ML070400312
| ML070400312 | |
| Person / Time | |
|---|---|
| Site: | Indian Point  |
| Issue date: | 12/07/2006 |
| From: | Donahue P Entergy Nuclear Northeast |
| To: | Rice T NRC/FSME, State of NY, Dept of Environmental Conservation |
| References | |
| FOIA/PA-2007-0080 | |
| Download: ML070400312 (12) | |
Text
,Listing ot PUJB samples & MSDS's tor Tracer Dyes Page I otlI John White - Listing of PCB samples & MSDS's for Tracer Dyes From: "Donahue, Patrick J" <PDonahu@entergy.com>
To: <tbrice@gw.dec.state.ny.us>
Date: 12/07/2006 2:48 PM
Subject:
Listing of PCB samples & MSDS's for Tracer Dyes CC: "Adler, Joseph J." <jadler@entergy.com>, "Hollenbeck, Peter" <pholl91 @entergy.com>,
"Sachatello, Ronald" <rsach90 @entergy.com>, <jrw 1@nrc.gov>, "Mayer, Donald M"
<DMayerl @entergy.com>
Tim, Attached is a table with pcb samples taken to date for the purposes of the groundwater project and for meeting a commitment to sample certain wells for the purposes of renewing the Unit 2 Mixed Waste Permit..
Also attached are the msds sheets for the three dyes to be used for the tracer test. I was incorrect on the name Uranine. Apparently that is the aka for Fluorescine. So the three dyes to be used are Fluorescine, Eosine, and Rhodamine.
I spoke with GZA and we will measure the depth of the oil in MW-33, 34 and 35 on Monday, collect samples for PCB analysis and fingerprinting, and remove any remaining standing oil from these wells.
<<Summary of Well PCB Results.xls>> <<Rhodamine WT MSDS.pdf>> <<Eosine MSDS.pdf>> <<Fluorescein MSDS.pdf>>
Regards, Sr. HP/Chemistry Specialist Entergy Nuclear Northeast Indian Point Energy Center 450 Broadway, Suite 3 Buchanan, NY 10511 pdonahu@entergy.com (914) 736-8405 Voice (914) 734-6247 Fax This e-mail and any attachments thereto are intended only for the use by the addressee(s) named herein and containproprietaryand confidential information. If you are not the intended recipientof this e-mail, you are hereby notified that any dissemination,distribution, or copying of this e-mail, and any attachments thereto, is strictlyprohibited.If you have received this e-mail in error,please immediately notify me by telephone and permanently delete the originaland any copy of any e-mail and any printout thereof.
file://C:\temp\GW }00001 .HTM 01/18/2007
iwonn wnite - H-noalamine wy i Mz~uz5.D raged Material Safety Data Sheet 16972 Rhodamine WT 20%
I CHEMCENTRAIdDyes & Pigments REVISION DATE: ............ 03/1912003 13395 Huron River Drive CHENTREC: ..................... 800-424-9300 Romulus, MI 48174 EMERGENCY: .................... 734-941-8235 SECTION I - IDENTIFICATION
.TPA _N A I. Material Safety Data Sheet S16972RhodamineWT 20%/,
VOLATILITY: ~ NIA i ~SECTION IV- FIRE AND EXPLOSION DATA FL~ASH PON:~NIA
~EXTINGUISHING MEDIA: _ Water fog, C02, or Dry chemicaL FIRE FIGHT PROCEDURES:_ F.ire Fieters should be equipped with self contained breathing app andturnou~t gear-~'>
UNUSUAL FIEHAZARD. __...Adequtue ventilation and clean up must be maintained to mninimii fume as~umulation.
SECTION V - REACTIVII DATA STABILITY:- - - " Stable Vet CONDITIONS TO AVOID: - N/A",
HAZARDOUS POLYMERIZATION: Does not occur
-POLYMERIZATIONTO.AVOID: N/A INCOMPATIBILITY: `-. . "." Unknown DECOMPOSMON'._ "_*_"
Carbon monoxideCarbon dioxideand oxides of Nitrogen.
