Text

VYNPS Air Emissions Record-Keeping Logs and Waste Oil Analyses
	ML061770490
Person / Time
Site:	Vermont Yankee File:NorthStar Vermont Yankee icon.png; (DPR-028)
Issue date:	01/19/2005
From:	; - No Known Affiliation
To:	; Office of Nuclear Reactor Regulation
References
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	Download: ML061770490 (76)
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VY AIR EMISSIONS RECORDKEEPING-2001 H

House Heating Boilers I an'wl Tons Period 1/1-1/31/2001 2/1-2/29/2001 2/23/2001 3/1-3/31/2001 3/1-3/31/2001 3/1-3/31/2001 4/1-4/30/2001 5/1-5/31/2001 6/1-6/30/2001 7/1-7/31/2001 8/1-8/31/2001 9/1-9/30/2001 10/1-10/31/2001 11/1-11/30/2001 12/1-12/31/2001 12/1-12/31/2001 Totals Average Waste Oil Burner Period 2/1-2/28/2001 7/3/2001 11/1-11/30/2001 12/1-12/31/2001 Gallons Used % Sulfur lb/kgal, S lb/kgal, Ott Total Tons 50000 50000 4000 39000 7500 4500 21000 6700 0

0 0

0 14501 34000 34500 5500 271201 0.0689 0.0689 0.041 0.09324 0.10216 0.12 0.12 0.12 0

0 0

0 0.1 0.1 0.05 0.0292 9.92 9.92 5.90 13.43 14.71 17.28 17.28 17.28 0.00 0.00 0.00 0.00 14.40 14.40 7.20 4.20 27.29 27.29 27.29 27.29 27.29 27.29 27.29 27.29 27.29 27.29 27.29 27.29 27.29 27.29 27.29 27.29 0.93 0.93 0.65 0.79 0.82 0.17 0.47 0.15 0.00 0.00 0.00 0.00 0.30 0.71 0.59 0.09 6.60 HHB Emission factors from EPA AP-42 Section 1.3 lb/1 000 gal S02 142*%S S03 2*%S NOx 20 Part.

2 CO 5

VOC 0.252 Trace Metals 0.038 0.06 Note: Started using 70/30 #2/Kerosene December 2000 Waste oil Emission factors from EPA AP-42 Section 1.11 Ib/1000 gal Sox 107*%S NOx 16 Part.

41.6 CO 2.1 0.1 Trace Metals 0.63 OPT OUT PROVISION DIESEL HOUR METER READINGS Gallons Used 399.7 1.62 1431.26 1431.26

% Sulfur 1.31 1.31 1.31 1.31 lb/kgal, S 188.64 188.64 188.64 188.64 lb/kgal, Ott Total Tons 60.43 0.05 60.43 0.0002 60.43 0.18 60.43 0 18 0

60.43 0

60.43 0.00 0.00 0.00 0.00 0.41 Totals 3263.84 VYAPF 015001 1/1/2001 Emergency Desiel Tank Vol= 38,500 gal 1,2502001 Delivery of 4Q00 gal 2 1 '2001 Delivery of 4000 gal 2,,22/2001 Delivery of 7500 gal 2, 23.2001 Delivery of 3500 gal 2,23/2001 Delivery of 7500 gal 904/2001 Delivery of 18000 gal VYAPF 0150.01 12/31/2001 Emergency Desiel Tank Vol= 52,500 gal JOHN DEERE Date A EDG Date B EDG Date 1042.1 12/11/2000 3743.1 12/18/2000 409.5 12/19/2000 1043.4 1/10/2001 3747.6 1/24/2001 416.4 1/22/2001 1048.6 2/14/2001 3758.9 2/21/2001 425.1 2/22/2001 1050 3/14/2001 3763.4 3/16/2001 429.6 3/17/2001 1051.3 4/11/2001 3768 4/26/2001 434.2 4/23/2001 1192.5 6/7/2001 3782.4 5/23/2001 443.7 5/18/2001 1194.4 6/28/2001 3786.9 6/24/2001 448.3 6/24/2001 1195.7 7/11/2001 3791.4 7/23/2001 452.8 7/24/2001 1197.1 8/15/2001 3795.8 8/20/2001 458.9 8/21/2001 1199.9 9/24/2001 3800.5 9/24/2001 463.5 9/25/2001 1201.3 10/11/2001 3826.5 10/28/2001 468.1 10/22/2001 1202.7 11/9/2001 3830.9 11/19/2001 472.5 11/19/2001 1205.3 12/13/2001 3835.9 12/26/2001 477 12/26/2001 163.2 92.8 67.51YR TOT

VY AIR EMISSIONS RECORDKEEPING-2002 Grand Total Tons 8,08 House Heating Boilers Period 1/1-1/31/2002" 2/1-2/29/2002*

3/1-3/31/2002*

3/1-3/31/2002"*

3/1-3/31/2002 4/1-4/30/2002 5/1-5/31/2002 6/1-6/30/2002 (LS) 7/1-7/31/2002 8/1-8/31/2002 9/1-9/30/2002 10/1-10/31/2002 11/1-11/30/2002 12/4/02 & 12/27/02**

12/1-12/31/2002 Totals Gallons Used % Sulfur lb/kgal, S Ib/kgal, Ott Total Tons 53303 43000 14500 25700 6600 24400 18600 2800 0

0 0

20979 46124 12804 43852 312662 0.15 0.15 0.15 0.20 0.27 0.27 0.27 0.1 21.6 21.6 21.6 28.8 38.88 38.88 38.88 14.4 0

0 0

33.12 33.12 28.8 33.12 27.29 27.29 27.29 27.29 27.29 27.29 27.29 27.29 27.29 27.29 27.29 27.29 27.29 27.29 27.29 1.30 1.05 0.35 0.41 0.85 0.81 0.62 0.06 0.00 0.00 0.00 0.63 1.39 0.36 1.32 9.16 HHB Emission factors from EPA AP-42 Section 1.3 lb/1000 gal S02 142*%S S03 2*%S NOx 20 Part.

2 CO 5

VOC 0.252 Trace Metals 0.038 0.23 0.23 0.20 0.23 Total with average °°Sulfur 312662 0.20 23.52 27.29 7.94 Used Oil Burner Period Gallons Used % Sulfur Ib/kgal, S lb/kgal, Ott Total Tons 01/01/02-01/31/02 325,2 1.31 188.64 60.43 0.04 11/01-11/30/2002 406.2 1.31 188.64 60.43 0.05 12/01-12/31/2002 409.2 1.31 188.64 60.43 0.05 0

60.43 0.00 0

60.43 0.00 Totals 1140.6 0.14 (LS) indicates Low sulfur diesel was delivered

(*) indicates a 50/50 #2/Kerosene mix was delivered

(*) indicates a 70/30 #2/Kerosene mix was delivered Waste oil Emission factors from EPA AP-42 Section 1.11 lb/1000 gal SOx 107*%S NOx 16 Part.

41.6 CO 2.1 0.1 Trace Metals 0.63 OPT OUT PROVISION DIESEL HOUR METER READINGS VYAPF 0150.01 1/1/2002 Emergency Diesel Tank Vol= 52,500 gal 6/4/2002 Delivery of 7500 gallons 6/10/2002 Delivery of 9500 gallons VYAPF 0150.01 12/31/2002 Emergency Diesel Tank Volume= 49,250 JOHN DEERE Date A EDG Date B EDG Date 1205.3 12/13/2001 3835.9 12/26/2001 477 12/26/2001 1206.5 1/16/2002 3840.5 1/21/2002 481,7 1/22/2002 1207.9 2/13/2002 3845.1 2/20/2002 486.4 2/22/2002 1209.2 3/12/2002 3849.5 3/16/2002 491.3 3/22/2002 1211.2 4/10/2002 3852.2 4/18/2002 493.8 4/18/2002 1212.5 5/15/2002 3854.6 5/18/2002 496.4 5/17/2002 1214.4 6/11/2002 3857.2 6/21/2002 498.9 6/21/2002 1217.1 7/10/2002 3861.4 7/25/2002 510.2 7/24/2002 1218.5 8/14/2002 3870.3 8/18/2002 518.9 8/20/2002 1220.3 9/11/2002 3872.8 9/24/2002 523.1 9/23/2002 1221.7 10/31/2002 3881.3 10/21/2002 528.2 10/21/2002 1222.9 11/14/2002 3883.8 11/12/2002 530.8 11/12/2002 1224.2 12/11/2002 3886.3 12/18/2002 533.3 12/18/2002 18.9 50.4 56.31YR TOT Total

VY AIR EMISSIONS RECORDKEEPING-2003 Grand Total Tons 7.84 House Heating Boilers Period 1/1-1/31/2003"*

1/17/2003 2/3/2003 02/01/03-02/28/03"*

3/1-3/31/2003*

3/ 8&31/2003 4/1-4/30/2003 5/1-5/31/2003 6/1-6/30/2003 7/1-7/31/2003 8/1-8/31/2003 9/1-9/30/2003 10/1-10/31/2003 11/1-11/30/2003 12/1-12/31/2003 Gallons Used 55517 6500 6750 43500 40900 15007 33800 12500 0

0 0

0 25402 33904 51411

% Sulfur lb/kgal, S lb/kgal, Ott Total Tons 0.03 0.04 0.04 0.03 0.03 0.04 0.04 0.04 4.

5..

5.7 4.3 5.-

5.7 5.7 32 27.29 76 27.29 76 27.29 32 27.29 32 27.29 76 27.29 76 27.29 76 27.29 0

27.29 0

27.29 B4 27.29 14 27.29 12 27.29 0.88 0.11 0.11 0.69 0.69 0.68 0.56 0.21 0.00 0.00 0.00 0.00 0.81 1.10 1.69 HHB Emission factors from EPA AP-42 Section 1.3 lb/1 000 gal S02 142*%S S03 2*%S NOx 20 Part.

2 CO 5

VOC 0.252 Trace Metals 0.038 0.256 0.261 0.268 36.86 37.58 38.59 Totals 325191 7.52 Average 0.10 10.32 27.29 Waste Oil Burners Period Gallons Used

% Sulfur lb/kgal, S lb/kgal, Ott Total Tons 2/8-25/03 421 1.31 140.17 60.43 0.04 2/10/03-3/21/03 686 1.31 188.64 60.43 0.09 3/13-28/03 379 1.31 188.64 60.43 0.05 10/20/03-12/31/03 1106 1.31 188.64 60.43 0.14 Totals 2592 0.32

() indicates a 50/50 #2/Kerosene mix was delivered

(**) indicates a 70/30 #2/Kerosene mix was delivered Waste oil Emission factors from EPA AP-42 Section 1.11 lb/1 000 gal SOx 107*%S NOx 16 Part.

41.6 CO 2.1 0.1 Trace Metals 0.63 OPT OUT PROVISION DIESEL HOUR METER READINGS VYAPF 0150.01 1/1/2003 Emergency Desiel Tank Vol= 49,000 gal 5/7/2003 Delivery of 17000 gallons VYAPF 0150.01 12/31/2003 Emergency Diesel Tank Volume= 53,000 53000-49000+17000 JOHN DEERE Date A EDG Date B EDG Date 1224.2 12/11/2002 3886.3 12/18/2002 533.3 12/18/2002 1225.4 1/15/2003 3888.8 1/16/2003 535.8 1/16/2003 1226.7 2/13/2003 3891.6 2/20/2003 538.6 2/20/2003 1227.9 3/12/2003 3895.4 3/28/2003 541.3 3/23/2003 1229.2 4/16/2003 3898 4/21/2003 543.9 4/22/2003 1230.6 5/14/2003 3900.6 5/20/2003 546.6 5/20/2003 1231.8 6/11/2003 3903.5 6/23/2003 551 6/25/2003 1233.2 7/16/2003 3906.2 7/21/2003 553.7 7/22/2003 1234.5 8/14/2003 3909.4 8/18/2003 556.5 8/19/2003 1235.9 9/10/2003 3912 9/21/2003 561.8 9/25/2003 1237.4 10/15/2003 3914.7 10/20/2003 564.3 10/21/2003 1238.7 11/12/2003 3917.3 11/23/2003 566.8 11/23/2003 1240 12/10/2003 3920.1 12/18/2003 569.5 12/18/2003 15.8 33.8 36.21YR TOT

VY AIR EMISSIONS RECORDKEEPING-2004 Grand Total Tns 7.43 House Heating Boilers Period 1/1-1/31/2004 01/10-31/2004*

02/01-20/2004"*

2/26/2004 03/01-31/2004 04/01-30/2004 05/01-30/2004 06/01-30/2004 07/01-31/2004 08/01-31/2004 09/01-30/2004 10/01-31/2004 11/01-30/2004 12/01-31/2004 Gallons Used 13506 50509 35300 7500 39301 26301 4501 0

0 0

3000 20106 33,805 53,014

% Sulfur lb/kgal, Sulfur lb/kgal, Other Total Tons 0.167 0.121 0.118 0.163 0.139 0.264 0.166 0.166 0.196 0.175 0.243 24.048 17.424 16&992 23.472 20.016 38.016 23.904 0

0 0

23.904 28&224 25.2 34.992 27.29 27.29 27.29 27.29 27.29 27.29 27.29 27,29 27.29 27.29 27.29 27.29 27.29 27.29 0.35 1.13 0.78 0.19 0.18 1.28 0.12 0.00 0.00 0.00 0.08 0.56 0.89 1.65 HHB Emission factors from EPA AP-42 Section 1.3 lb/1 000 gal S02 142*%S S03 2*%S NOx 20 Part.

2 CO 5

VOC 0.252 Trace Metals 0.038

(*) indicates a 50/50 #2/Kerosene mix was delivered

(**) indicates a 70/30 #2/Kerosene mix was delivered Waste oil Emission factors from EPA AP-42 Section 1.11 lb/1 000 gal SOx 107*%S NOx 16 Part.

