ML033370067
| ML033370067 | |
| Person / Time | |
|---|---|
| Site: | Cook  |
| Issue date: | 11/20/2003 |
| From: | Zwolinski J Indiana Michigan Power Co |
| To: | Document Control Desk, Office of Nuclear Reactor Regulation |
| References | |
| AEP:NRC:2401-09 | |
| Download: ML033370067 (18) | |
Text
Indiana Michigan Power Company 500 Circle Drive Buchanan, MI 49107 1395 INDIANA MICHIGAN POWER November 20, 2003 AEP:NRC:2401-09 10 CFR 50.4 Docket Nos: 50-315 50-316 U. S. Nuclear Regulatory Commission ATTN: Document Control Desk Mail Stop O-P1-17 Washington, D.C. 20555-0001 Donald C. Cook Nuclear Plant Units 1 and 2 EHC HYDRAULIC FLUID SPILL NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM AND GROUNDWATER DISCHARGE AUTHORIZATION NOTIFICATION Indiana Michigan Power Company is the holder of National Pollutant Discharge Elimination System (NPDES) permit MI0005827 and Groundwater Discharge Authorization (GDA) permit M00988 for the Donald C. Cook Nuclear Plant (CNP). Appendix B, Part II, Section 3.2 of the Environmental Technical Specifications to Facility Operating Licenses DPR-58 and DPR-74 requires violations of the NPDES Permit to be reported to the Nuclear Regulatory Commission (NRC) by submittal of copies of the reports required by the NPDES Permit.
In a letter dated November 20, 2003, the Michigan Department of Environmental Quality (MDEQ) was notified that approximately /2-liter of Fyrquelo EHC Fire Resistant Hydraulic Fluid was released to the turbine room sump and then to the on-site absorption pond through discharge Outfall OOD. A sustained high wind condition from November 11-13, 2003, caused the vapor extraction circuit to malfunction, forcing an abnormal amount of EHC fluid from the drain line into an overflow pan. The pan was designed to collect minor leakage from the extraction circuit and was overwhelmed when the system malfunctioned.
Approximately 5 gallons leaked to the floor inside of the turbine building. A very small amount of the fluid (approximately /2-liter) reached a floor drain, where it was released through discharge Outfall OOD. An immediate notification to the Pollution Emergency Alert System was made on November 13, 2003, at 2330 hours0.027 days <br />0.647 hours <br />0.00385 weeks <br />8.86565e-4 months <br /> after verification of product loss to the floor drain.
U. S. Nuclear Regulatory Commission AEP:NRC:2401-09 Page 2 Written notification was provided to the MDEQ per Part II, Section C.7 of the NPDES Permit and Part II, Section A.7 of the GDA permit. In accordance with the Environmental Technical Specifications, a copy of the report to the MDEQ is being provided to the NRC as an attachment to this letter.
This letter contains no new commitments.
Should you have any questions or concerns regarding this notification, please contact John P. Carlson, Environmental Manager, at (269) 465-5901, extension .1153.
Sincerely, John A. Zwolinski Director, Design Engineering and Regulatory Affairs JEN/jen attachment c: J. L. Caldwell - NRC Region III K. D. Curry - AEP Ft. Wayne, w/o attachment J. T. King - MPSC, w/o attachment MDEQ - WHMD/HWRPS, w/o attachment NRC Resident Inspector M. A. Shuaibi - NRC Washington, DC
ATTACHMENT TO AEP:NRC:2401-09 NOTIFICATION TO MICHIGAN DEPARTMENT OF ENVIRONMENTAL QUALITY
Indiana Michigan Power Company ..
500 Circle Drive . . -. ; . . . - ;
Buchanan, Ml 49107 1395
- - -: -- :: -- . --- -- -;-.- INDIANA -,
MCHIGAN Mr. John Vollmer, District Supervisor.
Michigan Department of Environmental Quality.
Surface 'Water'Quality Division .
- 7953.Adobe Road',
Kalamazoo, Michigan 49009 November 20, 2003' .
Dear Mr. Vollmer:
Subject:
' ...Donald C. Cook Nuclear Plant
- NPDES Permit No. MI 0005827 Donald C. Cook Nuclear Plant
..Groundwater Discharge'Authorization M 00988 This notification is made pursuant to Cook Nuclear Plant's NPDES .Permit MI 0005827,Part II.'Section C.7, Spill Notification.,- .... . . . . -
This notification is.made pursuant to Cook Nuclear Groundwater.
