ML17334B521

Forwards Groundwater Discharge Permit Application,Storm Water Discharge Permit Application & NPDES Permit Application for Review Per App B of Ts.W/One Oversized Drawing

ML17334B521
Person / Time
Site:	Cook
Issue date:	04/13/1994
From:	FITZPATRICK E INDIANA MICHIGAN POWER CO. (FORMERLY INDIANA & MICHIG
To:	HICKMAN J B NRC OFFICE OF INFORMATION RESOURCES MANAGEMENT (IRM)
References
AEP:NRC:1208B, NUDOCS 9412070157
Download: ML17334B521 (690)

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{{#Wiki_filter:IndianaMichiganPowerCompanyOneSummitSquare,P.O.Box60FortWayne,IN468012194252111CERTIFIED MAIL4P37890l729IItIDIAItIA NICHIGANPOWERMr.J.B.Beauboeuf -WasteManagement DivisionMichiganDepartment ofNaturalResources JohnHannahBuildingP.0.Box30241Lansing,MI48909Marchll,1994

DearMr.Beauboeuf:

RE:DonaldC.CookNuclear.PlantGroundwater Discharge PermitApplication Enclosedpleasefindagroundwater discharge permitapplication fortheCookNuclearPlantlocatedinBridgman,

Michigan, BerrienCounty.Asrequested byMr.ScottRossduringourmeetingonNovember10,1993,alsoenclosedisastudywhichcomparesthequalityoftheeffluentfromtheTurbineRoomSump(TRS)discharge tothatoftheabsorption ponddischarge togroundwater.

Includedwiththepermitapplication isadescription ofthechangesscheduled tobemadetofurtherreducetheconcentrations ofimpurities discharged intotheabsorption pond.Pleasenote,alsoasrequested byMr.ScottRoss,thatthisapplication addresses onlytheCookNuclearPlant'sdischarges tothegroundwater. Anapplication forrenewaloftheNPDESsurfacewaterdischarge permitMI0005827 willbesubmitted byApril1,1994.Theattachedstudyindicates theabsorption pondprovidesexcellent mixing,withamixing/dilution factorofapproximately 20:1.Furthermore, theactual.waterenteringthegroundmeetsalloftheproposedgroundwater effluentlimitswiththeexception ofaluminum. Thealuminumdischarge istheresultoftheuseofaluminumsulfate(alum)asaflocculent inthemakeupwaterplant.Thereplacement ofalumiscurrently beingpursued,asdescribed inAttachment 4.Additional changesplannedfortheCookNuclearPlantwillresultinfurtherreduction oftheconcentrations ofimpurities totheabsorption pond.Attachments 1and2describethemakeupplantneutralization systemandsequencing batchreactorsrespectively, whichwillresultinimprovedeffluentwaterquality. March11,1994Mr.J.B.Beauboeuf Page2Attachment 3isadescription ofthepresentzebramussel-controlstrategyasitaffectsthegroundwater discharge aswellassomeoftheoptionsbeingevaluated forfutureimprovements. Attachment 5isadescription of'hemical corrosion controladditives whichwillbeusedinvariousplantsystems.Theseadditives willbechosenontheirreducedenvironmental toxicityaswellascorrosion controlperformance. Finally,weoffertotheagencythefollowing proposals forestablishing compliance withtheproposedgroundwater effluentstandards:

• Weproposetocontinuecompliance monitoring

.attheturbineroomsumpdischarge. Theabsorption pondstudyhas.demonstrated thatthewaterenteringtheaquifermeetstheproposed.groundwater effluentlimitsforboron,sulfates, sodium,andtotaldissolved solids.Therefore, weproposeamonthlycomposite samplemadeupof24hourdailycomposite samplesbeutilizedforcompliance monitoring.

• Werequestthataluminumberegulated bytotalpoundsreleasedasproposedbyMr.RossinourNovembermeeting,ratherthanbyconcentration intheabsorption pond.Theproposedpoundagelimitisamaximum125poundsalumperday.Shouldyouhaveanyquestions ontheattachedmaterialpleasecontactJohnCarlson,CookNuclearPlantEnvironmental Supervisor, at(616)465-5901 ext.1153ormeat(219)425-2118.

Wewouldbehappytomeetwithyouatyourconvenience todiscusstheapplication ifyoubelievethatwouldbehelpful.Verytrulyyours,DonaldL.BakerEnvironmental AffairsDirectorDLB/sdb/046, 042Enclosure March11,1994Mr.J.B.Beauboeuf Page3bc:W.A.S.D.E.D.ToN.D'Onofrio/M. A.Bailey/J. L.HugheyA.BlindJ.BrewerM.Fitzgerald/J. P.CarlsonE.Fitzpatrick W.Kemp/K.D.MackE.Webb/J.P.Novotny Attachment 1MakeupDemineralizer Regeneration WasteNeutralization SystemTheCookPlantisinstalling asystemtocollectandtreatmakeupdemineralizer regeneration wastestomeetproposedpHpermitlimits.ThecurrentpracticeistoisolatetheTurbineRoomSump(TRS),accumulate thewasteswithintheTRS,neutralize thewastewithsulfuricacidorsodiumhydroxide, thendischarge theneutralized contentsoftheTRStotheAbsorption Pond.Becausetheregeneration wastesarenottheonlysourceofwaterbeingcollected intheTRS,ahighwaterlevelwithintheTRSmayrequirethedischarge ofthesumpcontentspriortothewastesbeingcompletely neutralized. Thenewsystemwillallowcollection andneutralization oftheregeneration wastesapartfromtheTRS.Theholdingtankforthewastewillalsobethepointoftreatment withthecapability toaddandmixsulfuricacidorsodiumhydroxide withthewastepriortometeringtheneutralmixturetotheTRS.ThetotalcostoftheMakeupDemineralization WasteSystemis$3,600,000.00. Thesystemistargetedforcompletion byJanuaryof1995,withsystemstartuptooccurthereafter. Attachment 2Sequencing BatchReactorsTheCookPlantiscurrently requesting quotations toinstallapairofpre-engineered sequencing batchreactors(SBR)tomeettheproposedgroundwater effluentlimits.Thenewsystemwilloperateatadesignflowof50,000GPDwithamaximumflowof60,000GPD.TheSouthExtendedAerationPackagePlantwillbeutilizedasaretention tanktoensureefficient SBRoperation. Effluentfromthenewsystemwillcontinuetobedischarged intooneofthetwoseepagelagoons.Thenewsystemwillbeinstalled andoperational byDecemberof1995. Attachment 3ZebraMusselControlStrategyZebramusselsareamenacetoanyindustrial ormunicipal processdrawingwaterfromLakeMichigan. Ourcurrentcontrolplanistochlorinate andperformperiodicshockchemicaltreatments utilizing aproprietary chemicalformulation. ThePlanthasalsochangedthesourcewaterforthefireprotection systemtoapotablesupplyfromLakeTownship. Thismethodofcontrolwasdeveloped forshorttermrelieffromtheeffectsofzebramusselinfestation. Basedonoverthreeyearsexperience indealingwiththemusselsatCookPlantandotherGreatLakesfacilities, anewstrategyisbeingproposedtoourcorporate management forapprovaltoprotectalloperations froginfestation. Thenewstrategyincorporates intermittent oxidizing biocidetreatments ofthecirculating watersystembeginning attheintakestructures inLakeMichigan, continuous oxidizing biocidetreatment oftheessential servicewaterandnon-essential servicewatersystems,additionofsodiumbisulfite toreduceanyresidualoxidizing biocidepriortodischarge tothelake,and,ifnecessary, shocktreatments utilizing proprietary chemicalformulations. Thegoaloftheprogramisto(1)eradicate existingpopulations andcontrolfurthersettlement ofzebramusselswithintheplantsystemsutilizing lakewater,(2)treattheresidualoxidantbeingdischarged tonon-detectable levels,and(3)reduceoreliminate thenumberofremedialshocktreatments necessary tokillsettledcoloniesofzebramussels.Theresultant zebramusselcontrolchangeswillultimately affectdischarges totheTurbineRoomSumpfromplantsystemsthataresuppliedbymiscellaneous sealingandcoolingwaterandsystemsthatusenon-essential servicewaterthatdischarge directlytotheTRS. Attachment 4AlumReplacement ProgramAChemistry TaskForcehasbeenevaluating chemicalflocculent replacements foralum(aluminum sulfate). Ourcorporate management iscurrently reviewing variousflocculents, takingbothgroundwater effluentstandards andreverseosmosissystemperformance intoconsideration. Thereplacements currently beingreviewedaremainlypolymeric flocculent whichwillenhancetheremovalofsuspended solidsinthepre-filters andmeetmanufacturer recommendations forthewaterenteringthereverseosmosissystem.Therecommendations fromthetaskforce,onceapproved, willrequireadditional timetotestandimplement. Theenvironmental benefitofthisreviewisthereducedamountofaluminumwhichwillbedischarged tothegroundwater throughtheTurbineRoomSumpdischarge. Thescheduled targetimplementation datetouseanewflocculent isfovrthquarterof1994.

Attachment 5Chemistry Corrosion ControlAdditives ThePlantisevaluating substitutes forthecurrentcorrosion controladditives inthesteamgenerators, plantheatingboiler,feedwater andcondensate systems,andclosedheating/cooling systems.Thesesubstitutes willincludecarbohydrazide, andotheravailable productsfromchemicalcompanies suchasBetzorNalco.Theenvironmental benefitsoftheseadditives includeutilization ofmorebenigncorrosion controlproductsorproductsrequiring lowereffective concentrations. Useoftheseproductswillnecessitate discharge totheTurbineRoomSumppathwayinconcentrations tobedetermined uponeffective optimization. Consequently, higherconcentrations orironandothersystemproductscaninitially beexpected. Comparative StudyofTurbineRoomSumpDischarges andAbsorption PondWaterChemistry CookNuclearPlantGroundwater Application February7,1994 INTRODUCTION Astudywasconducted tocharacterize thewaterqualityintheCookNuclearPlantAbsorption Pondcomplexpriortodischarge intothegroundwater. ThiswasattherequestofMr.ScottRoss(Michigan DNR)duringourNovember1993meetinginLansing,MI.Theintentofthestudywastodetermine themixinganddilutioneffectsoftheAbsorption Pondondischarges fromtheplant'sTurbineRoomSump(TRS).Thisreportpresentstheresultsofthestudy,dataanalysis, andgroundwater implications. Wastewater generated intheplanteitherdrainstotheTRSorispumpedtotheTRSfromlocalized sumps.Theprimarysourcesofwastewater includeMakeupPlantdemineralizer regenerations, filterbackwashes, floordrains,chemistry labwastes,variousequipment andsystemdrains,andnon-contact coolingwater.Wateriscollected intheTRS,'eutralized asnecessary, andisperiodically discharged toanonsiteAbsorption Pondcomplex.Thepondsarelocatedapproximately 825feetsoutheast oftheplant(Figure1).TheAbsorption PondcomplexconsistsoftheoriginalAbsorption PondandanOverflowPondconnected bya392footditch.ThepondshavereceivedanaverageTRSdischarge flowof301,000gallonsperdayduringthelastsixmonthsofplantoperation. Bothpondsmaintainrelatively stablewaterlevelswiththeAbsorption Pondoverflowing continuously tothedownstream OverflowPond.Thepondwaterenteringthegroundeventually flowstoLakeMichiganbasedona1991hydrogeology study.MATERIALS ANDMETHODS'he Absorption Pondstudyconsisted ofthreestages:1)apreliminary conductivity surveyandpondvolumedetermination, 2)an18-daycomparison ofTRSandAbsorption Pondwaterchemistry, and3)dataanalysisandreportgeneration. Thepreliminary conductivity surveywasconducted todetermine theuniformity ofwaterchemistry withintheAbsorption Pondandtoobtainponddepthreadings. Thesubsequent 18-daystudyincludedtwoMakeupPlantdemineralizer regenerations andwasconducted withbothplantunitsoperating between70and100<power.Thesecondregeneration was"forced"tocompressthestudytimeandprovideamoreconservative evaluation oftheeffectsofregenerations. Theamountofacidandcausticusedintheregenerations wasmaintained atnormallevels.Page1of20

Preliminar SurveAsamplinggridwasestablished ontheAbsorption PondandOverflowPondon40footintervals usingpermanent reference points.Ateachpoint,aconductivity measurement wastakenatadepthofapproximately 1.5feetusingaHachModel44600conductivity meter.PonddepthswerealsotakenateachpointusinganImpulseModel4400depthfinder.Additional depthreadingsweretakenaroundtheperiphery ofthepondstobetterdevelopdepthcontourmaps.Theareasofthetwopondsweredetermined usingaNovember1993aerialphotograph scaledto1inch=660feetandanelectronic planimeter. Tenrepetitive measurements weretakenoneachpond.Averageareaswerethencalculated fortheponds.Thevolumesofthetwopondsandtheinterconnecting streamwerecalculated usingthedepthcontourmapsandareadata.Theareasbetweenthedepthcontourlinesweremultiplied bytheaveragedepthandaddedtoobtainthetotalpondvolumes.18-DaStudThestudywasdesignedtoobtaindailycomposite samplesfromtheTRSandAbsorption Pondcomplexduringaperiodencompassing twodemineralizer regenerations. Sampleswerecollected onceperdayfromtheAbsorption Pond.TheNPDESautocompositor wasusedtoobtaindailyTRScomposites forthestudy.CookNuclearPlantpersonnel analyzedthesamplesforpHandconductivity. Halliburton NUSEnvironmental Laboratory analyzedthesamplesforsulfate,chloride, sodium,totaldissolved solids,totalaluminum, dissolved

aluminum, totalboronanddissolved boron.Foursamplelocations wereselectedtomakeupthedailycomposite fortheAbsorption Pondcomplex.Twocentralpointswerelocatedat10footdepthsintheAbsorption PondandtwocentralpointsattwofootdepthswerelocatedintheOverflowPond(Figure2).Tygontubingwassecuredateachsamplelocationandruntothepondshoresforsampling.

Batteryoperatedperistaltic pumpswereusedtopurgeanddrawthesamples.Equalquantities fromeachpointwerecombinedtomakeuptheAbsorption Pondcomposite. ATRSandAbsorption Pondstudyperiodcomposite wasalsoanalyzedfortheaboveparameters whichconsisted ofequalquantities fromthe18dailycomposites. Thecomposites wereusedaschecksonthedailyanalytical data.Anadditional setofindependent grabsampleswascollected overa28hourperiodduringandaftertheseconddemineralizer regeneration toprovidemoredetaileddataontheevent.Grabsampleswerecollected everyfourhoursfromtheTRSandcomposite samples(fourpoints)werecollected everysixhoursfromtheAbsorption Pond.Thesampleswereanalyzedforconductivity toprovidearelativeindication oftheshort-term effectsofdemineralizer regenerations. Page2of20 DataAnalsisandReortThedatafromthestudywascomparedstatistically usingSystatsoftware. Thefollowing comparisons andcalculations wereperformed toevaluatethedataandtestthevalidityofthestudy:-TheTRSandAbsorption Ponddatawerecomparedwithproposedgroundwater discharge limitstodetermine ifthelimitswouldbemetduringdemineralizer regenerations. -TheTRSandAbsorption Ponddatawerecomparedgraphically toensurethepatternsmatchedmassbalancecalculations. -Massbalancesforselectedchemistry parameters wereperformed including calculated versusactualAbsorption Pondvaluecomparisons. -ThestudydatawerecomparedwiththeNPDESdischarge monitoring datafrompastmonthstoensurethestudywasrepresentative ofplantoperations. Statistical significance isexpressed withapercentconfidence levelandmethod,whenappropriate. RESULTSPreliminar SurveandPondVolumesInitialconductivity measurements indicated thepondsweremixinguniformly. Conductivities rangedfrom310-328uSintheAbsorption Pondandfrom340-347uSintheOverflowPonds.Itwasconcluded thattheTRSdischarge plumewasmixingveryquicklyandthattheselection ofsamplepointscouldbebasedonrepresenting equalareasoftheAbsorption Pondcomplex.ThefoursamplepointsshowninFigure2wereselectedonthisbasis.Depthreadingswereobtainedat60locations intheAbsorption Pondandat15locations intheOverflowPond.Depthcontourmapsweredeveloped fromthisdataforthetwoponds(Figures3and4).ThemaximummeasureddepthoftheAbsorption Pondwas19.0feetand4.7feetfortheOverflowPond.PondsurfaceareasandvolumesareshowninTable1.Thetotalwatersurfaceareais2.21acreswithacombinedvolumeofapproximately sixmilliongallons.ThisprovidesadailyTRSdilutionfactorofalmost20:1basedona301,000gpdaverageflowrate.Page3of20

18DaStudTheTRSwaterchemistry remainsrelatively constant(normalTDSrangeof130-170mg/1)exceptfollowing MakeupPlant(MUP)demineralizer regenerations. Thesulfuricacidandsodiumhydroxide usedtoregenerate thedemineralizers sharplyincreasethesulfate,sodium,conductivity, andTDSlevelsforapproximately 12hours.Theregenerations areconducted onanasneededbasisandaveragedonceper12daysduringthelastsixmonths.Thetrendistowardmoreinfrequent regenerations asoperation ofthereverseosmosis(RO)unitisrefined.Analysisresultsforthe18daysamplingperiodfortheTRSandAbsorption PondarelistedinTable2.TheanalysisresultsfortheTRSandAbsorption Pondarecomparedgraphically inFigures5through14.Evenfollowing demineralizer regenerations, thestudiedchemistry parameters remainedwellbelowtheproposedgroundwater limitsintheAbsorption Pondwiththeexception ofdissolved aluminum. Thesharpincreases inconductivity, sulfate,sodium,boron,andTDSaredirectlycorrelated withMUPdemineralizer regenerations. Thetwoboronpeaksarethoughttobeduetothereleaseofboronfromthecationbedsduringtheregenerations. ALakeMichiganboronlevelof83ug/lwasreportedinour1990NPDESPermitapllication. Theamountofboronremovedfromprocessing approximately 4-5milliongallonsofLakeMichiganwaterbetweenregenerations wouldaccountforthepeaks.Thedissolved aluminumexceededorequaledproposedgroundwaterdischarge limitsintheAbsorption Pondoneachday;dissolved aluminumvaluesrangedfrom50-140ug/lcomparedtoalimitof50ug/l.AluminumlevelsintheTRSareelevatedduetotheuseofalum(aluminum sulfate)atanaveragerateof300poundsperweek.Higherratesareusedduringturbidlakeconditions. Therewasexcellent correlation betweentheTRSandAbsorption Pondresultsforallparameters studied.Table3liststhemultiplecorrelation coefficients (R~),F-Ratiosforthelinearregression tests,andsignificance level(p).Inmostcases,theprobability oftheTRSandAbsorption Pondchemistry parameters notbeingrelatedislessthanO.l<.Thecorrelation betweentheTRSandAbsorption Pondcouldbeimprovedslightlybycomparing Absorption PonddataonedaylaterthantheTRSdata("lagging oneday").Thisprobablyreflectsthesamplingtimedifference: 1000hoursfortheAbsorption Pondand2200hoursfortheTRS.Thisindicates theAbsorption Ponddataarereliableinassessing thetrueeffectsoftheTRSonAbsorption Pondwaterchemistry. Page4of20