41.6 CO 2.1 0.1 Trace Metals 0.63 Total 286,843 7.20 Waste Oil Burner Period 1/1/04 - 1/31/04 2/6/04 - 2/27/04 11/10/04 - 12/28/04 Gallons Used

% Sulfur 114.9 1.31 366.2 1.31 1,419.66 1.31 lb/kgal, S lb/kgal, Other Total T 188.64 60.43 188.64 60.43 188.64 60.43 ons 0.01 0.05 0,18 OPT OUT PROVISION DIESEL HOUR METER READINGS I otals 1,900.76 0.24 JDD Date A EDG Date B EDG Date JDD Date B EDG Date I

I VYA'AVF0150.01 i/2004 EmergencyDesielTankVolurne VV'APF 01 5001 1 2/31/2004 Emergency Diesel Tank Volume 53,000 52,000 1240 1241.3 1242.7 1244.1 1245.4 1246.7 1249.9 1253.8 1255.1 1256 1258 1259 1260 12/10/2003 1/14/2004 2/11/2004 3/10/2004 4/17/2004 5/12/2004 6/16/2004 7/23/2004 8/11/2004 9/15/2004 10/13/2004 11/14/2004 12/15/2004 3920.1 3922.9 3931.8 3934.2 3941.7 3944.3 3946.9 3949.5 3952 3945 3958 3960 3962.6 12/18/2003 1/19/2004 2/17/2004 3/23/2004 4/28/2004 5/23/2004 6/21/2004 7/17/2004 8/21/2004 9/24/2004 10/12/2004 11/14/2004 12/19/2004 569.5 571.9 580.8 583.4 590.6 593.1 595.8 598.2 602.4 604.9 607.4 610 613 12/18/2003 1/21/2004 2/19/2004 3/22/2004 4/27/2004 5/23/2004 6/22/2004 7/17/2004 8/21/2004 9/19/2004 10/13/2004 11/15/2004 12/19/2004 Fuel Delivery Dates Gallons delivered 71 2004 19,002 Tula estimated fiel consumption for 2004 20,002 20 i

42.5 i

43.51YR TOT

VY AIR EMISSIONS RECORDKEEPING-2005 Grand Total Tons 9.07 1

House Heating Boilers Period 1/1/05-1/31/05 2/1/05 - 2/28/05 3/1/05 - 3/31/05 4/1/05 - 4/30/05 5/1/05 - 5/31/05 6/1/05 - 6/30/05 7/1/05 - 7/30/05 8/1/05 - 8/31/05 9/1/05 - 9/30/05 10/1/05 - 10/31/05 11/1/05 - 11/30/05 12/1/05 - 12/31/05 average Gallons Used 48115 48407 41514 19200 19301 0

0 0

0 13302 32805 61709

% Sulfur lb/kgal, Sulfur 0.176 25.344 0.194 27.936 0.243 34.992 0.243 34.992 0.243 34.992 0.243 34.992 0.197 28.368 0.040 5.76 0.237 34.128 0.270 38.88 0.275 39.6 0.277 39.888 0.220 lb/kgal, Other Total Tons 27.29 27.29 27.29 27.29 27.29 27.29 27.29 27.29 27.29 27.29 27.29 27.29 1.27 1.34 1.29 0.60 0.60 0.00 0.00 0.00 0.00 0.44 1.10 2.07 HHB Emission factors from EPA AP-42 Section 1.3 lb/1 000 gal S02 142*%S S03 2*%S NOx 20 Part.

2 CO 5

VOC 0.252 Trace Metals 0.038

(*) indicates a 50/50 #2/Kerosene mix was delivered

(*) indicates a 70/30 #2/Kerosene mix was delivered Waste oil Emission factors from EPA AP-42 Section 1.11 lb/1 000 gal SOx 107*%S NOx 16 Part.

41.6 CO 2.1 0.1 Trace Metals 0.63 Total 284,353 8.70 Waste Oil Burner Period Gallons Used 2/12/2005-2/28/2005 2952.26 6/15/2005 1.36

% Sulfur 1.31 1.31 lb/kgal, S lb/kgal, Other Total Tons 188.64 60.43 0.37 188.64 44.43 0.00 OPT OUT PROVISION DIESEL HOUR METER READINGS Totals 2,953.62 0.37 JDD Date A EDG Date B EDG Date JDD Date Date I

I VYAPF 0150.01 1/1/2005 Emergency Desiel Tank Volume VYAPF 0150.01 12:31/2005 Emergency Diesel Tank Volume 53,000 55,979 1260.4 1261.7 1263.1 1265.2 1266.6 1268.3 1269.8 1271.2 1272.6 1273.9 1275.4 1286.2 1290.4 12/15/2004 1/12/2005 2/15/2005 3/16/2005 4/13/2005 5/11/2005 6/7/2005 7/13/2005 8/10/2005 9/14/2005 10/12/2005 11/16/2005 12/14/2005 3962.6 3965.15 3968.1 3973 3975.8 3978.4 3981.2 3984.1 3994.9 3997.6 3999.4 4007.3 4010.2 12/19/2004 1/17/2005 2/23/2005 3/21/2005 4/18/2005 5/22/2005 6/19/2005 7/18/2005 8/22/2005 9/19/2005 10/19/2005 11/20/2005 12/18/2005 613 616.7 619.3 621.3 626.6 629.2 631.9 634.2 644.8 647.3 650.1 654.9 659.5 12/19/2004 1/17/2005 2/23/2005 3/26/2005 4/19/2005 5/22/2005 6/19/2005 7/18/2005 8/24/2005 9/20/2005 10/19/2005 11/20/2005 12/21/2005 Fuel Delivery Dates Gallons delivered 6,29/2005 7,502 11/30'2005 15,001 oral estimated fuel consumption for 2005 19,524 gallons 30 i

47.6 T

46.51YR TOT

Analytical Report Client: TELEDYNE-VERMONT YANKEE W.O.#: 11699-600-005-9999-00 LVL#: 0203L244 Date Received: 03-22-02 INORGANIC NARRATIVE

1.

This narrative covers the analyses of 2 oil samples.

2.

The samples were prepared and analyzed in accordance with the methods indicated on the attached glossary.

3.

All results presented in this report are derived from samples that met LvLI's sample acceptance policy with the exception the cooler temperature and the label discrepancies noted on the Sample Receipt Checklist.

4.

Sample holding times as required by the method and/or contract were met.

5.

The method blanks were within the method criteria.

6.

The Laboratory Control Samples (LCS) were within the laboratory control limits.

7.

The matrix spike recoveries were within the 75-125% control limits.

8.

The replicate analysis for Total Halides was within the 20% Relative Percent Difference (RPD) control limit, however replicate analysis for Chloride was outside the control limit that may be attributed to sample inhomiogeneity.

9.

Results for oil samples are reported on a wet weight basis.

lain Daniels Date Laboratory Manager

[ *

l ]

Lionville Laboratory Incorporated

.APR 0 4.2002 njp'i03-244 u

The results presented in this report relate to the analytical testing and conditions of the samples upon receipt and during storage. All pages of this report are integral parts of the analytical data. Therefore. this report should only be reproduced in its entirety of It pages..'-.

I 208 Welsh Pool Road e Lionville, PA 19341-1333 e (610) 280-3000

Fax (610) 280-3041

Lionville Laboratory Incorporated WET CHEMISTRY METHODS GLOSSARY FOR SOIL/SOLIDS SAMPLE ANALYSIS ASTM SW846 OTHER

% Ash D2216-80

"% Moisture D2216-80

% Solids D2216-80

% Volatile Solids D2216-80 ASTM Extraction in Water D3987-81/85 BTU D240-87 CEC Chromium VI Corrosivity _

by coupon by pH Cyanide, Total Cyanide, Reactive Halides, Extractable Organic

~l~es, Total EP Toxicity Flash Point Ignitability Oil & Grease Carbon, Total Organic Oxygen Bomb Prep for Anions D240-87(mod)

Petroleum Hydrocarbons, Total Recoverable pH, Soil Sulfide, Reactive Sulfide Specific Gravity D1429-76C/

Sulfur, Total Synthetic Preparation Leach Paint Filter Other:

Method:

.er:

Method

ILMO4.0 (e)

ILMO4.0 (e) 9081 3060A/7196A 1110(mod) 9045C 9010B Section 7.3/9014 9020B V/9020B 1310A 1010 1010 9071A 9060 5050 9071 9045C

Section 7.3/9030B 9030B(mod)

D5057-90 C

ILMO4.0 (e)

EPA 600/4/84-008

/EPA 600/4/84-008 Lloyd Kahn (mod)

EPA 418.1 9056 1312 9095A EPA L-WI-034/B-01/01

~7~/

2.

Lionv ille Laboratory Incorporated METHOD REFERENCES AND DATA QUALIFIERS DATA QUALIFIERS U

Indicates that the parameter was not detected at or above the reported limit. The associated numerical value is the sample detection limit.

=

Indicates that the original sample result is greater than 4x the spike amount added.

AB3BREVIATIONS MB

= Method or Preparation Blank.

MS

= Matrix Spike.

MSD = Matrix Spike Duplicate.

REP = Sample Replicate LC Laboratory Control Sample.

NC = Not calculated.

A suffix of-R, -S, or -T following these codes indicate a replicate, spike or sample duplicate analysis respectively.

ANALYTI CAL WET CHEMISTRY METHODS I.

ASTM Standard Methods.

2.

USEPA Methods for Chemical Analysis of Water and Wastes (USEPA 60014 020).

.3.

Test Methods for Evaluating Solid Waste (USEPA SW-846).

a.

Standard Methods for the Examination of Water and Waste, 16 ed, (1983).

b.

Standard Methods for the Examination of Water and Waste, 17 ed, (1989)/1 8ed (1992).

c.

Method of Soil Analysis, Part 1, Physical and Mineralogical Methods, 2nd ed, (1986).

d.

Method of Soil Analysis, Part 2, Chemical and Microbiological Properties, Am.

Soc. Agron., Madison, W" (1965).

e.

USEPA Contract Laboratory Program, Statement of Work for Inorganic Analysis.

f.

Code of Federal Regulations.

L-WI-034/D-02/01 3

Lionville Laboratory, Inc.

INORGANICS DATA

SUMMARY

REPORT 03/27/02 CLIENT: TELEDYNE-VERMONT YANKEE WORK ORDER: 11699-600-00S-9999-00 LVL LOT #:

0203L244 SAMPLE

-001 SITE ID 1

ANALYTE Chloride by IC Total Halides RESULT 3.3 137 u

MG/KG MG/KG REPORTING LIMIT 1.2 137 DILUTION FACTOR 1.0 1.0

-002 2

Chloride by IC Total Halides 5.0 MG/KG 197 MG/KG 1.2 136 1.0 1.0 rt~

4

Lionville Laboratory, Inc.

INORGANICS METHOD BLANK DATA

SUMMARY

PAGE 03/27/02 CLIENT: TELEDYNE-VERMONT YANKEE WORK ORDER: 11699-600-005-9999-00 LVL LOT #:

0203L244 REPORTING RESULT UNITS LIMIT 1.2 u

MG/KG 1.2 SAMPLE BLANK10 SITE ID ANALYTE 02LICB23-MBI Chloride by IC DILUTION FACTOR 1.0 BLANK1 02LE004 -MBI BLANK2 02LE004-MB2 Total Halides Total Halides 20.0 u

MG/KG 20.0 u

MG/KG 20.0 20.0 1.0 1.0 ce' 5

Lionville Laboratory, Inc.

INORGANICS ACCURACY REPORT 03/27/02 CLIENT: TELEDYNE-VERMONT YANKEE WORK ORDER: 11699-600-005-9999-00 LVL LOT #:

0203L244 SAMPLE

-001

-002 BLANK10 LCS1 LCS2 SITE ID 1

2 02LICB23-MB1 02LE004-LC1 02LE004-LC2 ANALYTE Total Halides Chloride by IC Chloride by IC Total Halides Total Halides SPIKED SAMPLE 3200 30.8 24.8 477 490 INITIAL RESULT 28.9 5.0 1.2 -u 20.0 u 20.0 u SPIKED AMOUNT

%RECOV 3420 92.6 25.0 102.9 25.0 99.0 500 95.5 500 97.9 DILUTION FACTOR (SPK) 1.0 1.0 1.0 1.0 1.0 6

Lionville Laboratory, Inc.

INORGANICS PRECISION REPORT 03/27/02 CLIENT: TELEDYNE-VERMONT YANKEE WORK ORDER: 11699-600-005-9999-00 LVL LOT #: 0203L244 INITIAL SAMPLE SITE ID ANALYTE RESULT REPLICATE RPD

-001REP 1

Total Halides 137 u

137 u

NC

-002REP 2

Chloride by IC' 5.0 3.5 34.8 DILUTION PACTOR (REP) 1.0 la0 7

Lionville Laboratory, Inc.

INORGANIC ANALYTICAL DATA PACKAGE FOR TELEDYNE-VERMONT YANKEE DATE RECEIVED:

03/22/02 LVL LOT # :0203L244 CLIENT ID /ANALYSIS LVL #

MTX PREP #

COLLECTION EXTR/PREP ANALYSIS CHLORIDE BY IC TOTAL HALIDES TOTAL HALIDES TOTAL.HALIDES 2

CHLORIDE BY IC CHLORIDE BY IC CHLORIDE BY IC TOTAL HALIDES LAB QC:

001 001 001 REP 001 MS 002 002 REP 002 MS 002 0i 01 0I 01 01 01 01 0I 02LICB23 02LE004 02LE004 02LE004 02LICB23 02LICB23 02LICB23 02LE004 03/18/02 03/18/02 03/18/02 03/18/02 03/18/02 03/18/02 03/18/02 03/18/02 03/23/02 03/26/02 03/26/02 03/26/02 03/23/02 03/23/02 03/23/02 03/26/02 03/23/02 03/26/02 03/26/02 03/26/02 03/23/02 03/23/02 03/23/02 03/26/02 CHLORIDE BY IC CHLORIDE BY IC TOTAL HALIDES TOTAL HALIDES TOTAL HALIDES TOTAL HALIDES MBI MB1 BS LC1 BS LC2 BS MBI MB2 s

S w

w w

w 02LICB23 02LICB23 02LE004 02LE004 02LE004 02LE004 N/A N/A N/A N/A N/A N/A 03/23/02 03/23/02 03/26/02 03/26/02 03/26/02 03/26/02 03/23/02 03/23/02 03/26/02 03/26/02 03/26/02 03/26/02 t' P 8

ionvilfe Laboratory Use Only Z07,3 LZ,q, Custody Transfer Record/Lab Work Request Pagelofi I

I..*,,.

FIELD PERSONNEL: COMPLETE ONLY SHADED AREAS A

Client..

-'r'(c J,,Ak Z V?,

t

,YOui 4

-C Refrigerator #

Est. Final Proj. Sampling Date

- -_ -_Type Contains.

Liui Project#

'I (6qq - coo - OOT -

g-" oo CSolid Liquid

L I

Project Contact/Phone #

Volume r

LUonville'Laboratory Project Manager 41 0 Solid SDel TAT dQA Preservatives I

-:r OC

.J' Del TAORGANIC INORG DateRec'd 3-2..-o2.

Date Due 3--Ot REQUESTED 0j j

MATRIX Matrix

'Llonvilie Laboratory Use Only____

CODES:

0C

.So L

abD Chosen Ma Date Time

'c S -

Soil Lab Client ID/Descrlption Chsnmatrix Dae TmJ SE-Sediment L) r Collected Collected SO-Solid SL -. Sludge

-I MS MSD W

e-Water a-all 3_

_-160-toltz A -.

thr Air DS.

Fis

-r-Solids DL - Drum Liquids **I L -

EP--CLP-",-..

Leachate

-Wipe F

D Fi-shE'IS N" DATE/REVISIONS:

'!lJ-nvlll-b ohrsto-Usne (Onlv (2."