Discharge Authorization M:00988,. Part II. Section A.7,' Spill Notification. -
On November 13, 2003.at approximately 2300 hrs,.approximately '-
liter of Fyrquel EHC Fire Resistant'Hydraulic-Fluid was released to the Turbine Room Sump and then to the on-site
- . absorption pond through Outfall 00D.' -
A sustained.high wind:condition with maximum gusts up to 69 mph from 11/11/03 to 11/13/03'caused the vapor extraction circuit to malfunction,.forcing.an abnormal amount of EHC from the-drain line'onto an'overflow pan. The pan was designed to '
.collect minor'leakage from the extraction circuit. :'The pan was
. overwhelmed when the system malfunctioned. Approximately five gallons leaked to 'the floor -inside of the turbine building.' A very. small amount'of.the fluid reached'a floor drain, where it was released through-Outfall-OOD. An immediate notification to'.
-the Pollution Emergency Alert'System was done on.11/13/03 2330'
- ' hrs,.after verification of product-loss to.theifloor drain.
This fluid is denser than water, and'will sink to the bottom of the sump. This'characteristic,'along with the small'amount of product lost,.made the spill non-recoverable.-Plant personnel
- : .were dispatched to contain and clean up'-the spill.. .
Weather'conditions at theplant.have returned to'normal, and . .
- -' the vapor' extraction circuit is .operating properly. 'The drain'.'.-
line is currently funneled to a 55 gallon drum in a containment 2003-1724
Mr. John Vollmer.
'November 20, 2003 -
Page 2
.Re: Cook Nuclear.Plant:. -
NPDES Permit No. MI.0005827 ;
Groundwater Discharge Authorization-M 00988 :
The
..area.where potential leakage.'would be collected.
underway and a permanent'-
preventive action investigation'is will take place'when the Unit is taken solution to this issue line. This spill does not':pose .a threat to the off environment,- public health or safety. -
(269) 465-5901 Should you'.have any questions, please contact me at extension 1153.;:
Sincerely, J hn P.C on nvironmental'Manages' Enclosure . -
c: Mr. 'Greg'.Danneffel,.MDEQ - Kalamazoo USNRC per Appendix B. T. S. Page 2
-S
.e R --. .- -
, - ,, . . . . . -~~~~~~~~~~~~~
Mr. John Vollmer November 20, 2003 Page 3 Re: Cook Nuclear Plant
.NPDES Permit No. MI 0005827 Groundwater Discharge Authorization M 00988 I certify under penalty of law that I have personally examined and am familiar with the-information submitted on this and all attached documents; and based on my inquiry of-those individuals...immediately responsible for obtaining the information, I'believe'the submitted information is true, accurate'and complete. I am aware that there are significant penalties for submitting' false information, including the possibility of fine and imprisonment. .
.Jensen Site Vice President I
Mr. John: Volmer November 20, 2003
.Page 4 Re: :Cook'Nuclear Plant NPDES Pertuit No. MI'0005827'
.Groundwater Discharge .Authorization-M 00988 --
bc:' J. F.Butcher
-J. P. Carlson:
- M., J. Finissi.
C. E. Hawk J. N. Jensen D.-S. Naughton M. K.'-Nazar W.. H. Schalk S.-: Vazquez
. -Watson.
'W.: D. Wood T. Woods' B. K. Zordell
Akzo Nobel Functional.Chemicals LLC
. MATERIAL SAFETY'DATA SHEET ,
DATE PRINTED:. 5/27/2003- - PAGE 1 FYRQUEL EHC- -.. .:.;..,:- .. : .., '-. ..'MSDS.NO. 16-084461 EHC SFYRQUEL C P A C INFORMATION'
, , - ,SECTION' '.'HMCLPOUTADCOMPANY'INFO ':
PRODUCT NAME CHEMICAL NAME
-'FYRQUEL EHC Mixture SYNONYM -CHEMICAL FORMULA Mixture . Mixture CAS# .. ... -.. - CHEMICAL'FAMILY MIXTURE . . . .. . ' Aryl phosphate..'.
' MANUFACTURERS NAME PRODUCT/TECHNICAL INFORMATION Akzo Nobel Functional Chemicals LLC 1-800-666-1200 ADDRESS - MEDICAL/HANDLING EMERGENCY' 5 Livingstone Avenue' . , : .: 1-914-693-6946 Dobbs Ferry, NY 10522 '-
COUNTRY TRANSPORTATION EMERGENCY USA CHEMTREC 1-800-424-9300 PRODUCT USE . ' . - . - - -REVISION DATE Fire-resistant hydraulic fluid ' .2/06/2003 ISSUE DATE . . . -.
REVISION NO.
6/19/1995 . .- '- . , 009 SECTION: 2.:COMPOSITION/INFORMATION ON INGREDIENTS SUBSTANCE DESCRIPTION PERCENT CAS
. Trixylenyl phosphate . . . . ., - 40.000- 50.000 25155-23-1
- t-Butylphenyl diphenyl phosphate . '. 15.000- 21.000 56803-37-3 Bis(t-butylphenyl) phenyl phosphate . .. . -15.000- 21.000 65652-41-7 Tri(t-butylphenyl) phosphate,::- 5.000- 9.000 78-33-1 Triphenyl phosphate . . 7.500- 15.000 115-86-6 SECTION 3. HAZARDS IDENTIFICATION
'Appearance & Odor. .
