More Sand 5% Bentonite Grout= Bentonite SCALE Not to Scale.End of Boring M.P. Measuring Point. Top of 2-inch PVC well casing unless otherwise noted.Depth Below Land Surface ARCADWIS Appendix D Monitoring Well Form Bs MONITORING WELL CERTIFICATION FORM B LOCATION CERTIFICATION ', Name of Owner Name of Facility PSE&G Salem Generating Facility PSE&G Salem Generating Facility Location Lower Allowavs Creek. Salem County UST Number: SRP Case I" LAND SURVEYOR'S CERTIFICATION Well Permit Number: This number must be permanently affixed to the well casing.Owners Well Number (As shown on application or plans)Geographic Coordinates NAD 83 (to the nearest 1/10 of second)Longitude: West 750 32' 11.06" New Jersey State Plane Coordinates NAD 83 to nearest 10 feet: North 230,867.61 Elevation of Top of Inner Casing (Cap off)atReference mark (to nearest 0.01' in relation to permanenton-site datum) MW-AU Latitude: North 390 27' 45,45" East 199,525.52 Rim 99.36 PVC 98.38 Source of elevation datum (benchmark, number/description and elevation/datum. If an on-site datum is used, identify here, assume datum of 100', and give approximate actual elevation. Please note that, if information from the well is to be submitted electronically, the EDSA manual specifies the well elevation to be reported according to NAVD 1988 to an accuracy of 0.2'.)Site Monument N 5-0, E 2+0 Elevation 102.78 scaled actual elevation 10Significant observations and notes: AUTHENTICATION I certify under penalty of law that I have personally examined and am familiar with the information submitted in this document and all attachments and that, based on my inquiry of those individuals immediately responsible for obtaining the information, I believe the submitted information is true, accurate and complete. I am aware that there are significant penalties for submitting false, inaccurate, and incomplete information and that I am committing a crime in the fourth degree if I make a false statement that I do not believe to be true. I am also aware that if I knowingly direct or authorize the violation of any statute, I am personally liable for the penalties. PROFESSIONAL LAND SURVEYOR'S SIGNATURE 12/10/04 DATE RICHARD C. MATHEWS GS29353 PROFESSIONAL LAND SURVEYOR'S NAME AND LICENSE NUMBER 43 WEST HIGH STREET. SOMERVILLE. NEW JERSEY 908 725 0230 PROFESSIONAL LAND SURVEYOR'S ADDRESS AND PHONE NUMBER MONITORING WELL CERTIFICATION FORM B LOCATION CERTIFICATION Name of Owner Name of Facility PSE&G Salem Generating Facility PSE&G Salem Generatin2 Facility LocationLower Allowavs Creek. Salem CountyUST Number: SRP Case No.: LAND SURVEYOR'S CERTIFICATION Well Permit Number: This number must be permanently affixed to the well casing.Owners Well Number (As shown on application or plans)Geographic Coordinates NAD 83 (to the nearest I /10 of second)Longitude: West 750 32' 11.17" New Jersey State Plane Coordinates NAD 83 to nearest 10 feet: North 230,837.74 Elevation of Top of Inner Casing (Cap off) at Reference mark (to nearest 0,01' in relation to permanent on-site datum)MW-AW Latitude: North 390 27' 45.15" Eart 199.516.37 Rim 99.40 PVC 99.08 Source of elevation datum (benchmark, number/description and elevationldatum. If an on-site datum is used, identify here, assume datum of 100', and give approximate actual elevation. Please note that, if information from the well is to be submitted electronically, the EDSA manual specifies the well elevation to be reported according to NAVD 1988 to an accuracy of 0.2'.)Site Monument N 5+0. E 2+0 Elevation 102.78 scaled actual elevation 10 Significant observations and notes: AUTHENTICATION I certify under penalty of law that I have personally examined and am familiar with the information submitted in this document and all attachments and that, based on my inquiry of those individuals immediately responsible for obtaining the information, I believe the submitted information is true, accurate and complete. I am aware that there are significant penalties for submitting false, inaccurate, and incomplete information and that I am committing a crime in the fourth degree if I make a false statement that I do not believe to be true. I am also aware that if I knowingly direct or authorize the violation of any statute, I am personally liable for the penalties. PRA LAN E ' S PROFESSI ONAL LAND SURVEYOR'S SIGNATUrRE 12/10/04 DATE RICHARD C. MATHEWS GS29353 PROFESSIONAL LAND SURVEYOR'S NAME AND LICENSE NUMBER 43 WEST HIGH STREET, SOMERVILLE, NEW JERSEY 908 725 0230 PROFESSIONAL LAND SURVEYOR'S ADDRESS AND PHONE NUMBER MONITORING WELL CERTIFICATION FORM B LOCATION CERTIFICATION 0&Name of Owner Name of Facility PSE&G Salem Generatinp Facility PSE&G Salem Generating Facility Location I ,wopr At1c~u,~x,~ Cr~k ~t~m (7niintv Lower Allowa-s Creek Salem Countv UST Number: SRP Case LAND SURVEYOR'S CERTIFICATION Well Permit Number: This number must be permanently affixed to the well casing.Owners Well Number (As shown on application or plans)Geographic Coordinates NAD 83 (to the nearest 1/10 of second)No.:_MW-AV Longitude: West 750 32' 11.76" Latitude: North 390 27' 45.08" New Jersey State Plane Coordinates NAD 83 to nearest 10 feet: North 230,831.11 East 199,469.71 Elevation of Top of Inner Casing (Cap off) at Reference mark (to nearest 0.01' in relation to permanent on-site datum)Rim 99.09 PVC 98.74 Source of elevation datum (benchmark, number/description and elevation/datum. If an on-site datum is used, identify here, assume datum of 100', and give approximate actual elevation. Please note that, if information from the well is to besubmitted electronically, the EDSA manual specifies the well elevation to be reported according to NAVD 1988 to an accuracy of 0.2'.)Site Monument N 5+0, E 2+0 Elevation 102.78 scaled actual elevation 10Significant observations and notes: AUTHENTICATION I certify under penalty of law that I have personally examined and am familiar with the information submitted in this document and all attachments and that, based on my inquiry of those individuals immediately responsible for obtaining the information, I believe the submitted information is true, accurate and complete. I am aware that there are significant penalties for submitting false, inaccurate, and incomplete information and that I am committing a crime in the fourth degree if I make a false statement that I do not believe to be true. I am also aware that if I knowingly direct or authorize the violation of any statute, I am personally liable for the penalties. SEAL PROFESSIONAL LAND SURVEYOR'S SIGNATURE RICHARD C. MATHEWS GS29353 PROFESSIONAL LAND SURVEYOR'S NAME AND LICENSE NUMBER 43 WEST -IGH STREET, SOMERVILLE, NEW JERSEY. 908 725 0230 PROFESSIONAL LAND SURVEYOR'S ADDRESS AND PHONE NUMBER 12/10/04 DATE MONITORING WELL CERTIFICATION FORM B LOCATION CERTIFICATION Name of Owner Name of Facility PSE&G Salem Generating Facility PSE&G Salem Generating Facility I ~T All f, 11 4Z 1 t'- f UST Number: SRP Case No.: LAND SURVEYOR'S CERTIFICATION Well Permit Number: This number must be permanently affixed to the well casing.Owners Well Number (As shown on application or plans) MW-AY Geographic Coordinates NAD 83 (to the nearest 1/10 of second)Longitude: West 750 32' 11.10" Latitude: North 390 27' 44.84" New Jersey State Plane Coordinates NAD 83 to nearest 10 feet: North 230,805.92 East 199,5214A2 Elevation of Top of Inner Casing (Cap off) at Reference mark (to nearest 0.01' in relation to permanent on-site datum) Rim 99.32 PVC 98.96 Source of elevation datum (benchmark, number/description and elevation/datum. If an on-site datum is used, identify here, assume datmn of 100', and give approximate actual elevation. Please note that, if information from the well is to be submitted electronically, the EDSA manual specifies the well elevation to be reported according to NAVD 1988 to an accuracy of 0.2'.)Site Monument N 5+0, E 2+0 Elevation 102.78 scaled actual elevation 10Significant observations and notes: AUTHENTICATION I certify under penalty of law that I have personally examined and am familiar with the information submitted in this document and all attachments and that, based on my inquiry of those individuals immediately responsible for obtaining the information, I believe the submitted information is true, accurate and complete. I am aware that there are significant penalties for submitting false, inaccurate, and incomplete information and that I am committing a crime in the fourth degree if I make a false statement that I do not believe to be true. I am also aware that if I knowingly direct or authorize the violation of any statute, I am personally liable for the penalties. PROFESSIONAL LAND SURVEYOR'S SIGNATURE 12/10/04 DATE RICHARD C. MATHEWS GS29353 PROFESSIONAL LAND SURVEYOR'S NAME AND LICENSE NUMBER 43 WEST HIGH STREET, SOMERVILLE, NEW JERSEY 908 725 0230 PROFESSIONAL LAND SURVEYOR'S ADDRESS AND PHONE NUMBER MONITORING WELL CERTIFICATION FORM B LOCATION CERTIFICATION Name of Owner Name of Facility PSE&G Salem Generating Facility PSE&G Salem Generating, Facility.Location Lower Allowavs Creek. Salem Countv UST Number: SRP Case I LAND SURVEYOR'S CERTIFICATION Well Permit Number: This number must be permanently affixed to the well casing. Owners Well Number (As shown on application or plans)Geographic Coordinates NAD 83 (to the nearest 1/10 of second)Longitude: West 750 32' 10.72"New Jersey State Plane Coordinates NAD 83 to nearest 10 feet: North 230,764.41 Elevation of Top of Inner Casing (Cap off) at Reference mark (to nearest 0.01' in relation to permanent on-site datum)No.: MW-AZ Latitude: North 390 27' 44.43" East 199.551.16 _r_Rim 99.25 PVC 98.58 Source of elevation datum (benchmark, number/description and elevation/datum. If an on-site datum is used, identify here, assume datum of 100', and give approximate actual elevation. Please note that, if information from the well is to be submitted electronically, the EDSA manual specifies the well elevation to be reported according to NAVD 1988 to an accuracy of 0.2'.)Site Monument N 5+0, E 2+0 Elevation 102.78 scaled actual elevation 10Significant observations and notes: AUTHENTICATIONI certify under penalty of law that I have personally examined and am familiar with the information submitted in this document and all attachments and that, based on my inquiry of those individuals immediately responsible for obtaining the information, I believe the submitted information is true, accurate and complete. I am aware that there are significantpenalties for submitting false, inaccurate, and incomplete information and that I am committing a crime in the fourth degree if I make a false statement that I do not believe to be true. 1 am also aware that if I knowingly direct or authorize the violation of any statute, I am personally liable for the penalties. PROFESSIONAL LAND SURVEYOR'S SIGNATURE 12/10/04 DATE RICHARD C. MATH{EWS GS29353 PROFESSIONAL LAND SURVEYOR'S NAME AND LICENSE NUMBER 43 WEST HIGH STREET, SOMERVILLE._NEW JERSEY 908 725 0230 PROFESSIONAL LAND SURVEYOR'S ADDRESS AND PHONE NUMBER MONITORING WELL CERTIFICATION FORM B LOCATION CERTIFICATION Name of Owner PSE&G Salem Generating Facility Name of Facility PSE&G Salem Generating Facility Location Lower Alloways Creek, Salem County UST Number: SRP Case No.: LAND SURVEYOR'S CERTIFICATIONWell Permit Number: This number must be permanently affixed to the well casing.Owners Well Number (As shown on application or plans) MW-X Geographic Coordinates NAD 83 (to the nearest 1/10 of second)Longitude: West 750 32' 10.68" Latitude: North 390 27' 45.24" New Jersey State Plane Coordinates NAD 83 to nearest 10 feet: North 230,845.66 East 199,554.29 Elevation of Top of Inner Casing (Cap off) at Reference mark (to nearest 0.01' in relation to permanent on-site datum) Rim 99.09 PVC 98.74 Source of elevation datum (benchmark, number/description and elevation/datum. If an on-site datum is used, identify here, assume datum of 100', and give approximate actual elevation. Please note that, if information from the well is to be submitted electronically, the EDSA manual specifies the well elevation to be reported according to NAVD 1988 to an accuracy of 0.2'.)Site Monument N 5+0, E 2+0 Elevation 102.78 scaled actual elevation 10 Significant observations and notes: AUTHENTICATION I certify under penalty of law that I have personally examined and am familiar with the information submitted in this document and all' attachments and that, based on my inquiry of those individuals immediately responsible for obtaining the information, I believe the submitted information is true, accurate and complete. I am aware that there are significant penalties for submitting false, inaccurate, and incomplete information and that I am committing a crime in the fourth degree if I make a false statement that I do not believe to be true. I am also aware that if I knowingly direct or authorize the violation of any statute, I am personally liable for the penalties. / 12/10/04 PROFESSIONAL LAND SURVEYOR'S SIGNATURE DATE RICHARD C. MATHEWS GS29353 PROFESSIONAL LAND SURVEYOR'S NAME AND LICENSE NUMBER 43 WEST HIGH STREET. SOMERVILLE. NEW JERSEY 908 725 0230 PROFESSIONAL LAND SURVEYOR'S ADDRESS AND PHONE NUMBER Appendix E Groundwater Sampling Logs V ARCADIS Groundwater Sampling Form Project No. NP000603.0001.00004 Well ID Well XProject Name/Location PSEG Nuclear, LLC, Salem Generating Station, Hancock's Bridge, New Jersey. Measuring Pt. Screen Casing Description TOC Setting (ft-bgs) 7.47 to -2.53 Diameter (in.)Static Water Water Column/Level lft-bmp) 6.71 Total Depth ft-bmp) 13.03 Gallons in Well MP Elevation 12.00 Pump Intake (ft-bmp) 10 Purge Method: CentrifugalPump On/Off -- Volumes Purged -- Submersible Other Bladder Sample Time: Label 17:15 Replicate/ Start Code No. Well AX End Page 1 of 1 Date 12/13/2004 Weather Sunny Well Material X PVC SS Sample Method Low-flow Sampled by R. McKinney Time Minutes Rate Depth to Gallons pH Cond. Turbidity Dissolved Temp. Redox Appearance Elapsed (gpm) Water Purged Oxygen (mL/min) (ft) (mS/cm) (NTU) (mg/L) CC) (mV) Color Odor 16:45 5 150 6.91 -- 6.57 0.217 37.6 7.53 13.7 31.3 ....16:50 10 125 7.01 -- 6.49 0.217 15.6 6.63 14.32 34.4 ....16:55 15 125 7.08 -- 6.47 0.217 12.7 6.16 14.44 32.6 ....17:00 20 125 7.14 -- 6.45 0.218 11.0 5.74 14.34 28.7 ..17:05 25 100 7.16 -- 6.43 0.219 10.5 5.46 14.29 24.9 ..17:10 30 100 7.18 -- 6.42 0.219 12.8 5.29 14.19 22.6 ....Constituents Sampled Container Number Preservative VOCs by 8260 40 ml VOA 6 Hcl SVOCs by 8270 1 liter amber 4 --Well Casing Volumes Gallons/Foot 1" = 0.04 1.5" = 0.09 2.5" = 0.26 3.5" = 0.50 6" = 1.47 1.25" = 0.06 2" = 0.16 3" = 0.37 4" = 0.65 Well Information Well Location: Adjacent to Unit One Reactor Well Locked at Arrival: Yes Condition of Well: Good Well Locked at Departure: Yes Well Completion: Flush Mount Key Number To Well: American Lock ARCADIS Groundwater Sampling Form Project No: NP000603.0001.00004 PSEG Nuclear, LLC, S Well ID Well AV alem Generating Station, Hancock's Bridge, New Jersey.Project Name/Location Page 1 of 1 Date 12/13/2004 Weather Overcast Well Material X PVC SS Measuring Pt.Description Static Water Screen Setting (ft-bgs)TOC Casing 5.17 to -0.83 Diameter (in.) 4 Water Column/Level (ft-bmp) 4.49 Total Depth (ft-bmp) 9.66 Gallons in Well MP Elevation 9.17 Pump Intake (ft-bmp) 7 Purge Method: Sample Centrifugal Method Low-flowPump On/Off -- Volumes Purged -- Submersible Other Bladder Sample Time: Label 15:35 Replicate/ Start Code No. Sampled by R. McKinney End Time Minutes Rate Depth to Gallons pH Cond. Turbidity Dissolved Temp. Redox Appearance Elapsed (gpm) Water Purged Oxygen (mLmin) (ft) (mS/cm) (NTU) (mg/L) (C) (mV) Color Odor 15:08 8 75 4.51 -- 6.71 0.278 89.8 8.09 10.61 -26.5 ....15:13 13 75 4.51 -- 6.62 0,270 88.6 5.73 11.09 -26.8 ....15:18 18 75 4.51 -6.60 , 0.267 85.3 4.38 11.4 -27.2 ....15:23 23 75 4.51 -- 6.59 0.265 81.2 3.69 11.47 -27.8 ....15:28 28 75 4.51 -- 6.59 0.266 78.3 3.51 11.35 -28.7 ...15:33 33 75 4.51 -- 6.60 0.265 75.7 3.40 11.24 -29.0 ....4 4 + 4 + 4 + 4 +4 I- + I + I 4- I + I 4 4 4- 4 4- 4 4- 4 4. 4 4 4 4~ 4 4- 4 + 4 4- 4 4 4 4 4 4- 4 + 4 4- 4 Constituents Sampled Container Number Preservative VOCs by 8260 40 ml VOA 3 Hcl SVOCs by 8270 1 liter amber 2 'Well Casing Volumes Gallons/Foot 1" = 0.04 1.5" = 0.09 2.5" = 0.26 3.5" = 0.50 6" = 1.47 1.25" = 0.06 2= 0.16 3" = 0.37 4"'= 0.65 Well Information Well Location: Adjacent to Unit One Reactor Well Locked at Arrival: Yes Condition of Well: Good Well Locked at Departure: Yes Well Completion: Flush Mount Key Number To Well: American Lock .... ARCADIS Groundwater Sampling Form Project No. NP000603.0001.00004 Project Name/Location PSEG Nuclear, LLC, S Well ID Well AY alem Generatinq Station, Hancock's Bridqe, New Jersey.Page 1 of 1 Date 12/13/2004 Weather Sunny Measuring Pt. Screen Casing Well Material X PVC Description TOC Setting (ft-bgs) 5.40 to 1.40 Diameter (in.) 4 SS Static Water Water Column/Level (ft-bmp) 4.39 Total Depth (ft-bmp) 7.30 Gallons in Well MP Elevation 9.04 Pump Intake (ft-bmp) 6.50 Purge Method: Sample Centrifugal Method Low-flow Pump On/Off -- Volumes Purged -- Submersible Other Bladder Sample Time: Label 13:55 Replicate/ Start Code No. -- Sampled by R. McKinney End Time Minutes Rate Depth to Gallons pH Cond. Turbidity Dissolved Temp. Redox Elapsed (gpm) Water Purged Oxygen (mL/min) (ft) (mS/cm) (NTU) (mq/L) (1C) (mV) Color Odor 12:48 5 -- 4.39 -- 7.06 0.572 88.0 9.46 11.42 154.3 ..12:53 10 75 4.40 -- 7.07 1.067 87.5 8.37 11.49 154.8 ....12:58 15 50 4.40 -- 7.06 1.063 88.3 8.22 11.2 141.2 ....13:03 20 75 4.41 -- 7.06 1.052 89.0 8.15 10.82 119.4 .-..-13:08 25 75 4.41 7.06 1.034 88.1 8.17 10.54 81.7 ....13:13 30 75 4.41 -- 7.06 1.019 87.8 8.28 10.54 63.2 ...13:18 35 75 4.41 -- 7.04 0.995 84.8 8.50 10.61 48.7 ....13:23 40 75 4.42 -- 7.04 0.974 80.0 8.71 10.63 41.5 ....13:28 45 75 4.42 -7.04 0.953 72.5 8.94 10.72 58.0 ....13:33 50 75 4.42 -- 7.04 0.951 71.6 8.95 10.74 50.1 ....13:38 55 75 4.43 7.04 0.950 70.8 8.96 10.65 42.2 .. ..13:43 60 75 4.43 -7.04 0.949 66.9 8.97 10.63 32.6 ....13:48 65 75 4.43 -7.04 0.951 63.7 8.93 10.56 26.9 ..13:53 70 75 4.43 -- 7.05 0.952 61.5 8.92 10.74 23.6 -- -Constituents Sampled Container Number Preservative VOCs by 8260 40 ml VOA 6 Hcl SVOCs by 8270 1 liter amber 4 --Well Casing Volumes Gallons/Foot 1" = 0.04 1.5" = 0.09 2.5" = 0.26 3.5" = 0.50 6" = 1.47 1.25" = 0.06 2" = 0.16 3" = 0.37 4" = 0.65 Well Information Well Location: Adjacent to Unit One Reactor Well Locked at Arrival: Yes Condition of Well: Good Well Locked at Departure: Yes Well Completion: Flush Mount Key Number To Well: American Lock -1...D -5,207 02, ARCADIS Groundwater Sampling Form Project No. NP000603.0001.00004 PSEG Nuclear. LLC. S Well ID Well AZ alem Generatino Station. Hancock's Bridoe. New Jersey.Project Name/Location Measuring Pt.Description Page 1 of 1 Date 12/10/2004 Weather Light Rain Well Material X PVC SS TOC Screen Setting (ft-bgs)Casing 5.33 to 0.33 Diameter (in.) 4 Static Water Water Column/Level (ft-bmp) 4.09 Total Depth (ft-bmp) 9.07 Gallons in Well MP Elevation 8.66 Pump Intake (ft-bmp) 6.50 Purge Method: Sample Centrifugal Method Low-flowPump On/Off -- Volumes Purged -- Submersible Other Bladder Sample Time: Label _ Replicate/ Start Code No. -- Sampled by R. McKinney End Time Minutes Rate Depth to Gallons pH Cond. Turbidity Dissolved Temp. Redox Appearance Elapsed (gpm) Water Purged Oxygen (mL/min) (ft) (mS/cm) (NTU) (mg/L) (°C) (mV) Color Odor 13:55 5 250 4.20 -- 6.58 0.566 104.7 7.71 14.35 148.8 ..14:00 10 250 4.26 -- 6.61 0.453 93.0 7.31 14.42 129.0 ....14:05 15 150 4.26 -- 6.52 0.453 77.3 7.15 14.3 138.8 ....14:10 20 150 4.26 -- 6.55 0.454 75.0 7.13 14.24 136.0 ....14:15 25 150 4.26 -- 6.56 0.457 62.8 7.04 14.26 137.0 ....14:20 30 150 4.26 -- 6.56 0.458 59.5 6.96 14.25 142.1 -_ --14:25 35 150 4:26 -- 6.60 0.460 56.4 6.89 14.33 137.5 -...14:30 40 150 4.26 -- , 6.59 0.461 53.5 6.84 14.28 142.4 ....Constituents Sampled Container Number Preservative VOCs by 8260 40 ml VOA 3 Hcl SVOCs by 8270 1 liter amber 2 --Well Casing Volumes Gallons/Foot 1" = 0.04 1.5" = 0.09 2.5" = 0.26 3.5" = 0.50 6" = 1.47 1.25" = 0.06 2" = 0.16 3" = 0.37 4" = 0.65 Well Information Well Location: Adjacent to Unit One Reactor Well Locked at Arrival: Yes Condition of Well: Good Well Locked at Departure: Yes Well Completion: Flush Mount Key Number To Well: American Lock w1,1 0t1-w200 ARCADIS Groundwater Sampling Form Project No. NP000603.0001.00004Project Name/Location PSEG Nuclear, LLC, S Well ID Well X alem Generating Station, Hancock's Bridqe, New Jersey.Page 1 of 1 Date 3/15/2005 Weather Sunny 30s Well Material X PVC SS Measuring Pt.Description Static Water Screen Setting (ft-bgs)TOC Casing 7.47 to -2.53 Diameter (in.)Water Column/Level (ft-bmp) 8.02 Total Depth (ft-bmp) 13.03 Gallons in Well MP Elevation 12.00 Pump Intake (ft-bmp) 10.5 Purge Method: Sample Centrifugal Method Low-flow Pump On/Off -- Volumes Purged -- Submersible Other Bladder Sample Time: Label 13:12 Replicate/ Start Code No. Sampled by R. McKinney End Time Minutes Rate Depth to Gallons pH Cond. Turbidity Dissolved Temp. Redox.Elapsed (gpm) Water Purged Oxygen Ap- earan- e (mL/min) (ft) (mS/cm) (NTU) ,mg/L) (CC) (mV) Color Odor 12:09 5 200 8.25 -- 6.91 0.379 +999 15.38 10.23 163 It brown --12:14 10 200 8.46 6.68 0.379 690 14.07 10.02 120 It brown --12:19 15 200 8.56 -- 6.59 0.373 1 130 12.97 10.12 121 It brown --12:24 20 200 8.64 -- 6.56 0.374 71 12.2 10.18 108 clear --12:29 25 200 8.70 6.54 0.391 51 11.47 10.24 96 clear --12:34 30 200 8.75 6.53 0.428 50 11.00 10.28 83 clear --12:39 35 200 8.79 -- 6.52 0.477 36 10.45 10.3 56 clear --12:44 40 200 8.85 -- 6.51 0,496 32 10.29 10.32 37 clear --12:49 45 200 8.89 -- 6.51 0.494 34 9.80 10.28 26 clear --12:54 50 200 8.96 -- 6.52 0.496 41 9.55 10.27 16 clear --12:59 , 55 200 9.03 -- 6.52 0.497 56 9.48 10.38 10 clear --13:04 60 200 9.25 6.52 0.496 60 9.77 10.44
5.0 clear
--13:09 65 200 9.34 6.52 0.499 61 9.36 10.59 6.0 clear --Constituents Sampled Container Number Preservative VOCs by 8260 40 ml VOA 3 Hcl SVOCs by 8270 1 liter amber 2 --Well Casing Volumes Gallons/Foot 1" = 0.04 1.5" = 0.09 2.5" = 0.26 3.5" = 0.50 6" 1.47 1.25" = 0.06 2" = 0.16 3" = 0.37 4" = 0.65 Well Information Well Location: Adjacent to Unit One Reactor Well Locked at Arrival: Yes Condition of Well: Good Well Locked at Departure: Yes Well Completion: Flush Mount Key Number To Well: American Lock .. " ý-ARCADIS Groundwater Sampling Form Project No. NP000603.0001.00004 PSEG Nuclear, LLC, S Well ID Well AV alem Generating Station, Hancock's Bridge, New Jersey.Project Name/Location Page 1 of 1 Date 3/15/2005 Weather Sunny 30s Well Material X PVC SS Measuring Pt.Description Static Water Screen Casing TOC Setting (ft-bgs) 5.17 to -0.83 Diameter (in.) 4 Water Column/Level (ft-bmp) 4.88 Total Depth (ft-bmp) 9.66 Gallons in Well MP Elevation 9.17 Pump Intake (ft-bmp) 7.5 Purge Method: Sample Centrifugal Method Low-flowPump On/Off -- Volumes Purged -Submersible Other Bladder Sample Time: Label 14:25 Replicate/ Start ____ Code No. Well AVD Sampled by R. McKinney End Time Minutes Rate Depth to Gallons pH Cond. Turbidity Dissolved Temp. Redox Appearance Elapsed (gpm) Water Purged Oxygen (mL/min) (ft) (mS/cm) (NTU) 1mg/LI (IC) (mV) Color Odor 13:53 5 250 4,93 -- 6.33 0.365 41 4.27 7.74 -50 ...13:58 10 250 4,93 -- 6.3 0.364 19 9,18 7.72 -57 ..14:03 15 250 4,95 -- 6.31 0.357 120 4.13 7.76 -62 ..14:08 20 250 4.95 -- 6.31 0.364 400 3.88 7.74 -66 .. ..14:13 25 250 4.95 -- 6.31 0.369 4.8 3.84 7.78 -70 ....14:18 30 250 4.96 -- 6.32 0.369 3.7 4.20 7.74 -72 ....14:23 35 250 4.96 -- 6.32 0.367 3.1 4.22 7.79 -76 ..Constituents Sampled Container Number Preservative VOCs by 8260 40 ml VOA 3 Hcl SVOCs by 8270 1 liter amber 2 --Well Casing Volumes Gallons/Foot 1" = 0.04 1.5" = 0.09 2.5" = 0.26 3.5" = 0.50 6" = 1.47 1.25" = 0.06 2" = 0.16 3" = 0.37 4" = 0.65 Well Information Well Location: Adjacent to Unit One Reactor Well Locked at Arrival: Yes Condition of Well: Good Well Locked at Departure: Yes Well Completion: Flush Mount Key Number To Well: American Lock w,11 V ARCADIS Groundwater Sampling Form Project No. NP000603.0001.00004 Project Name/Location PSEG Nuclear, LLC, S Well ID Well AY alem Generatinq Station, Hancock's Bridge, New Jersey.Page 1 of Date 3/15/2005 Weather Sunny 30s Well Material X PVC SS Measuring Pt. Screen Description TOC Setting (ft-bgs)Static Water Casing 5.40 to 1.40 Diameter (in.) 4 Water Column/Level (ft-bmp) 4.39 Total Depth (ft-bmp) 7.30 Gallons in Well MP Elevation 9.04 Pump Intake (ft-bmp) 6.50 Purge Method: Sample Centrifugal Method Low-flowPump On/Off -- Volumes Purged -- Submersible Other Bladder Sample Time: Label 11:00 Replicate/ Start Code No. Sampled by R. McKinney End Time Minutes Rate Depth to Gallons pH Cond. Turbidity Dissolved Temp. Redox Appearance Elapsed (gpm) Water Purged Oxygen (mL/min) (ft) (mS/cm) (NTU) (mq/L) (°C) (mV) Color Odor 9:50 5 250 4.9 -- 6.60 5.41 640.0 18.21 6.33 172 It brown --9:55 10 250 4.94 -- 6.87 5.35 650 17.43 6.27 171 It brown --10:00 15 250 4.96 -- 7.00 5.24 520 17.31 6.25 172 It brown --10:05 20 250 4.98 -- 7.07 5.16 420.0 17.17 6.26 173 It brown --10:10 25 250 4.99 -- 7.13 5.1 330 16.97 6.24 173 It brown --10:15 30 250 5.01 -- 7.19 5.02 250 16.42 6.32 173 It brown --10:20 35 250 5.02 -- 7.22 4.98 200 16.32 6.32 173 It brown --10:25 40 250 5.03 -- 7.25 4.95 130.0 15.09 6.33 172 It brown --10:30 45 250 5.04 -- 7.28 4.91 90 15.95 6.33 171.0 It brown --10:35 50 250 5.06 -- 7.3 4.88 51 15.8 6.36 170 clear --10:40 55 250 5.07 -- 7.31 4.860 26 15.69 6.37 169 clear --10:45 60 250 5.08 -- 7.32 4.84 10 15.64 6.42 167 clear --10:50 65 250 5.09 -- 7.34 4.82 3 15.29 6.47 167 clear --10:55 70 250 5.10 -- 7.34 4.80 1.5 15.76 6.48 166 clear Constituents Sampled Container Number .Preservative VOCs by 8260 40 ml VOA 3 Hcl SVOCs by 8270 1 liter amber 2 --Well Casing Volumes Gallons/Foot 1" = 0.04 1.5" = 0.09 2.5" = 0.26 3.5" = 0.50 6" = 1.47 1.25" = 0.06 2" = 0.16 3" = 0.37 4" = 0.65 Well Information Well Location: Adjacent to Unit One Reactor Well Locked at Arrival: Yes Condition of Well: Good Well Locked at Departure: Yes Well Completion: Flush Mount Key Number To Well: American Lock .w,,,AY ARCADIS Groundwater Sampling Form Project No. NP000603.0001.00004 Well ID Well AZ Project Name/Location PSEG Nuclear, LLC, Salem Generating Station, Hancock's Bridge, New Jersey.Measuring Pt. Screen Casing Description TOC Setting (ft-bgs) 5.33 to 0.33 Diameter (in.) 4 Static Water Water Column/Level (ft-bmp) 4.18 Total Depth (ft-bmrp) 9.07 Gallons in Well MP Elevation 8.66 Pump Intake (ft-bmp) 6.50 Purge Method: CentrifugalPump On/Off -- Volumes Purged -- Submersible Other Bladder Sample Time: Label 9:05 Replicate/ Start Code No.End Page 1 of 1 Date 3/15/2005 Weather Sunny 30s Well Material X PVC SS Sample Method Low-flow Sampled by R. McKinney Time Minutes Rate Depth to Gallons pH Cond. Turbidity Dissolved Temp. Redox Appearance Elapsed (gpm) Water Purged Oxygen (mL/min) (ft) (mS/cm) (NTU) (mg/L) (1C) (mV) Color Odor 8:25 5 225 4.28 -- 5.66 1.12 5.0 15.84 1 7.84 247 ..8:30 10 225 Recalibrated water quality meter due to high DO readin s --8:35 15 225 4.38 -- 5.34 1.15 1.5 17.16 7.76 256 --8:40 20 225 4.42 -- 5.8 1.13 1.5 16.46 8 244 ..8:45 25 225 4.41 -- 5.86 1.11 2.0 17.54 7.65 238 ....8:50 30 '225 4.46 5.89 1.11 1.5 17.08 7.93 236 ...8:55 35 225 4.49 5.91 1.12 1.5 16.72 7.96 237 ...9:00 40 225 4.5 -5.93 1.12 1.5 16.79 8.01 237 --Constituents Sampled Container Number Preservative VOCs by 8260 40 ml VOA 3 Hcl SVOCs by 8270 1 liter amber 2 --Well Casing Volumes Gallons/Foot 1" = 0.04 1.5" = 0.09 2.5" 0.26 3.5" = 0.50 6" = 1.47 1.25" = 0.06 2" = 0.16 3" = 0.37 4" = 0.65 Well Information Well Location: Adjacent to Unit One Reactor Well Locked at Arrival: Yes Condition of Well: Good Well Locked at Departure: Yes Well Completion: Flush Mount Key Number To Well: American Lock . ARCADIS Appendix F Groundwater Analytical Results December 2004 & March 2005 New Jersey 2ADCUTEST. Laboratories 01/07/05~4m-T cnical Repor. t Ofor.Arcadis Geraghty & Miller PSEG-Salem, Artificial Island, Salem, NJ NP000571 Accutest Job Number: N85893 Sampling Date: 12/10/04 Report to: Arcadis Geraghty & Miller 6 Terry Drive Newtown, PA 18940 ATTN: Brad Pierce Total number of pages in report: 98 to~o 4,01 Test results contained within this data package meet the requirements of the National Environmental Laboratory Accreditation Conference and/or state specific certification programs as applicable. cident J iese President Certifications: NJ(12129), NY(10983), CA, CT. DE, FL, IL, IN. KS. KY, LA, MA, MD, MI, MT, NC, PA, RI, SC, TN, VA, WV This report shall not be reproduced, except in its entirety, without the written approval of Accutest Laboratories. New Jersey s 2235 Route 130 a Dayton, NJ 08810 *tel: 732-329-0200 0 fax: 732-329-3499 a http://www.accutest.com Accutest Laboratories
- AV Sample Summary Arcadis Geraghty & Miller PSEG-Salem., Artificial Island, Salem, NJ Project No: NP000571 Sample Collecied "v Number Date Time By Received C N85893-1 12/10/04 00:00 RPM 12/13/04 AN85893-2 .12/10/04 00:00 RPM 12/13/04 A N85893-3 12/10/04 00:00 RPM 12/13/04 A Job No: N85893 latrix ode Type.Q Ground WaterField Blank Water kQ Trip Blank Water Client Sample ID WELL AZ FB- .7TRIP , 2 UACCUTEST.
Table Of Contents Reduced Laboratory Data Deliverables
- 'For Non-USEPAICLP Methods Title/Cover Pare Table Of Contents Section 1 General A. Results Summary B. Chain of C.stody C. Sample Tracking Chronicle/Method References Section 2 GCIMS Support Data (grouped by fraction)A:
Summary B. Method Blank Summar.y'C. Blank Spike Summary D. MatriK Spike/Matrix Spike Duplicate Summary E. Tufie Results Summary F. lnternal. Standard Summary G. Surrogate Rtt.gery Results Summary H. Calibration Summary (sorted by Instrument) I. Initial Calibration Check Summary Continuing Calibration Check Summary J. Sample and Blank Chromatogramsi Quant Reports, Mass Spectra, and Library Search Data Seetlon 3 GC Support Data'A. Conformance/Non-conformance Summary B. Method Blank Summary C. Blank Spike Summary D. Matrix Spike/Matrix Spike Duplicate Surmnary E. Surrogate Recovery Results Summary F. Calibration Summary (sorted by Instrument) Initial Calibration Check Summary Continuing Calibration Check Summary G. Retention Time Shift Summary H. Sample, Blank and Multi-peak Standaid Chromatograms and Quant Reports Section 4 Metals Support Data (sorted by Instrument Type-ICP, Furnace, Flame, and'Mercury) A. Conforri6hne/Nbhn-conformance Sumrnary*B. Initial .ahd Contin~uing Calibration Blank-.C. Initial and Continuing Calibration Checks D. Hina and Low Check Standards E. InteHfering Element Check Standards F. Method Blank SuChicary G.. Matrix Spike and Duplicates Summary H. Miatrk Spike and ulb Control Sample Summary I. Serial.Dilution Sumarnay Section 5 General Chbmistrv/]Petroleum Hydrocarbon Support Data A. Conformance/Non-Conformance Summary B. Batch Quality Control Summary Method Blank and Spike Blank Results Summary Duplicate Results Summary Matrix Spike Results Summr C. Raw Data and IR Spectra (Petroleum Hydrocarbons) D. -Raw Data and Run Record (Hexavalent Chromium)New Jersey
- Fresh Ponds.Corporate Village I Building B " 2235 Route 130 Dayton, NJ D8810 Teli 732.329.0200 Fax: 732.329.3499 http:J/www.accvtestcom RedTie2 r2/r9B2004 "V RESULTS 4 Accutest Laboratories Report of Analysis Page 1 of 2 Client Sample ID: WELL AZ Lab Sample ID: N85893-1 Date Sampled: 12/10/04 Matrix: AQ -Ground Water Date Received:
12/13/04 Method: SW846 8260B Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2C1396.D 1 12/19104 KNV n/a n/a V2C63 Run #2 Purge Volume Run #1 5.0 ml Run #2 VOA TCL List CAS No. ' Compound Result RL MDL Units Q 67-64-1 71-43-2 75-27-4 75-25-2 74-83-9 78-93-3 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3 124-48-1 75-34-3 107-06-2 75-35-4 156-59-2 156-60-5 78-87-5 10061-01-5 10061-02-6 100-41-4 591-78-6 108-10-1 75-09-2 100-42-5 79-34-5 127-18-4 108-88-3 71-55-6 79-00-5 79-01-6 Acetone Benzene Bromodichioromethane Bromoform Bromomethane2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chl orobenzene Chloroethane Chloroform Chloromethane DibromochIorometbane 1,1-Dichloroethane 1,2-Dichloroethane1, 1 -Dichloroethene cis- 1,2-Dichloroethene trans- 1,2-Dichloroethene i ,2-Dichloropropane cis- 1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone 4-Methyl-2-pentanone(M IBK)Methylene chloride Styrene 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1, ] -Trichloroethane 1,1,2-Trichloroethane Trichloroethene ND ND ND-ND', ND N.D: " ND ND ND)ND ND ND ND ND.ND:ND.ND ND ND: 'ND.ND ND ND ND ND ND ND ND ND ND ND ND 10 1.0 1.0 4.0 2,0* 10 2.0 1.0.1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0.1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 2.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 2,3 0.31 0.11 0.17 0,15 2.5 0.23 0,15 0.23 0.73 0.081 0.13 0.18 0.13 0.35 0.81 0.24 0.17 0.11 0.071 0.080 0.27 0.73 0.59 0.20 0.12 0.14 0.37 0.14 0.25 0.17 0.13 ug/lI ug/l ug/1 ug/.ug/, ug/l ug/t ug/l ug/I ug/l ug/I ug/l ug/l ug/1 ug/h ug/l ug/l ug/1 ug/I ug/lI ug/l ug!1 ug/l ug/l ug/lI ug/l ug/1 ug/l ug/1 ug/1 ug/l ug/l V ND = Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value 5 B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 2 of 2 Client Sample ID: WELL AZ Lab Sample ID: N85893-1 Date Sampled: 12/10/04 Matrix: AQ -Ground Water Date Received: 12/13/04 Method: SW846 8260B Percent Solids: n/a Project: PSEG-Salem, Artificial island, Salem, NJ VOA TCL List CAS No. Compound 75-01-4 Vinyl chloride1330-20-7 Xylene (total) Result RL MDL Units Q.ND 1.0:ND 1.0 0.66 ug/1 0.17 ug/l CAS No. Surrogate Recoveries Run# I Run# 2 Limits 1868-53-7 17060-07-0 2037-26-5 460-00-4 Dibromofluoromethane 1,2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene
- 1.03%.96%.'88%J 06%" :c 79-119%68-129%83-118%82-120%4w ND = Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page I of 3 Client Sample ID: WELL AZLab Sample ID: N85893-1 Date Sampled: 12/10/04 Matrix: AQ -Ground Water Date Received:
12/13/04 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run#1 F47282.D 1 12/31/04 NAP 12/14/04 OP19011 EF2503 Run #2 Initial Volume Final Volume Run #.I 1000 ml 1.0 ml Run #2 ABN TCL List CAS No. Compound Result RL MDL Units Q'V 95-57-8 59-50-7 120-83-2 105-67-9 51-28-5 534-52-1 95-48-7 88-75-5 100-02-7 87-86-5 108-95-2 95-95-4 88-06-2 83-32-9 208-96-8 120-12-7 56-55-3 50-32-8 205-99-2 191-24-2 207-08-9 101-55-3, 85-68-7 91-58-7 106-47-8 86-74-8 218-01-9 111-91-1 111-44-4 108-60-1 7005-72-3 2-Chlorophenol 4-Chloro-3-methyl phenol 2,4-Dichlorophenol 2,4-Dimethylphenol
2,4-Dinitrophenol 4,6-Dinitro-o-cresol 2-Methylphenol 3&4-Methylphenol 2-.Niirophenol 4-Nitrophenol Pentachlorophenol Phenol 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene 4-Bromophenyl phenyl ether Butyl benzyl phthalate 2-Chloronaphthalene 4-Chloroaniline Carbazole Chrysene bis(2-Chloroethoxy)methane bis(2-Chloroethyl)ether bis(2-Chloroisopropyl)ether 4-Chlorophenyl phenyl ether ND.ND.ND ., ND.ND-ND.ND.: ND, ND..ND ND ND ND ND ND ND ND.ND...ND::.ND ND: ND..ND..ND.ND ND ND ND ND ND ND ND..5.0 5.0 5.0 5.0 20.20 5.0 5.0 5.0 20 20 5.0 5,0 5.0 2.0 2.0 2.0... .0 2.0 2.0 2.0 2.0 2.0 2.0 5.0 5.0 2.0 2.0 2.0 2.0 2.0 2.0 4.3 4.7 0.73 1.0 1.1 0.65 0.72 0,70 0.73 2.3 0.75 1.8 0.74 0.80 0.30 0.35 0.22 0.27 0.38 0.37 0.50 0.37 0.54 0.54 0.38 0.43 0.34 0.26 0.34 0.49 0.44 1.0 ug/l ug/l ug/]ug/l ug/h ugh ug/]ug/l ug/1 ug/l ug/h ug/I ug/l ug/I ug/l ug/1 ug/1 ug/I ug/]ug/l ug/I ug/l ug/h ug/1 ug/l ug/l ug/1 ug/l ug/l ug/l ugl1 ug/l ND = Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range= Indicates an estimated vJue 7 B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 2 of 3%w Client Sample ID: WELL AZ Lab Sample ID: N85893-1 Date Sampled: 12/10/04 Matrix: AQ -Ground Water Date Received: 12/13/04 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ ABN TCL List CAS No. Compound Result RL MDL Units Q 95-50-1 1,2-Dichlorobenzene 541-73-1 1,3-Dichlorobenzene 106-46-7 1,4-Dichlorobenzene 121-14-2 2,4-Dinitrotoluene 606-20-2 2,6-Dinitrotoluene 91-94-1 3,3'-Dichlorobenzidine 53-70-3 Dibenzo(a,h)anthracene 132-64-9 Dibenzofuran 84-74-2 Di-n-butyl phthalate]17-84-0 Di-n-octyl pbthalate 84-66-2 Diethy] phthalate 131-11-3 Dimethyl phthalate 117-81-7 bis(2-Ethylhexyl)phthalate 206-44-0 Fluoranthene 86-73-7 Fluorene 118-74-1 Hexachlorobenzene 87-68-3 Ilexachlorobutadiene 77-47-4 Hexachlorocyclopentadiene 67-72-1 Hexachloroethane 193-39-5 lndeno(1,2,3-cd)pyrene 78-59-1 Isophorone 91-57-6 2-Methylnaphthalene 88-74-4 2-Nitroaniline 99-09-2 3-Nitroaniline 100-01-6 4-Nitroaniline 91-20-3 Naphthalene 98-95-3 Nihrobenzene 621-64-7 N-Nitroso-di-n-propylamine 86-30-6 N-Nitrosodiphenylamine 85-01-8 Phenanthrene 129-00-0 Pyrene 120-82-1 1,2,4-Trichlorobenzene CAS No. Surrogate Recoveries NDO.- 2.0 ND " 2.0.ND 2.0 ND 2.0.ND 2.0 ,ND 5.0 ND 2.0 ND 5.0 ND 2.0 ND 2.0 ND 2.0 ND. "" 2.0 ND 2.:.0 ND .2.0 ND 2.0-ND,: 2.0 ND : 2,0]ND 20 ND' 5.0 ND 2.0 NDI 2.0 ND 2.0 ND 5.0 ND 5.0 ND".:.. : 5.0 ND 2.0 ND. 2.0 ND .2.0 ND 5.0 ND 2.0 ND 2.0 ND 2.0 0.24 0.32 0.25 0.78 0.62 0.39 0.58 0.49 0.79 0.63 1.4 0.58 0.74 0.63 0.89 1.2 0.41 0.45 0.67 1.5 0.54 0.72 1.4 1.2 1.1 1.0 0.61 0.50 0.80 0.23 0.58 0.32 ugll ug/l ug/l ug/l ug/1 ug/]ug/l ug/1 ug/l ug/l ug/1 ug/l ug/1 ug/l ug/l ug/l ug/l ughl ug/]ug/1 ug/h ug/]ug/l ug/)ug/h ug/1 ug/1 ug/1 ugh]ug/1 ug/I ug/1 Run# I Run# 2 Limits 367-12-4 4165-62-2 118-79-6 4165-60-0 321-60-8 2-Fluorophenol Phenol-d5 2,4,6-Tribromophenol Nitrobenzene-d5 2-Fluorobiphenyl 40%2.8%86%70%66%10-88%10-71%45-134%32-128%34-123%ND Not detected MDL -Method Detection Limit RL Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value 8 B Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 3 of 3$4w Client Sample ID: WELL AZ Lab Sample ID: N85893-1 Date Sampled: 12/10/04 Matrix: AQ- Ground Water Date Received: 12113/04 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ ABN TCL List CAS No. Surrogate Recoveries 1718-51-0 Terphenyl-d14 Run# 1 Run# 2 Limits'8% 41 -129%"V"V ND = Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value 9 B = Indicates analyte found in associated method blank N Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page I of 2%W Client Sample ID: FBAt Lab Sample ID: N85893-2 Date Sampled: 12/10/04 Matrix: AQ -Field Blank Water Date Received: 12113/04 Method: SW846 8260B Percent Solids: nia Project: PSEG-Salem, Artificial Island, Salem, NJ File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2C1397.D 1 12/19/04 KNV n/a n/a V2C63[Run #2 I Purge Volume Run #1 5.0 rml Run #2 VOA TCL List CAS No. Compound Result RL MDL Units Q 67-64-1 71-43-2 75-27-4 75-25-2 74-83-9 78-93-3 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3 124-48-1 75-34-3 107-06-2 75-35-4 156-59-2 156-60-5 78-87-5 10061-01-5 10061-02-6 100-41-4 591-78-6 108-10-1 75-09-2 100-42-5 79-34-5 127-18-4 108-88-3 71-55-6 79-00-5 79-01-6 Acetone Benzene Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK)Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Dibromochloromethane 1,1 -Dichloroethane 1,2-Dichloroethane1, 1 -Dichloroethene cis- 1,2-Dichloroethene trans-I1,2-Dichloroethene 1,2-Dichloropropane cis- 1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-ttexanone 4-M ethyl-2-pentanone(M IBK)Methylene chloride Styrene 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichioroethane Trichloroethene ND: ND~ND ND ND'.ND.ND-ND ND'ND ND.ND ND,: ND ND ND ND, ND ND:" ND.ND ND ND:: ND ND.ND.ND+.:ND.?ND.ND ND 10 1.0 1.0 4.0 2,0 10 2.0 1.0 1.0 1.0 1.0 1.0 1.0* 1.0: 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 2.0 1.0 1.0 1.0 1.0 1.0 1.0 2.3 0.31 0.11 0.17 0.15 2.5 0.23 0.15 0.23 0.73 0.081 0.13 0.18 0.13 0.35 0.81 0.24 0.17 0.11 0,071 0.080 0.27 0.73 0.59 0.20 0.12 0.14 0.37 0.14 0.25 0.17 0.13 ug/l ug/l ug/I ug/l ug/1 ug/l ug/l ughl ug/l ug/h ug/l uglI ug/l ug/l ug/l ug/h ug/I ug/l ug/]ug/1 ug/1 ug/1 ug/I ug/1 ug/]ug/l ug/]ug/1 ug/h ug/l ug/I ug/l ND Not detected MDL -Method Detection Limit RL -Reporting Limit E = Indicates value exceeds calibration range J= Indicates an estimated vala.. 3.0 B Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 2 of 2 4, Client Sample ID: FB- I Lab Sample ID: N85893-2 Date Sampled: 12/10/04 Matrix: AQ -Field Blank Water Date Received: 12/13/04 Method: SW846 8260B Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ VOA TCL List CAS No. Compound 75-01-4 Vinyl chloride 1330-20-7 Xylene (total)Result RL MDL Units Q ND.: 1.0-N.D' 10 0.66 ug/I 0.17 ug/1 CAS No. Surrogate Recoveries Run# I Run# 2 Limits 1868-53-7 17060-07-0 2037-26-5 460-00-4 Dibromofluoromethane 1,2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene 102%97%89%105%79-119%68-129%83-118%82-120%ND Not detected MDL -Method Detection Limit RL Reporting Limit E = Indicates value exceeds calibration range I = Indicates an estimated vaie B Indicates analyte found illi'sociated method blank N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis PageI of 3 Client Sample ID: FB-I Lab Sample ID: N85893-2 Date Sampled: 32/10/04 Matrix: AQ -Field Blank Water Date Received: 12/13/04 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG-Salem, Arificial Island, Salem, NJ File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 F47283.D 1 12/31/04 NAP 12/14/04 OP19011 EF2503 Run #2 Initial Volume Final Volume Run #1 1000 ml 1.0 ml Run #2 ABN TCL List CAS No. Compound Result RL MDL Units Q 95-57-8 2-Chlorophenol ND .: 5.0 4.3 ug/l 59-50-7 4-Chloro-3-methyl phenol ND 5.0 4.7 ug/h 120-83-2 2,4-Dichlorophenol ND 5.0 0.73 ug/h 105-67-9 2,4-Dimethylphenol ND 5.0 1.0 ugB/51-28-5 2,4-Dinitrophenol ND 20 1,. ug/l 534-52-1 4,6-Dinitro-o-cresol ND 20 0.65 ug/l95-48-7 2-Methylphenol ND 5.0 0.72 ug/1 3&4-Methylphenol ND 5.0 0.70 ug/l 88-75-5 2-Nitrophenol ND 5.0 0.73 ug/1 100-02-7 4-Nitrophenol ND 20 2.3 ug/l 87-86-5 Pentachlorophenol ND 20 0.75 ug/I 108-95-2 Phenol 1ND1) 5.0 1.8 ug/l 95-95-4 2,4,5-Trichlorophenol ýND 5.0 0.74 ug/1 88-06-2 2,4,6-Trichlorophenol
- ND. 5.0 0.80 ug/1 83-32-9 Acenaphthene ND -2.0 0.30 ug/l208-96-8 Acenaphthylene -2.0 0.35 ug/]120-12-7 Anthracene ND 2.0 0.22 ug/!56-55-3 Benzo(a)anthracene ND 2.0 0.27 ug/h 50-32-8 Berizo(a)pyrene ND 2.0 0.38 ug/h205-99-2 Benzo(b)fluoranthene ND 2,0 0.37 ug/I 191-24-2 Benzo(g,h,i)perylene ND 2.0 0.50 ug/h 207-08-9 Benzo(k)fluoranthene ND 2.0 0.37 ug/!101-55-3 4-Bromophenyl phenyl ether ND 2.0 0.54 ug/]85-68-7 Butyl benzyl phthalate ND 2.0 0.54 ug/l 91-58-7 2-Chloronaphthalene ND 5.0 0.38 ug/!106-47-8 4-Chloroaniline ND 5.0 0.43 ug/l 86-74-8 Carbazole ND 2.0 0.34 ug*218-01-9 Chrysene ND 2.0 0.26 ug/.111-91-1 bis(2-Chloroethoxy)methane ND 2.0 0.34 ug1]111-44-4 bis(2-Chloroethyl)eiher ND 2.0 0.49 ug/]108-60-1 bis(2-Chloroisopropyl)ether ND 2.0 0.44 ug/l 7005-72-3 4-Chlorophenyl phenyl ether ND 2.0 1.0 ug/l ND Not detected MDL -Method Detection Limit J = Indicates an estimated vala, RL = Reporting Limit B lndicaies analyie found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 2 of 3 Client Sample ID: FB-1 Lab Sample ID: N85893-2 Date Sampled: 12/10/04 Matrix: AQ -Field Blank Water Date Received:
12/13/04 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ ABN TCL List CAS No. Compound Result RL MDL Units Q f4w 95-50-1 541-73-1 106-46-7 121-14-2 606-20-2 91-94-1 53-70-3 132-64-9 84-74-2 117-84-0 84-66-2 131-11-3 117-81-7 206-44-0 86-73-7 118-74-1 87-68-3 77-47-4 67-72-1 193-39-5 78-59-1 91-57-6 88-74-4 99-09-2 100-01-6 91-20-3 98-95-3 621-64-7 86-30-6 85-01-8 129-00-0 120-82-1 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 2,4-Dinitrotoluene 2,6-Dinitrotoluene 3,3'-Dichlorobenzidine Dibenzo(a,h)anthracene Dibenzofuran Di-n-butyl phthalate Di-n-octyl phthalate Diethyl phthalate Dimethyl phthalate bis(2-Ethylhexyl)phthalate Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene H exachlorocyclopentadiene Bexachloroethane lndeno(1,2,3-cd)pyrene Isophorone 2-Methylnaphthalene 2-Nitroaniline 3-Nitroaniline 4-Nitroaniline Naphthalene N itrobenzene N-Nitroso-di-n-propyl amine N-Niirosodiphenylamine Phenanthrene Pyrene 1,2,4-Trichlorobenzene ND. 2.0 ND: 2.0 ND 2.0:ND ::'. ".: 2.0 ND 2.0 ND .5.0 ND:I -- 2.0 ND ' 5.0"ND.. .' 2.0 ND 2.0 ND.ý 2.0 ND 2.0 ND 2.0 ND.. 2.0 ND.. 2.0 ND: 2.0 ND 2.0 ND 20 ND 5.0 ND 2.0*ND 2.0 ND 2.0 ND 5.0 ND 5.0 ND 5.0 ND. 2.0 N2.0.ND: ..2.0 ND. -5.0 ND. 2.0 ND 2.0 ND: 2.0 0.24 0.32 0.25 0,78 0.62 0.39 0.58 0.49 0.79 0.63 1.4 0.58 0.74 0.63 0.89 1.2 0.41 0,45 0.67 1..5 0.54 0.72 1.4 1.2 1.1 1.0 0.61 0.50 0.80 0.23 0.58 0.32 ug/l ugh ug/h ug/h ug/I ug/1 ug/]ug/l ug/1 ug/l ug/1 ughl ug/l ug/I ug/l ug/]ug/l ug/1 ug/l ug/l ug/1 ug/h ug/l ug/l ug/l ug/I ugh]ug/A ug/1 ughl ught ug/1 CAS No. Surrogate RecoveriesRun# 1 Run# 2 Limits 367-12-4 4165-62-2 118-79-6 4165-60-0 321-60-8 2-Fluorophenol Phenol-d5 2,4,6-Tribromophenol Nitrobenzene-d5 2-Fluorobiphenyl 37%34-%89%85%79%10-88%10-71%45-134%32-128%34-121%ND = Not detected MDL -Method Detection Limit RL Reporting Limit E = Indicates value exceeds calibration range I = Indicates an estimated 0 A B Indicates analyte found ir associate"method blank N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 3 of 3#4,Client Sample ID: FB-I Lab Sample ID: N85893-2 Date Sampled: 12/10/04 Matrix: AQ -Field Blank Water Date Received: 12/13/04 Method: SW846 8270C SW846 35]0C Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ ABN TCL List CAS No. Surrogate Recoveries 1718-51-0 Terphenyl-d 14 Run# 1 Run# 2 Limits 90Q%41-129%ND = Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range I Indicates an estimated vat. " .1, B = Indicates analyte found inr."Ossociated met od blank N = Indicates presumptive evidence of a compound Accutest Laboyatories Report of Analysis Page ] of 2 Client Sample ID: TRIP BLANK Lab Sample ID: N85893-3 Date Sampled: 12/10/04 Matrix: AQ -Trip Blank Water Date Received: 12/13/04 Method: SW846 8260B Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2C]398.D 1 12/19/04 KNV n/a n/a V2C63 Run #2 Purge Volume Run #1 5.0 ml Run #2 VOA TCL List CAS No. Compound Result RL MDL Units Q 67-64-1 Acetone ND 10 2.3 ug/1 71-43-2 Benzene ND 1.0 0.31 ug/h 75-27-4 Bromodichloromethane ND 1.0 0.11 ug/h75-25-2 Bromoform ND 4.0 0.17 ug/!74-83-9 Bromomethane ND 2.0 0.15 ug!1 78-93-3 2-Butanone (MEK) ND 10 2.5 ug/I 75-15-0 Carbon disulfide ND 2.0 0.23 ug/1 56-23-5 Carbon tetrachloride ND 1.0 0.15 ug/1 108-90-7 Chlorobenzene ND 1.0 0.23 ug/l 75-00-3 Chloroethane ND 1.0 0.73 ug/I 67-66-3 Chloroform ND 1.0 0.081 ug/l 74-87-3 Chloromethane ND 1.0 0.13 ug/l 124-48-1 Dibromochloromethane ND 1.0 0.18 ug/]75-34-3 1, 1-Dichloroethane ND 1.0 0.13 ug/l 107-06-2 1,2-Dichloroethane ND 1.0 0.35 ug/l 75-35-4 1,1-Dichloroethene ND 1.0 0.81 ug/h 156-59-2 cis-1,2-Dichloroethene ND 1.0 0.24 ug/l 156-60-5 trans- 1,2-Dichloroethene ND 1.0 0.17 ug/l 78-87-5 1,2-Dichloropropane ND 1.0 0.11 ug/h 10061-01-5 cis-1,3-Dichloropropene ND 1.0 0.071 ug/]10061-02-6 trans- 1,3-Dichloropropene ND 1.0 0.080 ug/l 100-41-4 Ethylbenzene ND 1.0 0.27 ug/l 591-78-6 2-Hexanone ND 5.0 0.73 ughl 108-10-1 4-Methyl-2-pentanone(MIBK) ND 5.0 0.59 ug/l 75-09-2 Methylene chloride ND 2.0 0.20 ug/1 100-42-5 Styrene ND 5.0 0.12 ughl 79-34-5 1, 1,2,2-Tetrachloroethane ND 1.0 0.14 ugl ..127-18-4 Tetrachloroethene ND 1.0 0.37 ug/1 ..108-88-3 Toluene ND 1.0 0.14 ug/l 71-55-6 1,1, 1-Trichloroethane ND 1.0 0,25 ug/l 79-00-5 1, 1,2-Trichloroethane ND 1.0 0.17 ug/h 79-01-6 Trichloroethene ND 1.0 0.13 ug/i ND Not detected MDL -Method Detection Limit I1 Indicates an estimated valuQ " is RL = Reporting Limit B = Indicates analyte found in 'associated method blank E = Indicates value exceeds calibration range N Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 2 of 2 Client Sample ID: TRIP BLANK Lab Sample ID: N85893-3 Date Sampled: 12/10/04 Matrix: AQ -Trip Blank Water Date Received: 12/13/04 IMethod: SW846 8260B Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ VOA TCL List CAS No. Compound 75-01-4 Vinyl chloride 1330-20-7 Xylene (total)Result RL MDL Units Q.ND :: 1.0 ND 1.0 0.66 ug/I 0.17 ug/l CAS No. Surrogate Recoveries Run# I Run# 2 Limits 1868-53-7 17060-07-0 2037 5 460-00-4 Dibromofluoromethane 1,2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene 102*%960%90%1'05'%79-119%68-129%83-118%82-120%"Vw ND Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds. calibration range J = Indicates an estimated valt4" IL 6 B = Indicates analyte found in¶n96ciated method blank N Indicates presumptive evidence of a compound SACCUTEST*Laboratories CHAIP( F CUSTODY 2235 Route 130, DOyton NJ 08810 FED-TEL. 732-329-0200 FAX: 732-329-3499/3480 w-'w ecutlest.com Acoe______ C j BoiPe Order Corrtr~iU EX Tracking I I Battle Order Control 0 Accuinsl lest Ouole 0 Amrt.M Jb It/ v ? 5 ý6 r.M,,~ I Cliet I epoiings afomtioM:qlfiY OW-' ct xf1e s I Company Name.Ar C405h~Pr2ectam Address city state Zip City Slate Phone ff ( Fax/cf? -- G .- oo .6") O1 Sampler , am CiGenat Perch°as Order #DO 0oo O0 00 0 o ii 00 00 00 00 00 00-0 W. -WaterSIN -&(c-un W." SW. Water SO-S61 SL -Studge 1.1 -Othr AIR -Air SOL -S d-Wipe LAO USE ONLY AcCulesi Samyfe 0 CJ Field tO Point of Collection SUMMl~AII Colwcta I N errsred Battes'4aww~i' Vei 1m -' tXJ'4tS 0 1ý11er I i .5 0-,_ ___-- 2I'1__ , ', ,r , , ....,_F3)_ __ ~~ ,5. ~. _ _ __ --I ---__ _'I I-- ------------------------------- -,, Tufnatound Thle (Bmsinelsas Data DelierablelrIrMotiaon -N Co nt I e O Std. 15 Business Day Approved By. Date: 0 Corrnercial' D FULLClP CL P t o to Day RUSH 0 Commeccat "' ] NYASP Category A O1 5 Day RUSH __ NJ Reduced 0 NYASP Category B 01 3 Day EME.RGENCY .0 NJ F H 0 State Forms S-Day MERGENCY 0 Oilier EDO F m .at .O] 1 Day El.4RGE:NCV ... eu~Ol 0] 1 Day EMERGENCY O 01h, " rc mer " Results Only EA dal veable VIA LabLink I Sample Custody must be documented below each rime samples change possesson. including courie( everY.Reewe y-ose n": Rac klin.. .. Use -_o __,, 13 " pelinqmeshed by" Dame Tiwne ee 5 _ _ _;ed hreisred by: "rat: Receiwed 4 redr esidr5.01*Pesrnd omee plicabi OnIce Cente TerrO, wd by,. Accuiest Laboratories Internal Sample Tracking Chronicle Arcadis Geraghty & Miller Job No: N85893 PSEG-Salem, Artificial Island, Salem, NJ Project No: NP000571 I Sample Number Method Analyzed By Prepped By Test Codes N85893-1 SW846 8260B 19-DEC-04 20:42 KNV V8260TCL N85893-1 SW846 8270C 31-DEC-04 06:05 NAP 14-DEC-04 VDT AB8270TCL.................................. .............. ....... ~ .. ..... ..... ............ ......... .. .u'" ............................... .......... .. .......-.. .......NS589~... ..C.......... .1~ EC 0 .... .......... TR.....P. .... ....N8S893-3 ~ ~ ~ ~ ~ ~ ..W4 ....9-E-4214 N V2OC to o is.-Page 1 of I GC/MS 6wr VOLATILE 20 GC/MS Analysis Case Narrative/Conformance/Non-Conformance Summary Fraction NO YES 1. Chromatograms Labeled/Compounds Identified (Field Samples and Method Blanks) __/2. GCUMS Tune Meet Criteria _____3. GC/MS Tuning Frequency -Performed every 24 hours for 600 series and 12 hours for 8000 sernes. _ _4, GC/MS Calibration -Initial and.Continuing Calibration Meet Method Requirements 5, GC/MS Calibration Requirements
- a. Calibration Check Compounds b. System Performance Check Compounds 6. Blank Contamination
___ifyes, the sample result is qualified with a "B".7. Surrogate Recoveries'Meet Criteria.If the requirement is not met, refer to the Surrogate Summaryfor comment.8. Matrix Spike/Matrix Spike Duplicate Recoveries. Meet Criteria If the requirement is not met, refer to MS/MSD Summaryfor comment.9. Internal Standard Area/Retention Time Shift Meet Criteria _ __if the requirement is not met, refer to the internal Standard Summaryfor comment.10. Extraction Holding Time Met If the holding time is not met, refer to the Sample Result page for comment.11. Analysis Holding Time Met _If the holding time is not met, refer to the Sample Result page for comment.12. Volatile -Sample Preservation-pH should be < 2. List anynon-compliant samples below: Additional Comments: QC Review Sicnature: \ l 7 Date: I, /Form: RG04 Rev. Date: 2/9/00 Method Blank Summary Page I of 2 Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V2C63-MB1 2C1383.D 1 12/19/04 KNV n/a n/a V2C63 The QC reported here applies to the following samples: Method: SW846 8260B N85893-1, N85893-2, N85893-3 CAS No. Compound Result RL MDL Units Q 67-64-1 Acetone NO 10 2.3 ugh 71-43-2 Benzene ND 1.0 0.31 ug/l 75-27-4 Bromodichloromethane ND "1.0 0.11 ug/l75-25-2 Bromoforrn ND 4.0 0.17 ug/1 74-83-9 Bromomethane N. 2.0 0.15 ug/l 78-93-3 2-Butanone (MEK) ND .10 2.5 ug/l75-15-0 Carbon disulfide ND 2.0 0.23 ug/l 56-23-5 Carbon tetrachloride ND 1.0. 0.15 ug/l 108-90-7 Chlorobenzene ND 1.0 0.23 ug/l 75-00-3 Chloroethane ND 1.0 0.73 ug/1 67-66-3 Chloroform ND 1.0 0.081 ug/l 74-87-3 Chloromethane ND 1.0 0.13 ugh 124-48-1 Dibromochloromethane ND 1.0 0.18 ug/1 75-34-3 1,1-Dichloroethane ND 1.0 0.13 ug/l 107-06-2 1,2-Dichloroethane ND .1.0 0.35 ug/]75-35-4 1,1 -Dichloroethene ND.: 1.0 0.81 ug/l 156-59-2 cis- 1,2-Dichloroethene ND 1.0 0.24 ug/l 156-60-5 trans- 1,2-Dichloroethene
- N.D.:: 1.0 0.17 ug/l 78-87-5 1,2-Dichloropropane ND 1.0 0.11 ug/l 10061-01-5 cis-l,3-Dichloropropene ND. 1.0 0,071 ug/l 10061-02-6 trans- I,3-Dichloropropene ND. 1.0 0.080 ug/l 100-41-4 Ethylbenzene ND. 1.0 0.27 ug/l 591-78-6 2-Hexanone ND 5.0 0.73 ug/1 108-10-1 4-Methyl-2-pentanone(MIBK)
ND 5.0 0.59 ug/l;75-09-2 Methylene chloride ND 2,0 0.20 ug/l 100-42-5 Styrene ND 5.0 0.12 ug/l 79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.14 ug/l 127-18-4 Tetrachloroethene ND 1.0 0.37 ug/l 108-88-3 Toluene ND 1.0 0.14 ug/l 71-55-6 1, 1, 1-Trichloroethane ND 1.0 0.25 ug/l 79-00-5 1, 1,2-Trichloroethane ND 1.0 0.17 ug/l79-01-6 Trichloroethene ND 1.0 0.13 ug/l 75-01-4 Vinyl chloride ND 1.0 0.66 ug/l 1330-20-7 Xylene (total) ND 1.0 0,17 ug/l 9,.z Method Blank Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 2 kv Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V2C63-MBI 2C1383.D 1 12/19/04 KNV n/a n/a V2C63The QC reported here applies to the following samples: Method: SW846 8260B N85893-1, N85893-2, N85893-3 CAS No. Surrogate Recoveries 1868-53-7 Dibromofluoromeihane 17060-07-0 1,2-Dichloroethane-D4 2037-26-5 Toluene-D8 460-00-4 4-Bromofluorobenzene Limits:98:%88%:1:05%79-119%68-129%83-118%82-120%CAS No. Tentatively Identified Compounds R.T.Est. Cone. Units Q Total TIC, Volatile 0 ug/l#%V Blank Spike Summary Page I of 2 Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller~ Project: PSEG-Salem, Artificial Island, Salem, NJ Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V2C63-BS 2C1384.D 1 12/19/04 KNV nla n/a V2C63 The QC reported here applies to the following samples: Method: SW846 8260B N85893-1, N85893-2, N85893-3 Spike BSP BSP CAS No. Compound ug/l ug/h % Limits 67-64-1 Acetone 50 41.6 83 .53-153 71-43-2 Benzene 50 49.6 99 77-119 75-27-4 Bromodichloromethane 50 54.3 109. 82-126 75-25-2 Bromoform 50 56.3 .1.13 73-135 74-83-9 Bromomethane 50 55.4 .111 61-138 78-93-3 2-Butanone (MEK) 50 50.9 )02 58-142 75-15-0 Carbon disulfide 50 55.5 '4111 60-130 56-23-5 Carbon tetrachloride 50 60.2 120 "72-140 108-90-7 Cblorobenzene 50 51.0 1.02- 81-117 75-00-3 Chloroethane 50 56.8 1. 14 69-135 67-66-3 Chloroform 50 53.5 1:07: 80-122 74-87-3 Chloromethane 50 65.8 -132 59-132 124-4841 Dibromochloromelhane 50 59.0 .118 80-125 75-34-3 1,1-Dichloroethane 50 53.6 107 78-121 107-06-2 1,2-Dichloroethane 50 60,] 120. 66-137 75-35-4 .1, 1-Dichloroethene 50 55.1 110 73-124 156-59-2 cis-1,2-Dichloroethene 50 47.8 96 76-120 156-60-5 trans-1,2-Dichloroethene 50 51.0 102::..: 73-119 78-87-5 1,2-Dichloropropane 50 50.9 102 82-117 10061-01-5 cis-1,3-Dichloropropene 50 47.6 95.. 81-120 10061-02-6 trans-I ,3-Dichloropropene 50 49.9 100 81-125 100-41-4 Ethylbenzene 50 51.7 .1103 79-120 591-78-6 2-Hexanone 50 44.,6 89 66-140 108-10-1 4-Methyl-2-pentanone(MIBK) 50 51.6 103 70-134 75-09-2 Methylene chloride 50 55.6 11.1 75-122 100-42-5 Styrene 50 50.9 102 80-125 79-34-5 ] ,l,2,2-Tetrachloroethane 50 53.4 107 76-117 127-18-4 Tetrachloroethene 50 50.2 100 69-130 108-88-3 Toluene 50 47.4 95 81-120 71-55-6 1,1,1-Trichloroethane 50 53.5 10.7 77-132 79-00-5 1,1,2-Trichloroethane 50 49.5 99 85-117 79-01-6 Trichloroethene 50 51.9 .104 83-119 75-01-4 Vinyl chloride 50 62.0 .124 65-135 .. .1330-20-7 Xylene (total) 150 150 100 81-119 2.*: ~s;. Blank Spike Summary Job Number: N85893Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 2 LV Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V2C63-BS 2C1384.D 1 12/19/04 KNV n/a n/a V2C63 The QC reported here applies to the following samples: Method: SW846 8260B N85893-1, N85893-2, N85893-3 CAS No. Surrogate Recoveries 1868-53-7 Dibromofluoromethane 17060-07-0 1,2-Dichloroethane-D4 2037-26-5 Toluene-D8 460-00-4 4-Bromofluorobenzene BSP.. ..:9 t.0:.Limits 79-119%68-129%83-118%82-120%kav a,-trix Scpie/Matrix Spike Duplicate Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 1 of 2 Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch N85524-33MS 2C1401.D 1 12/19/04 KNV n/a n/a V2C63 N85524-33MSD2C1402,D 1 12119/04 KNV n/a n/a V2C63 N85524-33 2C1385.D 1 12/19/04 KNV .n/a n/a V2C63 The QC reported here applies to (he following samples: Method: SW846 i260B N85893-1, N85893-2, N85893-3 N85524-33 Spike ug/h Q ug/l MS ug/h MS MSD MSD% ug/l %Limits Rec/RPD CAS No. Compound RPD 67-64-1 Acetone 71-43-2 Benzene 75-27-4 Bromodichlorormethane 75-25-2 Bromoform74-83-9 Bromomethane 78-93-3 2-Butanone (MEK)75-15-0 Carbon disulfide 56-23-5 Carbon tetrachloride 108-90-7 Chlorobenzene 75-00-3 Chloroethane 67-66-3 Chloroform 74-87-3 Chloromethane 124-48-1 Dibromochloromethane 75-34-3 1,1-Dichloroethane 107-06-2 1,2-Dichloroethane 75-35-4 1,1 -Dichloroeihene 156-59-2 cis-1,2-Dichloroethene 156-60-5 trans- 1,2-Dichloroethene 78-87-5 1,2-Dichloropropane 10061-01-5 cis-1,3-Dichloropropene 10061-02-6 trans- 1,3-Dichloropropene 100-41-4 Ethylbenzene 591-78-6 2-Hexanone 108-10-1 4-Metbyl-2-pentanone(M1BK) 75-09-2 Methylene chloride 100-42-5 Styrene 79-34-5 1,1,2,2-Tetrachloroethane 127-18-4 Tetrachloroethene 108-88-3 Toluene 71-55-6 1,1,1 -Trichloroethane 79-00-5 1, 1,2-Trichloroethane 79-01-6 Trichloroethene 75-01-4 Vinyl, chloride 1330-20-7 Xylene (total)ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.82 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 50 50 50 50 50 50 50.50 50 50 50 50 50 50 50 50 3 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 150 45.2 48.6 53.1 54.5 51.8 43.0 56.6 59.6 50.0 54.5 53.2 57.0 58.5 53.5 56.2 55.5 50.0 50.5 50.0 44.2 45.9 49.9 43.5 48.7 54.5 47.2 51.0.49,7 45.3 53.5 49.0 51.5 59.4 146 90,.971..i:.. 1 t06.: 109 104 113* .1o9 .100 109 106 1.1:.....1:1.7: 107 112 911 98 101 100 88*92 *100 87 : 97. -,109".'94 -* 102:99 91 107 98 103.1.19 97 46.2 49.5 54.3 54.8 51.0 41.2 57.6 62.3 50.8 54.9 53.9 55.7 59.1 54.3 57.3 57.0 50.4 50.9 51.3 45.6 47.4 51.0 44.2 49.3 55.4 48.7 51.9 51.2 47.7 54.8 50.0..53.1 59.3..15 1" :ý92 2:99. 2..-110 1 1 02 2 82 .4:.15.125:. .4.*12: 2 11.0 .1 108 -1 11.1 2 118 1 109 1.115 2 114 3 99. 1 102 1.103 3 91t 3 3 102 .2 88 ..2" 99 1.I1..11 2 97 3 104 2 102 3:95 5 1001 2 106 .3 119. 0 101 3 47-163/22 51-138/10 80-128/10 68-137/10 61-141/17 55-149/22 59-128/14 71-143/13 78-120/10 67-139116 78-126111 57-134/17 79-127110 75-125/11 63-142/12 69-129112 73-127/10 71-123/11 81-120/10 78-121/10 77-128/11 51-142/11 64-145/13 66-140/12 73-126/10 79-130/10 74-121/10 70-128/12 49-147/10 74-136/13'83,121/10 75-128/10.60-141/16 44-146/11 pu~ Matrix Spike/xatrix Spike Duplicate SummaryJob Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 2 Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch N85524-33MS 2C1401.D 1 12/19/04 KNV n/a n/a V2C63 N85524-33MSD2C1402.D 1 12/39/04 KNV n/a n/a V2C63 N85524-33 2C1385.D 1 12/19/04 KNV n/a n/a V2C63 The QC reported here applies to the following samples: N85893-1, N85893-2, N85893-3 Method: SW846 8260B CAS No. -Surrogate Recoveries 1868-53-7 Dibromofluoromethane 17060-07-0 1,2-Dichloroethane-D4 2037-26-5 Toluene-D8 460-00-4 4-Bromofluorobenzene MS MSD N85524-33 Limits 103%,.95%90%1.03W%102%95%92%104%G00%*97 %.88%*106%79-119%68-129%83-118%82-120%27' instrument Performance Check (BFB)Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 1 of 1 to Sample: V2C1-BFB Injection Date: 11/15/04 Lab File ID: 2C0021..D Injection Time: 13:30 Instrument ID: GCMS2C Raw % Relative m/e Ion Abundance Criteria Abundance Abundance Pass/Fail 50 15.0- 40:0% of mass 95 2341 1.71..2 Pass 75. 30.0- 60.0% of mass 95 6185 45.3-Pass-9ý5 Base peak, 100% relative abundance 13642 Pass 96 5.0- 9.0% of mass 95 1065 .7., Pass 7173 Less than 2.0% of mass 174 0 0.0 .:(0;0)2a Pass 17. 50.0 -150.0% of mass 95 14402 105.6 .Pass 175 .5.0 -9.0% of mass 174 1049 7.7' (73)a Pass 176:.¢ 95.0- 101.0% of mass 174 14331 -05.J (99.5)" Pass 177' 5.0- 9.0% of mass 176 957 7.0 .(6:7) ::. Pass (a) Value is % of mass 174 (b) Value is % of mass 176 This check applies to the following Samples, MS, MSD, Blanks, and Standards: Lab Lab Date Time Hours Client Sample ID File ID Analyzed Analyzed Lapsed Sample ID V2CI-]COOI 2C0022.D 11/15/04 14:04 00:34 Initial cal 1 V2CI-IC00I 2C0023.D 11/15/04 14:35 01:05 Initial cal 2 V2CI-IC00I 2C0024.D 11/15/04 15:06 01:36 Initial cal 5 V2CI-ICOO] 2C0025.D .11/15/04 15:38 02:08 Initial cal 20 V2CI-ICCOO1 2C0026.D 11/15/04 16:09 02:39 Initial cal 50 V2CI-1C001 2C0027.D 11/15/04 16:40 03:10 Initial cal 100 V2C]-1C001 2C0028.D 11/15/04 17:11 03:41 Initial cal 200 0 .... 1Istrument Performance Check (BFB)Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 1 of I Sample: V2C63-BFB Injection Date: 12/19/04 Lab File ID: 2C1381.D Injection Time: 12:06 Instrument ID: GCMS2C Raw % Relative ro/e Ion Abundance Criteria Abundance Abundance Pass/Fail 50. 15.0 -40.0% of mass 95 75 -30.0 -60.0% of mass 95 95 Base peak, 100% relative abundance 96 .:5.0- 9.0% of mass 95 1:73 Less than 2.0% of mass 174 1 74: .50.0 -150.0% of mass 95: :.75 5.0- 9.0% of mass 174 176,. 95.0- 101.0% of mass 174-177:.1 5.0 -9.0% of mass 176 1396 3512 6725 499 0 6353 454 6123 418 20,8 52.2 100.0 7.4 0.0 94..5 6,8 91.0 6.2, Pass Pass Pass Pass (0.0)a..,. (:,i 6;8):b~Pass Pass Pass Pass (a) Value is % of mass 174 (b) Value is % of mass 176 This check applies to the following Samples, MS, MSD, Blanks, and Standards:
- AV Lab Sample ID V2C63-CCOO1 V2C63-MBI V2C63-BS N85524-33 ZZZZZZ ZZZZZZ ZZZZZZ ZZZZZZ ZZZZZZ ZZZZZZ ZZZZZZ ZZZZZZ ZZZZZZ ZZZZZZ N85893-1 N85893-2 N85893-3 ZZZZZZ ZZZZZZ N85524-33MS N85524-33MSD Lab File ID 2C1382.D 2C1383.D 2C1384.D 2C1385.D 2C1386,D 2C1387.D 2C1388.D 2C1389.D 2C1390.D 2C1391.D 2C1392.D 2C1393.D 2C]394.D 2C1395.1D 2C1396.D 2C1397.D 2C1398.D 2C1399.D 2C1400.D 2C1401.D 2C1402.D Date Time Hours Analyzed Analyzed Lapsed 12/19/04 12119/04 12119/04 12/19/04 12/19/04 12/19/04 12/19/04 12/19/04 12/19/04 12/19/04 12/19/04 12/19/04 12/19/04 12/19/04 12/19/04 12/19/04 12/19/04 12/19/04 12/19/04 12/19/04 12/19/04 13:22 13:53 14:25 14:56 15:28 15:59 16:31 17:02 17:33 18:05 18:36 19:08 19:39 20:10 20:42 21:13 21:44 22:16 22:47 23:19 23:50 01:16 01:47 02:19 02:50 03:22 03:53 04:25 04:56 05:27 05:59 06:30 07:02 07:33 08:04 08:36 09:07 09:38 10:10 10:41 11:13 11:44 Client Sample ID Continuing cal 20 Method Blank Blank Spike (used for QC only; not part of job N85893)(unrelated sample)(unrelated sample)(unrelated sample)(unrelated sample)(unrelated sample)(unrelated sample)(unrelated sample)(unrelated sample)(unrelated sample)(unrelated sample)WELL AZ FB- I TRIP BLANK (unrelated sample)(unrelated sample)Matrix Spike Matrix Spike Duplicate 21 to Volatile internal Standard Area Summary Page I of I Job Number: N85893Account: AGMPAL Arcadis Geraghty &
Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Check Std: V2C63-CCOO1 Injection Date: 12/19/04 Lab File ID: 2CI382.D Injection Time: 13:22 Instrument ID: GCMS2C Method: SW846 8260B IS1 IS2 IS3 1S4 IS5 AREA RT AREA RT AREA RT AREA RT AREA RT Clheck.Std.i. .:.ý": .27362 8,24 10912.1 10.68 139460, .11.61 104982:- 14.62 ::61.983. 16.78 Upper Limita 54724 8.74 .12I18242.:::- 11.18 .278920 12.11 .209964 15.12 6 17.28 Lower Limit b 13681:'. 7.74 54561 10.18 069730: 11.11 5249"' .. 14.12 .30992.. 16.28 Lab ISi IS2 IS3 1S4 IS5 Sample ID AREA RT AREA RT AREA RT AREA RT AREA RT V2C63,MBI 27688 8.24 107086 10,68 134740 11.61 100625 14.62. 56677 16.78 V2C63-BS' 28768' 8.23 1155:15 10.67 147.2.19 11.61 111299 14.61' 64843 16.78 N85524-33 29678 8.23 116263 10.68 144551 11.61 1,084119 14.61 61031 16,78 ZZZZZZ '29734 8.24 11.6268. 10.68 145428 11,61 1075.93. 14.61 6.1102. 16.78 ZZZZZZ 28541. 8.24 113.113 10.68 142202 11.61 104845:.,. 14.61 59025 .16.78 ZZZZZZ 27870 8.23 1114288 10.68 138503 11,61 '10284.3 14.61 58374 16,78 ZZZZZZ 28809. 8.23 115438;:-:. 10.67 146863 11.61 107960'; :,::.: 14.61 b.1339..: 16.78 ZZZZZZ 27862. 8.23 1:1:11479 10.67 1-4204.1 .11,61 104850Q::.- 14.61 :5829 16.78 ZZZZZZ ý28733:. 8.23 11 4082 10.67 144557 1,61 1-06169...
- .. 14.61 60498 16.78 ZZZZZZ .27754.. 8.24 108957., 10.68 '137253. 11.61 1.01925 14.61 .58.083 16.78 ZZZZZZ 287906. 8,23 113853" 10,68 143662 11.61 1707559. 14.61 60023 16.78 ZZZZZZ -.29356 8.23 .113463::..
10.68 145460. 11.61 107978, 14.61 60588 .16.78 ZZZZZZ 2677.9 8.24 .11000"01 10.67 140121 11.61 103947 14.61 .597.17 16.78 N85893-1 28847. 8.24 112901 10,68 143489 11.61 106439 14.61 59636 16.78 N85893-2 :29612.. 8.23 1-12704, 10,68 143678 11.61 107329 14.61 :59.647 *16.78 N85893-3 29328 8.23 .112490 10.68 143200 11.61 1:06559 14.61 60579 16,78 ZZZZZZ 28487.- 8.23 110962.. 10.67 143008 11.61 105533: 14,61 5.9236 16.78 ZZZZZZ .287-76* .8.23 .112189. .10.68 142549 11.61 106684..: 14.61 .59984 '16,78 N85524-33MS 3.1,121 8.23 -117683-:.,- 10.68 150643 11.61 113333 14.61 "6655.7 16.78 N85524-33MSD .31928. 8.24 3123303': 10.67 155678 11.61 119553:.:" 14.61 :69473. '16.78'IS 1 = Tert Butyl Alcohol-D9 IS 2 = Pentafluorobenzene IS3 = 1,4-Difluorobenzene IS 4 = Chlorobenzene-D5 IS 5 = 1,4-Dichlorobenzene-d4 (a) Upper Limit = + 100% of check standard area; Retention time +0.5 minutes.(b) Lower Limit = -50% of check standard area; Retention time -0.5 minutes.' 30 Volatile Surrogate Recovery Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page I of I kle Method: SW846 8260B Matrix: AQSamples and QC shown here apply to the above method Lab Sample ID Lab File ID S1 S2 S3 S4 N85893-1 N85893-2 N85893-3 N85524-33MS N85524-33MSD V2C63-BS V2C63-MB1 2C1396.D 2C1397.D 2C1398.D 2C]401,D 2C 1402. D 2C1384.D 2C1383.D:1103 .0 .ý:;. 96.0 10220.0 97,0:lO i ..:: 96.0 1.0 95.0 102:.0: 95.0 102.ý,0, 98.0 102..0 98.0 Recovery Limits 83-118%7v 82-120%900.92.0.88.0:106.0 105.0 J05.0 103.0 104.0* 104.0 105.0 Surrogate Compounds S1 = Dibromofluoromethane S2 = I ,2-Dichloroethane-D4 S3 = Toluene-D8 S4 = 4-Bromofluorobenzene o_*. Initial Calibration Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page I of 3 Sample: V2CI-ICCOOI Lab FilelD: 2C0026.D Response Factor Report MS2C Method Title Last Update Response via C:\MSDCHEM\2\METHODS\M2CO00.M (RTE Integrator) SW-846 Method 8260Thu Nov 18 10:21:14 2004 Initial Calibration Calibration Files 1 =2C0022.D 2 =2C0023.D 20 =2C0025.D 200 =2C0028.D 100 =2C0027.D 5 =2C0,024.D 50 =2C0026.D Compound 1 2 100 50 20 200 5 Avg %RSD...........................................................................
- 1) I Tert Butyl Alcohol-d9
ISTD --------------------- 2)M tertiary butyl al 0.991 1.006 0.951 1.038 0.960 0.9893 .57 For special project Tertiary butyl alcohol RL = 10 ppb.2)M tertiary butyl al 0.335 0.991 1.006 0.951 1.038 0.960 0.880 30.57-....Linear regression Coefficient = 0.9996 Response Ratio = -0.01692 + 1.03889 *A******** ***** *********
- * ****** **** ** *********
- *A* *** ******3)M 1,4-dioxane 0.088 0.091 0.081 0.097 0.071 0.086 11.72----ISTD-.---------------------
- * ****** **** ** *********
- 4) 1 5)M 6)m 7)M 8)M 9)M 10)M 1l)M 12)M 13) M 14)M 15)M 16) M 17)M 18)M 19)M 20)M 21)M 22)M 23)M 24) M 25)M 26)M 27)M 28)M 29)M 30)M pentafluorobenzene chlorodifluoromet dichlorodifluorom chloromethane vinyl chloride bromomethane chloroethane trichlorofluorome ethyl ether acrolein 0.936 0.391 0.636 0.508 0.394 0.237 0.647 0,783 0.402 0.641 0.567 0.403 0.301 0.679 0.187 0.875 0.561 0.629 0.631 0.385 0.299 0.778 0.224 0.006 0.826 0.530 0.599 0.601 0.378 0.299 0,759 0 .213 0.006 0.832 0.520 0 .601 0.601 0 .381 0.298 0.741 0.204 O.004 0.858 0.567 0.621 0.631 0.363 0.288 0.793 0.228 0.006 0.865 0.503 0.631 0.600 0.392 0.299 0.761 0.203 0.002 0.854 0.496 0.623 0.591 0.385 0.289 0.737 0,210 0.0054-Linear regression
Coefficient
= 0.9995 Response Ratio = -0.00752 + 0.00653 *A 1,1-dichloroethen acetone allyl chloride, acetonitrile iodomethane iso-butyl alcohol carbon disulfide metbylene chlorid methyl acetate methyl tert butyl trans-l,2-dichlor di-isopropyl ethe 2-butanone 1,1-dichloroethan chloroprene acrylonitrile vinyl acetate0.381 0.451 0.425 0.428 0.401 0.440 0.126 1.558 1.503 0.0410.665 0.810 1.362 0.368 0.221 1.00 0.574 1.693 0.352 0.756 0.537 0.090 1.480 0,489 0.259 2.180 0.533 1.595 0.396 0.848 0.517 0,110 0.118 1.373 0.035 0.890 0.005 1.540 0.481 0.297 1.222 0.478 1.755 0.489 0.885 0.628 0.127 0.054 0.122 1.353 0.034 0.864 0.005 1.522 0.473 0.289 1.154 0.468 1.722 0.470 0.871 0.610 0.120 0.051 0.119 1.305 0.034 0.807 0.004 1.425 0.450 0.276 1.095 0.457 1.631 0,446 0.827 0.574 0.114 0,110 1,360 0 .033 0 .902 0.005 1.548 0.487 0.294 2. 188 0.489 1.736 0.478 0. 902 0.641 0.127 0.433 0.423 0.134 0.121.1.432 1.412 0.040 0.036 0.838 0.825 0 .005#1.480 1.480 0,479 0.461 0.310.0-.278 1.262 1.'156 0.554' 0.5.0.8 1"71,6 :.6..920.471 '0.443-- 0.880 .o.iý2 0.591 0.585" 0.117 0.115 0,036 0.048 5.55 14 .48 2.67 7.19 3.38 8.03 7.30 7.26 35.29 5.65 6.78 6.41 9.60 9.67 12. 01 4.54 9.37 10.76 3.81 9.01-3.46 S1i.' 41 5..78 7.86 10.99 16.24 0.045 0.055----- Linear regression
Coefficient
= 0.9998 Response Ratio = -0.00377 + 0.05624 *A 0 Initial Calibration Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 3 Sample: V2CI-ICCOO0 Lab FilelD: 2C0026.D 31)M 32)M 33)M 34)M 35) M 36)M 37)M 38)M 39) S 40) S 41)M 42) M 43)M 44)M ethyl tert-butyl ethyl acetate 2,2-dichloropropa cis-1,2-dichloroe propionitrile bromochloromethan tetrahydrofuran chloroform dibromofluorometh 1,2-dichloroethan freon 113 methacrylonitrile 1,1,1-trichloroet Cyclohexane 1.471 1.312 0.727 0.787 0.517 0.563 0,036 0.232 1.549 0.047 0.798 0.540 0.045 0.255 0. 101 0.856 0.467 0.462 0.447 0.230 0.814 0.771 1.485 0.046 0.779 0.598 0.043 0.245 0.096 0.846 0.446 0.444 0.430 0.223 0.792 0.734 1.416 0.041 0.747 0.538 0.040 0.233 0.087 0.801 0.443 0.444 0.420 0.212 0.756 0.704 1.527 0.046 0.799 0.556 0,045 0.260 0.101 0.881. 0.485 0. 464 0.452 0.232 0.826 0.786 1.467 0.036 0.794 0.587 0.041 0.236 0.069 0.829 0.447 0.453 0.421 0.224 0.796 0.721 1.461 0.043 0.776 0.557 0.042 0,243 0.091 0.828 0.438 0.443 0.406 0.233 0.778 0.723 0.738 0.359 0.416 0.350 0.261 0.670 0.637 0.847 0.420 0.422 0.325 0.253 0.789 0.708 45) I 1,4-difluorobenzene
ISTD ----------------------
- 46) M 47) M 48)M 49)M 50) M 51)m 52)M 53) M 54) M 55)14 56)m 57)M 58)M 59)M 60) M 61)M 62)M 63)M 64)M 65)M 66)M 67) M 68)S 69)M 70) M 71)M 72)M 73)M 74)M 75)M Di-isobutylene 0.824 0.827 0D994 0.953 0.863 1.036 0.876 epichlorohydrin 0.021 0.020 0.018 0.021 0.018 n-butyl alcohol 0.005 0.005 0.004 0.004 0.007 0.004 0.007 Linear regression
.....-Coefficient = 0.9951 Response Ratio = 0.01353 + 0.00427 *A 0.910 0.019 0.005#carbon tetrachlor 1,1-dichloroprope hexane tert amyl alcohol iso-octane benzene tert-amyl methyl heptane isopropyl acetate 1,2-dichloroethan trichloroethene 2-nitropropane 2-chloroethyl vin methyl methacryla 1,2-dichloropropa dibromomethane methylcyclohexane bromodichlorometh cis-1,3-dichlorop toluene-d8 (s)4-methyl-2-pentan toluene 3-methyl-l-butano trans-l,3-dichlor ethyl methacrylat 1,1,2-trichloroet 2-hexanone 0.424 0.410 0.507 0 .498 0.453 0.401 1.488 1.475 1.052 0.936 0.236 0.184 0.447 0.413 0,340 0.396 0.318 0.338 0.146 0.142 0.133 0.120 0.291 0.336 0.128 0.170 0.561 0.504 0.362 0.395 0.442 0.491 1.095 1.086 0.228 0.278 0,726 0.752 0.382 0.403 0.227 0.150 0.189 0.116 0.550 0.471 0.438 1.371 0.984 0.210 0.475 0.416 0.357 0.151 0.165 0.160 0.356 0.189 0.570 0.450 0.543 1.144 0.306 0.800 0.007 0.455 0.303 0.207 0.132 0.535 0.461 0.437 1.358 0.959 0.209 0.459 0.411 0.349 0.161 0.160 0.148 0.352 0.183 0.551 0.434 0.528 1.103 0.304 0.784 0.008 0.436 0.284 0.199 0.136 0.500 0.439 0.419 1.292 0.918 0.200 0.442 0. 393 0.333 0.152 0.149 0.135 0.328 0.175 0.529 0.396 0.489 1.095 0.281 0.722 0. 007 0 .406 0 .254 0.187 0.127 0.560 0.484 0.454 1,388 0.941 0.219 0.466 0.405 0.367 0.142 0.161 0.167 0.361 0.193 0 .578 0.462 0.55.8 1.182 0.302 0 .828 0.007 0. 464 0.309 0.213 0 .126 0.507 0.511 0.469 0.455 0.444 0.443 0. 000#0.000#1.393 1.395 0.976 0.967 0.214 0.210 0.479.0.454 0.410 0.396 0.340 0.343 0.152 0.151 0,157 0.152 0.139 0.145 0.341 0.338 0.173 0.173 0.540 0,547 0.404 0.415 0.501 0.507 1.114 1.117 0.294 0.285 0.747 0.765 0.006 0.007#0.419 0.424 0.252 0.271 0.194§0.191 0.12.9 0.128 5.38 10.25 3.62 5.10 8.43 4.91 14..68 5.64 9.21 4.21 12.10 7.48 6.75 6.76 9.24 7.46 23.59 8.88 5.39 7.49-1.00-1.00 4 .88 4 .59 7.58 5 .07 6.50 4.70 4 .29 7 .59 1. 91 7 .04 12 .39 4.66 8.48 7.70 3.09 9.57 5.18 10.26 6.93 11.97 10.71 5.23 76) I chlorobenzene-d
- 77) M 78)M 79)M 80)M 81)m 82)M 83) M 84) M 85)M tetrachloroethene 1,3-dichloropropa butyl acetate dibromochlorometh 1,2-dibromoethane chlorobenzene 1,1,1,2-tetrachlo ethylbenzene m,p-xylene 5 ----------------
ISTD ---------- 0.337 0.373 0.395 0.387 0.365 0.401 0.368 0.438 0.467 0.450 0.426 0.458 0.097 0.248 0.144 0.137 0.146 0.271 0.312 0.386 0.359 0.332 0.397 0.209 0.250 0.290 0.275 0.263 0.292 0.955 1.000 1.069 1.047 0.989 1.086 0.322 0.391 0.448 0.427 0.405 0.444 1.597 1.624 1.676 1.658 1.575 1.688 0.641 0.657 0.682 0.670 0.631 0.687 0';.3 7 R. 0 376 5.70 0,4'57 0.438 7.68 0.14l. 0.135. .14.05 0,320 0.340 13.05 0.269 0.264 10.73 1.033 1.025 4.56 0.399 0.405 1.051 1.62901. 635 3,&53.650-0:660 3.17 Initial Calibration Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 3 of 3 Sample: V2Cl-]CC001 Lab FilelD: 2C0026.D'V 86)M 87)M 88)M o-xylene styrene bromoform 0.615 0.666 0.844 0.936 0.187 0.709 1.076 0.258 0.687 1.035 0.234 0.659 0.961 0.210 0,712 1.099 0.271 0 .673 0.971 0.198 0.674 0.989 0.227 89) I 1,4-dichlorobenzene-d
--ISTD ---------------------
- 90) M 91)S 92)M 93)M
- 94) M 95)M 96)M 97)M 98)M 99)M 100)m 101)M 102) M 103)M 104) M 105)M 106) M 107) M 108) M 109)M 110) N 111)m 112)M 113) M 114)M 115)M isopropylbenzene 2.479 4-bromofluorobenz 0.830 cyclohexanone bromobenzene 0.772 1,1,2,2-tetrachlo 0.464 trans-l,4-dichlor 1,2,3-trichloropr n-propylbenzene 3.132 2-chlorotoluene 2 .302 4-chlorotoluene 2 .065 1,3,5-trimethylbe 2.357 tert-butylbenzene 1.368 pentachloroethane 0 .373 1,2,4-trimethylbe 2.411 sec-butylbenzene 3 .021 1,3-dichlorobenze 1.618 p-isopropyltoluen
- 2. 711 1,4-dichlorobenze 1.607 1,2-dichlorobenze 1.492 n-butylbenzene 2 .642 1,2-dibromo-3-chl 1,2,4-trichlorobe 1.555 hexachlorobutadie 0.851 naphthalene 2.435 1,2,3-trichlorobe 1.498 hexachloroethane 2.483 0.792 0.806 0.483 3.240 2.316 2.096 2.305 1.437 0.403 2.443 3.070 1.648 2.658 1.691 1.527 2.476 1.415 0.750 2.333 1.285 2.820 0.834 0.030 0.870 0.553 0.145 0.149 3.359 2.356 2.083 2.561 1.521 0.544 2.616 3.354 1.685 2.917 1.704 1.624 2.550 0.110 1.580 0.810 2.593 1.395 0.644 2.747 0.809 0.032 0.844 0.528 0.141 0.144 3.325 2.352 2.070 2.488.484 0.502 2 .553 3.232 1.652 2.810 1 .654 1 565 2.492 0.102 1.444 0.750 2,368 1.288 0.585 2.540 0.804 0.028 0.801 0.500 0 132 0.138 3.158 2.205 1.955 2.313 1.383 0.457 2.393 2. 995 1.547 2.610 1.559 1.475 2.351 0.098 1.391 0. 710 2.292 1.245 0.505 2.809 2.573 0.837 0.826 0.028 0.024 0.861 0.836 0.539 0.508 0.144 0.125 0.143 0.138 3.315 3.286 2.326 2.302 2.082 2.080 2.570 2.348 1.517 1.393 0.552 0.439 2.680 2.444 3.402 3.032 1.702 1.635 3.001 2.631 1.722, 1.621 1.646 1.542 2.630 2.433 0.110 0.108 1.542 1.408 0.790 0.739 2.413 2.327 1.295 1.274 0.681 0.444 2.636 0.819 0.029 0.827 0.511 0.138 0.142 3.259 2.308 2.062 2.420 1.443 0.467 2.506 3.158 1.641 2.762 1.651 1.553 2 .511 0.106 1.476 0.771 2.394 1.326 0.572 4 .92 8.91 14 .85 5 .74 2.11 10.44 4.31 6.21 6.23 3.47 2.65 2 .19 2.33 4.79 4.47 14.71 4 .44 5.36 3.06 5.48 3.56 4.10 4 .18 5.04 5.38 6.24 4.22 6.72 I? .04 Linear regression
.....-Coefficient = 0.9990 Response Ratio = -0.07087 + 0.69292 *A (l) =Out of Range M2CO01.M Thu Dec 02 21:37:01 2004 MS2C G) 34 Continuing Calibration Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 1 of 3 Sample: V2C63-CC001 Lab FilelD: 2C1382.D Evaluate Continuing Calibration Report Data File : C:\MSDCHEM\!\DATA\2CI382.D Acq On 19 Dec 2004 1:22 pm Sample : CCOO-20 Misc MS8372,V2C063,W,.,,, MS Integration Params: rteint.p Vial: 2 Operator: KANYAV Inst : ms2C Multiplr: 1.00 Method Title Last Update Response via Min. RRF Max. RRF Dev C:\MSDCHEM\1\METHODS\M2C001.M (RTE Integrator) SW-846 Method 8260 Thu Nov 18 10:21:14 2004 Multiple Level Calibration 0.010 Min. Rel. Area 50% Max. R.T; Dev 0.50min 20% Max. Rel. Area : 200%Compound 1 2 3 4 5 6 7 8 9 10 11 12 I M M I M M M M M M M M Tert Butyl Alcohol-d9 tertiary butyl alcohol 1,4-dioxane pentafluorobenzene chlorodifluoromethane dichlorodifluoromethane chloromethane vinyl chloride bromomethane chloroethane trichlorofluoromethane ethyl ether AvgRF CCRF 1.000 1.000 0.989 0.998 0.086 0.075 0.0-0.9 12.8 75 -0.03 79 -0.02 69' -0.02 1.000 0.854 0.496 0.623 0.591 0.385 0.289 0.737 0.210 1.000 0,982 0.626 0.685 0.670 0.406 0.313 0.897 0.217 0.0-15.0-26.2#-10.0-13.4-5.5-8.3-21.7#-3.3 79 93 95 90 88 84 83 95 84%Dev Area% Dev(min)R.T.