Massbalanceswerealsoconducted following theregeneration eventstofurtherdefinethevalidityofthestudy.Thecalculated concentrations fortheAbsorption Pondfollowing regeneration arereasonably closetotheactualconcentrations obtainedfromanalysis. Theresultsarepresented inTable4.Amoreintensive short-term studyoftheeffectsofregenerations onTRSandAbsorption Pondwaterchemistry wasconducted onJanuary4-5,1994.Theconductivity resultsareincludedinTable5andshowngraphically inFigure15.TheresultsindicatethattheTRSreturnstonormalwaterchemistry approximately 12hoursafterthestartofaregeneration. Thedataalsoindicates thattheAbsorption Pondmixesveryquickly,therebybuffering TRSchemistry spikes.XnadditiontomeetingtheproposedlimitsfortheTRSdischarges, installation ofthereverseosmosis(RO)unithasresultedinamarkedreduction inlevelsofgroundwater contaminants. Figure16illustrates thewaterqualityeffectsofoperating theROunittoreducedemineralizer regenerations ontheTRSandgroundwater Wellf11,theclosestwelltotheAbsorption Pond.Astheplantbecomesmoreefficient atoperating theMakeupPlantandotherimprovements aremade,weexpectthistrendtocontinue. CONCL'USZONS ThequalityoftheAbsorption Pondwaterenteringtheaquiferwaswithintheproposedgroundwater limitsforalloftheparameters studiedexceptfordissolved aluminum. Thealuminumlevelswerestillverylowandwillbereducedbelowthe50ug/1limitonceplanstoreplacealumasaflocculant arecompleted. Therefore, theTRScompositor samplecancontinuetobeusedfordischarge monitoring withassurance thatthegroundwater limitswillbemet.MixinganddilutionofTRSdischarges withAbsorption Pondcomplexwaterprovidedabuffering effectresulting instablepondwaterqualityevenduringdemineralizer regeneration periods.Otherthanaluminum, theaverageconcentrations ofthechemicalparameters studiedwereequaltoorlessthan60percentoftheproposedconcentration limits.Thisindicates that.thereis'substantial marginagainstexceedances shouldplantoperating conditions deviatefromthenormalconditions includedinthisstudy.Fromthetrendsingroundwater welldataoverthelastyear,itisalsoapparentthattheCookNuclearPlanthasmadegreatstridesinimproving groundwater discharge quality.Weexpectthistrendtocontinuewithfurtherrefinements ofourMakeupPlantandinstallation oftheneutralization tankandnewsewagetreatment facility. Page5of20

Tablel-PondVolumesandAbsorption AreasAreaVolumeLocationAbsorption PondOverflowPondConnecting StreamTotalSq.Feet62,29130,0563,92096,267Acres1.430.690.092.21Cu.Feet704,60685,3963,920793,922Gallons5,270,453 638,76229,3215,938,536 page6of20

Table2-TRSandAbsorption PondAnalytical Results(mg/l)Day'ulfate SodiumChlorideTDSTotal-AlDissol-Al Total-BDissol-BCond(uS)pHTRSAPTRSAPTRSAPTRSAPTRSAPTRSAPTRSAPTRSAPTRSAPTRSAP53NN10N150N0.50N0.10N0.04N0.05N261N7.22N53886.22210111502000.800.400.070.090.040.060.060.062633637.197.252964.848914.755908.59112310102310101502101502200.580.671602200.890.200.240.250.090:050.060.190.070.050.140.140.050.060.060.060.060.070.050.060.050.062672752653657.257.23727.167.23627267010121314851001649945555978.360925.94809419047110511106.353110521105.6511005.924101122101122111123101123111025111028111128103010103110101702100.901302101.601402001.201402000.757401901.101302200.911401900.971302100.981302101.601401901.500.220.260.250.320.310.230.360.330.350.500.090.150.060.11<.050.060.160.100.050.150.060.060.090.080.120.120.080.060.300.070.050.300.100.050.200.100.060.300.070.050.060.060.060.060.060.060.060.060.060.060.060.062810.050.062760.050.062750.030.062870.110.0611350.040.063060.060.043000.050.062690.050.053030.050.062513797.087.03816.997.1376706713657.607.23697.677.14157.447.24067.427.14067.727.44207.497.64257.607.615471105.51668011026017186513014N120NAvg.11310331Comp35011015091038N102610102911102810102710101501901.809602200.161602600.61N240N2232110.976002200.660.500.270.380.280.310.290.170.090.050.500.070.090.160.200.16N0.07N0.170.090.060.300.080.10.060.060.060.070.060.060.050.053030.090.0617000.150.06284N0.06N0.060.064060.110.069894107.307.03957.187.6450719703997.166.83427'07.13997.166.8Page7of20 0 Table2-Continued ThefirstTRSsamplewascollected atapproximately 2200onDecember19,1993(Day0).TheDay0datawasincludedintheTable3linearregression modelwhenTRSdatawasshifteddown(lagged)oneday.ATRSsamplewasnotcollected ontheeveningofthefinaldayofthestudy,January6,1994.Demineralizer regenerations wereconducted onDay9(December 28)andDay16(January4).2.Studycomposite samplesconsisted ofcombining equalquantities ofthedailycomposites fromtheTRSandAP.Themuchhigherthanexpectedanalytical resultsfortheTRScomposite arebelievedtohavebeencausedbytheinadvertent additionofagrabsampleduringthe28-hourregeneration study.Page8of20 t' ~~~~r~~~~~~~~~~~~~~~II0~~IIIIIII~IIIIIIIII~II~I~~~~~III~~IIIII'I~~I~~~~--~~I~~~~~~~>~~I~II'~e~00I~~e'IIIIIII~II~~IIIIII~~III~I~I~I~~I~~-~~II~I+I~i~IIIIIIIIIIIIIIII~~0~~~~I~0~~~~~~~~0~~~IIIo--o0~~~~~~0~~~~~~00~~~I'.~~0~

0~.-~0=~~~-~e~~~~~~~e~e"R5RR.%5II~IIIIII~~~~~eIe~I~~~i~~iRRIII~I~~~II~~e~1~~~e~~~e~~e~e~e~~ee~e~eI~e~ee~eI~l~e~~e~~~~eeea're~.I~e~~~4rer4~e-I~el~e~~~~lee~.~~eee~~~0e

Table5-Regeneration EffectsonConductivity (uS)overa28-HourPeriodTime80010001200160020002200240040080010001200263NA6,8202,380367NA195200256NA245Abs.Pond395NA470NA447NA436NA445NA1.MakeupPlantdemineralizer regeneration discharge fromtheTRSbeganatapproximately 1140hoursonOl/04/93. Page11of20 ~>g<>B1-CookNuclearPlant,Absorption PondComplexandWLL~~CRSL40tWPlant/)Cj-'L'~Llaw~v0OLP(LISverfloPONDI-~.'~~".Page12of20 Figu1e2-Absorption PondandOverflowPondSampleLocations Absorption PondConnecting Stream(392feet)OverflowCulvertp/y/IlgX=SampleLocationP=PumpLocationOverflowXPondPPage13of20 Figure3-Absorption PondDepthContours/go)PEtj>'rroFigure4-OverflowPondDepthContours41Page14of20 Figure5-conductivity 200015001000O005000IIIoi2oisereoio>>iaisi4isieirieDAY----APTRSFigure6-pH1.00.9~ApH8.50.80.7~pH6.50i2s4sereoioii1213i4isieirieDAY----LOGAPLOGTRSLOGMAXLOGMINPage15of20 Figure7-Sulfate700600500O)4pp~300CO2001000120458189101'11215141518ll18OAY----APTRSLIMITFigure8-sodium3002000~~0001204587881011121814ld181718DAY----AP-TRSLIMITPage16of20 Figure9-Chloride300200l0Z0100012Q45018910111218)4151Sll18DAY----APTRSLIMITFigure10-TotalDissolved Solids1000800600203P4002000120~55760101112181415151118DAY----APTRSLIMITPage,17of20 Figure11-TotalAluminum2.01.52i.00.50.00125455I8910111213141$15ll18----AP-TRSDAYFigure12-Dissolved Aluminum0.6~04E0g0.2O0.0///~efIIA/NI----AP-TRSLIMIT0125455I89101112'51415151718DAYPage18of20 ]i Figure13-TotalBoron0.200.15ECo010OK00.05iI'iIII'iII'\IIIIIIIIIIII0.000i20~sersoioiii2iewisieiris----TRSAPDAYFigure14-Dissolved Boron0.150.10CQ0CCl~oQQ5O\IIIIIIII0IilIIIIIIII~~~IIIIIII0.00III0i204sdI8010ll12lslaisieil18----TRSAPLIMITDAYPage19of20 Figure15-EffectsofDemineralizer Regenerations onTRSandAbsorption PondConductivity Overa28-HourPeriod700060005000>,4000O3000O020001000I(IIIIIIIIIIIII\I\IIIIIIII0481216202428HOURSAPFigure16-Decreases in1993Chemistry Parameters forGroundwater WellN11andtheTRSDuetoROUnitInstallation andReducedRegenerations 15001000500123457101112MONTH"---""WELLSO4-------WELLNA---TRSS04-TRSTDSPage20of20

.~SEEINSTRUCTIONS 'wNREVERSESIDEr"':SECTIONIrearllEPAI.D.NuMSER MID0'98647621NUMBER-~MI0005827APPLICATION FORDISHARGEERMITIICOIFIQTICN EXI~IICINEIfIICREASEO USEREISSUAtCE 5t'00EI'--lTEMA.PARENTCOIPANY~CEPTI'ADER"- INDINMICHIGAN0WERCOMPAB.DIV./RmUN/APHYSICALLOCATIONADDRESSFeSlREEfIAISERoe'G,ISTREETNVECOOKLACCPLANfORFACILITYn"O'PK'PLANT'TM,",,E"L' "CTRICGE'ESTAIOARDIIEXISTRIAL CLASSIFICATION (REFERTOTAREIII)L44911I~ANOINFORMATION 'eCllYNA%RIGMANMlIeZIPCODE46'eTQIISNIPLKE%RIENCOeH4%CORISER~LeNt%OFAUIHXIIZEDCONTACTPERSON0NALDLBAKERNeTIllEENVAFFAIRSIR2194.25~211OeAIXRESS(IFDIFFEREHf FRIIABOVE)110EWAYNESTEETPeCITYNAIEonF0TWAYNEOeSTAlEReZIPCXE46802SelYPEOFTREATIEHT FACILITY(REFERTOTABLEII)~1L~1~2~3A~4GTePRXRAIIRNIEFFECTIVE RESIDLNLSIIANG9%Ãf DATESLDNITTED 0YES'HS'N.A,DATEIIPLIIEHIED UeBACK~ICIERSOLRCEzVeFOUllfION IIN:ICEHT PREVEHTION PLAN11/18/92DATESIEHITTED 906XelYPECFDISCHARGE ~~QYeRIVIXINAVEACERTIFIED OPERATCII? El~Cl0+D.H.Fetearalde,e,g~atr 9~ro~4992ITEM2A>>tiVERBoNA%MENGEMAILINGADDRESSOFAPPLICANT CeSTREETABÃE%CRPOSTOFFICEBOX110EWDoCllYNVEFORTWYNESREETEeSTATE~INFeZIPaXE46802REOUIRIOSIGNATISIE I~theooollcsnt, <<ertltvunderDensltvotIsvthstIhoveoersonsllyexercised ondsootsnlliervlththeIntorsestlon subeoltted InthisooDIIcstlon ond~IIottsctveeents ondtn4t,bssedonovInoulryotthoseIndlvlduols lerooedlotely resoonslble forobtslnln9 theIntoetootlon, Ibelieveth4ttheInteretioIstrue,occur4te4ndccslots.Ieoversth4ttheresre5lonlflcsnt oenoltl~5rorsubnlttln9 tolseInfection, Includln9 theDO$5lblIltyotfinesndIeaorlsoevoent, SIGNATURE OFAPPLICANT ch~.R.C.Mene~/<9(9'4>>.,President SIGNATURE OFLOCALGOVERNIIIITAL REPRESENTATIVE (SEENOTEONREVERSESIDE)TITL15 (~"'.v>>~\>a2'm~'I>j,INSTRUCI'IONS FORCCMPLETING SECTIONIlIIi'r'(>(r"I"~'Th<5farmrequlreSInfcrmat(cn abOutthefaCllltyaddreSS>,di5Charge IOCat(On, PlantCOntrOIS, tyPeOfdl5PO5alfaCIIltYandname.'""address,andsignature oftheapplicant"'and 'local'governmental representative. kEnterEnv(rorvrrental Protection Agency.lOcNumber-')f available. "'-,"-*"-"ENTERTHEPERMITN<MBERIN,THEBOXAT"THETOPOFTHISFORM.THEPERMITIAIMBERCANBEFOUNOONTHEFRONTPAGE,OFYOUREXPIRING',<<c,pERMIT.,lfthisis,anevornotpreviously permitted

