ML073300611
ML073300611 | |
Person / Time | |
---|---|
Site: | Vogtle |
Issue date: | 03/17/2004 |
From: | Carr W Southern Nuclear Operating Co |
To: | Gillespie H Office of Nuclear Reactor Regulation, State of GA, Environmental Protection Div |
References | |
017-006D(L)(I), 017-007D(L)(I), EV-04-0432 | |
Download: ML073300611 (199) | |
Text
{{#Wiki_filter:Southern Nuclear Operating Company, Inc. Post Office Box 1295 Birmingham, Alabama 35201-1295 Tel 205.992.5000 SOUTHERN COMPANY A. Energy to Serve Your World"" File: E.03.40C Log: EV-04-0432 March 17, 2004 FEDERAL EXPRESS Vogtle Electric Generating Plant Landfill #2 and #3 Solid Waste Permit No. 017-006D(L)(I) Solid Waste Permit No. 017-007D(L)(I) Mr. Harold C. Gillespie Unit Coordinator - Industrial Solid Waste Unit Georgia Environmental Protection Division 4244 International Parkway, Suite 104 Atlanta, GA 30354
Dear Mr. Gillespie:
Pursuant to EPD Solid Waste Rule 391-3-4-.14 and in accordance with the approved Plant Vogtle Landfill #2 and #3 Groundwater Monitoring Plans, Southern Nuclear is submitting the attached semi-annual groundwater monitoring report which was prepared for Southern Nuclear by the Dextra Group. This report presents the analytical results for the semi-annual groundwater monitoring samples and annual Appendix II assessment monitoring samples taken in December 2003. As discussed in Sections 5 and 6 of the attached report, there was no statistically significant increase in the concentration of any detected parameter in the compliance well samples compared to the background well samples at Landfill #2. At Landfill #3 there was a statistically significant increase over background for barium, 1,1-dichloroethane and cis-1,2-dichloroethane in wells GWC-13/MW-13 and GWC-14/MW-14; chlorobenzene and 1A-dichlorobenzene in well GWC-14/MW-14 and trichlorofluoromethane in well GWC-13/MW-13. There was also a detection of mercury, an Appendix II parameter, in the sample from well GWC-14/MW-14. Statistical analyses of mercury concentrations were not performed since this was only the second analysis for this parameter. A copy of this letter and the attached report will be placed in the operating record within 14 days to serve as the notice to the operating record in accordance with EPD Solid Waste Rules 391-3-4. The next scheduled semi-annual sampling event is June 2004. In addition to the regular semi-annual monitoring for Appendix I parameters, all wells will continue to be analyzed for mercury. The next annual assessment monitoring for Appendix II parameters in wells GWC-13/MW-13, GWC-14/MW-14 and GWA-15/MW-15 will be conducted in December 2004.
EV-04-0432 Page 2 Georgia Environmental Protection Division Mr. Harold C. Gillespie If you have any questions, please contact Rachel Grimes at (205) 992-7025. Sincerely, ~ W. C. Carr Manager - Environmental Services WCC/RLG:ahl cc: Mr. Michael Kemp (w/o) Mr. Earl Hinkle (w/o) Mr. Kurt Batsel (w/o) Attachment
EV-04-0432 Page 3 Georgia Environmental Protection Division Mr. Harold C. Gillespie bc: P. D. Rushton (w/o) A. Harris (w/o) W. F. Kitchens (w/o) N. J. Stringfellow (w/o) M. E. Wilder (w/o) I. A. Kochery (w/o) B. D. Carter (w/o) S. Sundaram (w/o) C. M. Burke (w/o) (Return Receipt) SNC Document Management - Vogtle (Return Receipt)
GROUNDWATER MONITORING REPORT PLANT VOGTLE LANDFILLS #2 AND #3 SOLID WASTE PERMIT Nos. 017-006D(L)(I) AND 017-007D(L)(I) BURKE COUNTY, GEORGIA MARCH 2004 PREPARED FOR: Southern Nuclear Operating Company, Inc. 40 Inverness Center Parkway Birmingham, Alabama 35201 PREPARED By: Kurt R. Batsel, P.E. Georgia License Number 16594 The Dextra Group, LLC 4665 Lower Roswell Road, #154 Dextra Marietta, Georgia 30068
TABLE OF CONTENTS 1 - Introduction 1 2 - Monitoring Well Network 1 3 - Groundwater Flow Rate and Directional Data 2 3.1 Geology/Hydrogeology 3.2 Groundwater Elevations and Gradients 4 - Sampling Procedures and Parameter Analyses 3 4.1 Procedures and Field Measurements 4.2 Parameter Analyses 5 - Groundwater Quality Evaluation 4 5.1 Detected Parameters 5.2 Statistical Analyses 5.2.1 Landfill #2 5.2.2 Landfill #3 6 - Conclusions 6 In Order Following Page 7 Tables 1 - Groundwater Elevations and Monitoring Well Construction Details, Landfill #2 2 - Groundwater Elevations and Monitoring Well Construction Details, Landfill #3 3 - Groundwater Sampling Field Measurements, Landfill #2 4 - Groundwater Sampling Field Measurements, Landfill #3 5 - Constituents for Detection Monitoring 6 - Constituents for Assessment Monitoring 7 - Summary of Detected Parameters, Landfill #2 8 - Summary of Detected Parameters, Landfill #3 Figures 1 - Potentiometric Surface Map Landfill #2, December 17, 2003 2 - Groundwater Contour Elevation Map Landfill #3, December 16, 2003 Appendices A - Laboratory Analytical Reports B - Statistical Analyses
1 - Introduction This report presents the results of groundwater sampling conducted in December 2003 at two private solid waste landfills (Landfill #2 and Landfill #3) operated by Southern Nuclear Operating Company, Inc. (SNC) at Plant Vogtle in Waynesboro, Georgia. Groundwater monitoring was initiated in 2002 in accordance with the approved Groundwater Monitoring Plan for the landfills. The landfills are used for disposal of non-putrescible, non-liquid office and solid waste as well as construction/demolition debris such as asbestos insulation, wooden pallets, and concrete. The landfills are operated under Solid Waste Permit #s 017-006D(L)(I) and 017-007D(L)(I). The active trench at Landfill #2 is used only for asbestos disposal. Landfill #3, permitted in 1987, has been utilized for construction and demolition debris disposal since 1992. Sampling, analyses and data evaluation were conducted in accordance with the rules of the Georgia Department of Natural Resources Environmental Protection Division, Chapter 391-3-4, the September 1991 "Manual for Groundwater Monitoring" and the approved Groundwater Monitoring Plan for the landfills. The findings of the initial four sampling events, conducted from August 2002 through December 2002, and subsequent semi-annual sampling events were presented in reports previously submitted to the Department. This report presents the results of the December 2003 semi-annual detection monitoring sampling event and annual assessment monitoring. Subsequent reports will be prepared upon completion of semi-annual sampling events as scheduled in the Groundwater Monitoring Plan. 2 - Monitoring Well Network The groundwater monitoring well network consists of four permanent monitoring wells located along the north, east and south waste unit management boundaries of Landfill #2 (Figure 1), and seven permanent monitoring wells located along the perimeter of the waste management unit boundary of Landfill #3 (Figure 2). As shown in the figures, the wells are located outside of, but as close as practical to, the waste disposal areas. The wells are screened within the uppermost water-producing zones underlying the landfills, which occur from approximately 35 to 60 feet below land surface at Landfill #2 and from approximately 30 to 50 feet below land surface at Landfill #3. The four permanent groundwater monitoring wells at Landfill #2 were installed in September 2001 after advancing a total of eight deep soil borings around the landfill boundary. The upgradient well is GWA-2/MW-2 and the downgradient, or compliance, wells are GWC-3/MW-3 and GWC-ll/MW-
- 11. Well GWB-4/MW-4 is best characterized as a cross-gradient well, but is evaluated as a compliance well for this report. The well construction details are presented in Table 1.
The seven permanent groundwater monitoring wells at Landfill #3 were installed in September 2001 and in July 2002. The well construction details are presented in Table 2. Wells GWA-7/MW-7 and GWA-15/MW-15 are located at the south and southwest portions of the landfill boundary. Wells GWC-5/MW-5, GWC-13/MW-13 and GWC-14/MW-14 are located along the eastern portion of the landfill boundary, and wells GWB-6/MW-6 and GWB-16/MW-16 are located along the northern landfill boundary. As discussed in Section 3.2, well GWA-15/MW-15 is the designated background well, and the remaining wells are designated compliance wells. No surface water monitoring stations were present at the landfill at the time of the December 2003 sampling event. However, two new stormwater sedimentation ponds, constructed in accordance with the approved Design and Operational Plan, were completed at Landfill #3 after the December 2003
sampling event. It is anticipated that the surface water monitoring stations associated with the new sedimentation ponds will be sampled during the next semi-annual sampling event in June 2004. 3 - Groundwater Flow Rate and Directional Data 3.1 GeoloJ!l/HydrogeoloJ!l The geology of the Plant V ogtle site consists of sedimentary deposits within the Coastal Plain physiographic province of Georgia. These sediments consist of unconsolidated sands, silts and clays comprised of marine and non-marine fluvial deposits. Marls and limestone were also encountered at depth in deep borings completed at the landfills. A boring completed to approximately 126 feet below land surface at the northwest boundary of Landfill #2 appears to have been completed just into or immediately on top of the Utley Limestone member. The marls encountered during drilling were components of the Irwinton Sand member. Either all or parts of the Barnwell Group members (except the Utley Limestone member) were also encountered in the other borings conducted at the landfills. Underlying the Barnwell Group is the Lisbon Formation with its uppermost unit, the Blue Bluff Marl, located immediately under the Utley Limestone. This marl layer, approximately 70 feet thick, is a near-impermeable layer that effectively conftnes the Tertiary and Cretaceous aquifers, the two conftned aquifers beneath the Plant site. The occurrence of groundwater underlying the landfills appears in conftned, semi-confmed, unconftned, and perched hydrogeologic units. Groundwater is found primarily in sands, silty sands, clayey sands and marl limestone interfaces. The main difference between boring/well water production characteristics and aquifer conftning characteristics appears to be the thickness of the water-producing zone, the grain size of the sand component, the sand/clay ratio and the characteristics of the marl/limestone interface. Groundwater may also exist in an unconfmed water table aquifer in the Barnwell sands and limestone that overlie the marl. The water table aquifer at the site is on an interfluvial ridge, or a topographically high area in which the groundwater in the water table discharges along streams that surround the topographic high. The streams eventually discharge to the Savannah River. 3.2 Groundwater Elevations and Gradients During well installation, the occurrence of groundwater was determined by collecting continuous split spoon samples beginning approximately ftve feet above the location of expected groundwater-producing zones. At both landfills, groundwater was generally found in water producing zones less than one foot thick and is frequently under semi-confmed or conftned conditions. Upon completion of all drilling activities, measuring points were located on the tops of the well casings and surveyed relative to mean sea level (msl). During each sampling event, depth to water measurements were recorded in the wells from the surveyed elevations using an electronic water-level indicator. The water level measurements were then subtracted from the appropriate measuring point elevations to determine groundwater elevations in the wells. Hydraulic conductivity (K) in the wells was measured on September 26,2001. The values ranged from 5.634 x 10.4 em/sec in GWB-6/MW-6 to 3.064 x 10.2 cm/sec in GWA-2/MW-2. Landfill #2 Depth to water measurements and groundwater elevations for the wells at Landfill 2 are presented in Table 1. Based on groundwater elevations measured during the sampling events to date, groundwater 2
underneath Landfill 2 trends from a relatively higher elevation at the eastern portion of the landfill (GWA-2/MW-2) to relatively lower elevations in the west to southwest direction beneath the landfill (Figure 1). Well GWC-ll is not used to construct the potentiometric surface map because the uppermost water- bearing unit at this location appears to be within a different hydrologic zone based on the significantly lower groundwater elevation measured in well GWC-ll compared to wells GWA-2, GWC-3 and GWB-4. The hydraulic gradient (shown on Figure 1 for December 2003) was calculated using a three-point problem from potentiometric surface elevations in monitoring wells GWA-2/MW-2, GWC-3/MW-3 and GWB-4/MW-4. The hydraulic gradient has ranged from a minimum of 0.01 (October 2002) to a maximum of 0.08 Oune 2003). Landfill #3 Depth to water measurements and groundwater elevations for the wells at Landfill #3 are presented in Table 2. Based on the measured groundwater elevations to date, it appears that the groundwater elevation, or hydraulic 'head,' is greatest beneath the center area of the landfill, and decreases to the southeast, to the northeast and to the west-southwest beneath the landfill. This mounding effect is believed to be the result of natural inf1ltration in the sandy soils within the topographically high area in the center of the landfill. This topographically high area, which encompasses a broad area within the landfill, is a natural site feature that was present prior to any landfilling operations. As discussed previously, the water-bearing stratigraphy beneath Landfill #3 is composed of individual saturated sand units within a clayey/marl matrix. These units mayor may not be interconnected. As such, groundwater elevations in the monitoring wells may reflect head in multiple perched layers and may not represent groundwater 'flow' direction beneath the landfill. Figure 2 presents a map depicting the saturated head contours measured on December 16, 2003. Monitoring well GWA-15 /MW-15 is the well most representative of background water quality at the site because of the distance between the well and the current landfilled area, and the location of the area of relatively higher head located between the well and the current landfilled area on the eastern portion of the site. This well is therefore used as a background well to evaluate groundwater quality at the landf1ll. The hydraulic gradient was calculated using a three-point problem from groundwater elevations in the monitoring wells as follows for each main direction of head difference: Southeast: GWA-7/MW-7, GWC-13/MW-13, and GWC-14/MW-14; Northeast: GWB-6/MW-6, GWC-13/MW-13, and GWC-5/MW-5; and West-Southwest: GWA-7/MW-7, GWB-6/MW-6, and GWA-15/MW-15. The calculated hydraulic gradient is presented on the contour map (Figures 2). To date the steepest hydraulic gradient has been consistently to the north-northeast. The north-northeast trending gradient has ranged from a minimum of 0.08 (October and December 2002) to a maximum of 0.17 Oune 2003). 4 - Sampling Procedures and Parameter Analyses 4.1 Procedures and Field Measurements Prior to sample collection during each sampling event, depth to water measurements are recorded in each well from the surveyed elevations using an electronic water level indicator. The water level indicator is decontaminated using a potable water and Alconox wash and a potable water rinse 3
between use at each well. The water level measurements are then subtracted from the appropriate measuring point elevations to determine the groundwater elevations in the wells. Groundwater samples were collected from all monitoring wells after the wells were properly purged according to the EPA document entided "Low-Flow Purging & Sampling of Groundwater Monitoring Wells (Bulletin QAD023)". The wells were purged and sampled using QED SamplePro pumps equipped with Teflon bladders. Purge rates were matched to the recovery rates of the wells, verified by periodic depth to water measurements to determine draw-down during purging. Purging was conducted until at least three consecutive stable readings of pH, conductivity, and turbidity were recorded. Groundwater samples were then collected direcdy into pre-preserved sample containers supplied by the laboratory. Final measurements of pH, conductivity, and turbidity were performed to verify that these parameters remained stable during sampling. All field instruments were calibrated in the field daily prior to use and at the conclusion of each sampling event. The field measurements are provided in Tables 3and 4. After each sample was collected, the SamplePro pumps and airlines were decontaminated according to the following protocol:
- The pump and air line were placed on clean plastic;
- The pump was disassembled and the bladder was removed;
- The pump was sprayed with a potable water and Alconox solution, followed with a distilled water rinse until all soap residue was removed;
- A new pump bladder was then installed in the pump prior to reassembly; and
- The pump airline was placed in a clean plastic bag between use at each well.
4.2 Parameter Ana!yses In accordance with the approved Groundwater Monitoring Plan, the groundwater samples and field and laboratory quality assurance/quality control (QA/Qc) samples were analyzed for the Chapter 391-3-4 Appendix I list of parameters, which consists of total metals and volatile organic compounds (Table 5). The field QA/QC samples consisted of duplicate samples, trip blanks and equipment blanks. Metals analyses were conducted using EPA Methods 6010B/7841, and VOCs analyses were conducted using EPA Methods 6010B/8260B and 504.1 to provide sufficiendy sensitive quantitation limits for comparison with maximum contaminant limits. Advanced Chemistry Labs, Inc., Adanta, Georgia performed the laboratory analyses. The complete laboratory analytical reports, which include field and laboratory QA/QC results and chain-of-custody forms, are provided in Appendix A. In addition, assessment monitoring was conducted at Landfill #3 for the December 2003 sampling event based on the results of previous detection monitoring events in which statistically significant concentrations of barium and several organic parameters were indicated in the GWC-13 and GWC-14 well samples. Mercury was also detected previously in the GWC-13 and GWC-14 well samples. Assessment monitoring consisted of analyses of the Chapter 391-3-4 Appendix II list of parameters for the GWA-15, GWC-13 and GWC-14 well samples, and mercury for all well samples. 5 - Groundwater Quality Evaluation 5.1 Detected Parameters Tables 6 and 7 present a summary of all analyzed parameters that were detected above the laboratory method reporting limits. 4
Lmdfil/#2 At Landfill #2, barium was detected at 0.022 milligrams per liter (mg/l) in the GWC-ll sample. The maximum contaminant level (MCL) for barium is 2.0 mg/I. The organic parameter trichlorofluoromethane was also detected at 6 micrograms per liter (ug/l) in the GWB-4 sample. There is no MCL for this parameter. No parameters were detected in any of the field or laboratory QA/QC samples, and the laboratory QA/QC checks were within acceptable limits. LJndfill#3 At Landfill #3, barium was detected at concentrations below the MCL in the samples from wells GWC-5, GWC-13, and GWC-14 and zinc was also detected in background well GWA-7, and wells GWC-5 and GWC-14. As shown in Table 7, a number of additional metals were also detected in the samples from GWC-5 and GWC-14. All detected concentrations were below the MCLs except for Mercury at 0.01 mg/l (MCL of 0.002 mg/l) and cadmium at 0.011 mg/l (MCL of 0.005 mg/l), both of which occurred in well GWC-14. It should be noted that the turbidity measured in wells GWC-5 (79.7 ntu's) and GWA-7 (100 ntu's) was significantly higher than in previous sampling events, and higher than the recommended maximum of 10 ntu's. In addition, well GWC-13 required 6 gallons of purging to reduce the turbidity below 10 ntu's compared to 1 to 2.5 gallons purged in previous sampling events. In GWC-14, there was insufficient water to facilitate sample collection using the low-flow pump assembly. The well was sampled using a bailer after purging the previous evening. No indicator parameters were measured during sampling of GWC-14 due to the lack of water in the well during purging. The increased detections of metals and VOCs in the wells during this sampling event is likely due to the increased turbidity in the wells, an indication that particles from the aquifer were suspended in the samples during collection. The VOCs 1,1-dichloroethane, and cis-l,2-dichloroethene were detected in the GWC-13 and GWC-14 samples. Chlorobenzene and 1,4-dichlorobenzene were also detected in the GWC-14 sample. Trichlorofluoromethane was detected in samples from GWA-7, and GWC-13. Xylenes were also detected in the sample from GWC-14. All of the detected VOCs were reported at concentrations below the MCLs, where applicable. No parameters were detected in any of the field or laboratory QA/QC samples, and the laboratory QA/QC checks were within acceptable limits. The Department collected split samples from wells GWC-5, GWC-13, GWC-14 and GWA-15 for VOCs and metals analyses. 5.2 StatisticalAnalYses In accordance with the approved Groundwater Monitoring Plan, statistical analyses were conducted for each constituent detected in the compliance well samples for this sampling event. The analyses were conducted to help identify any significant increase in constituent concentrations in downgradient, or compliance, well samples over samples representative of background water quality. The analyses were conducted consistent with U.S. EPA recommended methods as detailed in the guidance document "Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities - Interim Final Guidelines" (1989) and the corresponding Addendum (1992). 5
The following methodology was used to evaluate the data:
- The distribution of the data was first evaluated for normality using the Shapiro-Wilkes Test as recommended in the 1992 EPA guidance. The test indicates that the concentrations of the detected parameters in all wells at both landfills do not follow normal distributions.
- For the well data sets at both landfills, the Kruskal-Wallis non-parametric analysis of variance method was used to compare the concentrations of individual parameters in each compliance well to the concentrations of these parameters in the background wells. This method is recommended by the 1992 EPA guidance for sample sets that do not follow a normal distribution or that have between 15% and 90% non-detects.
The detailed statistical analyses are provided in Appendix B and the results are summarized below. 5.2.1 Landfill #2 At Landfill #2, barium was detected in the sample from compliance well GWC-11/MW-11 and trichlorofluoromethane was detected in the GWB-4 well sample. The analyses indicate no statistically significant increase in the concentrations of these parameters in the compliance well samples as compared to the concentrations in the background well samples. 5.2.2 Landfill #3 Compared to background wells GWA-7/MW-7 and GWA-15/MW-15, the analyses indicate statistically significant higher concentrations of the following parameters:
- Barium in wells GWC-13/MW-13 and GWC-14/MW-14;
- 1,1-dichloroethane and cis-1,2-dichloroethene in wells GWC-13 and GWC-14;
- CWorobenzene and 1,4-dichlorobenzene in well GWC-14/MW-14; and
- Trichlorofluoromethane in well GWC-13/MW-13.
The Appendix II parameter, mercury, was also detected in the GWC-14/MW-14 well sample at 0.01 mg/I. The MCL for mercury is 0.002 mg/I. Statistical analyses of mercury concentrations were not performed since this parameter was only analyzed for the second time as a component of assessment monitoring for this event. 6 - Conclusions Since a statistically significant increase over background is indicated for several analyzed parameters in wells GWC-13/MW-13 and GWC-14/MW-14 at Landfill #3, SNC will place a notice in the operating record within 14 days of submittal of this report as required by Chapter 391-3-4. The notice will indicate which constituents have shown statistically significant higher concentrations than in the background wells. The notice will also include detection of the Appendix II parameter, mercury, in well sample GWC-14/MW-14. SNC will continue assessment monitoring per the requirements of paragraphs (20) through (33) of Chapter 391-3-4-.14. Based on detection of the Appendix II parameter mercury during this sampling event, future semi-annual sampling will include analysis for mercury in all wells. In addition, the December 2004 sampling event will include the complete Appendix II analyses in wells GWA-15/MW-15, GWC-13/MW-13 and GWC-14/MW-14 to satisfy the assessment monitoring program requirement for annual Appendix II analysis in wells showing statistically significant increases of 6
baseline monitoring parameters. After completion of 4 semi-annual sampling events for mercury, this parameter will be added to the routine statistical analysis that is currently performed for the Appendix I parameters. 7
TABLES Table 1 Southern Nuclear Operating Company Plant Vogtle Landfill #2 Groundwater Elevations and Monitoring Well Construction Details Total Boring Total Well Riser Groundwater Measuring Point Elevation Ground Surface Elevation Depth to Water Depth Depth Height Screened Interval Elevation WelllD Date (feet, msl) (feet, msl) (feet, topvc) (feet, bls) (feet, topvc) (feet) (feet, msl) (feet, msl) GWA-2/MW-2 9/26/2001 249.41 246.76 40.02 57 47.30 2.70 191.76 to 201.76 209.39 7/29/2002 41.69 207.72 9/9/2002 41.64 207.77 10/21/2002 42.72 206.69 12/3/2002 40.69 208.72 6/24/2003 37.58 211.83 12/17/2003 39.98 209.43 GWC-3/MW-3 9/26/2001 250.41 247.81 50.45 50 52.08 2.66 187.81 to 197.81 199.96 7/29/2002 50.05 200.36 9/9/2002 50.79 199.62 10/21/2002 49.30 201.11 12/3/2002 50.26 200.15 6/24/2003 51.58 198.83 12/1712003 47.89 202.52 GWB-4/MW-4 9/26/2001 242.40 239.83 39.84 54 48.80 2.60 183.83 to 193.83 202.56 7/29/2002 40.06 202.34 9/9/2002 41.27 201.13 10/21/2002 40.50 201.90 12/4/2002 39.65 202.75 6/24/2003 38.10 204.30 12/17/2003 39.53 202.87 GWC-11/MW-11 7/29/2002 227.53 225.09 64.80 65 68.95 2.44 158.58 to 168.58 162.73 9/9/2002 59.99 167.54 10/21/2002 65.27 162.26 12/4/2002 65.49 162.04 6/24/2003 59.72 167.81 12/17/2003 59.33 168.20 Notes: Ground surface measured at survey bolt set in concrete pad at base of protective casing. msl = mean sea level.
=
topvc measured from top of pvc riser. bls = below land surface. Page 1 of 1
Table 2 Southern Nuclear Operating Company Plant VogUe Landfill #3 Groundwater Elevations and Monitoring Well Construction Details Total Boring Total Well Riser Groundwater Measuring Point Elevation Ground Surface Elevation Depth to Water Depth Depth Height Soreened Interval Elevation Well 10 Olte (feet, mIl) (feet, mIl) (feet, topvc) (feet, bll) (feet, topvc) (feet) (feet, msl) (feet, mIl) GWC-5IMW-5 912612001 251.96 249.11 48.65 57 5741 2.89 185.11 to 195.11 203.31 712912002 50.21 201.75 91912002 5043 201.53 1012112002 49.26 202.70 12/312002 49.26 20270 612412003 44.60 207.36 1211612003 47.55 204.41 GWB-6IMW-6 912612001 278.87 276.45 4747 67 64.34 243 202.45 to 212.45 231.40 712912002 48.52 230.35 91912002 48.55 230.32 1012112002 49.21 229.66 121312002 48.86 230.Q1 612412003 46.92 231.95 12/1612003 46.30 232.57 GWA-7IMW-7 912612001 261.33 259.39 31.11 50 4022 1.90 211.11 t0221.11 23022 712912002 33.16 22817 91912002 33.25 228.08 1012112002 33.20 228.13 121312002 32.94 228.39 612412003 27.51 233.82 1211612003 30.59 230.74 GWC-131MW-13 712912002 273.08 270.99 40.92 50 50.14 209 222.94 to 232.94 232.16 91912002 41.00 232.08 1012112002 40.94 232.14 121312002 40.48 232.60 612412003 36.90 236.18 1211612003 39.17 233.91 GWC-14IMW-14 712912002 262.88 260.66 40.05 60 53.38 2.22 209.50 to 229.50 222.83 91912002 42.31 220.57 1012112002 42.79 220.09 1213/2002 42.35 220.53 612412003 44.29 218.59 12/1612003 51.52 211.36 GWA*15IMW-15 712912002 268.15 265.34 45.94 55 56.86 2.81 211.29 to 22129 222.21 91912002 46.05 222.10 1012112002 46.19 221.96 121312002 46.23 221.92 612412003 41.76 226.39 1211612003 43.29 224.86 GWB*161MW-16 712912002 256.95 254.57 DRY 65 67.39 2.38 189.56 to 209.56 DRY 91912002 DRY DRY 1012112002 DRY DRY 121312002 DRY DRY 612412003 DRY DRY 12/1612003 DRY DRY Notes: Ground surface measured at survey bolt set in concrete pad at base of protective casin9. msl = mean sea level; topvc = measured from top of pvc riser; bls = below land surface Page 1 of 1
Table 3 Southern Nuclear Operating Company Plant Vogtle Landfill #2 Groundwater Sampling Field Measurements Gallons 1 WelllD Date pH Conductivity Turbidity2 Purged Odor Color Notes GWA-2/MW-2 9/2612001 -- -- -- -- -- -- Well development only 7/29/2002 4.69 19 13.8 2.5 none none 9/912002 4.51 24.9 7.53 -- none none 10/21/2002 5.17 18 1.31 3.1 none none 12/312002 5.30 13 9.1 3.5 none none 6/24/2003 6.28 26.9 5.76 1.0 none none 12/17/2003 4.93 22.7 4.5 3.5 none none GWC-3/MW-3 9/2612001 -- -- -- -- -- -- Well development only 7/29/2002 4.08 27.9 22.2 1.3 none none 9/912002 6.03 36.5 4.08 0.5 none none 10/21/2002 - 176 35.6 <0.5 gal -- -- Too little water to purge and sample 12/312002 5.51 488 14.0 <0.5 gal -- -- Too little water to purge and sample 6/24/2003 -- -- <0.5 gal none none Too little water to purge and sample 12/17/2003 6.59 22.7 2.79 2.0 none none GWB-4/MW-4 9/2612001 4.73 36.0 15.5 35.0 -- -- Well development only 7/29/2002 4.21 269 3.63 2.0 none none 9/912002 4.35 34.8 0.55 2.0 none none 10/21/2002 5.01 25 6.44 3.0 none none 12/412002 5.51 98.7 2.60 4.0 none none 6/24/2003 5.33 36.0 5.27 2.0 none none 1211712003 4.62 3.55 0.00 1.5 none none GWC-11/MW-11 7/29/2002 5.30 67.5 36.6 4.0 none pale white 9/912002 6.24 97.0 6.51 2.0 none none 10/21/2002 5.05 75.0 8.05 1.8 none none 12/412002 5.72 57.1 8.10 2.0 none none 6/24/2003 6.93 70.0 2.70 2.5 none none 1211712003 7.04 69.2 11.2 4.5 none none Notes: _. = no data recorded 1 - Conductivity in units of umhoslsec 2 - Turbidity in units of NTU 1 of 1
Table 4 Southern Nuclear Operating Company Plant Vogtle Landfill #3 Groundwater Sampling Field Measurements Gallons Well 10 Date pH Conductivity' Turbidity' Puraed Odor Color Note. GWC-5/MW-5 912612001 5.11 47.5 28.6 6.0 none doudy Well development only 712912002 5.41 24.4 283 1.75 none none 91912002 813 365 4.11 20 none none 1012112002 - -- -- -- -- none none 121312002 5.94 117 78 20 612412003 5.18 29 3.5 6.0 none none 1211612003 6.27 210 79.7 3.0 none doudy Split with GAEPD GWB-6IMW-6 912612001 713 242 256 2.0 none -- Well development only 712912002 6.75 1,338 0.35 1.5 none none 91912002 4.13 198 6.43 1.5 none none 1012112002 6.72 573 0.44 2.5 none none 121312002 6.14 116 0.45 1.5 none none 612412003 7.09 155 9.1 1.5 none none 12/1712003 6.82 126 2.27 1.5 none none GWA-7IMW-7 912612001 -- -- doudy 300 -- - Well development only 712912002 6.97 251 8.33 2.5 none none 91912002 7.52 327 9.97 5.0 none none 1012112002 4.39 92 3.14 2.0 none none 121312002 6.51 188 7.3 2.5 none none 612412003 7.02 163 101.3 4.0 none dark brown Turbidity >100 ntu for 2 hours. 12/1612003 5.73 627 100 4.0 none mod. brown Turbidity 85-100 ntu for 1 hour. GWC-13/MW-13 712912002 6.52 421 0.66 -- 9/912002 5.96 77.5 6.40 1.0 none none 10121/2002 6.19 73.4 3.09 2.5 none none 121312002 6.54 481 100 2.5 none none 612412003 5.95 271 2.02 2.5 none none 12/1612003 5.65 294 0.75 6.0 none none Split with GAEPD GWC-14IMW-14 712912002 6.49 448 1.15 -- none none 9/912002 5.57 717 5.19 - none none 1012112002 6.00 674 4.65 3.2 none none 121312002 5.54 547 2.7 4.5 none none 612412003 5.97 197 3.61 2.5 none none 12/1712003 -- -- - -- -- -- Split with GAEPD-VOCs & metals GWA-15IMW-15 712912002 5.70 95.8 112 4.0 none none 9/912002 5.92 118 8.53 2.5 none none 1012112002 5.19 81 1.88 4.5 none none 121312002 7.58 78.2 36 2.5 none none 612412003 7.44 48.0 5.38 2.5 none none 12/1712003 6.93 39.4 4.55 6.5 none none Split with GAEPD GWB-16IMW-16 7129/2002 -- -- -- -- -- -- Well Dry 919/2002 -- -- -- -- - - Well Dry 1012112002 -- -- --_. -- -- - Well Dry 121312002 - -- -- -- Well Dry 6124/2003 -- -- -- -- --
- Well Dry 12/1612003 -- -- -- - Well Dry Notes: -- = no data recorded; 1 - Conductivity in units of umhoslsec; 2 - TUrbidity in units of NTU.
