DCL-10-083, Emergency Operations Facility (DCPP EOF) Facility Emissions and Throughput Data for Inventory Year 2008 (Annual Air Emissions Report) and Associated Facility Reporting Requirements
| ML11166A271 | |
| Person / Time | |
|---|---|
| Site: | Diablo Canyon  |
| Issue date: | 02/25/2009 |
| From: | Welch J Pacific Gas & Electric Co |
| To: | Carlson D Office of Nuclear Reactor Regulation, San Luis Obispo County, Air Pollution Control District |
| References | |
| DCL-10-083, DCL-09-511 | |
| Download: ML11166A271 (24) | |
Text
PG&E Letter DCL-2009-511 Certified Return Receipt 1 7007-2680-0000-5565-3981 February 25, 2009 Air Pollution Control District (APCII))
County of Sall Luis Obispo 3433 Roberto Court San Luis Obispo, CA 93401-7126 Attention: Dean Carlson Diablo Canyon Power Plant (DCPP) and Diablo Canyon Power Plant Emergency Operations Facility fDCPP EOF ) Fcility Emissions and Throughput Dama for Inventory Year 2008 (Annual Air Emissions Report) and Associated Facility Reporting Requirements In response to APCD letters dated January 28, 2009 requesting emissions data for 1)CPP and the DCPP EOF, DCPP is submitling the Facility Emissions and Throughput Data Report for Inventory Year 2008 (Enclosure 1 ). Requested emissions data for both facilities have been incorporated into a single report using APCI) Forms 1, 2, 3, 4 and 32, or equivalent facility generated forms. Additionally, monthly operating logs for stationary emergency diesel engines, facility gasoline dispensing data, and diesel fuel use information for portable emissions units operated in accordance with APCD Permit-to-Operate (PTO) 1065-5 are provided.
If you have any questions or concerns regarding the enclosed report, or require additional information, please contact Tom Esser of my staff at (805) 545-3326.
Sincerely, James Welseh DirLector - Opeirations Services 200951 1/twe/bkc Enclosure
PG&E Letter DCL 2009-511 Air Pollution Control District (APCD)
February 25, 2009 Page* 2 bcc w/enclosure:
BlKCunninghamn TWEsser BCi-iinds (104/5/534)
(104/5/3B)
(104/5/517)
(104/5/1 A-B)
Environmental Central Library *
" Note: Route one hardcopy with (listribution as follows:
BCHinds, B3KCunningham, Environmental Central Library (Final)
S:\\enveng\\correspondence\\outgoing\\2009 doc\\2009 complete\\DCL2009511 Supporting electronic data filed @:
S:\\ENVENG\\CATEGORIES by Media\\Air\\AAER\\2008 AAER\\
Enclosure-I APCD Forms (1-2-4-32) & Supporting Information 2008.doc Portable Unit Emissions Information PTO 1065-5 2008.doc BP Diesel Heat of Combustion Calculator 2009.xls Industrial Paint & Solvent VOC Emissions APCD Form-3 2008.doc Waste Disposal DCPP (Solvent and Paint) 2008.xis
PG&E Letter DCL-2009-511 Air Pollution Control District (APCD)
February 25, 2009 ENCLOSURE I 2008 AIR EMISSION INVENTORY REPORT FOR DIABLO CANYON POWER PLANT Data Certification, APCD Form-l, DCPP Data Certification, APCD Form-I, DCPP EOF Emissions Inventory nllormation - Fuel Combustion (Stationary Devices), APCD Form-2 Emissions Inventory In formation - Stand-By/Backup Generators, APCD Form-32 (2-Pages)
Supporting Data for Facility Diesel Fuel Oil Sulfur Content and Heat Value (11 -Pages)
Including - Calendar Year Operating Logs/br *Saionar, Emergencj, Diesel Engines Emissions Inventory Information - Permitted Diesel-Fired Portable Units Emissions Inventory [nformation - Gasoline Dispensing Facilities Emissions Inventory Information - Other Solvents and Organic Compoun, d Sources, APCD Form-4 Emissions I[ventory Information - Industrial Paint and Solvent Use, APCD Form-3 (2-Pages)
Including - l'acility Disposal Records/bfr o'aint and Solventi Related Iastes
AIR POLLUTION CONTROL DISTRICT COUNTY OF SAN LUIS OBISPO DATA CERTIFICATION FORM For Inventory Year - 2008 Please till in all space and retain ai copy for your records. Completed forms may be faxed. Print your name and sign this form in the spaces provided. Submit completed forms by due (late to avoid fines or penalties.