Spe;ial InstructIons; 1.

2.

3.

4.

5.

ror Alrbillv (mblen r Chilled eelivedlp Good CondIton or N

4) Samples Properly Pr rved Time Discrepancies Between or N Samples Labels and S) Received Within COC Record? Y or Holng Ti s

NOTES:

U or N

(__Z__

(

.SVJ6o3 1014,03 3 -q7-7 Tamper Resistant Saal was:

1) Present on Outep,3 Package Y or V

2) Unbroken on Outer Package Y or N

3) Present on Samrle)

Y or NQ

4) Unbroken on Sample Y or N COC Record Present Upon Samp apec't or N J,

e3yc R"

6' Relinquished Received Date t Time by I

I LAp

-a 3j497 5,V,'

3-214oL 1 J 0 Relinquished by Received by Date C O'tAlP 0cITE

.I I-

0

-7

ýz 01--3 L12 If If I~M~YMIJ Shipment Number: 2002-09 Date of Shipment: 3119102 Vermont Yankee Nuclear Power Station Shipping Method:

_UPS FEDERAL EXPRESS

_COURIER

___xxxxx__COMMON Requested Turnaround Time _Standard From:

Tim McCarthy. Radwaste I Hazwaste Supervisor Vermont Nuclear Power Station P.O. Box 157 Governor Hunt Road Vernon, VT 05354 (Phone: 802.258-5476)

(Fax: 502.258-5489)

.x_

Rush __ Working Days(specify #)

ANALYSIS TO BE PERFORMED W_

Collection Period Sart stop z)

0)

=

0 OTHER C1 Sample OTE Amount

=$

0)

Volkm rno C

.2~

0 a

L Waste Oil From Designated Locations toom ri

=-"v

"'S"=

E EWeight (MKS 0-a) 0 CL ca Sample Type I Description I Comments C..

s: U

(

1 L.

OilComposite-RCA 10 30 10 30 x x X

2 L

Oil Composite 10 30 10 30 1000mls x

x x

Collected By:

DCH Relinquished B Tim McCarthy COMMENTS or SPECIAL INSTRUCTIONS Received at laboratory '4gZPROVIDE TWO COPIES OF THE LAB REPORT Date received: "

-e"*'

.,.t~

LXONVILLE LABORATORY INCORPORATED SAMPLE RECEIPT CHECKLIST CLI ENT:

Pur*.'

Order/Project:

SAF# I SOW ] i Release N:

Laboratory SDG #:

DATE:

NOTE: ALL ENTRIES MARKED "NO" MUST BE EXPLAINED IN THE COMMENT SECTION I.

Custody seals on coolers or shipping

. container intact, signed and dated?

Li Yes

~rr'io U I~IA El Yes

2.

Outside of coolers or shipping containers are free from damage?

3.

Airbill # recorded?

4.

All expected paperwork received (coc and other client specific: historical data, alphalbeta or other screening data as applicable)? (paperwork sealed in plastic bag and taped to inside lid)

5.

Sample containers are intact?

6.

Custody seals on sample containers intact, signed and dated?

All samples on coc received?

8.

All sample label information matches coc?

9.

Laboratory QC samples designated on coc?

(QC stickers placed on bottles?)

10. Shipment meets LvLI Sample Acceptance Policy? (identify all bottles not within policy. See reverse side for policy)

HI. Where applicable, bar code labels are affixed to coc?

12. coc signed and dated?

13. coc faxed or emailed to client?

14. Project Manager/Client contacted concerning discrepancies? (name/date) 13 No o No o No rD No ONo O No O NjA o NIA ON/A

[] NIA O N/A O N/A 0 Yes "e Coment-o see Comment N o see Comment N O see Comment N a see Commentf o see Comment N o see Comment i n see Comment N O see Comment #

r see Comment N 0 see Comment #

0 see Comment N O see Comment #

0 see Comment #

0 Yes 0 Yes O No

' N/A O Yes

yes 0 Yes O Yes 0140 ONO ONo 0 No O N/A 0 N/A 0 NIA Cooler # / temp and Comments: to (fo, 7;,,%

./9, 5,.06e 61 z/11 Laboratory Sample Custodian:

Laboratory Project Manager:

V..

Analytical Report Client: TELEDYNE-VERMONT YANKEE W.ONi: 11699-600-005-9999-00 LVfI: 0203L244 Date Received: 03-22-02 INORGANIC NARRATIVE I.

This narrative covers the analyses of 2 oil samples.

2.

The samples were prepared and analyzed in accordance with the methods indicated on the attached glossary.

3.

All results presented in this report are derived from samples that met LvLI's sample acceptance policy with the exception the cooler temperature and the label discrepancies noted on the Sample Receipt Checklist.

4.

Sample holding times as required by the method and/or contract were met.

5.

The method blanks were within the method criteria.

6.

The Laboratory Control Samples (LCS) were within the laboratory control limits.

7.

The matrix spike recoveries were within the 75-125% control limits.

8.

The replicate analysis for Total Halides was within the 20% Relative Percent Difference (RPD) control limit, however replicate analysis for Chloride was outside the control limit that may be attributed to sample inhomogeneity.

9.

Results for oil samples are reported on a wet weight basis.

lain Daniels Date Laboratory Manager Lionville Laboratory Incorporated njpV03-244 The results presented in this report relate to the analytical testing and onditio fhsamples.. reeipt and during storage. All pages of this report are integral parts of the analytical data. Therefore, this report should only be reproduced in its entirety of I I pages.

1 208 Welsh Pool Road

Lionville, PA 19341-1333 * (610) 280-3000 - Fax (610) 280-3041

Lionville Laboratory Incorporated WET CHEMISTRY J

METHODS GLOSSARY.FOR SOIL/SOLIDS SAMPLE ANALYSIS ASTM SW846 OTHER

% Ash D2216-80

% Moisture D2216-80

% Solids D2216-80

% Volatile Solids D2216-80 ASTM Extraction in Water D3987-81/85 BTU D240-87 CEC Chromium VI Corrosivity _ by coupon by pH Cyanide, Total Cyanide, Reactive Halides, Extractable Organic Y "'des, Total E r~oxicity Flash Point

Ignitability Oil & Grease Carbon, Total Organic Oxygen Bomb Prep for Anions D240-87(mod)

Petroleum Hydrocarbons, Total Recoverable pH, Soil Sulfide, Reactive Sulfide Specific Gravity D1429-76C/

Sulfur, Total Synthetic Preparation Leach Paint Filter Other:

Method:

Other:

Method ILMO4.0 (e)

ILMO4.0 (e) 9081 c

3060A/7196A 1110(mod) 9045C 9010B ILMO4.0 (e Section 7.3/9014 9020B EPA 600/4'

,/9020B

--i/EPA 600/4/

1310A 1010 1010 9071A 9060 Lloyd Kahn

5050 9071 EPA 418.1 9045C Section 7.3/9030B 9030B(mod)

D5057-90 9056 1312 9095A EPA (

-0 4-008 84-008 (mod)

L-WI-034/B-01/01

6~{ AZ49tjOb4~

1~)

4

Lionville Laboratory Incorporated METHOD REFERENCES AND DATA QUALIFIERS DATA QUALIFIERS U)=

Indicates that the parameter was not detected at or above the reported limit. The associated numerical value is the sample detection limit.

=

Indicates that the original sample result is greater than 4x the spike amount added.

ABBREVIATIONS MB

= Method or Preparation Blank.

MS

= Matrix Spike.

MSD = Matrix Spike Duplicate.

REP = Sample Replicate LC = Laboratory Control Sample.

NC = Not calculated.

A suffix of-R, -S, or -T following these codes indicate a replicate, spike or sample duplicate analysis respectively.

ANALYTICAL WET CHEMISTRY METHODS

1.

ASTM Standard Methods.

2.

USEPA Methods for Chemical Analysis of Water and Wastes (USEPA 600/4 020).

3.

Test Methods for Evaluating Solid Waste (USEPA SW-846).

a.

Standard Methods for the Examination of Water and Waste, 16 ed, (1983).

b.

Standard Methods for the Examination of Water and Waste, 17 ed, (1 989)11 8ed (1992).

c.

Method of Soil Analysis, Part 1, Physical and Mineralogical Methods, 2nd ed,

.(1986).

d.

Method of Soil Analysis, Part 2, Chemical and Microbiological Properties, And.

Soc. Agron., Madison, WI (1965).

e.

USEPA Contract Laboratory Program, Statement of Work for Inorganic Analysis.

f.

Code of Federal Regulations.

L-WI-034/D-02/01

"'¢'

3

Lionville Laboratory, Inc.

INORGANICS DATA

SUMMARY

REPORT 03/27/02 CLIENT: TELEDYNE-VERMONT YANKEE WORK ORDER: 11699-600-005-9999-00 SAMPLE

" SITE ID ANALYTE

-001 1

chloride by IC Total Halides

-002 2

Chloride by IC Total Halides LVL LOT #: 0203L244 REPORTING RESULT UNITS LIMIT 3.3 MG/KG 1.2 137 U

MG/KG 137 DILUTION FACTOR 1.0 1.0 1.0 1.0 5.0 MG/KG 197.

MG/KG 1.2 136 4

Lionville Laboratory, Inc.

INORGANICS METHOD BLANK DATA

SUMMARY

PAGE 03/27/02 CLIENT: TELEDYNE-VERMONT YANKEE WORK ORDER: 21699-600-005-9999-00 SAMPLE SITE ID ANALYTE BLANK10 02LICB23-MB1 chloride by IC BLANK1 02LE004-MB1 Total Halides BLANK2 02LE004-MB2 Total Halides LVL LOT 4: 0203L244 REPORTING RESULT UNITS LIMIT 1.2 u

MG/KG 1.2 20.0 u

MG/KG 20.0 20.0 u

MG/KG 20.0 DILUTION FACTOR 1.0 1.0 1.0 re.~

S

Lionville Laboratory, Inc.

INORGANICS ACCURACY REPORT 03/27/02 CLIENT: TELEDYNE-VERMONT YANKEE WORK ORDER: 11699-600-005-9999-00 LVL LOT #:

0203L244 SAMPLE

-001

-002 BLANK10 LCS1 LCS2 SITE ID 1

2 02LICB23-MBI 02LE004-LC1 02LE004-LC2 ANALYTE Total Halides Chloride by IC Chloride by IC Total Halides Total Halides SPIKED SAMPLE 3200 30.8 24.8 477 490 INITIAL RESULT 28.9 5.0 1.2 U 20.0 U 20.0 U SPIKED AMOUNT 3420 25.0 25.0 S00 500

%RECOV 92.6 102.9 99.0 95.5 97.9 DILUTION FACTOR (SPK) 1.0 1.0 1.0 1.0 1.0 6

Lionville Laboratory, Inc.

INORGANICS PRECISION REPORT 03/27/02 CLIENT: TELEDYNE-VERMONT YANKEE WORK ORDER: 11699-600-005-9999-00 LVL LOT #:

0203L244 SAMPLE

-001REP

-002REP INITIAL SITE ID ANALYTE RESULT REPLICATE RPD 1

Total Halides 137 u

137 u

NC 2

Chloride by IC 5.0 3.5 34.8 DILUTION FACTOR (REP) 1.0 1.0 7

Lionville Laboratory, Inc.

INORGANIC ANALYTICAL DATA PACKAGE FOR TELEDYNE-VERMONT YANKEE DATE RECEIVED:

03/22/02 LVL LOT # :0203L244 CLIENT ID /ANALYSIS LVL #

MTX PREP #

COLLECTION EXTR/PREP ANALYSIS CHLORIDE BY IC TOTAL HALIDES TOTAL HALIDES TOTAL HALIDES 2

CHLORIDE BY IC CHLORIDE BY IC CHLORIDE BY IC TOTAL HALIDES LAB QC:

001 001 001 REP 001 MS 0O 01 01 01 02LICB23 02LE004 02LE004 02LE004 02LICB23 02LICB23 02LICB23 02LE004 03/18/02 03/18/02 03/18/02 03/18/02 03/18/02 03/18/02 03/18/02 03/18/02 03/23/02 03/26/02 03/26/02 03/26/02 03/23/02 03/23/02 03/23/02 03/26/02 03/23/02 03/26/02 03/26/02 03/26/02 03/23/02 03/23/02 03/23/02 03/26/02 002 002 REP 002 MS 002 0I 01 0I 0I CHLORIDE BY IC.

CHLORIDE BY IC TOTAL HALIDES TOTAL HALIDES TOTAL HALIDES TOTAL HALIDES MB1 M*B1 BS LC1 BS LC2 BS MBI MB2 S

S w

w w

W 02LICB23 02LICB23 02LE004 02LE004 02LE004 02LE004 N/A N/A N/A N/A N/A N/A 03/23/02 03/23/02 03/26/02 03/26/02 03/26/02 03/26/02 03/23/02 03/23/02 03/26/02 03/26/02 03/26/02 03/26/02 r'~ 8

ionville Laboratory Use Only Custody Transfer Record/Lab Work Request Page of _L.

04,03L Zq-t.

FIELD PERSONNEL: COMPLETE ONLY SHADED AREAS A

Cr) 4 Client

-Rerigerator 4

Est. Final ProJ. Sampling Date

/Type Container L

L Project I

{( lo g

__ G o o O- 0 S " -q q q q~ - a o

,,d Project Contact/Phone #

Volume Liui L

Lionville Laboratory project Manager Moi 0C Del TAT..

dam I Preservatives

.I I

ORGANIC t

NOii ANALYSES i

Date Rec'd 3-2..-O.

Date Due 3 7-7"--O'.

REAUESTED 0>

W I

MATRIX Matrix Lionville Laboratory Use Only CODES:

0C SL-Sobl La Client ID/Descrlptlon Chosen Matrix Date Time

x.

SE-Sediment ti)

Collected Collected SO - Solid MSQD S E. S edi en o;-

1 I SL.- Sludge

-Ms

-MS w-WaOil 1'-e 1030 A

r-

-ir A - A ir 1

£

" '"LI 7

~i DS-Drum

.J.

Solids DL-Drum...

Liquids L-EP/tCLP Leachate I

Wl-Wipe X-Other F-Fish

(.2.

Special Instructions:

wit It-Int-Viblia:lO 1.

2.

3.

4.

LIonville Lal

ý or Hiý ýDoverad -L Alrbill I#

"A(

blenr Chilled S TeceivedzJr Good Condition 7 or N

4) Samples Properly Pr rved Discrepancles Between V

or N Samples Labels and

5) Received Within COC Record? Y or)

Holdin Time NOTES:

(9Y or N t,I

~W*3o iL*o3 6s 77v boratory use u0y Tamper Resistant Seal was:

1) Present on Oute].r Package Y or

2) Unbroken on Outer Package Y or N

3) Present on Samrnie' Y or QV}

4) Unbroken on Sample Y or N COC Record Present Upon SampJnec't

(./or N

Y~I Relinquished Received by I

, Py I

II Date Time Relinquished Date T.I by",

3i~-z-.0 ojoo COQMPOEITE

ý,_ 1 ý1

-WT ecelved Date by I

I=e Time INALI I.