1 of 1
Table 5 Southern Nuclear Operating Company Plant Vogde Landfills #2 and #3 Appendix I to Part 40 CFR Part 258: Constituents for Detection Monitoring (1) Common Name (2) EPA Method Inorganic Constituents: (1) Antimony . 6010B/7041 (2) Arsenic . 6010B/7061 (3) Barium . 6010B/7091 (4) Beryllium . 6010B/7091 (5) Cadmium . 6010B/7131 (6) Chromium . 6010B/7191 (7) Cobalt . 6010B/7201 (8) Copper . 6010B/7211 (9) Lead . 6010B/7421 (10) Nickel . 6010B/7520 (11) Selenium . 6010B/7741 (12) Silver . 6010B/7761 (13) Thallium . 6010B/7841 (14) Vanadium . 6010B/7911 (15) Zinc . 6DI0B/7951 Organic Constituents: 8260 (16) Acetone . (17) Acrylonitrile . (18) Benzene . (19) Bromochloromethane . (20) Bromodichloromethane . (21) Bromoform; Tribromomethane . (22) Carbon disulfide . (23) Carbon tetrachloride . (24) Chlorobenzene . (25) Chloroethane; Ethyl chloride . (26) Chloroform; Trichloromethane . (27) Dibromochloromethane; Chlorodibromomethane . (28) 1,2-Dibromo-3-chloropropane; DBCP . (29) 1,2-Dibromoethane; Ethylene dibromide; EDB . (30) o-Dichlorobenzene; 1,2-Dichlorobenzene . (31) p-Dichlorobenzene; 1,4-Dichlorobenzene . (32) trans-l,4-Dichloro-2-butene . (33) 1,I-Dichloroethane; Ethylidene chloride . (34) 1,2-Dichloroethane; Ethylene dichloride . (35) 1,I-Dichloroethylene; 1,I-Dichloroethene; Vinylidene chloride . (36) cis-l,2-Dichloroethylene; cis-l,2-Dichloroethene . (37) trans-l,2-Dichloroethylene; trans-l,2-Dichloroethene (38) 1,2-Dichloropropane; Propylene dichloride . (39) cis-l,3-Dichloropropene . (40) trans-l,3-Dichloropropene . (41) Ethylbenzene . (42) 2-Hexanone; Methyl butyl ketone . (43) Methyl bromide; Bromomethane . (44) Methyl chloride; Chloromethane . Page 1 of 2
Table 5 (continued) Southern Nuclear Operating Company, Inc. Plant Vogtle Landfills #2 and #3 Appendix I to Part 40 CFR Part 258: Constituents for Detection Monitoring (1) Common Name (2) EPA Method (45) Methylene bromide; Dibromomethane . 8260 (46) Methylene chloride; Dichloromethane . (47) Methyl ethyl ketone; MEK; 2-Butanone . (48) Methyl iodide; Iodomethane . (49) 4-Methyl-2-pentanone; Methyl isobutyl ketone . (50) Styrene . (51) 1,1,1, 2-Tetrachloroethane . (52) 1,1,2,2-Tetrachloroethane . (53) Tetrachloroethylene; Tetrachloroethene; Perchloroethylene . (54) Toluene . (55) 1, 1, I-Trichloroethane; Methylchloroform . (56) 1,1, 2-Trichloroethane . (57) Trichloroethylene; Trichloroethene . (58) Trichlorofluoromethane; CFC-ll . (59) 1,2, 3-Trichloropropane . (60) Vinyl acetate . (61) Vinyl chloride . (62) Xylenes . (1) This list contains 47 volatile organics for which possible analytical procedures provided in EPA Report SW-846 "Test Methods for Evaluating Solid Waste, " third edition, November 1986, as revised December 1987,includes Method 8260; and 15 metals for which SW-846 provides either Method 6010 or a method from the 7000 series of methods. (2) Common names are those widely used in government regulations, scientific publications, and commerce; synonyms exist for many chemicals. Page 2 of 2
1.. _.: 6 I Southern Nuclear Operating Company Plant Vogtle Landfills # 2 and #3 Appendix II to Part 40 CFR Part 258: Constituents for Assessment Monitoring Suggested Common Name \2\ CAS RN \3\ Chemical abstracts service methods PQL (p index name \4\ \5\ giL) \6\ Acenaphthene . 83-32-9 Acenaphthylene, 1,2-dihydro- .. 8100 200 8270 10 Acenaphthylene . 208-96-8 Acenaphthylene . 8100 200 8270 10 Acetone . 67-64-1 2-Propanone . 8260 100 Acetonitrile; Methyl cyanide . 75-05-8 Acetonitrile . 8015 100 Acetophenone . 98-86-2 Ethanone, 1-phenyl- . 8270 10 2-Acetylaminofluorene; 2-AAF . 53-96-3 Acetamide, N-9H-fluoren-2-yl-. 8270 20 Acrolein . 107-02-8 2-Propenal . 8030 5 8260 100 Acrylonitrile . 107-13-1 2-Propenenitrile . 8030 5 8260 200 Aldrin . 309-00-2 1, 4:5, 8-0imethanonaphthalene, 8080 0.05 1,2,3,4,10,10-hexachloro- 8270 10 1,4,4a,5,8,8a-hexahydro-(lcx,4cx,4af3,5 cx,8cx,8af3)- Allyl chloride . 107-05-1 I-Propene, 3-chloro- .. '" ..... 8010 5 8260 10 4-Aminobiphenyl . 92-67-1 [l,1\1\-Biphenyl]-4-amine . 8270 20 Anthracene . 120-12-7 Anthracene . 8100 200 8270 10 Antimony . (Total) Antimony . 6010 300 7040 2000 7041 30 Arsenic . (Total) Arsenic . 6010 500 7060 10 7061 20 Barium . (Total) Barium . 6010 20 7080 1000 Benzene . 71-43-2 Benzene . 8020 2 8021 0.1 8260 5 Benzo[a]anthracene; Benzanthracene .... 56-55-3 Benz[a]anthracene . 8100 200 8270 10 Page 1 of 16
T .. _~~ 6 Southern Nuclear Operating Company Plant Vogtle Landfills # 2 and #3 Appendix II to Part 40 CFR Part 258: Constituents for Assessment Monitoring Suggested Corrunon Name \2\ CAS RN \3\ Chemical abstracts service methods PQL (]J index name \4\ \5\ giL) \6\ Benzo[b]fluoranthene . 205-99-2 Benz [e]acephenanthrylene . 8100 200 8270 10 Benzo[k]fluoranthene . 207-08-9 Benzo[k]fluoranthene . 8100 200 8270 10 Benzo[ghi]perylene . 191-24-2 Benzo[ghi]perylene . 8100 200 8270 10 Ben zo [a] pyrene . 50-32-8 Benzo[a]pyrene . 8100 200 8270 10 Benzyl alcohol . 100-51-6 Benzenemethanol . 8270 20 Beryllium . (Total) Beryllium . 6010 3 7090 50 7091 2 alpha-BHC . 319-84-6 Cyclohexane, 1,2,3,4,5,6- 8080 0.05 hexachloro-, 8270 10 (lcx,2cx,3f),4& alpha;,5f),6f))-. beta-BHC . 319-85-7 Cyc1ohexane, 1,2,3,4,5,6- 8080 0.05 hexachloro-, 8270 20 (lcx,2f),3cx,4& beta;,5cx,6f))-. delta-BHC . 319-86-8 Cyclohexane, 1,2,3,4,5,6- 8080 0.1 hexachloro-, 8270 20 (lcx,2cx,3cx,4 f),5cx,6f))-. garruna-BHC; Lindane '" . 58-89-9 Cyclohexane, 1,2,3,4,5,6- 8080 0.05 hexachloro-, 8270 20 (lcx,2cx,3f),4& alpha;,5cx,6f))-. Bis(2-ch10roethoxy)methane . 111-91-1 Ethane, 1,1\1\- 8HO 5 [methylenebis(oxy)]bis[2- 8270 10 chloro-. Bis(2-chloroethyl) ether; 111-44-4 Ethane, 1,1\1\-oxybis[2-chloro- 8HO 3 Dichloroethyl ether. 8270 10 Page 2 of 16
TaUle 6 Southern Nuclear Operating Company Plant Vogtle Landfills # 2 and #3 Appendix II to Part 40 CFR Part 258: Constituents for Assessment Monitoring Suggested Common Name \2\ CAS RN \3\ Chemical abstracts service methods PQL (j.l index name \4\ \5\ giL) \6\ Bis-(2-chloro-1-methy1ethyl) ether; 108-60-1 Propane, 2,2\1\-oxybis[1- 8110 10 2,2\1\-Dichlorodiisopropyl ether; chloro-. 8270 10 DCIP, See note 7 Bis(2-ethylhexyl) phthalate . 117-81-7 1,2-Benzenedicarboxylic acid, 8060 20 bis(2-ethylhexyl) ester. Bromochloromethane; Chlorobromomethane 74-97-5 Methane, bromochloro- . 8021 0.1 8260 5 Bromodichloromethane; 75-27-4 Methane, bromodichloro- . 8010 1 Dibromochloromethane. 8021 0.2 8260 5 Bromoform; Tribromomethane . 75-25-2 Methane, tribromo- . 8010 2 8021 15 8260 5 4-Bromopheny1 phenyl ether . 101-55-3 Benzene, 1-bromo-4-phenoxy- ... 8110 25 8270 10 Butyl benzyl phthalate; Benzyl butyl 85-68-7 1,2-Benzenedicarboxylic acid, 8060 5 phthalate. butyl pheny1methyl ester. 8270 10 Cadmium . (Total) Cadmium . 6010 40 7130 50 7131 1 Carbon disulfide . 75-15-0 Carbon disulfide . 8260 100 Carbon tetrachloride . 56-23-5 Methane, tetrachloro- . 8010 1 8021 0.1 8260 10 Chlordane . See Note 8 4,7-Methano-1H-indene, 8080 0.1 1,2,4,5,6,7,8,8-octachloro- 8270 50 2,3,3a,4,7,7a-hexahydro-. p-Chloroaniline . 106-47-8 Benzenamine, 4-ch1oro- . 8270 20 Chlorobenzene . 108-90-7 Benzene, chloro- '" 8010 2 8020 2 8021 0.1 8260 5 Chlorobenzilate . 510-15-6 Benzeneacetic acid, 4-chloro- 8270 10 a-(4-ch1orophenyl)- a-hydroxy-, ethyl ester. Page 3 of 16
l~~.e 6 Southern Nuclear Operating Company Plant Vogde Landfills # 2 and #3 Appendix II to Part 40 CFR Part 258: Constituents for Assessment Monitoring Suggested Corrunon Name \2\ CAS RN \3\ Chemical abstracts service methods PQL (].1 index name \4\ \5\ giL) \6\ p-Chloro-m-cresol; 4-Chloro 59-50-7 Phenol, 4-chloro-3-methyl- .... 8040 5 methylphenol. 8270 20 Chloroethane; Ethyl chloride . 75-00-3 Ethane, chloro- . . . . . . . . . . . . . . . 8010 5 8021 1 8260 10 Chloroform; Trichloromethane ... '" .... 67-66-3 Methane, trichloro- . . . . . . . . . . . 8010 0.5 8021 0.2 8260 5 2-Chloronaphthalene '" . 91-58-7 Naphthalene, 2-chloro- ........ 8120 10 8270 10 2-Chlorophenol . 95-57-8 Phenol, 2-chloro- . . . . . . . . . . . . . 8040 5 8270 10 4-Chlorophenyl phenyl ether . 7005-72-3 Benzene, 1-chloro-4-phenoxy- .. 8110 40 8270 10 Chloroprene . 126-99-8 1,3-Butadiene, 2-chloro- ...... 8010 50 8260 20 Chromium . (Total) Chromium . . . . . . . . . . . . . . . . . . . . . . 6010 70 7190 500 7191 10 Chrysene . 218-01-9 Chrysene . . . . . . . . . . . . . . . . . . . . . . 8100 200 8270 10 Cobal t . (Total) Cobalt . . . . . . . . . . . . . . . . . . . . . . . . 6010 70 7200 500 7201 10 Copper . (Total) Copper . . . . . . . . . . . . . . . . . . . . . . . . 6010 60 7210 200 7211 10 m-Cresol; 3-methylphenol . 108-39-4 Phenol, 3-methyl- ........... " 8270 10 o-Cresol; 2-methylphenol . 95-48-7 Phenol, 2-methyl- ............. 8270 10 p-Cresol; 4-methylphenol . 106-44-5 Phenol, 4-methyl- .......... '" 8270 10 Cyanide . 57-12-5 Cyanide . . . . . . . . . . . . . . . . . . . . . . . 9010 200 2,4-D; 2,4-Dichlorophenoxyacetic acid. 94-75-7 Acetic acid, (2,4- 8150 10 dichlorophenoxy)-. Page 4 of 16
Tavie 6 Southern Nuclear Operating Company Plant Vogde Landfills # 2 and #3 Appendix II to Part 40 CFR Part 258: Constituents for Assessment Monitoring Suggested Common Name \2\ CAS RN \3\ Chemical abstracts service methods PQL (fl index name \4\ \5\ giL) \6\ 4,4\1\-000 . 72-54-8 Benzene 1,1\1\-(2,2- 8080 0.1 dichloroethylidene)bis[4- 8270 10 chloro-. 4,4\1\-DDE . 72-55-9 Benzene, 1,1\1\- 8080 0.05 (dichIoroethyenylidene)bis[4- 8270 10 chloro-. 4,4\1\-DOT . 50-29-3 Benzene, 1,1\1\-(2,2,2- 8080 0.1 trichIoroethylidene)bis[4- 8270 10 chloro-. Oia11ate . 2303-16-4 Carbamothioic acid, bis(l- 8270 10 methyIethyI)-,S-(2,3-dichIoro-2-propenyl) ester. Dibenz[a,h]anthracene . 53-70-3 Dibenz[a,h]anthracene '" 8100 200 8270 10 Dibenzofuran . 132-64-9 Dibenzofuran . 8270 10 Oibromoch1oromethane; 124-48-1 Methane, dibromochloro- . 8010 1 Ch1orodibromomethane. 8021 0.3 8260 5 1,2-Dibromo-3-ch1oropropane; DBCP ..... 96-12-8 Propane, 1,2-dibrome-3-chloro- 8011 0.1 8021 30 8260 25 1,2-Dibromoethane; Ethylene 106-93-4 Ethane, 1,2-dibromo- . 8011 0.1 dribromide; EOB. 8021 10 8260 5 Oi-n-butyl phthalate . 84-74-2 1,2-Benzenedicarboxylic acid, 8060 5 dibutyl ester. 8270 10 o-Dich1orobenzene; 1,2-0ichlorobenzene 95-50-1 Benzene, 1,2-dichloro- . 8010 2 8020 5 8021 0.5 8120 10 8260 5 8270 10 m-Dichlorobenzene; 1,3-Dichlorobenzene 541-73-1 Benzene, 1,3-Dichloro- . 8010 5 8020 5 8021 0.2 Page 5 of 16
T~h,.e 6 Southern Nuclear Operating Company Plant Vogde Landfills # 2 and #3 Appendix II to Part 40 CFR Part 258: Constituents for Assessment Monitoring Suggested Common Name \2\ CAS RN \3\ Chemical abstracts service methods PQL (p index name \4\ \5\ giL) \6\ 8120 10 8260 5 8270 10 p-Oichlorobenzene; 1,4-0ichlorobenzene 106-46-7 Benzene, 1,4-dichloro- . 8010 2 8020 5 8021 0.1 8120 15 8260 5 8270 10 3,3\1\-Oichlorobenzidine . 91-94-1 [l,1\1\-BiphenylJ-4,4\1\- 8270 20 diamine, 3,3\1\-dichloro-. trans-1,4-0ichloro-2-butene . 110-57-6 2-Butene, 1,4-dichloro-, (E)-. 8260 100 Oichlorodifluoromethane; CFC 12; . 75-71-8 Methane, dichlorodifluoro- .... 8021 0.5 8260 5 1,1-Dichloroethane; Ethyldidene 75-34-3 Ethane, 1,1-dichloro- . 8010 1 chloride. 8021 0.5 8260 5 1,2-Dichloroethane; Ethylene Ethane, 1,1-dichloro- . 8010 0.5 dichloride. 8021 0.3 8260 5 1,1-Dichloroethylene; 1,1- 75-35-4 Ethene, 1,1-dichloro- . 8010 1 Oichloroethene; Vinylidene chloride. 8021 0.5 8260 5 cis-1,2-Dichloroethylene; cis-1,2- 156-59-2 Ethene, 1,2-dichloro-, (Z)- ... 8021 0.2 Oichloroethene. 8260 5 trans-1,2-0ichloroethylene trans-1,2- 156-60-5 Ethene, 1, 2-dichloro-, (E) - ... 8010 1 Oichloroethene. 8021 0.5 8260 5 2,4-Dichlorophenol . 120-83-2 Phenol, 2, 4 -dichloro- . 8040 5 8270 10 2,6-Dichlorophenol . 87-65-0 Phenol, 2,6-dichloro- . 8270 10 1,2-0ichloropropane; Propylene 78-87-5 Propane, 1,2-dichloro- . 8010 0.5 dichloride. 8021 0.05 8260 5 Page 60f16
1 .. ~e 6 Southern Nuclear Operating Company Plant Vogtle Landfills # 2 and #3 Appendix II to Part 40 CFR Part 258: Constituents for Assessment Monitoring Suggested Conunon Name \2\ CAS RN \3\ Chemical abstracts service methods PQL (ll index name \4\ \5\ giL) \6\ 1,3-Dichloropropane; Trimethylene 142-28-9 Propane, l,3-dichloro- . 8021 0.3 dichloride. 8260 5 2,2-Dichloropropane; Isopropylidene 594-20-7 Propane, 2,2-dichloro- . 8021 0.5 chloride. 8260 15 1,1-Dichloropropene . 563-58-6 I-Propene, 1,1-dichloro- . 8021 0.2 8260 5 cis-1,3-Dichloropropene . 10061-01-5 I-Propene, 1,3-dichloro-, (2)- 8010 20 8260 10 trans-1,3-Dichloropropene . 10061-02-6 I-Propene, l,3-dichloro-, (E)- 8010 5 8260 10 Dieldrin . 60-57-1 2,7:3,6-Dimethanonaphth[2,3- 8080 0.05 b]oxirene, 3,4,5,6,9,9-hexa, 8270 10 chloro-1a,2,2a,3,6,6a,7,7a-octahydro-, (lacx,2~,2acx, 3~,6~,6acx,7
~,7acx)-.
Diethyl phthalate . 84-66-2 l,2-Benzenedicarboxylic acid, 8060 5 diethyl ester. 8270 10 O,O-Diethyl 0-2-pyrazinyl 297-97-2 Phosphorothioic acid, 0,0- 8141 5 phosphorothioate; Thionazin. diethyl O-pyrazinyl ester. 8270 20 Oimethoate . 60-51-5 Phosphorodithioic acid, 0,0- 8141 3 dimethyl S-[2-(methylamino) 8270 20 oxoethyl] ester. p-(Dimethylamino)azobenzene . 60-11-7 Benzenamine, N,N-dimethyl 8270 10 (phenylazo)-. 7, 12-0imethylbenz[a]anthracene . 57-97-6 Benz[a]anthracene, 7,12- 8270 10 dimethyl-. 3,3\1\-Oimethylbenzidine . 119-93-7 [l,l\1\-Biphenyl]-4,4\1\- 8270 10 diamine, 3,3\1\-dimethyl-. 2,4-0imethylphenol; m-Xylenol . 105-67-9 Phenol, 2,4-dimethyl- . 8040 5 8270 10 Dimethyl phthalate . 131-11-3 1,2-Benzenedicarboxylic acid, 8060 5 dimethyl ester. 8270 10 m-Dini trobenzene . 99-65-0 Benzene, 1,3-dinitro- . 8270 20 Page 7 of 16
Taole 6 Southern Nuclear Operating Company Plant Vogde Landfills # 2 and #3 Appendix II to Part 40 CFR Part 258: Constituents for Assessment Monitoring Suggested Common Name \2\ CAS RN \3\ Chemical abstracts service methods PQL (ll index name \4\ \5\ giL) \6\ 4,6-Dinitro-o-cresol 4,6-Dinitro 534-52-1 Phenol, 2-methyl-4,6-dinitro .. 8040 150 methylphenol. 8270 50 2,4-Dinitrophenol; . 51-28-5 Phenol, 2,4-dinitro- . . . . . . . . . . 8040 150 8270 50 2,4-Dinitrotoluene . 121-14-2 Benzene, 1-methyl-2,4-dinitro- 8090 0.2 8270 10 2,6-Dinitrotoluene . 606-20-2 Benzene, 2-methyl-1,3-dinitro- 8090 0.1 8270 10 Dinoseb; DNBP; 2-sec-Butyl-4,6- 88-85-7 Phenol, 2-(1-methylpropyl)-4,6- 8150 1 dinitrophenol. dinitro-. 8270 20 Di-n-octyl phthalate . 117-84-0 1,2-Benzenedicarboxylic acid, 8060 30 dioctyl ester. 8270 10 Diphenylamine . 122-39-4 Benzenamine, N-phenyl- . 8270 10 Disulfoton . 298-04-4 Phosphorodithioic acid, 0,0- 8140 2 diethyl S-[2- 8141 0.5 (ethylthio) ethyl] ester. 8270 10 Endosulfan I . 959-98-8 6,9-Methano-2,4,3- 8080 0.1 benzodioxathiepin, 8270 20 6,7,8,9,10,10-hexa- chloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide, Endosulfan II . 33213-65-9 6,9-Methano-2,4,3- 8080 0.05 benzodioxathiepin, 8270 20 6,7,8,9,10,10-hexa- chloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide, (3o:,5ao:,613,9 13,9ao:)-. Endosulfan sulfate . 1031-07-8 6,9-Methano-2,4,3- 8080 0.5 benzodioxathiepin, 8270 10 6,7,8,9,10,10-hexa- chi oro-1,5,5a,6,9,9a-hexahydro-,3 dioxide. Page 8 of 16
TaOle6 Southern Nuclear Operating Company Plant Vogde Landfills # 2 and #3 Appendix II to Part 40 CFR Part 258: Constituents for Assessment Monitoring Suggested Common Name \2\ CAS RN \3\ Chemical abstracts service methods PQL (p index name \4\ \5\ giL) \6\ Endrin . 72-20-8 2,7:3,6-0imethanonaphth[2,3- 8080 0.1 b]oxirene, 3,4,5,6,9,9- 8270 20 hexachloro-la,2,2a,3,6,6a,7,7a-octahydro-, (laex, 2f3,2af3,3ex,6 ex,6af3,7f3,7a ex)-. Endrin aldehyde . 7421-93-4 1,2,4- 8080 0.2 Methenocyclopenta[cd]pentalen 8270 10 e-5-carboxaldehyde, 2,2a,3,3,4,7-hexachlorodecahydro-, (lex,2f3,2af3, 4f3,4a(3,5f3,6a (3,6bf3,7R*)-. Ethylbenzene . 100-41-4 Benzene, ethyl-. '" . 8020 2 8221 0.05 8260 5 Ethyl methacrylate . 97-63-2 2-Propenoic acid, 2-methyl-, 8015 5 ethyl ester. 8260 10 8270 10 Ethyl methanesulfonate . 62-50-0 Methanesulfonic acid, ethyl 8270 20 ester. Famphur . 52-85-7 Phosphorothioic acid, 0-[4- 8270 20 [(dimethylamino)sulfonyl]phen yl] O,O-dimethyl ester. Fluoranthene . 206-44-0 Fluoranthene . 8100 200 8270 10 Fluorene . 86-73-7 9H-Fluorene . 8100 200 8270 10 Heptachlor . 76-44-8 4,7-Methano-1H-indene, 8080 0.05 1,4,5,6,7,8,8-heptachloro- 8270 10 3a,4,7,7a-tetrahydro-. Page 9 of 16
Taule 6 Southern Nuclear Operating Company Plant Vogde Landfills # 2 and #3 Appendix II to Part 40 CFR Part 258: Constituents for Assessment Monitoring Suggested Corrunon Name \2\ CAS RN \3\ Chemical abstracts service methods PQL (]l index name \4\ \5\ giL) \6\ Heptachlor epoxide . 1024-57-3 2,5-Methano-2H-indeno[1,2- 8080 1 b]oxirene, 2,3,4,5,6,7,7- 8270 10 heptachloro-1a,lb,5,5a,6,6a-hexahydro-, (lao:, 1br5, 20:, 50:, 5ar5, 6r5, 6ao:). Hexachlorobenzene . 118-74-1 Benzene, hexachloro- . 8120 0.5 8270 10 Hexachlorobutadiene . 87-68-3 1,3-Butadiene, 1,1,2,3,4,4- 8021 0.5 hexachloro-. 8120 5 8260 10 8270 10 Hexachlorocyclopentadiene . 77-47-4 1,3-Cyclopentadiene, 8120 5 1,2,3,4,5,5-hexachloro-. 8270 10 Hexachloroethane . 67-72-1 Ethane, hexachloro- . 8120 0.5 8260 10 8270 10 Hexachloropropene . 1888-71-7 I-Propene, 1,1,2,3,3,3- 8270 10 hexachloro-. 2-Hexanone; Methyl butyl ketone . 591-78-6 2-Hexanone . 8260 50 Indeno(1,2,3-cd)pyrene . 193-39-5 Indeno(1,2,3-cd)pyrene . 8100 200 8270 10 Isobutyl alcohol . 78-83-1 I-Propanol, 2-methyl- . 8015 50 8240 100 Isodrin . 465-73-6 1,4,5,8- 8270 20 Dimethanonaphthalene,1,2,3,4, 8260 10 10,10- hexachloro-1,4,4a,5,8,8a hexahydro-(10:,40:,4ar5,5 r5,8r5,8ar5)-. Isophorone . 78-59-1 2-Cyclohexen-1-one, 3,5,5- 8090 60 trimethyl-. 8270 10 Isosafrole . 120-58-1 1,3-Benzodioxole, 5-(1- 8270 10 propenyl)-. Page 10 ofl6
Tab... 6 Southern Nuclear Operating Company Plant Vogde Landfills # 2 and #3 Appendix II to Part 40 CFR Part 258: Constituents for Assessment Monitoring Suggested Cornmon Name \2\ CAS RN \3\ Chemical abstracts service methods PQL (]J index name \4\ \5\ giL) \6\ Kepone . 143-50-0 1,3,4-Metheno-2H- 8270 20 cyclobuta[cd]pentalen-2-one, 1, la, 3, 3a, 4, 5, 5, 5a, 5b, 6-decachlorooctahydro-. Lead . (Total) Lead . 6010 400 7420 1000 7421 10 Mercury . (Total) Mercury . 7470 2 Methacryloni trile . 126-98-7 2-Propenenitrile, 2-methyl- . 8015 5 8260 100 Methapyrilene . 91-80-5 1,2-Ethanediamine, N.N- 8270 100 dimethyl-N\1\-2-pyridinyl-N11 2-thienylmethyl)-. Methoxychlor . 72-43-5 Benzene,l,l\l\- 8080 2 (2,2,2,trichloroethy1idene)bi 8270 10 s[4-methoxy-. Methyl bromide; Bromomethane . 74-83-9 Methane, bromo- . 8010 20 8021 10 Methyl chloride; Chloromethane . 74-87-3 Methane, chloro- . 8010 1 8021 0.3 3-Methylcholanthrene . 56-49-5 Benz [j]aceanthrylene, 1,2- 8270 10 dihydro-3-methy1-. Methyl ethyl ketone; MEK; 2-Butanone .. 78-93-3 2-Butanone . 8015 10 8260 100 Methyl iodide; Iodomethane . 74-88-4 Methane, iodo- . 8010 40 8260 10 Methyl methacrylate . 80-62-6 2-Propenoic acid, 2-methyl-, 8015 2 methyl ester. 8260 30 Methyl methanesulfonate . 66-27-3 Methanesulfonic acid, methyl 8270 10 ester. 2-Methylnaphthalene . 91-57-6 Naphthalene, 2-methyl- ..... '" 8270 10 Methyl parathion; Parathion methyl . 298-00-0 Phosphorothioic acid, 0,0- 8140 0.5 dimethyl. 8141 1 8270 10 4-Methyl-2-pentanone; Methyl isobutyl 108-10-1 2-Pentanone, 4-methyl- . 8015 5 Page 11 ofl6
i T~..,.e 6 Southern Nuclear Operating Company Plant Vogtle Landfills # 2 and #3 Appendix II to Part 40 CFR Part 258: Constituents for Assessment Monitoring Suggested Common Name \2\ CAS RN \3\ Chemical abstracts service methods PQL (].l index name \4\ \5\ giL) \6\ ketone. 8260 100 Methylene bromide; Dibromomethane ..... 74-95-3 Methane, dibromo- . 8010 15 8021 20 8260 10 Methylene chloride; Dichloromethane ... 75-09-2 Methane, dichloro- . 8010 5 8021 0.2 8260 10 Naphthalene . 91-20-3 Naphthalene . 8021 0.5 8100 200 8260 5 8270 10 1,4-Naphthoquinone . 130-15-4 1,4-Naphthalenedione . 8270 10 1-Naphthy1amine . 134-32-7 1-Naphthalenamine . 8270 10 2-Naphthylamine . 91-59-8 2-Naphthalenamine . 8270 10 Nickel . (Total) Nickel . 6010 150 7520 400 o-Nitroaniline; 2-Nitroaniline . 88-74-4 Benzenamine, 2-nitro- . 8270 50 m-Nitroaniline; 3-Nitroanile . 99-09-2 Benzenamine, 3-nitro- . 8270 50 p-Nitroaniline; 4-Nitroaniline . 100-01-6 Benzenamine, 4-nitro . 8270 20 Ni trobenzene . 98-95-3 Benzene, nitro- . 8090 40 8270 10 o-Nitrophenol; 2-Nitrophenol . 88-75-5 Phenol, 2-nitro- . 8040 5 8270 10 p-Nitrophenol; 4-Nitrophenol . 100-02-7 Phenol, 4-nitro- . 8040 10 8270 50 N-Nitrosodi-n-butylamine . 924-16-3 1-Butanamine, N-butyl-N- 8270 10 nitroso-. N-Ni trosodiethy1amine . 55-18-5 Ethanamine, N-ethyl-N-nitroso- 8270 20 N-Nitrosodimethylamine . 62-75-9 Methanamine, N-methyl-N- 8070 2 nitroso-. N-Nitrosodipheny1amine . 86-30-6 Benzenamine, N-nitroso-N- 8070 5 phenyl-. N-Nitrosodipropylamine; N-Nitroso-N- 621-64-7 1-Propanamine, N-nitroso-N- 8070 10 dipropylamine; Di-n-propylnitrosamine. propyl-. Page 12 of 16
Tawe6 Southern Nuclear Operating Company Plant Vogtle Landfills # 2 and #3 Appendix II to Part 40 CFR Part 258: Constituents for Assessment Monitoring Suggested Common Name \2\ CAS RN \3\ Chemical abstracts service methods PQL (fl index name \4\ \5\ giL) \6\ N-Nitrosomethylethalamine . 10595-95-6 Ethanamine, N-methyl-N-nitroso- 8270 10 N-Nitrosopiperidine . 100-75-4 Piperidine, 1-nitroso- . 8270 20 N-Nitrosopyrrolidine . 930-55-2 Pyrro1idine, 1-nitroso- . 8270 40 5-Nitro-o-toluidine . 99-55-8 Benzenamine, 2-methyl-5-nitro- 8270 10 Parathion . 56-38-2 Phosphorothioic acid, 0,0- 8141 0.5 diethyl 0-(4-nitropheny1) 8270 10 ester. Pentachlorobenzene . 608-93-5 Benzene, pentachloro- . 8270 10 Pentachloronitrobenzene . 82-68-8 Benzene, pentachloronitro- . 8270 20 Pentachlorophenol . 87-86-5 Phenol, pentachloro- . 8040 5 8270 50 Phenacetin . 62-44-2 Acetamide, N-(4-ethoxyphenl) .. 8270 20 Phenanthrene . 85-01-8 Phenanthrene . 8100 200 8270 10 Phenol . 108-95-2 Phenol . 8040 1 p-Phenylenediamine . 106-50-3 1,4-Benzenediamine . 8270 10 Phorate . 298-02-2 Phosphorodithioic acid, 0,0- 8140 2 diethy1 S-[(ethylthio)methyl] 8141 0.5 ester. 8270 10 Polychlorinated biphenyls; PCBs; See Note 9 I,l'-Biphenyl, ch1oro 8080 50 Aroclors. derivatives. 8270 200 Pronamide . 23950-58-5 Benzamide, 3,5-dichloro-N-(1,1- 8270 10 dimethyl-2-propynyl)-. Propionitrile; Ethyl cyanide . 107-12-0 Propanenitrile . 8015 60 8260 150 Pyrene . 129-00-0 Pyrene . 8100 200 8270 10 Safrole . 94-59-7 1,3-Benzodioxo1e, 5-(2- 8270 10 propeny1)-. Selenium . (Total) Selenium . 6010 750 7740 20 7741 20 Silver . (Total) Silver . 6010 70 7760 100 7761 10 Page 13 ofl6
TaUle6 Southern Nuclear Operating Company Plant Vogtle Landfills # 2 and #3 Appendix II to Part 40 CFR Part 258: Constituents for Assessment Monitoring Suggested Common Name \2\ CAS RN \3\ Chemical abstracts service methods PQL ()l index name \4\ \5\ giL) \6\ Silvex; 2,4,5-TP . 93-72-1 Propanoic acid, 2-(2,4,5- 8150 2 trichlorophenoxy)-. Styrene . 100-42-5 Benzene, ethenyl- . 8020 1 8021 0.1 8260 10 Sulfide . 18496-25-8 Sulfide . 9030 4000 2,4,5-T; 2,4,5-Trichlorophenoxyacetic 93-76-5 Acetic acid, (2,4,5- 8150 2 acid. trichlorophenoxy)-. l,2,4,5-Tetrachlorobenzene . 95-94-3 Benzene, l,2,4,5-tetrachloro-. 8270 10 l,l,l,2-Tetrachloroethane . 630-20-6 Ethane, l,l,l,2-tetrachloro- .. 8010 5 8021 0.05 8260 5 l,l,2,2-Tetrachloroethane . 79-34-5 Ethane, l,l,2,2-tetrach1oro- .. 8010 0.5 8021 0.1 8260 5 Tetrachloroethylene; 127-18-4 Ethene, tetrachloro- . 8010 0.5 Tetrachloroethene; Perchloroethylene. 8021 0.5 8260 5 2,3,4,6-Tetrachlorophenol . 58-90-2 Phenol, 2, 3, 4, 6-tetrachloro- .. 8270 10 Thallium . (Total) Thallium . 6010 400 7840 1000 7841 10 Tin . (Total) Tin . 6010 40 Toluene . 108-88-3 Benzene, methyl- . 8020 2 8021 0.1 8260 5 o-Toluidine . 95-53-4 Benzenamine, 2-methyl- . 8270 10 Toxaphene . See Note 10 Toxaphene . 8080 2 l,2,4-Trichlorobenzene . 120-82-1 Benzene, l,2,4-trichloro- . 8021 0.3 8120 0.5 8260 10 8270 10 1, 1, I-Trichloroethane; 71-55-6 Ethane, l,l,l-trichloro- . 8010 0.3 Methylchloroform. 8021 0.3 8260 5 Page 14 of 16
TaUle 6 Southern Nuclear Operating Company Plant Vogtle Landfills # 2 and #3 Appendix II to Part 40 CFR Part 258: Constituents for Assessment Monitoring Suggested Cornmon Name \2\ CAS RN \3\ Chemical abstracts service methods PQL (].1 index name \4\ \5\ giL) \6\ 1,1,2-Trichloroethane '" . 79-00-5 Ethane, 1,1,2-trichloro- . 8010 0.2 8260 5 Trichloroethylene; Trich1oroethene .... 79-01-6 Ethene, trichloro- . 8010 1 8021 0.2 8260 5 Trichlorofluoromethane; CFC-11 . 75-69-4 Methane, trichlorofluoro- ..... 8010 10 8021 0.3 8260 5 2,4,5-Trichlorophenol . 95-95-4 Phenol, 2,4,5-trichloro- . 8270 10 2,4,6-Trichlorophenol . 88-06-2 Phenol, 2, 4, 6-trichloro- . 8040 5 8270 10 1,2,3-Trichloropropane . 96-18-4 Propane, 1,2,3-trichloro- ..... 8010 10 8021 5 8260 15 0,0,0-Triethy1 phosphorothioate . 126-68-1 Phosphorothioic acid, 0,0,0- 8270 10 triethylester. sym-Trinitrobenzene , 99-35-4 Benzene, 1,3,5-trinitro- . 8270 10 Vanadium . (Total) Vanadium . 6010 80 7910 2000 7911 40 Vinyl acetate . 108-05-4 Acetic acid, ethenyl ester . 8260 50 Vinyl chloride; Chloroethene . 75-01-4 Ethene, chloro- . 8010 2 8021 0.4 8260 10 Xylene (total) . See Note 11 Benzene, dimethyl- . 8020 5 8021 0.2 8260 5 Zinc . (Total) Zinc . 6010 20 7950 50 7951 0.5 Notes \1\ The regulatory requirements pertain only to the list of substances; the right hand columns (Methods and PQL) are given for informational purposes only. See also footnotes 5 and 6. Page 15 of 16
i Tau£e 6 Southern Nuclear Operating Company Plant Vogde Landfills # 2 and #3 Appendix II to Part 40 CFR Part 258: Constituents for Assessment Monitoring Suggested Corrunon Name \2\ CAS RN \3\ Chemical abstracts service methods PQL (11 index name \4\ \5\ giL) \6\ \2\ Corrunon names are those widely used in government regulations, scientific publications, and corrunerce; synonyms exist for many chemicals. \3\ Chemical Abstracts Service registry number. Where "Total" is entered, all species in the ground water that contain this element are included. \4\ CAS index are those used in the 9th Collective Index. \5\ Suggested Methods refer to analytical procedure numbers used in EPA Report SW-846 "Test Methods for Evaluating Solid Waste", third edition, November 1986, as revised, December 1987. Analytical details can be found in SW-846 and in documentation on file at the agency. CAUTION: The methods listed are representative SW-846 procedures and may not always be the most suitable method(s) for monitoring an analyte under the regulations. \6\ Practical Quantitation Limits (PQLs) are the lowest concentrations of analytes in ground waters that can be realiably determined within specified limits of precision and accuracy by the indicated methods under routine laboratory operating conditions. The PQLs listed are generally stated to one significant figure. PQLs are based on 5 mL samples for volatile organics and 1 L samples for semivolatile organics. CAUTION: The PQL values in many cases are based only on a general estimate for the method and not on a determination for individual compounds; PQLs are not a part of the regulation. \7\ This substance is often called Bis(2-chloroisopropyl) ether, the name Chemical Abstracts Service applies to its noncorrunercial isomer, Propane, 2,2[sec]-oxybis[2-chloro- (CAS RN 39638-32-9). \8\ Chlordane: This entry includes alpha-chlordane (CAS RN 5103-71-9), beta-chlordane (CAS RN 5103-74-2), garruna-chlordane (CAS RN 5566-34-7), and constituents of chlordane (CAS RN 57-74-9 and CAS RN 12789-03-6). PQL shown is for technical chlordane. PQLs of specific isomers are about 20 llg/L by method 8270. \9\ Polychlorinated biphenyls (CAS RN 1336-36-3); this category contains congener chemicals, including constituents of Aroclor 1016 (CAS RN 12674-11-2), Aroclor 1221 (CAS RN 11104-28-2), Aroclor 1232 (CAS RN 11141-16-5), Aroclor 1242 (CAS RN 53469-21-9), Aroclor 1248 (CAS RN 12672-29-6), Aroclor 1254 (CAS RN 11097-69-1), and Aroclor 1260 (CAS RN 11096-82-5). The PQL shown is an average value for PCB congeners. \10\ Toxaphene: This entry includes congener chemicals contained in technical toxaphene (CAS RN 8001-35-2), i.e., chlorinated camphene. \11\ Xylene (total): This entry includes a-xylene (CAS RN 96-47-6), m-xylene (CAS RN 108-38-3), p-xylene (CAS RN 106-42-3), and unspecified xylenes (dimethylbenzenes) (CAS RN 1330-20-7). PQLs for method 8021 are 0.2 for 0-xylene and 0.1 for m- or p-xylene. The PQL for m-xylene is 2.0 llg/L by method 8020 or 8260. Page 16 of 16
Table 7 Southern Nuclear Operating Company Plant Vogtle Landfill #2 Summary of Detected Parameters July 2002 WEll SAMPLES CONSTITUENT MCl GWA-2/MW-2 GWC-3/MW-3 GWS-4/MW-4 GWC-11/MW-11 1 Metals Sarium 2 0.027 SQl 0.021 0.085 Zinc NA SQl SQl SQl 0.034 Organics2 1,1-Dichloroethane NA SQl SQl SQl SQl Chlorobenzene 100 SQl SQl SQl SQl 1A-Dichlorobenzene 75 SQl SQl SQl SQl Methylene chloride 5 SQl SQl cis-1,2-Dichloroethene 70 SQl SQl SQl SQl Trichlorofluoromethane NA SQl SQl 5 SQl 1,1-Dichloroethene 7 SQl SQl SQl SQl Xylenes (Total) 10000 SQl SQl SQl SQl Vinyl chloride 2 SQl SQl SQl SQl SQl - Selow quantification level MCl - Maximum Contaminant level per Georgia EPD Rule Chapter 391-3-5; NA - None available 1Metals concentrations in mg/l 20 rgan ics concentrations in ug/l or ppb Indicates exceedance of MCl Page 1 of6
Table 7 (continued) Southern Nuclear Operating Company Plant Vogtle Landfill #2 Summary of Detected Parameters September 2002 WEll SAMPLES CONSTITUENT MCl GWA-2/MW-2 GWC-3/MW-3 GWS-4/MW-4 GWC-11/MW-11 Metals 1 Sarium 2 SOL SOL 0.021 0.020 Zinc NA SOL SOL SOL SOL 2 Organics 1,1-Dichloroethane NA SOL SOL SOL SOL Chlorobenzene 100 SOL SOL SOL SOL 1,4-Dichlorobenzene 75 SOL SOL SOL SOL Methylene chloride 5 SOL SOL SOL SOL cis-1,2-Dichloroethene 70 SOL SOL SOL SOL Trichlorofluoromethane NA SOL SOL SOL SOL 1,1-Dichloroethene 7 SOL SOL SOL SOL Xylenes (Total) 10000 SOL SOL SOL SOL Vinyl chloride 2 SOL SOL SOL SOL SOL - Selow quantification level MCl - Maximum Contaminant level per Georgia EPD Rule Chapter 391-3-5; NA - None available 1Metals concentrations in mg/l 20rganics concentrations in ug/I or ppb Indicates exceedance of MCl Page 2 of6
Table 7 (continued) Southern Nuclear Operating Company Plant Vogtle Landfill #2 Summary of Detected Parameters October 2002 WELL SAMPLES CONSTITUENT MCL GWA-2/MW-2 GWC-3/MW-3 3 GWS-4/MW-4 GWC-11/MW-11 1 Metals Sarium 2 SOL NS 0.021 0.025 Zinc NA SOL NS SOL SOL 2 Organics 1,1-Dichloroethane NA SOL NS SOL SOL Chlorobenzene 100 SOL NS SOL SOL 1A-Dichlorobenzene 75 SOL NS SOL SOL Methylene chloride 5 SOL NS SOL SOL cis-1,2-Dichloroethene 70 SOL NS SOL SOL Trichlorofluoromethane NA SOL NS SOL SOL 1,1-Dichloroethene 7 SOL NS SOL SOL Xylenes (Total) 10000 SOL NS SOL SOL Vinyl chloride 2 SOL NS SOL BOL BOL - Below quantification level MCl - Maximum Contaminant Level per EPD Rule Chapter 391-3-5; NA - None available 1Metals concentrations in mg/L 20 rganics concentrations in ug/I or ppb 3Dry well, not sampled (NS) Indicates exceedance of MCL Page 3 of6
