ML073300641
| ML073300641 | |
| Person / Time | |
|---|---|
| Site: | Vogtle |
| Issue date: | 09/28/2006 |
| From: | Godfrey J Southern Nuclear Operating Co |
| To: | Cown J Office of Nuclear Reactor Regulation, State of GA, Environmental Protection Div |
| References | |
| 017-007D(L)(I), EV-06-2237 | |
| Download: ML073300641 (153) | |
Text
Southern flillclear Operating Company, Inc, SOUTHERN'\\.
COMPANY File: E.03.41 Log: EV-06-2237 September 28, 2006 FEDERAL EXPRESS VOatle Electric Generating Plant Landfill #3 Solid Waste Permit No. 017-007D(L)(I)
Mr. Jeff Cown Program Manager - Solid Waste Management Program Georgia Environmental Protection Division 4244 International Parkway, Suite 104 Atlanta, GA 30354
Dear Mr. Cown:
Pursuant to EPD Solid Waste Rule 391-3-4-.14, and in accordance with the Plant Vogtle Landfill #3 approved landfill groundwater monitoring program, Southern Nuclear is submitting the June, 2006 semi-annual groundwater monitoring report. This report was prepared for Southern Nuclear by the Dextra Group and was completed in September, 2006. Statistically significant increases over background were indicated for several analyzed parameters in GWA-7, GWC-13 and GWC-14 at Landfill #3. In accordance with Rule 391-3-4, Southern Nuclear will place a notice in the landfill operating record within 14 days of submittal of this report. The notice will indicate which constituents have shown statistically higher concentrations compared to the background wells.
Based on previous detections of mercury in several wells during Appendix II sampling, Southern Nuclear will continue to perform analysis for mercury in all Landfill #3 wells during the routine groundwater sampling events.
EV-06-2237 Page 2 Georgia Environmental Protection Division Mr. Jeff Gown Please find enclosed the June, 2006 landfill groundwater monitoring report for this sampling period. If you have any questions regarding this information, please contact Mickey Perry at (205) 992-6994.
Sincerely
~.I~j/y J. M. Godfrey rr Manager - Environmental Affairs JMG/MEP:ahl Enclosure
EV~06-2237 Page 3 Georgia Environmental Protection Division Mr. Jeff Cown cc:
Mr. Michael Kemp (w/o)
Mr. Earl Hinkle (w/o)
Mr. Kurt Batsell (Dextra) (w/o)
EV-06-2237 Page 4 Georgia Environmental Protection Division Mr. Jeff Cown bc:
T. E. Tynan (w/o)
N. D. Dennis (w/o)
C. L. Buck (w/o)
S. A. Varnum (w/o)
J. A. Joyner (w/o)
D. G. Goodwin (Return Receipt)
SNC Document Management - Vogtle (Return Receipt)
GROUNDWATER MONITORING REPORT PLANT VOGTLE LANDFILL #3 SOLID WASTE PERMIT NO. 017-007D(L)(I)
BURKE COUNTY, GEORGIA SEPTEMBER 2006 PREPARED FOR:
Southern Nuclear Operating Company, Inc.
40 Inverness Center Parkway Birmingham, Alabama 35201 PREPARED BY:
Kurt R. Batsel, P.E.
Georgia License Number 16594 The Dextra Group, Inc.
1205 Johnson Ferry Road Suite #136-446 Marietta, Georgia 30068
i TABLE OF CONTENTS 1 - Introduction................................................................................................................................................ 1 2 - Monitoring Well Network........................................................................................................................ 1 3 - Groundwater Flow Rate and Directional Data...................................................................................... 2 3.1 Geology/Hydrogeology 3.2 Groundwater Elevations and Gradients 4 - Sampling Procedures and Parameter Analyses...................................................................................... 3 4.1 Procedures and Field Measurements 4.2 Parameter Analyses 5 - Groundwater Quality Evaluation............................................................................................................ 4 5.1 Detected Parameters 5.2 Statistical Analyses 6 - Conclusions................................................................................................................................................. 5 In Order Following Page 5 Tables 1 - Groundwater Elevations and Monitoring Well Construction Details 2 - Groundwater Sampling Field Measurements 3 - Constituents for Detection Monitoring 4 - Summary of Detected Parameters Figures 1 - Groundwater Contour Elevation Map, June 5, 2006 Appendices A - Hydraulic Gradient Calculation Sheets B - Laboratory Analytical Reports C - Statistical Analyses
1 1 - Introduction This report presents the results of groundwater sampling conducted in June 2006 at private solid waste Landfill #3 operated by Southern Nuclear Operating Company, Inc. (SNC) at Plant Vogtle in Waynesboro, Georgia. Groundwater monitoring was initiated in 2002 in accordance with the approved Groundwater Monitoring Plan for the landfill. The landfill is operated under Solid Waste Permit #017-007D(L)(I) and used for disposal of non-putrescible, non-liquid office and solid waste as well as construction/demolition debris such as asbestos insulation, wooden pallets and concrete.
Landfill #3, permitted in 1987, has been utilized solely for construction and demolition debris disposal since 1992.
Sampling, analyses and data evaluation were conducted in accordance with the rules of the Georgia Department of Natural Resources Environmental Protection Division (EPD), Chapter 391-3-4, the September 1991 Manual for Groundwater Monitoring and the approved Groundwater Monitoring Plan for the landfill.
The findings of the initial four sampling events, conducted from August 2002 through December 2002, and subsequent semi-annual sampling events are presented in reports previously submitted to the EPD. This report presents the results of the June 2006 semi-annual monitoring event.
Subsequent reports will be prepared upon completion of semi-annual monitoring events as scheduled in the Groundwater Monitoring Plan.
2 - Monitoring Well Network The groundwater monitoring well network consists of nine permanent monitoring wells located along the perimeter of the waste management unit boundary of Landfill #3 (Figure 1). As shown in the figure, the wells are located outside of, but as close as practical to, the waste disposal areas. The wells are screened within the uppermost water-producing zones underlying the landfill, which occur from approximately 30 to 80 feet below land surface at Landfill #3.
The nine permanent groundwater monitoring wells at Landfill #3 were installed in September 2001, July 2002 and June 2005. The well construction details are presented in Table 1. As noted in the table, well GWC-16 has been dry during each groundwater monitoring event. Wells GWA-7/MW-7 and GWA-15/MW-15 are located at the south and southwest portions of the landfill boundary.
Wells GWC-5/MW-5, GWC-13/MW-13 and GWC-14/MW-14 are located along the eastern portion of the landfill boundary, and wells GWB-6/MW-6 and GWB-16/MW-16 are located along the northern landfill boundary. Wells GWC-17/MW-17 and GWC-18/MW-18 were recently installed at the southeast corner of the landfill as part of the contamination assessment program at Landfill #3.
Well GWA-7/MW-7 was initially treated as a compliance (downgradient) well for Landfill #3.
However, due to review of water level measurements showing this well to be side gradient from the active fill area of the landfill, well GWA-7/MW-7 was evaluated as a background well in the monitoring reports from the June 2003 and December 2003 sampling events. Based on the consistent detection of trichlorofluoromethane and the June 2004 detection of trichloroethene in Well GWA-7/MW-7, it was decided to return to evaluating this well as a compliance well. This approach was used in this monitoring report. The most appropriate designation for this well will continue to be evaluated in light of future monitoring results. For this report, well GWA-15/MW-15 is the designated background well, and the remaining wells are designated compliance wells. The wells will be referred to as GWC-5, GWB-6, GWA-7, GWC-13, GWC-14, GWA-15, GWB-16, GWC-17 and GWC-18 in this report in accordance with the EPDs well identification guidelines.
2 Two stormwater sediment ponds were completed in 2004 in accordance with the approved Design and Operational Plan for the Vogtle Landfill #3. As there was no discharge from either pond at the time of the June 2006 groundwater monitoring event, no surface water samples were collected from the surface water monitoring stations located at the pond outfalls.
3 - Groundwater Flow Rate and Directional Data 3.1 Geology/Hydrogeology The geology of the Plant Vogtle site consists of sedimentary deposits within the Coastal Plain physiographic province of Georgia. These sediments consist of unconsolidated sands, silts and clays comprised of marine and non-marine fluvial deposits. Marls and limestone were also encountered at depth in deep borings completed at the landfill. The marls encountered during drilling were components of the Irwinton Sand member. Either all or parts of the Barnwell Group members (except the Utley Limestone member) were also encountered in the other borings conducted at the landfill. Underlying the Barnwell Group is the Lisbon Formation with its uppermost unit, the Blue Bluff Marl, located immediately under the Utley Limestone. This marl layer, approximately 70 feet thick, is a near-impermeable layer that effectively confines the Tertiary and Cretaceous aquifers, the two confined aquifers beneath the Plant site.
The occurrence of groundwater underlying the landfill appears in confined, semi-confined, unconfined, and perched hydrogeologic units. Groundwater is found primarily in sands, silty sands, clayey sands and marl limestone interfaces. The main difference between boring/well water production characteristics and aquifer confining characteristics appears to be the thickness of the water-producing zone, the grain size of the sand component, the sand/clay ratio and the characteristics of the marl/limestone interface.
Groundwater may also exist in an unconfined water table aquifer in the Barnwell sands and limestone that overlie the marl. The water table aquifer at the site is on an interfluvial ridge, or a topographically high area in which the groundwater in the water table discharges along streams that surround the topographic high. The streams eventually discharge to the Savannah River.
3.2 Groundwater Elevations and Gradients During well installation, the occurrence of groundwater was determined by collecting continuous split spoon samples beginning approximately five feet above the location of expected groundwater-producing zones. At both landfill, groundwater was generally found in water producing zones less than one foot thick and was observed to be under semi-confined or confined conditions.
Upon completion of all drilling activities, measuring points were located on the tops of the well casings and surveyed relative to mean sea level (msl). During each sampling event, depth to water measurements were recorded in the wells from the surveyed elevations using an electronic water-level indicator. The water level measurements were then subtracted from the appropriate measuring point elevations to determine groundwater elevations in the wells.
Hydraulic conductivity (K) in the wells was measured on September 26, 2001. The values ranged from 5.634 x 10-4 cm/sec in GWB-6 to 3.064 x 10-2 cm/sec in GWA-2.
Depth to water measurements and groundwater elevations for the wells at Landfill #3 are presented in Table 1. Groundwater elevations measured to date indicate that the groundwater elevation, or hydraulic head, is greatest beneath the center area of the landfill, and decreases to the southeast, to
3 the northeast and to the west-southwest beneath the landfill. This mounding effect is believed to be the result of natural infiltration in the sandy soils within the historic topographically high area in the center of the landfill. This topographically high area, which encompasses a broad area within the landfill, is a natural site feature that was present prior to any landfilling operations. Figure 1 shows the topography of the landfill.
As discussed previously, the water-bearing stratigraphy beneath Landfill #3 is composed of individual saturated sand units within a clayey/marl matrix. These units may or may not be interconnected. As such, groundwater elevations in the monitoring wells may reflect head in multiple perched layers and may not represent groundwater flow direction beneath the landfill. Figure 2 presents a map depicting the saturated head contours measured on June 5, 2006.
Monitoring well GWA-15 is the well most representative of background water quality at the site because of the distance between the well and the current landfilled area, and the location of the area of relatively higher head located between the well and the current landfilled area on the eastern portion of the site. This well is therefore used as a background well to evaluate groundwater quality at the landfill. Well GWA-7 is now evaluated as a downgradient well based on review of the groundwater elevation and chemical analysis data collected since 2002.
The hydraulic gradient was calculated using a three-point problem from groundwater elevations in the monitoring wells as follows for each main direction of head difference:
Southwest: GWB-6, GWA-7 and GWA-15; Northeast: GWC-13, GWB-6 and GWC-5; and Southeast: GWC-13, GWA-7 and GWC-14.
The calculated hydraulic gradients are presented on the contour map (Figure 1). The calculations used in determining the gradients are provided in Appendix A. For the June 2006 event, the southwest gradient was 0.010, the northeast gradient was 0.08, and the southeast gradient was 0.12. The southwest gradient has typically been 0.01, with a maximum of 0.02 (June 2003), reflecting the consistently flattest gradient across the landfill. The northeast trending gradient has ranged from a minimum of 0.08 (October and December 2002, June 2004) to a maximum of 0.17 (June 2003). The southeast gradient has ranged from a low of 0.06 (December 2002) to a maximum of 0.16 (June 2003). For this monitoring event, the steepest gradient was observed in the southeast flow component.
4 - Sampling Procedures and Parameter Analyses 4.1 Procedures and Field Measurements Prior to sample collection during each sampling event, depth to water measurements are recorded in each well from the surveyed elevations using an electronic water level indicator. The water level indicator is decontaminated using a potable water and Alconox wash and a distilled water rinse between use at each well. The water level measurements are then subtracted from the appropriate measuring point elevations to determine the groundwater elevations in the wells.
Groundwater samples were collected from all monitoring wells after the wells were properly purged according to the EPA document entitled Low-Flow Purging & Sampling of Groundwater Monitoring Wells (Bulletin QAD023). The wells were purged and sampled using QED SamplePro pumps equipped with Teflon bladders. Purge rates were matched to the recovery rates of the wells, verified by periodic depth to water measurements to determine draw-down during purging. Purging was conducted until at least three consecutive stable readings of pH, conductivity, and turbidity were
4 recorded. Groundwater samples were then collected directly into pre-preserved sample containers supplied by the laboratory. Final measurements of pH, conductivity, and turbidity were performed to verify that these parameters remained stable during sampling. All field instruments were calibrated in the field daily prior to use and at the conclusion of each sampling event. The field measurements are provided in Table 2.
After each sample was collected, the SamplePro pumps and airlines were decontaminated according to the following protocol:
The pump and air line were placed on clean plastic; The pump was disassembled and the bladder was removed; The pump was sprayed with a potable water and Alconox solution, followed with a distilled water rinse until all soap residue was removed; A new pump bladder was then installed in the pump prior to reassembly; and The pump airline was placed in a clean plastic bag between use at each well.
4.2 Parameter Analyses In accordance with the approved Groundwater Monitoring Plan, the groundwater samples and field and laboratory quality assurance/quality control (QA/QC) samples were analyzed for the Chapter 391-3-4 Appendix I list of parameters, which consists of total metals and volatile organic compounds (Table 5). The field QA/QC samples consisted of duplicate samples, trip blanks and equipment blanks. Metals analyses were conducted using EPA Methods 6010B/7841, and VOCs analyses were conducted using EPA Methods 6010B/8260B and 504.1 to provide sufficiently sensitive quantitation limits for comparison with maximum contaminant limits. Advanced Chemistry Labs, Inc., Atlanta, Georgia performed the laboratory analyses. The complete laboratory analytical reports, which include field and laboratory QA/QC results and chain-of-custody forms, are provided in Appendix B. Please note that the well GWC-6 on the chain-of-custody should be labeled GWB-6.
Samples were also collected for the Chapter 391-3-4 Appendix II parameter mercury in all wells due to this parameters detection in previous assessment monitoring conducted at the landfill. Full Appendix II analysis was performed for well GWA-7 during the June 2006 event.
5 - Groundwater Quality Evaluation 5.1 Detected Parameters Table 4 presents a summary of all analyzed parameters detected above the laboratory method reporting limits. Barium was detected at concentrations below the MCL in well GWC-5 (0.031 mg/l),
and in well GWC-13 (0.051 mg/l). Zinc was detected in well GWC-5 at 0.100 mg/l, in well GWB-6 at 0.083 mg/l, in well GWA-7 at 0.484 mg/l, in the replicate sample well GWA-7 at 0.266 mg/l, in well GWC-13 at 0.213 mg/l, in well GWA-15 at 0.063 mg/l and in well GWC-17 at 0.077 mg/l; there is no MCL for zinc. In the compliance well GWA-7 the VOC trichlorofluoromethane was detected at 66 ug/l, and at 94 ug/l in the replicate sample well GWA-7; there is no MCL for trichlorofluoromethane. In the compliance well GWC-13, 1,1-dichloroethane, cis-1,2-dichloroethene, and trichlorofluoromethane were detected at low levels. All VOC concentrations in GWC-13 were below applicable MCLs. The Appendix II parameter naphthalene was detected in well GWA-7 at 5 ug/l; however, this constituent was not detected in the duplicate sample from well GWA-7.
5 No parameters were detected in any of the field or laboratory QA/QC samples, and the laboratory QA/QC checks were within acceptable limits.
5.2 Statistical Analyses In accordance with the approved Groundwater Monitoring Plan, statistical analyses were conducted for each constituent detected in the compliance well samples for this sampling event. The analyses were conducted to help identify any significant increase in constituent concentrations in downgradient, or compliance, well samples over samples representative of background water quality.
The analyses were conducted consistent with U.S. EPA recommended methods as detailed in the guidance document Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities -
Interim Final Guidelines (1989) and the corresponding Addendum (1992).
The following methodology was used to evaluate the data:
The distribution of the data was first evaluated for normality using either the Shapiro-Wilkes Test (for parameters with less than 50 samples) or the Shapiro-Francia Test (for parameters with greater than 50 samples) as recommended in the 1992 EPA guidance. The tests indicate that the concentrations of all detected parameters do not follow normal distributions.
For the well data sets, the Kruskal-Wallis non-parametric analysis of variance method was used to compare the concentrations of individual parameters in each compliance well to the concentrations of these parameters in the background well. This method is recommended by the 1992 EPA guidance for non-normal sample sets that have between 15% and 90% non-detects.
The detailed statistical analyses are provided in Appendix C and the results are summarized below.
At Landfill #3, statistical analysis was performed for the five detected parameters barium, zinc, 1,1-dichloroethane, cis-1,2-dichloroethene, and trichlorofluoromethane. Compared to background well GWA-15/MW-15, the analyses indicate statistically significant higher concentrations of the following parameters:
Barium, 1,1-dichloroethane, cis-1,2-dichloroethene and trichlorofluoromethane in the GWC-13 well sample Barium, 1,1-dichloroethane, and cis-1,2-dichloroethene in the GWC-14 well sample Trichloroflouromethane in the GWA-7/MW-7 well sample It should be noted that the statistical analyses data sets include all sampling events to date for all wells. As a result, statistically higher concentrations of detected parameters in a well are determined based on all reported concentrations (including consideration of non-detects) from all sampling events for that well. If a concentration is lower in the current event for a well, the complete data set for the well may still indicate a statistically higher concentration over the background well data set considering all sampling events to date. For example, although there was no sample available for GWC-14 for this event, the statistical analyses indicate significantly higher concentrations of barium, 1,1-dichloroethane, and cis-1,2-dichloroethene for the GWC-14 historical sample data set.
6 - Conclusions Since a statistically significant increase over background is indicated for several analyzed parameters in wells GWC-13, GWC-14, and GWA-7 at Landfill #3, SNC will place a notice in the operating
6 record within 14 days of submittal of this report as required by Chapter 391-3-4. The notice will indicate which constituents have shown statistically significant higher concentrations compared to the background wells. Based on prior detections of the Appendix II parameter mercury in Landfill
- 3 wells, SNC will continue to perform analysis for mercury in all Landfill #3 wells during the regular semi-annual sampling events.
TABLES
Table 1 Southern Nuclear Operating Company Plant Vogtle Landfill #3 Groundwater Elevations and Monitoring Well Construction Details Well ID Date Measuring Point Elevation (feet, msl)
Ground Surface Elevation (feet, msl)
Depth to Water (feet, topvc)
Total Boring Depth (feet, bls)
Total Well Depth (feet, topvc)
Riser Height (feet)
Screened Interval (feet, msl)
Groundwater Elevation (feet, msl)
GWC-5/MW-5 9/26/2001 251.96 249.11 48.65 67 56.85 2.85 195.11 to 205.11 203.31 7/29/2002 50.21 201.75 9/9/2002 50.43 201.53 10/21/2002 49.26 202.70 12/3/2002 49.26 202.70 6/24/2003 44.60 207.36 12/16/2003 47.55 204.41 6/15/2004 47.76 204.20 12/28/2004 49.13 202.83 6/13/2005 45.94 206.02 12/5/2005 48.05 203.91 6/5/2006 47.85 204.11 GWB-6/MW-6 9/26/2001 278.87 276.45 47.47 67 64.42 2.42 214.45 to 224.45 231.40 7/29/2002 48.52 230.35 9/9/2002 48.55 230.32 10/21/2002 49.21 229.66 12/3/2002 48.86 230.01 6/24/2003 46.92 231.95 12/16/2003 46.30 232.57 6/15/2004 46.49 232.38 12/28/2004 47.22 231.65 6/13/2005 47.84 231.03 12/5/2005 47.20 231.67 6/5/2006 47.38 231.49 GWA-7/MW-7 9/26/2001 261.33 259.39 31.11 50 41.94 1.94 219.39 to 229.39 230.22 7/29/2002 33.16 228.17 9/9/2002 33.25 228.08 10/21/2002 33.20 228.13 12/3/2002 32.94 228.39 6/24/2003 27.51 233.82 12/16/2003 30.59 230.74 6/15/2004 30.87 230.46 12/28/2004 32.33 229.00 6/13/2005 30.64 230.69 12/5/2005 31.60 229.73 6/5/2006 31.74 229.59 Page 1 of 3
Table 1 Southern Nuclear Operating Company Plant Vogtle Landfill #3 Groundwater Elevations and Monitoring Well Construction Details Well ID Date Measuring Point Elevation (feet, msl)
Ground Surface Elevation (feet, msl)
Depth to Water (feet, topvc)
Total Boring Depth (feet, bls)
Total Well Depth (feet, topvc)
Riser Height (feet)
Screened Interval (feet, msl)
Groundwater Elevation (feet, msl)
GWC-13/MW-13 7/29/2002 273.08 270.99 40.92 50 50.09 2.09 222.99 to 232.99 232.16 9/9/2002 41.00 232.08 10/21/2002 40.94 232.14 12/3/2002 40.48 232.60 6/24/2003 36.90 236.18 12/16/2003 39.17 233.91 6/15/2004 39.59 233.49 12/28/2004 40.59 232.49 6/13/2005 38.76 234.32 12/5/2005 39.93 233.15 6/5/2006 39.97 233.11 GWC-14/MW-14 7/29/2002 262.88 260.66 40.05 55 53.22 2.22 209.66 to 219.66 222.83 9/9/2002 42.31 220.57 10/21/2002 42.79 220.09 12/3/2002 42.35 220.53 6/24/2003 44.29 218.59 12/16/2003 51.52 211.36 6/15/2004 52.11 210.77 12/28/2004 52.66 210.22 6/13/2005 51.66 211.22 12/5/2005 52.56 210.32 6/5/2006 53.03 209.85 GWA-15/MW-15 7/29/2002 268.15 265.34 45.94 55 55.81 2.81 212.34 to 222.34 222.21 9/9/2002 46.05 222.10 10/21/2002 46.19 221.96 12/3/2002 46.23 221.92 6/24/2003 41.76 226.39 12/16/2003 43.29 224.86 6/15/2004 43.24 224.91 12/28/2004 44.68 223.47 6/13/2005 40.1 228.05 12/5/2005 47.39 220.76 6/5/2006 44.32 223.83 Page 2 of 3
Table 1 Southern Nuclear Operating Company Plant Vogtle Landfill #3 Groundwater Elevations and Monitoring Well Construction Details Well ID Date Measuring Point Elevation (feet, msl)
Ground Surface Elevation (feet, msl)
Depth to Water (feet, topvc)
Total Boring Depth (feet, bls)
Total Well Depth (feet, topvc)
Riser Height (feet)
Screened Interval (feet, msl)
Groundwater Elevation (feet, msl)
GWB-16/MW-16 7/29/2002 256.95 254.57 DRY 65 55.38 2.38 201.57 to 211.57 DRY 9/9/2002 DRY DRY 10/21/2002 DRY DRY 12/3/2002 DRY DRY 6/24/2003 DRY DRY 12/16/2003 DRY DRY 6/15/2004 DRY DRY 12/28/2004 DRY DRY 6/13/2005 DRY DRY 12/5/2005 DRY DRY 6/5/2006 DRY DRY GWC-17/MW-17 6/13/2005 222.64 220.28 72.82 85 82.00 3.00 141.28 to 151.28 149.82 12/5/2005 72.6 150.04 6/5/2006 72.61 150.03 GWC-18/MW-18 6/13/2005 227.54 225.03 77.05 80 79.00 3.00 149.03 to 159.03 150.49 12/5/2005 DRY DRY 6/5/2006 DRY DRY Notes:
Ground surface measured at survey bolt set in concrete pad at base of protective casing.
msl = mean sea level; topvc = measured from top of pvc riser; bls = below land surface Page 3 of 3
Table 2 Southern Nuclear Operating Company Plant Vogtle Landfill #3 Groundwater Sampling Field Measurements Well ID Date pH Conductivity/1 Turbidity/2 Gallons Purged Odor Color Comments GWC-5/MW-5 9/26/2001 5.11 47.5 28.6 6.0 none cloudy Well development only 7/29/2002 5.41 24.4 2.83 1.75 none none 9/9/2002 8.13 365 4.11 2.0 none none 10/21/2002 12/3/2002 5.94 117 7.8 2.0 none none 6/24/2003 5.18 29 3.5 6.0 none none 12/16/2003 6.27 210 79.7 3.0 none cloudy Split with GAEPD 6/16/2004 5.94 40.7 16.5 2.0 none none 12/28/2004 4.96 30 7.33 2.3 none none 6/13/2005 5.86 580 6.2 3.5 none none 12/6/2005 5.48 548 6.03 2.5 none none 6/5/2006 6.38 550 2.23 1.5 none none GWB-6/MW-6 9/26/2001 7.13 242 25.6 2.0 none Well development only 7/29/2002 6.75 1,338 0.35 1.5 none none 9/9/2002 4.13 198 6.43 1.5 none none 10/21/2002 6.72 573 0.44 2.5 none none 12/3/2002 6.14 116 0.45 1.5 none none 6/24/2003 7.09 155 9.1 1.5 none none 12/17/2003 6.82 126 2.27 1.5 none none 6/16/2004 6.77 178.5 1.25 2.75 none none 12/28/2004 7.05 130 2.84 2.25 none none 6/13/2005 6.88 125 2.67 2.50 none none 12/5/2005 7.10 122 2.22 2.00 none none 6/5/2006 7.20 120 2.41 1.00 none none GWA-7/MW-7 9/26/2001 cloudy 30.0 Well development only 7/29/2002 6.97 251 8.33 2.5 none none 9/9/2002 7.52 327 9.97 5.0 none none 10/21/2002 4.39 92 3.14 2.0 none none 12/3/2002 6.51 188 7.3 2.5 none none 6/24/2003 7.02 163 101.3 4.0 none dark brown Turbidity >100 ntu for 2 hours2.314815e-5 days <br />5.555556e-4 hours <br />3.306878e-6 weeks <br />7.61e-7 months <br /> 12/16/2003 5.73 62.7 100 4.0 none mod. brown Turbidity 85-100 ntu for 1 hour1.157407e-5 days <br />2.777778e-4 hours <br />1.653439e-6 weeks <br />3.805e-7 months <br /> 6/15/2004 5.94 68.9 42.7 2.0 none none 12/28/2004 8.16 109 9.86 3.5 none none 6/14/2005 7.25 275 8.56 3.0 none none 12/6/2005 5.37 92 96 8.5 none mod. brown Turbidity >100 ntu for 2 hours2.314815e-5 days <br />5.555556e-4 hours <br />3.306878e-6 weeks <br />7.61e-7 months <br /> 6/5/2006 5.12 151 20 5.0 none none Page 1 of 3
Table 2 Southern Nuclear Operating Company Plant Vogtle Landfill #3 Groundwater Sampling Field Measurements Well ID Date pH Conductivity/1 Turbidity/2 Gallons Purged Odor Color Comments GWC-13/MW-13 7/29/2002 6.52 421 0.66 9/9/2002 5.96 77.5 6.40 1.0 none none 10/21/2002 6.19 73.4 3.09 2.5 none none 12/3/2002 6.54 481 1.00 2.5 none none 6/24/2003 5.95 271 2.02 2.5 none none 12/16/2003 5.65 294 0.75 6.0 none none Split with GAEPD 6/16/2004 5.84 366 4.70 1.75 none none 12/28/2004 6.09 268 0.38 1.75 none none 6/13/2005 5.75 255 2.00 1.50 none none 12/6/2005 4.03 4.24 1.07 2.50 none none 6/5/2006 7.17 250 1.11 1.00 none none GWC-14/MW-14 7/29/2002 6.49 448 1.15 none none 9/9/2002 5.57 717 5.19 none none 10/21/2002 6.00 674 4.65 3.2 none none 12/3/2002 5.54 547 2.7 4.5 none none 6/24/2003 5.97 197 3.61 2.5 none none 12/17/2003 Split with GAEPD-VOCs & metals 6/15/2004 Well Dry 12/28/2004 Too little water to purge and sample 6/14/2005 Too little water to purge and sample 12/6/2005 Too little water to purge and sample 6/6/2006 Too little water to purge and sample GWA-15/MW-15 7/29/2002 5.70 95.8 1.12 4.0 none none 9/9/2002 5.92 118 8.53 2.5 none none 10/21/2002 5.19 81 1.88 4.5 none none 12/3/2002 7.58 78.2 3.6 2.5 none none 6/24/2003 7.44 48.0 5.38 2.5 none none 12/17/2003 6.93 39.4 4.55 6.5 none none Split with GAEPD 6/15/2004 6.47 55.7 5.59 2.25 none none 12/28/2004 6.83 50.0 8.85 3.00 none none 6/14/2005 7.85 72.0 7.75 4.00 none none 12/5/2005 6.88 56.0 2.3 2.50 none none 6/5/2006 7.15 55.0 1.6 2.00 none none Page 2 of 3
Table 2 Southern Nuclear Operating Company Plant Vogtle Landfill #3 Groundwater Sampling Field Measurements Well ID Date pH Conductivity/1 Turbidity/2 Gallons Purged Odor Color Comments GWB-16/MW-16 7/29/2002 Well Dry 9/9/2002 Well Dry 10/21/2002 Well Dry 12/3/2002 Well Dry 6/24/2003 Well Dry 12/16/2003 Well Dry 6/15/2004 Well Dry 12/28/2004 Well Dry 6/15/2005 Well Dry 12/6/2005 Well Dry 6/5/2006 Well Dry GWB-17/MW-17 6/15/2005 5.84 77.58 5.29 3.5 none none 12/6/2005 6.33 68 10 3
none none 6/5/2006 6.56 80 10 1.5 none none GWB-18/MW-18 6/15/2005 6.67 85.6 8.2 4.2 none none 12/6/2005 Well Dry 6/5/2006 Well Dry Notes:
-- = no data recorded;
/1 - Conductivity in units of umhos/sec
/2 - Turbidity in units of NTU Page 3 of 3
Table 3 Southern Nuclear Operating Company Plant Vogtle Landfill #3 Appendix I to Part 40 CFR Part 258: Constituents for Detection Monitoring (1)
Common Name (2)
EPA Method Inorganic Constituents:
(1) Antimony............................................. 6010B/7041 (2) Arsenic.............................................. 6010B/7061 (3) Barium............................................... 6010B/7091 (4) Beryllium............................................ 6010B/7091 (5) Cadmium.............................................. 6010B/7131 (6) Chromium............................................. 6010B/7191 (7) Cobalt............................................... 6010B/7201 (8) Copper............................................... 6010B/7211 (9) Lead................................................. 6010B/7421 (10) Nickel.............................................. 6010B/7520 (11) Selenium............................................ 6010B/7741 (12) Silver.............................................. 6010B/7761 (13) Thallium............................................ 6010B/7841 (14) Vanadium............................................ 6010B/7911 (15) Zinc................................................ 6010B/7951 Organic Constituents:
8260 (16) Acetone.............................................
