ML17334B521

Forwards Groundwater Discharge Permit Application,Storm Water Discharge Permit Application & NPDES Permit Application for Review Per App B of Ts.W/One Oversized Drawing

ML17334B521
Person / Time
Site:	Cook
Issue date:	04/13/1994
From:	FITZPATRICK E INDIANA MICHIGAN POWER CO. (FORMERLY INDIANA & MICHIG
To:	HICKMAN J B NRC OFFICE OF INFORMATION RESOURCES MANAGEMENT (IRM)
References
AEP:NRC:1208B, NUDOCS 9412070157
Download: ML17334B521 (690)

Text

{{#Wiki_filter:Indiana Michigan Power Company One Summit Square , P.O.Box 60 Fort Wayne, IN 46801 219 425 2111 CERTIFIED MAIL 4 P 378 90l 729 IItIDIAItIA NICHIGAN POWER Mr.J.B.Beauboeuf-Waste Management Division Michigan Department of Natural Resources John Hannah Building P.0.Box 30241 Lansing, MI 48909 March ll, 1994

Dear Mr.Beauboeuf:

RE: Donald C.Cook Nuclear.Plant Groundwater Discharge Permit Application Enclosed please find a groundwater discharge permit application for the Cook Nuclear Plant located in Bridgman, Michigan, Berrien County.As requested by Mr.Scott Ross during our meeting on November 10, 1993, also enclosed is a study which compares the quality of the effluent from the Turbine Room Sump (TRS)discharge to that of the absorption pond discharge to groundwater. Included with the permit application is a description of the changes scheduled to be made to further reduce the concentrations of impurities discharged into the absorption pond.Please note, also as requested by Mr.Scott Ross, that this application addresses only the Cook Nuclear Plant's discharges to the groundwater. An application for renewal of the NPDES surface water discharge permit MI0005827 will be submitted by April 1, 1994.The attached study indicates the absorption pond provides excellent mixing, with a mixing/dilution factor of approximately 20:1.Furthermore, the actual.water entering the ground meets all of the proposed groundwater effluent limits with the exception of aluminum.The aluminum discharge is the result of the use of aluminum sulfate (alum)as a flocculent in the makeup water plant.The replacement of alum is currently being pursued, as described in Attachment 4.Additional changes planned for the Cook Nuclear Plant will result in further reduction of the concentrations of impurities to the absorption pond.Attachments 1 and 2 describe the makeup plant neutralization system and sequencing batch reactors respectively, which will result in improved effluent water quality. March 11, 1994 Mr.J.B.Beauboeuf Page 2 Attachment 3 is a description of the present zebra mussel-control strategy as it affects the groundwater discharge as well as some of the options being evaluated for future improvements. Attachment 5 is a description of'hemical corrosion control additives which will be used in various plant systems.These additives will be chosen on their reduced environmental toxicity as well as corrosion control performance. Finally, we offer to the agency the following proposals for establishing compliance with the proposed groundwater effluent standards:

• We propose to continue compliance monitoring

.at the turbine room sump discharge. The absorption pond study has.demonstrated that the water entering the aquifer meets the proposed.groundwater effluent limits for boron, sulfates, sodium, and total dissolved solids.Therefore, we propose a monthly composite sample made up of 24 hour daily composite samples be utilized for compliance monitoring.

• We request that aluminum be regulated by total pounds released as proposed by Mr.Ross in our November meeting, rather than by concentration in the absorption pond.The proposed poundage limit is a maximum 125 pounds alum per day.Should you have any questions on the attached material please contact John Carlson, Cook Nuclear Plant Environmental Supervisor, at (616)465-5901 ext.1153 or me at (219)425-2118.

We would be happy to meet with you at your convenience to discuss the application if you believe that would be helpful.Very truly yours, Donald L.Baker Environmental Affairs Director DLB/sdb/046, 042 Enclosure March 11, 1994 Mr.J.B.Beauboeuf Page 3 bc: W.A.S.D.E.D.To N.D'Onofrio/M. A.Bailey/J.L.Hughey A.Blind J.Brewer M.Fitzgerald/J. P.Carlson E.Fitzpatrick W.Kemp/K.D.Mack E.Webb/J.P.Novotny Attachment 1 Makeup Demineralizer Regeneration Waste Neutralization System The Cook Plant is installing a system to collect and treat makeup demineralizer regeneration wastes to meet proposed pH permit limits.The current practice is to isolate the Turbine Room Sump (TRS), accumulate the wastes within the TRS, neutralize the waste with sulfuric acid or sodium hydroxide, then discharge the neutralized contents of the TRS to the Absorption Pond.Because the regeneration wastes are not the only source of water being collected in the TRS, a high water level within the TRS may require the discharge of the sump contents prior to the wastes being completely neutralized. The new system will allow collection and neutralization of the regeneration wastes apart from the TRS.The holding tank for the waste will also be the point of treatment with the capability to add and mix sulfuric acid or sodium hydroxide with the waste prior to metering the neutral mixture to the TRS.The total cost of the Makeup Demineralization Waste System is$3,600,000.00. The system is targeted for completion by January of 1995, with system startup to occur thereafter. Attachment 2 Sequencing Batch Reactors The Cook Plant is currently requesting quotations to install a pair of pre-engineered sequencing batch reactors (SBR)to meet the proposed groundwater effluent limits.The new system will operate at a design flow of 50,000 GPD with a maximum flow of 60,000 GPD.The South Extended Aeration Package Plant will be utilized as a retention tank to ensure efficient SBR operation. Effluent from the new system will continue to be discharged into one of the two seepage lagoons.The new system will be installed and operational by December of 1995. Attachment 3 Zebra Mussel Control Strategy Zebra mussels are a menace to any industrial or municipal process drawing water from Lake Michigan.Our current control plan is to chlorinate and perform periodic shock chemical treatments utilizing a proprietary chemical formulation. The Plant has also changed the source water for the fire protection system to a potable supply from Lake Township.This method of control was developed for short term relief from the effects of zebra mussel infestation. Based on over three years experience in dealing with the mussels at Cook Plant and other Great Lakes facilities, a new strategy is being proposed to our corporate management for approval to protect all operations frog infestation. The new strategy incorporates intermittent oxidizing biocide treatments of the circulating water system beginning at the intake structures in Lake Michigan, continuous oxidizing biocide treatment of the essential service water and non-essential service water systems, addition of sodium bisulfite to reduce any residual oxidizing biocide prior to discharge to the lake, and, if necessary, shock treatments utilizing proprietary chemical formulations. The goal of the program is to (1)eradicate existing populations and control further settlement of zebra mussels within the plant systems utilizing lake water, (2)treat the residual oxidant being discharged to non-detectable levels, and (3)reduce or eliminate the number of remedial shock treatments necessary to kill settled colonies of zebra mussels.The resultant zebra mussel control changes will ultimately affect discharges to the Turbine Room Sump from plant systems that are supplied by miscellaneous sealing and cooling water and systems that use non-essential service water that discharge directly to the TRS. Attachment 4 Alum Replacement Program A Chemistry Task Force has been evaluating chemical flocculent replacements for alum (aluminum sulfate).Our corporate management is currently reviewing various flocculents, taking both groundwater effluent standards and reverse osmosis system performance into consideration. The replacements currently being reviewed are mainly polymeric flocculent which will enhance the removal of suspended solids in the pre-filters and meet manufacturer recommendations for the water entering the reverse osmosis system.The recommendations from the task force, once approved, will require additional time to test and implement. The environmental benefit of this review is the reduced amount of aluminum which will be discharged to the groundwater through the Turbine Room Sump discharge. The scheduled target implementation date to use a new flocculent is fovrth quarter of 1994.

Attachment 5 Chemistry Corrosion Control Additives The Plant is evaluating substitutes for the current corrosion control additives in the steam generators, plant heating boiler, feedwater and condensate systems, and closed heating/cooling systems.These substitutes will include carbohydrazide, and other available products from chemical companies such as Betz or Nalco.The environmental benefits of these additives include utilization of more benign corrosion control products or products requiring lower effective concentrations. Use of these products will necessitate discharge to the Turbine Room Sump pathway in concentrations to be determined upon effective optimization. Consequently, higher concentrations or iron and other system products can initially be expected. Comparative Study of Turbine Room Sump Discharges and Absorption Pond Water Chemistry Cook Nuclear Plant Groundwater Application February 7, 1994 INTRODUCTION A study was conducted to characterize the water quality in the Cook Nuclear Plant Absorption Pond complex prior to discharge into the groundwater. This was at the request of Mr.Scott Ross (Michigan DNR)during our November 1993 meeting in Lansing, MI.The intent of the study was to determine the mixing and dilution effects of the Absorption Pond on discharges from the plant's Turbine Room Sump (TRS).This report presents the results of the study, data analysis, and groundwater implications. Wastewater generated in the plant either drains to the TRS or is pumped to the TRS from localized sumps.The primary sources of wastewater include Makeup Plant demineralizer regenerations, filter backwashes, floor drains, chemistry lab wastes, various equipment and system drains, and non-contact cooling water.Water is collected in the TRS,'eutralized as necessary, and is periodically discharged to an onsite Absorption Pond complex.The ponds are located approximately 825 feet southeast of the plant (Figure 1).The Absorption Pond complex consists of the original Absorption Pond and an Overflow Pond connected by a 392 foot ditch.The ponds have received an average TRS discharge flow of 301,000 gallons per day during the last six months of plant operation. Both ponds maintain relatively stable water levels with the Absorption Pond overflowing continuously to the downstream Overflow Pond.The pond water entering the ground eventually flows to Lake Michigan based on a 1991 hydrogeology study.MATERIALS AND METHODS'he Absorption Pond study consisted of three stages: 1)a preliminary conductivity survey and pond volume determination, 2)an 18-day comparison of TRS and Absorption Pond water chemistry, and 3)data analysis and report generation. The preliminary conductivity survey was conducted to determine the uniformity of water chemistry within the Absorption Pond and to obtain pond depth readings.The subsequent 18-day study included two Makeup Plant demineralizer regenerations and was conducted with both plant units operating between 70 and 100<power.The second regeneration was"forced" to compress the study time and provide a more conservative evaluation of the effects of regenerations. The amount of acid and caustic used in the regenerations was maintained at normal levels.Page 1 of 20

Preliminar Surve A sampling grid was established on the Absorption Pond and Overflow Pond on 40 foot intervals using permanent reference points.At each point, a conductivity measurement was taken at a depth of approximately 1.5 feet using a Hach Model 44600 conductivity meter.Pond depths were also taken at each point using an Impulse Model 4400 depth finder.Additional depth readings were taken around the periphery of the ponds to better develop depth contour maps.The areas of the two ponds were determined using a November 1993 aerial photograph scaled to 1 inch=660 feet and an electronic planimeter. Ten repetitive measurements were taken on each pond.Average areas were then calculated for the ponds.The volumes of the two ponds and the interconnecting stream were calculated using the depth contour maps and area data.The areas between the depth contour lines were multiplied by the average depth and added to obtain the total pond volumes.18-Da Stud The study was designed to obtain daily composite samples from the TRS and Absorption Pond complex during a period encompassing two demineralizer regenerations. Samples were collected once per day from the Absorption Pond.The NPDES autocompositor was used to obtain daily TRS composites for the study.Cook Nuclear Plant personnel analyzed the samples for pH and conductivity. Halliburton NUS Environmental Laboratory analyzed the samples for sulfate, chloride, sodium, total dissolved solids, total aluminum, dissolved aluminum, total boron and dissolved boron.Four sample locations were selected to make up the daily composite for the Absorption Pond complex.Two central points were located at 10 foot depths in the Absorption Pond and two central points at two foot depths were located in the Overflow Pond (Figure 2).Tygon tubing was secured at each sample location and run to the pond shores for sampling.Battery operated peristaltic pumps were used to purge and draw the samples.Equal quantities from each point were combined to make up the Absorption Pond composite. A TRS and Absorption Pond study period composite was also analyzed for the above parameters which consisted of equal quantities from the 18 daily composites. The composites were used as checks on the daily analytical data.An additional set of independent grab samples was collected over a 28 hour period during and after the second demineralizer regeneration to provide more detailed data on the event.Grab samples were collected every four hours from the TRS and composite samples (four points)were collected every six hours from the Absorption Pond.The samples were analyzed for conductivity to provide a relative indication of the short-term effects of demineralizer regenerations. Page 2 of 20 Data Anal sis and Re ort The data from the study was compared statistically using Systat software.The following comparisons and calculations were performed to evaluate the data and test the validity of the study:-The TRS and Absorption Pond data were compared with proposed groundwater discharge limits to determine if the limits would be met during demineralizer regenerations.-The TRS and Absorption Pond data were compared graphically to ensure the patterns matched mass balance calculations.-Mass balances for selected chemistry parameters were performed including calculated versus actual Absorption Pond value comparisons.-The study data were compared with the NPDES discharge monitoring data from past months to ensure the study was representative of plant operations. Statistical significance is expressed with a percent confidence level and method, when appropriate. RESULTS Preliminar Surve and Pond Volumes Initial conductivity measurements indicated the ponds were mixing uniformly. Conductivities ranged from 310-328 uS in the Absorption Pond and from 340-347 uS in the Overflow Ponds.It was concluded that the TRS discharge plume was mixing very quickly and that the selection of sample points could be based on representing equal areas of the Absorption Pond complex.The four sample points shown in Figure 2 were selected on this basis.Depth readings were obtained at 60 locations in the Absorption Pond and at 15 locations in the Overflow Pond.Depth contour maps were developed from this data for the two ponds (Figures 3 and 4).The maximum measured depth of the Absorption Pond was 19.0 feet and 4.7 feet for the Overflow Pond.Pond surface areas and volumes are shown in Table 1.The total water surface area is 2.21 acres with a combined volume of approximately six million gallons.This provides a daily TRS dilution factor of almost 20:1 based on a 301,000 gpd average flow rate.Page 3 of 20

18 Da Stud The TRS water chemistry remains relatively constant (normal TDS range of 130-170 mg/1)except following Makeup Plant (MUP)demineralizer regenerations. The sulfuric acid and sodium hydroxide used to regenerate the demineralizers sharply increase the sulfate, sodium, conductivity, and TDS levels for approximately 12 hours.The regenerations are conducted on an as needed basis and averaged once per 12 days during the last six months.The trend is toward more infrequent regenerations as operation of the reverse osmosis (RO)unit is refined.Analysis results for the 18 day sampling period for the TRS and Absorption Pond are listed in Table 2.The analysis results for the TRS and Absorption Pond are compared graphically in Figures 5 through 14.Even following demineralizer regenerations, the studied chemistry parameters remained well below the proposed groundwater limits in the Absorption Pond with the exception of dissolved aluminum.The sharp increases in conductivity, sulfate, sodium, boron, and TDS are directly correlated with MUP demineralizer regenerations. The two boron peaks are thought to be due to the release of boron from the cation beds during the regenerations. A Lake Michigan boron level of 83 ug/l was reported in our 1990 NPDES Permit apllication. The amount of boron removed from processing approximately 4-5 million gallons of Lake Michigan water between regenerations would account for the peaks.The dissolved aluminum exceeded or equaled proposed ground water discharge limits in the Absorption Pond on each day;dissolved aluminum values ranged from 50-140 ug/l compared to a limit of 50 ug/l.Aluminum levels in the TRS are elevated due to the use of alum (aluminum sulfate)at an average rate of 300 pounds per week.Higher rates are used during turbid lake conditions. There was excellent correlation between the TRS and Absorption Pond results for all parameters studied.Table 3 lists the multiple correlation coefficients (R~), F-Ratios for the linear regression tests, and significance level (p).In most cases, the probability of the TRS and Absorption Pond chemistry parameters not being related is less than O.l<.The correlation between the TRS and Absorption Pond could be improved slightly by comparing Absorption Pond data one day later than the TRS data ("lagging one day").This probably reflects the sampling time difference: 1000 hours for the Absorption Pond and 2200 hours for the TRS.This indicates the Absorption Pond data are reliable in assessing the true effects of the TRS on Absorption Pond water chemistry. Page 4 of 20

Mass balances were also conducted following the regeneration events to further define the validity of the study.The calculated concentrations for the Absorption Pond following regeneration are reasonably close to the actual concentrations obtained from analysis.The results are presented in Table 4.A more intensive short-term study of the effects of regenerations on TRS and Absorption Pond water chemistry was conducted on January 4-5, 1994.The conductivity results are included in Table 5 and shown graphically in Figure 15.The results indicate that the TRS returns to normal water chemistry approximately 12 hours after the start of a regeneration. The data also indicates that the Absorption Pond mixes very quickly, thereby buffering TRS chemistry spikes.Xn addition to meeting the proposed limits for the TRS discharges, installation of the reverse osmosis (RO)unit has resulted in a marked reduction in levels of groundwater contaminants. Figure 16 illustrates the water quality effects of operating the RO unit to reduce demineralizer regenerations on the TRS and groundwater Well f11, the closest well to the Absorption Pond.As the plant becomes more efficient at operating the Makeup Plant and other improvements are made, we expect this trend to continue.CONCL'USZONS The quality of the Absorption Pond water entering the aquifer was within the proposed groundwater limits for all of the parameters studied except for dissolved aluminum.The aluminum levels were still very low and will be reduced below the 50 ug/1 limit once plans to replace alum as a flocculant are completed. Therefore, the TRS compositor sample can continue to be used for discharge monitoring with assurance that the groundwater limits will be met.Mixing and dilution of TRS discharges with Absorption Pond complex water provided a buffering effect resulting in stable pond water quality even during demineralizer regeneration periods.Other than aluminum, the average concentrations of the chemical parameters studied were equal to or less than 60 percent of the proposed concentration limits.This indicates that.there is'substantial margin against exceedances should plant operating conditions deviate from the normal conditions included in this study.From the trends in groundwater well data over the last year, it is also apparent that the Cook Nuclear Plant has made great strides in improving groundwater discharge quality.We expect this trend to continue with further refinements of our Makeup Plant and installation of the neutralization tank and new sewage treatment facility.Page 5 of 20

Table l-Pond Volumes and Absorption Areas Area Volume Location Absorption Pond Overflow Pond Connecting Stream Total Sq.Feet 62,291 30,056 3,920 96,267 Acres 1.43 0.69 0.09 2.21 Cu.Feet 704,606 85,396 3,920 793,922 Gallons 5,270,453 638,762 29,321 5,938,536 page 6 of 20

Table 2-TRS and Absorption Pond Analytical Results (mg/l)Day'ulfate Sodium Chloride TDS Total-Al Dissol-Al Total-B Dissol-B Cond(uS)pH TRS AP TRS AP TRS AP TRS AP TRS AP TRS AP TRS AP TRS AP TRS AP TRS AP 53 N N 10 N 150 N 0.50 N 0.10 N 0.04 N 0.05 N 261 N 7.22 N 53 88 6.2 22 10 11 150 200 0.80 0.40 0.07 0.09 0.04 0.06 0.06 0.06 263 363 7.19 7.2 52 96 4.8 48 91 4.7 55 90 8.5 9 11 23 10 10 23 10 10 150 210 150 220 0.58 0.67 160 220 0.89 0.20 0.24 0.25 0.09 0:05 0.06 0.19 0.07 0.05 0.14 0.14 0.05 0.06 0.06 0.06 0.06 0.07 0.05 0.06 0.05 0.06 267 275 265 365 7.25 7.2 372 7.16 7.2 362 7 26 7 0 10 12 13 14 85 100 16 49 94 5 5 55 97 8.3 60 92 5.9 480 94 190 47 110 51 110 6.3 53 110 52 110 5.6 51 100 5.9 24 10 11 22 10 11 22 11 11 23 10 11 23 11 10 25 11 10 28 11 11 28 10 30 10 10 31 10 10 170 210 0.90 130 210 1.60 140 200 1.20 140 200 0.75 740 190 1.10 130 220 0.91 140 190 0.97 130 210 0.98 130 210 1.60 140 190 1.50 0.22 0.26 0.25 0.32 0.31 0.23 0.36 0.33 0.35 0.50 0.09 0.15 0.06 0.11<.05 0.06 0.16 0.10 0.05 0.15 0.06 0.06 0.09 0.08 0.12 0.12 0.08 0.06 0.30 0.07 0.05 0.30 0.10 0.05 0.20 0.10 0.06 0.30 0.07 0.05 0.06 0.06 0.06 0.06 0.06 0.06 0.06 0.06 0.06 0.06 0.06 0.06 281 0.05 0.06 276 0.05 0.06 275 0.03 0.06 287 0.11 0.06 1135 0.04 0.06 306 0.06 0.04 300 0.05 0.06 269 0.05 0.05 303 0.05 0.06 251 379 7.08 7.0 381 6.99 7.1 376 7 06 7 1 365 7.60 7.2 369 7.67 7.1 415 7.44 7.2 406 7.42 7.1 406 7.72 7.4 420 7.49 7.6 425 7.60 7.6 15 47 110 5.5 16 680 110 260 17 18 65 130 14 N 120 N Avg.113 103 31 Comp 350 110 150 9 10 38 N 10 26 10 10 29 11 10 28 10 10 27 10 10 150 190 1.80 960 220 0.16 160 260 0.61 N 240 N 223 211 0.97 600 220 0.66 0.50 0.27 0.38 0.28 0.31 0.29 0.17 0.09 0.05 0.50 0.07 0.09 0.16 0.20 0.16 N 0.07 N 0.17 0.09 0.06 0.30 0.08 0.1 0.06 0.06 0.06 0.07 0.06 0.06 0.05 0.05 303 0.09 0.06 1700 0.15 0.06 284 N 0.06 N 0.06 0.06 406 0.11 0.06 989 410 7.30 7.0 395 7.18 7.6 450 7 19 7 0 399 7.16 6.8 342 7'0 7.1 399 7.16 6.8 Page 7 of 20 0 Table 2-Continued The first TRS sample was collected at approximately 2200 on December 19,1993 (Day 0).The Day 0 data was included in the Table 3 linear regression model when TRS data was shifted down (lagged)one day.A TRS sample was not collected on the evening of the final day of the study, January 6, 1994.Demineralizer regenerations were conducted on Day 9 (December 28)and Day 16 (January 4).2.Study composite samples consisted of combining equal quantities of the daily composites from the TRS and AP.The much higher than expected analytical results for the TRS composite are believed to have been caused by the inadvertent addition of a grab sample during the 28-hour regeneration study.Page 8 of 20 t' ~~~~r~~~~~~~~~~~~~~~I I 0~~I I I I I I I~I I I I I I III~I I~I~~~~~I I I~~I I I I I'I~~I~~~~--~~I~~~~~~~>~~I~I I'~e~0 0 I~~e'I I I I I I I~I I~~I I I I I I~~I I I~I~I~I~~I~~-~~I I~I+I~i~I I I I I I I I I III I I I I~~0~~~~I~0~~~~~~~~0~~~I I I o--o 0~~~~~~0~~~~~~0 0~~~I'.~~0~

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Table 5-Regeneration Effects on Conductivity (uS)over a 28-Hour Period Time 800 1000 1200 1600 2000 2200 2400 400 800 1000 1200 263 NA 6,820 2,380 367 NA 195 200 256 NA 245 Abs.Pond 395 NA 470 NA 447 NA 436 NA 445 NA 1.Makeup Plant demineralizer regeneration discharge from the TRS began at approximately 1140 hours on Ol/04/93.Page 11 of 20 ~>g<>B 1-Cook Nuclear Plant, Absorption Pond Complex and WLL~~CRS L 40t W Plant/)Cj-'L'~Ll a w~v 0 O L P (L I Sverflo POND I-~.'~~".Page 12 o f 20 Figu1e 2-Absorption Pond and Overflow Pond Sample Locations Absorption Pond Connecting Stream (392 feet)Overflow Culvert p/y/I lg X=Sample Location P=Pump Location Overflow X Pond P Page 13 of 20 Figure 3-Absorption Pond Depth Contours/go)PE tj>'r ro Figure 4-Overflow Pond Depth Contours 41 Page 14 of 20 Figure 5-conductivity 2000 1500 1000 O 0 0 500 0 I I I o i 2 o i s e r e o io>>ia is i4 is ie ir ie DAY----AP TRS Figure 6-pH 1.0 0.9~A pH 8.5 0.8 0.7~pH 6.5 0 i 2 s 4 s e r e o io ii 12 13 i4 is ie ir ie DAY----LOGAP LOGTRS LOGMAX LOGMIN Page 15 of 20 Figure 7-Sul f ate 700 600 500 O)4pp~300 CO 200 100 0 1 2 0 4 5 8 1 8 9 10 1'1 12 15 14 15 18 ll 18 OAY----AP TRS LIMIT Figure 8-sodium 300 200 0~~00 0 1 2 0 4 5 8 7 8 8 10 11 12 18 14 ld 18 17 18 DAY----AP-TRS LIMIT Page 16 of 20 Figure 9-Chloride 300 200 l 0 Z 0 100 0 1 2 Q 4 5 0 1 8 9 10 11 12 18)4 15 1S ll 18 DAY----AP TRS LIMIT Figure 10-Total Dissolved Solids 1000 800 600 2 03 P 400 200 0 1 2 0~5 5 7 6 0 10 11 12 18 14 15 15 11 18 DAY----AP TRS LIMIT Page,17 of 20 Figure 11-Total Aluminum 2.0 1.5 2 i.0 0.5 0.0 0 1 2 5 4 5 5 I 8 9 10 1 1 12 13 14 1$15 ll 18----AP-TRS DAY Figure 12-Dissolved Aluminum 0.6~04 E 0 g 0.2 O 0.0///~ef I I A/N I----AP-TRS LIMIT 0 1 2 5 4 5 5 I 8 9 10 11 12'5 14 15 15 17 18 DAY Page 18 of 20 ]i Figure 13-Total Boron 0.20 0.15 E C o 010 O K 0 0.05 i I'i I I I'i I I'\I I I I I I I I I I I I 0.00 0 i 2 0~s e r s o io ii i2 ie w is ie ir is----TRS AP DAY Figure 14-Dissolved Boron 0.15 0.10 C Q 0 CCl~oQQ5 O\I I I I I I I I 0 I il I I I I I I I I~~~I I I I I I I 0.00 I I I 0 i 2 0 4 s d I 8 0 10 ll 12 ls la is ie il 18----TRS AP LIMIT DAY Page 19 of 20 Figure 15-Effects of Demineralizer Regenerations on TRS and Absorption Pond Conductivity Over a 28-Hour Period 7000 6000 5000>, 4000 O 3000 O 0 2000 1000 I(I I I I I I I I I I I I I\I\I I I I I I I I 0 4 8 12 16 20 24 28 HOURS AP Figure 16-Decreases in 1993 Chemistry Parameters for Groundwater Well N11 and the TRS Due to RO Unit Installation and Reduced Regenerations 1500 1000 500 1 2 3 4 5 7 10 11 12 MONTH"---"" WELLSO4-------WELLNA---TRSS04-TRSTDS Page 20 of 20

.~SEE INSTRUCTIONS 'w NREVERSE SIDE r"': SECTION I re a rll EPA I.D.NuMSER M I D 0'9 86 4 7 62 1 NUMBER-~M I 0 0 0 5 8 2 7 APPLICATION FOR DIS HARGE ERMIT I ICOIFIQTICN EXI~IICI NEIf IICREASEO USE REISSUAtCE 5 t'0 0 EI'--lTEM A.PARENTCOIPANY~CEPTI'ADER"- I ND I N M IC HI GAN 0 WE R CO M PA B.DIV./RmU N/A PHYSICAL LOCATION ADDRESS F e SlREEf IAISER oe'G, I STREET NVE COOK LAC C PLANf OR FACILITY n" O'P K'P L A N T'T M,",,E"L'"C T R IC G E'E STAIOARD IIEXISTRIAL CLASSIFICATION (REFER TO TARE I I I)L44911I~ANO INFORMATION 'e CllY NA%RI GMAN Ml Ie ZIP CODE 4 6'e TQIISNIP L K E%RIEN COe H4%CO RISER~Le Nt%OF AUIHXI IZED CONTACT PERSON 0NAL D L BAK ER Ne TIllE ENV AFFAIRS IR 2 1 9 4.2 5~21 1 Oe AIXRESS (IF DIFFEREHf FRII ABOVE)1 10 E WA YNE ST EET Pe CITY NAIEo n F 0 T WAYNE Oe STAlE Re ZIP CXE 4 680 2 Se lYPE OF TREATIEHT FACILITY (REFER TO TABLE II)~1L~1~2~3A~4G Te PRXRAII RNI EFFECTIVE RES IDLNLS IIANG9%Ãf DATE SLDNITTED 0 YES'HS'N.A, DATE IIPLIIEHIED Ue BACK~ICIER SOLRCE z Ve FOUllfION IIN:ICEHT PREVEHTION PLAN 11/18/92 DATE SIEHITTED 906 Xe lYPE CF DISCHARGE~~Q Ye RI VIXI NAVE A CERTIFIED OPERATCII? El~Cl 0+D.H.Fete arald e,e,g~atr 9~ro~49 9 2 ITEM 2 A>>tiVE R Bo NA%MEN GE MAILING ADDRESS OF APPLICANT Ce STREET ABÃE%CR POST OFFICE BOX 1 1 0 E W Do CllY NVE F ORT W YNE S REET Ee STATE~IN Fe ZIP aXE 4 6802 REOUIRIO SIGNATISIE I~the ooollcsnt,<<ertltv under Densltv ot Isv thst I hove oersonsl ly exercised ond soo tsnl lier vlth the Intorsestlon subeoltted In this ooDIIcstlon ond~I I ottsctveeents ond tn4t, bssed on ov Inoulry ot those Indlvlduols lerooedlotely resoonslble for obtslnln9 the Intoetootlon, I believe th4t the Inter etio Is true, occur4te 4nd cc slots.I e overs th4t there sre 5lonlflcsnt oenoltl~5 ror subnlttln9 tolse Infection, Includln9 the DO$5lbl I lty ot fine snd Ieaorlsoevoent, SIGNATURE OF APPLICANT ch~.R.C.Men e~/<9(9'4>>.,President SIGNATURE OF LOCAL GOVERNIIIITAL REPRESENTATIVE (SEE NOTE ON REVERSE SIDE)TITL 15 (~"'.v>>~\>a 2'm~'I>j, INSTRUCI'IONS FOR CCMPLETING SECTION I l II i'r'(>(r"I"~'Th<5 farm requlreS Infcrmat(cn abOut the faClllty addreSS>,di5Charge IOCat(On, Plant COntrOIS, tyPe Of dl5PO5al faCIIltY and name.'"" address, and signature of the applicant"'and 'local'governmental representative. k Enter Env(rorvrrental Protection Agency.l Oc Number-')f available. "'-,"-*"-"ENTER THE PERMIT N<MBER IN, THE BOX AT" THE TOP OF THIS FORM.THE PERMIT IAIMBER CAN BE FOUNO ON THE FRONT PAGE, OF YOUR EXPIRING',<<c, pERMIT., lf this is,a nev or not previously permitted facility, then leave blank and a number will be asslqned.,>y Z C>, r In the box"Application For Olscharga Permit Isy check one of the five categories (modification, existing unperm(tted> ne<<>Increased use, or relssuance) <<hich your permit application falls Into (see page l4 for definitions). rr ITEM I PHYSICAL LOCATION AOORESS ANO IUFORMATION r'A.-C.Enter the naming Information In accordance with the following: Z e w-For Industrial facilities, provide The parent ocmpany name (A.), the division new (8.), and the plant name (c.).r r-For federal and state facilities p'rovlde the department. new (A.), the division,or.,the bureau.name (8.).and the facility new (C.).il-For corrrwrclal facilities provide the owner'5 name, doing-business as<d.b.a.)(A.)and the facility new<C~)~f!""'O.Enter type of facility.Exeaoles'of this arec foundry;high school;autarratlc car wash;dry cleaners;self-serve laundromat. ~~.>E.Refer to Table III (page 5)for the list of Standard Industrial Classification Code<SIC).Enter the code number that best describes the major product or service produced.F.-l.Ehter the PhySICal IOCatlan Of the faCI llty.OO NOT uae POSt Off(Ca bOX nrmrber..e't,Z)t J.-K.Lo-Ro U.Vo Enter the township and county In which this feel llty Is located.The county code number can be tound In Table I (page>5)~Enter the new, title, address and telephone nrmrber of the facility's authorized contact person.This Derson should be thoroughly ferrl liar vith the facts reported on these forms In the.event that contact regarding the permit appl Ication must be made.Refer to Table II (page 5)for the list of Treatment Facility Types, enter up to five methods used by the facility to treat the wastewater. F 4'>MrIndicate whether this facility has a"Residuals Management Plan".It so, enter'date plan wa5 submitted and the date tile Plan was or Is to be lmplewnted. Such a plan may be needed as deemed appropriate by.the proper Olvlslon 5taff Indicate vhether the waste treatment facilities have a back-up source of paver or whether emergency procedures have been developed In case of a power outage to the waste treatment facility.If the waste treatment feel llty Is not dependent on a source of pover, check the"NA" box.UJ Indicate whether this foci lity has submitted a pollution Incident prevention plan as required under the Michigan water Resources Corrmlsslon Part 5 Rules for the"Spl I lage of Ol I and Polluting Materials". J'f facility has sanitary vastevater (voter used for dawstlc purposes;~,g.~toilets,, slnk5~shover5).enter the nurrrber of people using this facility.X.Check the type of discharge(s) fran this facility.Indicate whether your waste treatment or control facilities are under the supervision of a certified operator.If yes>please provide the Oerson'S new, SOClal security nrmrber, and certificate number plus the ccneany'S feel llty nrmrber.ITEM 2 MAILING AOORESS FOR ALL CORRESPONOENCE A.provide the new of the aDDIIcant. For tha purposes of th)5 apol (cation the applicant Is defined as the Derson signing below In accordance with the directions provided on page ld.Correspondence regarding this application and future permit matters vl I I be sent to the applicant. B.provide the new of the facility, company.or organization which the applicant In"A." above uses for receipt of mall c.~, provide the applicant's address to be used for future correspondence. SIGNATURE OF LOCAL GOVERQCENTAL REPRESENTATIVE NOTE: If sanitary savage Is to be discharged from housing developments, apartment bul ldlngs, shopping centers.or other corrrwrclal developments, Into 5 systerr other than an approved municipal sanitary vesta collection system, this application 5hall be co-signed by an authorized municipal official or township officer.It Is the rule of the Carmlssicn that applications Involving the dl5po5al of sevaoe of human origin from any entity other than local government should Include the local government as a co-5lgner of the statement, and that el I proceedlng5 and hearings against said entity<<III Include the local unit of government a5 a party by appropriate notice, and all permits 155ued as 5 re5ult of 5uch hear lngs and proceedings vll I be tIled jointly against the said unit and entity<water Resources ccnmlsslon part 5 Rules R 525.IO)8<5) and the Michigan Water Resources Ccnmlsslon Act 245 P.A.of l929 as amended Section 6<b)).This co-signature requlr<<rent Is only aDDllcable to sanitary sewage discharges and Is not for any nonsanltary waste streams from this facility. SEE INSTRUCTIONS ON REVERSE SIDE A.IXXIICIPAL 3 Be QRFACE MATER INTAKE SECTION I PERMIT~MI ppp5827 NUMBER LAKE TOWNSH~I P LAEMI C IGA te e SOURCE OF WATER SUPPLY Ce PRIYAlE NEIL De OlMER OUANnTY (we.)auveITY (NAx.)N A 2 6 5161 60 0 0~N A ITEM FACILITY WATER USAGE oIjwrm (we.)A>>PROCESS MATER INCLIDI%CONTACT aXX.Im MATER)ouANTITY (Be H3NCONTACT COOLI%MATER OOANTITY (we.)C e SANITARY MATER aewr TY.)De OTIER 6 3 4 40 0 0~DAY 6 4 2 1 1 2 0 0 0 SAIIDNs/DAY 6 0 00 0~DAY F IR E P RO TEC TI ON WTE R 3 6 00 00 0~DAY ITEM 5 aewrm HYDRAZINE 0 0 3020 12 6 5 0 0~TAEAR CRITICAL MATERIALS&PRIORITY POLLUTANTS USED STORED PRODUCED CLWTITY t4VK OF SIBSTANCE PARA%TER IAPSER ONNTITY CHLORINE SODIUM C 0 7 7 82 50 5 357500 KYLENE 0 1 3 3 02~07 2 50 0 REFER TO TABLES IV&V TOLUENE 0 01088 3 1 POUNDS 2 GALLONS 3 CUBIC YARDS 4 TONS CL'l IA I OOANTITY LITHIUM (Lithium H droxide form)CLASS02 HYDROQUINONE L>>It>>PARAIETER IAPSER asorllY MERCURY 0 0 12 3 319 CLASS 02 1 u/YeR OIMIfllY*L~J/YeR x Total quantity unknown, contained in thermometers, barometers and mercoid switches located throughout the plant. INSTRUCTIONS FOR COMPLETING SECTION I ITEMS 3, 4, AND 5 This form requires Information about the water supply to the feel llty, the feel lltyrs water usage, and crltlcal materials and prlorlty pollutants used, stored, or produced at this feel llty.ENTER THE PERMIT ICMBER IN THE BOX AT THE TOP OF THIS FORM.THE PERMIT NUMBER CAN BE FOUND ON THE FRONT PAGE OF YOUR EXPIRING PERMIT.If this Is a new or not previously permitted feel llty, then leave blank and a number'ill be assigned.ITEM 3 SCURCE OF MATER SUPPLY List all water supplies used.The volrmre may be estimated froyr water supply meter readings or from bl lllng statements from a~ster supply utl llty.If water Is not metered, estimate trcm prmrp capacity.Mhere a name Is required, enter name of water supply;e.g., Mud l.ake, Huron River, or the City of Millpond.ITEM 4 FACILITY MATER USAGE List amounts of water to be used for various purpo5e5 asr Process Mater-see Glossary tor deflnltlon lpage 48).Noncontact Cooling Mater-see Glossary for detlnltlon (page 48).Sanitary Mater-Mater used for dcmestlc purposes;e.g..toilets, sinks, showers.If water Is first used for'na purpose and the srme~ster Is subsequently u5ed for one or Inore other purposes~Indicate the volrmwr per day ot the Inst designated use betore treatment and/or discharge. For example, If water Is Inltlally used a5 noncontact cooling water end then as process water, the quantity ot~ster given should be Indicated as process~ster.The total of Item 4 should equal the total of Item 3.Any difference In these totals should be explained In an attached sheet of this appllcatlon. ITEM 5 CRITICAL MATERIALS ANO PRIORITY POLLUTANTS USED, STORED PRCOUCED List all chemical substances which are In Mlchlgan's Crltlcal Materials Register Table IV lpage 6)and/or U.S.EPA's Prlorlty yet lW t Litt teble y (bee yt tb t e e e tly M.t~.rKd d by tbl~teblllty. SEE INSTRUCTIONS ON REVERSE SIDE SECTION I PERMIT~MI 0005827 NUMBER ITEM 3 Ae Nltl CIPAL SOURCE OF WATER SUPPLY PRIVAlE MElL ouAttflTY (we.)ouANTITY (we.)aulnNs/DAv auUINs/DAv tTEM 4 FACILITY WATER USAGE As oautfITY (we.)PROCESS HATER INCLLD It6 CONfACT CCOLIm HATER)OOANTITY (r MINCONTACT CXILI t6 HATER txtANTITY (we.)SANITARY HATER OTIER (we.)aulnNsJ DAY~DAV GAllnNS/DAY aulnNs/DAv ITFM 5 I OOOITITY MERCURIC NITRATE C L S+W/YEAR CRITICAL MATERIALS PRIORITY POLLUTANTS USED STORED PRODUCED K QJN I x NA%OF SISSTANCE PARA%TER tltSER OOANfllv NttK OF QSSTANCE MERCURIC SULFATE CL SSQ 21 CHROMIC ACID C LASS 01 5 L~J/YEAR REFER TO TABLES IVaV NAIE OF QBSTANCE PARAtETER MJSER Oautf ITY CHLOROFORM 6 3 XJ/YEAR 1 POUNDS 2 GALLONS 3 CUBIC YARDS 4 TONS CL Ql IA I X NAIE OF QEISTAM:E PARAtETER MPEIER oSutf llY C LASS01 7 WITS LXI/YEAR PARA%TER MJSER oUutfllY NAtK OF QSSTAtCE PARAIETER MHKR ouANTITY S OS 0 13 32 214 T/m L~J/YEAR" Contained in insulation.throughout plant;believed not to be present in the discharge. 17 INSTRUCTIONS FOR COMPLETING SECTION I ITEMS 3, 4, AND 5 This form requires Information about the~ater supply to the feel llty, the feel Ilty's water usage, and crit teat materials and prlorlty pollutants used, stored, or produced at thIs faclllty.I ENTER THE PERMIT ISMBER IN THE BOX AT THE TOP OF THIS FORM.THE PERMIT NIPRIER CAN BE FCVNO ON THE FRONT PAGE OF YOUR EXPIRING pERHIT.If this Is a new or not previously pen((ltted feel llty, then leave blank and a number will be assigned.ITEM 3 SOURCE OF WATER SUPPLY l.lst all water supplies used.The volu((e may be estimated frcm water supply meter readings or frcm bllllng statements from a water supply utlllty.If~afar Is not metered, estimate from pm((p capacity.where a naee Is required, enter name of~ater supply;e.g., Mud Lake, Huron River, or the City of Millpond.ITEM 4 FACI LITY WATER USAGE List amounts of water to be used for various purposes as: Process Water-see Glossary for deflnltlon lpage 48).Noncontact Cooling'Water-see Glossary for deflnltlon Ipage 48).Sanitary Water-Water used for domestic purposes;e.g., toilets, sinks.showers.If~ater Is first used for one purpose and the sane water Is subsequently* used for one or more other purposes, Indicate the vol(m>>per day of the last designated use before treatment and/or discharge, For example, If water Is Inltlally used as noncontact cooling water and then as" process water, the qua'ntlty of water given should be Indicated as process water.The total of Item 4 Should equal the total of Item 3.Any difference In these totals should be explained In an attached sheet of this appllcatlon. ITEM 5 CRITICAL MATERIALS AND PRIORITY POLLUTANTS USED STORED PRCDUCED List all chemical substances which are ln Mlchlgan's Crltlcal Materials Register Table Iy (page 6)and/or U.S.EpA's Prlorlty Po((ut t (((t T ((V ((((((7)((t (nt(y~.(~.(~d ((y (((~((('((((y. SEE INSTRUCTIONS ON REVERSE SIDE SECTION I PERMIT~Mj pp p5827 NUMBER~EM 3 SOURCE OF WATER SUPPLY A e e'VI I C I PAI.Be SLRFACE'iJATER IteTAXE C~PRIVATE WELL D.OTnER ee IXI>>eIT TY u V l~%OF'ee'TER'eIAV ~MITITY"'AX,)".JAIITI Tv e uM.)P>>FV I I i I I I GALLOte DAY'eALLCe DAY cAt'te'oAv ITEiVI"UAIITITY uAX.)A~PROCESS WATER (IIJCLtXIIIJS COIITACT COOL!tlS WATER)>>LeAeIT I Ve B.IIOIICNITACT CCCL I M WATER QUAeYT I TY (FAX.)~I I I I I i te'DAv EA'";JS/DAY CALLNIS/OAT FAG IL IT Y WATER USAGE C, SAIII TARY WATER O.OTHER".UAIITI TY I FAX.)SP<4 I>>eIT I TY'uAX.)BALI>>>>JS/DAY)TEM 5 CRITICAL MATERIALS&P RID R IT Y LLUTANTS'JSED STORED I RODUCED REFER TO TABLES IV&V I POUNDS 2 GALLONS 3 CUBIC YARDS 4 TONS IeI i I Iel Cet I lIAeZ OF SUBST>>IJCE QUAtlTI TY HAtlE OF SUBSTAIJCE PARAMETER tll'BER OUAIIT I TY tA%OF SUBSTANCE PARAIETER tILI SER OUAI'll I TY tIAuE OF SLSSTAIJCE eeETER tllSER CU"IT I TY t~OF SL9STA'XE PARAuiPTER te?TSER tÃ%OF SUBSTAXCE NICKEL NITRATE C L IA S.S 0 2 2 ANTIMONY POTASS UM C LASSO 1 0 I I I I~~/YEAR IAI ITS~/vEAR uttl TS~!YEAR WITS LJ/vEAR LII IO IiI Ie PARAt E TER tlltSER OUUIT I TY:~uE OF SLSSTÃICE PARAMETER Ill~I I I WITS~/YEAR WITS LJ/VEAR 17 I'ISTRUCTIONS FCR CCI~ZLET I NG SECTICII I ITEMS 3, 4,<<ND 5 ,his!cr.requires infomarlon about!ne water suoplv to the facility, the facility's water<<sage, and critical n'aterlals and prlcrltv pollutants used, stored>cr produced at th,is foci I ltv.El)TER ME ogc>>IT'dJ'cB Q I)I TFE BOX AT TFE CP OF HIS FCFM.'PERMIT HU'VER CAN BE FOU)d)C".wE cFONT c"'ŽOF YOUR EXPIQING'IS IS 0 ew Cr not Prevlc'sly per<<I ec~pl li v en leave o ianx an 1urper<<'I oe assi ITEM 3""U-rc-NA Q SU""Iv:s!all.<<ater supplies used.The voluee b'av be esrlnared fron water supoly tater reaclncs c"'rcn bill(rg s-are,enrs '.rc~a ware!s piv~I I lry.>5 water Is ror re!epee~es!I are'n purp capacity.<<here a na e is recui 0c, enter na e o.water supplv: e~~i"ud Lake, riuron River, or the City of Ml llpcnd.I TE>>"ACILITv.CATER'JSAGE:.ourts of<<arer rc oe used for various purposes as: Process eater-see Glossary for ceflnltlon (page<<8).'icnccntac! Cooling)rater-see Glossary'cr deflnltlcn (page c8).Sanirarv Rater-'Aater used for dcresrlc ourooses: e.c., rollers.sinks.snowers.<<arer is f irsr used fcr one ourpose anc the sme<<arer ls suosequenrly usec'cr cne or"cre other purposes, lrclca!e he vclure cer cav C.-he last cesicnarec use before treatrenr and/or cischarce. ccr Rxancie..'atet ~s ln(tlal lv used as rcncontact tpci'"c*s!er snc"sn ss prccess'<<a<<er,;he quanri 7 of.<<a!er"ivan s<<pule be inclcatec as:recess<<ater.'e-tai cf lre<<:-'hould ecual the tora)cf Itw 3.Anv c(fference in these!ctals should=.exolainec Ir an attached sheet of r<<ls cool ication.ITc~a 5 Pl ICAL>>ATERIALS ANO PRIORITY POLLUTANTS USED.S CRED.PPCOLCED List all chenical substances '<<nlch are in Michigan's Critical>>aterlals Register Table IV (page 5)and/or"..EPA's Priority Fol I>>tant List Table V (page 7)that are currenrlv used, stored, or produced by this foci II tv. SEE INSTRUCTIONS ON REVERSE SIDE SECTION I BER~~MI 0005827 rEM 6 As PROVIDE A BRIEF DESCRIPTION AND LINE DIAGRAH SHXIIID THE HATER FUXI THROXIH YQB FACILITY FR%INTAKE TO DISCHARGEs SHGH ALL OPERATIONS CONTRIBUTING MASTEMATERs INCLUDING PROCESS AtQ PRODUCTION AREAS>SANITARY FLOMSs COOL!%MATERI AND STtA%QTER RIPOFFs YOU HAY GIKXX SIHIIAR OPERATIONS INID A SIIKsLE INITs llew MATER BAlANCE SHXXJj SHXI AVERAGE FLOHS~QKH AU.SIGNIFICANT USES CF MATER TO PROOUCTSs ATQSPHREs AND DISCHARGEs YOU SHXLD USE ACTUAL HEASLR9%NTS HIeIEVER AVAIIABLFJ OTKRHISE USE YOLB BEST ESTIIQTEs DESCRIPTION (See attached Descriptions) DIAG RANI 19 INSTRUCTIONS FOR COMPLETING SECTION I ITEM 6)This form requires Infomation about the~ater flow through your facility from Intake to discharge. ENTER THE PERMIT NUMBER IN THE BOX AT THE TOP OF THIS FORM.THE PERMIT NWBER CAN BE FOUNO ON THE FRONT PAGE OF YOUR EXISTING PERMIT.If this Is a new or not previously permitted facility, then leave blank and a number will be assigned.ITEM 6 DESCRIPTION ANO LINE DIAGRAM OF FACILITY'5 PROCESSES ANO TREATMENT SCHEME A.Briefly describe the route taken by~ater In your facility from the Intake to the discharge and also provide a line drawing.Example Description and Oia ram Narrative: The rinse water frcm the various plating operations Is collected ln one of the two 35,000 gallon tanks.calcium chloride and alen are added to assist'n fluoride removal and aid In coagulation. The water Is adJusted to a pH of about 5.5 using dilute sulfuric acid.The pH Is then raised to a pH of about IO.3<<lth lime to precipitate the metals as hydroxide. Polymer Is added to f locculate the metal hydroxides. The waste stream flows through a clarifier, the metal hydroxide settles to the bottcm as"sludge".The treated water flows frcm the clarifier to a manhole~here It ccnmlngles with contact cooling~ater fran the strip line.This ccnmlngled ~ater Is discharged to the Buck River.The sludge frcm the clarifier goes to a vacuole filter where It Is dewatered. The sludge Is later taken to a landfill.Calcium Chloride Alum Sul furic Acid Lime Polymer Plating Wastewater 70.000 Gallon Tank Acidification Neutral izatio Flocculat1on Batch Bumps Dump Tank Sludge Thickener Clarifier Hon-contact Cooling Hater Calcium Chloride Alma Sul furic Acid Lime Landfill VacuNa Filter Gondola Sludge Iiater Hanhol e Buck R1ve John Ooe, Inc., Oeertown, manufactures sleeve bearings for autoeotive and truck engines.Production Is divided Into 3 phases.Metal powder ls produced In the first phase.This is acconpanied by melting copper>tin and lead Into Ingots in an electric furnace and applying a Jet of water to quench end solidify the melting metal Into powder form.The second phase consists of adhering the fine metal powder to a coll of steel by passing the tio slowly through furnaces, Water used to cool the strip constitutes the contact cooling water.Bearings are then formed and machined from the coated steel.In the third phase, most bearings receive a nickel strike and lead, tin copper electroplate. The remaining bearings are aluminum or babbitt and receive a tin or lead plate.Rinse water before and after the various plating operations constitutes the process water.Huni ci pal Mater Supp'ly Sanitary Facility 30,000 gpd Huni ci pa 1 Treatment Std fsafa ter Str1pe Line 295.000 gpd Powder Hfg.4 000 gpd Cooling Hater 250,000 gpd Plating Process 40,000 gpd Maste Treatment Plant 45,000 gpd uck R1ve 20 Additional Information Section I Item 6, Subpart A Cook Nuclear Plant Groundwater Permit Application Outfall OOD-Descri tion of Utili Waste Waters Utility waste water from within the plant is discharged into an on-site absorption pond.The ultimate disposition of these waste waters is to the ground which vents to Lake Michigan.The waste waters include: WASTEWATER FLOW DIAGRAM 41 Wastes from the makeup water treatment system.The main contributors to the waste stream are: the makeup plant demineralizer regeneration wastes (avg.40,000 gallons per regeneration), degasifier pump seal water (108,000 gpd), carbon filter backwash water (avg.45,000 gpd)and pre-filter backwash water (avg.72,000 gpd).The retention tank periodically discharges a very small volume of solid material removed by settling.Alum (aluminum sulfate)is added to the pre-filter influent as a flocculent. These pre-filters are backwashed to the TRS to remove the suspended matter captured on the filter media.The Alum contained in the backwash is discharged to the TRS in the form of insoluble aluminum hydroxide. Carbon filters are also periodically backwashed to the TRS.These filters primarily remove organics, chlorine and small amounts of iron.Sulfuric acid and sodium hydroxide used by the makeup demineralizers to regenerate the resin are rinsed to the TRS and generally neutralize each other in the sump, forming sodium sulfate prior to discharge. Non-essential service water is used to supply vacuum degasifier pumps which utilize approximately 75 gpm total via two pumps to remove dissolved gases (primarily carbon dioxide and oxygen)from the vacuum degasifier and exhaust them to the atmosphere. A new component of the makeup plant, a reverse osmosis (RO)system, has been installed to remove the bulk of the dissolved solids from the lake water prior to demineralization. Normal reject water flow is to Lake Michigan.The RO system must maintain very clean membranes to assure efficient operation and purity of water.Several methods are used to maintain this level of cleanliness from scale and biofouling. Using hydrochloric acid or sulfuric acid, the feed water pH is lowered to reduce the scaling tendencies of the water.Approximately once per month a flush is performed using approximately 0.5%hydrochloric acid and caustic to dissolve any scale that deposits on the membranes (avg.5000 gallons per month).A chemical cleaning is performed when the periodic acid washes no longer are effective. 19a Additional Information Section I Item 6, Subpart A Cook Nuclear Plant Groundwater Permit Application WASTEWATER FLOW DIAGRAM 41 (cont.)The chemical cleaning involves several steps and may contain citric acid, hydrochloric acid, phosphoric acid, sodium hydroxide and a neutral pH detergent (avg.10,000 gallons per event).Also, to remove dead biological matter from the membranes, a soak using sodium bisulfite may be performed as necessary, approximately once per year (avg.5000 gallons per event).WASTEWATER FLOW DIAGRAM 42 During periods when not in operation, the heating boiler is stored full of treated boiler water containing at most 400 ppm hydrazine (for oxygen scavenging) and 50 ppm ammonia or 50 ppm ethanolamine (ETA)(for corrosion protection). Prior to use, this"wet lay-up" water is drained to the TRS for discharge into the Absorption Pond.The volume drained is approximately 1600 gallons and may occur 30 times per year.During a unit outage, the condensers are checked for leaks by filling the steam'ide with condensate containing approximately, 1000 grams of fluorescein disodium salt or Rhodamine B.These dyes are fluorescent under black light which aids in the detection of joint and tube leaks during visual inspection. The volume of water drained from the condensers ranges from 160,000 up to 1,000,000 gallons and may occur one time per year.In addition, the cooling water side of the condensers are drained to the TRS for general maintenance periodically (8 condenser halves per unit, approximately 25,000 gallons of lake water per half).The component cooling water system (CCW)is periodically drained to allow for equipment inspection, maintenance or repair.This system uses demineralized water from the makeup plant as its source of makeup water along with a maximum of 1200 ppm nitrite (from Calgon LCS 60)and 100 ppm glutaraldehyde as treatment chemicals. The infrequent drainings may occur and release approximately 60,000 gallons of treated water to the TRS per year.The diesel generator cooling jacket water system(DJW) also employs the same chemical control for corrosion as in the component cooling water system with a maximum of 2000 ppm nitrites from Calgon LCS 60.19b

Additional Information Section I Item 6, Subpart A Cook Nuclear Plant Groundwater Permit Application WASTEWATER FLOW DlAGRAM g2 (cont.)This system is drained to'the floor drains to the TRS when maintenance is performed on the jacket water system.The system volume is approximately 1000 gallons.Any minor system leaks would also be directed to the floor drain during normal operations. The essential service water systems (ESW)and non-essential service water systems (NESW)are also periodically drained to allow for equipment inspection, maintenance, or repair.These drains may discharge approximately 72,000 gallons of Lake Michigan water used for non-contact cooling into the TRS.This water is either chlorinated intermittently at a residual concentration of 0.2 mg/1 TRC or continuously at 0.036 ppm total residual chlorine.During some special treatment periods, this water may contain zebra mussel ,biocides, used as a molluscicide for zebra mussel control.Periodically, components of the ESW or NESW systems may be chemically cleaned to remove iron deposits using vendor supplied cleaning solution such as EDTA (ethylenediaminetetraacetic acid)or ascorbic acid, acetic acid and ammonia.These wastes could either be drained to the TRS or Lake Michigan.The steam generators (S/G)are drained for inspection and maintenance during scheduled unit outages (approximately every 18 months)and during an event where steam generator failure is detected that requires a unit shutdown.The steam generators.utilize 150 ppb hydrazine, 20 ppm ammonia, and 2.5 ppm ETA to control the water and steam chemistry to be non-aggressive to cycle components. Unit 1 steam generator also utilizes 10 ppm boron to control corrosion. A steam generator volume released during the draining is approximately 32,000 gallons each.During wet lay-up the S/Gs are stored full of water with up to 400 ppm of hydrazine and 50 ppm ammonia or ETA are added for corrosion control.This water is normally drained to surface water via NPDES outfalls OOA or OOB, but may be drained to the TRS in some instances. The miscellaneous drain tanks can be aligned to discharge to the TRS.As much as 350,000 gallons per day may be directed to the TRS to control the"chemistry limitations on the secondary water systems.Water chemistry is primarily the same as steam generators. Around the plant miscellaneous sumps collect approximately 45,000 gpd of water from various equipment drains, leaks, pump seals, steam jet air ejector drains, etc.19c ~9 Additional Information Section I Item 6, Subpart A Cook Nuclear Plant Groundwater Permit Application WASTEWATER FLOW DIAGRAM 42 (cont.)The frequency of discharge and types of chemicals used in this equipment have been described elsewhere in this description. Miscellaneous floor drains are located throughout the plant to provide a safe working environment by routing spilled or leaked water to the TRS.The major chemical influx into these drains are from the detergents and waxes used to maintain the floors.Also routed to the TRS through the floor drains are the chemical feed tank drains, fire protection water, drinking water, cooling water, and drains from bioboxes used to monitor the zebra mussel control measures and other chemical control monitors.The chemical feed tanks which may be drained contain hydrazine, ammonia, boron, ETA, sodium hypochlorite. The bioboxes will discharge chlorine and, during zebra mussel treatments, zebra mussel biocides.Non-radiological chemical lab sink and floor drains are routed to the TRS for disposal.The drains carry water and the wastes generated while performing analyses and preparing laboratory standards including those on the attached list.Also discharged will be glassware and normal laboratory cleaning wastes.The average volume directed to the TRS is estimated to be 500-1000 gpd.Secondary (steam generator or condensate) sample water from continuous analyzers are routed to drains which discharge to the TRS.The analyzers are on the cycles which may contain as much as 10 ppm boron, 150 ppb hydrazine, 20 ppm ammonia, and 2.5 ppm ethanolamine. The analyzers measure corrosion transport at a average flow of 8500 gallons per day.Miscellaneous sealing and cooling water supplies cooling and sealing water to the TRS pumps, condensate booster pumps, circulating water pumps, vacuum priming pumps, drain seal reservoir tanks and drain sample coolers.The average flow per day is approximately 150,000 gallons.Non-essential service water supplies approximately 53,000 gpd of non-contact cooling water to various sample coolers throughout the plant's turbine building including the Conductivity Room and the Steam Jet Air Ejector sample points.Chemical spills that enter the TRS may be neutralized within the sump to prevent a discharge to the environment. The potential for spills to the TRS exists for the following chemicals with the proposed neutralizers listed: 19d , Additional Information Section I Item 6, Subpart A Cook Nuclear Plant Groundwater Permit Application WASTEWATER FLOW DIAGRAM g2 (cont.)Chemical Sulfuric acid Sodium hydroxide Sodium hypochlorite Hydrazine Neutralizer Sodium hydroxide Sulfuric acid Sodium thiosulfate NESW (lake water), Hydrogen peroxide Outfall OOE-Sanitar Waste Dischar es WASTEWATER FLOW DIAGRAM 43 Sanitary wastes are presently segregated and routed to two extended aeration package treatment plants.The existing equipment is designed to treat 50,000 GPD and the effluent from the sewage treatment plants discharge into one of the two seepage lagoons.The lagoons discharge into the groundwater with the ultimate disposition being Lake Michigan.The sludge removed from the sedimentation tank basins is taken to a local POTW for disposal or dewatered and stored as low level radioactive waste, as appropriate. Plant sanitary waste consists of shower and restroom facilities, janitor washbasins located throughout the plant non-radiological property.Kitchen wastes are generated from the plant cafeteria, the Energy Information Center and Training buildings. The chemistry training laboratory discharges to the sewage treatment plants via a limestone bed neutralization tank.The chemistry lab is used to train technicians on analyses performed in the plant.The discharge from the lab carries water and wastes generated while performing analyses and preparing laboratory standards including those on the attached list.A small photo lab in the training building uses (on a emergency basis)small quantities of hydroquinone to develop black and white pictures for plant use.The training building HVAC system also drains to the limestone bed.A radiography lab in the plant also discharges small quantities of processing chemicals for non-destructive testing in the plant.None of the products in the radiography lab contain critical materials or priority pollutants. All portable toilet wastes on the plant site are collected and discharged to the package plants.A biodegradable deodorant is used in the portable toilets.Sludge effluent waste may also be recycled through the plants to decrease the amount of sludge for processing when possible.19e

Additional Information Section I Item 6, Subpart A Cook Nuclear Plant Groundwater Permit Application WASTEWATER FLOW DIAGRAM 43 (cont.)Miscellaneous rinsing of waste receptacles and possible miscellaneous cleaning operations waste utilizing various detergents may be rinsed to the sewage treatment plants.Miscellanous Outfall WASTEWATER FLOW DIAGRAM 44 The main plant transformers on each unit are located within concrete berms.The berms are for spill containment should a catastrophic failure of a transformer occur.To protect against operational and safety concerns which stem from ponded water, these areas gravity drain to oil/water separators specific for each unit.Each separator is a below ground concrete basin designed to retain oil and release water to a series of drywells.Also discharging into the separators are the emergency diesel generator pit sumps.These sumps collect limited water and fuel oil (less than 500 gallons per year)from the emergency diesel generator room.Periodically, the oil/water separators are pumped clean to remove the accumulated oil for proper off-site disposal.The Security Diesel Generator Day tank has an overflow line that connects to the Unit One transformer deck catchbasin. Discharge to the catchbasin would only occur if the day tank were overfilled. Procedures and level indicators are used to prevent overfilling. CHEMICAL LAB ANALYSIS Additional Information Section I Item 6, Subpart A Cook Nuclear Plant Groundwater Permit Application PLANT CHEMISTRY LAB (to Outfall OOD)Chloride Fluoride Hardness Hydrazine Silica Oil 6 Grease pH Free Mineral Acidity Total Phosphorus Chemical Oxygen Demand Sulfate Nitrites Total Residual Chlorine ASTM D-512-81 (1986)ASTM D-1179-80 (1986)Standard Methods 413 B (1985)ASTM D-1126-80 EPA-600-4-79-020 Method 130.2 (1979)ASTM D-1385 (1983)ASTM D Power Water Analysis Manual CH-41 EPA-600-4-79-020 Method 413.1 (1979)ASTM D-1293-84 Standard Methods 423 (1985)ASTM D-1067-82 Method B EPA-600-4-79-020 Method 365.3 (1979)EPA-600-4-79-020 Method 410.2 (1979)ASTM D-516-82 Method A (1985)EPA-600-4-79-020 Method 375.3 (1979)Standard Methods 426 A (1980)Determination of Corrosion Inhibition by Calgon Corporation ASTM D-1253 (1986)Standard Methods (1980)TRAINING BUILDING LAB'to Outfall OOE)Boron Chloride Fluoride Haxdness Hydrazine Silica Oil&Grease pH Total Phosphorus Atomic Absorption Metals Ion Chromatography Westinghouse Chemical Analysis Procedure for PWR WCAD 7333 Rev.1 (1973)ASTM D-512-81 (1986)ASTM D-1179-80 (1986)Standard Methods 413 B (1985)~ASTM D-1126-80 EPA-600-4-79-020 Method 130.2 (1979)ASTM D-1385 (1983)ASTM Power Water Analysis Manual CH-41 EPA-600-4-79-020 Method 413.1 (1979)ASTM D-1293-84 Standard Methods 423 (1985)EPA-600-4-79-020 Method 365.3 (1979)Standard Methods 302B, 303A (1985)EPA-600-4-79-020 Method 215.1, 220.1, 242.1, 249.1, 273.1 (1979)Dionex System Operators Manual WASTEWATER FLOW DIAGRAM Pl MAKEUP PLANT'dditional Information Section I Item 6.Subpart A Cook Nuclear Plant Groundwater Permit Application Lake Township (Potable Water)Non-essential Service Water (NESW)Alum Addition Pre-filter Backwash 2x Day Aug.ee e Sodium Hypochlorite (IfNeeded) Retention Tank Blow Down I x Day Or As Needed Reject Water to Lake Michigan 001-002 Sulfuric Acid or llydrochloric Acid Addition Reverse Osmosis Carbon Filter Backwash 2 x Day Avg Or As Needed Acid/Caustic Rinse Chem Cleaning Biofouling Cleaning NESW water for seals Cation Resin Beds Regeneration Waste Degasifier NESW ca ater Neutralization Tat)k (Installed by 1-95)Mixed Beds Anion Resin Beds Caustic egene ration tvaste cid/Caustic Regeneration Waste Makeup Plant Water to Plant Services Turbine Room Sump Flow to OOD 'E OUTFALL'ooi OUTFALL~002 WASTEWATER FLOW DIAGRAM P2 OUTFALL 003 Additional Information Section I Item 6, Subpart A Cook nuclear Plant Groundwater Permit Application Unit 2 Misc.Cooling Unit 2 Discharge Intake Forebay Unit 1 Discharge Unit 1 Misc.Cooling Dye Checks Heat Exchangers Sample Coolers Units IP.2 SJAEs Drains Cleaning Waste Bioboxes Unit-2 Condenser Unit-2 ESW Unit-2 Steam Generator I I NESW i Makeup Plant Flow Diagram tt l Unit-1 Condenser Unit-1 Steam Generator Unit-1 ESW Dye Checks Drains Cleaning Wastes Bioboxes In-linc Monitors Misc.Drains Layup Drains U-2 CCW DJW Makeup Plant Regeneration Wastes (An.i)Plant Heating Boiler U-1 CCW DJW In-line Monitors Misc.Drains Layup Drains Chem Feed Tank Drains Barrel Rinse Neutralization Tank Installed By 1-95 Misc.Plant Sumps Non-rad Lab Drains Misc.Floor Drains Turbine Room Sump pH Meter Sodium Hydroxide Sulfuric Acid Misc.Processed Waste e.g.Glycol Auto Compositor How Meter Absorption Pond GROUNDWATER e WASTE WATER FLOW DIAGRAM 83 SEWAGE TREATMENT PLANT Additional Information Section I Item 6, Subpart A Cook Nuclear Plant Groundwater Permit Application Fire Protection (Frusbing and sassing wares is dirccscd so ssorsnwascr and/or groundwarcr). Lake Township Potable Water Supply Plant Site Sanitary Waste&Kitchen Waste Radiograph Processing Laboratory Waste Photo Lab Training Building Chemistry Lab Waste Training Building HVAC System Wastes Portable Toilet Wastes East Extended Aeration Plant Limestone Bed Neutralization Tank EIIlucnt North Outfall OOE SeepageTank South Outfall OOE SeepageTank Miscellaneous Rinsing Operations l I South Extended Aeration Plant Sludge Effluent gf Procegged) Sludge To a POTW To Groundwater

WASTE WATER FLOW DIAGRAM-4 DRY WELLS Additional Information Section I Item 6, Subpart A Cook Nuclear Plant Groundwater Permit Application Security Diesel Generator Day Tank Overfiow Unit 1 Main Transformer Deck Drains (Stormwater) Unit 1 Emergency Generator Pit Sump Unit 2 Main Transformer Deck Drains (Stormwater) Unit 2 Emergency Generator Pit Sump Unit 1 Catchbasin Oil/Water Separator Unit 2 Catchbasin Oil/Water Separator Unit 1 Dwells Unit 2 Dwells GROUNDWATER SEE INSTRUCTIONS QN REVERSE SIDE SECT1ON I NUMBER-~MI 00058 27EM 7 Ao PROVIDE A ttAP OF THE TREATMENT FACILITY UXATIOtb SCNlt6 Tl%LOCATION OF~DISCNARSE POINT(S)AIO OTIER INRR%TICN RGXKSTED ON REVERSE SIDE OF PAGEa LOCATION AIAP (See Attached Map)21 INSTRUCTIONS FOR COMPLETlt4 SECTION I ITEM 7 This form requires a location map of the treatment facility showing discharge point(s).ENTER THE PER4HT NUMBER IN THE BOX AT THE TOP OF THIS FOIa(.THE PERMIT Ias(BER CAN BE FOUNO ON THE FRONT PAGE OF YOUR EXPIRING PERMIT.If thlS IS a new Or nOt PreVIOualy Permitted faCIIlty, then leaVe blank and a number<<III be aSSlgned.ITEM 7 LOCATION MAP A.Provide a detailed location man of the treatment facility, showing the location of the discharge point(s)for all surface water and groundwater discharges, and all known supply and drinking water wells of adjacent properties to the facility.For both surface and groundwater discharge applicants, Indicate the location and Identlf Icatlon number of any groundwater monitoring wells relative to the facility which are currently being used by the applicant to monitor the groundwater. Also>Include the receiving stream, lake, or storm sewer and the streets and roads In the area.22 SEE INSTRUCTIONS ON REVERSE SIDE SECTION I NUMBER W MZ 0005827.EM 8 CONCEN TRATED ANIMAL FEEDING OPERATION Ae IQ VCU TE A COtCEIIIRATEO ANI FEEDIMI FJCILI (IF tO CONTItAK TO IIIII Q)Se MJSBI OF ACRES USED FOI COtFI%I%HT FEKDIMI?Ce IF 11%RE IS OPEN COIFI%1%NTe HAS A RtMFF DIVERSION AtO CONIROL SYSIEN MEN CONSTR'?(IF Mls CONTI'O ITEN 9)Ds WAT IS TI%IESIGN BASIS KR TIE CWiRK SYSTIH?C%CK NK OF 1%RUJRIMI AtO EHIER MJSER OF II&KB OF RAIN?lD me, 2II MXR SIOFII Q 25 YEA+2II MXR SIORII P OT%R (SPECIFY)~e~IICI%S IMIES~s~INC%S Ee WAT IS TIE MJ%ER OF AQKS OF CONmISUTIMI ERAIQGE?F>WAT IS TIE DESIGN SAFEIY FACBXI IOR THIS CONIROL SYSTEI(?~~~esses LJ~LJ Ae LIST lYPE OF ANINLs N/A~LJ L JITEIVI 9 TYPE NUMBER OF ANIMALS IN OPEN AND HOUSED.INE MENT Ill 4 I III 4Iel I 4IO I Bs GIVE'D%MJSBI OF 1HIS lYPE OF ANINIL IN OPEN COKIMJ%NTe Ce GIVE ll%MJSER OF THIS lYPE OF ANIIVIL IH MXISED IXtlFI%%NTe As LIST lYPE OF AHINALe Bs GIVE TI%MISER OF THIS lYPE OF ANItsAL IK OPEN%IF ll&%HT e Cs GIVE TIE MJSER OF THIS lYPE OF ANINL IH MXNED Ae LIST TYPE OF ANINLe Be GIVE TI%MJSER OF THIS TYPE OF ANINAL IN OPEN COIF IMJ%HTe Cs GIVE TI%MJSBI OF lHIS lYPE OF AHULL IN MNSED CCtF II8%HTe As LIST lYPE OF AHIHALs Be GIVE 11%MJSER OF THIS TYI%OF ANIHAL IN OPEN COtF1%%HTe Ce GIVE TIE MJSER OF'THIS lYPE OF ANIMAL IN MXSED Ae LIST lYPE OF ANINALe Bs GIVE 1HE MJ%%R OF lHIS lYPE OF ANINAL IN IXsEH CO%1%I%HTs Ce GIVE 11%MJmBI CF THIS lYPE OF ANINL IN INUSED COtF As LIST TYPE OF ANINLe Be GIVE 1%MJ%ER OF 1HIS TYPE OF ANINAL IH OPEN COIF I MJ%NTe Ce GIVE 11%MJSER OF'THIS 1YPE OF ANINAL IH MNSED CCH'Il&%NTs Ae LIST lYPE OF ANINALe Be GIVE TIE MJSBI OF THIS TYPE OF ANINAL IH QKH Ce GIVE THE MJSER OF THIS 1YPE OF ANINAL IN INUSED CCIF I%t%NT e Ae LIST lYPE OF ANINLs Bs GIVE TI%MJSER OF THIS lYPE OF ANIISL IN 0%N GXFIIBJ%HTe Ce GIVE 11%MJSKR OF THIS lYPE OF AHINAL IN MXISED COM-1%%HI'e 23 INSTRUCTIONS FOR COMPLETING SECTION I ITEMS 8 ANO'P.This form requires information about the design, size, and type and numbers of animals In a concentrated animal feedlot.ENTER THE PERMIT NHBER IN THE BOX AT THE TOP OF THIS FORM.THE PERMIT NIÃBER CAN BE FO(P4)ON THE FRONT PAGE OF YOUR EXPIRING PERMIT.If this Is s new or not previously permitted feel llty, then leave blank and n number vll I be assigned.I GENERAL INFORMATION Not all animal feeding operations are required to obtain NpoEs permits.Exclusions are based on sIte and occurrence of discharge. In particular, for animal feeding operations, the size cutoffs depend on whether or not pollutants sra discharged through n manmade device or by direct contact<<Ith the facility or animals.A facility for laying hens or brollers Is not required to have a permit unless It hns n liquid manure handling system or continuous overflow watering.Also, facilities which discharge only In the case of n 25 year, 24 hour storm event are not required to have a permit.ITEM 9-8 Give only the ares used for the animal confinement or feeding facility.Oo not Include.sny area used for growing or operating feed.~0 I ITEM 9-C V E Check"Yas" lf sny system for collection of runoff hss been constructed. Supply the Information under 0, E, and F to the best of your knowledge. ITEM IO-B ANO C'i to, g I'!Give the maximum nunber of each type of animal In open confinement or housed uri'er roof (either partially or total ly)which are held nt your facility for s total of 45 days or more In any l2 month period.I Use the following categories for type of animals: Slaughter Cattle-Feeder Cattle-Mature Dairy Cattle (milked or dry)-Swine (each weighing over 55 pounds)-Horses-Sheep-Lambs-Turkeys-Laying Hens I-Broi lars(Ducks I A permit ls not required unless the facility has s I lquld manure handling system or continuous overflow watering.ANIMAL FEEDING OPERATION means a lot or facility (other than an aquatic animal production facility)where tha following conditions are met: (A)Animals (other thnn aquatic animals)have been, are, or will be stabled or confined nnd fed or maintained for a total of 45 days or more In any I2 month period)and (8)Crops, vegetation, forage growth, or post-harvest residues ara not sustained in the normal growing season over anY portion of the lot or facility.Two or more animal feeding opertlons under cameo ownership nre n single animal feedIng operation lf they adjoin each other or If they use a ccnmon area or system for the disposal of wastes.ANIMAL UNIT means a unit of measurement for any animal feeding operation calculated by adding the following nunbersf The number of slaughter and feeder cattle multiplied by 1.0;plus the number of mature dairy cattle multiplied by 1.4;plus the number of swine veighlng over 25 kllogrnms (approximately 55 pounds)multiplied by 0.4;plus the number of sheep multiplied by O.l;plus the number of horses multiplied by 2.0.CONCENTRATED ANIMAL FEEDING OPERATION means an animal feeding operation which meets the criteria set forth In either (A)or (8)below or<<hlch the Director designates as such on s case-by-case basis.A.More than the nunbers of animals specified In sny of the following categories sre confined (REGARDLESS OF WHETHER A SURFACE WATER DISCHARGE EXISTS): t.I.I,OOO slaughter or feeder cattle.2.700 mature dairy cattle (whether ml lked or dry cows).3.2,500 swine each weighing over 25 kllogrnms (approximately 55 pounds).4.500 horses.5.I0,000 Sheep Or lambe.6~55,000 turkeys.7.I00,000 laying hens or boilers (lf the facility has s continuous overflow watering). B.30,000 laying hans or brollers (If the facility has s liquid manure handling system).9.5,000 ducks.10.I,000 animal units.B.More than the following nunbers and types of animals are confined (WITH SURFACE WATER DISCHARGE AS DESCRIBED BELOw': I.300 slaughter or feeder cattle.24 2~200 mature dairy cattle (whether milked or dry cows).3.750 swine each weighing over 25 kllcgroas (approximately 55 pounds).4.I50 horses.5.3,000 Sheep Or lambS.6.I6,500 turkeys.30,000 laying hens or brollers (if the facility has continuous overflow watering). 8.9,000 laying hens or brollers (lf the facility has a I)quid manure handling system)~9.I,500 ducks.IO.300 animal units."Either one of the following conditions are'mat: pollutants are discharged Into waters of the United States throuch a mamsade ditch, flushing systea or other similar mannada device (wmaenade" means constructed by man and used for the purpose of transporting wastes);or pollutants are discharged directly into waters of the United States<<hlch originate outside of and pass over, across, or through the facility or otherwise ccme Into direct contact<<Ith the animals confined In the operation. provided, however, that no animal feeding operation Is a concentrated animal feeding operation as defined above lf such animal feeding operatlcn discharges only In the event of a 25 year, 24 hour storm event.N0TE: The permittee shall continue<<Ith Section,ll and address Items I, 2, 4, and 5 on pages 3).33, and 35. SEE INSTRUCTIONS ON REVERSE SIDE SECTION I PERMIT~gg p p p 5827 EM 10 AO VATIC ANIMAL PRODUTION FACILITY tTEM't1 SPECIES OF AQUATIC ANIMALS PRODUCED AT THIS FACILITY As DO YOU OPERATE AN AXIATIC ANIHAL PRODUCTION FACILITY?(IF tfts CCNfltAE TO ITBI 12)Bs INDICATE TIE TOTAL tAtSER OF PON5s RACKHAYS AMI SINILAR STRÃllRES AT YOlR FACILITYs Cs IN)ICATK IN ltIICH CALENDAR tONIH tVtXItttI FEED1%OCQRIs D.MKR Tta TOTAL IANBER OF PlXtKIS OF POCO FKD IXRIm THIS As IS THIS SPECIE A HARN CR tXXD HATER SPECIE?g/p Bs GIVE THE t4VE OF THIS SPECIEs Cs MER TIE TOTAL HARVESTABLE HEIQIT OF THIS SPECIE PRODUCED BY THIS FACILITY PER YEAR IN RXMSs Ds MER TIE HAXItttI HEIGHT PRESENT FOR THIS SPECIE ttIICH HEXAD REPRESENT YMI 8ÃNL OPERATIONs As IS THIS SPECK A 1ARH OR COLD I%TER SPECIE B>>GIVE TIE WE OF THIS SPECIEs Cs EN1KR TIE TOTAL H4RVESTABLE HEIGHT OF THIS SPECIE PRmXD BY THIS FACILITY PER YEAR IN RXtOS>>De MKR TIE HAXItltI ttEIQIT PRESE%RR THIS SPECIE ttIICH HXAD REPRESENT YOUI tOAHAL OPERATIONs A, 15 THIS SPECIE A HARII CR GXD HATER SPECIE?g B~GIVE TIE NA%OF THIS SPECIEs Vn Cs MKR THE TOTAL NRVESTABLE NEIQIT OF THIS SPECIE F Ds ENIER THE tVUUtttt HEIGHT PRESENT FOR THIS SPECIE ISICH ICXU)REPRESENT VOIR NXHAL CPERATI ONs As IS THIS SPECIE A HARII OR CXD HATKR SPECIE?Bs GIVE TIE NttE OF THIS SPECIEs Cs ENIKR TIE TOTAL HARVESTABIE HEIGNf OF THIS SPECIE PtmXH)BY THIS FACILITY PER YEIR IN POQOSe Ds ENIKR TIE HAXI tM HEIGHT PRKSBIf FCR THIS SPECIE ttIICH lORD RERIESENT YON tCNNL OPERAT ION s As IS THIS SPKIE A HARtl CR COLD HATER SPECIE?Bs GIVE TIE N4%OF'THIS SPECIEs Ce MKR THE TOTAL NRVESTABLE HEIGHT OF THIS SPECIE PRQOUCED BY THIS FACILITY PER YEAR IN Pres Ds EHIKR TIE HAXIt%M IEIGHT PRESENT FCR THIS SPECIE tSIOI lORD REPRESENT YQR tCÃNAL OPERATIQls Ae IS THIS SPECIE A HAttI OR OXD HATER SPECIE?Bs GIVE TIE HttK OF THIS SPECIEs Cs ENfKR T%TOTAL tVUIVESTABLE HEIGHT OF THIS SPECIE PRCQXED BY TH S FAC TY Y N Ds ENTER TIE HLYItttt NEIGHf PRESENf FCR THIS SPECIE tttICH MXAD REPRESENT YNR tCRPAL OPKRATIONe INSTRUCTIONS FOR CCMPLETING SECTION I ITEMS 10 ANO I I This form requires infq{mation about the design, size, and type and numbers of animals In an aquatic anŽal production feel ll y.ENTER THE PERMIT NIA{BER IN THE BQX AT THE TOP OF THIS FORM THE PERMIT NIPBER CAN BE FOUND ON THE FRONT PAGE OF YOUR EXoIRING PFRMIT.If thlS IS a new Or nOt preVIOuSly pe{mitted faClllty, then leaVe blank and a nunber Will be aSSigned.GENERAL INFORMATION Not ail fish farmsare required to obtain NPOES permits.Exclusions are based on size and occurrence of discharge. For aquatic animal production facilities, the size cutoff5 are based on whether the species are wa{m~ater or cold water, on the production weight per year In harVeStabie POundS, and On the Zmqunt Of feeding In paundS Of fOOd IfOr COld~ater 5Pecie5).AISO~faCI litleS which discharge less than 30 days per year, or only durlno periods of excess runoff I for warm~ater fish)are not required to have a permit.coNcENTRATEQ AQUATlc ANIMAL pRQQUOTIQN FAQII,ITY means a hatcnery, tish fern, or other facility which contains, grows or holds aquatic animals In either Of the following cateaorles, or which the Director desianates as such on a ca5e-by-case ba515~A.Cold water fish species or other cold~ater aquatic animals Including, but not limited to, the Salmonidae family ot fish Ie.g..trout and salmon)In ponds, raceways or other similar structures ~bleb discharge at least 30 days per Year but doe5 not Include: I..Facilities which produce less than 9,090 harvest~eight kllograms Iapproxlmateiy 20,000 pounds)ot aquatic animals per year.2., Facilities which feed less than 2,272 kllograms (approximately 5,0QQ pounds)ot food during the calendar month ot maximum feeding.B.Harm~ater fish species or other warm water aquatic animals Including, but not limited to, the Amelurldae, Cet{achldae, and Cyprlnldae families ot fish (e.g., respectlveiy, catfish, sunfish, and minnows)In ponds, raceways, or other similar StruCtureS whlCh diSCharge at leaat 30 daya per year, but dOeS nat InClude: I.Closed ponds which discharge only during periods ot excess runoff.2.Facilities which produce less than 45,454 harvest weight kllog{ams{approximately 100,000 pounds)of aquatic animals per yea{', ITEN 10 B Give the total nunber of discrete ponds or raceways In your facility.. Under"other" give a descriptive name of any structure which 15 not a pond or a raceway but which results In discharge to waters of the United States.ITEN 10-D The value gIven for maximum monthly pounds of food should be representative of your normal operation. ITEN 11 8 The name of fish species should be proper, c{mtnon, or scientific names.ITEN Il C AND D The values given tor total~eight produced by your facility per year and the maximum~eight present at any one time should be representative of your normal operation. NOTE: The permittee shall continue with Section II and address Items I, 2, 4, and 5 on pages 31, 33, and 35.28 SECTION t MI 0005827 i TEM 12 LIST NAHE AND HAILING ADDRESS OF ALL PROPERTY$4ERS ALIACENT TO TIE TREATMENT FACII.ITY AND OR DISC%ROE/DISPOSAL AREAs See attached list.MAILING LIST OF ADJACENT PROPERTY OWNERS 29 SO MI0005827 Section I, Item 12 ADJACENT PROPERTY OWNERS EAST Interstate I-94 (Michigan Dept.of State Highways)SOUTH Lake Township c/o Gerald Wasko Township Supervisor 1410 Shawnee Road Bridgman, MI 49106 WEST Lake Michigan (State of Michigan and United States of America)NORTH Rosemary Beach 11-11-6800 0038-00-5 Tengerstrom, Eric H.;3415 S.59th;Cicero, IL 60650 0037-02-5 Tengerstrom, Eric H.;3415 Cicero, IL 60650 S.59th;0037-01-7 Merkel's Floor Covering, Inc.;8314 Scottdale Rd.;Berrien Springs, MI 49103 0037-00-9 Kraiss, Wilbur&Marilou;5004 S.Long Ave.;Chicago, IL 60638 I 0036-00-2 Temmel, Edward P.&Kathleen;9617 E.Shore Dr.;Oak Lawn, IL 60453 0033-00-3 Gilpin, Clark&Nancy;1005 E.60th St.;Chicago, IL 60637 0032-01-'5 Wittebort, Robert J., Jr.&Nancy H.;3180 N.Lakeshore Dr.;Chicago, IL 60657 0030-02-1 Meier, Paul&Louise G.;1357 Madison Park;Chicago, IL 60615 0028-01-8 Balka, Ronald A.&Janet M.;3334 Louise Dr.;Lansing, IL 60438 Section I, Item 12 ADJACENT PROPERTY OWNERS Page 2 11-110006 0002-03 0004-00 0004-04 0004-01 0004-02 11-11-0007 0013-00 0013-01 Michigan Dept.of Natural Resources; P.O.Box 30028;Lansing, MI 48909 Franklin Real Estate Co.;P.O.Box 2000;St.Joseph, MI 49085 Temmel, Edward P.;9617 E.Shore Dr.;Oak Lawn, IL 60453 Caparo, William E.6 Oyler, Kathryn E.;122 S.Ellsworth Pl.;South Bend, IN 46635 Rosemary Beach Corp.;c/o Secretary; 3415 S.59th St.;Cicero, IL 60650 Lake Charter Twp.;Shawnee Rd.;Bridgman, MI 49106 Lake Charter Twp.;Shawnee Rd.;Bridgman, MI 49106 0006-01 Indiana Michigan Power Company 0001-01 0004-01 11-11-0005 0029 0036-01 0027-00 0036-00 0036-02 11-11-0005-0002 01-6 11-11-0008 0041-00 0009-00 Lake Charter Twp.;Shawnee Rd.;Bridgman, MI 49106 Lake Charter Twp.;Shawnee Rd.;Bridgman, MI 49106 Technisand, Inc.;11833 Ravenna Rd.;Chardon, OH 44024 Ruff, Timothy W.;P.O.Box 504 Bridgman, MI 49106 Technisand, Inc.;11833 Ravenna Rd.;Chardon, OH 44024 Emery, Martin;Hopkins, Elwood J.&Mable N.;7499 Thornton Dr.;Stevensville, MI 49127 Indiana Michigan Power Company Bank of America Texas P.O.Box 650380 Dallas, TX 75265 Michigan Dept.of Transportation; Lansing, MI 48900 Franklin Real Estate Co.;P.O.Box 2000;St.Joseph, MI 49085

NARSULEX,'xQ (~iQ Ii MATERlAL SAFETY DATA SHEET Sulfuric Acid 1.PRODUCT AND COMPANY IDENTIFICATION .Product Name: Sulfuric Acid Formui: H,SO, Molec War Weight: 98.08 Chemical Name: Sulfuric Acid ghemlcai Family: Inorganic Acid~Su 7664-93-9~Synonyms: Sulphuric Acid, Oil of Vitriol, Battery Acid product Use: Used tn manufacture of fertilizers, explosives, other acids, metal pickling and petroleum processing. MARSULEX inc.111 Gordon Baker Road Suite 300 orth York, ONT M2H 3R1 (416)496-9655 MARSULEX Inc.40 Richards Avenue P.O.Box 5453 Nofwalk, CT 06856-5453 (203)8544300 EMERGENCY TELEPHONE NUMBER (800)263-9502 Prepared by MARSULEX Technical Section (416)496-4164.2.COMPOSITION/INFORMATION ON INGREDIENTS -Sulfuric Acid N n-Water I nt%by Wt.70-100%OM%CAS Number 7664-93-9 7732-186 3.HA2'ARD INFORMATION EMERGENCY OVERVIEW:/Oangerl Extremely corrosive. Causes severe burns.Reacts violently with water.Highly reactive and capable of igniting combustible materials on contact.Not flammable, but reacts with most metals to form explosive hydrogen gas./Sulfuric Ackl h a colorless to amber, dear to slightly cloudy, oily liquid.National Rre Protection Assochtlon (NFPA)Rating Hazardous Materials Identification System (HMIS)Rating RRE f 0 4 Extreme/Severe '3 High/Serous ~2 Moderate 1=Slight 0=Minimum W Water Reactive ectNe Date: Februay, 1993.Supefaedea: Februasy, 1990 MARSULEX MSOS 4010E Page 1 of 9 MATERIAL SAFETY DATA'SHEET, Sulfuric Acid 3.HAZARD INFORMATtON (continued) POTENTIAL HEALTH EFFECTS: Exposure Llmlts: Sulfuric Acid ACGIH (TLV)1 mg/m'TWA)3 mg/m'STEL) OSHA (PEL)1 mg/8 (TWA)In contact with the skin: Concentrated solution may cause pain and severe burns to the skin and brownish or yellow stains.Prolonged and repeated exposure to dilute solutions may cause irritation, redness, paIn and drying and cracking of the skin.ln contact with the eyes: Immediate paIn, severe burns and corneal damage which may result in blindness. C Inhaled: Mists and vapors may cause Irritation of the eyes, nose and respiratory tract.May cause Increased'ulmonary resistance, transient cough and bronchoconstrlctlon. Severe overexposure may result In lung collapse and pulmonary edema which can be fatal.Ingested: Severe burning and pain In the mouth, throat and abdomen.Vomiting, diarrhea and perforation of the esophagus and stomach lining may occur.Long Term Exposure: , Repeated exposure may produce erosion and discoloration of teeth.~l'lthough no direct link has been established between exposure to sulfuric acid, Itself, and cancer In man, the World Health Organization (WHO)International Agency for Research on Cancer (IARC)have concluded that occupational exposure to strong Inorganic acid mists containing sulfuric acid is carcinogenic to man, causing cancer of the larynx (the voice box)and, to a lesser extent, the lung.Exposure to any mist or aerosol during the use of this product should be avokied and, in any case, keep exposures below the occupational exposure limit for sulfuric acid.1 Corrosive effects on the skin and eyes may be delayed, and damage may occur without the sensation or onset of pain.Repeated overexposure may lead to contact dermatitis, may cause bronchitis with cough, phlegm, shortness of breath and emphysema, can cause chronic runny nose, tearing of the eyes, nosebleeds and stomach upsets.Strict adherence to first aid measures following any exposure Is essential. Existing Medical Conditions Possibly Aggravated By Exposure: Skin Irritation may be aggravated in Individuals with existing skin lesions.Breathing of vapors or sprays.(mists)may aggravate acute or chronic asthma and chronic pulmonary disease such as emphysema and bronchitis. Carcinogenicity Data: Although there are reports linking exposure to sulfuric acid to cancer, this product Is not classified by NTP (National Toxicology Program), not regulated as carcinogenic by OSHA (Occupational Safety and Health Administration), and has not been evaluated by IARC (International Agency for Research on Cancer)or ACGIH (American Conference of Governmental Industrial Hyglenlsts).(See also, Long Term Exposure). Effective Date: February, 1993 Supersedes: February, 1990 MARSULEX MSDS k010E Page 2of 9 NATU LEX, MATERIAL SAFETY DATA SHEET Sulfuric Acid 4.FlRST AID MEASURES Prompt removal of this material from contact with the body is of utmost importance. &TART FIRST AID AT ONCE.Precaution: Persons attending the victim should avoid direct contact with heavily contaminated clothing and vomitus.Wear impervious gloves while decontaminating skin and hair.In contact with the skin: Flush skin with running water for a minimum of 20 minutes.Start flushing while removing g contaminated clothing.If irritation persists, repeat flushing.Obtain medical attention IMMEDIATELY. Do not transport victim unless the recommended flushing period is completed or flushing can be continued during , transport. a, While the patient Is being transported to a medical facility, apply compresses of Iced water.If medical treatment must be delayed, Immerse the affected area in iced water.If immersion is not practical, compresses of Iced water can be applied.Avoid freezing tissues.Discard heavily contaminated clothing and shoes ln a manner which limits further exposure.Otherwise, wash clothing separately before reuse.ln contact with the eyes: Immediately flush eyes with running water for a minimum of 20 minutes.Hold eyelids open during flushing.If Irritation persists, repeat flushing.Obtain medical attention IMMEDIATELY. Do not transport~~victim until the recommended flushing period Is completed unless flushing can be continued during transport. Inhaled: Move victim to fresh air.Give artmclal respiration ONLY If breathIng has stopped.Give Cardiopulmonary flesuscltatlon (CPR)If there ls no breathing AND no pulse.Obtain rnedlcal attention IMMEDIATELY. Ingested: If victim ls alert and not convulsing, rinse mouth and give N to 1 glass of water to dilute materhl.If spontaneous vomiting occurs, have victim lean forward with head down to avoid breathing ln of vomitus, rinse f mouth and administer more water.IMMEDIATELY contact local poison control center.Vomiting may need to be Induced but should be directed by a physician or a poison control center.IMMEDIATELY transport victim to an emergency facility.Note to Physician: All treatments should be based on observed signs and symptoms of distress in the patient.Medical conditions that may be aggravated by exposure indude asthma, bronchitis, emphysema and other lung diseases and chronic nose, sinus or throat conditions. Severity of the bum is generally determined by the concentration of the solution and the duration of exposure.In the event of skin or eye contact, lmmedhte and thorough flushing is essential. Continued washing of the effected area with cold or iced water will be helpful in removing the last traces of sulfuric acid.Cream or ointments should not be applied before or during the washing phase of the treatment. 5.FIRE FtGHTING MEASURES F sh Point (method): Not applicable, product Is non-flammable utolgnltlon Temperature: Not combustible Rammabllity Limits In air(%): UEL Not applicable LEL Not applicable Effective Date: February, 1993 Superaed ea: February, 1990 MARSULEX MSDS fffetOE Page 3 of 9 MATERIAL SAFEIY DATA SHEET Sulfuric Acid 5.FIRE FIGHTING MEASURES (continued) Fire Extinguishing Media: For small fires use dry chemical or carbon dioxide.For large Ares, flood fire area with water from a distance.Expect violent reaction with water.Do not get solid stream of water on spilled material.Special Fire Fighting Procedures: Wear a NIOSH/MSHA approved selfwontalned breathing apparatus If vapors or mists are present and full protective clothing.For fighting fires In close proximity to spill or vapors, use acid-resistant personal protective equipment. Evacuate residents who are downwind of Are.Prevent unauthorized entry to Are area, Dike area to contain runoff and prevent contamination of water sources.Neutralize runoff with lime, soda ash or other suitable neutralizing agents (see Deactivating Chemicals, Section 6).Cool containers that are exposed to flame with streams of water until fire is out.Other Fire or Explosion Hazards: Not flammable but highly reactive.Capable of igniting finely divkled combustible materhls on contact.Reacts violently with water and organic materials with evolution of heat.Extremely hazardous.~in contact with many materials, particularly carbides, chlorates, fulmlnates, nltrates and picrates.Sulfuric acid reacts with most metals, especially when dilute to give flammable, potentially explosive hydrogen gas.Hydrogen gas can accumulate to explosive concentrations inside confined spaces.Follow approprhte NFPA codes.6.ACCIDENTAL RELEASE MEASURES Steps to be taken In the event of a spill or leak: Remove all ignition sources.Ventilate area.Use appropriate Personal Protection Equipment. Prevent liquid from entering sewers or watetways. Dike with inert material (sand, earth, etc.).Stop or reduce leak if safe to do so.Collect Into containers for reclamation or disposal only if container~r (s suitable to withstand the material.Conskler lnsitu neutralization and disposal.Ensure adequate decontamination of tools and equipment following dean up.Comply with Federal, Provincial/State and local regulations on reporting releases.=: " Deactivating Chemicals: Ume, limestone, sodium carbonate (soda ash), sodium bicarbonate, dilute sodium'hydroxide, dilute aqua ammonia.Waste Disposal Methods: Dispose of waste material at an approved waste treatment/disposal facility, In accordance with applicable regulations. Do not dispose of waste with normal garbage or to sewer systems.Note-Clean-up material may be a RCRA Hazardous Waste on disposal..-'Spills are subject to CERCLA reporting requirements: RQ=1000 lbs.7.HANDLING AND STORAGE Precautions: Wear appropriate Personal Protection Equipment. Do not breath sprays or mists.Do not Ingest.Do not get In eyes, on skin or on clothing.Keep ignition sources away from sulfuric acid storage, handling and transportation equipment. Handling Procedures and Equipment: Carbon steel or stainless steel materials are suitable for use for acid concentrations equal to or greater than 93%.However, the effect of lower concentrations on the materhls of construction can be very complex.Contact product supplier for specific recommendatlons when handling sulfuric acid at strengths less than 77%.Effective Oate: February, 1993 Supersedes: February, 1990 MARSULEX MSDS 4010E Page 4 of 9 NAILciULKK... MATERIAL SAFETY DATA SHEET Sulfuric Acid 7.HANDLING AND STORAGE (continued) Storage Temperature: Store above freezing point (Section 9).Elevated temperatures will Increase the corrosion/rate of most metals.Storage Requirements: Store packaged acid in a dry, well, ventilated location away from combustibles, oxkllzers, bases, or metallic powders.Storage tanks should be protected from water ingress, be well ventilated, and'aintained structurally in a safe and reliable condition. Other Precautions: Sulfuric acid will attack some forms of plastics and coatings.Always add acid to water-not g water to acid.If kept In upper floors of building, floors should be ackl proof with drains to a recovery tank.8.EXPOSURE CONTROLS/PERSONAL PROTECTION -'Recommendatlons listed in this section Indicate the type of equipment which will provkle protection against over exposure to this product Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific protective devices at your workplace. ~<Engineering Controls: Local exhaust ventilation required.spiratory Protection: A NIOSH/MSHA approved air-purifying respirator equipped with acid gas/fume, dust, mist cartridges for concentrations up to 10 mg/nf'.An air-supplied respirator if concentrations are higher or unknown.S)tin Protection: impervious (l.e., neoprene, PVC)gloves, coveralls, boots and/or other acid resistant protective ~clothing. Eye Protection: Tight-fitting chemical goggles and face shield./Other Personal Protective Equipment: Where there is a danger of spilling or splashing, acid resistant aprons or suits should be worn.Trouser legs should be worn outside (not tucked in)rubber boots.Safety showers and~eyewash fountains should be Installed in storage and handling areas.9.PHYSICAL AND CHEMICAL PROPERTIES h Physical State: Llqukf Appearance and Odor.Sulfuric acid Is a clear to amber, heavy, oily liquid which may have a sharp penetrating odor..Odor Threshold: No data Boiling Point: 77.67%:193'C(380'F); 93.19%: 276'C (529'F);98%: 330'C (626'F)Melting/Freezing Point: 77.67%:-11.2'C (+11.6'F); 93.19%:-29.5'C (-21.1'F); 98%:-1.1'C (30'F)Vapor Pressure at 40'C (102'F): 77.67%: 1.2 mmHg;93.19%: 0.0016 mmHg;98%:.0.002 mmHg Specific Gravity at 16'C (60'F): 77.67%: 1.7059;93.19%: 1.8354;98%: 1.8437 Vapor Density: (Air=1): 3.4 sulfuric acid component Bulk Density: Not applicable (see specific gravity)ffecthre Date: February, 1993 Supersede@ February, 1990 MARSULEX MSDS 401 OE Page 5 of 9 MATERIAL SAFETY DATA SHEET Sulfuric Acid 9.PHYSICAL AND CHEMICAL PROPERTIES (continued) Evaporation Rate: Not applicable /~.Solubility: Miscible In all proportions In water.Also soluble in alcohol.pH: 0.3 (1N solution at 25'C/78'F) 10.STABILITY AND REACTIVITY Stability: .~Under Normal Conditions: Stable, but reacts violently with water and organic materials with evolution of heat.Under Fire Conditions: Decomposes to form sulfur oxides(SQ). Conditions to Avoid: Temperatures which may have a negative effect on the materials of construction used ln equipment. Materials to Avoid: Contact with organic materials (such as chlorates, carbldes, fulmlnates and plcrates)may cause , fire and expiosions. Contact with metals may produce flammable hydrogen gas.When diluting, add acid to water.Do NOT add water to the acid.n Hazardous Decomposltlon or Combustion Products: Toxic gases and vapors (e.g.sulfur dioxide, sulfuric acid;vapors/mists and sulfur trloxkfe)may be released when sulfuric acid decomposes. Hazardous Polymerization: WIII not occur 11.TOXICOLOGICAL INFORMATION Toxicological Data:.Lox, (oral, rat)2140 mg/kg L+(inhalatlon, rat)=510 mg/nt'or 2 hrs Skin effects (rabbit): Severe irritation Eye effects (rabbit): Severe irritation Carcinogenicity Data: Although there are reports linking exposure to sulfuric acid to cancer, this product Is not.classied by NTP (National Toxicology Program), not regulated as carcinogenic by OSHA (Occupational Safety and Health Administration), and has not been evaluated by IARC (Intematlonal Agency for Research on Cancer)or ACGIH (American Conference of Governmental Industrial Hyglenlsts). See Section 3.Hazard Information, regarding Potential Health Effects (Long Term Exposure)for further discussion. Reproductive Effects: No information Is available and no adverse reproductive effects are anticipated. Mutagenicity Data: No'information is available and no adverse mutagenic effects are anticipated. , Teratogeniclty Data: No Information is available and no adverse teratogenIc effects are anticipated. Synerglstlc Materials: None known/Effective Oats: February, 1993 Supersedes: February, 1990 MARSULEX MSDS 4010E Page 6 ef 9 NIAII5ULKX,'ATERIAL SAFETY DATA SHEET Sulfuric Acid 12.ECOLOGICAL INFORMATION Ecotoxlc Effects: Harmful to aquatic life ln very low concentrations. Ijtiay be dangerous if it enters water Intake;Fish toxicity critical concentration 10 mg/L;7.34 mg/L/48 hrs-Lymneae Palustrls-0-100%mortality, 13.DISPOSAL CONSIDERATIONS ~Responsibility for proper waste disposal ls with the owner of the waste.Work with the appropriate regulatory bodies to ensure compliance with regulations. ~Consider the collection of residual sulfuric acid Into containers for reclamation or disposal only if the container Is suitable to withstand the material.~Conskler lnsitu neutralization and disposal.Clean-up materhl may be a RCRA Hazardous Waste on disposal.~Provincial/State or local regulations or restrictions are complex and may differ from Federal regulations. ~The information applies to the material as manufactured; processing, neutralizing, use or contamination may make the Information inappropriate, Inaccurate or Incomplete. 14.TRANSPORT INFORMATION U.S.(Under DOT)//Shipping Name: RQ Sulfuric acid Hazard Chss or Division: 8 Product Identification No.(PIN): UN1830 Packing Group: II Canada (Under TC)Shipping Name: Sulphuric acid Chsslficatlon(s): Class 8 (9.2)Product Identification No.(PIN): UN1830 Packing Group: II 16.REGULATORY INFORMATION.A.SARA Title III HAZARD CATEGORIES AND LISTS Pr H t rl Acute (Immedhte) Health: Chronic (Delayed)Health: Rre: Reactivity: t Sudden Release of Pressure: Yes Yes No Yes No~U Extremely Hazardous Substance (40 CFR 355, SARA Title III Section 302)CERCLA Hazardous Substance (40 CFR 302.4)Toxic Chemical (40 CFR 372.65, SARA Title III Section 313)Yes Yes Yes Effective Date: February, f993 Supersedes: February, 1990 MARSULEX MSDS 4010E Page 7 of 9 MATERIAL SAFETY DATA"SHEET Sulfuric Acid 15.REGULATORY INFORMATION (continued) Reportable Quantity (RQ)under U.S.EPA CERCLA: RQ=1000 Ib TSCA Inventory Status: Reported/Included /'~~aNaoa.Workplace Hazardous Materials Information System (WHMIS)WHMIS Classification(s): Class E-Corrosive Qass D1A-Very Toxic WHMIS Health Effects Index: Acute Lethality-very toxic-Immedhte Corrosive to animal skin WHMIS ingredient Disclosure List: Confirmed A;Meets crlterh for disclosure at 1%or greater.Reportable Quantity (RQ)under Transport Canada-, TDG: RQ=5 Iltres (or Kg)If It represents a danger to health, life, property or the environment. 16.OTHER INFORMATION Additional Information and References 1.Enviro-TIPS Manual,'Sulphuric Acid and Oleum", Environment Canada, February 1984.2.Weast, R.C.(Ed.),"CRC Handbook of Chemistry and Physics', 60th Edition (1980)3.Sax, N.l.,'Dangerous Properties of Industrial Materials', 7th Edition (1989)I 4.ACGIH, Threshold Umit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, 1991-92 5.Sittig, Marshall,"Handbook of Toxic arid Hazardous Chemicals and Carclnogens", 2nd Edition, 1985 Revision Indicators: g a ln the left margIn Indicates a revision or addition of Information since the previous Issue.Effectiv Date: February, 1998 supersedes: February, 1990 MARSULEX MSDS 441 0E Page 8 of 9 NARSULKX, MATERIAL SAFETY DATA SHEET Sulfuric Acid 16.OTHER INFORMATION (continued) Legend: CAS 8 CERClA CFR DOT EPA MSHA NIOSH PEL pvc RCRA SARA STEL TCTDG TLV TSCA'DNA UEL-Chemical Abstracts Service Registry Number-Comprehensive Environmental Response, Compensation, and Uabillty Act-Code of Federal Regulations -Department of Transportation -Environmental Protection Agency-The concentration of material in air expected to kill 50%of a group of test animals-Lethal Dose expected to kill 50%of a group of test animals-Lower Explosive Limit-Mine Safety and Health Administration -National institute for Occupational Safety and Health-Permissible Exposure Limit-Polyvinyl chloride-Resource Conservation and Recovery Act-Superfund Amendments and Reauthorlzatlon Act of the U.S.EPA-Short Term Exposure Umlt-Transport Canada-Transportation of Dangerous Goods Act/Regulations -Threshold Limit Value-Toxic Substances Control Act-Time-Weighted Average-Upper Explosive Limit The information contained herein has been prepared by MARSULEX Inc.and is offered only as a guide to the handling of this specific materhl and has been prepared In good faith by technically knowledgeable personnel. It Is not Intended to be all-Inclusive and the manner and conditions of use and handling may Involve other and additional conslderatlons. No warranty of any kind!s given or Implied and MARSULEX Inc.will not be liable for any.damages, losses, inJurles or consequential damages which may result from the use or reliance of any Information contained herein.EffecUve Date: February, 1993 Supersedes: February, 1990 MARSULEX MSDS 4010E Page 9 of 9