A. Please print clearly.
Company Name Pacific Gas & Electric Company, Diablo Canyon Power Plant (DCPP)
Contact Name Bryan K. Cunmingham i Title Supervisor, Environmental Operations Mailing Address p.o. Box 56 104/5/534 City, State ZIP Avila Beach, CA 93424 Contact Phone (805) 545-14439 Fax I (805) 545-3459 Equipment Address 9 Miles Northwest of Avila Beach City, State ZIP Avila Beach, CA 93424 Facility ID (see cover letter) 74 Tfype of Business Electric Power Generation B.
Is trade secret dlata included!
Yes [ ]
No [X]
If M, attach explanation.
C. Are there any NEW sources of criteria pollutants: oxides of nitrogen, oxides of Yes [XJ No [ ]
sulfur, particulate matter, volatile organic compounds (VOCs)?
If yes, describe in box below.
D.
Are there any emission sources no longer in service?
Yes I ]
No [X]
If M, write pennit number in box below.
Remarks:
Added one new portable emission unit.
0 Portable Diesel-Fuelcd Electric Generator, MQ Power Model DCA-45LS12, Permit 1065-5.
Under California Ilealth and Safety Code sections 40701 and 42303, the District has the right to request data needed to estimate pollutant emissionis. Consequently, you are obligated to provide all requested data by the (tle (late. This data is also requested mmnoder the atuthority of the Air Toxics Hot Spots program. Fihe (data may be used to determine permit reniewal fees. Failure to provide complete data by the (tlme (late may result in fnhes or penalties.
I, James Welsch (Clearly Print Name), certify that the data provided above and in all tile attachments is complete and accurate to the best of my knowledge.
Signature:
Date:
ClngO()I Rev iscd 0i111I6/07 Electroniic Copies ofe cinision inventory forms are located ont our WEBI site.
AIR POLLUTION CONTROL DISTRICT COUNTY OF SAN LUIS OBISPO DATA CERTIFICATION FORM For Inventory Year - 2008 Please fill in all space and retain a copy for your records. Completed forms may be faxed. Print your name and sign this form in the spaces provided. Submit completed forms by clue (late to avoid fines or penalties.
- 13. Please print clearly.
Pacific Gas & Electric Company, Diablo Canyon Power Plant Emergency Operations Facility Company Name (DCIIP EOF)
Contact Name Thomas W. Esser Title En vironmental Coordinator Mailing Address P.O. Box 56 104/5/31B City, State ZIP Avila Beach, CA 93424 Contact Phone (805) 545-3326 Fax (805) 545-3459 Equipment Address 1525 Kansas Avenue City, State ZIP San Lnis Obispo, CA 93405 Facility ID (see cover letter) 232 1 Type of Business Electric Power Generation B.
Is trade secret data included?
E.
Are there any NEW sources of criteria pollutants: oxides of nitrogen, oxides of sulfur, particulate matter, volatile organic compounds (VOCs)?
F.
Are there any emission sources no longer in service?
Yes[]
No[X]
If yes, attach explanation.
Yes[]
No[X]
If yes, describe in box below.
Yes[]
No[X]
If yes, write permit number in box below.
Under California Health and Safety Code sections 40701 and 42303, the District has the right to request data needed to estimate pollutant emissions. Consequently, you are obligated to provide all requested data by the due date. This data is also requested under the authority of the Air Toxics Ilot Spots program. The data may be used to determine permit renewal fees. Failure to provide complete data by the (ilme (late may result ill fines or penalties.
I, James WeIsch (Clearly Print Name), certify that the data provided above and in all the attachments is complete and accurate to the best of my knowledge.
Signature:
t-lectionic copies of emission inventory fornls are tocated on oar WEB site.
Date:
enig0 I Revised 0(1 / 1 6/07
,AIR POLLUTION CONTROL DISTRICT COUNTY OF SAN LUIS OBISPO EMISSIONS INVENTORY INFORMATION For Inventory Year - 2008 FUEL COMBUSTION Company Name Pacific Gas & Electric Company, Diablo Canyon Power Plant (DCPP)
Contact Initials TWE Use this form to report all stationary combustion devices. Do not report stand-by or backup generators on this forn. List each item separately, unless identical. Do not include mobile equipment such as loaders or trucks. Please fill in all spaces and include supporting data where requested. Retain a copy for your records.
Unit of Heat Content Sulfur Unit of Rait 1
(,)
Annual Measure Yearly Hour (tlntvlm*)
otn~)Maue6 Device No.
Device Description Equipment Rating Fuel Type Fuel Used Y
i Use (7) t 4 )
(nn e
6 )
DA-18 Auxiliarv Boiler 0-2 8 1.816 mm BTU/hour CARB No.'2 0
Gallons 0
136,S56 BTU/gallon 0.015 Weight %
ULS Diesel Fuel (1)
(2)
(3)
(4)
(5)
(6)
(7)
Forboilers, heaters, k-ilns, flares, and related equipment give the design heat input (rmm BTU/hr). For internal combustion engines, specil*y horsepower (lip).
