ML092890036
| ML092890036 | |
| Person / Time | |
|---|---|
| Site: | Sequoyah  |
| Issue date: | 10/13/2009 |
| From: | Cleary T Tennessee Valley Authority |
| To: | Barton B Office of Nuclear Reactor Regulation, State of TN, Dept of Environment & Conservation, Div of Water Pollution Control |
| References | |
| TN0026450 | |
| Download: ML092890036 (28) | |
Text
Tennessee Valley Authority -
Post Office Box 2000 Soddy Daisy, Tennessee 37384-2000 Timothy P. Cleary Site Vice President Sequoyah Nuclear Plant October-13, 2009 .
Ms, B. Paulette Barton State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement.& Compliance Section 6 th Floor, L&C Annex 401 ChurchStreet Nashville, Tennessee 37243-1534 Ms, Barton:.
2009 DISCHARGE MONITQRING REPORT - QUALITY ASSURANCE (DMR-QA) STUDY 29 PROVIDER-GRADED TEST RESULTS - FINAL REPORT Please find enclosed'the provider-graded test results for the 2009 DMR-QA Study 29 Laboratory Performance Evaluation obtained by TVA Sequoyah Nuclear Plant (SQN) and supporting laboratories as required by NPDES Permit TN0026450. Upon review of the DMR-QA 29 final report,...
there were two analyte results that were-evaluated as "Not Acceptable." The two "Not Acceptable" analyte results have been entered into the TVA corrective action program and investigations have been initiated to identify the problems at both laboratories in order to implement adequate corrective actions. Remedial samples have also been ordered for analysis to confi'rm that identified problems are corrected. A completed and signedcorrective action report will be submitted by.December 4, 2009. If you have any questions or need additional information, please contact Ann Hurt at (423) 843-6714 or Stephanie Howard at (423) 843-6700 of Sequoyah's Environmental staff.
Sincerely, Timothy P. VCleary Site Vice President Sequoyah Nuclear Plant Enclosure cc (Enclosure)
Mr. Ray Terhune. U.S. Nuclear Regulatory Commission US EPA Region IV ATTN: Document Control Desk SESD/MTSB/QAS Washington, D.C. 20555 980 College Station Road Athens, Georgia 30605-2720 Chattanooga Environmental Assistance Center Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013
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0MB Control No. 2080-0021 Approval expires 12/313/2010 United States V`EPAUnited Slates Envýiom en-ý al Pmtpoleton ENVIRONMENTAL PROTECTION AGENCY Agency Washington, D.C. 20460 Laboratory DMR-QA Evaluation Study 29 Laboratory Performance Evaluation Office of Enforcement and Compliance Assurance (These data are collected under the authority of the Federal Water Pollution Control Act.)
NPDES Permittee Data Report Form State NPDES Permit Attention: Follow the instructions on the previous
- Permit Extension Due October 16,2009 - page to complete this form and submit data for TAH Number evaluation.
62&(,a '/5o Permittee name .r - / -ss ---' *// 16/ 4 1 _-7" / r/ - . / 4,/
.I4A/:
Current Permittee mailing address , - / .- 2O Cityý ( ZVL2 _- Z " State TA Zip Code 35 s9*,/1 Phone Number" .cO/4 -6:'- FAX'Number - -/3 7/00 e-mail 17-V/.v',".
For DMR-QA Study 29, conducted in 2009, the Permittee ensured that their laboratory(s) performing the required analyses:
Submitted Complete and Accurate Data Received a Graded Report by Received PT Samples by August 31,2009 September 21, 2009 Yes No Yes X No Yes I No Certification by Permit Holder or Authorized Representative I *... .(as per 40 C.F.R, Section 122.22 - see instructions.) - .
I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted.
Based on my inquiry of the person or persons-who manage the system,..or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. Each reported value was produced'from a single analyticalirun using the-analytical system that routinely performs thbse analyses to produce compliancemonitoring data required under our National Pollutant.Discharge Elimination System (NPDES) permit.
Neither I nor any of my subordinates compared our results.with results from independent analyses conducted by us or any other laboratory.beforewe reported our results to the U.S.EPA. l am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations, Name of Certifying Official T/-/ 'V. dZ!-7* Ti tl e 5,~A Signature ..,:?rzA? P-&-% Date - "-- '
Address, phone ntmber and e-mail of cetifying official orj/required if different from babove.
Address Phone No.
city State Zip Code e-mail EPA 6400-01 Rev. 03-09. Previous editions are obsolete. 14
0MB Control No. 2080-0021 Approval expires 12/31/2010 United States AEPA United Slates Environmental Proz,;clion ENVIRONMENTAL PROTECTION AGENCY Agp*ncy Washington, D.C. 20460
'Laboratory DMR-QA Evaluation Study 29 Laboratory Performance Evaluation Office.of Enforcement and Compliance Assurance (These data are collected under the authority of the Federal Water Pollution Control Act.)
P"te 7 --
name - ---e */ y;//_ /7,, , / State NPDES Permit No. Peimit Extension Identification of all CHEM, MICRO and WET laboratories who did analyses for this permit -
Lab Analysis.
Name of Laboratory ....-- Address of Laboratory *Code U.S. EPA Lab. __ Check box(es) that apply
_ _ Lab Type*
CHEM., MICRO WET
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Lab Cmec Tyesy lF ,,,
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- Lab. Types: C =Commercial F =Federal G Locail Government 1 -Industrial 0 Other S =State If you need additional space, please make a copy of this page for additional laboratories.
i5 EPA 6400-01 Rev. 03-09. Previous editions are obsolete.
ERA A Waters Company Permittee Name: TVA - Sequoyah Permit Number: TN0026450 EPA Lab Code: TNO0003
- Nuclear Plant.
Chemistry/Microbiology Analyte Checklist WP Study 174 Laboratory's Graded Result Test Required Acceptable Not Acceptable Analoe Test / Method (Corrective Action Required)
Minerals Alkalinity as CaCo3 EPA 310.1 E5 [E jJ EPA 310.2 0l [] .l SM2320B EQ [J Q Chloride EPA 300.0 Q [] []
EPA 300.1 .l [] El EPA 9056 E .
EPA 9056A El' [E] ]
SM 4110B [F]
NQ E Conrductivity at,250 C EPA 120.1 El I] El SM2510B " [] [] El Fluoride EPA 300.0 . * [] El EPA 300.1 5 []
EPA 9056 [] El El EPA9056A El [.] 0" SM 4110B .. El [F] -l Potassium. -
EPA200.7 El [] El EPA6010B E * [60 El EPA6010C , "3 ] El
]
Sodium EPA 200.7 El [I] El EPA 6010B El [F] El EPA 60100 El El Sulfate '*
EPA 300.0 0l .[] El EPA 300.1 LE El EPA 9056 El [] El EPA 9056A [] El EEl SM 4110B 10El [] El Total Dissolved Solids at 1801C EPA 160.1 El []. El SM2540C . XI El 0
TotalSolids atl105"C C EPA 160.3 El [.] El SM2540G El . El SM2540B - [] El
A Waters Company Hardness Non-Filterable Residue (TSS)
EPA 160.2 Q -
SM2540D ' f]J Calcium EPA 200.7 0 Q[
EPA 6o10B .l "1 EPA 6010C Q" []
1-1 Magnesium EPA 200.7
EPA60100C' 0J SM2340B . E" Total Hardness asCaCO3 EPA 130.1 El .r- El EPA 200.7 []. El EPA 6010B "l [] El EPA 60100 OC [] El SM2340B - El [] .
SM2340C nl [x1 Fl pH pH EPA 150.1 El [] El EPA 9040B El -x- El SM4500H+ B El Exl El Settleable Solids Settleable Solids EPA 160.5 El [] El SM2540F El -[ .- El Solids Concentrate No n-Filterable Residue T.SS)
TotalDissolved Solids at 1801C*
Total.Solids at 1051C _.___*
Solids Non-Filterable Residue.(TSS)
Total Dissolved Solids at 1801C Total Solids at 1051C Simple Nutrients.
Ammonia as N:
EPA 350.1 ,l El SM4500NH3 G El " El Nitrate + Nitrite as N EPA353.2 .. E"- *"
SM4500N03- F . [] ..