- SECT1ON VI - HEALTH DATA THRESHOLD LIMIT VALUE:. Not established' Smay' OVER EXPOSURE EFFECTS:. Contat with eyes mhay result in severe irritation. Contact with ski result in irritation. Ingestion may result in gastric disturbances.
Inhalation of dust may irritate respiratory tract.
ii SECTION VII FIRST AID FIRST AID PROCEDURES: Flush eyes with flowing water at least 15 minutes. If irritation developconsult a physician. Wash affected skin areas thoroughly with soap and water. If istitation develops, consult a physician. Remove and launder contaxninated'clothing before reuse.
If swallowed, dilute with water and induce vomiting.. Get immediate medical attention.. Ifinhaled, mi fresh air. Aid in breathing, ifnecessary, and get medical attention.-
-NEVERGIVE FLUIDS OR INDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAS CONVULSIONS.- C
Flage "'I1 I~.nhn White - Hhodamine W I MbUS.Ddt Pq 1
_-I.
NMaterial Safety Data ShM 16972 Rhodamine WT 20*/
ADDITIONAL MEASURES. Eye wash fountains shoad be easily HANDLING AND STORAGE:. Keep away from excessive heat and i
ýkVENTILATION: . Local exhaust to control fumies SECTION IX - SPILL AND DIPOSAL I SPILL: - ', 1 Spills should be conained and placei WASTE DISPOSAL- Do not discharge into sewers or waat with local regulaioas.
177ý ~ SECTION X -TRANSPORTATIONODA PROPER SHIPPING NAME: . INK MATERIAL' ILZARD CLASS AND LABEL: L - MFR, PRO ITECT FROM ,FREE UN NUMBER:_ N/A REPORTAl3IFNQUAYN1WY:_....N/A I SECTION XI - AODD1ONAL INFORMA4 FOOT NOTES: : K '~ N
- This in.rformation i fursnish.d without warranty. representatim, or Icen, ac*ura*e*to the best ofCHEMCENTRAL Corporation's knwledge or obi CHEMCENTRAL Corporation tob cuae Th*' C*HEMCENTRALCorportion does not assume any legal resporsibl Customers are encouraged to conduct their own tests. Before using any;
-". . N/A=NotApplicable "
PAGE 3 of3
[John White - Hhodami.ne WI MSDS.pdf Page 4i Material Safety Data Sheet 16972 Rhodamine WT 20%
ADDITIONAL MEASURES: - Eye wash fountains should be easily accessible.
HANDLING AND STORAGE: Keep away from excessive heat and moisture. Keep containers closed.
VENTILATION:. Local exhaust to control fumes.
SECTiON IX - SPILL AND DISPOSAL DATA SPILL: .... Spills should be contained and placed in suitable containers.
WASTE DISPOSAL: - Do not discharge into sewers or waterways. Dispose of in accordance with local regulations.
SECTION X -TRANSPORTATION DATA PROPER SHIPPING NAME. - INK MATERIAL HAZARD CLASS AND LABEL: L - MFR, PROTECT FROM FREEZING UN NUMBER: - N/A REPORTABLE QUANTITY: -,. N/A SECTION XI - ADTIONAL INFORMATION FOOT NOTES:
This information is furnished without warranty, representation, or license of any kind, except that it is accurate to the best of CHEMCENTRAL Corporation's know ledge or obtained from sources believed by CHEMCENTRAL.Corporation to be accurate.
The CHEMCENTRAL Corporation does not assume any legal responsibility for use or reliance upon same.
Customers are encouraged to conduct their own tests. Before using any product, read its label.