(17) Acrylonitrile.......................................
(18) Benzene.............................................
(19) Bromochloromethane..................................
(20) Bromodichloromethane................................
(21) Bromoform; Tribromomethane..........................
(22) Carbon disulfide....................................
(23) Carbon tetrachloride................................
(24) Chlorobenzene.......................................
(25) Chloroethane; Ethyl chloride........................
(26) Chloroform; Trichloromethane........................
(27) Dibromochloromethane; Chlorodibromomethane..........
(28) 1,2-Dibromo-3-chloropropane; DBCP...................
(29) 1,2-Dibromoethane; Ethylene dibromide; EDB..........
(30) o-Dichlorobenzene; 1,2-Dichlorobenzene..............
(31) p-Dichlorobenzene; 1,4-Dichlorobenzene..............
(32) trans-1,4-Dichloro-2-butene.........................
(33) 1,1-Dichloroethane; Ethylidene chloride.............
(34) 1,2-Dichloroethane; Ethylene dichloride.............
(35) 1,1-Dichloroethylene; 1,1-Dichloroethene; Vinylidene chloride................................................
(36) cis-1,2-Dichloroethylene; cis-1,2-Dichloroethene....
(37) trans-1,2-Dichloroethylene; trans-1,2-Dichloroethene (38) 1,2-Dichloropropane; Propylene dichloride...........
(39) cis-1,3-Dichloropropene.............................
(40) trans-1,3-Dichloropropene...........................
(41) Ethylbenzene........................................
(42) 2-Hexanone; Methyl butyl ketone.....................
(43) Methyl bromide; Bromomethane........................
(44) Methyl chloride; Chloromethane......................
Page 1 of 2
Table 3 (continued)
Southern Nuclear Operating Company, Inc.
Plant Vogtle Landfill #3 Appendix I to Part 40 CFR Part 258: Constituents for Detection Monitoring (1)
Common Name (2)
EPA Method (45) Methylene bromide; Dibromomethane................... 8260 (46) Methylene chloride; Dichloromethane.................
(47) Methyl ethyl ketone; MEK; 2-Butanone................
(48) Methyl iodide; Iodomethane..........................
(49) 4-Methyl-2-pentanone; Methyl isobutyl ketone........
(50) Styrene.............................................
(51) 1,1,1,2-Tetrachloroethane...........................
(52) 1,1,2,2-Tetrachloroethane...........................
(53) Tetrachloroethylene; Tetrachloroethene; Perchloroethylene.......................................
(54) Toluene.............................................
(55) 1,1,1-Trichloroethane; Methylchloroform.............
(56) 1,1,2-Trichloroethane...............................
(57) Trichloroethylene; Trichloroethene..................
(58) Trichlorofluoromethane; CFC-11......................
(59) 1,2,3-Trichloropropane..............................
(60) Vinyl acetate.......................................
(61) Vinyl chloride......................................
(62) Xylenes.............................................
(1) This list contains 47 volatile organics for which possible analytical procedures provided in EPA Report SW-846 ``Test Methods for Evaluating Solid Waste, third edition, November 1986, as revised December 1987,includes Method 8260; and 15 metals for which SW-846 provides either Method 6010 or a method from the 7000 series of methods.
(2) Common names are those widely used in government regulations, scientific publications, and commerce; synonyms exist for many chemicals.
Page 2 of 2
GWC-5/MW-5 GWB-6/MW-6 GWA-7/MW-7 GWA-7/MW-73 GWC-13/MW-13 GWC-14/MW-14 GWA-15/MW-15 GWC-17/MW-17 GWC-18/MW-18 Metals1 Barium 2.00 0.031 BQL BQL BQL 0.051 NS BQL BQL NS Zinc NA 0.100 0.083 0.484 0.266 0.213 NS 0.063 0.077 NS Organics2 1,1-Dichloroethane NA BQL BQL BQL BQL 15 NS BQL BQL NS Chlorobenzene 100 BQL BQL BQL BQL BQL NS BQL BQL NS cis-1,2-Dichloroethene 70 BQL BQL BQL BQL 8
NS BQL BQL NS Trichlorofluoromethane NA BQL BQL 66 94 92 NS BQL BQL NS Vinyl chloride 2
BQL BQL BQL BQL BQL NS BQL BQL NS Napthalene4 NA NA NA 5
BQL NA NS NA NA NA Benzene 5
BQL BQL BQL BQL BQL NS BQL BQL NS Trichloroethene 5
BQL BQL BQL BQL BQL NS BQL BQL NS BQL - Below quantification level; J - Estimated Value MCL - Maximum Contaminant Level per EPD Rule Chapter 391-3-5; NA - None available NS - Not sampled; well dry or insufficient recovery to sample well 1Metals concentrations in mg/L 2Organics concentration units in ug/l or ppb 3Replicate sample of well GWC-7/MW-7 sample 4Appendix II parameter; NA reflects that this parameter was not analyzed for those wells not included in the Assessment Monitoring Program Bold indicates detected concentration is greater than the MCL.
CONSTITUENT MCL WELL SAMPLES Table 4 Southern Nuclear Operating Company Plant Vogtle Landfill #3 Summary of Detected Parameters June 2006 Page 1 of 11
GWC-5/MW-5 GWB-6/MW-6 GWA-7/MW-7 GWA-7/MW-73 GWC-13/MW-13 GWC-14/MW-14 GWA-15/MW-15 GWC-17/MW-17 GWC-18/MW-18 Metals1 Barium 2.00 BQL BQL 0.024 0.022 0.044 NS BQL BQL NS Zinc NA 0.055 0.020 0.068 0.217 0.194 NS 0.042 0.096 NS Organics2 1,1-Dichloroethane NA BQL BQL BQL BQL 18 NS BQL BQL NS Chlorobenzene 100 BQL BQL BQL BQL 4J NS BQL BQL NS cis-1,2-Dichloroethene 70 BQL BQL BQL BQL 9
NS BQL BQL NS Trichlorofluoromethane NA BQL BQL 88 85 60 NS BQL BQL NS Vinyl chloride 2
BQL BQL BQL BQL 1J NS BQL BQL NS Napthalene4 NA NA NA 5
BQL NA NS NA NA NA Benzene 5
BQL BQL BQL BQL 5
NS BQL BQL NS Trichloroethene 5
BQL BQL BQL BQL 5
NS BQL BQL NS BQL - Below quantification level; J - Estimated Value MCL - Maximum Contaminant Level per EPD Rule Chapter 391-3-5; NA - None available NS - Not sampled; well dry or insufficient recovery to sample well 1Metals concentrations in mg/L 2Organics concentration units in ug/l or ppb 3Replicate sample of well GWC-7/MW-7 sample 4Appendix II parameter; NA reflects that this parameter was not analyzed for those wells not included in the Assessment Monitoring Program Bold indicates detected concentration is greater than the MCL.
CONSTITUENT MCL WELL SAMPLES Table 4 (Continued)
Southern Nuclear Operating Company Plant Vogtle Landfill #3 Summary of Detected Parameters December 2005 Page 2 of 11
GWC-5/MW-5 GWB-6/MW-6 GWA-7/MW-7 GWC-13/MW-13 GWC-13/MW-135 GWC-14/MW-14 GWA-15/MW-15 GWC-17/MW-17 GWC-18/MW-18 Metals1 Barium 2.00 BQL BQL BQL 0.028 0.031 NS BQL BQL BQL Zinc NA BQL BQL BQL 0.020 BQL NS 0.029 BQL BQL Copper 1.36 BQL BQL BQL BQL BQL NS BQL BQL BQL Mercury4 0.002 BQL BQL BQL BQL BQL NS BQL BQL BQL Chromium (total) 0.1 BQL BQL BQL BQL BQL NS BQL BQL BQL Beryllium 0.004 BQL BQL BQL BQL BQL NS BQL BQL BQL Cadmium 0.005 BQL BQL BQL BQL BQL NS BQL BQL BQL Nickel NA BQL BQL BQL BQL BQL NS BQL BQL BQL Lead 0.0156 BQL BQL BQL BQL BQL NS BQL BQL BQL Vanadium NA BQL BQL BQL BQL BQL NS BQL BQL BQL Organics2 1,1-Dichloroethane NA BQL BQL BQL 15 15 NS BQL BQL BQL Carbon disulfide NA BQL BQL BQL BQL BQL NS BQL 32 BQL Chlorobenzene 100 BQL BQL BQL BQL BQL NS BQL BQL BQL 1,4-Dicholorbenzene 75 BQL BQL BQL BQL BQL NS BQL BQL BQL Methylene chloride 5
BQL BQL BQL BQL BQL NS BQL BQL BQL cis-1,2-Dichloroethene 70 BQL BQL BQL 8
8 NS BQL BQL BQL Trichlorofluoromethane NA BQL BQL 22 46 45 NS BQL BQL BQL 1,1-Dichloroethene 7
BQL BQL BQL BQL BQL NS BQL BQL BQL Xylenes (Total) 10000 BQL BQL BQL BQL BQL NS BQL BQL BQL Vinyl chloride 2
BQL BQL BQL BQL BQL NS BQL BQL BQL Chloroform3 0.1 BQL BQL BQL BQL BQL NS BQL BQL BQL Trichloroethene 5
BQL BQL BQL BQL BQL NS BQL BQL BQL BQL - Below quantification level MCL - Maximum Contaminant Level per EPD Rule Chapter 391-3-5; NA - None available NS - Not sampled; well dry or insufficient recovery to sample well 1Metals concentrations in mg/L 2Organics concentration units in ug/l or ppb 3Applies only to Community Water Systems serving 10,000 4Appendix II parameter; NA reflects that this parameter was not analyzed for those wells not included in the Assessment Monitoring Program 5Replicate sample of well GWC-13/MW-13 sample 6Action Level Bold indicates detected concentration is greater than the MCL.
CONSTITUENT MCL WELL SAMPLES Table 4 (Continued)
Southern Nuclear Operating Company Plant Vogtle Landfill #3 Summary of Detected Parameters June 2005 Page 3 of 11
GWC-5/MW-5 GWB-6/MW-6 GWA-7/MW-7 GWA-7/MW-75 GWC-13/MW-13 GWC-14/MW-14 GWA-15/MW-15 Metals1 Barium 2.00 BQL BQL BQL BQL 0.043 NS BQL Zinc NA BQL BQL BQL BQL 0.044 NS BQL Copper 1.36 BQL BQL BQL BQL BQL NS BQL Mercury4 0.002 BQL BQL BQL 0.0017 BQL NS 0.0004 Chromium (total) 0.1 BQL BQL BQL BQL BQL NS BQL Beryllium 0.004 BQL BQL BQL BQL BQL NS BQL Cadmium 0.005 BQL BQL BQL BQL BQL NS BQL Nickel NA BQL BQL BQL BQL BQL NS BQL Lead 0.0156 BQL BQL BQL BQL BQL NS BQL Vanadium NA BQL BQL BQL BQL BQL NS BQL Organics2 1,1-Dichloroethane NA BQL BQL BQL BQL 16 NS BQL Chlorobenzene 100 BQL BQL BQL BQL BQL NS BQL 1,4-Dicholorbenzene 75 BQL BQL BQL BQL BQL NS BQL Methylene chloride 5
BQL BQL BQL BQL BQL NS BQL cis-1,2-Dichloroethene 70 BQL BQL BQL BQL 8
NS BQL Trichlorofluoromethane NA BQL BQL 146 143 81 NS BQL 1,1-Dichloroethene 7
BQL BQL BQL BQL BQL NS BQL Xylenes (Total) 10000 BQL BQL BQL BQL BQL NS BQL Vinyl chloride 2
BQL BQL BQL BQL BQL NS BQL Chloroform3 0.1 BQL BQL BQL BQL BQL NS BQL Trichloroethene 5
BQL BQL BQL BQL BQL NS BQL BQL - Below quantification level MCL - Maximum Contaminant Level per EPD Rule Chapter 391-3-5; NA - None available NS - Not sampled; well dry or insufficient recovery to sample well 1Metals concentrations in mg/L 2Organics concentration units in ug/l or ppb 3Applies only to Community Water Systems serving 10,000 4Appendix II parameter; NA reflects that this parameter was not analyzed for those wells not included in the Assessment Monitoring Program 5Replicate sample of well GWA-7/MW-7 sample 6Action Level Bold indicates detected concentration is greater than the MCL.
Table 4 (Continued)
Southern Nuclear Operating Company Plant Vogtle Landfill #3 Summary of Detected Parameters CONSTITUENT MCL WELL SAMPLES December 2004 Page 4 of 11
GWC-5/MW-5 GWB-6/MW-6 GWA-7/MW-7 GWC-13/MW-13 GWC-13/MW-135 GWC-14/MW-14 GWA-15/MW-15 Metals1 Barium 2.00 0.040 BQL BQL 0.034 0.034 NS BQL Zinc NA BQL BQL BQL BQL BQL NS BQL Copper 1.36 BQL BQL BQL BQL BQL NS BQL Mercury4 0.002 BQL BQL 0.0006 BQL BQL NS BQL Chromium (total) 0.1 BQL BQL BQL BQL BQL NS BQL Beryllium 0.004 BQL BQL BQL BQL BQL NS BQL Cadmium 0.005 BQL BQL BQL BQL BQL NS BQL Nickel NA BQL BQL BQL BQL BQL NS BQL Lead 0.0156 BQL BQL BQL BQL BQL NS BQL Vanadium NA BQL BQL BQL BQL BQL NS BQL Organics2 1,1-Dichloroethane NA BQL BQL BQL 17 19 NS BQL Chlorobenzene 100 BQL BQL BQL BQL BQL NS BQL 1,4-Dicholorbenzene 75 BQL BQL BQL BQL BQL NS BQL Methylene chloride 5
BQL BQL BQL BQL BQL NS BQL cis-1,2-Dichloroethene 70 BQL BQL BQL 9
10 NS BQL Trichlorofluoromethane NA BQL BQL 46 121 133 NS BQL 1,1-Dichloroethene 7
BQL BQL BQL BQL BQL NS BQL Xylenes (Total) 10000 BQL BQL BQL BQL BQL NS BQL Vinyl chloride 2
BQL BQL BQL 2
2 NS BQL Chloroform3 0.1 BQL BQL BQL BQL BQL NS BQL Trichloroethene 5
BQL BQL 13 BQL BQL NS BQL BQL - Below quantification level MCL - Maximum Contaminant Level per EPD Rule Chapter 391-3-5; NA - None available NS - Not sampled; well dry or insufficient recovery to sample well 1Metals concentrations in mg/L 2Organics concentration units in ug/l or ppb 3Applies only to Community Water Systems serving 10,000 4Appendix II parameter; NA reflects that this parameter was not analyzed for those wells not included in the Assessment Monitoring Program 5Replicate sample of well GWC-13/MW-13 sample 6Action Level Bold indicates detected concentration is greater than the MCL.
Table 4 (Continued)
Southern Nuclear Operating Company Plant Vogtle Landfill #3 Summary of Detected Parameters CONSTITUENT MCL WELL SAMPLES June 2004 Page 5 of 11
GWC-5/MW-5 GWB-6/MW-6 GWA-7/MW-7 GWC-13/MW-13 GWC-13/MW-135 GWC-14/MW-14 GWA-15/MW-15 Metals1 Barium 2.00 0.142 BQL BQL 0.033 0.032 0.189 BQL Zinc NA 0.032 BQL 0.023 BQL BQL 0.127 BQL Copper 1.36 0.025 BQL BQL BQL BQL 0.026 BQL Mercury4 0.002 BQL BQL BQL BQL BQL 0.01 BQL Chromium (total) 0.1 0.028 BQL BQL BQL BQL 0.091 BQL Beryllium 0.004 BQL BQL BQL BQL BQL 0.004 BQL Cadmium 0.005 BQL BQL BQL BQL BQL 0.011 BQL Nickel NA BQL BQL BQL BQL BQL 0.034 BQL Lead 0.0156 BQL BQL BQL BQL BQL 0.015 BQL Vanadium NA BQL BQL BQL BQL BQL 0.060 BQL Organics2 1,1-Dichloroethane NA BQL BQL BQL 20 21 10 BQL Chlorobenzene 100 BQL BQL BQL BQL BQL 19 BQL 1,4-Dicholorbenzene 75 BQL BQL BQL BQL BQL 33 BQL Methylene chloride 5
BQL BQL BQL BQL BQL BQL BQL cis-1,2-Dichloroethene 70 BQL BQL BQL 14 14 17 BQL Trichlorofluoromethane NA BQL BQL 34 102 97 BQL BQL 1,1-Dichloroethene 7
BQL BQL BQL BQL BQL BQL BQL Xylenes (Total) 10000 BQL BQL BQL BQL BQL 10 BQL Vinyl chloride 2
BQL BQL BQL BQL BQL BQL BQL Chloroform3 0.1 BQL BQL BQL BQL BQL BQL BQL BQL - Below quantification level MCL - Maximum Contaminant Level per EPD Rule Chapter 391-3-5; NA - None available 1Metals concentrations in mg/L 2Organics concentration units in ug/l or ppb 3Applies only to Community Water Systems serving 10,000 4Appendix II parameter 5Replicate sample of well GWC-13/MW-13 sample 6Action Level Bold indicates detected concentration is greater than the MCL.
Table 4 (Continued)
Southern Nuclear Operating Company Plant Vogtle Landfill #3 Summary of Detected Parameters CONSTITUENT MCL WELL SAMPLES December 2003 Page 6 of 11
GWC-5/MW-5 GWB-6/MW-6 GWA-7/MW-7 GWC-13/MW-13 GWC-13/MW-135 GWC-14/MW-14 GWA-15/MW-15 Metals1 Barium 2.00 BQL BQL 0.036 0.029 0.030 0.051 BQL Zinc NA BQL BQL 0.034 BQL BQL BQL BQL Copper 1.3 BQL BQL 0.035 BQL BQL BQL BQL Mercury4 0.002 NS NS NS 0.0005 0.0005 0.0072 BQL Organics2 1,1-Dichloroethane NA BQL BQL BQL 9
9 10 BQL Chlorobenzene 100 BQL BQL BQL BQL BQL 7
BQL 1,4-Dicholorbenzene 75 BQL BQL BQL BQL BQL 16 BQL Methylene chloride 5
BQL BQL BQL BQL BQL BQL BQL cis-1,2-Dichloroethene 70 BQL BQL BQL 6
6 10 BQL Trichlorofluoromethane NA BQL BQL 23 41 47 5
BQL 1,1-Dichloroethene 7
BQL BQL BQL BQL BQL BQL BQL Xylenes (Total) 10000 BQL BQL BQL BQL BQL BQL BQL Vinyl chloride 2
BQL BQL BQL BQL BQL BQL BQL Chloroform3 0.1 BQL BQL BQL BQL BQL BQL BQL BQL - Below quantification level MCL - Maximum Contaminant Level per EPD Rule Chapter 391-3-5; NA - None available 1Metals concentrations in mg/L 2Organics concentration units in ug/l or ppb 3Applies only to Community Water Systems serving 10,000 4Appendix II parameter; NS reflects that this parameter was not analyzed for those wells not included in the Assessment Monitoring Program 5Replicate sample of well GWC-13/MW-13 sample Bold indicates detected concentration is greater than the MCL.
Table 4 (Continued)
Southern Nuclear Operating Company Plant Vogtle Landfill #3 Summary of Detected Parameters CONSTITUENT MCL WELL SAMPLES June 2003 Page 7 of 11
GWC-5/MW-5 GWB-6/MW-6 GWA-7/MW-7 GWC-13/MW-13 GWC-14/MW-14 GWA-15/MW-15 Metals1 Barium 2.00 0.018 BQL 0.015 0.082 0.106 BQL Zinc NA BQL BQL BQL 0.027 BQL BQL Organics2 1,1-Dichloroethane NA BQL BQL BQL 7
16 BQL Chlorobenzene 100 BQL BQL BQL BQL 10 BQL 1,4-Dicholorbenzene 75 BQL BQL BQL BQL 39 BQL Methylene chloride 5
BQL BQL BQL BQL BQL BQL cis-1,2-Dichloroethene 70 BQL BQL BQL BQL 19 BQL Trichlorofluoromethane NA BQL BQL 210 391 27 BQL 1,1-Dichloroethene 7
BQL BQL BQL 11 24 BQL Xylenes (Total) 10000 BQL BQL BQL BQL 21 BQL Vinyl chloride 2
BQL BQL BQL BQL 4
BQL Chloroform3 0.1 BQL BQL BQL 5
BQL BQL BQL - Below quantification level MCL - Maximum Contaminant Level per EPD Rule Chapter 391-3-5; NA - None available 1Metals concentrations in mg/L 2Organics concentration units in ug/l or ppb 3Applies only to Community Water Systems serving 10,000 Bold indicates detected concentration is greater than the MCL.
Table 4 (Continued)
Southern Nuclear Operating Company Plant Vogtle Landfill #3 Summary of Detected Parameters CONSTITUENT MCL WELL SAMPLES December 2002 Page 8 of 11
GWC-5/MW-5 GWB-6/MW-6 GWA-7/MW-7 GWC-13/MW-13 GWC-14/MW-14 GWA-15/MW-15 GWA-15-2/MW-15-23 Metals1 Barium BQL BQL BQL 0.083 0.064 BQL BQL Zinc BQL BQL BQL 0.027 BQL BQL BQL Organics2 1,1-Dichloroethane NA BQL BQL BQL 6
17 BQL BQL Chlorobenzene 100 BQL BQL BQL BQL 9
BQL BQL 1,4-Dicholorbenzene 75 BQL BQL BQL BQL 35 BQL BQL Methylene chloride 5
BQL BQL BQL BQL 11 BQL BQL cis-1,2-Dichloroethene 70 BQL BQL BQL BQL 16 BQL BQL Trichlorofluoromethane NA BQL BQL 221 348 31 BQL BQL 1,1-Dichloroethene 7
BQL BQL BQL BQL BQL BQL BQL Xylenes (Total) 10000 BQL BQL BQL BQL 11 BQL BQL Vinyl chloride 2
BQL BQL BQL BQL BQL BQL BQL BQL - Below quantification level MCL - Maximum Contaminant Level per EPD Rule Chapter 391-3-5; NA - None available 1Metals concentrations in mg/L 2Organics concentration units in ug/l or ppb 3Replicate sample of GWA-15//MW-15 well Bold indicates detected concentration is greater than the MCL.
CONSTITUENT MCL WELL SAMPLES Table 4 (Continued)
Southern Nuclear Operating Company Plant Vogtle Landfill #3 Summary of Detected Parameters October 2002 Page 9 of 11
GWC-5/MW-5 GWB-6/MW-6 GWA-7/MW-7 GWC-13/MW-13 GWC-14/MW-14 GWC-14-2/MW-14-23 GWA-15/MW-15 Metals1 Barium 2
0.020 BQL BQL 0.085 0.092 0.095 BQL Zinc NA BQL BQL BQL 0.023 BQL BQL BQL Organics2 1,1-Dichloroethane NA BQL BQL BQL 6
21 21 BQL Chlorobenzene 100 BQL BQL BQL BQL 8
8 BQL 1,4-Dichlorobenzene 75 BQL BQL BQL BQL 37 36 BQL Methylene chloride 5
BQL BQL BQL BQL BQL BQL BQL cis-1,2-Dichloroethene 70 BQL BQL BQL BQL 19 18 BQL Trichlorofluoromethane NA BQL BQL 32 381 47 48 BQL 1,1-Dichloroethene 7
BQL BQL BQL 8
29 28 BQL Xylenes (Total) 10000 BQL BQL BQL BQL 23 23 BQL Vinyl chloride 2
BQL BQL BQL BQL BQL 3
BQL BQL - Below quantification level MCL - Maximum Contaminant Level per Georgia EPD Rule Chapter 391-3-5; NA - None available 1Metals concentrations in mg/L 2Organics concentration units in ug/l or ppb 3Replicate sample of GWB-14//MW-14 well sample Bold indicates detected concentration is greater than the MCL.
CONSTITUENT MCL WELL SAMPLES Table 4 (Continued)
Southern Nuclear Operating Company Plant Vogtle Landfill #3 Summary of Detected Parameters September 2002 Page 10 of 11
GWC-5/MW-5 GWB-6/MW-6 GWA-7/MW-7 GWA-7-2/MW-7-23 GWC-13/MW-13 GWC-14/MW-14 GWA-15/MW-15 Metals1 Barium 2
BQL BQL BQL BQL 0.077 0.068 BQL Zinc NA BQL BQL BQL BQL BQL BQL BQL Organics2 1,1-Dichloroethane NA BQL BQL BQL BQL BQL 13 BQL Chlorobenzene 100 BQL BQL BQL BQL BQL BQL BQL 1,4-Dichlorobenzene 75 BQL BQL BQL BQL BQL 20 BQL Methylene chloride 5
9 6
8 7
8 8
BQL cis-1,2-Dichloroethene 70 BQL BQL BQL BQL BQL 10 BQL Trichlorofluoromethane NA BQL BQL 177 192 300 43 BQL 1,1-Dichloroethene 7
BQL BQL BQL BQL BQL BQL BQL Xylenes (Total) 10000 BQL BQL BQL BQL BQL 8
BQL Vinyl chloride 2
BQL BQL BQL BQL BQL BQL BQL BQL - Below quantification level MCL - Maximum Contaminant Level per Georgia EPD Rule Chapter 391-3-5; NA - None available 1Metals concentrations in mg/L 2Organics concentration units in ug/l or ppb 3Replicate sample of GWA-7/MW-7 well sample Bold indicates detected concentration is greater than the MCL.
CONSTITUENT MCL WELLS1 Table 4 (Continued)
Southern Nuclear Operating Company Plant Vogtle Landfill #3 Summary of Detected Parameters July 2002 Page 11 of 11
FIGURE
I W....'lTF.Ml1NAGIiMF.mUNIT/BUl'P!'.*
BOl=AIl.Y!I!AJ.KFJl.
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ARANDQl'l1'D SOIT..\\lOJUNG f'O'n'!'I'IlQMET1UCro~L'lI.l1NP.