Nitrate as N.
EPA 300.0 El El EPA 300.1 El . [ . l EPA 9056 El [] E .
EPA 9056A "l [] El SM 41 10B El [Ej El ortho-Phosphate as P EPA 365.2 . 0l (Xl -l SM4500P E E El Complex Nutrients Total Kjeldahl Nitrogen EPA 351.2 .E l] El SM4500Norg C *E [] El Total phosphorus as P EPA 365.1 El EPA 365.2 *E [] El EPA 365.3- El E El
ERA A Waters Company Nitrite Nitrite as N EPA 300.0 *l Fx EPA 300.1 El 0
.EPA 9056 0l
[] El EPA 9056A . rQ E*
SM 4110B1. El [] .E Demand BOD EPA 405.1 E El SM5210B El [] []
CBOD SM5210B "[ [I .
COD EPA 410.4 El El SM5220D [' ,I 0l TOC EPA 415.1 0l- E*-
EPA 9060 0l. [0] .l EPA 9060A 0l E.
SM5310B 03 IX! El SM5310C El .
Oil & Grease Concentrate Oil & Grease (Gravimetric) __________ __________________________
Oil & Grease Oil & Grease (Gravimetric)
EPA 1664A SepF Q .
EPA9070ASepF 0 ..
-SM 5520B ". E I--. - l Oil &.Grease (Infrared) _ _" __ __" _ _ __ __ __ _
Trace Metals Aluminum.
EPA 200.7 El EPA 6010B EX EPA 6010C El Antimony EPA 200.7, El EPA 200.8 El~ E0 EPA 6010B El Eli EPA 60.10C El El EPA 6020 11 11 El EPA 6020A El El Arsenic2 EPA 200.7 El El EPA 200.8 El 11 El EPA 60100 El C1 EPA 6010C El EPA 6020 .. El El!
EPA 6020A Barium El El!
EPA 200.7 EPA 200.8 191 EPA 6010B-E.F EPA 60110C El EPA 6020 EPA 6020A Beryllium EPA 200.7 El El EPA 200.8 El EPA 6010B IXI ElI EPA 6010C Ml EPA 6020
A Waters Company EPA 6010C El Cadmium EPA 200.7 EPA 200.8 EPA 6010B
EPA 6020A Chromium LI EPA 200.7 El EPA 200.8 LI El EPA 601OB 0I EPA 6010C LI El EPA .6020* LI EPA 6020A LI El Cobalt EPA 200.7
.I EPA 200.8 LI EPA 60108 LI EPA 6010C LI EPA 6020 EPA 6020A Copper LI LI EPA 200.7 EPA 200.8 EPA 6010B KEPA 6010C
EPA 6010B EPA 60100O LI1 Lead LI EPA 200.7 LI'
]
EPA 200.8 1-1 EPA 6010B LI EPA 6010C ,L-EPA 6020 LI D
EPA 6020A Manganese EPA 200.7 LI EPA 200.8 LI
. LI. LI EPA 6010B EPA 6010C LI LI EPA 6020' LI LI EPA 6020A° "
[
LI Molybdenum LI . 0I
- EPA 200.7
. LI[
EPA 200.8 LI LI[ LI EPA 6010B i~I EPA 601 0C LI[ LI EPA 6020 LI[
LI 0
EPA 6020A LI Nickel LI EPA 200.7 LI LI EPA 200.8 LI LI LI EPA 6010B EPA 6010C EPA 6020 EPA 6020A Selenium gPP 9flf 7 r-' I--1
A Waters Company EPA 6020 EPA 6020A El Silver EPA 200.7 El EPA 200.8 0l EPA 6010B EPA 6010C 0
EPA 6020 0 EPA 6020A Strontium. El EPA 200.7 EPA"6010B El EPA 6010C Thallium 11 EPA 200.7 C1 EPA 200.8 EPA 6010B El El EPA 6010C 11 EPA 6020 EPA 6020A Vanadium' El EPA 200.7 11 EPA 200.8 El EPA 6010B 0l EPA 6010C 0l EPA 6020
.0 EPA 6020A Zinc 11 EPA 200.7 1:1 EPA 200.8 11 EPA 60108 .11
, [-
EPA 6010C 171 E.*
EPA 6020 .. l[
EPA 6020A Mercury..
Mercury EPA 245.1 0D EPA 7470A El Hexavaleent Chromium Hexavalent Chromium' EPA 218.6. '. [1] "
EPA 7166A ' El [] El EPA 7199 11 .
SM3500Cr C" 1.
SM3500Cr D 'El Elj. El SM3500Cr E " El SM3500CrB 20th . . ,
Turbidity Turbidity EPA180.1 -
SM2130B El El Total Cyanide Cyanide, total EPA 335.4 .
EPA 9012B . El EPA335.2(CLP-M) 5 . E[
SM4500CN E *_ _ _ __ E0 _
Total Phenolics (4-AAP)
Phenolics, total EPA,'420.1/420.4 El El "
EPA 420.2 0 El EPA 9066 El . El SM5530D _ __ __ ___
A Waters Company WasteWatRTm Coliform MicrobEm Total Coliforms (MF)
SM9222B 11 191 0 Fecal Coliforms (MF)
SM9222D 5 [] 5 E.coli (MF).
Total Coliforms (MPN)
Fecal Coliforms.(MPN)-
SM 9221CC 5 SM9221EE 5 E.coli (MPNI __"_"_"
I x(ý 1-0 Prinq:1 Date Signature/Title I V IUse a separate checklist for EACH lab used
A Waters Company Permittee Name: TVA -Sequoyah Permit Number: TN0026450 EPA Lab Code:.. NC01 230 Nuclear Plant WET Organisms/Test Conditions/End Points Checklist DMRQA Study 29 Laboratory's Graded Result Analyte Not Acceptable Number Organisms,/ Conditions Test(Cretv End Points Required Acceptable (Corrective Required)
Fathead minnow (Test Code 13) 0754 48Hr., Acute, Non-Renewal, 250 C, MHSF LC50 " EJ C1 Fathead minnow (Test Code 14).
0755 48Hr., Acute, Non-Renewal, 250C, 20% DMW LC50. 0 .-0]
Fathead minnow (Test Code 15) 0808 7-day Short term Chronic, Daiiy Renewal, MHSF 1C25 (ON) Growth Q El 11 0808 7-day Short term Chronic, Daily Renewal, MHSF 0IC25 (ON) Growth r x El 0810 7-day Short term Chronic, Daily Renewal, MHSF NOEC (ON).Growth '. El El 0756 7-dayShort term Chronic, Daily Renewal, MHSF . NOEC Survival EQ 51 E5 Fathead minnow (Test Code 16) 0812 7-day Short term Chronic, Daily Renewal, 20% DMW IC25 (ON) Growth E] 0l E 0814 7-day Short term Chronic, Daily Renewal, 20% DMW NOEC (ON) Growth El 13 El 0759 7-day Short term Chronic, Daily Renewal, 20% DMW NOEC Survival El El E Ceriodaphnia dubia (Test Code 19) 0764 48Hr., Acute Renewal,25°C, MHSF LC50 El E E1 l1 Ceriodaphnia dubia (Test Code 20) 0765 48Hr., Acute Renewal, 25'C, 20%.DMW " LC50 El I El Ceriodaphnia dubia (Test Code 21) ...
0767 7-day Short term Chronic, Daily Renewal, MHSF IC25 Reproduction El El El 0767 7-day Short term Chronic, Daily Renewal, MHSF IC25 Reproduction . L El.
0768 7-day Short term Chronic, Daily Renewal, MHSF NOEC Reproduction El El El 0766 7-day Short term Chronici'Daily Renewal, MHSF NOEC Survival El El El Ceriodaphnia dubia (Test Code 22) 0770 7-day Short term Chronic, Daily Renewal, 20% DMW IC25 Reproduction El El El 0771 7-day Short term Chronic, Daily Renewal, 20% DMW NOEC ReproduJction El El El 0769 7-day Short term Chronic, Daily Renewal, 20% DMW NOEC Survival El E1 El Daphnia magna(Test Code 32) 0788 48Hr., Acute, Non-Renewal, 25°C, MHSF LC50 l l El Daphnia'pulex (Test Code 38) 0794 48Hr., Acute, Non-Renewal, 250 C, MHSF LC50 El El El Mysid.(Test.Code 42)..