-0.02-0.01-0.02-0.03-0.02-0.02-0.01-0,01-0.02 8.24 8.38 12.32 10.68 4.22 4.18 4.60 4.90 5.68 5.89 6.42 6..93----------------------- True Calc.13 M acrolein 200.000 1294.533% Drift ------------ -547.3# 709 -0.02 7 .24 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 M M M M M M M M M M M M M M M M----------------------- AvgRF l,l-dichloroethene 0.423 acetone 0.121 allyl chloride 1.412 acetonitrile 0.036 iodomethane 0.825 iso-butyl alcohol 0.005 carbon disulfide 1,480 methylene chloride 0.461 methyl acetate 0.278 methyl tert butyl ether 1.156 trans-i,2-dichloroethene 0.508 di-isopropyl ether 1.692 2-butanone 0.443 1,1-dichioroethane 0.852 chloroprene 0.585 acrylonitrile 0.115 CCRF 0.444 0.098 1.443 0.040 0.941 0 .004#1.450 0.505.0.269 1.160 0.487 1.649 0.443 0.905 0.556 0.134 Calc.21.109 CCRF 1.400 0.039 0.821% Dev-5.0 19.0-2.2-11.1-14.1 20.0 2.0-9.5 3.2-0.3 4.1 2.5 0.0-6.2 5.0-16.5 87 -0.01 7.41 65 -0.03 7.51 87 -0.02 8.03 94 -0.02 8.02 92 -0.02 7.73 77 -0.02 10.97 80 -0.02 7.87 88 -0.02 8.26 77 -0.02 8.03 83 -0.02 8.63 84 -0.02 8.68 80 -0.02 9.29 78 -0.02 10.12 86 -0.02 9..32 76 -0.02 9.'43 93 -0.02 8.65------------------------ True 30 M vinyl acetate 20.000% Drift .- _.-5.5 87 1-0.02 9.31.31 32 33 M M M----------------------- AvgRF ethyl tert-butyl ether 1.461ethyl acetate 0.043 2,2-dichloropropane 0.776% Dev 4.2 9.3-5.8 78 , -0.02 74 .70.,01 87 .02 9.80 0,12 612 Continuing Calibration Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 3 Sample: V2C63-CCOOI Lab FilelD: 2C1382.D 34 35 36 37 38 39 40 41 42 43 44 45 46 47 M M M M M S S M M M M I M M cis-1,2-dichloroethene propionitrile bromochloromethane tetrahydrofuran chloroform dibromofluoromethane (s)1,2-dichloroethane-d4 (s)freon 113 methacrylonitrile 1,1,1-trichioroethane Cyclohexane 1,4-difluorobenzene Di-isobutylene epichlorohydrin 0 .557 0.042 0.243 0 091 0.828 0.438 0.443 0.406 0.233 0.778 0. 723 1.000 0.910 0.019 0.527 0.046 0.263 0.083 0.882 0.457 0.443 0.511 0.212 0.824 0. 678 1.000 0.793 0.018 5.4-9.5-8.2 8.8-6.5-4 .3 0.0-25. 9#9. 0-5.9 6.2 0.0 12.9 5.3 77 92 89 75 87 81 79 96 79 86 76 75 69 75-0.02-0,02-0.02-0.02-0.02-0.02-0.02 0.00-0.02-0.02-0.02-0.02-0.02-0.01 10.13 10.21 10.47 10.52 10.53 10.74 11.17 7 .38 10 .41 10.79 10.85 11.61 11.82 12.84----------------------- True Calc.48 M n-butyl alcohol 1000.000 604.289% Drift ------------ 39.6# 34 -0.02 11.76 49 50 51.52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 carbon tetrachloride .1,l-dichloropropene hexane tert amyl alcohol iso-octane benzene tert-amyl methyl ether heptane isopropyl acetate 1,2-dichlbroethane trichloroethene 2-nitropropane 2-chloroethyl vinyl ether methyl methacrylate 1j2-dichloropropane dibromomethane methylcyclohexane bromodichloromethane cis-1,3-dichloropropene toluene-d8 (s)4-methyl-2-pentanone toluene 3-methyl-l-butanol trans-1,3-dichloropropene ethyl methacrylate 1,1,2-trichloroethane 2-hexanone chlorobenzene-d5 tetrachloroethene 1,3-dichloropropane butyl acetate dibromochloromethane 1,2-dibromoethane chlorobenzene 1,1,1,2-tetrachloroethane ethylbenzene m,p-xylene o-xylene styrene AvgRF 0.511 0.455 0.443 0.000 0. 000 1.395 0.967 0.210 0.454 0.396 0.343 0. 151 0. 152 0.145 0.338 0. 173 0.547 0.415 0.507 1.117 0.285 0.765 0.007 0.424 0.271 0 .191 0.128 1.000 0.376 0.438 0. 135 0.340 0.264 1.025 0.405 1 .635 0.660 0.674 0.989 CCRF 0.598 0.462 0.434 0.o000 0.017 1.304 0.942 0.199 0,439 0.468 0.345 0.145 0.152 0.130 0.334 0.198 0.519 0.444 0.477 1.016 0,270 0.673 0. 006#0.423 0.220 0.192 0.100 1.000 0,384 0.495 0.136 0.388 0.291 1.023 0.451 1. 597 0.635 0.636 0.868% Dev-17.0o-1.5 2.0 0.0 0.0 6.5 2.6 5.2 3.3-18.2-0.6 4.0 0.0 10.3 1.2-14. 5 5.1-7.0 5.9 9.0 5.3 12 0 14 .3 0.2 18.8-0.5 21. 9#0,C)-2.1-13..0-0.7-14.1-10.2 0.2-11.4 2.3 3.8 5.6 12 .2 89 -0.02 10.99 79 -0.02 10.97 77 -0.02 9,01 77 -0.02 11.94 0# -0.19 12.15 75 -0.02 i1.24 77 -0.02 11.27 74 -0.02 11.40 74 -0.02 11.16 89 -0.02 11.26 78 -0.02 11.94 72 -0.01 13.03 76 -0.02 12.70 72 -0.02 12.21 76 -0.02 12.21 85 -0.02 12.36 73 -0.02 12.15 84 -0.02 12.49 7,3 -0.02 12.92 69 -0.02 13.19 72 -0.02 13.01 70 -0.01 13.26 64 -0.02 13.03 78 -0.02 13.45 65 -0.01 13.43 77 -0.02 13.65 59 0.00 13 .82 I M M M M M M M M M M N 68 -0.01 71 -0.02 79' -0.02 67: -0.01 79 -0..02 75' -'0. 02 70 -0. 02 75' -0.02 69 -0.02 68 -0.01 65 -0.02 61 0-0. 01 14 .62 13 .81 13 .,83 13, 87 14 .A8 14.22 14 .64 14 .70 14.69 14 .79 15.18 519 Continuing Calibration Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 3 of 3 Sample: V2C63-CC001 Lab FilelD: 2C1382.D 88 M bromoform 0.227 0.233-2.6 75 -0.02 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 ill 112 113 114 1,4-dichlorobenzene-d4 isopropylbenzene 4-bromofluorobenzene (s)cyclohexanone bromobenzene 1,1,2,2-tetrachloroethane trans-l,4-dichloro-2-bute 1,2,3-trichloropropane n-propylbenzene 2-chlorotoluene 4-chlorotoluene 1,3,5-trimethylbenzene tert-butylbenzene pentachloroethane 1,2,4-trimethylbenzene sec-butylbenzene 1,3-dichlorobenzene p-isopropyltoluene 1,4-dichlorobenzene 1,2-dichlorobenzene n-butylbenzene 1,2-dibromo-3-chioropropa 1,2,4-trichlorobenzene hexachlorobutadiene naphthalene 1,2,3-trichlorobenzene 1.000 2.636 0.819 0.029 0.827 0.511 0.138 0.142 3.259 2.308 2.062 2.420 1.443 0.467 2.506 3.158 1.641 2.762 1.651 1.553 2 .511 0 .106 1.476 0.771 2 .394 1.326 1.000 2.426 0.852 0.026 0.826 0.542 0.099 0. 164 3.115 2 .298 2 .012 2.252 1.431 0.547 2.372 2 .884 1.551 2.520 1.584 1.467 2.339 0.111 1.401 0.757 2.323 1.308 0.0 8.0-4 .0 10.3 0.1-6.1 28 .3#-15.5 4.4 0.4 2.4 6.9 0.8-17.1 5.3 8.7 5.5 8.8 4.1 5.5 6.8-4.7.5 .1 1.8 3 .0 1.4% Drift-3.5 69 66 73 64 71 74 51 82 68 72 71 67 71 82 68 66 69 66 70 68 68 78 69 73 70 72-0.02-0.01-0 .02-0.02-0.01-0.02-0.02-0.02-0.02-0.02-0.01-0.02-0.01-0.02-0.01-0.01-0.01-0.01-0.02-0.02-0.02-0.02-0.02-0.02-0.02-0.02 15.45 16.78 15.49 15.69 13 .03 15.88 15.79 15.82 15.86 15.87 16.02 16 .11 16 .01 16 .34 16.43 16.38 16.54 16 .73 16 .65 16 .80 17 .19 17 .04 17 .96 18.79 18.90 19.08 19.33ýAw 115 M hexachloroethane -True Calc.20.000 20.701 73 -0.01 17.44 (#) = Out of Range 2C0025.D M2COO1.M SPCC's out = 0 CCC's out = 0 Mon Dec 20 08:54:03 2004 MS2C 37 Data File : C:\MSDCHEM\I\DATA\MS2C\2C1396.D Acq On 19 Dec 2004 8:42 pm Sample N85893-1 Misc MS8569,V2C063,W .... I MS Integration Params: rteint.p Q, 't Time: Dec 19 21:07:38 2004 Vial: Operator: Inst Multiplr: 16., .KANYAV ms2C 1.00 Quant Results File: M2C001.RES Alt Method Title Last Update Response via DataAcq Meth C:\MSDCHEM\1\METHODS\M2CO01.M (RTE Integrator) SW-846 Method 8260 Thu Nov 18 10:21:14 2004 Initial Calibration M2CO01 Internal Standards-----------------------------
- 1) Tert Butyl Alcohol-d9
- 4) pentafluorobenzene
- 45) 1,4-difluorobenzene
- 76) chlorobenzene-d5
- 89) 1,4-dichlorobenzene-d4 R.T. QIon Response Conc Units Dev(Min)8.24 10.68 11.61 14.61 16.78 65 168 114 117 152 28847 112901 143489 106439 59636 500.00 50.00 50.00 50.00 50.00 ug/L ug/L ug/L ug/L ug/L-0.03-0.02-0.02-0.02-0.02 System Monitoring Compounds 39) dibromofluoromethane (s) 10.73 Spiked Amount 50.000 Range 79 40) 1,2-dichloroethane-d4 (s) 11.17 Spiked Amount 50.000 Range 68 68) toluene-d8 (s) 13.19 Spiked Amount 50.000 Range 83 91) 4-bromofluorobenzene (s) 15.69 Spiked Amount 50.000 Range 82 113-119 65-129 98-118 95-120 50795 51.33 Recovery 48063 48.00 Recovery =141202 44.04 Recovery =51820 53.07 Recovery =ug/L -0.03 102.66%ug/L -0.02 96.00%ug/L -0.02 88.08%ug/L -0.02 106.14%Target Compounds Qvalue XV,\'44\cv*3 (@) = qualifier out of range (m) manual integration
(+) = signals summed D= - Data File C:\MSDCHEM\I\DATA\MS2C\2CI396.D Vial: 16 Acq On 19 Dec 2004 8:42 pm Operator: KANYAV Sample : N85893-1 Inst : ms2C Misc : MS8569,V2C063,W .... 1 Multiplr; 1.00 MS Integration Params: rteint.p'ant Time: Dec 21 10:57 2004 Quant Results File: M2C00!.RES 'ethod : C:\MSDCHEM\I\METHODS\M2C'001.M (RTE Integrator) Title : SW-846 Method 8260 Last Update :Mon Nov 15 19:32:24 2004 Response via Initial Calibration Abundanice'- ... ...... ..10 2 19 '-270000 260000 250000 240000 230000 22000 0 2 210000 200000 0) 0 190000 C0E'18000 0 170000 9000oý01500o 140000 130000 120000 110000 100000 90000 80 80000 70000 60000 50000 40000 30000 10000~1000 .0[0...rm Time_> 5.00 600 7 0 0 8. 0 g.00 10.00 11.00 12.00 13.00 14.00 1 ..0 17.0-)rl -Qg fl M5Cf1n .W. )l~( r)=4 n~ j fO~ D11O~ Data File C:\MSDCHEM\l\DATA\MS2C\2C!397.D Acq On 19 Dec 2004 9:13 pm Sample N85893-2 Misc MS8569,V2C063,W.... I MS Integration Params: rteint.p Q" 't Time: Dec 19 21:39:06 2004 Vial: 17 Operator: KANYAV inst : ms2C Multiplr; 1.00 Duant Results File: M2COOl.RES o t Method ; C:\MSDCHEM\I\METHODS\M2C00l.M (RTE Integrator) Title : SW-846 Method 8260 Last Update : Thu Nov 18 10:21:14 2004 Response via : Initial Calibration DataAcq Meth : M2C001 Internal Standards-----------------------------
- 1) Tert Butyl Alcohol-d9
- 4) pentafluorobenzene
- 45) 1,4-difluorobenzene
- 76) chlorobenzene-d5
- 89) 1,4-dichlorobenzene-d4 R.T. QIon Response Cone Units Dev(Min)--------------------------------------------
8 .23 10.68 11.61 14.61 16.78 65 168 114 117 152 29612 112704 143678 107329 59647 500.00 50.00 50.00 50.00 50.00 ug/L ug/L ug/L ug/L ug/L-0.04-0.02-0.02-0.02-0.02 System Monitoring Compounds 39) dibromofluoromethane (s) 10.73 Spiked Amount 50.000 Range 79 40) 1,2-dichloroethane-d4 (s) 11.17 Spiked Amount 50.000 Range 68 68) toluene-d8 (s) 13.19 Spiked Amount 50.000 Range 83 91) 4-bromofluorobenzene (s) 15.69 Spiked Amount 50.000 Range 82 113-119 65-129 98 118 95 220 50348 50.96 Recovery =48297 48.31 Recovery 142818 44.49 Recovery =51090 52.32 Recovery =ug/L -0.03 101.92%ug/L -0'. 02 96.62%ug/L -0.02 88.98%ug/L -0.02 104.64%Target Compounds Qvalue S 27 40 (#) = aualifier out of range (m) = manual integration (+) = signals summed')r' I Q 7 T. W ('0 0 1 M In".= 1-~ 1i ii I A 11 f)r)/ --V=-- Data File : C;\MSDCHEM\I\DATA\MS2C\2C!397.D Vial: 17 Acq On : 19 Dec 2004 9:13 pm Operator: KANYAV Sample *N85893-2 Inst : ms2C Misc MS8569,V2C063,W .... 1 Multiplr: 1.00 MS Integration Params: rteint.p Wuant Time: Dec 21 10:57 2004 Quant Results File; M2C001.RES 4'Method : C:\MSDCHEM\I\METHODS\M2C001.M (RTE Integrator) Title : SW-846 Method 8260 Last Update :Mon Nov 15 19:32:24 2004 Response via : Initial Calibration Abndnce TIC10 2C1397.D 260000 250000 240000 230000 220000 210000 200000 190000 2 0 F (1 4.180000 170000 160000 S150000 140000 130000 120000 110000 100000 90000 80000 70000 60000 50000 40000(.0 0 2 E2 2 2 0 I-30000 20000 f 10000 Time- 5.00 -6.00 7.00 8.00 9.00 -'10.00 .1' 1.00' '1'2.'0 '13.00 '1'4.00' '1'5'.0' ' '6!00 17.00 18.00 19.00' ' 0'0'I _ý1 T-)' M' ]v9"). ' r, f) 91 1 1-1 15 1 1 ') n () 9t4 Dr1 Data File C:\MSDCHEM\1\DATA\MS2C\2CI398.D Acq On 19 Dec 2004 9:44 pm Sample : N85893-3 Misc : MS8569,V2C063,W .... 1 MS Integration Params: rteint.p Quint Time: Dec 19 22:10:27 2004 Vial: Operator: Inst Multiplr: 18 KANYAV ms2C 1.00 Quant Results File: M2C001.RES _ it Method Title Last Update Response via DataAcq Meth C:\MSDCHEM\I\METHODS\M2COO1.M (RTE Integrator) SW-846 Method 8260 Thu Nov 18 10:21:14 2004 Initial Calibration M2CO01 Internal Standards R.T. QIon Response Conc Units Dev(Min).......................................................................... 1)4)45)76)89)Tert Butyl Alcohol-d9 pentafluorobenzene 1,4-difluorobenzene chlorobenzene-d5 1,4-dichlorobenzene-d4 8.23 65 10.68 168 11.61 114 14.61 117 16.78 152 29328 112490 143200 106559 60579 500.00 50.00 50.00 50 00 50.00 ug/L ug/L ug/L ug/L ug/L-0.04-0.02-0; 02-0.02-0.02 System Monitoring Compounds 39) dibromofluoromethane (s) 10.73 Spiked Amount 50.000 Range 79 40) 1,2-dichloroethane-d4 (s) 11.17 Spiked Amount 50.000 Range 68 68) toluene-d8 (s) 13.19 Spiked Amount 50.000 Range 83 91) 4-bromofluorobenzene (s) 15.69 Spiked Amount 50.000 Range 82 113-119 65-129 98-118 95-120 50496 51.21 Recovery =48000 48.11 Recovery 143862 44.96 Recovery =51910 52.34 Recovery =ug/L -0.03 102.42%ug/L -0:.02 96.22%ug/L -0.02 89.92%ug/L -0.02 104.68%Target Compounds Qvalue (') = qualifier out of range (m) = manual integration (+) = signals summed n) Q W*T M TAl,, -5ý ?1 1 1
- I A
- I ') 5C) rI4T-42D ~
Data File C:\MSDCHEM\I\DATA\MS2C\2Cl398.D Vial: 18 Acq On : 19 Dec 2004 9:44 pm Operator: KANYAV Sample N85893-3 Inst : ms2C Misc MS8569,V2C063,W, .. Multiplr: 1.00 MS Integration Params; rteint.p Ouant Time: Dec 21 10:57 2004 Quant Results File: M2C001.RES 'Method : C:\MSDCHEM\I\METHODS\M2COOl.M (RTE Integrator) Title SW-846 Method 8260 Last Update :Mon Nov 15 19:32:24 2004 Response via :Initial Calibration ........~~.. ..! ...... .... ..... .. ....................... .... .. .. ... .... bndance TIC: 2C1398.D 270000 260000 2500 240000 230000 220000N 210000 200000 20 190000 E2 1800002 170000 60000%,150ooo 140000 130000 120000 110000 100000 90000 80000 70000 60000 50000 V 40000 30000* -20000 to0000 Ti me- 5 .00 6.00 70 :0 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 180 90 2.0-> ...5.q ....106 ........10 ... .. £ ......18-0.0 19__..0o,.0. ...J#gZ .!L9 ,...! :# ._19# .:o....... ..... .... .... .... .1 ........ I 1 q Q D D Data File C:\MSDCHEM\I\DATA\MS2C\2C1383.D Acq On : 19 Dec 2004 1:53 pm Sample : MBI Misc MS8206,V2C063,W .... I MS Integration Params: rteint.p Quint Time: Dec 19 14:19:29 2004 Vial: Operator: Inst.Multiplr: 3 KA1NYAV Ms2C 1.00 Quant Results File: M2C001.RES T t Method Ti *1e Last Update Response via DataAcq Meth C:\MSDCHEM\I\METHODS\M2C001.M (RTE Integrator) SW-846 Method 8260 Thu Nov 18 10:21:14 2004 Initial Calibration M2CO01 Internal StandardsR.T. QIon Response Conc Units Dev(Min)1) Tert Putyl Alcohol-d9
- 4) pentafluorobenzene
- 45) 1,4-difluorobenzene
- 76) chlorobenzene-d5
- 89) 1,4-dichlorobenzene-d4 8.24 10.68 11.61 14.62 16.78 65 168 114 117 152 27688 107086 134740 100625 56677 500.00 50.00 50.00 50.00 50.00 ug/L ug/L ug/L ug/L ug/L-0.03-0.02-0.02-0.01-0.02 System Monitoring Compounds 39) dibromofluoromethane (s) 10.73 Spiked Amount 50.000 Range 79 40), 1,2-dichloroethane-d4 (s) 11.17 Spiked Amount 50.000 Range 68 68) toluene-d8 (s) 13.19 Spiked Amount 50.000 Range 83 91) 4-bromofluorobenzene (s) 15.69 Spiked Amount 50.000 Range 82 113-119 65-129 98-118 95-120 47749 50.87 Recovery =46643 49.11 Recovery =133001 44.18 Recovery 48839 52.63 Recovery =ug/L -0.03 101.74%ug/L -0.02 98.22%ug/L -0.02 88.36%ug/L -0.02 105.26%Target Compounds Qvalue w 44 (#t) = qualifier out of range (m) = manual integration
(+) = signals summed 9t)(1 'qp,4 ,") w rnni"1 " "' v, i ' )l m -- Data Pile C:\MSDCHEM\l\DATA\MS2C\2C1383.D Vial: 3 Acq On : 19 Dec 2004 1:53 pm Operator: KANYAV Sample : MBI Inst : ms2C Misc : MS8206,V2C063,W-, .1 Multiplr: 1.00 MS Integration Params: rteint.p ,ant Time: Dec 21 10:50 2004 Quant Results File: M2C001.RESethod : C:\MSDCHEM\IkMETHODS\M2C001.M (RTE Integrator) Title : SW-846 Method 8260 Last Update :Mon Nov 15 19:32:24 2004 Response via : Initial Calibration 250000 240000 230000 220000 210000 200000 .C w 190OO E 180000.2 170000 160000 50000 140000 130000 120000 110000 100000 V 90000 80000 70000 60000 50000 -40000 30000 20000 40100001 Time-- 5.00 6.00 7.00 8.00 9.00 1 1 10 1 1300 14.00 15.00 100 0 17.00 18.00 19.00 20.00"Time--> 5,0 8.0 rv .,'-,0 --l 'A ".00 )0 (3 12q" Oý .,,-, Data File Acq On Sample C:\MSDCHEM\l\DATA\MS2C\2CI383.D 19 Dec 2004 1:53 pm MBI Vial: 3 Operator: KANYAV Inst : ms2C Multiplr: 1.00 Misc : MS8206,V2C063,W .... 1 MS Integration Params: LSCINT.P e Smoothing Sampling Start Thrs: Stop Thrs : C:.\MSDCHEM\I\METHODS\M2C001.M (RTE Integrator) SW-846 Method 8260 ON Filtering: 5 1 Min Area: 100 0.1 Max Peaks: 100 0.1 Peak Location: TOP Area counts If leading or trailing edge < 100 prefer < Baseline drop else tangent >Peak separation: 5 Signa2 : TIC)eak R.T. first# min scan 1 4.216 2 4.441 3 4.535 4 4.567 5 4.583 6 4.609 7 4.719 8 4.845 9 4.881.0 5.023.1 5.081 5 .138 3 5 .186.4 5.275.5 5.317.6 5.401.7 5.432.8 5.484.9 5.521!0 5.563!1 5.642!2 5,715!3 5.794 i4 5.883!5 5.925!6 5.988!7 6.087'8 6.140ý9 6.239 0. 6.323 1 6.376.2 6.439;3 7 .078;4 7.183 5& 7.330 16 64 78 88 95 100 114 143 149 178 188 199 210 223 235 247 257 266 274 280 293 310 323 343 351 361 381 387 410 425 434 445 567 590 613 max scan 26 69 87 93 96 101 122 146 153 180 191 202 211 228 236 252 258 268 275 283 298 312 327 344 352 364 383 393 412 428 438 450 572 592 620 last scan 43 78 88 95 100 107 124 149 172 188 199 206 223 233 242 257 266 274 280 293 304 323 333 351 359 366 387 398 425 434 445 468 578 613 623 PK TY rVB3 rBV2 rBV2 rVV3 rVV3 rVV3 rBV2 rVB3 rBV2 rVB2 rBV4 rVB2 rBV3 rVB2 rVB rVB3 rBV3 rVV2 rVV3 rVV4 rVV3 rVV3 rVB3 rVB2 rVB2 rBV2 rVB rBV3 rVB2 rVV2 rVV2 rVV3 rBV3 rVV3 rVV2 peak height 485 379 469 550 531 467 392 732 724 473 568 401 509 434 492 446 468 442 573 550 499 446 464 612 682 550 603 646 479 410 381 391 434 347 440 corr.area 2319 1118 817 764 667 785 735 549 2545 770 1150 500 1023 513 606 862 881 601 536 1168 908 970 875 603 714 577 645 1027 945 639 668 1359 650 1282 745 corr.% max.0.67%0.32%0.24%0.22%0.19%0.23%0.21%0.16%0.74%0.22%0.33%0.15%0.30%0.15%0.18%0.25%0.26%0.17%0.16%0.34%0.26%0.28%0.25%0.17%0.21%0.17%0.19%0.30%0.27%0.19%0.19%0.39%0.19%0.37%0.22%% of total 0.094%0.045%0.033%0.031%0.027%0.032%0.030%0.022%0.103%0.031%0.046%0.020%0.041%0.021%0.024%0.035%0.036%0.024%0.022%0.047%0.037%0.039%0.035%0.024%0.029%0.023%-0.026%0.042%0.038%0.026%0.027%0.055%0.026%0.052%0.030%0.034%0.022%0.023%7.351 7.424?.482 623 624 633 rVB2 636 638 645 rVB 645 649 651 .rVE 469 336 605 852 0.25%539 0.16%571 0.17%.ýt I -*,I ý P I n v,.1rnn1 'N.P *0M I U I.:Dn bbZ t b.5 bbb r3v z qjl U.14ý. U.Ueulo 1 7.597 2 7.639 3 7.707 4 8.012 5 8.090 Av8,153 7 8.237 8 8.515 9 8.588 0 8.614 1 8.683 2 8.756 3 8.814 4 8.898 5 8.940 6 9.034 7 9.128 8 9.186 9 9.254 0 9.333 1 9.453 2 9.511 3 9.637 4 9 .763 5 9 .862 6 10.282 7 10.675 8 0 .733 Al 0.832 0.879 668 678 691 745 762 774 782 845 853 863 876 890 900 917 926 944 960 973 978 1000 1023 1035 1056 1079 1098 1179 1247 1264 1286 1296 1306 1313 1327 1341 1427 1728 1769 2001 2207 2353 2373 2415 2502 2639 2699 2706 2732 2744 2759 2774 2806 2815 2832 2859 2871 671 679 692 750 765 777 793 846 860 865 878 892 903 919 927 945 963 974 987 1002 1025 1036 1060 1084 1103 1183 1258 1269 1288 1297 1311 1314 1330 1352 1436 1737 1773 2009 2215 2359 2376 2423 2504 2657 2702 2713 2735 2746 2767 2780 678 rVV2 687 rVV 696 rVB 762 rVB 770 rBV2 782 rBV2 826 rBV 853 rVB 863 rBV2 876 rVB2 884 rBV2 900 rVV 917 rVV2 926 rVV2 933 rVB 954 rVV2 966 rVB2 978 rVB2 989 rBV2 1013 rVB2 1030 rBV2 1043 rBV2 1065 rVV 1092 rVV 1107 rVB 1196 rVV 1264 rVV 1286 rVV 1296 rVV 1306.rVV 1313 rVV 1327 rVV 1337 rVV 1368 rVB 1452 rBB 1751 rBB 1778 rBB 2023 rBB 2227 rBB 2363 rBB 2382 rVB 2437 rVV 2510 rVV2 2661 rBV 2706 rBV2 2719 rVV2 2744 rVV 2753 rBV 2769 rBV2 2787 rBV3 486 454 593 390 577 392 12213 602 457 391 255 325 469 412 439 628 451 459 557 391 348 476 423 273 327 239 116082 67730 234 285 268 283 262 57843 146841 201681 365 182928 163900 261 277 215679 390 242 389 290 379 224 468 426 816 725 572 660 618 604 51774 849 898 790 466 626 1158 771 567 880 519 475 1050.705 502 742 590 558 491 584 258981 153632 553 623 472 815 544 122653 289149 344681 567 294281 243378 506 596 326878 627 656 545 784 669 466 842 1044 0.24%0.21%0.17%0.19%0.18%0.18%15.02%0.25%0.26%0.23%0.14%0.18%0.34%0.22%0.16%0.26%0.15%0.14%0.30%0.20%0.15%0.22%0.17%0.16%0.14%0.17%75.14%44.57%0 .16%0.18%0.14%0.24%0.16%35.58%83 .89%100.00%0.16%85.38%70.61%0,15%0.17%94.83%0.18%0.19%0.16%0.23%0.19%0.14%0.24%0.30%0.033%0.029%0.023%0.027%0.025%0.024%2.093%0.034%0.036%0.032%0.019%0.025%0.047%0.031%0.023%0.036%0.021%0.019% 0.042%0.028%0 .020%0.030%0.024%0.023%0.020%0.024%10.467%6.209%0.022%0.0.25%0 .019%0.033%0.022%4.957%11.686%13.931%0.023%11 .894%9.836%0.020%0.024%13.211%0.025%0.027%0.022%0. 032%0.027%0.019%0.034%0.042%10.953 10.969 11.053 11.168 11.608 13.186 13.375 14.613 15.693 16.448 16.537 16.783 17.208 18.010 18 .246 18. 304 18. 419 18.477 18.587 18.655 1 8.807 2408 849 3 19 064 4 19 .080 5 19 .184 2809 2817 2858 2861 2881 2812 2825 2859 2871 2885 rBV2 rBV2 rBV2 rBV3 rB8V4 564 370 832 682 564 470 796 4182 1250 1462 0.14%0.23%1.21%0,36%0.42%0.019%0.032% 0.169%0.051%0.059%.471 -1 p -Z n virnni m ,P,, r&9),fl 914 in R -p g nzP9 Vp-m ? 6 19.258 2885 2895 2897 rBV3 899 1529 0.44% 0.062% 7 19.368 2905 2916 2919 rBV5 765 1917 0.56% 0.077%8 19.415 2919 2925 2929 rBV5 491 998 0.29% 0.040%9 19.787 2929 2996 3006 rBV4 2729 32174 9.33% 1.300%10 20.894 3021 3207 3216 rBV5 9266 281937 81.80% 11,395%Sum of corrected areas: 2474250 i'1 I I -ý q 'ý T) 74, 1) r n n I V, ITh I~Cfn ý 1) , ) 10- -ýp ?)1:DrpI LSC Report -Integrated Chromatogram File Operator KANYAV Acquired 19 Dec 2004 1:53 pm using AcqMethod M2C001*strument ms2C.nple Name: MBl sc Info : MSS.206,V2C063,W ... " Vial Number: 3 Quant File :m2C001.RES (RTE Integrator) 200000 150000 1 0000G 500OG 0 Mme-8.24 4.50 5.00 55I 6. 00 6.50 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50 Abundance 200000 T1C: 2C1383.D 13.19 14.61 10D000 50000]11.61 10.68.73 J.M86 10.28 MWý 13.38 Mine-->n 10.00 10.50 11.00 11.50 ý12.00 12.50 13.00 13.50 14,00 14.50 15.00:Abundance 200000 150000 0C: 2C1383.D 78 15.69 100000 50000 20.8!18.01 9 1 1614554 i 17.21 1614B54 I I I I lssn.I , , , , I ' ' I I I ..I ' --ý , ; ý i ..ý9 1 ...; i 4 , k , 16.00 1E50 17.00 17.50 18.00 18.50 1 .00 19,50 20.00 20.50 TIME--> 1550 I P I " M " (I n" n I "V-". T)-- ?I lnýqn-qq )nnA PDrl'D=-.- A . Data File : C:\MSDCHEM\I\DATA\MS2C\2CI383.D ,cq On 19 Dec 2004 1:53 pm 3ample : MB1'disc MS8206,V2C063,W .... I'S Integration Params: LSCINT.P Vial: 3 Operator: KANYAV Inst : ms2C Multiplr: 1.00 Method C:\MSDCHEM\1\METHODS\M2C001.M (RTE Integrator)
- SW-846 Method 8260 Library : C:\DATABASE\NBS75K.L Peak Number 1 2-Methyl-7-phenylindole Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T.---------------------------------------------------------------------
20.89 43.13 ug/L 281937 l,4-dichlorobenzene-d4 16.78 Hit4 of 5 Tentative ID MW MolForm CAS# Qual--------------------------------- 1 2-Methyl-7-phenylindole 207 C15H13N 000000-00-0 59 2 3-Methyl-2-phenylindole 207 C15H13N 010257-92-8 42 3 CycJotrisiloxane, hexamethyl-222 C6H18O3Si3 000541-05-9 40 4 Cyclotrisiloxane, hexamethyl-222 C6H18O3Si3 000541-05-9 38 Abnac ...*...S canozo (20 ~.894 min): 2t-138.'D. (-302)2(7 5000 191 96 119 133 147 163 177 1 253 ,,, ' .... .. .. H/z--> 20 40 60 80 100 120 140 160 180 200 220 240 Abundance
- 24652: 2-Methyl-7-phenylindole 207 5000 30 102 165178191 C7 I8 I 1 I m/z--> 20 40 60 80 100 120 140 160 180 200 220 240 Abunance#24653:
3-Methyl-2-phenylindole 2 7 5000 130 77 102 178 mtz--_ 20 40 60 80 100 120 140 160 180 200 220 240 Abundance
- 70.586: Cycot isilxane, hexanmethyl-207 5000 m/z 207.00 100.00%i j nlz 208.0 22 .09%e 20.5020.6020.7020.8020.90 m/z 209.00 11.92s.20.5020.6020.7020.8020.90 m/z 191.00 11 .74%20.5020.6020.7020.8020 90 rnm/z 96.00 7.95%!20.5020.6020, 7020. 8020.90 96 133 191 75 I 1 19 1 1 4 7 163 177 20406080100120 140l 160 .180 200'220...240.
20 _409_ 60__ _ 8._.o_.., 1o..,!20 ,,_4 0_. 1 0. 2 0 2_2.0 2_£ ? o_ 40....'3 50 perator ID: KANYAV Date Acquired: 19 Dec 2004 1:53 pm ata File: C:\MSDCHEM\I\DATA\MS2C\2CI383.D ame: MBI.isc: MS8206,V2C063,W .... 1-ethod: C: \MSDCHEM\I\METHODS\M2COO1,M (RTE Integrator) itae: SW-846 Method 8260 ii -y Searched: C:\DATABASE\NBS75K.L I--Internal Standard---I TIC Top Hit name RT EstConc Units Response I# RT Resp Concl...........................................................................-Methyl-7-phenyl... 20.89 43.1 ug/L 281937 5 16.78 326878 50.0 I r- -, -Z P -4 7-. w") r, r) r) 1 V, M, ý .n. ý -') 1 1 n -Cý () -4 r) 1) () f) A 10D rP I SEMI-VOLATILE f'i 52 ACCUTEST~. GCUMS Analysis Case Narrative/Conformance/Non-Conformance Summary Fraction -36 NO-,E 1. Chroniatograms Labeled/Compounds Identified (Field Samples and Method Blanks)2. GC(MS Tune Meet Criteria 3. GC/MS Tuning Frequency -Performed every 24 hours for 600 series and 12 hours for 8000 series.4. GC/MS Calibraon -Initial and.Continuing Calibration Meet Method Requirements ___,/ " 5. GC/MS Calibration Requirements
- a. Calibration Check Compounds b. System Performance Check Compounds 6. Blank Contamination
'___'_.______.f yes, the samplexresult is -qualofied with a "B'".7. Surrogate Recoyeries Meet Criteria ._*If the requirement is not met, refer to the Surrogate Summary for comment.8. Matrix Spike/Matrix Spike Duplicate Recoveries.Meet Criteria _ef the requirement is not met, refer to MSIMSD Summary for comment.9. Internal Standard Area/Retention Time Shift Meet Criteria _._If the requirement is not met, refer to the Internal Standard Summary for comment.10. Extraction Holding Time Met "_If the holding time is not met, refer to the Sample Result page for comment.11. Analysis Holding Time Met __"____If the holding time is not met, refer to the Sample .Resultpagefor comment.12. Volatile Sample Preservation -ph should be < 2. List any non-compliant samples below: Additional Comments: QC Reviewv Signatbre: ff QA .A-r Date:___________________ Form: RG04 53 Rev. Date: 2/9100 Method Blank Summary Job Number; N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page I of 3 Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OPI9011-MBl F46968.D 1 12/15/04 NAP 12/14/04 OP19011 EF2492 The QC reported here applies to the following samples: Method: SW846 8270C N85893-1, N85893-2 CAS No. Compound Result RL MDL Units Q 95-57-8 59-50-7 120-83-2 105-67-9 51-28-5 534-52-1 95-48-7 88-75-5 100-02-7 87-86-5 108-95-2 95-95-4 88-06-2 83-32-9 208-96-8 120-12-7 56-55-3 50-32-8 205-99-2 191-24-2 207-08-9 101-55-3 85-68-7 91-58-7 106-47-8 86-74-8 218-01-9 111-91-1 111-44-4 108-60-1 7005-72-3 95-50-1 54J-73-1 106-46-7 121-14-2 2-Chlorophenol 4-Chloro-3-methyl phenol 2,4-Dichiorophenol 2,4-Dimethylphenol 2,4-Dinitrophenol 4,6-Dinitro-o-cresol 2-M ethylphenol 3&4-Methylphenol 2-Nitrophenol 4-Nitrophenol Pentachiorophenol Phenol 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol Acenaphthene Acenaphthylene Anthracene
Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,hi)perylene Benzo(k)fluoranthene 4-Bromophenyl phenyl etherButyl benzyl phthalate 2-Chloronaphthalene 4-Chloroaniline Carbazole Chrysene bis(2-Chi oroethoxy)methane bis(2-Chl oroethyl)ether bis(2-Chloroisopropyl)ether 4-Chlorophenyl phenyl ether 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 2,4-Dinitrotoluene ND 5.0 4.3 ND 5.0 4.7 ND 5.0 0.73 ND. .: 5.0 1.0 ND 20 1.1 N)D 20 0.65 ND.:"': 5.0 0,72ýND 5.0 0.70 ND 5.0 0.73 ND. .20 2.3 ND 20 0.75:ND 5.0 1.8 ND 5.0 0.74 ND) 5.0 0.80 ND -.2.0 0.30.ND .2.0 0.35 ND. 2.0 0.22 ND. 2.0 0.27 ND. 2.0 0.38 ND.. 2.0 0.37 ND 2.0 0.50 ND 2.0 0.37 ND 2.0 0.54 ND 2.0 0.54 ND 5.0 0.38 ND 5.0 0.43 ND 2.0 0.34 ND 2.0 0.26 ND. 2.0 0.34 ND 2.0 0.49 ND- 2.0 0.44.ND 2.0 1.0 ND, 2.0 0,24 ND. 2.0 0.32 ND 2.0 0.25 ND 2.0 0.78 ug/I ug/1 ug/l ug/]ug/l ug/1 ug/t ug/1 ug/l ug/1 ug/1 ug/h ug/I ug/l ug/h ug/1 ug/l ug/l ug/]ug/l ug/]ug/h ug/l ug/l ug/l ug/l ughl ug/1 ug/l ug/]ug/]ug/]ug/l ug/h ug/I ug/1 54 Method Blank Summary Page 2 of 3 Job Number: N85893Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OP19011-MB1 F46968.D 1 12/15/04 NAP 12/14/04 OP19011 EF2492 The QC reported here applies to the following samples: Method: SW846 8270C N85893-1, N85893-2 CAS No. Compound Result RL MDL Units Q 606-20-2 2,6-Dinitrotoluene ýND]:: 2.0 0.62 ug/h 91-94-1 3,3'-Dichlorobenzidine ND 5.0 0.39 ug/]53-70-3 Dibenzo(a,h)anthracene ND 2.0 0.58 ug/l 132-64-9 Dibenzofuran ND 5.0 0.49 ug/1 84-74-2 Di-n-butyl phthalate ND:" 2.0 0.79 ug/l 117-84-0 Di-n-octyl phthalate ND 2.0 0.63 ug/l84-66-2 Diethyl phthalate ND 2.0 1.4 ugh]131-11-3 Dimethyl phthalate N.D. 2.0 0.58 ug/l 117-81-7 bis(2-Ethylhexyl)phthalate ND .2.0 0.74 ug/]206-44-0 Fluoranihene ND 2.0 0.63 ugh/86-73-7 Fluorene ND 2.0 0.89 ug/]118-74-1 Hexachlorobenzene
- ND. 2.0 1.2 ug/]87-68-3 Hlexachlorobutadiene ND 2.0 0.41 ug/1 77-47-4 Ilexachlorocyclopeniadiene ND 20 0,45 ugh]67-72-1 Hexachloroethane
- N:D 5.0 0.67 ug/1 193-39-5 Indeno(1,2,3-cd)pyrene
- ND2.0 1.5 ug/h 78-59-1 Isophorone .N.ID :2.0 0.54 ug/]91-57-6 2-Methylnaphihalene -ND: ...2.0 0.72 ug/1 88-74-4 2-Nitroaniline ND 5.0 1.4 ug/]99-09-2 3-Nitroaniline ND :5.0 1.2 ug/]100-01-6 4-Nitroaniline ND. 5.0 1.1 ug/191-20-3 Naphthalene ND. 2.0 1.0 ugh]98-95-3 Nitrobenzene ND 2.0 0.61 ug/]621-64-7 N-Nitroso-di-n-propylamine ND 2,0 0.50 ug/l 86-30-6 N-Nitrosodiphenylamine ND .5.0 0.80 ug/]85-01-8 Phenanthrene ND 2.0 0.23 ug/1 129-00-0 Pyrene ND ::2.0 0.58 ug/l 120-82-1 1,2,4-Trichlorobenzene ND 2.0 0.32 ug/l CAS No. Surrogate Recoveries Limits 367-12-4 2-Fluorophenol 37.% 10-88%4165-62-2 Phenol-d5 31% 10-71%118-79-6 2,4,6-Tribromophenol 72.% 45-134%4165-60-0 Nitrobenzene-d5
'70.1% 32-128 %55 Method Blank Summary Job Number: N85893Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 3 of 3 I&Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OP19011-MBI F46968.D 1 12/15/04 NAP 12/14/04 OP19011 EF2492 The QC reported here applies to the following samples:N85893-1, N85893-2 CAS No. Surrogate Recoveries Limits Method: SW846 8270C 321-60-8 2-Fluorobiphenyl1718-51-0 Terphenyl-d14 69% 34-121%:83% 41-129%CAS No. Tentatively Identified Compounds system artifact/aldol-condensation Total: TIC, Semi-Volatile. R.T.4.05 Est. Conc. Units Q 4W;4 ugh ug/1 J.56 Blank Spike Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page I of 3 Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OP19011-BSI F47332.D 1 01/04/05 NAP 12/14/04 OP19011 EF2504 The QC reported here applies to the following samples: Method: SW846 8270C N85893-1, N85893-2 CAS No. Compound ,95-57-8 59-50-7 120-83-2 105-67-9 51-28-5 534-52-1 95-48-7 88-75-5 100-02-7 87-86-5 108-95-2 95-95-4 88-06-2 83-32-9 208-96-8 120-12-7 56-55-3 50-32-8 205-99-2 191-24-2 207-08-9 101-55-3 85-68-7 91-58-7 106-47-8 86-74-8 218-01-9 111-91-1 111-44-4 108-60-1 7005-72-3 95-50-1 541-73-1 106-46-7 2-Chlorophenol 4-Chloro-3-metbyl phenol 2,4-Dichlorophenol 2,4-Dimeihylphenol 2,4-Dinitrophenol 4,6-Dinitro-o-cresol 2-Meihylphenol 3&4-Methylphenol 2-Nitrophenol 4-Nitrophenol Pentachlorophenol Phenol 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol Acenaphibhene Acenaphthylene. Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene 4-Bromophenyl phenyl ether Butyl benzyl phthalate 2-Chloronaphthalene 4-Chloroaniline Carbazole Chrysene bis(2-Chloroethoxy)methane bis(2-Chloroethyl)ether bis(2-Chloroisopropyl)ether 4-Chloropheny) phenyl ether 1,2-Dichlorobenzene 1,3-Dichlorobenzene
1,4-Dichlorobenzene Spike BSP BSP ug/! ug/l % Limits 50 36.4 73 49-101 50 42.7 :85- 52-111 50 41.4 83'.- 54-110 50 39.0 78.: 40-108 100 83.6 8-. 32-129 50 46.8 .94 49-125 50 29.0 '58 .40-98 50 26.3 :ý53:: :: 32-97 50 44.7 89. 50-112 50 12.5 -25 1-88 50 39.6 .79 37-121 50 14.8 3. 1-84 50 42.1 84. 57-118 50 40.6 8-1; 55-114 50 38.4 77 *.i 53-109 50 35.7 71. 48-101 50 40.9 82.:.- 61-113 50 41.5 " 62-115 50 42.3 8:5 60-118 50 48.2 .96; 58-122 50 34.0 68:.., 52-131 50 39.9 80 51-131 50 43.8 .88 57-115 50 44.4 89 61-124 50 38.2 76 50-109 50 32.3 65. 27-115 50 44.1 88 60-133 50 41.0 82.2 61-118 50 42.0 :84If. 50-115 50 41.8 84. 45-113 50 41.1 82 46-109 50 42.3 :85.,- 54-115 50 39.1 78.. 41-106 50 36.9 74 38-102 50 38.2 76 39-103 50 45.4 91. 62-118 121-14-2 2,4-Dinitrotoluene 0 57 Blank Spike Summary Page 2 of 3 Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OP19011-BSI F47332.D 1 01/04/05 NAP 12/14/04 OP19011 EF2504 The QC reported here applies to the following samples: Method: SW846 8270C N85893-1, N85893-2 Spike BSP BSP CAS No. Compound ug/I ug/1 % Limits 606-20-2 2,6-Dinitrotoluene 50 45.0 90. ...57-118 91-94-1 3,3'-Dichlorobenzidine 50 41.5 -83:... 39-131 53-70-3 Dibenzo(a,h)anthracene 50 36.5 '73 53-130 132-64-9 Dibenzofuran 50 40.4 81. 55-115 84-74-2 Di-n-butyl phthalate 50 48.1 96 61-125 117-84-0 Di-n-octyl phthalate 50 55.6 111 55-140 84-66m2 Diethyl phihalate 50 44.7 89 57-118 131-11-3 Dimethyl phthalate 50 43.8 88 45-123 117-81-7 bis(2-Ethylhexyl)phthalate 50 47.2 94 57-128 206-44-0 FRuoranthene 50 43.5 87 60-122 86-73-7 Fluorene 50 42.0 -.84ý. 54-112 118-74-1 Hexachlorobenzene 50 44.1 88 58-114 87-68-3 Hexachlorobutadiene 50 41.8 84 41-116 77-47-4 H exachlorocyclopentadiene 100 62.4 62 19-107 67-72-1 Hexachloroethane 50 40.2 :806'..- -J 36-104 193-39-5 ]ndeno(1,2,3-cd)pyrene 50 36.7 :'73".:. 52-131 78-59-1 Isophorone 50 42.3 :8.5 46-113 91-57-6 2-Methylnaphthalene 50 40.3 81 47-109 88-74-4 2-Nitroaniline 50 47.1 94 53-122 99-09-2 3-Nitroaniline 50 38.6 77 43-127 100-01-6 4-Nitroaniline 50 44.3 895 47-140 91-20-3 Naphthalene 50 38.3 77 44-105 98-95-3 Nitrobenzene 50 39.9 801.: 46-108 621-64-7 N-Nitroso-di-n-propylamine 50 42.5 :85 50-117 86-30-6 N-Nitrosodiphenylamine 50 39.9 :80: 60-121 85-01-8 Phenanthrene 50 39.6 79 59-110 129-00-0 Pyrene 50 39.4 79:* 60-115 120-82-1 1,2,4-Trichlorobenzene 50 39.6 79 44-103 CAS No. Surrogate Recoveries BSP Limits 367-12-4 2-Fluorophenol 35% 10-88%4165-62-2 Phenol-d5 22% 10-71%118-79-6 2,4,6-Tribromophenol 88:% 45-134%4165-60-0 Nitrobenzene-d5 76% 32-128%qh, Blank Spike Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 3 of 3 Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OP19011-BSI F47332.D 1 01/04/05 NAP 12/14/04 OP19011 EF2504 The QC reported here applies to the following samples: Method: SW846 8270C N85893-1, N85893-2 CAS No. Surrogate Recoveries 321-60-8 2-Fluorobiphenyl 1718-51-0 Terphenyl-d]4 BSP Limits 7..1%. 34-121%76%* 41-129%0" 5U Matrix Spike/Matrix Spike Duplicate Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page ) of 3 6F Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OP19011-MS F47334.D 1 01104105 NAP 12/14/04 OP19011 EF2504 OP19011-MSD F47335.D 1 01/04/05 NAP 12/14/04 OP19011 EF2504 N85706-1 F47333.D 1 01/04/05 NAP 12/14/04 OP19011 EF2504 The QC reported here applies to the following samples: Method: SW846 8270CN85893-1, N85893-2 CAS No. Compound N85706-1 Spike ug/I Q ug/l MS MS MSD MSD ug/l % ug/l %Limits RPD Rec/RPD#0 95-57-8 2-Chlorophenol ND 59-50-7 4-Chloro-3-methyl phenol ND 120-83-2 2,4-Dichlorophenol ND 105-67-9 2,4-Dimethylphenol ND 51-28-5 2,4-Dinitrophenol ND 534-52-1 .4,6-Dinitro-o-cresol ND 95-48-7 2-Methylphenol ND 3&4-Methylphenol ND 88-75-5 2-Nitrophenol ND 100-02-7 4-Nitrophenol ND 87-86-5 Pentachlorophenol ND108-95-2 Phenol ND 95-95-4 2,4,5-Trichlorophenol ND 88-06-2 2,4,6-Trichlorophenol ND 83-32-9 Acenaphthene ND 208-96-8 Acenaphihylene ND120-12-7 Anthracene ND56-55-3 Benzo(a)anthracene ND50-32-8 Benzo(a)pyrene ND 205-99-2 Benzo(b)fluoranthene ND 191-24-2 Benzo(g,hi)perylene ND 207-08-9 Benzo(k)fluoranthene ND 101-55-3 4-Bromophenyl phenyl ether ND 85-68-7 Butyl benzy] phihalate ND 91-58-7 2-Chloronaphthalene ND 106-47-8 4-Chloroaniline ND 86-74-8 Carbazole ND 218-01-9 Chrysene ND 111-91-1 bis(2-Chloroethoxy)methane NDI i 1-44-4 bis(2-Chloroethyl)ether ND 108-60-3 bis(2-Chloroisopropyl)ether ND 7005-72-3 4-Chlorophenyl phenyl ether ND 95-50-1 1,2-Dichlorobenzene ND 541-73-1 1,3-Dichlorobenzene ND 106-46-7 1,4-Dichlorobenzene ND 121-14-2 2,4-Dinitrotoluene ND 100 1oo 100 100 200 100 100 100 100 100 100 100 100 100 100 1oo 100 100 100 100 lOO 100 100 100 100 100 100 100 100 1oo 100 100 lOO 1oo 100 100 88.7 89 84.7 85 .5: 117/28 103 103 97.4 _97 6 36-129/25 96.2 96 92.0 :92 -4 .37-124/27 94.1 94;.. 89.9 90. 5..28-121/28 207 ;104 198 99 4 8-144132 113 .11:3 105 105. 7 24-142/29 78.5 79 74.3 ::74. 5 30-114/28 73.8 i.74 : 71.3 '71...: 21-122/28 103 103 98.4 .98:1. 5 34-123127 51.4 51 49.7 50 3 1-129/33 97.4 97 89.1 89 9 36-143/24 51.0 .51 48.4 48: 5 1-102/32 99.8 100 95.0 95 .5 41-131/24 96.6 97 92.6 '93ý 4 43-121125 90.1 90. 86.0 8'6 ' 40-114/30 83.5 84 80.0 80. .4 36-106/31 96.0 -96 89.6 90 7 54-119/23 98.9 99. 94.7 95 .4. 57-122/22 102 102 96,7 97 5 53-126/23 118 .11:8 113 113 4 .50-135/26 80.3 80 76.7 :77 5- 35-141129 97.0 97 90.7 91 7 37-144/24 103 103 94.7 .95 8 49-121/25107 107 102 102 5 56-132/23 89,9 90 86.1 86 4 34-115/30 68.8 69 66.5. -67* 3 10-108/37 104 104 96.4 96 8 49-146/22 98.4 98 94.1 94 '4 55-125/23 95.2 .9.5 90.9 9.1 5 37-119/32 95.5 96 91.1 9.1 5 32-122/37 94.1 -94 88.9 ..89 .6 34-112/32 98.7 .99 94.2- 94 5. 43-118/27 89.6 :90 86.2 ' 86 4 31-110/31 84.7 85 81 :6.: :82 .4 27-107/32 87,8 88 84.9 .85 3 29-108/31 108 :1-08 102 102 6 50-125/31 kv U 60 Matrix Spike/Matrix Spike Duplicate Summary Job Number: N85893 Page 2 of 3 Account: Project: AGMPAL Arcadis Geraghty & Miller PSEG-Salem, Artificial Island, Salem, NJ'V, Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OP19011-MS F47334.D 1 01/04105 NAP 12/14/04 OP19011 EF2504 OP19011-MSD F47335.D 1 01/04/05 NAP 12/14/04 OP19011 EF2504 N85706-1 F47333.D 1 01/04/05 NAP 12/14/04 OP19011 EF2504 The QC reported here applies to the following samples: Method: SW846 8270C N85893-1, N85893-2 CAS No. Compound N85706-1 Spike ug/! Q ug/I MS MS MSD MSD ug/I % ug/i %Limits RPD Rec/RPD 606-20-2 2,6-Dinitrotoluene 91-94-1 3,3'-Dichlorobenzidine 53-70-3 Dibenzo(a,h)anthracene 132-64-9 Dibenzofuran 84-74-2 Di-n-butyl phthalate 117-84-0 Di-n-octyl phthalate 84-66-2 Diethyl phthalate 131-11-3 Dimethyl phthalate 117-81-7 bis(2-Ethylhexyl)phthalaie 206-44-0 Fluoranthene 86-73-7 Fluorene 118-74-1 Hexachlorobenzene 87-68-3 Hexachlorobutadiene77-47-4 Hexachlorocyclopentadiene 67-72-1 Hexachloroethane 193-39-5 lndeno(1,2,3-cd)pyrene 78-59-1 Isophorone91-57-6 2-Methylnaphthalene 88-74-4 2-Nitroaniline 99-09-2 3-Nitroaniline 100-01-6 4-Nitroaniline 91-20-3 Naphthalene 98-95-3 Nitrobenzene 621-64-7 N-Nitroso-di-n-propylamine86-30-6 N-Nitrosodiphenylamine85-01-8 Phenanthrene 129-00-0 Pyrene 120-82-1 1,2,4-Trichlorobenzene CAS No. Surrogate Recoveries367-12-4 2-Fluorophenol4165-62-2 Phenol-d5 118-79-6 2,4,6-Tribromophenol 4165-60-0 Nitrobenzene-d5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND MS 54:%41.%104%86%100.100 100 100 100 100 100 100 100 100 100 100 100 200 100 100 100 100 100 100 100 100 100 100 100 100 100 100 MSD 52%38%:97%83%106 95.0 86.8 94.3 113 136 106 102 113 103 98.7 104 97.5 148 92.7 87.2 97.3 92.6 110 86.5 103 87.7 90.8 95.2 92.9 93.3 94.5 90.4 106:::-. 101 101 '5 "45-124/28 95 .91.9 .92: 3 1-145/37 87 82.2 82 5 40-138/27"94 90.3 90 4 42-119/28 ,113 104 104 8 54-131/22 136 126 126 8 49-151/25 106 99.9 .100 6 49-123124 102 97.7 98 .4 39-124/27 11.3 108 .108 5. 51-140/29 103 95.1 95 8 52-129/22 99 94.1 94: 5 43-116/26 1i04 95.5 96:. :9' 49-121/24 98.. 94.4 .94 ... 30-126/33. 74 140 :70: 6. 1-109/41.93 89.8 90 3 22-113/34 87 82.7 83 5. 40-139/28.97... 92.8 "93.:.' 5 .34-116/37 93 0 88.7 :89 4. 28-123/32 11:0 105 5 30-135/33-87 83.3 83:. 4 15-134/35 103 99.4 99 4 18-153/32 88 84.2 84 4 .22-120/30 91 88,2 88. 3. 31-118/32 95" 92.4 92 3 32-125/33 93 86.7 87 7. 49-131/24 93". 86.7 .87 7 51-117/23 9.5 .90.3 "90. 5 54-.122/22 90 87.3 '87 3 27-115/31 N85706-1 Limits 37% .10-897.22% 1,0-7 98% 45-134%:88% 32-128%0*~ ~ Matrix Spike/Matrix Spike Duplicate SummaryJob Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 3 of 3 6V Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OP19011-MS F47334.D 1 01/04/05 NAP 12/14/04 OP19011 EF2504 OP19011-MSD F47335.D 1 01/04/05 NAP 12/14/04 OP19011 EF2504 N85706-1 F47333.D 1 01/04/05 NAP 12/14/04 OP19011 EF2504 The QC reported here applies to the following samples: Method: SW846 8270C N85893-1, N85893-2 CAS No. -Surrogate Recoveries 321-60-8 2-Fluorobiphenyl 1718-51-0 Terphenyl-dl4 MS MSD N85706-1 Limits 83%92%80% 83%89% 98%34-121%41-129%9 ,62 Instrument Perfornmance Check (DFTPP) Page] of ]Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Sample: EF2491-DFTPP injection Date: 12/14/04 Lab File ID: F46939.D Injection Time:. 16:21 Instrument ID:. GCMSF Raw % Relative m/e Ion Abundance Criteria Abundance Abundance Pass/Fail30.0 -60.0 % of mass 198 4643 .: Pass.8 Less than 2.0% of mass 69 52 0.51 .1)- Pass 69 .. Mass 69 relative abundance 4650 45.8 Pass.70 :.:"ý'Less than 2.0% of mass 69 0 U00 (0.0) Pass:127:1" 40.0 -60.0% of mass 198 5573 54.9 Pass:1:97 .Less than 1.0% of mass 198 0 0.0 Pass 198.'.. Base peak, 100% relative abundance 10149 100.0 Pass 199: 5.0- 9.0% of mass 198 607 6.0 Pass 275.:. 10,0 -30.0% of mass 198 2337 23..0. .Pass 365 1.0 -100.0% of mass 198 192 1.9 Pass 41. Present, but less than mass 443 1092 10.8 (7..21 Pass 442: 40.0-100.0% of mass 198 7223 71.2 , .: ..Pass 414313 17.0- 23.0% of mass 442 1414 1. .() .Pass (a) Value is % of mass 69 (b) Value is % of mass 443 (c) Value is % of mass 442 This check applies to the following Samples, MS, MSD, Blanks, and Standards: Lab Lab Date Time Hours Client Sample ID File ID Analyzed Analyzed Lapsed Sample ID EF2491-ICC2491 F46940.D 12/14/04 16:45 00:24 Initial cal 50 EF2491-1C2491 F46941,D 12/14/04 17:22 01:01 Initial cal 100 EF2491-IC2491 F46942.D 12/14/04 17:59 01:38 Initial cal 80 EF2491-IC2491 F46943.D 12/14/04 18:36 02:15 Initial cal 25 EF2491-1C2491 F46944.D 12/14/04 19:12 02:51 Initial cal 10 EF2491-IC2491 F46945.D 12/14/04 19:49 03:28 Initial cal 5 EF2491-1C2491 F46946.D 12/14/04 20:26 04:05 Initial cal 2 OP18875-MBI F46948.D 12/14/04 21:39 05:18 Method Blank ZZZZZZ F46949.D 12/14/04 22:15 05:54 (unrelated sample)ZZZZZZ F46950.D 12/14/04 22:52 06:31 (unrelated sample)ZZZZZZ F46951 ,D 12/14/04 23:29 07:08 (unrelated sample)ZZZZZZ F46952.D 12/15/04 00:05 07:44 (unrelated sample)ZZZZZZ F46953.D 12/15/04 00:42 08:21 (unrelated sample)ZZZZZZ F46954.D 12/15/04 01:19 08:58 (unrelated sample)ZZZZZZ F46955.D 12/15/04 01:56 09:35 (unrelated sample)ZZZZZZ F46956.D 12/15/04 02:32 10:11 (unrelated. sample)ZZZZZZ F46957.D 12/15/04 03:09 10:48 (unrelated sample)ZZZZZZ F46958.D 12/15/04 03:47 11:26 (unrelated sample)F63 Instrument Performance Check (DFTPP)Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 1 of 2 Sample: EF2492-DFTPP Injection Date: 12/15/04 Lab File ID: F46960.D Injection Time: 08:40 Instrument ID: GCMSF Raw % Relative m/e ]on Abundance Criteria Abundance Abundance Pass/Fail 5 30.0 -60.0% of mass 198 3544 40.4 Pass 68 Less than 2.0% of mass 69 17 10.19.. Pass 69 Mass 69 relative abundance 3552 0.5.Pass 70) Less than 2.0% of mass 69 0 0.0. :. (0). Pass 127 40.0 -60.0% of mass 198 4398 50:1 Pass:197: Less than 1.0% of mass 198 0 0,0. Pass 19:8 Base peak, 100% relative abundance 8780 160. .Pass'199, 5.0 -9.0% of mass 198 657 7,5 Pass 275 100.0- 30.0% of mass 198 2002 22i8.:8:_. Pass 365: 1.0 -100.0% of mass 198 193 2.2 Pass 44.1 Present, but less than mass 443 1018 11.6 (80..8) b Pass.442 1 40.0 -100.0% of mass 198 6686 '76.2 Pass 443. 17.0- 23.0% of mass 442 1260 .14.4 (18.8) C Pass (a) Value is % of mass 69 (b) Value is % of mass 443 (c) Value is % of mass 442 This check applies to the following Samples, MS, MSD, Blanks, and Standards: Lab Lab Date Time flours Client Sample ID File ID Analyzed Analyzed Lapsed Sample ID EF2492-CC2491 F46961.D 12/15/04 08:54 00:14 Continuing cal 50 OP18822-MBI F46962.D 12/15/04 09:31 00:51 Method Blank OP18822-BS1 F46966.D 12/15/04 10:08 01:28 Blank Spike ZZZZZZ F46963.D 12/15/04 10:44 02:04 (unrelated sample)ZZZZZZ F46964.D 12/15/04 11:21 02:41 (unrelated sample)ZZZZZZ F46965.D 12/15/04 11:57 03:17 (unrelated sample)OP18958-MBI F46967.D 12/15/04 12:34 03:54 Method Blank OP19011-MBI F46968.D 12/15/04 13:11 04:31 Method Blank ZZZZZZ F46969.D 12/15/04 13:47 05:07 (unrelated sample)OP18902-MB1 F46970.D 12/15/04 14:25 05:45 Method Blank OP18902-BSI F46971..D 12/15/04 15:01 06:21 Blank Spike ZZZZZZ F46972.D 12/15/04 15:37 06:57 (unrelated sample)ZZZZZZ F46973.D 12/15/04 16:14 07:34 (unrelated sample)N85098-8 F46974.D 12/15/04 16:51 08:11 (used for QC only; not part of job N85893)OP18902-MS F46975.D 12/15/04 17:27 08:47 Matrix Spike OP18902-MSD F46976.D 12/15/04 18:04 09:24 Matrix Spike Doplicate zzzzzz F46977.D 12/15/04 18:41 10:01 (unrelated sample)ZZZZZZ F46978.D 12/15104 19:17 10:37 (unrelated sample)ZZZZZZ F46979.D 12/15/04 19:54 11:14 (unrelated sample)6, 64 Instrument Performance Check (DFTPP)Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 2 Sample: EF2492-DFTPP Injection Date: 12/15/04 Lab File ID: F46960.D Injection Time: 08:40 Instrument ID: GCMSF Lab Sample ID Lab File ID Dale Time Hours Analyzed Analyzed Lapsed Client Sample ID ZZZZZZ N85602-1 OP18980-MS OP18980-MSD F46980.D F46983.D F46984.D F46985.D 12/15/04 12/15/04 12/16/04 12/16/04 20:31 23:35 00:12 00:49 11:51 14:55 15:32 16:09 (unrelated sample)(used for QC only; not part of job N85893)Matrix Spike Matrix Spike Duplicate OW , 65 Instrument Performance Check (DFTPP) Page I of 2 Job Number: N85893Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Sample: EF2503-DFTPP Injection Date: 12/31/04 Lab File ID: F47278.D Injection Time: 03:27 Instrument ID: GCMSF Raw % Relative m/e Ion Abundance Criteria Abundance Abundance Pass/Fail 51, 30.0 -60.0% of mass 198 6762 40.3 Pass 68 Less than 2.0% of mass 69 0 10:.0 (0.0) a Pass:69. Mass 69 relative abundance 6499 '38.7 Pass 70' Less than 2,0% of mass 69 0 0.0 (0.0) a Pass.127 40.0- 60.0% of mass 198 8341 49.7. Pass 1197 Less than 1.0% of mass 198 0 0.0 Pass:198... Base peak, 100% relative abundance 16785 100.0 Pass5.0 -9.0 % of mass 198 1155 6.9 Pass 275 10.0 -30.0% of mass 198 4170 24..8. Pass 365 1.0- 100.0% of mass 198 425 2.5 ..Pass 4 :41 Present, but less than mass 443 2120 1:26:: .(7 8: 4 b Pass:442 40.0 -100.0% of mass 198 14427 86.0. ...Pass 443. 17,0- 23.0% of mass 442 2704 1.3:: .(i8: 7 c Pass (a) Value is % of mass 69 (b) Value is % of mass 443 (c) Value is % of mass 442 This check applies to the following Samples, MS, MSD, Blanks, and Standards: Lab Lab Date Time Hours Client Sample ID File ID Analyzed Analyzed Lapsed Sample ID EF2503-CC2491 F47279.D 12/31/04 03:41 00:14 Continuing cal 50 OP19078-MBI F47280.D 12/31/04 04:53 01:26 Method Blank ZZZZZZ F47281.D 12/31/04 05:29 02:02 (unrelated sample)N85893-1 F47282.D 12/31/04 06:05 02:38 WELL AZ N85893-2 F47283.D 12/31/04 06:41 03:14 FB-I ZZZZZZ F47284.1D 12/31/04 07:17 03:50 (unrelated sample)ZZZZZZ F47285,D 12/31/04 07:53 04;26 (unrelated sample)ZZZZZZ F47286.D 12/31/04 08:29 05:02 (unrelated sample)ZZZZZZ F47287.D 12/31/04 09:05 05:38 (unrelated sample)ZZZZZZ F47288.D 12/31/04 09:41 06:14 (unrelated sample)ZZZZZZ F47289.D 12/31/04 10:16 06:49 (unrelated sample)ZZZZZZ F47290.D 12/31/04 10:52 07:25 (unrelated sample)ZZZZZZ F47291.D 12/31/04 11:27 08:00 (unrelated sample)'ZZZZZZ F47292.D 12/31/04 12:03 08:36 (unrelated sample)ZZZZZZ F47293.D 12/31/04 12:39 09:12 (unrelated sample)-ZZZZZZ F47294.D 12/31/04 13:15 09:48 (unrelated sample)ZZZZZZ F47295.D 12/31/04 13:50 10:23 (unrelated sample),.ZZZZZZ F47296.D 12/31/04 14:27 11:00 (unrelated'sarnple) .ZZZZZZ F47297,D 12/31/04 15:03 11:36 (unrelated sample)'F, 0o , Instrument Performance Check (DFTPP)Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 2 Sample: EF2503-DFTPP Injection Date: 12/31/04 Lab File ID: F47278.D Injection Time: 03:27 Instrument ID: GCMSF Lab Sample ID ZZZZZZ Lab File ID Date Time Hours Analyzed Analyzed Lapsed Client Sample ID F47302.D 12/31/04 20:24 16:57 (unrelated sample)few 9" 6o7 Instrument Performance Check (DFTPP)Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page I of 2Sample: EF2504-DFTPP Injection Date: 01/04/05 Lab File ID: F47324.D Injection Time: 08:28 Instrument ID: GCMSF Raw % Relative m/e Ion Abundance Criteria Abundance Abundance Pass/Fail 1 30.0 -60.0% of mass 198 4630 41.0 Pass 68 Less than 2.0% of mass 69 0 0.0 (0.0) a Pass 9. Mass 69 relative abundance 4689 41.5' Pass7 i. .Less than 2.0% of mass 69 0 0.0 (0.0) a Pass 127 40.0 -60.0% of mass. 198 5600 49.6 PassLess than 1.0% of mass 198 53 -0:47 Pass 4198 '. Base peak, 100% relative abundance 11292 1:00.0..- Pass 0199 5.0- 9.0% of mass 198 820 7.3 Pass 275 10.0- 30.0% of mass 198 2715 24.;.0.1 .Pass 365. 1.0- 100.0% of mass 198 303 2.7:::: Pass 441-:.. Present, but less than mass 443 1446 .128 .(73.7) .b Pass 442 :).*. 40.0- 100.0% of mass 198 9828 .Pass 443 17.0 -23.0% of mass 442 1961 17,4 (20.0)c Pass (a) Value is % of mass 69 (b) Value is % of mass 443 (c) Value is % of mass 442 This check applies to the following Samples, MS, MSD, Blanks, and Standards: Lab Lab Date Time Hours Client Sample ID File ID Analyzed Analyzed Lapsed Sample ID EF2504-CC2491 F47325.D 01/04/05 09:23 00:55 Continuing cal 25 oP19176-MBI F47326.D 01/04/05 09:59 01:31 Method Blank OP19176-BSl F47327.D 01/04/05 10:35 02:07 Blank Spike OP19078-BSI F47328.D 01/04/05 11:11 02:43 Blank Spike N86593-2 F47329.D 01/04/05 11:46 03:18 (used for QC only; not part.of job N85893)OP19078-MS F47330.D 01/04/05 12:22 03:54 Matrix Spike OP19078-MSD F47331.D 01/04/05 12:58 04:30 Matrix Spike Duplicate OP19011-BS1 F47332.D 01/04/05 13:35 05:07 Blank Spike N85706-1 F47333.D 01/04/05 14:10 05:42 (used for QC only; not part of job N85893)OP19011-MS F47334.D 01/04/05 14:46 06:18 Matrix Spike OP19011-MSD F47335.D 01/04/05 15:21 06:53 Matrix Spike Duplicate ZZZZZZ F47336.D 01/04/05 15:57 07:29 (unrelated sample)OPI9014-MS F47337,D 01/04/05 16:33 08:05 Matrix Spike OP19014-MSD F47341.D 01/04/05 17:09 08:41 Matrix Spike. Duplicate N87336-10 F47338.D 01/04/05 17:45 09:17 (used for. QC onily; not.part of job N85893)OP19176-MS F47339.D 01/04/05 18:20 09:52 Matrix.Spike ." OP19176-MSD F47340.D 01/04105 18:56 10:28 Matrix Spike.DuplicateOP19128-MS F47342.D 01/04/05 19:32 11:04 Matrix Spike OP19128-MSD F47343..D 01/04/05 20:08 11:40 Matrix Spike Dbplicate Instrument Performance Check (DFTPP)Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 2 Sample: EF2504-DFTPP Injection Date: 01/04/05 Lab File ID: F47324.D Injection Time: 08:28 Instrument ID: GCMSF Lab Sample ID Lab File ID Date Time Hours Client Analyzed Analyzed Lapsed Sample ID OP19072-MB1 OP19072-BSI ZZZZZZ ZZZZZZ ZZZZZZ ZZZZZZ.ZZZZZZ ZZZZZZ ZZZZZZ ZZZZZZ ZZZZZZ ZZZZZZ ZZZZZZ N86590-1 OP19072-MS. OP 9072-MSD ZZZZZZ F47344.D F47345.D F47346.D F47347.D F47348.D F47349.D F47350.D F47351.D F47352.D F47353.D F47354.D F47355.D F47356.D F47357.D F47358.D F47359.D F47360.D 01/04/05 01104105 01104105 01/05/05 01/05/05 01/05/05 01105/05 01/05105 01105/051 01105/05 01/05/05 01/05/05 01/05/05 01/05/05 01/05/05 01/05/05 01/05/05 22:31 23:06 23.:42 00:18 00:53 01:28 02:04 02:39 03:15 03:51 04:27 05:02 05:38 06:14 06:49 07:25 08:01 14:03 14:38 15:14 15:50 16:25 17:00 17:36 18:11 18:47 19:23 19:59 20:34 21:10 21:46 22:21 22:57 23:33 Method Blank Blank Spike (unrelated sample)(unrelated sample)(unrelated sample)(unrelated sample)(unrelated sample)(unrelated sample)(unrelated sample)(unrelated sample)(unrelated sample)(unrelated sample)(unrelated sample)(used for QC only; not part of job N85893)Matrix Spike Matrix Spike Duplicate (unrelated sample)0.69 Semivolatile Internal Standard Area Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page I of I Check Std: EF2492-CC2491 Injection Date: 12/15/04 Lab File ID: F46961.D Injection Time: 08:54 Instrument ID: GCMSF Method: SW846 8270C IS1 IS2 IS3 IS4 ISs 1S6 AREA RT AREA RT AREA RT AREA RT AREA RT AREA RTStid: 329763.: 6.51 9.14 609484: 13.24 1023602 16.72 955259:; 22.22 580571' 24.56 Upper Limita 65.95 G.:..:- 7.01 24,74290 9.64 :121.8968 13.74 2047204 17.22 19100518 22.72 1.1.61t42 25.06 Lower Limitb 14882 6.01 6!8573.4 8.64 304712 12.74 51980' 16.22 477630 21.72 290286. 24.06 Loe Limi b 1..48.2 6"0 ":.5,3ý 8.6 "ý4 q'" -62 760: '...Lab Sample ID OP18822-MBI OF18822-BSl zzzzzz zzzzzz zzzzzz OP]8958-MB] OP1901 1-MB1 zzzzzz 0P 18902-MBI OP18902-BS 2 zzzzzz zzzzzz N85098-8 OP1 8902-MS OP18902-MSD zzzzzz zzzzzz zzzzzz zzzzzz N85602-1 OP18980-MS OP1 8980-MSD IS I AREA RT 316069 6.50 303460 6.50 328.115 6.50 32.1755 6.50 299205 6.50 34.85.19.ý'. 6.49 3719360.. 6.50 290625 6.50 393804.: 6.50 341453 6.50 308996.: 6.49 307620 6.50 30125-1 6.49 342684 6.50 377.956 6.50 298463 6.50 2.81476 6.50 2579,73 6,51 272051 6.51 283337 6.50 327824ý 6.51 270248 6.50 IS2 AREA RT 1229840 9.13.1175722 9.14 1246253 9.14 1205661 9.13 1164225 9,13 1:326.745 9.03 12:13909 9.13 111t6317 9.13 1t'49.989-6 9.13 1298729 9.14 1.154654 9.13 1:150469 9,13 1142244 9.13.1268736 9.14 1405494 9.14 1.051864 9.13 999864. 9.14 925524. 9.14 930516 _ 9.14 1024955 9.14'1202.188 9.14 987409 9.14 IS3 AREA 6215 3 592964 652058 597670 591228 67.120.1 6 051:59.ý5640491/7668.70.ý' 634915.568426 5-61329 565372 60621:0 665371 480622 453816.6 420138 403053-483651 561897 462580 IS 4 AREA RT IS5 AREA RT RT 13.23 13.24 13.25 13.24 13.23 13.23 13.23 13.23 13.23 13.24 13.23 13.23 13.23 13.23 23.24 13.22 13.23 13.23 13.23 13.23 13.24 13.24 1072770 16.71 1008445 16.72 1052957 16.74 97127-0 16.71 101i9980 16.71 1118445 16.71 1:03 6319 16.71 967309 16.71 1306290 16.71 1031634 16.71 9.16569.1 16.7116.71 91 2014 16.71 971820 16.71 1060813 .16.72 793939 16.71 729066 16.71 688846 16.71 63067,2 16.71 761971 16.71 896469 16.72 74848 1 16.71 1007542 22.21 941.666 22.22 9011:00 22.22 790814: 22.21 890696: 22.21.9857750. 22.21 8964-41-:.; 22.21 875-6177. 22.211 195627 22.21 967424: 22.22 8157661 22.21 806729. 22.20 846-1.94.. 22.21 963618 22.22 1076893 22.22 4967:18 22.21 50,7273: 22.20 480621. 22.20 426435" 22.20 549.932 22.20 675759 22.22 557504 22.21 607739" 24.56 566076 24.56 555843. 24.56 443-:82 24.56 507244ý 24.56 582961 24.56 51:7876 24.56 497666:: 24.56 702470 24.56 602061 24.56 452673 24,56 481754 24,56 485275 24.56 530459 24.56 553,943 24.56.1:66300" 24.56 170102* 24.54:16.6042* 24.54 1:41'205* 24.54 1 93786* 24.55 244223-* 24.55 186344* 24.55 IS 6 AREA RT IS ] = 1,4-Dichlorobenzene-d4 IS 2 = Naphthalene-d8 IS 3 = Acenaphthene-DI0 IS 4 = Phenanihrene-dlO IS 5 = Chrysene-d12IS 6 = Perytene-d12 (a) Upper Limit + 100% of check standard area; Retention time +0.5 minutes.(b) Lower Limit = -50% of check standard area; Retention time -0.5 minutes.01 70 Semivolafile Internal Standard Area Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project,- PSEG-Salem, Artificial Island, Salem, NJ Page 1 of I Check Std: EF2503-CC2491 Injection Date: 12/31/04 Lab File ID: F47279.D Injection Time: 03:41 Instrument ID: GCMSF Method: SW846 8270C IS] ]S2 IS3 IS4 IS5 IS6 AREA RT AREA RT AREA RT AREA RT AREA RT AREA RT CheckS~td 393671 6.34 1502855 8.96 797227 13.05 1376917 16.53 1379319 22.07 853382< 24.39 Upper Limita 787342':ý 6.84 30057.10 9.46 1594454 13.55 27 53834 17.03 27,58638 22.57 170.6764 24.89 Lower Limit b 196836.. 5.84 751428,:: 8.46 398614. 12.55 68:9459, 16.03 689.660-' 21.57 426691 23.89 Lab Sample ID OP19078-MBI zzzzzz N85893-1 N85893-2 zzzzzz zzzzzz zzzzzz zzzzzz zzzzzz zzzzzz#VW zzzz~zz zzzzzz zzzzzz zzzzzz zzzzzz zzzzzz zzzzzz zzzzzz zzzzzzIS i AREA RT 3977.09- 6.33 36-:6641, 6.33 393345 6.34 401821' 6.33 433467 6.33 403960 6.33 1254* 6.50 422722: 6.33 404460 6.33 445379 6.33 3.98332 6.33 390,337. 6,33 4.18423 6.34 42:1.910 6.33 5119888. 6.33 41:4841 : 6.33 4:1:5847-1: 6.33 445802.. 6.33 3667774. 6.34 IS2 AREA RT:1549240 8.95:14458,13 8.95 P544503 8.96 159.5622 8.96 1723272 8.95 1605282 8.95 1759419 8.95 1690634 8.95 1606256 8.95 1782272 8.96 15:83-617 8.95.1.568343 8.96 1645497 8.97 1687721 8.96 2064770 8.96 1660814 8.95 16488.19 8.95 1777495 8.95-14571.69 8.96 IS3 AREA 830963 77:13.03.829676 839326 915096 859287 941165 900866 864324 972898 846897 842001 895625 917468 13.04 13.04 13.04 13.04 13.04 13.04 13.04 13.04 13.04 13,04 13.04 13,04 13.05 13.04 1453.389 16.52 1:355179 16.52 1437523 16.52 1453838 16.521609304 16.52 1489886 16.52 1629379 16.52 1637772 16.52 1520495 16.521671985 16.53 1474.179 16.52 1446713 16.52 1543768 16.52 1580669 16.52 191.6927 16.53 1563339 16.52 1508687 16,52 1684146 16,53 1.330587 16,52 1S4 IS5 RT AREA RT AREA RT 1:434540 22.06.13.521.52 22.06 1405309 22.06 1.429040 22.06 1-630647 22.06.1456736 22.06 1:626388 22.06 1608884 22.06 1528720 22.06 1647242 22.06 1.487988 22.06 1433089 22.06 15 8431 22.06 1542562 22.06 19249.36 22.06 1506972 22.06 1434345 22.06.1.644513 22.07 1309446 22.06 IS 6 AREA RT24.3824.38 908747 24.38 905723. 24.38 1:023757 24.38 750045. 24.38 1038280 24.38 1009821 24.38 943447 24.38 995740 24.38 92.3638 24.38 837.623 24.38 923737 24.38 9347.14 24.38 115.8784 24.39 892700 24.38 7W0747. 24.38 765618o. 24.40 724484 24.38 1:098840 13.04 885401 13.04 880949 13.04 9605.69 13.04 768980 13.04 IS = 3,4-Dichlorobenzene-d4 IS 2 = Naphihalene-d8 IS 3 = Acenaphchene-D10 IS 4 = Phenanthrene-dlO IS 5 = Chrysene-d12 IS 6 = Perylene-d12 (a) Upper Limit = +100% of check standard area; Retention time +0.5 minutes.(b) Lower Limit = -50% of check standard area; Retention time -0.5 minutes.-~-*~ 71.-a... Semivolatile Internal Standard Area Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 1 of 2 Check Std: EF2504-CC2491 Injection Date: 01/04/05 Lab File ID: F47325.D Injection Time: 09:23 Instrument ID: GCMSF Method: SW846 8270C IS1 IS2 IS3 1S4 IS5 IS6 AREA RT AREA RT AREA RT AREA RT AREA RT AREA RT Ciheck Sidf.. 329243 6.32 1.272297 8.94 691200 13.03 1219532 16.50 1221.144 22.04 738072. 24.37 Upper Limit a 658486.: 6.82 2544594 9.44 13:82400 13.53 243.9064 17.00 2442288 22.54 147651.44 24.87 Lower Limit b 164622.: 5.82 636149 8.44 .345600, 12.53 609766 16.00 610572 21.54 369036.: 23.87 Lab Sample ID&V OP19176-MBI OP19176-BS1 OP19078-BSI N86593-2 OP19078-MS OPI 9078-MSD OP19011-BSI N85706-1 0P19011-MS OP19011-MSD zzzzzz OP19014-MS OP19014-MSD N87336-1 0 OP19176-MS OP19176-MSD OP19128-MS OP19128-MSD OPI 9072-MB1 OP]9072-BSI zzzzzz zzzzzz zzzzzz zzzzzz zzzzzz zzzzzz zzzzzz zzzzzz zzzzzz zzzzzz zzzzzz N86590-1 OP19072-MS OP19072-MSD zzzzzz IS I AREA RT 3,962'2 6.32 389501t... 6.32 354750 6.32 3-703351: 6.32 392255ý1ý 6.32 380849, 6.32 379975 .6.33 330873 6.33 3341:18 6.32 3.38685 6.33 164254* 6.33 390460 6.32 3.76168 6.32 233544 6.33 257997:: 6.32 236445 6,32 37.14.62 6,32 360124- 6.33 330851 6.33 332067 6.33 3..14-588 6.33 29702.1 6.33 3 4442 6.34 293461 6.33 310876 6.33 322233 6.33 325028.: 6.33 350247ý 6.33 303037. 6.33 312767 6.33 316753 6.33 310292 6.33 310721 6.33 31:0316 6.33 309893 6.34 IS2 AREA RT 1387.420 8.94 14.95466 8.94 1374663 8.95 1409286 8.94 1522798 8.95.14.74268 8.95 1476576 8.95.11272627 8.94 1298638 8.95 13.07671 8.95 6322525 8.94 1527329 8.95 1464-1,09 8.94 9:11983 8,94.1:0305.38 8.94 957568 8.93 1431.909 8.94.1385749 8,94 11268437 8.94 1282695 8.95 1:213576 8.94 1 1151904 8.94:1.252437 8.97 1144853 8.941 186689 8.94 1261.392 8.95.1.242.533 8.94 113414949 8.94 1154610 8.94 1,202934 8.96 1227106 8.94 1205772 8.94 11.96968 8.95.191607 8.95 1174889 8.96 IS 3 AREA RT IS 4 AREA RT 70,891.7 749260 7085.79 829530 80473.1.813425: 647045.702401: 698902 3.1:89:16* 833681.801.191 475566, 5283.64..: 496089.799652.775099 657638 689787.620183: 606628.692223:: 618780 627374 674584.638095 689474 607138 654887 644283 650871l 645344 638445 615804 13.03 13.03 13.03 13:03 13.03 13.03 13.03 13.02 13.03 13.03 13.02 13.03 13.03 13.02 13.02 13.02 13.03 13.03 13.02 13.03 13.03 13.03 13.13 13.03 13.03 13.03 13.03 13.03 13.02 13.03 13.03 13.04 13.03 13.03 13.03 11300682 16.50 1:423482 16.51.1303989 16.51 12.87530 16.50 14-6130] 16.51'1410721 16.51.1413349 16.51 1158089 16.50 1219056 16.51 1241377 16.51 569326* 16.50 146..707:8 16.52 1:39.8709 16.51 887642, 16.50 9,19.19381 -16.50 872775 16.50 1408724 16.51.1350156 16.51 1'174147 16.50.1.190827 16.51 1.126371 16.50 1:058340 16.50 642101. 16.67 1.tt461l 16.50 11-01:899 16.50 1122 865 16.50 1t087624 16.50 120,011:.8 16.51 31 024654 16.50 1167664 16.54 1168567 16.52 115441.1 16.53 1139543 16.53:1128439 16.52 1014162 16.51.125051"6 22.04 1438661 22.05 1336642 22.05.1213707 22.04 1468024 22.05 14110773 22.05 143.241.6 22.05 1095379 22.04 1215773 22.05.1200889 5 19200*'1523094 1.41.0952 842035 886-113 8252-44: 1283553 IS5 AREA RT 22.05 22.04 22.06 22.05 22.04 22.04 22.04 22.05 1206086 22.05 1002627 22.04 1081014 22.05 977393, 22.04 948714 22.04 1132765 22.08 969451 22.04 995478 22,04 9607003 22.04 9981.189 22.04 1009.550 22.04 936393. 22,04 7211.20 22.08 957995.' 22.,06 899579." 22.06 912094:.. 22.06 91:8682 22.06 81425.1 22.05 IS 6 AREA RT 764887 24.36 865084... 24.37 809665'. 24.37 7 252 .13 24.37 887098!:24.37 843445 24.37 842340. 24.37 646358 24.37 702539 24.37 703793 24.37 284758* 24.36 91:13.19 24.38 834798 24.37 455797 24,37 46791t7 24.37 383295. 24.37 55.6898 24.37 50.1323.: 24.37 456682 24.37 460474'. 24.37 43084:1: 24.37 4*15370 24.37 433172 24.38 423:14 1- 24.37 434072 24.37 412882 24.37 439427 24.37 444059 24.37 401:839: 24.37 182607* 24.41 3713693 24.38 3004.15. 24.38 33-:731
- 24.38 34.83.99*"24.38 319009* 24.37 0.. 7Z C Semivolatile Internal Standard Area Summary Page 2 of 2 Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Check Std: EF2504-CC2491 Injection Date: 01/04/05 Lab File ID: F47325.D Injection Time: 09:23 Instrument ID: GCMSF Method. SW846 8270C Lab IS1 IS2 IS 3 IS 4 IS5 1S 6 Sample ID AREA RT AREA RT AR.EA RT AREA RT AREA RT AREA RT IS 1 = 1,4-Dichlorobenzene-d4 IS 2 = Naphthalene-d8 IS 3 = Acenaphthene-DIO IS 4 = Phenanthrene-dlO IS 5 = Chrysene-d12 IS 6 = Perylene-d12 (a) Upper Limit = +100% of check standard,'area; Retention time +0.5 minutes.(b) Lower Limit = -50% of check standard area; Retention time -0.5 minutes..3. .
4V Semivolatile Surrogate Recovery Summary Page 1 of I Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Method: SW846 8270C Matrix: AQ Samples and QC shown here apply to the above method Lab Lab Sample ID File ID S1 S2 $3 S4 S5 S6 N85893-1 F47282.D 40.0 28.0 86.0. 70.0 66.0 84.0 N85893-2 F47283.D 37.0 34.0 :89.0. 85.0 79.0 90.0 OP19011-BSI F47332.D 35:..0 22.0 88.0 76.0 '71.0 76.0 OP19011-MBI F46968.D 37,0 31.0 72:0 70.0 69...-.0 83.0 OP19011-MBI P11097.D 49,0.0. 31.0 103.:0: 77.0 71.0.:D 85.0 0P19011-MS F47334.D -54:0`;: 41.0 1.040 86.0 -837;.4D.,!:..: 92.0 0P19011-MSD F47335.D :52;0:. .38.0 97..0 83.0 .89.0 Surrogate Recovery Compounds Limits S1 = 2-Fluorophenol 10-88%S2 = Phenol-d5 10-71 .%S3 = 2,4,6-Tribromopheno] .45-134-%`: S4 = Nitrobenzene-d5 32-128%S5 = 2-Fluorobiphenyl 34-121T S6 = Terphenyl-d14 41-129% Initial Calibration Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page I of 3 Sample: EF249) -1CC2491 Lab FilelD: F46940.D Response Factor Report MSF Method Title Last Update Response via C:\MSDCHEM\I\METHODS\MF2491.M (RTE Integrator) Semi Volatile Extractables by GC/MS Mon Dec 20 09:17:47 2004Initial Calibration Calibration Files 2 =F46946.D 5 100 =F46941.D 50=F46945 .D=F46940 .D 25 =F46943.D 10 =F46944.D 80 =F46942.D Compound 2 5 25 80 100 50 10 Avg %RSD...........................................................................
- 1) I 1,4-Dichlorobenzene-d
ISTD --------------------- .2) 1,4-Dioxane 0.629 0.741 0.653 0.583 0.594 0.628 0.708 0,676 3) Pyridine 1.702 1.719 1.682 1.489 1.514 1.594 1.780 1,640 4) N-Nitrosodim 0.621 0.550 0.532 0.481 0.488 0.514 0.581 0.538 5) 2-Fluorophen 1.486 1.528 1.409 1.250 1.257 1.344 1.491 1.395 6) Indene 2.452 2.509 2.532 2.320 2.349 2.429 2.670 2.466 7) Cumene 3.078 3.209 3.184 3.030 3.075 3.134 3.361 3.153 8) Phenol-d5 1.825 1.872 1.724 1.450 1.450 1.605 1.829 1.679 9) Phenol 1.969 1.989 1.927 1.569 1.567 1.765 2.048 1.833 10) Aniline 2,140 2.285 2J.232 1.837 3-852 2.040 2.380 2.110 11) bis(2-Chloro 1.345 1.370 1.348 1.213 1.213 1.276 1.418 1.312 12) Benzaldehyde 0.275 0.361 0.593 0.238 0.181 0.401 0.405 0.351 13) 2-Chlorophen 1.433 1.462 1.447 1.271 1.281 1.366 1.537 1.399 14) Decane 1.292 1.363 1.313 1.174 1.166 1.231 1.423 1.280 15) 1,3-Dichloro 1.535 1.598 1.584 1.468 1.492 1.529 1.669 1.554 16) 1,4-Dichloro 1.637 1.653 1.595 1.490 1.499 1.552 1.690 1.588 17) Benzyl alcoh 0.909 0.925 0'.949 0.823 0.826 0.901 0.985 0.903 18) 1,2-Dichloro 1.495 1.533 1.489 1.365 1.382 1.441 1.584 1.470 19) Acetophenone 1.926 1,959 1.948 1.703 1.731 1.837 2.056 1.880 20) 2-Methylphen 1.309 1.336 1,.303 1.103 1.116 1.210 1,370 1.250 21) 2,2'-oxybis( 0.460 0,466 0.459 0.419 0.420 0.437 0.490 0.450 22) 3&4-Methylph 1.348 1.374 1.388 1.150 1.163 1.276 1.455 1.308 23) n-Nitroso-di 0.758 0.811 0.823 0.717 0.728 0.772 0.850 0.780 24) Bexachloroet 0.479 0.507 0.525 0.500 0.511 0.515 0.547 0.512 13 .05 6.69 9.37 8 19 4 .81 3 .54 10.. 69 10 .98 9.96 6.05 38.87 7.02 7.47 4.43 4.87 6.67 5.39 6.85 8.60 5.74 8.87 6.36 4.14 25)26)27)28)29)30)31)32)33)34)35)36)37)38)39)40)41)42)43)44)45)I Naphthalene-d8
ISTD--Nitrobenzene Nitrobenzene Quinoline Isophorone 2-Nitropheno 2,4-Dimethyl Benzoic acid bis(2-Chloro 2,4-Dichloro 1,3, 5-Trichl 1,2,4-Trichl 1,2,3-Trichl alpha-Terpin Naphthalene 4-Chloroanil 2,3-Dichloro Caprolactam Hexachlorobu 4-Chloro-3-m 2-Methylnaph 0.349 0.161 0.664 0.607 0.131 0.317 0,382 0,251 0.335 0.324 0.310 0.268 1. 111 0.404 0.311 0.100 0.182 0.248 0.673 0.372 0.172 0.679 0.637 0.154 0.338 0.398 0.264 0.343 0.326 0.314 0.278 1 110 0.441 0.332 0.121 0.183 0.276 0 .693 0.390 0.181 0.691 0.645 0.183 0.349 0.238 0.396 0.278 0.335 0.322 0.309 0.277 1.063 0.444 0.335 0.137 0. 184 0.296 0.702 0.371 0.172 0.618 0.580 0.180 0.313 0.253 0. 364 0.256 0.326 0.313 0.297 0 .241 0.983 0 .389 0.299 0 .117 0.182 0.265 0 .641 0.378 0.176 0.640 0.593 0.184 0.322 0.263 0.370 0.262 0.331 0.320 0.306 0.240 0.998 0.396 0.307 0.122 0.186 0.274 0.657 0.383 0. 177 0 .662 0 .614 0.181 0.334 0.244 0.376 0.269 0.331 0.318 0.305 0 .255 1.027 0.421 0.322 0. 128 0.183 0 .284 0.675 0.408 0 .188 0.727 0.681 0.184 0.355 0.181 0.418 0.289 0.354 0.343 0.329 0.257 1.137 0.470 0.352 0.139 0.195 0.300 0.740 0.379 4.84 0.175 4.81 0.669 5.29 0.622 5.56 0.171 12.07 0.332 4.81 0.236 13.56 0.386 4.90 0.267 4.90 0.337 2.75 0.324 .2.94 0.310 3.22 0.265 7.90 1--.061 5.68.0.423 '.6.98 0.323 5.68 0.124 10.68 0.185 2.54 0,278 6 47 o 0 68 d4 77 Initial Calibration Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 3 Sample: EF2491-ICC2491 Lab FilelD: F46940.D 46) 1-Methylnaph 0.655 0.676 0.678 0.620 0.636 0.659 0,713 47) Dimethylnaph 0.565 0.591 0.601 0.541 0,552 0.578 0.633 0.662 4.56 0.580 5.38 48) I Acenaphthene-dlO
------------
ISTD ----------------------
- 49) Hexachlorocy 0.180 0.209 0.304 0.358 0.369 0.335 0.283 0.291 Linear regression Coefficient
= 0.9984 Response Ratio = -0.05128 + 0.37242 *A 50)51)52)53)54)55)56)57)58)2,4,6-Trichl 2,4,5-Trichl 2-Fluorobiph 2-Chloronaph Biphenyl 2-Nitroanili Dimethylphth Acenaphthyle 2,6-Dinitrot 0.324 0.369 1.530 1.222 1.692 0.239 1.184 1.782 0.369 0.401 1.522 1.229 2.699 0.305 1.256 1.899 0.397 0.438 1.507 1.212 1.663 0.341 1.289 1.991 0.278 0.395 0.433 1.523 1.177 1.598 0.297 1.220 1. 912 0.279 0.405 0.444 1. 537 1. 183 1.598 0.299 1.250 1. 961 0.285 0.392 0.435 1.491 1.182 1.617 0. 317 1.255 1.944 0.275 0.406 0.445 1.591 1.281 1. 763 0.349 1.331 2. 056 0.2670.162 0.221-Linear regression .....-Coefficient = 0.9997 Response Ratio = -0.00705 + 0.28508 *A 59) 3-Nitroanili 0.228 0.287 0.337 0.309'0.316 0.322 0.341 60) Acenaphthene 1.241 1.243 1.226 1.177 1.209 1.203 1.305 61) 2,4-Dinitrop 0.064 0.137 0.168 0.175 0.151 0.108----- Linear regression
Coefficient
= 0.9975 Response Ratio = -0.04432 + 0.17979 *A 62) 4-Nitropheno 0.141 0.170 0.165 0.170 0.173 0,167 63) Dibenzofuran 1.716 1.734 1.674 1.597 1.629 1.642 1,786 64) 2,4-Dinitrot 0.217 0.315 0.381 0.364 0.378 0.371 0.371 Linear regression
Coefficient
= 0.9993 Response Ratio = -0.00471 + 0.37513 *A.0.384 0.424 1.529 1.212 1.662 0.307 1.255 1.935 0.252 0.306 1.229 0.134 0.164 1.683 0.342 0.308 1.225 1.319 0.676 0.285 24 .99 7.56 6.68 2.06 3.03 3.70 11.70 3.72 4.41 17.95 12.65 3.31 31.28 7.28 3.94 17.45 13.81 4.67 3.81 2.56 14.31 27 .52 12. 75 3.24 5.51 11.21 5.52 2.88.11.48 3.43 3.31 9.16 i.66 6,56 5.63 65)66)67)68)69)2,3,4,6-Tetr Diethylphtha Fluorene 4-Chlorophen 4-Nitroanili 0.220 1.160 1.288 0.671 0.211 0.284 1.241 1.341 0.674 0.286 0.331 1.267 1.341 0.682 0.327 0.325 1.167 1.259 0. 655 0.271 0.339 0.329 0.328 1.195 1.227 1.320 1.2,88 1.303 1.411 0.675 0.662 0.710 0.267 0.303 0.328 70) I Phenanthrene-dlO
ISTD ---------------------
- 71) 4,6-Dinitro-0.058 0.106 0.132 0.135 0.117 0.089 0.106----- Linear regression
Coefficient
= 0.9973 Response Ratio = -0.01635 + 0.13942 *A 72)73)74)75)76)77)78)79)80)81)82)83)84)85)86)87)Atrazine n-Nitrosodip 1,2-Diphenyl 2,4,6-Tribro 4-Bromopheny Hexachlorobe Pentachlorop Phenanthrene Anthracene Carbazole Di-n-butylph Fluoranthene Octadecane I Chrysene-Benzidine Pyrene.0.096 0.533 0.749 0.068 0.188 0.205 0.146 1,214 1.149 0.922 0,793 0.989 0.384 0.121 0.563 0.772 0.082 0.205 0.210 0.112 1.210 1.228 0.993 1.063 1'.189 0.431 0.132 0.569 0.742 0,089 0.209 0.205 0.144 1.167 1.207 0. 977 1.144 1.170 0.420 0.110 0.556 0. 687 0.094 0.217 0,214 0.155 1.133 1.174 0.830 1.089 1.113 0.3399 0.206 0.562 0.716 0.097 0.224 0.222 0.161 1,169 1.202 0,810 1.114 1.161 0.391 0.118 0.134 0.559 0.595 0.705 0.805 0.090 0.087 0.210"0.216 0.209 0.217 0.154 0.136 1.153 1.250 1.192 1.273.0.904 1,039 1.128 1.142 1.181 1.211 0.397 0.447 0.117 0.563 0.739 0,087 0.210 0.212 0.144 1.185 i.204 0.925 1.068 1.145 0.410-d12---- ISTD-- -------------------- 0.127 0.189 0.231 0.165 0.153 0.205 0.221 1.205 1.323 1.315 1.313 1.314 1.291 1.357-.0 1847 ~65 o .1303 .63 Initial Calibration Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJPage 3 of 3 Sample: EF2491-1CC2491 Lab FilelD: F46940.D 88) Terphenyl-dl 0.815 0.908 0.914 0.919 0.929 0.895 0.934 89) Butylbenzylp 0.262 0.425 0.485 0.479 0.479 0.474 0.464----- Linear regression
Coefficient
= 0.9999 Response Ratio = -0.00607 + 0.48182 *A 0.902 4.48 0.438 18.29 90) Butyl steara 0.156 0.249 0.280 0.251 0.236 0.255 0.280 0.244 17.27----- Linear regression
Coefficient=
0.9966 Response Ratio = 0.00901 + 0.23987 *A 91)92)93)94)Benzo[ajantb 0.979 ).142 1.155 1.163 1.184 1,156 1.192 3,3'-Dichlor 0.256 0.313 0.363 0.337 0.320 0.363 0.347 Chrysene 1.181 1.187 1.162 1.139 1.156 1,128 1.241 bis(2-Ethylh 0.337 0.552 0.629 0.624 0.611 0.608 0.610----- Linear regression Coefficient = 0.9997 Response Ratio = -0.00528 + 0.61819 *A 2.139 0.329 1.171 0.567 95) 1 Perylene-d12
ISTD ---------------------
- 96) Di-n-octylph 0.477 1.060 1.414 1.439 1.419 1.399 1.238 1.206----- Linear regression
Coefficient
= 0.9998 Response Ratio = -0.04348 + 1.44516 *A 6.39 11.37 3.20 18.49 28 .98 9.67 4.40 10.81 16.11 97)98)99)100)Benzo[bjfluo 1.370 1.553 1.746 1.846 1.780 1.723 2.725 Benzo[k]fluo 1.675 1.822 1.811 1.684 1.851 1.848 1.856 Benzo~alpyre 1.196 1.482 1.592 1.630 1.689 1.639 1.604 Indeno[l,2,3 1.014 1.239 1.441 1.630 1,647 1.570 1.428-Linear regression
Coefficient
= 0.9994 Response Ratio = -0.07280 + 1.66364 *A 1.677 1.792 1.547 1.424 101) Dibenz(a,h)a 0.683 0.923 1-.099 1.275 1.286 1.210 1.065-Linear regression
Coefficient
= 0.9991 Response Ratio = -0.06856 + 1.30299 *A 102) Dibenz(a,h)a 0.878 1.058 1.255 1.421 1.441 1.366 1.245 Linear regression
. Coefficient
= 0.9993 Response Ratio = -0.06637 + 1.45402 *A 1.077 20,06 1,238 16.60 103)104)105)7,12-Dimethy 0.544 0.664 0.774 0.770 0.796 0.777 0.756 3-Methylchol Benzo[g,h,i] 0.826 1.008 1.164 1.358 1.368 1.309 1.162----- Linear regression
Coefficient
= 0.9992 Response Ratio = -0.06719 + 1.38666 *A 0.726 0. 000#1.1171 12.53-1.00 17 .04 (#) = Out of Range ### Number of calibration levels exceeded format fll MF2491.M Mon Dec 20 16:50:35 2004 RPTI 70-7 Continuing Calibration Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, N)Page 1 of 3 Sample: EF2492-CC2491 Lab FilelD: F46961.D Evaluate Continuing Calibration Report Data File : C:\MSDCHEM\l\DATA\EF2492D\F46961.D Acq On : 15 Dec 2004 8:54 am Sample : CC2491-50 Misc OP18812,EF2492, MS Integration Params: LSCINT.P Vial: 2 Operator: NINAP Inst : MSF Multiplr: 1.00 Method Title Last Update Response via: C:\MSDCHEM\I\METHODS\MF2491.M (RTE Integrator) Semi Volatile Extractables by GC/MS Mon Dec 20 09:17:47 2004 Multiple Level Calibration Min. RRF : 0.050 Min. Rel. Area 48% Max. R.T. Dev 0.50min Max. RRF Dev 20% Max. Rel. Area : 200%Compound AvgRF CCRF%Dev Area% Dev(min)R.T. 'V 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 I t t t S t S t t t t t t t t t t t t t t t t 1,4-Dichlorobenzene-d4 1,4-Dioxane Pyridine N-Nitrosodimethylamine
2-Fluorophenol Indene Cumene Phenol-d5 Phenol Aniline bis(2-Chloroethyl)ether Benzaldehyde 2-Chlorophenol Decane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Benzyl alcohol 1,2-Dichlorobenzene Acetophenone 2-Methyiphenol 2,2'-oxybis(l-Chloropropa 3&4-Methylphenol n-Nitroso-di-n-propylamin Hexachloroethane Naphthalene-d8 Nitrobenzene-d5 Nitrobenzene Quinoline Isophorone 2-Nitrophenol 2,4-Dimethylphenol Benzoic acid bis(2-Chloroethoxy)methan 2,4-Dichlorophenol 1,3,5-Trichlorobenzene
1,2,4-Trichlorobenzene 1,2,3-Trichlorobenzene alpha-Terpineol Naphthalene 4-Chloroaniline 2,3-Dichloroaniline 1.000 0.676 1.640 0.538 1.395 2.466 3.153 1.679 1.833 2.110 1.312 0.351 1.399 1,280 1.554 1.588 0.903 1.470 1.880 1.250 0.450 1.308 0.780 0.512 1.000 00.379 0.175 0 .669 0.622 0.171 0.332 0.236 0.386 0.267 0.337 0.324 0.310 0.265 1.061 0.423 0.323 1.000 0 .607 i.550 0 .502 1.344 2.429 3 .080 1.578 1.732 1 .950 1 .268 0 .430 1 .358 1.185 1.530 1.540 0.890 1.435 1.825 1.196 0.443 1.255 0.765 0.512 1.000 0.369 0.174 0.657 0.625 0.174 0.331 0.222 0.374 0.272 0.335 0.324 0.311 0.254 1.020 0.410 0.319 0.0 10.2 5.5 6.7 3.7 1.5 2.3 6.0 5.5 7.6 3.4-22.5#2.9 7.4 1.5 3.0 1.4 2.4 2.9 4.3 1.6 4.1 1.9 0.0 123 119 119 120 123 123 121 121'120 117 122 132 122 118 123 122 121 122 122 121 124 121 122 122 0.00-0.02-0.01-0.10 0.00 0. 00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00'.0.00 0.00 0.00 0.00 0.00 6.51 2.70 3 .02 2 .90 4.48 7 .04 5.22 5.94 5.96 5.99 6.09 5.74 6.18 6.27 6.44 6.54 6.82 6.89 7.35 7.09 7.13 7.40 7.42 7.50 25 I 26 S 27 t 28 t 29 t 30 t 31 t 32 t 33 t 34 t 35 36 t 37 38 t 39 t 40 t 41 t 0.0 2.6 0.6 1.8 1.1 0.3 5.9 3.1-1.9 0.6 0.0-0.3 4.2 3.9 3.1 1.2 123 0.00 118 0.00 120 0.00 122 0.01 123 0.00 118. 0.00 122 0.00 112 0,02 122. 0.00 124 0.00 124 '0.00"125 0.00 9 .14 7 .65 7.69 9.97 8 .19 8.37 8.51 8.87 8.72 8.88., 38 9.06 9.60 9.23.9.18 7 39.51 125 122 122 120 122 0.00 0.00 0:00 00D.O0 0.0. o Continuing Calibration Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 3 Sample: EF2492-CC2491 Lab File]D: F46961..D 4p 42 43 44 45 46 47 t t t t t t Caprolactam Hexachlorobutadiene 4-Chloro-3-methylphenol 2-Methylnaphthalene 1-Methylnaphthalene Dimethylnaphthalene 0.124 0.185 0.278 0.683 0.662 0.580 0.124 0.188 0.282 0.673 0.653 0.577 0.0-1.6-1.4 1.5 1.4 0.5 119 126 122 122 122 123 0.02 0.00 0.00 0.00 0.00 0.00 10.14 9.63 10.57 10.76 11. 01 12 .25 48 I Acenaphthene-dlO 1.000 1.000 0.0 122 0.00 13.24% Drift ------------ 6.3 120 0.00 11.32----------------------- True 49 t Hexachlorocyclopentadiene 100.000----------------------- AvgRF 50 t 2,4,6-Trichiorophenol 0.384 51 t 2,4,5-Trichlorophenol 0.424 52 S 2-Fluorobiphenyl 1.529 53 t 2-Chloronaphthalene 1.212 54 t Biphenyl 1.662 55 t 2-Nitroaniline 0,307 56 t Dimethylphthalate 1.255 57 t Acenaphthylene 1,935---------------------- True 58 t 2,6-Dinitrotoluene 50.000----------------------- AvgRF 59 t 3-Nitroaniline 0.306 60 t Acenaphthene 1.229----------------------- True 61 t 2,4-Dinitrophenol 100.000----------------------- AvqRF 62 t 4-Nitrophenol 0.164 63 t Dibenzofuran 1.683----------------------- True 64 t 2,4-Dinitrotoluene 50.000----------------------- AvqRF 65 2,3,4,6-Tetrachlorophenol 0.308 66 t Diethvlnhthalate 1.225 Caic.93.661 CCRF 0.399 0.432 1.501 1.180 1.602 0.290 1.271 1.943 Caic.45,963 CCRF 0.304 1.196 Caic.83.610% Dev-3.9-1.9 1.8 2.6 3.6 5;ý5-1.3-0.4 124 0.00 21.52 122 0.00 11.60 123 0.00 11.71 122 0.00 11.88 121 0.00 11.90 112 0.00 12.24 124 0.00 12 .81 122. 0.00 12.86% D r i f t ..........--8.2. 114 0.D0 12.93% Dev 0.7 2.7 115 0.00 13.24 121 0.00 13.32% Drift ------------ 16.4 107 0.00 13.48 CCRF 0.166 1.638% Dev-1.2 2.7 117 0.00 13.72 122 0.00 13.70 Calc.47.893 CCRF 0.335 1.239 1.312 0.678 0.274 67 68 69% Drift ------------ 4.2 117 0.00 13.84 t t t Fluorene 4 -Chlorophenyl -phenylethe 4-Nit roaniline% Dev-8.8'1.1 0.5-0.3 3.9 1.319 0.676 0.285 124 0.00 14.12 123 0.00 14.52 123 0.00 14.51 125 0.00 14,57 II! 0.01 14.71 70 1 Phenanthrene-dlO 1.000 1.000 0.0 123 -0.00 16.72% Drift ------------- 16.4 10.9 0.01 14.83.----------------------- True 71 t 4,6-Dinitro-2-methylpheno 50.000 72 73 74 75 76 77 78 79 t t t S t t t t---------------
Avg RF Atrazine 0.117 n-Nitrosodiphenylamine 0.563 1,2-Diphenyihydrazine 0.739 2,4,6-Tribromophenol 0.087 4-Bromophenyl-phenylether 0.210 Hexachlorobenzene 0.212 Pentachlorophenol 0.144 Phenanthrene 1.185 Calc.41.807 CCRF 0.110 0.556 0.689 0.091 0.215 0.214 0.154 1.158% Dev 6.0 1.2 6.8-4 .6-2.4-0.9-6.9 2 .3 115 0.00 16.30.122 0.00 14.,89 1 .20 0.00 .14:.95.124 0.00 15.1 126 0.00 15.72 126 0.00 16.02 123 0.00 16.47 123)., -0. 00o7i6.78 Continuing Calibration Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, Ni Page 3 of 3 Sample: EF2492-CC2491 Lab FilelD: F46961.D 80 81 82 8.3 84 85 86 87 88 t t t t t I t t S Anthracene Carbazole Di-n-butylphthalate Fluoranthene Octadecane Chrysene-dI2 Benzidine Pyrene Terphenyl-d14 1.204 0.925 1.068 1.145 0.410 1.000 0.184 1.303 0.902-----------------------
True 89 t Butylbenzylphthalate 50.000 90 Butyl stearate 50.000 91 92 93 t t t Benzo[a)anthracene 3,3'-Dichlorobenzidine Chrysene AvgRF 1.139 0.329 1.171 1.190 0. 810 1 .140 1ý173 0.388 1.000 0.155 1.315 0. 932 Calc.50.279 51.902 CCRF 1.173 0.337 1.129 Calc.50.320 CCRF 1.000 Caic.50.942 CCRF 1.698 1.884 1.600 Caic.48.121 46.928 47.397 1.2 12.4-6.7-2.4 5.4 0.0 15.8-0.9-3.3% Drift-0.6-3.8% Dev-3.0-2.4 3.6 123 110 124 122 120 118 89 120 123 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 16.88 17 .32 18.41 19.48 16.71 22.22 19 .82 19.92 20.33 119 0100 21.37 118 0.00 21.48 119 0.00 22. 19 109 0.00 22.20 118 0.00 22.26----------------------- True 94 t bis(2-Ethylhexyl)phthalat 50.000----------------------- AvgRF 95 I Perylene-d12 1.000---------------- 7------ True 96 t Di-n-octylphthalate 50.000% Drift -- --------0.6 119 0.00 22.47% Dev -------------- 0.0 115 0.00 24.56% Drift ------------ -1.9 118 0.00 23.45 97 98 99 t t t----------------------- AvgRF Benzo [b] fluoranthene
- 1. 677 Benzo [k] fluoranthene
- 1. 792 Benzo [a) pyrene 1.547-----------------------
True Indeno(i,2,3-cd]pyrene 50.000 Dibenz(a,h)acridine 50.000 Dibenz [a,h] anthracene 50. 000 Dev-1.3-5.1-3.4% Drift 3.8 6.1 5.2 113 0.00 23.95 117 0.00 23.99 112 0.00 24.46 113 0.00 26.63 111 0.00 26.15 il 0.00 26.67 100 t 101 t 102 t----------------------- AvgRF 103 t 7,12-Dimethylbenz(a)anthr 0.726 104 t 3-MethylCholanthrene CCRF % Dev ------------- 0.779 -7.3 115 0.00 23.99---------- NA ----------
True Caic. %Drift ------------ 105 t Benzo[g,h,i~perylene 50.000 48.237 3.5 112 0.00 27.23 () = Out of Range F46940.D MF2491.M SPCC's out = 0 CCC's out = 0 Mon Dec 20 11:13:59 2004 -.RPTI 0 ý 80 Continuing Calibration Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial lsland, Salem, NJ Page 1 of 3 Sample: EF2503-CC2491 Lab FilelD: F47279.D Evaluate Continuing Calibration Report Data File C:\MSDCHEM\I\DATA\EF2503\F47279.D Acq On : 31 Dec 2004 3:41 am Sample CC2491-50 1'Misc OP19139,EF2503,1000 MS Integration Params: LSCINT.P Vial: 2 Operator: NINAP Inst : MSF Multipir: 1.00 Method : C:\MSDCHEM\I\METHODS\MF2491.M (RTE Integrator) Title : Semi Volatile Extractables by GC/MS Last Update :Mon Dec 20 09:17:47 2004 Response via i Multiple Level Calibration Min. RRF : 0.050 Min. Rel. Area 48% Max. R.T. Dev 0.50min Max. RRF Dev : 20% Max. Rel. Area
- 200%Compound AvgRF CCRF %Dev Area% Dev(min)R.T.