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~~
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~~~~
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APPENDIX A - HYDRAULIC GRADIENT CALCULATION SHEETS
Plant Vogtle Landfill #3 Gradient Calculation (based on three-point problem)
June 2006 Monitoring Event Well Designation Water Table Elevation Northing Easting GWC-5/MW-5 204.11 9604.30 7999.33 GWB-6/MW-6 231.49 9432.48 7473.25 GWA-7/MW-7 229.59 8826.22 7657.89 GWC-13/MW-13 233.11 9242.72 7995.86 GWC-14/MW-14 209.85 8960.64 7999.10 GWA-15/MW-15 223.83 8975.71 6886.73 GWC-17/MW-17 150.03 8553.09 8135.59 GWC-18/MW-18 DRY 8938.05 8238.63 Gradient Calculation from fitting a plane to three points a x1 + b y1 + cz1 + d = 0 a x2 + b y2 + cz2 + d = 0 a x3 + b y3 + cz3 + d = 0 where (xi,yi) are the coordinates of the well and zi is the head, i = 1,2,3 The gradient is calculated from the square root of (a2 + b2)
Southwest Gradient Wells of Interest = (GWB-6, GWA-7 & GWA-15)
(High-Mid-Low) x y
z GWB-6/MW-6 9432.48 7473.25 231.49 GWA-7/MW-7 8826.22 7657.89 229.59 GWA-15/MW-15 8975.71 6886.73 223.83 7473.25 231.49 1
a =
7657.89 229.59 1
=
-2528.73 6886.73 223.83 1
9432.48 231.49 1
b =
8826.22 229.59 1
=
3776.0886 8975.71 223.83 1
9432.48 7473.25 1
c =
8826.22 7657.89 1
=
439921.63 8975.71 6886.73 1
9432.48 7473.25 231.49 d =
8826.22 7657.89 229.59
=
49765605 8975.71 6886.73 223.83 z0 =
-113.1237963 mx =
0.005748138 my =
-0.008583548 Southwest Gradient =
0.010 Page 1 of 3
Plant Vogtle Landfill #3 Gradient Calculation (based on three-point problem)
Northeast Gradient Wells of Interest = (GWC-13, GWB-6 & GWC-5)
(High-Mid-Low) x y
z GWC-13/MW-13 9242.72 7995.86 233.11 GWB-6/MW-6 9432.48 7473.25 231.49 GWC-5/MW-5 9604.30 7999.33 204.11 7995.86 233.11 1
a =
7473.25 231.49 1
=
15161.311 7999.33 204.11 1
9242.72 233.11 1
b =
9432.48 231.49 1
=
-4917.28 9604.30 204.11 1
9242.72 7995.86 1
c =
9432.48 7473.25 1
=
189623.79 9604.30 7999.33 1
9242.72 7995.86 233.11 d =
9432.48 7473.25 231.49
=
223652844 9604.30 7999.33 204.11 z0 =
-1179.455608 mx =
-0.07995469 my =
0.025931769 Northeast Gradient =
0.08 Page 2 of 3
Plant Vogtle Landfill #3 Gradient Calculation (based on three-point problem)
Southeast Gradient Wells of Interest = (GWC-13, GWA-7 & GWC-14)
(High-Mid-Low) x y
z GWC-13/MW-13 9242.72 7995.86 233.11 GWA-7/MW-7 8826.22 7657.89 229.59 GWC-14/MW-14 8960.64 7999.10 209.85 7995.86 233.11 1
a =
7657.89 229.59 1
=
7872.587 7999.10 209.85 1
9242.72 233.11 1
b =
8826.22 229.59 1
=
8694.8684 8960.64 209.85 1
9242.72 7995.86 1
c =
8826.22 7657.89 1
=
-96684.04 8960.64 7999.10 1
9242.72 7995.86 233.11 d =
8826.22 7657.89 229.59
=
-19296849 8960.64 7999.10 209.85 z0 =
-199.5867116 mx =
0.081425923 my =
0.089930754 Southeast Gradient =
0.12 Page 3 of 3
APPENDIX B - LABORATORY ANALYTICAL REPORT JUNE 2006
ADVANCED CHEMISTRY LABS, INC.
.:I ACL I Phone: (770) 4~09~-~14~4~4----------------~3~0~39~A~m-w~ile-r~R!""'0-ad~'
~Su~it-e~1~0~0-'~A~tla-n-ta-,~G~A-3~0~3~6~0-Fax: (770) 409-1844 P.O. Box 88610' Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Laboratory Report ACL Project #:
50727 Client Proj #:
Vogtle LF #3 Prepared For:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Attention: Mr. Kurt Batsel Report Date:
07/06/2006 This report contains 78 pages.
(including this cover page and chain of custody)
~
John An os Technical Director Advanced Chemistry Labs is a woman owned small business concern.
If you have any questions concerning this report, please do not hesitate to call us at (770) 409-1444.
This report may not be reproduced, except in full, without the written permission of ACL (Advanced Chemistry Labs, Inc).
ACL certifies that the following analytical results meet all the requirements of NELAC.
ACL is accredited by the National Environmental Laboratory Accreditation Program (NELAP).
ACL maintains the following certifications: NELAC (E87212), South Carolina (98009001), North Carolina (362), Florida (E87212),
USDA Soil Import License (S-36503).
Page 1 of 78
IACL 1~~
A_D_VA_N_C_'E~1J~C_'H~E~M_IS~T~'R~Y~L~A~B~S~, ~IN~C~.
Phone: (770) 409-1444 3039 Amwiler Road, Suite 100, Atlanta, GA 30360 Fax: (770) 409-1844 P. O. Box 88610, Atlanta, GA 30356 e-mail: acl@acl-Iabs.net Data Qualifier Codes Code A
S SQL OW E
H J
PQL TIC Description Value reported is the mean of two or more determinations; Indicates the analyte was detected in the sample and method blank; Below practical quantitation limit; Results reported on a dry-weight basis (ex: mg/kg,dw);
Estimated value: (i) sample received or analyzed beyond the accepted holding time; (ii) sample received at improper temperature; (iii) the continuing calibration for an analyte did not meet qc criteria; Estimated value; result higher than the highest calibration standard; Reported value is between the method detection limit and the practical quantitation limit; Practical quantitation limit; Tentatively identified compound; Not analyzed due to interferences; Upon client request, a statement of the test result estimated uncertainty can be provided.
NOTE: Unless otherwise noted, all results are reported on an as received basis.
Page 2 of 78
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRY LABS, INC.
3039 Amwiler Road* Suite 100
- Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 v.o. (50308/82608) - Appendix I Sample ID:
GWC-5/MW-5 Matrix:
Water Date Sampled:
06/05/2006 Date Extracted:
Date Analyzed:
06/12/2006 ACL Sample #: 244061 Units:
IJg/L Analyst:
JA Analyte Result PQL Analyte Result PQL Acetone SOL 100 Styrene SOL 5
Acrylonitrile SOL 50 1,1,1,2-Tetrachloroethane SOL 5
Senzene SOL 5
1,1,2,2-Tetrachloroethane SOL 5
Sromochloromethane SOL 5
Tetrachloroethene SOL 5
Sromodichloromethane SOL 5
Toluene SOL 5
Sromoform SOL 5
1,1,1-Trichloroethane SOL 5
Carbon disulfide SOL 5
1,1,2-Trichloroethane SOL 5
Carbon tetrachloride SOL 5
Trichloroethene SOL 5
Chlorobenzene SOL 5
Trichlorofluoromethane SOL 5
Chloroethane SOL 10 1,2,3-Trichloropropane SOL 5
Chloroform SOL 5
Vinyl acetate SOL 50 1,2-Dibromo-3-chloropropane SOL 20 Vinyl chloride SOL 2
Dibromochloromethane SOL 5
m & p-Xylenes SOL 10 1,2-Dibromoethane SOL 5
o-Xylene SOL 5
trans-1,4-Dichloro-2-butene SOL 10 1,2-Dichlorobenzene SOL 5
1A-Dichlorobenzene SOL 5
1,1-Dichloroethane SOL 5
1,2-Dichloroethane SOL 5
1,1-Dichloroethene SOL 5
cis-1,2-Dichloroethene SOL 5
trans-1,2-Dichloroethene SOL 5
1,2-Dichloropropane SOL 5
cis-1,3-Dichloropropene SOL 5
trans-1,3-Dichloropropene SOL 5
Ethylbenzene SOL 5
2-Hexanone SOL 50 Methyl bromide SOL 10 Methyl chloride SOL 10 Methyl ethyl ketone SOL 100 Methyl iodide SOL 5
4-Methyl-2-pentanone SOL 50 Methylene bromide SOL 5
Methylene chloride SOL 5
Page 3 of 78
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRY LABS, INC.
3039 Amwiler Road* Suite 100
- Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Miscellaneous Organics (8011) - Appendix II Sample 10:
GWC-5/MW-5 Matrix:
Water Date Sampled:
06/05/2006 Date Extracted:
06/12/2006 Date Analyzed:
06/14/2006 ACL Sample #: 244061 Units:
IJg/L Analyst:
AD Analyte 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Result SQL SQL PQL 0.20 0.05 Page 4 of 78
IACL 1~
A_D_Jt:_'A_Nl"!""""C~'E_D~C_'H~E_'M~Z~S_TR~Y_LA_B~S_,,,!,,,,,,,,IN
.......C_.
Phone: (770) 409-1444 3039 Amwiler Road* Suite 100* Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Appendix I Metals (60108/7841/7041)
ACL Sample #: 244061 Units:
mg/L Analyte Result PQL Antimony Sal 0.006 Arsenic Sal 0.010 Sarium 0.031 0.020 Seryllium Sal 0.004 Cadmium Sal 0.005 Chromium Sal 0.020 Cobalt Sal 0.050 Copper Sal 0.020 lead Sal 0.010 Nickel Sal 0.020 Selenium Sal 0.040 Silver Sal 0.010 Thallium Sal 0.002 Vanadium Sal 0.050 Zinc 0.100 0.020 Sample 10:
GWC-5/MW-5 Matrix:
Date Sampled:
Date Extracted:
Date Analyzed:
Analyst:
Water 06/05/2006 06/12/2006 AD Page 5 of 78
.I ACL 1~~
A_D_~_:4~N~CE~'D~C~'H_EM~IS~T.~'R~Y~L~A~B~S,~IN~C.
Phone: (770) 409-1444 3039 Amwiler Road* Suite 100* Atlanta, GA 30360 Fax: (770) 409*1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
The Dextra Group Client Proj #:
Vogtle IF #3 1205 Johnson Ferry Rd.
ACL Project #:
50727 Suite 136-446 Date Received:
06/08/2006 Marietta, GA 30068-0000 Date Reported:
07106/2006
Contact:
Mr. Kurt Satsel Date Sample 10 ACL#
Analyte Matrix Result PQL Units Analyzed GWC-5/MW-5 244061 Mercury (7470A)
Water Sal 0.0005 mg/l 06/12/2006 Page 6 of 78
IACL 1
AD-VA-N
.....C
......'E__D C......'H-E-'M......IS-T.....'R__y-L-A-B......S-,...../N......C_.
Phone: (770) 409-1444 3039 Amwiler Road* Suite 100* Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 v.o. (50308/82608) - Appendix I Sample ID:
GWC-6/MW-6 Matrix:
Water Date Sampled:
06/05/2006 Date Extracted:
Date Analyzed:
06/12/2006 ACL Sample #: 244062 Units:
1J9/L Analyst:
JA Analyte Result PQL Analyte Result PQL Acetone SOL 100 Styrene SOL 5
Acrylonitrile SOL 50 1,1,1,2-Tetrachloroethane SOL 5
Senzene SOL 5
1,1,2,2-Tetrachloroethane SOL 5
Sromochloromethane SOL 5
Tetrachloroethene SOL 5
Sromodichloromethane SOL 5
Toluene SOL 5
Sromoform SOL 5
1,1,1-Trichloroethane SOL 5
Carbon disulfide SOL 5
1,1,2-Trichloroethane SOL 5
Carbon tetrachloride SOL 5
Trichloroethene SOL 5
Chlorobenzene SOL 5
Trichlorofluoromethane SOL 5
Chloroethane SOL 10 1,2,3-Trichloropropane SOL 5
Chloroform SOL 5
Vinyl acetate SOL 50 1,2-Dibromo-3-chloropropane SOL 20 Vinyl chloride SOL 2
Dibromochloromethane SOL 5
m &p-Xylenes SOL 10 1,2-Dibromoethane SOL 5
o-Xylene SOL 5
trans-1,4-Dichloro-2-butene SOL 10 1,2-Dichlorobenzene SOL 5
1,4-Dichlorobenzene SOL 5
1,1-Dichloroethane SOL 5
1,2-Dichloroethane SOL 5
1,1-Dichloroethene SOL 5
cis-1,2-Dichloroethene SOL 5
trans-1,2-Dichloroethene SOL 5
1,2-Dichloropropane SOL 5
cis-1,3-Dichloropropene SOL 5
trans-1,3-Dichloropropene SOL 5
Ethylbenzene SOL 5
2-Hexanone SOL 50 Methyl bromide SOL 10 Methyl chloride SOL 10 Methyl ethyl ketone SOL 100 Methyl iodide Sal 5
4-Methyl-2-pentanone SOL 50 Methylene bromide SOL 5
Methylene chloride SOL 5
Page 7 of 78
~
IACL 1~
A_D_Jt':_:4_N"""",,"C.-.-'E~1J~C_'H~E~'M~J.~S_TR~Y-.-LA_B~S~, """",,"IN~C_.
Phone: (770) 409-1444 3039 Amwiler Road* Suite 100* Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACl Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Miscellaneous Organics (8011) - Appendix II Sample 10:
GWC-6/MW-6 Matrix:
Water Date Sampled:
06/05/2006 Date Extracted:
06/12/2006 Date Analyzed:
06/14/2006 ACl Sample #: 244062 Units:
1J9/L Analyst:
AD Analyte 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Result BQL BQL PQl 0.20 0.05 Page 8 of 78
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRY LABS, INC.
3039 Amwiler Road* Suite 100* Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Appendix I Metals (60108/7841/7041)
ACL Sample #: 244062 Units:
mg/L Analyte Result PQL Antimony SOL 0.006 Arsenic SOL 0.010 Sarium SOL 0.020 Seryllium SOL 0.004 Cadmium SOL 0.005 Chromium SOL 0.020 Cobalt SOL 0.050 Copper SOL 0.020 lead SOL 0.010 Nickel SOL 0.020 Selenium SOL 0.040 Silver SOL 0.010 Thallium SOL 0.002 Vanadium SOL 0.050 Zinc 0.083 0.020 Sample 10:
GWC-6/MW-6 Matrix:
Date Sampled:
Date Extracted:
Date Analyzed:
Analyst:
Water 06/05/2006 06/12/2006 AD Page 9 of 78
'I ACL I Phone: (770) 409-1444 Fax: (770) 409*1844 e-mail: acl@acl-labs.net ADVANCED CHEMISTRYLABS, INC.
3039 Amwiler Road
- Suite 100
- Atlanta. GA 30360 P.O. Box 88610* Atlanta. GA 30356 www.advancedchemistrylabs.com Client:
The Dextra Group Client Proj #:
Vogtle IF #3 1205 Johnson Ferry Rd.
ACL Project #:
50727 Suite 136-446 Date Received:
06/08/2006 Marietta. GA 30068-0000 Date Reported:
07/06/2006
Contact:
Mr. Kurt Satsel Date Sample 10 ACL#
Analyte Matrix Result PQL Units Analyzed GWC-6/MW-6 244062 Mercury (7470A)
Water Sal 0.0005 mg/l 06/12/2006 Page 10 of 78
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRY LABS, INC.
3039 Amwiler Road' Suite 100' Atlanta, GA 30360 P.O. Box 88610' Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
The Dextra Group Client Proj #:
Vogtle LF #3 1205 Johnson Ferry Rd.
ACl Project #:
50727 Suite 136-446 Date Received:
06/08/2006 Marietta, GA 30068-0000 Date Reported:
07/06/2006
Contact:
Mr. Kurt Batsel v.a. (50308/82608) - Appendix II Sample 10:
GWA-7/MW-7 Matrix:
Water Date Sampled:
06/05/2006 Date Extracted:
Date Analyzed:
06/12/2006 ACl Sample #: 244063 Units:
IJg/L Analyst:
JA Analyte Result PQl Analyte Result PQl Acetone SaL 100 Ethyl methacrylate SaL 10 Acetonitrile SaL 100 Ethylbenzene saL 5
Acrolein SaL 100 2-Hexanone saL 50 Acrylonitrile SaL 50 Isobutyl alcohol SaL 50 Allyl chloride SaL 10 Methacrylonitrile saL 100 Senzene saL 5
Methyl bromide SaL 10 Sromochloromethane saL 5
Methyl chloride SaL 10 Sromodichloromethane saL 5
Methyl ethyl ketone SaL 100 Sromoform saL 5
Methyl iodide SaL 5
Carbon disulfide SaL 5
Methyl methacrylate SaL 30 Carbon tetrachloride SaL 5
4-Methyl-2-pentanone Sal 50 Chlorobenzene sal 5
Methylene bromide Sal 5
Chloroethane sal 10 Methylene chloride Sal 5
Chloroform Sal 5
Naphthalene 5
5 Chloroprene Sal 20 Propionitrile Sal 150 1,2-Dibromo-3-chloropropane sal 20 Styrene Sal 5
Dibromochloromethane sal 5
1,1,1,2-Tetrachloroethane sal 5
1,2-Dibromoethane sal 5
1,1,2,2-Tetrachloroethane sal 5
trans-1 A-Dichloro-2-butene sal 10 Tetrachloroethene sal 5
1,2-Dichlorobenzene sal 5
Toluene Sal 5
1,3-Dichlorobenzene sal 5
1,1,1-Trichloroethane Sal 5
1A-Dichlorobenzene Sal 5
1,1,2-Trichloroethane sal 5
Dichlorodifluoromethane SOL 5
Trichloroethene sal 5
1,1-Dichloroethane saL 5
Trichlorofluoromethane 66 5
1,2-Dichloroethane saL 5
1,2,3-Trichloropropane SOL 5
1,1-Dichloroethene SOL 5
Vinyl acetate Sal 50 cis-1,2-Dichloroethene SOL 5
Vinyl chloride Sal 2
trans-1,2-Dichloroethene sal 5
m & p-Xylenes sal 10 1,2-Dichloropropane sal 5
o-Xylene SOL 5
1,3-Dichloropropane sal 5
2,2-Dichloropropane SOL 15 1,1-Dichloropropene sal 5
cis-1,3-Dichloropropene SOL 5
trans-1,3-Dichloropropene sal 5
Page 11 of 78
IACL 1~
A_D_VA_N~C~'E~1J~C-='H_E~M~IS~T~'R~Y~L~A~B~S~, l~N~C_.
Phone: (770) 409-1444 3039 Amwiler Road* Suite 100* Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACl Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Acid Extractables (8270C) - Appendix II ACl Sample #: 244063 Units:
IJg/L Analyte Result pal 4-Chloro-3-methylphenol Sal 20 2-Chlorophenol Sal 10 m & p-Cresol Sal 10 o-Cresol Sal 10 2,4-Dichlorophenol Sal 10 2,6-Dichlorophenol Sal 10 2,4-Dimethylphenol Sal 10 4,6-Dinitro-2-methylphenol Sal 50 2,4-Dinitrophenol Sal 50 2-Nitrophenol Sal 10 4-Nitrophenol Sal 50 Pentachlorophenol Sal 50 Phenol Sal 10 2,3,4,6-Tetrachlorophenol Sal 10 2,4,5-Trichlorophenol Sal 10 2,4,6-Trichlorophenol Sal 10 Sample ID:
GWA-7/MW-7 Matrix:
Date Sampled:
Date Extracted:
Date Analyzed:
Analyst:
Water 06/05/2006 06/12/2006 06/13/2006 RB Page 12 of 78
IACL I c
Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRY LABS, INC.
3039 Amwiler Road* Suite 100* Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACl Project #:
Date Received:
Date Reported:
Vogtle IF #3 50727 06/08/2006 07/06/2006 Base Neutral Extractables (8270C) - Appendix II Sample 10:
GWA-7/MW-7 Matrix:
Water Date Sampled:
06/05/2006 Date Extracted:
06/12/2006 Date Analyzed:
06/13/2006 ACl Sample #: 244063 Units:
~g/L Analyst:
RB Analyte Result pal Analyte Result pal Acenaphthene SOL 10 Dimethyl phthalate SOL 10 Acenaphthylene SOL 10 p-(Dimethylamino)azobenzene SOL 10 Acetophenone SOL 10 7,12-Dimethylbenz(a)anthracene SOL 10 2-Acetylaminofluorene SOL 20 3,3'-Dimethylbenzidine SOL 10 4-Aminobiphenyl SOL 20 m-Dinitrobenzene SOL 20 Anthracene SOL 10 2,4-Dinitrotoluene SOL 10 Senzo(a)anthracene SOL 10 2,6-Dinitrotoluene SOL 10 Senzo(a)pyrene SOL 10 Diphenylamine SOL 10 Senzo(b)fluoranthene SOL 10 Disulfoton SOL 10 Senzo(g,h,i)perylene SOL 10 Ethyl methanesulfonate SOL 20 Senzo(k)fluoranthene SOL 10 Famphur SOL 20 Senzyl alcohol SOL 20 Fluoranthene SOL 10 Sis(2-chloroethoxy)methane SOL 10 Fluorene SOL 10 Sis(2-chloroethyl)ether SOL 10 Hexachlorobenzene SOL 10 Sis(2-chloroisopropyl)ether SOL 10 Hexachlorobutadiene SOL 10 Sis(2-ethylhexyl)phthalate SOL 10 Hexachlorocyclopentadiene SOL 10 4-Sromophenyl phenyl ether SOL 10 Hexachloroethane SOL 10 Sutyl benzyl phthalate SOL 10 Hexachloropropene SOL 10 p-Chloroaniline SOL 20 Indeno(1,2,3-cd)pyrene SOL 10 Chlorobenzilate SOL 10 Isodrin SOL 20 2-Chloronaphthalene SOL 10 Isophorone SOL 10 4-Chlorophenyl phenyl ether SOL 10 Isosafrole SOL 10 Chrysene SOL 10 Kepone SOL 20 Di-n-butyl phthalate SOL 10 Methapyrilene SOL 100 Di-n-octyl phthalate SOL 10 Methyl methanesulfonate SOL 10 Diallate SOL 10 Methyl parathion SOL 10 Dibenz(a,h)anthracene SOL 10 3-Methylcholanthrene SOL 10 Dibenzofuran SOL 10 2-Methylnaphthalene SOL 10 1,2-Dichlorobenzene SOL 10 Naphthalene SOL 10 1,3-Dichlorobenzene SOL 10 1,4-Naphthoquinone SOL 10 1A-Dichlorobenzene SOL 10 1-Naphthylamine SOL 10 3,3'-Dichlorobenzidine SOL 20 2-Naphthylamine SOL 10 Diethyl phthalate SOL 10 5-Nitro-o-toluidine SOL 10 Dimethoate SOL 10 2-Nitroaniline SOL 50 Page 13 of 78
- ~ - - ~ --------
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRY LABS, INC.
3039 Amwiler Road' Suite 100
- Atlanta, GA 30360 P.O. Box 88610' Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Base Neutral Extractables (8270C) - Appendix II Sample 10:
GWA-7/MW-7 Matrix:
Water Date Sampled:
06/05/2006 Date Extracted:
06/12/2006 Date Analyzed:
06/13/2006 ACL Sample #: 244063 Units:
IJg/L Analyst:
RB Analyte 3-Nitroaniline 4-Nitroaniline Nitrobenzene N-Nitroso-di-n-butylamine N-Nitrosodiethylamine N-Nitrosodimethylamine N-Nitrosodiphenylamine N-Nitrosodipropylamine N-Nitrosomethylethylamine N-Nitrosopiperidine N-Nitrosopyrrolidine Parathion Pentachlorobenzene Pentachloronitrobenzene Phenacetin Phenanthrene p-Phenylenediamine Phorate Pronamide pyrene Safrole 1,2,4,5-Tetrachlorobenzene Thionazin o-Toluidine 1,2,4-Trichlorobenzene 0,0,0-Triethyl phosphorothioate 1,3,5-Trinitrobenzene Result SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL PQL 50 20 10 10 20 10 10 10 10 20 40 20 10 20 20 10 10 10 10 10 10 10 20 10 10 50 10 Page 14 of 78
IACL 1~
A_D_J-':_:4_N~C~'E~1J~C:--'H~E~M~I.~S~TR~Y~LA~B~S~,~IN~C~.
Phone: (770) 409-1444 3039 Amwiler Road' Suite 100' Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610' Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACl Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Pesticides/PCBs (8081A18082) - Appendix II ACl Sample #: 244063 Units:
IJg/L Analyte Result pal Aldrin Sal 0.05 Arochlor-1016 Sal 0.50 Arochlor-1221 Sal 0.50 Arochlor-1232 Sal 0.50 Arochlor-1242 Sal 0.50 Arochlor-1248 Sal 0.50 Arochlor-1254 Sal 0.50 Arochlor-1260 Sal 0.50 a-SHC Sal 0.05 b-SHC Sal 0.05 d-SHC Sal 0.05 g-SHC Sal 0.05 Chlordane Sal 0.10 4,4'-DDD Sal 0.05 4,4'-DDE Sal 0.05 4,4'-DDT Sal 0.05 Dieldrin Sal 0.05 Endosulfan I Sal 0.05 Endosulfan II Sal 0.05 Endosulfan sulfate Sal 0.05 Endrin Sal 0.05 Endrin aldehyde Sal 0.05 Heptachlor Sal 0.05 Heptachlor epoxide Sal 0.05 Methoxychlor Sal 0.05 Toxaphene Sal 2.00 Sample 10:
GWA-7/MW-7 Matrix:
Date Sampled:
Date Extracted:
Date Analyzed:
Analyst:
Water 06/05/2006 06/12/2006 06/20/2006 AM Page 15 of 78
ADVANCED CHEMISTRY LABS, INC.
IACL I Phone: (770) 40~9~-1~4~44~-------------~3~0~39~A~m-w~i1-er~R~o-ad~.
S~u~ite~1O~O-*~A~t1a-n~ta~,G~A~30~3~60~
Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Chlorinated Herbicides (8151A) - Appendix II ACL Sample #: 244063 Units:
j.Jg/L Analyte Result PQL 2,4-0 SQL 1.0 Oinoseb SQL 1.0 2,4,5-TP (Silvex)
SQL 1.0 2,4,5-T SQL 1.0 Sample 10:
GWA-7/MW-7 Matrix:
Water Date Sampled:
06/05/2006 Date Extracted:
06/08/2006 Date Analyzed:
06/23/2006 Analyst:
AM Page 16 of 78
IACL 1
A-D-~-:4-N-C-'E-'D-C-'H....E-M
......L-S-TR-Y-LA-B......S-,__INC_.
Phone: (770) 409-1444 3039 Amwiler Road* Suite 100* Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACl Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Miscellaneous Organics (8011)
- Appendix II Sample 10:
GWA-7/MW-7 Matrix:
Water Date Sampled:
06/05/2006 Date Extracted:
06/12/2006 Date Analyzed:
06/14/2006 ACl Sample #: 244063 Units:
IJg/L Analyst:
AD Analyte 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Result Sal Sal PQl 0.20 0.05 Page 17 of 78
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRY LABS, INC.
3039 Amwiler Road* Suite 100* Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 w.wv.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Appendix II Metals (6010B/7470Al7841/7041)
ACL Sample #: 244063 Units:
mg/L Analyte Result PQL Antimony Sal 0.006 Arsenic Sal 0.010 Sarium Sal 0.020 Seryllium Sal 0.004 Cadmium Sal 0.005 Chromium Sal 0.020 Cobalt Sal 0.050 Copper Sal 0.020 lead Sal 0.010 Mercury Sal 0.0005 Nickel Sal 0.020 Selenium Sal 0.040 Silver Sal 0.010 Thallium Sal 0.002 Tin Sal 0.025 Vanadium Sal 0.050 Zinc 0.484 0.020 Sample 10:
GWA-7/MW-7 Matrix:
Date Sampled:
Date Extracted:
Date Analyzed:
Analyst:
Water 06/05/2006 06/12/2006 AD/JR Page 18 of 78
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRY LABS, INC.
3039 Amwiler Road* Suite 100
- Atlanta, GA 30360 P.O. Box 88610' Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
The Dextra Group Client Proj #:
Vogtle LF #3 1205 Johnson Ferry Rd.
ACl Project #:
50727 Suite 136-446 Date Received:
06/08/2006 Marietta, GA 30068-0000 Date Reported:
07/06/2006
Contact:
Mr. Kurt Satsel Date Sample 10 ACl#
Analyte Matrix Result PQl Units Analyzed GWA-7/MW-7 244063 Cyanide (9012A)
Water SOL 0.020 mg/L 06/15/2006 GWA-7/MW-7 244063 Sulfide (9034)
Water SOL 1.0 mg/L 06/12/2006 Page 19 of 78
IACL 1~
A_D_V:_:4_N~C.......'E~'D--.C_'H~E_'M~Z~S_TR~Y-.-LA_B~S~,~IN~C_.