0798 48Hr., Acute, Non-Renewal, 250C, 40 FSW LC50 El El El Inland Silverside (Test Code 45) 0825 7-day Short term Chronic, Daily Renewal, 40 FSW IC25 (ON) Growth El El El 0826 7-day Short term Chronic, Daily Renewal, 40 FSW NOEC (ON) Growth El El . El 0824 . 7-day Short term Chronic, Daily Renewal, 40 FSW NOEC Survival El El El Mysid (Test Code 43) 0816. 7-day Short.term Chronic, Daily Renewal, 40 FSW IC25 (ON)Growth El El[]
0818 7-day Short term Chronic, Daily Renewal, 40 FSW NOEC (ON) Growth El El El 0799 7-day Short term Chronic, Daily Renewal, 40 FSW NOEC Survival El El El Inland silverside (Test Code 44) 0803 48Hr., Acute, Non-Renewal, 25 c,'40 FSW LC50 El El El Sheepshead minnow (Test Code 46) 0804 48Hr., Acute, Non-Renewal, 250C, 40 FSW. LC50 El El El Sheepshead minnow (Test Code 47) 0820 7-day Short.term Chronic, Daily Renewal, 40 FSW IC25 (ON) Growth El El El 0822 7-day Short term Chronic, Daily Renewal, 40 FSW NOEC (ON) Growth El El El 0805 7-day Short term Chronic, Daily Renewal, 40 FSW NOEC Survival El El El f S ) TOýj Print Nlm.-
Print I ~
N~m~ I i~'YJ~~JLy
ERA A Waters Company Permittee Name: TVA - Sequoyah Permit Number: TN0026450 EPA Lab Code: TN00999 Nuclear Plant Chemistry/Microbiology Analyte Checklist DMRQA Study 29.
Laboratory's Graded Result Sd Test Required Actable Not Acceptable Analyte Test / Method Tccepae (Corrective Action Required)
Minerals' Alkalinity as CaCO3 Chloride Conductivity at 25 0C Fluoride Potassium Sodium -'
Sulfate:*
Total Dissolved Solids at 180C0 Total Solids at 105'C _ .___ ,--_"_'_"" ___" ___" _"___"
Hardness Non-Filterable Residue (TSS)
Calcium Magnesium .
Calcium Hardness as CaCO3 Total Hardness as CaCO3 -___ _:_____ _"_"___*__
pH pH SM4500H+ B E]
Settleable Solids' Settleable'Solids "_ _ ___ _
Solids Concentrate -
Nan-Filterable Residue (TSS)
Total Dissolved Solids at 180C00 Total Solids at 105'C*
Solids Non-Filterable Residue (TSS)
Total Dissolved Solids at 180 0C Total Solids at_1050C -_._ __. " . : * "
Simple Nutrients Ammonia as N Nitrate -+ Nitrite as N Nitrate as N ortho-Phos~hate as P _ _ _"_"_"_-_ '"__
Complex Nutrients Total Kjeldahl Nitrogen Total phosphorus'asP "P...._._ _-
Nitrite Nitrite as N Demand B0D CBOD COD Oil & Grease Concentrate Oil & Grease (Gravimetric) ._.-__
Oil & Grease Oil & Grease (Gravimetric)
Oil & Grease (Infrared) .
IA A Waters Company Trace Metals Aluminum Antimony Arsenic Barium Beryllium Boron, Cadmium Chromium, Cobalt Copper Iron Lead Manganese Molybdenum Nickel Selenium Silver, Strontium Thallium
.Vanadium Zinc Mercury .
Mercury' v_______ ___________________________r_____-__
Hexavalent Chromium Hexavaleni Chromium . ....
Turbidity Turbidity .... ._"_.. ... _*_...._"_"_"_ _"_.,
Total Cyanide Cyanide. total ___"_"___"_"_"_"
Total.Phenolics (4-AAP)
Phenolics. total ________-_"_'_"___"________
Total Residual Chlorine Total Residual Chlorine SM4500CI G , -
WasteWatRm Coliform MicrobETM Total Coliforms (MF)
Fecal Coliforms (MF)
"E.coli (MF) ' ... " * * :
Total Coliforms (MPN)
Fecal Coliforms (MPN)
E.coli_(MPNI -_"_ __......_*__ _ _ _-_*_..
Print Name / 1 Date Use a separate checklist for EACH lab used SignaturefTitle
A Waters Company Stephanie A Howard TVA - Sequoyah Nuclear Plant PO Box 2000
. Mailstop: SB-2A-SQN Soddy-Daisy, TN 37384-2000 LA ýý4 r:id Fina ~ rt I
4-,
r K
3 ~
DMR-QA. Study Open Date: 05/04/09 Close. Date: 08/31/09 Report Issued Date: 09/20/09.
ERA A Waters Company September 21, 2009 Stephanie A Howard TVA - Sequoyah Nuclear Plant PO Box 2000 Mailstop: SB-2A-SQN Soddy-Daisy, TN 37384-2000 Enclosed is your final report for ERA's DMR-QA 29 Proficiency Testing study. Your final report includes an evaluation of every result submitted to your NPDES permit number by your contract laboratory(ies).
Your report also contains the USEPA checklists for all of the laboratories that have reported data to your NPDES permit number. Please note that reports. weresent as required to both the USEPA DMR-QA office and your state or regional DMR-QA coordinator.
If your contract laboratory(ies) have any "Not Acceptable" evaluations for the DMR-QA 29 study a letter of corrective action listing the required remedial samples is attached for your convenience. If you have a "Not Acceptable" evaluation on your report, ERA recommends that you contact your DMR-QA coordinator for their corrective action requirements.
Thank you for your participation in ERA's DMR-QA 29 Proficiency Testing study. If youhave any'.
questions, please contact myself orERA's Proficiency Testing Group, at.1-800-372-0122.
Sincerely, Shawn Kassner Jay R. McBurney Proficiency Testing Manager Quality Program Manager attachments smk 6000 West 54th Ave., Arvada, CO .80002 800-372-0122 fax (303) 421-0159 www.eraqc.com
ERA A Waters Company DMRQA-29 Definitions & Study Discussion Study Dates: 05/04/09 - 08/31/09
- Report Issued: 09/20/09 DMRQA Study Definitions DMRQA Study Discussion The Reported Value is the value that the laboratory reported ERA's DMR-QA 29 Proficiency Testing study has been to ERA. reviewed by ERA senior management and certified compliant with the requirements of.the USEPA's National Standards for The ERA Assigned Values are compliant with the most Water Proficiency. Testing Studies Criteria Document current USEPA/NELAC FoPT tables. A parameter not added (December 1998), and the criteria contained in the most to the standard is given an Assigned Value of "0" per the current NELAC FoPT tables.
guidelines contained in the USEPA's Criteria Document and NELAC standards. ERA's DMR-QA-29 study standards were examined for any anomalies. A full review of all homogeneity, stability and The Acceptance Limits are established per the criteria accuracy verification data was completed. All analytical contained in the most current USEPA/NELAC FoPT tables, or. verification data for all analytes met the acceptance criteria ERA's SOP for the Generation of Performance Acceptance contained in the USEPA's National Criteria Document for LimitsTM as applicable. Water ProficiencyTesting Studies, December 1998, and the criteria contained in the most current NELAC FoPT tables.
The Performance Evaluation: The data submitted by participating laboratories was also examined for study anomalies. There were three anomalies observed during the statistical review of the data. If your Acceptable = Reported Value falls within the laboratory received the Solids Concentrate sample, catalog Acceptance Limits. #4030, the Inland Silverside (Test Code.44), catalog
- WET018, or the Inland Silverside (Test Code 45) sample, catalog #WET013, these anomalies are addressed-on the Not Acceptable =Reported Value falls outside the following page.
Acceptance Limits.