facility, thenleaveblankandanumberwillbeasslqned.,

>yZC>,rInthebox"Application ForOlscharga PermitIsycheckoneofthefivecategories (modification, existingunperm(tted> ne<<>Increased use,orrelssuance) <<hichyourpermitapplication fallsInto(seepagel4fordefinitions). rrITEMIPHYSICALLOCATIONAOORESSANOIUFORMATION r'A.-C.EnterthenamingInformation Inaccordance withthefollowing: Zew-ForIndustrial facilities, provideTheparentocmpanyname(A.),thedivisionnew(8.),andtheplantname(c.).rr-Forfederalandstatefacilities p'rovldethedepartment. new(A.),thedivision,or.,the bureau.name(8.).andthefacilitynew(C.).il-Forcorrrwrclal facilities providetheowner'5name,doing-business as<d.b.a.)(A.)andthefacilitynew<C~)~f!""'O.Entertypeoffacility. Exeaoles'ofthisarecfoundry;highschool;autarratlc carwash;drycleaners; self-serve laundromat. ~~.>E.RefertoTableIII(page5)forthelistofStandardIndustrial Classification Code<SIC).Enterthecodenumberthatbestdescribes themajorproductorserviceproduced. F.-l.EhterthePhySICalIOCatlanOfthefaCIllty.OONOTuaePOStOff(CabOXnrmrber..e't,Z)tJ.-K.Lo-RoU.VoEnterthetownshipandcountyInwhichthisfeellltyIslocated.ThecountycodenumbercanbetoundInTableI(page>5)~Enterthenew,title,addressandtelephone nrmrberofthefacility's authorized contactperson.ThisDersonshouldbethoroughly ferrlliarviththefactsreportedontheseformsInthe.eventthatcontactregarding thepermitapplIcationmustbemade.RefertoTableII(page5)forthelistofTreatment FacilityTypes,enteruptofivemethodsusedbythefacilitytotreatthewastewater. F4'>MrIndicatewhetherthisfacilityhasa"Residuals Management Plan".Itso,enter'date planwa5submitted andthedatetilePlanwasorIstobelmplewnted. Suchaplanmaybeneededasdeemedappropriate by.theproperOlvlslon5taffIndicatevhetherthewastetreatment facilities haveaback-upsourceofpaverorwhetheremergency procedures havebeendeveloped Incaseofapoweroutagetothewastetreatment facility. Ifthewastetreatment feellltyIsnotdependent onasourceofpover,checkthe"NA"box.UJIndicatewhetherthisfocilityhassubmitted apollution Incidentprevention planasrequiredundertheMichiganwaterResources Corrmlsslon Part5Rulesforthe"SplIlageofOlIandPolluting Materials". J'ffacilityhassanitaryvastevater (voterusedfordawstlcpurposes; ~,g.~toilets,, slnk5~shover5). enterthenurrrberofpeopleusingthisfacility. X.Checkthetypeofdischarge(s) franthisfacility. Indicatewhetheryourwastetreatment orcontrolfacilities areunderthesupervision ofacertified operator. Ifyes>pleaseprovidetheOerson'Snew,SOClalsecuritynrmrber,andcertificate numberplustheccneany'S feellltynrmrber.ITEM2MAILINGAOORESSFORALLCORRESPONOENCE A.providethenewoftheaDDIIcant. Forthapurposesofth)5apol(cationtheapplicant IsdefinedastheDersonsigningbelowInaccordance withthedirections providedonpageld.Correspondence regarding thisapplication andfuturepermitmattersvlIIbesenttotheapplicant. B.providethenewofthefacility, company.ororganization whichtheapplicant In"A."aboveusesforreceiptofmallc.~,providetheapplicant's addresstobeusedforfuturecorrespondence. SIGNATURE OFLOCALGOVERQCENTAL REPRESENTATIVE NOTE:IfsanitarysavageIstobedischarged fromhousingdevelopments, apartment bulldlngs,shoppingcenters.orothercorrrwrclal developments, Into5systerrotherthananapprovedmunicipal sanitaryvestacollection system,thisapplication 5hallbeco-signed byanauthorized municipal officialortownshipofficer.ItIstheruleoftheCarmlssicn thatapplications Involving thedl5po5alofsevaoeofhumanoriginfromanyentityotherthanlocalgovernment shouldIncludethelocalgovernment asaco-5lgner ofthestatement, andthatelIproceedlng5 andhearingsagainstsaidentity<<IIIIncludethelocalunitofgovernment a5apartybyappropriate notice,andallpermits155uedas5re5ultof5uchhearlngsandproceedings vllIbetIledjointlyagainstthesaidunitandentity<waterResources ccnmlsslon part5RulesR525.IO)8<5) andtheMichiganWaterResources Ccnmlsslon Act245P.A.ofl929asamendedSection6<b)).Thisco-signature requlr<<rent IsonlyaDDllcable tosanitarysewagedischarges andIsnotforanynonsanltary wastestreamsfromthisfacility. SEEINSTRUCTIONS ONREVERSESIDEA.IXXIICIPAL 3BeQRFACEMATERINTAKESECTIONIPERMIT~MIppp5827NUMBERLAKETOWNSH~IPLAEMICIGAteeSOURCEOFWATERSUPPLYCePRIYAlENEILDeOlMEROUANnTY(we.)auveITY(NAx.)NA2651616000~NAITEMFACILITYWATERUSAGEoIjwrm(we.)A>>PROCESSMATERINCLIDI%CONTACTaXX.ImMATER)ouANTITY(BeH3NCONTACT COOLI%MATEROOANTITY(we.)CeSANITARYMATERaewrTY.)DeOTIER6344000~DAY642112000SAIIDNs/DAY 60000~DAYFIREPROTECTIONWTER3600000~DAYITEM5aewrmHYDRAZINE 003020126500~TAEARCRITICALMATERIALS &PRIORITYPOLLUTANTS USEDSTOREDPRODUCEDCLWTITYt4VKOFSIBSTANCE PARA%TERIAPSERONNTITYCHLORINESODIUMC07782505357500KYLENE013302~072500REFERTOTABLESIV&VTOLUENE00108831POUNDS2GALLONS3CUBICYARDS4TONSCL'lIAIOOANTITYLITHIUM(LithiumHdroxideform)CLASS02HYDROQUINONE L>>It>>PARAIETER IAPSERasorllYMERCURY00123319CLASS021u/YeROIMIfllY*L~J/YeRxTotalquantityunknown,contained inthermometers, barometers andmercoidswitcheslocatedthroughout theplant. INSTRUCTIONS FORCOMPLETING SECTIONIITEMS3,4,AND5ThisformrequiresInformation aboutthewatersupplytothefeelllty,thefeellltyrswaterusage,andcrltlcalmaterials andprlorltypollutants used,stored,orproducedatthisfeelllty.ENTERTHEPERMITICMBERINTHEBOXATTHETOPOFTHISFORM.THEPERMITNUMBERCANBEFOUNDONTHEFRONTPAGEOFYOUREXPIRINGPERMIT.IfthisIsanewornotpreviously permitted feelllty,thenleaveblankandanumber'ill beassigned. ITEM3SCURCEOFMATERSUPPLYListallwatersuppliesused.Thevolrmremaybeestimated froyrwatersupplymeterreadingsorfrombllllngstatements froma~stersupplyutlllty.IfwaterIsnotmetered,estimatetrcmprmrpcapacity. MhereanameIsrequired, enternameofwatersupply;e.g.,Mudl.ake,HuronRiver,ortheCityofMillpond. ITEM4FACILITYMATERUSAGEListamountsofwatertobeusedforvariouspurpo5e5asrProcessMater-seeGlossarytordeflnltlon lpage48).Noncontact CoolingMater-seeGlossaryfordetlnltlon (page48).SanitaryMater-Materusedfordcmestlcpurposes; e.g..toilets,sinks,showers.IfwaterIsfirstusedfor'napurposeandthesrme~sterIssubsequently u5edforoneorInoreotherpurposes~IndicatethevolrmwrperdayottheInstdesignated usebetoretreatment and/ordischarge. Forexample,IfwaterIsInltlally useda5noncontact coolingwaterendthenasprocesswater,thequantityot~stergivenshouldbeIndicated asprocess~ster.ThetotalofItem4shouldequalthetotalofItem3.Anydifference Inthesetotalsshouldbeexplained Inanattachedsheetofthisappllcatlon. ITEM5CRITICALMATERIALS ANOPRIORITYPOLLUTANTS USED,STOREDPRCOUCEDListallchemicalsubstances whichareInMlchlgan's CrltlcalMaterials RegisterTableIVlpage6)and/orU.S.EPA'sPrlorltyyetlWtLitttebley(beeyttbteeetlyM.t~.rKddbytbl~teblllty. SEEINSTRUCTIONS ONREVERSESIDESECTIONIPERMIT~MI0005827NUMBERITEM3AeNltlCIPALSOURCEOFWATERSUPPLYPRIVAlEMElLouAttflTY (we.)ouANTITY(we.)aulnNs/DAv auUINs/DAv tTEM4FACILITYWATERUSAGEAsoautfITY(we.)PROCESSHATERINCLLDIt6CONfACTCCOLImHATER)OOANTITY(rMINCONTACT CXILIt6HATERtxtANTITY (we.)SANITARYHATEROTIER(we.)aulnNsJDAY~DAVGAllnNS/DAY aulnNs/DAv ITFM5IOOOITITYMERCURICNITRATECLS+W/YEARCRITICALMATERIALS PRIORITYPOLLUTANTS USEDSTOREDPRODUCEDKQJNIxNA%OFSISSTANCE PARA%TERtltSEROOANfllvNttKOFQSSTANCEMERCURICSULFATECLSSQ21CHROMICACIDCLASS015L~J/YEARREFERTOTABLESIVaVNAIEOFQBSTANCEPARAtETER MJSEROautfITYCHLOROFORM 63XJ/YEAR1POUNDS2GALLONS3CUBICYARDS4TONSCLQlIAIXNAIEOFQEISTAM:E PARAtETER MPEIERoSutfllYCLASS017WITSLXI/YEARPARA%TERMJSERoUutfllYNAtKOFQSSTAtCEPARAIETER MHKRouANTITYSOS01332214T/mL~J/YEAR"Contained ininsulation .throughout plant;believednottobepresentinthedischarge. 17 INSTRUCTIONS FORCOMPLETING SECTIONIITEMS3,4,AND5ThisformrequiresInformation aboutthe~atersupplytothefeelllty,thefeelIlty'swaterusage,andcritteatmaterials andprlorltypollutants used,stored,orproducedatthIsfaclllty. IENTERTHEPERMITISMBERINTHEBOXATTHETOPOFTHISFORM.THEPERMITNIPRIERCANBEFCVNOONTHEFRONTPAGEOFYOUREXPIRINGpERHIT.IfthisIsanewornotpreviously pen((ltted feelllty,thenleaveblankandanumberwillbeassigned. ITEM3SOURCEOFWATERSUPPLYl.lstallwatersuppliesused.Thevolu((emaybeestimated frcmwatersupplymeterreadingsorfrcmbllllngstatements fromawatersupplyutlllty.If~afarIsnotmetered,estimatefrompm((pcapacity. whereanaeeIsrequired, enternameof~atersupply;e.g.,MudLake,HuronRiver,ortheCityofMillpond. ITEM4FACILITYWATERUSAGEListamountsofwatertobeusedforvariouspurposesas:ProcessWater-seeGlossaryfordeflnltlon lpage48).Noncontact Cooling'Water-seeGlossaryfordeflnltlon Ipage48).SanitaryWater-Waterusedfordomesticpurposes; e.g.,toilets,sinks.showers.If~aterIsfirstusedforonepurposeandthesanewaterIssubsequently* usedforoneormoreotherpurposes, Indicatethevol(m>>perdayofthelastdesignated usebeforetreatment and/ordischarge, Forexample,IfwaterIsInltlally usedasnoncontact coolingwaterandthenas"processwater,thequa'ntlty ofwatergivenshouldbeIndicated asprocesswater.ThetotalofItem4ShouldequalthetotalofItem3.Anydifference Inthesetotalsshouldbeexplained Inanattachedsheetofthisappllcatlon. ITEM5CRITICALMATERIALS ANDPRIORITYPOLLUTANTS USEDSTOREDPRCDUCEDListallchemicalsubstances whicharelnMlchlgan's CrltlcalMaterials RegisterTableIy(page6)and/orU.S.EpA'sPrlorltyPo((utt(((tT((V((((((7)((t(nt(y~.(~.(~d((y(((~((('((((y. SEEINSTRUCTIONS ONREVERSESIDESECTIONIPERMIT~Mjppp5827NUMBER~EM3SOURCEOFWATERSUPPLYAee'VIICIPAI.BeSLRFACE'iJATERIteTAXEC~PRIVATEWELLD.OTnEReeIXI>>eITTYuVl~%OF'ee'TER'eIAV ~MITITY"'AX,)".JAIITITveuM.)P>>FVIIiIIIGALLOteDAY'eALLCeDAYcAt'te'oAvITEiVI"UAIITITY uAX.)A~PROCESSWATER(IIJCLtXIIIJS COIITACTCOOL!tlSWATER)>>LeAeITIVeB.IIOIICNITACT CCCLIMWATERQUAeYTITY(FAX.)~IIIIIite'DAvEA'";JS/DAYCALLNIS/OAT FAGILITYWATERUSAGEC,SAIIITARYWATERO.OTHER".UAIITITYIFAX.)SP<4I>>eITITY'uAX.)BALI>>>>JS/DAY)TEM5CRITICALMATERIALS &PRIDRITYLLUTANTS'JSEDSTOREDIRODUCEDREFERTOTABLESIV&VIPOUNDS2GALLONS3CUBICYARDS4TONSIeIiIIelCetIlIAeZOFSUBST>>IJCE QUAtlTITYHAtlEOFSUBSTAIJCE PARAMETER tll'BEROUAIITITYtA%OFSUBSTANCE PARAIETER tILISEROUAI'llITYtIAuEOFSLSSTAIJCE eeETERtllSERCU"ITITYt~OFSL9STA'XE PARAuiPTER te?TSERtÃ%OFSUBSTAXCE NICKELNITRATECLIAS.S022ANTIMONYPOTASSUMCLASSO10IIII~~/YEARIAIITS~/vEARuttlTS~!YEARWITSLJ/vEARLIIIOIiIIePARAtETERtlltSEROUUITITY:~uEOFSLSSTÃICE PARAMETER Ill~IIIWITS~/YEARWITSLJ/VEAR17 I'ISTRUCTIONS FCRCCI~ZLETINGSECTICIIIITEMS3,4,<<ND5,his!cr.requiresinfomarlon about!newatersuoplvtothefacility, thefacility's water<<sage,andcriticaln'aterlals andprlcrltvpollutants used,stored>crproducedatth,isfociIltv.El)TERMEogc>>IT'dJ'cBQI)ITFEBOXATTFECPOFHISFCFM.'PERMITHU'VERCANBEFOU)d)C".wEcFONTc"'ŽOFYOUREXPIQING'ISIS0ewCrnotPrevlc'slyper<<Iec~pllivenleaveoianxan1urper<<'IoeassiITEM3""U-rc-NAQSU""Iv:s!all.<<atersuppliesused.Thevolueeb'avbeesrlnared fronwatersupolytaterreaclncsc"'rcnbill(rgs-are,enrs '.rc~aware!spiv~IIlry.>5waterIsrorre!epee~es!Iare'npurpcapacity. <<hereanaeisrecui0c,enternaeo.watersupplv:e~~i"udLake,riuronRiver,ortheCityofMlllpcnd.ITE>>"ACILITv.CATER'JSAGE:.ourtsof<<arerrcoeusedforvariouspurposesas:Processeater-seeGlossaryforceflnltlon (page<<8).'icnccntac! Cooling)rater-seeGlossary'crdeflnltlcn (pagec8).SanirarvRater-'Aaterusedfordcresrlcourooses: e.c.,rollers.sinks.snowers.<<arerisfirsrusedfcroneourposeancthesme<<arerlssuosequenrly usec'crcneor"creotherpurposes, lrclca!ehevclurecercavC.-helastcesicnarec usebeforetreatrenr and/orcischarce. ccrRxancie..'atet ~sln(tlallvusedasrcncontact tpci'"c*s!ersnc"snssprccess'<<a<<er,;he quanri7of.<<a!er"ivans<<pulebeinclcatec as:recess <<ater.'e-taicflre<<:-'houldecualthetora)cfItw3.Anvc(fference inthese!ctals should=.exolainec Iranattachedsheetofr<<lscoolication.ITc~a5PlICAL>>ATERIALS ANOPRIORITYPOLLUTANTS USED.SCRED.PPCOLCEDListallchenicalsubstances '<<nlchareinMichigan's Critical>>aterlals RegisterTableIV(page5)and/or"..EPA'sPriorityFolI>>tantListTableV(page7)thatarecurrenrlv used,stored,orproducedbythisfociIItv. SEEINSTRUCTIONS ONREVERSESIDESECTIONIBER~~MI0005827rEM6AsPROVIDEABRIEFDESCRIPTION ANDLINEDIAGRAHSHXIIIDTHEHATERFUXITHROXIHYQBFACILITYFR%INTAKETODISCHARGEs SHGHALLOPERATIONS CONTRIBUTING MASTEMATERs INCLUDING PROCESSAtQPRODUCTION AREAS>SANITARYFLOMSsCOOL!%MATERIANDSTtA%QTER RIPOFFsYOUHAYGIKXXSIHIIAROPERATIONS INIDASIIKsLEINITsllewMATERBAlANCESHXXJjSHXIAVERAGEFLOHS~QKHAU.SIGNIFICANT USESCFMATERTOPROOUCTSs ATQSPHREs ANDDISCHARGEs YOUSHXLDUSEACTUALHEASLR9%NTS HIeIEVERAVAIIABLFJ OTKRHISEUSEYOLBBESTESTIIQTEs DESCRIPTION (SeeattachedDescriptions) DIAGRANI19 INSTRUCTIONS FORCOMPLETING SECTIONIITEM6)ThisformrequiresInfomation aboutthe~aterflowthroughyourfacilityfromIntaketodischarge. ENTERTHEPERMITNUMBERINTHEBOXATTHETOPOFTHISFORM.THEPERMITNWBERCANBEFOUNOONTHEFRONTPAGEOFYOUREXISTINGPERMIT.IfthisIsanewornotpreviously permitted

facility, thenleaveblankandanumberwillbeassigned.