I L

.17A c2 7~

.-

I i Q-,..

IN,-

"Al 21ý0-10 I

Shipment Number: 2002-09 Date of Shipment: 3119/02 Vermont Yankee Nuclear Power Station Shipping Method:

UPS FEDERAL EXPRESS COURIER

__xxxxx__COMMON Requested Turnaround Time Standard From:

Tim McCarthyp Radwaste / Hazwaste Supervisor Vermont Nuclear Power Station P.O. Box 157 Governor Hunt Road Vernon, VT 05354 (Phone: 802.258-5476)

(Fax: 802-258-5489)

_x_ Rush Working Days(specify #)

(01L ANAI V.AIR TO RF PFRFORMED Collection eriod

-start stop (D.

"CE C

OTHER 6

C Sample z

i-Amount E

2 O

0 0 ~T~ntedL~aion~iVolume or

.2 2

4 S

Waste Oil From Deinae Loaton S

0 E

E Weight (MKS o2 Q)

M E

u CL Sample Type I Description Comments 3

Units) r L

L.

OilComposite-RCA 10 30 10 30 lOO.m.s x

x x.

2 L

Oil Composite 10 30 10 30 1000 mIs x

x x

Collected By:

DCH Relinquished B Tim McCarthy COMMENTS or SPECIAL INSTRUCTIONS Received at laboratory by X

PROVIDE TJJ'O COPIES OF THE LAB REPORT Date received:,",-4.

r d.

L D

LIONVILLE LABORATORY INCORPORATED SAMPLE RECEIPT CHECKLIST CLIENT:/

Pur

-e Order/Project:

DATE:

SAF# / SOWN I Release 11:

Laboratory SDG #:

M2y3'a,

.9/19 NOTE: ALL ENTRIES MARKED "NO" MUST BE EXPLAINED IN THE COMMENT SECT)ION

1. Custody seals on coolers or shipping container intact, signed and dated?

2.

Outside of coolers or shipping containers are free from damage?

3.

Airbill # recorded?

4.

All expected paperwork received (coc and other client specific: historical data, alpha/beta or other screening data as applicable)? (paperwork sealed in plastic bag and taped to inside lid)

5.

Sample containers are intact?

6.

Custody seals on sample containers intact, signed and dated?

All samples on coc received?

8.

All sample label information matches coc?

9.

Laboratory QC samples designated on coc?

(QC stickers placed on bottles?)

U Yes U NIA E Yes U N/A 13 No 0 No ONO o NIA 0 N/A o NIA 0 N/A O N/A N N/A O Yes D4" O"Ye" 10 No 0 No ONO ONO osc Comment N o see Comment X 0 see Comment #

0 see Comment N a see Comment N a see Comment N O see Comment 1 O see Comment N 0 see Comment N O see Comment #

O see Comment N 0 see Comment N 0 see Comment N n see Comment #

10. Shipment meets LVLI Sample Acceptance Policy? (identify all bottles not within policy. See reverse side for policy) 0 Yes 0 N/A

11. Where applicable, bar code labels are affixed to coc?

0 Yes tNt pNwAoc"

12. coc signed and dated?

13. coc faxed or emailed to client?

14. Project Manager/Client contacted concerning discrepancies? (name/date)

O Yes

" Yes ONO ONo O No O3 NIA O N/A Cooler # / temp andComments: -

6'77"

z Laboratory Sample Custodian

Laboratory Project Manager-I-.

'iLl January 19, 2005 Ms. Lynn DeWald Entergy Nuclear Northeast, Vermont Yankee 322 Governor Hunt Rd Vernon, VT 05354 RE:

Analytical Data 0411L176

Dear Lynn,

Lionville Laboratory Incorporated (LvLI) is pleased to deliver the following analytical data reports:

RFW Batch #

Date. Received Fraction 0411L176 11.17.04 Metals 0411L176 11.17.04 General Chemistry 0411L176 11.17.04 PCB If you have any questions, please do not hesitate to contact me at 610. 8 or haslettm@lionvillelab.com.

REVIEWED

/r/ j Lionvil Incorporated FEB 1 021005 I

By Mr Mark D. Haslett Project Manager Enclosure 208 Welsh Pool Road

Exton, PA 19341-1313 a (610) 280-3000

Fax (610) 280-3041

Lionville Laboratory, Inc.

PCB ANALYTICAL DATA PACKAGE FOR TELEDYNE-VERMONT YANKEE DATE RECEIVED:

11/17/04 LVL LOT # :0411L176

. CLIENT ID COMP'OIL.PLANT SYSTE COMP NWH OIL RESERVO COMP CAB OIL RESERVO TRANSFORMER OIL CRANK CASE OIL LVL #

001 002 003 004 005 MTX PREP #

COLLECTION EXTR/PREP 0I 0I 0I 01 0I 04LE1405 04LE1405 04LE1405 04LE1405 04LE1405 11/08/04.

11/08/04 11/08/04 11/08/04 11:08/04 11/19/04 11/19/04 11/19/04 11/19/04 11/19/04 ANALYSIS 11/24/04 11/24/04 11/24/04 11/24/04 11/24/04 LAB OC:

PBLKAS PBLKAS PBLKAS MB1 MR!

BSD MBI BSD S

S 04LE1405 04LE1405 04LE1405 N/A N/A N/A 11/19/04 11/19/04 11/19/04 11/24/04 11/24/04 11/24/04

.{-.

a=-"-If=4.

V-L Case Narrative Client: TELEDYNE-VERMONT YANKEE W.O.#: 11699-600-005-9999-00 LVL#: 0411L176 Date Received: 11-17-2004 PCB Five (5) oil samples were collected on 11-08-2004.

The samples and their associated QC samples were extracted on 11-19-2004 and analyzed according to Lionville Laboratory SOPs on 11-24-2004.

The extraction procedure was based on method 3580A (waste dilution-lg into 1OmL of Hexane) and the extracts were analyzed based on method 8082.

The following is a summary of the QC results accompanying the sample results and a description of any problems encountered during their analyses:

1.

All results presented in this report are derived from samples that met LVLI's sample acceptance policy.

2.

The required holding time for extraction and analysis was met.

Samples and their associated QC samples received a Sulfuric Acid cleanup according to Lionville Laboratory SOPs based on SW 846 method 3665A.

4.

The method blank was below the reporting limits for all target compounds.

5.

One (1) of six (6) obtainable surrogate recoveries was outside acceptance criteria. However, the surrogate recovery criteria were met (i.e., no more than one outlier per sample).

6.

All blank spike recoveries were within acceptance criteria.

7.

All samples required a 20-fold dilution due to the matrix interferences. The reporting limits were adjusted to reflect the necessary dilution.

8.

All initial calibrations associated with this data set were within acceptance criteria.

9.

All continuing calibration standards analyzed prior to sample extracts were within acceptance criteria.

I& Dani&

Date

[__}

oratory Manager

,Lionville Laboratory Incorporated somr\\rgroupýdata\\pest\\Teledyne venmont-yankee4l 1-176.pcb The results presented in this report relate only to the analytical testing and conditions of the samples at receipt and during storage. All pages of this report arwe integral parts of the analytical data. Therefore, this report should only be reproduced in its entirety of 7 pages.

208 Welsh Pool Road e Exton, PA 19341-1313 e (610) 280-3000

Fax (610) 280-3041 Fee8ae2

fvL, GLOSSARY OF DATA DTA QUAUFJE5

" dicates that the compound was analyzed for but not detected. The minimum detectionliit for the U,riple (not the M*ethod detection limit) is reported with the U (e.g., IOU).

,cdicates an estimated value. This flag is used in cases where a larget analyte is detectd at a level less than the lower quantification level.. If the limit of quantification is 10 ug/L and a concentration of-.3 ug/L is calculated, it is reported as 3L.

B

. 1

'-j.j-is flag is used.when the analyte is found in the associated blank as well as in the sample. It indicates possible/probable blank contamination.

E

'rdicates that the compound was detected beyond the calibration range and was subsequently

",,alyzed at a dilution.:

Interference.

indicates an interference on one analytical column only. Result is reported from remaining analytical

]3]3oEYmATJO_."S

ýs l~Jnicates blank spike in which reagent gmde water is spiked with the CLP matrix spiking solutions and carried through all the steps in the method.* Spike recoveries are reported.

BSD Indicates blank spike duplicate.

dicates matrix spike.

MSD

=

Indicates matrix spike duplicate..

D, dcates that recoveries were not obtained because the extract had to be dilted for analysis.

NA

=

ot Applicable.

DF-ilution Factor.

NiR 4ot Required.

NS 1,ot Spiked.

P

.bdicates Spiked Compound.

I bis flag is used for an PESTICIDE/PCB target analyte when there is greater than 25%

difference for detected concentraiions between the two GC columns (see Form X). The lower of the two -alues is reported on Form I and flagged with a "P".

D

. fl.is flag identifies all compounds identified in an analysis at a secondary dilution factor.

C "Iis flag applies to a compound that has been confirmed by GC/MS.

NPM 1 pattern match for multi-component target analytes..

Lionville Laboratory, Inc.

PCBs by GC Report Date: 11/30/04 19:02 RFW Batch Number: 0411L176 Client.:TELEDYNE-VERMONT YANKEE Work Order: 11699600005 Page:

1 Cust ID: CO4P OIL PLA.

COMP HWU OIL COMP CAB OIL TRANSFORMER CRANK CASE PBLKAS NT SYSTE RESERVO RESERVO OIL OIL Sample.

RFW#:

001 002 003 004 005 04LE1405-MB1 Information Matrix:

OIL OIL OIL OIL OIL SOIL D.F.:

.20.0 20.0 20.0 20.0..

20.0 1.00 Units:

UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG..

Surrogate:

Tetrachloro-m-xylene D

V D

D t

D D

116 Decachlorobiphenyl D

!k D

D t

D k

D.%

106 Aroclor-1016 8000 U

8000 U

400 U

Aroclor-1221 8000 U

8000 U

400 U

Axoclor-1232__

8000 U

400 U

Aroclor-1242 8000 U

8000 U

400 U

Aroclor-1248 8000 U

8000 U

400 U

Aroclor-1254 8000 U

8000 U

400 U

Aroclor-1260 8000 U

8000 U

8000 U-400 U

Cust ID: PBLKAS BS PBLKAS BSD

-'.,Sample RFW#: 04LE1405-MBI 04LE1405-M1B Information Matrix:

SOIL SOIL D.F.:

.1.00 1.00 Units:

UG/KG UG/KG Surrogate:

Tetrachloro-m-xylene 124

118 q

Decachlorobiphenyl 114 110 Aroclor-1016 124 120 Aroclor-1221 400 U

400 U

Aroclor-1232.

400 U

Aroclor-1242 400 U

400 U

Aroclor-1248 400 U

400 U

Aroclor-1254 400 U

400 U

Aroclor-1260 119 k

117 W

U-Analyzed, not detected.

Ju Present below detection limit. B-Present in blank. NR= Not reported.

NS=aNot spiked.

%- Percent recovery.

D= Diluted out.

I-Interference.

NA= Not Applicable.

a Outside of EPA CLP QC

luonviLaboratory Use°"nyI Custody Transfer Record/Lab Work Request Page'of/

(P-/i

/4 IFIELD PERSONNEL-COMPLETE ONLY SHADED AREAS Se dL e 8RC A

V ~

V V -

~-1 1

~. -

1 i

LL Fifrlgertto #

I:

1*.

I I

J Vflype ContainerN

0.

111101 WINE!

Vo Pr ilume Ywjwý

_pgrqý reservatives Date Rec'.

Date Due

~

/~/0f'ct/

I l

ANALYSES REQUESTED ORE ANIC INC 9

1

.omville Laborptory Usa Only

.1,

Matrix-0 Dto-Time Client ID/DescrIption Chosen C

Cl I

S ED F

1 AF E ý U

6~

1 W.4A4

'031 K;

A M45 W2400_I rm 1,1, V,1

-7

~i~5

1*

Special instructionw.

7;~4rs9 p..

DATE/REVISIONS 2

-~4 I:

!I

.4 i.

1.

F lobe~ahd Received

~

'Date Relinquished iby nn, m

Date Time Relinquished Received by

~

by mme r~i EZIIIILIII l

1lfIbmIUL8jq~gqp.

I b ý2

o'-UL / 7 ý I M-~

I

_K A1

.Shipment NIumber: 2004-114 Date of Shipment: 1119104 LiUonvilleo Laboratory Inc.

208 Welsh Pool Road Ucoville, PA 19341.1333 From:

Tim McCarthy-Radwaste / Hazwaste tupervisor Shipping Method: ___

UPS.*

Vermoht Nuclear Power Station FEDERAL EXPRESS P.O. Box 157 Governor Hunt Road

_COURIER_..O.N Vernon, VT 05354 (Phone: 802.258-5476)

-*COMM I

(Fa*: 802-258-5489).

Requested Turnaround Time__X Standard "

Rush Working Days( specify #)

ANALYSIS TO BE PERFORMED i

i i -

CollI Penod Sat stop I

oI, OTHER Waste Oil Fmm Designated Locations I Jill II I i i

-0 E

9 10.

I B 5amwo 0

I -ii I>

10

a Sample TYne I Description I Comments

.jAg1.jj~

VwqU~RN Of Wevgt (MKS urate) i,

5 Ec e

A 0)

1

.2 A)

Cu 0

C a

I.-

8L M.

A_

(-

.~

-1

-a I

L Composite Oil Plant Systems (Rad) 118 118 1000MLS x

x x

X x x

x 'x 2

L.

Composite NWH Oil Reservoir (Rad) 11 8

11 8

1000 MLS x

x x

x

.x x

x x

3 L

Com.positeCABOiIReservoir 118 11 8

1000 MLS x

x.

x x

x X

x 4

L Transformer Oil I1 8

1008 1MLS X

X x

x x

x x x

.. x 5

L Crank CaseOi11 8

8 1 000MLS x

x x

X x

6 L

7

'1___-___._:_

-8 L

9 L

10 L.

Collected By:

DCH -

Relinquished By:. Tim McCarthy m

=,

Receir "t laboratory b Date r, -Jed:

/(/r7, tZ.

COMMENTS or SPECIAL INSTRUCTIONS PROVIDE TWO f-JIES OF THE JAB REPORT

-Send back unused quantities of sample to VY f

Lionville Laboratory Incorporated

.SAMPLE RECEIPT CHECKLIST (SRC)

CLIENT:

Date:,

Purchase Order Project#:."