N/A = Not Applicable PAGE 3 of3
John W hite - Eosine MSDS.pdf .. . ... ........... Page 1I Material Safety Data Sheet 15189 Eosine OJ 13395 Huron River Drive CHEMTREC: .......................... 800424-9300 Romulus, MI 48174 EMERGENCY:... .....734-941-8235 CHEMCENTRAIdDyes & Pigments REVISION DATE:...............914/02 SECTION I - IDENTIFICATION TRADE NAME:_-- ... .... _ 15189 Eosine OJ CHEMICAL NAME: .. ........ Acid Red 87 (Color Index Name)
CHEMICAL FAMILY: .... Xanthene CAS NUMBER: ............ Proprietary SECTION II- HAZARDOUS INGREDIENTS HAZARDOUS INGREDIENT PERCENT CAS NUMBER PEL None as per 29CFR part 1910.1200 or Sara Title III HMIS HAZARD RATINGS (if apnlicable):
HEALTH:.. ................ 2 FIRE ....... ................. I REACTIVITY ....................... 0 SECTION III-PHYSICAL DATA APPEARANCE: . Brownish Red Powder, No Odor BOILING POINT:__............... N/A MELTING POINT: ._...._.......... N/A FREEZING POINT: .............. N/A VAPOR PRESSURE:.-_........ N/A VAPOR DENSITY (AIR-I):.._... N/A SPECIFIC GRAVITY:_.......... Approximately I PH: ... . .. . . .... N/A SOLUBILITY IN WATER:-....... Complete VOLATILITY: .... ....... N/A SECTION IV- FIRE AND EXPLOSION DATA FLASH POINT:_............... N/A EXTINGUISHING MEDIA: ..... Water fog, C02, or Dry chemical.
FIRE FIGHT PROCEDURES: - Fire fighters should be equipped with self contained breathing apparatus and turnout gear.
UNUSUAL FIRE HAZARD: ...... Adequate ventilation and clean up must be maintained to minimize dust accumulation. May form explosive dust/air mixture.
IlJohn White - Eosine MSDS.Pdf Page 211 Material Safety Data Sheet 15189 Eosine OJ SECTION V -REACTIVITY DATA STABILITY: . .. .. Stable CONDITIONS TO AVOID: _._ Avoid contact with strong oidzers, excessive heat, sparks or open flames.
HAZARDOUS POLYMERIZATION: Does not occur POLYMERIZATION TO AVOID: N/A INCOMPATIBILITY: ..... Strong oxidizers DECOMPOSITION: _....
Thermal decomposition products may include toxic fumes of bromide and sodium.
SECTION VI - HEALTH DATA THRESHOLD LIMIT VALUE: Causes skin irritation. May be irritating to the respiratory tract and eyes. Oral-Mouse LDS0: 2344 MG/KG Intraperitioneal-Rat Ldlo: 500 mg/kg Mutagenic data (RTECSO Tumorigenic Carcinogen Status: Animal inadequate evidence (IARC GROUP-3)
OVER EXPOSURE EFFECTS:.. Contact with eyes may result in severe irritation. Contact with skin may result in irritation. Ingestion may result in gastric disturbances.
Inhalation of dust may irritate respiratory tract.
SECTION VII FIRST AID FIRST AID PROCEDURES: Flush eyes with flowing water at least 15 minutes. If irritation develops, consult a physician.. Wash affected skin areas thoroughly with soap and water. If irritation develops, consult a physician. Remove and launder contaminated clothing before reuse.
If swallowed. dilute with water and induce vomiting. Get immediate medical attention. If inhaled, move to fresh air. Aid in breathing, if necessary, and get medical attention.
"NEVER GIVE FLUIDS OR INDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAS CONVULSIONS.*
SECTION VilI EMPLOYEE PROTECTION RESPIRATORY PROTECTION: NIOSH/OSHA approved dust respirator as necessary.
PROTECTIVE GLOVES: ........ To prevent skin contact.
EYE PROTECTION: -.....
Goggles.
ADDITIONAL MEASURES: .._ Eye wash fountains should be easily accessible.
HANDLING AND STORAGE: . Keep away from excessive heat and moisture. Keep containers closed.
VENTILATION:_...... ........ Local exhaust to control dusts.
SECTION IX - SPILL AND DISPOSAL DATA SPILL: ............................ Spills should be contained and placed in suitable containers.
PAGE 2 of 3
Johon White - EosineMSDS.pd- l-'age ý,
Material Safety Data Sheet 15189 Eosine OJ WASTE DISPOSAL: Bury or incinerate in approved site or facility in accordance with local, State and Federal Regulations.