ITEM6DESCRIPTION ANOLINEDIAGRAMOFFACILITY'5 PROCESSES ANOTREATMENT SCHEMEA.Brieflydescribetheroutetakenby~aterInyourfacilityfromtheIntaketothedischarge andalsoprovidealinedrawing.ExampleDescription andOiaramNarrative: Therinsewaterfrcmthevariousplatingoperations Iscollected lnoneofthetwo35,000gallontanks.calciumchlorideandalenareaddedtoassist'nfluorideremovalandaidIncoagulation. ThewaterIsadJustedtoapHofabout5.5usingdilutesulfuricacid.ThepHIsthenraisedtoapHofaboutIO.3<<lthlimetoprecipitate themetalsashydroxide. PolymerIsaddedtoflocculate themetalhydroxides. Thewastestreamflowsthroughaclarifier, themetalhydroxide settlestothebottcmas"sludge". Thetreatedwaterflowsfrcmtheclarifier toamanhole~hereItccnmlngles withcontactcooling~aterfranthestripline.Thisccnmlngled ~aterIsdischarged totheBuckRiver.Thesludgefrcmtheclarifier goestoavacuolefilterwhereItIsdewatered. ThesludgeIslatertakentoalandfill. CalciumChlorideAlumSulfuricAcidLimePolymerPlatingWastewater 70.000GallonTankAcidification NeutralizatioFlocculat1on BatchBumpsDumpTankSludgeThickener Clarifier Hon-contact CoolingHaterCalciumChlorideAlmaSulfuricAcidLimeLandfillVacuNaFilterGondolaSludgeIiaterHanholeBuckR1veJohnOoe,Inc.,Oeertown, manufactures sleevebearingsforautoeotive andtruckengines.Production IsdividedInto3phases.MetalpowderlsproducedInthefirstphase.Thisisacconpanied bymeltingcopper>tinandleadIntoIngotsinanelectricfurnaceandapplyingaJetofwatertoquenchendsolidifythemeltingmetalIntopowderform.Thesecondphaseconsistsofadheringthefinemetalpowdertoacollofsteelbypassingthetioslowlythroughfurnaces, Waterusedtocoolthestripconstitutes thecontactcoolingwater.Bearingsarethenformedandmachinedfromthecoatedsteel.Inthethirdphase,mostbearingsreceiveanickelstrikeandlead,tincopperelectroplate. Theremaining bearingsarealuminumorbabbittandreceiveatinorleadplate.Rinsewaterbeforeandafterthevariousplatingoperations constitutes theprocesswater.HunicipalMaterSupp'lySanitaryFacility30,000gpdHunicipa1Treatment StdfsafaterStr1peLine295.000gpdPowderHfg.4000gpdCoolingHater250,000gpdPlatingProcess40,000gpdMasteTreatment Plant45,000gpduckR1ve20 Additional Information SectionIItem6,SubpartACookNuclearPlantGroundwater PermitApplication OutfallOOD-DescritionofUtiliWasteWatersUtilitywastewaterfromwithintheplantisdischarged intoanon-siteabsorption pond.Theultimatedisposition ofthesewastewatersistothegroundwhichventstoLakeMichigan. Thewastewatersinclude:WASTEWATER FLOWDIAGRAM41Wastesfromthemakeupwatertreatment system.Themaincontributors tothewastestreamare:themakeupplantdemineralizer regeneration wastes(avg.40,000gallonsperregeneration), degasifier pumpsealwater(108,000gpd),carbonfilterbackwashwater(avg.45,000gpd)andpre-filterbackwashwater(avg.72,000gpd).Theretention tankperiodically discharges averysmallvolumeofsolidmaterialremovedbysettling. Alum(aluminum sulfate)isaddedtothepre-filter influentasaflocculent. Thesepre-filters arebackwashed totheTRStoremovethesuspended mattercapturedonthefiltermedia.TheAlumcontained inthebackwashisdischarged totheTRSintheformofinsoluble aluminumhydroxide. Carbonfiltersarealsoperiodically backwashed totheTRS.Thesefiltersprimarily removeorganics, chlorineandsmallamountsofiron.Sulfuricacidandsodiumhydroxide usedbythemakeupdemineralizers toregenerate theresinarerinsedtotheTRSandgenerally neutralize eachotherinthesump,formingsodiumsulfatepriortodischarge. Non-essential servicewaterisusedtosupplyvacuumdegasifier pumpswhichutilizeapproximately 75gpmtotalviatwopumpstoremovedissolved gases(primarily carbondioxideandoxygen)fromthevacuumdegasifier andexhaustthemtotheatmosphere. Anewcomponent ofthemakeupplant,areverseosmosis(RO)system,hasbeeninstalled toremovethebulkofthedissolved solidsfromthelakewaterpriortodemineralization. NormalrejectwaterflowistoLakeMichigan. TheROsystemmustmaintainverycleanmembranes toassureefficient operation andpurityofwater.Severalmethodsareusedtomaintainthislevelofcleanliness fromscaleandbiofouling. Usinghydrochloric acidorsulfuricacid,thefeedwaterpHisloweredtoreducethescalingtendencies ofthewater.Approximately oncepermonthaflushisperformed usingapproximately 0.5%hydrochloric acidandcaustictodissolveanyscalethatdepositsonthemembranes (avg.5000gallonspermonth).Achemicalcleaningisperformed whentheperiodicacidwashesnolongerareeffective. 19a Additional Information SectionIItem6,SubpartACookNuclearPlantGroundwater PermitApplication WASTEWATER FLOWDIAGRAM41(cont.)Thechemicalcleaninginvolvesseveralstepsandmaycontaincitricacid,hydrochloric acid,phosphoric acid,sodiumhydroxide andaneutralpHdetergent (avg.10,000gallonsperevent).Also,toremovedeadbiological matterfromthemembranes, asoakusingsodiumbisulfite maybeperformed asnecessary, approximately onceperyear(avg.5000gallonsperevent).WASTEWATER FLOWDIAGRAM42Duringperiodswhennotinoperation, theheatingboilerisstoredfulloftreatedboilerwatercontaining atmost400ppmhydrazine (foroxygenscavenging) and50ppmammoniaor50ppmethanolamine (ETA)(for corrosion protection). Priortouse,this"wetlay-up"waterisdrainedtotheTRSfordischarge intotheAbsorption Pond.Thevolumedrainedisapproximately 1600gallonsandmayoccur30timesperyear.Duringaunitoutage,thecondensers arecheckedforleaksbyfillingthesteam'ide withcondensate containing approximately, 1000gramsoffluorescein disodiumsaltorRhodamine B.Thesedyesarefluorescent underblacklightwhichaidsinthedetection ofjointandtubeleaksduringvisualinspection. Thevolumeofwaterdrainedfromthecondensers rangesfrom160,000upto1,000,000 gallonsandmayoccuronetimeperyear.Inaddition, thecoolingwatersideofthecondensers aredrainedtotheTRSforgeneralmaintenance periodically (8condenser halvesperunit,approximately 25,000gallonsoflakewaterperhalf).Thecomponent coolingwatersystem(CCW)isperiodically drainedtoallowforequipment inspection, maintenance orrepair.Thissystemusesdemineralized waterfromthemakeupplantasitssourceofmakeupwateralongwithamaximumof1200ppmnitrite(fromCalgonLCS60)and100ppmglutaraldehyde astreatment chemicals. Theinfrequent drainings mayoccurandreleaseapproximately 60,000gallonsoftreatedwatertotheTRSperyear.Thedieselgenerator coolingjacketwatersystem(DJW) alsoemploysthesamechemicalcontrolforcorrosion asinthecomponent coolingwatersystemwithamaximumof2000ppmnitritesfromCalgonLCS60.19b

Additional Information SectionIItem6,SubpartACookNuclearPlantGroundwater PermitApplication WASTEWATER FLOWDlAGRAMg2(cont.)Thissystemisdrainedto'thefloordrainstotheTRSwhenmaintenance isperformed onthejacketwatersystem.Thesystemvolumeisapproximately 1000gallons.Anyminorsystemleakswouldalsobedirectedtothefloordrainduringnormaloperations. Theessential servicewatersystems(ESW)andnon-essential servicewatersystems(NESW)arealsoperiodically drainedtoallowforequipment inspection, maintenance, orrepair.Thesedrainsmaydischarge approximately 72,000gallonsofLakeMichiganwaterusedfornon-contact coolingintotheTRS.Thiswateriseitherchlorinated intermittently ataresidualconcentration of0.2mg/1TRCorcontinuously at0.036ppmtotalresidualchlorine. Duringsomespecialtreatment periods,thiswatermaycontainzebramussel,biocides, usedasamolluscicide forzebramusselcontrol.Periodically, components oftheESWorNESWsystemsmaybechemically cleanedtoremoveirondepositsusingvendorsuppliedcleaningsolutionsuchasEDTA(ethylenediaminetetraacetic acid)orascorbicacid,aceticacidandammonia.ThesewastescouldeitherbedrainedtotheTRSorLakeMichigan. Thesteamgenerators (S/G)aredrainedforinspection andmaintenance duringscheduled unitoutages(approximately every18months)andduringaneventwheresteamgenerator failureisdetectedthatrequiresaunitshutdown. Thesteamgenerators .utilize150ppbhydrazine, 20ppmammonia,and2.5ppmETAtocontrolthewaterandsteamchemistry tobenon-aggressive tocyclecomponents. Unit1steamgenerator alsoutilizes10ppmborontocontrolcorrosion. Asteamgenerator volumereleasedduringthedrainingisapproximately 32,000gallonseach.Duringwetlay-uptheS/Gsarestoredfullofwaterwithupto400ppmofhydrazine and50ppmammoniaorETAareaddedforcorrosion control.ThiswaterisnormallydrainedtosurfacewaterviaNPDESoutfallsOOAorOOB,butmaybedrainedtotheTRSinsomeinstances. Themiscellaneous draintankscanbealignedtodischarge totheTRS.Asmuchas350,000gallonsperdaymaybedirectedtotheTRStocontrolthe"chemistry limitations onthesecondary watersystems.Waterchemistry isprimarily thesameassteamgenerators. Aroundtheplantmiscellaneous sumpscollectapproximately 45,000gpdofwaterfromvariousequipment drains,leaks,pumpseals,steamjetairejectordrains,etc.19c ~9 Additional Information SectionIItem6,SubpartACookNuclearPlantGroundwater PermitApplication WASTEWATER FLOWDIAGRAM42(cont.)Thefrequency ofdischarge andtypesofchemicals usedinthisequipment havebeendescribed elsewhere inthisdescription. Miscellaneous floordrainsarelocatedthroughout theplanttoprovideasafeworkingenvironment byroutingspilledorleakedwatertotheTRS.Themajorchemicalinfluxintothesedrainsarefromthedetergents andwaxesusedtomaintainthefloors.AlsoroutedtotheTRSthroughthefloordrainsarethechemicalfeedtankdrains,fireprotection water,drinkingwater,coolingwater,anddrainsfrombioboxesusedtomonitorthezebramusselcontrolmeasuresandotherchemicalcontrolmonitors. Thechemicalfeedtankswhichmaybedrainedcontainhydrazine, ammonia,boron,ETA,sodiumhypochlorite. Thebioboxeswilldischarge chlorineand,duringzebramusseltreatments, zebramusselbiocides. Non-radiological chemicallabsinkandfloordrainsareroutedtotheTRSfordisposal. Thedrainscarrywaterandthewastesgenerated whileperforming analysesandpreparing laboratory standards including thoseontheattachedlist.Alsodischarged willbeglassware andnormallaboratory cleaningwastes.TheaveragevolumedirectedtotheTRSisestimated tobe500-1000gpd.Secondary (steamgenerator orcondensate) samplewaterfromcontinuous analyzers areroutedtodrainswhichdischarge totheTRS.Theanalyzers areonthecycleswhichmaycontainasmuchas10ppmboron,150ppbhydrazine, 20ppmammonia,and2.5ppmethanolamine. Theanalyzers measurecorrosion transport ataaverageflowof8500gallonsperday.Miscellaneous sealingandcoolingwatersuppliescoolingandsealingwatertotheTRSpumps,condensate boosterpumps,circulating waterpumps,vacuumprimingpumps,drainsealreservoir tanksanddrainsamplecoolers.Theaverageflowperdayisapproximately 150,000gallons.Non-essential servicewatersuppliesapproximately 53,000gpdofnon-contact coolingwatertovarioussamplecoolersthroughout theplant'sturbinebuildingincluding theConductivity RoomandtheSteamJetAirEjectorsamplepoints.ChemicalspillsthatentertheTRSmaybeneutralized withinthesumptopreventadischarge totheenvironment. Thepotential forspillstotheTRSexistsforthefollowing chemicals withtheproposedneutralizers listed:19d , Additional Information SectionIItem6,SubpartACookNuclearPlantGroundwater PermitApplication WASTEWATER FLOWDIAGRAMg2(cont.)ChemicalSulfuricacidSodiumhydroxide Sodiumhypochlorite Hydrazine Neutralizer Sodiumhydroxide SulfuricacidSodiumthiosulfate NESW(lakewater),HydrogenperoxideOutfallOOE-SanitarWasteDischaresWASTEWATER FLOWDIAGRAM43Sanitarywastesarepresently segregated androutedtotwoextendedaerationpackagetreatment plants.Theexistingequipment isdesignedtotreat50,000GPDandtheeffluentfromthesewagetreatment plantsdischarge intooneofthetwoseepagelagoons.Thelagoonsdischarge intothegroundwater withtheultimatedisposition beingLakeMichigan. Thesludgeremovedfromthesedimentation tankbasinsistakentoalocalPOTWfordisposalordewatered andstoredaslowlevelradioactive waste,asappropriate. Plantsanitarywasteconsistsofshowerandrestroomfacilities, janitorwashbasins locatedthroughout theplantnon-radiological property. Kitchenwastesaregenerated fromtheplantcafeteria, theEnergyInformation CenterandTrainingbuildings. Thechemistry traininglaboratory discharges tothesewagetreatment plantsviaalimestone bedneutralization tank.Thechemistry labisusedtotraintechnicians onanalysesperformed intheplant.Thedischarge fromthelabcarrieswaterandwastesgenerated whileperforming analysesandpreparing laboratory standards including thoseontheattachedlist.Asmallphotolabinthetrainingbuildinguses(onaemergency basis)smallquantities ofhydroquinone todevelopblackandwhitepicturesforplantuse.ThetrainingbuildingHVACsystemalsodrainstothelimestone bed.Aradiography labintheplantalsodischarges smallquantities ofprocessing chemicals fornon-destructive testingintheplant.Noneoftheproductsintheradiography labcontaincriticalmaterials orprioritypollutants. Allportabletoiletwastesontheplantsitearecollected anddischarged tothepackageplants.Abiodegradable deodorant isusedintheportabletoilets.Sludgeeffluentwastemayalsoberecycledthroughtheplantstodecreasetheamountofsludgeforprocessing whenpossible. 19e

Additional Information SectionIItem6,SubpartACookNuclearPlantGroundwater PermitApplication WASTEWATER FLOWDIAGRAM43(cont.)Miscellaneous rinsingofwastereceptacles andpossiblemiscellaneous cleaningoperations wasteutilizing variousdetergents mayberinsedtothesewagetreatment plants.Miscellanous OutfallWASTEWATER FLOWDIAGRAM44Themainplanttransformers oneachunitarelocatedwithinconcreteberms.Thebermsareforspillcontainment shouldacatastrophic failureofatransformer occur.Toprotectagainstoperational andsafetyconcernswhichstemfrompondedwater,theseareasgravitydraintooil/water separators specificforeachunit.Eachseparator isabelowgroundconcretebasindesignedtoretainoilandreleasewatertoaseriesofdrywells. Alsodischarging intotheseparators aretheemergency dieselgenerator pitsumps.Thesesumpscollectlimitedwaterandfueloil(lessthan500gallonsperyear)fromtheemergency dieselgenerator room.Periodically, theoil/water separators arepumpedcleantoremovetheaccumulated oilforproperoff-sitedisposal. TheSecurityDieselGenerator DaytankhasanoverflowlinethatconnectstotheUnitOnetransformer deckcatchbasin. Discharge tothecatchbasin wouldonlyoccurifthedaytankwereoverfilled. Procedures andlevelindicators areusedtopreventoverfilling. CHEMICALLABANALYSISAdditional Information SectionIItem6,SubpartACookNuclearPlantGroundwater PermitApplication PLANTCHEMISTRY LAB(toOutfallOOD)ChlorideFluorideHardnessHydrazine SilicaOil6GreasepHFreeMineralAcidityTotalPhosphorus ChemicalOxygenDemandSulfateNitritesTotalResidualChlorineASTMD-512-81(1986)ASTMD-1179-80 (1986)StandardMethods413B(1985)ASTMD-1126-80 EPA-600-4-79-020 Method130.2(1979)ASTMD-1385(1983)ASTMDPowerWaterAnalysisManualCH-41EPA-600-4-79-020 Method413.1(1979)ASTMD-1293-84 StandardMethods423(1985)ASTMD-1067-82 MethodBEPA-600-4-79-020 Method365.3(1979)EPA-600-4-79-020 Method410.2(1979)ASTMD-516-82MethodA(1985)EPA-600-4-79-020 Method375.3(1979)StandardMethods426A(1980)Determination ofCorrosion Inhibition byCalgonCorporation ASTMD-1253(1986)StandardMethods(1980)TRAININGBUILDINGLAB'toOutfallOOE)BoronChlorideFluorideHaxdnessHydrazine SilicaOil&GreasepHTotalPhosphorus AtomicAbsorption MetalsIonChromatography Westinghouse ChemicalAnalysisProcedure forPWRWCAD7333Rev.1(1973)ASTMD-512-81(1986)ASTMD-1179-80 (1986)StandardMethods413B(1985)~ASTMD-1126-80 EPA-600-4-79-020 Method130.2(1979)ASTMD-1385(1983)ASTMPowerWaterAnalysisManualCH-41EPA-600-4-79-020 Method413.1(1979)ASTMD-1293-84 StandardMethods423(1985)EPA-600-4-79-020 Method365.3(1979)StandardMethods302B,303A(1985)EPA-600-4-79-020 Method215.1,220.1,242.1,249.1,273.1(1979)DionexSystemOperators Manual WASTEWATER FLOWDIAGRAMPlMAKEUPPLANT'dditional Information SectionIItem6.SubpartACookNuclearPlantGroundwater PermitApplication LakeTownship(PotableWater)Non-essential ServiceWater(NESW)AlumAdditionPre-filter Backwash2xDayAug.eeeSodiumHypochlorite (IfNeeded) Retention TankBlowDownIxDayOrAsNeededRejectWatertoLakeMichigan001-002SulfuricAcidorllydrochloric AcidAdditionReverseOsmosisCarbonFilterBackwash2xDayAvgOrAsNeededAcid/Caustic RinseChemCleaningBiofouling CleaningNESWwaterforsealsCationResinBedsRegeneration WasteDegasifier NESWcaaterNeutralization Tat)k(Installed by1-95)MixedBedsAnionResinBedsCausticegenerationtvastecid/Caustic Regeneration WasteMakeupPlantWatertoPlantServicesTurbineRoomSumpFlowtoOOD 'E OUTFALL'ooiOUTFALL~002WASTEWATER FLOWDIAGRAMP2OUTFALL003Additional Information SectionIItem6,SubpartACooknuclearPlantGroundwater PermitApplication Unit2Misc.CoolingUnit2Discharge IntakeForebayUnit1Discharge Unit1Misc.CoolingDyeChecksHeatExchangers SampleCoolersUnitsIP.2SJAEsDrainsCleaningWasteBioboxesUnit-2Condenser Unit-2ESWUnit-2SteamGenerator IINESWiMakeupPlantFlowDiagramttlUnit-1Condenser Unit-1SteamGenerator Unit-1ESWDyeChecksDrainsCleaningWastesBioboxesIn-lincMonitorsMisc.DrainsLayupDrainsU-2CCWDJWMakeupPlantRegeneration Wastes(An.i)PlantHeatingBoilerU-1CCWDJWIn-lineMonitorsMisc.DrainsLayupDrainsChemFeedTankDrainsBarrelRinseNeutralization TankInstalled By1-95Misc.PlantSumpsNon-radLabDrainsMisc.FloorDrainsTurbineRoomSumppHMeterSodiumHydroxide SulfuricAcidMisc.Processed Wastee.g.GlycolAutoCompositor HowMeterAbsorption PondGROUNDWATER e WASTEWATERFLOWDIAGRAM83SEWAGETREATMENT PLANTAdditional Information SectionIItem6,SubpartACookNuclearPlantGroundwater PermitApplication FireProtection (Frusbing andsassingwaresisdirccscdsossorsnwascr and/orgroundwarcr). LakeTownshipPotableWaterSupplyPlantSiteSanitaryWaste&KitchenWasteRadiograph Processing Laboratory WastePhotoLabTrainingBuildingChemistry LabWasteTrainingBuildingHVACSystemWastesPortableToiletWastesEastExtendedAerationPlantLimestone BedNeutralization TankEIIlucntNorthOutfallOOESeepageTank SouthOutfallOOESeepageTank Miscellaneous RinsingOperations lISouthExtendedAerationPlantSludgeEffluentgfProcegged) SludgeToaPOTWToGroundwater

WASTEWATERFLOWDIAGRAM-4 DRYWELLSAdditional Information SectionIItem6,SubpartACookNuclearPlantGroundwater PermitApplication SecurityDieselGenerator DayTankOverfiowUnit1MainTransformer DeckDrains(Stormwater) Unit1Emergency Generator PitSumpUnit2MainTransformer DeckDrains(Stormwater) Unit2Emergency Generator PitSumpUnit1Catchbasin Oil/Water Separator Unit2Catchbasin Oil/Water Separator Unit1DwellsUnit2DwellsGROUNDWATER SEEINSTRUCTIONS QNREVERSESIDESECT1ONINUMBER-~MI0005827EM7AoPROVIDEAttAPOFTHETREATMENT FACILITYUXATIOtbSCNlt6Tl%LOCATIONOF~DISCNARSE POINT(S)AIOOTIERINRR%TICN RGXKSTEDONREVERSESIDEOFPAGEaLOCATIONAIAP(SeeAttachedMap)21 INSTRUCTIONS FORCOMPLETlt4 SECTIONIITEM7Thisformrequiresalocationmapofthetreatment facilityshowingdischarge point(s). ENTERTHEPER4HTNUMBERINTHEBOXATTHETOPOFTHISFOIa(.THEPERMITIas(BERCANBEFOUNOONTHEFRONTPAGEOFYOUREXPIRINGPERMIT.IfthlSISanewOrnOtPreVIOualy Permitted

faCIIlty, thenleaVeblankandanumber<<IIIbeaSSlgned.