INSTRUCTIONS FOR CCMPLETI IIG SECTION I I ITEMS I AND 2 ThiS farm requires information on the facility's discharge additives. location, discharge schedule, volume f low rate and water treatment FNTER THE PERMIT NUMBER IN THE BOX AT THE TOP OF THIS FORM.THE PERMIT NUMBER CAN BE FOUND ON THE FRONT PAGE OF YOUR EXPIRING pEIa(IT.If this Is a new or not previously permitted facility, then leave blank and a number will be assigned.Enter the outfall number In space provided tor each page of sectIon I I.Far each Individual discharge point o separate set of Section Il forms must be filled out.ITEM I DISCHARGE LOCATION SCHEDULE AND FLOW RATES A.Enter the location of discharge, this should Include quarter-quarter section, quarter section, section, to n, and range.8.List nome of receiving water (If surface voter discharge). C.Indicate whether foci)Ity discharges on a seasonal basis.D.If yes, list discharge periods.Provide the land application rates used or expected to be used In terms of inches per hour, hours pec day.and Inches p<<w<<".F.Indicate the type of wastewater to be discharged fram this outfall.Refer to the wastewater type code given In the left margin More than one code may be applicable. G.Provide the average number of hours per day In~hich the facility discharges treated wastewater and the total number of days per year in whiah the d(SCharge OCCurS.H.Provide current (from the last l2 months)or expected flow rates os requested. Refer to unit code divan In the lett margin far the appropriate flow units.)sly-million gallons per year;MGD-million gallons per day;GPD-gallons pec doy.I.Provide the maximum discharge flow rate which you want to have authorized within the permit.NOTE: For NPOES permits on)Y.the use of such a flow rate will not place on actual limit restriction on the flaw but will be the flaw rote used to develop ettluent limits.Also, when the Monthly Operating Reports are reviewed by Compliance staff It will help thee to determine If any new or Increased uses might have occurred at the facility.J.Provide the design flow tor this specific outtall discharge (e.g.batch treatment system flaw, packaged treatment system flaw.or sane other finite treatment system flaw).ITEM 2 WATER TREATMENT ADO IT IVES A.Indicate~bather discharge Is treated with conditioners, Inhibitors, or mlcrobloclde. If not, continue to Item 3.B.Give name, function, and chemical composition of additives used.C.Give nome and address of the monutacturer(s) ot the additives used.D.Indicate expected minimis, overage and maxlcmxs discharge concentrations of the additive(s) tor this discharge. Indicate whether you treat the discharge to remove the additive(s) before discharge of wastewater. F.Indicate the removal efficiency of each additive from the wastewater ond the discharge frequency of each additive to the surface water or groundwater. G.hOTE: It Is the responsibility ot the applicant to supply the product Information as requested In this Item 4.Information requested but not supplied may result In the application being returned to the applicant for ccmpletlon. 32 SEE INSTRUCTIONS ON REVERSE SIDE SECTlON II PERMIT~~"Cl 4005827 lTEM OJIFNI.IlfKR As LOCATION OF DISCNRGE~~<s'5E e.$ErKfl I~05, 1M~><<, pA%E L11 5~B.IVY RECEIVING HATER (IE.GROLIEWATER OR IPVE OF SIRFACE BSOPTIONOND DISCHARGE LOCATION Cs DO YW DISCHARGE SEASWILLY.(IF IOs CCNTIIAE TO E)D.IF YESe LIST DISCNRGE PERIODS N/A IOe/DAY Q~QX~IOe/DAY FLOW RATE WASTEWATER Ee (AND APPLICATION RATE N/A INs IR>>~~LJ IRs DAY INs/NKe~~u~~'u KJ Nc(1 CONTACT COOUNG 2 NON CONTI(CT COOLING 3 PROCESS 4 SANITARY 5 STORMWATER Fe lYPE OF HASIEHATER DISCNRGE G s D ISOQRGE SOHlIE (YEARLY AVERAGE)Hs DISCHARGE FLOI RATE All time daily maximum times 365.TOTAL YEARLY DAILY HINIMPI DAILY NXIILPI 4 9 W ITj C0DE 0'2J 2.6~2 L3 L~J u W LJ LJ HG(RS/DAY 1 MGY 2 MGD 3 QPD ITEM Je HAXlKPI DESIGN DISCHARGE FLOI RATEe As DO YW USE HATER TREAllEHT ACOITIVES lO TREAT YOLR DI~(IF Ie.CCNTDAE TO IITH 3)Bs, Nt%FWCTIONe AID OEHICAL COSOSITICN OF TAESE AID IT IVES e DESIGN SULFURIC ACID SODIUM HYDROX 5-2 u~H Neutralization* I~TIE NXDSPI DISCNRGE FLOV RATE TO BE AIRICR IZED IN PBPIIT>>~6 WIT)OXK WATER TREATMENT ADDITIVES c.rwE ao mmnrm~~~SULFURI C ACID SODIUM HYDROXIDE 1 MQ/I 2 UQ/I MARSULEX, INC.111 GORDON BAKER ROAD, SUITE 30 NORTH YORK, ONT M2H 3R1 Ds EXPECTED DISCNRX COKENIRATION CF AIOITIVESe AcoITIYE wvE Sodium Sulfate ACOI TIVE KVE ACOI TIVE HA%E.DO YW TREAT lIE DISCHARGE lO ABOVE ACOITIVES? HAVILAND PRODUCTS COMPANY 421 ANN ST., N.W.GRAND RAPIDS, MI 49504 HIHIISJI WITS AVERAGE WITS NXDSPI WITS CXE aXE'0 1 3 0 0 1 1 5 0 0~1~s~s LJ;~LJs~LJ LJ'~M:~LJ F.l4KT IS lHE RBClVAL EFF ICIBCY AM)D ISONRGE PREOEHCY?N/A ACOI TIVE HA%ACOITIVE HA%ACDI TIVE HNE IRS s/DAY DAYS/HK>>LJ G AS AN ATTAtHsEHT lD THIS APPLICATIOI PROVIDE SPECIFIC NPRALIAN CR AQSLTIC lOXICOLOGICAL D(TA OI REFERENCE HHIOI ARE AVAILABLE AND INFNP(ATICN CN THE RATE OF DEGRADATICN OF lIE PRCOCIS FCR EKH ACOITIVEe MSDS attached.*Approximately instantaneous neutralization upon mixing-(New tank to be completed January of 1995 will ensure complete neutralization prior to discharge.) S1 MATERIAL SAFETY DATA SHEET SODIUM HYDROXIDE 50%ENDUSTREAL GRADE SECTION I-IDENTIFICATION MANUFACTURER'S NAME............ ADDRESS (STREET, CITY, STATE, Z IP)PHONE NUMBER e a>~s~~~~~~a~~~~~~s EMERGENCY PHONE NUMBER......... EFFECTIVE DATE................. TRADE NAME................ ~....CHEMICAL FAMILY..............-. Havi1 and Products Campany 421 Ann St., N.N., Grand Rapids, ME 49504 (616)~61-6691 CHKMTREC (800)424-9Z00 6/18/91 SOD I UM HYDROXIDE 50%INDUSTRIAL GRADE Alkali, Base SECTION I I-HAZARDOUS INGREDIENTS HAZARDOUS COMPONENTS OSHA/PKL ACGIH/TLV (Units)PROD.CAS N Sodium Hydroxide (Caustic Soda)(48.5-51.0% by wt)mg/m=TNA 2 mg/m~T4IA 1.10-73-2 Sodium Chl aride (0.8-1,.3%by xt)Mater (Balance)Nat Estab 1 i shed Not Established Nat Estab 1 i shed Nat Kstab 1 i shed 7647-14-5 77~F2-18-5 SECTION III-PHYSICAL DATA BOILING POINT~~~~~~~~~~~~~~a~~FREEZ ING POINT~~e~~~~~~~~~~~~VAPOR PRESSURE (mm Hg)........ VAPOR DENSITY (Air~i)......... SOLUBILITY IN H20............. APPEARANCE/ODOR a~~~~~~~~~~~~~~SPEC IF I C GRA V I TY (H20=1)......Ha~~~~~~~~~~~~~~~~s~~~~~~~~~~P.9~~F (145 C)60 F (15.6 C)1.5 C~20 C Na Enlormation Available Completely Cl ear, Color)ess liquid;Odorless 1~52 Not Established SECTION IV-FIRE AND EXPLOSION HAZARD DATA FLASH POINT..~..........-........... Nat Flammable LONER EXPLOSIVE LIMIT (%by Valume)Nat Appl icable UPPER EXPLOSIVE LIMIT (%by Volume)Nat Applicable EXTINGUISH MEDEA................... As far Surraunding Fires 07/.~0/1991 C'ATERIAL SAFETY DATA SHEET SODIUM HYDROXIDE 50/ENDUSTRIAL GRADE SPECIAL FIRE FIGHTING PROCEDURES... Wear NIOSH/MSHA approved sel f cantained breathing appar atus and f ul 1 protective equipment when this material is involved in a fire.UNUSUAL FIRE HAZARD........ ~.......En solution causti c can react wi th amphateric metals generating hydrogen which is flammable and/or e plosive if ignited.SECTION V-HEALTH HAZARD DATA CARCINOGENICITY............... None N TP~~~s~~~~~~~e~~~~~~~~~~~~~~~No I ARC~~~~~~~~~~~~~~~~~~~~~~~~~~no OVER EXPOSURE EFFECTS......... Redness of Exposed Tissues with possible burns r esul ting in deep ulceration. PRIMARY ROUTF (S)QF ENTRY..... Skin Contact FIRST AID PROCEDURES.......... If inhaled: Remove to fresh air.If nat breathing', give artif icial respiration, preferably mouth-to-mauth. If breathing is difficult, aive oxygen.Get medical attention. In case of contact: Immedi atel y flush eyes ar skin with plenty af water for at least 15 minutes while removing contaminated clothing and shaes.Get medi cal attent i an.Wash c)othing bef or e reuse.Ingestion: Do not induce vomiting.Ef canscious, dilute by giving several glasses of water.Call a Physician Immediately. EXPOSURE AGGRAVATED MEDECAL CONDITIONS None Currently Known SECTION VI-REACTIVITY DATA CHEMICAL STABILITY............ CONDITIONS TQ AVOID........... INCOMPATIBLE MATERIALS........ DECOMPOSITION PRODUCTS........ HAZARDOUS POLYMERIZATION...... POLYMERIZATION AVOID.......... Stable Nat App 1 i cab 1 e Acids None Current.l y Knawn Wi 1 1 Not Occur Not Applicable SECTION VII-SPILL QR LEAK PROCEDURE 07/~0/1991 I r MATERIAL SAFETY DATA SHEET SODIUM HYDROXIDE 50/INDUSTRIAL GRADE FOR SPILL~s~~~~w~i~a a><~~a~s~WASTE DISPOSAL METHOD......... Add non-reactive dry, absorbent such as diatomaceous earth.Shovel or sweep up and place in an approved DQT container and seal.Flush contaminated area and neutrali"=e with dilute acid.Dispose of spill,ed or waste product, contaminated soil and other contaminated materials in licensed landfill or treatment facility in accordance with all federal, state and local regulations. SECTION V RESPIRATORY PROTECTION....... VENT I LAT I ON~~~~~~~~~~~~~~t o~~PROTECTIVE GLOVES............ EYE PROTECTION............; ..QTHER PROTECTIVE EQUIPMENT... HANDLING AND STORAGE......... III-SPECIAL PROTECTION Supplied air or sel f contained breathing apparatus with full face piece.To maintain vapors below limits.Rubber or other impervious materials. Chemical splash proof goggles.A safety shower and eye bath should be available. For operations where spills or splashing may occur, use an impervious body covering and boots.Store in cool, dry, well ventilated area.Keep containers closed when not in use.SECTION IX-SPECIAL PRECAUTIONS HA Z ARD CLASS~~~~~~~~~~~~~~~~DOT SHIPPING NAME........... VN NUMBER e~~~~~~~~~~~~~~~~~~REPORTABLE QUANTITY (RQ).'...Corr osi ve Material SODIUM HYDROXIDE, LILDUID UN1 824 2000 lbs.REFERENCES HMIS: H-3, F-O, R-1 SQDHYDOX 07/0/1991 SEE INSTRUCTIONS ON REVERSE SIDE SECTlON I I PERMIT~IYI1 00005827 NUMBER rEM 3 Ae NctE OFY PROCESS CotnRIBUTINI TO 1NE DISOIARGE ltttOUGH lNIS OUIFAU.At@SIC CODE B, PROCESS SCHHXLE (YEARLY AVERAGE)OOD STM LECT thorn/DAY~4 491~65 PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE c/t M cct OY 0 cc Ce PROCESS HASTKHATER FIDH RATE See various contributing waste streams in Section j.6.A De PROCESS PRODUCTION RATE N/A A.tUYE 0F PRocEss coNIRIBUTI% To TIE DIGQccRGK N/A TNOIXiH 1NIS OUTFALL ANt SIC CODE TOTAL YEARLY DAILY HINltttl DAILV HAXItXH 1 1 1.3 5 4 w~~T5jl.090~6.683~6 WITS/TIIE 1 POUNDS 2 GALLONS 3 CUBIC YARDS 4 TONS 5 MGY 6 MGD 7 GPD TIME 1 HOUR 2 DAY 3 WEEK 4 MONTH 5 YEAR Be PROCESS SCIEDIXE (YEARLY AVERAGE)c/t Ce PROCESS HASTEHATER FUXI RATE O01 0 D.PROCESS PRODUCTION RATE A NAtE OF PRXEss cotnRIBUTING To TIE DlsctFIRGE N/A TIRCXXIH 1NIS OUIFALL AtQ SIC CODE Be PROCESS SCIEDIAE (YEARLY AVERAGE)Ce PROCESS HASTKHATKR FUXI RATE D.PROCESS PRODUCTION RAlE A.NAtE OF PROCESS CenRIBUTING To TIE DISCHARGE N/A AtD SIC CXXIE Be PROCESS SCIEIXLK (YEARLY AVERAGE)PROCESS tcASTBaTER FIDH RATE De PROCESS PRNXX,TION RATE A.IIAtE DF PROCKss cottmrBUTING To TIE DlscHIRGK N/A TI%GLXIH 1NIS OUIFAIL AND SIC CCCE Be PROCESS SctHXLE (YEARLY AVERAGE)c/t C, PROCESS HASTBtCTER FtlH RATE OcO 0 De PROCESS PROIXCTION RATE Uses/oev~oevs/vsse TOTAL YEARLY, DAlLY HINWPI DAILY HAXIIXH TOTAL YEARLY DAII.Y HININPI DAILY HAXIHH TOTAI.YEARLY DAlLY HINItSPI DAILY HAXItCPC IOUII/SSY~OSYS/YYSS TOTAL YEARLY DAILY HINIIMI DAILY&XI tXPI WITS/TIHE WITS XTIHE IHIT CODE Wlls~It%WIT CODE LL UNITS~TltE INSTRUCTIONS FOR COMPLETING SECTION I I ITEM S Tt Is form requires Information on the process streams<<hlch contribute to this discharge. ENTER THE PERMIT NLSIBER IN THE BOX AT THE TOP OF THIS FORM.THE PERMIT NISIBER CAN BE FOUNO ON THE FRONT PAGE OF YOUR EXPIRING PERMIT.I f this Is a new or not previously permitted facility, then leave blank and a number<<ill be assigned.Enter outfall numaer in space provided for each page of Section II.For each Individual dlscharoe oint a seaarate set of Section II forms must be filled out.PROCESS STREAMS CONTRIBUTING TO OISCHARGE: FOR EACH SEPARATE PROCESS PROVIDE THE FOLLOWING INFORMATIO'I A.Enter the name of the process<<hlch contributes to this discharge. Also provide the proper SIC code.B.Indicate the yearly average process schedule Jn hours per day and days-per-year. C Provide the process<<aste<<ster flow rate information as requested based on your last I2 months of operations. Refer to unit code given in the left margin for the appropriate flaw units~0.Process Production Rate-Certain permit limitations may be based on production rates.The production rates used to determine permit limits shall be represented by a reasonable measure of actual production of the facility, such as the production during the high month of the previous year, or the monthly averaqe for the highest of the previous five years.or other reasonable measure as stated In applicable U.S.E.P.A. categorical rules and regulations. For new sources or new dlschargers, actual production shall be estimated using pro]ected production. Record your production rates In the terms and units used in the applicable U.S.E.P.A. categorical rules and regulations for your type of facility.34 SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I PERMIT~IeIT 0005827 NUMBER E EM GROUNDWATER DISCHARGE INFORMATION Ae IS THE DISCHARGE FROM 1HIS OUTFALL DIRECIKD TO lHE GRIXNO OR GROINDIATKRS?(IF tOP CCttfltAE TO ITBI 5)B.HAS A HYDROGEOLOGICAL STUDY OR ITS EQUIVALENf BEEN PKRFORtED OR IS TIMBRE SIFFICIKNT CURRENf HYKROGEO)re ICAL INFORHATION AVAILABLE g REOIRKD@V~HATER REQXE2CES THIS EXISTI%OR PROPOSED DISCHARGE) IF YES AlTACH A COPY CF THE REPORTS Ce ARE YOU~RSTIHj AN EXKHPTICN FIKtl SIKPHTfltti A HITROGKOUXIICAL REPORT INOKR RULE RPX5e22II (Q(PAGE 56)OR FlKtl GRONDQTKR tSNITORItts gEOUIRBKNIS INDER RULE R.ZSP (5)(PAGE IIZ)OF TIE PART 22 RULES~IF YES ATTACH DOCLNKNTS AN)EXPIANATION TO DBSNSTRATK THAT YOLR DISCNRGE tEXAD OUALIFY FOR AN EXEtls ION.De ARE YOU REQLESTIt6 A VARIANCE FRAN RtaK 323e2205 (PAGE 99 (tDNDKGRADATICN) OF TIE HATER RESIXNCES CCEfll SS ION PART 22 GRtXSDQTER R1LES2 IF YES ATTACH SIKH DOCU5BIIS AS NECESSARY TO DQQNSIRATE TIE NEED FCR A VARIANCE IN TKPNS OF TIE cRllKRIA$PEclFIED IN RIAE 5Dei210 (PAGE0F THE PART 22 RIAKs~~OD C~I YES tO g Re Report Submitted 12/6/91 LITEM 5 EXPECTED WASTEWATER CHARAC UNETS CODE 1 Mg/I 2 Ug/I 3 COUNTS/100 ml 4 S.U.5 F S LBS/GAY TIE APPLICANI'AY BE RECUIRED TO DO AIXIITICIAL HASTE ANALYSESP A e DISCHARGE CHAIIACTKR I ST I CS CONC BIIRAT I ON QX NOT APPLICABLK/BELIEVED ABSBIT RtKSENTP DATA PROVIDED IN l781 7 CI INITS CCOE 0 ANALYSES CODE BOO5 (F IVE DAY B IOCteI ICAL OXYGEN DKHAte)'COD (DeIICAL OXYGBI DKHAND)'TOC (TOTAL ORGANIC CARBCN)~5,~0 , L00I AttsNIA NITROGBI (AS N)TOTAL SUSPEMKD SOLIDS TOTAL PteSPICRUS (AS I)TOTAL RESIlll4L OLORINE DISSOLVED OXYGEN HIN~.LJ~0.~02 0.~08 PLJ u>~52 FECAL COLIFCRH BACTERIA'nmaaTIEIK (SIPtER)TBFERATINE (HINIER)LLJ~LJ LJ~~LJ Be OTIBR HASTEHATER OIERACTERISTICS u>LJ5 LJ Ee I IST ALL Cte)ICAL SISSTAtCES lIHIDI ARE IN NICHIGAN S CRITICAL HATKRIALS REGISTER TAKE IV cPAGE II)ANWOR U S.EPA S PRICRllY RXLUfANT LIST TARE V (PAGE 7)OR ANY OIIER SLBSTAtCES MICH ARE OI HAY BKO%IMRIOUS TO TIE KESIGNATKD USES OF TIE GIXNDN8eTKR CR TO 7%PUKIC tEALTH THAT ARE DISCHARGED OR EXPECTED TO BE DISCNRGKD TQ TIE GRIXNDIATBL7IY 1HIS FACILllYe ESTIHAlK THK FINAL EFFUENT COMXNIRAT ION AND REQRD ALL DATA IN ITBI 7 OF SECflCN II IN 1HIS BOOIUTP~SAWP E JXBF 1 GRAB 2 24 HOUR COMPOSITE 0 I L 8 G R E A S E LCHLORI DE<ULF ATE LT;OETA L I L~10, E99e~80, I00I 0208~195, 0 1 0;2 0~58 2 925 ,~0~8~0~0~1~52 1~52~1 6 1 u'LJ 2~2 LJ LJ~LJ LJ RECUIRED ItAAQTIIN RN St%FACE HATER DISONRGESP Analyst.s per J.B.Beauboeuf, Target Permit Effluent Limits List. INSTRUCTIONS FOR CCMPLETING SECTION I I ITEMS 4 ANO 5 This forpp requires Information on a specific outfal I discharging to eIther the groundraters or the surface~aters.ENTER THE PERMIT NPIBER IN THE BOX AT THE TCP OF THIS FORM.THE PERMIT N(D(BER CAN BE FOUND ON THE FRCNT PAGE OF YOUR EXPIRING PERMIT.If thlS iS a ner Or nOt preVIOuSly permitted faCI llty, then leaVe blank and a number Will be aSSlgned.Enter the outfall number In the sDace provided for each page of Section II.For each Individual dlscharoe point a se arete set of Section II forms (Iteypps 4 and S)mu5t be filled out.ITEM 4 GROUfd)WATER DISCHARGE INFORMATION (DO NOT INCLUDE DEEP WELL INJECT(Off INFORMATION IN THIS ITEM)A.-O.The aDDlicant shall address each of these parts lf the discharge frcm this outfall Is to the oroundwater. ITEM 5 EXISTING OR EXPECTED (FOR A NEW DISCHARGE) WASTEWATEP. CHARACTERISTICS OF GROUNDWATER OR SURFACE wATER DISCHARGE (00 NOT INCLUDE w LL INJ I IN I N H A.The applicant shall report available discharge data (real data for existing discharge or expected data for a proposed discharge) for the parameters as listed.These parameters shall be addressed for either a surface water discharge ot as aDDroDrlate for a groundwater discharge. For assistance In determining appropriate parameters a groundwater dlscharoe appl leant may contact the Groundrater Qual lty Division, Permits Section or the appropriate Groundrater Quality Olvlslcn's District off ice.The apDI)cant shall report the sample type code best describing each reported place of data.See coding on the left margin of this form.If this outfall Is a surface water dlscharqe, the applicant must report quantitative data for each parameter Identified b an h pp y, o p tt p d h o d p t~b~, o h eo Pt tb ppotdby ded I tl\, hbe h d Pt tto4Mtt thl opll tl B.If data Is available for other parameters not lIsted above In A.or other parts ot this application the applicant should report that data In the blank space5 provided In this part.NOTESl I.Unit code5 tor parmppeters reported In parts A and B can be found on the lett hand side of this form.2.Grab sample shall be used to analyze for pH, temperature, total phenols, residual chlorine, oil and grease.and fecal coliform In a surface water discharge unless other frequency-sample type analyses are available. See Glossary (page 48)for detlnitlon ot grab sample.3.24-hour composite samples shall be used to analyze for Total BQos, coo, Toc, Anmonla Nitrogen, and Total Suspended Solids In a surface water discharge unless other frequency-staple type analyses are available. See Glossary (page 48)for detlnltlon of'composite seppple.4.REPORTING OF INTAKE DATA.You are not required to report unless you rlsh to demonstrate your ellglbl llty for a unct" etfluent Ilmltatian tOr One Or mOre POllutantSP that IS, an effluent llmltatlOn adjuated by SubtraCtlng the average level of the pollutant(s) present In your Intake~ater.NPDES regulations allow net limitations only In certain clrcumstance5. To demonstrate your eligibility, report the average of the results of analyses on your Intake water (If your rater is treated before use, test the water after It Is treated), and attach a 5eparate Sheet containing the following for each pollutant: la)A statement that the Intake~ater Is drawn from the body of rater Into which the discharge Is made.(Otherwise, you are not eligible tor net limitations.)(b)A statement ot the extent to which the level of the pollutant Is reduced by treatment of your wastewater.(Your limitations will be adjusted only to the extent that the pollutant is not removed.)(c)When apDIlcable (for exsnple, when the pollutant reDresents a class of ccmppounds), a demonstration ot the extent to which the pollutants In the Intake very physically, chemical ly, or biologically from the pollutants contained In your dIscharge.(Your limitations will be adjusted only to the extent that the Intake pollutants do not vary from the discharged pollutants.) 5.If you have tro or more substantially Indentlcal outtalls, you may request permission fran your permitting authoritv to sample and analyze only one outfall and submit the results of the analysis for other substantially Identloal OutfallS.If yOur requeSt IS granted by the permitting authOrlty, On a Separate Sheet attaChed tOethe application form Identify which outfall you did test, and describe why the outfalls rhlch you did not test are SubStantlally IdentlCal tO the Outfall rhlCh yOu did teSt.36 SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I PERMIT~IYIX QO Q 58 27 NUMBER ODD EM 6 PRIORITY POLLUTANTS AND ADDITIONAL INFORMATION FOR SURFACE WATER DISCHARGE ONLY THE FQLIQtl%REQUESTED 1%'ORHAT ION~r ADQIESSED~MIFACE HATER DI SCHARGERS~IDIEt NEW USE DISOQRGERS Q5U.PROVIDE EXPECTED VALI FOR THE QUANTITATIVE AMD QUALITATIVE INFORMATION RECITED BEIQte AI IS THIS FACILllY A PRIWVIY INDUSTRY?(REFER TO TABLE IA PAf<g3 (IF%,GOTOK)(IFYS GOTOB)BI INDICATE TYPE OF PRIMARY INDUSlRY AS LISTED IN TABLE IA PAGE gl.(CONTINUE WITH C.)CI DOES THIS OUTFA!L DISCHARGE CONTAIN ANY PROCESS'HASTEHATKR?(IF NQ, GO TO E)(IF YESi GO TO 0)DI INDICATE lHICH GC/HS FRACTIONS HUST SE TESTED FOR I (REFER TO TABLE IA PAfK III)IDIKI FOR FAOI GC/HS FRACTION CHECKEDs EACH SPECIFIC ORGANIC TOXIC POILUTAttf HITHIN EACH FRACTION IBISI BE ANALYZED FOR (SEE TABLE IIA PAGE 02, IN ADDITION, AIL PRll@RY INCUSTRY APPLICANTS WITH A PROCESS WASTEHAlKR DISOIARGE Qff PROVIDE QUUITITATIVE DATA FOR EACH TOXIC POLUITAMT IN TABLE II IA PNK 99 I RECORD ALL DATA OM FOILS PROVIDED (ITKH 7)IN THIS SOQKLETI (CXITItttE HITH E-K BEilH)E~IF~QIIFACE HATER DISCHARGE APPLICANT (PRIMARY OR SECCNDUIY INDUSTRY)s REGARDLESS OF THE TYPE OF DISCHARGE Kttlts CR NS REASON TO BELIEVE THAT ANY PIXLUTAMT LISTED IN TARE IIA AND IVA PAGES~IS DISCHARGED FRCH ANY CIIFAL41tE QUUITITATIVK DATA~SE PROVIDED+RECXID ALL DATA ON FNttS PROVIDED (ITKH 7)IN lHIS BOOKLETe STM LEC WR X YES NO Q~nu Analysis per Q J.B.Beauboeuf Target Permit Q~m Effluent Limits Q PESTICIDE%T APPLICABLE/BELIEVED ABSENT N/A Fa IF ANY QRFACE MATER DISCHARGE APPLICAMf (PRINRY OR SECCNDUIY IMXISTRY)a REGARRESS OF TYPE OF DISOIARGG K%ws OR HAS REASQI TO BELIEVE ANY POLUITAMIS LISTED IN TABLE VA PACk+ARE DISCHARfkD FRCtt ANY OUTFAlL TIE APPLICANT~H DESCRIBE RFASONS FOR TIE PCLUTAMT BE1%PRESENT A%PROVIDE AMY AVAILABLE QUAMflTATIVE DATA'ECORD ALL DATA OM F<AS PROVIDED (ITKH 7)IM THIS SOQIGEfo G>>AIL QRFACE HATER Dl SCNRGE APPLICANfS (PRIMARY A%SECCNDARY IIGXISTR I Es)OR ACTIIIES L tti f TRIQSIXIOPIE%XY ACETIC ACID (2s 4i 5 T)t TRloaoeeaae PROPANOIC Aclo (SILYKx, K ti, 5, TP)4, WgI~aagaOXY) KIHYL 2, 2-DIOSJXIOPROPICNAIK~(' 0, IrVTRIOLOIOPtENL (TCMPi OR HEXAOLOROPIENE tHCPRI (AU DATA FCR TIE ABOVE tKIST BE GENERATED US I%STA%ARD ANALYf ICAL CALISRATICN PROCEDQIKS) OR KRIS OR HAS REASON 10 BELIEVE THAT TCCD IS OR HAY BE PRESENT IN TIEIR DISCHARGEo ~REPORT tXIALITATIVK DATAe GKIERATKD l43ICH USED A SCREENING PROC6XIIE KIT CALIBRATED HITH ANALYTICAL STAIKARDSi FOR 6 A/8i-TKIIIAOEOIROISEKKPP DIOXIN (TCCD)>>REIXII AIL DATA OM FOES PROVIDED (ITKH k)IN THIS NOKLETI J I IF TIE QRFACE HATER DISOIARGE APPLICANT KM'R HAS REASON 10 BELIEVE 1HAT BIOUXilCAI TOXICITY TESTS HERE HADE IN 1HE LAST TIRKE U)YEARS ON AMY OF TIE APPLICANT S DISCHARGES CR ON A RECEIV1%HATER IN RELATION 10 A DISCHARGE PROVIDE lHIS IWÃHATION AS Att ATTAOtENT TO THIS APPLICATIONe KI IF A COMIRACT LABORATORY OR CONQLTI%FIRN PERFOR%D ANY OF TIE AIKAYSES REQUIRED BY 1HIS APPLICATION PROVIDE TIE Nt%AND AIXRESS OF EACH IABORATCRY OR FIRI A%THE AIQLYSES PKRFQttED AS AM ATTACHMENT CF THIS APPLICATICNI LI DQ YOU DISCHARGE Ath'THER TOXIC OR INtIRIOUS DKHICAL QSSTAMCES MT LISTKD IN TARES IV PAGE D AlO IIA llttCAl VA PtV4S~~I IF YESs TAN IDENTIEY TlE OellCAL SUBSTANCES AMD ESTIWLTK TIE FINAL EFFUEHT CCNCENIIIATIOISI SIKFIIT THIS ItAAIATICN AS AN ATTAOtENT TO 1HIS APPLICATION>> %T APPLI CABLE/SELI EYED ABSENT N/A PRESENf/DATA IS AlTACHED Q NT APPLICABLE/BELlEVKD ABSENT N/A Q PRESENf/DATA Is ATTAOED g%T APPLICABLE APPLICABLE/SKK ATTAQED Q%T APFLICASIZ g APPLICABIZ/SEK ATTAOIED QX%T APPLICABLE APPLICASLEJSKK ATTAQIKD 37 INSTRUCTIONS FOR CCMPLETING SECTION I I ITEM 6 This form requires Information on a specific outtall discharging to the surface waters.ENTER THE PEIBIIT NUMBER IN THE BOX AT THE TCP OF THIS FORM.THE PERMIT NIPIBER CAN BE FDNID ON THE FRONT PAGE OF YOUR EXPIRING PERMIT.If this Is a new or not previously permItted facility, then leave blank and a number will be assigned.Enter the outfall number In the space provided for each page of Section II.For each Individual dlscharqe point a separate set of Section I I, Item 6 forms must be fl I led out.PRIORITY POLLUTANTS AND ADDITIONAL INFORMATION ITEM 6 NOTE: If you have two or more substantially Indent)eel outfal ls, you may request permission from your permitting authority to sample and analyze only one outfall and submit the results of the analysis for other substantially Identical outfal ls.If your request Is granted by the permitting authority, on a separate sheet attached to the application form Identify which outfall you did test, and describe why the outfalls which you did not test are substantially Identical to the outfall which you did test.NOTE: 40 CFR Part I22.2l(g)(8), Friday, April I, 1983, provides for a Small Business Exemption from the reporting of quantitative data for organic toxic pollutants and toxic pollutants as required by Part I22.2)(g)(T)(ll)(A) or I22.2I(g)(7)(ill)(A). A.-C.These parts are selfwxplanatory and do not require further Instructions. Simply go through each parr and do as Indicated. and E.-J.0.Several Industrial categor lss and subcategories have been exempted fran submitting data on certain GC/MS Fractions (40 CFR Part l22, Vol.48, No.64, Friday, April I, l983, Notes I, 2, and 3).Review the following list to determine whether your teel lity qualifies to be exempt from reporting GC/MS (Gas Chrcmatogl aphy/Mass Spectroscopy) Fractions. Text l le Ml I Is Indust GC/MS Fract Ion Testing and ReportIng Exemptions -Al I tour GC/MS organic tractlons In the Greige Ml I Is Subcategory. -Pesticide fraction In all other subparts of this Industry'. Ore Mlnln and Oressl Indust-Volatile, base/neutral, and pesticide fractions In the Base and Precious Metals Subcategory. -Al I four GC/MS organic fractions in el I other subcategories of this Industry.Gus and Wood Chemicals Industr-Pesticide fraction in the Tall Oil Rosin Subcategory and the Rosin Based Derivatives Subcategory. Pesticide and base/neutral fractions in~II other subcategories of this Industry.Pul and Paper Industr-Pesticide fractIon In Papergrade Sulfite subcateqorles (subparts J and 0).-Base/neutral and pesticide fractions In Delnk Subpart 0, Dissolving Kratt Subpart F, and Paperboard from Waste Paper Subpart E.-Volatile, base/neutral, pesticide fractions In the BCT Bleached Kraft Subpart H, Semi-chemical Subparts 8 and C, and Honlntegrated-Fins Papers Subpart R.-Acid, base/neutral, and pesticide fractions in Fine Bleached Kraft Subpart I, Dissolving Sulfite Pulp Subpart K, Ground-wood Fine Papers Subpart 0, Market Bleached Kraft Subpart G, Tissue from Wastepaper Subpart T, and Nonlntegrated Tissue Papers Subpart S.Steam Electric Power Plant Industr-Base/neutral fraction In the Once Through Cooling Water, Fly Ash, and Bottom Ash Transport Water process wastestreams. 38 SEE INSTRUCTIONS ON REVERSE SIDE SECTlON I I ODD ppp5827.EM 7 CRITICAL MATERIALS TOXIC POLLUTJLNTS A, USE THIS DATA SHEEf TO RECORD IHFCRMATION AS RECLJIRKD IN;(OKCX APPROPRIATE BOX JOR ttIICH INFCRMATICN THIS DATA SHEET REPRESEMTSI) X 1 SECTION I I g ITEM MI GROLMXCLTKR DISOIARGE INFORMATION (PAGE 35)D D X 2.SECTION ll ITEM 6 PRIORITY POUJJTANfs IM SLRFACE lATER DlscttVYZ (PAGE 37)D~31 Bo BELOW: CRITICAL MATERIALS (TABLE IV)IN SLJLFACE HATBOX DISCHARGE (PAGE 3J))HAZARDOUS SUBSTANCES IN DISCHARGE Bo LIST ANY CRITICAL MATERIAL (TABLE IV PJGE 6)NOT ADD!ESSED IN SECTION ll ITEM 6 PRIORITY POLUJfAMTS !4IICH YLXJ ttOW OR HAVE REASON TO BELIEVE TO BE PRESENT IN TIP.DISCHLRGEs SEE REVERSE SIDE OF lHIS PAGE FOR FLJITIER DIRECTIONss X ler APPUcASE APPLICABLE (SEE BKLCtt)CC III'AI NLME OF CRITICAL MATERIAL CR PRIORllY POLUJTAMT Bo AVERAGE CCNCBIIRATIONJ SANTE lYPEJ It OF ANALYSES Ca HAXIISJI CONCBIIRATICN A!O MASS c H drazine 0 WIT CODE LJ LJ OF ANAl YSES WIT CXE NIT CODE IL III'UNITS CODE 1 MQ/I UQ/I LBS/DAY KG/DAY~AMP~LT 1 GRAB 2 24 HR.COMP.CC III's Qt%OF CRITICAL HATERIAL OR PRIORllY POLLIJTAMT BI AVKRJGE CCICEMTRATICNJ SANDIE TfPEJ tt OF ANALYSES CI MAXI JLH CCNCENIRATION AJO MASS A>>NA%OF CRITICAL MATBUAL CR FRICRllY RXLUTAMf B.AYBLAGE cctcKMIRATICNJ senz TYPE;1I DF ANALYSES Cs MAX IMP!CctCENllLAT ION At41 MASS AI NA%OF CRITICAL MATERIAL OR PRIORllY POLUJTANT BI AVERAGE COtCBIIRATICNJ QIANA lYPEJ 0 OF ANALYSES CI HAXItML COtCIDI!RAT ICN AJO MASS Ae QP%OF CRITIQL HATERIAL CR PRICRllY FOLUJTANT Bo AVERAGE CNCBIIRATILXIJ QPRE TYPEJ JI OF ANCLYSES CI MAX&PI CCNCENIIIATICN AtO MASS AI SV%OF CRITICAL tVLTERIAL OR PRICRITY POLUJTANT BI AVKRAGE CCNCENIRATIONJ QIANA TYPES 0 CF AMJLYSES C.HJNIJSJLCaLKMIILATICN AJO MASS A Nt%OF CRITICAL MATERIAL OR PRIOR llY POUJJTANT B.AVERAGE CONCBCIRATICNJ SAMPLE TYPE,'J OF ANALYSES C>>t%XIMPL CCCL'BIIRATION AtO HASS AI NAME OF CRITICAL MATERIAL OR PRIORITY FOUlJTANT Bo AVERAGE COMCKM!ILATIONJ SANTE TYPE J JJ OF ANALYSES CJXE WIT CODE LJ NIT OXE 54%LE TYPE F OF ANALYSES NIT CQJE SAINT lYPE OF ANALYSES LJ NIT CCOE WIT CCOE LJ~~~LJ LNIT CCCE~lYPE JJ OF ANALYSES NIT CODE NIT CODE LJ~~~LJ LJIIT CCOE QJPLE TYPE OF ANALYSES LJ WIT CODE WIT COCK LJ~~~LJ LJIIT CXXE QWlK TYPE OF ANALYSES LLLJ LJ WIT CODE LJIIT CODE LJ~~~LJ NIT CJXE~TYPE OF ANALYSES" Chlorine (Sodium H ochl!WLT CCXJE SAIFLE TYPE OF ANALYSES LJ NIT COX WIT COKE Cs MAXI'ctCBIIRAT ION AIO MASS WIT CODE NIT CODE LJ~~~LJ Hydrazine or Sodium Hypochlorite are not expected to be present in discharge but ACDITICNAL PJGES OF THIS ITEM 7 ARE ATTmm FOR TIB REST OF na CRITICAL Cl YES MATERIALS AJO/CR PRICRTIY POUltrAMTS RECUIRKD TD BE REPORTED.E NO small quantities may be found in the Turbine Room Sump but would not be expected to be found in the actual discharge flow to the absorption pond.39 INSTRUCTIONS FOR (XMPLETI IQ SECT ION I I ITEM 7 This form Is to be used by both surface and groundwater applicants to record Information on nny Hlchlgan critical mnterlnl, E.P.A.priority pollutant, or hazardous substance in which this application requires data to be provided.This would Include ony chemical substance trom the Michigan Critical Materials Register (Toble IV), the E.P.A.Priority Pollutant Listing (Table V), or Tables IIA-YA which Ilats Organic Toxic Pollutants, Other Toxic Pollutants, Conventlonnl and Nonconventional Pollutants nnd Hazardous Substances. ITEH 7 CRITICAL MATERIALS, PRIORITY POLLUTANTS AND/OR HAZARDOUS SUDSTANCES IN THE DISCHARGE Material I 2 3~..8 A.List the nome of the chemlcol substance (critical material, priority pollutant, or hazardous substance) frrmr Tables Iyy V ond IIA-YA as required In the box<<hlch you checked In A.l 3.above.Enter each chemical substancers,parameter number as listed In Tables IV, V and IIA-VA lf provided.8.Provide the average concentration of the chemical substance named in A.Indicate the sample type used nnd the number of analyses mode to provide the concentration data for the chemical substance named In A.C.Provide the maximum concentration nnd determine the mass loading of the chemical substance nrrrred In A.NOTESr I.It only one analysis was mode for a chemical substance then record thnt data as n maximus,value. It more than one analysis hos been mode tor a chemical substance then provide an average value of those analyses nnd the maxim'alue. 2.This Section II, Item 7, Data Sheet provides space for recording dntn for 8 chemical substances (Materials) ~Additional space for recording of data tor more thon 8 Materials can be made by making copies of this Item 7 Data Sheet as needed.It Is olso Important to use a separate set ot Onto Sheets for each applicable reporting requirement as listed In A.l-3.and for each outtall.Refer to the left margin for the code number representing the sample type used and the appropriate unit codes.40 Lockheed Analytical Services INDIANA MICHICAN POWER COIWPANY SAMPLE ANALYSIS SUIVIIVIARY PACKAGE FOR VOLATILE AND SEMI-VOLATILE ORGANICS, PESTICIDE/PCBS, CHLORIDE, NITRATE/NITRITE, SULFATE, FLUORIDE, CYANIDE, IVIETALS, AND MERCURY LOG-IN NUMBER: QUOTATION NUMBER: L1009 Q331 620 DOCUMENT FILE NUMBER: 1229485

bloc/rheed Environmenta/ Systems 6 Techcgeyfe~ Co Lockheed Analytical Services 975 Kelly Johnson Drive Las Vegas, Nevada 89119Q705 Phone: (800)361-0220 Fax: (702)361-6434 February 4, 1994 Mr.Rocky Beem Cook Nuclear Plant 1 Cook Place Bridgeman, Ml 49106 RE: Log-in No.: Quotation No.: Document File No.: L1009 Q331620 1229485 The attached data package contains the results of analyses on samples that were submitted to Lockheed Analytical Services on December 29, 1993.The samples were received at 5'C.

SUMMARY

ANALYSIS STATEMENT: Inorganics All ground water samples were received in good condition on December 29, 1993.All samples were analyzed within the method-specific holding times.The method blanks were free of contamination. All Internal Quality Control were within acceptance limits with the following exception: The matrix spike recoveries for barium and selenium were slightly outside of acceptance limits.The acceptable recovery of the Laboratory Control Samples supports that the analytical systems were operating within control limits.The reporting detection limit for nitrite was raised to 0.50 mg/L for sample S.Sewage Plant Eff.(L1009-4)due to interferences from chloride.Organics Method 8260 All calibrations and quality control criteria were met with the following exceptions: All samples were analyzed initially within holding times but failed surrogate recovery QC limits.The samples were reanalyzed one day beyond the method specified holding time and all samples met surrogate recovery QC limits.Tentatively identified compound searches were performed on all submitted samples.Only the reanalyses are reported. 0 COOK NUCLEAR February 4, 1994 PAGE 2 Method 8010/8020 All calibrations and quality control criteria were met with the following exceptions: The matrix spike and matrix spike duplicate precision for 1,1-dichloroethene exceeded the QC criteria although all percent recovery criteria were met.Data quality is not effected.Method 8270 All samples were extracted and analyzed within the method specified holding time.All initial and continuing calibration criteria were met.Bis(2-ethylhexyl)phthalate was detected in the method blank at 1.3 ug/L.There was no other contamination detected in the method blank.Percent recoveries for all surrogate compounds was within QC limits for all samples analyzed.A laboratory control sample (LCS)and laboratory control sample duplicate (LCS DUP)was prepared and analyzed with this set of samples.The percent recovery criteria for all spiked compounds was within the QC limits as was the relative percent difference between the two.The response for bis(2-ethylhexyl)phthalate in sample TRANS.CATCHBASIN exceeded the calibration range in the initial analysis.The sample was reanalyzed at a dilution of 1:4 and all compounds fell within the calibration range.Both sets of results are reported.Method 8080 All samples were extracted and analyzed within the method specified holding time.All initial and continuing calibration criteria were met.No contamination was found in the method blank.Few of the surrogate spike recoveries were within the QC limits due to an apparent spiking solution problem.Data quality is not effected since all percent recovery criteria were met for the laboratory control sample and laboratory control sample duplicate. No target compounds were detected above the reporting detection limit and there was no dilution or reanalysis performed. If you have any questions concerning the analysis or the data please do not hesitate to contact James L.Jordan, (702)361-3955, ext.289.Release of this data report has been authorized by the Laboratory Director or the Director's designee as evidenced by the following signature. James L.Jo dan Client Services Representative JLJ/at cc: Client Services Document Control Department El bloc/r/reed Lockheed Analytical Services 975 Kelly Johnson Orive Las Vegas.Nevada 891194705 Phone: (800)582-7605 Fax: (702)361 8146 February 17, 1994 Mr.Rocky Beem Cook Nuclear Plant 1 Cook Place Bridgman, Ml 49106

Dear Rocky,

Per your request during our phone conversation this morning, the following is an explanation of the procedure used for the determination of the non-standard organic compounds in your groundwater samples.The samples were analyzed using instruments that were set up for standard methods 8260 and 8270, A few of the compounds on your lists of analytes are not standard method 8260 or 8270 compounds. Once the samples are analyzed and a chromatogram was obtained for the samples, all peaks that were present in the samples that did not correspond to one of the calibrated compounds were investigated further.This involved taking the mass spectra obtained from these peaks and comparing the spectra to an NIST library of spectra.This library contains approximately 52,000 known mass spectra.The mass spectra of the additional analytes of interest to you are contained within this library.None of the non-standard analytes were detected in any of your samples.For the next quarters round of sampling, we are endeavoring to obtain the standards for these compounds so that they will be calibrated for in the analyses of those samples.If you have any further questions or if I can be of any further assistance, please do not hesitate to call me at (702)361-1626 ex.289.'ncerely, James L.rdan Project Manager cc: M.Butler

Lockheed Analytical Services DATA QUALIFIERS FOR INORGANIC ANALYSES/Revised 08/28/92)For Use on the Analytical Data Reporting Forms D E N X, Y,orZ For CLP Analyses Only-Reported value is less than the contract required detection limit (CRDL)but greater than or equal to the instrument detection limit (IDL).For Routine, Non-CLP Analyses Only-Any constituent that was also detected in the associated blank whose concentration was greater than the reporting detection limit (RDL).Presence of high levels of interfering constituents required dilution of sample which increased the RDL by the dilution factor.Estimated value due to presence of interference. Sample analysis performed outside of method-or client-specified maximum holding time requirement. For CLP Analyses Only-Duplicate injection precision criterion was not met.Matrix spike recovery exceeded acceptance limits.Reported value was determined from the method of standard addition.For CLP Reporting Only-Constituent was analyzed for but not detected (sample quantitation must be corrected for dilution and percent moisture). For AAS Only-Post-digestion spike for Furnace AAS did not meet acceptance criteria and sample absorbance is less than 50%of spike absorbance. Analyst-detined qualifier. Relative percent difference (RPD)for duplicate analysis exceeded acceptance limits.Correlation coefficient (r)for the MSA is less than 0.995.For Use on the QC Data Reporting Forms The spike recovery and/or RPD for matrix spike and matrix spike duplicates cannot be evaluated due to insufficient spiking level compared to the elevated sample analyte concentration. The RPD cannot be computed because the sample and/or duplicate concentration was below the RDL.'sed as footnote designations on the QC summary form. Lockheed Analytical Services DATA QUALIFIERS FOR ORGANIC ANALYSES (Revised 04/20/93J For Use on the Analytical Data Reporting Forms D H X, Y,orZ For CLP analyses Only-The TIC is a suspected aldol-condensation product.Any constituent that was also detected in the associated blank whose concentration was greater than the practical or reporting detection limit (PQL or RDL).Constituent contirmed by GC/MS analysis.(pesticide/PCB analyses only/Constituent detected in the diluted sample.It also indicates that an accurate quantitation is not possible due to~surr i~ate.being diluted out of the samples during the course of the analysis.Constituent concentration exceeded the calibration range.The quantitation is not gasoline or diesel but believed to be some other combination of hydrocarbons. Sample analysis performed outside of method-or client-specified maximum holding time requirement. Estimated value-(I)constituent detected at a level less than the RDL or PQL and greater than or equal to the MDL;(2)estimated concentration for TICs (For CLP Reporting Only).For CLP Reporting Only-Tentatively identified constituents (TICs)identified based on mass spectral library search.For CLP Reporting Only-The percent difference between the concentrations detected on both GC columns was greater than 25 percent (pesticide/PCB analyses only).For CLP Reporting Only-Constituent was analyzed for but not detected (sample quantitation must be corrected for dilution and percent moisture). Analyst-detined qualitier. For Use on-the QC Data Reporting Forms nI hl QC data (i.e..percent recovery data for matrix spike, matrix spike duplicate, laboratory <<iintrol standard.or surrogates: and RPD for matrix spike duplicate or unspiked duplicate) exceeded acceptance limits.The spike recovery and/or RPD for matrix spike and matrix spike duplicates cannot be evaluated due to insufficient spiking level compared to the, elevated sample analyte concentration. The RPD cannot he computed because the sample and/or duplicate concentration was below the RDL.Use as tootnote t esignations on the summary torm. VOLATILE ORGANIC ANALYSIS RESULTS GC/HALL ANALYSES USING EPA METHOD 8010 lin am I ID: TR D II d: 2-DE Date Anal zed: 04-JAN-94 Matrix: WATER Anal tical Batch¹: 122093-801020-0-3 LAL m I ID: L1 D R ive: 2-DE-Dilution Factor: 1 QC Batch ID: 122093-801020-0-3 BCM BFB rr a Re ver o 114 92 Limi 65-125 60-120 Constituent Dihl r difl r m hne hlrm hn Vin I chloride Bromomethane hlr hn Tri hl r fl r m han 1 1-Dichloroethene Meth lene chloride r n-1 2-Di hl r h n 11-Dihl r h n Chloroform 1 1 1-Trichloroethane ar n r hl ri e 12-Dihl r hn Trichloro ethene TCE 1 2-Dichloro ro ane Br mo i hl r m han 2-hlr hlvinl hr cis-1 3-Dichloro ro ene trans-1 3-Dichloro ro ene 112-Trihl r hn T r hlr hn P E Dibromochlorome hane Chlorobenzene Br mof rm 1122T r hl r hn 1 3-Dichlorobenzene 1 4-Dichlorobenzene 1 2-Dichlorobenzene Concentration (/Jg/L)<0.50<3<6<4<0.5<0.5<2 Reporting Detection Limit/L 0.5 0.5 0.5 Data Qualifier(sl LOCKHEED ANALYTICAL SERVICES A V~

VOLATILE ORGANIC ANALYSIS RESULTS GC/PID ANALYSES USING METHOD 8020 lin m I ID: TR AL ml ID: L1 D II-DE D R iv: 29 DE Date Anal zed: 04-JAN-94 Matrix: WATER Anal tical Batch¹: 122093-801020-0-3 Dilution Factor: 1 QC Batch ID: 122093-801020-0-3 TFT BFB rr a R ver 94 95 Limi 70-120 75-120 Benzene Tol n Constituent Concentration /L 0.52 Reporting Detection Limit/L 0.5 Data Qualifier s hl r nz n Eth I Benzene m-X lene-X len 1-Dihl r nz n 1 4-Dichlorobenzene 1 2-Dichlorobenzene <2<2<2 LOCKHEED ANALYTICAL SERVICES u4 VOLATILE ORGANIC ANALYSIS RESULTS GC/HALL ANALYSES USING EPA METHOD 8010 lin ml ID: TR-A D II: 2-DE Date Anal zed: 04-JAN-94 Matrix: WATER Anal tical Batch¹: 122093-801020-0-3 AL m I ID: Ll D R iv: 2-D Dilution Factor: 1 QC Batch ID: 122093-801020-0-3 BCM BFB urro a R vr 120 86 QC Limi 65-125 60-120 Constituent Dihl r ifl r m hne hlrm hn Vin I chloride Bromomethane hlr hn Trihl r fl'r m h n 1 1-Dichloroethene Meth Iene chloride rn-12-Dihl r hn 11-Dihl r hn Chloroform 1 1 1-Trichloroethane r n r hl rid 12-Dihl r hn Trichloroethene TCE 1 2-Dichloro ro ane Brm ihlrm hn 2-hlr hlvinl hr cis-1 3-Dichloro ro ene trans-1 3-Dichloro ro ene 1 1 2-Tri hl r han Terahlr hn P E Dibromochloromethane Chlorobenzene Brmfrm 1 1 2 2-T r hl r h n 1 3-Dichlorobenzene 1 4-Dichlorobenzene 1 2-Dichlorobenzene Concentration (yg/L)<0.50<3<6<4<0.5<0.5<2 Reporting Detection Limit/L 0.5 0.5 0.5 Data Qualifier(s) LOCKHEED ANAL YTICAL SERVICES nr.1J V

VOLATILE ORGANIC ANALYSIS RESULTS GC/PID ANALYSES USING METHOD 8020 lin ml ID: TR-A D II: 2-D Date Anal zed: 04-JAN-94 Matrix: WATER Anal tical Batch 4: 122093-801020-0-3 LAL am I ID;L1 Da R iv: 2-DE-9 Dilution Factor: 1 QC Batch ID: 122093-801020-0-3 TFT BFB rr a Re v r 97 97 Q Limi 70-120 75-120 Benzene T I n Constituent Concentration IL 0.53 Reporting Detection Limit IL 0.5 Data Qualifier s hlr nzn Eth I Benzene m-X lene-X I n 1-Di hl r b nz n 1 4-Dichlorobenzene 1 2-Dichlorobenzene <2<2<2 LOCKHEEO ANAL YTICAL SERVICES hg li n m I ID: TRS VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 LAL m I ID: L1-41 Page 1 of 2 Date Collected: 28-DEC-93 Matrix: WATER An I i IB h¹: 11 4-2-F2 QC Batch ID: 011094-8260-F2 Date Received: 29-DEC-93 Date Anal zed: 11-JAN-94 Dil inF r: 1 SURROGATE RECOVERY 12-Dihl r h n-d4 TI n-4-Bromofluorobenzene 4 88 QC Limits 7-114 86-115 Constituent Chloromethane Vin I hl ri Brmm hn Chloroethane Trichlorofluoromethane A n 11-Dihl r h n Carbon Disulfide Meth lene Chloride ran-1 2-Dichl ro h n Vin IAc ae 1 1-Dichloroethane 2-Buta none is-1 2-Di hl r h n hlrf rm 1 1 1-Trichloroethane Carbon Te rachloride 12-Dihl r hn B nz n Trichloroethene TCE 1 2-Dichloro ro ane Brom ihl r m hn 2-hl r hIVin I hr 4-Meth I-2-entanone cis-1 3-Dichloro ro ene Tol n r n-1-Dihl r r n 2-Hexanone 1 1 2-Trichloroethane Tetrachloroethene PCE Concentration IL<5<5<5<5<5<10<5<10<5<5<5<5<2<10<5<10<5<5 Reporting Detection Limit IL 10 10 10 Data Qualifier s LOCKHEED ANAL Y jICAL SERVICES lu

Client Sam le ID: TRS VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 LAL Sam le ID: L1009-41 Page 2 of 2 Constituent Dibromochloromethane Chl r nz n Ehl n n m-X lene o-X lene r n Br mof rm 1 1 2 2-Tetrachloroethane 1 3-Dichlorobenzene 14-Dihl r nz n 1 2-Dichlorobenzene Concentration IL<5<5<5<5<5<5 Reporting Detection Limit IL Data Qualifier s LOCKHEED ANAL YTICAL SERVICES VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 TENTATIVELY IDENTIFIED COMPOUNDS Client Sample ID: TRS Date Received: 29-DEC-93 Matrix: WATER Analytical Batch: 011094-8260-F2 LAL Sample ID: L1009-41 Date Analyzed: 11-JAN-94 Dilutiorl Factor: 1 QC Batch ID: 011094-8260-F2 NONE Tentatively Identified Compound Estimated Concentration (yg/L)(10 Retention Time (minutes)0.00 Data Qualifier(sl LOCKHEED ANALYTICAL SERVICES VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 1 of 2 lin ml ID: TR-A Date Collected: 28-DEC-93 Matrix: WATER An I i IB h¹: 11 4--F QC Batch ID: 011094-8260-F2 LAL m le ID: L1-43 Date Received: 29-DEC-93 Date Anal zed: 11-JAN-94 Dil i nF r: 1 SURROGATE RECOVERY 1 2-Dichloroe han-d4 TI n-QC Limits 7-114 4-Bromofluorobenzene 89 86-115 Constituent Chloromethane Vin I hl ri Br mom han Chloroethane Trichlorofluorom ethane A n 11-Dihl r hn Carbon Disulfide Meth lene Chloride rn-1-Dihl r hn Vin I A 1 1-Dichloroethane 2-Butanone i-12-Dihl r h n hlor f rm 1 1 1-Trichloroethane Carbon Tetrachloride 12-Dihl r hn B nz n Trichloroethene TCE 1 2-Dichloro ro ane Brom ihl r m hn 2-hl r h I Vin I E h r 4-Meth l-2-entanone cis-1 3-Dichloro ro ene T I n r n-1-Dihl r r ne 2-Hexanone 1 1 2-Trichloroethane Tetrachloroethene PC E Concentration IL<5<5<5<5<5<5<10<5<5<5<5<2<10<10<5<5 Reporting Detection Limit IL 10 10 10 Data Qualifier s LOCKHEED ANALYTICAL SERVICES IB VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING IVIETHOD 8260 Client Sam le ID: TRS-QA LAL Sam le ID: L1009-43 Page 2 of 2 Constituent Dibromochloromethane hl r enz n Ehl nzn m-X lene o-X lene r n Brmfrm 1 1 2 2-Tetrachloroethane 1 3-Dichlorobenzene 1 4-Di hl r enz n 1 2-Dichlorobenzene Concentration IL<5<5<5<5<5 Reporting Detection Limit IL Data Qualifier s LOCKHEED ANALYTICAL SERVICES VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 TENTATIVELY IDENTIFIED COMPOUNDS Client Sample ID: TRS-QA Date Received: 29-DEC-93 Matrix: WATER Analytical Batch: 011094-8260-F2 LAL Sample ID: L1009-43 Date Analyzed: 11-JAN-94 Dilution Factor: 1 QC Batch ID: 011094-8260-F2 NONE Tentatively Identified Compound Estimated Concentration Ipg/L)(10 Retention Time (minutes)0.00 Data Qualifieris) LOCKHEED ANALYTICAL SERVICES SEMIVOLATILE ORGANIC ANALYSIS RESULTS ,FOR GC/MS ANALYSES USING METHOD 8270 P 1 f2 lin m I ID: TR Date Collected: 28-DEC-93 Matrix: WATER Anl i IB h¹: 111 4-27-8 QC Batch ID: 8270-SEMIVOLATILES-3964 LAL m I ID: L1-2 Date Received: 29-DEC-93 Dilution Factor: 1 D Exra: 4-AN-4 Date Anal zed: 11-JAN-94 2-Fluoro henol Phenol-d, Nitrobenzene-d~ RR ATE RE VERY 0/41 26 59 QC Limits 21-100 10-94 35-114 2-Fluorobi hen I 246-Tri r m hn I p-Terphenyl-d,4 55 99 43-116 1-12 33-141 on i uen Phenol bis 2-Chloroeth I ether 2-hlr hnl 1-Dihl r n n 1 4-Dichlorobenzene Benz I alcohol 1 2-Di hl r nz n 2-'M h I h n I bis 2-Chloroiso ro I ether 4-Meth I henol N-Ni r-Di-n-r I min Hx hlr hn Nitrobenzene Iso horone-Ni r h n I 2 4-Dime h I h n I Benzoic acid bis 2-Chloroethox methane 4-Dihl r hn I 1 24-Tri hl r nz n Na hthalene 4-Chloroaniline Hx hlr in 4-hlr--m hlhnl 2-Meth Ina hthalene Hexachloroc clo entadiene Concentration L<10<10<10<10<10<10<10<10<50<10<10<10<10<10.Reporting Detection Limit L 10 10 10 10 10 10 10 10 50 10 10 10 10 10 D LOCKHEED Ah/ALYTICAL SERVICES 4w SEIVIIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/IVIS ANALYSES USING METHOD 8270 Client Sam le ID: TRS LAL Sam le ID: L1009-25 P 2 f2 Constituent 24-Trihl r hn I 4-Trihl r h n I 2-Chlorona hthalene 2-Nitroaniline Dim h I hhal A n hhln 2 6-Dinitrotoluene 3-Nitroaniline A n hhn 2 4-Dini r henol 4-Nitro henol Dibenzofuran 2 4-Dini r I n Di h I hh I 4-Chloro hen I-hen lether Fluorene 4-Ni r nilin 4-Dinir-2m h I h n I N-Nitrosodi hen lamine 4-Bromo hen I-hen lether Hx hlr nzn Pn hlr hnl Phenanthrene Anthracene Di-n-I hh I Fl r nhn P rene But Ibenz I hthalate'-Di hl r nzi in 8 nzo n hr n Chr sene bis 2-Eth)hex I hthalate Di-n-I hh I Bnz fl rnhn Benzo k fluoranthene Benzo a rene In n 12-c r ne Di nz h n hr n Benzo h i er lene Carbazole Concentration IL)<10<25<10<25<25<25<10<10<10<2<2<10<10<2<10<10 1.4<10<10<2<10<10 1.5<10<10<10<10 Reporting Detection Limit (IL)10 25 10 25 25 25 10 10 10 10 10 10 10 10 10 10 10 10 10'10 10 10 Data Qualifier(s) J B LOCKHEED ANALYTICAL SERIIICES 30 VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8270 TENTATIVELY IDENTIFIED COMPOUNDS Client Sample ID: TRS Date Received: 29-DEC-93 Matrix: WATER Analytical Batch: 011194-8270-8 LAL Sample ID: L1009-25 Date Analyzed: 11-JAN-94 Dilution Factor: 1 QC Batch ID: 8270-SEMIVOLATILES-3964 Unknown Unknown Tentatively Identified Compound Estimated Concentration (pg/L)100 20 Retention Time (minutes)6.44 30.26 Data Qualifier(s) LOCKHEED AIVAL YTICAL SERVICES 3L SEIVIIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 P 1 f2 lin ml ID: TR-A Date Collected: 28-DEC-93 Matrix: WATER An I i IB hA': 111 4-27-B QC Batch ID: 8270-SEMIVOLATILES-3964 LAL m le ID: L10-27 Date Received: 29-DEC-93 Dilution Factor: 1 Da Ex r c: 04-JAN-4 Date Anal zed: 11-JAN-94 2-Fluoro henol Phenol-d, Nitro benzene-d, RR ATE RE VERY 0 38 26 61 Limi 21-100 10-94 35-114 2-Fluorobi hen I 2 4 6-Tribromo h nol p-Terphenyl-d 56 97 43-116 1-12 33-141 Phenol n i n Concentration L<10 Reporting Detection Limit L 10 D bis 2-Chloroeth I ether 2-hl r hn I 1-Di hl r nz n 1 4-Dichlorobenzene Benz I alcohol 12-Dihl r nz n 2-M h I h n I bis 2-Chloroiso ro I ether 4-Meth I henol N-Ni r-Di-n-r I min Hx hlr hn Nitrobenzene Iso horone 2-Nir h n I 24Dim h I hn I Benzoic acid bis 2-Chloroethox me hane 24-Dihl r hn I 1 2 4-Tri hl r nz n Na hthalene 4-Chloroaniline Hx hlr in 4-hlr--m hlhnl 2-Meth Ina hthalene Hexachloroc clo entadiene<10<10<10<10<10<10<10<50<10<10<10<10<10 10 10 10 10 10 10 10 10 50 10 10 10 10 10 LOCKHEED ANALYTICAL SERVICES 2 SEIVIIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Client Sam le ID: TRS-OA LAL Sam le ID: L1009-27 P 2 f2 Constituent 24-Trihl r h n I 24-Trihl r hn I 2-Chlorona hthalene 2-Nitroaniline Dim h I hh I A n hhln 2 6-Dinitrotoluene 3-Nitroaniline A n h hen 24-Dinir h n I 4-Nitro henol Dibenzofuran 2'4-Dini r I n Di hi hhl 4-Chloro hen I-hen lether Fluorene 4-Ni r anilin 4-Dinir-2m h I h n I N-Nitrosodi hen lamine 4-Bromo hen I-hen lether Hx hlr nzn Pn hl n I Phenanthrene Anthracene Di-n-I hh I Fl r nhn P rene But Ibenz I hthalate'-Di h r nzi in B nz nhr n Chr sene bis 2-fth Ihex I hthalate Di-n-I hh I Bnz fl rnhn Benzo k fluoranthene Concentration I IL)<10<10<25<10<25<10<2<25<10<10<10<10<2<10<10<10<10<10<10<2<10 1.9<10 Reporting Detection Limit (ILI 10 10 25 10 25 25 10 10 10 10 10 10 10 10 10 10 10 10 10 10 Data Qualifier(si J 8 Benzo a rene In en 12 ren<10 10 10 Di enz a h an hr n Benzo h i er lene Carbazole<10<10 10 10 LOCKHEEO ANALYTICAL SERVICES 0 VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8270 TENTATIVELY IDENTIFIED COMPOUNDS Client Sample ID: TRS-QA Date Received: 29-DEC-93 Matrix: WATER Analytical Batch: 011194-8270-8 LAL Sample ID: L1009-27 Date Analyzed: 29-DEC-93 Dilution Factor: 1 QC Batch ID: 8270-SEIVIIVOLATILES-3964 Unknown Unknown Tentatively Identified Compound Estimated Concentration Iyg/L)4 100 Retention Time I minutes)5.28 6.44 Data Qualifier(s) Hydrocarbon Unknown Hydrocarbon Hydrocarbon Hydrocarbon 20 29.97 30.26 31.98 32.94 33.86 LOCKHEEO ANALYTICAL SERIIICES".4 PESTICIDE ANALYSES RESULTS BY GC/ECD USING METHOD 8080 FOR COOK NUCLEAR PLANT Clien Sam te ID: TRS Da e Collec ed: 28-DEC-93 Date Extracted: 04-JAN-94 Matrix: WATER Anal tical Batch¹: 012094-8080-A-1 LAL Sam Ie ID: L1009-17 Da e R eived:29-JAN-94 Date Anal zed: 21-JAN-94 Dilution Factor: 1 QC Grou ID: 8080 PEST/PCBS 3965 SURROGATE RECOVERY oo QC Limits TCMX DCB 65 52 60-150 60-150 A-BHC B-BHC-BH D-BHC Constituent Concentration IL<0.05.0<0.05 Reporting Detection Limit IL 0.05 0.0.05 Data Qualifier(s) HEPTACHLOR ALDRIN HEPTACHLOR EPOXIDE G-CHLORDANE ENDOSULFAN I A-CHLORDANE 4 4'-DDE 4 4'-DDT DIELDRIN ENDRIN ENDOSULFAN II 4 4'-DDD ENDRIN ALDEHYDE ENDO LFAN LFATE METHOXY HL R TOXAPHENE PCB-1016 P B-1221 PCB-12 2 PCB-1242 PCB-1248 PCB-12 4 PCB-12 0 TECHNICAL CHLORDANE MIREX TCMX-tetra-chloro-meta-xylene DCB-Deca-chloro-biphenyl <0.05<0.0<0.05<0.05<.05<0.1<0.1<0.1<0.1<0.1<5<2<0.1 0.05 0.05 0.05 0.05 0.1 0.1 0.1 0.1 0.1<0.1 LOCKHEED ANALYTICAL SERVICES 5f PESTICIDE ANALYSES RESULTS BY GC/ECD USING METHOD 8080 FOR COOK NUCLEAR PLANT Clien S m le ID: TR-QA Da e Collec ed: 28-DEC-93 Date Extracted: 04-JAN-94 Matrix: WATER Anal tical Batch¹: 012094-8080-A-1 LAL S m I ID:L1009-19 Date Received:29-JAN-94 Date Anal zed: 21-JAN-94 Dilution Factor: 1 QC Grou ID: 8080 PEST/PCBS 3965 SURROGATE RECOVERY TCMX QC Limits 60-150 DCB 46 60-150 A-BHC B-BHC-BH D-BHC Constituent Concentration /L<0.05<0.05 Reporting Detection Limit/L 0.05 0.05 Data Qualifier(s) HEPTACHLOR ALDRIN HEPTA HLOR EPOXIDE G-CHLORDANE ENDOSULFAN I A-CHLORDANE 4 4'-DDE 4 4'-DDT DIELDRIN ENDRIN ENDOSULFAN II 4 4'-DDD ENDRIN ALDEHYDE ENDOSULFAN SULFATE METHOXYCHL R TOXAPHENE PCB-1016 PCB-1221 PCB-1232 PCB-1242 PCB-1248 P B-12 4 PCB-126 TECHNICAL CHLORDANE MIREX TCMX-tetra-chloro-meta-xylene DCB-Deca-chloro-biphenyl <0.05<0.05<0.05<0.05<.05<0.1<0.1<0.1<0.1<0.1<5<2<0.1 0.05 0.05 0.05 0.05 0.1 0.1 0.1 0.1 0.1 0.<0.1 LOCKHEED ANALYTICAL SERVICES 5 2

IVIETALS RESULTS Clie'n't Sam"le ID: TRS LAL Batch ID(s): 1220 im Date Collected: 12-28-93 Date Received: 12-29-93 Matrix: round'water P0¹69095-040-3N Constituents: .'Meth'od Concentration .(m IL)..Reporting Detection Limit (m IL)Data Qualifier(s) Data Anal zed LAL Sam le ID.Aluminum Antimon Arsenic Barium Be Ilium Boron Cadmium Chromium Cobalt Co er Iron Lead Ma nesium Man anese Mercu Mol bdenum Nickel Selenium Silver Sodium Thallium Tin Titanium Vanadium Zinc 6010 6020 6020 6020 6020 6010 6020 6020 6020 6020 6010 6020 6010 6020 7470 6020 6020 6020 6020 6010 6020 6020 6010 6010 6020<0.20<0.060<0.010<0.20<0.005 0.28<0.005<0.010<0.050<0.025<0.10<0.003 18 0.026<0.0002<0.20<0.040 0.0055<0.010 900<0.010<0.20<0.10<0.050<0.020 0.20 0.060 0.010 0.20 0.005 0.20 0.005 0.010 0.050 0.025 0.10 0.003 5.0 0.01 5 0.0002 0.20 0.040 0.005 0.010 5.0 0.010 0.20 0.10 0.050 0.020 01-20-94 01-27-94 01-27-94 01-27-94 01-27-94 01-20-94 01-27-94 01-27-94 01-27-94 01-27-94 01-20-94 01-27-94 01-20-94 01-27-94 01-07-94 01-27-94 01-27-94 01-27-94 01-27-94 01-20-94 01-27-94 01-27-94 01-20-94 01-20-94 01-27-94 L1009-13 L1009-13 L1009-13 L1009-13 L1009-13 L1009-13 L1009-13 L1009-13 L1009-13 L1009-13 L1009-13 L1009-13 L1009-13 L1009-13 L1009-13 L1009-13 L1009-13 L1009-13 L1009-13 L1009-1 3 L1009-13 L1009-13 L1009-13 L1009-13 L1009-13 Comments: LOCKHEED AIVALVTICAL SERVICES 0 METALS RESULTS-Client Sam le ID: TRS-OA LAL Batch ID(s): 1220 im Date: Collected: 12-28-93 Date Received: 12-29-93 Matrix:.round water POP'69095-040-3N

Constituents Aluminum Antimon Method 6010 6020 Concentration

{r'n IL'l<0.20<0.060 Reporting Detection Limit{m Ill 0.20 0.060 Oats Date Qualtfier{s).Anal ied 01-20-94 01-27-94 LAL Sam'le ID" L1009-14 L1009-14 Arsenic Barium Be Ilium Boron Cadmium Chromium Cobalt Co er Iron Lead Ma nesium Man anese Mercu Mol bdenum Nickel Selenium Silver Sodium Thallium Tin Titanium Vanadium Zinc 6020 6020 6020 6010 6020 6020 6020 6020 6010 6020 6010 6020 7470 6020 6020 6020 6020 6010 6020 6020 6010 6010 6020<0.010<0.20<0.005 0.27<0.005<0.010<0.050<0.025<0.10<0.003 17 0.027<0.0002<0.20<0.040 0.0078<0.010 890<0.010<0.20<0.10<0.050 0.022 0.010 0.20 0.005 0.20 0.005 0.010 0.050 0.'025 0.10 0.003 5.0 0.015 0.0002 0.20 0.040 0.005 0.010 5.0 0.010 0.20 0.10 0.050 0.020 N N 01-27-94 01-27-94 01-27-94 01-20-94 01-27-94 01-27-94 01-27-94 01-27-94 01-20-94 01-27-94 01-20-94 01-27-94 01-07-94 01-27-94 01-27-94 01-27-94 01-27-94 01-20-94 01-27-94 01-27-94 01-20-94 01-20-94 01-27-94 L1009-14 L1009-14 L1009-14 L1009-14 L1009-14 L1009-14 L1009-14 L1009-14 L1009-14 L1 009-14 L1009-14 L1009-14 L1009-14 L1009-14 L1009-14 L1 009-14 L1009-14 L1009-14 L1009-14 L1009-14 L1 009-14 L1009-14 L1009-14 Comments: LOCKHEED ANALYTICAL SERVICES 0 0 GENERAL CHEMISTRY RESULTS Client Sam le ID: TRS LAL Batch ID(s): 1229 im Date Collected: 12-28-93 Matrix: round water Date Received: 12-29-93 PO¹69095-040-3N Constituent Method Result Reporting Detection Limit Data Qualifierls) Date Anal zed LAL Sam ie ID Fluoride, in m IL Chloride, in m IL 340.2 300.0 0.29 19 0.15 0.016 01-24-94 L1 009-1 12-29-93 L1009-1 Nitrite.Nitro en, in m/L Sulfate, inm IL 300.0 300.0 Nitrate-Nitro en, in m IL 300.0 0.91<0.012 2000 0.01 7 0.01 2 0.59 D(1:10)1 2-29-93 L1 009-1 12-29-93 L1009-1 12-29-93 L1009-1 Ammonia-Nitrogen, in m/L Total Cyanide, in mg/L 350.1 335.2 3.4<0.020 0.050 0.020 01-05-94 L1009-5 01-03-94 L1009-9 Comments: LOCKHEED ANAL YTICAL SERVICES 65 GENERAL CHEMISTRY RESULTS Client Sam le'ID: TRS-QA LAL Batch ID(s): 1229 im Date Collected: 12-28-93 Date Received: 12-29-93 Matrix: round water P0469095-040-3N Constituent Method Result Reporting Detection Limit Data Qualifier(s) Date Anal zed LAL Sam le ID Fluoride, in m IL Chloride.in m IL Nitrate-Nitro en, in m IL Nitrite.Nitro en, in m IL Sulfate, in m IL Ammonia-Nitrogen, inm IL Total Cyanide, in mg/L 340.2 300.0 300.0 300.0 300.0 350.1 335.2 0.31 20 0.90<0.012 2200 3,4<0.020 0.15 0.01 6 0.01 7 0.01 2 0.59 0.050 0.020 D(1:10l 01-24-94 L1009-2 12-29-93 L1009-2 12-29-93 L1009-2 12-29-93 L1009-2 12-29-93 L1009-2 01-05-94 L1009-6 01-03-94 L1009-10 Comments: LOCKHEED ANALYTICAL SERVICES

GENERAL CHEIVIISTRY QC DATA SUIVIIVIARY .LAL Batch ID(s): 1229 im QC Sam le Anal ses.Constituent-Fluoride, in m/L Client'Sample'D TRS L'AL Sample ID L1 009-1 Date Analyzed 01-24-94 Reagent Blank<0.15 Matrix Duplicate: 'Spike Precision'eco'very (9o RPD)(%)107 Chloride, in m/L Nitrate-Nitrogen, in m/L TRS TRS L1 009-1 L1 009-1 1 2-29-93 1 2-29-93'<0.016 0.2<0.01 7 91 93 Nitrite-Nitro en, in m/L Sulfate, in m/L Ammonia-Nitrogen, in m/L Total Cyanide, in mg/L TRS TRS TRS TRS L1 009-1 L1 009-1 L1 009-5 L1 009-9 12-29-93 12-29-93 01-05-94 01-03-94<0.012<0.059<0.050<0.020 0.1 0 96 96 122 94"b"-The RPD cannot be computed, because the sample or the duplicate concentration was below the Detection Limit.Comments: LOCKHEED ANALYTICAL SERVICES

on NUS a~aaw~~C 0 R P 0 R A T I 0 N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Report Ho.: 00018939 Section A Page 1 CLIENT NAME: ADDRESS: ATTENTION: INDIANA MICHIGAN POWER COMPANY ONE COOK PLACE BRIDGMAN, Ml 49106-0000 MS.JENI LEWIS-CHEMISTRY DEPT.HUS CLIENT NO: 0663 0020'WORK ORDER NO: 55830 VENDOR NO: 05411000 Carbon Copy: SAMPLE ID: HUS SAMPLE NO: P.O.NO.: TURBINE ROOM SUMP 27476 P0259284 69034-040.3N DATE SAMPLED: 30-DEC-93 DATE RECEIVED: 05-JAN-94 APPROVED BY: Kieda, Chuck TEST LH CODE DETERMINATION RESULT UNIT 1 I 730 2 AHA'W 3 I130 4 I590 5 AALW Sulfate, Turbidimetric (as S04)Sodiun, Total (Na)Chloride (as Cl)Solids, Dissolved at 180C Atunintm, Total (Al)51 mg/L 6.3 mg/L 11 mg/L 140 mg/L 0.97 mg/L COMMENTS:

/dh HBSUft011 NUS I~~~C P R P P R A T I P N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Report Ho.: 00018939 Section A Page 2 CLIENT NAME: ADDRESS: ATTENTIOH: INDIANA MICHIGAN POWER COMPANY OHE COOK PLACE.BRIDGMAN, Ml 49106-0000 MS.JENI LEWIS-CHEMISTRY DEPT.NUS CLIENT NO: 0663 0020 WORK ORDER NO: 55830 VENDOR HO: 05411000 Carbon Copy: SAMPLE ID: HUS SAMPLE HO: P.O.HO.: TURBINE ROOM SUMP 27476/FILTERED P0259285 69034-040-3N DATE SAMPLED: 30.DEC-93 DATE RECEIVED: 05-JAH-94 APPROVED BY: Kieda, Chuck TEST LN CODE DETERMIHATIOH RESULT UNITS1 AALF Atuninun, Dissotved (At)COMME HTS: 0.3 mg/L

.".Halliburton NUS+++C 0 R P 0 R A T I 0 N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Report No.: 00018939 Section A Page 3 CLIENT NAME: ADDRESS: ATTEHTION: INDIANA MICHIGAN POWER COMPANY ONE COOK PLACE BRIDGMAN, MI 49106-0000 MS.JENI LEWIS-CHEMISTRY DEPT.NUS CLIENT NO: 0663 0020 WORK ORDER HO: 55830 VENDOR NO: 05411000 Carbon Copy: SAMPLE ID: NUS SAMPLE NO: P.O.NO.: TURBINE ROOM SUMP 27503 P0259286 69034-040-3N DATE SAMPLED: 31.DEC-93 DATE RECEIVED: 05-JAN-94 APPROVED BY: Kieda, Chuck TEST LN CODE DETERMI HAT IOH RESULT UNITS 1 I730 2 AHAW 3 I 130 4 I590 5 AALW COMMEHTS: Sulfate, Turbidimetric (as S04)Sodiun, Total (Na)Chloride (as Cl)Solids, Dissolved at 180C Atuninun, Total (Al)53 mg/L 6.0 mg/L 10 mg/L 130 mg/L 0.98 mg/L

.-: H<b~on~S++++C 0 R P 0 R A T I 0 N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pit tsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Report No.: 00018939 Section A Page 4 CLIENT NAME: ADDRESS: ATTENTION: INDIANA MICHIGAH POWER COMPANY ONE COOK PLACE BRIDGMAH, MI 49106.0000 MS.JEHI LEWIS-CHEMISTRY DEPT.NUS CLIENT NO: 0663 0020 WORK ORDER NO: 55830 VENDOR HO: 05411000 Carbon Copy: SAMPLE ID: HUS SAMPLE NO: P.O.HO.: TURBINE ROOM SUMP 27503/FILTERED P0259287 69034-040-3H DATE SAMPLED: 31-DEC.93 DATE RECEIVED: OS-JAN.94 APPROVED BY: Kieda, Chuck TEST LN CODE DETERMINATION RESULT UNITS ,1 AALF Atminun, Dissolved (At)0.3 mg/L COMMENTS: i'Halliburton NUS I+++C 0 R P 0 R A T I 0 N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Report No.: 00018939 Section A Page 5 CLIENT NAME: ADDRESS: ATTENTION: INDIANA MICHIGAN POWER COMPANY OHE COOK PLACE BRIDGMAN, MI 49106-0000 MS.JENI LEWIS-CHEMISTRY DEPT.NUS CLIENT NO: 0663 0020 WORK ORDER NO: 55830 VENDOR NO: 05411000 Carbon Copy: SAMPLE ID: NUS SAMPLE NO: P.O.NO.: TURBINE ROOM SUMP 27506 P0259288 69034-040-3N DATE SAMPLED: 01-JAN.94 DATE RECEIVED: 05-JAH 94 APPROVED BY: Kieda, Chuck TEST LN CODE DETERMIHATIOH RESULT UNITS 1 I 730 2 AHAW 3 1130 4 I 590 5 AALW Sulfate, Turbidimetric (as S04)Sodiua, Total (Ha)Chloride (as Cl)Solids', Dissolved at 180C Atuninun, Total (Al)52 mg/L 5.6 mg/L 10 mg/L 130 mg/L 1.6 mg/L COMMENTS:

h: Halliburton NUS CORPORATION LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (4'12)747-2684 January 18, 1994 Report Ho.: 00018939 Section A Page 6'L IENI'AME: ADDRESS: ATTENTION: Carbon Copy: IND IAHA MICHIGAN POWER COMPANY ONE COOK PLACE BRIDGMAN, MI 49106-0000 MS.JEHI LEWIS-CHEMISTRY DEPT.NUS CLIEHT HO: 0663 0020 WORK ORDER HO: 55830 VEHDOR NO: 05411000 SAMPLE ID: HUS SAMPLE NO: P.O.NO.: TRUBIHE ROOM SUMP 27506/FILTERED P0259289 69034-040-3H DATE SAMPLED: 01-JAH-94 DATE RECEIVED: 05-JAH-94 APPROVED BY: Kieda, Chuck TEST LN CODE DETERMINATION RESULT UNITS 1 AALF Alumina, Dissolved (At)COMMENTS: 0.2 mg/L AL Halliburton NUS I+C 0 R P 0 R AT I 0 N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Report No.: 00018939 Section A Page 7 CLIENT NAME: ADDRESS: ATTENTION: INDIANA MICHIGAN POWER COHPANY ONE COOK PLACE BRIDGHAN, Hi 49106-0000 HS.JENI LEWIS-CHEMISTRY DEPT.NUS CLIENT NO: 0663 0020 WORK ORDER NO: 55830 VENDOR NO: 05411000 Carbon Copy: SAMPLE ID: NUS SAHPLE NO: P.O.NO.: TURBINE ROOH SUHP 27509 P0259290 69034-040-3N DATE SAMPLED: 02-JAN-94 DATE RECEIVED: 05-JAN-94 APPROVED BY: Kieda, Chuck TEST LN CODE DETERHINATION RESULT UNITS 1 1730 2 ANAW 3 1130 4 I 590 5 AALW 6 I490 7 1700 Sulfate, Turbidimetric (as SO4)Bedizen, Total (Na)Chloride (as Cl)Solids, Dissolved at 180C Atuninun, Total (Al)pN Specific Conductance at 25C 51 mg/L 5.9 mg/L 10 mg/L 140 mg/L 1.5, mg/L 7.6 300 umhos/cm COHHENTS: on gJS I+C 0 R P 0 R AT I 0 N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Report No.: 00018939 Section A Page 8 CLIENT NAME: ADDRESS: ATTENTION: INDIANA HICNIGAN POWER COHPANY ONE COOK PLACE BRIDGHAN, Hl 49106-0000 MS.JENI LEWIS-CHEHISTRY DEPT.NUS CLIENT NO: 0663 0020 WORK ORDER NO: 55830 VENDOR NO: 05411000 Carbon Copy: SAHPLE ID: TURBINE ROOH SUHP 27509/FILTERED NUS SAHPLE NO: P0259291 P.O.NO.: 69034-040-3N DATE SAMPLED: 02-JAN-94 DATE RECEIVED: 05-JAN-94 APPROVED BY: Kieda, Chuck TEST LN CODE DETERHINATION RESULT UNITS 1 AALF.Atuninun, Dissotved (At)COHMENTS: 0.3 mg/L /4L: Halliburton NUS+C 0 R P 0 R AT I 0 N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Report No.: 00018939 Section A Page 9 CLIEHT NAME: INDIANA MICHIGAN POWER COMPANY ADDRESS: ONE COOK PLACE BRIDGMAN, MI 49106-0000 ATTENTIOH: MS.JENI LEWIS-CHEMISTRY DEPT.NUS CLIENT HO: 0663 0020 WORK ORDER NO: 55830 VENDOR NO: 05411000 Carbon Copy: SAMPLE ID: ABS POND COMP.HUS SAMPLE NO: P0259292 P.O.NO.: 69034-040-3H DATE SAMPLED: 31-0EC.93 DATE RECEIVED: 05-JAH 94 APPROVED BY: Kieda, Chuck TEST.LN CODE DETERMIHAT ION RESULT UNITS 1 1730 2 ANAW 3 1130 4 1590 5 AALW Sulfate, Turbidimetric (as S04)Sodiun, Total (Ha)Chloride (as Cl)Solids, Dissolved at 180C Atuninm, Total (Al)110 28 9 210 0.33 mg/L mg/L mg/L mg/L mg/L COMMENTS: on NU$I++C 0 R P 0 R AT I 0 N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 1B, 1994 Report No.: 0001B939 Section A Page 10 CLIENT NAME: ADDRESS: ATTENTION: Carbon Copy: INDIANA MICHIGAN POWER COMPANY ONE COOK PLACE BRIDGMAN, Ml 49106-0000 MS.JENI LEWIS-CHEMISTRY DEPT.NUS CLIENT No: 0663 0020 WORK ORDER HO: 55030 VENDOR NO: 05411000 SAMPLE ID: ABS POND COMP./FILTERED HUS SAMPLE NO: P0259293 P.O.NO.: 69034-040-3N DATE SAMPLED: 31-DEC.93 DATE RECEIVED: 05-JAH.94 APPROVED BY: Kieda, Chuck TEST LN CODE DETERMINATION RESULT UNITS 1 AALF COMMENTS: Atuninun, Dissotved iAI)0.099 mg/L

4'.Halliburton NUS%%EN C 0 R P 0 R AT I 0 N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pit tsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Report Ho.: 00018939 Section A Page 11 CLIENT NAME: ADDRESS: ATTENTION:

INDIANA MICHIGAN POWER COMPANY OHE COOK PLACE BRIDGMAN, Mi 49106-0000 MS.JENI LEWIS-CHEMISTRY DEPT.HUS CLIENT HO: 0663 0020 WORK ORDER NO: 55830 VENDOR HO: 05411000 Carbon Copy: SAMPLE ID: HUS SAMPLE HO: P.O.HO.: ABS POHD COMP.P0259294 69034-040-3N DATE SAMPLED: 01-JAN 94 DATE RECEIVED: 05-JAH-94 APPROVED BY: Kieda, Chuck TEST LN CODE DETERMIHATIOH RESULT UNITS 1 1730 2 AHAW 3 I 130 4 I590 5 AALW Sulfate, Turbidimetric (as S04)Sodiun, Total (Na)Chloride (as Cl)Solids, Dissolved at 180C Aluminize, Total (Al)110 mg/L 30 mg/L 10 mg/L 210 mg/L 0.35 mg/L COMMENTS: i: Halliburton NUS I+++C 0 R P 0 R AT I 0 N LABORATORY ANALYSIS REPORT NUS LASORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Report No.: 00018939 Section A Page 12 CLIENT NAME: ADDRESS: ATTENTION: Carbon Copy: INDIANA MICHIGAN POWER COMPANY ONE COOK PLACE BRIDGMAN, Ml 49106-0000 MS.JEHI LEWIS-CHEMISTRY DEPT.HUS CLIENT NO: 0663 0020 WORK ORDER HO: 55830 VEHDOR NO: 05411000 SAMPLE ID: ABS POND COMP./FILTERED HUS SAMPLE HO: P0259295 P.O.HO.: 69034-040-3N DATE SAMPLED: 01-JAN-94 DATE RECEIVED: 05-JAN-94 APPROVED BY: Kieda, Chuck TEST LN CODE DETERMI NATION RESULT.UNITS 1 AALF Atuninua, Dissolved (At)0.10 mg/L COMMENTS:

L: Halliburton NUS I+++C 0 R P 0 R A T I 0 N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Report No.: 00018939 Section A Page 13 CLIENT NAME: ADDRESS: ATTENTION: INDIANA MICHIGAN POWER COMPANY ONE COOK PLACE BRIDGMAH, MI 49106-0000 MS.JEHI LEWIS-CHEMISTRY DEPT.NUS CLIENT NO: 0663 0020 WORK ORDER HO: 55830 VENDOR NO: 05411000 Carbon Copy: SAMPLE ID: NUS SAMPLE HO: P.O.NO.: ABS POND COMP.P0259296 69034-040-3N DATE SAMPLED: 02-JAN-94 DATE RECEIVED: 05-JAN-94 APPROVED BY: Kieda, Chuck TEST LN CODE DETERMINATION RESULT UNITS 1 I 730 2 ANAW 3 1130 4 1590 5 AALW 6 1700 Sulfate, Turbidimetric (as S04)Sodiun, Total (Ha)Chloride (as Cl)So l i ds, Dissolved at 180C Alumina, Total (Al)Specific Conductance at 25C 100 31 10 190 0.5 400 mg/L mg/L mg/L mg/L mg/L umhos/cm COMMENTS: .".Halliburton NUS I~~iC0R P 0R AT I 0N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Report No.: 00018939 Section A Page 14 CLIENT kAME: ADDRESS: ATTENTION: IHDIAHA MICHIGAN POWER COMPANY ONE COOK PLACE BRIDGMAN, Mi 49106-0000 MS.JENI LEWIS-CHEMISTRY DEPT.NUS CLIENT NO: 0663 0020 WORK ORDER NO: 55830 VENDOR NO: 05411000 Carbon Copy: SAMPLE ID: ABS POHD COMP./FILTERED NUS SAMPLE NO: P0259297 P.O.HO.: 69034-040-3H DATE SAMPLED: 02-JAN.94 DATE RECEIVED: 05-JAH-94 APPROVED BY: Kieda, Chuck TEST LH CODE DETERMINATION RESULT UNITS 1 AALF Atuainun, Dissolved (At)0.072 mg/L COMMENTS: /4L'Halliburton NUS+++C 0 R P 0 R A T I 0 N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Report No.: 00018939 Section A Page 15 CLIENT HAME: ADDRESS: ATTENTIOH: INDIANA MICHIGAN POWER COMPANY OHE COOK PLACE BRIDGMAN, MI 49106-0000 MS.JEHI LEWIS-CHEMISTRY DEPT.NUS CLIENT HO: 0663 0020 WORK ORDER HO: 55830 VENDOR HO: 05411000 Carbon Copy: SAMPLE ID: ABS POND COMP 66998 NUS SAMPLE NO: P0259298 P.O.NO.: 69034-040-3N DATE SAMPLED: 03 JAN-94 DATE RECEIVED: 05-JAN-94 APPROVED BY: Kieda, Chuck TEST LN CODE DETERMINATION RESULT UNITS 1 1 730 2 ANAW 3 1130 4 I590 5 AALW 8 I700 COMMENTS: Sulfate, Turbidimetric (as SO4)Sodiun, Total (Na)Chloride (as Cl)Solids, Dissolved at 180C Atuninua, Total (Al)Specific Conductance at 25C I 110 28 10 190 0.5 410 mg/L mg/L mg/L mg/L mg/L umhos/cm .".Hallibu1 ton NUS CORPORATION LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Report No.: 00018939 Section A Page 16 CLIENT NAME: ADDRESS: ATTENTIOH: IHDIANA MICHIGAN POWER COMPANY ONE COOK PLACE BRIDGMAH, MI 49106-0000 MS.JENI LEWIS-CHEMISTRY DEPT.NUS CLIENT NO: 0663 0020'WORK ORDER NO: 55830 VENDOR NO: 05411000 Carbon Copy: SAMPLE ID: NUS SAMPLE NO: P.O.HO.: ABS POND COMP 66998/FILTERED P0259299 69034-040-3N DATE SAMPLED: 03-JAN-94 DATE RECEIVED: 05-JAN-94 APPROVED BY: Kieda, Chuck TEST LH CODE DETERMINATION RESULT UNITS 1 AALF Atuainua, Dissolved (Al)0.088 mg/L COMMENTS: SEE INSTRUCTIONS ON REVERSE SIDE SECTION II NUMBER PERMIT~NI ppp5827~OO E As LOCATION OF DISCHARGE~~~t~EE~v, ernss i~00.Ee DISCHARGE LOCATION B N%RECEIVLNL HATER (IEs GROINLNATER CR NA%OF QRFACE MA C>>OO@XI DISCHARGE SEASCNALLY LLF Ms CONTIIAK IO E)Ds IF YESe LISI'ISCNRGE PERIODS IQs/DAY HL,/DAY SA NI TAR Y ABS PON D FLOW RATE WASTEWATER JZKSQQF 1 CONTACT COOUNG 2 NONCONTACT COOL NG 3 PROCESS 4 SANITARY 5 STORMWATER QQE 1 MGY MGD 3 GPD ITEM2 WATER TREATMENT ADDITIVES. LINLLS CODE 1 Mg/I 2 Ug/I Es LAND APPLICATION RALE Fs TYPE OF HASLEHALER DISCNRGE G~DISCNRGE SOELXAE (YEARLY AVERAGE)o ISCHARGE FUNŽE NA INs HIe IRs DAY INs/NKs LLJ~LJ LLJ~LJ LLJ~LJ Q N U4 L3J LJ LJ LJ L-I HOURS/DAY~4 lOTAL YEARLY DAILY HINIISH DAILY HAXIISN svvlvsss*13.505~1 037 2 Je NXIILH DESIGN DISCNRGE FUN RATEs As 9)YOU USE'KATER 1REAL%NL ACOITIVES TO lREAT YIR DISOHKO (LF N).COILS@YO LTLH 3)Se N%FINCTICNs AEI OEHICAL CQSKSITICN OF THESE ALSIITIVESe DESIGN 0.060 px C1 86K Calcium H ochlorite for F'ae C>>N%AIEI AZCRESS OF H4MFACLLRERS OF LIAISE AIDITIVESe VAN WATERS AND ROGERS, INC.L600 NORTON BUILDING SEATTLE, WASHINGTON 98104-156 Ls lIE NXDSN DISCNRGK FUN RATE TO SE AIIIHCRLZED IN PERIITe~LZpg p p 6 p IN I)LODE Ds EXPKTED DISCNRSE CQCEHIRATI(N OF ALOLTIVESe HINIISH INILS AVERAGE CLLK IN ITS NXIISN evevvvvs ssevv Total Residual Chlorine 0~, 0 ALOI TIVE NA%LJ s~ALII TIVE NA%Es DO%XI TREAT l%DLSCNRGE lO ROTE ALOlT1VES? Fs ISN'T IS lHK RBOVAL EFFLCL8CY AND DISCNRGE FRKLLKLCY7 ACOI TIVE NA%ALE ITIVE NA%ALOI TIVE NA%IRSs/OAY DAYS/'HK.LJ LLJ LJ LJ G, AS AN ATTACHMENT lO lHIS APPLLCATICN PROVIDE SPKIFIC HASQLIAN CR ACUATIC lOXICOUSLCAL DATA CR REFERENCE HHIOI ARE AVAIIASLE ND INRRQTLCN CN lHE RATE OF DKRAMTICN OF lIE PRXXCTS FCR EACH ALOITLVEi IYISDS Attached Calcium Hypochlorite is added to the mixed liquor and is used up prior to discharge. 31 INSTRUCTIONS FOR COMPLETING SECTION I I ITEMS I ANO 2 This form requires Intormatlon on the feel I ity's discharge location, discharge schedule, volume f lov rate and water treatment additives. ENTER THE PERMIT NUMBFR IN THE BOX AT THE TOP OF THIS FOFM.THE PERMIT NUMBER CAN BE FCUNO ON THE FRONT PAGE OF YOUR EXPIRING PERMIT.If this Is a nev or not previously permitted facility, then leave blank and a number wll I be assigned.Enter the outta II number In space provided for each page o!Section II.For each Individual discharoe point a separate set of Section II forms must be filled out.ITEM I DISCHARGE LOCATION SCHEDULE AIO FLOW RATES A.Enter the location of discharge, this should Include quarter-quarter section, quarter section, section.(own, and range.B.List name of receIving water (if surface water discharge). C.IndlCate whether taCi llty dlSChargeS On a SeaSOnal baSIS.O.If yes, list discharge periods.E.Provide the land application rates used or expected to be used In terms of Inches per hour, hout s per day, and Inches per v<<k~F~Indicate the type of wastewater to be discharged from this outfall.Refer to the wastewater type code given In the left margin.More than one code may be appl lcable.G~Provide the average nuxber of hours per day In which the facility dlschargeS treated wastewater and the total nmxber of days per year In which the discharge occurs.H.Provide current (from the Inst l2 months)or expected flow rates as requested. Refer to unit code qlven In the left margin~for the appropriate flow units.MGY-million gallons per year;MGO-million gallons per day)GPO-gallons per day.I.Provide the maximum discharge flow rate which you vent to have authorised within the permit.NOTE: For NPOES permits only.the use of such a flow rate will not place an actual limit restriction on the tlov but will be the flow rate used to develop etf (vent limits.Also, when the Monthly Operating Reports are reviewed by Compliance staff It vill help tham to determine It any nev or increased uses might have occurred at the facility.J.Provide the design flow for this specific outfall discharge (e.g.batch treatment system flow, packaged treatment system flow.or scme other finite treatment system flow).ITEM 2 WATER TREATMENT ADO ITI YES A.Indicate whether discharge Is treated with conditioners, Inhibitors, or mlcrobloclde. If not, continue to Item 3.B.Give name, function, and chemical ccmposltlon of additives used.C.Give name and address of the manutacturer(s) ot the additives used.o.Indicate expected mlnlxxxn, average and maxlaxxx discharge concentrations of the additive(s) tor this discharge. E.IndiCate vhether yOu treat the d(SCharge tO remOVe the addltlVe(S) betOre diSCharge Of WaSteVater. F.Indicate the removal ettlclency of each additive t(xxx the vastevater and the discharge frequency of each additive to the surtace water or groundwater. G.NOTE: It Is the responSlblllty of the applicant to supply the product Information as requested In this Item 4.Information requested but not supplied may result In the application being returned to the applicant for completion. 32 VAN WAXEfis b ROGERS XNC.NhrERXAI,".,AFE'l Y nhrA:-"HEEr REF'('.)BT NLJI"I BE R: 971 NSD!)H(3: PG0310 I EC I I VF.DATE: 06/21/93 PRODl)C r l CAI (.,XUN HYPOCHL(3RITE GRANI)I,.AIR f'A(3E.', 001 Vf:.RSIQH: 004 (3RDER HQ i P RQI3 HO VAH WATFRS 6 ROGERS INC., SLJBSXD3:ARY (3F UNXVAR 6100 CARXLI ON P(3XNT KXRKLAHD (20/>)889-3400 , WA 98033 ENERGENCY AS,.X.TAHCE F(3R ENERGENCY ASSXSTAHCE INVOI.VXNG CHFiIXCALS CALI.-CHENTREC<800)424-9300 FOR PRODUCT AND SAII=S XNFORNATION CONTACT YOUR LOCAI.VAN WATERS h, ROGERS BRANCH OFFICE AT VWbR SOUTH.BEHD 219-289-0321 SOUTH BEND, XN PRODLJCT NANE: CAL(::XUN HYPOCMI ORITE GRAHLJLAR NSDS e: F GO31O CALCIUN HYPQCHLORXTE GRAHLJLAR D A T I=:.'.'~7"05)',:L6'I',93'i "',.'-,-'i."i TRADE NANE i,"..'.CAI..CXUH,'.HYPQCHLOR I TE 6 RANlJLA R (".HEN HAilE/SYH~,".GAL;QYPP,' PXTTCLOR, IN13(JCL(3R, REPAK, ZAPPIT CHENXCAL FANXLY~i-' .:-"-'YfOCHLORXTE FQRN(JLA: CA(OCL)2 CAS HUNBER: 007778-54-3 (J.S, DOT SHIPPING NANE i CALCIUN HYPQCHLORXTE, HYDRATED U,S.DQT HAZARD CLASS: 5.1 (QXXDXZER) SUBSIDXARY RISK H/A X.DE NUNBFR: LJN2880~~~~KXHG GROlJP: XX.ORT*BLE QUANTITY: lo LBS/4.5 l<G XNQ DESCRXPTXON: GAL CXUN HYPOCHLORXTF, I-IYDRATED, CLASS 5.1, UN2880, PACl<XHG GRQlJP XX, RQ, INDG CODE PAGE 5138,

r~a~.i.-.J'1 VAN WATI:.RS~r<(3('ACERB XNC.HATI'."RIAI... SAFETY I)ATA Sl-IEFT RF,P(3RT Hi,)FBI'-"R: 97:I.i(SI3S H(3: P60310'~'CTX VE DATE: 06/2i/93 PR()i3(J(;,T; CALCXIJH HYPQCHLORXTE (3(<AHIJl AR PAGI.'>Oc'FR') X(lid;ORDER Nn: PROD HG SE(JTXOH].-PHYSICAL DATA l3(3II.XNG P(31NT 6 760 HH I-IG: VAPOR DENSITY (AIR=::i): 8 P E C X F X C 6 R A V I T Y<H 2 (3'-'-I): PH GF SGl.UTXGNB: FIEEEZXN(3/HELTING POINT: SOLUBILITY (WEIGHT%XN WATER): DEC(3HPGSES m ceo C H/A H/A ALKALXNE N/A 21 7 G/L 8 27 C BULI<DENSITY: VOLUHE%VOLATILE: VAP(3R PRESSURE: EVAPORAT3:QH RATE: HFAT OF SQLUT ION: APPEARANCE AND ODOR: WHITE POWDER WITH~~65-67 l.BS/CIJ.FT, H/A N/A H/A SLXGHTI.Y FXOTI-Il"-..RHIC SLXGHT CHLORINE ODOR SFCTXOH 2-XNGREI3XENTS HATERXAL CAI CIUH HYP(3CHI ORXTE<65%AVAXLABLE CHLORXNE)XHERT (XHCLUDES 5 i-l0%HOISTURE)PERCENT 65 35 SECTXGH 3-FIRE/EXPLOSION HAZARD DATA PLASH POINT<NETH(3(3..USEb)P, NONE FLAHNABI F LXHITG;'XN'g'l,R< ('%BY VOLUHE)UEL: N/A EXTXNGUXSHXNG IREDIA: WATER ONLY!SMOTHERING INEFFECTIVE-PRGDIJCT SUPPLXES OWN OXYGFH SPECTAL FIRE FXGHTXNG PRO("EDURES l F I RE F I GI-ITERS HUST WEAR HXOSH/HSI-IA AP P ROVED, P REBBURF DEHAN 9 SELF-CONTAINED 'RFATI-IXNG APPARATUS WITH F ULL FACE PIFCE FOR PQSSXBI E EXPOSURE TO.AZARDOUS GASES.UNUSUAL FIRF AND EXPLOSXON HAZARDS: DECOMPOSE, AT 1SO C RELEASING OXYGEN GAS I CONTAINERS HAY RUPTURE. VAN WATERS X RQGEI<,":> XHC, MATERIAL SAFETY DATA Sl-IEI"'T REr>OVT NI>>IeEf.HBI'IS>.HO: P(303'l0 2"E(;TIVE DATE: oe/2X/93 PRODIGY(;T; CALCIUM HYPQCI<LORITE GRANULAR f>A(>>['00'3 VERSION.'0II ORDER NO: PROD NQ SECT ION 0-I.IFAI Tl-I I IAZA RI3 DATA TOXICITY DATA;I.,C,.r0 X HI-IALAT X OH: L I350 DE IRIDAL: SKIN/EYE IRRXT*TXOH: L l350 INGI'=ST I (3N;FXSI.I,LC50 <LETHAL COHCENTRATXON): <RAT)HO HORTAI..ITY 8 3~5<IPABBXT)>1.000 HG/KG SEE SECTXON 5 SLF t (I X(3N TLH 96 HR.: 3.0-i PPH HG>/L<J.I.IR)CI.ASBXFICATXON; XHHALATIQH: IRRXTATXHG Sl<XH: SLIGHTLY TOXXC BI<IN/EYE: CORROSIVE'I:HGFSTXOH: SLXGHTLY TOXIC AQUATIC: HXGHLY TOXIC:.i>)Bi'>ri-SECTION 5-EFFECTS (3F OVEREXPOSURE XB CHEHXCAL LISTED AS A C*RCXHOGEH OR POTEHTTAL CARCINOGEN: NTP-HQ XARC-NQ OSHA-NO HEDICAL COHDXTXOHB GENERALLY AGGRAVATFD BY, EXPOSURE: NONE KNOWN PERMISSIBLE EXPBQQURP LXHXTP'I~HONE ESTABL'AAEI3J">8&~6%H'AN:Cv,(-,"'ACGIH FOR THIS PRODUCT, P P6 INTERNAL'~~KPHX'.4,B;I,"BE".E/EXPOSURE L X HIT<I PEL): 3.HG/CU~8., 8-HOUR TWA<TTNE UExl>'HTEogASER>tBEi>'ig2 NB/BU.N.BTEL (BNl>RT-TERN FxPQBURE LTNTT>.X HI-IALAT X OH: X HHALAT ION OF CALC IUH I.IY POCI.ILO R X TE DUST AN D DE POSITION OF PARTICLES XN Tl-IE RESPXRATORY TRACT CAN I EAD TO IRRXTATIOH OF TIIE TISSUE AND CAUSE A VARIETY OF EFFECTS~Tl-IESE EFFECTS ARE DEPENDENT OH CONCEN-TRATION*NI3 XH(>>l IJDE: UPPER RFSPXRAT(3RY TRACT TRRXTATXON, NASAL CQHGES"-TXON, CQU(>HING, BORE THROAT, LARYNGITXS AND Sl-IORTHEBS QF BREATH~IH~~'E RAT XOHS WHE RE Tl-IE RE ARE HX GI-I CONCI"=NT RAT XOHS OF RESP I RA BLE PA RT XCIJ-.ATES, PULHOHARY EDEIIA<FLUID IN THE LIJHG)NAY fIE PRODUCED~IF NOT TREATI=D IHNEDXATI-"LY, PULHONARY EDEHA CAH BE LXFE THREATENING. SXHCF TKXS PRODUCT XS XN GRANULAR FQRN, PARTICLES QF'ESPIRABLE SIZE ARE NOT (.rF.NFRAI I.Y ENC(3UN TERED, 3 VAH WA l i".-.:RS 6 ROGERS IHC.MATERIA(.. SAP E r V DA rA STREET REP()RT N(JMBEre;9ZX MSDS N(3'.PG033.0 l'E(ITIVE DATE: 06/21/93 PRQDU(:T: CALCIUil IHYPQCIII (3RXTE Gl,AH(JI..AR PA()ED 004 VER<<:3(3N; <:~')ORDER HO: P RQI3 HO EYF/8 I<XH: CALC IU>f HY P..)CM(.Q RITE X S COR RQS EVE TC)Tl IE EYES~CONTACT OF CALCIUM ((YPOC())ORXTF DU.'.T WXTW TJ<E EYE,>, EVEN A MXN(JTE AMOUNT FOR A SIIORT DURATXQN, CAN CAUSE SEVERE XRRXTAT~IOH AND EVEN BLINDNESS~CONTACT WX TIN Tl-IF 8 K XH MAY CAUSE,>>EVE RE I RRXTATX(3H, BURHS, QR TISSUE DFSTRUCTXOH, XN STUDIES UTIL lZXNG RABBXTS, TI-JE,.l<XH IRR1TATXQN SCORE WAS 8/8 AHD Tl-IL.EYE XRRXTATXQH SCQRI:.."WAS 98.5/1:LO.TidE CLASSXFICATXOH FOR BOTH Ol=THESE XS CORRQSXVF~XHGESTXQN: CALCIUM I.IYPOCIILQRXTE, XF SWALLOWED, CAUSES SEVERE BURNS TO Tl-IE DIGESTIVE TRACT AiHI3 CAN BE FATAL~4+-='HRONIC:.4 g GEHQTOXICXTY: CALCIUM I-IYPOCHLORXTE PRODUCED POSXTIVE RESPONSES IN'L~~XH-VITRO ASSAYS USING BACTERXAL SYSTEM)<TI-IE AMES TEST>AND CHROMOSOMAL 3FRRATXQNS IH CHINESE)HAMSTER FXBRQRLASTS. XN A WHOLE ANIMAL EXPERIMENT <MOUSE MICRQHUCLEUS TEST), EXPOSURES RANGIHG FROM 20 TQ 160 MG/l<G PRODUCED NQ COMPOUND RFI ATED CHROMOS>(3MAL ABNQRMAI.XTXES, CARCINOGEHISIS: ALTHOUGI-I HO STUDY llAS BEEN COHDUCTED WITH CALCIUM HYPOCHLQRITE, THE CARCINQ(GENIC POTEHTXAL OF SODIUM HYPQCHLORITE WAS STUDIED IH F344 RATS.AFTER 104 WFEKS OF DRXHKXNG WATER CONTAINXHG UP TQ 000 PPM SODXUM HYPOCHLQRITE, THERE WAS NO FVXDEHCE THAT THIS CHEMXCAl PRODUCED ANY CARCXNQGEN3;C RESPONSE~XN ADDXTXON, TI.IIS EXPOSURE DXD NOT RESUI T XN ANY ADVERSE EFFI."CTS IH BLOOD, CLXNXCAL CHEMISTRY, OR QTI.IER TARGET ORGANS.ONE OF THE MAJORUSES.OQ,.CALCIUM I-IYPOCI-ILORXTE XS AS A SOURCE QF CHLORINE FOR MATERt"SAN1jT'ItZAjTLXOH" X>i+i,DRXNI(XNG ANI>IXECIEEATXONAL MATER BTMOXES IIAVE IIEEN CONGO/YES.jlOrt'P+TERHXHE, TIRE L.ONG-TERH EFFECTS OF CHLORXNATEO ORXNKXNG MIJTERi+SEVE(I'::GLENEKRATXONB OF IEATS MERE GXVEN:l00 PPH CHLORXNE IH THE I R DR>I'NKX'$9gQATjER',+'HO D 3: FF E REN CF..IN FF RT IL IT Y, G ROWTH, 8 LOG D PARAMETERS',PgŽQR~~+PEGXF~LC-O'RGAN TQXICXTY WAS OBSERVED BETWEEN CONTROL ANI)EXPOSED AHIMAi"S'".--"k~iWOiSEPA'RATE ANIMA(STUDIES CONDUCTED BY DIFFERENT GOVERNMENT AGENCIES l3ETERMXNED THAT THE CHLORINATION OF MUNICIPAL DRXHl<XHG WATER DXD HQT RESUI T XN TQXXCXTY TO TIIE DEVELOPXHG MOUSE FETLJS SAF(=HAHDLXNG OF Tl-lXS MATERIAL ON A I QHG-TERM BASIS SHOULD EMPHASIZE MXN3:MIZXHG REPEATED ACUTE EXPQSURFS. EMERGENCY AND FIRSV hID f RQCEDURES IHHALAT ION: REMOVE TO FRESH AXR, XF HQT BREATJ-IXHG, G1VE ARTXFXCXAL RESPXRATXQH, VAH WATERS>b fkf)(3r:,,P('.> IHC MATERIAL sAFFTY DA(A sl<r:::~::r rcEr f)R i NUMBER: Ms (3$Ho: P60310 t'(., (: i'I VE DATE: 06/21/93 PROI3(J(,T; CALCXUM HYPOCHLORITE GRANU(...AR PATE: 0(>".:i Vl: R lx()N'04 f.)R DER Ha: P ROI3 Ha PREFERABl,.Y MOUTl(-Ta-MOUTH.3:F BREATI(IN2 >DXFFICULT, GXVE OXYGEN.CAI.L A Pi'IYSXCIAH ~EYE OR SKIN CONTACT: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, WHXLE REMOVXNG (.;(3HTAMIHATEI3 CI OTHXH(3 AND.>I.IQES.F(3R EYE CONTACT, GET XMMEDIATE MFDXCAL ATTENTION. XF SKXN XRRXTATXON OCCURS, GFT MEDXCAL ATTENTXQN. IHGLST ION: 3:F CQHSCI()US, DRXHK LARGE QUANTITIES OF WATER AND AHY COMMON Caa(<I46<VEGETABI E>OIL, IF AVAXI ABI E.Do H(3T XHDUCE VOMXTXHG.TAKE IMMEOXATEL'Y Ta A HaspxTAL are f HYsxcxhN~xF uNcaHscxaus, OR xN coNvuLSXOHS,:,TAi<F...'MMEDIATELY To A HOSP ITAl.Do NOT ATTEMPT To INDUCE VQM X TING OR-,;GIVE',;, AHYTHXHG BY MOUTH To AN UNCONSCIOUS PERSON.NOTES To PHYSXCX*N<INCLUDING ANTI(30TES): TREAT SYMPTOMATICALLY, SECTI(3N 6-REACTXVXTY DATA STABII.XTY: UNSTABLE coNDxTxaNs To AvnxD: CONTAMXNATION OR EXCESSIVE HEAT ABQVE 177 C HAZARDOUS POLYMFRXZATION: WXLL HOT OCCUR COHDXTIONS Ta AVOID: NONE-WXLL NOT POLYMERIZE X H(.;0M PAT I 8 IL, X'TY....<'8AYERX'Al",g'(-"TO;,A Vo I D): ACIDS, COMBUSTXBL'E'. MATgRIAt S, ORGAHXCS, REDUCING AGENTS HAZARDOUS DECOMPOSITION"PRQDQCTS: ACIDS OR AMMUHQQ:~CQNIQQXHA'TXON WXLL RELEASE TOXIC GASES, EXCESSIVE MEAT WXLL CAUSE.DFLOMPPSX'TX(3H RESULTING XN THE RELEASE OF OXYGEN AND CHLORINE GAS~SFCTION 7-SPXLL OR LEAK PROCEDURES Ps To BE TAKEN XF MATERIAL XS SPXLLED OR RELEASED:.QTE: USE EXTREME CAUTXON XN HANDLIHG SPXLLED MATERIAL~CQNTAMINATXON WITIH ORGANIC OR COMBUSTIBLE MATERIAL MAY CAUSE FIRE OR VXOLENT DECOMPQSXTION. XF FxRF aR DECOMPosxTxoN OccuRs xN ARFA aF SPILL, xMMEDxATELY DousE WxTH PLENTY OF WATER.OTHERWISE, SWEEP UP ALL VXSIBLE MATERIAL USXNG A CLEAN, DRY SI.IQVEL AND BROOM AHD DXSSOLVE MATERXAL IN WATI=R DISPOSE OF WASTE MATERIAL AS VAN MATE R!')A R(')(E I'<s I Hr'..MATr,:.RIAL IAFETY DATA.: 1<F<I PEP()RT NUMBER: 971 MS I.')!3 H(3: PG0310"E(: TI VE l3ATE: 06/21/93 I'R(39(.JCT: CALCXUM HYPOCHLORXTE (3RANUI.AR PA(',~i".: 00/)Vr;::RSXGN: 004 ORDER HG: P R(30 HQ ()UTLXNEO BELOW.WASTE DXBPGSAL METHOD: ,":)PILLED MATERXAL TI.IAT I.IAS BEEN SWEPT (JP AHO DXBSOLVED XH WATER SHOULD BE IJ, ED XMMEDXATELY XN THE NGRMAl APPLXC*TXOH FOR WHXCH CALCXUM HYPGCHLGRITE XS BEING caHSUMEO XF THIS Xs HOT POBS1BLE:, CAREFULLY NEUTRALIZE DXSSGLVED M*TERXAL BY ADDING HYDROGEN PEROXIDE (QNE PXNT OF 35/HYDROGEN PEROXIDE SOLUTIQN PER POUND OF CALCXUM HYPGCHLQRITE To BE NEUTRALIZED) THEN DXLUTE THE HEUTR*LXZED MATERXAL WITH PLENTY GF WATER AHD FLIJBH TO SFWER.NGTF.: ONLY PROPERLY NEUTRALIZED MATERXAL SHOULD BE FLUSHEI3 To'E:WER.UNNEUTRALIZED M*TERXAL CAN CAUSE EHVXRONMEHTAL DAM*BE To RECEIVlHG WATER OR CAN INTERFERE WXTH TREATMENT PLANT OPERATION. FGR OH-SXTE NEUTRALXZATION, C*REFULLY AHD SLOWLY POUR THE APPRQPRIATF., QUANTITY GF 35/HYDROGEN PERQXXDE SOLUTION OVER ALL SPXLLED M*TERIAL THFN FLUSH AREA WITH PLENTY OF WATER.COMMENTS'ARE MUST BE T*KEN WHEN USXHG QR DXSPOSXNG OF CI.IEMXCAL MATFRXALs AHO/aR THEIR coHTAxNERS To PREVENT ENVIRONMENTAL CQH'LAMINATION. Xs YOUR DUTY Ta OXSPOBE QF THE CHEMICAL MATERIALS AND/OR THEIR L',OHTAINERS IH ACCORDANCE MXTH THE CLEAN AXR ACT, THE CLEAN MATER ACT, THE RESOURCE CONSERVATION ANO RECOVERY ACT, FIFRA, AS MELL AS ANY OTHER RELEVANT FEDERAL, ST*TE, OR LOC*L LAWS/REGULATXONS REGARDING DISPOSAL, SECTION 8-SPECIAL PROTECTION XHFORMATION RESPIRATORY PROTECTION l IF DUSTY CQNDXTIQNS ARE ENCOUNTERED, USE HXOSH/MSH* APPROVEO RESPXRATOR WXTH ACXD GAS CARTRXDGE AHO DUST PREFXLTER. THE RESPIRATOR USE LXMXTATIONS BPECIFXED BY HXO.H/MSHA OR THE MANUFACTURER MUST BE OBSERVED, RESPIRATORY PROTECTION PRQt3RAM8 M(JST BE.XH ACCORDANCE WITH 29 CFR 1910, 134.VENTILATIOH<TYPE3; HoHE, uNLESB.OusTY coNDITIGHB ARE EHcouHTFRED. EYE PROTECTION: CHEMXCAL SAFETY GOGGLES GLOVES'ATUR*L GR BYNTHETXC RUBBER OTHER P RGTECTI VE EQUIPMEHT I"ooTs, Ar RGNs, oR CHEMICAt suxTS sHouLD BE usEO WHEN HEcEssARY Ta PREVENT RXN CONTACT>PERSONAL PROTECTXVE CLOTHXHG AND USE OF EQUIPMENT MUST BF.XH ACCORDANCE MITH 29 CFR 1910, 132 ANO 29 CFR 1910.133, VAH WATERS A ROGERS 1H(::, MATERXAL SAFFTY D*TA BHFET REPORT HI JM BE R: 97 i MSDS NO: PG03i0" ECTIVE OATEN'S/~i/93 I ROD(JCT: CALCXUM HYPQCHLQRXTF GRAH(JLAR PA(3E: 007 VERSION: 00<ORDER HO: PROD NO SECTION 9-SPECIAL PRECAU'1'XGHB PRECA IJTXGNB TQ BE TAKEN DURING HANOLIHG AND BTORXHG.'Q HOT GET XN EYFB, ON SKIN OR ON CLOTHXNG, l<EEP IN ORIGXNAL CONTAINER IN*COOL, DRY PI..ACE, KEEP CONTAXNFR CLOSFD WHEN NGT IH USF..KEEP AWAY FROM HEAT SOURCES, SPARKS, OPEN FL*MES AND LXGHTEO TOBACCO PRODUCTS.USE ONLY A CLEAN, DRY SCOOP MADE QF METAL OR PLASTIC EACH TXME THXS P ROD(JCT XB TA I<FN FROM CON TA INF R, DO HOT*OD THIS PRODUCT TO ANY DISPFNSING DEUICE CONTAXNING REMNANTS OF*NY OTHER PRODUCT'.SUCH USE MAY CAUSE VIQLEHT REACTION LEAOXNG TO FIRE OR EXPLOSION, ADO THXS PRODUCT ONLY TO WATER MAY CAUSE FIRE OR EXPLOSIOH XF MIXED WITH OTHER CHFMXCALS. FXRE MAY RESULT XF CQHTAMIHATEO WITH ACIDS OR EASILY COMBUSTIBLE MATERIAL SUCH AB OXL, KFROBFNE, GASOLINE, PAINT PRODUCTS AND MOST OTHER ORGANXC MATERXALS, WASH HANDS AFTER HANDLXNG DO NOT REUSE CQNTAIHER, RESIDUAL MATERXAL REMAXHXHG IH EMPTY DRUM CAN RE*CT TO CAUSE FIRE, THQROUGHI Y FLUSH EMPTY CONTAXNER WXTH WATER THEN DESTROY BY PLACXNG IN TRASH COLLECTION. DO NQT CONTAMINATE WATERp FOOD, QR FEED BY STORAGE QR DISPOSAL.OTHER PRECAUTIONS'EEP GUT OF RE*CH QF CHXLDREH STRONG OXIDIZER-FXRE MAY REBUL.T FROM CONTACT WXTH HEATi ACXOSp ORGANXC OR CQMBUSTXBLE MATTER.MAY BE FATAL OR HARMFUL XF SWALLOWED, MAY CAUSE ("HEMXCAL BURNS.XRRXTATXNG TG HOSE AHD, TlfROAT-AUQXD BREATHIHG DUST, COMMENTS: TSCA-CALCIUM HYPQCHLQRXTF. XS QN THF TBCA INVENTORY UNDER CAB e777e-S4-3 ~SARA TITLE XXX-A)3ii/3i2 CATEGQRXES -ACUTE AHD REACTIVITY, 8)HQT LISTED IN SECTION 3i3, C)NGT LXBTED AS AN"EXTREMELY HAZARDOUS SUBST*NCE" XN SECTION 302, CERCLA-LXSTED XN TABLE 302.4 QF 40 CFR PART 302 AS A I"IAZARDQUS SUBSTANCE WITH A REPORTABLE QUANTITY QF i0 POUNDS RELEASES TQ AXR p LAND QR WATER l'HXCH EXCEED THE RQ MUST BE REPORTED TQ Tl-1E NATXONAL RESPONSE CENTER, 00-<2~-SS02. RCRA-WASTE CALCIUM HYPOCHLQRXTE AHD CONTAMXNATEO SQXLS/MATERIALS FROM SPILL CLEANUP ARE 000K HAZ*ROOUS WASTE AS PER 40 CFR 26i,2i<A)<4)AND MIJST BE OXSPOSFD OF ACCORDXHGLY UNDER RCRA, VAN WATE RS b RO()ERB XNC.HATI.=..RIAL SAFETY l3ATA SHEET RE(OR r NUMBER: 971 HSI3S Nn: P(-'0310""'CTXVF.DATE: 06/2i/93 i R(3DUCT: CALCIUM HYPOCHLORXTE (iRANIJI..AR PAGE: 008 VERBJQN: 004 ORDER NO: PROD NG F1FRA-CALCXUH HYPOCIILQRITE XS REGISTERED WXTH EPA AB A PEBTICXOE~NSI'=-PPG CAI CIUH HYPOCHI GRITE IS CFRTIFXED FOR HAXXMUH USE AT 46 HG/L (JNDER ANSI/NBF STANDARD 60, REVXBXQNS HADE TO 7/28/92, 3RD EDXTXQN: D*TE, EDITXON, AODITXQN QF NBF STATEMENT. FOR ADDITIONAL XNFORHATION HL CONTACT: HSDS COORDINATOR VW6R SOUTH BEND DURING BUSXNESS HOURS, PACXFXC TIME 02/:L7/94 12:21 PRODUCT: CUST NO: A<206>889-3406 'ORDER 8{3.('F."----NOTICE VAN WATERS b, ROGERS INC, ("VW6R")EXPRESSLY DXSCLAIHS ALL EXPRESS QR XHPLXED WARRANTIES QF HERCHANTABXLXTY AND FITNESS FOR A PARTXCULAR PURPOSE, WXTH RESPECT TQ THE PRODUCT QR INFORM*TIQN PROVIDED HEREIN~**ALL XNFQRHATION APPEARXNC HEREXN XS BASED UPON DATA t3BTAINED FROM THE H*NUFACTURER .,AN0$05>>.RFCOLGNXZED TECHNICAL SOURCES WHXLE THE XNFORHATXQN 18 BELXEVEO TQi jgg".':-'QCCl'lRA fF'j","VLfhR'AKES NO REP RESENTATXONS

• S TO XTS ACCURACY Q R SUFFICIENCY C(NOXTT0$

8'F,: Ui>>PE ARE BEYOND VWARS CONTROL AND THEREFORE USER,.ARE RESPONSIBLE",'O" VEQXFY TtgPXB'AT* UNDER THEIR QWN OPERATXNG CGNDXTXONS T(3 OETERHXNE WHETHER,,'-TflF':,PPUDUCl'.,'XS BUXTAB1 E FOR THEIR PARTXCULAR PURPOSES AND TI.IEY ABSUHE ALL';RIQICS";OTF!,'THEIR.,:USE~ H*NOLING,*NO OXBPOBAL OF THE PROOUCT, OR FROH THE PUBLXCALTXON;,:OR','USE'F.,::.GR'ELIANCE UPON, XNFORHATION CONTAINER HEREXN.THIS INFORHAT1ON" RELATES'NLY TO THE PROOUCT OEBIGNATEO HEREXN.ANO OOEB N(XT RELATE TQ ITS USE XN COHBINATXON WXTH ANY OTI.IER MATERIAL OR XN ANY OTHER PROCESS'+ENDQFHSDS*a.*

SEE INSTRUCTIONS ON REVERSE SIDE SECTION fl PERMIT~IYI1 0005827 NUMBER IEM 3 As NatE OF PROCESS CONTRIBUTING TO THE DISCHARGE TNOUSI THIS OUTFALL Ate SIC CODE Be PRXESS SCHEDLLE (YEARLY AVERAGE)~OO E SANTTARYW TER 4911 PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE Ch CO Cit Os 0 CE CL Ce PRCCESS ICCSTEHATKR FLD/I RATE De PROCESS PRODUCTION RATE N/A TOTAL YEARLY DAILY MINIt/LTC DAILY HAXIttti 8 5 7 7 wIT~0 11~6 037~6 WITS i TI%~LJ 1 POUNDS 2 GALLONS 3 CUBIC YARDS 4 TONS 5 MGY 6 MGD 7 GPD TIME 1 HOUR 2 DAY 3 WEEK 4 MONTH 5 YEAR C/I Oili 0 Ae NA%OF PROCESS CONIRIBUTM TO TIE DISQCLRGE g/A TIRLXXIH THIS OUIFALL Ate SIC CODE B.PROCESS SOGXIE (YEARLY AVERAGE)C.PROCESS HASTEHATER FLDH RATE ReCESS PRODUCTICN RaTE A'E oF PRxEss coNIIBUTIID To TIE DlscHARGE g/A TIROUGH lHIS OUTFALL AtCI SIC CLXE Be PROCESS SQEDLAE (YEARLY AVERAGE)Cs PROCESS HLSTEHATER FLDH RATE De PROCESS PRODLCTI ON RATE As NAIE OF PROCESS CONTRIBUTING TO TIE DISCHAR%g/A TH Ate SIC CLXE B e PROCESS SQEDLLE (YEARLY AVERAGE)Cs PRXESS HASTENCTER FLDH RATE esses/sev~ssvs/vses TOTAL YEARLY DAILY HINIIRII DAILY I/AX IPLPI TOTAL YEARLY DAlLY HININtl DAILY HAX It%PI TOTAL YEARLY DAILY HI HI%PI WITS/TIIE WITS PTltE WIT CODE CO CE CL De PROCESS PteDUCTION RATE Hat%oF PtecEss coNIRIBUTING To TLE DlmARGE g/A TIROUIH lHIS OUIFALL AND SIC CODE B s PRXESS SCHEDLLE (YEARLY AVERAGE)Ce PROCESS HASTEHATER FLOH RATE De PRXESS PRODUCTION RATE DAILY HAXI MM TOTAL YEARLY DAILY HINIIEtl DAILY HAXItLPI ssvs/vsse WITS MIHK WIT CODE W~NITS TIIE 33 INSTRUCTIONS FOR COMPLETING SECTION I I ITEM 3 Tr is form requires Information on the proceas streamS which contribute to this discharge. ENTER THE PERMIT NLSIBER IN THE BOX AT THE TOP OF THIS FORM.THE PERMIT NISIBER CAN BE FOUhTI ON THE FRONT PAGE OF YOUR EXPIRING PERMIT.If thlS IS a naw Or nOt PreVIOuSly Permitted faClllty, then leaVe blank and a number<<ill be aSSlgned.Enter outfall number In space provided for each page of Section II.For each Individual dlscharce oint a separate set cf Section II forms must be filled out.PROCESS STREAMS CONTRIIRITING TO DISCHARGE: FOR EACH SEPARATE PROCESS PROVIDE THE FOLLOflf6 INFORMATION A.Enter the name of the process<<hlch contributes to this discharge. Also provide the proper SIC code.B.Indicate the yearly average process schedule In hours per day and days-per-year. C Provide the process wastewater firn rate Information as requested based on your last l2 months of operations'efer to unit coda given in the left margin for the appropriate flow units.D.Process ProductIon Rate-Certain permit limitations may be based on production rates.The production rates used to determine permit limits shall be represented by a reasonable measure of actual production of the facility, such as the production during the high month of the previous year, or the monthly averaqe for the highest of the previous five years, or Other reasonable measure as stated in applicable U.S.E.P.A. categorical rules and regulations. For new sources or new dlschargers, actual production shall be estimated using proJected production. Record your production rates In the terms and units used In the applicable U.S.E.P.A. categorical rules and regulations for your type of facility.34 SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I NUMBER~EM 4 GROUNDWATER DISCHARGE INFORMATION Ae IS THE DISCHARGE FROM THIS OUTFALL DIRECIKD TO lHE GRa5D OR GROQCWATERS?(IF%A COttTINK TO ITEM 0)Be HAS A HYDROGEOLOG ICAL STUDY OR ITS EQUIVALENT BEEN PERFORMED OR IS THERE BIFF ICI BIT CURRENT HYDROGEQLQGICAL INFORMATION AVAllABLE AS REQUIRED BY TIE HATER RESIMICES atttlsstON PART Z2 GRONIDtATKR RIAES OF AuiUST ltlo 19%RI525.2207 (PAGE ILI)FOR THIS EXISTI%OR PROPOSED DISCHSRGET IF YES ATTACH A CCPY CF THE REPORTS Ce ARE YOU REIXEST1%AN EXB1PTION FRCM SIBIITTI%A HYIIIQGEQUXIICAL REPORT%DER RLAE Re323AZR7 (19}(PAGE Q)OR FROM GRIXNDtATKB tCEIIIORI% IIEOU)RBIENIS WDER RULE Re525IZdS (5)(PAGE+OF 1%PART 22 RLLES~IF YES ATTACH DQat6ENTS AND EXPIANATICN TO DBXINSTRATK THAT VIX'ISCHARGE MXAD QUALIFY FOR AN EXBf lONe De ARE YOU RBXKSTI%A VARIANCE FIOI RULE 323e2205 (PAGE P (tOteEGRADATION) OF THE HATER REstxwcEs cctt11ssIQN PART 22 GRQNIDIATER RILEs?IF YKS, ATTAOH SUOH DOQHBITS AS NECESSAlÃTO DEMONSTRATE TIE NEED FCR A VARIANCE IN TERMS OF TIE CRITERIA SPECIFIED IN RIAE 525e2210 (PAGECF 1HE PART 2Z RRESA Ee I,IST Alp.CHEIIICAL SIBSTANCES HHICH ARE IN MICHIGAN S CRITICAL MATERIALS REGISTER TABLE IV LPAGE D)AND/OR Uese EPA'S PRIORITY POILUTANT LIST TABLE V (PAGE 7)OR ANY mtER SIBSTANCES ttIICH ARE CR HAY BECOME IMHIOUS TO TIE EESIGNATKD USES OF 1%GRXMlATKR OR TO THE PUBLIC%ALTH lHAT ARE DISCHUIGED OR EXPECTED TO BE DISCHARGED TO TIE RQXLIKX6ATKRAY 1HIS FACILllYe ESTIMATE THE FINAL EFFLUENT CONCENIRATIIXI ND RECORD ALL DATA IN ITBI 7 OF SECTICN II IN 1HIS BOOILETe TIE APPLICANT HAY BE RECUIRED lD DO AIXIITIONAL HASTE ANALYSESA~OO E Eg YES X.S, Submitted 12/6/91 YES X a-NOT APPLICABtx/BELIEVED ABSENT PRESENTS DATA PROVIDED IN ITBI 7 El ITENI 5 EXPECTED WASlEWATER CHARAC-UNETS CODE 1 MQ/I 2 UQ/I 3 COUNTS/100 ml 4 S.U.5 F 6 LBS/DAY Ae DISCHARGE CHARACTERISTICS 'TOC (TOTAL ORGANIC CARBON)AtfCNIA NITROGEN (AS N)TOTAL SUSPB4KD SOLIDS TOTAL PtDSPHOftUS (As P)TOTAL RESIIXIAL OUNINE DISSOLVED OXYGEN MIN~6~4 FECAL COLIFORtl BACTKRIA'TBmmltttE (sums)79%%RATINE (HINIKR)BQOI3 (FIVE DAY BIOCteIICAL OXYGEN DEHAIB)COD (CtetlCAL OXYGBI DEMAND)CCNCENIIIATI ON AVE HAX~40.~05~99.~6~~~QJ~ELlZ~~~5.~55'11 6,~0~73,~03 6~12.~05 LLJ~LJ~~LJ Be OTHER HASTKHATER CHUIACIKR I STICS WITS CODE 0 ANALYSES SAtPLK TYPE COCE u1~l 2~60~1~1 1 3~3 u3~RAMP E ZXBE 1 GRAB 2 24 KOUR COMPOSITE 0 I L S G R E A S E n'c 1 cc.~65 ,~56~20 8,~0 LJ~l~65 RBXIIRED IIFOWATICN FIERY SINFACE HATER DISCHARGESe INSTRUCTIONS FOR COMPLETING SECTION I I ITEMS 4 ANO 5 This tom requires Information on s specific outfall discharging to either the groundwsters or the surface waters.ENTER THc PER4IIT hlPIBER IN THE BOX AT THE TDP OF THIS FORM.THE PERMIT Nl+IBER CAN BE FOUND ON THE FRONT PAGE OF YOUR EXPIRING PERMIT.If thlS IS S new Or nOt preVIOuSly permitted faCI llty, then lenVe blank Ond O number<<II I be SSSlgned.Enter the outfall number In the space provided for each Doge of Section II.For each Individual disehsroe point a se arete set of Section II forms (Items 4 and 5)must be filled out.ITEM 4 GRCUNDWATER DISCHARGE INFORMATION (00 NOT INCLUDE DEEP WELL INJECTION INFORMATION IN THIS ITEM)A.-D.The applicant shall address each of these parts If the discharge trcm this outfall Is to the qroundwoter. ITEM 5 EXISTING OR EXPECTED (FOR A NEW DISCHARGE) WASTEWATEP CHARACTERISTICS OF GROUNDWATER OR SURFACE WATER DISCHARGE (DO NOT INCLUDE<<LL INJ I N IN N H A.The applicant shel I report nvni lable discharge data (real data for existing discharge or expected dots for n proposed discharge) for the Darnmeters as listed.These parameters shall be addressed for either a surface rater discharge or ss aDDroDrlate for s groundwater discharge. For assistance In determining appropriate parameters a ground~ster discharoe applicant msy contact the Groundwater Duality Division, permits Section or the appropr late Groundwater punl ity Division's District oftlce.The applicant shall i'eport the sample type code best describing each reported piece of dots.see coding on the left margin of this tofm If this outfall Is n surface water dlschsrqe, the applicant must report quantitative dots for each parameter Identified b on PPI t y," , I etd 9 d h ell d p t P o.P h eo e t t be~ppd ted by deo pt tied I.d h odh e ell ept p ttp h t 0 thl pell tl B.If data Is available tor other parameters not listed above In A.or other parts of this application the applicant should reDort that data In the blank spaces provided In this part.<OTESt I.Unit codes for parameters reported In ports A snd 8 cnn be found on the lett hand side of this tore.2~Grab Snmole Shel I be uSed tO SnolyZe far PH, temperature, tOtsl PhenOIS, reSldual ChlOrlne, Oil nnd grea5e~and fecal coliform In n svrtaee water discharge unless other frequency-snmD(e type analyses are available. See Glossary (pnge 48)for definition ot grab Sample.24-hour composite samples shall be used to analyze for Total 8005, COO, TDC, Amnonln Nitrogen, and Total SusDended Solids in o surface~ster discharge unless other frequency-sample type analyses sre available. See Glossary (page 48)tor definition ot comDOSlte sample.4.REPORTING OF INTAKE DATA.You are not required to report unless yov<<Ish to demonstrate your eligibility for o"net<<effluent limitation for one or more pollutants, that Is, nn effluent limitation odJusted by subtracting the overage level ot the pollutant(s) present In your Intake~ster.NPOES regulations nl (ow net limitations only In certain circumstances. To demonstrate your eliglbl llty, report the overage of the results ot analyses on your intake water (if your<<ster Is treated before use, test the~ster ofter It Is treated), snd attach s separate Sheet contninlng the following tor each pollutant: (a)A statement that the Intake<<ster Is drown trom the body ot<<ster Into which the discharge Is mode.(Otherwise, you ore not eligible for net limitations.)(b)A statement ot the extent to which the level of the pollutant Is reduced by treatment of your wastewater .(Yovi limitations <<ill be sdJusted only to the extent that the pollutant Is not removed.)(c)When applicable (for ex(mpple, when the pollutant represents a cla55 ot compounds), n demonstration of the extent to which the pollutants In the Intake very physically, chemically, or biologically fran the pollutants contained In youi'ischarge.(Your limitations <<ill be adjusted only to the extent that the Intake pollutants do not vary frobb the discharged Do)lvtants.) 5.If you have two oi'ore substantially Indentlcal outfslls, you msy request permission tron your permitting OuthOrltv to sample nnd analyze only one outtsll nnd Submit the results of the analysis tor other Substantially Identical outfalls.If your request Is granted by the permlttlno authority, on s separate sheet attached to the SDPIICstlOn fOrm Identity WhlCh Outtall ydu did teSt, Snd deSerlbe<<hy the Outta(IS wh(Ch yOu did nOt teSt nre substantially Identical to the ovtfoll which you did test.'36 SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I PERMIT~IYIZ 0005827 NUMBER OOEeNI 6 PRIORITY POLLUTANTS aND ADDITIONAL INFORMATION FOR SURFACE WATER DISCHARGE ONLY THE FOUXHI%REQUESTED INFOIVIATION ~ADCRESSED BYJILL QJIFACE HATER DISCHARGERSI IIGIEt NKH USE Dl SCHARGERS SUB'ROVIDE EXPECTED VALIKS FOR THE QUANTITATIVE AND QUALITATIVE INFORtllT ION REQUESTED BELOhlo AI IS THIS FACILllY A PRIMLY INIXSTR(.(REFER TO TABIE IA PPl<(IF tKJ GO TO E)(IF Y S GO TO B)BI INDICATE TYPE OF PRIMARY INDUSTRY AS LISTED IN TABIE IA PAGE Q (CONTI~HITH C~)CI ICES 1HIS OUTFALL DISCHARGE CCttfAIN ANY PROCESS HASTEHATKR7 (IF NOr GO TO E)(IF YES.GO TO D)De tNDICATK ltttCH GC/MS FRACflONS tKJST BE TESTED FORe (REFER TO TABLE IA PJJ>EKQEI FOR EACH QJMS FRACTION CHECKEDr EAtH SPECIFIC ORGANIC TOXtC POUJJTAMT HITHIN EAQI FRACTION 55'K ANALYZED FOR (SEE TABLE I IA PAGE Q, IN ADDITION ALL PRINARY IMXJSTRY APPLIuWTS HITH A PROCESS HASTKHATER DISQURGE~PROVIDE QUWTITATIVE CATA FOR EACH TOXIC POLUJfANT IN TABLE lllA PN4 99 I RECORD ALL DATA ON FORMS PROVIDED (ITEM 7)IN THIS BOOKLETI (CQMTINE HITH E K BEUAt)Q YES NO STMEL'EPWR YES~X MO D Analysis per J.B.Beauboeuf D BASK/NKUIRAL Groundwater Division ACID PESTICIDE Eo IF~QJIFACE HATER DISQIARGE APPLICANT (PRINRY OR SECNIDUIY IMIXJSTRY)r REGARDLESS OF THE TYPE OF DISCHARGEr KXHS OR HAS REASON TO BELIEVE TlQT ANY POLLUTANT LISTED IN TABLE IIA AND IVA PAGKS~Is DISCHARGED FRQI AMY IXJIFAILr TIE QOWTITATIVE DATA~BE PROVIDED'EcoRD ALL DATA 0N F0RMs PRQYIDED (ITKJI 7)IN THIs BQQKLEf.F.IF AMY QRFACE lATER DISCHARGE APPLICANT (PRIMLY OR SECONDARY IMXJSTRY)r REGARDLESS OF TYPE OF DISQJUIGEr KIKXts OR HAS REASON TO BELIEVE ANY POUJJTANIS LISTKD IN TABLE VA PAGE+ARE DISCHARCM FROM AMY IXJIFALL TIE APPLICANT~DESCRIBE REASONS FOR TIE POUJJTANf BEI%PRESENT ANJ PROVIDE ANY AVAILABLE QUANTITATIVE DATAI RECORD NL KATA OM FOttts PROVIDED (ITEM 7)IN THIS BOOKLET>NOT APPI.I CABLE/BELIEVED ABSENf 0 N/A O PRESENT/DATA IS AlTACHED Q%T APPLICABLE/BELIEVED ABSENT N/A Q PRESENT/CATA IS ATTACHED GI AIL SIRFACE HATER DISC@AGE APPLICANTS (PRIMARY AMD SECONDARY INDUSTRIES) %T APPLICABLE/BEUEVKD Assatf QrVTRIQLOIIOPJE%L eTC~Pl OR HEXACtLONPIEJE ttCRPJ (AlL DATA FCR TIE ABOVE tKJST BE GENERATED US1%STANDARD AMAt.YTICAL CALISRATIIXI PROCEDIRES) CR KtKBts OR HAS REASON TO BELIEVE THAT TIXO IS CR MAY BE PRESENT IN TlEIR DISCNRGEr~REPORT tBIALITATIVE SLTAr GEJERATKD ltg IQI USED A SCREEN!%PROCEDNE%T CALIBRATED Hl'tH ANALYTICAL STANDAtmr FOR 4 5r 1 8r TKIIIAQLDRODIBENZO PDIOXIN (TCIXJ)~RECORD AIL DATA ON FORMS PROVIDED (ITBI f)IN THIS BOOKLETr Q PRESENT/DATA IS ATTAQED N/A Jr IF TIE SUIFACE HAlKR DISOIAAK APPLICANT KJKXts OR WLS REASON 10 BELIEVE THAT BIQUJGI~loxtcllY TKsfs HERE MADE IN THE Iasf TtttEE (5)YEARs QN ANY 0F TlE APPLtuWT S DISCHARGES OR ON A RECEIVI%HATER IN RELATIOtt lD A DISCHARGEr PROVIDE THIS ItAAQTION AS AN ATTAQtENT TO lHIS APPLICATIONI KI IF A CtWIIRACT LABXIATORY OR CONQLTI%FIRM PERFORPKD ANY OF Tlt AtaaYSES REQUIRED BY THIS APPLICATIOttr PROVIDE TIE NAME AND ADDRESS OF EAQI tasORATCRY OR FIRM ANJ THE ANALYSES PERFQttED AS AM ATTAQtKNT OF THIS APPLICATIONa LI DO YCU DISCMUIGK ANY OTHER TOXiC OR INJLJIIOUS (JKMICAL SUBSTANCES %T LISTED IN TABLES IV PAGE tt AtO IIA THOU%VA PJVM~~, IF YES TIKJI IDENTIEY TIE CHBttCAL Q8STAJKXS AMO ESTIMATE TIE FINAL EFFUXMT CCNCEJttttaTICNsr SUttIT THIS ltFOtttATION AS AN ATTAQtEMT TO THIS APPLICATIONs Q%T APPLICABLE '/A Q APPLICABLE/SEE ATTAQIED Q MOT APPLICABLE X APPLicastE/SEK ATTAQIED Q%T appLicasLE N/A Q APPLtues/SKK ATTAQIKD 37 INSTRUCTIONS FOR CCMPLET I NG SECTION I I ITEM 6 This form requires Information on a specific outtnl I discharging to the surface waters.ENTER THE PERMIT NUMBER IN THE BOX AT THE TCP OF THIS FORM.THE PERHIT IRNBER CAN BE FOUND ON THE FRONT PAGE OF YOUR EXPIRING PERMIT.If thlS iS O new Or nOt preVIOuSly permitted fOCI lity, then lenVe blank and n number Wll I be nSSlgned.Enter the outfall number In the space provided for each page of Section II.For each Individual dlschorqe oint n separate set ot Section II, Item 6 forms must be f I lied out.PRIORITY POLLUTANTS ANO AGOITIONAL INFORMATION ITEH 6 NOTE: NOTE: If you have two or more substantially Indentlcal outtnlls, you may request permission frcm your permitting authority to s<<cp(e nnd analyze only one outfnl I and submit the results ot the analysis for other substantially Identical outfol ls.It your request Is granted by the permitting authcrlty, on a separate sheet attached to the appllcntlon form Identify which outfal I you did test, and describe why the outfalla which you did not test ore substantially Identical,to the outfall which you did test.40 CFR Part 122.21(g)(8), Friday, Aprl I I, 1983, provides for a Smal I Business Exemption from the reporting of quantitative data tor organic toxic pollutants and toxic pollutants as required by Port 122.21(g)(7)(ll)(A) or 122.21(g)(T)(ill)(A). A~-C.These ports are selfwxplanotory ond do not require further Instructions. Simply go through each part and do ns Indicated. and E.-J.0.Several Industrial cotegor les and subcategories hove been exempted fran submltt lng dots on certain GC/MS Fractions (40 CFR Port 122, Vol.48, No.64, Friday, Apt II I, 1983, Notes I.2.and 3).'eview the following list to determine whether your facility qualities to be exempt from reporting GC/MS (Gas Chrcmatography/ Moss Spectroscopy) Fractions. GC/MS Frnct ion Testing nnd Reporting Exemptions Textile Mills Induct-All four GC/MS organic tractlons In the Greige MII Is Subcategory. -Pesticide traction In oil other subports of this Industry.Ore Mini n ond Brass l Indust-Volatile, base/neutral, and pesticide fractions In the Bose and Precious Metals Subcategory. -All four GC/MS organIc fractions In all other Subcategories of this Industry.Cue and Mood Chemicals Industr-Pesticide fraction In the Tall Oil Rosin Subcategory and the Rosin Based Oerlvatlves Subcategory. -Pesticide and base/neutral fractions In all other subcategories of this Industry.Pul and Paper Induct Pesticide fraction In Papergrade Sulfite subcatcqories (subparts J and U).-Base/neutral and pesticide fractions in Oelnk Subpart Q, Blssolvinq Kraft Subpart F, and Paperboard from Masts Paper Subpart E.lt-Volatile, base/neutral, pesticide fract(ons In the SCT Sleschcd Kraft Subpart H, Saci-chemical Subparts 8 and C, and Nonintegrated"Fine Papers Subpart R.-Acid, base/neutral, snd pesticide fractions in Fine Bleached Kraft Subpart I, Olssolvlng Sulfite Pulp Subpart K, Ground-wood Fine Papers Subpart 0, Harket Bleached Kraft Subpart 0, Tissue from Mastepaper Subpart T, and Nonlntegratcd Tissue Papers Subpart S.Steam Electric Power Plant Indust 1-Base/neutral fraction In the Once-Through Cooling Mater, Fly Ash, and Bottom Ash Transport Mater process wsstestreams. 38 SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I Mj.pop5827 EM 7 CRITICAL MATERIALS TOXIC POLLUTANTS ~OO E Ae USE THIS DATA SHEET TO RECORD INFGLtLATIOM AS RECUIRED IN: (CHECK APPROPRIATE BOX FIN WICH IMFLJLMATICN THIS DATA SHEET REPRESEMTS ~)O X ls SECTION IIE ITEM Me GROMlLATER DISCHJJLGE INFCttULTION (PAGE 35)2e SECTICN I IE ITEM 6e PRIORITY RXJlJTAMTS IN SLRFACE HATER DISCHLWiE (PAGE 3Tl D X 3e Bs BELJJELL CRITICAL MATERIALS (TABLE lv)IN SLJLFACE HATER DIMJLARGE (PAGE 39)HAZARDOUS SUBSTANCES IN DISCHARGE Be LIST ANY CRITICAL MATERIAL (TABLE IV PAGE 6)NOT ADCRESSED IM SECTICN I I ITEH 6 PRIORllY POLLJJTAMTS HHICH YOU tlat%OR HAVE REASON lo BELIEVE TO BE PRESENf IN TIE DISCHLRGEI SEE REVERSE SIDE OF THIS PAGE FOR FLJLTIER DIRECTICNSE tOT APPLICABLE APPLICABLE (SEE BELCN)UNITS CODE 1 MQ/I L Ug/I LBS/DAY KG/DAY~AMPL~TYPg 1 GRAB 2 24 HR.COMP.CE ILL E I LLJ Let I LE Lit tee I Ae NLHE OF CRITICAL MATERIAL CR PRIORITY JOLLJJTANT Be AVERAGE CNCEMIRATICNJ SAMPLE TYPEJ II OF ANALYSES Ce MAX It4N CCttCEtmLATICN AIO MASS Ae Ntt%OF CRITICAL MATERIAL CR PRIORllY POLLUTANT Be AVERAGE CCJJCEMIRATICNJ Qt%%E lYPEJ JI OF ANALYSES Ce MAXI JLPI CCNCENllVLTION AtO MASS Ae H4%OF CRITICAL HATERIAL CR PRICRllY POLLIJTANT Be AVERAGE CotCEJIIRATICNJ QWE TYPEJ f.OF ANALYSES Ce MAX IJLN COMXMIILATI ON AN)MASS Ae NA%OF CRITICAL MATERIAL OR PR!OR llY PCLLJJTANT Be AVERAGE COICEMTRATICNJ QtssLE TYPEJ JI OF ANALYSES Ce MAXI JLN COtCEtmLATICN AtO HASS Ae NA%CF CRITICAL HATERIAL CR PRIORITY POLlltfANT Bs AVERAGE CXCEMTILATIONJ QJ4ELE TYPEJ JJOF ANALYSES Ce HAXD%N COLCEMIILATION AJO MASS A>>NJ%OF CRITICAL MATERIAL CR PRICRllY POUJJfANT Bs AVERAGE CCNCEMIRATIOIU SAtsLE TYPEJ f/OF ANALYSES C HLXINJ1 CCtCEMIILATINI AJO MASS Ae NA%OF CRITICAL MATERIAL OR PRICRllY POLLLJTAMT Be AVERAGE CONCEMIILATICNJ SA+tE TYPE J ff OF ANALYSES Ce HAXIJLJL CONXMIRATICN AJO MASS As NA%OF CRITICAL MATERIAL OR PRIORITY PCLLJJTANT Be AVERAGE CPJCEtflRATIONJ QPPLE TYPEJ tJ OF ANALYSES HydrocIuinone

• WIT CCDE QHPIE TYPE OF ANAl YSES u LNIT CODE LNIT CODE LJ~~LJ LN IT CCK SAME TYPE OF ANALYSES~.LLLJ LJ LNIT GXK LNI T CODE LJ LNIT CCDE SAMPLE TYPE OF ANALYSES LN CXK LNI T CODE LNIT CCOE SAINTE lYPE OF ANALYSES LNIT CXK LNIT CODE LJ~~~LJ LNIT CXK QtsELE TYPE Jf OF ANALYSES LNIT CCDE LNIT CODE LJ~~~LJ LN IT CXK SAftELE lYPE OF ANALYSES~.LLLJ LJ UNIT GXK LNIT COIK LJ~~~LJ IIII Y IEEE EIEEIE YIYE Cs EEICYEEE LNIT GXK LNIT CODE LJ~~~LJ LNIT CXE SWALE lYPE OF ANALYSES LJ Ce HAXIKJL CONCEMIRATIOM AtO HASS UNIT CODE LNI T CODE LJ+Small onl y.would ADDITIONAL PAGES CF THIS ITBl 7 ARE ATTAC%D FCR 7%REST OF~CRITICAL E3 YES MATERIALS AIO/CL PRICRTIY PLXWTAMTS RBXJIRED TD BE REPORTED.K NO quantities of Hydroquinone may be used in black and white film developing in emergency situations No film was developed in 1993 and no hydroquinone was discharged.