........................................... ('y 1 1 2 t 3 t 4 t 5 S.6 t 7 t 8 S 9 t 10 t 11 t 12 t 13 t 14 t 15 t 16 t 17 t 18 t 19 t 20 t 21 t 22 t 23 t 24 t 25 I 26 S 27 t 28 t 29 t 30 t 31 t 32 t 33 t 34 t 35 36 t 37 38 t 39 t 40 t 41 t 1,4-Dichlorobenzene-d4 1,4-Dioxane Pyridine N-Nitrosodimethylamine 2-Fluorophenol Indene Cumene Phenol-d5 Phenol Aniline bis(2-Chloroethyl)ether Benzaldehyde 2-Chlorophenol Decane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Benzyl alcohol 1,2-Dichlorobenzene Acetophenone 2-Methylphenol 2,2'-oxybis(l-Chloropropa 3&4-Methylphenol n-Nitroso-di-n-propylamin Hexachloroethane Naphthalene-d8 Nitrobenzene-d5 Nitrobenzene Quinoline Isophorone 2-Nitrophenol 2,4-Dimethylphenol Benzoic acid bis(2-Chloroethoxy)methan 2,4-Dichlorophenol 1,3,5-Trichlorobenzene 1,2,4-Trichlorobenzene 1,2,3-Trichlorobenzene alpha-Terpineol Naphthalene 4-Chloroaniline 2,3-Dichloroaniline
- 1. 000 0.676 1.640 0.538 1.395 2.466 3.153 1.679 1. 833 2.110 1.312 0.351 1.399 1.280 1 .554 1 .588 0.903 1.470 1.880 1.250 0.450 1.308 0.780 0.512 1,000 0.379 0.175 0.669 0.622 0.171 0.332 0.236 0,386 0.267 0.337 0 .324 0. 310 0 .265 1.061 0 .423 0 .323 1.000 0.574 1.430 0.522 1.279 2.387 3.065 1.514 1.742 1.770 1.319 0.401 1.339 1.268 1.472 1.524 0.847 1.428 1.822 1.161 0.436 1.229 0.791 0.534 1.000 0.385 0.171 0.668 0.632 0.187 0.340 0.231 0.374 0.275 0.337 0.326 0.315 0.269 1.008 0.397 0.342 0.0 15.1 12.8 3.0 8.3 3.2 2.8 9.8 5.0 16; 1-0.5-14.2 4.3 0.9 5.3 4.0 6.2 2.9 3.1 7.1 3.1 6.0-1.4-4.3 0.0-1.6 2.3 0.1-1.6-9.4-2.4 2.1 3 .1-3.0*0. 0-0.6-1.6-1.5 5.0 6.1-5.9 146 134 131 149 139 144 143 138 145 127 151 146 144 151 141 a44 138 145 145 141 146 141 150 152-0.17-0.25-0.22-0.21-0.12-0.17-0.17-0.13-0.13-0.15-0.16-0.15-0.15-0.17
-0.17-0.17-0.16-0.17-0.17-0.15-0.17-0.15;-0.18-0.18 6.34 2.472 .80 2.79 4.35 6.87 5.06 5.80 5.83 5.84 5.93 5.59 6. 03 6.11 6.27 6.37 6.66 6.72 7.18 6.94 6.97 7.24 7.25 7.32 149 -0.18 8.96 150 -0.27 7.48 144 -0.17 7.52 150 -0.16 9.79 154 -0.17 8.02 154 -0.17 8.20 152 -0.16 8.35 141 -0.11 8..74 148 -0.17 8.54'152 -.0. 16 8.72 152 -0.18 8.21 153 -0.17. 8.89 154 -0.18 9.42 158 -0.17 9.06 146 -0.18 9.00 141 .0 17 9 22 150 ý- .AS1l1 33 Continuing Calibration Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 3 Sample: EF2503-CC2491 Lab FilMD: F47279.D'V 42 43 44 45 46 47 t t t t t t Caprolactam Rexachlorobutadiene 4-Chloro-3-methylphenol 2-Methylnaphthalene 1-Methylnaphthalene Dimethylnaphthalene 0.124 0.185 0.278 0.683 0. 662 0.580 0 .133 0.197 0 .294 0.687 0.674 0. 606-7.3-6.5-5.8-0.6-1.8-4.5 154 161 155 152 153 156-0.13-0.18-0.14-0.18-0.18-0.18 9.98 9 .45 10 .42 10.58 10. 83 12. 06.13 .05 48 I Acenaphthene-dlO 1.000 1.000 0.0 160 -0.18----------------------- True 49 t Hexachlorocyclopentadiene 100.000 50 51 52 53 54 55 56 57 t t S t t t t t 2,4, 6-Trichiorophenol 2,4,5-Trichlorophenol 2-Fluorobiphenyl 2-Chloronaphthalene Biphenyl 2-Nitroaniline Dimethylphthalate Acenaphthylene AvgRF 0.384 0.424 1.529 1.212 1.662 0.307 1.255 1.935 Caic.89.908 CCRF 0.393 0.435 1.464 1. 155 1.567 0. 332 1.277 1.892 Calc.52.751 CCRF 0.299 1.172% Dev-2.3-2.6 4.3 4.7 5.7-8.1-1.8 2.2 160 -0.17 11.35 160 -0.15 .11.45 157 -0.18 11.53 156 -0.18 11.70 155 -0.18 11.71 168 -0.17 12.07 163 -0.18 12.63 155 -0.19 12.67% Drift ------------ 10.1 150 -0.19 11.13----------------------- True 58 t 2,6-Dinitrotoluene 50.000------------------- AvgRF 59 t 3-Nitroaniline 0.306 60 t Acenaphthene 1.229% Drift ------------ -5.5 171 -0.17 12.75% Dev 2.3 4.6.........------ 148 -0.16 13.07 i56 -0.19 13.12-------------------- True Caic.61 t 2,4-Dinitrophenol 100.000 109.621% Drift ............ -9.6 190 -0.15 13.32----------------------- AvgRF 62 t 4-Nitrophenol 0.164 63 t Dibenzofuran 1.683----------------------- True 64 t 2,4-Dinitrotoluene 50.000 CCRF 0.164 1.621 Calc.53.311 CCRF 0.344 1.270 1.306 0.679 0.257% Dev 0.0 3.7 151 -0.13 13.59 158 -0.18 13.51% Drift ------------ -6.6 171 -0.16 13.68 65 66 67 68 69 t t t t 2,3,4,6-Tetrachlorophenol Diethylphthalate Fluorene 4-Chiorophenyl-phenylethe 4-Nitroaniline AvgRF 0.308 1.225 1.319 0.676 0.285% Dev-11.7-3.7 1.0-0.4 9.8 168 -0.17 13.95 165 -0.19 24.34 160 -0.19 14.32 164 -0.18 .14.39 136 -0.17 14.54 70 I Phenanthrene-dlO 1.000 1.000 0.0 165 -0.18 16.53----------------------- True Caic.71 t 4,6-Dinitro-.2-methylpheno 50.000. 54.938 72 73 74 75 76 77 78 79 t t t S t t t t---------------
.. AvgRF Atrazine 0.117 n-Nitrosodiphenylamine 0.563 1,2-Diphenylhydrazine 0.739 2,4,6-Tribromophenol 0.087 4-Bromophenyl-phenylether 0.210 Hexachlorobenzene 0 .212 Pentachlorophenol 0 .144 Phenanthrene
- 1. 185 CCRF 0.113 0.526 0.667 0.095 0.217 0.220 0.156 1.109 Drift-.9.9% Dev 3.4 6.6-9.7-9.2-3.3-3.8-8.3 6.4 199 -0.15 14.65 159 -0.1.7 16.12-156 -0.18 .14.71 257 -0 '18 14-.76 174 -0.18 14.95 171 -0.19 15.53 174 -0.18 15.83 166 -0.17 16.30 15 .-0.1S 16 58 Continuing Calibration Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Saiem, Anificial Island, Salem, NJ Page 3 of 3 Sample: EF2503-CC2491 Lab FilelD: F47279.D CV 80 81 82 83 84 85 86 87 88 t t t t t I t t S Anthracene Carbazole Di-n-butylphthalate Fluoranthene Octadecane Chrysene-d12 Benzidine Pyrene Terphenyl-d14 1.204 0. 925 1.068 1. 145 0.410 1.000 0.184 1.303 0.902 1.149 0.778 1.180 1.169 0.394 1.000 0.123 1.243 0.908 4.6 15.9-10.5-2.1 3.9 0.0 33.24 4.6-0.7% Drift-2.8-1.6% Dev 0.4 2.1 3.6 159 142 173 164 164 170 102 164 172-0.19-0.18-0.18-0.17-0.18-0.15-0.16-0.16-0.16 16.69 17.13 18.23 19.31 16.53 22.07 19.66 19.75 20.17 89 t 90----------------
True Butylbenzylphthalate 50.000 Butyl stearate 50,000 91 92 93 t t t Benzo(alanthracene 3,3'-Dichlorobenzidine Chrysene AvgRF 1.139 0.329 1.171-----------------------
True 94 t bis(2-Ethylhexy!)phthalat 50.000----------------------- AvqRF 95 1 Perylene-d12 1.000----------------------- True 96 t Di-n-octylphthalate 50.000 Calc.51.385 50.806 CCRF 1.134 0.322 1.129 Ca1c.54.940 CCRF 1.000 Calc.57.812 CCRF 1.897 1.655 1.602 Caic.47.158 48.275 46.678 CCRF 0.785 176 -0.16 167 -0.15 21.21 21.33 167 -0.15 22.03 151 -0.15 22.06 170 -0.15 22.11% Drift ------------ -9.9 188 -0.15 22.32% Dev ------------- 0.0 168 -0.17 24.39% Drift ------------ -15.6 197 -0.16 23.30 97 98 99 t t t Benzo [b] fluoranthene Benzo [kb fluoranthene Benzo [a] pyrene AvgRF 1.677 1.792 1.547% Dev-13.1 7.6-3.6% Drift 5.7'3. 5 6.6 185 -0.15 23.80 151 -0.15 23.84 165 -0.17 24.30 162 -0.24 26.39 167 -0.22 25.93 161 -0.25 26.43 100 t 101 t 102 t---------------
True Indeno(1,2,3-cd]pyrene 50.000 Dibenz(a,h)acridine 50.000 Dibenz[a,h)anthracene 50.000-----------------------
AvgRF 203 t 7,12-Dimethylbenz(a)anthr 0.726 104 t 3-Methylcholanthrene
True% Dev ---------8.1 170 -0.16 23.83------ NA ---------- Caic. % Drift ------------ 105 t Benzo[g,h,i]perylene 50.000 46.405 7.2 159 -0.27 26.96---------------------------------------------------------------------------
(#) = Out of Range F46940.D MF2491.M SPCC's out = 0 CCC's out = 0 Mon Jan 03 09:31:52 2005 RPT1 Q. 83 Continuing Calibration Summary Job Number: N85893Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 1 of 3 Sample: EF2504-CC2491Lab FilelD: F47325.D Evaluate Continuing Calibration Report Data File C:\MSDCHEM\I\DATA\EF2504\F47325.D Acq On : 4 Jan 2005 9:23 am Sample : CC2491-25 Misc : oP19067,EF2504, .1 MS Integration Params: LSCINT.P Vial: 3 Operator: NINAP Inst : MSF Multiplr: 1.00 Method Title Last Update Response via z Min. RRF Max. RRF Dev C:\MSDCHEM\I\METHODS\MF2491.M (RTE Integrator) Semi Volatile Extractables by GC/MS Mon Dec 20 09:17:47 2004 Multiple Level Calibration 0.050 Min. Rel. Area : 48% Max. R.T. Dev 0.50min 20% Max. Rel. Area
- 200%6F Compound AvgRF CCRF %Dev Area% Dev(min)R.T.
1 I '1,4-Dichlorobenzene-d4 1.000 1.000 0.0 112 -0.18 6.32 2 t 1,4-Dioxane 0.676 0.618 8.6 106 -0.12 2.59 3 t Pyridine 1.640 1.539 6.2 103 -0.13 2.89 4 t N-Nitrosodimethylamine 0.538 0.599 -11.3 126 -0.14 2.86 5 S 2-Fluorophenol 1.395 1.366 2.1 109 -0.13ý 4.35 6 t Indene 2.466 2.540 -3.0 112 -0.19 6.86 7 t Cumene 3.153 3.216 -2.0 113 -0.18 5.04 8 S Phenol-d5 1.679 1.801 -7.3 117 -0.13 5.81 9 t Phenol 1.833 1,855 -1.2 108 -0.13 5,83 10 t Aniline 2.110 1.864 11.7 94 -0.17 5.81 11 t bis(2-Chloroethyl)ether 1.312 1.436 -9.5 119 -0.18 5.92 12 t Benzaldehyde 0.351 0,704 -100.6# 133 -0.17 5.57 13 t 2-Chlorophenol 1.399 1,424 -1.8 110 -0.17 6.02 14 t Decane 1.280 1.357 -6.0 116 -0.18 6.10 15 t 1,3-Dichlorobenzene 1.554 1.553 0.1 110 -0.18 6.26 16 t 1,4-Dichlorobenzene 1.588 1.620 -2.0 114 -0.18 6.35 17 t; Benzyl alcohol 0.903 0.828 8.3 98 -0.17 6.65 18 t 1,2-Dichlorobenzene 1.470 1.532 -4.2 115 -0.19 6.71 19 t Acetophenone 1.880 1.967 -4.6 113 -0.19 7.16 20 t 2-Methylphenol 1.250 1.201 3.9 103 -0.15 6.94 21 t 2,2'-oxybis(1-Chloropropa 0.450 0.460 -2.2 112 -0.19 6.95 22 t 3&4-Methylphenol 1.308 1.294 1.1 10A -0.14 7.25 23 t n-Nitroso-di-n-propylamin 0.780 0.836 -7.2 114 -0.20 7.23 24 t Hexachloroethane 0.512 0.552 -7.8 118 -0.20 7.31 25 1 26 S 27 t 28 t 29 t 30 t 31 t 32 t 33 t 34 t 35 36 t 37 38 t 39 t 40 t 41 t Naphthalene-d8 Nitrobenzene-d5 Nitrobenzene Quinoline Isophorone 2-Nitrophenol 2,4-Dimethylphenol Benzoic acid bis(2-Chloroethoxy)methan 2,4-Dichlorophenol 1,3,5-Trichlorobenzene 1,2,4-Trichlorobenzene
1,2,3-Trichlorobenzene alpha-Terpineol Naphthalene 4-Chloroaniline 2,3-Dichloroaniline 1.000 0.379 0.175 0.669 0.622 0.171 0.332 0.236 0.386 0.267 0.337 0.324 0.310 0.265 1.061 0.423 0.323 1.000 0.401 0.180 0.687 0.687 0.190 0.345 0.196 0.393 0.277 0.351 0.340 0.329 0.291 1.081 0.390 0. 347 0.0-5.8-2.9-2.7-10.5-3.9 16. 9-3 '..7-4.2.'-4,9-6.1-9.8-1.9 7.8-7.4 112 115 ill 112 120 117 111 92 112.112 118 119 120 118 114-0.20 *8.94 -0.18 7.47-0.19 7.50 -0.20 9.76-0.19 7.99-0.18 8.18 -0.16 '8,35-0.20 8.65-0.19 .8.52-0.15 .8.73-0.20 8.129-0.19 8'.87-0.19 9.40-0.19 9.04-0.20 8.98 0.1 411. 32 Continuing Calibration Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 3 Sample: EF2504-CC2491 Lab FilelD: F47325.D 42 43 44 45 46 47 t t t t t t Caprolactam Hexachlorobutadiene 4-Chloro-3-methylphenol 2-Methylnaphthalene 1-Methylnaphthalene Dimethylnaphthalene 0.124 0.185 0.278 0.683 0.662 0.580 0.144 0.203 0.299 0.721 0.721 0.637-16.1-9.7-7.6-5.6-8.9-9.8 118 124 114 115 120 119-0.19-0.20-0.13-0.20-0.20-0.20 9.92 9.43 10.43 10.56 10.80 12,04 48 I Acenaphthene-dlO 1.000 1.000 0.0 121 -0.20 13.03----------------------- True 49 t liexachlorocyclopentadiene 50.000 50 51 52 53 54 55 56 57 t t S t t t t t----------------
AvgRF 2,4,6-Trichlorophenol 0.384 2,4,5-Trichlorophenol 0 .424 2-Fluorobiphenyl 1.529 2-Chloronaphthalene 1.212 Biphenyl 1.662 2-Nitroaniline 0.307 Dimethylphthalate 1.255 Acenaphthylene
- 1. 935-----------------------
True 58 t 2,6-Dinitrotoluene 25.000 Calc.44.165 CCRF 0.377 0.431 1.514 1.183 1.597 0.352 1.336 1.951 Calc.27.095 CCRF 0.311 1.213 Calc.47.487 CCRF 0.145 1.689 Calc.27.331 t Drift 11.7% Dev 1.8-1.7 1.0 2.4 3.9-14 .7-6.5-0.8% Drift-8.4 114 -0.20 11.11 115 -0.18 11.34 119 -0.14 11.46 121 -0.20 11.50 118 -0.20 11.68 116 -0.20 11.69 125 -0.18 12.05 125 -0.20 12.60 118 -0.21 12.65 129 -0,20 12.73 59 t 60 t----------------------- AvgRF 3-Nitroaniline 0.306 Acenaphthene 1.229%Dev ---1.6 112 1.3 119-0.18 13.05-0.21 13.10----------------------- True 61 t 2,4-Dinitrophenol 50.000----------------------- AvgRF 62 t 4-Nitrophenol 0.164 63 t Dibenzofuran 1.683----------------------- True 64 t 2,4-Dinitrotoluene 25.000% Drift 5.0 119 -0.18 13.29% Dev --11.6 103-0.4 122-0.04 13.68-0.21 13.49% Drift ------------- -9.3 127 -0.19 13.65 65 2,3,4,6-Tetrachlorophenol 66 t Diethylphthalate 67 t Fluorene 68 t 4-Chlorophenyl-phenylethe 69 t 4-Nitroaniline 70 I Phenanthrene-dl0 AvgRF CCRF 0.308 0.346 1.225 1.338 1.319 1.372 0.676 0.699 0.285 0.300 1.000 1.000% Dev-12.3-9.2-4 .0-3.4-5.3 126 -0.18 13.94 127 -0.22 14.30 124 -0.21 14.30 124 -0.20 14.37 ill -0.18 14.52 0.0 125 -0.21 16.50----------------------- True 71 t 4,6-Dinitro-2-methylpheno 25.000 Caic, 26.097% Drift-4.4 141 -0.19 14.61 72 73 74 75 76 77 78 79 t t t S t t t---------------
AvgRF CCRF Atrazine 0.117 0.128 n-Nitrosodiphenylamine 0.563 0.548 1,2-Diphenylhydrazine 0.739 0.725 2,4,6-Tribromophenol 0.087 0.095 4-Bromophenyl-phenylether 0.210 0.216 Hexachlorobenzene 0.212 0.220 Pentachlorophenol 0.144 0.146 Phenanthrene 1.185 1.129% Dev-9.4 2.7 1.9-9.2-2.9-3.8-1.4 4,7 120 120 122 132 129 134 126 121-0.20-0.21-0.21-0 .20-0.21-0.21-0 .19-0.21 16 .09 14.68 14 .74 14.93 15.51 15.80 Continuing Calibration Summary Job Number: N85893 Account: AGMPAL Arcadis Geraghty
& Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 3 of 3 Sample: EF2504-CC2491 Lab FilelD: F47325.D 80 t 81 t 82 t 83. t 84 t Anthracene Carbazole Di-n-butylphthalate Fluoranthene Octadecane 1,204 1.1930.925 0.898 1.068 1.182 1.145 1.1770.410 0.427 85 86 87 88 I t t S Chrysene-d12 Benzidine Pyrene Terphenyl-d14 1.000 0.184 1.303 0.902 1.000 0.136 1.246 0.904 0.9 2.9-10.7-2.8-4 .1 0.0 26. 1#4.4-0.2% Drift-4.8 -5.5% Dev 0.9-6.4 0.6 123 115 129 126 127 131 77 124 129-0.21-0.19-0.20-0.19-0.21-0.17-0.15-0.19-0.18 16.66 17.12 18.21 19.29 16.50 22.04 19.67 19.73 20.15----------------------- True 89 t Butylbenzylphthalate 25.000 90 Butyl stearate .25.000 91 92 93 t t t----------------------- AvgRF BenzoEalanthracene 1.139 3,3'-Dichlorobenzidine 0.329 Chrysene 1.171-----7.---------------- True 94 t bis(2-Ethylhexyl)phthalat 25.000----------------------- AvgRF 95 I Perylene-d12 1.000----------------------- True 96 t Di-n-octylphthalate 25.000 Calc.26.191 26.378 CCRF 1.129 0.350 1.164 Calc..27.877 CCRF 1.000 Cabc.29,830 CCRF 1.820 1,770 1.603 Caic.23.051 24.190 23.074% Drift ------------ -11.5 142 -0.17 22.30 134 -0.18 21.20 125 -0.17 21.31 128 -0.17 22.01 126 -0.16 22.04 131 -0.17 22..09% Dev 0.0 128 -0.19 24.37 % Drift ------------ -19.3 149 -0.17 23.28 97 98 99 t t t----------------------- AvgRF Benzo [b] fluoranthene
- 1. 677 Benzo (k] fluoranthene
- 1. 792 Benzola]pyrene 1.547-----------------------
True Indenol[,2,3-cd]pyrene 25.000 Dibenz (a,h)acridine 25.000 Dibenz [a, h anthracene 25.000% Dev-8.5 1.2-3.6% Drift 7.8 3.2 7.7 133 -0.18 23.78 125 -0.18 23.82 129 -0.19 24.27 126 -0.28 26.35 134 -0.26 25.89 126 -0.30 26.38 100 t 101 t i02 t----------------------- AvgRF 103 t 7,12-Dimethylbenz(a)anthr 0.726 104 t 3-Methylcholanthrene
True 105 t Benzo(g,h,ijperylene 25.000 CCRF ! Dev ----0.759 -4.5 125 -0.18 23.80---- NA---------- Cabc.22.277% Drift ---10,9 124 -0,32 26.91------------------------------------------------------------------
(#) = Out of Range F46943.D MF2491.M SPCC's out = 0 CCC'S'out ='0.Tue Jan 04 09:56:23 2005 RPTi..)86 Data File C:\MSDCHEM\I\DATA\EF2503\F47282.D Vial Acq On : 31 Dec 2004 6:05 am Operator Sample : N85893-1 Inst Misc : oP19011,EF2503,l000 Multiplr MS 'ntegration Params: LSCINT.P Time: Dec 31 06:33:44 2004 Quant.Results File Quant Method C:\MSDCHEM\1\METHODS\MF2491.M (RTE Integrator) Title : Semi Volatile Extractables by GC/MS Last Update : Mon Dec 20 09:17:47 2004 Pe:';onse via : Initial Calibration
- .<CaAcq Meth : MF2491 27 NINAP MSF 1. 00: MF2491.RES Internal Standards----------------------------
- 1) 1,4-Dichlorobenzene-d4
- 25) Naphthalene-d8
- 48) Acenaphthene-dl0
- 70) Phenanthrene-dlO
- 85) Chrysene-dl2
- 95) Perylene-d12 System Monitoring;-Compounds
- 5) 2-Fluorophenol Spiked Amount 50.000 8) Phenol-d5 Spiked Amount 50.000 26) Nitrobenzene-d5 Spiked Amount 50.000 52) 2-Fluorobiphenyl Spiked Amount 50.000 75) 2,4,6-Tribromophenol piked Amount 50.000.) Terphenyl-d14 Spiked Amount 50.000 R.T. QIon Response Conc Units Dev(Min)------------------.....................------
6.34 8.96 13.04 16.52 22.06 24.38 152 136'164'188 240'264 393345 1544503 829676 1437523 1405309 908747 40.00 40.00 40.00 40.00 40.00 40.00 ppb ppb ppb ppb ppb ppb-0. 17-0.18-0.19-0.19-0.16-0.18 4.33 112 276735m 20.17 Recovery 5.79 99 232729 14.09 Recovery 7.47 82 513061 35.06 Recovery =11.52 172 a038490 32.75 Recovery =14.94 330 134730 43.17 Recovery 20.17 244 1327919 41.90 Recovery =ppb -0. 14 40.34%ppb -0.15 28.18%ppb -0.18 70.12%ppb -0.19 65.50%ppb -0.19 86.34%ppb -0.16 83.80%Target Compounds Qvalue (W) = qualifier out of range (m) manual integration (4) = signals summed I- --- )nnr. V r5 I Pp = , Data File C:\MSDCHEM\I\DATA\EF2503\F47282.D Acq On 31 Dec 2004 6:05 am Sample : N85893-1 Misc : OP19011,EF2503,1000 MS Integration Params: LSCINT.P luant Time: Jan 3 10:21 2005 Qu Vial: Operator: inst Multiplr: 27 NINAP MSF 1.00 ant Results File: MF2491.RES 'Method Title Last Update Response via C:\MSDCHEM\I\METHODS\MF2491.M (RTE Integrator) Semi Volatile Extractables by GC/MS Mon Dec 20 09:17:47 2004 Initial Calibration Abundance 1 3200000 TMC: F47282.D 3000000 2800000 2600000 2400000 il I i I-220000C 200000i L.f, C i 06 1800000 1600000 1400000 1200000 100000 800000 600000 V z.C 0D (C Ci E C ,r."6 (N 4 00000 J0000 WCi'9 Z8 (L kýji __ Ii 1200 14.00 16,00 18.00 20.00 22.00 24.00 26.00 Tie*> .00- 6.00 _8.00 _10.00 P4-10po n mrlýdqi M M -.'Y P , r),ý 1 0 -') I -') -1 ')Or),, 0'rC. 0 Data File : C:\MSDCHEM\I\DATA\EF2503\F47283.D Vial Acq On : 31 Dec 2004 6:41 am Operator Sample : N85893-2 Inst Misc : OP19011,EF2503,1000 Multiplr MS Tntegration Params: LSCINT.P 4 : Time: Dec 31 07:09:45 2004 Quant Results File nt Method : C:\MSDCHEM\I\METHODS\MF2491.M (RTE Integrator) Title Semi Volatile Extractables by GC/MS Last Update : Mon Dec 20 09:17:47 2004 Response via : Initial Calibration DataAcq Meth : MF2491 28 NINAP MSF:1.00: MF2491.RES Internal Standards 1) 1,4-Dichlorobenzene-d4
- 25) Naphthalene-d8
- 48) Acenaphthene-d10
- 70) Phenanthrene-dl0
- 85) Chrysene-d12
- 95) Perylene-d12 System Monitoring Compounds 5) 2-Fluorophenol Spiked Amount 50.000 8) Phenol-d5 Spiked Amount 50.000 26) Nitrobenzene-d5 Spiked Amount 50.000'52) 2-Fluorobiphenyl Spiked Amount 50.000 75) 2,4,6-Tribromophenol Spiked Amount 50.000 3) Terphenyl-d14 Spiked Amount 50.000 R.T. QIon Response Conc Units Dev(Min)6.33 8.96 13.04 16.52 22.06 24 .38 152 136 164 188 240 264 401821 1595622 839326 1453838 1429040 905723 40.00 40.00 40.00 40.00 40.00 40.00 ppb ppb ppb ppb ppb ppb-0.17-0.18-0.19-0.19-0.16-0.18 4.33 112 256317 18.29 Recovery =5.79 99 285398 16,92 Recovery =7.47 82 641688 42.45 Recovery =11.52 172 1267637 39.52 Recovery =14.94 330 140646 44.56 Recovery =20.17 244 1449300 44.98 Recovery ppb -0.14 36.58%ppb -0.15 33 .84%ppb -0.18 84 .90%ppb -0.19 79 .04%ppb -0.19 89.12%ppb -0.16 89.96%Target Compounds Qvalue(W) = qualifier out of range (m) = manual integration
(+) = signals summed V=-- Data File : C:\MSDCHEM\l\DATA\EF2503\F47283.D Acq On 31 Dec 2004 6:41 am Sample N85893-2 Misc : OPI9011,EF2503,1000 MS Integration Params: LSCINT.P)uant Time: Jan 3 10:22 2005 Qu.Vial: Operator: Inst Multiplr: 28 NINAP MSF 1.00 ant Results File: MF2491.RES Method Title Last Update Response via C:\MSDCHEM\I\METHODS\MF2491.M (RTE Integrator) Semi Volatile Extractables by GC/MS Mon Dec 20 09:17:47 2004 Initial Calibration Abundance 320000 TIC: F47283.D 3000000 2800000 6'I, 0-2600000 2400000 2200000 JO00000 180000 1600000 14000 12000001 o 0 ,2r CL 10.&5 2-10 9 0n.2 100000C 80000C 600000 400000-2o00000.2 04 Cj c CL 0L90 A I Time--> 4 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.0.00 22.00 24.00 .26.0 I..-.... .T ... .. ........ .. .... ....... ........ -._ ... -... _. _ ..-... .. .. ... .T;1679 q n MT;,?A0 W.M-, .-T=- ()'ý >Or)q VT)rri ID=-- Data File C:\MSDCHEM\I\DATA\EF2492\F46968.D Acq On : 15 Dec 2004 1:11 pm Sample : OP19011-MBI Misc : oP19011,EF2.492,1000 MS Integration Params: LSCINT.P Qup-t Time: Dec 15 14:42:36 2004 Qu Cnt Method : C:\MSDCHEM\l\MET}iODS\MF249i.M Title Semi Volatile Extractables by Last Update Wed Dec 15 14:17:29 2004 Via!: Operator: Inst Multiplr: 9 NINAP MSF 1.00 ant Results File: MF2491.RES (RTE Integrator) GC/MS Response via DataAcq Meth Initial Calibration MF2491 Internal Standards R.T. QIon Response Conc Units Dev(Min)1)25)48)70)85)95)1,4-Dichlorobenzene-d4 Naphthalene-d8 Acenaphthene-dlO Phenanthrene-dlO Chrysene-dl2 Perylene-d12 6.50 9.13 13.23 16.71 22.21 24.56 152 136 164 188 240 264 319360 1213909 605159 1036319 896441 517876 40.00 40.00 40.00 40.00 40.00 40.00 ppb ppb ppb ppb ppb ppb 0.00 0.00 0.00 0.00 0.00 0.00 System Monitoring Compounds 5) 2-Fluorophenol Spiked Amount 50.000 8) Phenol-d5 Spiked Amount 50.000 26) Nitrobenzene-d5 Spiked Amount 50.000 ,52) 2-Fluorobiphenyl Spiked Amount 50.000 75) 2,4,6-Tribromophenol Spiked Amount 50.000) Terphenyl-d14 -.piked Amount 50.000 Target Compounds 4.47 112 205627 18.46 Recovery =5.93 99 210276 15.68 Recovery =7.64 82 401912 34.95 Recovery 11.70 172 802254 34.69 Recovery =15.12 330 80916 .35.96 Recovery 20.33 244 837013 41.41 Recovery =ppb 0.00 36.92%ppb 0.00 31.3.6%ppb 0.00 69.90%ppb 0.00 69.38%ppb 0.00 71.92%ppb 0.00 82.82%Qvalue ~P9, (4i) = qualifier out of range (m) = manual integration H-) = signals summed Data File C:\MSDCHEM\I\DATA\EF2492\F46968.D Acq On : 15 Dec 2004 1:11 pm Sample : OPl9011-MBi Misc : OPl9011,EF2492,1000 MS Integration Params: LSCINT.P-'.ant Time: Dec 15 14:43 2004 Qu Vial: Operator: Inst Multiplr: 9 NINAP MSF 1.00 ant Results File: MF2491.RES C. ethod Title Last Update Response via[,bundance C:\MSDCHEM\I\METHODS\MF2491.M (RTE Integrator) Semi Volatile Extractables by GC/MS Wed Dec 15 14:17:29 2004 Initial Calibration MlC: F46968.D 2000000 1900000 1800000 1700000 1800000 6 A 0.0 2 6E z I.1500000 1400000 130000C CL QrOOOC 1100000 1000000 900000 800000 C a 0)700000 600000 500000 400000 300000 200000 r00000 0 Time-(J~.a C F'S (0 e.i U, a E Co ta-Lýi I 1.I[92.. .............] I J I 4 i .00 .I 6 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 V49QAP T-) M v *') A Q 1 M.W-A ný' I ý' 1 A .4 I n ?nnA Q ID-. I Oar, o Data File : C:\MSDCHEM\I\DATA\F46968.D Acq On 15 Dec 2004 1:11 pm Sample OP19011-MBI Misc oP19011,EF2492,1000 MS Integration Params: LSCINT.P Vial: 9 Operator: NINAP Inst : MSF Multiplr: 1,00ý .od : C:\MSDCHEM\I\METHODS\MF2491.M (RTE Integrator) w.le : Semi Volatile Extractables by GC/MS Smoothing
- ON Filtering:
5 Sampling : I Min Area: 1000 Area counts Start Thrs: 0.05 Max Peaks: 125 Stop Thrs : 0 Peak Location: TOP If leading or trailing edge < 100 prefer < Baseline drop else tangent >Peak separation: 5 Signal TIC peak R.T.f min 1 3.240 2 3.486 3 3.544 4 3.705 5 4.004 6 4.047 7 4.180 4.426 4.474 10 4.7894.923 5.729 13 5.756 14 5.927 15 6.194 16 6.290 17 6.504 18 6.696 19 7.337 20 7.642 21 7.786 22 7.856 23 8.561 24 8.988 25 9.132 26 9.266 27 9.752 28 9.854 29 10.922 30 11.024 31 11.333 32 11.499 33 11.702 3 -11.755 4w 11.787 36 11.841 37 11.878 38 12.023 first s can 159 201 212 242 298.307 335 375 385 443 472 618 629 650 709 717 756 802 922 974 1006 1021 1152 1231 1253 1283 1375 1390 1591 1613 1669 1699 1734 1752 1758 1768 1776 1800 max scan 161 207 218 248 304 312 337 383 392 451 476 627 632 664 714 732 772 808 928 985 1012 1025 1157 1237 1264 1289 1380 1399 1599 1618 1676 1707 1745 1755 1761 1771 1778 1805 last scan 180 211 219 257 307 328 342 385 411 458 479 629 639 682 717 745 786 812 934 1006 1019 1029 1161 1241 1280 1297 1387 1408 1606 1623 1686 1713 1752 1758 1768 1776 1785 1806 PK peak TY height rVB8 4702 rBV7 1738 rBV4 2084 rVB5 2688 rBV 66121 rVB2 82632 rVB2 1090 rBV 121764 rVB 203756 rVB4 1465 rVB4 803 rBV5 932 rVB6 926 rVB 242435 rVB3 1084 rBVI0 7800 rBV 708561 rBV3 738 rBV3 988 rBV 631246 rVV7 1347 rVB4 1322 rVB2 2775 rVB3 1298 rBV 1395563 rVB 7331 rBV2 1527 rBV 50427 rVB2 5705 rBV3 1248 rVB 6623 rBV3 849 rBV 1434801 rVV2 6325 rVV3 9861 rVV3 2108 rVB 1966 rBV2 728 corr.area 14860 3750 3028 6828 103959 255107 1440 198687 653393 3882 1197 2132 1767 539556 1594 20263 1881777 1036 1589 1130078 3532 1405 3959 1727 2332843 11771 2428 75081 9697 1926 9326 1787 2273686 10209 17762 3749 2819 1077 corr.% max.0.56%0.14%0.11i%0.26%3.90%9.58%0. 05%7.46%24.53%0,15%0.04%0.08%0.07%20.25%0.06%0.76%70. 64%0.04%0.06%42.42%0.13%0.05%0.15%0.06%87.57%0.44%0.09%2.82%0.36%0.07%0.35%0.07%85.35%0,38%0,67%0.14%0.11%0.04%% of total 0.065%0.017%0.013%0.030%0.458%1.124%0. 006%0.875%2.879%0.017%0.005%0.009%0.008%2.377%0.007%0.089%8.292%0.005%0.007%4.979%0.016%0.006%0.017%0.008%10.279%0.052%0.011%0.331%0.043% 0.008%0.041%0.008%10.019%0.045%0.078%0.017%0.012%0.005%P4 ;qrR .1) MF'24 91 .M W H nA Tr. I c' 14:5F):3R 2004 40 12.226 1835 1843 1848 rVB4 1455 zubb U.Uot U. uvliz 41 12.300 1851 1857 1862 rBV3 1429 2126 0.08% 0.009%42 13.230 2020 2031 2044 rBV 1551464 2537648 95.26% 11.182%43 13.363 2053 2056 2066 rVB2 1112 1782 0.07% 0.008%44 13.454 2071 2073. 2081 rVB3 965 1546 0.06% 0.007%4 13.529 2081 2087 2097 rBV 19208 26410 0.99% 0.116% 13.609 2097 2102 2111 rBV3 1469 2290 0.09% 01010%47 13.807 2135 2139 2146 rBV3 1142 1477 0.06% 0.007%48 14.480 2260 2265 2270 rBV2 833 1219 0.05% 0.005%49 14.523 2270 2273 2285 rVB4 1038 2149 0.08% 0.009%50 15.068 2369 2375 2376 rBV3 658 1066 0.04% 0.005%51 15.116 2376 2384 2402 rVB 472282 750110 28.16% 3.305%52 15.324 2416 2423 2433 rBV3 1609 4087 0.15% 0.018%53 15.623 2470 2479 2481 rBV2 591 1117 0.04% 0.005%54 15.725 2492 2498 2502 rVB2 1443 2125 0.08% 0.009%55 15.810 2502 2514 2519 rBV2 28172 45125 1.69% 0.199%56 15.858 2519 2523 2531 rVB2 2019 3580 0.13% 0.016%57 15.933 2531 2537 2544 zBV5 1738 3620 0.14% 0.016%58 15.992 2544-2548 2553 rVB3 1220 1894 0.07% 0.008%59 16.104 2562 2569 2572 rBV 1087 1591 0.06% 0.007%60 16.195 2582 2586 2591 rBV2 1161 1675 0.06% 0.007%61 16.286 2598 2603 2609 rBV 3103 5029 0.19% 0.022%62 16.414 2619 2627 2635 rVB2 11190 19591 0.74% 0.086%63 16.708 2671 2682 2695 rBV2 1475986 2664029 100.00% 13.739%64 16.815 2695 2702 2713 rVB 13464 24512 0.92% 0.108% 65 17.124 2750 2760 2766 rVB3 5375 7899 0.30% 0.035%66 18.262 2965 2973 2980 rBB3 1459 2264 0.08% 0.010% 6'7 18.396 2989 2998 3008 rVB 26834 38210 1.43% 0.168%18.626 3034 3041 3047 rBV4 3597 6436 0.24% 0.028%fm 18.690 3047 3053 3057 rVB3 2283 3400 0.13% 0.015% 19.032 3112 3117 3124 rBB2 2466 3126 0.12% 0.014%71 19.256 3155 3159 3161 rBV 832 1095 0.04% 0.005%72 19.454 3187 3196 3200 rBB2 1136 1658 0.06% 0.007%73 19.758 3247 3253 3257 rVB 814 1309 0.05% 0.006%74 20.148 3321 3326 3332 rBV 8832 11583 0.43% 0.051%75 20.202 3332 3336 3339 rVB3 1438 1412 0.05% 0.006%76 20.239 3339 3343 3349 rBV 853 1634 0.06% 0.007%77 20.330 3349.3360 3372 rBV 1745067 2472166 92.80% 10.893%78 20.640 3412 3418 3425 rVE 1041 1694 0.06% 0.007%79 20.773 3435 3443 3447 rBV2 519 1178 0.04% 0.005%80 21.275 3530 3537 3541 rBV 864 1354 0.05% 0.006%81 21.478 3565 3575 3580 rBV2 6069 8875 0.33% 0.039% 82 21.542 3584 3587 3595 rVB2 872 1840 0.07% 0.008%83 21.713 3612 3619 3623 rBV2 5258 7324 0.27% 0.032%84 22.130 3694 3697 3702 rBV3 830 1366 0.05% 0.006%85 22.210 3702 3712 3727 rBV 1693411 2467321 92.62% 10.8721%86 22,467 3754 3760 3762 rBV3 3827 5037 0.19% 0.022%87 22.504 3762 3767 3776 rVB2 15704 22801 0.86% 0.1001 88 22.825 3822 3827 3835 rBV4 1484 2635 0.10% 0,012%89 23.076 3867 3874 3881 rBV4 1029 1874 0.07% 0.008%'90 23.156 3886 3889 3894 rBV2 945 1026 0.04% 0.005%23.364 3922 3928 3940 rBV2 12408 23045 0.87% 0.102%23.492 3948 3952 3956 rVB3 1353 1315 0.05% 0.006%23.792 4001 4008 4012 rBV4 1811 2824 0.11% 0.012% .94 94 24.059 4055 4058 4065 rVB3 640 1107 0.04% 0.005%95 24.246 4092 4093 4099 rBV3 719 1048 0.04% 0.005%r4 f; AP , D WlF24 q I .M WPH Der. 15 14:56:3S 2004 fl RPTI 96 24.310 4099 4105 4106 rBV4 1165 1419 0.05% 0.006%97 24.443 4123 4130 4139 rBV2 5778 11597 0.44%, 0.051%98 24.555 41.39 4151 4171 rVV2 1082603 1869842 70.19% 8.239%99 24.726 4180 4183 4190 rBV4 760 1217 0.05% 0.005%100 24.897 4213 4215 4221 rBV4 722 1206 0.05% 0.005%10" 25.512 4325 4330 4332 rBV3 821 1142 0.04% 0.005%4 26.131 4441 4446 4450 rBV3 710 1087 0.04% 0,005%26.383 4489 4493 4496 rBV4 752 1039 0.04% 0.005%Sum of corrected areas: 22694764 95 F4 6q (R. -) YF24ql .M Wp- nf-r- 15 14:5ý;::R 2,nn4 PPTI P; nf 3 LSC Report -Integrated Chromatogram File C:\MSDCHEM\I\DATA\F46968.D' Operator : NINAP Acquired 15 Dec 2004 1:11 pm using AcqMethod MF2491 Instrument
- MSF Sample Name: OP19011-MBl Misc Info : OP19011,EF2492,1000 Vial Number: 9 Quant File :MF2491.RES (RTE Integrator)
...u.d.... fl- C": F4"6"968.'D" 16OOOO0 1409.13 1.200000 10o0O S800000 6.50 7.64 400000 2 4475693 OL~ 4. 3 1 3_24.70V 18 4.W92 5 6. 6.70 7.34 777.6 8.56 8.9 .27 Z.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7,50 8.00 50 9.00 9. 10.00 10,50 Abundance TIC: F46968.D 160000 13.23 11.70 1671 1200000 1000000 8400000 1DOOOOO 60000 15.12 40DO PZ211 .ýq. AtBaZ230 IL NZ8 1W,4E 15 75.3215 ff4 6.8117.12
- 18. 19.0m.Time-- 1100 '1.50 12.00' 125 13.00 '13."5 '14.00 14.50 15.00 15.50 16.50 17.00 17.n50 '1'800' 1850 19.00 Abundance TIC: F46968.D 2C 33 Z 21 1600000 1400000 1200000 24.56 100000 80=00!.600000 400000 O19.76 f .21.2I4BI71
- 22. 3V..:22.8223);O E 3.794.GM42, 4.27.90 25.51 C ' 1 i i i i i i i i l i l l , l l i ~ i 'i l i 1 i i i / , i i i i i i i i i i t ,i i i i , Time--> 19.50 20.00 20.50 21.00 21.50 22.00 22:50 23.00 23:50 24:00 24.50 25.00 25.50 2&,00 26.50 27.00 27.50 P 4 6 C) C, Ci .D MF?.4 q1 .M W9~R3 NP2.jqlj 15 4:S,:iPp.PlAn(-. -
Data File : C:\MSDCHEM\I\DATA\F46968.D Acq On 15 Dec 2004 1:11 pm Sample : oP19011-MBI Misc : OP19011,EF2492,1000 MS Integration Params: LSCINT.P Vial: 9 Operator: NINAP Inst : MSF Multiplr: 1.00 at Method : C:\MSDCHEM\1\METHODS\MF2491.M (RTE Integrator) Wtie Semi Volatile Extractables by GC/MS Library : C:\DATABASE\NIST98.L Peak Number 1 2-Pentanone, 4-hydroxy-4-me... Concentration Rank. 1 R.T. EstConc Area Relative to ISTD R.T.4.05 4.37 ppb 255107 Naphthalene-d8 9.13 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 2-Pentanone, 4-hydroxy-4-methyl-116 C6H1202 000123-42-2 72 2 Propane, 2-methyl-2-(1-methyleth... 116 C7H160 017348-59-3 38 3 2-Pentanone, 4-hydroxy-4-methyl-116 C6H1202 000123-42-2 38 4 Oxirane, 3-ethyl-2,2-dimethyl-100 C6H120 001192-22-9 25 Abna C'a~n 3'1*2 ('4.0'47 mi): F46968,D (-307) ()m/z 43.10 100.00%: 43 59 5D00.101 38 80 4. 4,40_ _37,1_1_ 53 _ _ 8 m/z 59.20 63 05!V 6rnz-> 10 20 30 40 50 60 70 80 90 100 110 NbundanlcE
- 10975.: 2-Pentanone, 4-hydroxy-4-methyl-43 p 5000 59 37, 93 101............ql*,q .........I. ....W. .., .....I. ,J,. .'z- > 10 20 30 40 50 60 70 80 90b10010 5000 41 101[1 .. 53 73 86 im/z--> 10 ...20'.. 3'0 ...40 ...50' 6'0' 70 .80 9b.0 100 '110 5000 15 101 i25,,,37,1..
53; 83 3.80 400 4 440 m/z 101.10 27. 34%ý-, 3.80 4.00 4.20 4.40 mlz 58.15 23 62V 3.80 4.0 4.20 4 .40 m/z 41, 20 703 380.......... 400..--4.20 .. 4.40....'ýO ..... 5 1 0 60 7 .0 9b 11 10 2'0 40 1.......... .................................... ...... I ...... ...................... ................. ................... I ................. )perator ID: NINAP Date Acquired: 15 Dec 2004 1:11 pm)ata File: C:\MSDCHEM\I\DATA\F46968.D lame: OP19011-MB1 lisc: OP19011,EF2492,1000 4ethod: C:\MSDCHEM\!\METHODS\MF2491.M (RTE Integrator) N' Semi Volatile Extractables by GC/MS z-y Searched: C:\DATABASE\NIST98.L 1--Internal Standard---I TIC Top Hit name RT EstConc Units Response # RT Resp Concl-------------------------------------------------------------------------------- 2-Pentanone, 4-hy... 4.05 4.4 ppb 255107 2 9.13 2332840 40.0 Pb,MPN24q1 M WpdDci lS 2004 RPT1 P;;n P New Jersey g1ACCUTEST" Laboratories 01112105 Arcadis Geraghty & Miller PSEG-Salem, Artificial Island, Salem, NJ NP000571 Accutest Job Number: N86261 Sampling Date: 12/13/04 Report to: Arcadis Geraghty & Miller 6 Terry Drive Newtown, PA 18940 ATTN: Brad Pierce Total number of pages in report: 137 Test results contained within this data package meet the requirements of the National Environmental Laboratory Accreditation Conference and/or state specific certification programs as applicable. incent 3. P President Certifications: NJ(12129), NY(10983), CA, CT, DE, FL, IL, IN, KS, KY, LA, MA, MD, MI. MT, NC, PA.RI, SC, TN, VA, WVThis report shall not be reproduced, except in its entirety, without the wrirten approval of Accutest Laboratories. New Jersey i 2235 Route 130 a Dayton, NJ 08810 " tel: 732-329-0200 a fax: 732-329-3499 a http;:www.accutestcom Accutest Laboratories tv Sample Summary Arcadis Geraghty & Miller PSEG-Salem, Artificial Island, Salem, NJ Project No: NP000571 Sample Collected. " Number Date Time By Received C N86261-1 .12/13/04 13:55 RM 12/15/04 A N86261-2 12/13/04 15:35 RM 12/15/04 A N86261-3 12/13/04 17:15 RM 12/15/04 A N86261-4 12/13/04 18:05 RM 12/15/04 A N86261-5 12/13/04 18:05RM 12/15/04 A N86261-6 12/13/04 17:I5RM 12/15/04 A Job No: N86261 latrix ode Type iQ Ground Water ,Q Ground Water ,Q Ground WaterField Blank WaterTrip Blank WaterGround Water Client Sample ID WELL AY WELL AV WELL X FB-2 TRIP BLANK WELL AX I e 2 9 9ACCUTEST. Table Of Contents Reduced Laboratory Data Deliverables For Non-USEPA/CLP Methods Title/Cover Palze Table Of Contents Section I General A. Results Summary B. Chain of Ciittody C. Sample Tracking Chronicle/Method References. Section 2 GC[MS Support Data (grouped by fraction)A. Conformatice/Non-conforrnane Surnmary B. Method Blank Summar C. Blankc Spike Summary" D. Matrix Spike/Matrix Spike. Duplicate Summary E. Tufie Results Summary F. Ifittmal Standard Summary
- 0. Surrogate Recovery Results Summary 14. C4.ibration Summary (sorted by Instrumnent)
I. initial Calibration Check Summary Continuing Calibration Check Sumrary J.. Sample and Blank Chromatogramsi Quant Reports, Mass Spectra, and Library Search Data Section 3 GC Suppoý Data A. Conformance/Non-conformance Surrmary B. Method Blank Summary C. Blank Spike SummaryD. Matrix Spike/Matrix Spike Duplicate Surnritary E. Surrogate Recovery Results Summary F. Calibration Summary (sorted by Instrument) Initial Calibration Check SummaryContinuing Calibration Check Summary G. Retention Time Shift Summary H. Sample, Blank and Multi-peak Standtid Chromatograms and Quant Reports Section 4 Metals Support Data (sorted by Instrument Type-ICP, Furnace, Flame, and'Mercury) A. ConforriAhce/Non-conformance Summary B." initial and Continuin g Calibration Blank-C. initiai and Continuing Calibratioh Checks D. High and Low Check Standards E. Intertering Element Check Standards F. Method Blank Summary G.. Matrix Spike and Duplicates Summary H. Blank Spike and Lab Control Sample Summary I. Serial Dilution Summary Section 5 General Chemistrv/Petroleusn Hydrocarbon Support Data A, Conformance/Non-Conformance Summary B. Batch Quality Control Summary Method Blank and Spike Blank Results Summary Duplicate Results Surmmary Matrix Spike Results Sumrnary C. Raw Data and IR Spectra (Petroleum Hydrocarbons) D. Raw Data and Rim Record (Hexavalent Chromium)New Jersey F iresh Ponds.Corporate Village Building B " 2235 Route 30 1 Dayton, NJ 098t0 Teh 732.329.0200 Fax; 732.329.3499 "*/*,npVWvw.accutestcom RedTir2 12/29/2004 3%W RESULTS 4 Accutest Laboratories Report of Analysis Page I of 2 Client Sample ID: WELL AY Lab Sample ID: N86261-1 Date Sampled: 12/13/04 Matrix: AQ -Ground Water Date Received: 12/15/04 Method: SW846 8260B Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 S70819.D 1 12/23/04 MMC n/a n/a VS2585 Run #2 Purge Volume Run #1 5.0 ml Run #2 VOA TCL List CAS No. Compound Result RL MDL Units Q 67-64-1 Acetone ND 10 2.3 ug/I 71-43-2 Benzene ND 1.0 0.31 ug!1 75-27-4 Bromodichloromethane ND 1.0 0.11 ug/I 75-25-2 Bromoform ND 4.0 0.17 ug/I 74-83-9 Bromometbane ND 2.0 0.15 ug/h 78-93-3 2-Butanone (MEK) ND 10 2.5 ug/i 75-15-0 Carbon disulfide ND 2.0 0.23 ug/l 56-23-5 Carbon tetrachloride ND 1.0 0.15 ug/h 108-90-7 Chlorobenzene ND 1.0 0.23 ug/l 75-00-3 Chloroethane ND 1.0 0.73 ug/1 67-66-3 Chloroform ND 1.0 0,081 ug/l 74-87-3 Chlorometbane ND 1.0 0.13 ug/]124-48-1 Dibromochloromethane ND 1.0 0.18 ug/l 75-34-3 1, 1-Dichloroethane ND 1.0 0.13 ug/]107-06-2 1,2-Dichloroethane ND 1.0 0.35 ug/]75-35-4 1, 1-Dichloroethene ND 1.0 0.81 ug/1 156-59-2 cis- 1,2-Dichloroethene ND 1.0 0.24 ugh 156-60-5 trans- 1,2-Dichloroethene ND 1.0 0.17 ug/1 78-87-5 1,2-Dichloropropane ND 1.0 0.11 ug/l 10061-01-5 cis- 1,3-Dichloropropene ND 1.0 0.071 ug/1 10061-02-6 irans-1,3-Dichloropropene ND 1.0 0.080 ug/h 100-41-4 Ethylbenzene ND 1.0 0.27 ug/1 591-78-6 2-Hexanone ND 5.0 0.73 ug/l 108-10-1 4- Methyl-2-pentanone(M IBK) ND 5.0 0.59 ug/]75-09-2 Methylene chloride ND 2.0 0.20 ug8]100-42-5 Styrene ND 5.0 0.12 ug/I 79-34-5 1,1,2,2-Teirachloroethane ND 1.0 0.14 ug/1 127-18-4 Tetrachloroethene ND 1.0 0.37 ug/1 108-88-3 Toluene ND 1.0 0.14 ug/]71-55-6 1,1,1-Trichloroethane ND 1.0 0.25 ug/]79-00-5 1,1,2-Trichloroethane ND 1.0 0.17 ug/h 79-01-6 Trichloroethene ND 1.0 0.13 ug/h ND Not detected MDL -Method Detection Limit .= Indicates an estimated value RL = Reporting Limit B Indicates analyte found in associatecnethod blank E = Indicates value exceeds calibration range N Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 2 of 2 I&Client Sample ID: WELL AY Lab Sample ID: N86261-1 Date Sampled: 12/13/04 Matrix: AQ -Ground Water Date Received: 12/15/04 Method: SW846 8260B Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ VOA TCL List CAS No. Compound 75-01-4 Vinyl chloride 1330-20-7 Xylene (total)CAS No. Surrogate Recoveries 1868-53-7 Dibromofluoromethane 17060-07-0 1,2-Dichloroethane-D4 2037-26-5 Toluene-D8 460-00-4 4-Bromofluorobenzene Result RL MDL Units Q ND.. 1.0 0.66 ug/l ND 1.0 0.17 ugh Run# 1 Run# 2 Limits 99%95%98%101%79-119%68-129%83-118%82-120%ir ND = Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range.1 = Indicates an estimated value 13 Indicates analyte found in associatekethod blank N = Indicates presumptive evidence of a compound Accutesi Laboratories Report of Analysis Page 1 of 3 Client Sample ID: WELL AY Lab Sample ID: N86261-1 Date Sampled: 12/13/04 Matrix: AQ -Ground Water Date Received: 12/15/04 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG-Salem, Arificial Island, Salem, NJ File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 F47512.D 1 01/10/05 NAP 12/16/04 OP19045 EF2509 Run #2 Initial Volume Final Volume Run #1 940 ml 1.0 ml Run #2 ABN TCL List CAS No. Compound Result RL MDL Units Q 95-57-8 59-50-7 120-83-2 105-67-9 51-28-5 534-52-1 95-48-7 88-75-5 100-02-7 87-86-5 108-95-2.95-95-4 88-06-2 83-32-9 208-96-8 120-12-7 56-55-3 50-32-8 205-99-2 191-24-2 207-08-9 101-55-3 85-68-7 91-58-7 106-47-8 86-74-8 218-01-9 111-91-1 111-44-4 108-60-1 7005-72-3 2-Chlorophenol 4-Chloro-3-methyl phenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrophenol 4,6-Dinitro-o-cresol 2-Methylphenol 3&4-Methylphenol 2-Nitrophenol 4- Nitrophenol Pentachlorophenol Phenol 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene 4-Bromophenyl phenyl ether Butyl benzyl phthalate 2-Chloronaphthalene 4-Chloroaniline Carbazole Chrysene bis(2-Chloroethoxy)methane bis(2-Chloroethyl)ether bis(2-Chloroisopropyl)ether 4-Chiorophenyl phenyl ether ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5,3 5.3 5.3 5.3 21 21 5.3 5.3 5.3 21 21 5.3 5.3 5.3 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.1 5.3 5.3 2.1 2.1 2.1 2.1 2.1 2.1 4.5 5.0 0.78 1.1 1.]0.69 0.77 0.75 0.78 2.4 0.80 1.9 0.79 0.85 0.31 0.37 0.23 0.29 0.41 0.39 0.53 0.40 0.57 0.57 0.40 0.45 0.36 0.28 0.36 0.52 0.47 I.1 ug/1 ug/I ug/1 ug/h ug/]ug/I ug/]ug/1 ug/l ug/l ug/1 ug/l ug/h ug/l ug/l ug/1 ug/1 ugh/ug/h ug/l ug/l ug/]ugl]ug/1 ug/l ug/1 ug/1 ug/l ughi ug/]ug/]ug/]ND = Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 2 of 3Client Sample ID: WELL AY Lab Sample ID: N86261-1 Date Sampled: 12/13/04 Matrix: AQ -Ground Water Date Received: 12/15/04 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ ABN TCL List CAS No. Compound Result RL MDL Units Q 95-50-1 541-73-1 106-46-7 121-14-2 606-20-2 91-94-1 53-70-3 132-64-9 84-74-2 117-84-0 84-66-2 131-11-3 117-81-7 206-44-0 86-73-7 118-74-1 87-68-3 77-47-4 67-72-1 193-39-5 78-59-1 91-57-6 88-74-4 99-09-2 100-01-6 91-20-3 98-95-3 621-64-7 86-30-6 85-01-8 129-00-0 120-82-1 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 2,4-Dinitrotoluene 2,6-Dinitrotoluene 3,3'-Dichlorobenzidine Dibenzo(a,h)anthracene Dibenzofuran Di-n-butyl phthalateDi-n-octyl phthalate
Diethyl phthalate Dimethyl phthalate bis(2-Ethylhexyl)phthalate
Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Indeno(1,2,3-cd)pyrene Isophorone 2-MeIbylnaphilalene 2-Nitroaniline 3-Nitroaniline 4-Nitroaniline Naphthalene Nitrobenzene N-Nitroso-di-n-propylamine N-N itrosodiphenyl amine Phenanthrene Pyrene 1,2,4-Trichlorobenzene ND ND ND ND ND ND: ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2.1 2.1 2.1 2,1 2.1 5.3 2.1 5,3 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.1 21 5.3 2.1 2.1 2.1 5.3 5.3 5.3 2.1 2.1 2.1 5.3 2.1 2.1 2.1 0.25 0.34 0.27 0,82 0.66 0.41 0.62 0.52 0.84 0,67 1.5 0.61 0.78 0.67 0.95 1.3 0.44 0.48 0.71 1.6 0.57 0.77 1.5 1.3 1.1 1.1 0.65 0.53 0.85 0.25 0.62 0.34 ug/h ug/l ug/l ug/l ug/I ug/l ug/1 ug/I ug/l ug/l ug/l ug/1 ug/l ug/]ug/1 ug/l ug/1 ug/h ug/]ug/1 ug/l ug/]ug/l ug/l ug/l ug/l ug/]ug/1 ug/l ug/h ug/h ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 367-12-4 4165-62-2 118-79-6 4165-60-0 321-60-8 2-Fluorophenol Phenol-d5 2,4,6-Tribromophenol Nitrobenzene-d5 2-Fluorobipheny! 44%29%87%76%70%10-88%10-71%45-134%32-128%34-121%ND = Not detected MDL -Method Detection LimitRL Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value 8 B Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 3 of 3 Client Sample ID: WELL AY Lab Sample TD: N86261-1 Date Sampled: 12/13/04 Matrix: AQ -Ground Water Date Received: 12/15/04 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ ABN TCL List CAS No. Surrogate Recoveries1718-51-0 Terphenyl-d14 Run# 1 Run# 2 Limits 83-%41-129%bt ND = Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J -Indicates an estimated value B = Indicates analyte found in associatepmethod blank N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 1 of 2 Client Sample ID: WELL AV Lab Sample ID: N86261-2 Date Sampled: 12/13/04 Matrix: AQ -Ground Water Date Received: 12115/04 Method: SW846 8260B Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ Frile ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 S70820.D I 12/23/04 MMC n/a n/a VS2585 Run #2 Purge Volume Run #1 5.0 ml Run #2 VOA TCL List CAS No. Compound 67-64-1 Acetone 71-43-2 Benzene 75-27-4 Bromodichloromethane 75-25-2 Bromoform 74-83-9 Bromomethane 78-93-3 2-Butanone (MEK)75-15-0 Carbon disulfide 56-23-5 Carbon tetrachloride 108-90-7 Chlorobenzene 75-00-3 Chloroethane 67-66-3 Chloroform 74-87-3 Chloromethane 124-48-1 Dibromochloromethane 75-34-3 1,1-Dichloroethane 107-06-2 1,2-Dichloroethane 75-35-4 1, 1 -Dichloroethene 156-59-2 cis-1,2-Dichloroethene 156-60-5 trans- 1,2-Dichloroethene 78-87-5 1,2-Dichloropropane 10061-01-5 cis- 1,3-Dichloropropene 10061-02-6 trans- 1,3-Dichloropropene 100-41-4 Ethylbenzene 591-78-6 2-Hexanone 108-10-1 4-Methyl-2-pentanone(MIBK) 75-09-2 Methylene chloride 100-42-5 Styrene 79-34-5 1,1,2,2-Tetrachloroethane 127-18-4 Tetrachloroethene108-88-3 Toluene 71-55-6 1, 1, 1 -Trichloroethane 79-00-5 1,1,2-Trichloroethane 79-01-6 Trichloroethene Result RL MDL Units Q 10 1.0 1.0 4.0 2.0 10 2.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1,0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 2.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 2.3 ug/I 0.31 ug!l 0.11 ug/I 0.17 .ug/I 0.15. ug/I 2.5 ug/il 0.23 ug/l 0.15 ug/l 0.23 ug/I 0.73 ugt]0.081 ug/I 0.13 ug/I 0.18 ug/I 0.13 ug/h 0.35 ug/I 0.81 ug/I 0.24 ug/I 0.17 ug/I 0.11 ug/]0,071 ug/I 0.080 ug/I 0.27 ug/i 0.73 ug/I 0.59 ug/I 0.20 ug/I 0.12: utg/I 0.14 ug/h 0.37 ug/I 0.14 ug/I 0.25 ug/]0.17 ug/l 0.13 ug/1ND Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range= Indicates an estimated value B = Indicates analyte found in associldmethod blank N -Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 2 of 2 Client Sample ID: WELL AV Lab Sample ID: N86261-2 Date Sampled: 12/13/04 Matrix: AQ -Ground Water Date Received: 12/15/04 Method: SW846 8260B Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ VOA TCL List CAS No. Compound 75-01-4 Vinyl chloride 1330-20-7 Xylene (total)CAS No. Surrogate Recoveries Result RL MDL Units Q ND ND 1.0 1.0 0.66 ug/l 0.17 ug/1 Run# I Run# 2 Limits 1868-53-7 17060-07-0 2037-26-5 460-00-4 Dibromofluoromethane 1,2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene 99%97%98%101%79-119%68-129%83-118%82-120%4w ND = Not detected MDL -Method Detection Limit RL Reporting Limit E = Indicates value exceeds calibration range J Indicates an estimated value 5. ,, B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 1 of 3 Client Sample ID: WELL AV Lab Sample ID: N86261-2 Date Sampled: 12/13/04 Matrix: AQ -Ground Water Date Received: 12/15/04 Method: SW846,8270C SW846 3510C Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 F47513.D 1 01/10/05 NAP 12/16/04 OP19045 EF2509Run #2 Initial Volume Final Volume Run #1 900 ml 1.0 ml Run #2 ABN TCL List CAS No. Compound 95-57-8 2-Chlorophenol59-50-7 4-Chloro-3-methyl phenol 120-83-2 2,4-Dichlorophenol 105-67-9 2,4-Dimethylphenol 51-28-5 2,4-Dinitrophenol 534-52-1 4,6-Dinitro-o-cresol 95-48-7 2-Methylphenol 3&4-Methylphenol 88-75-5 2-Nitrophenol 100-02-7 4-Nitrophenol 87-86-5 Pentachlorophenol 108-95-2 Phenol 95-95-4 2,4,5-Trichlorophenol 88-06-2 2,4,6-Trichlorophenol83-32-9 Acenaphthene208-96-8 Acenaphthylene 120-12-7 Anthracene56-55-3 Benzo(a)anthracene 50-32-8 Benzo(a)pyrene205-99-2 Benzo(b)fluoranthene 191-24-2 Benzo(g,h,i)perylene 207-08-9 Benzo(k)fluoranthene 101-55-3 4-Bromophenyl phenyl ether 85-68-7 Buiyl benzyl phthalate 91-58-7 2-Chloronaphihalene 106-47-8 4-Chloroaniline 86-74-8 Carbazole 218-01-9 Chrsene 111-91-1 bis(2-Chloroethoxy)methane 111-44-4 bis(2-Chloroethyl)ether 108-60-1 bis(2-Chloroisopropyl)Cther 7005-72-3 4-Chlorophenyl phenyl ether Result RL MDL Units ND ND ND ND ND ND ND ND ND ND ND ND'ND ND 0.64 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5.6 5.6 5.6 5.6 22 22 5.6 5.6 5.6 22 22 5,6 5.6 5.6 2.2 2.2 2.2 2.2 2.2 2.2 2.2 2.2 2.2 2.2 5.6 5.6 2.2 2.2 2.2 2.2 2.2 2.2 4.7 5.3 0.81 1.1 1.2 0.72 0.80 0.78 0.81 2.5 0.84 1.9 0.83 0.89 0.33 0.39 0.24 0.30 0.43 0.41 0.55 0.42 0.60 0.60 0.42 0,47 0.38 0.29 0.37 0.54 0.49 1.1 ug/l ug/l ug/l ug/l ug/1 ug/l ug/l ug/l ug/l ug/l ug/l ug/I ug/l ug/l ug/l ug/I ug/l ug/1 ug/l ug/l ug/l ug/1 ug/l ug/l ug/l ughl ug/l ug/l ug/l ug/l ug/l ug/I Q J ND = Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value ' 12 B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 2 of 3 Client Sample ID: WELL AV Lab Sample ID: N86261-2 Date Sampled: 12/13/04 Matrix: AQ -Ground Water Date Received: 12/15/04 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ ABN TCL List CAS No. Compound Result RL MDL Units Q 95-50-1 54.1-73-1 106-46-7 121-14-2 606-20-2 91-94-1 53-70-3 132-64-9 84-74-2 117-84-0 84-66-2 131-11-3 117-81-7 206-44-0 86-73-7 118-74-1 87-68-3 77-47-4 67-72-1 193-39-5 78-59-1 91-57-6 88-74-4 99-09-2 100-01-6 91-20-3 98-95-3 621-64-7 86-30-6 85-01-8 129-00-0 120-82-1 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 2,4-Dinitrotoluene 2,6-Dinitrotoluene 3,3'-Dichlorobenzidine Dibenzo(a,h)anthracene Dibenzofuran Di-n-butyl phthalate Di-n-octyl phihalateDiethyl phthalate Dimethyl phthalate bis(2-Ethylhexy])phthalate Fluoranthene Fluorene Hexachlorobenzene flexachlorobutadiene Hexachlorocyclopentad iene Hexachloroethane Indeno(1,2,3-cd)pyrene lsophorone 2-Methylnaphthalene 2-Nitroaniline 3-Nitroaniline 4-Nitroaniline Naphthalene Nitrobenzene N-Nitroso-di-n-propylamine N-Nitrosodiphenylamine Phenanthrene Pyrene 1,2,4-Trichlorobenzene ND ND ND ND ND ND ND 0.71 ND ND ND ND ND 1.0 1.4 ND ND ND ND ND ND 1.8 ND ND ND 3.9 ND ND ND ND 0.96 ND 2.2 2.2 2.2 2.2 2.2 5.6 2.2 5,6 2.2 2.2 2.2 2.2 2.2 2.2 2.2 2.2 2.2 22 5.6 2.2 2.2 2.2 5.6 5.6 5.6 2.2 2.2 2.2 5.6 2,2 2.2 2.2 0.27 0.36 0.28 0.86 0.69 0.43 0.64 0.54 0.87 0.70 1.6 0.64 0.82 0.70 0.99 1.3 0.46 0.50 0.74 1.7 0.60 0.80 1.5 1.4 1.2 1.1 0.68 0.56 0.88 0,26 0.65 0.36 ug/I ug/h ug/l ugl.ug/]ug/1 ug/I ug/l ug/h ug/l ug/1 ug/t ug/1 ug/l ughl ug/l ug/1 ug/l ug/I ug/I ug/1 ug/l ug/l ug/l ug/l ug/1 ug/l ugJl ug/l ug/h ug/l ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 367-12-4 4165-62-2 118-79-6 4165-60-0 321-60-8 2-Fluorophenol Phenol-d5 2,4,6-Tribromophenol Nitrobenzene-d5 2-Fluorobiphenyl 46%32%99.%78%73%10-88%10-71%45-134%32-128%34-121%ND = Not detected MDL -Method Detection LimitRL Reporting Limit E = Indicates value exceeds calibration range.1 Indicates an estimated value I B = Indicates analyte found in associatd"method blank N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 3 of 3 Client Sample ID: WELL AV Lab Sample ID: N86261-2 Date Sampled: 12/13/04 Matrix: AQ -Ground Water Date Received: 12"115/04 Method: SW846 8270C SW846 3510C Percent Solids: nra Project: PSEG-Salem, Artificial Island, Salem, NJ ABN TCL List CAS No. Surrogate Recoveries 1718-51-0 Terphenyl-d14 Run# 1 Run# 2 Limits 93%41-129%#AV ND = Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J. Indicates an estimated value 14 *B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page I of 2 Client Sample ID: WELL X Lab Sample ID: N86261-3 Date Sampled: 12/13/04 Matrix: AQ -Ground Water Date Received: 12/15/04 Method: SW846 8260B Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 S70853.D 1 12/24/04 MMC n/a n/a VS2588 Run #2 Purge Volume Run #1 5.0 ml Run #2 VOA TCL List CAS No. Compound Result RL MDL Units Q 67-64-1 Acetone ND 10 2.3 ug!1 71-43-2 Benzene ND 1.0 0.31 ug/h 75-27-4 Bromodichloromethane ND 1.0 0.11 ug/1 75-25-2 Bromoform ND 4.0 0.17 ug/l 74-83-9 Bromomethane ND 2.0 0.15 ug/l 78-93-3 2-Butanone (MEK) ND 10 2.5 ug/l 75-15-0 Carbon disulfide ND 2.0 0.23 ug/h 56-23-5 Carbon tetrachloride ND 1.0 0.15 ug/l 108-90-7 Chlorobenzene ND 1.0 0.23 ug/1 75-00-3 Chloroethane N-D 10 0.73 ug/1 67-66-3 Chloroform ND 1.0 0.081 ug/l 74-87-3 Chloromethane ND 1.0 0.13 ug/1 124-48-1 Dibromochloromethane ND 1.0 0.18 ug/l 75-34-3 1,1 -Dichloroelhane ND 1.0 0.13 ug/h 107-06-2 1,2-Dichloroelhane ND 1.0 0.35 ug/]75-35-4 1,1-Dichloroethene ND 1.0 0.81 ug/1 156-59-2 cis-1,2-Dichloroethene ND 1.0 0.24 ug/1 156-60-5 trans- 1,2-Dichloroethene ND 1.0 0.17 ug/h 78-87-5 1,2-Dichloropropane ND 1.0 0.11 ug/h 10061-01-5 cis- 1,3-Dichloropropene ND 1.0 0.071 ug/1 10061-02-6 trans-],3-Dichloropropene ND 1.0 0,080 ug/l 100-41-4 Ethylbenzene ND 1.0 0.27 ug/l 591-78-6 2-Hexanone ND 5.0 0.73 ughl 108-10-1 4-Methyl-2-pentanone(MIBK) ND 5.0 0.59 ug/1 75-09-2 Methylene chloride ND 2.0 0.20 ug/l 100-42-5 Styrene ND 5.0 0.12 ug/]79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.14 ug/h 127-18-4 Tetrachloroethene 0.87 1.0 0.37 ug/1 J 108-88-3 Toluene ND 1.0 0.14 ug/l 71-55-6 1,1 ,1-Trichloroethane ND 1,0 0.25 ug/l 79-00-5 1,1,2-Trichloroethane ND 1.0 0.17 ug/h 79-01-6 Trichloroethene ND 1.0 0.13 ug/l ND = Not detected MDL -Method Detection Limit J Indicates an estimated value j5 RL Reporting Limit B = Indicates analyte found in associated method blank E = Indicaies value exceeds calibration range N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 2 of 2 Client Sample ID: WELL X Lab Sample ID: N86261-3 Date Sampled: 12/13/04 Matrix: AQ -Ground Water Date Received: 12/15/04 Method: SW846 8260B Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ VOA TCL List CAS No. Compound 75-01-4 Vinyl chloride 1330-20-7 Xylene (total)CAS No. Surrogate RecoveriesResult RL MDL Units Q ND ND 1.0 1,0 0.66 ugh 0.17 ug/1 Run# I Run# 2 Limits 1868-53-7 17060-07-0 2037-26-5 460-00-4 Dibromofluoromethane 1,2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene 97%99"%100%100%79-119%68-129%83-118%82-120%fav ND = Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estinmaed value 16 B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page I of 3 Client Sample ID: WELL X Lab Sample ID: N86261-3 Date Sampled: 12/13/04 Matrix: AQ -Ground Water Date Received: 12/15104 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 F47474.D 1 01/08/05 NAP 12/16/04 OP19045 EF2508 Run #2 Initial Volume Final Volume Run #1 100 ml 1.0 ml Run #2 ABN TCL List CAS No. Compound Result RL MDL Units Q 95-57-8 2-Chlorophenol ND 5.0 4.3 ug/1 59-50-7 4-Chloro-3-methyl phenol ND 5.0 4.7 ug/l 120-83-2 2,4-Dichlorophenol ND 5.0 0.73 ug/1 105-67-9 2,4-Dimethylphenol ND 5.0 1.0 ug/l 51-28-5 2,4-Dinitrophenol ND 20 1.1 ug/I 534-52-1 4,6-Dinitro-o-cresol ND 20 0.65 ug/l 95-48-7 2-Methylphenol ND 5.0 0.72 ug/l 3&4-Methylphenol ND 5.0 0.70 ug/1 88-75-5 2-Nitrophenol ND 5.0 0.73 ug/l 100-02-7 4-Nitrophenol ND 20 2.3 ug/l 87-86-5 Pentachlorophenol ND 20 0.75 ug/l 108-95-2 Phenol ND 5.0 1.8 ug/I 95-95-4 2,4,5-Trichlorophenol ND 5.0 0.74 ug/1 88-06-2 2,4,6-Trichlorophenol ND 5.0 0.80 ug/1 83-32-9 Acenaphthene ND 2.0 030 ug/1 208-96-8 Acenaphthylene ND 2.0 0.35 ug/l 120-12-7 Anthracene ND 2.0 0.22 ug/h 56-55-3 Benzo(a)anthracene ND 2.0 0.27 ug/l 50-32-8 Benzo(a)pyrene ND 2.0 0.38 ug/I 205-99-2 Benzo(b)fluoranthene ND 2.0 0.37 ug/l 191-24-2 Benzo(g,h,i)perylene ND 2.0 0.50 ug/]207-08-9 Benzo(k)fluoranthene ND 2.0 0.37 ug/]101-55-3 4-Bromophenyl pbenyl ether ND 2,0 0.54 ug/1 85-68-7 Butyl benzyl phthalate ND 2.0 0.54 ug/8 91-58-7 2-Chloronaphthalene ND 5.0 0.38 ug/1 106-47-8 4-Chloroaniline ND 5.0 0.43 ug/l 86-74-8 Carbazole ND 2.0 0.34 ug/i 218-01-9 Chrysene ND 2.0 0.26 ug/h111-91-1 bis(2-Chboroethoxy)mnethane ND 2.0 0.34 ug/h 111-44-4 bis(2-Chloroethyl)ether ND 2,0 0.49 ug/l 108-60-1 bis(2-Chloroisopropyl)ether ND 2.0 0.44 ug/I 7005-72-3 4-Chlorophenyl phenyl ether ND 2.0 1.0 ug/l ND = Not detected MDL -Method Detection Limit 3 = Indicates an estimated value RL = Reporting Limit B Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 2 of 3 Client Sample ID: WELL X Lab Sample ID: N86261-3 Date Sampled: 12/13/04 Matrix: AQ -Ground Water Date Received: 12/15104 Method: SW846 8270C SW846 3510C Percent Solids: n/a.Project: PSEG-Salem, Artificial Island, Salem, NJ ABN TCL List CAS No. Compound Result RL MDL Units Q 95-50-1 541-73-1 106-46-7 121-14-2 606-20-2 91-94-1 53-70-3 132-64-9 84-74-2 117-84-0 84-66-2 131-11-3 117-81-7 206-44-0 86-73-7 118-74-1 87-68-3 77-47-4 67-72-1 193-39-5 78-59-1 91-57-6 88-74-4 99-09-2 100-01-6 91-20-3 98-95-3 621-64-7 86-30-6 85-01-8 129-00-0 120-82-1 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 2,4-Dinitrotoluene 2,6-Dinitrotoluene 3,3'-Dichlorobenzidine Dibenzo(a,h)anthracene Dibenzofuran Di-n-butyl phthalateDi-n-octyl phthalate Diethyl phthalate Dimethyl phthalate bis(2-Ethylhexyl)phthalate Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane lndeno( 1,2,3-cd)pyrene Isophorone 2-Methylnaphthalene
2-Nitroaniline 3-Nitroaniline 4-Nitroaniline Naphthalene Nitrobenzene N-Nitroso-di-n-propylamine N-Nitrosodiphenylainine Phenanthrene Pyrene 1,2,4-Trichlorobenzene ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2.0 2.0 2.0 2,0 2.0 5.0 2.0 5,0 2.0 2.0 2.0 2.0 2,0 2.0 2.0 2.0 2.0 20 5.0 2.0 2.0 2.0 5.0 5.0 5.0 2.0 2.0 2.0 5.0 2.0 2.0 2.0 0.24 0.32 0.25 0.78 0.62 0.39 0.58 0.49 0.79 0.63 1.4 0.58 0.74 0.63 0.89 1.2 0.41 0.45 0.67 1.5 0.54 0.72 1.4 1.2 1.1 1.0 0.61 0.50 0.80 0.23 0.58 0.32 ug/l ug/l ug/l ug/l ug/1 ug/1 ug/1 ug/l ug/l ug/h ug/l ug/l ug/1 ug/l ug/1 ug/l ug/l ug/l ugll ug/1 ug/l ug/]ug/I ug/]ugh]ugll ug/1 ughl ug/l ug/h ug/t ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 367-12-4 4165-62-2 118-79-6 4165-60-0 321-60-8 2-Fluorophenol Phenol-d5 2,4,6-Tribromophenol Nitrobenzene-d5 2-Fluorobiphenyl 397%27%88:%72%69%10-88%10-71%45-134%32-128%34-121%'V0 ND Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value IN B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 3 of 3 Client Sample ID: WELL X Lab Sample ID: N86261-3 Date Sampled: 12/13/04 Matrix: AQ -Ground Water Date Received: 12/15104 Method: SW846 8270C SW846 3510C Percent Solids: n/a.Project: PSEG-Salem, Artificial Island, Salem, NJ ABN TCL List CAS No. Surrogate Recoveries 1718-51-0. Terphenyl-dl4 Run# 1 Run# 2 Limits 955% 41-129%'p ND = Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J= Indicates an estimated value 19 B = Indicates analyte fo6nd in associated method blank N Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page I of 2 Client Sample ID: FB-2 LabSample ID: N86261-4 Date Sampled: 12/13/04 Matrix: AQ -Field Blank Water Date Received: 12/15/04 Method: SW846 8260B Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 S70854.D 1 12/24/04 MMC n/a n/a VS2588 Run #2 Purge Volume Run #1 5.0 m]Run #2 VOA TCL List CAS No. CompoundResult RL MDL Units Q 67-64-1 71-43-2 75-27-4 75-25-2 74-83-9 78-93-3 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3 124-48-1 75-34-3 107-06-2 75-35-4 156-59-2 156-60-5 78-87-5 10061-01-5 10061-02-6 100-41-4 591-78-6 108-10-1 75-09-2 100-42-5 79-34-5 127-18-4 108-88-3 71-55-6 79-00-5 79-01-6 Acetone Benzene Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK)Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Dibromochloromethane I,I-Dichloroethane ] ,2-Dichloroethane , 1-Dichloroethene cis- 1,2-Dichloroethene trans-I ,2-Dichloroethene 1,2-Dichloropropane cis- 1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone 4- M ethyl-2-pentanone(M IBK)Methylene chloride Styrene 1,1,2,2-Tetrachloroethane Teirachloroeihene Toluene 11,, J-Trichloroeihane 1,1,2-Trichloroethane Trichloroethene ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 10 1.0 1.0 4.0 2.0 10 2.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 2.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 2.3 0.31 0.11 0.17 0.15 2.5 0.23 0.15 0.23 0.73 0.081 0.13 0.18 0.13 0.35 0.81 0.24 0.17 0.11 0.071 0.080 0.27 0,73 0.59 0.20 0,12 0.14 0.37 0.14 0.25 0.17 0.13 ug/l ug/t ug/h ug/1 ug/l ug/1 ug/l ug/1 ug/I ug/I ug/1 ug/h ug/I ug/I ug/t ug/I ug/] ug/h ug/1 ug/l ug/h ug/l ug/l ug/]ug/l ug/]ug/l ug/l ug/l ug/1 ug/l ug/l ND Not detected MDL -. Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value 20 B = Indicates analyte found in associated method blank N Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 2 of 2 Client Sample ID: FB-2 Lab Sample ID: N86261-4 Date Sampled: 12/13/04 Matrix: AQ -Field Blank Water Date Received: 12/15/04 Method: SW846 8260B Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ VOA TCL List CAS No. Compound 75-01-4 Vinyl chloride1330-20-7 Xylene (total)CAS No. Surrogate Recoveries Result RL MDL Units Q ND ND 1.0 1.0 0.66 ug/h 0.17 ug/l Run# I Run# 2 Limits 1868-53-7 17060-07-0 2037-26-5 460-00-4 Dibromofluoromethane ] ,2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene 98%101%100%102%79-119%68-129%83-118%82-120%ND -Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B Indicates analyte found in assozad method blank N Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 1 of 3 Client Sample ID: FB-2 Lab Sample ID: N86261-4 Date Sampled: 12113/04 Matrix: AQ -Field Blank Water Date Received: .12/15/04 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 F47475.D 1 01/08/05 NAP 12/16/04 OP19045 EF2508 Run #2Initial Volume Final Volume Run l 1000 ml 1.O mlRun #2 ABN TCL List CAS No. Compound Result RL MDL Units Q 95-57-8 2-Chlorophenol ND 5.0 4.3 ug/lI 59-50-7 4-Chloro-3-methyl phenol ND 5.0 4.7 ug/l 120-83-2 2,4-Dichlorophenol ND 5.0 0.73 ug/l 105-67-9 2,4-Dimethylphenol ND 5.0 1.0 ug/1 51-28-5 2,4-Dinitrophenol ND 20 1.1 ug/l 534-52-1 4,6-Dinitro-o-cresol ND 20 0.65 ug/]95-48-7 2-Methylphenol ND 5.0 0.72 ug/l 3&4-Methylphenol ND 5.0 0.70 ug/l 88-75-5 .2-Nitrophenol ND 5.0 0.73 ug/l 100-02-7 4-Nitrophenol ND 20 2.3 ug/1 87-86-5 Pentachlorophenol ND 20 0.75 ug/l 108-95-2 Phenol ND 5.0 1.8 ug/I 9.5-95-4 2,4,5-Trichlorophenol ND 5.0 0.74 ug/l 88-06-2 2,4,6-Trichlorophenol ND 5.0 0.80 ug/h 83-32-9 Acenaphthene ND 2.0 0.30 ug/l 208-96-8 Acenaphthylene ND 2.0 0.35 ug/l 120-12-7 Anthracene ND 2.0 0.22 ug/l 56-55-3 Benzo(a)anthracene ND 2.0 0.27 ug/]50-32-8 Benzo(a)pyrene ND 2.0 0.38 ug/]205-99-2 Benzo(b)fluoranthene ND 2.0 0.37 ug/]191-24-2 Benzo(g,h,i)perylene ND 2.0 0.50 ug/]207-08-9 Benzo(k)fluoranthene ND 2.0 0.37 ug/]101-55-3 4-Bromophenyl phenyl ether ND 2.0 0.54 ug/]85-68-7 Butyl benzyl phthalate ND 2.0 0.54 uglI 91-58-7 2-Chloronaphthalene ND 5.0 0.38 ug/I 106-47-8 4-Chloroaniline ND 5.0 0.43 ug/h-86-74-8 Carbazole ND 2.0 0.34 ug/l 218-01-9 Chrysene ND 2.0 0.26 ug/l 111-91-1 bis(2-Chloroethoxy)methane ND 2.0 0.34 ug/l. .'111-44-4 bis(2-Chloroethyl)ether ND 2.0 0.49 ug/l 108-60-1 bis(2-ChIoroisopropyl)ether ND 2.0 0.44 ug/]7005-72-3 4-Chlorophenyl phenyl ether ND 2.0 1.0 ug/l ND = Not detected MDL -Method Detection Limit 3 = Indicates an estimated ýalue RL = Reporting Limit B = Indicates analyte found in method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 2 of 3 48V Client Sample ID: FB-2 Lab Sample ID: N86261-4 Date Sampled: 12/13/04 Matrix: AQ -Field Blank Water Date Received: 12/15/04 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ ABN TCL List CAS No. Compound Result RL MDL Units Q 95-50-1 541-73-1 106-46-7 121-14-2 606-20-2 91-94-1 53-70-3 132-64-9 84-74-2 117-84-0 84-66-2 131-11-3 117-81-7 206-44-0 86-73-7 118-74-1 87-68-3 77-47-4 67-72-I 193-39-5 78-59-1 91-57-6 88-74-4 99-09-2 100-01-6 91-20-3 98-95-3 621-64-7 86-30-6 85-01-8 129-00-0 120-82-1 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 2,4-Dinitrotoluene 2,6-Dinitrotoluene 3,3'-Dichlorobenzidine Dibenzo(a,h)anlhracene Dibenzofuran Di-n-butyl phthalateDi-n-octyl phthalate Diethyl phthalate Dimethyl phthalate bis(2-Ethylbexyl)pbthalate Fluoranthene Fluorene H exachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene H lexachloroethane Indeno(1,2,3-cd)pyrene Isophorone 2-Methylnaphthalene 2-Nitroaniline 3-Nitroaniline 4-Nitroaniline Naphthalene Nitrobenzene N-Nitroso-di-n-propylamine N-Nitrosodiphenylamine Phenanthrene Pyrene 1,2,4-Trichlorobenzene ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2.0 2.0 2.0 2.0 2.0 5.0 2.0 5.0 2.0 2.0 2.0 2.0 2,0 2.0 2.0 2.0 2.0 20 5.0 2.0 2.0 2.0 5,0 5.0 5.0 2.0 2.0 2.0 5.0 2.0 2.0 2.0 0.24 0.32 0.25 0.78 0.62 0,39 0.58 0.49 0.79 0.63 1.4 0,58 0.74 0.63 0.89 1.2 0.41 0.45 0.67 1.5 0.54 0,72 1.4 1.2 1.1 1.0 0.61 0.50 0.80 0.23 0.58 0.32 ug/I ug/l ugil ug/I ug/l ug/l ug/l ug/l ug/l ug/l ug/1 ug/l ug/i ug/l ug/I ug/l ughI ug/l ug/i ug/l ug/!ug/l ug/l ug/l ug/l ug/h ug/l ug/l ug/1 ug/l ug/1 ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 367-12-4 4165-62-2 118-79-6 4165-60-0 321-60-8 2-Fluorophenol Phenol-d5 2,4,6-Tribromophenol Nitrobenzene-d5 2-Fluorobiphenyl 45%29%81%85%75%10-88%10-71%45-134%32-128%34-121%ND = Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibralion range.1 = Indicates an estimated value 0.B = Indicates analyte found in associat-method blank N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 3 of 3 Client Sample ID.Lab Sample ID: Matrix: Method: Project: FB-2 N86261-4 AQ -Field Blank Water SW846 8270C SW846 3510CPSEG-Salem, Artificial Island, Salem, NJ Date Sampled: 12/13/04 Date Received: 12/15/04 Percent Solids: n/a ABN TCL List CAS No. Surrogate Recoveries 1718-51-0 Terphenyl-d14 Run# I Run# 2 Limits 92%41-129%ND Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range 3 = Indicates an estimated value B = Indicates analyte found in associa';A'ethod blank N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 1 of 2Client Sample ID: TRIP BLANK tLab Sample ID: N86261-5 Date Sampled: 12/13/04 Matrix: AQ -Trip Blank Water Dale Received: 12/15/04 Method: SW846 8260B Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 S70855.D 1 12/24/04 MMC n/a n/a VS2588 Run #2 Purge Volume Run #1 5.0 ml Run #2 VOA TCL List CAS No. Compound Result RL MDL Units Q 67-64-1 Acetone ND 10 2.3 ug/h 7]-43-2 Benzene ND 1.0 0,31 ug/]75-27-4 Bromodichloromethane ND 1.0 0,11 ug/1 75-25-2 Bromoform ND 4.0 0,17 ug/1 74-83-9 Bromomethane ND 2,0 0.15 ug/l 78-93-3 2-Butanone (MEK) ND 10 2.5 ug/l 75-15-0 Carbon disulfide ND 2.0 0.23 ug/1 56-23-5 Carbon tetrachloride ND 1.0 0.15 ug/h 108-90-7 Chlorobenzene ND 1.0 0.23 ug/l 75-00-3 Chloroethane ND 1.0 0.73 ug/l 67-66-3 Chloroform ND 1.0 0.081 ug/l 74-87-3 Chloromethane ND 1.0 0.13 ug/]124-48-1 Dibromochloromeihane ND 1.0 0.18 ug/l 75-34-3 1,1 -Dichloroethane ND 1.0 0.13 ug/1 107-06-2 1,2-Dichloroethane ND 1.0 0.35 ug/1 75-35-4 1,1 -Dichloroethene ND 1.0 0.81 ug/l 156-59-2 cis- 1,2-Dichloroelhene ND 1.0 0.24 ug/l 156-60-5 trans- 1,2-Dichtoroethene ND 1.0 0.17 ughl 78-87-5 1,2-Dichloropropane ND 1.0 0.11 ug/l 10061-01-5 cis- 1,3-Dichloropropene ND 1.0 0.071 ug/l 10061-02-6 trans- 1,3-Dichloropropene ND 1.0 0.080 ug/]100-41-4 Ethylbenzene ND 1.0 0.27 ug/]591-78-6 2-Hexanone ND 5.0 0.73 ug/]108-10-1 4-Methyl-2-pentanone(M IBK) ND 5.0 0.59 ug/h 75-09-2 Methylene chloride ND 2.0 0.20 ug/l 100-42-5 Styrene ND 5.0 0.12 ug/" 79-34-5 1, 1,2,2-Tetrachloroethane ND 1.0 0.14 ug/h 127-18-4 Tetrachloroethene ND 1.0 0.37 ug/Il 108-88-3 Toluene ND 1.0 0.14 ug/1 71-55-6 1,1,1 -Trichloroethane ND 1.0 0,25 ug/l 79-00-5 1,1,2-Trichloroethane ND 1.0 0.17 ug/l 79-01-6 Trichloroethene ND 1.0 0,13 ug/l ND Not detected MDL -Method Detection Limit J = Indicates an estimated value 2 RL Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 2 of 2 (w Client Sample ID: TRIP BLANK Lab Sample ID: N86261-5 Date Sampled: 12113/04 Matrix, AQ -Trip Blank Water Date Received: 12/15/04 Mlethod: SW846 8260B Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ VOA TCL List CAS No. Compound 75-01-4 Vinyl chloride 1330-20-7 Xylene (total)CAS No. Surrogate Recoveries Result RL MDL Units Q ND ND 1.0 1.0 0.66 ug/1 0.17 ug/1 Run# I Run# 2 Limits 1868-53-7 17060-07-0 2037-26-5 460-00-4 Dibromofluoromethane 1,2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene 99%103 %101I%103.%79-119%68-129%83-118%82-120%ND Not detected MDL -Method Detection Limit RL Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found -in associated method blartk N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 1 of 2 6Y Client Sample ID: WELL AX Lab Sample ID: N86261-6 Date Sampled: 12/13/04 Matrix: AQ -Ground Water Date Received: 12/15/04 Method: SW846 8260B Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 S70856.D 1 12/24/04 MMC n/a n/a VS2588 Run #2 Purge Volume Run #1 5.0 ml Run #2 VOA TCL List CAS No. CompoundResult RL MDL Units Q 67-64-1 71-43-2 75-27-4 75-25-2 74-83-9 78-93-3 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3 124-48-1 75-34-3 107-06-2 75-35-4 156-59-2 156-60-5 78-87-5 10061-01-5 10061-02-6 100-41-4 591-78-6 108-10-1 75-09-2 100-42-5 79-34-5 127-18-4 108-88-3 71-55-6 79-00-5 79-01-6 Acetone Benzene Bromodichloromethane Bromoform Bromomethane 2-Buianone (MEK)Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Dibromochloromethane 1,1 -Dichloroethane 1,2-Dichloroeihane 1,1-Dichloroethene cis-1 ,2-Dichloroethene trans-I1,2-Dichl oroethene 1,2-Dichloropropane cis- 2,3-Dichloropropene trans-i1,3-Dichloropropene Ethylbenzene 2-Hexanone 4-M ethyl-2-pentanone(M IBK)Methylene chloride Styrene 1, 1,2,2-Tetrachlioroethane Tetrachloroethene Toluene 1, 2, I -Trichloroethane 1, 1,2-Trichloroethane Trichloroethene ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 10 1.0 1.0 4.0 2.0 10 2.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 2.0 5,0 1.0 1.0 1.0 1.0 1.0 1.0 2.3 0.31 0.11 0.17 0.15 2.5 0.23 0.15 0.23 0.73 0.081 0.13 0.18 0.13 0.35 0.81 0.24 0.17 0.11 0.071 0,080 0.27 0.73 0.59 0.20 0.12 0.14 0.37 0.14 0.25 0.17 0.13 ugh ug/l ug/l ug/h ug/1 ug/l ugtl ug/l ug/l ug/1 ug!2 ug/l ug/l ug/l ug/1 ug/l ug/l ug/l ug/1 ug/h ug/1 ug/l ughl ug/l ug/l ug/l ug/1 ugh]ugh ug/I ug/l ug!]ND Not detected MDL -Method Detection Limit RL Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B1 Indicates analyte found in associated method blank N -Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 2 of 2Client Sample ID: WELL AX Lab Sample ID: N86261-6 Date Sampled. 12113/04 Matrix: AQ -Ground Water Date Received: 12115/04 Method: SW846 8260B Percent Solids- n/a Project: PSEG-Salem, Artificial Island, Salem, NJ VOA TCL List CAS No. Compound 75-01-4 Vinyl chloride 1330-20-7 Xylene (total)Result RL MDL Units Q ND ' 1.0 ND 1.0 0.66 ug/l 0.17 ug/l CAS No. Surrogate Recoveries 1868-53-7 Dibromofluoromethane 17060-07-0 1,2-Dichloroethane-D4 2037-26-5 Toluene-D8 460-00-4 4-BromoflUorobenzene Run# I Run# 2 Limits 100%105%101%101%79-119%68-129%83-118%82-120%ND = Not detected MDL -Method Detection Limit RL Reporting Limit E = Indicates value exceeds calibration range 3 = Indicates an estimated value " Q B Indicates analyte found in associateWdmethod blank N = Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page I of 3 Client Sample ID: WELL AX Lab Sample ID: N86261-6 Date Sampled: 12/13/04 Matrix: AQ -Ground Water. Date Received: 12/15/04 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 F47484,D 1 01/08/05 NAP 12/16/04 OP19045 EF2508 Run #2 Initial Volume Final Volume Run #1 1000 ml 1.0 ml Run #2 ABN TCL List CAS No. Compound Result RL MDL Units Q 95-57-8 2-Chlorophenol ND 5.0 4.3 ug/l 59-50-7 4-Chloro-3-methyl phenol ND 5.0 4.7 ug/1 120-83-2 2,4-Dichlorophenol ND 5.0 0.73 ug/I 105-67-9 2,4-Dimethylphenol ND 5.0 1.0 ug/l 51-28-5 2,4-Dinitrophenol ND 20 1.1 ughl 534-52-1 4,6-Dinitro-o-cresol ND 20 0.65 ug/l 95-48-7 2-Methylphenol ND 5.0 0.72 ug/l 3&4-Methylphenol ND 5.0 0.70 ug/1l 88-75-5 2-Nitrophenol ND 5.0 0.73 ug/l 100-02-7 4-Nitrophenol ND 20 2.3 ug/l 87-86-5 Pentachlorophenol ND 20 0.75 ug/l 108-95-2 Phenol ND 5.0 1.8 ug/l 95-95-4 2,4,5-Trichlorophenol ND 5.0 0.74 ug/l.88-06-2 2,4,6-Trichlorophenol ND 5.0 0.80 ug/l 83-32-9 Acenaphthene ND 2.0 0.30 ug/1 208-96-8 Acenaphthylene ND 2.0 0.35 ug/l 120-12-7 Anthracene ND 2.0 0.22 ughl 56-55-3 Benzo(a)anthracene ND 2.0 0.27 ug/150-32-8 Benzo(a)pyrene ND 2.0 0.38 ug/l 205-99-2 Benzo(b)fluoranthene ND 2.0 0.37 ug/l 191-24-2 Benzo(g,h,i)perylene ND 2.0 0.50 ug/l 207-08-9 Benzo(k)fluoranthene ND 2.0 0.37 ug/l.101-55-3 4-Bromophenyl phenyl ether ND 2.0 0.54 ugl1 85-68-7 Butyl benzyl phthalate ND 2.0 0.54 ug/l 91-58-7 2-Chloronaphthalene ND 5.0 0.38 ug/l 106-47-8 4-Chloroaniline ND 5.0 0.43 ug/l 86-74-8 Carbazole ND 2.0 0.34 ug/l218-01-9 Chrysene ND 2.0 0.26 ug/l 111-91-I bis(2-Chloroethoxy)methane ND 2.0 0.34 ug/ '111-44-4 bis(2-Chloroethyl)ether ND 2.0 0.49 ug/l 108-60-1 bis(2-Chloroisopropyl)ether ND 2.0 0.44 ug/l 7005-72-3 4-Chlorophenyl phenyl ether ND 2.0 1.0 ug/h ND = Not detected MDL -Method Detection Limit J Indicates an estimated value ' Q RL = Reporting Limit B = Indicates analyte found in associatedkfehod blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound Accutest LaboratoriesReport of Analysis Page 2 of 3Client Sample ID: WELL AX Lab Sample ID: N86261-6 Date Sampled: 12/13/04 Matrix: AQ -Ground Water Date Received: 12/15/04 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG-Salem, Artificial Island, Salem, NJ ABN TCL List CAS No. Compound Result RL MDL Units Q 95-50-1 541-73-1 106-46-7 121-14-2 606-20-2 91-94-1 53-70-3 132-64-9 84-74-2 117-84-0 84-66-2 131-11-3 117-81-7 206-44-0 86-73-7 118-74-1 87-68-3 77-47-4 67-72-1 193-39-5 78-59-1 91-57-6 88-74-4 99-09-2 100-01-6 91-20-3 98-95-3 621-64-7 86-30-6 85-01-8 129-00-0 120-82-1 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 2,4-Dinitroioluene 2,6-Dinitrotoluene 3,3'-Dichlorobenzidine Dibenzo(a,h)anthracene Dibenzofuran Di-n-butyl phthalateDi-n-octyl phthalate Diethyl phthalate Dimethyl phthalate bis(2-Ethylhexyl)phthalate Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Indeno(],2,3-cd)pyrene Isophorone 2-Methylnaphthalene 2-Nitroaniline 3-Nitroaniline 4-Nitroaniline Naphthalene Nitrobenzene N-Nitroso-di-n-propylamine N-Nicrosodiphenylamine Phenanthrene Pyrene 1,2,4-Trichlorobenzene ND ND ND ND ND ND ND ND ND ND.ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2.0 2.0 2.0 2.0 2.0 5.0 2.0 5.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 20 5.0 2.0 2.0 2.0 5.0 5.0 5.0 2.0 2.0 2.0 5.0 2.0 2.0 2.0 0.24 0.32 0.25 0.78 0.62 0.39 0.58 0.49 0.79 0.63 1.4 0.58* 0.74 0.63 0.89 1.2 0.41 0.45 0.67 1.5 0.54 0.72 1.4 1.2 1.1 1.0 0.61 0.50 0.80 0.23 0.58 0.32 ug/l ug/1 ugll ug/]ug/1 ug/1 ug/i ug/l ug/1 ug)]ug/]ugi1 ug/h ug/l ug/h ug/]ug/]ug/1 ug/1 ug/l ug/I ug/1 ug/1 ug/1 ug/l ug/l ugh]ug/]ug/]ug/h ugh1 ug/l CAS No. Surrogate Recoveries Run# I Run# 2 Limits 367-12-4 4165-62-2 118-79-6 4165-60-0 321-60-8 2-Fluorophenol Phenol-d5 2,4,6-Tribromophenol Nitrobenzene-d5 2-Fluorobipheny] .49%32%96%89%85%10-88%10-71%45-134%32-128%34-121%ND = Not detected MDL -Method Detection Limit RL Reporting Limit E = Indicates value exceeds calibration range'J = Indicates an estimated 'alue -3 B = Indicates analyte found in associated method blank N Indicates presumptive evidence of a compound Accutest Laboratories Report of Analysis Page 3 of 3 CF Client Sample ID: WELL AX Lab Sample ID: N86261-6 Date Sampled: 12/13104 Matrix: AQ -Ground Water Date Received: 12/15/04 Method: SW846 8270C SW846 3510C Percent Solids: n/a Projeýt: PSEG-Salem, Artificial island, Salem, NJ ABN TCL List CAS No. Surrogate Recoveries 1718-51-0 Terphenyl-d14 Run# 1 Run# 2 Limits I 12%41-129%6w ND = Not detected MDL -Method Detection Limit RL Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated2method blank N = Indicates presumptive evidence of a compound 12ACCUTEST. Lab o ra to ri es CHAIVt F CUSTODI 2235 Route 1311, Dayton NJ 08810 TEL. 732-329-0200 FAX- 732-329.349913480 www.ae~u~tt~.com FED-EX 1~~lsit~ U Bollie Order Control U FED-EX Ttacking 9 I Mile Order Control 4____________________________________________________________ F.A~srteat Oriole ft AsSelest Jab Company Nam~t Project Name Addrest iQ 360 StreI City .Stale zi cty SaleContact E.r-r Projecl 0 DrmA ...Phone it 264.-6'T5-~ 15"___ ___ __L90)_Sampler's Nay M'Client Purchase Order t i I i i 01 a 13 00 0 0Renueened Analeeta W.I Acculest Job # ý0 0 M j YW. Drrnkirta Water OV.Ground lVAVe%Wn -V.r SW. -sviane Water St. -Sicane 1-10 Other L-Quid ArIR -Ail SOLt-Other S~WP, Wiee LAB USE ONLdtY Accetesl Field t0 1 Point of -1;lo SUJMMA At Cleio I Number Iot~reservadBorles we'.ll 5xIr 3'l >,'5}q-Z W,i) X >-'5 Trip [4_.,.. ,,,- ~5 ~~ ------- _ 2 g S e_______ _,_ t905 53 _ x-2C/ 1213r-iRY171 RV ~?~6Wj _Turnaroundt Tirme(BusineSS Oay8)-- _ Data Deie alreeisnformationt NMMJ n 3 Sld. ,15 BusinesS Days Approved By: Date: 0 Comme,, 01 .tt C., .P ý.,Ce , ..10 IDay RUSH' 0 Commercial V 0 NYASPCalegoryA [O 5 Da RfUSH __N 0 L Reduced LI NYASP Category 8 5 3Day EMGENCY RS NJ FrIll 0 State Forms D DayEMERGENCY other--0 03 EDO Formal -LI 2 Day EMERGENCY 0 1___y_________Y_ Commercial A = Resulls Only SOiher'nergencyj&46ý?/AA joa--aV0ble VIA LabL-ink -. Ia ViA S ame Ceoledy Wont be dacernented below ech ime es change e , mSsesjo Ingcloudi ne couet ery,.... W " 5 r .'l cc+1 orame Ty: Bate Tr& e Refe i 3Rtrrjte~ &an 3rre enl 44 ('1k AAA/A'xCutd Preeerne ehtrM Wlrrrble on MC I by, C lodysalf 1 I Accuiest Laboratories Internal Sample Tracking Chronicle Arcadis Geraghty & Miller Job No: N86261'PSEG-Salem, Artificial Island, Salem, NJ Project No: NP000571 Sample Number Method Analyzed By Prepped By Test Codes N86261-1 SW846 8260B 23-DEC-04 06:36 MMC V8260TCL N86261-1 SW846 8270C 10-JAN-05 10:31 NAP 16-DEC-04 CAS AB8270TCL N86261-2 SW846 8260B 23-DEC-04 07:07 MMC V8260TCL N86261-2 SW846 8270C 10-JAN-05 11:07 NAP 16-DEC-04 CAS AB8270TCL N86261-3 coll............ ..-D C-0 17:. .y I ~ ... .~ivd .5D C0 .y. ....N86261-3 SW846 8260B 24-DEC-04 02:20 MMC V8260TCL N86261-3 SW846 8270C 08-JAN-05 12:13 NAP 16-DEC-04 CAS AB8270TCL N86261-4 SW846 8260B 24-DEC-04 02:50 MMC V8260TCL N86261-4 SW846 8270C 08-JAN-05 12:49 NAP 16-DEC-04 CAS AB8270TCL N86261-5 Col46e8260B 23-DEC-04180 y 03M2 MMCed 1582C640B-CL N86261-6 SW846 8260B 24-DEC-04 03:20 MMC V8260TCL.............. B. .M.................C N86261-6 SW846 82700 08-JAN-05 18:12 NAP 16-DEC-04 CAS AB827OTCL Page 1 of 1 33 G CIMS 34 GCIMS VOLATI.LE. 25 ImA,7 LAU GCUMS Analysis Case Narrative/Conformance/Non-Conformance Summary 4W Fraction P NO YES 1. Chromatograms Labeled/Compounds Identified (Field Samples and Method Blanks) _2. GC/MS Tune Meet Criteria .__/_3. GC/MS Tuning Frequency -Performed every 24 hours for.600 series.nd 12 hours for 8000 series.4. GCUMS Calibration -Initial and Continuing Calibration Meet Method Requirements " _.._ _5. GC/MS Calibration Requirements