Clear liquid;,essentially odorless.,...
STATEMENT OF HAZARDS-ay cause~mild--skin M.Inalatic Mayhaustiiosinan n of vapor and-eye or mist tymay irritation.'
irritationccause respiratory . traCt-irritation.
may cause nerve damage.'.if inhaled, swallowed, or absorbed through the skin.,
May cause cholinesterase inhibition.
Fire & Explosion Hazards This product is not defined as flammable or combustible. It is
-self-extinguishing'once the source of ignition is removed. The material is not sensitive to static discharge or physical impact'.
It may decompose under fire conditions.
Primary Route of Exposure Skin contact andinhalation are.the primary, routes of exposure to this'product.
Inhalation Acute Exposure' Inhalation of vapors or mists may cause respiratory tract irritation.- Inhalation.may cause cholinesterase.inhibition and nerve damae' (see Section ,."Note to'Physician,"for signs and' symptoms o these effects).-
Akzo Nobel Functional Chemicals LLC MATERIAL -SAFETY DATA SHEET
DATE PRINTED: 5/27/2003 - - PAGE 2-
- - - ;: - :--; -- ,MSDS NO. 16-084461 FYRQUEL EHC SECTION_ 3. HAZARDS IDENTIFICATION (CONTINUED)
Skin Contact - ACUTE Skin contact may cause mild'irritation. '- '
May cause nerve damage and cholinesterase inhibition if absorbed through the skin. See Section 4,'*"Note to; Physician,'"for signs and symptoms of these effects.
Eye contact - ACUTE Eye contact may cause mild irritation.
Ingestion - ACUTE Ingestion'may cause gastrointestinal'tract irritation and diarrhea.
May cause cholinesterase inhibition and nerve damage. See Section' 4, "Note to Physician;," for signs and symptoms of these effects.
CARCINOGENICITY IARC .... NO OSHA .... NO NTP .... NO ACGIH .... NO SECTION :4. FIRST AID.-MEASURES Inhalation First Aid - . .
If inhaled, remove victim to fresh air.- If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical attention. ,
Skin Contact - First Aid Immediately remove contaminated clothing and shoes. Under a safety shower, wash all-affected areas with soap and lenty'of water for at least 15 minutes. Get medicalattention. wash clothing before reuse. Thoroughly:clean or destroy contaminated shoes.
Eye Contact - First Aid Immediately flush eyes with plenty of water for at least 15-minutes. If easy to do, remove contact lenses, if.worn. Hold-the eyelids apart during the flushing to ensure rinsinq of the entire surface of the-eye and lids. Get medical attention if irritation develops and persists.
Ingestion - First Aid Get medical attention by callinga physiian or a poison control center immediately. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, keep head below hips to reduce the risk of-aspiration. Never.give anything.by mouth to an unconscious person.-
- Medical conditions aggravated - ---
Persons with pre-existing neuromuscular disorders may be at an increased risk from exposure to-this material.'
Note to Physician - -
- This product contains trixylenyl phosphate and triphenyl phosphate... '
Overexposure to this product by ingestion, inhalation or through
-skin absorption may produce -abdominal pain nausea and vomiting.-. :
DelaLyed eflects -such.as-peripheral neuropahy and cholinesterase in-hibition may. result.' Symptoms of peripheral neuropathy my include:.
diarrhea, conjunctivitis, laryngitis, rhinitis pharyngitis, distal-
- . : extremity paresthesias- and cramping pain in tie calves. Later.-
symptoms may include: laccid paralysis followed by-spasticity of the lower extremities resulting in a spastic gait. .
Symptoms of cholinesterase inhibition-may include:-headache,'nausea, -
sweating,- numbness and tingling of the hands and feet, salivation,-'
muscle witching, tremors, incoordination, blurred vision,-:tears, abdominal cramps, diarrhea, and.chest discomfort.- In cases of
Akzo Functional Chemicals LLC 1bel
-:MATERIAL SAFETY DATA SHEET DATE PRINTED:. 5/27/2003 PAGE .3
- RUEL E.C -". . .-. NO. 16-084461
......... .. , - ..... - . . -MSDS FYRQUEL EHC - - ..~::: ;.
- .SECTION :.4. FIRST AID MEASURES - .
(CONTINUED) . . ; -
cholinesterase inhibition atropine by injection-is antidotal.
Pralidoxime chloride (2-PIkM; Protopam chloride) is also antidotal when administered early and in conjunction with atropine'... .
SECTION.. 5.' FIRE FIGHTING MEASURES FLASH POINT - . - FLASH METHOD 225.00 F .107.22 C . - . . SETA CLOSED CUP
-GREATER THAN--
AUTO IGNITION TEMPERATURE - UPPER EXPLOSION LIMIT 1030.00 F . 554.44 C N/D LOWER EXPLOSION LIMIT.