ERA's DMR-QA 29 study reports shall not be reproduced except in their entirety and not without the permission of the No Evaluation = Reported Value cannot be evaluated. participating laboratories. The report must not be used by-the participating laboratories to claim product endorsement by any agency of the U.. S. government.
Not Reported = No Value reported. . The data contained herein are confidential and intended for your use only.
The Method Description is the method the laboratory reported If you have any questions or-concerns regarding your to ERA. assessment in ERA's DMRQA Proficiency Testing program, please contact Shawn Kassner, Proficiency:Testing Manager, or Curtis Wood, Director of Regulatory Affairs and Business
.Development, at 1-800-372-0122.
MET MR
AWaters Company Study: DMRQA-29 NPDES Permit#: TN0026450 Laboratory Name: TVA - Sequoyah Nuclear Plant Page 1 of 13
DMRQA-29 Final Complete Report A Waters Company NPDES Permit #: TN0026450 ERA Customer Number: T203302 Permit Holder: Stephanie-A Howard Report Issued: 09/20/09 Principal Environmental Engineer Study Dates:-. 05/04/09 - 08/31/09 TVA - Sequoyah Nuclear Plant P.O. Box 2000 Mailstop: SB-2A-SQN Soddy-Daisy, TN 37384-2000 423-843-6700 Performance Reported Assigned Acceptance Units Method USEPA Lab Anatyte Evaluation Value Value Limits Description Code I Study.
Minerals Alkalinity as CaCO3 Acceptable 34.7 36.1 30.5.- 42.5 mg/L EPA 310.1 TN00003 WP174 Alkalinity as CaCO3 A.cceptable 32.6 36.1 30.5-42.5 mg/L EPA 310i2 TNOoo03 WP174 Alkalinity Chloride as CaCO3 Acceptable Acceptable
-18." . 34.7 - 36.116 - 30.5 99.8 -.42.5
-- 132 mg/L mg/L . SM2320B EPA-300.. TNO00033 TN0 WP174 P.....
74 Chloride Acceptable 118. 116 99.8-132 mg/L EPA 300.1 TN00003 WP174 Chloride ------Acceptable 118. 116 116I 99......
.8.. -132. E8 9- TN003 --WP174 Chloride Acceptable 118. 116 99.8-132 mg/L EPA 9056A TNO0003 WP174 Chloride Acceptable 118. 116 99.8-132 mg/L SM 4110B - TNO0003 WP174 Conductivitydat 250 " Acceptable 511. 508 1" 9457-559 mhos/cm EPA 120.A TNO0003 WP174 Conductivity at 25 0C Acceptable 511. 508 457-559 pmhos/cm EPA 120.1 TNO0003 WP174 0
Conductivity at 25 C Acceptable 511. 508 457-559 pmhos/cm SM2512B.1 TNO0003 WP174 Fluoride...... Acceptable 3.24 .mg/L 3.45 2.90-4.01 E . - I...3. 17 Fluoride Acceptable 3.24 3.45 2.90-4.01 mg/L EPA 300.1 TNO0003 WP174 Fluoride Acceptable 3.24 3.45 2.90 - 4.01 mg/L EPA 9056 TNO0003 WP174 Fluoride .. A l..e... ........ 3 45 2. ... .. ..... E A
........... 6A. ........ .
Fluoride Acceptable 3.24 3.45 2.90- 4.01 .. mg/L ...... 9056 F~uorid... ": ....*... .. ...........
2...-4:0 EPA TNO0003 WP174
'.....cc pt........ 24 ..... 45... mg/L..... "B..... TN 000---------4" Potassium Acceptable 17.8 17.9 14.6-21.4 mg/L EPA 200.7 TN00003 WP174 Potassium Acceptable 17.2 17.9 14.6 -21.4 mg/L EPA 6010B TNO0003 WP174 I . . i -
. -.. . -. .- .... ..-., ý.
Potassium - - - - - - - - - -
Acceptable - --.
17.2 . .... . . . . . ..
17.9 . ý. ...
14.6-21.4. . .....
mg/L . . . . . . . ...
EPA -I. ....
6010C . . . . .
TNO0003 . . . .. . .
WP174 . .
- Acceptable 89.6 90.0 76.4 - 103 mg/L EPA 200.7 TN00003 WP174 Sodium Acceptable " 85.6 90.0 76.4 - 103 mg/L EPA 6010B TNO0003 WP174 Sodium Acceptable 85.6 90.0 76.4- 103 mgI/L EPA 2010C TN0003 WP174 Sulfae - -- . Acceptable-Acetal 12.1 .. 13.3 9.89 1. -1IL-E PA 3000--- -P.7 Sulfate Acceptable 12.1 913.3 9.89 6 16.4- mg/L EPA 300.1 TN0TN0003 WP174 Sulfate Acceptable 12.1 13.3 9.89-16.4 0 mg/L EPA 9056 TNO0003 WP174 Sulfate Acceptable 12.1 13.3 9.89- 16.4 . mg/L EPA 9056A TNO0003 WP174 Sulfate TolftalDsovdSoisae8 Acceptable Acceptable 12.1 308.1 13.3 2909217-634
~-----f---I -----
Totalfassoleds at d 8C Acceptable 337.. 302 629-1363 mg/L SM241 0. TN-0003 WP174 Total iSolids at 1805C Acceptable 337. 302 262.-338 .mg/L SM-2540G TN00003 WP174 Total Solids at 1050 C Acceptable 337. 302 262-338 mg/L SM2540B TNO0003 WP174 Page 2 of 13 M All analytes are included in ERA's A2LA accreditation. Lab Code: 1539-01
DMRQA-29 Final Complete Report A Waters Company NPDES Permit #: TN0026450 ERA Customer Number: T203302 Permit Holder: Stephanie A Howard Report Issued: 09/20/09
. Principal Environmental Engineer Study Dates: 05/04/09 - 08/31/09 TVA - Sequoyah Nuclear Plant P.O. Box 2000 Mailstop: SB-2A-SQN
- Soddy-Daisy, TN 37384-2000 423-843-6700.
Analyte Performance Reported Assigned Acceptance Units Method USEPA Lab Study Evaluation Value Value Limits Description Code Hardness Non-Filterable Residue (TSS) Not Acceptable 65.0 43.3 32.8-50.1 mgIL EPA 160.2 TN00003 WP174 Non-Filterable Residue (TSS) Not Acceptable . 65.0 43.3 32.8-50.1 mg/L SM2540D TNO0003 WP174 Calcium Acceptable 64.5 66.0 59.0 - 74.8 mg/L. EPA 200.7 TNO0003 WP174 Calcium . Acceptable 64.3 66.0 59.0- 74.8 mg/L EPA 6010B TN00003 WP174 Calcium- Acceptable 64.3 66.0 59.0 -74.8 mgIL EPA 60100C TNO0003 ,WP1 74 Magnesium Acceptable 21.7 21.7 18.6-24.9 m/ P 0. N00 P7
------------------ I------------- EP 200.7-
-N---- WP1----
74---
Magnesium Acceptable 22.2 , 21.7 18.6- 24.9 mg*L EPA 601OB TNO0003 WP174 Magnesium Acceptable 22.2 21.7 18.6 -24.9 mg/L - EPA 6010C TNO0003 WP174 Calcium Hardness rdne s ass CaCO3 saicum'H CO
-- -- Acceptable ce bl-"
-- ... i161.