Approximately oneliter be used when processing is necessary. 39 INSTRUCT I ONS FOR COMPLETING SECTION I I ITEM 7 This form Is to be used by both surtace and ground<<ater applicants to record Information on any Michigan critical material, E.P.A.priority pollutant, or hazardous substance In<<hich this application requires data to be provided.This<<ovid Include any chemical Subatanoe tram the MIChlgan CrltICal MaterlalS ReglSter (Table IV), the E.P.A.PrlOrlty POllutant LIStlng ITable Y), Or TableS I IA-YA<<hlch I lsts Organic Toxic Pol lutants, Other Toxic Pol lutants, conventional and Nonconventional Pol lutants and Hazardous Substances. ITEM 7 CRITICAL MATERIALS PRIORITY POLLUTANTS AND/OR HAZARDOUS SUBSTANCES IN THE DISCHARGE Material I 2, 3...8 A.List the name of the chemical substance icrltlcal material, priority pollutant, or hazardous substance) fran Tables Iv, V and IIA-YA as required In the box<<hlch you checked In A.I-3.above.Enter each chemical substance's parameter number as listed In Tables IV, Y and IIA-VA It provided.B.Provide the average concentration of the chemical substance named In A.Indicate the sanple type used and the number of analyses made to provide the concentration data for the chemical substance named In A.C.Provide the maximus concentration and determine the mass loading ot the chemical substance nmsed In A.NDTEs: I.If only one analysis<<as made for a chenlcal substance then record that data as a maxlmvn value.It more than one analysis has been made for a chemical substance then provide an average value of those analyses and the maxlmma value.2.This Section II, Item 7.Data Sheet provides space for recording data for 8 chemical substances (Haterlals). Additional space for recording of data for more than 8 Materials can be made by making copies of this Item 7 Data Sheet as needed.It Is also Important to use a separate set ot Data Sheets for each applicable reporting requirement as listed In A.I-3.and for each outfall'efer to the lett margin for the code number representing the senple type used and the appropriate unit codes.40 VOLATILE ORGANIC ANALYSIS RESULTS GC/HALL ANALYSES USING EPA METHOD 8010 li n m I ID:.EWA PLANT EFFL D oil'-DE-3 Date Anal zed: 05-JAN-94 Matrix: WATER Anal tical Batch¹:.122093-801020-0-3 LAL Sam le ID: L100-D R iv;2-DE Dilution Factor: 1 QC Batch ID: 122093-801020-0-3 BCM BFB rr t R vr 108 85 QC Limi s 65-125 60-120 Constituent Dihl r ifl orm hn hlrm hn Vin I chloride Bromomethane hl r hn Trihir fl rm hn 1 1-Dichloroethene Meth lene chloride ran-1 2-Di hl ro h ne 11-Dihl r hn Chloroform 1 1 1-Trichloroethane arb n r hl ride 12-Dihl r hn Trichloroethene TCE 1 2-Dichloro ro ane Brm ihlrm hn 2-hl r h Ivin I her cis-1 3-Dichloro ro ene trans-1 3-Dichloro ro ene 11-Trihlr hn Ter hir hn P E Dibromochloro methane Chlorobenzene Brom form 1 1 2 2-T r hl r h n 1 3-Dichlorobenzene 1 4-Dichlorobenzene 1 2-Dichlorobenzene Concentration Iyg/LI<0.50<3<6<4<0.<0.5<0.5<2 Reporting Detection Limit/L 0.5 0.5 0.5 Data Qualifierls) LOCKHEED ANALYTICAL SERVICES hg

VOLATILE ORGANIC ANALYSIS RESULTS GC/PID ANALYSES USING IVIETHOD 8020 li n m I ID:.EWA EP ANT FFL D II ce: 28DE-9 Date Anal zed: 04-JAN-94 Matrix: WATER Anal tical Batch 4': 122093-801020-0-3 AL ml ID: L1 09-Da R iv: 2-DE-Dilution Factor: 1 QC Batch ID: 122093-801020-0-3 TFT BFB urr R v r 93 101 Q Limi s 70-120 75-120 Benzene T I n Constituent Concentration IL<0.5<0 Reporting Detection Limit IL 0.5 Data Qualifier s hl r nz n Eth I Benzene m-X lene-Xln 1-Di hl r nzen 1 4-Dichlorobenzene 1 2-Dichlorobenzene <2<2<2 LOCKHEED AIVALVTICAL SERVICES$0 VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 1 of 2 li n m I ID:.EWA E PLANT EFFL Date Collected: 28-DEC-93 Matrix: WATER Anal i I Ba h 0 11 4-2-F2 QC Batch ID: 011094-8260-F2 LAL m I ID;L1-47 Date Received: 29-DEC-93 Date Anal zed: 11-JAN-94 Dil inFc r: 1 SURROGATE RECOVERY 1 2-Di hl r h n-4 Tl n-QC Limits 7-114 4-Bromofluorobenzene 86 86-115 Constituent Ghloromethane Vin I hl rid Br mom hn Chloroethane Trichlorofluoromethane A n 11-Dihl r hn Carbon Disulfide Meth lene Chloride rans-1 2-Di hl r h n Vin I A 1 1-Dichloroethane 2-Butanone i-1 2-Di hl r hen hlrfrm 1 1 1-Trichloroethane Carbon Tetrachloride 12-Dihi r hn B n n Trichloroethene TCE 1 2-Dichloro ro ane Bromodi hl r m h n 2-hl ro h IVin IEh r 4-Meth I-2-entanone cis-1 3-Dichloro ro ene T I n r n-1-Dihl r r n 2-Hexanone 1 1 2-Trichloroethane-Tetra chloroethene PCE Concentration IL<5<5<5<5<5<5<10<5<5<5<5<2<10<5<10<5<5 Reporting Detection Limit IL 10 10 10 Data Qualifier s LOCKHEED ANALYTICAL SERVICES VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 2 of 2 Client Sam le ID: S.SEWAGE PLANT EFFL.LAL Sam le ID: L1009-47 Constituent Dibromochloromethane hir nzn Ehl nz n m-X lene o-X lene r n Br m f rm 1 1 2 2-Tetrachloroethane 1 3-Dichlorobenzene 1 4-Di hlor enz ne 1 2-Dichiorobenzene Concentration IL<5<5<5<5<5 Reporting Detection Limit IL Data Qualifier s LOCKHEED ANALYTICAL SERVICES 22 VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 TENTATIVELY IDENTIFIED COMPOUNDS Client Sample ID: S.SEWAGE PLANT EFFL Date Received: 29-DEC-93 Matrix: WATER Analytical Batch: 011094-8260-F2 LAL Sample ID: L1009-47 Date Analyzed: 11-JAN-94 Dilution Factor: 1 QC Batch ID: 011094-8260-F2 Tentatively Identified Compound UNKNOWN SULFUR COMPOUND UNKNOWN Estimated Concentration Iyg/L)37 28 Retention Time (minutes)4.47 9.70 Data Qualifierls) LOCKHEEO ANALYTICAL SERVICES SEMIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 li n m I ID:.EWA EP ANT EFFL Date Collected: 28-DEC-93 Matrix: WATER An I i I B ch¹': 111 4-827-B QC Batch ID: 8270-SEMIVOLATILES-3964 IAL m I ID: L1-1 Date Received: 29-DEC-93 Dilu ion Factor: 1 D Ex r: 4-JAN-4 Date Anal zed: 11-JAN-94 P 1 f2 2-Fluoro henol RR ATE RE VERY 0 26 Limi 21-100 Phenol-d, Nitrobenzene-d, 2-Fluorobi hen I 2 4-Tribromo henol p-Terphenyl-d,4 18 61 54 76 10-94 35-114 43-116 1-12 33-141 n i uen Phenol bis 2-Chloroeth I ether 2-hl r hn I 1-Di hl r nz n 1 4-Dichlorobenzene Benz I alcohol 1 2-Di hl r benz ne 2-M h I h nol bis 2-Chloroiso ro I ether 4-Meth I henol N-Ni r-Di-n-r I min Hx hlr hn Nitrobenzene Iso horone-Ni r h n I 24-Dimeh I h n I Benzoic acid bis 2-Chloroethox methane 24Dihl r hn I 1 24-Tri hl r nz n Na hthalene 4-Chloroaniline Hx hlr in 4-hl r--m h I h n I 2-Meth Ina hthalene Hexachloroc clo entadiene Concentration L<10<10<10<10<10<10<10<10<50<10<10<10<10<10 Reporting Detection Limit IL 10 10 10 10 10 10 10 10 10 10 50 10 10 10 10 10 Da a alifi r s LOCKHEED ANALYTICAL SERVICES SEIViIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/IVIS ANALYSES USING IVIETHOD 8270 Client Sam le ID: S.SEWAGE PLANT EFFL LAL Sam le ID: L1009-31 Pa 2 f2 Constituent 24-Trihl r h n I 24-Trihl r h n I 2-Chlorona hthalene 2-Nitroaniline Dim h I hh I A n hhln 2 6-Dinitrotoluene 3-Nitroaniline A n hhn 2 4 Dini r h n I 4-Nitro henol Dibenzofuran 24Dinir I n Di hlhhl 4-Chloro hen I-hen lether Fluorene 4-Ni r nilin 4-Dinir--m h I h n I N-Nitrosodi hen lamine 4-Bromo hen I-hen lether Hx hlr nzn Pn hlr hnl Phenanthrene Anthracene Din-I hh I Flu r n hene P rene But Ibenz I hthalate'-Di hl r nzi in 8 n'hr n Chr sene bis 2-Eth Ihex I hthalate Di-n-I hh I Bnz fl rnhn Benzo k fluoranthene Benzo a rene In n 1-rn Di nz h n hr n Benzo h i er lene Carbazole Concentration (IL)<10<25<10<10<25<2<25<10<10<10<2<2<10<10<2<10<10<10<10<2<10 1.3<10<10<10<10 Reporting Detection Limit I IL)10 25 10 10 25 25 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 Data Qualifieris) JB LOCKHEED AItIALYTICAL SERVICES 4 J. VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD'8270 TENTATIVELY IDENTIFIED COMPOUNDS Client Sample ID: S.SEWAGE PLANT EFFL Date Received: 29-DEC-93 Matrix: WATE R Analytical Batch: 011194-8270-8 LAL Sample ID: L1009-31 Date Analyzed: 11-JAN-94 Dilution Factor: 1 QC Batch ID: 8270-SEIVIIVOLATILES-3964 Tentatively Identified Compound Benzaldehyde Unknown Unknown Unknown Hydrocarbon Hydrocarbon Estimated Concentration (yg/L)10 Retention Time (minutes)7.85 25.05 27.46 30.25 31.99 33.87 Data Qualifier(s) LOCKHEED ANALYTICAL SERVICES 42 PESTICIDE ANALYSES RESULTS BY GC/ECD USING METHOD 8080 FOR COOK NUCLEAR PLANT Clien Sam le ID: S.SEWAGE PLANT EFFL Date Collec ed: 28-DEC-93 Date Extracted: 04-JAN-94 Matrix: WATER Anal tical Batch 4: 012094-8080-A-1 LAL S m le ID: L10 9-2 D e R eived:29-JAN-94 Date Anal zed: 21-JAN-94 Dilution Factor: 1 QC Grou ID: 8080 PEST/PCBS 3965 SURROGATE RECOVERY Oo QC Limits TCMX DCB 70 50 60-150 60-1 50 A-BHC B-BHC G-BHC D-BHC Constituent Concentration /L<0.05.05<0.05 Reporting Detection Limit/L 0.05.05 0.05 Data Qualifier(s) HEPTACHLOR ALDR IN HEPTACHLOR EPOXIDE G-CHLORDANE ENDOSULFAN I A-CHLORDANE 4 4'-DDE 4 4'-DDT DIELDRIN ENDRIN ENDOSULFAN II 4 4'-DDD ENDRIN ALDEHYDE ENDOSULFAN SULFATE METHOXYCHLOR TOXAPHENE PCB-101 6 PCB-1 221 P B-12 2 PCB-1242 PCB-1 248 PCB-12 4 PCB-1 260 TECHNICAL CHLORDANE MIREX TCMX-tetra-chloro-meta-xylene DCB-Deca-chloro-biphenyl <0.05.5.0<0.05<0.05<.05<0.1<0.1<0.1<0.1<0.1<5<2<0.1 0.05.0 0.05 0.05 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.5<0.1 LOCKHEED ANALYTICAL SERVICES METALS RESULTS Client Sam le'D: S..SEWAGE.'.PLANT. EFF, Date Collected. '12-28-93, Matrix:.round.water LAL Batch ID(s): 1220 im Date Received: 12-29-93 PO¹69095-040-3N -.Constituents Method Concentration-im IL)Reporting Detection. Umit lm IL)Data Qualifierls) Date Anal zed LAL'am le ID Aluminum Antimon Arsenic Barium Be Ilium Boron Cadmium Chromium Cobalt Co er Iron Lead Ma nesium Man anese Mercu Mol bdenum Nickel Selenium Silver Sodium Thallium Tin Titanium Vanadium Zinc 6010 6020 6020 6020 6020 6010 6020 6020 6020 6020 6010 6020 6010 6020 7470 6020 6020 6020 6020 6010 6020 6020 6010 6010 6020<0.20<0.060<0.010<0.20<0.005<0.20<0.005<0.010<0.050<0.025<0.10<0.003 14 0.025<0.0002<0.20<0.040<0.005<0.010 34<0.010<0.20<0.10<0.050 0.047 0.20 0.060 0.010 0.20 0.005 0.20 0.005 0.010 0.050 0.025 0.10 0.003 5.0 0.01 5 0.0002 0.20 0.040 0.005 0.010 5.0 0.010 0.20 0.10 0.050 0.020 01-20-94 L1009-16 01-27-94 L1009-16 01-27-94 L1009-16 01-27-94 L1009-16 01-27-94 L1009-16 01-20-94 L1009-16 01-27-94 L1009-16 01-27-94 L1009-16-01-27-94 L1 009-16 01-27-94 L1 009-16 01-20-94 L1009-16 01-27-94 L1009-16 01-20-94 L1009-16 01-27-94 L1009-16 01-07-94 L1009-16 01-27-94 L1009-16 01-27-94 L1009-16 01-27-94 L1 009-1 6 01-27-94 L1 009-1 6 01-20-94 L1009-16 01-27-94 L1009-16 01-27-94 L1009-16 01-20-94 L1009-16 01-20-94 L1009-16 01-27-94 L1009-16 Comments: LOCKHEED ANALYTICAL SERVICES

GENERAL CHEIVIISTRY RESULTS Client Sam le (D: S.SEWAGE PLANT EFFL Date Collected: 12-28-93 Matrix: round water LAL Batch (D(s): 1229 im Date Received: 12-29-93 POP69095-040-3N Constituent Fluoride, in m IL Chloride, in m/L Nitrate-Nitro en, in m IL Nitrite-Nitro en, in m/L Sulfate, in m IL Ammonia-Nitrogen, in m/L Total Cyanide, in mg/L Method 340.2 300.0 300.0 300.0 300.0 350.1 335.2 Result<0.15 120 24<0.50 39 24<0.020 Reporting Detection Limit 0.15 0.01 6 0.01 7 0.50 0.059 0.50 0.020 Data Qualifier(s)

D(1: 10)Date Anal zed 01-24-94 12-29-93 12-29-93 12-29-93 12-29-93 01-05-94 01-03-94 LAL Sam le'ID L1 009-4 L1 009-4 L1 009-4 L1 009-4 L1 009-4 L1009-8.L1009-12 Comments: LOCKHEED ANALYTICAL SERVICES SEE INSTRUCTIONS ON REVERSE SIDE SECTION II NUMSEA PERMIT~!ail ppp5827 i EM t Ae UXATION OF DISCHARGE B>>H4%RECEIVING HATER (IE>>GROIKWATER CR IU<%OF SIRFACE DR Y WE S~NA~SW<~SP j SEtTI I I~P6 TM~jJQJ RAKE DISCHARGE LOCATION Ce l}0 YOU DISCHARGE S~Y (IF IO>>CNTIIAE TO E)De IF YES>>LIST DISCHARGE PERIODS tO>>/DAY YES tO>>/DAY FLOW RATE WASTEWATER ZXHMEK.1 CONTACT COOUNQ 2 NONCONTBCT COOLINQ 3 PROCESS 4 SANITARY 5 STORMWATER E>>LAND APPLICATION RAlE F>>lYPE OF HASTKHATKR DISCHARGE Ge DISCHtRGE SCIHlIE (YEARLY AVERAGE)H>>DISCHARGE FIEN RATE IN>~~LJ IR>>DAY, IN>>/WK>>~~'w IOURS/DAY lOTAL YEARLY DAILY HINIttH DAILY SWINII~25: 0,~00 WIT1CCCE~3~3 WASTBIATKR TYPE CODE~3~5 1 MQY 2 MQD 3 QPD ITEM2 WATER TREATMENT ADDITIVES Je HIXIIEPI DESIGN DISCHijRGE FUN RATE<Ae IS YOU USE WAlKR TREATISE AEOITIVES TO TRFAT YNR DI~(IF tO CNTIIAK TO ITBI 3)Be t&%FWCTION>>AtO CIKIIICAL CPASITIN OF TIIESE AISITIVES>> DESIGN Ce Hit%AIO AEORKSS OF HAIAFACTIRERS OF TIESE AISITIVES>> I e lIE NXIMPl DISCHIIRGE FlOt RATE TO BE AUMR IZED IH PEBIIT>>Wl GXK 1 MQ/I 2 UQ/I D>>EXPECTED DISCHARGE CCtCKIIIRATIOH CF AEOIT IVES>>AEOITIVE IU%ACOITIVE IU%AISI TIVE HA%Ee DO VIXI TREAT TIE DISCHARGE TO RBOVE AISITIVES? Fe HIAT IS THE RBOVAL EFFICIBICY ND DIKHARGE FRECEEIICY? HINIMII WITS AVERAGE WITS HAXIISPI WITS CQE COCK M s~LJ g~LJ LJ I~LJI~LJ LJ'LJ'LJ AID!TIVE HA%AIS ITIVE NA%AEOITIVE tWE tRS>>/DAY DAYS/WK>>G.AS AH ATTACttEHT TO THIS APPLICATIN f%0VIOE SPECIFIC MPH%.IAN OR AOUATIC TOXICOUXIICAL DATA CR REFB\BICE WHIOI ARE AVAILARE AND INRRIATIN CN THE RATE CF DKGRAOATIN OF TIE PA0RCG FCR EACH AISITIVE>>31 INSTRUCTIONS FOR COMPI.ETING SECTION I I ITEMS I ANO 2 t This form requires Information on the tacility's discharge location, discharge schedule, volume tlow rate and voter treatment additives. ENTER THE PERMIT IAP(8ER IN THE BOX AT THE TOP OF THIS FORM.THE PERMIT INM8ER CAN BE FOUND ON THE FRONT PAGE OF YOUR EXPIRING PERMIT.If this Is a ner or not previously permitted facility, then leave blank and a number vill be assigned.Enter the outfall nmber In space provided tor each page of Section II.For each Individual discharge point a separate set of Section II forms must be filled ovt.ITEM I DISCHARGE LOCATION SCHEDULE ANO FLOH RATES A.Enter the location of discharge, this should Include qvarter-quarter section, quarter sectIon, section~town, snd range.B.List name of receiving water (if surface voter discharge). C.IndlCnte whether fOClllty dlSChargeS On O SenSOnal bnSIS.O.If yes, list discharge periods.E.Pro Ide the land application rates used or expected to be used In terms of Inches per hour, hours per doy, nnd Inches per week.F~Indicate the type of wastewater to be dlschnrged fran this outfall.Refer to the wasterster type code given In the lett mn gin.More than one code may be applicable. G~Provide the average nvnber of hours per day In which the facility discharges treated wastevnter ond the total number of days per year In rhiCh the discharge occurs.H.Provide current (fran the Inst l2 months)ot'xpected flow rates ss requested. Refer to unit code qlven In the lett margin for the appropriate flow units.MGY-million gallons per year;MGD-million gallons per doyi GPD-gallons per day.I.Provide the maximum discharge flow rate which you want to have authorized within the permit.NOTE: For NPDES permits only, the use ot such s t low rote vill not ploce an actual limit restriction on the flow but vill be the flow rote used to develop effluent limits.Also, when the Monthly operating Reports are revie~ed by ccmpllsnce staff It<<III help then to determine if nny ner or increased uses might have occurred st the taclllty.J.Provide the design f lor for this specific outtsll discharge (e.g.botch treatment system flow, packaged treatment system t lo , or sane other finite treatment system flow)~ITEM 2 MATER TREATMENT ADO IT IVES A.Indicate~nether discharge Is treated vlth conditioners, inhibitors, or mlcrobloclde. If not, continue to Item S.B.Give nome, function, snd chemical composition of additives used.C.Give name and address ot the mnnutscturer(s) of the additives used.O.Indicate expected mlnlmNn, svernge and maximum discharge concentrations of the additive(s) for this discharge. E.Indicate~bather you treat the discharge to remove the additive(s) before discharge of wastewater. F.,Indicate the removal eftlclency of each additive{rem the vastcwster and the discharge trequency ot each additive to the surface voter or groundwater. G, NOTE: It Is The responsibility of the applicant to supply the product Information as requested In'his Item 4.Information requested but not supplied msy result In the application being returned to the applicant tor completion. 32 SEE INSTRUCTIONS ON REVERSE SIDE-SECTtON I I PERMIT~Ivil 0005827 NUMBER A~NPK OF PROCESS CONIRIBUTING TO THE DISCHARGE THOROUGH THIS OUTFAIL AttO SIC CODE Be PRXESS SCHGXAE (YEARLY AVERAGE)*~N~A TRANS DECK DRN 4911 PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCIIARGE t/9 4/t Os 0 CC CL Ce PROCESS HASTEHAT8I FUX4 RATE De PROCESS PRODUCTION RATE TOTAI.YEARLY DAILY MINIMA DAILY MAXIM'~2 1 20 00~2 WITS l TIME~LJ JlHIL'Uc5HK T POUNDS 2 GALLONS 3 CUBIC YARDS 4 TONS 5 MGY 6 MGD 7 GPD ttt 4/t Ocv 0 Ae NAtE OF PROCESS CXIIIBUTIt6 TO TIE DISCHARGE TlFOIGH THIS OUTFALL 9%SIC CCÃBe PROCESS SCIETXLE (YEARLY AVERAGE)**Ce IROCESS HASTEHATER FLOW RATE**De PROCESS PRODUCTION RATE Ae NA%OF PROCESS CONTRIBUTING TO TIE DISCNRGE TIROXIH THIS OUIFAIL Ate SIC GXE Be PROCESS SCtHXXE (YEARLY AVERAGE)**A C.PROCES SQSEHteTER Flat RATE*4'*/esse/sev~seve/vses TOTAI.YEARLY DAILY MINItXT4 DAILY tVNItTT4 WITS J'TIFE ES EL OI LTK~49 11 esses/sev~srs/vses TOTAL YEARLY DAILY MIN WH DAILY NXIltN D I ESE L SU MPS 4 9 1 1 HOUR 2 DAY 3 WEEK 4 MONTH 5 YEAR De PROCESS PRODICTICN RATE***Ae NA%OF PROCESS COtnRIBUTit4 TD TIE DISCHARGE AN)SIC OXE B~PROCESS SCIEIXXE (YEARLY AVERAGE)PROCESS HASTEtliTER PION RATE D.PROCESS PIOXXTION RATE Ae NA%OF PROCESS CONTRIBUTII6 TO T%DISCBUIGE ITttXXB THIS OUIFALL AND SIC OXE Be PRXESS SCIEDIXE (YEARI.Y AVERAGE)Ce PROCESS HASTEttATER FUJI RATE De PROCESS PRODUCTION RATE TOTAL YEARLY DAILY MINIISTI DAILY tVNIt994 TOTAL YEARLY DAlLY MIHIISTI DAILY MAXI NB WITS/TIME WIT CCOE WITS MIME WIT CODE UNITS/TIME Primarily based on rainfall frequency and duration.Deluge testing would be 3-30min/day for no more than 10 days.**EDG sump discharges volumes are insignificant.

• • • No known discharges 33 INSTRUCTIONS FOR COMPLETING SECTION I I ITEM 3 Tr ls torm requires information on the process streams<<hleh contrlbvte to this discharge.

ENTER THE PERMIT NWBER IN THE BOX AT THE TOP OF THIS FORM.THE PERMIT NISIBER CAN BE FOUNO ON THE FRONT PAGE OF YOUR EXPIRING PERMIT.\f this Is a new or not previously permitted facility, then leave blank and a number<<ill be assigned.Enter outfnl I nvmoer ln sonce provided tor each page ot Section II.For each Individual discharge oint n separate set cf Section II forr>>s must be filled out.ITEM 3 PROCESS STREAMS CONTRIBUTING TO OI SCHARGEr FOR EACH SEPARATE PROCESS PROVIOE THE COLL(PING INFORMATION A.Enter the nome of the process which contributes to this discharge. Also provide the proper SIC code.B.Indicate tne yearly average process schedule In hours per doy ond days>>per-year. C~provide the process wastewater flow rate information as requested based on your inst I2 months of operations. Refer to unit code given in the left margin for the appropriate flow units.O.Process Production Rote Certain permit Itm/totlons may be based on production rates.The production rates used to determine permit limits shall be represented by a reasonnble measure of actual production of the facility, such as the production during the high month of the previous year, or the monthly nveroqe for the highest of the previous five years, or other reasonable measure ns stated in applicable U.S.E.P.A. categorical rules and regulations. For new sources or new dlschargers, actunl production shell be estlmoted using projected production. Record your production rates ln the terms nnd units used In the applicable U.S.E.P.A. categorical rules and regulations for your type ot facility, 34 SEE INSTRUCTIONS ON REVERSE SIDE SECT(ON I I PERMIT~MT 0005827 NUMBER J EM 4 GROUNDWATER DISCHARGE INFORMATION A.IS THE DISCHARGE FROM THIS OUIFALL DIRECIED TO lHE GRCNID OR GROIWDtATERSZ (IF tCI>>CCttTIIAE TO ITBI P)Be HAS A HYDROGEOUXIICAL STUDY OR ITS EQUIVALENT BEEN PERFORtKXI OR IS THERE BIFF ICIENT CURRENI'YCROGEOLOGICAL INFORMATION AVAILABLE AS REQUIRED BY TIE MATER R~CCttIISSION PART 22 GRONIDtATER RULE/OF AISUST 14>>1%9 R>>5ZS>>Z?07 (PAGE ILI)FOR lHIS EXISTI%OR PROPOSED DISCHARGE! IF YES ATTADI A CCPY OF THE REPCRT>>Ce ARE YOU RBXKSTIMI AN EXPPTICN FRCM SIKHITTII6 A HYIIIOGEOUXiICAL REPORT IXKIER RIAE R>>X5>>22F (Q(PAGE t15)CR FRCM GROL59IATKR MGNITORIgi IIEQUJREMENTS LIBER RIAE Re 25>>(5)(PAGEOF TIE PART 22 BILES>>IF YES ATTACH COQttENIS AN)EXPLANATION TO DEIDNSTRATE THAT YIXR DISCHARGE ICtID QUALIFY FCR AN EXEtP ION>>De ARE YOU REQLKSTI%A VARIANCE FIOI RULE 323>>2205 (PAGE 5)(NXIDEGRADATICN) OF THE HATER REQXRCES CCt%ISS ION PART Zi?~TER RIIESZ IF YES>>ATTACH SUCH DOCU'ANTS AS NECESSARY TO DEMtINSTRATK TIE NEED FOR A VARIANCE IN TERMS OF TIE CRITERIA SPECIFIED IN'RID X5>>2210 (PAGE+OF THE PART 2Z RULES>>Ee I,IST Alp.CIKHICAL SIBSTANCES HHICH ARE IH M1CHIGAN S CRITICAL MATERIALS REGISTER TABLE IV IPAGE II)AND/OR U>>S>>EPA S PRIORIIY FIXLUTANT LIST TABIK V (PAGE 7)OR ANY OTIER QSSTANCES NIICH ARE OR MAY BOXPE INXRIOUS TO T%: DESIGNATED USES OF TIE G(IXNDHATKR IXI TO TIE PUBLIC HEALTH THAT ARE DISCHARGED OR EXPECTED TO BE DISCHARGED TO TIE RRIXtCltATERJIY THIS FACILITY>>ESTIMATE THE FINAL EFFIleIT COCBIIRATION AtO REND AIL DATA IN ITBI 7 OF SECTIIXI I I IN THIS BOOST>>~~YES K0 Submitted 12/6/91 YES Pg tO Q YES Q gl NOT APPLICABLE/BELIEVED ABSENT T%APPLICANT MAY BE REQIIRED TO DO ACDITICNAL HASTE ANALYSES>>A>>DISCHARGE CHARACTKRISTICS CONCDIIRATI ON PRESENT>>DATA PROVIDED IN ITKM 7 0 ITEM 5 EXPECTED WASTEWATER CHARAC'I>>>>les UNiTS CODE 1 Mg/I 2 UO/I 3 COUNTS/100 ml 4 S.U.5 F 6 LBS/DAY TOC (TOTAL ORGANIC CARBON)AtttGNIA NITRIXiEN (AS H)TOTAL SUSPEMKD SOLIDS TOTAL PteSPHORUS (AS P)TOTAL RESIRNL CttDRINE DISSOLVED OXYGEN HIH~.LJ FECAL COLIFORM BACTERIA~TINE (QPPER)TKtPERATINE (KINIER)BCO5 (FIVE DAY BIOCteIICAL OXYGEN BEMA%)COD (OeIICAL CEIYGEH DEMAND)AVE>>~~LJ~~LJ Be OIIKR HLSTBWKR CHIIIACIKRISTICS >>LJ LJ5~5 LJ LJ LJ LJ LJ LJ LJ SAMPLE JXEF 1 GRAB 2 24 HOUR COMPOSITE 0 I L Il G R E A S E i<>>PCB AYt T O C LJ~LJ LJ~LJ LJ LJ~LJ LJ~LJ LJ~LJ REOIIRED IIFIXPIAT ICN RXI QRFACE HATKR DISCHARGES ~See attached sample analysis INSTRUCTIO'IS FOR CCMPLETING SECTION I I ITEMS 4 ANO 5 This forrt requires Information on a specific outfall discharging to either the groundraters or the surface~aters.ENTER THC PERMIT NLSIBER IN THE BOX AT THE TCP OF THIS FORM.THE PERMIT hWBER CAN BE FOUND Ot(THE FRONT PAGE OF YOUR EXPIRING pERMIT.If this ls a ne>>or not previously permitted feei llty, then leave blank and a number wll I be assigned.Enter the outfall number in the space provided for each paae of Section I I.For each Individual dischar e point a separate set of Section I I forms (Items 4 and 5)must be f I lied out.ITEM 4 GROUNDWATER DISCHARGE INFORMATION (00 NOT IIICLUOE DEEP WELL IIUECTION INFORMATION IN THIS ITEM)A.-O.The applicant shall address each of these parts If the discharge fran this outfal I Is to the aroundwater. ITEM 5 EXISTING OR EXPECTED (FOR A NEW DISCHARGE) WASTEWATEP. CHARACTERISTICS OF GROUNDWATER OR SURFACE WATER DISCHARGE (00 NOT INCLUDE W LL IN)I IN IN H A.The applicant shel I report available discharge data (real data for existing discharge or expected data for a proposed discharge) for the parameters as listed.These parameters shall be addressed for either a surface rater discharge or as appropriate for a groundwater discharge. For assistance In determining appropriate parameters a groundrater dl scharae app I leant may contact the Groundwater Duality Division, Permits section or the appropriate Groundwater Duality Division's District office.The applicant shall reporr the sample type code best describing each reported piece of data.See coding on the left margin of this form.If this outfall Is a surface water discharge, the applicant must report quantitative data for each parameter identified b an eel y", I~e 9 d" e b'e~.b b ee et tb ebbtdby dee t tlb I, tlb bdb d bt tt<<ett tbl~ebllebtl 8.If data Is available for other parameters not listed above In A.or other parts of this application the applicant should report that data in the blank spaces provided In this part.I'OTES: I.Unit codes for parmreters reported In parts A and 8 can be found on the lett hand side of this fotta.2.Grab sample shall be used to analyze for pH, temperature, tote)phenols, residual chlorine, oil and grease.and fecal coliform In a surface water discharge unless other frequency-sample type analyses are available. See GlossarY (page 48)for definition of grab sample.24-hour composite samples shall be used to analyze for Total B005, ccD, Toc, Amnonla Nitrogen, and Total Suspended Solids In a surface~ater discharge unless other frequency>>sample type analyses are available. See Glossary (page 4B)for definition of composite sample.4.REpoRTING 0F INTAKE DATA.You are not required to report'unless you wish to demonstrate your el)glbl llty for a metr effluent IimltatiOn far One Or mOre pOllutantS, that IS, an effluent llmltatlOn adjuSted by SubtraCtlng the average level of the pollutant(s) present In your Intake water.NPOES regulations allow net limitations only In certain circumstances. To demonstrate your eligibility, report the average of the results of analyses on your Intake water (lf your rater is treated before use, test the water after it Is treated), and attach a separate sheet containing the folloring for eacn pollutant: (a)A statement that the Intake~ater Is drawn from the body of water into which the discharge Is made.(Otherrlseb you are not eligible for net limitations.)(b)A statement of the extent to which the level of the pollutant Is reduced by treatment of your wastewater.(Your limitations rill be adjusted only to the extent that the pollutant is not removed.)(c)'when applicable (for example, when the pollutant represents a class of compounds), a demonstration of the extent to which the pollutants In the Intake very physically, chemically, or biologically from the pollutants contained In your discharge.(Your limitations wl I I be adjusted only to the extent that the intake pollutants do not vary frow the discharged pollutants.) 5.If you have two or more substantially Indentlcal outfalls, you may request permission fran your permitting authoritv to sample and analyze only one outfal I and submit the results of the analysis for other substantially Identical outfalls.If your reauest is granted by the permittlna authority, on a separate sheet attached to the application form Identify which outfall you did test, and describe why the outfal ls>>hich you did not test are SubStantlally ldentlCal tO the Outfall whlCh yOu did teSt.36 .>L.H<b~On]gJ$aarCOR POR AT I ON LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (4'12)747-2684 January 11, 1994 Report No.: 00018818 Section A Page 2 CLIEHT NAME: ADDRESS: ATTENTION: INDIANA MICHIGAN POWER COMPANY ONE COOK PLACE BRIDGEMAN, MI 49106-MR.ROLAHD BEEN HUS CLIENT NO: 0663 0018 WORK ORDER HO: 55830 VEHOOR HO: 05411000 Carbon Copy: SAMPLE ID: OIL/WATER SEPARATOR HUS SAMPLE NO: P0258839 P.O.NO.: 69034-040-3N DATE SAMPLED: 28-OEC-93 DATE RECEIVED: 29.DEC.93 APPROVED BY: Kieda, Chuck TEST LN CODE OETERMINATIOH RESULT UNITS 1 G122W 3 1106 4 1680 5 1490 PCB ANALYSIS PCB-1016 PCB-1221 PCB-1232 PCB-1242 PCB-1248 PCB-1254 PCB-1260 Carbon, Organic-Nonpurgeable Oil and Grease, Gravimetric pH<0.05 ug/L<0.05 ug/L<0.05 ug/L<0.05 ug/L<0.05 ug/L<1.0 ug/L<1.0 ug/L 6 mg/L 3 mg/L 7.4 COMMENTS: SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I PERMIT~>>IVIz p p p 5827 NUMBER i EM 6 PRIORITY POLLUTANTS AND ADDITIONAL INFORMATION FOR SURFACE WATER DISCHARGE ONLY REQUESTED INFCRt47ICH ~~ADCRESSED~QRFACE HATER DISCHARGERS. IDIEt NEW USE DISCHUIGERS 2IIIIL PROVIDE EXPECTED VALIES FOR THE CUAMflTATIVE AND QUALITATIVE INFCRHAT ION REOIKSTKD BEUWe A.IS THIS FACILllY A PRItVVIY INDUS1RY?(REFER TO TABLE IA Par<gJ)(IF tOe GO 70 E)(IF Y 5 GO TO B)Be IMIICATE lYPE OF PRIIVUIY INDUSTRY AS LISTED IN TABlE IA PAGoK Q, (CONTIN%WITH C.)C.DOES 1HI5 CUIFALL DISCHARGE CctlTAIN ANY PROCESS WASTEWATER?(IF NOe GO TO E)(IF YKSe GO 70 D)Do INDICATE HlICH GC/tm FRACflONS FttST BE TESTED FCR~(REFER TQ TABLE Ia Pate 9D KIIE!FOR EACH GC/HS FRACTION OIECKKDeKAOI SPECIFIC ORGANIC TOXIC POLunaNT HITHIN EacH FRACTIQN t55I BE AMALYIKD FOR (5EE TABLE I IA PAGE 92, IM ADDITIQNe ALL FRIARY IMXISTRY APPLICANTS WITH A PROCESS WASTEWATER DISCHARGE'~ PROVIDE QUAtnI TATI VE DATA FOR EACH TOXIC POLLUTAMT IN TAKE IIIA PA%Q)e RECORD ALL DATA ON FCRHS PROVIDED (ITKH 7)IN THIS BQ)KLETe (CctnttUE HllH E K BELCH)~NA VOLATILE Q BASE/NElm4L D cele PESTI CIDE Analysis per J.B.Beauboeuf Target Permit Effluent Limits YES MO STM E'LE C PWR X YES NO Ee IF~QRFACE HATER DISCHARGE APPLICAtn (PRIMARY OR SKCOGI4RY IMIXISTRY)e REGARDLE%OF THE lYPE OF DISCHUIGKe KMHS OR HAS REASON TQ BELIEVE THAT AHY POLLUTANT LISTED IN TARE IIA AND IVA PAGES~IS DISCHARGED FIKtt ANY QITFAILeltE QIAtntTATIVE DATA ISgif, BE PROVIDEDe RECCRD AIL DATA ON FORtS PROVIDED (ITKH 7)IN 1HIS BOOKLETe Fe IF ANY QRFACE HATER DISOIARGK APPLICAMT (PRIMARY OR SECONDLY IMXISTRY)e REGARDLESS OF lYPE OF DISCIIARGKe KMXts OR HAS REASON TO BELIEVE ANY POLLUTANTS LISTED IN TABLE VA PAGE+ARE DISCHARCM FRCH ANY QnFAIL TIE APPLICANT Ltd(I DESCRIBE REASONS FOR TIE PQLlnaMT BEING PRESen AMI PROVIDE AMY AVAILABLE QIAMTITATIVE DATAe RECORD ALL DATA ON FOIVts PROVIDED (ITKH 7)IN THIS BCOKLETe ter APPLI CABLE/BELIEVED ABSENt N/A D PRESENT/DATA IS ATTACHED Q MOT APPLICABLE/BELIEVED assen N/A PRESENT/DATA I 5 ATTACHED D Ge AIL SIRFACE HATER DISCHARGE APPLICANIS (PRIMARY AMl SECCN04RY IMXITRIES) QR~actIRKS 2 4.)-TRtosfxtfPtEMDIY AcET!c AclD (2, 4, 5-7):-.4,~7RtoIuwoPIEMIKY) PRQPAMQIC AOID (SILYKx, Z, 4, 5, TP)TRI04xRQPtERx.(TcMPJ 0R HExacMJIRQPtEIE tHCPSJ (ALL DATA FcR TIE ABOVE MIST BE GENERATED USING STAMFORD ANALYTICAL CALIIRATICN PROCBXRES) QR KREIS OR HAS REASCN 1Q BELIEVE THAT TCKQ IS CR tlkY BE PRESBIT IN 7%IR DISOIARGEe ~REPORT tXIALITATIVE IVITA GENERATED%IOI USED A SCREENING PROCHXRE tOT CALIBRATED HllH At4LYTICAL STAleatme FOR 2 De 7 8e-TEIIIAOLORODI~DIOXIN (TCKD)e REQRD AIL DATA Qt FOtts PROVIDED (tlttt 5 IN THIS BOOKLETe Je IF TtE QRFACE HATER DISCHARGE APPLICAtn KMX6 CR HAS REASON lQ BELIEVE THAT BIQDGICAI, TOXICITY TESTS WERE HADE IN THE tasr TIREK (5)YEARS ON AHY QF TIE APPLICANT 5 Dl~OR CN A RECE IV IMG HATER IN REIATION lQ A DISOIARGEe PROVIDE THIS ltFORHATION AS AM ATTAOFENT TQ THIS APPLICATIOMe Ke IF A COtnRACT LABORATORY OR CQIQLTIMG FIRN PERFCR%D Petr OF TIE AMAYSES RECUIRED BY THIS APPLICATIOMe PROVIDE TIE t4V%AHD AICRESS OF EAOt LABORATTRY OR Flirt AM)ttE ANtLYSES PERFCR%D AS AM ATTAOtEtn OF THIS APPLICATIONe Le DO YCU DISCHARGE ANY OTIER TOXIC OR IMJIRIOUS CteIICAL QBSTAHCES NOT LISTED IN TABLES IV PAGE tt AMI IIA TtRQFtl VA PA4S~~, IF YES TAN IDEtntNY TIE OKttICAL QISTANCES AND ESTIHATE 7%FINAL EFFURIT CctK:em47ICNS, Slstttr THIS IHFORQTIOH AS AM ATTAOPEtn TQ THIS APPLICATION> wr APPLICABLE/BELIEVED allen N/A Q PRESENT/DATA Is ATTAOED Q ter APPLICABLE N/A Q APPLICABLE/SKE ATTACHED Q tOT APPLICABLE pg APPLICABLK/SEE ATTACHED MOT APPLI CABLE 0 APPLICABLK/sEE ATTADIKD N/A 37 IHSTRUCTIQNS FOR CCMPLETING SECTION I I ITEM 6 This form requires Information on a specific outfall discharging to the surface waters.ENTER THE PEIB(IT NUMBER IN THE BOX AT THE TCP OF THIS FCRM.THE PERMIT N(P(BER CAN BE FOUNO ON THE FRONT PAGE OF YOUR EXPIRING pERMIT.If this Is a new or not previously permitted facility, then leave blank and a number<<III be osslqned.Enter the outfall number in the space provided for each page of Section II.For each Individual dlscharoe point o separate set of Section Il, Item 6 forms must be f1 lied out.ITEM 6 PRIORITY POLLUTANTS ANO AOOITIONAL INFO(a(ATION NOTE: If yOu haVe twO Or mOre Subatantlal ly IndentlCal OutfallS, yOu may requeSt permlSSIOn frCm yOur permitting authOrlty tO somp(e and analyze only one outfall and submit the results of the analysis for other substantially Identical outfalls.If your request Is granted by the permitting authority, on a separate sheet attached to the application form Identify which outfall you did test, and describe why the outfalls which you did not test are substantially ident)col to the outfall whlCh yOu did teSt.NOTE: A.-C.ond E.-J.O.40 CFR Port I22.2)(g)(8), Friday, April I, l983, provides for a Small Business Exemption from the reporting of quantitative data for orgonlc toxic pollutants and toxic pollutants as required by Part 122.2I(g)(7)(il)(A) or I22.21(g)(7)(ill)(A). These parts are selfwxplonatory and do not require further Instructions, Simply go through each part and do as Indicated. Several Industrial categories and subcategories hove been exempted fran submitting dots on certain GC/MS Fractions (40 CFR Pert l22, Vol.48, No.64, Friday, April I, l983, Notes I, 2, ond 3).Review the following list to determine whether your facility qualifies to be exempt from reporting GC/MS (Gas ChrcmatographY/ Moss Spectroscopy) Fractions. GC/MS Fraction Testing and Reporting Exemptions Textile MIIIs Indust-All four GC/MS organic fractIons In the Greige MIIIs Subcategory. -Pesticide fraction In oil other svbports of this Industry.Ore Mlnln and Dress(Indust-Volatile, base/neutral, and pesticide fractions In the Bose and Preclovs Metals Subcategory. -All four GC/MS organic fractions ln all other subcategories of this Industry.Gum and Mood Chem(cols Industr-Pesticide fraction In the Tall Oil Rosin Subcategory and the Rosin Based Oerlvatlves Subcategory. Pesticide and base/neutral fractions In~II other subcategories of this Industry.Pvl and Paper Indust-Pesticide fraction In Papergrade Sulfite subcateqorles (subparts J and U).-Base/neutral and pesticide fractions in Oelnk Subpart Q, Olssolvlnq Kraft Subpart F, and Paperboard from Maste Paper Subpart E.-Volatile, base/neutral, pesticide fracttons In the BCT Bleached Kraft Subpart H, Sam(-chemical Subparts 8 and C, and Nonlntegrated.F(ne Papers Subpart R.-Acid, base/neutral, and pesticide fractions (n Fine Bleached Kraft Subpart I, Dissolving Sulfite Pulp Subpart K, Ground-wood Fine Papers Subpart 0, Harket bleached Kraft Subpart C, Tissue from Mastepaper Subpart T, and Nonlntegrated Tissue Papers Subpart S.Steam Electric Power Plant Industr-Base/neutral fraction In the Once-Through Cooling Mater, Fly Ash, and Bottom Ash Transport Mater process wastestreams. 38 SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I PERMIT~Ml 0005827 CRmCAL MATERIALS TOXIC POLLUTANTS A.USE THIS DATA SHEET IO RECORD INRXVIATION AS RECJIRED IN: (DECK APPROPRIATE BOX IOR tttICH INRÃHATICN THIS Dl>>TA SHEEf REPRESBffs>>) Q 1>>SECflOM 1ri IIEII M>>GRIJ&AIER DISCHARGE IMFCVIATION (PJGE 33)O 2>>SECTICN I I>>ITEN 6>>PRICRIIY RXIUTAMTS IH SNFACE IIAIER DISCHIVttK (PAGE 37)O 3.B.BEUXI: CRITICAL HAIERIALS (TABLE IV)IN SIXIFACE HATER DISaaeK (PAX 39)HAZARDOUS SUBSTANCES IN DISCHARGE B>>LlsT AMv cRITlcAL HATERIAL (TABLE Iv PAGE 6)MDT ADDREssED IN sEcTIctt II IIEH 6 PRIDRllY POLUJTAMTS INICH YCJ IOXXI OR HAVE REASON TO BELIEVE TO BE PRESENT IN IIE DISCHUIGE>> SEE REVERSE SIDE OF'THIS PAGE FOR FIJIIIER DIRECTICNS>> z APPLICABIE (SEE BEUXI)A>>NVK OF CRITICAL HATERIAL CR PRIORITY POLUJTAMT FI>>B>>AVERAGE CXCEIIIRATIONJ QPRE lYPEJ¹OF JNALYSES C>>HAXPSlt CXCENIRATICN AIO HASS WIT CCK SAWLE lYPE OF ANALYSES LJ WIT CXK WIT CODE A>>MJt%OF CRITICAL HATERIAL CR PRIORllY RXLUTANT wc>>I B.AVERAGE CXCENIRATICIJ QFFLE TYPES¹OF ANALYSES C>>HAX Pelt CNCEIIIRAT ION AJO HASS NIIT CXK SWEE TYPE OF ANALYSES~.LLLJ LJ WIT CXK WIT CXE UNITS CODE 1 My/I Uy/I 3S/DAY KQ/DAY GRAB 2 24 HR.COMR A>>NJJ%OF CRITICAL HAIERIAL CR PRICRtlY POLUJTANT wn B, AVBIAGE CXCBIIRATIIXIJ SWLE IYPE1 8 OF ANALYSES I C>>HAXPMI COICEIIIRATICN AIO HASS A>>Mt%CF CRITICAL HAIERIJI.CR PRIORllY RJUJJTANT B>>AVERJGE CDICEIIIRATIONJ QtPLE IYPEJ¹OF ANALYSES C HAXPtlt CNCEIIIRATIIXI AJO HASS A>>NA%OF CRITICAL HATERIAL CR PRIORITY AXLJJTAMT B>>AVERAGE CXCENlltATIIXI J QfRE IYPEJ¹OF ANALYSES I C>>HAXPSN CXCBIIRATION AJO HASS WIT COE QIVLE TYPE IK ANALYSES IN WIT CXK WIT CXK QPAE TYPE INIT CODE till T.CXK LJ~~~LJ Wlr CCK aVez TYPE¹OF ANALYSES LJ INIT COE INIT CODE A>>HAIK OF CRITICAL HATERIAL CR PRICRIIY POLUJfANT we B AVERAGE CNCENIRATIOtU Q%LE TYPE J¹OF ANALYSES C.HAXPSPICOCBIIRATICN AJO MSS WIT CXK QJFIK TYPE OF ANALYSES LJ WIT CODE INIT COIK A>>NJPK OF CIITICAL HAIERIJL Ct PRIORIIY RXLllfAMT wI>>', AVBIJGE CXCBAltATIOI J ALE IYIE I¹OF ANALYSES I C>>HAXIISPI CXCENIIIATICN AJO HASS A.NVK OF CRITICAL HAIERIAL OR PRIORllY RXUJTAMT we B>>AVERAGE CXXXJIIRATIONJ SAPFLE TYPEJ¹OF AlWYSES C, HAXPSH CaCIIIIRAIICtt AIO HASS IPIIT CCK Qtl>>LE lYPE¹OF ANALYSES LJ INIT CXK IN I CODE LJ IN II CXK~TYPE OF ANALYSES LJ Wlr CXK WIT CODE LJ~~~LJ ADDITreuL PJGES oF THrs IIEH 7 ARE AIIActED POR IIE REST DF IIK cRITrcAL Cl YEs HAIERIALS Jva/Ct PRrarIY PCLIJJTJttfs RECIJIRED TO BE RERXIIED, E JO 39 INSTRUCTIONS FOR CI7ZPLETING SECTION I I ITEN 7 This torm Is to be used by both surface and groundvater applicants to record information on any Michigan critical material, E.P.A.priority pollutant, or hazardous substance In vhich this application requires data to be provided.This vould Include any chemical substance from the Hlchlgan Critical Materials Register ITable IV), the E.p.A.priority Pollutant Listing ITable V), or Tables I Ih-Vh which I ists Organic Toxic Pol lutants, Other Toxic Pol lutants, Conventional and Nonconventional Pol lutants and Hazardous Substances. ITEN 7 CRITIChL MhTERIALS PRIORITY POLLUTANTS AND/OR HAZARDOUS SU8STANCES IN THE DISCHARGE Material I 2 3...8 A.List the name of the chemical substance Icrltlcal mater lal, priority pollutant, or hazardous substance) tron Tables IV." and IIA-VA as reoulred In the box vhlch you checked In A.I-3.above.Enter each chemical substance's parameter number as listed In Tables IV, V and IIA-VA If provided.8.Provide the average concentration of the chemical substance named In A.Indicate the sample type used and the number of analyses made to provide the ccncentratlon data for the chemical substance nmned In A.n C.Provide the maximus concentration and determine the mass loading of the chemical substance naeed In A.I~I f only one analysis was made for a chealcal substance then record that data as a maximus value.It more then one analysis has been made for a chemical substance then provide an average value of those analyses and the maxlmma value~2.This Section II, Iten 7, Data Sheet provides space tor recording data for 8 chemical substances (Materlalsl ~Additional space for recording of data tor more than 8 Materials can be made by making copies of this Item 7 Data Sheet as needed.It Is also Important to use a separate set of Data Sheets for each applicable reporting reaulrmnent as listed In A.l-3.and tor each outfall.3~Refer to the left margin tor the code number representing the'smapl~type used and the appropriate unit codes.40 VOLATILE ORGANIC ANALYSIS RESULTS GC/HALL ANALYSES USING EPA METHOD 8010 li n m I ID: TRAN AT HBA IN D II 2-DE Da e Anal zed: 05-JAN-94 Matrix WATER Anal tical Batch 4: 122093-801020-0-3 LAL m I ID: L1-7 D R iv: 2-DE Dilution Factor: 1 QC Batch ID: 122093-801020-0-3 BCIVI BFB Srro R vr 99 76 Limi 65-125 60-1 20 Constituent Dihlr ifl r m hn hlrm hn Vin I chloride Bromomethane hl r hn Tri hl r fl r m h ne 1 1-Dichloroethene Meth lene chloride r n-1 2-Di hi r h n 11-Dihl r hn Chloroform 1 1 1-Trichloroethane r n r hl rid 12-Dihl r hn Trichloroethene TCE 1 2-Dichloro ro ane Brm ihlrm hn 2-hl r hlvin I hr cis-1 3-Dichloro ro ene trans-1 3-Dichloro ro ene 112-Trihl r hn T r hir hn P E Dibromochlorometh an e Chlorobenzene Brmfrm 1122T r hl r han 1 3-Dichlorobenzene 1 4-Dichlorobenzene 1 2-Dichlorobenzene Concentration (yg/L)<0.50<3<6<4.5<0.5<0.5<2 Reporting Detection Limit/L 0.5 0.5 0.5 Data Qualifieris) LOCKHEED ANAL YTICAL SERVICES h7 VOLATILE ORGANIC ANALYSIS RESULTS GC/PID ANALYSES USING IVIETHOD 8020 lin m I ID: TRAN AT HBA IN D II: 2-DE Date Anal zed: 04-JAN-94 Matrix: WATER Anal tical Batch II: 122093-801020-0-3 LAL ml ID: L1-7 D R iv: 2-DEC-Dilution Factor: 1 QC Batch ID: 122093-801020-0-3 TFT BFB rr R vr 89 89 Q Limi s 70-120 75-120 Benzene T I ne Constituent Concentration IL<0.5 Reporting Detection Limit IL 0.5 Data Qualifier s hlr n n Eth I Benzene m-X Iene-X I n 1-Dihl r n n 1 4-Dichlorobenzene 1 2-Dichlorobenzene <2<2 LOCKHEED ANALYTICAL SERVICES SEIVIIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 P 1 f2 li n m I ID: TRAN.AT HBA IN Date Collected: 28-DEC-93 Matrix: WATER An I i IB h¹': 111 4-27-8 QC Batch ID: 8270-SEMIVOLATILES-3964 LAL m I ID: L1-2 Date Received: 29-DEC-93 Dilution Factor: 1 D Exr: 4-AN-4 Date Anal zed: 11-JAN-94 2-Fluoro henol Phenol-d, Nitro benzene-d, RRO ATE RE VERY 38 28 59 Limi 21-100 10-94 35-114 2-Fluorobi hen I 2 4-Tribrom h n I p-Terphenyl-d 62 84 43-116 1-12 33-141 Phenol n I n Concentration L Reporting Detection Limit L D alifi r bis 2-Chloroeth I ether 2-hl r hn I 1-Di hl r nz n 1 4-Dichlorobenzene Benz I alcohol 12Dihl r nz n 2-M h I h n I bis 2-Chloroiso ro I ether 4-Meth I henol N-Ni r-Di-n-r I min Hx hlr hn Nitrobenzene Iso horone 2-Ni r h n I 2 4-Dim h I h n I Benzoic acid bis 2-hloroethox me hane 24-Di hl r h n I 1 4Tri hl r nz n Na hthalene 4-Chloroaniline Hx hlr in 4-hlr--m hlhnl 2-Meth Ina hthalene Hexachloroc clo entadiene<55 55 LOCKHEED ANALYTICAL SERVICES U5 SEMIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/IVIS ANALYSES USING IVIETHOD 8270 Client Sam le ID: TRANS.CATCHBASIN LAL Sam le ID: L1009-29 P 2 f2 Constituent 24-Trihl r hn I 24-Trihl r h n I 2-Chlorona hthalene 2-Nitroa niline Dim h I hh I A n hhln 2 6-Dinitrotoluene 3-Nitroaniline A n hhn 24-Dinir h n I 4-Nitro henol Dibenzofuran 2 4-Dini r I n Di h I hh(4-Chloro hen I-hen lether Fluorene 4-Ni r nilin 4-Dini r-2-m h I h n I N-Nitrosodi hen lamine 4-Bromo hen I-hen lether Hx hlr nzn Pn hlr hnl Phenanthrene Anthracene Di-n-I hh I Fl rnhn P rene But Ibenz I hthalate'-Di hl r nzi in B nz nhr n Chr sene bis 2-Eth Ihex I hthalate Di-n-I hh I 8nz fl rnhn Benzo k fluoran hene Benzo a rene In n 12-rn Di nz h n hr n Benzo h i er lene Carbazole Concentration (IL)<28<28<2<28<2<2<2<22 280 Reporting Detection Limit (IL)28 28 28 22 Data Qualifier(s) EB LOCKHEED ANALYTICAL SERVICES VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8270 TENTATIVELY IDENTIFIED COMPOUNDS Client Sample ID: TRANS.CATCHBASIN Date Received: 29-DEC-93 Matrix: WATER Analytical Batch: 011194-8270-B LAL Sample ID: L1009-29 Date Analyzed: 114AN-94 Dilution Factor: 1 QC Batch ID: 8270-SEMIVOLATILES-3964 Tentatively Identified Compound Hydrocarbon Hydrocarbon Unknown Hydrocarbon Unknown Hydrocarbon Unknown Hydrocarbon Unknown Unknown Hydrocarbon Hydrocarbon Hydrocarbon Hydrocarbon Unknown Hydrocarbon Hydrocarbon Hydrocarbon Hydrocarbon Hydrocarbon Estimated Concentration (pg/L)10 20 10 20 10 30 10 10 30 30 30 20 10 10, Retention Time (minutes)14.50 1 5.00 1 5.83 1 6.75 17.58 17.79 1 8.01 18.40 19.17 1 9.25 19.42 19.96 21.43 21.51 22.32 22.95 24.1 7 24.54 25.43 26.65 Data Qualifier(s) LOCKHEED ANALYTICAL SERVICES 7 u I SEIVllVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 lin m I ID: TRAN.AT HBA IN D II Matrix: WATER-D Anal tical Batch II'11194-8270-B QC Batch ID: 8270-SEMI VOLATILES-3964 LAL m I ID: L1-2 RE D R iv'-DE Dilu ion Factor: 4 Date Extracted: 04-JAN-94 Date Anal zed: 18-JAN-94 Pa e1of2 SURROGATE RECOVERY Q Limi s 2-Fl r h n I Phenol-d, Nitrobenzene-d, 2-Fluorobi hen I 2 4 6-Tribromo henol p-Terphenyl-d,4 42 28 56 66 76 72 21-1 10-94 35-114 43-116 10-123 33-141 Phn I n iun Concentration L<4 Reporting Detection Limit L D bis 2-Chloroeth I ether 2-Chloro henol 1-Dihl r nz n 14Dihl r nz n Benz I alcohol 1 2-Dichlorobenzene 2-M h I h n I i 2-hlri r I hr 4-Meth I henol N-Nitroso-Di-n-ro lamine Hx hlr hn Ni r nz n Iso horone 2-Nitro henol 24-Dim h I h n I B n i i bis 2-Chloroethox methane 2 4-Dichloro hanoi 1 2 4Tri hl r n n N hhln 4-Chloroaniline Hexachlorobutadiene 4-hlr--m hlhnl 2-M h Ina h hal n Hexachloroc clo entadiene<40<40<4<40<40<40<4<4<40<40<4<4<40<40<4<40<40<4<4<40<40<4<4<40 40 40 40 40 40 40 40 40 40 40 40 40 40 LOCKHEED ANALYTICAL SERVICES SEIVIIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/IVIS ANALYSES USING METHOD 8270 Client Sam le ID: TRANS.CATCHBASIN LAL Sam le ID: L1009-29RE P 2 f2 Constituent 24-Trihi r h n I 24-Trihl r hn I 2-Chlorona hthalene 2-Nitroaniline Dim h I hh I A n hhln 2 6-Dini ro oluene 3-Nitroaniline A n hhn 2 4-Dini r h n I 4-Nitro henol Dibenzofuran 2 4-Dini r lu n Di hlhhl 4-Chloro hen I-hen lether Fluorene 4-Ni r nilin 4-Dini r-2-m h I h n I N-Nitrosodi hen lamine'-Bromo hen I-hen lether Hx hlr n n Pn hir hnl Phenanthrene Anthracene Din-I hh I Fl rnhn P rene But Ibenz I hthalate'-Dihl r ni in B nz n hr n Chr sene bis 2-Eth Ihex I hthalate Di-n-I hh I Bnz fl rnhn Benzo k fluoranthene Concentration (IL)<4<4<40<100<4<4<40<100<4<100<40<4<4<40<40<40<40<4<40<40<4<4<40<40<4<40 350<4<4<40 Reporting Detection Limit (IL)4Q 100 4Q 100 100 4Q 4p 4Q 4Q 40 40 4Q 4p 40 40 40 4p"40 Data Qualifier(s) Benzo a rene In n 12 r n<40<4 40 Di nz h n hr n Benzo h i er lene Carbazole<4<40<40 40 40 LOCKHEED ANALYTICAL SERVICES PESTICIDE ANALYSES RESULTS BY GC/ECD USING METHOD 8080 FOR COOK NUCLEAR PLANT Clien Sam le ID: TRANS CATCHBASIN Da e Collec ed: 28-DEC-93 Date Extracted: 04-JAN-94 Matrix: WATER Anal tical Batch 4: 012094-8080-A-1 LAL Sam Ie ID: L1009-21 D e Received:29-JAN-94 Date Anal zed: 21-JAN-94 Dilution Factor: 1 QC Grou ID: 8080 PEST/PCBS 3965 SURROGATE RECOVERY o TCMX DCB 85 40 QC Limits 60-150 60-150 A-'BHC B-BHC G-BH D-BHC Constituent Concentration /L<0.05<0.05 Reporting Detection Limit/L 0.05.0 0.05 Data Qualifier(s) HEPTACHLOR ALDRIN HEPTACHLOR EPOXIDE G-CHLORDANE ENDOSULFAN I A-CHLORDANE 4 4'-DDE 4 4'-DDT DIELDRIN ENDRIN ENDOSULFAN II 4 4'-DDD ENDRIN ALDEHYDE ENDOSULFAN SULFATE METHOXYCHLOR TOXAPHENE PCB-1016 PCB-1221 PCB-1232 PCB-1242 PCB-1248 PCB-1254 PCB-12 0 TECHNICAL CHLORDANE MIREX TCMX-tetra-chloro-meta-xylene DCB-Deca-chloro-biphenyl <0.05<0.5<0.05<0.05<0.05<0.1<0.1<0.1<0.1<0.1<0.5<5<2<0.1 0.05 0.5 0.05 0.05 0.0 0.1 0.1 0.1 0.1 0.1<0.1 LOCKHEED ANALYTICAL SERVICES g h V V METALS RESULTS Client Sam le ID: TRANS.CATCHBASIN Date Collected: 12-28-93 Matrix: round"water: LAL Batch ID(s): 1220 im Date Received: 12-29-93 POP69095-040-3N .Conitituents-Aluminum Antimon Arsenic Barium Be Ilium Boron Cadmium Chromium Cobalt Co er tron Lead Ma nesium Man anese Mercu Mol bdenum Nickel Selenium Silver Sodium Thallium Tin Titanium Vanadium Zinc.Method 6010 6020 6020 6020 6020 6010 6020 6020 6020 6020 6010 6020 6010 6020 7470 6020 6020 6020 6020 6010 6020 6020 6010 6010 6020 Concentration .{m IL)<0.20<0.060<0.010<0.20<0.005<0.20<0.005<0.010<0.060<0.025 0.54<0.003 1.6 0.059<0.0002<0.20<0.040<0.005<0.010<5.0<0.010<0.20<0.10<0.050 0.15 Reporting Detection Umit lm/L)0.20 0.060 0.010 0.20 0.005 0.20 0.006 0.010 0.060 0.025 0.10 0.003 5.0 0.015 0.0002 0.20 0.040 0.005 0.010 5.0 0.010 0.20 0.10 0.050 0.020 Data Qualifieris) Date: AL.Anal zed;.:-Sam le ID 01-20-94 L1009-15 01-27-94 L1009-16 01-27-94 L1009-15 01-27-94 L1009-15 01-27-94 L1009-15 01-20-94 L1009-15 01-27-94 L1 009-1 5 01-27-94 L1 009-1 5 01-27-94 L1 009-1 5 01-27-94 L1009-15 01-27-94 L1 009-15 01-27-94 L1009-15 01-20-94 L1 009-1 5 01-27-94 L1009-15 01-07-94 L1009-15 01-27-94 L1009-15 01-27-94 L1009-16 01-27-94 L1009-15 01-27-94 L1 009-15 01-20-94 L1 009-1 5 01-27-94 L1 009-1 5 01-27-94 L1 009-15 01-20-94 L1 009-15 01-20-94 L1 009-1 5 01-27-94 L1 009-15 Comments: LOCKHEED ANAL YTICAL SERVICES GENERAL CHEMiSTRY RESULTS Client Sam le ID: TRANS.CATCHBASIN Date Collected: 12-28-93 Matrix: round water LAL Batch IDIs): 1229 im Date Received: 12-29-93 PO¹69095-040-3N Constituent Method Result Reporting Detection Limit Data Qualifierlsl Date Anal zed LAL Sam le ID Fluoride, in m/L Chloride, inm IL Nitrate-Nitro en, in m IL Nitrite.Nitro en, in m IL Sulfate, inm IL Ammonia-Nitrogen, inm IL Total Cyanide, in mg/L 340.2 300.0 300.0 300.0 300.0 350.1 335.2<0.15 0.52<0.017<0.012 4.7 13<0.020 0.15 0.016 0.01 7 0.01 2 0.059 0.50 0.020 DI1:10)01-24-94 L1 009-3 12-29-93 L1009-3 12-29-93 L1009-3 1 2-29-93 L1009.3 12-29-93 L1009-3 01-05-94 L1009-7 01-03-94 L1 009-1 1 Comments: LOCKHEED ANALYTICAL SERVICES VOLATILE ORGANIC ANALYSIS RESULTS GC/HALL ANALYSES USING EPA METHOD 8010 li n m I ID: BLANK D Coll'A Date Anal zed: 04-JAN-94 Matrix: WATER Anal tical Batch 4: 122093-801020-0-3 LA m I ID: AD 17 D R iv: NA Dilution Factor: 1 QC Batch ID: 122093-801020-0-3 BCM BFB urro a e Recover 94 94 Limi s 65-125 60-120 Constituent Di hl r ifl or me h ne hlrm hn Vin I chloride Bromomethane hlr hn Trihlrfl rm hn 1 1-Dichloroethene Meth lene chloride r n-1 2-Di hl r h n 11-Dihl r hn Chloroform 1 1 1-Trichloroethane r n r hl ri 12-Dihl r hn Trichloroethene TCE 1 2-Dichloro ro ane Brom i hl rome h n 2-hlr hlvinl hr cis-1 3-Dichloro ro ene trans-1 3-Dichloro ro ene 1 1-Tri hl r han T r hlr hn P E Dibromochlorom ethane Chlorobenzene Br m f rm 1 1 22-T ra hl ro han 1 3-Dichlorobenzene 1 4-Dichlorobenzene 1 2-Dichlorobenzene Concentration (yg/L)<0.50<3<6<4<0.<0.5<0.5<2 Reporting Detection Limit IL 0.5 0.5 0.5 Data Qualifier(s) LOCKHEED ANAL YTICAL SERVICES VOLATILE ORGANIC ANALYSIS RESULTS GC/PID ANALYSES USING IVlETHOD 8020 li n m I ID: BLANK D e lie e: NA Date Anal zed: 04-JAN-94 Matrix: WATER Anal tical Batch¹: 122093-801020-0-3 LAL ml ID: AD 17 D R iv: NA Dilution Factor: 1 QC Batch ID: 122093-801020-0-3 TFT BFB rr R vr 102 99 QC Limi 70-120 75-120 Benzene T I n Constituent Concentration /L<0.5 Reporting Detection Limit/L 0.5 Data Qualifier s hlr nzn Eth I Benzene m-X lene-X I n 1-Di hl r nz n 1 4-Dichlorobenzene 1 2-Dichlorobenzene <2<2<2 LOCKHEED ANAL YTICAL SERVICES t,'Z AQUEOUS MATRIX SPIKE DATA

SUMMARY

FOR VOLATILE ORGANIC ANALYSIS USING EPA IVIETHOD 8010 Client Sample ID: MATRIX SPIKE/DUPLICATE Analytical Batch 4:.122093-801020-0-3 QC Batch ID: 122093-801020-0-3 LAL Sample ID: L1012-7 Date Analyzed: 05-JAN-94 Constituent 1,1-Dichloroethene Trichloroethene Chlorobenzene Spike Added lpg/L)15 15 15 Sample Concentration tpg/L)ND ND ND IVlatrix Spike Concentration lyg/L)7.30 14.5 1 2.6 Recovery 49 97 84 QC Limits Recovery 28-167 35-146 38-150 QC Limits Constituent 1,1-Dichloroethene Trichloroethene Chlorobenzene Spike Added lyg/L)15 15 15 Matrix Spike Duplicate Concentration (pg/L)11.4 14.5 12.6 Recovery 76 97 84 RPD 43+RPD 20 20 20 Recovery 28-167 35-146 38-150 LOCKHEED ANALYTICAL SERVICES Il

AQUEOUS MATRIX SPIKE DATA

SUMMARY

FOR VOLATILE ORGANIC ANALYSIS USING EPA METHOD 8020 Client Sample ID: MATRIX SPIKE/DUPLICATE Analytical Batch¹: 122093-801020-0-3 QC Batch ID: 122093-801020-0-3 LAL Sample ID: L1012-7 Date Analyzed: 05-JAN-94 Constituent Benzene Toluene Chloroben zen e Spike Added (yg/L)15 15 15 Sample Concentration (yg/L)ND ND ND Matrix Spike Concentration (yg/L)12.9 12.5 12.6 Recovery 86 83 84 QC Limits Recovery 39-1 50 46-148 55-135 QC Limits Constituent Benzene Toluene Chlorobenzene Spike Added lyg/L)15 15 15 Matrix Spike Duplicate Concentration (yg/L)12.4 1 2.0 12.6 Recovery 83 80 84 RPD RPD 20 20 20 Recovery 39-150 46-148 55-135 LOCKHEED ANALYTICAL SERVICES 12 LCS DATA SUNIMARY FOR VOLATILE ORGANIC ANALYSIS USING EPA METHOD 8010 Client Sample ID: LCS Analytical Batch¹: 122093-801020-0-3 QC Batch ID: 122093-801020-0-3 LAL Sample ID: AD5177 Date Analyzed: 04-JAN-94 Constituent 1,1-Dichloroethene Trichloroethene Chio robenzene Spike Added (yg/L)15 15 15 Blank Concentration I/Ig/L)ND ND ND LCS Concentration Iyg/L)9.1 1 5.0 1 2.2 Recovery 100 81 QC Limits Recovery 28-167 35-146 38-1 50 LOCKHEEO AIVAL V7'ICAL SERVICES LCS DATA SUIVIMARY FOR VOLATILE ORGANIC ANALYSIS USING EPA METHOD 8020 Client Sample ID: LCS Analytical Batch//: 122093-801020-0-3 QC Batch ID: 122093-801020-0-3 LAL Sample ID: AD5177 Date Analyzed: 04-JAN-93 Constituent Benzene Toluene Chlorobenzene Spike Added Ipg/L)15 15 15 Blank Concentration (yg/L)ND ND ND LCS Concentration (/Ig/L)14.9 14.1 14.4 Recovery 99 94 96 QC Limits Recovery 39-150 46-148 55-135 LOCKHEED ANALyTICAL SERVICES

VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 1 of 2 li n am I ID: BLANK Date Collected: N A Matrix: WATER Anl i IB h¹: 11 4-2-F2 QC Batch ID: 011094-8260-F2 LAL m le ID: AD 214 Date Received: N/A Date Anal zed: 11-JAN-94 Dil inF r: 1 SURROGATE RECOVERY 1 2-Di hl r h n-4 Tlen-8 4-Bromofluorobenzene 1 2 94 QC Limits 7-114 86-115 Constituent Chloromethane Vin I hl ri Bromom h n Chloroethane Trichlorofluoro methane A n 11-Dihl r hn Carbon Disulfide Meth lene Chloride ran-1 2-Di hl ro h n Vin I A 1 1-Dichloroethane 2-Butanone i-12-Di hl r h n hl r f rm 1 1 1-Trichloroethane Carbon Tetrachloride 12Dihi r hn Benz ne Trichloroethene TCE 1 2-Dichioro ro ane Brom i hl rom h n 2Chl r h IVin I h r 4-Meth 1-2-entanone cis-1 3-Dichloro ro ene Tol n rn-1-Dihlr r n 2-Hexanone 1 1 2-Trichloroethane Tetrachloroethene PCE Concentration /L<5<5<5<5<5<5<10<5<5<5<5<2<10<5<10<5<5 Reporting Detection Limit/L 10 10 10 Data Qualifier s LOCKHEED ANAL YTICAL SERVICES Cq g VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 2 of 2 Client Sam le ID: BLANK LAL Sam le ID: AD5214 Constituent Dibromochloromethane hl r nzen Ehl nzn m-X lene o-X lene r n Br m f rm 1 1 2 2-Tetrachloroethane 1 3-Dichlorobenzene 1 4-Di hl r nz n 1 2-Dichlorobenzene Concentration IL<5<5<5<5<5 Reporting Detection Limit IL Data Qualifier s LOCKHEED AIVALYTICAL SERVICES VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 TENTATIVELY IDENTIFIED COMPOUNDS Client Sample ID: BLANK Date Received: N/A Matrix: WATER Analytical Batch: 011094-8260-F2 LAL Sample ID: AD5412 Date Analyzed: 11-JAN-94 Dilution Factor: 1 QC Batch ID: 011094-8260-F2 NONE Tentatively Identified Compound Estimated Concentration (yg/L)(10 Retention Time (minutes)0.00 Data Qualifierls) LOCKHEED ANAL YTICAL SERVICES r.6 WATER MATRIX SPIKE DATA

SUMMARY

FOR VOLATILE ORGANIC ANALYSIS USING EPA METHOD 8260 Client Sample ID: MATRIX SPIKE/DUPLICATE Analytical Batch: 011294-8260-F2 QC Batch ID: 011294-8260-F2 LAL Sample ID: L968-27MS/MSD Date Analyzed: 124AN-94 Constituent 1,1-Dichloroethene Benzene Trichloroethene Toluene Chlorobenzene Spike Added (yg/L)50 50 50 50 50 Sample Concentration (yg/L)1.2 1.4 1.2 1.7 Matrix Spike Concentration (yg/L)51 52 52 54 Recovery 99 99 102 101 106 QC Limits Recovery 62-1 24 67-1 27 60-1 20 72-132 68-128 Constituent 1,1-Dichloroethene Benzene Trichloroethene Toluene Chlorobenzene Spike Added.(yg/L)50 50 50 50 50 Matrix Spike Duplicate Concentration (yg/L)49 50 51 53 Recovery 96 99 98 99 104 RPD RPD 14 14 13 13 QC Limits Recovery 62-124 67-1 27 60-120 72-132 68-128 LOCKHEED ANAL YTICAL SERVICES 2( WATER LCS DATA

SUMMARY

FOR VOLATILE ORGANIC ANALYSIS USING EPA METHOD 8260 Client Sample ID: LCS Analytical Batch: 011094-8260-F2 QC Batch ID: 011094-8260-F2 LAL Sample ID: AD5213 Date Analyzed: 11-JAN-94 Constituent 1,1-Dichloroethene Benzene Trichloroethene Toluene Chio rob enzene LCS Recovery 100 108 110 117 QC Limits Recovery 62-124 67-127 60-120 72-132 68-128 LOCKHEED AIVAL YTICAL SERVICES

SEIVllVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Clien am I ID: BLANK Date Collected: N/A Matrix: WATER Anl i IB h¹: 111 4-27-B QC Batch ID: 8270-SEMIVOLATILES-3964 LAL Sam Ie ID: 9 4MB Date Received: N/A Dilution Factor: 1 D Exr: 4-AN-4 Date Anal zed: 11-JAN-94 P 1 f2 URR GATE RECOVERY I 2-Fluoro henol Phenol-d, Nitrobenzene-d, 2-Fluorobi hen I 246-Tribr m h n I p-Terphenyl-d 43 27 66 64 86 C Limi 21-100 10-94 35-114 43-116 1-12 33-141 C ns i en Phenol bis 2-Chloroeth I ether 2-hir hnl 1-Dihl r nz n 1 4-Dichlorobenzene Benz I alcohol 12-Di hl r nz n 2M h I h n I bis 2-Chioroiso ro I ether 4-Meth I henol N-Ni r-Di-n-r I min Hx hlr hn Nitrobenzene Iso horone 2-Ni r h n I 2 4-Dim h I hen I Benzoic acid bis 2-Chloroethox methane 2 4-Dichl r h n I'1 2 4-Tri hl r nz n Na hthalene 4-Chloroaniline Hex hl r inc 4-hl r--m h I hn I 2-Meth Ina hthalene Hexachloroc clo entadiene Concentration /L<10<10<10<10<10<10<10<10<10<50<10<10<10<10<10<10<10 Reporting Detection Limit/L 10 10 10 10 10 10 10 10 50 10 10 10 10 10 10 Da a ualifier LOCKHEED AIVAL YTICAL SERVICES p, t SEIVIIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Client Sam le ID: BLANK LAL Sam fe ID: 3964MB P 2 f2 Constituent 24-Trihl r hn I 24-Trihl r hn I 2-Chlorona hthalene 2-Nitroaniline Dim h I hh I A n hhln 2 6-Dinitrotoluene 3-Nitroaniline A n hhn 2 4-Dini r h n I 4-Nitro henol Dibenzofuran 2 4Dini r I n Di h I hh I e 4-Chloro hen I-hen lether Fluo rene 4-Ni r nilin 4-Dinir-2-m h I h n I N-Nitrosodi hen lamine 4-Bromo hen I-hen lether Hx hlr nzn Pn hlr hnl Phenanthrene Anthracene Di-n-u I hh I Fl rnhn P rene But Ibenz I hthalate'-Di hl r nzi in 8 nz n hr n Chr sene bis 2-E h Ihex I h halate Di-n-I hh I Bnz fl rnhn Benzo k fluoranthene Benzo a rene In n 12-rn Di nz h n hr n Benzo h i er lene Carbazole Concentration I IL)<10<25<10<10<25<2<25<10<10<10'2<2<10<10<10<10<10<10<2<10 1.3<10<10<10<10 Reporting Detection Limit (IL)10 25 10 25 25 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 Data Qualifierls) LOCKHEED ANALYTICAL SERVICES

VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8270 TENTATIVELY IDENTIFIED COMPOUNDS Client Sample ID: BLANK Date Received: N/A Matrix: WATER Analytical Batch: 011194-8270-B LAL Sample ID: 3964MB Date Analyzed: 11-JAN-94 Dilution Factor: 1 QC Batch ID: 8270-SEMIVOLATILES-3964 None Tentatively Identified Compound Estimated Concentration iyg/LI Retention Time lminutesl Data Qualifier(s) LOCKHEED ANALYTICAL SERVICES SEIVIIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 P 1 f2 lin mi ID: L Date Collected: N/A Matrix: WATER Anal i alB h¹: 111 4-27-B QC Batch ID: 8270-SEMIVOLATILES-3964 LAL m I ID: 4 Date Received: N/A Dilution Factor: 1 D Ex ra: 04-AN-4 Date Anal zed: 11-JAN-94 2-Fluoro henol Phenol-d, Nitro benzene-d, 2-Fluorobi hen I RR ATE RECOVERY 37 26 60 60 Limi 21-100 10-94 35-114 43-1 1 6 246-Tri rom h n I p-Terphenyl-d 80 33-141 Phenol n i n Concentration L 40 Reporting Detection Limit/L 10 D bis 2-Chloroeth I ether 2-hlr hnl 1-Di hl r nz n 1 4-Dichlorobenzene Benz I alcohol 12-Dihl r nz n 2-M hlhnl bis 2-Chloroiso ro I ether 4-Meth I henol N-Ni r-Di-n-r I min Hx hlr hn Nitro benzene Iso horone 2-Ni r hen I 2 4-Dime h I h nol Benzoic acid bis 2-Chloroethox methane 4-Dihl r hn I 1 2 4-Tri hl r nz n Na h halene 4-Chloroaniline Hx hlr in 4-hlr--m hlhnl 2-Me h Ina hthalene Hexachloroc clo entadiene<10 39<10<10<10<10<10<50<10<10<10 100<10<10 10 10 10 10 10 10 10 10 10 10 50 10 10 10 10 10 LOCKHEED ANALy'TICAL SERVICES SEMIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Client Sam le ID: LCS LAL Sam le ID: 3964LCS Pa 2 f2 Constituent 24-Trihl r hn I 24-Trihl r h n I 2-Chlorona hthalene 2-Nitroaniline Dim h I hh I A n hhln 2 6-Dinitrotoluene 3-Nitroaniline A n hhn 2 4-Dini r h n I 4-Nitro henol Dibenzofuran 2 4-Dini r I n Di h I hh I 4-Chloro hen I-hen lether Fluorene 4-Ni r nilin 4-Dinir-2-m h I h n I N-Nitrosodi hen lamine 4-Bromo hen I-hen lether Hx hlr n n P n hlor hn I Phenanthrene Anthracene Di-n-I h h I Fluor n h n P rene But Ibenz I hthalate'-Di hi r nzi in B nz n hr n Chr sene bis 2-Eth Ihex I hthalate Di n-I h h I 8 nzo b fluoran hen Benzo k fluoranthene Benzo a rene In n 12-rn Dib nz h an hrac n Benzo h i er lene Carbazole Concentration IL)<10<10<25<10<25<2 22<10<10<10<2-<2<10<10 17<10<10 100<10<2<10<10<10<10<10<10<10<10 Reporting Detection Limit I IL)10 25 10 25 10 25 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 Data Qualifier(s) LOCKHEED ANALYTICAL SERVICES SEIVIIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Pa e1 f2 lin m I ID: Date Collected: N A D P LA ml ID: 4 D P Date Received: N/A Matrix: WATER An I i IB h¹: 111 4-27-B QC Batch ID: 8270-SEMIVOLATILES-3964 Dilution Factor: 1 Da Exr ed: 4-AN-4 Date Anal zed: 11-JAN-94 2-Fluoro henol Phenol-de Nitrobenzene-d, RRO ATE REC VERY 31 24 62 Limi 21-100 10-94 35-114 2-Fluorobi hen I 24-Tri r m h n I p-Terphenyl-d,4 62 85 43-116 1-12 33-141 Phenol n i n Concentration L 39 Reporting Detection Limit L 10 D bis 2-Chloroe h I ether 2-hl r hen I 1-Dihl r nz n 1 4-Dichlorobenzene Benz I alcohol 12-Di hl r nz n 2-M h I hn I bis 2-Chloroiso ro I ether 4-Meth I henol N-Ni r-Di-n-r I min Hx hlr hn Nitrobenzene Iso horone 2-Nir h n I 2 4-Dim h I h n I Benzoic acid bis 2-Chloroethox methane 24Dihl r hn I*1 2 4-Tri hl r nz n Na hthalene 4-Chloroaniline Hx hlr in 4-hlr--m hlhnl 2-Meth Ina hthalene Hexachloroc clo entadiene<10 41<10<10<10 74<10<10<10<50<10<10<10<10<10 10 10 10 10 10 10 10 50 10 10 10~10 10 LOCKHEED ANALYTICAL SERV/CES SEIVlIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Client Sam Ie ID: LCS DUP LAL Sam le ID: 3964LCS DUP P 2 f2 Constituent 24-Trihl r h n I 24-Trihl r h n I 2-Chlorona hthalene 2-Nitroaniline Dim hlhhla A n hhln 2 6-Dinitrotoluene 3-Nitroaniline A en hhn 24-Dinir h n I 4-Nitro henol Dibenzofuran 2 4-Dini r ol n Di h I hh I 4-Chloro hen I-hen lether Flu orene 4-Ni r nilin 4-Dinir-2-meh I h n I N-Nitrosodi hen lamine 4-Bromo hen I-hen lether Hx hlr nzn Pn hl r hnol Phenanthrene Anthracene Di-n-I hh I Fl ran h n P rene But Ibenz I hthalate'-Dihl r ni in B nz n hr n Chr sene bis 2-fth Ihex I hthalate Di-n-I hh I 8 nz fl r nh n Benzo k fluoranthene Benzo a rene In n 1-rn Di nz h n hra n Benzo h i er lene Concentration IL)<10<25<10<10<25<2 35<10<10<10.<2<2<10<10<10<10 100<10<10<10<10<10<10<10 Reporting Detection Limit I IL)10 10 25 25 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 Data Qualifierls) LOCKHEED ANALYTICAL SERVICES

SEMIVOLATILE ORGANICS QUALITY CONTROL DATA

SUMMARY

FOR METHOD 8270 Client Sample ID: LCS Analytical Batch¹: 011194-8270-B QC Batch ID: 8270-SENIIVOLATILES-3964 LAL Sample ID: 3964LCS/LCS DUP Date Analyzed: 11-JAN-94'C Limits Phenol Compound Spike%Recovery 27 Spike Duplicate%Recovery 26 RPD Recovery 5-112 RPD 42 2-Chlorophenol 1,4-Dichlorobenzene N-Nitroso-di-n-propylamine 1,2,4-Trichlorobenzene 4-Chloro-3-methylphenol Acenaphthene 4-Nitrophenol 2,4-Dinitrotoluene Pentachlorophenol Pyrene 57 39 78 45 68 68 81 101 53 41 74 52 66 69 23 79 121 101 14 42 23-134 20-124 D-230 44-142 22-147 47-145 D-132 39-139 14-1 76 52-115 40 28 38 28 42 31 5038 50 31 LOCKHEED ANALYTICAL SERVICES" PESTICIDE ANALYSES RESULTS BY GC/ECD USING METHOD 8080 FOR COOK NUCLEAR PLANT Clien Sam le ID: METHOD BLANK D Collec ed: NA Date Extracted: 04-JAN-94 Matrix: WATER Anal tical Batch¹: 012094-8080-A-1 LAL Sam ie ID: 3965MB Da e Re eiv: NA Date Anal zed: 21-JAN-94 Dilution Factor: 1 QC Grou ID: 8080 PEST/PCBS 3965 SURROGATE RECOVERY 0 QC Limits TCMX DCB 46" 23 60-150 60-1 50 A-BHC B-BHC Constituent Concentration /L<0.05 Reporting Detection Limit/L 0.05 Data Qualifier(s) G-BHC D-BHC HEPTACHLOR ALDRIN HEPTA HL R EPOXIDE G-CHLORDANE ENDOSULFAN I A-CHLORDANE 4 4'-DDE 4 4'-DDT DIELDRIN ENDRIN ENDOSULFAN II 4 4'-DDD ENDRIN ALDEHYDE ENDOSULFAN SULFATE METHOXYCHLOR TOXAPHENE PCB-1016 PCB-1221 PCB-1232 PCB-1242 PCB-1248 PCB-12 4 PCB-1260 TECHNICAL CHLORDANE MIREX TCMX-tetra-chloro-meta-xylene DCB-Deca-chioro-biphenyl <0.05<0.05<0.<0.<0.05<0.05<0.<0.1<0.1<0.1<0.1<0.1<0.1<0.1<0.<5<2<0.1 0.05 0.05 0.05 0.05 0.1 0.1 0.1 0.1<0.1 LOCKHEED ANALYTICAL SERVICES PESTICIDE ANALYSES RESULTS BY GC/ECD USING METHOD 8080 FOR COOK NUCLEAR PLANT Clien Sam le ID:LAB CONTROL SAMPLE Da Clle d NA Date Extracted: 04-JAN-94 Matrix: WATER Anal tical Batch¹: 012094-8080-A-1 LAL Sam le ID: 3965 LCS D e Rec ive: NA Date Anal zed: 21-JAN-94 Dilution Factor: 1 QC Grou ID: 8080 PEST/PCBS 3965 SURROGATE RECOVERY oo TCMX DCB 60 29 QC Limits 60-1 50 60-150 A-BHC B-BHC G-BHC D-BHC Constituent Concentration IL<0.05 0.88<0.05 Reporting Detection Limit IL 0.05 0.0 0.05 Data Qualifier(s) HEPTACHLOR ALDRIN HEPTACHLOR EPOXIDE G-CHLORDANE ENDOSULFAN I A-CHLORDANE 4 4'-DDE 4 4'-DDT DIELDRIN ENDRIN ENDOSULFAN II 4 4'-DDD ENDRIN ALDEHYDE END ULFAN S LFATE METHOXYCHLOR TOXAPHENE PCB-101 6 PCB-1221 PCB-12 2 PCB-1242 PCB-1248 PCB-12 4 PCB-12 TECHNICAL CHLORDANE MIREX TCMX-tetra-chloro-meta-xylene DCB-Deca-chloro-biphenyl 0.70<0.05<0.05<0.05<0.<0.1 1.85 1.81 1.91<0.1<0.1<0.1<5<2<0.1 0.05 0.05 0.05 0.1 0.1 0.1 0.1 0.1 0.1 0.1<0.1 LOCKHEED AIVALYTICAL SERVICES er 1 PESTICIDE ANALYSES RESULTS BY GC/ECD USING METHOD 8080 FOR COOK NUCLEAR PLANT Clien Sam le ID: LAB CONTROL SAMPLE DUP D Collec ed: NA Date Extracted: 04-JAN-94 Matrix: WATER Anal tical Batch¹: 012094-8080-A-1 LAL Sam Ie ID: 3965 LCSD D eR eive: NA Date Anal zed: 21-JAN-94 Dilution Factor: 1 QC Grou ID: 8080 PEST/PCBS 3965 SURROGATE RECOVERY o TCIVIX DCB 54" 20 QC Limits 60-150 60-150 A-BHC B-BH G-BHC D-BHC Constituent Concentration /L<0.05.0<0.05 Reporting Detection Limit/L 0.05 0.0.05 Data Qualifier(s) HEPTACHLOR ALDRIN HEPTACHLOR EPOXIDE G-CHLORDANE ENDOSULFAN I A-CHL RDANE 4 4'-DDE 4 4'-DDT DIELDRIN ENDRIN ENDOSULFAN II 4 4'-DDD ENDRIN ALDEHYDE ENDOSULFAN SULFATE METHOXYCHLOR TOXAPHENE PCB-1016 PCB-1221 PCB-1232 PCB-1242 PCB-1248 PCB-12 4 PCB-12 0 TECHNICAL CHLORDANE MIREX TCMX-tetra-chloro-meta-xylene DCB-Deca-chloro-biphenyl 0.66.5<0.05<0.05 5<0.1 1.80 1.85 1.94<0.1<0.1<0.5<5<2<0.1 0.05 0.05 0.05 0.05 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.5<0.1 LOCKHEED ANALYTICAL SERVICES PESTICIDES QUALITY CONTROL DATA

SUMMARY

FOR METHOD 8080 Client Sample ID: LAB CONTROL SAMPLE Analytical Batch 4': 012094-8080-C-1 QC Batch ID: 8080 PES/PCBS 3965 LAL Sample ID: 3965 LCS Date Analyzed: 21 VAN-94 Matrix: WATER SURROGATE RECOVERY (%)TCMX DCB 60 29" QC Limits 60-1 50 60-1 50 Constituent G-BHC (Lindane)Heptachlor Aldrin 4,4'-DDT Dieldrin Endrin Spike Added (yg/L)LCS Concentration (yg/L)0.88 0.70 0.60 1.85 1.81 Recovery 88 70 60 92 90 96 QC Limits Recovery 56-1 23 40-131 40-120 38-1 27 52-1 26 56-121 LOCKHEED ANALYTICAL SERVICES 58 PESTICIDES QUALITY CONTROL DATA

SUMMARY

FOR METHOD 8080 Client Sample ID: LAB CONTROL SAMPLE Analytical Batch¹: 012094-8080-C-1 QC Batch ID: 8080 PEST/PCBS 3965 LAL Sample ID: 3965 LCS/LCSD Date Analyzed: 21-JAN-94 Constituent G-BHC (Lindane)Heptachlor Aldrin 4,4'-DDT Dieldrin Spike Added (yg/L)Sample Concentration (yg/L)Matrix Spike Concentration (yg/L)0.88 0.70 0.60 1.85 1.81 1.91 Recovery 88'70 60 92 90 96 QC Limits Recovery 32-1 27 34-111 42-122 25-1 60 36-146 30-147 Constituent G-BHC (Lindane)Heptachlor Aldrin 4,4'-DDT Dieldrin Endrin Spike Added (yg/L)Matrix Spike Duplicate Concentration (yg/L)0.88 0.66 0.55 1.8 1.85 1.94 Recovery 88 66 55 90 93 97 RPD RPD 15 20 22 27 18 21 QC Limits Recovery 32-127 34-1 1 1 42-1 22 25-160 36-146 30-147 LOCKHEED AIVAL YTICAL SERVICES 58 0 METALS QC DATA

SUMMARY

'LAL Batch ID(s):.1220.:im QC Sam le Anal ses'.,'onstituent .Aluminum Antimon Arsenic Barium Be Ilium Boron Cadmium Chromium Cobalt Co er Iron Lead Ma nesium Man anese Mercu Mol bdenum Nickel Selenium Silver Sodium Thallium Tln Titanium Vanadium Zinc Client"Sample'ID TRS TRS TRS TRS TRS TRS TRS TRS TRS TRS TRS TRS TRS TRS TRS-QA TRS TRS TRS TRS TRS TRS TRS TRS TRS TRS LAL Sample , ID;L1009-13 L1 009-13 L1 009-13 L1009-13 L1009-13 L1009-13 L1009-13 L1009-13 L1009-13 L1009-13 L1009-13 L1009-13 L1009-13 L1009-13 L1009-14 L1009-13 L1 009-13 L1009-13 L1 009-13 L1009-13 L1 009-13 L1 009-13 L1 009-13 L1009-13 L1009-13 Date A'nalyxed 01-20-94 01-27-94 01-27-94 01-27-94 01-27-94 01-20-94 01-27-94 01-27-94 01-27-94 01-27-94 01-20-94 01-27-94 01-20-94 01-27-94 01-07-94 01-27-94 01-27-94 01-27-94 01-27-94 01-20-94 01-27-94 01-27-94 01-20-94 01-20-94 01-27-94 Reagent Blank (m IL)<0.20<0.060<0.010<0.20<0.005<0.20<0.005<0.010<0.050<0.025<0.10<0.003<5.0<0.015<0.0002<0.20<0.040<0.005<0.010<5.0<0.010<0.20<0.20<0.050<0.020 Duplicate P,.recision (%RPD)Matrix Spike-Recovery"(%)104 104 110 74 97 88 100 98 96 97 101 84 102 98 106 106 94 137 98 103 104 NA 107 94~Ibw~NA The RPD cannot be computed, because the sample or the duplicate concentration was below the Reporting Detection Limit.The matrix spike recovery is not reported.The sample concentration was greater than four times the spiking level.Titanium is not included in the spiking solution.LOCKHEED ANAL YTICAL SERVICES l'0~~RRRRHIRRH~l I yPJ..~~~ >i I iA iA.I I'j")A)f)t, e l'<,'I l"I.IA)bP..<I I AI<<.'.P;Ah:A l: I)l I l<I')tlat I'AQ<)I')I, I, I.I I:>'p I I'I'i<): Ii;I')A)'J'li)(I('I'I'i):i'!('(i I')ll(',~(I, Aii'>I;<il'I t<<,I ii I<r<<)I,<((<'I<!I)i", I, i, I.<i<'I i)<(.":I)'(" ll(i I'IV(f:<(i(~',.IA('("I.)< I I<('.VIAIA~I)'Q V l~l I II I.()V.V V X ()I (')'I:<'(Ji'A)I'":I.d ~))'.I 1I i(<)<(l.'I.I'l)I'I~)I', (<')I lllil Ii%:IIV:i),l P (.(i)I.(~(< 0 ~'0'<v<.5,).imp 3)j'I'!I"j)j-l'/s X I--I,'//J.".I.'4 J.X>'" l'-I li')J.-.L u"'5'I;I;/ljA-J.uu J.-l:ju xh-J.uu X 5-:-l:5:ji'I I.:I'Ii')J.u/I l: j.">x)>"Iub Xj'-I.:J:)i)l'i-l ub I'-l:5'/I'u-J.3u XI--I:5:5 JJA-iud l'h-l:5 J JJA l 40'-l/I<)J.4 L l'I I.I'h-IRAN N 0-l'I'/hlJ-J.5'/)=I)'-I.:)il HC-Jul W-I.'5'/HLi-"Vu KA-..b'J:H-'2:jr U-'/uu gp At1-"/I 5, I<i, Il)>'I i'I I (>!il I(il>)I'IP (I'.<<J)<>0:l~'/I,/I',!'/.I')i'<)r'5/I;,I(i/,'I II, l f>.'5~'J:I (>>(>>/(>>>)i~ReIJ w lf>i'l',i(>>..0 J)2'J~I5'j HJ..()0 rl:5 5'Nd~(>>0/!'/0 l,'//I;I u/)'/();I li">0/I I'.I/I 4 J/>))'r'<>'.)f>J 0/;I:..0/b<>I., I>.')I:(>>J (>>'...I",>\4:).u:p l)"J<>J)0.',<;/l'I>.'I'I w~l, I r j4I/5 JI.(I, l".'/I, I.)<>:5').'5 I,-;/'/>)<>'/'.I.7<)(>>0':);<J')lJ:5.le(l;IJ;!0 I.<)<>.I,:5 g I J<1 IIA (I>I 1/II),)l~I'.)l;.h-vu I~/:"i'J)'Vu l/'/<)lh-Ou I-vu<>I'Jl)h-0'/ 5-0(>>/;J-0'/l'Jr<4".>h-Ou J" (J::::I:-0 u'-: 5'I'/:Sh-Vu '>I"'llew J:" Ou l~2'I'/f>h-0'/ 5 I"l(l I vu')~'/i!.p'/h-Q/("':>J'/):- 0/l~5'/I I'0'/I'/"III I,'-vu ('ilpuh-vb J.'/I:(>>/I I-.Ou l.'5'/<)iI I."-vu J~".();'5;-Ob l e'/<>0',/I-0~J v J',>',>l<J: ~~0(>l-:5'I l lI-:-Ou')'I JJ 5'-Vu l.I>:5:8;.'h-Vu 0//~(>>5~-vb I.(:5>n):-ou J-vb/)/,'5-0/'I-<>42'/h-ou w'<>>I I 0 J>)5'u'I-:5."))5'/h-Vu I-(:/"'.)5-Ou<>~(')0/Ih-Vu 5-'/QI'5:,--Qu r(I.Luh-Ou'<~">'/'.)J):.-Ou'I-'Jbo<)h-Ou"">I"p'/5:-vu).):l>Uh-Ou I<~/I,'>;I I J-Qu 11 I I)),AII>hl Ilk'e>~e~e,,'e I c r>r', e Wl'l,P le(l>(re peal))e)I e I IJ)5'e(}()/e)(I r)>crt>I>.'e"<: et y I~<~e I SQP>>e'>e,l I epe}I e tee(}e~>J>>el I eel-'I HA-;!>>!HA-"<<I L;I..-:I'I r,-tv A t(-'I I.~5\'-<<Ib L'K-)\(1H'-b<<t l1H'-:)I>I"I.I-V'/L'lJ-:)il k>h-')~3 L'.l-8 0 t'I I-b 4 H l-b:)ZH-ba'/.H-b")i'I 8 h'-'/5 AU-'/r>IJH-8'<<IJK->>5<<t l(K-Uv V)K-'I:)i'I>>-Ub i(->>I')i1 R K-8'/)i A'-~led KCJ-88 X-I'58 R t5-8")l1I.J-')0 UH-Dl X-"J" X-')I H8-'J<<t H I5-"):)ZK-i)b H LC-~)'/'/.H-'2'/l1I I-')')'I: L'-'J iJ (1 KU-(0:1 HH-l 0+KI.J-l 0')HU-I.vb L;I)-l 0')Ab-l I vl1 UH-I.\:I JJC Il.';3 I>e',I.'>>I r)I J t'.~e 0'<<0'I'/~:50')~'/t'.'/.<<I~~Te e~p I.'/.'<<0 JV.ly<<!0..4:J.'<<0 J:)'/.J.l~'<<>>P<<ll>., 5 P;I<<!'/.)'<<ep'/./.l:I, e>e (>>"i'), l<<I~l)I)r l).J'eiIi (" I" I)>(ez~s'Lg)<<e'/'/p C i'.I l'!'/>>t.)>>I J"'bt: J<<,'(eV t'J\'<<!"):I'r)<<t I I,V',>J:5)!0., 0~I'I'll).'/:))'!'!~0(>>'5 I.O~'/I)J 0'I'I l I I<<'t')I;cr,;,Pl)V I.'t:5 (.CI>>t I J)e),;>'<<!'t 5'I'!('<<)~(>>l):))').lv~~e~be e'<<e!I'I l.')0'>J'.'I'I l:)l,\!J;)J;I P'.I'.)I)')<<I V<<!P', i t,r l)r>.5.!I t"Ib~0)l!J:lr>.0 l 5 0" 5.t'tl".:)'/.".5>>t )0<<.'r.;:0:)')'/.:)'/!I;"Cr>>,<<;(,<<!I)I>.')0'/V<<!.(;i;I/I>')./')'/:i(>>.'/>>'>:)'/.")0 l'CO~:)l.I<<)0,"))'I')'/.0CI;I J CCVV'/<<l't:)0 (>>;<<J Pt:<<;el~I, ():I (>>'</>')e>(>>e'I, l I I I II A (>II.X/f1L }V/l~')'J5l>h-08',etlr, C,'I 08')..'/>>ll)>0 I-0'/I'I~e I e I e'e'le 0/l,/:)r,)I;-0/J.t lr'i<<!I:" 08\~\)0'/I-0'/I~e~"lb'/I'0 8 t..:5 500h-0'/I>'I 5 Vl-'08 I..<<I:<<50ÃI-08',!,'/I e'l',il" VU\.:500")I;-08 ('e"(>>',<'/'/R-(}b I>.')>50>5h-0'/ i!p'/<<"./'e)J:-eV8 >>!~l8'/')h-08 I;I>;I',(J-;" 08:I<<!/I.'/h-08<<!~5 0"I 5 I-08:.5.0:900h-Ob~.',Cr tlvl:-Vb')~I'J l I-08 l.ril>t:(>>I:-OL<

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V'/:I~0 5")\I'-0'/5.t"/(t'J 00 l.:5'5<<lr)I;-08'/.'.I'/tl'<<! J:," Vb't.0<<!'/'/I;-08 b~I b(>bl~-'08 7')8")I--0'/t';.!I"I J'"0'/'!.')l'/'/h-0'/ l~l>b<<CbJ:" 08 l'I't<<")I'-OU r."'t".<J" VU:5.>>I')l dh-0'/I'I'/t" I J'-OU l'!')b'I I.;-08~(/'.IJ:-08 l 0')ll'/h-OU '/,;e<<;bt:I:-08\.:I'!bith-0'/ 5,!I'I))I" 0'/')et')'9h-0'/ J, (>>r.,<<CI J:-08 l~:)'l';)'" OU:!~<<!(>>"e(>>I:-'08 .'i.Halliburton NUS+++C 0 R P 0 R AT I 0 N DUALITY CONTROL REPORT SUPPLEMENTAL INFORMATION NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 11, 1994 Report No.: 00018818 Section 8 Page 1------------ SAMPLE PREPARATION------------

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SAMPLE ANALYSIS-----------------.- TEST LR-LN CODE BATCH METHOD DATE/TIHE ANALYST LR-METNOD DATE/TIME ANLS ANALYST BATCH INSTRUMENI'AMPLE ID: SEWAGE PLANT NUS SAMPLE NO: P0258838 1 ASNW 23036 02-4'.3 03-JAH-94 0730 RAW 2 1050 23039 NA 3 I 610 23014 NA 4 I 490 23050 NA R2-200.7 07-JAN-94 808 JWC 03-507 03-JAN-93 700 DB 02-160.2 30.DEC-93 700 EDB 02-150.1 03-JAN-93 715 DB 0 3560 0 0 0 LR Method Literature Reference 02 EPA-Methods for Chemical Analysis of Water&Wastes, 1984.03 APNA-Standard Methods for the Examination of Water and Wastewater, 16th edition R2 Inductively Coupled Plasma-Atomic Emission Spectrometric Method for Trace Elemen SAMPLE ID: OIL/WATER SEPARATOR 1 G122W 22987 05-608 29-DEC-93 0800 PS 3 I106 23061 NA 4 I680 23097 NA 5 I490 23050 NA NUS SAMPLE NO: P0258839 22987 0 0 0 05-608 30.0EC-93 1146 JC 02-415.1 04-JAN-94 1000 JJH 02-413.1 03-JAN-93 1230 TM 02-150.1 03-JAN-93 715 DB LR Method Literature Reference 02 EPA-Methods for Chemical Analysis of Water 8 Wastes, 1984.05 EPA-40 CFR 136, October 26, 1984. 4'alliburton NUS++C 0 R P 0 R AT I 0 N OUALITY CONTROL REPORT SURROGATE STANDARD RECOVERY NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (4'12)747-2580 FAX: (412)747-2684 January 11, 1994 Report No.: 00018818 Section C Page 1 TEST SURROGATE LN CODE COMPOUND PERCENT RECOVERY ACCEPTANCE LIMITS REF LN SAMPLE ID: OIL/WATER SEPARATOR NUS SAMPLE NO: P0258S39 2 SPCBW PCB SURROGATE nonachtorobiphenyt