- a. Calibration Check Compounds
_ .b. System Performance Check Compounds _" 6. Bllank Contamination Ifyes, the sample result is qualified with a "B.".7. Surrogate Recoveries Meet Criteria if the requirement is not met, refer to the Surrogate Summary for comment.8. Matrix Spike/Matrix Spike Duplicate Recoveries Meet Criteria ___If-the requirement is not met, refer to MS/vIMSD Summary for comment.9. Internal Standard Area/Retention Time Shift Meet Criteria /if the requirement is not met, refer to the Internal Standard Summary for comment.10. Extraction Holding Time Met* If the holding time is not met, refer to the Sample Result pagefor comment.11. Analysis Hoding Time Met If the holding time is not met, refer to the Sample Result page for comment.12! Volatile Sample Preservation -pH should be < 2. List any non-compliant samples below: Additional Comments: ..e -< e J /IY, 4.,"V QC Review Signature:__ ________ Date: -( 7- ,z Form RG04 * ,"* Rev. Date: 2/9/00 Method Blank Summary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 1 of 2 Sample File ID DF Analyzed .By Prep Date Prep Batch Analytical Batch VS2585-MB1 S70809.D 1 12/23/04 MMC n/a n/a VS2585 The QC reportled here applies to the following samples: Method: SW846 8260B N86261-1, N86261-2 CAS No. Compound Result RL MDL Units Q'V 67-64-1 Acetone 71-43-2 Benzene 75-27-4 Bromodichloromethane 75-25-2 Bromoform74-83-9 Bromomethane78-93-3 2-Butanone (MEK)75-15-0 Carbon disulfide56-23-5 Carbon tetrachloride 108-90-7 Chlorobenzene 75-00-3 Chloroethane 67-66-3 Chloroform74-87-3 Chloromethane 124-48-1 Dibromochloromethane 75-34-3 1,1 -Dichloroethane 107-06-2 1,2-Dichloroethane 75-35-4 I,1 -Dichloroethene 156-59-2 cis- 1,2-Dichloroethene 156-60-5 trans-I1,2-Dichloroethene 78-87-5 1,2-Dichloropropane 10061-01-5 cis-],3-Dichloropropene 10061-02-6 trans- 1,3-Dichloropropene 100-41-4 Ethylbenzene 591-78-6 2-Hexanone 108-10-1 4-M ethyl-2-pentanone(M IBK)75-09-2 Methylene chloride 100-42-5 Styrene 79-34-5 1, 1,2,2-Tetrachloroethane 127-18-4 Tetrachloroethene108-88-3 Toluene 71-55-6 1,1 I-Trichloroethane 79-00-5 1, 1,2-Trichloroethane79-01-6 Trichloroethene 75-01-4 Vinyl chloride 1330-20-7 Xylene (total)ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 10 1.0 1.0 4.0 2.0 10 2.0 1.0 1.0 1,0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 2.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 2.3 0.31 0.11 0.17 0.15 2.5 0.23 0.15 0.23 0.73 0.081 0.13 0.18 0.13 0.35 0.81 0.24 0.17 0.11 0.071 0.080 0.27 0.73 0.59 0.20 0.12 0.14 0.37 0.14 0.25 0.17 0.13 0.66 0.17 ug/1 ug/l ug/l ug/l ug/I.ug/l ug/1 ug/l ug/l ug/1 ug/1 ug/l ug/l ug/l ug/l ug/1 ug/l ug/l ug/1 ug/l ug/h ug/l ug/h ug/l ug/1 ug/l ug/l ug/l ug/l ughl ug/I ug!1 ug/l ug/h.37 Method Blank Summary ,lob Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 2 Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch VS2585-MBI S70809.D 1 12/23/04 MMC n/a n/a VS2585 The QC reported here applies to the following samples: Method: SW846 8260B N86261-1, N86261-2 CAS No. Surrogate Recoveries 1868-53-7 Dibromofluoromethane 17060-07-0 1,2-Dichloroethane-D4 2037-26-5 Toluene-D8 460-00-4 4-Bromofluorobenzene 95%89%97%98%Limits 79-119%68-129%83-118%82-120%CAS No. Tentatively Identified Compounds R.T.Est. Conc. Units Q Total TIC, Volatile 0 ug/l to Method Blank SummaryJob Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 1 of 2'Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch VS2588-MB1 S70847.D 1 12/23/04 MMC n/a n/a VS2588 The QC reported here applies to the following samples: Method: SW846 8260BN86261-3, N86261-4, N86261-5, N86261-6 CAS No. Compound Result RL MDL Units Q 67-64-1 Acetone ND 71-43-2 Benzene ND 75-27-4 Bromodichloromethane ND75-25-2 Bromoform ND 74-83-9 Bromomethane ND 78-93-3 2-Butanone (MEK) ND 75-15-0 Carbon disulfide ND 56-23-5 Carbon tetrachloride ND 108-90-7 Chlorobenzene ND 75-00-3 Chloroethane ND 67-66-3 Chloroform ND 74-87-3 Chloromethane ND 124-48-1 Dibromochloromethane ND 75-34-3 1, 1-Dichloroethane ND 107-06-2 1,2-Dichloroethane ND 75-35-4 1,1-Dichloroethene ND 156-59-2 cis- 1,2-Dichloroethene ND 156-60-5 trans-I1,2-Dichloroethene ND 78-87-5 1,2-Dichloropropane ND 10061-01-5 cis- 1,3-Dichloropropene ND 10061-02-6 trans- 1,3-Dichloropropene ND 100-41-4 Elbyibenzene ND 591-78-6 2-Hexanone ND 108-10-1 4-Metbyl-2-pentanone(M IBK) ND 75-09-2 Methylene chloride ND 100-42-5 Styrene ND 79-34-5 1,1,2,2-Tetrachloroethane ND 127-18-4 Tetrachloroethene ND 108-88-3 Toluene ND 71-55-6 1,1,1 -Trichloroethane ND 79-00-5 1,1,2-Trichloroethane ND 79-01-6 Trichloroethene ND 75-01-4 Vinyl chloride ND 1330-20-7 Xylene (total) ND 10 1.0 1.0 4,0 2.0 10 2,0 1.0 1.0 1.0 1.0 1,0 1.0 1.0 1.0 1,0 1.0 1.0 1.0 1,0 1.0 1.0 5.0 5.0 2.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 2.3 ug/l 0.31 ug/t 0.11 ug/l 0.17 ugh 0.15 ug/l 2.5 ug/1l 0.23 ug/h.0.15 ug/l 0.23 ug/1 0.73 ug/1 0.081 ug/l 0.13 ug/l 0.18 ug/l 0.13 ug/l 0.35 ug/l 0.81 ug/l 0.24 ug/l 0.17 ug/l 0.11 ug/I0.071 ug/l 0.080 ug/1 0.27 ug/l 0.73 ug/l 0.59 ug/h 0.20 ug/l 0.12 ug/l 0.14 ug/l 0.37 ug/l 0.14 ug/1.0.25 ug/l 0.17 ug/l 0.13 ug/1 0.66 ug/l 0.17 ug/l 39 Method Blank Summary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 2 Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch VS2588-MB1 S70847.D 1 12/23/04 MMC n/a n/a VS2588 The QC reported here applies to the following samples: Method: SW846 8260BN86261-3, N86261-4, N86261-5, N86261-6 CAS No. Surrogate Recoveries 1868-53-7 17060-07-0 2037-26-5 460-00-4 Dibromofluoromethane 1,2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene 97%98%101%1.00%Limits 79-119%68-129%83-118%82-120%CAS No, Tentatively Identified Compounds Total TIC, Volatile R.T. Est. Conc. Units Q, 0 ug/l" 40
- IV Blank Spike Summary Page 1 of 2 Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch VS2585-BS S708 10. D 1 12/23/04 MMC n/a n/a VS2585 The QC reported here applies to the following samples: Method: SW846 8260B N86261-1, N86261-2 Spike BSP BSP CAS No. Compound' ugth ug/i % Limits 67-64-1 Acetone 50 45.5 91 53-153 71-43-2 Benzene 50 48.0 96 77-119 75-27-4 Bromodichloromethane 50 48.5 97 82-126 75-25-2 Bromoform 50 53.4 107 73-135 74-83-9 Bromomethane 50 53.3 107 61-138 78-93-3 2-Butanone (MEK) 50 46.0 92 58-142 75-15-0 Carbon disulfide 50 33.4 '67 60-130 56-23-5 Carbon tetrachloride 50 47.4 95 72-140 108-90-7 Chlorobenzene 50 50.0 100 81-1 17 75-00-3 Chloroethane 50 53.7 107 69-135 67-66-3 Chloroform 50 45.4 91 80-122 74-87-3 Chloromethane 50 59.7 119 59-132 124-48-1 Dibromochloromethane 50 50.8 102 80-125 75-34-3 1,1-Dichloroethane 50 44.6 89 78-121 107-06-2 1,2-Dichloroethane 50 46.2 92 66-137 75-35-4 1,1-Dichloroethene 50 42.9 86 73-124 156-59-2 cis-1,2-Dichloroethene 50 44.2 88 76-120 156-60-5 trans-1,2-Dichloroethene 50 43.2 86 73-119 78-87-5 1,2-Dichloropropane 50 47.4 95 82-117 10061-01-5 cis-1,3-Dichloropropene 50 47.3 95 81-120 10061-02-6 trans- 1,3-Dichloropropene 50 47.6 95 81-125 100-41-4 Ethylbenzene 50 50.7 101 79-120 591-78-6 2-Hexanone 50 45.3 91 66-140 108-10-1 4-Methyl-2-pentanone(M IBK) 50 47.4 95 70-134 75-09-2 Methylene chloride 50 45.5 91 75-122 100-42-5 Styrene 50 53.8 108 80-125 79-34-5 1,1,2,2-Tetrachloroethane 50 49.3 99 76-117 127-18-4 Tetrachloroethene 50 49.5 99 69-130 108-88-3 Toluene 50 48.2 .96 81-120 71-55-6 1,1,1-Trichloroethane 50 45.3 91 77-132 79-00-5 1,1,2-Trichloroethane 50 48.6 97 85-117 79-01-6 Trichloroethene 50 47.5 95 83-119 75-01-4 Vinyl chloride 50 60,1 120 65-135 1330-20-7 Xylene (total) 150 151 101 81-119 Blank Spike Summary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 2 00 Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch VS2585-BS S70810.D 1 12/23/04 MMC n/a n/a VS2585 The QC reported here applies to the following samples: Method: SW846 8260B N86261-1, N86261-2 CAS No. Surrogate Recoveries 1868-53-7 Dibromofluoromethane 17060-07-0 1,2-Dichloroethane-D4 2037-26-5 Toluene-D8 460-00-4 4-Bromofluorobenzene BSP 95%89%99%97%Limits 79-119%68-129%83-118%82-120%
Blank Spike Summary Page 1 of 2 Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ t Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch VS2588-BS S70848.D 1 12/23/04 MMC n/a n/a VS2588 The QC reported here applies to the following samples: Method: SW846 8260B N86261-3, N86261-4, N86261-5, N86261-6 Spike BSP BSP CAS No. Compound ug/h ug!! % Limits 67-64-1 Acetone 50 48.3 97 53-153 71-43-2 Benzene 50 48.6 97 77-119 75-27-4 Bromodichloromethane 50 49.3 99 82-126 75-25-2 Bromoforn 50 49.5 99 73-135 74-83-9 Bromomethane 50 52.0 104 61-138 78-93-3 2-Butanone (MEK) 50 47.1 94 58-142 75-15-0 Carbon disulfide 50 47.6 95 60-13056-23-5 Carbon tetrachloride 50 50.6 101 72-140 108-90-7 Chlorobenzene 50 51.3 103 81-117 75-00-3 Chloroethane 50 52.9 106 69-135 67-66-3 Chloroform 50 48.5 97 80-122 O 74-87-3 Chloromethane 50 51.4 103 59-132 124-48-1 Dibromochloromethane 50 50.2 100 80-125 75-34-3 1, 1-Dichloroethane 50 50.6 101 78-121 107-06-2 1,2-Dichloroethane 50 51.4 103 66-137 75-35-4 1,1-Dichloroethene 50 47.2 94 73-124 156-59-2 cis-1,2-Dichloroethene 50 47.6 95 76-120 156-60-5 trans- 1,2-Dichloroethene 50 47.3 '95 73-119 78-87-5 1,2-Dichloropropane 50 49.4 99 82-117 10061-01-5 cis- 1,3-Dichloropropene 50 50.3 101 81-120 10061-02-6 trans- 1,3-Dichloropropene 50 50.3 101 81-125 100-41-4 Ethylbenzene 50 50.4 101 79-120 591-78-6 2-Hexanone 50 48.6 97 66-140 108-10-1 4-Methyl-2-pentanone(M IBK) 50 49.5 99 70-134 75-09-2 Methylene chloride 50 48.2 96 75-122 100-42-5 Styrene 50 50.9 102 80-125 79-34-5 1,1,2,2-Tetrachloroethane 50 48.5 97 76-117 127-18-4 Tetrachloroethene 50 51.9 104 69-130 108-88-3 Toluene 50 48.3 '97 81-120 71-55-6 1, 1, l-Trichloroethane 50 48.6 97 77-132 79-00-5 1,1,2-Trichloroethane 50 48.7 97 85-117 79-01-6 Trichloroeihene 50 49.5 99 83-119 *75-01-4 Vinyl chloride 50 53.6 107 65-135 1330-20-7 Xylene (iota]) 150 151 101 81-119 V NtX Blank Spike Summary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 2 Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch VS2588-BS S70848.D1 1 12/23104 MMC n/a n/a VS2588 The QC reported here applies to the following samples: Method: SW846 8260B N86261-3, N86261-4, N86261-5, N86261-6 CAS No. Surrogate Recoveries 1868-53-7 Dibromofluoromethane 17060-07-0 1,2 -Dichloroethane-D4 2037-26-5 Toluene-D8 460-00-4 4-Bromofluorobenzene BSP 98%99%101%99%Limits 79-119%68-129%83-118%82-120%'44 Matrix Spike/Matrix Spike Duplicate Summary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page I of 2'pa Sample File ID DF N86169-2MS S70811. D 5 N86169-2MSD S70812.D 5 N86169-2 S70813.D 5 N86169-2 S70814.D 25 Analyzed By Prep Date Prep Batch Analytical Batch 12/23/04 MMC n/a n/a VS2585 12/23/04 MMC n/a n/a VS2585 12/23/04 MMC n/a n/a VS2585 12/23/04 MMC n/a n/a VS2585 The QC reported here applies to the following samples: Method: SW846 8260B N86261-1, N86261-2 N86169-2 Spike MS ug/I Q ug/l ug/l CAS No. Compound 67-64-1 Acetone ND 71-43-2 Benzene ND 75-27-4 Bromodichloromethane ND 75-25-2 Bromoform ND 74-83-9 Bromomethane ND 78-93-3 2-Butanone (MEK) ND 75-15-0 Carbon disulfide ND 56-23-5 Carbon tetrachloride 2.7 108-90-7 Chlorobenzene ND 75-00-3 Chloroethane ND 67-66-3 Chloroform ND 74-87-3 Chloromethane ND 124-48-1 Dibromochloromethane ND 75-34-3 1,1 -Dichloroethane ND 107-06-2 1,2-Dichloroeihane ND 75-35-4 1, 1 -Dichloroethene 4.3 156-59-2 cis-1,2-Dichloroethene 10 156-60-5 trans-l ,2-Dichloroethene ND 78-87-5 1,2-Dichloropropane ND 10061-01-5 cis-1,3-Dichloropropene ND10061-02-6 trans- ,3-Dichloropropene ND 100-41-4 Ethylbenzene ND 591-78-6 2-Hexanone ND 108-10-1 4-Methyl-2-pentanone(M IBK) ND 75-09-2 Methylene chloride ND 100-42-5 Styrene ND 79-34-5 1,1,2,2-Tetrachloroethane ND 127-18-4 Terrachloroethene 10.9 108-88-3 Toluene ND 71'55-6 1,1,1 -Trichloroethane 3.4 79-00-5 1,1,2-Trichloroethane ND 79-01-6 Trichloroethene 3700 b 75-01-4 Vinyl chloride ND 1330-20-7 Xylene (total) ND 250 240 250 248 250 250 250 276 250 234 250 253 250 232 J 250 255 250 255 250 231 250 237 250 215 250 265 250 236 250 238 3 250 242 250 248 250 240 250 246 250 245 250 244 250 254 250 245 250 236 250 241 250 260 250 254 250 270 250 251 J 250 242 250 253 250 3210 250 229 750 769 MS 96 99 100 110 94 101 93 101 102 92 95 86 106 94 95 95 95 96 98 98 98 102 98 94 96 104 102 104 100 95 101 MSD MSD Limits ug/l % RPD Rec/RPD 224 246 248 267 232 242 236 253 254 226 231 207 260 231 234 240 245 236 244 241 240 252 226 223 238 257 245 270 249 238 2A47.90 7 47-163122 98 1 51-138/10 99 1 80-128/10 107 3 68-137/10 93 1 61-141/17 97 4 55-149/22 94 2 59-128/14 100 1 71-143/13 102 0 78-120/10 90 2 67-139/16 92 3 78-126/1183 4 57-134/17104 2 79-127/10 92 2 75-125/11 ,94 2 .63-142/12 94 1 69-129/12 94 1 73-127/10 94 2 71-123/11 98 1 81-120/10 96 2 78-121/10 96 2 77-128/11 101 1 51-142/11 90 8 64-145/13 89 6 66-140/12 95 1 73-126/10 103 1 79-130/10 98 4 74-121/10 104 0 70-128/12 100 1 49-147/10 94 2 74-136/13 99 2 .83-121/10 -196*a 3180. ,208*a 1 75-128/10 92 228 91,' 0 .60-141/16 103 759 *.l'Oi 1.' .44-146/11 Matrix Spike/Matrix Spike Duplicate Summary Job Number: N86261Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 2 to Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch N86169-2MS S70811.D 5 12/23/04 MMC n/a n/a VS2585 N86169-2MSD S70812,D 5 12/23/04 MMC n/a n/a VS2585 N86169-2 S70813.D 5 12/23104 MMC n/a n/a VS2585 N86169-2 S70814,D 25 12/23/04 MMC n/a n/a VS2585 The QC reported here applies to the following samples: Method: SW846 8260BN86261-1, N86261-2 CAS No. Surrogale Recoveries 1868-53-7 Dibromofluoromethane 17060-07-0 1,2-Dichloroezhane-D4 2037-26-5 Toluene-D8 460-00-4 4-Bromofluorobenzene MS 96%89%99%98%MSD 95%87%99%97%N86]69-2 N86169-2 93%88%97%98%96%89%98%99%Limits 79-119%68-129%83-118%82-120%(a) Outside control limits due to high level in sample relative to spike amount.(b) Result is from Run #2. Matrix Spike/Matrix Spike Duplicate Summary Job Number: N86261 Page 1 of 2 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch N86426-16MS S70849.D 10 12/24/04 MMC n/a n/a VS2588 N86426-16MSDS70850.D 10 12/24/04 MMC n/a n/a VS2588 N86426-16 S70852,D 10 12/24/04 MMC n/a n/a VS2588 The QC reported here applies to the following samples: Method: SW846 8260BN86261-3, N86261-4, N86261-5, N86261-6 N86426-16 Spike MS ug/l Q ug/i ug/l MS MSD MSD Limits CAS No. Compound 67-64-1 Acetone ND.71-43-2 Benzene ND 75-27-4 Bromodichloromethane ND 75-25-2 Bromoform ND 74-83-9 Bromomethane ND 78-93-3 2-Butanone (MEK) ND 75-15-0 Carbon disulfide ND 56-23-5 Carbon tetrachloride ND 108-90-7 Chlorobenzene ND 75-00-3 Chloroethane ND67-66-3 Chloroform ND 74-87-3 Chloromethane ND 124-48-1 Dibromochloromethane ND 75-34-3 ),1-Dichloroethane ND 107-06-2 1,2-Dichloroethane ND 75-35-4 1,1 -Dichloroethene ND 156-59-2 cis- 1,2-Dichloroethene ND156-60-5 trans-1,2-Dichloroethene ND 78-87-5 1,2-Dichloropropane ND 10061-01-5 cis- 1,3-Dichloropropene ND 10061-02-6 trans- 1,3-Dichloropropene ND 100-41-4 Ethylbenzene ND 591-78-6 2-Hexanone ND 108-10-1 4-Methyl-2-pentanone(MIBK) ND 75-09-2 Methylene chloride ND 100-42-5 Styrene ND 79-34-5 1,1,2,2-Tetrachloroethane ND 127-18-4 Tetrachloroethene 1460 108-88-3 Toluene ND 71-55-6 1,1,1 -Trichloroethane ND79-00-5 1,1,2-Trichloroethane ND 79-01-6 Trichloroethene ND 75-01-4 Vinyl chloride ND 1330-20-7 Xylene (total) 4.2 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 1 1500 512 501 502 508 506 482 463 518 513 518 479 502 508 502 517 471 472 473 507 505 508 508 500 499 474 509 495 1870 495 481 499 506 519 1530% ug/h % RPD Rec/RPD 102 509 102 1 47-163/22 100 494 99 .1 51-138/10 100 495 99 1 80-128/10 102 498 1.00 2 68-137/10 101 487 97 4 61-141/17 96 497 99 3 55-149/22 93 450 90 3 59-128/14 104 501 100 3 71-143/13 103 513 103 0 78-120/10104 501 100 3 67-139/16 96 470 94 2 78-126/11 100 481 96 4 57-134/17 102 507 101 0 79-127/10 100 490 98 2 75-125/11 103 506 101 2 63-142/12 94 461 92 2 69-129/12 94 471 94 0 73-127/10 95 455 91 4 71-123/11 101 507 101 0 81-120/10 101 493 99 2 78-121/10 102 497 99 2 77-128/11 102 503 101 1 51-142/11 100 485 97 3 64-145/13 100 487 97 2 66-140/12 95 465 93 2. 73-126/10 102 504 101 1 79-130/10 99 488 98 1 74-121110 82 1850 78 .1 70-128/12 99 485 .97 2 49-147/10 96 469 94 3 74-136/13 100 489 08. 2 83-121110 101 495 99. 2 ' 75-128110 104 504 -101 3. 60-141/16 102 1500 100 -2.' 44-146/11 4.7 Matrix Spike/Matrix Spike Duplicate Summary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 2'V, Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch N86426-I6MS S70849.D 10 12/24/04 MMC n/a r/a VS2588 N86426-16MSDS7085O.D 10 12/24/04 MMC n/a n/a VS2588 N86426-16 S70852.D 10 12/24/04 MMC n/a n/a VS2588 The QC reported here applies to the following samples: Method: SW846 8260BN86261-3, N86261-4, N86261-5, N86261-6 CAS No. Surrogate Recoveries 1868-53-7 17060-07-0 2037-26-5 460-00-4 Dibromofluoromethane 1,2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene MS 97%97%101%99%MSD 96%96%100%99%N86426-16 Limits 97%99%100%100%79-119%68-129%83-118%82-120% Instrument Performance Check (BFB)Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page I of !Sample: VS2585-BFB Injection Date: 12/22/04 Lab File ID: S70797.D Injection Time: 19:37 Instrument ID: GCMSS Raw % Relative m/e Ion Abundance Criteria Abundance Abundance Pass/Fail 50 15.0- 40.0% of mass 95 2513 15,2 Pass 75: 30.0 -60.0% of mass 95 7106 43.0 Pass 95 Base peak, 100% relative abundance 16507 100.0 Pass 96,. 5.0- 9.0% of mass 95 1129 6.8 Pass 173 Less than 2,0% of mass 174 0 0.0 (0.0) a Pass1743 :. .50.0 -150.0% of mass 95 15383 93v2 Pass 175,. ' 5.0 -9.0% of mass 174 1106 6.7 '(7.2) a Pass 176 .95.0- 101.0% of mass 174 14932 90.5 (97.1) 8 Pass 177 77 5.0- 9.0% of mass 176 1003 6.1 (6.7) b Pass (a) Value is % of mass 174 (b) Value is % of mass 176 This check applies to the following Samples, MS, MSD, Blanks, and Standards: Lab Lab Date Time lHours Client Sample ID File )D Analyzed Analyzed Lapsed Sample ID VS2585-IC2585 S70799.D 12/22/04 20:37 01:00 Initial cal 5 VS2585-1C2585 $70800.D 12/22/04 21:06 01:29 Initial cal 2 VS2585-1C2585 S70801.D 12/22/04 21:37 02:00 Initial cal 1 VS2585-]C2585 S70803.D 12/22/04 22:36 02:59 Initial cal 20 VS2585-1CC2585 S70804.D 12/22/04 23:06 03:29 Initial cal 50 VS2585-IC2585 S70805.D 12/22/04 23:36 03:59 Initial cal 100 VS2585-1C2585 S70806.D 12/23/04 00:06 04:29 Initial cal 200 VS2585-MBI S70809.D 12/23/04 01:36 05:59 Method Blank VS2585-BS S70810.D 12/23/04 02:06 06:29 Blank Spike N86169-2MS S70811.D 12/23/04 02:36 06:59 Matrix Spike N86169-2MSD S70812.D 12/23/04 03:06 07:29 Matrix Spike Duplicate* N86169-2 S70813.D 12123/04 03:36 07:59 (used for QC only; not part of job N86261)N86169-2 S70814.D 12/23/04 04:06 08:29 (used for QC only; not part of job N86261)ZZZZZZ S70815.D 12/23/04 04:36 08:59 (unrelated sample)ZZZZZZ $70816.D 12/23/04 05:06 09:29 (unrelated sample)ZZZZZZ S70817.D 12/23/04 05:36 09:59 (unrelated sample)ZZZZZZ S70818.D 12/23/04 06:06 10:29 (unrelated sample)N86261-1 S70819.D 12/23/04 06:36 10:59 WELL AY N86261-2 S70820.D 12/23/04 07:07 11:30 WELL AV Instrument Performance Check (BFB) Page 1 of I Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Sample: VS2588-BFB Injection Date: 12123/04 Lab File ID: S70844.1) Injection Time: 21:49 Instrument ID: GCMSS Raw % Relative rn/e Ion Abundance Criteria Abundance Abundance Pass/Fail 50.. 15.0 -40.0% of mass 95 2823 16.8 Pass 75. 30.0- 60.0% of mass 95 7610. 45.2 Pass 95.'. Base peak, 100% relative abundance 16852 100.0 Pass 96, 5.0 -9.0% of mass 95 1141 6.8 Pass 173 Less than 2.0% of mass 174 0 0.0 (0.0) a Pass:174 50.0 -150.0% of mass 95 16207 96.2 Pass 175 5.0 -9.0% of mass 174 1147 6.8 (7.1). Pass 176 95.0 -101.0% of mass 174 15861 94.1 (97.9)a Pass 177 5.0 -9.0% of mass 176 1018 6.0 (6.4) b Pass (a) Value is % of mass 174(b) Value is % of mass 176 This check applies to the following Samples, MS, MSD, Blanks, and Standards: Lab Lab Date Time Hours Client Sample ID File ID Analyzed Analyzed Lapsed Sample ID VS2588-CC2585 S70845.D 12123/04 22:19 00:30 Continuing cal 50 VS2588-MBl S70847.D 12/23/04 23:19 01:30 Method Blank VS2588-BS S70848.D 12/23/04 23:49 02:00 Blank Spike N86426-16MS S70849.D 12/24/04 00:20 02:31 Matrix Spike N86426-16MSD S70850.D 12/24/04 00:50 03:01 Matrix Spike Duplicate N86426-16 S70852.D 12/24/04 01:50 04:01 (used for QC only; not part oif job N86261)N86261-3 S70853.D 12/24/04 02:20 04:31 WELL X N86261-4 S70854.D 12/24/04 02:50 05:01 FB-2 N86261-5 S70855.D 12/24/04 03:20, 05:31 TRIP BLANK N86261-6 S70856.D 12/24/04 03:50 06:01 WELL AX ZZZZZZ S70857.D 12/24/04 04:20 06:31 (unrelated sample)ZZZZZZ S70858.D 12/24/04 04:50 07:01 (unrelated sample)ZZZZZZ S70859.D 12/24/04 05:20 07:31 (unrelated sample)ZZZZZZ S70860.D 12/24/04 05:49 08:00 (unrelated sample)ZZZZZZ S70861.D 12/24/04 06:19 08:30 (unrelated sample)ZZZZZZ S70862.D 12/24/04 06:49 09:00 (unrelated sample)ZZZZZZ S70863.D 12/24/04 07:19 09:30 (unrelated sample)ZZZZZZ $70864.D 12/24/04 07:49 10:00 (unrelated sample)ZZZZZZ $70865.D 12/24/04 08:19 10:30 (unrelated sample)ZZZZZZ $70866.D 12/24/04 08:49 11:00 (unrelated sample)., ZZZZZZ S70867.D 12/24/04 09:19 11:30 (unrelated sam.pl).50 Volatile Internal Standard Area Summary Page I of I Job Number: Account: Project: N86261 AGMPAL Arcadis Geraghty & Miller PSEG-Salem, Artificial Island, Salem, NJ to Check Std: VS2585-1CC2585. Injection Date: 12/22/04 Lab File ID: S70804.D Injection Time: 23:06 Instrument ID: GCMSS Method: SW846 8260B 1S1 IS2 IS3 IS4 IS5 AREA RT AREA RT AREA RT AREA RT AREA RT Check Srd 142231. 7.59 257444 9.60 389270 10.47 380451 13.70 240635 16.26 Upper Limit a 284462 8.09 514888 10.10 778540 10.97 760902 14.20 481270 16.76 Lower Limit b 71:116 7.09 128722 9.10 194635 9.97 190226 13.20 120318 15.76 Lab Sample ID VS2585-MI 1 VS2585-BS N86169-2MS N86169-2MSD N86169-2 N86169-2 zzzzzz zzzzzz zzzzzz zzzzzz N86261-1 N86261-2 IS 1 AREA 146231.147868 151407 140254 147506 146803 125035 131835 130848 125106 110965 107650 IS 2 RT AREA IS3 IS4 RT AREA RT AREA IS 5 RT AREA RT 7.59 7.59 7.59 7,59 7.59 7.59 7.59 7.59 7.59 7.59 7.59 7.59 289404 288868 290286 293852 295324 289224.283538 280986 270971 263077 254342 250030 9.60 9.60 9.60 9.60 9.59 9.60 9.60 9.60 9.60 9.60 9.59 9.60 417767 421316 426442 428565 424180 415806 409689 406180 3955118 387494 376908.371416 10.48 10.47 10.47 10,47 10.48 10.48 10.48 10.48 10.48 10.48 10.48 10.48 400467 401379 407447 411518 409233 401922 394160 392546 384068 373512 363663 359174 13.70 13.70 13.70 13.70 13.70 13.70 13.70 13.70 13.70 13.70 13.70 13.70 255030 257236 258599 260543 257996 253438 251281 246523 242839 236236 227335 225266 16.25 16.26 16.25 16.25 16.26 16.25 16,26 16.26 16.26 16.26 16.25 16.26 IS 1 IS2 IS 3 IS 4= Ten Butyl Alcohol-D9 = Pentafluorobenzene = 1,4-Difluorobenzene = Chlorobenzene-D5 IS 5 = 1,4-Dichlorobenzene-d4 (a) Upper Limit = + 100% of check standard area; Retention time 40.5 minutes.(b) Lower Limit = -50% of check standard area; Retention time -0.5 minutes. 4t Volatile Internal Standard Area Summary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 1 of I Check Std: VS2588-CC2585 Injection Date: 12/23/04 Lab File IID: $70845.D Injection Time: *22:19 instrument ID: GMSMethod: SW846 8260B IS1 IS2 IS3 IS4 1S5 AREA RT AREA RT AREA RT AREA RT AREA RT Check Std 137731 7.59 257340 9.60 382506 10.48 359753 13.70 228607 16.26 Upper Limita 275462 8.09 514680 10.10 7650.12 10.98 719506 14.20 457214 16.76 Lower Limit b :68866.- 7.09 128670.. 9.10 191253 9.98 .179877 13.20 114304 15.76 Lab Sample ID VS2588-MB1 VS2588-BS N86426-16MS N86426-16MSD N86426-16 N86261-3 N86261-4 N86261-5 N86261-6 zzzzzz zzzzzz ZZzzzz zzzzzz zzzzzz zzzzzz zzzzzz zzzzzz zzzzzz zzzzzz zzzzzz IS 1 AREA 13*1125 131699 1.36033 136296 133500 120415 128228 123466 1,16999 122387 109691 120296 118918 1*06796 115458 1.12796 1104337 112795 t12528 113603 IS 2 RT AREA IS 3 RT AREA IS4 1S5 RT AREA RT AREA RT 7.59 7.59 7.59 7.59 7.59 7.59 7.59 7.59 7.59 7.59 7.59 7.59 7.59 7.59 7.59 7.59 7.59 7.59 7.59 7.59 247644 248149 255696 261044 252007 244167 235560 230812 223659 217805 217564 214180 211713 208786 207976 206573 205003, 206563 206622 204502 9.60 9.60 9.60 9.60 9.60 9.60 9.60 9.60 9.60 9,60 9.60 9.60 9.60 9.60 9.60 9.60 9.60 9.60 9,60 9.60 358779 372637 375540 383760 368707 355427 347723 338799 330045 323296 319471 318943 316009 311868 313487 310471 307457 309066 310173 306543 10.48 10.48 10.48 10.48 10.47 10.48 10.48 10,47 10.48 10.48 10.48 10.48 10.47 10.48 10.48 10.47 10,48 10.48 10.48 10.48 342020r 352707 358609 3632.12 351813 337546 329152 324546 316585 309483 308098 305573 29843.1 300189 297167 296110 293669.294663 295909 294262 13.70, 218134 13.70 225729 13.70 22791013.70 229267 13.70 222458 13,70 215032 13.70 20876513.70 202292 13.70 199045 13.70 197850 13.70 194245 13.70 192701 13.70 190263 13.70 .189700 13.70 187999 13.70 187184 13.70 186044 13,70 188296 13.70 189108 13.70 186671 16.25 16.25 16.25 16,26 16.25 16.26 16,25 16.25 16.26 16.25 16.26 16.25 16.25 16.25 16.25 16.25 16.25 16.25 16.25 16.26 IS I IS 2 IS 3 IS 4= Ten Butyl Alcohol-D9 = Pentafluorobenzene = 1,4-Difluorobenzene = Chlorobenzene-D5 IS 5 = 1,4-Dichlorobenzene-d4 (a) Upper Limit = + 100% of check standard area; Retention time +0.5 minutes.(b) Lower Limit -50% of check standard area; Retention time -0.5 minutes.52 Volatile Surrogate Recovery Summary Page 1 of I Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ bMethod: SW846 8260B Matrix: AQ Samples and QC shown here apply to the above method Lab Lab Sample ID File ID S1 S2 S3 S4 N86261-1 S70819.D 99.0 95.0 98.0 101.0 N86261-2 S70820.D 99.0 97.0 98.0 101.0 N86261-3 S70853.D 97.0 99.0 100.0 100.0 N86261-4 S70854.D 98.0 101.0 100.0 102.0 N86261-5 S70855.D 99.0 103,0 101.0 103.0 N86261-6 S70856.D 100.0 105.0 101.0 101,0 N86169-2MS S70811.D 96.0 89.0 99.0 98.0 N86169-2MSD S70812.D :95.0 87.0 99.0 97.0 N86426-16MS S70849.D 97.0 97.0 101.0 99.0 N86426-16MSD S70850.D 96.0 96,0 100.0 99.0 VS2585-BS S70810.D 95.0 89.0 99.0 97.0 VS2585-MB1 $70809.D 95.0 89.0 97.0 98.0 VS2588-BS S70848.D 98.0 99.0 101.0 99.0 VS2588-MBI S70847.D '97.0 98.0 101.0 100.0 Surrogate Recovery Compounds Limits S1 = Dibromofluoromethane 79-119%S2 = 1,2-Dichloroethane-D4 68-129%S3 = Toluene-D8 83-118%S4 = 4-Bromofluorobenzene 82-120% Initial Calibration Summary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page ] of 3 Sample: VS2585-ICC2585 Lab FilelD: S70804.D Response Factor Report MSS Method Title Last Update Response via C:\HPCHEM\I\METHODS\MS2585.M (RTE Integrator) SW-846 Method 8260 Thu Dec 23 08:35:44 2004 Initial Calibration Calibration Files 1 =S70801.D 200 =S70806.D 5 100 =S70805.D=$70799.D 50 =S70804.D 2 =S70800.D 20 =$70803.D Compound 1 100 50 20 200 5 2 Avg %RSD........................................................................... 1)2)3)I Tert Butyl tertiary but 1,4-dioxane Alcohol-d9
ISTD ---------------------1.133 1.150 1.175 1.105 1.084 1.047 1.116 0.110 0.106 0.092 0.106 0.082 0.099 4.16 12.05 4)5)6)7)8)9)10)11)12)13)14)15)16)17)I pentafluorobenzene --ISTD --------------------- chlorodifluo 0.494 dichlorodifl chloromethan 0.497 vinyl chlori 0.470 bromomethane 0.395 chloroethane 0.286 trichloroflu ethyl ether acrolein 0.078 1,1-dichloro 0.548 0.484 0.427 0.438 0.502 0.355 0.261 0.614 0.278 0.060 0.483 0.106 1.188 0.034 0.521 0.445 0.466 0.534 0.386 0.292 0.640 0.288 0.069 0.484 0. 122 1.330 0.042 0.561 0.470 0.499 0.546 0.411 0.311 0.659 0.293 0.081 0.509 0.124 1.377 0.044 0.454 0.390 0.400 0.474 0.312 0.221 0.579 0.270 0.470 0.101 1.098 0.032 0.539 0.487 0.436 0.474 0.447 0.515 0.479 0.417 0.390 0.312 0.280 0.582 0.274 0.235 0.082 0.079 0.503 0.486 0 .120 1.411 1.359 0.051 0.506 7.26 0.434 6 .71 0.460 7.65 0.503 5.99 0.381 9.57 0.280 11.29 0.615 5.74 0.273 7.55 0.075 11.43 0.497 5-.21 0.115 9.22 1.305 8.90 0.040 18.62 acetone allyl chlori acetonitrile 1.370-Linear regression
Coefficient
0.9959 Response Ratio = 0.05590 + 0.03105 *A 18)19)20)21)22)23)24)25)26)27)28)29)30)31)32)33)34)35)36)iodomethane iso-butyl al carbon disul methylene ch methyl aceta methyl tert trans-1,2-di di-isopropyl 2-butanone 0.923 0.957 0.006 1.886*1.640 0.555 0.529 0.294 1.504 1.401 0.608 0.516 1.471 1.389 0,057 0.967 0.007 1 .711 0.548 0.332 1.491 0.533 1.510 0.060 0.984 0.007 1.772 0.570 0.333 1.535 0.540 1.577 0.058 0.947 0.955 0.872 0.006 1.575 0.514 0.274 1.333 0.500 1.282 0.054 0 006 1.793 1.645 0.567 0.489 0 .320 1.557 1.462 0.546 0.525 1.584 1.462 0 .040 0.943 0 .006#1.717.0.539 0.311 1.469 0.538 1.468 0.054 3.90 6.78 6.22 5.53 8.23 5.34 6.37 7 .26 15.43 5.05 8.66 9.73 2.2 .'54-Linear regression------ -Coefficient
0.9983 Response Ratio = 0.00244 + 0.05419 *A 1,1-dichloro 0.856 0.812 0.866 0.900 0.773 0.871 0.826 0..843 chloroprene 0.438 0,510 0.543 0.563 0.489 0.521 0.465 0.504 acrylonitril 0.162 0.180 0.179 0.148 0.181 0.146 0.166 vinyl acetat 0.086 0.090 0.081 0.085 0.047 ' .0.078-Linear regression
Coefficient
= 0,.999.3 Response Ratio = -0.00019 + 0.08516 *A ethyl tert-b 1.517 1.517 ethyl acetat 0.056 2,2-dichloro 0.703 0.638 cis-1,2-dich 0.609 0.563 propionitril 0.048 0.064 bromochlorom 0.243 0.279 1.614 0.062 0.677 0.582 0.071 0.284 1.656 0.060 0.722 0.599 0.072 0.289 1.453 0.052 0.599 0.542 0.059 0.275 1.653 1.547 0. 045 0.728 0.662 0.601 0.574 0.068 0.058 0.276 0.254 1.565 -4 95 0.055 12.54 0.676 .6.93 0.582 4 08 S.063.73 68 0.2 7 1!54 17 Initial Calibration SummaryJob Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 3 Sample: VS2585-ICC2585 Lab FilelD: S70804.D 37)38)39)40)41)42)43)44)tetrahydrofu chloroform dibromofluor 1,2-dichloro freon 113 methacryloni 1,h1,-trichl Cyclohexane 0 .123 0.871 0 .824 0.461 0 .440 0.447 0.398 0.335 0 .419 0 230 0.772 0.7260.755 0.732 0.148 0.874 0.451 0.423 0 .412 0 .251 0,766 0.756 0.148 0.903 0.455 0.434 0.415 0.257 0.797 0.780 0 .114 0.795 0.436 0.380 0.407 0.218 0.703 0.701 0.147 0.140 0.8.73 0.854 0.466 0.460 0.455 0.452 0.397 0.343 0.234 0.782 0.735 0.782 0.678 0.137 0.856 0.453 0.427 0.390 0.238 0.755 0.741 45) I 1,4-difluorobenzene
ISTD ------------------- 46)47)48)49)50)51)52)53)54)55)56)57)58)59)60)61)62)63)64)65)66)67)68)69)70)71)72)73)74)Di-isobutyle 0.617 epichlorohyd n-butyl alco carbon tetra 0.428 0.649 0 .033 0.010 0.443 0.409 0.297 1,1-dichloro hexane tert amyl al benzene tert-amyl me heptane isopropyl ac 1,2-dichloro trichloroeth 2-nitropropa 2-chloroethy methyl metha 1,2-dichloro dibromometha methylcycloh bromodichior cis-l,3-dich toluene-d8 (4-methyl-2-p toluene 3-methyl-l-b trans-1,3-di ethyl methac 1,1,2-trichl 2-hexanone 0.417 0.302 1.378 1.235 1.042 1.005 0.108 0.128 0.4890.352 0.341 0.321 0.342 0.2550.149 0.184 0.311 0.310 0.326 0.169 0.205 0.415 0.4600.385 0.435 0.504 0.544 1.139 1.159 0.455 0.838 0.853 0.018 0.018 0.448 0.474 0,319 0.426 0.227 0.253 0.178 0.660 0.036 0.011 0.450 0.424 0.304 1.309 1.070 0.130 0.533 0.364 0.351 0.288 0.198 0.323 0.339 0.211 0.462 0.452 0.558 1.167 0.509 0.870 0.020 0.497 0.448 0.263 0.182 0.654 0.035 0.010 0.457 0.425 0.309 1.348 1.080 0.135 0.541 0.376 0.350 0.306 0.193 0.316 0.344 0.215 0.462 0.451 0.565 1.156 0 .527 0.875 0.021 0.499 0.439 0.262 0. 169 0.638 0.031 0,009 0.437 0.392 0.281 1.114 0 .920 0 124 0.466 0.324 0.338 0.223 0.170 0.300 0.315 0.201 0.449 0.426 0.531 1.163 0.410 0.833 0.016 0.464 0.417 0.251 0.171 0.642 0,034 0.009 0 .449 0.431 0.302 1.361 1.077 0.130 0.543 0.376 0.351 0.318 0. 181 0.299 0,336 0.201 0.440 0.438 0.544 1 .156 0.535 0.835 0 .021 0 .479 0.418 0 256 0 .105 0 .595 0.026 0.398 0.401 0.287 1.302 1.043 0. 117 0.497 0.353 0.319 0.276 0.162 0.322 0.191 0.422 0.404 0.515 1.149 0.489 0.799 0.016 0.439 0.363 0.227 4w 0.636 0.033 0 .010#0.437 0.414 0.297 0 .000#1.292 1.034 0.125 0.512 0.355 0.339 0.278 0. 177 0.310 0.328 0. 199 0 .444 0.427 0.537 1.155 0.488 0 .844 01.018 0.471 0.404 0,248 0.161 0.317 0.495 0.213 0.372 0.319 1 .002 0.380 1 .554 0 .652 0.682 1.075 0,275 10.80 4.19 2.48 6.67 9.08 6.60 4.48 5.32 3.62 11.42 10.55 4.55 3.41 3.31-1.00 7.11 5,48 7.58 6.26 5.30 4 .07 12.51 9.74 3.27 3.90 7.65 4 .34 5.82 4 .10 0.82 9.74 3.06 11.64 4.83 11.50 6.11 19.70 4 .99 4 .51 9.68 7.05 7.49 2.06 4 .96 3.36 3.43 3.43 5.27 11.39 3 .08 2.09-Linear regression Coefficient = 0.9990 Response Ratio = 0.00202 + 0.17205 *A 75) I chlorobenzene-d5
ISTD--------------- 76)77)78)79)80)81)82) 83)84)85)86)87)tetrachlorce 1,3-dichloro butyl acetat dibromochlor 1,2-dibromoe chlorobenzen 1,1,1,2-tetr ethylbenzene m,p-xylene o-xylene styrene bromoform 0.308 0.327 0.472 0.485 0.209 0.342 0.390 0.277 0.331 1.004 1.002 0.370 0.389 1.524 1.556 0.640 0.652 0.686 0.684 1.028 1.109 0.231 0.300 0.328 0.513 0.230 0.393 0.342 1.016 0.394 1.600 0.669 0.698 1. 128 0.299 0.327 0. 527 0. 234 0.388 0.335 1. 033 0 .393 S.626 0.685 0.714 1.132 0.286 0.332 0.468 0. 195 0.391 0. 328 0. 986 0.390 1.506 0.638 0.672 1.088 0. 307 0.312 0.510 0.229 0.368 0.324 1.006 0.380 1.583 0.664 0.678 1.068 0 .267 0.288 0.488 0.184 0.329 0 .293 0.968 0.342 1.483 0.618 0.639 0.976 0.235 88) I 1,4-dichlorobenzene-d
ISTD----------------------
- 89) isopropylben 2.301 2.320 2.373 2.388 2.262 2.276 2.179 2.300 90) 4-bromofluor 0.779 0.742 0.757 0.759 0 .736 0.769 0.773 0.759 Initial Calibration Summary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 3 of 3 Sample: VS2585-ICC2585 Lab FilelD: S70804.D 91)92)93)94)95)96)97)98)99)100)101)102)103)104)105)106)107)108)109)110)111)112)113)114)115)cyclohexanon bromobenzene 1,1,2,2-tetr trans-l,4-di 1,2,3-trichl n-propylbenz 2-chlorotolu 4-chlorotolu 1,3,5-trimet tert-butylbe pentachloroe 1,2,4-trimet sec-butylben 1,3-dichloro p-isopropylt 1,4-dichloro vinyltoluene 1,2-dichioro n-butylbenze 1,2-dibromo-1,2,4-trichl hexachlorobu naphthalene 1,2,3-trichl hexachloroet 0.766 0.710 0.141 2.820 2.124 1.968 2. 131 1.137 0 .440 2.248 2 .518 1. 529 2.137 1.620 0.774 0.700 0.164 0.194 2.799 2.041 1.895 2.141 1.127 0 .530 2.279 2.586 1.504 2.268 1.578 0.788 0.741 0.175 0.203 2,923 2.099 1.947 2.170 1.148 0.530 2.311 2.629 1.517 2.261 1.586 1.535 1.889 0.137 0.953 0.375 2.288 0.801 0.438 0.780 0.732 0.190 0.203 2 .981 2 .125 1.989 2.193 1.180 0.519 2.343 2. 615 1.525 2.272 1.610 1.537 1.919 0.138 0.958 0.388 2.307 0 .824 D.420 0.770 0.678 0.166 0.186 2.663 1.988 1.852 2.081 1. 100 0.528 2.222 2.504 1.486 2.2195 1.537 1.457 1.786 0.117 0.886 0.349 2.026 0.738 0.453 0.761 0. 724 0.184 0.205 2,908 2.094 1.955 2.09.8 1.121 0.478 2.218 2,471 1.503 2.158 1.557 1.505 1.834 0.136 0. 900 0.383 2.233 0.798 0.378 0.712 0.707 0 .154 0.189 2 .764 2.065 1.895 1. 984 1.039 0.456 2 .123 2.361 1.399 2.023 1.528 1.422 1.710 0. 125 0.841 0.379 2.060 0.730 0.337 0.000#'-1.00 0.765 3.26 0.713 3.00 0.168 10.25 0.197 4.20 2.837 3.82 2.077 2.38 1.928 2.54 2.114 3.26 1.122 3.93 0.497 7 .77 2,249 3.21 2.526 3.72 1.495 2.98 2.188 4.15 1.574 2:21 0.000# -1,00 1.495 2.85 1.835 3.80 0.130 6.36 0.909 4.48 0.373 3.91 2.176 5.03 0.771 4.79 0.413 11.19 1.488 1.520 1.836 1.868 0 .1280.897 0.926 0.361 2.123 2 197 0.740 0.770 0.450 (4) = Out of Range #4# Number of calibration levels exceeded format fi#4 MS2585.M Thu Dec 23 16:50:49 2004 RPT!to 56 Continuing Calibration Summary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page ] of 3 Sample: VS2588-CC2585 Lab FilelD: S70845.D Evaluate Continuing Calibration Report Data File C:\HPCHEM\I\DATA\S70845.D Vial: Acq On : 23 Dec 2004 10:19 pm Operator: Sample : cc2585-50
.Inst Misc : MS8620,VS2588,5,,, I Multiplr: MS Integration Params: LSCINT.P 100 mei MSS 1.00 Method Title Last Update Response via Min. RRF Max. RRF Dev C:\HPCHEM\I\METHODS\MS2585.M (RTE Integrator) SW-846 Method 8260 Thu Dec 23 08:35:44 2004 Single Level Calibration 0.010 Min. Rel. Area : 50% Max. R.T. Dev 20% Max. Rel. Area : 200%0. 50min Compound AvgRF CCRF%Dev Area% Dev(min)R.T. 1 2 3 4 5 6 7 8 9 10 11 12 23 14 15 16 I M N I M M M M M M.M M N M N M Tert Butyl Alcohol-d9 tertiary butyl alcohol 1,4-dioxane pentafluorobenzene chlorodifluoromethane dichlorodifluoromethane chloromethane vinyl chloride bromomethane chloroethane trichlorofluoromethane ethyl ether acrolein 1,l-dichloroethene acetone allyl chloride 1.000 1.116 0.099 1.000 0.506 0.434 0.460 0.503 0.381 0.280 0.615 0.273 0. 075 0 .497 0. 115 1 305 1.000 1.150 0.096 2.000 0.558 0.432 0.475 0.536 0.397 0,295 0.632 0.270 0. 054 0.466.11.3 1.268 0.0-3.0 3.0 0.0-10.3 0.5-3.3-6.6-4.2-5.4-2.8 1.1 28. ,0 6.2 1,7 2.8% Drift-2.3 97 0.00 97- 0.00 88. 0.00 100 107 97 102 100 103 101 99 94 78 96 93 95 0.00-0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00.0.00 7.59 7.70 12.18 9.60 4.41 4.40 4 .76 5.01 5.67 5.83 6.26 6.61 6.88 7 .02 7 .08 7.49 7.48----------------------- True Calc.17 M acetonitrile 500.000 511.327 90 0.00 18 19 20 21 22 23 24 25 M M M M M M M M-- AvgRF iodomethane 0.943 iso-butyl alcohol 0.006 carbon disulfide 1.717 methylene chloride 0.539 methyl acetate 0.3i1 methyl tert butyl ether 1.469 trans-l,2-dichloroethene 0.538 di-isopropyl ether 1.468 CCRF 0.955 0. 007#1.602 0.523 0.318 1.417 0.513 1.468 Calc.48.108 CCRF 0.845 0.536 0.166 Calc.46.715% Dev-2.3-16.7 6.7 3.0-2.3 3.5 4.6 0.0 99 99 94 95 96 95 96 97 0.00 0.00 0.00 0. 00 0.00 0.00 0.00 0.00 7.30 9.90 7.43 7.67 7.46 7 .93 7 .99 8.43----------------------- True 26 M 2-butanone 50.000----------------------- AvgRF 27 M l,l-dichloroethane 0.843 28 M chloroprene 0.504 29 M acrylonitrile 0.166----------------------- True 30 M vinyl acetate 50.000% Drift 3.8% Dev-0.2-6.3 0.0% Drift 6.6 91 0.00 9.14 97 0.00 8.51 99 0.00 8.60 92 0.0.0 7.97 88 0.00 Continuing Calibration Summary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Anificia] Island, Salem, NJ Page 2 of 3 Sample: VS2588-CC2585 Lab FilelD: S70845.D 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 72 72 73 ethyl tert-butyl ether ethyl acetate 2,2-dichloropropane cis-l,2-dichloroethene propionitrile bromochloromethane tetrahydrofuran chloroform dibromofluoromethane (s)1,2-dichloroethane-d4 (s)freon 113 methacrylonitrile 1,1,1-trichloroethane Cyclohexane 1,4-difluorobenzene Di-isobutylene 'epichiorohydrin n-butyl alcohol carbon tetrachloride 1,1-dichloropropene hexane tert amyl alcohol benzene tert-amyl methyl ether heptane isopropyl acetate 1,2-dichloroethane trichloroethene 2-nitropropane
2-chloroethyl vinyl ether methyl methacrylate 1,2-dichloropropane dibromomethane methylcyclohexane bromodichloromethane cis-l,3-dichloropropene toluene-d8 (s)4-methyl-2-pentanone toluene 3-methyl-l-butanol trans-i,3-dichloropropene ethyl methacrylate 1,1,2-trichloroethane -AvgRF 1.565 0.055 0.676 0.582 0.063 0.271 0.137 0.856 0.453 0.427 0.390 0.238 0.755 0.741 1.000 0.636 0.033 0.010 0.437 0.414 0.297 0.000 1.292 1.034 0.125 0.512 0.355 0.339 0.278 0.177 0.310 0.328 0.199 0.444 0.427 0.537 1.155 0.488 0,844 0 .018 0.471 0.404 0.248 CCRF 1. 570 0. 058 0. 675 0.555 0.065 0. 274 0.128 0.816 0.444 0.413 0.438 0.232 0.731 0.758 1.000 0.663 0.033 0.010 0.442 0.424 0.317 0 .ooo 1.270 1 .037 0.134 0.515 0.359 0.336 0.278 0.188 0.305 0 .330 0.199 0.473 0.423 0.540 1.152 0.477 0.822 0.018 0.472 0.410 0,244% Dev-0.3-5.5 0.1 4.6-3.2-1.1 6.6 4.7 2.0 3.3-12.3 2.5 3.2-2.3 0.0-4.2 0.0 0.0-I.1-2.4-6.7 0.0 1.7-0.3-7.2-0.6-1.1 0.9 0.0-6.2 1.6-0.6 0.0-6.5 0.9-0.6 0.3 2.3 2.6 0.0-0.2-1.5 1.6 97 93 100 95 91 96 86 93 98 98 106 93 95.100 98 99 91 89 97 98 103 93 95 95 101 95 97 94 95 94 93 96 92 101 92 95 97 92 93 90 93 90 91 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0 .00 0 .00 0.00 0 .00 0.00 0.00 0 .00 0. 00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0 .00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 8.85 9.12 9.18 9.18 9.25 9.47 9.50 9.50 9.69 10.09 6.97 9.41 9.74 9.81 10 .48 10.66 11.72 10.579. 93 9.91 8.23 10 .02 10.16 10.14 10.25 10.02 10.18 10.82 11.88 11.56 11.04 11.08 12.25 2.1.02 11.36 11.80 12.009 11.88 12.17 11. 88 12.37 12 .32 12.60 74 M 2-hexanone 75 76 77 78 79 80 81 I M M M M M M chlorobenzene-d5 tetrachloroethene 1,3-dichloropropane butyl acetate dibromochloromethane 1,2-dibromoethane chlorobenzene -True Calc.50.000 49.419-AvgRF CCRF 1.000 1.000 0.317 0.323 0 .495 0.503 0.213 0.2230.372 0.372 0.319 0.322 1.002 1.031 0.380 0.395 1.554 1.578 Drift ------------ 1.2 93 0.00 1. 2.76% Dev 0.0-1.9-1.6-4.7 0.0-0.9-2.9-3.9-1.5 95 0.00 13.70 93 0.00 12.78 93 0.00 12.80 92 0.00 12.81 89 0.00 13.09 89 0.00 13.26 96 0.00 13.74 95 0.00 13.80 93 0.00 -1.77 82 M 1,1,1,2-tetrachloroethane 83 M ethylbenzene Continuing Calibration Summary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 3 of 3 Sample: VS2588-CC2585 Lab FilelD: S70845.D 84 85 86 87 M M M M m, p-xylene o-xylene styrene bromoform 0.652 0.682 1.075 0.275 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 ill 112 113 114 115 1,4-dichlorobenzene-d4 isopropylbenzene 4-bromofluorobenzene (s)-cyclohexanone bromobenzene 1,1,2,2-tetrachloroethane trans-1,4-dichloro-2-bute 1,2,3-trichloropropane n-propylbenzene 2-chlorotoluene 4-chlorotoluene 1,3,5-trimethylbenzene tert-butylbenzene pentachloroethane 1,2,4-trimethylbenzene sec-butylbenzene 1,3-dichlorobenzene p-isopropyltoluene 1,4-dichlorobenzene vinyltoluene 1,2-dichlorobenzene n-butylbenzene 1,2-dibromo-3-chloropropa 1,2,4-trichlorobenzene hexachlorobutadiene naphthalene 1,2,3-trichlorobenzene hexachloroethane 1.000 2.300 0.759 0.000 0.765 0.713 0.168 0.197 2.837 2.077 1.928 2.114 1.122 0.497 2.249 2.526 1 .495 2. 188 1.574 0.000 1 .495 1. 835 0.130 0. 909 0.373 2.176 0.771 0 .413 0.654 0.684 1.089 0 .274 1.000 2 .334 0.751 0.037 0.757 0.695 0.172 0.189 2.846 2.051 1.884 2.132 1.145 0,512 2.244 2.536 1.455 2.225 1 .515 0.168 1.470 1.839 0.132 0.937 0.362 2.147 0 .788 0.433-0.3-0.3-1.3 0.4 0.0-1.5 I.1 0.0 1.0 2.5-2.4 4.1-0.3 1.3 2.3-0.9-2.0-3.0 0.2-0.4 2.7-1.7 3 .7 0.0 1.7-0.2-1.5-3 .1 2.9 1.3-2.2-4 .8 95 93 94 04 91 89 94 89 93 93 92 93 95 92 92 92 91 93 91 0#91 92 92 93 92 89 93 94 92 93 91 86 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00.0 .00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0 .00 0.00 0.00 0.00 0.00 0.00 13 89 14 .35 14 .36 14 .69 16.26 14 .71 14 .96 14. 95 15.19 15 .07 15.12 15 .16 15.17 15,35.15.46 15.32 15.72 15 .84 15.77 15 .95 16 .19 16 .08 16.28 16 .26 16.73 16 .54 17 .59 18.56 18 .67 18.92 19.22 17.00 (#) = Out of Range S70804.D MS2585.M SPCC's out = 0 CCC'.s out = 0 Mon Dec 27 10:56:08 2004 RPTI 59 Data File C:\HPCHEM\l\DATA\S70819.D Acq On : 23 Dec 2004 6:36 am Sample n86261-1 Misc : MS8583,VS2585,5 .... 1 MS Integration Params: LSCINT.P uant Time: Dec 23 16:57 2004 Vial: 100 Operator: mei inst : MSS Multipir: 1.00 Quant Results File: MS2585.RES Ouant Method Title Last Update Response via DataAcq Meth C:\HPCHEM\1\METHODS\MS2585.M (RTE Integrator) SW-846 Method 8260 Thu Dec 23 08:35:44 2004 Initial Calibration MS2585 Internal Standards R.T. QIon Response Conc Units Dev(Min).........................................................................
- 1) Tert Butyl Alcohol-d9 7.59 65 110965 500.00 ug/L 0.00 4) pentafluorobenzene 9.59 168 254342 50.00 ug/L 0.00 45) 1,4-difluorobenzene 10.48 114 376908 50.00 ug/L 0.00 75) chlorobenzene-d5 13.70 117 363663 50.00 ug/L 0.00 88) 1,4-dichlorobenzene-d4 16.25 152 227335 50.00 ug/L 0.00 System Monitoring Compounds 39) dibromofluoromethane (s) 9.69 Spiked Amount 50.000 Range 79 40) 1,2-dichloroethane-d4 (s) 10.i0 Spiked Amount 50.000 Range 68 67) toluene-d8 (s) 12.09 Spiked Amount 50.000 Range 83 90) 4-bromofluorobenzene (S) 14.96 Spiked Amount 50.000 Range 82 113-119 65-129 98-118 95-120 113715 49.39 Recovery 103606 47.71 Recovery =427205 49.05 Recovery =174136 50.45 Recovery =ug/L 0.00 98.78%ug/L 0.00 95.42%ug/L 0.00 98.10%ug/L 0.00 100.90%Target Compounds 76) tetrachloroethene Qvalue 88 12.78 164 852 0.37 ug/L (P) = qualifier out of range (m) = manual integration
$70819.D MS2585.M Thu Dec 23 16:58:27 2004 RPTI 6O Page 1 Data File : C:\HPCHEM\l\DATA\S70819.D Vial: 100 Acq On 23 Dec 2004 6:36 am Operator: mei Sample : n86261-1 Inst : MSS Misc : MS8583,VS2585,5 .... 1 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Time: Dec 23 16:57 2004 Quant Results File: MS2585.RES ' Method : C:\HPCHEM\l\METHODS\MS2585.M (RTE Integrator) Title : SW-846 Method 8260 Last Update Thu Dec 23 08:35:44 2004 Response via : Initial Calibration Abundance 3400000 3200000 300000D 2800000 2600000 2400000 2200000 2000000 1800000 1600000 1400000 1200000 1000000 800000 600000 400000 200000 TIC: $70819.D~0 In A 0"=, 9 b)0.?3 r-8 4#b'V IT'500 600 700 800 9.00 10.00 11.00 12.00 13.00 14,00 5. 0 .. .. I '1 '15.00 16.00 1 7.00 18.00L ^-J.00 20.00 L r -... ... ... ..S70819.D MS2585 °N Thu Dec 23 26:58:28 2004 RPTI Page 2 %W Abundance Scan 1624 (12.782 min): S69678.D (-)166 129 Ref50 76 47 59 76 3, )1 i J, I 7 i 1 117 n/vz-> 40 60 80 100 120 140 160 Abundance Scan 1625 (12.783 rmin): S70819.D 1 6 131 Raw50 44 94 0 60.. I 10 0 .... I I I 1 0 ,40 60 80 100 120 140 160 Delta R.T.Lab File: Acq: 23 Dec Tgt. Ion:164 ion Ratio 164 100 129 74.8 131 81.2 166 104.5#76 tetrachloroethene Concen: 0.37 ug/L RT: 12.78 min Scan# 1625 0.00 min S70819..D 2004 6:36 am Resp: 852 Lower Upper 55.6 51.4 98.2 115.6 111.4 158.2 0bundance Ion 164.00 (163170 to 164.70)-Ion 129.00 (128.70 to 129.70)800{Ion 131.00 (130,70 to 131.70)Ion 166.00 (165.70 to 166.70)D0 kbundance Sub50 Scan 1625 (12.783 min): S70819.D (-)I Z6 94 I131 40 21 Time-)A) 1 7 101 12!75' 12'80 '44...0 .. 60 .. 0 1 0' 1 201 1 40111 160 40 60 80 1 00 120 140 160 S70819-D MS2585.M Thu Dec 23 16:58:30 2004 RPTP Page 3 X--.. ---- ---.. .--, ---Data File C:\HPCHEM\I\DATA\S70820.D Acq Onr 23 Dec 2004 7:07 am Sample : n86261-2 Misc : MS8583,VS2585,5,,,,5. w- Integration Params: LSCINT.P ant Time: Dec 23 17:00 2004 Vial: 100 Operator: mei Inst : MSS Multiplr: 1.00 Quant Results File: MS2585.RES Quant Method Title Last Update Response via DataAcq Meth C:\HPCHEM\I\METHODS\MS2585.M (RTE Integrator) SW-846 Method 8260 Thu Dec 23 08:35:44 2004 Initial Calibration MS2585 Internal Standards R.T. QIon Response Conc Units Dev(Min)1) Tert Butyl Alcohol-d9 7.59 65 107650 500.00 ug/L 0.00 4) pentafluorobenzene 9.60 168 250030 50.00 ug/L 0.00 45) 1,4-difluorobenzene 10.48 114 371416 50.00 ug/L 0.00 75) chlorobenzene-d5 13.70 117 359174 50.00 ug/L 0.00 88) 1,4-dichlorobenzene-d4 16.26 152 225266 50.00 ug/L 0.00 System Monitoring Compounds 39) dibromofluoromethane (s) 9.69 113 Spiked Amount 50.000 Range 79 -119 40) 1,2-dichloroethane-d4 (s) 10.10 65 Spiked Amount 50.000 Range 68 -129 67) toluene-d8 (s) 12.09 98 Spiked Amount 50.000 Range 83 -118 90) 4-bromofluorobenzene (s) 14.96 95 Spiked Amount 50.000 Range 82 120 111853 49.42 Recovery 103847 48.65 Recovery 422127 49.18 Recovery 172681 50.48 Recovery =uq/L 98.84%ug/L 97.30%ug/L 98.36%ug/L 100.96%0.00 0.00 0.00 0.00 Target Compounds 76) tetrachloroetbene Qvalue 75 12.78 164 789 0.35 ug/L (4) = qualifier out of range (m) = manual integration $70820.D MS2585.M Thu Dec 23 17:00:14 2004 RPTI Pagei 4bundance Scan 1624 (12.782 min): S69678.D )129 I Re o 94 II"r e-> 40 7 76 0 W-> 40 60 80 10 20 140 160#76 tetrachloroethene Concen: 0.35 ug/L RT: 12.78 min Scan# 1624 Delta R.T.Lab File: Acq: 23 Dec-0.00 min S70820.D 2004 7:07 am*bundance Raws 0 Scan 1624 (12.779 min): S70820.D 44 94 129 I]Tgt I on 164 129 131 166 Ion:164 Resp: Ratio Lower 100 61.4 55.6 60.8 51.4 98.6 98.2 789 Upper 115.6 111.4 158.2 f.bundance Ion 164.00 (163.70 to 164.70), 0)0 j~on 12900 (128,70 to 129.70)Ion 131.00 (130.70 to 131.70)Ion 166.00 (165.70 to 166.70)C), i I , I ..40 60 80 100 120 140 160 i i t 800 AbundancE Sub s0 Scan 1624 (12.779 min): S70820.D (-)11 94 129 600 400 200 0[12.7 1217S 12.80)4 60..0.100.1....20 1 06..... .....40 60 80 100 120 140 160 S70820.D MS2SBS.M Thu Dec 23 17:00:17 2004 RPTI Page 3 Data File : C:\HPCHEM\I\DATA\S70853.D Acq On : 24 Dec 2004 2:20 am Sample n86261-3 Misc : MS8583,VS2588,5 .... 1 MS Integration Params: LSCINT.P)ant Time: Dec 27 10:59 2004 Vial: 100 Operator: mei Inst : MSS Multipir: 1.00 Quant Results File: MS2585.RES etuant Method Title Last Update Response via DataAcq Meth C:\HPCHEM\I\METHODS\MS2585.M (RTE Integrator) SW-846 Method 8260 Thu Dec 23 08:35:44 2004 Initial Calibration MS2585 Internal Standards R.T. QIon Response Conc Units Dev(Min)1) Tert Butyl Alcohol-d9 7.59 65 120415 500.00 ug/L 0.00 4) pentafluorobenzene 9.60 168 244167 50.00 ug/L 0.00 45) 1,4-difluorobenzene 10.48 114 355427 50.00 ug/L 0.00 75) chlorobenzene-d5 13.70 117 337546 50.00 ug/L 0.00 88) 1,4-dichlorobenzene-d4 16.26 152 215032 50.00 ug/L 0.00 System Monitoring Compounds 39) dibromofluoromethane (s) 9,70 Spiked Amount 50.000 Range 79 40) 1,2-dichloroethane-d4 (s) 10.09 Spiked Amount 50.000 Range 68 67) toluene-d8 (s) 12.09 Spiked Amount 50.000 Range 83 90) 4-bromofluorobenzene (s) 14.96 Spiked Amount 50.000 Range. 82 113-119 65-129 98-118 95-120 107488 48.63 Recovery 103150 49.48 Recovery =409506 49.86 Recovery =163813 50.17 Recovery ug/L 0.00 97 .26%ug/L 0..00 98. 96%ug/L 0.00 99.72%ug/L 0.00 100.34%Target Compounds 76) tetrachloroethene Qvalue 91 12.79 164 1871 0.87 ug/L (i') = qualifier out of range (m) = manual integration $70853.D MS2585.M Mon Dec 27 15:04:27 2004 RPTI Page 1 Data File C:\HPCHEM\l\DATA\S70853.D Acq On 24 Dec 2004 2:20 am Sample : n86261-3 Misc. MS8583,VS2588,5 .... I MS Integration Params: LSCINT.P Quant Time: Dec 27 10:59 2004 Vial: Operator: Inst Multiplr: 100 mei MSS 1.00 Quant Results File: MS2585.RES Method Title Last Update Response via C:\HPCHEM\l\METHODS\MS2585.M (RTE Integrator) SW-846 Method 8260 Thu Dec 23 08:35:44 2004 Initial Calibration !Abundance TIC: S70853.D 700000 650000 600000 550000 I-C,,)500000 450000 400000 350000 300000 250000 200000 150000 100000 50000 C N'N N,, IL Z, 0N cC, b 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 20.00 Iý0!ýO'S?0853.D MS2585.M Mon Dec 27 15:04:28 2004 RPT1a Page 2 t---------- MAundance Scan 1624 (12.782 rnn): S69678.D (-)Ref50 94 47 76 129 117I 166#76 tetrachloroethene Concen: 0.87 ug/L RT: 12.79 min ScanB 1625 Delta RT. 0.01 min Lab File: 970853.D Acq: 24 Dec 2004. 2:20 am'4 .....0 80.. 10 40 60 80 100 120 140 160 Abundance Raw50 44 Scan 1625 (12.788 min): S70853,D 6 Tgt Ion 164 129 131 166 Ion: 164 Ratio 100 71.2 81.0 117.9 Resp: 1871 Lower Upper 94 131 55.6 51.4 98.2 Abundancelon 164.00 (163.70 to 164,70).Ion 129,00 (128.70 to 129.70)Ion 131.00 (130.70 to 131.70)Ion 166,00 (165.70 to 166.70)115.6 111.4 158.2lI , E ,.. Jl I0 60. .... I" 8 0 11 1 1 0 I I 1 I 0 40 60 80 100 120 140 16I 160!,bundance Sub 60 Scan 1625 (12.788 min): S70853.D (-)1l 94 131 1000 1 .79 600 0 Time--> 12.75 12.80 12.85 U.. ......... .......,( , ". 1 40 6i ..I 10 0 I I .... 1 20. 1 1 60 80 100 120 140 160 S70853.D MS2585.M Mon Dec 27 15:04:30 2004 RPTI Page 3 Data File C:\HPCHEM\I\DATA\S70854.D Acq On : 24 Dec 2004 2:50 am Sample : n86261-4 Misc MS8583,VS2588,5 .... I M Integration Params: LSCINT.P*u ant Time: Dec 27 11:00 2004 Uant Method : C:\HPCHEM\I\METHODS\MS2 Title : SW-846 Method 8260 Last Update Thu Dec 23 08:35:44 20(Response via : Initial Calibration DataAcq Meth MS2585 Vial: 100 Operator: mei Inst : MSS Multiplr: 1.00 Quant Results File: MS2585.RES 2585.M (RTE Integrator) Internal Standards R.T. QIon Response Conc Units Dev(Min)1) Tert Butyl Alcohol-d9 7.59 65 128228 500.00 ug/L 0.00 4) pentafluorobenzene 9.60 168 235560 50.00 ug/L 0.00 45) 1,4-difluorobenzene 10.48 114 347723 50.00 ug/L 0.00 75) chlorobenzene-d5 13.70 117 329152 50.00 ug/L 0.00 88) 1,4-dichlorobenzene-d4 16.25 152 208765 50.00 ug/L 0.00 System Monitoring Compounds 39) dibromofluoromethane (s) 9.69 113 Spiked Amount 50.000 Range 79 -119 40) l,2-dichloroethane-d4 (s) 10.09 65 Spiked Amount 50.000 Range 68 -129 67) toluene-d8 (s) 12.10 98 Spiked Amount 50.000 Range 83 -118 90) 4-bromofluorobenzene (s) 14.96 95 Spiked Amount 50.000 Range 82 -120 104434 48.97 Recovery =101980 50.71 Recovery =402289 50.06 Recovery =161314 50.89 Recovery =ug/L 0.60 97.94%ug/L 0.00 101.42%ug/L 0.00 100.12%ug/L 0.00 101.78%Target Compounds.Qvalue(') = qualifier out of range (m) = manual integration S70854.D MS2585.M Mon Dec 27 15:04:42 2004 RPTI Page 2 Data File C:\HPCHEM\I\DATA\S70854.D Acq On : 24 Dec 2004 2:50 am Sample : n86261-4 Misc : MS8583,VS2588,5 .... 1 MS Integration Params: LSCINT.P Quant Time: Dec 27 11:00 2004 Vial: Operator: Inst Multiplr: 100 mei MISS 1.00 Quant Results File: MS2585.RES Method Title Last Update Response via C:\HPCHEM\!\METHODS\MS2585.M (RTE Integrator) SW-846 Method 8260Thu Dec 23 08:35:44 2004 Initial Calibration Fbundance 650000 TIC: S70854.D 6000001 550000 C, 500000-8 450000 C,'8 400000`8 350000 300000 250000 200000 150000 100000 50000'8 C, C,'V 0 b'0 P'V C,'V d 1ýlime-->A -5.00 6.00 7.00 8.00 9.00 10.00 11.00 12,00 13.00 14.00 15,00 16.00 17.00 18.00 if 20.00 S70854 .D MS2585. M Mon Dec 27 15:04:44 2004 RPTI Page 2 Data File : C:\HPCHEM\I\DATA\S70855.D Acq On : 24 Dec 2004 3:20 am Sample n86261-5 Misc MS8583,VS2588,5 .... 1 MQ Integration Params: LSCINT.P.ant Time: Dec 27 iilQ0 2004 uant Method C:\HPCHEM\I\METHODS\MS; Title : SW-846 Method 8260 Last Update : Thu Dec 23 08:35:44 20(Response via : Initial Calibration DataAcq Meth : MS2585 Vial: 100 Operator: mei Inst : MSS Multiplr: 1.00 Quant Results File: MS2585.RES 2585.M (RTE Integrator) 04 Internal Standards R.T. QIon Response Conc Units Dev(Min)1) Tert Butyl Alcohol-d9 7.59 65 123466 500.00 ug/L 0.00 4) pentafluorobenzene 9.60 168 230812 50.00 ug/L 0.00 45) 1,4-difluorobenzene 10.47 114 338799 50.00 ug/L 0.00 75) chlorobenzene-d5 13.70 117 324546 50.00 ug/L 0.00.88) 1,4-dichlorobenzene-d4 16.25 152 202292 50.00 ug/L 0.00 System Monitoring Compounds 39) dibromofluoromethane (s) 9.69 Spiked Amount 50.000 Range 79 40) 1,2-dichloroethane-d4 (s) 10.09 Spiked Amount 50.000 Range 68 67) toluene-d8 (s) 12.09 Spiked Amount 50.000 Range 83 90) 4-bromofluorobenzene (s) 14.96 Spiked Amount 50.000 Range 82 113 119 65 129 98-118 95-120 103641 49.60 Recovery =101432 51.47 Recovery =395368 50.50 Recovery 257541 51.29 Recovery ug/L 0.00 99.20%ug/L 0..00 102.94%ug/L 0.00 101.00%Ug/L 0.00 102.58%Target Compounds Qvalue(4) = qualifier out of range (m) = manual integration $70855.D MS2585.M Mon Dec 27 15:04:57 2004 RPTI Page i Data File C:\HPCHEM\l\DATA\S70855.D Acq On 24 Dec 2004 3:20 am-Sample n86261-5 Misc MS8583,VS2588,5,,,,I MS Integration Params: LSCINT.P Quant Time: Dec 27 11:00 2004 Vial: Operator: Inst Multiplr: 100 mei MSS 1.00 Quant Results File: MS2585.RES 'v Method Title Last Update Response via C:\HPCHEM\!\METHODS\MS2585.M (RTE Integrator) SW-846 Method 8260 Thu Dec 23 08:35:44 2004 Initial Calibration Fbundance 650000 TIC: S70855.D 600000 550000..I 500000 ci, 8"8 b 450000 b 400000 14W-8 V 350000 300000 250000 200000 150000: 100000 50000 P 0 N N N OLme>K 11 t I j*2~w k'~IT'5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 ' 20 S70PSS.D MS2585.M Mon Dec 27 15:04:59 2004 RPTPPage 2 Data File : C:\HPCHEM\I\DATA\S70856.D Acq On 24 Dec 2004 3:50 am Sample n86261-6 Misc MS8583,VS2588,5 .... I MS Integration Params: LSCINT.P luant Time: Dec 27 15:54 2004 Vial: 100 Operator: mei inst : MSS Multiplr: 1.00 Quant Results File: MS2585,RES 0uant Method Title Last Update Response via DataAcq Meth C:\HPCHEM\I\METHODS\MS2585.M (RTE Integrator) SW-846 Method 8260 Thu Dec 23 08:35:44 2004 Initial Calibration MS2585 Internal Standards R.T. QIon Response Conc Units Dev(Min)1)4)45)75)88)Tert Butyl Alcohol-d9 pentafluorobenzene 1,4-difluorobenzene chlorobenzene-d5 1,4-dichlorobenzene-d4 7.59 65 9.60 168 10.48 114.13.70 117 16.26 152 116999 223659 330045 316585 199045 500.00 50.00 50.00 50.00 50.00 ug/L ug/L ug9/L ug/L ug/L 0.00 0.00 0.00 0,00 0.00 System Monitoring Compounds 39) dibromofluoromethane (s) 9.69 Spiked Amount, 50,000 Range 79 40) 1,2-dichloroethane-d4 (s) 10.09 Spiked Amount 50.000 Range 68 67) toluene-d8 (s) 12.09 Spiked Amount 50.000 Range 83 90) 4-bromofluorobenzene (s) 14.96 Spiked Amount 50.000 Range 82 113-119 65-129 98-118 95-120 101228 50.00 Recovery 100430 52.59 Recovery 385304 50.52 Recovery =153186 50.68 Recovery ug/L 0.00 100.00$ug/L 0.00 105.18%ug/L 0.00 101.04%ug/L 0.00 101.36%Target Compounds Qvalue#0;; ~,.4 ( c) = rualifier out of range (m) = manual integration S70856.D MS2585.M Mon Dec 27 15:54:09 2004 RPTI Page .2 Data File C:\HPCHEM\1\DATA\S70856.D Acq On : 24 Dec 2004 3:50 am Sample : n86261-6 Misc : MS8583,VS2588,5,,.l MS Integration Params: LSCINT.P Quant Time: Dec 27 15:54 2004 Vial: Operator: inst Multiplr: 100 me i MSS 1 .00 Quant Results File: MS2585.RES Method-Title Last Update Response via C:\HPCHEM\I\METHODS\MS2585.M (RTE Integrator) SW-846 Method 8260 Thu Dec 23 08:35:44 2004 Initial Calibration Obundance 6500001 TIC: S70856.D 600000 550000 500000@$450000 (/2 LA 400000'V V.350000 300000 250000 200000 150000 100000 50000.5 b ((2 ((2 V 0"9'F Timp >0 5.00 6,00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14:00 15.00 16:00 17:00 18.00 1 "0" ";20.00 i ......S70856.D MS2585.M Mon Dec 27 15:54:21 2004 RPT1 Page 2$70856.D MS2585,Mi Mort Dec 27 15:54:11 2004 RPTI Page 2 Data File : C:\HPCHEM\I\DATA\S70809.D Acq On :.23 Dec 2004 1:36 am Sample : rnbl Misc MS8583,VS2585,5 .... I MS Integration Params: LSCINT.P Quant Time: Dec 23 16:51 2004# ant Method C:\HPCHEM\I\METHODS\MS Title : SW-846 Method 8260 Last Update Thu Dec 23 08:35:44 20(Response via Initial Calibration DataAcq Meth MS2585 Vial: 100 Operator: mei Inst : MSS Multiplr: 1.00 Quant Results File: MS2585.RES 2585.M (RTE Integrator) 04 Internal Standards .R.T. QIon Response Conc Units Dev(Min).........................................................................
- 1) Tert Butyl Alcohol-d9 7.59 65 146231 500.00 ug/L 0.00 4) pentafluorobenzene 9.60 168 289404 50.00 ug/L 0.00 45) 1,4-difluorobenzene 10.48 114 417767 50.00 ug/L 0.00 75) chlorobenzene-d5 13.70 117 400467 50.00 ug/L 0.00 88) 1,4-dichlorobenzene-d4 16.25 152 255030 50.00 ug/L 0.00 System Monitoring Compounds 39) dibromofluoromethane (s) 9.69 113 Spiked Amount 50.000 Range 79 -119 40) l,2-dichloroethane-d4 (s) 10.10 65.Spiked Amount 50.000 Range 68 -129 67) toluene-d8 (s) 12.09 98 Spiked Amount 50.000 Range 83 -118 90) 4-bromofluorobenzene (s) 14.96 95 Spiked Amount 50.000 Range 82 -120 124133 47.38 Recovery =110259 44.62 Recovery =466180 48.29 Recovery =190267 49.13 Recovery -ug/L 0.00 94 .76%ug/L 0.00 89.24%ug/L 0.00 96.58%Ug/L 0.00 98. 26%Target Compounds Qvalue is (4) = qualifier out of range (m) = manual integration
$70809.D MS2585.M Thu Dec 23 16:59:17 2004 RPTI Page 1 Data File C:\HPCHEM\l\DATA\S70809.D Acq On 23 Dec 2004 1:36 am Sample : mbl Misc : MS8583,VS2585,5 .... 1 MS Integration Params: LSCINT.P Quant Time: Dec 23 16:51 2004 Vial: Operator: Inst Multiplr: 100 mei MSS 1.00 Quant Results File: MS2585.RES to Method Title Last Update Response via C:\HPCHEM\I\METHODS\MS2585.M (RTE Integrator) SW-846 Method 8260Thu Dec 23 08:35:44 2004 Initial Calibration Abundance TIC: S70809.D 8000001 7500001 700000 650000 Tp 600000 ,n.-8 550000 500000 C N b bF 450000 400000"S 350000 300000 b 250000 200000'C 150000 100000 50000 Z-to Tirre-->11 n .I-.. "_I___I__.,___-___1_T 5.00 6.00 7.00 8.00 0.f*lf ii1 2.0 I .00 I 1. 0 16. 17.0 18.00' 0, 20.00"12.00 13.00 14,00 15.00 16.00 .17.00 18.00100 00 2ý- 01010 i 900 1000 1100 S70809.D MS2585.M Tbi Dec 23 16:59:19 2004 R PT1 Page 2 Thu Dec 23 16:59:19 20D4 S70809.D MS2585.M RPTI Page 2 Data File : C:\HPCHEM\1\DATA\S70809.D Acq On 23 Dec 2004 1:36 am Sample : nib Misc : MS8583,VS2585,5 .... 1 MS Integration Params: LSCINT.P vial: 100 Operator: mei Inst : MSS Multiplr: 1.00 16 thod Pitle Smoothing Sampling Start Thrs: Stop Thrs : C:\HPCHEM\I\METHODS\MS2585.M (RTE Integrator) SW-846 Method 8260 ON Filtering: 5 1 0.06 0.04 Min Area: 100 Max Peaks: 100 Peak Location: TOP Area counts If leading or trailing edge < 100 prefer < Baseline drop else tangent >Peak separation: 5 Signal : TIC peak 1 2 3 4 5 6 7 8 9 io R.T.min 4.669 4.732 4. 962 4.988 5.009 5. 072 5. 124 5.417 5.438 5.459 1 5. 532 5 631 5 694 4 5.987 15 6.102 16 6.311 17 6.619 18 7.032 19 7.241 20 7.430 21 7.471 22 7.592 23 7.858 24 7.911 25 7.932 26 7. 973 27 8.015 28 8.041 29 8.177 30 8.219 31 8.235 32 8.313 33 8.580 34 8.690 35 8.747 S9.108 9.427 38 9.594 first scan 71 84 125 131 136 149 157 S2.12 218 222 232 252 264 324 343 384 439 523 562 599 608 619 680 691 696 701 708 717 739 748 754 766 820 840 850 920 981 1005 max scan 73 85 129 134 138 150 160 216 220 224 238 257 269 325 347 387 446 525 565 601 609 632 683.693 697 705 713 718 744 752 755 770 821 842 853 922 983 1015 last scan 79 91 131 136 144 156 163 218 222 227 245 259 271 332 348 394 449 532 574 608 619 675 691 696 701 708 717 725 748 754 763 781 827 850 861 930 988 1026 PK TY rBV2 rVB2 rBV3 rBV2 rBV2 rBV2 rVB2 rVB2 rBV2 rVV2 rBV3 rBV rBV2 rVB3 rBV rVV2 rBV2 rVB2 rBV3 rVB3 rVB3 rBV rVV3 rVV2 rVB3 rBV3 rVB3 rBV2 rVB2 rBV2 rVV3 rBV2 rBV2 rVB3 rBV2 rBV2 rBV rBV peak height 683 730 476 515 700 413 731 741 793 497 532 1004 479 459 550 574 352 413 666 667 627 47746 690 625 661 770 653 484 511 1106 1034 353 450 565 312 513 829 279861 corr.area 711 571 530 538 583 722 719 1064 737 547 1143 1065 723 661 605 855 696 776 1269 805 1299 230351 1642 628 575 1024 716 627 693 970 998 1002 637 669 530 807 761 675015 corr.% max.0. 05%0.04%0.04%0.04%0.04%0.05%0.05%0.08%0. 06%0.04%0.09%0.08%0.05%0.05%0. 05%0. 06%0.05%0. 06%0.09%0.06%0.10%17.22%0.12%0.05%0.04%0.08%0. 05%0.05%0.05%0.07%0.07%0 .07%0. 05%0.05%0. 04%0.06%0.06%50.46%% of total 0.010%0.008%0.008%0.008%0.008%0.010%0.010% 0.015%0.011%0.008%0.016%0.015%0. 010%0.009%0. 009%0. 012%0. 010%0.011%0.018%0.011%0.019%3.290%0.023%0. 009%0. 008%0.015%0. 010P%0.009%0.010%0.014%0. 014%0.014%0. 009%0. 010%0. 008%0.012% 0.011%9.642% 'v .'I.J'J. ýUVVP .VVO .)vlt .&JJ IvuW.. V -0 I'" .2
- ,VI *o 41 42 43 44 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 e66 67 68'v 71 72 73 74 75 76 77 78 79 80 81 82 83 8.4 85 86 87 88 89 90 91 9 95 10.096 l0.478 10.666 11,011 12.093 12.339 12,783 13.348 13.567 13.703 13.891 14.357 14.718 14. 963 15 .178 15.340 15.355 15,481 15.523 15.638 15.716 15.779 15. 957 16.082 16.255 16.417 16. 553 16.694 16.736 16.803 16.887 16.908 17.275 17.326 17.515 17.546 17.640 17.734 17.760 17.786 17.839 17,880 17.954 18.053 18.095 18.168 18.267 18.304 18.335 18.492 18.523 18.565 18.623 18.659 18.853 1098 1173 1218 1284 1474 1539 1620 1730 1768 1787 1833 1917 1989 2029 2075 2107 2116 2134 2248 2167 2181 2192 2226 2249 2272 2318 2337 2367 2376 2392 2402 2413 2462 2492 2529 2535 2553 2568 2574 2580 2590 2597 2611 2630 2640 2651 2670 2676 2685 2714 2722 2725 2738 2746 2783 1111 1184 1220 1286 1493 1540 1625 1733 1775 1801 1837 1926 1995 2042 2083 2114 2117 2141 2149 2171 2186 2198 2232 2256 2289 2320 2346 2373 2381 2394 2410 2414 2465 2494 2530 2536 2554 2572 2577 2582 2592 2600 2614 2633 2641 2655 2674 2681 2687 2717 2723 2731 2742 2749 2786 1137 1218 1233 1295 1532 1550 1631 1743 1782 1833 1849 1933 2002 2075 2092 2116 2130 2148 2157 2176 2192 2205 2243 2262 2317 2327 2352 2376 2392 2399 2413 2422 2477 2499 2535 2541 2558 2574 2579 2590 2597 2611 2624 2640 2644 2660 2676 2682 2695 2722 2725 2738 2746 2756 2794 rVB rBV rVB2 rVB rBV rVB3 rBV3 rVB rBV2 rVV rVV3 rBV3 rVV rBV rVB3 rBV2 rVB2 rBV3 rVB rBV2 rVV rVB3 rVV rBV rBV rVB rBV2 rVV3 rVV3 rVB2 rBV2 rBV2 rBV2 rVV3 rBV2 rVV2 rBV rBV3 rVV3 rVB3 rBV2 rVB3 rBV3 rVB3 rBV2 rBV3 rVB3 rRV3 rVB3 rVB3 rBV2 rVV4 rVB4 rBV5 rBVs 129261 359088 800 462 523708 798 959 439 866 490743 2567 1092 1069 434332 1762 1566 1383 1355 498 492 1198 1668 1349 1352 680018 826 1351 652 2068 468 628 432 552 522 716 433 718 647 524 759 497 795 795 553 768 865 739 681 1090 822 869 1918 1082 2130 1142 311907 832827 1482 773 1152180 1106 1209 766 1353 1043734 5932 2385 2166 881093 4324 2821 2065 2769 566 671 2222 3123 2620 2276 1337601 1128 2955 1125 3435 543 2060 536 1284 632 738 577 673 829 540 1147 752 1777 2210 839 581 1325 757 904 1337 1258 544 4432 1121 3437 2079 23.32%62.26%0.11%0.06%86.14%0.08%0.09%0.06%0.10%78.03%0.44%0.18%0.16%65.87%0.32%0.21%0.15%0.21%0.04%0.05%0.17%0.23%0,20%0.17%100.00%0.08%0.22%0.08%0.26%0.04%0.08%0. 04%0.10%0.05%0.06%0.04%0.05%
0.06%0.04%0 .09%0. 06%0.13%0.17%0.06%0.04%0.10%0.06%0.07%0.10%0. 09%0.04%0.33%0.08%0.26%0.16%,4.455%11. 896%0.021%0. 011%16.458%0.016%0.017%0.011%0.019%14.909%0. 085%0. 034%0.031%12.586%0.062%0.040% 0.029%0.040%0.008%0.010%0.032%0.045%0. 037%0.033%19. 207%0.016%0.042%0.016%0.049%0.008%0.015%0.008%0.018%0.009%0.011%0.008%0.010%0.012%0.008%0.016%0.011%0. 025%0. 032%0.012%0.008%0.019%0.011%0.013%0.019%0.018%0.008%0.063%0.016%0.049%0.030% 97 98 99 100 19.219 19.365 19.459 19.946 2853 2856 2865 rVB5 2910 5819 2876 2884 2888 rBV5 935 2430 2901 2902 2905 rBV2 818 774 2960 2995 3003 rBV9 1275 10237 Sum of corrected areas: 0. 44%0.18%0.06%0.77%7000668 0 083%0.035%0.146%S70809.D MS2585.M Thu Dec 23 16:59:33 2004 RPT1 79-a.J.W... ~ t, -File : C:\HPCHEM\1\DATA\S70809.D Operator mei Acquired : 23 Dec 2004 1:36 am using AcqMethod MS2585 Instrument MSS Sample Name: mbl C Misc Info : .MS8583,VS2585,5 .... 1 Vial Number: 100 Quant File :MS2585.RES (RTE Integrator) bundance 600000 500000 400000 300000 200000 100000 0 Time-->TIC: S70809.D 9,57 7.03 7.24 7744j\, 7-MSMMZI 8.SM95 9,11 9.43 4.4.73 ., 7172 f4M.39 5.99.10 6.31 6.62 ,, .w , , ," , ....... ..4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50 Abundance 600000 500000 400000 300000 200000 100000 0 Time-->10.48 69 10.10 9.87 10.67 11.01 TIC: S70809.D 12.09 12.34 12.78 13.70!13.89 14.96 14.36 14.72 13.3513.5' 10.00 10.50 11.00 11.50 12.00 12,50 13.00 13.50 14.00 1i45 14.50 Abundance 600000 500000 400000 300000 200000 100000 Fime.->25 TIC: S70809.D 5V536ta2596.01 93S 41869& 1 17 317Z7i4'8t 4w 19.95.I 15.50 15.00 16.50 17.00 17.50 18.00 18.50 19.00 19.50 20.0D so S70809.D MS2585.M Thu Dec 23 16:59:35 2004 RPT1 Operator ID: mei Date Acquired: 23 Dec 2004 1:36 am Data File: C:\HPCHEM\I\DATA\S7O809.D Name: nbl Misc: MS8583,VS2585,5.... I Method: C:\HPCHEM\I\METHODS\MS258S.M (RTE Integrator) ýle: SW-846 Method 8260 brary Searched: C:\DATABASE\NBS75K.L TIC Top Hit name RT EstConc Units Area IntStd ISRT ISArea ISConc................... Thu.....Dec.....23....16:5......:35.....2004............. $70809.D MS2585.M Thu Dec 23 16:59:35 2004 RPTI%P Data Pile C:\HPCHEM\1\DATA\S70847.D Acq On 23 Dec 2004 11:19 pm Sample mbl Misc : MS8694,VS2588,5 .... 1 MS Integration Params: LSCINT.P'Ouant Time: Dec 27 10:56 2004 Vial: 100 Operator: mei Inst : MSS Multiplr: 1.00 Quant Results File: MS2585.RES %ant Method Title Last Update Response via DataAcq Meth C:\HPCHEM\I\METHODS\MS2585.M (RTE Integrator) SW-846 Method 8260 Thu Dec 23 08:35:44 2004 Initial Calibration MS2585 Internal Standards R.T. QIon Response Conc Units Dev(Min).........................................................................
- 1) Tert Butyl Alcohol-d9 7.59 65 131125 500.00 ug/L 0.00 4) pentafluorobenzene 9.60 168 247644 50.00 ug/L 0.00 45) 1,4-difluorobenzene 10.48 114 358779 50.00 ug/L 0.00 75) chlorobenzene-d5 13.70. 117 342020 50.00 ug/L 0.00 88) 1,4-dichlorobenzene-d4 16.25 152 218134 50.00 ug/L 0.00 System Monitoring Compounds 39) dibromofluoromethane (s) 9.69 113 Spiked Amount 50.000 Range 79 -119 40) 1,2-dichloroethane-d4 (s) 10.09 65 Spiked Amount 50.000 Range 68 -129 67) toluene-d8 (s) 12.09 98 Spiked Amount 50.000 Range 83 -118 90) 4-bromofluorobenzene (s) 14.96 95 Spiked Amount 50.000 Range 82 -120 108583 48.43 Recovery =103695 49.04 Recovery 417666 50.38 Recovery =166171 50.17 Recovery =ug/L 0.00 96.86%ug/L 0.00 98.08%ug/L 0.00 100.76%ug/L 0.00 1.00.34%Target Compounds tar Qvalue (V) = qualifier out of range (m) = manual integration
$70847.D MS2585.M Tue Dec 28 12:53:22 2004 RPT1 (V.Page 1 Data File : C:\HPCHEM\I\DATA\S70847.D Acq On 23 Dec 2004 11:19 pm Sample : mbl Misc MS8694,VS2588,5 .... I MS Integration Params: LSCINT.P Quant Time: Dec 27 10:56 2004 Vial: Operator: Inst Multiplr: 100 mei MSS 1.00 Quant Results File: MS2585.RES Method Title Last Update Response via C:\HPCHEM\l\METEODS\MS2585.M (RTE Integrator) SW-846 Method 8260 Thu Dec 23 08:35:44 20-04 Initial Calibration r=.rDundanceI TIC: S 70 A7.'700000 650000 600000 550000.ýf T C9 1, m 500000 C-8 b C,,.b 450000%I 400000 N-8 350000 300000 250000 200000 150000 100000 50000 N b C,, V b I-20.00 itore 01 --11,"","II , -',ý .~ .rjiý .5.00 6.00 7.00 8,00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 S70847.D MS2585.M Tue Dec 28 12:53:23 2004 RPT1 Page 2$70847.D MS2585.M Tue Dec 28 12:53:23 2004 RPT1 Page 2 Data File C:\HPCHEM\l\DATA\S70847.D Acq On : 23 Dec 2004 11:19 pm Sample :mbl Misc : MS8694,VS2588,5,,,,I MS Integration Params: LSCINT.P Vial: 100 Operator: mei Inst : MSS Multiplr: 1.00.% hod C:\HPCHEM\l\METHODS\MS2585.M (RTE Integrator)" tle : SW-846 Method 8260 Smoothing
- ON Filtering:
5 Sampling : 1 Min Area: 100 Start Thrs: 0.06 Max Peaks: 100 Stop Thrs : 0.04 Peak Location: TOP Area counts If leading or trailing edge < 100 prefer < Baseline drop else tangent >Peak separation: 5 Signal : TIC peak 1 2 3 4 5 6 7 8 9 10 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 1I 32 1i 33 1(34 1: 35 i:% 1: 381 R.T.min 4. 670 4 .832 4.916 5. 005 5. 554 5.590 5.726 5. 753 5. 847 6. 077 6.140 6.202 6.270 6.349 6.412 6.684 6.752 6. 872 7.102 7.337 7,363 7.442 7.594 7,913 8. 069 8.216 8.990 9. 199 9 .597 9.696 0. 094 0.475 0.747 1.113 1.380 1,432 R. 091 R.275 first scan 66 100 110 135 241 247 270 279 297 340 353 364 377 392 403 457 468 489 534 578 587 601 617 691 715 748 895 932 1004 1025 1100 1171 1233 1299 1353 1361 1479 1526 max scan 73 104 120 i37 242 249 275 280 298 342 354 366 379 394 406 458 471 494 538 583 588 603 632 693 723 751 899 939 1015 1034 1110 1183 1235 1305 1356 1366 1492 1527 last scan 75 110 125 144 247 256 279 285 306 348 359 373 385 403 411 464 479 498 544 587 601 610 678 699 726 761 902 942 1025 1064 1144 1208 1240 1307 1361 1368 1526 1530 PK TY rBV2 rVV2 rVB3 rBV3 rVB3 rBV3 rBV3 rBV2 rBV rVB2 rBV rVB2 rBV2 rVB2 rBV2 rBV2 rVV2 rVV2 rBV2 rVB2 rVB2 rBV2 rBV rVB3 rBV2 rBV rBV2 rVB2 rBV rVB rVB rEV rVB2 rBV rVB rBB rVV rVV2 peak height 508 657 498 679 690 620 768 611 630 502 427 509 476 817 565 551 604 487 535 564 414 365 43134 736 305 533 521 290 247922 138399 123257 320887 368 476 435 476 466142 1551 corr.area 1022 888 1024 963 710 1013 1030 636 836 551 587 620 555 915 562 844 962 597 784 665 898 599 208177 743 720 888 715 569 585454 353041 288684 742624 568 729 622 546 1034682 1414 corr.% max.0.09%0.08%0.09%0.08%0.06%0.09%0.09%0.05%0.07%0.05%0.05%0.05%0.05%0.08%0.05%0.07%0.08%0.05%0.07%0. 06%0.08%0.05%17. 68%0.06%0.06%0.08%0.06%0.05%49.71%29.98%24 .51%63.06%0. 05%0.06%0.05%0.05%87.86%0.122%% of total 0 .017%0.014%0.017%0.016%0.011%0.016%0.017%0.010%0.014%0.009%0.010%0.010%0.009%0.015%0. 009%0.014%0,016%0.010%0.013%0,011%0.015%0.010%3.369%0.012%0.012%0.014%0.012%0.009%9.476%5.714%4.672%12.020%0.009%0,012%0.010%0.009%16.747%0.023%.84, 40 12.343 1537 1540 1544 rVV 879 1307 '0.11% 0.021%41 42 43 44 47 48 49 50 51 52 53 54 55 56 57 58 59 60 13.572 13 .702 13.917 14.361 14.722 14.963.15.193 15 .345 15.366 15.470 15.721 15.773 15.909 15.957 16.009 16.072 16.255 16.396 16.553 16.574 16.616 16.689 16.736 16.778 17.201 61 62 63 64 66 17.280 67 17.343 17.42617.479 17.510 1767 1789 1834 1921 1991.2031 2076 2106 2115 2136 2179 2192 2219 2226 2238 2245 2273 2312 2341 2347 2354 2365 2378 2387 2468 2476 2494 2508 2518 2525 2533 2563 2573 2578 2589 2596 2602 2611 2618 2635 2645 2653 2700 2723 2752 2777 2786 2796 2807 2817 2830 2836 2843 2852 2870 1775 1800 1841 1926 1995 2041 2085 2114 2118 2138 2186 2196 2222 2231 2241 2253 2288 2315 2345 2349 2357 2371 2380 2388 2469 2484 2496 2512 2522 2528 2537 2564 2575 2581 2592 2597 2608 2613 2620 2643 2647 2655 2702 2731 2754 2783 2789 2798 2810 2828 2833 2837 2847 2856 2873 1779 1834 1844 1932 2002 2073 2088 2115 2122 2146 2192 2205 2226 2238 2245 2259 2312 2319 2347 2354 2362 2378 2387 2400 2473 2487 2502 2518 2524 2533 2539 2573 2578 2588 2596 2602 2611 2618 2623 2645 2650 2657 2711 2737 2763 2786 2796 2807 2813 2830 2836 2843 2849 2870 2874 rBV2 rBV rVV2 rVB2 rVB rVV rVB2 rVV2 rVV2 rBV rVV3 rVV3 rVB rBV2 rVB2 rBV3 rBV rVB3 rBV2 rVV2 rVV2 rBV2 rVV2 rVB rVB32 rBV2 rVB2 rVB2 rBV2 rVB2 rBV3 rBV3 rBV rVB2 rBV2 rBV3 rVV rVB2 rBV2 rVB3 rVB2 rBV2 rBV3 rBV3 rVB5 rVB3 rBV4 rVB3 rBV2 rVB5 rBV4 rBV3 rBV2 rBV7 rBV2 836 432787 863 588 529 378426 688 602 622 515 941 726 604 960 506 793 606392 787 946 722 412 705 1014 471 535 773 678 730 751 515 408 671 673 702 677 698 608 886 621 627 541 728 1211 1291 862 818 698 1615 864 1104 711 928 817 1166 1015 1176 913817 2123 898 944 775757 1571 1190 728 847 1878 1623 637 1986 656 2134 1177692 970 1160 732 679 1884 1201 580 548 1246 908 1186 745 619 562 1555 561 1330 969 788 719 2083 617 1028 546 577 2001 3181 1579 976 1360 3054 989 2107 863 847.1054 3259 763 0,10%77.59%0.18%0.08%0.08%65.87%0.13%0.10%0.06%0.07%0.16%0.14%0,05%0.17% 0.06%0.18%100.00%0.08%0.10%0.06%0.06-%0.16%0.10%0.05%0.05%0 .11%0 .08%0. 10%0. 06%0.05%0 .05%0 .13%0. 05%0.11%0 .08%0 .07%0.06%0.09%0 .05%0.09%0.05%0 .05%0.17%0.27%0.13%0 .08%0.12%0 .26%0.08%0.18%0.07%0.07%0.09%0.28%0.06%0. 019%14.791%0.034%0.015%0.015%12.556%0. 025%0.019%0.012%0.014%0. 030%0.026%0.010%0.032%0.011%0.035%19.062%0.016%0.019%0.012%0.011%0.. 030%0.019%0.009%, 0.009%0.020%0.015%0.019%0.012%0.010%0.009%0.025%0.009%0,022%0.016%0.013%0.012%0.018% 0,010%, 0. 017%0 .009%0.009%0.032%0.051%0.026%71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 95 95 17.557 17.698 17.756 17,787 17.845 17.871 17.928 17.954 17.991 18.111 18.132 18.174 18.420 18.572 18.692 18.844 18 .875 18.922 18.985 19.079 19.105 19.126 19.178 19.225 19.314 0.016%0.022%0.049%0.016%0,034%0.014%0.014%0. 017%0. 053%0.012% LSC Report -Integrated Chromatogram File C:\HPCHEM\I\DATA\S70847.D Operator mei Acquired : 23 Dec 2004 11:19 pm using AcqMethod MS2585 Instrument
- MSS Sample Name: mbl40 Misc Info : MS8694,VS2588,5....