Phone: (770) 409-1444 3039 Amwiler Road* Suite 100* Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
The Dextra Group Client Proj #:
Vogtle LF #3 1205 Johnson Ferry Rd.
ACL Project #:
50727 Suite 136-446 Date Received:
06/08/2006 Marietta, GA 30068-0000 Date Reported:
07/06/2006
Contact:
Mr. Kurt Batsel V.O. (50308/82608) - Appendix II Sample 10:
GWA-7/MW-7 (DUP)
Matrix:
Water Date Sampled:
06/05/2006 Date Extracted:
Date Analyzed:
06/12/2006 ACl Sample #: 244064 Units:
IJg/L Analyst:
JA Analyte Result pal Analyte Result pal Acetone SOL 100 Ethyl methacrylate SOL 10 Acetonitrile SOL 100 Ethylbenzene SOL 5
Acrolein SOL 100 2-Hexanone SOL 50 Acrylonitrile SOL 50 Isobutyl alcohol SOL 50 Allyl chloride SOL 10 Methacrylonitrile SOL 100 Senzene SOL 5
Methyl bromide SOL 10 Sromochloromethane SOL 5
Methyl chloride SOL 10 Sromodichloromethane SOL 5
Methyl ethyl ketone SOL 100 Sromoform SOL 5
Methyl iodide SOL 5
Carbon disulfide SOL 5
Methyl methacrylate SOL 30 Carbon tetrachloride SOL 5
4-Methyl-2-pentanone SOL 50 Chlorobenzene SOL 5
Methylene bromide SOL 5
Chloroethane SOL 10 Methylene chloride SOL 5
Chloroform SOL 5
Naphthalene SOL 5
Chloroprene SOL 20 Propionitrile SOL 150 1,2-Dibromo-3-chloropropane SOL 20 Styrene SOL 5
Dibromochloromethane SOL 5
1,1,1,2-Tetrachloroethane SOL 5
1,2-Dibromoethane SOL 5
1,1,2,2-Tetrachloroethane SOL 5
trans-1,4-Dichloro-2-butene SOL 10 Tetrachloroethene SOL 5
1,2-Dichlorobenzene SOL 5
Toluene SOL 5
1,3-Dichlorobenzene SOL 5
1,1,1-Trichloroethane SOL 5
1A-Dichlorobenzene SOL 5
1,1,2-Trichloroethane SOL 5
Dichlorodifluoromethane SOL 5
Trichloroethene SOL 5
1,1-Dichloroethane SOL 5
Trichlorofluoromethane 94 5
1,2-Dichloroethane SOL 5
1,2,3-Trichloropropane SOL 5
1,1-Dichloroethene SOL 5
Vinyl acetate SOL 50 cis-1,2-Dichloroethene SOL 5
Vinyl chloride SOL 2
trans-1,2-Dichloroethene SOL 5
m & p-Xylenes SOL 10 1,2-Dichloropropane SOL 5
o-Xylene SOL 5
1,3-Dichloropropane SOL 5
2,2-Dichloropropane SOL 15 1,1-Dichloropropene SOL 5
cis-1,3-Dichloropropene SOL 5
trans-1,3-Dichloropropene SOL 5
Page 20 of 78
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRYLABS, INC.
3039 Amwiler Road' Suite 100
- Atlanta, GA 30360 P.O. Box 88610' Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 ACL Sample #: 244064 Units:
IJg/L Analyte Result PQL 4-Chloro-3-methylphenol SQl 20 2-Chlorophenol SQl 10 m & p-Cresol SQl 10 o-Cresol SQl 10 2,4-Dichlorophenol SQl 10 2,6-Dichlorophenol SQl 10 2,4-Dimethylphenol SQl 10 4,6-Dinitro-2-methylphenol SQl 50 2,4-Dinitrophenol SQl 50 2-Nitrophenol SQl 10 4-Nitrophenol SQl 50 Pentachlorophenol SQl 50 Phenol SQl 10 2,3,4,6-Tetrachlorophenol SQl 10 2,4,5-Trichlorophenol SQl 10 2,4,6-Trichlorophenol SQl 10 Sample 10:
Acid Extractables (8270C) - Appendix II GWA-7/MW-7 (DUP)
Matrix:
Date Sampled:
Date Extracted:
Date Analyzed:
Analyst:
Water 06/05/2006 06/12/2006 06/13/2006 RB Page 21 of 78
ADVANCED CHEMISTRY LABS, INC.
IACL I Phone: (770) 40~9~-1~4~4~4---------------~30~3~9~A-m-w~ile-r~R~o-a~d -.~Su"":'it:-e~1~00~*A~t~la-nt:-a-,G~A~3~03~6~0-Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Base Neutral Extractables (8270C) - Appendix II Sample 10:
GWA-7/MW-7 (DUP)
Matrix:
Water Date Sampled:
06/05/2006 Date Extracted:
06/12/2006 Date Analyzed:
06/13/2006 ACL Sample #: 244064 Units:
f./g/L Analyst:
RB Analyte Result PQL Analyte Result PQL Acenaphthene SOL 10 Dimethyl phthalate Sal 10 Acenaphthylene Sal 10 p-(Dimethylamino)azobenzene Sal 10 Acetophenone Sal 10 7,12-Dimethylbenz(a)anthracene Sal 10 2-Acetylaminofluorene Sal 20 3,3'-Dimethylbenzidine Sal 10 4-Aminobiphenyl Sal 20 m-Dinitrobenzene Sal 20 Anthracene Sal 10 2A-Dinitrotoluene Sal 10 Senzo(a)anthracene Sal 10 2,6-Dinitrotoluene Sal 10 Senzo(a)pyrene Sal 10 Diphenylamine Sal 10 Senzo(b)fluoranthene Sal 10 Disulfoton Sal 10 Senzo(g,h,i)perylene Sal 10 Ethyl methanesulfonate Sal 20 Senzo(k)fluoranthene Sal 10 Famphur Sal 20 Senzyl alcohol Sal 20 Fluoranthene Sal 10 Sis(2-chloroethoxy)methane Sal 10 Fluorene Sal 10 Sis(2-chloroethyl)ether Sal 10 Hexachlorobenzene Sal 10 Sis(2-chloroisopropyl)ether Sal 10 Hexachlorobutadiene Sal 10 Sis(2-ethylhexyl)phthalate Sal 10 Hexachlorocyclopentadiene Sal 10 4-Sromophenyl phenyl ether Sal 10 Hexachloroethane Sal 10 Sutyl benzyl phthalate Sal 10 Hexachloropropene Sal 10 p-Chloroaniline Sal 20 Indeno(1,2,3-cd)pyrene Sal 10 Chlorobenzilate Sal 10 Isodrin Sal 20 2-Chloronaphthalene Sal 10 Isophorone Sal 10 4-Chlorophenyl phenyl ether Sal 10 Isosafrole Sal 10 Chrysene Sal 10 Kepone Sal 20 Di-n-butyl phthalate Sal 10 Methapyrilene Sal 100 Di-n-octyl phthalate Sal 10 Methyl methanesulfonate Sal 10 Diallate Sal 10 Methyl parathion Sal 10 Dibenz(a,h)anthracene Sal 10 3-Methylcholanthrene Sal 10 Dibenzofuran Sal 10 2-Methylnaphthalene Sal 10 1,2-Dichlorobenzene Sal 10 Naphthalene Sal 10 1,3-Dichlorobenzene Sal 10 1A-Naphthoquinone Sal 10 1A-Dichlorobenzene SOL 10 1-Naphthylamine SOL 10 3,3'-Dichlorobenzidine SOL 20 2-Naphthylamine Sal 10 Diethyl phthalate Sal 10 5-Nitro-o-toluidine Sal 10 Dimethoate Sal 10 2-Nitroaniline Sal 50 Page 22 of 78
--'--~------"----'--.---
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRY LABS, INC.
3039 Amwiler Road' Suite 100
- Atlanta, GA 30360 P.O. Box 88610' Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACl Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 ACl Sample #: 244064 Units:
~g/L Analyte Result PQl 3-Nitroaniline BOL 50 4-Nitroaniline SOL 20 Nitrobenzene SOL 10 N-Nitroso-di-n-butylamine SOL 10 N-Nitrosodiethylamine SOL 20 N-Nitrosodimethylamine SOL 10 N-Nitrosodiphenylamine SOL 10 N-Nitrosodipropylamine SOL 10 N-Nitrosomethylethylamine SOL 10 N-Nitrosopiperidine SOL 20 N-Nitrosopyrrolidine SOL 40 Parathion SOL 20 Pentachlorobenzene SOL 10 Pentachloronitrobenzene SOL 20 Phenacetin SOL 20 Phenanthrene SOL 10 p-Phenylenediamine SOL 10 Phorate SOL 10 Pronamide SOL 10 Pyrene SOL 10 Safrole BOL 10 1,2,4,5-Tetrachlorobenzene SOL 10 Thionazin SOL 20 o-Toluidine SOL 10 1,2,4-Trichlorobenzene SOL 10 0,0,0-Triethyl phosphorothioate SOL 50 1,3,5-Trinitrobenzene SOL 10 Sample 10:
Base Neutral Extractables (8270C) - Appendix II GWA-7/MW-7 (DUP)
Matrix:
Water Date Sampled:
06/05/2006 Date Extracted:
06/12/2006 Date Analyzed:
06/13/2006 Analyst:
RB Page 23 of 78
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRY LABS, INC.
3039 Amwiler Road* Suite 100* Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 ACL Sample #: 244064 Units:
1J9/L Analyte Result PQL Aldrin Sal 0.05 Arochlor-1016 Sal 0.50 Arochlor-1221 Sal 050 Arochlor-1232 Sal 0.50 Arochlor-1242 Sal 050 Arochlor-1248 Sal 0.50 Arochlor-1254 Sal 0.50 Arochlor-1260 Sal 0.50 a-SHC Sal 0.05 b-SHC Sal 0.05 d-SHC Sal 0.05 g-SHC Sal 0.05 Chlordane Sal 0.10 4,4'-DDD Sal 0.05 4,4'-DDE Sal 0.05 4,4'-DDT Sal 0.05 Dieldrin Sal 0.05 Endosulfan I Sal 0.05 Endosulfan II Sal 0.05 Endosulfan sulfate Sal 0.05 Endrin Sal 0.05 Endrin aldehyde Sal 0.05 Heptachlor Sal 0.05 Heptachlor epoxide Sal 0.05 Methoxychlor Sal 0.05 Toxaphene Sal 2.00 Sample 10:
Pesticides/PCBs (8081A18082) - Appendix II GWA-7/MW-7 (DUP)
Matrix:
Water Date Sampled:
06/05/2006 Date Extracted:
06/12/2006 Date Analyzed:
06/20/2006 Analyst:
AM Page 24 of 78
~---~--------- ----------
ADVANCED CHEMISTRY LABS, INC.
IACL I Phone: (770) 40~9--1"'4-44---------------""3~03!""!9"'A"'m-w~i1e-r~R"'o-ad~.~S"'u~ite-1~0~0-.
A"t~la-nt-a,~G"'A-3"0~3"60""-
Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Chlorinated Herbicides (8151A) - Appendix II ACL Sample #: 244064 Units:
IJg/L Analyte Result PQL 2,4-D SQL 1.0 Dinoseb SQL 1.0 2,4,5-TP (Silvex)
SQL 1.0 2,4,5-T SQL 1.0 Sample 10:
GWA-7/MW-7 (DUP)
Matrix:
Water Date Sampled:
06/05/2006 Date Extracted:
06/08/2006 Date Analyzed:
06/23/2006 Analyst:
AM Page 25 of 78
IA CL 1~
A_D_Jl:_:4_N~C,!",!",'E~D~C_'H~E~'M~1.~S~TR~Y-.-LA_B~S~, ~IN~C~.
Phone: (770) 409-1444 3039 Amwiler Road* Suite 100* Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Miscellaneous Organics (8011) - Appendix II Sample 10:
GWA-7/MW-7 (DUP)
Matrix:
Water Date Sampled:
06/05/2006 Date Extracted:
06/12/2006 Date Analyzed:
06/15/2006 ACL Sample #: 244064 Units:
1J9/L Analyst:
AD Analyte 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Result Sal Sal POL 0.20 0.05 Page 26 of 78
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRYLABS, INC.
3039 Amwiler Road* Suite 100
- Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 ACL Sample #: 244064 Units:
mg/L Analyte Result PQL Antimony SOL 0.006 Arsenic SOL 0.010 Sarium SOL 0.020 Seryllium SOL 0.004 Cadmium SOL 0.005 Chromium SOL 0.020 Cobalt SOL 0.050 Copper SOL 0.020 Lead SOL 0.010 Mercury SOL 0.0005 Nickel SOL 0.020 Selenium SOL 0.040 Silver SOL 0.010 Thallium SOL 0.002 Tin SOL 0.025 Vanadium SOL 0.050 Zinc 0.266 0.020 Sample 10:
Appendix II Metals (6010B/7470Al7841/7041)
GWA-7/MW-7 (DUP)
Matrix:
Water Date Sampled:
06/05/2006 Date Extracted:
Date Analyzed:
06/12/2006 Analyst:
AD/JR Page 27 of 78
- IACL 1~~
A_D_V:_:4N~CE~D~CH~EM~IS~T~'R~Y~L~A~BS~,~IN~C~*
Phone: (770) 409-1444 3039 Amwiler Road* Suite 100* Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Satsel Client Proj #:
ACl Project #:
Date Received:
Date Reported:
Vogtle IF #3 50727 06/08/2006 07/06/2006 Sample 10 GWA-7/MW-7 (DUP)
GWA-7/MW-7 (DUP)
ACl#
244064 244064 Analyte Cyanide (9012A)
Sulfide (9034)
Matrix Water Water Result Sal Sal PQl 0.020 1.0 Units mg/l mg/l Page 28 of 78 Date Analyzed 06/15/2006 06/12/2006
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRY LABS, INC.
3039 Amwiler Road* Suite 100
- Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACl Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 v.o. (50308/82608) - Appendix II Sample ID:
GWC-13/MW-13 Matrix:
Water Date Sampled:
06/05/2006 Date Extracted:
Date Analyzed:
06/12/2006 ACl Sample #: 244065 Units:
~g/L Analyst:
JA Analyte Result PQl Analyte Result PQl Acetone SOL 100 Ethyl methacrylate SOL 10 Acetonitrile SOL 100 Ethylbenzene SOL 5
Acrolein SOL 100 2-Hexanone SOL 50 Acrylonitrile SOL 50 Isobutyl alcohol SOL 50 Allyl chloride SOL 10 Methacrylonitrile SOL 100 Senzene SOL 5
Methyl bromide SOL 10 Sromochloromethane SOL 5
Methyl chloride SOL 10 Sromodichloromethane SOL 5
Methyl ethyl ketone SOL 100 Sromoform SOL 5
Methyl iodide SOL 5
Carbon disulfide SOL 5
Methyl methacrylate SOL 30 Carbon tetrachloride SOL 5
4-Methyl-2-pentanone SOL 50 Chlorobenzene SOL 5
Methylene bromide SOL 5
Chloroethane SOL 10 Methylene chloride SOL 5
Chloroform SOL 5
Naphthalene SOL 5
Chloroprene SOL 20 Propionitrile SOL 150 1,2-Dibromo-3-chloropropane SOL 20 Styrene SOL 5
Dibromochloromethane SOL 5
1,1,1,2-Tetrachloroethane SOL 5
1,2-Dibromoethane SOL 5
1,1,2,2-Tetrachloroethane SOL 5
trans-1 A-Dichloro-2-butene SOL 10 Tetrachloroethene SOL 5
1,2-Dichlorobenzene SOL 5
Toluene SOL 5
1,3-Dichlorobenzene SOL 5
1,1,1-Trichloroethane SOL 5
1A-Dichlorobenzene SOL 5
1,1,2-Trichloroethane SOL 5
Dichlorodifluoromethane SOL 5
Trichloroethene SOL 5
1,1-Dichloroethane 15 5
Trichlorofluoromethane 92 5
1,2-Dichloroethane SOL 5
1,2,3-Trichloropropane SOL 5
1,1-Dichloroethene SOL 5
Vinyl acetate SOL 50 cis-1,2-Dichloroethene 8
5 Vinyl chloride SOL 2
trans-1,2-Dichloroethene SOL 5
m & p-Xylenes SOL 10 1,2-Dichloropropane SOL 5
o-Xylene SOL 5
1,3-Dichloropropane SOL 5
2,2-Dichloropropane SOL 15 1,1-Dichloropropene SOL 5
cis-1,3-Dichloropropene SOL 5
trans-1,3-Dichloropropene SOL 5
Page 29 of 78
IACL 1~~
A_D_Ji:_:4_N~C~'Eo:--V~C~'H~E-:-M~Z~S~TR~Y~L~A~B~S~, ~IN~C_.
Phone: (770) 409-1444 3039 Amwiler Road* Suite 100' Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: aci@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Acid Extractables (8270C) - Appendix II ACL Sample #: 244065 Units:
IJg/L Analyte Result PQL 4-Chloro-3-methylphenol SOL 20 2-Chlorophenol SOL 10 m &p-Cresol SOL 10 o-Cresol SOL 10 2,4-Dichlorophenol SOL 10 2,6-Dichlorophenol SOL 10 2,4-Dimethylphenol SOL 10 4,6-Dinitro-2-methylphenol SOL 50 2,4-Dinitrophenol SOL 50 2-Nitrophenol SOL 10 4-Nitrophenol SOL 50 Pentachlorophenol SOL 50 Phenol SOL 10 2,3,4,6-Tetrachlorophenol SOL 10 2,4,5-Trichlorophenol SOL 10 2,4,6-Trichlorophenol SOL 10 Sample 10:
GWC-13/MW-13 Matrix:
Date Sampled:
Date Extracted:
Date Analyzed:
Analyst:
Water 06/05/2006 06/12/2006 06/13/2006 RB Page 30 of 78
IA CL 1~
A_D_VA_N_C~'E_1J_C~'H_E_'M__lS_T....'R.....Y_L_A_B__S......, l....N__C_.
Phone: (770) 409-1444 3039 Amwiler Road* Suite 100* Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@aci-Iabs.net www.advancedchemistrylabs.com Client:
The Dextra Group Client Proj #:
Vogtle LF #3 1205 Johnson Ferry Rd.
ACL Project #:
50727 Suite 136-446 Date Received:
06/08/2006 Marietta, GA 30068-0000 Date Reported:
07/06/2006
Contact:
Mr. Kurt Batsel Base Neutral Extractables (8270C) - Appendix II Sample 10:
GWC-13/MW-13 Matrix:
Water Date Sampled:
06/0512006 Date Extracted:
06/12/2006 Date Analyzed:
06/13/2006 ACL Sample #: 244065 Units:
IJg/L Analyst:
RB Analyte Result PQL Analyte Result PQL Acenaphthene SOL 10 Dimethyl phthalate SOL 10 Acenaphthylene SOL 10 p-(Dimethylamino)azobenzene SOL 10 Acetophenone SOL 10 7,12-Dimethylbenz(a)anthracene SOL 10 2-Acetylaminofluorene SOL 20 3,3'-Dimethylbenzidine SOL 10 4-Aminobiphenyl SOL 20 m-Dinitrobenzene SOL 20 Anthracene SOL 10 2A-Dinitrotoluene SOL 10 Senzo(a)anthracene SOL 10 2,6-Dinitrotoluene SOL 10 Senzo(a)pyrene SOL 10 Diphenylamine SOL 10 Senzo(b)fluoranthene SOL 10 Disulfoton SOL 10 Senzo(g, h, i)perylene SOL 10 Ethyl methanesulfonate SOL 20 Senzo(k)fluoranthene SOL 10 Famphur SOL 20 Senzyl alcohol SOL 20 Fluoranthene SOL 10 Sis(2-chloroethoxy)methane SOL 10 Fluorene SOL 10 Sis(2-chloroethyl)ether SOL 10 Hexachlorobenzene SOL 10 Sis(2-chloroisopropyl)ether SOL 10 Hexachlorobutadiene SOL 10 Sis(2-ethylhexyl)phthalate SOL 10 Hexachlorocyclopentadiene SOL 10 4-Sromophenyl phenyl ether SOL 10 Hexachloroethane SOL 10 Sutyl benzyl phthalate SOL 10 Hexachloropropene SOL 10 p-Chloroaniline SOL 20 Indeno(1,2,3-cd)pyrene SOL 10 Chlorobenzilate SOL 10 Isodrin SOL 20 2-Chloronaphthalene SOL 10 Isophorone SOL 10 4-Chlorophenyl phenyl ether SOL 10 Isosafrole SOL 10 Chrysene SOL 10 Kepone SOL 20 Di-n-butyl phthalate SOL 10 Methapyrilene SOL 100 Di-n-octyl phthalate SOL 10 Methyl methanesulfonate SOL 10 Diallate SOL 10 Methyl parathion SOL 10 Dibenz(a, h)anthracene SOL 10 3-Methylcholanthrene SOL 10 Dibenzofuran SOL 10 2-Methylnaphthalene SOL 10 1,2-Dichlorobenzene SOL 10 Naphthalene SOL 10 1,3-Dichlorobenzene SOL 10 1A-Naphthoquinone SOL 10 1A-Dichlorobenzene SOL 10 1-Naphthylamine SOL 10 3,3'-Dichlorobenzidine SOL 20 2-Naphthylamine SOL 10 Diethyl phthalate SOL 10 5-Nitro-o-toluidine SOL 10 Dimethoate SOL 10 2-Nitroaniline SOL 50 Page 31 of 78
~--_._----_._--
IA CL 1~
A_D_V:_:4_N~C~'E~1J~C~'H~E~'M~Z~S~TR~Y~L-.-A_B~S~,
~IN~C_.
Phone: (770) 409-1444 3039 Amwiler Road' Suite 100' Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Base Neutral Extractables (8270C) - Appendix II ACl Sample #: 244065 Units:
~g/L Analyte Result pal 3-Nitroaniline Sal 50 4-Nitroaniline Sal 20 Nitrobenzene Sal 10 N-Nitroso-di-n-butylamine Sal 10 N-Nitrosodiethylamine Sal 20 N-Nitrosodimethylamine Sal 10 N-Nitrosodiphenylamine Sal 10 N-Nitrosodipropylamine Sal 10 N-Nitrosomethylethylamine Sal 10 N-Nitrosopiperidine Sal 20 N-Nitrosopyrrolidine Sal 40 Parathion Sal 20 Pentachlorobenzene Sal 10 Pentachloronitrobenzene Sal 20 Phenacetin Sal 20 Phenanthrene Sal 10 p-Phenylenediamine Sal 10 Phorate Sal 10 Pronamide Sal 10 Pyrene Sal 10 Safrole Sal 10 1,2,4,5-Tetrachlorobenzene Sal 10 Thionazin Sal 20 o-Toluidine Sal 10 1,2,4-Trichlorobenzene Sal 10 o,o,o-Triethyl phosphorothioate Sal 50 1,3,5-Trinitrobenzene Sal 10 Sample 10:
GWC-13/MW-13 Matrix:
Water Date Sampled:
06/05/2006 Date Extracted:
06/12/2006 Date Analyzed:
06/13/2006 Analyst:
RB Page 32 of 78
IA CL 1
A-D-VA-N~C""""""E~'D~C''''''''H-E-'M~IS~T.....'R~Y~L~A-B~S....., l~N~C-.
Phone: (770) 409-1444 3039 Amwiler Road* Suite 100* Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACl Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Pesticides/PCBs (8081A18082) - Appendix II ACl Sample #: 244065 Units:
IJg/L Analyte Result PQl Aldrin SQL 0.05 Arochlor-1016 SQL 0.50 Arochlor-1221 SQL 0.50 Arochlor-1232 SQL 0.50 Arochlor-1242 SQL 0.50 Arochlor-1248 SQL 0.50 Arochlor-1254 SQL 0.50 Arochlor-1260 SQL 0.50 a-SHC SQL 0.05 b-SHC SQL 0.05 d-SHC SQL 0.05 g-SHC SQL 0.05 Chlordane SQL 0.10 4,4'-DDD SQL 0.05 4,4'-DDE SQL 0.05 4,4'-DDT SQL 0.05 Dieldrin SQL 0.05 Endosulfan I SQL 0.05 Endosulfan II SQL 0.05 Endosulfan sulfate SQL 0.05 Endrin SQL 0.05 Endrin aldehyde SQL 0.05 Heptachlor SQL 0.05 Heptachlor epoxide SQL 0.05 Methoxychlor SQL 0.05 Toxaphene SQL 2.00 Sample 10:
GWC-13/MW-13 Matrix:
Date Sampled:
Date Extracted:
Date Analyzed:
Analyst:
Water 06/0512006 06/12/2006 06/20/2006 AM Page 33 of 78
IA CL 1~
A_D_V:_:4_N~C~'E~D~C~'H~E~'M~'L~S~TR~Y~L-.-A_B~S~,
~IJV~C_.
Phone: (770) 409-1444 3039 Amwiler Road* Suite 100
- Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACl Project #:
Date Received:
Date Reported:
Vogtle IF #3 50727 06/08/2006 07/06/2006 Chlorinated Herbicides (8151A) - Appendix II ACl Sample #: 244065 Units:
J,Jg/L Analyte Result PQl 2,4-0 Sal 1.0 Oinoseb Sal 1.0 2,4,5-TP (Silvex)
Sal 1.0 2,4,5-T Sal 1.0 Sample ID:
GWC-13/MW-13 Matrix:
Water Date Sampled:
06/05/2006 Date Extracted:
06/08/2006 Date Analyzed:
06/23/2006 Analyst:
AM Page 34 of 78
IA CL 1'---
A_D_Jl:_:4_N~C__'E-1J-C-'H.....E-M~l-S-TR~Y-L-A-B~S-, IN......C_.
Phone: (770) 409-1444 3039 Amwiler Road' Suite 100' Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610' Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Miscellaneous Organics (8011)
- Appendix II ACL Sample #: 244065 Units:
IJg/L Analyte Result POL 1,2-Dibromo-3-chloropropane Sal 0.20 1,2-Dibromoethane Sal 0.05 Sample 10:
GWC-13/MW-13 Matrix:
Water Date Sampled:
06/0512006 Date Extracted:
06/12/2006 Date Analyzed:
06/15/2006 Analyst:
AD Page 35 of 78
IACL 1~
A_D_Jl:_'A_N~C~'E~V~C~'H~E~M~I.~S~TR~Y~L~A_B~S~, ~IN~C_.
Phone: (770) 409-1444 3039 Amwiler Road* Suite 100
- Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACl Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Appendix II Metals (6010B/7470Al7841/7041)
ACl Sample #: 244065 Units:
mg/L Analyte Result POL Antimony Sal 0.006 Arsenic Sal 0.010 Sarium 0.051 0.020 Seryllium Sal 0.004 Cadmium Sal 0.005 Chromium Sal 0.020 Cobalt Sal 0.050 Copper Sal 0.020 lead Sal 0.010 Mercury Sal 0.0005 Nickel Sal 0.020 Selenium Sal 0.040 Silver Sal 0.010 Thallium Sal 0.002 Tin Sal 0.025 Vanadium Sal 0.050 Zinc 0.213 0.020 Sample 10:
GWC-13/MW-13 Matrix:
Date Sampled:
Date Extracted:
Date Analyzed:
Analyst:
Water 06/0512006 06/12/2006 AD/JR Page 36 of 78
ADVANCED CHEMISTRYLABS, INC.
IACL I Phone: (770) 40~9~-1~4"'!"'44~-------------~3~03~9~A:-m-w~i1e-r~R:-o-ad~'~S~u~ite-1~0~0-'
A~t~la~nt:-a,~G~A~30:-=3~60::--
Fax: (770) 409-1844 P.O. Box 88610' Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
The Dextra Group Client Proj #:
VogUe IF #3 1205 Johnson Ferry Rd.
ACl Project #:
50727 Suite 136-446 Date Received:
06/08/2006 Marietta, GA 30068-0000 Date Reported:
07/06/2006
Contact:
Mr. Kurt Satsel Date Sample 10 ACl#
Analyte Matrix Result POL Units Analyzed GWC-13/MW-13 244065 Cyanide (9012A)
Water Sal 0.020 mg/l 06/15/2006 GWC-13/MW-13 244065 Sulfide (9034)
Water Sal 1.0 mg/l 06/12/2006 Page 37 of 78
IACL 1~
A_D_~_:4_N__C~'E_1J_C_'H.......E_'M~l_S_TR~Y_LA_B~S~, ~IN~C_.