0". . --165 6 -" -- - 18 148
- - 187 - . "-....m
-187 -- mg/L EPA 200.7 EA.0.B..... TNO0003 003"" WP174
"*P'7 Calcium Hardness as CaCO3 Acceptable 160. 165 148- 187 mg/Li EPA 6010B TNO0003 WP174 Calcium Hardness as CaCO3 Acceptable 160. 165 148- 187 mgIL EPA 60100C TNO0003 WP174 Calcium Hardness as CaCO3 Acceptable 161. 165 148-187 mgL SM2340B TNO0003 WP174 Total Hardness as CaCO3 Acceptable 255. .254 224-,289 mg/L EPA 130.1 TNO0003 WP174 Total Hardness as CaCO3 Acceptable 250. 254 224 - 289 mgIL EPA 200.7 TNO0003 WP174 Total Hardness as CaCO3. Acceptable 252.' 254 224 -289 mg/L EPA'6010c TNO0003 WP174 Total.Hardness as CaCO3 .. Acceptable 252 . 254 --- 289 . mg/L EPA 63010 TN 3 .WP174
-224 Total Hardness as CaCO3 Acceptable 250. 254 224,-289 mg/L SM2340C TNO0003 WP174 Total Hardness as CaCO3 Acceptable 256. 254 224 -289 mg/L SM2340B -TNO0003 WP174 pH Acceptable 7.59 7.53 7.33-7.73 S.U. EPA 150.1 TNO0003 WP174 pH- Acceptable 7.59 7.53 7.33 -7.73 S.U
-040B j EPA 00oooo3 WP174 pHAcceptable 7.59 7.53 7.33 -7.73 S. U. SM4500H+ B TNO0003 WP174 pH .. .I Acceptlable . .8.51,-"I- 8.53 8.33-8.73 S.U . SM4ý00OH,- B [ TNo0999 DMRQA29 Settleable Solids .. _" _- _ _- ' _ " -_
SettleableSolids Acceptable 35.0 36.0 28.7-46.1 mL/L EPA 160.5 TN.0003 WP174 ISettleable Solids Acceptable 35.0 36.0 28.7-6.1 mL"L SA1. I Simple Nutrients .. _.
Ammonia as N Acceptable 11.3 11.0 " 8.15 - 13.7 . 1mg/L EPA 350.1 TNO0003 WP174 Ammonia as N Acceptable 11.3 11.0 8.15 - 13.7 mg/L SM450ONH3 G TNO0003 . WP174 Nitrate + Nitrite as N Acceptable 11.7 13.5 11.0 - 15 .7 rng/L - EPA 353.2 TN00003 WP7 Nitrate.+ Nitrite as N . Acceptable 11.7 13.5 11.0-15.7 .glL SM4500N03-F TN00003 WP174 Nitrate as N Acceptable 13.7 .13.5 10.5-163 mg/L EA 300 .TN00003 WP174 Nitrate as N Acceptable 13.7 13.5 10.5- 16.3 mg/L EPA 300.1 TNO0003 WP174 Nitrate as N Acceptable 13.7 13.5 . 10.5- 16.3 mg/L. EPA 905 TN.0003 - WP174
.-------------------- - E--
Nitrate as N Acceptable Acceptable 13.7.
13.7 13.5 13.5 10.5 10.5 -- 16.3 16.3 -mg/ mg/L,L - EPA 9056 EPA1O9056A TNO0003 WP174, WP174 Nit-rate-als.N.
ortho-Phosphate aslP Acceptable 2.2 2.10 1.69-2.53 -mg/ I .L EPA 365.2 TNO0003 WP174 ortho-Phosphate as P Acceptable . 2.2 2.10 1.69-2.53 mg/L SM4500P E TNO0003 WP174 Page 3 of 13 All analytes are included in ERA's A2LA accreditation. Lab Code: 1539-01
DMRQA-29 Final Complete Report A Waters Company NPDES Permit #: TN0026450 ERA Customer Number: T203302 Permit Holder: Stephanie A Howard Report Issued: 09/20/09 Principal Environmental Engineer .Study Dates: 05/04/09 - 08/31/09 TVA - Sequoyah Nuclear Plant P.O. Box 2000 Mailstop: SB-2A-SQN Soddy-Daisy, TN 37384-2000 423-843-6700 Analyte Performance Reported Assigned Acceptance Units Method Descri tion USEPA Lab CodEPAa Study Evaluation Value. Value Limits DeUnitstiMethod Complex Nutrients Total Kjeldahl Nitrogen Acceptable 9.16 9.03 6.03-11.8 mg/L EPA 351.2 TNO003 WP174 Total Kieldahl Nitrogen ...Acceptable 9.16 9.03 6.03-11.8 mg/L SM45O0Norg C TNO0003 WP174 Total phos-phorus as P Acceptable 2.38 2.08 1-66 --2.55 mg/L. EPA 365.1 TN0--03 WP174 Total phosphorus as P Acceptable 2.38 2.08 1.66 -2.55 mg/L EPA 365.2 . TN0003 WP174 Total phosphorus as P Acceptable 2.38 2 08 1.66-12.55 mg/L EPA 3650. TNO0003 WP174 Total phosphorus as P . Acceptable .2.38 2.08 1.66"-2.55 mglL .EPA30P 5 E TNO0003 WP1 74 T -otal phosphorus as -P-Acceptable -- 2. 38 2.08 1.66-2.55 ---- mg/ ,L - S M4500P F- '.T'NOOO3' WIP 174 Nitrie-as- Acceptable 1.44 1-.418 1.16-1.655 - - mgL - - EPA4300.0 F TN--- ---- W P1 .74 Nitrit ahshrs N s Acetbe 14P.1 11616 gL P 0. TNO0003 WP7 Nitrite as N Acceptable 1.44 1.41 1.16-1.65, mg/L. EPA 90560 TNO0003 WP174 Nitrite as N Acceptable 1.44 1.41 1.16-1.65 mg/L EPA 9056A TNO0003 WP174 Demand - ---- . -. "... I. . .-
BOD . Acceptable 68. 70.2 35.41- 105 mg/L EPA 405.1 TNO0003 WP174
........... .. Accep e 6. 70.2 354 -- 5 ......... ........... T ........
OBOD CDite as N Acceptable 1.63.3.-
4' 60.5 1131 27.1 1.8 --1.3 93.9 ""mglL mg/L SM5210B EPA 41046 TN00003.
TNOo003 WP174 CoD.......I Acceptable 1..- 113 8.7-131 1I.. M20- TNoooo3 P14 NitOe N.--cceptable A 4. 44. 3.6-51.65 mgL EA 41.1 ' TNOOOO3", WP174 TOO
- Acceptable 49.2 44.7 37.3-151. mg/L SM5210B .jTNO0003 WP174 TOC Acceptable 49.264.-73 35-5.64 0 mg/L EPA 9060 TNOooo3 WP174 T.....C ..
- Ac-eptab - ---4 .2- 4. --------
7 3. -
--....- . . .. E A. - - TN.....
. - - 74--
TOO" Acceptable 49.2 44.7 373-51.6 mg/L SM5310B TNO0003* WP174 Oil &Grease -____________
COil& Grease(Gravimetric) . Acceptable 39. 32.0 18.2-41.1 mg/L EPA 1664A1SepF TNO0003 WP174 Oill& Grease (Gravimnetric)
Oil&OGrease(Gravimetric)
Acceptable Acceptable l 38.
39.
32.0 32.0 18.2 -41.1 18.2-41.1 rn.g/L mg/L
- IEPA'SEPA 1G64A' SPEI T0000A 5070DSepF TNO0003
-, vvP174-WP174 TOil&Grease (Gravimetric) Acceptable 4938. 32.0 18.2 -411 mg/L EPA 70A'SE.1 TN00003" WP174 Oil& Grease (Gravimetric) .. Acceptable 39.* 32.07.' 18.3 -41.1 mg/L - SM 5320B TNOOOO3-r WP174 Page 4 of 13 All analytes.are included in ERA's A2LA accreditation. Lab Code: 1539-01 A
DMRQA-29 Final Complete Report
-Q,ýERA I *A Waters Company NPDES Permit #: TN0026450 , ERA Customer Number: T203302 Permit Holder: Stephanie A Howard Report Issued: 09/20/09 Principal Environmental Engineer Study Dates: 05/04/09 -.08/31/09 TVA - Sequoyah Nuclear Plant
--- P.O. Box 2000
- , Mailstop: SB-2A-SQN
-..:ýSoddy-Daisy, TN 37384-2000 423-843-6700 Analyte Performance Evaluation Reported Value Assigned Value Acceptance Limits Units.I Dethod io oSPdeL Description Code Study Trace Metals Aluminum Acceptable 355 265-448 pgfL EPA 200.7 TNO0003 "419..