Table 7 (continued) Southern Nuclear Operating Company Plant Vogtle Landfill #2 Summary of Detected Parameters December 2002 M WELL SAMPLES CONSTITUENT 3 CL GWA-2/MW-2 GWC-3/MW-3 GWS-4/MW-4 GWS-4/MW-4 GWC-11/MW-11 1 Metals Sarium 2.00 0.015 0.020 0.021 0.020 0.018 Zinc NA SOL 0.047 SOL SOL SOL Organics2 1,1-Dichloroethane NA SOL SOL SOL SOL SOL Chlorobenzene 100 SOL SOL SOL SOL SOL 1,4-Dicholorbenzene 75 SOL SOL SOL SOL SOL Methylene chloride 5 SOL SOL SOL SOL SOL cis-1,2-Dichloroethene 70 SOL SOL SOL SOL SOL Trich lorofluoromethane NA SOL SOL SOL SOL SOL 1,1-Dichloroethene 7 SOL SOL SOL SOL SOL Xylenes (Total) 10000 SOL SOL SOL SOL SOL Vinyl chloride 2 SOL SOL SOL SOL SOL SOL - Selow quantification level MCL - Maximum Contaminant Level per EPD Rule Chapter 391-3-5; NA - None available 1Metals concentrations in mg/L 20rganics concentrations in ug/l or ppb 3Replicate sample of GWS-4/1MW-4 well Indicates exceedance of MCL Page 4 of6
Table 7 (continued) Southern Nuclear Operating Company Plant Vogtle Landfill #2 Summary of Detected Parameters June 2003 WEll SAMPLES CONSTITUENT MCl GWA-2/MW-2 GWC-3/MW-3 GWS-4/MW-4 GWC-11/MW-11 Metals 1 Sarium 2.00 Sal NS Sal Sal Zinc NA Sal NS Sal 0.029 Organics 2 1,1-Dichloroethane NA Sal NS Sal Sal Chlorobenzene 100 Sal NS Sal Sal 1,4-Dicholorbenzene 75 Sal NS Sal Sal Methylene chloride 5 Sal NS Sal Sal cis-1,2-Dichloroethene 70 Sal NS Sal Sal Trichlorofluoromethane NA Sal NS Sal Sal 1,1-Dichloroethene 7 Sal NS Sal Sal Xylenes (Total) 10000 Sal NS Sal Sal Vinyl chloride 2 Sal NS Sal Sal Sal - Selow quantification level MCl - Maximum Contaminant level per EPD Rule Chapter 391-3-5; NA - None available NS - Not sampled; well dry 1Metals concentrations in mg/l 20 rganics concentrations in ug/l or ppb Indicates exceedance of MCl Page 50f6
Table 7 (continued) Southern Nuclear Operating Company Plant Vogtle Landfill #2 Summary of Detected Parameters December 2003 WEll SAMPLES CONSTITUENT MCl GWA-2/MW-2 GWC-3/MW-3 GWS-4/MW-4 GWC-11/MW-11 1 Metals Sarium 2.00 Sal Sal Sal 0.022 Zinc NA Sal Sal Sal Sal Organics 2 1,1-Dichloroethane NA Sal Sal Sal Sal Chlorobenzene 100 Sal Sal Sal Sal 1,4-Dicholorbenzene 75 Sal Sal Sal Sal Methylene chloride 5 Sal Sal Sal Sal cis-1,2-Dichloroethene 70 Sal Sal Sal Sal Trichlorofluoromethane NA Sal Sal 6 Sal 1,1-Dichloroethene 7 Sal Sal Sal Sal Xylenes (Total) 10000 Sal Sal Sal Sal Vinyl chloride 2 Sal Sal Sal Sal Sal - Selow quantification level MCl - Maximum Contaminant level per EPD Rule Chapter 391-3-5; NA - None available NS - Not sampled; well dry 1Metals concentrations in mg/l 20 rgan ics concentrations in ug/l or ppb Indicates exceedance of MCl Page 6 of6
Table 8 Southern Nuclear Operating Company Plant Vogtle Landfill #3 Summary of Detected Parameters July 2002 WEllS1 CONSTITUENT MCl GWC-5IMW-5 GWS-6/MW-6 GWA-7/MW-7 GWA-7-2JMW-7-2 3 GWC-13/MW-13 GWC-14/MW-14 GWA-15/MW-15 Metals1 Sarium 2 Sal Sal Sal Sal 0.077 0.068 Sal Zinc NA Sal Sal Sal Sal Sal Sal Sal Organics 2 1,1-Dichloroethane NA Sal Sal Sal Sal Sal 13 Sal Chlorobenzene 100 Sal Sal Sal Sal Sal Sal Sal 1A-Dichlorobenzene 75 Sal Sal Sal Sal Sal 20 Sal Methylene chloride 5 Sal cis-1,2-Dichloroethene 70 Sal Sal Sal Sal Sal 10 Sal Trichlorofluoromethane NA Sal Sal 177 192 300 43 Sal 1,1-Dichloroethene 7 Sal Sal Sal Sal Sal Sal Sal Xylenes (Total) 10000 Sal Sal Sal Sal Sal 8 Sal Vinyl chloride 2 Sal Sal Sal Sal Sal Sal Sal Sal - Selow quantification level MCl - Maximum Contaminant level per Georgia EPD Rule Chapter 391-3-5; NA - None available .e 1Metals concentrations in mg/l 20rganics concentration units in ug/l or ppb 3Replicate sample of GWA-7/MW-7 well sample i_Indicates exceedance of Mel Page 1 of6
Table 8 (continued) Southern Nuclear Operating Company Plant Vogtle Landfill #3 Summary of Detected Parameters September 2002 WELL SAMPLES CONSTITUENT MCL 3 GWC-51MW-5 GWS-6/MW-6 GWA-7IMW-7 GWC-13IMW-13 GWC-141MW-14 GWC-14-2IMW-14-2 GWA-15IMW-15 Metals' Sarium 2 0.020 SaL saL 0.085 0.092 0.095 saL Zinc NA SaL saL saL 0.023 saL saL saL Organics2 1,1-DiChloroethane NA saL saL saL 6 21 21 saL Chlorobenzene 100 saL saL saL saL 8 8 saL l,4-Dichlorobenzene 75 saL saL saL saL 37 36 saL Methylene chloride 5 SaL saL saL saL saL saL saL cis-l,2-Dichloroethene 70 saL saL saL saL 19 18 saL Trichlorofluoromethane NA saL saL 32 381 47 48 saL 1,1-Dichloroethene 7 saL saL saL saL Xylenes (Total) 10000 SaL saL saL saL 23 23 saL Vinyl chloride 2 SaL saL saL saL saL saL saL - Selow quantification level MCL - Maximum Contaminant Level per Georgia EPD Rule Chapter 391-3-5; NA - None available 'Metals concentrations in mglL 20rganics concentration units in ugn or ppb 3Replicate sample ot GWS-14/1MW-14 well sample Ifll:~* * * * *
- lndlicates exceedance ot MCL Page 20t6
Table 8 (continued) Southern Nuclear OperatIng Company Plant Vogtle Landfill #3 Summary of Detected Parameters October 2002 WEll SAMPLES CONSTITUENT MCl 3 GWC-5IMW-5 GWS-6/MW-6 GWA-7/MW-7 GWC-13/MW-13 GWC-14/MW-14 GWA-15/MW-15 GWA-15-21MW-15-2 Metals' Sarium SOL SOL SOL 0.083 0.064 SOL SOL Zinc SOL SOL SOL 0.027 SOL SOL SOL Organics2 1,1-Dichloroethane NA SOL SOL SOL 6 17 SOL SOL Chlorobenzene 100 SOL SOL SOL SOL 9 SOL SOL 1,4-Dicholorbenzene 75 SOL SOL SOL SOL 35 SOL SOL Methylene chloride 5 SOL SOL SOL SOL SOL SOL cis-l ,2-Dichloroethene 70 SOL SOL SOL SOL 16 SOL SOL Trichlorofluoromethane NA SOL SOL 221 348 31 SOL SOL 1,1-Dichloroethene 7 SOL SOL SOL SOL SOL SOL SOL Xylenes (Total) 10000 SOL SOL SOL SOL 11 SOL SOL Vinyl chloride 2 SOL SOL SOL SOL SOL SOL SOL SOL - Selow quantification level MCl - Maximum Contaminant level per EPD Rule Chapter 391-3-5; NA - None available 'Metals concentrations in mg/l 20rganics concentration units in ugll or ppb 3Replicate sample of GWA-15/IMW-15 well 11* * * * * *1 Indicates exceedance of MCl Page 3 of6
Table 8 (continued) Southern Nuclear Operating Company Plant Vogtle Landfill #3 Summary of Detected Parameters December 2002 WEll SAMPLES CONSTITUENT MCl GWC-5/MW-5 GWS-6/MW-6 GWA-7/MW-7 GWC-13/MW-13 GWC-14/MW-14 GWA-15/MW-15 1 Metals Sarium 2.00 0.018 SOL 0.015 0.082 0.106 SOL Zinc NA SOL SOL SOL 0.027 SOL SOL Organics 2 1,1-Dichloroethane NA SOL SOL SOL 7 16 SOL Chlorobenzene 100 SOL SOL SOL SOL 10 SOL 1,4-Dicholorbenzene 75 SOL SOL SOL SOL 39 SOL Methylene chloride 5 SOL SOL SOL SOL SOL SOL cis-1,2-Dichloroethene 70 SOL SOL SOL SOL 19 SOL Trichlorofluoromethane NA SOL SOL 210 391 27 SOL 1,1-Dichloroethene 7 SOL SOL SOL SOL Xylenes (Total) 10000 SOL SOL SOL SOL 21 SOL Vinyl chloride 2 SOL SOL SOL SOL SOL 3 Chloroform 0.1 SOL SOL SOL 5 SOL SOL SOL - Selow quantification level MCl - Maximum Contaminant level per EPD Rule Chapter 391-3-5; NA - None available 1Metals concentrations in mg/l 20 rgan ics concentration units in ug/l or ppb 3Applies only to Community Water Systems serving 10,000 Indicates exceedance of MCl Page 4 of6
Table 8 (continued) Southern Nuclear Operating Company Plant Vogtle Landfill #3 Summary of Detected Parameters June 2003 WEll SAMPLES CONSTITUENT MCl 5 GWC-5/MW-5 GWS-6/MW-6 GWA-7/MW-7 GWC-13/MW-13 GWC-13/MW-13 GWC-14/MW-14 GWA-15/MW-15 Metals' Sarium 2.00 Sal Sal 0.036 0.029 0.030 0.051 Sal Zinc NA Sal Sal 0.034 Sal Sal Sal Sal Copper 1.3 Sal Sal 0.035 Sal Sal Sal Sal Mercurl 0.002 NA NA NA 0.0005 0.0005 Sal 2 Organics 1,1-Dichloroethane NA Sal Sal Sal 9 9 10 Sal Chlorobenzene 100 Sal Sal Sal Sal Sal 7 Sal 1,4-Dicholorbenzene 75 Sal Sal Sal Sal Sal 16 Sal Methylene chloride 5 Sal Sal Sal Sal Sal Sal Sal cis-1,2-Dichloroethene 70 Sal Sal Sal 6 6 10 Sal Trichlorofluoromethane NA Sal Sal 23 41 47 5 Sal 1,1-Dichloroethene 7 Sal Sal Sal Sal Sal Sal Sal Xylenes (Total) 10000 Sal Sal Sal Sal Sal Sal Sal Vinyl chloride 2 Sal Sal Sal Sal Sal Sal Sal Chloroform3 0.1 Sal Sal Sal Sal Sal Sal Sal Sal - Selow quantification level MCl - Maximum Contaminant level per EPD Rule Chapter 391-3-5; NA - None Available or Not Analyzed
'Metals concentrations in mg/l 20rganics concentration units in ugll or ppb 3Applies only to Community Water Systems serving 10,000 'Appendix 1\ parameter; NA reflects that this parameter was not analyzed for those wells not included in the Assessment Monitoring Program 5Replicate sample of well GWC-13/MW-13 sample Nill!lli~IlI¥J* * * *
- lndicates exceedance of MCl Page 5 of6
Table 8 (continued) Southern Nuclear Operating Company Plant Vogtle Landfill #3 Summary of Detected Parameters December 2003 WELL SAMPLES CONSTITUENT MCL GWC-5/MW-5 GWS-6/MW-6 GWA-7/MW-7 GWC-13/MW-13 GWC-13/MW-135 GWC-14/MW-14 GWA-15/MW-15 1 Metals Sarium 2.00 0.142 SOL SOL 0.033 0.032 0.169 SOL Zinc NA 0.032 SOL 0.023 SOL SOL 0.127 SOL 6 Copper 1.3 0.025 SOL SOL SOL SOL 0.026 SOL Mercury' 0.002 SOL SOL SOL SOL SOL SOL Chromium (total) 0.1 0.026 SOL SOL SOL SOL 0.091 SOL Seryllium 0.004 SOL SOL SOL SOL SOL 0.004 SOL Cadmium 0.005 SOL SOL SOL SOL SOL SOL Nickel NA SOL SOL SOL SOL SOL 0.034 SOL Lead 0.0156 SOL SOL SOL SOL SOL 0.015 SOL Vanadium NA SOL SOL SOL SOL SOL 0.060 SOL Organics 2 1,1-Dichloroethane NA SOL SOL SOL 20 21 10 SOL Chlorobenzene 100 SOL SOL SOL SOL SOL 19 SOL 1,4-Dicholorbenzene 75 SOL SOL SOL SOL SOL 33 SOL Methylene chloride 5 SOL SOL SOL SOL SOL SOL SOL cis-1,2-Dichloroethene 70 SOL SOL SOL 14 14 17 SOL Trichlorofluoromethane NA SOL SOL 34 102 97 SOL SOL 1,1-Dichloroethene 7 SOL SOL SOL SOL SOL SOL SOL Xylenes (Total) 10000 SOL SOL SOL SOL SOL 10 SOL Vinyl chloride 2 SOL SOL SOL SOL SOL SOL SOL Chloroform) 0.1 SOL SOL SOL SOL SOL SOL SOL SOL - Selow quantification level MCL - Maximum Contaminant Level per EPD Rule Chapter 391-3-5; NA - None Available or Not Analyzed lMetals concentrations in mg/L 20rganics concentration units in ugll or ppb )Applies only to Community Water Systems serving 10,000 4Appendix II parameter; NA reflects that this parameter was not analyzed for those wells not included in the Assessment Monitoring Program 5Replicate sample of well GWC-13/MW-13 sample 6Action Level IIIIl!11 _Indicates exceedance of MCL Page 6 of6
FIGURES
ApPENDIX A - LABORATORY ANALYTICAL REPORTS LANDFILL #2 IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40~9~-1~4:":'4~4 ----------------~30~3~9~A:-m-w-:i:-le-r :'Ro-a-d~*-::S:-u~ite~10~0~*-:A~tl:-an-:t-a,-:G~A~3~03~6~0-Fax: (770) 409-1844 P.O. Box 88610' Atlanta, GA 30356 e-mail: ac/@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell V.O. (50308/82608)
- Appendix I Sample 10: GWA-21MW-2 Matrix: Water Date Sampled: 12/1712003 Date Extracted:
Date Analyzed: 12/30/2003 ACL Sample #: 210466 Units: /Jg/L Analyst: RP Analyte Result PQL Analyte Result PQL Acetone Sal 100 Methylene bromide Sal 5 Acrylonitrile Sal 50 Methylene chloride Sal 5 Senzene Sal 5 Styrene Sal 5 Sromoch loromethane Sal 5 1,1,1,2-Tetrachloroethane Sal 5 Sromodichloromethane Sal 5 1,1 ,2,2-Tetrachloroethane Sal 5 Bromoform Sal 5 Tetrachloroethene Sal 5 ""-'rbon disulfide Sal 5 Toluene Sal 5
..bon tetrachloride Sal 5 1,1,1-Trichloroethane Sal 5 Chlorobenzene Sal 5 1,1,2-Trichloroethane Sal 5 Chloroethane Sal 10 Trichloroethene Sal 5 Chloroform Sal 5 Trichlorofluoromethane Sal 5 1,2-Dibromo-3-chloropropane Sal 20 1,2,3-Trichloropropane Sal 5 Dibromochloromethane Sal 5 Vinyl acetate Sal 50 1,2-Dibromoethane Sal 5 Vinyl chloride Sal 2 trans-1,4-Dichloro-2-butene Sal 10 m & p-Xylenes Sal 10 1,2-Dichlorobenzene Sal 5 o-Xylene Sal 5 1A-Dichlorobenzene Sal 5 1,1-Dichloroethane Sal 5 1,2-Dichloroethane Sal 5 1,1-Dichloroethene Sal 5 cis-1.2-Dichloroethene Sal 5 trans-1,2-Dichloroethene Sal 5 1,2-Dichloropropane Sal 5 cis-1,3-Dichloropropene Sal 5 trans-1,3-Dichloropropene Sal 5 Ethylbenzene Sal 5 2-Hexanone Sal 50 Methyl bromide Sal 10 Methyl chloride Sal 10 Methyl ethyl ketone Sal 100
.~ethyl iodide Sal 5 1ethyl-2-pentanone Sal 50 BOl = Below Quanlilalion lim~ J = less than Ouantitation llmiL Approximate Value POL =Practical Quantilation limit
Phone: (770) Fax: (770) 409-1844 I
!ACL 40~9~-1~4:":'4":"4----------------~30~3~9-:A~m-w~i1:-er-:R::"o-a-:d:-*"'::S~u~ite~10~O:-*-:A~t1-an~ta-,~G~A~30~3~6~O-ADVANCED CHEMISTRY LABS, INC.
P.O. Box 88610
- Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell V.o. (50308/82608)
- Appendix I Sample 10: GWC-3/MW-3 Matrix: Water Date Sampled: 12/17/2003 Date Extracted:
Date Analyzed: 12130/2003 ACL Sample #: 210467 Units: IJg/L Analyst: RP Analvte Result PQL Analvte Result PQL Acetone BOl 100 Methylene bromide BOl 5 Acrylonitrile BOl 50 Methylene chloride BOl 5 Benzene BOl 5 Styrene BOl 5 Bromochloromethane BOl 5 1,1,1,2-Tetrachloroethane BOl 5 Bromodichloromethane BOl 5 1,1,2,2-Tetrachloroethane BOl 5 Bromoform BOl 5 Tetrachloroethene BOl 5
"'arbon disulfide BOl 5 Toluene BOl 5
..;arbon tetrachloride BOl 5 1,1,1-Trichloroethane BOl 5 Chlorobenzene BOl 5 1,1,2-Trichloroethane BOl 5 Chloroethane BOl 10 Trichloroethene BOl 5 Chloroform BOl 5 Trichlorofluoromethane BOl 5 1,2-Dibromo-3-chloropropane BOl 20 1,2,3-Trichloropropane Sal 5 Dibromochloromethane BOl 5 Vinyl acetate Sal 50 1,2-Dibromoethane BOl 5 Vinyl chloride Sal 2 trans-1,4-Dichloro-2-butene BOl 10 m & p-Xylenes BOl 10 1,2-Dichlorobenzene BOl 5 o-Xylene Sal 5 1,4-Dichlorobenzene BOl 5 1,1-Dichloroethane BOl 5 1,2-Dichloroethane BOl 5 1,1-Dichloroethene BOl 5 cis-1,2-Dichloroethene BOl 5 trans-1,2-Dichforoethene BOl 5 1,2-Dichloropropane BOl 5 cis-1,3-Dichloropropene BOl 5 trans-1,3-Dichloropropene BOl 5 Ethylbenzene BOl 5 2-Hexanone BOl 50 Methyl bromide BOl 10 Methyl chloride BOl 10 Methyl ethyl ketone BOl 100 Methyl iodide BOl 5
-Methyl-2-pentanone BOl 50 BOL = Below Quanlilation Llm~
J = Less than Ouantilalion Limit, Approximate Value POL = Practical Ouanlilation LIm~
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40~9-.1-4-4-4----------------'!"30~3~9~A~m-w~i1~e~r R~o-a~d-*~S~u~ite-10!"""0-*~A"t1-an-ta-,-G!""'A--30"!"'3!"""6~0-Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/1912003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell v.o. (50308/82608)
- Appendix I SamplelD: GWB-4/MW-4 Matrix: Water Date Sampled: 12/1712003 Date Extracted:
Date Analyzed: 1213012003 ACL Sample #: 210468 Units: ~g/L Analyst: RP Analyte Result PQL Analyte Result PQL Acetone Sal 100 Methylene bromide Sal 5 Acrylonitrile Sal 50 Methylene chloride SOL 5 Senzene Sal 5 Styrene SOL 5 Sromochloromethane Sal 5 1,1,1,2-Tetrachloroethane SOL 5 Sromodichloromethane Sal 5 1,1,2,2-Tetrachloroethane SOL 5 Sromoform Sal 5 Tetrachloroethene SOL 5 -'arbon disulfide Sal 5 Toluene SOL 5
,arbon tetrachloride Sal 5 1,1 ,1-Trichloroethane SOL 5 Chlorobenzene Sal 5 1,1,2-Trichloroethane SOL 5 Chloroethane Sal 10 Trichloroethene Sal 5 Chloroform Sal 5 Trichlorofluoromethane 6 5 l,2-Dibromo-3-chloropropane Sal 20 1,2,3-Trichloropropane SOL 5 Dibromochloromethane Sal 5 Vinyl acetate SOL 50 l,2-Dibromoethane Sal 5 Vinyl chloride SOL 2 trans-1,4-Dichloro-2-butene Sal 10 m & p-Xylenes SOL 10 1,2-Dichlorobenzene Sal 5 o-Xylene SOL 5
. 1A-Dichlorobenzene SOL 5 1,1-Dichloroethane Sal 5 1,2-Dichloroethane Sal 5 1,1-Dichloroethene Sal 5 cis-1,2-Dichloroethene SOL 5 trans-1,2-Dichloroethene Sal 5 1,2-Dichloropropane SOL 5 cis-1,3-Dichloropropene SOL 5 trans-1,3-Dichloropropene SOL 5 Ethylbenzene SOL 5 2-Hexanone SOL 50 Methyl bromide Sal 10 Methyl chloride SOL 10 Methyl ethyl ketone SOL 100 _!v1ethyt iodide SOL 5 Methyl-2-pentanone Sal 50
=
SOL Below Quantilation limit J = less than OuantUtion limit. Approximate Value POL = Practical Ouanlitalion limit
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40~9~-1~44:"":"":"4----------------"='30~3~9~Am~Wl"':"~le-r R~o-a~d~*~S~u':':"ite~10~0~*~A~t1~an"':'ta-,"':'G~A~3~03~6~O-Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acf-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACl Project #: 44014 Smyrna. GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell v.o. (5030B/8260B)
- Appendix I Sample 10: GWC-11/MW-11 Matrix: Water Date Sampled: 12/1712003 Date Extracted:
Date Analyzed: 12/30/2003 ACl Sample #: 210472 Units: IJg /L Analyst: RP Analyte Result PQl Analyte Result PQl Acetone Sal 100 Methylene bromide Sal 5 Acrylonitrile Sal 50 Methylene chloride Sal 5 Senzene Sal 5 Styrene Sal 5 Sromochloromethane Sal 5 1,1,1 ,2-Tetrachloroethane Sal 5 Sromodichloromethane Sal 5 1,1,2,2-Tetrachloroethane Sal 5 Sromoform Sal 5 Tetrachloroethene Sal 5
'ubon disulfide Sal 5 Toluene Sal 5 ....arbon tetrachloride Sal 5 1,1,1-Trichloroethane Sal 5 Chlorobenzene Sal 5 1,1,2-Trichloroethane Sal 5 Chloroethane Sal 10 Trich loroethene Sal 5 Chloroform Sal 5 Trichlorofluoromethane Sal 5 1,2-Dibromo-3-chloropropane Sal 20 1,2,3-Trichloropropane Sal 5 Dibromochloromethane Sal 5 Vinyl acetate Sal 50 1,2-Dibromoethane Sal 5 Vinyl chloride Sal 2 trans-1 ,4-Dichloro-2-butene Sal 10 m & p-Xylenes Sal 10 1,2-Dichlorobenzene Sal 5 o-Xylene Sal 5 1,4-Dichlorobenzene Sal 5 1,1-Dichloroethane Sal 5 1,2-Dichloroethane Sal 5 1,1-Dichloroethene Sal 5 cis-1,2-Dichloroethene Sal 5 trans-1,2-Dichloroethene Sal 5 1,2-Dichloropropane Sal 5 cis-1,3-Dichloropropene Sal 5 trans-1,3-Dichloropropene Sal 5 Ethylbenzene Sal 5 2-Hexanone Sal 50 Methyl bromide Sal 10 Methyl chloride Sal 10 Methyl ethyl ketone Sal 100
..Methyl iodide Sal 5 Methyl-2-pentanone Sal 50 BQL = Below QuanUlalion Limit J = Less than Quanlitalion LimK. ApPIOximate Value POL = Practical Quanlitation LimK
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 409-~1~4~44~--------------~3~03~9~A!"""m-w~il-er~R~o-ad~* S~u~ite~10~0-.""!'A""tla-n-ta-. ~GA~3"!"03'!""!6~0-Fax: (770) 409*1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACl Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12119/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Miscellaneous Organics (504.1)
- AppendiX II Sample 10: GWA-21MW-2 Matrix: Water Date Sampled: 12/17/2003 Date Extracted: 12/23/2003 Date Analyzed: 12130/2003 ACl Sample #: 210466 Units: ~g/L Analyst: SS Analvte Result PQl 1.2.0ibromo-3-chloropropane SQL 0.20 1.2-0ibromoethane SQL 0.05 SOL =Below Quantitation Linlt J =less than Ouantilallon Linit. APllfOximale Value POL =Practical Ouanlitatlon limit
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40~9-~1~44"':"'4~-----------~--"":3~03~9~A~m-w":':i1-er"":R~o-ad":".~S~u~lt-e ~10~O~*"":'A~t1a-n":"ta-, ~GA~30~3:-:6~0-Fax: (770) 409*1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemlstrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080~0000 Date Received: 12119/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Miscellaneous Organics (504.1) - Appendix II Sample 10: GWC-3/MW-3 Matrix: Water Date Sampled: 12/1712003 Date Extracted: 12/23/2003 Date Analyzed: 12/30/2003 ACL Sample #: 210467 Units: 1J9/L Analyst: SS Analyte Result PQL 1,2-Dibromo-3-chloropropane Sal 0.20 1,2-Dibromoethane Sal 0,05 BQl =Below Quanlilatlon limit J .. Less than Quanlilatlon linit. ADDroxmale Value
=
POL Practical Quant\lalion Limit ~-~--------- ---- _._-- -------~-------- ------- ----- - --------
Phone: (770) Fax: (770) 409-1844 I IACL 40~9~-1~4"':"44~--------------""'::3~0~39~A~m-w~iI~er""'::R~o-a"':"d ADVANCED CHEMISTRY LABS, INC.
-.S:"u~it~e"':"10~0~.""'::A~tla-n"':"ta-,~G~A""'::3~0~36~0-P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Miscellaneous Organics (504.1)
- Appendix II Sample 10: GWB-4/MW-4 Matrix: Water Date Sampled: 12/17/2003 Date Extracted: 12/23/2003 Date Analyzed: 01/0212004 ACL Sample #: 210468 Units: J.lg/L Analyst: SS An aIvte Result PQL 1,2-Dibromo-3-chloropropane Sal 0.20 1,2-Dibromoethane Sal 0.05 BQl =Below Quanlilation limit J = less than Quantltatlon limit. ADOroximate Value
=
pal Pradical Ouantilallon limit
IA CL 1~~ Phone: (770) 409-1444 Fax: (770) 409*1844 A_D_V;_~_N~C~'E~'D~c:--'H~"E-:-'M-='L~'S-:-TR~Y-:-L~A-:-B-:,S~, l~'N~C_. 3039 Amwiler Road* Suite 100* Atlanta. GA 30360 P.O. Box 88610* Atlanta. GA 30356 a-mail: acl@acl-labs.net www.advancedchamistrylabs.com Client: Genesis Project Client ProJ #: Plant Vogtle 1258 Concord Rd. ACl Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12119/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Miscellaneous Organics (504.1)
- Appendix II Sample 10: GWC-11/MW-11 Matrix: Water Date Sampled: 12117/2003 Date Extracted: 12/23/2003 Date Analyzed: 01/0212004 ACl Sample #: 210472 Units: IJg/ L Analyst: SS Analyte Result PQl 1,2-Dibromo-3-chloropropane SQl 0.20 1,2-Dibromoethane SQl 0.05 BOl " Below Quantilalion lim~
J " less than Ouantilalion Limit, Approximate Value PQl"P~akaIO~mml~
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 409~-1~4"":"44~--------------~3~O~39~A~m-w~il~er~R~o-a"":"d-' S~u~it-e"":"10~O~'~A~t1-an-ta-.~G"":"A~3~0~36~O-Fax: (770) 409-1844 P.O. Box 88610' Atlanta. GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Appendix I Metals (60108/7841) Sample ID: GWA-21MW-2 Matrix: Water Date Sampled: 12/17/2003 Date Extracted: Date Analyzed: 12130/2003 ACL Sample #: 210466 Units: mg/L Analyst: SW/AD Analvte Result PQL Antimony BOl 0.006 Arsenic BOl 0.010 Barium BOl 0.020 Beryllium BOL 0.004 Cadmium BOL 0.005 Chromium BOL 0.020
~obalt BOL 0.050 .;opper BOL 0.020 lead BOL 0.010 Nickel BOl 0.020 Selenium BOL 0.040 Silver BOl 0.010 Thallium BOl 0.002 Vanadium BOL 0.050 Zinc BOL 0.020 BQl = Below Quanlitation Linit J = less than Quantitation limit. AllD/OXimate Value PQl = Practical Quantitalion limit
~--- ---- - - - -
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40~9-.1~44"!"4~--------------""'!3~0~39~A~m-W-il~er""'!R~o-a""!"d-. S~u""!"it-e""!"10""0-*-A-tla-n-ta-.~G-A-3~O""36"'0-Fax: (770) 409-1844 P.O. Box 88610
- Atlanta. GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACl Project #: 44014 Smyrna. GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Appendix I Metals (60108/7841) Sample 10: GWC-3/MW-3 Matrix: Water Date Sampled: 12/17/2003 Date Extracted: Date Analyzed: 12/30/2003 ACl Sample #: 210467 Units: mg/l Analyst: SW/AD Analyte Result PQl Antimony Sal 0.006 Arsenic Sal 0.010 Sarium Sal 0.020 Seryllium Sal 0.004 Cadmium Sal 0.005 Chromium Sal 0.020 '~obalt Sal 0.050 opper Sal 0.020 lead Sal 0.010 Nickel Sal 0.020 Selenium Sal 0.040 Silver Sal 0.010 Thallium Sal 0.002 Vanadium Sal 0.050 Zinc Sal 0.020 BQl ,. Below Quantilalion limit J = less than Quanlilalion LimiL Approxinate Value PQl ,. Praclical QuanlDlion limit
IACL I Phone: (770) 409-1444 Fax: (770) 409*1844 ADVANCED CHEMISTRY LABS, INC. 3039 Amwiler Road' Suite 100
- Atlanta. GA 30360 P.O. Box 88610' Atlanta. GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: . Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Appendix I Metals (60108/7841) Sample 10: GWB-4/MW-4 Matrix: Water Date Sampled: 12/17/2003 Date Extracted: Date Analyzed: 12/30/2003 ACL Sample #: 210468 Units: mg/L Analyst: SW/AD Analvte Result PQL Antimony Sal 0.006 Arsenic Sal 0.010 Sarium Sal 0.020 Seryllium Sal 0.004 Cadmium Sal 0.005 Chromium Sal 0.020
'obalt Sal 0.050 ...opper Sal 0.020 lead Sal 0.010 Nickel Sal 0.020 Selenium Sal 0.040 Silver Sal 0.010 Thallium Sal 0.002 Vanadium Sal 0.050 Zinc Sal 0.020 BOl = Below Quanlitalion limit J =less than Ouantilation Linit. AoDroxlmate Value =
POL Practical Ouantilation limit
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40~9~.1~44"":"4~--------------~3~0~39~Am~w~i1:-er~R~o-a~d-. ~Su~it:-e~1~00~*~A~t1~an-ta-.~GA~3~0~36~0~ Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna. GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Appendix I Metals (6010B/7841) Sample ID: GWC-11/MW-11 Matrix: Water Date Sampled: 12/1712003 Date Extracted: Date Analyzed: 12130/2003 ACL Sample #: 210472 Units: mg/L Analyst: SW/AD Analyte Result PQL Antimony BOl 0.006 Arsenic BOl 0.010 Barium 0.022 0.020 Beryllium BOl 0.004 Cadmium Sal 0.005 ~. Chromium Sal 0.020
'obalt Sal 0.050 Copper Sal 0.020 lead BOL 0.010 Nickel Sal 0.020 Selenium SOL 0.040 Silver SOL 0.010 Thallium SOL 0.002 Vanadium Sal 0.050 Zinc SOL 0.020 BOl =Below Quantitation lim~
J = less than Quanlitation limit, Approximate Value POL =Practical Ouantitation limit
~---- ~ .~ ~~--' _.~---
LANDFILL #3 Phone: (770) Fax: (770) 409-1844 I IACL 40~9~-1:-:4~4~4----------------~30~3~9~A~m-w~i1~er~R~o-a~d~*-:S~u~ite~1 ADVANCED CHEMISTRY LABS, INC. 0~0-.~A~t1-an~ta-,~G~A~30~3~6~0-P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell V.O. (5030B/8260B) - Appendix I Sample 10: GWC-5/MW-5 Matrix: Water Date Sampled: 12/16/2003 Date Extracted: Date Analyzed: 12/30/2003 ACL Sample #: 210469 Units: IJg/L Analyst: RP Analvte Result PQL Analvte Result PQL Acetone Sal 100 Methylene bromide Sal 5 Acrylonitrile Sal 50 Methylene chloride Sal 5 Senzene Sal 5 Styrene Sal 5 SromochJoromethane Sal 5 1,1,1,2-Tetrachloroethane Sal 5 Sromodichloromethane Sal 5 1,1,2,2-Tetrachloroethane Sal 5 Sromoform Sal 5 Tetrachloroethene Sal 5
'arbon disulfide Sal 5 Toluene Sal 5 ....arbon tetrachloride Sal 5 1,1,1-TriChloroethane Sal 5 Chlorobenzene Sal 5 1,1,2-Trichloroethane Sal 5 Chloroethane Sal 10 Trichloroethene Sal 5 Chloroform Sal 5 Trichlorofluoromethane Sal 5 1,2-Dibromo-3-chloropropane Sal 20 1,2,3-Trichloropropane Sal 5 Dibromochloromethane Sal 5 Vinyl acetate Sal 50 1,2-Dibromoethane Sal 5 Vinyl chloride Sal 2 trans-1,4-Dichloro-2-butene Sal 10 m & p-Xylenes Sal 10 1,2-Dichlorobenzene Sal 5 o-Xylene Sal 5 1A-Dichlorobenzene Sal 5 1,1-Dichloroethane Sal 5 1.2-Dichloroethane Sal 5 1,1-Dichloroethene Sal 5 cis-1,2-Dichloroethene Sal 5 trans-1,2-Dichloroethene Sal 5 1,2-Dichloropropane Sal 5 cis-1,3-Dichloropropene Sal 5 trans-1 ,3-Dichloropropene Sal 5 Ethylbenzene Sal 5 2-Hexanone Sal 50 Methyl bromide Sal 10 Methyl chloride Sal 10 Methyl ethyl ketone Sal 100
_Methyl iodide Sal 5
*MethyI-2-pentanone Sal 50 BOL = Below Quantitalion Limit J = less than Ouanlitalion Limit. Approximale Value POL = Practical Ouanlitalion limit
IA CL 1~~ Phone: (770) 409-1444 Fax: (770) 409-1844 A_D_VA_N~C~'E~'D~CH~'E_'M~1.~S_T~'R_Y~LA_B~S.....,~IN~C_. 3039 Amwiler Road* Suite 100* Atlanta. GA 30360 P.O. Box 88610
- Atlanta. GA 30356 a-mail: acl@acl-fabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell V.O. (50308/82608)
- Appendix I Sample 10: GWB-6/MW-6 Matrix: Water Date Sampled: 12/17/2003 Date Extracted:
Date Analyzed: 12/30/2003 ACL Sample #: 210470 Units: ~g/L Analyst: RP Analvte Result PQL Analvte Result PQL Acetone Sal 100 Methylene bromide Sal 5 Acrylon itrile Sal 50 Methylene chloride Sal 5 Senzene Sal 5 Styrene Sal 5 Sromochloromethane Sal 5 1.1.1.2-Tetrachloroethane Sal 5 Sromodichloromethane Sal 5 1 1,2.2-Tetrachloroethane 0 Sal 5 Sromoform Sal 5 Tetrachloroethene Sal 5 lrbon disulfide Sal 5 Toluene Sal 5
....arbon tetrachloride Sal 5 1.1 i-Trichloroethane 0 Sal 5 Chlorobenzene Sal 5 1,1,2-Trichloroethane Sal 5 Chloroethane Sal 10 Trichloroethene SOL 5 Chloroform Sal 5 Trichlorofluoromethane Sal 5 1,2-Dibromo-3-chloropropane Sal 20 1.2,3-Trichloropropane Sal 5 Dibromochloromethane Sal 5 Vinyl acetate SOL 50 1,2-Dibromoethane Sal 5 Vinyl chloride Sal 2 trans-1,4-Dichloro-2-butene Sal 10 m & p-Xylenes Sal 10 1,2-Dichlorobenzene Sal 5 o-Xylene Sal 5 1,4-Dichlorobenzene Sal 5 1,1-Dichloroethane Sal 5 1.2-Dichloroethane Sal 5 1.1-Dichloroethene Sal 5 cis-1,2-Dichloroethene Sal 5 trans-1,2-Dichloroethene Sal 5 1,2-Dichloropropane Sal 5 cis-1.3-Dichloropropene Sal 5 trans-1.3-Dichloropropene Sal 5 Ethylbenzene Sal 5 2-Hexanone Sal 50 Methyl bromide Sal 10 Methyl chloride Sal 10 Methyl ethyl ketone Sal 100
,..Methyl iodide Sal 5 Methyl-2-pentanone Sal 50 eOl " Below Quanlilation limij J "less !han Ouantilation limit. Approximate Value pal" Practical Ouantllalion limit
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40~9-.1~4~44~-----~---------~30~3~9~A~m-w~il~er~R~o-a~d-*~S~u~jte~10~0-*~A-'t1-an-ta-.~G~A~30~3~6~0-Fax: (770) 409-1844 P.O. Box 88610* Atlanta. GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell v.o. (50308/82608)
- Appendix I Sample ID: GWA-7/MW-7 Matrix: Water Date Sampled: 12/16/2003 Date Extracted:
Date Analyzed: 12/30/2003 ACL Sample #: 210471 Units: IJg/L Analyst: RP Analvte Result POL Analvte Result POL Acetone SOL 100 Methylene bromide SOL 5 Acrylonitrile SOL 50 Methylene chloride SOL 5 Benzene SOL 5 Styrene SOL 5 Bromochloromethane SOL 5 1.1.1,2-Tetrachloroethane SOL 5 Bromodichloromethane SOL 5 1,1,2,2-Tetrachloroethane SOL 5 Bromoform SOL 5 Tetrachloroethene SOL 5
- 1rbon disulfide SOL 5 Toluene SOL 5 Jrbon tetrachloride SOL 5 1,1,1-Trichloroethane SOL 5 Chlorobenzene SOL 5 1,1 ,2-Trichloroethane SOL 5 Chloroethane SOL 10 Trichloroethene SOL 5 Chloroform SOL 5 Trichlorofluoromethane 34 5 1,2-Dibromo-3-chloropropane BOL 20 1,2,3-Trichloropropane Sal 5 Dibromochloromethane SOL 5 Vinyl acetate Sal 50 1.2-Dibromoethane SOL 5 Vinyl chloride SOL 2 trans-1.4-Dichloro-2-butene SOL 10 m & p-Xylenes Sal 10 1,2-Dichlorobenzene BOL 5 o-Xylene SOL 5 1A-Dichlorobenzene SOL 5 1,1-Dichloroethane SOL 5 1,2-Dichloroethane SOL 5 1,1-Dichloroethene SOL 5 cis-1,2-Dichloroethene SOL 5 trans-1,2-Dichloroethene SOL 5 1,2-Dichloropropane SOL 5 cis-1 ,3-Dichloropropene SOL 5 trans-1,3-Dichloropropene BOL 5 Ethylbenzene SOL 5 2-Hexanone SOL 50 Methyl bromide BOL 10 Methyl chloride Sal 10 Methyl ethyl ketone Sal 100
,jv1ethyl iodide SOL 5 V1ethyl-2-pentanone SOL 50 BOl = Below Quanlilalion lim~ J = less than Quantilalion Liml ADDroximale Value PQl = Practical Quanlilalion limit
IACL I Phone: (770) 409-1444 Fax: (770) 409-1644 ADVANCED CHEMISTRY LABS, INC. 3039 Amwiler Road* Suite 100* Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant VogUe 1258 Concord Rd. ACl Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell v.o. (5030B/8260B)
- Appendix II Sample 10: GWC-13/MW-13 Matrix: Water Date Sampled: 12/16/2003 Date Extracted:
Date Analyzed: 12/29/2003 ACl Sample #: 210461 Units: IJg/l Analyst: RP Analvte Result PQl Analvte Result PQl Acetone Sal 100 cis-1,3-Dichloropropene Sal 5 Acetonitrile Sal 100 trans-1,3-Dichloropropene Sal 5 Acrolein Sal 100 Ethyl methacrylate Sal 10 Acrylonitrile Sal 50 Ethylbenzene Sal 5 Allyl chloride Sal 10 2-Hexanone Sal 50 Senzene Sal 5 Isobutyl alcohol Sal 50
'romochloromethane Sal 5 Methacrylonitrile Sal 100 Jromodichloromethane Sal 5 Methyl bromide Sal 10 Sromoform Sal 5 Methyl chloride Sal 10 Carbon disulfide Sal 5 Methyl ethyl ketone Sal 100 Carbon tetrachloride Sal 5 Methyl iodide Sal 5 Chlorobenzene Sal 5 Methyl methacrylate Sal 30 Chloroethane Sal 10 4-Methyl-2-pentanone Sal 50 Chloroform Sal 5 Methylene bromide Sal 5 Chloroprene Sal 20 Methylene chloride Sal 5 1,2-Dibromo-3-chloropropane Sal 20 Naphthalene Sal 5 Dibromochloromethane Sal 5 Propionitrile Sal 150 1,2-Dibromoethane Sal 5 Styrene Sal 5 trans-1 ,4-Dichloro-2-butene Sal 10 1,1,1,2-Tetrachloroethane Sal 5 1.2-Dichlorobenzene Sal 5 1,1,2,2-Tetrachloroethane Sal 5 1,3-Dichlorobenzene Sal 5 Tetrachloroethene Sal 5 1,4-Dichlorobenzene Sal 5 Toluene Sal 5 Dichlorodifluoromethane Sal 5 1,1,1-Trichloroethane Sal 5 1,1-Dichloroethane 20 5 1,1,2-Trichloroethane Sal 5 1,2-Dichloroethane Sal 5 Trichloroethene Sal 5 1.1-Dichloroethene Sal 5 Trichlorofluoromethane 102 5 cis-1,2-Dichloroethene 14 5 1,2,3-Trichloropropane Sal 5 trans-1,2-Dichloroethene Sal 5 Vinyl acetate Sal 50 1,2-Dichloropropane Sal 5 Vinyl chloride Sal 2 1,3-Dichloropropane Sal 5 m & p-Xylenes Sal 10
~,2-Djchloropropane SOL 15 o-Xylene SOL 5
,,1-Dichloropropene Sal 5 Jl~~.$ ~