1'Halliburton NUS CORPORATION QUALITY CONTROL REPORT LABORATORY CONTROL SAMPLE RECOVERY NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 11, 1994 Report No.: 00018818 Section D Page 1 TEST CODE DETERMINATION PERCENT RECOVERY DUPLICATE RECOVERY RPD ACCEPTANCE LIMITS BATCH: 23036 SAMPLE ID: Lab Control Sample ASNN Tin, Total (Sn)BATCH: 23039 SAMPLE ID: Lab Control Sample 92'NUS SAMPLE NO: P0259637 NA NUS SAMPLE NO: P0259643 I050 BOO (02)-5 day BOD (02)-5 day¹2 BOD (02)-5 day¹3 BOO (02)-5 day¹4 101~7 94 99 104 NA NA NA NA BATCH: 23050 SAMPLE ID: Lab Control Sample HUS SAMPLE NO: P0259658 1490 pH pH¹2 pH¹3 100.5 100 99.1 NA NA NA BATCH: 23061 SAMPLE ID: Lab Control Sample HUS SAMPLE NO: P0259673 1106 Carbon, Organic-.Nonpurgeable Carbon, Organic-Nonpurgeable ¹2 Carbon, Organic-Honpurgeable ¹3 110 96.3 106 HA NA NA BATCH: 23097 SAMPLE ID: Lab Control Sample I680 Oil and Grease, Gravimetric 84.8 HUS SAMPLE NO: P0259728 83.8 1.19 .'i Halliburton NUS++++C 0 R P 0 R AT I 0 N QUALITY CONTROL REPORT METHOD BLANK DATA NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 11, 1994 Report No.: 00018818 Section E Page 1 TEST CODE Determination RESULT UNITS BATCH: 22987 SAMPLE ID: Method Blank NUS SAMPLE NO: P0259059 G122'N PCB ANALYSIS PCB-1016 PCB-1221 PCB-1232 PCB-1242 PCB-1248 PCB-1254 PCB-1260<0.50<0.50<0.50<0.50<0.50<1.0<1.0 ug/L ug/L ug/L ug/L ug/L ug/L ug/L BATCH: 23014 SAMPLE ID: Method Blank HUS SAMPLE HO: P0259602 I610 Solids, Suspended at 103C BATCH: 23036 SAMPLE ID: Method Btank<10 mg/L NUS SAMPLE NO: P0259638 ASNM Tin, Total (Sn)<0.1 mg/L BATCH: 23039 SAMPLE ID: Method Blank I050 BOD (02)-5 day BATCH: 23061 SAHPLE ID: Hethod Blank 0.63 mg/L NUS SAHPLE NO: P0259674 NUS SAHPLE NO: P0259644 1106 Carbon, Organic-Nonpurgeable <1 mg/L BATCH: 23097 SAMPLE ID: Method Blank HUS SAHPLE NO: P0259729 1680 Oil and Grease, Gravimetric <3 mg/L '.Halliburton NUS Iaar C 0 R P 0 R AT I 0 N QUALITY CONTROL REPORT DUPLICATE AND MATRIX SPIKE DATA NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (4'12)747-2580 FAX: (412)747-2684 January 11, 1994 Report No.: 00018818 Section F Page 1 PREP BATCH: 23050 HUS SAHPLE NO: P0258838 TEST DETERMINATION 1490 pH ORIGINAL DUPLICATE RESULT RESULT 6.8 6'7 RANGE/UNITS RPD~02 UNITS HS MS%RESULT RCVRY PREP BATCH: 23014 HUS SAHPLE HO: P0258810 TEST DETERMINATION 1610 Solids, Suspended at 103C ORIGINAL DUPLICATE RANGE/HS HS H RESULT RESULT UNITS RPD UHITS RESULT RCVRY 12 13 mg/L 1 mg/L PREP BATCH: 23036 NUS SAMPLE NO: P0259167 TEST DETERMINATION ASNlJ Tin, Total (Sn)ORIGINAL DUPLICATE RESULT RESULT 0.4 0.4 RANGE/UNITS RPO mg/L 1.98 UNITS mg/L RESULT 2.28 RCVRY 94.0 HS MS/.PREP BATCH: 23039 HUS SAMPLE NO: P0258780 TEST DETERHI NATION I050 BOD (02)-5 day ORIGINAL DUPLICATE RESULT RESULT 5 3.81 RANGE/UNITS RPD mg/L 1 UNITS mg/L HS MS yo RESULT RCVRY PREP BATCH: 23061 HUS SAMPLE NO: P0258851 TEST DETERHINAT I ON I106 Carbon, Organic-Nonpurgeable OR I G I MAL DUPLICATE RESULT RESULT 7 6.86 RANGE/UNITS RPD mg/L 3.82 UNITS mg/L HS HS K RESULT RCVRY 57.7 101 '.HallibuIIton NUS+++C 0 R P 0 R A T l 0 N I NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 11, 1994 Report No.: 00018818 Section H Page 1 QUALITY CONTROL REPORT MATRIX SPIKE AND MATRIX SPIKE DUPLICATE DATA ANLS BATCH: 22987 NUS SAMPLE NO: P0258792 TEST G122W PCB-1242 G122W PCB-1260 DETERMINATION MS RESULT 4'7 4.T5 MSD RESULT 4.55'.73 UNITS ug/L ug/L MS PCT MSD PCT RPD RECOVERY RECOVERY 0.4 91 91 0 95 95 0' NPDES STORM WATER DRAINAGE PERMIT APPLICATION D.C.COOK NUCLEAR PLANT ONE COOK PLACE BRIDGMAN, MI 49106 E LI I'ICCTC VI I~~~Vl IT Vr'"~(fill-in areas are spaced for elite rype, i.e., 12 charac rers/inch(.U.S, tHVIROHMCHTAI PIIOTCCTIOH AOBHCY riiniirlpplovro. ITITIII~Iv.rvrv'ITvrv rlpIVIITCI rrpllrr r VI mv GENERAL I.EPA I.D.NUMB R ill).FACILITY AME ACILITY'AILIN ADDRESS VI FACIL'ITY'OCATION GENERAL INFORMATION Consoli dered Pemli re Program ()lead lhe"General inllriieilons" before Irarrrne.l P EASE PL C LABEL IN THIS SPAC I.EPA I.D.NUMBER F IIID 098647621 P OCHBRAL INSTRUCTIONS It a prsprinted label hss been provided, affix lt in the designated space.Review the inform.~lion carefully; if sny of It Is incorrect. cross through it snd enter tha correct data In the appropriate fill-in sra below.Also, if sny of ths plePrintsd dsts is absent (dis sre~ro di~left of di~label space lisle di~information dist should sppasrl, please provide It In tha proper fill-in siss(s)below.If the label ls'compl~Ilt and correct, you need not complete Items I, III, V, shd Vl (ixcepr Vl B wfikh must be compleltd rsgerdless/. Complete sll Rems if no label hss been provided.Aeter to the Innrucllons tor detailed Item descrip-tions snd for the legal suthorisations under which this data ls collected. II.POLLUTANT CHARACTERISTICS INSTRUCTIONS: Complete A through J to determine whether you need ta submit any permit application forms to tha FPA.If yau answer"yes" to any questions, you must submit this form and tha supplemental form listed in the parenthesis fallowing the question, Mark"X" in the box in tha third columlt if the supplemental form is attached, If you answer"no" to each question, you need not submit any of these forms.You may answer"no" if your activity is excluded from permit requirements; see Section C of the instructions. Sea also, Section 0 of the Instluctions for definitions of bold-faced terms.SPKCIPIC DUCSTIOHS~OP TI apccl pic DUtsTIDNs ITVACIIC rory CD 0 ATTACIICO , Is I is s scililv which cunenl v resuls in Isc srgcs lo wslsrs of the U.S.olherahon Ihqts described in X A or Babove)2N Form 2b I I is a propos sciity o er sn ost ascn In A or B shovel which will result in~discharge lo wst~t ths U S 7 F RM 2 I A.Is this facility s publicly owned treatment works 8.Does or will this facility (either exist(np or proposcdl which resuIII in s discharge lo waters of ths U.S.)include s concentrated animal fadlhg operation or IFORM 2A)~qusslc animal production facility which results in a discharge lo wsssls of the U$2 IFOAM 28)~~I~~~X E.Does or will this facility tress, store, or dispose of hszsrI)ous wsnssf IFORM 3)o you or wi you ihlecl sl I is so ily shy pro uc water or other fluids which sra brought to the surface in connection with conventional oil or natural gss pro.duction, inject tluids used for enhanced recovery of oil or natural gss, or ihjeC!fluids for storage of liquid h drocsrbohst IFORM 4)~5 lllis sci ily~propose ssssiohsry source w>>s one of the 28 industrial categories listed in the in-structions snd which will potentially emit 100 tons psr year of any air pollutant regulated under the Clean Air Acl and Ihay SffeCt Or be located in sn snsihmcnt arcs)IFORM Sl III.NAME OF FACILITY 1 5<<P D.C, COOK NUCLEAR PLANT F.Do you or will you inject at this facility industrial or municipal effluent below tha.lowermost stratum con-X~taining, within one quarter mile of the well bort, underground sources ot drinking water?IFOA M 4)H, Do you or will you inject st this facility tluids for sps cisl processes such as mining ot sulfur by lhs Frasch process, solution mining of minerals, in situ combus.tlon of fossil fuel, or recovery ot geothermal ensrgyt IFORM 4)~I l is aci ity~prop nsiy source whic is NOT one ot tht 28 industrial categories lined in the Instructions and which will potentially emit 250 tons per year of any eir pollutant regulated under the Clean Air Act snd may affect or be located In an sttalnmeIIS ~Ies)IFORM 5)X X T~I~I~'l X IV.FACILITY CONTACT A, NAM t SI TITLC (loll, (lNI, Ia llllel C 2 BAKER D.L.Fnvironmental Affairs Director B, I'HDNC faTCC code k no.l 2 1 9 425 2118 V.FACILITY MAILING ADDRESS 3 P 0 BOX 60 A STRttT OR P.O BOX 4 FORT WAYNE~.CITY OR TOWN C,STATt D, ZIP CODC IN 4680 Vl.FACILITY LOCATION A STRtCTI ROUTC HO OR OTHCR SPtCIPIC IDtNTIPICR 5 ONE COOK" PLACE BERRIEN Bl COUNTY NAMt 6 BRIDGOIN C.CITY OR TOWN D STATt Cl ZIP CODS 416 EPA Form 3610.1 IRsv.104I0)CONTINUE ON REVEASE TIN ED FROM THE FR NT Vlf, SIC CODES (4<ipit.Jn order of pr(orlrvJ Ao Fltt5T 9 1 1"""fyJ STEAM ELECTRIC POriZR (speci fyI~, SCCONO C.'rNIItO (speci fy I 7~~~i~VIII.OPERATOR INFORMATION I C 8 NDIANA MICHIGAN PO R 0~I Ao NAMC (specify I O, FOURTH.Is tha name listed In Item VIII.A~la ths owners K3 YES C3 NO sa ,I~t~c STATU5 oF orcRAToR (Enter thc approprlatc lcncr Into thc anstrcr ooxtlf-Other", spcclfy.l o.r Notte (area code a no.l~a AL S~STATE P~PRIVATE ONE COOK PLACE U LI (other than fcdcral or state J (speci fy J 0~OTHER (IpeclfyJ P C, 5TRCCT 0tl F.OI SOX A 616 65 901~~I~I~~~~s BRIDGMAN I, CITY OR TOWN~e~I~I~'~I Is the facility located on Indian landst O YES CB NO aa X.EXISTING ENVIRONMENTAL PERMITS A.III ois (Discharges to Surface WaterJ ig N MI 0005827 5.UIC (underground In/cation of Fluldsl 9 U (H o.rso (A4 Emlsslons from proposed Sources J'r~9 P C.oTNcR (specify I (I fyJ Fir Permit'applicat;i n sa matte (speal fy J 9 R 9~~~4 11'I'I~I~~~~~~~~I~XI.MAP Attach to this application a topographic map of the area extending to at least one mile beyond property bounderies. The map must show the outline of the facility, the location of each of its existing and proposed intake and discharge structures, each of its hazardous waste treatment, storage, or disposal facilities, and each well where it injects fluids underground. Include ell springs, rivers and other surface water bodies in the map area.See instructions for precise requirements. XII.NATURE OF BUSINESS (provide~aria(description The Cook Nuclear Plant is a 2130 Mt4 steam electric generating station situated in 6*belt of sand dunes on the southeastern shore of Lake Michigan between Stevensville and Bridgman.Preparation of the site for construction of the plant began in 1968.Unit 1 was operat-tional in 1975 and Unit 2 in 1978.XIII.CERTIFICATION (seeinsuvcdonsl I certify under penalty of law that I have personally examined and am familiar wirh theinformatlon submitted in this application end all attachments and chat, based on my inquiry of those persons immediarely msponsible for obtaining the Information contained in the application, I believe that the information is true, accurate and complete.I am aware that them am significant penalties for submitting false information, including the possibility of fine andimprisonment. A M c Is o F F I c I A L T I T L c (type or prln I I R.C.Menge, President 9 SIGNATURC C, OAT COMMENTS FOR OFFICIAL USE ONLY C C EPA Form 3510.1{Rav.10 80)Reverse rr rrlartar attire I I9SS 'I Several of the sections in this permit application (Form 2F)are completed via the use of attachments. These sections reference the appropriate attachment. Please carefully read each section to avoid any confusion. Form Approved.OMB No.20404086 Approval expires 541.92 United tates Environmenta Protection Agency Washington, DC 20460 Appi!cat!on for Perm!t to D!schprge Storm Y/at~r Oischar es Associated with industrial Activi Form 2F I., k EPAID Number (copy from item iof Form i)Please print or type in the unshaded areas only HLD098647621 I.Outfaii LocatIon For each outlall list the latitude and lon itude of its location to the nearest 15 seconds and the name of the recolvin water.A Outfall Number ist~D.Receiving Water name B.Latitude C.Lon itude 1S 41 58 50 86 34 00 Lake Hichi'2S 41 58 45 86 34 00 Lake Mich 41'8 43 86 34 00 Lake Hichi an 41 58 43 86 34 00 Lake Hichi Paperworlr Reduction Act Notice , Public repoNnII burden for this ap'plication is estimated to average 28.6 hours per application, includ!ng time for reviewing instructions,-searching existing data sources, gathering and maintaining the data needed, and completing and reviewing the collection of information. Send comments regarding the burden estimate, any other aspect of this collection of information, or suggestions for Ihtproving this form, including suagostions which may Increase or reduce this burden to: Chief, Information Policy Branch, pM-223, U.S.Environmental Protection Agency, 401 M Bt., SW, Washington, DC 20460, or Director, Office of Information and Regulatory Affaire, Office of Management and Budget, Washington, DC 2C503 II.Im rovements A.Are you now required by any Federal, State, or local authority to meet any Implementation schedule for the construction, upgrading or operation of wastewater treatment equlpmont or practices or any other environmental programs which may atfect the discharges described in this application2 This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters, stipulations, court orders, ahd grant or loan conditions. N/A 1.Identification of Conditions, reements.Etc.number 2.Affected Outfalls source of dischar e 3.Brief Descri tion of Pro ect 4.Final Com liance Date b.ro.a.re.Continue on Page 2 Page 1 of 3 EPA Form 3510 2F (Rev.1.92)you may attach additional sheets describing any additional'water pollution (or other environmental projects which may affect your discharges) you now have under way or which you plan.Indicate whether each program is now under way or planned, and indicate your actual or planned schedules for construction Re fer to Attachment A.!I.Site DraIna e Ma""ach a site map showing topography (or indicating the outline of drainage areas served by the outfall(s) covered in the application if a gr~phiC map iS ui available) depiCting the faCility inCIuding: eaCh Of itS intake and diSCharge StruCtureS; the drainage area Of eaCh StOrm""'"'u"all: paved areas and buildings within the drainage area of each storm water outfall, each known past or present areas used for outdoor'oiago or<<<posal of significant materials, each existing structural control measure to reduce pollutants in storm water runoff, materials loading an<<c~ss areas.areas where pesticides, horbicides, soil conditioners and fertilizers are applied;each of its hazardous waste treatment,""-rags<<disposal uni:s (including each area not required to have a RCRA permit which is used for accumulating hazardous waste under 40<'" 26234): each weil where fluids from the facility are injectod underground; springe, and other surface water bodies which receive storm r.a!or",sc.'.a os ficm!" e facili Continued from the Front For each outfall, provide an estimate of the area (include units)of Impervious surfaces (Including paved areas arid building roofs)drained to the outfall, and an estimate of tho total surfaoe area drained bY the outfall.See At taChment: B Outfall Area of Impervious Surface Total Area Drained Area of knpelvlous Suflace Total Area Drained B.provide a narrative description of significant materials that are currentlyorin the past throe years have beerrtreatod, stored or dispcsed ln a manner to allow exposure to storm water;method of treatment, storage, or disposal;past and present materials management practices employed to minimize contact by these materials with storm water runoff;materials keding and aocesa areas;and the location, manner, and frequency in which pesticides, herbicides, soil conditioners, and fertilizers are applied.1.See Attachment B for significant materials See Att.achment B-1 for Herbicide Information See Attachment B-2 for other potential exposures to storlhwater C.For each outfall, provide the location and a description of existing structural and nonstructural control measures to reduce pollutants in storm water runoff;and a description of the treatment the storm water receives, Including the schedul~and type of maintenance for control Ust Codes from See Attachment' V.Nonstorrnwater Dlschar es A I cenify under penalty of law that the outfall(s) oovered by this application have been tested or evaluated for the presence of nonstormwater discharqes, and that all nonstormwater dischargee from these outfall(s) aro identified in oither an accompanying Form 2C or Form 2E i Name and Official Title (type or print)D.L.Baker i'.Affairs Director, Date Signed 3b-gg B.Provide a description of the method used, the date of any testing, and the onslto drainage points that were directly observed during a test.Samples procured and analyzed as per applicable guidelines. Outfall 003S sampled before and after mixing with groundwater. Vl.Sl nlficant Leaks orS ills Provide existing Information regarding the history of significant leaks or spills of toxic or hazardous pollutants at the facility in the last three years, Including the approximate date and location of the spill or leak, and the type and amount of material released.See Attachment C EPA Form 3510.2F (Aev.1-92)Page 2 of 3 Continue on Page 3 l er-'"Kx~&5%IS~ Continued from Page 2 EPA lD Number (copyfiom item iof Form 1)HID098647621 AB.G.4 D: see Instructions before proceeding. complete one set of lables for each outfall.Annotate the outlall number in the apace provided.Tables Vll.A.Vll-B, and V!LC are included on se arete sheets numbered Vll-1 and Vil 2.E.Potential discharges not covered by analysis~is any toxic pollutant listed in table 2F.2, 2F4 or 2F<, a substance or a componant ol a substance which you currently use or manufacture as an intermediate or final product or byproduct? Yes list ail such iiurants below No o to Section Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years?Yes istall such iiuranrs below No o fo Section N/A vrere any of the analysis reported in item Vll performed by a contract laboratory or consulting firm?X Yes (list the name, address, and telephone number of, and pollutants No (go to Section?r) A.Name B.Address C.Area Code if, Phone No.D.Pollutants Anal ed Lockheed Analytical Services 975 Kelly Johnson Dr.1(800)361-0220 Las Vegas, Nevada 89119-3705 W.W.Engineering tf Science Glenwood Hills Parkway 1(616)942-9600 P.O.Box 874 Grand Rapids, HI 49588-0874 Inorganic s Organics Radiochemistry BOD 5 (Biological Oxygen Demand)Surfactants I certify under penalty of law that this document and all attachments were prepared under my direction or supervr'sion in accordance with a'ystem designed to assure that qualified personnel properly gather and evaluate theinformation submitted. Based on myinquiry of the person or persons who manage the system or those persons directly responsible for gathering the informa;ion, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete.I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. A Name lf Otficial Title (~or pn'nr)R.C.Henge, President is+1~~r iver~Page 3 of 3 B.Area Code and Phone No.(219)425-2118 D.Date Signed s/su/qg 'EPA lD Number (copy from rrem I of Form t)tiMID 0 9 8 6 4 7 6 2 1 I Vll.Dischar e Information (Confrnued (rom a e 3 of Form 2F Form Approved.OMB No.20404 6)NI Part-You must provide th~results of at least one analysis lor every pollutant in this table.Compl~le one tabl~for each curtail.erne.instructions for additional details.Pollutant and CAS Number (if available) Grab Sample Taken Ouhng First 30 Minutes Flow-weighted Composite Maximum Values (include vnns)Grab Sampl~Taken During First 30 Minutes Row-weighted Composite Average Values (include units)Number of Storm Events Sampled Sources of Pollutants O'I and Grease BiOlOgiCal Oxygen Demand (8005)Chemical Oxygen Demand lCODl Total Suspended Sokds (TSS)Total Kjefdaht Nitro en Nitrat~plus I Nitrite Nitro en Total Phcschorus Minimum'.taxirr urn REFER TO ATTACHMENT D Minimum Maximum part 8-t.ist each pollutant that is umited in an etfluent guidekne wnicn the tacivty is suolect to or any poilutant listed in the tacuity s NFDEs permit for its'process wastewater lil the lacikty is operating under an existing NpDES permnl.Complete one table ior eacn outfait, h in I I i~Pollutant and CAS Number (if available) Grab Samole Taken During First 30 Minutes Row weighted Composite Maximum Values (include units)Grab Sampf~Taken Ounng First 30 Minutes Flow.weignted Composit~Average Values (include units)Number of Storm Events Sampled Sources of Ponutants REFER TO ATTACHMENT D EPA Form 3510-2F~~Page Va.l Continue on Reverse Continued from the Front Pert C-Ust each pollutant shown in Tables 2F-2, 2F4, and 2'hat you know or have reason to believe is present.See the instructions for additional details and requirements. Complete one table for each outfall..Pollutant and CAS Number fif available) Grab Sample Taken Dunng First 20 Minutes Flow~ighted Composite Maximum Values (incfude units)Grab Sample Ta'an During First 20 Minutes Row~fghted Composite Average Values ffncfude units)Number of Storm Events Sampled Sources of Pollutants REFER TO ATTACHMENT D Pert D-Provide data for the storm event s which resulted in the maximum values for the.ow wei hted corn site sam le.Date of Storm Event 2 Duration of Storm Event in minutes 3.Total rainfall during storm event in inches 4.Number of hours between beginning of storm meas-ured and end of previous measurable rain event 5.Maximum flow rate during rain event (gallons/minute or s ec units 6.Total flow from rain event allonsors ec'nits Dec.18 194 210 min.0.14 inches 280.5 hours (Refer to Attachm nt D for Storm Ev 2 liters/min. nt Description) 1,260 liters 210 min.x 1.5 I./min.x 4 outfalls=1260 liters 7.Provide a descri tion of the method of flow measurement or estimate.One liter container used in conjuction vith a stop vatch.EPA Form 3510-2F (Rev.1-P2)Page Vll.2 Instructions -Form 2F Application for Permit to Discharge Storm Water Associated with Industrial Activity Who Must File Form 2F Form 2F must be completed by operators of facilities which discharge storm water associated with industrial activity or by operators of storm water discharges that EPA is evaluating for designation as a significant contributor of pollutants to waters of the United States, or as contributing to a violation of a water quality standard.Operators of discharges v'hich are composed entirely of storm water must complete Form 2F (EPA Form 3510-2F)in conjunction with Form 1 (EPA Form 3510-1).Operators of discharges of storm water which are combined with process wastewater (process wastewater is water that comes into direct contact with or results from the production or use of any raw material, interme-diate product, finished product, byproduct, waste product, or wastewater) must complete and submit Form 2F, Form 1, and Form 2C (EPA Form 3510-2C).Operators of discharges of storm water which are combined with nonprocess wastewater (nonprocess wastewater includes noncontact cooling water and sanitary wastes which are not regulated by effluent guide-lines or a new source performance standard, except discharges by educational, medical, or commercial chemical laboratories) must complete Form 1~Form 2F, and Form 2E (EPA Form 3510.2E).Operators of new sources or new discharges of storm water associated with industrial activity which'will be combined with other nonstormwater new sources or new discharges must submit Form 1, Form 2F, and Form 2D (EPA Form 3510-2D).Where to File Applications The application forms should be sent to the EPA Regional Office which covers the State in which the facility is located.Form 2F must be used only when applying for permits in States where the NPDES permits program is administered by EPA.For facilities located in States which are approved to administer the NPDES permits program, the State'nvironmental agency should be contacted for proper permit application forms and instructions. Information on whether a particular program is administered by EPA or by a State agency can be obtained from your EPA Regional Office.Form 1~Table 1 of the"General Instructions" lists the addresses of EPA , Regional Offices and the States within the jurisdiction of each Office.Completeness Yotir application will not be considered complete unless you answer every question on this form and on Form 1.If an item does not apply to you, enter"NA (for not applicable) to show that you considered the question.Public Availability of Submitted Information You may not claim as confidential any information required by this form or Form 1~whether the information is reported on the forms or in an attachment. Section 402(j)of the Clean Water Act requires that all permit applications will be available to the public.This information will be made available to the public upon request.Any information you submit to EPA which goes beyond that required by this form, Form 1, or Form 2C you may claim as confidential, but claims for information which are effluent data will be denied.lf you do not assert a claim of confidentiality at the time of submitting the information, EPA may make the information public without further notice to you.Claims of confidentiality will be handled in accordance with EPA's business confidentiality regulations at 40 CFR Part 2.Definitions All significant terms used in these instructions and in the form are defined in the glossary found in the General Instructions which accompany Form 1.EPA ID Number Fill in your EPA ICentification Number at the top of each odd-numbered page of Form 2F.You may copy this iiumber d:rectly'.om item I of Form l. ATTACHMENT A ATTACHMENT A II.Improvements B.The D.C.Cook Nuclear Plant is pursuing the following water treatment projects: Makeup Demineralizer Regeneration Waste Neutralization System The Cook Plant is installing a system to collect and treat makeup demineralizer regeneration wastes to meet proposed pH permit limits.The current practice is to isolate the Turbine Room Sump (TRS), accumulate the wastes within the TRS, neutralize the waste with sulfuric acid or sodium hydroxide, then discharge the neutralized contents of the TRS to the Absorption Pond.Because the regeneration wastes are not the only source of water being collected in the TRS, a high water level within the TRS may require the discharge of the sump contents prior to the wastes being completely neutralized. The new system will allow collection and neutralization of the regeneration wastes apart from the TRS.The holding tank for the waste will also be the point of treatment with the capability to add and mix sulfuric acid or sodium hydroxide with the waste prior to metering the neutral mixture to the TRS.The system is targeted for completion by January of 1995, with system start-up to occur thereafter. Sequencing Batch Reactors The Cook Plant is currently requesting quotations to install a pair of pre-engineered sequencing batch reactors (SBR)to meet the proposed groundwater effluent limits.The new system will operate at a design flow of 50,000 GPD with a maximum flow of 60,000 GPD.The South Extended Aeration Package Plant will be utilized as a retention tank to ensure efficient SBR operation. Effluent from the new system will continue to be discharged into one of the two seepage lagoons.The new system will be installed and operational by December of 1995.3.Alum Replacement Program A Chemistry Task Force is evaluating chemical flocculent replacements for alum (aluminum sulfate), taking both groundwater effluent standards and reverse osmosis system performance into consideration. The replacements currently being reviewed are pofymeric flocculents that.will enhance the removal of suspended solids in the pre-filters and meet manufacturer's recommendations for the water ATTACHMENT A (Cont.)entering the reverse osmosis system.The recommendations from the task force, once approved, will require additional time to test and implement. The environmental benefit of this review is the reduced amount of aluminum that will be discharged to the groundwater through the Turbine Room Sump discharge. The scheduled implementation date to use a new flocculent is fourth quarter of 1994.Zebra Mussel Control Strategy The current control plan employs chlorination and periodic shock chemical treatments utilizing a proprietary chemical formulation. The Plant has also changed the source water for the fire protection system to a potable supply from Lake Township.This method of control was developed for short term relief from the effects of zebra mussel infestation. Based on over three years of experience in dealing with the mussels at the Plant and other Great Lakes facilities', a new strategy is being evaluated to protect all operations from infestation. The new strategy incorporates intermittent oxidizing biocide treatments of the circulating water system beginning at the intake structures in Lake Michigan, continuous oxidizing biocide treatment of the essential service water and non-essential service water systems, and addition of sodium bisulflite to reduce any residual oxidizing biocide prior to discharge to the lake.If necessary, shock treatments utilizing proprietary chemical formulations will be administered. The goal of the program is to (l)eradicate existing populations and control further settlement of zebra mussels within the plant systems which utilize lake water, (2)treat the residual oxidant being discharged to non-detectable levels, and (3)reduce or eliminate the number of remedial shock treatments necessary to kill settled colonies of zebra mussels.5.Chemistry Corrosion Control Additives The Plant is evaluating substitutes for the current corrosion control additives in the steam generators, plant heating boiler, feedwater and condensate systems, and closed heating/cooling systems.These substitutes will include carbohydrazide, and other available products from chemical companies such as Betz or Nalco.The environmental benefits of these additives include utilization of more benign corrosion control products or products requiring lower effective concentrations. These products will discharge to the Turbine Room Sump in concentrations to be determined upon treatment optimization. ATTACHMENT B ATTACHMENT B IV.Narrative Description of Pollutant Sources at the D.C.Cook Nuclear Plant in Bridgman, Michigan.A.Approximate Surface Area (in ft')of Impervious Surface and Total Area Drained (Impervious and Pervious)by Outfall Number: OUTFALLP SURFACE AREA TOTAL AREA DRAINED Im ervious 8c Pervious 001S 002S 003S 004S 1,400,000 400,000 150,000 4,000 1,800,000 800,000 450,000 300,000 B.Significant Materials-Treated, Stored, or Disposed of: Specific chemicals that are stored or used in a way that may potentially expose them to the yard drainage system are as follows: Fuel Oil-Stored in several underground and above ground storage tanks throughout the site.All fill areas are within a containment area and overfill alarms are installed for each tank.Yard drain basins are installed with a valve which is closed during the filling process.In the unlikely event a spill does occur, free product is held within the containment. Any and all free product is properly removed by qualified and trained personnel prior to the opening of the basin valve.Strict procedures are outlined by the company for proper" filling procedures in these areas.During maintenance periods, small tanks containing diesel fuel are located around the plant site to fuel generators, compressors, and other auxiliary equipment. These tanks are bermed and deliveries to them are in small quantities. Spills which could occur are immediately cleaned up with absorbent material. ATTACHMENT B (cont.)Sulfuric Acid-Stored in a 10,000 gallon tank which is bermed within a lined concrete structure designed to hold 150%of it's contents in the event of tank overfill or rupture.The sulfuric acid in this tank is used for demineralizer regenerations and pH neutralization. The tank and it'containment structure are located outside and directly adjacent to the Unit 1 Turbine Building.This tank, like all other bulk chemical and fuel oil storage tanks, has an overfill alarm system to help prevent spill events while filling the tank.The fill for this tank is located along the west wall of the Unit 1 Turbine Building and shares a lined concrete spill basin located within the North Chemical Unloading Area with the heating boiler fuel oil tank vents.NOTE: The North Chemical Unloading Area is a bermed tank truck unloading area typical of other unloading areas on the plant site.The area is slightly depressed and sloped to a single storm drain.This drain is outfitted with a valve to isolate the containment from the storm drainage system.The operation of this valve, and others like it within containment areas around the plant site are controlled by plant procedures. Sulfuric acid is also used to regenerate the membranes in the reverse osmosis (RO)unit used for water purification. The RO unit is located outside in the roadway directly west of the Screenhouse. The sulfuric acid is stored in 55 gallon drums which are bermed within a containment system adjacent to the reverse osmosis unit.These drums are changed under the direction of the RO unit operator.Plans are to upgrade this bulk storage to a bermed tank system.Hydrochloric acid as a substitute for the sulfuric acid is being evaluated. Sodium Hydroxide-Stored in a 10,000 gallon tank which is vaulted in the basement of the Unit 1 Turbine Building.This tank has an overfill alarm system.Leaks and spills from the tank and piping are contained within the vault and routed to the turbine room sump for neutralization. The fill for this tank is located next to the fill for the sulfuric acid tank located within the North Chemical Unloading Area.Transformer Oil-Transformers containing mineral oil contaminated with low level PCB's (<50 ppm)which are not routed to oil water separators, are bermed and contain a shutoff valve or manually controlled sump pump.These containments are inspected and released by a trained operator onto the roadways, which eventually enter the yard drain system.Any contamination that is found within the containment areas is removed prior ATTACHMENT B (cont.)to release of the material to the roadways and yard drain system.The transformers are routinely drained for maintenance and refilled on the plant site.Trucks and piping are bermed during transferring operations. IAM transmission/distribution crews maintain the transformers on the plant site in accordance with company procedures. Sodium Hypochlorite (Chlorine) -Unloaded at the South Chemical Unloading Area which is similar in design to the North Chemical Unloading Area.Yard drain basins in this area, are installed with a valve, which is closed during the offload process.In the unlikely event a spill does occur, all free product is held within the containment. Any runoff that enters the yard drain system is retained by the valve at the basin.Any and all free product is properly removed prior to the opening of the basin valve.Clam-trol CT-1 (or other zebra mussel control biocides)-Are applied via tanker trucks staged at the North Chemical Unloading Area.Yard drain basins in this area are installed with a valve, which is closed during the application process.In the unlikely event a spill does occur, all free product is retained within the containment. Any runoff that enters the yard drain system is retained by the valve at the basin.Any and all free product is properly removed prior to the opening of the basin valve.Company procedures are used to apply this chemical.Basin drains in the vicinity of the chemical spargers are diked to prevent release of this chemical to the yard drain system.Herbicides -These materials are used in various areas throughout the Cook Plant property.No bulk quantities of these materials are stored on site.All quantities. are ordered and mixed before applications provided by an offsite vendor.Attachment B-I lists the herbicide reports for the past three years.These reports describe application locations, quantity, and type of material used. ATTACHMENT B (cont.)Non-radioactive Waste Oil and Non-Hazardous Wastes-An above ground 2,000 gallon concrete vaulted (Convault) waste oil tank is located within a containment area directly north of the North Chemical Unloading Area.The stormwater basin within this area is covered with a rubber gasketed steel cover.Draining of stormwater, and loading and unloading of waste oil in this area, is performed by qualified personnel. Barrels of waste oils and other non-hazardous wastes including hydraulic oil, EPA 2000 and glycol waiting processing are also accumulated in this area.Radioactive Waste Oil-One 1,500 gallon radioactive waste oil tank is located in the North Chemical Unloading Area.Radioactive waste oil is processed in accordance with plant procedures. Spills from this tank would be contained within the North Chemical Unloading Area.Sodium Nitrite (Calgon LCS-60)-Added as a corrosion inhibitor in many of the Plant's closed cooling systems.These include the component cooling water system, diesel jacket cooling water system, and air conditioning and heating systems on the plant site.The potential of sodium nitrite contaminating the storm water system is most likely in the office building HVAC systems where small amounts of sodium nitrite solution may leak to condensate drains and into outfall 001S.Storage of this chemical is in bulk drums vyhich pose no threat to the stormwater system.Ethylene Glycol-Used as a refrigerant in the plant's containment ice condenser system and also in the training simulator chiller system.Leaks from the plant's containment ice condenser system are contained and collected within the confines of the auxiliary building and reactor containments. Leaks from the training simulator chiller system are contained and drummed.The resulting ethylene glycol/water solutions can also be collected in the temporary glycol storage tank located within the North Chemical Unloading Area.Periodically, a temporary processing unit is erected on the plant site to process the collected ethylene glycol/water solution.The process is as follows: Hydrogen peroxide (35%)for oxidation and sodium hydroxide (50%)for pH balance are added to the glycol/water solution and introduced into a UV light cell.Ethylene glycol is broken down into carbon dioxide and organic acids.The processing unit is completely bermed and processing is performed under continuous supervision of the processing contractor with oversight from plant staff. ATTACHMENT B (cont.)Make-up Plant Regeneration Waste-After January 1995, acidic and caustic waste solutions produced from regeneration of the Make-up Plant resin'beds will be routed to the Make-up Plant Neutralization Tank located immediately west of the Unit 2 Turbine Building.Sulfuric Acid or sodium hydroxide are added to neutralize the wastes in the tank before they are eventually drained and pumped to the turbine room sump for release to the on site absorption pond.The tank is of a double-walled construction with both walls having been hydro-tested. The inner tank is equipped with level alarm instrumentation. The overflow for the inner tank is routed to the interstitial space between the tank walls.This space can be visually inspected and drained under plant supervision. Piping is above ground and heat traced.Any leak in this piping would be easily detected and repaired.Low Level Radioactive Corrosion Products-During outage periods, low level radioactive corrosion products are sludge-lanced from the steam generators. A high pressure demineralized water hose is used to clean out the corrosion products which collect at the tube sheet.The resulting solution is removed and processed by a contractor with oversight by plant personnel. The sludge-lance unit and auxiliary equipment are completely bermed with the probability of a release from this system to the stormwater system unlikely.Sewage Sludge-Sewage sludge is collected in a temporary tank located at the south end of the South Sewage Treatment Plant.Transferring of sludge is performed by the sewage waste contractor under the supervision of plant personnel. o.Chemicals Awaiting Storage-For brief periods, portable bulk tanks and pallets containing chemicals in drums are off-loaded onto the loading dock in the shipping and receiving area until they can be placed into storage.Deliveries are made to the plant protected area via trucks and forklifts, and placed inside'the Turbine Building or other areas where needed.p.Chemical Cleaning of Heat Exchangers 4 Piping-Oxidizers and organic acids are used to clean heat exchangers and piping around the plant site.The cleaning equipment is contained and operated by contractors with oversight by plant supervision. All other chemical materials are stored within the confines of various buildings and are not considered to be a threat to the yard drainage system. ATTACHMENT B (cont.)C.Control Methods by Outfall (refer to table 2F-1 for codes)001S&002S-Containment areas and basin valves are structural and mechanical control measures in place for these two outfalls.'n addition, containment oil booms are strategically placed at the outlets of these two outfalls.These booms will aid in the containment and absorption of any contaminants should other containment systems fail.These booms are inspected and replaced routinely. Treatment Code: 4-A (discharge to open water)003S&004S-Risk of contaminants from these two outfalls is negligible, therefore, no control measures are in place at this time.Treatment Code: 4-A(discharge to open water) ATTACHMENT B-1 ATTACHMENT B-1 D.C.Cook Plant

SUMMARY

OF PROGRAM-1991 Herbicide Spray Report From April 22-May 1, 1991, Townsend Tree Service applied a mixture of Karmex, Amizine and Oust to control weed growth on the Plant Site.A total of 48 lbs.of Karmex, 560 lbs.of Amizine and 2 Ibs of Oust was applied over 36 acres.The following areas were inspected and treated for weeds: l.2.3.4 5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.Sewage Ponds Road to Absorption Pond 765 Kv Switchgear Yard 345 Kv Switchgear Yard Railroad Tracks east of Training Center Parking lot B 69 Kv Switchgear Yard North Protected Area Fence South Protected Area Fence East Protected Area Fence ICMS Office Trailer ICMS Fab Shop Southwest side of Turbine Building South end of Turbine Building Unit 1 RWST Area Unit 2 RWST Area Hydrogen/Nitrogen Storage Tank Area Construction Fab Shop Road to Meteorological Towers Based upon review of application records and observations of the treated areas, it appears that the herbicides were applied in accordance with herbicide label requirements, and no adverse environmental effects occurred. ATTACHMENT B-1 (cont.)

SUMMARY

OF PROGRAM-1992 Herbicide Spray Report From June 3-7, 1992, Townsend Tree Service applied a mixture of Stomp and Oust to control weed growth on the Plant Site.A total of 91.2 quarts of Stomp and 91.2 ounces of Oust were applied over 36 acres.The manufacturer's label recommends that Stomp be applied at a rate of between 2-4 quarts per acre.Stomp was applied at a rate of 2.7 quarts per acre.The manufacturer's label recommends that Oust be applied up to 12 ounces per acre.Oust was applied at a rate of 2.7 ounces per acre.The following areas were inspected and treated for weeds: l.2.3.4 5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.Sewage Ponds Road to Absorption Pond 765 Kv Switchgear Yard 345 Kv Switchgear Yard Railroad Tracks east of Training Center Parking lot B 69 Kv Switchgear Yard North Protected Area Fence South Protected Area Fence East Protected Area Fence ICMS Office Trailer ICMS Fab Shop Southwest side of Turbine Building South end of Turbine Building Unit 1 RWST Area Unit 2 RWST Area Hydrogen/Nitrogen Storage Tank Area Construction Fab Shop Road to Meteorological Towers Based upon review of application records and observations of the treated areas, it appears that the herbicides were applied in accordance with herbicide label requirements, and no adverse environmental effects occurred. ATTACHMENT B-1 (cont.)

SUMMARY

OF PROGRAM-1993 Herbicide Spray Report From March 8-October 5, 1993, various contractors have applied a mixture of Trimec 899, Orthene 75s, Stomp, Oust, Roundup, and Tri-power to control weed growth on the Plant Site.A total of 270 ounces of Trimec 899, 2 lbs.of Orthene 75s, 103.5 quarts of Stomp, 103.5 ounces of Oust, 214 ounces of Roundup, and 298.4 oz of Tri-power were applied over 36 acres.All were applied as per manufacturers'abels recommendations. The following areas were inspected and treated for weeds: l.2.3.4 5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.Sewage Ponds Road to Absorption Pond 765 Kv Switchgear Yard 345 Kv Switchgear Yard Railroad Tracks east of Training Center Parking lot B 69 Kv Switchgear Yard North Protected Area Fence South Protected Area Fence East Protected Area Fence ICMS Office Trailer ICMS Fab Shop Southwest side of Turbine Building South end of Turbine Building Unit 1 RWST Area Unit 2 RWST Area Hydrogen/Nitrogen Storage Tank Area Construction Fab Shop Road to Meteorological Towers Energy Information. Center Lawn Based upon review of application records and observations of the treated areas, it appears that the herbicides were applied in accordance with herbicide label requirements, and no adverse environmental effects occurred. ATTACHMENT B-2 ATTACHMENT B-2 THER POTENTIAL EXPO URES TO TORMWATER There are seven (7)potential areas of concern which apply to this section which are as follows: 1.Lube Oil Vapor Extractors -located at various sites on the roof of the turbine building.Small amounts of oil vapor droplets (Mobile DTE 797)have the potential to be spilled onto the roof.During rain periods this oil material would eventually be washed into the roof drain system.From this point it would enter the yard drains and be released to Lake Michigan as depicted in the following diagram:.Col~Twg IN V~Dwtlrl~y IH~Awe~Loot Snla~~IW4%1 o Ve4 Wwt TIE tin e lol1 RloW 2.Steam Generator Blowdowns-Two (2)blowdown outlets are located on the east side of the Auxiliary Building.The steam generators are purged of corrosion products periodically to prevent degradation to the steam generator tubes.Large amounts of steam, which may contain trace amounts of organics, ethanolamine, and boric acid are released into the air outside the plant.The products in the steam precipitate to the ground and eventually enter the yard drain system as demonstrated in the following diagram: Note: Water used in this system (to form the steam)is ultra-purified lake water.This water undergoes stringent purification process before it enters the system. 3.Dumpster Cleaning-Dumpster Cleaning Main condenser cooling water is screened through 3/8" mesh traveling screens before passing through the main circ.water pump and service water pump inlets.Materials impinged on these screens including sticks, leaves, zebra mussels, and fish, are routinely backwashed into,a trench and sluiced to both ends of the Screenhouse into debris collection baskets.These collection baskets are then dumped into dumpsters which are hauled ofF the plant site by a local.waste hauler.For public health reasons, these dumpsters are cleaned out periodically. Pathfinder, a low suds cleaner, is used with water to wash out these dumpsters. The wash water flows down a yard drain and out outfall 001S.Outfall 001 a Bar.Ia Lsk0Mictagata ~N Stean Dcaaa~I Oucataaa i I XIANg p'alct Pip~ 4.Roadways and Parking Lots-Automobiles, trucks, and heavy equipment require gasoline, diesel fuel, coolants, hydraulic oil, and lubricants for their operation. Small leaks can eventually be washed down the storm drains to Outfalls 001S, 002S, 003S, and 004S.5.Garon De-Icer 95%Calcium Chloride and 4%Sodium Chloride.Gran-U-Thaw: 90%Carbonyldiamine, Nitrogen Compounds-Urea. Safe Step Airport Ice Control: Potassium Chloride, Sodium Chloride, Urea, and Methylglucoside. Manufacturer trade secret, percentages unavailable. Used on roads, and sidewalks throughout the facility.This material with precipitation will eventually enter the yard drain system that flows to Lake Michigan through outfalls 001S, 002S, 003S and 004S.These road salt compounds tend to leach oils from the asphalt pavement which are washed into the yard drainage system.UppernmplopaotartloSLoi +Memtal Drahapa Cg Tralslsp BsUSiap tarplsp Loi~7 thai hroaa Rosa SMara alt C>5 U pphS ssd kaaairlsS tarlls5 Los Vlrlmi tartlsp Lsi Storm Dralaa~ 6.Fire Protection Systems-To eliminate the threat of zebra mussel infestation in its fire protection system, the plant converted from lake water to a chlorinated municipal water supply.Two 650,000 gallon tanks located south of the plant site provide storage for the fire protection water.The tanks are equipped with an alarm system.The overflow and drainage for these tanks are to the yard drainage system Outfall 003S.On occasion these tanks are drained to perform repairs.Periodically, the fire protection system header and hydrants are flow tested with the water being directed'to the yard drain system.Outfalls 001S, 002S, 003S, and 004S are impacted by these by this testing procedure. The following diagram illustrates the testing and draining process: Fke Prccccaca Wacr Tcrke Bene To Yard Drain S)rt pl))care I Bore To take Mictatna 7.Lawn Sprinkler System-The plant lawn sprinkler system is operated using both circulating water and municipal water supplies.Small amounts of chlorine are contained in the municipal water and in the circulating water which can enter the storm water drainage system and Outfall 001S.Refer to the following diagram for further information. Tramna Corner Poet I Oae Man Oonrd Bonne Encrty Infonnaioa Corner Of5ce Bai)dmS Leke Mictntna Waer Scrota W~Pornp R htcrrnkt~C)dorimtcd From Dr~t Tannel Boer To Ycrd Drein S)rtem Dac~To Lake'ce OO IS)bkorinaed Wacr From Late Tocrnetop ATTACHMENT C ATTACHMENT C I NIFI ANT LEAKS OR SPILLS (past three years)On February 15, March 4, and March 22, 1993, Cook Plant personnel observed a slight sheen on the surface of Lake Michigan, adjacent to the plant's storm water discharges. Subsequent investigation of plant oil systems and operations proved the source to be oil residue from employee vehicles entering the storm water collection system from parking lot runofK Attempts were made to prevent additional oil from entering the catch basins by the use of absorbent booms on all three occasions. A summary of each event is as follows: February 15, 1993 March 4, 1993 Oil sheen from Outfalls 001S and 002S Oil sheen from Outfall 001S March 22, 1993 Oil sheen from Outfall 001S ATTACHMENT D (ANALYTICAL RESULTS) ATTACHMENT D**DESCRIPTION OF RAINFALL EVENT**Fourteen one-hundredths of an inch (0.14)of rain fell on December 18, 1993.The event started at 0630 hrs.and.terminated at 1000 hrs.Outfalls 001S, 002S, 003S, and 004S continued to flow at a rate of 1-2 liters/min. until 1100 hrs.The previous significant event terminated at 1400 hrs.on December 6, 1993 for a total elapsed time of 280.5 hrs.between events.**SAMPLING METHOD**Both grab and flow composite samples were taken during the single storm event of December 18, 1993.Stormwater outfalls 001S, 002S, and 003S were sampled.Since the outfall characteristics of Outfall 003S and 004S are essentially identical, and in very close proximity, Outfall 004S was not sampled.Both Outfall 003S and 004S receive groundwater which emerges from the base of a dune and collects in a trench east of the outfalls.This groundwater mixes with stormwater runoff from the parking lots and roadways south of the plant and flows through outfalls 003S and 004S to Lake Michigan.For purposes of this characterization study, samples were taken of Outfall 003S both before and after mixing with groundwater during the storm event.The results of the analyses are shown in the following pages. ATTACHMENT D VII.Discharge Information PART A 0 TFALL 001S Maximum Values Average Values Pollutant and CAS Number (if available) Grab Sample Taken During First 30 Minutes Flow-weighted Composite Grab Sample Taken During First 30 Minutes Flow-wcightcd Composite Number of Storm Events Sampled Sources of Pollutants Oil and Grease Biological Oxygen Demand (BOD5)3.6 mg/I 2.8 mg/I 4.8 mg/I 3.2 mg/I 3.6 mg/I 4.8 mg/I 2.8 mg/I 3.2 mg/I Storm water runoff Storm water runoff Chemical Oxygen Demand (COD)Total Suspended Solids (TSS)37 mg/I 34 mg/I<18 mg/I 13 mg/I 37 mg/I 34 mg/I<18 mg/I 13 mg/I Storm water runoff Storm water runoff Total Kjeldahl Nitrogen Nitrate plus Nitrite Nitrogen Total Phosphorus 4.9 mg/I 3.7 mg/I 1.5 mg/I 1.8 mg/I 0.19 mg/I 0.11 mg/I 4.9 mg/I 1.5 mg/I 0.19 mg/I 3.7 mg/I 1.8 mg/I 0.11 mg/I Storm water runoff Storm water runoff Storm water runoff pH Minimum 7.4 Maximum 7.4 XTYACHMENT D (cont.)Part A OUTFALL 002S Maximum Values Average Values Pollutant and CAS Number (if available) Grab Sample Taken During First 30 Minutes Flow-weighted Composite Grab Sample Taken During First 30 Minutes Flow-weighted Composite Number of Storm Events Sampled Sources of Pollutants Oil and Grease Biological Oxygen Demand (BOD5)Chemical Oxygen Demand (COD)Total Suspended Solids (TSS)<1 mg/I<1 mg/I 1.5 mg/I 2.9 mg/I<12 mal<12 mg/I<18 mg/I<18 mg/I<I mg/I 1.5 mg/I<18 mg/I<12 mg/I<1 mg/I 2.9 mg/I<18 mg/I<12 mg/I Storm water runoff Storm water runoff Storm water runoff Storm water runoff Total Kjeldahl Nitrogen 20 mg/I 13 mg/I 20 mg/I 13 mg/I Storm water runoff Nitrate plus Nitrite Nitrogen Total Phosphorus 5.6 mg/I 3.2 mg/I 0.14 mg/I 0.20 mg/I 5.6 mg/I 0.14 mg/I 3.2 mg/I 0.20 mg/I Storm water runoff Storm water runoff pH Minimum 7.9 Maximum 8.4 ATTACHMENT D (cont.)'Part A OUTFALL 003S (Before mixing with groundwater) Maximum Values Average Values Pollutant and CAS Number (if available) Grab Sample Taken During First 30 Minutes Flow-weighted Composite Grab Sample Taken During First 30 Minutes Flow-weighted Composite Number of Storm Events Sampled Sources of Pollutants 'il and Grease Biological Oxygen Demand (BOD5)2.1 mg/1 2.7 mg/1 1.8 mg/1 2.6 mg/1 2.1 mg/1 1.8 mg/1 2.7 mg/1 2.6 mg/1 Storm water runoff Storm water runoff Chemical Oxygen Demand (COD)18 mg/1 19 mg/1 18 mg/1 19 mg/1'torm water runoff Total Suspended Solids (TSS)Total Kjeldahl Nitrogen Nitrate plus Nitrite Nitrogen Total Phosphorus 23 mg/1 2.0 mg/1 0.78 mg/1 0.29 mg/I 15 mg/1 2.1 mg/I 1.0 mg/1 0.36 mg/1 23 mg/1 15 mg/1 2.0 mg/1 2.1 mg/1 0.78 mg/1 1.0 mg/1 0.29 mg/1 0.36 mg/1 Storm water runoff Storm water runoff Storm water runoff Storm water runoff pH Minimum 7.5 Maximum 7.5 <<.TTACHMEI<<IT D (cont.)Part A OUTFALL 003S (After mixing with ground water)Maximum Values Average Values Pollutant and CAS Number (if available) Grab Sample Taken During First 30 Minutes Flow-weighted Composite Grab Sample Taken During First 30 Minutes Flow-weighted Composite Number of Storm Events Sampled Sources of Pollutants Oil and Grease Biological Oxygen Demand (BODS)2.2 mg/I 1.8 mg/I 2.2 mg/I 2.9 mg/I 1.8 mg/I 2.9 mg/I 1.8 mg/I 1.8 mg/I Storm water runoff Storm water runoff Chemical Oxygen Demand (COD)Total Suspended Solids (TSS)26 mg/I 19 mg/I<18 mg/I<12 mg/I 26 mg/I 19 mg/I<18 mg/I<12 mg/I Storm water runoff Storm water runoff Total Kjeldahl Nitrogen Nitrate plus Nitrite Nitrogen Total Phosphorus 1.6 mg/I 0.90 mg/I 1.6 mg/I 1.1 mg/I 2.2 mg/I 1.1 mg/I 0.23 mg/I 0.13 mg/I 0.23 mg/I 0.90 mg/I 2.2 mg/I 0.13 mg/I Storm water runoff Storm water runoff Storm water runoff pH Minimum 7.7 Maximum 8.0 .O'TACHMENT D (cont.)VII.Discharge Information PART B OUTFALL 001S Maximum Values Average Values Pollutant and CAS Number (if available) Grab Sample Taken During First 30 Minutes Flow-weighted Composite Grab Sample Taken During First 30 Minutes Flow-weighted Composite Number of Storm Events Sampled Sources of Pollutants Cadmium<.005 mg/I<.005 mg/I<.005 mg/I<.005 mg/I Storm water runoff Chloride Chlorine (total residual)36 mg/I<0.02 ppm 46 mg/I 36 mg/I<0.02 ppm 46 mg/I Storm water runoff Storm water runoff Copper Sulfate 13 mg/I 16 mg/I 13 mg/I<.025 mg/I<.025 mg/I<.025 mg/I<.025 mg/I 16 mg/I Storm water runoff Storm water runoff Total Dissolved Solids (TDS)93 mg/I 160 mg/I 93 mg/I 160 mg/I Storm water runoff Zinc 0.31 mg/I 0.21 mg/I 0.31 mg/I 0.21 mg/I Storm water runoff TTACHMENT D (cont.)PART B OUTFALL 002S Maximum Values Average Values Pollutant an'd CAS Number (if available) Gmb Sample Taken During First 30 Minutes Flow-weighted Composite Grab Sample Taken During First 30 Minutes Flow-weighted Composite Number of Storm Events Sampled Sources of Pollutants Cadmium Chloride<.005 mg/I<.005 mg/I<.005 mg/I 2.9 mg/I 3.4 mg/I 2.9 mg/I<.005 mg/I 3.4 mg/I Storm water runoff Storm water runoff Chlorine (total residual)<0.02 ppm<0.02 ppm Storm water runoff Copper Sulfate Total Dissolved Solids (TDS)Zinc 18 mg/I 26 mg/I 18 mg/I 83 mg/I 100 mg/I 83 mg/I 0.46 mg/I 0.22 mg/I 0.46 mg/I 0.029 mg/I<.025 mg/I 0.029 mg/I<.025 mg/I 26 mg/I 100 mg/I 0.22 mg/I Storm water runoff Storm water runoff Storm water runoff Storm water runoff <<TTACHMENT D (cont.)PART B" OUTFALL 003S (before mixing with groundwater) Maximum Values Average Values Pollutant and CAS Number (if available) Grab Sample Taken During First 30 Minutes Flow-weighted Composite Grab Sample Taken During First 30 Minutes Flow-weighted Composite Number of Storm Events Sampled Sources of Pollutants Cadmium Chloride Chlorine (total residual)Copper Sulfate Total Dissolved Solids (TDS)Zine<.025 mg/I<.025 mg/I 3.4 mg/I 4.0 mg/I 88 mg/I 93 mg/I 0.28 mg/I 0.29 mg/I<.005 mg/I<.005 mg/I 0.75 mg/I 0.86 mg/I<0.02 ppm<.005 mg/I 0.75 mg/I<0.02 ppm<.025 mg/I 3.4 mg/I 88 mg/I 0.28 mg/I<.005 mg/I 0.86 mg/I<.025 mg/I 4.0 mg/I 93 mg/I 0.29 mg/I Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff 4.TTACHMENT D (cont.).PART B OUTFALL 003S (after mixing with ground water)Maximum Values Average Values Pollutant and CAS Number (if available) Grab Sample Taken During First 30 Minutes Flow-weighted Composite Grab Sample Taken During First 30 Minutes Flow-weighted Composite Number of Storm Events Sampled Sources of Pollutants Cadmium Chloride Chlorine (total residual)Copper<.005 mg/I 1.5 mg/I<0.02 ppm<.025 mg/I<.005 mg/I<.005 mg/I<.005 mg/I 4.5 mg/I 1.5 mg/I 4.5 mg/I<0.02 ppm<.025 mg/I<.025 mg/I<.025 mg/I Storm water runoff Storm water runoff Storm water runoff Storm water runoff Sulfate 25 mg/I 120 mg/I 25 mg/I 120 mg/I Storm water runoff Total Dissolved Solids (TDS)97 mg/I 370 mg/I 97 mg/I 370 mg/I Storm water runoff Zinc 0.25 mg/I 0.13 mg/I 0.25 mg/I 0.13 mg/I Storm water runoff ',TTACHMENT D (cont.)VII.Discharge Information PART C OUTFALL 001S Maximum Values Average Values Pollutant and CAS Number (if available) Grab Sample Taken During First 30 Minutes Flow-weighted Composite Grab Sample Taken During First 30 Minutes Flow-weighted Composite Number of Storm Events Sampled Sources of Pollutants Aluminum Barium Boron Cobalt 0.79 mg/I 0.41 mg/I<.20 mg/I<.20 mg/I<.20 mg/I<.20 mg/I<0.05 mg/I<0.05 mg/I 0.79 mg/I<.20 mg/I<.20 mg/I<0.05 mg/I 0.41 mg/I<.20 mg/I<.20 mg/I<0.05 mg/I Storm water runoff.Storm water runoff Storm water runoff Storm water runoff Iron 1.6 mg/I 0.7 mg/I 1.6 mg/I 0.7 mg/I Storm water runoff Lead Magnesium Molybdenum Surfactants Sulfide Tin Radioactivity (alpha)Radioactivity (beta)6.9 pCi/1 4.3 pCi/I 0.049 mg/I 0.016 mg/I<5.0 mg/I<5.0 mg/I<0.2 mg/I<0.2 mg/I 0.060 mg/I 0.029 mg/I<3.0 mg/I<3.0 mg/I<0.2 mg/I<0.2 mg/I 2.1 pCi/1 0.69 pCi/1 0.049 mg/I<5.0 mg/I<0.2 mg/I 0.060 mg/I<3.0 mg/I<0.2 mg/I 2.1 pCi/I 6.9 pCi/I 0.016 mg/I<5.0 mg/I<0.2 mg/I 0.029 mg/I I<3.0 mg/I<0.2 mg/I 0.69 pCifl 4.3 pCi/I Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff 10 ATTACHMENT D (cont.)PA'RT C OUTFALL 002S Maximum Values Average Values Pollutant and CAS Number (if available) Grab Sample Taken During First 30 Minutes Flow-weighted Composite Grab Sample Taken During First 30 Minutes Flow-weighted Composite Number of Storm Events Sampled Sources of Pollutants Aluminum Barium Boron Cobalt Iron Lead Magnesium Molybdenum Surfactants Sulfide Radioactivity (alpha)0.26 mg/I<0.20 mg/I 0.26 mg/I<0.20 mg/I<0.20 mg/I<0.20 mg/I<0.20 mg/I<0.20 mg/I<0.20 mg/I<0.05 mg/I<0.05 mg/I<0.05 mg/I 0.73 mg/I 0.40 mg/I 0.73 mg/I 0.0048 mg/I 0.0032 mg/I 0.0048 mg/I<5.0 mg/I<5.0 mg/I<5.0 mg/I<0.2 mg/I<0.2 mg/I<0.2 mg/I 0.029 mg/I 0.031 mg/I 0.029 mg/I<3.0 mg/I<3.0 mg/I<3.0 mg/I<0.2 mg/I<0.2 mg/I<0.2 mg/I 0.54 pCi/I 0.64 pCi/I 0.54 pCi/I<0.20 mg/I<0.20 mg/I<0.20 mg/I<0.05 mg/I 0.40 mg/I 0.0032 mg/I<5.0 mg/I<0.2 mg/I 0.031 mg/I<3.0 mg/I<0.2 mg/I 0.64 pCi/I Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Radioactivity (beta)7.0 pCi/I 4.7 pCi/I 7.0 pCi/I 4.7 pCi/1 Storm water runoff 11 ,TTACHMENT D (cont.)PART C OUTFALL 003S (before mixing with ground water)Maximum Values Average Values Pollutant alld CAS Number (if available) Grab Sample Taken During First 30 Minutes Flow-weighted Composite Grab Sample Taken During First 30 Minutes Flow-weighted Composite Number of Storm Events Sampled Sources of Pollutants Aluminum Barium Boron Cobalt Iron Lead Magnesium Molybdenum Surfactants Sulfide Tln Radioactivity (alpha)1.2 mg/I 0.85 mg/I 1.2 mg/I<0.20 mg/I<0.20 mg/I<0.20 mg/I<0.20 mg/I<0.20 mg/I<0.20 mg/I<0.05 mg/I<0.05 mg/I<0.05 mg/I 2.5 mg/I 1.7 mg/I 2.5 mg/I 0.0096 mg/I 0.0063 mg/I 0.0096 mg/I<5.0 mg/I<5.0 mg/I<5.0 mg/I<0.2 mg/I<0.2 mg/I<0.2 mg/I 0.043 mg/I 0.049 mg/I 0.043 mg/I<3.0 mg/I<3.0 mg/I<3.0 mg/I<0.2 mg/I<0.2 mg/I<0.2 mg/I 1.63 pCi/I 0.73 pCi/1 1.63 pCi/1 0.85 mg/I<0.20 mg/I<0.20 mg/I<0.05 mg/I 1.7 mg/I 0.0063 mg/I<5.0 mg/I<0.2 mg/I 0.049.mg/I <3.0 mg/I<0.2 mg/I 0.73 pCi/I Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Radioactivity (beta)5.2 pCi/I 3.1 pCi/I 5.2 pCi/I 3.1 pCi/1 Storm water runoff 12 ~.TTACHMENT D (cont.)PART C" OUTFALL 003S (after mixing with ground water)Maximum Values Average Values Pollutant and CAS Number (if available) Grab Sample Taken During First 30 Minutes Flow-weighted Composite Grab Sample Taken During First 30 Minutes Flow-wcightcd Composite Number of Storm Events Sampled Sourci:s of Pollutants Aluminum Barium Boron Cobalt Lead Magnesium Molybdenum Surfactants Sulfide Radioactivity (alpha)Radioactivity (beta)1.2 mg/I<0.20 mg/I<0.20 mg/I<0.05 mg/I 0.0082 mg/I<5.0 mg/I<0.2 mg/I 0.031 mg/I<3.0 mg/I<0.2 mg/I 1.2 pCi/1 5.0 pCin 1.1 pCi/1 1.2 pCi/1 1.1 pCin 4.3 pCi/I 5.0 pCi/I 4.3 pCi/I 0.46 mg/I 1.2 mg/I 0.46 mg/I<0.20 mg/I<0.20 mg/I<0.20 mg/I<0.20 mg/I<0.20 mg/I<0.20 mg/I<0.05 mg/I<0.05 mg/I<0.05 mg/I 0.94 mg/I 2.3 mg/I 0.94 mg/I 0.0031 mg/I 0.0082 mg/I 0.0031 mg/I 14.0 mg/I<5.0 mg/I'4.0 mg/I<0.2 mg/I<0.2 mg/I<0.2 mg/I 0.031 mg/I 0.031 mg/I 0.031 mg/I<3.0 mg/I<3.0 mg/I<3.0 mg/I<0.2 mg/I<0.2 mg/I<0.2 mg/I Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff Storm water runoff 13 ATTACHMENT E (DRAWINGS) DRA WING NUMBER DESCRIPTION 01 02 03 04 05 06 07 08 09 10 11A 11B ENTIRE PROPERTY PLANT WITH 001S&002S PLANT WITH 001S ONLY PLANT WITH 002S ONLY TRAINING CENTER AND ROAD AREA (OUTFALL 001S)SOUTH AREA WITH 003S 2 004S ENERGY INFORMATION CENTER AREA POST 1 GUARD HOUSE AREA PERVIOUS/IMPERVIOUS DRAINAGE AREAS HERBICIDE APPLICATION AREAS TOPO MAP (BRIDGMAN) TOPO MAP (COOK PLANT) Indiana Michigan Power Company O."e SLrnnin Soeare Pa Box60 For;'Boyne lixed.'6691 219'25 2111 CERTIFIED MAIL f Z 756 046 675 lilt INDIANA NICHIGiAN POWER Mr.William E.McCracken Surface Water Quality Division Permits Section Department of Natural Resources P.0.Box 30028 Lansing, MI 48909 March 31, 1994

Dear Mr.McCracken:

Sub)ect: Indiana Michigan Power Company Donald C.Cook nuclear Plant NPDES Permit No.MI 0005827 Renewal Application Enclosed is the Industrial and Commeicial Wastewater Discharge Application for renewal of the Cook Nuclear Plant NPDES Permit.Also enclosed, is for 2P for renewal of the Cook Nuclear Plant Storm Water Discharge Permit.These applications are being submitted 180 days prior to the expiration of the present permit.Cook Nuclear Plant also has submitted a separate groundwater permit application to the agency's groundwater division;the information is also enclosed with this application. During the term of the present permit, several permit modifications were made to improve Cook Nuclear Plant operations. We appreciate your efforts in these permit modifications. Additional changes are under development which will affect Cook Nuclear plant operations. Information regarding these improvements is enclosed with the following attachments: Attachment Descri tion Makeup Demineralizer Regeneration Waste Neutralization System Sequencing Batch Reactors Zebra Mussel Control Strategy Alum Replacement Program Chemistry Corrosion Control Additives Thermal Effluent Should you have any questions regarding these renewal applications, please contact John Carlson, Cook Nuclear Plant March 31, 1994 Mr.William E.McCracken Page 2 Environmental Supervisor, at (616)465-5901 ext.1153, or me at (219)425-2118. We would be happy to meet with you at your convenience to discuss the application. very truly yours, Donald L.Baker Environmental Affairs Director DLB/sdb/065,66 Attachments certify under penalty of law that I have personally examined and'am familiar with the information submitted on this and all attached documents; and based on my inquiry of those individuals immediately responsible for obtaining the information, I believe the submitted information is true, accurate and complete.I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment. Donald L.Baker March 31, 1994 Mr.William E.McCracken Page 3 bc: W.N.D'Onofrio/M. A.Bailey/J.L.Hughey A.A.Blind S.J.Brewer D.M.Fitzgerald/J. P.Carlson E.E.Fitzpatrick D.W.Kemp/K.D.Hack T.E.Webb/J.P.Novotony

Attachment 1 Makeup Demineralizer Regeneration Waste Neutralization System Cook Nuclear Plant is installing a system to collect and treat makeup demineralizer regeneration wastes to meet proposed pH permit limits.The current practice is to isolate the Turbine Room Sump (TRS), accumulate the wastes within the TRS, neutralize the waste with sulfuric acid or sodium hydroxide, and then discharge the neutralized contents of.the TRS to the Absorption Pond.Because the regeneration wastes are not the only source of water being collected in the TRS, a high water level within the TRS may require the discharge of the sump contents prior to the wastes being completely neutralized. I The new system vill allow collection and neutralization of the regeneration wastes apart from the TRS.The holding tank for the waste will also be the point.of treatment with the capability to add and mix sulfuric acid or sodium hydroxide with the waste prior to metering the neutral mixture to the TRS.The total cost of the Makeup Demineralization Waste System is$3,600,000.00. The system is targeted for completion by January of 1995, with system start-up to occur thereafter. Attachment 2 Sequencing Batch Reactors Cook Nuclear Plant is currently requesting quotations to install a pair of pre-engineered sequencing batch reactors (SBR)to meet the proposed groundwater effluent limits.The new system will operate at a design flow of 50,000 GPD with a maximum flow of 60,000 GPD.The South Extended Aeration Package Plant will be utilized as a retention tank to ensure efficient SBR operation. Effluent from the new system will continue to be discharged into one of the two seepage lagoons.The new system will be installed and operational by December of 1995. Attachment 3 Zebra Mussel Control Strategy Zebra mussels are a menace to any industrial or municipal process drawing water from Lake Michigan.Our current control plan is to chlorinate and perform periodic shock chemical treatments utilizing proprietary chemical formulations. This method of control was developed for short term relief from the effects of zebra mussel infestation. We have also changed our source water for our fire protection system to a potable supply from Lake Township.After four years of experience in dealing with zebra mussels at Cook Nuclear Plant and other Great Lake facilities, a new strategy is under consideration to protect all operations from infestation. The new strategy incorporates intermittent oxidizing biocide treatments of the circulating water system beginning at the intake structures in Lake Michigan, continuous oxidizing biocide treatment of the essential service water and non-essential service water systems, addition of sodium bisulfate to reduce any residual oxidizing biocide prior to discharge to Lake Michigan, and if necessary, shock treatments utilizing proprietary chemical formulations. The goal of the program is to (1)eradicate existing populations and control further settlement of zebra mussels within plant systems that utilize lake water, (2)reduce the residual oxidant being discharged to non-detectable levels, and (3)reduce or eliminate the number of remedial shock treatments necessary to kill settled colonies of zebra mussels.The proposed oxidizing biocide treatment uses sodium bromide and sodium hypochlorite, or a proprietary mixture such as Nalco Acti-Brom, to retard veliger settlement and maintain microbiological control.Should non-oxidizing biocides be required, we plan to use either Betz CT-2, Betz CT-4, Calgon H-130M, or Nalco 9210.We request the flexibility to use any FIFRA (Federal Insecticide, Fungicide, and Rodenticide Agency)approved non-oxidizing biocide.The concentration of any of the treatment chemicals will be brought to within the water quality based effluent limits, as required, using formulations of bentonite clay or other appropriate material.The resultant chemical changes will ultimately affect discharges to Lake Michigan via ESW, NESW, and the circulating water systems, and discharges to the groundwater through the turbine room sump, from pump seals and equipment drains of the treated systems.We may begin portions of the plan, such as continuous oxidizing biocide treatments of the ESW and NESW systems, in 1994.Portions of the plan, where new systems require capital expenditures along with design and installation of the equipment, will take longer.Therefore, the plan may not be fully implemented for several years.We will continue to inform the MDNR of planned operational changes as they are finalized. Attachment 4 Alum Replacement Program A Chemistry Task Force is evaluating chemical flocculent replacements for alum (aluminum sulfate)to improve performance of the makeup water system.The replacements being reviewed are mainly polymeric'flocculents which will enhance the removal of suspended solids in the pre-filters and meet manufacturer recommendations for the water entering the reverse osmosis system.The recommendations from the task force, once approved, will require additional time to test and implement. The environmental benefit of product substitution is the reduced amount of aluminum which will be discharged to the groundwater through the turbine room sump.The scheduled target implementation date to use a new flocculent is the fourth quarter of 1994. Attachment 5 Chemistry Corrosion Control Additives Cook Nuclear Plant is evaluating substitutes for the current corrosion control additives in the steam generators, plant heating boiler, feedwater and condensate systems, and closed heating/cooling systems.These substitutes will include carbohydrazide, and other available products from chemical companies such as Betz or Nalco.The environmental benefits of these additives include utilization of more benign corrosion control products or products requiring lower effective concentrations. Use of these products will necessitate discharge to Outfalls 001, 002, 003, OOA, OOB, OOC and OOD in concentrations to be determined upon effective optimization. Consequently, higher concentrations of iron and other system products may be seen temporarily. Attachment 6 Therma1 Effluent The current thermal effluent limit for the circulating water system discharging to Lake Michigan is 15.5 X 10'TU/hr.This is calculated from measurements taken at Outfalls 001 and 002 for Units 1 and 2, respectively. At this limit, the units are operating with calculated maximum temperature differentials of 22.3 and 18.3 degrees F for Units 1 and 2, respectively. The units are have been required to reduce load from 1004 during the hottest summer months to maintain the thermal discharge withxn limits.In order to maintain 1004 load throughout the entire year, including the hot summer months, we propose increasing the thermal discharge limit to 16.25 X 10'TU/hr.At the proposed thermal discharge, the temperature differentials are calculated to be approximately 1 degree F greater<or 23.4 and 19.3 degrees F for Units 1 and 2 respectively, using the same conditions as in the above calculations. The increase in heat load and discharge temperature to Lake Michigan are minimal and are not expected to result in adverse environmental harm in and around the plant discharges. As in the past, the maximum inlet temperature which the units can operate at full power is 87.5 degrees F, because of the limitations on the control room air conditioning system.The maximum effluent temperatures during 1993 were 98.7 and 89.7 degrees F for Units 1 and 2, respectively. Note that Unit 2 operated at 704 load during most of 1993 to increase the time between refueling outages of the two Cook Nuclear Plant Units.Indiana Michigan Power Company funded one of the most extensive aquatic ecological research projects on the Great Lakes from 1973 through 1982 at the Cook Nuclear Plant.Indiana Michigan Power Company's contractor, The University of Michigan, Center for Great Lakes Research Center (then the Great Lakes Research Division), published a book in 1986 that was a compilation of the physical, chemical, and biological studies conducted under the direction of Dr.John C.Ayers.Among other conclusions, these studies documented the lack of adverse impacts from the thermal discharge. The title page, table of contents, and list of publications generated from the research were copied from the book and are attached to this permit application. Thermal plume maps were made during different seasons of the year to determine the impact of the Cook Nuclear Plant thermal effluent on Lake Michigan.These maps showed the surface area of the plume was well within the 570 acre mixing zone specified in the NPDES Permit issued for Cook Nuclear Plant on December 27, 1974, and modified April 4, 1978.Even in the simplistic assumption that a 54 increase in the heat rejection rate resulted in a similar increase of the thermal plume surface area, the resulting plume would still be well within the mixing zone limit.The small increase in the maximum delta T will not measurably alter the thermal regime that already exists in the immediate vicxnity of the high velocity discharge. The thermal discharge from Cook Nuclear Plant was granted a variance from meeting best available treatment technology under Section 316(a)of the Federal Water Pollution Control Act of 1972 by the Water Resources Commission in May, 1977. GREAT LAKES RESEARCH DIYISION/PUBLICATION 22 SOUTHEASTERN NEARSHORE LAKE MICHIGAN: IMPACT OF THE DONALD C.COOK NUCLEAR PLANT Edited by Ronald Rossmann GREAT LAKES RESEARCH DIVISION The University of Michigan Ann Arbor, Michigan 48109 A FINAL REPORT TO INDIANA&MICHIGAN ELECTRIC COMPANY 1986 4 pl CONTENTS INTRODUCTlON Ronald Rossmann SEDIMENTS OF SOUTHEASTERN NEARSHORE~LAKE MICHIGAN Ronald Rossmann, Kjel/A.Johansen, and Erwin Seibel............... WATERS OF SOUTHEASTERN NEARSHORE LAKE MICHIGAN Ronald Rossmann IMPACT OF THE DONALD C.COOK NUCLEAR PLANT ON PHYTOPLANKTON Ronald Rossmann, William Y.B.Chang, James A.Bowers, Laurie Feldt, and James Barres PHYTOPLANKTON POPULATIONS OF SOUTHEAST LAKE MICHIGAN 1974-1982 James A.Bowers, Ronald Rossmann, James Barres, and William Y.B.Chang IMPACT OF THE DONALD C.COOK NUCLEAR PLANT ON ZOOPLANKTON IN SOUTHEASTERN LAKE MICHIGAN Marlene S.Evans and Glenn J.Warren EFFECTS OF THE DONALD C.COOK NUCLEAR PLANT ON'ACROZOOBENTHOS IN NEARSHORE SOUTHEASTERN LAKE MICHIGAN David S.White, Michael Winnell, Catherine Zawacki, Roger LaDronka, Thomas Zdeba, and Samuel Mozley ECOLOGY OF THE MACROZOOBENTHOS IN THE VICINITY OF THE DONALD C.COOK NUCLEAR PLANT David.S.White, Michael Winnell, Catherine Zawacki, Roger LaDronka, Thomas Zdeba, and Samuel Mozley IMPACT OF THE DONALD C.COOK NUCLEAR PLANT ON FISH.David J.Jude, David Bimber, Nancy Thurber, Frank Tesar, Laura Nogucht', Pamela Mansfield, Heang Tin, Paul Rago ECOLOGY OF FISH IN NEARSHORE SOUTHEASTERN LAKE MICHIGAN, 1973-1982 Frank Tesar, David J.Jude, He'ang Tin, Pamela Mansfield............ LAKE AND SHORE ICE CONDITIONS ON SOUTHEASTERN LAKE MICHIGAN Erwin Seibel.13 51 87 141 169 207 253 285 353 401 INTRODUCTION Ronald Rossmann The Laurentian Great Lakes serve as a source of cooling water for both fossil-and nuclear-fueled power plants.In the early 1960s, projected heavy utilization of this freshwater resource by power plants raised concerns about the environmental impact of power plants on the lakes.Such public, governmental, and industrial concerns led to the federal requirement that environmental impact studies be con-ducted at all proposed or newly constructed power plants, especially nuclear power plants.The Great Lakes Research Division of The University of Michigan was contracted by Indiana&Michigan Electric Company to conduct an environmental" impact study of the Donald C.Cook Nuclear Plant, investigating the area through the pre-operational years of construction and into the period of plant operation. DONALD C.COOK NUCLEAR PLANT The Donald C.Cook Nuclear Plant is a 2,200 MW steam electric generating station situated in a belt of sand dunes on the southeastern shore of Lake Michigan about 18 km southwest of St.Joseph, Michigan (Indiana&Michigan Electric Com-pany and Indiana&, Michigan Power Company 1973)(Fig.I).Preparation of the site for construction of the plant began in 1968.Unit I was operational in 1975 and Unit 2 in 1978.The plant was built at a time when public concern for the environ-ment reached its zenith.At full operation, the plant uses roughly 6,300 m'f lake water per minute in once-through cooling of its condensers; the water returned to the lake is 9-12C'bove the intake temperature. Water is withdrawn from the lake through three intake cribs located at a water depth of 7.3 m approximately 686 m offshore (Fig.2).The intake structures extend 2 m above the lake bottom.Maximum water velocity is 1.8 m/s within the three 4.9-m diameter intake pipes.Condenser cooling water is returned to the lake through two discharge pipes located at a water depth of 5.5 m approximately 366 m offshore.Riprap beds of crushed limestone were deposited around the intake and discharge structures to prevent erosion and scour of the lake bottom.During winter, water is only drawn into the plant through the two outer intake cribs.Heated water is discharged through the center intake, which is turned into a discharge to prevent ice formation around the other intake structures. Within the screenhouse, trash bars 6.6 cm apart prevent large pieces of debris.from entering the intake forebay.Vertical traveling 9.5-mm bar mesh screens within the forebay impinge trash and fish too large to pass through the condensers. HISTORY OF THE ENVIRONMENTAL IMPACT STUDY Though the Great Lakes Research Division's environmental impact study included physical and chemical studies of nearshore southeastern Lake Michigan, it focused 2 D.C.COOK iVUCLEAR PLAtVT IMPACT MILWAUKE E MUSKEGON Ktlometero CHICAGO ST.JOSEPH COOK PLANT FIGURE I.Location of the Donald C.Cook Nuclear Plant on the southeastern shoreline of Lake Michigan.on major biological components of the ecosystem (benthos, phytoplankton, zoo-plankton, fish)and shoreline erosion.Preoperational surveys began in 1966.Until 1970, they were sporadic and consisted mainly of phytoplankton enumerations and some benthos and zooplankton enumerations. Between 1970 and 1972, seasonal surveys, primarily of phytoplankton and secondarily of zooplankton and benthos, were conducted. Beginning in 19'72 and continuing iltto 1982, sampling frequency and intensity increased and equal effort was given to studies of phytoplankton, zooplankton, and benthos.Fishery studies began in 1972.They represented roughly 50olo of the study effort between 1973 and 1982.Until 1974, all studies were carried out on nearshore southeastern Lake Michigan.ln 1974, preliminary studies of the entrainment of organisms through the plant and their impingement on the plant's traveling screens began.When unit 1 of the plant became operational in 1975, full-scale entrainment studies of phytoplankton, zoo-IIVTRODUCTlON 3 PITAKES tdepttr S)SOUTH DISCHARGE tdepth~6m) IIORTH DISCHARGE tdeptli 6m)Lcd Atichipn TRASH BARS WIT 2 DISCHARGE FOREBAY TRAVELING SCREEIIS ptTAKE FOREtutf tet II 8 7 6S es T I CIRCILATPIQ TER PINPS PITAKE SALPUIIG LOCATIOIIS I I UNT I OSCHARGE FOREBAY DISCHARGE AAIAPLPIG CONDENSER WIT 2 COIE)ENSER LNIT I FIGURE 2.Schematic representation of the Donald C.Cook hluclear Plant circu-lating water system.plankton, benthos, fish eggs, and fish larvae began.At the same time, impingement of fish and benthos on the traveling screens was monitored. All field studies ceased in 1982.This book represents the highlights of the findings from the impact study.For details of each facet of the study, the reader is referred to the list of all project reports (Table I).These are available upon request.y), y).d)t TABLE l.Reports on the Donald C.Cook Nuclear Plant environmental impact study.Ayers, J.C., and J.C.K.Huang.1967.General studies.Part I, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.31 pp.Ayers, J.C., A.E.Strong, C.F.Powers, and R.Rossmann.1967.Studies of local winds and alongshore currents.Part II, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.45 pp Ayers.J.C., R.F.Anderson, N.W.O'ara, and C.Kidd.1970.Cook Plant preaperational studies l969.Part IV, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.92 pp.Ayers, J.C..D.E.Arnold, R.F.Anderson, and H.K.Soo.1971.Cook Plant preaperational sludies l970.Part VII, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.85 pp.Ayers.J.C., N.W.O'ara, and W.L.Yocum.1971.fYinter operations 1970-1971. Part

4 D.C.COOK NUCLEAR PLANT IMPACT Vill.Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.41 pp.Ayers, J.C..W.L.Yocum, H.K.Soo, T.W.Bottrell, S.C.Mozley, and L.C.Garcia.1971.The biological survey of 10 July 1970.Part IX, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division.The University of Michigan, Ann Arbor, Mich.72 pp.Ayers, J.C., H.K.Soo, and W.L.Yocum.1972.Cook Plant preoperational studies 1971.Part X, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.152 pp.Ayers, J.C., and W.L.Yocum.1972.IVinter operations 1971-1972. Part XI, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.26 pp.Ayers, J.C.;and E.Seibel (eds.).1973.Cook Plant preoperational studies 1972.Part Xlll.Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.281 pp.Ayers, J.C., W.L.Yocum, and E.Seibel.1973.IYinter operations 1972-1973. Part XIV, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.22 pp.Ayers.J.C., S.C.Mozley, and J.C.Roth.1973.The biological survey of 12 iVovember 1970.Part XV, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.69 pp.Ayers, J.C., and E.Seibel (eds.).1973.Program of aquatic studies related to the Donald C.Cook Nuclear Plant.Part XVII, Benton Harbor Power Plant Limnological Studies, Spe-cial Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.57 pp.Ayers.J.C., S.C.Mozley, and J.A.Stewart.1974.The seasonal biological surveys of 1971.Part XIX, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.181 pp.Ayers, J.C.1975.Bacteria and phytoplankton of the seasonal surveys of 1972 and 1973.Part XXI, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.153 pp.Ayers, J.C.1975.The phytoplankton of the Cook Plant monthly minimal surveys during the preoperational years 1972, 1973 and 1974.Special Report 59, Great Lakes Research Divi-sion, The University of Michigan, Ann Arbor, Mich.51 pp.Ayers.J.C., N.V.Southwick, and D.G.Robinson.1977.Phytoplankton of the seasonal surveys of 1974 and 197S and initial pre-vs.post-operational comparisons at Cook Nuclear Plant.Part XXIII, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.279 pp.Ayers, J.C.1978.Phytoplankton of the seasonal surveys of 1976, of September 1970, and pre-vs.post-operational comparison at Cook Nuclear Plant.Part XXV, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.258 pp.Ayers, J.C., and S.J.Wiley.1979.Phytoplankton of the seasonal surveys of 1977, and further pre-vs.post-operational comparisons at Cook Nuclear Plant.Part XXVII, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division.The University of Michigan, Ann Arbor, Mich.92 pp., plus Appendix of 3 microfiche cards (122 pp.).Ayers, J.C., and L.E.Feldt.1982.Phytoplankton of the seasonal surveys of 1978 and 1979, and further pre-vs.post-operational comparisons at Cook Nuclear Plant.Part XXIX, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.70 pp., plus Appendi-ces of 9 microfiche cards (256 pp.).Ayers, J.C., and L.E.Feldt.1983.Phytoplankton of the seasonal surveys of 1980, 1981, and April 1982 and further pre-vs.postoperational comparisons at Cook Nuclear Plant.Part INTRODUCTION 5" l.at al tk tl h.nd>of he nd on ch f 3 79, IX, kes idt-XXXI, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.91 pp., plus Appendi-ces of 5 microfiche cards (268 pp.).Barres, J., L.Feldt, W.Chang, and R.Rossmann.1984.Entrainment of phytoplank(on at the Donald C.Cook lVuclear Plant-1980-19B2. Part XXXII, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The Uni-versity of Michigan, Ann Arbor, Mich.92 pp., plus Appendices of 7 microfiche cards (486 pp).Bimber, D.L., M.Perrone, Jr., 1.Noguchi, and D.J.Jude.1984.Field distribution and entrainment of fish larvae and eggs at the Donald C.Cook Nuclear Power Plant, south-eastern Lake Michigan, 1973-1979. Special-Report 105.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.320 pp.Chang, W., R.Rossmann, J.Pappas, and W.L.Yocum.1981.En(rainmen(of phyto-plankton at (he Donald C.Cook Nuclear Plant-1978. Part XXVlll, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.106 pp., plus Appendix of 4 microfiche cards (180 pp.).Chang, W.Y.B., and M.S.Shahraray. 1986.Interactive data base managemen(system for ecological studies rela(ed to the Donald C.Cook¹clear Power Plant.Special Report 119.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.158 pp.Dorr, J.A., I I I, and T.J.Miller.1975.Underwater opera(ionsin southeastern Lake Michigan near the Donald C.Cook (Vuclear Plant during 1974.Part XXII,-Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The Uni-versity of Michigan, Ann Arbor, Mich.32 pp.Dorr, J.A., lll, and D.J.Jude.1986.Diver assessment of (he inshore sou(heastern Lake Michigan environment near the D.C.Cook iVuclear Plant, 1973-82.Special Report 120.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.Evans, M.S.1975.The 1975 preoperational zooplank(on investigations relative to the Donald C.Cook Nuclear Power Plant.Special Report 58.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.187 pp.Evans, M.S., T.E.Wurstcr, and B.E.Hawkins.1978.The 1975 and 1976 operational

ooplankton inves(igations relative to the Donald C.Cook iVuctear Power Plam, with tests for plant effects (1971-197(f).

Special Report 64.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.166 pp., plus Appendix of 4 microfiche cards (236 pp.).Evans, M.S., D.W.Sell, and D.I.Page.1982.Zooplankton studiesin 1977 and 1978 at'the Donald C.Cook Nuclear Power Plant;comparisons of preoperational (1971-/974) and opera(ional (197$-1978)population chare(eristics. Special Report 89.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.235 pp., plus Appendix of 5 microfiche cards (222 pp.).Evans, M.S., G.J.Warren, D.I.Page, and L.F.Flath.1986.Zooplankton studies at the Donald C.Cook Nuclear Power Plant: 1979-1982 investigations including preoperational (1971-1974) and operational (1975-1982) comparisons. Special Report 111.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.Johnston, E.M.1973.Effect of a thermal discharge on benthos populations: Statistical methods for assessing the impact of the Cook Nuclear Plant.Part XVIII, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The University of Michigan.Ann Arbor, Mich.20 pp.Johnston.E.M.1974.Statistical po~er of a proposed method for detecting the effect of waste heat on benthos populations. Part XX, Benton Harbor Power Plant Limnological Studies, Specia!Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.29 pp.Jude, D.J-, T.W.Bottrell, J.A.Dorr III, and T.J.Miller.1973.S(udies of the fish population near the Donald C.Cook Nuclear power plant, 1972.Part Xlt, Benton 6 D.C.COOK NUCLEAR PLANT IMPACT Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.115 pp.Jude, D.J., F.J.Tcsar, J.A.Dorr III, T.J.Miller, P.J.Rago, and D.J.Stewart.1975.Inshore Lake Michigan fish populations near the Donald C.Cook Nuclear Power Plan(, l973.Special Report 52.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.267 pp.Jude, D.J., F.J.Tesar, J.C.Tomlinson, T.J.Miller, N.J.Thurber, G.G.Godun, and J.A.Dorr lll.1979.Inshore Lake Michigan fish populations near the D.C.Cook Nuclear Plan(during preopera(ional years-l973, l974.Special Report 71.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.529 pp.Kidd, C.C.1970.Pontoporcia af finis (Crus(acea, Amphipoda) as a moni(or of radionuclides released (o Lake Michigan.Part VI, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.71 pp.Krezoski, J.R.1969.Some effects of power plant was(e heat on the ecology of Lake Michi-gan.Part lll, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.78 pp.LaDronka, R.M.1984.Oligochae(a. Part 3: Ecology of the zoobenthos of southeastern Lake Michigan near the D.C.Cook Nuclear Power Plant.Special Report 103.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.290 pp.Lauritsen, D.D., and D.S.White.1981.Compara(ives(udies of the zoobenthos of a na(ural and a man-made rocky habi(a(on the eas(em'shore of Lake Michigan.Special Report 74.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.65 pp.Mozley, S.C.1975.Preopera(ional investigations of zoobenthos in southeastern Lake Michi-gan near the Cook Nuclear Plan(.Special Report 56.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.132 pp.Noguchi, L.S., D.L.Bimber, H.T.Tin, P.J.Mansfield, and D.J.Jude.1985.Field dis(ribu(ion and en(rainmen(of fish larvae and eggs a((he Donald C.Cook Nuclear Power Plant, sou(heas(em Lake Michigan, l980-l982. Special Rcport 116.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.251 pp.O'ara, N.W., R.F.Anderson, W.L.Yocum, and J.C.Ayers.1970.Winter opera(ions, March l970.Part V, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, Thc University of Michigan, Ann Arbor, Mich.17 pp.Rossmann, R.1975.Chemis(ry of nearshore sur/icial sediments from sou(heas(em Lake Michigan.Special Report 57.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.62 pp.Rossmann, R., N.M.Miller, and D.G.Robinson.1977.Entrainment of phy(oplank(on a(the Donald C.Cook Nuclear Plan(-l97S. Part XXIV, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.265 pp.Rossmann, R., L.D.Damaske, and N.M.Miller.1979.Entrainment of phy(oplank(on a(the Donald C.Cook Nuclear Plan(-l976. Part XXVI, Benton Harbor Power Plant Limno-logical Studies, Special Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.88 pp., plus Appendix of 3 microfiche cards (154 pp.).Rossmann, R., W.Chang, L.D.Damaske, and W.L.Yocum.1980.Entrainment of phy(o-plank(on a(the Donald C.Cook Nuclear Plan(-/977. Special Report 67.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.180 pp., plus Appendix of 2 microfiche cards (118 pp.).Rossmann, R., W.Chang, and J.Barres.1982.En(rainmen(of phy(oplank(on a(the Donald C.Cook Nuclear Plan(-l979. Part XXX, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor.Mich.98 pp., plus Appendix of 4 microfiche cards (156 pp.).Seibel, E..J.C.Roth, J.A.Stewart, S.L.Williams.1973.Psammoli((oral inves(iga(ion 1972.Part XVI, Benton Harbor Power Plant Limnological Studies, Special Report 44.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.63 pp. INTRODUCTION 7.rch>75.znt, Xnn and ook ikcs ides lies, Ann chi-rcat.akc skes'ural The~ield~iwer arch~ns, pof't PP ,ake gan, in at'lant:rsity rt the mno-ty of)hyto-akes cndix Scibcl, E., and J.C.Ayers (cds.).1974.The biological, chemical, and physical character of Lake Michigan in the vicinity of (he Donald C.Cook Nuclear Plant.Special Report 51.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.475 pp.Scibcl, E., C.T.Carlson, and J.W.Maresca, Jr.1975.Lake and shore ice conditions on southeastern Lake Michigan in the vicinity of the Donald C.Cook Nuclear Plant:~inter l973-74.Special Report 55.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.62 pp.Tcsar, F.J., and D.J.Jude.1985.Adul(and juvenile fish populations of inshore southeast-ern Lake Michigan near the Cook Nuclear Power Plant during l973-82.Special Report 106.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.94 pp., plus Appendices of 5 microfiche cards (301 pp.).Tesar, F.J., D.Einhousc, H.T.Tin, D.L.Bimber, and D.J.Jude.1985.Adult and juvenile fish populations near the D.C.Cook Nuclear Power Plant southeastern Lake Michigan during preoperational (I973-74)and operational (l97$-79)years.Special Report 109.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.341 pp.Thurber, N..and D.J.Jude.1984.Impingement losses at the D.C.Cook iVuclear Plant during l975-l979 with a discussion of fac(ors responsible and rela(ionships to field catches.Special Report 104.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.24 pp., plus Appendix (75 pp.).Thurber, N., and D.J.Jude.1985.Impingement losses at the D.C.Cook lVuclear Plant during l975-l982 with a discussion of factors responsible and possible impac(on local populations. Special Report 115.Great Lakes Research Division, The University of Michi-gan, Ann Arbor, Mich.70 pp., plus Appendix (88 pp.).White, D.S., and M.H.Winncll.1986.Introduction. Part 1: Ecology of the zoobenthos of southeastern Lake Michigan near thc D.C.Cook Nuclear Povver Plant.Special Report 122.Great Lakes Research Division, Thc University of Michigan.Ann Arbor, Mich.Winncll, M.H.1984.Malacostraca (Amphipoda, Mysidacea, Isopoda, and Decapoda). Part 5: Ecology of the zoobenthos of southeastern Lake Michigan near the D.C.Cook Nuclear Power Plant.Special Report 99.Great Lakes Research Division, The University of Michi-gan, Ann Arbor, Mich.94 pp.Winncll, M.H.1984.Chironomidae (and other Diptera).Part 6: Ecology of the zoobenthos of southeastern Lake Michigan near the D.C.Cook Nuclear Pouter Plant.Special Report 100.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.177 pp.Zawacki, C.M.1985.Minor taxa (Hydrozoa, Turbellaria, Hirudinea, Arachnoidea, non-Dip(eran insects, Gastropoda, and zoobenthic meiofauna). Part 2: Ecology of the zooben-thos of southeastern Lake Michigan near the D.C.Cook Nuclear Power Plant.Special Report 112.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.201 pp.Zdeba, T.W., and D.S.White.1985.Pisidiidae. Part 4: Ecology of the zoobenthos of southeastern Lake Michigan near the D.C.Cook Nuclear Power Plant.Special Report 113.Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.85 pp.onald agical uigan.at,)PP This book has been structured so that each chapter dealing with a specific facet of the study will be complete in itself, and can be read as a separate entity by those who wish.To familiarize the reader with the region of southeastern Lake Michigan where the plant is situated, a description of the area's characteristics follows. 8 D.C.COOK hIUCLEAR PLANT IMPACT Depth Contours INTERVAL=2 hKTERS SX JOSEPH~12~4 DONALD C.COOK NUCLEAR PLANT FIGURE 3.Bathymetry of nearshore southeastern Lake Michigan.DESCRIPTION OF THE SOUTHEASTERN LAKE MICHIGAN REGION LAKE BOTTOM TOPOGRAPHY The topography of the lake bottom within the region of study slopes toward the northwest with greatest depths in excess of 38 m (Fig.3).At depths greater than 20 m, a series of ridges and runnels perpendicular to shore occurs (Rossmann 1975).

INTRODUCTION 9 The ridges consist of coarser sediments than the runnels (Rossmann and Seibel 1977).Near the shoreline, one ephemeral and two permanent sand bars exist (Seibel et al.1976).The ephemeral bar is located approximately 47 m from the shoreline. The inner and outer permanent bars are located 116 and 216 m from the shoreline, respectively. Water depths between the inner bar and shoreline and between the two permanent bars are 1.5 to 1.8 m and 3.7 to 4.0 m, respectively (Ayers and Huang 1967).The depth of water over the crest of the inner bar is 1.2 m and that over the outer bar is 2.6 m.SEDIMENTS Sediments vary from coarse to fine quartz sands at the shoreline to carbonate-rich very fine sands and silts offshore{Rossmann and Seibel 1977).The sediments are derived from sand dunes and unconsolidated bluffs along the shoreline (Hands 1970).The bluffs are clay-rich and contain carbonates (Rossmann 1975).During the early to mid-l970s, severe shoreline erosion occurred within the study area (Davis et al.1973, Tanner 1975).Material derived from this erosion as well as from rain runoff and stream transport is resuspended and sorted by waves and currents (Sly and Thomas 1974).Materials are finally deposited offshore where waves and cur-rents are incapable of transporting them farther.CURRENTS The major lake current within the region of Lake Michigan is called the Benton Harbor eddy.This eddy moves in a clockwise direction with currents moving south-westward along the shoreline (Ayers et al.1958, Bellaire 1964).Inshore of this eddy, a counterclockwise eddy with currents moving northeastward adjacent to the shore-line was tentatively identified by Ayers et al.{1958).Between May and November, current direction between the inner and outer sand bars is predominantly to the northwest. Direction was always to the north, north-west, or west between May and July regardless of wind direction (Ayers et al.1967).Beginning in August when the wind was brisk from northerly directions, currents moving in a southward direction began to occur with increased frequency. Smaller velocity and frequency of northerly winds were required to produce southward currents later in the fall.For the months of May through October in 1967, over 86Vo of the time current direction between the two bars was northward. Monthly mean current velocities ranged between 31.7 and 69.8 cm/sec.Inshore of the inner sand bar, current direction is controlled by wind direction. Water between the beach and inner bar is postulated to be water spilled over the inner bar during surf action.It is cut off from the main-lake circulation by the inner bar and is moved in a downwind direction (Ayers et al.1967).1 the 17 WAVES Wave observations have been reported by Liu and Housley (1969)for St.Joseph, Michigan (Fig.1).For the periods of 28 September 1966 to 16 December 1966 and 21 10 D.C.COOK NUCLEAR PLANT IMPACT September 1967 to 30 December 1967, maximum observed wave height was between 3.6 and 3.0 m.Maximum wave period was between 7 and 8 seconds.The most frequent wave height and period were 0.6 to 1.3 m and 5 to 6 seconds, respectively. Waves most often approached the shoreline from the northwest or southwest. LOCAL WINDS Based upon observations during 1967, surface winds adjacent to the shoreline are greatly influenced by a bluff of sand dunes 61 m from the shoreline that parallel the shore and run in a north-northeast to south-southwest direction (Ayers et al.1967).These dunes serve to protect nearshore waters from winds from north-northeast, around through east and south, to south-southwest. They also channel winds from northerly and southerly directions into a NNE-SSW direction. Between May and mid-November the most often recorded winds were from the NNE (14.2o/o of the time)and SSW (22.6o/o of the time).Average wind velocity ranged from 9 km/h in June to 16 km/h in November.General prevailing winds for the region are from westerly directions throughout the year.THERMAL CYCLE OF WATER COLUMN The exact time of occurrence of various events in the thermal cycle is dependent upon the rate at which the lake warms as well as the severity of a winter.Warming of nearshore waters begins in spring with snowmelt and spring rains.As lake waters warm, a nearshore thermal bar develops which is delineated by the 4'C isotherm.As the lake continues to warm, the thermal bar progresses farther offshore.The ther-mal bar was usually found within the study area during April.Eventually, the thermal bar moves out of the study area and a thermally stratified water column develops.This usually occurs in May or very early June.Thermal stratification usually continues into and occasionally through November.For the calendar year, surface water temperatures range between I.l and 26.9'C, while those of the hypolimnion range between 5.0 and 6.5'C.During stratification, upwellings of hypolimnion water with temperatures as low as 6'C are common along the shoreline. Except during upwellings, water depths ((45.m)in the study area were only great enough to permit sampling hypolimnetic water at those stations farthest offshore.LITERATURE CITED Ayers, J.C., D.C.Chandler, G.H.Lauff, C.F.Powers, and E.B.Henson.1958.Currenls and wafer masses of Lake Michigan.Publ.No.3, Great Lakes Res.Div., Univ.Michigan, 116 pp.Ayers, J.C., and J.C.K.Huang.1967.Ben(on Harbor power plant studies, Part I.General studies.Spec.Rep.No.44, Great Lakes Res.Div., Univ.Michigan, 37 pp.Ayers, J.C., A.E.Strong, C.F.Powers, and R.Rossmann.1967.Benton Harbor power plant studies, Part II.Studies of local winds and alongshore currents.Spec.Rep.No.44, Great Lakes Res.Div., Univ.Michigan, 20 pp.

INTRODUCTION cI I n st re te).t, m id>e~n n af rs Xs Bellaire, F.R.1964.A comparison of methods of current determinations. In Proc.7(h Conf.Great Lakes Res., pp.171-178 Great Lakes Res.Div., Univ.Michigan.Davis, R.A., E.Seibel, and W.T.Fox.1973.Coastal erosion in eastern Lake Michigan-causes and effects.In Proc.16th Conf.Great Lakes Res., pp.404-412.Internat.Assoc.Great Lakes Res.Hands, E.B.1970.A geomorphic map of Lake Michigan shoreline. In Proc.16th Conf.Great Lakes Res., pp.250-265.Internat.Assoc.Great Lakes Res.Indiana&Michigan Electric Company and Indiana&Michigan Power Company.1973.Final environmental statement related to operation of Donald C.Cook Nuclear Plant Units I and 2.Liu, P.D., and J.G.Housley.1969.Visual wave observations along'the Lake Michigan shore.In Proc.12th Conf.Great Lakes Res., pp.608-621.Internat.Assoc.Great Lakes Res.Rossmann, R.1975.Chemisrry of nearshore surficial sediments from southeastern Lake Michigan.Spec.Rep.No.57, Great Lakes Res.Div., Univ.Michigan, 62 pp.Rossmann, R., and E.Seibel.1977.Surficial sediment redistribution by wave energy: element-grain size relationships. J.Great Lakes Res.3:258-262. Seibel, E., C.T.Carlson, and J.W.Maresca, Jr.1976.Ice ridge formation: proba-ble control by nearshore bars.J.Great Lakes Res.2:384-392. Sly, P.G., and R.L.Thomas.1974.Review of geological research as it relates to an understanding of Great Lakes limnology. J.Fish Res.Board Can.31:795-825. Tanner, F.W.1975.Beach processes, Berrien County, Michigan.J.Great Lakes Res.I:171-178..I e 1, n y 15 SEE INSTRUCTIONS ON REVERSE SIDE SECTION I EPA I.D.NUMBER M I D 0 9 6 4 7 6 1 PERMIT NUMBER~M100 05827'APPLICATION FOR DISCHARGE PERMIT IS: tsm[F I TION EXI TING hEM ItKREASED USE RE ISSIAIICE 0 D H ITEM 1 PHYSICAL LOCATION ADDRESS C.PLAIITOR FACILITY D C C 0 0 K P L A N T D.TYPE CF FACILITY S T M E L E C T R Es STANDARD INDUSTRI)[L C[ASSIF ICATION (REFER TO TABLE II)G E N~qg f e STREET tlHKR G~STREET BVK COOK P LAC E AP~~~~~'~~'ER INDIANA M I C I GAN POWER COMP NY B.DIV.i[NREAU N A AND INFORMATION Hs CllY[[A%BRI DGMAN J s TCWNSHIP LAKE Le NA%OF AUDCRIZED CONTACT PERSON Ml K>>CXNIY (REFER TO TABLE I)BERRIEN Hs TITLE I~ZIP CODE 491 06 CO.IAPBER~>DONALDLBAKR O.AXRESS (IF DIFFERENT FR[V[ABOVE)NV AFFAIRS I R 2 1 9~42~21 Ps CITY RVK FORT WAY E POBOX60 Oe STATE Re ZIP GXK 468 01 5~lYPE OF TREATMENT FACILITY (REFER TO TABLE ll)~lL~ltr~2K~3A~4G l'PROGRAM FOR EFFECTIVE RES[DIALS HANAGE%W DATE SLBHITTED YES CI ta HN.A.DATE ltPLEPENTED U>>BACK~POwER QXRCE YES M N Ae Vs POLLUTION INCIDENT PREVENTION PLAN DATE SINVIITTED X VES tD N A DATE[~[TED 1 1/1 5/92 Me tltVIER OF EIVNJIVEES X.TYPE OF DISCIARGE~~Q Qx Ye DO YOU HAVE A CERTIFIED OPERATOR?El YES CI te D.M.FITZGERALD ee 4~30 9~70~48 0 2 ITEM 2 MAILING ADDRESS OF APPLICANT As W%RCMENGE Be t4VK IND I ANAMI CHI GAN POWER CMP C STREET,AXRESS CR POST OFFICE BOX P BO60 De CllY t4V%FORTWAYNE PEOulDEO Stctthrttt2E Ee STATE F>>ZIP CODE I.the dDDI[cant. cettlly under penalty ot Iav that I have personalty erdhlned and dm tdml tlat'lth the Intormatlon submitted In this dDDtlcatt, and al I attachments ano that, based on my Inoulry ot those Indlvldudts Immediately respon51ble tot obtalnlng the Intormatlon, I believe ttdt tte lhtormatlon Is true, accurate and complete.I dm dvare that there dre 5[obit[cant petldl ties'tor 5ubmlttlng tdt5e Intotmdtloh Ihcludlflo DD55[bi I Ity ot tine dno Imprlsotvsent. SIGNATURE OF APPLICANT 3 ao R4-SIGNATURE OF LOCAL GOVERNMENTAL REPRESENTATIVE (SEE NOTE ON REVERSE SIDE)R-C.MENGE.PRESIDENT T[TLEI 15 SEE INSTRUCTIONS ON REVERSE SIDE SECTION I RMIT~I 0 ITEM 3 SOURCE OF WATER SUPPLY A MW IC I?AL 3.SDRFiVE nATER It>>AXE C~-FIXATE nEU.O.CT>IER NAME CF ITATERHAV.M~>Tl TY;>AX.).MAX.)Door Fu L A K E T 0 N SIHI I P NA I NI A r~>C JS/SAY C'LLOlJS/OAY I QALLr Its/r~y L A K E IM I C H II G A N I ITEiVI 4 L>>tITI>Y IŽAX.)-maSS'ATER (IIICLUOrrts CO ITACT:OOLIlJO n'ER):!jAIJTITY>MAX.)B.'CttCOIITACT COOL I tlG'nATER YTITY (uAX,)GAL>>XIS/CAY 6 3>4 4 0 0 OAI>ctq/n~y 2>6 4 2 1 1 2 0 0 0 oAuotB/~y FACILITY WATER USAGE C.SARI TARY'>JATER D O TIER AJAttTI TY I>SAX.)OUAttT TY (MAX.)F I 6 0 0 0 0 CAL>>xts/BAY P R OTE.CT IO N WIT 3 6 0 0 0 0 0 oALLctts/BAy lTEM 5 CRITICAL MATERIALS&PRIORITY POLLU TANTS CC IJJ~I MJ ETI I E;,~E OF SUBSTAtJCE PARAMETER IAPZER CUAIITI Ty NA%OF SUBSTANCE PARA%TER tlH3ER CUANTI TY HYDRAZINE A ueous 0 03020 12 47o o<~ivy SODIUM HYPOCHLORITE (12%)C LASS 01 4 ITS 6489 4 USED STORED PRODUCED REFER TO TABLES IVS>V ttA"E OF SUBSTAlJCE PARA%TER tlPBER SIPUIT I TY MJ RE I TER t>Lt%ER'U>UIT I TY:~OF SUBSTAIJCE XYLENE TOLUENE Otl 3>3 02 0 7 1 6 3 T~/YEAR 0 01088,8<tg Ts 6 9 9~1/YEAR JlHlL'iCQE I POUNDS 2 GALLONS 3 CUBIC YARDS 4 TONS l>J IO I MJ I I:RUE OF it>MTAIJCE P~'%ac;R:AtSER QUAttt I ly ttŽE OF SUBSTAttcE PARE>E.R IAPBER rRUAIIT I>Y i""E CF SLBSTAIJCE DARAt E TER:lt S>ER C LASS 0 2 HYDRO UINONE ITS IL/ve MERCURY+ITS/YEAR UN I TS LLI/YEAR LITHIUM as LITHIUM HYDROXIDE 17 ")$<<~a t 3<<"a 3<<>>:I'/>>a><<r~I 3'5<<a Qt sa<<~r<<03<<II<<I$ 5 an a3va 3~<<'r I~e<<5$, n g ru)3<<e, aron ie5$e>><<3 er I a=Iver, cr<<ne Itv a~v ra~~7"~I'c 3>>3 e 5>>>>>p 4 ae r<<3'r'3 er e>>$3 t<<a>>3 I 3 ara 3>>l n I a<<5<<<<a r<<<<a I I 5T"louhTS f<<ater to oe u5ec>or var Icus ur cses 351 o"ccess Tater-see G>cssarv!Or ceflnltrcr:ace -'-).'~nccntact"colin>><<hater -see Gl=ssarv 3" Ta'I-:Tlc":oace C.).l<<nlta>>v aster<<ster]sea rar I ras I~r.5a$: a...I rat5, 3~na5, Ir<<ars.ster ls"rs-<<sea'cr 3 e carcase 3-r-"e 5 a a er 13 5'.5ecr ere)r.3ec'nr 3 e 3--" 5 o-"er C.rccses,'"crea<<e-"e vo>ure i<<5.es',<<,ar ,se e'r e<<3 e 3 ,.:'-3r3a.=.qi)-e'3 a I'-131>V~sar 33 rnacnta.:31'-3*3-er:-=en 3$$$$<<a e , a: 3>>'a ar , e I3 e I 3$5<<e~Inoul c eru t>>ls aoollcaTlcn ~: v CI'fereqce 1-ese-!Sls 3 cul Ce ev>>Iainec rr sr 3 acqea 3 eet cf ITiv 5 Tr"ATE~I Au5 O'A)O'RIGIDITY ~1>>UT3~5 r ST 3II Cne)aal 3COSTanceS <<nlCO are I-"I n)C3-'3,>>.'-IC31"sterl3IS cec)Stn"!Cle'>33ce"'>>a/Cr..8.=33'5 ar ICr:tV=O>1utant I.est taole V (oace 7)3'rat sre curren.>V<<sea.storea~cr oroaucea Ov Tn)5>aali II Tv. SEE INSTRUCTIONS ON REVERSE SIDE SECTION I PERMIT~qZ pppg827 NUMBER ITEM 3 SOURCE OF WATER SUPPLY A r i'TNIC IPAL Br SURFACE rrATER ItateE Cr PRIVATE'rrEIL D.DINER r LrAra tra'~'5 CF WATERWAY alTY (tAx.)ITV ttrAX,)carr Fy ITEiVI 4 OUAtaITY (t AX.)A.PROCESS RATER (ItCLUDltJG COtaACT NS NATER)Tv lt 3~NCttCOtaACT COOLItlG WATER".UAtat Tv (we.)C.SANITARY'HATER GAuDttS/DAv GALIDNS/DAY FACILITY WATER USAGE ITEM 5 CR IT ICA L MATERIALS PRIORITY I POLLUTANTS USED STORED D 0 TIER tlVK CF SUMTAtCE PARAIKTER R!%ER OUVallY N4%OF SUBSTANCE PARAtETER t AMKR OUANTllv NVK OF QSSTANCE nuamt Tv (we.)SP OUrVa TV (We.)Mercuric Nitrate Cadmium CL Ass 01 3 Eth lene Dichloride WITS L1J/YEAR Wl TS~1/YEAR PRODUCED REFER TO TABLES IV Sr V JLHlLiCQE I POUNDS 2 GALLONS 3 CUBIC YARDS 4 TONS I TY NAtE OF QBSTANCE PAPA"ETER lAtSER tgrE OF QrMTAttCE PAIUVETER tttteER OUAtallv tA%OF SIISTANCE PARA%TER tlHKR OUANl'I TY le%OF SIISTAtCE 00 107 062 26~T Chloroform ppp 6766 3 WITS/VEAR Lead 0 13322 14 W I'TS 4 4 QJ/YEAR CLSS 019 WITS 3 0 0~1/YEAR Triar l Phos hate Ester EHC*CL S S 084 WITS 2 1 0 0 0~1/YEAR Asbestos*Hydraulic Fluid 17 f~4 I~I I ls 4~4 I<<I'~~4*~I r\5)1~~~3 4~'1<<OTO>>SO 9~'I>>%1'4~~5~I 5%43vr34A I IJI l~5)ve1"" I>>4r I" 9 assi"vc Ie'I II I Ve>>9'al'a r>>~I~1 4%~4 l j%I 9 f 1%4>>I:st 5-Curts Ct<<Oter-::e.SeC acr rsrl:5 TvrseseS 51 c.ccess Oi-er-595.:acssarv tc ss"-'-'co: ce 5 l!':cnccc-ocT ".call"., dater-See Glcssarv'cr seflnltlcc lsa>>te 54 l I'~ea'r" 595 9!l 5 5 1<" 5'<<4 5~5.4'""5-.595'5-:-e:;rccse 1-c--9 sa>>e'll'al 1 4 39 l'5" 5%l" 455*d>>4>>'5 5e 9~le~4 9 4>>r 595 9 1~1 a')4>>')I'(le>>]43 15 4'5 4'Clc 9~5~al 5 4>>a!I.'1 aI'r"aq a 9 Sse I 5~~5%ed t 5T 3'.Ml ol 3 5.Ss ala~of'9""1 11'l 1'lterr"5+is-9".".le l",'.: Sce.'".4a/cr.~'I"IB~355 I."I.I"..I.I.'5'I=.=-5 9"Icrltv SEE INSTRUCTIONS ON REVERSE SIDE SECTION I PERMIT-~HI 0005827 ITEM 3 SOURCE OF WATER SUPPLY A~WNICIPAL S.SURFACE HATER INTAXE C~PRIVATE'nELL D.OTHER~m TV I"'tA'B CF WLTERHAV rOAt(TITY (FAX.)".ttAt(T I TV (~AX.)ITEM 4 FAG I LIT Y WATER USAGE ITEM 5 C o SAN!TART HATER De OTIER OUANTI TY (~)t~'6 OF S(MTANCE OUANT TV (t(AX.)I OUANTITY O(IAt(TITY (tAX.)A.PRXESS HATER'(IttCLUDI%COt(TACT COOL(ta HATER).UANTITV (>AX~8~tQNCOt(TACT CCCEIt6 HATER~VTITY (FAX,)0-Dichlorobenzene 000 955 01*OAuONS/DAV CALLO(IS/DAV acus(S/DAY CRITICAL MATERIALS PRIORITY POLLUTANTS USED STORED PRODUCED REFER TO TABLES Ivav CC wc@t X+C CC UJ 6)I CC~@ted NA%OF SUBSTANCE PARAIKTER MtBER ouNITIlY OUMIII TV NA%OF S(BSTANCE PARA%TER hVSER OUANTt TY NAtE OF SUBSTAtCE Antimon Potassium Tartrate Pentachloro henol LS ITS LLI/YEAR C L Qt(TS M/YEAR Tri hen 1 hos hate EHC*ut(Ts 4~1/YEAR Pol chlorinated Bi hen ls PCB I POUNDS 2 GALLONS 3 CUBIC YARDS 4 TONS CC Ul lA NA%OF S(BSTANCE CLA SSO 84 Trix len 1 hos hate EHC*X/YEAR CC Ql lO~C OWP llY t(A%OF S(BSTAN:E Zinc CLA SS08 4 u(ITs 2 1 0 0 0~1/YEAR PARA%TER tAPBER I OOANTITV CLAS S0 2 7 WITS 27 00*Hydraulic Fluid ~Q~"Is'-r.-<<Cui-es 4nfo~aticn aocut 7-e<<ater)coiv-".<<5~)oil I)V,-e': "4(-v'5<<ate<<.sace.-'*-n s sec 5-r<<3-r)r""""e"---'S""'I:tv'<<el~)ls~f)(<<~"~($'l"-, u)T I(ivgc<q 8p g:4',(<<vlc 5'~l*<<<<<<I'e<<e3ve>~g 4 c<<<<roar<<a(if<<55("ace)<<I<<~uc'ate, (es Ie<<<<e 4 I e~(e 45 i~pP 4<<<<<<ater<<<<<<~~<<I<<<<<<t I 5 4~)<<<<5'<<ate<<~)e<<'S<<t<<<<<<S a<<~>~3C~>r<<r<<S 0 5 4 5<<<<~~<<-aron a(ver, cr tne Gitv of M(I IOCnc.:5t)"cunt)ct ater-." Ce usec'o(v3rlous curccses 35 crccess na<<er-see Giossarv for ceflni-Icn (cace 38).'.once;-act co(ing<<ate>-see Glossary'cr Ceflnlticn (cage 38).:anltarv x!ter-Aeter useo for domestic curooses(e.o.,-oilet5, Sinks.)rovers.<<ater 75'r)t vSec far cne curoOSe ano 7-e 5(74e<<ater iS 5.3Seouent:V.Se'Cr 5-e cr-cre 7"er:.r)CSeS.'-)(ca e"e volute)<<)]it<<5 Qsi)ol jse cef Pe<<<<<<<<e<<t)c/cr.'c"ar e.Tcr<<<<5 T'e.'<<<<5 I I I 4 v csee)5~rc ntact 3-e"!"c-en)s: c ss<<ate(, T-e C.ant'-.:-<<a er-,'ven>>-cuic:e'-)ic)-ec)5:-ccess*a.er.<<<<C)nOu4C ao 34 tne terai'-em.'.Cnv ci"trance ir--ese-)tais 5-Culc ce<<xclalnec I")n<<7-)Csea Sneer of-<<IS accliC TIOn.ITQ4 8!sT)I I ccemical sucstances <<nice are ln ync<<l 73n 5 rltlcal"aterials>eels)a<<able Iy (cace 8)anclcr.~.=ca'5 orlorltv<t Table V laaae 7)that 6 e i e i 7,~, 0 I D i~i tili SEE INSTRUCTIONS ON REVERSE SIDE SECTION I PERMIT M NI 0005827 I'T E M A, rrrrcrprL3 B r StttFACE HA'fER INfAKE SOURCE OF WATER SUPPLY C~PRIVATE H'ELL Dr OTHER ltA%CF WATERWAY (uAX)OUAttfl Tv (we.)SP~DAY ITEM 4 FACILITY WATER USAGE ITEM 5.CR ITICA L MATERIALS PRIORITY POLLUTANTS USED STORED PRODUCED REFER TO TABLES IVBr V 1 POUNDS 2 GALLONS 3 CUBIC YARDS 4 TONS tFtE OF SUBSTAttCE Tv (we.)CL'rrr Crt NrrPK OF SLSSTANCE PARAtETER tttSER OUANfllY NA%OF SUBSTANCE PPJJtETER MtSER OUANTllY NAPE OF SIBSTANCE PARt4%TER tAtSER OUANTllY NAPE OF SUBSTAttCE PARA%TER t AteER CC rrr Ih r X OUANTITf NAIE OF S%STANCE PARAMETER IAAF rrr rO Z OUANfllY oUANrITY (we.)Ar PROCESS HATER IIIICUSIt6 COt(TACT aOLIto HATER)CUANTI Tv (we.B.ICNCONTACT COOL INS WATER OUANTITY (we.)C~SANITARY HATER OUAttf I TY (we.)D.OTHER OAuDNS/DAY oAutm/DAY OAuDNS/DAY OAuDttS/DAY Benzene Gasoline 00071432 7 0 0 0 Q/YEAR Toluene Gasoline 0 01088 83 UNI TS 7 0 0 0~1/YEAR X lene Gasoline 0133 0 207 UNITS L1J/YEAR UNITS~/YEAR UNI TS~/YEAR UNITS LJ/YEAR HAIK OF SISSTAtCE PARA%TER IAt%ER r OUUIfllY UN I TS LJ/YEAR ~~cr=gtCTIrhIS PCR C vPLc.I~cE.IC'I I ITEMS 5, 4, AhO 5 This.'Orm reoui, es it.atl n abcur 5<<3~er S" pl'a 5 g I a y orle>>l-v col lu.ants ASed, Stored, cr produces at-nfs'llitv.~ewe 3C'l V'S<<are>>Sade.SnC C-'-iCSI-3<<e>>ials and 3E,'.llT.g.e5 i5 3>>ew cr not prevtcus<v cer" i ec oil i tv,-nen IT Uv8ER"AM E cCU'O C'I-""-nr v I,'W.Irgl';G leave bianx ar-3 nurcec<>c't<<ATEn SLppiv List sli<<ater supplies used."e vol<<e mav pe estimated~roy3<<ater supplv>>e er>>eacings or'ran piii inc S.are"ants 'ran 3 ware 5<<pl I Atlll,v.Ia water is>>.eterec, es, l>>are yrx pump apacitv.aghere 3 ns e es a%vireo, enter"3>>e"<<3 er 5ucply;uud Lake, Huron River, or the CIty ot IAII lpono.ITEM 4 PACILITy WATER iJSAGE'ist amounts ot water ro be used for various purposes as: process gfater-See Glossary for definition lpage 48)..'lonccntact Cooling Water-See Glossary tor definition <page 48).Sanitary Water-Water used tor dcmestic purposes;e.g., toilets, sinxs, sho ers.~f<<ater iS.IrSt uSed fcr Cne purpOSe and the Same water iS SupSeduently Sed aar Cne Cr are Other purpOSeS, indlCate the Vclu>>e er cav ot rhe Inst ce5icnarec use petore reatrent snc/og discharge.-cr Rxa>>cie, ig<<ater l5 inltlallv used as noncontact CCOlln"*ater no hen 3S->>"CeSS~ater, tne Suan l V Cf arer~iVen 5"Ould be inoioated SS OrOCeSS water.The total of item 4 should ecual the total of item 5.Any dlfterence in these rctals should be exp laineo in an attached sheet ot this appllcarlon. ITEM 5 CRITICAL MATERIALS AWO PRIORITY POLLUTAiITS USED.TCREO.noCOUCEO'St all ChemiCal SubatanCeS whiCh are In MIChlgan'5 CrltlCal uaterlalS OegISter Table IV IP8ge 6)and/Or U.S.EPA'S PrlOrlty hilt tlitthi y(egeyitht e etiy d,e d, g a aey;hi~tediiity. SEE INSTRUCTIONS ON REVERSE SIDE SECTION I PERMIT~~MI 0005827TEM 6 DESCRIPTION A>>:gyIDE A PRIEF DESCRIPTIQN 4<ING lbE'<<ATER~'P WMI>>(TCUR FACILlTY RCH INTAKE>>Q i NATE.-~'.PA>>,l,'.5 ~iiRISUTING>>(ASic>>(AicR>> IllCU<<>>IIIG FHKESS AI<<>>FACDUCTICN AREASi 5>><<iITARY FL>>'.>>>>(5>> CQQLING'HATER>>AND STQAATER RVCFF~,QU<<AY SAQP SINILAR CPERATICNS INTO A SINGLE UNIT>>TNE WATER BALA(iCE SHDULO QCw AVERAGE FLQWS~SAW ALL SIGNIFICANT QSSFS:F<<ATER~F>>~CQUCTS, APQSP(>>ERE>> 4(D DISCNARGE~YQU SNQLLJ USE AC~>><<EAS(A(EVENTS '~NEVER AVAIlAELEI QTI>>ERNISE USE YQ(R SEST ASTI"ATE.[SEE ATTACHED DESCRIPTION] ANO DIAGRAM ~<<I 85)<<" u 8 a<<<<t)Cili)y'rt"" 3<<8,'ISC>)r-* ~<<r"ey'u I a~tr eave<<I'~J~'t u<<~-i r~-.-i-go'85 8 8<<"<<'8 I~V o<<J<<8)ve SC"st'"8)"<<)5O" V<<3<<'t'sc.Ion)<<8 Sct'<<,)r~<<.,3<<58<<8 8<<o<<t-<<.)r" 3-,<<.-ersri n5'-~~8<<8<<8-e,o olin),)<<s.)I-'-Ior'i<<8)c 3)<<)ec-!33'33'" t cr'ce<<<<cvst 3 c)'.'0-8 ts t.8<<8 8 3 3'5~8<<" 3 Cf 3)u...'Si C"'".4 3.'.-Sore.8" 5"8>>")3 Se, 3.<<Ocur*8CI" as<<8 8 3 5 35 3.v 8.IV er'5'C'Cut 3 8"8<<8<<)I"YCt'tl.<<5~-)5 e 5-83~"o<<s-nro'."n 3:~""'"er.-8-8)t"~s<<curse ser-'es---e sc--r, as<<st;cce<<."e-<<3;ec<<8 er I's<<5<<M<8 8!arl':er-8-anrote<<8<<e'-sot<<<<tlngles <<sn ccn-ac-ol<<g 8~8r o""8 5 rtc'-e."is con~--leo<<sve<<'5:isc-srsec -".--8 B.cv)iver."e si.cce'<<st"-e clari"er-oes ro!rscu~"'-8"<<ere'?5 Ce<<ave-eo.-8 3.Cce'S-e<<-S.er Calcium Chloride Sulfuric Acid 1 Lime I Polymer Plating Wastewater 70.000 Gal ion Tank Acidification Iieutral ization'locculation Ba tCh Outtlps~0ump Tank.Sludge nickener Clarifier Non-contact Cooling water Calcium Chloride yacuum Filter Water Sulfuric Acid I.ime Landfill Gondola Sludge Ifanho I e Buck Rive.-".:e.'-;...Ser<<C<<h, an'C-.85 5leeve 383<<":5'Ct'u!Cr"C-Ive a<<c<<<<uc>>encineS.-"Cauc lcn IS-SeS.Vo<<)*-Ce-5--""8"'-<<'r 5---SSe-I 5: 5~-OncanieC Sv ei<<C::cser.-<<)-5 ss'n--cc 5")" etec---.'.-)ce)no.o<<'-g 3 er 3~-srer 3).ence sno ic'v e-ei ing-e<<al'"-.)ovoer'cr.-8 lscct c)hase ccnsis:s sf scnering"e~it:e"eral oo<<cer 3 Scil t 3 881 SV Oa))ihc<<8<<0 5 o<<tv"<<'ur<<aceS.ta<<er.Sec-" COI she Svrlc ccnssi.u)85 Ctt<<<<8 8<<)83<<l 5 ar<<8"'3<<3<<<<i<<~~<<8)<<5 set'"<<)58, 55 eatlncs~8Cei re)ic<<81 5.t~8 Sr'8C..338 8>>I 3 8."8 tei<<al"I<<<< sear'8OOIT shc I 8<<ei'Ie 8 3 n C<<aC)~<<,=:nSe a-er:<<lore )<<C sf)en-<<8 tar icuS: 33',-g 338<<sions cons)i u.es 3-e)recess<<).er.Municipal Water Supply Sanitary Facility 30,000 gpd Nunicipal Treatment Stripe i.ine 295.000 gpd Cooling lfater 250.000 gpd iiaste Treatment Plant 45,000 gpd Buck Rive Powder Nfg.4.000 gpd Plating Process 40,000 gpd 20 SECTION I, ITEM 6, SUBPART A Cont'd OUTFALL DESCRIPTIONS OUTFALL 001-Unit 1 Circulatin Water Dischar e Outfall 001 is a non-contact cooling water discharge. Most of the non-contact cooling water is used to condense the steam exhausting from the steam driven turbines.The condenser cooling water is drawn from Lake Michigan, screened to remove large particles entrained in the water, routed through the Unit 1 condensers and then discharged to Lake Michigan.Outfall 001 also includes Steam Generator Blowdown, Plant Heating Boiler (described later as internal Outfalls OOA, OOB and OOC respectively), and the Reverse Osmosis (RO)system (described on page 10).Outfall 001 also contains the effluent flow from the Essential Service Water (ESW)system, Non-Essential Service Water (NESW)system, and monitor tank releases.ESW (20,000 GPM maximum)is Lake Michigan water that is used to provide cooling to Nuclear Regulatory Commission (NRC)defined safety-related equipment and as an emergency backup water supply.NESW (9000 GPM maximum)is also Lake Michigan water used for non-contact cooling, as a source of water for the demineralized makeup system, and to supply water for NRC defined non-safety related equipment. Monitor tank releases (-20,000 gallons per event)are regulated by the NRC and consist of waste water generated within the Auxiliary Building that has been processed prior to batch discharge. The non-contact cooling water for the circulating water system, the ESW system and the NESW system is.treated for biological control using liquid sodium hypochlorite, with treatments usually beginning in May and terminating in November, depending on Lake Michigan temperatures. The biocide is added at the intake forebay and the average residual measured in the discharge is maintained at less than 0.2 mg/l at Outfall 001.The treatments last for no more than 160 minutes per day.If continuous chlorination is utilized, the residual measured in the discharge is maintained at less than 0.036 mg/l at Outfall 001. This same water is periodically treated using a non-oxidizing biocide to eradicate the cooling systems of zebra mussels.The biocides we are considering (Betz CT-1, Betz CT-2, Betz CT-4, Calgon H-130M, and Nalco 9210)are all polyquats which will be detoxified, as required using bentonite clay to meet water quality based effluent limits.The treatments are directed to the critical plant systems from the intake structures located about one-half mile out in Lake Michigan through the entire plant cooling system, including the ESW and NESW systems.Systems are treated dependent upon zebra mussel infestation. Concentrations and chemical feed points are chosen to minimize the amount of biocide required and to maximize the treatment program.The systems may be treated at the same time or individually to allow more efficient use of chemicals. We plan to treat all systems within the plant a maximum of twice per year (six applications per year total)to assure safe operation of the nuclear generating units.The current NPDES permit includes the use of sodium bromide and sodium hypochlorite solutions for treatment of the circulating water systems.These solutions, which are the major constituents of many proprietary mixtures such as Nalco Acti-Brom, are presently being considered as the basis of the Cook Nuclear Plant's strategic plan to control zebra mussels.Effective use of these oxidizing biocides are expected to reduce the frequency of non-oxidizing biocide treatments. See Attachment 3 of the cover letter for more details regarding our future zebra mussel control strategy.The monitor tanks receive treated water from the radioactive waste removal system.One system handles the waste for Units 1 and 2 and the Auxiliary Building.This system treats wastes generated from the reactor coolant pump seal leakoffs, the refueling cavity water, equipment leaks, floor drains, valve stem leakoffs, waste sample solutions and laboratory wastes from the radiochemistry analysis in the hot chemical laboratory, system equipment drains, non-contact cooling water and decontamination processes. The wastes are collected in one of several tanks and treated when enough water is collected. The treatment utilizes either an evaporator system or a demineralizer system to remove radioactive contaminants. The treated water is accumulated in the monitor tanks and sampled to ensure the waste meets the Nuclear Regulatory Commission radiological requirements prior to being discharged into the circulating water system.Periodically, due to equipment leaks and/or system upsets, a waste stream is generated that contains radioactively contaminated ethylene glycol and water.This water is processed on-site prior to being released to Outfalls 001, 002 or 003.Sulfur hexafluoride gas (SF6)is utilized in the non.-contact cooling water systems at the plant to detect leaks in various components such as the condensers. The gas is injected in the cooling water stream and discharged to Outfalls 001, 002 or 003 at less than 54 ul/L.During upset conditions it is possible to overflow the contents of the Turbine Room Sump (see Outfall OOD)to Outfalls 001, 002 and/or 003 if the flow path to the on-site absorption pond cannot be used.0 t n W ter'sc ar e Outfall 002 is a non-contact cooling water discharge. Most of the non-contact cooling water is used to condense the steam exhausting from the steam driven turbines.The condenser cooling water is drawn from Lake Michigan, screened to remove large particles entrained in the water, routed through the Unit 2 condensers and then discharged to Lake Michigan.Outfall 002 also includes Steam Generator Blowdown, Plant Heating Boiler (described later as internal Outfalls OOA, OOB and 00C respectively), and the Reverse Osmosis (RO)system (described on page.10).Outfall 002 also contains the effluent flow from the Essential Service Water (ESW)system, Non-Essential Service Water (NESW)system, and monitor tank releases.ESW (20,000 GPM maximum)is Lake Michigan water that is used to provide cooling to Nuclear Regulatory Commission (NRC)defined safety-related equipment and as an emergency backup water supply. NESW (9000 GPM maximum)is also Lake Michigan water used for non-contact cooling, as a source of water for the demineralized makeup system, and to supply water for NRC defined non-safety related equipment. Monitor tank releases (-20,000 gallons per event)are regulated by the NRC and consist of waste water generated within the Auxiliary Building that has been processed prior to the batch discharge. The non-contact cooling water for the circulating water system, the ESW system and the NESW system is treated for biological control using liquid sodium hypochlorite, with treatments usually beginning in May and terminating in November, depending on Lake Michigan temperatures. The biocide is added at the intake forebay and the average residual measured in the discharge is maintained at less than 0.2 mg/l at Outfall 002.The treatments last for no more than 160 minutes per day.If continuous chlorination is utilized, the residual measured in the discharge is maintained at less than 0.036 mg/l at Outfall 002.This same water is periodically treated using a non-oxidizing biocide to eradicate the cooling systems of zebra mussels.The biocides we are considering (Betz CT-1, Betz CT-2, Betz CT-4, Calgon H-130M, and Nalco 9210)are all polyquats which will be detoxified as required, using bentonite clay to meet water quality based effluent limits.The treatments are directed to the critical systems from the intake structures located about one-half mile out in Lake Michigan through the entire plant cooling system, including the ESW and NESW systems.Systems are treated dependent upon zebra mussel infestation. Concentrations and chemical feed points are chosen to minimize the amount of biocide required and to maximize the treatment program.The systems may be treated at the same time or individually to allow more efficient use of chemicals. We plan to treat all systems within the plant a maximum of twice per year (six applications per year total)to assure safe operation of the nuclear generating units.The current NPDES permit includes the use of sodium bromide and sodium hypochlorite solutions for treatment of the circulating water systems. These solutions, which are the major constituents of many proprietary mixtures such as Nalco Acti-Brom, are presently being considered as the basis of the Cook Nuclear Plant's strategic plan to control zebra mussels.Effective use of these~xidizing biocides are expected to reduce the frequency of non-oxidizing biocide treatments. See Attachment 3 of the cover letter for more details regarding our future zebra mussel control strategy.The monitor tanks receive treated water from the radioactive waste removal system.One system handles the waste for Units 1 and 2 and the Auxiliary Building.This system treats wastes generated from the reactor coolant pump seal leakoffs, the refueling cavity water, equipment leaks, floor drains, valve stem leakoffs, waste sample solutions and laboratory wastes from the radiochemistry analysis in the hot chemical laboratory, system equipment drains, non-contact cooling water and decontamination processes. The waste is'collected in one of several tanks and treated when enough water is collected. The treatment utilizes either an evaporator system or a demineralizer system to remove radioactive contaminants. The treated water is accumulated in the monitor tanks and sampled to ensure the waste meets the Nuclear Regulatory Commission radiological requirements prior to being discharged into the circulating water system.Periodically, due to equipment leaks and/or system upsets, a waste stream is generated that contains radioactively contaminated ethylene glycol and water.This water is processed on-site prior to being released to~Outfalls 001, 002 or 003.Sulfur hexafluoride gas (SF6)is utilized in the non-contact cooling water systems at the plant to detect leaks in various components such as the condensers. The gas is injected in the cooling water stream and discharged to Outfalls 001, 002 or 003 at less than 54 ul/L.During upset conditions it is possible to overflow the contents of the Turbine Room Sump (see Outfall OOD)to Outfalls 001, 002 and/or 003 if the flow path to the on-site absorption pond cannot be used. OUTFALL 003-Deicin Dischar e Outfall 003 is a deicing discharge which is used on a limited basis.A portion of the flow from Outfall 001 and/or Outfall 002 is directed through the center intake tunnel to temper the intake water and prevent ice buildup on the intake structures which would restrict intake flow.Use of this discharge is generally only required during the period from December through April depending on water temperatures and ice buildup along the shores of Lake Michigan.The chemical constituent of Outfall 003 is the same as Outfalls 001 and 002.OUTFALL OOA-Unit 1 Steam Generator Blowdown The steam generators require ultra high purity water for operation. Makeup water used in the steam generators is withdrawn from the intake forebay (or from Lake Township water supply)and essentially all natural impurities are removed through sedimentation, filtration, reverse osmosis, and demineralization. Periodically, impurities enter the steam generators through system corrosion transport mechanisms, the makeup water, or system upsets (such as condenser leakage)and must be removed to protect the steam turbines and heat transfer surfaces of the steam generators. The impurities are removed by draining a portion of the water from.the steam generators. In the steam generator, steam is separated from the water, further heated, and then routed to the turbines.When the steam separates from the water, the impurities remain in the water, concentrating in the steam generator. Blowdown consists of two forms, a liquid portion (700 GPM maximum)and a wet steam portion which is exhausted to the atmosphere. The liquid portion of the steam generator blowdown is discharged to the screenhouse forebay either directly, or after processing through mixed bed demineralizers. Impurities in this discharge may consist of insoluble iron and copper and at times, impurities from the cooling water (Lake Michigan)used to cool the condensers. Steam generator additives consist of ammonia and/or monoethanolamine (ETA)for pH adjustment, hydrazine and/or carbohydrazide for oxygen scavenging, and boric acid for corrosion protection..Periodically, sodium nitrite is used as a tracer to determine the steam generator blowdown rate through each of its blowdown valves.During unit outages, the steam generators are stored full of water, including treatment chemicals, to protect against corrosion during storage.This layup water is intermittently discharged (32,000 gallons per steam generator) through Outfall OOA to Lake Michigan.The layup water contains a maximum.concentration of 400 ppm hydrazine and/or 40 ppm carbohydrazide, 50 ppm ammonia and/or ETA, and 20 ppm boron.The waste strength of this discharge is reduced through mixing with Outfalls 001, 002 or 003 by more than 40,000 times.Demineralized water or secondary water is used to pressure clean the steam generators during outage periods.The water is recirculated through temporary filters to remove suspended solids.The major constituent of the suspended solids is iron oxide from the steam generators. The water is then returned to the steam generators and drained to Outfalls OOA, OOB, or OOD via the turbine room sump.OUTFALL OOB-Unit 2 Steam Generator Blowdown The steam generators require ultra high purity water for operation. Makeup water used in the steam generators is withdrawn from the intake forebay (or from Lake Township water supply)and essentially all natural impurities are removed through sedimentation, filtration, reverse osmosis, and demineralization. Periodically, impurities enter the steam generators through system corrosion transport mechanisms, the makeup water, or system upsets (such as condenser leakage)and must be removed to protect the steam turbines and heat transfer surfaces of the steam generators. The impurities are removed by draining a portion of the water from the steam generator. In the steam generator steam is separated.from the water, is further heated and then routed to the turbines.When the steam separates from the water, the impurities remain in the water, concentrating in the steam generator. Blowdown consists of two forms, a liquid portion (700 GPM maximum)and a wet steam portion which is exhausted to the atmosphere. The liquid portion of the steam generator blowdown is discharged to the screenhouse forebay either directly, or after processing through mixed bed demineralizers. Impurities in this discharge may consist of insoluble iron and copper and at times, impurities from the cooling water (Lake Michigan)used to cool the condenser. Steam generator additives consist of ammonia and/or monoethanolamine (ETA)for pH adjustment, and hydrazine and/or carbohydrazide for oxygen scavenging. Periodically, sodium nitrite is used as a tracer to determine the steam generator blowdown rate through each of its blowdown valves.*During unit outages, the steam generators are stored full of water, including treatment chemicals, to protect against corrosion during storage.The layup water is intermittently discharged (32,000 gallons per steam generator) through Outfall OOB to Lake Michigan.The layup water contains a maximum concentration of 400 ppm hydrazine and/or 40 ppm carbohydrazide, and 50 ppm ammonia and/or ETA.The waste strength of this discharge is reduced through mixing with Outfalls 001, 002 or 003 by more than 40,000 times.Demineralized water or secondary water is used to pressure clean the steam generators during outage periods.The water is recirculated through temporary filters to remove suspended solids.The major constituent of the suspended solids is iron oxide from the steam generators. The water is then returned to the steam generators and drained to Outfalls OOA, OOB, or OOD via the turbine room sump.OUTFALL OOC-Plant Heatin Boiler A heating boiler (150,000 lb/hr capacity)operates to supply plant heating and auxiliary steam when Unit 1 and/or Unit 2 steam generators are out of service.