SECTION X - TRANSPORTATION DATA PROPER SHIPPING NAME: - INK MATERIAL HAZARD CLASS AND LABEL: MFR LABELONLY UN NUMBER. --.... N/A REPORTABLE QUANTITY: - N/A SECTION XI - ADDTIONAL INFORMATION FOOT NOTES: This information is furnished without warranty, representation, or license of any kind, except that it is accurate to the best ofCHEMCENTRAL Corporation's knowledge or obtained from sources believed by CHEMCENTRAL Corporation to be accurate.
The CHEMCENTRAL Corporation does not assume any legal responsibility for use or reliance upon same.
Customers are encouraged to conduct their own tests. Before using any product, read its label-N/A - Not applicable PAGE 3 of3
.1
J!John White - Fluorescein MSDS.pdf -age 111 Material Safety Data Sheet 15174 URANINE C CHEMCENTRAL/Dyes & Pigments REVISION DATE: ...................... 0112012003 13395 Huron River Drive CKEMTREC: ............................. 800-424-9300 R33uluroMI Riv Romulus, 48174 Drie EMERGENCY: ........................... 734-941-8235 SECTION I- IDENTIFICATION TRADE NAME: .......... 15174 URANINE C CHEMICAL NAME: ................... Acid Yellow 73 CHEMICAL FAMILY: ............... Xanthene CAS NUMBER: ........................... 518-47-8 SECTION 11- HAZARDOUS INGREDIENTS HAZARDOUS INGREDIENT PERCENT CAS NUMBER PEL None as per 29CFR part 1910.1200 or Sra Title III HMIS HAZARD RATINGS (if applicable):
HEALTH: ...................................... I FIRE ......................................... 0 REACTIVITY ............................ 0 SECTION III - PHYSICAL DATA APPEARANCE: ........................... Orange powder, no characteristic odor.
BOILING POINT: ........................ N/A MELTING POINT: ..................... N/A FREEZING POINT: ..................... N/A VAPOR PRESSURE: ................... N/A VAPOR DENSITY (AIR=I): ....... N/A SPECIFIC GRAVITY: ................ Approximately I pH: .............................................. N/A SOLUBILITY IN WATER: ......... Moderate VOLATILITY: ............................. N/A SECTION IV - FIRE AND EXPLOSION DATA FLASH POINT: ............................ N/A EXTINGUISHING MEDIA: ....... Water fog, C02, or Dry chemical.
FIRE FIGHT PROCEDURES: ... Fire fighters should be equipped with self contained breathing apparatus and turnout gear.
UNUSUAL FIRE HAZARD: ...... Adequate ventilation and clean up must be maintained to minimize dust accumulation. May form explosive dust/air mixture.
PAGE 1 of 3
[1John White - Fluorescein MSDS.odf HaioR 211
[
Facle 2 11 I
Material Safety Data Sheet 15174 URANINE C SECTION V - REACTIVITY DATA STABILITY: ................................ Stable CONDITIONS TO AVOID: ...... N/A HAZARDOUS POLYMERIZATION: Does not occur POLYMERIZATION TO AVOID: N/A INCOMPATIBILITY: ................ Avoid contact with strong oxidizing agents DECOMPOSITION: .................... Carbon monoxide,Carbon dioxide,and oxides of Nitrogen and Sulfur.
SECTION VI - HEALTH DATA THRESHOLD LIMIT VALUE:.. Not Established OVER EXPOSURE EFFECTS: Contact with eyes may result in severe irritation. Contact with skin may result in irritation. Ingestion may result in gastric disturbances. Inhalation of dust may irritate respiratory tract.
SECTION VII FIRST AID FIRST AID PROCEDURES: Flush eyes with flowing water at least 15 minutes. If irritation develops, consult a physician. Wash affected skin areas thoroughly with soap and water. If irritation develops, consult a physician. Remove and launder contaminated clothing before reuse.
If swallowed, dilute with water and induce vomiting. Get immediate medical attention. If inhaled, move to fresh air. Aid in breathing, if necessary, and get medical attention.
- SECTION VIII EMPLOYEE PROTECTION RESPIRATORY PROTECTION: NIOSH/OSHA approved dust respirator as necessary.