N/D
-Extinguishing Media Use water fog or.spray, dry chemical,.foam or carbon dioxide extinguishing agents..-'
Fire Fighting Procedures AS in any fire, prevent human exposure to 'fire ;'smoke,' fumes or roducts of combustion. .Evacuate non-essentiai personnel from the ire area... Firefighters should wear full-face, .self-contained breathing apparatus and impervious protective clothing.. If pos- .
sible, move containers from the fire area. If not leaking, keep fire-exposed containers cool with a water'fog or spray.to prevent rupture due to excessive heat. High pressure water may spread prod-uct from broken containers increasing contamination or fire hazard.
Dike'fire control water for later: disposal. Do not allow contami-nated water to enter waterways....- -
Fire &-Explosion Hazards This product-is not-defined'as flammable or combustible. It is self-extinguishing once the'source of ignition is removed. The material is not sensitive to static'discharge or physical impact.
It may decompose under fire conditions.
Other Fire + Explosion Hazards t p a ko.
No other .
fire:or
.N- -t.e.
explosion hazards of
- -hi....o..uct.a..-.n.w. .
Hazardous Products/Combustion Decomposition of this. product-under.fire conditions can produce carbon monoxide, 'phosphorus oxides,':'and organic decomposition products..:
NFPA HEALTH RATING': NFPA FLAMMABILITY RATING 2 .
NFPA REACTIVITY RATING NFPA OTHER 0 ND.
-SECTION 6. ACCIDENTAL RELEASE MEASURES-Cleanup .' . - - - .
Isolate'spill area and restrict nonessential 'ersornel. All personnel involved in spill cleanup should follow appropriate industrial hygiene practices (see Section 8). Stop source.of spill if-possible without.being injured. .-Dike area to-prevent spill. rom spreading.. Soak-up liquid with'a suitable absorbent such as clay,.
sawdust, orkitty litter. Sweep up absorbed material.and place,.
.-in a chemical waste container for disposal. CAUTION! Spill.'
- 'Pl; io h Akzo Nobel O em calS LLC MATERIAL.SAFETY-DATA SHEET- ,
DATE PRINTED: 5/27/2003- -PAGE ; 4
-F-Y.Q.U.E- EC . - -.. . : * :. . MSDS NO. 16-084461
- QL EHC . :.P.. } . . . ; - . . -.
SECTION 6. ACCIDENTAL RELEASE MEASURES (CONTINUED) area may be'slippery.' Cover spill area with'a slur of owdered household detergent and water., :Use stiff brush to work slurry into cracks and-crevices'. Allow to stand for 2 minutes, then flush
-with water. Dike wash water-for later disposal. Do not allow
.contaminated-water to enter waterways or sewers.-".
--' :.': SECTION': 7.' HANDLING-AND STORAGE Handl ing ...
Wearrotective clothingincludinq chemical'and/or face shield-and rubber- loves when handling this product to avoid eye and skin contact. Handle in a well-ventilated area. Avoid-inhalation of vapor or mist.. Wash thoroughly after-handling.
Containers should be.located in an area where they can be.rotated regularly (first-in, first out) and visually inspected'for.dents-and bulging on a weekly basis. If bulged drums are 'found, they should be venEed in an -open area-by removing the two-inch-bung very slowly.
The two-inch bung should not be removed completely until there is no
-sound of Pressure being released. The bung can then be removed,- but this should be done slowly and with care.
Emptied container-may retain product residues. Follow all warnings and precautions even after container.is emptied.
- -Storage <-..- - . - .........................
Store away from foodstuffs'and'animal-feed. '.Containers should be
. stored in a cool, dry, well.ventilated area away from flammable or oxidizing materials and sources-of heator flame.'. Exercise due caution to prevent.damage to or leakage from the container.,
Prolonged storage at-elevated temperatures under wet alkaline or acidic conditions-should -be avoided to assure product integrity.'
Care should be.taken to'prevent-moisture condensation in te con-tainer. Carbon steel is the preferred material of construction for storage containers.- The product.is normally-shipped in unlined tank cars,, trucks.and drums. r s in unlined MAXIMUM STORAGE TEMPERATURE -
149.00 F 65.00 C.-
Higher in absence air/moisture.
General Comments At temperatures below 4.4 C* (40 F), the'viscosity characteristics. -
.are such that improved pumping rates may be achieved by warming.-
Temperatures from 27-37.8.-C (0-100 F).provide good rates of fow.
This product can be stored"and transported in equipment constructed' of mild steel. - -
SECTION - 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Respiratory rotection .-.