Examples: natural gas. fiuel gas, landfill gas, diesel fuel, fuel oil. If fuel oil is burned, specif'y grade (example: fuel oil No. 2).
Ifa device bums more than one fuel. use a separate line lbr each fuel.
Include units of teasure (thenns. mtcl' mmcf, gal. regal. bbl, or rbbl). Be sure that your units of measure are correct!
This form is incomplete without an accompanying, recent analysis of the sulfur content. Omit for natural (utility) gas-fired sources.
Express sulfur content in gridscf or lb./nuncf for gasses and weight %/vol for liquids.
The total numnnbcr ofl hours the unit has been run for the current year.
Eng002-doc Revised 8/3/06
SAIR POLLUTION CONTROL DISTRICT COUNTY OF SAN LUIS OBISPO EMISSIONS INVENTORY INFORMATION For Inventory Year - 2008 STAND-BY/BACKUP GENERATORS Company Name Pacific Gas & Electric Company, Diablo Canyon Power Plant (DCPP)
Contact Initials TWE Use this form to report all Stand-By and Backup Generators. List each device separately. Please fill in all spaces and include supporting data where requested. Retain a copy, for your records.
Please also include a copy of the operating log for calendar year 2008 as required by your Permit to Operate.
12,3 J Unit of Yearly Maintenance Meter Device No.
Device Description Equipment Ratingt Fuel rype' Annual Fuel Use Nleasure(4)
Hour Usecs' Hlourst 6' Reading t No..__
_6,0_
Galon 39_
39_
43.
DA-I Emergencv Diesel Generator I - 1 3.630 horsepowcr CARB No, 2 G
n9.1 ULS Diesel Fuel DA-2 Emergency Diesel Generator 1-2 3,630 horsepower CARB No. 2 8,969 Gallons 57.6 57.6 2622.0 I
ULS Diesel Fuel DA-S3 Emergency Diesel Generator I-3 1
3,630 horsepower CARB No. 2 4,952 Gallons 31.8 31.8 2487.8
__________________ULS Diesel Fuel DA-4 Emergency Diesel Generator 2-1 3,630 horsepower CARB No. 2 10,666 Gallons 685 68.5 1601.2 ULS Diesel Fuel 1G DA-5 Erncrgcncy Diesel Generator 2-2 3,630 horsepower GARB No.2 12,784 Gallons 82.1 82.1 2018.4 ULS Diesel Fuel D.A-25 Emergency Diesel Generator 2-3 3,63f0 horsepower CARB No.2 12,519 Gallons S0.4 80.4 1393.6 ULS Diesel Fuel DA-6 Security Diesel Generator 449 horsepower CUALR B
Fuel 687.3 Gallons 61 61 893 UILS Diesel Fuel 68.Gaon61183 (1)
(2)
(3)
(4)
(5)
(6)
(7)
For internal combustion engines, specify horsepower (lip) or design heat input (mm BTUihr).
Examples: natural gas, propane gas, diesel fuel, fuel oil. If fuel oil is burned, specifv grade (example: fuel oil No. 2).
Ifa device burns more than one fuel, use a separate line for each fuel.
Include units of measure (therms, mef, mtmcf. gal, regal, bbl, or rabbl). Be sure that your units of measure are correct!!
The total number of hours the unit has been run for the cunrent calendar year.
The number of hours the device has been used for maintenance.
The end of year hour mneter reading frorn the device.
Eng032.doc Revised 1/25/08
S AIR POLLUTION CONTROL DISTRICT COUNTY OF SAN LUIS OBISPO EMISSIONS INVENTORY INFORMATION For Inventory Year - 2008 STAND-BY/BACKUP GENERATORS Company Name Pacific Gas & Electric Company, Diablo Canyon Power Plant Emergency Operations Contact Initials TWE Facility (DCPP EOF)
Use this form to report all Stand-By and Backup Generators. List each device separately. Please fill in all spaces and include supporting data where requested. Retain a copy for your records.
Please also include a copy of the operating log for calendar year 2008 as required by your Permit to Operate.
Unit of Yearly Maintenance Meter eice evice esriptionFuelType Annual Fuel Use Measurei41 Hlour Use(5' Hours 1 Readingot Emergency Operations Facility (EOF)
CARB No. 2 Ernergency Diesel Generator 62 horsepower ULS Diesel Fuel F
I (I)
(2)
(3)
(4)
(5)
(6)
(7)
For internal combustion engines. specify horsepower (hp) or design heat input (ram BTUihr).