BOl =Below Quantitalion limit J =less lhan Ouanlilalion limit. APDlOximale Value Digitally signed by Markorios MIdaIaIAdib. QNac Minaaer POL =Practical Ouanlitalion limit Markorios Adaire
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IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40~9~-1~4~4~4----------------~30~3~9~A~m-w"":':il~er~R~o-a~d-*~S~u~ite~10~0~.~A~tl-an~ta-,~G~A~30~3~6~0-Fax: (770) 409*1844 P.O. Box 88610* Atlanta. GA 30356 a-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell v.o. (50308/82608)
- Appendix II Sample 10: GWC-13/MW-13-(Dupe) Matrix: Water Date Sampled: 12/1612003 Date Extracted:
Date Analyzed: 12/29/2003 ACL Sample #: 210462 Units: 1J9/ L Analyst: RP Analvte Result PQL An aIyte Result PQL Acetone SOL 100 cis-1,3-Dichloropropene SOL 5 Acetonitrile SOL 100 trans-1,3-Dichloropropene SOL 5 Acrolein SOL 100 Ethyl methacrylate SOL 10 Acrylonitrile SOL 50 Ethylbenzene SOL 5 Allyl chloride SOL 10 2-Hexanone SOL 50 Senzene SOL 5 Isobutyl alcohol SOL 50
,romochloromethane SOL 5 Methacrylonitrile SOL 100 ..:lromodichloromethane Sal 5 Methyl bromide SOL 10 Sromoform Sal 5 Methyl chloride Sal 10 Carbon disulfide SOL 5 Methyl ethyl ketone SOL 100 Carbon tetrachloride SOL 5 Methyl iodide Sal 5 Chlorobenzene SOL 5 Methyl methacrylate SOL 30 Chloroethane SOL 10 4-Methyl-2-pentanone SOL 50 Chloroform SOL 5 Methylene bromide SOL 5 Chloroprene Sal 20 Methylene chloride SOL 5 1,2-Dibromo-3-chloropropane SOL 20 Naphthalene SOL 5 Dibromochloromethane SOL 5 Propionitrile Sal 150 1,2-Dibromoethane SOL 5 Styrene SOL 5 trans-1,4-Dichloro-2-butene SOL 10 1,1,1,2-Tetrachloroethane SOL 5 1,2-Dichlorobenzene SOL 5 1,1,2,2-Tetrachloroethane SOL 5 1.3-Dichlorobenzene Sal 5 Tetrachloroethene Sal 5 1A-Dichlorobenzene SOL 5 Toluene Sal 5 Dich lorodifluoromethane SOL 5 1,1 ,1-Trichloroethane SOL 5 1,1-Dichloroethane 21 5 1,1,2-Trichloroethane SOL 5 1.2-Dichloroethane SOL 5 Trichloroethene SOL 5 1,1-Dichloroethene SOL 5 Trichlorofluoromethane 97 5 cis-1,2-Dichloroethene 14 5 1,2,3-Trichloropropane SOL 5 trans-1,2-Dichloroethene SOL 5 Vinyl acetate SOL 50 1,2-Dichloropropane SOL 5 Vinyl chloride Sal 2 1,3-Dichloropropane SOL 5 m & p-Xylenes Sal 10
- 2,2-Dichloropropane SOL 15 o-Xylene Sal 5
,,1-Dichloropropene SOL 5 eOL =Below Quanlilation Lillit J =Less than Ouantilation lina. Approximate Value POL =Practical Ouantilation lima
IA CL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40~9:--1~4:"':'4~4----------------~30~3~9~Am:--w-::lI:-er-:R::"o-a-:d-."'::S:-u~ite-1':"':0~0:-*-::A~t1a-n"':'ta-,~G~A~30~3~6~0-Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell v.o. (5030B/8260B)
- Appendix II Sample 10: GWC-15/MW-15 Matrix: Water Date Sampled: 12117/2003 Date Extracted:
Date Analyzed: 12/29/2003 ACL Sample #: 210463 Units: IJg/L Analyst: RP Analyte Result PQL Analvte Result PQL Acetone Sal 100 cis-1,3-Dichloropropene Sal 5 Acetonitrile Sal 100 trans-1,3-Dichloropropene Sal 5 Acrolein Sal 100 Ethyl methacrylate Sal 10 Acrylonitrile Sal 50 Ethylbenzene Sal 5 Allyl chloride Sal 10 2-Hexanone Sal 50 Senzene Sal 5 Isobutyl alcohol Sal 50
'omochloromethane Sal 5 Methacrylonitrile Sal 100 ,omodichloromethane Sal 5 Methyl bromide Sal 10 Sromoform Sal 5 Methyl chloride Sal 10 Carbon disulfide Sal 5 Methyl ethyl ketone Sal 100 Carbon tetrachloride Sal 5 Methyl iodide Sal 5 Chlorobenzene Sal 5 Methyl methacrylate Sal 30 Chloroethane Sal 10 4-Methyl-2-pentanone Sal 50 Chloroform Sal 5 Methylene bromide Sal 5 Chloroprene Sal 20 Methylene chloride Sal 5 1,2-Dibromo-3-chloropropane Sal 20 Naphthalene Sal 5 Dibromochloromethane Sal 5 Propionitrile Sal 150 1,2-Dibromoethane Sal 5 Styrene Sal 5 trans-1,4-Dichloro-2-butene eOl 10 1,1 ,1,2-Tetrachloroethane Sal 5 1,2-Dichlorobenzene Sal 5 1,1 ,2,2-Tetrachloroethane Sal 5 1,3-Dichlorobenzene Sal 5 Tetrachloroethene Sal 5 1A-Dichlorobenzene Sal 5 Toluene Sal 5 Dichlorodifluoromethane Sal 5 1,1,1-Trichloroethane Sal 5 1,1-Dichloroethane Sal 5 1,1 ,2-Trichloroethane Sal 5 1,2-Dichloroethane Sal 5 Trichloroethene Sal 5 1,1-Dichloroethene Sal 5 Trichlorofluoromethane Sal 5 cis-1,2-Dichloroethene Sal 5 1,2,3-Trichloropropane Sal 5 trans-1,2-Dichloroethene Sal 5 Vinyl acetate Sal 50 1,2-Dichloropropane Sal 5 Vinyl chloride Sal 2 1,3-Dichloropropane Sal 5 m & p-Xylenes Sal 10 .2 ,2-Dichloropropane Sal 15 o-Xylene Sal 5 l-Dichloropropene Sal 5 BOl =Below Ouantitalion lim~
J '" less than Ouantilalion limit. Approximate Value POL =Practical Ouantitation Limit
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 ADVANCED CHEMISTRY LABS, INC. 3039 Amwiler Road* Suite 100
- Atlanta. GA 30360 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistryfabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACl Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12119/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell v.o. (50308/82608)
- Appendix II Sample 10: GWC-14/MW-14 Matrix: Water Date Sampled: 12117/2003 Date Extracted:
Date Analyzed: 12/30/2003 ACl Sample #: 210473 Units: IJg/L Analyst: RP Analvte Result PQl Analvte Result PQl Acetone Sal 100 cis-1,3-Dichloropropene Sal 5 Acetonitrile Sal 100 trans-1,3-Dichloropropene Sal 5 Acrolein Sal 100 Ethyl methacrylate Sal 10 Acrylonitrile Sal 50 Ethylbenzene Sal 5 Allyl chloride Sal 10 2-Hexanone Sal 50 Senzene Sal 5 Isobutyl alcohol Sal 50
)mochloromelhane Sal 5 Methacrylonitrile Sal 100
_,omodichloromethane Sal 5 Methyl bromide Sal 10 Sromoform Sal 5 Methyl chloride Sal 10 Carbon disulfide Sal 5 Methyl elhyl ketone Sal 100 Carbon tetrachloride Sal 5 Methyl iodide Sal 5 Chlorobenzene 19 5 Methyl methacrylate Sal 30 Chloroethane Sal 10 4-Methyl-2-pentanone Sal 50 Chloroform Sal 5 Methylene bromide Sal 5 Chloroprene Sal 20 Methylene chloride Sal 5 1,2-Dibromo-3-chloropropane Sal 20 Naphthalene Sal 5 Dibromochloromethane Sal 5 Propionitrile Sal 150 1,2-Dibromoethane Sal 5 Styrene Sal 5 trans-1 ,4-Dichloro-2-butene Sal 10 1,1,1,2-Tetrachloroethane Sal 5 1,2-Dichlorobenzene Sal 5 1,1,2,2-Tetrachloroethane Sal 5 1,3-Dichlorobenzene Sal 5 Tetrachloroethene Sal 5 1,4-Dichlorobenzene 33 5 Toluene Sal 5 Dichlorodifluoromethane Sal 5 1,1,1-Trichloroethane Sal 5 1,1-Dichloroethane 10 5 1,1,2-Trichloroethane Sal 5 1,2-Dichloroethane Sal 5 Trichloroethene Sal 5 1,1-Dichloroethene Sal 5 Trichlorofluoromethane Sal 5 cis-1,2-Dichloroethene 17 5 1,2,3-Trichloropropane Sal 5 trans-1,2-Dichloroethene Sal 5 Vinyl acetate Sal 50 1,2-Dichloropropane Sal 5 Vinyl chloride Sal 2 1,3-Dichloropropane Sal 5 m & p-Xylenes Sal 10
-2,2-Dichloropropane Sal 15 o-Xylene 10 5 1-Dichloropropene Sal 5 BOL = Below Ouantitalion Limit J = Less than Ouantilalion Lim~. Approximate Value POL = Practical Ouantilalion Limit
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40~9~-1~4~44-:----------------~3~0~3~9 "'!"A-m-w':"!"'i1e-r"=R~oa-d~*~S~u~ite~1 0~0~*~A~t1a-n"'!"ta-.~G~A-3~0~3~60~ Fax: (770) 409-1844 P.O. Box 88610* Atlanta. GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Acid Extractables (8270C)
- Appendix II Sample 10: GWC-13/MW-13 Matrix: Water Date Sampled: 12/16/2003 Date Extracted: 12/2212003 Date Analyzed: 12/23/2003 ACL Sample #: 210461 Units: ~g/L Analyst: RB An aIvte Result PQL 4-Chloro-3-methylphenol Sal 20 2-Chlorophenol Sal 10 m & p-Cresol Sal 10 o-Cresol Sal 10 2,4-Dichlorophenol Sal 10 2,6-Dichlorophenol Sal 10
"- 4-Dimethylphenol Sal 10
.o-Dinitro-2-methylphenol Sal 50 2,4-Dinitrophenol Sal 50 2-Nitrophenol Sal 10 4-Nitrophenol Sal 50 Pentachlorophenol Sal 50 Phenol Sal 10 2,3,4,6-Tetrachlorophenol Sal 10 2.4,5-Trichlorophenol Sal 10 2,4,6-Trichlorophenol Sal 10 BOL = Below Ouantitalion Limit J = Less than Ouantltatlon Limit. Approximate Value POL =Practical Quanlilalion Limit
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 ADVANCED CHEMISTRY LABS, INC. 3039 AmwiJer Road, Suite 100
- Atlanta, GA 30360 P.O. Box 88610' Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Base Neutral Extractables (8270C)
- Appendix II Sample 10: GWC-13/MW-13 Matrix: Water Date Sampled: 12/1612003 Date Extracted: 12/22/2003 Date Analyzed: 12/23/2003 ACL Sample #: 210461 Units: IJg/L Analyst: RB Analvte Result PQL Analyte Result PQL Acenaphthene SOL 10 Diethyl phthalate Sal 10 Acenaphthylene SOL 10 Dimethoate Sal 10 Acetophenone SOL 10 Dimethyl phthalate Sal 10 2-Acetylaminofluorene Sal 20 p-(Dimethylam ina)azobenzene Sal 10 4-Aminobiphenyl Sal 20 7,12-Dimethylbenz(a)anthracene Sal 10 Anthracene SOL 10 3,3'-Dimethylbenzidine Sal 10
-- 'nzo(a)anthracene Sal 10 m-Dinitrobenzene Sal 20 A~nzo(a )pyrene SOL 10 2,4-Dinitrotoluene Sal 10 Senzo(b)fluoranthene SOL 10 2,6-Dinitrotoluene Sal 10 Senzo(g,h ,i)perylene Sal 10 Diphenylamine Sal 10 Senzo(k)fluoranthene SOL 10 Disulfoton SOL 10 Senzyl alcohol SOL 20 Ethyl methanesulfonate SOL 20 Sis(2-chloroethoxy)methane SOL 10 Famphur SOL 20 Sis(2-chloroethyl)ether SOL 10 Fluoranthene SOL 10 Sis(2-chloroisopropyl)ether SOL 10 Fluorene SOL 10 Sis(2-ethylhexyl)phthalate SOL 10 Hexachlorobenzene SOL 10 4-Sromophenyl phenyl ether SOL 10 Hexach lorobutadiene SOL 10 Sutyl benzyl phthalate SOL 10 Hexach lorocyclopentadiene SOL 10 p-Chloroaniline SOL 20 Hexachloroethane SOL 10 Chlorobenzilate SOL 10 Hexachloropropene SOL 10 2-Chloronaphthalene SOL 10 Indeno(1,2,3-cd)pyrene SOL 10 4-Chlorophenyl phenyl ether SOL 10 Isodrin SOL 20 Chrysene SOL 10 Isophorone SOL 10 Di-n-butyl phthalate SOL 10 Isosafrole SOL 10 Di-n-octyl phthalate SOL 10 Kepone SOL 20 Diallate SOL 10 Malathion SOL 50 Dibenz(a,h)anthracene SOL 10 Methapyrilene SOL 100 Dibenzofuran SOL 10 Methyl methanesulfonate SOL 10 1,2-Dichlorobenzene SOL 10 Methyl parathion SOL 10 1.3*Dichlorobenzene SOL 10 3-Methylcholanthrene SOL 10 ..j A-Dichlorobenzene SOL 10 2-Methylnaphthalene BOL 10 3'-Dichlorobenzidine SOL 20 Naphthalene Sal 10 BQL =Below Quantilalion Lim~
J =Less than Quanlilation Limit. Approximate Value PQL =Practical Quantilalion Limit
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40~9~-1:-:4~44~--------------~3::":0:-=3':"9 ~A-m-W1':':"'*le-r"=R~oa-d':"".-:S~u":':'ite~10::":0~*-:A":':t1a-n~ta-."=G~A~3::":0:-=3':":60~ Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACl Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Base Neutral Extractables (8270C)
- Appendix II Sample 10: GWC-13/MW-13 Matrix: Water Date Sampled: 12/16/2003 Date Extracted: 12/22/2003 Date Analyzed: 12/23/2003 ACl Sample #: 210461 Units: ",g/L Analyst: RB Analvte Result PQl 1,4-Naphthoquinone Sal 10 1-Naphthylamine Sal 10 2-Naphthylamine Sal 10 5-Nitro-o-toluidine Sal 10 2-Nitroaniline sal 50 3-Nitroaniline Sal 50 "litroaniline Sal 20 lrobenzene sal 10 N-Nitroso-di-n-butylam ine Sal 10 N-Nitrosodiethylamine Sal 20 N-Nitrosodimethylamine BOl 10 N-Nitrosodiphenylamine BOl 10 N-Nitrosodipropylamine BOl 10 N-Nitrosomethylethylamine BOl 10 N-Nitrosopiperidine BOl 20 N-Nitrosopyrrolidine BOl 40 Parathion BOl 20 Pentachlorobenzene Sal 10 Penlachloronitrobenzene Sal 20 Phenacetin BOl 20 Phenanthrene Sal 10 p-Phenylenediamine Bal 10 Phorate BOl 10 Pronamide Sal 10 Pyrene BOl 10 Safrole BOl 10 1,2,4,5-Tetrachlorobenzene BOl 10 Thionazin Sal 20 0- Toluidine sal 10 1,2,4-Trichlorobenzene Sal 10
..2,0,0-Triethyl phosphorothioate Sal 50
'3,5-Trinitrobenzene BOl 10 BOL " Below Quantilalion Lim~
J " Less than Ouanlilation Lim~. Approximate Value POL" Practical Ouanlilalion Limit
Phone: (770) I IACL 40~9~.1~4"':"44~--------------~3~0~3~9"':"A-m-w~i1e-r~R~oa-d':'"*~S~u~it-e ADVANCED CHEMISTRY LABS, INC.
~10~0~*~A~tl-an~ta-,~G~A-3~0~3~60~
Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Acid Extractables (8270C)
- Appendix II Sample 10: GWC-13/MW-13-(Dupe) Matrix: Water Date Sampled: 12/16/2003 Date Extracted: 12/22/2003 Date Analyzed: 12/23/2003 ACL Sample #: 210462 Units: IJg/L Analyst: RB Analvte Result PQL 4-Chloro-3-methylphenol Sal 20 2-Chlorophenol Sal 10 m & p-Cresol Sal 10 o-Cresol Sal 10 2,4-Dichlorophenol Sal 10 2,6-Dichlorophenol Sal 10
-0 4-Dimethylphenol Sal 10 3-Dinitro-2-methylphenol Sal 50 2,4-Dinitrophenol Sal 50 2-Nitrophenol Sal 10 4-Nitrophenol Sal 50 Pentachlorophenol Sal 50 Phenol Sal 10 2,3,4,6-Tetrachlorophenol Sal 10 2,4,5-Trichlorophenol Sal 10 2,4,6-Trichlorophenol Sal 10 BOl = Below Quanlilallon limit J =less than Ouanlilalion liml. Approximate Value POL = Practical Ouantitalion limit
IA CL 1~~ Phone: (770) 409-1444 Fax: (770) 409-1844 A_D_Jl:_~_N~C~'E~D~C_'H~E~'M~L~S_TR~Y_L_A_B~S~,l......N......C_. 3039 Amwiler Road, Suite 100' Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant VogUe 1258 Concord Rd. ACl Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Base Neutral Extractables (8270C)
- Appendix II Sample 10: GWC-13/MW-13-(Dupe) Matrix: Water Date Sampled: 12/16/2003 Date Extracted: 12/22/2003 Date Analyzed: 12/23/2003 ACL Sample #: 210462 Units: IJg/l Analyst: RB Analvte Result PQl Analvte Result Pgl Acenaphthene BOl 10 Diethyl phthalate BOl 10 Acenaphthylene BOl 10 Dimethoate BOl 10 Acetophenone BOl 10 Dimethyl phthalate BOl 10 2-Acetylaminofluorene Sal 20 p-(Dimethylamino)azobenzene BOl 10 4-Aminobiphenyl BOl 20 7,12-Dimethylbenz(a)anthracene BOl 10 Anthracene BOl 10 3,3'-Dimethylbenzidine BOl 10
~. --nzo(a)anthracene BOl 10 m-Dinitrobenzene BOl 20 I1zo(a)pyrene BOl 10 2,4-Dinitrotoluene BOl 10 Benzo(b)f1uoranthene BOl 10 2,6-Dinitrotoluene BOl 10 Benzo(g ,h ,i)peryJene BOl 10 Diphenylamine BOl 10 Benzo(k)f1uoranthene BOl 10 Disulfoton BOl 10 Benzyl alcohol Sal 20 Ethyl methanesulfonate BOl 20 Bis(2-ehloroethoxy)methane BOl 10 Famphur BOl 20 Bis(2-ehloroethyl)ether BOl 10 Fluoranthene BOl 10 Bis(2-chloroisopropyl)ether BOl 10 Fluorene BOl 10 Bis(2-ethylhexyl)phthalate BOl 10 Hexachlorobenzene BOl 10 4-Bromophenyl phenyl ether BOl 10 Hexachlorobutadiene BOl 10 Butyl benzyl phthalate BOl 10 Hexachlorocyclopentadiene BOl 10 p-Chloroaniline BOl 20 Hexachloroethane BOl 10 Chlorobenzilate BOl 10 Hexachloropropene BOl 10 2-Chloronaphthalene BOl 10 Indeno(1,2,3-cd)pyrene BOl 10 4-ChlorophenyJ phenyl ether BOl 10 Isodrin Sal 20 Chrysene BOl 10 Isophorone BOl 10 Di-n-butyl phthalate BOl 10 Isosafrole BOl 10 Di-n-octyl phthalate BOl 10 Kepone BOl 20 Diallate BOl 10 Malathion BOl 50 Dibenz(a,h)anthracene BOl 10 Methapyrilene BOl 100 Dibenzofuran BOl 10 Methyl methanesulfonate BOl 10 1,2-Dichlorobenzene BOl 10 Methyl parathion Sal 10 1,3-Dichlorobenzene BOl 10 3-Methylcholanthrene BOl 10 .!,4-Dichlorobenzene BOl 10 2-Methylnaphthalene BOl 10 "-Dichlorobenzidine BOl 20 Naphthalene BOl 10 BQL =Below Quantilalion Limit J =Less than Quantitation Lim~. Approximate Value PQL =Practical Quanlilalion Lim~
IACL I ADVANCED CHEMISTR Y LABS, INC. Phone: (770) 40~9~-1~4:-:'4~4---------------~30~3~9~A-m-w~i1e-r"=R~o-ad~ .*~S~u~it-e""!"10~O~.-A~t1~an-ta-.~G~A~30~3 Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACl Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Base Neutral Extractables (8270C)
- Appendix II Sample 10: GWC-13/MW-13-(Dupe) Matrix: Water Date Sampled: 12/16/2003 Date Extracted: 12/2212003 Date Analyzed: 12/23/2003 ACl Sample #: 210462 Units: IJg/L Analyst: RB Analvte Result PQl 1A-Naphthoquinone Sal 10 1-Naphthylamine Sal 10 2-Naphthylamine Sal 10 5-Nitro-o-toluidine Sal 10 2-Nitroaniline Sal 50 3-Nitroaniline Sal 50
. ~ Nitroaniline Sal 20 Lrobenzene Sal 10 N-Nitroso-di-n-butylamine Sal 10 N-Nitrosodiethylamine Sal 20 N-Nitrosodimethylamine Sal 10 N-Nitrosodiphenylamine Sal 10 N-Nitrosodipropylamine Sal 10 N-Nitrosomethylethylamine Sal 10 N-Nitrosopiperidine Sal 20 N-Nitrosopyrrolldine Sal 40 Parathion Sal 20 Pentachlorobenzene Sal 10 Pentachloronitrobenzene Sal 20 Phenacetin Sal 20 Phenanthrene Sal 10 p-Phenylenediamine Sal 10 Phorate Sal 10 Pronamide Sal 10 Pyrene Sal 10 Safrole Sal 10 1,2A,5-Tetrachlorobenzene Sal 10 Thionazin Sal 20 o-Toluidine SOL 10 1,2,4-Trichlorobenzene SOL 10 2,o,o-Triethyl phosphorothioate SOL 50 3,5-Trinitrobenzene SOL 10 BOL = Below Ouanlitalion Lima J = Less than Quantitation Limit Approximate Value POL = Practical QuantllalJon Linll
IACL I Phone: (770) 409-1444 Fax: (770) 409*1844 ADVANCED CHEMISTRY LABS, INC. 3039 Amwiler Road' Suite 100* Atlanta. GA 30360 P.O. Box 88610
- Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACl Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Acid Extractables (8270C)
- Appendix II Sample 10: GWC-15/MW-15 Matrix: Water Date Sampled: 12/17/2003 Date Extracted: 12/22/2003 Date Analyzed: 12/23/2003 ACl Sample #: 210463 Units: ~g/L Analyst: RB Analvte Result Pgl 4-Chloro-3-methylphenol BOl 20 2-Chlorophenol BOl 10 m & p-Cresol BOl 10 o-Cresol Sal 10 2.4-0ichlorophenol BOl 10 2,6-0ichlorophenol BOl 10 1-0imethylphenol BOl 10
,d-Oinitro-2-methylphenol BOl 50 2,4-0initrophenol SOL 50 2-Nitrophenol BOl 10 4-Nitrophenol BOl 50 Pentachlorophenol BOl 50 Phenol BOl 10 2,3.4,6-Tetrachlorophenol Sal 10 2.4,5-Trichlorophenol BOl 10 2,4,6-Trichlorophenol BOl 10 BOl = Below Ouantilalion limit J = less than Ouantilation lmil. Approxmale Value POL = Practical Ouantilalion lim~
IACL I ADVANCEDCHEMISTRYLABS,INC Phone: (770) 40~9:--1:-:4~44-:----------------~3:":0:":'3':"9 "':"A-m-W1::-'le-r-=R~oa-d':""~S~u~ite~100~'""'!A-'t1-an~ta-,~G~A-3~0:":'3~60~ Fax: (770) 409-1844 P.O. Box 88610' Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna. GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell
IA CL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40~9~-1:-::4~44~----------------:3~0~39~Am-w~i1e-r'=R~oa-d~'-:S:-u~ite~10~0~'-:A~t1a-n~ta-, "'.:G~A~3~0~3~60~ Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: ac/@acl-Iabs.net www.advancedchemistryJabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACl Project #: 44014 Smyrna. GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Base Neutral Extractables (8270C) - Appendix II Sample 10: GWC-15/MW-15 Matrix: Water Date Sampled: 12117/2003 Date Extracted: 12/22/2003 Date Analyzed: 12/23/2003 ACl Sample #: 210463 Units: IJg/L Analyst: RB Analyte Result PQl 1A-Naphthoquinone sal 10 1-Naphthylamine sal 10 2-Naphthylamine sal 10 5-Nitro-o-toluidine sal 10 2-Nitroaniline sal 50 3-Nitroaniline sal 50 "Jitroaniline sal 20
.*lrobenzene sal 10 N-Nitroso-di-n-butylamine sal 10 N-Nitrosodiethylamine sal 20 N-Nitrosodimethylamine sal 10 N-Nitrosodiphenylamine sal 10 N-Nitrosodipropylamine sal 10 N-Nitrosomethylethylamine sal 10 N-Nitrosopiperidine sal 20 N-Nitrosopyrrolidine sal 40 Parathion sal 20 Pentachlorobenzene sal 10 Pentachloronitrobenzene sal 20 Phenacetin sal 20 Phenanthrene sal 10 p-Phenylenedlamine sal 10 Phorate sal 10 Pronamide sal 10 Pyrene sal 10 Safrole sal 10 1,2,4,5-Tetrachlorobenzene sal 10 Thionazin sal 20 0- Toluidine sal 10 1,2,4-Trichlorobenzene sal 10
-0.0.0- Triethyl phosphorothioate sal 50 3,5-Trinitrobenzene sal 10 BOl = Below Ouantilalion limit J = less than Ouantilalion limit, Approximate Value POL =Practical Ouantilalion Urnit
IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 ADVANCED CHEMISTRY LABS, INC. 3039 Amwiler Road* Suite 100* Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Pesticides/PCBs (8081A18082)
- Appendix II Sample 10: GWC-13/MW-13 Matrix: Water Date Sampled: 12/1612003 Date Extracted: 12/22/2003 Date Analyzed: 12/29/2003 ACl Sample #: 210461 Units: 1J9/L Analyst: SS Analvte Result PQl Aldrin SOL 0.05 Arochlor-1016 SOL 0.50 Arochlor-1221 SOL 0.50 Arochlor-1232 SOL 0.50 Arochlor-1242 SOL 0.50 Arochlor-1248 SOL 0.50
\rochlor-1254 SOL 0.50 Arochlor-1260 SOL 0.50 a-SHC SOL 0.05 b-SHC SOL 0.05 d-SHC SOL 0.05 g-SHC SOL 0.05 Chlordane SOL 0.10 4,4'-DDD SOL 0.05 4,4'-DDE SOL 0.05 4,4'-DDT SOL 0.05 Dieldrin SOL 0.05 Endosulfan I SOL 0.05 Endosulfan II SOL 0.05 Endosulfan sulfate SOL 0.05 Endrin SOL 0.05 Endrin aldehyde SOL 0.05 Heptachlor SOL 0.05 Heptachlor epoxide SOL 0.05 Methoxychlor SOL 0.05 Toxaphene SOL 2.00 BOl =Below Quanlitation limit J = less than Ouanlllation limit. Approximate Value POL = Practical Quantialion Limi
IA CL 1~~ Phone: (nO) 409-1444 Fax: (770) 409-1844 A_D_~_~_N~C=-=-'E~'D-:,:C~'ll~"E-:-M~1.~S~TR~Y~L-.-A-.-B~S~, l~N~C_. 3039 Amwiler Road* Suite 100* Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACl Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Pesticides/PCBs (8081A18082)* Appendix II Sample 10: GWC-13/MW-13-(Dupe) Matrix: Water Date Sampled: 12/16/2003 Date Extracted: 12/22/2003 Date Analyzed: 12/29/2003 ACl Sample #: 210462 Units: IJg/L Analyst: SS Analvte Result PQl Aldrin Sal 0.05 Arochlor-1016 Sal 0.50 Arochlor-1221 SOL 0.50 Arochlor-1232 SOL 0.50 Arochlor-1242 SOL 0.50 Arochlor-1248 Sal 0.50 - 'ochlor-1254 SOL 0.50
.ochlor-1260 SOL 0.50 a-BHC SOL 0.05 b-BHC SOL 0.05 d-BHC SOL 0.05 g-BHC SOL 0.05 Chlordane SOL 0.10 4,4'-DDD SOL 0.05 4,4'-DDE SOL 0.05 4,4'-DDT SaL 0.05 Dieldrin Sal 0.05 Endosulfan I SOL 0.05 Endosulfan II SOL 0.05 Endosulfan sulfate SOL 0.05 Endrin SaL 0.05 Endrin aldehyde SOL 0.05 Heptachlor SaL 0.05 Heptachlor epoxide SOL 0.05 Methoxychlor SaL 0.05 Toxaphene SOL 2.00 BOL = Below Ouantilalion Linit =
J Less lhan Ouanlilalion Limit, Approximate Value
=
POL Practical Quanlitation Limit
Phone: (770) Fax: (770) 409-1844 I IACL 40~9~-1~44~4~---------------:3~03:-:9~A~m-w-::i1:-er-:R~o-ad~. ADVANCED CHEMISTRY LABS, INC. S~u"':':ite~1O:-:O~.~A~tla-n":""ta-. ~G":""A-:3~03~6~0-P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client ProJ #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Pesticides/PCBs (8081A18082). Appendix II Sample 10: GWC-15/MW-15 Matrix: Water Date Sampled: 12/17/2003 Date Extracted: 12/22/2003 Date Analyzed: 12/29/2003 ACL Sample #: 210463 Units: ~g/L Analyst: SS Analvte Result P9L Aldrin SOL 0.05 Arochlor-1016 SOL 0.50 Arochlor-1221 SOL 0.50 Arochlor-1232 SOL 0.50 Arochlor-1242 SOL 0.50 Arochlor-1248 SOL 0.50 - '\rochlor-1254 SOL 0.50
.rochlor-1260 SOL 0.50 a-SHC Sal 0.05 b-SHC Sal 0.05 d-SHC Sal 0.05 g-BHC Sal 0.05 Chlordane Sal 0.10 4,4'-000 SOL 0.05 4,4'-DDE Sal 0.05 4,4'-DDT Sal 0.05 Dieldrin Sal 0.05 Endosulfan I Sal 0.05 Endosulfan II SOL 0.05 Endosulfan sulfate Sal 0.05 Endrin Sal 0.05 Endrin aldehyde Sal 0.05 Heptachlor Sal 0.05 Heptachlor epoxide Sal 0.05 Methoxychlor Sal 0.05 Toxaphene Sal 2.00 BOL :: Below Quanlitatlon Lima J "less than Ouantilation limit, Approximate Value pal:: Practical Quantilatlon limit
Phone: (770) Fax: (770) 409-1844 I IACL 409~-1~4~44~--------------~3~0~39~A~m-W~i1~er~R~O-ad~' ADVANCED CHEMISTRY LABS, INC. S~u~it-e~10~O~.~A~t1a-n~ta-,~G~A~3~03~6~O-P.O. Box 88610' Atlanta, GA 30356 a-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Chlorinated Herbicides (8151A) - Appendix II Sample 10: GWC-13/MW-13 Matrix: Water Date Sampled: 12116/2003 Date Extracted: 12/23/2003 Date Analyzed: 12129/2003 ACL Sample #: 210461 Units: ~g/L Analyst: SS Analyte Result PQL 2,4-0 BQL 1.0 Oinoseb BQL 1.0 2,4,5-TP (Silvex) BQL 1.0 2,4,5-T BQL 1.0 BOl = Below Quantitation limit J =less than Quantilalion limit, APD/llxlmate Value
=
POL Praclical Ouanlilalion limit
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40~9~-1~4~44O:----------------~3~0~39~A':"'m-WJ~'I~er~R~o-a~d-. ~Su~it~e~10~0~.~A~t1-an~ta-,~G~A~3~0"!"36~0-Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 a-mail: acl@acl-Iabs.nat www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Chlorinated Herbicides (8151A)
- Appendix II Sample 10: GWC-13/MW-13-(Dupe) Matrix: Water Date Sampled: 12116/2003 Date Extracted: 12/23/2003 Date Analyzed: 1212912003 ACL Sample #: 210462 Units: ~g/L Analyst: . SS Analvte Result PQL 2,4-0 Sal 1.0 Oinoseb Sal 1.0 2,4,5-TP (Silvex) Sal 1.0 2.4,5-T Sal 1.0 BOl = Below Quantitalion limit J =less than Ouantitslion limit, Approximate Value POL = Practical Quantitalion limit
IA CL 1~ Phone: (770) 409-1444 Fax: (770) 409-1844 A_D_~_:4_N~C~'E~V~C~'H~'E__M~l~'S__TR~Y__L-.-A_B" " ,!,S~, L~'N......C_. 3039 Amwiler Road* Suite 100* Atlanta. GA 30360 P.O. Box 88610* Atlanta. GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACl Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Chlorinated Herbicides (8151 A)
- Appendix II Sample 10: GWC-15/MW-15 Matrix: Water Date Sampled: 12/17/2003 Date Extracted: 12/23/2003 Date Analyzed: 12/29/2003 ACl Sample #: 210463 Units: ~g/L Analyst: SS Analvte Result PQl 2,4-D Sal 1.0 Dinoseb Sal 1.0 2,4,5-TP (Silvex) Sal 1.0 2,4,5-T Sal 1.0 BOL = Below Quanlilation Linil J = Less than Ouanlilatlon Limit, ADO/Oxlmale Value
=
POL Practical Ouanlilation lim~
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40:":9~-1~4~44~--------------""'::3~0~39~A~m-W1-::'I:-er""'::R~o-a"":"d -.S~u-::it-e"":"10~0:-*""'::A~t1a-n~ta-.~G~A""'::3~0~36~0-Fax: (770) 409-1844 P.O. Box 88610* Atlanta. GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Miscellaneous Organics (504.1)
- Appendix II Sample 10: GWC-13/MW-13 Matrix: Water Date Sampled: 12/16/2003 Date Extracted: 12/23/2003 Date Analyzed: 12/30/2003 ACL Sample #: 210461 Units: ~g/L Analyst: SS Analvte Result PgL 1,2-Dibromo-3-chloropropane SOL 0.20 1,2-Dibromoethane SOL 0.05 BOl = Below Quantilation limit J =less than Quanlilatlon linil APP/'Oxlmate Value pal = Practical Quanlilation linR
IACL i Phone: (770) 409*1444 Fax: (770) 409-1844 ADVANCED CHEMISTRY LABS, INC. 3039 Amwiler Road* Suite 100. Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Miscellaneous Organics (504.1) - Appendix II Sample ID: GWC-13/MW-13-(Dupe) Matrix: Water Date Sampled: 12116/2003 Date Extracted: 12123/2003 Date Analyzed: 12/30/2003 ACL Sample #: 210462 Units: IJg/L Analyst: SS An aIvte Result PQL 1,2-Dibromo-3-chloropropane Sal 0.20 1,2-Dibromoethane Sal 0.05 BQL = Below Quanlilation Limit J = Less than Quanlilalion Limlt. Approxinate Value PaL = Pradical Quanlilalion Lilli
Phone: (770) Fax: (770) 409-1844 I IACL 40~9--1~444~--------------~3~03~9"":A-m-W1~*le-r~R-oa~d~.-:S~ui~te"":1~00~*~A~t1~an~ta-.-:G~A~3~03~6!"!'0-ADVANCED CHEMISTRY LABS, INC. P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACl Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12119/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Miscellaneous Organics (504.1)
- Appendix II Sample 10: GWC-15/MW-15 Matrix: Water Date Sampled: 12/17/2003 Date Extracted: 12123/2003 Date Analyzed: 12/30/2003 ACl Sample #: 210463 Units: ~g/L Analyst: SS Analvte Result Pgl 1.2-Dibromo-3-chloropropane aOL 0.20 1,2-Dibromoethane aOL 0.05 BOL :: Below Quanlitatlon Limit J = less than Quantilation Limil. Approximate Value
=
POL Practical Quanlitalion limit
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40:":9~.1~44~4~---------------::3~03~9:-Am~W1~*I:-er""':R:-o-ad~. S=-u~it-e~100~*""':A":':'tla-nt~a-, '=GA~3~0~36:":0-Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemlstrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna. GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Miscellaneous Organics (504.1) - Appendix II Sample 10: GWC-S/MW-5 Matrix: Water Date Sampled: 1211612003 Date Extracted: 12123/2003 Date Analyzed: 01/0212004 ACL Sample #: 210469 Units: ~g/L Analyst: SS Analvte Result 'PQL 1.2-Dibromo-3-chloropropane BOl 0.20 1.2-Dibromoethane BOl 0.05
=
BOl Below Quanlilalion limit J =less than Ouanlitation llmK. Approximate Value
=
pal Practical Quanlilation limit
--_._------------------ -~.~_._- -
IACL I ADVANCED CHEMISTRY LABS, INC Phone: (770) 409~.1~4~44~--------------~3~0~39~A~m-W1~*~le~r R::"o-a""':'d-*~Su""':'it~e""':'1~00~*~At~I~an-ta-,~G~A-3~0~36~0~ Fax: (770) 409*1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACl Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Miscellaneous Organics (504.1)
- Appendix II Sample 10: GWB-6/MW-6 Matrix: Water Date Sampled: 12/17/2003 Date Extracted: 12/23/2003 Date Analyzed: 01/02/2004 ACl Sample #: 210470 Units: ~g/L Analyst: SS Analvte Result PQl 1.2-Dibromo-3-chloropropane Sal 0.20 1,2-Dibromoethane BOl 0.05 BOL =Below Quantilallon Limit J = Less than Ouantilalion Limit. APIllOxmate Value POL =Practical Ouantilation Limit
IACL I ADVANCED CHEMISTRYLABS,INC Phone: (770) 40~9-.1~4~44~--------------~3~03~9~A~m-W1~*J-er~Ro~ad~'~S~u~it-e ~10~0~'~A~tJa-n-ta-, ~GA~3~03~6~0-Fax: (770) 409-1844 P.O. Box 88610' Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant VogUe 1258 Concord Rd. ACl Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12119/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Miscellaneous Organics (504.1)
- Appendix II Sample 10: GWA-7/MW-7 Matrix: Water Date Sampled: 12116/2003 Date Extracted: 12/23/2003 Date Analyzed: 01/0212004 ACl Sample #: 210471 Units: ~g/L Analyst: SS Analvte Result Pgl 1,2-Dibromo-3-chloropropane SOL 0.20 1.2-Dibromoethane SOL 0.05 BQL =Below Quanlitallon llmJl J = lest than Quantilalion UmII. Aplll'Oxinale Value POL = Practical auantitallon limit
Phone: (770) Fax: (770) 409-1844 I IACL 40~9~-1!""!'4~44~-------------~3~03~9-:Am-w~ile-r~R-Oa~d~.~S~ui~te-:1~OO~.~A~t1-an~ta-.~G"!"A-:3"!"03~6"!"0-ADVANCED CHEMISTRY LABS, INC. P.O. Box 88610* AUanta, GA 30356 e-mail: acl@act-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Miscellaneous Organics (504.1)
- Appendix II Sample 10: GWC-14/MW-14 Matrix: Water Date Sampled: 12/17/2003 Date Extracted: 12123/2003 Date Analyzed: 01/0212004 ACL Sample #: 210473 Units: ~g/L Analyst: SS Analvte Result PQL 1,2-Dibromo-3-chloropropane Sal 0.20 1,2-Dibromoethane sal 0.05 BOl =Below Quantllalion limit J " less than Ouantlatlon lim" AllIlIOxlmate Value POL =Praelicat QuantUtion limit
Phone: (770) Fax: (770) 409*1844 I IACL 40~9~.1~444~--------------~3~03~9~A:-m-w-::i1:-er-:R~o-ad~. ADVANCED CHEMISTRY LABS, INC. S~u~it-e~10~0:-."":'A":":'t1a-n~ta-. ~G":"'A-:3~03~6~0-P.O. Box 88610* Atlanta. GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna. GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
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Mr. Mark Mitchell Appendix II Metals (6010B/7470A/7841) Sample 10: GWC-13/MW-13 Matrix: Water Date Sampled: 12/16/2003 Date Extracted: Date Analyzed: 12/30/2003 ACL Sample #: 210461 Units: mg/L Analyst: SW/AD/JR Analyte Result PQL Antimony BOl 0.006 Arsenic BOl 0.010 Barium 0.033 0.020 Beryllium BOl 0.004 Cadmium BOl 0.005 Chromium BOl 0.020
- ~obalt SOL 0.050
';opper SOL 0.020 lead SOL 0.010 Mercury SOL 0.0005 Nickel SOL 0.020 Selenium BOl 0.040 Silver BOl 0.010 Thallium SOL 0.002 Tin SOL 0.025 Vanadium SOL 0.050 Zinc BOl 0.020 BOl = Below QuanlJlalion Unit J = Less lhan Quanlilallon Limit, Approximate Value POL =PracIIcal Quantilalion limit
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40~9~.1:-:4":"44~---------------=:3~03::':9:-:A:-m-w~i1-er-=:R~o-ad"':"".~S:-u~it-e ~1OO:-:-.~A~tla-n"':""ta-, ~GA~30~3~6~0-Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Appendix II Metals (6010B/7470A/7841) Sample 10: GWC-13/MW-13-(Dupe} Matrix: Water Date Sampled: 12116/2003 Date Extracted: Date Analyzed: 12/30/2003 ACL Sample #: 210462 Units: mg/L Analyst: SW/AD/JR Analvte Result PQL Antimony BOl 0.006 Arsenic BOl 0.010 Barium 0.032 0.020 Beryllium BOl 0.004 Cadmium BOl 0.005 Chromium BOl 0.020 ~obalt BOl 0.050
;opper BOl 0.020 lead BOl 0.010 Mercury BOl 0.0005 Nickel BOl 0.020 Selenium BOl 0.040 Silver BOl 0.010 Thallium BOl 0.002 Tin BOl 0.025 Vanadium BOl 0.050 Zinc BOl 0.020 BOl = Below Quantilalion limit J = less than Quanliation linit, Approximate Value pal = Pradical Quanlilalion lim.