ITEM7LOCATIONMAPA.Provideadetailedlocationmanofthetreatment

facility, showingthelocationofthedischarge point(s)forallsurfacewaterandgroundwater discharges, andallknownsupplyanddrinkingwaterwellsofadjacentproperties tothefacility.

Forbothsurfaceandgroundwater discharge applicants, IndicatethelocationandIdentlfIcatlonnumberofanygroundwater monitoring wellsrelativetothefacilitywhicharecurrently beingusedbytheapplicant tomonitorthegroundwater. Also>Includethereceiving stream,lake,orstormsewerandthestreetsandroadsInthearea.22 SEEINSTRUCTIONS ONREVERSESIDESECTIONINUMBERWMZ0005827.EM8CONCENTRATEDANIMALFEEDINGOPERATION AeIQVCUTEACOtCEIIIRATEO ANIFEEDIMIFJCILI(IFtOCONTItAKTOIIIIIQ)SeMJSBIOFACRESUSEDFOICOtFI%I%HT FEKDIMI?CeIF11%REISOPENCOIFI%1%NTe HASARtMFFDIVERSION AtOCONIROLSYSIENMENCONSTR'?(IFMlsCONTI'OITEN9)DsWATISTI%IESIGNBASISKRTIECWiRKSYSTIH?C%CKNKOF1%RUJRIMIAtOEHIERMJSEROFII&KBOFRAIN?lDme,2IIMXRSIOFIIQ25YEA+2IIMXRSIORIIPOT%R(SPECIFY) ~e~IICI%SIMIES~s~INC%SEeWATISTIEMJ%EROFAQKSOFCONmISUTIMI ERAIQGE?F>WATISTIEDESIGNSAFEIYFACBXIIORTHISCONIROLSYSTEI(?~~~essesLJ~LJAeLISTlYPEOFANINLsN/A~LJLJITEIVI9TYPENUMBEROFANIMALSINOPENANDHOUSED.INEMENTIll4IIII4IelI4IOIBsGIVE'D%MJSBIOF1HISlYPEOFANINILINOPENCOKIMJ%NTe CeGIVEll%MJSEROFTHISlYPEOFANIIVILIHMXISEDIXtlFI%%NTe AsLISTlYPEOFAHINALeBsGIVETI%MISEROFTHISlYPEOFANItsALIKOPEN%IFll&%HTeCsGIVETIEMJSEROFTHISlYPEOFANINLIHMXNEDAeLISTTYPEOFANINLeBeGIVETI%MJSEROFTHISTYPEOFANINALINOPENCOIFIMJ%HTeCsGIVETI%MJSBIOFlHISlYPEOFAHULLINMNSEDCCtFII8%HTeAsLISTlYPEOFAHIHALsBeGIVE11%MJSEROFTHISTYI%OFANIHALINOPENCOtF1%%HTe CeGIVETIEMJSEROF'THISlYPEOFANIMALINMXSEDAeLISTlYPEOFANINALeBsGIVE1HEMJ%%ROFlHISlYPEOFANINALINIXsEHCO%1%I%HTs CeGIVE11%MJmBICFTHISlYPEOFANINLININUSEDCOtFAsLISTTYPEOFANINLeBeGIVE1%MJ%EROF1HISTYPEOFANINALIHOPENCOIFIMJ%NTeCeGIVE11%MJSEROF'THIS1YPEOFANINALIHMNSEDCCH'Il&%NTs AeLISTlYPEOFANINALeBeGIVETIEMJSBIOFTHISTYPEOFANINALIHQKHCeGIVETHEMJSEROFTHIS1YPEOFANINALININUSEDCCIFI%t%NTeAeLISTlYPEOFANINLsBsGIVETI%MJSEROFTHISlYPEOFANIISLIN0%NGXFIIBJ%HTe CeGIVE11%MJSKROFTHISlYPEOFAHINALINMXISEDCOM-1%%HI'e 23 INSTRUCTIONS FORCOMPLETING SECTIONIITEMS8ANO'P.Thisformrequiresinformation aboutthedesign,size,andtypeandnumbersofanimalsInaconcentrated animalfeedlot.ENTERTHEPERMITNHBERINTHEBOXATTHETOPOFTHISFORM.THEPERMITNIÃBERCANBEFO(P4)ONTHEFRONTPAGEOFYOUREXPIRINGPERMIT.IfthisIssnewornotpreviously permitted feelllty,thenleaveblankandnnumbervllIbeassigned. IGENERALINFORMATION Notallanimalfeedingoperations arerequiredtoobtainNpoEspermits.Exclusions arebasedonsIteandoccurrence ofdischarge. Inparticular, foranimalfeedingoperations, thesizecutoffsdependonwhetherornotpollutants sradischarged throughnmanmadedeviceorbydirectcontact<<Iththefacilityoranimals.AfacilityforlayinghensorbrollersIsnotrequiredtohaveapermitunlessIthnsnliquidmanurehandlingsystemorcontinuous overflowwatering. Also,facilities whichdischarge onlyInthecaseofn25year,24hourstormeventarenotrequiredtohaveapermit.ITEM9-8Giveonlythearesusedfortheanimalconfinement orfeedingfacility. OonotInclude.sny areausedforgrowingoroperating feed.~0IITEM9-CVECheck"Yas"lfsnysystemforcollection ofrunoffhssbeenconstructed. SupplytheInformation under0,E,andFtothebestofyourknowledge. ITEMIO-BANOC'ito,gI'!GivethemaximumnunberofeachtypeofanimalInopenconfinement orhouseduri'erroof(eitherpartially ortotally)whichareheldntyourfacilityforstotalof45daysormoreInanyl2monthperiod.IUsethefollowing categories fortypeofanimals:Slaughter Cattle-FeederCattle-MatureDairyCattle(milkedordry)-Swine(eachweighingover55pounds)-Horses-Sheep-Lambs-Turkeys-LayingHensI-Broilars(DucksIApermitlsnotrequiredunlessthefacilityhassIlquldmanurehandlingsystemorcontinuous overflowwatering. ANIMALFEEDINGOPERATION meansalotorfacility(otherthananaquaticanimalproduction facility) wherethafollowing conditions aremet:(A)Animals(otherthnnaquaticanimals)havebeen,are,orwillbestabledorconfinednndfedormaintained foratotalof45daysormoreInanyI2monthperiod)and(8)Crops,vegetation, foragegrowth,orpost-harvest residuesaranotsustained inthenormalgrowingseasonoveranYportionofthelotorfacility. Twoormoreanimalfeedingopertlons undercameoownership nrensingleanimalfeedIngoperation lftheyadjoineachotherorIftheyuseaccnmonareaorsystemforthedisposalofwastes.ANIMALUNITmeansaunitofmeasurement foranyanimalfeedingoperation calculated byaddingthefollowing nunbersfThenumberofslaughter andfeedercattlemultiplied by1.0;plusthenumberofmaturedairycattlemultiplied by1.4;plusthenumberofswineveighlngover25kllogrnms (approximately 55pounds)multiplied by0.4;plusthenumberofsheepmultiplied byO.l;plusthenumberofhorsesmultiplied by2.0.CONCENTRATED ANIMALFEEDINGOPERATION meansananimalfeedingoperation whichmeetsthecriteriasetforthIneither(A)or(8)belowor<<hlchtheDirectordesignates assuchonscase-by-case basis.A.Morethanthenunbersofanimalsspecified Insnyofthefollowing categories sreconfined(REGARDLESS OFWHETHERASURFACEWATERDISCHARGE EXISTS):t.I.I,OOOslaughter orfeedercattle.2.700maturedairycattle(whethermllkedordrycows).3.2,500swineeachweighingover25kllogrnms (approximately 55pounds).4.500horses.5.I0,000SheepOrlambe.6~55,000turkeys.7.I00,000layinghensorboilers(lfthefacilityhasscontinuous overflowwatering). B.30,000layinghansorbrollers(Ifthefacilityhassliquidmanurehandlingsystem).9.5,000ducks.10.I,000animalunits.B.Morethanthefollowing nunbersandtypesofanimalsareconfined(WITHSURFACEWATERDISCHARGE ASDESCRIBED BELOw':I.300slaughter orfeedercattle.24 2~200maturedairycattle(whethermilkedordrycows).3.750swineeachweighingover25kllcgroas (approximately 55pounds).4.I50horses.5.3,000SheepOrlambS.6.I6,500turkeys.30,000layinghensorbrollers(ifthefacilityhascontinuous overflowwatering). 8.9,000layinghensorbrollers(lfthefacilityhasaI)quidmanurehandlingsystem)~9.I,500ducks.IO.300animalunits."Eitheroneofthefollowing conditions are'mat:pollutants aredischarged IntowatersoftheUnitedStatesthrouchamamsadeditch,flushingsysteaorothersimilarmannadadevice(wmaenade" meansconstructed bymanandusedforthepurposeoftransporting wastes);orpollutants aredischarged directlyintowatersoftheUnitedStates<<hlchoriginate outsideofandpassover,across,orthroughthefacilityorotherwise ccmeIntodirectcontact<<IththeanimalsconfinedIntheoperation.

provided, however,thatnoanimalfeedingoperation Isaconcentrated animalfeedingoperation asdefinedabovelfsuchanimalfeedingoperatlcn discharges onlyIntheeventofa25year,24hourstormevent.N0TE:Thepermittee shallcontinue<<IthSection,ll andaddressItemsI,2,4,and5onpages3).33,and35.

SEEINSTRUCTIONS ONREVERSESIDESECTIONIPERMIT~ggppp5827EM10AOVATICANIMALPRODUTION FACILITYtTEM't1SPECIESOFAQUATICANIMALSPRODUCEDATTHISFACILITYAsDOYOUOPERATEANAXIATICANIHALPRODUCTION FACILITY? (IFtftsCCNfltAETOITBI12)BsINDICATETIETOTALtAtSEROFPON5sRACKHAYSAMISINILARSTRÃllRES ATYOlRFACILITYs CsIN)ICATKINltIICHCALENDARtONIHtVtXItttI FEED1%OCQRIsD.MKRTtaTOTALIANBEROFPlXtKISOFPOCOFKDIXRImTHISAsISTHISSPECIEAHARNCRtXXDHATERSPECIE?g/pBsGIVETHEt4VEOFTHISSPECIEsCsMERTIETOTALHARVESTABLE HEIQITOFTHISSPECIEPRODUCEDBYTHISFACILITYPERYEARINRXMSsDsMERTIEHAXItttIHEIGHTPRESENTFORTHISSPECIEttIICHHEXADREPRESENT YMI8ÃNLOPERATIONs AsISTHISSPECKA1ARHORCOLDI%TERSPECIEB>>GIVETIEWEOFTHISSPECIEsCsEN1KRTIETOTALH4RVESTABLE HEIGHTOFTHISSPECIEPRmXDBYTHISFACILITYPERYEARINRXtOS>>DeMKRTIEHAXItltIttEIQITPRESE%RRTHISSPECIEttIICHHXADREPRESENT YOUItOAHALOPERATIONs A,15THISSPECIEAHARIICRGXDHATERSPECIE?gB~GIVETIENA%OFTHISSPECIEsVnCsMKRTHETOTALNRVESTABLE NEIQITOFTHISSPECIEFDsENIERTHEtVUUttttHEIGHTPRESENTFORTHISSPECIEISICHICXU)REPRESENT VOIRNXHALCPERATIONsAsISTHISSPECIEAHARIIORCXDHATKRSPECIE?BsGIVETIENttEOFTHISSPECIEsCsENIKRTIETOTALHARVESTABIE HEIGNfOFTHISSPECIEPtmXH)BYTHISFACILITYPERYEIRINPOQOSeDsENIKRTIEHAXItMHEIGHTPRKSBIfFCRTHISSPECIEttIICHlORDRERIESENT YONtCNNLOPERATIONsAsISTHISSPKIEAHARtlCRCOLDHATERSPECIE?BsGIVETIEN4%OF'THISSPECIEsCeMKRTHETOTALNRVESTABLE HEIGHTOFTHISSPECIEPRQOUCEDBYTHISFACILITYPERYEARINPresDsEHIKRTIEHAXIt%MIEIGHTPRESENTFCRTHISSPECIEtSIOIlORDREPRESENT YQRtCÃNALOPERATIQls AeISTHISSPECIEAHAttIOROXDHATERSPECIE?BsGIVETIEHttKOFTHISSPECIEsCsENfKRT%TOTALtVUIVESTABLE HEIGHTOFTHISSPECIEPRCQXEDBYTHSFACTYYNDsENTERTIEHLYIttttNEIGHfPRESENfFCRTHISSPECIEtttICHMXADREPRESENT YNRtCRPALOPKRATIONe INSTRUCTIONS FORCCMPLETING SECTIONIITEMS10ANOIIThisformrequiresinfq{mation aboutthedesign,size,andtypeandnumbersofanimalsInanaquaticanŽalproduction feellly.ENTERTHEPERMITNIA{BERINTHEBQXATTHETOPOFTHISFORMTHEPERMITNIPBERCANBEFOUNDONTHEFRONTPAGEOFYOUREXoIRINGPFRMIT.IfthlSISanewOrnOtpreVIOuSly pe{mitted

faClllty, thenleaVeblankandanunberWillbeaSSigned.

GENERALINFORMATION NotailfishfarmsarerequiredtoobtainNPOESpermits.Exclusions arebasedonsizeandoccurrence ofdischarge. Foraquaticanimalproduction facilities, thesizecutoff5arebasedonwhetherthespeciesarewa{m~aterorcoldwater,ontheproduction weightperyearInharVeStabie POundS,andOntheZmquntOffeedingInpaundSOffOOdIfOrCOld~ater5Pecie5). AISO~faCIlitleSwhichdischarge lessthan30daysperyear,oronlydurlnoperiodsofexcessrunoffIforwarm~aterfish)arenotrequiredtohaveapermit.coNcENTRATEQ AQUATlcANIMALpRQQUOTIQN FAQII,ITY meansahatcnery, tishfern,orotherfacilitywhichcontains, growsorholdsaquaticanimalsIneitherOfthefollowing cateaorles, orwhichtheDirectordesianates assuchonaca5e-by-case ba515~A.Coldwaterfishspeciesorothercold~ateraquaticanimalsIncluding, butnotlimitedto,theSalmonidae familyotfishIe.g..troutandsalmon)Inponds,racewaysorothersimilarstructures ~blebdischarge atleast30daysperYearbutdoe5notInclude:I..Facilities whichproducelessthan9,090harvest~eightkllograms Iapproxlmateiy 20,000pounds)otaquaticanimalsperyear.2.,Facilities whichfeedlessthan2,272kllograms (approximately 5,0QQpounds)otfoodduringthecalendarmonthotmaximumfeeding.B.Harm~aterfishspeciesorotherwarmwateraquaticanimalsIncluding, butnotlimitedto,theAmelurldae, Cet{achldae, andCyprlnldae familiesotfish(e.g.,respectlveiy, catfish,sunfish,andminnows)Inponds,raceways, orothersimilarStruCtureS whlChdiSCharge atleaat30dayaperyear,butdOeSnatInClude:I.Closedpondswhichdischarge onlyduringperiodsotexcessrunoff.2.Facilities whichproducelessthan45,454harvestweightkllog{ams {approximately 100,000pounds)ofaquaticanimalsperyea{',ITEN10BGivethetotalnunberofdiscretepondsorracewaysInyourfacility.. Under"other"giveadescriptive nameofanystructure which15notapondoraracewaybutwhichresultsIndischarge towatersoftheUnitedStates.ITEN10-DThevaluegIvenformaximummonthlypoundsoffoodshouldberepresentative ofyournormaloperation. ITEN118Thenameoffishspeciesshouldbeproper,c{mtnon,orscientific names.ITENIlCANDDThevaluesgiventortotal~eightproducedbyyourfacilityperyearandthemaximum~eightpresentatanyonetimeshouldberepresentative ofyournormaloperation. NOTE:Thepermittee shallcontinuewithSectionIIandaddressItemsI,2,4,and5onpages31,33,and35.28 SECTIONtMI0005827iTEM12LISTNAHEANDHAILINGADDRESSOFALLPROPERTY$4ERSALIACENTTOTIETREATMENT FACII.ITY ANDORDISC%ROE/DISPOSAL AREAsSeeattachedlist.MAILINGLISTOFADJACENTPROPERTYOWNERS29 SO MI0005827 SectionI,Item12ADJACENTPROPERTYOWNERSEASTInterstate I-94(Michigan Dept.ofStateHighways) SOUTHLakeTownshipc/oGeraldWaskoTownshipSupervisor 1410ShawneeRoadBridgman, MI49106WESTLakeMichigan(StateofMichiganandUnitedStatesofAmerica)NORTHRosemaryBeach11-11-6800 0038-00-5 Tengerstrom, EricH.;3415S.59th;Cicero,IL606500037-02-5 Tengerstrom, EricH.;3415Cicero,IL60650S.59th;0037-01-7 Merkel'sFloorCovering, Inc.;8314Scottdale Rd.;BerrienSprings,MI491030037-00-9 Kraiss,Wilbur&Marilou;5004S.LongAve.;Chicago,IL60638I0036-00-2 Temmel,EdwardP.&Kathleen; 9617E.ShoreDr.;OakLawn,IL604530033-00-3 Gilpin,Clark&Nancy;1005E.60thSt.;Chicago,IL606370032-01-'5 Wittebort, RobertJ.,Jr.&NancyH.;3180N.Lakeshore Dr.;Chicago,IL606570030-02-1 Meier,Paul&LouiseG.;1357MadisonPark;Chicago,IL606150028-01-8 Balka,RonaldA.&JanetM.;3334LouiseDr.;Lansing,IL60438 SectionI,Item12ADJACENTPROPERTYOWNERSPage211-110006 0002-030004-000004-040004-010004-0211-11-0007 0013-000013-01MichiganDept.ofNaturalResources; P.O.Box30028;Lansing,MI48909FranklinRealEstateCo.;P.O.Box2000;St.Joseph,MI49085Temmel,EdwardP.;9617E.ShoreDr.;OakLawn,IL60453Caparo,WilliamE.6Oyler,KathrynE.;122S.Ellsworth Pl.;SouthBend,IN46635RosemaryBeachCorp.;c/oSecretary; 3415S.59thSt.;Cicero,IL60650LakeCharterTwp.;ShawneeRd.;Bridgman, MI49106LakeCharterTwp.;ShawneeRd.;Bridgman, MI491060006-01IndianaMichiganPowerCompany0001-010004-0111-11-0005 00290036-010027-000036-000036-0211-11-0005-0002 01-611-11-0008 0041-000009-00LakeCharterTwp.;ShawneeRd.;Bridgman, MI49106LakeCharterTwp.;ShawneeRd.;Bridgman, MI49106Technisand, Inc.;11833RavennaRd.;Chardon,OH44024Ruff,TimothyW.;P.O.Box504Bridgman, MI49106Technisand, Inc.;11833RavennaRd.;Chardon,OH44024Emery,Martin;Hopkins,ElwoodJ.&MableN.;7499ThorntonDr.;Stevensville, MI49127IndianaMichiganPowerCompanyBankofAmericaTexasP.O.Box650380Dallas,TX75265MichiganDept.ofTransportation; Lansing,MI48900FranklinRealEstateCo.;P.O.Box2000;St.Joseph,MI49085