Examples: natural gas, propane gas, diesel fuel, fuel oil. If fuel oil is burned, specify grade (example: fuel oil No. 2).
If a device burns more than one fuel. use a separate line for each fuel.
Include units of'measurc (thcrms, mcf, mimcf, gal, regal, bbl, or mbbl). Be sure that your units of measure are correct!!!
The total number of hours the unit has been run for the current calendar year.
The number ofhours the device has been used for maintenance.
The end of v'ear hour meter reading from the device.
Eng032.doc Revised 1/25/08
AIR POLLUTION CONTROL DISTRICT - SAN LUIS OBISPO COUNTY EMISSION INVENTORY INFORMATION Supporting Data Diesel Fuel Oil Sulfur Content and BTU Values 2008 Monthly Operating Logs for Permitted Stationary Emergency Diesel Generators DCPP Emergency Diesel Generators (DCPP EDGs) and the DCPP Emergency Operations Facility Emergency Diesel Generator (DCPP EOF EDG) arc fueled with CARB Ultra Low Sulfur (ULS) diesel fuel oil in accordance with conditions of APCD Permit-To-Operate (PTO) 919-2 and 886-2 to meet the requirements of Title 17 California Code of Regulations (CCR) Section 93115.5. Representative analyses of the fuel burned in the DCPP EDGs during 2008 are attached.
These analyses indicate the sulfur content of fuiel added to the EDG fuel tanks was less than 0.001%. No fuel was added to the DCPP EOF EDG fuel tank during 2008.
Attached
References:
Copy 02/28/2008 Receipt fiOron The Jankovich Company for ULS Red-Dyed CARB Diesel Fuel.
Test Summary Report for DCPP #2 DFO Composite Sample 4/1/2008.
Test Summary Report for DCPP #2 DFO Composite Sample 11/20/2008.
- If operated, the DCPP Auxiliary Boiler would burn CARB ULS diesel fuiel. The estimated heat content (BTU) value for the fuel provided on APCD Formn-2 was calculated using a Heat of Combustion Calculator (spreadsheet) provided by BP Fuels Global Technology Quality and Technical Service Department.
Attached
Reference:
Heat of Combustion Calculator provided by BP Fuels Global Technology Quality and Technical Service Department.
The DCPP Security Diesel Generator and Facility Diesel-Fired Portable Units burn CARB Ultra Low Sulfur (ULS) clear highway #2 diesel fuel oil supplied by the JB Dewar Company and the Silvas Oil Company. Both vendors supplied receipts indicating that ULS diesel fuel was delivered to DCPP.
Attached
References:
Copy 4/2/2008 Receipt from J.B. Dewar Company (ULS Diesel #2).
Copy 7/8/2008 Receipt fiom Silvas Oil Company (Gasoline and ULS Diesel #2).
2008 Operating Logs for Permitted Stationary Emergency Diesel Generators:
2008 Monthly Operating Log for DCPP Emergency Diesel Generators, PTO 919-2 2008 Monthly Operating Log for DCPP Security Emergency Diesel Generator, PTO 919-2 2008 Monthly Operating Log for DCPP EOF Emergency Diesel Generator, PTO 886-2
,AIR POLLUTION CONTROL DISTRICT COUNTY OF SAN LUIS OBISPO EMISSIONS INVENTORY INFORMATION For Inventory Year - 2008 OTHER SOLVENTS AND ORGANIC COMPOUND SOURCES Company Name Pacific Gas & Electric Company, Diablo Canyon Power Plant (DCPP)
Contact Initials TWE Report emissions from other sources of volatile organic compounds. Be sure to use the correct units use this form for surface coating operations. Please fill in all spaces and retain a copy for your records.
of measure. Do not D evice I DM ateri l d
D escription of P rocess in W hich A ouse Pt to
(
y ea
)
A n nual V O C s Amount Amount to Waste VOCtn Emittedt5 1 D i eID M aterial Em itted("D s rpi no P o esi h c Used Per YearGz)
(per year) (2,3)
Content (4) m ttd' (optional)
Material is Released (lb/yr)
__A B
C D
E xanple 1 Rocnt,,o, used in plating line to rcmoýe oil from raN stock 550 gal
[ 250,z 7.0 li,'g.t 2,gtl, ibiye None (n/a)
Total VOCs emitted None (n/a) lb/yr (I)
(2)
(3)
(4)
(5)
List acetone-based solvents and products separately.
Include appropriate units - tons, gallons, barrels, pounds.
Includes only off'site disposal or recycling. Include a summary of the materials sent off site including date, vendor, and amount shipped.