Phone: (770) 409-1444 3039 Amwiler Road' Suite 100' Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610' Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 V.O. (50308/82608) - Appendix II GWA-15/MW-15 Sample 10:
ACL Sample #: 244066 Analyte Acetone Acetonitrile Acrolein Acrylonitrile Allyl chloride Senzene Sromochloromethane Sromodichloromethane Bromoform Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloroprene 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane trans-1,4-Dichloro-2-butene 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Units:
Result SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL IJg/L POL 100 100 100 50 10 5
5 5
5 5
5 5
10 5
20 20 5
5 10 5
5 5
5 5
5 5
5 5
5 5
15 5
5 5
Matrix:
Date Sampled:
Date Extracted:
Date Analyzed:
Analyst:
Analyte Ethyl methacrylate Ethylbenzene 2-Hexanone Isobutyl alcohol Methacrylonitrile Methyl bromide Methyl chloride Methyl ethyl ketone Methyl iodide Methyl methacrylate 4-Methyl-2-pentanone Methylene bromide Methylene chloride Naphthalene Propionitrile Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride m & p-Xylenes o-Xylene Water 06/05/2006 06/12/2006 JA Result SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL SOL BOL SOL BOL Page 38 of 78 POL 10 5
50 50 100 10 10 100 5
30 50 5
5 5
150 5
5 5
5 5
5 5
5 5
5 50 2
10 5
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRY LABS, INC.
3039 Amwiler Road' Suite 100* Atlanta, GA 30360 P.O. Box 88610' Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACl Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 ACl Sample #: 244066 Units:
IJg/L Analyte Result PQl 4-Chloro-3-methylphenol Sal 20 2-Chlorophenol Sal 10 m & p-Cresol Sal 10 o-Cresol Sal 10 2,4-Dichlorophenol Sal 10 2,6-Dichlorophenol Sal 10 2,4-Dimethylphenol Sal 10 4,6-Dinitro-2-methylphenol Sal 50 2,4-Dinitrophenol Sal 50 2-Nitrophenol Sal 10 4-Nitrophenol Sal 50 Pentachlorophenol Sal 50 Phenol Sal 10 2,3,4,6-Tetrachlorophenol Sal 10 2,4,5-Trichlorophenol Sal 10 2,4,6-Trichlorophenol Sal 10 Sample ID:
Acid Extractables (8270C) - Appendix II GWA-15/MW-15 Matrix:
Date Sampled:
Date Extracted:
Date Analyzed:
Analyst:
Water 06/0512006 06/12/2006 06/13/2006 RB Page 39 of 78
IA CL 1~
A_D_Jt:_:4_NC_'E_D_C_'H~E_M_l_S_T_'R_Y_LA_B_S_,_IN_C_.
Phone: (770) 409-1444 3039 Amwiler Road' Suite 100' Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610' Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACl Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Base Neutral Extractables (8270C) - Appendix II Sample ID:
GWA-15/MW-15 Matrix:
Water Date Sampled:
06/05/2006 Date Extracted:
06/12/2006 Date Analyzed:
06/13/2006 ACl Sample #: 244066 Units:
IJg/L Analyst:
RB Analyte Result pal Analyte Result pal Acenaphthene SOL 10 Dimethyl phthalate SOL 10 Acenaphthylene SOL 10 p-(Dimethylamino)azobenzene SOL 10 Acetophenone SOL 10 7,12-Dimethylbenz(a)anthracene SOL 10 2-Acetylaminofluorene SOL 20 3,3'-Dimethylbenzidine SOL 10 4-Aminobiphenyl SOL 20 m-Dinitrobenzene SOL 20 Anthracene SOL 10 2,4-Dinitrotoluene SOL 10 Senzo(a)anthracene SOL 10 2,6-Dinitrotoluene SOL 10 Benzo(a)pyrene SOL 10 Diphenylamine SOL 10 Senzo(b)fluoranthene SOL 10 Disulfoton SOL 10 Senzo(g,h,i)perylene SOL 10 Ethyl methanesulfonate SOL 20 Senzo(k)f1uoranthene SOL 10 Famphur SOL 20 Senzyl alcohol SOL 20 Fluoranthene SOL 10 Sis(2-chloroethoxy)methane SOL 10 Fluorene SOL 10 Bis(2-chloroethyl)ether SOL 10 Hexachlorobenzene SOL 10 Sis(2-chloroisopropyl)ether SOL 10 Hexachlorobutadiene SOL 10 Sis(2-ethylhexyl)phthalate SOL 10 Hexachlorocyclopentadiene SOL 10 4-Bromophenyl phenyl ether SOL 10 Hexachloroethane SOL 10 Sutyl benzyl phthalate SOL 10 Hexachloropropene SOL 10 p-Chloroaniline SOL 20 Indeno(1,2,3-cd)pyrene SOL 10 Chlorobenzilate SOL 10 Isodrin SOL 20 2-Chloronaphthalene SOL 10 Isophorone SOL 10 4-Chlorophenyl phenyl ether SOL 10 Isosafrole SOL 10 Chrysene BOL 10 Kepone SOL 20 Di-n-butyl phthalate SOL 10 Methapyrilene SOL 100 Di-n-octyl phthalate SOL 10 Methyl methanesulfonate SOL 10 Diallate SOL 10 Methyl parathion SOL 10 Dibenz(a, h)anthracene SOL 10 3-Methylcholanthrene SOL 10 Dibenzofuran SOL 10 2-Methylnaphthalene SOL 10 1,2-Dichlorobenzene SOL 10 Naphthalene SOL 10 1,3-Dichlorobenzene BOL 10 1,4-Naphthoquinone SOL 10 1A-Dichlorobenzene SOL 10 1-Naphthylamine SOL 10 3,3'-Dichlorobenzidine SOL 20 2-Naphthylamine SOL 10 Diethyl phthalate BOL 10 5-Nitro-o-toluidine BOL 10 Dimethoate SOL 10 2-Nitroaniline SOL 50 Page 40 of 78
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRYLABS, INC.
3039 Amwiler Road* Suite 100* Atlanta, GA 30360 P.O. Box 88610* Atlanta. GA 30356 www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACl Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Base Neutral Extractables (8270C) - Appendix II ACl Sample #: 244066 Units:
IJg/L Analyte Result pal 3-Nitroaniline SOL 50 4-Nitroaniline SOL 20 Nitrobenzene SQL 10 N-Nitroso-di-n-butylamine SQL 10 N-Nitrosodiethylamine SOL 20 N-Nitrosodimethylamine SOL 10 N-Nitrosodiphenylamine SQL 10 N-Nitrosodipropylamine SQL 10 N-Nitrosomethylethylamine SOL 10 N-Nitrosopiperidine SQl 20 N-Nitrosopyrrolidine SOL 40 Parathion SOL 20 Pentachlorobenzene SQL 10 Pentachloronitrobenzene SQL 20 Phenacetin SQL 20 Phenanthrene SQL 10 p-Phenylenediamine SQL 10 Phorate SOL 10 Pronamide SQL 10 Pyrene SQL 10 Safrole SOL 10 1,2,4,5-Tetrachlorobenzene SQL 10 Thionazin SOL 20 a-Toluidine SOL 10 1,2,4-Trichlorobenzene SQL 10 0,0,0-Triethyl phosphorothioate Sal 50 1,3,5-Trinitrobenzene SQL 10 Sample 10:
GWA-15/MW-15 Matrix:
Date Sampled:
Date Extracted:
Date Analyzed:
Analyst:
Water 06/05/2006 06/12/2006 06/13/2006 RB Page 41 of 78
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRY LABS, INC.
3039 Amwiler Road* Suite 100
- Atlanta, GA 30360 P.O. Box 88610* Atlanta. GA 30356 www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACl Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 ACl Sample #: 244066 Units:
IJg/L Analyte Result pal Aldrin Sal 0.05 Arochlor-1016 Sal 0.50 Arochlor-1221 Sal 0.50 Arochlor-1232 Sal 0.50 Arochlor-1242 Sal 0.50 Arochlor-1248 Sal 0.50 Arochlor-1254 Sal 0.50 Arochlor-1260 Sal 0.50 a-SHC Sal 0.05 b-SHC Sal 0.05 d-SHC Sal 0.05 g-SHC Sal 0.05 Chlordane Sal 0.10 4,4'-DDD Sal 0.05 4,4'-DDE Sal 0.05 4,4'-DDT Sal 0.05 Dieldrin Sal 0.05 Endosulfan I Sal 0.05 Endosulfan II Sal 0.05 Endosulfan sulfate Sal 0.05 Endrin Sal 0.05 Endrin aldehyde Sal 0.05 Heptachlor Sal 0.05 Heptachlor epoxide Sal 0.05 Methoxychlor Sal 0.05 Toxaphene Sal 2.00 Sample 10:
Pesticides/PCBs (8081A18082)* Appendix II GWA-15/MW-15 Matrix:
Water Date Sampled:
06/05/2006 Date Extracted:
06/12/2006 Date Analyzed:
06/20/2006 Analyst:
AM Page 42 of 78
IACL 1~
A_D_VA_N"""!",C,!",!",'E!""",!,,D~C~'H_E~'M~IS~T~'R~Y~L~A_B~S~, l~N~C_.
Phone: (770) 409-1444 3039 Amwiler Road* Suite 100' Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610' Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACl Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Chlorinated Herbicides (8151A) - Appendix II ACl Sample #: 244066 Units:
IJg/L Analyte Result pal 2,4-D SQl 1.0 Dinoseb SQl 1.0 2,4,5-TP (Silvex)
SQl 1.0 2,4,5-T SQl 1.0 Sample ID:
GWA-15/MW-15 Matrix:
Water Date Sampled:
06/0512006 Date Extracted:
06/08/2006 Date Analyzed:
06/23/2006 Analyst:
AM Page 43 of 78
IACL 11...-
A_D_VA_N~CE__D CH~EM__...._IS-T'R-Y__L-A~BS__,.......IN~C-.
Phone: (770) 409-1444 3039 Amwiler Road* Suite 100* Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acJ@acl-labs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Miscellaneous Organics (8011) - Appendix II Sample 10:
GWA-15/MW-15 Matrix:
Water Date Sampled:
06/0512006 Date Extracted:
06/12/2006 Date Analyzed:
06/15/2006 ACL Sample #: 244066 Units:
1J9/L Analyst:
AD Analyte 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Result Sal Sal POL 0.20 0.05 Page 44 of 78
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRY LABS, INC.
3039 Amwiler Road* Suite 100* Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACl Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Appendix II Metals (6010B/7470Al7841/7041)
ACl Sample #: 244066 Units:
mg/L Analyte Result pal Antimony BOl 0.006 Arsenic BOl 0.010 Barium BOl 0.020 Beryllium BOl 0.004 Cadmium BOl 0.005 Chromium BOl 0.020 Cobalt BOl 0.050 Copper BOl 0.020 Lead BOl 0.010 Mercury BOl 0.0005 Nickel BOl 0.020 Selenium BOl 0.040 Silver BOl 0.010 Thallium BOl 0.002 Tin BOl 0.025 Vanadium BOl 0.050 Zinc 0.063 0.020 Sample 10:
GWA-15/MW-15 Matrix:
Date Sampled:
Date Extracted:
Date Analyzed:
Analyst:
Water 06/05/2006 06/12/2006 AD/JR Page 45 of 78
ADVANCED CHEMISTRY LABS, INC.
IACL I Phone: (770) 40~9~-1~44~4O:---------------~3~0~39~A~m-w~il-er-:R~o-ad":"'*-=S~u~jte~1 O~O-*"':"'At~la-nt~a-=,G~A~30=O::3~60~
Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
The Dextra Group Client Proj #:
Vogtle IF #3 1205 Johnson Ferry Rd.
ACL Project #:
50727 Suite 136-446 Date Received:
06/08/2006 Marietta, GA 30068-0000 Date Reported:
07/06/2006
Contact:
Mr. Kurt Satsel Date Sample 10 ACL#
Analyte Matrix Result PQL Units Analyzed GWA-15/MW-15 244066 Cyanide (9012A)
Water Sal 0.020 mg/l 06/15/2006 GWA-15/MW-15 244066 Sulfide (9034)
Water Sal 1.0 mg/l 06/12/2006 Page 46 of 78
IA CL 1~
A_D_~_:4_N.......C....'E_1J_C_'H.....E_M
......l,_S_TR~Y_LA_B_S_, __INC_.
Phone: (770) 409-1444 3039 Amwiler Road* Suite 100
- Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@aci-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACl Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 v.o. (50308/82608) - Appendix I ACl Sample #: 244067 Units:
IJg/L Analyte Result pal Acetone SOL 100 Acrylonitrile SOL 50 Senzene SOL 5
Sromochloromethane SOL 5
Sromodichloromethane SOL 5
Sromoform SOL 5
Carbon disulfide SOL 5
Carbon tetrachloride SOL 5
Chlorobenzene Sal 5
Chloroethane SOL 10 Chloroform SOL 5
1,2-Dibromo-3-chloropropane SOL 20 Dibromochloromethane SOL 5
1,2-Dibromoethane SOL 5
trans-1,4-Dichloro-2-butene SOL 10 1,2-Dichlorobenzene SOL 5
1A-Dichlorobenzene SOL 5
1,1-Dichloroethane SOL 5
1,2-Dichloroethane SOL 5
1,1-Dichloroethene SOL 5
cis-1,2-Dichloroethene SOL 5
trans-1,2-Dichloroethene SOL 5
1,2-Dichloropropane SOL 5
cis-1,3-Dichloropropene SOL 5
trans-1,3-Dichloropropene SOL 5
Ethylbenzene Sal 5
2-Hexanone Sal 50 Methyl bromide SOL 10 Methyl chloride Sal 10 Methyl ethyl ketone SOL 100 Methyl iodide SOL 5
4-Methyl-2-pentanone SOL 50 Methylene bromide SOL 5
Methylene chloride SaL 5
Sample 10:
GWC-17/MW-17 Matrix:
Date Sampled:
Date Extracted:
Date Analyzed:
Analyst:
Analyte Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride m & p-Xylenes o-Xylene Water 06/05/2006 06/12/2006 JA Result SaL sal saL saL sal sal saL saL saL saL saL sal saL saL Page 47 of 78 pal 5
5 5
5 5
5 5
5 5
5 50 2
10 5
ADVANCED CHEMISTRY LABS, INC.
IACL I Phone: (770) 40~9~-1~4~44~-------------~3~0~39~A:-m-w~il-er~R:-o-ad":'"'.-:S:-u~ite~1 O~O-*~At:':"'la-nt~a-:,G~A~30::":3~60:-OOOO Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Miscellaneous Organics (8011) - Appendix II Sample ID:
GWC-17/MW-17 Matrix:
Water Date Sampled:
06/0512006 Date Extracted:
06/12/2006 Date Analyzed:
06/15/2006 ACL Sample #: 244067 Units:
1J9/L Analyst:
AD Analyte 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Result sal sal POL 0.20 0.05 Page 48 of 78
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRY LABS, INC.
3039 Amwiler Road* Suite 100
- Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 ACL Sample #: 244067 Units:
mg/L Analyte Result POL Antimony SOL 0.006 Arsenic SOL 0.010 Sarium SOL 0.020 Seryllium SOL 0.004 Cadmium SOL 0.005 Chromium SOL 0.020 Cobalt SOL 0.050 Copper SOL 0.020 Lead SOL 0.010 Nickel SOL 0.020 Selenium SOL 0.040 Silver SOL 0.010 Thallium SOL 0.002 Vanadium SOL 0.050 Zinc 0.077 0.020 Sample 10:
Appendix I Metals (60108/7841/7041)
GWC-17/MW-17 Matrix:
Date Sampled:
Date Extracted:
Date Analyzed:
Analyst:
Water 06/0512006 06/12/2006 AD Page 49 of 78
ADVANCED CHEMISTRYLABS, INC IACL I Phone: (770) 40~9~-1~44~4~-------------~3~03~9~A~m-w~i1e-r-:R~o-ad":"'*~S~u~ite-1~O~0-'
A~t":"'la~nt:-a,~G::-:A~30::"=3':":60:--
Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: ac/@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Satsel Client Proj #:
ACl Project #:
Date Received:
Date Reported:
Vogtle IF #3 50727 06/08/2006 07/06/2006 Sample 10 GWC-17/MW-17 ACl#
244067 Analyte Mercury (7470A)
Matrix Water Result Sal PQl Units 0.0005 mg/l Page 50 of 78 Date Analyzed 06/12/2006
IA CL 1
A_D_J-':_:4_N......c.....'E_1J~C-'H.......E~'M~'L~S~TR......Y~L~A-B~S~,......IN~C_.
Phone: (770) 409-1444 3039 Amwiler Road* Suite 100* Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 v.o. (50308/82608) - Appendix I Sample 10:
EO Blank Matrix:
Water Date Sampled:
06/0612006 Date Extracted:
Date Analyzed:
06/12/2006 ACL Sample #: 244068 Units:
IJg/L Analyst:
JA Analyte Result POL Analyte Result POL Acetone SOL 100 Styrene SOL 5
Acrylonitrile SOL 50 1,1,1,2-Tetrachloroethane SOL 5
Senzene SOL 5
1,1,2,2-Tetrachloroethane SOL 5
Sromochloromethane SOL 5
Tetrachloroethene SOL 5
Sromodichloromethane SOL 5
Toluene SOL 5
Sromoform SOL 5
1,1,1-Trichloroethane SOL 5
Carbon disulfide SOL 5
1,1,2-Trichloroethane SOL 5
Carbon tetrachloride SOL 5
Trichloroethene SOL 5
Chlorobenzene SOL 5
Trichlorofluoromethane SOL 5
Chloroethane SOL 10 1,2,3-Trichloropropane SOL 5
Chloroform SOL 5
Vinyl acetate SOL 50 1,2-Dibromo-3-chloropropane SOL 20 Vinyl chloride SOL 2
Dibromochloromethane SOL 5
m & p-Xylenes SOL 10 1,2-Dibromoethane SOL 5
o-Xylene SOL 5
trans-1 A-Dichloro-2-butene SOL 10 1,2-Dichlorobenzene SOL 5
1A-Dichlorobenzene SOL 5
1,1-Dichloroethane SOL 5
1,2-Dichloroethane SOL 5
1,1-Dichloroethene SOL 5
cis-1,2-Dichloroethene SOL 5
trans-1,2-Dichloroethene SOL 5
1,2-Dichloropropane SOL 5
cis-1,3-Dichloropropene SOL 5
trans-1,3-Dichloropropene SOL 5
Ethylbenzene SOL 5
2-Hexanone SOL 50 Methyl bromide SOL 10 Methyl chloride SOL 10 Methyl ethyl ketone SOL 100 Methyl iodide Sal 5
4-Methyl-2-pentanone SOL 50 Methylene bromide SOL 5
Methylene chloride SOL 5
Page 51 of 78
_.~-_.._-
-~. -----------------
- ~ -
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRY LABS, INC.
3039 Amwiler Road* Suite 100
- Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Miscellaneous Organics (8011) - Appendix II ACL Sample #: 244068 Sample 10:
EO Blank Units:
IJg/L Matrix:
Date Sampled:
Date Extracted:
Date Analyzed:
Analyst:
Water 06/06/2006 06/12/2006 06/15/2006 AD Analyte 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Result SQL SQL POL 0.20 0.05 Page 52 of 78
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRY LABS, INC.
3039 Amwiler Road* Suite 100
- Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07106/2006 Appendix I Metals (60108/7841/7041)
ACL Sample #: 244068 Units:
mg/L Analyte Result POL Antimony Sal 0.006 Arsenic Sal 0.010 Sarium Sal 0.020 Seryllium Sal 0.004 Cadmium Sal 0.005 Chromium Sal 0.020 Cobalt Sal 0.050 Copper Sal 0.020 lead Sal 0.010 Nickel Sal 0.020 Selenium Sal 0.040 Silver Sal 0.010 Thallium Sal 0.002 Vanadium Sal 0.050 Zinc Sal 0.020 Sample 10:
EO Blank Matrix:
Date Sampled:
Date Extracted:
Date Analyzed:
Analyst:
Water 06/06/2006 06/12/2006 AD Page 53 of 78
'I ACL I
~
Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRY LABS, INC.
3039 Amwiler Road* Suite 100
- Atlanta. GA 30360 P.O. Box 88610* Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
The Dextra Group Client Proj #:
Vogtle IF #3 1205 Johnson Ferry Rd.
ACl Project #:
50727 Suite 136-446 Date Received:
06/08/2006 Marietta, GA 30068-0000 Date Reported:
07/06/2006
Contact:
Mr. Kurt Batsel Date Sample 10 ACl#
Analyte Matrix Result PQl Units Analyzed EO Blank 244068 Mercury (7470A)
Water BOl 0.0005 mg/l 06/12/2006 Page 54 of 78
IACL 1~
A_D_f':_A_N_C_E~'D!""!"","C~'H~E~M~IS~T~'R~Y~L~A_B--!S'~I",!",!,,,N~c.
Phone: (770) 409-1444 3039 Amwiler Road, Suite 100, Atlanta, GA 30360 Fax: (770) 409-1844 P. O. Box 88610, Atlanta, GA 30356 e-mail: acl@acl-Iabs.net QUALITY CONTROL SECTION Page 55 of 78
~--~-
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRYLABS, INC.
3039 Amwiler Road* Suite 100' Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 V.O. (50308/82608) - Appendix I SURROGATE PERCENT RECOVERY
SUMMARY
Water Dibromofluoromethane 1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene (77-137)
(72-138)
(84-112)
(77-125)
ACL Sample #
244061 106 106 102 99 244062 108 110 102 99 244067 112 111 104 100 244068 106 113 104 96
- Matrix Interference DO=Diluted Out Page 56 of 78
IA CL 1~
A_D_Jl:_:4_N~C~'E~D~C~'H~E~M~I.~S~TR~Y--=-L-.-A-.-B~S~,
~IN~C_.
Phone: (770) 409-1444 3039 Amwiler Road* Suite 100* Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 V.O. (50308/82608) - Appendix II SURROGATE PERCENT RECOVERY
SUMMARY
Water Dibromofluoromethane 1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene (77-137)
(72-138)
(84-112)
(77-125)
ACL Sample #
244063 111 110 101 96 244064 110 107 98 104 244065 112 110 100 102 244066 113 104 102 97
- Matrix Interference DO=Diluted Out Page 57 of 78
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRY LABS, INC.
3039 Amwiler Road* Suite 100
- Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
The Dextra Group Client Proj #:
Vogtle LF #3 1205 Johnson Ferry Rd.
ACL Project #:
50727 Suite 136-446 Date Received:
06/08/2006 Marietta, GA 30068-0000 Date Reported:
07/06/2006
Contact:
Mr. Kurt Batsel V.C. (50308/82608) - Appendix II Sample 10:
Matrix:
Water Date Sampled:
Date Extracted:
Date Analyzed:
06/12/2006 ACL Sample #:
Blank Units:
I-lg/L Analyst:
JA Analyte Result PQL Analyte Result PQL Acetone Sal 100 Ethyl methacrylate Sal 10 Acetonitrile Sal 100 Ethylbenzene Sal 5
Acrolein Sal 100 2-Hexanone Sal 50 Acrylonitrile Sal 50 Isobutyl alcohol Sal 50 Allyl chloride Sal 10 Methacrylonitrile Sal 100 Senzene Sal 5
Methyl bromide Sal 10 Sromochloromethane Sal 5
Methyl chloride Sal 10 Sromodichloromethane Sal 5
Methyl ethyl ketone Sal 100 Sromoform Sal 5
Methyl iodide Sal 5
Carbon disulfide Sal 5
Methyl methacrylate Sal 30 Carbon tetrachloride Sal 5
4-Methyl-2-pentanone Sal 50 Chlorobenzene Sal 5
Methylene bromide Sal 5
Chloroethane Sal 10 Methylene chloride Sal 5
Chloroform Sal 5
Naphthalene Sal 5
Chloroprene Sal 20 Propionitrile Sal 150 1,2-Dibromo-3-chloropropane Sal 20 Styrene Sal 5
Dibromochloromethane Sal 5
1,1,1,2-Tetrachloroethane Sal 5
1,2-Dibromoethane Sal 5
1,1,2,2-Tetrachloroethane Sal 5
trans-1,4-Dichloro-2-butene Sal 10 Tetrachloroethene Sal 5
1,2-Dichlorobenzene SOL 5
Toluene SOL 5
1,3-Dichlorobenzene Sal 5
1,1,1-Trichloroethane Sal 5
1,4-Dichlorobenzene Sal 5
1,1,2-Trichloroethane Sal 5
Dichlorodifluoromethane Sal 5
Trichloroethene Sal 5
1,1-Dichloroethane SOL 5
Trichlorofluoromethane SOL 5
1,2-Dichloroethane Sal 5
1,2,3-Trichloropropane Sal 5
1,1-Dichloroethene Sal 5
Vinyl acetate Sal 50 cis-1,2-Dichloroethene Sal 5
Vinyl chloride Sal 2
trans-1,2-Dichloroethene Sal 5
m & p-Xylenes Sal 10 1,2-Dichloropropane Sal 5
o-Xylene Sal 5
1,3-Dichloropropane SOL 5
2,2-Dichloropropane SOL 15 1,1-Dichloropropene Sal 5
cis-1,3-Dichloropropene Sal 5
trans-1,3-Dichloropropene Sal 5
Page 58 of 78
ADVANCED CHEMISTRY LABS, INC.
GC/MS UNIT # 3 WATER VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY Sequence Date :
06-12-06 244058-1 SPIKE SAMPLE MS MS ac.
ADDED CONCENTRATION CONCENTRATION LIMITS COMPOUND (lJg/L)
(lJg/L)
(lJg/L)
REC REC.
1,1-dichloroethene 20.0 0.0 22.5 112 (54-144) benzene 20.0 0.0 22.4 112 (82-132) trichloroethene 20.0 0.0 20.5 103 (73-128) toluene 20.0 0.0 20.9 105 (83-130) chlorobenzene 20.0 0.0 21.5 107 (82-123)
SPIKE MSD MSD ADDED CONCENTRATION ac LIMITS COMPOUND (lJg/L)
(lJg/L)
1,1-dichloroethene 20.0 23.1 115 3
14 (54-144) benzene 20.0 21.6 108 3
14 (82-132) trichloroethene 20.0 21.0 105 2
14 (73-128) toluene 20.0 20.4 102 3
13 (83-130) chlorobenzene 20.0 21.3 106 1
13 (82-123) 22.94
- Column to be used to flag recovery and RPD values with an asterisk Values outside of ac limits RPD:
0 out of 5 outside limits Spike Recovery:
0 out of 10 outside limits Comments:
Page 59 of 78
3039 Amwiler Road' Suite 100
- Atlanta, GA 30360 P.O. Box 88610' Atlanta, GA 30356 www.advancedchemistrylabs.com ADVANCED CHEMISTRYLABS, INC.
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Acid Extractables (8270C) - Appendix II SURROGATE PERCENT RECOVERY
SUMMARY
Water Phenol-d6 2-Fluorophenol 2,4,6-Tribromophenol (8-50)
(8-58)
(10-123)
ACL Sample #
244063 11 23 36 244064 14 26 29 244065 13 23 67 244066 15 24 17
.* Matrix Interference DO=Diluted Out Page 60 of 78
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRYLABS, INC.
3039 Amwiler Road* Suite 100
- Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Acid Extractables (8270C) - Appendix II Sample ID:
ACL Sample #:
Blank Units:
IJg/L Analyte Result PQL 4-Chloro-3-methylphenol SQl 20 2-Chlorophenol SQl 10 m & p-Cresol SQl 10 o-Cresol SQl 10 2,4-Dichlorophenol SQl 10 2,6-Dichlorophenol SQl 10 2,4-Dimethylphenol SQl 10 4,6-Dinitro-2-methylphenol SQl 50 2,4-Dinitrophenol SQl 50 2-N itrophenol SQl 10 4-Nitrophenol SQl 50 Pentachlorophenol SQl 50 Phenol SQl 10 2,3,4,6-Tetrachlorophenol SQl 10 2,4,5-Trichlorophenol SQl 10 2,4,6-Trichlorophenol SQl 10 Matrix:
Date Sampled:
Date Extracted:
Date Analyzed:
Analyst:
Water 06/12/2006 06/13/2006 RB Page 61 of 78
ADVANCED CHEMISTRY LABS, INC.
SEMI-VOL GC/MS UNIT # 4 ACID EXTRACTABLES (8270C)
WATER SEMI-VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY Sequence Date:
06-13-06 Matrix Spike - Sample No.:
LCS/LCSD SPIKE SAMPLE MS MS ac.
COMPOUND ADDED CONCENTRATION CONCENTRATION LIMITS (lJg/L)
(IJQ/L)
(IJQ/L)
REC REC.