SAF#/SOW# I/Release#0

LvLI Batch #:

02///

./

Sample Custodian:

NOTE: EXPLAIN ALL DISCREPANCIES I. Samplesand ]Delivered o*

-I Caier Airbill#.,

2.

Custody seals on 0bolers or shipping container intac4 signed and dated?

3...Outside of.coolers or shipping containersare free from damage?

4.

All expected paperwork received (coc.and other client specific information) sealed in plastic bag and easily accessible?

5. -Samples received'cooled COYes 0 No

ýWneaie Comnments 12-fs 0140

,3yes 0 No Temp /

-4 c"

6.

Custody.seals on sample container intac...

signed and dated?

7; coc signed and dated?

8.

Sample containers are intact?

.9..All samples on coc received? All samples received on coc?

10.. All simple label information matches co.??

.11. Samples.properly preserved?

12..Samples received within hold times?

Short holds taken to wet lab?

13. VOA, TOC, TOX free of headspace?

14:".QC stickers placed on bottles designated by client?

15. Shipment meets LvLI Sample Acceptance

, Policy? (IdentiY all bottles not within Policy.* See reverse side for policy)

L)

16. Project Manager contacted concerning discrepancies? name/date (or samples outside criteria)

Cooler# W4

.E 4~s 0 Yes Yes Cr/c es

. Yes 0 Yes D Yes 0 No 0 No E0 No 0 No O No

.O3No tONo NIA D No DNo Dicvrepan' SR-002-B

Lionville Laboratory, Inc.

INORGANIC ANALYTICAL DATA PACKAGE FOR TELEDYNE-VERMONT YANKEE DATE RECEIVED:

11/17/04 LVL LOT # :0411L176 CLIENT ID /ANALYSIS LVL #

MTX PREP #

COLLECTION EXTR/PREP ANALYSIS COMP OIL PLANT SYSTE

% ASH

% ASH.

CALORIMETER BOMB PRE BRITISH THERMAL UNIT FLASH POINT

.TOTAL HALIDES COMP NWH OIL RESERVO

% ASH CALORIMETER BOMB PRE BRITISH THERMAL UNIT FLASH POINT AL HALIDES' COMP CAB OIL RESERVO

% ASH CALORIMETER BOMB PRE BRITISH THERMAL UNIT FLASH POINT TOTAL HALIDES 001 001 REP 001-001 001 001 0I 01 01 01 0I 0I 002 002 002 002 002 003 003 003 003 003 004 004-004 004 004 005 005 0I 0I 01 0I 0I 04L%A016 04L%A016 04BOMB22 04LRR024 04LFP026 04LE017 04L%AO16 04BOMB22 04LRRO24 04LFP026 04LE017 04LAO16 04BOMB22 04LRRO24 04LFP026 04LE017 04L%A016 04BOMB22 04LRR024 04LFP026 04LE017.

0I 01 0I 01 0I 11/08/04 11/08/04 11/08/04 11/08/04 11/08/04

.11/08/04 11/08/04 11/08/04 11/08/04 11/08/04 11/08/04 11/08/04 11/08/04 11/08/04 11/08/04 11/08/04 11/08/04 11/08/04 11/08/04 11/08/04 11/08/04 11/08/04 11/08/04 11/26/04 11/26/04 12/01/04 11/22/04 11/23/04 11/29/64 11/26/04 12/01/04 11/22/04 11/23/04 11/29/04 11/26/04 12/01/04 11/22/04 11/23/04 11/29/04.

11/26/04 12/01/04 11/22/04 11/23/04 11/29/04 11/26/04 12/01/04 11/26/04 11/26/04 12/02/04 11/22/04 11/23/04 11/29/04 11/26/04 12/02/04 11/22/04 11/23/04 11/29/04 11/26/04 12/02/04 11/22/04 11/23/04 11/29/04 11/26/04 12/02/04 11/22/04 11/23/04 11/29/04 11/26/04 12/02/04 TRANSFORMER OIL

% ASH CALORIMETER BOMB PRE BRITISh THERMAL UNIT FLASH POINT TOTAL HALIDES 0I 0I 01 01 OI CRANK CASE OIL

% ASH CALORIMETER BOMB PRE 01 04L%A016 01 04BOMB22 FEB Z

0 2005 By 0I~

Lionville Laboratory, Inc.

INORGANIC ANALYTICAL DATA PACKAGE FOR TELEDYNE-VERMONT YANKEE DATE RECEIVED:

11/17/04 LVL. LOT #':0411L176' CLIENT ID /ANALYSIS LVL #

MTX PREP #

COLLECTION EXTR/PREP BRITISH THERMAL UNIT FLASH POINT TOTAL HALIDES TOTAL HALIDES TOTAL HALIDES COMP OIL PLANT SYSTE 005 005 005 005 REP 005 MS 01 04LRR024 OI 04LFP026 01 04LE017 01 04LE017 01 04LE017 CHLORIDE BY IC CHLORIDE BY IC CHLORIDE BY IC SULFATE BY IC SULFATE BY IC SULFATE BY IC 006 006 REP 006 MS 006 006 REP 006 MS COMP NWH OIL RESERVO CHLORIDE BY.IC SULFATE BY IC

k.

CAB OIL RESERVO w

w w

w

.CHLORIDE BY IC SULFATE BY IC TRANSFORMER OIL CHLORIDE BY IC*

SULFATE BY IC CRANK CASE OIL-CHLORIDE BY IC

.SULFATE BY IC 007 007 008 008 009 009 04LICA71 04LICA71 04LICA71 04LICA71 04LICA71 04LICA71 04LICA71 04LICA71 04LICA71 04LICA71 04LICA71 04LICA71 04LICA71 04LICA71 11/08/04 11/08/04

.11/08/04 11/08/04 11/08/04 11/08/04..

11/08/04 11/08/04 11/08/04 11/08/04 11/08/04

.11/08/04 11/08/04 11/22/04 11/23/04 11/29/04 11/29/04 11/29/04 12/02/04 12/02/04 12/02/04 12/02/04 12/02/04 12/02/04 12/02/04 12/02/04 w

w w

w ANALYSIS 11/22/04 11/23/04 11/29/04 11/29/04 11/29/04 12/02/04 12/02/04 "12/02/04 12/02/04 12/02/04 12/02/04 12/02/04 12/02/04 12/02/04 12/02/04 12/02/04 12/02/04 12/02/04 12/02/04 11/08/04

.11/08/04 11/08/04 11/08/04 11/08/04 11/08/04 12/02/04 12/02/04 12/02/04 12/02/04 12/02/04 12/02/04 010 010 LAB QC:

V ASH MB1 W

04L%AO16 N/A 11/26/04 11/26/04 02

Lionville Laboratory, Inc.

INORGANIC ANALYTICAL DATA PACKAGE FOR TELEDYNE-VERMONT YANKEE DATE RECEIVED:

11/17/04 LVL LOT # :0411L176 CLIENT ID /ANALYSIS BRITISH THERMAL UNIT TOTAL HALIDES TOTAL HALIDES CHLORIDE BY IC CHLORIDE BY IC CHLORIDE BY IC SULFATE BY IC SULFATE BY IC SULFATE BY IC LVL #

MBI BS MB1 MB1 BS MBI MB1 BS MB2 MBI MB1 BS MB2 MTX PREP'#-

COLLECTION EXTR/PREP w

w

-W w

w w

-W W

04LRRO24 04LE017 04LE017" 04LICA71 04LICA71 04LICA71 04LICA71 04LICA71 04LICA71 N/A N/A N/A N/A N/A N/A N/A N/A N/A ANALYSIS 11/22/04 11/29/04 11/29/04 12/02/04 12/02/04 12/02/04 12/02/04 12/02/04' 12/02/04 11/22/04 11/29/04 11/29/04 12/02/64 12/02/04 12/02/04 12/02/04 12/02/04 12/02/04 03

Analytical Report Client: TELEDYNE-VERMONT YANKEE W.O.#: 11699-600-005-9999-00 LVL#: 041 1L176 Date Received: 11-17-04 INORGANIC NARRATIVE

1.

This narrative covers the analyses of 5 oil samples.

2.

The samples were prepared and analyzed in accordance with the methods indicated on the attached glossary.

The Sulfate by IC results obtained from the oxygen bomb preparation represent the requested Sulfur analysis (Total Sulfate results were converted to Sulfur). The requested Total Inorganic Chloride is reported as total Chloride by IC from the oxygen bomb preparation due to the nature of the sample matrix.

3.

Sample holding times as required by the method and/or contract were met.

4.

The results presented in this report are derived from samples that did not meet LvLI's sample acceptance policy as noted on the Sample Receipt Checklist.

5.

The method blanks were within the method criteria: MB 04LICA71-MB2 represents the oxygen bomb preparation blank.

6.

The Laboratory Control Samples (LCS) were within the laboratory control limits.

7.

The matrix spike recoveries for Total Halides, Chloride and Sulfate were within the 75-125% control limits.

8.

The replicate analyses for Percent Ash, Chloride and Sulfate were within the 20% Relative Percent Difference (RPD) control limit however replicate analysis for Total Halides was outside the control limit that may be attributed to sample inhomogeneity.

9.

Results for oil samples are reported on a wet weight basis.

Da s

bate Lboratory Managger

(

~ Lionville Laboratory incorporated njp\\1il 1-176 The results presented in this report relate to the analytical testing and conditions of the samples upon receipt and during storage. All pages of this report are integral parts of the analytical data. Therefore, this report should only be reproduced in its entirety of 15 pages.

0 4 208 Welsh Pool Road

Exton, PA 19341-1313 * (610) 280-3000 - Fax (610) 280-3041

Lionville Laboratory Sample Discrepancy Report (SDR)

SDR Initiator.

Batch: c*4[tjLr

i Param.eter: -.,:/"C-.-

Date:

Samples:.

-~--o*-Matrix:

(m3nt:. --C

-V k-.*.Method:

Sws4wMCAWWAV/CLPI Prep. Batch.:.....

1. Reason for SDR

a. COC Discrepancy Tech Profile Error

.<Client Request Sampler Error on C-O-C Transcription Error Wrong Test Code

__ Other

b. General Discrepancy Missing Sample/Extract

__ Container Broken Wrong Sample Pulled

-- Label ID's Illegible Hold Time Exceeded

_ Insufficient Sample

_ Preservation Wrong

__ Received Past Hold improper Bottle Type NotAmenable to Analysis.

Note : Verified by [Log-In] or [Prep Group] (circle)..signatute/date:

c. Problem (Include all relevant specific results; attach data If necessary)

2. Kn.owrn or ProbableCauses(s)

3. Discussion and Proposed Action Other

Description:

,W Entioe Batch-

__ Following Samples:

__.o' 6..

cý (mRe-leach Re-extract..

./,,,,,.

Re-digest

//

Ž/4

-@ -010 Revise EDD

- Change Test Code to

/,/,/*

- Place On/Take Off Hold (circle)

4.

jPrject Manager lnstructions... slgnature/date:

I V."

(4-Cboncur with Proposed Action Disagree with Proposed Action; See Instruction

?.)lnrclude in Case Narrative Client Contacted:

Date/Person Add.

Cancel

5. Final Action... signaturelds te:r E

Other Explanation:

.YXerfied re-[loglleach][extract [di eso nalysis] (circle)

%/Included in Case Narrativje

.3 tC t'z~

&/r&-

o

__Hard Copy COC Revised 0

__Electronic COO Revised

_EDD Corrections Completed.

4

~ i'ia~/~zc~-

When Final Action has been recorded, forward original to OA Specialist for distribution and filing.

Route Distribution of 'Completed SDR.

Route Distribution of Completed SDR X Initiator

-__Metals:

Beegle XRLab General Manager~ M. Taylg~.~

~

2.... Inorganic: Perrone

_T..~Project Mgr StoneIJohntonsg t

GCILC: Kiger R Technical Mgr~ Wesson/Daniels

-MS:

Rychlak/Layma 'n D a D atMan aIVmeiiUF-41 Id m= n Admin:"Soos Sample Prep: Beegle/Kiger

-Other~

Eie

=

OA-1 U5-Ac-U8U1

LionVille Laboratory Incorporated WET CHEMISTRY METHODS GLOSSARY FOR SOIL/SOLIDS SAMPLE ANALYSIS ASTM SW846 OTHER

% Ash

/2t~~

% Moisture D2216-80 iLMO4.0 (e)

% Solids D2216-80 ILMO4.0 (e)

O/o Volatile Solids D2216-80 ASTM Extraction in Water

)-3987-81/85 BTU

-/D240-87

CEC 9081 c

Chromium VI 3060A/7196A Corrosivity by coupon by pH 111 0(mod) 9045C Cyanide, Total

.901 OB ILMO4.0 (e)

Cyanide, Reactive Section 7.3/9014

. Halides, Extractable Organic 9020B EPA 600/4/84-008

-Halides, Total 90QB-o3.

EPA 600/4/84-008 i.,ýroxicity 1310A Flash Point

Z1010 Ignitability 1010 Oil & Grease 9071A Carbon, Total Organic 9060 Lloyd Kahn (mod)

Oxygen Bomb Prep for Anions D240-87(mod)..*

050 Petroleum Hydrocarbons, Total Recoverable 9071 EPA 418.1 pH, Soil 9045C Sulfide, Reactive Section 7.3/9030B Sulfide 9030B(mod)

Specific Gravity D1429-76C/

D5057-90 Sulfur, Total 9056 synthetic Preparation Leach 1312 Paint Filter.

9095A Other:

//1 Method:

to (6

Other,

Ko o0Method L-WI-034B-1BO/O1 0

Lionville Laboratory Incorporated METHOD REFERENCES AND DATA QUALIFIERS DATA QUALIFIERS U =

Indicates that the parameter was not detected at or above the reported limit. The associated numerical value is the sample detection limit.

=

Indicates that the original sample result is greater than 4x the spike amount added.

ABBREVIATIONS MB

= Methbod or Preparation Blank.

MS

= Matrix Spike.

MSD = Matrix Spike Duplicate.

REP = Sample Replicate LC

= Laboratory Control Sample.

NC = Not calculated.

A suffix of-R, -S, or -T following these codes indicate a replicate, spike or sample duplicate analysis respectively.

ANALYTICAL WET CHEMISTRY METHODS

1.

ASTM Standard Methods.

2.

USEPA Methods for Chemical Analysis of Water and Wastes (USEPA 600/4 020).

..3.

Test Methods for Evaluating Solid Waste (USEPA SW-846).

a.

Standard Methods for the Examination of Water and Waste, 16 ed, (1983).:

b.

Standard Methods for the Examination of Water and Waste, 17 ed, (1989)/I8ed (1992).

c.

Method of Soil Analysis, Part 1, Physical and Mineralogical Methods' 2nd ed, (1986).

d.

Method of Soil Analysis, Part 2, Chemical and Microbiological Properties, Am.

Soc. Agron., Madison, WI (1965).

e.

USEPA Contract Laboratory Program, Statement of Work for Inorganic Analysis.

f.