I Vial Number: 100 Quant File :MS2585.RES (RTE Integrator) 0bundance 600000 500000 400000 200000 100000 0r-Tinne-->TIC: S70847.D 9.60'7.9'B.0"B.22 8.99 9.20 8 8 .5 I .8M0 8.50 9.00 9.50 7.59 755Ea585 66.8.lIB,.91 6.6E76.87 7.10 73ZM4f\ 7 4.674.83EM0 4.50 5,00 5.50 6.00 6.50 7,00 7.50 v bundance 600000 5000001 400000 300000 200000 100000 0 rie-10.48 70 10.09 k. J L10.75 1t1!..[11:893 TIC: S70847.D 12.09 13.70*.5i , 14.96 13 13.92 14.36 14.72 10.00 10.50 11.00 11.50 12.00 12.50 I [13.00 1:3.50 14.00 14.50 6bundance 600000 50O0000 400000 3000001 200000 100000 O1 TIC: 37084[.D 25 15. 1&-W.47 155',7B&M7; ý1 6.oe a 4'1M I7`I2Tff* JM6',l1 813 8- ta* __ B11969.?800 15.5,0 1600 16.50 17.0017,50 18.00 18.50 19.00 19.50 20.00 1550..1.00.... ... 17.00.(¢S7084?.D MS2585.1A Tue Dec 28 12:53:33 2004 RPTI Tentatively Identified Compound (LSC) summary Operator ID: mei Date Acquired: 23 Dec 2004 11:19 pm Data File: C:\]HPCHEM\1\DATA\S70847.D Name: mbl Misc: MS8694,VS2588,5 .... 1* od: C:\HPCHEM\I\METHODS\MS2585.M (RTE Integrator) kle: SW-846 Method 8260Searched: C:\DATABASE\NBS75K.L TIC Top Hit name RT EstConc Units Area IntStd ISRT ISArea ISConc S70847.D MS2585.M Tue Dec 28 12:53:33 2004 RPTI SEMI-VOLATILE GCIMS Analysis Case Narrative/Conformance/Non-Conformance SummaryNO YES 1, Chromatograms Labeled/Compounds Identified (Field Samples and Method Blanks) _ _2. GC/MS Tune Meet Criteria _..__7 3. GC/MS Tuning Frequency -Performed every 24 hours for 600 series and 12 hours for 8000 series.4. GCIMS Cali'bration -Initial and Continuing Calibration Meet Method Requirements ,, _, _/5. GC/MS Calibration Requirements
- a. Calbration Check Compounds b. System Performance Check Compounds el'l-6. Blank'Contamination
_Ifyes, the sample result is qualified with a "B".7. Surrogate Recoveries Meet Criteria ./If the requirement is not met, refer to the Surrogate Summary for comment.8. Matrix Spike/Matrix Spike Duplicate Recoveries Meet Criteria .._/If the requirement is not met, refer to MSMSD Summary for comment.9. Internal Standard Area/Retention Time Shift Meet Criteria _ __If the requirement is not met, refer to the Internal Standard Summary for comment.10. Extraction Holding Time Met If the holding time is not met, refer to the Sample Result page for comment.11. Analysis Holding Time Met _If the holding time is not met, refer to the Sample ResaIt page for comment.12.. Volatile Sample Preservation -pH shouldbe <2. List any non-compliant samples below: Additional Comments: QC Review Signature: 7 Date: K K 2 6 1 ro= RG 904 Rev. Dale: 2/9/00 Method Blank Summary Job Number: N86261 Account:. AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 1 of 3 4*Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OP19045-MB1 F47472.D 1 01/08/05 NAP 12/16/04 OP19045 EF2508 The QC reported here applies to the following samples: N86261-1, N86261-2, N86261-3, N86261-4, N86261-6 Method: SW846 8270C CAS No. Compound Result RL MDL Units Q'V 95-57-8 59-50-7 120-83-2 105-67-9 51-28-5 534-52-I 95-48-7 88-75-5 100-02-7 87-86-5 108-95-2 95-95-4 88-06-2 83-32-9 208-96-8 120-12-7 56-55-3 50-32-8 205-99-2 191-24-2 207-08-9 101-55-3 85-68-7 91-58-7 106-47-8 86-74-8 218-01-9 111-91-1 111-44-4 108-60-1 7005-72-3 95-50-i 541-73-1 106-46-7 121-14-2 2-Chlorophenol 4-Chloro-3-methyl phenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrophenol 4,6-Dinitro-o-cresol 2-Methylphenol 3&4-Methylphenol 2-Nitrophenol 4-Nitrophenol Pentachlorophenol Phenol 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranihene Benzo(g,h,i)perylene Benzo(k)fluoranthene 4-Bromopheny) phenyl ether Butyl benzyl phthalate 2-Chloronaphthalene 4-Chloroaniline Carbazole Chrysene bis(2-Chloroethoxy)methane bis(2-Chloroethyl)ether
bis(2-Chloroisopropyl)ether 4-Chlorophenyl phenyl ether 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 2,4-Dinitrotoluene
- ND 5.0 ND 5.0 SNDI , 5.0.N D 5.0 Nj: , 20...D 20 N-D- :5.0 N5.0 ND 2,0 N-
- .20.ND 5.0'N 5.02.0 N D 2.0 ND 2.0::ND. 2.0;ND 2.0 N:D:NI 2.0 N'D 2.0 ND ' 2.0 ND 2.0 ND 2.0"ND 5.0 ND- 5.0.ND 1 2.0 ND .2.0 ND 2.0 ND. 2.02.0-ND 2.0 ND .2.0 4.3 4.7 0.73 1.0 1.1 0.65 0.72 0.70 0.73 2.3 0.75 1.8 0.74 0.80 0.30 0.35 0.22 0.27 0.38 0.37 0.50 0.37 0.54 0.54 0.38 0.43 0.34 0.26 0.34 0.49 0.44 1.0 0.24 0.32 0.25 0.78 ug/l ug/1 ug/1 ug/I ug./l ug/1 ug/1 ugh ug/1 ug/1 ug/l ug/1 ug/!ug/I ug/1 ug/I ug/I ug/l ug/l ug/I ug/l ug/l ug/I ug/l ug/I ug/1 ug/I ug/l ug/I ug/I ug/l ug/l ug/I ug/l ug/I ug/l Method Blank Summary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 3 Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OP19045-MB1 F47472.D 1 01/08/05 NAP 12/16/04 OP19045 EF2508 The QC reported here applies to the following samples: N86261-1, N86261-2, N86261-3, N86261-4, N86261-6 Method, SW846 8270C CAS No. Compound Result RL MIDL Units Q 606-20-2 2,6-Dinitrotoluene 91-94-1 3,3'-Dichlorobenzidine 53-7073 Dibenzo(a,h)anthracene 132-64-9 Dibenzo furan 84-74-2 Di-n-buty]
phbtalate 117-84-0 Di-n-octyl phthalate 84-66-2 Diethyl phthalate 131-11-3 Dimethyl phthalate 117-81-7 bis(2-Ethylhexyl)phthalate 206-44-0 Fluoranthene 86-73-7 Fluorene 118-74-1 Hexachlorobenzene 87-68-3 1exachiorobutadiene 77-47-4 Hexachlorocyclopentadiene 67-72-1 Hexachloroethane 193-39-5 Indeno(1,2,3-cd)pyrene 78-59-1 Isophorone 91-57-6 2-Methylnaphthalene 88-74-4 2-Nitroaniline 99-09-2 3-Nitroaniline 100-01-6 4-Nitroaniline 91-20-3 Naphthalene 98-95-3 Nitrobenzene 621-64-7 N-Nitroso-di-n-propylarnine 86-30-6 N-Nitrosodiphenylamiine 85-01-8 Phenanthrene 129-00-0 Pyrene 120-82-1 1,2,4-Trichl orobenzene CAS No. Surrogate Recoveries 367-12-4 2-Fluorophenol 4165-62-2 Phenol-d5 118-79-6 2,4,6-Tribromophenol 4165-60-0 Nitrobenzene-d5 ND 2.0 ND .5.02.0 ND 5.0 N;D 2.02.0 ND: 2.0 ND 2.0 N 2.0 S'ND .2.0 NKD 2.0:ND 2.0.ND 2.0 ND :20 ND: 5.0.ND .. 2.0 ND :2,0ýD. 2.0 ND. 5.0:N 5.0 ND 5.0 ND; 2.0 ,ýND 2.02.0 ND 5.0ýND. 2.0 NVD 2.0 ,ND 2.0 0.62 0.39 0.58 0.49 0.79 0.63 1.4 0.58 0.74 0.63 0.89 1.2 0.41 0.45 0.67 1.5 0.54 0.72 1.4 1.2 1.1 1.0 0.61 0.50 0.80 0.23 0.58 0.32 ug/l ug/l ug/I ug/l ug/l ugh ug/]ug/1 ugfl ugh ug/l ug/l ug/ug/!ughl ug/]ug/l ug/1 ug/t ug/l ug/l ug/]ug/l ug/l ug/]ug/h ug/1 ug/1*40 %-.1:035 1l05%Limits 10-88%10-71%45-134%32-128% Method Blank Summary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 3 of 3'V Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OPI9045-MB1 F47472.D 1 01/08/05 NAP 12/16/04 OP19045 EF2508 The QC reported here applies to the following samples: N86261-1, N86261-2, N86261-3, N86261-4, N86261-6 Method: SW846 8270C CAS No. Surrogate Recoveries Limits 321-60-8 2-Fluorobiphenyl 96%1718-51-0 Terpbenyl-d 14 .:06%CAS No. Tentatively Identified Compounds system anifactlaldol-condensaB ion Total~~ THC ei. S.i~* 34-121%41-129%R.T.3.88 Est. Cone. Units Q 0 .ughl J 93 Blank Spike Summary Page I of 3 Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Sample File 11D DF Analyzed By Prep Date Prep Batch Analytical Batch OP19045-BS1 F47511.D 1 01/10105 NAP 12/16/04 OP19045 EF2509 The QC reported here applies to the following samples: Method: SW846 8270C N86261-1, N86261-2, N86261-3, N86261-4, N86261-6 Spike BSP BSP CAS No.. Compound ug/l ug/Il % Limits 95-57-8 2-Chlorophenol 50 40.4 8 49-101 59-50-7 4-Chloro-3-methyl phenol 50 47.1 i!914-ýý,ý, 52-111 120-83-2 2,4-Dichlorophenol 50 46.0 9,2 54-110 105-67-9 2,4-Dimethylphenol 50 37.4 75 40-108 51-28-5 2,4-Dinitrophenol 100 93.7 94 32-129 534-52-1 4,6-Dinitro-o-cresol 50 49.3 9:9`W 49-125 95-48-7 2-Methylphenol 50 32.9 .ý661 40-98 3&4-Methylphenol 50 29.7 59.::' 32-97 88-75-5 2-Nitrophenol 50 48.4 97 50-112 100-02-7 4-Nitrophenol 50 14.7 .29 1-88 87-86-5 Pentachlorophenol 50 39.9 37-121 108-95-2 Phenol 50 16.7 33 1-84 95-95-4 2,4,5-Trichlorophenol 50 45.5 91 57-118 88-06-2 2,4,6-Trichlorophenol 50 45.3 ý"9 1 55-114 83-32-9 Acenaphthene 50 41.9 !ý84ýý 53-109 208-96-8 Acenaphthylene 50 38.8 :.97-8 48-101 120-12-7 Anthracene 50 42.9 86 61-113 56-55-3 Benzo(a)anthracene 50 44.5 :8::89 62-115 50-32-8 l3enzo(a)pyrene 50 44.2 88 60-118 205-99-2 Benzo(b)fluorantbene 50 46.2 :92 58-122 191-24-2. Benzo(g,h,i)perylene 50 44.2 `:8 8 52-131 207-08-9 Benzo(k)fluoranthene 50 45.5 :91 51-131 101-55-3 4-Bromophenyl phenyl ether 50 46.0 .92 'ý 57-115 85-68-7 Butyl benzyl phthalate 50 48.2 96 61-124 91-58-7 2-Chloronaphthalene 50 41.3 83 50-109 106-47-8 4-Chloroaniline 50 34.4 :69 27-115 86-74-8 Carbazole 50 47.2 94 60-133 218-01-9 Chrysene 50 43.5 .'87- 61-118 111-91-1 bis(2-Chloroethoxy)methane 50 46.5 -'93ý 50-115 111-44-4 bis(2-Chloroethyl)ether 50 46.9 94-' 45-113 108-60-I bis(2-Chloroisopropyl)ether 50 46.2 ý92 46-109 7005-72-3 4-Chlorophenyl phenyl ether 50 44.9 :90. 54-115 95-50-1 1,2-Dichlorobenzene 50 41.5 .'83 41-106 541-73-I 1,3-Dichlorobenzene 50 38.9 i78: 38-102 106-46-7 1,4-Dichlorobenzene 50 40.6 .:81 39-103 121-14-2 2,4-Dinitrotoluene 50 48.0 :.96 62-118 94 Blank Spike SummaryJob Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 3 Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OP19045-BS1 F47511.D 1 01/10/05 NAP 12/16/04 OP19045 EF2509 The QC reported here applies to the following samples: N86261-1, N86261-2, N86261-3, N86261-4, N86261-6 Method: SW846 8270C Spike BSP BSP ug/l ug/1 %CAS No. Compound Limits 606-20-2 91-94-I 53-70-3 132-64-9 84-74-2 117-84-0 84-66-2 131-11-3 117-81-7 206-44-0 86-73-7 118-74-1 87-68-3 77-47-4 67-72-1 193-39-5 78-59-1 91-57-6 88-74-4 99-09-2 100-01-6 91-20-3 98-95-3 621-64-7 86-30-6 85-01-8 129-00-0 120-82-1 2,6-Dinitrotoluene 3,3'-Dichlorobenzidine Dibenzo(a,h)anthracene Dibenzofuran Di-n-butyl phthalate Di-n-octyl phthalate Diethyl phthalate Dimethyl phthalate bis(2-Ethylhexyl)phthalate Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hex achlorocyclopentadiene Hexachloroethane Indeno(1,2,3-cd)pyrene lsophorone 2-Methylnaphihalene 2-Nitroaniline 3-Nitroaniline 4-Nitroaniline Naphthalene Nitrobenzene N-Nitroso-di-n-propylamine N-Nitrosodiphenylamine Phenanth rene Pyrene 1,2,4-Trichlorobenzene 50 50 50 50 50 50 50 50 50 50 50 50 50 100 50 50 50 50 50 50 50 50 50 50 50 50 50 50 BSP 8.%84 'Y 47.5 39.7 44.6 42.7 54.6 56.9 49.9 47.2 51.2 47.7 45.0 47.5 45.2 60.6.42.8 45.3 47.6 43.7 51.4 39.8 46.6 41.3 42.5 49.1 41.4 41.9 41.1 41.8 95 i 57-118 79 39-131:89> 1 53-130:85" 55-115 1)069. 61-125 114 55-14057-118 94. i 45-123 102.'ý 57-128 95 i 60-122 90 54-112!"95 58-114.90!. 41-116 61 19-107:.:.86 36-104 91 52-131:95 46-113..87 47-109 1:03" 53-122::80 43-12747-140.83- 44-105 5.85 46-108 98.. 50-117 83. 60-121:84 59-110 82 60-115.84 ! 44-103 CAS No. Surrogate Recoveries 367-12-4 4165-62-2 118-79-6 4165-60-0 2-Fluorophenol Phenol-d5 2,4,6-Tribromophenol Nitrobenzene-d5 Limits 10-88%*: 10-71%45-134%32-128%9Si Blank Spike Summary Job Number: N86261Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 3 of 3 Sample File ED DF Analyzed By Prep Date Prep Batch Analytical Batch OP19045-BSI F47511.D 1 01/10/05 NAP 12/16/04 OP19045 EF2509 The QC reported here applies to the follovirng samples: N86261-1, N86261-2, N86261-3, N86261-4, N86261-6 Method: SW846 8270C CAS No. Surrogate Recoveries 321-60-8 2-Fluorobiphenyl 1718-51-0 Terphenyl-d14 BSP Limits 78:%t 34-121%83%. .41-129% Matrix Spike/Matrix Spike Duplicate Sunmnmary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 1 of 3 Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OP19045-MS F47515.D 1 01/10/05 NAP 12/16/04 OP19045 EF2509 OP19045-MSD F47516,D 1 01/10/05 NAP 12/16/04 OP19045 EF2509 N86299-1 F47514.D 1 01/10/05 NAP 12/16/04 OP19045 EF2509 The QC reported here applies to the following samples: N86261-1, N86261-2, N86261-3, N86261-4, N86261-6 Method: SW846 8270C N86299-1 Spike MS ug/i Q ug/l ug/l MS MSD MSD% ug/l %Limits RPD Rec/RPD CAS No. Compound 95-57-8 59-50-7 120-83-2 105-67-9 51-28-5 534-52-1 95-48-7 88-75-5 100-02-7 87-86-5 108-95-2 95-95-4 88-06-2 83-32-9 208-96-8 120-12-7 56-55-3 50-32-8 205-99-2 191-24-2 207-08-9 101-55-3 85-68-7 91-58-7 106-47-8 86-74-8 218-01-9 111-91-1 111-44-4 108-60-1 7005-72-3 95-50-1 541-73-1 106-46-7 121-14-2 2-Chlorophenol 4-Chloro-3-methyl phenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrophenol 4,6-Dinitro-o-cresol 2-Methylphenol 3&4-Methylphenol 2-Nitrophenol
4-Nitrophenol Pentachlorophenol Phenol 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene 4-Bromophenyl phenyl ether Butyl benzyl phthalate 2-Chloronaphthalene 4-Chloroaniline Carbazole Chrysene bis(2-Chloroethoxy)methane bis(2-Chloroethyl)ether bis(2-Chloroisopropyl)ether 4-Chloropheny) phenyl ether 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichl orobenzene 2,4-Dinitrotoluene ND ND ND 2.4 ND ND ND ND ND ND ND ND ND ND 34.2 0.68 1.2 ND ND ND ND ND ND ND ND ND 13.4 ND ND ND ND ND ND ND ND ND 100 100 100 3 100 200 100 100 100 100 100 100 100 100 100 100 J 100 J 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 88.5 101 95.5 97.9 205 110 80.9 78.1 100 55.6 96.9 51.9 95.9 95.6 119 79.6 90.8 93.7 92.2 100 92.0 91.6 97.0 102 84.3 62.3 113 90.8 93.7 94.9 94,4 91.7 86.7 81.6 84.7 98.0 8.96 101!::9.67 !i::.i!: 6::9:96'1903.:.....1.:
- ., 0 .., 5.6 7.:9 592::8-59 ... .. ..... ..1...00.:.:...:
.92S 92,,. : .*978:': : 91.5 105 98.9 103 217 113 82.8 80.0 104 59.3 96.5 53.7 98.4 99.0 119 80.8 92.0 93.2 91.0 105 92.4 86.1 98.2 102 86.3 65.7 115 91.1 95.5 96.5 95.4 93'.9 89:1 84.2 87.4 101 92. :3 30-117/28.05: .4 36-129/25 99:. 3 37-124/27 101 { 5 28-121/28 1:09. 6: 8-144/32 113 3 24-142/29:8 2.:" 30-114128.:h .0 : 21-122/28 A 104 4 34-123/27:59 6 1-129/33.97, 0- 36-143/24 54: 3.. 1-102/32`98 3 41-131/24991: 3 43-121/25:85 0:: 40-114/30 80 1 :.{ 36-106/31:.91 I .54-119/23 93 1.i i 57-122/22-91 1 53-126/23:105 5 50-135/26 ,92: 0 35-141/29:86 6 37-144/24:98<: * : ii.< 49-121/25 102 0 56-132/23.86 2 : 34-115/30 ,66 5 10-108/372 49-146/22::::1 55-125123 96 "-2 37-119/32 97 2 32-122/37 95 1 34-112/32..i94 2' 43-118/27.89 3 31-110/31..13 .27-107/32 87 3 29-108/31 1:01 3 .50-125/31 4mAv 97. Matrix Spike/Matrix Spike Duplicate Summary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 3 to Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OP19045-MS F47515.D 1 01110105 NAP 12/16/04 OP19045 EF2509 OP19045-MSD F47516.D 1 01/10/05 NAP 12/16/04 OP19045 EF2509 N86299-1 F47514.D 1 01/10/05 NAP 12/16/04 OP19045 EF2509 The QC reported here applies to the following samples: N86261-1, N86261-2, N86261-3, N86261-4, N86261-6 Method: SW846 8270C N86299-1 Spike MS MS MSD MSD ug/1 Q ug/l ug/h % ug/l %Limits Rec/RPD CAS No. Compound RPD 606-20-2 2,6-Dinitrotoluene 91-94-1 3,3'-Dichlorobenzidine 53-70-3 Dibenzo(a,h)anthracene 132-64-9 Dibenzofuran 84-74-2 Di-n-butyl phthalate 117-84-0 Di-n-octyl phthalate 84-66-2 Diethyl phthalate 131-11-3 Dimethyl phthalate 117-81-7 bis(2-Ethylhexyl)phthalate 206-44-0 Fluoranthene 86-73-7 Fluorene 118-74-1 Hexachlorobenzene 87-68-3 Hexachlorobutadiene 77-47-A4 Hexachlorocyclopentadiene 67-72-1 Hexachloroethane 193-39-5 Indeno(1,2,3-cd)pyrene 78-59-1 Isophorone 91-57-6 2-Methylnaphthalene 88-74-4 2-Nitroaniline 99-09-2 3-Nitroaniline 100-01-6 4-Nitroaniline 91-20-3 Naphthalene 98-95-3 Nitrobenzene 621-64-7 N-Nitroso-di-n-propylainine 86-30-6 N-Nitrosodiphenylamine 85-01-8 Phenanthrene 129-00-0 Pyrene 120-82-1 1,2,4-Trichlorobenzene CAS No. Surrogate Recoveries ND ND ND 27.3 ND ND ND ND ND 1.9 7.1 ND ND ND ND ND ND 1.3 ND ND ND 37.2 ND ND ND 6.6 0.91 ND MS 56.-85f 100 100 100 100 100 100 100 100 100 J 100 100 100 100 200 100 100 100 J 100 100 100 100 100 100 100 100 100 J 100 100 MSD 98.3 74.8 93.5 ill 117.123 103 98.0 110 102 98,5 103 95.7 120 91.6 95.1 95.7 90.3 102 78.9 97.8 117 86.8 99.2 88.1 94.3 86.6 86.7:::84 A117-.123 103.98 1101:100, 91:.96.92'95 89 87.99:88:86 :!:!:'i: 101 82.9 94.1 115 113 121 102 98.5 108 102 101 99.1 97.8 131 94.4 94.7 96.9 92.0 107 79.0 103 119 88.4 100 89.7 94,7 86.7 89A1 101 3 45-124/28 83 8. 0 1-145/37 94 .40-138/27 88 4 42-119/28 13 3 i 54-131/22 1:21,: 2: 49-151/25 102: 49-123124 9.. .39-124/27 108 2 .51-140/290! , 52-129/22 94: 3 43-116/26 9 4: : 49-121/24 9&8 2 30-126/33 6~ 9 1-109/41{4 3! !22-113/34 9:.. 0! 40-139/28 97- 1 34-116/37~1 .2 28-123/32 1:0T: :5: 30-135/33 79-7 -0 15-134/35 103l 5 18-153/32 -2 22-120/30 2 : 31-118/32 100 : 1 , 32-125/33 2. 49-131/24 88 i 0 51-117/23.:86: 54-122/22 89 3 27-115/31 N86299-1 Limits 367-12-4 4165-62-2 118-79-6 4165-60-0 2-Fluorophenol Phenol-d5 2,4,6-Tribromophenol Nitrobenzene-d5
- 56 -% ::::::::::::{: i: 43%:5ýc 10.1% .102%.87%
!i g }:;:{::!: 10-88%V., 10-71 ~45-.134%.. 32-128%w 98 Matrix Spike/Matrix Spike Duplicate Sunmmary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 3 of 3 Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OP19045-MS F47515.D 1 01/10/05 NAP 12/16/04 OP19045 EF2509OPI9045-MSD F47516.D 1 01/10/05 NAP 12/16/04 OP19045 EF2509 N86299-1 F47514.D 1 01/10/05 NAP 12/16/04 OP19045 EF2509 The QC reported here applies to the following samples: N86261-1, N86261-2, N86261-3, N86261-4, N86261-6 Method: SW846 8270C CAS No. Surrogate Recoveries 321-60-8 2-Fluorobiphenyl 1718-51-0 Terphenyl-dl4 MS MSD N86299-1 Limits 80% 81 @ :::i ;.i2!. 34-121%85 9ý .8. 7
- %:: 41-129%
Instrument Performance Check (DFTPP)Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 1 of I 6 Sample: EF2491-DFTPP Injection Date: 12/14/04 Lab File ID: F46939.D Injection Time: 16:21 Instrument ID: GCMSF Raw % Relative m/e Ion Abundance Criteria Abundance Abundance Pass/Fail 51 30.0 -60.0% of mass 198 4643 :4.? .Pass:68 Less than 2.0% of mass 69 52 ,(:1.1)a Pass 6 :9 Mass 69 relative abundance 4650 Pass.. .Less than 2.0% of mass 69 0 -i:(Q..0) Pass 1,27 40.0 -60.0% of mass 198 5573 54." Pass 1:97, Less than 1.0% of mass 198 0 ,i0-.......... Pass:19B Base peak, 100% relative abundance 10149 100.0 Pass5.0- 9.0% of mass 198 607 6.0: Pass10.0- 30.0% of mass 198 2337 .2-.:0 Pass 365 1.0 -100.0% of mass 198 192 ':'1.9 Pass 441:... Present, but less than mass 443 1092 1( b Pass 442 < 40,0- 100.0% of mass 198 7223 7:.2 Pass 443: 17.0- 23.0% of mass 442 1414 "3.9 (19.6 7 Pass (a) Value is % of mass 69 (b) Value is % of mass 443 (c) Value is % of mass 442 This check applies to the following Samples, MS, MSD, Blanks, and Standards: Lab Lab Date Time Hours Client Sample ID File ID Analyzed Analyzed Lapsed Sample ID EF2491-1CC2491 F46940.D 12/14/04 16:45 00:24 Initial cal 50 EF2491-1C2491 F46941.D 12/14/04 17:22 01:01 Initial cal 100 EF2491-1C2491 F46942.D 12/14/04 17:59 01:38 Initial cal 80 EF2491-IC2491 F46943.D 12/14/04 18:36 02:15 Initial cal 25 EF2491-IC2491 F46944.D 12/14/04 19:12 02:51 Initial cal 10 EF2491-IC2491 F46945.D 12/14/04 19:49 03:28 Initial cal 5 EF2491-1C2491 F46946.D 12/14/04 20:26 04:05 Initial cal 2 OPI8875-MBI F46948.D 12/14/04 21:39 05:18 Method Blank ZZZZZZ F46949.D 12/14/04 22:15 05:54 (unrelated sample)ZZZZZZ F46950.D 12/14/04 22:52 06:31 (unrelated sample)ZZZZZZ F46951..D 12/14/04 23:29 07:08 (unrelated sample), ZZZZZZ F46952.D 12/15/04 00:05 07:44 (unrelated sample)ZZZZZZ F46953.D 12/15/04 00:42 08:21 (unrelated sample), ZZZZZZ F46954.D 12/15/04 01:19 08:58 (unrelated sample)'ZZZZZZ F46955.D 12/15/04 01:56 09:35 (unrelated sampile)ZZZZZZ F46956.D 12/15/04 02:32 10:11 (unrelated sample)ZZZZZZ F46957.D 12/15/04 03:09 10:48 (unrelated sample), ZZZZZZ F46958.D 12/15/04 03:47 11:26 (unrelated sample). " Stoo instrument Performance Check (DFTPP) Page 1 of 1 Job Number: N86261Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Sample: EF2508-DFTPP Injection Date: 01/08/05 Lab File ID: F47468.D Injection Time: 08:59 Instrument ID: GCMSF Raw % Relative m/e Ion Abundance Criteria Abundance Abundance Pass/Fail 30.0- 60.0% of mass 198 10455 p42 ...' Pass 68 Less than 2.0% of mass 69 0 .0.0 (0.0)a Pass 6 i9 ' Mass 69 relative abundance 10463 42.3. Pass.70 Less than 2.0% of mass 69 189 :(.8): ' Pass 127 40.0- 60.0% of mass 198 12101 49.0 Pass 1 -. Less than 1.0% of mass 198 0 "0.0 Pass 19.8 Base peak, 100% relative abundance 24717 100.0 Pass 10 : 5.0- 9.0% of mass 198 1661 61 : Pass 27S 10.0- 30.0% of mass 198 5676 23.0 Pass 365 1.0- 100.0% of mass 198 596 :24 Pass 4-1: Present, but less than mass 443 2901 .1.1.7, (75.4) Pass 442 40.0- 100.0% of mass 198 19728 79.8 ;Pass 443. 17.0- 23.0% of mass 442 3850 1:;:5. 6. (19.5) Pass (a) Value is % of mass 69 (b) Value is % of mass 443 (c) Value is % of mass 442 This check applies to the following Samples, MS, MSD, Blanks, and Standards: Lab Lab Date Time Hours Client Sample ID File ID Analyzed Analyzed Lapsed Sample ID EF2508-CC2491 F47469.D 01/08/05 09:13 00:14 Continuing cal 25 OPi 9048-MB] F47470.D 01/08/05 09:50 00:51 Method Blank OP19048-BSI F47471.D 01/08/05 10:25 01:26 Blank Spike OP19045-MB1 F47472.D 01/08/05 11:01 02:02 Method Blank ZZZZZZ F47473.D 01/08/05 11:37 02:38 (unrelated sample)N86261-3 F47474.D 01/08/05 12:13 03:14 WELL X N86261-4 F47475.D 01/08/05 12:49 03:50 FB-2 N86157-4A F47476.D 01/08/05 13:25 04:26 (used for QC only; not part of job N86261)ZZZZZZ F47477.D 01/08/05 14:01 05:02 (unrelated sample)OP19048-MS F47478.D 01/08/05 14:37 05:38 Matrix Spike OP19048-MSD F47479.D 01/08/05 15:13 06:14 Matrix Spike Duplicate ZZZZZZ F47481.D 01/08/05 16:24 07:25 (unrelated sample)N86261-6 F47484.D 01/08/05 18:12 09:13 WELL AX ZZZZZZ F47485.D 01/08/05 18:48 09:49 (unrelated sample)ZZZZZZ F47486.D 01/08/05 19:24 10:25 (unrelated sample)ZZZZZZ F47488.D 01/08/05 20:35 11:36 (unrelated sample)iQi Instrument Performance Check (DFTPP)Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 1 of 1%0 Sample: EF2509-DFTPP Injection Date: 01/10/05 Lab File ID: F47509,D Injection Time: 08:29 Instrument ID: GCMSF Raw % Relative m/e ]on Abundance Criteria Abundance Abundance Pass/Fail 1 : 30.0 -60.0% of mass 198 10423 -45..8 *Pass 68: ý Less than 2,0% of mass 69 Ps65 (29 (0.62) .s:69 Mass 69 relative abundance 10514 61, !i .*ý:2 Pass 70 Less than 2.0% of mass 69 .59 0.6a0s6sa 1 2-7 40.0- 60.0% of mass 198 12127 53.3. Pass I19-77 Less than 1.0% of mass 198 0 0:O.0 Pass 1918", Base peak, 100% relative abundance 22741 190.10..... .. Pass 199 5.0- 9.0% of mass 198 1687 7,4 Pass 275 10.0 -30.0% of mass 198 5424 Pass1.0- 100.0% of mass 198 510 2.2 PassPresent, but less than mass 443 2546 11,2 Pass40.0-100.0% of mass 198 17620 7 7.5. :: Pass 443 : 17.0 -23.0% of mass 442 3458 15:.2 Pass (a) Value is % of mass 69 (b) Value is % of mass 443 (c) Value is % of mass 442 This check applies to the following Samples, MS, MSD, Blanks, and Standards: Lab Lab Date Time Hours Client Sample ID File ID Analyzed Analyzed Lapsed Sample ID EF2509-CC2491 F47510.D 01/10/05 09:20 00:51 Continuing cal 25 OP19045-BSI F47511 .D 01/10/05 09:55 01:26 Blank Spike N86261-1 F47512.D 01/10/05 10:3) 02:02 WELL AY N86261-2 F47513.D 01/10/05 11:07 02:38 WELL AV N86299-1 F47514.D 01/10/05 11:43 03:14 (used for QC only; not part of job N86261)OP19045-MS F47515.D 01/10/05 12:19 03:50 Matrix Spike OP19045-MSD F47516.D 01/10/05 12:54 04:25 Matrix Spike Duplicate ZZZZZZ F47517.D 01/10/05 13:30 05:01 (unrelated sample)ZZZZZZ F47518.D 01/10/05 14:06 05:37 (unrelated sample)ZZZZZZ F47519.D 01/10/05 14:42 06:13 (unrelated sample)ZZZZZZ F47520.D 01/10/05 15:18 06:49 (unrelated sample)ZZZZZZ F47521.D 01/10/05 15:54 07:25 (unrelated sample)'..r ... Semivo!atfle internal Standard Area S,,mmr,.y Job Number: N86261Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 1 of 1Check Std: EF2508-CC2491 Injection Date: 01/08/05 Lab File ID: F47469.D Injection Time: 09:13 Instrument ID: GCMSF Method: SW846 8270C ISI IS2 IS3 IS4 1S5 1S6 AREA RT AREA RT AREA RT AREA RT AREA RT AREA RT Check:Std. 304882::. 6.30 -1:1-77486: 8.92 627020 13.00 1093894 16.48 :052973 22.03 641020: 24.35 Upper Limita 609764.:: 6.80 23549ý6.0 9.42 :1254040 13.50 2187-7.88 16.98 210594. 22.53 4.2:864 24.85 Lower Limit b .1-5244:1 5.80 58874.0 8.42 3.,35110: 12.50 .54694:7. 15.98 5::::: 21.53 .350. 23.85 Lab Sample ID OP]9048-MB 1 OP]9048-BS1 OP19045-MB1 zzzzzz N86261-3 N86261-4 N86157-4A zzzzzz OP19048-MS OP19048-MSD zzzzzz N86261-6 zzzzzz zzzzzz zzzzzz IS ]AREA RT 2907,80.: 6.29 V-5*575:5`ý'- 6.30 223f34i: 6.30 254499 6.30 6.30 2*68040:.: 6.30 32685.1. 6.30 6.306.30 3103601- 6.30 281.300.:: 6.30 2ý622.35 6.3.]280957 6.31 28540.2.: 6.30 3,19466 6.30 I 2 AREA 1206755:1 908.7 1:08 79,24 1:062546 1.2'17622:127363 '3:.102'7625 .1093151 1042068.1.02395-2 1.151:672] .ii54J27 1.176903i!:v 8.91 8.91 8.91 8.91 8.91 8.91 8.91 8.91 8.91 8.92 8.92 8.92 8.92 8.92 8.92 604412 13.00 62614.1. 13.00 461. 9164 12.99 5231740..: 12.99 5794611- 12.99 567-538 12.99 58 622 5 13.00 6.1638: 13.0013.0013.01 5270.97.. 13.01 548337 13.00 586856 13.0013.01 5571:011 13.0016.48 10'Q566117 16.4816.48 928946 16.48 19 0294,63 16,48 9908.71 16.48 1055i946 16.48 9846,07 16.48 9.262.14 .- 16.4816.49 93,34.05: 16.49.960822 16.4816.48:1043352 16.48 9228-32; 16.48 1 3 I 4 IS 5 RT AREA RT AREA RT AREA RT 9718057 22.0222.03 746263. 22.02 864232i 22.02 973213':ý 22.02 9129862':!'- 22.03 901557i 22.05 9566:88 22.03 781-487ý 22.05 73B918- 22.0622.04 762285i 22.03 76 3009. 22.0322.03 7.6048.0. 22.03 IS 6 AREA RT 6T1,687711* 24.35 6414226". 24.35 4683-09 24.35 524368ý 24.35 6012{34 24.35 576024.35 28492:3ý*ý 24.39 574188-s; 24.35 2381'31-* 24.39 220048* 24.40 224922'ý 24.37-320964 24.35 3.3.:66241, 24.3624.35 27.28.38V 24.36 IS 1 = 'l,4-Dichlorobenzene-d4 IS 2 = Naphthalene-d8 is 3 = Acenaphthene-D10 IS4 = Phenanthrene-dlO IS 5 = Chrysene-d12 IS 6 = Perylene-d12 (a) Upper Limit = + 100% of check standard area; Retention time +0.5 minutes.(b) Lower Limit = -50% of check standard area; Retention time -0.5 minutes.1L~3 Semivolatile Internal Standard Area Summary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 1 of 1 Check Std: EF2509-CC2491 'Injection Date: 01/10/05 Lab File ID: F47510.D Injection Time: 09:20 Instrument ID: GCMSF Method: SW846 8270C ISi IS2 IS3 IS4 IS5 1S6 AREA RT AREA RT AREA RT AREA RT AREA RT AREA RT CQh 65!: 7 :i 6.30 1393234 8.92 762ý9.7:ý 13.01 1292189 16.49 22.03 761360. 24.36 Upper Limita 731530: 6.80 2786468 9.42 13.51 16.99 2.56677 22.53 112 Q 24.86 Lower Limit b 5.80 696617 8.42 $U1.471,;, 12.51 6,.4Q95 15.99 64.1694 21.53 360: 23.86 Lab Sample ID OP19045-BS1 N86261-1 N86261-2 N86299-1 OPI9045-MS
OPI 9045-MSD zzzzzz zzzzzz zzzzzz zzzzzz zzzzzz IS 1 AREA RT 398009 6.30 297550: 6.30 291001, 6.30 2940624 6.30 3453:.18 6.30 32:1713. 6.30 29819 6.30 2862.70 6.30 2147401 6.30 30.6358: 6.30 IS2 , AREA RT:1203835 8.92.12:16250 8.91 1200.52 8.92 1.162419 8.91 1-349187 8.928.92 1:171009 8.91 13102060 8.95.1002919 8.96 131:8907 8.92 11.564-4-'14 8.91 IS3 AREA RT 659759I:§: 13.01 6639197'10 13.00 650226.i 13.0113.00 7,324:34. 13.01 687635 :13.01 65-6582 13.00 6542-209 13.01 604556 13.01 ,71.9 13.00 6324;1:9.;i; 13.00 1S4 AREA RT IS 5 AREA RT 11563039 16.49 1.182796 16.48 1I 15220 9 16.49.11.57250 16.48.1248428 16.49'1ý1923,92 16.49 3:119745. 16.48 109706.0 16.49.101:823.2 16.48 1263,470 16.48 1-1407798 16.48.12 3ý70 22.03 22.03 1.089300 22.0322.03.:34541:3 22.04.1262890 22.04 1103065 22.03 11.42,76-222.03 904473 22.03 1:8.1240 22.0322.03 7 24.36 7.34,86 6 24.35 6608!.11* 24.35 674896.`.: 24.35 8229%0.5: 24.36 7179765 24.36 674192..:. 24.35 730436- 24.36.5.533.78-:1 24.36 7,37:778 '. 24.36 697416. 24.36 IS 6 AREA RT to IS 1 IS2 IS 3 IS 4 is 5 IS 6= 1,4-Dichlorobenzene-d4 = Naphthalene-d8 = Acenaphthene-D I0= Phenanthrene-dlO = Chrysene-d 12= Perylene-d12 (a) Upper Limit = + 100% of check standard area; Retention time +0.5 minutes.(b) Lower Limit = -50% of check standard area; Retention time -0.5 minutes.#60 Selivolatile Surrogate Recovery Sununary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page I of 1 4W Method: SW846 8270C Matrix: AQ Samples and QC shown here apply to the above method Lab Sample ID Lab File ID S1 S2 S3 S4 S5 S6 N86261-1 N86261-2 N86261-3 N86261-4 N86261-6 OP19045-BSI OP19045-MBI OP19045-MB1 OP19045-MS OPI9045-MSD F47512.D F47513.D F47474.D F47475.D F47484.D F47511.D F47472.1D PI1389.D F47515.1 F47516.D A44.0 29.0 46.0 32.0 39.0 -27.0 45.0 29.0 S.49.0 : 32.0 38.G .60.0 40.0 6 .0 : 39.0 56:0 .56-0 ý43.0 8..B7.0::: 76.0 99:.0 78.0 88.0 72.0 810 85.0.:96.0 89.084.0 105.0 I124:0.ý. 101.0 12.10Z 85.0 101-.0 87.0 70.0 83.093.0 649.11* 95.0 75.0 :92.0112.083.0:96.10 106.05 o106.0 800 85.0 8..-0 87.0 Surrogate'Compounds S1 = 2-Fluorophenol S2 = Phenol-d5 S3 = 2,4,6-Tribromophenol S4 = Nitrobenzene-d5 S5 = 2-Fluorobipheny) S6 = Terphenyl-d]4 Recovery Lim-its 32-:128%5,: 4.1-129%tap Initial Calibration Summary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page I of 3 Sample: EF2491-]CC2491 Lab FilelD: F46940.D Response Factor Report MSF Method Title Last Update Response via C:\MSDCHEM\1\METHODS\MF2491.M (RTE Integrator) Semi Volatile Extractables by GC/MS Mon Dec 20 09:17:47 2004 Initial Calibration Calibration Filt 2 =F46946.D 100 =F46941.D 5 =F46945.D 50 =F46940.D 25 =F46943.D 10 =F46944.D 80 =F46942.D Compound 2 5 25 80 100 50 10 Avg %RSD 1)2)3)* 4)5)6)7)8)9)10)11)12)13) 14)15)16)17)18)19)20)21)22)23)24)25)26)27)28)29)30)31)32)33)34)35)36)37)38)39)40)41)42)43)44)45)I 1,4-Dichlorobenzene-d
1,4-Dioxane 0.829 0.741 0.653 Pyridine 1.702 1.719 1.682 N-Nitrosodim 0.621 0.550 0.532 2-Fluorophen 1.486 1.528 1.409 Indene 2.452 2.509 2.532 Cumene 3.078 3.209 3.184 Phenol-d5 1.825 1.872 1.724 Phenol 1.969 1.989 1.927 Aniline 2.140 2.285 2.232 bis(2-Chloro 1.345 1.370 1.348 Benzaldehyde 0.275 0.361 0.593 2-Chlorophen 1.433 1.462 1.447 Decane 1.292 1.363 1.313 1,3-Dichloro 1.535 1.598 1.584 1,4-Dichloro 1.637 1.653 1.595 Benzyl alcoh 0.909 0.925 0.949 1,2-Dichloro 1.495 1.533 1.489 Acetophenone 1.926 1.959 1.948 2-Methylphen 1.309 1.336 1.303 2,2'-oxybis( 0.460 0.466 0.459 3&4-Methylph 1.348 1.374 1.388 n-Nitroso-di 0.758 0.811 0.823 Hexachloroet 0.479 0.507 0.525------------
ISTD --------------------- 0.583 1.489 0.481 1.250 2.320 3.030 1.450 1.569 1.837 1.213 0.238 1.271 1.174 1.468 1.490 0.823 1.365 1.703 1 .103 0.419 1.150 0.717 0.500 0.594 1.514 0.488 1.257 2.349 3.075 1.450 1.567 1. 852 1.213 0.181 1.281 1.166 1.492 1.499 0.826 1.382 1.731 1.116 0.420 1.163 0.728 0.511 0.628 1.594 0.514 1.344 2.429 3.134 1 .605 1.765 2 .040 1.276 0.401 1.366 1.231 1.529 1.552 0.901 1.441 1.837 1.210 0.437 1.276 0.772 0.515 0.708 1.780 0.581 1.491 2 .670 3.361 1.829 2.048 2.38o 1.418 0.405 1 .537 1.423 1.669 1.690 0.985 1.584 2.056 1.370 0.490 1.455 0 .850 0. 547 0 .676 1.640 0.538 1.395 2.466 3 .153 1.679 1 .833 2.110 1.312 0.351 1.399 1.280 1.554 1.588 0. 903 1.470 1.880 1.250 0.450 1.308 0.780 0.512 13.05 6.69 9.37 8.19 4.81 3.54 10.69 10.98 9.96 6.05 38.87 7.02 7 .47 4 .43 4.87 6.67 5.39 6 .85 8.60 5 .74 8.87 6.36 4 .14 I Naphthalene-d8 Nitrobenzene 0.349 Nitrobenzene 0.161 Quinoline 0.664 Isophorone 0.607 2-Nitropheno 0.131 2,4-Dimethyl 0.317 Benzoic acid bis(2-Chloro 0.382 2,4-Dichloro 0.251 1,3,5-Trichl 0.335 1,2,4-Trichl 0.324 1,2,3-Trichl 0.310 alpha-Terpin 0.268 Naphthalene 1.111 4-Chloroanil 0.404 2,3-Dichloro 0.311 Caprolactam 0.100 Hexachlorobu 0 .182 4-Chloro-3-m 0.248 2-Methylnaph 0.673------ISTD--0.372 0.172 0.679 0.637 0.154 0.338 0.398 0.264 0.343 0.326 0 .314 0.278 1.110 0.441 0 .332 0 .121 0.183 0.276 0.390 0.181 0.691 0.645 0.183 0.349 0.238 0.396 0.278 0.335 0 322 0 .309 0.277 1.063 0.444 0.335 0.137 0.184 0.296 0.371 0.172 0.618 0.580 0.180 0.313 0 .253 0 .364 0.256 0 .326 0 .313 0 .297 0.241 0.983 0.389 0.299 0.117 0.182 0.265 0.641 0.378 0.176 0.640 0 .593 0 .184 0.322 0.263 0.370 0.262 0.331 0.320 0.306 0.240 0. 998 0.396 0.307 0.122 0.186 0.274 0.657 0'. 383 0.177 0 .662 0 .614 0.181 0 .334 0 .244 0.376 0.269 0.331 0.318 0 .305 0.255 1 .027 0.421 0 .322 0 .128 0.183 0.284 0 .675 0.408 0.379 4.84 0.188 0.175 4.81 0.727 0.669 5.29 0.681 0.622 5.56 0.184 0.171 12.070.355 0.332 4.81 0.181 0.236 13.56 0.418 0,386 4.90 0.289 0.267 4.90 0.354 0.337 2.75 0.343 0.324 2.94 0.329 0.310 3.22 0.297 0.265 7,90 1.137 1.061 5.68 0.470 .0.423 6.98 0.352 0.323 5.68 0.139 0.124 10.68 0.195 0.185 2.54 0.300 0.278 6.47 0.740 0 .68CG.77 0.693.0.702 Initial Calibration Summary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 3 Sample: EF2491-ICC2491Lab FileID: F46940.D 46) 1-Methylnaph 0.655 0.676 0.678 0.620 0.636 0.659 0.713 47) Dimethylnaph 0.565 0.591 0.601 0.541 0.552 0.578 0.633 48) I Acenaphthene-dlO
ISTD --------------
- 49) Hexachlorocy 0.180 0.209 0.304 0.358 0.369 0.335 0.283----- Linear regression
Coefficient
= 0.9984 Response Ratio = -0.05128 + 0.37242 *A 0.662 4.56 0.580 5.38 0.291 24.99 50)51)52)53)54)55)56)57)58)59)60)61)2,4,6-Trichl 2,4,5-Trichl 2-Fluorobiph 2-Chloronaph Biphenyl 2-Nitroanili Dimethylphth Acenaphthyle 2,6-Dinitrot 0.324 0.369 1.530 1.222 1.692 0.239 1.184 1.782 0.162 0.369 0.401 1.522 1.229 1.699 0.305 1.256 1.899 0.221 0.397 0.438 1.507 1.212 1.663 0.341 1.289 1.991 0.278 0.395 0.433 1 523 1.177 1.598 0 .297 1.220 1 .912 0.279 0.405 0.444 1.537 1.183 1.598 0.299 1.250 1.961 0.285 0.392 0.435 1.491 1 .182 1.617 0.317 1.255 1 .944 0.275 0.406 0.445 1.591 1.281 1.763 0,349 1.331 2.056 0.267 Linear regression
Coefficient
= 0.9997 Response Ratio = -0.00705 + 0.28508 *A 3-Nitroanili 0.228 0.287 0.337 0.309 0.316 0.322 0.341 Acenaphthene 1.241 1.243 1.226 1.177 1.209 1.203 1.305 2,4-Dinitrop 0,064 0.137 0.168 0.175 0.151 0.108 SLinear regression
Coefficient
= 0.9975 Response Ratio = -0.04432 + 0.17979 *A 0.384 0.424 1.529 1.212 1.662 0.307 1.255 1.935 0.252 0.306 1.229 0.134 0.164 1.683 0.342 0.308 1.225 1.319 0.676 0.285 7.56 6.68 2 .06 3 .03 3.70 11.70 3.72 4.41 17.95 12.65 3.31 31.28 7.28 3.94 17.45 13.81 4.67 3.81 2.56 14.31 62) 4-Nitropheno 0.141 0,170 0.165 0.170 0.173 0.167 63) Dibenzofuran 1.716 1.734 1.674 1.597 1.629 1.642 1.786 64) 2,4-Dinitrot 0.217 0.315 0.381 0.364 0.378 0.371 0.371-Linear regression
Coefficient
=* 0.9993 Response Ratio = -0.00471 + 0.37513 *A 65)66)67)68)69)2,3,4,6-Tetr Diethylphtha Fluorene 4-Chlorophen 4-Nitroanili 0.220 1.160 1.288 0.671 0.211 0.284 1.241 1.341 0.674 0.286 0.331 1.267 1.341 0.682 0.327 0.325 1.167 1.259 0,655 0.271 0.339 1.195 1.288 0.675 0.267 0,329 0.328 1.227 1.320 1.303 1.411 0.662 0.710 0.303 0.328 70) I Phenanthrene-dlO
ISTD ----------------------
- 71) 4,6-Dinitro-0.058 0.106 0.132 0.135 0.117 0.089 0.206 27.52-Linear regression
.....-Coefficient = 0.9973 Response Ratio = -0.01635 + 0.13942 *A 72)73)74)75)76)77)78)79)80)81)82)83)84)Atrazine n-Nitrosodip 1,2-Diphenyl 2,4,6-Tribro 4-Bromopheny Hexachlorobe Pentachlorop Phenanthrene Anthracene Carbazole Di-n-butylph Fluoranthene Octadecane
- 0. 096 0.533 0.749 0.068 0.188 0.205 0.146 1.214 1.149 0.922 0.793 0.989 0.384 0.121 0.563 0.772 0.082 0.205 0.210 0.112 1.210 1.228 0.993 1.063 1.189 0,431 0.132 0.569 0.742 0.089 0.209 0.205 0.144 1.167 1.207 0 .977 1.144 1.170 0.420 0.110 0 .556 0.687 0.094 0.217 0.214 0.155 1 .133 1 .174 0.830 1 .089 1 .113 0.399 0.106 0.562 0.716 0.097 0 .224 0.222 0.161 1.169 1.202 0 .810 1 .114 1 .161 0 .391 0.118 0 .559 0 705 0 .090 0.210 0 .209 0 .154 1 .153 1 .192 0 .904 1.128 1.181 0.397 0.134 0.595 0.805 0.087 0.216 0.217 0.136 1.250 1.273 1.039 1.142 1.211 0.447 0.117 0.563 0.739 0.087 0.210 0 .212 0 .144 1.185 1 .204 0.925 1.068 1.145 0.410 11.75 3.24 5.51 11.21 5.52 2.88 11.48 3.43 3.31 9.16 11.66 6.56 5.63 20.65 Q0-763 85) I Chrysene-d12
- 86) Benzidine 0.127 87) Pyrene 1.205---I-STD-.---------------------
0.189 0.231 0.165 0.153 0.205 0.221 0.184 1.323 1.315 1.313 1.314 1.291 1.357 1.3031 Initial Calibration Summary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 3 of 3 Sample: EF2491-ICC2491 Lab FilelID: F46940.D 88) Terphenyl-dl 0.815 0.908 0.914 0.919 0.929 0.895 0.934 89) Butylbenzylp 0.262 0.425 0.485 0.479 0.479 0.474 0.464 Linear regression Coefficient = 0.9999 Response Ratio = -0.00607 + 0.48182 *A 90) Butyl steara 0.156 0.249 0.280 0.251 0.236 0.255 0.280----- Linear regression .....-Coefficient = 0.9966 Response Ratio = 0.00901 + 0.23987 *A 0.902 4.48 0.438 18.29 0.244 17.27 91)92)93)94)Benzo[a]anth 0.979 1.142 1.155 1.163 1.184 1.156 1.192 3,3'-Dichlor 0.256 0.313 0.363 0.337 0.320 0.363 0.347 Chrysene 1.181 1.187 1.162 1.139 1.156 1.128 1.241 bis(2-Ethylh 0.337 0.552 0.629 0.624 0.611 0.608 0.610 Linear regression .....-Coefficient = 0.9997 Response Ratio = -0.00518 + 0.61819 *A 1.139 0.329 1,171 0.567 95) I Perylene-d12 -- -------------- ISTD ----------------------
- 96) Di-n-octylph 0.477 1.060 1.414 1.439 1.419 1.399 1.238 1.206----- Linear regression Coefficient
= 0.9998 Response Ratio = -0.04348 + 1.44516 *A 6.39 11.37 3.20 18.49 28.98 9.67 4.40 10.81 16.11 97)98)99)100)Benzo[b)fluo 1.370 1.553 1.746 1.846 1.780 1.723 1.725 Benzo[k)fluo 1.675 1.822 1.811 1.684 1.851 1.848 1.856 Benzo(a)pyre 1.196 1.482 1.592 1.630 1.689 1.639 1.604 Indeno[1,2,3 1.014 1.239 1.441 1.630 1.647 1.570 1.428----- Linear regression Coefficient = 0.9994 Response Ratio = -0.07280 4 1.66364 *A 1.677 1.792 1.547 1.424 6w 101) Dibenz(a,h)a 0.683 0.923 1.099 1.275 1.286 1.210 1.065 SLinear regression
Coefficient
= 0.9991 Response Ratio = -0.06856 + 1.30299 *A 102) Dibenzia,h]a 0.878 1.058 1.255 1.421 1.441 1.366 1.245 Linear regression
Coefficient
= 0.9993 Response Ratio = -0.06637 + 1.45402 *A 1.077 20.06 1.238 16.60 103)104)105)7,12-Dimethy 0.544 0.664 0.774 0.770.0.796 0.7770.756 3-Methylchol Benzo[g,h,i] 0.826 1.008 1.164 1.358 1.368 1.309 1.162----- Linear regression
Coefficient 0.9992 Response Ratio = -0.06719 + 1.38666 *A 0.726 0. 000#1.171 12.53-1.00 17.04 (#) = Out of Range 1### Number of calibration levels exceeded format MF249!.M Mon Dec 20 16:50:35 2004 RPTI Continuing Calibration Summary Job Number: N86261 Account: AGMPAL Arcadis Geraghty, & Miller Project: PSEG-Salem, Artificial Island, Salem, NJPage 1 of 3Sample: EF2508-CC249 1 Lab FilelD: F47469.D Evaluate Continuing Calibration Report Data File : C:\MSDCHEM\1\DATA\EF2508\F47469.D Acq On 8 Jan 2005 9:13 am Sample CC2491-25 Misc OP19067,EF2508 MS Integration Params: LSCINT.P Vial: 2 Operator:
NINAP Inst : MSF Multiplr: 1,00 Method Title Last Update Response via Min. RRF Max. RRF Dev C:\MSDCHEM\I\METHODS\MF2491.M (RTE Integrator) Semi Volatile Extractables by GC/MSSat Jan 08 09:45:35 2005 Multiple Level Calibration 0.050 Min. Rel. Area : 48% Max. R.T. Dev 0.50min 20% .Max. Rel. Area : 200%Compound AvgRF CCRF%Dev Area% Dev(min)R.T. 'Vw 1 2 3 4 S 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24.1,4-Dichlorobenzene-d4 1,4-Dioxane Pyridine N-Nitrosodimethylamine 2-Fluorophenol Indene Cumene Phenol-d5 Phenol Aniline bis(2-Chloroethyl)ether Benzaldehyde 2-Chlorophenol Decane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Benzyl alcohol 1,2-Dichlorobenzene Acetophenone 2-Methylphenol 2,2'-oxybis(1-Chloropropa 3&4-Methylphenol n-Nitroso-di-n-propylamin Hexachloroethane Naphthalene-d8 Nitrobenzene-d5 Nitrobenzene Quinoline Isophorone 2-Nitrophenol 2,4-Dimethylphenol Benzoic acid bis(2-Chloroethoxy)methan 2,4-Dichlorophenol 1,3,5-Trichlorobenzene 1,2,4-Trichlorobenzene 1,2,3-Trichlorobenzene alpha-Terpineol Naphthalene 4-Chloroaniline 2,3-Dichloroaniline 1.000 0.676 1.640 0.538 1.395 2.466 3.153 1.679 1.833 2.110 1.312 0.351 1.399 1.280 1.554 1.588 0.903 1.470 1.880 1.250 0.450 1.308 0.780 0.512 1.000 0.379 0.175 0.669 0.622 0.171 0.332 0.236 0.386 0.267 0.337 0.324 0.310 0.265 1.061 0.423 0.323 1.000 0.576 1.564 0.631 1.386 2.576 3 .251 1.673 1.938 1 .956 1.219 0.605 1.444 1.424 1 .554 1.658 0.886 1 .513 1.980 1.213 0.453 1.319 0 .835 0 565 1.000 0.416 0.181 0.681 0.668 0.197 0.359 0.181 0.388 0.284 0.347 0.338 0.324 0.298 1.082 0.411 0.345 0.0 14 .8 4.6-17.3 0.6-4.5-3.1 0.4-5.7 7.3 7.1-72.4#-3.2-11.2 0.0-4.4 1.9-2.9-5.3 3.0-0.7-0.8-7.1-10.4 0.0-9.8-3.4-1.8 -7.4-15.2-8.1 23 .3-0.5-6.4-3.0-4.3-4.5-12.5-2.0 2.8-6.8 104 91 96 123 102 106 106 101 104 91 94 106 104 113 102 108 97 105 106 97 103 99 105 112 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0. 00 0.00 0.00 0i00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 6.30 2.57 2.89 2.87 4 .33 6.83 5.02 5.79 5.81 5.79 5.89 5.55 6.00 6.07 6.24 6.33 6 .63 6.68 7.14 6.92 6.93 7.22 7.20 7.28 25 I 26 S 27 t 28 t 29 t 30 t 31 t 32 t 33 t 34 t 35 36 t 37 38 t 39 t 40 t 41 t 104 i1 104 103 108 112 107.79 102 10.6, 1*08 109..109 112 106 96 107 0-.00 8.92 0.00 7.44 0.00 7.48 0.00 9.73 0.00 7.97 0.00 8.15 0.00 8.33 00.00. 8.63 Q*00 0 8.s5 0.00 "8. 70-.00 Q 8.16 0.00 #.6. 84 0.00 9.37 0.00 9.01 0.00 .96 0.00 .9 18 0 .o t .30 Continuing Calibration Summary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 3 Sample: EF2508-CC249 1 Lab FilelD: F47469.1)42 43 44 45 46 47 t t t t t t Caprolactam Hexachlorobutadiene 4-Chloro-3-methylphenol 2-Methylnaphthalene 1-Methylnaphthalene Dimethylnaphthalene 0.124 0.185 0.278 0.683 0.662 0.580 0.132 0.202 0.312 0.721 0.690 0.628-6.5-9.2-12.2-5.6-4.2-8.3 100 114 110 107 106 109 0.00 0.00 0.00 0.00 0.00 0.00 9.90 9.40 10.40 10.54 10.78 12.01 48 1 Acenaphthene-dlo 1.000 1.000--------------------- True 49 t Hexachlorocyclopentadiene 50.000-----------------------. AvgRF 50 t 2,4,6-Trichlorophenol 0.384 51 t 2,4,5-Trichlorophenol 0.424 52 S 2-Fluorobiphenyl 1.529 53 t 2-Chloronaphthalene 1.212 54 t Biphenyl 1.662 55 t 2-Nitroaniline 0.307 56 t Dimethylphthalate 1.255 57 t Acenaphthylene 1.935----------------------- True 58 t 2,6-Dinitrotoluene 25.000 Calc.46.321 CCRF 0.399 0.433 1.526 1.204 1 .642 0.381 1.291 1 .971 Calc.27.049 0.0 110 0.00 13.00% Drift ------------ 7.4 109 0.00 11.08 Dev-3.9-2.1 0.2 0.7 1.2-24 .1#-2.9-1.9 110 108 109 108 122 110 108 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 11.31 11.43.11.48 11.65 11.66 12.03 12.58 12.63% Drift ------------- -8.2 117 0.00 12.'71-------------------- AvgRF CCRF 59 t 3-Nitroaniline 0.306 0.321 60 t Acenaphthene 1.229 1.227% Dev-4.9 0.2% Drift-14.2 104 0.00 13.03 110 0.0 0 13.07 136 0.00 13.28----------------------- True 61 t 2,4-Dinitrophenol 50.000----------------------- AvgRF 62 t 4-Nitrophenol 0.164 63 t Dibenzofuran 1.683------------ ------- ---- T ru e 64 t 2,4-Dinitrotoluene 25.000----------------------- AvgRF 65 2,3,4,6-Tetrachlorophenol 0.308 66 t Diethylphthalate 1.225 67 t Fluorene 1.319 68 t 4-Chlorophenyl-phenylethe 0.676 69 t 4-Nitroaniline 0.285 Calc.57.114 CCRF 0.161 1.694 Caic.27.391 CCRF 0.337 1.286 1.351 0.694 0.273% Dev --1.8 104-0.7 Ill 0.00 13.64 0.00 13.46% Drift-9.6% Dev-9.4-5.0-2.4-2.7 4.2 116. 0.00 13.64 112 0.00 13.91 112 0.00. 14.28 110 0.00 14.28 112 0.00 14.34 91 .0.00 14.50 70 I Phenanthrene-dli 1.000 1.000 0.0 112 0.00 16.48----------------------- True 71 t 4,6-Dinitro-2-methylpheno 25.000 72 73 74 75 76 77 78 79 t t t S t t t t----------------------- AvgRF Atrazine 0.117 n-Nitrosodiphenylamine 0.563 1,2-Diphenylhydrazine 0.739 2,4,6-Tribromophenol 0.087 4-Bromophenyl-phenylether 0.210 Hexachlorobenzene 0.212 Pentachlorophenol 0.144 Phenanthrene 1.185 Calc.28.693 CCRF 0.114 0.543 0.748 0.094 0.212 0.214 0.132 1.120% Dev 2.6 3.6-1.2-8.0-1.0-0.9 8.3 5.5% Drift --.. -......-14.8 141 0.00 .14.59.96 0".0"0 16 07 107 .0o0 14.66 1'3- 0.00 14.71 118 0.00 14.91 114 0.00 15.48 I16. 0.00 15.78 103 0.00 1.6 25 107 0 .1 .5 4 Continuing Calibration Summary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 3 of 3 Sample: EF2508-CC2491 Lab FileID: F47469.D 41, 80 8e 82 83 84 85 86 87 88 t t t t t I t t S Anthracene Carbazole Di-n-butylphthalate Fluoranthene Octadecane Chrysene-dl2 Benzidine Pyrene Terphenyl-d14 1.204 0.925 1.068 1.145 0.410 1.000 0.184 1.303 0.902 89 t 90 91 t 92 t 93 t----------------------- True Butylbenzylphthalate 25.000 Butyl stearate 25.000----------------------- AvgRF Benzo[a)anthracene 1.139 3,3'-Dichlorobenzidine 0.329 Chrysene 1.171----------------------- True 94 t. bis(2-Ethylhexyl)phthalat 25.000 1.154 0.897 1.100 1.160 0.454 1.000 0.109 1.259 0.904 Caic.24.213 26.590 CCRF 1.138 0.344 1.143 Caic.23.048 CCRF 1.000 Caic.23.034 CCRF 1.780 1.790 1.612 Ca1c.24.156 23.837 23.729 CCRF 0.710 4.2 3.0-3.0-1.3-10.7 0.0 40.8#3.4-0.2% Drift 3.1-6.4% Dev 0.1-4.6 2.4 107 103 108 III 121 113 53 108 112 106 109 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0 00 0.00 0.00 21.18 0.00 21.29 11 0.00 22.00 107 0.00 22.03 ill 0.00 22.07% Drift ------------ 7.8 101 0.00 22.28% Dev 0.0 ill 0.00 24.35 16.64 17.10 18.19 19.27 16.48 22.03 19.65 19.71 20.1395 I----------------------- AvgRF Perylene-d12 1.000..--------------------- True 96 t Di-n-octylphthalate 25.000&av 97 98 99 t t t----------------------- AvgRF Benzo [b] fluoranthene
- 1. 677 Benzo [k] fluoranthene
- 1. 792 Benzo [a] pyrene 1,.547-----------------------
True Indeno[i,2,3-cd])pyrene 25.000 Dibenz (a,h) acridine 25.000 Dibenz [a, h) anthracene 25.000% Drift 7.9% Dev-6.1 0.1-4.2% Drift 3.4 4.7 5.1 99 0.00 23.26 113 0.00 23.76 110 0.00 23.80 112 0.00 24.26 115 0.00 26.33 114 0.00 25.87 113 0.00 26.36 100 t 101 t 102 t----------------------- AvgRF 103 t 7,12-Dimethylbenz(a)anthr 0.726 104 t 3-Methylcholanthrene
True 105 t Benzo[g,h,ilperylene 25.000% Dev ------------- 2.2 102 0.00 23.79---------- NA ---------- Caic.24.439% Drift ------------ 2.2 119 0.00 26.89 (#W = Out of Range F47469.D MF2491.M SPCC's out = 0 CCC'S out 0 Sat Jan 08 13:01:11 2005ý RPT!iii Continuing Calibration Summary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page I of 3 Sample: EF2509-CC2491 Lab FileID: F47510.D Evaluate Continuing Calibration Report Data File C:\MSDCHEM\I\DATA\EF2509\F47510.D Vial: Acq On 10 Jan 2005 9:20 am Operator: Sample CC2491-25 Inst Misc : OP19067,EF2509 Multiplr: MS Integration Params: LSCINT.P 2 NINAP MSF 1.00 Method Title Last Update Response via Min. RRFMax. RRF Dev C:\MSDCHEM\I\METHODS\MF2491.M (RTE Integrator) Semi Volatile Extractables by GC/MS Sat Jan 08 09:45:35 2005 Multiple Level Calibration 0.050 Min. Rel. Area : 48% Max. R.T.. Dev 0.50min 20% Max. Rel. Area : 200%Compound AvgRF CCRF%Dev Area% Dev(min)R.T. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 1,4-Dichlorobenzene-d4 1,4-Dioxane Pyridine N-Nitrosodimethylamine 2-Fluorophenol Indene Cumene Phenol-d5 Phenol Aniline bis(2-Chloroethyl)ether Benzaldehyde 2-Chiorophenol Decane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Benzyl alcohol 1,2-Dichlorobenzene Acetophenone 2-Methylphenol 2,2'-oxybis(a-Chloropropa 3&4-Methylphenol n-Nitroso-di-n-propylamin Hexachloroethane Naphthalene-d8 Nitrobenzene-d5 Nitrobenzene Quinoline Isophorone 2-Nitrophenol 2,4-Dimethylphenol Benzoic acid bis(2-Chloroethoxy)methan 2,4-Dichlorophenol 1,3.,5-Trichlorobenzene 1,2,4-Trichlorobenzene 1,2,3-Trichlorobenzene alpha-Terpineol Naphthalene 4-Chloroaniline 2,3-Dichloroaniline 1 .000 0.676 1 .640 0.538 1 .395 2.466 3 .153 1 .679.1 .833 2 .110 1.312 0 .351 1.399 1.280 1 .554 1.588 0.903 1.470 1.880 1.250 0.450 1.308 0.780 0.512 1 .000 0,.379 0.175 0.669 0.622 0 .171 0 .332 0.236 0.386 0.267 0.337 0 .324 0 .310 0.265 1 .061 0 .423 0.323 1.000 0.625 1.541 0.593 1.376 2.566 3.320 1.619 1.898 1.749 1.489 0.623 1.424 1.507 1.549 1.636 0.866 1.536 1.961 1.234 0.467 1.339 0.881 0.557 1.000 0.416 0.182 0 .687 0.697 0 192 0 .358 0.192 0.400 0.285 0.356 0.344 0.333 0.312 1.085 0.368 0.357 0.0 7.5 6.0-10.2 1.4-4.1-5.3 3.6-3.5 17.1-13.5-77. 5 #-1.8-17.7 0.3-3.0 4.1-4.5-4.3 1.3-3.8-2.4-12.9-8.8 0.0-9.8-4. 0-2.7-12.1-12.3-7. 8 18.6-3.6-6.7-5.6-6.2 -7.4-17.7-2.3 13.0-10.5 125 119 114 139 122 126 130 117 123 98 138 131 123 143 122 128 114 128 125 118 127 120 133 132 123 131 123 122 133 129.126"99 124 126 131 1ý32 132 139 126.102 131 0.00-0.12-0.11-0.09 0.00 0.00 0.00-0.01.0.00 0.00 0.00 0.00 0.00 0.00 0. 00 0.00 0.00 0.00 0 .00 0.00 0 .00 0 .00 0.00 0 .00 6.30 2.45 2.78 2.78 4.33 6.83 5.02 5.78 5.80 5.79 5 .89 5.55 5.99 6 .07 6 .23 6.33 6 .64 6.68 7 .14 6 .92 6.93 7 .22 7.20 7 .28 25 I 26 S 27 t 28 t 29 t 30 t 31 t 32 t 33 t 34 t 35 36 t 37 38 t 39 t 40 t 41 t 0.00 8.92*0.00 7.44'0.00 7.48 0.01 9.74 0.00, 7.97 0.00 8.15 0 .00 8.32 0 82" " 8.65 0.O0 8.50*0- 00 .8.70' 00," .8..17*-0 -.00. 8.84 0.00 9.37 0.00 9.01 0.00 8.96 0.00 9.19 0 0oJ, .30 Continuing Calibration Summary Job Number: N86261 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 2 of 3Sample: EF2509-CC2491 Lab FilelD: F47510.D 42 43 44 45 46 47 t t t t t t Caprolactam Hexachlorobutadiene 4-Chloro-3-methylphenol 2-Methylnaphthalene 1-Methylnaphthalene Dimethylnaphthalene
- 0. 124 0.185 0.278 0.683 0 .662 0 .580 0.143 0.208 0.313 0.732 0.728 0.645-15.3-12.4-12.6-7.2-10.0-11.2 128 139 130 128 132 132 0.02 0.00 0.00 0.00 0.00 0.00 9.92 9.40 10.40 10.54 10.78 12.01 13.01 48 I Acenaphthene-dlO 1.000 1.000 0.0 133 0.00------------------
True 49 t Hexachlorocyclopentadiene 50.000 50 51 52 53 54 55 56 57 t t S t t t t t.................
AvgRF 2,4,6-Trichlorophenol 0.384 2,4,5-Trichlorophenol 0.424 2-Fluorobiphenyl 1.529 2-Chloronaphthalene 1.212 Biphenyl 1.662 2-Nitroaniline 0.307 Dimethylphthalate 1.255 Acenaphthylene 1 .935-----------------------
True 58 t 2,6-Dinitrotoluene 25.000----------------------- AvgRF 59 t 3-Nitroaniline 0.306 60 t Acenaphthene 1.229----------------------- True 61 t 2,4-Dinitrophenol 50.000----------------------- AvgRF 62 t 4-Nitrophenol 0.164 63 t Dibenzofuran 1.683------------------- True 64 t 2,4-Dinitrotoluene 25.000------------------- AvgRF 65 2,3,4,6-Tetrachlorophenol 0.308 66 t Diethylphthalate 1.225 67 t Fluorene 1.319 68 t 4-Chlorophenyl-phenylethe 0.676 69 t 4-Nitroaniline 0.285 Calc.41.968 CCRF 0.386 0.433 1.500 1.172 1.601 0.367 1.301 1.940 Calc.26.485 CCRF 0.279 1.209 Calc.51.973 CCRF 0.150 1.635 Caic.26.416 CCRF 0.334 1.322 1.322 0.675 0.256% Dev-0.5-2.1 1.9 3.3 3.7-19.5-3.7-0.3 130 132 133 129 128 143 134 130 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 11.31 11.43.11.48 11.65 11.67 12.04 12.58 12.63% Drift ------------ -5.9 140 0.00 12.71% Drift ------------ 16.1 119 0.00 11.08% Dev 8.8 1.6 110 0.01 13.04 131 0.00 13.07% Drift ------------ -3.9 147 0.00 13.28% Dev 8.5 2.9% Drift-5.7% Dev-8.4-7.9-0.2 0.1 10.2 117 0.00 13.63 130 0.00 13.46 136 0.00 13.64 135.139 131 132, 104 0.00 0.00 0.00 0.00 0.02 13.91 14.28 14.28 14.34 14.51 16.49 70 I Phenanthrene-dlO 1.000 1.000 0.0 132 0.00----------------------- True 71 t 4,6-Dinitro-2-methyapheno 25.000----------------------- AvgRF 72 t Atrazine 0.117 73 t n-Nitrosodiphenylamine 0.563 74 t 1,2-Diphenylhydrazine 0.739 75 S 2,4.6-Tribromophenol 0.087 Calc. % Drift -------27.528 -10.1 259 0.01 14.60 CCRF 0.118 0.545 0.746 0.094 0.217 0.228 0.141 1.127% Dev-0.9 3.2-0.9-8.0-3.3-7.5 2.1 4.9 76 77 78 79 t t t t 4-Bromophenyl-phenylether Hexachlorobenzene Pentachlorophenol Phenanthrene 118 0:00 .16.07 127.0.00 14.66 133 o0. 00 .14.71 138 0.00 14.91 137 0.00 25.48 147 0.00 15.78 129 0.00 16.26 128 .0.210 0.212 0.144 1 .185 Continuing Calibration Summary Job Number: N86261Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG-Salem, Artificial Island, Salem, NJ Page 3 of 3Sample: EF2509-CC2491 Lab FileID: F47510.D 80 81 82 83 84 85 86 87 88 t t t t t I t t S Anthracene Carbazole Di-n-butylphthalate Fluoranthene Octadecane Chrysene-d12 Benzidine Pyrene Terphenyl-d14 1.204 0.925 1.068 1.245 0.410 1.000 0.184 1.303 0.902 1.191 0.841 1.221 1.199 0.482 1.000 0.081 1.281 0.924 Calc.26.473 28.834 CCRF 1.142 0.312 1.162 Calc, 26.593 1.1 130 9.1 114-14.3'.. 141-4.7 135-17.6 151 0.0 138 56.0# 48 1.7 134-2.4 139 0.00 0.01 0.00 0.0o 0.00 0.00 0.02 0.00 0.00 16.64 17.11 18.19 19.27 16.48 22.03 19.67 19.72 20.14----------------------- True 89 t Butylbenzylphthalate 25.000 90 Butyl stearate 25.000% Drift-5.9-15.3% Dev-0.3 5.2 0.8 142 0.00 '21.18 143 0.00 21.29 136 0.00 22.00 118 0.01 22.04 138 0.00 22.08 91 92 93 t t t Benzofa]anthracene 3,3'-Dichlorobenzidine.Chrysene AvgRF 1.139 0.329 1.171----------------------- True 94 t bis(2-Ethylhexyl)phthalat 25.000----------------------- AvqRF 95 1 Perylene-d12 1.000----------------------- True 96 t Di-n-octylphthalate 25.000%Drift ---6.4 142 0.00 22.28 CCRF % Dev 1.000 0.0 132 0.00 24.36 to 97 98 99 t t t Benzo [b] fluoranthene Benzo (k] fluoranthene Benzo [a] pyrene AvgRF 1.677 1.792 1.547 Calc.28.270 CCRF 1.781 1.805 1.609 Calc.25.239 25.163 25.119 CCRF 0.703 100 t 101 t 102 t% Drift-13.1 146 0.00' 23.26---------------
True Indeno[1,2,3-cdJpyrene 25.000 Dibenz(a,h)acridine 25.000 Dibenz[a,hJanthracene 25.000% Dev-6.2-0.7-4.0% Drift-1.0-0.7-0.5% Dev 3.2 134 0.00 23.76 131 0.00 23.80 133 0.00 24.26 143 0.00 26.34 144 0.00 25.88 142 0.01 26.37 120 0.00 23.?9-----------------------
AvgRF 103 t 7,12-Dimethylbenz(a)anthr 0.726 104 t 3-Methylcholanthrene
True 105 t Benzo[g,h,i]perylene 25.000---------- NA ---------- Calc.24.991% Drift 0.0 145 0.01 26.90 (4) = Out of Range F47469.D MF2491.M SPCC's out = 0 CCC's out 0 Mon Jan 10 10:00:14 2005 RPT1 w Data File C:\MSDCHEM\!\DATA\EF2509\F47512.D Acq On 10 Jan 2005 10:31 am Sample : N86261-I Misc : oP19045,EF2509,940 MS Integration Params: LSCINT.P Quant Time: Jan 1011:12:14 2005 Qu Vial: Operator: Inst Multiplr: 4 NINAP MSF 1.00 ant Results File: MF2491.RES nt Method wtle Last Update Response via DataAcq Meth C:\MSDCHEM\IMETHODS\MF2491.M (RTE Integrator) Semi Volatile Extractables by GC/MS Sat Jan 08 09:45:35 2005 Initial Calibration MF2491 Internal Standards R.T. QIon Response Conc Units Dev(Min)......................................---------------- -- -- -- ................1) 1,4-Dichlorobenzene-d4 6.30 152 297550 40.00 ppb 0.00 25) Naphthalene-d8 8.91 136 1216250 40.00 ppb 0.00 48) Acenaphthene-dlO 13.00 164 663970 40.00 ppb 0.00 70) Phenanthrene-diG 16.48 188 1182796 40.00 ppb 0.00 85) Chrysene-d12 22.03 240 1161702 40.00 ppb 0.00 95) Perylene-d12 24.35 264 734866 40.00 ppb 0.00 System Monitoring Compounds 5) 2-Fluorophenol Spiked Amount 50.000 8) Phenol-d5 Spiked Amount 50.000 26) Nitrobenzene-d5 Spiked Amount 50.000 52) 2-Fluorobiphenyl Spiked Amount 50.000 75) 2,4,6-Tribromophenol Spiked Amount 50.000 q8) Terphenyl-d14" Spiked Amount 50.000 Target Compounds 4.31 112 225765 21.75 Recovery 5.79 99 183381 14.68 Recovery =7.44 82 439761 38.16 Recovery =11.48 172 884815 34.87 Recovery =14.91 330 111837 43.55 Recovery 20.13 244 1088136 41.54 Recovery =ppb -0.02 43.50%ppb .0.00 29.36%ppb 0.00 76.32%ppb 0.00 69.74%ppb 0.00 87.10%ppb 0.00 83.08%Qvalue (6 (t) = qualifier out of range (m) = manual integration (+ = signals summed P6-7ý I? r) W L- M 4 0m 1 11-I' .11-O rAnr, Data File C:\MSDCHEM\I\DATA\EF2509\F47512.D Vial: 4 Acq On : 10 Jan 2005 10:31 am Operator: NINAP Sample : N86261-1 Inst : MSF Misc OP19045,EF2509,940 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Time: Jan 10 11:13 2005 Quant Results File: MF2491.RES pMethod C:\MSDCHEM\1\METHODS\MF2491.M (RTE Integrator) Title :Semi Volatile Extractables by GC/MS Last Update Sat Jan 08 09:45:35 2005 Response via Initial Calibration ............ IAhi mrrinr'a 220000D 2100000 2000000 19P00000 180000c 1700006 1600000 1500000 1400000 00 300 120000 1100000 10000[900000 800000 700000 600000 50DO 400000 300000 200000 V00000 0 tme-->1 -n C -i F47 512 ... ... .... ... .. ..... ...... ......... .. ..... 6 d 6,.-C-U)£k U-, c a U).-7 U)If)0 Co 19 C a-K LJ-~-,L 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 r) ?,/. P)4 QI M V.,_ .-I1A 1 1 .1.9 r A~ ? DýOro I~n Data File : C:\MSDCHEM\I\DATA\EF2509\F47513.D Acq On 10 Jan 2005 11:07 am Sample : N86261-2 Misc : oP19045,EF2509,900 MS Integration Params: Quant Time: Jan 10 12:12:34 2005 Qu Vial: 5 Operator: Inst Multiplr: NINAP MSF 1.00 ant Results File: MF2491.RES L wnt Method Title Last Update Response via DataAcq Meth C:;\MSDCHEM\I\METHODS\MF2491,M (RTE Integrator) Semi Volatile Extractables by GC/MS Sat Jan 08 09:45:35 2005 Initial Calibration MF2491 Internal Standards R.T. QIon Response Conc Units Dev(Min)1)25)48)70)85)95)1,4-Dichlorobenzene-d4 Naphthalene-d8 Acenaphthene-dl0 Phenanthrene-dl0 Chrysene-di2 Perylene-dl2 6.30 8.92 13.01 16.49 22.03 24.35 152 136 164 188 240 264 291001 1200521 650226 1152209 1089300 660811 40.00 40.00 40.00 40.00 40.00 40.00 ppb ppb ppb ppb ppb ppb 0.00 0.00 0.00 0.00 0.00 0.00 System Monitoring Compounds 5) 2-Fluorophenol Spiked Amount 50.000 8) Phenol-d5 Spiked Amount 50.000 26) Nitrobenzene-d5 Spiked Amount 50,000 52) 2-Fluorobiphenyl Spiked Amount 50.000 75) 2,4,6-Tribromophenol Spiked Amount 50.000 Q8) Terphenyl-d14 4w 3piked Amount 50.000 Target Compounds 39) Naphthalene
- 45) 2-Methylnaphthalene
- 60) Acenaphthene
- 63) Dibenzofuran
- 67) Fluorene 83) Fluoranthene
- 87) Pyrene 4.32 112 233505m/,/
23.01 Recovery 5.79 99 192794 15.78 Recovery =7.44 82 446357. 39.24 Recovery =11.48 172 909539 36.60 Recovery =14.91 330 124389 49.72 Recovery 20.14 244 1138860 46.36 ppb -0.01 46.02%ppb 0.00 31.56%ppb 0.00 78.48%ppb 0.00 73 .20%ppb 0.00 99.44%ppb 0.00 92.72%Recovery 8.96 10.54 13 .07 13.46 14.28 19.27 19.72 128 142 153 168 166 202 202 112424 33095 11496m/17558 27862 29694 30572 3.53 1.61 0.58 0.64 1.30 0.900. 86 ppb ppb ppb ppb ppb ppb ppb Qvalue 97 98 94 99 95 97'V (4) = qualifier out of range (m) = manual integration (+) = signals summed Data File C:\MSDCHEM\I\DATA\EF2509\F47513.D Via!: 5 Acq On 10 Jan 2005 11:07 am Operator: NINAP Sample : N86261-2 Inst : MSF Misc oP19045,EF2509,900 Multiplr: 1.00 MS Integration Params; LSCINT.P Quant Time: Jan 10 12:14 2005 Quant Results File: MF2491.RES
- Method C:\MSDCHEM\l\METHODS\MF2491.M (RTE Integrator)
Title Semi Volatile Extractables by GC/MS Last Update : Sat Jan 08 09:45:35 2005 Response via : Initial Calibration 2bundanc lIC: F47513.D I28O0O 2700000 260000D 250000 2400D 2300000 220O 2100000 1900000 , 0.'180000C " 1700000 15000 1400000 1300000 1200000 E 800000 0 700000 600000 700000 U9, 600000 8.Sooo 200000 ,00000 u b 7-...ime--> _. 1600 _.... 1..0. 0 ........A.00 600T, m. ., 10.0 12.00 14.00c A >nn:VDI Data File : C:\MSDCHEM\l\DATA\EF2509\F47513.D Acq On 10 Jan 2005 11:07 am Sample : N86261-2 Misc : OP19045,EF2509,900 MS Integration Params: LSCINT.P Quant Time: Jan 10 12:12 2005 vial: Operator: Inst Multipir: 5 NINAP MSF 1.00 temp.res ant Results.File:
- chod Title Last Update Response via C:\MSDCHEM\I\METHODS\MF2491.M (RTE Integrator)
Semi Volatile Extractables by GC/MS Sat Jan 08 09:45:35 2005 Multiple Level Calibration LAbundance 50000 4000O Ion 112.00 (111.70 to 112.70): F47513.D Ion 64.00 (63.70 to 64.70): F47513,D}or o 6G.70i: F4T;.'5S.; 30000 20000 100 ,me--> 2..bundance 30000 4J32 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 60 2,80 3.00 3.20 3A40 3.60 3&80 Scan 363 (4.319 min): F47513.D 1" 2 20000'A, 39 549...... ......42 5 30 35 40 45 50 Abundance 3 504 5 S36 39 42 45 50 64 57 6 53.,I. 6,11 , 83 92 68 73 77 80. I, 86 95...., , I I r I I 1 '5'5 .6.0.... 65. 7o0 75 80 85 90 95 Scan 392 (4.474 rain): F45940.D (-373)...I .I ! 1 -i i 100 105 110 115 1 I 2 120 64 57 83 53.. 61., 68 73 77 80, 1 86 112 II 92 95 F -L4 I ... 1-1 _'_-_ýJ_, 1--, ' -1 30 35 40 4.550 55 60 65 70C: F'7E~t3.I~0 8590 95 100 105 110 115 1,0 I... -ý 30 35 40 45 50 55 60 65 7OC: F4M13.E80 85 90 95 100 105 110 115 120 (5) 2-Fluorophenol (S)4.32min (-0.011) 23.01ppb m response 233505 Ion E2>% Act%112.00 100 100 64.00 54.00 57.87 63.00 26.50 29.65 0.00 0.00 0.00'V 7v,-, , ,, 1. ? .c,") -,tin% TDD'T
- ... -~. *.., ~ 7~..OflJ.L' ~
- 4UL) V)¶8 Naphthalene Concen: 3.53 ppb RT: 8.96 min Scan# 1231 Ref5Q Delta R.T.Lab File: Acq: 10 Jan 0.00 min F47513.D 2005 11:07 am 39 7,4, 86 102.1 111'V.. ... .J .. ... L ..... ..... ... ....... ...... ... .. ...... ..... ..%%
11 I I I rm/z-->3O40 50 60 70 80 90 100110120130140150160170 Abundance Scan 1231 (8.956 min): F47513.D 136 Tgt Ion 128 129 127 Ion:128 Resp: Ratio Lower 100 12.7 0.0 13.5 0.0 112424 Upper 41.0 43.0 41 54 64 76 91 I.1 P ! .. r. ,,h1 ..l .i 108 127 .I. 1,17 : 1 46111 1,6 162 Abundance Ion 128.00 (127.70 to 128.70): F, 60000 Ion 12P.00 (128.70 to 129.70): F, tn n 127.00nl C.2 C t -i "!.f.6;:, JT~I~IIIIJIIT~ 1 IT~r p iii~piiriji TrrpI-T-r~pI~prT~T.pTrT.pI~Ii mrz-->30 40 50 60 70 09 10011031050160170 Abundance Subj Scan 1231 m8,s5 Tr): F4751S.D (-1i37 136 54 108 1271" 768 7 88 97; 118 ,' I 146 40000 3000C 20000 10000 8.96 8.90 9.00 9.10 42 162 1 0"n/z-->30 40 50 60 70 80 90 100110120130140150160170 tTme-->Abundance Ref50 ,,TTV2- ->Scan 1569 (10.762 min): F46940.D ,1559) (-)1.ý2#45 2-Methylnaphthalene Concen: 1.61 ppb RT: 10.54 min Scan# 1528 Delta R.T.Lab File: Acq: 10 Jan 0.01 min F47513.D 2005 11:07 3. 58, 7 89 101 126 am I l P '1 ~I 40 60 80 100 120 140 160 180 Abundance Scan 1528 (10.543, min): F47513.D 142 Ra 41 9 81 5 115i , ] ' I ~131i (. ] 10 5 ,", ,i.n 152 YPi5 ' ,nv.trr:6 Tgt Ion:142 Resp: Ion Ratio Lower 142 100 141 86.4 55.0 115 34.9 2.8 33095 Upper 115.0 62.8 180]j "0 40 6o 8o 166 120 140 16D 18 Abundance Sub50 S an 15 2,, '1.5 i ." -431' ..142 115 Abu.& Ion 142.00 (141.70 to 142.70): F.Ion i41,00(140.70 tO 141.70);80000 60000 40000 20000-.10.5 4 39 57 69 89 104.i,.79 131 160 176 40 60 80.100 20...0 .... 0 1...0 m....e- ..1.40 1060 108 40 60 80 100 120 10 160 180 M3me-->10.40 10.60 10.80q I', M Re :[5 C-.. ~ ~flJCflU.LJ ~~C.~JSflJ] ~U 1~3 1~ 1 'O Acenaphthene Concen: 0.58 ppb m RT: 13.07 min Scan# 2001Delta R.T. -0.01 min Lab File: F47513.D Acq: 10 Jan 2005 11:0ý am 76 nl 11ý* ., w"t ., , ..".'% , , ..................... .40 60 80 100 120 140 160 180 200'Abundance Raýs0 Scan 2001 (13.069 min-: F1175,13.0 41 153: 164 log i " " III-.2 .1 11 L 1175 185 208 Tgt Ion 153 Ion:153 Resp: Ratio Lower 100 152 50.8 17.0 77.0 154 88.1 61.6 121.8 11496 Upper Abundance Ion 153.00 (152.70 to 153.70): F, 100 r), -L.--' ' ' I ' ' I I I I I ý I ý ý I I I I .ý I I ý I I .I ..I ý I ..I I I ..ý I I .I ýTVz--> 40 60 80 100 120 140 160 180 200 Sub 50 rj in-vz-->S I, ein 20ý0'1 '.,,.06P nniM: --47510.D (-1?081, H 97 132 81.6.7 117, 39 186 8 6 4 20 ton 152.00 (151,T) to 152.70):)0 13.07)0)0)0 00 0 3'05' 13.10 210 40....I ....I .............6 '60 80 100 120 140 160 160 2 0 L .......463 Dibenzofuran Concen: 0.64 ppb RT: 13.46 min Scan# 2075 Ion 168.00 (167.7010 168 70), F, I o r. 3 0 0 3 2. 7 0 t o 13 0) ýi 13.46r 6 7 ý 1 'ý M WTý 1) & Q I W.'Purlpq0=ýý ý, Re Fluorene Concen: 1.30 ppb RT: 14.28 min Scan# 2227 Delta R.T. 0.00 min Lab File: F47513.D Acq: 10 Jan 2005 11:07 am CSO 806, ..3 10 12Liý 119 2 Ij I IL j 3? ~ 1 4 40 60 80 100 120 140 160 180 200 220 Scan 2227, (14.2771 mir;n: F,17513.0 166 81 95 Tgt Ion 166 165 167 Ion:166 Resp: Ratio Lower 27862 Upper 100 92.0 14.7 61.7 121.7 0.0 43.2 Abundance Ion 166.00 (165.70 to 166.70): F O150 5o0C 50c I0 on 165.00 (16-4.70 to 165.70): f 14.28 14.20 14.30 14.40 Time-->Abundance Scan 3282 (19.913 min): F46940.D (-3271)(-) 2'2 RefSO 101 38 65 .5 122 m'z--> 40 60 80 100 120 140 160 180 200 220 240 260 280#83 Fluoranthene Concen& 0.90 ppb RT: 19.27 min Scan#,3162 Delta R.T. 0.01 min Lab File: F47513.D Acq: 10 Jan 2005 11:07 am Abundance Ralto im'z-->Scan 3162 (t9.272 rnin): F47S13,D 202 Tgt Ion 202 1on:202 Ratio 100 Resp: 29694 Lower Upper 39K 55 91 7 -- i. 109 128 43 1 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance Sub 50 C.~t .-202 101 12..1 0,0 44.3 100 8.7 0.0 40.4 iAbundance Ion 202.00 (201.70 to 202.70): P, 20000 Ion 101.00 (1100.70c i0.70 F 15000 19.27 5000 Mfme--> 19.20 19,30 1940 101 61 86 ; 121 141156 176 226 253269 40rTT,, , I60 80 10 1 20 1 416 1 i,2,022 240 6 , 0, 28 40 60 80 100 120 4 160 180 200 ý22024'0-260 280 izz.;7A"Tr-,ý1 '4 T M7, AQ.Iq v Mn, .-r;. n I r) 1 ') -I ý, -f) r ') 0 W; vvrri Ref50 ok~dui o o i zIj.ziO io i ail). r&+O'dU.LI k-,54 I) k-)38 55 T5 ý ~122 150 175 Pyrene Concen: RT: 19.72 Delta R.T.Lab File: Acq; 10 Ja 0.86 ppb min Scan# 3245 0.01 min F47513.D In 2005 11:07 am 2 Resp: 30572 Lower Upper 0.0 46.4 0.0 43.0 I Wn/Z--> 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundanc(Ravi 0 Scan 3245 (1C.715 min): F47513.D 262 I 'Ii 91 115 3 3h, 157 175 ki 2224326 ., liiI.i , ' 2I... , Tgt Ion 202 101 100 Ion:20 Ratio 100 17.6 11,5 Abundance Ion 202,00 (201.70 to 202.70): F, 20000 Ion 101.00 0100.70 to 101.70): 5 1 cq w0.0* ~ vM 288 I t ., y IM .1"1 ,-`1.,1-- .N. r. W , , .". .- 1 -1.1 11, 1 .1 ... .. .I .. ý 6 ..g .. .I. I ...1 '..I ...I ..n-z- 0605,80 10 ~1ý0140 1 1 0 20 220 240 260 280 (Abundance Sub 0 trn/z-->Scan 3245 (9.71i5 min): Fe7513.D (-C) 50)202 15000 1 000ý19.72 19.60 19.70 19.80 19.90 101 50 75 .. i 500C r Time-->138 159174 226243 263 288., ...... ._ ..__40 60 80 100 120 140 160 180 200 220 240 260 280 koF v 14 '7 Cý 'I "Z M W. T7 1) A Q I V.?A-,1 .,t= 1 p', c nr nn T? IP ' Data File : C:\MSDCHEM\l\DATA\EF2508\F47474.D Acq On 8 Jan 2005 12:13 pm Sample : N86261-3 Misc : OP19045,EF2508,1000 MS Integration Params: LSCINT.P Q",nt Time: Jan 08 12:41:10 2005 Vial: Operator: Inst 7 NINAP MSF Multiplr: 1.00 ant Results File: MF2491.RES nt Method Title Last Update Response via DataAcq Meth C:\MSDCHEM\I\METHODS\MF2491,M (RTE Integrator) Semi Volatile Extractables by GC/MS Sat Jan 08 09:45:35 2005'Initial Calibration MF2491 Internal Standards R.T. QIon Response Conc Units Dev(Min)1)25)48)70)85)95)1,4-Dichlorobenzene-d4 Naphthalene-d8 Acenaphthene-dl0 Phenanthrene-dl0 Chrysene-d12 Perylene-d12 6.30 8.91 12.99 16.48 22.02 24.35 152 136 164 188 240 264 275454 1087924 579461 1029463 973213 601234 40.00 40.00 40.00 40..00 40.00 40.00 ppb ppb ppb ppb ppb ppb 0.00 0.00 0.00 0.00 0.00 0.00 System Monitoring Compounds 5) 2-Fluorophenol Spiked Amount 50.000 8) Phenol-d5 Spiked Amount 50.000 26) Nitrobenzene-d5 Spiked Amount 50.000 52) 2-Fluorobiphenyl Spiked Amount 50.000 75) 2,4,6-Tribromophenol Spiked Amount 50.000 1) Terphenyl-d14 spiked Amount 50.000 Target Compounds 4.32 112 186709 19.43 Recovery -5.80 99 153756 13.30 Recovery =7.44 82 372622 36.15 Recovery =11.48 172 764954 34.54 Recovery =14.91 330 98851 44.23 Recovery =20.14 244 1037287 47.27 Recovery =ppb 0.00 38.86%ppb 0.00 26.6.0%ppb 0.00 72.30%ppb 0.00 69.08%ppb 0.00.88.46%ppb 0.00 94.54%Qvalue Jv-, 7 (,I) = quali fier-out of range (in) =manual integration (+) = signals summed Data File C:\MSDCHEM\I\DATA\EF2508\F47474.D Acq On : 8 Jan 2005 12:13 pm Sample N86261-3 Misc : OPi9045,EF2508,1000 MS Integration Params: LSCINT.P Quant Time: Jan 10 9:41 2005 Vial: 7 Operator: NINAP Inst : MSF Multiplr: 1.00 ant Results File: MF2491.RES Method.Title Last Update Response via 22OOOO C:\MSDCHEM\I\METHODS\MF2491.M (RTE Integrator) Semi Volatile Extractables by GC/MS Sat Jan 08 09:45:35 2005 Initial Calibration TIC: F47474.D 2100000 2000000 1900000 1800000 1700000 1600000 1500000 1400000 o" a 1300000*12000 1100000 1000000 90000)! 800000 a;z, UZ.i..2 700000 600000 CC C7 (0 E'.7 50000C 40000C* 300000 200000% 00000"6.0 (0 K.22.00 24.00 26.00<~Ak y I\_K_ I .I', I V~fVV ~T'~ -r ~rm ~Time--> 4.00 6.00 8.00 10.00 12o00 14.00 16.00 18.00.....2.0,00.r247A7j n Mý,?AQI. Mm- .-Tý_ 1 n f)Q -/5 1 -1 '7
- ) i)Ocý V DIr"I Data File C:\MSDCHEM\I\DATA\EF2508\F47475.D Acq On : 8 Jan 2005 12:49 pm Sample N86261-4 Misc OP19045,EF2508,1000 MS Integration Params: LSCINT.PTime: Jan 08 13:17:14 2005 .Vial: Operator: inst Multipir: 8 , NINAP MSF 1.00 ant Results File: MF2491.RESMethod Title Last Update Response via DataAcq Meth C:\MSDCHEM\I\METHODS\MF2491.M. (RTE Integrator)
Semi Volatile Extractables by GC/MS Sat Jan 08 09:45:35 2005 Initial Calibration MF2491 Internal Standards R.T. QIon Response Conc Units Dev(Min)..........................................................................
- 1) 1,4-Dichlorobenzene-d4 6.30 152 268040 40.00 ppb 0.00 25) Naphthaiene-d8
.8.91 136 1062546 40.00 ppb 0.00 48) Acenaphthene-dl0 12.99 164 567538 40.00 ppb 0.00 70) Phenanthrene-dl0 16.48 188 990871 40.00 ppb 0.00 85) Chrysene-d12 22.03 240 929862 40.00 ppb 0.00 95) Perylene-d12 24.35 264 572690 40.00 ppb 0.00 System Monitoring Compounds 5) 2-Fluorophenol Spiked Amount 50.000 8) Phenol-d5 Spiked Amount 50.000 26) Nitrobenzene-d5 Spiked Amount 50.000 52) 2-Fluorobiphenyl Spiked Amount 50.000 75) 2,4,6-Tribromophenol Spiked Amount 50.000 8) Terphenyl-d14 Spiked Amount 50.000 Target Compounds 4.32 112 212331 22.71 Recovery =5.79 99 164941 14.66 Recovery 7.44 82 426336 42.35 Recovery =11.48 172 816966 37.67 Recovery 14.91 330 87573 40.71 Recovery =20.14 244 964776 46.01 Recovery ppb 0.00 45 .42%ppb 0.00 29.32%ppb 0.00 84.70%ppb 0.00 75. 34%ppb 0.00 81 .42%ppb 0.00 92 02%Qvalue 4.-(P) = qualifier out of range (m) = manual integration (+) = signals summed Data File : C:\MSDCHEM\I\DATA\EF2508\F47475.D Vial: 8 Acq On : 8 Jan 2005 12:49 pm Operator: NINAP Sample : N86261-4 Inst : MSF Misc : OP19045,EF2508,1000 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Time: Jan 10 9:41 2005 Quant Results File: MF2491.RES Method C:\MSDCHEM\I\METHODS\MF2491.M (RTE Integrator) Title :Semi Volatile Extractables by GCUMS Last Update : Sat Jan 08 09:45:35 2005 Response via Initial Calibration L~~.bundanceTIC T F47475.D -.- -.._ _1900000 1800000 1700000 1600000 1500000 6 1400000 1300000.0 -1200000 C. ._= .0'V1100000 4-1000000 900000 800000 700000 2 60000 I?N C.0 a 400000 200000 C-00W 21 4 2000000 2.0 Time--> 4.00 6.00 8.00 1000 12.00 14.00 1600 18.00 20.00 2200 240 26.00 woio c n m ,Aql V u,-)- . a 1 1 no-i * () 1) C; POt'rl Da-a Data File C:\MSDCHEM\1\DATA\EF2508\F47484.D Acq On 8 Jan 2005 6:12 pm Sample N86261-6 Misc 0P19045,EF2508,1000 MS Integration Params: LSCINT.P r int Time: Jan 08 18:40:09 2005 Qu vial: 17 Operator: NINAP inst : MSF Multiplr: 1.00 ant Results File: MF2491.RES
- ant Method Title Last Update Response via DataAcq Meth C:\MSDCHEM\1\METHODS\MF2491.M (RTE Integrator)
Semi Volatile Extractables by GC/MS Sat Jan 08 09:45:35 2005 Initial Calibration MF2491 Internal Standards R.T. QIon Response Conc Units Dev(Min)..........................................................................
- 1) 1,4-Dichlorobenzene-d4 6.31 152 262235 40.00 ppb 0.00 25) Naphthalene-d8 8.92 136 1023952 40.00 ppb 0.00 48) Acenaphthene-d10 13.00 164 548337 40.00 ppb 0.00 70) Phenanthrene-dlO 16.48 188 960822 40.00 ppb 0.00 85) Chrysene-d12 22.03 240 762285 40.00 ppb 0.00 95) Perylene-d12 24.35 264 320964 40.00 ppb 0.00 System Monitoring Compounds 5) 2-Fluorophenol Spiked Amount 50.000 8) Phenol-d5 Spiked Amount 50.000 26) Nitrobenzene-d5 Spiked Amount 50.000 ,52) 2-Fluorobiphenyl Spiked Amount 50.000 75) 2,4,6-Tribromophenol Spiked Amount 50.000'8) Terphenyl-d14 Spiked Amount 50.000 Target Compounds 4.34 112 221989 24.27 Recovery =5.80 99 176846 16.06 Recovery -7.44 82 432155 44.55 Recovery =11.48 172 890279 42.48 Recovery =14.91 330 100542 48.20 Recovery =20.14 244 958499 55.76 Recovery -ppb 0.00 48.54%ppb 0.01 32.12%ppb 0.00 89.10%ppb 0.00 84 .96%ppb 0.00 96.40%ppb 0.00 111.52%Qvalue I? I tV (4i) = qualifier out of range (m) manual integration
(+) = signals summed D=,.~ Data File : C:\MSDCHEM\I\DATA\EF2 1 508\F47484.D Vial: 17 Acq On :8 Jan 2005 6:12 pm Operator: NINAP Sample N86261-6 Inst : MSF Misc : OP19045,EF2508,1000 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Time: Jan 10 10:42 2005 1 Quant Results File: MF2491.RES 00 Method : C:\MSDCHEM\I\METHODS\MF2491.M (RTE Integrator) Title : Semi Volatile Extractables by GC/MS Last Update : Sat Jan 08 09:45:35 2005 Response via : Initial Calibration ]Abundance 210O S2t000000 1900000 1800000 1700O 1600 1500000 14000 I 1300000l 120000D 110=1000000 900000 80000 70000 C 600000 50000 400000 30000 20000 1, 100000..",, 47AP n~ , TIC; F47484.D ,-r c, <£..0.0.0)-z 0D.9V)03 E 02 (n.9.5~A/L ?d K K.IL 29 JL d(4.00 6.00 18,00 20.00'. ..106 24ý0C) 26.00............ ......... .....MT:1*)40j M in ')nn', Data File C:\MSDCHEM\I\DATA\EF2508\F47472.D Acq On 8 Jan 2005 11:01 am Sample OP19045-MBI Misc OP19045,EF2508,1000 MS Integration Params: LSCINT.Pý' nt Time: Jan 08 11:29:34 2005
- nt Method C:\MSDCHEM\I\MET1iODS\MF2491.M Title : Semi Volatile Extractables by Last Update : Sat Jan 08 09:45:35 2005 Response via : Initial Calibration DataAcq Meth : MF2491 Vial: Operator: Inst Multiplr: 5 NINAP MSF 2.00 ant Results File: MF2491.RES (RTE Integrator)
GC/MS Internal Standards R.T. QIon Response Conc Units Dev(Min)......................................... I)25)48)70)85)95)1,4-Dichlorobenzene-d4 Naphthalene-d8 Acenaphthene-d10 Phenanthrene-dl0 Chrysene-d12 Perylene-d12 6.30 8.91 12.99 16.48 22.02 24.35 152 136 164 188 240 264 225134 881061 461964 810039 746263 468309 40.00 40.00 40.00 40.00 40.00 40.00 System Monitoring Compounds 5) 2-Fluorophenol Spiked Amount 50.000 8) Phenol-d5 Spiked Amount 50.000 26) Nitrobenzene-d5 Spiked Amount 50.000 ,52) 2-Fluorobiphenyl Spiked Amount .50.000 75) 2,4,6-Tribromophenol Spiked Amount 50.000 3) Terphenyl-d14 tSpiked Amount 50.000 Target Compounds 4.33 112 235289 29.97 Recovery =5.79 99 188254 19.92 Recovery 7.44 82 436986 52.35 Recovery 11.48 172 849223 48.10 Recovery 14.91 330 90255 51.32 Recovery =20.13 244 892990 53.,07 Recovery =ppb ppb ppb ppb ppb ppb ppb 59.94%ppb 39.84%ppb 104.70%ppb 96.20%ppb 102.64%ppb 106.14%0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Qvalueýý, ell, 11to 0.ý~3G (l) = qualifier out of range (m) = manua.l integration (+) = signals summed Data File C:\MSDCHEM\l\DATA\EF2508\F47472.D Acq On 8 Jan 2005 11:01 aml Sample oP19045-MBI Misc OP19045,EF2508,1000 MS Integration Params: LSCINT.P Quant Time: Jan 10 9:39 2005 1 Qu Vial-Operator: Inst Multipir: 5 NINAP MSF 1.00 ant Results File: MF2491.RES ' Method Title Last Update Response via C:\MSDCHEM\1\METHODS\MF2491.M (RTE Integrator) Semi Volatile Extractables by GC/MS Sat Jan 08 09:45:35 2005 Initial Calibration I 11l: F4747D2.180000C 170000C 1600000 150000D 1400000 1300000 1200000 ,3m 0'3*0 U I 00000 1000000 6-a ('3.03 03-900000", M5 z 800000 700000 600000 50000C 40000C 30000C 20000C V 0 a 2 9 z E (.3 r-, 4 Na (3 c3.Time-->)00 4 I 7. -~ -*~ ~ 3 ~303~~3 ~*~*(~¶~03 ~ 33 3-. ~ 3. , 3- ~ -______________________________________________ 4.00 6.00 8.00 10.00 ,12.00 14.00 16.00 1 I .00 .I .1 8, 00 20.00.I , 22.00 24.00 2i. O0 ,---;1 1W 7147A^71) T) Mv,)6q1 W.W.- -I =, I I.'3i Pr01 p Imi Data File C:\MSDCHEM\I\DATA\EF2508\F47472.D Acq On : 8 jan 2005 11:01 am Sample OP19045-MBIMisc OP19045,EF2508,1000 MS Integration Params: LSCINT.P Vial: 5 Operator: NINAP inst : MSF multiplr: 1.00 nod C:\MSDCHEM\1\METHODS\MF2491.M (RTE Integrator) le : Semi Volatile Extractables by GC/MS Smoothing
- ON Filtering:
5 Sampling : 1 Min Area: 1000 Start Thrs: 0.05 Max Peaks: 125 Stop Thrs : 0 Peak Location: TOP Area counts If leading or trailing edge < 100 prefer < Baseline drop else tangent >Peak separation: 5 Signal : TIC peak 1 2 3 4 5 6 7 8 9 10 R.T. first max min scan scan 3.325 174 177 3.539 214 217 3.646 235 237 3.838 265 273 3.876 276 280 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 4.330 4.565 4.698 4 .805 5.355 5.558 5.660 5.793 6.301 6.696 7.017 7.161 7. 332 7 .444 7.962 8.085 8.342 8.758 8.913 9.298 9.335 10.719 10.794 11.478 11.825 348 408 433 453 5ý0 588 610 629 722 805 863 890 920 939 1043 1063 1111 1188 1215 1294 1299 1555 1570 1691 1765 1784 1793 1809 1909 1976 2038 2078 2218 365 409 434 454 557 595 614 639 734 808 868 895 927 948 1045 1068 1116 1194 1223 1295 1302 1561 1575 1703 1768 1787 1798 1812 1914 1987 2045 2079 2223 last scan 181 225 244 276 300 402 415 441 460 564 597 623 678 792 815 873 901 934 1008 1050 1069 1127 1199 1294 1299 1308 1570 1583 1765 1774 1793 1803 1823 1920 2038 2053 2089 2226 PK TY rBV5 rVB6 rVB5 rBV rVB2 rBV3 rVB6 rVB4 rVB4 rVB5 rBV4 rVB6 rBV2 rBV rVB4 rVB6 rVB3 rBV4 rBV rVB3 rVB3 rBV rBv rBV rVV3 rVB5 rBV3 rVB2 rBV rVB4 rVB4 rVB4 rVB5 rVB2 rBV2 rVB2 rVB3 rBV3 peak height 955 1579 864 43179 51404 150481 1323 1077 907 588 990 923 130697 409934 1291 702 517 608 389979 1058 989 5819 4190 664596 2374 1064 1823 3648 1032295 1576 1154 2376 3047 452 896023 9478 881 1357 corr.area 1387 3385 1178 79097 182779 779806 1738 1794 12.82 1167 1508 1966 514816 1413511 2358 1278 1157 1322 1269929 1140 1036 8349 5783 1810597 2325 1825 4234 5139 2462653 2727 1539 3463 4956 1090 1988014 14320 1923 1608 corr.% max.0,05%0.13%0.04%2.96%6 .85%29.23%0. 07%0.07%0.05%0.04%0.06%0.07%19.30%52.98%0.09%0.05%0.04%0.05%47.60%0.04%0.04%0.31%0.22%67.86%0.09%0.07%0.16%0.19%92.30%o0.10%0.06%0.13%0.19% 0.04%74.51%0.54%0.07%0.06%% of total 0.007%0.017%0.006%0.390%0.902%3.847%0.009%0.009%0.006% 0.006%0.007%0.010%2.540%6.974%0.012%0.006%0.006%0.007%6.265%0.006%0.005%0.041%0.029%8.933%0.011%0.009%0.021%0.025%12.150%0.013%0.008%0.017%0. 024%ý0.005%9.808%0.071%0.009% 0.008%31 11.926 32 11.985 33 12.060 34 12.605 3 6- 2.995 36 13.30537 13 .486 38 14 .256',d '7 A '? ' ) r) V, 'P ? A Q I M Mlý .1 ) f )-ý0-' )00r )DT13ý I 4U 14..9U'41 15.180 42 15.228 43 15.393 44 15.458 45 15.564 8w16 .211 47 16.478 48 16.772 49 16.911 50 17.605 51 18.027 52 18.193 53 18.412 54 18.460 55 18.893 56 19.138 57 19.299 58 20.020 59 20.132 60 20.730 61 21.216 62 21.564 63 21.793 64 21.916 65 21.932 66 22.023 67 22.280 6§ 2 .333 6%w ;2 402 70 22.504 71 22.547 72 22.589 73 22.643 74 22.702 75 22.734 76 22.808 77 22.824 78 22.979 79 23.022 80 23.092 81 23.118 82 23.252 83 23.348 84 23.433 85 23.578 86 23.610 87 23.722 88 23.754 89 23.834 90 23.941 93 .962 9 L 4.010 93 24.059 94 24.112 95 24.160 2333 2345 2394 rBV2 27107'5 845385 31.69%2394 2400 2429 2445 2461 2581 2629 2691 2714 2840 2924 2954 2995 3007 3089 3126 3160 3294 3312 3427 3523 3584 3630 3653-3659 3669 3719 3730 3742 3765 3771 3782 3788 3801 3808 3821 3825 3852 3861 3873 3880 3900 3921 3938 3965 3971 3988 4000 4008 4033 4038 4047 4054 4067 4076 2396 2405 2436 2448 2468 2589 2639 2694 2720 2850 2929 2960 3001 3010 3091 3137 3167 3302 3323 3435 3526 3591 3634 3657 3660 3677 3725 3735 3748 3767 3775 3783 3793 3804 3810 3824 3827 3856 3864 3877 3882 3907 3925 3941 3968 3974 3995 4001 4026 4036 4040 4049 4058 4068 4077 2400 2410 2441 2452 2479 2604 2691 2703 2726 2854 2935 29 68 3007 3020 3098 3149 3171 3312 3360 3439 3530 3597 3640 3659 3662 3705 3730 3738 3758 3771 3779 3788 3797 3808 3815.3825 3829 3861 3867 3878 3885 3912 3928 3946 3970 3978 3998 4006 4017 4038 4041 4051 4059 4071 4080 rVV2 rVB4 rBV3 rBB2 rBB2 rBB3 rBV2 rVB4 rVB2 rBV3 rVB3 rBV2 rBV3 rVB3 rBV3 rBV3 rVB2 rBB3 rBV2 rBV2 rVB r BV3 rBV4 rBV2 rBV2 rBV rVB5 rVB5 rBV5 rVB4 rVB6 rVB4 rBV6 rVV5 rVB5 rBV3 rVV3 rVB7 rBV4 rVB4 rBV3 rBV7 rBV5 rBV5 rBV4 rVB5 rBV8 rVV5 rVV7 rVB4 rBV2 rVB3 rBV4 rBV3 rBV3 1317 0 O9 839 11218 3892,2 434,3 8131913 134ý3 166,4 1364 2363 12012 334 6 1349 967 8660 1265 5920 1553461 941 861 2993 1337 1145 1368 1122600 1515 lO3O 4782 14772 1219 1514 2795 1079 1225 1912 1511 1994 16 16 1310 104 5 2402 1973 1568 18413 1538 3567 1723 1835 1900 1893 1868 2312 1578 2112 1669 1513 1250 1420 60624 11923 2090094 2914 3471 2298 3473 2688 6659 2517 1337 24542 1518 13074 2668076 1636 1186 5585 2946 1196 1090 2043421 1933 1154 13554 1493 2088 1537 3891 1665 1975 1644 1214 2358 1820'1533 1157 5732 2594 1753 1336 2186 7414 2508 3785 1614 1484 1209 2510 1470 1721 0.06%0.06%0.05%0.05%2.27%0.45%78.34%0.11%0.13%0.09%0.13%0.10%0.25%0.09%0.05%0.92%0.06%0.49%100.00%0.06%0.04%0.21% 0.11%0.04%0.04%76.59%0.07%0.04%0.51%0.06%0.08%0.06%0.15%0.06%0.07%0.06%0.05%0.09%0.07%0.06%0.04%0.21%0.10%0.07%0.05%0.08%0.28%0.09%0.14%0.06%0.06%0.05%0.09%0.06%0.06%4.171%0.008%0. 007%0.006%0.007%0.299%0.059%10.312%0.014%0.017%0.011%0.017%0.013%0.033%0.012%0.007%0.121%0.007%0.065%13.163%0.008%0.006%0.028%0.015%0.006%0.00.5%10.082%0.010%0.006%0.067% 0.007%0.010%0.008%0.019%0.008%0.010%0.008%0.006%0.012%0.009%0.008%0.006%0.028%0.013%0.009%0.007%0.011%0.037%0.012%0.019%0.008%0.007%0.006%0.012%0.007%0.008%47 T7 h 71r, -Ic M I V Y., .,T=n -in o a. ýlo .,ýl )nný 96 97 98 99 LO0 24 .240 24.352 24 .801 24 .849 24.865 LOJ 24.961 1.0 1 25.036 lo0 25 138 104 25 .164 105 25.223 106 25.271 107 25.405 L08 25.442 L09 25.581 L10 25.640 Lll 25.854 L12 25.875 L13 26.258 L14 26.484 L15 26.537 L16 26.612 L17 26.671 L18 26.698 L19 26.804 L20 26.997 L21 27.077 L22 27.376 L23 27.488 L24 27.515-2E 7. 958 4089 4102 4196 4204 4208 4218 4238 4258 4264 4273 4283 4308 4314 4337 4352 4393 4396 4447 4509 4519 4533 4545 4551 4567 4607 4621 4676 4698 4702 4786 4092 4113 4197 4206 4209 4227 4241 4260 4265 4276 4285 4310 4317 4343 4354 4394 4398 4451 4512 4522 4536 4547 4552 4572 4608 4623 4679 4700 4705 4788 4094 4145 4199 4208 4212 4236 4244 4264 4267 4278 4288 4313 4319 4345 4357 4396 4402 4453 4516 4524 4538 4549 4560 4573 4610 4627 4682 4702 4709 4791 rBV4 rBV2 rBV2 rVB3 rBV3 rBV3 rBV5 rVB5 rBV2 rBV4 rBV4 rBV4 rVB4 rBV7 rVB3 rVB2 rBV5 rBV4 rBV6 rVV4 rBV4 rBV3 rVV8 rBV4 rBV2 rBV5 rEV5 rVB3 rBV5 rBV4 1773 785793 1640 1948 2082 2513 3444 2461 2267 1870 2812 3239 2010 2902 2114 2562 2525 2915 1581 1581 2762 2204 2215 2182 1900 1514 2074 2111 1994 2534 1777 1726509 1484 1739 1956 9628 3906 2876 1274 1893 2086 3355 2216 4507 1688 1529 3211 3183 1764 1588 2111 1960 4355 3290 1360 2070 2755 1523 3256 2579 0.07%64 .71%0.06%0.07%0.07%0.36%0.15%0.11%0.05%0.07%0.08%0.13%0.08%0.17%0.06%0.06%0.12%0.12%0.07%0.06%0.08%0.07%0.16%0.12% 0.05%0.08%0.10%0.06%0.12%0.10%0.009%.8.518%0.007%0.009%0.010%0.048%0.019%0.014%0.006%0.009%0.010%0.017%0.011%0.022%0.008%0.008%0.016%0.016% 0.009%0.008%0.010%0.010%0.021%0.016%0.007%0.010%0.014%0.008%0.016%0.013%Sum of corrected areas: 20268949.134'4 '7 A '7 ') n lrv ") 4 0 1 Mi mýn .,rp- in )r)nr, 3:ýOrrl LSC Report -Integrated Chromatogram File C:\MSDCHEM\l\DATA\EF2508\F47472.D Operator NINAP.Acquired : 8 Jan 2005 11:01 am using AcqMethod MF2491 Instrument
- MSF Sample Name: oP19045-MBI Misc Info : OPl9045,EF2508,1000 Vial Number: 5 Quant File :MF2491.RES (RTE Integrator) 11C: F47472.D Abundance 1400000 1200000 1000000 80000D 60000 400000 2000 0 tmmL--> 2.50 liC: F47472.D 8.91 6.30 7.44 3.3.4.. B1 5,36.5f1fK,, 6.70.7.rQ21 7.,8 .98,34 8.7k 1 , '. , ..,. .....! 1-, -r.'0 I I 4 6.00 I 7.0 7.. 0 8 ....