'The boiler is also fired approximately once per month for testing purposes to ensure its availability. Impurities from the boiler water consisting primarily of insoluble iron and copper, are discharged (30 GPM maximum)to the intake forebay.Boiler water treatment additives consist of ammonia and/or ETA for pH adjustment and hydrazine and/or carbohydrazide for oxygen scavenging.(See Outfall OOD for wet layup drains)OUTFALL OOD-Utilit Waste Waters Utility waste water from within the plant is discharged via the turbine room sump (TRS)into an on-site absorption pond.The ultimate disposition of these waste waters is to the ground which vents to Lake Michigan.The waste waters include: Wastes from the makeup water treatment system.The main contributors to the waste stream are: the makeup plant demineralizer regeneration wastes (average 40,000 gallons per regeneration), degasifier pump seal water (108,000 GPD), carbon filter backwash water (average 45,000 GPD)and pre-filter backwash water (average 72,000 GPD).The retention tank periodically discharges a very small volume of solid material removed by settling.Alum (aluminum sulfate)is added to the pre-filter influent as a flocculent. These pre-filters are backwashed to the TRS to remove the suspended matter captured on the filter media.The alum contained in the backwash is discharged to the TRS in the form of insoluble aluminum hydroxide. Carbon filters are also periodically backwashed to the TRS.These filters primarily remove organics, chlorine and small amounts of iron.Sulfuric acid and sodium hydroxide used by the makeup demineralizers to regenerate the resin, are rinsed to the TRS and generally neutralize each other in the sump to form sodium sulfate prior to discharge. Non-essential service water is used to supply vacuum degasifier pumps which utilize approximately 75 gpm total via two pumps to remove dissolved gases (primarily carbon dioxide and oxygen)from the vacuum degasifier and exhaust them to the atmosphere. A new component of the makeup plant, a reverse osmosis (RO)system, has been installed to remove the bulk of the dissolved solids from the lake water prior to demineralization. Normal reject water flow is to Lake Michigan.The RO system must maintain very clean membranes to assure efficient operation and purity of water.Several methods are used to maintain this level of cleanliness from scale and biofouling. Using hydrochloric acid or sulfuric acid, the feed water pH is lowered to reduce the scaling tendencies of the water.Approximately once per month, a flush is performed using approximately 0.5%hydrochloric acid and caustic to dissolve any scale that deposits on the membranes (average 5000 gallons per month).Chemical cleaning is performed when the above flushes are no longer are effective. The chemical cleaning involves several steps and may contain citric acid, hydrochloric acid, phosphoric acid, sodium hydroxide and a neutral pH detergent (average 10,000 gallons per event).Also, to remove dead biological matter from the membranes, a soak using sodium bisulfite may be performed approximately once per year (average 5000 gallons per event).e During periods when not in operation, the heating boiler is stored full of treated boiler water containing at most 400 ppm hydrazine or 40 ppm carbohydrazide for oxygen scavenging and 50 ppm ammonia or 50 ppm ethanolamine (ETA)(for corrosion protection). Prior to use, this"wet lay-up" water is drained to the TRS for discharge into the absorption pond.The volume drained is approximately 1600 gallons and may occur 30 times per year.n During a unit outage, the condensers are checked for leaks by filling the steam side with condensate containing approximately 1000 grams of fluorescein disodium salt or Rhodamine B.These dyes, which are fluorescent under black light, aid in the detection of joint and tube leaks during visual inspection. The volume of water drained from the condensers ranges from 160,000 up to 1,000,000 gallons and may occur one time per year.10 Zn addition, the cooling water side of the condensers are periodically drained to the TRS for general maintenance periodically (8 condenser halves per unit, approximately 25,000 gallons of lake water per half).The component cooling water system (CCW)is periodically drained to allow for equipment inspection, maintenance or repair.This system uses demineralized water from the makeup plant as its source of makeup water along with a maximum of 1200 ppm nitrite (from Calgon LCS 60)and 100 ppm glutaraldehyde as treatment chemicals.. The infrequent drainings release approximately 60,000 gallons of treated water to the TRS per year.The diesel generator cooling jacket water system (DJW)employs the same chemical control for corrosion as in the component cooling water system with a maximum of 2000 ppm nitrites from Calgon LCS 60.This system is drained through the floor drains to the TRS when maintenance is performed. The system volume is approximately 1000 gallons.Any minor system leaks would also be directed to the floor drain during normal operations. The essential service water systems (ESW)and non-essential service water systems (NESW)are also periodically drained to allow for equipment inspection, maintenance, or repair.These drains may discharge approximately 72,000 gallons of Lake Michigan water used for non-contact cooling into the TRS.This water is either chlorinated intermittently at a residual concentration of 0.2 mg/1 TRC or continuously at 0.036 mg/l TRC.During some special treatment periods, this water may contain zebra mussel biocides, used as a molluscicide for zebra mussel control.Periodically, components of the ESW or NESW systems may be chemically cleaned to remove iron deposits using vendor supplied cleaning solution such as EDTA (ethylenediaminetetraacetic acid)or ascorbic acid, acetic acid and ammonia.These wastes could either be drained to the TRS or Lake Michigan.11 The steam generators (S/G)are drained for inspection and maintenance during scheduled unit outages (approximately every 18 months)and during an event where steam generator failure is detected that requires a unit shutdown.The steam generators utilize 150 ppb hydrazine (from either direct hydrazine feed or as a breakdown product of carbohydrazide), 20 ppm ammonia, and 2.5 ppm ETA to control the water and steam chemistry to be non-.aggressive to cycle components. Unit 1 steam generators also utilize 10 ppm boron to control corrosion. A steam generator volume released during the draining is approximately 32,000 gallons each.During wet lay-up, the S/Gs are stored full of water with up to 400 ppm of hydrazine or 40 ppm carbohydrazide and 50 ppm ammonia or ETA are added for corrosion control.This water is normally drained to surface water via NPDES Outfalls OOA or OOB, but may be drained to the TRS in some instances. The miscellaneous drain tanks can be aligned to discharge to the TRS.As much as 350,000 gallons per day may be directed to the TRS to control the chemistry limitations on the secondary water systems.Water chemistry is primarily the same as in the steam generators. Around the plant, miscellaneous sumps collect approximately 45,000 GPD of water from various equipment drains, leaks, pump seals, and steam jet air ejector drains.The frequency of discharge and types of chemicals used in this equipment have been described elsewhere in this description. Mi.scellanoous floor drains are located throughout the plant to provide a safe working environment by routing spilled or leaked water to the TRS.The major chemical influx into these drains are from the detergents and waxes used to maintain the floors.Also routed to the TRS through the floor drains are the chemical feed tank drains, fire protection water, drinking water, cooling water, and drains from bioboxes used to monitor the zebra mussel control measures and other chemical control monitors.The chemical feed tanks which may be drained contain hydrazine, ammonia, boron, ETA, carbohydrazide, and sodium hypochlorite. The bioboxes will discharge chlorine and zebra mussel biocides during treatments. 12 Non-ra4iological chemical lab sink and floor drains are routed to the TRS for disposal.The drains carry water and the wastes generated while performing analyses and preparing laboratory standards including those on the attached list.Also discharged will be glassware and normal laboratory cleaning wastes.The average volume directed to the TRS is estimated to be 500-1000 GPD.8econdary (steam generator or condensate) sample water from continuous analyzers are routed to drains which discharge to the TRS and the miscellaneous drain tank.The analyzers are on the cycles which may contain as much as 10 ppm boron, 150 ppb hydrazine (from either a direct feed or as a breakdown product of carbohydrazide), 20 ppm ammonia,'nd 2.5 ppm ethanolamine. The analyzers measure corrosion transport at a average flow of 8500 gallons per day.Mi.scellaneous sealing an4 cooling water supplies cooling and sealing water to the TRS pumps, condensate booster pumps, circulating water pumps, vacuum priming pumps, drain seal reservoir tanks and drain sample coolers.The average flow per day is approximately 150,000 gallons.Non-essential service water supplies approximately 53,000 GPD of non-contact cooling water to various sample coolers throughout the plant's turbine building including the conductivity room and the steam jet air ejector sample points.Chemical spills that enter the TRS may be neutralized within the sump'to prevent a discharge to the environment. The potential for spills to the TRS exists for the following chemicals with the proposed neutralizers listed:~Ce~ica Sulfuric acid Sodium hydroxide Sodium hypochlorite Hydrazine Ethylene glycol Neutralizer Sodium hydroxide Sulfuric acid Sodium thiosulfate NESW (lake water), Hydrogen peroxide 13

OUTFALL OOE-Sanitar Waste Dischar es Sanitary wastes are presently segregated and routed to two extended aeration package treatment plants.The existing equipment is designed to treat 50,000 GPD and the effluent from the sewage treatment plants discharge into one of the two seepage lagoons.The lagoons discharge into the groundwater with the ultimate disposition being Lake Michigan.The sludge removed from the sedimentation tank basins is taken to a local POTW (public owned treatment works)for disposal or dewatered and stored as low level radioactive waste, as appropriate. 1 Plant sanitary waste consists of shower and rest room facilities, and janitor washbasins located throughout the Plant's non-radiological property.Kitchen wastes are generated from the plant cafeteria, the Cook Energy Xnformation Center and Training buildings. The chemistry training laboratory discharges to the sewage treatment plants through a limestone bed neutralization tank.The chemistry lab is used to train technicians on analyses performed in the plant.The discharge from the lab carries water and wastes generated while performing analyses and preparing laboratory standards including those on the attached list.A small photo lab, in the training building, uses (on a emergency basis)small quantities of hydroquinone'o develop black and white pictures for plant use.The training building HVAC system also drains to the limestone bed.A radiography lab in the plant also discharges small quantities of processing chemicals for non-destructive testing in the plant.None of the radiography.products contain critical materials or priority pollutants. All portable toilet wastes on the plant site are collected and discharged to the package plants.A biodegradable deodorant is used in the portable toilets.Sludge effluent waste may also be recycled through the plants to decrease the amount of sludge for processing when possible.Miscellaneous rinsing of waste receptacles and possible cleaning operations waste, utilizing various detergents, may be rinsed to the sewage treatment plants.14

Miscellaneous Outfalls The main plant transformers on each unit are located within concrete berms.The berms are for spill containment should a~catastrophic failure of a transformer occur.To protect against operational and safety concerns which stem from ponded water, these'areas gravity drain to oil/water separators specific for each unit.Each separator is a below ground concrete basin designed to retain oil and release water to a series of drywells.Also discharging into the separators, are the emergency diesel generator pit sumps.These sumps collect limited water and fuel oil (less than 500 gallons per year)from the emergency diesel generator room.Periodically, the oil/water separators are pumped clean to remove the accumulated oil for proper off-site disposal.The security diesel generator day tank has an overflow line that connects to the Unit One transformer deck catchbasin. Discharge to the~catchbasin would only occur if the day tank were overfilled. Procedures and level indicators are used to prevent overfilling. 15

CHEMICAL LAB ANALYSIS Additional Information Section I Item 6, Subpart A Cook Nuclear Plant Surface Water Permit Application PLANT CHEMISTRY LAB (to Outfall OOD)Chloride Fluoride Hardness Hydrazine Silica Oil 6 Grease pH Free Mineral Acidity Total Phosphorus Chemical Oxygen Demand Sulfate Nitrites Total Residual Chlorine ASTM D-512-81 (1986)ASTM D-1179-80 (1986)Standard Methods 413 B (1985)ASTM D-1126-80 EPA-600-4-79-020 Method 130.2 (1979)ASTM D-1385 (1983)ASTM D Power Water Analysis Manual CH-41 EPA-600-4-79-020 Method 413.1 (1979)ASTM D-1293-84 Standard Methods 423 (1985)ASTM D-1067-82 Method B EPA-600-4-79-020 Method 365.3 (1979)EPA-600-4-79-020 Method 410.2 (1979)ASTM D-516-82 Method A (1985)EPA-600-4"79-020 Method 375.3 (1979)Standard Methods 426 A (1980)Determination of Corrosion Inhibition by Calgon Corporation ASTM D-1253 (1986)Standard Methods (1980)TRAINING BUILDING LAB (to Outfall OOE)Boron Chloride Fluoride Hardness Hydrazine Silica Oil 6 Grease pH Total Phosphorus Atomic Absorption Metals Ion Chromatography Westinghouse Chemical Analysis Procedure for PWR WCAD 7333 Rev.1 (1973)ASTM D-512-81 (1986)ASTM D-1179-80 (1986)Standard Methods 413 B (1985)ASTM D-1126-80 EPA-600-4-79-020 Method 130.2 (1979)ASTM D-1385 (1983)ASTM Power Water Analysis Manual CH-41 EPA-600-4-79-020 Method 413.1 (1979)ASTM D-1293-84 Standard Methods 423 (1985)EPA-600-4-79-020 Method 365.3 (1979)Standard Methods 302B, 303A (1985)EPA-600-4-79-020 Method 215 F 1, 220.1, 242 1~249 1g 273'(1979)Dionex System Operators Manual SEE INSTRUCTIONS QN REVERSE SIOE SECTlON I PERMIT NUMBER~iII 00058 27~EM 7'coVI"E A'F rE~cA~i.ElP=CN~ll4,.""E=RA idi"F ccE IEGiAIKE?QIIIT(3)"G i'c'P.".:"i ='H-"(AE'tE~SE sa E C~c<E.LOCATION[SEE ATTACHED DRAWING]MAP 21 4~I I~~4~I~'4 4~4'5~3I 3)~~'4 si))")1 s s J 4~JI'~~")0 5 s 5))~~C s 3~]y))s 4 s 4 0 y'Cs4'8'y 4~3 QI'J~)~4 4 I S~+I JP)4 5 4$5~4 4~sA 44 V ss))I s)44 4~f ps H\4)44) SEE INSTRUCTIONS ON REVERSE SIOE SECTION I NUMBER PERMIT-EM 8 CONCEN TR ATE 0 ANIMAL FEEDING OPERATION A, DQ YCU OPERAic A CQt~~TB>>'<<."Al, FEl IttG FACII.IIY?(IF NQ tCCtCiltAtE TG I,-ts J~))TYPE I I E.~T IS IHE MPSKR OF ACRES CF r"4IRIBUTltrG KAItQGE?Fs>trAT IS IHE DESIGtr SAFER FACTS'R THIS Ce>IIIRGL SYSisH B~MISER OF ACRES USED FOR CQttFINBENT FEDltG?C~sF ittRE IS OPEN 0)NFIM'TNT> rerS A erlrCFF DIVERSICN AIQ OQNIRQL SYSi~l BEEN CONS'si>K?(IF tO, CCttiltAIE TQ I icP1'3)D'~T IS BE DESIGN BASIS FQR l%C"NTROL SYSTEN?CIECK ONE CF BE FQLI WING AIID ENTER:AIBER OF IttCIES OF RAIN?NA NA NA NA 10~, 2II HrxR sTDFN 25 YEAR.2II tOR STCRN OBKR (SPECIFY)'tES YES NO ItrCtE3 INCHES~~~INCHES~~eeftES ITEM 9 TYPE NUMBER OF ANIMALS IN OPEN I AND HOUSEO IFINEMENT llr 4 I lit 4r4 I llr 4n 4 I A, I.!ST'SSE OF ANIHALS 3~GIVE IHE MPBKR GF THIS T~K OF>>4lt>AL IN CPBI CONF I trK)ENT.NA C.GIVE IHE MPSER CF THIS~>PE OF Alii<<AL l>4 HQU'ED CONF I teENT.Ae LIST TYPE OF ANIIVlLS 3~GIVE~EE"ASSER OF THIS,'~OF Attl."AL I:I CPE4 GCttFIN9%NTE .~GIVE&E tlPKR QF>sIS'-K t F 4'IINL ltl HCUSED rQNF I 4T.Ae LIST TTPE CF ANIS4ALS 3~GIVE TE E Mt%9 OF TEEIS=3 QF>>SINAL It: QP.'I INK)SP.C GIVE BE MtSKR OF'IHIS>APE OF ANIMAL Itr tOUSED XNF MKBf e A.LIST TYPE OF ANItVlLS 3.GIVE THE WBKR OF THIS T>~OF ANIHAL ltt OPEN 0>NF I%ANTE E E IAPBER QF TEEIS=K QF ANI'QL'lr~KD r A~LIST'>>PE QF ANIHAL.3.GIVE EHE USER GF IS>IS+E CF ANIHAL~W OPEN"QrF I>CW>IT.GIVE BEE tAPSKR CF THIS.YPE OF ANIMAL Itr HOUSED Q)tF I N Ae'ST TYPE OF AtrIHALS 3.GIVE TrE MISER QF THIS~(=E QF ANIHAL Ite<<PEN COIF IhK%NT~C, GIVE IEE NW3ER OF THIS~IPE OF ANIHAL lrr HXISED rQtr Ireen.A.LIST iYPE OF ANINALS 3~GIVE BE NW3ER OF BIIS s rPE OF ANIr>AL IN OPEN C.GIVE THE MHKR OF BIIS e>~E OF ANP'AL IW HOUSED CAF IIEHENT>Ae LIST TYPE OF ANIMALS GIVE BSE MICR QF ee>IS,=E QF ANIS>AL Iti GPK4 MF I'SK"Beti C, GIVE TEEE MPSIER GF THIS~C<<E GF A4IHAL Itr tOISK CAF I t6%NT'e~~I l I l 23 Iin't~u5 3)hD g 4"vlf'Bs,hfc, 3>>l n))cut"8 0854 h, 5'~)A I>>e)"" bars)I)nftats h 8 i n Bi 3 Bc)0 al'Bec~t Itl YI33 4~-C 3Py 4;-:-P-c'1=Cst-%03bsti,.;I<43gq 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INSTRUCTIONS ON REVERSE SIDE SECTION I PERMIT~ZZ pppg827 NUMBER DC M CFc=<<:sc AN ACUATtC ZltMAL PROCUCTI tt FACILI~<<ilF tO lesilAK TO:~2I X AO VATIC ANIMAL PROOUTION FACILITY lTEM SPECIES OF AQUATIC ANIMALS PROOUCEO AT THIS FAG I LIT Y B.DesstCATE.=E.OTAL tAlIER CF PDtCS<<RACEWAYS A'>>D SIMIM 3>>s>>UCT>>DES '7 (CUI FACILITY.NA:pcripv CD It>>DICA<<c ,'~>>>>WICH CALBBAR tCNik, AXI<<tlI FEEDI,'IG OCCURS NA BPi<<R i<<E TOTAL MPSER OF POtl<<DS CF.OOD.ED DlRtttG TrllS~?A.IS THIS 3PECIE A scUIM CR CCLD WATER SPECIE?NA Bi GIVE>>>>E NAME CF 1HIS SPECIE.C.ENTER TrE TOTAL HARVESTABLE WEIGHT OF THIS SPECIE~BY THIS FACIL.'TY PER YEAR IN PCLhDS~D BITER T.-E MAX!MLS WEIGHT PRESENT FOR THIS SPECIE sttICH'<<CULD RE.RESENT YtXR KRMAL OPERATION<< iS ani3 SPECIE A'ASM CR C LD ssAIER SPECIE.B.3IVE.rE NtME OF THIS SPECIE>>C~ENTER HE TOTAL HAIIVESTABLE WEIGHT CF TrtlS SPECIE PcCDUCED BY THtS FACILITY PER YEAR IN POtl4)S.D Biicc E st<<AXIPV1 WEIGHT PRESBIT FOR IHIS SPECIE WHICH OIA" cEPRESENT YEA tCRMAL CPBIATIOtt

S Tssi3 SPECIE A WARM CR COLD WATER SPECIE?B~'zi'>>E-'PFE CF THIS SPECiE~HcRM~.see<<sess I I s~C~EIIIER~E TOTAL HARVESTABLE s>>EIGrIT CF iest3 SPE>>>>E<<3Y TH FAC TY P R Y N D.BIIF..s E~AX!Nit WEIGHT PcESENT FOR THIS SPECIE WHICH~cEPRESENT YCUI MRMAL CPERA'TICN.

A IS>>HIS SPECIE A>>08M CR COLD WATER SPECIE.B.GIVE=E IA'E OF IHIS 3PcCIE.cess c'<<TEc~E TOTAL HARVESTABI c wEIGHT OF THIS SPEC:-ccOCUCE~BY DilS FACILI Y>ER'EAR IN PCIl>>DS."~='>>T==E MAXIM WEIGHT-,ESB>>T=CR IRIS SPEC:E itttCH~'4 cEcRESBiT YOUR tsCRe'AL SocoATICN, rt3 SPECIE A'RM OR COLD stATER SPECIE.B..i>>E=E LIAME OF THIS SPECIE>>I i I DOlg@S'!~OTAL MARVESTABLE

• EI5'T DF THIS ircC;ccGC~-BY er'.IS.ACILITv>cEP<<BB Irt cCQQS='iTER<<<MAXIMcHl>>EIGrIT PRESENT FOR THIS SPECIE MICH~'="RESENT YON l4ÃMAL CERATION>>As~:3 s".'3 SPECIE*WARM CR COLD WATER SPECSE.3~st<<K scE NAt%OF THIS SPECIE<<c.'sicR'?E TOTAL<<IARVESTABLE WEIGHT OF THIS SPECIE ccCCUC D BY TH I S FACILITY PER YEAR I N Kc lCIS~D.E.'ii-R=c MAXIM WEIGHT PRESEtiT FOR THIS 3PEC>>E+ICH tAA c=cCESENT YOIR N?RMAL GPBIATION.

27 ~~~~>>0(>>~~~>>$4 4$I n>>" Cu<<0 es~" I~ar<>'>>>>>>~'~~-'<<<<>>'~~>>>>~.~~5 I a<>ct)<<ey 05(y 9 4 (5 RI~4~Va I>><<)0)I 0<<<>4>>>>5 f<<!'>>B~3 3 5~R)<<d 0>>"4-!>>iree 0 C)ta:n"P":8:er-.it-...XC.S'CRS)re OBSec"".SiZB)CC Ccccrr!"CO '->>rc!.-Rs.-4 5:!:.-=F 15)re))sac:-"0--!I-"e scec'es)re<<ai-<<ate<<cc:o(=Rt!r.:",--!:-=-...-:--)r'Bs-)3 0)0"cd 350=."--e<<cuc-!!ci-l" ccvncs-'-cc"".:Oi<<0-e})ec Bs ss--3-'" avs<<0".ea<<,: "."..r':!')cs ct excess r not~(tcr<<aftl<<ater"5"I)re a(5 9 u cr+>>>>0 (0}>><<)3 5 3!}h)>><<<<er (>><>v<<>>>>I<<)'>>$<<$}er.Ce~~C<<>>nC 3 BCCI i 05~<<,>>"9<<~CBC Or Rsi nates 35 5 3 54 V i!S I~>>0<<arer'sn}acies or otic()o(c<<ater)cuatic)--)3'-ci ci-c,=r-".">>!c-,-ne 3ai~<<cae (5<<,'-"I-'~}3>>.~, CS~)0!<<0($)r 9<<})r 5<<CC,CI'!5<<h>>C iSC.Br 0!t IBast 0 ays R<<(ear.4$CB.Rs"I c<<coco'0$$3n?,?0).(05<<4<g)5~)c xi~ateiv 20, 0 ocul'0$5 t)cua'I" 3 5 er.ear.=!ci('-:!s nich'eec'ess t"3(,.<<.'.Cgr)s , 1!RC'-g~x(3 d>>v 0 I'cs((00 cin a)>>a<<<<)r 4>>>>~<<3-!r'(5" 5 ao'<<S C<<0<<he<<<<)r <<ater)cua<<IC)-:-)'3'""I"i"C."--'=-:->>miteC;C-<<e--Ri.r(:)e..!-")0"'.ae. I')B~3>>>>I>>'!5 (1 sh'R...!5 00'rd~', 3'", i'3", 5"0>>"nO<<$('ones,)CB<<av5,<<her}>>a>>)I r.et<<res nich cischarge ar Ieasr.'0 cavs cer year,=t oes ncr l<<c(uce}5!""$" (SCt'af'n<<I" 4~!5 C RS I'cu 0 4$5>3n'3~4 1 5:e..!)r,~)I>>.'f}:TEr.ID-8-!-)-)I"moe ct 0:screte x)ones cr)ce<<avs 5 3'9<<ay"'4$'-;O)Ci': V.noer-:<<er")I(e S CeSCt'icriVe name".'"V S<<arS Ot-e niteC$-3 eS IT8H 10 0 0~31 0".(Rn or ax(>><<ln monthly cun05 I (OOC 5nouic 9!Cresentativ! 0.>>Cr<<on a(ccet'at~TE((I: 8 I I Rj 3<<0"" B I t)mes I I.C ANO 0 4 3 4>>'~9'<<~!<<ar!}!>>0'>>0('<<<<--4">>X">>n<<0:-"--<<Se<<-~-5"V"9-<<->>)i"<<4<<i BC!II 0 5 4<<~0$I ii~<<I<< SECTION I NUMBER~~LIST NA"4 A,'6,"/tILIM ADNESS Ci ALL=~PPT/~'.EBS AL,~sT,O.W-V I~SNT iÃlL:~s"8 CR DISCS*%w/DISP"iSAL '>~,[SEE ATTACHED LIST]MAILING LIST OF ADJACENT PROPERTY OWNERS Section I, Item 12 ADJACENT PROPERTY OWNERS MI0005827 EAST Interstate I-94 (Michigan Dept.of State Highways)SOUTH Lake Township c/o Gerald Wasko Township Supervisor 1410 Shawnee Road Bridgman, MI 49106 WEST Lake Michigan (State of Michigan and United States of America)NORTH Rosemary Beach 11-11-6800 0038-00-5 Tengerstrom, Eric H.;3415 S.59th;Cicero, IL 60650 0037-02-5 Tengerstrom, Eric H.;3415 S.59th;Cicero, IL 60650 0037-01-7 Merkel's Floor Covering, Inc.;8314 Scottdale Rd.;Berrien Springs, MI 49103 0037-00-9 Kraiss, Wilbur&Marilou;5004 S.Long Ave.;Chicago, IL 60638 0036-00-2 Temmel, Edward P.&Kathleen;9617 E.Shore Dr.;Oak Lawn, IL 60453 0033-00-3 Gilpin, Clark&Nancy;1005 E.60th St.;Chicago, IL 60637 0032-01-5 Wittebort, Robert J., Jr.&Nancy H.;3180 N.Lakeshore Dr.;Chicago, IL 60657 0030-02-1 Meier, Paul&Louise G.;1357 Madison Park;Chicago, IL 60615 0028-01-8 Balka, Ronald A.&Janet M.;3334 Louise Dr.;Lansing, IL 60438 Section I, Item 12 ADJACENT PROPERTY OWNERS Page 2 11-110006 0002-03 0004-00 0004-04 0004-01 0004-02 11-11-0007 0013-00 0013-01 0006-01 0001-01 0004-01 11-11-0005 0029 0036-01 0027-00 0036-00 0036-02 11-11-0005-0002 01-6 11-11-0008 Michigan Dept.of Natural Resources; P.O.Box 30028;Lansing, MI 48909 Franklin Real Estate Co.;P.O.Box 2000;St.Joseph, MI 49085 Temmel, Edward P.;9617 E.Shore Dr.;Oak Lawn, IL 60453 Caparo, William E.&Oyler, Kathryn E.;122 S.Ellsworth Pl.;South Bend, IN 46635 Rosemary Beach Corp.;c/o Secretary; 3415 S.59th St.;Cicero, IL 60650 Lake Charter Twp.;Shawnee Rd.;Bridgman, MI 49106 Lake Charter Twp.;Shawnee Rd.;Bridgman, MI 49106 Indiana Michigan Power Company Lake Charter Twp.;Shawnee Rd.;Bridgman, MI 49106 Lake Charter Twp.;Shawnee Rd.;Bridgman, MI 49106 Technisand, Inc.;11833 Ravenna Rd.;Chardon, OH 44024 Ruff, Timothy W.;P.O.Box 504 Bridgman, MI 49106 Technisand, Inc.;11833 Ravenna Rd.;Chardon, OH 44024 Emery, Martin;Hopkins, Elwood J.&Mable N.;7499 Thornton Dr.;Stevensville, MI 49127 Indiana Michigan Power Company Bank of America Texas P.O.Box 650380 Dallas, TX 75265 0041-00 0009-00 Michigan Dept.of Transportation; Lansing, MI 48900 Franklin Real Estate Co.;P.O.Box 2000;St.Joseph, MI 49085 0~0 W I 0,~~~I~~,~~~I~~~~~r~I~~tt~I~I'~~~C~~~I~~~~~~'st~~~'~I~~~~~'l~Jhl~t'I~r I~~tt~~I~I3~~~~a'0'~~I~~I'.It~~~~'I~~'~'5~I~~~~QI I~'~.I~~~~~~~I~~I~~~~I I~~~~~'~It I 1'~I~'~~~~~~~4~~~~'~~~C.I'~'I~~~~'~ 30 SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I PERMIT~qZ pppg NUMBER LITEM 3 AIIFALL%lKD A~"~'4 CF PRXESS COltIRIBUTII4 IO EHE DISOIARGE e~THIS CUAFALL~Q SIC CCDE B~?ROCFSS SCHEDULE (YEARLY AYERAGE)L~O CIO0L I NG I TRI 49 tCIXIS/DAY"AY/PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE 4/I Lft O~0 0 De PROCESS PRODUCTION RATE NA C~I'SIOCESS HASTEtlATER FLQH RATE Basis: 1993 actual data submitted DMRS TOTAL YEARLY DAILY ttINItXTI DAILY INAXINM 38P227~5~6 1323~6 Lttl TS/TIHE I I 1 POUNDS 2 GALLONS 3 CUBIC YARDS 4 TONS 5 MGY MGD 7 GPD TIME hatt 4/t fit Mcv O GL A, tl4tfE OF PRQCESS CONIRIBUTING TO TsfE DISCHARGE itFCUGH THIS OUTFALL Al4)SIC COTE NA Be PROCESS SCHEDIAZ (YEARLY AVERAGE)Ce PROCESS HASTEHATER FLOH RATE D PROCESS PRODUCTIOI RATE A.IIAIE OF PROCESS CQNTRIBUTIIIG ro THE DISCHARGE TIIIQUGH 1HIS OUTFALL AISD SIC CODE B.PROCESS SCIEDULE (YEARLY AVERAGE')C.PROCESS IASTEHATER FICtt RATE De PROCESS PRODUCTION RATE HERS/DAY~DAYS/YEN TOTAL YEARI.Y DAILY HINIHIN DAILY HAXItuS EYES/DAY~DAYS/YEN TOTAL YEARLY DAILY HINI t%N DAILY MAX WN UNITS C'TIHE~LJ 1 HOUR 2 DAY 3 WEEK 4 MONTH 5 YEAR A e tIA%OF PROCESS CONTR I BUT ING ID TIE D I SCHRRGE NA TH Atg SIC CODE B~l%OCESS SCHHAAX (YEARLY AVERAGE)RECESS HASTEHATER FLOH RATE ISAIAS/DAY ~SAYS/YEN L-L-I-l TOTAL YEARLY DAILY H INIIXPI DAILY A'AXItstPI LNII'ODE<h 4/)Offt Ct tX De srESS PRODUCTION RATE Ae tfAtE OF PROCESS CQNIRIBUTING TO TIE DISCHARGE TI4KXXB THIS OUIFALL AttD SIC CODE Be PRXESS SCHHXLE (YEARI.Y AVERAGE)C, PROCESS HASTEIIATER FLCtt RATE D, PROCESS PRODUCTION RATE TOTAI.YEARLY DAII.Y NINIIXTI DAII.Y tAAXWN DAYS/YSN UAIITS/T(HE<<II T C<<"E I UNITS/TIPE 5"'l"I'e r 555 5 ros~s I'4 IS 3;<<)4=4';t'-E"-Cx At-==-~4 Cc-.-IE cgcu.'-=4Eoul>".iynCR AII EE 49.'tQ CN fi E PCNT RAGE=r'4 EXPIRI"B 5 5 3 ew,r r ev'5I 5 Ar l, e~3 3 I~v, ren leave c I snA a,.d 3 1ul per~I I I:e ass icnec.d 5~3l I, e~5 ace 4 video~eac.dace EecTIcn<<I, cr each trdlvl val dlsc1arce saint 3 Secara~3 ser c"e 5 usr e ci I laa , I C 3"C JTh, t IC g 4 Carll C', riC cc altc'j'gII~IhF uATIC'I E"-ec--e-m='1e process<<nlcn ccnrn'cures "Is Siscnarae. <<Iso provide-"e prccer IC c-ae."calo e-re veal lv 3verage process Scneaule In hours:er cav ana days-cer-veer. Provide t14 prcde55<<35tcwater flow rate infornation 35 reaueSted basea on your last 12 lnanths of operationS. Refer to unit code given in the left margin for the appropriate flow units.orpcess prcauction pate-certain demit limitations may be based cn production la.es..he croductlcn rates used to ceter1lne demit l'nits Sr all ce.eprese"-ec bv 3 reascl,acle caesura c'.cruel production c', he<scllltv, svch as the:rccvct!cn during~he 1ign"anth c'"e previous veer, r T1e nOnthlv averade',Cr tne highest cf The plevlcus five years', or CT1er.eaSOnable"easure as stated ,'n sdpi:Cable d.E.E.4.A.categoriCal rules ana reaulaticns."ew 3 ur es r"ew pl5c13r or5'~tave r 513s=e asti atec.Sir=crclected crcductlcn ReCCrd y" r C"Cd;C-'Cn rateS In-re-er.S snC.nlrS.Sea'n me 334<loadie ~.E.E.P.A. CateacriCal iuleS and reduiaricnS fdl'4 SEE INSTRUCTIONS 'N REVERSE SIDE SECTlON t I PERMIT~eII 0005827 NUMBER CBEM OJIFkL IU'FE A.IS eeIE DISCHARGE FROM THIS OUTFALL DIRECTED TO THE GRCUt41 CR GRQVtCWATERS2 I IF toe CONTINUE TQ ITEM 5)YES AO t le GROUNDWATER DISCHARGE INFORMATION B.TWAS A stYDROGECLCGICAL STVDY OR ITS EQUIVALENT BEEN PERFORMED OR IS THERE SIFFICIENT CURRENT HYDROGEQLQGICAL INFORMATION AVAIIABLE AS REQUIRED BY DE wATER RESOURCES H~ISSICN PART 22 GRCVADWATER RN PS CF AUGUST 14 1%6 R,$23,22O7 (PAGE 4Q)FQR Dtts EXISTING CiR PROPOSED DISCHARGE. IF YES ATTACH A COPY OF IHE REPORT.C*RE YCV REQUESTING AN EXEMPTICtt FRCM SUBMITTING A HYDROGEOLOGICAL REPCRT VteDER RULE R.323.22(I (Lo)(PAJGE tttt)QR FROM GRQLNDWLTER HQIIITORttts I)EQVJREHEttTS VNDER RULE R'>Zse/JUICE (5)(PAGE Ll)OF THE PART 22 RIES~IF'ES ATTACH COON'S 441 EXPLANATtON TQ DEttQNSTRAIE THAT YAH DISCHARGE WIXaD QUALIFY FOR AN EXEt1s IQtt.De ARE YOU REQUESTtttl A VARIAttCE FRCM RULE 323e2205 (PAGE 5)(ttQttDEGRADATICN) OF THE WATER REsoURcEs cQtTt tss ION PART 22 GRQUNDtATER RULEs2 IF YEs, ATTAcH sUcH DQCVtENTS AS tiECESSARY TO DEMONSTRATE THE NEED FCR A YARIANCE IN TERMS QF Ttt CRITERIA SPECIFIED IN RIAE 325.2210 (PAGE~CF THE PART 22 RULES~NA NA'es:c YES ITEM 5 EXPECTED WASTE WATS II CHARAC-ISTICS Usi..a CODE 1 Mg/I 2 Ug/I 3 COUNTS/100 mt 4 S.U.5 F 6 LBS/DAY 11%APF1.ICANT IAAY BE RECUIRED 10 DO ADDITIONAL WASTE ANALYSESe A>>DISCHARGE CHARACTERISTICS CQNCEttTRATICtt Q NQT APPLICABLE/BELIEVED ABSENT NA PRESENTS CATA PROVIDED IN ITEM 7 NITS CODE tt ANALYSES SA"PLE TYPE CODE BQD5 (F I YE DAY B 1 octet lcAL oxYGEN DETAAttD)CQD (CHEMICAL OXYGEN DEMAND)TOC (TOTAL ORGANIC CARBON)AtfEXIIA NITROGEN (AS N)TOTAL SUSPENDED SOLIDS TOTAL Pt42SPtCRUS (AS P)TOTAL RESIDUAL CtLORINE D I SSOLVED OXYGEN PH HIN~7~0 FECAL COLIFORM BACTERIA TEMPERATURE (SttttER)mdiv TEE (WINTER)~0,~ll 8 l.u3~65,~5~0~20~8~2~83~4 ul LlJ~u ul~u ul ul ul ul u3 u3 Be OTHER WASTEWATER CHARACTERISTICS Ee I,IST AI,L CHSIICAL SIBSTANCES WHICH ARE IN MICHIGAN'S CRITICAL MATERIALS REGISTER TABLE IV'LPAGE II)AND/QR U Se EPA S PRIORITY PIXLUTANT LIST TABLE V (PAGE 7)OR ANY OTHER SIISTANCES NIICH ARE OR tAAY BKQK INJUIICUS TO 1%DESIGNIITED USES OF T%GSXNDWATER OR TO THE PUBLIC HEALTH 1HAT ARE DISCHARGED OR EXPECTED TO BE DISCHSIIGED TO 11%GROutDWATERAY THIS FACILITY.ESTIMATE 1HE FINAL EFFLUENT CONCEtttRATION AAD RECORD ALL DATA IN ITEN 7 OF SECTION ll IN 1HIS BODICE~SAATRLR 2222.1 GRAB 2 24 HOUR COMPOSIyE 0 I I.B Ce R E A S E I-LJ LJ LJ LJ~LJ LJ~LJ LJ LJ DMRS REQUIRED INFQI4tATI(Xt FCR SURFACE WATER DISCHARGEse LJ SEE ATTACHED SHEETS FOR ANALYSIS DATA*Basis: 1993 actual data submitted on u u 35 8'r'rc rai i~>>c~~>7Ev5'"'0 5 s r<<.8>>Jires nrcr.dticn cn 3 3 8>>ri<<Ti Ir I,rsc dr'ging ei"Br I'8 grcuncwnters r Tr'8 5ur.dcB<<dters.VI 7'."BE>>ru 7RE~X 3~i E 0 rF 7i (5 CRY.PE EBI7 IASvBER CAV EE FCvNO Crl TpE FPCT(7 PAGE CF yCQR EAPIR(r;5 5 3 3 ne>>cr nct previous:v cerml ttec'dci I i tv,-hen ledve blank dnd 3 hurber wl I I be assicned.I<<<<-.:8>>'" 7"8 5:3>>B 3>>av:sec'3>>sdr>>".dce or 5ec-(cn', I.=cr Bach indlviduni d(sc>dree cc>>5 separa-e set"e i<<Eid 3~,c'rcv>>t ii'r'3*E(.i i'Jc IC'r rhBCFBA I'I Irr irl 5 I~Eu)SCCI.'cdr,t Shall sdcress each a!-nese=arts I'e ciscndrce'-an-.".Is outfnl I:5 Ta The grauhc<<nte>>. I'7E4I=.I5~l'.G".P.KaEC.E" (FCR A KE)r O(5CHARGE) rr35 EhATER C!ACACTEPI57lrg 5<PROV\O'irATER CR 5I'RFACE'rrATER O(5CP'RGE ("O'!07 lrCI.UOE.-C.I'<ru,'RvA7 I I I~irl>ru I 7he applicant shall report available discharge dnt: (real data tor ex(sting discharge or expected data for 3 proposed discharge) tcr The parnrre<<ers ds Ii5ted.74838 parameters shall be addressed far either 3 surface water discharge or ss appropriate tor 3:raur Cwater CISCndrge. FOr SSSIStanCe In determining apprOpriate barnmeterS 3 grOundWater d(SCharCe nppl)Cnnt mny CantdCt The~rcurc<<dter gua)itv Olvlsicn, Permits 5BC;icn cr The dcorcprlate GraundwdTer Qudlitv Oivislan'5 Oi5trlct a!flee.",.<<ocr)cant 5"all>>Boar."e sdmole tvpe cede best sescribirg Bdch repar Rd olece of data.See cad(rc an t"e left margin of n:5!err."is: 'T!3: I 5 3 surface<<ster l5C r', 8 dept~cant-ust-Boer"."anti Tntive data fcr eden parameter Identified bv an Ts,er 3<<.;8 dppiicdnt mav, however,, dcqest--dt-ne repor-hc a:dtd cr cne or mare o Tnese recuirec parsreters be<<diveC.Cn 8".'BST ust be 5'opal'.BC bv SCBcudte 3 (Chare.dkB Such a recueST dn attachment TO this application.

'3,3~5 Svdiidb'8 tcr other para>>ieters r CT I~stec Sbave in'.Cr other pdr'Ts of Thi5 dcpllcatioh The sap()cant 5havld repor'T-dt"3rd in Tre:rdnx SPaces crovlced ln this part.rg7E5.r)nit codes for parameters reported In oarts A dnd B can be found on the lett hand side of this form.:rnb 53BO(e Snail e uSeo t" Sr a(VZe'Or Crr~Temberature, TO<

>, coo, 7cc, Ammon(a Ilitrogen. dnd iotdl Suspended Ealics In 3 surface<<ster clscnarre unless other'recuency-sample tvoe analyses are available. See Glossnry (pace 4B)for definition cf ccr.casite sdmole.ceo<<7"rur:F I'rTAKE 373.'Ci, 3rd nat recvired Tc reccr'.Class ycv<<isn To demonstrate vour Bllcibillty tcr a"et err luent limitation 'c" cne cr cre al lvtdnts, ThsT is~dn ef fluent limitation adjusted by subtracting the dverdce level at the ool lutdnt(s)present In your Intake water.VpoES regulations a(law net limitations only in:ertain err cumstnnces. a cercnstrdze vour Blicibili.v, repor.-he sverdce of Tr'e results ot dnalvses on your'nts<<e<<ster (it vour<<ster 35 Tented berCre<<Se, BS.-ne aTer atter lt is treated), 3 c attaCn a Separate 3>>BBT=5-Sining-8 rCIIC<<irc rar 83Ch:Crrutsnt: (5)'<<3-<<Bnt"ST<<"8 r>>make<<dter'5 drawn i>>cm"8 cccv=<<ster nta<<nlcn<<he ci5cndrce is<<ade.,Ther>>ISB w>>u 3r'B>>cT 8 i i ib)e rcr BT'>>I 3 lans.)Std<<8>>ent Ci<<"8 BXTBnt.a>>hi.",>>8'BVBl C~Tne Cal rutnr T (5 rBrluCBC by Treatment Ct'rCur<<35TBWdtBr.-vcur linlt3T(ons wi (I ce adjusted only Tc The extent that The pcr lvtdnt:5 nct reeved.)fc)xhen applicable (tor exdmpte, when tne oollutant represents 3 class ot co.pounds) ~3 demonst stion ot the extent<<a wl Icri<<he pollutants iq he l>>take.Brv t"vs(ca!Iv, 8<<lcd(!v,>>r b)alacics'Iv ra~"8 cc(lu 3"Ts Icntnl"Bc ivcur Ci5cndt'CB. Your:mi Tat*5-5<<': r 38 SC'.Ste-Criy Ta Tre BXtent-dt Tre Ir Td<<e Col li)tanTS:3 nat vary!rom the dlscndraeo Pai lvtanTS.: ic'.nave t o>>-cre).cst>>" id)i cr'v Tc same id Snc d>>5 Iv[8 g 5 5"~dl lv ICPnt cdi a>>P'I~'"Centred I."5 3.,3~Tv>>8 uast=er,isslon Ir~vcur:er lttlrr,~v" 8 cv dr I}.5<<bml 8 85<<I 5 ar ne d<<atvs)5 i r a r Br Supstdr tin(Iy st 3:>>3"-o1:i"8 38~i--'"c duthcri:, cr d sepsr3te shee-3-Sc"Bc tc.<<we-C Ies:-:be nv-.e curidils hier.Cu"C-Ct-eSt dre SEE INSTRUCTIONS ON REVERSE SIDE 0IIt.kL NXB SECTlON ll PERMIT~MI 0005827 NUMBER~00 1 eTEM 6 PRIORI T Y POLLUTANTS AND ADDITIONAL INFORMATION FOR SURFACE WATER OISCHARGE ONLY<ATE FCI'OWING REQUESTED INFORt'ATIOtt ~c>><cc A"DRESSED~~SIRFACE WATER DISCHARGERS> IIQIEI.'>Ew USE DISCHARGERS e~>>PRQYICE ggECTED VALUES FQR ThE QUAIITITATIVE AttD Q~lTATIVE IhFOR"ATICN REQUESTED BELCH, A.IS THIS FACILllY A PRit>PRY IIKLSTRY2 (REFGI TO TABLE IA PAGE 4+t>c>C, GQ TQ E)(tF VES GQ TG 8)8 INDICATE TYPE GF PRIMARY INDUSTRY AS Lls~IN TABLE IA PAGE 49~<CCtlf ttNK WITH C~)C>XES THIS CUfFALL DISCHARGE CCttfAIM ANY PROCESS WASTKWATKR2 (>F NQ>GQ TO E)'IIF YES, GO TQ D)NDICATE WHICH C/YS FRACT'CNS MUST BE>FSTED FOR (REFER TO TABLE tA PCiE 4~t IIQIE!FCR EACH GC/t'S FRACTION CHECKED, EACH SPECIFIC ORGANIC TOXIC POI'TAMT WITHIN EACH FRACTION f2!!5J BE AIIALYZED FQR (SEE TABLE I(A PAGE 92.IH ADitITICM> ALL PRIPARY ttKXISTRY APPLICANTS WITH A PRQCESS WASTEWATER DISCHARGE~PROVIDE QUAMflTATIVE DATA FOR EACH TOXIC POLLUTANT IN TABLE lllA PA;E Q)>RECCRD AU.DATA GN FCRMS PROVIDED (ITEM 7)IN THIS BCOXLET>(CQNTIIAIE WITH E-t(BELOW)X YEs STM EL EC PtMR X YES Q>o X VIXAT I LE QX BASE/NFUTRAL X ACID PESTICIDE*'.IF~SURFACE WATER DISOIARGE APPLICAMT (PRIMlRY QR SECCNCARY INDUSTRY), REGARDLESS OF THE TYPE OF DISCHARGE> KtCWS OR HAS REASON TO BELIEVE THAT ANY PIXLUfANT LISTED IN TABLE IIA AND IVA PAGES~IS DISCHARGED FRCM ANY OUTFAU.>THE QUANTITATIVE DATA~BK PROVIDED>RECORD ALL DATA ON FORMS PROVIDED (ITK>t 7)IN THIS BOOKLET>NQT APPLICABLE/BEI.IEVED ABSENT O O X PRESENT/CATA IS ATTAOlKD F.IF ANY SURFACE WATER DISOURGE APPLICAVT (PRIMARY OR SECONDARY ltGXJSTRY)> REGARDLESS OF TYPE QF DISCIIUIGE> KtCHS OR HAS REASON TO BELtEVE ANY POLLUTANTS USTED IN TABLE VA PAGE+ARE DISCHARGED FRtYI ANY OUTFALL THE APPLICANT~>DESCRIBE REASONS FOR THE POLLUTANT BEtt5 PRESENT AND PROVIDE ANY AVAILAB(E QUANTITATIVE DATA>RECORD ALL DATA ON FORMS PROVIDED (ITEM 7)IN THIS BOOKLET.G>ALL SNFACE WATER DISCHARGE APPLICAMTS (PRIMARY AND SECONDARY INDUSTRIES) WHO'QR HAMIX'ACTMES 2, 4, 5-TRICILCACPHENQXf ACETIC ACID (2, 4, 5-T);(>4>5 TRIOkDROPHENQXY) PROPANQIC ACID (SILVEX>2>4>5>TP)'I%7HYL U (2>4>5 TRICRDROPHENYL) PNSPHQROTHIOATE (ROWEL)'TRICtLQRQPHEIOL (TOPI'R HEXACHJOROPHEt>E (KP)'ALL DATA FOR THE ABOVE PI/ST BE GENERATED US It6 STANDARD ANALYTICAL CALIBRAl ION PROCKDIRES) QR Kt4WS OR HAS REASON TQ BELIEVE THAT TCCD IS OR MAY BE PRESEMf IM THEIR DISCHARGE>> ~REPORT%ALITATIVE DATA>GENERATED WHICII gjED A SCREENING PROCKDNE NQT CALIBRATED WITH ANALYTICAL STAIIDARDS, FQR 2, 5,/)8,-TKTRACHLORQDIBENZO P DIOXIN (TcDD)~REcQRD ALL cATA 0N FQRMs PRovlDED (ITEM k)IM THts BQoxLET.J~IF ThE SURFACE WATER DISCHARGE APPLICA'g KtCWS CR HAS REASON TQ BELIEYK>>AT BIQUXIICAI TQXICtTY TESTS wERE."ACE IN THE LAST THREE (5)YSlRS Qtt Attt OF Tt>E<<FLIC"'tf 5 DISOIARGES QR ON A RECEIVING WATER lit RELATIQtt TQ A DISCHARGE> FROVIDE THIS It>FORhATICN AS AN ATTACHMENT TQ THIS APPLICATIOM> tF A CONDUCT VBQRATORY OR CONSll.TING FIRM PERFORMED Atft OF Tte ANLAYSES REQUIRED BY THIS APPLICATION> PROVIDE THE NAME AND ADDRESS OF EACH VBGRATORY OR FIRM AND THE ANALYSES PERFORMED AS AN ATTAQC%HT OF THIS APPLICATIQtt ~CO YQU DISCHARGE ANY OTHER TOXIC CR INJIRIOUS CHEMICAL SISSTANCES NQT LISTED Itt TABLES IV PAGE (I AtKI t tA THIOUt4l VA PAtiES~~+~'>c+ES>THEN IDENT lcY THE ICAL SUBSTANCES AND ESTIMATE THE FtttAL EFFLUEMT CCNCENTRATIONS. SLKttIT THIS thFOBATICN AS AN AITAt&%lP TO THIS APPLICATION> QX NQT APPLICABLE/BELIEVED ABSENT PRESENT/DATA IS ATTACHED O X NQT APPLICABLE/BELIEVED ABSENT Q PRESENT/CATA IS ATTACHED NQT APPLICABLE Cl QX APPLICABLE/SKE ATTACHED Q NOT APPLICABLE X APPLICABLE/SEE ATTACHED X NQT APPI.I CABLE Cl APPI.ICABLE/SEE ATTACHED*Pesticide data is not required;however, it is provided. vI I v)~'-es'"=-5'".." Pn 3)cec'.'Ic out<<5)I-'scnarc)"c tc-"e s>>rfece<<aters."Jv='==7<<5."", nl5 FCRu~'"5 egos<IT"tt3BEP CAN": cg.t(O CN T>>B orNT e<(:e OF v"(.'R exoip('.c)5:5 3;e>>or nct crevicuslv per lttec iaci Il-v, tnen leave blanx anc 3 nunoer<<:I I be 3ssicnec.<<"e space Dv'o fcr edc,"age ie ticn.'.-<<escn're<vidual ciscnarce coin 3 5e"arete 5 1ust sa i'ec>>t~T=4l 5'TOTS: "'ou have.<<o cr'iore 5ub5tantlal lv Incenzlcai outfal ls.vou"av reccest cenlssicn!rm vour cere!tt(na author(tv-c Iaxp le anc snalv e cr ly one outfel I ano sufi t the results ct he and lvsi 5 or her subs'tanti el iv icen.I-al u.fbi Is.(vous"ec<<est Is orantec by."e pe~it<<lng authorltv, on a separate sheet at ached tc the application fc~)centi fv<<nicn o'.ail,ou ic test.anc case.ice>>nv the outfal ls inich vou CIC rot test sre substantial lv icentlcal-o the outfall<<n(Cn ycu Cid te5t.e~ano art I".I<c)(B), Fricav, Aprl I I~IBB3, provices icr a Sea<I='siness:xemptlon !.on the reporting of cuantltative cata Icr organic toxic pollutants anc toxic pollutants as recuired bv>art l22.I(q)<7)(ll)<A) or 122.2I<c)<7)(ill)(A). hese parts are self-exolanatory anc co not require furher instructions. Si ply go through each port anc co as lndlcatec. Several ndustrl'sl categories anc suocsteccrles nave peen exe otec'rx 5uo.I~t'"c Cata cn certain riG/us Fractions:30 Ceq Part)22,/OI.JB,"O.".-',=".IC3V,'Pr'll I.)793,'.OteS I.,)no 3:.Revie>>the fo(ic<<ing i(st to cetemine>>nether vour facility cubi)lies to ce exempt free reporting G/NS<tas Chr<xnatograonv/ uass Spectrosccpy) .=ractlons. Textile Pills Incustrv GC/u5 Fractlcn Testing and Repor, Irg Exemptions -All'our GC/uS organic fractions ln the Greiqe u(ils Suocategory. -Pesticide fraction in ail other subparts of this Incu5try.Ore Minlno and Qresslno Industry-lolatlle, base/neutral, and pesticlce fractions In tie Base anc precious uetals subcategory. -All tour Gc/us orqanic fractions In all other subcategories of this Industrv.Gun and Wood Chenicals Industry-Pesticide Fraction in the TalI Oi I Rosin Subcategory and the Rosin Based Oerivatives Subcategory. .Pesticide and base/neutral fractions In all other Subcateqories of this industry.Pulp and Paper Industry.Pesticide fraction in Paperqrade sulfite subcateoories (subparts J and U)..Base/neutral and pe5ticlde fractions in Oeink Subpart Q, Dissolvina Kraft Subpart F, and Paperboard frc<<3 Maste Paper Subpart E.-Vole!ile.base/neutral, pesticide fractions in the BCT Bleacned Kraft Subpart H, Sem(-chemical Suboarts B and C, and Nonintegrated Fine PaperS Subpart R.-Acid, base/neutral, and pesticide Fractions in Fine Bleached Kraft Subpart I, Olssolvlnq Sulfite Pulo Subpart K, Ground-wood Fine PaperS Subpart O.Harket Bleached Kraft Subpart G, Tissue frtxe Mastepaper Subpart T, and Noninteqrated Tissue Papers Subpart 5, Stean<<Electric Po>>er Plant Industry.Base/neutral fraction in the Once-Through cooling'uater, Fly Ash.and Bottc<<n Ash Transport Mater process<<astestrear<<s. 38 SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I NUMBER~i~fI 0005827 9JIFkL elJKI~00!CRITICAL PIATERIALS TOXIC)LLUTANTS USE THIS DATA SHEET TO RECORD INFORMATION AS REQJIRED INl (CHECK APPROPRIATE BOX FOR ttlICH ItIFCRtIATICN THIS""TA SITEET RE'ESFJITS ~)SECTION Ilp ITEM II-Ee GROWDWATER DISCHARGE INFORMATION (PAGE 59 CI O 2e SECT ICN I I p ITD!6e PRIORITY POLLUTANf S IN SIJIFACE WATER DISCH4RGE (PAGE~~X 3.B.BELOW: CRITICAL MATERIALS (TABLE IV)IN SURFACE WATER DISCHARGE (PAGE 39)ZARDOUS JBSTANCES IN 3ISCHARGE Be LIST AtA'RITICAL tATERIAL (TABLE IV PAGE 6)NOT ADDRESSED IN SECTION II ITEM F'RIORllY POLUJTWifs 'eettICH YOU Ieete4t OR HAVE REASON TO BELIEVE TO EE PRESEIIT IN T%DISOARGEP SEE REVERSE SIDE OF THIS PAGE FOR FUJAFR DIRECTIats. NOT APPLICABLE X APPLICABLE (SEE BELOII)K 144~I Ae NAME OF CRITICAL MATERIAL CR PRIORITY IXJLLUTA'8 B.AVERAGE CCNCEJnRATICNJ SAMPLE TYPE;¹OF ANALYSES C.AAXI W CaiCENTRAT ION Ato MASS Ae N/tAZ CF CRITeiCAL AIATERIAL OR PRIORITY POLLUTAttf B AVERAGE CaICENIRATIONJ SAMPLE lYPEl¹OF ANALYSES c..AXItlft caICENTRATION eo MASS*Sodium Hypochlorite .C L A S S 0 1/4~0~gj~]~LJ~FV~0~20'~1~17 8~4"'~3 WIT CODE SAMPLE TYPE OF ANALYSES LJ WIT CODE WIT CODE NITS CODE Mg/I Ug/I I~/DAY~/DaV IAPEE TYPE GRAB 24 HR.COMP.Ae tIAME OF CRITICAL MATERIAL OR PRICRllY POuJJTANT B~AVERAGE CCtICENIRATIONJ SAMPLE TYPE;¹OF ANALYSES Ce NAX INN CONCENIRATICN AND MASS Ae NAME OF CRITICAL MATERIAL CR PRIORllY POLLUTANT B.AVERAGE CC:ICENTPATION; SAMPLE TYPEJ".OF ANALYSES C~MAXIMA CctCENIRATICN AND MASS Ae tIAe%OF CRITICAL MATERIetL CR PRIORITY POLLUTANT Be AVERAGE CatCENTRATICNJ QPAE TYPEJ¹OF ANALYSES C~i'AAX IMYW CCtlCENTRAT ICtl AJYD MASS WIT CCDE QIANA TYPE R AF ANALYSES W T CODE WIT CODE WIT 4XXJE SAtPLE TYPE JJ OF ANALYSES WIT CODE UNIT CODE LJ~~~LJ WIT CODE SAtFLE TfPE¹OF ANALYSES WIT CODE WIT IX'GE Ae tIAME OF CRITICAL MATERIAL OR PRICRllY POLLUfANT 441<!7 B AVERAGE CaJCENIRATION; SAMPLE TYPE;OF ANALYSES C~~AXltlf8'CXICENTRATION AtO MASS Ae NAME OF CRITICAL MATERIAL OR PR(CRITY POU.UTANT 3.AvERAGE CaICENIRATICN; SAMPLE TYPEJ¹CF ANALYSES I~Ce MAX lttN CCICENIRAT ION At@I MASS WIT CODE SAJFLE lYPE iP'F ANALYSES LJ IIVI T CODE WIT CODE LJ Ueuf CODE SAMPLE TYPE 0 OF ANALYSES LJ atlT CODE Wlf CODE Ae tIAME CF CRITICAL, MATERIAL OR PRICRITY POLLUTANT~AVEPAGE CO'KENTRATIONJ SAMPLE TYPE J¹OF ANALYSES C~',~AXI"AP. CaticENTRATION A'Cl MASS*Discharged as total residual chlorine.WIT CODE SAMPLE IYPE OF ANALYSES LJ WIT CCDE WIT CODE LJ~~~LJ**Basis: ADDITIONAL PAGES CF THIS I~7 ARE ATTACIED FOR T)E REST OF THE CRITICAL Cl YES MtelERIALS AND/CR PRICRITY PCLLUTANTS REQJIRED TO BE REPORTED e El NO 1993 actual data submitted on DMRS.Average concentration based on data from May to December.39 EVS>NO'4<<5 r<<)n 0<<i~i~3 is~i<<:.5-lcn~)isc"arse sc-ecuie, ici.-e.Ic>>ra-8 snc aver-rear"ent-=""IT'K.VEER I'i TI'E BDX AT T E,CP rF Th(S F"Rs."is i 5 3 1<<>>C!CV Vr<<viou>>lv er I<<>>~3<<;(curtail;>ocr ln scace orovicea'cr eden caie"'Ior...S.S.Ce i I led Cuv.i(E<<Eou(T'<NBER CAl(BE FQ.'~D CN TRE FRONT?AGE CF YODR EXPIRING vv,~"en leave 0(snx sna s-4-oer<<Ill 08 ssslcnea.0 Section li.=cr!sc)<<civic al aischsrce cin.5 separate ser cf Enrer-ne Iccaticn ot dlscnsrge. Tn(s snouic inc)uce.ual'<<Br iudi ter SBC.icn, Suan,ei'8c Icn.5BC(ion.(own.Snd range~2.C:sr name ot recelvinc water (lt surface waver aiscnarce) ',<a(CatB wnBTner (SCI Ii~V di5Cnaraes Cn 5 5BSS ndl"OSiS.I!yes.))st alscnarge periods.E.?rcV)de the land SOp)ICar(On rateS uSea Or eXOBCVea VO Oe uSea In VermS Of inCneS Oer (.Our, rOurS per day, Snd inCneS per week.:ndicste the type ot wastewater to oe aischarqea from mls curtail.oefer o the wastewdter tyoe code given In the left.45rgin..4ore than one coae nay oe soolicdoIB ~orcvice-ne average nunoer ot hours oei:av in Rien vne'ac)i)Tv aiscnarces treated wasvewsver snd-he rcral numoer of cays cer vest.n<<nlcn vhe alscnarce occurs.orovlde current (fran the last l2 ncnrhs)cr exoectea ficw rates as recuesred. cefer ro unit code aiven In rhe lett margin fcr vne soorcoriste tlcw unirs."GY-ni(l:cn oallcnS Oer.gear: 'GD-n))l)Cn gallons oer asy;GPO-gallons oer CsV.R ovice tne maximum clscnslge flow I'atB<<nlcn vou dnT c navB suTnorlzea within vhe oennit.'x)TEi ror NpDEs oernlts cnlv, rhe use ot such s flow rate>>i i)nct ploce sn actual)(nit iesrricrlcn on vhe tlow but w)II be the i Icw rate used to ceveloc ettluent limits.Also,<<hen tne ivcnthly Doerstlng Reoorts sre reviewed by compliance staff it will helo them to cetermlne it dny new Or inCreased uSes miqht have oCcurred at the faaility.rovlde The design flow for this soeai!Ic cuvfali alsahdrae (e.g.odtcn+rearmenr SySTem flow, packaged treatment SyStem flow, or some other tinite treatment syStem tlow).ITE4 2 XATER TOEATS'IENT ADDITIVES'no)care>>nether discharge Is resrec>>lvh:cn<<:tlcners,:nnlbircrs ~0<<nicrcolcclce. It not, continue vo Item S.B.Give name, function, snd chenicdl compos)tion of additives used.Give name snd address of the manufacturer(s) ot vne additives used.'<<d)cave Bxoectea min)r~in, sveraae ana-ax)mum ciscnsrce ccncenvrations ot vhe acai.lve(s) for this alscnsrae. .~Ci are wneTher Vou Vt'Bdt Vhe diSCnarie VO r<<moVB"8 dial IVB(5)beiot'8 CiSCharae O.Wds~BWarer~.no(cate ne re oval etticlencv oi eden scaitive tron the<<ssrewater sna<<>8 Cischarae trecuenCV Of each sdai+Ive to the 5>>rface<<ster or grcuna<<ster. 'IDTEi Iv Is me resocnslbllltv of rhe aoolicsnr vo suoply tne product information ss reauested in this Iten s.Information reauesrea out nor 5uooliBd msv result ln the soollcstion baird returned to thB doolicsnt'foi co p(BT)cn, 32 'oi GREAT LAKES ENVIRONMENTAL CENTER 6i6i 941-22'0 i530 King Avenue Cc(UniDUs. Ct'lo 432 l 2 Phone i61~l 297.6801 Fax i61<)297.8666 October 12, 1993 Mr.John Carlson Indiana Michigan Power Company Cook Nuclear Plant One Cook Place Bridgman, MI 49106

Dear John:

TOXICITY TESI'EPORT FOR SULFUR HEXAFLUORIDE GAS (SF6)We have completed our analyses of the 48-hour+dgPghgia~and 96-hour fathead minnow ilhi~grggpggg static renewal-acute toxicity tests performed with sulfur hexafluoride (SF6)gas in Lake Michigan water.The Lake Michigan water sample was collected by Indiana Michigan Company personnel on September 28, 1993.The sample was transported overnight to Great Lakes Environmental Center (GLEC), and we received the sample in good condition on September 29, 1993.The g.~d'nd fathead minnow tests were conducted in accordance with GLEC Standard Operating Procedures, which are based on procedures developed by U.S.EPA (Peltier and Weber, 1990, rM T xi'n Fr hw M'm,Fourth Edition, EPA/600/4-90/027) and ASTM i v , E729-88a, 1993).T ii T wi It is our understanding that the Cook Nuclear Plant currently injects SF6 into approximately 690,000 gpm of noncontact cooling water at a rate of 5 cfm, which is equivalent to a rate of 54 pl/L of SF6 gas.The fathead minnow acute toxicity test was initiated on October 1, 1993, using an undiluted Lake Michigan water sample that was injected with sulfur hexafluoride gas at a rate of 108 pl/L (twice the plant's injection rate).The gas was injected into a sealed airtight chamber using a gas injection syringe.After injection, the sample was shaken and thoroughly mixed for one minute.This sample was then used as the highest test concentration. A reconstituted laboratory water (Hardness=172 mg/L CaCO>)was used to prepare nominal test concentrations of 54, 27, 14, and 7 pl/L SF6 gas.Twenty fathead minnows (3 days old at test initiation) were exposed for 96 hours in groups of ten, in 250 ml glass beakers, each containing 200 ml of test solution (65 x 60 mm of solution in the beakers).Each day the test solutions were carefully renewed by siphoning most of the old solutions from the beakers;freshly prepared solutions were added back to each test chamber daily and the number of surviving fish was recorded.The SF6 concentrations in the test chambers were not measured analytically. ~Applied Water Quality and Environmental Sciences Q))AEVI C Mr.John Carlson Indiana Michigan Power Company October 12, 1993 The~r~h~ni~acute toxicity test was initiated simultaneously with the fathead minnow test using identical exposure concentrations. In each g~test concentration we exposed 20 animals ((24 hours old at test initiation) in groups of five in 30 ml glass beakers, each containing 25 mls of test solution (40 x 45 mm of solution in the beakers).After 24 hours the animals were transferred to fresh solutions using a wide bore pipet, and the number of surviving or dead animals was recorded.The reconstituted water used in Q,~and fathead minnow toxicity testing is prepared according to EPAmethods f rM rin eAcu T i i f ffl n F hw r M in Qrgg~, Fourth Edition, EPA/600/4-90/027). We used dechlorinated reverse osmosis (R/0)treated municipal water for the culture of fathead minnows, and.Boardman River water (headwaters) for culturing our Q,~.Deionized reversewsmosis (R/0)treated municipal water is the base water, to which reagent-grade salts are added to prepare each batch of reconstituted water.The results of the Q.~and fathead minnow tests indicate that the sulfur hexafluoride gas injected into the Lake Michigan water sample was not acutely toxic.There was 100 percent survival of the Q.in the 7, 14, 27, and 108 pl/L SF6 concentrations, and 95 percent survival in the laboratory water controls and the 54 pl/L SF6 concentration (Table 1).Therefore, the 48-hour LC~~value was greater than 108 pl/L SF6 gas.The water chemistry data for the g.~test are summarized in Table 2.In the fathead minnow test there was 100 percent survival in the 7, 54, and 108 pl/L SF6 concentrations and in the laboratory water controls g able 3).There was 95 percent survival in the 14 and 27 pl/L test concentrations. Because there was less than 50 percent mortality in the 108 pl/L test concentration, the 96-hour LC for fathead minnows was also greater than 108 pl/L SF6 gas.The water chemistry data for the fathead minnow test are summarized in Table 4.In summary, neither Q,~du i nor fathead minnow survival was affected by any of the SF6 concentrations we tested, including the 108 pl/L (highest test concentration) and 54 pl/L (present application of SF6)test concentrations. Copies of the raw data sheets and standard reference toxicant data for the acute effluent toxicity tests are included with this report in Appendices A and B.If you have any questions or comments concerning the results of these toxicity tests, please contact either me or Mick DeGraeve at (616)941-2230.Thank you for the opportunity to provide this service to the Indiana Michigan Power Company.We appreciate your business and hope we can be of further service to you in the future.I will be in contact with you to arrange for the visit we have discussed. 'erely,;,~.,;~-//0~~Dennis J.McCauley Research Scientist DJM:dm Enclosures TABLE 1.RESIILTS OF 6 AR RM!~CIOAPXR 6 EUUA STATIC REIIEIIAL ACU'IE TOXICITY TEST III TR SULFUR SEXAFLUORIOE RAS ISFAI IRJECIEO IRIS A SAHPLE OF LAKE IIICHIGAN MATER (GLCB 1765)RECEIVED OH SEPTEHBER 28, 1993, FROH COOK NUCLEAR PLANT NEAR BRIDGHAN, HICHIGAN USING RECONSTITUTED LABORATORY MATER AS DILUTIOH MATER (TEST DATES: OCTOBER 1-3, 1993)Test Concentration (AI/L)eI ce't SUI Y val Es 0 24hr 48hr Laboratory Mater Control 7/Ll/L 14 HI/L 27 RI/L 54 HI/L 108 pl/L 95 100 100 100 100 95 100 100 100 95 100 48-hour LC~value was not calculable (greater than 108 HI/L). TABLE 2.IIAIER CHEIIISTRT UHHIART FOR A 48-IIOUR~CER OOAPH UH A STATIC REIIEIIAL ACUTE TOXICITT TEST IIITH SULFUR HEXAFLUORIOE SAS ISFAI INJECTED IHTO A SAHPLE OF LAKE kICHIGAN MATER (GLCB 1765)RECEIVED OH SEPTEHBER 28, 1993, FROH COOK NUCLEAR POMER PLANT NEAR BRIDGHAN, kICHIGAH USING RECONSTITUTED LABORATORY MATER AS DILUTION MATER (TEST DATES: OCTOBER 1-3, 1993)Test Concentrat ion (NI/L)keen Range keen Range 0 i ssol ved'xygen L Teaperature'C keen Range Specific Conductivity os cm keen~AI Al h I JI8PdII AA (mg/L CaCOs)(mg/L CaCO>)Laboratory Mater Control 7 NI/L 8.2 (8.1-8.4)8.3 (8.2-8.4)8.6 (8.0-9.0)8.6 (8.0.9.0)24.6 (24.1-25.0) 24.6 (24.1-25.0) 537 557 14 pl/L 8.3 (8.2-8.4)8.6 (8.0.9.2)24.6 (24.1-25.0) 543 27 NI/L 54 pi/L 8.3 (8.3-8.4)8.3 (8.2-8.4)8.7 (8.0-9.4)8.7 (8.0-9.4)24.6 (24.1-25.0) 24.7 (24.2.25.0) 511 445 108 AI/L 8.2 (8.1-8.4)9.0 (8.0-9.8)24.8 (24.3-25.0) 128 keasurements vere made daily in each test charber.A single measurement Has made at the beginning of the test on a coaposite saapie before distribution to the test chacbers and at the end of the test on a cceposite sample.Alkalinity and hardness measurements vere made upon preparation of the reconstituted laboratory Mater and upon arrival at the laboratory of the effluent.

TABLE 3.RESULTS OF A 96-HQJR FATHEAD HIHHOM STATIC REHEMAL ACUTE TOXICITY TEST MITH SULFUR HEXAFLUORIDE GAS (SF6)INJECTED IHTO A SAHPLE OF LAKE IIICHIGAN MATER (GLCB 1765)RECEIVED OH SEPTEHBER 28, 1993, FROH COOK NUCLEAR POMER PLANT NEAR BRIDGHAN, ilICHIGAH USING RECONSTITUTED LABORATORT MATER AS DILUTIOH MATER (TEST DATES: OCTOBER 1-5, 1993)Test Concentration (aI/L)24hr ece Suvval H~0 48hr 72hr 96hr Laboratory Mater Control 7 HI/L 14 HI/L 27 HI/L 54 HI/L 108 III/L 100 100 100 100 100 100 100 100 100 100 100 100 100 95 100 100 100 100 95 95 100 100 96-hour LCso value uas not calculable (greater than 108 HI/L). TABLE 4.MATER CHENISTRY SLNB(ARY FOR A 96-HOUR FATHEAD HINNOM STATIC RENEMAL ACUTE TOXICITY TEST Ml'lH SULFUR HEXAFLUORIDE GAS INJECTED INTO A LAKE NICHIGAN MATER SANPLE (GLECN 1765)RECEIVED ON SEPTENBER 28, 1993, FRON COOK NUCLEAR PLANT NEAR BRIDGHAN, NICHIGAN USING RECONSTITUTED LABORATORY MATER AS DILUTION MAIER (TEST DATES: OCIOBER 1-5, 1993)Test Concentration (NL/L)Old Dissolved'xygen L OLd Teaperature' Neu OLcl Speci f ic'onductivity os cm Neu OLd~kkk I k~rdn (mg/L CaCO>)(mg/L CaCO>)Laboiatoly Mater Control 7 NL/L 1C liL/L 27 NL/L 54 lil/L 108 ltL/L 8.2 (8.2-e.C)8.1 (7.9-e.2)8.3 (8.2.8.3)8.2 (8.2-8.3)8.1 (S.1-8.2)8.1 (8.0.8.2)8.1 (8.1-8.2)8.0 (7.C.8.2)8.3 8.1 (8.2-8.C)(7.9-8.2)8.3 8.2 (8.2-8.3)(8.1.8.2)B.S (8.8.8.9)8.9 (8.8-9.0)9.0 (9.0.9.2)9.1 (8.9.9.4)9.2 (9.0-9.4)9.8 (9.6-10.2) 6.9 (6.2-7.5)7.5 (7.1-8.0)7.4 (6.6-e.o)7.1 (6.5-8.0)7.2 (6.9-7.6)7.5 (7.4-7.6)25.0 (25.0.25.0) 24.6 (24.2-25.1) 25.0 24.6 (25.0-25.0) (24.3-25.1) 25.0 24.6 (25.0.25.0) (24.0-25.1) 25.0 24.6 (25.0-25.0) (24.1-25.2) 25.0 24.6 (25.0-25.0) (24.2-.25.3) 25.0 24.6 (25.0-25.0) (24.2-25.2) 537 (494-566)556 (537-587)539 (531-557)514 (502-516)444 (4C0.450)311 (303-316)539 (539-539)547 (547-547)531 (531.531)502 (502-516)438 (438-438)304 (304-304)104 (104-104)106 (106-106)172 (172-172)128 (128-128)Ileasurements uere made on neu test solutions and old test solutions. The nurbers represent the mean and range (in parentheses) of measurements observed during the test.Alkalinity and hardness measurements Mere made upon preparation of the reconstituted laboratory eater and upon arrival of the sample. APPENDIX A RA~V DATA SHEET C'RS~w~a'a t SRSRIRlhRl688888888RlklhlRlbbRRf 5 HRHRlHHHHIWRRSHpHHRRHSHHHHH5 WRWRRERSWESRRESRRSISWSRRIRE 0~I a y~~e~RHKSKRHRRERRRI RHRRIRQ'5SRHRRfREI RKKIR HRSSSHSHRIHIHSIHHHRRRHWWWRS 5ERRSQERQE5$ %85$ldl'5$5QRRE 'I'cat hlslco~t:)'ls j I Nu..I cst SII I~k lwihlll Wjlk.QA I L f PE A)2~i-'I-FlSal 96-llOUR STA;tJQ Type of Test: 0 No.Fish/Chantbcr: 0 No.of Chambers: Agc of Fish: CUTE TOXlClTY TEST Dilutiun Water: GLC and/or Batch No.: jl Tcntpcraturc: c)ncubalor 4: 2c~"c ,O'i rj 6/(I Iau Test Day Tech.)nil.Trcsltncnl vcl Rcplicatc Number.Control Tcm craturc DO miIL S.Cond.umhos/cm No.Live 10 (0 JO I CI/0 g'0 Obsarvau sns j 05 oss I'i7 0 II).Q~)7 0 gl7 d,z't C'J I DO m'IL Tcln cralurc No.Live DO m/L 1 7 V RZ Zg 2 lg.Q L l.Z 0 0 f g'17]g 2>.v qn.7 8-+~f/l~l'll'r yO Tcm cralurc No.Live Obscrvaltons Tcm cralurc No.Live Observations DO m II.S.Cord.umhos/cnt 0 IO IO 2g 7./,f'.0 T.0 rj~7 n 1 l Cf aS.C 7, I zo C//+rfjvrz>,/~n C K-/0 t)hicrvstuu< hcy: DOS-Drie Oul uu ScsLcr PM-Paniculstc Msucr ERR-Erratic Swimmin Rcvicwcd by: FS-Film on Surface F-Floater)MM-bnmobilc ~. EFFLUENT Ai%)RECEIVING WATER CHECK-IN FORM Client:(t"C I-'4'ICI00-4 project No,: Investigators: INITIAL WATER CHEMISTRY (UPON RECEIPT)Date Initials GLC No.Collection Date (time interval)Temperature pa~WATER CHEMISTRY AT TEST TEMPERATURES Date: GLC No.Temperature pH Dissolved Oxygen (mg/L)Conductivity (umhos's/cm) Hardness (mg/L)Alkalinity (mg/L)Total Chlorine (mg/L)*Total Ammonia (mg/L)*Initials CcnC tutjcl<z Y/7$'~/DQ Check with project manager to see if necessary

Lrekee Envirnnrnenkrl Cenler C 739 I tastings Street Trarerse City, MI 49684 Phone: (616)941-2239 Fax: (616)941-22AO CHANC OF CUSTODY RKCO14B 9 O BE COMPLETED ON-S)TE AND SUBMITI'ED Wm)SAMPLES)Facility:.C~+++'/~~~+./c4.Location;re~~~~e e.'rf c'p&re.AM&Contact Person:~-~C>r.~~-a Phone Number: re a&~~So~Co0ector: Date Witness: Date:-z-.s-'V3 r z 1 c iO SAMPLE ID (8-ZggC./q,4nr g DATE/I'IME OF SAMPLE i.;.-~S/io VOLUME SAMPLE SAMPLE COLLECTED COLLECTOR CONTAIN)UK .(I--M.c~e~~a DESCRIPTION (Type of sample, source, physical characteristics) PRESE RYATION ANALYSES REQUIRED ver>7 rr Cr TRANSFER OF SAMPLES: (First signature is sampler, lust silenature is authorized laboratory representative.) 1.2e 5LHXF)L~~i P~r'-zs-g3 V7~nii f ml l n<0 less than 100K effluent., The letter modification of the Cook Plant NPDES Permit was conditional on the study plan being approved by the MDNR.MDNR notified Z&M by letter dated July 16, 1992 that the study plan was acceptable. Treatment of the Cook Plant for zebra mussel control has evolved from attempts to treat the entire plant in one operation to treating components of the plant in separate operations. The intake tunnels are treated individu-ally, the circulating water system is treated as one system and components of the essential service water (ESW)and'on-essential service water (NESW)systems are treated as needed.Treatment Pro ram Com leted In 1992 The north and center intake water tunnels were treated with Clam-Trol on August 12 and 13 and September 11 and 12, 1992, respectively. The circula-ting water system was treated on September 16 with Clam-Trol. Water samples were collected during each of these three periods as described in the ap-proved study plan.These samples of detoxified effluent were split and then shipped to a contract laboratory and to the MDNR toxicity testing laboratory for analyses.The contract laboratory conducted a 48-hour acute toxicity test using~pa hnia fulex on each of the three water samples.At the same time the detoxified effluent samples were being analyzed, a series of ben-tonite clay solutions were being tested for impact on the test organisms. ~Da hnia sp.and other zooplankters can be adversely affected by mechanical (rather than chemically toxic)means when exposed to excessive amounts of suspended clay.These clay blank test series were conducted using Lake Michigan water and the same clay used to detoxify the Clam-Trol. Lake Michigan water used for dilution of the detoxified effluent tests and the clay blank tests was collected before the Clam-Trol treatments began. ~' Methods 0 Water samples were collected from the discharge tunnel manways using a submerged pump at the beginning of the treatment, at the fourth hour, at the eighth hour and at the twelfth hour of treatment. Samples were collected from Unit 2 discharge manway and composited in one container. At the end of the test, a sample was removed from the composited sample container and shipped to the contract laboratory. During treatments to the north and center intake tunnels on August 12-13 and September 11-12, 1992, there was no effluent from the Unit 1 discharge.tunnel.During the circulating water system treatment on September 16, samples were collected from both the Unit 1 and Unit 2 discharge tunnel manways and composited into one container, from which the water for WET testing was taken.The laboratory followed the procedure for conducting 48-hour EC50 acute toxicity tests according to the EPA protocol,"Method for Measuring the Acute Toxicity of Effluent to Freshwater and Marine Organisms," EPA/600/4-85/013. A dilution series of 100X, 50X, 25X, 12.5X, 6.25X and OX (control)effluent was set up.Lake Michigan water filtered to remove native zooplankton was used for dilution.Four 30 ml beakers were set up for each test concentra-cion and 25 ul oi test solution uas put in each beaker pive.~Da hnia Dulex juveniles (<24 hours old)were placed in each beaker.Temperature was.~maintained at 25'+1 C.Temperature, DO, and conductivity were measured every 24 hours.The effects were recorded every 24 hours.Organisms that failed to remain in the water column for five seconds after a gentle prod or swirling the beaker were considered effected.Results are reported as acute 48-hour EC5 values. A test series of bentonite clay blanks was conducted the same as the detoxi-fied Clam-Trol effluent.t'iltered Lake Michigan water was mixed with the same concentration of bentonite clay used to detoxify the Clam-Trol. This concentration of bentonite clay was tested at 100X, 50X, 25X, 12.5X, 6.25X and OZ (control). Results Whole Effluent Toxicity tests were conducted August 15 through 17, September 13 through 15, and September 17 through 19, 1992.Table 1 shows the immobility percentages of the detoxified Clam-Trol effluent and the bentonite clay blank test concentrations. Immobility results exceeded the EC50 for 100Z effluent at all detoxified effluent and clay blank test concen-trations.The highest immobility result was 30Z for the detoxified Clam-Trol effluent samples and 25X for the bentonite clay blanks at the 100X effluent concentration. One test series was technically invalid because the control (OX effluent)had>10X immobility. Except for the immobility observed at the control concentration in the detoxified effluent test conducted on September 13-15, toxicity was low and the immobilities that were observed followed a similar pattern as the clay blank test series.Immobility per-centage differences between the detoxified Clam-Trol and clay blank test concentrations were usually 5Z or less.Discussion The 70X immobility value obtained for the control test on September l.3-15 would appear to be an anomolous value, since the bentonite clay blank control e using Lake Michigan water supplied to the contract laboratory in the same shipment showed OX immobilitye Three of the four control replicates showed all or nearly all test organisms vere immobilized and in one of the four replicates none of the organisms were immobilized during the 48-hour test.An examination of the laboratory sheet for the treatment concentrations shows that the organisms in the replicates were immobilized in nearly equal num-bers, e.g., the 50X and 100X effluent replicates had one or two immobilized e organisms. None of the treatment replicates individually accounted for all of the immobilities, which would indicate a contaminated replicate. The immobilities were equally distributed among the replicates. There is no water quality parameter that vas measured before, during, or after the toxicity test that indicates a problem for~Da hnia pulex's well being.Given the general lack of immobilization response of organisms in the dif-ferent treatment concentrations tested on any given date and the similarity of test results from one test date to the nest, there vas little difference between the detoxified Clam-Trol effluent and the bentonite clay blanks effects on the test organisms. All tests were in compliance with the re-quirement that the 48-hour EC for~pa hnia exceed 100Z effluent.in other vords the tests shoved that effluent toxicity vas less than the toxicity needed to produce an EC>0 in 100X effluent.The lack of toxicity indicates the detoxified effluent had little impact on the Lake Michigan aquatic community.

TABLE 1~Da hnia pulex 48-hour Pereenr Immoblllry Values Obtained from Whole Effluent Toxicity Tests Conducted with Detoxified Clam-Trol in Lake Michigan Water and Bentonite Clay Blank Test Run in Lake Michigan Water (clay blank immobility percentages in parentheses) Test Date Control (OX)6.25X 12.5X 252 502 l002 Aug 15-17 OX (OX)OX (OZ)OX (10X)15X (OX)OX 25X (10X)(5X)Sep 13-15 70Z (OX)OX (5X)15X (10X)20X (25X)30X (20X)30X (25X)Sep 17-19 OX (5Z)OZ (5Z)10X (5X)10X (5X)5X (OX)15X (5X) ANALYTXCAL REPORT Cook Nuclear Proj: Waste Water Analysis Subm: Jan 26 Samples Submittal Number: 29609-3 Location: Contact: Ray V.Buhl Phone: (616)942-9600 Outfall 001 Outfall 002 Circ.Intake Detection Units Limit WWES Sample No: 78371 78372'8373 BOD, (5-Day)Sampled by: Date Sampled: Time Sampled: Date Received: Time Received: (1.0 01/26/94 00 00 01/27/94 13:30 (1.0 01/26/94 00 00 01/27/94 13:30 (1.0 01/26/94 00 00 01/27/94 13:30 1.0 mg/1.)')).)(II<'11N'<l<)d llllis I arkKval SI'I'()l3<)'><874.(Iraad Rapids.Ill 49588-0874. 6 I 6/942-<J600 I'0%9-!2-li~! llll I n V>Ctrl>F-Snl'ru'e i illllllllli (.)IIII/Allo STATEMENT OF DATA QUALIFICATIONS CLIENT: Cook Nuclear SUBMITTAL: 29609-3 All analyses have been validated and comply with our Quality Control Program.No qualifications required.The following analyses have been qualiTied for the reasons cited.KEY l.2.3.4, 5.6.7.8.9.10.Sample integrity suspect upon receipt (explain). Analysis performed beyond EPA established maximum allowable holding time.Detection limit elevated due to matrix interferences. Laboratory control sample value outside established acceptable limits.Matrix spike sample value outside established acceptable limits.Duplicate analysis value outside established acceptable limits.Surrogate/internal standard recoveries outside established acceptable limits.Data point suspect due to potential laboratory contamination (explain). Coelutes with the compound cited.Result may represent a combination of both compounds. Other (explain). Noler This document is included as part of the Analytical Report for the above referenced and should be retained as a permanent record thereof.5555 Glenwood Illlls Parkway St',.t'0 Box 874.()rand Rapids.Atl 49588-08?4. 6 l6/942-9600 t'nx 9 t'-'-6.l99

lt'1 1'n<~ul((I'uI~~8-'(7('ll('(' .~nlnnn(<ann+.in'I.l'I'(: X I, 5 I:.I'I (.':..ANALYTICAL REPORT Cook Nuclear Proj: Waste Water Analysis Subm: January Samples Submittal Number: 29609-4 Location: Contact: Ray V.Buhl Phone: (616)942-9600 Outfall Outfall 001-Circ 002-Circ Water Dsch Water Dsch Circ Water Detection Units Intake Limit WWES Sample No: 78532 78533 78534.Surfactants,-.NBAS Coliform, Fecal Color (Apparent) Sampled by: Date Sampled: Time Sampled: Date Received: Time Received:<0.025 2<5 V.Shah 01/26/94 00 00 01/28/94 00 00.<0.025<1<5 V.Shah 01/26/94'0'00 01/28/94 00 00<0.025 4<5 V.Shah 01/28/94 00 00 0.025 1 5 mg/1 cl/100ml e pH 5555 (Ilenn'()n(l Iiills Purkway SE.PO Box 874.(Irdnd RnPids.All 49588-0874. 6I6/942-9600 I';>x ll I2-(i.l9I

1V1V I:rg>mar<<~>&Sne<<ce i.v>>>>1>N(4>>>>p>j>l STATEMENT OF DATA QUALIFICATIONS A 5 A I, Y'I'(:,K I, 8 l'.R t I (: f'CLIENT: Cook Nuclear SUBMITTAL: 29if09<All analyses have been validated and comply with our Quality Control Program.No qualifications required.The following analyses have been qualiTied for the reasons cited.Sample No.(s): Explanation: Reason:~KEY l.2.3.4.5.6.7.8.9.10.Sample integrity suspect upon receipt (explain). Analysis performed beyond EPA established maximum allowable holding time.Detection limit elevated due to matrix interferences. Laboratory control sample value outside established acceptable limits.Matrix spike sample value outside established acceptable limits.Duplicate analysis value outside established acceptable limits.Surrogate/internal standard recoveries outside established acceptable limits.Data point suspect due to potential laboratory contamination (explain). Coelutes with the compound cited.Result may represent a combination of both compounds. Other (explain). Note: This document is included as part of the Analytical Report for the above referenced and should be retained as a permanent record thereof.5555 (ileum>od lt Ills Parkway St,".PO Box 874.(irand Rapids.Itl 49588-0874 ~616/942-9600 Vas 9-t2>-tijou

Lockheed Analytical Services DATA QUALIFIERS FOR INORGANIC ANALYSES (Revised 08/28/92J B D E H M N U X, Y,orZ al bi For Use on the Analytical Data Reporting Forms For CLP Analyses Only-Reported value is less than the contract required detection limit (CRDL)but greater than or equal to the instrument detection limit (iDL).For Routine, Non-CLP Analyses Only-Any constituent that was also detected in the associated blank whose concentration was greater than the reporting detection limit (RDL).Presence of high levels of interfering constituents required dilution of sample which increased the RDL by the dilution factor.Estimated value due to presence of interference. Sample analysis performed outside of method-or client-specified maximum holding time requirement. For CLP Analyses Only-Duplicate injection precision criterion was not met.Matrix spike recovery exceeded acceptance limits.Reported value was determined from the method of standard addition.For CLP Reporting Only-Constituent was analyzed for but not detected (sample quantitation must be corrected for dilution and percent moisture). For AAS Only-Post-digestion spike for Furnace AAS did not meet acceptance criteria and sample absorbance is less than 50%of spike absorbance. Analystdefined qualifier. Relative percent difference (RPD)for duplicate analysis exceeded acceptance limits.Correlation coefficient (r)for the MSA is less than 0.995.'-..For Use on the QC Data Reporting Forms'he spike recovery and/or RPD for matrix spike and matrix spike duplicates cannot be evaluated due to insufficient spiking level compared to the elevated sample analyte concentration. The RPD cannot be computed because the sample and/or duplicate concentration was below the RDL.'sed as footnote designations on the QC summary form. Lockheed Analytical Services DATA QVALIFIERS FOR ORGANIC ANALYSES fgÃvkaf:;:"Og/X98$ 94J For Use On The Analytical Data Reporting Forms A B H N U X, Y,orZ N/A (%Moisture)For CLP analyses Only-The TIC is a suspected aldol-condensation product.Any constituent that was also detected in the associated blank whose concentration was greater than the practical or reporting detection limit (PQL or RDL).Constituent confirmed by GC/MS analysis.Ipesticide/PCB analyses onlyJ Constituent detected in the diluted sample.It also indicates that an accurate quantitation is not possible due to g~rggg~being diluted out of the samples during the course of the analysis.Constituent concentration exceeded the calibration range.The quantitation is not gasoline or diesel but believed to be some other combination of hydrocarbons. Sample analysis performed outside of method-or client-specified maximum holding time requirement. Estimated value-(1)constituent detected at a level less than the RDL or PQL and greater than or equal to the MDL;(2)estimated concentration for TICs (For CLP Reporting Only).For CLP Reporting Only-Tentatively identified constituents PICs)identified based on mass spectral library search.For CLP Reporting Only-The percent difference between the concentrations detected on both GC columns was greater than 25 percent/pesticide/PCB analyses only J.For CLP Reporting Only-Constituent was analyzed for but not detected (sample quantitation must be corrected for dilution and percent moisture). Analyst-defined qualifier. N/A in the%moisture cell indicates that data are reported on an"as received" basis.A value in the%moisture cell indicates that data are reported based on a"dry weight" basis.For non-CLP wort, RDLs are not adjusted for%moisture even when data are reported on a"dry weight" basis.al...;:.:=:,-For;Use On The QC Data Reporting Forms QC data (i.e., percent recovery data for matrix spike, matrix spike duplicate, laboratory control standard, or surrogates; and RPD for matrix spike duplicate or unspiked duplicate) exceeded acceptance limits.The spike recovery and/or RPD for matrix spike and matrix spike duplicates cannot be evaluated due to insufficient spiking level compared to the elevated sample analyte concentration. The RPD cannot be computed because the sample and/or duplicate concentration was below the RDL.'sed as footnote designations on the QC Summary Form. Lockheed Analytical Services DATA QUALIFIERS FOR RADIOCHEMICAL ANALYSES/Revised 08/28/92J B H al bi For Use on the Analytical Data Reporting Forms Any constituent that was also detected in the associated blank whose concentration was greater than the reporting detection limit (RDL)and/or minimum detectable activity (MDA), Presence of high TDS in sample required reduction of sample size which increased the MDA.Constituent detected in the diluted sample.Constituent concentration exceeded the calibration or attenuation curve range.For Alpha Spectrometry Only-FWHM exceeded acceptance limits.Sample analysis performed outside of method-specified maximum holding time requirement. Chemical yield exceeded acceptance limits.';.-': For Use on'the QC'Data Reporting ForIns',"...',"',',"','C data (i.e., percent recovery data for laboratory control standard and matrix spike;and RPD for replicate analyses)exceeded acceptance limits.The spike recovery and/or RPD for matrix spike and duplicates cannot be evaluated due to insufficient spiking level compared to the elevated sample analyte concentration. The RPD cannot be computed because the sample and/or duplicate concentration was below the MDA.'sed as foot note designations on the QC summary form. GENERAL CHEMlSTRY RESULTS Client Sam le ID: OUTFALL 001 Date Collected: 01-24-94 Matrix: water LAL Batch ID(s): 126 im Date Received: 01-26-94 PO469095-040-3N Constituent Method Result Reporting Detection Umlt Data Qualiflarls) Date Anal zad LAL Sam la ID Fluoride, in m IL Bromide, inm IL Nitrite-Nitrate-Nitrogen, inm IL 340.2<0.15 353.2 0.35 300.0'0.050 0.15 0.050 0.050 03-02-94 L11 31-8 01-28-94 L1 131-16 02-1 1-94 L1 1 31-21 Sulfate, inm IL Total C anide, inm IL Total Phenolics, in m IL Sulfide, inm IL 300.0 335.2 420.1 376.1 22<0.020<0.15<1.0 0.059 0.020 0.15 1.0 01-27-94 L1 1 31-1 6 01-27-94 L1131-25 02-08-94 L1131-30 01-27-94 L1131-11 Comments: GENERAL CHEMISTRY RESULTS Client Sample ID: OUTFALL 001 CIRC WATER LAL Batch ID(s): 126 im, 127 im Date Collected: 01-26-94 Date Received: 01-27-94 Matrix: whter P0 469095-040-3N Constituent Total Phosphorus, in m/L Ammonia Nitrogen, inm IL Total Suspended Solids, inm IL Total Organic Carbon, in m IL Chemical Oxygen Demand, inm IL Total Kjeldahl Nitrogen, in m/L Method 365.2 350.1 160.2 415.2 410.2 351.2 Result (0.030<0.050 (12 1.8 (18 0.20 Reporting Detection Umlt 0.030 0.050 12 1.0 18 0.10 Deto Ouellflerls) Date Anal ed 02-08-94 02-01-94 02-02-94 02-16-94 01-28-94 03-03-94 LAL Sem le ID L1142-5 L1142-5 L1 142-9 L1142-1 L1142-1 Ll 142-5 Comments: GENERAL CHEIVllSTRY RESULTS Client Sam le ID: OUTFALL 001 Date Collected: 01-27-94 Matrix: water LAL Batch ID(s): 128 im Date Received: 01-28-94 PO469095-040-3N Constituent Method Result Reporting Detection Umlt Data Qualifie(s) Date Anal ed LAL Sam le ID Color Sulfite, in rng/L 1 10.3 377.1<5.0<1.0 5.0 1.0 01-28-94 L1151-1 01-29-94 L1151-1 Comments: CQC METALS RESULTS Client Sam le ID: OUTFALL 001 LAL Batch ID(s): 126 im Date Collected: 01-24-94 Date Received: 01-26-94 Matrix: water POI)'69095-040-3N Constituente Method Concentration (m IL)Reporting Detection umit lm lL)Date Qualifier)a) Date Anal zed LAL Sam le ID Aluminum Antimon Arsenic Barium Ber Ilium Boron Cadmium Chromium Cobalt Co er Iron Lead Ma nesium Man anese Mercur Mol bdenum Nickel Phos horus Selenium Silver Strontium Thallium Tin Titanium Uranium Vanadium Zinc 6010 6010 7060 6010 6010 6010 6010 6010 6010 6010 6010 7421 6010 6010 7470 6010 6010 6010 7740 6010 6010 7841 6010 6010 6020 6010 6010<0.20<0.060<0.010<0.20<0.005<0.20<0.005<0.010<0.050<0.025<0.10<0.003 12<0.015<0.0002<0.067<0.040<0.050<0.005<0.010 0.13<0.010<0.20<0.10<0.001<0.050<0.020 0.20 0.060 0.010 0.20 0.005 0.20 0.005 0.010 0.050 0.025 0.10 0.003 5.0 0.015 0.0002 0.067 0.040 0.050 0.005 0.010 0.10 0.010 0.20 0.10 0.001 0.050 0.020 02-22-94 L1 1 31-94 02-22-94 L1 131-94 02-20-94 L1 131-94 02-22-94 L1 131-94 02-22-94 L1 1 31-94 02-22-94 L11 31-94 02-22-94 L1 131-94 02-22-94 L1 131-94 02-22-94 L1131-94 02-22-94 L1131-94 02-22-94 L1 131-94 02-23-94 L1 131-94 02-22-94 L11 31-94 02-22-94 L1 131-94 02-09-94 L1 131-94 02-22-94 L1131-94 02-22-94 L11 31-94 02-22-94 L1 131-94 02-25-94 L1131-94 02-22-94 L1 131-94 02-22-94 L1 131-94 02-28-94 L1 1 31-94 02-22-94 L1 131-94 02-22-94 L1131-94 03-07-94 L1131-94 02-22-94 L1 1 31-94 02-22-94 L1131-94 Comments: VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 1 of 2 Clien S m I ID: TFALL 0 1 D e C llec ed: 24-AN-4 Matrix: WATER Anal tical Batch¹: 020394-8260-J-2 QC Batch ID: 020394-8260 LAL S m I ID: L11 1-41 Da e.Receive: 2-JAN-4 Date Anal zed: 03-FEB-94 Dilution Factor: 1 SURRO ATE RECOVERY o QC Limits 1 2-Dichloroethane-d4 Tol ene-d 4-Bromofluorobenzene 98 97 76-114 86-115 Con ti e Chloromethane Vin I Chloride Brmm hn hir hn Trichlorofluoromethane Acetone 11-Di hl r h n r n Di Ifi Meth lene Chloride trans-1 2-Dichloroe hene Vin I A 11-Di hl r h n 2-Butanone cis-1 2-Dichloroe hene hlr frm 111-Trihi r h n Carbon Tetrachloride 1 2-Dichloroethane B nz n Tri h 1 2-Dichloro ro ne Bromodichlorome h ne hl r h IVin I h r 4-M hl--n cis-1 3-Dichloro ro ene Toluene rn-1-Dihl r r n-H x n n 1 1 2-Trichloroethane Tetrachloroethene PCE Concentration L<5<5<5<10<5<5<10<5<5<5<5<5<2<5<5<5<5 Reporting Detection Limit L 10 10 De Q'ifier 14 L LOCKHEED AIVALYTICAL SERVICES

VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING IVIETHOD 8260 Client Sam le ID: OUTFALL 01 LAL Sam le ID: L1131-41 Page 2 of 2 Constituent Dibromochloromethane hlr n n h I n n m-X lene o-X lene Concentration IL<5<5<5 Reporting Detection Limit IL Data Qualifier s Srmfrm 1 1 2 2-Tetrachloroethane 1 3-Dichlorobenzene 14-Dihl r nz n 1 2-Dichlorobenzene <5<5<5 LOCKHEED AhfALYTICAL SERVICES VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 TENTATIVELY IDENTIFIED COMPOUNDS Client Sample ID: OUTFALL 001 Date Received: 264AN-94 Matrix: WATER Analytical Batch: 020394-82604-2 LAL Sample ID: L1131%1 Date Analyzed: 03-FEB-94 Dilution Factor: 1 QC Batch ID: 020394-8260 Tentatively Identified Compound NO COMPOUNDS IDENTIFIED Estimated Concentration Iyg/L)Retention Time lminutes)Data Qualifier(s) LOCKHEED AIVALYTICAL SERVICES SEIVIIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Pa e 1 of 2 Clien S m I ID: OUTFALL 001 Date Collected: 24-JAN-94 Matrix: WATER Anl i IB h4': 2 4-7-A QC Batch ID: 8270-SEMIVOLATILE 4825 LAL Sam I ID: L1131-55 Date Received: 26-JAN-94 Dilution Factor: 1 Da Ex r: 1-JAN-4 Date Anal zed: 03-FEB-94 SURRO ATE RE OVERY Y 2-Fluoro hanoi Phenol-d, Nitrobenzene-d, 2-Fluorobi hen I 24-Tri r mo h n I p-Terphenyl-d 27 22 64 57 48 37 0 Limi 21-100 10-94 35-114 43-116 33-141 Phenol n'Concentration L<10 Reporting Detection Limit 10 De lifi s bis 2-Chloroe h I ether hlr hnl 1-Dihl r nz n 1 4-Dichlorobenzene Benz I alcohol 1-Dihl r n-M h I h n I bis 2-Chloroiso ro I e her 4-Me h I henol N-Ni r-Di-n-r I in Hx hlr hn Nitro benzene Iso horone-Nir h n I 4-Dim Benzoic acid bis 2-Chloroethox me hane 4-Dihi r h n I 1 4-Trihl r n n Na h halene 4-Chloroaniline H hlr in 4-hlr--m hlhnl 2-Meth Ina h halene Hexachloroc clo entadiene<10<10<10<10<10<10<10<50<10<10<10<10<10'0 10 10 10 10 10 10 50 10 10 10 10 10 LOCKHEED ANALYTICAL SERVICES SEMIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Client Sam le ID: OUTFALL.001 LAL Sam le ID: L1131-55 Pa e2of2 Constituent 24-Trihl r hn I 4-Trihlr hn I 2-Chlorona hthalene 2-Nitroaniline Dim h I h h I A n hhin 2 6-Dinitrotoluene 3-Nitroaniline A n hhn 4-Dini r h n I 4-Nitro henol Dibenzofuran '4-Dini r I n i hlhhl 4-Chloro hen I-hen le her Fluorene 4-Ni r nilin 4-Dinir--m I h n I N-Nitrosodi hen lamine 4-Bromo hen I-hen le her Hx hlr nzn Pn hlr hnl Phenanthrene An hracene r I Di-n-I hh I Fluoran hene P rene 8 I n I hh I'-Di h r Benzo a an hrac n Chr sene i-hlhx Di-n-I hh I Benzo b fluoranthene Benzo k fluoranthene Bnz rn Concentration I IL)<10<25<10<25<25<10<10<10<10<10<10<10<10<10<10<10<10<10 Reporting Detection Limit I IL)10 25 10 25 25 10 10 10 10 10 10 10 10 10 10 10 10 10 Data Qualifierls) In n 1 r n Dibenz a h anthracene Benzol h i)er lene<10<10 10 10 LOCKHEED ANALYTICAL SERVICES

SEMI-VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8270 TENTATIVELY IDENTIFIED COMPOUNDS Client Sample ID: OUTFALL 001 Date Received: 264AN-94 Matrix: WATER Analytical Batch: 020394-8270-A LAL Sample ID: L1131-55 Date Analyzed: 03-FEB-94 Dilution Factor: 1 QC Batch ID: 8270 SEMIVOLATILE 4825 Tentatively Identified Compound NO COMPOUNDS DETECTED Estimated Concentration (yg/L)Retention Time (minutes)Data Qualifierls) LOCKHEED AIVALVTICAL SERVICES

OIL AND GREASE EXTRACTABLES ANAI YSIS RESULTS BY FT/IR USING METHOD 413.2 Client Sam le ID: OUTFALL 001 Date Collected: 24-JAN-94 D R iv:2-AN-4 M rix W Anal tical Batch¹: 020494-413.2 LAL Sam le ID: L1131-75 Date Anal zed: 07-FEB-94 Dil inF r 1 D r-F B-4 QC Batch ID: 020294-413.2 Constituent Oil and Grease Concentration m L Reporting Detection Limit Data Qualifier(s) LOCKHEED ANALYTICAL SERVICES PESTICIDE ANALYSES RESULTS BY GC/ECD USING METHOD 8080 li n S m I ID: TFALL-0 1 D oil: 4-AN-4 Date Extracted: 31-JAN-94 Matrix: WATER Analytical Batch¹: 013194-.8080-E-4 LAL m I ID: L11 1-D e Re eiv: 2-AN-94 Date Anal zed: 01-FEB-94 Dilution Factor: 1 QC Group ID: 8080 PEST/PCBS 4822 S RRO ATE REC VERY TCMX DCB 50 39 QC Limits 60-1 50 60-150 Constituent Concentration Reporting Detection Limit Data Qualifier(s) A-BH B-BHC G-BHC D-BH H PTA HL R ALDRIN HEPTACHLOR EPOXIDE HL R DANE END FAN I A-CHLORDANE 4 4'-DDE 4 4'-DDT DI LDRIN ENDRIN ENDOSULFAN II 4'-DDD NDRI A D HYD ENDOSULFAN SULFATE METHOXYCHLOR T XAPH NE P-1 1 PCB-1221 PCB-1232 P B-1 42 P B-1 4 PCB-1254 PCB-1260 TECHNICAL CHLORDANE<0.05<0.05<0.05<0.05<0.05<0.1<0.1<0.1<0.1<0.5<2 0.05 0.05 0.05 0.05 0.05 0.1 0.1 0.1 0.1 0.5 14.LOCKHEED ANAL Yl'ICAL SERVICES RAO OATA REPORT (ra01)Indiana Hichigan Pomr Co.e Bridgman,NI Organic and Inorganic Contaeinanta (Project C(XX.JENI) Client Sangria IO: OITFALL 001 LAL Sanpla IO: L1131.b5 Hatrixt llater Oate Collected: 24.JAN.94 Oate Received!26.JANE 94 Login Nuaber: L113'I 8%3FCo()akl ttientg""44Mi@KN~>w "~Anal)Iaed:"' SetcIT~<-~5~~i'"" Qi'F:."'<~)'..'".""."Acti Vf>Q',5.'rotg~gj'N@:-:. ~~i>Oatmeal':::~lUnita;.".,'.Gross Alpha Grosa Beta 23-FEB 94 GR ALP/BETA LAL~0060 4756 23.FEB.94 GR ALP/BETA LAL.0060 4756 0.4 3.2 1.1 1.5 2 2.2 pCi/L pCi/L Page 6 RAD DATA REPOP.T (ra01)lndfana lffchfgan P~r Co.~Brfdgman,NI Organfc and lnorganfc Contaninanta (Project CNX.JEkf)lfatrfx: Rater CI fent Sarpfe lOs OUTFALL 00'I Date Collected: 24.JAk.94 LAL Saepfe ID: L1131-89 Octa Recefvedt 26.JAk.94 Logfn ktnhert L'l13'I Ra-226 Ra-228 22-FEB-94 RA 226 LAL-0073 4771 23-FEB.94 RA 228 LAL-0074 5503 0.02 0 11 0 22 3 0.44 0.59 pCI/L pCI/L Page 10 PH Meter CPC/P lOL-Cal date due Sample Time Sample g Sample Date CDM Entered by PH Analysis (LAB.079)Outfall 001 0 p o~K=5.3.5 6)Sample C/ph (prior to correction) 7)NH3 pH correction .9E g O2.7e 7 5.3.6 8))ample results C/pH (after'7.7 P NH Correction) 3 Sample Sample Time Sample$j Sample Date CDM Entered by 5.3.5 6)Sample C/ph (prior to correction) 7)NH3 pH correction 5.3.6 8)Sample results'C/pH (after Correction) 9)LAB.041 Specs Verified by: h/IR Supervisor Review/Date ~W+l&Form prepared by/Date Form approved by/Date 12 THP LAB.041.25s Revision 1 Outfall 001 Determination of Total (Lab 170)Chlorine Instrument CPG(j 50~Standard ICN-CIDj(2-5 I~Technician Sample/Standard Sample g Date Time CDM Entered by 3D 1)Absorbance 6.11 2)Results, ppm C.w 3}Dilutions made 4)Results, ppm ((I2*8 3)5)1AB.041 Specs Verified by:~)9 Supervisor Review/Dote~MR t Form prepared by/Date Form approved by/Date 12 THP LAB.041-25]l Revision 0 SEE INSTRUCTIONS ON REYERSE SIDE SECTION I I NUMBER PERMIT~NZ 0005827 A~LCCAT IQI OF Dl SCHARGE~00 2~SW e,~W i, we-(TIWI e~06, iiNS~0,6 S TJIISE~l9 W DISCHARGE LOCATION SCHEDULE De IF YESe I.IST DISCHARGE PERIODS NA B.W CF RECK!vltO WATER i!E.'RcuWATER CR NAE C SLRFACE N C.OO YOU DISCHARGE SEASQtTALLYY (IF NQe Ccttt!tATE TO E)e'Oe/%Y YES LiA KiE i4TZ CiHTZ G A N eOe/DAY FLOW RATE WASTEWATER ~TY~D CONTACT COOLING NONCONTACT COOLING PROCESS SANITARY STORMWATER ~NIT c 00 1 MGY 2 MGD 3 GPD ITEM 2 WATER TREATMENT ADDITIVES Ee LS/iD APPLICATION RATE F>>TYPE OF WASTEWATER DISCHARGE G e D ISOIARGE SCHEDULE (YEARLY AVERAGE)INe/tR.WRe/DAY INe/WKe~~LJ LLJ~LJ~~~EI N WASTEIIATER IYPE COCE L~J IOISIS/DAY ~24 eeevzwee He DISCHARGE FIDH RATE TOTAL YEARLY DAILY MINItTPI IXTILY MAXIPAM p p!NIT~CODE 0~2 1 820~2 e"AXIS DES!BI DISCHSRGE FLDI RATE~Ae CO YOU USE HATER TREATIENT ACDITIVES TO TREAT YTXR DISCHARGE?(IF te, CONT!tAE TO ITBI 3)8~NAtE Futct!CN, AND c!EHICAL COMPOSITION CF THESE AlXIITIVESe wIE QXIE DESIGN 1 820 NA Ce rt/ME AND ADCRESS OF MAIAFACTIRERS OF TIESE ACOITIVESe I~,HE MAXIMKA DISCHARGE FIDtt RATE TO BE AUIHCRIZED IN PE%IT.1 820 2 UNITS CODE 1 Mg/I 2 Ug/I NA D.EXPECTED DISCHARGE CctCENIRAT ION CF AID IT!YES.NA ADDITIVE NAtE MIN INDI UN I TS AVERAGE CODE Itt ITS MAXltSPI CODE AcolTIYE NSr%ADDITIVE NAtE E, DO Ymt TREAT TIE DISOURCTE 10 RBQVE ACOITIVES? 'NA F.wHIT IS THE RBQVAL EFFICIENCY AND DISCHARGE FREILKNCY. NA ADDITIVE NAIE ADDITIVE NAME ADDI T I VK NAtE Q YES K RBOVAL LJ/~LJ HRS/DAY DAYS/W.LJ G~AS AN AITACttENT TO IHI5 APPLICATICN PROVIDE SPECIFIC MA!tVTLIAN CR AOUSeTIC TOXICOUIGICAL DATA CR REFKRBICE WHICH ARE AVAIIABIE AND INFOBQTICN ON THE RATE OF DEGRADATION OF TIE PROIXCTS FOR EACH A!OITIVKe NA 30 SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I PERMIT~My pppg827 AIII'ALL tUKR A~%4K OF PROCESS CCttlRIBUTING TO THE DISCHARGE/ROUGH THIS OUTFALL<<8 SIC CCCE B~PROCESS SCHEDULE (YEARLY AVERAGE)tOLRS/DAY~24 I~OI~2 WTR 49 I I~/v PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE Ih Ih IAI Ct~0 C.PROCESS WASTEWATER FLCW RATE Basis: 1993 actual data submitted On DMRS D.PROCESS PRODUCTION RATE Av AX<<"E GF PROCFSS CCttmIBUTltIG TO THE DISCHARGE THROUGH THIS OUTFALL AIID SIC CA/DE NA TOTAL YEARLY DAILY MINIMA DAILY MAX IP%B 48,0844~5 u6 1743~6 1 POUNDS 2 GALLONS 3 CUBIC YARDS 4 TONS 5 MGY 6 MGD 7 GPD TIME 1 HOUR 2 DAY 3 WEEK 4 MONTH 5 YEAR Ih Ih 00I 0 C', 0 B.PROCESS SCIEDULE (YE/UILY AVERAGE)CA PROCESS WASTEWATER FLOW RATE'.PROCESS PRODUCTION RATE A IIAtE OF PROCESS CONTRIBUTItIG TO THE DISCHARGE IHIOUGH THIS OUIFALL AtiD SIC CODE BA PROCESS SQELX1Z (YEARLY AVERAGE)C.PROCESS WASTEWATER FlOW RATE D.PROCESS PRODUCTION RATE A.NA%OF PROCESS CONTR IBUTIttS TO TIE DISCHARGE NA TH AND SIC CODE B.PROCESS SCHXILE (YEARLY AvERAGE)Cv PROCESS WASTEWATER FLOW RATE Dv PROCESS PRODUCTION RATE AA NAtE OF PROCESS CONTRIBUTING TO IIE DISOIARGE , THOROUGH THIS OUTFALL AND-SIC CODE B~PRXESS SCHEDILE (YEARLY AVERAGE)Cv PROCESS WASTEWATER FU)/t RATE D.PROCESS PRODUCTION RATE AVYAVY/OAY ~DAY Y/VYAA TOI'AL YEARI.Y DAILY MINltRH DAlLY M4XItul TOTAL YEARLY DAILY M INIMM DA I I.Y MAXI'vvAVY/AAV ~AAVY/VYAA TOTAL YEARLY DAILY M IN INN DAILY."AXINJ4 AAVY/VVAA TOTAL YEARI.Y DAI I.Y MINION DAILY MAX!AN UNITS/TIME INIT CODE WITS/TIPE UNIT~UNITS/TIVE 33 <<$<<<<3~3~1<<<<J~I 3$<<r n, SC al 8 3 OC (8~I 8 J W ra 8 a C<<ater<<3, 8<<'5 ahJI-'=,=:=<<I:='.=".>>==Soul T'.'"=R Ah":=C:bh0"E;R"!Jt oAGE 7 YCIIR EXPIC't'r l 3<<*8 Si 8 J 8<<<<3 I t V en.Save I af<<<<\<<~<<~5$)c A<<w<<x<<5 5 5CO Vi<<OC i 8<<1 3CB Sec Icn I'.=cr<<ac-:"<<Iv'a< c:scharce Ccint 3 Secarate 3~3 c'1<<'~'~IS~3 8 35 3,~"Iuce".'r.et'var Or Sec CtJ.'at et'8C, io1, 38CC~Cn.(Own, and range~JsT<<.8 ece" vi.g<<8 el Iif sul I)ce<<atef o:sc, al<<8).'1CicaTO<<hetter'3ci.Tv cischarces ",", 3 5835 1al basis.(f yes, i I St C I scnarce car leds.-rovlCe-"e 331C OCR)Ication rateS csee cr Oxbected to be used In terrS Ct'nCneS Cer"our,~curS Cer dav, and Incres per<<eex.Indicate-ne<<vce of wastewaT8I o be isc..reed frcn this cutfall.nefec to the wastewater tvae ceca oiven In tne left-atgln.VOre-Can One COCe may Oe aabliCable. 3":vice--e Oversee nvnber cf"ours.Ot:av:r<<nic.8 x clli~v 3cnat'$~ea<<c<<as Owater 3 8 Tai number of days er,ear<<t,<<<<St O 3"OVICO C.rt ant:frcn the 185t I" nontnS)Cr OXOeo,eo 3 ICW rateS 85 reoueSTed. Refer tO unit Cede OiVen In the left margin FOr The 3cbroariate flow units.'4Y-million ca)lot 5 der veer: '40-million gat lons Der Cay;N)-gallonS Oer day.o-ovlce-te-axi"um cisc1arge f tow rate wnlch vou ant 31 wave author I ted'<<itl'In 18 bernlt.'J0T~: mor'JnoEs bermits onlv,"e use f Such 3 flow rate<<ill nct blaco an actual Jlnlt restriction on the flew ut will be tne flaw rate used to develoo effluent Iin(ts.3)so,<<nen tne Ivcnthiy Cberating Reborts are reviewed bv conoltance staff It will helo tham to determine if any new or increasec uses mloht have oocurreo at the facility,. !.nrov)de t"e design'Io>>for this soeciflc outfall discnarce Ie.g.batch<<reatnent svstem flow, cackaoed treatment system flew, or sore tner finite treatment system flow).TIATSR TREAT'IS'lT PDOITIVES'ncicate<<nether clscharce Is treatec<<a'tn onc)tloners, inn)bi tors~or m)crob)deice. t I noT, continue to item 3.:ive name,,;nCticn, and Chemical CcncOSi tion Of addltlues<<Sed..)Je 13J 8 3nc Ncress 1'8 nanufac 3 o\5)of the addi tivns used."c)cate J<<cec<<ec n)nimun, averaoe 81<<."Sxi-um discnarce ccncent<<atlons of 318 adoitlveis) 'cr-1ls:Ischarce.-c'Ira-8-<<<<er.Cu-<<3--"8$'.Sc~!rce".-~ve-"8 Scc-)veis):o',cre clscrarce o'stewater. '"dicate"8 removal 8'f tc:Oncv.<<ach acdi tive frcn.he astewater and the discharoe frocuencv of each addit>>Je to the 3'rtaoe<<3,8<<'-'I-8 resocnsibili v c'.-Te aecJtcant To suoolv the arocuct'.nfottta!Ion as recuested In this Item 4.Information r dues>>c bct-ot Svbbliec~av result l1 t"8 abo Ilcat)81 bel"o r<<Tur18c to~he aoolicant'or comoiet)cn. 32 SEE INSTRUCTIONS ON REVERSE SIDE SECTION II PERMIT~Mt 0005827 NUMBER GROUNDWATER DISCHARGE INFORMATION %IF%.IlÃB A.IS ISE DISCHUIGE FRCM THIS CUTFALL DIREC1ED TO BIE GRQNsD GR GRQU7CWATERS?(tF tO, CONTlttUE TO ITEM 5)B~HAS A HYDRQGEQLCGICAI. STUDY GR ITS EQUIVALENT BEEN PERFGIYED OR IS THERE SIFF ICIENT cURRENT HYDRGGEQLQGlcAl. INFORMATION AYAttaBLE As REQUIRED BY TI4 wATER REsQURcE's CGtltISSINI PART 22 GROlGIWATER RULES OF ADJUST 1 s 1980 R 523 22O7 (PAGE<<Q)THIS EXIS'TING OR PROPOSED DISCHARGE? IF YES ATTACH A COPY CF THE REPORT.C.ARE YQU REQUES IIO AN EXEMPTIGN FRCM SUBMITTtt2G A HYDROGEQLOGICAL REPORT Ut2QER RILE R.323.22(I7 (7{})(PAGE g)OR FROM GROLCIDwATER MONITORING t)EQUrtREMENTS LNDER RULE R.523.24'5)(PAGE Ug)QF THE PART 22 RLLEs.IF YEs ATTAcH DOQRENTS AND EXPtattATICtt TO DBONSTRATE THAT Y(XFI DISCHARGE HEXAD QUAt.lFY FOR AN EXPION.Ds ARE YGU REQUEsTlto A vaRIattcE FRcM RIAE 323.22(5 (PAGE L~)(NQtmEGRADATIGN) 0F THE WATER RESOURCES CCtltISSICN PART 22 GRIEtDWATER RULES?IF YES ATTACH SUCH DOCUMENTS AS NECESSARY TO DEMON@RATE THE NEED FOR A VARIANCE IN TERMS OF BE cRITERIA sPEcIFIED IN RIAL 525s~o (PAGE~0F THE PART 22 RULEss NA NA NA~0.0 2 YES CI:Es YES X NQ Es I,IST AIJ.CtetICAL Su)STANCES WHICH ARE IN MICHIGAN S CRITICAL MATERIALS REGISTER TABLE IV (PAGE tt)AND/QR Uss~EPA s PRIcRITY PQILUTANT LlsT TABLE v (PAGE 7)cR ANY 0THER slssTANGEs HIICH ARE OR HAY BECCA INJIHIOUS TO BE DESIGNATED USES OF BE GSXSQHATER OR ID THE PUBLIC HEALTH THAT ARE DISGORGED OR EXPKTED TO BE DISCHARGED TQ THE GRQUIDtATERAY THIS FACILllYs ESTIMATE BIE FINAL EFFLUENT CONCENBIATION AND RECCRD ALL DATA IN ITEM 7 OF SECTION I I IN THIS BOO@ET.NQT APPLICABLE/BELIEVED ABSENT NA COD (OetICAL OXYGEN DEMAttD)TOC (TOTAL ORGANIC CARBON)'un'a N I TRQGEN (as N)TOTAL SUSPENDED SOLIDS EXPECTED WASTEWATER CHARAC-slcs UNiTS CODE~TOTAL hOSPHNUS (AS P)BE APPLICANT MAY BE RECUIRED TO DO ADDITIGttAL HASTE ANAL'(SESs As DISCHARGE CHARACTERISTICS tTEM 5 BQD5 (FIVE DAY BIOCIEHICAL OXYGEN DEMAt4t)CONCENTRATION PRESENTi DATA PROVtDED IN ITEM 7 u1 ul u LJ u1 u1 u wtTS cQDE II ANALYsES~TYPE CODE 1 Mg/I 2 Ug/I 3 COUNTS/100 ml.4 S.U.5'F 6 LBS/DAY TOTAL RESIDUAL CH.CRINE DISSO!.VED OXYGEN'PH FECAL COLIFORM BACTERIA~ERATU2E (sue+)1~iERATIRE (wINTER)MIN~7~0~73, u5~60 u4~89 u7 ul u3 u5 u5 u1 ul Bs OTHER WASTEWATER CHAIIACTER ISTICS SAMPLE ZXEF 1 GRAB 2 24 HOUR COMPOSITE 0 I L tt G R E A S E u I u u u LJ u~SEE ATTACHED SHEETS FOR ANALYSIS DATA*Basis: 1993 actual data submitted on DMRS RECIIIRED INFORMATICN FOR SURFACE HATER DISCHARGES ~35 I I~res J" asr s C"e s 35$l S3rS""" r'S 5 ISC a (i elf Srv I sr', Sc'.tv.-", en'esvs: 'nk 0-c 3 nvr cer wi II Os 355 rchec.-.-Cer" SCSCe s 5 e J I re vfcst r sk ssss ITCH 3=cr eac-'sdlv:dual Iscnarce ccir t 3 se ara e set cf rJ Jo CCC 5 3'll u+CT J sf r-',I.PCcuATIC .3"-er-"e"3"s'"e prcCeSS<<niC" Cc"~"'C.tes --sIS 5 SCnalCe.--"vrce--e"""er-IC-""e"clca-e-;e vearlv Sverage process S=hecule r"cuts cer cav nc cavs-:er-lear. .~provide tne process wastewater flow rate information as recuestec based on your last l2 rrrcnths of operations. rtefer to unit code given in the left natcin for the appropriate flow units.p ocess production cate-certain per rit I:rritatlons lrrav oe cased cn production rates.The production rates used to letsrnlne Cernit limits Shall e repTsSen-ed >V 3 reaSCnapie rSeasure C<<C-ual CrCCVCtiOn Cf the faCI IISV, SVCn aS:t""otic" ccln""e"icn rent%cJ"e cre'llcu5'lea.~cr neer rcnthlv averace for the nirihest of,r e orevlcus five years, or tne..lasonaple"easvre as 5~steo rn 3 0>re'.-,.-'..-eccr'csr-res Src"scvlations. r ew 5 Jp(es cr'sw ci scnar'cel 5~a.<el T tn 5sar), e est feats S Inc ro lecsed production.C r 3-CCVC lcn rs-es in--s-Srst Sno..'-5.Se',n tro SCCI Jcac,e,.=.=.;.A. Cate"Orioal ruieS Snd neouiaticnS Cr' SEE INSTRUCTIONS ON REVERSE SIDE SEGTlON I I PERMIT~ME 0005827 NUMBER lM 6 PRIORITY POLLUTANTS AND ADDITIONAL iNFORMATION FOR SURFACE WATER DISCHARGE ONLY (NF JILL MB r>>>>E FQUDWIMG REQUESTED INFORMATION e~r ADDRESSED av a>>'URFACE WATER DISCHARGERS, 6'>>J USE DISCHARGERS ~s>>'RQVICE EJECTED VALUES FCR IHE QUANTITATIVE AM QUALITATIVE It<FORlQTIQM REQUESTED BKLQW.A.:S THIS FACILI1Y A PRIMARY Il<DUSTRY?(REFER TO TABLE IA PAGE 4+SQ TO E)(tF v>JATER?(IF M GO TO E)(IF YES GQ TO O)O>>NDICATK WHICH GC/tYJ FRACTIONS Wsf BE TFSTED FOR~(REFER TO TABLE IA P4%U~I JQIEI FcR EAcH Gc/Hs FRAcTIQN cHEcKED, EAcH sPKclFIc QRGANlc Toxic POLLUTANT'WITHIN~MH FRAcTtQN~BE ANALYzED F0R (sEE TABLE IIA PAGE IJ2, IN ADQITIQN>>AU.PRIMARY IMUSTRY APPLICANTS. WITH a PROCESS wasTKWATKR otsoURGE~PRQVioE QUAMTITATtVE DATA FOR EACH TOXIC POUIJTAMT IM TABLE IIIA Pal<4+~RECORD ALL DATA ON FORMS PROVIDED (ITKH 7)IN THIS BOOKLET>>(CCNTttAJE 'WITH E K BOX')~00 2 YE<JQ STM ELEC PMR X YES X vQLATILE X BasE/MEUIRAL ACID CI PESTICIDE**E~IF~<SURFACE WATER DISOIARGE APPLICANT (PRIIVUIY OR SECCNDARY IMIVSTRY)>> REGARDLESS OF THE TYPE OF DISCHARGE>> KMWS OR HAS REASON To BELIEVE THAT ANY POILUTAMT LISTED IN TABLE I IA AND IVA PAGES~Is DISCHARGED FROI ANY OJTFALL THE QUANTITATIVE DATA~BE PROVIDED>>RECCRD AU.CATA ON FORMS PROVIDED (ITKH 7)IN THIS BOOKLET>>wr.APPLICABLE/BELIEVED ABSENr O X PRESENT/DATA IS ATTACHED F.IF JUJY SURFACE WATER DISCHARGE APPLICANT (PRIHARY OR SECONDARY INDUSTRY), REGARDLESS QF TYPE QF DISOIARGE>> IQJQWS OR HAS REASON TO BELIEVE ANY POultfANTS LISTED IN TABLE VA PAGE~Q ARE DISCHARGED FRot ANY CtffFALL THE APPLICJUIT t~DESCRIBE REASONS FOR THE PIKLUTANT BEING PRESENT ANO PROVIDE ANY AVAILABLE QUANTITATIVE DATA>>RECCRD ALL DATA ON F(XttS PROVIDED (ITEN 7)IN THIS BOOKLET>>X MT APPLICABLE/BELIEVED ABSENT G>>AU.SIRFACE WATER DISCHARGE APPLICANTS (PRINRY AND SECONDUIY IMXJSTRIES) ~QR HAMLFActutES 2, 4, j-TtttostxtQPIEMKY AQETtc Acto (2, 4, 5-r);-(l, 4, 5-TRIQHLDRQPWEMxY PRQPAMIC acto (SILYEx, 2, 4, 5, TP)>>4>>&IRIotJxtcPHEML (TcP);0R HExAcKoRQPtK%(HP);(ALL DATA F0R THE ABOVE i%ST BE GENERATED USING STJUIQARD ANALYTICAL CALIBRATION PROCEIXRES) OR Kilty's OR HAS REASON TQ BELIEVE THAT TCDD tS OR HAY BE PRESENT tN TKIR DtsCHARGE>> ~REPORT QIALITATIVE DATA>>GEIERATED le IOI USED A SCREENIW PROCEDNE MT cALIBRATKD 'WITH ANALYTlcAL sfANDARDs, F0R 2.5./8>>-TKtttaotoRQDIBEMzo-P DloxlN (TCDD)>>RECORD ALL DATA ON FORFAR PROVIDED (ITEM)IN THIS BOOKLET<~',F r>>'E SURFACE WATER DISIHARGE APPLICA<VT KMWS OR HAS REASON TQ BELIEVE 1>>ar 3IQLGGI(AI a~xlcllY TEsTs'WERE MADE IN THE LAsT THREE (5)YEARs 0N Attr 0F THE 4VLICAVT S DISCHUIGES CR ON A RECEIVING HATER IN RELATION 10 A DISCHARGE>> PROVIDE THIS INFQRHATICN AS AN ATTAotEMT TO THIS APPLICATION>>

F A CQMIRACT LU}QRATCRY CR CQNSLLTIW FIRN PERFORMED ANY OF TIE<UAAYSES REQUIRED BY THIS APPLICATION>>

PROVIDE THE NAME AND ADCRESS OF EACH LABCRATQRY OR FIRN AM THE JVJALYSES PERFCAKD AS AN ATTAOtENT OF THIS APPLICATION>> QQ YQU DlscHARGE ANY 0THER Toxic QR IMURIQUs{KHIQAL sutsTAMQEs NQT LIBTED IN TABLES IV PAGE (I AIO I IA THIQU4t VA PAGES~~<t~vES>>THEN IDENTIC THE~MAGICAL SUBSTANCES JVJD ESTIMATE THE FINAL EFFUJENT CONCENTRATICNS. SIEPIIT THIS t<VQRHATICN AS AN ATTAOt%MT TO THIS APPLICATION>> X wr APPLIQABLE/BELIEYED ABSENT Q PRESENT/DATA is arraoED Mr APPLICABLE APPLICABLE/SEE ATTACHED*Q MT APPLICABLE X aPPLIQABLE/SEE arfacHED MT APPLICABLE APPLICABLE/SEE ATTAOIED*See whole effluent test data attached to Outfall 001.**Pesticide data is not required;. however, it is provided. ~>>o>>>>--u 8 5 5~35'c e 5 r c e*ate('5 4 0 n 5 3"e>>cr"""ev~---e 5-a-e 5<<'5-'--eh leave b>>anx 31c 3"u, oet<<>>II ce asslcrea.as a$e<>JSC CSV'sl SC bt>>a<<<<>>5e<<a 8>>5>>-3.e-.O:" Cre Subeta"T I ble 5.3" Ss'rsv:le l" sour Sc.eST"S,,rantea bv--*1sal.a a 55t.'.,'.v'"cent'.as c.tassts~~u av'vest cermiss(cn 'rara vcur=e<<~-'"" avt"cr'Tv 3 3<<5 tsl 5 4Sus 5.e aha a VS>>5 I Toes 5 Jbstantl as Is I en 3.3(utf SI IS.5 ca~it-Iran autncrl-v,:n a secarate s"eet ettac1ec-."."e aaotlcaticn t"t'=enrv caser.e rv-"e S.tasl IS*niC1 vCu cic 1OT-eST std S.ostarrias Iv lcenti 5(TO the Out'.al I cr zr eric toxic collurantS 3 I s~8'3 a as 3 as s'5~e55%e<<action~.r.Tte~e cs'c ct sflTI Tatsve Sna TCXIC OS luranTS SS reauirea by mart a 22~Zl (a)(7)(I i)(A)Or IZZ~2l (8)(7)(I i I)(A).vase oart5 3re self<<exolanarcrv Sna o not reauire'>>.rtt et Inst(ucticrs.Slmc lv a)o Tt'tcuan eben carp 3<<a.o as sncicated. 53".5'3>>3 ea r>>es a I<<er'85 5/5 ee<<e>>>>C O e>5'5 Cn~<<sin'9/a+" 3<<ICns>>IVI>>t>>"<<SOS<<l<<C 5 l5T O Cet>>3"Sss Scectrtscccs. ='racrions. 9<>etre<<~l'.'3'v 5<<as 35".e g>>amer s g<<e<<cr 5<<:,>>'s'rcraaroarabrv/ Sr/VS=racticn e5Ti:lc ana Reocrtlna=xemotlcns axtile allis srcustrv-<<ll sour r>>C/VS Srtanic fracrlo1s!"r T"e rreiqe": Ils'catecorv~-=eSTICICe<<aCriOn an all Othet SubbartS Cf ThlS IrCuSrry.:re la'lin(na ana Cresslna Industry/latI!c~case/"cuts'al, 5>>a=e5'::e"3.Icrs-R Base a>>a~lecic'u3tals Subcateaorv. -all'r""/"S rgansc aractacns'sl-t"er subcareaories of this incustrv..um ana Stnaa Chemicals Industry-SSCSCIC(de fraCtian sn the Tall Q(l WOS In SubCateaarV anO the Rasin Sasea OeriVatiVes Subaatea)ary. -tscsticiae and base/neutral Fractions in all ocher Subcaceaories of this induscry.3 ato and oaocr S<<avstrv-aCS(iC:de fraCCian In PaOeraraae Sulfite SVOCateCOries (SubOarCS J and U).~3}sct-cut>>.3i 3-c scsticsae lcttc-4~<<ocinx suboart'), olssolvina Krast suboart F, ana paoerboara frc<<caste a)ocr Suooas't 8, valet i le.baSC/neuCral, OeSC iCiae fraat ianS s 1 Cl e BCT Sleaanea KrafC SubOart SI.Semi-ChemiCal SubOarCS 8 and C.and yonintcaratca.c(ne Paoers Suboart e.<<csa.Sascttcutral, ana ocst~ca c fractions an F~ne Bleacnea Kraft SubOart I.Oissolvsna Sulfite Palo Subaart'(.",~rauna-aoa p:nc ssaoers suboart o.marxec Bleacnca Kraft suooarc o.Tissue from Mastcoaoer suboart T.and Nonsncearaced Ti55ue eaoers Suboart S.Stcam Electr(c Po>>er Plant Induscrv Basctneucral traction sn the Once-Throua)n Coolinq dater.tiv Ash.ana Soctom Ash Transoort'Maccr orncess>>astescreams.