Code of Federal Regulations.

L-WI-034/D-02/01 07

Inorganic Data Summary Report Physical Testing Observation Client: TELEDYNE-VERMONT YANKEE LVL#:0411L176 Anal.te:.

W.O.#: 11699-600-005-9999-00 Date Received: 11-17-04 Observation:

Flash Point No Flash Points observed for samples COMP OIL PLANT SYSTEM, COMP NWH OIL RESERVOIR, COMP CAB OIL RESERVOIR, TRANSFORMER OIL and CRANK CASE OIL.

The samples were heated to approximately 200°F.

p-Xylene was used to determined the accuracy of the flash point apparatus. The p-Xylene will flash at 81 OF + 1 OF. For this test, the p-Xylene flashed at 81 OF.

v jp\\II-176.pt2 vLIV-08

Lionville Laboratory, Inc.

INORGANICS DATA SUtMMARY REPORT 12/08/04 CLIENT: TELEDYNE-VERMONT YANKEE WORK ORDER: 11699-600-005-9999-00 LVL LOT #:

0411L176 SAMPLE

-001 SITE ID COMP OIL PLANT SYSTE ANALYTE

% Ash British Thermal Units Total Halides

-002 COMP NWH OIL RESERVO

% Ash British Thermal Units Total Halides

-003 COMP CAB OIL RESERVO

% Ash British Thermal Units Total Halides

-004 TRANSFORMER OIL

-005 CRANK CASE OIL

-006 COMP OIL PLANT SYSTE

% Ash British Thermal Units Total Halides V Ash British Thermal Units Total Halides Chloride by IC Sulfate by IC Chloride by IC Sulfate by IC Chloride by IC Sulfate by IC Chloride by IC Sulfate by IC RESULT 0.16 5740 98.8 u

0.01 U 15700 442 0.01 U 15300 487 0.01 14900 114 0.42

-17000 111 U

360 3370 312 1090 277 1390 BTU/LB MG/KG BTU/LB MG/KG BTr/LB MG/KG BTTJ/LB MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG REPORTING UNITS LIMIT

'5 0.01 BTU/LB 205 MG/KG 98.8 DILUTION FACTOR 1.0 1.0 1.0 0.01 182 81.4 0.01 215 95.9 0.01 182 94.0 0.01 174 111 141 235 167 55.7 195

65.2 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 10.0 50.0 10.0 10.0 10.0 10.0

-007 COMP NWH OIL RESERVO

-008 COMP CAB OIL RESERVO

-009 TRANSFORMER OIL

-010 CRANK CASE OIL 248 MG/KG 763 MG/KG 223.

74.6 10.0 10.0 Chloride by IC Sulfate by IC 317 3630 MG/KG MG/KG 216 360 10.0 50.0 09

Lionville Laboratory, Inc.

INORGANICS METHOD BLANK DATA SUM4ARY PAGE 12/08/04 CLIENT: TELEDYNE-VERMONT YANKEE WORK ORDER: 11699-600-005-9999-00 SAMPLE.

SITE ID ANALYTE BLANK10 04LA016-MB1 A

Ash BLANKM 04LE017-MB1 Total Halides BLANK10 04LICA71-MB1 Chloride by IC Sulfate by IC BLANK20 04LICA7l-MB2 Chloride by IC Sulfate by IC LVL LOT #:

0411L176 REPORTING RESULT UNITS LIMIT 0.01 U k

0.01 20.0 u

MG/KG 20.0 12.5 u

MG/KG 12.5 4.2 u

MG/KG 4.2 71.4 MG/KG 24.3 209 MG/KG 8.1 DILUTION FACTOR 50.0 1.0 1.0 1.0 2.0 2.0

.10

Lionville Laboratory, Inc.

INORGANICS ACCURACY REPORT 12/08/04 CLIENT: TELEDYNE-VERMONT YANKEE WORK ORDER: 11699-600-005-9999-00 LVL LOT #:

0411L176 SAMPLE

-005

-006 BLANK10 BLANK1 BLANK10 SITE ID.

CRANK CASE OIL COMP OIL PLANT SYSTE 04LRRo2 4-MBl 04LE017-MBI 04LICA71-MBI ANALYTE Total Halides Chloride by IC Sulfate by IC British Thermal Units Total Halides Chloride by IC Sulfate by IC SPIKED SAMPLE 2220 6400 14400 10900 537 232 80.0 INITIAL RESULT 109 360 3370 0.0 20.0 u 12.5 u 4.2 u SPIKED AMOUNT

2350 5630 9410 11400 500 250 83.5

%RECOV 89.5 107.2 117.2 95.5 107.3 92.7 95.8 DILUTION FACTOR (SPK) 1.0 20.0 100 50.0 1.0 1.0 1.0 119

Lionville Laboratory, Inc.

INORGANICS PRECISION REPORT 12/08/04 CLIENT: TELEDYNE-VERMONT YANKEE WORK ORDER:.11699-600-005-9999-00 LVL LOT #:

0411L176 SAMPLE

-001REP

-005REP

-006REP SITE ID COMP OIL PLANT SYSTE CRANK CASE OIL COMP OIL PLANT SYSTE ANALYTE

% Ash Total Halides Chloride by IC Sulfate by IC INITIAL RESULT REPLICATE 0.16 0.18 111 u

156 360 298 3370 3490 DILUTION RPD FACTOR (REP) 11.8 1.0 I1.0 18.8 10.0 3.6 50.0 12

Uonvltle Lab!

ry Use Only 0.1///(-/-?

Custody.Transfer Reco.d(jd b Work Request Page __of/

FIELD PERSONNEL-COMPLETE ONLY SHADED AREAS See SRC Special Instructions:

~

7

%e#v4 cm &5d fA

~e-6tbi~-s DATE REYISIONS:

r7 I

2.

3.

4.

5.

8.

Relinquished r,

by

04'//L /47 F ~

~

1 Iýi:ýý'

'i C

Shipment Number. 2004-114 Date of Shipment: 1119/04 LUonville Laboratory Inc.

208 Walsh Pool Road Ubnvllle, PA 19341-11333 Shipping Method:

UPS.,

FEDERAL EXPRESS From:

17Tm Mccarthy-Radwaste IHazwaste 'Supervisor Vermoht Nuclear Power Station IP.O. Box 157 Governor Hunt Road Vernon, VT 05354-(Phone: 802-258.5476)

(Fail 802-258-548.9)

xxxxxr COMMON Requested Turnaround Time._X_Standard Rush _Working D.ays( specify #)

ANA~VRI~ TO RF PPR~OQMFfl ANLYI TOll BE PVlw m W

p p

Collection Peiod Start Stop

. II 'i I

I I

Waste Oil From Designated Locations I IL mild OTHER E

W Mn 01-CL Sample Amount Volume o weigm (MKS Units) 0 V

'U U

In3 0'U 0o e

.C ti

0 U

CM 0I 0

.3:

0 V.

0 e

10 It-I Sample Type I Descriptlon'l Comments

. !!;I."I arl

!51.r%

1 L

Composite Oil Plant Systems (Rad) 11 8

118 a

100 MLS x

x x

2 L

Composite NWH Oil Reservoir(Rad).

11 8

a 1000 MLS x

x x

3 L

Composite CAB OilReservolr 8

11 8

1000 MLS x

x X.

x x

x X x 4

L.

Transformer Oil 11 8

11 8 1000MLSx x

x x

x T CranicCaseol 11 8

11 8 1000MLS x

x x

7 L

8 L

10 L

Collected By.

DCH Relinquished By: Tim McCartlhy COMMENTS or SPECIAL INSTRUCTIONS Received at laboratyry PROVIDE TWO COPIES OF THE LAB REPORT Date received:

1t7 Send back unused quantities of sample to VY

Lioni'iJle Laboratory Incorporated QSAMPLE RECEIPT CHECKLIST (SRC)..

CLIENT Date:.

Purchase Order / Project# /

SAF# / SOW# / Release #:

LvLI Batch #:

/ *.

Sample Custodian:

NOTE: EXPLAIN ALL DISCREPANCIES I.

Samples Hand Delivered or"E i

Carrier Fr_

Airbill# dW$7'>

69 O0N

2.

Custody seals on coblers or shipping container intact, signed and dated?

3...Outside of.coolers or shipping containers are free from damage?

.4. All expected paperwork received (coc.and other client specific information) sealkd in plastic bag and easily accessible?

5. -Samples received'cooled

6.

Custody seals on sanmple containers intact signed and dated?

7.

coc signed and dated?

8.

Sample containers are intact?..

-.9..All samples on coc received? All samples received on coc?

10.. -.AI sample label information matches coc?

S11. Samples -properlY preserved?

12. -Samples received within hold times?

Short holds taken to wet lab?

13. VOA, TOC, TOX free ofheadspace?

14.*.QC stickers pla~ce on bottles designated by client?

15. Shipment meets LvLI Sample Acceptan.c Policy? (ldentifY all bottles not within policy." See reverse side for policy)

16. Project Manager contacted concerning discrepancies? name/date (or samples outside criteria) aYes 13 No 0-9 ea* s Comrm ents

.. Ye 0 Yes 0 No 0 No Temp 1/:7L

-C 0 Yes or-YDces O N Yets O N C;,Cs

0ON, S

-DN a -.C.S 0' NI D Yes O N Cooler#

ro 0

0 0

D Yes 13 No

N/A Discrepancies SR-002-B 15..

FWýq

'K R, Q - Avowal

k.

, f

'All W."J9000. "MMH UWARMT ShlpmerE nber 2004-114 Date of Sh Pment: 1119104 II II I

I I

C Lionville Laboratory Inc.

208 Welsh Pool Road

. Lionville, PA 19341-1333 Shipping Method:

_UPS FEDERAL EXPRESS COURIER mxx__COMMON From:

Tim McCarthy-Radwaste / Hazwaste Supervisor Vermont Nuclear Power Station P.O. Box 157 Governor Hunt Road Vernon, VT 05354 (Phone: 802-258-5476)

(Fao: 802-258-5489)

Requested Turnaround Time_X_Standard Rush Working Days(specify #)

ANALYSIS TO BE PERFORMED Coollection Perod Start Stp Waste Oil From Designated Locations OTHER 6:z E

(a ci, 0.

E WU to, sample kmount Volume or IAVolnht IMM 108 C-r I E

"0 FE 0

(U 0

zo 0I 0o

.2 (U

O0=

C (U.

0

'0 0.d.

IL Sample Type I Description I Comments

~I ~1 ~IUni ci,

-1 L

-Composite Oil Plant Systems (Rad) 11 8

11 8

1000 MLS x

x x

2 L

Composite NWH Oil Reservoir (Rad) 11 8

11 8

1000 MLS x

x x

x x i 3 L Composite CAB Oil Reservoir 118 118 1000MLS x

x x

x x x x

4 L

Transformer Oil 11 8

11 8

1000 MLS x

x x

5 L

Crank Case Oil 11 8

11 8

1000MLS x

x x

i6 L

7 L

8 L

91 L

10 L

Collected By:.

DCH Relinquished By: TIm McCarthy COMMENTS or SPECIAL INSTRUCTIONS Received at laboratory by:_

PROVIDE TWO COPIES OF THE LAB REPORT Date received:

~wI0

~:

SjIM Shlpme't mber: 2004-114 Date of Shllment: 1119104 Lionville Laboratory Inc.

208 Welsh Pool Road I

Lionville, PA 1934141333 Shipping Method:

_UPS FEDERAL EXPRESS

.COURIER

__xxxxr__COMMON From:

Tim McCarthy-Radwaste / Hazwaste Supervisor Vermont Nuclear Power Station P.O. Box 157 Governor Hunt Road Vernon, VT 05354 (Phone:802-258-5476)

(Fax: 802-258.5489)

C Requested Turnaround Time X Standard Rush Working Days( specify #)

ANALYSIq TQ HE PERFnnurn ANA[V~ TA fl~ 0~(UI~fl(UU~fl r

Collection Perio Waste Oil From Designated Locations

.2

.0 OTHER C;

0~

E co (I3 CL E

cc Sample Am~ount Volume or WPeight (MKS Units)

(U 4'

C, 0

(U 0

0 (D

0.

U.)

d.

0 (D

4)

E (D

E JA Sample Type I Description I Comments MIDI 'm

,1

'115

.~~~~~

~ ~ ~

0

.0

0.

4

.01 j1 0

I LI -

1 L

Composite Oil Plant Systems (Rad) 11 8

11 8

1000 MLS x

x x

2 L

Composlte NWH Ol Reservoir (Rad) 11 8

11 8

1000 MLS x

x x

3 L

Composite CAB Oil Reservoir

.11 8

11 8

1000 MLS x

x x

x 7x x

x 4

L iTransformerOil 11 8

11 8

1000MLS x

x x

5 L

CrankCaseOi1 8

11 8

1000MLSx x

x x

x

x.

x 6

L 7

L 8

L

.9 L

10 L

Collected By:

DCH Relinquished By: Tim McCarthy COMMENTS or SPECIAL INSTRUCTIONS Received at laboratory by:

PROVIDE TWO COPIES OF THE LAB REPORT Date received:

REVIEWED FEB 10.2005 f*FI By

,Lionville Laboratory, Inc.

INORGANIC ANALYTICAL DATA PACKAGE FOR TELEDYNE-VERMONT YANKEE DATE RECEIVED:

11/17/04 CLIENT ID /ANALYSIS LVL #

LVL LOT'#

0411L176 MTX PREP #

COLLECTION EXTR/PREP ANALYSIS COMP OIL PLANT SYSTE

ARSENIC, TOTAL.

ARSENIC, TOTAL

CADMIUM, TOTAL

-CHROMIUM, TOTAL

CHROMIUM, TOTAL

.CHROMIUM, TOTAL LEAD, TOTAL L'r

, TOTAL TOTAL 001 001 REP 001 MS 001 001 REP 001 MS 001 001 REP 001 MS 001 001 REP 001 MS 01 04L0701 01 04L0701 01 04L0701' 01 04L070i 01 04L0701 01 04L0701 01 04L0701 01 04L0701 01 04L0701 01 04L0701 01 04L0701 01 04L0701 COMP NWH OIL RESERVO

ARSENIC, TOTAL

CADMIUM, TOTAL

CHROMIUM, TOTAL LEAM, TOTAL COMP CAB OIL RESERVO 002 002 002 002

. 003 003 003 003 0I 01 0I 01 0I 0I 0I 0I 04L0701 04L0701 04L0701 04L0701 11/08/04 11/08/04 il/08/04 11/08/04

-. 11/08/04 11/08/04 11/08/04 11/08/04 11/08/04 11/08/04 11/08/04 11/08/04 11/08/04.

11/68/04 11/08/04 11/08/04 11/08/64 11/08/04 11/08/04 11/08/04 11/08/04 11/08/04 11/08/04 11/08/04

-11/19/04.