NARSULEX,

'xQ(~iQIiMATERlALSAFETYDATASHEETSulfuricAcid1.PRODUCTANDCOMPANYIDENTIFICATION .ProductName:SulfuricAcidFormui:H,SO,MolecWarWeight:98.08ChemicalName:SulfuricAcidghemlcaiFamily:Inorganic Acid~Su7664-93-9 ~Synonyms: Sulphuric Acid,OilofVitriol,BatteryAcidproductUse:Usedtnmanufacture offertilizers, explosives, otheracids,metalpicklingandpetroleum processing. MARSULEXinc.111GordonBakerRoadSuite300orthYork,ONTM2H3R1(416)496-9655MARSULEXInc.40RichardsAvenueP.O.Box5453Nofwalk,CT06856-5453 (203)8544300EMERGENCY TELEPHONE NUMBER(800)263-9502PreparedbyMARSULEXTechnical Section(416)496-4164. 2.COMPOSITION/INFORMATION ONINGREDIENTS -SulfuricAcidNn-WaterInt%byWt.70-100%OM%CASNumber7664-93-9 7732-1863.HA2'ARDINFORMATION EMERGENCY OVERVIEW: /OangerlExtremely corrosive. Causessevereburns.Reactsviolently withwater.Highlyreactiveandcapableofignitingcombustible materials oncontact.Notflammable, butreactswithmostmetalstoformexplosive hydrogengas./Sulfuric Acklhacolorless toamber,deartoslightlycloudy,oilyliquid.NationalRreProtection Assochtlon (NFPA)RatingHazardous Materials Identification System(HMIS)RatingRREf04Extreme/Severe '3High/Serous ~2Moderate1=Slight0=MinimumWWaterReactiveectNeDate:Februay,1993.Supefaedea:

Februasy, 1990MARSULEXMSOS4010EPage1of9 MATERIALSAFETYDATA'SHEET,SulfuricAcid3.HAZARDINFORMATtON (continued)

POTENTIAL HEALTHEFFECTS:ExposureLlmlts:SulfuricAcidACGIH(TLV)1mg/m'TWA) 3mg/m'STEL) OSHA(PEL)1mg/8(TWA)Incontactwiththeskin:Concentrated solutionmaycausepainandsevereburnstotheskinandbrownishoryellowstains.Prolonged andrepeatedexposuretodilutesolutions maycauseirritation, redness,paInanddryingandcrackingoftheskin.lncontactwiththeeyes:Immediate paIn,severeburnsandcornealdamagewhichmayresultinblindness. CInhaled:MistsandvaporsmaycauseIrritation oftheeyes,noseandrespiratory tract.MaycauseIncreased 'ulmonary resistance, transient coughandbronchoconstrlctlon. Severeoverexposure mayresultInlungcollapseandpulmonary edemawhichcanbefatal.Ingested: SevereburningandpainInthemouth,throatandabdomen.Vomiting, diarrheaandperforation oftheesophagus andstomachliningmayoccur.LongTermExposure: ,Repeatedexposuremayproduceerosionanddiscoloration ofteeth.~l'lthough nodirectlinkhasbeenestablished betweenexposuretosulfuricacid,Itself,andcancerInman,theWorldHealthOrganization (WHO)International AgencyforResearchonCancer(IARC)haveconcluded thatoccupational exposuretostrongInorganic acidmistscontaining sulfuricacidiscarcinogenic toman,causingcancerofthelarynx(thevoicebox)and,toalesserextent,thelung.Exposuretoanymistoraerosolduringtheuseofthisproductshouldbeavokiedand,inanycase,keepexposures belowtheoccupational exposurelimitforsulfuricacid.1Corrosive effectsontheskinandeyesmaybedelayed,anddamagemayoccurwithoutthesensation oronsetofpain.Repeatedoverexposure mayleadtocontactdermatitis, maycausebronchitis withcough,phlegm,shortness ofbreathandemphysema, cancausechronicrunnynose,tearingoftheeyes,nosebleeds andstomachupsets.Strictadherence tofirstaidmeasuresfollowing anyexposureIsessential. ExistingMedicalConditions PossiblyAggravated ByExposure: SkinIrritation maybeaggravated inIndividuals withexistingskinlesions.Breathing ofvaporsorsprays.(mists)mayaggravate acuteorchronicasthmaandchronicpulmonary diseasesuchasemphysema andbronchitis. Carcinogenicity Data:Althoughtherearereportslinkingexposuretosulfuricacidtocancer,thisproductIsnotclassified byNTP(National Toxicology Program), notregulated ascarcinogenic byOSHA(Occupational SafetyandHealthAdministration), andhasnotbeenevaluated byIARC(International AgencyforResearchonCancer)orACGIH(American Conference ofGovernmental Industrial Hyglenlsts). (Seealso,LongTermExposure). Effective Date:February, 1993Supersedes:

February, 1990MARSULEXMSDSk010EPage2of9 NATULEX,MATERIALSAFETYDATASHEETSulfuricAcid4.FlRSTAIDMEASURESPromptremovalofthismaterialfromcontactwiththebodyisofutmostimportance.

&TARTFIRSTAIDATONCE.Precaution: Personsattending thevictimshouldavoiddirectcontactwithheavilycontaminated clothingandvomitus.Wearimpervious gloveswhiledecontaminating skinandhair.Incontactwiththeskin:Flushskinwithrunningwaterforaminimumof20minutes.Startflushingwhileremovinggcontaminated clothing. Ifirritation

persists, repeatflushing.

Obtainmedicalattention IMMEDIATELY. Donottransport victimunlesstherecommended flushingperiodiscompleted orflushingcanbecontinued during,transport. a,WhilethepatientIsbeingtransported toamedicalfacility, applycompresses ofIcedwater.Ifmedicaltreatment mustbedelayed,Immersetheaffectedareainicedwater.Ifimmersion isnotpractical, compresses ofIcedwatercanbeapplied.Avoidfreezingtissues.Discardheavilycontaminated clothingandshoeslnamannerwhichlimitsfurtherexposure. Otherwise, washclothingseparately beforereuse.lncontactwiththeeyes:Immediately flusheyeswithrunningwaterforaminimumof20minutes.Holdeyelidsopenduringflushing. IfIrritation

persists, repeatflushing.

Obtainmedicalattention IMMEDIATELY. Donottransport ~~victimuntiltherecommended flushingperiodIscompleted unlessflushingcanbecontinued duringtransport. Inhaled:Movevictimtofreshair.Giveartmclalrespiration ONLYIfbreathIng hasstopped.GiveCardiopulmonary flesuscltatlon (CPR)Iftherelsnobreathing ANDnopulse.Obtainrnedlcalattention IMMEDIATELY. Ingested: Ifvictimlsalertandnotconvulsing, rinsemouthandgiveNto1glassofwatertodilutematerhl.Ifspontaneous vomitingoccurs,havevictimleanforwardwithheaddowntoavoidbreathing lnofvomitus,rinsefmouthandadminister morewater.IMMEDIATELY contactlocalpoisoncontrolcenter.VomitingmayneedtobeInducedbutshouldbedirectedbyaphysician orapoisoncontrolcenter.IMMEDIATELY transport victimtoanemergency facility. NotetoPhysician: Alltreatments shouldbebasedonobservedsignsandsymptomsofdistressinthepatient.Medicalconditions thatmaybeaggravated byexposureindudeasthma,bronchitis, emphysema andotherlungdiseasesandchronicnose,sinusorthroatconditions. Severityofthebumisgenerally determined bytheconcentration ofthesolutionandthedurationofexposure. Intheeventofskinoreyecontact,lmmedhteandthoroughflushingisessential. Continued washingoftheeffectedareawithcoldoricedwaterwillbehelpfulinremovingthelasttracesofsulfuricacid.Creamorointments shouldnotbeappliedbeforeorduringthewashingphaseofthetreatment. 5.FIREFtGHTINGMEASURESFshPoint(method): Notapplicable, productIsnon-flammable utolgnltlon Temperature: Notcombustible Rammabllity LimitsInair(%):UELNotapplicable LELNotapplicable Effective Date:February, 1993Superaedea:February, 1990MARSULEXMSDSfffetOEPage3of9 MATERIALSAFEIYDATASHEETSulfuricAcid5.FIREFIGHTINGMEASURES(continued) FireExtinguishing Media:Forsmallfiresusedrychemicalorcarbondioxide.ForlargeAres,floodfireareawithwaterfromadistance. Expectviolentreactionwithwater.Donotgetsolidstreamofwateronspilledmaterial. SpecialFireFightingProcedures: WearaNIOSH/MSHA approvedselfwontalned breathing apparatus Ifvaporsormistsarepresentandfullprotective clothing. ForfightingfiresIncloseproximity tospillorvapors,useacid-resistant personalprotective equipment. Evacuateresidents whoaredownwindofAre.Preventunauthorized entrytoArearea,Dikeareatocontainrunoffandpreventcontamination ofwatersources.Neutralize runoffwithlime,sodaashorothersuitableneutralizing agents(seeDeactivating Chemicals, Section6).Coolcontainers thatareexposedtoflamewithstreamsofwateruntilfireisout.OtherFireorExplosion Hazards:Notflammable buthighlyreactive. Capableofignitingfinelydivkledcombustible materhlsoncontact.Reactsviolently withwaterandorganicmaterials withevolution ofheat.Extremely hazardous .~incontactwithmanymaterials, particularly

carbides, chlorates, fulmlnates, nltratesandpicrates.

Sulfuricacidreactswithmostmetals,especially whendilutetogiveflammable, potentially explosive hydrogengas.Hydrogengascanaccumulate toexplosive concentrations insideconfinedspaces.Followapproprhte NFPAcodes.6.ACCIDENTAL RELEASEMEASURESStepstobetakenIntheeventofaspillorleak:Removeallignitionsources.Ventilate area.Useappropriate PersonalProtection Equipment. Preventliquidfromenteringsewersorwatetways. Dikewithinertmaterial(sand,earth,etc.).Stoporreduceleakifsafetodoso.CollectIntocontainers forreclamation ordisposalonlyifcontainer ~r(ssuitabletowithstand thematerial. Consklerlnsituneutralization anddisposal. Ensureadequatedecontamination oftoolsandequipment following deanup.ComplywithFederal,Provincial/State andlocalregulations onreporting releases. =:"Deactivating Chemicals: Ume,limestone, sodiumcarbonate (sodaash),sodiumbicarbonate, dilutesodium'hydroxide, diluteaquaammonia.WasteDisposalMethods:Disposeofwastematerialatanapprovedwastetreatment/disposal

facility, Inaccordance withapplicable regulations.

Donotdisposeofwastewithnormalgarbageortosewersystems.Note-Clean-upmaterialmaybeaRCRAHazardous Wasteondisposal. .-'Spills aresubjecttoCERCLAreporting requirements: RQ=1000lbs.7.HANDLINGANDSTORAGEPrecautions: Wearappropriate PersonalProtection Equipment. Donotbreathspraysormists.DonotIngest.DonotgetIneyes,onskinoronclothing. Keepignitionsourcesawayfromsulfuricacidstorage,handlingandtransportation equipment. HandlingProcedures andEquipment: Carbonsteelorstainless steelmaterials aresuitableforuseforacidconcentrations equaltoorgreaterthan93%.However,theeffectoflowerconcentrations onthematerhlsofconstruction canbeverycomplex.Contactproductsupplierforspecificrecommendatlons whenhandlingsulfuricacidatstrengths lessthan77%.Effective Oate:February, 1993Supersedes:

February, 1990MARSULEXMSDS4010EPage4of9 NAILciULKK...

MATERIALSAFETYDATASHEETSulfuricAcid7.HANDLINGANDSTORAGE(continued) StorageTemperature: Storeabovefreezingpoint(Section9).Elevatedtemperatures willIncreasethecorrosion /rateofmostmetals.StorageRequirements: Storepackagedacidinadry,well,ventilated locationawayfromcombustibles, oxkllzers, bases,ormetallicpowders.Storagetanksshouldbeprotected fromwateringress,bewellventilated, and'aintained structurally inasafeandreliablecondition. OtherPrecautions: Sulfuricacidwillattacksomeformsofplasticsandcoatings. Alwaysaddacidtowater-notgwatertoacid.IfkeptInupperfloorsofbuilding, floorsshouldbeacklproofwithdrainstoarecoverytank.8.EXPOSURECONTROLS/PERSONAL PROTECTION -'Recommendatlons listedinthissectionIndicatethetypeofequipment whichwillprovkleprotection againstoverexposuretothisproductConditions ofuse,adequacyofengineering orothercontrolmeasures, andactualexposures willdictatetheneedforspecificprotective devicesatyourworkplace. ~<Engineering Controls: Localexhaustventilation required. spiratory Protection: ANIOSH/MSHA approvedair-purifying respirator equippedwithacidgas/fume, dust,mistcartridges forconcentrations upto10mg/nf'.Anair-supplied respirator ifconcentrations arehigherorunknown.S)tinProtection: impervious (l.e.,neoprene, PVC)gloves,coveralls, bootsand/orotheracidresistant protective ~clothing. EyeProtection: Tight-fitting chemicalgogglesandfaceshield./OtherPersonalProtective Equipment: Wherethereisadangerofspillingorsplashing, acidresistant apronsorsuitsshouldbeworn.Trouserlegsshouldbewornoutside(nottuckedin)rubberboots.Safetyshowersand~eyewashfountains shouldbeInstalled instorageandhandlingareas.9.PHYSICALANDCHEMICALPROPERTIES hPhysicalState:LlqukfAppearance andOdor.SulfuricacidIsacleartoamber,heavy,oilyliquidwhichmayhaveasharppenetrating odor..OdorThreshold: NodataBoilingPoint:77.67%:193'C(380'F); 93.19%:276'C(529'F);98%:330'C(626'F)Melting/Freezing Point:77.67%:-11.2'C(+11.6'F); 93.19%:-29.5'C(-21.1'F); 98%:-1.1'C(30'F)VaporPressureat40'C(102'F):77.67%:1.2mmHg;93.19%:0.0016mmHg;98%:.0.002 mmHgSpecificGravityat16'C(60'F):77.67%:1.7059;93.19%:1.8354;98%:1.8437VaporDensity:(Air=1):3.4sulfuricacidcomponent BulkDensity:Notapplicable (seespecificgravity)ffecthreDate:February, 1993Supersede@

February, 1990MARSULEXMSDS401OEPage5of9 MATERIALSAFETYDATASHEETSulfuricAcid9.PHYSICALANDCHEMICALPROPERTIES (continued)

Evaporation Rate:Notapplicable /~.Solubility: MiscibleInallproportions Inwater.Alsosolubleinalcohol.pH:0.3(1Nsolutionat25'C/78'F) 10.STABILITY ANDREACTIVITY Stability: .~UnderNormalConditions: Stable,butreactsviolently withwaterandorganicmaterials withevolution ofheat.UnderFireConditions: Decomposes toformsulfuroxides(SQ). Conditions toAvoid:Temperatures whichmayhaveanegativeeffectonthematerials ofconstruction usedlnequipment. Materials toAvoid:Contactwithorganicmaterials (suchaschlorates,

carbldes, fulmlnates andplcrates) maycause,fireandexpiosions.

