ML050750545

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3/18/05, Kewaunee, Summary of Telephone Conference Steam Generator Water Chemistry Excursion (TAC No. M40695)
ML050750545
Person / Time
Site: Kewaunee Dominion icon.png
Issue date: 03/18/2005
From: Raghavan L
NRC/NRR/DLPM/LPD3
To: Mohseni A
NRC/NRR/DLPM/LPD3
Lyon C, NRR/DLPM, 415-2296
References
TAC M40695
Download: ML050750545 (4)


Text

March 18, 2005 MEMORANDUM TO: Aby Mohseni, Acting Director Project Directorate III Division of Licensing Project Management Office of Nuclear Reactor Regulation FROM: L. Raghavan, Chief, Section 1 /RA/

Project Directorate III Division of Licensing Project Management Office of Nuclear Reactor Regulation

SUBJECT:

KEWAUNEE NUCLEAR POWER PLANT -

SUMMARY

OF TELEPHONE CONFERENCE RE: STEAM GENERATOR WATER CHEMISTRY EXCURSION (TAC NO. M40695)

This memorandum summarizes the telephone discussion on March 3, 2005, between U. S. Nuclear Regulatory Commission staff and Nuclear Management Company, LLC (the licensee) regarding a steam generator chemistry excursion at the Kewaunee Nuclear Power Plant on February 20, 2005. Nuclear Reactor Regulation staff (K. Karwoski, F. Lyon, et al.)

and licensee staff (K. Hoops, W. Flynt, G. Riste, et al.) participated in the call.

During a plant shutdown/cooldown on February 20, 2005, approximately 1000 gallons of service water, which is drawn from Lake Michigan, entered the secondary side of the steam generators at Kewaunee. Additional information regarding the cause of the shutdown is provided in Preliminary Notification PNO-III-05-003, Shutdown in Excess of 72 Hours Due to Auxiliary Feedwater System Declared Inoperable Due to High Energy Line Break Concerns" (ADAMS ML050540652) and in Event Notifications 41423 and 41425.

The enclosed summary provides the details of the staff's discussion with the licensee. No regulatory decisions were made during the call. The staff did not identify any immediate or additional safety concerns to the licensee.

Docket No. 50-305

Enclosure:

As stated

March 18, 2005 MEMORANDUM TO: Aby Mohseni, Acting Director Project Directorate III Division of Licensing Project Management Office of Nuclear Reactor Regulation FROM: L. Raghavan, Chief, Section 1 /RA/

Project Directorate III Division of Licensing Project Management Office of Nuclear Reactor Regulation

SUBJECT:

KEWAUNEE NUCLEAR POWER PLANT -

SUMMARY

OF TELEPHONE CONFERENCE RE: STEAM GENERATOR WATER CHEMISTRY EXCURSION (TAC NO. M40695)

This memorandum summarizes the telephone discussion on March 3, 2005, between U. S. Nuclear Regulatory Commission staff and Nuclear Management Company, LLC (the licensee) regarding a steam generator chemistry excursion at the Kewaunee Nuclear Power Plant on February 20, 2005. Nuclear Reactor Regulation staff (K. Karwoski, F. Lyon, et al.)

and licensee staff (K. Hoops, W. Flynt, G. Riste, et al.) participated in the call.

During a plant shutdown/cooldown on February 20, 2005, approximately 1000 gallons of service water, which is drawn from Lake Michigan, entered the secondary side of the steam generators at Kewaunee. Additional information regarding the cause of the shutdown is provided in Preliminary Notification PNO-III-05-003, Shutdown in Excess of 72 Hours Due to Auxiliary Feedwater System Declared Inoperable Due to High Energy Line Break Concerns" (ADAMS ML050540652) and in Event Notifications 41423 and 41425.

The enclosed summary provides the details of the staff's discussion with the licensee. No regulatory decisions were made during the call. The staff did not identify any immediate or additional safety concerns to the licensee.