38 SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I NUMBFR W i4II 0005827 9JIFRL MB~00 2 USE THIS DATA SJEET TO RECORD INFORMATIGN AS RECUIRED IN: (CHEQ<APPROPRIATE BOX FCR IttICH INFORMATION THIS DATA SHEET REPRESFDJTS

~)CRITICAL MATERIALS l.SECTION lli ITDI 4 E~GROLttDLLATKR DISCH/>>RGE INFORMATION (PAGE 55)X 2.SECTION I I.ITEM b.PRIORITY PGLLJJTANTS IN SLRFACE HATER DISCHARGE (PAGE 37)TOXIC POLLUTANTS HAZARDOUS SUBSTANCES IN DISCHARGE Bi LIST ANY CRITICAL t"ATERIAL (TABLE IV PAGE 6)NOT ADIJ2ESSED IN SECTICtt II ITEM FP, RIORITY PCLLUTANTS MILCH YOU JGXJPt OR HAVE REASGN TLL BELIEVE TO BE PRESENT IN TIE DISCHARGE>> SEE REVERSE SIDE GF THIS PAGE FGR FUJ7TIER DIRECTIONS>> t2OT APPLICABLE APPL I CABLE (SEE BEL7at)UNITS CODE 1 Mg/I 2 Ug/I LBS/DAY KG/DAY~P>>MPLE i>>P 1 GRAB 2 24 HR.COMP.LJ Lit~I~PL Ai NAME OF CRITICAl.MATERIAL CR PRIORITY POLLJJTANT Bi AVERAGE CCNCEJIIRATICNJ SAMPLE lYPEJ III OF ANALYSES C~MAXI LJt CatCENIRATICN AJO t'ASS A.NAME OF CRITICAL MATERIAL OR PRIORITY POLLUTAJIT 8 AYERAGE CCttCENTPATICN; SAMPLE TYPEJ tt OF AttALYSES C.JLlLX Ittlt CCNCENIRAT I ON At4)MASS A.ttAME OF CRITICAL MATERIAL CR PRICRITY POLLUTANT B.AYERAGE CONCENIRATION; SJMPLK lYPE;l'F ANALYSES C.MILXItllL CONCKNIRAT ION AND MASS A~NAME OF CRITICAL MATERIAL OR PRIORITY POLUJTA%'. AVERAGK CONCENTRATIONJ SA PLE TYPE'>>OF AttALYSES C"AXIttlt CO'CENIRAT ION AND MASS A.ttAJE CF CRITICAL MATERIAL CR PRIOR llY POLLUTANT S~AVERAGE CGNCEJITRATION; SAME TYPEJ~OF ANALYSES C.~AXIMLtt CGNCENIRATION AMJ MASS A JA%GF CRITICAL"ATK7IIAL OR PRIORITY POLLUTAVT*Sodium H ochloride t.ASS 014I UNIT CODE SV'PLK TYPE OF ANALYSES LJ WIT CODE Ut!T COCK LJ LN IT CODE SAMPLE TYPE LJF ANALYSES WIT CODE WIT CODE LJ WIT CCDE SAMPLE TYPE OF AJLALYSES WIT CODE WIT CODE LJ~.~LJ WIT CODE SAJYPLE TYPE JJ OF ANALYSES LJ Llt IT CODE WIT CODE LJ~~~LJ WIT CCDE SAMPLE TYPE OF ANALYSES~.LJJ~~L>J~~~*~0,~23~1~27 3.~~V 2~B.AVEJLAGEcatcENTRATIGN; SAMPLE TYPE;I" GF ANALYSES c.AXI~cONCEJILATlal AJ4J MASS A.%PE OF CRITICAL MATERIAL OR PRIORllY POLLUTANT 3.AVERAGE CONCKNIRATION; SJMPLK lYPE: Jt OF ANALYSES C>>,MAXlttP. CCttCENIRATICN AttD MASS WIT CODE'AMPLE TYPE OF ANALYSES UNIT CODE WIT CODE LJ Lhll T CODE SA'LPLE TYPE JJ OF AttALYSES LLLJ WIT CODE WIT CODE A.:>>AMK OF CRITICAL i"ATERIAL OR PRICRITY POLLPJTJVLT Bi AvEPAGE catcENIRATIGNJ SA>>LPLE TYPE;>>It 0F ANALYsEs c.MAXIMJJL catcENTRATION AJ4)MAss SJVLPLE TYPE OF AtLALYSES LJ UNIT CODE WIT CODE LJ*Discharged as total residual chlorine**Basis: ADDITIONAL PAGES OF THIS ITEIL 7 ARE ATTAOED FOR Tte REST OF THE CRITICAL CI YES MATERIALS Ata/CR PRICRITY PLXLUTANTS RECUIRED TO BK REPORTED.QX NO 1993 actual data submitted on DMRs.Average concentration based on data from May to December.39 I'S!,'"'S" R"rdzPL:TEu 7 rais tor.Is ro be used bv both surface and groundworer aoplicants to record lnformorlon on anv michigan crltlcai material, E.p.A.Z-"C<<I Pcflu-onr. =.nazarccus svas-ance In<<nice-'s Tool!car!on requires cata-O be provided.his<<ou!C inCluce anv chemico!.:-cs ancee"icnlgan critico!"arer.ais egisrer i,ab)e I'/).The E.p.A.p~icrltv polluran.'sr!no ITable'/).-r Tables A-<<<<nion!ISTS<<rgan!C TOXIC POllutanTS, Other TOXIC uqllutantS,"nVentlcnal and NcnqqnVenricnal POI+tantS Ond NOZardcuS S.bsrances. ITmz 7:.ITIC/I."ATEPI ALS,=RIORITY QLLUTANTS, AND/OR HAZARDOUS SUBSTANCES IN THE OISCHAPGE vaterial I, 2.3...8 List rhe none ot the chemical substance Icritlcal material, priorlrv pollutant, or nazardous substance) from Tables IV, V ono I IA-VA os required In tne box<<nlcn you checked In A.l-3.abbve.Enter each chemiCOI substanCe'S parameter number os listed In Tables IV,.V and I IA-VA it provided.B.orovlde the average concentration of the chemical substance named In A.Indicate the sample type used and the number of analyses mode to provide the concentration data for the chemical substance named in A.Provide the maximum concentration and determine the mass loading of the chemical substance named In A.NOTES: I.If only one analysis was mode for a chemical substance then record that data os a maximum value.If more than one analysis has been mace for a chemical subsTance Then provide an average value ot those analyses and the maximum value.2.This Section II, Item 7, Data Sheet provides space for recording cata for 8 chemical substances IMoterlals). Addlticnal SbOCe<Or reCOrqlng Of data tOr mere rhan 8 MarerlalS Can be made by making COPleS Of thlS Item.7 Data Sheet os needed.It is also imporront to use a separate ser of Data SheeTs for each applicable reporting requirement as listed In A.I-3.and for each outfall.3.Refer to the left margin for the code number representing the SamPle type used and the appropriate unit codes.40 ANALYTICAL REPORT Cook Nuclear Proj: Waste Water Analysis Subm: Jan 26 Samples Submittal Number: 29609-3 Location: Contact: Ray V.Buhl Phone: (616)942-9600 Outfall 001 Outfall 002 Circ.Intake Detection Units Limi t WWES Sample No: 78371 78372 78373 BOD, (5-Day)Sampled by: Date Sampled: Time Sampled: Date Received: Time Received:<1.0 01/26/94 00:00 01/27/94 13:30<1.0 01/26/94 00 00 01/27/94 13:30<1.0 01/26/94 00 00 01/27/94 13:30 1.0 mg/1:>')~)')(I I('ll'6 rlr)rl I I I I IH I ale'h 5 alt 8 I'.I ()lkrl 5 874.(I I'rl ll(l Rrl pl(IH.11 I II)588 0874.8 I 8/I)4 2 0I)00 I'rl'r 0 I~2 II I 8 ll ll/lI In('(I'BI i 6.S'(7nI('(1~emu@(('>Ilvallll STATEMENT OF DATA QUALIFICATIONS CLIENT: Cook Nuclear SUBMITTAL'9609-3 All analyses have been validated and comply with our Quality Control Program.No qualifications required.The following analyses have been qualified for the reasons cited.KEY l.2.3.4.5.6.7.8.9.10.Sample integrity suspect upon receipt (explain). Analysis performed beyond EPA established maximum allowable holding time.Detection limit elevated due to matrix interferences. Laboratory control sample value outside established acceptable limits.Matrix spike sample value outside established acceptable limits.Duplicate analysis value outside established acceptable limits.Surrogate/internal standard recoveries outside established acceptable limits.Data point suspect due to potential laboratory contamination (explain). Coelutes with the compound cited.Result may represent a combination of both compounds. Other (explain). Note: This document is included as part of the Analytical Report for the above referenced and should be.retained as a permanent record thereof.)'>')>(llenwond Illlls Parkway SI'.PO Box 874.(Iran(l Rnpl(ls.Xtl 49588-0874. 8 I G/842-8800 !'ax 0-I2-8 In! tl1!'En)e(no!E-'.')n(n(7 l,iatnmi((nmp,vn Xl 1 I I(Xl sl I'K I(I ANALYTICAL REPORT Cook Nuclear Proj: Waste Water Analysis Subm: January Samples 29609-4 Ray V.Buhl (616)942-9600 Submittal Number: Location: Contact: Phone: Outfall Outfall 001-Circ 002-Circ Water Dsch Water Dsch Circ Water Detection Units Intake Limit WWES Sample No: 78532 78533'8534 Surfactants, MBAS Coliform, Fecal Color (Apparent) Sampled by: Date Sampled: Time Sampled: Date Received: Time Received: (0.025 2<5 V.Shah 01/26/94 00'00 01/28/94 00 00<0.025<1<5 V.Shah 01/26/94 00 00 01/28/94 00 00 (0.025<5 V.Shah 01/28/94 00 00 0.025 1 5 mg/1 cl/100ml 6 pH 5:)55 (II(.'nivn()(l II!Ils Pnr kivny SE.PO Box 874.(I('nn(l Rnpl(ls.III 49588>>0874. 616/902-9()00 I'nx 9 I'-6 I!)9 lHV Ert,>ateelVn >f-SneBCe tt.s>>>>>>>>i I c:rt>>>p'>>>t STATEMENT OF DATA QUALIFICATIONS

4 X A l.'>'I'(l 5 I.,'b I'.R't I t

t!: CLIENT: Cook Nuclear SUBMITTALr 29609M All analyses have been validated and comply with our Quality Control Program.No qualifications required.The following analyses have been qualiTied for Ihe reasons cited.Sample No.(s): Explanation:

Parameter: KEY l.2.3.4.5.6.7.8.9.10.Sample integrity suspect upon receipt (explain). Analysis performed beyond EPA established maximum allowable holding time.Detection limit elevated due to matrix interferences. Laboratory control sample value outside established acceptable limits.Matrix spike sample value outside established acceptable limits.Duplicate analysis value outside established acceptable limits.Surrogate/internal standard recoveries outside established acceptable limits.Data point suspect due to potential laboratory contamination (explain). Coelutes with the compound cited.Result may represent a combination of both compounds. Other (explain). Note: This document is included as part of the Analytical Report for the above referenced and should be retained as a permanent record thereof.5555 (s'tenwood ttllls Parkway SE.PO Box 874.(>rand Rapids, Mt 49588-0874. 616/942-9600 t'ax!)4'>-t!4!)s GENERAL CHElVIISTRY RESULTS Client Sam ie ID: OUTFALL 002 LAL Batch IDls): 126 im Date Collected: 01-24-94 Date Received: 01-26-94 Matrix: water PO¹69095-040-3N Constituent Met oa Result Reporting Detection Limit Date Quelifierfs) Data Anal zed LAL Sem Ie ID Fluoride, inm IL Bromide.in m IL Nitrite-Nitrate-Nitrogen, inm IL Sulfate, inm IL Total C anide, inm IL Total Phenolics, in m IL Sulfide, inm IL 340.2 300.0 353.2 300.0 335.2 420.1 376.1<0.15<0.050 0.34 23<0.020<0.15<1.0 0.15 0.050 0.050 0.059 0.020 0.15 1.0 03-02-94 L1 131-9 01-28-94 L11 31-17 02-11-94 L11 31-22 01-27-94 L1131-17 01-27-94 L11 31-26 02-08-94 L1131-32 01-27-94 L1131-12 Comments: GENERAL CHEIVllSTRY Rf SULTS Client Sample ID: OUTFALL 002-CW DISCH LAL Batch ID(s): 126 im, 127 im Date Collected: 01-26-94 Date Received: 01-27-94 Matrix: water PO¹69095-040-3N Constituent Total Phosphorus, inm IL Ammonia-Nitrogen, inm IL Total Suspended Solids, inm IL Total Organic Carbon, in m IL Chemical Oxygen Demand, in m IL Total Kjeldahl Nitrogen, inm IL Method 365.2 350.1 160.2 41 5.2 410.2 351.2 Result<0.030<0.050<12 2.0<18<0.10 Reporting Detection Limit 0.030 0.050 12 1.0 18 0.10 Data Qualifier(s) Date Anal zed 02-08-94 02-01-94 02-02-94 02-16-94 01-28-94 03-03-94 LAL Sam le ID L1142.6 L1 142.6 L1 142-10 L1142-2 L1142-2 L1 142-6 Comments: GENERAL CHEMISTRY RESULTS Client Sam le ID: OUTFALL 002 LAL Batch ID(s): 128 im Date Collected: 01-27-94 Date Received: 01-28-94 Matrix: water P0469095-040-3N Color Constituent Sultite, in mg/L Met od 1 10.3 377.1 Result (5.0 (1.0 Reporting Data Detection Limit Quallflerls) 5.0 1.0 Date Anal zed 01-28-94 01-29-94 LAL Sam le ID L1151-2 L1151-2 Comments: METALS RESULTS Client Sam Ie ID: OUTFALL 002 LAL Batch)DIs): 126 im Date Collected: 01-24-94 Date Received: 01-26-94 Matrix: water PO¹69095-040-3N Constituents Method Concentration Im IL)Reporting Detection Limit (m IL)Data Qualifierls) Date Anal sed LAL Sem le ID Aluminum Antimon Arsenic Barium Ber Ilium Boron Cadmium Chromium Cobalt Co er Iron Lead Ma nesium Man anese Mercur Mol bdenum Nickel Phos horus Selenium Silver Strontium Thallium Tin Titanium Uranium Vanadium Zinc 6010 6010 7060 6010 6010 6010 6010 6010 6010 6010 6010 7421 6010 6010 7470 6010 6010 6010 7740 6010 6010 7841 6010 6010 6020 6010 6010<0.20<0.060<0.010<0.20<0.005<0.20<0.005<0.010<0.050<0.025<0.10<0.003 12<0.01 5<0.0002<0.067<0.040<0.050<0.005<0.010 0.13<0.010<0.20<0.10<0.001<0.050<0.020 0.20 0.060 0.010 0.20 0.005 0.20 0.005 0.010 0.050 0.025 0.10 0.003 5.0 0.01 5 0.0002 0.067 0.040 0.050 0.005 0.010 0.10 0.010 0.20 0.10 0.001 0.050 0.020 02-22-94 L1 131-95 02-22-94 L1 131-95 02-20-94 L1131-95 02-22-94 L1131-95 02-22-94 L1 1 31-95 02-22-94 L1 131-95 02-22-94 L1131-95 02-22-94 L1131-95 02-22-94 L1 1 31-95 02-22-94 L11 31-95 02-22-94 L1 1 31-95 02-23-94 L1 1 31-95 02-22-94 L1131-95 02-22-94 L1 131-95 02-09-94 L1 1 31-95 02-22-94 L11 31-95 02-22-94 L1131-95 02-22-94 L1 131-95 02-25-94 L1 131-95 02-22-94 L1131-95 02-22-94 L1131-95 02-28-94 L11 31-95 02-22-94 L11 31-95 02-22-94 L1131-95 03-07-94 L1 1 31-95 02-22-94 L1131-95 02-22-94 L1 131-95 Comments: VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 1 of 2 li n am le ID: OUTFALL 00 D II: 4-AN-4 Matrix: WATER Anal tical Batch¹: 020394-8260-J-2 QC Batch ID: 020394-8260 LAL am le ID: L1131-44 D R iv 2-AN-4 Date Anal zed: 03-FEB-94 Dilution Factor: 1 RR TE RE OVERY QC Limits 1 2-Dichloroethene-d4 T n 4-Bromofluorobenzene 99 1 4 97 76-1 14 86-1 1 5 Chloromethane Vin I Chloride Br mmehn h r h n Trichlorofluoro methane Ac one 11-Di I r h n n Di Ifi Meth lene Chloride trans-1 2-Dichloroe bene Vin I A 11-Di I r hn 2-Butanone cis-1 2-Dichloroethene hlrf rm 111-rihl r h Carbon Tetrachloride 1 2-Dichloroe han 8 n n Trihi r hn 1 2-Dichloro ro an Bromodichlorome hane Concentration L<5<5<10<5<5<10<5<5<5<5<5 Reporting Detection Limit 10 10 D hl I Vin r 4M hl--en nn cis-1 3-Dichloro ro ene Toluene rn-1-Dihl r r n 2-Hxnn 1 1 2-Trichloroethane Tetrachloroethene PCE<5<5<5<5 LOCKHEED ANALYTICAL SERVICES .VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 2 of 2 Client Sam le ID: OUTFALL 002 LAL Sam le ID: L1131-44 Constituent Dibromochlo rom ethane hlr n n Eh I n n m-X lena o-X lene r n Br m f rm 1 1 2 2-Tetrachloroe hane 1 3-Dichlorobenzene 14-Di hl r n n 1 2-Dichlorobenzene Concentration /L<5<5<5<5<5<5 Reporting Detection Limit/L Data Qualifier s ZCG LOCKHEED AIVALYTICAL SERVICES VOL'ATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING IVIETHOD 8260 TENTATIVELY IDENTIFIED COMPOUNDS Client Sample ID: OUTFALL 002 Date Received: 264AN-94 Matrix: WATER Analytical Batch: 020394-8260-J-2 LAL Sample ID: L1131~Date Analyzed: 03-FEB-94 Dilution Factor: 1 QC Batch ID: 020394-8260 Tentatively Identified Compound NO COMPOUNDS IDENTIFIED Estimated Concentration Iyg/L)Retention Time (minutes)Data Qualifier(s) LCG LOCKHEED AIVAL YTICAL SERVICES

SEMIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING ViETIIOD 827p Clien Sam le ID: OUTFALL 02 Date Collected: 24-JAN-94'atrix: WATER Anl i IB h4'.2 4-7-A QC Batch ID: 8270-SEMIVOLATILE 4825 LAL Sam le ID: L1131-57 Date Received: 26-JAN-94 Dilution Factor: 1 D Exr d 31-AN-4 Date Anal zed: 03-FEB-94 P e I of2 S RR GATE RE OVERY 0 Limi 2-Fluoro henol Phenol-d, Nitrobenzene-d, 2-Fluorobi hen I 24-Tri rom h n I p-Terphenyl-d 27 20 67 58 48 41 21-100 10-94 35-114 43-116 33-141 Phenol bis 2-Chloroeth I e her hlr hn I 1-Dihl r nz n 1 4-Dichlorobenzene Benz I alcohol 1-Dihl r nz n 2-M hl hn I bis 2-Chloroiso ro I ether 4-Meth I henol N-Ni r-Di-n-r I min Hex hl r hane Nitrobenzene Iso horone-Ni r h n I 4-Dim h I h Benzoic acid bis 2-Chloroethox me hane 4-Dihl r h n 1 4-Tri hl r n n Na hthalene 4-Chloroaniline Hx r in 4-hlr--m hlhnl 2-Meth Ina hthalene Hexachloroc clo entadiene Concentration L<10<10<10<10<10<10<10<10<50<10<10<10<10<10 Reporting Detection Limit 10 10 10 10 10 10 10 10 5p 10 10 10 10 10 D LOCKHEED ANALYTICAL SERVICES 0 SEMIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Client Sam le ID: OUTFALL 002 LAL Sam le ID: L1131-57 Pa e2of2 Constituent 4-Tri hl r hen I 4-Tri hl r hen I 2-Chlorona hthalene 2-Nitroaniline Dim h I hh I A n hhln 2 6-Dinitrotoluene 3-Ni roaniline A n h hen 4-Dini r h n I 4-Nitro henol Dibenzofuran 4-Dini r I n Di hlhhl 4-Chloro hen I-hen lether Fluorene.4-Ni r nilin 4-Dinir--m h I h n I N-Nitrosodi hen lamine 4-Bromo hen I-hen lether Hx hlr nzn Pn hlr hn Phenanthrene Anthracene Concentration I IL)<10<25<10<25<25<10<10<10<2<2<10<10<10<10 Reporting Detection Limit I IL)10 25 10 25 25 10 10 10 10 10 10 10 Data Qualifierls) Di-n-I h I Fluoranthene P rene B I n I h'-Di hl r n Benzo a anthrac n Chr sene i 2-h Ih I Di-n-I hh I Benzo b fluoranthene Benzo k fluoranthene <10<10<10<10<10<10 10 10 10 10 10 10 Bn rn In n 1 r n Dibenz a h an hracene Benzo h i)e lene<10<10 10 10 LOCKHEED AIVALYTICAL SERVICES SEMI-VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8270 TENTATIVELY IDENTIFIED COMPOUNDS Client Sample ID: OUTFALL 002 Date Received: 26-JAN-94 Matrix: WATER Analytical Batch: 020394-8270-A LAL Sample ID: L1131-57 Date Analyzed: 03-FEB-94 Dilution Factor: 1 QC Batch ID: 8270 SEMIVOLATILE 4825 Tentatively Identified Compound UNKNOWN KETONE Estimated Concentration Iyg/L)9.3 Retention Tlrne Iminutes)4.80 Data Qualifierls) C LOCKHEED AIVALYTICAL SERVICES OIL AND GREASE EXTRACTABLES ANALYSIS RESULTS BY FT/IR USING METHOD 413.2 Client Sam Ie ID: OUTFALL 002 D II: 4-AN-4 D R iv:-AN-4 Matrix: WATER Anal tical Batch¹: 020494-413.2 LAL Sam le ID: L1131-77 D Anl: 7F B-4 Dil i nF r:1 Date Ex racted: 02-FEB-94 QC Batch ID: 020294-413.2 Constituent Oil and Grease Concentration m L Reporting Detection Limit m Data Qualifier(s) LOCKHEED AIVALY TICAL SERVICES PESTICIDE ANALYSES RESULTS BY GC/ECD USING METHOD 8080 lien m le ID: TFALL-2 Da II: 4-AN-4 Date Extracted: 31-JAN-94 Matrix: WATER Analytical Batch¹: 013194-8080-E-4 LAL Sam I ID: L11 1-7 D R iv: 2-JAN-4 Date Anal zed: 01-FEB-94 Dilution Factor: 1 QC Group ID: 8080 PEST/PCBS 4822 TCMX DCB RR ATE RE VERY 63 45" QC Limits 60-150 60-150 A-BH B-BHC G-BHC D-BH Constituent Concentration L<0.05<0.05 Reporting Detection Limit 0.05 0.05 Data Qualifier(s) HEPTA HL R ALDRIN HEPTACHLOR EPOXIDE H RDANE ND LFAN I A-CHLORDANE 4 4'-DDE 4 4'-DDT DIELDRIN ENDRIN ENDOSULFAN II 4 4'-DDD ENDRIN ALDEHYD ENDOSULFAN SULFATE METH OXYCHLOR T XAPHEN P B1 1 PCB-1221 PCB-1232 P B1 4 P B-1 PCB-1 254 PCB-1 260 TECHNICAL CHLORDANE TCMX-tetra-chloro-meta-xylene DCB-Deca-chloro-biphenyl <0.05<0.05<0.05<0.1<0.1<0.1<0.1<0.5<2 0.0 0.05 0.05 0.1 0.1 0.1 0.1 0.5 l44 LOCKHEED ANALYTICAL SERVICES RAD DATA REPORT (ra01)Indiana Hichigan Pover Co.~Bridgman,HI.Organic and Inorganic Contaminants (Project COOK-JENI) Hatrixt'lister Client Sample ID: OUTFALL 002 Date Collected; 24-JAN-94 LAL Sar@le ID: L113+86 Date Receivedt 26.JAN-94 Login N+4ert L1131s"""'""><"'Anal~ed 'Babb'"""<"~"""'-'-': "l'"-'"""""-"":<':-'-'~~~Act Mty@" O'For'~~IB)IL~~".~: -'a'tagual'-'Infts-"'ross Alpha Gross Beta 23 FEB-94 GR ALP/BETA LAL~0060 4756 23-FEB 94 GR ALP/BETA LAL 0060 4756 0.33 1.9 O.M 1.3 1.7 2.2 pCi/L pCI/L Page 7

RAD DATA REPORT (ra01)Indiana HIchigan Pcwer Co.e Bridyaan,HI Organic and inorganic Contaeinanta (Project COX JENl)Hatrlx: llater Client Seep(a ID: QITFALL 002 Date Collected: 24.JAN-94 LAL Sancta lD: L1131-90 Date Received: 26-JAN-94 Log ln Kwhr: L1131 QP~Coni't Ra-226 Ra.228 22.FEB.94 RA.226 LAL.0073 4771 23-FEB.94 RA-228 LAL.0074 5503 0.016 0.52 0.056 0.12 0.34 0.55 pCI/L pCI/L Page 11 PH Meter CPC 9 Jom C date due PH Analysis (LAB.079)Outfall 002 Sample Sample Time Sample P S amp le Date CDM Entered by 0 5.3.5 6)Sample C/ph (prior to correction) 7)NHz pH correction 5.3.6 Sample Sample Time Sample$j Sample Date CDM Entered by 8))ample results C/pH"(after t.~g NH Correction) 3 P 2e3 a cb)c-P'4~(6/7>oo U 2/L-3oo 5.3.5 6)Sample C/ph (prior to correction) 7)NH3 pH correction 5.3'8)Sample results'C/pH (after Correction) 9)IAB.041 Specs Verified by: hl/8 Rwpeevieee Review/Deee ~&+I~Form prepared by/Date Form approved by/Date 12 THP LAB.041.25s Revision 1 Outfall 002 Determination of Total (Lab 170)Chlorine Instrument CPCIj 50~""""'"'~s'echnician Sample/Standard Sample g Date Time CDH Entered by 1)Absorbance 6.11 2)Results, ppm (~c~3}Dilutions made CH W 4)Results, ppm (III2*8 3)5)LAB.041 Specs Verified by:~)9 vperviaor Revi'ev/Date~MR~ para prepared by/Date/~f+Form approved by/Date 12 THP LAB.041-25)l Revision 0

SEE INSTRUCTIONS ON REVERSE SIDE GlIFALL'KKR SECTION I I PERMIT~MI pppg827~00 3 j'j~iVI DISCHARGE LOCATION SCHEDULE FLOW RATE A~LOCATION OF DISCHeVIGE CF RECEIVING WATER (IE.GRC(tGHATER CR tisV6E GF SIRFACE Cs DO YCU DISCHARGE S~Y.(IF tO.CCNTttAIE TO E)Ds IF YESe LIST DISCHARGE PERIODS L AKIE MIC HIGA N X YES tes/IRY~12~01 te,/DAY~04~30~SW ('s,~NW V, KCIIWI i~6, i0II~06 6~IJII06~I WASTEWATER ~I~gg E.LUID APPLICATION RATE CONTACT COOLING?NONCONTACT COOLING 3 PROCESS S SANITARY B STORMWATER F e TYPE QF WASTEHATER D I SCHUIGE G~DISCHARGE SOEDIAE (YEARLY AVERAGE)He DISOIARGE FLOt RATE IOURS/DAY ssv/vsse~12 I (tIIT COCE TOTAL YEARLY DAILY HINI~DAILY HAXItSPI/NIT Cygne I MGY 2 MGO GPO I.'M FAXING DISCH6RGE Rlw RATE TO BE AUIHOIIZED IN PERIIT.*uIIT CCDE (NIT OXE LJ Js HAXtt(tt DESIGN DISCNRGE FIOI RATEs*DESIGN Cl YES Ae CO YOU USE HATER IREATHEHT ACOITIVES TO TREAT YOIR DISCH6RZ?(IF Mt, ccNTIN(z To ITet 3)Be NA%FutCTICN, AtO OettCAL CCt&KITICN OF lAESE ACOITIVESe lTEM 2 WATER NA TR EAT ME NT AODITIVES Ce N4%Ate ADCRESS OF HAIAS'ACTIRERS OF IHESE ADDITIVESe INe/WRe HR~CAY IN./wK~~u~.'~K IIA WASTDIATER 1YPE COCE~3 u M.M LJ UNITS CODE I Mgrl 2 Ugrt Ds EXPECTED DISQQRGE CCtCEHIRATICN CF AIOITIVESe NA NA HI Nit%8 AVERAGE CODE IHI TS HAXINtt (ODE W I TS CODE AIXII TIVE HA%ADDITIVE NA%ADDITIVE NA%LJ;~M;~LJ Es DO Y(XI TREAT TIE DISCHARGE IO REteVE ADDITIVES? NA F.tAIAT IS 1HE RseVAL EFFICIENCY ANO DISCHARGE FREQUENCY ADO ITIVE Ntt%ACOITIVE NA%ACOITIVE NAt%I ReeVe.tRS./DAY DAYs/wx.G~AS AH ATTAOf%Ãf TO THIS APPLICATICN PROVIDE SPECIFIC NWVLIAH CR ACUATIC TOXICOUF)ICAL DATA CR REFERENCE HHICH ARE AVAIIAELE AND INFOR(ATICN CN THE RATE OF DEGRADATICN OF T%RRCIXICTS FCR EACH AIOITIVEs*The flow for this outfall is not monitored separately from Outfalls 001 and 002 r 3 41~'\j 1'8)<<'1 4<<4~<<p~4~1~'<<'14~~1 5'41 8~re~g 1 C 5<<l 1 4)scil 4O 3 4 I\~<<'<<R'l4)1 4 14<<r 3)r rt t$3+I 1 8-.r Rr at 4r Sec I,.-)r-4)5 ric", lect ton.)Own.d1o rant)c St 1 8$<<BI" BTB<<'2 1'<<~SC ci" re<<1et.Br'<<ci.:Tv:)scnarces -..)Seas=net:as."3.res~~is):iscnarce)Brloos=cvlce 8)1C)Colic)rien )-8$.SeC=.-4VCRC ea-::e uSea i--Br S='"CneS e<<-cur, 1aurS Cer C)v,)na ICC1eS Oer week.'1CIC).e 5 11 8 C'ST4<<aTR<<, Ce:I sc-lrCeo I-Ž--Is ovtfal I~)e<<der"--8<<aSreraTer TVOe Coca aiven)1 t1e left-ar<<r)n."Ore-<<an C1e Ccae maV Oe)balll ab'lr4"<<8<<.ORr<<Jr 3 I*~<<'\~~\1~5'3 4~4)3 Rw)--4-.-5'.Cer cf days.v~Ce;.5-".4 4~))."S, I 41)4 8-rw I)85)5 recuestea. )0)8<<-.',1it Oe)ivRn~r"8 ler<<af'Cln ".r-'18))Orcbr~ate.I.<<lr1lf5 ry-~it':)" Callcns:Br year;v%-million,at lets cer Say;drO-latlanS Oer cay.bvl)8 8)x, tr)".SC')ar<<8 flow r).e nicn'rau)n-navB avtnari)BJ <<Ital<<.')cermlt.'CTE:-18 use of)ucn)'Icw r)te<<i)I-ct"lace an actual')t restrlc,'cn cn The'Ic<<ou;<<il I be tne ent I'1)-$.)Iso, nen 18"cntnlv.aerating eocrts are reviewed bv Camo)lance sraff it will~I anv Ile'lr ol i<<creased u585 mlaht trave occur Ieo at tne foci I I tv,~tar"8"CS err<<its only, IlCw I'ate CSed ta dave)OO nelo tren to Cerermine"8 cesi"rn'.w cr r'))$3ceci I" rf)ll:1scnarae te.g.C)rcn-neat.enr Svstem f la>>, cackaaeo treatmnt SV5tem flow, ct'ere c)18r'l<<l)4-reatrent srstem f Icw).)dr-'~'-"'Tltc<<alc)~4<<"8"4<<j)r 8)3~r<<)BC<<>>1al I 8<<$,'11)<<)f rs~3<<liar CI cice~~1ct b"tltue~-I-41'4~8 1 I 1 r 4<<l\C$1<<'1 RS jgt:.ite 1are I"C))c RSS: 1e manufaCture"IS) CI-"e<<coitiveS dsea.4<<eh 1 1$4~<<I 4~~<<3 5 lr~4 i 4~4<<<<4 1<<, 4,1<<I~tl1 4 l3 4 1-1~-4-"4-4-"v)l 8 I'-tencv" 4)c1 5)I I"8 r 1 3<<ITR<<'a*i)4<<~4 ast4<<af4<<~8 1$,)r 8 l<<<<ever cv ct R<<cn Sac i 1 fe-" t.'le 4$.5," i)'", ICI)r I I I 4 I")Cuar p ati,.15 4.J8$)BO I'$~4PI C,.1'fcrmatlCn 41IR5t<<a.T".!.)ct(eo 4av<<<<suit<<8)oolic)ttc<<eel"c<<1)'t'1eo o"8)coif)...'"r crtoteticn ~ SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I NUMBER W HI 0005827 PROCESS STREAMS CON TR I BUT IN G TO OUTFALL DISCHARGE tft 4/t 44t Oe Ct Q.Ae Ntt%OF PSIQCESS CIXIIRIBUTII6 mv/THEDISolARGE THOUGH THIS OUTFALL<<6 SIC CODE B.PRXESS SOtEIXLE (YEARLY AVEIU6E)C.RIQCESS WASTEMtITER FLOW RATE De PROCESS PRODUCTION RATE NA.Dt E~00 3 WIT COCE TOTAL YEARLY DAILY MINIMtM DAILY I AXIS WITS/'TII"E Ioios/oev~24Y~56 1 POUNDS 2 GALLONS 3 CUBIC YARDS 4 TONS 5 MGY 6 MGD st GPD TIME 1 HOUR 2 DAY 3 WEEK 4 MONTH 5 YEAR Ae NAME OF PROCESS CONIRIBUTII6 TO THE DISCHARGE N THIQUGH THIS OUTFALL AtO SIC CXAE Be PROCESS SCIEDULE (YEARLY AVERAGE)C~PROCESS WASTEWATER FLOW RATE PROCESS PRODUCTION RATE Ae MAIS OF PROCESS CQNIRIBUT lt6 TO TIE DISCHARGE NA THOROUGH THIS OUTFALL AttD SIC CCOE Be PROCESS SCHEME (YEARLY AVERAGE)Ce PROCESS WSTEWATER FLOW RATE De PROCESS PRODUCTION RATE Ae NAME OF PROCESS CQNIRIBUTII6 TO THE DISCHARGE NA At6 SIC CODE B~PROCESS SCHZkAE (YEARLY AVERAGE'PROCESS WASTEWATER FLOW RATE De PROCESS PRODUCTION RATE HOUIS/SAY~SAYS/VSAS TOTAL YEARLY DA ILY M IN IHM DAILY MAXIHM HIIOS/OAY~SAYS/YSAS TQI'AL YEARLY DAILY MINIHM DAILY MINIHM HteelS/OAY ~OAYA/YSAA TOTAL YEARLY DA I LY M IN IHM DAILY tAAX IBM WITS CTIME WIT CODE WITS/Tlt%Ae NAPE OF PROCESS CONIRIBUTlt6 TO TIE DISCHARGE THIQUGH THIS OUIFALL AND SIC CODE B.ReCESS SCHULE (YEARI.Y aVERAGE)Ce PROCFSS WASTEWATER FLCW RATE De PROCFSS PRODUCTION RATE TOTAL YFARI.Y DAILY MINIHM DAILY MAXIHM SIVA/VSAA UNI'TS/Tli"E*The flov for this outfall is not monitored separately from Outfalls 001 and 002 33 IP kc,<<35}: r<<5 5 5 355 I o)f 5<<<<Ic1ri te o,s Isobar~~~5'" I" I'5 I>e 5)g el'<iacl<<r a5 e<<v<<lan<<<<3 tg<<'(xl)c vrt A vqfCI>Ce 3SS CreC.)i-.-"e-cace=<<ovlcec cr esc3 qa<<te of section i'I, ccr eben Inoivlcuat clscharce qoint 3 separate set cf t 3 4=--3---<<-!-5-"-e-roceSS<<niCC Cont-IC tes-q-nlS ISCharCe.MISO"rCViCe-ne Cr""et=.IC COCS e"e.carts bier<<"e process 5 recule in ncurs cer csv anc cavs-ber-veer. Provide t3C process.wastewater flow rate information as recuested based on your last IR months of operations. Refer to Jnlt COde given In tne left margin for the appropriate flow units.-rocess qrccuction cate-certain qermlt I;mltatlons mav be based cn production rates.The qroducticn rates used to:3 e~'"e car.'-~'-I s snail<<e reqr<<sen ec)v a reascnable <<easure cf actual"rcduc ion of the facilitv, such as the."-..."-'".-

.'-"-<<-Icn ,ento cf."e crevi us tearer cr t<<e<<onthlv 3verace'cr tne nichest of the crevlcus f(ve vears, or=-her"eascnsb.'e eas.re as statec tn 3 q>>cable J.S.K.o.h.

cat8gor!caI rules and reoulaticns. ir 45:lSC3arde<<s, 33-.3~5"Cduc-Žr 5>ail:e eStl ate.is:no:roiec+ec crcduC iCn 55<<e 3<5 3 c~ri ts 5ec>5 3'I)Ie.t..c,h, 3 B rlcal rules and reculatlcns 'cr SEE INSTRUCTIONS ON REVERSE SIDE (UIFALL IUD SECTlQN I l M2 0003827~00 3 GROUNDWATER DISCHARGE INFORMATION IS THE DISCHARGE FROM THIS CflFALL DIRECIED TO THE GRCUt47 OR GRON4WATERS?(IF NOe CCttTIhUE TO Iieet r)MAS*ttYDRCGEOLOGICAL STUDY OR ITS EOUIVALENT BEBI PERFORMED OR IS THERE SLFFICIENT CNRENT HYDROGEOLOGICAL INFOfitQTION AVAIIABLE AS RECUIRED BY~wATER RESOIIRCES COtHISSION PARi'2 GRONIDWATER RULES OF AIIIUST ltte 19m)R.525 ZQJ7 (PAGE 4Q)FCR THIS EXISTltiG OR PROPOSED DISCHARGE? IF YES ATTACH A COPY OF THE REPCRTe C.ARE YOU REOUESTING AN EXP'PTION FRQt SUIPIITTING A HYIXIOGEOLOGICAL REPORT UteDER RULE R.32$.27/(19}(PAGE Ltt)OR FRCM GRIX5DHATER MONITORING I)EOUJREte~0 UCER RULE R 25 ZLV5 (5)(PAGE Q)OF THE PART 22 RILES~IF YES ATTACH DOQBENTS At43~TICN TO DEIIONSTRAlE THAT YOR DISCHARGE WOULD OUALIFY FOR AN EXEtP ION.De ARE YOU REOESTlttt A VARIANCE FRCtt RULE 323e22(5 (PAGE 5)(NONOEGRADATION) OF THE WATER RESIXRCES CCtttlsstON PART 22 GRONIDtATER RULES?IF YESe ATTACH SUCH DOQPGPS AS NECESSARY TO DEWNSTRATE THE NEED FCR A VARIANCE IN TEtiMS OF TtE CRITERIA SPECIFIED IN RtAE 525e2210 (PAGE IIL7)OF THE PART 22 RULES>>NA NA NA YES'DIES YES YES e>>Ee LIST AteeL Cte)ICAL SIBSTANCES WHICH ARE IN MICHIGAN S CRITICAL MATERIALS REGISTER TABLE IV (PAGE tt)AND/OR UeSe EPA S PRICRITY POILUTANT LIST TABLE V (PAGE 7)OR ANY OPER SI8STAtKES WHICH ARE OR MAY BECCA%INJINIOUS TO TIE IESIGNATED USES OF TIE 68XNDWATER OR TO THE PUBLIC HEALTH THAT ARE DISCH8RGED OR EXPECTED TO BE DISCHARGED lD T}E GRIXNDWATER JIY THIS FACILITY ESTIMATE THE FINAL EFFLUENT CONCENII7ATICN AND RECORD ALL DATA IN ITIN 7 OF SECTICN II IN THIS BOOILETe t%APPLICANT MAY BE RECUIRED TD DO ADDITIONAL HASTE ANALYSEse NOT APPLICABLEJBELIEVED ABSENT NA Q RIESENT, DATA PROVIDED IN ITII8 7 ITEM 5 EXPECTED WASTEWATER CHARAC-UNcsa CODE l Mg/I 2 Ug/I 3 COUNTS/100 ml 4 S.U.5 F S LBS/DAY Ae DISCHARGE CHARACTERISTICS tV44XIIA NITROGEN (As N)TOTAL SUSPENDED SOLIDS lDTAL PteSPHORUS (AS P)TOTAL RESIDUAL Ct40RINE DISSOLVED OXYGEN MIN FECAL COLIFORM BACTERtA TEtPERATI4IE (SueCR)TEtPERATURE (WINTER)BOD5 (FtVE DAY BIOOENICAL OXYGEN OP%74))COD (Ctet ICAL OXYGEN DEMAIO)'TOC (TOTAL ORGANIC CARBON)COtKENTRATI ON LLJ~LJ~~~LJ~~LJ LJ WITS CODE tt ANALYSES SAtPIE TYPE CODE LJ LJ u1~u u>~l u>u~~5 B~OTHER WASTEWATER CH8IUtCTER I ST ICS SAMPLE ZXEF l GRAB 2 24 HOUR COMPOSITE 0 I L S G R E A S E*SEE NOTE ON PAGE 37, Outfall 003 LJ~LJ LJ LJ LJ~LJ LJ~LJ LJ~LJ REQIIRED INFC848ATICN FQI SINFACE HATER DISCH8RGESe 35 8~)<<5 r<<'1 5 8>>t'<<~I~'SC'>>','Qr h>><<3 8 5<>8 dttirs c*<<5 8 I ii csi,~Scc~I.i'4 i4<<>>c vrl"h'tcl I~>>-'5'5-8<<:r>>ct crevrcisl~18>>-i<<I<<ct I i v,-nen leave 3l'onx 3rd 3>>u-cer<<)li.e assicnec.*<<i<><<>>vise>>'.Bi 358 Di Sec, Icn i(.TCi 81cn r"clv<<ual disc"3r 8"ci~5 sBDorste$8 i v"e acct'con-snoll scaress Boc"'nese Dor<>crt-"ls S.t'all'5--".-ne crcvrc<<oter. ITEl(5 lCl.l.'.)C i l I't i hi<<>>rvhi t<<tN I't iwt 3 hc h-""uccc ED: S IGS Tc i hAT=-",o St'DFB.8 hATED-"I 8"L'cqrc IG.'.".l>g(,EE re applicant stol I report available cischarce aa.a (real cata for existlnc cischdrge or expected ddta for 3 Drooosed discharger 'cr the DdrameTers as I 5 ed.These Darareters shall be addressed for either 3 surface water dlscharae or as appropriate !or o;Dune othr cischorge. =Cr 355(stance>> Btet'tnlnir.q abprcbriate DarsreterS 3=raunCxdter alscharae ocolicanT tzy contact"e:"ovhc<<ate>> ',i31i tv~i vision, Dem(ts:Bctlcr ".;-08 ocorcbrl'dte Srovnaitdter.vol I v<<Iv(5'M'5 oi5trlct a!flee.he scclicont shall>>Sport tte srrlole tvpe>>cce best ascribing each reportea piece of data.See ccdiro cn t<<e left marqln Df is-"'-t!<<tt'3 5-r."Sce<<ate>>.I'"<<.:8.--e<<Dpi'con<<vst-Bear-T.dn-l-1 (ve cato'.-.eocr'corameter (centi!led bv on ls Br 1<<.Ce acct.cont mov, nc<<ever,-ecu85--"at-ne recort hs ot cato ct c"e cr cre D these>><<cvlrea Dora>>eters ce<<3 I vea~.I'c'l B>>ues<vst DO 5'DDort9c 3 r icBDUBTQ 1t rs t8~"dke 5I c, 1 re>>v85t 1n'I~acht"ent 0 this DD I I catlcn, Ta~5 variable ror=ther Dardmeters not I: scca 3<<ove in A.Cr ether Dar<>.temberoture, total Drencls.resiaiai chlcrire, oil and grease, and fecal coliform In 3 sur'.oce<<oter ciscndrce unless ether'recuencv-sample tvpe Snalvses are available. See Glossary (Dace 48)tor aefinitlon of,rab sample.'-nour ccmcoslte samples snail De usea to analyze fcr Total 300c, KD, TGG, crmonla i'litrogen, and Tctal suspendea Sollas ln a surface water 5)schorre unless o~her ireauency-samole tvoe analyses are avoilable. See Glossary (caoe 48)'or Ceflnlticn c!Oc>>bcsite somole.<<RED,RT)ttG titTAKE GATA, vou are riot t 8>>vireo to rebcrt unless ycu<<isn to demonstrate your Bl la(bi I ity fot'" Bt" Bf it"Bnt Ilmi.]tlcn t.O>>e cr cre collutants, nat i5.Bn elr Ivent li itatlon ad)lusted bv svDtractinc the 1VBro>>B leret Ot the DOIIC-'Snr(5) CreSBnt In your ltltake<<atBr..CCES>>BCulatiCnS allcu ret t(rtltatlonS Cniy ln ertdln=rc'mstances. -crtrcnst ate vcvr hliclbll~tv, repcrt he sverace o(the results of 3nalvses cn your-.axe<<Otet',ll Vour*aT<<'5 t, Bdtea be!ere iSB,-eST-<<e<<ater 1!ter it 5 treated).and aTtaCh 3 Separate)>>Bet cn-5 5: c 8~'t',<<a>>r r Bs>>.-Oltto<<~~i ll 5 3-h<<nt<<3't 8'a<<Q<<ot<<>>is>>rolen r>>~B>>cv Tr o<<er i'i.BB tsc'lat'ce ls]CQ h>><<5>>v<<h 8~*r 8'ri 1'rr>>of-.8<<x-hnt--r I-.r--h'>>vhi-i~<<8-cli to-5 s reavcec v treat-eht of vcvr<<aste<<ater. ns<<i 8 acjvstea onlv-=The Bxrent<<<<at-<<8 Cot Ivtdn+'5 tot re<ovea.)I iCoble i r B>rrto le~<<hen ne Ol Ivtant rebrBSents 3 Class cf~ccunCS)~3 Cemor Stratlcr of the Bvte<<t-<<<<r ICn-<<e Dollutants ln The)t<<>>dtte ve>>V>><<'/5i>>3IIV," 8<<(cal.V, I'IC)cq:CSIIV <<re 8 C(lutsr~5 Tc>tot"Bc'cur crs"arre.'c>>'t<<ST'1<<s<<:Ž8 oc'ustes" v-:-re Bxten<<--St 5-e!rtaxe coil tan=5 varf fran tile sischdrcea collvtants.) 'ite'<<o>>o<<>>~I~}<<'~5'r i 8 85'5'5 (n'c"r 8 I;.--Or'ti"shm ie lra 1nolv=e cn;v 3<<8 Cu-ro.'I 3rd 5:tt~5--8-hs.i-s--e 1>>dlvsis'",".ter substant:allv CBn~.11 v.f 3 I I s.=Ovt B>>ve55 5<<ron Bs<<v 8 B>>>>i--: nc ov n" r'.:" 8 Ser era.8 Shee-ar BC.BC t t>8 I".-'-;'-~t-Bn" i.Dl~---"~-"-'c-hr--~',:<<.<<i--8:.-".Is"'3",cv c'c.est are 5 1.'ll~i~,Brit~i'.3.<<'ti dr~<<nl i,c it.<<5 SEE INSTRUCTIONS ON REVERSE SIDE (UIFALL MP SECTlON I I PERMIT~MI 0005827 NUMBER~00 3 LITEM 6 PRIORITY POLLUTANTS AND ADDITIONAL INFORMATION FOR SURFACE WATER DISCHARGE ONLY THE FOLLCWING REQUESTED ItrFO@1ATIQN ~e" 0~AD[X[ESSED ~r SLJIFACE WATrR DISCHARGERS ~JZE!MEW USE DISCHARGERS ~PROYIQE ExPECTED vALUEs FOR IHE CUANTI TAT[YE AtrD QUA[.[TAT[YE INF IDIOM REQUESTED BELOW IS THIS FaCILITY A PRIMARY[NDUSTRY?(REFER TO TABLE[A PAGE 4~[(IF rrQ GQ TQ E)(IF YES GQ TQ B)B[MD[CATE TYPE OF PRIMARY tNDUSTRY AS LISTED IN TABLE fA PAGE 4+.(CprrftttUE WITH C.)C.OQES THIS OUTFALL DISCHARGE CCttfa[N AVY PROCFSS WASTEWATER?(IF tent, GQ TO E)([F YES,'Q TO D)D It[DICATE WHICH GC/MS FRACT[Ctrs MUST BE TESTED FCR o (REFER TO TABLE IA PAGE 4+1 XIIK.FCR EACH GC/Ms FRACTION OrECKEDi EACH SPECIFIC ORGANIC TOXIC POLLUTANT wlTHIN EACH FRACTION QgrT BE ANALYZED FOR (SEE TABLE I[A PAGE 42, IN ADDITICNi ALL PR[trARY IttDLrsTRY APPLICANTS WITH A PRQCKSS WASTEHATKR DISCHARGE~PROVIDE QUANTITATIVE DATA FCR EACH TOXIC PQLLUfAMT IN TABLE II[A Par<~$~RECORD ALL DATA ON FORMS PROVIDED (ITEM 7)IN THIS BQOKLETI (cQNT[tarE wlTH E-K BELow)X YES'rQ S T M E L E C I P W R YES trQ VOLATILE BASE/MElflRAL ACID PESTICIDE Ee IF JII(K SLJIFACE WATER DISO[ARGE APPLICANT (PRIMARY OR SECONDARY INDUSTRY)i REGARDLESS OF THE TYPE OF DISCHARGE, KJJQWS OR HAS REASON TO BELIEVE THAT ANY POLLUTANT LlslKD IN TABLE[IA AND IVA PAGES~tS DISCHARGED FRCM ANY OU[FAL4 THE QUANT ITATIVE DATA ZssL): BE PRQVIDEDI RECORD AL[.DATA OM FORMS PROVIDED (ITEM 7)IN THIS BOOKLETs Q NOT APPLICABLE/BELIEVED ABSENT O X PRESENT/DATA Is ATfACHED*F.IF A IY SLJIFACE WATER DISCHARGE APPLICANT (FR[JURY OR SECONDARY INDUSTRY)i REGARDLESS OF TYPK OF DISC5LRGEr KMWS OR HAS REASON TO BELIEVE AMY POLLIJTANTS LISTED IN TABLE VA PAGE 4Q ARE DISCHARGED FRCM ANY OUTFALL TIE APPLICANT~DESCRIBE REASONS FOR THE POLLUTANT BE[%PRESENT AND PROVIDE ANY AVAILABLE QUANTITATIVE DATAI RECORD ALL DATA ON FONS PROVIDED (ITEM 7)IN THIS BQOKLKTs X%T APPL[cABLE/BEL[EYED ABSENT PRESENT/DATA Is ATTACHED G>>ALL SU[FACE HATER DISCHARGK APPLICAMTS (PRIMrjRY AND SECONDrUIY INDUSTRIES) Es cR MAM[f'Act[REs 2, 4, 5-TR[oL[x[QPHExxY acKT[c ac[D (2.4, 5-T);-(), 4, gfR[cHLDRQPHEMQxYI PROPAMIN[c ac[D (sl[.YEx, 2, 4, 5, TP)~DIME(HYL RID, MoexoPHEMYL) P~IH[oaq (RQta~FJ'(9 4.XYI ETHYL 2-DtoaJXIQPROP[Ct[ATK (J 0, TRICHAXIOPtetQL (TCP)J OR HEXAOEGROPHE%(HCP J (ALL DATA FOR THE ABOVE PJJST BE GEJJERATKD,US[% STAICARD ANALYTICAL CALIBRATION PRQCGXRES) OR KXlts OR HAS REASON TO BELIEVE THAT TCDD IS OR MAY BE PRESENT IM THEIR DISCHARGEI rrLF[I REPORT rXJALITATIVK Dafar GEJERATKD WHIC[t USED A SCREEN[%PROCGXRE%T QK[BRATKD'WITH ANAI YTICAL STANDARDS FOR 2i 5r I 8i TETRACHLDRODIBENZQ P DIOXIN (TCDD)e RECORD ALL DATA ON FORMS PROVIDED (ITEM l)IN THIS BQOXLETa~I IF TIE SURFACE WATER DISCHARGE APPLICANT Ktows OR HAS REASON TO BELIEVE tHAT BIOLOGICAI TOXtCITY TESTS WKRE MADE IN 1HE LAST THREE (5)YEARS ON ANY OF TIE APPLICANT S DISCHARGES CR ON A RECEIV[%WATER IN RELATION TD A DISO[ARGEi PROVIDE[HIS[NFORMAT[CN AS AM ATTAOFlENT TO 1HIS APPLICATIOM>> K.[F A CCMIRACT LABORATORY OR CONSULTING FIRM PERFORMED ANY OF TJE AMLAYSES REQUIRED BY THIS APPLICATIONS PROVIDE THE MJtrE AND ADCRESS OF EAOI LABORATORY OR FIRM AN)THE ANALYSES PERFCO%D AS AN ATTACH%MT CF THIS APPLICATION. L DO YQU DISOLLRGK AMY OTIC TOXIC OR INJURIQIJS OfPIICAL SLBSTANCES NQT LISTED IN TABLES IV PAGE tt Ate I[A THIOLAI VA PAf<s~<~[4 YES, THEN IDEttf[0Y TIE OrEMICAL SUBSTANCES AND ESTIMATE THE FttlAL EFFLUENT CCttCEMIRATICNS ~SLKYIIT THIS ti&QRMATICN AS AN ATTAOMEMT TO THIS APPLICATIONS X NQT APPL[caBLE/BEL[EYKD ABSENT PRESENT/DATA I S ATTAOK)NQT APPLICABLE APP[.[CABLE/SEE AlTACHED 0%.~PL[~Q APPLICABLE/SEE ATTACHED tOT APPLICABLE Q APPLICABLE/SEE ATTACHED*Water discharged for De-Icing is the same as Outfalls 001 and 002.Indiana Michigan Power requests permission to use the screening data for Outfall 001 and 002 to characterize this discharge. 37 SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I NUMBER~MI 0005827 8IIFALL INKR~00 IT EM 7 CRITICAL MATERIALS'OXIC POLLUTANTS Ae USE THIS GATA SHEET To RECORD INFORMATION AS REDJIRED IN: (CHECK APPROPRIATE BOX RJR WHICH IMFC@1ATION THIS CATA SHEET RKPRESF2tTse) o SECTION II, ITEN I Ee GROLIGJWATER DISOIARGE INFQJTUlTION (PAGf.59 CI X 2 SECTION I te ITDI 6e PRIORITY POLLUTANTS IN SlRPACE WATER DISCHAIY)E (PAGE'7)0 X 3, B.BElow: CRITIQAL.ATKRIALS (TABLE tv)IM svRFACE waTER Dts(HARGK (PAGE 39)HAZARDOUS SUBSTANCES IN DISCHARGE B~LlsT AhY cRITlcAL MATERIAL (TABLE lv PAGE 6)NQT ADDREssED IM sEQTIGN I I ITKH R PR IQRITY POLLUTANTS wHICH YCV KNow OR HAVE REASON T>BELIEVE To BE PRESENT IM TIE DISCHARGE. SEE REVERSE SIDE OF THIS PAGE fOR FURR DIRECTtals ~NOT APPI.I CABLE X APPLICABLE (SEE BEUJW)*Ae NAJef OF CRITICAL MATERIAL OR PRICRITY POLL%ANT Be AVERAGE CCNCEMIRATIONJ SAMPLE TYPE J tI CF Au0LYSKS c..Axl~caJCKMTRATIQN AJD Hass IPJ IT CODE SatlPLE TYPE OF ANAIYSES WIT CODE UNIT CODE LJ ill CeJ Ae JJJJeE Of CRITICAL MATERIAL OR PRIORITY POLLUTANT B.AVERAGE CaJCEMTRATICNJ SA'usaf TYPEJ st OF ANALYSES UNIT CQGE SJE TYPE OF ANALYSES UNITS CODE 1 Mg/I 2 Ug/I 3 LBS/DAY 4 KG/DAY AMPLE TYPE 1 GRAB 2 24 HR.COMP.c.Haxtnfl caJCKMIRATtoN eo Mass Ae JJAHE OF CRITICAL JIATERIAL CR PRICRITY POLLlTANT B, AVERAGE CQNQEMTRATIONJ SA PLE TYPE J I OF ANALYSES Ce HAXIJ4PI CaCEMIRATICN A%MASS Ae W%GF CRITICAL HATKRIAL OR PRIORITY POLIJJTANT B~AVERAGE COJJQEIITRATlotlJ SWPLE TYPEJ te OF ANALYSES c.Haxtt1pl cowcKMIRATtat AJ4)FASS A JAPE QF CRITICAL HATER IAL CR PRIORITY POLLUTANT B.AYERAGE CCNCDITRATION; Satuuf TYPE;JJ 0F ANALYSEs Ce PAXIPIJI CaJCEMIRATIat tuD MASS Ae,'A"E CF CRITICAL HATER IAL CR PCI IQR ITY POLLUTANT B~AVERAGE CCNCEMTRATIONJ SAMPLE TYPEJ Pe OF tuIALYSES C~eVUI INH'CONCEMIRAT I ON AJD MASS Ae NA%OF CRITICAL MATERIAL OR PRIORllY POLLUTANT UNIT CODE lNIT CQGE LJ UNIT CODE SJVePLK TYPE OF ANALYSES WIT CODE WIT QXE LJ~~~LJ WIT COOK~LK TYPE OF ANALYSES LJ WIT CODE WIT CODE WIT CODE SAWLE TYPE f OF ANALYSES LJ LJ NIT CODE NIT CODE LJ~~~LJ UNIT CODE StuPLE TltPE OF ANALYSES LJ UNIT CCDE Nti CODE LJ~~~Le uJJ B.AVERAGE CmreetaTICN; SAHPLK TYPE: A'F ANALYSES I Ce MAXIM'aCKMIRAT ION AND IVES lhl IT CODE SAMPLE TYPE JJ OF ANALYSES LJ WIT CODE WIT CODE a.NAME OF CRITICAL MATERIAL oR PRIORITY POLLUTANT I Be AVERAGE CaJCEMIIIATIOMJ SAMPLE TYPEJ II CF ANALYSES Ce~AX IHUl CONCENTRATION AJ4J MASS UNIT CXE SA~TYPE OF A'IALYSES LJ lJN IT CODE NIT CQQK LJ*SEE NOTE ON PAGE 37, OUTFALL 003.ADDITIONAL PAGES QF THIS ITKH 7 ARE ATTACHED FQR T%REST QF THE CRITICAL C3 YES MATERIALS atft/CR PRIORITY POLLUTANTS REQUIRED To BE REPORTED, El NO SEE IN ON REV STRUCTIONS ERSE SIDE SECTION I I PERMIT TEM Ae IDCATION OF DISCHARGE~00 A~SW s,~NW 4, 6ECIIWI)~06, IM~06 6 6 PAI06 I I I-I DISCHARGE LOCATION SCHEDULE De IF YESs LIST DISCHARGE PERIODS NA Bs tIA%DF REcEIvttg HATER (IE~GRGUIDIATER oR t'ai%oF sUIFAcE wA Cs DO YOU DISCHUIGE SEASONAILY ~(IF NOs CONTItAIE TO E)LAK E M I MO./DAV YES X NO n./DAV FLOW RATE WASTEWATER Ee LAN APPLICATION RATE HR s/DAY IN,/wK~.u~.'m EI Nr I INI HRs~~~WASTEIIATER lYPE CCCE L~J LJ LJ LJ LJ LJ 1 CONTACT COOLING 2 NONCONTACT COOLING 3-PROCESS 4 SANITARY 5 STORMWATER ~NIT gg 1 MGY 2 MGD-3 GPD Fs lYPE OF WASTEHATER DISCHARGE Ge DISOIARGE SO%DULE (YEARLY AVBUGE)HXNS/DAY~24 esse sess~36 He DISOQRGE FLlAI RATE'OTAL YEARLY DAILY MINION DAILY MAXINII 121.5 4 g wipcoDE 0~2 0.333'2 le IHE MAXIISN DISCHARGE FUtit RATE TO BE AUIHORIZED IN PEfBITe 1 WIT=CODE J.PAXIPLH DESIGN DISCHARGE FLOI RATEe A>>IXI YOU USE HATER TREAlHENT ADDITIVES TO TREAT YNR DISCHARGE?(IF NO CONTIIAK TO ITBI 5)WIT2COPE DESIGN YES lTEM 2 Be NA%FWCTICNs AND CHEMICAL CPRSITION OF TAESE AITIITIVESe WATER TREATMENT ADDITIVES Ce NAHE AMI ACOIESS OF MAIAS'ACTINERS OF 7%SE ADO ITIVESs NA UNITS CODE 1 MQ/I 2 UQ/I NA D.EXPECTED DISCHARGE COICENIRATICN OF ACOITIVES. NA ACOITIVE NA%ANITIVE NA%ADDITIVE NA%E~CO YOU TREAT 1%DISCHARGE TO RENIVE AIXIITIVES? NA UN I TS AVERAGE CODE YES WITS MAXlttN WITS CODE CODE Fe~T IS lHE RBSVAL EFFICIENCY AIID DISCHARGE FREQUENCY? ACOI TIVE NA%AEOI TIVE N6%ACOITIVE tiVE L REIOVAL HIS./DAY DAYS/WKe LJ LJ LJ Ge AS AN AITACHIENT TO THIS APPLICATION PROVIDE SPECIFIC/%1%.IAN CR AOUATIC TOXICOUIGICAL DATA CR REFERENCE WHIOI ARE AVAILABLE AND INFORUITION CN THE RATE OF DEGRADATICN OF T%PRODUCTS FOR EACH AISITIVE NA 31 SEE INSTRUCTIONS ON REVERSE SIDE SECTION II PERMIT~MI 0005827 NUMBER IIT EM PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE POUNDS 2 GALLONS 3 CUBIC YARDS 4 TONS 5 MGY 6 MGD 7 GPD I/2 IU Or 0 0 Ih 6/2 IAI Ocvt O A.IUPE OF PROCESS IXXIIRIBUTIIIG TO THE DISCHARGE'ESI THIS OUTFALL~D SIC CODE Be PROCESS SCHEDILE (YEARLY AVERAGE)C~PROCESS WASTEIIATER FLOW RATE Basis: 1993 actual data submitted on DMRs De PROCESS PRODUCT IOtt RATE NA C.PROCESS WASTEWATER FLOW RATE De PROCESS PRODUCTION RATE A.tIAtE OF PROCESS CCIIIRIBUTIta TO THE DISCHARGE THOROUGH THIS OUTFALL AlQ SIC CODE Be PROCESS SQEIXAE (YEARLY AVERAGE)C.PROCESS HLSTEWATER FIDW RATE Ae NA E OF PROCESS CONTRIBUTltJG TO TIE DISOIARGE NA THOUGH THIS OUTFALL A'8 SIC CODE Be PROCESS~(YEARLY AVERAGE)TOTAL YEARLY DA I LY MINING DAlLY MAXI'0 LTIITS ZTI"E LJ saws/svv~seve/vsa TOTAL YEARLY DAILY MININH DAILY tQXWtI ears/ssv~seve/aa TOTAL YEARLY DAILY M INI@M DAILY MAXI'~OO A U,l BLOW BOW,N i~4>911 IOIIS/DAY~24 y~36 2 3 6 1 1 7 wlT5Lo TIME 1 HOUR 2 DAY 3 WEEK 4 MONTH 5 YEAR I/I th OWI O 0 D PROCESS PRODUCTION RATE A.NAME OF PROCESS CONTRIBUTING TO THE DISCHARGE NA TH AIS SIC CODE B~PROCESS SCHEIXLE (YEARI.Y AVERAGE)C>>PROCESS WASTEWATER FI.OW RATE De PROCESS PRODUCTIOtt RATE Ae HASE OF PROCESS CONIRIBUTING TO IIE DISCHARGE THOROUGH THIS OUTFALL A'ID SIC CCOE NA Be PROCESS SCHGXLE (YEARLY AVERAGE)Ce PROCESS HASTEIIATER FLOW RATE De PROCESS PRODUCTION RATE eases/sev~seve/vas TOTAL YEARLY CAILY MINIFY DAILY MAXI'svs/vas TOTAL YEARLY DAILY MININII DAILY M/Nit%PI UNITS CTIME UIIT CODE WITS CTIME WITS/TIME 33 "STR TI2;.'5 sSR"<<"DELETING SEGTICN I I ITEI-1S I Ai<O 2"is crm recuires'-<cr ation cn tne!ac!<(tv's clscnarce~coat(en, lscnarce so<ecule, vol.<<e flow rare and<<ater treatrent=":ITFR THE P"@IT NbuBER I:I THE BOX AT THE TP GF<HIS FGfr<.THE pERMIT)AetBER CA%BE FCUNO rtl THE FRONT PAGE GF YOUR EXPIRING"'nls's s ne<<or nct:revlousiv"er-if ec fscil'tv,"en leave.lank enc a nu per<<~Ii be asslcned.E",-e<-ne cut!all r(macr ln space provided!cr each cage c!section II.ror each Individual clscnarce point 3 separate set of formS.St e'(lied Out.'TE'A I VATIC'I,=.nE'vJLE<I<<)LOW P>TES Enter the lccaticn of discharge, this snoulc incluce cuarter-cuarter section, cuarter sect)nn, sec(ion.town.and range.3.u)St name Of reCelVlnc<<ate<<(if SurfaCe<<ater d(SCna.oe) G.InCioate wnether!cell lty dlscharceS cn a SeaScnal basis.If yes~I ist dlscnarge periods.provide the lane application rates used or excected to be used in terms of inc),es per I,our, nours pe<cav, and inches pe<week.F.Indicate the type of wastewater to pe discharged from this outfall.=afar to~he wastewater tvae code divan In the left rgin.)<ore than One Code may be applicaple. Provide the averace number of hours per day In wnlch the facllltv dlscnarges treated wastewater and the total numpe<of days per year In wnlch he cischarce occurs.urovice current (!rom tne last l2 mcnths)or expected flow rates as recuested. Refer to unit code oiven ln the left margin for the appropriate flow units.'GY-mllllcn calicns per year;'4lO-.Illlcn gallons per cay;GPO-gallons per cay.provide he rax)~um discharge flow rate<<nlcn vou<<ant.o have authorized within the permit.';0TE: ucr N>Es permits only,.he use of such a!Iow rate will not place an actual limit restrlc.lon on the flow but will be tne flow rate used to develop effluent limits.Also,<<nen the I'onthly Operating Reports are revieweC bv Compliance staff it will help them to determine (f any new or Increased uses mlcht have occurred at the facility'. !.Provide the design'low for this speci!le o tfail dlscharce (e.g.oaten treatment system flow, packaoed treatment system flow, or some other finite treatment system flow).ITEMi 2'xATER TREATF1ENT AOOITIYES'ndicate wnetner;ischa<ge <s treatec<<Ith:cndltloners. Inntb)ters, cr nicrcpfocICe. 1'ct, contirue<<o item 3.B.Give name, functlcn, and chemical ccmposltlcn of acditives used.lve name 5nd asc ass o.'",e manutac';<<"',S)O<-"e<<<<<<!ITS.Sed.'"cicate expected<<inl<,.<m. averaae snc maxi~urn Clscharce CnCent<<atlons o!tne additive(s) 'cr-nls clscnarce. '"cicate wnetner,c treat tne olscna<ce t r~ve the ace(.Ive(s<"e!cre ciscnarne of<<astewate<. '<dicate<<he r6 OVSI ef!IcienCV C.eaoh aCCit!Ve<rcm the<<aStewater'Snd the CISCharae!reCuenCy Of eaCn addltiVe tO the)urface<<ater cr..dune<<ate< .'.")E: I Is tne respcnslbll(ty o'.the applicant to supply the product information as recuested In this Iten 4.infer<ration reauested but ro Suaalied may reSV)t in the applioatlon heine returnee to the applicant'c<completlcn. SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I t4UMBER~M2 0005827 PERMIT~00 A TEM 4 GROUNDWATER DISCHARGE INFORMATION IS THE DISCHARGE FRCM THIS OUTFALL DIRECjED To THE GRIXÃID OR GROUNDtATERS7 I!F to CCtttlt2UE To ITEM))Ba WAS A HYDROGEOLOGICAL STUDY CR ITS EQUIVALENT BEEN PERRRKD OR ls THERE SIFFICIENT cURRENT HYDROGEQCQGIcaL ItFQIY4ATICN AYAllaBLE As REQUIRED BY Tl6'wATER REsoURcEs CotMISSIOtt PART ZZ GRQViDWATER RULES OF AUIUST ltt>lcM R.>23.ZZ()7 (PAGE GQ)FOR THIS EXISTM OR PROPOSED DISCHARGEZ IF YES ATTACH A COPY OF 1HE REPCRTe CI ARE YQU REQUESTlt6 att EXEt'PTIC;< FRCM SUBMITTING A HYDROGEOLOG ICAL REPORT UttDER RIXE R 323,@It (l0)(PAGE La)QR FRQM GRoutcwatER MQNITCRING IIEQUpEMENts UtlDER RULE R.Z5IZ4UI (5)(PAGE II/)OF THE PART ZZ RULES>>IF YES ATTACH DOCUMENTS AND EXPI/Utattott TO DEISNSTRAIE THAT YOR DISCHARGE WQLAD QUALIFY FOR AN EXEPP ION.DI ARE YQU REQUEsTING 4 vaRIattcE FRQM RULE 32312205 (PAGE Q (tQNDEGRADATIctt) 0F THE wATER REsculcEs cotttlss tet PART ZZ GRolfcwATER RIAEBT IF YEsi ATTAcH sUcH DQIXPtENTS AS NECESSARY TO DEMOttsTRAIE Wc NEED FCR A VARIANCE ltt TERMS CF Tte cRITERIA sPEclFIED IN RILE>Z3IZZ10 (PAGE tl7)0F 1HE PART ZZ RULEs~NA NA NA YES"ES Q YES YES NO NO N)Es I,IST ALL CHEtt ICAL$%stattCES WHICH ARE IN MICHIGAN S CRITICAL MATERIALS REGISlER TAB!E IV lPAGE D)AND/QR Vise EPA s PRICRITY PQILUTANT LlsT TABLE v (PAGE 7)0R ANY GTHER sUBsTANcEs wlcH ARE oR Hav BEcctE INJURIOUS to TIE DESIGNATED USEs OF TIE cArwowtER oR TO THE PUILIC HEALTH THAT ARE DISCH4RGED QR EXPECTED To BE DISCHARGED To THE GROUIDWATERAY 1HIS FACILITY, ESTIMATE THE FINAL EFFLUENI'ONCENIRATION attD RECORD AIL DATA IN ITEM/OF SECTta<<t IN THIS BCOasr.TIE APPLICANT MAY BE REQUIRED To DO ADDITIONAL WASTE ANALYSES.Q NQT APPLICABLE/BELIEVED ABSENT NA PRESENTi DATA PROVIDED IN ITEM 7 ITEM 5 EXPECTED WASTEWATER CHARAC" TER ISTICS UNiTS CODE 1 Mg/I 2 Ug/I 3 COUNTS/100 ml 4 S.U.5'F 6 LBS/DAY AI DISCHARGE CHARACTER I ST I CS PtSNIA NITROGEN (As N)TOTAL SUSPENDED SOLIDS totaL ptY)SFHQRUS (as p)TOTAL RES I DUAL CtLCR INE D I SSOLVED OXYGEN MIN~.LJ FECAL COLIFORM BACTERIA TEKERATlRE (SIJY4ER)TEtfiERATURE (WINTER)BO05 (FIVE DAY BIOCHEMICAL OXYGEN DB'AND)cQD (CHEMICAL QXYGEtt Der VD)TOC (TOTAL ORGANIC CARBON)CottCENTRAT ICtt BI OTHER WASTEWATER CHARAC'ST ICS Max 4~LJ utttS CODE 4 ANALYSES SA~TYPE CODE u1 ul~3~5~5 SAMPLE ZXBF 1 GRAB 2 24 HOUR COMPOSITC 0 I L B G R E a s E LJ LJ~LJ LJ~LJ LJ~LJ'J~LJ SEE ATTACHED SHEETS FOR ANALYSIS DATA REQUIRED INFOIY4ATICN FQR SURFACE WATER DISCHARGEss

• Basis: 1993 actual data submitted on DMRS

'-.--Sc.res'~'c~atlcn cn tne crccess 3-"ea s nice ocr tc louse-"-~'.3 tlscbar"8 ..TE=E-=='-""".UBER IN TPE BCX AT'-'=" f-IE.CR4.--=cEo!IIT'"trABEO C I'I BE CCUI'0 C;I TPE fRQNT OSGE CF YCUII EXPIRING--"S'S 3"eW Cr-3-:reVIC.S< ~38~"-~r'~"IlitV.-ren leaVe"land and 3 number rill be OSSICnec.E";er;.-Is ~~-.-er'" 3"ace-.Cvicec': esc-.33 8 cr Eecticn<I.=Or eccn IncivIduai ciscnarce point 3 seoara.e set cf ITE'A lr'ng f o tj~~'r~r E"-er-8"a~"'",e OrOCeSS<<nlcn Conrlautea-O,.hiS OISCnarae. ~ISO CrOVide 3"e Orober SIC COCe ncica-8--e vearlv sverace crccess screcuie'""ours cer cav ano days-cer-veer. ?rovlde tne orOCCSS waStewater ficw rate informatiOn aS requeSteo based on your last 12 months of ooerations. Refer to.nit code given in the left maroin for tne aooropriate flow units.=.Ocess orcductlon Rate-.ertain"armis'Imltatlcns mav be based cn orcductlcn rates.he oroduct'Icn rates used to tate~>.8 cermlt I'~I~S s ail be recresen-ec bv 3 reasonable measure of sctua<crocuct: n of tbe feel lltv, such as tl e , irr'n n>retious i ear,.8 rCOtnlV 3'eraCe~ne.I nes~C 8 SVICOS iV8 year S~Cr I;ner 8 sonable assure as stated'3 scoiic ble'E.E.P.A.Catecorlcal r'es sno reou>a-,lens. =cr~ew S urCeS or new OIscnarcers, actual crcouction snail be estimated vSIng orojectec=rcduCticn. uc.I 1 rates 1~"8 er>FC{V{ATIGlt ~e">0e AXRESSED~A>>eNFACE'ATER DISCHARGERS ~RHEI t>>EW USE DISCHARGERS ~s>>PROVIDE~eECTED VALUES FOR Tt ECUAVflTATIVE AND QUALITATIVE INFORMAT IGN REQUESTFD BELCH>>A>>IS THIS FACILITY A PRltARY Itt{XSTF(.(REFER TO TABLE IA PAGE+{IF NO>>GO TO E)(IF VES>>GO TO B)B~IhDICATE TYPE GF PRIMARY ltOUSTRV AS LISTED IN TABLE IA PAGE<>~(CQttftttUE WITH C.)C.DOES THIS OUTFALL DISQ{ARGE CCtffAIN Ar{Y PROCESS WASTB{ATER.(IF NO>>GO TO E)(IF VES>>GO TO D)D>>INDICATE WHICH GC/r'S FRACTIQr{S>>MUST BE TESTED FOR~(REFER TO TABLE IA PA">>E~t IIQIEI FCR EACH GC/MS FRACTION CHECKED>>EACH SPECIFIC ORGANIC TOXIC POLLUTANT WllHIN EAGH FRAGTINt QADI BE At{ALYEM FGR (sEE TABLE I IA PAGE tt2.It(ADDITION, ALL PRIMARY It>>DUSTRV APPLICANTS WITH A PROCESS WASTEWATER DISCHARGE~PROVIDE QUANTITATIVE DATA FOR EACH TOXIC POLLUTANT Itt TABLE I I IA PAGE.RECORD ALL DATA OM FORMS PROVIDED (ITEM 7)IN THIS BOOKLET.(CONTINUE WITH E K BELCH)VES tO STM EIL EC PWR X YES tO V{XAT I LE BASE/NEUTRAL ACID PESTICIDE*ED IF~SLIPPAGE WATER DISCHARGE APPLICANT (PRIMARY OR SECCr{DARY it{DUSTRY)>> REGARDLESS OF THE lYPE OF DISCHARGE>> KIKWS CR t>>AS REASON TO BELIEVE THAT Attf POLLVfAMT LISTED IN TABLE I IA AND IVA PAGES~IS DISCHARGED FRCM ANY OUTFALL>>THE QUANTITATIVE DATA BE PROVIDED RECORD ALL DATA ON FORMS PROVIDED (ITS>>t 7)IN THIS BOOKLET>>>>tOT APPLICABLE/BELIEVED ABSENT O X PRESENT/DATA I S ATTACHED F~IF ANY SURFACE WATER DISCHARGE APPLICANT (PRIMARY OR SECONDARY INDUSTRY)>> REGARDLESS OF TYPE OF DISCSUIGE>> KIOWS OR HAS REASON TO BELIEVE ANY POLLUTANTS LISTED Itt TABLE VA PAGE{I>>>>ARE DISCHARGED FRQ{ANY CUTFALL THE APPLICAVT VII'ESCRIBE REASONS FOR THE POLLUTANT BEING PRESEttf At{D PROVIDE ANY AVAILABLE QUANTITATIVE DATA>>RECORD AIL DATA GN FGIV{S PROVIDED (ITEM 7)IN THIS BOOK!ET>>X tOT APPLICABLE/BELIEVED ABSENT PRESEMT/DATA IS ATTAQ{ED G.AIL S{IIFACE WATER DISCHARGE APPLICANTS (PRIMARY AttD SECONDARY INDUSTRIES) E)CR MANIA-ACTNES 2.4i)-TRIQKDRGPHEIOXV ACEftg ACID (2.4i 5-T)l-I),.5-)AtO 4>>5 TRICHLGROPHEIOXV PROPANOIC ACtD (SILVEX 2>>4>>5>>TP)'Z.4.>IRIQ{LGRGPHEtOXV) ETHYL 2, 2-DICHLGRGPRGPIGMATE (ERBGMt;0, 4 NTRICH OROPHE{OL (TCP)>>OR HEXAQl.OROPHENE (HCP)t (AIL DATA FOR THE ABOVE t>>UST BE GEhERATED USING STANDARD At{ALYTICAL CALIBRATION PROCHXRES) OR KIOWS CR HAS REASON TO BELIEVE THAT TCDD IS CR MAY BE PRESENT IN THEIR DISCHARGE>> ~REPORT 9IALITATIVE DATA, GEIERATED WHICtt USED A SCREENltO PROCHXRE tOT CALIBRATED WITH AVALYTICAL STAt{DARDS>> FGR 2.>>>/8>>TETRACHLORODIBENZO P DIOXIN (TCDD)>>RECGRD ALL DATA ON FORMS PROVIDED (ITEM))IM THIS BOOKLET>>J~IF THE SURFACE WATER DISCHARGE APPLICAMf KtOWS CR HAS REASON TO BELIEVE lHAT BIOLOGICAI TOXtCITY TESTS wHIE vADE IN THE LAST TWEE (5)YEARS OM ANY OF THE APPLtCArlT S DISCHARGES OR CN A RECEIVINS WATER IN REIATINt TO A DISCHARGE. PROVIDE THIS INFORMATION AS AV A1TAQI{EMT TO THIS APPLICATION>> K IF A CONTRACT LABORATORY OR CCrtSULTING FIRM PERFCRMED Ath'F THE AIN{YSES REQUIRED BY THIS APPLICATION, PROVIDE THE NAME AND ADDRESS OF EACH LABORATCRY OR FIRM AND THE ANALYSES PERP'"Ht AS AV ATTACHMENT OF THIS APPI.ICATtON>> 'L.DO YOU DISCHARGE AN OTHER TOXIC OR INJ(PIOUS CHEMICAL S{8STANCES tOT LISTED IN TABLES IV PAGE (I Al>>D I IA THROU 4l VA PAGES V~A+>>c YES>>THEN IDENT I CHEMICAL SUBSTANCES A'O ESTIMATE THE Ftt{AL EFFLUEttf CCtKENTRATICr{S. SUIT{IT THIS IhFORMATION AS AV ATTAQteENT TO THIS APPLICATIGN>> NOT APPLICABLE/BELIEVED ABSENT PRESH{f/DATA tS ATfACHED NOT APPLICABLE APPLICABLE/SEr AlTACHED NOT APPLICABLE X APPLICABLE/SEE AlTACHED X tOT APPLICABLE APPLICABLE/SEE ATTACHED*Pesticide data is not required;however, it is provided.37 IIISTROCTIONS.Oo CCfJPLETI'/3 SECTIC!I I I ITEMS 4 ANO S.his form reculres Inforration on a speci!ic cut!all lscnarglng to either,he grouncwaters or The surface waTBrs.rENTER THE P ozz(T NLSIBER IN THE BOX AT THE TW CF THIS FCRM.THE PEIB(IT NONBER CAN BE FOUND Oi THE FRONT PAGE OF YCOR EXPIR(tfg CERuli~:.',~5(S (S a rew Or nOt preV(cuS(V permitted faCI I(ty, Then leaVe blank and a number Will be BSSICred.nter-B cu~fa(I umber In The space provided fcr eben pace of Section I I.For eacn individual dlscharce point a separate set"'n-T!Bn!','"rms (Items'nc)must=e filled out.ITE)l 4 SBDJ;.WA==DISCHARGE INFCi JAT(CN (00 N"T iNCLCCE DEEP WFL(.I"JECTION INFC"NATION I'I THIS ITEvl)A.-D.he applicant shall address each of these parts lf the clscnarce from this outfall is to the oroundwater. ITEM 5<ISTI"G CR EXP CTED~FOR A NEW O(SCHARGE) <<ASTFWATER CHAoACTERISTICS CF SR v'4)WATER OR SI'RFACE WATEo DISCHARGE (DO"OT'NCLUDE hcLL INJ 3ICN IN RNAI'I IN H r VI The applicant shall report available discharge data (real data Aor existing discharge or expected data for a prcposed d(scharge) fcr the parameters as listed.These parameters shall be addressed for either a surtace~ater discharge or as appropriate for a groundwater dlscrarge. For assistance in determlnlno abproorlate par~ters a orcundwater dlscharce applicant may contact the<<Arouncwater Dual (tv olvlslcn, permits section or tne appropriate Grouncwater Duality oiv(s(on's District office.The applicant shall report the sama(e Type code best describing each reported piece of data.See coding on the left margin of this form.If This outfal(ls a surface water ciscnarce. tne applicant must repor-ouantitative data for each parameter Identified bv an asterisk.,he appi cant may, however, recuest That-ne report nc o, cata<<or cne or more o~hese reouired oarai.eters be<<aivec.Such recuest must be supported by acecuato<<atlcnale. i'ake such a recuest an attachment.o this application. 'I'ata is availabke fcr ether parameters not IisTBd abovB (n A.or ether parts ot this application the applicant should report hat cata ln The blank spaces provldea:n this part.I"OTES: I.Ontt codes for parameters reported In parts A and 8 can be found on the lett hand side of thIs form.Grab samole snail be used Tc analyze tor pH, Temperature, total ohenols, residual chlorine, oil and grease, and fecal col)form In a surface water discharge unless other frecuencv-sample type analyses are available. See Glossary (pace 48)for definition of grab sample.24-hour~pcs(te samples shall bo used to analvze for Total BMs, CCO, TOC, Armon(a Illtrcgen, and Total Suspended SO(iCS in 4 SurfaCe water CisCnarge un(BSS O~her freauenoy-Sample type analySeS are BVBI (able.See GIOSSary (page 48)for definition of compos(te sanole.REPORT(l)G CF INTAKE CATA.'5u are not reruired To reOCr.unless you wish to demcnStrate yOur ellciblllty for 4"retw sff I ent l(mltat(cn 'Cr One Or mere POllutantS, that IS, an effluent limitat(On adjuSted by SubtraCtlng the average level o!the col lutantfs)present In your Intake water.NPOES regulations al low net I (mltatlons only In certain circtmstances. c cnronstraTe vour ellclbl litv,-epor T the averaco of the resui 3 of analvses on your 3 I)r*u ii').B B'C B ie, B<<.eare<<sf Br'.IS T.eated)~\5 3, sebaratB"BBT"cnt!ning Tre fc)lc in@fcr Bach oiiutanT: (5)<state ent T"at-"B Intake water'3 drawn'rcm Tre cccv of water.(nto which the d(scnarqe Is~ace.('.Ther lse,'ou are-;: ellcible!cr net i:m(tat(ons.) ib)>state"ent o!e Bxront.which.ne level of tne.I futant is reduced bv Treatment of ycur<<astewater.(Your"Im(tationa <<ill pe aajuStec Only TC The eXTent Teat the pCI(utant 3S nct remOVed~)<<'C)ahen acplicao)e (tcr example,<<hen.ne pollutant represents a class of compounds), a demcnStrat(cn of the<xtent<<o.<<wlc"~ii<<tc(33tants i ne (~~eke very p";3'cai Iv, chemical lv,'biological(v 'rom T"e pc(lutants contained In vour clscrarge.(Your (in(tat)cna <<Ill be adjusted only TO the extent That tne intake pollutanTS do not vary from tne d(scnargeo pollutants.) vcu nave t'<<o or-cre i.stantial ly L cantle<<'utfs ~fs,,cu mav recuest cer..isslon from peur per-,ittinc 5urnoritv Tc sa<<aie ano ari)!vze on'v.-.e cut!el I snc suc.I-"B resul 3 of the analvsls fcr ether suostantlal ly CB'it3C51 cut!5(ls.'>>ur r<<ciest~3 Trente)bv-he pe~i-(no ausncrltv, cn a seoarate sheet at-ac"Bd to.the 3.""Icatlci.cr<<i fcenT<<(*ni ln ut'5l'i,.u die est, 5.c:ascribe wnv ne ourfai ls<<Bien.u cid.c TBST are su sT5n ial IV ldenticai zo-re ouT!all wnlch vou J(d Tes SEE INSTRUCTIONS ON REVERSE SIDE SECTION II PERMIT~MI 0005827 NUMBER EM CRITICAL MATERIALS TOXIC POLLUTANTS A.USE THIS DATA SHEET TO RECCRD It(FORMATION AS REOUIRED IN: (CHEQ(APPROPRIATE BOX FOR WHICH ItiFORMATICN THIS DATA SHEET REPRESEIITS )1 e SECT ION I I P ITEM 4 E e GROWDWATER DISCHARGE ltIFCNAT ION (PAGE 55)2.SECTION IIP ITEM 6.PRIORITY POLlJITANTS Itt SURFACE WATER DISCHARIZ (PAGE 37)O X 3e B.BEIDW: CRITICAL YATERIALS (TABLE IV)IN SURFACE WATBI DISOIARGE (PAGE 2)HAZARDOUS SUBSTANCES IN DISCHARGE Be LIST AttY CRITICAL YATERIAL (TABLE IV PAGE 6)NOT ADDRESSED Itl'SECTION II ITEM Fe PRIOIIITY FOLUITAIITS WHICH YOU KNOW OR HAVE REASON TO BELIEVE TO BE PRESENT Itl TIE DISCHARGEP SEE REVERSE SIDE CF THIS PAGE FOR FUItTIFR DIRECTIONS ~NOT APPLICABLE APPLICABLE (SEE BaDW)Ae NAPE OF CRITICAL MATERIAL OR PRIORITY POLUITANT*H dr a'z inc 00 30 2 0 12 UNITS CODE l Mg/I 2 UQ/I LBS/DAY KG/DAY It LIt~I Bs AVERAGE CONCENIRATIONI SAIPLE TYPE;II OF AIALYSES C>>teAXI.'VI CCttCENIRATI ON Ata YASS As ePYYE OF CRITICAL MATERIAL OR PRIORITY POLLUTANT Bs AVERAGE CONCENTRATION; SAMPLE TYPEl lII OF ANALYSES Ce YAK IF'NCENNIRIATION AttD MASS Ae ttAIIE OF CRITICAL MATERIAL OR PR ICRllY POLU/TANT Be AVERAGE COICENIRATICNI SAMPLE lYPEi tt OF ANALYSES Ce MAXI'ONCENIRATION AND MASS Ae NAME OF CRITICAL MATERIAL CR PRIORITY POLUITANI'IT CODE SAMPLE TYPE CF ANALYSES LJ I I.LJJ J LJ LJ WIT CODE WIT CODE LJ~~~LJ UNIT CODE SAYPLE TYPE OF ANALYSES~.LLLJ LJ WIT CODE WIT CODE LJ WIT CODE SAMPLE TYPE OF ANALYSES LJ Wll'ODE WIT CODE LJ~~~LJ 3.AVERAGE COtICENTPATICNP SA"PLE TYPEI II OF AIIALYSES WIT CCDE~LE TYPE LJ OF ANALYSES Ce YAXltul COtLENTRAT ION AND MASS~PMPL YYP l GRAB 2 24 HR.COMP.As NAtE OF CRITICAL MATERIAL OR PRIORITY POLLllTAttT Ce eMAXIYUYI COtlCENIRATIOtt Ato YASS Ae ttA'IE OF CRITICAL MATERIAI.OR PRICRITY POLLUTAIIT 3~AVERAGE CCttCENTRATIONI SAMPLE TYPEp ee OF ANAI.YSES Ce"AX!le'COIICENTRATIOI Ate YASS B, AVERAGE CCIICENIRATIONl SAMPLE TYPE;Itt OF ANALYSES I UNIT CODE WIT CODE LJ~~~LJ WIT CXE SAtPLE TYPE II OF ANALYSES LJ WIT CODE WIT CODE LJ~~~LJ WIT CODE SVPLE TYPE h OF ANALYSES LJ WIT CODE WIT CODE Ae tIAYE OF CRITICAL YATERIAL CR PRIORllY POILUTANT 3.AVBVGE COttCENIRATICtt; SA~TYPE: tt OF ANALYSES I Ltl I T CODE SAtPLE lYPE OF ANALYSES Ce YAXIMN CONCENIRAT ION AND MASS Ae tIAYE OF CRITICAL MATERIAL OR PRIORITY POLUJTAeVT WIT CODE WIT CODE LJ 3~AVEPAGE OIWCENIRATIONI SAMPLE TYPEI II OF ANALYSES Ce MAX IYLM CONCENTRATICN AttD MASS WIT CCOE SAYPLE TYPE OF AttALYSES LJ WIT CODE WIT CODE LJ ADDITIONAL PAGES OF THIS ITEN 7 ARE ATTACIED FOR TIE REST OF THE CRITICAL C3 YES MATERIALS AND/CR PRICRITY POLLUTANTS RECUIRED TO BE REPORTEDi El NO+Hydrazine is not expected to be present in discharge but small quantities may be found in the steam generators but would not be expected to be found in the actual discharge flow to Outfalls 001 or 002.39

iSTRVCTIr..'S c

q CCIip(.ETI r, SECTic;i I'TEM 6 his orm recuires Iniormarion on a specific ourfol I

iscnorql"c ro the sur!oce<<oters.:"I Ec PE pERFIIT'4,'~'J)ER lii THE BOX A THE T&CF HIS PCS..fE PEPMIT':WMSER CAN EE FOvh0 CN THE FRONT PAGE OF VCvp EXPiRING oERMIT.'I rois is o new or not previously permitted feel litv,,hen leave plonk ana o nuroer wli I be osslaned.e e u~foi I number in the space provided fcr each page o'ection I I..or each inaivicuol dlscnorce point 4 separate ser Sacr!cn:'I.

item 6 forms nusr oe filled our.iTEM 6 opICRIr" cx)ll.UTAH(TS ANO ACOITICIIAI. I'IFCRMATION 'IOTE: A~I ona lf vou hove t<<o ar more substanrlol ly indenricoi ourfoi Is, you may reavest permission from vour perm(trina outnorlty to sample ond analyze only one outfall and submit rhe results of the onoiysls for other substantially Identical cutfalls.If your reauest Is granted by rhe permitting outnoritv, on a separate sheet attached to rhe application form Identify<<hlCn Outfal I ycu ald teor, Ond deSCrlbe wny ti.e OutfallS wnlah yau did rOt reSt Ore SWPStantlal ly Idenrlaal-O the Outfall<<nich You old rest.40 CFR Part I22.2l(g)<8), Friday, Abri I I, l983~provides for o Smail Business Exemoticn from the reporrlrg of auontitotlve aota for organic toxic pollutants ond tcxlc pollutants os reaulred by port 122.2I(g)<T)<il)(A) or 122.21(q)(7)<ili)(A). These parts ore self-explanatory and do not require furrher Instrucrions. S(moly oo hrough each parr and do os Indicated. Several Industrial categories and subcategories hove been.exempted frcm submitting dora on certain GC/ius Froctlons (40 CFR Part (22, Vol.48, lio.64, Friday, April I, l983, Iiotes I, 2, and 3).Review the following list to determine whether your facility qualifies to be exempt from reportlna Gc/Ms (Gos chromotoarephy/ Moss Spectroscopy) Fractions. Textile MIIIs Industry GCIMS Fraction Testing ond peporrlng Exempt(cns -AII!our GC/MS organic fractions in rhe Greige MIIIs Subcategory. -Pesriclde fraction In ail other subporrs of this Industry.Ore Mi nina and Dressing Industry-volatile, bose/neutral, ond pesticide fractions In rhe Base ond precious Metals subcategory. -AII four GC/MS orqonic fractions in oll other subcategories of this Industry.Gum and'Wood Chemicals Industry-Pesticide fraction in the Tall Ol I Rosin Subcategory and the Rosin Based Derivatives Subcategory. -Pesticide and base/neutral fractions in all other subcateaories of this Industry.eulo and Paper Industry-Pesticide fraction in Papergrade Sulfite subcateaories (subparts J and U).-Base/neutral and oesticlde fractions in Deink Subpart q, Oissolvlna Kraft Suboart F, and paperboard from Waste Paoer Subpart E..volatile, base/neutrals pesticide I'rect lons In the BGT Bleached Kraft Suboart H, Semi-chemical Subparts 8 and C.and Nonintegrated-Fine Papers Subpart R.-Acid, base/neutral, and pesticide fractions In Fine Bleached Kraft Suboart I, Oissolvinq Sulfite Pulo Subpart K.Ground-wOOd Fine paperS Subpart 0, Harket BleaChed Kraft Subpart G~TiSSue frOm'WaStepaper Subpart T~and NOnintegrated TISSue Papers Subpart S.Steam Electric Power Plant Industr-Base/neutral fraction In the Once-Through Cooling water Fly Ash.and Bottom Ash Transport water orocess wastestreams. 38 GENERAL CHEMISTRY RESULTS Client Sample ID: OUTFALL OOA-VI)-SLOWDOWN LAL Batch ID(s): 126 im, 127 im, 128 im Date Collected: 01-26-94 Matrix: water Date Received: 01-28-94 P0469095-040-3N 'Constltuerit Fluoride in m IL Bromide, inm IL Nitrite-Nitrate-Nitrogen, inm IL Sulfate inm IL Total C anide, in m IL Color Total Phenolics, in m IL Sulfide in rn IL Sulfite, in m IL Method 340.2 300.0 353.2 300.0 335.2 110.3 420.1 376.1 377.1 Result<0.15<0.050<0.050<0.059<0.020<5.0<0.15<1.0<1.0 Reporting,,','";. Detection'Umlt'.15 0.050 0.050 0.059 0.020 5.0 0.15 1.0 1.0..-,,;Date QualNer(s) Date Anal zed 03-02-94 02-17-94 02-11-94 03-05-94 02-07-94 01-28-94 02-08-94 01-29-94 01-29-94 LAL Sam le lD L1 1 50-3 L11 50-12 L1150-15 L1 1 50-12 L1150-18 L1160-3 L1 150-24 L1150-9 L1160-6 Comments: 0 GENERAL CHEMISTRY RESULTS Client Sample iD: OUTFALL OOA BLOWD OWN LAL Batch ID(s): 126 im, 127 im Date Collected: 01-26-94 Matrix: water Date Received: 01-27-94 PO¹69095-040-3N Constituent Total Phosphorus, in m/L Ammonia-Nitrogen, inm IL Total Suspended Solids, in m IL Total Organic Carbon, inm IL Chemical Oxygen Demand, in m IL Total Kjeldahl Nitrogen, in m/L Method 365.2 350.1 160.2 415.2 410.2 351.2 Result<0.030<0.050<12 1.8<18 2.4 Reporting Detection Limit 0.030 0.050 12 1.0 18 0.10 Data Qualifieris) Date Anal ed LAL Sam le ID 02-08-94 L11 42-8 02-01-94 L1142-8 02-16-94 L1 142-4 01-28-94 L1142-4 03-03-94 L1 142-8 0242-94 L1 142-12 Comments:

METALS RESULTS Client Sample ID: OUTFALL OOA-U/I-BLOWD OWN LAL Batch ID(s): 126 im Date Collected: 01-26-94 Date Received: 01-26-94 Matrix: water PO469095-040-3N Constituents Method Concentration lm IL)Reporting Detection Umlt Im IL)Data Qualif)eris)Date Anal zed LAL Sam le ID Aluminum Antimon Arsenic Barium Be ilium Boron Cadmium Chromium Cobalt Co er Iron Lead Ma nesium Man anese Mercur Mol bdenum Nickel Phos horus Selenium Silver Strontium Thallium Tin Titanium Uranium Vanadium Zinc 6010 6010 7060 6010 6010 6010 6010 6010 6010 6010 6010 7421 6010 6010 7470 6010 6010 6010 7740 6010'.6010 7841 6010 6010 6020 6010 6010<0.20<0.060<0.010<0.20<0.005<0.005<0.010<0.050<0.025<0.10<0.003<5.0<0.01 5<0.0002<0.067<0.040<0.050<0.005~<0.010<0.10<0.010<0.20<0.10<0.001<0.050<0.020 0.20 0.060 0.010 0.20 0.005 0.20 0.005 0.010 0.050 0.025 0.10 0.003 5.0 0.01 5 0.0002 0.067 0.040 0.050 0.005 0.010 0.10 0.010 0.20 0.10 0.001 0.050 0.020 02-22-94 L1150-52 02-22-94 L1150-52 02-20-94 L1150-52 02-22-94 L1150-52 02-22-94 L1 150-52 02-22-94 L1150-52 02-22-94 L1 150-52 02-22-94 L1150-52 02-22-94 L1 150-52 02-22-94 L11 50-52 02-22-94 L1 150-52 02-23-94 L1150-52 02-22-94 L1 1 50-52 02-22-94 L11 50-52 02-09-94 L1150-52 02-22-94 L1 150-52 02-22-94 L1 150-52 02-22-94 L1150-52 02-25-94 L1 150-52 02-22-94 L1150-52 02-22-94 L1150-52 02-28-94 L1 1 50-52 02-22-94 L1 1 50-52 02-22-94 L1 1 50-52 03-07-94 L1 1 50-52 02-22-94 L1150-52 02-22-94 L1150-52 Comments:

VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 1 of 2 li n m le ID: TFALL A-I BL WD WN Date Collected: 31-JAN-94 Matrix: WATER Anl i IB¹: 244--1 QC Batch ID: 020494-8260-C1 LAL m I ID: L117-2 Date Received: 01-FEB-94 Date Anal zed: 04-FEB-94 Dil inF r 1 SURROGATE RECOVERY 1 2-Di hl h n-4 Tol n-QC Limits 7-114-110 4-Bromofluorobenzene 110 86-115 Constituent Chloromethane Vin I hl ri Brmm hn Chloroethane Trichlorofluoromethane A n 11-Di hl r h n Carbon Disulfide Meth lene Chloride r n-12-Dihl r hn Vin I A 1 1-Dichloroethane 2-Butanone i-12-Dihl r h n hlrfrm 1 1 1-Trichloroethane Carbon Tetrachloride 12-Dihl r h B nz n Trichloroethene TCE 1 2-Dichloro ro ane Brm ihlrm hn 2-hl r h I Vin I E h r 4-Meth 1-2-entanone cis-1 3-Dichloro ro ene T I n r n-1-Dihl r r n 2-Hexanone 1 1 2-Trichloroethane Tetrachloroethene PCE Concentration IL<5<5<5<5<5<5<10<5<5<5<5<2<10<5<10<5<5 Reporting Detection Limit IL 10 10 10 Data Qualifier s LOCKHEED ANALYTICAL SERVICES VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Client Sam le ID: OUTFALL OOA-U/I BLOWDOWN LAL Sam le ID: L1175-23 Page 2 of 2 Constituent Dibromochioromethane hl r nz n Eh I n n m-X lene o-X Iene r n r m f rm 1 1 2 2-Tetrachloroethane 1 3-Dichlorobenzene 1 4-Di hl r nz n 1 2-Dichlorobenzene Concentration IL<5<5<5<5<5<5 Reporting Detection Limit IL Data Qualifier s LOCKHEED AIVALYTICAL SERVICES SEIVIIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Pa 1 of 2 li n Sam I ID: TFALL A-U I BLOWD WN Date Collected: 26-JAN-94 Matrix: WATER Anl i IB h¹: 2 4-27-A QC Batch ID: 8270 SEMIVOLATILES 4825 LALSml ID: L11 Date Received: 28-JAN-94 Dilution Factor: 1 D Exr d: 1-AN-4 Date Analyzed: 04-FEB-94 SURROGATE RE VERY 00 2-Fluoro hanoi Phenol-d, Nitrobenzene-d, 2-Fl oro'en I 24-Tri r mo n p-Terphenyl-d,4 42 30 84 38 QC Limits 21-100 10-94 35-114 4-11 33-141 Phenol Constituent Concentration IL<10 Reporting Detection Limit IL 10 Data Qualifier s i 2-hl r h I h r hir hnl 1 3-Dichlorobenzene 1 4-Dichiorobenzene Bnzl I hl 1-Di hl r nz n 2-Me h I henoi bis 2-Chloroiso ro I ether 4M h I h n I N-Ni r-Di-n-r I in Hexachloroethane Nitrobenzene I hrn-Nir h n I 2 4-Dimeth I henol Benzoic acid i 2-hlr hx m hn 24-Dihl r hn I 1 2 4-Trichlorobenzene Na hthalene 4-hl r nilin Hx hlr u in 4-Chloro-3-me h I henol 2-Meth Ina hthalene Hexachloroc clo entadiene<10<10<10<10<10<10<10<50<10<10<10<10<10<10 10 10 10 10 10 10 10 50 10 10 10 10 10 LOCKHEED ANALYTICAL SERVICES I SEIVIIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Client Sam le ID: OUTFALL OOA-U/I BLOWDOWN LAL Sam le ID: L1 1 50-30 Pa e2of2 Constituent 2 4-Tri hloro hanoi 4-Trihl r h n I 2-Chlorona hthalene 2-Nitroaniline Dim h I hh I A n hhln 2 6-Dini rotoluene 3-Nitroaniline A n hhn 2 4-Dini r h noi 4-Nitro henol Dibenzofuran 2 4-Dini r I en Di h I hh I 4-Chloro hen I-hen lether Fluorene 4-Ni r nilin 4-Dinir-2-m h I h n I N-Nitrosodi hen lamine 4-Bromo hen I-hen le her Hx hlr n n Pn hlr hn I Phenanthrene Anthra cene r z I Di-n-I hh I Fluoranthene P rene B I nz I'hh I 3'-Di hl r nzi in Benzo a anthracene Chr sene i 2-Ehlhxl h I Di-n-I hh I Benzo b fluoranthene Benzo k fluoranthene Bn rn Concentration (/L)<10<25<10<25<2<25<10<10<10<2<10<10<2<10<10<10<10<20<10<10<10<10 Reporting Detection Limit I/L)10 10 10 25 10 10 25 25 10 10 10 1 2 10 10 10 10 10 10 20 10 10 10 10 Data Qualifierls) In n 12 r n Dibenz a h anthracene Benzo h i er lene<10<10 10 10 LOCKHEED ANALYTICAL SERVICES SEMI-VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8270 TENTATIVELY IDENTIFIED COMPOUNDS Client Sample ID: OUTFALL OOA-U/I BLOWDOWN LAL Sample ID: L1150-30 Date Received: 28-JAN-94 Matrix: WATER Analytical Batch: 020394-8270-A Date Analyzed: 04-FEB-94 Dilution Factor: 1 QC Batch ID: 8270 SEMIVOLATILES 4825 Tentatively Identified Compound Unknowm Organic Acid Estimated Concentration (yg/L)Retention Time (minutes)25.24 Data Qualifier(s) f Cn LOCKHEED ANALYTICAL SERVICES

OIL AND GREASE EXTRACTABLES ANALYSIS RESULTS BY FT/IR USING IVIETHOD 413.2 lin m I ID: TFAL-IBL WD WN D Ilc:2-AN-4 Date Received: N A Matrix: WATER Anal tical Batch¹: 020494-413.2 A m I ID: 11.42 D An I z: 7-FEB-4 Dilution Fac or: 1 Da e Extracted: 02-FEB-94 QC Batch ID: 020294-413.2 Constituent Oil and Grease Concentration m/L Reporting Detection Limit m IL Data QualifierIs) LOCKHEED ANALYTICAL SERVICES PESTICIDE ANALYSES RESULTS BY GC/ECD USING METHOD 8080 Cli n S m ie ID: TFALL 0 A-U I BL WDOWN Da Coll e:2-AN-4 Date Extracted: 31-JAN-94 Matrix: WATER Analytical Batch II: 013194-8080-E-4 LAL'S m I ID: L11 D R ive:2-AN-4 Date Anal zed: 01-FEB-94 Dilution Factor: 1 QC Group ID: 8080-PEST/PCBS 4822 SURRO ATE RECOVERY o QC Limits TCMX DCB 69 27"'0-150 60-1 50 A-BH B-BHC G-BHC D-BH Constituent r Concentration L<0.05<0.05 Reporting Detection Limit L 0.05 0.05 Data Qualifier(s) HEPTA H R ALDRIN HEPTACHLOR EPOXIDE HL R DANE END ULFAN I A-CHLORDANE 4 4'-DDE 4 4'-DDT DIELDRIN ENDRIN ENDOSULFAN II 4 4'-DDD ENDRIN ALDEHYDE ENDOSULFAN SULFATE'ETH OXYCHLOR T XAPHENE P B-1 1 PCB-1221 PCB-1232 P B-1 4 PCB-124 PCB-1 254 PCB-1260 TECHNICAL CHLORDANE TCMX-tetra-chloro-meta-xylene DCB-Deca-chloro-biphenyl <0.05<0.05<0.05<0.1<0.1<0.1<0.1<0.5<2 0.05 0.05 0.05 0.1 0.1 0.1 0.1 0.5 LOCKHEED AIVALYTICAL SERVICES RAD DATA REPORT (ra01)Indiana Nichigan Pouer Co.e Bridgman,HI Organic and Inorganic Contaminants (project COOK.JENI) Client Sample ID: OU'IFALL OOA-U/I BLOlDOMN Date Collected: 26-JAN-94 LAL Sample ID: L1150-46 i Date Received: 28-JAN-94 Hatrixt Mater Login Number: L1150 Gross Alpha Gross Beta 23-FEB-94 GR ALP/BETA LAL-0060 4756 23-FEB.94 GR ALP/BETA LAL-0060 4756 0 30.2 0.69 3.2 1.5 3.1 pC I/L pCi/L Page 6 nag<v'5

RAD DATA REPORT (ra01)Indiana Nichigan Parer Co.*Bridgman,NI Organic and Inorganic Contaninanta (Project COOK.JENI) Hatrixt Water Client Sangria ID: OUTFALL 00A-U/I BLOUDOMN Date Collected: 26-JAN-94 LAL Saapie ID: L1150-49 Date Received: 28-JAN-94 Login Nmhert L1150 Ra-226 Ra-228 22-FEB.94 RA-226 LAL.0073 4771 23.FEB-94 RA-228 LAL-0074 5503 0 0.62 0.14 0.34 pCI/L 0.56 0.91 pCI/L g Page 9 h~I PH Meter cpc y-lo~Cal date due Sample Time Sampl'e g Sample Date CDM Entered by PH Analysis (LAB.079)Outfall OOA 0 P D 5.3.5 6)Sample C/ph (prior to correction) 7)NH3 pH correction g oz.5.3'Sample Sample Time Sample jj Sample Date CDM Entered by 8))ample results C/pH (af ter'7.7 g NH Correction) 3+boa m cux-p'-4~/+/7>+U+/L Zoo 5.3.5 6)Sample C/ph (prior to correction) 7)NH3 pH correction 5.3.6 8)Sample results C/pH (after Correction) 9)LAB.041 Specs Verified by: hl/8 Supervisor Review/Date ~W+IW Form prepared by/Date Form approved by/Date 12 THP LAB.041.25s Revision 1 --4 Outfall OOA Sample/Standard Sample g Date Time CDM Entered by)So Determination of Total Chlorine (Lab 170)/0~~'~~(y~~/'/Instrument CPCf)Technician Vi l)Absorbance 6.11 2)Results, ppm 3)Dilutions made 4)Results, ppm (I)2~0 3)z oC 51 LAB.041 Specs Verified by:~N Fl luperi rvRsecview/Bere~~HI +Form prepared by/Date Form approved by/Date~~~12 THP LAB.041-25)l Revision 0 SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I PERMIT~gZ ppp582~%tS Iy~A.LOCATIOtt OF DISCHARGE ASSt i,~W i,>>ZCTIUN t~06, iUPN~06 S, iTTUE~i9 W DISCHARGE 8>>tIA%RECEIVlttG HATER IIE>>GROItZHATER OR NAPE OF SIRFACE HA C>>DO YCU DISCHARGE SEASOttALLY>>(IF ttOP CCIIT!t@E TO E)LAIKE MI C HI YES X ta LOCATION D.IF YES>>I.I ST DISCHARGE PERIODS NA Nt./DAY Nt./DAY SCHEDULE CONTACT COOLING F>>TYPE OF HASTEHATER DISCHARGE FLOW RATE WASTEWATER ~Typ SE E.EAtS APPAIIATI>>ti IIATE NA IN>>HRe HR>>DAY IN>>/WK>>~~M~~M~~~0 N HASTBIATER lYPE COKE L~J LJ LJ LJ LJ LJ NONCONTACT G~DISCHARGE SCHZUIE (YEARLY AVERAGE)COOLING PROCESS He DISCHARGE FLCH RATE SANITARY STORMWATER U~NIT GUS HOURS/DAY~24 TOTAL YEARLY DAILY HININII DAILY HAXINN a>>>>PS>>>>~36 157.68 p~2 0.432~2 1 MGY 2 MGD S GPD ITEM 2 WATER TREATMENT ADDITIVES I e THE NXINN DISCHARGE FIDH RATE TO BE AUIHCR IZED IN PERHIT>>Je>>"AXING DESIGN DISCNRGE FIM RATE>>A>>IX)YOU USE HAlER TREATHENT AKDITIVES TO TREAT YON DISCHARGE?(IF NO, CCNTINIE TO ITBI 3)Bi NtNE FIICTIOtt>> At%I CHEHICAL COMPOSITION OF lAESE AKDITIVES>> NA Ce NAME AND ADKRESS OF HAIAFACTIRERS OF lHESE AISLE IT IVES e DESIGN UNITS CODE 1 Mg/I 2 Ug/I NA D.EXPECTED DISCHARGE CCtCENTRATION OF AIKIITIVES ~NA ADDITIVE NA%AKDI TIVE NA%H IN INN UNITS AVERAGE CODE W ITS HAX INtt CODE WITS CODE ADDITIVE NA%E DO YOU TREAT THE DISCHARGE lQ RENIVE ADDITIVES? NA Q YES LJ:~LJ F HHAT IS IHE RENIVAL EFFICIENCY AND DISCHARGE FREOUENCY NA ADDITIVE Nt4%ADDITIVE NAHE ADDITIVE NA%K RENIVAL NS>>/DAY KAYS/WK~LJ Ge AS Att ATTACIPENT TD lHIS APPLICATION PROVIDE SPECIFICÃtNVLIAV CR AOUATIC TOXICOUYilCAL KATA OR REFERBICE HHICH ARE AVAIIAIRE ND INFORHATION ON THE RATE OF DEGRADATION OF THE PRODUCTS FOR EACH ADDITIVE~NA 31 >>VSTr~XTI".'IS E R CCMPL~:IQ SECT:"'I I I ITEM 7'.is fse ls to'e used ov both surfaCe and grcunc~ater aap((cents tc record in!crratlcn on anv Michigan critical material, E.P.A.:rlcri-v ollu.ant~cr nazarcous substance In>>>>nlch tnls app(ication reouires cata to be provided.This vould include any chemical substance from the Michigan Cr Itlcal Materials Register (Table IV), the E.P,A.Priority Pollutant Listing (Table v), or Tables~.A->>z n(cn liatS"rganiC Toxic col~rants..ther axle Pollutants, Conventional and Nonconventional Pollutants and Hazardous ps a",ces,',Tel 7"R!Tl" L uATEPIAIS. op(DR(TV PDLL~F<rITS. ~ID/CR uAZARDNS SL>>BSTAMCES IW THE DISCHARGE"'a-er I s>>I';st the name of the cnemlcal substance (crltlca)material, priority pollutant, or nazardous substance) from Tables IV, V-no IIA-vi as reauirea ln the oox which ycu cnecxeo in A.(-3.above.Enter each cnemlcal substance's parameter number as (lsted in Tables IV, V and IIA-VA It provided.--ovlde trs aierace ccncenrra.icn -..'-e cnemicai supstance rarao:n A.'-c(cate tre semble type used and tne number of ZnalySeS race tO prCVlde the CCnCentratlCn data IOr.he CnemlCal SubStanoe named In A.C.Provide the maximum concentration and determine the mass loading of the chemical substance named In A'>>DTES: l.(t cnlv one analysis vas mace tor a cher>>ical substance then record+hat data as a maximum value.(f more than one analysis nas been made tor a chemical substance then provide an averaoe value of those analyses and the maximum value~Z.,his Section II, Item 7, ata Sl.eet prov(des space fcr recording cata tor 8 chemical subStanceS (Materials). zcsitlcnal space'or t"cr"ing.cata rcr more than 8"arorials c n ce mace by maxing cbies cf this item 7 Data Sheet aS needed.it>>S alSO rpOrtant tO uSe a Separate Set Ot Data Sl.eeta fcr eaon applloable repcrtlng requirement as listed In A.l-3.and for aacn outfall."efer Io The left maroln for the code number representing tne sample type used and the appropriate unit codes.40 SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I PERMIT~MI 0005827 NUMBER NIFALL tltKR As tIAPE OF PRXESS COIIIRIBUTIIIG TO THE DISCHARGE TlROUGH THIS OUTFALL A'Q SIC CODE B PROCESS SCHHXLE (YEARLY AVERAGE)U 2 BLOWID OWIN IDURS/DAY L224I v/v~till ,PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE I/I C/I III OE 0 II D s PROCESS PRODUCTION RATE NA Cs PROCESS WASTEWATER FLOW RATE Basis: 1993 actual data submitted on DMRs TOTAL YEARLY DAILY HlttINtt DAILY HAXII/IN 2 2 QJ i0.234~6 UNI TS/T IPE 1 POUNDS 2 GALLONS 3 CUBIC YARDS 4 TONS 6 MGY 6 MGD 7 GPD!ME 1 HOUR 2 DAY 3 WEEK 4 MONTH 5 YEAR Itt Itt Oust CI K I/I III OMt O 0 A>>ttA%OF PROCESS CONIRIBUTIIG TO THE DISCHARGE TIROUGH THIS OIIFALL AtEI SIC COPE Be PROCESS SCIEIXAE (YEARLY AVERAGE)C.PROCESS WASTEWATER FLOW RATE Ds PROCESS PRODUCTION RATE Ae tIAt%OF PROCESS COIIIRIBUTIt4 TO THE DI SCHULE THOROUGH THIS OUTFALL AttO SIC CODE Bs PROCESS~(YEARLY AVERAGE)Ce PRXESS WASTEWATER FISH RATE D.PROCESS PRODUCTION RATE A.NAHE OF PRXESS CONIRIBUTING TO TIE DISCHARGE NA TH AtID SIC CODE B.PROCESS SCHEDULE (YEARLY AVERAGE)Cs PROCESS WASTGATER FLOW RATE D.PROCESS PRODUCT IOII RATE sssvM/Osv~sEvs/vEM TOTAL YEARLY DAILY MINING DAILY I/AX I PIN Esrs/Er~Esvs/vs@TOTAL YEARLY DAILY HINIPIN DAILY HAXINPI!EEE/ssv~seve/vs!I! TOTAL YEARLY DAILY MININN DAILY HAXltlN WITS STIPE WIT CODE WITS/TINE A.VW%OF PROCESS CONTRIBUTING TO TIE DISOQRGE NA TIROUGH THIS OUTFALL AND SIC CCDE Be PROCESS SCHHXAE (YEARLY AVERAGE)Ce PROCESS WASTEttATER FLCH RATE De PROCESS PRODUCTION RATE TOTAL YEARLY DAILY Hl NltXN DAILY HAXINN vevs/vsM WIT%DE UNITS/TltE 33 INSTRUCTIONS FCP.CCIsPI.ETING SECTICN I I ITEM 3 T~IS farn requireS infarmetlCn On tre OrCCeSS S-reamS WhiCh Cantrlbute TO thiS dlSCnerge. NTEo t" E PEP'4 I T NlPIBER IN THE BOX AT.HE TCP CF TH IS FCRAI THE PEPSI T IeIMBER CAN SE FOUND CN THE FRONT PAGE OF yCUR EXP I R ING<<Rui.If rnis Is e new or i,at previously"emit,ed facility, then leave blank end a number will be assigned.Enter'~~31 I numaer in SOaCe OrOViCed fOr eaCn Oaqe Of SeCtian I I~mar eeCn indiVICual diSCherCe paint e Separate Set Cf Secticn il'orms must oe filled out.ITEM 3 PROCESS STREAMS CCNTRIBLITING TC QISCHARGE: <CR EACH SEPARAT" FPOCESS PROVIDE THE FCLLCNIISI INFCONATICii A, Enter tne here of the prccess which contributes to this discharge. Also orovlde he prcoer SIC code.S.Indicate The yearly average process schedule in hours per day and days-per-year. Provide cne orocess wascewacer fiihv race information as requested based on your last l2 months of operations. Refer to unit code given In the left margin for the appropriate flow units.O.Process Production Rate-Certain pernlt linitatlons mey be based on production rates.The production rates used to determlre oernit linlts shell be reoresented by a reasonable measure of actual production of the facility, such as the production curing the rign ncnth cf the previous year, or the nanthly averace for tne hiahest of the previous five years, or other reasonable measuc e as stated In aoolicabie U.ST E.P.A.categorical rules and regulations .=cr new sources ar new dlschergers, actual raduction shall be estimated using projected oroduc.ian. Reccrd your-.ocuctlcn rates In tne terns ano units used in tne eoolicaole V.S.E.P.A. csteaarical rules and re-ulations for iour tvpe of facility. SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I 74UMBER~MI 0005827~00 8 GROUNDWATER DISCHARGE INFORMATION Ae IS THE DISCHARGE FROM THIS OUTFALL DIRECTED To THE GRONID OR GRSNWATERS?(IF ttOe CCttTlttUE To sTEM 5)Be HAS A HYDROGEOLOGICAL STUDY OR ITS EQUIVALEIIT BEEN PERFORMED OR tS ThERE SIFFICIENT CURRENI'ÃXOGEOLOGICAL thFONATICN AVAILABLE AS REQUIRED BY TIE WATER RESOURCES Cotttlsstott PART 22 GROUNDWATER RULES OF AUIUST ltl4 1980 R~523eZ707 (PAGE Q)FOR THIS EXIST!t7G OR PROPOSED DISCHARGE. IF YES ATTACH A COPY OF TWE REPORT.Ce ARE YCU REQUESTttg AN EXP'PTICN FRI¹t SUBMITTlt4 A HYCROGEOLOG ICAL REPORT l5DER RULE R.323.22F (Q(PAGE t15)OR FRCM GRONGtwATER MONITORING I)EQUJREYSNlS UIIER RULE R.Z5e (>)(PAGE fQ)OF THE PART R RILES>>IF YES ATTACH DOQNEIITS AND EXPlA'VLTION To DEIONSTRATE THAT YOUR DISCHARGE WOULD QUALIFY FCR AN EXPIRE loth De ARE YOU REQUESTING A VARIANCE FRCtt RULE 323.2205 (PAGE 5)(tgNDEGRADATION) Of THE WATER RESIX¹ICES COB%I SS ION PART 22 GRONG5ATER RULEST tF YES ATTACH SUCH DOCI¹'EATS AS h'ECESSARY To DEMONSTRATE THE NEED FOR A VARIANCE Itt TERMS OF THE CRITERIA SPECIFIED IN RIIE 5'DeQ10 (PAGE+OF THE PART 22 RULESe NA NA NA YES lee YES YES ITEM 5 EXPECTED WASTEWATER CHARAC-TERISTICS U COOE 1 Mg/I 2 Ug/I 3 COUNTS/100 ml 4 S.U.5 F 6 LBS/DAY TIE APPLICANT MAY BE REQUIRED'ID Do ADDITICtIAL WASTE ANALYSESe Ae DISCHARGE CHARACTERISTICS COIICENIRAT ION BOD5 (FIVE DAY BIOCtetICAL OXYGEN DEMAIO)'COD (CHEMICAL OXYGEN DEMAND)TOC (TOTAL ORGANIC CARBON)NOT APPLICABLE/BELIEVED ABSENT NA PRESENTS DATA PROVIDED IN ITEM 7 I¹IITS CODE lt ANALYSES~TYPE CODE u1 ul ennta NITROGEN (As N)TOTAL SUSPENDED SOLIDS TOTAL FHQSFHOIIUS (as p)TOTAL RESIDUAL CtiXR!ttE DISSOLVED OXYGEN PH HIM~.LJ~8,~6~LJ u1 u1~u FECAL COLIFORM BACTERIA TEMPERATI¹IE (Su¹4ER)TEtPERATI¹IE (WlttTER)~~u~~u Be OIHER WASTEHaTER CHARACTERISTICS u5 u5 E~I IST ALL CHEIIICAL SISSTANCES WHICH ARE IN MICHIGAN S CRITICAL PATERIALS REGISTER TABLE IV IPAGE D)ANWOR UeSe EPA S PRIORITY Pou UTANT LIST TABLE V (PAGE 7)OR ANY OIIKR SUBSTANCES NltcH ARE 0R HAY BEcot%INJI¹IIQUs To TIE DEB IGNATED UsEs 0F TIE GI(tx¹GIHaTER 0R To THE PUBLIC HEALTH THAT ARE DISCHARGED OR EXPECTED To BE DISCHBRGED To THE GRtX5DWATERAY THIS FACILITY.ESTIMATE THE FINAL EFFLLENT CottCENIRATICN Atto RECORD ALL DATA IN ITEM 7 OF SECI'ION II IN THIS BooleLET.SAMPLE ZYRF 1 GRAB 2 24 HOUR COMPOSITE 0 I L It G R E A S E u u LAJ u u u~u LJ SEE ATTACHED SHEETS FOR ANALYSIS DATA REQUIRED INFORMATION FOR SURFACE WATER DISCHARGES.