Contactwithmetalsmayproduceflammable hydrogengas.Whendiluting, addacidtowater.DoNOTaddwatertotheacid.nHazardous Decomposltlon orCombustion Products: Toxicgasesandvapors(e.g.sulfurdioxide,sulfuricacid;vapors/mists andsulfurtrloxkfe) maybereleasedwhensulfuricaciddecomposes. Hazardous Polymerization: WIIInotoccur11.TOXICOLOGICAL INFORMATION Toxicological Data:.Lox,(oral,rat)2140mg/kgL+(inhalatlon, rat)=510mg/nt'or2hrsSkineffects(rabbit): Severeirritation Eyeeffects(rabbit): Severeirritation Carcinogenicity Data:Althoughtherearereportslinkingexposuretosulfuricacidtocancer,thisproductIsnot.classied byNTP(National Toxicology Program), notregulated ascarcinogenic byOSHA(Occupational SafetyandHealthAdministration), andhasnotbeenevaluated byIARC(Intematlonal AgencyforResearchonCancer)orACGIH(American Conference ofGovernmental Industrial Hyglenlsts). SeeSection3.HazardInformation, regarding Potential HealthEffects(LongTermExposure) forfurtherdiscussion. Reproductive Effects:Noinformation Isavailable andnoadversereproductive effectsareanticipated. Mutagenicity Data:No'information isavailable andnoadversemutagenic effectsareanticipated. ,Teratogeniclty Data:NoInformation isavailable andnoadverseteratogenIc effectsareanticipated. Synerglstlc Materials: Noneknown/Effective Oats:February, 1993Supersedes:

February, 1990MARSULEXMSDS4010EPage6ef9 NIAII5ULKX,

'ATERIALSAFETYDATASHEETSulfuricAcid12.ECOLOGICAL INFORMATION EcotoxlcEffects:Harmfultoaquaticlifelnverylowconcentrations. Ijtiaybedangerous ifitenterswaterIntake;Fishtoxicitycriticalconcentration 10mg/L;7.34mg/L/48hrs-LymneaePalustrls 100%mortality, 13.DISPOSALCONSIDERATIONS ~Responsibility forproperwastedisposallswiththeownerofthewaste.Workwiththeappropriate regulatory bodiestoensurecompliance withregulations. ~Considerthecollection ofresidualsulfuricacidIntocontainers forreclamation ordisposalonlyifthecontainer Issuitabletowithstand thematerial. ~Consklerlnsituneutralization anddisposal. Clean-upmaterhlmaybeaRCRAHazardous Wasteondisposal. ~Provincial/State orlocalregulations orrestrictions arecomplexandmaydifferfromFederalregulations. ~Theinformation appliestothematerialasmanufactured; processing, neutralizing, useorcontamination maymaketheInformation inappropriate, Inaccurate orIncomplete. 14.TRANSPORT INFORMATION U.S.(UnderDOT)//ShippingName:RQSulfuricacidHazardChssorDivision: 8ProductIdentification No.(PIN):UN1830PackingGroup:IICanada(UnderTC)ShippingName:Sulphuric acidChsslficatlon(s): Class8(9.2)ProductIdentification No.(PIN):UN1830PackingGroup:II16.REGULATORY INFORMATION .A.SARATitleIIIHAZARDCATEGORIES ANDLISTSPrHtrlAcute(Immedhte) Health:Chronic(Delayed) Health:Rre:Reactivity: tSuddenReleaseofPressure: YesYesNoYesNo~UExtremely Hazardous Substance (40CFR355,SARATitleIIISection302)CERCLAHazardous Substance (40CFR302.4)ToxicChemical(40CFR372.65,SARATitleIIISection313)YesYesYesEffective Date:February, f993Supersedes:

February, 1990MARSULEXMSDS4010EPage7of9 MATERIALSAFETYDATA"SHEETSulfuricAcid15.REGULATORY INFORMATION (continued)

Reportable Quantity(RQ)underU.S.EPACERCLA:RQ=1000IbTSCAInventory Status:Reported/Included /'~~aNaoa.Workplace Hazardous Materials Information System(WHMIS)WHMISClassification(s): ClassE-Corrosive QassD1A-VeryToxicWHMISHealthEffectsIndex:AcuteLethality -verytoxic-ImmedhteCorrosive toanimalskinWHMISingredient Disclosure List:Confirmed A;Meetscrlterhfordisclosure at1%orgreater.Reportable Quantity(RQ)underTransport Canada-,TDG:RQ=5Iltres(orKg)IfItrepresents adangertohealth,life,propertyortheenvironment. 16.OTHERINFORMATION Additional Information andReferences 1.Enviro-TIPS Manual,'Sulphuric AcidandOleum",Environment Canada,February1984.2.Weast,R.C.(Ed.),"CRCHandbookofChemistry andPhysics', 60thEdition(1980)3.Sax,N.l.,'Dangerous Properties ofIndustrial Materials', 7thEdition(1989)I4.ACGIH,Threshold UmitValuesforChemicalSubstances andPhysicalAgentsandBiological ExposureIndices,1991-925.Sittig,Marshall, "Handbook ofToxicaridHazardous Chemicals andCarclnogens", 2ndEdition,1985RevisionIndicators: galntheleftmargInIndicates arevisionoradditionofInformation sincethepreviousIssue.EffectivDate:February, 1998supersedes:

February, 1990MARSULEXMSDS4410EPage8of9

NARSULKX, MATERIALSAFETYDATASHEETSulfuricAcid16.OTHERINFORMATION (continued)

Legend:CAS8CERClACFRDOTEPAMSHANIOSHPELpvcRCRASARASTELTCTDGTLVTSCA'DNAUEL-ChemicalAbstracts ServiceRegistryNumber-Comprehensive Environmental

Response, Compensation, andUabilltyAct-CodeofFederalRegulations

-Department ofTransportation -Environmental Protection Agency-Theconcentration ofmaterialinairexpectedtokill50%ofagroupoftestanimals-LethalDoseexpectedtokill50%ofagroupoftestanimals-LowerExplosive Limit-MineSafetyandHealthAdministration -Nationalinstitute forOccupational SafetyandHealth-Permissible ExposureLimit-Polyvinyl chloride-ResourceConservation andRecoveryAct-Superfund Amendments andReauthorlzatlon ActoftheU.S.EPA-ShortTermExposureUmlt-Transport Canada-Transportation ofDangerous GoodsAct/Regulations -Threshold LimitValue-ToxicSubstances ControlAct-Time-Weighted Average-UpperExplosive LimitTheinformation contained hereinhasbeenpreparedbyMARSULEXInc.andisofferedonlyasaguidetothehandlingofthisspecificmaterhlandhasbeenpreparedIngoodfaithbytechnically knowledgeable personnel. ItIsnotIntendedtobeall-Inclusive andthemannerandconditions ofuseandhandlingmayInvolveotherandadditional conslderatlons. Nowarrantyofanykind!sgivenorImpliedandMARSULEXInc.willnotbeliableforany.damages,losses,inJurlesorconsequential damageswhichmayresultfromtheuseorrelianceofanyInformation contained herein.EffecUveDate:February, 1993Supersedes:

February, 1990MARSULEXMSDS4010EPage9of9

INSTRUCTIONS FORCCMPLETIIIGSECTIONIIITEMSIAND2ThiSfarmrequiresinformation onthefacility's discharge additives.

location, discharge

schedule, volumeflowrateandwatertreatment FNTERTHEPERMITNUMBERINTHEBOXATTHETOPOFTHISFORM.THEPERMITNUMBERCANBEFOUNDONTHEFRONTPAGEOFYOUREXPIRINGpEIa(IT.IfthisIsanewornotpreviously permitted

facility, thenleaveblankandanumberwillbeassigned.

EntertheoutfallnumberInspaceprovidedtoreachpageofsectIonII.FareachIndividual discharge pointoseparatesetofSectionIlformsmustbefilledout.ITEMIDISCHARGE LOCATIONSCHEDULEANDFLOWRATESA.Enterthelocationofdischarge, thisshouldIncludequarter-quarter section,quartersection,section,ton,andrange.8.Listnomeofreceiving water(Ifsurfacevoterdischarge). C.Indicatewhetherfoci)Itydischarges onaseasonalbasis.D.Ifyes,listdischarge periods.Providethelandapplication ratesusedorexpectedtobeusedIntermsofinchesperhour,hourspecday.andInchesp<<w<<".F.Indicatethetypeofwastewater tobedischarged framthisoutfall.Refertothewastewater typecodegivenIntheleftmarginMorethanonecodemaybeapplicable. G.ProvidetheaveragenumberofhoursperdayIn~hichthefacilitydischarges treatedwastewater andthetotalnumberofdaysperyearinwhiahthed(SCharge OCCurS.H.Providecurrent(fromthelastl2months)orexpectedflowratesosrequested. RefertounitcodedivanInthelettmarginfartheappropriate flowunits.)sly-milliongallonsperyear;MGD-milliongallonsperday;GPD-gallonspecdoy.I.Providethemaximumdischarge flowratewhichyouwanttohaveauthorized withinthepermit.NOTE:ForNPOESpermitson)Y.theuseofsuchaflowratewillnotplaceonactuallimitrestriction ontheflawbutwillbetheflawroteusedtodevelopettluentlimits.Also,whentheMonthlyOperating ReportsarereviewedbyCompliance staffItwillhelptheetodetermine IfanyneworIncreased usesmighthaveoccurredatthefacility. J.Providethedesignflowtorthisspecificouttalldischarge (e.g.batchtreatment systemflaw,packagedtreatment systemflaw.orsaneotherfinitetreatment systemflaw).ITEM2WATERTREATMENT ADOITIVESA.Indicate~batherdischarge Istreatedwithconditioners, Inhibitors, ormlcrobloclde. Ifnot,continuetoItem3.B.Givename,function, andchemicalcomposition ofadditives used.C.Givenomeandaddressofthemonutacturer(s) ottheadditives used.D.Indicateexpectedminimis,overageandmaxlcmxsdischarge concentrations oftheadditive(s) torthisdischarge. Indicatewhetheryoutreatthedischarge toremovetheadditive(s) beforedischarge ofwastewater. F.Indicatetheremovalefficiency ofeachadditivefromthewastewater ondthedischarge frequency ofeachadditivetothesurfacewaterorgroundwater. G.hOTE:ItIstheresponsibility ottheapplicant tosupplytheproductInformation asrequested InthisItem4.Information requested butnotsuppliedmayresultIntheapplication beingreturnedtotheapplicant forccmpletlon. 32 SEEINSTRUCTIONS ONREVERSESIDESECTlONIIPERMIT~~"Cl4005827lTEMOJIFNI.IlfKRAsLOCATIONOFDISCNRGE~~<s'5Ee.$ErKflI~05,1M~><<,pA%EL115~B.IVYRECEIVING HATER(IE.GROLIEWATER ORIPVEOFSIRFACEBSOPTIONOND DISCHARGE LOCATIONCsDOYWDISCHARGE SEASWILLY. (IFIOsCCNTIIAETOE)D.IFYESeLISTDISCNRGEPERIODSN/AIOe/DAYQ~QX~IOe/DAYFLOWRATEWASTEWATER Ee(ANDAPPLICATION RATEN/AINsIR>>~~LJIRsDAYINs/NKe~~u~~'uKJNc(1CONTACTCOOUNG2NONCONTI(CTCOOLING3PROCESS4SANITARY5STORMWATER FelYPEOFHASIEHATER DISCNRGEGsDISOQRGESOHlIE(YEARLYAVERAGE)HsDISCHARGE FLOIRATEAlltimedailymaximumtimes365.TOTALYEARLYDAILYHINIMPIDAILYNXIILPI49WITjC0DE0'2J2.6~2L3L~JuWLJLJHG(RS/DAY 1MGY2MGD3QPDITEMJeHAXlKPIDESIGNDISCHARGE FLOIRATEeAsDOYWUSEHATERTREAllEHT ACOITIVES lOTREATYOLRDI~(IFIe.CCNTDAETOIITH3)Bs,Nt%FWCTIONeAIDOEHICALCOSOSITICN OFTAESEAIDITIVESeDESIGNSULFURICACIDSODIUMHYDROX5-2u~HNeutralization* I~TIENXDSPIDISCNRGEFLOVRATETOBEAIRICRIZEDINPBPIIT>>~6WIT)OXKWATERTREATMENT ADDITIVES c.rwEaommnrm~~~SULFURICACIDSODIUMHYDROXIDE 1MQ/I2UQ/IMARSULEX, INC.111GORDONBAKERROAD,SUITE30NORTHYORK,ONTM2H3R1DsEXPECTEDDISCNRXCOKENIRATION CFAIOITIVESe AcoITIYEwvESodiumSulfateACOITIVEKVEACOITIVEHA%E.DOYWTREATlIEDISCHARGE lOABOVEACOITIVES? HAVILANDPRODUCTSCOMPANY421ANNST.,N.W.GRANDRAPIDS,MI49504HIHIISJIWITSAVERAGEWITSNXDSPIWITSCXEaXE'0130011500~1~s~sLJ;~LJs~LJLJ'~M:~LJF.l4KTISlHERBClVALEFFICIBCYAM)DISONRGEPREOEHCY? N/AACOITIVEHA%ACOITIVEHA%ACDITIVEHNEIRSs/DAYDAYS/HK>>LJGASANATTAtHsEHT lDTHISAPPLICATIOI PROVIDESPECIFICNPRALIANCRAQSLTIClOXICOLOGICAL D(TAOIREFERENCE HHIOIAREAVAILABLE ANDINFNP(ATICN CNTHERATEOFDEGRADATICN OFlIEPRCOCISFCREKHACOITIVEe MSDSattached.

• Approximately instantaneous neutralization uponmixing-(Newtanktobecompleted Januaryof1995willensurecompleteneutralization priortodischarge.)

S1 MATERIALSAFETYDATASHEETSODIUMHYDROXIDE 50%ENDUSTREAL GRADESECTIONI-IDENTIFICATION MANUFACTURER'S NAME............ ADDRESS(STREET,CITY,STATE,ZIP)PHONENUMBERea>~s~~~~~~a~~~~~~sEMERGENCY PHONENUMBER......... EFFECTIVE DATE................. TRADENAME................ ~....CHEMICALFAMILY..............-. Havi1andProductsCampany421AnnSt.,N.N.,GrandRapids,ME49504(616)~61-6691CHKMTREC(800)424-9Z006/18/91SODIUMHYDROXIDE 50%INDUSTRIAL GRADEAlkali,BaseSECTIONII-HAZARDOUS INGREDIENTS HAZARDOUS COMPONENTS OSHA/PKLACGIH/TLV (Units)PROD.CASNSodiumHydroxide (CausticSoda)(48.5-51.0% bywt)mg/m=TNA2mg/m~T4IA1.10-73-2 SodiumChlaride(0.8-1,.3%byxt)Mater(Balance) NatEstab1ishedNotEstablished NatEstab1ishedNatKstab1ished7647-14-5 77~F2-18-5 SECTIONIII-PHYSICALDATABOILINGPOINT~~~~~~~~~~~~~~a~~FREEZINGPOINT~~e~~~~~~~~~~~~VAPORPRESSURE(mmHg)........ VAPORDENSITY(Air~i)......... SOLUBILITY INH20............. APPEARANCE/ODOR a~~~~~~~~~~~~~~SPECIFICGRAVITY(H20=1)......Ha~~~~~~~~~~~~~~~~s~~~~~~~~~~P.9~~F(145C)60F(15.6C)1.5C~20CNaEnlormation Available Completely Clear,Color)essliquid;Odorless1~52NotEstablished SECTIONIV-FIREANDEXPLOSION HAZARDDATAFLASHPOINT..~..........-........... NatFlammable LONEREXPLOSIVE LIMIT(%byValume)NatApplicableUPPEREXPLOSIVE LIMIT(%byVolume)NatApplicable EXTINGUISH MEDEA................... AsfarSurraunding Fires07/.~0/1991 C'ATERIAL SAFETYDATASHEETSODIUMHYDROXIDE 50/ENDUSTRIAL GRADESPECIALFIREFIGHTINGPROCEDURES... WearNIOSH/MSHA approvedselfcantained breathing apparatusandful1protective equipment whenthismaterialisinvolvedinafire.UNUSUALFIREHAZARD........ ~.......Ensolutioncausticcanreactwithamphateric metalsgenerating hydrogenwhichisflammable and/oreplosiveifignited.SECTIONV-HEALTHHAZARDDATACARCINOGENICITY............... NoneNTP~~~s~~~~~~~e~~~~~~~~~~~~~~~NoIARC~~~~~~~~~~~~~~~~~~~~~~~~~~noOVEREXPOSUREEFFECTS......... RednessofExposedTissueswithpossibleburnsresultingindeepulceration. PRIMARYROUTF(S)QFENTRY..... SkinContactFIRSTAIDPROCEDURES.......... Ifinhaled:Removetofreshair.Ifnatbreathing', giveartificialrespiration, preferably mouth-to-mauth. Ifbreathing isdifficult, aiveoxygen.Getmedicalattention. Incaseofcontact:Immediatelyflusheyesarskinwithplentyafwaterforatleast15minuteswhileremovingcontaminated clothingandshaes.Getmedicalattentian.Washc)othingbeforereuse.Ingestion: Donotinducevomiting. Efcanscious, dilutebygivingseveralglassesofwater.CallaPhysician Immediately. EXPOSUREAGGRAVATED MEDECALCONDITIONS NoneCurrently KnownSECTIONVI-REACTIVITY DATACHEMICALSTABILITY............ CONDITIONS TQAVOID........... INCOMPATIBLE MATERIALS........ DECOMPOSITION PRODUCTS........ HAZARDOUS POLYMERIZATION...... POLYMERIZATION AVOID.......... StableNatApp1icab1eAcidsNoneCurrent.l yKnawnWi11NotOccurNotApplicable SECTIONVII-SPILLQRLEAKPROCEDURE 07/~0/1991 IrMATERIALSAFETYDATASHEETSODIUMHYDROXIDE 50/INDUSTRIAL GRADEFORSPILL~s~~~~w~i~aa><~~a~s~WASTEDISPOSALMETHOD......... Addnon-reactive dry,absorbent suchasdiatomaceous earth.ShovelorsweepupandplaceinanapprovedDQTcontainer andseal.Flushcontaminated areaandneutrali"=e withdiluteacid.Disposeofspill,edorwasteproduct,contaminated soilandothercontaminated materials inlicensedlandfillortreatment facilityinaccordance withallfederal,stateandlocalregulations. SECTIONVRESPIRATORY PROTECTION....... VENTILATION~~~~~~~~~~~~~~to~~PROTECTIVE GLOVES............ EYEPROTECTION............; ..QTHERPROTECTIVE EQUIPMENT... HANDLINGANDSTORAGE......... III-SPECIALPROTECTION Suppliedairorselfcontained breathing apparatus withfullfacepiece.Tomaintainvaporsbelowlimits.Rubberorotherimpervious materials. Chemicalsplashproofgoggles.Asafetyshowerandeyebathshouldbeavailable. Foroperations wherespillsorsplashing mayoccur,useanimpervious bodycoveringandboots.Storeincool,dry,wellventilated area.Keepcontainers closedwhennotinuse.SECTIONIX-SPECIALPRECAUTIONS HAZARDCLASS~~~~~~~~~~~~~~~~DOTSHIPPINGNAME........... VNNUMBERe~~~~~~~~~~~~~~~~~~REPORTABLE QUANTITY(RQ).'...CorrosiveMaterialSODIUMHYDROXIDE, LILDUIDUN18242000lbs.REFERENCES HMIS:H-3,F-O,R-1SQDHYDOX07/0/1991 SEEINSTRUCTIONS ONREVERSESIDESECTlONIIPERMIT~IYI100005827NUMBERrEM3AeNctEOFYPROCESSCotnRIBUTINI TO1NEDISOIARGE ltttOUGHlNISOUIFAU.At@SICCODEB,PROCESSSCHHXLE(YEARLYAVERAGE)OODSTMLECTthorn/DAY ~4491~65PROCESSSTREAMSCONTRIBUTING TOOUTFALLDISCHARGE c/tMcctOY0ccCePROCESSHASTKHATER FIDHRATESeevariouscontributing wastestreamsinSectionj.6.ADePROCESSPRODUCTION RATEN/AA.tUYE0FPRocEsscoNIRIBUTI% ToTIEDIGQccRGK N/ATNOIXiH1NISOUTFALLANtSICCODETOTALYEARLYDAILYHINltttlDAILVHAXItXH111.354w~~T5jl.090~6.683~6WITS/TIIE1POUNDS2GALLONS3CUBICYARDS4TONS5MGY6MGD7GPDTIME1HOUR2DAY3WEEK4MONTH5YEARBePROCESSSCIEDIXE(YEARLYAVERAGE)c/tCePROCESSHASTEHATER FUXIRATEO010D.PROCESSPRODUCTION RATEANAtEOFPRXEsscotnRIBUTING ToTIEDlsctFIRGE N/ATIRCXXIH1NISOUIFALLAtQSICCODEBePROCESSSCIEDIAE(YEARLYAVERAGE)CePROCESSHASTKHATKR FUXIRATED.PROCESSPRODUCTION RAlEA.NAtEOFPROCESSCenRIBUTING ToTIEDISCHARGE N/AAtDSICCXXIEBePROCESSSCIEIXLK(YEARLYAVERAGE)PROCESStcASTBaTER FIDHRATEDePROCESSPRNXX,TION RATEA.IIAtEDFPROCKsscottmrBUTING ToTIEDlscHIRGK N/ATI%GLXIH1NISOUIFAILANDSICCCCEBePROCESSSctHXLE(YEARLYAVERAGE)c/tC,PROCESSHASTBtCTER FtlHRATEOcO0DePROCESSPROIXCTION RATEUses/oev~oevs/vsse TOTALYEARLY,DAlLYHINWPIDAILYHAXIIXHTOTALYEARLYDAII.YHININPIDAILYHAXIHHTOTAI.YEARLYDAlLYHINItSPIDAILYHAXItCPCIOUII/SSY ~OSYS/YYSS TOTALYEARLYDAILYHINIIMIDAILY&XItXPIWITS/TIHEWITSXTIHEIHITCODEWlls~It%WITCODELLUNITS~TltE INSTRUCTIONS FORCOMPLETING SECTIONIIITEMSTtIsformrequiresInformation ontheprocessstreams<<hlchcontribute tothisdischarge. ENTERTHEPERMITNLSIBERINTHEBOXATTHETOPOFTHISFORM.THEPERMITNISIBERCANBEFOUNOONTHEFRONTPAGEOFYOUREXPIRINGPERMIT.IfthisIsanewornotpreviously permitted