Units must be consistent with (2) and (3)
Annual VOCs Emitted = (A minus B) quantity times C; example: 650 gal - 250 gal = 400 gal. 400 gal x 7.0 lbigal = 2.800 lb En,004.doc Revised I-"2i02
AIR POLLUTION CONTROL DISTRICT COUNTY OF SAN LUIS OBISPO EMVISSIONS INVENTORY INFORMATION Inventory Year - 2008 GASOLINE DISPENSING FACILITIES Company Name Pacific Gas & Electric Company, Diablo Canyon Power Plant (DCPP)
Contact Initials TWE Please fill in all spaces and retain a copy For your records. The data listed below will be used to estimate the community cancer risk under the Air Toxics Hot Spots (ATHS) program.
A. Enter the total number of gallons of gasoline or methanol/gasoline mix sold or dispensed during the emission year. Do NOT include diesel. If not known, enter the number of gallons of gasoline loaded into your tanks.
33,020 gallons B.
Enter the operating hours per clay and the number of days per year that your facility is open for gasoline sales.
operating hours per day 24 days per year 365 C.
Type of Phase LI vapor control system: vacuum assist []
balance [X]
other [ ]
Manufacturer of Phase II vapor control system: Trusco Tank, Inc. (Supervault)
D.
Accurately determine the following distances. This form is incomplete without this information. If any of the distances reqluested below are known to be greater than 600 feet, list I> 600."
Distance from the nearest nozzle to:
the closest home, apartment, mobile home, or long-term care facility:
>600 feet the closest off-site work site (businesses, motels, schools, offices, and restaurants, and any co-located work site, such as a restaurant or mini-mart, where employees are not direct service station employees):
>600 feet
EMISSIONS INVENTORY INFORMATION For Inventory Year 2008 INDUSTRIAL PAINT AND SOLVENT USE Compmany Namne: Pacific Gas & Electric Company Diablo Canyon Power Plant Contact Initials: TWE List paints and all solvents used foi cleanul) and thinning for commercial, industrial, and institutional coating operations and applications. Please list acetone separately. Find the VOC content of the materials from the MSDS or your paint supplier. Calculate emissions. Please fill in each column and retain a copy for your Records. Be sure to use the correct units of measure.
Type of Coating or Thinner Amount Amount VOC VOCs Emitted Chromates Used Recycled Content (Ib/yr)
(yes/no)
(gal/yr)
(gal/yr)
(lb/gal ADUREL PROCOATINGS U3300 2.50 0.25 2.0 4.50 No URETHANE ROOF COATING AMERLOCK 400 PAINT KIT, GRAY 21.80 1.25 1.5 30.83 No LT 2-PART FAST CURE AMERON PSX 700 700C0000 88.88 7.71 1.0 81.17 No AMERON PSX 700 RESIN 3.25 0.50 1.0 2.75 No AMERON PSX-700 BROWN 0.25 0.00 1.0 0.25 No AMERON PSX-700 RED 7.19 0.56 1.0 6.63 No CARBOLINE CARBOGUARD 890N 114.75 7.50 1.7 182.33 No CARBOLINE #2 SOLVENT 18.92 11.00 7.1 56.24 No DEVGARD 238 (THINNED) 29.00 3.50 2.07 52.79 No DEVGUARD 238 ABRASION 6.31 0.38 1.7 10.09 No RESISTANT EPOXY COAT BLACK DEVGUARD 238 ABRASION 0.50 0.00 1.7 0.85 No RESISTANT EPOXY COATING GRAY DEVGUARD 238 ABRASION 17.31 2.13 1.7 25.81 No RESISTANT EPOXY COATING HAZE KEELER & LONG 4500 EPOXY 1.00 0.00 0.6 0.60 No SELF-PRIMING SURFACE ENAMEL HAZE KEELER & LONG 4500 EPOXY 0.25 0.00 0.6 0.15 No SELF-PRIMING SURFACE ENAMEL PEARL GRAY KEELER & LONG 4500 EPOXY 0.10 0.00 2.06 0.21 No SELF-PRIMING SURFACE ENAMEL PROFUNDO BLUE (THINNED)
NATIONWIDE ULTRASATIN 2730 77.50 10.00 0.74 49.95 No SHERWIN WILLIAMS PREP RITE 3.00 0.00 0.35 1.05 No PRIMER SIERRA METAL MAX S39 BEYOND 0.06 0.00 0
0.00 No THINNER BUTYL ACETATE 11.48 2.13 7.34 68.63 No Total VOCs Emitted 574.83 (Ib/year)
Do you use a booth in your coating operation?
Yes[X]
No[ ]
If yes, p)lease provide the filter efficiency of your filters.
- 98. 1% (for Binks 29-2186 filter)
I.
Attach a summary of disposal records verifying vendor and dates/volumes disposed.
- 2.
(Amount Used - Amount to Waste) X VOC Content = VOC emitted
- 3.