Use a NIOStH-approved orqanic vapor/acid gas-respirator (OVAG) with - -
dust, mist an fume filters',to reduce potential for.inhalation exposureit use conditions'.generate vapor mist,- or aerosol and."
adequate ventilation (e.g.,- outdoor or well-ventilated area is -not-available. Where .exposure-potential-necessitates a higher level of- protection, usea.NIOSH-approved,. positive-pressure, pressure demand,- air-supplied respirator.' When using respirator, cartridges or canisters, they must be changed frequently (following each use or at the end of the workshift) to assure breakthrough exposure does not occur.,
Akzo Nobel Functional Chemicals LLC
.'MATERIAL SAFETY DATA SHEET:
DATE PRINTED: 5/27/2003 . . PAGE. 5
. QE EHC : - . . .. . -; :~ . -:. MSDS NO. 16-084461 FYRQUEL EHC . .- . : : ,- . :;-~ . - .--- - '-
'SECTION .8.' EXPOSURE CONTROLS/PERSONAL PROTECTION.. .
-- :. . - -.(CONTINUED) -.
Skin Protection - . - . - -
. . Skin contact with:the'liquid'or its aerosol must be prevented
through the use of suitable protective clothing, gloves, and footwear selected with regard for use-condition exposure potential..
Combination neoprene over natural latex gloves are recommended.
Eye Protection Eve contact with-the liquid.or its aerosol must be prevented through the use of chemical safety goggles and/or a face shield selected.
with regard for use condition.exposure potential.
Ventilation protection At elevated processing temperatures or.in the event that'use Conditions generate airborne vapor, aerosol, or-mist, the material should be handled in a well-ventilated area.- Where adequate
.ventilation.is not available, respiratory protection should be used.
Other Protection' .-
Safety showers, with quick opening.valves'which stay.o en, and eye wash lountains, or-other means of washing the eyes with a gentle flow of cool to tepid.tap.water, should be readily available in all areas where this material is handled or stored.. Water should be supplied.through insulated and heat-traced lines to prevent freeze-ps in cold weather.. Long sleeved clothing may be used to minimize skin contact.' '- --..- ' ; . .
All food and smoking materials'should be kept in a separate area away from the storaqe/use-location. Eating, drinkinq and smoking should be prohibitea.in areas where-there is a potential for signi-ficant exposure to this material... Before eating drinking or smoking, hands and.face should-befthoroughly wasfied-. .
APPLICABLE EXPOSURE LIMITS -
Other.than.any-exposure.limits which may be displayed in Section 8 .
there* are.no other known exposure-limits applicable.to this.producE..
Or its components.,
..EXPOSURE.LIMITSEGOINRITORY INFORMATION
- -.. N MG/M3)
SUBSTANCE DESCRIPTION REG. AGCY , PEL TLV TWA STEL ' CEIL Trixylezyl phosphate'-
- : ... .' '. - OSHA N/D. -N/D . N/D: N/D. N/D
.. /~ .. /f *OS/HAfl .. N/fl SUPPLIER~ N/D** N/l N/D N/f ND t-Butylphenyl diphenyl phosphate
-ACGIH
- N/ . N/D . N/fD N/D N/D NIOSH - , N/D N/fD N/D N/fD N/D SUPPLIER , N/l .. .N/fl N/f *N/D N/D Bis-t-butylphenyl) phenyl phosphate - .- *
.. ,-- OSHA .-- N/D - N/D N/D N/ N/D .
., .- .. . ACGIH , N/D N/D N/f N/D N/D
- .. .. - : ,. *., , Z :' NIOSH-
.......................... . - -. N/D - ..'N/D .s , , '.- N//
N .. , - . N/D
' ' SUPPLIER . 'N/fD . N/fD N/D N/D , N/D '
- Azo Nobel: Functional Chemicals'LLC MATERIALSAFETY DATA SHEET' DATE PRINTED: 5/27/2003' PAGE6
- FYRQUEL EHC ~~~~~~~~~~~~~~~~~MSDS NO. 16-084461 SECTION. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION (CONTINUED)
- ~ ~ - - - - - - - - - - - - - - - - - - - - - - - - - - - - -- - - - -
Tri~t-butylphenyl) phosphate, OSHA N/fl N/fl N/D N/fl N/D
- ~ACGIH
- N/fl N/Dl N/f N/D N/fl NIOSH N/fl N/fl N/fl N/D -N/fl SUPPLIER N/fD N/fl N/fl N/fl N/fl Triphenyl phosphate.
OSHA 3.0000' -Nf N/fl Nfl N/fl ACGIH N/fl -_3.0000' N/fl N/fl N/fl:
NIOSH N/fl , .N/fl 3.0000 N/fl N/fl SUPPLIER N/fl N/fl N/fl N/ N/fl LEGEND:
EXPOSURE LIMIT DESCRIPTIONS CEIL Ceiling Exposure Limit*.
PEL- Permissible Exposure Limit STEL- Short Term Exposure Limit-TLV Threshold Limit Value
- 7 J~~TA ' Time Weiahted Avrage..