Pentachlorophenol 200 0
156 78.0 (9-103)
Phenol 200 0
40 20.0 (12-89) 2-Chlorophenol 200 0
168 84.0 (27-123) 4-Chloro-3-methylphenol 200 0
159 79.5 (23-97) 4-Nitrophenol 200 0
53 26.5 (10-80)
SPIKE MSD MSD ac LIMITS COMPOUND ADDED CONCENTRATION (IJQ/L)
(IJQ/L)
Pentachlorophenol 200 135 77.0 1.3 50 (9-103)
Phenol 200 34 17.0 16.2 42 (12-89) 2-Chlorophenol 200 156 78.0 7.4 40 (27-123) 4-Chloro-3-methylphenol 200 156 78.0 1.9 42 (23-97) 4-Nitrophenol 200 50 25.0 5.8 50 (10-80)
- Column to be used to flag recovery and RPD values with an asterisk Values outside of ac limits RPD:
0 out of 5 outside limits Spike Recovery:
0 out of 10 outside limits Comments:
Page 62 of 78
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRYLABS, INC.
3039 Amwiler Road* Suite 100
- Atlanta, GA 30360 P.O. Box 88610' Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Base Neutral Extractables (8270C) - Appendix II SURROGATE PERCENT RECOVERY
SUMMARY
Water Nitrobenzene-d5 2-Fluorobiphenyl Terphenyl-d14 (28-87)
(25-106)
(32-135)
ACL Sample #
244063 81 68 108 244064 67 58 100 244065 85 73 60 244066 105 93 51
- Matrix Interference DO=Diluted Out Page 63 of 78
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRY LABS, INC.
3039 Amwiler Road* Suite 100
- Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
The Dextra Group Client Proj #:
Vogtle LF #3 1205 Johnson Ferry Rd.
ACL Project #:
50727 Suite 136-446 Date Received:
06/08/2006 Marietta, GA 30068-0000 Date Reported:
07/06/2006
Contact:
Mr. Kurt Batsel Base Neutral Extractables (8270C) - Appendix II Sample 10:
Matrix:
Water Date Sampled:
Date Extracted:
06/12/2006 Date Analyzed:
06/13/2006 ACL Sample #:
Blank Units:
I-lg/L Analyst:
RB Analyte Result PQL Analyte Result PQL Acenaphthene Sal 10 Dimethyl phthalate Sal 10 Acenaphthylene Sal 10 p-(Dimethylamino)azobenzene Sal 10 Acetophenone Sal 10 7,12-Dimethylbenz(a)anthracene Sal 10 2-Acetylaminofluorene Sal 20 3,3'-Dimethylbenzidine Sal 10 4-Aminobiphenyl Sal 20 m-Dinitrobenzene Sal 20 Anthracene Sal 10 2,4-Dinitrotoluene Sal 10 Senzo(a)anthracene Sal 10 2,6-Dinitrotoluene Sal 10 Senzo(a)pyrene Sal 10 Diphenylamine Sal 10 Senzo(b)fluoranthene Sal 10 Disulfoton Sal 10 Senzo(g,h,i)perylene Sal 10 Ethyl methanesulfonate Sal 20 Senzo(k)fluoranthene Sal 10 Famphur Sal 20 Senzyl alcohol Sal 20 Fluoranthene Sal 10 Sis(2-chloroethoxy)methane Sal 10 Fluorene Sal 10 Sis(2-chloroethyl)ether Sal 10 Hexachlorobenzene Sal 10 Sis(2-chloroisopropyl)ether Sal 10 Hexachlorobutadiene Sal 10 Sis(2-ethylhexyl)phthalate Sal 10 Hexachlorocyclopentadiene Sal 10 4-Sromophenyl phenyl ether Sal 10 Hexachloroethane Sal 10 Sutyl benzyl phthalate Sal 10 Hexachloropropene Sal 10 p-Chloroaniline Sal 20 Indeno(1,2,3-cd)pyrene Sal 10 Chlorobenzilate Sal 10 Isodrin Sal 20 2-Chloronaphthalene Sal 10 Isophorone Sal 10 4-Chlorophenyl phenyl ether Sal 10 Isosafrole Sal 10 Chrysene Sal 10 Kepone Sal 20 Di-n-butyl phthalate Sal 10 Methapyrilene Sal 100 Di-n-octyl phthalate Sal 10 Methyl methanesulfonate Sal 10 Diallate Sal 10 Methyl parathion Sal 10 Dibenz(a,h)anthracene Sal 10 3-Methylcholanthrene Sal 10 Dibenzofuran Sal 10 2-Methylnaphthalene Sal 10 1,2-Dichlorobenzene Sal 10 Naphthalene Sal 10 1,3-Dichlorobenzene Sal 10 1,4-Naphthoquinone Sal 10 1A-Dichlorobenzene SOL 10 1-Naphthylamine SOL 10 3,3'-Dichlorobenzidine Sal 20 2-Naphthylamine Sal 10 Diethyl phthalate Sal 10 5-Nitro-o-toluidine Sal 10 Dimethoate Sal 10 2-Nitroaniline Sal 50 Page 64 of 78
IACL 1~~
A_D_Jt:_:4~N~C~'E~1J~C--:'H~E~'M~L~S~TR~Y~L~A_B~S~, l~N~C_.
Phone: (770) 409-1444 3039 Amwiler Road' Suite 100' Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610' Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Base Neutral Extractables (8270C)
- Appendix II Sample 10:
ACL Sample #:
Blank Units:
~g/L Analyte Result PQL 3-Nitroaniline SQl 50 4-Nitroaniline SQl 20 Nitrobenzene SQl 10 N-Nitroso-di-n-butylamine SQl 10 N-Nitrosodiethylamine SQl 20 N-Nitrosodimethylamine SQl 10 N-Nitrosodiphenylamine SQl 10 N-Nitrosodipropylamine SQl 10 N-Nitrosomethylethylamine SQl 10 N-Nitrosopiperidine SQl 20 N-Nitrosopyrrolidine SQl 40 Parathion SQl 20 Pentachlorobenzene SQl 10 Pentachloronitrobenzene SQl 20 Phenacetin SQl 20 Phenanthrene SQl 10 p-Phenylenediamine SQl 10 Phorate SQl 10 Pronamide SQl 10 Pyrene SQl 10 Safrole SQl 10 1,2,4,5-Tetrachlorobenzene SQl 10 Thionazin SQl 20 0-Toluidine SQl 10 1,2,4-Trichlorobenzene SQl 10 0,0,0-Triethyl phosphorothioate SQl 50 1,3,5-Trinitrobenzene SQl 10 Matrix:
Date Sampled:
Date Extracted:
Date Analyzed:
Analyst:
Water 06/12/2006 06/13/2006 RB Page 65 of 78
ADVANCED CHEMISTRY LABS, INC.
SEMI-VOL GC/MS UNIT # 1 BASE/NEUTRAL EXTRACTABLES (8270C)
WATER SEMI-VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY Sequence Date :
06-13-06 Matrix Spike - Sample No.:
LCS/LCSD SPIKE SAMPLE MS MS ac.
ADDED CONCENTRATION CONCENTRATION LIMITS COMPOUND (lJg/L)
(lJg/L)
(lJg/L)
REC REC.
1,2,4-Trichlorobenzene 100 0
88 88.0 (39-98)
Acenaphthene 100 0
63 63.0 (46-118) 2,4-Dinitrotoluene 100 0
63 63.0 (24-96)
Di-n-butyl phthalate 100 0
110 110.0 (11-117)
Pyrene 100 0
119 119.0 (26-127)
N-Nitrosodi-n-propylamine 100 0
88 88.0 (41-116) 1,4-Dichlorobenzene 100 0
95 95.0 (36-97)
SPIKE MSD MSD ADDED CONCENTRATION ac LIMITS COMPOUND IJQ/L IJg/L REC RPD RPD REC.
1,2,4-Trichlorobenzene 100 87 81.0 8.3 28 (39-98)
Acenaphthene 100 85 85.0 29.7 31 (46-118) 2,4-Dinitrotoluene 100 70 70.0 10.5 38 (24-96)
Di-n-butyl phthalate 100 99 99.0 10.5 40 (11-117)
Pyrene 100 124 124.0 4.1 31 (26-127)
N-Nitrosodi-n-propylamine 100 86 86.0 2.3 38 (41-116) 1,4-Dichlorobenzene 100 75 75.0 23.5 28 (36-97)
- Column to be used to flag recovery and RPD values with an asterisk Values outside of ac limits RPD:
0 out of 7 outside limits Spike Recovery:
0 out of 14 outside limits Comments:
Page 66 of 78
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRY LABS, INC.
3039 Amwiler Road* Suite 100
- Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07106/2006 Pesticides/PCBs (8081A18082) - Appendix II SURROGATE PERCENT RECOVERY
SUMMARY
Water TCMX DCBP (30-130)
(30-130)
ACL Sample #
244063 167""
97 244064 90 48 244065 170""
58 244066 78 55
"* Matrix Interference DO=Diluted Out Page 67 of 78
IACL 1..--
A_D_V;_:4_N~C~'E~'D~C~'H~E~'M~Z~S~TR~Y~L_._A-B~S~, l~N~C-.
Phone: (770) 409-1444 3039 Amwiler Road* Suite 100* Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACl Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Pesticides/PCBs (8081A18082) - Appendix II Sample ID:
ACl Sample #:
Blank Units:
IJg/L Analyte Result PQl Aldrin SQL 0.05 Arochlor-1016 SQL 0.50 Arochlor-1221 SQL 0.50 Arochlor-1232 SQL 0.50 Arochlor-1242 SQL 0.50 Arochlor-1248 SQL 0.50 Arochlor-1254 SQL 0.50 Arochlor-1260 SQL 0.50 a-SHC SQL 0.05 b-SHC SQL 0.05 d-SHC SQL 0.05 g-SHC SQL 0.05 Chlordane SQL 0.10 4,4'-DDD SQL 0.05 4,4'-DDE SQL 0.05 4,4'-DDT SQL 0.05 Dieldrin SQL 0.05 Endosulfan I SQL 0.05 Endosulfan II SQL 0.05 Endosulfan sulfate SQL 0.05 Endrin SQL 0.05 Endrin aldehyde SQL 0.05 Heptachlor SQL 0.05 Heptachlor epoxide SQL 0.05 Methoxychlor SQL 0.05 Toxaphene SQL 2.00 Matrix:
Date Sampled:
Date Extracted:
Date Analyzed:
Analyst:
Water 06/12/2006 06/20/2006 AM Page 68 of 78
Advanced Chemistry Labs Pesticides Spike/Spike Dup. Report (SW-846 Method 8081A)
Instrument 10:
Column:
ACL #:
Matrix:
Extraction Date:
Analysis Date:
Initial Volume:
Final Volume:
Dilution Factor:
Unit:
HP5890A-ECDGC#1 STx-CLP, 30m, O.53mm, O.5pm LCS WATER 6/12/06 6/20106 1000.0 ml 1
1 pg/L or ppb R.T.
Spike Sample MS MS R.T.
MSD MSD RPD QCLimits Pesticide MS Added Result Cone.
Ree. (%)
MSD Cone.
Ree. (%)
(%)
RPD
% Recovery a-SHC 4.318 0.500 0.000 0.504 101 4.317 0.505 101 Q
25 40 160 g-BHC (Lindane) 4.870 0.500 0.000 0.473 95 4.869 0.475 95 0
25 40 160 b-BHC 5.066 0.500 0.000 0.428 86 5.065 0.430 86 0
25 40 160 d-BHC 5.431 0.500 0.000 0.457 91 5.431 0.460 92 0
25 40 160 Heptachlor 5.798 0.500 0.000 0.445 89 5.797 0.447 89 0
25 40 160 Aldrin 6.453 0.500 0.000 0.471 94 6.454 0.473 95 0
25 40 160 Heptachlor Epoxide 7.935 0.500 0.000 0:484 97 7.936 0.486 97 0
25 40 160 DDE 8.927 0.500 0.000 0.323 65 8.933 0.361 72 11 25 40 160 a-End05ulfan I 8.957 0.500 0.000 0.600 120 8.958 0.564 113 6
25 40 160 Dieldrin 9.648 0.500 0.000 0.460 92 9.649 0.421 84 9
25 40 160 Endrin 10.300 0.500 0.000 0.369 74 10.302 0.409 82 10 25 40 160 DDD 10.669 0.500 0.000 0.468 94 10.670 0.472 94 1
25 40 160 b-Endosulfan II 10.994 0.500
.. 0.000 0~493 99
' - 10:g95 0.498 100 1
- 25 40 160 DDT 11.497 0.500 0.000 0.554 111" 11.499 0.558 112 1
25 40 160 Endrin Aldehyde 12.296 0.500 0.000 0.444 89 12.298 0.448 90 1
25 40 160 Methoxychlor 13.213 0.500 0.000 0.663 133 13.220 0.716 143 8
25 40 160 Endo5ulfan Sulfate 13.684 0.500 0.000 0.418 84 13.686 0.424 85 1
25 40 160 Endrin Ketone 14.550 0.500 0.000 0.441 88 14.552 0.446 89 1
25 40 160 Pesticide Calculation based on curve prep. on
- Outside QC limits 01124106 Page 69 of 78
IACL 1
A_D_~_:4_N.....C......'E~V.....C-'H......E-'M
......Z-S-TR.....Y-L-A-B~S~, """""""'IN
........C_.
Phone: (770) 409-1444 3039 Amwiler Road* Suite 100* Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Chlorinated Herbicides (8151A) - Appendix II SURROGATE PERCENT RECOVERY
SUMMARY
Water oeAA (30-130)
ACL Sample #
244063 48 244064 49 244065 108 244066 119
- Matrix Interference DO=Diluted Out Page 70 of 78
IACL 1~
A_D_J!:_:4_N~C~'E~1)~C~'H~E~'M~I.~S~TR~Y~L~A~B~S~, l~N~C_.
Phone: (770) 409-1444 3039 Amwiler Road* Suite 100* Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Chlorinated Herbicides (8151A) - Appendix II Sample ID:
ACL Sample #:
Blank Units:
IJg/L Analyte Result PQL 2,4-D Sal 1.0 Dinoseb Sal 1.0 2,4,5-TP (Silvex)
Sal 1.0 2,4,5-T Sal
1.0 Matrix
Date Sampled:
Date Extracted:
Date Analyzed:
Analyst:
Water 06/08/2006 06/13/2006 AM Page 71 of 78
Instrument:
Date Extracted :
Date Analyzed :
ACL Sample No.:
ADVANCED CHEMISTRY LABS, INC.
Chlorinated Herbicides (8151A)
- Appendix II Water Matrix Spike/Spike Duplicate Recoveries HP5890A (w/Dual ECDs) 06-08-06 06-13-06 LCS060806 SPIKE SAMPLE MS MS MSD MSD Added Result Cone.
Rec.
Cone.
Rec.
QC Limits ANALYTE (ug/L)
(ug/L)
(ug/L)
(%)
(ug/L)
(%)
RPD RPD
% Recovery 2,4-0 4.00 0.000 1.79 45 1.72 43 4
25 40 160 I
Dinoseb 0.800 0.000 0.643 80 0.657 82 2
25 40 160 2,4,5-TP (Silvex) 0.800 0.000 0.655 82 0.630 79 4
25 40 160 2,4,5-T 0.800 0.000 0.958 120 0.928 116 3
25 40 160
- Outside QC Limits Comment:
Page 72 of 78
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRY LABS, INC.
3039 Amwiler Road* Suite 100
- Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Miscellaneous Organics (8011) - Appendix II SURROGATE PERCENT RECOVERY
SUMMARY
Water Bromofluorobenzene (40-140)
ACL Sample #
244061 111 244062 112 244063 109 244064 108 244065 121 244066 110 244067 109 244068 106
- Matrix Interference DO=Diluted Out Page 73 of 78
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 e-mail: acl@acl-Iabs.net ADVANCED CHEMISTRYLABS, INC.
3039 Amwiler Road* Suite 100
- Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt Batsel Client Proj #:
ACl Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Miscellaneous Organics (8011)
- Appendix II Sample 10:
ACl Sample #:
Blank Analyte 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Units:
Result SOL SOL j../g/L PQl 0.20 0.05 Matrix:
Date Sampled:
Date Extracted:
Date Analyzed:
Analyst:
Water 06/12/2006 06/14/2006 AM Page 74 of 78
Instrument:
Date Extracted :
Date Analyzed:
ACL Sample No.:
ADVANCED CHEMISTRY LABS, INC.
EDB/DBCP (8011)
Water Matrix Spike/Spike Duplicate Recoveries HP5890A-ECD GC#2 06-12-06 06-14-06 LCSW061206 SPIKE SAMPLE MS MS MSD MSD Added Result Cone.
Rec.
Cone.
Rec.
QC Limits ANALYTE (ug/L)
(ug/L)
(ug/L)
(%)
(ug/L)
(%)
RPD RPD
% Recovery EDS 0.500 0.000 0.382 76 0.432 86 12 25 60 140 DSCP 0.500 0.000 0.435 87 0.429 86 1
25 60 140
- Outside QC Limits Comment:
Page 75 of 78
IACL 1:.......-
A_D_VA_M~C"""""""'E~1J~C~'H-E-M~IS~T~'R~Y~L~A-B~S~, l~'N~C-.
Phone: (770) 409-1444 3039 Amwiler Road, Suite 100' Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610' Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client:
Contact:
The Dextra Group 1205 Johnson Ferry Rd.
Suite 136-446 Marietta, GA 30068-0000 Mr. Kurt 8atsel Client Proj #:
ACL Project #:
Date Received:
Date Reported:
Vogtle LF #3 50727 06/08/2006 07/06/2006 Appendix II Metals (6010B/7470Al7841/7041)
Sample 10:
ACL Sample #:
81ank Units:
mg/L Analyte Result POL Antimony Sal 0.006 Arsenic Sal 0.010 Sarium Sal 0.020 Seryllium Sal 0.004 Cadmium Sal 0.005 Chromium Sal 0.020 Cobalt Sal 0.050 Copper Sal 0.020 lead Sal 0.010 Mercury Sal 0.0005 Nickel Sal 0.020 Selenium Sal 0.040 Silver Sal 0.010 Thallium Sal 0.002 Tin Sal 0.025 Vanadium Sal 0.050 Zinc Sal 0.020
~~~~~ _._..-.--.---~~
Matrix:
Date Sampled:
Date Extracted:
Date Analyzed:
Analyst:
Water 06/12/2006 AD/JR Page 76 of 78
Instrument:
Date Digested:
Date Analyzed:
ACL Sample No.:
ADVANCED CHEMISTRY LABS, INC.
Appendix II Metals (6010Bf7470Al7841f7041)
Water Matrix Spike/Spike Duplicate Recoveries TJA 61E Trace ICAP 06-09-06 06-12-06 244066 (244068 for Hg)
SPIKE SAMPLE MS MS MSD MSD Added Result Cone.
Ree.
Cone.
Ree.
QC Limits ANALYTE (mgfL)
(mgfL)
(mgfL)
(%)
(mgfL)
(%)
RPD RPD
% Recovery Antimony (7041) 0.200 0.000 0.181 91 0.183 91 1
20 70 130 Arsenic 0.200 0.000 0.190 95 0.191 95 0
20 75 125 Barium 1.000 0.000 0.982 98 0.996 100 1
20 75 125 Beryllium 0.200 0.000 0.198 99 0.201 101 2
20 75 125 Cadmium 0.050 0.000 0.047 94 0.048 96 2
20 75 125 Chromium 0.200 0.000 0.199 99 0.203 101 2
20 75 125 Cobalt 0.200 0.000 0.194 97 0.197 98 1
20 75 125 Copper 0.200 0.000 0.203 101 0.207 103 2
20 75 125 Lead 0.200 0.000 0.195 98 0.198 99 1
20 75 125 Mercury (7470A) 0.0020 0.0000 0.0021 107 0.0022 108 1
20 70 130 Nickel 0.200 0.000 0.195 98 0.198 99 2
20 75 125 Selenium 0.050 0.000 0.045 90 0.046 92 2
20 75 125 Silver 0.020 0.000 0.019 96 0.019 96 0
20 75 125 Tin 0.200 0.000 0.189 94 0.191 95 1
20 75 125 Thallium (7841) 0.200 0.000 0.185 93 0.190 95 3
20 70 130 Vanadium 0.500 0.000 0.479 96 0.487 97 2
20 75 125 Zinc 0.200 0.063 0.256 96 0.257 97 1
20 75 125
- Outside QC Limits Comment:
Page 77 of 78
IACLI ADVANCED CHEMISTRY LABS, INC.
3039 Amwiler Road* Suite 100* Atlanta, GA 30360. P. O. Box 88610* Atlanta, GA 30356. (770) 409-1444* Fax (770) 409-1844 CHAIN-OF CUSTODY RECORD AND ANALYSIS REQUEST Company Name:
Phone #:(770) Pj1e-qh'l~
tn1£ 1XX7f?II GkJJrJ.f Fax # :(((O)g~/ "3"'ZJ<f-5 CO_r"!UlaIlY f~~~ess:
()..iJ /lL Site location:
VA"" JOr"'V?dI) t:'~~, ':zifC ~ 'ILI'-
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Project Manager:
Client Project: (#)
(Name) YarrL£ tF:ti:3 I attest that the proper field sampling Sampler Name (Print):
procedures were used during the r I
-tJ.
collection of these samples.