Indicate whether each prodluct contains chromates (compounds containing Cr"'). See MSDS.
Include copy of MSDS for all products containing chromates.
FIN(3003 I ndw;t I lalntSo I vei it. doc 1ýcvisc-d l!"2/01)
Pacific Gas & Electric Company, Diablo Canyon Power Plant (DCPP)
Emissions Inventory Information for Permitted Diesel-Fired Portable Units The following table lists the operating hours and fuel consumption during 2008 for permitted diesel-fired portable emissions units located at DCPP. The units are operated under SLO APCD Permit-To-Operate (PTO) 1065-5.
Unit Identification 2008 2008 Hours of Operation Diesel Fuel Added (in gallons)
Ingersol Rand XP375 Compressor 23.2 35.3 Butterworth Model 610DT Pressure Washer 0.6 0
MQ Power Model DCA-1 50SSVU Generator 2.8 88.9 Ingersol Rand Compressor-Yanmar 41R18T 147.7 123.3 MQ Power Model DCA-45US12 Generator 0
0
ziuvas uil uompany, inc.
LUHIK'UA I I=UFUI:-(
A"'W needn erlu itiuo 2121 So. Third St.
- H*
1*
!Indeendnt Ptroeum istibutr.O.
Box 1048 - Fresno. CA 93714
.5
- 59) 2,33.5171 - www.silvasoil.com
-v PLEASE RETURN REMITTANCE TO E~oN Mobil r
~ConocoPhiillips 7~)ADES BV ACCOUNT NUMBER:
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~~DATE:
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MATERIAL SAFETY DATA SHEET bp ECD ULTRA LOW SULFUR DIESEL MSDS No. 0000000795 USA/ENGLISH 1.0 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: ECD ULTRA LOW SULFUR DIESEL MANUFACTURER/SUPPLIER:
EMERGENCY HEALTH INFORMATION:
1 (800) 447-8735 BP Products North America 200 East Randolph Drive EMERGENCY SPILL INFORMATION:
Chicago, Illinois 60601 U.S.A.
1 (800) 424-9300 CHEMTREC (USA)
OTHER PRODUCT SAFETY INFORMATION:
1 (866) 4 BP-MSDS (866-427-6737 Toll fiee -- North America) e-mail: bpcares@bp.com 2.0 COMPOSITION/INFORMATION ON INGREDIENTS
-Component
[CAS#
Range % by Wt.
Petroleairn distillate F- -
95-99 IXye'e.1330-20-71 0.10-1.5 ITrimethylbenzene 195-63-6 0.5-2.0 oFlaie II11-84-2 1 0-1.1 (See Section 8.0, "Exposure Controls/Personal Protection", for exposure guidelines)
3.0 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: Warning! Combustible. Harmful or fatal if liquid is aspirated into hlngs. Causes skin irritation on prolonged or repeated contact.
POTENTIAL HEALTH EFFECTS:
EYE CONTACT: No significant health hazards identified.
SKIN CONTACT: Causes skin irritation on prolonged or repeated contact. See "Toxicological Information" section (Section 11.0).
INHALATION: No significant health hazards identified for the liquid fuel. See "Toxicological Information" section (Section 11.0).
INGESTION: Harmful or fatal if liquid is aspirated into lungs. Ingestion causes gastrointestinal irritation and diarrhea. See "Toxicological Information" section (Section 11.0).
HMIS CODE: (Health:0) (Flammability:2) (Reactivity:0)
NFPA CODE: (Health:0) (Flammability:2) (Instability:0) 4.0 FIRST AID MEASURES EYE: Flush eyes with plenty of water.
SKIN: Wash exposed skin with soap and water. Remove contaminated clothing, including shoes, and thoroughly clean and dry before reuse.
INHALATION: If adverse effects occur, remove to uncontaminated area. Get medical attention.
INGESTION: If swallowed, do NOT induce vomiting. Get immediate medical attention.
5.0 FIRE FIGHTING MEASURES FLASI-HP1OINT: 125'F (Tag closed cup)
UEL: 7.5%
LEl.,: 0.6%
A\\ UTOIGNIT[ION "I'EM PERATURE: Not determined.
FLAMMABILITY CLASSIFICATION: Conmbustible Liquid.
EXTINGUISHING MEDIA: Agents approved for Class [3 hazards (e.g., dry chemical, carbon dioxide, foam, steam) or water fog. Water may be ineffective but should be used to cool-fire exposed containers, structures and to protect personnel.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Combustible liquid.
FIRE-FIGHTING EQUIPMENT: Firefighters should wear full bunker gear, including a positive pressure self[-contained breathing apparatus.
PRECAUTIONS: Keep away from sources of ignition (e.g., heat and open flames). Use with adequate ventilation.