IA CL I ADVANCED CHEMISTRY LABS, INC Phone: (770) 40~9~.1:"":'4":"44~---------------::3~03~9~A~m-w-::i1-er-::R~o-ad":"'.~S~u~ite~10~0~*"":'A~tla-n":""ta-. G~A":""-::3~03~6~0-Fax: (770) 409*1844 P.O. Box 88610* Atlanta. GA 30356 e-mail: acl@aci-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
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Mr. Mark Mitchell Appendix I Metals (60108/7841) Sample 10: GWC-5/MW-5 Matrix: Water Date Sampled: 12/16/2003 Date Extracted: Date Analyzed: 12130/2003 ACL Sample #: 210469 Units:. mg/l Analyst: SW/AD Analvte Result PQL Antimony SaL 0.006 Arsenic Sal 0.010 Barium 0.142 0.020 Beryllium Sal 0.004 Cadmium Sal 0.005 Chromium 0.028 0.020
~obalt Sal 0.050
';opper 0.025 0.020 lead Sal 0.010 Nickel Sal 0.020 Selenium Sal 0.040 Silver SOL 0.010 Thallium Sal 0.002 Vanadium Sal 0.050 Zinc 0.032 0.020 BOL " Below Ouanlilation Limit J " Less than Quanlilalion limit. AllPlOxmate Value pal" Practical Ouanlitation Limit
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40~9~.1~4~44~--------------~3:":O~39~A~m-Wl-:'*I:-er~R~o-a"":"d-. S~u~it~e~10~0:-*~A~tla-n"'!"'ta-.~G~A~3:":0~36~0-Fax: (770) 409-1844 P.O. Box 88610' Atlanta. GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Appendix I Metals (60108/7841) Sample 10: GWB-6/MW-6 Matrix: Water Date Sampled: 12/1712003 Date Extracted: Date Analyzed: 12130/2003 ACL Sample #: 210470 Units: mg/L Analyst: SW/AD Analvte Result PQL Antimony Sal 0.006 Arsenic Sal 0.010 Sarium Sal 0.020 Seryllium Sal 0.004 Cadmium Sal 0.005 Chromium Sal 0.020 -'":obalt Sal 0.050
~opper Sal 0.020 lead Sal 0.010 Nickel Sal 0.020 Selenium Sal 0.040 Silver Sal 0.010 Thallium Sal 0.002 Vanadium Sal 0.050 Zinc Sal 0.020 BOL .. Below Quanlilation limit J .. less than Quanlilalion limit. Approximate Value POL" Practical Ouantitalion limit
IA CL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40~9~-1~4~44~--------------~3~03~9~A~m-w~i1~er~R~o-ad-:--* S~u~it-e~10~0~*~A~t1a-n~ta-. ":G~A~3~0~36~0-Fax: (770) 409-1844 P.O. Box 88610* Atlanta. GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna. GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Appendix I Metals (60108/7841) Sample 10: GWA-7/MW-7 Matrix: Water Date Sampled: 12/16/2003 Date Extracted: Date Analyzed: 12/30/2003 ACL Sample #: 210471 Units: mg/L Analyst: SW/AD Analyte Result PQL Antimony Sal 0.006 Arsenic Sal 0.010 Sarium Sal 0.020 Seryllium Sal 0.004 Cadmium Sal 0.005 Chromium Sal 0.020
- 'obalt Sal 0.050 ..;opper Sal 0.020 lead Sal 0.010 Nickel Sal 0.020 Selenium Sal 0.040 Silver Sal 0.010 Thallium Sal 0.002 Vanadium Sal 0.050 Zinc 0.023 0.020 =
SOL Below Quantltallon LIm~ J =Less than Ouantitalion Limit, Approximate Value POL '" Practical Quantilalion LImil
IA CL 1~~ Phone: (770) 409-1444 Fax: (770) 409-1844 A_D_~_:4_N~C~'E~1J~C_'H!!!"""E~M~L_'S_TR~Y~L_A_B""",!,,S~, l~'N~C_. 3039 Amwiler Road* Suite 100* Atlanta. GA 30360 P.O. Box 88610* Atlanta. GA 30356 e-mail: acl@acl-labs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACl Project #: 44014 Smyrna. GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Appendix II Metals (6010B/7470A/7841) Sample 10: GWC-14/MW-14 Matrix: Water Date Sampled: 12/1712003 Date Extracted: Date Analyzed: 12/30/2003 ACl Sample #: 210473 Units: mg/L Analyst: SW/AD/JR Analvte Result PQl Antimony Sal 0.006 Arsenic Sal 0.010 Sarium 0.189 0.020 Seryllium 0.004 0.004 Cadmium 0.011 0.005 Chromium 0.091 0.020
'obalt Sal 0.050 ...opper 0.026 0.020 lead 0.015 0.010 Mercury 0.0100 0.0005 Nickel 0.034 0.020 Selenium Sal 0.040 Silver Sal 0.010 Thallium Sal 0.002 Tin Sal 0.025 Vanadium 0.060 0.050 Zinc 0.127 0.020 BOl =Below Ouanlilalion limil J = less than Ouanlltalion limit. Approxlmate Value POL = Practical Quantitallon linit
IACL I ADVANCEDCHEMISTRYLABS,INC. Phone: (770) 40~9~-1~4~44~--------------~3~0"!"39~A"l'"m-w~i!'"'le-r R!!!""o-a~d-*"!"Su~it-e~1"!"OO~*-A~t1~an-ta-,""!!G~A-3""""'O"'36"0-Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-labs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACl Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
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Mr. Mark Mitchell Appendix II Metals (6010B/7470A/7841) Sample 10: GWC-15/MW-15 Matrix: Water Date Sampled: 12/1712003 Date Extracted: Date Analyzed: 12/30/2003 ACl Sample #: 210463 Units: mg/L Analyst: SW/AD/JR Analvte Result PQl Antimony BOl 0.006 Arsenic BOl 0.010 Barium BOl 0.020 Beryllium BOl 0.004 Cadmium BOl 0.005 Chromium BOl 0.020
~obalt BOl 0.050 ";opper BOl 0.020 lead BOl 0.010 Mercury BOl 0.0005 Nickel BOl 0.020 Selenium BOl 0.040 Silver BOl 0.010 Thallium BOl 0.002 Tin BOl 0.025 Vanadium BOl 0.050 Zinc BOl 0.020 BOl = Below Quantilallon limit =
J less than Ouanlllalion Limit. Approximate Value POL = Practical Ouanfilatlon Limit
Phone: (770) Fax: (770) 409-1844 I IACL 409-~1"'!"44~4~-------------"'"":'30~3::':'9~Am-w~i1e-r"=R-oa""':d:-*~S""':ui~te~1~OO:-*""':At:-=:I-an~ta-.~G~A~3~03~60~ ADVANCED CHEMISTRY LABS, INC. P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client ProJ #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12119/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Date Sample ID ACL# Analvte Matrix Result PQL Y!!!!! Analyzed GWC-13/MW-13 210461 Cyanide (9012A) Water BOL 0.020 mg/L 12123/2003 GWC-13/MW-13 210461 Sulfide (9034) Water BOL 1.0 mg/L 12123/2003 BOL =Below Cluanlilatlon Limit J.= Less than Quantiation Linit. AllllIOximaIe Value
=
POL Practical Quenlilatlon Limit
IA CL 1~~ Phone: (770) 409-1444 Fax: (770) 409-1844 AD_V:_:4_N~C~'E~'D~C_'H~E~MWO"!L~S~TR"!"!,,,Y~L~A_B~S,,!,,,",l""""""N......C_. 3039 Amwiler Road* Suite 100* Atlanta. GA 30360 P.O. Box 88610* Atlanta. GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACl Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Date Sample 10 &..! Analvte Matrix Result PQl Y!!!t! AnalYZed GW C-13/MW-13-(Oa 10462 Cyanide (9012A) Water SOL 0.020 mglL 12/23/2003 GWC-13/MW-13-(Oa10462 Sulfide (9034) Water SOL 1.0 mglL 12/2312003
=
BOL Below Quanllallon Llmll
=
J Less than Quanlllatlon Limit. AllllIOximaIe Value POL '" Practical Quanlilalion Limi
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 409~-1~44~4~-------------~3~03~9~Am~w1"::"le"r"'=R~oa"d:-'=S~uit~e~1~OO~*-A~t1:-'an""':'ta""."'=G~A-:3:O:::0'::":36~O-Fax: (770) 409-1844 P.O. Box 88610
- Atlanta. GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant VogUe 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Date Sample 10 ACL# Analvte Matrix Result PQL Units Analyzed GWC-15/MW-15 210463 Cyanide (9012A) Water SOL 0.020 mg/L 12123/2003 GWC-15/MW-15 210463 Sulfide (9034) Water SOL 1.0 mg/L 12/23/2003 BOl = Below Quanlltatlon llmil J :: less than Quantilalion linll. AllPlOxinale Value PQl =Practical Quanlitation limit
IA CL Phone: mO) 409-1444 Fax: (770) 409-1844 1... -------AD-Jl:-'AN~CE!""!"1J~CH~'E-'M~lS~l:~'R~Y L-AB~S~,~IN~C_. 3039 Amwiler Road* SUite 100
- Atlanta. GA 30360 P.O. Box 88610
- Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date ReceIved: 12119/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Date Sample 10 ~ Analvte Matrix Result P9L Units Analyzed EO-Blank 210464 Cyanide (9012A) Water BOL 0.020 mg/L 12123/2003 EO-Blank 210464 Sulfide (9034) Water BOL 1.0 mglL 12123/2003 eal =BeloW Quanliation limit J =less than Quantllallon Unll. ApproUnale Value PaL =Pradicat auantilalion limit
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 409~*1~44~4:---------------"""':'30~3~9-:Am""'W1':':"*Ie-r ':::'Ro-ad-:-*":Su-:ite~1~OO~*-:A~tla-n"":"'ta-. ":GA~3~03~6~0-Fax: (770) 409*1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna. GA 30080-0000 Date Received: 12119/2003 Date Reported: 01/06/2004
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Mr. Mark Mitchell Date Sample 10 A£U Analvte Matrix Result PQL Units Analyzed GWC-5/MW-5 210469 Mercury (7470A) Water Sal 0.0005 mg/L 12124/2003 Bal = Below Quantllallon Linit J =less IIlan Quanlllallon llml AllOIOxinate Value PaL =Plaetical Quantbllon Limit
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 409~.1!""!'444~--------------~30~3~9""'!!Am-W1~*le-r"=!Ro-a'""'!d~.~S'""'!ui~te""'!!1~00~*'""'!A~t\-an-ta-. "=!G~A""!!3~03~6~0-Fax: (770) 409-1844 P.O. Box 88610* Atlanta. GA 30356 a-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACl Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12119/2003 Date Reported: 01/06/2004
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Mr. Mark Mitchell Date Sample 10 ACl# Analvte Matrix Result PQl Units Analyzed GWS-6/MW-6 210470 Mercury (7470A) Water Sal 0.0005 mg/L 12124/2003 8Ql = Below Quanlitalion limil J = less !han Quantitalion lmil, AllI)IOJlinaIe Value
=
POL PradIcaI QuantiIalion lilllll
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 409-~1~44~4:-----------------::'30~3::o::'9'"":'Am-W1~'le-r '='Ro-a-'d-*~Su-'ite~1':":OO~*-'A~tla-n~ta-. '='GA~3~03~6~0-Fax: (770) 409-1844 P.O. Box 88610* AUanta. GA 30356 e-mail: aci@acI-labs.net www.advancedchemistrylabs.com Client: Genesis Project Client ProJ #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received; 12/19/2003 Date Reported: 01/0612004
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Mr. Mark Mitchell Date Sample ID ACL# Analvte Matrix Result PQL Units Analyzed GWA-7/MW-7 210471 Mercury (7470A) Water BOL 0.0005 mg/L 12/24/2003 Bel =Below Quantbtion linI J .. less than Quardatlon Un" AiJIlloxinale Value PQl .. Practical Quantllalion limit
LABORATORY QA/QC RESULTS IACL I Phone: (770) 409-1444 Fax: (770) 409-1844 ADVANCED CHEMISTRY LABS, INC. 3039 Amwiler Road* Suite 100* Atlanta, GA 30360 P.O. Box 88610* Atlanta. GA 30356 e-mail;acl@acJ-labs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell v.o. (5030B/8260B)
- Appendix II Sample 10: EO-Blank Matrix: Water Date Sampled: 12/17/2003 Date Extracted:
Date Analyzed: 12/30/2003 ACL Sample #: 210464 Units: IJg/l Analyst: RP Analyte Result PQL Analyte Result PQL Acetone Sal 100 cis-1,3-Dichloropropene Sal 5 Acetonitrile Sal 100 trans-1.3-Dichloropropene Sal 5 Acrolein Sal 100 Ethyl methacrylate Sal 10 Acrylonitrile Sal 50 Ethylbenzene Sal 5 Allyl chloride Sal 10 2-Hexanone Sal 50 Senzene Sal 5 Isobutyl alcohol Sal 50
- 'omochloromethane Sal 5 Methacrylonitrile Sal 100 .Jromodichloromethane Sal 5 Methyl bromide Sal 10 Sromoform Sal 5 Methyl chloride Sal 10 Carbon disulfide Sal 5 Methyl ethyl ketone Sal 100 Carbon tetrachloride Sal 5 Methyl iodide Sal 5 Chlorobenzene Sal 5 Methyl methacrylate Sal 30 Chloroethane Sal 10 4-Methyl-2-pentanone Sal 50 Chloroform Sal 5 Methylene bromide Sal 5 Chloroprene Sal 20 Methylene chloride Sal 5 1.2-Dibromo-3-chloropropane Sal 20 Naphthalene Sal 5 Dibromochloromethane Sal 5 Propionitrile Sal 150 1,2-Dibromoethane Sal 5 Styrene Sal 5 trans-1,4-Dichloro-2-butene Sal 10 1,1,1,2-Tetrachloroethane Sal 5 1,2-Dichlorobenzene Sal 5 1,1,2,2-Tetrachloroethane Sal 5 1,3-Dichlorobenzene sal 5 Tetrachloroethene Sal 5 1A-Dichlorobenzene Sal 5 Toluene Sal 5 Dichlorodifluoromethane sal 5 1,1.1-Trichloroethane Sal 5 1,1-Dichloroethane Sal 5 1,1.2-Trichloroethane Sal 5 1,2-Dichloroethane sal 5 Trichloroethene sal 5 1,1-Dichloroethene Sal 5 Trichlorofluoromethane Sal 5 cis-1,2-Dichloroethene Sal 5 1,2,3-Trichloropropane Sal 5 trans-1.2-Dichloroethene Sal 5 Vinyl acetate Sal 50 1,2-Dichloropropane sal 5 Vinyl chloride Sal 2 1,3-Dichloropropane Sal 5 m & p-Xylenes sal 10 ..2,2-Dichloropropane sal 15 a-Xylene Sal 5 ,1-Dichloropropene Sal 5 BOl = Below Quantitation Limit J = less than Ouantitation limR. Approximate Value POL = Practical Ouantitation limit
IACL I Phone: (770) 409~-1~4~4"'!'4----------------""!"3~03~9~A~m-w~i~le-r ADVANCED CHEMISTRY LABS, INC.
~Ro-a-d~'~S~u~ite~10~0-'-A~t1-an-ta-,~G~A~3~03~6""!"0-Fax: (770) 409-1844 P.O. Box 88610' Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell V.O.(5030B/8260B)
- Appendix II Sample 10: Trip Blank Matrix: Water Date Sampled: 12/16/2003 Date Extracted:
Date Analyzed: 12/29/2003 ACL Sample #: 210465 Units: 1J9/L Analyst: RP Analvte Result PQL Analvte Result PQL Acetone SOL 100 cis-1,3-Dichloropropene SOL 5 Acetonitrile SOL 100 trans-1,3-Dichloropropene SOL 5 Acrolein SOL 100 Ethyl methacrylate SOL 10 Acrylonitrile SOL 50 Ethylbenzene SOL 5 Allyl chloride SOL 10 2-Hexanone SOL 50 Senzene SOL 5 Isobutyl alcohol SOL 50 fomochloromethane SOL 5 Methacrylonitrile SOL 100 dromodichloromethane SOL 5 Methyl bromide SOL 10 Sromoform SOL 5 Methyl chloride SOL 10 Carbon disulfide SOL 5 Methyl ethyl ketone SOL 100 Carbon tetrachloride SOL 5 Methyl iodide SOL 5 Ch/orobenzene SOL 5 Methyl methacrylate Sal 30 Chloroethane SOL 10 4-Methyl-2-pentanone SOL 50 Chloroform SOL 5 Methylene bromide SOL 5 Chloroprene SOL 20 Methylene chloride SOL 5 1,2-Dibromo-3-chloropropane SOL 20 Naphthalene Sal 5 Dibromochloromethane Sal 5 Propionitrile Sal 150 1,2-Dibromoethane SOL 5 Styrene SOL 5 trans-1 ,4-Dichloro-2-butene SOL 10 1,1,1,2-Tetrachloroethane SOL 5 1,2-Dichlorobenzene SOL 5 1,1.2,2-Tetrachloroethane SOL 5 1,3-Dichlorobenzene SOL 5 Tetrachloroethene SOL 5 1,4-Dichlorobenzene SOL 5 Toluene SOL 5 Dichlorodifluoromethane SOL 5 1,1.1-Trichloroethane SOL 5 1,1-Dichloroethane SOL 5 1,1 ,2-Trichloroethane SOL 5 1,2-Dichloroethane SOL 5 Trichloroethene SOL 5 1,1-Dichloroethene SOL 5 Trichlorofluoromethane SOL 5 cis-1,2-Dichloroethene SOL 5 1,2,3-Trichloropropane SOL 5 trans-1,2-Dichloroethene SOL 5 Vinyl acetate Sal 50 1,2-Dichloropropane SOL 5 Vinyl chloride Sal 2 1,3-Dichloropropane SOL 5 m & p-Xylenes SOL 10 ... (,2-Dichloropropane SOL 15 o-Xylene sal 5
.,1-Dichloropropene Sal 5 BOl " Below Quantitation limit J =less than Ouanlilation limit, ApJl(Oximate Value POL" Practical Ouanlilation lillil .... _-_ .. _ ~
IACL I ADVANCED CHEMISTR Y LABS, INC Phone: (770) 40~9~-1~4~44-:---------------~3~0~3':"9 ":"A-m-Wl~*le-r~R~oa-d':""*-:S:-u~ite~10~0~.-:A~t1a-n"':"ta-.~G"':"A~3~0~36':":0=-- Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client ProJ #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Acid Extractables (8270C) - Appendix II Sample 10: EQ-Blank MatrIx: Water Date Sampled: 12/17/2003 Date Extracted: 12/2212003 Date Analyzed: 12123/2003 ACL Sample #: 210464 Units: jJg/L Analyst: RB Analvte Result PQL 4-Chloro-3-methylphenol Sal 20 2-Chlorophenol Sal 10 m & p-Cresol Sal 10 o-Cresol Sal 10 2,4-Dichlorophenol Sal 10 2,6-Dichlorophenol Sal 10 Dimethylphenol Sal 10
.6-Dinitro-2-methylphenol Sal 50 2,4-Dinitrophenol Sal 50 2-Nitrophenol Sal 10 4-Nitrophenol Sal 50 Pentachlorophenol Sal 50 Phenol Sal 10 2.3,4,6-Tetrachlorophenol Sal 10 2.4,5-Trichlorophenol Sal 10 2,4,6-Trichlorophenol Sal 10 BOL = Below Quantilalion Limit J =Lesslhan Ouantitation Lim~. Approximate Value POL = Practical Quanlilation Limi
IACL I ADVANCEDCHEMISTRYLABS,lNC. Phone: (770) 40~9~-1~4""!'44~---------------3~0~3~9~A-m-W~i1e-r"'=R~o-ad~*~S~u~it-e""!"10~0~*~A~t1-an-ta-,~G~A-3~0~3~60~ Fax: (770) 409-1844 P.O. Sox 88610* Atlanta, GA 30356 e-mail: aCI@acl*labs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant VogUe 1258 Concord Rd. ACl Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Base Neutral Extractables (8270C) - Appendix II Sample 10: EO-Blank Matrix: Water Date Sampled: 12/17/2003 Date Extracted: 12/22/2003 Date Analyzed: 12/23/2003 ACl Sample #: 210464 Units: lJg/L Analyst: RB Analyte Result Pgl Analvte Result POL Acenaphthene Sal 10 Diethyl phthalate Sal 10 Acenaphthylene Sal 10 Dimethoate Sal 10 Acetophenone Sal 10 Dimethyl phthalate Sal 10 2-Acetylaminofluorene Sal 20 p-(Dimethylamino)azobenzene Sal 10 4-Aminobiphenyl Sal 20 7,12-Dimethylbenz(a)anthracene Sal 10 Anthracene Sal 10 3,3'-Dimethylbenzidine Sal 10
'enzo(a)anthracene Sal 10 m-Dinitrobenzene Sal 20 .Jenzo(a)pyrene Sal 10 2,4-Dinitrotoluene Sal 10 Senzo(b)fluoranthene Sal 10 2,6-Dinitrotoluene Sal 10 Senzo(g,h.i)perylene Sal 10 Diphenylamine Sal 10 Senzo(k)f1uoranthene Sal 10 Disulfoton Sal 10 Senzyl alcohol Sal 20 Ethyl methanesulfonate Sal 20 Sis(2-chloroethoxy)methane Sal 10 Famphur Sal 20 Sis(2-chloroethyl)ether Sal 10 Fluoranthene Sal 10 Sis(2-chloroisopropyl)ether Sal 10 Fluorene Sal 10 Sis(2-ethylhexyl)phthalate Sal 10 Hexachlorobenzene Sal 10 4-Sromophenyl phenyl ether Sal 10 Hexachlorobutadiene Sal 10 Sutyl benzyl phthalate Sal 10 Hexachlorocyclopentadlene Sal 10 p-Chloroaniline Sal 20 Hexachloroethane Sal 10 Chlorobenzilate Sal 10 Hexachloropropene Sal 10 2-Chloronaphthalene Sal 10 Indeno(1,2.3-cd)pyrene Sal 10 4-Chlorophenyl phenyl ether Sal 10 Isodrin Sal 20 Chrysene Sal 10 Isophorone Sal 10 Di-n-butyl phthalate Sal 10 Isosafrole Sal 10 Di-n-octyl phthalate Sal 10 Kepone Sal 20 Diallate Sal 10 Malathion Sal 50 Dibenz(a,h)anthracene Sal 10 Methapyrilene Sal 100 Dibenzofuran Sal 10 Methyl methanesulfonate Sal 10 1,2-Dichlorobenzene Sal 10 Methyl parathion Sal 10 1,3-Dichlorobenzene Sal 10 3-Methylcholanthrene Sal 10 o,1,4-Dichlorobenzene Sal 10 2-Methylnaphthalene Sal 10 .3'-Dichlorobenzidine Sal 20 Naphthalene Sal 10 eOL =Below Ouanli1ation Limit J =Less than Ouantitalion Lilla. Approximate Value POL =Practical Quantitalion Limit
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 409~-1~4"":"44~--------------~3~0~3~9"":"A-m-w~i1e-r~R~oa-d~*~S~u~ite~10~0~*~A~1I-ant-a-,~G~A-3~0~3~60~ Fax: (770) 409-1844 P.O. Box 88610* Atlanta. GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Base Neutral Extractables (8270C)
- Appendix II Sample 10: EO-Blank Matrix: Water Date Sampled: 12/17/2003 Date Extracted: 12/22/2003 Date Analyzed: 1212312003 ACL Sample #: 210464 Units: ~g/L Analyst: RB Analvte Result PQL 1A-Naphthoquinone Sal 10 1-Naphthylamine Sal 10 2-Naphthylamine Sal 10 5-Nitro-o-toluidlne Sal 10 2-Nitroaniline Sal 50 3-Nitroaniline SOL 50
.-Nitroaniline Sal 20 .J itrobenzene Sal 10 N-Nitroso-di-n-butylamine Sal 10 N-Nitrosodiethylamine SOL 20 N-Nitrosodimethylamine SOL 10 N-Nitrosodiphenylamine Sal 10 N-N itrosodipropylamine Sal 10 N-Nitrosomethylethylamine SOL 10 N-Nitrosopiperidine Sal 20 N-Nitrosopyrrolidine Sal 40 Parathion Sal 20 Pentachlorobenzene SOL 10 Pentachloronitrobenzene Sal 20 Phenacetin Sal 20 Phenanthrene Sal 10 p-Phenylenediamine SOL 10 Phorate Sal 10 Pronamide Sal 10 Pyrene Sal 10 Safrole Sal 10 1,2,4,5-Tetrachlorobenzene SOl 10 Thionazin Sal 20 o-Toluidine Sal 10 1,2,4-Trichlorobenzene Sal 10
..... 0,0,0-Triethyl phosphorothioate Sal 50 1,3.5-Trinitrobenzene Sal 10 Sal = Below Ouantitalion Limit J " less lhan Quanlilalion limit, ADDlOximale Value pal = Praclical Quanlilalion Limit
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40~9-:.1~444~--------------~3~03::':9:-A:-m-w~il:-er-:R::-o-ad~* S::"u~it-e~100::'::-.-:A~t1-an~ta-.":G~A-:3~0~36~0~ Fax: (770) 409-1844 P.O. Box 88610* Atlanta. GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACl Project #: 44014 Smyrna. GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Pesticides/PCBs (8081A18082)
- Appendix II Sample 10: EQ-Blank Matrix: Water Date Sampled: 12/17/2003 Date Extracted: 12/22/2003 Date Analyzed: 12/29/2003 ACl Sample #: 210464 Units: J.Ig/L Analyst: SS Analvte Result PQl Aldrin Sal 0.05 Arochlor-1016 Sal 0.50 Arochlor-1221 Sal 0.50 Arochlor-1232 Sal 0.50 Arochlor-1242 Sal 0.50 Arochlor-1248 Sal 0.50
-~rochlor-1254 Sal 0.50 Jochlor-1260 Sal 0.50 a-SHC Sal 0.05 b-SHC Sal 0.05 d-SHC Sal 0.05 g-SHC Sal 0.05 Chlordane Sal 0.10 4,4'-000 Sal 0.05 4,4'*00E Sal 0.05 4,4'-00T Sal 0.05 Dieldrin Sal 0.05 Endosulfan I Sal 0.05 Endosulfan II Sal 0.05 Endosulfan sulfate Sal 0.05 Endrin Sal 0.05 Endrin aldehyde Sal 0.05 Heptachlor Sal 0.05 Heptachlor epoxide Sal 0.05 Methoxychlor Sal 0.05 Toxaphene Sal 2.00 SOL = Selow QuantitaUon lim~
=
J less than OuantMUon limit. Approximate Value POL = Practical Ouanlilaoon limit
Phone: (770) Fax: (770) 409*1844 I IACL 40~9~-1~4~44~--------------~3~03~9~A~m-w~i1~er-:R~o-ad~'ADVANCED CHEMISTRY LABS, INC. S~u~it-e-10~0~'-:A-'t1a-n~ta-, ~G-A-'3"'0~36""'0-P.O. Box 88610' Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12119/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Chlorinated Herbicides (8151A)
- Appendix II Sample ID: EO-Blank Matrix: Water Date Sampled: 12/17/2003 Date Extracted: 12/23/2003 Date Analyzed: 12/29/2003 ACL Sample #: 210464 Units: ~g/L Analyst: S8 Analvte Result PQL 2,4-0 SOL 1.0 Oinoseb SOL 1.0 2.4,5-TP (Silvex) SOL 1.0 2,4,5-T SOL 1.0 BOl ,. Below Quanlilalion lim~
J ,. less than Quantilalion lmK. Approximate Value pal" Practical QuanUlation lmi!
IACL I ADVANCEDCHEMISTRYLABS,lNC. Phone: (770) 4Q9..~1~44":""4:-----------------::3~03~9~Am:--W1-::*I~er-:Ro~ad~' S::"u~it-e~10~0~'-:A":":'tla-n"':"ta-,~G"':"A-:3~03=-:6~0-Fax: (770) 409-1844 P.O. Box 88610' Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Miscellaneous Organics (504.1)
- Appendix II Sample 10: EO-Blank Matrix: Water Date Sampled: 12/17/2003 Date Extracted: 12/23/2003 Date Analyzed: 12/30/2003 ACL Sample #: 210464 Units: J,Jg/L Analyst: SS Analvte Result PQL 1,2-Dibromo-3-chloropropane SOL 0.20 1,2-Dibromoethane SOL 0.05 Sal = Below Quanlialion limK J = less than Ouanlilalion Limit. APPIOximale Value pal =Praclical Quanlilalion limR
IACL I ADVANCED CHEMISTRY LABS,INC Phone: (770) 40~9~-1~4~44~--------------~3!"!'0~39!'""A~m-w~lI~er~R!""o-a~d -.S~u"'!'it-e"'!'10~0~'~A-'t1a-n-ta-,~G"'!"A-3""'!'0~360~- Fax: (770) 409-1844 P.O. Box 88610' Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabS.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna. GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Appendix II Metals (6010B/7470A/7841) Sample ID: EO-Blank Matrix: Water Date Sampled: 12/17/2003 Date Extracted: Date Analyzed: 12/30/2003 ACL Sample #: 210464 Units: mg/L Analyst: SW/AD/JR Analvte Result PQL Antimony BOl 0.006 Arsenic BOl 0.010 Barium BOl 0.020 Beryllium BOl 0.004 Cadmium BOl 0.005 Chromium SOL 0.020 -obalt SOL 0.050 Jpper BOl 0.020 Lead BOl 0.010 Mercury SOL 0.0005 Nickel SOL 0.020 Selenium BOL 0.040 Silver BOl 0.010 Thallium Sal 0.002 Tin BOl 0.025 Vanadium Sal 0.050 Zinc BOl 0.020 BOl = Below Quantitatlon Limit J = less than Quanlilation lim~. Approximate Value
=
POL Practical Quanlitalion limit
IACL 1"'-- Phone: (770) 409-1444 AD_VA_N_C_13_D~CH-E-M-IS-T-'R-Y-LA-B~S,-IN-C. 3039 Amwiier Road* Suite 100* Atlanta, GA 30360 Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 Outside GA: (800) 277-0520 www.advancedchemistrylabs.com e-mail: acl@mindspring.com QUALITY CONTROL SECTION
IA CL 1"-- Phone: (770) 409-1444 Fax: (770) 409-1844 A_D_v:_:4_N~C~'E-'D"""'!!C-'H~'E~M"""'!"L""!"'S-TR......Y" "'!"'L~A-.B.....S-,l" !", ,!N~_C _ 3039 Amwiler Road- Suite 100' Atlanta, GA 30360 P.O. Box 88610' Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell
IA CL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 409~-1~4~4~4----------------~30~3~9~A~m-w~il~er~R~o-a~d-*~S~u~ite-1~0~0-*~A~t1-an-ta-,~G~A~30~3~6~0-Fax: (770) 409-1844 P.O. Box 88610* Atlanta. GA 30356 e-mail: acl@acl-Jabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Pro) #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12119/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell v.o. (50308/82608)
- Appendix II Sample 10: -----_._- Matrix: Water Date Sampled: --- ........