WP174 Aluminum . Acceptable 375. 355 265-448 pg/L EPA 60106B TN00003 WP174 Aluminum Acceptable 375. 355 265-448 . pg/L . EPA 601 OC TNO0003 WP174 Antimony Acceplable 216. .208 138-254 pg/L EPA 200.7 TNO0003 WP174 Antimony Acceptable 202. 208 '138 - 254 pg/L EPA 200.8 TNO0003 WP1 74 Antimony Acceptable 203.
9208 138--254 pg/L EPA 601*.B TNO0003 WP174 Antimony Acceptable 203. 208 138 -254 pqg/L EPA 60100 TNO0003 WP174 Antimony ---- ------------
Ac- ---------------------------------- pL- --- EPA.6020 ...O----------
................. ceptable , 197. 208 138 -254 p/ P 00 TO03 W17 Antimony Acceptable . 197. 208 138 -254 pg/L _EPA 6020A -TNO0003 WP1174 Arsenic Acceptable 708. 723 "-608-608- 846 846. pgIL EPA 200.7 TNO0003 WP174 A'rsenic ~........ "I.... OO3 I' 'PI"4
.....84 ......
Arsenic Acceptable 745. 723 -A--
Arsenic
....Acceptable
... ....... *688. 723 608-846 pgL EPA 601068 TNO0003
......WP174 Arsenic Acceptable . 688. 723 608 - 846 pg/L EPA 601 Oc TNOooo3 i WP174 Arsenic" " ........
tbe ...... 69"..... :7 3...... 6-ce 8 46 ..... I~l6021
-........ T ....
0 0 3 [ " ...... 1 4..
Arsenic Acceptable 699. 723 608 - 846 pg/L EPA 6020O TNO0003 WP174 Arsenic . Acceptable 699. 723 6081- 846 pg/L EPA 6020A TN00003 WP174 Barium Acceptable 957. 145 125-8163 pg/L- EPA 200.8 TNO0003 WP174 Barium Acceptable 150. 145 125-163 _g/L EPA 6200. TNO0003 WP174 Barium ............... ... cceptable . .....45 125-163 g/L EPA 600 TN 3 WP174 Barium Acceptable 143. 145- - 125- 163 pg/L--- ---EPA Beryll um... Accptble - 46. - - -- - 466 - -52
-396--- -- EPA 60200 200.7
-- TNO0003 WP174 Barium Acceptable 470. 145 325-163 pg/L EPA 200.O .TNO0003 WP174 Bearlium Acceptable 453. 0 .463-563 .. pg/L .EPA 60106 TNO0003 WP174 Bearium . Acceptable 45. . 466 2396-526 pg/L EPA 60200 TNO0003 WP174 Bearylium Acceptable 43. 466 396 -526 pg/L EPA 6020A TNO0003 WP174 Beryllium Acceptable 493. 466 396 -526 pg/L EPA 6020A TNO"OO3 WP174 Boron Beryllium..
Boronlium Acceptable Acceptable 480. .
453 826. 836 46 866 . 39694.-975 9-2 369.-59 . pg/L g/L pg/L EPA 6010 EPA 200.7 EPA"6010B TNO0003
.C TNO0(003 TNO..3 .. WP174 WP174 Boronlli"um'"" Acceptable pg/L EPA 60200 WP;174
. .. 39...64-""5267...-----.
- 82. 4836 694 -975 ýg/L-
. ..EPAP,6020Ao*
0i c i T-N;o0003 Boerny ... .. * .... Acceptable 493.. 466
- 2. .... TNO0003 WP174 oo........... . . . . . . . . ;.... .....
.p* ...** ----
- .... *,o0 Cadmiumn Acceptable 602. -63 . 523-6964 pg/L EPA 200.7 - " TN00003 WP174 Cadm .......... -.. Accepabl.e A....... 6.." 6. 5 6 - ........ E 2.....
FPage 5 of 13 All analytes are included in ERA's A2LA accreditation. Lab Code:1539-01
DMRQA-29 Final Complete Report A Waters Company NPDES Permit #: TN0026450 ERA Customer Number: T203302 Permit Holder: Stephanie A Howard Report Issued: 09/20/09 Principal Environmental Engineer Study Dates: 05/04/09 - 08/31/09 TVA - Sequoyah Nuclear Plant
-.P.O. Box 2000
.- :Mailstop: SB-2A-SQN
- 'Soddy-Daisy, TN 37384-2000 423-843-6700 Analyte S Performance Evaluation Reported Value Assigned Value Acceptance Limits Units* Method Description USEPACodeLab Study Trace Metals (Continued)_
Cadmium. Acceptable 620. 613 523-696 ptg/L EPA 6010B TNO0003 WP174 Cadmium Acceptable.. 620--- &-23-696-3 pg/L EPA 6010C TNO00003 WP174 Cadmium--- . --- 590.- 613-- 5-23-696 -- g;-- E PA 600--
-- Noooo3 w-P74 Cadmium Acceptable 590. 613 523 -696 pg/L EPA 6020A TNO0003 WP174 Chromium Acceptable 968. 3 826-1070 52- pg/L . EPA 200.7 - TNO0003 WP174 Chromium Acceptable 944. 947 826- 1070 pg/L EPA 200.8 TNO0003 WP174 Chromium Acceptable 971. 947 826-10701 ,
a....g/L ... 'EA60cOB
. TNO000- WP1-74" Chromium 'Acceptable . 971. 947 , 826- 1070 pg/L EA61C TNO0003 WP1 74 Chromium Acceptable 926. 947 826-1070 pg/L EP.A 6020 . TNO0003 .WP174 Chromium Acceptable 926. 947 826 - 1070 .pg/L EPA 6020A TNO0003 WP174.
Cobaltiu Acceptable Acetal
-Cb ... 792.
802 787 787-- 692 692---
-882 882--- pg/L - EPA EP 602008 - -. TN00003 20._NOO3 WP1774 W17 1igIL Cobalt
- - Acc-e-p-t-able 8... 1 78748. 69 -
-88.2....L - ------ - EPA 61.... .. 4 Cobalt Acceptable 848. 787 692-882 pg/L EPA 6010C TNO0003 WP174 Cobalt Cobalt . Acceptable
... Acceptable.I.. . 778.
778. 787 787 62 --.............
692 882.... . ......pg/L -.. E 6010A EPA 2 TNO0003 WP174
. 262 Co ..
Coppert "Acceptable' 2758. ......
262 236-290
- 29 '
.... g/L p/L .. [. EEP.;#
...A......
- Aa200.7 -TN0-200.803 Toooo3 .... P-74 wP 74 Copper Copper
... . Acceptable ce.a~e Acceptable 265.
265.
.6.-
262 262
." _.3 9._ ..... pg/L
- 236-290 236-290
- g -..
pg/L
- I..-
00 0 -.I TNO0003 EPA 601013 EPA 6010C
~ ~od.. "W TNO0003
....F7- -
WP174 WP174 Copper Acceptable 265. 262 . 236 - 290 pg/L EPA 6020 TNO0003 WP174 Copper . Acceptable 7-265. 262 2836 -290 pg/L EPA6*2o*A TNOooo3 WP174-Iron* ~..... : A....
cceptable"-1"490. ] 1440" 1270-162-0" ... g/L ... I EPA20°0.7 T°°°N1OwO74 iron .... . .... Acceptable 1...I500. -1440 I 1270-1620 p*gIL* EPA. 6*.0108 i-TN00003 ... W'P174" Iron Leader . Acceptable Acceptable 1500.
598 265. 1-440 594 1...--
270--1620 51 23-2668 g....
pg/L EA0 EPA...601 OC TTNO0003
. .... w.
WP1.P174..
74 Lead . Acceptable - 612. 594 518--668. pg/L EPA 200.7 TN0003 WP174 Lead Acceptable 587. 594 5182-668 pg/L EPA 200.8 TNO0003 WP174 L4ea Acceptable 659. 54 51-668-2 pg/L EPA 6010B TNO0003 WP174 Lead . Acceptable 565. 594 6 518- 668 pg/L EPA 6020 TNO0003 WP174 Leadr Acceptable 565. 594 518-668 pg/L
" Page6of13 All analytes are included in ERA's A2LA accreditation. Lab Code: 1539-01 I ý__'4ý)
DMRQA-.29 Final Complete Report A Waters Company NPDES Permit #: TN0026450 ERA Customer Number: T203302 Permit Holder: Stephanie A Howard Report Issued: 09/20/09 Principal Environmental Engineer Study Dates: 05/04/09 - 08/31/09 TVA - Sequoyah Nuclear Plant P.O.- Box 2000 Mailstop: SB-2A-SQN S-. Soddy-Daisy, TN 37384-2000 423-843-6700 Analyte " Performance Reported Assigned Acceptance Units Method USEPA Lab
- Evaluation.. Value Value Limits Description Code Study Trace Metals (Continued)
Manganese Manganese .. Acceptable Acceptable 1100.