11/19/04 11/19/04 11/19/04 11/19/04 11/19/04 11/19/04 11/19/04 11/19/04 11/19/04 11/19/04 11/19/04 11/19/04"

.11/19/04 11/19/04 11/19/04 11/20/04 11/20/04 11/20/04 11/20/04 11/20/04 11/20/04 11/20/04 11/20/04 11/20/04 11/20/04 11/20/04 11/20/04

.11/20/04 11/20/04 11/20/04 11/20/04

ARSENIC, TOTAL

CADMIUM, TOTAL.

CHROMIUM, TOTAL

LEAD, TOTAL TRANSFORMER OIL

ARSENIC, TOTAL

CADMIUM, TOTAL

CHROMIUM, TOTAL LEAD, TOTAL CRANK CASE OIL 04L0701 04L0701 04L0701 04L0701 11/19/04 11/19/04

.11/19/04

.11/19/04 11/19/04 11/19/04 11/19/04

.11/19/04.

11/20/04 11/20/04.

11/20/04 11/20/04 004

. 004 004 "004 0I 0I 0I 04L0701 04L0701 04L0701 04L0701 11/20/04 11/20/04 11/20/04 11/20/04 A

4IC,. TOTAL 0015 OI 04L0701 11/08/04 11/19/04 11/20/04

Lionville Laboratory,.Inc.

INORGANIC ANALYTICAL DATA PACKAGE FOR TELEDYNE-VERMONT YANKEE DATE RECEIVED:

11/17/04 LVL LOT # :0411L176

CLIENT ID /ANALYSIS LVL #

MTX PREP #

01 04L0701 01 04L0701 01 04L0701 COLLECTION EXTR/PREP ANALYSIS 11/20/04 11/20/04 11/20/04

CADMIUM, TOTAL

CHROMIUM, TOTAL LEAD, TOTAL 005 005 005 11/08/04 11/08/04 11/08/04 11/19/04 11/19/04 11/19/04 LAB QC:

ARSENIC LABORATORY

ARSENIC, TOTAL CADMIUM LABORATORY

CADMIUM, TOTAL CHROMIUM LABORATORY

CHROMIUM, TOTAL Lo LABORATORY Limý TOTAL" LC1. BS MB1 LC1 BS MBI LC1 BS MBI LC1 BS MBI S

S S

S 04i;0701 04L0701 04L0701 04j60701 04L0701 04L0701 04L0701 04LO701 N/A" N/A N/A N/A N/A N/A N/A N/A 11/19/04 11/19/04 11/19/04 11/19/04.

11/19/04 11/19/04 11/19/04 11/19/04 11/20/04 11/20/04 11/20/04 11/20/04 11/20/04 11/20-/04 11/20/04 11/20/04 68680682

~.vL I

Analytical Report Client: TELEDYNE VERMONT-YANKEE W.O.#: 11699-600-005-9999-00 LVL#: 0411L176 Date Received: 11-17-04 METALS CASE NARRATIVE

1.

This narrative covers the analyses of 5 oil samples.

2.

The samples were prepared and analyzed in accordance with methods checked on the attached glossary.

3.

All analyses were performed within the required holding times.

4.

All results presented in this report are derived from samples that met LvLr's sample acceptance policy.

5.

All Initial and Continuing Calibration Verifications (ICV/CCVs) were within control limits.

6.

All Initial and Continuing Calibration Blanks (ICB/CCBs) were within control limits.

7.

All preparation/method blanks were within method criteria. Refer to the Inorganics Method Blank Data Summary.

8.

All ICP Interference Check Standards were within control limits.

9.

All laboratory control samples (LCS) were within the 80-120% control limits. Refer to the Inorganics Laboratory Control Standards Report.

10.

All matrix spike (MS) recoveries were within the 75-125% control limits. Refer to the Inorganics Accuracy Report.

11.

The duplicate analysis for 1 analyte was outside'the 20% Relative Percent Difference (RPD) control limits. Refer to the Inorganics Precision Report.

12.

For the purposes of this report, the data has been reported to the Instrument Detection Limit (IDL).

Values between the IDL and the Practical Quantitation Limit (PQL) are acquired in a region of less-certain quantification.

4ganeer Date

-LHbratory Manager Lionville Laboratory Incorporated

1) gmb/nul1-176

he reait presented in this report relate only to the analytical testing and conditions of the samples at recept and dung storage. AlU pages of this report we integral parts of the 2a08ecal data.Te eforeo Es report should only be reproduced in its entrety of

{6) pag8 208 Welsh Pool'Road

Exton, PA 19341-1313 * (610) 280-3000 e Fax (610) 280-3041

METALS METHOD GLOSSARY The following methods are used as reference for the digestion and analysis of samples-contained within this Leaching Procedure:

1310 1311 1312 -Other:

CLP Metals

_ Digestion and _Analysis Methods:

__ILM03.0

.__ILM04.0 Metals Digestion Methods: __3005A __3010A

-3015 Other_.

3020A ýjOSOJ 3051 200.7 __SS17 Metals Analysis Methods EPA OSWR Aluminum Antimony Arsenic Barium Beryllium Bismuth Boron Cadmium Calcium Chromium Cot*

.Cop r

Iron Lead Lithium Magnesium Manganese Mercury Molybdenum Nickel Potassium Rare Earths Selenium Silicon Silica Silver Sodium Strontium Thallium Tin Titanium Ura.

-d Vanyaum Zinc Zirconium

.SW846 6010B 601011 7041' 60101B __7060As 6010B

_6010B 601011'

_60101 E160101B _7131AA 4

011 E. GNU_ 7191' 60101 60101B 7211.

6010B

.-010B 74215 6010B 74304 60101 6010B 7470A 3 _7471A 3 6010B 6010B

_60101B.7 610.'

6010B11 6010B 7740' 60101B 60101

_6010B 77611 60101 7770'

601011 6010B 7841' 6010B 601011 601011' 6010B 60101B 6010B1' EPA S

_200.7 200.7.

204.2 200.7.. 206.2 200.7

__200.7-200.71

_.200.7 200.7 213.2 200.7 200.7*

218.2 200.7 200.7 220.2 200.7 200.7 239.2 200.7 200.7 200.7

'245.12 245. 52

_200.7 200.7 200.7 258.1 4 200.7' 200.7

.270.2

.200.7 200.7.-

200.7 272.2 200.7 273.14 200.7 200.7 279.2__200.9 200.7 7200.7 200.7' 200.7 200.7 200.7 1 TD MTD 3113B 1620 3113B 1620 1620 1620 1620 USATHAMA 99 99 99.

99 99 99 99 99 99 SS17 99 99 99 99 99 99 99 99.

99.

99 99 99 99 99 99 99 99 99 99.

99

.99 99 99 99 99 3113B 1620 1620 Other'.

Method:

LwM33M-M3

METHOD REFERENCES AND'DATA QUALIFIERS DATA QUALIFIERS U =

Indicates that the parameter was not detected at or above the reported limit. The associated numerical value is the sample detection limit.

=

Indicates that the original sample result is greater than 4x the spike amount added.

ABBREVIATIONS MB

= Method or Preparation Blank.

MS Matrix-Spike.

MSD= Matrix Spike Duplicate.

REP= Sample Replicate" LCS Laboratory Control Sample.

NC = Notcalculated.

ANALYTICAL METAL METHODS L.

Not included in the meth6d element list.

2.

Modified Hg: Hg] and Hg2 require less total volume of digestate due to the autosampler analysis. Sample volumes and reagents for mercury determinations

-in water and soil have been proportionately scaled down to adapt to this semi-automated lechmique. The sample volume us&l for water analysis is 33 mL For soils, approximately.0.3 grams of sample is taken to a final volume of 50 niL (including all reagents).

3.

Flame AA.

4.

Graphite Furnace AA.

L-WI-0303)N-04/98

Lionville Laboratory, Inc.

INORGANICS DATA

SUMMARY

REPORT 11/30/04 CLIENT: TELEDYNE-VERMONT YANKEE WORK ORDER: 11699-600-0OS-9999-00 LVL LOT #: 0411L176 SAMPLE

-.001 SITE ID COMP OIL PLANT SYSTE ANALYTE RESULT UNITS Arsenic, Total Cadmium, Total Chromium, Total Lead, Total Arsenic, Total Cadmium,'Total Chromium, Total Lead, Total 0.24 u 0.03 0.13 0.92 MG/KG MG/KG MG/KG MG/KG REPORTING LIMIT

.ll....l...

0.24 0.03 0.07 0.21 DILUTION FACTOR 1.0 1.0 1.0 1.0

-002 COMP NWH OIL RESERVO 0.25 u MG/KG 0.31.

MG/XKG 0.24 MG/KG 14.7 MG/KG

-003 COMP CAB OIL RESERVO Arsenic, Total Cadmium, Total Chromium, Total Lead, Total TRANSFORMER OIL Arsenic, Total Cadmium, Total Chromium, Total Lead, Total

-005 CRANK CASE OIL Arsenic, Total Cadmium,.Total Chromium. Total Lead, Total 0.32 0.03 U 0.17 11.0 0.25 0.03 u 0.15 0.20 U 0.25 u 0.07 0.25 2.9 MG/KG MG/KG MGIKG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG 0.25 0.03 0.08 0.21 0.23 0.03 0.07 0.19 0.24 0.03 0.07 0.20 0.25 0.03 0.08 0.21 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

Lionville Laboratory, Inc.

INORGANICS METHOD BLANK DATA

SUMMARY

PAGE 11/30/04 CLIENT: TELEDYNE-VERRMONT YANKEE WORK ORDER: 11699-600-O0S-9999-00 LVL LOT #1: 04111;76 REPORTING RESULT UNITS LIMIT SAMPLE SITE ID ANALYTE BLANK2 04L0701-MB1 Arsenic, Total Cad'ium, Total Chromium, Total Lead, Total 0.26 u MG/xG 0.03 u MG/KG 0.1 MG/KG 0.22 u MG/KG 0.26 0.03 0.22 DILUTION FACTOR 1..

70.

1.0 1.0 1.0

Lionville Laboratory, Inc.

INORGANICS ACCURACY REPORT 11/30/04 CLIENT: TELEDYNE-VERMONT YANKEE WORK ORDER: 11699"-600-00S-9999-00 "LVL LOT #: 0411L176 SAMPLE

-001 SITE ID COMP OIL PLANT SYSTE ANALYTE Arsenic, Total Cadmium, Total Chromium, Total Lead, Total SPIKED SAMPLE "164 4.3 17.1 43.0 INITIAL RESULT 0.24u 0;03 0.13 0.92 SPIKED AMOUNT

%RECOV 194 84.5 4.9 87.1 19.4 87.S 48.6 86.6 DILUTION PACTOR (Sx) 1.0 1.0 1.0 1.0

Lionville Laboratory, Inc.

INORGANICS PRECISION REPORT 11/30/04 CI.IENT: TELEDYNE-VERMONT YANKEE WORK ORDER: 11699-600-OOS-9999-00 SITE ID COMP OIL PLANT SYSTE INITIAL ANALYTE RESULT Arsenic, Total 0.24u Cadmium, Total 0.03 Chromium, Total 0.13 Lead, Total 0.92 LVL LOT #:

04111,176 REPLICATE RPD 0.25u NC 0.03 8.6 0.23 36.1

1.

17.5 DILUTION PACTOR (REP) 1.0 1.0 1.0 1.0 o~nnamomma

Lionville Laboratory, Inc.

INORGANICS LABORATORY CONTROL STANDARDS REPORT 11/30/04

CLIENT: TELEDYNE-VERMONT YANKEE LVL LOT #:

0411L176 WORK ORDER: 21699-600-005-9999-00 SPIKED SPIKED

-SAMPLE SITE ID ANALYTE SAMPLE AMOUNT UNITS ARCOv LCS1 04L0701-LCI Arsenic, LCS 914 1000 MG/KG

.91.4 Cadmium, LCS 23.8 25.0 MG/KG 95.2 Chromium. LCS 48.7 50.0 MG/KG 97.4

Lead, LCS 241 250 MG/KG 96.3

Uovl Laoatr Work Only L

Laboratory Custody Transfer Record/Lb Request P

Sl Use Onl a*WorkI*11RequestI"dlMCI P

o M

ie SRC

. (/-/ I IL I fco A

ou

.7,

~~~

Refrigerator #--

~~Ia

~

'#/Type Container~4'~

-~~

Volume,:

Preservatives ORGANIC

~

INO )R Date Rec'd

-7 1/&-

Dae Due ROUESTE KSaltid i

it Lab 11)

Client ID/Descrlption Matrix Qc.

Chosen

. V)

Matrix C I

1!

V ~

f

¶~

7 I'

Date ollected Time Collectsid M'M 1

'a'!

I.

. I' Lionville Laboratory Use Only ci I-,.

I-

,:I (001 F.

L~I I~I ~1U~)4 1

~

A96'3 9

I*

14,5M "01s (

M, M

12 ýA Special Instructions:

V ~L~

DATEIREVISIONS:

2.

,b"13.

-4.

1 1.

Th&j~41 s,~4 (& 1Q~r ReIirJ hod Received

-5.

6.

by Dote J-1(/,

~

.6qllt.174 00*

D Shipment Number 2004-114 Date of Shipment: 1119104 Lionville Laboratory Inc.

I 1208 Welsh Pool Road I

I Lionville, PA 19341-1333 Shipping Method: _UPS.

FEDERAL EXPRESS "f3f'llhIDIlD From:

Tim McCarthy. Radwaste / Hazwaste 'Supervisor.

Vermont Nuclear Power Station P.O. Box 157 GovernorHunt Road Vernon, VT 05354 (Phone: 802-258-5476)

"(Faj: 802.258.5489).

ays( specify #)

ANALYSIS TO BE PERFORMED I

..XXXX__COMMON Requested Turnaround Time.,X Standard Rush __._Working Da

, ap

.~

p

~ m

~

Collection Period Start Stop1

1 Waste Oil From Designated Locations B

I (0

4),

E saffo A4nOUN Voclume or Weighit (MKS units) 4)

Sample Type I Description I Comments 51 A WI I

E

,.2EM A

(U 4)

-j E

.0ao (U

(U 0

I-p.

0 0

0.

IL OTHER IsI n v__

A V,,

m.- i

-1 L

Composlte Oil Plant Systems (Rad) 11 8

i11 8

1000 MLS x

x x

x X

-2 L

Composite NWH Oil Reservoir (Rad) 11 8

11 8

1000 MLS x

x x

x*

x x

x 3

L Composite CAB Oil Reservoir 11 1000 MLS x

x x

4 L

Transformer Oil 11 8

11 8-IO0MLS x

x x

5 L

CrankCaseOil 11 88 IO00MLS " x x

x x

x X

x 6

L "x_

7 L

9 L

10 L

Collected By.

DCH Relinquished By: Tim McCarthy COMMENTS or SPECIAL INSTRUCTIONS Receive("

abory a)d4 R VD W O OF THE LAB REPORT Date re.

t:

If)704 Send back unuse uantities of sample to VY

Lionville Laboratory Incorporated SAMPLE RECEIPT CHECKLIST (SRC)

CLIENT:

Date:.

./7(104 Purchase Order/ Project#

SA1F#l/SOW#I/Release V:

LvLI.Balcht#:

W-/L [

Sample Custodian:

-NOTE: EXPLAIN ALL DISCREPANCIES

1. Samples Hand Deliver.ed or C1I arrier F,9~ 6, Airbill#.

S

'77?4 60.)ON

2.

Custody seals on coblers or shipping container intact, signed and dated?

.3..Outside of~cooleTr or shipping containers are free from damage?

4.. All expected paperwork received (coc.and other client specifiC information) sealed in plastic bag and easily accessible?

5. -Samples received-cooled

6.

Custody seals op sample containers intaci, signed and dated?

7.

coc signed and dated.?

8.

Sample containeas are intact?

.9... All samples on coC received? All samples received on coc?.

10...All sample label information matches coc?

1 1i. Samples properlY preserved?

12. -Samples received within hold times?

Short hiolds taken to wet lab?

13. VOA, TOC, TOX free of headspace?

14: QC stickers placed on bottles designated by client?

15. Shipment meets LvLI Sample Acceptance Policy? (Identify all bottles not within policy.* See reverse side for policy)

16. Project Manager contacted concerning discrepancies? name/date (or samples outside criteria)

O'Ycs o 3Yes o No ONo Oi3-ootais Comrnents Temp /*C.L oC D3 Yes O No Dýes 0 NO

,Y-,ýC~

K No cY"es 0 NO

-Cooler#

11; g es D Yes O Yes AYs D Yes O No

" No o No ONO 1 No NIA ONo 0 No uo Disctcpancies -

SR-002-B

Lionville Laboratory, Inc.

INORGANICS DATA

SUMMARY

REPORT 12/08/04 CLIENT: TELEDYNS-V RMONT YANKEE HORK ORDER: 11699-600-005-9999-00 LVL LOT #:

0411L176 SAMPLE

-001 SITE ID COMP OIL PLANT SYSTE

-002 COMP NWH OIL RESERVO

-003 COMP CAB OIL RESERVO

-004 TRANSFORMER OIL

-005 CRANK CASE OIL

-006 COMP OIL PLANT SYSTE

-007 COMP NWH OIL RESERVO

-008 COMP CAB OIL RESERVO ANALYTE

% Ash British Thermal Units Total Halides

% Ash British Thermal Units Total Halides V Ash British Thermal Units Total Halides V Ash British Thermal Units Total Halides

% Ash British Thermal Units Total Halides RESULT 0.16 5740 98.8 U

0.01 u 15700 442 0.01 u 15300 487 0.01 14900 114 0.42 17000 211 U

UNITS B'IU/LB

'BTQ/LB MG/KG BTV/LB MG/HG BTU/LB MG/KG REPORTING

LIMIT, 0.01 205 98.8 DILUTION FACTOR 1.0 1.0 1.0 0.01 182 81.4 0.01 215 95.9 0.01 182 94.0 0.01 174 ill 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 10.0 50.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0 50.0 Chloride by IC Sulfate by IC Chloride by IC Sulfate by IC Chloride by IC Sulfate by IC Chloride by IC Sulfate by IC Chloride by IC Sulfate by IC 360 WG/HG 141 3370 MG/KG 235 312 HG/HG 1090 MG/KG 167

'55.7 195 65.2 277 1390 MG/HG HG/HG

-009 TRANSFORMER OIL

-010 CRANK CASE OIL 248 MG/KG 223 763 MG/KG 74.6 317 MG/KG 216 3630 MG/KG 360 744JL1~C4 I

4'-

Lionville Laboratory, Inc.

INORGANICS METHOD BLANK DATA

SUMMARY

PAGE 12/08/04 CLIENT: TELEDYNE-VERMO~NT YANK1EE WORK ORDER: 11699-600-005-9999-00 LVL LOT 1: 0411L176 SAMPLE SLANIKlO SITE ID 04LVA016-MB1 ANALYTE

% Ash RESULT 0,01 u UNITS REPORTING LIMIT 0.01 DILUTION FACTOR 50.0 BLANKI 04LE017-MBI BILiNK1O O4LICA71-MB1 BLANX2O 04LICA71-l'B2 Total Halides Chloride by IC Sulfate by IC Chloride by IC Sulfate by IC 20.0 u MG/Ko 12.5 u

HG/KO

4.2 u

MG/KG 71.4 MG/KG 209 MG/KG

.20.0 12.5 4.2 24.3 8.1 1.0 1.0 1.0 2.0 2.0

Lionville Laboratory, Inc.

INORGANICS ACCRACY REPORT 12/08/04 CLIENT: TELEYNE-VE0 ONT YANKEE WORK ORDER: 11699-600-005-9999-00 LVL LOT #:

0411L176 SAMLE

-005

-006 BLANK10 BLANK1 BLANKIO kITE ID CRANK CASE OIL COMP OIL PLANT SYSTE 04LRR024-MBl 04LE017-MBI 04LICA71-MBI SPIKED ANALYTE SAMPLE Total Halides 2220 Chloride by IC 6400 Sulfate by IC 14400 British Thermal Units 10900 Total Halides 537 Chloride by IC 232 Sulfate by IC 80.0 INITIAL RESULT 109 360 3370 0.0 20.0 u 12.5 u 4.2 u SPIKED AMD=

%RECOV 2350 89.5 5630 107.2 9410 117.2 11400 95.5 500 107.3 250 92.1 83.5 95.8 DILUTION FACTOR (Spx) 1.0 20.0 100 50.0 1.0 1.0 1.0

Lionville Laboratory, Inc.

INORGANICS PRECISION REPORT 12/08/04 CLIENT TELEDYNE-VERMONT YAN~KEE WORK ORDlER: 11699-600-OOS-9999-O0 SAMPLE

-001REP

-O05REP

-006REP SITE ID ANALYTE COMP OIL PLANT SYSTE

% Ash CRANM CASE OIL Total Walides COMP OIL PLANT SYSTE Chloride by IC Sulfate by IC LVL LOT #. 0411L176 INITIAL RESULT REPLICATE RPD

=s 0.16 0.18 11.8 111 u

156 NC 360 298 18.8 DILUTION FA*TOR (REP) 1.0 1.0 10.0 50.0 3370 3490 3.6

y Licville.

Laboratory, Inc.

INORGANICS DATA SUMRY RIPORT 11/30/04 CLIxMr: TWLDYKR-VBRMONTI YTM8I2 WORK ORDER: 11699-600-00S-9999-00 LVL LOT #:

0411L176 REPORTING LIMIT SAMPLE

'ITE 1D ANALmT" RESULT UITS

..... 1 n.......

-001 COMP OIL PLANT SYSTE

-002 COMP NWH OIL RESERVO

-003 COMP CAB OIL RESERVO TRANSPOR14NR OIL

-005 CFLNK CASE OIL Arsenic, Total Cadmium, Total Chroium, Total Lead, Total Arsenic, Total Cai*mum, Total chromium, Total Lead, Total Arsenic, Total Cadmium, Total Chromium, Total Lead, Total Arsenic, Total Cadmium, Total Chromium, Total Lead, Total Arsenic. Total Cadmium, Total chromium, Total Lead, Total 0.24 0.03 0.13 0.92 0.2S 0.31 0.24 14.7 0.32 0.03 0,17 11.0 0.2S 0.03 0.1S 0.20 0.25 0.07 0.2S 2.9 u

NG/KG MG1i MG/KG u

NO/=

HG/KG U

HG/KG HG/KG MG/KG u

MG/K KG/KG u

G/KG H G/KG No/=

MG/KG MG/KG 0.24 0.03 0.07 0.21 0.25 0.03 0.08 0.21 0.23 0.03 0.07 0.19 0.24 0.03 0.07 0.20 0.2S 0.03 0.08 0.21 DILUTION FACTOR 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

Lionville Laboratory, Inc.

nmoRGAics xWTHOD BLLMO DATA SUMOhRY PAGE 11/30/04 CLIENT: TELEDY)5E-V M ONT YANKCEE WORK ORDER: 11699-600-005-9999-00 SAMPLE BLANX1 SITS XD ANALYTE 04L0701-MBI Arsenic, Total Cadmium, Total Chromium, Total Load. Total LVL LOT #: 0411L176 RNPORTING RESULT UNITS LIMIT 0.26 U 1G/KG 0.26 0.03 U "G/KG 0.03 0.1 HG/KG 0.08 0.22 U MG/KG 0.22 FACTOR 1.0 1.0 1.0 1.0

Lionville Laboratory, Inc.

INORGANICS ACCURACY REPORT 11/30/04 C.IEN"s TRLD

-V'IMONT YANKEE LVL LOT 0: 0411L176 WORK ORDER. 11699-600-005-9999-00 SPIKED INITIAL SPIKED DILUTION SAMPLE SITE ID ANALYTE SAMPLE RESULT ACMONT

%RRCOV FACTOR (PK)

... mn..

-001 COMP OIL PLANT SYSTE Arsenic. Total 164 0.24u 194 84.5 1.0 Cadmium, Total 4.3 0.03 4.9 87.1 1.0 Chromium, Total 17.1 0.13 19.4 87.5 1.0 Lead, Total 43.0 0.92 48.6 86.6 1.0

Lionville Laboratory, Inc.

INORGANIC PREISXION REPORT 11/30/04 cIR~Itn TSLRflTNR-VRRMONT YA1I)3E WORK ORDER: 2.1613-600-005-9993-00 LVL LOT #g 04111.176 INITIAL RESULT REPLICAT RPO SAMPLE SITE ID ANALYTE

-001REP COMP OIL PLANT BYSTE Arsenic, Total 0.24u Cadmium, Total 0.03 Chromium, Total 0.13*

Lead, Total 0.92 0.25u NC 0.03 9.6 0.23 56.1 1.1 17.5 DILUTION iACTOR (REP) 1.0 1.0 1.0 1.0

Liony ll. Laboratorz.

Inc.

.NORCANICS LABORATORY COTROL STANDARDS REPORT 12/30/04 CLIENT: TELEDYNX-VERMON'T YANKEN WORK ORDER: 11699-600-005-9999-00 LVL LOT #s 0411L176 I.-

SAMPLE LC52.

sBITE D

AHALMT 04L0701-LCI Arsenic, LCS cadmium, LCS

.Chromium, LCS Lead, LCS SPIKED SPIKED SAMPLE ANOOMT 914 1000 23.8 25.0 48.7 SO.0 241 250 IRIITS MG/KG N0/KG;

%RECOV

.91.4 97.4 96.3

RFW Batch Number: 0411L176 Lionville LV-Ja to0ry, Inc.

Cl~~~~PCý Sy GC

~~lY~V1MW1V~W Report. Date: 11/30/04C 35 nrdpre 116qqgnnonn pAcyp.

I RFKhtch Number: 0411LI76 Clit-nt--!

TELEDYNE -VERMONT YANKEE Work Sample Information Cust ID: COMP OIL PLA COMP MWH OIL NT SYSTE RESERVO RFW#:

001 002 Matrix:

OIL OIL D.F.:

20.0 20.0 Units:

UG/KG UG/KG COMP CAD OIL RESERVO 003 OIL 20.0 UG/KG TRANSFORMER CRANK CASE OIL OIL 004 005 OIL OIL 20.0 20.0 UG/KG UG/KG PBLKAS 04LE1405-MBI SOIL 1.00 UG/KG Surrogate:

Tetrachloro-m-xylene D

D D

W D

t D

116 t

Decachlorobiphenyl D

D D

106 V

l........

l...........ufl c

a f

f i

n n

s fli.......

...fl.......

.... fl u......fl

.Aroclor-1016 Aroclor-1221

.Aroclor-1232 Aroclor-l242 Aroclor-1248 Aroclor-1254 Aroclor-1260 8000 U

8000 8000 8000 8000 8000 8000 U

U U

U 8000 U

8000 U

8000 8000 8000 8000 8000 8000 8000 U

U U

8000 8000 8000 8000 8000 8000 8000 U

U U

8000 8000 8000 8000 8000 8000 8000 U

U U

400 400 400 400 400 400 400 U

U U

Cust ID: PBLKAS BS PBLKAS BSD Sample RFW#: 04LEI40S-MB1 04LE1405-MB1 Information Matrix:

SOIL SOIL D.F.:

1.00 1.00 Units:

UG/KG UG/KG Surrogate:

Tetrachloro-m-xylene 124

t 118 Decachlorobiphenyl 114 110 V

Aroclor-1016 124 V

120 V

Aroclor-1221 400 U

400 U

Aroclor-1232 400 U

400 U

Aroclor-12_2 400 U

400 U

Aroclor-1248 400 U

400 U

Aroclor-1254 400 U

400 U

Aroclor-1260 119 117 W

U-Analyzed, not detected. J-Present below detection limit. B-Present in blank. NR-Not reported.

NS-Not spiked.

t= Percent recovery.

Da Diluted out.

I-Interference.

NA= Not Applicable.

- Outside of EPA CLP QC I

1,Q* N, Iffli ý ý Shipr' Number 2004-114 D

pment: 1119104 L

Lionvile Laboratory Inc.

1208 Welsh Pool Road ILionville.

PA 19341-1333 C

I Shipping Method:

UPS____U FEDERAL EXPRESS COURIER xxxxxCOMMON From:

TIm McCarthy-Radwaste / Hazwaste Supervisor Vermont Nuclear Power Station P.O. Box 157 Governor Hunt Road Vernon, VT 05354 (Phone: 802.258.5476)

(Fax: 802.258.5489)

Requested Turnaround Time__XStandaril Rush _Working Days(specify #)

ANALYBIB TO RE P1211RFORED Collctio Stop Waste Oil From Designated Locations I OTHER 6z Sample Amount Volume or Weight (MKS Units) 8.2I I II a.I Sample Type I Description I Comments I

L Composite Oil Plant SXtems (Rad) 11 8

11 8

1000 MLS x

x x

2 ComposlteNWHOilReservoir(Red) 11 8

11 8

1000MLS x

x x

x X

X X

x x

3 L

Composite CAB Oil Reservoir 11 8

1

-8 1000 MLS x

x x

4 Transformer Oil I

TN 11 8

1000MLS x

x x

x 5

L Crank Case Oil 1

-8 11 8

1100MLS x

x x

x 6

L 7

L 8

L 10 L

Collected By:

DCH Relinquished By:. Tim McCarthy COMMENTS or SPECIAL INSTRUCTIONS Received at laboratory by_..

PROVIDE TWO COPIES OF THE LAB REPORT Date received:

Send back unused quantities of sample to VY

s..

........-'.'...........

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