Docket No. 50-305

Enclosure:

As stated DISTRIBUTION:

PUBLIC MMurphy YDiaz-Castillo PD3-1 R/F DHills, RIII THarris FLyon KKarwoski LRaghavan LMiller LLund NMorgan ADAMS Accession Number: ML050750545 *memo to LRaghavan OFFICE PDIII-1/PM PDIII-1/LA EMCB/SC PDIII-1/SC NAME FLyon THarris LLund* LRaghavan DATE 03/18/05 03/17/05 3/14/05 03/18/05 OFFICIAL RECORD COPY

SUMMARY

OF MARCH 3, 2005, CONFERENCE CALL STEAM GENERATOR WATER CHEMISTRY EXCURSION NUCLEAR MANAGEMENT COMPANY, LLC KEWAUNEE NUCLEAR POWER PLANT DOCKET NO. 50-305 On March 3, 2005, the Nuclear Regulatory Commission staff participated in a conference call with representatives from Nuclear Management Company, LLC (NMC, the licensee) regarding a steam generator water chemistry excursion at Kewaunee Nuclear Power Plant.

A summary of the information provided by the licensee during the call is provided below.

Kewaunee has two steam generators designed by Westinghouse and fabricated by Ansaldo Energia. The steam generators were installed in 2001. The thermally-treated Alloy 690 steam generator tubes have an outside diameter of 0.875-inch and a nominal wall thickness of 0.050-inch. The tubes are hydraulically expanded for the full depth of the tube sheet at each end and are supported by a number of stainless steel tube support plates and anti-vibration bars.

During a plant shutdown/cooldown February 20, 2005, approximately 1000 gallons of service water, which is drawn from Lake Michigan, entered the secondary side of the steam generators at Kewaunee. Additional information regarding the event is provided in Preliminary Notification Report, PNO-III-05-003, Shutdown in Excess of 72 Hours Due to Auxiliary Feedwater System Declared Inoperable Due to High Energy Line Break Concerns" (ML050540652) and in Event Notifications 41423 and 41425.

At the time of the introduction of the service (Lake Michigan) water, the steam generator pressure was 62 pounds per square inch gauge (psig) in Steam Generator A and 56 psig in Steam Generator B. The saturation temperatures associated with these pressures are 309 EF and 304 EF, respectively.

The typical chemical composition of Lake Michigan water is 5 parts per million (ppm) sodium, 38 ppm calcium, 12 ppm magnesium, 144 ppm bicarbonate, 10 ppm chloride, and 22 ppm sulfate. The total dissolved solids is 233 and the pH is 8.5.

The steam generator secondary water pH never dropped below 9.5 during this excursion.

Steam Generator B was considered to have the most off-normal water chemistry. It had 397 parts per billion (ppb) sodium, 2.03 ppm calcium, 699 ppb magnesium, 618 ppb chloride, and 1.47 ppm sulfate. The pH was 9.85. The licensee is following the Electric Power Research Institute (EPRI) water chemistry guidelines.

After the introduction of the service (Lake Michigan) water, Kewaunee interacted with EPRI and Westinghouse experts. They evaluated the near- and long-term implications of the water chemistry excursion, particularly with respect to the potential for the water chemistry

to result in cracking or pitting of the steam generator tubes. With respect to cracking in the near-term, they do not anticipate any cracking given the Alloy 690 tube material, the low temperature at the time of the service water introduction, and the absence of any appreciable heat flux at the time. With respect to pitting in the near-term, they do not anticipate any pitting since the secondary water was not highly oxidizing or acidic nor did it contain any copper. In the long-term, there is a possibility that the service water impurities (e.g., chlorides) could accumulate in deposits including sludge collars on the tubes. Given the recent replacement of the steam generators, the low iron transport into the steam generators, and the minimal heat flux following the service water introduction, flushing the impurities from the steam generators was recommended to avoid any long-term impact of the chemical excursion.

In order to drain and refill (flush) the steam generators, the auxiliary feedwater piping had to be flushed since it still contained service water. The piping was flushed through the auxiliary feedwater pump casing drain and a downstream drainline in the pipe. Some of the sections of the pipe could not be flushed so the water was introduced into the steam generators. The flushing operation was completed on February 24, 2005. On February 27, 2005, Steam Generator B was drained and refilled, and on February 28, 2005, Steam Generator A was drained and refilled. After the flush, the steam generators contained less than 100 ppb chloride. One more drain and refill is planned for the week of March 7, 2005.

The licensee reviewed related operating experience and identified a phosphate excursion at Vogtle Electric Generating Plant in 2002 (see ADAMS ML031150065 and ADAMS ML042430424). This excursion was considered more limiting since it involved thermally treated Alloy 600 tubes. To date, Vogtle has not identified any corrosion degradation in their steam generators.

The next steam generator tube inspections at Kewaunee are planned for April 2006.