HAZARDOUS COMBUSTION PRODUCTS: Combustion of this product in an area without adequate ventilation may result in hazardous levels oftcombustion products (e.g.,
carbon monoxide, carbon dioxide) and inadequate oxygen levels.
6.0 ACCIDENTAL RELEASE MEASURES Remove or shut off all sources of ignition. Prevent spreading by diking, ditching, or absorbing on inert materials. Keep out of sewers and waterways.
7.0 HANDLING AND STORAGE HANDLING: Use with adequate ventilation. Keep away from ignition sources (e.g.,
heat, sparks, or open flames). Ground and bond containers when transferring materials.
Wash thoroughly after handling.
STORAGE: Store in combustible liquids storage area. Store away from heat, ignition sources, and open flame in accordance with applicable regulations.
8.0 EXPOSURE CONTROLS / PERSONAL PROTECTION EYE: None required; however, use of eye protection is good industrial practice.
SKIN: Avoid prolonged or repeated skin contact. Wear protective clothing and gloves if prolonged or repeated contact is likely.
IN14ALATION: Use with adequate ventilation. If ventilation is inadequate, use NiOSH certified respirator that will protect against organic vapor and dust/m1ist.
ENGINEERING CONTROLS: Control airborne concentrations below the exposure guidelines.
EXPOSURE GUIDELINES:
component CAS#
FExposure Limits Petroleum distillate F
No exposure limit established Xylene 1330-20-7 OSHA PEL: 100 ppm (1989)(1971)
OSHA STEL: 150 ppm (1989); Not established. (1971)
ACGIH TLV-TWA: 100 ppm ACGIH TLV-STEL: 150 ppm Timethylbenzene 95-63-6 APEL:25 ppm (1989); Not established, (1971)
A CGIH TLV-TWA: 25 ppm
~NoOSHA 11184-A0 ppm (1989); Not. established. (1971) 9.0 CHEMICAL AND PHYSICAL PROPERTIES APPEARANCE AND ODOR: Liquid. Clear. Petroleum odor.
p)H: Not determined.
VAPOR PRESSURE: Not determined.
VAPOR DENSITY: Not determined.
BOILING POINT: 340-675°F (approximate range)
MELTING POINT: Not determined.
SOLUBILITY IN WATER: Negligible, below 0.1%.
SPECIFIC GRAVITY (WATER=I): <1.0 VISCOSITY: 1.8-3.6cSt at 100°F 10.0 STABILITY AND REACTIVITY STABILITY: Stable.
CONDITIONS TO AVOID: Keep away from ignition sources (e.g. heat, sparks, and opell flames).
MIATERIALS TO AVOID: Avoid chlorine, fluorine, and other strong oxidizers.
HAZARDOUS DECOMPOSITION: None identified.
HAZARDOUS POI,YMnXERIZATION: Will not occur.
11.0 TOXICOLOGICAL INFORMIATION ACUTE TOXICITY DATA:
EYE IRRITATiON: Testing not conducted, See Other Toxicity Data.
SKIN IRRITATION: Testing not conducted. See Other Toxicity Data.
DERMAIA, 1..)50: Testing not conducted. See Other Toxicity Data.
ORAL., 1,)50: Testing not conducted. See Other Toxicity Data.
INHALATION LC50: Testing not conducted. See Other Toxicity Data.
OTHER TOXICITY DATA: Similar products have produced maximum eye irritation scores ranging from 0.33 to 1.0/110.0; 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> (rabbits). Similar products have produced primary skin irritation scores ranging firom 0.67 to 3.83/8.0 (rabbits). Dermal LD50 for similar products was greater than 2g/kg; practically nontoxic for acute exposures by this route. For a similar proc(LICt oral LD50 was greater than 5g/kg; practically non-toxic for acute exposures by this route.
Middle distillate: From skin-painting studies olfpctroleum distillates of 'sJmilar composition and distillate range, it has been shown that these types of materials often possess weak carcinogenic activity in laboratory animals. In these tests, the material is painted on the shaved backs of mice twice a week for their lifetime. The material is not washed off between applications. Therefore, there may te a potential risk of skin cancer from prolonged or repeated skin contact with this product in the absence of good personal hygiene. This particular product has not been tested for carcinogenic activity, but we have chosen to be cautious in light of the findings with other distillate streams.
Occasional skin contact with this product is not expected to have serious eftfets, but good personal hygiene should be practiced and repeated skin contact avowided. This product can also be expected to produce skin irritation upon prolonged or repeated skin contact.
Personal hygiene measures taken to prevent skin irritation are exp)ectedl to be adequate to prevent risk of skin cancer.
Materials of this type have been shown to produce kidney damage in male rats following prolonged inhalation exposures. Following extensive research, this effect appears to be unique to the male rat and is considered to be of little or no relevance in terms of human health risk.