1130. 1100 1100 988-988- 1220. 1220 pg/L pg/ EPA 6010B EPA 200.8 TNO0003 TN003 WP174
-WP74 Manganese Acceptable 1130. 1100 988-1220 pg/L EPA6010B TNO0003 WP174 Manganese Acceptable 1120. 1100 988-1220 pg/L EPA 6020 TNO0003 WP174 Manganese -. Acceptable 1120. 1100 988 -"1220 pg/L EPA 6020A TNO0003 WP174 Molybdenum Acceptable 195*. 193 160-224 " pg/L EPA 200.7 TNO0003 WP174 Molybdenum " " Acceptable .. 99. 193 160-224 p...g/L . EPA.200.8 . TNO0003 .WP174 Molybdenum_ Acceptable 190. 193 160-224 pg/L EPA 6010B TNO0003 WPI74 Molybdenum Acceptable 190. "pg/L 193 160-224 EPA 6010C TNO0003 WP174 Mye 193 160--224 -A. EPAC6020
-g/L I N00003 - WP174 Molybdenum Acceptable 197. 193 160 -224 pg/L EPA 6020A TNO0003 WP174 Nickel Acceptable 386.* 371 " 331 - 417 pg/LU EPA 200.7 TN00003 WP174.
Nickel , Acceptable 391. " 371 33,1 - 417 pg/L EPA 200.8 TN00003 WP174 Nickel - Acceptable -378. 371 331 -417 pg/L EPA 6010 -TN00003 WP174 Nickely.... . . .. . . .. . . .. .I..
Acceptable
. ..:1 .
..... . I. ....
.378.
37-1 331-417 . .
pg/L... .
EPA 60100 TNO0003 WP174 Nicklybdel m .eptable Acc 376. 371 331 -417 pg/L EPA 6020 TNO0003 WP174
. . ... .. . . .. .. . . . . . . . . . . . .. . . . . ... ... .. . -. .. - - - - - - . -. -. . - . .- .- . - - -- - - - - t. . . . . .. . .. -.. - -. -. - .- .- - .- . - .- .- - .--- .--
Nickel Acceptable 376. 371 331 - 417 pg/L -... EPA 6020A TNO0003 WP'174 Selenium Acceptable 1131. 1150 915 - 1330 pg/L EPA 200.7 TNO0003 WP174 Selenium Sikelenu I.- -. - - - - -- ...... . . ......... t.. Acceptable Acceptable
... . . .. . *t. :. ....1100.
I. .
130. .. 1150 115
. . .. .I 915-915-13
.. ........ . 1330
. . . . . pg/L pg/L
... . *.. EPA200.8 EPA . . . ... . -1N00003 6010B . .....
TNO0003 .. - . .... WP174' WP174.. .. .
Selen-iu-m .. Acceptabe . 1030. .1150
...... . 915-10 selenium Acceptable 1030. 11 915-4133 .WP174 pg/U EPA 6020 TNO00 S-- - - - - ---- ---I--cc.a - - ---.- e.......!0......l --.......................
0.... 33 -179 0 9 . : _-.-- o0 -........
P7 Selenum -Accetabl 1070 115 9151330 pg/U EPA 6020A TN00~003- 9A -
Silvel Acceptable 167. 37156 133 -417 pg/L EPA 60200 TNO0003 WP174 Silveriu- Acceptable 1550.- 1156 1 133- 17 pg/L - KkQ--.- WP174-
.. . . . ... .. .. . .. .. . . . .. . - -- -- - -- -- - -- - -- - - --I- --
Silver *" _ Acceptable 156.
150. 156
- 331-- 179 133 pg/L pg/U EPA 60200 6010.7B TN00003
-. 003 WP174 Silverle Acceptable 1.50. 113-179 pg/U EPA .20.7TNOooo3 WP1;74 Silverni Acceptable 150. 156- 133-1790 pg/L EPA 6020A. - TN-0003.- WP174 -
Strontium " Acceptable 1324.. 135 1 215-150 pg/L EPA 200.71 TN0003 WP174 Strontium Acceptable . 117 1310 . 112- 150 pg/L EPA 60108 TNO0003 WP174 Strontium Acceptable .117. 131 1125-1350 pg/L EPA 6020C TNO0003 WP174 Page 7 of 13 All analytes are included in ERA's A2LA accreditation. Lab Code: 1539-01 0ý[
A F& DMRQA-29 Final Complete Report
_Q_ýERA.
A Waters Company NPDES Permit #: TN0026450 ERA Customer Number: T203302 Permit Holder: Stephanie A Howard Report Issued: 09/20/09 Principal Environmental Engineer Study Dates: 05/04/09 - 08/31/09 TVA - Sequoyah Nuclear Plant.
P.O. Box 2000 Mailstop: SB-2A-SQN
-Soddy-Daisy, TN 37384-2000 423-843-6700 Anal'e - Performancev Reported Assigned Acceptance Units Method USE Lab Study Evaluation Value Value Limits Description Code Trace Metals (Continued)
Thallium Acceptable 700. 711 583 - 846 pg/L EPA 200.7 TN00003 WP174 Thallium. Acceptable 707. 711 583 - 846 pg/L EPA 200.8 TNO0003 WP174 Thallium Acceptable 689. 711 583-846 -pg/L EPA 6010B TNO0003 WP174
Z: ..------------- - L --- --------------
EPA-----.. TN- - -P174 Thallium Acceptable 689. 711 583 -846 pglL EPA 6010C TNO0003 WP174 Thallium Thallium. 'Acceptable Acceptable 683.
683. 711 711 583 -846 583-846 pgL pg. L EPA 60AOA EPA 6020 I TNO0003 WP174 WP174 Vanadium Vanadium - --- -- Accept--
--- ble -
Acceptable 959.-61-84 963..- 961 842---- 1070 1070 --------
pg/L - - 200.78 EPA - - - - - -
TNO0003 WP174 Vanadium Acceptable 955-.- :1 070 2-1 .EP ---- 60--08-- i ------*3 ---
Vanadium Acceptable 955. 96.1 842-1070 pg/L EPA 6010. TN00003 WP174 Vanadium Acceptable 913. 961 842- 1070 pglL EPA 6020B TNO0003 WP174 00 3 Vanadium Acceptable 913. 96"1 842- 1070 pg/L. EPA 60 ... -C TS " WP 174 zinc Zinc - -.- -- ---- -- - -- - - A..
cceptable-
.. . . 57
--591... - 6 19 619- - 53- ..
53-73-gL 713-.. . . - .EEPA A 60
.. 2007
..0 . TN-ooo3 N O OP WP174.7 Znc . .m Acceptable 5913. 69 8531-713 pg/L EPA 6020. TNO0003 WP174 Zincadi -.- Acceptable Accept ,able 913..
'5647. 619 5314-7130
.531 -713 pg/L EPA 6010A IEPA6200.7 - TNO0003 WP174 Zinc Acceptable 641. 619 531 -713 pg/L EPA 6020A0. TN00003 WP174 Mercury _ Accptbl 591. 619 531 1 "713 ....
Merury - . ........ ..... Acceptable . 7.3 1.. 3.7 . 8.43- 18.5 WP174 iMercury Acceptable l 172 6 13.7 J 843- 18. pgcL IEPA76oA j TNOOOO3 J WP174 Hexavalent Chromium ,-. .. .. ..
Hexavalent Chrmium' Zi-cxavaent Chromim Acceptable Acceptable 392*.
764.