Date Extracted: Date Analyzed: 12/30/2003 ACL Sample #: Blank Units: jJg/L Analyst: RP Analvte Result PQL Analvte Result PQL Acetone Sal 100 cis-1,3-Dichloropropene Sal 5 Acetonitrile Sal 100 trans-1.3-Dichloropropene Sal 5 Acrolein 80l 100 Ethyl methacrylate 80l 10 Acrylon itrile 80l 50 Ethylbenzene 80l 5 Allyl chloride Sal 10 2-Hexanone 80l 50 Senzene 80l 5 Isobutyl alcohol Sal 50 romochloromethane 80l 5 Methacrylonitrile Sal 100 t:3romodichloromethane 80l 5 Methyl bromide 80l 10 Sromoform 80l 5 Methyl chloride 80l 10 Carbon disulfide Sal 5 Methyl ethyl ketone Sal 100 Carbon tetrachloride 80l 5 Methyl iodide Sal 5 Chlorobenzene 80l 5 Methyl methacrylate Sal 30 Chloroethane 80l 10 4-Methyl-2-pentanone 80l 50 Chloroform 80l 5 Methylene bromide Sal 5 Chloroprene Sal 20 Methylene chloride 80l 5 1,2-Dibromo-3-chloropropane 80l 20 Naphthalene Sal 5 Dibromochloromethane 80l 5 Propionitrile Sal 150 1.2-Dibromoethane Sal 5 Styrene Sal 5 trans-1 ,4-Dichloro-2-butene Sal 10 1,1,1.2-Tetrachloroethane Sal 5 1,2-Dichlorobenzene Sal 5 1,1.2.2-Tetrachloroethane Sal 5 1,3-Dichlorobenzene Sal 5 Tetrachloroethene Sal 5 1,4-Dichlorobenzene Sal 5 Toluene Sal 5 Dichlorodifluoromethane Sal 5 1,1,1-Trichloroethane 80l 5 1,1-Dichloroethane Sal 5 1,1,2-Trichloroethane Sal 5 1,2-Dichloroethane Sal 5 Trichloroethene Sal 5 1,1-Dichloroethene Sal 5 Trichlorofluoromethane 80l 5 cis-1,2-Dichloroethene Sal 5 1,2,3-Trichloropropane Sal 5 trans-1,2-0ichloroethene Sal 5 Vinyl acetate Sal 50 1,2-Dichloropropane Sal 5 Vinyl chloride Sal 2 1,3-0ichloropropane Sal 5 m & p-Xylenes Sal 10 2,2-Dichloropropane Sal 15 o-Xylene BOl 5 1,1-Dichloropropene 80l 5 80l = Below Ouanlllation limit J = less than Quantilation limit, Approximate Value PQl = Praaical Quantilation Lirnit
IACL Phone: (770)409-1444 Fax: (770) 409-1844 I ADVANCED CHEMISTRY LABS, INC. 3039 Amwiler Road* Suite 100* Atlanta, GA 30360 P.O. Box 88610
- Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACl Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12119/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell v.o. (50308/82608)
- Appendix I Sample 10: Matrix: Water Date Sampled: -------
Date Extracted: Date Analyzed: 12130/2003 ACl Sample #: Blank Units: ~g/l Analyst: RP Analvte Result Pgl Analvte Result PQl Acetone BOl 100 Methylene bromide BOl 5 Acrylonitrile BOl 50 Methylene chloride BOl 5 Benzene BOl 5 Styrene BOl 5 Bromochloromethane BOl 5 1,1,1 ,2-Tetrachloroethane BOl 5 Bromodichloromethane BOl 5 1,1,2,2-Tetrachloroethane BOl 5 Bromoform BOl 5 Tetrachloroethene BOl 5 1rbon disulfide BOl 5 Toluene BOl 5
....arbon tetrachloride BOl 5 1,1 ,1-Trichloroethane BOl 5 Chlorobenzene BOl 5 1,1 ,2-Trichloroethane BOl 5 Chloroethane BOl 10 Trichloroethene BOl 5 Chloroform BOl 5 Trichlorofluoromethane BOl 5 1,2-Dibromo-3-chloropropane BOl 20 1,2.3-Trichloropropane BOl 5 Dibromochloromethane BOl 5 Vinyl acetate BOl 50 1.2-Dibromoethane BOl 5 Vinyl chloride BOl 2 trans-1,4-Dichloro-2-butene BOl 10 m & p-Xylenes BOl 10 1,2-Dichlorobenzene BOl 5 o-Xylene BOl 5 1,4-Dichlorobenzene BOl 5 1,1-Dichloroethane BOl 5 1.2-Dichloroethane BOl 5 1,1-Dichloroethene BOl 5 cis-1,2-Dichloroethene BOl 5 trans-1,2-Dichloroethene BOl 5 1,2-Dichloropropane BOl 5 cis-1,3-Dichloropropene Sal 5 trans-1,3-Dichloropropene Sal 5 Ethylbenzene Sal 5 2-Hexanone Sal 50 Methyl bromide Sal 10 Methyl chloride Sal 10 Methyl ethyl ketone Sal 100
- Methyl iodide sal 5
-Methyl-2-pentanone Sal 50 BQl = Below Quanlilalion Limit J = less than Quanlitalion limit. AoolOximate Value pal = Practical Ouanlilalion limit
IA CL 1~~ Phone: (770) 409-1444 Fax: (770) 409-1844 A_D_V:_:4_N="C~'E~1J~C~'H~E~M.~L~SJ:_'R~Y_L_A_B.....S.....,I....N_C_. 3039 AmwiJer Road* Suite 100* Atlanta, GA 30360 P.O. Box 88610* Atlanta, GA 30356 e-mail: a c l @ a c l - l a b s . n e t W N W . a d v a n c e d c h e m i s t r y l a b s . c o m Client: Genesis Project Client Proj #: Plant VogUe 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell V.O. (50308/82608)
- Appendix II SURROGATE PERCENT RECOVERY
SUMMARY
Water Dibromofluoromethane 1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene (77-137) (72-138) (84-112) (77-125) ACL Sample # 210461 107 115 94 103 210462 106 116 96 104 210463 108 116 95 103 210464 108 114 95 102 210465 105 116 95 104 210473 106 114 95 105
** Matrix Interference DO=Diluted Out ----~-----
IACL I ADVANCED CHEMISTR Y LABS, INC. Phone: (770) 40~9~-1~44":""4:-----------------:::3~03::'::9~Am~w"::"i1e-r"=R-oa~d~."::S""':ul~te~1~00~.~A~t1-an~ta-. "::G~A~3~03~6~O-Fax: (770) 409-1844 P.O. Box 88610* Atlanta. GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell V.O. (50308/82608)
- Appendix I SURROGATE PERCENT RECOVERY
SUMMARY
Water Dibromofluoromethane 1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene (77-137) (72-138) (84-112) (77-125) ACL Sample # 210466 107 115 95 102 210467 107 115 94 103 210468 109 114 95 102 210469 107 115 96 104 210470 107 115 97 105 210471 106 115 95 103 210472 108 113 94 103
** Matrix Interference DO=Diluted Out
'"v .... "".,"'"
chlorobenzene 20.00 0.00 19.82 SPIKE MSD MSD ADDED CONCENTRATION % % QC LIMITS COMPOUND (ual/) Cual/) REC # RPD # RPD REC. 1,1-dichloroethene 20.00 21.79 109.0 3.2 14 (54-144) benzene 20.00 21.35 106.8 2.3 11 82-132 trichloroethene 20.00 21.16 105.8 2.6 14 73-128 toluene 20.00 22.43 112.2 0.5 13 (83-130 chlorobenzene 20.00 19.93 99.7 0.6 13 88-123
- Values outside of QC limits
., I. ... ... .- _ : _ ....
RPD: 0 out of 5 outside limits Spike Recovery: 0 out of 10 outside limits Comments:
ADVANCED CHEMISTRY LABS, INC. GCIMS UNIT # 2 WATER VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY Sequence Date: 12-30-03 Matrix Spike - Sample No.: 210538 5061 SAMPLE MS MS ac. ADDED CONCENTRATION CONCENTRATION % LIMITS COMPOUND (ua/I) (ualll (ua/l) REC # REC. 1,1-dichloroethene 5.00 0.00 5.34 106.8 54-144 benzene 5.00 0.00 5.30 106.0 82-132 trichloroethene 5.00 0.00 5.19 103.8 :73-128 toluene 5.00 0.00 5.56 111.2 83-130 chlorobenzene 5.00 0.00 4.90 98.0 88-123 SPIKE MSD MSD ADDED CONCENTRATION % % ac LIMITS COMPOUND (uO!J) (ua/J) REC # RPD # RPD REC. 1,1-dichloroethene 5.00 5.18 103.6 3.0 14 54-144 benzene 5.00 5.19 103.8 2.1 11 82-132 trichloroethene 5.00 5.10 102.0 1.7 14 :73-128 toluene 5.00 5.35 107.0 3.8 13 83-130 chlorobenzene 5.00 4.62 92.4 5.9 13 88-123
- Column to be used to flag recovery and RPD values with an asterisk
- Values outside of ac limits RPD: 0 out of 5 outside limits Spike Recovery: 0 out of 10 outside limits Comments:
SPIKE MSD MSD ADDED CONCENTRATION % % QC LIMITS COMPOUND (uo/l) (ua/l) REC # RPD # RPD REC. 1,1-dichloroethene 20.00 21.95 109.8 1.3 14 54-144) benzene 20.00 21.36 106.8 0.0 11 82-132) trichloroethene 20.00 21.07 105.4 2.6 14 ~3-128 toluene 20.00 22.20 111.0 0.2 13 83-130 chlorobenzene 20.00 19.27 96.4 0.1 13 88-123
- Column to be used to flag recovery and RPD values with an asterisk
- Values outside of QC limits RPD: 0 out of 5 outside limits Spike Recovery: 0 out of 10 outside limits Comments:
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40~9~-1:-:44"':"4~---------------:3:":0~39:-A':""m"W1-::"le~r R~o-a-:d-*~S-:ui:-te-:1~00:-'-A~t1:-an-:ta-.~G:-:A-3~0~3':":60=- Fax: (770) 409-1844 P.O. Box 88610* Atlanta, GA 30356 a-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client ProJ #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna. GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Acid Extractables (8270C)
- Appendix II Sample 10: Matrix: Water Date Sampled:
Date Extracted: 12122/2003 Date Analyzed: 12/23/2003 ACL Sample #: Blank Units: IJg/L Analyst: RB Analvte Result PQL 4-Chloro-3-methylphenol Sal 20 2-Chlorophenol SOL 10 m & p-Cresol SOL 10 o-Cresol SOL 10 2.4-Dichlorophenol SOL 10 ._2.6-Dichlorophenol Sal 10 4-Dimethylphenol SOL 10
....6-Dinitro-2-methylphenol Sal 50 2.4-Dinitrophenol SOL 50 2-Nitrophenol SOL 10 4-Nitrophenol SOL 50 Pentachlorophenol SOL 50 Phenol BOL 10 2.3,4.6-Tetrachlorophenol SOL 10 2,4,5-Trichlorophenol BOL 10 2.4.6-Trichlorophenol SOL 10 BOl = Below Ouanlilatlon LimR J = less lIIan Quanlftalion limit, A\lIlroxinale Value POL =Practical Quanlitation linit
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40!:':9~.1~4~44~--------------~3:":0~3':"9~A-m-w'::"i1e-r-=R~oa-d':".~S~u~jte~10:":0~*~A~t1-an~ta-.~GA~3~0~3~60~ Fax: (770) 409*1844 P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACl Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Base Neutral Extractables (8270C)
- Appendix II Sample 10: ------- Matrix: Water Date Sampled: -----.....-
Date Extracted: 12/2212003 Date Analyzed: 12123/2003 ACl Sample #: Blank Units: ~g/L Analyst: RP Analyte Result PQl Analyte Result Pgl Acenaphthene Sal 10 Diethyl phthalate Sal 10 Acenaphthylene Sal 10 Dimethoate Sal 10 Acetophenone Sal 10 Dimethyl phthalate Sal 10 2-Acetylam inofluorene sal 20 p-(Dimethylamino)azobenzene Sal 10 4-Aminoblphenyl Sal 20 7,12-Dimethylbenz(a)anthracene Sal 10 Anthracene Sal 10 3,3'-Dimethylbenzidine Sal 10 1enzo(a)anthracene sal 10 m-Dinitrobenzene Sal 20 denzo(a)pyrene Sal 10 2,4-Dinitrotoluene Sal 10 Senzo(b)fluoranthene Sal 10 2,6-Dinitrotoluene Sal 10 Senzo(g,h,i)perylene Sal 10 Diphenylamine Sal 10 Senzo(k)fluoranthene Sal 10 Disulfoton SOL 10 Benzyl alcohol Sal 20 Ethyl methanesulfonate SOL 20 Sis(2-chloroethoxy)methane SOL 10 Famphur SaL 20 Sis(2-ehloroethyl)ether SOL 10 Fluoranthene SaL 10 Sis(2-chloroisopropyl)ether Sal 10 Fluorene SaL 10 Sis(2-ethylhexyl)phthalate Sal 10 Hexachlorobenzene SaL 10 4-Sromophenyl phenyl ether Sal 10 Hexachlorobutadiene SOL 10 Sutyl benzyl phthalate SOL 10 Hexachlorocyclopentadiene SOL 10 p-Chloroaniline Sal 20 Hexachloroethane Sal 10 Chlorobenzilate Sal 10 Hexachloropropene SaL 10 2-Chloronaphthalene SaL 10 Indeno(1,2,3-cd)pyrene SOL 10 4-Chlorophenyl phenyl ether Sal 10 Isodrin SaL 20 Chrysene Sal 10 Isophorone BOL 10 Di-n-butyl phthalate Sal 10 Isosafrore Sal 10 Di-n-octyl phthalate Sal 10 Kepone SaL 20 Dial/ate Sal 10 Malathion SOL 50 Dibenz(a,h)anthracene SOL 10 Methapyrilene Sal 100 Dibenzofuran Sal 10 Methyl methanesulfonate Sal 10 1,2-Dichlorobenzene Sal 10 Methyl parathion SOL 10 1,3-Dichlorobenzene Sal 10 3-Methylcholanthrene SaL 10 1A-Dichlorobenzene Sal 10 2-Methylnaphthalene Sal 10 3,3'-Dichlorobenzidine Sal 20 Naphthalene SOL 10 BOl = Below OuantilaUon lim~ J =less than QuanUtation limit, Approximate Value POL = Practical QuanlitaUon Limit
Phone: (770) Fax: (770) 409-1844 I IACL 40:-:9~-1~44~4~---------------3~0~3~9~A-m-w~ile-r"'=R~o-ad"':'"*~S~u~it-e~100~*~A~t1~an-ta-,~G~A~30~3--60~ ADVANCED CHEMISTRY LABS, INC. P.O. Box 88610* Atlanta, GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemlstrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna. GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Base Neutral Extractables (8270C) - Appendix II Sample 10: ---_._.- Matrix: Water Date Sampled: Date Extracted: 12/22/2003 Date Analyzed: 1212312003 ACL Sample #: Blank Units: 1J9/L Analyst: RP Analyte Result PQL 1,4-Naphthoquinone SOL 10 1-Naphthylamine SOL 10 2-Naphlhylamine SOL 10 S-Nilro-o-loluidine SOL 10. 2-Nitroaniline SOL 50 3-Nitroaniline SOL 50
~-Nitroanjljne SOL 20 Nitrobenzene SOL 10 N-Nilroso-di-n-butylamine SOL 10 N-Nilrosodielhylamine SOL 20 N-Nilrosodimelhylamine SOL 10 N-Nilrosodiphenylamine SOL 10 N-Nilrosodipropylamine SOL 10 N-Nitrosomethylethylamine SOL 10 N-Nilrosopiperidine SOL 20 N-Nilrosopyrrolidine SOL 40 Parathion SOL 20 Penlachlorobenzene SOL 10 Penlachloronilrobenzene SOL 20 Phenacelin SOL 20 Phenanlhrene SOL 10 p-Phenylenediamine SOL 10 Phorale SOL 10 Pronamide SOL 10 Pyrene SOL 10 Safrole SOL 10 1,2,4,S-Telrachlorobenzene SOL 10 Thionazin SOL 20 0- Toluidine SOL 10 1,2,4*Trichlorobenzene SOL 10
" o,o,o-Triethyl phosphorothioate SOL 50 1,3,5-Trinilrobenzene SOL 10 BOl =Below Ouanlilation Limit J = Less lhan Ouanlilalion liM, Approximate Value PQl = Practical Quanlkalion Limit
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 409~*1~44~4--------------"'!"'30~3"'!"'9~A-mw~i~le~r R~o-ad~*S~u~ite-1~0"'!"'0-*A-t-lan-ta-.~G"'A""'!3"'03~6"'0-Fax: (770) 409*1844 P.O. Box 88610
- Atlanta. GA 30356 e-mail: acl@acl*labs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Acid Extractables (8270C)
- Appendix II SURROGATE PERCENT RECOVERY
SUMMARY
Water Phenol-d6 2-Fluorophenol 2,4,6-Trlbromophenol (10-94) (21-100) (10-123) ACL Sample # 210461 14 24 35 210462 17 28 49 210463 17 27 49 210464 16 24 56
.. Matrix Interference DO=Diluted Out
IA CL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40~9~.1~44':"":4~-------------~30::'::3~9"":'A"mWl-'*!:""'le""":r R='"o.... ad"':'-:*S=:-u~ite"1:"::0~0-.A~tl:-an"":'ta-,~G~A~3~03~6~0-Fax: (770) 409-1844 P.O. Box 88610* Atlanta. GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12119/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Base Neutral Extractables (8270C)
- Appendix II SURROGATE PERCENT RECOVERY
SUMMARY
Water Nltrobenzene-d5 2.fluorobiphenyl Terphenyl-d14 (35-114) (43-116) (33-141) ACL Sample # 210461 41 51 62 210462 54 64 64 210463 53 68 73 210464 53 69 65
*" Matrix Interference DO=Diluted Out
ADVANCED CHEMISTRY LABS, INC. SEMI-VOL GCIMS UNIT # 4 ACID EXTRACTABLES (8270C) WATER SEMI-VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY Sequence Date: 12-23-03 Matrix Spike
- Sample No.: LCS122203 SPIKE SAMPLE MS MS ac.
COMPOUND ADDED CONCENTRATION CONCENTRATION % LIMITS (ua/L) (!JQ/L) (IJQ/L) REC # REC. Pentachlorophenol 200 0 77 38.5 9-103) Phenol 200 0 39 19.5 12-89) 2-Chlorophenol 200 0 98 49.0 27-123) 4-Chloro-3-methylphenol 200 0 134 67.0 23-97) 4-Nitrophenol 200 0 -42 21.0 10-80) SPIKE MSD MSD ac LIMITS COMPOUND ADDED CONCENTRATION % (!JaiL) (!JaIL) REC # RPD # RPD REC. Pentachlorophenol 200 74 37.0 4.0 50 9-103) Phenol 200 35 17.5 10.8 42 12-89) 2-Chlorophenol 200 88 44.0 10.8 40 27-123) 4-Chloro-3-methylphenol 200 133 66.5 0.7 42 23-97) 4-Nitrophenol 200 45 22.5 6.9 50 10-80)
- Column to be. used to flag recovery and RPD values with an asterisk
- Values outside of ac limits RPD: 0 out of 5 outside limits Spike Recovery: 0 out of 10 ~utside limits Comments:
ADVANCED CHEMISTRY LABS, INC. SEMI-VOL GC/MS UNIT # 4 BASE/NEUTRAL EXTRACTABLES (8270C) WATER SEMI-VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY Sequence Date: 12-23-03 Matrix Spike - Sample No.: LCS122203 SPIKE SAMPLE MS MS ac. ADDED CONCENTRATION CONCENTRATION % LIMITS COMPOUND (IJr::I/L) (IJQ/L) (lJp/U REC # REC. 1,2,4-Trichlorobenzene 100 0 75 75.0 39-98) Acenaphthene 100 0 63 63.0 46-118 2,4-Dinitrotoluene 100 0 73 73.0 24-96) Di-n-butyl phthalate 100 0 76 76.0 11-117 Pyrene 100 0 68 68.0 26-127 N-Nitrosodi-n-oroovlamine 100 0 67 67.0 41-116 1,4-Dichlorobenzene 100 0 59 59.0 36-97) SPIKE MSD MSD ADDED CONCENTRATION % % ac LIMITS COMPOUND lJoIL IJr::IlL REC # RPD # RPD REC. 1.2.4-Trichlorobenzene 100 74 74.0 1.3 28 39-98) Acenaohthene 100 62 62.0 1.6 31 46-118 2,4-Dinitrotoluene 100 72 72.0 1.4 38 24-96) Di-n-butvl phthalate 100 76 76.0 0.0 40 11-117 IPyrene 100 70 70.0 2.9 31 26-127 N-Nitrosodi-n-propyJamine 100 62 62.0 7.8 38 41-116 1,4-Dichlorobenzene 100 57 57.0 3.4 28 36-97)
# Column to be used to flag recovery and RPD values with an asterisk
- Values outside of ac limits RPD: 0 out of 7 outside limits Spike Recovery: 0 out of 14 outside limits Comments:
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40='=9~-1~44":"'4:----------------~3~03='=9~A:-m-w~i1-er-:R~o-ad~. S~u"':':'it-e~100~.""':'A~t1a-n~ta-. '=G":"'A-:3~03~6~0-Fax: (770) 409-1844 P.O. Box 88610* Atlanta. GA 30356 e-mail: acl@acl-Iabs.net www.aclvancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Pesticides/PCBs (8081A18082)
- Appendix II Sample 10: Matrix: Water Date Sampled:
Date Extracted: 12/22/2003 Date Analyzed: 12/29/2003 ACL Sample #: Blank Units: ~g/L Analyst: SS Analyte Result PQL Aldrin SOL 0.05 Arochlor-1 016 BOl 0.50 Arochlor-1221 BOl 0.50 Arochlor-1232 SOL 0.50 Arochlor-1242 BOl 0.50 ,_, Arochlor*1248 SOL 0.50
\rochlor-1254 SOL 0.50 Arochlor-1260 BOl 0.50 a-SHC SOL 0.05 b-SHC SOL 0.05 d-SHC BOl 0.05 g-SHC BOl 0.05 Chlordane SOL 0.10 4,4'-000 SOL 0.05 4,4'-00E SOL 0.05 4.4'-00T SOL 0.05 Dieldrin BOl 0.05 Endosulfan I SOL 0.05 Endosulfan II SOL 0.05 Endosulfan sulfate SOL 0.05 Endrin SOL 0.05 Endrin aldehyde SOL 0.05 Heptachlor SOL 0.05 Heptachlor epoxide BOl 0.05 Methoxychlor BOl 0.05 Toxaphene Sal 2.00 BQL = Below Quanlilalion limR J = less than Quanlilalion lmR. APPlOxmate Value POL = Praclical Ouantitation lin~
IA CL I ADVANCED CHEMISTRY LABS, INC Phone: (770) 409~*1~444~-------------~30~3~9~A-mw""':i':"'le-:r R~o-ad"':"'*""':S~u~ite-1~0~0 -.A~t1:-an'"'!"ta-.~G"':"'A~3~03~6~0-Fax: (770) 409*1844 P.O. Box 88610* Atlanta. GA 30356 a-mail: acl@acl-Iabs.net www.advancedchemlstrylabs.com Client: Genesis Project Client ProJ #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna. GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Pesticides/PCBs (8081A18082). Appendix II SURROGATE PERCENT RECOVERY
SUMMARY
Water TCMX DCBP (30-130) (30-130) ACL Sample # 210461 217** 95 210462 232** 89 210463 67 90 210464 63 93
.. Matrix Interference DO=Diluted Out
Advanced Chemistry Labs Pesticides Spike/Spike Dup. Report(EPA Method 60B / SW-B46 Method BOB1A) Instrument 10: HP5890A-ECD Column: RTx-CLPII, 30m, 0.42tJm, O.53mm ACL #: LCSW122203 Matrix: Water Extraction Date: 12122103 Analysis Date: 12129/03 Initial Volume: 1000.0 ml Final Volume: 1 ml Dilution Factor: 1 Pestlelde I R.T. I MS I AI'H MS I IUnit: Actual MS
% Rec.
MS tfg/L orppb Cone. I I I I R. T. MSD Area MSD Actua' MSD "Rec. \SamP/e %D MSD Cone. (RPD) TCMX(SS#1) 7.354 640086 0.314 62.79% 0.500 7.365 714419 0.350 70.0'% 0.000 10.98% a-BHC 8.968 1739790 0.640 127.96% 0.500 8.977 1948650 0.717 143.32% 0.000 11.33% g-BHC (Lindane) 10.016 1592170 0.633 126.60% 0.500 10.025 1737480 0.691 138.16% 0.000 8.73% b-BHC 10.269 624078 0.505 101.00-" 0.500 10.278 653153 0.529 105.70% 0.000 4.55% d-BHC 11.215 1482970 0.741 14'.27% 0.500 11.224 1513520 0.757 151.33% 0.000 2.04% Heptachlor 11.379 1653580 0.531 106.19% 0.500 11.387 1839150 0.591 118.10-" 0.000 10.63% Aldrin 12.489 1731550 0.687 137.31% 0.500 12.497 1888460 0.749 149.75% 0.000 8.67% Heptachlor Epoxide 14.479 1576570 0.658 131.55% 0.500 14.486 1627330 0.679 135.79% 0.000 3.17°k a-Endosulfan I 15.936 1460990 0.653 130.60% 0.500 15.942 1492260 0.667 133.39"" 0.000 2.12% ODE 16.258 1540210 0.663 132.57% 0.500 16.264 1540140 0.663 132.57% 0.000 0.00% Dieldrin 16.945 1439470 0.632 126.49% 0.500 16.951 1456500 0.640 127.99% 0.000 1.18% Endrin 18.104 1181450 0.650 130.09"" 0.500 18.109 1193420 0.657 131.41% 0.000 1.01% DOD 18.455 1293590 0.806 161.11% 0.500 18.461 1280260 0.797 159.45% 0.000 1.04% b-Endosulfan II 18.914 1323020 0.645 129.07% 0.500 18.919 1314610 0.641 128.25% 0.000 0.64% DDT 19.630 1025390 0.605 121.06% 0.500 19.635 1039340 0.614 122.70% 0.000 1.35% Endrin Aldehyde 20.183 1031110 0.722 1.....34% 0.500 20.187 1045050 0.731 146.29% 0.000 1.34% Endosulfan Sulfate 21.279 1176900 0.684 136.75% 0.500 21.283 1179280 0.685 137.03% 0.000 0.20% Methoxychlor 22.411 534387 0.548 109.65% 0.500 22.415 541706 0.556 111.15% 0.000 1.36% Mirex 23.581 562785 0.258 51.62% 0.500 23.583 562319 0.258 51.58% 0.000 0.080/0 Endrin Ketone 23.751 1257640 0.596 119.23"" 0.500 23.752 1261190 0.598 119.54% 0.000 0.27% DCBP(SS#2) 31.585 955235 0.390 78.05% 0.500 31.586 954099 0.390 n,96% 0.000 0.12%
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40~9-~1~444~--------------~3~03~9~Am~w"::'i1e-r~R~oa-d~'~S~ui~te~1~00~' A~tl~an~ta-.~G~A~3~0~36~0-Fax: (770) 409-1844 P.O. Box 88610* Atlanta. GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12119/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Chlorinated Herbicides (8151A)
- Appendix II Sample 10: Matrix: Water Date Sampled:
Date Extracted: 12/23/2003 Date Analyzed: 12/29/2003 ACL Sample #: Blank Units: ",giL Analyst: SS Analvte Result PQL 2,4-0 BOl 1.0 Oinoseb BOl 1.0 2.4,5-TP (Silvex) BOl 1.0 2,4,5-T BOl 1.0
=
BOl Below Quantitatlon limit J =less than Quantitallon limit, Approximate Value pal = Practical auantilation limit
IACL I ADVANCED CHEMISTRY LABS, INC Phone: (770) 40~9-~1~44~4~-------------~3~03~9~Am-w~i1e-r ~Ro-a"':"d-'S~u~ite~10~0-' ~AtI'!'"'a-nta-.""!!!G~A~3~0~36~0-Fax: (770) 409-1844 P.O. Box 88610' Atlanta. GA 30356 a-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna. GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Chlorinated Herbicides (8151A)
- Appendix II SURROGATE PERCENT RECOVERY
SUMMARY
Water oeAA (30-130) ACLSample# 210461 69 210462 68 210463 67 210464 66
... Matrix Interference DO=Diluted OUt
Advanced Chemistry Labs Herbicides Spike/Spike Dup. Report SW-846 Method 8151A Instrument 10: HP5890A-ECD/FID Column: RTx-1, 30m, O.25pm, O.25mm 10 ACL #: LCSW122303 Matrix: Water Extraction Date: 12123/03 Analysis Date: 12/29/03 Initial Volume: 1000 ml FmalVowme: 4 ml Dilution Factor: 1 Unit: WIL or ppb Herbicide Spike I R.T. I Area ISpike Cone. I Actual I% Recovery RPD OCAA(SS) 18.993 1183812 16.000 9.865 61.66% 3.96% 2,4-0 21.438 632680 4.000 3.197 79.94% 8.25% Silvex 23.593 747029 0.800 0.683 85.40% 5.00% 2.4,5-T 23.923 627427 0.800 0.620 77.52% 5.05% Oinoseb 25.000 422722 0.800 0.139 17.35% 18.91% Herbicide Spike Dup. I R.T. I Area I Spike Cone. I Actual I% Recovery Cone. OCAA(SS) 18.994 1137886 16.000 9.483 59.27% 0.000 2,4-0 21.438 582581 4.000 2.944 73.61% 0.000 Silvex 23.594 710621 0.800 0.650 81.24% 0.000 2.4,5-T 23.924 596503 0.800 0.590 73.70% 0.000 Oinoseb 25.001 349677 0.800 0.115 14.35% 0.000 °Herb. Calculation based on curve prep. on 12/16103
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 409-~1~4~44~--------------~3~03~9~A~m-w~i1~er~R~o-ad~* S~u~it-e-10~0~*~A"t1a-n-ta-.~G"A~3""'!"0"!""36"""'0-Fax: (770) 409*1844 P.O. Box 88610
- Atlanta. GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemistrylabs.com Client: Genesis Project Client Proj #: Plant VogUe 1258 Concord Rd. ACL Project #: 44014 Smyrna, GA 30080-0000 Date Received: 12119/2003 Date Reported: 12/30/2003
Contact:
Mr. Mark Mitchell Appendix II Metals (6010B/7470A/7841) Sample 10: Matrix: Water Date Sampled: Date Extracted: Date Analyzed: 12130/2003 ACL Sample #: Blank Units: mg/L Analyst: SW/AD/JR Analyte Result PQL Antimony Sal 0.006 Arsenic Sal 0.010 Sarium sal 0.020 Seryllium sal 0.004 Cadmium Sal 0.005 Chromium Sal 0.020
~obalt sal 0.050 Copper Sal 0.020 lead Sal 0.010 Mercury Sal 0.0005 Nickel Sal 0.020 Selenium Sal 0.040 Silver Sal 0.010 Thallium Sal 0.002 Tin Sal 0.025 Vanadium Sal 0.050 Zinc Sal 0.020 eOl :: Below Ouanlilalion limit J :: less than Ouanlitalion limit. Approximate Value PQL :: Practical Quanlilalion limit
ADVANCED CHEMISTRY LABS, INC. Appendix II Metals Water Matrix Spike for Method (6010B/7470A) Sample 10 -_--_--_--_- _ ACL Sample Number L_C"-S _ SPIKE SAMPLE MATRIX SPIKE MS MS ADDED RESULT RESULT REC RANGE COMPOUND (mg/L) (mg/L) (mg/L) (%) (%) Antimonv 0.040 0.000 0.038 94 75--125 Arsenic 0.100 0.000 0.108 108 75--125 Barium 1.000 0.000 0.753 75 75--125 Beryllium 0.100 0.000 0.105 105 75-125 Cadmium 0.025 0.000 0.025 101 75--125 Chromium 0.100 0.000 0.102 102 75--125 Cobalt 0.100 0.000 0.099 99 75--125 Copper 0.100 0.000 0.107 107 75--125 Lead 0.100 0.000 0.097 97 75-125 Mercury 0.0020 0.000 0.0022 109 75--125 Nickel 0.100 0.000 0.100 100 75--125 Selenium 0.025 0.000 0.022 87 75--125 Silver 0.020 0.000 0.019 94 75--125 Thallium 0.040 0.000 0.040 100 75--125 Tin 0.200 0.000 0.192 96 75--125 Vanadium 0.250 0.000 0.249 100 75--125 Zinc 0.100 0.000 0.107 107 75--125 Comment: ---'~-~'--'~
IACL I ADVANCED CHEMISTRY LABS, INC. Phone: (770) 40::-:9~-1~4~44O:----------------~3~0~39~A:-m-w-::il~er~R~o-a~d -.S="u"":':it-e~10~0:-*~A~t1a-n~ta-.~G~A~3~0~36~0-Fax: (770) 409-1844 P.O. Box 88610
- Atlanta. GA 30356 e-mail: acl@acl-Iabs.net www.advancedchemlstrylabs.com Client: Genesis Project Client Proj #: Plant Vogtle 1258 Concord Rd. ACL Project #: 44014 Smyrna. GA 30080-0000 Date Received: 12/19/2003 Date Reported: 01/06/2004
Contact:
Mr. Mark Mitchell Appendix I Metals (60108/7841) Sample 10: Matrix: Water Date Sampled: Date Extracted: Date Analyzed: 12/3012003 ACL Sample #: Blank Units: mg/L Analyst: SW/AD Analvte Result PQL Antimony BOl 0.006 Arsenic BOl 0.010 Barium BOl 0.020 Beryllium BOl 0.004 Cadmium BOl 0.005 -Chromium BOl 0.020 obalt BOl 0.050 Copper BOl 0.020 lead BOl 0.010 Nickel BOl 0.020 Selenium BOl 0.040 Silver BOl 0.010 Thallium BOl 0.002 Vanadium BOl 0.050 Zinc BOl 0.020 BOl = Below Quantilalion linit J =less than Quantilalion limit, AlllIfOXimale Value POL = Pradical Ouanlilalion Limit
ADVANCED CHEMISTRY LABS, INC. Appendix I Metals Water Matrix Spike for Method (601 OBn841) Sample 10: GWC-11/MW-11 ACL Sample Number : _ _--.-;;;2;.;.104~7..:;;;,2 _ SPIKE SAMPLE MATRIX SPIKE MS MS ADDED RESULT RESULT REC RANGE COMPOUND (mg/L) (mg/L) (mg/L) (%) (%) Antimony 0.040 0.000 0.041 103 75--125 Arsenic 0.100 0.000 0.100 100 75--125 Barium 1.000 0.022 0.786 76 75--125 Bervllium 0.100 0.000 0.104 104 75**125 Cadmium 0.025 0.000 0.025 101 75--125 Chromium 0.100 0.000 0.106 106 75--125 Cobalt 0.100 0.000 0.101 101 75-125 Copper 0.100 0.000 0.100 100 75--125 Lead 0.100 0.000 0.099 99 75--125 Nickel 0.100 0.000 0.103 103 75--125 Selenium 0.025 0.000 0.024 94 75--125 Silver 0.020 0.000 0.019 97 75--125 Thallium 0.040 0.000 0.038 96 75--125 Vanadium 0.250 0.000 0.255 102 75--125 linc 0.100 0.000 0.114 114 75-125 Comment:
I-A-c-L-I__~~~~~~~~~A~D~\I.~~~N~CE~D~c~H~EM~/~S~~~R~Y~LA~B=!!iS~I~/N~C~. 3039 Amwiler Road' Suite 100* Atlanta, GA 30360. P. O. Box 88610* Atlanta, GA 30356. (770) 409-1444
- Fax (770) 409-1844 Company Name: Phone #: 7'10" 311- 7).17 CHAIN-OF CUSTODY RECORD AND ANALYSIS REQUEST Company AddresS: Site Location:
IJ':"1J LV'!cC?d /.,) 5,,1<-</,-/'1<-1 (;4 (;.4 Aurte r,o~ ~ Project Manager: Client Project (#) PIWlf VOJlle r ~ Il/lCA/-i /vI,'Ul':-I/ I attest that the proper field sampling (Name) Sampler Name (Print): ~ I~ I"i ltr- -{
.~ I~ ~ : ~ 1_ ~~ ~ ~
procedures were used during the / JI I':§ .; ~ .. J\I~ ~ ~ collection ofthese samples. ,JJ.)t -rJirtr:<P(5"n ~ III _~ 'Ii; ...; ~ ~ ct'1_~.Jl ~ I------...:..-w--r---M-a-tr-ix-------':":M~et:":"'h-o"':"d -"""-5--1-'--4........ ~~ L. L. ""3 ~ "l..: ...... ~ _ l::i 1:) ..... 1 Field ._~ '-,---,r--r--,-----r-+--r_p,...re_s.,..erv-r-ed-.--+-_a_m_p..-m_g--ll~$: ~ F;!I ~ _ ,-'~ Sample J!l -0 ,~~ j J ~ ; -:: ~ ~. ~:; "I 0Z 0<fl Ql
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jJ --fj Fax~ RelinqUished by Sampler: Lj33 111/9~3 I /~~~ R_le_ce_lv_e_d.....;blY_:- - - - - - ~, CUSTODY Relinqui~-.: -i// / t./ _ Date Ti~ Received by: RECORD I -------------- Relinquished by : . __'- _. _ __ Date Time Received by ~al>.or:jl~q[Y,j ~ *" '
- I.