.SECTION.' 9. PHYSICAL AND CHEMICAL PROPERTIES VAPOR PRESSURE (mm'Hg)':. -,VAPOR DENSITY (Air 'I .0)
EQ 0.17 mm Hg 06 20C. (68F)' N/D EVAPORATION RATE :-VOLATILE% .
N/Dl . N/D BOILING POINT.. ODOR THRESHOLD (ppm)
N/D F N/D-C N/fD SPECIFIC GRAVITY BULK DENSITY EQ ..145 . 15/15C'-160/60F) ... Not Applicable SOLUBILITY 'IN WATER-. SOLUBILITY IN OTHER'SOLVENTS LT 0.72 ug/mli Not Determined COEFFICIENT OF OIL/WATER POUR POINT N/D . 0.00 F -17.77.C MELTING POINT -pH FACTOR N/D-F -N/DC 'N/D CLOUD POINT *FLASH POINT.-
N/D F N/Dc 22.0 107.22 C GREATER THAN FLASH METHOD UPPER EXPLOSION LIMIT SETA CLOSED CUP, N/fl LOWER XLSO II AUTO IGNITION TEMPERATURE N/flD 1030.00 F 554.44 C Other viscosity@ .37'.S C ~.(100 F) = 220 SUS.
- .Akzo Nobel Functional Chemicals LLC MATERIAL SAFETY.DATA SHEET DATE PRINTED: 5/27/2003 - -. PAGE ' 7
'MSDS NO. 16-084461 FYRQUEL EHC : ' - . -
- ; .' .' SECTION 10. STABILITY AND REACTIVITY --.- .
Stability . . , .
This product is stable at ambient -temperatures and atmospheric ressure. It'is not self-reactive-and is not. sensitive to static Discharge or physical impact.. . . . - :- . '
-Incompatibilities
-This product is incompatible`with strong oxidizers, strong acids and' strong-alkalis.- It hydrolyzes slowly at'ambient temperatures in acidic or alkaline aqueous solutions.
Polymerization Hazardous polymerization is not expected-to occur. .
- Decomposition Under wet acidic or alkaline conditions'this product hydrolyzes slowly and nonviolently to form phenol, substituted phenols, and.
aryl phosphoric acids. '.
Va ors may deompose"'at elevated temperatures-to release harmful materials. .- - -
Conditions to Avoid - :
Prolonged-storage.'at- elevated temperatures (above 65.6 C; 150 F) should be avoided.'
- Avoid contact with strong acids, strong bases, and strong oxidizers.
SECTION:11. ,TOXICOLOGICAL INFORMATION
- ~~ ~~~~~~~~ .- ., ---
Toxicological - Inhalation '
The acute inhalation LC5O (rat) for a similar product following a 4-hour exposure was > 3.1-mg/Il, the'highest attainable concentra-tion. No mortalities were observed at this level. Inhalation of this product may cause nerve-damage, cholinesterase inhibition, and respiratory-tract irritation..'
Inhalation Chronic'Exposure..
Although.data are not available for this material, prolonged or repeated inhalation exposure may.cause nerve damage, chollnesterase inhibition, and respiratory.tract-irritation.
Toxicological -'Dermal -
Practically non-toxic;. the acute -dermal LD50 (rabbit) for -a.
similar-material is-greater than 2000 mg/kg., The acute dermal' -- .
LD50.(rabbit) for trixylenyl phosphate.and triphenyl phosphate is > 2000 mg/kg and.> 640 mg/kg,. respectively. . .-
Skin contact-may'cause nerve damage and'cholinesterase inhibition.
This product is'expected to be a mild skin'irritant based on
- component and.similar product data.
Skin Contact.- CHRONIC Although data are-not available for -this material prolonged -and/or repat~e .skin contact may cause nerve damage or cho inesterase inhibition. -
Toxicological - Eye.. ..
- This product is expected to be a.mild eye irritant based on.
component'and similar product data.-
Akzo Nobel Functional Chem ls LLC MATERIAL.SAFETY:DATA SHEET.
DATE PRINTED: 5/27/2003 . . PAGE 8
.YRQLEHC .. -- ...- - : . - : . MSDS NO. 16-084461 FYRQUEL EHC - . .- -: :.: .
SECTION -11. TOXICOLOGICAL INFORMATION (CONTINUED)
- - - ~~.
Toxicological Ingestion-Practically non-toxic; the acuteoral LD5O (rat) forasimilar .
material is'> 5000 mg/kg. The acute-oral.LDSO (rat) for trixylenyl phosphate and triphenyl phosphate is > 5000.mg/kg and,> 4640 mg/kg,.
respectively. Ingestion may cause nerve.damage and cholinesterase inhibition.
Ingestion- CHRONIC .
Although data are not available'for this'material, repeated.
ingestion may cause cholinesterase.inhibition and nerve damage.
Daily ingestion by'rats ofl100, 400,' or 1600 ppm of a similar urodct-in the diet:for.three months produced Increases in the, Yiver and adrenal gland weights in females and increases in the liver'weights of males at the highest dose level.. However, no histopathological changes were.noted.