This product has a sufficiently low vapor pressure to prevent a hazardous buildup of vapors unless the product is heated, used in a confined space with inadequate ventilation or misted. Inhalation of mist or high concentrations of vapors can produce dizziness, headache, nausea, unconsciousness and death, and possibly cause irritation of the eye, nlose and throat.
Ingestion of this material can cause gastrointestinal irritation and diarrhea. Aspiration of this product into the lungs can cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this product. Do not siphon by Illouth.
N IOSH has recommended that whole diesel exhaust be regarded as a potential occupational carcinogen, based on findings of carcinogenic responses in laboratory animals exposed to whole diesel exhaust. The excess cancer risk for workers exposed to diesel exhaust has not been calculated; however, exposure should be minimized to reduce potential risk.
No component of this product present at levels greater than 0. 1% is identified as a carcinogen by the U.S. National Toxicology Piogram, the U.S. Occupational Safety and Health Act, or the International Agency on Research on Cancer (1ARC).
12.0 ECOLOGICAL INFORMATION Ecological testing has not been conducted on this material by BP.
13.0 DISPOSAL INFORMATION Disposal must be in accordance with applicable fi.deral, state, or local regulations.
Enclosed-controlled incineration is recommended unless directed otherwise by applicable ordi nanrices.
The container for this product can present explosion or fire hazards, even when emptied!
To avoid risk of injury, do not cut, puncture, or weld on or near this container. Since the emptied containers retain product residue, follow label warnings even afier container is emptied.
14.0 TRANSPORTATION INFORMATION U.S. DEPT O TRANSPORTATION Shipping Name Diesel Fuel Hazard Class Combustible liquid.
Identification Number NA 1993 Packing Group Ill INTERNATIONAL INFORMATION:
Sea (IMO/IMDG)
Shipping Name Diesel Fuel Class 3.3 Packing Group III UN Number UN 1202 Air (ICAO/IATA)
Shipping Name Diesel Fuel, UN 1202 Class 3
Packing Group IIl European Road/Rail (ADRIRID)
Shipping Name Not determined.
Canadian Transportation of Dangerous Goods Shipping Name Fuel Oil Hazard Class 3
UN Number UN 1202 Packing Group Ill 15.0 REGULATORY INFORMATION CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR Part 302.4): This product is exempt from the CERCLA reporting requiremenlts under 40 CFR
Part 302.4. 1 However, if spilled into waters of the United States, it may be reportable under 33 CFR Part 153 il it produces a sheen.
SARA TIT.,E III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR Part 355): This product is not regulated under Section 302 of SARA and 40 CFR Part 355.
SARA TITLE III SECTIONS 311/312 HAZARDOUS CATEGORIZATION (40 CFR Part 370): This product is defined as hazardous by OSHA under 29 CFR Part 1910.1200(d). Hazardous categories For this product are: Acute = yes; Chronic = yes; Fire
= yes; Pressure = no; Reactive = no.
SARA TITLE III SECTION 313 (40 CFR Part 372): This product contains the following substance(s), which is on the Toxic Chemicals List in 40 CFR Part 372:
KComponent/CAS Number [Weight Percent I-Frimethylbenzene 95-63-6 12.0 FXylene 1330-20-7 11.5 U.S. INVENTORY (TSCA): Listed on inventory.
OSHA HAZARD COMMUNICATION STANDARD: Combustible liquid. Irritant.
WHMIS Controlled Product Classification: B3, D2A, D2B.
EC INVENTORY (EINECS/ELINCS): One or more components not listed on inventoly.
.JAPAN INVEN'TORY (MIITI): One or more components not listed on inventory.
AUSTRALIA INVENTORY (AICS): One or more components not listed on the inventory.
KOREA INVENTORY (ECL): One o" more components not listed on inventory.
CANADA INVENTORY (DSL): One or more of the components of this product is not listed on the DSL.
PHILIPPINE INVENTORY (PICCS): One or more components not listed on the iinventoiy.
CHINA INVENTORY (IECS): Not determined.
16.0 OTHER INFORMATION Prcpared by:
Product Stewardship Issued: February 11, 2002 This Material Sifihv Data Wieet con/brins to the requirements o/'ANVS Z400. 1.
NOTICE. 7This A/Žterial Safoev Data Sheet is based upon data considered to be accurate at the time a/'its preparation. Despite our c/fortsn, it iav not be up to date or ap)plicable to the circiinstances ofany particular case. We are not responsible fior an, damage or in/my restulting.f'iom abmormal use, f/omti any.V/
i/ih e to /1b/low aCpropriate practices or fr-ome hazards inherent in the nature of/he product.