.... .I '90 ' 9 .5 1 0 I .0 I .0 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6 .50 7.00 7.50 8.00 8.50 9,00 9.50 10.00 10.50n i @Abundance 1400000 1200000 10000OO 800000 600000 400000 200000 0C,, Time--> 11.00"M1C: F47472.U 11.48 12.99 16.48'1 161.91 U tgB96 12.60 14.91 1I4290 L 573w 6 16.2 17.61 18.89.1S1.31 I 11.50 12.00 12.50 13.00 13.50 14.00 14.50 15.00 15.50 16.00 16.50 17.00 17.50 18,00 18.50 19.00 I I Abundance 140000D 1200000 1000000 800000 600000 40000 200000 20 TIC: F47472.D 13 22.02 24.35 20.73 _ :."C Time--> 19.50 I 20.00 20.50 21.00 21.60 22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 2-O27.00 27.50;1 A '7 6, '7 -) -,') "M"P?-/0 M mn, -,r) )nr)cý 1:?Drri V~ný /A Data File : C:\MSDCHEM\I\DATA\EF2508\F47472.D Vial: 5 Acq On 8 Jan 2005 11:01 am Operator: NINAP Sample 0P19045-MBI Inst : YISF Misc : oP19045,EF2508,1000 Multiplr: 1.00 MF Integration Params: LSCINT.P k nt Method : C:\MSDCHEM\I\METHODS\MF2491.M (RTE Integrator) tle : Semi Volatile Extractables by GC/MS Library : C:\DATABASE\NIST98.L Peak Number 1 2-Pentanone, 4-hydroxy-4-me... Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T.----------------------....7_ ------------------------------------------3.88 5.17 ppb 182779 1,4-Dichlorobenzene-d4 6.30 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 2-Pentanone, 4-hyd-roxy-4-methyl-. 116 C6H1202 000123-42-2 64 2 2-Pentanone, 4-hydroxy-4-methyl- 116 C6H1202 000123-42-2 36 3 Acetic acid, cyano-, 1,1-dimethy ... 141 C7HIIN02 001116-98-9 17 4 Acetic acid, 1,1-dimetbylethyl e ... 116 C6H1202 000540-88-5 9 Abundance Scan 280 (3.876 min): F47472.D (-276) (-) m/z 43.10 100 .0019 6OO43 59 500101 S1,83.60 3.80 4.00 4.20 5 I , I,.I .. ..... m/z 59.20 56.62%mvfz--> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 indance it1109755: 2-Pentanone, 4-hydrox,-4-methyl-5000 ... T .., ..3.6 3.8 .0 4.20 0m/z 101.20 24.99%51J 83 z_> _ o 20 30 40 50 60o708090100 110 12 10140 VAbundance f109755: 2-Penanone, 4-hydroxy-4-methyl-4ý3 3.60 3.80 4.00 4.20 m/z 58.15 1.7.25s-31 83,.1_Z--> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 4t19572: Acetic acid, cyano-, 1,1-dimethylethyi ester 3.60 3.80 4.00 4.20 m/z 41.10 9 54%5000 41 .68 B 5011A, 126 i 142.10 20 30 40 50 60 70 80 90 100 110 120 130 140 3.60 3.80 4.00 4.20:11 G )perator ID: NINAP Date Acquired: 8 Jan 2005 11:01 am)ata File: C:\MSDCHEM\I\DATA\EF2508\F47i472ýD lame: oP19045-MBI lisc: 0P19045,EF2508,!000 lethod: C:\MSDCHEMkI\METHODS\MF2491.M (RTE Integrator) Semi Volatile Extractables by GC/MSSearched: C:\DATABASE\NIST98.L I--Internal Standard---I TIC Top Hit name RT EstConc Units Response j# RT Resp Conci------------------------------------------------------------------------------ ý-Pentanone, 4-hy ... 3.88 5.2 ppb 182779 1 6.30 1413510 40.0-A6'71'7 n V 71 *? Q I N v.-, 'in )nnr, e-lardcopy
2.0 Automated
Report riM19 New Jersey LA UTEST.Laib c.ra to r ie s 04/05/05 f4v TeChnical Report for Arcadis Geraghty & Miller PSEG, Hancock's Bridge, NJ Accutest Job Number: N93379 Sampling Date: 03/15/05 Report to: Arcadis Geraghty & Miller 6 Terry Drive Newtown, PA 18940 ATTN: Brad Pierce Total number of pages in report: 122 ,11t ACCopo AU..... Test results contained within this data package meet the requirements of the National Environmental Laboratory Accreditation Conference and/or state specific certification programs as applicable."Vincent J. Puglese President Certifications: NJ(12129), NY(10983), CA. CT, DE, FL, IL, IN, KS. KY, LA, MA, MD, MI, MT, NC, PA, RI, SC, TN, VA. WV This report shall not be reproduced, except in its entirety, without the written approval of Accutesi Laboratories.New Jersey -2235 Route 130
- Dayton, NJ 08810
- tel: 732-329-0200
-fax: 732-329-3499 -http://www.accutest.com E1!i 1 of122 IRACCU IES I N93379 -5
- Table of Contents sections: Section 1: Sample Summ ary ...................................................................................................
3 Section 2: Case Narrative/Conform ance Summ ary ........................................................... 4 Section 3: Sample Results ........................................................................................................ 3.1: N93379-1: W ELL AY .............................................................................................. 5 3.2: N93379-2: W ELL X ................................................................................................... 10 3.3: N93379-3: W ELL AV ................................................................................................ 15 3.4: N93379-4: W ELL AVD ............................................................................................ 203.5: N93379-5: FB-031505 .............................................................................................. 25 3.6: N93379-6: TRIP BLANK ......................................................................................... 30 Section 4: Misc. Forms ............................................. 32 4.1: Chain of Custody ........................................................................................................ 334.2: Sample Tracking Chronicle ........................................................................................ 34 4.3: Internal Chain of Custody ...................................................................................... ....... 35 Section 5: GC/M S Volatiles -QC Data Sum maries .......................................................... 375.1: Method Blank Summary ......................................... 38 5.2: Blank Spike Summary ............................. .............. 40 5.3: M atrix Spike Summary .............................................................................................. 425.4: Duplicate Summary ..................................................................................................... 44 5.5: Instrument Perform ance Checks (BFB) ...................................................................... 46! 5.6: Internal Standard Area Summ aries ............................................................................ 48 5.7: Surrogate Recovery Summ aries .................................................................................... 49 5.8: Initial and Continuing Calibration Summaries .......................................................... 50 Section 6: GCC/MIS Volatiles-Raw Data ................................... 56 6 .1 : S am p les ........................................................................................................................... 5 7 6.2: M ethod Blanks ............................................................................................................ 70 Section 7: GCU M S Sem i-volatiles -QC Data Sum m aries ................................................... 727.1: M ethod Blank Summary .............................................................................................. 73 7.2: Blank Spike Summary ................................................................................................ 79 7.3: M atrix Spike/M atrix Spike Duplicate Summary ....................................................... 82 7.4: Instrument Performance Checks (DFTPP) ................................................................. 85 7.5: Internal Standard Area Summaries ............................................................................. 88 7.6: Surrogate Recovery Summ aries ...... I ........................................................................... 907.7: Initial and Continuing Calibration Summaries .......................................................... 91 Section 8: GC/M S Seni-volatiles -Raw Data ........................................................................ 100 8 .1 : S am p les .......................................................................................................................... 10 1 8.2: M ethod Blanks ............................................................................................................... 121E 2 of 122 7A .,cLrres.., N93379 --::. -, Accutest Laboratories I Sample Summary Arcadis Geraghty & Miller PSEG, Hancock's Bridge, NJ Sample Collected Number Date Time By N93379-1 03/15105 09:05 RDI N93379-2 03/15/05 11:00 N93379-3 03/15/05 13:12 RDI N93379-4 03/15/05 14:25 N93379-5 03/15/05 14:05 N93379-6 03/15/05 14:25 Job No: N93379 A A A it 4 ii Received 03/16/05 03/16/05 03/16/05 03/16/05 03/16/05 03/16/05 Matrix Code Type AQ Ground Water AQ Ground Water AQ Ground Water AQ Ground Water AQ Field Blank Water AQ Trip Blank Water Client Sample ID WELL AY WELL X WELL AV WELL AVD FB-031505 TRIP BLANK EEMl 3 of122 OACC 'L
- EST.N93379 ,. ,--'!;1 .
'V L. a b o: r a ', o r i f, SAMPLE DELIVERY GROUP CASE NARRATIVE Client: Arcadis Geraghty & Miller Job No N93379 Site: PSEG, Hancock's Bridge, NJ Report Date 4/5/2005 i1:51:07 AM 4 Sample(s), I Trip Blank(s) and I Field Blank(s) were collected on 03/15(2005 and were received at Accutest on 03/16/2005 properly preserved, at 4 Deg. C and intact. These Samples received an Accutest job number of N93379, A listing of the Laboratory Sample ID, Client Sample ID and dates of collection are presented in the Results Summary Section of this report.Except as noted below, all method specified calibrations and quality control performance criteria were met for this job. For more information, please refer to QC summary pages. Volatiles by GCMS By Method SW846 8260B Matrix AQ Batch ID: VA2990" All samples were analyzed within the recommended method holding time.-All method blanks for this batch meet method specific criteria." Sample(s) N93391-3DUP, N93391-4MS were used as the QC samples indicated." Blank Spike Recovery(s) for Chloromethane are outside control limits." VA2990-BS for Chloromethane: High percent recoveries and no associated positive found in the QC batch.Extractables'by GCMS By Method SW846 8270C= Matrix AQ Batch ID: OP19692" All samples were extracted within the recommended method holding time.* All samples were analyzed within the recommended method holding time." All method blanks for this batch meet method specific criteria.* Sample(s) N93090-14MS, N93090-14MSD were used as the QC samples indicated. -Matrix Spike Recovery(s) for 3,3'-Dichlorobenzidine are outside control limits. Probable cause due to matrix interference.
- Matrix Spike Duplicate Recovery(s) for 3,3'-Dichlorobenzidine are outside control limits. Probable cause due to matrix interference.
- OP 19692-MS for 3,3-Dichlorobenzidine:
Outside of in house control limits.The Accutest Laboratories of New Jersey certifies that all analysis were performed within method specification. It is further recommended that this report to be used in its entirety.The Accutest Laboratories of NJ, Laboratory Director or assignee as verified by the signature on the cover page has authorized the release of this report(N93379). 'V Tuesday, April 05,2005 Page 1 of 1 all 4 of 122 2ACC=UTEST N93379 . -"- ' , ' , - Raw Data: = I Accutest Laboratories 'V0 Report of Analysis Page 1 of 2 4W Client Sample ID: WELL AY Lab Sample ID: N93379-1 Date Sampled: 03/15/05 Matrix: AQ -Ground Water Date Received: 03/16/05 Method: SW846 8260B Percent Solids: n/a Project: PSEG, Hancock's Bridge, NJ File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 A94444.D 1 03/22/05 NDJ n/a n/a VA2990 Run #2 Purge Volume Run #1 5.0 ml Run #2 VOA TCL List CAS No. Compound Result RL MDL Units Q 67-64-1 Acetone ND 10 2.3 ug/l 71-4.3-2 Benzene ND 1.0 0.31 ug/h 75-27-4 Bromodichloromethane ND 1.0 0.11 ug/1 75-25-2 Bromoform ND 4.0 0.17 ugll 74-83-9 Bromomethane ND 2.0 0.15 ug/I 78-93-3 2-Butanone (MEK) ND 10 2.5 ug/l 75-15-0 Carbon disulfide ND 2.0 0.23 ug/I 56-23-5 Carbon tetrachloride ND 1.0 0.15 ug/l 108-90-7 Chlorobenzene ND 1.0 0.23 ug/l 75-00-3 Chloroethane ND 1.0 0.73 ug/I 67-66-3 Chloroform ND 1.0 0.081 ug/h 74-87-3 Chloromethane ND 1.0 0.13 ug/]124-48-1 Dibromochloromethane ND 1.0 0.18 ug/h 75-34-3 1,1-Dichloroethane ND 1.0 0.13 ugh]107-06-2 1,2-Dichloroethane ND 1.0 0.35 ug/I 75-35-4 1,1 -Dichloroethene ND 1.0 0.81 ug/l 156-59-2 cis-1,2-Dichloroethene ND 1.0 0.24 ug/l 156-60-5 ' trans- 1,2-Dichloroethene ND 1.0 0.17 ug/l 78-87-5 1,2-Dichloropropane ND 1.0 0.11 ug/l 10061-01-5 cis- 1,3-Dichloropropene ND 1.0 0.071 ug/I 10061-02-6 trans-1,3-Dichloropropene ND 1.0 0.080 ug/l 100-41-4 Ethylbenzene ND 1.0 0.27 ug/l 591-78-6 2-Hexanone ND 5.0 0.73 ug/l 108-10-1 4-Methyl-2-penlanone(MIBK) ND 5.0 0.59 ug/I 75-09-2 Methylene chloride ND 2.0 0.20 ug/I 100-42-5 Styrene ND 5.0 0.12 ug/l 79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.14 ug/]127-18-4 Tetrachloroethene ND 1.0 0.37 ug/l 108-88-3 Toluene ND 1.0 0.14 ug/l 71-55-6 1,1,1-Trichloroethane ND 1.0 0.25 ug/l 79-00-5 1,1,2-Trichloroethane ND 1.0 0.17 ug/h 79-01-6 Trichloroethene ND 1.0 0.13 ug/1 t,, ND Not detected MDL -Method Detection Limit RL Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B I Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound an 5of 122 12ACCLITEEST. N93379 ,ý --ý .: Accutest Laboratories Report of Analysis Page 2 of 2Client Sample ID: WELL AY Lab Sample ID: N93379-1 Date Sampled: 03/15/05 Matrix: AQ -Ground Water Date Received: 03/16/05 Method: SW846 8260B Percent Solids: n/a Project: PSEG. Hancock's Bridge, NJ VOA TCL List (Q CAS No. Compound 75-01-4 Vinyl chloride 1330-20-7 Xylene (total)CAS No.. Surrogate Recoveries Result RL MDL Units Q ND ND 1.0 1.0 0.66 ugh 0.17 ug/l Run# I Run# 2 Limits 1868-53-7 17060-07-0 2037-26-5 460-00-4 Dibromofluoromethane 1,2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene 87%107%87%113%79-119%68-129% 83-118%82-120%4w#or ND = Not detected MDL -Method Detection Limit RL Reporting Limit E = Indicates value exceeds calibration range J Indicates an estimated value B Indicates analyte found in associated method blank N Indicates presumptive evidence of a compound El6 of 122 VACCUTST Raw Data.4w I 1 Accutest Laboratories Report of Analysis Page 1 of 3 Client Sample ID: WELL AY Lab Sample ID: N93379-1 ' Date Sampled: 03/15/05 Matrix: AQ -Ground Water Date Received: 03/16/05 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG, Hancock's Bridge! NJ File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 H74037.D 1 04/02/05 SSW 03/16/05 OP19692 EH3145 Run W2 Initial Volume Final Volume.Run #1 1000 ml 1.0 ml Run #2 ABN TCL List CAS No. Compound Result RL MDL Units Q 95-57-8 2-Chlorophenol ND 5.0 4.3 ug/l 59-50-7 4-Chloro-3-methyl phenol ND 5.0 4.7 ug/l 120-83-2 2,4-Dichlorophenol ND 5.0 0.73 ug/l 105-67-9 2,4-Dimethylphenol ND 5.0 1.0 ug/i 51-28-5 2,4-Dinitrophenol ND 20 1.1 ug/l 534-52-I 4,6-Dinitro-o-cresol ND 20 0.65 ug/l 95-48-7 2-Methylphenol ND 5.0 0.72 ug/l 3&4-Methylphenol ND 5.0 0.70 ug/l 88-75-5 2-Nitrophenol ND 5.0 0.73 ug/l 100-02-7 4-Nitrophenol ND 20 2.3 ug/l 87-86-5 Pentachlorophenol ND 20 0.75 ug/h 108-95-2 Phenol ND 5.0 1.8 ug/l 95-95-4 2,4,5-Trichlorophenol ND 5.0 0.74 ug/l 88-06-2 2,4,6-Trichlorophenol ND 5.0 0.80 ug/l 83-32-9 Acenaphthene ND 2.0 0.30 ug/!208-96-8 Acenaphthylene ND 2.0 0.35 ug/l 120-12-7 Anthracene ND 2.0 0.22 ug/l 56-55-3 Benzo(a)anthracene ND 2.0 0.27 ug/l 50-32-8 Benzo(a)pyrene ND 2.0 0.38 ug/l 205-99-2 Benzo(b)fluoranthene ND 2.0 0.37 ug/l 191-24-2 Benzo(g,h,i)perylene ND 2.0 0.50 ug/h 207-08-9 Benzo(k)fluoranthene ND 2.0 0.37 ug/I 101-55-3 4-Bromophenyl phenyl ether ND 2.0 0.54 ug/l 85-68-7 Butyl benzyl phthalate ND 2.0 0.54 ug/l 91-58-7 2-Chloronaphthalene ND 5.0 0.38 ug/l 106-47-8 4-Chloroaniline ND 5.0 0.43 ug/l 86-74-8 Carbazole ND 2.0 0.34 ug/l 218-01-9 Chrysene ND 2.0 0.26 ug/l 111-91-1 bis (2-Chloroethoxy) methane ND 2.0 0.34 ug/l 111-44-4 bis(2-Chloroethyl)ether ND 2.0 0.49 ug/l 108-60-1 bis (2-Chloroisopropyl) ether ND 2.0 0.44 ug/1 7005-72-3 4-Chlorophenyl phenyl ether ND 2.0 1.0 ug/l ND = Not defected MDL -Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B Indicates analyle found in associated method blank E = Indicates value exceeds calibration range N Indicates presumptive evidence of a compound 01 7 of 122 9ACCU I Accutest Laboratories Report of Analysis Page 2 of 3 Client Sample ID: WELL AY Lab Sample ID: N93379-1 Date Sampled: 03/15/05 Matrix: AQ -Ground Water Date Received: 03/16/05 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG, Hancock's Bridge, NJ ABN TCL List CAS No. Compound Result RL MDL Units Q 95-50-1 1,2-Dichlorobenzene ND 2.0 0.24 ug/I 541-73-4 1,3-Dichlorobenzene ND 2.0 0.32 ug/l 106-46-7 1,4-Dichlorobenzene ND 2.0 0.25 ug/i 121-14-2. 2,4-Dinitrotoluene ND 2.0 0.78 ug/l 606-20-2 2,6-Dinitrotoluene ND 2.0 0.62 ug/l'91-94-1 3,3'-Dichlorobenzidine ND 5.0 0.39 ug/l 53-70-3 Dibenzo(a,h)anthracene ND 2.0 0.58 ug/l 132-64-9 Dibenzofuran ND 5.0 0.49 ug/]84-74-2 Di-n-butyl phthalate ND 2.0 0.79 ug/]117-84-0 Di-n-octyl phthalate ND 2.0 0.63 ug/h 84-66-2 Diethyl phthalate ND 2.0 1.4 ug/]131-11-3 Dimethyl phthalate ND 2.0 0.58 ug/!117-81-7 bis(2-Ethylhexyl)phthalate ND 2.0 0.74 ug/l 206-44-0 Fluoranthene ND 2.0 0.63 ug/h 86-73-7 Fluorene ND 2.0 0.89 ugh]118-74-1 Hexachlorobenzene ND 2.0 1.2 ug/l 87-68-3 Hexachlorobutadiene ND 2.0 0.41 ug/l 77-47-4 Hexachlorocyclopeniadiene ND 20 0.45 ug/l 67-72-1 Hexachloroethane ND 5.0 0.67 ug/l 193-39-5 tndeno(1,2,3-cd)pyrene ND 2.0 1.5 ug/l 78-59-1 Isophorone ND 2.0 0.54 ug/l 91-57-6 2-Methylnaphthalene ND 2.0 0.72 ug/l 88-74-4 2-Nitroaniline ND 5.0 1.4 ug/]99-09-2 3-Nitroaniline ND 5.0 1.2 ug/h 100-01-6 4-Nitroaniline ND 5.0 1.1 ug/]91-20-3 Naphthalene ND 2.0 1.0 ug/I 98-95-3 Nitrobenzene ND 2.0 0.61 ug/l 621-64-7 N-Nitroso-di-n-propylarnine ND 2,0 0.50 ug/I 86-30-6 N-Nitrosodiphenylamine ND 5.0 0.80 ug/l 85-01-8 Phenanthrene ND 2.0 0.23 ug/l 129-00-0 Pyrene ND 2.0 0.58 ug/l 120-82-1 1,2,4-Trichlorobenzene ND 2.0 0.32 ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 367-12-4 2-Fluorophenol 45% 14-81%4165-62-2 Phenol-d5 27% 10-64%118-79-6 2,4,6-Tribromophenol 80% 43-126%4165-60-0 Nitrobenzene-d5 90% 28-125%321-60-8 2-Fluorobiphenyl 82% 32-120%ND Not detected MDL -Method Detection Limit J = Indicates an estimated value RL Reporting Limit 13 = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound un! 8 of 122 92 -ACCUT.ST. N93379 lt. 3 ..'. Accutest Laboratories 40 Report of Analysis Page 3 of 3 Client Sample ID: WELL AY Lab Sample ID: N93379-1 Date Sampled: 03/15/05 Matrix: AQ -Ground Water Date Received: 03/16/05 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG, Hancock's Bridge, NJ ABN TCL List CAS No. Surrogate Recoveries 1718-51-0 Terphenyl-d] 4 Run# 1 Run# 2 Limits 89%42-125%ND = Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range I = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound En! 9 of122 12 ACCUTIEST. N93379 .,p-5ýý-. Raw Data: 1*.Accutest Laboratories Report of Analysis Page 1 of 2 Client Sample ID: WELL X Lab Sample ID: N93379-2 Date Sampled: 03/15/05 Matrix: AQ -Ground Water Date Received: 03/16/05 Method: SW846 8260B Percent Solids: n/a Project: PSEG, Hancock's Bridge, NJ File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 A94445.D 1 03/22/05 NDJ n/a n/a VA2990 Run #2 Purge Volume Run#1 5.0 ml Run #2 VOA TCL List CAS No. Compound Result RL MDL Units Q 67-64-1 Acetone ND 10 2.3 ug/l 71-43-2 Benzene ND 1.0 0.31 ug/l 75-27-4 Bromodichloromethane ND 1.0 0.11 ug/l 75-25-2 Bromoform ND 4.0 0.17 ug/l 74-83-9 Bromomethane ND 2.0 0.15 ug/l 78-93-3 2-Butanone (MEK) ND 10 2.5 ug/l 75-15-0 Carbon disulfide ND 2.0 0.23 ug/l 56-23-5 Carbon tetrachloride ND 1.0 0.15 ug/l 108-90-7 Chlorobenzene ND 1.0 0.23 ug/l 75-00-3 Chloroethane ND 1.0 0.73 ug/l 67-66-3 Chloroform ND 1.0 0.081 ug/l 74-87-3 Chloromethane ND 1.0 0.13 ug/l 124-48-1 Dibromochloromethane ND 1.0 0.18 ug/l 75-34-3 1,1-Dichloroethane ND 1.0 0.13 ug/l 107-06-2 1,2-Dichloroethane ND 1.0 0.35 ugl]75-35-4 1,I-Dichloroethene ND 1.0 0.81 ug/l 156-59-2 cis-1,2-Dichloroethene ND 1.0 0.24 ug1 156-60-5 trans- 1,2-Dichloroethene ND 1.0 0.17 ug/l 78-87-5 1,2-Dichloropropane ND 1.0 0.11 ug/l 10061-01-5 cis-1,3-Dichloropropene ND 1.0 0.071 ug/l 10061-02-6 trans- 1,3-Dichloropropene ND 1.0 0.080 ug/l 100-41-4 Ethylbenzene 0.83 1.0 0.27 ug/l 591-78-6 2-Hexanone ND 5.0 0.73 ug/h 108-10-1 4-Methyl-2-pentanone(MIBK) ND 5.0 0.59 ug/1 75-09-2 Methylene chloride ND 2.0 0.20 ug/h 100-42-5 Styrene ND 5.0 0,12 ug/I 79-34-5 1,1,2,2-Tetrachloroelhane ND 1.0 0.14 ug/l 127-18-4 Tetrachloroethene ND 1.0 0.37 ug/1 108-88-3 Toluene ND 1.0 0.14 ug/1 71-55-6 1,1, 1-Trichloroethane ND 1.0 0.25 ug/l 79-00-5 1,1,2-Trichloroelhane ND 1.0 0.17 ug/l 79-01-6 Trichloroethene ND 1.0 0.13 ug/l ND = Not detected MDL -Method Detection Limit .= Indicates an estimated value RL = Reporting Limit B = Indicates analyle found in associated method blank E = Indicates value exceeds calibration range N Indicates presumptive evidence of a compound 2 10of122 N'ACCUTEST. N93379 Acculest Laboratories 'p Report of Analysis Page 2 of 2 Client Sample ID: WELL XLab Sample ID: N93379-2 Date Sampled: 03/15/05 Matrix: AQ -Ground Water Date Received: 03/16/05 Method: SW846 8260B Percent Solids: n/a Project: PSEG, Hancock's Bridge, NJ VOA TCL ListýO CAS No. Compound 75-01-4 Vinyl chloride 1330-20-7 Xylene (total)CAS No.. Surrogate Recoveries Result RL MDL Units Q ND ND 1,0 1.0 0.66 ug/l 0.17 ug/1 Run# I Run# 2 Limits 1868-53-7 17060-07-0 2037-26-5 460-00-4 Dibromofluoromethane 1,2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene 88%110%87%111%79-119%68-129%83-118%'82-120%ND = Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound CM111 of122 JUACCLJITES 1 N93379 Raw Data: Accutest Laboratories Report of Analysis Page 1 of 3 Client Sample ID: WELL X Lab Sample ID: N93379-2 Date Sampled: 03/15/05 Matrix: AQ -Ground Water Date Received: 03/16/05 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG, Hancock's Bridge, NJ File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 H74038.D 1 04/02/05 SSW 03/16/05 OP19692 EH3145 Run #2 Initial Volume Final Volume Run #1 980 ml 1.0 ml Run #2 ABN TCL List CAS No. Compound Result RL MDL Units Q 95-57-8 2-Chlorophenol ND 5.1 4.3 ug/l 59-50-7 4-Chloro-3-methyl phenol ND 5.1 4.8 ug/l 120-83-2 2,4-Dichlorophenol ND 5.1 0.74 ug/l 105-67-9 2,4-Dimethylphenol ND 5.1 1.0 ug/l 51-28-5 2,4-Dinitrophenol ND 20 1.1 ug/I 534-52-1 4,6-Dinitro-o-cresol ND 20 0.66 ug/l 95-48-7 2-Methylphenol ND 5.1 0.74 ug/I 3&4-Methylphenol ND 5.1 0.72 ug/h 88-75-5 2-Nitrophenol ND 5.1 0.75 ug/l 100-02-7 4-Nitrophenol ND 20 2.3 ug/l 87-86-5 Pentachlorophenol ND 20 *0.77 ug/l 108-95-2 Phenol ND 5.1 1.8 ug/l 95-95-4 2,4,5-Trichlorophenol ND 5.1 0.76 ug/l 88-06-2 2,4,6-Trichlorophenol ND 5.1 0.82 ug/l 83-32-9 Acenaphthene ND 2.0 0.30 ug/l 208-96-8 Acenaphthylene ND 2.0 0.35 ug/I 120-12-7 Anthracene ND 2.0 0.22 ug/I 56-55-3 Benzo(a)anthracene ND 2.0 0.28 ug/l 50-32-8 Benzo(a)pyrene ND 2,0 0.39 ughl 205-99-2 Benzo(b)fluoranthene ND 2.0 0.38 ug/l 191-24-2 Benzo(g,h,i)perylene ND 2.0 0.51 ug/h 207-08-9 Benzo(k)fluoranthene ND 2.0 0.38 ug/l 101-55-3 4-Bromophenyl phenyl ether ND 2.0 0.55 ug/l 85-68-7 Butyl benzyl phthalate ND 2.0 0.55 ug/l 91-58-7 2-Chloronaphthalene ND 5.1 0.38 ug/I 106-47-8 4-Chloroaniline ND 5.1 0.44 ug/l 86-74-8 Carbazole ND 2.0 0.35 ug/l 218-01-9 Chrysene ND 2.0 0.27 ug/h 111-91-1 bis(2-Chloroethoxy)methane ND 2.0 0.34 ug/l 111-44-4 bis(2-Chloroethyl)ether ND 2.0 0.49 ug/I 108-60-1 bis(2-Chloroisopropyl)ether ND 2.0 0.45 ug/l 7005-72-3 4-Chlorophenyl pheny] ether ND 2.0 1.0 ug/h~10 C, ND = Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyle found in associated method blank N = Indicates presumptive evidence of a compound 12ACCUTISC N93379 .." -1 Accutest Laboratories Report of Analysis Page 2 of 3Client Sample ID: WELL X Lab Sample ID: N93379-2 Matrix: AQ -Ground Water Method: SW846 8270C SW846 3510C Project: PSEG, Hancock's Bridge, NJ Date Sampled: 03/15/05 Date Received: 03/16/05 Percent Solids: n/a ABN TCL List CAS No. Compound 95-50-1 1,2-Dichlorobenzene 541-73-1 1,3-Dichlorobenzene 106-46-7 1,4-Dichlorobenzene 121-14-2 2,4-Dinitrotoluene 606-20-2 2,6-Dinitrotoluene 91-94-1 3,3'-Dichlorobenzidine 53-70-3 Dibenzo(ah)anthracene 132-64-9 Dibenzofuran 84-74-2 Di-n-butyl phthalate 117-84-0 Di-n-octyl phthalate 84-66-2 Diethyl phthalate 131-11-3 Dimethyl phithalate 117-81-7 bis (2-Ethylhexyl) phthalate 206-44-0 Fluoranthene 86-73-7 Fluorene 118-74-1 Hexachlorobenzene 87-68-3 Hexachlorobutadiene 77-47-4 Hexachlorocyclopentadiene 67-72-1 Hexachloroethane 193-39-5 Indeno(1,2,3-cd)pyrene 78-59-1 Isophorone 91-57-6 2-Methylnaphthalene 88-74-4 2-Nitroaniline 99-09-2 3-Nitroaniline 100-01-6 4-Nitroaniline 91-20-3 Naphlhalene 98-95-3 Nitrobenzene 621-64-7 N-Nitroso-di-n-propylamine 86-30-6 N-Nitrosodiphenylamine 85-01-8 Phenanthrene 129-00-0 Pyrene 120-82-1 1,2,4-Trichlorobenzene Result RL MDL Units Q 2.0 2.0 2.0 2.0 2.0 5.1 2.0 5.1 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 20 5.1 2.0 2.0 2.0 5.1 5.1 5.1 2.0 2.0 2.0 5.1 2.0 2.0 2.0 0.24 ug/h 0.33 ug/l 0.26 ug/l 0.79 ug/I 0.63 ug/h 0.40 ug/l 0.59 ug/l 0.50 ug/l 0.80 ug/I 0.64 ug/1.5 ug/I 0.59 ug/l 0.75 ug/I 0,65 ug/l 0,91 ug/h 1.2 ug/l 0.42 ug/1 0.46 ugll 0.68 ug/l 1.6 ug/l 0.55 ug/l 0.74 ug/l 1.4 ug/h 1.2 ugil 1.1 ug/l 1.0 ug/l 0.62 ug/l 0.51 ug/l 0.81 ug/h 0.24 ug/l 0.60 ug/l 0.33 ug/h CAS No. Surrogate Recoveries 367-12-4 2-Fluorophenol 4165-62-2 Phenol-d5 118-79-6 2,4,6-Tribromophenol 4165-60-0 Nitrobenzene-d5 321-60-8 2-Fluorobiphenyl Run# I 36%23%78%71%67%Run# 2 Limits 14-81%10-64%43-126%28-125%32-120%ND = Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blankN = Indicates presumptive evidence of a compound El13 of 122 Q ACCUTEST.N93379 -: .- : Accutest Laboratories 41w Report of Analysis Page 3 of 3 Client Sample ID: WELL XLab Sample ID: N93379-2 Date Sampled: 03/15/05 Matrix: AQ -Ground Water Date Received: 03/16/05 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG, Hancock's Bridge, NJ ABN TCL List CAS No. Surrogate Recoveries 1718-51-0 Terphenyl-d14 Run# I Run# 2 Limits 83%42-125%ND = Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound Egi14of 122 OACCLJTEST1 N93379e -:-- - R a v4 0 S! ý M -=Accutest Laboratories 4w Report of Analysis Page I of2 .Client Sample ID: WELL AV Lab Sample ID: N93379-3 Date Sampled: 03/15/05 Matrix: AQ- Ground Water Date Received: 03/16/05 Method: SW846 8260B Percent Solids: n/a Project: PSEG, Hancock's Bridge, NJ File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 A94446.D 1 03/22/05 NDJ n/a n/a VA2990 Run #2 Purge Volume Run #1 5.0 ml Run #2 VOA TCL List CAS No. Compound Result RL MDL Units Q 67-64-1 Acetone ND 10 2.3 ug/I 71-43-2 Benzene ND 1.0 0.31 ug/I 75-27-4 Bromodichloromethane ND 1.0 0.11 ug/!75-25-2 Bromoform ND 4.0 0.17 ug/l 74-83-9 Bromomethane ND 2.0 0.15 ug/l 78-93-3 2-Butanone (MEK) ND 10 2.5 ug/l 75-15-0 Carbon disulfide ND 2,0 0.23 ug/l 56-23-5 Carbon tetrachloride ND 1.0 0,15 ug/l 108-90-7 Chlorobenzene ND 1.0 0.23 ug/i 75-00-3 Chloroethane ND 1.0 0.73 ug/l 67-66-3 Chloroform ND 1.0 0.081 ug/l 74-87-3 Chloromethane ND 1.0 0.13 ug/h 124-48-1 Dibromochioromethane ND 1.0 0.18 ug!1 75-34-3 1, 1-Dichloroetbane ND 1.0 0.13 ug/h 107-06-2 1,2-Dichloroethane ND 1.0 0.35 ug/I 75-35-4 1,1-Dichloroethene ND 1.0 0.81 ug/l 156-59-2 cis- I,2-Dichloroethene ND 1.0 0.24 ug/I 156-60-5 trans- 1,2- Dichloroethene ND 1.0 0.17 ug/l 78-87-5 1,2-Dichloropropane ND 1.0 0.11 ug/l 10061-01-5 cis-l,3-Dichloropropene ND 1.0 0.071 ughl 10061-02-6 irans-1,3-Dichloropropene ND 1.0 0.080 ug/l 100-41-4 Ethylbenzene ND 1.0 0.27 ugh]591-78-6 2-Hexanone ND 5.0 0.73 ug/l 108-10-1 4-Methyl-2-pentanone(MIBK) ND 5.0 0.59 ug/l 75-09-2 Methylene chloride ND 2.0 0.20 ug/I 100-42-5 Styrene ND 5.0 0.12 ug/h 79-34-5 1,1,2,2-Teirachlioroethane ND 1.0 0.14 ug/h 127-18-4 Tetrachloroethene ND 1.0 0.37 ug/l 108-88-3 Toluene ND 1.0 0.14 ug/l 71-55-6 1, 1,1-Trichloroeihane ND 1.0 0.25 ugh]79-00-5 1, 1,2-Trichloroelhane ND 1.0 0.17 ugh/79-01-6 Trichloroethene ND 1.0 0.13 ug/1 ND = Not detected MDL -Method Detection Limit RL Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyle found in associated method blank N, = Indicates presumptive evidence of a compound En 15 of 122 SACCU IES N93379 Accutest LaboratoriesReport of Analysis Page 2 of 2 Client Sample ID: WELL AV Lab Sample ID: N93379-3 Date Sampled: 03/15/05 Matrix: AQ -Ground Water Date Received: 03/16/05 Method: SW846 8260B 'Percent Solids: n/a Project: PSEG, Hancock's Bridge, NJ VOA TCL List CAS No. Compound 75-01-4 Vinyl chloride 1330-20-7 Xylene (total) CAS No, Surrogate Recoveries Result RL MDL Units Q ND ND 1.0 1.0 0.66 ug/l 0.17 ug/I Run# 1 Run# 2 Limits 1868-53-7 17060-07-0 2037-26-5 460-00-4 Dibromofluoromethane 1,2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene 87%110% 87%108%79-119%68-129%83-118%82-120%ND = Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated valueB = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 12116 of122 GACCUTES!ý= N93379 : '.- : Raw Data: Accutest Laboratories Report of Analysis Page 1 of3 3 Client Sample ID: WELL AV Lab Sample ID: N93379-3 Date Sampled: 03/15/05 Matrix: AQ -Ground Water Date Received: 03/16/05 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG, Hancock's Bridge, NJFile ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 H74039.D 1 04/02/05 SSW 03/16/05 OP19692 EH3145 Run #2 Initial Volume Final Volume Run #1 1000 ml 1.0 ml Run #2 ABN TCL List CAS No. Compound Result RL MDL Units Q 95-57-8 2-Chlorophenol ND 5.0 4.3 ug/l 59-50-7 4-Chloro-3-methyl phenol ND 5.0 4.7 ug/l 120-83-2 2,4-Dichlorophenol ND 5.0 0.73 ug/h 105-67-9 2,4-Dimethylphenol ND 5.0 1.0 ug/l 51-28-5 2,4-Dinitrophenol ND 20 1.1 ug/l 534-52-1 4,6-Dinitro-o-cresol ND 20 0.65 ug/l 95-48-7 2-Methylphenol ND 5.0 0.72 ug/l 3&4-Methylphenol ND 5.0 0.70 ug/l 88-75-5 2-Nitrophenol ND 5.0 0.73 ug/l 100-02-7 4-Nitrophenol ND 20 2.3 ug/l 87-86-5 Pentachlorophenol ND 20 0.75 ug/l 108-95-2 Phenol ND 5.0 1.8 ug/l 95-95-4 2,4,5-Trichlorophenol ND 5.0 0.74 ug/!88-06-2 2,4,6-Trichlorophenol ND 5.0 0.80 ug/i 83-32-9 Acenaphthene 5.0 2.0 0.30 ug/208-96-8 Acenaphthylene ND 2.0 0,35 ug/l 120-12-7 Anthracene 0.95 2.0 0.22 ug/l 56-55-3 Benzo(a)anthracene ND 2,0 0.27 ug/l 50-32-8 Benzo(a)pyrene ND 2.0 0.38 ug/l 205-99-2 Benzo(b)fluoranthene ND 2.0 0.37 ug/l 191-24-2 Benzo(g,h,i)perylene ND 2.0 0.50 ug/l 207-08-9 Benzo(k)fluoranthene ND 2,0 0.37 ug/l 101-55-3 4-Bromophenyl phenyl ether ND 2.0 0.54 ug/l 85-68-7 Butyl benzyl phthalate ND 2.0 0.54 ug/l 91-58-7 2-Chloronaphthalene ND 5.0 0.38 ug/i 106-47-8 4-Chloroaniline ND 5.0 0.43 ug/l 86-74-8 Carbazole 9.9 2.0 0.34 ug/!218-01-9 Chrysene ND 2.0 0.26 ug/1 111-91-1 bis (2-Chloroethoxy) methane ND 2.0 0.34 ug/l 111-44-4 bis(2-Chloroethyl)ether ND 2.0 0.49 ug/l 108-60-1 bis(2-Chloroisopropyl)ether ND 2.0 0.44 ug/l 7005-72-3 4-Chlorophenyl phenyl ether ND 2,0 1.0 ug/l ND = Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration rangei J Indicates an estimated value B Indicates analyte found in associated method blank N Indicates presumptive evidence of a compound OM 17 of122 VACCU-rTzST. N93379 ýi" 1-Accutest Laboratories Report of Analysis Page 2 of 3Client Sample ID: WELL AV Lab Sample ID: N93379-3 Date Sampled: 03/15/05 Matrix- AQ -Ground Water Date Received: 03/16/05 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG, Hancock's Bridge, NJ ABN TCL List CAS No. Compound Result RL MDL Units Q 95-50-1 1,2-Dichlorobenzene ND 2.0 0.24 ug/l 541-73-1 1,3-Diclilorobenzene ND 2.0 0.32 ug/I 106-46-7 1,4-Dichlorobenzene ND 2.0 0.25 ugh 121-14-2 2,4-Dinitrotoluene ND 2.0 0.78 ug/l 606-20-2 2,6-Dinitrotoluene ND 2.0 0.62 ug/I 91-94-1 3,3'-Dichlorobenzidine ND 5.0 0.39 ug/I 53-70-3 Dibenzo(a,h)anthracene ND 2.0 0.58 ug/i 132-64-9 Dibenzofuran 2.7 5.0 0.49 ug/l J 84-74-2 Di-n-butyl phthalate ND 2.0 0.79 ug/l 117-84-0 Di-n-octy] phthalate ND 2.0 0.63 ug/l 84-66-2 Diethyl phthalate ND 2.0 1.4 ug/h 131-11-3 Dimethy] phthalate ND 2.0 0,58 ug/l 117-81-7 bis(2-Ethylhexyl) phthalate ND 2.0 0.74 ug/l 206-44-0 Fluoranthene 1.4 2.0 0.63 ug/!86-73-7 Fluorene 4.4 2.0 0.89 ug/I 118-74-1 Hexachlorobenzene ND 2.0 1.2 ug/i 87-68-3 Hexachlorobutadiene ND 2.0 0.41 ug/l 77-47-4 Hexachlorocyclopentadiene ND 20 0.45 ug/I 67-72-1 Hexachloroethane ND 5.0 0.67 ug/l 193-39-5 lndeno(1,2,3-cd)pyrene ND 2.0 1.5 ug/l 78-59-1 Isophorone ND 2.0 0.54 ug/l 91-57-6 2-Methylnaphthalene 2.0 2.0 0.72 ug/l 88-74-4 2-Nitroaniline ND 5.0 1.4 ug/l 99-09-2 3-Nilroaniline ND 5.0 1.2 ug/l 100-01-6 4-Nitroaniline ND 5,0 1.1 ug/l 91-20-3 Naphthalene 4.3 2.0 1.0 ug/I 98-95-3 Nitrobenzene ND 2.0 0.61 ug/l 621-64-7 N-Nitroso-di-n-propylamine ND 2.0 0.50 ug/I 86-30-6 N-Nitrosodiphenylamine ND 5.0 0.80 ug/I 85-01-8 Phenanthrene 5.3 2.0 0.23 ug/l 129-00-0 Pyrene 0.94 2.0 0.58 ug/I 120-82-1 1,2,4-Trichlorobenzene ND 2.0 0.32 ug/l CAS No. Surrogate Recoveries Run# I Run# 2 :Limits 367-12-4 2-Fluorophenol 45% 14-81%4165-62-2 Phenol-d5 28% 10-64%118-79-6 2,4,6-Tribromophenol 95% 43-126%4165-60-0 Nitrobenzene-d5 93% 28-125%321-60-8 2-Fluorobiphenyl 82% 32-120%ND = Not detected MDL -Method Detection Limit J = Indicates an estimated valueRL = Reporting Limit B Indicates analyle found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound18 of 122 9ACCU I N93379 Accutest Laboratories 6Report of Analysis Page 3 of 3 Client Sample ID: WELL AV Lab Sample ID: N93379-3 Date Sampled: 03/15/05 Matrix: AQ -Ground Water Date Received: 03/16/05 Method: SW846 9270C. SW846 3510C Percent Solids: n/a Project: PSEG, Hancock's Bridge, NJ ABN TCL List CAS No. Surrogate Recoveries 1718-51-0 Terphenyl-d14Run# 1 Run# 2 Limits 90%42-125%kw ND = Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J Indicates an estimated value B Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound El~j 19 of 122 12ACCLJTEMT. N~93379 Raw Date: Accutest Laboratories Report of Analysis Page 1 of 2 Client Sample ID: WELL AVD Lab Sample ID: N93379-4 Date Sampled: 03/15/05 Matrix: AQ -Ground Water Date Received: 03/16/05 Method: SW846 8260B Percent Solids: n/a Project: PSEG, Hancock's Bridge, NJ File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 A94447.D 1 03/22/05 NDJ n/a n/a VA2990 Run #2 Purge Volume Run #1 5.0 ml Run #2 VOA TCL List CAS No. Compound Result RL MDL Units Q 67-64-1 Acetone ND 10 2.3 ug/l.71-43-2 Benzene ND 1.0 0.31 ug/h 75-27-4 Bromodichloromethane ND 1.0 0.11 ug/I 75-25-2 Bromoform ND 4.0 0.17 ug/I 74-83-9 Bromomethane ND 2.0 0.15 ug/l 78-93-3 2-Butanone (MEK) ND 10 2.5 ug/I 75-15-0 Carbon disulfide ND 2.0 0.23 ug/l 56-23-5 Carbon tetrachloride ND 1.0 0.15 ug/l 108-90-7 Chlorobenzene ND 1.0 0.23 ug/h 75-00-3 Chloroelhane ND 1.0 0.73 ug/l 67-66-3 Chloroform ND 1.0 0.081 ug/l 74-87-3 Chloromethane ND 1.0 0.13 ug/l 124-48-1 Dibromochloromethane ND 1.0 0.18 ug/l 75-34-3 1,1-Dichloroethanie ND 1.0 0.13 ug/l 107-06-2 1,2-Dichloroethane ND 1.0 0.35 ug/I 75-35-4 1,1-Dichloroethene ND 1.0 0.81 ug/h 156-59-2 cis- 1,2-Dichioroethene ND 1.0 0.24 ug/1 156-60-5 trans- 1,2-Dichloroethene ND 1.0 0.17 ug/l 78-87-5 1,2-Dichloropropane ND 1.0 0.11 ug/I 10061-01-5 cis-1,3-Dichloropropene ND 1.0 0.071 ug/l 10061-02-6 trans- 1,3-Dichloropropene ND 1.0 0.080 ug/l 100-41-4 Ethylbenzene ND 1.0 0.27 ug/l 591-78-6 2-Hexanone ND 5.0 0.73 ug/h 108-10-1 4-Methyl-2-penlanone(MIBK) ND 5.0 0.59 ug/l 75-09-2 Methylene chloride ND 2.0 0.20 ug/l 100-42-5 Styrene ND 5.0 0.12 ug/l 79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.14 ugll 127-18-4 Teirachloroethene ND 1.0 0.37 ug/!108-88-3 Toluene ND 1.0 0.14 ug/I 71-55-6 1,1,1-Trichloroethane ND 1.0 0.25 ug/l 79-00-5 1,1,2-Trichloroethane ND 1.0 0.17 ug/79,01-6 Trichloroethene ND 1.0 0.13 ug/l ND = No( detected MDL -Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N Indicates presumptive evidence of a compound S20 of 122 3ACCU I ES I N93379 Accutest Laboratories 'Vw Report of Analysis Page 2 of 2 Client Sample ID: WELL AVD Lab Sample ID: N93379-4 Date Sampled: 03/15/05 Matrix: AQ -Ground Water Date Received: 03/16/05 Method: SW846 8260B Percent Solids: n/a Project: PSEG, Hancock's Bridge, NJ VOA TCL List.4-CAS No. Compound 75-01-4 Vinyl chloride 1330-20-7 Xylene (total)CAS No. Surrogate Recoveries Result RL MDL Units Q ND ND 1.0 1.0 0.66 ug/]0.17 ug/l Run# I Run# 2 Limits 1868-53-7 17060-07-0 2037-26-5 460-00-4 Dibromofluoromethane 1,2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene 87%107%87%108%79-119%68-129%83-118%82-120%'Vr ND = Not detected MDL -Method Detection Limit RL Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyle found in associated method blank N = Indicates presumptive evidence of a compound OACCUrrEzS-I N93379 Raw Data: Accutest Laboratories Report of Analysis Page 1 of 3 Client Sample ID: WELL AVD Lab Sample ID: N93379-4 Date Sampled: 03/15/05 Matrix: AQ -Ground Water Date Received: 03/16/05 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG, Hancock's Bridge, NJ File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 H74040.D 1 04/02/05 SSW 03/16/05 OP19692 EH3145 Run #2 Initial Volume Final Volume Run #1 1000ml 1.0mm Run #2 ABN TCL List CAS No. Compound Result RL MDL Units Q 95-57-8 2-Chlorophenol ND 5.0 4.3 ug/l 59-50-7 4-Chloro-3-methyl phenol ND 5.0 4.7 ug/l 120-83-2 2,4-Dichlorophenol ND 5.0 0.73 ug/l 105-67-9 2,4-Dimethylphenol ND 5.0 1.0 ug/1 51-28-5 2,4-Dinitrophenol ND 20 1,1 ug/l 534-52-1 4,6-Dinitro-o-cresol ND 20 0.65 ug/l 95-48-7 2-Methylphenol ND 5.0 0.72 ug/l 3&4-Methylphenol ND 5.0 0.70 ug/1 88-75-5 2-Nitrophenol ND 5.0 0.73 ug/1 100-02-7 4-Nitrophenol ND 20 2.3 ug/l 87-86-5 Pentachlorophenol ND 20 0.75 ug/l 108-95-2 Phenol ND 5.0 1.8 ug/l 95-95-4 2,4,5-Trichlorophenol ND 5.0 0.74 ug/l 88-06-2 2,4,6-Trichlorophenol ND 5.0 0.80 ug/I 83-32-9 Acenaphthene 5.1 2.0 0.30 ug/l 208-96-8 Acenaphthylene ND 2.0 0.35 ug/l 120-12-7 Anthracene 0.97 2.0 0.22 ug/l 56-55-3 Benzo(a)anthracene ND 2.0 0.27 ug/l 50-32-8 Benzo(a)pyrene ND. 2.0 0.38 ug/l 205-99-2 Benzo(b)fluoranthene ND 2.0 0.37 ug/h 191-24-2 Benzo(g,h,i)perylene ND 2.0 0.50 ug/l 207-08-9 Benzo(k)fluoranthene ND 2.0 0.37 ug/I 101-55-3 4-Bromophenyl phenyl ether ND 2.0. 0.54 ug/l 85-68-7 Butyl benzyl phthalate ND 2.0 0.54 ug/l 91-58-7 2-Chloronaphthalene ND 5.0 0.38 ug/l 106-47-8 4-Chioroaniline ND 5.0 0.43 ug/l 86-74-8 Carbazole 10 2.0 0.34 ug/l 218-01-9 Chrysene ND 2.0 0.26 ug/i 111-91-1 bis(2-Chloroelhoxy)methane ND 2.0 0.34 ug/i 111-44-4 bis (2-Chloroethyl)ether ND 2.0 0.49 ug/l 108-60-1 bis(2-Chloroisopropyl) ether ND 2.0 0.44 ug/l 7005-72-3 4-Chlorophenyl phenyl ether ND 2.0 1.0 ug/l ND -Not detected MDL -Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound22 of 122 3ACCUTEST. N93379 -' Accutest Laboratories Report of Analysis Page 2 of 3 Client Sample ID: WELL AVD Lab Sample ID: N93379-4 Date Sampled: 03/15/05 Matrix: AQ -Ground Water Date Received: 03/16/05 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG, Hancock's Bridge, NJ ABN TCL List'Vw CAS No. Compound Rest 95-50-1 1,2-Dicdlorobenzene ND 541-73-1 1,3-Dichlorobenzene ND 106-46-7 1,4-Dichlorobenzene ND 121-14-2 2,4-Dinitrotoluene ND 606-20-2 2,6-Dinitrotoluene ND 91-94-1 3,3'-Dichlorobenzidine ND 53-70-3 Dibenzo(a,h)anthracene ND 132-64-9 Dibenzofuran 2.7 84-74-2 Di-n-butyl phihalate ND 117-84-0 Di-n-octyl phthalate ND 84-66-2 Diethyl phthalate ND 131-11-3 Dimethyl phthalale ND 117-81-7 bis(2-Ethylhexyl)phthalate ND 206-44-0 Fluoranthene 1.4 86-73-7 Fluorene 4.7 118-74-1 Hexachlorobenzene ND 87-68-3 Hexachlorobutadiene ND 77-47-4 -lexachlorocyclopentadiene ND 67-72-1 Hexachloroethane ND 193-39-5 lndeno(1,2,3-cd)pyrene ND 78-59-1 Isophorone ND 91-57-6 2-Methylnaphthalene 2.3 88-74-4 2-Nitroaniline ND 99-09-2 3-Nitroaniline ND 100-01-6 4-Nitroaniline ND 91-20-3 Naphthalene 4.6 98-95-3 Nihrobenzene ND 621-64-7 N-Nitroso-di-n-propylamine ND 86-30-6 N-Nitrosodiphenylamine ND 85-01-8 Phenanthrene 5.6 129-00-0 Pyrene 0.97 120-82-1 1,2,4-Trichlorobenzene ND CAS No. Surrogate Recoveries Runj 367-12-4 2-Fluorophenol 47%4165-62-2 Phenol-d5 29%118-79-6 2,4,6-Tribromophenol 96%4165-60-0 Nitrobenzene-d5 97%321-60-8 2-Fluorobiphenyl 84%2.0 2.0 2.0 2.0 2.0 5.0 2.0 5.0 2,0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 20 5.0 2.0 2.0 2.0 5.0 5.0 5,0 2.0 2.0 2,0 5.0 2.0 2.0 2.0 0.24 ug/I 0.32 ug/I 0.25 ug/t 0.78 ug/l 0.62 ug/I 0.39 ug/l 0.58 ug/l 0.49 ug/I 0.79 ug/l 0.63 ug/I 1.4 ug/l 0.58 ug/I 0.74 ug/I 0.63 ug/I 0.89 ug/I 1.2 ug/I'0.41 ug/l 0,45 ug/I 0.67 ug/]1.5 ug/I 0.54 ug/I 0.72 ug/l 1.4 ug/I 1.2 ug/l 1.1 ug/l 1.0 ug/I 0.61 ug/I 0.50 ugh 0.80 ug/l 0.23 ug/l 0.58 ug/l 0.32 ug/I Ilt RL MDL Units# I RunW 2 Limits 14-81%10-64%43-126% 28-125%32-120%ND = Not detected MDL -Method Detection Limit RL Reporting Limit E = Indicates value exceeds calibration range J. Indicates an estimated value B Indicates analyte found in associated method blank N Indicates presumptive evidence of a compound f1!i 23 of 122 12ACCUTEnT. N93379 Accutest Laboratories Report of Analysis Page 3 of 3 Client Sample ID: WELL AVD Lab Sample ID: N93379-4 Date Sampled: 03/15/05 Matrix: AQ -Ground Water Date Received: 03/16/05 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG, Hancock's Bridge, NJ ABN TCL List CAS No. Surrogate Recoveries 1718-51-0 Terphenyl-d14 Run# 1 Run# 2 Limits 89%42-125%~hbw ND = No( detected MDL -Method Detection Limit RL Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound an! 24 of 122 UACCUTEPT N93379 Raw Data: Accutest Laboratories Report of Analysis Page I of 2 P Client Sample ID: FB-031505Lab Sample ID: N93379-5 Date Sampled: 03/15/05 Matrix: AQ -Field Blank Waler Date Received: 03/16/05 Method: SW846 8260B Percent Solids: n/a Project: PSEG, Hancock's Bridge, NJ File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 A94448.D 1 03/22/05 NDJ n/a n/a VA2990 Run #2 Purge Volume Run #1 5.0 ml Run #2 VOA TCL List CAS No. Compound Result RL MDL Units Q 67-64-1 Acetone ND 10 2.3 ug/l 71-43-2 Benzene ND 1.0 0.31 ug/l 75-27-4 Bromodichloromethane ND 1.0 0.11 ug/l 75-25-2 Bromoform ND 4.0 0.17 ug/l 74-83-9 Bromomethane ND 2.0 0,15 ug/]78-93-3 2-Butanone (MEK) ND 10 2,5 ug/l 75-15-0 Carbon disulfide ND 2.0 0.23 ug/I 56-23-5 Carbon tetrachloride ND 1.0 0.15 ug/l 108-90-7 Chlorobenzene ND 1.0 0.23 ug/l 75-00-3 Chloroethane ND 1.0 0.73 ug/l 67-66-3 Chloroform ND 1.0 0.08] ug/]74-87-3 Chloromethane ND 1.0 0.13 ug/l 124-48-1 Dibromochloromethane ND 1.0 0.18 ug/l 75-34-3 1,1-Dichloroethane ND 1.0 0.13 ug/l 107-06-2 1,2-Dichloroethane ND 1.0 0.35 ug/l 75-35-4 1, 1-Dichloroethene 'ND 1.0 0.81 ug/l 156-59-2 cis-1,2-Dichloroethene ND 1.0 0.24 ug/l 156-60-5 trans-1,2-Dichloroethene ND 1.0 0.17 ug/1 78-87-5 1,2-Dichloropropane ND 1.0 0.11 ug/I 10061-01-5 cis-1,3-Dichloropropene ND 1.0 0.071 ug/l 10061-02-6 trans- 1,3-Dichloropropene ND 1.0 0.080 ug/l 100-41-4 Ethylbenzene ND 1.0 0.27 ug/l 591-78-6 2-Hexanone ND 5.0 0.73 ug/l 108-10-1 4-Methyl-2-pentanone(MIBK) ND 5.0 0.59 ug/l 75-09-2 Methylene chloride ND 2.0 0.20 ug/l 100-42-5 Styrene ND 5.0 0.12 ug/l 79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.14 ug/l 127-18-4 Tetracbloroethene ND 1.0 0.37 ug/l 108-88-3 Toluene ND 1.0 0.14 ugh]71-55-6 1,1,1-Trichloroethane ND 1.0 0.25 ug/l 79-00-5 1,1,2-Trichloroethane ND 1.0 0.17 ug/t 79-01-6 Trichloroethene ND 1.0 0.13 ug/l A ND = Not detected MDL -Method Detection Limit RL Reporting Limit. E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound fi]25 of122 QACCU a ES-T N93379 ., -.% .ýýI Accutest Laboratories y Report of Analysis Page 2 of 2 Client Sample ID: FB-031505 Lab Sample ID: N93379-5 Date Sampled: 03/15/05 Matrix:. AQ -Field Blank Water Date Received: 03/16/05 Method: SW846 8260B Percent Solids: n/a Project: PSEG, Hancock's Bridge, NJ VOA TCL List is CAS No. Compound 75-01-4 Vinyl chloride 1330-20-7 Xylene (total)CAS No. Surrogate Recoveries Result RL MDL Units Q ND ND 1.0 1.0 0.66 ug/l 0.17 ug/l Run# 1 Run# 2 Limits 1868-53-7 17060-07-0 2037-26-5 460-00-4 Dibromofluoromethane 1,2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene 85%104%87%115%79-119%68-129%83-118%82-120%ý110 ND = Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyle found in associated method blank N Indicates presumptive evidence of a compound En! 26 of 122 JUACCUTEST. N93379 ' :.: Raw Data: Pa Data 40:-.0 -Accutest Laboratories Report of Analysis Page 1 of 3 U1 Client Sample ID: FB-031505 Lab Sample ID: N93379-5 Date Sampled: 03/15/05 Matrix: AQ -Field Blank Water Date Received: 03/16/05 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEC, Hancock's Bridge, NJ File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 H74041.D 1 04/02/05 SSW 03/16/05 OP19692 EH3145 Run #2 Initial Volume Final Volume Run #1 1000 mi 1.0 ml Run #2 ABN TCL List CAS No. Compound Result RL MDL Units Q 95-57-8 2-Chlorophenol ND 5.0 4.3 ug/l 59-50-7 4-Chloro-3-methyl phenol ND 5.0 4.7 ug/]120-83-2 2,4-Dichlorophenol ND 5.0 0.73 ug/I 105-67-9 2,4-Dimethylphenol ND 5.0 1.0 ug/]51-28-5 2,4-Dinitrophenol ND 20 1.1 ug/l 534-52-1 4,6-Dinitro-o-cresol ND 20 0.65 ug/1 95-48-7 2-Methylphenol ND 5.0 0.72 ugll 3&4-Methylphenol ND 5.0 0.70 ug/l 88-75-5 2-Nitrophenol ND 5.0 0.73 ug/I 100-02-7 4-Nitrophenol ND 20 2.3 ug/l 87-86-5 Pentachlorophenol ND 20 0.75 ug/l 108-95-2 Phenol ND 5.0 1.8 ug/l 95-95-4 2,4,5-Trichlorophenol ND 5.0 0.74 ug/I 88-06-2 2,4,6-Trichlorophenol ND 5.0 0.80 ug/i 83-32-9 Acenaphthene ND 2.0 0.30 ug/l 208-96-8 Acenaphthylene ND 2.0 0.35 ug/1 120-12-7 Anthracene ND 2.0 0.22 ug/l 56-55-3 Benzo(a)anthracene ND 2.0 0.27 ug/l50-32-8 Benzo(a)pyrene ND 2.0 0.38 ug/h 205-99-2 Benzo(b)fluoranthene ND 2.0 0.37 ugl 191-24-2 Benzo(g,h,i)perylene ND 2.0 0.50 ug/l 207-08-9 Benzo(k)fluoranthene ND 2.0 0.37 ug/l 101-55-3 4-Bromophenyl phenyl ether ND 2.0 0.54 ug/l 85-68-7 Butyl benzyl phthalate ND 2.0 0.54 ug/l 91-58-7 2-Chloronaphihalene ND 5.0 0.38 ug/]106-47-8 4-Chiloroaniline ND 5.0 0.43 ug/l 86-74-8 Carbazole ND 2.0 0.34 ug/1 218-01-9 Chrysene ND 2.0 0.26 ugA 111-91-I bis(2-Chloroethoxy)methane ND 2.0 0,34 ug/l 111-44-4 bis(2-Chloroethyl)ether ND 2.0 0.49 ug/l 108-60-1 bis(2-Chloroisopropyl)ether ND 2.0 0.44 ug/I 7005-72-3 4-Chlorophenyl phenyl ether ND 2.0 1.0 ug/I ND = Not detected MDL -Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound anfi 27 of 122 1ACCLITEST. N-93379 -' * '! : .... Accutest Laboratories Report of Analysis Page 2 of 3 P Client Sample ID: FB-031505 Lab Sample ID: N93379-5 Matrix: AQ -Field Blank Water Method: SW846 8270C SW846 3510C Project: PSEG, Hancock's Bridge, NJ I'm Date Sampled: 03/15/05 Date Received: 03/16/05 Percent Solids: n/a ABN TCL List.CAS No. Compound Result RL MDL Units Q 46W 95:50-1 1,2-Dichilorobenzene 541-73-1 1,3-Dichlorobenzene 106-46-7 1,4-Dichlorobenzene 121-14-2 2,4-Dinitrotoluene 606-20-2 2,6-Dinitrotoluene 91-94-1 3,3'-Dichlorobenzidine 53-70-3 Dibenzo(a,h)anthracene 132-64-9 Dibenzofuran 84-74-2 Di-n-butyl phthalate 117-84-0 Di-n-octyl phthalate 84-66-2 Diethyl phthalate 131-11-3 Dimethyl phlthalate 117-81-7 bis(2-Ethylhexyl)phthala(e 206-44-0 Fluoranthene 86-73-7 Fluorene 118-74-1 Hexachlorobenzene 87-68-3 Hexachlorobutadiene 77-47-4 Hexachlorocyclopentadiene 67-72-1 Hexachloroethane 193-39-5 Indeno(1,2,3-cd)pyrene 78-59-1 Isophorone 91-57-6 2-Methylnaphthalene 88-74-4 2-Nitroaniline 99-09-2 3-Nitroaniline 100-01-6 4-Nitroaniline 91-20-3 Naphthalene 98-95-3 Nitrobenzene 621-64-7 N-Nitroso-di-n-propylamine 86-30-6 N-Nitrosodiphenylamine 85-01-8 Phenanthrene 129-00-0 Pyrene 120-82-1 1,2,4-Trichlorobenzene CAS No. Surrogate Recoveries 367-12-4 2-Fluorophenol 4165-62-2 Phenol-d5 118-79-6 2,4,6-Tribromophenol 4165-60-0 Nitrobenzene-d5 321-60-8 2-Fluorobiphenyl ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2.0 2.0 2.0 2.0 2.0 5.0 2.0 5.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 20 5.0 2.0 2.0 2,0 5.0 5.0 5.0 2.0 2.0 2.0 5.0 2.0 2.0 2.0 0.24 ug/l 0.32 ug/I 0.25 ug/1 0.78 ug/l 0.62 ug/l 0.39 ug/h 0.58 ug/l 0.49 ug/l 0.79 ug/I 0.63 ug/l 1.4 ug/I 0.58 ug8I0.74 ug/h 0.63 ug/I 0.89 ug/I 1.2 ug/1 0.41 ug/l 0.45 ug/0.67 ug/h 1.5 ug/h 0.54 ug/h 0.72 ug/h 1.4 ug/I 1.2 ug/i 1.1 ughI 1.0 ug/h 0.61 ug/l 0.50 ug/l 0.80 ug/I 0,23 ughl 0.58 ug/h 0.32 ug/I Run# 1 Run# 2 Limits 44%28%80%92%83%14-81%10-64%43-126%28-125%32-120%ND = Not detected MDL -Method Deteclion Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound f1!I 28 of 122~ACCLITFST. N93379 Accutest Laboratories tar Report of Analysis Page 3 of 3 ý4 Client Sample ID: FB-031505 Lab Sample ID: N93379-5 Date Sampled: 03/15/05 Matrix: AQ -Field Blank Water Date Received: 03/16/05 Method: SW846 8270C SW846 3510C Percent Solids: n/a Project: PSEG, Hancock's Bridge, NJ ABN TCL List CAS No. Surrogate Recoveries 1718-51-0 Terphenyl-d04 Run# 1 Run# 2 Limits 92%42-125%ND = Not detected MDL -Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound~121 29 of 122 12ACCU ItiES1 1,93379 ,5 -; Raw Data: Accutest Laboratories Report of Analysis Page 1 of 2Client Sample ID: TRIP BLANK Lab Sample ID: N93379-6 Date Sampled: 03/15/05 Matrix: AQ -Trip Blank Water Date Received: 03/16/05 Method: SW846 8260B Percent Solids: n/a Project: PSEG, Hancock's Bridge, NJ File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 A94449.D 1 03/22/05 NDJ n/a n/a VA2990 Run #2 Purge Volume Run#1 5.0 ml Run #t2 VOA TCL List CAS No. Compound Result RL MDL Units Q 67-64-1 Acetone ND 10 2.3 ug/l 71-43-2 Benzene ND 1.0 0.31 ug/l 75-27-4 Bromodichloromethane ND 1.0 0.11 ug/l 75-25-2 Bromoform ND 4.0 0.17 ug/1 74-83-9 Bromomethane ND 2.0 0.15 ug/l 78-93-3 2-Butanone (MEK) ND 10 2.5 ug/]75-15-0 Carbon disulfide ND 2.0 0.23 ug/l 56-23-5 Carbon letrachloride ND 1.0 0.15 ug/l 108-90-7 Chlorobenzene ND 1.0 0.23 ug/h 75-00-3 Chloroethane ND 1.0 0.73 ug/l 67-66-3 Chloroform ND 1.0 0,081 ug/1 74-87-3 Chloromethane ND 1.0 0.13 ug/I 124-48-1 Dibromochloromechane ND 1.0 0.18 ug/l 75-34-3 1,1-Dichloroethane ND 1.0 0.13 ug/I 107-06-2 1,2-Dichloroethane ND 1.0 0.35 ug/l 75-35-4 1,1-Dichloroethene ND 1.0 0.81 ug/l 156-59-2 cis- 1,2-Dichloroethene ND 1.0 0.24 ug/l 156-60-5 trans-i ,2-Dichloroethene ND 1.0 0.17 ug/l 78-87-5 1,2-Dichloropropane ND 1.0 0.11 ug/I 10061-01-5 cis- I,3-Dichloropropene ND 1.0 0.071 ug/h 10061-02-6 trans-1,3-Dichloropropene ND 1.0 0.080 ug/l 100-41-4 Ethylbenzene ND 1.0 0.27 ug/l 591-78-6 2-Hexanone ND 5.0 0.73 ug/I 108-10-1 4-Methyl-2-pentanone(MIBK) ND 5.0 0.59 ug/h 75-09-2 Methylene chloride ND 2.0 0.20 ug/l 100-42-5 Styrene ND 5.0 0.12 ug/h 79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.14 ug/127-18-4 Tetrachloroethene ND 1.0 0.37 ughI 108-88-3 Toluene ND 1.0 0.14 ug/h 71-55-6 1,1,1-Trichloroethane ND 1.0 0.25 ug/l 79-00-5 1,1,2-Trichloroethane ND 1.0 0.17 ug/1 79-01-6 Trichloroethene ND 1.0 0.13 ug/l ND = Not detected MDL -Method Detection Limit J Indicates an estimated value RL = Reporting Limit B Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N Indicates presumptive evidence of a compound30 of 122 QACCTEST N93379 Accutest Laboratories Report of Analysis Page 2 of 2 Client Sample ID: TRIP BLANK Lab Sample ID: N93379-6 Date Sampled: 03/15/05 Matrix: AQ -Trip Blank Water Date Received: 03/16/05 Method: SW846 8260B Percent Solids: n/a Project: PSEG, Hancock's Bridge, NJ VOA TCL List!-0 cr)0'.CAS No. Compound 75-01-4 Vinyl chloride 1330-20-7 Xylene (total)CAS No. Surrogate Recoveries Result RL MDL Units Q ND ND 1.0 1.0 0.66 ugh 0.17 ugh]RunO I Run# 2 Limits 1868-53-7 17060-07-0 2037-26-5 460-00-4 Dibromofluoromethane 1,2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene 86%107%87%117%79-119%68-129%83-118%82-120%ND Not detected MDL -Method Detection Limit RL Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N -Indicates presumptive evidence of a compound SO 31 of122 U ACCUrrEM-I-Accutest LaboratoriesMisc. Forms Custody Documents and Other Forms includes the following where applicable:
- Chain of Custody-Sample Tracking Chronicle-Internal Chain of Custody 4W Efl 32 of 122 UACCUrEST.
N93379 LoACCUTEoT. L ab o r at o r i e CHAIN OF CUSTOD'TEL., 3M 329-0200 FAN: 732-329-34"(430 ,flrw ".*CUL;SO FED-Ex lswm P_______OW._______F '79ap g~ia 01or VA~d e~l -1 11 1,19 FA-ul It) D Pvlima1Gsii~m-l'/ 5UwiII 0i " Nu' ofl hp -~r W'*,"' ia/'o ' " ,k' Pth0, O 2 ,, i I"T,%-; ,. Dr, I T.. _______ LAI i_ _ _ _ _3.,Kqp RO1 W 13 1 1aW P I I Ih x- I -I Ig %-'~II [too I I x I We-I L 151 ig00 RUSH CT cart HY_ A SP j3"O k A SP Z _E- d.° -- o ,, WO SI S i Wl~ , -X .~ -m w.....: o'I&111 p-I I 411 N93379: Chain of Custody Page 1 of 1 far f'li 33 of 122 lACCUTEST N93379 Accutest Laboratories Internal Sample Tracking Chronicle Arcadis Geraghty & Miller PSEG, Hancock's Bridge, NJ Sample Number Method Analyzed By Prepped By Test Codes N93%9-,.1. 1 Cl w-d 15-M`A R.-0p5 '0 9. 05 By YPPC WELLY.':5B:R~ eevd.~MR N93379-1 SW846 8260B 22-MAR-05 05:13 NDJ V8260TCL N93379-1 SW846 8270C 02-APR-05 03:12 SSW 16-MAR-05 RL AB8270TCL.N93379 Conected:i & 5 11:00 B751RDM 5 WEDLLX N93379-2 SW846 8260B 22-MAR-05 05:43 NDJ VS260TCLN93379-2 SW846 8270C 02-APR-05 03:46 SSW 16-MAR-05 RL AB8270TCL N93379-15-MAR-05 13:12 By:- RDMK "Receive.d::..16-.MAR-05 By: MPG.( ' .W.ELL. AV, >N93379-3 SW846 8260B 22-MAR-05 06:27 NDJ V8260TCLN93379-3 SW846 8270C 02-APR-05 04:31 SSW 16-MAR-05 RL AB8270TCL N93379-4 Colle0cted: '15.-.M-A 05.14:25 :By.: RDM.. Re'eived.: 16-MA:R0 By: .MPCN93379-4 SW846 8260B 22-MAR-05 06:57 NDJ V8260TCLN93379-4 SW846 8270C 02-APR-05 05:01 SSW 16-MAR-05 RL AB8270TCL N93'3795 CoiJeced:" 5' MAROS 14: 05 By: RDM" Receiv I: 6-MAR-05 By: M.-FB-0)315 5 f: N93379-5 SW846 8260B 22-MAR-05 07:26 NDJ V8260TCL N93379-5 SW846 8270C 02-APR-05 05:45 SSW 16-MAR-05 RL AB8270TCL N933796. Collected:.15-MAR-05 14:25 By: RDM::: Receied: MAR05 B'y: MPC;.TRIP.BLANK N93379-6 SW846 8260B 22-MAR-05 07:56 NDJ V8260TCL Page] ofI tlrj 34 of 122 IACCU ESI N9337 . Accutest Internal Chain of CustodyJob Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Received: 03/16/05 Page 1 of 2 Sample.Bottle Transfer Transfer Number FROM TO Date/Time Reason N93379-1.2 Secured Storage N93379-1.2 Karl M. Ros1o N93379-1.2.1 N93379-1.2.1 N93379-1.2.1 N93379-1.3 N93379-1.3 N93379-1 3 N93379-1.3 Karl M. Rosko Organics Prep Karl M. Rosko Secured Storage Naresh Jadeja GCMSA Naresh Jadeja N93379-2.2 Secured Storage N93379-2.2 Karl M. Rosko N93379-2.2.1 N93379-2.2.1 N93379-2.2.1 N93379-2.3 N93379-2.3 N93379-2.3 N93379-2.3 Karl M. Rosko Organics Prep Karl M. Rosko Secured Storage Naresh Jadeja GCMSA Naresh Jadeja'V Karl M. Rosko Organics Prep Karl M. Rosko Extract Storage Naresh Jadeja GCMSA Naresh JadejaSecured Storage Karl M. Rosko Organics Prep Karl M. RoskoExtract Storage Naresh Jadeja GCMSA Naresh JadejaSecured Storage Karl M. Rosko Organics Prep Karl M. Rosko Extract Storage Naresh Jadeja GCMSA Naresh Jadeja Secured Storage Karl M. Rosko Organics Prep Karl M. Rosko Extract Storage Naresh Jadeja 03/16/05 16:51 03/16/05 20:08 03/16/05 20:08 03/21/05 16:36 03/21/05 16:36 03/22/05 16:34 03/22/05 16:34 03/16/05 16:51 03/16/05 20:08 03/16/05 20:08 03/21/05 16:36 03/21/05 16:36 03/22/05 16:34 03/22/05 16:34Extract from N93379-2.2Extract from N93379-2.2 Return to StorageRetrieve from Storage Load on Instrument Unload from Instrument Return to Storage 03/16/05 16:51 Retrieve from Storage 03/16/05 20:07 Depleted Extract from N93379-1.2 Extract from N93379-1.2 Return to Storage Retrieve from Storage Load on Instrument Unload from Instrument Return to Storage 03/16/05 16:51 Retrieve from.Storage 03/16/05 20:07 Depleted N93379-3.2 Secured Storage N93379-3.2 Karl M. Rosko 03/16/05 16:51 Retrieve from Storage 03/16/05 20:07 Depleted N93379-3.2.1 N93379-3,2.1 N93379-3.2.1 N93379-3.4 N93379-3.4
N93379-3.4 N93379-3.4 Karl M. Rosko Organics Prep Karl M. Rosko Secured Storage Naresh Jadeja GCMSA Naresh Jadeja 03/16/05 16:51 03/16/05 20:08 03/16/05 20:08 03/21/05 16:36 03/21/05 16:36 03/22/05 16:34 03/22/05 16:34Extract from N93379-3.2Extract from N93379-3.2 Return to StorageRetrieve from Storage Load on Instrument Unload from Instrument Return to Storage N93379-4.1 Secured Storage N93379-4.1 Karl M. Rosko 03/16/05 16:51 Retrieve from Storage 03/16/05 20:07 Depleted N93379-4.1.1 N93379-4.1.1 N93379-4.1.1 Karl M. Rosko Organics Prep Karl M. Rosko 03/16/05 16:51 03/16/05 20:08 03/16/05 20:08 Extract from N93379-4,1 Extract from N93379-4.1 Return to Storage N93379-4.4 Secured Storage 03/21/05 16:36 Retrieve from Storage Eon 35 of 122~ACCýiTES N93379 'p, Accutest Internal Chain of Custody Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Received: 03/16/05Page 2 of 2 Sample. Bottle Number N93379-4.4 N93379-4.4 N93379-4.4 Transfer FROM Transfer TODate/Time Reason Naresh Jadeja GCMSA Naresh Jadeja N93379-5.2 Secured Storage N93379-5.2 Karl M. Rosko N93379-5.2.1 N93379-5.2.1 N93379-5.2.1 N93379-5.4 N93379-5.4 N93379-5.4 N93379-5.4 N93379-6.3 N93379-6.3
N93379-6.3 N93379-6.3 Karl M. Rosko Organics Prep Karl M. Rosko Secured StorageNaresh Jadeja GCMSA Naresh Jadeja Secured Storage Naresh Jadeja GCMSA Naresh Jadeja GCMSA Naresh Jadeja Secured Storage Karl M. Rosko Organics Prep Karl M. Rosko Extract Storage Naresh Jadeja GCMSA Naresh Jadeja Secured Storage Naresh Jadeja GCMSA Naresh Jadeja Secured Storage 03/21/05 16:36 03/22/05 16:34 03/22/05 16:34 03/16/05 16:51 03/16/05 20:08 03/16/05 20:08 03/21/05 16:36 03/21/05 16:36 03/22/05 16:34 03/22/05 16:34 03/21/05 16:36 03/21/05 16:36 03/22/05 16:34 03/22/05 16:34 Extract from N93379-5.2 Extract from N93379-5.2 Return to Storage Retrieve from Storage Load on Instrument Unload from Instrument Return to StorageRetrieve from Storage Load on Instrument Unload from Instrument Return to Storage Load on InstrumentUnload from Instrument Return to Storage 03/16/05 16:51 Retrieve from Storage03/16/05 20:07 Depleted ýAv Eln 36 of 122N91 379 --; -' :'-'
- Accutest Laboratories GC/MS Volatiles QC Data Summaries Includes the following where applicable:
- Method Blank Summaries* Blank Spike Summaries* Matrix Spike and Duplicate Summaries* Instrument Performance Checks (BFB)* Internal Standard Area Summaries
- Surrogate Recovery Summaries I Initial and Conlinuing Calibration Summaries Ml-j 37 of122 12ACCUTTEST.
N92337 1 , '-. Method Blank SummaryJob Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 1 of 2 (kvSample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch VA2990-MBI A94436.D 1 03/22/05 NDJ n/a n/a VA2990 U, The QC reported here applies to the following samples: N93379-1, N93379-2, N93379-3, N93379-4, N93379-5, N93379-6 Method: SW846 8260B CAS No. Compound 67-64-1 Acetone 71-43-2 Benzene 75-27-4 Bromodichloromethane 75-25-2 Bromoform 74-83-9 Bromomethane78-93-3 2-Butanone (MEK)75-15-0 Carbon disulfide 56-23-5 Carbon tetrachloride 108-90-7 Chlorobenzene 75-00-3 Chloroethane 67-66-3 Chloroform 74-87-3 Chloromethane 124-48-1 Dibromochloromethane 75-34-3 1,l-Dichloroethane 107-06-2 1,2-Dichloroethane 75-35-4 1,] -Dichloroethene 156-59-2 cis-1,2-Dichloroethene 156-60-5 trans-i ,2-Dichloroethene 78-87-5 1,2-Dichloropropane 10061-01-5 cis-1,3-Dichloropropene 10061-02-6 trans- ,3-Dichloropropene 100-41-4 Ethylbenzene 591-78-6 2-Hlexanone 108-10-1 4-Methyl-2-pentanone(Ml BK)75-09-2 Methylene chloride100-42-5 Styrene 79-34-5 1,],2,2-Tetrachloroethane 127-18-4 Tetrachloroethene 108-88-3 Toluene 71-55-6 1,1,1-Trichloroethane 79-00-5 1, 1,2-Trichloroethane 79-01-6 Trichloroethene 75-01--4 Vinyl chloride 1330-20-7 Xylene (total)Result RL MDL Units Q 10 1.0 1.0 4.0 2,0 10 2.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 2.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 2.3 ug/l 0.31 ug/l 0.11 ug/l 0.17 ug/l 0,15 ug/1 2.5 ugh 0.23 ug/l 0.15 ug/l 0.23 ug/l 0.73 ug/l0.081 ug/l 0.13 ug/l 0.18 ug/l 0.13 ug/l 0.35 ug/l 0.81 ug/1 0,24 ug/l 0.17 ug/l 0.11 ug/l 0.071 ug/l 0.080 ug/l 0.27 ug/l 0.73 ug/l 0.59 ug/1 0.20 ug/l 0.12 ug/l 0.14 ug/t 0.37 ug/l0.14 ug/l 0.25 ug/l 0.17 ug/I 0.13 ug/]0.66 ug/l 0.17 ug/]M1tJ 38o1122 Q ACCUrrEST. N9337S Method Blank Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 2 of 2 Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch VA2990-MBI A94436.D 1 03/22/05 NDJ n/a n/a VA2990 (11 The QC reported here applies to the following samples: N93379-1, N93379-2, N93379-3, N93379-4, N93379-5, N93379-6 Method: SW846 8260B CAS No. Surrogate Recoveries 1868-53-7 17060-07-0 2037-26-5 460-00-4 Dibromofluoromethane 1,2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene 84%100%86%113%Limits 79-119%68-129%83-118%82-120%CAS No. Tentatively Identified Compounds R.T.Est. Conc. Units Q Total TIC, Volatile 0 ug/1 E 39 of122 12ACCUTEZST. N93379 Blank Spike Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 1 of 2 Sample File ID DF VA2990-BS A94442.D 1 Analyzed By 03/22/05 NDJ Prep Date Prep Batch Analytical Batch n/a n/a VA2990 M18 Method: SW846 8260B The QC reported here applies to the following samples: N93379-1, N93379-2, N93379-3, N93379-4, N93379-5, N93379-6 CAS No. Compound Spike BSP BSP ug/i ug/l %Limits 0&67-64-]' Acetone 50 71-43-2 Benzene 50 75-27-4 Bromodichloromethane 50 75-25-2 Bromoform 50 74-83-9 Bromomethane 50 78-93-3 2-Butanone (MEK) 50 75-15-0 Carbon disulfide 50 56-23-5 Carbon letrachloride 50 1 08-90-7 Chlorobenzene 50 75-00-3 Chloroethane 50 67-66-3 Chloroform 50 74-87-3 Chloromethane 50 124-48-1 Dibromochloromethane 50 75-34-3 1,1 -Dichlioroethane 50 107-06-2 1,2-Dichloroethane 50 75-35-4 1,1-Dichloroethene 50 156-59-2 cis-l,2-Dichloroethene 50 156-60-5 trans-1,2-Dichloroethene 50 78-87-5 1,2-Dichloropropane 50 10061-01-5 cis- 1,3-Dichloropropene 50 10061-02-6 (rans-1, 3-Dichloropropene 50 100-41-4 Ethylbenzene 50 591-78-6 2-Hexanone 50 108-10-1 4-Methyl-2-pentanone (MIBK) 50 75-09-2 Methylene chloride 50 100-42-5 Styrene 50 79-34-5 1,1,2,2-Tetrachloroedhane 50 127-18-4 Tetrachloroethene 50 108-88-3 Toluene 50 71-55-6 1,1,1-Trichloroethane 50 79-00-5 1, 1,2-Trichloroethane 50 79-01-6 Trichloroethene 50 75-01-4 Vinyl chloride 50 1330-20-7 Xylene (total) 150 61.3 50.0 55.8 54.6 60.7 48.0 57.3 62.4 51.6 56.3 52A 66.6 54.8 50.5 68.2 50.0 44.3 46.9 50.8 48.5 51.1 55.6 53.5 53.1 48.9 55.8 53.3 52.7 49.8 54.6 49.7 53.2 63.2 158 123 53-153 100 77-119 112 82-126 109 73-135 121 61-13896 58-142 115 60-130 125 72-140 1:03 81-117 113 69-135 105 80-122 133* a 59-132 110 80-125 101 78-121 136 66-137 100 73-124 89 76-120 94 73-119 102 82-117 97 81-120 102 81-125 111 79-120 107 66-140 106 70-134 98. 75-122 112 80-125 107 76-117 105 69-130 100 81-120 109 77-132 99 85-117 106 83-119 126 65-135 105 81-119&W En1I 40 of 122 N3 ACCUTEST.N93379 .1- -1 I. ,. Blank Spike Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 2 of 2 Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch VA2990-BS A94442.D 1 03/22/05 NDJ n/a n/a VA2990 N)The QC reported here applies to the following samples: N93379-1, N93379-2, N93379-3, N93379-4, N93379-5, N93379-6 Method: SW846 8260B CAS No. Surrogate Recoveries 1868-53-7 Dibromofluoromethane 17060-07-0 1,2-Dichloroethane-D4 2037-26-5 Toluene-D8 460-00-4 4-Bromofluorobenzene BSP 85%103%91%108%Limits 79-119%68-129%83-118%82-120%(a) High percent recoveries and no associated positive found in the QC batch.En~ 41 o1 122 t2ACCU ITS N93379 41W Matrix Spike Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 1 of 2Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch N93391-4MS A94451.D 1 03/22/05 NDJ n/a n/a VA2990 N93391-4 A94440.D 1 03/22/05 NDJ n/a n/a VA2990 To T he QC reported here applies to the following samples: Method: SW846 8260B N93379-1, N93379-2, N93379-3, N93379-4, N93379-5, N93379-6 N93391-4 Spike MS ug/h Q ugh ug/l MS CAS No. Compound Limits 4kv 67-64-1 Acetone ND 71-43-2 Benzene ND 75-27-4 Bromodichloromethane ND 75-25-2 Bromoform ND 74:83-9 Bromomethane ND78-93-3 2-Butanone (MEK) ND 75-15-0 Carbon disulfide ND 56-23-5 Carbon tetrachloride ND 308-90-7 Chlorobenzene ND 75-00-3 Chloroethane ND 67-66.3 Chloroform 0.64 74-87-3 Chloromethane ND 124-48-1 Dibromochloromethane ND 75-34-3 1, 1-Dichloroethane ND 107-06-2 1,2-Dichloroethane ND 75-35-4 1,1-Dichloroethene ND 156-59-2 cis-1,2-Dichloroethene 1.4 156-60-5 trans-I, 2-Dich)oroelhene ND 78-87-5 1,2-Dichloropropane ND 10061-01-5 cis- 1,3-Dichloropropene ND10061-02-6 trans-1,3-Dichloropropene ND 100-41-4 Ethylbenzene ND 591-78-6 2-Hexanone ND 108-10-1 4-Methyl-2-pentanone(MIBK) ND75-09-2 Methylene chloride ND100-42-5 Styrene ND 79-34-5 1,1,2,2-Tetrachloroethane ND 127-18-4 Tetrachloroethene 13.6 108-88-3 Toluene ND 71-55-6 1,1 ,1-Trichloroethane ND 79-00-5 1,1,2-Trichloroethane ND 79-01-6 Trichloroethene 1.4 75-01-4 Vinyl chloride ND1330-20-7 Xylene (Iota)) ND 50 50 50 50 50 50 50 50 50 50 J 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 150 58.8 46.5 53.6 51.0 55.9 47.6 53.0 61.7 48.7 51.3 51.3 57.4 52.9 49.1 66.0 46.9 45.4 44.4 49.4 45.6 49.6 51.0 51.7 51.8 45.3 48.6 50.9 64.2 46.4 54.0 48.2 53.3 57.3 147 118 47-163 93 51-138 107 80-128 102 68-137 112 61-141 95 55-149 106 59-128 123 71-143 97 78-120 303 67-139 101 78-126 115 57-134 106 79-127 98 75-125 132 63-142 94 69-129 88 73-127 89 71-123 99 81-120 91 78-121 99 77-128 102 51-142 103 64-145 104 66-140 91 73-126 97 79-130 102 74-121 101 70-128 93 49-147 108 74-136 96 83-321 104 75-128 115 60-141 98 44-146 ho WrJ 42 of 122 SACCU IESTI N9337S ... ..'. . Matrix Spike Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 2 of 2 Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch N93391-4MS A94451.D 1 03/22/05 NDJ n/a n/a VA2990 N93391-4 A94440.D 1 03/22/05 NDJ n/a n/a VA2990 CA>The QC reported here applies to the following samples: N93379-1, N93379-2, N93379-3, N93379-4, N93379-5, N93379-6 Method: SW846 8260B CAS No. Surrogate Recoveries MS N93391-4 Limits 1868-53'7 17060-07-0 2037-26-5 460-00-4 Dibromofluoromethane 1 ,2-Dichloroechane-D4 Toluene-D8 4-Bromofluorobenzene 85%105%90%107%86%107%87%116%79-119%68-129%83-118%82-120%*WV to 9n 43 of122 12ACCUTrES-r. N93379 :is: 1,I-. Duplicate Summary Page 1 of 2 Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch N93391-3DUP A94450.D 1 03/22/05 NDJ n/a n/a VA2990 N93391-3 A94439.D 1 03/22/05 NDJ n/a n/a VA2990 The QC reported here applies to the following samples: Method: SW846 8260B N93379-1, N93379-2, N93379-3, N93379-4, N93379-5, N93379-6 N93391-3 DUP CAS No. Compound ug/l Q ug/l Q RPD Limits 67-64-1 Acetone ND ND nc 10 71-43-2 Benzene ND ND nc 17 75-27-4 Bromodichloromethane ND ND nc 10 75-25-2 Bromoform ND ND nc 10 74-83-9 Bromomethane ND ND nc 10 78-93-3 2-Butanone (MEK) ND ND nc 10 75-15-0 Carbon disulfide ND ND nc 10 56-23-5 Carbon tetrachloride ND ND nc 10 108-90-7 Chlorobenzene ND ND nc 10 75-00-3 Chloroethane ND ND nc 10 67-66-3 Chloroform 4.6 4.6 0 10 74-87-3 Chloromeihane ND ND nc 10 124-48-1 Dibromochloromethane ND ND nc 10 75-34-3 1,1-Dichloroethane ND ND nc 10 107-06-2 1,2-Dichloroethane ND ND nc 10 75-35-4 1,1-Dichloroethene ND ND nc 10 156-59-2 cis-1,2-Dichloroethene ND ND nc 10 156-60-5 trans-1,2-Dichloraethene ND ND nc .10 78-87-5 1,2-Dichloropropane ND ND nc 10 10061-01-5 cis-1,3-Dichloropropene ND ND nc 10 10061-02-6 trans-1,3-Dichloropropene ND ND nc 10 100-41-4 Elhylbenzene ND ND nc 19 591-78-6 2-Hexanone ND ND nc 10 108-10-1 4-Methyl-2-pentanone(M]BK) ND ND nc 10 75-09-2 Methylene chloride ND ND nc 10 100-42-5 Styrene ND ND nc 10 79-34-5 1,1,2,2-Teirachloroethane ND ND nc 10 127-18-4 Tetrachloroethene ND ND nc 10 108-88-3 Toluene ND ND nc 19 71-55-6 1,1,1-Trichloroethane ND ND nc 10 79-00-5 1,1,2-Trichloroethane ND ND nc 10 79-01-6 Trichloroethene ND ND nc 10 75-01-4 Vinyl chloride ND ND nc 10 1330-20-7 Xylene (total) ND ND nc 16 O'l 44 of 122 1 ACCUTEST.N93379 Duplicate Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 2 of 2 Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch N93391-3DUP A94450.D 1 03/22/05 NDJ n/a n/a VA2990 N93391-3 A94439.D 1 03/22/05 NDJ n/a n/a VA2990 The QC reported here applies to the following samples: N93379-1, N93379-2, N93379-3, N93379-4, N93379-5, N93379-6 Method: SW846 8260B CAS No. Surrogate Recoveries 1868-53-7 17060-07-0 2037-26-5 460-00-4 Dibromofluoromethane 1,2-Dichloroeihane-D4 Toluene-D8 4-Bromofluorobenzene DUP 87%109%87%115%N93391-3 Limits 86% 107%87%115%79-119% 68-129% 83-118%82-120%%'0 OW E0145of 122 V ACCLITEST. N9337S -!- % -!-, Instrument Performance Check (BFB) Page 1 of I Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Sample: VA2955-BFB Injection Date: 02/28/05 Lab File ID: A93585.D Injection Time: 13:43 Instrument ID: GCMSA Raw % Relative m/e Ion Abundance Criteria Abundance Abundance Pass/Fail 15.0 -40.0% of mass 95 6075 16.2 Pass 75 30.0 -60.0% of mass 95 16435 43.9 Pass 95 Base peak, 100% relative abundance 37405 100.0 Pass 96 5.0 -9.0% of mass 95 2582 6-9 Pass 173 Less than 2.0% of mass 174 0 0.0 (0.0) 1 Pass 174 50,0 -150.0% of mass 95 37288 99.7 Pass 175 5.0 -9.0% of mass 174 2670 7.1 (7.2) 8 Pass 176 95.0 -101.0% of mass 174 36416 97.4 (97.7) a Pass 177 5.0 -9.0% of mass 176 2428 6.5 (6.7) b Pass (a) Value is % of mass 174 (b) Value is % of mass 176 This check applies to the following Samples, MS, MSD. Blanks, and Standards; Lab Lab Date Time Hours Client Sample ID File ID Analyzed Analyzed Lapsed Sample ID VA2955-1C2955 A93586.D 0Z/28/05 14:14 00:31 Initial cal I VA2955-1C2955 A93587.D 02/28/05. 14:44 01:01 Initial cal 2 VA2955-1C2955 A93588.D 02/28/05 15:13 01:30 Initial cal 5 VA2955-IC2955 A93589.D 02/28/05 15:40 01:57 Initial cal 20 VA2955-1CC2955 A93590,D 02/28/05 16:21 02:38 Initial cal 50 VA2955-1C2955 A93591..D 02/28/05 16:50 03:07 Initial cal 100 VA2955-IC2955 A93592.D 02/28/05 17:17 03:34 Initial cal 200 I 46of12.13 ACC :TE:. ...N93375 ,' Instrument Performance Check (BFB) Page I of I Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Sample: VA2990-BFB Injection Date: 03/21/05 Lab File ID: A94433.D Injection Time: 23:18 Instrument ID: GCMSA Raw % Relative m/e Jon Abundance Criteria Abundance Abundance Pass/Fail 50. 14.95 -40.0% of mass 95 9949 .20.5 Pass 75 30.0 -60.0% of mass 95 24779 51.2 Pass 95 Base peak, 100% relative abundance 48440 00;0 Pass 96 5.0 -9.0% of mass 95 3309 6.8 Pass 173 Less than 2.0% of mass 174 0 0.0 00.8)a Pass 174 50.0 -150.0% of mass 95 48235 99.6 Pass 175
- 5.0 -9.0% of mass 174 3419 7.1 (7A)a Pass 176 95.0 -101.0% of mass 174 47427 97.9 .(98.3) a Pass 177 5.0 -9.0% of mass 376 3074 6.3 (6.5) b Pass (a) Value is % of mass 174 (b) Value is % of mass 176 This check applies to the following Samples, MS, MSD, Blanks, and Standards:
Lab Lab Date Time Hours Client Sample ID File ID Analyzed Analyzed Lapsed Sample ID VA2990-CC2955 A94434,D 03/22/05 00:18 01:00 Continuing cal 20 VA2990-MB1 A94436.D 03/22/05 01:17 01:59 Method Blank ZZZZZZ A94437.D 03/22/05 01:46 02:28 (unrelated sample)ZZZZZZ A94438.D 03/22/05 02:16 02:58 (unrelated sample)N93391-3 A94439.D 03/22/05 02:45 03:27 (used for QC only; not part of job N93379)N93391-4 A94440.D 03/22/05 03:15 03:57 (used for QC only; not part of job N93379)ZZZZZZ A9444 1 .D 03/22/05 03:44 04:26 (unrelated sample)VA2990-BS A94442.D 03/22/05 04:14 04:56 Blank Spike N93379-1 A94444.D 03/22/05 05:13 05:55 WELL AY N93379-2 A94445.D 03/22/05 05:43 06:25 WELL X N93379-3 A94446.D 03/22/05 06:27 07:09 WELL AV N93379-4 A94447.D 03/22/05 06:57 07:39 WELL AVD N93379-5 A94448.D 03/22/05 07:26 08:08 FB-031505 N93379-6 A94449.D 03/22/05 07:56 08:38 TRIP BLANK N93391-3DUP A94450.D 03/22/05 08:26 09:08 Duplicate N93391-4MS A94451..D 03/22/05 08:56 09:38 Matrix Spike ZZZZZZ A94452.D 03/22/05 09:30 10:12 (unrelated sample)ft 47 of 122*ACCUTEST. N93379 Volatile Internal Standard Area Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 1 of 1 Check Std: VA2990-CC2955 Lab File ID: A94434.D Instrument ID: GCMSA Injection Date: 03/22/05 Injection Time: 00:18 Method: SW846 8260B U, a)IS1 IS2 IS3 IS4 IS5 AREA RT AREA RT AREA RT AREA RT AREA RT Check Std 104408. 6.77 124013 9.17 162300 10.11 168719 13.57 .111994 16.21 Upper Limit 208816 7.27 248026 9.67 324600 10.61 337438 14.07 223988 16.71 Lower Limit b 52204 6.27 62007 8.67 81150 9.61 84360 13.07 55997 15.71 Lab" Sample ID VA2990-MBI zzzzzz zzzzzz N93391-3 N93391-4.zzzzzz VA2990-BS N93379-1 N93379-2 N93379-3 N93379-4 N93379-5 N93379-6 N93391-3DUP N93391-4MS zzzzzz IS1 is 2 IS 3 IS 4 AREA RT AREA RT AREA RT AREA 105413 6.77 119136 9.17 158088 10.11 161683 106544 6.77 120487 9.17 159851 10.11 162976 101009 6.77 113642 9.17 149861 10.11 155384 102054 6.78 107192 9.17 144510 10.11 149685 102275 6.77 111983 9.17 148004 10.1] 152869 98502 6.77 100182 9.17 134733 10.11 139055 96311 6.77 108558 9.17 143936 10.11 154216 103014 6.77 110179 9.17 146955 10.11 151089 98730 6..77 102885 9,17 137953 10.11 141938 95007 6.77 103245 9.17 137633 10.11 142913 101322 6.76 107547 9.17 144383 10.11 148737 104607 6.77 116729 9.17 153426 10.11 157916 95564 6.77 106370 9.17 141632 10.11 146081 95675 6.76 103827 9.17 139325 10.11 140637 99590 6.77 107518 9.17 143585 10.11 153351 103285 6.76 108881 9.17 144765 10.11 151678 IS 5 RT AREA RT 13.56 97691 13.56 97706 13.56 92146 13,57 88975 13.57 90854 13.56 82147 13.57 105177 13.57 90934 13.56 89222 13.57 92848 13.57 96926 13.57 94260 13.56 86401 13.56 84821 13.56 104312 13.56 97406 16.21 16.21 16.21 16.21 16.21 16.21 16.21 16.20 16.21 16.20 16.21 16.21 16.21 16.21 16.20 16.20 IS IIS 2IS 3 154IS 5= Tert Butyl Alcohol-D9 = Pentafluorobenzene = 1 ,4-Difluorobenzene = Chlorobenzene-D5= 1,4-Dichlorobenzene-d4 (a) Upper Limit = + 100% of check standard area; Retention time +0.5 minutes.(b) Lower Limit -50% of check standard area; Retention time -0.5 minutes.fjtI 48 of 122 9 "ACC 'TEST. N9331.9 --: ,"--.; Volatile Surrogate Recovery Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 1 of I Method: SW846 8260B Matrix: AQ Samples and QC shown here apply to the above method 4 Lab Sample ID N93379-1 N93379-2 N93379-3 N93379-4 N93379-5 N93379-6 N93391-3DUP N93391:4MS VA2990-BS VA2990-MBI Lab File ID A94444.D A94445.D A94446.D A94447.D A94448.D A94449.D A94450,D A94451 .D A94442.D A94436.D S1 S2 S3 S4 87.0 88.0 87.0 87.0 85.0 86.0 87.0 85.0 85.0 84:0 107.D 110.0 110.0 107.0 104.0 107.0 109.0 105.0 103.0 100.0 87.0.87.0 87.0 87.0 87.0 87.0 87.0 90.0 91.0 86.0 113.0 111,0 108.0 108,0 115.0 117.0 115.0 107.0 108.0 113.0 Surrogate Compounds SI = Dibromofluoromethane S2 = 1,2-Dichloroethane-D4 S3 = Toluene-D8 S4 = I-Bromofluorobenzene Recovery Limits 79-119%68-129%83-118%82-120%El 49 of 122 t2ACCU IES I N93379 'a Initial Calibration Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 1 of 3 Sample: VA2955-ICC2955 Lab FilelD: A93590.D 4w Response Factor Report MSA Method Title Last Update Response via C:\HPCHEM\1\METHODS\MA2955.M (RTE Integrator) SW-846 Method 8260 Tue Mar 01 09:35:12 2005 Initial Calibration Calibration Files 5 =A93588.0 2 100 =A93591.D 1=A93587.D 20 =A93589.D=A93586.D 200 =A93592.D 50 =A93590.D Compound 5 2 20 50 100 1 200 Avg %RSD 1) I Tert Butyl Alcohol-d9
ISTD --------------------- 2)M ethanol 0.062 0.095 0.071 0.078 0.065 0.057 0.060 0.070 18.86 SLinear regression
Coefficient 0.9948 Response Ratio = 0.04349 + 0.06062 *A 3)M tertiary butyl at 0.883 0.824 0.802 0.876 0.867 0.825 0.873 0.850 3.78 kaw 4) I pentafluorobenzene 5)M chlorodifluoromet 0.685 6)M dichlorodifluorom 0.593 7)M chloromethane 0.713 8)M vinyl chloride 0.693 9)M bromomethane 0.542 IO)M chloroethane 0,432 11)M trichlorofluorome 0.899 12)M ethyl ether 0.314 13)M acrolein 0.082 14)M 1,1-dichloroethen 0.576 15)M acetone 0.248 16)M allyl chloride 0.360 17)M acetonitrile 0.068 18)M iodomethane 1.183 19)M iso-butyl alcohol 0.018 20)M carbon disulfide 1.769 21)M methylene chlorid 0.641 22)M methyl acetate 0.562 23)M methyl tert butyl 1.918 24)M trans-1,2-dichlor 0.620 25)M di-isopropyl ethe 1.463 26)M ethyl tert-butyl 1.448 27)M 2-butanone 0.155 28)M 1,1-dichloroethan 0.722 29)M chloroprene 0.502 30)M acrylonitrile 0.248 31)M vinyl acetate 0:066 32)M ethyl acetate 0.055 33)M 2,2-dichloropropa 0.650 34)M cis-1,2-dichloroe 0.455 35)M propionitrile 0.064 36)M bromochloromethan 0.228 37)M tetrahydrofuran 0.135 38)M chloroform 0.726 39)S dibromofluorometh 0.560 40)S 1,2-dichloroethan 0,573 41)M freon 113 0.522 42)M methacrylonitrile 0.270 0.659 0.463 0.657 0.609 0.477 0,412 0.756 0.293 0,073 0.579 0.335 0.062 1.082 0.014 1.685 0,602 0.574 1.783 0.632 1.355 1 346 0,686 0.459 0.216 0.604 0.417 0.052 0.188 0.110 0.678 0.582 0.570 0.479 0.240 0.604 0. 520 0.634 0.645 0.470 0,370 0.825 0.315 0.070 0.530 0.199 0.342 0 .064 1.109 0.017 1 .644 0. 604 0.487 1.790 0.563 1 .300 1.295 0,177 0.689 0.430 0,234 0.070 0.057 0.595 0.429 0.062 0.231 0.133 0.690 0.514 0.538 0.444 0.267 0.695 0.541 0.662 0.692 0.486 0.362 0.866 0.342 0.070 0.563 0.200 0.365 0,066 1.193 0.019 1 .756 0.652 0.522 1.915 0.596 1.415 1.418 0.186 0.732 0.484 0.253 0.077 0.061 0.637 0,463 0 .066 0.250 0.143 0 .744 0.539 0,562 0.519 0.286 0.693 0.509 0.625 0.667 0.441.0.318 0.817 0.318 0.063 0.523 0.178 0.348 0.063 1.134 0.018 1.661 0.619 0.485 1.835 0.561 1.379 1.386 0.191 0.697 0.473 0.238 0.076 0.059 0.597 0.444 0.062 0.239 0.136 0.707 0,522 0.532 0.500 0.270 0.631 0.701 0.430 0.544 0.656 0.610 0.597 0.713 0.528 0.437 0.443 0.734 0.851 0.287 0.313 0.084 0.062 0.563 0.536 0.180 0.362 0.076 0.056 1.104 1.176 0.016 1.726 1.721 0,641 0.637 0.607 0.486 1.896 1.853 0.636 0.568 1.374 1.348 1.295 1.381 0.194 0.675 0.713 0.454 0.466 0.228 0.245 0.077 0.057 0.634 0,596 0.424 0.454 0.056 0.063 0.211 0.248 0.137 0.730 0.722 0,610 0.534 0.590 0.538 0.443 0,496 0.194 0.275 0.667 0.514 0.651 0.659 0.483 0.389 0.821 0.312 0.072 0.553 0.201 0.352 0.065 1.140 0.017 1.709 0.628 0.532 1.856 0.597 1.376 1.367 0.181 0.702 0.467 0.238 0.073 0.058 0.616 0.441 0.061 0.228 0.132 0.714 0.551 0.558 0.486 0.257 5.54 10.50 5.12 6.71 8.30 12.28 7.19 5.73 11.62 4.18 13.97 3.50 9.23 3.86 9.31 2.77 3,14 9.32 3.04 5.52 3.76 4.27 8.65 2.97 4.89 5 .34 6.62 3.91 3.79 4.02 7.96 9.70 8.50 3.26 6.29 3.94 6.71 12.12----------------
ISTD--"V En[] 50 of 122 2AcCUTE T.N93379 ;J ." -,. .* .. Initial Calibration Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 2 of 3 Sample: VA2955-1CC2955 Lab FileID: A93590.D'p 43)M 1,1,1-trichloroet 0.617 0.583 0.595 0.647 0.623 0.627 0.635 0.618 44)M tert-amyl methyl 1.385 1,322 1.243 1,327 1.273 1.314 1.221 1.298 3.60 4.32 45) I 1,4-difluorobenzene 46)M Di-isobutylene 0.572 47)M epichlorohydrin 0.035 48)M n-butyl alcohol 0.011 49)M carbon tetrachlor 0.393 50)M 1,1-dichloroprope 0.369 51)M hexane 0.306 52)M benzene 1.106 53)M heptane 0.148 54)M isopropyl acetate 0.603 55)M 1,2-dichloroethan 0.367 56)M trichloroethene 0.283 57)M 2-nitropropane 0.035 58)m methylcyclohexane 0.445 59)M'2-chloroethyl vin 0.181 60)M methyl methacryla 0.209 61)M 1,2-dichloropropa 0.292 62)M dibromomethane 0.183 63)M 1,4-dioxane 0.004 64)M bromodichlorometh 0.399 65)M cis-1,3-dichlorop 0.514 66)S toluene-d8 (s) 1.393 67)M 4-methyl-2-pentan 0.512 68)M toluene 0.716 69)M 3-methyl-l-butano 0.018 70)M trans-1,3-dichlor 0.460 71)M ethyl methacrylat 0.385 72)M 1,1,2-trichloroet 0.231 73)M 2-hexanone 0.225---------------- ISTD --------------------- 0.567 0.587 0.659 0.618 0.528 0.647 0.597 7.82 0.029 0.033 0.036 0.035 0,025 0,035 0.033 12.48 0.010 0.011 0.011 0.010 0.011 3.56 0,359 0.385 0.417 0.403 0.369 0.402 0.390 5.19 0.355 0.345 0.374 0.357 0.318 0.354 0.353 5.15 0,299 0.262 0.301 0.291 0.289 0.285 0.290 5.00 1.064,1.040 1.096 1.049 1.093 1.031 1.069 2.80 0.137 0.125 0.145 0.140 0.136 0.139 5.95 0.538 0,543 0.581 0.573 0.564 0.545 0.564 4.20 0.334 0.361 0,383 0,367 0,339 0.359 0.358 4.71 0,266 0.280 0.299 0.288 0.271 0.285 0.282 3.84 0.034 0.039 0.038 0.035 0.036 5.74 0,411 0.366 0,434 0.428 0.430 0.420 0.419 6.13 0,169 0.174 0.192 0.188 0,178 0.179 0,180 4.31 0,200 0,218 0.213 0.215 0.211 3.37 0.266 0.288 0.308 0.295 0.282 0.291 0.289 4.42 0,176 0.187 0.200 0.195 0.168 0.195 0.186 6,14 0.004 0.004 0,004 0.004 0.004# 3,36 0,370 0.391 0.423 0.410 0.373 0.413 0.397 5.06 0.474 0.493 0.530 0.518 0.457 0.518 0.501 5.35 1,411 1,289 1.354 1.314 1.307 1.345 3,67 0.479 0.491 0.531 0.512 0.531 0.507 0.509 3.83 0.680 0.685 0.738 0.714 0.746 0,717 0.714 3.41 0,017 0.019 0.018 0.017 0.018 4.13 0.431 0,462 0.499 0.486 0.450 0.490 0.468 5,22 0.391 0.420 0.410 0,409 0.403 3.59 0.212 0.227 0.244 0,242 0.232 0.245 0.233 5,07 0.221 0.236 0.224 0.219 0.225 2.91 bo 11 74)75)M 76)M 77)M 78)M 79)M 80)M 81)M 82)M 83)M 84) M 85)M 86)M tet 1,3 but dib 1,2 chi 1,1 ethm, p sty bro chlorobenzene-d5.rachloroethene 0.268 3-dichloropropa 0.414:yI acetate 0.196 romochlorometh 0.335-dibromoethane 0.276 orobenzene 0.827 ,1,2-tetrachlo 0.323 ylbenzene 1.260-xylene 0.522<ylIene 0.535'rene 0,852 moform 0.278---------------- ISTD --------0,263 0.256 0.266 0,257 0.261 0.385 0.405 0.422 0.402 0.400 0,182 0.183 0.197 0.190 0.168 0.294 0.328 0.349 0.339 0.318 0.245 0.271 0,281 0.276 0.259 0.781 0.782 0.827 0.799 0.809 0.292 0.306 0.324 0.317 0.306 1.199 1.210 1.263 1.208 1.277 0.494 0.500 0.523 0.501 0.527 0,508 0.520 0.544 0.533 0.550 0.793 0.831 0.870 0.847 0.811 0.237"0.275 0.293 0.290 0.235 0,256 0.261 0.398 0.404 0.184 0.186 0.343 0,329 0,279 0,269 0.806 0.804 0.318'0.312 1.194 1.230 0.498 0,510 0.535 0.532 0.847 0.836 0,303 0.273 87) I 1,4-d)chlorobenzene-d 88)M isopropylbenzene 1.775 89)S 4-bromofluorobenz 0.753 90)M bromobenzene 0.598 91)M 1,1,2,2-tetrachlo 0.573 92)M trans-1,4-dichlor 0,149 93)M 1,2,3-trichloropr 0.157 94)M n-propylbenzene 2.250 95)M 2-chlorotoluene 1.606 96)M 4-chlorotoluene 1.488 97)M 1,3,5-trimethylbe 1.693 98)M tert-butylbenzene 1.505 99)M pentachloroethane 0.430---------------- ISTD ---------- 1.80 2 .98 5 .25 5.64 4 .87 2 .33 3.76 2.85 2.76 2.70 3.15 9.91 3.44 3.83 4.78 3.87 12.21 10.62 2.85 2.99 3.38 3.45 3.08 5.55 1.705 0.776 0.541 0.527 0.133 0.137 2.149 1.525 1.369 1.567 1.462).382 1.704 0.703 0,584 0.551 0.151 0.153 2.146 1.516 1.388 1.614 1 474 0.415 1 .858 0.735 0.621 0.589 0,163 0,165 2.283 1.638 1.481 1.726 1 .590 0.445 1.761 0.705 0.602 0.566 0.156 0.156 2.187 1 .576 1.435 1.649 1.516 0.433 1.802 1.845 0.733 0.585 0.626 0.573 0.588 0.113 0.1620.120 0.162 2.302 2,253 1.598 1.625 1.428 1.488 1.713 1,690 1.532 1.569 0.400 0.443 1.779 0.734 0.594 0.567 0.147 0.150 2,.225 1,.584 1,439 1 .665 1 .521 0.421 Rn 51 of122 12ACCL1TEST. N9337S a Initial Calibration Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 3 of 3 Sample: VA2955-ICC2955 Lab FIIeID: A93590.D 04, 100)M 101)M 102)M 103)M 104)M 105)M 106)M 107)M 108)M 109)M 110)M 111)M 112)M 113)114)M 1,2,4-trimethylbe sec-butylbenzene 1,3-dichlorobenze p-isopropyltoluen 1,4-dichlorobenze 1,2-dichlorobenze n-butylbenzene 1,2-dibromo-3-chl 1,2,4-trichlorobe hexachlorobutadie naphthaiene 1.2,3-trichlorobe hexachloroethane
2-methyinaphthale Cyclohexane 1.758 2.162 1.188 1.896 1,202 1.107 1.589 0.105 0.724 0.336 1 .572 0.638 0.379 1.666 2.081 1.087 1.805 1.123 1.061 1.504 0.086 0.703 0.334 1.422 0.629 0.349 1 .707 2.069 1,123 1,820 1.143 1.090 1.538 0.107 0.724 0.330 1,591 0.644 0.376 1.819 2.227 1 206 1.972 1.226 1.167 1.634 0.114 0.806 0.356 1.730 0,708 0.416 1.743 2.136 1,151 1.885 1.183 1.126 1.567 0.110 0.784 0.340 1.669 0.691 0.408 1.783 2.229 1,222 1.923 1.213 1.125 1,605 0,736 0.327 1.548 0.660 0,357 1,756 1.748-2,181 2.155 1.163 1.163 1.898 1,886 1.200 1.184 1.129 1,115 1.563 1.571 0.113 0.106 0,808 0.755 0.342 0,338 1.699 1.6050.706 0.668 0.423 0,387 0. 000#0.455 0,442 2.84 2.97 4.09 3.04 3.19 3.00 2.74 9.91 5.70 2.85 6.57 4.97 7.47-1.. 00 5.94 0.457 0.430 0.444 0.477 0.441 0,393 (#) = Out of Range MA2955.M Wed Mar 02 10:09:55 2005 MSA.#o 52 of 122 I ACCUTEST N93379 , S 1. v * ..-,. Continuing Calibration SummaryJob Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 1 of 3 Sample: VA2990-CC2955Lab FilelD: A94434.DýmwEvaluate Continuing Calibration Report Data File : C:\HPCHEM\1\DATA\A94434.D Acq On : 22 Mar 2005 12:18 am Sample : CC2955-20 Misc : MS12433,VA2990,W.... 1 MS Integration Params: LSCINT.P Vial: 29 Operator: NARESHJ Inst : MSA Multiplr: 1.00 Method Title Last Update Response via Min. RRF Max. RRF Dev C:\HPCHEM\1\METHODS\MA2955,M (RTE Integrator) SW-846 Method 8260 Fri Mar 04 09:32:21 2005 Multiple Level Calibration 0.010 Min. Rel. Area : 50% Max. R.T. Dev 050min 20% Max. Rel. Area : 200%Compound 1 I Tert Butyl Alcohol-d9 AvgRF CCRF 1.000 1.000----------------------- True Calc.2 M ethanol 2000.000 2654.118%Dev Area% Dev(min)R.T. 0.0 77 -0.03 6.77% Drift ------------ -32.7# 99 -0.03 5.48% Dev ------------- -6.5
- 87 -0.02 6.90-----------------------
AvgRF 3 M tertiary butyl alcohol. 0.850 4ýv 4 5 6 7 8 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26'27 28 29 30 31 32 33 34 35 36 37 pentafluorobenzene chlorodifluoromethane dichlorodifluoromethane chioromethane vinyl chloride bromomethane chloroethane trichlorofluoromethane ethyl ether acrolein 1,1-dichloroethene acetone allyl chloride acetonitrile iodomethane iso-butyl alcohol carbon disulfide methylene chloride methyl acetate methyl tert butyl ether trans-l,2-dichloroethene di-isopropyl ether ethyl tert-butyl ether 2-butanone 1,71-dichloroethane chloroprene acrylonitrile vinyl acetate ethyl acetate 2,2-dichloropropane cis-1,2-dichioroethene propionitrile bromochloromethane tetrahydrofuran 1.000 0.667 0.514 0.651 0,659 0.483 0,389 0.821 0.312 0.072 0 .553 0. 201 0.352 0 065 1 .140 0.017 1.709 0,628 0,532 1.856 0.597 1.376 1.367 0.181 0.702 0.467 0.238 0.073 0.058 0.616 0.441 0.061 0.228 0.132 CCRF 0.905 1.000 0.786 0.680 0.770 0.750 0.563 0.411 1.080 0.312 0.129 0.537 0.237 0.340 0.063 1.136 0.017 1 937 0.612 0.523 1 .808 0.568 1 .354 1.294 0.161 0.714 0.501 0.229 0.054 0.054 0.552 0.406 0.059 0.220 0.120 0,0-17.8-32, 3#-18.3-13.8 -16.6-5.7-31 .5#0.0*-79.2#2.9-17,9 3.4 3.1 0.4 0.0-13.3 2.5 1 .7 2.6 4.9 1.6 5.3 11.0-1.7-7.3 3.8 26.0#6.9 10.4 7.9 3,3 3.5 9.1 89 116 117 108 104 107 99 117 88 163 90 106 89 89 91 85 105 90 96 90 90 93 89 81 92 104 87 68 84 83 84 86 85 80-0.02-0.02-0.02-0.03-0.02-0.02-0.01-0.04-0.02-0.02-0.03-0.02-0.02-0.03-0.03-0.02-0.03-0.03-0.02-0.03-0.02-0.03-0.03-0.02-0.03-0.02-0.03-0.02-0.02-0.03-0.02-0.02 -0.03-0.02 9.17 3.48 3.47 3,74 3.98 4.60 4.79 5.26 5.67 5.87 6.08 6.10 6,61 6.52 6.33 9.45 6.47 6.79 6.60 7.19 7.21 7.85 8.34 8.55 7.79 7.93 7.11 7.81 8.60 8.59 8.58 8.61 8.88 8.96 G1n 53 of 122 19ACCLJTEST. N93379 ...I: I ." Continuing Calibration Summary Page 2 of 3 Job Number: N93379 Sample: VA2990-CC2955 Account: AGMPAL Arcadis Geraghty & Miller Lab FileID: A94434.D Project: PSEG, Hancock's Bridge, NJ 38 M chloroform 0,714 0.748 -4.8 97 -0.02 8.96 39 S dibromofluoromethane (s) 0.551 0.451 18.1 78 -0.02 9.17 40 S 1,2-dichloroethane-d4 (s) 0.558 0.537 3.8 89 -0.03 9.61 41 M freon 113 0.486 0.486 0.0 98 -0.03 6.08 42 M methacrylonitrile 0,257 0.255 0.8 85 -0.03 8.82 43 M 1,1,1-trichloroethane 0.618 0.669 -8.3 100 -0.02 9.25 44 M tert-amyl methyl ether 1.298 1.190 8.3 85 -0.03 9.79 45 1 1,4-difluorobenzene 1.000 1.000 0.0 82 -0.03 10,11 46 M Di-isobutylene 0.597 0.570 4.5 79 -0.02 10.41 47 M epichlorohydrin 0.033 0.032 3.0 78 -0.02 11.43 48 M n-butyl alcohol 0.011 0.010#49 M carbon tetrachloride 0.390 0.485 -24.4# 103 -0.03 9.47 50 M 1,1-dichloropropene 0.353 0.396 -12.2 93 -0.02 9.44 51 M hexane 0,290 0.263 9.3 82 -0.03 7.59 52 M benzene 1.069 .1,086 -1.6 85 -0.03 9.71 53 M heptane 0.139 0.117 15.8 77 -0.02 9.97 54 M isopropyl acetate 0.564 0.590 -4.6 89 -0.03 9.67 55 M 1,2-dichloroethane 0.358 0.477 -33.2# 108 -0.02 9.70 56 M trichloroethene 0.282 0.304 -7.8 89 -0.03 10.47 57 M 2-nitropropane 0.036 0.046 -27.8# 110 -0.02 11.33 58 m methylcyclohexane 0.419 0.398 5.0 89 -0.03 10.74 59 M 2-chioroethyl vinyl ether 0.180 0.178 1.1 83 -0.03 11.33 60 M methyl methacrylate 0.211 0.195 7.6 79 -0.02 10.79 61 M 1,2-dichloropropane 0.289 0.302 -4.5 86 -0.03 10.74 62 M dibromomethane 0.186 0.208 -11,8 91 -0.02 10.89 63 M 1,4-dioxane 0.004 0.003# 25.0# 70 -0.03 10.86 64 M bromodichloromethane 0.397 0.443 -11.6 92 -0.03 11.04 65 M cis-1,3-dichloropropene 0.501 0.498 0.6 82 -0.03 11.55 66 S toluene-d8 (s) 1,345 1.185 11.9 75 -0.02 11.89 67 M 4-methyl-2-pentanone 0.509 0,513 -0.8 85 -0.02 11.69 68 M toluene 0.714 0.717 -0.4 85 -0.03 11.97 69 M 3-methyl-l-butanol 0.018 0.017 5,6 81 -0.02 11.71 70 M trans-1,3-dichloropropene 0.468 0.485 -3.6 86 -0.02 12.17 71 M ethyl methacrylate 0.403 0.374 7.2 78 -0.02 12.22 72 M 1,1,2-trichloroethane 0.233 0,238 -2.1 86 -0.03 12.40 73 M 2-hexanone 0.225 0.217 3.6 80 -0.02 12.63 74 I chlorobenzene-d5 1,000 1.000 0.0 77 -0,03 13.57 75 M tetrachloroethene 0.261 0.287 -10.0 86' -0.02 12.63 76 M 1,3-dichloropropane 0.404 0.454 -12.4 86 -0.02 12.60 77 M butyl acetate 0.186 0.189 -1.6 79 -0.02 12.74 78 M dibromochloromethane 0.329 0.368 -11.9 86 -0.02 12.89 79 M 1,2-dibromoethane 0.269 0.297 -10.4 84 -0.03 13,05 80 M chlorobenzene 0.804 0.851 -5.8 83 -0.02 13.60 81 M 1,1,1,2-tetrachloroethane 0.312 0.352 -12.8 88 -0.03 13.67 82 M ethylbenzene 1.230 1.370 -11,4 87 -0.02 13.69 83 M m,p-xylene 0.510 0.545 -6.9 83 -0.02 13.82 84 M o-xylene 0.532 0.559 -5.1 82 -0,02 14.28 85 M styrene 0.836 0.875 -4.7 81 -0.03 14.29 86 M bromoform 0.273 0.286 -4.8 80 -0.02 14.54 87 1 1,4-dichlorobenzene-d4 1.000 1.000 0.0 74 -0.03 16.21 88 M isopropylbenzene 1.779 1.950 -9,6 84 -0.02 14,68 89 S 4-bromofluorobenzene (s) 0.734 0.772 -5.2 81 -0.02 14.88 90 M bromobenzene 0.594 0.689 -16.0 87 -0.02 15,10 91 M 1,1,2,2-tetrachloroethane 0,567 0.613 -8.1 82 -0.03 14.99 92 M trans-1,4-dichloro-2-bute 0.147 0.138 6.1 67 -0.02 15.05 93 M 1,2,3-trichloropropane 0.150 0.183 -22.0# 88 -0.02 15.07 94 M n-propylbenzene 2.225 2.509 -12.8 86 -0.02 15.1554 of 122 NACCUTEs'" N93379 -ak .. Continuing Calibration Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJPage 3 of 3 Sample: VA2990-CC2955 Lab FileID: A94434.D'*v 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 M M M M M M M M M M M M M M M M M M M 2-chlorotoluene 4-chlorotoluene 1,3,5-trimethylbenzene tert-butylbenzene pentachloroethane 1 2,4-trimethylbenzene sec-butylbenzene 1,3-dichlorobenzene p-isopropyltoluene 1,4-dichlorobenzene 1,2-dichlorobenzene n-butylbenzene 1,2-dibromo-3-chloropropa 1,2,4-trichlorobenzene hexachlorobutediene naphthalene 1,2,3-trichlorobenzene hexachloroethane 2-methyinaphthalene Cyclohexane 1.584 1.439 1.665 1.521 0.421 1 .748 2.155 1 .163 1,886 1,184 1.115 1 571 0. 106 0.755 0,338 1.605 0.668 0. 387 1.842 1.674 1.892 1.656 0.479 2.020 2.297 1,272 1,997 1.287 1.217 1.595 0.113 0.654 0.373 1.243 0.578 0.425-16.3-16.3-13.6-8.9-13.8-15.6-6.6-9.4-5.9-8.7-9.1-1.5-6.6 13.4-10.4 22.6#13.5-9.8 89 89 86 83 85 87 82 83 81 83 82 76 78 66 83 58 66 83-0.02-0.02-0.02-0.02-0.02-0.02-0.02-0.02-0.02-0.02-0.03-0,02-0.02-0.03-0.02-0.02-0.02-0.02 15.29 15.41 15.33 15.72 15.78 15.77 15,97 16.14 16.11 16.24 16.67 16.57 17.52 18.44 18 .60 18.74 19.01 16.99 9.35 Ln1 WIP-NA---------- 0.442 0.541 -22.4# 90 -0.02 (#) = Out of Range A93589.D MA2955.M SPCCs out = 0 CCCs out = 0 Tue Mar 22 10:14:18 2005 MSA IMJ550o1122 L3ACCUTEST. N93379 ,:1:. -- Accutest Laboratories ýbV GC/MS VolatilesRaw Data UllI 56 of122 UACCLnMýST. N9337S -' --' Sample Resuts: : Quantitation Report Data File : C:\HPCHEM\1\DATA\A94444.D Acq On : 22 Mar 2005 5:13 am Sample : N93379-1 Misc : MS12445,VA2990,W,,, ,I MS Integration Params: LSCINT.P Quant Time: Mar 22 9:23 2005 Quan (QT Reviewed)Vial: 39 Operator: NARESHJ Inst : MSA Multiplr: 1.00 t Results File: MA2955.RES Quant Method Title Last Update Response via DataAcq Meth C:\HPCHEM\I\METHODS\MA2955.M (RTE Integrator) SW-846 Method 8260 Fri Mar 04 09:32:21 2005 Initial Calibration MA2955 Internal Standards R.T. QIon Response Conc Units Dev(Min).........................................................................