61386 3861 312 -7455 531-45513 pg/L pgL 1 EPAEPA 218.6 6**0A TNO0003 TNO0003 WP174 WP174 Hexavalent Chromium . Acceptable
- 392. " 386 312-455 I gL" EPA 7199 TNO0003 . WP174 Hexavalent Chromium Acceptablee 392. 386. 32.-55 pgL SEA 7340CrAC TNO0003 WP*1*747 Hexavalent Chromium Acceptable 376. 386 31-2-455 I g/L SM35000rD TN00003 WP174 Hexavalent Chromium Acceptable, 392. . 386 312 -455 pg/L PSA35OOCr E.6 TNO03 .1WP174 Hexavalent Chromium Acceptable 376. 386 312 -455 - pg/L SM3500CrB 20th TNO0003 WP174 Turbidity .- ....... ......... .... ... . . . I .... _- - - - I. .
HTurbidity Chromium Acceptable 8.30 8.24 693-937- NTU EPA 1809 TNO0003 WP174 Turbidiy .... ......... Acceptable 8.30 J 8.24 6.93-9.37 s213oB-.
.NU TN 3--- .W74 Total Cyanide ...- ____. __________________-___ ___ ___
Cyanide, total Cyanialeet C "
- om.iu -Acceptable Acceptable . 0.846 0.2846 0
_0719 0719 . I"0_450 -00988__
0.50-40.988 I mg./L g/LoA : .. EPA 9*°01 335.4".. TN00003K TN!0°°3 _I WP174'_14IL Cyanide total-C Acceptable 0.846 0.719 0.450-0.988 3 mg/L "MA350)C - TNO0003 WP174 Cyanide, toial um Acceptable 0.846 0.719 10.450-0988 mg/L SM450OCN E .TN00003 -WP174 Page 8 of 13 All analytes are included in ERA's A2LA accreditation. Lab Code: 1539-01
._QERA DMRQA-29 .Final Complete Report A Waters Company NPDES Ptermit #: TN0026450 ERA Customer Number: T203302 Permit Ho'Ider: Stephanie A Howard Report Issued: 09/20/09 Principal Environmental Engineer Study Dates; 05/04/09 - 08/31/09 TVA - Sequoyah Nuclear Plant
-P.O.. Box 2000 Mailstop: SB-2A-SQN Soddy-Daisy, TN 37384-2000 423-843-b6UU.
Analyte Performance Reported Assigned Acceptance Units Method USEPA Lab Study Evaluation Value Value Limits Description Code Total Phenolics(4-AAP) .... ... _
Phenolics, total Acceptable 2.08 1.78 0*985- 2.58 mg/L /EPA 420.1/420.4 TNO0003 WP174 Phenolics, total Acceptable 2.08 1.78 0.985-2.58 mg/L - EPA 420.2 TNO0003 WP174 Phenolics, total . table Accep 2.08 1. 8 0.985 - 2.58 mgIL I EPA 9066 TN00003 WP174 Phenolics, totala Acceptable . 2.08 1.78 0.985 - 2.58 mg/L SM5530D TNO0003 WP1 74 Total Residual Chlorine Total Residual Chlorine Acceptable 0.85 0.922 1.15 mg/L EPA 330.5 TNO0003 WP174 Total Residual Chlorine Acceptable 0I85 0.922 0.665 - 1.15 m.ngL SM4500CI G TNO0003 WP174 LTotal Residual Chlorine Not Acceptable " 1.30 1.99"- 1.43"--2.46 mg/L .. ISM4500CI G - TNo0999 D DMROA29
.. Page 9 of 13 All analytes are included in' ERA's A2LA accreditation. Lab Code: 1539-01
A Waters Company Study: DMRQA-29 NPDES Permit #: TN0026450 Laboratory Name: TVA- Sequoyah Nuclear Plant,
- Page 10 of 13 6i**"\
AcC~FmTW~ r,Y-J,
-Y
j6iM DMRQA-29 Final Complete Report
_QERA A Waters Cormpany NPDES Permit#: TN0026450 ERA Customer Number: T203302 Permit Holder: Stephanie A Howard Report Issued: .. 09/20/09
.Principal Environmental Engineer Study Dates: 05/04/09 - 08/31/09 TVA - Sequoyah Nuclear Plant P.O. Box 2000
- Mailstop: SB-2A-SQN Soddy-Daisy, TN 37384-2000 423-843-6700.
Analyte Performance Reported Assigned Acceptance Units Method USEPA Lab Study:
Evaluation* Value Value Limits* Description Code Waste WatRTM Coliform MicrobETM Total Coliforms (MF) . Acceptable 230. 402 153-1050 CFU/1OOmL SM9222B TNO0003" WP174 Fecal Coliforms (MF) Acceptable 170. 180 . 28.0- 1170 CFU/IO0mL _ SM9222D--- -TNO0003- - W01741 Fecal Coliforms (MPN) Acceptable 500. 406 70.1 --2350 MPN/1OOmL SM 9221 C TNO0003 WP174 Fecal Coliforms (MPN) .. Acceptable . 500. 40.6 70.1 -2350 MPN/1 OOmL SM9221-E TNO0003 WP174
.. Page 11 of 13 All analytes are included in ERA's A2LA accreditation. Lab Code: 1539-01
ERA A Waters Company Study:, DMRQA-29 NPDES Permit #- TN0026450 Laboratory Name: TVA- Sequoyah Nuclear Plant Page 12 of 13 A
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- p. I DMRQA-29 Final Complete Report A Waters Company NPDES Permit #: TN0026450 ERA Customer Number: T203302 Permit Holder: Stephanie A Howard Report Issued: 09/20/09 Principal Environmental Engineer Study Dates: 05/04/09 - 08/31/09 TVA - Sequoyah Nuclear Plant
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-PO O. Box 2000
- --....Mailstop: SB-2A-SQN.
Soddy-Daisy, TN 37384-2000 423-843-6700, Test End Point Performance Reported Assigned Acceptance Method Description USEPA Lab Study EdoitEvaluation "Value.% Value % *Limits % Code Std Fatheadminnow (Test Code 14) 48Hr., Acute, Non-Renewal, 25° C, 20%DMW Potassium chloride ILC50 Acceptable 1 46.7 1 52.5 26.0 79.0. I EPA 2000 TN00003 DMRO A29 Fatheadminnow (Test Code 15) 7-day Short term Chronic, Daily Renewal, MHSF Ammonium phosphate dibasic.
l025 (ON) Growh Acceptable 51.0 45.0 15.1 -74.8, EPA 1000 I NC01230 IDMRoCA291 Fatheadminnow (Test Code 16) 7-day Short term Chronic,-DailyRenewal, 20% DMW Potassium chloride IC25 (ON) Growth- - Acceptable 29.3 36.3 12.4-60.1 EPA 1000 1TN00003 DMRQA29 NOEC (ON) Growth -Acceptable .25 .0 25.0 12.5- 50.0 EPA 1000 TNO0003 DMRQA29 NOEC Survival Acceptable 25.0 25.0 12.5 - .0 EPA 1000 TNOOOO3 DMRQA29, Ceriodaphniadubia (Test Code 20) 48Hr., Acute Renewal, 25 0 C, 20% DMW Potassium chloride ILC5o I Acceptable' 17.7' 28.1 1<6.25- 61.3 EPA 2002 TNOOO3 DMRQA29 Ceriodaphniadubia (Test Code 21) 7-day Short term Chronic, Daily Renewal; MHSF Potassium chloride IC25 Reproduction Acceptable 131.4 1 30.2 12.4-48.1 EPA 1002 NC0-1230 DMROA29 Ceriodaphniadubia (Test Code 22) 7-day Short term Chronic, Daily Renewal, 20% DMW Potassiumchloride 1025Reproduction- - I Acceptable 19.9 16.3 <6.25 -26.9 EPA 1002 TNO0003 [.DMRQA29 NOEC Reproduction Acceptable . 12.5 12 .5 6.25-25.0 EPA 1012 . .N.0003 DMRQA29 NOEC Survival IAcceptable 12.5 12.5 6.25 -25.0 .EPA 1002 TNO0003 IDMRQA29
. Page 13 of 13 All analytes are included in ERA's A2LA accreditation. Lab Code: 1539-01 if