Waybill# N*I1JLViJf1n1S 'oL//9,()3
ApPENDIX B - STATISTICAL ANALYSES LANDFILL #2 Shapiro-Wilks Test of Normality Parameter: Trichlorofluoromethane All Wells Normality Test of Parameter Concentrations Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL
=
K 11; Samples 22 = i x(i) x(n-i+1) x(n-1 +1 )-x(i)a(n-i+1) b(i) 1 2.5 6 3.5 0.459 1.6065 2 2.5 5 2.5 0.3156 0.789 3 2.5 2.5 o 0.2571 o 4 2.5 2.5 o 0.2131 o 5 2.5 2.5 o 0.1764 o 6 2.5 2.5 o 0.1443 o 7 2.5 2.5 o 0.115 o 8 2.5 2.5 o 0.0878 o 9 2.5 2.5 o 0.0618 o 10 2.5 2.5 o 0.0368 o 11 2.5 2.5 o 0.0122 o 12 2.5 2.5 o 13 2.5 2.5 o 14 2.5 2.5 o 15 2.5 2.5 o 16 2.5 2.5 o 17 2.5 2.5 o 18 2.5 2.5 o 19 2.5 2.5 o 20 2.5 2.5 o 21 5 2.5 -2.5 22 6 2.5 -3.5 Sum of b values = 2.3955 Sample Standard Deviation = 0.89612
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W Statistic 0.340284 5% Critical value of 0.911 exceeds 0.340284 Evidence of non-normality at 95% level of significance 1% Critical value of 0.878 exceeds 0.340284 Evidence of non-normality at 99% level of significance
Kruskal-Wallis Non-Parametric Test Parameter: Trichlorofluoromethane Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL Kruskal Wallis Ranks Background Wells WelllD Date Result Rank GWA-2/MW-2 7/30/2002 BQL2.5 10.5 9/24/2002 BQL2.5 10.5 10/21/2002 BQL2.5 10.5 12/4/2002 BQL2.5 10.5 6/25/2003 BQL2.5 10.5 12/17/2003 BQL2.5 10.5 Rank Sum = 63 Rank Mean = 10.5 Background Rank Sum = 63 Background Rank Mean = 10.5 Compliance Wells WelllD Date Result Rank GWB-4/MW-4 7/30/2002 5 21 9/24/2002 BQL2.5 10.5 10/21/2002 BQL2.5 10.5 12/4/2002 - BQL2.5 10.5 6/25/2003 BQL2.5 10.5 12/17/2003 6 22 Rank Sum = 85 Rank Mean = 14.1667 GWC-11/MW-117/30/2002 BQL2.5 10.5 9/24/2002 BQL2.5 10.5 10/21/2002 BQL2.5 10.5 12/4/2002 BQL2.5 10.5 6/25/2003 BQL2.5 10.5 12117/2003 BQL2.5 10.5 Rank Sum = 63 Rank Mean = 10.5 GWC-3/MW-3 7/30/2002 BQL2.5 10.5 9/24/2002 BQL2.5 10.5 12/4/2002 BQL2.5 10.5 12/17/2003 BQL2.5 10.5 Rank Sum = 42 Rank Mean = 10.5 Calculation Results:
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Kruskal-Wallis H Statistic 1.3913 Kruskal-Wallis H Statistic (adjusted for tied non-detects) = 5.5873
95% Confidence comparison value is 7.81472 at 3 degrees offreedom 1.3913 < 7.81472 indicating no significant group difference at 5% significance level 5.5873 < 7.81472 indicating no significant group difference at 5% significance level when adjusted for ties
Shapiro-Wilks Test of Normality Parameter: Barium All Wells Normality Test of Parameter Concentrations Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL
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K 11; Samples 22 = i x(i) x(n-i+1) x(n-1 +1 )-x(i)a(n-i+1) b(i) 1 0.01 0.085 0.075 0.459 0.034425 2 0.01 0.027 0.017 0.3156 0.0053652 3 0.01 0.025 0.015 0.2571 0.0038565 4 0.01 0.022 0.012 0.2131 0.0025572 5 0.01 0.021 0.011 0.1764 0.0019404 6 0.01 0.021 0.011 0.1443 0.0015873 7 0.01 0.021 0.011 0.115 0.001265 8 0.01 0.0205 0.0105 0.0878 0.0009219 9 0.01 0.02 0.01 0.0618 0.000618 10 0.01 0.02 0.01 0.0368 0.000368 11 0.015 0.018 0.003 0.0122 3.66e-005 12 0.018 0.015 -0.003 13 0.02 0.01 -0.01 14 0.02 0.01 -0.01 15 0.0205 0.01 -0.0105 16 0.021 0.01 -0.011 17 0.021 0.01 -0.011 18 0.021 0.01 -0.011 19 0.022 0.01 -0.012 20 0.025 0.01 -0.015 21 0.027 0.01 -0.017 22 0.085 0.01 -0.075 Sum of b values = 0.0529411 Sample Standard Deviation = 0.0158984 W Statistic = 0.528029 5% Critical value of 0.911 exceeds 0.528029 Evidence of non-normality at 95% level of significance 1% Critical value of 0.878 exceeds 0.528029 Evidence of non-normality at 99% level of significance
Kruskal-Wallis Non-Parametric Test Parameter: Barium Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL Kruskal Wallis Ranks Background Wells WelllD Date Result Rank GWA-2/MW-2 7/3012002 0.027 21 9/24/2002 BQLO.01 5.5 10/21/2002 BQLO.01 5.5 12/4/2002 0.015 11 6/25/2003 BQLO.01 5.5 12117/2003 BQLO.01 5.5 Rank Sum =54 Rank Mean =9 Background Rank Sum =54 Background Rank Mean =9 Compliance Wells WelllD Date Result Rank GWB-4/MW-4 7/3012002 0.021 16 9/24/2002 0.021 17 10/21/2002 0.021 18 12/412002 - 0.0205 15 6/25/2003 BQLO.01 5.5 12/17/2003 BQLO.01 5.5 Rank Sum =77 Rank Mean =12.8333 GWC-11/MW-117/30/2002 0.085 22 9/24/2002 0.02 13 10/21/2002 0.025 20 12/412002 0.018 12 6/25/2003 BQLO.01 5.5 12/17/2003 0.022 19
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Rank Sum 91.5
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Rank Mean 15.25 GWC-3/MW-3 7/3012002 BQLO.01 5.5 9/24/2002 BQLO.01 5.5 12/4/2002 0.02 14 12/17/2003 BQLO.01 5.5
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Rank Sum 30.5
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Rank Mean 7.625 Calculation Results:
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Kruskal-Wallis H Statistic 4.56769 Kruskal-Wallis H Statistic (adjusted for tied non-detects) =5.03697
95% Confidence comparison value is 7.81472 at 3 degrees offreedom 4.56769 < 7.81472 indicating no significant group difference at 5% significance level 5.03697 < 7.81472 indicating no significant group difference at 5% significance level when adjusted for ties
LANDFILL #3 Shapiro-Wilks Test of Normality Parameter: Chlorobenzene All Wells Normality Test of Parameter Concentrations Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL K = 18; Samples = 36 i x(i) x(n-i+1) x(n-1 +1 )-x(i)a(n-i+1) b(i) 1 2.5 19 16.5 0.4068 6.7122 2 2.5 10 7.5 0.2813 2.10975 3 2.5 9 6.5 0.2415 1.56975 4 2.5 8 5.5 0.2121 1.16655 5 2.5 7 4.5 0.1883 0.84735 6 2.5 2.5 o 0.1678 o 7 2.5 2.5 o 0.1496 o 8 2.5 2.5 o 0.1331 o 9 2.5 2.5 o 0.1179 o 10 2.5 2.5 o 0.1036 o 11 2.5 2.5 o 0.09 o 12 2.5 2.5 o 0.077 o 13 2.5 2.5 o 0.0645 o 14 2.5 2.5 o 0.0523 o 15 2.5 2.5 o 0.0404 o 16 2.5 2.5 o 0.0287 o 17 2.5 2.5 o 0.0172 o 18 2.5 2.5 o 0.0057 o 19 2.5 2.5 o 20 2.5 2.5 o 21 2.5 2.5 o 22 2.5 2.5 o 23 2.5 2.5 o 24 2.5 2.5 o 25 2.5 2.5 o 26 2.5 2.5 o 27 2.5 2.5 o 28 2.5 2.5 o 29 2.5 2.5 o 30 2.5 2.5 o 31 2.5 2.5 o 32 7 2.5 -4.5 33 8 2.5 -5.5 34 9 2.5 . -6.5 35 10 2.5 -7.5 36 19 2.5 -16.5 Sum of b values = 12.4056
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Sample Standard Deviation 3.27627 W Statistic = 0.409646 5% Critical value of 0.935 exceeds 0.409646 Evidence of non-normality at 95% level of significance 1% Critical value of 0.912 exceeds 0.409646 Evidence of non-normality at 99% level of significance
Kruskal-Wallis Non-Parametric Test Parameter: Chlorobenzene Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL Kruskal Wallis Ranks Background Wells WelllD Date Result Rank GWA-15/MW-157/30/2002 BQL2.5 16 9/24/2002 BQL2.5 16 10/21/2002 - BQL2.5 16 12/3/2002 BQL2.5 16 6/24/2003 BQL2.5 16 12/17/2003 BQL2.5 16 Rank Sum 96= Rank Mean 16= GWA-7/MW-7 7/30/2002 - BQL2.5 16 9/24/2002 BQL2.5 16 10/21/2002 BQL2.5 16 12/3/2002 BQL2.5 16 6/24/2003 BQL2.5 16 12/17/2003 BQL2.5 16 Rank Sum 96= Rank Mean 16 = Background Rank Sum 192 = Background Rank Mean 16 = Compliance Wells WelllD Date Result Rank GWB-6/MW-6 7/30/2002 BQL2.5 16 9/24/2002 BQL2.5 16 10/21/2002 BQL2.5 16 1213/2002 BQL2.5 16 6/24/2003 BQL2.5 16 12/17/2003 BQL2.5 16 Rank Sum 96 = Rank Mean 16 = GWC-13/MW-137/30/2002 BQL2.5 16 9/24/2002 BQL2.5 16 10/21/2002 BQL2.5 16 12/3/2002 BQL2.5 16 6/2412003 - BQL2.5 16 12117/2003 - BQL2.5 16 Rank Sum 96 = Rank Mean 16 = GWC-14/MW-147/30/2002 BQL2.5 16 9/24/2002 - 8 33 10/21/2002 9 34 12/3/2002 10 35
6/24/2003 7 32 12/17/2003 19 36
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Rank Sum 186
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Rank Mean 31 GWC-5/MW-5 7/3012002 BQL2.5 16 9/24/2002 BQL2.5 16 10/21/2002 BQL2.5 16 12/3/2002 BQL2.5 16 6/24/2003 BQL2.5 16 12/17/2003 BQL2.5 16
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Rank Sum 96
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Rank Mean 16 Calculation Results:
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Kruskal-Wallis H Statistic 10.1351 Kruskal-Wallis H Statistic (adjusted for tied non-detects) = 28.0249 95% Confidence comparison value is 9.48773 at 4 degrees of freedom 10.1351 > 9.48773 indicating a significant group difference at 5% significance level 28.0249 > 9.48773 indicating a significant group difference at 5% significance level when adjusted for ties Individual Well Comparisons at 1.25% Significance Level per Comparison 1.25% Z score is 2.25713 Mean background rank is 16 Well Mean Rank Diffrom Bkg Critical Value GWB-6/MW-6 16 o 11.8902 GWC-13/MW-1316 o 11.8902 GWC-14/MW-1431 15 11.8902 GWC-5/MW-5 16 o 11.8902 Individual Well Comparisons at Groupwise 5% Significance Level (1.25% Significance Level per comparison) 1.25% Z score is 2.25713 Mean background rank is 16 Well Mean Rank Diffrom Bkg Critical Value GWB-6/MW-6 16 o 11.8902 GWC-13/MW-1316 o 11.8902 GWC-14/MW-1431 15 11.8902 GWC-5/MW-5 16 o 11.8902
Shapiro-Wilks Test of Normality Parameter: 1,4-Dichlorobenzene All Wells Normality Test of Parameter Concentrations Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL K = 18; Samples = 36 i x(i) x(n-i+1 ) x(n-1 +1 )-x(i)a(n-i+1) b(i) 1 2.5 39 36.5 0.4068 14.8482 2 2.5 36.5 34 0.2813 9.5642 3 2.5 35 32.5 0.2415 7.84875 4 2.5 33 30.5 0.2121 6.46905 5 2.5 20 17.5 0.1883 3.29525 6 2.5 5 2.5 0.1678 0.4195 7 2.5 5 2.5 0.1496 0.374 8 2.5 5 2.5 0.1331 0.33275 9 2.5 5 2.5 0.1179 0.29475 10 2.5 5 2.5 0.1036 0.259 11 2.5 2.5 0 0.09 0 12 2.5 2.5 0 0.077 0 13 2.5 2.5 0 0.0645 0 14 2.5 2.5 0 0.0523 0 15 2.5 2.5 0 0.0404 0 16 2.5 2.5 0 0.0287 0 17 2.5 2.5 0 0.0172 0 18 2.5 2.5 0 0.0057 0 19 2.5 2.5 0 20 2.5 2.5 0 21 2.5 2.5 0 22 2.5 2.5 0 23 2.5 2.5 0 24 2.5 2.5 0 25 2.5 2.5 0 26 2.5 2.5 0 27 5 2.5 -2.5 28 5 2.5 -2.5 29 5 2.5 -2.5 30 5 2.5 -2.5 31 5 2.5 -2.5 32 20 2.5 -17.5 33 33 2.5 -30.5 34 35 2.5 -32.5 35 36.5 2.5 -34 36 39 2.5 -36.5
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Sum of b values 43.7055 Sample Standard Deviation = 10.7832
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W Statistic 0.469364 5% Critical value of 0.935 exceeds 0.469364 Evidence of non-normality at 95% level of significance 1% Critical value of 0.912 exceeds 0.469364 Evidence of non-normality at 99% level of significance
Kruskal-Wallis Non-Parametric Test I Parameter: 1,4-Dichlorobenzene Original Data (Not Transformed) Non-Detects Replaced with 1/2 Dl Kruskal Wallis Ranks Background Wells WelllD Date Result Rank GWA-15/MW-157/30/2002 BOl2.5 16 9/24/2002 BOl2.5 16 10/21/2002 - BOl2.5 16 12/3/2002 BOL2.5 16 6/24/2003 BOl5 16 12/17/2003 BOl5 16 Rank Sum 96= Rank Mean = 16 GWA-7/MW-7 7/30/2002 - BOl2.5 16 9/24/2002 BOl2.5 16 10/21/2002 BOl2.5 16 12/3/2002 BOl2.5 16 6/2412003 BOl2.5 16 12/17/2003 BOl2.5 16 Rank Sum 96= Rank Mean 16= Background Rank Sum = 192 Background Rank Mean = 16 Compliance Wells WelllD Date Result Rank GWB-6/MW-6 7/30/2002 BOl2.5 16 9/24/2002 BOl2.5 16 10/21/2002 BOl2.5 16 12/3/2002 BOL2.5 16 6/2412003 BOl2.5 16 12/17/2003 BOL2.5 16 Rank Sum = 96 Rank Mean 16 = GWC-13/MW-137/30/2002 BOl2.5 16 9/24/2002 BOl2.5 16 10121/2002 BOl2.5 16 12/3/2002 BOL2.5 16 6/24/2003 - BOl5 16 12117/2003 - BOl5 16 Rank Sum 96 = Rank Mean 16 = GWC-14/MW-147/30/2002 20 32 9/24/2002 - 36.5 35 10/21/2002 35 34 12/3/2002 39 36
6/24/2003 BQL5 16 12/17/2003 33 33
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Rank Sum 186
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Rank Mean 31 GWC-5/MW-5 7/30/2002 BQL2.5 16 9/24/2002 BQL2.5 16 10/21/2002 BQL2.5 16 1213/2002 BQL2.5 16 6/24/2003 BQL2.5 16 12/17/2003 BQL2.5 16
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Rank Sum 96 Rank Mean = 16 Calculation Results:
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Kruskal-Wallis H Statistic 10.1351
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Kruskal-Wallis H Statistic (adjusted for tied non-detects) 28.0249 95% Confidence comparison value is 9.48773 at 4 degrees of freedom 10.1351 > 9.48773 indicating a significant group difference at 5% significance level 28.0249> 9.48773 indicating a significant group difference at 5% significance level when adjusted for ties Individual Well Comparisons at 1.25% Significance Level per Comparison 1.25% Z score is 2.25713 Mean background rank is 16 Well Mean Rank Diffrom Bkg Critical Value GWB-6/MW-6 16 o 11.8902 GWC-13/MW-1316 o 11.8902 GWC-14/MW-1431 15 11.8902 GWC-5/MW-5 16 o 11.8902 Individual Well Comparisons at Groupwise 5% Significance Level (1.25% Significance Level per comparison) 1.25% Z score is 2.25713 Mean background rank is 16 Well Mean Rank Diffrom Bkg Critical Value GWB-6/MW-6 16 o 11.8902 GWC-13/MW-1316 o 11.8902 GWC-14/MW-1431 15 11.8902 GWC-5/MW-5 16 o 11.8902
Shapiro-Wilks Test of Normality Parameter: 1,1-Dichloroethane All Wells Normality Test of Parameter Concentrations Original Data (Not Transformed) Non-Detects Replaced with 1/2 Dl
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K 18; Samples 36 = i x(i) x(n-i+1) x(n-1+1 )-x(i)a(n-i+1) b(i) 1 2.5 21 18.5 0.4068 7.5258 2 2.5 20.5 18 0.2813 5.0634 3 2.5 17 14.5 0.2415 3.50175 4 2.5 16 13.5 0.2121 2.86335 5 2.5 13 10.5 0.1883 1.97715 6 2.5 10 7.5 0.1678 1.2585 7 2.5 10 7.5 0.1496 1.122 8 2.5 9 6.5 0.1331 0.86515 9 2.5 7 4.5 0.1179 0.53055 10 2.5 6 3.5 0.1036 0.3626 11 2.5 6 3.5 0.09 0.315 12 2.5 2.5 0 0.077 0 13 2.5 2.5 0 0.0645 0 14 2.5 2.5 0 0.0523 0 15 2.5 2.5 0 0.0404 0 16 2.5 2.5 0 0.0287 0 17 2.5 2.5 0 0.0172 0 18 2.5 2.5 0 0.0057 0 19 2.5 2.5 0 20 2.5 2.5 0 21 2.5 2.5 0 22 2.5 2.5 0 23 2.5 2.5 0 24 2.5 2.5 0 25 2.5 2.5 0 26 6 2.5 -3.5 27 6 2.5 -3.5 28 7 2.5 -4.5 29 9 2.5 -6.5 30 10 2.5 -7.5 31 10 2.5 -7.5 32 13 2.5 -10.5 33 16 2.5 -13.5 34 17 2.5 -14.5 35 20.5 2.5 -18 36 21 2.5 -18.5
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Sum of b values 25.3853
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Sample Standard Deviation 5.46286
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W Statistic 0.616956 5% Critical value of 0.935 exceeds 0.616956 Evidence of non-normality at 95% level of significance 1% Critical value of 0.912 exceeds 0.616956 Evidence of non-normality at 99% level of significance
Kruskal-Wallis Non-Parametric Test Parameter: 1,1-Dichloroethane Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL Kruskal Wallis Ranks Background Wells WelllD Date Result Rank GWA-15/MW-157/30/2002 BQL2.5 13 9/24/2002 BQL2.5 13 10/21/2002 - BQL2.5 13 12/3/2002 BQL2.5 13 6/24/2003 BQL2.5 13 12/17/2003 BQL2.5 13 Rank Sum 78= Rank Mean 13= GWA-7/MW-7 7/30/2002 - BQL2.5 13 9/24/2002 BQL2.5 13 10/21/2002 BQL2.5 13 12/3/2002 BQL2.5 13 6/24/2003 BQL2.5 13 12/17/2003 BQL2.5 13 Rank Sum 78= Rank Mean 13= Background Rank Sum 156 = Background Rank Mean 13 = Compliance Wells WelllD Date Result Rank GWB-6/MW-6 7/30/2002 BQL2.5 13 9/24/2002 BQL2.5 13 10/21/2002 BQL2.5 13 1213/2002 BQL2.5 13 6/24/2003 BQL2.5 13 12/17/2003 BQL2.5 13 Rank Sum 78= Rank Mean 13 = GWC-13/MW-137/30/2002 BQL2.5 13 9/24/2002 6 26 10/21/2002 6 27 12/3/2002 7 28 6/24/2003 - 9 29 12/17/2003 - 20.5 35
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Rank Sum 158
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Rank Mean 26.3333 GWC-14/MW-147/30/2002 13 32 9/24/2002 - 21 36 10/21/2002 17 34 1213/2002 16 33
6/24/2003 10 30 12/17/2003 10 31
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Rank Sum 196
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Rank Mean 32.6667 GWC-5/MW-5 7/3012002 BQL2.5 13 9/24/2002 BQL2.5 13 10/21/2002 BQL2.5 13 12/3/2002 BQL2.5 13 6/24/2003 BQL2.5 13 12/17/2003 BQL2.5 13
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Rank Sum 78
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Rank Mean 13 Calculation Results:
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Kruskal-Wallis H Statistic 20.7057
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Kruskal-Wallis H Statistic (adjusted for tied non-detects) 31.1186 95% Confidence comparison value is 9.48773 at 4 degrees of freedom 20.7057> 9.48773 indicating a significant group difference at 5% significance level 31.1186 > 9.48773 indicating a significant group difference at 5% significance level when adjusted for ties Individual Well Comparisons at 1.25% Significance Level per Comparison 1.25% Z score is 2.25713 Mean background rank is 13 Well Mean Rank Diffrom Bkg Critical Value GWB-6/MW-6 13 o 11.8902 GWC-13/MW-1326.3333 13.3333 11.8902 GWC-14/MW-1432.6667 19.6667 11.8902 GWC-5/MW-5 13 o 11.8902 Individual Well Comparisons at Groupwise 5% Significance Level (1.25% Significance Level per comparison) 1.25% Z score is 2.25713 Mean background rank is 13 Well Mean Rank Diffrom Bkg Critical Value GWB-6/MW-6 13 o 11.8902 GWC-13/MW-1326.3333 13.3333 11.8902 GWC-14/MW-1432.6667 19.6667 11.8902 GWC-5/MW-5 13 o 11.8902
Shapiro-Wilks Test of Normality Parameter: cis-1,2-Dichloroethene All Wells Normality Test of Parameter Concentrations Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL
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K 18; Samples 36 = i x(i) x(n-i+1) x(n-1 +1 )-x(i)a(n-i+1) b(i) 1 2.5 19 16.5 0.4068 6.7122 2 2.5 18.5 16 0.2813 4.5008 3 2.5 17 14.5 0.2415 3.50175 4 2.5 16 13.5 0.2121 2.86335 5 2.5 14 11.5 0.1883 2.16545 6 2.5 10 7.5 0.1678 1.2585 7 2.5 10 7.5 0.1496 1.122 8 2.5 6 3.5 0.1331 0.46585 9 2.5 2.5 o 0.1179 o 10 2.5 2.5 o 0.1036 o 11 2.5 2.5 o 0.09 o 12 2.5 2.5 o 0.077 o 13 2.5 2.5 o 0.0645 o 14 2.5 2.5 o 0.0523 o 15 2.5 2.5 o 0.0404 o 16 2.5 2.5 o 0.0287 o 17 2.5 2.5 o 0.0172 o 18 2.5 2.5 o 0.0057 o 19 2.5 2.5 o 20 2.5 2.5 o 21 2.5 2.5 o 22 2.5 2.5 o 23 2.5 2.5 o 24 2.5 2.5 o 25 2.5 2.5 o 26 2.5 2.5 o 27 2.5 2.5 o 28 2.5 2.5 o 29 6 2.5 -3.5 30 10 2.5 -7.5 31 10 2.5 -7.5 32 14 2.5 -11.5 33 16 2.5 -13.5 34 17 2.5 -14.5 35 18.5 2.5 -16 36 19 2.5 -16.5
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Sum of b values 22.5899
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Sample Standard Deviation 5.21055
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W Statistic 0.537024 5% Critical value of 0.935 exceeds 0.537024 Evidence of non-normality at 95% level of significance 1% Critical value of 0.912 exceeds 0.537024 Evidence of non-normality at 99% level of significance
Kruskal-Wallis Non-Parametric Test Parameter: cis-1,2-Dichloroethene Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL Kruskal Wallis Ranks Background Wells WelllD Date Result Rank GWA-15/MW-157/30/2002 BQL2.5 14.5 9/24/2002 BQL2.5 14.5 10/21/2002 - BQL2.5 14.5 12/3/2002 BQL2.5 14.5 6/24/2003 BQL2.5 14.5 12/17/2003 BQL2.5 14.5 Rank Sum =87 Rank Mean = 14.5 GWA-7/MW-7 7/30/2002 - BQL2.5 14.5 9/24/2002 BQL2.5 14.5 10/21/2002 BQL2.5 14.5 12/3/2002 BQL2.5 14.5 6/24/2003 BQL2.5 14.5 12/17/2003 BQL2.5 14.5 Rank Sum =87 Rank Mean = 14.5 Background Rank Sum = 174 Background Rank Mean = 14.5 Compliance Wells WelllD Date Result Rank GWB-6/MW-6 7/30/2002 BQL2.5 14.5 9/24/2002 BQL2.5 14.5 10/21/2002 BQL2.5 14.5 12/3/2002 BQL2.5 14.5 6/24/2003 BQL2.5 14.5 12/17/2003 BQL2.5 14.5 Rank Sum =87 Rank Mean = 14.5 GWC-13/MW-137/30/2002 BQL2.5 14.5 9/24/2002 BQL2.5 14.5 10/21/2002 BQL2.5 14.5 12/3/2002 BQL2.5 14.5 6/24/2003 - 6 29 12/17/2003 - 14 32 Rank Sum = 119 Rank Mean = 19.8333 GWC-14/MW-147/30/2002 10 30 9/24/2002 - 18.5 35 10/21/2002 16 33 12/3/2002 19 36
6/24/2003 10 31 12117/2003 17 34
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Rank Sum 199
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Rank Mean 33.1667 GWC-5/MW-5 7/30/2002 BQL2.5 14.5 9/24/2002 BQL2.5 14.5 10/21/2002 BQL2.5 14.5 12/3/2002 BQL2.5 14.5 6/24/2003 BQL2.5 14.5 12117/2003 BQL2.5 14.5
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Rank Sum 87
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Rank Mean 14.5 Calculation Results:
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Kruskal-Wallis H Statistic 15.1832
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Kruskal-Wallis H Statistic (adjusted for tied non-detects) 28.6621 95% Confidence comparison value is 9.48773 at 4 degrees of freedom 15.1832> 9.48773 indicating a significant group difference at 5% significance level 28.6621 > 9.48773 indicating a significant group difference at 5% significance level when adjusted for ties Individual Well Comparisons at 1.25% Significance Level per Comparison 1.25% Z score is 2.25713 Mean background rank is 14.5 Well Mean Rank Diffrom Bkg Critical Value GWB-6/MW-6 14.5 o 11.8902 GWC-13/MW-1319.8333 5.33333 11.8902 GWC-14/MW-1433.1667 18.6667 11.8902 GWC-5/MW-5 14.5 o 11.8902 Individual Well Comparisons at Groupwise 5% Significance Level (1.25% Significance Level per comparison) 1.25% Z score is 2.25713 Mean background rank is 14.5 Well Mean Rank Diffrom Bkg Critical Value GWB-6/MW-6 14.5 o 11.8902 GWC-13/MW-1319.8333 5.33333 11.8902 GWC-14/MW-1433.1667 18.6667 11.8902 GWC-5/MW-5 14.5 o 11.8902
Shapiro-Wilks Test of Normality Parameter: Trichlorofluoromethane All Wells Normality Test of Parameter Concentrations Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL
=
K 18; Samples 36 = i x(i) x(n-i+1) x(n-1 +1 )-x(i)a(n-i+1) b(i) 1 2.5 391 388.5 0.4068 158.042 2 2.5 381 378.5 0.2813 106.472 3 2.5 348 345.5 0.2415 83.4382 4 2.5 300 297.5 0.2121 63.0998 5 2.5 221 218.5 0.1883 41.1435 6 2.5 210 207.5 0.1678 34.8185 7 2.5 184.5 182 0.1496 27.2272 8 2.5 99.5 97 0.1331 12.9107 9 2.5 47.5 45 0.1179 5.3055 10 2.5 44 41.5 0.1036 4.2994 11 2.5 43 40.5 0.09 3.645 12 2.5 34 31.5 0.077 2.4255 13 2.5 32 29.5 0.0645 1.90275 14 2.5 31 28.5 0.0523 1.49055 15 2.5 27 24.5 0.0404 0.9898 16 2.5 23 20.5 0.0287 0.58835 17 2.5 5 2.5 0.0172 0.043 18 2.5 2.5 o 0.0057 o 19 2.5 2.5 o 20 5 2.5 -2.5 21 23 2.5 -20.5 22 27 2.5 -24.5 23 31 2.5 -28.5 24 32 2.5 -29.5 25 34 2.5 -31.5 26 43 2.5 -40.5 27 44 2.5 -41.5 28 47.5 2.5 -45 29 99.5 2.5 -97 30 184.5 2.5 -182 31 210 2.5 -207.5 32 221 2.5 -218.5 33 300 2.5 -297.5 34 348 2.5 -345.5 35 381 2.5 -378.5 36 391 2.5 -388.5
=
Sum of b values 547.842 Sample Standard Deviation = 117.993 W Statistic = 0.615931 5% Critical value of 0.935 exceeds 0.615931 Evidence of non-normality at 95% level of significance 1% Critical value of 0.912 exceeds 0.615931 Evidence of non-normality at 99% level of significance
Kruskal-Wallis Non-Parametric Test Parameter: Trichlorofluoromethane Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL Kruskal Wallis Ranks Background Wells WelllD Date Result Rank GWA-15/MW-157/30/2002 BQL2.5 10 9/24/2002 BQL2.5 10 10/21/2002 - BQL2.5 10 12/3/2002 BQL2.5 10 6/24/2003 BQL2.5 10 12/17/2003 BQL2.5 10 Rank Sum 60= Rank Mean 10= GWA-7/MW-7 7/30/2002- 184.5 30 9/24/2002 32 24 10/21/2002 221 32 12/3/2002 210 31 6/24/2003 23 21 12/17/2003 34 25 Rank Sum = 163 Rank Mean = 27.1667 Background Rank Sum = 223
=
Background Rank Mean 18.5833 Compliance Wells WelllD Date Result Rank GWB-6/MW-6 7/30/2002 BQL2.5 10 9/24/2002 BQL2.5 10 10/21/2002 BQL2.5 10 12/3/2002 BQL2.5 10 6/24/2003 BQL2.5 10 12/17/2003 BQL2.5 10 Rank Sum = 60 Rank Mean = 10 GWC-13/MW-137/30/2002 300 33 9/24/2002 381 35 10/21/2002 348 34 12/3/2002 391 36 6/24/2003 - 44 27 12/17/2003 - 99.5 29 Rank Sum = 194
=
Rank Mean 32.3333 GWC-14/MW-147/30/2002 43 26 9/24/2002 - 47.5 28 10/21/2002 31 23 12/3/2002 27 22
6/24/2003 5 20 12/17/2003 BQL2.5 10
=
Rank Sum 129
=
Rank Mean 21.5 GWC-5/MW-5 7/30/2002 BQL2.5 10 9/24/2002 BQL2.5 10 10/21/2002 BQL2.5 10 12/3/2002 BQL2.5 10 6/24/2003 BQL2.5 10 12/17/2003 BQL2.5 10
=
Rank Sum 60
=
Rank Mean 10 Calculation Results:
=
Kruskal-Wallis H Statistic 18.6419
=
Kruskal-Wallis H Statistic (adjusted for tied non-detects) 21.8473 95% Confidence comparison value is 9.48773 at 4 degrees of freedom 18.6419> 9.48773 indicating a significant group difference at 5% significance level 21.8473> 9.48773 indicating a significant group difference at 5% significance level when adjusted for ties Individual Well Comparisons at 1.25% Significance Level per Comparison 1.25% Z score is 2.25713 Mean background rank is 18.5833 Well Mean Rank Dif from Bkg Critical Value GWB-6/MW-6 10 -8.58333 11.8902 GWC-13/MW-1332.3333 13.75 11.8902 GWC-14/MW-1421.5 2.91667 11.8902 GWC-5/MW-5 10 -8.58333 11.8902 Individual Well Comparisons at Groupwise 5% Significance Level (1.25% Significance Level per comparison) 1.25% Z score is 2.25713 Mean background rank is 18.5833 Well Mean Rank Dif from Bkg Critical Value GWB-6/MW-6 10 -8.58333 11.8902 GWC-13/MW-1332.3333 13.75 11.8902 GWC-14/MW-1421.5 2.91667 11.8902 GWC-5/MW-5 10 -8.58333 11.8902
Shapiro-Wilks Test of Normality Parameter: Xylenes (total) All Wells Normality Test of Parameter Concentrations Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL K = 17; Samples = 35 i x(i) x(n-i+1) x(n-1 +1 )-x(i)a(n-i+1) b(i) 1 2.5 21 18.5 0.4096 7.5776 2 2.5 10 7.5 0.2834 2.1255 3 2.5 10 7.5 0.2427 1.82025 4 2.5 5 2.5 0.2127 0.53175 5 2.5 5 2.5 0.1883 0.47075 6 2.5 5 2.5 0.1673 0.41825 7 3.75 5 1.25 0.1487 0.185875 8 3.75 5 1.25 0.1317 0.164625 9 3.75 5 1.25 0.116 0.145 10 3.75 5 1.25 0.1013 0.126625 11 3.75 5 1.25 0.0873 0.109125 12 3.75 5 1.25 0.0739 0.092375 13 3.75 5 1.25 0.061 0.07625 14 3.75 5 1.25 0.0484 0.0605 15 3.75 5 1.25 0.0361 0.045125 16 3.75 5 1.25 0.0239 0.029875 17 3.75 5 1.25 0.0119 0.014875 18 5 5 o 19 5 3.75 -1.25 20 5 3.75 -1.25 21 5 3.75 -1.25 22 5 3.75 -1.25 23 5 3.75 -1.25 24 5 3.75 -1.25 25 5 3.75 -1.25 26 5 3.75 -1.25 27 5 3.75 -1.25 28 5 3.75 -1.25 29 5 3.75 -1.25 30 5 2.5 -2.5 31 5 2.5 -2.5 32 5 2.5 -2.5 33 10 2.5 -7.5 34 10 2.5 -7.5 35 21 2.5 -18.5 Sum of b values = 13.9944 Sample Standard Deviation = 3.25609 W Statistic = 0.543294 5% Critical value of 0.934 exceeds 0.543294 Evidence of non-normality at 95% level of significance 1% Critical value of 0.91 exceeds 0.543294 Evidence of non-normality at 99% level of significance
Kruskal-Wallis Non-Parametric Test Parameter: Xylenes (total) Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL Kruskal Wallis Ranks Background Wells WelllD Date Result Rank GWA-15/MW-157/30/2002 BOL5 16.5 9/24/2002 BOL5 16.5 10/21/2002 a BOL5 16.5 12/3/2002 BOL2.5 16.5 6/24/2003 - BOL3.75 16.5 12/17/2003 - BOL3.75 16.5 Rank Sum 99=
=
Rank Mean 16.5 GWA-7/MW-7 7/30/2002 - BOL5 16.5 9/24/2002 BOL5 16.5 10/21/2002 BOL5 16.5 12/3/2002 BOL2.5 16.5 6/24/2003 - BOL3.75 16.5 12/17/2003 - BOL3.75 16.5 Rank Sum 99 =
=
Rank Mean 16.5 Background Rank Sum 198 = Background Rank Mean 16.5= Compliance Wells WelllD Date Result Rank GWB-6/MW-6 7/30/2002 BOL5 16.5 9/24/2002 BOL5 16.5 10/21/2002 BOL5 16.5 12/3/2002 BOL2.5 16.5 6/24/2003 - BOL3.75 16.5 12/17/2003 - BOL3.75 16.5 Rank Sum 99 =
=
Rank Mean 16.5 GWC-13/MW-137/30/2002 BOL5 16.5 9/24/2002 BOL2.5 16.5 10/21/2002 BOL5 16.5 6/24/2003 - BOL3.75 16.5 12/17/2003 - BOL3.75 16.5
=
Rank Sum 82.5
=
Rank Mean 16.5 GWC-14/MW-147/30/2002 BOL5 16.5 9/24/2002 - 10 33 10/21/2002 BOL5 16.5 12/3/2002 21 35 6/24/2003 - BOL3.75 16.5
12/17/2003 - 10 34
=
Rank Sum 151.5
=
Rank Mean 25.25 GWC-5/MW-5 7/30/2002 BQL5 16.5 9/24/2002 BQL2.5 16.5 10/21/2002 BQL5 16.5 12/3/2002 BQL2.5 16.5 6/24/2003 - BQL3.75 16.5 12/17/2003 - BQL3.75 16.5 Rank Sum = 99 Rank Mean = 16.5 Calculation Results:
=
Kruskal-Wallis H Statistic 3.625
=
Kruskal-Wallis H Statistic (adjusted for tied non-detects) 15.3697 95% Confidence comparison value is 9.48773 at 4 degrees of freedom 3.625 < 9.48773 indicating no significant group difference at 5% significance level 15.3697> 9.48773 indicating a significant group difference at 5% significance level when adjusted for ties Individual Well Comparisons at 1.25% Significance Level per Comparison 1.25% Z score is 2.25713 Mean background rank is 16.5 Well Mean Rank Diffrom Bkg Critical Value GWB-6/MW-6 16.5 o 11.5643 GWC-13/MW-1316.5 o 12.3112 GWC-14/MW-1425.25 8.75 11.5643 GWC-5/MW-5 16.5 o 11.5643 Individual Well Comparisons at Groupwise 5% Significance Level (1.25% Significance Level per comparison) 1.25% Z score is 2.25713 Mean background rank is 16.5 Well Mean Rank Diffrom Bkg Critical Value GWB-6/MW-6 16.5 o 11.5643 GWC-13/MW-1316.5 o 12.3112 GWC-14/MW-1425.25 8.75 11.5643 GWC-5/MW-5 16.5 o 11.5643