CARC1NOGE2NICITY/MUTAGENIC1TY -: .-..
The carcinogenic/mutagenic properties of'this material have not
.been determined Neither this material nor its components have been'classified-as a carcinogen or suspect carcinogen by IARC NTP, OSHA, or ACGIH. A similar product was not mutagenic in the Ames test.- It did not induce an increase in chromosomal aberration or sister chromatid exchanges in mouse lymphoma cells and did not induce morphological-.transtormations in BALB/3T3'cells. Triphenyl phosphate, a product.component, was not mutagenic'-in the Ames test.
REPRODUCTIVE EFFECTS Daily administration of a similar product at 100 400 or 1000 mg/kg to rats on days 6 through 20 of gestation'demonstratea maternal toxicitv (increased liver weights-and reduced food consumption at the high-dose)and feto-toxicity (reduction in fetal body.
weight at the high-dose) but no indications of teratogenicity:'.
were observed. Triphen4 phosphate a product component, was not teratogenic in -rats at dietary levels oT up to 10 mg/kg administered through mating.and gestation.
NEUROTOXICITY Neurotoxicity data are not available for this-product. An oral dose of 1.14 g/kg of trixylenyl phosphate.did not produce significant inhibition of.brain neurotoxic esterase. Therefore, acute delayed neurotoxicity would not be expected at this dose level. Acute oral administration-of a hiqh dose of a similar material, 11.4.q/kg, to,.
hens produced 85% inhibition of plasma cholinesterase and 94-inhibition of brain neurotoxic.esterase. Hens observed for.three weeks following administration of this high dose showed motor incoordination starting on the tenth.day and increasing.in severity with time.-
Oral administration of 420 or 2000 mg/kg/day of triphenyl phosphate for 5days.to hens did not cause significant inhibi ion of neuro-toxic esterase-or clinical signs of neurotoxicity.. Hens dosed twice orally 3weeks apart wi h-11.7 g/kg of a similar product did' not show signs of delayed-neurotoxcity. In aseparate study, . -.
a similar product inhibited plasma cholinesterase but.not neuro-
.toxic esterase...-..
Other.Toxicological Effects No other-toxic effects for this product are known.
A .. - .
Akzo Nobel-Functional Chemicals LLC MATERIAL SAFETY DATA SHEET-DATE PRINTED: 5/27/2003 , .- -PAGE :. - 9 MSDS NO. 16-084461 FYRQUEL EHC . - : . -
-SECTION .'TOXICOLOGICAL INFORMATION:
- - - - -: . - :. . . -(CONTINUED). .
- -- - - - - 7 .: .- . . ,
Target Organs : . .- . .. - . .- . .
Overexposure to this material may affect the skin, eyes,:respiratory tract, and central and.peripheral nervous system.
SECTION* 12. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Data are not available for this product; however, the following data are available for a roduct.component and a similar roduct:
96-hr. LC50 (Rainbow trout) = > 100 mg/i trixylenyl phosphate '
-.(Practically non-toxic)-.- :- - - .- . . -
- 9-hr.LC50 (Sheepshead minnow) ='>'1.3 mg/i-similar product
(highest concentration tested)-
96-hr. LC50 (Mysid shrimp)-- > 1.0 mg/l similar product...
(highest concentration tested)
DISTRIBUTION Triaryl phosphate esters, including triphenyl phosphate, exhibit low aqueous solubility,,have moderate potential for bioconcentration, .-
and readily undergo.biodegradation.
CHEMICAL FATE
'Chemical fate'information on this product.'is not known.
TriphenyT phosphate, a product.component, is readily biodegradable.
Hydrolysis rates for triphenyl phosphate.are:
at pH 9.5: half-life: 0.23 days at pH 8.2: half-life: 7.5 days,-
-SECTION 13. DISPOSAL CONSIDERATIONS.
Waste Disposal ..-
- Materia? that cannot be usedor chemically reprocessed should be disposed of-in accordance with.all applicable requlations -
. Product containers designed for single use should be thoroughly.
emptied before disposal.
NOTE! State and local regulations may be more stringent than federal. -
.This product if unused, doesinot meet the EPA's RCRA.criteria as either a listed or a characteristic hazardous waste. Generators of wastes are remuired to evaluate their materials for compliance with RCRA and local disposal procedures and regulations.
CONTAINER DISPOSAL Emptied containers may.retain residues of this material. Follow all warnings-and precautions even after the container is emptied.'
- Containers:.should be drained of residual material before'disposal.
Emptied containers should be disposed of-in accordance-with all applicable.laws and-regulations. - -
SECTION .14. TRANSPORT INFORMATION
- .............................. - 7 - - - - - - - - -- -. - - - - - - -
SHIPPING DESCRIPTION FOLLOWING SHIPMENTS ARE.NOT REGULATED:FOR'TRANSPORT:
Surface transport within North America (U.S.A.,.Canada,'Mexico) in packages of 119 allons or less.(non-bulk). .