- 1) Tert Butyl Alcohol-d9 6.77 65 103014 500.00 ug/L -0.03 4) pentafluorobenzene 9.17 168 110179 50.00 ug/L -0.03 45) 1,4-difluorobenzene 10.11 114 146955 50.00 ug/L -0.03 74) chlorobenzene-d5 13.57 117 151089 50.00 ug/L -0.03 87) 1,4-dichlorobenzene-d4 16.20 152 90934 50.00 ug/L -0.03 System Monitoring Compounds 39) dibromofluoromethane (s) 9.16 Spiked Amount 50.000 Range 79 40) 1,2-dichloroethane-d4 (s) 9.60 Spiked Amount 50.000 Range 68 66) toluene-d8 (s) 11.89 Spiked Amount 50.000 Range 83 89) 4-bromofluorobenzene (s) 14.88 Spiked Amount 50.000 Range 82 223-119 65-129 98-118 95-120 52796 43.45 Recovery 66014 53.73 Recovery =171165 43.31 Recovery =75500 56.53 Recovery ug/l. -0.03 86.90%ug/L -0.03 107.46%ug/L -0.03 86.62%ug/L -0.03 113.06%Target Compounds Qvalue 4W (4) = qualifier out of range (m) = manual integration A94444,D MA2955.M Tue Mar 22 20:24:45 2005 MSA Page 1 aI 57 of 12: S .ACC.ITES.
N93379 ---- ;" Srn"ple Rlesufts: KýK;Quantitation Report Data File C:\HPCHEM\I\DATA\A94444.D Acq On 22 Mar 2005 5:13 am..Sample : N93379-3Misc MS12445,VA2990,W4,,,,I MS Integration Params: LSCINT.P Quant Time: Mar 22 9:23 2005 Vial: Operator: Inst Multiplr: 39 NARESHJ MSA 1.00 Quant Results File: MA2955.RES Method : C:\HPCHEM\I\METHODS\MA2955.2' (RTE Integrator) Title : SW-846 Method 8260 Last Update : Fri Mar 04 09:32:21 2005 Response via Initial Calibration. X6brnda flý6 C: A9444.4.D 380000 360000 340000 320000 300000 280000 .=260000 240000 220000 200000 180000 160000 140000 120000 100000 80000 60000 40000;20000 Tieb- .0 5.00 6.0 70 .0 80 00 10 20 30 1.0 1.01.0 1.0 80 90 00 0)A94444.D MA2955.M Tue Mar 22 10:24:45 2005 MSA Page 2 rj 58 of 122 GACCUT N93379 s " .I Sample MOMs K Quantitation Report Data File : C:\HPCHEM\1\DATA\A94445.D Aeq On 22 Mar 2005 5:43 am Sample : N93379-2 Misc : MS12445,VA2990,W,,,, 2 MS Integration Params: LSCINT.P Quant Time: Mar 22 10:58 2005 Quan (QT Reviewed)Vial: 40 Operator: NARESHJ Inst -MSA Multiplr: 1.00 t Results File: MA2955.RES Quant Method Title Last Update Response via DataAcq Meth C:\HPCHEM\I\METRODS\MA2955.M (RTE Integrator) SW-846 Method 8260 Fri Mar 04 09:32:21 2005 Initial Calibration MA2955 Internal Standards R.T. QIon Response Conc Units Dev(Min)*1'~1) Tert Butyl Alcohol-d9
- 4) pentafluorobenzene
- 45) 1,4-difluorobenzene
- 74) chlorobenzene-d5
- 87) 1,4-dichlorobenzene-d4 6.77 9.17 10.11 13.56 16.21 65 168 114 117 152 98730 102885 137953 141938 89222 500.00 50.00 50.00 50.00 50.00 ug/L ug/L ug/L ug/L ug/L-0.03-0.03-0.03-0.03-0.03 System Monitoring Compounds 39) dibromofluoromethane (s) 9.16 Spiked Amount 50.000 Range 79 40) 1,2-dichloroethane-d4 (s) 9.60 Spiked Amount 50.000 Range 68 66) toluene-d8 (s) 12.89 Spiked Amount 50.000 Range 83 89) 4-bromofluorobenzene (s) 14.88 Spiked Amount 50.000 Range 82 113-119 65-129 98-118 95-120 49831 43.92 Recovery 62901 54,83 Recovery -160546 43.28 Recovery =72601 55.41 Recovery ug/L -0.03 87.84%ug/L -0.03 109.66%ug/L -0.03 86.56%ug/L -0.02 110.82%Target Compounds 82) ethylbenzene Qvalue 95 13.69 91 2913 0.83 ug/L to (I1) = qualifier out of range (m) = manual integration A94q45.D MA2955.M Tue Mar 22 20:59:09 2005 MSA Page I 0 59of122MS N937 Sample Resufts: Quantitation Report Data File C:\HPCHEM\I\DATA\A94445.D Acq On 22 Mar 2005 5:43 am Sample : N93379-2 Misc MS12445,VA2990,W,,,,I MS Integration Params: LSCINT.P Quant Time: Mar 22 10:58 2005 Vial: 40 Operator:
NARESHJ Inst : MSA Multiplr: 1.00 Quant Results. File: MA2955.RES Method : C:\HPCHEM\I\METHODS\MA2955.M (RTE Integrator) Title : SW-846 Method 8260 Last Update Fri Mar 04 09:32:21 2005 Response via : Initial Calibration SiC: A9 44 4 5.0 380000 360000 340000 i 320000 30000C 280001 260000 240000 220000 2g a.5 a a a I I'V 200000 180000 160000 140000 120000 100000 80000 60000 40000 20000 a.2+"e%a-I ,I%W U. .. .. .. .' I.... .II. ý..IIIII. .1, ......1. .....I .I'.... I ,,;, ..,. II II .I ... -I L, ý i "..., ., E * -t r ,'Time--> 4.00 5.00_ 60 A94445.D MA2955.M TI -F 1 .0 3 I I I I 7.00 800 900 0.0 11.0 .1.0 13.0 1.016.0016.100 -.1'7.00 16.00 .19.00 20.00 Tue Mar 22 10:59:10 2005 MSA Page 2 Mn 60 of 122 Q ACC.'TE..N93379 Sampie Results: Abundance Scan 1950 (13.712 min): A93590.D(-) Re 1=50 106 39 51 65 7717 13> ,,...,,.7,.., ... , 010 ,8 OL- ..." '.... 1 , ., , .. ...". .." " h'vz-->. 30 40 50 6 0 8 0 10 10 120 130 140 482 ethylbenzene Concen: 0.83 ug/L RT: 13.69 min Scan# 1945 Delta R.T. -0,02 min Lab File: A94445,D Acq: 22 Mar 2005 5:43 am Abundance Raw 0 , 01z:__ ....3.%Abundance SUb 5 hrz--> 30 Scan 1945 (13.690 min): A94445.D 1'Tgt Ion 91 106 77 Ion: 91 Ratio 100 29.2 9.6 Resp: 2923 Lower Upper 2.4 62.4 0.0 38.1 39 51 65 77 I I i i!106 I 1 40 50 60 70 80 90 100 110 120 130 140 lAbundance Ion 91.00 (90.70 to 91,70): A94i Ion 106.00 (105.701o 106.70): 4, I2in 77.00 (76.70 to 77.7f",: A94}2000 13.69 1500 IOO0 Scai 19.15 (13.&KD (1141'r A94445-D -5 51 106 50013.65 13.70 65 77 0,...... I II .... .' ..... ... ... .. .. .... .i .... 1 i Iml l 40 50 60 70 80 90 100 110 120 130 140 to A94445.1) MA2955-M Tue Mar 22 10:59:10 2005 MSA Page 3 011 61 of 122S. .N9337S Somple Resuits: MI.= IM .Quantitation Report Data File : C;\HPCHEM\2\DATA\A94446.D Acq On 22 Mar 2005 6:27 am Sample N93379-3Misc MS12445,VA2990,W,,,,l MS Integration Params: LSCINT.P Quant Time: Mar 22 9:59 2005 Quan (QT Reviewed)Vial: 41 Operator: NARESHJ Inst : MSA Multiplr: 2.00 t Results File: MA2955.RES Quant Method Title Last Update Response via DataAcq Meth C:\HPCHEM\I\METHODS\MA2955.M (RTE Integrator) SW-846 Method 8260 Fri Mar 04 09:32:21 2005 Initial Calibration MA2955 Internal Standards R.T. QIon Response Conc Units Dev(Min)1) Tert Butyl Alcohol-d9 6.77 65 95007 500.00 ug/L -0.02 4) pentafluorobenzene 9.17 168 103245 50.00 ug/L -0.03 45) 1,4-difluorobenzene 10.11 114 137633 50.00 ug/L -0.03 74) chlorobenzene-d5 13.57 117 142913 50.00 ug/L -0.03 87) 1,4-dichlorobenzene-d4 16.20 152 92848 50.00 ug/L -0.03 0)Po System Monitoring Compounds 39) dibromofluoromethane (s) 9.16 Spiked Amount 50.000 Range 79 40) 1,2-dichloroethane-d4 (s) 9.60 Spiked Amount 50.000 Range 68 66) toluene-d8 (s) 11.89 Spiked Amount 50.000 Range 83 89) 4-bromofluorobenzene (s) 14.88 Spiked Amount 50.000 Range 82 113-119 65-129 98-218 95-120 49493 43.47 Recovery =63588 55.23 Recovery =161794 43.72 Recovery =73863 54.17 Recovery =ug/L -0.03 86. 94%ug/L -0.03.110.46%ug/L -0.03 87.44%ug/L -0.03 108.34%Target Compounds Qvalue (f) = qualifier out of range (m) = manual integration A94446.D MA2955.M Tue Mar 22 10:25:11 2005 MSA Page I fflg 62 of 12;,ACC- "EST N9Z37V Sarnpie results: WIRI"E Quantitation Report Data File : C:\HPCHEM\1\DATA\A94446.D Vial: 43 Acq On 22 Mar 2005 6:27 am Operator: NARESI4 Sample N93379-3 Inst : MSA Misc : MS12445,VA2990,W,,,,I Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Time: Mar 22 9:59 2005 Quant Results File: MA2955.RES Method : C:\HPCHEM\I\METHODS\MA2955.M (RTE Integrator) Title : SW-846 Method 8260 Last Update : Fri Mar 04 09:32:21 2005 Rep n e via Initial Calibration
----- -... --..... -- ..ne TIC: A94446.0 400000 380000 S360000 340000 320000 300000 280000 260000 240o00 220000 20000D 180000 160000 140000 120000 100000 80000 60000 20000 i:Trrne.->
4.00 5.O 6.0 7.0 0 .0 io.00 10 11.00 12.00 13.00 14.00 15.00 16.0D017-00 18.00 19.00 20.00 A94446.D MA2955.M Tue Mar 22 10:25:a2 2005 MSA Page 2 M5 63 of 122______ ACCLJTEST, L~ 72ZM.1 =I= .:1 N9337S ,*-t5-,-; sample Resulis- , Quantitation Report Data File : C:\HPCHEM\I\DATA\A94447.D Acq On : 22 Mar 2005 6:57 am Sample : N93379-4 Misc MS12445,VA2990,W.,,, I MS Integration Params: LSCINT.P Quant Time: Mar 22 20:00 2005 Quan{QT Reviewed)Vial: 42 Operator: NARESHJ Inst : MSA Multiplr: 1.00 t Results File: MA2955.RES Quant Method Title Last Update Response via DataAcq Meth C:\HPCHEM\I\METHODS\MA2955.M (RTE Integrator) SW-846 Method 8260 Fri Mar 04 09:32:21 2005 Initial Calibration MA2955 P)Internal Standards R.T. QIon Response Conc Units Dev(Min)......................................................................... I)4)45)74)87)Tert Butyl Alcohol-d9 pentafluorobenzene 1,4-difluorobenzene chlorobenzene-d5 1,4-dichlorobenzene-d4 6.76 65 9.27 268 10.11 114 23.57 117 16.21 152 101322 207547 144383 148737 96926 500.00 50.00 50,00 50.00 50.00 System Monitoring Compounds 39) dibromofluoromethane (s) 9.26 Spiked Amount 50.000 Range 79 40) 1,2-dichloroethane-d4 (s) 9.60 Spiked Amount 50.000 Range 68 66) toluene-dE (s) 11.89 Spiked Amount 50.000 Range 83 89) 4-bromofluorobenzene (s) 14.88 Spiked Amount 50.000 Range 82 Target Compounds 113-119 65-129 98-118 95-120 51'748 43.63 Recovery 64310 53.62 Recovery 169137 43.56 Recovery 76895 54.02 Recovery =ug/L -0.03 ug/L -0.03 ug/L -0.03 ug/L -0.03 ug/L -0.03 ug/L -0.03 87.26%ug/L -0.03 107.24%ug/L -0.03 87.12%ug/L -0.03 108.04%Qvalue'V (t) = qualifier out of range (m) = manual integration A94447.D MA2955.M Tue Mar 22 10:25:24 2005 MSAP Page I64 of 122 SACCUrE.S N93379 .; -'- , t , .5: P7kTýT7-7M'77 ý,MWr, M-IMITIM711; snmplep.csulls: LwCmim Quantitation Report Data File : C:\HPCHEM\I\DATA\A94447.D Acq On 22 Mar 2005 6:51 am Sample : N93379-4 Misc : MS12445,VA2990,W,,,,l MS Integration Params: LSCINT.P Quant Time: Mar 22 10:00 2005 Vial: 42 Operator: NARESHJ Inst : MSA Multiplr: 1,00 Quant Results File: MA2955.RES Method C:\HPCHEM\I\METHODS\MA2955.M (RTE Integrator) Title : SW-846 Method 8260 Last Update : Fri Mar 04 09:32:21 2005 Response via :Initial Calibration 'V~bundnce
- fC: A94447.D 400000 380000 36000o 340000 320000 300000-280000 w=E 260000 .240000 220000 200000 180000 16000C 140000 120000 100000 80000'2'o 60000 40000 20000 i 1 II~1., ,11 I Tin~' 4.00 6.00 6,60 A94447.D MA2955.M.00. 800 T 0 ;. 10 .0 1 1 .1 1. 00 12.00 1. 0 .0 1- .0...................
....-00 17.00 1. ........... 00 ... 00. 20.00 Tue Mar 22 10:25:25 2005 MSA Page 265 of 122 VACCUEST.N93379 Sarnpie Resuits: Quantitation Report Data File : C:\HPCHEM\1\DATA\A94448.D Acq On 22 Mar 2005 7:26 am SSample : N93379-5 Misc MS12445,VA2990,W,,,, I MS Integration Params: LSCINT.P Quant Time: Mar 22 20:00 2005 Quan (QT Reviewed)Vial: 43 Operator: NARESHJ Inst : MSA Multiplr: 1.00 t Results File: MA2955.RES Quant Method Title Last Update Response via DataAcq Meth* C:\HPCHEM\I\METHODS\MA2955.M
- SW-846 Method 8260: Fri Mar 04 09:32:21 2005* Initial Calibration
- MA2955 (RTE Integrator)
Internal Standards R.T. QIon...........................................
- 1) Tert Butyl Alcohol-d9
- 4) pentafluorobenzene
- 45) 1,4-difluorobenzene
- 74) chlorobenzene-d5
- 87) 1,4-dichlorobenzene-d4 6.77 9.17 10.11 13.57 16.21 65 168 114 117 152 Response Conc Units Dev(Min)------------------------------
204607 500.00 ug/L -0.03 116729 50.00 ug/L -0.03 253426 50.00 ug/L -0.03 157916 50.00 ug/L -0.03 94260 .50.00 ug/L -0.03 System Monitoring Compounds 39) dibromofluoromethane (s) 9.16 Spiked Amount 50.000 Range 79 40) 1,2-dichloroethane-d4 (s) 9.60 Spiked Amount 50.000 Range 68 66) toluene-d8 (s) 11.89 Spiked Amount 50.000 Range 83 89) 4-bromofluorobenzene (s) 14.88 Spiked Amount 50.000 Range 82 113-119 65-129 98-118 95-120 54687 42.48 Recovery =67421 51.80 Recovery 180377 43.72 Recovery 79541 57.46 Recovery ug/L -0.03 84.96%ug/L -0.03 103.60%ug/L -0.03 87,44%ug/L -0.03 114.92%Target Compounds Qvalue (0) = qualifier out of range (m) = manual integration A94448.D MA2955.M Tue Mar 22 10:25:37 2005 MSA Page 1 919 66 of 122 12ACCUTES N93379 C Quantitation Report Data File C:\HPCHEM\1\DATA\A94448.D Vial: 43 Acq On : 22 Mar 2005 7:26 am Operator: NARESHJ Sample : N93379-5 Inst : MSA Misc MS12445,VA2990,W,,,,I Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Time: Mar 22 10:00 2005 Quant Results File: MA2955.RES Method : C:\HPCHEM\]\METHODS\MA2955.M (RTE Integrator) Title : SW-846 Method 8260 Last Update : Fri Mar 04 09:32:21 2005 Response via : Initial Calibration {Ab~ a~ e ....... ..... ... ... ... ........ ... .........nQ A94448.D 400000 380000 36000V 340000 320000 300000 280000 2 260000 240000 220000 200000 180000 160000 140000 120000 100000 80000 60000 40000 20000 Trne--> 4.00 5.00 6,00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 A9418.D MA2955.M Tue Mar 22 10:25:38 2005 MSA. Page 2 S! 6 6of 122_ _ _ _ _ _ A CC U T 'E S-1 N9337 * :' 2 ., -, 2 .#A
- 1-"'-Quantitation Report Data File : C:\HPCHEM\I\DATA\A94449.D Acq On 22 Mar 2005 7:56 am' Sample N93379-6 Misc : MS12445,VA2990,W,,,,.l MS Integration Params. LSCINT.P Quant Time: Mar 22 10:01 2005 Quan (QT Reviewed)vial: 44 Operator:
NARESHJ Inst :.MSA Multiplr: 1.00 t Results File: MA2955.RES Quant Method Title Last Update Response via DataAcq Meth C:\HPCHEM\I\METHODS\MA2955.M (RTE Integrator) SW-846 Method 8260 Fri Mar 04 09:32:21 2005 Initial Calibration MA2955 0)~1 O~)Internal Standards R.T. QIon Response Conc Units Dev(Min)1) Tert Butyl Alcohol-d9 6.77 65 95564 500.00 ug/L -0.03 4) pentafluorobenzene 9.17 168 106370 50.00 ug/L -0.03 45) 1,4-difluorobenzene 10.11 114 141632 50.00 ug/L -0.03 74) chlorobenzene-d5 13.56 117 146081 50.00 ug/L -0.03 87) 1,4-dichlorobenzene-d4 16.21 252 86401 50.00 ug/L -0.03 System Monitoring Compounds 39) dibromofluoromethane (s) 9.16 Spiked Amount 50.000 Range 79 40) 1,2-dichloroethane-d4 (s) 9.59 Spiked Amount 50.000 Range 68 66) toluene-d8 (s) 11.89 SpikedAmount 50.000 Range 83 89) 4-bromofluorobenzene (s) 14.88 Spiked Amount 50.000 Range 82 113-119 65-129 98-118 95-120 50623 43.15 Recovery 63545 53.57 Recovery 166245 43.65 Recovery =73973 58.30 Recovery =ug/L -0.03 86.30%ug/L -0.04 107.14%ug/L -0.03 87.30%ug/L -0.03 116.60%Target Compounds Qvalue (f) = qualifier out of range (m) = manual integration A94449.D MA2955.M Tue Mar 22 10:25:51 2005 MSA Page I B'j- 68 of 122 N ACCLT....N93379 -$ " Quantitation Report Data File C:\HPCHEM\I\DATA\A94449.D Vial: 44 Acq On 22 Mar 2005 1:56 am Operator: NARESHJ.Sample N93379-6 Inst : MSA Misc MS12445,VA2990,W,,,,I Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Time: Mar 22 10:01 2005 Quant Results File: MA2955.RES Method : C:\HPCHEM\l\METHODS\MA2955.M (RTE Integrator) Title : SW-846 Method 8260 Last Update : Fri Mar 04 09:32:21 2005 Response via : Initial Calibration 360000 340000 320000 300000& "6 280000 26000D E 240000 220000 200000 160000 160000 140000 120000 100000 60000 60000 40000 20000.Time--> 4.00 5,00 600..00 8.00 9.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 A9'449,D MA2955.M Tue Mar 22 10:25:51 2005 MSA Page 2 135 69of 122-~ UACC1TIEST. 6 EZ OII..L N93379 -- 6-, VV 1 JIt.Quantitation Report Data File C:\HPCHEM\I\DATA\A94436.D Acq On 22 Mar 2005 1:17 am Sample : MBI Misc : MS12433,VA2990,W,,,,1 MS Integration Params: LSCINT.PQuant Time: Mar 22 8:.09 2005 Quan (QT Reviewed)vial: 31 Operator: NARESHJ Inst : MSA Multiplr: 1.00 t Results File: MA2955,RES Quant Method : C:\HPCHEM\I\METHODS\MA2955.M (RTE Integrator) Title : SW-846 Method 8260 Last Update : Fri Mar 04 09:32:21 2005 Response via : Initial Calibration DataAcq Meth : MA2955 Internal Standards R.T. QIon Response Conc Units Dev(Min)1)4)45)74)87)Tert Butyl Alcohol-d9 pentafluorobenzene 1,4-difluorobenzene chlorobenzene-d5 1,4-dichlorobenzene-d4 6.77 9.17 10.11 13.56 16.21 System Monitoring Compounds 39) dibromofluoromethane (s) 9.17 Spiked Amount 50.0.00 Range 79 40) 1,2-dichloroethane-d4 (s) 9.60 Spiked Amount 50.000 Range 68 66) toluene-d8 (s) 11.89 Spiked Amount 50.000 Range 83 89) 4-bromofluorobenzene (s) 14.88 Spiked Amount 50.000 Range 82 65 168 114 117 152 113-119 65-129 98-118 95-120 105413 500.00 ug/L -0.03 119136 50.00 ug/L -0.02 158088 50.00 ug/L -0.03 161683 50.00 ug/L -0.03 97691 50.00 ug/L -0.03 55166 41.99 Recovery 66697 50.20 Recovery =183126 43.08 Recovery =80831 56.34 Recovery =ug/L -0:02 83.98%ug/L -0.03 100.40%ug/L -0.02 86.16%ug/L -0.02 112.68%Target Compounds Qvalue (P) = qualifier out of range (m) = manual integration A94436.D MA2955.M Tue Mar 22 10:16:07 2005 MSA Page ]On 70 of 122.ACCUTES,' N9337S ý;, :1 M:7',:, ... -m , 0(; Report: KX;XLktjMM Quantitation Report Data File C:\HPCHEM\I\DATA\A94436.D Acq On 22 Mar 2005 1:17 am* Sample MBI Misc MS12133,VA2990,W,,,, I MS Integration Params: LSCINT.P Quant Time: Mar 22 8:09 2005 Vial: 31 Operator: NARESHJ Inst : MSA Multiplr: 1.00 Quant Results File: MA2955.RES Method Title Last Update Response via-: 400000 380000 C:\HPCHEM\I\METHODS\MA2955.M (RTE Integrator) SW-846 Method 8260 Fri Mar 04 09:32:21 2005 Initial Calibration TIC: A9436.D V 36000C 340000'C" 3200001 300000{n CC)I 6 280000 260000 240000 CC)'6 220000 200000 180000 160000 140000 120000 100000 80000 60000 40000 20000 1?zi-a Co k t...... l...T I .I 'Dm-> 4.00 5.00 6.00.. .. ......... -.- I ....... o.... ....... .....A94436.D MA2955.M 8.00 9.00 1000 11,00 12.00 6' .0 14.00 15.00 16.00 17.00 1800 1900 20.00 Tue Mar 22 30:16:0? 2005 MSA Page 2 B]!' 71 of 122 VACCUTEST N93379ý7.;)-, El--Mllrrvyl-.,=--ý.,:i,ý-rýll-ý. =T. B". Accutest Laboratories GCUMS Semi-volatiles QC Data Summaries Includes the following where applicable: " Method Blank Summaries" Blank Spike Summaries* Matrix Spike and Duplicate Summaries" Instrument Performance Checks (DFTPP)" Internal Standard Area Summaries" Surrogate Recovery Summaries* Initial and Continuing Calibration Summaries (M5 72 of 122 QACCLJrTEST. N93379 ,":S-:. Raw D~ata: m&;?kIe-AI. Method Blank Summary Page I of 3 Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OP19692-MB2 H74032.D 1 04/01/05 SSW 03/16/05 OP19692 EH3145 The QC reported here applies to the following samples: Method: SW846 8270C N93379-1, N93379-2, N93379-3, N93379-4, N93379-5 -4 CAS No. Compound Result RL MDL Units Q 95-57-8 2-Chlorophenol ND 5.0 4.3 ug/l 59-50-7 4-Chloro-3-methyl phenol ND 5.0 4.7 ug/l 120-83-2 2,4-Dichlorophenol ND 5.0 0.73 ug/l 105-67-9 2,4-Dimethylphenol ND 5.0 1.0 ug/i 51-28-5 2,4-Dinitrophenol ND 20 1.1 ug/l 534-52-1 4,6-Dinitro-o-cresol ND 20 0.65 ug/l 95-48-7 2-Methylphenol ND 5.0 0.72 ug/l 3&4-Methylphenol ND 5.0 0.70 ug/l 88-75-5 2-Nitrophenol ND 5.0 0.73 ug/l 100-02-7 4-Nitrophenol ND 20 2.3 ug/l 87-86-5 Pentachlorophenol ND 20 0.75 ug/l 108-95-2 Phenol ND 5.0 1.8 ug/l 95-95-4 2,4,5-Trichlorophenol ND 5.0 0.74 ug/l 88-06-2 2,4,6-Trichlorophenol ND 5.0 0.80 ug/l 83-32-9 Acenaphthene ND 2.0 0.30 ug/l 208-96-8 Acenaphthylene ND 2.0 0.35 ug/l 120-12-7 Anthracene ND 2.0 0.22 ug/l 56-55-3 Benzo(a)anthracene ND 2.0 0.27 ug/l 50-32-8 Benzo(a)pyrene ND 2.0 0.38 ug/l 205-99-2 Benzo(b)fluoranthene ND 2.0 0.37 ug/l 191-24-2 Benzo(g,h,i)perylene ND 2.0 0.50 ug/l 207-08-9 Benzo(k)fluoranthene ND 2.0 0.37 ug/l 301-55-3 4-Bromophenyl phenyl ether ND 2.0 0.54 ughl 85-68-7 Butyl benzyl phthalate ND 2:0 0.54 ug/l 91-58-7 2-Chloronaphthalene ND 5.0 0.38 ug/l 106-47-8 4-Chloroaniline ND 5.0 0.43 ughl 86-74-8 Carbazole ND 2.0 0.34 ug/l 218-01-9 Chrysene ND 2.0 0.26 ug/I 111-91-1 bis(2-Chloroethoxy)methane ND 2.0 0.34 ug/l 111-44-4 bis(2-Chloroethyl)ether ND 2.0 0.49 ug/l 108-60-1 bis(2-Chloroisopropyl)elher ND 2.0 0.44 ug/l 7005-72-3 4-Chlorophenyl-phenyl ether ND 2.0 1.0 ug/l 95-50-1 1,2-Dichlorobenzene ND 2.0 0.24 ug/l 541-73-1 1,3-Dichlorobenzene ND 2.0 0.32 ug/l 106-46-7 1,4-Dichlorobenzene ND 2.0 0.25 ug/l 121-14-2 2,4-Dinitrotoluene ND 2.0 0.78 ug/l E[l 73 of 122 1 "AC--C.r"TE:,S;T. Method Blank Summary J ob Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 2 of 3 Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OP19692-MB2 H74032.D 1 04/01/05 SSW 03/16/05 OP19692 EH3145 The QC reported here applies to the following samples: N93379-1, N93379-2, N93379-3, N93379-4, N93379-5 Method: SW846 8270C CAS No. Compound 606-20-2 2,6-Dinitrotoluene 91-94-1 3,3'-Dichlorobenzidine 53-70-3 Dibenzo (a,h)anthracene 132-64-9 Dibenzofuran 84-74-2 Di-n-butyl phthalate 117-84-0 Di-n-octy] phithalate 84-66-2 Diethyl phthalate 131-11-3 Dimethyl phthalate 117-81-7 bis(2-Ethylhexyl)phthalate 206-44-0 Fluoranthene 86-73-7 Fluorene 118-74-1 Hexachlorobenzene 87-68-3 Hexachlorobuladiene 77-47-4 Hexachlorocyclopentadiene 67-72-1 Hexachloroethane 193-39-5 lndeno(1,2,3-cd)pyrene 78-59-1 Isophorone 91-57-6 2-Methylnaphihalene 88-74-4 '2-Nitroaniline 99-09-2 3 -Nitroaniline 100-01-6 4-Nitroaniline 91-20-3 Naphthalene 98-95-3 Nitrobenzene 621-64-7 N-Nitroso-di-n-propylamine 86-30-6 N-Nitrosodiphenylamine 85-01-8 Phenanthrene 129-00-0 Pyrene 120-82-1 1,2,4-Trichlorobenzene CAS No. Surrogate Recoveries Result RL MDL Units Q 2.0 5.0 2.0 5.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 20 5.0 2.0 2.0 2.0 5.0 5.0 5.0 2.0 2.0 2.0 5.0 2.0 2.0 2.0 0.62 ug/h 0.39 ug/h 0.58 ug/l 0.49 ug/l 0.79 ug/l 0.63 ug/l 1.4 ug/l 0.58 ug/l 0.74 ug/l 0.63 ug/t 0.89 ugA 1.2 ug/l 0.41 ug/1 0.45 ug/1 0.67 ugh 1.5 ug/l 0.54 ug/l 0.72 ug/1 1.4 ug/l 1.2 ug/l 1.1 ughl 1.0 ughl 0.61 ug/l 0.50 ug/l 0.80 ug/l 0.23 'ug/l 0.58 ug/1 0.32 ug/l 367-12-4 2-Fluorophenol 4165-62-2 Phenol-d5 118-79-6 2,4,6-Tribromophenol 4165-60-0 Nitrobenzene-d5 58%43%72%85%Limits 14-81%10-64%43-126%28-125%OIr3 74 of 122 QACCUTEST. N9337S m!- Method Blank Summary Job Number: N93379Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 3 of 3 Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OP19692-MB2 H74032.D 1 04/01/05 SSW 03/16/05 OP19692 EH3145 The QC reported here applies to the following samples: N93379-1, N93379-2, N93379-3, N93379-4, N93379-5 CAS No. Surrogate Recoveries Method: SW846 8270C 321-60-8 2-Fluorobiphenyl 1718-51-0 Terphenyl-d14 77%86%Limits 32-120%42-125%CAS No. Tentatively Identified Compounds system artifact/aldol-condensation unknownTotal TIC, Semi-Volatile R.T. Est. Conc. Units Q 5.92 32 ug/l 3 17.26 4.1 ug/t J 4.1 ug/l J MIn 75 of 122 UACCUTEST. N9337S .. , .$ Method Blank Summary Page 1 of 3 Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OP19692-MBI R43744.D 1 03/18/05 WHS 03/14/05 OP19692 ER1479 The QC reported here applies to the following samples: Method: SW846 8270C OP19692-MS, OP19692-MSD CAS No. Compound Result RL MDL Units Q 95-57-8 2-Chlorophenol ND 5.0 4.3 ug/h 59-50-7 4-Chloro-3-methyl phenol ND 5.0 4.7 ug/l 120-83-2 2,4-Dichlorophenol ND 5.0 0.73 ug/l 105-67-9 2,4-Dimethylphenol ND 5.0 1.0 ug/l 51-28-5 2,4-Dinitrophenol ND 20 1.1 ug/h 534-52-1 4,6-Dinitro-o-cresol ND 20 0.65 ug/l 95-48-7 2-Methylphenol ND 5.0 0.72 ug/i 3&4-Methylphenol ND 5.0 0.70 ug/l 88-75-5 2-Nitrophenol ND 5,0 0.73 ug/l 100-02-7 4-Nitrophenol ND 20 2.3 ug/l 87-86-5 Pentachlorophenol ND 20 0.75 ug/l 108-95-2 Phenol ND 5.0 1.8 ug/l 95-95-4 2,4,5-Trichlorophenol ND 5.0 0.74 ug/l 88-06-2 2,4,6-Trichlorophenol ND 5.0 0.80 ug/l 83-32-9 Acenaphthene ,ND 2.0 0.30 ug/l 208-96-8 Acenaphthylene ND 2.0 0.35 ug/l 120-12-7 Anthracene ND 2.0 0.22 ug/l 56-55-3 Benzo(a)anthracene ND 2.0 0.27 ug/l 50-32-8 Benzo(a)pyrene ND 2.0 0.38 ug/l 205-99-2 Benzo(b)fluoranthene ND 2.0 0.37 ug/l 191-24-2 Benzo(g,h,i)perylene ND 2.0 0.50 ug/l 207-08-9 Benzo(k)fluoranlhene ND 2.0 0.37 ug/l 101-55-3 4-Bromophenyl phenyl ether ND 2.0 0.54 ug/l 85-68-7 Butyl benzyl phthalate ND 2.0 0.54 ug/l 91-58-7 2-Chloronaphthalene ND 5.0 0.38 ug/l 106-47-8 4-Chloroaniline ND 5.0 0.43 ug/l 86-74-8 Carbazole ND 2.0 0.34 ug/l 218-01-9 Chrysene ND 2.0 0.26 ug/l 111-91-1 bis(2-Chloroethoxy)rmethane ND 2.0 0.34 ug/l 111-44-4 bis(2-Chloroethyl)ether ND 2.0 0.49 ug/l 108-60-1 bis(2-Chloroisopropyl)ether ND 2.0 0.44 ug/l 7005-72-3 4-Chlorophenyl phenyl ether ND 2.0 1.0 ug/l 95-50-1 1,2-Dichlorobenzene ND 2.0 0,24 ug/]541-73-1 1,3-Dichlorobenzene ND 2.0 0.32 ug/l 106-46-7 1,4-Dichlorobenzene ND 2.0 0.25 ug/]121-14-2 2,4-Dinitrotoluene ND 2.0 0.78 ug/l 76 of 122 37ACCUT.EST. N93375 Method Blank Summary Page 2 of 3 Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Sample File ID DF Analyzed By Prep Date Pfep Batch Analytical Batch OP19692-MB1 R43744.D 1 03/18/05 WHS 03/14/05 OP19692 ER1479 The QC reported here applies to the following samples: Method: SW846 8270C OP19692-MS, OP]9692-MSD -.CAS No. Compound Result RL MDL Units Q 606-20-2 2,6-Dinitrotoluene ND 2.0 0,62 ug/t 91-94-1 3,3'-Dichlorobenzidine ND 5.0 0.39 ug/1 53-70-3 Dibenzo(a,h)anthracene ND 2.0 0.58 ug/l 132-64-9 Dibenzofuran ND 5.0 0.49 ug/l 84-74-2 Di-n-butyl phthalate ND 2.0 0.79 ug/l 117-84-0 Di-n-octyl phthalate ND 2.0 0.63 ug/l 84-66-2 Diethyl phihalate ND 2.0 1.4 ug/131-11-3 Dimethyl phthalate ND 2.0 0.58 ug/l 117-81-7 bis(2-Ethylhexyl)phthalate ND 2.0 0.74 ug/I 206-44-0 Fluoranthene ND 2.0 0.63 ug/I 86-73-7 Fluorene ND 2.0 0.89 ug/118-74-1 Hexachlorobenzene ND 2.0 1.2 ug/1 87-68-3 Hexachlorobutadiene ND 2.0 0.41 ug/l 77-47-4 Hexachlorocyclopentadiene ND 20 0.45 ug/l 67-72-1 Hexachloroethane ND 5,0 0.67 ug/l 193-39-5 ]ndeno(1,2,3-cd)pyrene ND 2.0 1.5 ug/l 78-59-1 Isophorone ND 2,0 0.54 ug/l 91-57-6 2-Methylnaphthalene ND 2.0 0.72 ug/l 88-74-4 2-Nitroaniline ND 5.0 1.4 ug/I 99-09-2 3-Nitroaniline ND 5.0 1.2 ug/l 100-01-6 4-Nitroaniline ND 5.0 1.1 ugh]91-20-3 Naphthalene ND 2.0 1.0 ug/l 98-95-3 Nitrobenzene ND 2.0 0.61 ug/l 621-64-7 N-Nitroso-di-n-propylamine ND 2.0 0.50 ug/l 86-30-6 N-Nitrosodiphenylamine ND 5.0 0.80 ug/l 85-01-8 Phenanthrene ND 2.0 0.23 ug/l 129-00-0 Pyrene ND 2.0 0.58 ughl 120-82-1 1,2,4-Trichlorobenzene ND 2.0 0.32 ug/]CAS No. Surrogate Recoveries Limits 367-12-4 2-Fluorophenol 43% 10-88%4165-62-2 Pheno)-d5 24% J0-71%118-79-6 2,4,6-Tribromophenol 67% 45-134%4165-60-0 Nitrobenzene-d5 70% 32-128%1 77 of 122.ACCUT1, ST.N9337S ..:" Method Blank Summary job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 3 of 3 4 4W Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OP19692-MBl R43744.D 1 03/18/05 WHS 03/14/05 OP19692 ER1479 The QC reported here applies to the following samples: Method: SW846 8270C OP19692-MS, OP19692-MSDCAS No. Surrogate Recoveries 321-60-8 2-Fluorobiphenyl 1718-51-0 Terphenyl-d14 -4 Limits 34-121%41-129%72%88%'V'V li 78of 122 Q ACCU IES I N93~379 .-... S.!. Blank Spike Summary Page 1 of 3 Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OP)9692-BS2 H74033.D 1 04/02/05 SSW 03/16/05 OP19692 EH3145 The QC reported here applies to the following samples: Method: SW846 8270C N93379-1, N93379-2, N93379-3, N93379-4, N93379-5 .4 Spike BSP BSP CAS No. Compound ug/l ug/h % Limits 95-57-8" 2-Chlorophenol 50 36.5 73 50-108 59-50-7 4-Chloro-3-methyl phenol 50 40.5 81 55-116 120-83-2 2,4-Dichlorophenol 50 39.2 78 55-115 105-67-9 2,4-Dimethylphenol 50 39.1 78 40-115 51-28-5 2,4-Dinitrophenol 100 70.9 71 33-130 534-52-1 4,6-Dinitro-o-cresol 50 40.7 81 51-125 95-48-7 2-Methylphenol 50 33.0 66 36-101 3&4-Meihylphenol 50 31.9 64 29-96 88-75-5 2-Nitrophenol 50 38.3 77 52-120 100-02-7 4-Nitrophenol 50 28.1 56 1-74 87-86-5 Pentachlorophenol 50 28.6 57 35-124 108-95-2 Phenol 50 19.0 38 4-64 95-95-4 2,4,5-Trichlorophenol 50 39.9 80 57-118 88-06-2 2,4,6-Trichlorophenol 50 42.8 86 59-117 83-32-9 Acenaphthene 50 39.6 79 58-109 208-96-8 Acenaphthylene 50 36.8 74 50-107 120-12-7 Anthracene 50 42.1 84 65-113 56-55-3 Benzo(a)anthracene 50 41.6 83 63-114 50-32-8 Benzo(a)pyrene 50 42.9 86 63-117 205-99-2 Benzo(b)fluoranthene 50 40.7 81 60-121 191-24-2 Benzo(g,h,i)perylene 50 40.9 82 58-125 207-08-9 Benzo(k)fluoranthene 50 49.5 99 60-123 101-55-3 4-Bromophenyl phenyl ether 50 42.8 86 62-117 85-68-7 Butyl benzy] phthalate 50 43.0 86 63-123 91-58-7 2-Chloronaphihalene 50 40.0 80 58-110 106-47-8 4-Chloroaniline 50 32.7 65 38-116 86-74-8 Carbazole 50 44.4 89 68-122 218-01-9 Chrysene 50 44.4 89 65-114 111-91-1 bis(2-Chloroethoxy)methane 50 40.5 81 57-119 111-44-4 bis(2-Chloroethyl)ether 50 38.6 77 53-116 108-60-1 bis(2-Chloroisopropyl)ether 50 39.4 79 56-113 7005-72-3 4-Chloroplienyl phenyl ether 50 41.8 84 61-114 95-50-1 1,2-Dichlorobenzene 50 35.6 71 54-106 541-73-1 1,3-Dichlorobenzene 50 35.5 71 51-104 106-46-7 1,4-Dichlorobenzene 50 35.2 70 52-104 121-14-2 2,4-Dinitrotoluene 50 43.2 86 62-12279 of 122 3-ACCUTEST. N9337S? ý: - Blank Spike Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 2 of 3 Sample File ID DF OP]9692-BS2 H74033.D I Analyzed By Prep Date Prep Batch Analytical Batch 04/02/05 SSW 03/16/05 OP19692 EH3145 The QC reported here applies to the following samples: N93379-1, N93379-2, N93379-3, N93379-4, N93379-5 Method: SW846 8270C-4 i~o Spike BSP BSP ug/l ug/l % LimitsýwV CAS No. Compound 606-20-2 2,6-Dinitrotoluene 91-94-1 3,3'-Dichlorobenzidine 53-70-3 Dibenzo(a,h)anthracene 132-64-9 Dibenzofuran 84-74-2 Di-n-butyl phthalate 117-84-0 Di-n-octyl phthalate 84-66-2 Diethyl phthalate 131-11-3 Dimelhyl phthalate:117-81-7 bis(2-Ethylhexyl)phthalale 206-44-0 Fluoranthene 86-73-7 Fluorene 118-74-1 Hexachlorobenzene 87-68-3 Hexachlorobutadiene 77-47-4 Hexachlorocyclopentadiene 67-72-1 Hexachloroethane 193-39-5 lndeno(1,2,3-cd)pyrene 78-59-1 Isophorone 91-57-6 2-Methylnaphthalene 88-74-4 2-Nitroaniline 99-09-2 3-Nitroaniline 100-01-6 4-Nitroaniline 91-20-3 Naphthalene 98-95-3 Nitrobenzene 621-64-7 N-Nitroso-di-n-propylamine 86-30-6 N-Nitrosodiphenylamine 85-01-8 Phenanthrene 129-00-0 Pyrene 120-82-1 1,2,4-Trichlorobenzene CAS No. Surrogate Recoveries 367-12-4 2-Fluorophenol 4,165-62-2 Pheno!-d5 118-79-6 2,4,6-Tribromophenol 4165-60-0 Nitrobenzene-d5 50 50 50 50 50 50 50 50,-50 50 50 50 50 100 50 50 50 50 50 50 50 50 50 50 50 50 50 50 BSP 46%36%83%71%43.1 86 63-122 34.7 69 43-129 42.4 85 60-126 40.2 80 62-114 42.5 85 67-122 50.6 101 60-139 41.4 83 60-123 41.5 83 63-116 43.9 88 61-124 42.2 84 64-117 42.3 85 61-114 42.8 86 62-116 37.2 74 50-118 53.6 54 24-114 35.1 70 50-106 43.1 86 58-124 39.6 79 51-111 36.1 72 55-108 41.5 83 57-128 34.1 68 48-128 41.3 83 51-131 37.0 74 53-106 37.3 75 55-110 39.3 79 54-123 42.7 85 62-119 41.7 83 63-111 43.9 88 61-113 35.6 71 52-105 Limits 14-81%10-64%43-126%28-125%80 of 122 7ACCUTT.S.. N93379 Blank Spike Summary Job Number: N93379Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 3 of 3 6F Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OP19692-BS2 H74033.D 1 04/02/05 SSW 03/16/05 OP19692 EH3145 The QC reported here applies to the following samples: N93379-1, N93379-2, N93379-3, N93379-4, N93379-5 Method: SW846 8270C-J CAS No. Surrogate Recoveries 321-60-8 2-Fluorobiphenyl 1718-51-0 Terphenyl-d14 BSP 74%85%Limits 32-120%42-125%QACCUTIEST. N93379 -1 .; I Matrix Spike/Matrix Spike Duplicate Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 1 of 3 Sample File ID DF OP19692-MS R43747.D 1 OP19692-MSD R43748.D I N93090-14 R43746.D I Analyzed By Prep Date Prep Batch Analytical Batch 03/18/05 WHS 03/14/05 OP19692 ER1479 03/18/05 WHS 03/14/05 OP19692 ER1479 03/18/05-WHS 03/14/05 OP19692 ER1479 The QC reported here applies to the following samples:N93379-1, N93379-2, N93379-3, N93379-4, N93379-5 Method: SW846 8270C N93090-14 Spike MS MS MSD MSD ug/l Q ug/l ug/l % ug/l % RPD Limits Rec/RPD CAS No. Compound#4V 95-57-8 2-Chlorophenol ND 59-50-7 4-Chloro-3-methyl phenol ND 120-83-2 2,4-Dichlorophenol ND 105-67-9 2,4-Dimethylphenol ND 51-28-5 2,4-Dinitrophenol ND 534-52-1 4,6-Dinitro-o-cresol ND 95-48-7 2-Methylphenol ND 3&4.Methylphenol ND 88-75-5 2-Nitrophenol ND 100-02-7 4-Nitrophenol ND 87-86-5 Pentachlorophenol ND 108-95-2 Phenol ND 95-95-4 2,4,5-Trichlorophenol ND 88-06-2 2,4,6-Trichlorophenol ND 83-32-9 Acenaphthene ND 208-96-8 Acenaphthylene ND 120-12-7 Anthracene ND 56-55-3 Benzo(a)anthracene ND 50-32-8 Benzo(a)pyrene ND205-99-2 Benzo(b)fluoranthene ND 191-24-2 Benzo(g,h,i)perylene ND207-08-9 Benzo(k)fluoranthene ND 101-55-3 4-Bromophenyl phenyl ether ND 85-68-7 Buty] benzyl phthalate ND 91-58-7 2-Chloronaphthalene ND 106-47-8 4-Chloroaniline ND86-74-8 Carbazole ND218-01-9 Chrysene ND 1 11-91-1 bis(2-Chloroethoxy)methane ND 111-44-4 bis(2-Chloroelhyl)ether ND 108-60-1 bis(2-Chloroisopropyl)ether ND 7005-72-3 4-Chlorophenyl phenyl ether ND 95-50-1 1,2-Dichlorobenzene ND 541-73-1 1,3-Diclhlorobenzene ND 106-46-7 1,4-Dichlorobenzene ND 121-14-2 2,4-Dinitrotoluene ND 50 50 50 50 100 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 39.8 80 38.6 77 3 49.2 98 47.6 95 3 49.4 99 47.7 95 4 41.1 82 40.5 81 1 90.7 91 84.2 84 7.48,2 96 46.3 93 4 32.6 65 31.5 63 3 30,0 60 28.7 57 4 51.3 103 49.3 99 4 25.7 51 22.9 46 12 52.0 104 49.4 99 5 13.6 27 12.5 25 8 52.3 105 49.7 99 5 52,1 104 50.3 101 4 40.8 82 40.0 80 .2 39.3 79 38.4 77. 2 42.9 86 42.5 85 1 45.5 91 44.1 88 3 45.3 91 43.3 87 5 54.3 109 52.2 104 4 27.3 55 28.0 56 3 48.4 97 46.7 93 4 51.0 102 49.7 99 3 50.0 100 47.9 96 4 45.7 91 .45.0 90 2 26.2 52 27.8. 56 6 47.3 95 47.1 94 0 45.8 92 44.0 88 4 45.0 90 43.6 87 3 41.1 82 40,] 80 2 46.0 92 45.5 91 1 50.7 101 48.9 98 4 41.5 83 41.3 83 0 40.9 82 40.8 82 :040.1 80 39.1 78 3 53.7 107 52.3 105 3 30-117/28 36-129/25 37-124/27 28-121/28 8-144/32 24-142/29 30-114/28 21-122/28 34-123/27 1-129/33 36-143/24 1-102/32 41-131/24 43-121/25 40- 114/30 36-106/31 54-119/23 57-122/22 53-126/23 50-135/26 35-141/29 37-144/24 49-121/25 56-132/23 34-115/30 10-108/37 49-146/22 55-125/23 37-119/32 32-122/37 34-112/32 43-1 18/27 31-110/31 27-107/32 29-108/31 50-125/3]*AV B13, r 82 of 122"ACCUTEST. Matrix Spike/Matrix Spike Duplicate Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJPage 2 of 3 Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OP19692-MS R43747.D 1 03/18/05 WES 03/14/05 OP19692 ER1479 OP19692.MSD R43748.D 1 03/18/05 WHS 03/14/05 OP19692 ER1479 N93090-14 R43746.D 1 03/18/05 WHS 03/14/05 OP19692 ER1479 The QC reported here applies to the following samples: N93379-1, N93379-2, N93379-3, N93379-4, N93379-5 Method: SW846 8270C-4 CAS No. Compound N93090-14 Spike MS MS MSD MSD ug/l Q ug/1 ug/l % ug/1 %Limits RPD Rec/RPD'6V 606-20-2 2,6-Dinilrotoluene ND 91-94-1 3,3'-Dichlorobenzidine ND 53-70-3 Dibenzo(a,h)anthracene ND 132-64-9 Dibenzofuran ND 84-74-2 Di-n-butyl phthalate ND 117-84-0 Di-n-octyl phthalate ND 84-66-2 Diethy] phthalate ND 131-11-3 Dimethyl phthalate ND 117-81-7 bis(2-Ethylhexyl)phthalate ND 206-44-0 Fluoranthene ND 86-73-7 Fluorene ND 1]8-74-1 Hexachlorobenzene ND 87-68-3 Hexachlorobutadiene ND 77-47-4 Hexachlorocyclopeniadiene ND 67-72-1 Hexachloroethane ND 193-39-5 Indeno(1,2,3-cd)pyrene ND 78-59-1 Isophorone ND 91-57-6 2-Methylnaphihalene ND 88-74-4 2-Nitroaniline ND 99-09-2 3-Nitroaniline ND 100-01-6 4-Nitroaniline ND 91-20-3 Naphthalene ND 98-95-3 Nitrobenzene ND 621-64-7 N-Nitroso-di-n-propylamine ND 86-30-6 N-Nitrosodiphenylamine ND 85-01-8 Phenanthrene ND 129-00-0 Pyrene ND 120-82-1 1,2,4-Trichliorobenzene ND 50 50 50 50 50 50 50 50 50 50 50 50 50 100 50 50 50 50 50 50 50 50 50 50 50 50 50 50 55.1 110 ND 0*a 32.3 65 45.0 90 47.1 94 68.0 136 45.9 92 48.0 96 50.1 100 47.0 94 45.4 91 52.1 104 45.2 90 61.8 62 43.2 86 31.0 62 40.5 81 42.3 85 41.3 83 27.7 55 46.2 92 41.2 82 45.3 91 41.0 82 42.6 85 43.4 87 45.5 91 43.8 88 53.1 106 .4 ND 0* nc 32.9 .66 2 43.8 88 346.1 92 2 63.4 127 7 44.6 89 3 46.8 94 3 48.0 96 4 46.9 94 0 45.3 91] .0 50.9 102 2.44.5 89 2 58.1 58 6 43.1 86 0 32.1 64 3 40.6 81, 0 41.4 .83 2 40.1 80 3 26.9 54 3 45.6 91 1 40.8 82 1 44.4 89 2 39.9 80 3 41.7 83 .2 42.7 85 2 44.2 88 3 42.7 85 3 45-124/28 1-145/37 40-138/27 42-119/28 54-131/22 49-151/25 49-123/24 39-124/27 51-140/29 52-129/22 43-116/26 49-121/24 30-126/33 1-109/41 22-113/34 40-139/28 34-116/37 28-123/32 30-135/33 15-134/35 18-153/32 22-120/30 31-118/32 32-125/33 49-131/24 51-117/23 54-122/22 27-115/31 CAS No. Surrogate Recoveries 367-12-4 2-Fluorophenol4165-62-2 Pheno]-d5 118-79-6 2,4,6-Tribromophenol 4165-60-0 Nitrobenzene-d5 MS MSD N93090-14 Limits 38%22%99%72%35%26%95%71%31%16%87%80%10-88%10-71%45-134%32-128%far 0 .J- 83 of 122 1ACCUTEST. N93379 .I ,, ý." ! , -* Matrix Spike/Matrix Spike Duplicate Summary Job Number: N93379 Page 3 of 3 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch OPI9692-MS R43747.D 1 03/18/05 WHS 03/14/05 OP19692 ER1479 OP19692-MSD R43748.D 1 03/18/05 WHS 03/14/05 OP19692 ER1479 N93090-14 R43746.D 1 03/18/05 WHS 03/14/05 OP19692 ER1479 The QC reported here applies to the following samples: N93379-1, N93379-2, N93379-3, N93379-4, N93379-5 Method: SW846 8270C-4 CAS No. Surrogate Recoveries 321-60-8 2-Fluorobiphenyl 1718-51-0 Terphenyl-di4 (a) Outside of in house control limits.MS 81%94%MSD 79%88%N93090-14 Limits 80%95%34-121%41-129%IUACCUTIEES N'93379 -;"ý - Instrument Performance Check (DFTPP)Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 1 of I kw'V Sample: EH3145-DFTPP Injection Date: 04/01/05 Lab File ID: H74023.D Injection Time: 18:02 Instrument ID: GCMSH Raw % Relative m/e ]on Abundance Criteria Abundance Abundance Pass/Fail 51 30.0- 60.0% of mass 198 4103 42.3 Pass 68 Less than 2.0% of mass 69 52 0.54 (0.88)2 Pass 69 Mass 69 relative abundance 5933 61.2 Pass 70 Less than 2.0% of mass 69 0 0.0 (0.0)2 Pass 127 40.0 -60.0% of mass 198 5552 57.2 Pass 197 Less than 1.0% of mass 198 0 0.0 Pass 198 Base peak, 100% relative abundance 9701 100.0 Pass 199 5.0 -9.0% of mass 198 726 7.5 Pass 275 10.0 -30.0% of mass 198 2259 23.3 Pass 365 1.0 -100.0% of mass 198 237 2.4 Pass 441 Present, but less than mass 443 1027 10.6 .(74.0) b Pass 442 40.0 -100.0% of mass 198 7484 77.1 Pass 443 17.0 -23.0% of mass 442 1387 14.3 (18.5)C Pass (a) Value is % of mass 69 (b) Value is % of mass 443 (c) Value is % of mass 442 This check applies to the following Samples, MS, MSD, Blanks, and Standards: Lab Lab Date Time Hours Client Sample ID File ID Analyzed Analyzed Lapsed Sample ID EH3145-1CC3145 H74024.D 04/01/05 19:04 01:02 Initial cal 25 EH3145-1C3145 H74025.D 04101/05 19:35 01:33 Initial cal 50EH3145-]C3145 H74026.D 04/01/05 20:06 02:04 Initial cal 80 EH3145-IC3145 H74027.D 04(01/05 20:51 02:49 Initial cal 100 EH3145-1C3145 H74028.D 04/01/05 21:21 03:19 Initial cal 10 EH3145-1C3145 H74029.D 04/01/05 22:06 04:04 Initial cal 5 EH3145-1C3145 H74030.D 04/01/05 22:36 04:34 Initial cal 2 OP19692-MBZ H74032.D 04/01/05 23:54 05:52 Method Blank OP19692-BS2 H74033.D 04/02/05 00:39 06:37 Blank Spike ZZZZZZ H74034.D 04/02/05 01:23 07:21 (unrelated sample) ZZZZZZ H74035.D 04/02/05 01:52 07:50 (unrelated sample)ZZZZZZ H74036.D 04/02/05 02:28 08:26 (unrelated sample)N93379-1 H74037.D 04/02/05 03:12 09:10 WELL AY N93379-2 H74038.D 04/02/05 03:46 09:44 WELL X N93379-3 H74039.D 04/02/05 04:31 10:29 WELL AV N93379-4 H74040.D 04/02/05 05:01 10:59 WELL AVD N93379-5 H74041..D 04/02/05 05:45 11:43 FB-031505 610 f~i85 of 122 Q ACCUITEST. N9337S Instrument Performance Check (DFTPP)Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 1 of 1 Sample: ER1468-DFTPP" Injection Date: 03(03/05 Lab File ID: R43545.D Injection Time: 16:50 Instrument ID: GCMSR Raw % Relative m/e Ion Abundance Criteria Abundance Abundance Pass/Fail 51 30.0 -60.0% of mass 198 32145 44.3 Pass 68 Less than 2.0% of mass 69 382 0.53 (1.1)a Pass 69 Mass 69 relative abundance 35172 48.5 Pass 70, Less than 2.0% of mass 69 58 0.08 (0.16) a Pass 127 40.0 -60.0% of mass 198 39640 54.6 Pass 197 Less than 1.0% of mass 198 0 0.0 Pass 198 Base peak, 100% relative abundance 72552 100.0 Pass 199 5.0 -9.0% of mass 198 5075 7.0 Pass 275 10.0 -30.0% of mass 198 17659 24.3 Pass 365 1.0 -100.0% of mass 198 2540 3.5 Pass 441 Present, but less than mass 443 7677 10.6 (80.7) b Pass 442 40.0 -100.0% of mass 198 50147 69.1 Pass 443 17.0 -23.0% of mass 442 9514 13.1 (19.0) C Pass (a) Value is % of mass 69 (b) Value is % of mass 443 (c) Value is % of mass 442 This check applies to the following Samples, MS, MSD, Blanks, and Standards: Lab Lab Date Time Hours Client Sample ID File ID Analyzed Analyzed Lapsed Sample ID ER1468-1CC1468 R43546.D 03/03/05 17:00 00:10 Initial cal 50 ER1468-1C1468 R43547.D 03/03/05 17:48 00:58 Initial cal 100 ER1468-1C1468 R43548.D 03/03/05 18:32 01:42 Initial cal 80 ER1468-1C1468 R43549.D 03/03/05 19:15 02:25 Initial cal 25 ER1468-1C1468 R43550.D 03/03/05 19:59 03:09 Initial cal 10 ER1468-ICI 468 R43551.D 03/03/05 20:43 03:53 Initial cal 5 ER3468-IC1468 R43552,D 03/03/05 21:26 04:36 Initial cal 2-4 U CE r] 86 of 122 U ACCUTE-ST. N93379 Instrument Performance Check (DFTPP)Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 1 of 1 Sample: ER1479-DFTPP Injection Date: 03/18/05 Lab File ID: R43740.D Injection Time: 10:30 Instrument ID: GCMSR Raw % Relative m/e Ion Abundance Criteria Abundance Abundance Pass/Fail 51 30.0 -60.0% of mass 198 42965 34.2 Pass 68 Less than 2.0% of mass 69 261 0.21 (0.54) 2 Pass 69 Mass 69 relative abundance 48635 38.7 Pass 70 Less than 2.0% of mass 69 211 0.17 (0.43) 8 Pass 127 40.0 -60.0% of mass 198 61345 48.8 Pass 197 Less than 1.0% of mass 198 0 0.0 Pass 198 Base peak, 100% relative abundance 125768 100.0 Pass 199 5.0 -9.0% of mass 198 8364 6.7 Pass 275 10.0 -30,0% of mass 198 34584 27.5 Pass 365 1.0 -100.0% of mass 198 4956 3.9 Pass 441 Present, but less than mass 443 16859 13.4 (74.9) b Pass 442 40.0 -100.0% of mass 198 114779 91.3 Pass 443 17.0 -23.0% of mass 442 22499 17.9 (19.6) C Pass (a) Value is % of mass 69 (b) Value is % of mass 443 (c) Value is % of mass 442 This check applies to the following Samples, MS, MSD, Blanks, and Standards: Lab Lab Date Time Hours Client Sample ID File ID Analyzed Analyzed Lapsed Sample ID ER1479-CC1468 R43741.D 03/18/05 10:45 00:15 Continuing cal 25 OP19709-LS2 R43742.D 03/18/05 11:21 00:51 Leachate Spike ZZZZZZ R43743.D 03/18/05 12:07 01:37 (unrelated sample)OP19692-MBI R43744.D 03/18/05 12:53 02:23 Method Blank OP19692-BSI R43745.D 03/18/05 13:36 03:06 Blank Spike N93090-14 R43746.D 03/18/05 14:19 03:49 (used for QC only; no( part of job N93379)OP19692-MS R43747.D 03/18/05 15:03 04:33 Matrix Spike OP19692-MSD R43748.D 03/18/05 15:47 05:37 Matrix Spike Duplicate ZZZZZZ R43749.D 03/18/05 16:29 05:59 (unrelated sample)ZZZZZZ R43750.D 03/18/05 17:13 06:43 (unrelated sample)ZZZZZZ R43751.D 03/18/05 17:56 07:26 (unrelated sample)ZZZZZZ R43752.D 03/18/05 18:40 08:10 (unrelated sample)ZZZZZZ R43753.D 03/18/05 19:23 08:53 (unrelated sample)ZZZZZZ R43754.D 03/18/05 20:06 09:36 (unrelated sample)ZZZZZZ R43755.D 03/18/05 20:50 10:20 (unrelated sample)ZZZZZZ R43756.D 03/18/05 21:33 11:03 (unrelated sample)ERTJ 87 of 122 NACCUTES.- N9337S Semivolatile Internal Standard Area Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 1 of I*W Check Std: EH3145-1CC3145 Injection Date: 04/01/05 Lab File ID: H74024.1) Injection Time: 19:04 Instrument ID: GCMSH Method: SW846 8270C IS] IS2 IS3 IS 4 IS5 IS6 AREA RT AREA RT AREA RT AREA RT AREA RT AREA RT Check Std 1531.58 8.63 636381 10.66 276929 14.10 409247 17.47 335074 22.51 315770. 24.90 Upper Limita 306316 9.13 1272762 11.16 553858 14.60 818494 17.97 670148 23.01 631:540 25.40 Lower Limitb 76579 8.13 318191 10.16 138465 13.60 204624 16.97 167537 22.01 157885 24,40 Lab Sample ID ISI AREA RT OP19692-MB2 OP]9692-BS2 zzzzzz zzzzzz zzzzzz N93379-1 N93379-2 N93379-3 N93379-4 N93379-5 157294 161578 132716 181943 187046 162438 151724 166034 159765 157954 8.63 8.64 8.64 8.64 8.64 8.64 8.64 8.65 8.65 8.65 Is 2 AREA 608911 703386 520478 713707 736247 631491 578453 627729 611615 620822 10.66 10.67 10.67 10.68 10.67 10.67 10.68 10.68 10.68 10.68 IS 3 RT AREA RT 294346 292342 248554 357643 350343 301014 271059 295517 285582 295023 14.10 14.11 14.11 14.13 14.11 14.12 14.13 14.13 14,13 14.12 IS 4 AREA 442111 413336 353134 449966 500411 424267 384031 410401 397200 425212 IS5 IS6 RT AREA RT AREA RT 17.47 17.49 17.48 17.50 17.49 17.49 17.49 17.50 17.50 17.50 330113 22.52 302017 22.52 261497: 22.52 300475 22.52 356482. 22.52 323807 22.52 304464. 22.52 312340 22.52 304682 22.53 320843 22.53 291971 262436 234528 286321 309192 303459 305873 306595 295846 300804 24.91 24.91 24.91 24.93 24.92.24.92 24.93 24.93 24.93 24.93 is 1 IS 2 IS 3 IS 4 IS 5 IS 6= 1,4-Dichlorobenzene-d4 = Naphthalene-d8 = Acenaphthene-DI 0= Phenanthrene-d]0 = Chrysene-d]2 = Perylene-d1 2 (a) Upper Limit + 100% of check standard area; Retention time +0.5 minutes.(b) Lower Limit -50% of check standard area; Retention time -0.5 minutes.EI! 88 of 122 12ACCU ES1." ' Semivolatile Internal Standard Area Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 1 of ICheck Std: ER1479-CC1468 Injection Date: 03/18/05 Lab File ID: R43741.D Injection Time: 10:45 Instrument ID: GCMSR Method: SW846 8270C is I ' IS2 IS3 IS4 IS5 IS6 AREA RT AREA RT AREA RT AREA RT AREA RT AREA RT Check Std 352195 7.80 1274165 11.96 65.3525 18,24 1013796 22.23 811227 28.67 689790 31.83 Upper Limit a 704390 8.30 2548330 12.46 1307050 18.74 2027592 22.73 1622454 29.17 1379580 32.33 Lower Limit b 17,6098 7.30 637083 11.46 326763 17.74 506898 21.73 405614 28.17 344895 31.33 Lab is 1 Sample ID AREA RT IS 2 IS 3 AREA RT AREA RT IS 4 IS 5 IS6 AREA RT AREA RT AREA RTOPI 9709-LS2 zzzzzz OP19692-MB1 OPI9692-BSI N93090-14 OP19692-MS OPI9692-MSD zzzzzz zzzzzz zzzzzz zzzzzz zzzzzz zzzzzz zzzzzz zzzzzz 332974 346220 367504 353877 299940 394331 335399 361145 326038 347617 314792 382064 378553 414688 333353 7.81 7.80 7.81 7.81 7.82 7.81 7.81 7.81 7.81 7.81 7.81 7.83 7.81 7.81 7.81 1227618 11.95 1267163 11.95 1274885 11.95 1346002 11.95 1020291 11.96 1501241 11.96 1279709 11.96 1256143 11.95 1262732 11.95 1285817 11.95 1085439 11.96 1425453 11.96 1329413 11.95 1512042 11.95 1157767 11,95 655631 631027 680764 715568 57,2424 824139 702791 695124 730390 731717 589102 711118 706117 794951 633028 18.23 18&24 18.24 18.23 18.23 18.24 18.24 18,24 18.24 18,24 18.23 18.23 18.23 18.24 18.24 1098964 22.24 989766 22.24.1107702 22,24 1153467 22.241003530 22.23 1341781 22.24 1137541 22.24 1155644 22.23 1247066 22.24 1241462 22.23 977125 22.241146483 22.231146848 22.23 1289419 22.23 1068194 22.23 850404 28.68 7927,67 28.67 888996. 28.68985923. 28.67 89291B 28.67 1.133754 28.67 995673 28.67 101.0936 28.67 1078502 28.67 1027959 28.67 804080 28.68 933393 28.67 944187 28.67 1039205 28.67 933424 28.67 671296 657628 694727 837675 67.6803 757628 698726 823956 764920 700013 583952 673506 721182 786817 739134 31.83 31.83 31.83 31.83 31.82 31.82 31,82 31.82 31.82 31.83 31.83 31.82 31.82 31.82 31.82IS I IS 2 IS 3 IS 4 IS 5 IS 6= 1,4-Dichlorobenzene-d4 = Naphthalene-d8 = Acenaphthene-DIO = Phenanthrene-dIO = Chrysene-d 12= Perylene-d02 (a) Upper Limit = + 100% of check standard area; Retention time +0.5 minutes.(b) Lower Limit = -50% of check siandard area; Retention time -0.5 minutes, fn 89 of 122 1ACCUTES .N93375 ; : .:, .-f -. Semivolatile Surrogate Recovery Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJPage 1 of I 'V Method: SW846 8270C Matrix: AQ Samples and QC shown here apply to the above method Lab Sample ID Lab File ID N93379-1 H74037.D N93379-2 H74038.DN93379-3 H74039.D N93379-4 H74040.D N93379-5 H74041..D OP19692-BS2 H74033.D OPJ9692-MB2 H74032.D OPI9692-MS R43747.D OP]9692-MSD R43748.D OP19692-MB1 R43744.D Surrogate Compounds Si = 2-Fluorophenol S2 = Phenol-d5 S3 = 2,4,6-Tribromophenol S4 = Nitrobenzene-d5 S5 = 2-Fluorobiphenyl S6 = Terphenyl-d14 S1 S2 S3 S4 S5 S6 45.0 27.0 80.0 90.0 82.0 89.0 36.0 23.0 78.0 71.0 67.0 83.0 45.0 28.0 95.0 93.0 82.0 90,0 47.0 29.0 96.0 97.0 84.0 89.0 44.0 28.0 80.0 92.0 83.0 92.046.0 36.0 83.0 71.0 74.0 85.0 58.0 43.0 72.0 85.0 77.0 86.0 38.0 22.0 99.0 72.0 81.0 94.0 35.0 26.0 95.0 71.0 79.0 88,0 43.0 24.0 67.0 70.0 72.0 88,0 Recovery Limits 14-81%10-64%43-126%28-125%32-120%42-125%0, EM~ 9001f122 UACCUTIMT. N93379 .. ',.. Initial Calibration Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 1 of 3 Sample: EH3145-1CC3145 Lab FilelD: H74024.D Response Factor Report MSH Method Title Last Update Response via C:\HPCHEM\1\METHODS\MH3145.M (RTE Integrator) Semi Volatile Extractables by GC/MS Sat Apr 02 08:32:42 2005 Initial Calibration Calibration File!100 =H74027.D 25 =H74024;D 2 =H74030,D 50 =H74025.D 5 =H74029.D 80 =H74026.D 10 =H74028.D Compound 100 2 5 10 25 50 80 Avg %RSD-4-'I1) I 1,4-Dichlorobenzene-d
ISTD --------------------- 2)t 1,4-Dioxane 0.539 0.941 0.797 0.715 0.642 0.625 0.615 0.696----- Linear regression
Coefficient
= 0.9912 Response Ratio = 0.04514 + 0.55440 *A 3)t 4)t 5)S 6)t 7)t 8)S 9)t 10)t Pyr i di ne N-Nitrosodimethyl
2-Fluorophenol I ndene Cumene Phenol-d5 Phenol Aniline 1.460 0.521 1.464 2.257 2.468 1.981 2.130 1.762 1.356 0.602 1.336 2.258 2 .643 1.781 1.862 1.895 1.548 0.560 1.431 2.368 2.716 1.948 2.002 1.945 1.744 0.646 1.645 2.717 3.089 2.255 2.304 0.858 1.289 0.583 1.676 2.505 2.902 2.280 2.036 1.767 1.492 0.575 1,709 2.500 2.838 2.295 2.241 1.848 1.593 0,560 1.735 2.465 2,722 2.320 2.265 1.851 1..497 0.578 1 .571 2.439 2. 768 2.123 2.120 1 .704-Linear regression
Coefficient
= 0.9962 Response Ratio = -0.04649 + 1.82345 *A 11)t bis(2-Chloroethyl 1.641 1.604 1,742 2.426 1.788 1,720 1.613 1.791-Linear regression
Coefficient
= 0,9976 Response Ratio = 0,08515 + 1.60374 *A 12)13)t 14)t 15)t 16)t 17)t 18)t 19)t 20) t 21)t 22)t 23)t 24)t Benzaldehyde 2-Chlorophenol Decane 1,3-Dich)orobenze 1,4-Dichlorobenze Benzy] alcohol 1,2-Dichlorobenze Acetophenone 2-Methylphenol 2,2'-oxybis(1-Chl 3&4-Methylphenol n-Nitroso-di-n-pr Hexachloroethane 0.095 1.445 1.316 1.405 1.450 0.920 1.405 1 .776 1,271 0.511 1.372 0.944 0.546 0.636 1.410 1.691 1.528 1.595 0.591 1.466 1.774 1.187 0.551 1.218 0.952 0.594 0.967 1.452 1,499 1 .536 1.627 0.692 1,461 1.921 1.367 0.525 1.467 0.972 0.610 0.913 1.686 1.648 1.715 1.787 0.791 1,679 2.176 1.537 0.609 1.723 1.145 0.670 0.483 1 .532 1 .538 1.557 1.638 0.980 1 .510 1 .994 1.382 0.540 1 .465 1 .037 0.620 0.399 1.511 1.450 1.537 1.599 0,898 1.519 1.978 1.399 0.536 1 .457 1.009 0.608 0.341 0.318 0.601 0.637 0.204 0.284 0.219 0,406 0,238 0.255 0.245 0.182 1,553 1,423 1.516 1.568 0.803 1.539 1.973 1.403 0.536 1.334 1.011 0.592 0.312 0.281 0.540 0.573 0.189 0.239 0.197 0.372 0.222 0.234 0.226 0.525 1.513 1.509 1.542 1.609 0.811 1.511 1.942 1,364 0.544 1.434 1.010 0.606 0.349 0,324 0.619 0.656 0.206 0.300 0.197 0.422 0.252 0.261 0.254 19.44 10.11 6.76 10.03 6.63 7.17 10.15 7,63 22.21 16.12 64.00 6.08 8.62 5.90 6.22 16.77 5.72 7.15 8.10 5.73 10.91 6.79 6.12 12.82 13.38 14.74 14.09 11.42 14.38 13.70 13.94 11 .84 12.50 12.76 25) I Naphthalene-d8 26)5 Nitrobenzene-d5 27)t Nitrobenzene 28)t Quinoline 29)t Isophorone 30)t 2-Nitrophenol 31)t 2,4-Dimethylpheno 32)t Benzoic acid 33)t bis(2-Chloroethox 34)t 2,4-Dichloropheno 35)t 1,3,5-Trichlorobe 36)T 1,2,4-Trichlorobe
ISTD-0.279 0.258 0,478 0.516 0.172 0.182 0,334 0.209 0.207 0.202 0.366 0.342 0.653 0.684 0.202 0.278 0.439 0.270 0.283 0.268 0.369 0.350 0.654 0.688 0.218 0.325 0.154 0.453 0.267 0.268 0.272 0.418 0.387 0.761 0.801 0.247 0.364 0.229 0.516 0 294 0.306 0 .300 0. 361 0.333 0. 649 0.692 0.212 0.312 0.204 0.431 0.264 0.272 0.262 N93379 Initial Calibration Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 2 of 3 Sample: EH3145-]CC3145 Lab FilelD: H74024.D y 37)T 38)t 39)t 40)t 41)t 42)t 43)t 44) t 45)t 46)t 4.7)t 1,2,3-Trichlorobe alpha-Terpineol Naphthalene 4-Chloroaniline 2,3-Dichloroanili Caprolactam Hexachlorobutadie 4-Chloro-3-methyl 2-Methylnaphthale 1-Methylnaphthale Dimethylnaphtha le 0.193 0.256 0.217 0.291 0.750 1.015 0.419 0.231 0.316 0.139 0.094 0.125 0.209 0.272 0.482 0.667 0.440 0.626 0.382 0.509 0.260 0. 288 1.003 0.428 0.312 0.157 0.122 0.277 0.661 0.616 0.514 0,288 0.329 1 .137 0.374 0.347 0.177 0.140 0.316 0.742 0.693 0.580 0.255 0.292 0.972 0.363 0.311 0.151 0.120 0.271 0.654 0.602 0.512 0,235 0.270 0.912 0.363 0.287 0,134 0,114 0.251 0.599 0,560 0.482 0.213 0,242 0.842 0.292 0.258 0.125 0.106 0.217 0,555 0,519 0,434 0.243 0.276 0.947 0.373 0.295 0.147 0.117 0.259 0.623 0.579 0.488 48) I Acenaphthene-dlO
ISTD --------------------- 49)t Hexachlorocyclope 0.029 0.094 0.141 0.205 0.241 0.142------Linear regression
Coefficient
= 0.9905 Response Ratio = -0.09414 + 0.25625 *A 50)t.2,4,6-Trichloroph 51)t 2,4,5-Trichloroph 52)S 2-Fluorobiphenyl 53)t 2-Chloronaphthale 54)t Biphenyl 55)t 2-Nitroaniline 56)t Dimethylphthalate 57)t Acenaphthylene 58)t 2,6-Dinitrotoluen 59)t 3-Nitroaniline 60)t Acenaphthene 61)t 2,4-Dinitrophenol 62)t 4-Nitrophenol 63)t Dibenzofuran64)t 2,4-Dinitrotoluen65)t Diethylphthalate 66)t Fluorene 67)t 4-Chlorophenyl-ph 68)t 4-Nitroaniline 0.342 0.380 1.346 1.113 1 419 0.344 1, 257 1 776 0.319 0.389 1.089 0.214 0.109 1 .556 0.441 1.270 1.227 0.527 0.383 0.250 1.312 1.127 1 .505 0.326 1.327 1.796 0.286 0.348 1.175 1.574 0.371 1 .354 1.216 0.521 0.318 0,323 0.282 1.373 1.156 1 .498 0.342 1 362 1.883 0.315 0.401 1 .140 0.092 1.646 0.439 1 .389 1 .287 0.535 0,394 0.371 0.410 1.586 1.331 1.741 0.414 1.590 2.182 0.381 0.473 1.337 0.203 0.127 1. 886 0.531 1.,604 1 .472 0.624 0,479 0.361 0,399 1.493 1.272 1.630 0.389 1.427 2.050 0.363 0.434 1.252 0.207 0.129 1.783 0.490 1.489 1.374 0.558 0.453 0.345 0.421 1,504 1.249 1.649 0.396 1.404 2.015 0,365 0.442 1.236 0.235 0.119 1.786 0.506 1.458 1 .384 0.584 0.452 0,199 0.170 0.641 1.050 0.161 0.216 0.269 0.155 1,188 1 .257 1.167 1.704 1.133 0.685 0.333 0.419 1.513 1.223 1.592 0.382 1 349 1.918 0.354 0.419 1 .194 0.233 0.109 1 .736 0.492 1 .379 1 336 0.565 0.424 0.332 0.385 1.447 1,210 1.576 0.371 1.388 1.946 0,341 0.415 1.203 0.218 0.114 1.710 0.467 1.420 1.328 0.559 0.415 13.05 13,32 13.33 13.08 13.28 12.72 12.49 14,31 13.71 14.13 13,07 59.68 11.95 13.67 7.07 6.71 6.92 8.91 7.54 7.49 10.04 9.76 6.72 6.77 11.99 7.12 11.56 7.58 6.90 6.52 13.19 13.77 10.27 6.97 8.51 13.48 8.62 5.04 11.13 5.89 7.18 8.63 7.32 8.07 6.08 25,01 5.65 7.67 6.41 9.71 7.15-4 69) I 70)t 71)t 72)t 73)t 74)S 75)t 76)t 77)t 78)t 79)t 80) t 81)t 82)t 83)t I Phenanthrene-dlO---------------ISTD-- 4,6-Dinitro-2-met Atrazine n-Nitrosodiphenyl 1,2-Diphenylhydra 2,4,6-Tribromophe 4-Bromophenyl-phe Hexachlorobenzene Pentachlorophenol Phenanthrene Anthracene Carbazole Di-n-butylphthala Fluoranhhene Octadecane 0.192 0.614 0.966 0.147 0.220 0.264 0.153 1.099 1.148 1.035 1.579 1 .041 0.642 0.302 1.411 1.003 0.904 0.151 1,154 0.174 0.578 0.876 0.115 0.187 0.252 1.162 1.125 1 .000 1.571 1 .047 0.670 0,136 0.176 0.584 0.899 0.119 0.200 0.253-1.138 1.139 1. 064 1.581 1,081 0.608 0,200 0.212 0.704 1 .086 0.146 0.244 0.290 0,128 1.323 1 .368 1 .281 1.917 1 298 0.724 0.189 0.204 0.626 1.010 0.152 0.217 0.262 0.137 1.190 1.259 1.180 1.725 1.192 0.657 0.208 0.187 0.187 0.659 0.630 1.080 0.995 0.165 0.144 0.230 0.216 0.277 0.267 0.170 0.149 1.182 1.183 1.243 1.220 1.132 1.123 1.678 1.679 1.106 1.128 0.716 0,672 84) I Chrysene-d12 85)t Benzidine 86)t Pyrene 87)S Terphenyl-d14 88)t Butylbenzylphthal 89)t Butyl stearate 90)t Benzo[a]anthracen
ISTD--------------------- 0.378 0.364 0.369 0.285 0.248 0.172 0.302 1.423 1.411 1.609 1.472 1.480 1.594 1.486 0.956 0.918 1.127 1.056 1.057 1.122 1.034 0.859 0.859 1.028 0.923 0.928 0.959 0.923 0.127 0.120 0.145 0.127 0.139 0.156 0.138 1.313 1.214 1.444 1.259 1.243 1.275 1.272 92 of 122 33ACCUTEST N93379TS ...'. .. Initial Calibration Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 3 of 3 Sample: EH3145-1CC3145 Lab FilelD: H74024.D#49 91)t 92)t 93)t 3,3'-Dichlorobenz Chrysene bis(2-Ethylhexyl)
- 94) 1 Peryiene-d12 95)t Di-n-octylphthala 96)t Benzo[b]fluoranth97)t Benzo[kjfluoranth 98)t Benzo[alpyrene 99)t Indeno[1,2,3-cd]p 100)t Dibenz(a,h)acridi 101)t Dibenz[a,h)anthra 102)t 7,12-Dimethylbenz 103)t Benzo[g,h,ilperyl ( = Out of Range MH3145.M 0.440 1.043 1.237 1 .995 1 .295 1.228 1 .190 1 .437 1.127 1 259 0,573 1.080 0.464 1.091 1,211 1.804 1,347 1.126 1.107 1.277 0.980 1.127 0.486 1.186 0.450 1.077 1.166 1.917 1.338 1.118 1.152 1.293 1.004 1.131 0.483 1.118 0.528 1.263 1.379 0.495 1.216 1.251-ISTD--2.300 1 .539 1.396 1.388 1.616 1,217 1 396 0.542 1.343 2.107 1.490 1.280 1.287 1.452 1.132 1,297 0.634 1.179 0.494 1.165 1.306 2.146 1.519 1.243 1.262 1.479 1.172 1.298 0,617 1.156 0.483 1.140 1.321 2.068 1.653 1.103 1.283 1.609 1.292 1.419 0.603 1.192 0.479 1,142 1.267 2.048 1.454 1.214 1.238 1.452 1.132 1.275 0.562 1,179 6.28 6.90 5,71 7.88 8.98 8.77 7.67 9.25 9.80 9.02 10.88 7.04 Sat Apr 02 08:51:59 2005 MSH ACCUTEST.N93379 -:..I.