Shapiro-Wilks Test of Normality Parameter: Barium All Wells Normality Test of Parameter Concentrations Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL K = 18; Samples = 36 i x(i) x(n-i+1) x(n-1 +1 )-x(i)a(n-i+1) b(i) 1 0.005 0.189 0.184 0.4068 0.0748512 2 0.005 0.142 0.137 0.2813 0.0385381 3 0.01 0.106 0.096 0.2415 0.023184 4 0.01 0.0935 0.0835 0.2121 0.0177104 5 0.01 0.085 0.075 0.1883 0.0141225 6 0.01 0.083 0.073 0.1678 0.0122494 7 0.01 0.082 0.072 0.1496 0.0107712 8 0.01 0.077 0.067 0.1331 0.0089177 9 0.01 0.068 0.058 0.1179 0.0068382 10 0.01 0.064 0.054 0.1036 0.0055944 11 0.01 0.051 0.041 0.09 0.00369 12 0.01 0.036 0.026 0.077 0.002002 13 0.01 0.0325 0.0225 0.0645 0.00145125 14 0.01 0.0295 0.0195 0.0523 0.00101985 15 0.01 0.02 0.01 0.0404 0.000404 16 0.01 0.018 0.008 0.0287 0.0002296 17 0.01 0.015 0.005 0.0172 8.6e-005 18 0.01 0.01 o 0.0057 o 19 0.01 0.01 o 20 0.015 0.01 -0.005 21 0.018 0.01 -0.008 22 0.02 0.01 -0.01 23 0.0295 0.01 -0.0195 24 0.0325 0.01 -0.0225 25 0.036 0.01 -0.026 26 0.051 0.01 -0.041 27 0.064 0.01 -0.054 28 0.068 0.01 -0.058 29 0.077 0.01 -0.067 30 0.082 0.01 -0.072 31 0.083 0.01 -0.073 32 0.085 0.01 -0.075 33 0.0935 0.01 -0.0835 34 0.106 0.01 -0.096 35 0.142 0.005 -0.137 36 0.189 0.005 -0.184 Sum of b values = 0.22166
=
Sample Standard Deviation 0.0439553
=
W Statistic 0.726579 5% Critical value of 0.935 exceeds 0.726579 Evidence of non-normality at 95% level of significance 1% Critical value of 0.912 exceeds 0.726579 Evidence of non-normality at 99% level of significance
Kruskal-Wallis Non-Parametric Test Parameter: Barium Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL Kruskal Wallis Ranks Background Wells WelllD Date Result Rank GWA-15/MW-157/30/2002 BQLO.01 10 9/24/2002 BQLO.01 10 10/21/2002 - BQLO.01 10 12/3/2002 BQLO.005 10 6/24/2003 BQLO.01 10 12/17/2003 BQLO.01 10 Rank Sum 60= Rank Mean 10= GWA-7/MW-7 7/30/2002- BQLO.01 10 9/24/2002 BQLO.01 10 10/21/2002 BQLO.01 10 12/3/2002 0.015 20 6/24/2003 0.036 25 12/17/2003 BQLO.01 10 Rank Sum = 85
=
Rank Mean 14.1667 Background Rank Sum 145 =
=
Background Rank Mean 12.0833 Compliance Wells WelllD Date Result Rank GWB-6/MW-6 7/30/2002 BQLO.01 10 9/24/2002 BQLO.01 10 10/21/2002 BQLO.01 10 1213/2002 BQLO.005 10 6/24/2003 BQLO.01 10 12117/2003 BQLO.01 10 Rank Sum 60 = Rank Mean 10 = GWC-13/MW-137/30/2002 0.077 29 9/24/2002 0.085 32 10/21/2002 0.083 31 12/3/2002 0.082 30 6/24/2003 - 0.0295 23 12/17/2003 - 0.0325 24 Rank Sum 169= Rank Mean = 28.1667 GWC-14/MW-147/30/2002 0.068 28 9/24/2002 - 0.0935 33 10/21/2002 0.064 27 12/3/2002 0.106 34
6/24/2003 0.051 26 12/17/2003 0.189 36
=
Rank Sum 184
=
Rank Mean 30.6667 GWC-5/MW-5 7/3012002 BQLO.01 10 9/24/2002 0.02 22 10/21/2002 BQLO.01 10 1213/2002 0.018 21 6/24/2003 BQLO.01 10 12/17/2003 0.142 35
=
Rank Sum 108
=
Rank Mean 18 Calculation Results:
=
Kruskal-Wallis H Statistic 21.4227
=
Kruskal-Wallis H Statistic (adjusted for tied non-detects) 25.1062 95% Confidence comparison value is 9.48773 at 4 degrees of freedom 21.4227 > 9.48773 indicating a significant group difference at 5% significance level 25.1062 > 9.48773 indicating a significant group difference at 5% significance level when adjusted for ties Individual Well Comparisons at 1.25% Significance Level per Comparison 1.25% Z score is 2.25713 Mean background rank is 12.0833 Well Mean Rank Dif from Bkg Critical Value GWB-6/MW-6 10 -2.08333 11.8902 GWC-13/MW-1328.1667 16.0833 11.8902 GWC-14/MW-1430.6667 18.5833 11.8902 GWC-5/MW-5 18 5.91667 11.8902 Individual Well Comparisons at Groupwise 5% Significance Level (1.25% Significance Level per comparison) 1.25% Z score is 2.25713 Mean background rank is 12.0833 Well Mean Rank Dif from Bkg Critical Value GWB-6/MW-6 10 -2.08333 11.8902 GWC-13/MW-1328.1667 16.0833 11.8902 GWC-14/MW-1430.6667 18.5833 11.8902 GWC-5/MW-5 18 5.91667 11.8902
Shapiro-Wilks Test of Normality Parameter: Beryllium All Wells Normality Test of Parameter Concentrations Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL K = 18; Samples = 36 i xCi) x(n-i+1) x(n-1 +1 )-x(i}a(n-i+1) b(i) 1 0.0015 0.004 0.0025 0.4068 0.001017 2 0.0015 0.002 0.0005 0.2813 0.00014065 3 0.0015 0.002 0.0005 0.2415 0.00012075 4 0.0015 0.002 0.0005 0.2121 0.00010605 5 0.0015 0.002 0.0005 0.1883 9.415e-005 6 0.0015 0.002 0.0005 0.1678 8.3ge-005 7 0.002 0.002 o 0.1496 o 8 0.002 0.002 o 0.1331 o 9 0.002 0.002 o 0.1179 o 10 0.002 0.002 o 0.1036 o 11 0.002 0.002 o 0.09 o 12 0.002 0.002 o 0.077 o 13 0.002 0.002 o 0.0645 o 14 0.002 0.002 o 0.0523 o 15 0.002 0.002 o 0.0404 o 16 0.002 0.002 o 0.0287 o 17 0.002 0.002 o 0.0172 o 18 0.002 0.002 o 0.0057 o 19 0.002 0.002 o 20 0.002 0.002 o 21 0.002 0.002 o 22 0.002 0.002 o 23 0.002 0.002 o 24 0.002 0.002 o 25 0.002 0.002 o 26 0.002 0.002 o 27 0.002 0.002 o 28 0.002 0.002 o 29 0.002 0.002 o 30 0.002 0.002 o 31 0.002 0.0015 -0.0005 32 0.002 0.0015 -0.0005 33 0.002 0.0015 -0.0005 34 0.002 0.0015 -0.0005 35 0.002 0.0015 -0.0005 36 0.004 0.0015 -0.0025 Sum of b values = 0.0015625 Sample Standard Deviation = 0.00039541 W Statistic = 0.446145 5% Critical value of 0.935 exceeds 0.446145 Evidence of non-normality at 95% level of significance 1% Critical value of 0.912 exceeds 0.446145 Evidence of non-normality at 99% level of significance
Kruskal-Wallis Non-Parametric Test Parameter: Beryllium Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL Kruskal Wallis Ranks Background Wells WelllD Date Result Rank GWA-15/MW-157/30/2002 BQLO.002 18 9/24/2002 BQLO.002 18 10/21/2002 - BQLO.002 18 12/3/2002 BQLO.0015 18 6/24/2003 BQLO.002 18 12/17/2003 BQLO.002 18
=
Rank Sum 108 Rank Mean 18= GWA-7/MW-7 7/30/2002 - BQLO.002 18 9/24/2002 BQLO.002 18 10/21/2002 BQLO.002 18 12/3/2002 BQLO.0015 18 6/24/2003 BQLO.002 18 12/17/2003 BQLO.002 18
=
Rank Sum 108 Rank Mean 18= Background Rank Sum 216 = Background Rank Mean 18 = Compliance Wells WelllD Date Result Rank GWB-6/MW-6 7/30/2002 BQLO.002 18 9/24/2002 BQLO.002 18 10/21/2002 BQLO.002 18 12/3/2002 BQLO.0015 18 6/24/2003 BQLO.002 18 12/17/2003 BQLO.002 18 Rank Sum 108= Rank Mean 18 = GWC-13/MW-137/30/2002 BQLO.002 18 9/24/2002 BQLO.002 18 10/21/2002 BQLO.002 18 12/3/2002 BQLO.0015 18 6/24/2003 - BQLO.002 18 12/17/2003 - BQLO.002 18 Rank Sum 108= Rank Mean 18 = GWC-14/MW-147/30/2002 BQLO.002 18 9/24/2002 - BQLO.002 18 10/21/2002 BQLO.002 18 12/3/2002 BQLO.0015 18
6/24/2003 BQLO.002 18 12/17/2003 0.004 36 Rank Sum = 126
=
Rank Mean 21 GWC-5/MW-5 7/3012002 BQLO.002 18 9/24/2002 BQLO.002 18 10/21/2002 BQLO.002 18 12/312002 BQLO.0015 18 6124/2003 BQLO.002 18 12/17/2003 BQLO.002 18 Rank Sum = 108
=
Rank Mean 18 Calculation Results:
=
Kruskal-Wallis H Statistic 0.405405 Kruskal-Wallis H Statistic (adjusted for tied non-detects) = 5 95% Confidence comparison value is 9.48773 at 4 degrees of freedom 0.405405 < 9.48773 indicating no significant group difference at 5% significance level 5 < 9.48773 indicating no significant group difference at 5% significance level when adjusted for ties
Shapiro-Wilks Test of Normality Parameter: Cadmium All Wells Normality Test of Parameter Concentrations Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL
=
K 18; Samples 36 = i x(i) x(n-i+1) x(n-1 +1 )-x(i)a(n-i+1) b(i) 1 0.0025 0.011 0.0085 0.4068 0.0034578 2 0.0025 0.0025 o 0.2813 o 3 0.0025 0.0025 o 0.2415 o 4 0.0025 0.0025 o 0.2121 o 5 0.0025 0.0025 o 0.1883 o 6 0.0025 0.0025 o 0.1678 o 7 0.0025 0.0025 o 0.1496 o 8 0.0025 0.0025 o 0.1331 o 9 0.0025 0.0025 o 0.1179 o 10 0.0025 0.0025 o 0.1036 o 11 0.0025 0.0025 o 0.09 o 12 0.0025 0.0025 o 0.077 o 13 0.0025 0.0025 o 0.0645 o 14 0.0025 0.0025 o 0.0523 o 15 0.0025 0.0025 o 0.0404 o 16 0.0025 0.0025 o 0.0287 o 17 0.0025 0.0025 o 0.0172 o 18 0.0025 0.0025 o 0.0057 o 19 0.0025 0.0025 o 20 0.0025 0.0025 o 21 0.0025 0.0025 o 22 0.0025 0.0025 o 23 0.0025 0.0025 o 24 0.0025 0.0025 o 25 0.0025 0.0025 o 26 0.0025 0.0025 o 27 0.0025 0.0025 o 28 0.0025 0.0025 o 29 0.0025 0.0025 o 30 0.0025 0.0025 o 31 0.0025 0.0025 o 32 0.0025 0.0025 o 33 0.0025 0.0025 o 34 0.0025 0.0025 o 35 0.0025 0.0025 o 36 0.011 0.0025 -0.0085
=
Sum of b values 0.0034578 Sample Standard Deviation = 0.00141667
=
W Statistic 0.170214 5% Critical value of 0.935 exceeds 0.170214 Evidence of non-normality at 95% level of significance 1% Critical value of 0.912 exceeds 0.170214 Evidence of non-normality at 99% level of significance
Kruskal-Wallis Non-Parametric Test Parameter: Cadmium Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL Kruskal Wallis Ranks Background Wells WelllD Date Result Rank GWA-15/MW-157/30/2002 BQLO.0025 18 9/24/2002 BQLO.0025 18 10/21/2002 - BQLO.0025 18 12/3/2002 BQLO.0025 18 6/24/2003 BQLO.0025 18 12/17/2003 BQLO.0025 18
=
Rank Sum 108 Rank Mean 18= GWA-7/MW-7 7/30/2002 - BQLO.0025 18 9/24/2002 BQLO.0025 18 10/21/2002 BQLO.0025 18 12/3/2002 BQLO.0025 18 6/24/2003 BQLO.0025 18 12/17/2003 BQLO.0025 18
=
Rank Sum 108 Rank Mean 18 = Background Rank Sum 216 = Background Rank Mean 18 = Compliance Wells WelllD Date Result Rank GWB-6/MW-6 7/30/2002 BQLO.0025 18 9/24/2002 BQLO.0025 18 10/21/2002 BQLO.0025 18 12/3/2002 BQLO.0025 18 6/24/2003 BQLO.0025 18 12/17/2003 BQLO.0025 18 Rank Sum 108= Rank Mean 18 = GWC-13/MW-137/30/2002 BQLO.0025 18 9/24/2002 BQLO.0025 18 10/21/2002 BQLO.0025 18 12/3/2002 BQLO.0025 18 6/24/2003 - BQLO.0025 18 12/17/2003 - BQLO.0025 18 Rank Sum 108= Rank Mean 18 = GWC-14/MW-147/30/2002 BQLO.0025 18 9/24/2002 - BQLO.0025 18 10/21/2002 BQLO.0025 18 12/3/2002 BQLO.0025 18
6/24/2003 BQLO.0025 18 12/17/2003 0.011 36
=
Rank Sum 126
=
Rank Mean 21 GWC-5/MW-5 7/30/2002 BQLO.0025 18 9/24/2002 BQLO.0025 18 10/21/2002 BQLO.0025 18 12/3/2002 BQLO.0025 18 6/24/2003 BQLO.0025 18 12/17/2003 BQLO.0025 18
=
Rank Sum 108
=
Rank Mean 18 Calculation Results:
=
Kruskal-Wallis H Statistic 0.405405
=
Kruskal-Wallis H Statistic (adjusted for tied non-detects) 5 95% Confidence comparison value is 9.48773 at 4 degrees of freedom 0.405405 < 9.48773 indicating no significant group difference at 5% significance level 5 < 9.48773 indicating no significant group difference at 5% significance level when adjusted for ties
Shapiro-Wilks Test of Normality Parameter: Chromium All Wells Normality Test of Parameter Concentrations Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL
=
K 18; Samples 36 = i xCi) x(n-i+1) x(n-1 +1 )-x(i)a(n-i+1) b(i) 1 0.005 0.091 0.086 0.4068 0.0349848 2 0.005 0.028 0.023 0.2813 0.0064699 3 0.005 0.01 0.005 0.2415 0.0012075 4 0.005 0.01 0.005 0.2121 0.0010605 5 0.005 0.01 0.005 0.1883 0.0009415 6 0.005 0.01 0.005 0.1678 0.000839 7 0.01 0.01 o 0.1496 o 8 0.01 0.01 o 0.1331 o 9 0.01 0.01 o 0.1179 o 10 0.01 0.01 o 0.1036 o 11 0.01 0.01 o 0.09 o 12 0.01 0.01 o 0.077 o 13 0.01 0.01 o 0.0645 o 14 0.01 0.01 o 0.0523 o 15 0.01 0.01 o 0.0404 o 16 0.01 0.01 o 0.0287 o 17 0.01 0.01 o 0.0172 o 18 0.01 0.01 o 0.0057 o 19 0.01 0.01 o 20 0.01 0.01 o 21 0.01 0.01 o 22 0.01 0.01 o 23 0.01 0.01 o 24 0.01 0.01 o 25 0.01 0.01 o 26 0.01 0.01 o 27 0.01 0.01 o 28 0.01 0.01 o 29 0.01 0.01 o 30 0.01 0.01 o 31 0.01 0.005 -0.005 32 0.01 0.005 -0.005 33 0.01 0.005 -0.005 34 0.01 0.005 -0.005 35 0.028 0.005 -0.023 36 0.091 0.005 -0.086 Sum of b values = 0.0455032 Sample Standard Deviation = 0.0140436
=
W Statistic 0.299959 5% Critical value of 0.935 exceeds 0.299959 Evidence of non-normality at 95% level of significance 1% Critical value of 0.912 exceeds 0.299959 Evidence of non-normality at 99% level of significance
Kruskal-Wallis Non-Parametric Test Parameter: Chromium Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL Kruskal Wallis Ranks Background Wells WelllD Date Result Rank GWA-15/MW-157/30/2002 BQLO.01 17.5 9/24/2002 BQLO.01 17.5 10/21/2002 - BQLO.01 17.5 12/3/2002 BQLO.005 17.5 6/24/2003 BQLO.01 17.5 12/17/2003 BQLO.01 17.5
=
Rank Sum 105
=
Rank Mean 17.5 GWA-7/MW-7 7/30/2002 - BQLO.01 17.5 9/2412002 BQLO.01 17.5 10/21/2002 BQLO.01 17.5 1213/2002 BQLO.005 17.5 6/24/2003 BQLO.01 17.5 12/17/2003 BQLO.01 17.5 Rank Sum 105=
=
Rank Mean 17.5 Background Rank Sum 210 = Background Rank Mean 17.5= Compliance Wells WelllD Date Result Rank GWB-6/MW-6 7/30/2002 BQLO.01 17.5 9/24/2002 BQLO.01 17.5 10/21/2002 BQLO.01 17.5 12/3/2002 BQLO.005 17.5 6/24/2003 BQLO.01 17.5 12/17/2003 BQLO.01 17.5 Rank Sum 105=
=
Rank Mean 17.5 GWC-13/MW-137/30/2002 BQLO.01 17.5 9/24/2002 BQLO.01 17.5 10/21/2002 BQLO.01 17.5 12/3/2002 BQLO.005 17.5 6/24/2003 - BQLO.01 17.5 12/17/2003 - BQLO.01 17.5 Rank Sum 105=
=
Rank Mean 17.5 GWC-14/MW-147/30/2002 BQLO.01 17.5 9/24/2002 - BQLO.01 17.5 10/21/2002 BQLO.01 17.5 12/3/2002 BQLO.005 17.5
6/24/2003 BQlO.01 17.5 12/17/2003 0.091 36 Rank Sum = 123.5 Rank Mean = 20.5833 GWC-5/MW-5 7/30/2002 BQlO.01 17.5 9/24/2002 BQlO.01 17.5 10/21/2002 BQlO.01 17.5 12/3/2002 BQlO.005 17.5 6/24/2003 BQlO.01 17.5 12117/2003 0.028 35
=
Rank Sum 122.5 Rank Mean = 20.4167 Calculation Results:
=
Kruskal-Wallis H Statistic 0.649399 Kruskal-Wallis H Statistic (adjusted for tied non-detects) = 4.11905 95% Confidence comparison value is 9.48773 at 4 degrees of freedom 0.649399 < 9.48773 indicating no significant group difference at 5% significance level 4.11905 < 9.48773 indicating no significant group difference at 5% significance level when adjusted for ties
Shapiro-Wilks Test of Normality Parameter: Copper All Wells Normality Test of Parameter Concentrations Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL K = 18; Samples = 36 i x(i) x(n-i+1) x(n-1 +1 )-x(i)a(n-i+1) b(i) 1 0.01 0.035 0.025 0.4068 0.01017 2 0.01 0.026 0.016 0.2813 0.0045008 3 0.01 0.025 0.015 0.2415 0.0036225 4 0.01 0.0125 0.0025 0.2121 0.00053025 5 0.01 0.0125 0.0025 0.1883 0.00047075 6 0.01 0.0125 0.0025 0.1678 0.0004195 7 0.01 0.0125 0.0025 0.1496 0.000374 8 0.01 0.0125 0.0025 0.1331 0.00033275 9 0.01 0.0125 0.0025 0.1179 0.00029475 10 0.01 0.01 0 0.1036 0 11 0.01 0.01 0 0.09 0 12 0.01 0.01 0 0.077 0 13 0.01 0.01 0 0.0645 0 14 0.01 0.01 0 0.0523 0 15 0.01 0.01 0 0.0404 0 16 0.01 0.01 0 0.0287 0 17 0.01 0.01 0 0.0172 0 18 0.01 0.01 0 0.0057 0 19 0.01 0.01 0 20 0.01 0.01 0 21 0.01 0.01 0 22 0.01 0.01 0 23 0.01 0.01 0 24 0.01 0.01 0 25 0.01 0.01 0 26 0.01 0.01 0 27 0.01 0.01 0 28 0.0125 0.01 -0.0025 29 0.0125 0.01 -0.0025 30 0.0125 0.01 -0.0025 31 0.0125 0.01 -0.0025 32 0.0125 0.01 -0.0025 33 0.0125 0.01 -0.0025 34 0.025 0.01 -0.015 35 0.026 0.01 -0.016 36 0.035 0.01 -0.025
=
Sum of b values 0.0207153
=
Sample Standard Deviation 0.0053545 W Statistic = 0.427639 5% Critical value of 0.935 exceeds 0.427639 Evidence of non-normality at 95% level of significance 1% Critical value of 0.912 exceeds 0.427639 Evidence of non-normality at 99% level of significance
Kruskal-Wallis Non-Parametric Test Parameter: Copper Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL Kruskal Wallis Ranks Background Wells WelllD Date Result Rank GWA-15/MW-157/30/2002 BQLO.01 17 9/24/2002 BQLO.01 17 10/21/2002 - BQLO.01 17 12/3/2002 BQLO.0125 17 6/24/2003 BQLO.01 17 12/17/2003 BQLO.01 17
=
Rank Sum 102 Rank Mean 17= GWA-7/MW-7 7/30/2002- BQLO.01 17 9/24/2002 BQLO.01 17 10/21/2002 BQLO.01 17 12/3/2002 BQLO.0125 17 6/24/2003 0.035 36 12/17/2003 BQLO.01 17
=
Rank Sum 121
=
Rank Mean 20.1667 Background Rank Sum 223 = Background Rank Mean = 18.5833 Compliance Wells WelllD Date Result Rank GWB-6/MW-6 7/30/2002 BQLO.01 17 9/24/2002 BQLO.01 17 10/21/2002 BQLO.01 17 12/3/2002 BQLO.0125 17 6/24/2003 BQLO.01 17 12/17/2003 BQLO.01 17 Rank Sum = 102 Rank Mean 17 = GWC-13/MW-137/30/2002 BQLO.01 17 9/24/2002 BQLO.01 17 10/21/2002 BQLO.01 17 12/3/2002 BQLO.0125 17 6/24/2003 - BQLO.01 17 12/17/2003 - BQLO.01 17 Rank Sum = 102 Rank Mean 17 = GWC-14/MW-147/30/2002 BQLO.01 17 9/24/2002 - BQLO.01 17 10/21/2002 BQLO.01 17 12/3/2002 BQLO.0125 17
6/24/2003 BQLO.01 17 12117/2003 0.026 35 Rank Sum = 120
=
Rank Mean 20 GWC-5/MW-5 7/30/2002 BQLO.01 17 9/24/2002 BQLO.01 17 10/21/2002 BQLO.01 17 12/3/2002 BQLO.0125 17 6/24/2003 BQLO.01 17 12/17/2003 0.025 34
=
Rank Sum 119 Rank Mean = 19.8333 Calculation Results:
=
Kruskal-Wallis H Statistic 0.461712
=
Kruskal-Wallis H Statistic (adjusted for tied non-detects) 2.00868 95% Confidence comparison value is 9.48773 at 4 degrees of freedom 0.461712 < 9.48773 indicating no significant group difference at 5% significance level 2.00868 < 9.48773 indicating no significant group difference at 5% significance level when adjusted for ties
Shapiro-Wilks Test of Normality Parameter: Lead All Wells Normality Test of Parameter Concentrations Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL
=
K 18; Samples 36 = i x(i) x(n-i+1 ) x(n-1 +1 )-x(i)a(n-i+1) b(i) 1 0.005 0.015 0.01 0.4068 0.004068 2 0.005 0.0075 0.0025 0.2813 0.00070325 3 0.005 0.0075 0.0025 0.2415 0.00060375 4 0.005 0.0075 0.0025 0.2121 0.00053025 5 0.005 0.0075 0.0025 0.1883 0.00047075 6 0.005 0.0075 0.0025 0.1678 0.0004195 7 0.005 0.0075 0.0025 0.1496 0.000374 8 0.005 0.005 o 0.1331 o 9 0.005 0.005 o 0.1179 o 10 0.005 0.005 o 0.1036 o 11 0.005 0.005 o 0.09 o 12 0.005 0.005 o 0.077 o 13 0.005 0.005 o 0.0645 o 14 0.005 0.005 o 0.0523 o 15 0.005 0.005 o 0.0404 o 16 0.005 0.005 o 0.0287 o 17 0.005 0.005 o 0.0172 o 18 0.005 0.005 o 0.0057 o 19 0.005 0.005 o 20 0.005 0.005 o 21 0.005 0.005 o 22 0.005 0.005 o 23 0.005 0.005 o 24 0.005 0.005 o 25 0.005 0.005 o 26 0.005 0.005 o 27 0.005 0.005 o 28 0.005 0.005 o 29 0.005 0.005 o 30 0.0075 0.005 -0.0025 31 0.0075 0.005 -0.0025 32 0.0075 0.005 -0.0025 33 0.0075 0.005 -0.0025 34 0.0075 0.005 -0.0025 35 0.0075 0.005 -0.0025 36 0.015 0.005 -0.01
=
Sum of b values 0.0071695
=
Sample Standard Deviation 0.00185271
=
W Statistic 0.427853 5% Critical value of 0.935 exceeds 0.427853 Evidence of non-normality at 95% level of significance 1% Critical value of 0.912 exceeds 0.427853 Evidence of non-normality at 99% level of significance
Kruskal-Wallis Non-Parametric Test Parameter: Lead Original Data (Not Transformed) Non-Detects Replaced with 1/2 Dl Kruskal Wallis Ranks Background Wells WelllD Date Result Rank GWA-1S/MW-1S7/30/2002 BQlO.OOS 18 9/24/2002 BQlO.OOS 18 10/21/2002 - BQlO.OOS 18 12/3/2002 BQlO.007S 18 6/24/2003 BQlO.OOS 18 12/17/2003 BQlO.OOS 18 Rank Sum = 108 Rank Mean = 18 GWA-7/MW-7 7/30/2002 - BQlO.OOS 18 9/24/2002 BQlO.OOS 18 10/21/2002 BQlO.OOS 18 12/3/2002 BQlO.007S 18 6/24/2003 BQlO.OOS 18 12/17/2003 BQlO.OOS 18 Rank Sum = 108 Rank Mean = 18 Background Rank Sum = 216 Background Rank Mean = 18 Compliance Wells WelllD Date Result Rank GWB-6/MW-6 7/30/2002 BQlO.OOS 18 9/2412002 BQlO.OOS 18 10/21/2002 BQlO.OOS 18 1213/2002 BQlO.007S 18 6/24/2003 BQlO.OOS 18 12/17/2003 BQlO.OOS 18 Rank Sum = 108 Rank Mean = 18 GWC-13/MW-137/30/2002 BQlO.OOS 18 9/24/2002 BQlO.OOS 18 10/21/2002 BQlO.OOS 18 12/3/2002 BQlO.007S 18 6/24/2003 - BQlO.OOS 18 12117/2003 - BQlO.OOS 18 Rank Sum = 108 Rank Mean = 18 GWC-14/MW-147/30/2002 BQlO.OOS 18 9/24/2002 - BQlO.OOS 18 10/21/2002 BQlO.OOS 18 12/3/2002 BQlO.007S 18
6/24/2003 BOlO.005 18 12/17/2003 0.015 36 Rank Sum = 126 Rank Mean = 21 GWC-5/MW-5 7/30/2002 BOlO.005 18 9/24/2002 BOlO.005 18 10/21/2002 BOlO.005 18 12/3/2002 BOlO.00l5 18 6/24/2003 BOlO.005 18 12/17/2003 BOlO.005 18 Rank Sum = 108 Rank Mean = 18 Calculation Results:
=
Kruskal-Wallis H Statistic 0.405405
=
Kruskal-Wallis H Statistic (adjusted for tied non-detects) 5 95% Confidence comparison value is 9.48773 at 4 degrees of freedom 0.405405 < 9.48773 indicating no significant group difference at 5% significance level 5 < 9.48773 indicating no significant group difference at 5% significance level when adjusted for ties
Shapiro-Wilks Test of Normality Parameter: Nickel All Wells Normality Test of Parameter Concentrations Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL
=
K 18; Samples 36 = i xCi) x(n-i+1) x(n-1 +1 )-x(i)a(n-i+1) b(i) 1 0.01 0.034 0.024 0.4068 0.0097632 2 0.01 0.02 0.01 0.2813 0.002813 3 0.01 0.02 0.01 0.2415 0.002415 4 0.01 0.02 0.01 0.2121 0.002121 5 0.01 0.02 0.01 0.1883 0.001883 6 0.01 0.02 0.01 0.1678 0.001678 7 0.01 0.02 0.01 0.1496 0.001496 8 0.01 0.01 o 0.1331 o 9 0.01 0.01 o 0.1179 o 10 0.01 0.01 o 0.1036 o 11 0.01 0.01 o 0.09 o 12 0.01 0.01 o 0.077 o 13 0.01 0.01 o 0.0645 o 14 0.01 0.01 o 0.0523 o 15 0.01 0.01 o 0.0404 o 16 0.01 0.01 o 0.0287 o 17 0.01 0.01 o 0.0172 o 18 0.01 0.01 o 0.0057 o 19 0.01 0.01 o 20 0.01 0.01 o 21 0.01 0.01 o 22 0.01 0.01 o 23 0.01 0.01 o 24 0.01 0.01 o 25 0.01 0.01 o 26 0.01 0.01 o 27 0.01 0.01 o 28 0.01 0.01 o 29 0.01 0.01 o 30 0.02 0.01 -0.01 31 0.02 0.01 -0.01 32 0.02 0.01 -0.01 33 0.02 0.01 -0.01 34 0.02 0.01 -0.01 35 0.02 0.01 -0.01 36 0.034 0.01 -0.024 Sum of b values = 0.0221692
=
Sample Standard Deviation 0.0052915 W Statistic = 0.501503 5% Critical value of 0.935 exceeds 0.501503 Evidence of non-normality at 95% level of significance 1% Critical value of 0.912 exceeds 0.501503 Evidence of non-normality at 99% level of significance
Kruskal-Wallis Non-Parametric Test Parameter: Nickel Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL Kruskal Wallis Ranks Background Wells WelllD Date Result Rank GWA-15/MW-157/30/2002 BQLO.01 18 9/24/2002 BQLO.01 18 10/21/2002 - BQLO.01 18 12/3/2002 BQLO.02 18 6/24/2003 BQLO.01 18 12/17/2003 BQLO.01 18
=
Rank Sum 108 Rank Mean 18= GWA-7/MW-7 7/30/2002 - BQLO.01 18 9/24/2002 BQLO.01 18 10/21/2002 BQLO.01 18 12/3/2002 BQLO.02 18 6/24/2003 BQLO.01 18 12/17/2003 BQLO.01 18
=
Rank Sum 108 Rank Mean 18= Background Rank Sum 216 = Background Rank Mean 18 = Compliance Wells WelllD Date Result Rank GWB-6/MW-6 7/30/2002 BQLO.01 18 9/24/2002 BQLO.01 18 10/21/2002 BQLO.01 18 1213/2002 BQLO.02 18 6/24/2003 BQLO.01 18 12/17/2003 BQLO.01 18 Rank Sum 108= Rank Mean 18 = GWC-13/MW-137/30/2002 BQLO.01 18 9/24/2002 BQLO.01 18 10/21/2002 BQLO.01 18 1213/2002 BQLO.02 18 6/24/2003 - BQLO.01 18 12/17/2003 - BQLO.01 18 Rank Sum 108= Rank Mean 18 = GWC-14/MW-147/30/2002 BQLO.01 18 9/24/2002 - BQLO.01 18 10/21/2002 BQLO.01 18 12/3/2002 BQLO.02 18
6/24/2003 BQLO.01 18 12/17/2003 0.034 36 Rank Sum = 126 Rank Mean = 21 GWC-5/MW-5 7/30/2002 BQLO.01 18 9/24/2002 BQLO.01 18 10/21/2002 BQLO.01 18 12/3/2002 BQLO.02 18 6/24/2003 BQLO.01 18 12/17/2003 BQLO.01 18 Rank Sum = 108 Rank Mean = 18 Calculation Results:
=
Kruskal-Wallis H Statistic 0.405405 Kruskal-Wallis H Statistic (adjusted for tied non-detects) = 5 95% Confidence comparison value is 9.48773 at 4 degrees of freedom 0.405405 < 9.48773 indicating no significant group difference at 5% significance level 5 < 9.48773 indicating no significant group difference at 5% significance level when adjusted for ties
Shapiro-Wilks Test of Normality Parameter: Vanadium All Wells Normality Test of Parameter Concentrations Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL
=
K 18; Samples 36 = i x(i) x(n-i+1) x(n-1 +1 )-x(i)a(n-i+1) b(i) 1 0.005 0.06 0.055 0.4068 0.022374 2 0.005 0.025 0.02 0.2813 0.005626 3 0.005 0.025 0.02 0.2415 0.00483 4 0.005 0.025 0.02 0.2121 0.004242 5 0.005 0.025 0.02 0.1883 0.003766 6 0.005 0.025 0.02 0.1678 0.003356 7 0.025 0.025 0 0.1496 0 8 0.025 0.025 0 0.1331 0 9 0.025 0.025 0 0.1179 0 10 0.025 0.025 0 0.1036 0 11 0.025 0.025 0 0.09 0 12 0.025 0.025 0 0.077 0 13 0.025 0.025 0 0.0645 0 14 0.025 0.025 0 0.0523 0 15 0.025 0.025 0 0.0404 0 16 0.025 0.025 0 0.0287 0 17 0.025 0.025 0 0.0172 0 18 0.025 0.025 0 0.0057 0 19 0.025 0.025 0 20 0.025 0.025 0 21 0.025 0.025 0 22 0.025 0.025 0 23 0.025 0.025 0 24 0.025 0.025 0 25 0.025 0.025 0 26 0.025 0.025 0 27 0.025 0.025 0 28 0.025 0.025 0 29 0.025 0.025 0 30 0.025 0.025 0 31 0.025 0.005 -0.02 32 0.025 0.005 -0.02 33 0.025 0.005 -0.02 34 0.025 0.005 -0.02 35 0.025 0.005 -0.02 36 0.06 0.005 -0.055 ,'.~.'.' W** ___ *,.*AW~*.~WA_._.' __", ,,,-*,*_~*___ ______
~,,,_,_,*",_**_'~"' ___
YN~.'~'~'_A
'-'-***'*'--_"*'.~=~'_~V~ *~ _ _V_ _.*__ .'~. ___*"_*___ .*~*'*'~~"O_~"~"""" __ *_"_"_"~~_~m~_'_", .-. _ '_._ "~'A_'~.~_"y.,~~,w~,
Sum of b values = 0.044194 Sample Standard Deviation 0.00989127 = W Statistic 0.570367 = 5% Critical value of 0.935 exceeds 0.570367 Evidence of non-normality at 95% level of significance 1% Critical value of 0.912 exceeds 0.570367 Evidence of non-normality at 99% level of significance
Kruskal-Wallis Non-Parametric Test Parameter: Vanadium Original Data (Not Transformed) Non-Detects Replaced with 1/2 Dl Kruskal Wallis Ranks Background Wells WelllD Date Result Rank GWA-15/MW-157/30/2002 BQlO.025 18 9/24/2002 BQlO.025 18 10/21/2002 - BQlO.025 18 12/3/2002 BQlO.005 18 6/24/2003 BQlO.025 18 12/17/2003 BQlO.025 18 Rank Sum = 108 Rank Mean = 18 GWA-7/MW-7 7/30/2002 - BQlO.025 18 9/24/2002 BQlO.025 18 10/21/2002 BQlO.025 18 12/3/2002 BQlO.005 18 6/24/2003 BQlO.025 18 12/17/2003 BQlO.025 18 Rank Sum = 108 Rank Mean =18 Background Rank Sum =216 Background Rank Mean =18 Compliance Wells WelllD Date Result Rank GWB-6/MW-6 7/30/2002 BQlO.025 18 9/24/2002 BQlO.025 18 10/21/2002 BQlO.025 18 12/3/2002 BQlO.005 18 6/24/2003 BQlO.025 18 12/17/2003 BQlO.025 18 Rank Sum =108 Rank Mean =18 GWC-13/MW-137/30/2002 BQlO.025 18 9/24/2002 BQlO.025 18 10/21/2002 BQlO.025 18 12/3/2002 BQlO.005 18 6/24/2003 - BQlO.025 18 12/17/2003 - BQlO.025 18 Rank Sum = 108 Rank Mean =18 GWC-14/MW-147/30/2002 BQlO.025 18 9/24/2002 - BQlO.025 18 10/21/2002 BQlO.025 18 12/3/2002 BQlO.005 18
6/24/2003 BQlO.025 18 12/17/2003 0.06 36 Rank Sum = 126 Rank Mean = 21 GWC-5/MW-5 7/30/2002 BQlO.025 18 9/24/2002 BQlO.025 18 10/21/2002 BQlO.025 18 12/3/2002 BQlO.005 18 6/24/2003 BQlO.025 18 12/17/2003 BQlO.025 18 Rank Sum = 108 Rank Mean = 18 Calculation Results:
=
Kruskal-Wallis H Statistic 0.405405
=
Kruskal-Wallis H Statistic (adjusted for tied non-detects) 5 95% Confidence comparison value is 9.48773 at 4 degrees of freedom 0.405405 < 9.48773 indicating no significant group difference at 5% significance level 5 < 9.48773 indicating no significant group difference at 5% significance level when adjusted for ties
Shapiro-Wilks Test of Normality Parameter: Zinc All Wells Normality Test of Parameter Concentrations Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL
=
K 18; Samples 36 = i x(i) x(n-i+1) x(n-1 +1 )-x(i)a(n-i+1) b(i) 1 0.01 0.127 0.117 0.4068 0.0475956 2 0.01 0.034 0.024 0.2813 0.0067512 3 0.01 0.032 0.022 0.2415 0.005313 4 0.01 0.027 0.017 0.2121 0.0036057 5 0.01 0.027 0.017 0.1883 0.0032011 6 0.01 0.023 0.013 0.1678 0.0021814 7 0.01 0.023 0.013 0.1496 0.0019448 8 0.01 0.01 o 0.1331 o 9 0.01 0.01 o 0.1179 o 10 0.01 0.01 o 0.1036 o 11 0.01 0.01 o 0.09 o 12 0.01 0.01 o 0.077 o 13 0.01 0.01 o 0.0645 o 14 0.01 0.01 o 0.0523 o 15 0.01 0.01 o 0.0404 o 16 0.01 0.01 o 0.0287 o 17 0.01 0.01 o 0.0172 o 18 0.01 0.01 o 0.0057 o 19 0.01 0.01 o 20 0.01 0.01 o 21 0.01 0.01 o 22 0.01 0.01 o 23 0.01 0.01 o 24 0.01 0.01 o 25 0.01 0.01 o 26 0.01 0.01 o 27 0.01 0.01 o 28 0.01 0.01 o 29 0.01 0.01 o 30 0.023 0.01 -0.013 31 0.023 0.01 -0.013 32 0.027 0.01 -0.017 33 0.027 0.01 -0.017 34 0.032 0.01 -0.022 35 0.034 0.01 -0.024 36 0.127 0.01 -0.117
=
Sum of b values 0.0705928
=
Sample Standard Deviation 0.0202016
=
W Statistic 0.348885 5% Critical value of 0.935 exceeds 0.348885 Evidence of non-normality at 95% level of significance 1% Critical value of 0.912 exceeds 0.348885 Evidence of non-normality at 99% level of significance
Kruskal-Wallis Non-Parametric Test Parameter: Zinc Original Data (Not Transformed) Non-Detects Replaced with 1/2 DL Kruskal Wallis Ranks Background Wells WelllD Date Result Rank GWA-15/MW-157/30/2002 BQLO.01 15 9/24/2002 BQLO.01 15 10/21/2002 - BQLO.01 15 12/3/2002 BQLO.01 15 6/24/2003 BQLO.01 15 12/17/2003 BQLO.01 15 Rank Sum 90= Rank Mean 15= GWA-7/MW-7 7/30/2002- BQLO.01 15 9/24/2002 BQLO.01 15 10/21/2002 BQLO.01 15 12/3/2002 BQLO.01 15 6/24/2003 0.034 35 12/17/2003 0.023 30
=
Rank Sum 125
=
Rank Mean 20.8333 Background Rank Sum 215 = Background Rank Mean = 17.9167 Compliance Wells WelllD Date Result Rank GWB-6/MW-6 7/30/2002 BQLO.01 15 9/24/2002 BQLO.01 15 10/21/2002 BQLO.01 15 12/3/2002 BQLO.01 15 6/24/2003 BQLO.01 15 12/17/2003 BQLO.01 15 Rank Sum = 90 Rank Mean 15 = GWC-13/MW-137/30/2002 BQLO.01 15 9/24/2002 0.023 31 10/21/2002 0.027 32 12/3/2002 0.027 33 6/24/2003 - BQLO.01 15 12/17/2003 - BQLO.01 15 Rank Sum 141=
=
Rank Mean 23.5 GWC-14/MW-147/30/2002 BQLO.01 15 9/24/2002 - BQLO.01 15 10/21/2002 BQLO.01 15 12/3/2002 BQLO.01 15
6/24/2003 BQLO.01 15 12/17/2003 0.127 36
=
Rank Sum 111
=
Rank Mean 18.5 GWC-5/MW-5 7/30/2002 BQLO.01 15 9/24/2002 BQLO.01 15 10/21/2002 BQLO.01 15 12/3/2002 BQLO.01 15 6/24/2003 BQLO.01 15 12/17/2003 0.032 34
=
Rank Sum 109
=
Rank Mean 18.1667 Calculation Results:
=
Kruskal-Wallis H Statistic 2.05631 Kruskal-Wallis H Statistic (adjusted for tied non-detects) = 4.3066 95% Confidence comparison value is 9.48773 at 4 degrees of freedom 2.05631 < 9.48773 indicating no significant group difference at 5% significance level 4.3066 < 9.48773 indicating no significant group difference at 5% significance level when adjusted for ties}}