I i/Ot;,/f ( ~ cI Method F" Id Matnx Preserved Samplmg Ie Q; ~-r--r---r-r--r--+---r-r--r--r---,-+-----,~-~
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I Relinguished by :
CUSTODY RECORD Special Detection Limits Special Reporting Requirements FaxD TAT ~
Special Handling Priority (24 hr) D ACL Contact Rush (48 hr)
D IRush (72 hr)
D Quote #
I I
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APPENDIX C - STATISTICAL ANALYSES
Page 1 Concentrations (mg/L)
Parameter: Barium Original Data (Not Transformed)
Non-Detects Replaced with 1/2 DL Total Samples: 65 Total Non-Detect: 40 Percent Non-Detects: 61.5385%
Total Background Samples: 11 There is 1 background well Well Samples ND Date Result Original GWA-15/MW-1511 11 (100%)
7/30/2002 ND<0.01 ND<0.02 9/24/2002 ND<0.01 ND<0.02 10/21/2002 ~
ND<0.01 ND<0.02 12/3/2002 ND<0.005 ND<0.01 6/24/2003 ND<0.01 ND<0.02 12/17/2003 ND<0.01 ND<0.02 6/15/2004 ND<0.01 ND<0.02 12/28/2004 ND<0.01 ND<0.02 6/14/2005 ND<0.01 ND<0.02 12/5/2005 ND<0.01 ND<0.02 6/5/2006 ND<0.01 ND<0.02 There are 7 compliance wells Well Samples ND Date Result Original GWB-6/MW-6 11 11 (100%)
7/30/2002 ND<0.01 ND<0.02 9/24/2002 ND<0.01 ND<0.02 10/21/2002 ND<0.01 ND<0.02 12/3/2002 ND<0.005 ND<0.01 6/24/2003 ND<0.01 ND<0.02 12/17/2003 ND<0.01 ND<0.02 6/15/2004 ND<0.01 ND<0.02 12/28/2004 ND<0.01 ND<0.02 6/13/2005 ND<0.01 ND<0.02 12/5/2005 ND<0.01 ND<0.02 6/5/2006 ND<0.01 ND<0.02 GWC-13/MW-1311 0 (0%)
7/30/2002 0.077 0.077 9/24/2002 0.085 0.085 10/21/2002 0.083 0.083 12/3/2002 0.082 0.082 6/24/2003 ~
0.0295 0.0295 12/17/2003 ~
0.0325 0.0325 6/15/2004 ~
0.034 0.034 12/28/2004 0.043 0.043 6/13/2005 ~
0.03 0.03 12/6/2005 0.044 0.044 6/5/2006 0.051 0.051 GWC-14/MW-146 0 (0%)
7/30/2002 0.068 0.068 9/24/2002 ~
0.0935 0.0935 10/21/2002 0.064 0.064 12/3/2002 0.106 0.106
Page 2 6/24/2003 0.051 0.051 12/17/2003 0.189 0.189 GWC-5/MW-5 11 6 (54.5455%)
7/30/2002 ND<0.01 ND<0.02 9/24/2002 0.02 0.02 10/21/2002 ND<0.01 ND<0.02 12/3/2002 0.018 0.018 6/24/2003 ND<0.01 ND<0.02 12/17/2003 0.142 0.142 6/15/2004 0.04 0.04 12/28/2004 ND<0.01 ND<0.02 6/13/2005 ND<0.01 ND<0.02 12/6/2005 ND<0.01 ND<0.02 6/5/2006 0.031 0.031 GWC-17/MW-173 3 (100%)
6/15/2005 ND<0.01 ND<0.02 12/6/2005 ND<0.01 ND<0.02 6/5/2006 ND<0.01 ND<0.02 GWC-18/MW-181 1 (100%)
6/15/2005 ND<0.01 ND<0.02 GWA-7/MW-7 11 8 (72.7273%)
7/30/2002 ~
ND<0.01 ND<0.02 9/24/2002 ND<0.01 ND<0.02 10/21/2002 ND<0.01 ND<0.02 12/3/2002 0.015 0.015 6/24/2003 0.036 0.036 12/17/2003 ND<0.01 ND<0.02 6/15/2004 ND<0.01 ND<0.02 12/28/2004 ~
ND<0.01 ND<0.02 6/14/2005 ND<0.01 ND<0.02 12/6/2005 ~
0.023 0.023 6/5/2006 ~
ND<0.01 ND<0.02 There is 1 unused well Well Samples ND Date Result Original EQ-Blank 7
7 (100%)
6/24/2003 ND<0.01 ND<0.02 12/17/2003 ND<0.01 ND<0.02 6/15/2004 ND<0.01 ND<0.02 12/28/2004 ~
ND<0.01 ND<0.02 6/15/2005 ~
ND<0.01 ND<0.02 12/6/2005 ND<0.01 ND<0.02 6/6/2006 ND<0.01 ND<0.02
Page 3 Shapiro-Francia Test of Normality Parameter: Barium All Wells Normality Test of Parameter Concentrations Original Data (Not Transformed)
Non-Detects Replaced with 1/2 DL Total Sample Size = 65 i
x(i) m(i) sum(m^2) sum(mx) 0 0
0 0
0 1
0.005
-2.17009 4.70929
-0.0108505 2
0.005
-1.88079 8.24666
-0.0202544 3
0.01
-1.6954 11.121
-0.0372084 4
0.01
-1.55477 13.5384
-0.0527561 5
0.01
-1.43953 15.6106
-0.0671514 6
0.01
-1.34075 17.4082
-0.0805589 7
0.01
-1.24809 18.9659
-0.0930398 8
0.01
-1.17 20.3348
-0.10474 9
0.01
-1.09847 21.5415
-0.115725 10 0.01
-1.03215 22.6068
-0.126046 11 0.01
-0.970094 23.5479
-0.135747 12 0.01
-0.911562 24.3788
-0.144863 13 0.01
-0.855996 25.1116
-0.153423 14 0.01
-0.7995 25.7508
-0.161418 15 0.01
-0.748762 26.3114
-0.168905 16 0.01
-0.699883 26.8013
-0.175904 17 0.01
-0.652622 27.2272
-0.18243 18 0.01
-0.606775 27.5954
-0.188498 19 0.01
-0.56217 27.9114
-0.19412 20 0.01
-0.515791 28.1774
-0.199278 21 0.01
-0.473299 28.4014
-0.204011 22 0.01
-0.431644 28.5878
-0.208327 23 0.01
-0.390726 28.7404
-0.212234 24 0.01
-0.350451 28.8632
-0.215739 25 0.01
-0.310738 28.9598
-0.218846 26 0.01
-0.271509 29.0335
-0.221561 27 0.01
-0.230118 29.0865
-0.223862 28 0.01
-0.191671 29.1232
-0.225779 29 0.01
-0.153505 29.1468
-0.227314 30 0.01
-0.115562 29.1601
-0.22847 31 0.01
-0.0777834 29.1662
-0.229248 32 0.01
-0.0401167 29.1678
-0.229649 33 0.01 0
29.1678
-0.229649 34 0.01 0.0401167 29.1694
-0.229248 35 0.01 0.0777834 29.1754
-0.22847 36 0.01 0.115562 29.1888
-0.227314 37 0.01 0.153505 29.2124
-0.225779 38 0.01 0.191671 29.2491
-0.223862 39 0.01 0.230118 29.3021
-0.221561 40 0.01 0.271509 29.3758
-0.218846 41 0.015 0.310738 29.4723
-0.214185 42 0.018 0.350451 29.5951
-0.207877 43 0.02 0.390726 29.7478
-0.200062 44 0.023 0.431644 29.9341
-0.190135 45 0.0295 0.473299 30.1581
-0.176172 46 0.03 0.515791 30.4242
-0.160699
Page 4 47 0.031 0.56217 30.7402
-0.143271 48 0.0325 0.606775 31.1084
-0.123551 49 0.034 0.652622 31.5343
-0.101362 50 0.036 0.699883 32.0241
-0.0761662 51 0.04 0.748762 32.5848
-0.0462157 52 0.043 0.7995 33.224
-0.0118372 53 0.044 0.855996 33.9567 0.0258266 54 0.051 0.911562 34.7877 0.0723162 55 0.051 0.970094 35.7287 0.121791 56 0.064 1.03215 36.7941 0.187849 57 0.068 1.09847 38.0007 0.262545 58 0.077 1.17 39.3696 0.352635 59 0.082 1.24809 40.9273 0.454978 60 0.083 1.34075 42.725 0.566261 61 0.085 1.43953 44.7972 0.688621 62 0.0935 1.55477 47.2145 0.833992 63 0.106 1.6954 50.0889 1.0137 64 0.142 1.88079 53.6263 1.28078 Sample Standard Deviation = 0.0351945 Numerator = 1.64039 Denominator = 4.25116 = 64 53.6263 W Statistic = 0.385868 5% Critical value of 0.965 exceeds 0.385868 Evidence of non-normality at 95% level of significance 1% Critical value of 0.948 exceeds 0.385868 Evidence of non-normality at 99% level of significance
Page 5 Kruskal-Wallis Non-Parametric Test Parameter: Barium Original Data (Not Transformed)
Non-Detects Replaced with 1/2 DL Kruskal Wallis Ranks Background Wells Well ID Date Result Rank GWA-15/MW-157/30/2002 ND<0.01 20.5 9/24/2002 ND<0.01 20.5 10/21/2002 ~
ND<0.01 20.5 12/3/2002 ND<0.005 20.5 6/24/2003 ND<0.01 20.5 12/17/2003 ND<0.01 20.5 6/15/2004 ND<0.01 20.5 12/28/2004 ND<0.01 20.5 6/14/2005 ND<0.01 20.5 12/5/2005 ND<0.01 20.5 6/5/2006 ND<0.01 20.5 Rank Sum = 225.5 Rank Mean = 20.5 Background Rank Sum = 225.5 Background Rank Mean = 20.5 Compliance Wells Well ID Date Result Rank GWB-6/MW-6 7/30/2002 ND<0.01 20.5 9/24/2002 ND<0.01 20.5 10/21/2002 ND<0.01 20.5 12/3/2002 ND<0.005 20.5 6/24/2003 ND<0.01 20.5 12/17/2003 ND<0.01 20.5 6/15/2004 ND<0.01 20.5 12/28/2004 ND<0.01 20.5 6/13/2005 ND<0.01 20.5 12/5/2005 ND<0.01 20.5 6/5/2006 ND<0.01 20.5 Rank Sum = 225.5 Rank Mean = 20.5 GWC-13/MW-137/30/2002 0.077 58 9/24/2002 0.085 61 10/21/2002 0.083 60 12/3/2002 0.082 59 6/24/2003 ~
0.0295 45 12/17/2003 ~
0.0325 48 6/15/2004 ~
0.034 49 12/28/2004 0.043 52 6/13/2005 ~
0.03 46 12/6/2005 0.044 53 6/5/2006 0.051 54
Page 6 Rank Sum = 585 Rank Mean = 53.1818 GWC-14/MW-147/30/2002 0.068 57 9/24/2002 ~
0.0935 62 10/21/2002 0.064 56 12/3/2002 0.106 63 6/24/2003 0.051 55 12/17/2003 0.189 65 Rank Sum = 358 Rank Mean = 59.6667 GWC-5/MW-5 7/30/2002 ND<0.01 20.5 9/24/2002 0.02 43 10/21/2002 ND<0.01 20.5 12/3/2002 0.018 42 6/24/2003 ND<0.01 20.5 12/17/2003 0.142 64 6/15/2004 0.04 51 12/28/2004 ND<0.01 20.5 6/13/2005 ND<0.01 20.5 12/6/2005 ND<0.01 20.5 6/5/2006 0.031 47 Rank Sum = 370 Rank Mean = 33.6364 GWC-17/MW-176/15/2005 ND<0.01 20.5 12/6/2005 ND<0.01 20.5 6/5/2006 ND<0.01 20.5 Rank Sum = 61.5 Rank Mean = 20.5 GWC-18/MW-186/15/2005 ND<0.01 20.5 Rank Sum = 20.5 Rank Mean = 20.5 GWA-7/MW-7 7/30/2002 ~
ND<0.01 20.5 9/24/2002 ND<0.01 20.5 10/21/2002 ND<0.01 20.5 12/3/2002 0.015 41 6/24/2003 0.036 50 12/17/2003 ND<0.01 20.5 6/15/2004 ND<0.01 20.5 12/28/2004 ~
ND<0.01 20.5 6/14/2005 ND<0.01 20.5 12/6/2005 ~
0.023 44 6/5/2006 ~
ND<0.01 20.5 Rank Sum = 299 Rank Mean = 27.1818 Calculation Results:
Kruskal-Wallis H Statistic = 36.8849 Kruskal-Wallis H Statistic (adjusted for tied non-detects) = 48.087 95% Confidence comparison value is 14.0671 at 7 degrees of freedom 36.8849 > 14.0671 indicating a significant group difference at 5% significance level 48.087 > 14.0671 indicating a significant group difference at 5% significance level when adjusted for ties
Page 7 Individual Well Comparisons at 1% Significance Level per Comparison 1% Z score is 2.32634 Mean background rank is 20.5 Well Mean Rank Dif from Bkg Critical Value GWB-6/MW-6 20.5 0
18.7556 GWC-13/MW-1353.1818 32.6818 18.7556 GWC-14/MW-1459.6667 39.1667 22.3236 GWC-5/MW-5 33.6364 13.1364 18.7556 GWC-17/MW-1720.5 0
28.6496 GWC-18/MW-1820.5 0
45.9416 GWA-7/MW-7 27.1818 6.68182 18.7556 Individual Well Comparisons at Groupwise 5% Significance Level (0.714286% Significance Level per comparison) 0.714286% Z score is 2.45727 Mean background rank is 20.5 Well Mean Rank Dif from Bkg Critical Value GWB-6/MW-6 20.5 0
19.8112 GWC-13/MW-1353.1818 32.6818 19.8112 GWC-14/MW-1459.6667 39.1667 23.58 GWC-5/MW-5 33.6364 13.1364 19.8112 GWC-17/MW-1720.5 0
30.2621 GWC-18/MW-1820.5 0
48.5272 GWA-7/MW-7 27.1818 6.68182 19.8112
Page 8 Concentrations (mg/L)
Parameter: Zinc Original Data (Not Transformed)
Non-Detects Replaced with 1/2 DL Total Samples: 65 Total Non-Detect: 43 Percent Non-Detects: 66.1538%
Total Background Samples: 11 There is 1 background well Well Samples ND Date Result Original GWA-15/MW-1511 8 (72.7273%)
7/30/2002 ND<0.01 ND<0.02 9/24/2002 ND<0.01 ND<0.02 10/21/2002 ~
ND<0.01 ND<0.02 12/3/2002 ND<0.01 ND<0.02 6/24/2003 ND<0.01 ND<0.02 12/17/2003 ND<0.01 ND<0.02 6/15/2004 ND<0.01 ND<0.02 12/28/2004 ND<0.01 ND<0.02 6/14/2005 0.029 0.029 12/5/2005 0.042 0.042 6/5/2006 0.063 0.063 There are 7 compliance wells Well Samples ND Date Result Original GWB-6/MW-6 11 9 (81.8182%)
7/30/2002 ND<0.01 ND<0.02 9/24/2002 ND<0.01 ND<0.02 10/21/2002 ND<0.01 ND<0.02 12/3/2002 ND<0.01 ND<0.02 6/24/2003 ND<0.01 ND<0.02 12/17/2003 ND<0.01 ND<0.02 6/15/2004 ND<0.01 ND<0.02 12/28/2004 ND<0.01 ND<0.02 6/13/2005 ND<0.01 ND<0.02 12/5/2005 0.02 0.02 6/5/2006 0.083 0.083 GWC-13/MW-1311 4 (36.3636%)
7/30/2002 ND<0.01 ND<0.02 9/24/2002 0.023 0.023 10/21/2002 0.027 0.027 12/3/2002 0.027 0.027 6/24/2003 ~
ND<0.01 ND<0.02 12/17/2003 ~
ND<0.01 ND<0.02 6/15/2004 ~
ND<0.01 ND<0.02 12/28/2004 0.044 0.044 6/13/2005 ~
0.02 0.02 12/6/2005 0.194 0.194 6/5/2006 0.213 0.213 GWC-14/MW-146 5 (83.3333%)
7/30/2002 ND<0.01 ND<0.02 9/24/2002 ~
ND<0.01 ND<0.02 10/21/2002 ND<0.01 ND<0.02 12/3/2002 ND<0.01 ND<0.02
Page 9 6/24/2003 ND<0.01 ND<0.02 12/17/2003 0.127 0.127 GWC-5/MW-5 11 8 (72.7273%)
7/30/2002 ND<0.01 ND<0.02 9/24/2002 ND<0.01 ND<0.02 10/21/2002 ND<0.01 ND<0.02 12/3/2002 ND<0.01 ND<0.02 6/24/2003 ND<0.01 ND<0.02 12/17/2003 0.032 0.032 6/15/2004 ND<0.01 ND<0.02 12/28/2004 ND<0.01 ND<0.02 6/13/2005 ND<0.01 ND<0.02 12/6/2005 0.055 0.055 6/5/2006 0.1 0.1 GWC-17/MW-173 1 (33.3333%)
6/15/2005 ND<0.01 ND<0.02 12/6/2005 0.096 0.096 6/5/2006 0.077 0.077 GWC-18/MW-181 1 (100%)
6/15/2005 ND<0.01 ND<0.02 GWA-7/MW-7 11 7 (63.6364%)
7/30/2002 ~
ND<0.01 ND<0.02 9/24/2002 ND<0.01 ND<0.02 10/21/2002 ND<0.01 ND<0.02 12/3/2002 ND<0.01 ND<0.02 6/24/2003 0.034 0.034 12/17/2003 0.023 0.023 6/15/2004 ND<0.01 ND<0.02 12/28/2004 ~
ND<0.01 ND<0.02 6/14/2005 ND<0.01 ND<0.02 12/6/2005 ~
0.1425 0.1425 6/5/2006 ~
0.375 0.375 There is 1 unused well Well Samples ND Date Result Original EQ-Blank 7
7 (100%)
6/24/2003 ND<0.01 ND<0.02 12/17/2003 ND<0.01 ND<0.02 6/15/2004 ND<0.01 ND<0.02 12/28/2004 ~
ND<0.01 ND<0.02 6/15/2005 ~
ND<0.01 ND<0.02 12/6/2005 ND<0.01 ND<0.02 6/6/2006 ND<0.01 ND<0.02
Page 10 Shapiro-Francia Test of Normality Parameter: Zinc All Wells Normality Test of Parameter Concentrations Original Data (Not Transformed)
Non-Detects Replaced with 1/2 DL Total Sample Size = 65 i
x(i) m(i) sum(m^2) sum(mx) 0 0
0 0
0 1
0.01
-2.17009 4.70929
-0.0217009 2
0.01
-1.88079 8.24666
-0.0405088 3
0.01
-1.6954 11.121
-0.0574628 4
0.01
-1.55477 13.5384
-0.0730105 5
0.01
-1.43953 15.6106
-0.0874058 6
0.01
-1.34075 17.4082
-0.100813 7
0.01
-1.24809 18.9659
-0.113294 8
0.01
-1.17 20.3348
-0.124994 9
0.01
-1.09847 21.5415
-0.135979 10 0.01
-1.03215 22.6068
-0.1463 11 0.01
-0.970094 23.5479
-0.156001 12 0.01
-0.911562 24.3788
-0.165117 13 0.01
-0.855996 25.1116
-0.173677 14 0.01
-0.7995 25.7508
-0.181672 15 0.01
-0.748762 26.3114
-0.18916 16 0.01
-0.699883 26.8013
-0.196158 17 0.01
-0.652622 27.2272
-0.202685 18 0.01
-0.606775 27.5954
-0.208752 19 0.01
-0.56217 27.9114
-0.214374 20 0.01
-0.515791 28.1774
-0.219532 21 0.01
-0.473299 28.4014
-0.224265 22 0.01
-0.431644 28.5878
-0.228581 23 0.01
-0.390726 28.7404
-0.232489 24 0.01
-0.350451 28.8632
-0.235993 25 0.01
-0.310738 28.9598
-0.239101 26 0.01
-0.271509 29.0335
-0.241816 27 0.01
-0.230118 29.0865
-0.244117 28 0.01
-0.191671 29.1232
-0.246034 29 0.01
-0.153505 29.1468
-0.247569 30 0.01
-0.115562 29.1601
-0.248724 31 0.01
-0.0777834 29.1662
-0.249502 32 0.01
-0.0401167 29.1678
-0.249903 33 0.01 0
29.1678
-0.249903 34 0.01 0.0401167 29.1694
-0.249502 35 0.01 0.0777834 29.1754
-0.248724 36 0.01 0.115562 29.1888
-0.247569 37 0.01 0.153505 29.2124
-0.246034 38 0.01 0.191671 29.2491
-0.244117 39 0.01 0.230118 29.3021
-0.241816 40 0.01 0.271509 29.3758
-0.239101 41 0.01 0.310738 29.4723
-0.235993 42 0.01 0.350451 29.5951
-0.232489 43 0.01 0.390726 29.7478
-0.228581 44 0.02 0.431644 29.9341
-0.219949 45 0.02 0.473299 30.1581
-0.210483 46 0.023 0.515791 30.4242
-0.198619
Page 11 47 0.023 0.56217 30.7402
-0.185689 48 0.027 0.606775 31.1084
-0.169307 49 0.027 0.652622 31.5343
-0.151686 50 0.029 0.699883 32.0241
-0.131389 51 0.032 0.748762 32.5848
-0.107429 52 0.034 0.7995 33.224
-0.0802457 53 0.042 0.855996 33.9567
-0.0442939 54 0.044 0.911562 34.7877
-0.00418521 55 0.055 0.970094 35.7287 0.04917 56 0.063 1.03215 36.7941 0.114196 57 0.077 1.09847 38.0007 0.198778 58 0.083 1.17 39.3696 0.295888 59 0.096 1.24809 40.9273 0.415704 60 0.1 1.34075 42.725 0.54978 61 0.127 1.43953 44.7972 0.7326 62 0.1425 1.55477 47.2145 0.954155 63 0.194 1.6954 50.0889 1.28306 64 0.213 1.88079 53.6263 1.68367 Sample Standard Deviation = 0.0604282 Numerator = 2.83475 Denominator = 12.5325 = 64 53.6263 W Statistic = 0.226192 5% Critical value of 0.965 exceeds 0.226192 Evidence of non-normality at 95% level of significance 1% Critical value of 0.948 exceeds 0.226192 Evidence of non-normality at 99% level of significance
Page 12 Kruskal-Wallis Non-Parametric Test Parameter: Zinc Original Data (Not Transformed)
Non-Detects Replaced with 1/2 DL Kruskal Wallis Ranks Background Wells Well ID Date Result Rank GWA-15/MW-157/30/2002 ND<0.01 22 9/24/2002 ND<0.01 22 10/21/2002 ~
ND<0.01 22 12/3/2002 ND<0.01 22 6/24/2003 ND<0.01 22 12/17/2003 ND<0.01 22 6/15/2004 ND<0.01 22 12/28/2004 ND<0.01 22 6/14/2005 0.029 50 12/5/2005 0.042 53 6/5/2006 0.063 56 Rank Sum = 335 Rank Mean = 30.4545 Background Rank Sum = 335 Background Rank Mean = 30.4545 Compliance Wells Well ID Date Result Rank GWB-6/MW-6 7/30/2002 ND<0.01 22 9/24/2002 ND<0.01 22 10/21/2002 ND<0.01 22 12/3/2002 ND<0.01 22 6/24/2003 ND<0.01 22 12/17/2003 ND<0.01 22 6/15/2004 ND<0.01 22 12/28/2004 ND<0.01 22 6/13/2005 ND<0.01 22 12/5/2005 0.02 44 6/5/2006 0.083 58 Rank Sum = 300 Rank Mean = 27.2727 GWC-13/MW-137/30/2002 ND<0.01 22 9/24/2002 0.023 46 10/21/2002 0.027 48 12/3/2002 0.027 49 6/24/2003 ~
ND<0.01 22 12/17/2003 ~
ND<0.01 22 6/15/2004 ~
ND<0.01 22 12/28/2004 0.044 54 6/13/2005 ~
0.02 45 12/6/2005 0.194 63 6/5/2006 0.213 64
Page 13 Rank Sum = 457 Rank Mean = 41.5455 GWC-14/MW-147/30/2002 ND<0.01 22 9/24/2002 ~
ND<0.01 22 10/21/2002 ND<0.01 22 12/3/2002 ND<0.01 22 6/24/2003 ND<0.01 22 12/17/2003 0.127 61 Rank Sum = 171 Rank Mean = 28.5 GWC-5/MW-5 7/30/2002 ND<0.01 22 9/24/2002 ND<0.01 22 10/21/2002 ND<0.01 22 12/3/2002 ND<0.01 22 6/24/2003 ND<0.01 22 12/17/2003 0.032 51 6/15/2004 ND<0.01 22 12/28/2004 ND<0.01 22 6/13/2005 ND<0.01 22 12/6/2005 0.055 55 6/5/2006 0.1 60 Rank Sum = 342 Rank Mean = 31.0909 GWC-17/MW-176/15/2005 ND<0.01 22 12/6/2005 0.096 59 6/5/2006 0.077 57 Rank Sum = 138 Rank Mean = 46 GWC-18/MW-186/15/2005 ND<0.01 22 Rank Sum = 22 Rank Mean = 22 GWA-7/MW-7 7/30/2002 ~
ND<0.01 22 9/24/2002 ND<0.01 22 10/21/2002 ND<0.01 22 12/3/2002 ND<0.01 22 6/24/2003 0.034 52 12/17/2003 0.023 47 6/15/2004 ND<0.01 22 12/28/2004 ~
ND<0.01 22 6/14/2005 ND<0.01 22 12/6/2005 ~
0.1425 62 6/5/2006 ~
0.375 65 Rank Sum = 380 Rank Mean = 34.5455 Calculation Results:
Kruskal-Wallis H Statistic = 5.7377 Kruskal-Wallis H Statistic (adjusted for tied non-detects) = 8.0747 95% Confidence comparison value is 14.0671 at 7 degrees of freedom 5.7377 < 14.0671 indicating no significant group difference at 5% significance level 8.0747 < 14.0671 indicating no significant group difference at 5% significance level when adjusted for ties
Page 14
Page 15 Concentrations (µg/L)
Parameter: 1,1-Dichloroethane Original Data (Not Transformed)
Non-Detects Replaced with 1/2 DL Total Samples: 65 Total Non-Detect: 49 Percent Non-Detects: 75.3846%
Total Background Samples: 11 There is 1 background well Well Samples ND Date Result Original GWA-15/MW-1511 11 (100%)
7/30/2002 ND<2.5 ND<5 9/24/2002 ND<2.5 ND<5 10/21/2002 ~
ND<2.5 ND<5 12/3/2002 ND<2.5 ND<5 6/24/2003 ND<2.5 ND<5 12/17/2003 ND<2.5 ND<5 6/15/2004 ND<2.5 ND<5 12/28/2004 ND<2.5 ND<5 6/14/2005 ND<2.5 ND<5 12/5/2005 ND<2.5 ND<5 6/5/2006 ND<2.5 ND<5 There are 7 compliance wells Well Samples ND Date Result Original GWB-6/MW-6 11 11 (100%)
7/30/2002 ND<2.5 ND<5 9/24/2002 ND<2.5 ND<5 10/21/2002 ND<2.5 ND<5 12/3/2002 ND<2.5 ND<5 6/24/2003 ND<2.5 ND<5 12/17/2003 ND<2.5 ND<5 6/15/2004 ND<2.5 ND<5 12/28/2004 ND<2.5 ND<5 6/13/2005 ND<2.5 ND<5 12/5/2005 ND<2.5 ND<5 6/5/2006 ND<2.5 ND<5 GWC-13/MW-1311 1 (9.09091%)
7/30/2002 ND<2.5 ND<5 9/24/2002 6
6 10/21/2002 6
6 12/3/2002 7
7 6/24/2003 ~
9 9
12/17/2003 ~
20.5 20.5 6/15/2004 ~
18 18 12/28/2004 16 16 6/13/2005 ~
15 15 12/6/2005 18 18 6/5/2006 15 15 GWC-14/MW-146 0 (0%)
7/30/2002 13 13 9/24/2002 ~
21 21 10/21/2002 17 17 12/3/2002 16 16
Page 16 6/24/2003 10 10 12/17/2003 10 10 GWC-5/MW-5 11 11 (100%)
7/30/2002 ND<2.5 ND<5 9/24/2002 ND<2.5 ND<5 10/21/2002 ND<2.5 ND<5 12/3/2002 ND<2.5 ND<5 6/24/2003 ND<2.5 ND<5 12/17/2003 ND<2.5 ND<5 6/15/2004 ND<2.5 ND<5 12/28/2004 ND<2.5 ND<5 6/13/2005 ND<2.5 ND<5 12/6/2005 ND<2.5 ND<5 6/5/2006 ND<2.5 ND<5 GWC-17/MW-173 3 (100%)
6/15/2005 ND<2.5 ND<5 12/6/2005 ND<2.5 ND<5 6/5/2006 ND<2.5 ND<5 GWC-18/MW-181 1 (100%)
6/15/2005 ND<2.5 ND<5 GWA-7/MW-7 11 11 (100%)
7/30/2002 ~
ND<2.5 ND<5 9/24/2002 ND<2.5 ND<5 10/21/2002 ND<2.5 ND<5 12/3/2002 ND<2.5 ND<5 6/24/2003 ND<2.5 ND<5 12/17/2003 ND<2.5 ND<5 6/15/2004 ND<2.5 ND<5 12/28/2004 ~
ND<2.5 ND<5 6/14/2005 ND<2.5 ND<5 12/6/2005 ~
ND<2.5 ND<5 6/5/2006 ~
ND<2.5 ND<5 There are 2 unused wells Well Samples ND Date Result Original EQ-Blank 7
7 (100%)
6/24/2003 ND<2.5 ND<5 12/17/2003 ND<2.5 ND<5 6/15/2004 ND<2.5 ND<5 12/28/2004 ~
ND<2.5 ND<5 6/15/2005 ~
ND<2.5 ND<5 12/6/2005 ND<2.5 ND<5 6/6/2006 ND<2.5 ND<5 Trip Blank 3
3 (100%)
12/17/2003 ND<2.5 ND<5 6/13/2005 ND<2.5 ND<5 12/5/2005 ND<2.5 ND<5
Page 17 Shapiro-Francia Test of Normality Parameter: 1,1-Dichloroethane All Wells Normality Test of Parameter Concentrations Original Data (Not Transformed)
Non-Detects Replaced with 1/2 DL Total Sample Size = 65 i
x(i) m(i) sum(m^2) sum(mx) 0 0
0 0
0 1
2.5
-2.17009 4.70929
-5.42523 2
2.5
-1.88079 8.24666
-10.1272 3
2.5
-1.6954 11.121
-14.3657 4
2.5
-1.55477 13.5384
-18.2526 5
2.5
-1.43953 15.6106
-21.8515 6
2.5
-1.34075 17.4082
-25.2033 7
2.5
-1.24809 18.9659
-28.3236 8
2.5
-1.17 20.3348
-31.2486 9
2.5
-1.09847 21.5415
-33.9947 10 2.5
-1.03215 22.6068
-36.5751 11 2.5
-0.970094 23.5479
-39.0003 12 2.5
-0.911562 24.3788
-41.2793 13 2.5
-0.855996 25.1116
-43.4192 14 2.5
-0.7995 25.7508
-45.418 15 2.5
-0.748762 26.3114
-47.2899 16 2.5
-0.699883 26.8013
-49.0396 17 2.5
-0.652622 27.2272
-50.6712 18 2.5
-0.606775 27.5954
-52.1881 19 2.5
-0.56217 27.9114
-53.5935 20 2.5
-0.515791 28.1774
-54.883 21 2.5
-0.473299 28.4014
-56.0662 22 2.5
-0.431644 28.5878
-57.1454 23 2.5
-0.390726 28.7404
-58.1222 24 2.5
-0.350451 28.8632
-58.9983 25 2.5
-0.310738 28.9598
-59.7751 26 2.5
-0.271509 29.0335
-60.4539 27 2.5
-0.230118 29.0865
-61.0292 28 2.5
-0.191671 29.1232
-61.5084 29 2.5
-0.153505 29.1468
-61.8922 30 2.5
-0.115562 29.1601
-62.1811 31 2.5
-0.0777834 29.1662
-62.3755 32 2.5
-0.0401167 29.1678
-62.4758 33 2.5 0
29.1678
-62.4758 34 2.5 0.0401167 29.1694
-62.3755 35 2.5 0.0777834 29.1754
-62.1811 36 2.5 0.115562 29.1888
-61.8922 37 2.5 0.153505 29.2124
-61.5084 38 2.5 0.191671 29.2491