• Basis: 1993 actual data submitted on DMRS 35 INSTRUCT ICNS FCR CCIZPLET>taS SECTION I I ITEMS 4 ANO 5 his!orm recuires Information cn a specific ou.aa>I discharging to either the grouncwaters or the su!face>>aters.NTER T,E P RMIT IIPIBER If<THE BOX AT THE TCP CF THIS ORM.THE PERMIT NUMBER CAN BE FOUND ON THE FRONT PAGE OF YOUR EXPIRING" OMITS lf Tn)S IS a ne>>Or nOt DreVIOuSly permitted faClllty, then leaVe blank and a number s<<ill be aSSlcned.Enter-"e umfall number in the soaCe provided for eacn Dade Of SectiOn II.For eacn individual d Ischarce point a separate set Se TI n II!brms (Items 4 anc 5)must be!Illed out.ITEM 4 ROJlO'".ATEP DISCHARGE INFCRuaTIC.'I (OO NOT ll>CLsJDE DEEP'HELL INJECTION INFORMATICN IN THIS ITEVI)A.-O.The aoploCant Shall addreSS eaCh Of theSe carta lf the dlSCharge frcm th>S Outfall IS tO The Orcund>>ater.

ITEM 5 5'<IS I'6 CP E<PECTEO (Fgo A NEN DISCHARGE) NASTENATEa CHaRaCTERISTICS QF GROUIC>HATER CR SURFaCE><ATEo DISCI!ARGE (00.<OT INCLUDE It>>>uws ION Isn Rvas ls!N It<sHla F>>M The applicant shall report available discharge data (real data for existing discharge or expected data for a proposed discharge) for the parameters as listed.These parameters shall be addressed for either a surface water discharge or as appropriate for a grcundwater dlscnarge. For assistance in determining aoproprlate parameters a groundwater dlscnarce applicant may contact the".roundwater Quality 0>vision, Permits Sec.Ion or The approorlate Groundwater Quality Olvlslon's District office.The applicant shall report the sample tvpe code best describing each reported olece of data.See coding on the left margin of Tnls fern.If This outfall is a surface<<ater cischarce. The ecol>cant must report nuantltatlve data for each parameter Identified bv an oot<<-.t.e r,;sa"....e*oa S a re o m se oa a o>>e e~oe*.o..'.o.s aoa a ot sa a t*I-" s.:t t s'es e t s t..si asia If data iS aVal>able fC<Other parameterS nOt I!Sted abOVe In A.Or Cther OarTS Of th(S aopliCatlOn Tre aopliCant Shculd repart That data in the blank spaces provided ln this part.ssOTES: I.Unit COdeS fcr parameterS repcrted In par tS A and B Can be fcund OO the left hand Side Of th>S fOTTn.2.Grab samole shall be used to analyze for pH, tempe<ature, Total ohenols, res(dual chlorine~oil and grease, and fecal coliform in a surface water discharge unless other frequency-sample type analyses are available. See Glossary<page 48)tor definition of grab sample.3.24-hour ccmposlte samples shall be used to analyze for Total 9005, COO, TOC, armenia Nitrogen, and Total Suspended Solids In a Surface water diScharge unless other frecuency-Sample type analyses are aval lab le.See Glossary<page 48)tor definlt'lon of composite sample.REFQRTI'a<<DF >i<TAKE DATA.You are not recuirec to reocrt unless you wish To demonstrate your ellclbl lity for a<<net" effluent limitation fcr one or more pollutants, that Is, an ef fluent limitation adJusted by subtracting the average level of the pollutant(s) present in your intake water.NPOES regulations allow net limitations only in certain c(rcumstances. To cemonstrate your eliclbl llty, report the average of the results of analyses on your intake<<ater (If your wate>>is T.eated before use,.est tne water after It Is treated), anc attach a separate sheet containing the fcllo<<ipo fo!each pollutant: (a)a state ent That t"e intake<<ater's drawn!rcm tr e body of water into wnich the discharge Is mace.(Cthe!<<ise, you are",c e!Iolb le fcr rat limitations,) a state"ent of'".e e<<tent Tc<<nlch the level cf The Dollutant Is reduced bv Treatment of ycur<<astewater.(You!limitations <<Ill be adJusted only To Tne extent that tne pollutant is not removed.)(c)'when aDDllcaole <for example, when the pollutant represents a class of ccmpounds), a demonstration of the exten~to which tne pollutants <n the inta'ke ve!y phvslcally, chemlcallv, or ololo<>icallv fr@-.Tao pollutants Conte nec.-VCur CISCbarre. <<YCur s:mitat(cnS <<:II be ad!uSTed C!Iy-" Tne eXTe~t T>>at The lrtake DOllutantS Co not vary frcm tne dlscnarceo pollutants.) <a vou have t"o or more suosTantlally incentlcal cutfalls, you mhv reauest permission from your Der...lttlng author:Tv c sa-:D!e anc analv e on!v n<cu fall and suan(T<<ne results of ne analvs(s'.cr other substantially cent c I uT~alis,'cu-ec!esT ls ran eo y Tne perm>.~Inc auThol Itv~cn a sepal aTe shee aTTacrec To tl'e Topi>ca>>cn form (centi!y which cutfall you clc test, and cescribe wnv The outfalls wnich vou c(d not test are SuOSTantially IdentlCal TO The Outfall wn<Cn Vcu Old teST. SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I PERMIT NUMSER HI 0005827, PRIORITY POLLUTANTS AND AOOITIONAL INFORMATION FOR SURFACE WATER DISCHARGE ONLY THE FOLLCWING REOUESTED IPJFORYATION c~>s oc ADDRESSED~SURFACE WATER DISCHARGERS. KIIE!JJEW USE DISCHARGERS ~e" PROVIDE EXPECTED VALUES FOR THE OUAMTI TAT IVE AND OVAL I TAT IVE IPJFOJU AT ION REOUESTED BELOW I AI IS THIS FACILIIY A PRIMARY I'JDUSIRY?(REFER TO TABLE IA PAf<4J)(IF tQ, GO TO E)(IF YES, GO TO BI B.IPJDICATE TYPE OF PRIMARY IPJDUSTRY AS LISTED IN TABIE IA PAPJE 491 (CCPJTIMJE WI TH C.)C.DOES THIS OUTFALL DISCHARGE CCPJTAIN Ath'ROCESS WASTEWATER?(IF NO>GO TO E)(IF YES'O TO D)DI ItJDICATE WHICH GC/MS FRACTIOtJS MUST BE TESTED FCR~(REFER TO TABLE IA PAGE 4~I KIIE.FOR EACH GC/MS FRACTION CHECKEDY EACH SPECIFIC ORGANIC TOXIC POU.iffANf 'HITHIN MH FRACTIOti 557 BE APJALYZED FOR (SEE TABLE I IA PAGE 42, IN ADDITIOPJ ALL PRlt"ARY INDUSTRY APPLICANTS WITH A PROCESS WASTEWATER DISCHARGE~PROVIDE OUAMTITATIVE DATA FOR EACH TOXIC POLLUTANT IN TABLE lllA PN4 JI3 a RECORD ALL DATA ON FORMS PROVIDED (ITEM 7)IN THIS BOOKIES'I (CONTINJE WITH E-K BEUJW)X YES JJO ELEC PWR X YES JJO X vJXATILE BASE/NEUTRAL ACID PESTICIDE*E~IF~SURFACE HATER DISCHARGE APPLICANT (PRIMARY OR SECONDUIY INDUSTRY), REGARDLESS OF THE TYPE OF DISCHARGE KPJOWS CR HAS RFASOPI TO BELIEVE TIVE ANY POlLUTAMf LISTED IN TABLE IIA AND IVA PAGES~IS DISCHARGED FRCM ANY OUTFALL'HE OUANTITATIVE DATA~BE PROVIDEDI RECORD ALL DATA OM FORMS PROVIDED (ITEM 7)Iti THIS BOOKLETS PKJT APPLICABLE/BELIEVED ABSENT O X PRESEtif/DATA IS ATTACHED F.IF AVY SURFACE WATER DISCHARGE APPLICANT (PRIMARY OR SECONDARY INDUSTRY)g REGARDLESS OF TYPE OF DIS(595Ep KPJCWS OR HAS REASON TO BELIEVE Attf POLLUfANTS LISTED IN TABLE VA PAGE+ARE DISCHARGED FRJXI ANY OUfFALL THE APPLICJPIT ~P'ESCRIBE REASONS FCR THE POLLUTANT BEING PRESENT APJD PROVIDE AMY AVAILABLE CUJUJTITATIVE DATAI RECORD ALL DATA ON FORMS PROVIDED (ITEM 7)IN THIS BOOKlETo X NOT APPLICABLE/BELIEVED ABSENT PRESEMf/DATA IS ATTACHED G AIL SURFACE WATER DISCHARGE APPLICANTS (PRIMARY AND SECCNKARY INDUSTRIES) WHO:)OR MAPJUFACTIRES Ze Iip 5 TRICPKDJPOPHBJOXY ACETIC ACID (2p 4 5 T)I-(I, JI, 5-TRIOIIORDPk teXY)PRCPAP IC ACID (SILVEX, 2, JI, 5, TP)Ir TTRICPLORCPHBKPL (TCPP J OR HEXACHLOROPHENE (HCP/J (AIL DATA FOR THE ABOVE MUST BE GENERATED USIIJG STAPJDARD APJALYTICAL CALIBRATION PROCBXPIES) OR KNXJS OR HAS REASON TO BELIEVE THAT TCDD IS OR MAY BE PRESENT IN THEIR DISCHARGEa ~REPORT JXIALITATIVE DATJ4 GENERATED WHICH USED A SCREENING PROCGXRE NOT CALIBRATED 'WITH ANALYTICAL STAJJDJIRDS, FOR 2.5z/8r-TETRACHLDRODIBENZO P DIOXIN (TCDD)~RECORD ALL DATA ON FCRMS PROVIDED (ITEM 3)IN THIS BOOKLETe J~IF~QSFACE WATER DISCHARGE APPLICANT KPQIJS OR HAS REASCM TO BELIEVE THAT BIOLOGICAI TOXICITY TESTS WERE VADE IN THE LAST TIFJEE (5)YEARS ON ANY OF THE API'LICAMT S DISCHUJGES OR Oi A RECEIVIP6 WATER IN RELATIOPJ TO A DISCHARGE, PROVIDE TJIS ItifORMATICN AS AV AITACPPJEMT TO THIS APPLICATIOMI X NOT APPLICABLE/BELIEVED ABSENT PRESENT/DATA IS ATTACHED NOT APPLICABLE APPLICABLE/SEE ATTACHED K.IF A CONTRACT IABCRATORY OR CONSULTIPJG FIRM PERFORMED ANY OF THE AVLAYSES RECUIRED BY THIS APPLICATION PROVIDE THE NAME AND AXRESS OF EACH LABORATCRY OR FIRM AMD THE ANIJLYSES PERFORMED AS A'I ATTACPMEMT OF THIS APPLICATIOMI X P JOT APPLICABLE APPLICABLE/SEE ATTACHED LI DO YOU DISCHARGE ANY OTHER TOXIC OR INJURIOUS CHEMICAL SUBSTANCES PJOT LISTED IN TABLES IV PAGE II AP4)I IA TPIPJXJ%VA PN;ES~A, lc vES, THEN IDENTlcY THE CHEMICAL SUBSTANCES AND ESTIMATE THE FINAL EFFLUENT CONCENTRATICPJS ~SQUIT THIS INFCRMAT ION AS AN ATTACPMEMT TO THIS APPLICAT IGNI X mf APPLICABLE APPLICABLE/SEE ATTACHED*Pesticide data is not required;however, it is provided. I'STRCGT!".S =R G""PEEP:/7 SEC-':I i!%Pc I Dc&4!7 o.-.("Bs (~for a'cn C1 s steel!>c cut(all-ischa,"in" tc t,"e surface aters.c=cu!.'4~'BEp!"I nE 20K A~-=..-""F I!IS FC?'~.!E FERSIIT GvitBER 2 g 22=RllO CII 7+E FCOIIT PAGE OF YOCo E>oIRII4"f this is a new or not previous!v erh(ttec fac!I(tv, then leave b!Bnx anc a 1urber wii I be asslcned.e Bete"-"e cv-fa!I"'.macr (1 The space CV.:ec!Cr Bach"ace ot Sect)en','.-~each I"dividual dlscnarce point a se"grate set IT=i!5*ATE t vcu hsvB~'O.mcl e SUPS'tanT la!I incent(cai Cvtfal Is, vou av rB I Bst Permission lcm vcur perm(=inC auTCCri ty TO sample a1d analvze only one cuttal)ahc submit the results c'.he anaivsis for other substantially identical outfalls.if your,ecuest Is granted by-1e perilttlng authority, on a separate sneet at.ached to the application form identify which outfal I you did test, anc dose, ibe wnv the outfal ls wnich you d!c-ot,est are substantial lv Identical to the outfal I<<n(Ch)Pu did TBSP C.snc CO"FR Part I 2.2I(g)(B), Frlcav,-"I,!323, rcvldes'r a imall=.siness=xemoticn'r"-1 the repel t!rg cf-.antltatlve ..ata for organic toxic pollutants anc oxlc pollutants as recuired by"ar l22.21<g)(7)(il)(A) or I22.2((c)(7)(lii)<A). these parts are self-explanatcry anc co not require furtner instructlchs. Slmolv go thrcucn each par,.and"." as indicated. S=everai!nduStrlal CategorieS CC S.csateCCrleS have been BXempTBC'r~S"bml--I"C Cata Cr, Certain GG/VS FwaetlonS0"FR part'!2~yo(.BB, llc.".-', T"'.av,'or!i!,;BBT,'.aTes:,", s".3)..Bvlew t"e fol lcwlno list to ceternlr e whether vcur facility cue!i'ies--pe exe,ot'rcm recon.Inc G"/"S',Gas hrcmatocraohv/"ass Spectroscopy) Fract(ons. M/.'-'S Free.icn.est(no anc Repcrtlrc Exemptions.exti le M!I Is Industry-Al!four X/ISS CrganiC ftaCTIO1S I" xhe Greige"illS SuCCategcry. -Pesticide fraction In all orner su parts of this Industry.Ore a!In!no and Oresslnc Industry-volatile.base/neutral, and"estlc':e fractions in the Base ano preclc s petals subcategory. -All taur GC/!4S Organ(C fraCTICnS I ail Other SuPCateccrieS Of th(S iwCuStrV.Gum and Mood Chemicals Industry-Pesticide fraction in the Tall Oll Rosin Subcategory and the Rosin Based Derivatives Subcategory. -Pesticide and base/neutral fractions in all other subcatecories of this industry.Pulp and Paper Industry Pesticide fraCtiOn in Papergrade Sulfite SubcatecoriBS (Subparts J and U).-Base/neutral and pesticide fractions in oeink suboart Q, oissolvinc Kraft suboart F.and Paperboard from Maste Paper Subpart E.".olat i ice base/neutral, Castle(de r actions ln the BcT Bleacned Kraft suboart u.semI-chem(ca) suboarts 8 and c, and Nonintegrateo-Fine Papers Suboart R.Acid, base/neutral. and pest(cide fractions in Fine Bleached Kraft Suboart i.oissolving Sulfite Pulp Subpart K, Ground-wood Fine Papers Subpart 0, I(arket Bleached Kraft Subpart 0, Tissue from'uastepaper Suboart T, and Nonintegrated Tissue Papers Suboart S.Steam Electric Power Plant Industry-Base/neutral fraction In the once-Through cooling Mater, Fly Ash.and Bottom Ash Transport Mater process wastestreams. 38 SEE INSTRUCTIONS ON REVERSE SIDE SECTION II NUMBER~MI 0005827 (3HFkL IU'R9 USE THIS DATA SHEET 0 RECCRD INFO'"ATION AS REQUIRED ltl: (CHECK APPI(SPRIAT BOX FQR WHICH IIIFOR"ATICN THIS DATA SHEET REP"ESSITS ~'RITICAL'lIATERIALS TOXIC OLLUTANTS SECTI(XI lli ITEN (I-E~GROItlDWATER DISCHARGE I!<FOPA ATIO!t (PAGE 55)X'ECT IQI I le ITC~O.PRICRITY IPOLutTA'<TS IN SIIIFACE WATER DISCH((RGE (PAGE 57)D 3.3~BELQH: cRIilcAL NATERIALs (TABLE Iv)Itl sURFAcE wATst DlscHARGE (PAGE 8)~IZARDOUS USSTANCES IN DISCHARGE 3~LIST A'Y CRITICA'"ATERIAL (TABLE IV Pt<'AE 6)teOT ADDRESSED Itl SECTIQI II ITEYI R KIQRITY A~X UTA'ITS WHICH YOU ICIQ(t OR HAVE REASQI To BELIEVE TO BE PRESBIT IN THE DISCHARGE~SFE REVERSE SIDE OF THIS PAGE FCR FUI(ETHER DIRECTIQ5 e NOT APPLICABLE X APPLICABLE (SEE BELOw)(1(e Ae I!A<<E QF CRITICAL PATER IAL OR PRICRITY POLUJTANT Be AVERAGE CQICENTRATIONI SA<<ZLE TYPE;tT OF e(VIALYSES

• Hydrazine 00 3 0 2 012!PI IT CODE GM'PLE TYPE i7 OF AIAI YSFS Ce.<<AXE CQJCSiiRATION Ale PASS A.'A"E CF CRITIC'L<<ATERIAL OR PRIORITY PO(J.VTATIT WIT CODE IPNT CODE K ((J Ce(B.AVERAGE CQKEIITRATIQI; SA"PLE (YPEP i(OF A!IALYSES C.FAX Itltt CQXBT((AT I Ql A'D t"ASS WIT CCQE~G TYPE OF ANALYSES LJ WIT CODE WIT COBE NITS CODE Mg/I Ug<I/DAY DAY A(P(E TYPE GRAB 24 HR.COMR A,;N;E OF CRITICAL t(ATERIAL CR PRICRITY POL((~T At<T'9.AVERAGE CQCENIRATIOtV SA".PLE TYPES'" CF AtIALYEES Cp I'AXItltt COtlCEtm!ATICtt A'(D i<<ASS A.;u(<<Z OF CRITICAL PATERIAL CR PRIORITY POLLIITAtIT 3.AVERAGE CveiCE,ITPATIQN Se<<"PLE TYPEI (/OF/L,'IALYS S C.<<AXItlPI CQJCBA'RAT IQI A'4)PASS'IA E CF CRITICAL uATERI>>CR-"RIOR ITY PCLLVTAlii 3.AVERAGE CQICSITRATIQI; BAFLE (<PE;"OF A'NLYSES C.<<AXI~PI CQICE.'iTPATICtt"D PASS A.IIA<<E OF CRITICAL NATERIAL CR PGIICRIIY PCILVTA!Ii 3~AVERAGE CQICSITPAT ION!SA<<PLE TYPE;ii C(: A'IALYSES C.<<AXIS'ltt'CQICEIITPATIQI AND i<<ASS le~'!APE CF CRITICAL<<ATERIAL CR P>IQRITY PQLLVTAtIT e AVF4GE CQltCEtt((ATIQlt S'<<PLE TYPE: e: CF A'IALYSES C,<<AXItltt CCICEINPAT IQI AD<<ASS UIIT CODE SA<<PLE TYPE F OF At!ALYSES LJ Wli CODE WIT CODE LJ~~LJ WIT CCDE VVPLE TYPE tt QF AtIALYSES Utlli CODE WIT CCCE LJ~~~LJ WIT CODE SA<<<PLE TYPE=.OF A!IALYSES et<IT CODE WIT CODE QIIT CODE S'PLE IYPE v'F ANALYSES QIIT CODE WIT COCE LJ J;IT CCQE SA(PLE i<PE<<QF At<ALYSES LJ WIT CODE Wli CODE A:IA<<E QF CRITICAL l<<ATERIAL CR""RIORITY POLL(JTP(tti Be AVEPACm COAICDANRATION; SA<<EGLE (YPE;tI OF AtlALYSES C~<<AXIS'It<CUE'Pi&TIQI AY<<)X(ASS WIT CODE SA<<PLE TYPE RT OF A'IALYSES QNT CODE WIT CCOE LJ'~~LJ~~~Ll ADDITIONAL PAGES CF THIS Ii I 7 ARE ATTACHED FOR T((ReST CF THE CRITICAL 6 YES<<ATERIALS At<D/OR PRICRITY KAL(JTA%'S REQUIRED TO BE REPORTED(EI a*Hydrazine is expected to be present in discharge but small quantities may be found in the steam generators but would not be expected to found in the actual discharge flow to Outfalls 001 or 002.

'ENERAL CHEIVIISTRY RESULTS Client Sample ID: OUTFALL OOS-U/2 SLOWDOWN LAL Batch ID(s): 126 im, 128 im.201 im Date Collected: 01-31-94 Matrix: water Date Received: 02-01-94 PO¹69095-040-3N Constltuent -'ethod-'esult'-.,;,"Rep'ortlng;:,.- 'Data-Detection Umit Qualifier(s) 'Date-Anal zed LAL Sam le ID Fluoride, inm IL Bromide.in m IL Nitrite-Nitrate-Nitrogen, inm IL Sulfate in m IL Total C snide, in m IL Color\Total Phenolics. in m IL Sulfide in m IL Sulfite, inm IL 340.2 300.0 353.2 300.0 335.2 110.3 420.1 376.1 377.1<0.15<0.050<0.050 0.12<0.020<5.0<0.15<1.0 1.2 0.15 0.050 0.050 0.059 0.020 5.0 0.15 1.0 1.0 03-02-94 L1175-1 02-17-94 L1175-4 02-11-94 L1175-5 03-05-94 L11 75-4 02-07-94 L1175-6 02-01-94 L1 175-1 02-08-94 L1 175-7 02-03-94 L1175-1 02-01-94 L11 75-2 Comments:

IVIETALS RESULTS Client Sample ID: OUTFALL OOB-U/2 BLOWDOWN LAL Batch ID(s): 126 im Date Collected: 01-31-94 Date Received: 02-01-94 Matrix: water PO469096-040-3N Constltuenta Aluminum Antimon Arsenic Barium Ber ilium Boron Cadmium Chromium Cobalt Co er Iron Lead Ma nesium Man anese Mercur Mol bdenum Nickel Phos horus Selenium Silver Strontium Thallium Tin Titanium Uranium Vanadium Zinc Method 6010 6010 7060 6010 6010 6010 6010 6010 6010 6010 6010 7421 6010 6010 7470 6010 6010 6010 7740 6010'010 7841 6010 6010 6020 6010 6010 Concentration lm IL)<0.20<0.060<0.010<0.20<0.005<0.20<0.005<0.010<0.050<0.025 0.15<0.003<5.0<0.015<0.0002<0.067<0.040<0.050<0.005<0.010<0.10<0.010<0.20<0.10<0.001<0.050<0.020 Reporting Detection Limit Im IL)0.20 0.060 0.010 0.20 0.005 0.20 0.005 0.010 0.050 0.025 0.10 0.003 5.0 0.015 0.0002 0.067 0.040 0.050 0.005 0.010 0.10 0.010 0.20 0.10 0.001 0.050 0.020 Data~Qualifier(a) Date'nal@ed 02-22-94 02-22-94 02-20-94 02-22-94 02-22-94 02-22-94 02-22-94 02-22-94 02-22-94 02-22-94 02-22-94 02-23-94 02-22-94 02-22-94 02-09-94 02-22-94 02-22-94 02-22-94 02-25-94 02-22-94 02-22-94 02-28-94 02-22-94 02-22-94 03-07-94 02-22-94 02-22-94 LAL Sam Ie ID L1 175-17 L11 75-17 L1175-17 L1 175-17 L1175-17 L1175.17 L1 175-17 L1 175-17 L1175-17 L1175-17 L1 175-17 L1 175-17 L1175-17 L1 1 75.1 7 L1 1 75-17 L1 175-17 L1 175-17 L1175-17 L1 175-17 L1 175-17 L1 175-17 L1175-17 L1 175-17 L1175-17 L1175-17 L11 75-17 L1175-17 Comments: VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 1 of 2 lien m I ID: TFALL B-BL WD WN Date Collected: 31-JAN-94 Matrix: WATER Ani i IB h¹: 244-2-1 QC Batch ID: 020494-8260-C1 LAL m I ID: 117-2 Date Received: 01-FEB-94 Date Anal zed: 04-FEB-94 Dil inF r: 1 SURROGATE RECOVERY 1 2-Di r h-4 Tl n-4-Bromofluorobenzene 1 4 106 QC Limits 7-114 86-115 Constituent Chloromethane Vin I hl ri Brmm hn Chloroethane Trichlorofluoro meth ane A e n 11-Di hl r h Carbon Disulfide Meth lene Chloride rn-12-Dihlr hn Vin I A 1 1-Dichloroethane 2-Butanone i-1 2-Di hl r h n hlrfrm 1 1 1-Trichloroethane Carbon Tetrachloride 12-Dihl r h B nz n Trichloroethene TCE 1 2-Dichioro ro an Brm ihlrm hn 2-hl r h I Vin I E h r 4-Meth l-2-entanone cis-1 3-Dichloro ro ene T I n rn-1-Dihl r r n 2-Hexanone 1 1 2-Trichloroethane Tetrachloroethene PCE Concentration IL<5<5<5<5<5<10<5<5<5<5<2<10<5<10<5 Reporting Detection Limit IL 10 10 10 Data Qualifier s LOCKHEED AiVALYTICAL SERVICES VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 2 of 2 Client Sam Ie ID: OUTFALL OOB-U/2 BLOWDOWN LAL Sam fe ID: L1175-20 n I n Dirm hlrm hn Chlorobenzene Eth Ibenzene m-Xln-X I n St rene Bromoform 1122-T r hl r h n 1-Dihlr zn 1 4-Dichlorobenzene 1 2-Dichlorobenzene Concentration L<5<5<5<5<5<5 Reporting Detection Limit IL D alifi r s LOCKHEED AIVALYTICAL SERVICES VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 TENTATIVELY IDENTIFIED COMPOUNDS Client Sample ID: OUTFALL OOB-U/2 BLOWDOWN Date Collected: 314AN-94 Date Received: 01-FEB-94 Matrix: WATER Analytical Batch: 020494-8260-C1 QC Batch ID: 020494-8260-C1 LAL Sample ID: L1175-20 Date Analyzed: 04-FEB-94 Dilution Factor: 1 Sample Weight: N/A No.of TICs: 0 Tentatively Identified Compound Estimated Concentration (yg/L)Retention Time (minutes)Data Qualifier(s) LOCKHEED ANALYTICAL SERVICES SEIVIIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/IVIS ANALYSES USING METHOD 8270 Pa el of2 li n m I ID: TFALL 8-U 2 BL WD WN D II: 1-AN-4.Matrix: WATER Anal tical Batch¹: 021094-8270-A QC Batch ID: 8270-SVOA-4903 LAL m I ID: L117-D R iv: 1-FEB-4 Dilution Factor: 1 Date Extracted: 03-FEB-94 Date Anal zed: 10-FEB-94 SURROGATE RECOVERY o 0 Limi 2-Fl oro h n I Phenol*de Nitrobenzene-d, 2-Fluorobi hen I 2 4 6-Tribromo henol p-Terphenyl-d,i 22 70 67 60 41 21-1 10-94 35-114 43-116 1 0-1 23 33-141 Phn I Con Concentration L Reporting Detection Limit L D bis 2-Chloroeth I ether 2-Chloro henol 1-Dihl r n n 14Di I r n n Benz I alcohol 1 2-Dichlorobenzene 2-M hlhnl i 2-hlri r I hr 4-Meth I henol N-Nitroso-Di-n-ro lamine H hlr h Nir n n Iso horone 2-Nitro henol'-Dim h I h Bnzi i bis 2-Chloroetho me hane 2 4-Dichloro henol 1 4-Trihl r n n N hhl 4-Chloroaniline Hexachlorobutadiene 4-hlr--m hlhnl-M h In hh I n Hexachloroc clo entadiene<10<10<10<10<10<10<10<10<10<10<10<10<10 10 10 10 10 10 10 10 10 10 10 10 10 10 LOCKHEED ANALYTICAL SERVICES SEMIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Client Sam le)D: OUTFALL OOB-U/2 BLOWDOWN LAL Sam le ID: L1 1 75-9 P 2of2 Constituent 4-Trihl r h n I 2 4 5-Tri hl ro henol 2-Chlorona hthalene 2-Nitroaniline Dim h I hh I A n hhln 2 6-Dinitrotoluene 3-Nitroaniline A n hhn 4-Dini r h n I 4-Nitro henol Dibenzofuran 4-Dini r I Di h I hh I 4-Chloro hen I-hen Ie her Fluo rene 4-Ni r nilin 4-Dinir--m h I h n I N-Nitrosodi hen lamine 4-Bromo hen I-hen le her Hx hlr nzn Pn hir hnl Phenanthrene Anthracene Concentration (/L)<10<10<25<10<25<25<10<10<10<10<10<10<10 Reporting Detection Limit (/L)10 25 10 25 25 10 10 10 10 10 10 10 Data Qualifier(s) Di-n-I hh I Fluoran hene P rene B I z I h I'-Di hl Benzo a anthracene Chr sene i 2-Eh Ih Di-n-I h Benzo b fluoranthene Benzo k flu ranthene B n r<10<10<10<10<10<10 10 10 10 10 10 10 In n 2 r n Dibenz a h anthracene Benzo h i er lane<10<10 10 10 LOCKHEED ANALYTICAL SERVICES

SEMI-VOLATILE ORGANIC ANALYSIS RESULTS C~FOR ANALYSES USING IVIETHOD 8270 TENTATIVELY IDENTIFIED COIVIPOUNDS Client Sample ID: OUTFALL 00B-U/2 BLOWDOWN LAL Sample ID: L1175-9 Date Received: 01-FEB-94 Matrix: WATER Analytical Batch: 021094-8270-A Date Analyzed: 10-FEB-94 Dilution Factor: 1 QC Batch ID: 8270-SVOAP903 Tentatively Identified Compound Substituted Hexanedoic Acid Estimated Concentration Iyg/L)270 Retention Time (minutes)30.3 Data Qualifier{a) LOCKHEED ANALYTICAL SERVICES OIL AND GREASE EXTRACTABLES ANALYSIS RESULTS BY FT/IR USING METHOD 413.2 Client Sam le ID: OUTFALL OOB-U 2 BLOWDOWN LAL Sam le ID: L1175-13 Date Collected: 31-JAN-94 D R iv: 1-F B-4 M rix: WATER Anal tical Batch¹: 020994-413.2 Date Anal zed: 09-FEB-94 Dil inF r 1 D Ex r:-FEB-4 QC Batch ID: 020894-413.2 Constituent Oil and Grease Concentration m L Reporting Detection Limit m L Data Qualifier(s) LOCKHEED AItIALYTICAL SERVICES PESTICIDE.ANALYSES RESULTS BY GC/ECD USING METHOD 8080 Clien Sam le ID: UTFALL 0 B-U 2 BLOWDOWN Da C Ile ed: 31-JAN-94 Date Extracted: 07-JAN-94 Matrix: WATER Analytical Batch¹: 021294-8080-E-3 LAL S m I ID: L117-11 D R eiv: 1-FEB 94 Date Anal zed: 14-FEB-94 Dilution Factor: 1 QC Group ID: 8080 PEST/PCB 5054 SURROGATE RE OVERY 00 QC Limits TCIVIX DCB 64 86 60-150 60-150 A-BH B-BHC G-BHC Constituent Concentration L<0.05<0.05 Reporting Detection Limit L 0.05 0.05 Data Qualifierls) D-BHC HEPTA HL R ALDRIN HEPTACHLOR EPOXIDE HL R DANE END LFAN I A-CHLORDANE 4 4'-DDE 4 4'-DDT DIELDRIN ENDRIN ENDOSULFAN II 4 4'-DDD ENDRIN ALDEHYDE ENDOSULFAN SULFATE'ETHOXYCHLOR T XAP HEN PCB-1016 PCB-1221 PCB-1232 P B-124 P B-124 PCB-1254 PCB-1260 TECHNICAL CHLORDANE TCMX-tetra-chloro-meta-xylene DCB-Deca-chloro-biphenyl <0.05<0.05<0.05<0.1<0.1<0.1<0.1<0.5<2 0.05 0.05.05 0.05 0.1 0.1 0.1 0.1 0.5 LOCKHEED ANALYTICAL SERVICES

RAD DATA REPORT (ra01)indiana Michigan Powr Co.~Bridgman,HI Organic and inorganic Contaninants (Project COOK.JEMl) Client Sample iO: OUTFALL OOB-U/2 BLOSSOM LAL Senile 10: L1175-15 Katrixt Mater Date Collected: 31-JAM-94 Date Received: 01-FEB-94 Log in Mwhert L1175 Gross Alpha Gross Beta 23-FEB-94 GR ALP/BETA LAL-0060 4756 23.FEB-94 GR ALP/BETA LAL.0060 4756-0.08 0.3B 0.92 0.4 1.2 2.1 pCi/L pCi/L Page 2 RAD DATA REPORT (ra01)Indiana Hichigan Power Co.*Bridgman,HI Organic and Inorganic Contamlnants (Project COOK-JENI) Hatrix: Water Client Sample ID: OUTFALL DDB-U/2 BLOW Date Collected: 31-JAN-94 LAL Sea@le ID: L1175-16 Date Received: 01-FEB-94 Log in Number: L1175~~%'i:";":'(Cari s tg't'tigj't:i.".':::::W"':N:::::.:AWII5ity'iel:; 'Igitgb;::::::::."'~ Ra-226 Ra-228 10.HAR-94 RA-226 LAL-0073 5201 25-FEB-94 RA-228 LAL-0074 5199 0.62 0.03 0.28 0.37 0.31 0.65 pC i/L pCi/L Page 3 PH Meter CPC y-lO~Cal date due Sample Sample Time Sample/j Sample Date CDM Entered by Outfall OOB g I C, J4 0 o o PH Analysis (LAB.079)5.3.5 6)Sample C/ph (prior to correction) 7)NH3 pH correction 7 7P 5.3.6 8))ample results C/pH (after t.7g NH Correction) 3 Sample Sample Time Sample g Sample Date CDM Entered by 5.3.5 6)Sample C/ph (prior to correction) 7)NH3 pH correction 5.3.6 8)Sample results'C/pH (after Correction) 9)LAB.041 Specs Verified by: A(/8 Rupewvieoz Review/Date ~W+IW Form prepared by/Date Form approved by/Date 12 THP LAB.041.25s Revision 1 Sample/Standard Sample jj Date Time CDM Entered by Outfall OOB I Sg-7Determination of Total Chlorine (Lab 170)~~/q~/instrument CPC/j Technician h l)Absorbance 6.11 2)Results, ppm 3)Dilutions made C.~C2M CZ M 4)Results, ppm (/I2*0 3)C 51 1AB.Ddl Specs Verified by:~N R Supervisor Review/Date~~9I ~Form prepared by/Date/~fŽForm approved by/Date 12 THP LAB.041-25)l Revision 0 SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I NUMBER PERMIT~i4I 0005827 (UIFkL rkPKR~00 0.M DISCHARGE LOCATION Ae~QCAT ION OF DISCHARGE B~MME cF REcEIYIttG HATER'{IEs GRQ{ttDHATER 0R NA'K 0F sutFAcE<<A Ce DO YCU DISCHARGE SEASQliALLY: {IF NO)CQVTltAIE TO E)MECH)IG AN YES ta D, IF YES)LIST DISCHARGE PERIODS NA MOe/DAY./DAY~6 e,~NW e,~e-DII0I I~06,-0)l L006I e)IDE~19)I SCHEDULE FLOW RATE WASTEWATER CONTACT COOLING: NONCONTACT COOLING PROCESS SANITARY STORMWATER U~NIT 0 D I MGY 2 MGD 3 GPD ITEM Es LAtrD APPLI CAT ION RATE Fe TYPE QF WASTEWATER DISCHARGE G~DISCHARGE~(YEARLY AVERAGE)Irt./HR.HRe/DAY IN,/WK, ELJ~H~~w KI IIA wASTEIIATER TYPE COCE.LJ HQ{Frs/DAY ~24 Dsv/Tees L5365 I He 0 ISCM6RGE FLOW RATE TOTAL YEARLY**Based on all-time daily maximum times DAILYMIttIPut 365 DAILY t'AXltttt 5.11)0 0.014 UNIT CODE L4~2~2 Js MAXIISH DESIGV DISCHARGE FLOW RATE, As CO YOU USE WATER TREATMENT ADDITIVES TO TREAT YQ{R DISCHARGE?(IF tro cQNTItt{E To ITEM 3)Be NAME FgtCTIQrte AND CHEMICAL~S IT ION OF TIIESE ACOITlVEST DES IG'I 0 YES 0.043~P I e IHE t)AXIts{M DISCHARGE flOW RATE TO BE AUIHQR IZED Itt PERIITT p p 4 3 UN I TRODE WATER TREATMENT ADDITIVES Ce NA%ArtD ADDRESS OF MAIAFACTLT)ERS QF lHESE ADDITIVES~NA UNITS CODE 1 Mg/I 2 Ugzl De XPECTED DISCHARGE CCttCENIRATIQrt OF AITIITIVESs ADDITIVE NAME NA NA MI NIM{f1 UNI TS AVERAGE ut ITS MAX It%tt UNITS CODE CODE CODE ACDITIVE tQ%ADDITIVE t5%E, DO Yet TREAT THE DISCHARGE)s REMOVE ADDITIVES? NA LJ LJ:~LJ:~LJ YES F.WHA'T IS THE RP9OVAL EFFICIENCY AVD DISCHARGE FREQUENCY? NA ADDITIVE tA%ADDITIVE NAME ADDITIVE N6ME~REPCVAL MRS e/DAY DAYS/WK~LJ G, AS Art ATTACHTENT TO THIS APPLICATIQtt PROVIDE SPECIFIC."Ast)ALIAS CR AQUATIC TOXICOLOGICAL DATA CR REFERBICE WMICH ARE AVAILABLE AND INFORMATICN CN THE RATE OF DEGRADATION OF THE PRODUCTS FCR EACH All!TIVE NA

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JI~I)I acr I)I 4<<C l I I~<<5 h}+ns<<A<<5 At~5'I J~I h<<avs'Jt~-"<<}5---"--'" 4'ac-4-.>><<r}-es<<s 4-es-ea=e'et-I"it"0"e"fvon i<<-4.eft<<eraln f , 0)r}Te I<<Jnl sI')f'e}r: vrhr--'l:ttn eel~1s cer"ny.F-.hflc"s-er"}v.)'4 q 5 at e h 4>>~l nevo 0'5<<ftl 4<<9I-"e'se:~Svc1)'IC>>rate<<t if"".-'}Ce an ectJ}l',it"estrlctlcn cn tne flew but will'I AI ent!'titS.}Isa,*1en-ne'Cntf IV Ceretlca}5 CrtS}re reuieweC=;ramollanae StaffffnV new Cr'<<tro<<Sea uSeS miant"eVe}>>Cur rea f)t--5 I}CllltV.be Tne flew rate usea to aevelac lt will"eia Tr~-0 Cetermine-""fiaa"4'53'-II I-etf'"-)I I I'.4 fa"<<TC-"Ael ont 3 5 At'I->>ef)tea o<<4 sfstotl f I w, 5 ta}1et f fhl Te,.at}Trent 5 Istem ITEV 2}RTE TCERTIJEfIT r DITISEE 4 4~r 4'4 I I l 5"fa 1<<to~~;.CTIC.)nt tbemiC}f: 03I." 0 50~I"AS ISeC~4 e~r h CIh 3~~4<<10 lr 4 I" hf 5 h~f'ls IJset~'I~~~,II I))Vef h 4 h II" I 5'I 5" Cah 1$fl PI 5S~IS 5(4 J.,<<r=h)a')0';A h)I'ol)~',}f'<<gs A<<e}4>>, a-e"4"h""V}f 4'IC 5<<CV-~'J<<I 5 l<<e AI AI<<)I 4 I 4<<esto<<<<tot I h I 5\h r<<IIJAI (0 f 6~I'4 I'I14 hs rec'eSTea l I" 5 grl.'ar metlan)$1 1T-}el!0}V Asu,%.I}CI I 0 I 0 rh r>>e ne}<<l hnt Jtf~)2 SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I PERMIT~MT.0005827 NUMBER[IJII'M.Ilf BEI(OF PDOCESS OC)ITRIBUTI[JG TQ THE DISCHARGE rROU%TYIIS QUTFAU-~'D SIC CCCE 40~0>0 DAN N~4i9 I I B=ROCESS SA-ED[LE (YEARLY AYRE)IOUS/DAY~24 I"Avs/v e PROCESS STREAMS ONTRIBUTING 'O OUTFALL DISCHARGE VI V9 Or 0 0 C~=ROCESS WASTEYIATER FLOW RATE Basis: 1993 actual data submitted on DMRs De PROCESS F0')CT ION RATE TOTAL YEARLY DAlLY M IN INN DAILY e<<AXINTI 0.003~*I I 0,~6 0.002~6*ut ITS/T IME I I I I I I I POUNDS 2 GALLONS 3 CUBIC YARDS 4 TONS 5 MGY 6 MGO 7 GPD VI VI 001 0 VI CC 4L A.iVVZ OF PDQCESS CONTRIBUTING TO THE DISCHARGE DSQUGH Tri[S OUTFALL~YT)SIC C<<E B.PROCESS~(YEARLY AVERAGE)Ce PROCESS>IASTEWATER FLOW RATE D PROCESS FPODUCTIOtt RATE A.:VINE OF PRXESS COtt[RIBUT[t)G TO THE DISCHARGE TH[OUGH THIS OUTFALL A'ID SIC CCCE Be PROCESS SO'X)LE (YEARLY AVERAGE)C.PROCESS lQSTEYIATER FU)W RATE De PROCESS PPODUCTIOtt RATE IYADS/IDY~DAYS/YSAII TOTAI.YEARLY DAILY Mttl[NH DAILY NAX INN HADS/DAY~DAYS/VSAA TOTAL YEARLY DAILY MININH DAILY PAXINTI UN[TS/TIME I HOUR 2 OAY 3 WEEK MONTH 5 YEAR Vl VI Lt~Q Q.Ae NAWIE OF PROCESS COIITRIBUT[tlG TO THE DISCHARGE TH At&SIC COPE B PROCESS SC~DE (YEARLY AVERAGE)Ce PROCESS WASTEWATER FLOW RATE~'DAV~DAVS/VSAA TOTAL YEARLY DAILY MININTI Lt[IT CODE D.PROCESS PDQCUCTIQII RATE Ae IW%OF PPQCESS CQt[IRIBUT[NG TO THE DISCHARGE Ng IlFAOUGH THIS OUTFALL AlID SIC CQCE B.PROCESS SOIEDRE (YEARLY AVGAS/iE)C.PROCESS WASTEIIATER FLOW RATE De PROCESS PRODUCT IOtt RATE DAILY 4'AX[t~IIQURS/DAY TOTAL YEARLY DA t LY;I[NINA DAILY WXINM UtttTS/TIPE I I I DAIS/YDYI UNIT wX~I I UNITS/TIPE*Heating boiler was out of service for maintenance during most of 1993.33 a/<<<<Re'a lar 9 9" SSS I>5*n!C" r 8'I-,.=gy.-.-=-~="==i"-.=:=..==n=.-.!It',.c-"=-.-'l=c=tI.';0:;I HE F;"CRIT PtGE-".vCN C>PI!III'G '"Is'!.-Rw cr ot-ov.st.3 rnl--~c'scil tv,-Rn'eave Isn~a c a nu>><<ce*ill"0 assianec.cl~e 5 ace, vlcec Rs 5 9 ot Pc tcl I oa t I ual c 3.ce c ln 5o elate sor'--5-5--O':IieC>>u-Ir 5 5~~~<<~" p Y(>>--9--9-e process<<n'C.Cc--"'c.-es "-i!s:Iscrs-co. -':-rcvl:e-9 c-."Rr-.'.ccce-clca-0"9 F45.I.Cyersce crace!3 ic-45<<io'--ours cor csv R<<c ccvs-:er-voa" aroviae t"e process<<aste~ater f!ou rate Infornation as recuesteo baseo on your last 12..ontns of operations. Refer to nit COae oiven in tee loft naroin for tne acprOoriate flow units~.=ocess proauctlor. Rate-certain cer"i;ti>>ltations nav ce casea cn crccuctlcn rates."9 crcauctlcn ra~Os usea o 39;Or Ir+CO>>>>',-'>ICS 5nai I CR>>R<<>>>SR--~C CV 3 rROScnaCle RaSure C'eveal C"CauCC'C<< Cf t"e IOCi ll V.5'Cn CS"e'"n-"-"-~"~"-3 oar"-o-"--"'~-->>"-"---9-'-"os--'"~--etic"s" 9"ears cr:--Rr-Rsscnac.o -9)sure as s->>oc scc.': cle..=.-".a.R.-e:cr'I'os a~c 9 cta 3."4<<S'r<<RS"r<<4>>I SCnar<<>>53~"'5 aI I 95 4<<0)<<a\~~.<<'OC 9>><<O5 g 5\\~!5 4\h*~9 ri 3$!95 h]9 1,)3 i>>f 5 f SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I NUMBER PERMIT MZ 0005827>>BENI 4 GROUNDWATER ,DISCHARGE INFORMATION QJIFAU.NKR Ae IS IHE DISCHARG(FROM THIS CUTFALL 3$REC1ED TO THe GRONO OR GRoutGWATERS7 4IF t>>O<<Ca>>TIMUE To IT&>>u)B.WAS A HYDRQGEOLQGICAL STUDY OR ITS EQUIVALB>>T BEEN PERFORMED OR IS IHERE SIFFICIEMT CURRENT HYDROGEOLOGICAL It<<FOIT>>ATIa>> AVAIIJ<<BLE AS REQUIRED BY~WATER RESOURCES cat>>tssla>> PART 22 GR>>xl>>owATER RULES cF AUGUsT lt>>e 1%0 R~525 2D)7 (PAGE Q)F0R IHIS EXISTlt>>S OR PROPOSED DISCHARGE! IF YES ATTACH A COPY CF IHE REPORT.C ARE YQU REQUESTIttl Att EXP'PTICN FRCM SUBMITTIt>>G A HYDROGEOLOGICAL REPORT ut>>QER R>>AE R.323<<22(I7 Q (PAGE$A)OR FRCM GR>>Xl>>DWATER MONIICRIt>>G I)EQU1REMB>>TS CiDER RULE RR~23e (5)(PAGE Lg)OF THE PART 22 R>>LESe IF'ES ATTACH DQC>>l>>ENTS M)EXPIANATla>> To DB)ot>>STRAIE THAT YOUR DISCHARGE Wa)LD QUALIFY FOR EXBP lONe De ARE You REQUEsTIt6 4 vARtAt>>cE FRcM RULE 323.2$)05 (PAGE 5)(NQNDEGRADATIQN) QF IHE wATER REsouRcEs cotHIsslcN PART 22 GRout>>DHAIER RuLEs!IF YEs, ATTAcH sucH DOC>>1'Et>>TS AS NECESSARY TO DEM(INSTRAIE THE NEED FOR A VARIAI>>CE IN TEFMS OF Tte CRITERIA SPECIFIED IN RIAL 525 Z10 (PAGE>>I>>t)CF THE PART Zd RULEse NA~00 C YES CI':<<$'le t>>O$>>e<<Ee I,IST AI,L CHEMICAL SLBSTANCES WHICH ARE IN MICHIGAN'S CRITICAL<<MATERIALS REGISTER TABLE IV'>>PAGE D)At>>D/cR U.s.EPA s PRI0RITY PQU.UTANT Llsf TABLE v (PAGE 1)0R ANY 0THER SUBSTANcES WHICH ARE OR MAY BECCt%IIL>>URIa)s TO THE DESIGNTED USES OF THE GSXl>>DIETER OR TO THE PUBLIC H~TH THAT ARE DISCHARGED OR EXPECTED TO BE DISCHARGED To THE GRCu>>DWATER>Y IHIS FACILITY.ESTIMATE IHE F ttujL EFFWEMT CONCB>>IRATION At>>D RECORD ALL DATA IN tTEM/OF SECTION it IN THIS BOO)LET~THE APPLIGWT MAY BE REQUIRED TO DO ADDITICt>>AL WASTE ANALYSES.NOT APPLICABLE/BELIEVED ABSB>>T NA PRESENT<>DEMAt>>D)TOC (TOTAL ORGA<<M IC CARBa>>)AftSMIA NIIROGEM (AS N)TOTAL SUSPENDED SOLIDS ToTAL ptcspHQRus (As p)TOTAL RESIDUAL CH.CRINE DISSOLVED OXYGEN PH Mlt>>FECAL COLIFORM RACTERtA IEMPERAIURE (S>>ll4ER)TEMPERATURE (WINIER)BOD5 (FtVE DAY BIOCHEHICAL OXYGEtt DP'At>>D)Cot>>CEMIRAT I a>>~~LJ~~LJ~~LJ ll>>ITS CODE$$>>At>>ALYSES~LE TYPE CODE~3~5~5 B.OIHER WASTEWATER Ct>>ARACIER 1ST ICS SAMPLE ZXBF 1 GRAB 2 24 HOUR COMPOSITE 0 I L)t, G R E A S E LJ I LJ LJ LJ~LJ LJ LJ LJ~SEE ATTACHED SHEETS FOR ANALYSIS D TA e<<>>ECUIRED ItSORMATIa>> FOR SURFACE WATER DISCHARGESe

• Basis: 1993 actual data submitted on DMRS

~5.,v~4 S g<<>>P Pi Ii(4 lh}i rt=(S 3",n g is C o)vires'" o.!~c<<.".'!3)ac'(-cu (4'I'cbarci c" at ther'prof.nc}(ate, 5 cr=E<<izI7'.""BEC Ih THE BOX AT I'o}EP CF T}}IS r CR!I.>E PE&IT'."J'ABER"A}l BE, DUI(0 O'I THE'".is~S)-e<<)hot b-OVicuslv cer,It!ed'<<oil}tv,!he<<leave CI)nk ano a rr."<<ber<<il(s r')ce<<arers.t F-Ct(T PAGE CF v00R ExoIRii<<4 be ass tered.a-4 5()I.<<)or'4 3))CO Zr)v: C<<C (C<<e)c<<!)ce 'eo:,on}I=c<<>>cn I"dividual!Isc)rco octn.a!eon}nto 5(}-'crrs'I e.s-)r c."-.st ce.I I!Iec cut.I'o~i~gi\~i i i~<<g 7 ii'I~i~~I chf~~'i IC}i)i'"e)ool:cant shall!Cdross o)c"ese carts I'e ctscharce!A;-"Is out'nrl'5-=tbe:-curcwator. Evi 5 I".(c-EVPEcTED;FcP 'E(r IscHARBF)a)STE'r}ATEP cuARAcTEc'sT)cs 0"0'.0'4'ATEo cP 40RFAcc'((ATEC Btsci ARriE (0 i0T It)I.UDE A.The aoolicant shall re)ort avnllab(e discharge cata (real cata for existinc discharge or exoected data for a brooosec discharge) !cr r}e barn.eters as 1}sted.ihese onraceters shat I be ccresseo for either a surface water discr.arne or as nooroor late rcr!-,rcurchater C'sonar"e,-cr aSSIstnnco '" cater(,lnirc aoorcoriate ara"e-arS a crourC}rater CISCnarce abblicnnt.av contact-"e'c<<ater Cunt I, v'., 3 ten, oe<<Its Secticn or tne a)ore)r:ate:rcu<<exeter.unl 1"', (I sion'5 Ci 5, rlct o.f.'co i I iC)rl~5!I t 1 1'e 5)ala'("e C O Ost asCr')inr(q)c<<<<OOCr e OCO Cntn, Sae i, (I Crr t e tert af'CI<<$f'I rl r";!)Ct'nl}}5!I.rface<<ato":i!eh)rte. "-e!"<<}Ic)"-:5-rhc r".anr'-)tl.e Sa.a fcr encn))rareter iden!If ted bv a<<)s<<er!w.",e)oo}5)".av~..*over, nc os;-"nt-"e.o-r->>,-c)t<<)r'e cr cre o, nese recu}r'Oc oarvetors oe<<a}vec..uc;, e).ost-;st be 3~boor-ec b()cecunte)t'5"aie.~!Re S.c)rocuest)<<!7 achrhont-".this)Col icntlcn.))-a: s)(n'}acre'>>t"er c)r~~to<<5-Ot 1'5-OC)oo.e'-A.Z 5<<.er)),-5)'"'S)coilcatlcn -"e aoolicant 5<<auld re cr that zat)In tre<<iinn<<scaCeS Orcviced:<<rniS Cart.'TES,;"I-codes'oars.oters reocr tac ln oor ts A)rd B can bo for.rc cn the ie't nano sice cf tais fcf<<h sn O}a$>)I I"e used-".)CalVZO'Cr O"~te4)era-urn, tc-)I t"e"Cr 5~~es lcual C",.IC~ine, Oi I)nd 1:reaae~and'4)}<<', I)4 r)Ze<<ate,.is)r Ce ess t" Or ("4 werc.5).'4.Voe)noiVSOS a, e avni I ale~See" Ssaf V (once 4B)'c eel ir I-ion of,rao san)le.3.Ez-hou, c" ooslte sar}ales snail be used to ann}vze fcr T>tat 9&4, 000~.cc,,~onia '.Itrogon, nnd Total susoenced Solids Ir Surface<<ater Clscnbrro unless other;recueoCV-Sn ole tvpe analvses are avnllable. See Glossary ()ace 48)'"r Ce!Initicr. Cf Ct"OOStte Sn-.ble.A<<C l i}Pa<<ce grra i)r 4 5<<*5 O Pons ra 4 y)r 4I lil'iv rcr'." qf (i 4<<','I)fr'mre Cci ar;ts~<<n<<4, a ar (t,q<<r lri tati n a" i'ustOC OV Suatf'OCtlro .e averace le(e}c.'be boll.(tant(s) orosont In vour Intnxo>>nter. '.CQES eculaticns Olfe}(net ltrhttaticns cnlv in:er-)<<!-t:.Stances.: ca~nst,).4 vour e')Ib,:'l-v, e)cr--ne!Veraco cf tr'e rasut 5 of)halvses on your 4 (<<nt i<<~4)vhd 4 4 34 45'}4 4+)'I 4 is an<<ac),)<<C)54 af ate$4 h I hai 5 4 h<<en<<<<h 1<<LO*era<<5'i*4'(<<i}ra<<*i}C e 5 Lat e t!4 4<<3$~4 i 1'\i va<<4~agv*fi1 aie, e<<$,4 4 v t 4)t alt r (..-<<sto<<ater*g)c",us ed c<<Iv-:-<<e extent"!t-.e c;.--~tart'5 nct<<hooved.)~<<<<I)"ia<<ah"<i'" 4<<<<esp<<~<<tJ}<<i 1 4'i I)<<5 e'4%i<<(I~i l<<<<)r 4+}~ai}I ()43 h h~<<<<I}4<<~, O<<I V<<t)5-,4.4-<<)---C!4<<e" i}4 I O i'4 I 4<<t<<ll I,'<<~(hi I~~4~~~4 r es-*r%34 4)a 5 ee nr<<C ai,, 4}$4""C est SEE INSTRUCTIONS ON REVERSE SIDE SECTlON l I NUMBER~MI 0005827 PERMIT TEM 6 PRIORITY POLLUTANTS AND ADDITIONAL INFORMATION FOR SURFACE WATER DISCHARGE ONLY OlTF/ILL NEFB THE FQUMAIMG REQUESTED ItÃGIL4ATIGtl ~4'c A"DRESSED~<vSIRFACE'<<ATER DISCHARGERS. BZEI;eDJ VSE DISCHARGERS c~PROVIDE BIPECTED VALVES FOR THE QUANTITATIVE AIJD QUALITATIVE ItiFOJLeAT IGtt REQUESTED BELQWe A.IS TnIS FACILITY A PR!ueARY I'etXJSTRY?(REFER TO TABLE IA PAPE 4+1 (IF lf), GO TO E)(tF YES, GO TG B)B I:iDICATE TYPE QF PRIMARY IIISTRY AS LISTED IM TABLE IA PJJiE Qe CG;titty)E WITH C.)Ce 0 ES THIS OUTFALL DISCHARGE CGtffAie4 J4IY PROCESS WASTEWATER? flF tJGe GG TO E)(IF YES.GO TO 0)D INDICATE HHICH GC/PS FRACTIONS FJJST BE TESTED FOR~<REFER TO TABLE IA P4iE 4~1 IJQIE)cQR EACH GC/f'8 FRACTION CHECKEDe EACH SPECIFIC ORGANIC TOXIC POLLUTANT WITHltt EACH FRACTIGtt~BE AJJALYZED FOR (SEE TAB c I IA PAGE 42, IN ADDITIOtte ALL PRIMARY I QJSTRY APPLICAtftS WITH A PROCESS WASTEWATER DISCHARGE e~PROVIDE QUAJJTITATIVE DATA FCR EACH TOXIC POLLUTANT ltl TABLE 111A PAI<99~RECORD ALL DATA et FORMS PROVIDED (ITG4 7)Ilt THIS BQQKLETe (CONTINJE WITH E-K BELOW)~00 C QX YES STM ELJECJ)PWR X YES ta VOLATILE BASE/I'e'FUTRAL X ACID PESTICIDE*E IF JJtt)'.SURFACE WATER DISCHARGE APPLICA'ft (PRIHARY OR SECCtiDARY IJIDVSTRY)e REGARDLESS GF THE TYPE OF DISCHARGE KJK)WS GR HAS REASIXI TO BELIEVE THAT AJIY PIXLUTA'ft LISTED IN TABLE I IA AND IVA PAGES~IS DISCHVIGED FRCH AtJY IXJIFALlg THE QUANTITATIVE DATA~BE PRGVIDEDe RECORD~DATA ON FCRMS PROVIDED (ITEM 7)trt THIS BOOKLET.ttQT APPLICABLE/BELIEVED ABSENT PRESBIT/DATA IS ATTACHED c, IF A4Y SIJIFACE WATER DISCHARGE APPLICAtfi (PRIMARY GR SECGtJDARY ItCUSTRY), REGARDLESS OF TYPE OF'ISCMIGEe KVJOWS OR HAS REASCtt TO BELIEVE AIJY POLLUTÃffS uSTED IN TABLE VA PAGE~ARE DISOIARFED FRÃANY OVTCALL THE APPLICANT y~DESCRIBE REASQtiS FCR THE POILVTAtfi BEING PRESENT AND PROVIDE ANY AVAILABLE QUANTITATIVE CATAe REGQRD ALL DATA QN FORMS PROVIDB)(ITE)t 7)IN THIS BGOKLETe NGT APPLICABLE/BELIEVED ABSENT g, PRESENT/DATA tS ATTA(BED D G.ALL SIJIFACE WATER DISCHARGE APPLIC4JTS (PRIHARY AtfD SECCtGNRY INDUSTRIES) W)e: j GR JANUFACTVRES 2, 4, 5-TRICHJ)RGPHBK)XY ACETIC ACtD (2, 4, 5-t): l, 4, 5-TRICHLGRQPHBK)XY) PRGPANOIC ACID (SILVEX, 1, 4 5 TP))DIJE)jf/L U-l2e 4e 5-TRICHLORGPHBWL) PHQSPteROTHIOATE (ROtfJEL)J >TRIOLHCPJEJIL (TCPJ I OR HEXACHJ)ROPHEteE (HCP)J (Au.DATA FOR THE Pl)ST BE GBiBQTED VSItIG STAG)ARD AttALYTICAL CAJ.IBRATIOJ PROCE"IRES) QR KJJQWS GR HAS REASON TO BELIEVE lHAT TCDD IS OR HAY BE PRESENT Itt THEIR DISCHARGEe ~REPORT JXJALITATIVE DATAe GENERATED WHICH'SED A SCREENItJG PROCBXRE MOT~<IBRATED WITH A4ALYTIG'4. STA'OARDSe FGR 2.>e/L Se-TETRA:HLORQDIBEJJEO-P-DIOXItt (TCDDJ~RECGRD ALL DATA Ott FORD PROVIDED (ITFJI/)Itt THIS BOQKLETe:F icE SVRFACE wATER DISOIARGE APPLICAtfi gfXJS CR)AS REASON TO BELIEVE ieAT BIQLCGI+TOXICllY e-STS'<<ERE JeADE Itf IHE LAST THREE (5)YEARS gt A'h'F Mi APPLICA'll S DISCHARGES GR ON A RECEIVIMG WATER IN RELAY ICe4 TO A DISCHARGEi PROVIDE ietIS IteFGCATICM AS A4 ATTAOf)Bft TO 1HIS APPLIC)TIGMe K.:F A Ct)4TRACT LABORATORY OR CONSVLTltJG FIRM PERFORMED Ath'F TJE AteLAYSES REQUIRED BY THiS WFLICATICNe PROVIDE THE NAe%AND ADDRESS OF EAOI uBORATGRY OR FIRM AND te,E ANALYSES PERFQRJ'ED AS AN ATTACWEtft GF THIS*PPLICATIQMe 'DQ YQU DISCHARGE Ath'THER tOXIC QR IttJURIGVS CHEHICAL SVBSTA4CES t)QT':)TED ltt S IV PAGeE II AJ4)IIA leÃVA PA'ES Jf/+Qe lc"ESe THEN ICBftl v eeE"EHICA.c4!BSTANCES A'eD ESTIMATE eHE F I JF4.EFFUJEJJT CCJJCEMTRATIGJJS. SVB4IT THIS FGRI'IATIeAJ AS A.'I ATTAINT TG THIS APPLICettlGM

• Pesticide data is not required;however, it is D e X tK)T JV'PLICABLE/BELIEVED ABSENT PRESENT/DATA IS ATTACHED MOT APP'CABLE APPLICABLE/SEE ATTAOFJ)t JQT APPLIABLE g APPL ImLciSEE ATTAOIED X~JOT APPL'CABLE APPeLICABLciSEE ATTACHED provided.

"'lS"".CTICKS CR C.ttolETI",V: SECTICII i I ITEW 6 vis'ci,-ec ires)-'c~at'cn cn a spec('Ic cut(all ciscnar-ino to the s'r'ace~aters.Eht=-"-=ER'IIT'.".::"-"= IN THE BOX A THE"-"=, THIS ECRU.THE PE?MIT,':V'ABER CA)I BE FrnNO CII THE=p"."IT pAGE CF YCUo Ro(RING'!t" ls Ts a"ev cr not previousiv Ce~lttec foci lltv, then leave blank end a nu Per<<Il (be ass(oned.En,e-e cu-fal I'.er ln he space crcr'cec',cr seen page of Secticn I(.=or eacn'lvicua(clscnarce point s separate se tf iec-'cn i.,-e" cr.s must=e fV l~c s.-.ITEvi 6 4.anC ycu>ave-~o or more substantially.ncent(cai outfalls, vou mav reouest pormlsslcn from vout'ermlttinc but"crlty to)a"O~e Snc ana)VZe Only One Out(ail."" Supm(t the reeultS Of the anaiVSiS fOr other SubStant(ai(V (Centi"a(Outfal(S.vcur ecuest is cranted by tne pem(ttlno authorltv, cn a separate sneet attecnoc tc-"e acpllca-lcn foin ide.rifv<nicn out, a(I ,cu c(c test, anc caser ce wnv the utfal ls~nlch you<<Id not test are suostantia: Iv ident(al to-ne outfal I xnlcn you cic test.cO CFR part"."I<c)(8), Fridav,-'"-I" I~tg83, provides',cr a Small Business Exeipricn xicm tne repcrt(ng of" antitat(ve cata for organic toxic po(lutants anc toxic pollutants as redo(red by part 122.2((q)(7)(il)(A) or l22~'l(o)(7)<i(I)(A). These parts are self-explanatory ano co not reouire further lnstructicns. Slnolv go.Iicucn each cart snc c" as Indicated. Several incus-lai categories a,.c s.:csteccr(es nave been exemptec.ioi: submittln" cata cr car-slo TC/US"iactlcns ,'0:=R Oar-'~VO(.,a8, lip.".-', C-'CSV, april I,)g83,'OteS I, 2~and 3)."eviex the foiicxlno list to cete<tt(re xnetrer vour (ac(((tv dual(!Ies to be exe.ct'rom report:nc SC/"S lgas Chroatoorapnv/ uass Specticscc=y).Broctions. ext I I e:a I I Is Incustrv SC/I',S traction Testing and Reporting Exemptions -All'our GC/vS organic fractions ir-xe Greloe tsi I Is Subcategorv. -Pesticlae fraction In all otner S.ppartS Of this Incustrv.Ore)1(nlno anc Cress(no Industr-volatile.base/neutral, and pestlcice fractions In the Base and precious uetals subcateoory. -A(I four cc/vs organic fractions in all other subcategor les of this incustrv.Gum and Wood Chemicals Industry-Pesticide fraction in the Tall OII Rosin Subcategory and the Rosin Based Derivatives Subcateoory. -Pesticide and base/neutral fractions In all other subcateuorles of this Industry.oulo and Paper InduStrv-Pest(clde fraction In Papergrade Sulfite subcatecories <subparts J and U).Base/neutral and pesticide fractions in Oeink Subpart Q, Disso(vino Kraft Subpart F, and Paperboard from Waste Paper Subpart E.-volatile, base/neutral, pesticide fractions In the BGT Bleacned Kraft Subpart H.Sem(-chemical Suboarts B and C.and Nonintegrateo-Fine Papers Subpart R.-Acid.base/neutral. and pesticide fractions in Fine Bleached Kraft Suboart I, olssolvlng Sulfite Pulo Suboart K.Ground-xood Fine papers Subpart 0.xarket Bleached Kraft subpart G, Tissue from wastepaper suboart T.and Nonlnteerated Tissue Papert Subpart S.Steam Electric Power Plant Industry-Base/neutral fraction in thc Once.Through Cooling Water, Fly Ash.and Bottom Ash Transport Water process wastestreams. 38 SEE INSTRUCTIONS ON REVERSE SIDE SECTION II PERMIT~gZ 0005827~00<0 Ae USE THIS DATA SHEET TO RECORD I"FORMATION AS REQUIRED Itt'CHECX APPROPRIATE BOX FOR YHICH INFQRHATIQI THIS DATA SHEEf REPRESBITSs) CRITICAL MATERIALS 1 SECTIIXI II, ITEN 4-E.GRIXttDWATER DISCHARGE IttFQRYATIQtt (PAGE 55)X 2.sEcTIQI II ITBI 6.PRI0RITY PQLUITAMfs IN sIRFAQE HATER DlscHARGE (PAGE 37)TOXIC POLLUTANTS HAZARDOUS SUBSTANCES IN DISCHARGE LIST AIIY CRITICAL tATERIAL (TABLE IV PAGE 6)tNT ADDRESSED IN SECTIQI II ITBI 6 PRIORITY PIXLUTAMTS hHICH YOU XttQW OR HAVE REASON TO BELIEVE TO EE PRESENT It>THE DISCHARGE. SEE REVERSE SIDE OF THIS PAGE FQR clPvHPR DIRECTIQIS ~NOT APPLICABLE X APPLICABIE (SEE BELCH)UNITS CODE 1 Mg/I 2 Ug/I LBS/DAY KG/DAY LU e I A.NA<<E OF CRITICAL I'ATERIAL OR PRIORITY POLLUTANT B.AVERAGE CQICENIRATION; SA"PLE TYPEI (I OF ANALYSES C.vAX ItXN CQMCBIIRAT I Qt Ata vASS Ae IIAtlE OF CRITICAL<<ATERIAL CR PRIORITY PQLLUfAttf B.AVERAGE CCNCENTRATIONI SNePLE TYPE;4 OF ANALYSES C.YAX INN CQICEMTRAT ION AttD.ASS As NAt'k OF CRITICAL YATERIAL OR PRIORITY RXLIMANf Bs AVERAGE CQICENIRATIONI SA"PLE TYPEI ft OF A%LLYSES Ce PlAX INN COtCENIRAT ION AtID I'ASS*H draz e 00 3 0 20 12 WIT CODE Sts"RE TYPE OF AttAIYSES WIT CODE'IIT COCE LJ UNIT CODE W"lPLE TYPE OF AttALYSES UNIT CODE lttlT CODE LJ WIT CODE SAevPLE TYPE P OF ANALYSES LJ Qtll'ODE WIT CQDE LJ Ae NtYE OF CRITICAL MATERIAL QR PRIORITY PQLUffANT B.AVERAGE CQNCBITRATIQII SA<<PsLE TYPEe 1f OF AttALYSES QIIT CCDE SA'PLE TYPE LJ OF ANALYSES SAMPLE TYPE 1 GRAB 2 24 HR.COMP.C.MAXI'OttCEMIRATIQI AtsD I'ASS Ae IIAHE QF CRITICAL e lATERIAL QR PRIORllY PQLLUfAttf B.AVERAGE CQtCENTRATIOMl ~~<<PLE TYPE;>OF AltALYSES Ce YAX IYIf4 CQtCEMIRATIQI Ato YASS As IIA'1E CF CRITICAL YATERIAL OR PRIORllY POLLUTANT su(o B.AVERAGE CQICEIITRAT IQNl SAMPLE TYPE;" OF A IALYSES C~<<AXItlN'CQICBITRATIQI AtD YASS WIT CODE WIT CODE LJ WIT CODE SA"PLE TYPE ff OF AttALYSES WIT CODE WIT CODE LJ Ut IT CODE SA'tPLE TYPE r'r OF ANALYSES UltIT CODE WIT CCDE 4~tUetlE OF CRITICAL vATER IAL CR PRIORITY POLLUTANT m~W B, AVERAGE CQICBITPAT IOMI SA<<PLE TYPE~I QF ANALYSES Ce e"AXIS CQLEIIIRATIQI AlB MASS UstlT CODE SA'IPLE TYPE ff OF ANALYSES WIT CODE WIT CQQE As i%YE OF CRITICAL YATERIAL QR PRIORITY POLUJTAttf B, AVEPAGE COsCEMIRATION; SA<<PLE TYPE;fff OF ANALYSES C.,<<AX IHW CONCENTRATION AttD"ASS WIT CODE SA'lPLE TYPE ff OF ANALYSES LJ QIIT CODE lftlT CODE ADDITIONAL PAGES OF THIS ITEM 7 ARE ATTACHED FCR TK REST OF THE CRITICAL 0 YES MATERIALS Atilt/CR PRICRITY POLLUTANTS REQUIRED TO BE REPORTED~2 MO*Hydrazine is not expected to be present in discharge but small quantities may be found in the steam generators but would not be expected to be found in the actual discharge flow to Outfalls 001 or 002. '""STPS I'.--" R CC/LP<ET!)IS SECTIC)i I I"ls'cr>>fs To be used bv both sur'o.anc crouncwater <<:pl!cant T" record Irfornatlon on anv uichlcan critical material, E.p.A.r-y cc>l.tan. cr>>a:arpcus <<:s->>rce ln<<nicn r's scollcatlcn recuires Cata To oe crcvlcec.This<<ovid include anv chemical I.b cence'"w-"e"ic>>igan Cr!Tic~"sterlais~egister>>ble I'/).-'e E.P.A.P"lorl<<y pollute>>T'stlno!Table V).Cr Tables<<>>lcrsTS Crganic Toxic col lutants.'.her Toxic-ellut nTS~"-nvenTlonal and Nonconventional"cllutants and hazardous.,Cs a>>ces~!TE's 7 n!QQITV cCL<'VTS, A'IQ/Cn HAZARDS JSSTA.CES material I.E.3...8'st Tre name of The cremical s essence!critical material, prior lty'ollutant ~or hazardous substance) from Tables Iv, v 1c I l'A-/A as reculrec in the bcx<<nlc1 you checked", A.I-3.above.E1ter each chemical substance's parameter number as!Istec In Tables Iv, v and I IA<<//if provided.S.Provide T>>e average concentratlcn cf Tne chemical sucstance ne.ed In A.Indicate Tne sample type used and The number of analyses race To prcvlde the concentration cata for-"e c>>emlcal substance nenad ln A.Provide the maxlrtum concentratlc1 and cetermlne the ress loadlno o!the cnemlcal substance named in A.')8TES: I.If cnly one a>>alysls'<<as>>ace!Cr a chemical s;bstance then record that data as a maxlmun value.If more than one analysis nas been made!or a chemical substance Then orovide an averace value of those analyses and the maximum value.2.>>Is Section If, lte.7, sta Sheet oroviCes space fcr"eccrdlng cata!or 8 chemical substances !Materials). -'dditlcnal space for"sccrcing of data!Cr~ore Tran 8"aterlals can be mace by mak!ng copies cf this Iten 7 Data Sheet as~ceded.it Is also I, porta>>T To use separate set of Oata Sheets for each applicable reporting reculrement as I ls ed In A I 3.and or each out.al I 3.defer To The left naroin for The code number<<eoresentlng the sample type used and the appropriate unit codes.40 llGV Bngineeiiag &Science I Sununit Cuwpanp A X.K I, Y'I'(l.k I,'>ll R K I (l I','>ANALYT ICAL REPORT Cook Nuclear Proj: Waste Water Analysis Subm: Feb 21 Samples 29609-7 Ray V.Buhl (616)942-9600 Submittal Number: Location: Contact: Phone: Outfall OOC Htng Boiler Detection Units Limit WWES Sample No: 79691 Surfactants, MBAS Coliform,'ecal BOD, (5-Day)Sampled by: Date Sampled: Time Sampled: Date Received: Time Received: (0.025 (1 (31 02/21/94 00:00 02/22/94 09:00 0.025 1 1.0 mg/l cl/100ml mg/l e 1-End of Analytical Report*BOD sample is being reanalyzed and will be submitted after the results are received.55:>>;Gloniroo(l Illllo I'nrkwnp'I,". I'0 Box 87 I.(Iron(l Rnl>lds, XII I9588-087 I, 616/942-9600 I'nx 9 I2-6 I9l ll'1V LagiBeeiiii &SCienCe" I!Amunil (~imp:vu STATEMENT OF DATA QUALIFICATIONS ~%Y;KI,)"'I'l(l Xli NI(V,K It;I',s CLIENT: Cook Nuclear SUBMITTAL'9609-7 All analyses have been validated and comply with our Quality Control Program.No qualifications required.The following analyses have been qualified for the reasons cited.Sample No.(s): Explanation: Parameter: Reason:~KEY 1.2.3.4.5.6.7.8.9.10.Sample integrity suspect upon receipt (explain). Analysis performed beyond EPA established maximum allowable holding time.Detection limit elevated due to matrix interferences. Laboratory control sample value outside established acceptable limits.Matrix spike sample value outside established acceptable limits.Duplicate analysis value outside established acceptable limits.Surrogate/internal standard recoveries outside established acceptable limits.Data point suspect due to potential laboratory contamination (explain). Coelutes with the compound cited.Result may represent a combination of both compounds. Other (explain). Note: This document is included as part of the Analytical Report for the above referenced and should be retained as a permanent record thereof.:>5:>5 0!enw<>nit ttltts t nrkwny St;.t<>tt<>x n7.t.t;rnnu Rnt>ilats..ill lo;>88-087 l.6 t6/O t>->>t>OO I:nx O-t>-O>.Bin

GENERAL CHEMfSTRY RESULTS"Client Sa'mple'D: OUTFAL'L"',OOC- HEATlNG.BOILER:l'..,'..'AL Batch ID(s): 222 im Date'Colic'cte'di '02-21-94!:: $Date Received: 02-22-94"Matrix;,'vol'ater: P0469095-040-3N s'.,':.'::.::i".':::'.".Constituent::: ".':::::.':.":: Meth'od':> ':.<:,Res'uft';";:!:.':""".".'Detection Umlt"-" h<-'.,..;-,Datii';,,';,;.:,:,::: ".,;Date,,"....'Quallfierts)""""Anal'ed'-7;,'LALSam le" ID" Fluoride inm IL Bromide, inm IL Nitrate-Nitro en inm IL Sulfate, inm IL Total Phosphorus, inm IL Total Kjeldahl Nitrogen, inm IL Total C anide in m IL Total Suspended Solids, inm IL Chemical Oxygen Demand inm IL Total Organic Carbon, in m IL Ammonia-Nitrogen, in m/L Color Total Phenolics in m IL Sulfide, inm/L Sulfite, in mg/L 340.2 300.0 300.0 300.0 365.2 351.2 335.2 160.3 410.2 415.2 350.1 110.3 420.1 376.1 377.1<0.15<0.050<0.017<0.059 0.049 8.0<0.020 12 23 9.5 3.7<5.0<0.15<1.0 1.6 0.15 0.050 0.017 0.059 0.030 0.10 0.020 12 18 1.0 0.050 5.0 0.15 1.0 1.0 03-08-94 03-14-94 03-11-94 03-10-94 02-24-94 03-17-94 03-01-94 02-28-94 02-26-94 03-10-94 03-21-94 02-24-94 03-08-94 02-25-94 02-23-94 L1 304-22 L1 304-22 L1304-17 L1 304-22 L1304-16 L1304-16 L1 304-13 L1 304-21 L1 304-23 L1 304-23 L1 304-16 L1304-18 L1 304-14 L1304-19 L1 304-20 Comments: Nitrite4lltrogen ls not present in preserved samples.LOCKHEED ANALYTICAL SERVICES METALS RESULTS', Client" Simple'D."OUTFALL" OOC-':;:;.,':,.;.:,'EATING BOILER". .".:: ":"-"-'.LAL Batch IDls): 222 im'Date'Collecte'd '02-'21-94'.:

, Date Received: 02-22-94 Matrix: w'ater.PO¹69095-040-3N Conitltuentii:-

Aluminum Antimon Arsenic Barium Be Ilium Boron Cadmium Chromium Cobalt Co er Iron Lead Ma nesium Man anese Mercu Mol bdenum Nickel Phos horus Selenium Silver Strontium Thallium Tin Titanium Uranium Vanadium Zinc@Method 6010 6010 7060 6010 6010 6010 6010 6010 6010 6010 6010 7421 6010 6010 7470 6010 6010 6010 7740 6010 6010 7841 6010 6010 6020 6010 6010 Con'ceiitratlo'n .,-:-.Iin IL)..:-.<0.20<0.060<0.010<0.20<0.005<0.20<0.005<0.010<0.050 0.026 3.6<0.003<5.0 0.017<0.0002<0.067<o.oao<0.050<0.005<0.010<0.10<0.010<0.20<0.10<0.001<0.050<0.020;-Re'po'rtlnIj,;... .'Detection'mit .....,::.(m IL):,.0.20 0.060 0.010 0.20 0.005 0.20 0.005 0.010 0.050 0.025 0.10 0.003 5.0 0.01 5 0.0002 0.067 o.oao 0.050 0.005 0.010 0.10 0.010 0.20 0.10 0.001 0.050 0.020":"'De't'e: ."::'-.'"'Date".'.'Quallflerls) '-.A'nal ed 03-12-94 03-12-94 03-14-94 03-12-94 03-12-94 03-12-94 03-12-94 03-12-94 03-12-94 03-12-94 03-12-94 03-22-94 03-12-94 03-1 2-'94 03-04-94 03-12-94 03-12-94 03-12-94 03-22-94 03-12-94 03-12-94 03-22-94 03-12-94 03-12-94 03-1 1-94 03-12-94 03-12-94 Sam le ID L1 304-12 L1304-12 L1304-12 L1 304-12 L1 304-12 L1 304-12 L1 304-12 L1 304-12 L1304-12 L1304-12 L1304-12 L1304-12 L1304-12 L1304-12 L1304-12 L1 304-12 L1 304-12 L1 304-12 L1 304-12 L1304-12 L1304-12 L1 304-12 L1 304-12 L1 304-12 L1304-12 L1304-12 L1304-12 Comments: LOCKHEED ANALYTICAL SERVICES

VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 1 of 2 Clien S m le ID: 0 TFALL OC-HEATING BOILER Date Collected: 21-FEB-94 Matrix: WATER Anal ical Ba ch¹: 022594-8260F1 QC Batch ID: 022594-8260F1 LAL m I ID: L13 4-1 Date Received: 22-FEB-94 Date Anal zed: 25-FEB-94 Dilu ion Fac or: 1 SURROGATE RECOVERY 1 2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene 103 105 109 QC Limits 76-114 88-1 10 86-115 Constituent Chloromethane Vin I Chl ride Bromome h n Chloroethane Trichlorofluoromethane A n 11-Dihl r hn Carbon Disulfide Meth lene Chloride r ns-1 2-Dichloroe hene Vin IA ea 1 1-Dichloroethane 2-Butanone is-1 2-Dichloroe hene Chlrfrm 1 1 1-Trichloroethane Carbon Tetrachloride 1 2-Dichl ro h n B nzene Trichloroethene TCE 1 2-Dichloro ro ane Brm ihlrmehn 2-Chlor h I Vin I E h r 4-Meth I-2-entanone cis-1 3-Dichloro ro ene T I ene r ns-1-Dichloro r en 2-Hexa none 1 1 2-Trichloroethane Tetrachloroethene PCE Concentration /L<5<5<5<5<10<5<5<10<5<10<5<5<5<5<5<2<10<5<5<10<5<5 Reporting Detection Limit/L 10 10 10 Data Qualifier s LOCKHEED AIVAL YTICAL SERVICES VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING IVIETHOD 8260 Client Sam le ID: OUTFALL OOC-HEATING BOILER LAL Sam le ID: L1304-1 Page 2 of 2 Constituent Dibromochloromethane Chl rob nzen E h Ibenzene m-X lene o-X Iene S me Bromoform 1 1 2 2-Tetrachloroethane 1 3-Dichlorobenzene 1 4-Dichlor enzene 1 2-Dichlorobenzene Concentration /L<5<5<5<5<5<5 Reporting Detection Limit IL Data Qualifier s LOCKHEED ANALYTICAL SERVICES SEIVllVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 1 f2 D II: 21-FEB-4 M rix: WATER D R iv: 22-FEB-4 Dil inF r: 1 QC Batch ID: 8270-SEMIVOLATILES-5616 Date Anal zed: 04-MAR-94 R ATE RE VER 2-Ff r h n I Pheno!4, Nitrobenzene-d, 2-Fl r bi hen I 24 21 67 21-1 10-94 35-114 43-11 p-Terphenyld 21 33-141 Concentration Reporting Detection Limit Ph n i-hlr h r 1 4-Di hl r nz n Bnzl I h i 2-Iri r I hr 4M h I h n I ir nzn I hrn 10 Bnzi i i 2-hlr h m hn N hhin 4-hl r nilin 2M h ln hh I n Hexachloroc clo entadiene<10 10 LOCKHEED ANALYTICAL SERVICES SEMIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Client Sam le ID: OUTFALL OOC-HEATING BOILER LAL Sam le ID: L1304-4 Pa e 2 of 2 Constituent 2 4 6-Tri hl ro henol 2 4 5-Trichloro henol 2-Chlorona hthalene 2-Nitroaniline Dime h I h h la e Acena hth lene 2 6-Dinitrotoluene 3-Ni r nilin Ac na h hene 2 4-Dinitro henol 4-Nitro henol Dibenzof r n 2 4-Dini r oluene Dieth I hthalate 4-Chloro hen I-hen lether Fl rene 4-Ni r aniline 4 6-Dinitro-2-meth I henol N-Nitrosodi hen lamine 4-Brom hen I-hen le her Hex hl r nz ne Pentachloro henol Phenanthrene An hr ene r zle Di-n-but I hthalate Fluoranthene Prn B Ib nz I hhai 3 3'-Dichlorobenzidine Benzo a anthracene Chr sane is 2-E h Ihex I h h I Di-n-oct I hthalate Benzo b fluoranthene B nz kfl ranh ne Benzo ren Indeno 1 2 3-cd rene Dibenz a h anthracene Benzo h i er lene Concentration (IL)<10<10<10<25<10<10<2<25<25<10<10<10<10<10<2<25<10<10<25<10<10<10<10<20<10<10<10<10<10<10<10<10~Reporting Detection Limit (IL 10 10 10 25 10 10 10 25 10 25 25 10 10 10 10 10 10 10 25 10 10 10 10 10 20 10 10 10 10 10 10 10 10 10 10 Data Qualifier(s) LOCKHEED ANALYTICAL SERVICES SEMIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 P 1 D II: 1-FE-4 M rix: WATER I R m I D R iv: 22-FEB-4 Dil inF r: 1 QC Batch ID: 8270-SEMIVOLATILES-5616 Date Anal zed: 06-MAR-94 2-Fl r h n I Phenol', NltrobenzeneM, 2-FI r ihnl 21 19 61 21-1 10-94 35-114 4-11 p-Terphenyl-d 21 33-141 Concentration Reporting Detection Limit hn i-I I h r 4-Di hi r nz n Bnzl I hl i-h ri r I hr 4M h I h n I Ni r nz I r n Bnzi i i-r h hn N hhln I r nili 2M h In hh I n Hexachloroc clo entadiene<10<10 10 LOCKHEED ANALYTICAL SERVICES SEMIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Client Sam le ID: OUTFALL OOC-HEATING BOILER LAL Sam le ID: L1304-4RE Pa e2of2 Constituent 2 4 6-Trichloro henol 2 4 5-Trichlor hen I 2-Chlorona hthalene 2-Nitroaniline Dime h I h hal e Acena hh len 2 6-Dinitrotoluene 3-Nitroaniline Acen h hene 2 4-Dini r hen I 4-Nitro henol Dibenzofuran 2 4-Dini r luene Di h I hh I 4-Chloro hen I-hen lether Fluorene 4-Ni ro niline 4 6-Dini ro-2-me h I hen I N-Nitrosodi hen lamine 4-Bromo hen I-hen lether H x hl r enzen Pen chloro henol Phenanthrene Anthra cene r zole Di-n-u I h hal e Fluoranthene P rene Bu I enz I h h la 3 3'-Dichlorobenzidine Benzo a anthracene Chr sene bis 2-E h Ihex I h hal e Di n-c I h h I e Benzo b fluoranthene Benzo k fluoranthene Benzo r ne Inden 1 2-cd rene Dibenz a h anthracene Concentration I/L)<10<10<10<25<10<10<10<25<10<2<25<10<10<10<10<10<25<2<10<10<10<25<10<10<10<10<10<2<10<10<10<10<10<10<10<10 Reporting Detection Limit I/L)10 10 10 25 10 10 10 25 10 25 25 10 10 10 10 10 10 10 25 10 10 10 10 10 10 10 10 10 10 10 10 10 10 Data Qualifierls) LOCKHEED ANALYTICAL SERVICES LOCKHEED ANALYTICAL SERVICES L AND GREASE BY FTIR L3.2 OIL AND GREASE Indiana Michigan Power Co." Bridgman,MZ Attn: Client

Reference:

(Project COOK-JENZ)

Client Sample ID: Date Collected! Date Received: Matrix: Analytical Batch f: OUTFALL OOC-HEATING 21-FEB-94 22-FEB-94 Water 030894-418.1 BOILER LAL Sample ID: Date Analyzed: Date Extracted: Dilution Factor: QC Batch ID<L1304-8 08-MAR-94 02-MAR-94' 413.2 OIL AND 1 Total Oil and Grease 1.0 r PESTICIDE ANALYSES RESULTS BY GC/ECD USING METHOD 8080 m I 1 4-D E r:-FEB-4 M ri: WATR Anal ical Batch¹: 030390-8080-E-1 D An I z-MAR-4 Dii inF r: 1 QC Grou ID: 8080 PEST/PCB 5666 T MX DCB RR A E RE VERY 97 QC Limits 60-150 Constituent Concentration L Reporting Detection Limit L Data Qualifier(sl -H-H HEPTA H R P XIDE HL R DANE 4 4'-DDE 4'-DDT END LFAN II 4I METH XY H R XAPHEN P B-12 2 P B-4 TECHNICAL CHLORDANE TCMX-tetra-chloro-meta-xylene DCB-Deca-chloro-biphenyl LOCKHEED ANALYTICAL SERVICES

RAD DATA REPORT (ra01)Indiana Hichigan Power Co.*Bridgman,HI Organic and Inorganic Contaminants (Project COOK-JEHI) Hatrix: lister Client Sample ID: OUTFALL OOC-HEATING BOILER Date Collected: 21-FEB-94 LAL Sample ID: L1304-10 Date Received: 22-FEB-94 Login Hubert L1304 Gross Alpha Gross Beta 13 HAR.94 GR ALP/BETA LAL-0060 5902 13-HAR-94 GR ALP/BETA LAL-0060 5902 0.24 0.1 0.5 1.2 0.92 2.1 pCI/L pCI/L Page 2

RAD DATA REPORT (ra01)Indiana Hichigan Power Co.*Bridgman,HI Organic and Inorganic Contamfnants (Project COOK-JEHI) Hatrix: Mater Client Sample ID: OUTFALL OOC-HEATIHG BOILER Date Collected: 21-FEB-94 LAL Sample ID: L1304-11 Date Received: 22-FEB-94 Login Number: L1304 Ra-226 Ra-228 21-HAR-94 RA-226 LAL-0073 5874 14-HAR-94 RA-228 LAL-0074 5873 0'49 7.39 0.055 0.5 0.044 0.5 pCI/L pCi/L Page 3 PH Meter CPC y-le~Cal date due f+/Sample Sample Time Sample 9 Sample Date CDM Entered by PH Analysis (LAB.079)Outfall OOC 5.3.5 6)Sample C/ph (prior to correction) 7)NH~pH correction 02 5.3.6 8))ample results C/pH.(after 2 7'H Correction) 3 Sample Sample Time Sample jj Sample Date CDM Entered by 5.3.5 6)Sample C/ph (prior to correction) 7)NH3 pH correction 5.3.6 8)Sample results'C/pH (after Correction) 9)LAS.041 Specs Verified by:~R'upervisor Review/Date ~~/+/~Form prepared by/Date Form approved by/Date 12 THP LAB.041.25s Revision 1 Outfall OOC Determination of Total (Lab 170)Chlorine Instrument CPC//S0~Technician Sample/Standard Sample j/Date Time CDM Entered by 37 3i 5 Z~.I)Absorbance 6.11 2)Results, ppm C-A (~C~cm 3)Dilutions made C2 C3 CZ M 4)Results, ppm (82~8 3)c..W 5)LAB.041 Specs Verified by:~H Supervisor Review/Dare~Mt~~ Pore prepared by/Dree/~f'+Form approved by/Date 12 THP LAB.041-25)l Revision 0 SEE 1NSTRUCTIONS ON REVERSE SlDE SECTION I I PEŽT~.qZ g006SZT 0 OD A o LOCATION OF D I SOWSIE~SW q~SE o, EZ00,,~06, zos~06 6, pj9E~19~DISCHARGE LOCATION Bo H4t%RECEIVIHI HATER (IEo GAOLtCWATER CR IQ%CF QRFACE'NA Co OO YOU DISCNRGE SEASIXRLLY (IF IOo CCNTItlK lO E)Do IF YES LIST DISOHKE PERIODS N/A IO./EAV tQo/DAY B SO PT ION OND FLOW RATE WASTEWATER ~p~ggg Eo IhM)APPLICATION RAlK N/A IHo/IRo~s LJ IRo/DAY IHo/ICo~u~~'u KI+1 CONTACT COOUNQ 2 NONCOIIDICT COOLDIQ 3 PROCESS SANITARY 5 STORMWATER F o 1YPE OF HASIEHAIKR DISCHA%E Go DISEHU4E SOEnlK (YEARLY AVERNKI Ho DISCHhRtK FUBI RATE All time daily maximum times 365.IDTAL YEARLY DAILY HIHIIItl DAILY tQXIIItI 4 9 Itl+CXE 0~2 2.6~2~2~u LJ HXRS/DAY oovhooo 1 MQY 2 MQD 3 QPD Jo HAXDltl DESIGN DISCHUSIE FUX RNKo Ao IXI YCU USE HATER TREAT%HE AIDITIVKS 10 1RFAT VIXR Dl~(IF HSo CCNTIIAK 1D IT81 3)DESIGN 5.2 V lo TIE HAXIPltl DISCHARGE FLDH RATE TO BE AUDERIZED IH PBIIITo ltllQCXK ITEM 2 WATER TREATMENT ADDITIVES Bo IW%RlCTlENo JUO OEIIICAL IXPEOSITICN OF TABIE AIIITIVESo oF TIEBK ITIYEs, SULFURI C ACID SULFURIC ACID SODIUM H Neutralization" SODIUM HYDROXIDE UNITS CODE 1 MQ/I 2 UQ/I MARSULEX, INC.111 GORDON BAKER ROAD, SUITE 30 NORTH YORK, ONT M2H 3R1 Do EXPECIED DISCHUGE CEIEEHIIIATICN OF AIDITIVESo AEDITIYE~Sodium Sulfate AEDITIVE IWE AEOITIVK Nh%E.DO 51I 1RFAT 1IE DISONCE lD RBOtE AISITIVEST HAVILAND PRODUCTS COMPANY 421 ANN ST., N.W.GRAND RAPIDS, MI 49504 HINII%tl INITS AY8IIGE ItlITS HAXIIEtl ItUTS ECCK~gag~COCK'0130011500~1 ~l Wo~LJo~LJi~Fo WLT IS THK RBEHAL EFFICIBEY AHD DISCHARGE FR81EIC6 N/A AEDITIVE HNE AESITIVE VIE AED ITIVE IWE IRSo/DAY DAYS/HH.LJ G, AS AH ATTICIP%HT 1D 1HIS APPLICATICN PROVIIX SPECIFIC HAPtQLIAH CR ACULTIC TOXICCUXIICAL DATA ER REFERENCE HHICH ARE AVAILABLE AHD IHPOI6ATICN IXI II%RATE OF DESRADATICN OF TIE fRXLCQ FCR DCH AEDITIVEo MSDS attached.*Approximately instantaneous neutralization upon mixing-(New tank to be completed January of 1995 will ensure complete neutralization prior to discharge.) 31 INSTRUCTIONS FOR COMPLETING SECT)Of I I ITEMS I ANO 2 This form requires Information on the facility'5 dl5charge location, discharge schedule, volume t lov rate and vater treatment add lt I ves.ENTER THE PERHIT NUMBER IN THE BOX AT THE TOP OF THIS FBI.THE PERMIT NUMBER CAN BE FOUNO ON THE FRONT PAGE OF YOUR EXPIRING pERMIT.It tnls Is a nev or not previously perm)tted facility, then leave blank and a numoer rill be as5lgned.Enter the outtall nuaber In space provided for eacn page o'.Section I I.For caen Individual dlscnaroe point 5 separate set ot Section II forms must be filled out.ITEM I OISCHARGE LCCATION SCHEDULE ANO FLOW RATES A.Enter the location ot discharge, this should include quarter~uarter section.quarter section, section, Iorni and range.B.List name of receiving water<If surface~ater discharge). C.Indicate rnetnar facility discharges on a seasonal basis.O.If yei, list dlscnarge periods.E.provide the land application rates used or expected to be used In terms of inches per hour, hours Der day, and Inches Der raex.F.Indicate the type of vastevater to be discharged froa this outfall.Rater to the wastewater type code given In the lett margin.MOre than One COqe may be applICable. G.Provide the average nuroer of hours per day In vhlch the taclllty dlscnarges treated wastewater and the total number ot days per year in mich The dl5cnarge occur5.H.provide current (frcm the last l2 months)or expected f low rates as requested, Refer to unit code divan In the lett margin for tne appropriate t low units.MGY-million gallons per year;MGo million gallons per day;GPO gallons D>>day.I.Provide the maximum discharge tlor rate which you rant to have authorised within the Detmlt.NOTE: For NPOES permlt5 allY.the use ot such a tlor rate rill not place an actual limit restriction on the f lor but vill be the t low rate used to dewloo ett luent limits.Also, when the Monthly operating Reports are reviewed by compliance statf It vill help thea to determine If any ner or Increased uses might have occurred at the taclllty.J.Provide the design t low tor this specific outfall discharge (e.g.batch treatment System flow, packaged treatment syat~flows or acme other f Inlte treats>>nt systea flow).ITOI 2 WATER TREATMENT AOOITIVES A.Indicate rhether dl5Charge Is treated vlth conditioners, Inhibitors, or mlcrobloclde. If not, continue to Item 3.B.Give name, function, and chemical ccnoosltlon ot additives used.C.Give name and address ot the manutactureris) ot the additives used.0, Indicate expected mlnlaxxa, awrage and maxlaxaa discharge concentrations ot the addltlvels) tor this dl5char9e. Ind)Cate rnetner yOu treat the dlSCnarge tO ramOVe the addltlVela) befOre d)SCharge Ot raaterater. F~Indicate the removal efficiency ot each additive from the wastewater and the discharge frequency ot each additive to the surface water or groundwater. G.NOTE: lt ls the responsibility ot the applicant to supply the product Intormat)on as requested, in this item a.Information requested but not suDp lied may re5ult In the aDpl lcatlon being returned to the apDI leant for completion. 32 MATERIAL SAFETY DATA SHEET SODIUM HYDROX I DE 50%INDUSTRIAL GRADE e33k SECT I QN I-I DENT IF I CATION MANUFACTURER S NAME o o~~~~~~~~~~ADDRESS (STREET, CITY, STATE, Z IP)PHONE NUMBERS a~~o~o~~~~~a~a~~~~EMERGENCY PHONE NUMBER......... EFFECT I VK DATE s~a~~~~~~e o~e~~~~TRADE NAME o~~~~~~s~~~~~~~~~~~~~CHEMICAL FAMELY Haviland Products Company 421 Ann St., N.W., Grand Rapids, MI 49504 (616)361-6691 CHEMTREC (800)424-9300 6/18/91 SODIUM HYDROXIDE 50%INDUSTREAL GRADK Alkali, Base SECTION II-HAZARDOUS INGREDIENTS HAZARDOUS COMPONENTS QSHA/PEL ACGIH/TLV (Uni ts)PROD.CAS 0 Sodium Hydra-ide (Caust i c Sada)(48.5-51.0% by wt)Sodium Chlaride (0.8-1.3%by wt)Water (Bal ance)2 mg/m=TWA Nat Kst ab 1 i shed Nat Estab 1 i shed 2 mg/m~TWA Not Established Nat Kstab l i shed 10-7 7647-14-5 7732-18-5 SECTION III-PHYSICAL DATA MCXM MCC BOILING POINT................ 293 F (145 C)FREEZING POINT............... 60 F (15.6 C)VAPOR PRESSURE (mm Hg)........ 1.5 C<20 C VAPOR DENSITY (Air~i)......... Na Information Available SOLUBILITY IN H20-~~.~~~.~....Campletely APPEARANCE/ODOR.' ~...~.~~..~~Clear, Color less Liquid;Odorless SPECIFIC GRAVITY (H20~i).....1.52 PH............................ Nat Established SECTION IV-FIRK AND EXPLQSIQN HAZARD DATA D RR RCt C DPCRCRZECZ R R K RCXRCDXZKRRCtCSRP K R%R D CIRC@FLASH POINT..................'...... Nat Flammable LOWER EXPLOSIVE LIMIT (%by Volume)Nat Appl i cabl e UPPER EXPLOSIVE LIMIT (%by Volume)Nat Applicable EXTENGUESH MEDIA................... As f ar Surrounding Fires 07/30/1'F91

MATERIAL SAFETY DATA SHEET SODIUM HYDROXIDE 50%INDUSTR I Al GRADE SPECIAL FIRE FIGHTING PROCEDURES... UNUSUAL FIRE HAZARD................ Near NIOSH/MSHA approved self contained breathing apparatus and full protective equipment when this material is involved in a fire.In solution caustic can react with amphateric metals generating hydrogen whi ch i s f 1ammabl e and/or e:~pl osi ve i f i gni ted o SECTION V-HEALTH HAZARD DATA CARCINOGENICITY............. NTP~~~~~~~~~~~~~~~~~~~~~~~~~I ARC~~~~~~~~~~~~s s s~~~~~~~~~OVER EXPOSURE EFFECTS....... PRIMARY ROUTE (S)OF ENTRY...FIRST AID PROCEDURES........ EXPOSURE AGGRAVATED MEDICAL None Na~~no Redness of E:cposed Tissues with passible burns r esul ting in deep ulceration. Skin Contact, If inhaled: Remove to fresh air.If not breathing', give artif icial respiratian, pref erably mouth-to-mouth. If breathing is diff icult, give o-ygen.Get medical attention. In case of contact: Immediately flush, eyes or skin with plenty af~ater for at 1east 15 minutes while removing cont,aminated clothing and shoes.Get medi cal attent.i on.Nash cl othing bef ore reused Ingestion: Da not induce vomiting.If conscious, dilute by giving several glasses af water.Call a Physician Immediately. CONDITIONS None Currently Known SECTION VI-REACTIVITY DATA MZf MMMMMMMWCCCR&MMM MClMXt CHEMICAL STABILITY............ Stab 1 e CONDITIONS TQ AVOID........... Nat Applicable INCOMPATIBLE MATERI ALS........ Acids DECOMPOSITION PRODUCTS.~~.~~~~Nane Curr entl y Known HAZARDOUS POLYMERIZATION...... Ni 1 1 Nat Occur POLYMERIZATION AVOID.......... Nat Applicable Ckm RRRCECP C RRXtStRCJDR SX'CRCt R'C R PAR~QR gLRR RCSCCC5 SECTION VII-SPILL OR LEAK PROCEDURE MATERIAL SAFETY DATA SHEET SODIUM HYDROXIDE 50/INDUSTRIAL GRADE FOR SP ILL~~~~~~~~~~~~a s~~~~s~MASTK DISPOSAL METHOD..... i...Add non-r cacti ve dry, absorbent such as diatomaceous earth.Shovel or sweep up and place in an approved DOT container and seal.Flush contaminated area and neutrali"e with dilute acid.Dispose of spilled or waste product, contaminated soil and other contaminated mater ials in licensed landfill or treatment facility in accordance with all federal, state and local regulations. SECTION VI I I-SPECIAL PRQTECTION WCR RESPIRATORY PROTECTION........ Supplied air or self contained breathing apparatua with ful l f ace piece.VENTILATION.............,..... To maintain vapors below limits.PROTECTIVE GLOVES............. Rubber or other impervious materials. KYE PROTECTION............;... Chemical splash proof goggles.OTHER PROTECTIVE EQUIPMENT.... A safety shower and eye bath should be available. For operations where spills or splashing may occur, use an impervious body covering and boots.HANDLING AND STORAGE.......... Store in cool, dry, well ventilated area.Keep containers closed when not, in use.SECTION IX-SPECIAL PRECAUTIONS CCM HAZARD CLASS...............:.. Corrosive Material DQT SHIPPING NAMK.........~..SODIUM HYDROXIDE, LILQUID UN NUMBER e~~~~~~~~~~~~~~~~~~~~UN 1 824 REPORTABLE QUANTITY (RQ)...... 2000 lbs.REFERENCES HMI S: H-S, F-O, R-1 SODHYDOX 07/" 0/1 9'P 1 friARSULEX, r~(Q I 0"I I MATERIAL SAFETY DATA SHEET.Sulfuric Acid 1.PRODUCT AND COMPANY IDENTIFICATION Molecular Weight: 98.08 vCASP 7664-93-9.Product Name: Sulfuric Acid:Formula: H,SO, Chemical Name: Sulfuric Acid chemical Family: Inorganic Acid~Synonyms: Sulphuric Acid, Oil of Vitriol, Battery Acid Product Use: Used tn manufacture of fertilizers, explosives, other ackls, metal plclding and petroleum processing. MARSULEX Inc.111 Gordon Baker Road ulte 300 orth York, ONT M2H 3R1 (416)496-9655 MARSULEX inc.40 Richards Avenue P.O.Box 5453 Nofwalk, CT 0685&6453 (203)8544300 EMERGENCY TELEPHONE NUMBER (800)263-S502 Prepared by MARSULEX Technical Section (416)49&4164.2.COMPOSITION/INFORMATION ON INGREDIENTS Sulfuric Ackl Water%by Wt.70-100%CAS Number 7664-93%7732-186 3.HAZARD INFORMATION EMERGENCY OVERVlEW:/Dangerl Extremelycorrosive. Causesseverebums. Reacts vlolentlywlthwater. Hlghlyreactlveand capable'f igniting combustible materials on contact.Not flammable, but reacts with most metals to form explosive hydrogen gas./Sulfuric Add h a colorfess to amber, dear to slightly doudy, oily liquid.National Rre Protection Association (NFPA)Rating Hazardous Materials fdentNcatlon System (HMIS)Rating FlRE 4 Extreme/Severe .3 High/Serious ~2 Moderate 1=Slight 0~Minimum W Water Reactive Date: February, 1993.Superaedea: February, 1990 MARSULEX MSDS 4010E Page 1 of 9 MPTERIAL SAFETY DATASHEET, Sulfuric Acid 3.HAZARD INFORMATlON (continued) POTENTIAL HEALTH EFFECTS: Exposure Limits: SWfuric Acki ACGIH (TLV)1 mg/m (TWA)3 mg/m'STEL) OSHA (PEL)1 mg/m'fWA)In contact with the skin: Concentrated solution may cause pain and severe burns to the skin and brownish or yellow stains.Prolonged and repeated exposure to dilute solutions may cause irritation, redness, pain and drying and cracking of the skin.ln contact with the eyes: Immediate pain, severe burns and corneal damage which may result In bllndnesa C~Inhaled: Mists and vapors may cause Irritation of the eyes, nose and respiratory tract.May cause Increased~pulmonary resistance, transient cough and bronchoconstrlctlon. Severe overexposure may result In lung collapse and pWmonary edema which can be fatal.ingested: Severe burning and pain ln the mouth, throat and abdomen.Vomiting, dhrrhea and perforation of the esophagus and stomach lining may occur.Long Term Exposure:~Repeated exposure may produce erosion and discoloration of teeth.Although no direct link has been established between exposure to sulfuric acid, Itself, and cancer In man, the World Health Organization (WHO)Intematlonal Agency for Research on Cancer (IARC)have concluded that occupational exposure to strong Inorganic acid mists containing sulfuric acid Is carcinogenic to man, causing ,'ancer of the larynx (the voice box)and, to a lesser extent, the lung.Exposure to any mist or aerosol during the use of this product shoWd be avoided and, In any case, keep exposures below the occupational exposure limit for sulfuric acid.Corrosive effects on the skin and eyes may be delayed, and damage may occur without the sensation or onset of pain.Repeated overexposure may lead to contact dermatitis, may cause bronchitis with cough, phlegm,>'hortness of breath and emphysema, can cause chronic runny nose, tearing of the eyes, nosebleeds and stomach upsets.Strict adherence to first akl measures following any exposure Is essenthl.Existing Medical CondNons Possibly Aggravated By Exposure: Skin irritation may be aggravated In IndMduals with existing skin lesions.Breathing of vapors or sprays (mists)may aggravate acute or chronic asthma and chronic pulmonary disease such as emphysema and bronchitis. Carcinogenicity Data: Although there are reports linking exposure to sulfuric ackl to cancer, this product Is not classified by NTP (National Toxicology Program), not regulated as carcinogenic by OSHA (Occupational Safety and Health Administration), and has not been evaluated by IARC (International Agency for Research on Cancer)/or ACGIH (American Conference of Governmental Industrial Hyglenlsts).(See also, Long Term Exposure). N Effective Oate: February, 1993 Supersedes: February, 1990 MARSULEX MSDS 4010E Page 2 of 9 NARSULEK, MATERIAL SAFE IY DATA SHEET Sulfuric Acid , 4.FIRST AID MEASURES Prompt removal of this material from contact with the body ls of utmost Importance. &TART FIRST AID AT ONCE.Precaution: Persons attending the victim should avoid direct contact with heavily contaminated dothlng and'omitus.Wear impervious gloves while decontaminating skin and hair.In contact with the skin: Rush skin with running water for a minimum of 20 minutes.Start flushing while removing~contaminated dothlng.If Irritation persists, repeat flushing.Obtain medical attention IMMEDIATELY. Do not transport victim unless the recommended flushing period ls completed or flushing can be continued during transport a/'hile the patient ts being transported to a medical facility, apply compresses of Iced water.If medical treatment must be delayed, immerse the affected area ln iced water.If immersion ls not practical, compresses of iced water can be applied.Avoid freezing tissues.Discard heavily contaminated dothlng and shoes in a manner which limits further exposure.Otherwise, wash/.dothtng separately before reuse.In contact with the eyes: Immedhtely flush eyes with running water for a minimum of 20 minutes.Hold eyelkfs open during flushing.If irritation persists, repeat flushing.Obtain medical attention IMMEDIATELY. Do not transport/victim until the recommended flushing period Is completed unless flushing can be continued during transport. .Inhaled: Move victim to fresh air.Give artlcial respiration ONLY If breathing has stopped.Give Cardiopulmonary flesuscltatlon (CPR)Il there ls no breathing AND no pulse.Obtain medical attention IMMEDIATELY. Ingested: If vlctlm ls alert and not convulsing, rinse mouth and give TA to 1 glass of water to dilute materiaL If spontaneous vomiting occurs, have victim lean forward with head down to avoid breathing In of vomitus, rinse mouth and administer more water.IMMEDIATELY contact local poison control center.Vomiting may need to be induced but should be directed by a physlchn or a poison control center.IMMEDIATELY transport victim to an emergency facility.h//Note to Physician: AII treatments should be based on observed signs and symptoms of distress In the patient.Medical conditions that may be aggravated by exposure lndude asthma, bronchitis, emphysema and other lung diseases and chronic nose, sinus or throat conditions. Severity of the bum Is generally determined by the concentration of the solution and the duration of exposure.In the event of skin or eye contact, lmmedhte and thorough flushing Is essential. Continued washing of the effected area with cold or Iced water wIII be helpful in removing the last traces of sulfuric acid.Cream or ointments should not be applied before or during the washing phase of the treatment. 5.FIRE FIGHTING MEASURES sh Point (method): Not applicable, product Is non-flammable utolgnltlon Temperature: Not combustible Rammabllity Limiti in air(%): UEL Not applicable LEL Not applicable Eeettlte Date: February, 1993 Supersedes: February, 1990 MARSULEX MSDS ItI010E Page 3 of 9 MATERIAL SAFETY DATA SHEET Sulfuric Acid 5.FIRE FIGHTING MEASURES (continued) Fire Extinguishing Media: For small fires use dry chemical or carbon dloxkie.For large fires, flood fire area with r'ater from a distance.Expect violent reaction with water.Do not get solid stream of water on spilled materhl.Special Fire Fighting Procedures: Wear a NIOSH/MSHA approved self~ntalned breathing apparatus If vapors or mists are present and full protective clothing.For fighting fires in dose proximity to spill or vapors, use acld-resistant personal protective equipment. Evacuate residents who are downwind of fir.Prevent unauthorized entry to fire area.Dike area to contain runoff and prevent contamination of water sources.Neutralize runoff with lime, soda ash or other suitable neutralizing agents (see Deactivating Chemicals, Section 6).Cool containers that are exposed to flame with streams of water until fire ls out.Other Fire or Explosion Hazards: Not flammable but highly reactive.Capable of Igniting finely divided combustible materhls on contact.Reacts violently with water and organic materials with evolution of heat.Extremely hazardous Jin contact with many materials, particularly carbldes, chlorates, fulminates, nitrates and plcrates.Sulfuric acid reacts with most metals, espechlly when dilute to give flammable, potenthliy explosive hydrogen gas.Hydrogen gas can accumulate to explosive concentrations Inskle conflned spaces.Follow appropriate NFPA codes.6.ACCIDENTAL RELEASE MEASURES Steps to be taken In the event of a spill or leak: Remove all Ignition sources.Ventilate area Use approprhte Personal Protection Equipment. Prevent liquid from entering sewers or waterways. Dike with Inert material (sand, earth, etc.).Stop or reduce leak lf safe to do so.Collect Into containers for reclamation or disposal only if container~is suitable to withstand the material.Consider insitu neutralization and disposal.Ensure adequate decontamination of tools and equipment following dean up.Comply with Federal, Provincial/Stateand local regulations on reporting releases.Deactivating Chemicals:,Ume, limestone, sodium carbonate (soda ash), sodium bicarbonate, dilute sodium+hydroxide, dilute aqua ammonia.Waste Dlsposai Methods: Dispose of waste material at an approved waste treatment/dtsposai facility, ln accordance with applicable regulations. Do not dispose of waste with normal garbage or to sewer systems.V'ote-pean-up materfal may be a RCRA Hazardous Waste on dhposal.rr'Spills are subject to CERCLA reporting requirements: RQ 1000 lbs.7.HANDLING AND STORAGE Precautions: Wear appropriate Personal Protection Equipment. Do not breath sprays or mists.Do not ingest.Do/not get In eyes, on skin or on clothing.Keep ignition sources away from sulfuric acid storage, handling and transportation equipment. Handling Procedures and Equipment: Carbon steel or stainless steel materials are suitable for use for acid concentrations equal to or greater than 93%.However, the effect of lower concentrations on the materhls of construction can be very complex.Contact product supplier for specmc recommendations when handling sulfuric acid at strengths less than 77%.Effecffve Date: February, 1993 Supersedes: February, 1990 MARSULEX MSDS 0010E Page 4 of 9 FJRSUI.EX, MATERIAL SAFETY DATA SHEET Sulfuric Acid 7.HANDLING AND STORAGE (continued) Storage Temperature: Store above freezing point (Section 9).Elevated temperatures will increase the corrosion/rate of most metals.Storage Requirements: Store packaged acid in a dry, well, ventilated location away from combustibles, oxldlzers, bases, or metallic powders.Storage tanks should be protected from water Ingress, be well ventilated, and maintained structurally in a safe and relhbie condition. Other Precautions: Sulfuric ackl will attack some forms of plastics and coatings.Always add acid to water-not j water to acid.If kept In upper floors of building, floors should be acid proof with drains to a recovery tank.8.EXPOSURE CONTROLS/PERSONAL PROTECTION-Recommendatlons listed In this section Indicate the type of equipment which will provkle protection against over exposure to this product Conditions of use, adequacy of englneerlng or other control measures, and actual exposures will dictate the need for specific protective devices at your workplace. ~Engineering Controls: Local exhaust venNation required.plratory Protection: A NIOSH/MSHA approved air-purifying respirator equipped with acid gas/fume, dust, mist cartridges for concentrations up to 10 mg/m.An air-supplied respirator If concentrations are higher or unknown.S)tin Protection: Impervious (l.e., neoprene, PVC)gloves, coveralls, boots and/or other acid resistant protective ~clothing. Eye Protection: Tight-fitting chemIcal goggles and face shield./Other Personal Protective Equipment: Where there Is a danger of spilling or splashing, acid resistant aprons or q suits should be worn.Trouser legs should be worn outside (not tucked In)rubber boots.Safety showers and l eyewash fountains should be installed in storage and handling areas.9.PHYSICAL AND CHEMICAL PROPERTIES h d d h Physical State: Vquld Appearance and Odor.SWfurlc acid Is a clear to amber, heavy, oily liquid which may have a sharp penetrating odor.Odor Threshold: No data Boiling Point: 77.67%: 193'C (380'F);93.19%: 278K (529'F);98%: 330'C (626'F)I@citing/Freezing Point: 77.67%:-11.2'C (+11.6'F); 93.19%:-29.5'C (-21.'I'); 98%:-1.1'C (30'F)Vapor Pressure at%PC (102'F): 77.67%: 1.2 mmHg;93.19%: 0.0016 mmHg;98%: 0.002 mmHg Specific Gravity at 15'C (60'F): 77.67%: 1.7059;93.19%: 1.8354;98%: 1.8437 Vapor Density: (Air=1): 3.4 sulfuric ackl component Bulk Density: Not applicable (see specific gravity)ffecthre Date: February, 1993 supersedes: February, 1990 MARSULEX MSDS 40tOE Page 5 of 9 MATERIAL SAFETY DATA SHEET Sulfuric Acid 9.PHYSICAL AND CHEMICAL PROPERTIES (continued) Evaporation Rate: Not applicable /Solubility: Miscible In all proportions ln water.Also soluble In alcohol.pH: 0.3 (1N solution at 25'C/78'F) 10.STABILITY AND REACTWITY S tability: Under.Normal Conditions: Stable, but reacts violently with water and organic materials with evolution of heat.Under Fire Conditions: Decomposes to form sulfur oxides(SQ,). Conditions to Avoid: Temperatures which may have a negative effect on the materials of construction used In equipment. Materials to Avoid: Contact with organic materhls (such as chlorates, carbldes, fulmlnates and plcrates)may cause~flre and explosions. Contact with metals may produce flammable hydrogen gaL When diluting, add acid to water.Do NOT add water to the acid.Hazardous Decomposition or Combustion Products: Toxic gases and vapors (e.g.sulfur dioxide, sulfuric acid p vapors/mists and sulfur trioxide)may be released when sulfuric acid decomposes. Hazardous Polymerization: Will not occur 11.TOXICOLOGICAI INFORMATION Toxicological Data:, Lote (oral, rat)2140 mg/kg L+(Inhahtion, rat)510 mg/re for 2 hrs Skin effects (rabbit): Severe Irritation Eye effects (rabbit): Severe irritation Carcinogenicity Data: Although there are reports linking exposure to sulfuric acid to cancer, this product h not ,dasslfled by NTP (National Toxicology Program), not regulated as carcinogenic by OSHA (Occupational Safety'nd Health Admlnistratton), and has not been evaluated by IARC (International Agency for Research on Cancer)or ACGIH (American Conference of Governmental Industrhl Hyglenlsts). See Section 3.Hazard Information, regarding Potenthl Health Effects (Long Term Exposure)for further discussion. ~Reproductive Effects: No Information Is available and no adverse reproductive effects are anticipated. ~Mutagenlclty Data: No information h,available and no adverse mutagenic effects are anticipated. <'reratogeniclty Data: No Information Is available and no adverse teratogenic effects are anticipated. Synerglstlc Materials: None known Effective Oats: February, 1993 Supersedes: February, 1990 MARSULEX MSDS 4i010E Page 8 of 9 NARSULH(,'ATERlAL SAFETY DATA SHEET Sulfuric Acid 12.ECOLOGICAL INFORMATION -Ecotoxlc Effects: Harmful to aquatic life in very low concentrations. May be dangerous if It enters water Intake;Rsh toxicity critical concentration 10 mg/L;7.34 mg/L/48 hrs-Lymneae Palustrls-0-100%mortality. 13.DISPOSAL CONSIDERATIONS ~Responsibility for proper waste disposal h with the owner of the waste.Work with the appropriate regulatory bodies to ensure complhnce with regulations. ~Consider the collection of residual sulfuric acid into containers for reclamation or disposal only If the container Is suitable to withstand the materhl.~Consider lnsltu neutralization and disposal.~Qean-up material may be a RCRA Hazardous Waste on disposal.~Provincial/State or local regulations or restrictions are complex and may differ from Federal regulations. ~The Information applIes to the materhl as manufactured; processing, neutralizing, use or contamination may make the Information tnapproprhte, Inaccurate or Incomplete. 14.TRANSPORT INFORMATION U.S.(Under DOT)/'hipping Name: RQ SWfurlc ackl Hazard Class or Division: 8 Product Identification No.(PIN): UN1830 Packing Group: II Canada (Under TC)Shlpplng Name: Sulphuric acid Classificatio(s): Qass 8 (9.2)Product Identlflcatlon No.(PIN): UN1830 Packing Group: II 15.REGULATORY INFORMATION ..A SARA Title lll HAZARD CATEGORIES AND LISTS p'cute (Immedhte) Health: Chronic (Delayed)Health: Fire: Reactivity: Sudden Release of Pressure;Yes Yes No Yes No Extremely Hazardous Substance (40 CFR 355, SARA Title III Section 302)CERCLA Hazardous Substance (40 CFR 302.4)'oxic Chemical (40 CFR 372.65, SARA Title III Section 313)Yes EffecUve Date: February, 1993 Supersedes: February, 1990 MARSULEX MSOS 4010E Page 7 of 9 MATERIAL SAFETY DATA'SHEET Sulfur/c Acid 15.REGULATORY INFORMATION (continued) Reportable Quantity (RQ)under U.S.EPA CERCLA: RQ=1000 Ib TSCA inventory Status: Reported/Included ~A~D Workplace Hazardous Materials Information System (WHMIS)WHMIS Classification(s): Qass E-Corrosive Qass D1A-Very Toxic WHMIS Health Effects Index: Acute Lethality-very toxic-immedhte Corrosive to animal skin WHMIS Ingredient Disclosure LIS: Confirmed A;Meets criterh for disclosure at 1%or greater.Reportable Quantity (RQ)under Transport Canada-TDG: RQ 5 lltres (or Kg)If lt represents a danger to health, life, property or the environment. 16.OTHER INFORMATION Additional Information and References 1.Envlro-TIPS Manual,'SWphurlc Acid and Oleum', Environment Canada, February 1S84./2.Weast, R.C.(Ed.),'CRC Handbook of Chemistry and Physics', 60th Edition (1S80)3.Sax, N.l.,"Dangerous Properties of Industrhl Materhls', 7th Edition (1989)4.ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices', 1S91-92 5.Slttlg, Marshall,'Handbook of Toxic and Hazardous Chemicals and Carclnogens", 2nd Edition, 1985 Revision Indicators: J a In the left margin Indicates a revhlon or addition of information since the previous Issue.ffeottlee Date: February, 199S SuporeodoL February, 1990 MARSULEX MSDS W10E Pagosofg NARSULB(, MATERlAL SAFETY DATA SHEET Sulfuric Acid 16.OTHER INFORMATION (continued) Legend: CAS 8 CERCIA CFR DOT EPA LC LEL MSHA NIOSH PEL PVC RCRA SARA STEL TCTDG TSCA TWA UEL-Chemical Abstracts Service Registry Number'I-Comprehensive Environmental Response, Compensation, and Uabllity Act-Code of Federal Regulations -Department of Transportation -Environmental Protection Agency-The concentration of materhl ln air expected to ldll 50%of a group of test animals-Lethal Dose expected to kill 50%of a group of test animals-Lower Explosive Limit-Mine Safety and Health Administration -National Institute'for Occupational Safety and Health-Permissible Exposure Limit-Polyvinyl chloride-Resource Conservation and Recovery Act-Superfund Amendments and Reauthorizatlon Act of the U.S.EPA-Short Term Exposure Limit-Transport Canada-Transportation of Dangerous Goods Act/Regulations -Threshold Umlt Value-Toxic Substances Control Act-Time-Weighted Average-Upper Explosive Umit J The information contained herein has been prepared by MARSULEX Inc.and Is offered only as a gukie to the handling of this specific material and has been prepared ln good faith by technically knowledgeable personnel. It Is not Intended to be aII-Inclusive and the manner and conditions of use and handling may Involve other and additional considerations. No warranty of any kind Is given or Implied and MARSULEX Inc.will not be lIable for any damages, losses, InJurles or consequenthl damages which may result from the use or relhnce of any information contained herein.EffeeUve Date: February, 1993 Superaedea: February, 1990 MARSULEX MSDS W10E Page 9 of 9