Air transport within North America (U.S.A., Canada, Mexico).
FOLLOWING SHIPMENTS ARE REGULATED.FOR TRANSPORT (SHIPPING DESCRIPTION FOLLOWS): '
Bulk surface shipments.within'North America.(> 119 gallons). -
Akzo Nobel Functional Chemicals LLC
'MATERIAL SAFETY DATA'SHEET DATE PRINTED: 5/27/2003 PAGE 10
-* : .-.-::-... :-:. MSDS NO. 16-084461 FYRQUEL EHC . .. . .. -. . -. -
SECTION 1'4. TRANSPORT INFORMATION
- (COU INUED)
Water transport :withih North America (U.S.A. Canada, Mexi6o).
Export shipments (excluding non-bulk shipments to Canada and Mexico anu shipments via air transport to Canada and Mexico)..
ENVIRONMENTALLY HAZARDOUS SUBSTANCE,. LIQUID, N.O.S.'
(Triphenyl hosphatetert-butylated triphenyl phosphates mixtures containing 10% to 48 triphenyl phosphates).
9 UN3082 PG III N6RTH AMEkICAN EMERGENCY.RESPONSE GUIDE NO. 171 REQUIRED LABELS .
PRIMARY LABEL: Class 9
-SUBSIDIARY.RISK LABEL:' Marine pollutant .
ENVIRON. HAZARDOUS SUBSTANCE This product contains triphenyl phosphate and trixylenyl phosphate which are Marine Pollutants as per 49 CFR, 172.1, Appenlix B..
- SECTION 15. REGULATORY INFORMATION
--- Toxic St. .Cont. Act - - . .- - .
. .- 7 - -------
Component Trixylenyl phosphate phis.asubject ttthe following Enviromental List -
DSL - Domestic Substance List-Canada TSCA Toxic Subst. Cont. Act -listed . .
Component-tt-Butylphen ydiphenyl phosphate is subject t the following Enviromental List DSL Domestic Substance List-Canada'..
TSCA, Toxic Subst. Cont. Act -listed Component.Bis(t-butylphenyl) phenyl phosphate is'subject the to f ollo wing Enviromental List DSL Domestic Substance List-Canada' TSCA Toxic Subst. Cont.' Act -listed - - - -
' -- - -- -- .. , : '- -- '---- - --- - - -- -- --- 7 -- --- - -
ComponentTri(t-butylphenyl) phosphate is subject to the.-following Enviromental List --- : -
DSL Domestic Substance'List-Canada -
- ~ ~
~~~~~~~~_AkzoNobe1'Functiona1 Chemicals'LLC MATERIAL,:SAFETY DATA SHEET
-DATE PRINTED: 5/27/2003 PAGE, 11 FYRQUEL
- ~~~~~~~
EHC K .. . . ~MSDS NO. 16-084461
.. . ~SECTION- 15. REGULATORY.'INFORMATION (CONTINUED)
- TSCA -Toxic Subst. ont. -Act -listed Component Triphenyl phosphate'is' subject to the following Enviromnental List DSL, Domestic Substance List-Canada-.,..
MA. LIST Massachusetts Substance List-'
NJ R-T-Kc New Jersey R-T-K Hazard. Sub.
'PA. LIST. 7Penn. ~Hazardous Substance List TSCA Toxic Subst. Cont. Act -listed OTHER REGULATORY INFORMATION No other regulatory information is avalbeo ti roduict.
WHMIS HAZARD CLASS, . .. HAZARD RATING SOURCE D-2A;' D-2B .HI HEALTH- REACTIVITY.
2 -. 0
- LA4ABILITY OTHER SECTION.-16. OTHER INFORMATION.
OTHER INFORMATION FYRQUTEL is a' registered trademark of. Akzo Nobel Chemicals Inc.
Revisions made in' S ect ion(s) 2, !,3', 5, 9.
CREATED BY Product Safety 914/674-5000 KEY TO ABBREVIATIONS:
EQ=EQual LT=Less Than- GT=Greater-Than A.P=APproximately , TR=TRace . ND=No Data available The information inthis material safety data sheet should be provided to all who will use. handle, store, transport or otherwise be exposed to this and/or suggestions for handling and use contained herein are offered ingood faith and are believed to be reliable as at-the date of publication. H accuracy of and/or sufficiency of such information and/or suggestions as to the merchantability or fitness of the product for any particular purpose infringe any patent. Nothing in here shall be construed as granting or extending any license under any patent. Buyer oust determine for himself. b suitability of this product-for his purposes.. including mixing with other products. The information contained herein supersedes all previously issu covered. Ifthe date of this document Ismore than three years old,. callI to make certain that this sheet iscurrent.,