PROTECTIVE GLOVES: ........... To prevent skin contact.
EYE PROTECTION: ............... Goggles.
ADDITIONAL MEASURES: ..... Eye wash fountains should be easily accessible.
HANDLING AND STORAGE: ... Keep away from excessive heat and moisture. Keep containers closed.
VENTILATION: ........................... Local exhaust to control dusts.
SECTION IX - SPILL AND DISPOSAL DATA SPILL: .......................................... Spills should be contained and placed in suitable containers.
WASTE DISPOSAL: .................... Do not discharge into sewers or waterways. Dispose of in accordance with local regulations.
PAGE 2 of 3
John White -Fluorescein MSDS.pdf 1ý Paqe 3 11 I~John White -Fluorescein MSDS.Ddf Page 311 Material Safety Data Sheet 15174 URANINE C-SECTION X - TRANSPORTATION DATA 77 PROPER SHIPPING NAME: ..... INK MATERIAL HAZARD CLASS AND LABEL: MFR LABEL ONLY UN NUMBER: .............................. N/A REPORTABLE QUANTITY: ..... N/A SECTION XI, ADDTIONAL INFORMATION FOOT NOTES: This information is furnished without warranty, representation, or license of any kind, except that it is accurate to the best of CHEMCENTRAL Corporation's knowledge or obtained from sources believed by CHEMCENTRAL Corporation to be accurate.
The CHEMCENTRAL Corporation does not assume any legal responsibility for use or reliance upon same.
Customers are encouraged to conduct their own tests. Before using any product, read its label.
PAGE 3 of 3
MONITOR WELL PCB SAMPLING & ANALYSIS 4 F-
- '-WELL NO:,ý DATE COLLECTED SAMPLE DEPTH _RESULTS (ppb) Arochlor MW-1ill 1-2/08/2005 _ : *- ,__ _ <0.061 na MW-50 03/22/2006 42' <0.062 na MW-50 03/22/2006 67' <0.063 na, MW-49 03/22/2006 25.5W <0.067 na MW-49 Q3/22/2006 -.42'E <-..0.064 na MW-49 03/22/2006 65.5' <0.098 na MW-42 03/23/2006 49' <0.098 na MW-42 03/24/2006 78' <0.064 na MW-36 03/23/2006 261 <0.063 na MW-36 03/23/2006 52' <0.062 na MW-37 03/29/2006 22'. <0.069 :na MW-37 03/29/2006 32' <0.065 na, MW-37 03/29/2006 40' <0.066 na MW-37 03/29/2006 57' <0.066 na CSS " , 04/27/2006 Bottom 0.242 1254 CSS 11/03/2006 Bottom (<6" water) 0.52 1254 MW-i 08 05/05/2006 13' false positive 0.124 1254 MW-109 05/05/2006 13' <0.061 na MW-108 05/13/2006 13', <0.061 .:,,na MW-109 05/13/2006 13' <0.061 na MW-108 05/18/2006 13' <0.066 na MW-108 05/18/2006 13' <0.066 na MW-53 08/23/2006 80' <0.065 na MW-53 08/23/2006 120' <0.065 na MW-55 08/25/2006 <0.065 na MW-57 08/24/2006 45' <0.065 na MW-58 MW-54 09/07/2006 206 <0.065 MW-56 ' 09/08/2006 , 85' .<0.065 MW-59 09/15/2006 <0.066 MW-60 MW-61 MW-62 __*_ _ '__
MW-63 10/02/2006 53.5' <0.061 MW-63 10/02/2006 93' <0.061 MW-63 10/02/2006 191' <0.061 MW-65 09/08/2006 80' <0.065 MH8 09/07/2006 ," ...... _ <0.065 "_,
MH17 09/07/2006 <0.065 DEC commitment is related to the renewal of the Unit 2 MW Storage Permit.
Yellow hilicihtina denotes those wells still requirinq PCB analysis. Samples will be drawn when wells
DEC Commitment DEC Commitment DEC Commitment DEC Commitment DEC Commitment DEC Commitment DEC Commitment DEC Commitment DEC Commitment DEC Commitment DEC Commitment XFMR Yard XFMR Yard