-61.0292 39 2.5 0.230118 29.3021
-60.4539 40 2.5 0.271509 29.3758
-59.7751 41 2.5 0.310738 29.4723
-58.9983 42 2.5 0.350451 29.5951
-58.1222 43 2.5 0.390726 29.7478
-57.1454 44 2.5 0.431644 29.9341
-56.0662 45 2.5 0.473299 30.1581
-54.883 46 2.5 0.515791 30.4242
-53.5935
Page 18 47 2.5 0.56217 30.7402
-52.1881 48 2.5 0.606775 31.1084
-50.6712 49 2.5 0.652622 31.5343
-49.0396 50 6
0.699883 32.0241
-44.8403 51 6
0.748762 32.5848
-40.3477 52 7
0.7995 33.224
-34.7512 53 9
0.855996 33.9567
-27.0473 54 10 0.911562 34.7877
-17.9317 55 10 0.970094 35.7287
-8.23071 56 13 1.03215 36.7941 5.18729 57 15 1.09847 38.0007 21.6643 58 15 1.17 39.3696 39.2143 59 16 1.24809 40.9273 59.1837 60 16 1.34075 42.725 80.6358 61 17 1.43953 44.7972 105.108 62 18 1.55477 47.2145 133.094 63 18 1.6954 50.0889 163.611 64 20.5 1.88079 53.6263 202.167 Sample Standard Deviation = 5.38957 Numerator = 40871.5 Denominator = 99693.3 = 64 53.6263 W Statistic = 0.409973 5% Critical value of 0.965 exceeds 0.409973 Evidence of non-normality at 95% level of significance 1% Critical value of 0.948 exceeds 0.409973 Evidence of non-normality at 99% level of significance
Page 19 Kruskal-Wallis Non-Parametric Test Parameter: 1,1-Dichloroethane Original Data (Not Transformed)
Non-Detects Replaced with 1/2 DL Kruskal Wallis Ranks Background Wells Well ID Date Result Rank GWA-15/MW-157/30/2002 ND<2.5 25 9/24/2002 ND<2.5 25 10/21/2002 ~
ND<2.5 25 12/3/2002 ND<2.5 25 6/24/2003 ND<2.5 25 12/17/2003 ND<2.5 25 6/15/2004 ND<2.5 25 12/28/2004 ND<2.5 25 6/14/2005 ND<2.5 25 12/5/2005 ND<2.5 25 6/5/2006 ND<2.5 25 Rank Sum = 275 Rank Mean = 25 Background Rank Sum = 275 Background Rank Mean = 25 Compliance Wells Well ID Date Result Rank GWB-6/MW-6 7/30/2002 ND<2.5 25 9/24/2002 ND<2.5 25 10/21/2002 ND<2.5 25 12/3/2002 ND<2.5 25 6/24/2003 ND<2.5 25 12/17/2003 ND<2.5 25 6/15/2004 ND<2.5 25 12/28/2004 ND<2.5 25 6/13/2005 ND<2.5 25 12/5/2005 ND<2.5 25 6/5/2006 ND<2.5 25 Rank Sum = 275 Rank Mean = 25 GWC-13/MW-137/30/2002 ND<2.5 25 9/24/2002 6
50 10/21/2002 6
51 12/3/2002 7
52 6/24/2003 ~
9 53 12/17/2003 ~
20.5 64 6/15/2004 ~
18 62 12/28/2004 16 59 6/13/2005 ~
15 57 12/6/2005 18 63 6/5/2006 15 58
Page 20 Rank Sum = 594 Rank Mean = 54 GWC-14/MW-147/30/2002 13 56 9/24/2002 ~
21 65 10/21/2002 17 61 12/3/2002 16 60 6/24/2003 10 54 12/17/2003 10 55 Rank Sum = 351 Rank Mean = 58.5 GWC-5/MW-5 7/30/2002 ND<2.5 25 9/24/2002 ND<2.5 25 10/21/2002 ND<2.5 25 12/3/2002 ND<2.5 25 6/24/2003 ND<2.5 25 12/17/2003 ND<2.5 25 6/15/2004 ND<2.5 25 12/28/2004 ND<2.5 25 6/13/2005 ND<2.5 25 12/6/2005 ND<2.5 25 6/5/2006 ND<2.5 25 Rank Sum = 275 Rank Mean = 25 GWC-17/MW-176/15/2005 ND<2.5 25 12/6/2005 ND<2.5 25 6/5/2006 ND<2.5 25 Rank Sum = 75 Rank Mean = 25 GWC-18/MW-186/15/2005 ND<2.5 25 Rank Sum = 25 Rank Mean = 25 GWA-7/MW-7 7/30/2002 ~
ND<2.5 25 9/24/2002 ND<2.5 25 10/21/2002 ND<2.5 25 12/3/2002 ND<2.5 25 6/24/2003 ND<2.5 25 12/17/2003 ND<2.5 25 6/15/2004 ND<2.5 25 12/28/2004 ~
ND<2.5 25 6/14/2005 ND<2.5 25 12/6/2005 ~
ND<2.5 25 6/5/2006 ~
ND<2.5 25 Rank Sum = 275 Rank Mean = 25 Calculation Results:
Kruskal-Wallis H Statistic = 33.0755 Kruskal-Wallis H Statistic (adjusted for tied non-detects) = 57.8569 95% Confidence comparison value is 14.0671 at 7 degrees of freedom 33.0755 > 14.0671 indicating a significant group difference at 5% significance level 57.8569 > 14.0671 indicating a significant group difference at 5% significance level when adjusted for ties
Page 21 Individual Well Comparisons at 1% Significance Level per Comparison 1% Z score is 2.32634 Mean background rank is 25 Well Mean Rank Dif from Bkg Critical Value GWB-6/MW-6 25 0
18.7556 GWC-13/MW-1354 29 18.7556 GWC-14/MW-1458.5 33.5 22.3236 GWC-5/MW-5 25 0
18.7556 GWC-17/MW-1725 0
28.6496 GWC-18/MW-1825 0
45.9416 GWA-7/MW-7 25 0
18.7556 Individual Well Comparisons at Groupwise 5% Significance Level (0.714286% Significance Level per comparison) 0.714286% Z score is 2.45727 Mean background rank is 25 Well Mean Rank Dif from Bkg Critical Value GWB-6/MW-6 25 0
19.8112 GWC-13/MW-1354 29 19.8112 GWC-14/MW-1458.5 33.5 23.58 GWC-5/MW-5 25 0
19.8112 GWC-17/MW-1725 0
30.2621 GWC-18/MW-1825 0
48.5272 GWA-7/MW-7 25 0
19.8112
Page 22 Concentrations (µg/L)
Parameter: cis-1,2-Dichloroethene Original Data (Not Transformed)
Non-Detects Replaced with 1/2 DL Total Samples: 65 Total Non-Detect: 52 Percent Non-Detects: 80%
Total Background Samples: 11 There is 1 background well Well Samples ND Date Result Original GWA-15/MW-1511 11 (100%)
7/30/2002 ND<2.5 ND<5 9/24/2002 ND<2.5 ND<5 10/21/2002 ~
ND<2.5 ND<5 12/3/2002 ND<2.5 ND<5 6/24/2003 ND<2.5 ND<5 12/17/2003 ND<2.5 ND<5 6/15/2004 ND<2.5 ND<5 12/28/2004 ND<2.5 ND<5 6/14/2005 ND<2.5 ND<5 12/5/2005 ND<2.5 ND<5 6/5/2006 ND<2.5 ND<5 There are 7 compliance wells Well Samples ND Date Result Original GWB-6/MW-6 11 11 (100%)
7/30/2002 ND<2.5 ND<5 9/24/2002 ND<2.5 ND<5 10/21/2002 ND<2.5 ND<5 12/3/2002 ND<2.5 ND<5 6/24/2003 ND<2.5 ND<5 12/17/2003 ND<2.5 ND<5 6/15/2004 ND<2.5 ND<5 12/28/2004 ND<2.5 ND<5 6/13/2005 ND<2.5 ND<5 12/5/2005 ND<2.5 ND<5 6/5/2006 ND<2.5 ND<5 GWC-13/MW-1311 4 (36.3636%)
7/30/2002 ND<2.5 ND<5 9/24/2002 ND<2.5 ND<5 10/21/2002 ND<2.5 ND<5 12/3/2002 ND<2.5 ND<5 6/24/2003 ~
6 6
12/17/2003 ~
14 14 6/15/2004 ~
9.5 9.5 12/28/2004 8
8 6/13/2005 ~
8 8
12/6/2005 9
9 6/5/2006 8
8 GWC-14/MW-146 0 (0%)
7/30/2002 10 10 9/24/2002 ~
18.5 18.5 10/21/2002 16 16 12/3/2002 19 19
Page 23 6/24/2003 10 10 12/17/2003 17 17 GWC-5/MW-5 11 11 (100%)
7/30/2002 ND<2.5 ND<5 9/24/2002 ND<2.5 ND<5 10/21/2002 ND<2.5 ND<5 12/3/2002 ND<2.5 ND<5 6/24/2003 ND<2.5 ND<5 12/17/2003 ND<2.5 ND<5 6/15/2004 ND<2.5 ND<5 12/28/2004 ND<2.5 ND<5 6/13/2005 ND<2.5 ND<5 12/6/2005 ND<2.5 ND<5 6/5/2006 ND<2.5 ND<5 GWC-17/MW-173 3 (100%)
6/15/2005 ND<2.5 ND<5 12/6/2005 ND<2.5 ND<5 6/5/2006 ND<2.5 ND<5 GWC-18/MW-181 1 (100%)
6/15/2005 ND<2.5 ND<5 GWA-7/MW-7 11 11 (100%)
7/30/2002 ~
ND<2.5 ND<5 9/24/2002 ND<2.5 ND<5 10/21/2002 ND<2.5 ND<5 12/3/2002 ND<2.5 ND<5 6/24/2003 ND<2.5 ND<5 12/17/2003 ND<2.5 ND<5 6/15/2004 ND<2.5 ND<5 12/28/2004 ~
ND<2.5 ND<5 6/14/2005 ND<2.5 ND<5 12/6/2005 ~
ND<2.5 ND<5 6/5/2006 ~
ND<2.5 ND<5 There are 2 unused wells Well Samples ND Date Result Original EQ-Blank 7
7 (100%)
6/24/2003 ND<2.5 ND<5 12/17/2003 ND<2.5 ND<5 6/15/2004 ND<2.5 ND<5 12/28/2004 ~
ND<2.5 ND<5 6/15/2005 ~
ND<2.5 ND<5 12/6/2005 ND<2.5 ND<5 6/6/2006 ND<2.5 ND<5 Trip Blank 3
3 (100%)
12/17/2003 ND<2.5 ND<5 6/13/2005 ND<2.5 ND<5 12/5/2005 ND<2.5 ND<5
Page 24 Shapiro-Francia Test of Normality Parameter: cis-1,2-Dichloroethene All Wells Normality Test of Parameter Concentrations Original Data (Not Transformed)
Non-Detects Replaced with 1/2 DL Total Sample Size = 65 i
x(i) m(i) sum(m^2) sum(mx) 0 0
0 0
0 1
2.5
-2.17009 4.70929
-5.42523 2
2.5
-1.88079 8.24666
-10.1272 3
2.5
-1.6954 11.121
-14.3657 4
2.5
-1.55477 13.5384
-18.2526 5
2.5
-1.43953 15.6106
-21.8515 6
2.5
-1.34075 17.4082
-25.2033 7
2.5
-1.24809 18.9659
-28.3236 8
2.5
-1.17 20.3348
-31.2486 9
2.5
-1.09847 21.5415
-33.9947 10 2.5
-1.03215 22.6068
-36.5751 11 2.5
-0.970094 23.5479
-39.0003 12 2.5
-0.911562 24.3788
-41.2793 13 2.5
-0.855996 25.1116
-43.4192 14 2.5
-0.7995 25.7508
-45.418 15 2.5
-0.748762 26.3114
-47.2899 16 2.5
-0.699883 26.8013
-49.0396 17 2.5
-0.652622 27.2272
-50.6712 18 2.5
-0.606775 27.5954
-52.1881 19 2.5
-0.56217 27.9114
-53.5935 20 2.5
-0.515791 28.1774
-54.883 21 2.5
-0.473299 28.4014
-56.0662 22 2.5
-0.431644 28.5878
-57.1454 23 2.5
-0.390726 28.7404
-58.1222 24 2.5
-0.350451 28.8632
-58.9983 25 2.5
-0.310738 28.9598
-59.7751 26 2.5
-0.271509 29.0335
-60.4539 27 2.5
-0.230118 29.0865
-61.0292 28 2.5
-0.191671 29.1232
-61.5084 29 2.5
-0.153505 29.1468
-61.8922 30 2.5
-0.115562 29.1601
-62.1811 31 2.5
-0.0777834 29.1662
-62.3755 32 2.5
-0.0401167 29.1678
-62.4758 33 2.5 0
29.1678
-62.4758 34 2.5 0.0401167 29.1694
-62.3755 35 2.5 0.0777834 29.1754
-62.1811 36 2.5 0.115562 29.1888
-61.8922 37 2.5 0.153505 29.2124
-61.5084 38 2.5 0.191671 29.2491
-61.0292 39 2.5 0.230118 29.3021
-60.4539 40 2.5 0.271509 29.3758
-59.7751 41 2.5 0.310738 29.4723
-58.9983 42 2.5 0.350451 29.5951
-58.1222 43 2.5 0.390726 29.7478
-57.1454 44 2.5 0.431644 29.9341
-56.0662 45 2.5 0.473299 30.1581
-54.883 46 2.5 0.515791 30.4242
-53.5935
Page 25 47 2.5 0.56217 30.7402
-52.1881 48 2.5 0.606775 31.1084
-50.6712 49 2.5 0.652622 31.5343
-49.0396 50 2.5 0.699883 32.0241
-47.2899 51 2.5 0.748762 32.5848
-45.418 52 2.5 0.7995 33.224
-43.4192 53 6
0.855996 33.9567
-38.2833 54 8
0.911562 34.7877
-30.9908 55 8
0.970094 35.7287
-23.23 56 8
1.03215 36.7941
-14.9728 57 9
1.09847 38.0007
-5.08657 58 9.5 1.17 39.3696 6.02845 59 10 1.24809 40.9273 18.5093 60 10 1.34075 42.725 31.9168 61 14 1.43953 44.7972 52.0703 62 16 1.55477 47.2145 76.9466 63 17 1.6954 50.0889 105.768 64 18.5 1.88079 53.6263 140.563 Sample Standard Deviation = 4.21375 Numerator = 19758 Denominator = 60938.8 = 64 53.6263 W Statistic = 0.324226 5% Critical value of 0.965 exceeds 0.324226 Evidence of non-normality at 95% level of significance 1% Critical value of 0.948 exceeds 0.324226 Evidence of non-normality at 99% level of significance
Page 26 Kruskal-Wallis Non-Parametric Test Parameter: cis-1,2-Dichloroethene Original Data (Not Transformed)
Non-Detects Replaced with 1/2 DL Kruskal Wallis Ranks Background Wells Well ID Date Result Rank GWA-15/MW-157/30/2002 ND<2.5 26.5 9/24/2002 ND<2.5 26.5 10/21/2002 ~
ND<2.5 26.5 12/3/2002 ND<2.5 26.5 6/24/2003 ND<2.5 26.5 12/17/2003 ND<2.5 26.5 6/15/2004 ND<2.5 26.5 12/28/2004 ND<2.5 26.5 6/14/2005 ND<2.5 26.5 12/5/2005 ND<2.5 26.5 6/5/2006 ND<2.5 26.5 Rank Sum = 291.5 Rank Mean = 26.5 Background Rank Sum = 291.5 Background Rank Mean = 26.5 Compliance Wells Well ID Date Result Rank GWB-6/MW-6 7/30/2002 ND<2.5 26.5 9/24/2002 ND<2.5 26.5 10/21/2002 ND<2.5 26.5 12/3/2002 ND<2.5 26.5 6/24/2003 ND<2.5 26.5 12/17/2003 ND<2.5 26.5 6/15/2004 ND<2.5 26.5 12/28/2004 ND<2.5 26.5 6/13/2005 ND<2.5 26.5 12/5/2005 ND<2.5 26.5 6/5/2006 ND<2.5 26.5 Rank Sum = 291.5 Rank Mean = 26.5 GWC-13/MW-137/30/2002 ND<2.5 26.5 9/24/2002 ND<2.5 26.5 10/21/2002 ND<2.5 26.5 12/3/2002 ND<2.5 26.5 6/24/2003 ~
6 53 12/17/2003 ~
14 61 6/15/2004 ~
9.5 58 12/28/2004 8
54 6/13/2005 ~
8 55 12/6/2005 9
57 6/5/2006 8
56
Page 27 Rank Sum = 500 Rank Mean = 45.4545 GWC-14/MW-147/30/2002 10 59 9/24/2002 ~
18.5 64 10/21/2002 16 62 12/3/2002 19 65 6/24/2003 10 60 12/17/2003 17 63 Rank Sum = 373 Rank Mean = 62.1667 GWC-5/MW-5 7/30/2002 ND<2.5 26.5 9/24/2002 ND<2.5 26.5 10/21/2002 ND<2.5 26.5 12/3/2002 ND<2.5 26.5 6/24/2003 ND<2.5 26.5 12/17/2003 ND<2.5 26.5 6/15/2004 ND<2.5 26.5 12/28/2004 ND<2.5 26.5 6/13/2005 ND<2.5 26.5 12/6/2005 ND<2.5 26.5 6/5/2006 ND<2.5 26.5 Rank Sum = 291.5 Rank Mean = 26.5 GWC-17/MW-176/15/2005 ND<2.5 26.5 12/6/2005 ND<2.5 26.5 6/5/2006 ND<2.5 26.5 Rank Sum = 79.5 Rank Mean = 26.5 GWC-18/MW-186/15/2005 ND<2.5 26.5 Rank Sum = 26.5 Rank Mean = 26.5 GWA-7/MW-7 7/30/2002 ~
ND<2.5 26.5 9/24/2002 ND<2.5 26.5 10/21/2002 ND<2.5 26.5 12/3/2002 ND<2.5 26.5 6/24/2003 ND<2.5 26.5 12/17/2003 ND<2.5 26.5 6/15/2004 ND<2.5 26.5 12/28/2004 ~
ND<2.5 26.5 6/14/2005 ND<2.5 26.5 12/6/2005 ~
ND<2.5 26.5 6/5/2006 ~
ND<2.5 26.5 Rank Sum = 291.5 Rank Mean = 26.5 Calculation Results:
Kruskal-Wallis H Statistic = 24.7229 Kruskal-Wallis H Statistic (adjusted for tied non-detects) = 50.6546 95% Confidence comparison value is 14.0671 at 7 degrees of freedom 24.7229 > 14.0671 indicating a significant group difference at 5% significance level 50.6546 > 14.0671 indicating a significant group difference at 5% significance level when adjusted for ties
Page 28 Individual Well Comparisons at 1% Significance Level per Comparison 1% Z score is 2.32634 Mean background rank is 26.5 Well Mean Rank Dif from Bkg Critical Value GWB-6/MW-6 26.5 0
18.7556 GWC-13/MW-1345.4545 18.9545 18.7556 GWC-14/MW-1462.1667 35.6667 22.3236 GWC-5/MW-5 26.5 0
18.7556 GWC-17/MW-1726.5 0
28.6496 GWC-18/MW-1826.5 0
45.9416 GWA-7/MW-7 26.5 0
18.7556 Individual Well Comparisons at Groupwise 5% Significance Level (0.714286% Significance Level per comparison) 0.714286% Z score is 2.45727 Mean background rank is 26.5 Well Mean Rank Dif from Bkg Critical Value GWB-6/MW-6 26.5 0
19.8112 GWC-13/MW-1345.4545 18.9545 19.8112 GWC-14/MW-1462.1667 35.6667 23.58 GWC-5/MW-5 26.5 0
19.8112 GWC-17/MW-1726.5 0
30.2621 GWC-18/MW-1826.5 0
48.5272 GWA-7/MW-7 26.5 0
19.8112
Page 29 Concentrations (µg/L)
Parameter: Trichlorofluoromethane Original Data (Not Transformed)
Non-Detects Replaced with 1/2 DL Total Samples: 65 Total Non-Detect: 38 Percent Non-Detects: 58.4615%
Total Background Samples: 11 There is 1 background well Well Samples ND Date Result Original GWA-15/MW-1511 11 (100%)
7/30/2002 ND<2.5 ND<5 9/24/2002 ND<2.5 ND<5 10/21/2002 ~
ND<2.5 ND<5 12/3/2002 ND<2.5 ND<5 6/24/2003 ND<2.5 ND<5 12/17/2003 ND<2.5 ND<5 6/15/2004 ND<2.5 ND<5 12/28/2004 ND<2.5 ND<5 6/14/2005 ND<2.5 ND<5 12/5/2005 ND<2.5 ND<5 6/5/2006 ND<2.5 ND<5 There are 7 compliance wells Well Samples ND Date Result Original GWB-6/MW-6 11 11 (100%)
7/30/2002 ND<2.5 ND<5 9/24/2002 ND<2.5 ND<5 10/21/2002 ND<2.5 ND<5 12/3/2002 ND<2.5 ND<5 6/24/2003 ND<2.5 ND<5 12/17/2003 ND<2.5 ND<5 6/15/2004 ND<2.5 ND<5 12/28/2004 ND<2.5 ND<5 6/13/2005 ND<2.5 ND<5 12/5/2005 ND<2.5 ND<5 6/5/2006 ND<2.5 ND<5 GWC-13/MW-1311 0 (0%)
7/30/2002 300 300 9/24/2002 381 381 10/21/2002 348 348 12/3/2002 391 391 6/24/2003 ~
44 44 12/17/2003 ~
99.5 99.5 6/15/2004 ~
127 127 12/28/2004 81 81 6/13/2005 ~
45.3333 45.3333 12/6/2005 60 60 6/5/2006 92 92 GWC-14/MW-146 1 (16.6667%)
7/30/2002 43 43 9/24/2002 ~
47.5 47.5 10/21/2002 31 31 12/3/2002 27 27
Page 30 6/24/2003 5
5 12/17/2003 ND<2.5 ND<5 GWC-5/MW-5 11 11 (100%)
7/30/2002 ND<2.5 ND<5 9/24/2002 ND<2.5 ND<5 10/21/2002 ND<2.5 ND<5 12/3/2002 ND<2.5 ND<5 6/24/2003 ND<2.5 ND<5 12/17/2003 ND<2.5 ND<5 6/15/2004 ND<2.5 ND<5 12/28/2004 ND<2.5 ND<5 6/13/2005 ND<2.5 ND<5 12/6/2005 ND<2.5 ND<5 6/5/2006 ND<2.5 ND<5 GWC-17/MW-173 3 (100%)
6/15/2005 ND<2.5 ND<5 12/6/2005 ND<2.5 ND<5 6/5/2006 ND<2.5 ND<5 GWC-18/MW-181 1 (100%)
6/15/2005 ND<2.5 ND<5 GWA-7/MW-7 11 0 (0%)
7/30/2002 ~
184.5 184.5 9/24/2002 32 32 10/21/2002 221 221 12/3/2002 210 210 6/24/2003 23 23 12/17/2003 34 34 6/15/2004 46 46 12/28/2004 ~
144 144 6/14/2005 22 22 12/6/2005 ~
86.5 86.5 6/5/2006 ~
80 80 There are 2 unused wells Well Samples ND Date Result Original EQ-Blank 7
7 (100%)
6/24/2003 ND<2.5 ND<5 12/17/2003 ND<2.5 ND<5 6/15/2004 ND<2.5 ND<5 12/28/2004 ~
ND<2.5 ND<5 6/15/2005 ~
ND<2.5 ND<5 12/6/2005 ND<2.5 ND<5 6/6/2006 ND<2.5 ND<5 Trip Blank 3
3 (100%)
12/17/2003 ND<2.5 ND<5 6/13/2005 ND<2.5 ND<5 12/5/2005 ND<2.5 ND<5
Page 31 Shapiro-Francia Test of Normality Parameter: Trichlorofluoromethane All Wells Normality Test of Parameter Concentrations Original Data (Not Transformed)
Non-Detects Replaced with 1/2 DL Total Sample Size = 65 i
x(i) m(i) sum(m^2) sum(mx) 0 0
0 0
0 1
2.5
-2.17009 4.70929
-5.42523 2
2.5
-1.88079 8.24666
-10.1272 3
2.5
-1.6954 11.121
-14.3657 4
2.5
-1.55477 13.5384
-18.2526 5
2.5
-1.43953 15.6106
-21.8515 6
2.5
-1.34075 17.4082
-25.2033 7
2.5
-1.24809 18.9659
-28.3236 8
2.5
-1.17 20.3348
-31.2486 9
2.5
-1.09847 21.5415
-33.9947 10 2.5
-1.03215 22.6068
-36.5751 11 2.5
-0.970094 23.5479
-39.0003 12 2.5
-0.911562 24.3788
-41.2793 13 2.5
-0.855996 25.1116
-43.4192 14 2.5
-0.7995 25.7508
-45.418 15 2.5
-0.748762 26.3114
-47.2899 16 2.5
-0.699883 26.8013
-49.0396 17 2.5
-0.652622 27.2272
-50.6712 18 2.5
-0.606775 27.5954
-52.1881 19 2.5
-0.56217 27.9114
-53.5935 20 2.5
-0.515791 28.1774
-54.883 21 2.5
-0.473299 28.4014
-56.0662 22 2.5
-0.431644 28.5878
-57.1454 23 2.5
-0.390726 28.7404
-58.1222 24 2.5
-0.350451 28.8632
-58.9983 25 2.5
-0.310738 28.9598
-59.7751 26 2.5
-0.271509 29.0335
-60.4539 27 2.5
-0.230118 29.0865
-61.0292 28 2.5
-0.191671 29.1232
-61.5084 29 2.5
-0.153505 29.1468
-61.8922 30 2.5
-0.115562 29.1601
-62.1811 31 2.5
-0.0777834 29.1662
-62.3755 32 2.5
-0.0401167 29.1678
-62.4758 33 2.5 0
29.1678
-62.4758 34 2.5 0.0401167 29.1694
-62.3755 35 2.5 0.0777834 29.1754
-62.1811 36 2.5 0.115562 29.1888
-61.8922 37 2.5 0.153505 29.2124
-61.5084 38 2.5 0.191671 29.2491
-61.0292 39 5
0.230118 29.3021
-59.8786 40 22 0.271509 29.3758
-53.9054 41 23 0.310738 29.4723
-46.7584 42 27 0.350451 29.5951
-37.2963 43 31 0.390726 29.7478
-25.1838 44 32 0.431644 29.9341
-11.3712 45 34 0.473299 30.1581 4.72099 46 43 0.515791 30.4242 26.9
Page 32 47 44 0.56217 30.7402 51.6355 48 45.3333 0.606775 31.1084 79.1426 49 46 0.652622 31.5343 109.163 50 47.5 0.699883 32.0241 142.408 51 60 0.748762 32.5848 187.333 52 80 0.7995 33.224 251.293 53 81 0.855996 33.9567 320.629 54 86.5 0.911562 34.7877 399.479 55 92 0.970094 35.7287 488.728 56 99.5 1.03215 36.7941 591.427 57 127 1.09847 38.0007 730.933 58 144 1.17 39.3696 899.413 59 184.5 1.24809 40.9273 1129.68 60 210 1.34075 42.725 1411.24 61 221 1.43953 44.7972 1729.38 62 300 1.55477 47.2145 2195.81 63 348 1.6954 50.0889 2785.81 64 381 1.88079 53.6263 3502.39 Sample Standard Deviation = 93.8071 Numerator = 1.22667e+007 Denominator = 3.02015e+007 = 64 53.6263 W Statistic = 0.406163 5% Critical value of 0.965 exceeds 0.406163 Evidence of non-normality at 95% level of significance 1% Critical value of 0.948 exceeds 0.406163 Evidence of non-normality at 99% level of significance
Page 33 Kruskal-Wallis Non-Parametric Test Parameter: Trichlorofluoromethane Original Data (Not Transformed)
Non-Detects Replaced with 1/2 DL Kruskal Wallis Ranks Background Wells Well ID Date Result Rank GWA-15/MW-157/30/2002 ND<2.5 19.5 9/24/2002 ND<2.5 19.5 10/21/2002 ~
ND<2.5 19.5 12/3/2002 ND<2.5 19.5 6/24/2003 ND<2.5 19.5 12/17/2003 ND<2.5 19.5 6/15/2004 ND<2.5 19.5 12/28/2004 ND<2.5 19.5 6/14/2005 ND<2.5 19.5 12/5/2005 ND<2.5 19.5 6/5/2006 ND<2.5 19.5 Rank Sum = 214.5 Rank Mean = 19.5 Background Rank Sum = 214.5 Background Rank Mean = 19.5 Compliance Wells Well ID Date Result Rank GWB-6/MW-6 7/30/2002 ND<2.5 19.5 9/24/2002 ND<2.5 19.5 10/21/2002 ND<2.5 19.5 12/3/2002 ND<2.5 19.5 6/24/2003 ND<2.5 19.5 12/17/2003 ND<2.5 19.5 6/15/2004 ND<2.5 19.5 12/28/2004 ND<2.5 19.5 6/13/2005 ND<2.5 19.5 12/5/2005 ND<2.5 19.5 6/5/2006 ND<2.5 19.5 Rank Sum = 214.5 Rank Mean = 19.5 GWC-13/MW-137/30/2002 300 62 9/24/2002 381 64 10/21/2002 348 63 12/3/2002 391 65 6/24/2003 ~
44 47 12/17/2003 ~
99.5 56 6/15/2004 ~
127 57 12/28/2004 81 53 6/13/2005 ~
45.3333 48 12/6/2005 60 51 6/5/2006 92 55
Page 34 Rank Sum = 621 Rank Mean = 56.4545 GWC-14/MW-147/30/2002 43 46 9/24/2002 ~
47.5 50 10/21/2002 31 43 12/3/2002 27 42 6/24/2003 5
39 12/17/2003 ND<2.5 19.5 Rank Sum = 239.5 Rank Mean = 39.9167 GWC-5/MW-5 7/30/2002 ND<2.5 19.5 9/24/2002 ND<2.5 19.5 10/21/2002 ND<2.5 19.5 12/3/2002 ND<2.5 19.5 6/24/2003 ND<2.5 19.5 12/17/2003 ND<2.5 19.5 6/15/2004 ND<2.5 19.5 12/28/2004 ND<2.5 19.5 6/13/2005 ND<2.5 19.5 12/6/2005 ND<2.5 19.5 6/5/2006 ND<2.5 19.5 Rank Sum = 214.5 Rank Mean = 19.5 GWC-17/MW-176/15/2005 ND<2.5 19.5 12/6/2005 ND<2.5 19.5 6/5/2006 ND<2.5 19.5 Rank Sum = 58.5 Rank Mean = 19.5 GWC-18/MW-186/15/2005 ND<2.5 19.5 Rank Sum = 19.5 Rank Mean = 19.5 GWA-7/MW-7 7/30/2002 ~
184.5 59 9/24/2002 32 44 10/21/2002 221 61 12/3/2002 210 60 6/24/2003 23 41 12/17/2003 34 45 6/15/2004 46 49 12/28/2004 ~
144 58 6/14/2005 22 40 12/6/2005 ~
86.5 54 6/5/2006 ~
80 52 Rank Sum = 563 Rank Mean = 51.1818 Calculation Results:
Kruskal-Wallis H Statistic = 46.7634 Kruskal-Wallis H Statistic (adjusted for tied non-detects) = 58.4335 95% Confidence comparison value is 14.0671 at 7 degrees of freedom 46.7634 > 14.0671 indicating a significant group difference at 5% significance level 58.4335 > 14.0671 indicating a significant group difference at 5% significance level when adjusted for ties
Page 35 Individual Well Comparisons at 1% Significance Level per Comparison 1% Z score is 2.32634 Mean background rank is 19.5 Well Mean Rank Dif from Bkg Critical Value GWB-6/MW-6 19.5 0
18.7556 GWC-13/MW-1356.4545 36.9545 18.7556 GWC-14/MW-1439.9167 20.4167 22.3236 GWC-5/MW-5 19.5 0
18.7556 GWC-17/MW-1719.5 0
28.6496 GWC-18/MW-1819.5 0
45.9416 GWA-7/MW-7 51.1818 31.6818 18.7556 Individual Well Comparisons at Groupwise 5% Significance Level (0.714286% Significance Level per comparison) 0.714286% Z score is 2.45727 Mean background rank is 19.5 Well Mean Rank Dif from Bkg Critical Value GWB-6/MW-6 19.5 0
19.8112 GWC-13/MW-1356.4545 36.9545 19.8112 GWC-14/MW-1439.9167 20.4167 23.58 GWC-5/MW-5 19.5 0
19.8112 GWC-17/MW-1719.5 0
30.2621 GWC-18/MW-1819.5 0
48.5272 GWA-7/MW-7 51.1818 31.6818 19.8112