Initial Calibration Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 1 of 3 Sample: ER1468-ICC1468 Lab FileID: R43546.D"V0 Response Factor Report MSR Method Title Last Update Response via C:\HPCHEM\1\METHODS\MR1468.M (RTE Integrator) Semi Volatile Extractables by GC/MS Fri Mar 04 10:17:31 2005 Initial Calibration Calibration Files 2 =R43552.D 5 10 =R43550.D 80=R43551 .D=R43548.D 100 =R43547.D 25 =R43549.0 50 =R43546.D Compound 2 5 100 50 10 80 25 Avg %RSD 1) 1 1,4-Dichlorobenzene-d
-ISTD ---------------------
- 2) 1,4-Dioxane 1.190 0.795 0.622 0,651 0.734 0.623 0.662 0.754 26.85 Linear regression
Coefficient
= 0.9998 Response Ratio = 0.03050 + 0.61141 *A -3)4)5)6)7)8)9)10)11)12)13)14)15)16)17)18)19)20)21)22)23)24)25)26)27)28)29)30)31)32)33)34)35)36)37)38)39)Pyridine 1.832 1.789 1.604 1.593 1.699 1.511 1.627 N-Nitrosodim 0.983 0.952 0.778 0.867 0.875 0.798 0.846 2-Fluorophen 1.514 1.246 1,162 1.368 1,322 1,303 1,314 Indene 3.076 2.711 2.484 2.544 2.523:2.508 2.453 Cumene 3.954 3.395 2.855 2,978 3.114 2.827 2.871 Phenol-d5 2,205 2.142 1.723 1.976 2.047 1.944 1.850 Phenol 2.092 1.608 1.770 1.854 1,800 1.801 1.725 Aniline 2.245 2.264 1.788 2.079 2.018 1.714 1.644 ,bis(2-Chloro 1.518 1,369 1,393 1.4711.367 1.420 1.377 Benzaldehyde 0.630 0.839 0.190 0.587 0.482 2-Chlorophen 1.568 1.428 1.339 1.344 1.349 1.330 1.310 Decane 2.498 1.943 2.110 2.268 1.957 2.082 1,3-Dichloro 1.915 1.623 1.586 1.527 1..567 1.501 1.477 1,4-Dichloro 2.100 1.761 1.598 1.580 1.603 1.563 1.536 Benzyl alcoh 0.559 0.520 0.834 0.894 0.615 0.837 0.749----- Linear regression Coefficient = 0.9978 Response Ratio = -0.03389 + 0.85709 *A 1,2-Dichloro Acetophenone 2-Methylphen 2,2'-oxybis(3&4-Methylph n-Nitroso-di Hexachloroet 1.866 2.433 1.604 0.554 1.294 1.280 0.597 1.592 2.110 1.344 0.463 1.200 1.169 0.533 1.517 1 .744 1.165 0.419 1.234 0.992 0.521 1.501 1.937 1.258 0.447 1 .299 1.087 0.513 1.500 1.921 1.209 0.441 1,208 1.068 0.511 1.484 1.831 1.201 0.421 1,.267 1.015 0.507 1.431 1.867 1.223 0.419 i .221 1.060 0.493 1.665 0.871 1.318 2.614 3.142 1.984 1,807 1:965 1.416 0.546'1.381 2.143 1.600 1.677 0.715 1.556 1.978 1.286 0.452 1.246 1.096 0.525 0.480 0,182 0,632 0.774 0.177 0.355 0.212 0,435 0.254 0.332 0.319 0.314 0.386 1.137 6.87 8.61 8,24 8.41 13.03 8.37 8.18 12.82 4.09 43.51 6.54 9.81 9.25 11.92 20.94 9.30 11.65 11.76 10.60 3.26 9.02 6.50 5.59 4.31 4.77 9.29 7.83 6.05 12.73 6 .78 7.13 8.42 7,31 7.25 9.44 8.00 1 Naphthalene-d8 Nitrobenzene 0.534 Nitrobenzene 0.195 Quinoline 0.696 Isophorone 0.928 2-Nitropheno 0.158 2,4-Dimethyl 0.390 Benzoic acid bis(2-Chloro 0.493 2,4-Dichloro 1,3,5-Trichl 0,364 1,2,4-Trichl 0.356 1,2,3-Trichl 0.344'alpha-Terpin 0.457 Naphthalene 1.316.... -I -ISTD---0.497 0.176 0.635 0.800 0.168 0.349 0.446 0.229 0.312 0.303 0.302 0.411 1.148 0.473 0.190 0.627 0.735 0.199 0.372 0.230.0.440 0.279 0.367 0.339 0.330 0.356 1.164 0.466 0.177 0.623 0.754 0.184 0.355 0.225 0.423 0.259 0,330 0.313 0.308 0.374 1.087 0.473 0.177 0.606 0.734 0.171 0.332 0.168 0.410 0.242 0.303 0.295 0.286 0.376 1.069 0.465 0.183 0.631 0.737 0.188 0.357 0.232 0.427 0.267 0.347 0.330 0.336 0.365 1.132 0.455 0.175 0.607 0.733 0.172 0.329 0.202 0.405 0.247 0.. 301 0.295 0.291 0.361 1.040 94 of 122 N N93379 Initial Calibration Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 2 of 3 Sample: ER1468-1CC1468 Lab FileID: R43546.D 40)41)42)43)44)45)46)4-Chloroanil 0.443 0.384 0.432 0.407 0.359 0.406 0.359 2,3-Dichloro 0.347 0.319 0,329 0.322 0.292 0.332 0.296 Caprolactam 0.159 0.156 0.163 0.170 0.151 0,166 0.165 Hexachlorobu 0.220 0.189 0.211 0.193 0.178 0,201 0.179 4-Chloro-3-m 0.250 0.282 0.262 0.239 0.267 0.226 2-Methylnaph 0.775 0.685 0.764 0.727 0.648 0,736 0.657 1-Methyinaph 1,018 0.783 0.719 0.705 0.682 0.725 0.670----- Linear regression
Coefficient
= .0;9994 Response Ratio = -0.00412 + 0.71988 *A 0.399 0.320 0.161 0.196 0.254 0.713 0.757 8.32 6.10 4.00 7.99 7.87 7.07 15.93 47) Dimethylnaph 0,608 0,562 0.622 0.597 0.509 0.619 0.544 0.580 7.37 48) I Acenaphthene-dlO
ISTD ----------------------
- 49) Hexachlorocy 0,204 0.392 0.350 0.232 0.366 0.284 0.305 SLinear regression
Coefficient
= 0.9966 Response Ratio = -0.09778 + 0.40056 *A 50)51)52)53)54)55)56)57)58)59)60)61)2,4,6-Trichl 2,4,5-Trichl 2-Fluorobiph 2-Chloronaph Biphenyl 2-Nitroani i Dimethylphth Acenaphthyle 2,6-Dinitrot 3-Nitroanili Acenaphthene 2,4-Dinitrop 0.314 0.347 1.645 1 263 1 .706 0.354 1.308 2 .015 0.187 0.299 1 .452 0.299 0.340 1.437 1. 130 1,549 0.388 1.214 1.860 0.229 0.253 1.276 0,393 0.404 1.644 ,1 260 1.708 0.444 1 .366 2,101 0.298 0,318 1.377 0.181 0.333 0.301 0.365 0.295 1.556 1.390 1.129 1.0911.575 1.476 0.415 0.409 1.228.1.152 1.955 1.816 0.269 0.239 0.297 0.279 1.302 1.209 0.149 0.060 0.357 0,386 1.573 1.197 1,648 0.425 1,291 1.987 0.286 0,306 1.314 0.168 0.303 0.320 1.380 1,066 1.467 0.400 1.162 1.791 0.250 0.284 1.205 0,118 0.329 0.351 1.518 1.162 1.590 0,405 1.246 1.932.0.251 0.291 1.305 0.135 25 .14 10.71 10.73 7 .52 6.79 6.33 7.15 6.34 5.89 14.99 7.26 6.77 35.72-4-4 SLinear regression
Coefficient
= 0.9965 Response Ratio = -0.08867 + 0.19387 *A 62) 4-Nitropheno 0.169 0.147 0.103 0.154 0.134------Linear regression
Coefficient
= 0.9948 Response Ratio = -0.02484 + 0.17328 *A 0.141 17.51 63)64)65)66)67)68) 69)Dibenzofuran 2,4-Dinitrot 2,3,4,6-Tetr Diethylphtha Fluorene 4-Chlorophen 4-Nitroanili 1.890 0.299 0.218 1.454 1.414 0,626 0.245 1.640 0.331 0.235 1.300 1.298 0.572 0.260 ,1.820 0.388 0.322 1.379 1 .442 0.676 0.307 1,699 0.354 0.272 1.351 1.349 0.594 0.288 1,570 0.334 0.235 1.217 1,224 0.539 0.286 1.741 0.364 0.293 1.308 1.389 0.623 0.300 1.596 0.330 0.245 1.222 1 .247 0.548 0.290 1.708 0.343 0.260 1.319 1.337 0.597 0.282 70) I Phenanthrene-dlO
ISTD ---------------------
- 71) 4,6-Dinitro-0.153 0.130 0.086 0.140 0.103 0.122------ Linear regression
Coefficient
= 0.9949 Response Ratio = -0.02971 + 0.15979 #A 6.89 8.36 14 .25 6.44 6.26 8.13 7.76 22.25 7.26 8.00 7.52 11.89 10.81 10.63 27,40 72)73)74)75)76)77)78)Atrazine 0.093 0.087 0.104 0,101 0.088 0.102 0.091 n-Nitrosodip 0.607 0.541 0.666 0.627 0.543 0.620 0.562 1,2-Diphenyl 1.260 1.122 1,054 1.046 1.087 1.029 1.031 2,4,6-Tribro 0.118 0.150 0.142 0,117 0.153 0,127 4-Bromopheny 0.230 0.198 0.258 0.225 0.194 0.240 0.202 Hexachlorobe 0.259 0.226 0.281 0.255 0.211 0.271 0.225 Pentachlorop 0.091 0.179 0.151 0.098 0.169 0.125.....-Linear regression
Coefficient
= 0.9950 Response Ratio = -0.05203 + 0.18458 *A 0.095 0.595 1. 090 0.135 0.221 0.247 0.135'U, 79) Phenanthrene 1.303 1.122 1.289 1.207 1.077 1.217 1.092 1.187 7.73 95 of 122~ACCU IES I Initial Calibration Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ*Page 3 of 3 Sample; .ER1468-1CC1468 Lab FileID: R43546.D 80)81)82)83)84)Anthracene Carbazole Di-n-butylph Fluoranthene Octadecane 1.331 1.1761.105 0.976 1.319 1.216 1T,192 1.0560.783 0.696 85)86)87)88)89)90)91)92)93)94)95)96)97)98)99)100)101)102)103)P B'T, B 3 Cl b Chrysene-d12 enzidline yrene utyl steara erphenyl-dl utylbenzylp enzo[a]anth ,3'-Dichlor hrysene is(2-Ethylh 0.274 1.533 0.'531 1.041 0.581 1.368 0.359 1,459 0.822 0.303 1.341 0.495 0.924 0.567 1.212 0.349 1.219 0.781 1,341 1.291 1.390 1.151 1.183 0.872 1.013 0.598 1.332 1.053 1.413 1.277 0.632 0.233 1.614 0,523 1.147 0.700 1.393 0,379 1,389 0.985 1.287 0,979 1.370 1,221 0.668 0.289 1.494 0,483 1.062 0.628 1.309 0,363 1.313 0.902 1.132.0.961 1.161 1.015 0.658 1.299 1.013 1,357 1.225 0.644 1,155 0,944 1.222 1.053 0.641 0.242 1.332 0.483 0.914.0.558 1.205 0.343 1,177 0.761 1,245 1.004 1.294 1.148 0.675 6.98 5.68 7,29 9.06 7.75 ISTD ------------------- 0,220 1,487 0.476 1.061 0.638 1,326 0.357 1.289 0,915 0.236 1.298 0.478 0.935 0.580 1.168 0.353 1.168 0.832 0.257 1.443 0.496 1.012 0.607 1.283 0,357 1.288 0.857 12.34 8.28 4.54 8,75-8.40 6.84 3.25 8.47 9.34 14.11 13.93 12.62 14.55 7.71 7.67 7.04 18.90 I Perylene-d12 Di-n-octylph 1.3w Benzo[b]fluo 1,3(Benzo[kjfluo 1.6: Benzo[a]pyre 1.2(Indeno[1,2,3 Dibenz(a,h)a 0,9{Dibenz[a,h]a 1.O0 7,12-Dimethy 0.6---------------- ISTD ---------60 03 31 09 75 01 92 18 1.925 1,626 1.282 0,945 1.097 0.927 1.603 1.580 1.667 1.419 1.490 1,076 1.237 0.808 1.339 1.273 1.380 1.172 1.249 0.893 1.031 0.607 1,861 1.759 1.714 1.538 1,388 1.015 1.175 0.861 1.407 1,348 1.439 1.209 1.353 0,954 1.123 0.657 1,485 1.426 1,592 1.332 1.317 0,951 1.110 0.725-Linear regression
oetficient
= 0.9944 Response Ratio = -0.08178
- 0.92515 *A 104) Benzo[g,hj]
1.114 0.981 0.910 1.143 0.964 1.000.1.058 1.024 8.21 (#) = Out of Range ### Number of calibration levels exceeded format ###MR1468.M Mon Mar 07 09:22:48 2005 RPT1 9610f122 UACCLJTEST. N93379 Continuing Calibration Summary Job Number; N93379Account; AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Sample; ER1479-CC1468 Page I of 3 Lab FileID: R43741..D Evaluate Continuing Cal ibration Report Data File C:\HPCHEM\1\DATA\ER1479\R43741.D Acq On : 18 Mar 2005 10:45 am Sample : CC1468-25 Misc : OP19709,ER1479 MS Integration Params: LSCINT.P Vial: 2 Operator: WENDYS Inst : MSR Multiplr: 1.00 Method Title Last Update Response via Min. RRF Max. RRF Dev C:\HPCHEM\1\METHODS\MR1468,M (RTE Integrator) Semi Volatile Extractables by GC/MS Fri Mar 18 11:31:36 2005 Multiple Level Calibration 0.050 Min. Rel. Area : 50% Max. R.T. Dev 0.50min 20% Max. 'Rel. Area : 200%-4 Compound AvgRF CCRF%Dev Area% Dev(min)R,T, 1 1 1,4-Dichlorobenzene-d4 1.000------------------------ True 2 t 1,4-Dioxane 25.000 3 4 5 6 7 8.9 10 11 12 13 14 15 16 t t S t t S t t t t t t t t Pyridine N-Nitrosodimethylamine 2-Fluorophenol Indene Cumene Phenol-d5 Phenol Aniline bis(2-Chloroethyl)ether Benzaldehyde 2-Chlorophenol Decane 1,3-Dichlorobenzene 1,4-Dichlorobenzene AvgRF 1.665 0.871 1,318 2.614 3.142 1.984 1.807 1.965 1.416 0.546 1.381 2.143 1.600 1t677--------------- True 17 t Benzyl alcohol 25.000 1.000 Calc, 24.449 CCRF 1.466 0.639 1.333 2. 547 3.059 1.877 1.534 1.882 1.259 0.303 1.322 1.668 1.600 1.597 Calc, 26.311 CCRF 1.524 1.815 1.211 0.449 1.223 0.900 0,537 1.000 0.429 0.182 0.636 0.695 0.189 0.342 0.177 0.395 0.263 0.0% Drift 2.2% Dev 12.0 26.6#-1.1 2.6 2.6 5.4 15.1 4.2 11.1 44.5#4.3 22.2#0.0 4.8 134 -0,07 108 0.00 91 -0.07 122 -0.07 125 -0.16 128 -0.15 122 -0.09 107 -0.09 138 -0.14 110 -0.16 76 -0.12 121 -0.13 96 -0.16 130 -0.16 125 -0.16 120 -0.17 7.80 2,13 2.66 2.68 4.96 8.64 5,81 7.36 7.39 7.12 7.32 6.75 7.41 7.58 7.69 7.85% Drift ------------ -5.2 136 -0,12 8.56 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 t t t t t t t S t t t t t t t t 1,2-Dichlorobenzene Acetophenone 2-Methylphenol 2,2'-oxybis(1-Chloropropa 3&4-Methylphenol n-Nitroso-di-n-propylamin Hexachloroethane Naphthalene-d8 Nitrobenzene-d5 Nitrobenzene Quinoline Isophorone 2-Nitrophenol 2,4-Dimethylphenol Benzoic acid bis(2-Chloroethoxy)methan 2,4-Dichlorophenol AvgRF 1.556 1.978 1.286 0.452 1.246 1.096 0.525 1.000 0.480 0.182 0.632 0.774 0.177 0.355 0.212 0,435 0.254% Dev 2.1 8.2 5.8 0.7 1.8 17.9-2.3 0.0 10.6 0.0-0.6 10.2-6.8 3.7 16.5 9.2-3.5 117 110 121 122 111 129 121 102 114 125 128 -0.16 117 -0,15 119 -0.12 129 -0.16 120 -0.07 102 -0.17 131 -0.17-0.18-0.16-0.16-0,14-0,16-0.15-0.13-0,06-0.17-0.07 1 t: 1 1: 1 1 8.39 9.26 9.13 8.95 9.69 9.42 9.30 1.96 9.68 9.74 3.40 0.57 0.85 1.37 2.37 1.54 1 .88~Ij97 of122 12 ACCUTrCST. N9?339 Continuing Calibration Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Sample: ER1479-CC1468 Page 2 of 3 Lab FileID: R43741.D 35 36 37 38 39 40 41 42 43 44 45 t t t t t t t t t t t 1,3,5-Trichlorobenzene 1,2,4-Trichlorobenzene 1,2,3-Trichlorobenzene alpha-Terpineol Naphthalene 4-Chloroaniline 2,3-Dichloroaniline Caprolactam Hexachlorobutadiene 4-Chloro-3-methylphenol 2-Methylnaphthalene 0.332 0.319 0.314 0.386 1,137 0,399 0.320 0.161 0.196 0,254 0.713 0.341 0.327 0.323 0.317 1.102 0.409 0.328 0.129 0.209 0.277 0.698 Calc.25.858-2.7-2.5-2.9 17.9 3.1-2.5-2.5 19.9-6.6-9.1 2.1 132 130 130 103 124 133 130 91 136 143 124-0.17-0.17-0.17-0.18-0.18-0.12-0.17-0.20-0.18-0.08-0.18 10.78 11.88 12.71 12.26 12.02 12.61 15.91 13.93 12.80 14.83 14.59-J-------------- True 46 t 1-Methylnaphthalene 25.000---------------- AvgRF 47 t Dimethylnaphthalene 0.580% Drift ------------ -3.4 129 -0.18 14.96 CCRF 0.584% Dev-0.7 125 -0.17 16.93 48 I Acenaphthene-dlO1.000 1.000 0.0 116 -0.16 18.24% Drift 17.1 104 -0.18 15.49-------------- True 49 t Hexachlorocyclopentadiene 50.000#V 50 51 52 53 54 55 56 57 58 59 60 t t S t t t t t t t t 2,4,6-Trichlorophenot 2,4,5-Trichlorophenol 2-Fluorobiphenyl 2-Chloronaphthalene Biphenyl 2-Nitroaniline Dimethylphthalate Acenaphthylene 2,6-Dinitrotoluene
3-Nitroaniline Acenaphthene AvgRF 0.329 0.351 1.518 1 .162 1.590 0 ,405 1.246 1 .932 0.251 0,291 1 .305 Calc.41.427 CCRF 0.360 0.363 1.536 1.226 1.599 0.369 1.265 1.926 0:274 0.292 1.244 Calc.43.458 20.906 CCRF 1,738 0.377 0.289 1 .250 1 325 0.640 0.305% Dev-9.4-3.4-1.2-5.5-0.6 8.9-1.5 0.3-9.2-0.3 4.7% Drift 13.1 16.4 138 -0.14 16.02 131 -0.05 16.31 129 -0.18 16.19 133 -0.18 16.36 126 -0.18 16.45 107 -0.10 17.16 126 -0.15 17.91 125 -0.16 17.74 127 -0.14 18.07 119 -0.07 18.55 120 -0.16 18.33 96 -0.01 18.90 91 0.27 19.80 126 -0.15 18.85 132 -0.11 19.24 137 -0.11 19.50 119 -0.15 19.99 123 -0.15 19.81 135 -0.14 19.95 122 -0.04 20.35--------------- True 61 t 2,4-Dinitrophenol 50.000 62 t 4-Nitrophenol 25.000 63 t 64 t 65 66 t 67 t 68 t 69 t..................
AvgRF Dibenzofuran 1.708 2,4-Dinitrotoluene 0.343 2,3,4,6-Tetrachlorophenol 0.260 Diethylphthalate 1.319 Fluorene 1.337 4-Chlorophenyl-phenylethe 0,597 4-Nitroaniline 0,282% Dev-1.8-9.9-11.2 5.2 0.9-7.2-8.2 70 I Phenanthrene-dlO 1.000 1.000-------------
True 71 t 4,6-Dinitro-2-methylpheno 25.000 72 73 74 75 76 t t t S t--AvgRF Atrazine 0.095 n-Nitrosodiphenylamine 0.595 1,2-Diphenylhydrazine 1.090 2,4,6-Tribromophenol 0.135 4-Bromophenyl-phenylether 0.221 Ca Ic.24.043 CCRF 0.103 0.562 0.884 0.157 0,240% Dev-8.4 5.5 18.9-16.3-8.6 0.0 115 -0.14 22.23% Drift ------------ 3.8 119 -0.08 20.37 130 -0,14 21.98 115 -0.14 20.36 99 -0.15 20.36 143 -0.11 20.59 137 -0.14 21.21 vn 98 of122 U ACCUT-EST. N9337S 1-' 1' Continuing Calibration Summary Job Number: N93379 Account: AGMPAL Arcadis Geraghty & Miller Project: PSEG, Hancock's Bridge, NJ Page 3 of 3 Sample: ER1479-CC1468 Lab FilelD: R43741 .D 77 t Hexachlorobenzene 0.247 0.276 -11.7 142 -0.14 21.49--------------- True 78 t Pentachlorophenol 50.000 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 Phenanthrene Anthracene Carbazole Di-n-butylphthalate Fluoranthene Octadecane Chrysene-d12 Benzidine Pyrene Butyl stearate Terphenyl -d14 Butylbenzylphthalate Benzo[a)anthracene 3,3'-Dichlorobenzidine Chrysene bis(2-Ethylhexyl)phthalat Perylene-d12 Di-n-octylphthalate Benzo[b]fluoranthene Benzo[k]fluoranthene Benzo[a]pyrene Indeno[1,2,3-cdlpyrene Dibenz(ah)acridine Dibenz[a,h)anthracene AvgRF 1,187 1.245 1.004 1.294 1.148 0.675 1.000 0.257 1 .443 0.496 1.012 0.607 1 .283 0.357 1.288 0 857 1.000 1.485 1 .426 1 .592 1 .332 1.317 0,951 1.110 CaIc: 47.075 CCRF 1.151 1.245 1.010 1.224 1.127 0.536 1 .000 0.216 1 479 0.405 1.107 0. 591 1 .228 0.394 1.322 0.850 1.000 1.413 1.322 1.611 1.324 1 .276 0.965 1.071 Ca I c.22.037 CCRF 0.983% Drift.5.8% Dev 3.0 0.0-0,6 5.4 1.8 20.6#t 0.0 16.0-2.5 18.3-9.4 2,6 4.3-10.4-2.6 0.8 0.0 4.8 7.3-1.2 0.6 3.1-1.5 3.5 122 -0.09 22.10 122 -0.14 22.29 124 -0.14 22.41 123 -0.09 23.00 116 -0.14 24.14 124 -0.13 25.23 96 -0.14 22.38 106 97 121 90 126 108 112 119 120 109 104 104 102 116 113 98 105 99-0.14-0.02-0.12-0.14-0.13-0.14-0.13-0.08-0.13-0.14-0.13-0.14-0.13-0.14-0.13-0.10-0.11-0.11.28.67 25.84 25.74 27 88 26.30 27.67 28.64 28.79 28.73 29.19 31.83 30.57 31.07 31.12 31.72 33,85 33.47 33.88 U------------------ True 103 t 7,12-Dimethylbenz(a)anthr 25.000----------------------- AvgRF 104 t Benzo[g,h,ilperylene 1.024% Drift 11.9 108 -0.16 31.08% Dev 4.0 96 -0.09 34.30 (#) = Out of Range R43741.D MR1468.M SPCC's out = 0 CCC's out = 0 Fri Mar 18 12:38:53 2005 RPT1 En 99 of 122 12ACCUrETE. N93379 %ý,ý- Accutest Laboratories b GC/MS Semi-volatiles Raw Data 4W On~ 1000f122 QACCU IEn I N93379 Quantitation Report (QT Reviewed)Data File C:\HPCHEM\I\DATA\EH3145\H74037,D Acq On 2 Apr 2005 3:12 am Sample N93379-1 Misc OP19692,EH3145,1000 MS Integration Params: RTEINT.P Quant Time: Apr 2 11:14 2005 Vial: 26 Operator: SEANWE Inst : MSH Multiplr: 1,00 Quant Results File: MH3145.RES Quant Method Title Last Update Response via DataAcq Meth C:\HPCHEM\i\METHODS\MH3145.M (RTE Integrator) Semi Volatile Extractables by GC/MS Sat Apr 02 08:32:42 2005 Initial Calibration MH3145 Internal Standards R.T. QIon Response Conc Units Dev(Min).........................................................................
- 1) 1,4-Dichlorobenzene-d4 8.64 152 162438 40.00 ppb 0.01 25) Naphthalene-d8 10.67 136 631491 40.00 ppb 0.01 48) Acenaphthene-dlO 14.12 264 301014 40.00 ppb 0.02 69) Phenanthrene-dl0 17.49 188 424267 40.00 ppb 0.01 84) Chrysene-d12 22.52 240 323807 40,00 ppb 0.01 94) Perylene-d12 24.92 264 303459 40.00 ppb 0.02 System Monitoring Compounds 5) 2-Fluorophenol Spiked Amount 50.000 8) Phenol-d5 Spiked Amount 50.000 26) Nitrobenzene-d5 Spiked Amount 50.000 52) 2-Fluorobiphenyl Spiked Amount 50.000 74) 2,4,6-Tribromophenol Spiked Amount 50.000 87) Terphenyl-dI4 Spiked Amount 50.000 6.76 112 142027 22.26 Recovery =8.24 99 117204 13.59 Recovery 9.51 82 246932 44.77 Recovery =12.67 172 443934 40.77 Recovery =15.89 330 61347 40.24 Recovery 20.81 244 373881 44.66 Recovery =ppb 0.01 44.52%ppb 0.03 27.18%ppb 0.02 89.54%ppb 0.01 81.54% 'ppb 0.01 80.48%ppb 0.01 89.32%Target Compounds Qvalue (W) -qualifier out of range (n = manual integration H74037.D MH3245.M Mon Apr 04 09:04:47 2005 MSH Page 1 W 101of122 2 .ACCU I "ES I N93379 s: ,T -,- '
0-J111PW MUNU!Lý;: Quantitation Report Data File C:\HPCHEM\I\DATA\EH3145\H74037.D Vial: 26 Acq On 2 Apr 2005 3:12 am Operator: SEANWE Sample : N93379-1 Inst : MSH Misc OP19692,EH3145,1000 Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Apr 2 11:14 2005 Quant Results File: MH3145.RES Method : C:\HPCHEM\2\METHODS\M}3I45.M (RTE Integrator) Title : Semi Volatile Extractables by GC/MS Last Update Sat Apr 02 08:32:42 2005 Response via : Initial Calibration ...C:A bun.D 650000 600000 1 550000 .500000 450000 A 400000 Ix j 350000 IP 300000 250000 f,'13 7 200000 150000 D L 1 ...0000..... '" 2 I '2O 0 60 .0 1.0 1. 40 68.00 .00 20.00 22.00 240O0 260O0 2800 H7M037.D MH3145.M Mon Apr 04 09:04:48 2005 MSH Page 2 S 102 of 122 I ACCU'TESTM 7 , r. N 9,3.. ., .3 .....7; ..9. inple HesuIIs: E X: Quantitation Report Data File C:\HPCHEM\1\DATA\EH3145\H74038.D Acq On : 2 Apr 2005 3:46 am Sample N93379-2 Misc OP19692,EH3145,980 MS Integration Params: RTEINT.P Quant Time: Apr 4 10:11 2005 Quan (QT Reviewed)Vial: 27 Operator: SEANWE Inst : MSH Multiplr: 1.00 t Results File: MH3145.RES Quant Method Title Last Update Response via DataAcq Meth C:\HPCHEM\k\METHODS\MH3145.M (RTE Integrator) Semi Volatile Extractables by GC/MS Sat Apr 02 08:32:42 2005 Initial Calibration MH3145 Internal Standards R.T. QIon Response Conc Units Dev(Min)1) 1,4-Dichlorobenzene-d4 8.64 152 151724 40.00 ppb 0.02 25) Naphthalene-d8 30.68 136 578453 40.00 ppb 0.02 48) Acenaphthene-d20 14.13 164 272059 40.00 ppb 0.03 69) Phenanthrene-dl0 17.49 188 384031 40.00 ppb 0.02 84) Chrysene-d12 22.52 240 304464 40.00 ppb 0.02 94) Perylene-d12 24.93 264 305873 40.00 ppb 0.03 System Monitoring Compounds 5) 2-Fluorophenol Spiked Amount 50.000 8) Phenoa-d5 Spiked Amount 50,000 26) Nitrobenzene-d5 Spiked Amount 50.000 52) 2-Fluorobiphenyl Spiked Amount 50.000 74) 2,4,6-Tribromophenol Spiked Amount 50.000 S 87) Terphenyl-d14 Spiked Amount 50.000 Target Compounds 6.76 112 206710 17.91 Recovery =8.25 99 91451 11.36 Recovery =9.50 82 179592 35.54 Recovery 12.67 172 328120 33.47 Recovery =15.90 330 53579 38.83 Recovery =20.82 244 328062 41.67 Recovery =ppb 35.82%ppb 22.72%ppb 71.08%ppb 66.94%ppb 77.66%ppb 83.34%0.02 0.04 0.02 0.02 0.02 0.02 Qvalue (4) = qualifier out of range (m) = manual integration H74038.D MH3145.M Mon Apr 04 20:11:24 2005 MSH Page I E 103 of 122 U ACC-'TEST Quantitation Report#%V Data File : C:\HPCHEM\I\DATA\EH3145\H74038.D Acq On : 2 Apr 2005 3:46 am Sample :N93379-2 Misc : OP19692,EH3145,980 MS Integration Params: RTEINT.P Quant Time: Apr 4 20:11 2005 Qu Vial: Operator: Inst Multiplr: 27 SEANWE MSH 1.00 uant Results File: MH3145.RES Method Title Last Update Response via C:\HPCHEM\I\METHODS\MH3145.M (RTE Integrator) Semi Volatile Extractables by GC/MS Mon Apr 04 10:09:32 2005 rnitial Calibration initial Calibration 2_6 0 .0 U 0o I" 0-250000 200000 150000 100000 50000 Tfrme-- 2.00 4.00.... .... ........ .... ....... ....H74038.D MH3245.M£&%0.... .0.o0_Mon Apr 04 10:11:25 2005 *MSH Page 2 OR 10.4of 122 QACC TEST.N93379 Quantitation Report (QT Reviewed)Data File C:\HPCHEM\I\DATA\EH3145\H74039.D Acq On 2 Apr 2005 4:31 am SSample : N93379-3 Misc : OP19692,EH3145,]000 MS Integration Params: RTEINT.P Quant Time: Apr 2 11:25 2005 Vial: 28 Operator: SEANWE Inst : MSH Multiplr: 1.00)uant Results File: MH3145.RES Quant Method C;\HPCHEM\I\METHODS\MH3145,M (RTE Integrator) Title Semi Volatile Extractables by GC/MS Last Update Sat Apr 02 08:32:42 2005 Response via Initial Calibration DataAcq Meth MH3145 Internal Standards R.T. QIon Response Conc Units Dev(Min)......................................................................... 1)25)48)69)84)94)1,4-Dichlorobenzene-d4 Naphthalene-d8 Acenaphthene-dlO Phenanthrene-dl0 Chrysene-d12 Perylene-d22 8.65 10.68 24.23 17.50 22.52 24 .93 152 136 164 188 240 264 166034 627729 295527 420401 312340 306595 40 .00 40.00 40.00 40.00 40.00 40.00 ppb ppb ppb ppb ppb ppb 0.02 0.02 0.03 0.03 0.02 0.03 w I System Monitoring Compounds 5) 2-Fluorophenol Spiked Amount 50.000 8) Phenol-d5 Spiked Amount 50.000 26) Nitrobenzene-d5 Spiked Amount 50.000 52) 2-Fluorobiphenyl Spiked Amount 50.000 74) 2,4,6-Tribromophenol Spiked Amount 50.000 87) Terphenyl-dI4 Spiked Amount 50.000 Target Compounds 39) Naphthalene
- 45) 2-Methylnaphthalene
- 60) Acenaphthene
- 63) Dibenzofuran
- 66) Fluorene 78) Phenanthrene
- 79) Anthracene
- 80) Carbazole 82) Fluoranthene
- 86) Pyrene 6.76 112 145444 22.31 Recovery 8.25 99 122114 13.86 Recovery 9.51 82 255163 46.53 Recovery =12.67 172 438377 41.01 Recovery =15.91 330 70262 47.65 Recovery 20.83 244 362898 44.94 Recovery =ppb 0.02 44.62%ppb 0.04 27.72%ppb 0.03 93.06%ppb 0.02 82.02%ppb 0.03 95.30%ppb 0.03 89.88%20.71 11 .97 2 4.20 14.57 25.34 27.55 17. 67 18.09 20.14 20.57 128 142 153 168 266 178 178 167 202 202 63953 19579 44489 33920 43632 64336 11877 2 4412 15769 10864 4 .30 2 .00 5.01 2 .69 4.45 5.30 0.95 9.93 1.36 0. 94 ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb Qvalue 84 91 98 98 95 99 98 99 96 93 (t) = qualifier out of range (m) ý manual integration H74039.D MH3145.M Mon Apr 04 09:05:03 2005 MSH Page I G 105of122 Q ACCUTEýST.
N9~3a7g 1`%1UT4=b---W91zýWELLW*6e1 W Quantitation Report Data File : C:\HPCHEM\I\DATA\EH3145\H74039.D Acq On 2 Apr 2005 4:31 am S Sample : N93379-3 Misc OP19692,EH3145,1000 MS Integration Params: RTEINT.P Quant Time: Apr 2 11:15 2005 Q Vial: Operator: Inst Multiplr: 28 SEANWE MSH 1.00 uant Results File: MH3145.RES Method : C:\HPCHEM\I\METHODS\MH3145.M (RTE Integrator) Title : Semi Volatiie Extractables by GC/MS Last Update : Sat Apr 02 08:32:42 2005 Response via: Initial Calibration IMC: H74039.D-2 w 0, f..f, 4-V a C-4,)2 C).Tirne Hý4039.D MH3345.M Mon Apr 04 09:05:03 2005 MSH Page 2 Mrj 106of122 Q ACCUTE"ST. N9337S 11W -Q"t: WIST1751,111wo h 2 Abundance Scan 868 (10.829 min): H73733.D (-)18 kv Re f80 I V39 Naphthalene Concen: 4.30 ppb RT: 20.71 min Scanr 831 Delta R.T. 0.02 min Lab File: H74039.D Acq: 2 Apr 2005 4:31 am 39 1 64 77 89 10211_J39 182 207.3' .-..- ., A; -,, -; 4'L , ; = 7 -, -, ,$ ....-, tvz--> 40 60 BO 160 120 140 160 10 260 1 ndbhiance -Scan 831 (10.710 mi) L703.1 6 Raw 50 64 91 115 39 51 64 77 102 , 7160.z -.> 4 0 60 80 10'0 120 140 160 .1 ' ., .8 _ ....2 Abundance Scan j (10.7 ; i3r;,: H743 J.L) ,-1 )136 Sub 50 4354 81 94 121J 7 160 Abn 0c Sn98(12.02,m);773. -mz> 40 60 80 10[0 120 140 160 18'0 200 Tgt Ion 128 129 127 Ion:128 Resp: Ratio Lower 100 22.0 0,0 13.2 0.0 63953 Upper 4 09 40.9 Abundance Ion 128.00 (127.70 to 128.70): I, ton 129.00 (128.70 to 129.70): H3 30000 lon 127.00 (126.70 to 127.70): Hi 25000 10.71 20000 15000 10000 5000 0 "1 e--> 10,60 10.70 10.80 Tine%W ,Abundance Scan 980 (12,092 min): i-73733.D(- 112 RefSO 11 115 19 57 71 8901 27J~ .....27-nz--> 40 60 80 100 120 140 160 180 2 0 1 2 415 w069 95 115 Rw 55 Ii IJ, 11.. 170 187 r t145 2-Methylnaphthalene Concen: 2.00 ppb RT: 21.97 min ScanA 943 Delta R.T. 0.03 min Lab File: B74039.D Acq: 2 Apr 2005 4:31 am Tgt lon:142 Resp: 19579 Ion Ratio Lower Upper 242 100 242 80.6 54.4 114.4 115 16.6 0.0 58,7 TIIz-->40 60 80 100 120 140 160 180 200'Abundance SA ?'-i.! 7 nir : '03J -)I
- 142 1 Sub 50 69 ý5 ,1 i 159 50 80 i.' 126 '! 170 187 I nyz--> 4. 60 80. 100 120 140 160 1 80 200 f..m.-tF H74039.D MH3145.M Mon Apr 04 09:05:04 2005 MSH Page 3 j1n 107 of'122 3 .ACCUTEST.
N93379 441tflC * ~.tat ,bunoance II Scan 1178 (14.326 rmin): H73733.D (-)1~3 Re fSC 4160 Acenaphthene Concen: 5.01 ppb RT: 14.20 min Scan# 1140 Delta R.T. 0.03 min Lab File: H74039.D 2Acq: 2 Apr 2005 4::31 am 207 76 39 5.1 6 87 98 113 126 139 S11" I ...n II I I ...I ....I ' -...I I. ..I ....I ' Tgt nanScan 1140 14197 min): H74039.D Ion 1 3 153 152 I i 154 Raw50 ouna i T~76 168 4 55 91 105117 135 169.20 09329.. ...................... Fdj--> 40 60 80 100 120 140 160 180 200 6ome-->Ion:153 Resp: Ratio Lower 100 44489 Upper 48.2 15.6 75.6 89.4 59.1 119.1 Ion 153.00 (152.70 to 153.70): E Ion 152.00 (151.70 to 152.70): ]Ion 154.00 (153.70 to 154.70): 00 00)OOji 14.20 14.10 14.20 H 00 0 Abundance Scan 1211 (14.699 rmin): H73733. (-)139 39 51 6 3 84 98 ..11.126. 11 150 , I 1'in/z-> 40 60 80 100 120 140 160 180 200 Abundance Scan (14.569 man): H74039.D Ri, 1916 0 139 41 55 69 81 95109123 5I5 C ,11 I ,, ,I,.4., , , r (, 192204 vn'z-> 40 60 80 100 120 140 160 180 200'Abundance Scan ' 7I4.5 i1, mrli': '7e0319., (-.1 168 Su 139 ( I 155 4163 4 Dibenzofuran Concert: 2.69 ppb RT: 14.57 min Scan# 1173 Delta R.T. 0.02 min Lab File: H74039.D Acq: 2 Apr 2005 4:31 am Tgt Ion:268 Resp: Ion Ratio Lower 168 100 139 32 .7 2.2 169 26.4 0.0 33920 Upper 62".2 44.0 Abundance Ion 168.00 (167.70 to 161.70): 4j Ion 139.00 (138.70 to 139.70): F.Ion 169 00 (16,70 t,. 160.70)y 15000 14.57 10000!0.ITjm-.- 14.501 .6 4.70 1484 41 57 69 84 98 113124 1 7912.0 40 6080)0010,4 160 160 200 d .,z:.;:,_ .......... _o.,....._ o _....,,.ao ,,...,!oo A ..o... .2... _o .,. f... ..~ .....H74039.D MH3345.Pi Mon Apr 04 09:05:04 2005 MSH Page 4 2 108 of 122 Q ACCUTEST.N9337S V57, IMI'-1 M FIX!, I v F. 6ample HesuIIs: _________Abundance Scan 1279 (15.466 min): H73733.D (-)Re f5O 82 204 39 99 ,69 11~Wz-..- 40 60 80 100 120 140 160 180 200 220#66 Fluorene Concen: 4.45 ppb RT: 15.34 min ScanM 1241 Delta R.T. 0.03 min Lab File: H74039.D Acq: 2 Apr 2005 4:31 am AbunOance Raw50 kbndnce 50 nmVz-.>Scan 1241 (15.336 min): H74 11 139.0 6 Tgt Ion 166 165 167 Ion:a66 Resp: Ratio Lower 100 93.5 59.7 17.3 0.0 43632 Upper 119.7 43.2 41 55 69 82 95 15-1395 ,h 1 .A 1 ,,I .1 .' 1 .I L 15 .182194206 221" hývý -ý; ýv-q4 , I ..' I ...I ...I ...I ...I ...I ..." 40 60 100_20 140160 Scrn 12.11 (15.336 riini): H740"" ... .i ...I -180 200 221 182 20322 Abundance Ion 166.00 (165.70 to 166.70): l Ion 165.00 (164.70 to 165.70): 20000 Ion 167.00' ,166.70 t: 167.70le I!15.34 15000 10000 5000 Time-- 15.20 1 5.30 15.40)82 42 60 10011312613940 60 80 100 120 140 160 180 200 220 Abundanct Re f5C Abundance Ra W~n Scan 1475 (17.677 min): H73733-D() 118#78 Phenanthrene Concen: 5.30 ppb RT: 17.55 min Scan# 1437 Delta R.T. 0.02 min Lab File: H74039.D Acq: 2 Apr 2005 4:31 am 76 152 51 J1 102 125 193 40 60 80 100 120 140 160 180 200 220 240 260 280 1 Scan 1437 (17.548 min): H74039.D 118 Tgt Ion 178 Ion:178 Resp: Ratio Lower 100 64336 Upper i 179 15,0 0.0 44.6 176 17.8 0.0 48.6 Abundance Ion 178.00 (177.70 to 178.70): 1, Ion 179.00 (178.70 to 179.70): tj-76 30000 ioni 176.00 (175.70 In 176.701r 41 7203218234 253 281 m'z-. 40 60 80 100 120 140 160 180 200 220 240 260 280 25000 17.55 1 Scrn 14137 (17.54Fmw inOi H74039.D 20000 15000 Sub100 50 1W 5000 76 52 i.3651z-- ~ (~4 q 10.126 11,.980214230 253 281 0 17.40 17.50 17.60 i n-V -, 40 0 0 10 10 10 60 80 00220 240 260 280 ~fm-> 17.40 1'7.50' 17.60 H74039.D MH3145.N Non Apr 04 09:05:04 2005 MSý]Page 5 e 109of122 r ACCUTEST N93379 -I ,. :S ' ! f , . "V Abundance Scan 1485 (17.790 min)1 Re f5O 89 505 1 ... I. 9,.. " .1 11 5- 1. ...hnz--> 40 60 80 100 120 140 160 1 W inda~n~ce Scan 1446T(17.672 m1 Raw1 5 0 S 66 89 15 149 0 60 80 100 120 140 160~Abundance Scan~ 1.448 (1 7172 rail Sub 66 89 149 nyz--> 40 60 80 100 120 140 160 1): H73733,D (-)18 479 Anthracene Concen: 0.95 ppb RT: 17.67 min Scant 1448 Delta R.T. 0.03 min Lab File: H74039.D Acq: 2 Apr 2005 4:31 am~6o 220 240 260 280 K0 2010'220 240 2160 28'0 n): H74039.D 203218.). 233 252 281 Tgt Ion 278 279 176 Ion:178 Resp: Ratio Lower 100 13.7 0.0 17.9 0.0 11877 upper 45.2 48.2 kbundance Ion 178.00 (177.70 to 178.70): 1.Ion 179.00 (178.70 to 179.70): I-30000 IQ,, 176.00 (175. 70, Iv, 176.70): -2500014 1f:- .4 ...... .......... I 1B 9 200 23_ 2 260 280! ,1992115 232 262 281 20000 15D000 10000 5000{ 17.67 0 1-> 17.60 17.70 7ýW a 80 200 220 240 260 280 "inr Abundance Scan 1520 (18.185 mn): H73733.D (-)l(7 Re f50 83 139 39 83,, .ýg 98113 mnvz--> 40 60 80 100 120 140 160 180 200 220 240 260 ~~~ ..... ........ .; .............. .- -.- ..... ........ ...... ...... ...b.ndanc Sc ýan 1455 (18.089 min): H74039.0 167 Raw50 83 139 3W 1 5 1 ,. ..1 10 0 1094209224239 265 DIM 4,,l0 6 80 7 0.. ......1.... .... ....40 60 80 100 120 140 160 180 200 220 240 260#80 Carbazole Concen: 9.93 ppb RT: 18.09 min Scant 1485 Delta R.T. 0.03 min Lab File: H74039.D Acq: 2 Apr 2005 4:31 am Tgt Ion:167 Resp: Ion Ratio Lower Upper, 167 100 166 20.6 0.0 139 12.3 0.0 50.2 42.1 Abundance Ion 167.00 (166.70 to 167.70): i Ion 166.00 (165.70 to 166.70): P 50000 Ion 139.00 (138.70 to 139,701: 14 18.09 40000 Abundance St:in 1480 ('8.0S" mn~h) H74039,.) I 30000 Sub5 20000 50! 83 139100 ,. 39 63 99114 I: 192208 225240 276 ( 0 ......... J__ i...._ .o .2 ., .... .. -, -..,....2 ........0. .H74039.D 81H3145.MMon Apr 04 09:05:05 2005 MSli MSH Page 6~ACCLUIET. N93379 T-DWTC' "K I I C.ý ý tS@MPIC HeSUITS: 60 Abundance Scan 1702 (20.238 min): H73733.D (-)2(2 Re f0 101 51 75 123 150174 n'z-- 50 100 150 200 250 300 350#82 Fluorantbene Concen: 1.36 ppb RT: 20.14 min ScanW 2667 Delta R.T. 0.02 min Lab File; H74039.D Acq: 2 Apr 2005 4:32 am i'Aounaance iRa Scan 1667 (20.143 min): H74039. D 2q2 Tgt Ion 202 101 100 Ion:202 Resp: Ratio Lower 100 18.2 0.0 17.8 0,0 15769 Upper 48.1 44.5 66 43 101 23~ OrA 281 J1 2 254 281 359.I I7--1 I M~undance 10. 150 200 250 300 Scon 1567 (20.1e43 rnt): H74039,D -).202 I 350 Abund on 202.00 (201.70 to 202.70): Ir 0 Ion 101.00 (100.70 to 101,70): 11 Ion 1 -10.00 (99,70 t. 100.70): H 01 8000 20.14 6000 4000 2000 Time--s 20.0020.1020.2020.30 st.bc 124145 .17 243 269 359 50 100 150 200 250 300 3 5 0 Abundance Scan 1740 (20.657 min): H73733.D (-)2 2 Re f5O10 39 55 715 122 160 174 rnfz--> 40 60 80 100 120 140 160 180 200 220 240 260 280 Ab ndee Scan 1705 (20. 571 min): H74039.D 2 21 R a w6C#86 Pyrene Concen: 0.94 ppb RT: 20.57 min Scanl 1705 Delta R.T. 0.03 min Lab File: H74039.D Acq: 2 Apr 2005 4:31 am Tgt Ion 202 101 100 Ion:202 Resp: Ratio Lower 100 19.2 0.0 18.0 0.0 10864 Upper 54 .2 49.8 0 )Abundance Ion 202.00 (201.70 to 202.70)" H! 40 0 0 Ion 101.00 (100.70 to 101.70)-i I i l ,/ ,128 149165 185 1i21 o,- 10 CU.r 0 0, 90.(70 1 r 0.. .7 0): 1;04A. 1 .. i...1', i ..i. ....i ...... ....... 20.57 inz-> 40608b100 120 140 160 180 200 220 240 260 280 2 Abundance 1705 (20.571 mnn): 1H74039.1) 1--202 4000 Ub50 2000 101 41 61 79 i 125 149 174 1 219 244 264281 01 jmvz-.> 40 60 80 100 120 140 160 180 200 220 240 280 28 .. 2050 20,60.H174039.D M313415.M~ Mon Apr 04 09:05:05 2005 Page 7 O -11of 122 Q ACCU TES I N9337£ .S' : .: *I ~ X k IM1, Sample Results: N Quantitation Report Data File C:\HPCHEM\I\DATA\EH3145\H74040.D Acq On : 2 Apr 2005 5:01 am Sample : N93379-4 Misc : OP19692,EH3145,1000 MS Integration Params: RTEINT.P Quant Time: Apr 2 11:16 2005 Quan (QT Reviewed)Vial: 29 Operator: SEANWE Inst : MSH Multiplr: 1.00 t Results File: MH3145.RES Quant Method : C:\HPCHEM\I\METHODS\MH3145.M (RTE Integrator) Title : Semi Volatile Extractables by GC/MS Last Update : Sat Apr 02 08:32:42 2005 Response via : Initial Calibration DataAcq Meth MH3145 Internal Standards R.T. QIon Response Cone Units Dev(Min)......................................................................... 1)25)48)69)84)94)1,4-Dichlorobenzene-d4 Naphthalene-d8 Acenaphthene-d10 Phenanthrene-dlO Chrysene-d12 Perylene-d12 8.65 10,68 14.13 17.50 22.53 24.93 152 136 164 188 240 264 159765 611615 285582 397200 304682 295846 40.00 40.00 40.00 40.00 40,.00 40.00 ppb ppb ppb ppb ppb ppb 0.02 0;02 0.03 0.03 0 .03 0.03 System Monitoring Compounds 5) 2-Fluorophenol Spiked Amount 50.000 8) Phenol-d5 Spiked Amount 50.000 26) Nitrobenzene-d5 Spiked Amount 50.000 52) 2-Fluorobiphenyl Spiked Amount 50.000 74) 2,4,6-Tribromophenol Spiked Amount 50.000 S 87) Terphenyl-d14 Spiked Amount 50.000 Target Compounds 39) Naphthalene
- 45) 2-Methylnaphthalene
- 60) Acenaphthene
- 63) Dibenzofuran
- 66) Fluorene 78) Phenanthrene
- 79) Anthracene
- 80) Carbazole 82) Fluoranthene
- 86) Pyrene I I 6.76 112 146408 23.34 Recovery =8.25 99 121598 14.34 Recovery =9.53 82. 260327 48.73 Recovery =2.67 172 431961 41.82 Recovery =5.91 330 68452 47.96 ppb 0.02 46.68%ppb 0.04 28.68%ppb 0.03 97.46%ppb 0.02 83.64%ppb 0.03 95. 92%ppb 0.03 88.82%I 20.83 244 Recovery 349838 44 Recovery.41 30.72 21. 97 14.20 14.57 35.34 37.56 37.67 38.10 20.15 20.57 128 142 153 168 366 178 178 167 202 202 66667 22294 44118 33378 44414 65966 31733 111152 15291 20984 4 .60.2 .34 5.14 2.73 4 .68 5. 61 0. 97 9.97 1.36 0.97 ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb Qvalue 79 94 94 95 99 99 96 98 93 91 (V) = qualifier out of range (m) = manual integration H74040.D MH3145.M Mon Apr 04 09:05:14 2005 MSH Page 1112 of 122 NACCU-'EST.
N93379 .;** -- 10 I rr'"M,, W t_ "P.Z ; y'- 111,117 W = = -ýijfiljjle Mv!ýUllýi: Pý &= .Quantitation Report Data File C:\HPCHEM\2\DATA\EH3145\H74040.D Acq On 2 Apr 2005 5:01 am Sample : N93379-4 Misc : OP19692,EH3145,1000 MS Integration Params: RTEINT.P Quant Time: Apr 2 11:16 2005 Q Vial: Operator: Inst Multiplr: 29 SEANWE MSH 1.00 ant Results File: MH3145.RES Method Title Last Update Response via C:\HPCHEM\I\METHODS\MH3145.M (RTE Integrator) Semi Volatile Extractables by GC/MS Sat Apr 02 08:32:42 2005 Initial Calibration Initial Calibration 0$4.9 C: -{?4040.O 0$V 5 6 6 a-0$0.z 4 Time >H?4040.D MH3145.M Mon Apr 04 09:05:14 2005 MSH Page 2 1 113 of 122 N "ACCUT.EST. N9337!)9 ;I --. ..ý ,. .1.61 *~ I -ýom-pie -4osulw-: Abundance Scan 868 (10.829 mi): H73733,D (-)Re f5O 39 1 , 89 1 13 i 39 162 207 ITVz--> 40 60 80 100 120 140 160 180 200 Abundance Scan 832 (10.721 min): H74040.D Rw 5 146#39 Naphthalene Concen: 4.60 ppb RT: 10.72 min Scan# 832 Delta R.T. 0.03 min Lab File: 1774040.D Acq: 2 Apr 2005 5:01 am Tgt Ion 128 129 127 Ion:128 Resp: Ratio Lower 100 22.4 0.0 15.6 0.0 66667 Upper 40.9 40.9 1 39 51 6477 102 115 0I 160ý'z- -.40 60 80 100 20 .140 6 180 200...'Abundance Scan 832 (10,721 min): H74('10.D C-)131 Subso 146 425 68 87102113 m'z-> 40 60 80 100 120 140 160 180 200 Abundance Ion 128.00 (127.70 to 128.70): V.Ion 129.00 (128.70.1o 129.70): HI 30000 1o0 127.00D126.70 tr 127.70). 0 1 10.72 20000 10000 Lime--> 10.60 10.70 10.80Abundance Re fb O Abundance Scan 980 (12,092 16n): H-173733.0 (-)142 445 2-Methylnaphthalene Concen: 2.34 ppb RT: 11,97 min Scan# 943 Delta R.T. 0.03 min Lab File: H74040.D Acq: 2 Apr 2005 5:01 V 115 1. 127 39 57, 7,1 8 1iO 207 40 60 80 100 120 140 ' 160 180 200 Scan 942 (11,974 rr;n). H74040.D 142 ,(..... i Tgt Ion 242 141 115 Ion:142 Resp: Ratio Lower 100 22294 Upper}81.7 54.4 114.4 21.2 0.0 58.7 Ra Wsn 1569 9A 115 bundance Ion 142.00 (141,70 to 142.70): 4 ~ t 1 55 69It 12000 :on 141.00 (140.70 to 141.70): P 17 15917 18i100 Io 1,1).00 i114.7 J.,115.70.))( 12 15170 187 1000 11.97.r'z--> 40 60 80 100 120 140 160 180 200 Abundance 9.m (i"4 min):H740.L .- 8000 142 6000 Subý 4 0 0 01 115 2000 t 55 69 ' I, , 38 50 ,0 ?61 2 ij 9 174 187... ....... .............. o......0P.. nV> 4'0 610 80 100 120' 14'0 16'0 18'0' 20 ' i- 11.9 12.0 120 H74040.D MH3145.M Mon Apr 04 09:05:15 2005 MSH MSH Page 3 SACCLJITES 1 N93379 MFý MZMTK, 71 :1 W W M-MG sampie Results: M, .M, -Jý80 ,Abundance Scan 1178 (14.326 min): H73 33.D (-)Re fsO 76 n3z--> 40 60 80 100 120140 160 180 200 vz--> 40 60 80 100 120 140 160 180 200 h3 50 0116 nYz--> 40 60 80 100 120 140 160 180 200 460 Acenaphthene Concen: 5.14 ppb RT: 14.20 min Scanl 1140 Delta R.T. 0.03 min Lab File: H74040.D Acq: 2 Apr 2005 5:01 am Tgt Ion 153 152 154 Ion:153 Resp: Ratio Lower 100 44118 Upper 50.6 15.6 75.6 93.6 59.1 119.1 Abundan.200 1001 Ce Ion 153.00 (152.70 to 153.70): F Ion 152.00 (151.70 lo 152.70): 1 lon 15.4.00. (13.70 to, 14.,70) .00 14.20 00 00 0 14.10 14.20 501 Time-.>Abundance Scan 1211 (14.699 mmn): H73733.D (-)148#63 Dibenzofuran Concen: 2.73 ppb RT: 14-.57 min ScanM 1173 Delta R.T. 0.02 min Lab File: H74040.D Acq: 2 Apr 2005 5:01 am Ref50 139 390 351 63 8 114 [15 l 1820'. 61.I .. .III I i iT inVz--> 40 60 80 100 120 140 160 180 200 220 i Abundance ~~Scan 117-3 (459m):H44 Raw50 ~39 69 ~155l41 55, 69 19¶5,. 1 95 OU.4. ii 111141 4 ~i.L w ~.18019 2 204 232 Tgt Ion 168 139 269 Ion:168 Resp: Ratio Lower 100 34.6 2.2 16.4 0.0 33378 Upper 62.2 44.0 Ion 168.00 (167.70 to 168.70): I, Ion 139.00 (138.70 t0 139.70): P, isooo 16."..00) (168.70 It" 1 9. 701): ki0 I .I ..I ..I I 40 60 80 100 120 140 Abundance Sub 50 ScIan 1173 min 139 3 53 6 i9 84 1 !5 1 ,i..6 180200 2 14.57 168 10000 5000 10208 232 o-160 180 I ,20 .... 1.0 46 1 .160 180 200 14.50 14.60 14.'70 I... .... 4 0. .. 100_ 120 140 1174040.D. MH31]5.M Mon Apr 04 09:05:15 2005 MSH Page 4 EM .J 115 of 122 N N93379 .ý,:,ni :ý PAW bampic Hesulls: W, Abundance RefSO 0 (Abundance Raw 5 z 0 Sub,5 Ii l Scan 1279 (15.466 rain): H73733.D (-)1 6 82 139 395,1 , 6, 99 , 127 1 151 11 178 204 I,#66 Fluorene Concen: RT: 15.34 Delta R.T.Lab File: Acq: 2 Ap 4.68 ppb min Scant 1241 0.03 min H74040.D'r 2005 5:01 am 6 Resp: 44414 Lower Upper 59.7 119,7 0.0 43.2 L..' '1 -' '1 ... I ' ;'. 1 ' '1 ... .1 . 1; 1 '1 40 60 80 100 120 140 160 Scan 1241 (15.336 min): H?4C 180 200 220 Tgt Ion 166 165 167 Ion: 16 Ratio 100 89.0 12.4 41 55 69 95,111 1111 ,..l.iI..]J 115 139 i IZ7 .15$.1219420621811 1 .. -I I IL-Oh. .W..1 ý*Vl- -40 60 80 100 120 140 160 180 200 220 ,:ýw, 12-11 (11.336 min): H-74(YWO 0 166 8 2 42 58 f 98 111124 139 ) 182 203 218 Abundance ton 166.00 (165.70 to 166.70): -'j Ion 165.00 (164.70 to 165.70): PI 20000 lon 167.00 (65,7C to 1)67.70): 'i 15.34 15000 10000 5000 05 Tme--> 15.20 15.3' 15.s4'0' 1'5.,5,C TVZ-->U, 40 60 80 100 120 140 160 180 200 220 r j~Abunldance Re 5O Scan 1475 (17.677 min): H73733.D (-)118 t78 Phenanthrene Concen: 5.61 ppb RT: 17.56 min Scant 1438 Delta R.T. 0.03 min Lab File: H74040.D Acq: 2 Apr 2005 5:01 ae m 76 152 51 J 1 102 125 II It' .. .i. ...... I .. ....40 60 80 100 120 140 160 1 V 193 80 200 220 240 260 280 8 Tgt Ion 178 179 176 Ion:178 Resp: Ratio Lower 100 14.1 0.0 19.2 0.0 65966 Upper 44.6 48.6 Ra w5oýAbundance ion 178.00 (177.70 to 178.70): H Ion 179.00 (178.70 to 179,70): 1 76 152 1766.00 il'17570 t. !76.70): C- '. .'.A~m. 1.ý1 Il 17.5640 60 80 100 120 140 160 180 200 220 240 260 280 1 Abundance a; 143 17 , 55 r 'vvi H740'..0.D H-D Su5" 10000 76 151 50 J 1 99 115131 1~ 194 213 232 252 281 1 ....40 10 1r-_-.> 1.740. 17.50 rrh'z-. 40 6080 100 120 140 160 180 200 220 240 260 280 [lie-T74 75 76 It74040.D Mtt3145.MMon Apr 04 09:05:15 2005 MSH Page 5 an 116 of 122 GACCUTrEST. N93 7 SS ý.. F: ý.: ..JUT AVELLAW,' Eli 6 617-1 Sample Resullts: Scan 1485 (17.790 rnmm): H73733.D(-) Ref50 89 15 1O 39 63 1 1101268152 0 1'; ' %
- ,,II1 '" .... 4" 0 .. 12 "' I. .t nvz--> 40 '610 ...810"1'00 1-0. 140 160 180 200 220 24026 4(79 Anthracene Concen
- RT: 17.67 mi Delta R.T.Lab File: Acq: 2 Apr 0.97 ppb in Scan# 1448 0.03 min H74040.D 2005 5:01 am 41 91 66 109 128 4 nyz-... 40 60 80100 120 140 160 180 200 220 240 260 Abundance Scan 1448 (17.671 min',i H74040.D '-1 Sub 7'50 Tgt Ion 178 179 176 Ion:178 Resp: Ratio Lower 100 13.5 0.0 19.7 0.0 12733 Upper 45.2 48.2 Abundance ion 178.00 (177.70 to 178.70): t Ion 179.00 (178.70 to 179.70): H.30000 Io, 176.l0 o175.0 t 170.70)20000 10000 Timne--> 17.60 17.70 CO q 4 6 3 1 106 143 J1 203218 240256 275 U , II,', I I ri, .. ..... .; [';"; ; i , [ i i ['T i={ i i .... ..
..... .. ...40 60 80 100 120 1 60 1 80 180 200 22O 240 260 Abundance Scan 1520 (18.1 Re f5O 85 m m): H73733.D (-)107#80 Carbazole Concen: 9.97 ppb RT: 18.10 min Scant 1486 Delta R.T. 0.04 min Lab File: H74040.D Acq: 2 Apr 2005 '5:01 am 1 8.3 1 39 39 63 11 3 1 rnfz--> 40 60 80 100 120 140 160 180 200 220 240 260 280 AbundanceScan 1486(18.100 min): H-74040.1) iRaW 5 0 j Tgt Ion 167 166 139 Ion:167 Resp: Ratio Lower 100 19.8 0.0 11.0 0.0 111252 Upper 50.2 42.1 II Oundance Ion 167.00 (166.70 to 167.70): H, fA Ion 166.00 (165.70 lo 13&70):I-i 4 683 9 15139 50000 lot- 1 i.0 1C3.'0 139.701): 83 66 9 1139 183 200215 232 249 267 285 i 0 ,4 to .............. ... ..Wz 40 60 8.0' 100120 140 160 180 200 220 240 260 280 400018.10 Abundance -.np 14/(' (11. 100 m~n): H7440.L .167 30000 Subo 20000 83 1391 0 , 43 63 113 182197216232249267285 0 ......wz=.a> 40 60 80 100 120 140 160 180 200.222 2.f.10 1 8, '1.. 10 8.r20....- ......H74040.D MH3145.M Mon Apr 04 09:05:16 2005 MSH Page 6 sn!' 117 of 122 3ACCUTr.ST. N93379 F"14-1 ?,17,V,,'77iTr117T?111r , I , Sample Results: ~ 'i 41 Abundance Scan 1702 (20.238 min): H73733,D (-)2 2 Re f5OI 101 51 75 i 123 150, 174 n'z--> 40 60 80100 120 140 160 180 200 220 240 260 280 Abundance Scan 1668 (20.154 min): H24040.D S22 Raw, 5 43 101 28145 1 74 218 22257 281 182 Fluoranthene Concen: 1.36 ppb RT: 20.15 min Scant 1668 Delta R.T. 0.03 min Lab File: H74040.D Acq: 2 Apr 2005 5:01 am Tgt Ion 202 101 100 Ion:202 Resp: Ratio Lower 100 22.7 0.0 15.4 0.0 15291 Upper 48.1 44.5 rrz-> 40.60 80 100 120 140 160 180 2('Abundance .c: 16(0.5.nlir( H74 2 SUbs0 101 z 40 60 80 1 123130 168180 74"nz--> 40 60 80 100 120 140 160 180 20 0 220 240 260 280 240.D 2 Abundance Ion 202.00 (201.70 to 202.70): F, Ion 101,00 (100.70 to 101.70): F-,Io)n 100.00 (,0.70 to i17 01) Hi 8000 20.15 6000 4000 2000 I 11 228 254 273 00 220 240 260 280 kme-->20.10 20.20 A4bundance 1Ref50 Scan 1740 (20.667 rain): H73733.0 (-)202 086 Pyrene Concen: 0.97 ppb RT: 20.57 min Scant 1705 Delta R.T. 0.03 min Lab File: H74040.D Acq: 2 Apr 2005 5:01 am%W 101 9 55 75 4 122 150 174 J rnvz--> 8'-4060 0100 120 140 160 180 200 220 240 260 .Tgt IOn:202 Resp; 1098.................... .1 ;~ iii ; { ..................... ......... I :on Ratio Lower Uppe r S bundance S~can 1705 (20.571 min): H74040.DIo Rai Lwe Up r 202 202 100 101 15.9 0.0 54 .2 100 19.9 0.0 49.8 Ra 0 66" ._tAbundance ion 202.00 (201.70 to 202.70): 41 101 ion 101.00(100.70 to 101.70); -145 165 183 .219 6000 on 100.00 H90 70 tc 100.70): o. l .1 ')! I 244260 281...1 ..[ ....i ........I ... 1. 1 ....I ....1 .......2 0 ,5 7 rn'z 40 60 "80 1 O 120 140 160 180 200 220 240 260 280 20.57 Abundance Scat: 1705 "20.571 vIll): 202 4000 Sub~o1 20 5002000 77 1!219 36 51 1. 125 148 174 j! 250 274 0l', " ", -,z- ...... 4060. 60 01 180o2_i 220o240 260_280 ,.lne.__2.50 20..............60 4 H74040.D 51H3145.M Mon Apr 04 09:05:16 2005 MSlq Page 7 M 1180f122 L9335 * "ývw -7 o f7j' So mpie Resu its: 08 =11 W Quantitation Report Data File : C:\HPCHEM\I\DATA\EH3145\H74041.D Acq On 2 Apr 2005 5:45 am Sample : N93379-5 Misc : OP29692,EH3145,1000 MS Integration Params: RTEINT.PQuant Time: Apr 2 11:36 2005 Quani (QT Reviewed)Vial: 30 Operator: SEANWE Inst : MSH Multiplr: 1.00 t Results File: MH3145.RES Quant Method Title Last Update Response via DataAcq Meth C:\HPCHEM\1\METHODS\MH3145.M (RTE Integrator) Semi Volatile Extractables by GC/MS Sat Apr 02 08:32:42 2005 Initial Calibration MH3145 Internal Standards R.T. QIon Response Conc Units Dev(Min)......................................................................... I) 1,4-Dichlorobenzene-d4 8.65 152 157954 40.00 ppb 0.02 25) Naphthalene-d8 1,0.68 236 620822 40.00 ppb 0.02 48) Acenaphthene-dlO 14.12 164 295023 40.00 ppb 0.02 69) Phenanthrene-dlG 17.50 388 425212 40.00 ppb 0.02*84) Chrysene-d12 22.53 240 320843 40.00 ppb 0.02 94) Perylene-d12 24.93 264 300804 40.00 ppb. 0.03 I System Monitoring Compounds 5) 2-Fluorophenol Spiked Amount 50.000 B) Phenol-d5 Spiked Amount 50.000 26) Nitrobenzene-d5 Spiked Amount 50.000 52) 2-Fluorobiphenyl Spiked Amount 50.000 74) 2,4,6-Tribromophenol Spiked Amount 50.000 S 87) Terphenyl-d14 Spiked Amount 50.000 6.77 112 138001 22.25 Recovery 8.26 99 117869 14.06 Recovery =9.52 82 248562 45.84 Recovery =12.68 172 440211 41.25 Recovery =25.91 330 60982 39.92 Recovery =20.83 244 383264 46.20 Recovery ppb 0.02 44.50%ppb 0.05 28.12%ppb 0.03 91.68%ppb 0.02 82.50%ppb 0.02 79.82%ppb 0.02 92.40%Target Compounds Qvalue (k) = qualifier out of range (m) = manual integration H74041.D MH3145.M Mon Apr 04 09:05:25 2005 MSH Page I O 119 of122 QACCUTEST N53379 *: .."- .. 3om le Requilm: V>i6E*7 1. 'j IMI , =H --1-Quantitation Report Data File C:\HPCHEM\I\DATA\EH3145\H74041.D Acq On : 2 Apr 2005 5:45 am Sample 1N93379-5 Misc OP19692,EH3145,1000 MS Integration Params: RTEINT.P Quant Time: Apr 2 11:16 2005 Q Vial: 30 Operator: SEhNWE Inst : MSH Multiplr: 1.00 uant Results File: M}13145.RES Method : C:\HPCHEM\I\METHODS\MH3145.M (RTE Integrator) Title Semi Volatile Extractables by GC/MS Last Update : Sat Apr 02 08:32:42 2005 Response via :Initial Calibration 1 Abundance TflC: H74041.D 750000 700000 650000 550000 -00 500000 lU 450000 40000035000 0 R V.0, A1 0, g a S 300000 250000 200000 150000 E 0, p*0,0,".100000 50000 oI4 8..00 ..0..0o0 1...!2,..00. ..4 .6.. 1o .20.0o 22.00 24.0._ 26 ..2 ..oo, Y?4041.D MH3145,M Mon Apr 04 09:05:26 2005 MSH G1!i 120of 122 Q A CCU T-S-T N93379'I. 0 *.. -~ I ..I~ ~ - QC Report: LACM Ieot 'Quantitation Report Data File : C:\HPCWEM\I\DATA\EH3145\H74032.DAcq On : 1Apr 2005 11:54 pm Sample OP19692-MB2 Misc : OP19692,EH3145,1000 MS Integration Params: RTEINT,P Quant Time: Apr 4 10:08 2005 Quan (QT/LSC Reviewed)Vial: 21 Operator: SEANWE Inst : MSH Multiplr: 1.00 t Results File: MH3145.RES Quant Method : C:\HPCHEM\I\METHODS\MH3145,M (RTF Integrator) Title : Semi Volatile Extractables by GC/MS Last Update : Sat Apr 02 08:32:42 2005 Response via Initial Calibration DataAcq Meth : MH3145 Internal Standards RT. QIon Response Conc Units Dev(Min)------------------------------...- ...........- ---------------------------1)25)48)69)84)94)1,4-Dichlorobenzene-d4 Naphthalene-d8 Acenaphthene-dlO Phenanthrene-dlO Chrysene-d12 Perylene-d12 8.63 10.66 14.10 17.47 22 .52 24.91 152 136 164 188 240 264 157294 608911 294346 442121 330113 291971 40 .00 40. 00 40.00 40.00 40.00 40.00 ppb ppb ppb ppb ppb ppb 0 .00 0.00 0.00 0 .00 0.01 0.01 0, I System Monitoring Compounds 5) 2-Fluorophenol Spiked Amount 50.000 8) Phenol-d5 Spiked Amount 50.000 26) Nitrobenzene-d5 Spiked Amount 50.000 52) 2-Fluorobiphenyl Spiked Amount 50.000 74) 2,4,6-Tribromophenol Spiked Amount 50.000 U 87) Terphenyl-d14 Spiked Amount 50.000 6.76 112 180182 29.37 Recovery 8.23 99 a79936 21.55 Recovery =9.50 82 225156 42.33 Recovery =12.66 172 407492 38.27 Recovery =15.88 330 57264 36.05 Recovery =20.81 244 368723 43.20 Recovery ppb 0.01 58.34%ppb 0.02 43.10%ppb 0.01 84.66%ppb 0.00 76.54%ppb 0.00 72.10%ppb 0.01 86.40%Target Compounds Qvalue t (#) = qualifier out of range (m) = manual integration H34032.D MH3145.M Mon Apr 04 10:08:58 2005 MSH Page , O 121 of 122 QACCuTIES1., NS933 9 ... .", *-*,-.1 .740 WA 4-l **.. '. , OC Report: I Quantitation Report Data File C:\HPCHEM\I\DATA\EH3145\H74032.D S Acq On 1 Apr 2005 11:54 pm Sample OP19692-MB2 Misc : OP19692,EH3145,1000 MS Integration Params: RTEINT.P Quant Time: Apr 4 20:08 2005 Qu Vial: Operator: Inst t Multiplr: 21 SEANWE MSH 1,00 uant Results File: MH3145.RES Method : C:\HPCHEM\k\METHODS\MH3145.M (RTE Integrator) Title : Semi Volatile Extractables by GC/MS Last Update : Sat Apr 02 08:32:42 2005 Response via : Initial Calibration 650000 600000 57 500000 z 450000 0 400000 V 350000 300000 250000 200000 , 150000 100000 50000 CI 0:, I.', flme--'2.00 4.00 6.00 8.00 10.00 12,00 14.00 16.00. 18.00 20.00 22.00 24.00 26.00 28.00 H74032.1 MH3125.M Mon Apr 04 10:08:58 2005 MSH Page 2 an 122 of 122 Q ACCME'T N93379!TYRITIVIMIYOZ Appendix G Baseline Ecological Evaluation Report Baseline Ecological Evaluation PSEG Salem Generation Station Hancock's Bridge, New Jersey Incident No. 04-08-02-2350-16 PREPARED FOR PSEG Nuclear, LLC Baseline Ecological Evaluation PSEG Services CorporationSalem Generating Station Hancock's Bridge, New Jersey Incident No. 04-08-02-2350-Kevin Costello Environmental Scientist Prepared for:PSEG Services Corporation Prepared by: ARCADIS G&M, Inc.1114 Benfield Boulevard Suite A Millersville, Maryland 21108 Tel 410 987 0032 Fax 410 987 4392 Miranda Henning Principal Scientist Our Ref.: NP000603.0001 Date: June 2005 This document is intended only for the use of the individual or entity for which it was prepared and may contain information that is privileged, confidential, and exempt from disclosure under applicable law. Any dissemination, distribution, or copying of this document is strictly prohibited. 16 Baseline Ecological Evaluation PSEG Services CorporationSalem Generating Station Hancock's Bridge, New Jersey 1. Introduction 2 2. Chemicals of Potential Ecological Concern 3 3. Environmentally Sensitive Area 3 3.1 Site Setting and Land Use 5 3.2 Characterization of Environmentally Sensitive Area 6 3.3 NJDEP Geographic Information System Search Results 7 4. Migration Pathways to Environmentally Sensitive Area 7 5. Summary and Conclusions 8 6. References 9 Tables 1 Summary of Groundwater Sampling Results 2 Summary of Soil Sampling Results 3 Comparison of Estimated Groundwater Concentrations to Surface Water Criteria Figures 1 Site Location and Old Well Locations 2 Site Map 3 New Well Locations 4 Photograph Map Attachments A New Jersey Department of Environmental Protection Geographic Information System Database Search Results B Photo Log Baseline Ecological Evaluation PSEG Services CorporationSalem Generating Station Hancock's Bridge, New Jersey 1. Introduction ARCADIS prepared this Baseline Ecological Evaluation (BEE) for the PSEG Nuclear, LLC Salem Generating Station (the Site) located in Hancock's Bridge, New Jersey (Figure 1). The BEE was conducted in accordance with the New Jersey Department of Environmental Protection's (NJDEP's) tiered approach for conducting ecological evaluations and ecological risk assessments. The BEE comprises Tier I, which is a screening process required for all NJDEP Site Remediation Program (SRP) sites. The objectives of the BEE are to ensure that all sites are assessed for potential ecological effects and that sites without ecological concern are quickly eliminated from further, more rigorous site-specific investigation. Only those sites that have the potential for adverse ecological effects are retained for further investigation and/or risk assessment at the Tier II level. It is only at the Tier II level that definitive estimates of risk and the basis for determining clean-up goals are provided.In accordance with NJDEP guidance (Hamill and Demarest 1997) and regulations N.J.A.C. 7:26E-3.11 (Technical Requirements for Site Remediation [Technical Requirements]; N.J.A.C. 7:26E-3.1 1), this BEE evaluates the co-occurrence of (a)chemicals of potential ecological concern (COPECs); (b) environmentally sensitive areas; and (c) chemical migration pathways at the Site. Existing site documents and analytical data, along with the results of a site reconnaissance, are used together to document these conditions. The Site is located on a 740-acre parcel adjacent to the Delaware River, in Hancock's Bridge, New Jersey. The Salem Generation Station consists of two nuclear generating stations. A third nuclear generation station is located to the north at the adjoining Hope Creek Generating Station (ARCADIS 2005). This BEE is specific to the area of the diesel fuel release (Incident No. 04-08-02-2350-16), which occurred just to the south of the Salem Unit 1 Fuel Handling Building. The remainder of the Site is an operating nuclear generating station and was not evaluated as a part of this BEE.On August 2, 2004, PSEG personnel observed a diesel fuel odor in a catch basin associated with the storm water collection system just south of the Salem Unit 1 Fuel Handling Building (ARCADIS 2005). A pressure test on the underground diesel line was performed and revealed the leak was within a 300-foot section of piping. A"Tracer Tight" gas analysis was performed and the approximate location of the leakwas identified. An excavation was opened around the piping to expose and repair the piping. The excavation was backfilled with clean fill material. The diesel leak area Baseline Ecological Evaluation PSEG Services CorporationSalem Generating Station Hancock's Bridge, New Jersey consists of asphalt covered drive and a gravel area adjacent to and south of the Salem Unit 1 Fuel Handling Building (see Section 3.2). The leak occurred approximately 300feet from the Delaware River.2. Chemicals of Potential Ecological Concern According to NJDEP guidance (Hamill and Demarest 1997) and regulations (N.J.A.C.7:26E-3.1 1), COPECs should be identified based on their ability to biomagnify or bioaccumulate and/or the presence of maximum measured concentrations greater than ecotoxicologically-based benchmarks or screening values. In general, BEEs identify COPECs only for those impacted environmental media that are accessible to ecological receptors (e.g., surface soil, sediment, and surface water). Analytical data for the CEA area are available only for subsurface soil (Table 1) and groundwater (Table 2).Currently, no impacted soils remain in the diesel leak area. The source has been temporarily mitigated, prior to implementation of the final remedy. Impacted soils were excavated from around the leak area and backfilled with clean fill (ARCADIS 2005).All historic soil sampling locations were at depths of at least 3.5 feet below ground surface (bgs) and were collected during the installation of monitoring wells AW throughAZ (Figure 3). Soil sampling results are presented in Table 1, in the interest of completeness. However, all impacted soils have either been excavated or are covered by pavement or buildings, thus precluding ecological exposures to chemicals in subsurface soil. Therefore, no COPECs are identified for subsurface soil.Groundwater monitoring activities at the Site have focused on volatile organic compounds (VOCs) and semivolatile organic compounds (SVOCS). Table 2 summarizes the most recent analytical data for groundwater at the site, including the results of the December 2004 and March 2005 groundwater sampling events.The Technical Requirements do not list any criteria or guidelines for use in selecting COPECs in groundwater, presumably because of the limited potential for ecological receptors to contact groundwater. It is only upon discharge of groundwater to surface water that ecological receptors could theoretically contact COPECs. Groundwater from this site discharges to the Delaware River, which is located approximately 300 feet fromthe diesel leak area. Given this distance and the relatively low concentrations of constituents detected in groundwater, concentrations are likely diluted to non-detectable concentrations prior to discharge to the Delaware River. Groundwater monitoring confirms that groundwater impacts are confined to a limited area of the Site. Separate-phase product has only been detected in Wells AU and AW, the two wells closest to the location of the leak. SVOCs have only been detected in Well-AV, located approximately Baseline Ecological Evaluation PSEG Services Corporation Salem Generating Station Hancock's Bridge, New Jersey 30 feet west-southwest of the leak area. VOCs have only been detected in Well X, located adjacent to the fuel handling building. Well X is approximately 20 feet east-southeast of the diesel leak area, more than 300 feet from the river. To ensure the conservatism of this BEE, ARCADIS compared average and maximum downgradient concentrations in groundwater to the lower value of the chronic marine and freshwater values listed in the National Oceanographic and Atmospheric Administration's Screening Quick Reference Tables (NOAA SQuiRTs) (Table 3). NewJersey Surface Water Quality Standards are not an appropriate basis for selecting COPECs at this Site, because those chemicals detected in groundwater only havestandards established to protect human health, rather than aquatic organisms. In contrast, NOAA SQuiRTs are based on protection of aquatic organisms and, therefore, serve as appropriate ecological screening criteria. Other potential sources of ecologically-based surface water screening values, including the Delaware River Basin Committee and the U.S. Environmental Protection Agency's (USEPA's) Ambient Water Quality Criteria (AWQC) also lacked values for the compounds detected at the CEA.Because there are no data from groundwater wells between the Well-AV and the Delaware River, the use of maximum detected groundwater concentrations represents worst case conditions. Average concentrations are more likely to reflect actual concentrations as groundwater migrates to and discharges to the Delaware River. As illustrated in Table 3, with one exception, the maximum concentrations of constituents detected in groundwater are less than the NOAA SQuiRTs values. That one exception is phenathrene, which was detected in two of nine samples. The two samples were duplicate samples and thus represent a single round of sampling at a single well. Theaverage concentration of phenanthrene was below the NOAA SQuiRT value. Thus, following dilution and attention as the groundwater migrates to the river, as well asmixing within the river, exposures of aquatic life within the river to phenanthrene are expected to be well below the screening level.In addition to considering concentrations relative to screening criteria, it is necessary to evaluate the bioaccumulative/biomagnifying potential of detected constituents. Based on NJDEP's guidance regarding biomagnifying compounds in sediment (NJDEP, 2005d)and the logarithms of the octanol water partitioning coefficients (log Kow values), dibenzofuran is the only detected compound in groundwater with the potential tobioaccumulate. Dibenzofuran was detected as an estimated concentration below the detection limit (J-qualified) in three out of nine samples. Given its low prevalence, low detected concentrations, and the likelihood of dilution and attenuation as it travels from groundwater to the Delaware River, it does not warrant inclusion as a COPEC. Baseline Ecological Evaluation PSEG Services CorporationSalem Generating Station Hancock's Bridge, New Jersey No samples have currently been taken from wells AU and AW due to the presence of separate phase diesel in the well. This product is being actively remediated by a Spill Buster unit which removes the separate phase diesel on a periodic schedule. Proof that this technique is working is illustrated by the lack of BTEX detected above the reporting limit in surrounding wells (Table 1). Further evidence tosupport this is that no TPH was detected in soil removed during well instillation (Table 2). The evidence shown above of and the continued active remediation of free product, no exposure pathways are open.Based on the above information, no COPECs are selected for groundwater. As previously noted, the absence of accessible surface soil on the site precludes identification of any COPECs in soil. Thus, there are no COPECs in any media at this Site.3. Environmentally Sensitive AreaThe second element of the BEE is the documentation of any environmentally sensitiveareas present on-site or immediately adjacent to the Site. Environmentally sensitive areas, as defined in N.J.A.C. 7:1E-4.10, include: " River channels;
- Interior wetlands;" Lakes and ponds;
- Beaches;" Reservoirs;
- Deciduous forest;" Bays and estuaries;
- Coniferous forest;" Cranberry bogs; Mixed forest; and" Coastal wetlands;
- Brush land and scrubland.
Based on a site reconnaissance conducted on April 26, 2005, information provided intechnical reports on the Site, and a search of the NJDEP Geographic Information System (GIS) database, this section describes ecological habitat types and potential environmentally sensitive areas at the Site and within a one-half mile radius of the Site.3.1 Site Setting and Land Use A site location map is shown on Figure 1. As previously noted, the Site is located on a 740-acre parcel adjacent to a brackish reach of the Delaware River. The Site is bounded to the south and west by the Delaware River, to the north by Hope Creek Generation Station, and to the east by undeveloped land. Land surrounding the site is zoned for industrial, residential, and agricultural uses (ARCADIS 2005). However, Baseline Ecological Evaluation PSEG Services Corporation Salem Generating Station Hancock's Bridge, New Jersey there are no homes located within several miles of the station. As illustrated on the GIS map provided in Attachment A, no natural heritage priority sites are located within one-half mile of the site.3.2 Characterization of Environmentally Sensitive Area Environmentally sensitive areas located within and adjacent to the Site were characterized during a site reconnaissance conducted on April 26, 2005. The Site reconnaissance was conducted by ARCADIS scientists familiar with the Site. No environmentally sensitive areas were identified within the diesel leak area. The cover in the immediate vicinity of the leak area is limited to dirt and gravel, with various sparsely growing grasses, approximately one to two inches in height (Attachment B, Photographs 1, 2 and 3). Cover in the surrounding area is comprised of asphalt, gravel, concrete and buildings (Attachment B, Photographs 4-10).Environmentally sensitive areas located near the diesel fuel leak area include the Delaware River, the associated riparian buffer along the river, and extensive wetlands.The Delaware River basin and its tributaries drain an area of approximately 1,341 square miles (NJDEP 2005a, 2005b, 2005c). The Salem Generation Station is locatedon a reach of the river known as the Central Delaware River. The Central Delaware River and its tributaries drain an area of approximately 274 square miles (NJDEP 2005b). From the Site, the Delaware River flows into the Delaware Bay and the Atlantic Ocean, approximately 50 miles away.The Delaware River and its tributaries provides habitat for numerous aquatic and terrestrial species, including aquatic birds [e.g., ospreys (Pandion haliaetus), great egrets (Ardea alba) mallards (Anas platyrhynchos)] and reptiles and amphibians [e.g., Eastern painted turtle (Chrysemys picta)]. Bird species observed during the Site reconnaissance included numerous bank swallows, a gull, an American robin, a common crow, and a great egret. In addition, the river provides habitat for many fish species, including striped bass (Morone saxatulus), bluefish (Pomatomus salatrix), and Atlantic shad (Alosa sapidissima.).The majority of land immediately adjacent to the river in the vicinity of the Site is classified as forest by NJDEP GIS. However, the area is in fact dominated by wetlands, with an estimated canopy cover of less then five percent at the time of the April 2005 site visit. The sandy soil is approximately 100 percent vegetated, with various native and exotic grasses. Arrow arum (Peltandra virginica), golden ragwort (Senecio aureus) and phragmites (Phragmites austalis [communi]) are abundant and Baseline Ecological Evaluation PSEG Services Corporation Salem Generating Station Hancock's Bridge, New Jersey stabilize the banks. Limited areas within one-half mile of the Site are also characterized as mowed lawn and service roads.
3.3 NJDEP
Geographic Information System Search Results As part of the evaluation of the presence of environmentally sensitive area, the NJDEP GIS database was searched. The following data layers were downloaded for landwithin approximately one-half mile of the Site:.Coastal centers N 1995/97 Land use/landcover
- Hydrography
- Linear wetlands* Natural Heritage priority sites 0 Streams* Lakes 0 Wetlands The GIS map is presented in Attachment A. Data layers that contain relevant information on the area searched include: the 1995/97 land use/land planning data layer, the streams data layer, and the wetlands area with Cowardin classifications datalayer. Other features listed in the NJDEP GIS database, such as Natural Heritage priority sites, are not located within the area searched.4. Migration Pathways to Environmentally Sensitive Areas The third element of the BEE is an evaluation of the potential for COPECs to migrate from the source to receptors that may be present in environmentally sensitive areas identified above. In order for a pathway to be complete, the following five components must be present: (a) COPECs in environmental media; (b) a source of release of COPECs; (c) a migration pathway that allows the COPEC to move from its source toa point of possible contact; (d) an exposure point, where the receptor may come into contact with the COPEC; and (e) an exposure pathway, through which the receptor receives an absorbed dose of the COPEC. If one of these five components is not present, exposure of the receptor to COPECs is not physically possible.Because COPECs were not identified for the diesel leak area, no pathways are complete, and exposure of ecological receptors to site-related COPECs is not possible.No COPECs were identified in soil, as all constituents have either been excavated or are covered by pavement or buildings.
Although groundwater from the diesel leak area discharges to the Delaware River, there are no COPECs for groundwater and the groundwater-to-surface water migration pathway is incomplete. Baseline Ecological Evaluation PSEG Services Corporation Salem Generating Station Hancock's Bridge, New Jersey The finding of no complete pathways is supported by the lack of evidence of potential effects in environmentally sensitive areas. For example, none of the following wereobserved during the site inspection: o Stressed or dead vegetation; o Discolored soil, sediment, or water;o Absence of biota in a specified area of the system as compared to other similar area of the same system; or o Presence of a seep or discharge.
- 5. Summary and Conclusions In accordance with NJDEP guidance (Hamill and Demarest 1997) and regulations (N.J.A.C.
7:26E-3.11 of the NJDEP Technical Requirements), this BEE evaluates the co-occurrence of (a) COPECs; (b) environmentally sensitive areas; and (c) chemical migration pathways.COPECs were not identified in either soil or groundwater at the diesel fuel leak area.Although SVOCs and VOCs have been detected in groundwater, concentrations in groundwater are below appropriate ecologically-based screening criteria for surface water. As a result of dilution and attenuation during transport, the concentrations that potentially discharge to surface water will be even lower. Thus, aquatic organisms are not expected to be exposed to harmful chemical concentrations. COPECs were not selected for soil because impacted soils either have been excavated or are covered by pavement or buildings. Therefore, no contact with ecological receptors is possible.Although the Site is largely surrounded by the Delaware River and its associated riparian corridor and wetlands, the NJDEP GIS database did not identify any Natural Heritage priority sites within one half mile of the Site. Because no COPECs are present at the CEA area, no further ecological evaluation is warranted. Baseline Ecological Evaluation PSEG Services CorporationSalem Generating Station Hancock's Bridge, New Jersey 6. References ARCADIS, 2005. Remedial Investigation Work Plan, PSEG Services Corporation, LLC Salem Generating Station. January. 2005.Delaware River Basin Commission (DRBC), 1996. Administrative Manual -PartIII: Water Quality Regulations. October. 1996.Hamill, N., and E. Demarest. 1997. Ecological risk assessment in NJDEP's Site Remediation Program: Conducting a baseline ecological evaluation. Site Remediation News. 9(1), Article 05, January.New Jersey Department of Environmental Protection (NJDEP). 2005a. WatershedManagement Area 1: Upper Delaware. May.(http://www.state.nj.us/dep/watershednegt/wmal info.htm)New Jersey Department of Environmental Protection (NJDEP). 2005b. Watershed Management Area 11: Central Delaware. May.(http://www.state.ni.us/dep/watershedm.t/wmal I info.htm)New Jersey Department of Environmental Protection (NJDEP). 2005c. Watershed Management Area 18: Lower Delaware. May.(lhtp://www.state.ni.us/dep/watershedmgt/wma 18 info.htiln) New Jersey Department of Environmental Protection (NJDEP). 2005d.
3.0 Sediment
Screening Values for Use in the Baseline Ecological Evaluation. May.(http://www.state.ni.us/dep/srp/regs/sediment/03 screen.htm)National Oceanic and Atmospheric Administration (NOAA). 1999. Screening QuickReference Table. September. RAIS. 2005. Risk Assessment Information System. Oak Ridge National Laboratory, Toxicology and Risk Analysis Section, Oak Ridge, Tennessee. The Delaware River Basin Collaborative Environmental Monitoring and Research Initiative (CEMRI). 2005.(http://www.fs.fed.us/ne/global/research/drb/basin.htmnl) Tables Table 1. Summary of Groundwater Sampling Results PSE&G Salem, Artificial Island, Salem, New Jersey.Sample ID Well X Well AX- Well AV Well AVD- Well AY Well AZ 112/13/041315/051 12/13/041 13/15/05 [ 3/15/05 112/13/041315/05 12/10/04 3/15/05 Semnivolatile Organic Compounds 2-Chlorophenol 4-Chloro-3-methyl phenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrophenol 4,6-Dinitro-o-cresol 2-Methylpherol 3&4-Methylphenol 2-Nitrophenol 4-Nitrophenol Pentachlorophenol Phenol 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(gh,i)perylene Benzo(k)fluoranthene 4-Bromopherlyl phenyl ether Butyl benzyl phthalate 2-Chloronaphthalene 4-Chloroaniline Carbazole Chrysene bis-(2-Chloroethoxy)methane bis(2-Chloroethyl)ether bis(2-Chloroisopropyl)ether 4-Chloropheflyl phenyl ether 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 2,4-Dinitrotoluene
2,6-Dinitrotoluene 3,3'-Dichlorobenzidine Dibenzo(a,h)anthracene Dibenzofuran Di-n-butyl phthalate Di-n-octyl phthalate Diethyl phthalate Dimethyl phthalate bis(2-Ethylhexyl)phthalate Fluoranthene Fluorene Hexachlorobenzene Hexaclorobutadiene Hexachlorocyclopentadiene Hexachloroethane Indeno(1,2,3-cd)pyrene Isophorone 2-Methylnaphthalene 2-Nitroaniline 3-Nitroaniline 4-Nitroaniline Naphthalene Nitrobenzene N-Nitroso-di-n-propylamine N-Nitrosodiphenylamine Phenanthrene Pyrene 1,2,4-Trichlorobenzene <5<5<5<5<20 <20<5<5<5<20 <20<5<5<5<2<2<2<2 <2<2<2<2<2<2<5<5<2<2<2<2 <2<2<2<2<2<2<2<5<2 <5<2<2<2<2<2<2<2<2<2<20<5<2<2<2<5<5<5<2<2<2<5<2<2<2<5<5<5<5<20<20<5<5<5<20<20<5<5<5<2<2<2<2<2<2<2<2<2<2<5<5<2<2<2<2<2<2<2<2<2<2<2<5<2<5<2<2<2<2<2<2<2<2<2<20<5<2<2<2<5<5<5<2<2<2<5<2<2<2<5<5<5<5<20<20<5<5<5<20<20<5<5<5<2<2<2<2<2<2<2<2<2<2<5<5<2<2<2<2<2<2<2<2<2<2<2<5<2<5 <2<2<2<2<2<2 <2<2<2<20<5<2<2<2<5<5<5<2<2<2<5<2<2<2<5.6 <5<5.6 <5<5.6 <5<5.6 <5<22 <20<22 <20<5.6 <5<5.6 <5<5.6 <5<22 <20<22 <20<5.6 <5<5.6 <5<5.6 <5 0.64 J 5.0<2.2 <2<2.2 0.95 J<2.2 <2<2.2 <2<2.2 <2<2.2 <2<2.2 <2<2.2 <2<2.2 <2<5.6 <5<5.6 <5<2.2 9.9<2.2 <2<2.2 <2<2.2 <2<2.2 <2<2.2 <2<2.2 <2<2.2 <2<2.2 <2<2.2 <2<2.2 <2<5.6 .<5<2.2 <2 0.71 J 2.7 J<2.2 <2<2.2 <2<2.2 .<2<2.2 <2<2.2 <2 1 J 1.4J 1.4 J 4.4<2.2 <2<2.2 <2<22 <20<5.6 <5<2.2 <2<2.2 <2 1.8 J 2.0<5.6 <5<5.6 <5<5.6 <5 3.9 4.3<2.2 <2<2.2 <2<5.6 <5<2.2 5.3 0.96 J 0.94 J<2.2 <2<5<5<5<5<20<20<5 <5<5<20<20<5<5<5 5.1<2 0.97 J<2<2<2<2<2<2<2<5<5 10<2<2<2<2<2 <2<2<2<2<2<5<2 2.7 J<2 <2<2 <2<2 1.4 J 4.7<2<2<20<5<2<2 2.3<5<5<5 4.6<2<2<5 5.6 0.97 J<2<5.3 <5<5.3 <5<5.3 <5<5.3 <5<21 <20<21 <20<5.3 <5<5.3 <5<5.3 <5<21 <20<21 <20<5.3 <5<5.3 <5<5.3 <5<2.1 <2<2.1 <2<2.1 <2<2.1 <2<2.1 <2<2.1 <2<2.1 <2<2.1 <2<2.1 <2<2.1 <2<5.3 <5<5.3 <5<2.1 <2<2.1 <2<2.1 <2<2.1 <2<2.1 <2<2.1 <2<2.1 <2<2.1 <2<2.1 <2<2.1 <2<2.1 <2<5.3 <5<2.1 <2<5.3 <5<2.1 <2<2.1 <2<2.1 <2<2.1 <2<2.1 <2<2.1 <2<2.1 <2<2.1 <2<2.1 <2<21 <20<5.3 <5<2.1 <2<2.1 <2<2.1 <2<5.3 <5<5.3 <5<5.3 <5<2.1 <2<2.1 <2<2.1 <2<5.3 <5<2.1 <2<2.1 <2<2.1 <2<5<5<5<5<20<20<5 <5<5<20<20<5<5<5<2<2<2<2<2<2<2<2<2<2<5 <5<2<2<2<2<2<2<2 <2<2<2<2<5<2<5<2<2<2<2<2<2<2<2<2<20<5<2<2<2<5<5<5<2<2 <2<5<2<2<2 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Table 1. Summary of Groundwater Sampling Results PSE&G Salem, Artificial Island, Salem, New Jersey.Sample ID Well X Well AX- Well AV Well AVD- Well AY Well AZ 12/13/0[ 13/15/051 12/13/04 1 1213/04131,5/5 3/15/05 12o1/15/05 12/10/04 3/15/05 Volatile Organic Compounds Acetone <10 <10 <10 <10 <10 <10 <10 <10 <10 NA Benzene, <1 <1 <1 <1 <1 <1 <1 <1 <1 NA Bromodichloromethane <1 <1 <1 <1 <1 <1 <1 <1 <1 NA Bromoform <4 <4 <4 <4 <4 <4 <4 <4 <4 NA Bromomethane <2 <2 <2 <2 <2 <2 <2 <2 <2 NA 2-Butanone (MEK) <10 <10 <10 <10 <10 <10 <10 <10 <10 NA Carbon Disulfide <2 <2 <2 <2 <2 <2 <2 <2 <2 NA Carbon Tetrachloride <1 <1 <1 <1 <1 <1 <1 <1 <1 NA Chlorobenzene <1 <1 <1 <1 <1 <1 <1 <1 <1 NA Chloroethane <1 <1 <1 <1 <1 <1 <1 <1 <1 NA Chloroform <1 <1 <1 <1 <1 <1 <1 <1 <1 NA Chloromethane <1 <1 <1 <1 <1 <1 <1 <1 <1 NA Dibromochloromethane <1 <1 <1 <1 <1 <1 <1 <1 <1 NA 1,1-Dichloroethane <1 <1 <1 <1 <1 <1 <1 <1 <1 NA 1,2-Dichloroethane <1 <1 <1 <1 <1 <1 <1 <1 <1 NA 1,1-Dichloroethene <1 <1 <1 <1 <1 <1 <1 <1 <1 NA cis-1,2-Dichloroethene <1 <1 <1 <1 <1 <1 <1 <1 <1 NA trans-l,2-Dichloroethene <1 , <1 <1 <1 <1 <1 <1 <1 <1 NA 1,2-Dichloropropane <1 <1 <1 <1 <1 <1 <1 <1 <1 NA cis-1,3-Dichloropropene <1 <1 <1 <1 <1 <1 <1 <1 <1 NA trans-1,3-Dichloropropene <1 <1 <1 <1 <1 <1 <1 <1 <1 NA Ethylbenzene <1 0.83 J <1 <1 <1 <1 <1 <1 <1 NA 2-Hexanone <5 <5 <5 <5 <5 <5 <5 <5 <5 NA 4-Methly-2-pentanone (MIBK) <5 <5 <5 <5 <5 <5 <5 <5 <5 NAMethylene Chloride <2 <2 <2 <2 <2 <2 <2 <2 <2 NA Styrene <5 <5 <5 <5 <5 <5 <5 <5 <5 NA 1,1,2,2-Tetrachloroethene <1 <1 <1 <1 <1 <1 <1 <1 <1 NA Tetrachloroethene 0.87 J <1 <1 <1 <1 <1 <1 <1 <1 NA Toulene <1 <1 <1 <1 <1 <1 <1 <1 <1 NA 1,1,1-Trichloroethane <1 <1 <1 <1 <1 <1 <1 <1 <1 NA 1,1,2-Trichloroethane <1 <1 <1 <1 <1 <1 <1 <1 <1 NA Trichloroethene <1 <1 <1 <1 <1 <1 <1 <1 <1 NA Vinyl Chloride <1 <1 <1 <1 <1 <1 <1 <1 <1 NA Xylenes (total) <1 <1 <1 <1 <1 <1 <1 <1 <1 NA Notes: ug/L Micrograms per liter (equivalent to parts per billion)2.3 Bold value indicates compound is above the method detection limit.< The compound was not detected at the indicated concentration. J Data indicates the presence of a compound that meets the identification criteria. The result is lessthan the quantitation limit but greater than zero. The concentration given is an approximate value.NA Not analyzed Well AX is a blind duplicate of Well X Well AVD is a blind duplicate of Well AV Table 2. Summary of Soil Sampling Results PSE&G Salem, Artificial Island, Salem, New Jersey.Sample ID D-2 (3.5-4.0) D-3 (3.5-4.0) D-4 (3.5-4.0) D-4 (9.0-9.5) D-5 (3.5-4.0) D-50 (3.5-4.0)Monitoring Well Location Well AW Well AV Well AY Well AY Well AZ Well AZ Sample Date 1118/04 11/8/04 11/8/04 11/8/04 11/9/04 11/9/04 Analyte (mg/kg)Petroleum Hydrocarbons <28 <29 <32 <29 <27 <26 Benzene <1 <1 <1 <1 <1 Bromodichloromethane <1 <1 <1 <1 <1 Bromoform <4 <4 <4 <4 <4 Bromomethane <2 <2 <2 <2 <2 2-Butanone (MEK) <10 <10 <10 <10 <1.0 Carbon Disulfide <2 <2 <2 <2 <2Carbon Tetrachloride <1 <1 <1 <1 <1 Chlorobenzene <1 <1 <1 <1 <1 Chloroethane <1 <1 <1 <1 <1 Chloroform <1 <1 <1 <1 <1 Chloromethane <1 <1 <1 <1 <1 Dibromochloromethane <1 <1 <1 <1 <1 1,1-Dichloroethane <1 <1 <1 <1 <1 1,2-Dichloroethane <1 <1 <1 <1 <1 1,1 -Dichloroethene <1 <1 <1 <1 <1 cis- 1,2-Dichloroethene <1 <1 <1 <1 <1 trans-1,2-Dichloroethene <1 <1 <1 <1 <1 1,2-Dichloropropane <1 <1 <1 <1 <1 cis-1,3-Dichloropropene <1 <1 <1 <1 <1 trans-1,3-Dichloropropene <1 <1 <1 <1 <1 Ethylbenzene <1 <1 <1 <1 <1 2-Hexanone <5 <5 <5 <5 <5 4-Methly-2-pentanone (MIBK) <5 <5 <5 <5 <5 Methylene Chloride <2 <2 <2 <2 <2 Styrene <5 <5 <5 <5 <5 1,1,2,2-Tetrachloroethene <1 <1 <1 <1 <1 Tetrachloroethene 0.87 J <1 <1 <1 <1 Toulene <1 <1 <1 <1 <1 1,1,1 -Trichloroethane <1 <1 <1 <1 <1 1,1,2-Trichloroethane <1 <1 <1 <1 <1 Trichloroethene <1 <1 <1 <1 <1 Vinyl Chloride <1 <1 <1 <1 <1 Xylenes (total) <1 <1 <1 <1 <1 Tentatively Identified Compounds (total) 4.2 J 27.1 Acetone 4.2 JN Chlorotrifluoroethene 20 JN 1,2-Dichloro-1,2,2-trifluoroethane 7.1 JN Freon 113 Notes: 0.87 Bold value indicates compound is above the NJGWQC standard mg/kg Milligrams per kilograms (equivalent to parts per million)< The compound was not detected at the indicated concentration. J Data indicates the presence of a compound that meets the identification criteria. The result is less than the quantitation limit but greater than zero. The concentration given is an approximate value.N Indicates presumptive evidence of a compound. This flag is only used for tentatively identified compoundswhere the indication is based on a library search NA Not analyzed Table 3. Comparison of Estimated Groundwater Concentrations to Surface Water Criteria PSE&G Salem, Artificial Island, Salem, New Jersey.Maximum Concentration Avarage Concentration Constituents Detected in Downgradient Wells in Downgradient Wells in Groundwater (a) (a) Log Kow (c) NOAA SQuiRTs(d)(ug/L) (ug/L) (ug/L),cenaphthene 5.1 1.87 3.92 520(0)Anthracene 0.97 1.01 4.45 300 (Carbazole 10 3.01 3.72 NA Dibenzofuran 2.7 2.36 4.12 NA Fluoranthene 1.4 1.09 5.15 16(g)Fluorene 4.7 1.84 4.18 300 (0 2-Methylnaphthalene 2.3 1.35 3.3 300 0 Naphthalene 4.6 2.09 3.86 620 (e)Phenanthrene 5.6 2.12 4.46 4.6(g)Pyrene 0.97 0.99 4.88 300 (Ethylbenzene 0.83 0.54 3.15 430 "1 Tetrachloroethene 0.87 0.54 3.4 450(g)Notes: ug/L = Micrograms per liter (equivalent to parts per billion)FCV = Final chronic value MIDEQ = Michigan Department of Environmental Quality NA Not Available (a) Includes samples collected from Well-X, Well-AV, Well-AY and Well-AZ.(b)(c)(d)(e)(f)(g)Includes samples collected from Well-X, Well-AV, WeII-AY and Well-AZ. Non-detects are assumed to be one half of the detection limit Risk Assessment Information System (RAIS), 2004.The values used from the NOAA SQuiRTs are as followed: The lower value between the chronic freshwater and chronic marine is used. If only one chronic value is listed, then it is used. If no chronic values are listed then the lower values between the acute freshwater and the acute marine criteria is used.Value used is NOAA SQuiRTs freshwater chronic criteria Value used is NOAA SQuiRTs marine acute criteria Value used is NOAA SQuiRTs marine chronic criteria Figures \~~A-- .-\I LEGEND..--PROPERTY BOUNDARYBLOW DOWN PIPING LIQUID "RAD" WASTE LINE SERVICE WATER PIPING CIRCULATING WATER OUTLET PIPING CIRCULATING WATER INLET PIPING STORM SEWER PIPING CATCH BASIN MANHOLE (STORM SEWER)SHEET PILE -EXTENDS FROM ABOVE THE WATER TABLE THROUGH THE KIRKWOOD FORMATIONSHEET PILE -DOES NOT EXTEND TO AN ELEVATION ABOVE THE WATER TABLE.AFST AUXILIARY FEEDWATER STORAGE TANK PWST PRIMARY WATER STORAGE TANK RWST REFUELING WATER STORAGE TANK NOTE: THE MEAN TIDAL LEVEL OF THE DELAWARE RIVER AT ARTIFICIAL ISLAND IS 0.11 FT (NAVD 1988)II jim---, ..J,.... ..DRAWN DATE PROJECT MANAGER DEPARTMENT MANAGER Io01M A -5/12/05 P. MDLIONIS A. ROBINSON 0 SOD LEAD DESGN PROF. CHECKED IT l00LAOU.T POTTER B. PIERCE© ]STATION LAYOUT_ _ j._U SCALE: 1"=300' PROJECT NUMBER DRAWNo NUMBER"RC.D I PSEG NUCLEAR, U-C NP000603.0001 1 STATION HANCOCK.S BRIDGE, .NEW JERSEY C,,i" WI ji -AFST:.. .. .. ..... CATCH BASIN 27 V APPROXIMATE LIMITS OF EXCAVATION-IS.-AG C,'1 .. .-< .SCALE: 1"=600'LEGEND: WETLANDGRAVEL AND STONE CONCRETE ASPHALT: .: SANDY AREA -DIESEL FUEL UNDERGROUND PIPING.... -PROPERTY BOUNDARY BLOW DOWN PIPING LIQUID "RAD" WASTE LINE X CHA1NLINK FENCE SERVICE WATER PIPING.-l. CIRCULATING WATER OUTLET PIPINGa CIRCULATING WATER INLET PIPING...... ...... STORM SEWER PIPING CATCH BASIN MANHOLE (STORM SEWER)SHEET PILE -EXTENDS FROM ABOVE THE WATER TABLETHROUGH THE KIRKWOOD FORMATION SHEET PILE -DOES NOT EXTEND TO AN ELEVATION ABOVE THE WATER TABLE.,"N'N MONITORING WELL DIESEL FUEL UNDERGROUND PIPING PROPERTY BOUNDARY BLOW DOWN PIPING LIQUID "RAD" WASTE LINE CHAINLINK FENCE SERVICE WATER PIPING CIRCULATING WATER OUTLET PIPING CIRCULATING WATER INLET PIPING STORM SEWER PIPINGCATCH BASIN Qi MANHOLE (STORM SEWER)SHEET PILE -EXTENDS FROM ABOVE THE WATER TABLE THROUGH THE KIRKWOOD FORMATION SHEET PILE -DOES NOT EXTEND TO AN ELEVATION ABOVE THE WATER TABLE.\II& till \4/4~1 N h ZN '4" ~K N rrX \ -w oYu-'#tr AREA O SITE LAYOUT SCALE: 1"=600'LEGEND. \\a PHOTOGRAPH NUMBER AND DIRECTION WELL-AZO MONITORING WELL 5--------- DIESEL FUEL UNDERGROUND PIPING .,\---- PROPERTY BOUNDARY\\ .BLOW DOWN PIPING----- LIQUID "RAD" WASTE UINE 0 \"\ \.,\\ B' ~CHAINLINK FENCE... "... SERVICE WATER PIPING \ "\CIRCULATING WATER OUTLET PIPING I "CIRCULATING WATER INLET PIPINGSTORM SEWER PIPING 7 ( CATCH BASIN B MANHOLE (STORM SEWER)SHEET PILE -EXTENDS FROM 3/4'N (ABOVE THE WATER TABLE THROUGH j ,THE KIRKWOOD FORMATION 2'N, SHEET PILE -DOES NOT EXTEND TO AN ELEVATION ABOVE THE WATER TABLE.CE -a P I DRAWN DATE PROJECT MANAGER DEPARTMENT MANAGER M. 0, WASILEWSKI 5/12/05 P. MO IONIS A. ROBINSON 01 1 MAP LEAD DESIGN PROF. CHECKED 0,50 fffM S POTTER B. PIERCE C) SCALE: 1"=50' k 1 AOKNCE.LPROJECT NUMBER DRAWING NUMBER 0 2 u A I PSEG NUCLEAR, U-CNP06 .014SALEM GENERATING STATION NPOO0bU5.UII1 4 HANCOCK'S BRIDGE, NEW JERSEY I Attachment A New Jersey Department of Environmental Protection Geographic Information System Database Search Results rARCADIS Salem Generation Station Hancock's Bridge, New Jersey Legend E Diesel Leak Location" 1/2 Mile Buffer Linear Wetlands Streams[ Site Boundary Land Use/Land Cover SAGRICULTURE I BARREN LAND FOREST URBAN WATER VWETLANDS -N E Lakes 0 325 650 1,300 1,950 2,600 Feet Attachment B Photo Log Attachment B Photo LogSalem Generation Station Hancock's Bridge, New Jersey Photograph 1 Radiation yard south of the fuel handling building. The radiation yard is covered by sand, gravel and hard packed dirt. Grasses grow sparsely in the yard.Photograph 2 View from well au, looking north at a radiation area..Ground is covered by concrete, sand and hard packed dirt. Grasses grow sparsely in this area. Attachment B Photo LogSalem Generation Station Hancock's Bridge, New Jersey Photograph 3 Well au, site of soil excavation, and Spill Buster oil and waterseparation system. Photograph 4 View of oil containment building from the south. Asphalt and gravel cover the ground. Attachment B Photo Log Salem Generation Station Hancock's Bridge, New Jersey Photograph 5 View from the fuel handling building looking west. Asphalt, concrete and gravel cover the soil.Photograph 6 View from gate outside ofthe diesel leak area, looking west. Asphalt covers the soil. Attachment B Photo Log Salem Generation Station Hancock's Bridge, New Jersey Photograph 7 View from well ad, looking northwest. Soil is covered by gravel, sand and asphalt.Photograph 8 View from well aj, looking west. Soil is covered by gravel, sand and asphalt. Attachment B Photo Log Salem Generation Station Hancock's Bridge, New Jersey Photograph 9 View from well au, looking east between the fuel handling building and the diesel generating building.Photograph 10 View from well aw looking south. Soil is covered by asphalt in the foreground and gravel in the back.Miscellaneous containers are against a gate and rest on top of gravel.}}