~'~e\~~I C~~e~.~~~7~~e C.~.I'~~~ei.~co~C'~ej ee C~I<<C'e.~ej 7)'~'I Ace'~~~C'~7'~c~~'e7 a~C'.~r I~~0~~e jA~7~~L I I'cjc'~'e jA C'.~ej'c~~~'~ed%oc Ea~~I I~~7A~7 C~C~I~C~e jx 7~~C~~'ejx~~~'e xx~c~r~C~C~C~e 7\~7~~~,~e 7%~e~'~~jA~~~ INSTRUCTIONS FOR COMPLETING SECTION I I ITEM 3 Tr Is form requires information on, the process streams rhlch contribute to this discharge. ENTER THE PERMIT NISIBER IN THE MX AT THE TCP OF THIS FORM.THE PEIbIIT NWBER CAN BE FOUND ON THE FRONT PAGE OF YOUR EXPIRING pEIpIIT.If this is a na>>or not previously permitted facility, then leave blank and a number<<ill be assigned.Enter outfall number in space provided for eacn page of Section II.For eben individual discnaroe point a separate set of Section il forms must be f I lied out.ITEM 3 PROCESS STREAMS CONTRIBUTING TO OISCHARGE: FOR EACH SEPARATE PROCESS PROVIOE THE FOLLOW'ING INFORMATION A.Enter tne name Of the prOCeSS uhlqn COntributeS tO thlS diSCharge. AISO prOVide the prOper SIC COde.B.Indicate tne yearly average process scnedule In hours per day and days-per year.C.Provide the process wastewater flow rate Infonaetion as requested based on your last I2 months of operations. Refer to unit code given In the left margin for the appropriate flow units.0.process production Rate-Certain permit limitations may be based on production rates.The production rates used to determine permit limits shall be represented by a reasonable measure of actual production of the facility, such as the production during the high montn of tne previous year, or the monthly averaqe for the highest of the previous five years, or otner reasonable measure as stated In applicable U.s.E.P.A. categorical rules and regulations. For neu sources or neu dlschargers, actual production shall be estimated using projected production. Record your production rates in the terms and units used in the applicable U.S.E.P.A. categorical rules one regulations for youl type of feel litye SEE INSTRUCTIONS ON REVERSE SIDE SECTlON I l PERMIT~ts11 0005827 NUMBER.:v GROUNDWATER DISCHARGE INR)RMATIDN As IS BE DISCHARGE FIEPI THIS OUTFALL DIRECTED TO BE GRCLBO OR GROLSDQTTRS2 (IF Mls CCtITIIIE TO ITBtl BJ Bs HAS A HBNLXIKOUXIICAL SBBTY OR ITS EOJIVALENT BEEN PERFORIEO OR IS THERE SLFFICIENT CJRREHT HtlROGKQICAL IHFCttWTICN AVAILABLE g REOQURED Q~HATER RESXRCES THIS DLISTIHI OR~DISCHARGE) IF YES ATTAOI A COPY CF THE REPCIITs Cs ARE YOU R STII41 AH EXBPTICN FRLBI SLttlllTI% A HYIROGIDUXIICAL REPORT LEKVAR RLAE R s (Q(PAGE Q)OR FRLBI GROLtEIWTEB KNITOII%IIEOUJRIBENIS LEGER ELLE Rs s (5)LPJGE Q)0F'nE PART 22 RLLKss IF YEs ATTAcH DOCLIENIS ANJ EXPLAIWTICN TO DMt9STRATK TIWT YOLII DISCHARGE IEXAD OUILIFY FOI AM~ONs Ds ARE YLXJ RBXESTIID A VARIANCE FRCN RULE 3Bs2Z6 (PJGE 19 (td%KIINATICN) OF BE HATER RESOLJEXS CCttllSSION PART 22 GRCLtGIWIKR RILEST IF YESs ATTACH QXH DOCLtEHIS AS IECESSARY TO OQQN$7INTK TIE NEED RTI A VARIANCE IN TBIBIS OF TIE CRITIRIA SPKIFIED IN RLAEV5sZ?10 (PJGKCF BE PART 22 RLIESs Es I,IST Alp, OEIIICAL SLBSTAtCKS WIOI ARE IN NICHIGAN S CRITICAL HATERIALS REGISTER TABLE P/LPAGE II)ANVCR UsSs KPA'S PRIOIITY ITXLLITANT LIST TABLE Y (PAGE 7)OR ANY OBER SLBSTAJCES %lot ARE cR twY BEcoE IILABIIQJs To BE BEBIQwTKD UBEs 0F TIE 6IIGLtEBwTER cR To TIE ILSLIC IEJILBI THAT ARE DISCHARGED OI EXPECTED TO BK DISCHIRGED TO BE GROLtElWTKILBY THIS FJCILIIYs ESTDWTK THE FINAL EFFLIENT COIEXIIIRATIOI AIO RECCRD ALL DATA IN ITEN 1 OF SECTIOI Il IH lHIS BCDILETs BE JPPLI CJJII'AY BE RKOJIRED TO DO AIDITIOWL IWSIK AIWLYSKSs QX YES p~Report Submitted 12/6/91.Q~S Pg X NOT APPLICABLK/BKLIEYED ABSENT Cl PRESENTi DATA IROYIBED IN ITTH 7 lTEM 6 As DISOIUEIK OWRACIBR I STICS BCO5 (FIVE DAY BIOOEIIICJIL OXYGEN DEHJjtO)'CCD (OKIIICAL aLYGEN IKIWIO)CCNBNBIATI Ol~5~0~18,~0~52 EXPECTED sssssswssssl SSSNSSC-~Uss c ass 1 lED/I 2 UO/I 3 COUNTS/100 tnl 4 S.U.5'F 5 LSS/DAY IOC (TOTAL OEANIC CARBON)JJBCNIA NITIOIEH (AS N)TOTAL SUSPEIKED SLLUN TIAL PICGPIOEJS (AS P)>>TOTAL RESICUIL OEJNINE DISSCQ%D OXIGEN FECIL LDLIRIBI BACTERIA'ntPBRABNK (SLttER)IEIPERATLIE (HINIBR)NDI~0.~02~0.~08 LLJ~LJ LJ~~LJ Bs OBER IWSTEIWTER OWRACIKRISTICS ~I u>u5~52~SM~P LXRE.1 GRAS 2 24 HOUR COllPOSITE 0 I L 4 G R E A S E LORI DE ATE I TOT A L I L~10.~9~80,~0 0 ID8~19 5.~0 1 0., 2 0~58 2 925.~0~8~0~0~1~52 1 5 2 1~61 1~6~1 2 2~2 REQJIRED IIFOEWTICN FOI SNIFACK IWTBR DIOIIA%ESs Analyses per J.B.Beauboeuf, Target Permit Effluent Limits List. INSTRUCTIONS FOR C(y(PLETING SECTION I I ITEMS 4 ANO 5 This tom requires Information on 4 specific outfall discharging to either the groundraters or the surface waters.ENTER THE PERMIT NISIBER IN THE BOX AT THE TCP OF THIS FORM.THE PERMIT NQd)ER CAN BE FOUNO ON THE FRONT PAGE OF YOUR EXPIRING PERMIT.It this is 4 ner or not previously permitted facility, then leave blank and 4 number rill be assigned.Enter the outtall number In the space provided for each Daae of section I I.For each Individual discharge point 4 separate set ot Section I I terms (items 4 ano 5)must be fl lied out.ITO(4 QROUhOWATER OISCHARGE INFOCMAT ION (OO NOT INCLUOE DEEP WELL INJECTION INFORMATION IN THIS ITEM>A.-O.The applicant shall address each of these parts If the discharge tron this outtal I ls to tne aroundrater. ITEM 5 EXISTING OR EXPECTEO (FOR A NEW OISCHARGE) WASTEWATER CHARACTERISTICS OF GRCUNOWATER CR SURFACE WATER DISCHARGE (OO NOT INCLUOE r LL INJ I N IN IN H A.The aDDI leant shall report available discharge data (real data for existing discharge or exoected data for 4 Drooosed discharge) for tne Dareneters as listed.These parameters shall be addressed for either 4 surface water discharge or as appropriate for e groundwater dlscnarge. For assistance in determining appropriate parameters 4 groundwater dlscharoe applicant may contact the Groundwater Ouality olvlsion, Pe(mits Section or the appropriate Groundwater ouallty olvlslon'5 Olstrlct otf Ice.The applicant shall report the sample type code best descglblng each reported place of data.see coding on the lett margin of this tore.It this outtall Is 4 su>face rater discharoe. the applicant must report quantitative data for each parameter Identified 4 an o v..ea oo m tov es a aa~a~.so:a ol st t ae~oaotv o ev esa e tlat l.a ao~a a ao st a steeve t t tal~aoolloatlo .B.If data ls available for other parameterS not listed above In A.or other parts ot this aDPlicatlon the applicant should report that data In the blank spaces provided In thl5 part.NOTES: I.Unit codes tor paraneters reported In parts A and 8 can be tound on the lett hand side ot this form.2.Grab sample shall be used to analyse tor pH, temoerature, total phenols, residual chlorine, oil and gre4se, and fecal coliform In 4 surface vater discharge unless other frequency-smnpl ~type analyses are avallabl~~See Glossary (page 48)tor detlnltlon ot grab sample.24-hour composite samples shel I be used to analyse tor Total B005, coo, Toc, Anmonla Nitrogen, and Total Suspended Solids In a 5urtaoe vater discharge unless other trequency-sample type analyses are aval labia.see Gloss4ry (page 48)tor definition of composite sawple.4.REPORTING OF INTAKE OATA.You are not required to report unless you vish to demonstrate your ellqlbl llty tor 4"net" effluent I imitation tor one ot'ore pollutants, that Is, an etfluent limitation adJusted by subtracting the average level of the pollutant(s) Dresent In your Intake vater.NpOES regulations allow net limitations only In certain clrclastances. To demonstrate your eligibility, report the avertx)e of the results ot analyses on your Intake rater (If your vater l5 tre4ted before use, test the vater atter It Is treated), and attach 4 separate sneer containing the tol loving tor eben pol lutant: (4)A 5taten>>nt that the Intake rater l5 drawn froh the body of vater Into which the dlsch4rge Is made.(Otherwise, you are not eligible tor net limitations.) Ib)A statement ot the extent to which the level ot the pollutant ls reduced by treatment of your wastewater.(Your limitations vill be adJusted only to the extent th4t the pollutant Is not removed.)(c)vnen apDllcable (for exampl~, when the pollutant represents 4 class of ccmpounds), 4 demonstration ot the extent to rnlcn the Dollutant5 In the Intake very physlc4!Iy, chemically, or biologically tran the pol lutant5 contained In your discharge.(Your limitations ri I I be adJusteo only to the extent that the Intake pollutants dO ndt Vary fraa the dlSCharged DOI lutentS~)If you have tro or more substantially indentlcal outta(15, you mav request permission fran your permitting authority to smnple and analyze only one outtall and 5ubmlt the results ot the analysis tor other substantially ~dentlqai OutfallS.If yaur requeat IS granted by the permitting authqrity, On a Separate Sheet attaChed tO the application term tdentify vhlch outfall you did test, and describe vhy the outtal la which you did not test are substantially identical to the outfall which you dld test.36 SEE INSTRUCTIONS ON REVERSE SIDE SECT1ON lI PERMIT~MI OQOS827 NUMBER OOD o PRIORITY POLLUTANTS AND ADDITIONAL INFORMATION FOR SURFACE WATER DISCHARGE ONLY THE FOLI&IINtt RSXESTKD IIHRWTION~s AIXJIESSED SEJM QJIFACE HATER DISDWJXIKRS>> EJTE)NBf USK DISOwXIERS 2JBLL PROVICE KPPKCIKD VALIKS FCR THE IXJANflTATIVE AND IXWLITATIVE INFORIWTICN REIXKSTED BEIJJI>>Ae IS THIS FACILllV A PRIMARY IMXJSTRY?(RKFBI TO TABIE IA PJGK+(IFW,GOVO)(IF YS GOTOB)Be INDICATE TYPE CF PRIIWIY IMXJSIRY AS LISTED IN TABJE IA PA%Q.ICCNTIMK HIIH C.)Ce GOES THIS OUIFALL DISCHARGE CNTAIK ANY PROCESS HASTKHATKR?(IF Mr GO TO E)(IF YES>GO TO D)De IWICATK NIICH Gt'JHS FRACTICNS MJST BE TESTED FOR>>(RKRR TO TABLE IA PJVK JII)IDIEI FCR EACH Gt'JHS FRACflON OtKCXKD>EAOI SPECIFIC ORGANIC TOXIC POUJJTANT HIIHIN EACH FRACTION t$5J BE ANALYZED FOR (SEE TABLE I IA PAGE 92~IN ADOITI0I>ALL PRII>>ARY IIClJSTRY APPLICANIS HITH A PROCESS IWSTKHATKR DISCHARGE ggJ PROVIDE OSWTITATIVE IWTA FCR EARTH TOXIC POLJJJTANT IH lAKE I I IA PAfE~~e RKcRD AIJ.DlrA oN F0Yts PROVIDED (ITEM 7)IN THIS Boozer.(CNTIMK HITH E K BKIJBI)LEC WR Q~>>em Analysis Per Q er>dere>re J.B.Beauboeuf Target Permit P re,e Effluent Limits PESTICIDE Ke IF JKg, QRFJcE HATER DrsowRGK APPLIGANT (PRIIwRY 0R$Kc06NY IMxrsTRY)> RKGARKLEss OF THE IVPE OF DISCHJJYIK>r EM'R IWS REASON TO BKUKVK TIWT ANY POIJJJTAHT LISTKD IN TAKE IIA ANO IVA PAGES 4JL9X ls DISCHARGED FR0t JHY OJIFAL4TIC IXJWTITATIYE DATA ggjf BK PRKIVIWh RECRD ALL DATA 01 PORC PROVIDED (ITKH 7)IN 1HIS$00ZkT>>Fe IF Nf QRFJCK lWTKR DISCJWRGE APPLICANT (PRIIWIY OR SEQÃCNIY IIKtJSIRY)> RKGJJOXKSS OF TYPE OF DISCNVIGK> IMEfs OR HIS REISCN TO BKUEVE AHY POIJJJTJHIB USTED IN TAKE VA PAGE~ARE DrsftwXM FR01 ANY tJJfFAJJ.TIE APPUCJItf rrrKL(DESCRIBE REASONS I0t TIE POIJJJTJHT BEI16 PRKSBIT JJKJ PROVIDE JJII AVAILABLK QOWTITATIVE DATA>>REcRD ILL DATA 01 F0ws IROYIKED (ITBI 7)IN THls BOOLEY>>Ge AIJ.SLRFACE IW18t DISCHNXIE APPUCJNIS (PRIMARY AW SKCOIJJtf IHIXISlRIKS) 0R fgFAcrtNKs 2>4>f~lllrcJKJ$4%%wxY AcKrrc AcID (2>4>M)J.JI,WIRIDKJxtsPINwxr PR0 Ic (srLttKx, 2, rr, 5, TP)~Pr>TRIKMJXKPIEMN (T~KP I cR HBIAaacl4%1RK Nfr (AIJ DlTA F0t Tl%AlotK ISJST BE GIMRATKD IIIMI STAwJRD aw mcAL CJUIYIAT10t ProCBXNKS) OR l0l$ts OR HA5 REASCN TO BELIEVE THlr TCKD 1$0t HIY BE PRKSBIT IN T%1R DISCHARGE>> RKP0IT>>XJAUTATIVE DATA>GE%RATKD HfrCH tgiKD A SCRKKHlw PwCKDIJIK wT TKD HITH AJWLmCJL STAwARDS, FOR z.a, I 8,-TKIRJCJKJJIKXJIM~IOXIN (TCD)e RECISID ALL DATA 0l F0Yts PROVIDED (ITBI 5 IN THIS BOOLEY>>IF IIE QJIFACE HATER DISCJWRGE APPLICJWf XMlo OR IWS RKISCN TO MUEVK%lr BIOIJXIICAt TOXICITY TESTS HERE HADE IN ll%LAST lINEE (5)YEARS OI ANI CF TIE APPLICANT 5 DISOWNIKS OR ON A RKCEIVIW HATBt IN RKLAT10I TO A DISCIWSKs PROVIDE THts IIRNHAT104 AS AN ATTAOIKÃf TO TH15 APPUCAT101>> X IF A CNRACt thtCRAT0IY CR KKYIILTIW Fl&PBRÃIED JJN'OF T%AMAVSKS RKIXJIRKD BY THIS APPLICAT101> PRCNIDE TIE Nt%AMJ AKKNESS OF EAOI LAB0IATDIY OR F IIII AW TIE AWLYSES PKRFIR%D AS AN ATTAKJI%HT OF THIS APPLICATION>> 1.>>00 VIXI DISOWEIK ANY OIIER TOXIC CR IILXNIIXJS DKHICAL SlaSTJNCKS Wr LISTED IH TAKES IY PAGE tt AW IIA TINOAI VA PIPES~~IF VK5>TISH IOBIflsY TIE IJKMICAL QSISTAWKS AO ESTIHATE TIE FINIL KFFLIKHT C0CBIIRAT10IS ~QJ>>HIT THIS IIARQTICN AS AN AITAOtKtlT IO'HIS APPUCATION> Q rrrr rr>u oar/ear>>re remrr.N/A a PRESKHf/DATA ls ATTAIMD wr APPUCABLdBKLIEYKD ABSBIT N/A 0 PRESENT/DATA IS ATTADED wr APPUCJBLFJBKUEVKD ABSENT N/A Q PRESENT/DATA IS ATTADED g wr AppucABLE Q APPuCABLE?'SKE AITADED.Q wr AppucABtz g]APPLICJBLe'SKE ATTADND QX wr JppucABtz APPLICABts/SKE ATTAKJND INSTRUCTIONS FOR C04PLETING SECTION I I ITEM 6 This form requires Information on a soeciflc outfal I discharging to the surface>>stere. ENTER THE PERMIT NUMBER IN THE BOX AT THE TCP OF THIS FORM.THE PERMIT NWBER CAN BE FOUND CN THE FRONT PAGE OF YOUR EXPIRING pERHIT.It this is a ne>>or not orevlously permitted facility, then leave blank and a nuroer>>ill be assigned.Enter the outfall number In the space orovlded for each page of Section II.For each Individual discharge point a separate set of Section II, Item 6 forms must be filled out.ITEM 6 PR I ORITY POLLUTANTS ANO ADO IT I ONAL INFOPHAT I ON NOTE: NOTE: lf you have tro or more substantially Indentical outfal ls, you may request permission frcm your permitting authority to samole and analyze only one outfall and submit the results of the analysis for other substantially Identical outfalls.It your request 15 9ranted by the permitting authority, on a seoarate sheet attaChad to the application form Identify rhlch outfall you did test, and describe my the outfalls rhlch you did not test are substantially Identical to the outfall rhlch you did test.40 CFR Part I22.2l(g)(8), Friday, Abri I I, l98S, provides for a Small Business Exemption from the reporting of quantitative data for organic toxic pollutants and toxic pollutants as required by Pert l22.2I(g)(7)(ll)(A) or 122.2I(g)(7)(lil)(A). A.K.These partsare self-explanatory and do not require further Instructions. Simply go through each part and do as Indicated. and E.-J.0.Several Industrial categories and subcategories have been exemoted frtm submitting data on certain GC/MS Fractions (40 CFR Part l22, Vol.48, No.64, Friday, April I, lgBS, Notes I, 2, and S).~Revle>>the folio>>lng list to determine>>bather your facility qualifies to be except free reporting GC/MS (Gss Chrcnetogrsphy/ Mass Spectroscopy) Fractions. GC/MS Fraction Testing and Reporting Exemptions Text I I e ill I Is Industry-All four GC/HS organic fractions In the Greige Hills Subcategory. -Pesticide fraction In el I other suboarts of this Industry.Ore Hlnln and Oressl Indust-Volatile, base/neutral, and pesticide fractions In the Base and Precious Hetals Subcategory. -All four GC/HS organic fractions In all other subcategories of this Industry.Gun and Uood Chemical~Industr pesticide fraction in the Tali Oil Rosin Subcategory and the hos(n Based Oerlvatlves Subcategory. -pesticide and base/neutral fractions in~li other subcategories of this industry.Pul and Paper Indust-Pesticide fraction In Paoergrsde Sulfite subcsteqorles (suboarts J and 0).-base/neutral and pesticide fractions ln oeink suboart 0, olssolvinq Kraft subpart F, and Paperboard from vast<<Paper Subpart E.4-Volatll~, base/neutral ~pesticide fractions In the OCT 8)cached Kraft SubOart N, Seelmhcmical Subparts 8 and C., and Nonlntegrated Fine Paoers Subpart R.'c-Acid, base/neutral, and oestlclde fractions In Fine 4)cached Kraft Subosrt I.oissolvlng sulfite Pulo Suboart K, Ground->>OOd Fine Papert SubOart 0~Narket OleaChed Kraft Subpart 0, TISSue frae UaStepaper Subpart T, and NOnlntegrated QSSue Papers Subpart S.'team Electric Po>>er aslant Indust Hater Fly Ash and Oottt4e Ash Transport Mater process>>astestreams 38 o i'~~~'l I~~~~~',~~'~C'.~~O'~'I~~'~O'~~~'I~)I~;r'~Ol~~I)'~'I'~~l~'I%)I)~~~~~~'~~'j)B E~~I I I I'I~)~I~~~\'I~o~~I~~I~1~'~'~II Jj~~I~~I~)~'~~I~~~~~~'I~r~I~1~I~((I.~C~~I~1'~I~~''I~1~I~~I~1'~I~~~~~C~I~~I~~I~1~I~~I'~I~1~I~~I e'~~'~I~~~~C'~~1~I~~I e)~I~I~~I~~~~~I~1~I~~I~~II~I'~~~~~~~~~~rj.~~~'~e)I~'IW~'~~I)l S>;I~~~~~~I II~~~~~~~~~~~~~~~~~ INSTRUCTIONS FOR CCMPLETIHG SECTION I I ITEM 7 This form Is to be used by both Surface and groundvater applicants to record Information on any Hlchlgan critical material, E.P.A.priority pol lutant, or hazardous substance In vhlch this app I l cation requires data to be provided.This vould Include any chemical substance fran tne Hlchlgan Critical Materials Register ITabl~IV), the E.P.A.Priority Pollutant Listing (Table V), or Tables I IA-VA vhlon I latS OrganlC TOXIC POI lutantS, Other TOXIC POI lutantS, COnVentlOnal and HcnocnVentlonal POI lutantS and HaZardOuS Substances. ITEM 7 CRITICAL MATERIALS, PRIORITV POLLUTANTS AHO/OR HAZAROOUS SUBSTANCES IN THE DISCHARGE Material I, 2, 3...8 A.List thi name ot the chemical substance (critical material, priority pollutant, or hazardous substance) fran Tables IV, V and I IA-VA as reoulrad In tne box mich you cheeked In A.I-3, above.Enter each chemical substance's paneeter number as listed In Tables IV, V and IIA-VA lf Provided.B.Provide the average concentration ot the chemical substance naned In A.Indicate the sample type used and the number of analyses made to prerlde the concentration data for the chemical substance nmned In A.C.Provide the maximum concentration and determine the mass loading ot the chemical substance nmmzd In A.HOTES: I.2.It only one analysis uas made for a chemical substance then record that data as a maxisxzs value.It more than one analysis has been made tor a chemical substance then provide an average value ot those analyses and the maximus value~This Section II, Itea 1, Oata Sheet provides space for recording data for 8 chemical substances IMaterlals). Additional space tor recording of data for more than 8 Materials can be made by making copies of this Item 1 Oats Sheet as needed.It ls also important to use a separate set of Oata Sheets fot each appllcabl~reporting reculrmaent as listed In A.l 3.and tor each outtali~3.Rater to the lett margin tor the code number representing the smapl~type used and the appropriate unit codes. Loci<heed Analytical Services INDIANA MICHICAN POWER COMPANY SAIVIPLE ANALYSIS

SUMMARY

PACKAGE FOR VOLATILE AND SEIVII-VOLATILE ORGANICS,-PESTICIDE/PCBS, CHLORIDE, NITRATE/NITRITE, SULFATE, FLUORIDE, CYANIDE, IVIETALS, AND MERCURY LOG-IN NUMBER: QUOTATION NUMBER: L1009 Q331 620 DOCUMENT FILE NUMBER: 1229485 ~toe/rheed elL'/a~a 7rllce~rv"l.s)'a r~-r"<<~~~~~~Lockheed Analytical Services 975 Kelly Johnson Orive Las Vegas, Nevada 891194705 Phone: (800)3614220 Fax: (702)361~February 4, 1994 Mr.Rocky Beem Cook Nuclear Plant 1 Cook Place Bridgeman, Ml 49106 RE: Log-in No.: Quotation No.: Document File No.: L1009 Q331620 1229485 The attached data package contains the results of analyses on samples that were submitted to Lockheed Analytical Services on December 29, 1993.The samples were received at 5'C.SUMIVIARY ANALYSIS STATEMENT: Inorganics All ground water samples were received in good condition, on December 29, 1993.All samples were analyzed within the method-specific holding times.The method blanks were free of contamination. All Internal Quality Control were within acceptance limits with the following exception: The matrix spike recoveries for barium and selenium were slightly outside of acceptance limits.The acceptable recovery of the Laboratory Control Samples supports that the analytical systems were operating within control limits.The reporting detection limit for nitrite was raised to 0.50 mg/L for sample S.Sewage Plant Eff.(L1009-4)due to interferences from chloride.Organics Method 8260 All calibrations and quality control criteria were met with the following exceptions: All samples were analyzed, initially within holding times but failed surrogate recovery QC limits.The samples were reanalyzed one day beyond the method specified holding time and all samples met surrogate recovery QC limits.Tentatively identified compound searches were performed on all submitted samples.Only the reanalyses are reported. COOK NUCLEAR February 4, 1994 PAGE 2 Method 8010/8020 All calibrations and quality control criteria were met with the following exceptions: The matrix spike and matrix spike duplicate precision for 1,1-dichloroethene exceeded the QC criteria although all percent recovery criteria were met.Data quality is not effected.Method 8270 All samples were extracted and analyzed within the method specified holding time.All initial and continuing calibration criteria were met.Bis(2-ethylhexyl)phthalate was detected in the method blank at 1.3 ug/L.There was no other contamination detected in the method blank.Percent recoveries for all surrogate compounds was within QC limits for all samples analyzed.A laboratory control sample (LCS)and laboratory control sample duplicate (LCS DUP)was prepared and analyzed with this set of samples.The percent recovery criteria for all spiked compounds was within the QC limits as was the relative percent difference between the two.The response for bis(2-ethylhexyl)phthalate in sample TRANS.CATCHBASIN exceeded the calibration range in the initial analysis.The sample was reanalyzed at a dilution of 1:4 and all compounds fell within the calibration range.Both sets of results are reported.Method 8080 AII samples were extracted and analyzed within the method specified holding time.All initial and continuing calibration criteria were met.No contamination was found in the method blank.Few of the surrogate spike recoveries were within the QC limits due to an apparent spiking solution problem.Data quality is not effected since all percent recovery criteria were met for the laboratory control sample and laboratory control sample duplicate. No target compounds were detected above the reporting detection limit and there was no dilution or reanalysis performed. If you have any questions concerning the analysis or the data please do not hesitate to contact James L.Jordan, (702)361-3955.ext.289.Release of this data report has been authorized by the Laboratory Director or the Director's designee as evidenced by the following signature. ncerely, James L.Jo dan Client Services Representative JL J/at cc: Client Services Document Control Department ~Wc/rheed Lockheed Analytical Services 975 Kelly Johnson Drive Las Vegas.Nevada 89119-3705 Phone: (800)582-7605 Fax: (702)361%146 February 17, 1994 Mr.Rocky Beem Cook Nuclear Plant 1 Cook Place Bridgman, Ml 49106

Dear Rocky,

Per your request during our phone conversation this morning, the following is an explanation of the procedure used for the determination of the non-standard organic compounds in your groundwater samples.The samples were analyzed using instruments that were set up for standard methods 8260 and 8270.A few of the compounds on your lists of analytes are not standard method 8260 or 8270 compounds. Once the samples are analyzed and a chromatogram was obtained for the samples, all peaks that were present in the samples that did not correspond to one of the calibrated compounds were investigated further.This involved taking the mass spectra obtained from these peaks and comparing the spectra to an NIST library of spectra.This library contains approximately 52,000 known mass spectra.The mass spectra of the additional analytes of interest to you are contained within this library.None of the non-standard analytes were detected in any of your samples.For the next quarters round of sampling, we are endeavoring to obtain the standards for these compounds so that they will be calibrated for in the analyses of those samples.If you have any further questions or if I can be of any further assistance, please do not hesitate to call me at (702)361-1626 ex.289.'ncerely, James L.rdan Project Manager cc: M.Butler I~4~4 g I g~~~I r~I Ir~'ll~I'll'I'I~..I'.~I'I~I'I I I~I'~~~~'~, I I I~I'I I~I I~~~I I'I~~~I~I'I'I r'II I.I~I.II I I I~~~I I~I'~~~I~I'I I'.~~I~~~~~~~~~~~~~I~I~~r~~~I'~~~~~~~~~~I~'~r~I I~~~I~~~'~~ a i~a~~~~~~~~I~I I I'~'~I~~~~I~I I I~'~~~~'I I'~I I'I I~'~I'~~~I I I~I~I I~~I I~I I I'~I~I~I I'I I I~I I I I'I~~~~~~~.I I~~I I~I I'I I I'I~~I I I I~~'I I'I I~~~~~~I~~~I I~~~'~I~~~~I I~ VOLATILE ORGANIC ANALYSIS RESULTS GC/HALL ANALYSES USING EPA METHOD 8010 lin m I ID: TR Da oil: 2-D Date Anal zed: 04-JAN-94 Matrix: WATER Anal tical Batch¹: 122093-801020-0-3 LAL ml ID: L1 D R iv:-D Dilution Factor: 1 QC Batch ID: 122093-801020-0-3 BCM BFB rro R v r 114 92 Limi 65-125 60-120 Constituent Dihl r ifl r m han hlrm hn Vin I chloride Brompm ethane hir hn Trihlrfl rm hn 1 1-Dichloroethene Meth lene chloride ran-1-Dihl r hn 1 1-Dichl r han Chloroform 1 1 1-Trichloroethane r n r hl ri 12-Dihl r hn Trichloroethene TCE 1 2-Dichloro ro ane Brm ihlrm hn 2-hl r h Ivin I her cis-1 3-Dichloro ro ene trans-1 3-Dichloro ro ene 11-Trihl r hn Ter hlr hn P Dibromochloro methane Chlorobenzene Brmfrm 1 1 2-T r I r h n 1 3-Dichlorobenzene 1 4-Dichlorobenzene 1 2-Dichlorobenzene Concentration Iyg/L)<0.50<3<6<4<0.5<0.5<0.5<2 Reporting Detection Limit IL 0.5 0.5 0.5 Data Qualifier(sl LOCKHEED ANALYTICAL SERVICES A V sJ VOLATILE ORGANIC ANAlYSIS RESULTS GC/PID ANALYSES USING METHOD 8020 li n m I ID: TR D II: 2-DE Date Anal zed: 04-JAN-94 Matrix: WATER Anal tical Batch¹: 122093-801020-0-3 LAL m I ID: L1 D R iv: 2-DE Dilution Factor: 1 QC Batch ID: 122093-801020-0-3 TFT BFB rro Re ver 94 95 Limi 70-120 75-120 Benzene T'I n Constituent Concentration IL 0.52 Reporting Detection Limit IL 0.5 Data Qualifier s hir n n Eth I Benzene m-X lene-X I n 1-'n 1 4-Dichlorobenzene 1 2-Dichlorobenzene <2<2 LOCKHEED ANALYTICAL SERVICES h4 VOLATILE ORGANIC ANALYSIS RESULTS GC/HALL ANALYSES USING EPA METHOD 8010 lin ml ID: TR-A D II'-DE Date Anal zed: 04-JAN-94 Matrix: WATER Anal tical Batch¹: 122093-801020-0-3 LAL m I ID: L1 D R'v: 2-D Dilution Factor: 1 QC Batch ID: 122093-801020-0-3 BCM BFB rr R v r'/120 86 Q Limi 65-125 60-120 Constituent Di hlor iflu r m han hlrm hn Vin I chloride Bromomethane hlr hn Trihlrfl rm hn 1 1-Dichloroe hen Meth lene chloride rn-1-Dihlr hn 11-Dihl r h Chloroform 1 1 1-Trichloroethane r n r hl ri'l2Dihlr hn Trichloroethene TCE 1 2-Dichloro ro ane Brmoihlrm hn 2-hlr hlvinl hr cis-1 3-Dichloro ro ene trans-1 3-Dichloro ro ene 1 1 2-Tri hl r h n Ter hlor h n P E Dibrornochlorome hane Chlorobenzene Br m f rm 11-T r hlr hn 1 3-Dichlorob nzene 1 4-Dichlorobenzene 1 2-Dichlorobenzene Concentration (yg/L)<0.50<3<6<4<0.5<0.5<2 Reporting Detection Limit/L 0.5 0.5 0.5 Data Qualifier(s) LOCKHEED ANALYTICAL SERVICES nr.Vv VOLATILE ORGANIC ANALYSIS RESULTS GC/PID ANALYSES USING IVlETHOD 8020 li n m I ID;TRS-A AL ml ID: 1 D II-DE D R iv: 2-D Date Anal zed: 04-JAN-94 Matrix: WATER Anal tical Batch 4'22093-801020-0-3 Dilution Factor: 1 QC Batch ID: 122093-801020-0-3 TFT BFB rr R vr 97 Q Limi 70-120 75-1 20 Benzene Tiun Constituent Concentration IL 0.53 Reporting Detection Limit/L 0.5 Data Qualifier s hl r n n Eth I Benzene m-X lene-X in 1-Dihl r n n 1 4-Dichlorobenzene 1 2-Dichlorobenzene <2<2 LOCKHEED ANALYTICAL SERVICES 06 ~~i~~~a~~o~~~~~~.~~..~~.~o~~~~....~~~~I'~~'~e.I~'>e~~~~0 s.)~I>o~~~~~~I~~~J~~~'~~~I~~~~~~~~~~~~~~~..~~..~~~~~~~~~~~~~~~~~~~~~~~~o~~~~s~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~-~~~~~!~~~~ VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Client Sam le ID: TRS LAL Sam le ID: L1009-41 Page 2 of 2 Constituent Dibromochloromethane hlr nzn Eh I nz n m-X lene o-X lene r n Brom f rm 1 1 2 2-Tetrachloroethane 1 3-Dichlorobenzene 1 4-Di hlor nz n 1 2-Dichlorobenzene Concentration IL<5<5<5<5<5<5 Reporting Detection Limit IL Data Qualifier s LOCKHEED ANALYTICAL SERVICES VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 TENTATIVELY IDENTIFIED COMPOUNDS Client Sample ID: TRS Date Received: 29-DEC-93 Matrix: WATER Analytical Batch: 011094-8260-F2 LAL Sample ID: L1009%1 Date Analyzed: 114AM-94 Dilution Factor: 1 QC Batch ID: 011094-8260-F2 Tentatively Identified Compound Estimated Concentration Iyg/L)(10 Retention Time Iminutes)0.00 Data Qualifierls) LOCKHEED AIVAL YTICAL SERVICES ~0 J I+a a~~I~~~-~~I II'.~-~~~~.....~~I~~~~~~.~~I.~I~I~~~~~~a~'~~~I~~~~~~~~~~~~~-~~~~~~s~~~~~~~~I~~-~~~~~~'~~-~~~.s~~~~~~~~~~~~~~~~~~~~~~I 0~~~~~~~~I~~~~~~~~~~I~~~~ ~i~~J~~~~L J~~~~I~-~~'--~~~~~~~~a~~~~~~~~~~~~~~~~- VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 TENTATIVELY IDENTIFIED COIVIPOUNDS Client Sample ID: TRS-QA Date Received: 29-DEC-93 Matrix: WATER Analytical Batch: 011094-8260-F2 LAL Sample ID: L1009%3 Date Analyzed: 114AN-94 Dilution Factor: 1 QC Batch ID: 011094-8260-F2 NONE Tentatively Identified Compound Estimated Concentration Iyg/L)(10 Retention Time (minutes)0.00 Data Qualifier(s) LOCKHEED ANAL YTICAL SERVICES 20 SElVllVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Iin m I ID: TR Date Collected: 28-DEC-93 Matrix: WATER An I i IB h¹: ill 4-7-8 QC Batch ID: 8270-SEMI VOLATILES-3964 LA m I ID: 1-2 Date Received: 29-DEC-93 Dilution Factor: 1 D xr 4-AN-4 Date Anal zed: 11-JAN-94 P 1 f 2 SURROGATE REC VERY 0/2-Fluoro henol Phenol-d, Nitrobenzene-d, 2-FIuorobi hen I 24-Tribr m h n I p-Ter phenyl-d,4 41 26 59 55 99 QC Limits 21-100 10-94 35-114 43-1 1 6 1-12 33-141 Phenol n i n Concentration L<10 Reporting Detection Limit L 10 D Q bis 2-Chloroeth I ether 2-hlr hnl 1-Di hl r nz n 1 4-Dichlorobenzene Benz I alcohol 1-Dihl r n n 2M h I h n I bis 2-Chloroiso ro I ether 4-Meth I henol N-Ni r-Di-n-ro I min Hx hlr hn Nitro benzene Iso horone-Nir h n I 24Dimeh I h n I Benzoic acid bis 2-Chloroethox methane 4Dihl r hn I 1 4-Tri hl r nz n Na hthalene 4-Chloroaniline Hx hlr in 4-hl r--m h I h n I 2-Meth Ina hthalene Hexachloroc clo entadiene<10<10<10<10<10<10<10<10<10<50<10<10<10<10<10 10 10 10 10 10 10 10 50 10 10 10 10 10 LOCKHEED ANALYTICAL SERVICES 4 v ~e~~J~I~~:~~.I~I'~~.~~~~~~~~I I~~~~~~~~~e~~~I~~~~~~~~-~~~~~~~~~I~~~0~~~~~~~~~~~~~~~~~o~~~e~~~~~~e~~~~~~~~'~P VOLATlLE ORGANIC ANALYSlS RESULTS FOR ANALYSES USING IVIETHOD 8270 TENTATIVELY IDENTIFIED COIVIPOUNDS Client Sample ID: TRS Date Received: 29-DEC-93 Matrix: WATER Analytical Batch: 011194-8270-B LAL Sample ID: L1009-25 Date Analyzed: 11-JAN-94 Dilution Factor: 1 QC Batch ID: 8270-SEIVIIVOLATILES-3964 Unknown Unknown Tentatively Identified Compound Estimated Concentration (yg/L)100 20 Retention Time (minutes l 6.44 30.26 Data-Qualifier(sl LOCKHEED ANAL YTICAL SERVICES 31 ~i~P~~J~~P I~'~-~~a~I'.-~.~~~-...~~~.~~)~~~P I~~a~~~~P.~a~)P~~~~\I~~~'~~~~~~~~~~~~~~~~~~;:~~:.~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~s~~~~~~~~~~~~~~~~~~~I~~~~~~~ ~k~0 l i~~~~I P~~)~~'~I~~~~~..~~~~~~'~~~'~~~~~~~~~~~~~e~~~~~~.~~~~I~~~~~~~~~~~~~~~~~I~~a-~~'~I~~~~0~~~~~~~~ VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8270 TENTATIVELY IDENTIFIED COMPOUNDS Client Sample ID: TRS-QA Date Received: 29-DEC-93 Matrix: WATER Analytical Batch: 011194-8270-8 LAL Sample ID: L1009-27 Date Analyzed: 29-DEC-93 Dilution Factor: 1 QC Batch ID: 8270-SEMIVOLATILES-3964 Unknown Unknown Tentatively Identified Compound Estimated Concentration (yg/L)100 Retention Time (minutes)5.28 6.44 Data..Qualifier(s) Hydrocarbon Unknown Hydrocarbon Hydrocarbon Hydrocarbon 20 29.97 30.26 31.98 32.94 33.86 LOCKHEED ANALYTICAL SERVICES PESTlclDE ANALYSES RESULTS BY GC/ECD USING METHOD 8080 FOR COOK NUCLEAR PLANT Clien Sam le ID: TR Da e Colle ed: 28-DE-9 Date Extracted: 04-JAN-94 Matrix: WATER Anal tical Batch¹: 012094-8080-A-1 LAL m I ID: I 1-17 Da e Receive:29-JAN-4 Date Anal zed: 21-JAN-94 Dilution Factor: 1 QC Grou ID: 8080 PEST/PCBS 3965 SURROGATE RECOVERY oo TCMX DCB 52'C Umits 60-1 50 60-150 A-BHC B-BHC-BH D-BHC Constituent Concentration /L<0.05<0.05 Reporting Detection Limit/L 0.05 0.0.05 Data Qualifier(s) HEPTACHLOR ALDRIN HEPTA HLOR EPOXIDE G-CHLORDANE ENDOSULFAN I A-CHL RDANE 4 4'-DDE 4 4'-DDT DIELDRIN ENDRIN ENDOS LFAN II 4 4'-DDD ENDRIN ALDEHYDE ENDO LFAN L FATE METHOXYCHLOR TOXAPHENE PCB-1016 PCB-1221 PCB-1 2 PCB-1242 PCB-1248-PCB-12 4 PCB-12 0 TECHNICAL CHLORDANE MIREX TCMX-tetra-chloro-meta-xylene DCB-Deca-chloro-biphenyl <0.05<0.05<0.05.5<0.1<0.1<0.1<0.1<0.<5<0.1 0.05 0.05 0.05 0.0.1 0.1 0.1 0.1 0.1 0.<0.1 LOCKHEED ANALYTICAL SERVICES 5' ~I I~~~~~I I I~0~~-~e~~.I II'..~-.~~~~~'~~e~~'~I~~~~~I~~~~~~~~~~I~I I~I~I'~~~I~~I I I~I~I~~~~~~~~'I~~~~~~~~~~~~~~~~~~I~I~I~I~I~~~I~I~~~~~~~~~~'~~~~~~~ ~~~..~~~.::::~~~~~'~~~~R5%gggg~gpss~%%~55%~ggg g$gg~55%~55%~gpss~55%R55%RE%R55%g$gg~gpss R5%R%%~55%g$@g 555%R55%R5%~~~~~~~~~~~I~~I~~~~I~~I I~~~~~~I~~~~~~~~~~'I~~~~~'~~~~~~~~~I I~~~~~~~~~~~~~~~~~I~~~I~~I~~I~~I~~I I~~~~~I I~~~~~~~I~~~~~~I~~I~~~~~.o:~~~'~~~~~~~~'~'~~I'~~I'~~~~~'~'~~~'~'~~~'~~~~~'0~~~~'lIll'~0~~II'I~'~'I'~'~l' METALS RESULTS Client Sam le'ID!'TRS-QA LAL Batch ID(s): 1220 im Date.Collected: 12-28-93 Date Received: 12-29-93 Matrix:, round;water. '0 469095-040-3N .<<?,')'y Co'nstitu ants Aluminum Antimon Arsenic Barium Be ilium Boron Cadmium Chromium Cobalt Co er Iron Lead Ma nesium Man anese Mercu Mol bdenum Nickel Selenium Silver Sodium Thallium Tin Titanium Vanadium Zinc-."Method 6010 6020 6020 6020 6020 6010 6020 6020 6020 6020 6010 6020 6010 6020 7470 6020 6020 6020 6020 6010 6020 6020 6010 6010 6020 Concentration" im ILl<0.20<0.060<0.010<0.20<0.005 0.27<0.005<0.010<0.050<0.025<0.10<0.003 17 0.027<0.0002<0.20<0.040 0.0078<0.010 890<0.010<0.20<0.10<0.050 0.022 Reeportlng Detection" Umlt lm ILl 0.20 0.060 0.010 0.20 0.005 0.20 0.005 0.010 0.050 0.025 0.10 0.003 5.0 0.015 0.0002 0.20 0.040 0.005 0.010 5.0 0.010 0.20 0.10 0.050 0.020 Data~QualWer(s) N N Date'.~'-A'nal ed,N 01-20-94 01-27-94 01-27-94 01-27-94 01-27-94 01-20-94 01-27-94 01-27-94 01-27-94 01-27-94 01-20-94 01-27-94 01-20-94 01-27-94 01-07-94 01-27-94 01-27-94 01-27-94 01-27-94 01-20-94 01-27-94 01-27-94 01-20-94 01-20-94 01-27-94?0':;;:;.L'ALcr.""S" le'1D)L1009-14 L1009-14 L1009-14 L1009-14 L1009-14 L1009-14 L1009-14 L1009-14 L1009-14 L1009-14 L1009-14 L1009-14 L1009-14 L1 009-14 L1009-14 L1009-14 L1009-14 L1009-14 L1009-14 L1 009-14 L1009-14 L1009-14 L1009-14 L1009-14 L1009-14 Comments: LOCKHEED ANALYTICAL SERVICES 0~..~:-~~~~~~~~I~~~~~~~t gg RR Qiittg Qiittg gpitiig Qiittg~~~~~~~~~I~~~~~t t~~~~~~~~~~~~~~~~NIIRÃ8~~'~~'~~~~~~~~~~~~~~~~'~~'~~~'~~~' GENERAL CHEMISTRY RESULTS Client Sam le ID: TRS-QA LAL Batch ID(s): 1229 im Date Collected: 12-28-93 Matrix: round water Date Received: 12-29-93 PO¹69095-040-3N Constituent Fluoride.in m IL Chloride.in m/L Nitrate-Nitro en, in m/L Nitrite-Nitro en, in m IL Sulfate.in m/L Ammonia.Nitrogen, him IL Total Cyanide.in mg/L Method 340.2 300.0 300.0 300.0 300.0 350.1 335.2 Result 0.31 20 0.90<0.012 2200 3.4<0.020 Reporting Detection Limit 0.15 0.01 6 0.01 7 0.01 2 0.59 0.050 0.020 Data Qualifieris) D(1:10)Date Anal zed, 01-24-94 1 2-29-93 1 2-29-93 1 2-29-93 12-29-93 01-05-94 01-03-94 LAL Sam le ID L1 009-2 L1 009-2 L1 009-2 L1 009-2 L1 009-2 L1 009-6 L1009-10 Comments: LOCKHEED ANALYTICAL SERVICES 66 GENERAL CHEMISTRY QC DATA

SUMMARY

LAL Batch}D(s}: 1229 im QC'Sam le Anal ses-Constituent Client Sample, ID LAL Sample ID Date Analyzed Reagent Blank Duplicate Precision (%RPD}Matrix" Spike.Recovery (%}Fluoride, in m/L Chloride, in mg/L Nitrate-Nitrogen, in m/L Nitrite-Nitro en, in m/L Sulfate, in m/L Ammonia-Nitrogen, in m/L Total Cyanide, in mg/L TRS TRS TRS TRS TRS TRS TRS L1 009-1 L1 009-1 L1 009-1 L1 009-1 L1 009-1 L1 009-5 L1 009-9 01-24-94<0.1 5 1 2-29-93<0.01 6 1 2-29-93<0.017 1 2-29-93<0.01 2 1 2-29-93<0.059 01-05-94<0.050 01-03-94<0.020 0.2 0.1 107 91 93 96 96 122 94 N b lt The RPD cannot be c'omputed. because the sample or the duplicate concentration was below the Detection Limit.Comments: LOCKHEED ANALYTICAL SERVICES 6n .".Halliburton NUS X5FJ++C 0 R P 0 R A T I 0 N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbeiis Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Report No.: 00018939 Section A Page I CLIENT NAME: ADDRESS: ATTENTIOH: INDIANA MICHIGAN POWER COMPANY OHE COOK PLACE BRIDGMAN, MI 49106-0000 MS.JEHI LEWIS-CHEMISTRY DEPT.HUS CLIENT NO: 0663 0020 WORK ORDER NO: 55830 VEHDOR NO: 05411000 Carbon Copy: SAMPLE ID: HUS SAMPLE NO: P.O.NO.: TURBIHE ROOM SUMP 27476 P0259284 69034-040-3H DATE SAMPLED: 30-DEC-93 DATE RECEIVED: 05-JAN-94 APPROVED BY: Kieda, Chuck TEST LN CODE DETERMIHATIOH RESULT UNIT 1 1730 2 AHAW 3 1130 4 1590 5 AALW Sulfate, Turbidimetric (as S04)Sodilsllt Total (Na)Chloride (as Cl)Solids, Dissolved at 180C Atuminun, Total (Al)51 mg/L 6.3 mg/L 11 mg/L 140 mg/L 0.97 mg/L COMMENTS: A;"';Halliburton NUS CORPORATION LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Report Ho.: 00018939 Section A Page 2 CLIENT NAME: ADDRESS: ATTENTION: INDIANA MICHIGAN POWER COMPANY ONE COOK PLACE BRIDGMAN, MI 49106 0000 MS.JENI LEWIS-CHEMISTRY DEPT.HUS CLIENT HO: 0663 0020 WORK ORDER NO: 55830 VEHDOR HO: 05411000 Carbon Copy: SAMPLE ID: NUS SAMPLE NO: P.O.NO.: TURBINE ROOM SUMP 27476/FILTERED P0259285 69034-040-3N DATE SAMPLED: 30 DEC-93 DATE RECEIVED: 05'JAN-94 APPROVED BY: Kieda, Chuck TEST LN CODE OETERMI HAT ION RESULT UNITS 1 AALF Atuainua, Dissolved (At)~0.3 mg/L COMMENTS:. L'Hallibullton NUS%1K++++C 0 R P 0 R A T I 0 N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Repor t No.: 00018939 Section A Page 3 CLIENT HAME: ADDRESS: ATTENTION: INDIANA MICHIGAN POWER COMPANY ONE COOK PLACE BRIDGMAH, MI 49106-0000 MS.JEHI LEWIS-CHEMISTRY DEPT.NUS CLIENT NO: 0663 0020 WORK ORDER HO: 55830 VENDOR HO: 05411000 Carbon Copy: SAMPLE ID: NUS SAMPLE NO: P.O.HO.: TURBINE ROOM SUMP 27503 P0259286 69034-040-3N DATE SAMPLED: 31-DEC-93 DATE RECEIVED: 05-JAN-94 APPROVED BY: Kieda, Chuck TEST LH CODE DETERMINATION RESULT UH ITS 1 I 730 2 ANAW 3 1130 4 I 590 5 AALW Sulfate, Turbidimetric (as SO4)Sodiun, Total (Ha)Chloride (as Cl)Solids, Dissolved at 180C Atuminun, Total (Al)53 mg/L 6.0 mg/L 10 mg/L 130 mg/L 0.98 mg/L COMMENTS: "'.Halhburton NUS imper+++C 0 R P 0 R AT I 0 N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 ,January 18, 1994 Report No.: 00018939 Section A Page 4 CLIENT NAME: ADDRESS: ATTENTIOH: INDIANA MICHIGAN POWER COMPANY ONE COOK PLACE BRIDGMAH, MI 49106-0000 MS.JEHI LEWIS-CHEMISTRY DEPT.NUS CLIENT NO: 0663 0020 WORK ORDER HO: 55830 VEHDOR NO: 05411000 Carbon Copy: SAMPLE ID: TURBINE ROOM SUMP 27503/FILTERED HUS SAMPLE HO P0259287 P.O.NO.: 69034-040-3N DATE SAMPLED: 31-DEC.93 DATE RECEIVED: 05-JAN-94 APPROVED BY: Kieda, Chuck TEST LN CODE DETERMI HAT ION RESULT UHI TS 1 AALF Aluninun, Dissolved (AI)0.3 mg/L COMMEHTSt

dL'Halliburton NUS waar C 0 R P 0 R A T I 0 N LABORATORY ANALYSIS REPORT"NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Report Ho.: 00018939 Section A Page 5 CLIENT NAME: ADDRESS: ATTENTION:

INDIANA MICHIGAN POWER COMPANY ONE COOK PLACE BRIDGMAH, MI 49106-0000 MS.JEHI LEWIS-CHEMISTRY DEPT.HUS CLIENT HO: 0663 0020 WORK ORDER HO: 55830 VENDOR NO: 05411000 Carbon Copy: SAMPLE ID: HUS SAMPLE HO: P.O.NO.: TURBINE ROOM SUMP 27506 P0259288 69034-040-3N DATE SAMPLED: 01-JAH-94 DATE RECEIVED: 05-JAH 94 APPROVED BY: Kieda, Chuck TEST LN CODE DETERMIHAT I ON RESULT UNITS 1 l 730 2 AHA'W 3 1130 4 l590 5 AALW Sulfate, Turbidimetric (as S04)Sodiun, Total (Na)Chloride (as Cl)Solids, Dissolved at 180C Atuninua, Total (Al)52 mg/L 5.6 mg/L 10 mg/L 130 mg/L 1.6 mg/L COMMENTS: h: HallibulIton NUS>mrs+++C 0 R P 0 R A T I 0 N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Report Ho.: 00018939 Section A Page 6 CLIENT NAME: INDIANA MICHIGAN POWER COMPANY ADDRESS: ONE COOK PLACE BRIDGMAN, MI 49106-0000 ATTEHTIOH: MS.JEHI LEWIS-CHEMISTRY DEPT.HUS CLIENT NO: 0663 0020 WORK ORDER HO: 55830 VEHDOR NO: 05411000 Carbon Copy: SAMPLE ID: TRUBINE ROOM SUMP 27506/FILTERED HUS SAMPLE HO: P0259289 P.O.NO.: 69034-040-3N DATE SAMPLED: 01-JAN-94 DATE RECEIVED: 05-JAH 94 APPROVED BY: Kieda, Chuck TEST LN CODE DETERMINATION RESULT UNITS 1 AALF Atuntram, Dissolved (At)0.2 mg/L CNNENTS: '.Halliburton NUS~%F1 CORPORATION LABORATORY ANALYSIS REPORT NUS LA8ORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684.January 1B, 1994 Report No.: 0001B939 Section A Page 7 CLIENT NAME: ADDRESS: ATTENTION: IHDIANA MICHIGAN POWER COMPANY ONE COOK PLACE BRIDGMAN, Ml 49106-0000 MS.JENI LEWIS-CHEMISTRY DEPT.HUS CLIENT HO: 0663 0020 WORK ORDER NO: 55030 VENDOR NO: 05411000 Carbon Copy: SAMPLE ID: HUS SAMPLE HO: P.O.HO.: TURBINE ROOM SUMP 27509 P0259290 69034-040.3N DATE SAMPLED: 02-JAH 94 DATE RECEIVED: 05-JAH-94 APPROVED BY: Kieda, Chuck TEST LN CODE DETERMI NAT ION I RESULT UNITS 1 1730 2 AHAW 3 1130 4 l 590 5 AALW 6 I490 7 l 700 Sulfate, Turbidimetric (as SO4)Sodiun, Total (Ha)Chloride (as Cl)Solids, Dissolved at 1BDC Atuninun, Total (Al)pH Specific Conductance at 25C 51 mg/L 5.9 mg/L 10 mg/L 140 mg/L 1.5 mg/L 7.6 300 umh os/cm COMMENTS: '.Halliburton NUS++C 0 R P 0 R A T I 0 N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Report No.: 00018939 Section A Page 8 CLIENT NAME: ADDRESS: ATTENTION: INDIANA MICHIGAN POWER COMPANY OHE COOK PLACE BRIDGMAN, Ml 49106-0000 MS.JENI LEWIS-CHEMISTRY DEPT~HUS CLIENT NO: 0663 0020 WORK ORDER No: 55830 VEHDOR HO: 05411000 Carbon Copy: SAMPLE 10: HUS SAMPLE NO: P.O.NO.: TURBINE ROOM SUMP 27509/FILTERED P0259291 69034 040 3H DATE SAMPLED: 02-JAH-94 DATE RECEIVED: 05-JAH-94 APPROVED BY: Kieda, Chuck TEST LH CODE DETERMINAT IOH RESULT UNITS 1 AALF Atuninun, Dissolved (At)0.3 mg/L COMMENTS: " Halliburton NUS%1 18+++C 0 R P 0 R A T I 0 N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plea, Suite 200 5313 CampbeHs Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Repor t No.: 00018939 Section A Page 9 CLIENT NAME: ADDRESS: ATTENTIOH: INDIANA MICHIGAN POWER COMPANY ONE COOK PLACE BRIDGMAHt MI 49106 0000 MS.JEHI LEWIS-CHEMISTRY DEPT.HUS CLIENT NO: 0663 0020 WORK ORDER HO: 55830 VENDOR HO: 05411000 Carbon Copy: SAMPLE ID: HUS SAMPLE NO: P.O.NO.: ABS POND CCMP.P0259292 69034-040-3N DATE SAMPLED: 31.DEC.93 DATE RECEIVED: 05-JAH 94 APPROVED BY: Kieda, Chuck TEST LN CODE DETERMINATION RESULT UNITS 1 I 730 2 ANA'W 3 1130 4 1590 5 AALW Sulfate, Turbidimetric (as Sodiua, Total (Na)Chloride (as Cl)Solids, Dissolved at 180C Atuainua, Total (Al)S04)110 mg/L 28 mg/L 9 mg/L 210 mg/L 0.33 mg/L COMMENTS: .4i.Halliburton NUS%1K'++C 0 R P 0 R A T I 0 N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pit tsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Report No.: 00018939 Section A Page 10 CLIENT NAME: ADDRESS: ATTEHTIOH: INDIANA MICHIGAN POWER COMPAHY OHE COOK PLACE BRIDGMAN, MI 49106-0000 MS.JEHI LEWIS-CHEMISTRY DEPT.NUS CLIENT Ho: 0663 0020 WORK ORDER HO: 55B30 VEHDOR NO: 05411000 Carbon Copy: SAMPLE ID: NUS SAMPLE HO: P.O.HO.: ABS POND COMP./FILTERED F0259293 69034-040-3H DATE SAMPLED: 31-DEC-93 DATE RECEIVED: 05-JAN.94 APPROVED BY: Kieda, Chuck TEST LN CODE DETERMI HAT ION RESULT UNITS 1 AALF Atuninua, Dissolved (At)0.099 mg/L COIMEHTS: '.Halliburton NUS+~~~~C 0 R P 0 R A T I 0 N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (4'12)747-2684 January 18, 1994 Report No.: 00018939 Section A Page 11 CLIENT HAME: ADDRESS: ATTENTIOH: INDIANA MICHIGAN PSlER COMPAHY OHE COOK PLACE BRIDGMAH, Ml 49106-0000 MS.JEHI LE'LIIS-CHEMISTRY DEPT.NUS CLIENT HO: 0663 0020'IQRK ORDER NO: 55830 VEHDOR HO: 05411000 Carbon Copy: SAMPLE ID: HUS SAMPLE NO: P.O.HO.: ABS POND COMP~P0259294 69034-040-3N DATE SAMPLEDI 01.JAN.94 DATE RECEIVED: 05-JAN.94 APPROVED BY: Kieda, Chuck TEST LN CODE DETERMINATION RESULT UNITS 1 l730 2 ANAII 3 1130 4 l590 5 AALU Sulfate, Turbidimetric (as S04)Sodiun, Total (Ha)Chloride (as Ct)Solids, Dissolved at 180C Atuninun, Total (At)110 my/L 30 my/L 10 my/L 210 mg/L 0.35 my/L CCMHENTS: .".Halliburton NUS~i@'++C 0 R P 0 R A T I 0 N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Report No.: 00018939 Section A Page 12 CLIENT NAME: INDIANA MICHIGAN POWER COMPANY ADDRESS: ONE COOK PLACE BRIOGMAN, MI 49106-0000 ATTENTION: MS.JENI LEWIS-CHEMISTRY DEPT.NUS CLIENT HO: 0663 0020 WORK ORDER NO: 55830 VEHDOR NO: 05411000 Carbon Copy: SAMPLE ID: ABS POND COMP./FILTERED NUS SAMPLE HO: P0259295 P.O.NO.: 69034-040-3N DATE SAMPLED: 01-JAN 94 DATE RECEIVED: 05-JAN.94 APPROVED BY: Kieda, Chuck TEST LH CODE DETERMINATION RESULT UNITS 1 AALF Atuninua, Dissolved (At).0.10 my/L CINMEHTSt '.Halliburton NUS~%fE+++~C 0 R P 0 R A T I 0 N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Report Ho.: 00018939 Section A Page 13 CLIENT NAME: ADDRESS: ATTENTION: INDIANA MICHIGAN POWER COMPANY ONE COOK PLACE BRIDGMAN, MI 49106-0000 MS.JENI LE'WIS-CNEMISTRY DEPT.NUS CLIEHT NO: 0663 0020 WORK ORDER HO: 55830 VEHDOR HO: 05411000 Carbon Copy: SAMPLE ID: HUS SAMPLE HO: P.O.NO.: ABS POND COMP.P0259296 69034-040-3H DATE SAMPLED: 02-JAN.94 DATE RECEIVED: 05 JAH 94 APPROVED BY: Kieda, Chuck TEST LH CODE DETERMIHATION RESULT UNITS'I I730 2 ANAW 3 I130 4 I 590 5 AALW 6 I 700 Sulfate, Turbidimetric (as SO4)Sodiun, Total (Na)Chloride (as Cl)Solids, Dissolved at 180C Atuslnua, Total (Al)Specific Conductance at 25C 100 31 10 190 0.5 400 mg/L mg/L mg/L mg/L mg/L thos/cm COMMENTS: "" Halliburton NUS%1gJ'+C 0 R P 0 R AT I 0 N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 1B, 1994 Report Ho.: 0001B939 Section A Page 14 CLIENT NAME: ADDRESS: ATTEHTIOH: INDIANA MICHIGAN POWER COMPANY OHE COOK PLACE BRIDGMAH, Ml 49106-0000 Ms.JEHI LEWIS-CHEMISTRY DEPT.NUS CLIENT HO: 0663 0020 WORK ORDER NO: 55B30 VENDOR NO: 05411000 Carbon Copy: SAMPLE ID: NUS SAMPLE HO: P.O.NO.: ABS POND COMP./FILTERED P0259297 69034.040-3H DATE SAMPLED: 02-JAH-94 DATE RECEIVED: 05 JAN 94 APPROVED BY: Kieda, Chuck TEST LH CODE DETERMI HAT ION RESULT UNITS 1 AALF Aluainun, Dissolved iAI)0.072 mg/L COMMENTS: "'alliburton NUS~lP'~>~CORPORATION LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Report No.: 00018939 Section A Page 15 CLIENT NAHE: ADDRESS: ATTENTION: INDIANA MICHIGAN POWER COMPANY OHE COOK PLACE BRIDGHAH, Nl 49106-0000 NS.JEHI LEWIS-CHEMISTRY DEPT.HUS CLIENT NO: 0663 0020 WORK ORDER NO: 55830 VEHDOR NO: 05411000 Carbon Copy: SAMPLE ID: NUS SAMPLE NO: P.O.NO.: ABS POND COMP 66998 P0259298 69034-040-3H DATE SAHPLED: 03-JAM-94 DATE RECEIVED: 05-JAH.94 APPROVED BY: Kieda, Chuck TEST LN CODE DETERNINATIOM RESULT UNITS 1 1730 2 AMAW 3 I130, 4 1590 5 AALW 8 l 700 Sulfate, Turbidimetric (as SO4)Sodius, Total (Ha)Chloride (as Cl)Solids, Dissolved at 180C Atuainua, Total (Al)Specific Cohductance at 25C 110 28 10 190 0.5 410 mg/L mg/L mg/L mg/L mg/L moos/cm COMMENTS: "" Halliburton NUS%%TE I++C 0 R P 0 R AT I 0 N LABORATORY ANALYSIS REPORT NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pit tsburgh, Pennsylvania 15205 (412)747-2580 FAX: (412)747-2684 January 18, 1994 Report No.: 00018939 Section A Page 16 CLIENT NANE: ADDRESS: ATTENTION: INDIANA HICHIGAN POWER COHPAHY ONE COOK PLACE BRIDGHAN, HI 49106-0000 HS.JEHI LEWIS-CHEHISTRY DEPT.NUS CLIENT NO: 0663 0020 WORK ORDER HO: 55830 VENDOR NO: 054'11000 Carbon Copy: SAMPLE ID: HUS SANPLE HO: P.O.HO: ABS POND COHP 66998/FILTERED P0259299 69034-040-3H DATE SANPLEDI 03-JAH-94 DATE RECEIVED: 05 JAN-94 APPROVED BY: Kieda, Chuck TEST LH CODE DETERNI NAT ION RESULT UNITS 1 AALF Aluninun, Dissolved (At)COHNEHTSr 0.088 mg/L SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I PERMIT~MI 0005827~OO E EM Ae LOCATION OF DISCHLRGE S,~RECEIVIIO HATER (IE.GAOWDQTER CR N4%OF MLFACE WA SA NI TAR 2t'BS PON D.~SW t~SEJ i, SOI0I i~06.\I~06 5, SSE~19 W DISCHARGE LOCATION SCHEDULE C I DO YOU Dl SOLLRGE SEASCNALLY (IF IOJ CONTIIAK IO EI De IF YESa LIST DISONKE PERIODS M)o/DLY Ion/DAY FLOW RATE WASTEWATER JXBKSiQQE 1 CONTACT COOUNQ 2 NONCONTRCT COOLWQ 3 PROCESS 4 SANITARY 5 STORM WATER llHUUcQDE 1 MQY 2 MQD 3 QPD[TEN EI IhtD APPLI CATION RATE, Fo TYPE OF HASIBGLTER DISCHLKE Go DISCNRK SOERLE (YE/RLY AVER/GE)NA INI/Hle HIe/DAY IH,/NN.~~u~~u~.'W 0)IF'4~~w u LJ NOLNS/DAY~4 equi~H, DISCHHLGEFUSIRATE ase on a-arne TOTAL YEARLY DAILY HINIISSI DAILY ILLXWPI 13 505 0 2 037 2 Jo HAXDQI DESIQI DL5CNAX FIDI RATEe Ao IEI YOLI USE HATER TREAIIRNT AIDITIVES 1D TREAT YOIR DISCNK4.(IF HG.ccNTDAE To ITBI 3)Se NIK FBCTICNp 110 OKNCAL CStOSITIlS OF lfC5E AISI ITIVB4 DESIGN o.o6o le GtKZJQL.Calcium H ochlorite for I I TIE$0(DSII DISCHVSIE FUSI RATE TO SE AUllER IZED IH PEBIITe o.o6o TREATMENT ADDITIVES 1 MQ/I 2 UQ/I Ca WIC AMI ACCRESS OF IWAFACARERS CF TMSE AISITIVESP VAN WATERS AND ROGERS, INC.1600 NORTON BUILDING SEATTLE, WASHINGTON 98104-156 De EXPKIED D ISCHLRK CBCEHIRATICN OF AID IT IVES a HIHIISPI WITS AVIRAGE aEE~LNITS HAXIISSI WITS QXE~axK~,~0 LJi~LJ J~M3~LJ sane we*Total Residual Chlorine 0 LJ, 0 ACDITIYE wte ADDITIVE HL/K Ea DO 511 TlKIT 1%DINAR TO RBOltE AISIITIVEST Fs Y6IAT IS TIE RBIVAL EFFICIBCY Ale DISTR%FRBSESCY2 ACOITIVE VIE I RBBVAL INSo/DAY DLYS/W., LJ G, AS AN ATTAOPEIIT TO THIS APPLICATICN PRESIDE SPECIFIC HJtNALIAH CR AQILTIC TOXICDUDICAL DLTA CR RERREHCE NHICH ARE AVAIIAILE AHD l%TSPLATIBI CN TIE RATE OF DEWADATICH OF TIE PIEXICTS RSI EKH ACOITIVEi b1SDS Attached Calcium Hypochlorite is added to the mixed liquor and is used up prior to discharge. INSTRUCTIONS FOR COCPLETING SECTIOI II ITEMS I ANO 2 This fom requires Information on the facility's dlscnarge location, discharge scnedule, volume flow rate and voter treatment additives.ENTER THE PERMIT IAP(B\R IN THE BOX AT THE TOP OF THIS FCIOI.THE PERMIT NIP(BER CAM BE FOUNO OM THE FRONT PAGE OF YCUR EXPIRING PERMIT.If this Is a ne>>or not previously permitted facility, then leave blank end s number will be assigned.Enter tne outfall ncxxaar In space provided for escn page of section II.For coon Individual discharge point a separate set of Section li forms must be filled Out.ITEM I DISCHARGE LOCATION SCHEOULE A%)FLOH RATES A.Enter the location of dlscnorga, this should Include quarter-quarter section, quarter section, section, town, snd range.B.List name of receiving voter (lf surface water discharge). C.Indicate vnether (scil)ty discharges on a seasonal basis.O.If yes.list discharge periods.E.Provide'the land appl)cation rates used or expected to be used in terms of Inches per hour, hours per doy, snd Inches per week.Indicate the type of wastewater to be discharged from this outfall.Refer to the rostevoter type code given In the lett margin.More thsn one code moy be applicable. G.Provide the average nurser of hours per dov In which the facility discharges treated wastewater ond the total number of days per year in vnlch tha dlscnsrge occurs.H.Provide current (fram the lost l2 months)or expected flow rates ss requested. Refer to unit code divan In the left margin for the appropriate flow units.HGY-million gallons per year)MGO-million gallons par day)GPO-gallons per dsy.I.Provide tne maximum discharge flow rate which you rent to have authorized within the permit.N0TE: For NPOES permits onlY.the use of such a flow rate vill not place an actual limit restriction on the flow but vill be the flow rote used to develop effluent limits.Also,>>nen the Monthly Operating Reports are reviewed by Ccmpllance staff It vill help thea to determine if any nev or increased uses might have occurred at the facility.J.Provide the design flow for this specific outfall discharge (e.g.batch treatment system flow~packaged treatment system flow.or sane other finite treatment system flow), ITEN 1 vATER TREATMENT AOOIT IVES A.Indicate vnether dlscnsrge Is treated with conditioners, inhibitors, oc microbiocide. If not, continue to Item 3.B.Give name.function, and chemical composition of additives used.C.Give name and address of the manufacturer(s) of the additives used.O.Indicate expected mlnlmcxe, average and max)meso discharge ccncantratlons of the additive(s) for this discharge~E.Indicate wnetner you treat the dischorge to remove the sddltlvelsl before discharge of wastewater. F~Indlcote the reaovsl efficiency of each additive fran the vastevatec'nd the discharge frequency of each additive to the surface voter or groundvater. G.N0TE: lt Is the responsibility of the applicant to supply the product Information ss requested In this Iten s.Information requested but not supplied may result In the application being returned to the sap)Ident for canpletlon. 32 VAH MATER.'>i~ROGERS I i(C.SA I.EIHEF T REPORT'"JLJHBF R'7'J i IS DS i'iQ: PG03 J.O~=" ECTIVE'!ATE: OF/2"/93.>6 DIJ(.s'.r',,Al C IUi'(HY POCi~ll 0 R X TE 6 I<AHIJI!4 lk PAGE: 00%VERS IOH: 00~)(3 R DER NO: P R(3I3 HQ vAN WATI".RS h ROGERS X HC., SLJ BSX D I A RY QF LING VAR i".>3.00 CAR I I L(3H P(3 IiHT KX RKLAHD<206>889-.i400 WA 98033 Ei(E RGEHCY AS>8 X 8>TAHCE I'3 R Ei(E RGENCY AS, T STAHCE X O'VOLV X HG CIHFiR ICAL S CAI L-(".HEI'lT REC<800>42>4-9300 I=O R V IC Q (3 I J C T A H I3 S!'.I E S:r.H F O R N A T I (3 H CONTACT YOLJR LOCA(..VAN WATERS b, ROGER.>BRANCH OFF ICE AT VWhlk SOUTI(.I3EHI3~'L9-'i89-03~ 1~OUTH P-Hll IH P RQ I3LJCT NAIVE: CALC ILJH HYPOCI II OR I TE 6 RAHLJI A R H.>i!8'"r:: P G 0:3 1.0 C A l C I UH i-I Y P 0 C I-I l.Q R X T E 6 R A HULA R l)A>E: rD I T X (3 N: 1'A DE HARE: i.,'l-I C i I i-r I'i i i E/8 Y N: '~~0/'l 93 now CALC IL)i(HY POCHLO R I TE (i RA)'IL)L A i<CAL l-IY P 3, P T T'i Cl..(3 R,.".Hll(JCLO R, RE PA K,.:A P P XT C IIEIIXCAL FAHIL Y: I-IY POCI-ILO R X TE F(3 f~iilJLA:!:A<(3CI..>2 CAB HLJH BE R: 0 0 7 7 7 8-5 4-'IJ, 8~DOT SHI P P I HG HAHE: CALC I UH HY PQCI-ILO R I TE, HY D RATE D IJ~S~DOT HAZARD Cl.ASS:.'r, J.<OX X D XZER>"-;I J I)S T.i3 I A R Y R I 8 K: i'I/A I.n.N L J V J3 I=.R: LJN2880 A("., I<IH(3 8>ROlJ P: XX:.~Q R TA Ill'=QI JAH T T T Y::L 0 L I38/4~-l<6 I;Hf)DESCRI P T I QH: CAL.C ILIA i I Y PQCHLOR X TE, HYDRATED, CLASS'3., UH2880, PA(.i<".I'IG>8 RQIJP I I, RA, X HOG (;Q l3E PAGI=.r l 38~

VAH MATERS 6 ROGERS XHC.is>>TI:RXAI SAr-ETY I3ArA Sl-IELT I'-'.E"">r'". I'LJHI3FR: 97 J"'-:I;.'i'I:): P60310"-'Fr EC!".VE.".)ATE: ()b/23./93 G CALC IUD HY P(3CI-IL(3 RITE L'r RAHLJLA R PAGE: 002.VERSXOH: 004 ORDER HO: PROD HQ SECTXQH 1.-PflYSXCAI... DATA 3(31I...XHR P(3XHT 6 7i~>0 AN I-l(3: POR DENSITY (AXR=-J.): ')PECIFXC GRAVITY (H2O=X): 'PH rJF SQI IJTXQHS: FREEZXH(3/HFLTXHG POIHT: Br)LUBXLXTY (AEXGf!T%):H MATE(2 DEC(3VPQSES e zen C N/A H/A ALKALINE H/A G/L e 2r C!3EH DI i'('OLL)HE%VOI..AT X l E: VAPOR'(>RESSlJRE: EVAPORATION RASE: I.IEAT OF S(3I IJTXON: APPEARANCE AHD ODOR: WHXTE P(3WI3ER WXTH Sl XGHT 65-~>7 i.BS/(3U.FT.H/A H/A N/A SLXGHTI..Y EXOTHERHXC CI.ILO R I NE 0 DO R SEC;I(3H;"-INGREDIENTS

.RXAI CA((3IUiI JJYP()(.",HI QRITE<~~5%AVAXI A8l E CHLORINE>IIERT<XHCLUDES 5..>-1.0%HQXSTURF)PERCENT 65 3iJ SECTXQH 3-FIRE/EXPLOSXOH HAZARD DATA;>I"I l>(3XHT (I";ETH(3D IJSI=D>: Ni",)id I".FI..AIIHAI)I..E LXHITS XH AXR (%BY VOLUHE)'.'=l..:-iH/A J JEI,..: N/A""'T'lO>LJXSI-IXH(."-.

I(I=DIA;MATFR ONLY!SilOTHERING XHEFFECTXVE-PRODUCT SUPPLIES OWN QXYGEH'~Fr:,-'.I.. F..RE I IGHTIHG PROCEDURES: RE FIGHTI.-",iRS JUST WEi'iP.HXOSII/IISIIA APPROVI':D, PRESSLJRE[)EJ'IAND SEl F-CQHTAIHED I R A I I'I I H(r A P PA I'FLATUS VJ I TH FLJLL FA("E P I ECE F(3 R I OSS I BLE LX PQSU Rl'" TQ i iAZ'.IR DOUG GAS>ES, r'-Pr=.;;.,HI3 E:<PLOS ION'<AZ>-'>P.I3$:!I r)SE'>!""s l'G>0!s!>." i'>&XI!IL') i JX i GI H GAS>!CQII1!13 Hlr R>>IH'(tcL>(TURL~ RFP!.)I>7';IUilBER: 771 HA'r-031.0 i" FFr" r 7.'iF)ATE'r>>/21/r!3)AH WA7ERS 6 ROBE!RS 3:HC i:iATERXAI. SAr-iETV DATA SHI.=I.=, PAGE: 003 Vt;RSXOH: 00<,.rl)~rr r i~i CAI.CXLJH IHVI'()CI<L(3RXTE GRAHULAIE ORt)ER No: PROD NO SECT X(3H~)-IIFAI Tl-I HAZARD DATA TOXIC:t TV DATA: LC.:r0 XHHALATXOiN: L}350 DERHAL: S)KTH/EYE IRRTTATXOH: l,.t)50'f.NGEBT't(3N: FIB}I, LC50 (l ETIIAL CoiHCFHTRAT3:ON ): (RAT)HQ HQRTAI ITY 8 3~r HG/I ('J.HR)(RABB:tT)>1000 il6/l<6 B)EE S)ECTXOH 5 SEE SECT ION 5)TLH r))h I-IR.: 3.0-'J.PPH (.,L(')SS IFICATI(3N: XNHALATXOH: IRRITATING BI<IN: Sl.XGHTl V rOXIC Sl<lN/EYE: CORROBXVE IHGI=BTION: SLXGHTLY TOXX(P AQUATIC: HXGHLY TOXXC SFCT X OH 5-EFFI=CTS OF OVF REX POSU RF I S CI}FHX CA}L I STED AS A CA RC IHQGFiH OR POTENT I AL CARCXHOGEH'? NTP-HQ XARC-NQ ()S)HA--Ho eIFDXC.'r ...CoiQDXTXOiis t)EidEiRr"66r<r'"Tl:"D BY l':Xf O.LJRE: H(3iHF.I<iH(3lJN Pl.-".RHXBBX BLE CXPASLJRE L3:HT.TS: r Iol ll ESTABLISHED l3Y OSI IA 0 R Ac('I"I FOR Tl'3 Is P R(3 I3UCT I I rr)6 XHTERNAI.;)ERHXSSXB}..t>> lXPOSLJRE i..XHXT<Xr EL>: 3.HG/CLJ.II., a-HOUR TWA (TXHE lJEIGHTED AVERAGE);.I}6/("U~H.STEL (SH(3RT-TERH EXPOSIJRF LXHXT>.ACLJTE: THI-IALATIOH: XHHALATIQN OF (.,AL(.,XLJH I-IYPOCI-ILORXTE t)UST AHD DEPOSITION OF I'ARTXCLES XN THE RFSPXRATORY 'l RACT CAN I I=AD TO XRRXTATION OF THF.TISSUE A>>D cAusF A VARxETv AF EFFECTS.THFsF EFFFcTs ARE DEPFiNDCHT OH coHcFN-RA I.ON AND.'.iii(.LUDI.: iJ PI IXR Rf.-:SP IRAT(3RY TRACT T RRITATI(3N, iiABAI.CQNGES-TXOH, COUGIIIHG, BORE TIIRAAT, LARVN63:TIS AHf)$}IORTNEBS t)F BREATII.IH i)Pl;.RAT XoiN()!JI IERE THE iRE r'E I I I Gl I COHCEN 7 RAT I AHS.3}=RESP I RA BLE PART I ClJ-I,A fES r PULHOHARY EDFi}A (FLUXD Irl THE LIJHG)HAY BE PRODLJCED~IF HOT)Rl:,:".i")TFD,iHHEI3XATI".LY, PIJI H(3i'iARY i:".I3}."HA (AH)E LIFE THRFATl=il:iHG. (INCE"")'Dl)CT i 3 I:I Gr f>>AII!!!,. 1R P'H'RTICLES f)F Es'P.RABLE.'."".T.:.F'".)Rt.NOT'"iE.LL'r:."iJC(3UHTF RF ir, '~l-i".'.A i L.."(5>..ROf>L" i"(~>>IM,.)s i>A6E~004"FRSZQH: 00'f-:>'-L{3X{ i4 i I>'"'GCI lLi3ik i" i R nr--";I Q;'.Rr;D:>O g p e~~g sac w p>~>e+~a'qawy>~p'~y>ge See rw r>r>~.ill..'.'.~>.,u>~>WC).>.>.iaaf.-:. >w>>"I>,""i0'>>t.G>l'ii I"I<.f QF>;:;->l i,X!Jil!3Y;(3(;ill,.(3R'iTE:3(JST 'lX"ld'!E I.YEB~EVEN A IIXHUTF>'i'IG(JHT F(3R A":)ii(3RT")URATXQN, (.;AtJ C..I..SE SFVERv.XRR..TATXOH AHD EVEH D..XiHDNr.' ~'!(3H'>ACT WXTH TrlE.SKXi'I i'iAY i AIJSi=;;VERE XRRXTATX{3N,!3URHB, Gk TXSSIJE I)ES>Tl~(.JCTXQH XN.: 7!JDXES..JTXL"ZZH6 RABRZTS.,"l, Bl<XH XRRXTATZQH SCORE WAB 8/8 AND 7!IE"~I'AT TAT X(3H:Ci3RI'3A'"'>'")~."'.>."..10~7!-'E{3.,ASS X F.i CAT X{3H FOR 807!I Ql-" G i!C'fhi'lEST X H: CALC Z Ut"I IY PQCI II...G R X 7.X r SWAL!.Our-..D, 6>'>US>ES S>EVE RE BURHS'>G Ti-il=":)TG~STX 2E TRACT AidD CAH i3E FATAL~Ci.l RON X (".: (7EHOTOXX'CX 7Y: CALCXUH IIYPOCHLQRX TE PPQDUCED PQSX TXVF RESPOH.ES XiH X iN-V XTRO ASSAYS US X N6 BACTE R X AL 8>YSTEIIB<Tl-IE AHES TEST>AND CI IRQHQSON*l 3 ABERPATXOHS XN (3IHXHESF. I~A>ISTER I=X I3RQI)LASTS. XH A Wll(3L(=AHXHAI EXPERXHEHT <i~IOUS>E i~i X CfkGHUCLEUB TF BT), FX POS(litFS RAH6 X N()I.RGH 20 TO i c)0 i~!6f l<6 , R(3I3!JCf D I!O CJ3HP{)I JHD'>FI.A I'.D i,liRONQB>OHAI.. AI3N(3RHAI.X TXI:-..8.CARCXiHQ6EHXBXS: ALTIIOUBIi NO 87!JDY!IAB f3(=EH COHDUCTED WXTI-I CALCXUI'I HY P{".::,i iLGR X TF,'"i>>E CA RC XHO6:i I":C P'37EXT XAI i3F,~Q I3 X!Ji(I-iY PQCI-II.(3 R X TE WAS BTVDXED H Fran RATS.AFTER.0 I'Jr=-Fl>PH SO i)MIJN l IY f>(3Cl!LORE'..~I IE RE W""': NG EV X (3l=t'!CE THA'i'H X".>("I.IEI'IXCAI .-RQD(JCED ANY..-5RŽ"IQOF'">>'"'.ESP",!HSE ~"H."'))XT, OH Tl.IXS P{3${.JRE}>vlf i'>I'~"jdI.,~~IQ i HI 4>\.I;,">~st','3':.c'I i~i.(Ji.), p'r>:>'ll (rp!~>!g'l Xg i p, (p 3R ()TI.<<i(TAR6ET GR6At~S~'",'HJ:-""'P I Il."".)'!A.J()<".i!8":: 8".IF'iL{3X I I"'I".Y P"'>('-<iljl RXTE"':>('><>.'OIIIP{i"'.:.)I-"I!..Q R 3 N!.,='">R'!.=.R RH X 7 XZ'-I'X l3!'(:-;"'I )R:."IK:: ii6 AHi)Rl:..CREAT X GNAi.WATER~STI JD X ES I IA VE")EEH CONDUCTED TO DETF-Rt'i X HF." I<E;.".)H6-TE Pi!EFFECTS GF CHILOR X HATED Di~'t",I'li<XN6 WATER, S>EV"iI'>>I.Hi" RAT'>"."."':IB ".F'PAT,>!JI'=RE l'Vl:.:H'I.00 PI'i'")CIHLC)P.XHE I.'H" lEXR...RXHKXN6 W'ER.'IO>)XFF.-:RF..I'!CI= f H I: f-..RT.i X', 6R:)IJTI-I, 9I QOD>>A RAI'll::". TERS>OR SPEC XF X(".i.)R{AH"">'r'XCXTY !JAS (38SI.='<<VE'3 .3ETWEEH Cc.)NTR{3L i IHI3 I'=".XP{)B::".f) ANIMALS.TWO S>EP."-RATE AHXHAL ST!)I):I:ES> C()HI)LJCTED 8Y DXr-r-f-RENT 6(3VEftHHI.-".Hl A6EHCX-S'3ETERHXHEf) 7'-ih'i HI"...(",IHLORXNAT'KQN Qi=I'IUH XCX I AL;)RX;"!<.: it!3'IATER DXD'!OT REB!JI T i'(".)>'.XCX" TQ Tl-iE f)EVELQPXtd('>> iOUB" FETUS,'.>>A!=E!'!AH(3!-X I6 GF'.ilXS iAATEi<XA!. '!H A!..(:)H6-TERN 8ASXS SH(3UI.D EihPHASXZE Ei!EF.6F:"!C'>'HD: ZP">>7 c"sX D P I~.i.)CED{.li'CEB> i".E;if)VE 0~MESH.4XR~XF HQT i!RE>'iTIIXH6,')XVE ART J FXi XAI..REBPXRATXGH

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'I I">XS!iS>"F Ti-ii: ':.R U."">F--'.".N>,)L,i'i>j .ANC)DXSPGS>~!.. GF"'-IE O'RGI3!JC"', (3R FIROhI"liE i'>JBLXCATXQH >3R.(JSE GF, 6)R RKI,.X'HCE UPON Xtif=GICIRATXOH COIMTAXHED iIEREXH."Vi".'-:).."i'GRlI*TX)N REI" ES<.:h(l Y'.")')" I-IE PRQ!3(JCT>')!X",: fGHATED Ii.REXi'i, AHD DOES N(37 i(F;.'."""'~!3:TS USF XN<""!I"IBXNATXQt'I <ii.'Til ANY".)TIIEP, iiATERXAI'">R":hl ANY llTIIER i" R(1(Fr-8 I)y>f A\)~g p. SEE INSTRUCTIONS ON REVERSE SIDE SECTION II PERMIT~IYII 0005827 NUMBER EM 3 A>>NA%OF PROCESS CONIRIBUTI III TO THE DISOIARGE TICEXXN THIS OUIFALL AM)SIC CODE Bs PROCESS SOCEDLLE (YFsVCLY AVERAGE)mum/DtLV~24~36 5~OO E SANITARY W TER 4911 PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE n th CCC Or 0 CC 0 C~PRXESS HASTEN%TER FUXI RATE Ds PROCESS PRCXXXTION RATE N/A TOTAL YEARLY DAILY HINII%N DAILY HAXII%N LN I TgXXIE 0 ll~6 0 3 7~6 LNITS PTIHE~LJ JlIIIZQZc!2JK 1 POUNDS 2 GALLONS 3 CUBIC YARDS 4 TONS S MGY 6 MGD.7 GPD TIME 1 HOUR 2 DAY WEEK 4 MONTH 5 YEAR cv Cll n OCC9 O CE CL As f4'%F PROCESS CONIRIBVTIICI TO llE DISOLUCGE g/A TIROUGH THIS OVIFALL AID SIC CLXE Bs PROCESS SDEDLIE (YEARLY AVERAGE Cs PROCESS HLSTEHATER FUXC RATE Ds PROCESS PRXLICTIOH RATE As HAIE OF PROCESS aXIIIBVTIHT TO TIE DISCHCRGE g/A TICBXXIH THIS OUIFALL JUO SIC OXE Bs PROCESS SQEDLIE (YEARLY AVERAGE)C s PROCESS HLSTKHATER FUBI RATE D.PIXXXSS PRXXCf1 ON RAlE As tQPE OF PROCESS CCNIRIBVTIIC lO TIE DISCHARGE g/A AM)SIC CTEE Bs PROCESS SOERIE (YEARLY AVBLAGE)RLXKSS HASTDNTKR FUXC RATE A.HHE OF mCKSS CCNIRIIXITIW TO TIE DImeaa N/A TI%%XCIH THIS OUIFALL ANO SIC CODE Bs PRXESS SOEDIE (YEARLY AVERSE)C.PROCESS HAST8%CTKR FLDC RATE Ds PRXESS PRXXCTION RATE TOTAL YEARLY DAlLY HIHII%N DEWILY HLX II%M TOTAL YEARLY DAILY H I HI I%N DAILY HAXIltN TOTAL YEARLY DAlLY HINIJ%N DAILY HLXIHEC lOTAL YEARLY DAILY HIHII%N DAlLY HAXII%N LN ITS/TINE LNIT aXK LJ LNITS nIHE LNITS/TIHE INSTRUCTIONS FOR COIL'LETING SECTION I I ITEM 3 Tf is form reauires Information on tne process streams<<hlch contribute to this dlscnarge. ENTER THE PERMIT Il'ABER IN THE BOX AT THE TOP OF THIS FORM.THE PERMIT NIWIBER CAN BE FOUNO ON THE FRONT PAGE OF YOUR EXPIRING FERMIT.If this is a new or nor oreviousiy permitted facility, then leave alan<and a number<<ill be a5signed.Enter outfaii number in space provided for eacn page of Section II.For eacn individual dlscharce point a separate set of Section I I'Orms muSt be f i I leg out.ITEM S PROCESS STREAMS CONTRIBUTING TO OISCHARGE: FOR EACH SEPARATE'ROCESS PROVIDE THE FOLLOHING INFORMATION A.Enter tne name of the process<<nich contributes to this discharge. Also provide the proper SIC code.B.Indicate tne yearly average proce55 Scnedule in hOurS Ocr day and days-oer-year. C.Provide the process wastewater flow rate information as requested ba5ed on your last l2 months of operations. Ilefer to unit code given in the left margin (or the appropriate flow units.0.Process Production Rate-Certain permit limitations mav be based on production rates.The production rates used to determine permit limits snail be represented by a reasonable measure of actual production of the facility, such as the proauctlon aurlng the high month of tne orevious year, or the monthly average for the highest of the previous five years, or other reasonable measure as stated in applicable U.S.E.P.A. categorical rules and regulations. For new sources or new dlscharaers, actual production 5hall be estimated u5ing projected production. Recora your production rates in the termS ana unitS uSea In the applicable V.S.E.P.A. categorical rules ana regulations for your type of facility. SEE INSTRUCTIONS. ON REVERSE SIDE SECTION I I e PERMIT~LNI Oit05827 NUMBER~OO: E GROUNDWATER DISCHARGE INFORMATION Ae IS 1HE DISCHARGE FRCN THIS OUTFALL DIRECTED TO THE GRONO OR GRONDtATKRS2 llF tDP CCttTltiE TO ITEM O)Be HAS A HYC62OIBXDGICAL STIXT/OR ITS EOJIVAIENT BEEH PKRFORPED OR IS THERE SIFFICIEHT cNIREHT HfÃGGEQ+GIaL INFOIHATION AYAILABlE AS RE0UIRKD BY Tte HATER RstxxstcEs alttISSICM PART ZZ RAIXltD6ATER RIIES OF AIDUST 14P lRU RP525PZ/W (PAGEFCR THIS EXISTI%OR PROPOSED DISCH6RGE/ IF YES AlTAOI A COPY CF lHE REPCRTP Ce ARE YCU RBXESTI%AN EXBGTTICN FRCM SIKPIITT1% A HYCRCGKOLOGIaL REPCRT tltDKR RISE R.323P221}l (l0}(PAGE tt5)Ot FR(M GRIXPIXtATKR N5ttITQRI% IIKOUJRIMEHIS tltCER RLAK RP525PZIU5 (5)(PAGE t(73 OF TIE PART Zl RLLESP IF YES ATTACH DXIMKHTS AM)EXPLANATICN TO DOIGCT IATK THAT YIXR DISOQf6E NXAD OUALIFY RXI~CNP De ARE YOU RBXESTI%A VARIANCE FRttt RULE 323e2Z6 (PAGE 5)(%tKXDIIADATICN) OF TIE HATER RESIXl2CES CCWISSION PART ZZ GRXXtttlATKR RIALSPA IF YESP ATTACH SIXH DOQMKHTS AS NECESSARY TO CQQtSTRATK TIE HEED FCR A VARIANCE IN TKIYtS CF TIE CRITERIA SPECIFIED IH RIAL 5Z5P2210 (PAGEOF THE PART ZL RILESP Ee I,IST ALL CteIICAL SIBSTAICES HHICH ARE IN MICHIGAN S CRITICAL MATERIALS REGISTKR TAKE IV lPAGK{j)Ot UPSP EPA'S PRICRITY RXll/TANT LIST TAKE V (PAGE 1)OR ANY OIIER SIBSTMXS tHIOI ARE Ot NAY BHXPE INXIIIIXS 1D TIE EESIGNATED USES OF TIE GNIXIKltATER OR 19 TIE PUBLIC IEALTH THAT ARE DISCM6RGED OR EXPECIED TO BE DISCH6RGKD TO TIE MX!KXIATKR~ THIS FJCILITYP ESTIHATE THE FINAL EFFLIEHT COtCEHB4TICN AtKI RKCCRD AII.DteTA IN ITBl 1 OF SECTION Il IH THIS IO)NEfe TIE APPLIa7IT HAY BE REIXIIRKD 1O DO ACOITIOIAL HASTE JIUI.YSESP z->>-a.Submitted 12/6Y91INT APPUaBLE/BELlKVKD ABSENT PRESENTS DATA IQOVIDKD IN ITBI 7 ITEM 5 Ae DISCH8RGE CHAIIACIKRISTICS BGDI7 (FIYE DAY BloctetlaL oxYGEH DKMAIKI)'coD (OKttlaL c0DGEN cetAto)CCNCEHIRATICtt AVE NAX~40.~05~99.~6 WITS CIXK lt ANALYSES SAtPIK TYPE CIXE u1~u EXPECTED WASTEWATER CHARAC 1 Mp/I 2 UQ/I 3 COUNTS/100 ml 4 S.U.5'F e I.BS/OAY ANCNIA HITRIXIKH (AS H)TOTAL SUSPKNXD SCUDS TOTAL PIOSPta2US (AS P)TOTAL RESIIXIAL OURIHE DISSOLVED OXIGKH NIN~6~4 FECAL CGUFXIN BACTERIA~TINE (SUPER)TDPERATISK (HINTER)TOC (TOTAL ORGANIC aRNXt)~25.~55~11 6,~0~7~.~03 6~12~~05 S7 8~~u LJ~~u Be ODKR INSTKHATKR CM6RACIKRISTICS ul 2~60 ul~65 u1 u1~1 1 3 u5 u5 u1 u1~SAHP TXBF 1 GRAB 2 24 HOUR COMPOSITE 0 I L B G R E A S E c i ro.~65.~56~20 8,~0 LJ u1~65 RECUIRKD IWXP5ATICN FIT SINFACE HATER DISCHNGVP INSTRUCTIONS FOR C(5IPLETING SECTION I I ITEMS 4 ANO 5 5 forr,require n tmatioIi on a specific outfall discharging to either the groundwaters or the surface Waters.5?(Is orto r equ r~e-q(ER TWE Dcq)f(T'h BER III THE BOX AT THE TCP OF THIS FORM.THE PERMIT NIDIBER CAN BE FOUND ON THE FRONT PAGE OF YOUR EXPIRING oER??IT.z+thi+5 a nett or not previously permitted facility, then leave plonk and a number<<ill be assiqned.Per r (le Ouc fal I numaer In the Space PrOvided tor eacn Dace of Section I I.For eden Individual discharge point a separate set ecVIotl'D~torm'5 (It's 4 ana 5)nust ae I i lied out.DP/ITEM 4 Il G"OUNDWATED DISCHARGE INFORMAT ION (00 NOT INCLUDE DEEP WELL INJECTION INFORMATION IN THIS ITEM)A.-D.The applicant shall address each ot thaqe oarts If the discharge fran this outtall Is to the groundwater. ITEM 5 EXISTING OR EXPECTED (FOR A NEW DISCHARGE) WASTEWATEP. CHARACTERISTICS OF GROUNDWATER OR SURFACE WATER DISCHARGE (DO NOT INCLUDE W>>LL INJt I N IN IN H ,?JP The applicant shall report available discharge data (real data for existing discharge or expected data for a oroposed discharge) for the Dard>>eters ds listed.These Darameter5 shall be addressed foI either a surface water dl5charge or as aDpropriate for a grounovater dlscnarge. For assistance In determining appropriate parameters a groundvater dlscharoe apollcant may contact the Grounovater Duality Division, Permits Section or the approorlate Grounorater pualltv Division's District office.The applicant shall report the Sanele type code best describing eden reported place of date.See coding on the left margin of this form.II'his outtall Is a surface Water dlscnarae. the aop?icant must report quantitative data for each Dard>>eter Identified bv an 5"~OCDODDODOD ~.I*CC Dt t 5~555 5 Ot DOOI tl I, II I 5OCO 5 Dt t CWIND tt tOI~DDIIC tlt 9.It data ls available for other parameters not listed above in A.or other parts ot this application the aDpllcant 5hould reDort that data In the blank 5Daces provided In this Dart.NOTESI I.Unit codes tor paraneters reported In parts A and B can be tound on the lett hand side ot this torm.2.Grab sample shall be used to analyze for pH, tenoerature, total phenols, residual chlorine, oil and grease, and fecal col ltorm In a surtace water discharge unless other frequency-sanple type analyses are availabl~.See Glossary (page 48)for ddt lnltlon of grab sandie.24-hour comooslte samoles shall be used to analyze for Total 8005, coo, Toc, Am>>onla Nitrogen, and Total Suspended Solids In d 5urtace Water d)5charge unle55 other frequency-sample type analyses are available. See GI055dry (page 4B)tor definition of ccmooslte sa>>pie, REPORTI)6 OF INTAKE DATA~You are not required to report unle55, you vish to demonstrate your eligibility foI d"net" effluent limitation tor one or more pollutants, tnat Is, an ettluant limitation adjusted by subtracting the average level ot the pollutant(s) present In your intake Water.NDDEs regulations allow net limitations only In certain circumstances. To demonstrate your eligibility, report the average ot the result5 ot analyse5 on your intake vater llf your Water Is treated betore use, test the voter atter It Is treated).and attach a 5epdl ate sneer containing the tol loving for each Do?lutant?(a)A statement that the Intake veter I5 dravn tram tne body of vater Into rh)ch the dl5chdrge Is made.(OthervIse, you are not eligible tor net limitations.)(b)A statement ot the extent to Which the level of the oollutant is reduced by treatment ot your vastevdter ~(Your limitations WI)I be ddju5ted only to the extent that the pollutant Is not removed.)(c)when apDI)cable (tor exonple, When the pollutant represents a class ot ca>>pounds), d demonstration of the extent to Which the pollutants In the Intake very physically, chemically, or biologically tree the pollutants contained in your discharge.(Your limitations vill be adjusted only to tne extent that the Intake Dol lutant5 do not vary frcm the discharged oollutants.) lt you have two or more substantially Indentlcal outtal ls, you may request permission tran your permitting authoritv to sample and analyze only one outtal I and submit the results ot the analysis tor other sub5tdntlally identical outtalls.It your reque5t is granted Dy the permittlno authority, on a separate 5heet attached toothe aap Ilcatlon to?m Identity vhlch outtall you dld test, and describe why the outtalls<<nich you old not te5t dre substantially identical to the outfall>>hich you did test. SEE It ISTRUCTIONS ON REVERSE SIDE SECTlON I I PERMIT~gl Qpp5827 NUMBER I PRIORITY POLLUTANTS AND ADDffIONAL INFORMATION FOR SURFACE WATER DISCHARGE ONLY THE FOLLJSI1%REOLESTKD INFORMATION ~e ADNESSED~QHFACE HATOt DISCHARGERS. IOZEI MDI USE DISCHARGE% BALLL PROVIDE EXPECIKD VALLES FOR lHE OUlUITITATIVE AND QUALITATIVE INFNHLTION REOLKSTED BELCHe A.ts THIS FACILIlY A PRIMARY IIOUSTRY?(REFER TO TABLE IA PAfg 9D (IF W GOTO E)(IF Y 5 GO TOB)Be IWICATE TYPE OF PRIMARY INDUSTRY AS LISTED IM TABLE tA PACE Qe I CONTIN'ITH C.)C>COES THIS OUIFALL DISCHARGE CCtITAIM ANY PROCESS HASTKHATER?(tF W, GOTO E)(IF YKS.GOTOD)De INDICATE ttIICH GC/tn FRACTIONS NJST BE TESTED FCR~(REFER TO TABLE IA PJIK (II)IOZEI FCR EACH GC/Hs FRACTION CHECKKDe EACH SPECIFIC ORGANIC TOXIC POLLIJfAMT HllHIH KAOI FRACTION tl5I BE ANALYZED FCR (SEE TABLE I IA PAGE Q, IN AODITIOMi ALL PRIIVLRY INLXJSTRY APPLICANTS)IITH A PROCESS HAS19IATER DISCHARGE'~ PRCNIDE OLJLMTITATIVE DATA FOR EACH TOXIC IOLJJJfAMT IN TABLE IIIA PA%gP e RHXRD ALL DATA ON FCRHS PROVIDED (ITBL 7)IN THIS BOOKLETe (CCttfltAE HtlH K, K BKLJBI)OOE S TH ELE W R D Analysis per J.B.Beauboeuf D BASE/MEUIRAL GrOundWater Division 0 eeee PESTI C IIX Ee IF gg, QJIFACE l4LTER DISC%ROE JPPLICAMf (PRINRY OR SECCtOUIY I IJJSIRY)e RKGAJICLESS OF THE TYPE OF DISCHARGEi KMlIS OR HAS REASON TO BELIEVE THAT AMY POLLUTANT LlslKD IN TABLE IIA AMD IVA PJGKS~IS DISCHARGED FROI ANY IXJIFALZiT)E OUMITITATIVE DATA~BE PROVIIKDe RECND ALL DATA ON FOIVIS PROVIDED (ITKH 7)IN THIS BOOKLETe Fe IF AMY SLJIFACE HATER DISCHARGE APPLICANT (PRIMARY OR SECOtOARY INXJSTRY)e REGJRKESS OF TYPE OF DISCHLRGKe XMAS OR ILLS REASCN TO BELIEVE JIFFY POLLJJTAMTS LISTED IN TARE VA PAGE+ARE DISCHIRM FRLtt AMY OLJIFALL l)E APPLICJJIf ~DESCRIBE RKASONS FCR 1%, PLXJJJTJtlf BEltO PRESEHT JJO PROVIDE AHY AVAIUBLE OUANTITATIVE DATAe RKCND ALL DATA ON FCttts PROVIDED (ITOI 7)IH 1HIS BOOILEfe WT APPLICABLE/BELIEVI ABSOIT N/A 0 PRESOIT/DATA ls ATTACHED Wf APPLICABLE/BELIEVED ABSOIT N/A PRESOIT/DATA Is ATTJUMD Ge ALL QRFACE HATOt DISCHARGE APPLICAMIS (PRIMARY AIO SECCtOARY IIGXJSTRIES) ttOJ cR HAIKFAclLSLEs 2 4i f TRIctslstpetEwxf AcETIG AGID (2e 4i 5-T)J i 4i et TRIOKJSOPIHWXY PRCPAWIC ACID (SILVEXi Zs Ii 5i TP)J DI%PIYL V PCi 4i l TRILJLJJRCP)KDIYL) PIOSPKIIOTHIOATK (RCtNEL)J>IRICJKJSIOPLEML (TCP)J OR HEXJOLNGPIEJE (ICP)J (ALL DATA FN T)E ABOVE tlJST BE GKMIIATED USt%STAIOARD AIHLYTICIL CALItttATICH PIOCOXJLKS) OR KtslO CR HLS REASON 1D BKLIEVE THAT TELO IS OR HAY BE PRESBIT IN T)EIR DISCHJJKIEe ~RKPNT QUALITATIVE DATAi GOERATKD l431ttt USED A SCRKKHIIO PIOCOXJLE Wf CALIBRATED HITH ANALYTICAL STAIOARDSe FN L Di 1 Si TKTJIAOKJSKXJIBEHZ~DIOXIH (TCZXJ)e RKCND ALL DATA ON FNtts PROVIDED (ITBL f)IN THIS BOOKLEfe Je IF~1lE QJLFACE HATER DISCHARGE APPLICAMf K)KHS N HAS REASON 1D BELIEVE THAT BIOLOGI~TOXICllY TESTS HOLE HADE IH lHE LAST T)ttEE (9)YEARS CN JJtf OF T)E APPLICANT S DISCHL%ES OR ON A RECEIV1%HATER IN RELATION lD A DISCHARGEi PROVIDE THIS ItFNHATION AS JJI ATTACttHIT TO 1HIS JPPLICATIONe Ke IF A OIIIRACT LABNATORY OR CSStLTI%Ftttt PBRÃtKD Jttf OF TIE ANAYSES REQUIRED BY THIS APPLICATICIL PROVIDE TIE NAtE AND ACNESS OF EAIH LABORATNY OR F IIVI AtO 1)E ANALYSES POIFCRtED AS AM ATTACttEMT CF'IHIS APPLICATIONe CO YOU DISCHL%E ANY OI)ER TOXIC OR INJLRIOLJS CteHCAL SLSSTANCES tOT LISTED IN TABLES IV PJGE tt AIO IIA lWOAI VA PPP4$~~IF YEsi TlEN IOEHTIEY TIE CJKPIICAL QSLSTANCES AW KSTIJLETE TIE FINAL EFFLLEttf IXYCEHIIIATHYISe SLKPIIT THIS IIFCALLTICN AS AN ATTAC)tENT TO THIS APPI.ICATIONe Wr APPLICABLE/BELIEVED ABSENT N/A Q PRESOIT/DATA IS ATTAC)ED N/A Q APPLICLBLE/SEE AITACIED Q WT APPLICABLE QX~IIE/SEK An~Q tOT APPLICABLE N/A APPLICABLE/SKE ATTAOED INSTRUCTIONS FOR.CCMPLETING SECTION II ITEM 6 This form reavires Information on s speCifiC Outfall dlsCharglng to the surface>>sterS. ENTER THE PERMIT NUMBER IN THE BOX AT THE TCP OF THIS FCRM.THE PERMIT N(S48ER CAN BE FOUNO ON THE FRONT PAGE OF TOUR EXPIRING pERMIT.If this is s ner or not previously permitted facility, then leave blank sna s number>>i(I be ass(oned.Enter tne outfall number In the space orovlded for tach page of Section II.For eben Individual discharge point s separate set of Section II.Item 6 forms must be filled out.ITEM 6 PRIORITY POU.UTANTS ANO AOOITIONAL INFORMATION NOTE: If you have t>>o or more substantial ly indenticsl outfsl ls, you msy request permission from your permitting author Ity to sssple sna analyze only one outfall sna svcmlt the results of the analysis for other substantially Identical outfsl is.lf Vour request Is granted by tne permitting authority, on s separate sneet sttscned to the application,form Identify>>nich outfsl I you aid test, sna describe>>ny tne outfslls>>nlch you aid not test are substantially Identical to tne outfall>>nlch you did test, NOTE: A.-C.sno E.-J.40 CFR Part l22.2((g)(8), Friday, April I, lg83, provlaes for s smell Business Exemption from the resorting of quantitative apts for organic toxic pollutants sna toxic pollutants ss required by Port I22.2((g)(7)(ll)(A) or I22.2((g)(7)(ill)(A), These Dorts sre self-explanatory snd do not require further Instructions. simply go through each part snd do ss indicated. 0.Several Industrial categories snd subcategories have been exemotea frcm submitting dots on certain GC/MS Fractions (40 CFR Pert l22, vol.'48, No.64, Friday, April I, 1983, Notes I, 2, sna 3)." Revle>>the folio>>lng list to determine>>nether your facility qualifies to be exempt from reporting Gc/HS (Gss Chrcmstogrspnv/ Moss Spectroscopy) Fractions. GC/MS Fraction Testing snd Reporting Exenetlons Textile Mills Industry All four GC/HS organic fractions ln the Greige Mills Subcategory. -Pesticide fraction In ell other supports of this Industry.Ore Mlnln snd Oresslno Indust-Volatile.base/neutral, snd pesticide fractions In the Base snd Precious ltetsls Subcategory. -AII four Gc/MS organic fractions In sll other subcategories of this Industry.Cu>>and Vood Chemicals Industry-Pesclclde fraccion In the Tall Oil Rosin Subcateqory and the Rosin based Derivatives Subcatsgofy. -Pesticide and base/neutral fractions in all other subcategories of th(s Industry.Pulp and Paper Industry-Pesticide fraction In Paoerqrade Sulfite subcateaorles {subparts J and 0).-Sass/neutral and pesciclde fractions in Oeink Subpart Q, Olssolvlnq Kraft Subparc F, and Paperboard from Vesta Paoer Subpart E.-Volaclle, base/neutral, pesticide fracclons in the BCT bleached Kraft Subpart H, Semi-chem(cal Subparts 8 and C.and Nonlnceqrated-Fine Papers Subpart R.Acid, base/neucral. and pesticide fraccions ln Fine 8)cached Kraft Subpart I, Olssolvlng Sulfite Pulp Subpart K, Ground>>ood Fine PaDers Subpart 0~Market Bleached Kraft Subpart 0, Tissue frcxa Vastepaper subpart T~and Nonlnteqrated Tissue Papers Subparc S.Steam Electric Peer Plant Induct-Base/neucral fraction in the Once Through Cooling Vater, Fly Ash, and Boctom Ash Transport Vater orocess>>astestreams. 38 l e eI~~')~'1~I I~'~e;~-~'~~I 1 l)~e 1 I"~.'c~~'~~'~~1'e~~')'~r'l~~~~~~I'~~II'~NI~)I I~~~'~~~1~e~~~e)~~~I~~el~~'~I~)~~~I~1~I~I~~I~~~~~~c'I e)~I~I C~~I~)~I~~I~~~~1I~I~e~~I~)~~~~Ie~~'I~~~~~I~)~~~I~~el~~~')l~1~I~~I~~II~~e~~~~~)~I~~I~1~I~I~~II~~.~r~I~-~I~~I~1~I~~I~~~~C'~)l~'I W~~~~~~~~'~~'~~~~~~~c)I~"ll~'~~~~ INSTRUCTIONS FOR CCHPLETING SECTION I I ITEN 7 Thl form Is to be used bv both surface and groundrater applicants to record Information on anv Hlchlgan critical material, E.P.A.prlorltv pollutant~or natardous substance in xhicn tnls application recuires data to be provided.This vould Include any cham ca arm~I I substance frcm tne Hlchlgan Critical Haterlals Register<Table Iv), the E.P.A.priority pollutant t.lstlng ITable V).or Tables I IA VA vhlon IIStS Organ)C TOXIC POI lutantS~Other TOXIC POI lutantS~CcnVentlanal and NOnCOnyentlOnal POI lutantS and Hasardcua Substances ~ITEN 7 CRITICAL MATERIALS* PRIORITY POLLUTANTS ~ANO/OR HAZAROOUS SUBSTANCES IN THE OISCHARGE Materiel I.2.3...8 A.List the name of the chemical substance Icrltlcal material, priority pollutant, or hasardous substance) frcm Tables IV.V and IIA-YA as reculred In tne aox vnicn you cnecxed In A.I-3.above.Enter eacn chemical substance's parameter nmnber as listed In Tables IV, V and IIA-VA It provided.8.Provide the average concentration of the chemical substance hewed In A.Indicate the smnple type used and the number of analyses made to provide the concentration cata for the chemical substance named In A.C, Pl+vide the maximus concentration and determine the mass loading of the chemical substance named In A.I'f only one analysis uas made for a chemical substance then record that data es a maximus value.If more than one analysis has been made for a cnemlcal substance then provide en average value of those analyses and the maximus value.2.This Section II, Item 7, Oata Sheet provides space for recording data for 8 chemical substances IHaterlals). Additional space for recording of data for more than 8 Haterlals can be made by making copies of this Item 7 Oata sheet es needed.It Is also Important to use e separate set of oata sheets for each applicable reporting reculrmnent as listed In A.)-3.end for each outfall.Refer to the lett margin for the code number representing the sample type used end the appropriate unit codes.40 0 i I~~~~o I I o~.~~~'.-~..~~~~~~~o~~~e~o.~'~~~~~'I~I~~~'~I~~~I~~~~~~~~~~~o~~~o~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~t~~~~~~~'~~~~I~~~~~~~ ~l~0 L~~~~L L~~~~I~.I~.~-e e~~~l~~~~o~~~a.e-~~~'~~~~'~~I~~~'~~~~.-~~~~~~~~~~~~~~~~~g~~ ~l~~o~s I a~j~~'.~~~Q~~..---~~~s~I)~~~~o.~I Ie~I 0~~~0~~~~~'~~~~~o~~~~~~~~-~~~..~~~~~o~I~~~~~I~~~~I~~I~~~~~~~~~~~~~~~~0~~~~~o~~~~~~',~~~~~t~~~~o~t~~~~

VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USiNG METHOD 8260 Page 2 of 2 Client Sam le ID: S.SEWAGE PLANT EFFL.LAL Sam le ID: L1009-47 Constituent Dibromochloromethane hl r nzn hl nzn m-X lene o-X lene r n Br m f rm 1 1 2 2-Tetrachloroethane 1 3-Dichlorobenzene 1 4-Dichl r nzen 1 2-Dichlorobenzene Concentration IL<5<5<5<5<5<5<5 Reporting Detection Limit IL Data Qualifier s LOCKHEED ANALYTICAL SERVICES 42 VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 TENTATIVELY IDENTIFIED COMPOUNDS Client Sample ID: S.SEWAGE PLANT EFFL Date Received: 29-DEC-93 Matrix: WATER Analytical Batch: 011094-8260-FZ LAL Sample ID: L1009%7 Date Analyzed: 114AN-94 Dilution Factor: 1 QC Batch ID: 011094-8260-F2 Tentatively Identified Compound UNKNOWN SULFUR COMPOUND UNKNOWN Estimated Concentration (pg/L)37 28 Retention Time Iminutes)4.47 , 9.70 Data.Qualifierls) LOCKHEED ANALYTICAL SERVICES ~~J~1 l l~~e I~~s.~~~'~s~~~~y~~~.--~~~.~~I'~~~w~~~a.~o~~a~~~~~~'~~~~~~~~~~~~~~~~~~.-~~..~~~~~~'~~~~e-~~~~~~~~~~~~~'~~0~~~~~~~~~I~~~~~~~'~~~~~~~~~~~~~~~~~~~~0 0 ~0~e~~I~~~.~e.~~~'~~-~~~e e~~~~~~~~~~'~~,~~~~~~~~~~~~~~~~~~~~.~~~~~~~~~e~~s~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~e~~~~~ ~e~+~~~~~~~~.~I~~I I~~~~~~~I'~~~~.~~~~~~~~g~ ~~~~~~I I e~~~~'-~~~~~~~..'-~I I'i~III~~~I~I~~I~~I I~I I~'I~~~I~~:;s~~~~0~~~~~'~'I I~~~~~I~~~I~~~~~~~~~~~~~~~~~~~~~~~~~'~-~~~~~~J~~ METALS RESULTS Client-Sam le-ID': S;...SENfAGE PLANT'EFF-LAL Batch ID(s): 1220 im Date: Collected: 12-28-93.Date Received: 12-29-93 Matrix:: round',water~: 'O¹69095-040-3N Constituents", Aluminum Antimon Arsenic Barium Be Ilium Boron Cadmium Chromium Cobalt Co er Iron Lead Ma nesium Man anese Mercu Mol bdenum Nickel Selenium Silver Sodium Thallium Tin Titanium Vanadium Zinc Method." 6010 6020'020 6020 6020 6010 6020 6020 6020 6020 6010 6020 6010 6020 7470 6020 6020 6020 6020 6010 6020 6020 6010 6010 6020 Co'ncentratlon lm ILl<0.20<0.060<0.010<0.20<0.005 (0.20<0.005<0.010<0.050<0.025<0.10<0.003 0.025<0.0002<0.20<0.040<0.005<0.010 34<0.010<0.20 (0.10<0.050 0.047 Reporting 0'atection Umit{m ILl 0.20 0.060 0.010 0.20 0.005 0.20 0.005 0.010 0.050 0.025 0.10 0.003 5.0 0.015 0.0002 0.20 0.040 0.005 0.010 5.0 0.010 0.20 0.10 0.050 0.020 Data'uallfierls) N Date;A'nal zed." 01-20-94 01-27-94 01-27-94 01-27-94 01-27-94 01-20-94 01-27-94 01-27-94 01-27-94 01-27-94 01-20-94 01-27-94 01-20-94 01-27-94 01-07-94 01-27-94 01-27-94 01-27-94 01-27-94 01-20-94 01-27-94 01-27-94 01-20-94 01-20-94 01-27-94=',.-.;, LA4.;-",-. "'S"'le"lD': L1009-16 L1009-16 L1009-16 L1009-16 L1009-16 L1009-16 L1009-16 L1009-16 L1 009-1 6 L1009-16 L1009-16 L1009-16 L1009-16 L1009-16 L1009-1 6 L1009-16 L1009-16 L1009-16 L1009-16 L1009-16 L1009-16 L1009-16 L1009-16 L1009-16 L1009-16 LOCKHEED ANALYTICAL SERVICES~

GENERAL CHEMISTRY RESULTS Client-Sam le ID.'S., SEWAGE PLANT EFFL LAL Batch ID(s): 1229 im Date Collected: 12-28-93 Date Received: 12-29-93 Matrix: round water.PO469095-040-3N Constituent Method Result Reporting Detection Limit'ata'ualifier is)." Date Anal zed LAL,.Sam le'ID Fluoride, in m IL Chloride, in m IL 340.2 300.0 Nitrate.Nitro en, in m IL 300.0<0.15 120 24 0.15 0.01 6 0.017 01-24-94 L1009-4 12-29-93 L1009-4 1 2-29-93 L1009-4 Nitrite-Nitro en, in m IL Sulfate.in m IL Ammonia-Nitrogen, inm IL Total Cyanide.in mg/L 300.0 300.0 350.1 335.2<0.50 39 24<0.020 0.50 0.059 0.50 0.020 Dl1:10)12-29-93 L1009-4 1 2-29-93 L1 009-4 01-05-94 L1 009-8 01-03-94 L1 009-12 Comments: LOCKHEED ANALYTICAL SERVICES

r~ANSTEC PPERTUR CARD 0 C3 1,.0 Also Availabie on~Pe~Ufe Qgpd l'I IL/t I I I I I I ttrf t 0 tf II 0004~Unit~1 Tronsforeter Deck Drains (5 Dryvells)Outfoll 001 1200'f fshore 3 Intokes 2250'ffshore /Ou foll 003 Oe-lain Oischof e 0 nvner 40 0=f=I=I=I ct OrOtKKI,Clter-)f N'-'I I I I~I/.I//~I I~////e r/~~c o 0'~~4~~/I East Savage Treataent Plont South Savage Treattttent Plont Sequenc)ng 8otch Reactor Tr eatvtent Plant Outfoll 002 1 1200'f fshore Neutral)zot lan Tonk Unlte2 Transforner Deck Drains (5 tfryvells) Storsvater Outfall S002 Storetvateg Outfall S003 tt t 00tf II 0004~I u12 sitesops/si te~.100 env Ivel 30 I n')ld tert~M-'1 j~i~<Ncipji;

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