facility, thenleaveblankandanumber<<illbeassigned.

EnteroutfallnumaerinspaceprovidedforeachpageofSectionII.ForeachIndividual dlscharoe ointaseaaratesetofSectionIIformsmustbefilledout.PROCESSSTREAMSCONTRIBUTING TOOISCHARGE: FOREACHSEPARATEPROCESSPROVIDETHEFOLLOWING INFORMATIO'I A.Enterthenameoftheprocess<<hlchcontributes tothisdischarge. AlsoprovidetheproperSICcode.B.IndicatetheyearlyaverageprocessscheduleJnhoursperdayanddays-per-year. CProvidetheprocess<<aste<<ster flowrateinformation asrequested basedonyourlastI2monthsofoperations. Refertounitcodegivenintheleftmarginfortheappropriate flawunits~0.ProcessProduction Rate-Certainpermitlimitations maybebasedonproduction rates.Theproduction ratesusedtodetermine permitlimitsshallberepresented byareasonable measureofactualproduction ofthefacility, suchastheproduction duringthehighmonthofthepreviousyear,orthemonthlyaveraqeforthehighestofthepreviousfiveyears.orotherreasonable measureasstatedInapplicable U.S.E.P.A. categorical rulesandregulations. Fornewsourcesornewdlschargers, actualproduction shallbeestimated usingpro]ected production. Recordyourproduction ratesInthetermsandunitsusedintheapplicable U.S.E.P.A. categorical rulesandregulations foryourtypeoffacility. 34 SEEINSTRUCTIONS ONREVERSESIDESECTIONIIPERMIT~IeIT0005827NUMBEREEMGROUNDWATER DISCHARGE INFORMATION AeISTHEDISCHARGE FROM1HISOUTFALLDIRECIKDTOlHEGRIXNOORGROINDIATKRS? (IFtOPCCttfltAE TOITBI5)B.HASAHYDROGEOLOGICAL STUDYORITSEQUIVALENf BEENPKRFORtED ORISTIMBRESIFFICIKNT CURRENfHYKROGEO)re ICALINFORHATION AVAILABLE gREOIRKD@V~HATERREQXE2CES THISEXISTI%ORPROPOSEDDISCHARGE) IFYESAlTACHACOPYCFTHEREPORTSCeAREYOU~RSTIHj ANEXKHPTICN FIKtlSIKPHTfltti AHITROGKOUXIICAL REPORTINOKRRULERPX5e22II (Q(PAGE56)ORFlKtlGRONDQTKR tSNITORItts gEOUIRBKNIS INDERRULER.ZSP(5)(PAGEIIZ)OFTIEPART22RULES~IFYESATTACHDOCLNKNTS AN)EXPIANATION TODBSNSTRATK THATYOLRDISCNRGEtEXADOUALIFYFORANEXEtlsION.DeAREYOUREQLESTIt6 AVARIANCEFRANRtaK323e2205(PAGE99(tDNDKGRADATICN) OFTIEHATERRESIXNCES CCEfllSSIONPART22GRtXSDQTER R1LES2IFYESATTACHSIKHDOCU5BIIS ASNECESSARY TODQQNSIRATE TIENEEDFCRAVARIANCEINTKPNSOFTIEcRllKRIA$PEclFIEDINRIAE5Dei210(PAGE0FTHEPART22RIAKs~~ODC~IYEStOgReReportSubmitted 12/6/91LITEM5EXPECTEDWASTEWATER CHARACUNETSCODE1Mg/I2Ug/I3COUNTS/100ml4S.U.5FSLBS/GAYTIEAPPLICANI'AY BERECUIREDTODOAIXIITICIAL HASTEANALYSESP AeDISCHARGE CHAIIACTKR ISTICSCONCBIIRATIONQXNOTAPPLICABLK/BELIEVED ABSBITRtKSENTPDATAPROVIDEDINl7817CIINITSCCOE0ANALYSESCODEBOO5(FIVEDAYBIOCteIICALOXYGENDKHAte)'COD(DeIICALOXYGBIDKHAND)'TOC(TOTALORGANICCARBCN)~5,~0,L00IAttsNIANITROGBI(ASN)TOTALSUSPEMKDSOLIDSTOTALPteSPICRUS (ASI)TOTALRESIlll4L OLORINEDISSOLVED OXYGENHIN~.LJ~0.~020.~08PLJu>~52FECALCOLIFCRHBACTERIA'nmaaTIEIK (SIPtER)TBFERATINE (HINIER)LLJ~LJLJ~~LJBeOTIBRHASTEHATER OIERACTERISTICS u>LJ5LJEeIISTALLCte)ICALSISSTAtCES lIHIDIAREINNICHIGANSCRITICALHATKRIALS REGISTERTAKEIVcPAGEII)ANWORUS.EPASPRICRllYRXLUfANTLISTTAREV(PAGE7)ORANYOIIERSLBSTAtCES MICHAREOIHAYBKO%IMRIOUSTOTIEKESIGNATKD USESOFTIEGIXNDN8eTKR CRTO7%PUKICtEALTHTHATAREDISCHARGED OREXPECTEDTOBEDISCNRGKD TQTIEGRIXNDIATBL7IY 1HISFACILllYe ESTIHAlKTHKFINALEFFUENTCOMXNIRAT IONANDREQRDALLDATAINITBI7OFSECflCNIIIN1HISBOOIUTP~SAWPEJXBF1GRAB224HOURCOMPOSITE 0IL8GREASELCHLORIDE<ULFATELT;OETALIL~10,E99e~80,I00I0208~195, 010;20~582925,~0~8~0~0~1~521~52~161u'LJ2~2LJLJ~LJLJRECUIREDItAAQTIIN RNSt%FACEHATERDISONRGESP Analyst.s perJ.B.Beauboeuf, TargetPermitEffluentLimitsList. INSTRUCTIONS FORCCMPLETING SECTIONIIITEMS4ANO5ThisforpprequiresInformation onaspecificoutfalIdischarging toeItherthegroundraters orthesurface~aters.ENTERTHEPERMITNPIBERINTHEBOXATTHETCPOFTHISFORM.THEPERMITN(D(BERCANBEFOUNDONTHEFRCNTPAGEOFYOUREXPIRINGPERMIT.IfthlSiSanerOrnOtpreVIOuSly permitted faCIllty,thenleaVeblankandanumberWillbeaSSlgned. EntertheoutfallnumberInthesDaceprovidedforeachpageofSectionII.ForeachIndividual dlscharoe pointasearetesetofSectionIIforms(Iteypps4andS)mu5tbefilledout.ITEM4GROUfd)WATER DISCHARGE INFORMATION (DONOTINCLUDEDEEPWELLINJECT(Off INFORMATION INTHISITEM)A.-O.TheaDDlicant shalladdresseachofthesepartslfthedischarge frcmthisoutfallIstotheoroundwater. ITEM5EXISTINGOREXPECTED(FORANEWDISCHARGE) WASTEWATEP. CHARACTERISTICS OFGROUNDWATER ORSURFACEwATERDISCHARGE (00NOTINCLUDEwLLINJIININHA.Theapplicant shallreportavailable discharge data(realdataforexistingdischarge orexpecteddataforaproposeddischarge) fortheparameters aslisted.Theseparameters shallbeaddressed foreitherasurfacewaterdischarge otasaDDroDrlate foragroundwater discharge. Forassistance Indetermining appropriate parameters agroundwater dlscharoe applleantmaycontacttheGroundrater QualltyDivision, PermitsSectionortheappropriate Groundrater QualityOlvlslcn's Districtoffice.TheapDI)cant shallreportthesampletypecodebestdescribing eachreportedplaceofdata.Seecodingontheleftmarginofthisform.IfthisoutfallIsasurfacewaterdlscharqe, theapplicant mustreportquantitative dataforeachparameter Identified banhppy,opttpdhodpt~b~,oheoPttbppotdbydedItl\,hbehdPttto4MttthloplltlB.IfdataIsavailable forotherparameters notlIstedaboveInA.orotherpartsotthisapplication theapplicant shouldreportthatdataIntheblankspace5providedInthispart.NOTESlI.Unitcode5torparmppeters reportedInpartsAandBcanbefoundontheletthandsideofthisform.2.GrabsampleshallbeusedtoanalyzeforpH,temperature, totalphenols,residualchlorine, oilandgrease.andfecalcoliformInasurfacewaterdischarge unlessotherfrequency-sample typeanalysesareavailable. SeeGlossary(page48)fordetlnitlon otgrabsample.3.24-hourcomposite samplesshallbeusedtoanalyzeforTotalBQos,coo,Toc,AnmonlaNitrogen, andTotalSuspended SolidsInasurfacewaterdischarge unlessotherfrequency-staple typeanalysesareavailable. SeeGlossary(page48)fordetlnltlon of'composite seppple.4.REPORTING OFINTAKEDATA.Youarenotrequiredtoreportunlessyourlshtodemonstrate yourellglbllltyforaunct"etfluentIlmltatian tOrOneOrmOrePOllutantSP thatIS,aneffluentllmltatlOn adjuatedbySubtraCtlng theaveragelevelofthepollutant(s) presentInyourIntake~ater.NPDESregulations allownetlimitations onlyIncertainclrcumstance5. Todemonstrate youreligibility, reporttheaverageoftheresultsofanalysesonyourIntakewater(Ifyourrateristreatedbeforeuse,testthewaterafterItIstreated), andattacha5eparateSheetcontaining thefollowing foreachpollutant: la)Astatement thattheIntake~aterIsdrawnfromthebodyofraterIntowhichthedischarge Ismade.(Otherwise, youarenoteligibletornetlimitations.) (b)Astatement ottheextenttowhichthelevelofthepollutant Isreducedbytreatment ofyourwastewater. (Yourlimitations willbeadjustedonlytotheextentthatthepollutant isnotremoved.) (c)WhenapDIlcable (forexsnple,whenthepollutant reDresents aclassofccmppounds), ademonstration ottheextenttowhichthepollutants IntheIntakeveryphysically, chemically,orbiologically fromthepollutants contained InyourdIscharge. (Yourlimitations willbeadjustedonlytotheextentthattheIntakepollutants donotvaryfromthedischarged pollutants.) 5.Ifyouhavetroormoresubstantially Indentlcal

outtalls, youmayrequestpermission franyourpermitting authoritv tosampleandanalyzeonlyoneoutfallandsubmittheresultsoftheanalysisforothersubstantially Identloal OutfallS.

IfyOurrequeStISgrantedbythepermitting authOrlty, OnaSeparateSheetattaChedtOetheapplication formIdentifywhichoutfallyoudidtest,anddescribewhytheoutfallsrhlchyoudidnottestareSubStantlally IdentlCal tOtheOutfallrhlChyOudidteSt.36 SEEINSTRUCTIONS ONREVERSESIDESECTIONIIPERMIT~IYIXQOQ5827NUMBERODDEM6PRIORITYPOLLUTANTS ANDADDITIONAL INFORMATION FORSURFACEWATERDISCHARGE ONLYTHEFQLIQtl%REQUESTED 1%'ORHATION~rADQIESSED ~MIFACEHATERDISCHARGERS ~IDIEtNEWUSEDISOQRGERS Q5U.PROVIDEEXPECTEDVALIFORTHEQUANTITATIVE AMDQUALITATIVE INFORMATION RECITEDBEIQteAIISTHISFACILllYAPRIWVIYINDUSTRY? (REFERTOTABLEIAPAf<g3(IF%,GOTOK) (IFYSGOTOB)BIINDICATETYPEOFPRIMARYINDUSlRYASLISTEDINTABLEIAPAGEgl.(CONTINUE WITHC.)CIDOESTHISOUTFA!LDISCHARGE CONTAINANYPROCESS'HASTEHATKR? (IFNQ,GOTOE)(IFYESiGOTO0)DIINDICATElHICHGC/HSFRACTIONS HUSTSETESTEDFORI(REFERTOTABLEIAPAfKIII)IDIKIFORFAOIGC/HSFRACTIONCHECKEDsEACHSPECIFICORGANICTOXICPOILUTAttf HITHINEACHFRACTIONIBISIBEANALYZEDFOR(SEETABLEIIAPAGE02,INADDITION, AILPRll@RYINCUSTRYAPPLICANTS WITHAPROCESSWASTEHAlKR DISOIARGE QffPROVIDEQUUITITATIVE DATAFOREACHTOXICPOLUITAMT INTABLEIIIAPNK99IRECORDALLDATAOMFOILSPROVIDED(ITKH7)INTHISSOQKLETI(CXITItttE HITHE-KBEilH)E~IF~QIIFACEHATERDISCHARGE APPLICANT (PRIMARYORSECCNDUIY INDUSTRY)s REGARDLESS OFTHETYPEOFDISCHARGE KttltsCRNSREASONTOBELIEVETHATANYPIXLUTAMT LISTEDINTAREIIAANDIVAPAGES~ISDISCHARGED FRCHANYCIIFAL41tE QUUITITATIVK DATA~SEPROVIDED+ RECXIDALLDATAONFNttSPROVIDED(ITKH7)INlHISBOOKLETeSTMLECWRXYESNOQ~nuAnalysisperQJ.B.Beauboeuf TargetPermitQ~mEffluentLimitsQPESTICIDE %TAPPLICABLE/BELIEVED ABSENTN/AFaIFANYQRFACEMATERDISCHARGE APPLICAMf (PRINRYORSECCNDUIY IMXISTRY)a REGARRESS OFTYPEOFDISOIARGG K%wsORHASREASQITOBELIEVEANYPOLUITAMIS LISTEDINTABLEVAPACk+AREDISCHARfkD FRCttANYOUTFAlLTIEAPPLICANT ~HDESCRIBERFASONSFORTIEPCLUTAMTBE1%PRESENTA%PROVIDEAMYAVAILABLE QUAMflTATIVE DATA'ECORD ALLDATAOMF<ASPROVIDED(ITKH7)IMTHISSOQIGEfoG>>AILQRFACEHATERDlSCNRGEAPPLICANfS (PRIMARYA%SECCNDARY IIGXISTRIEs)ORACTIIIESLttifTRIQSIXIOPIE%XY ACETICACID(2s4i5T)tTRloaoeeaae PROPANOIC Aclo(SILYKx,Kti,5,TP)4,WgI~aagaOXY) KIHYL2,2-DIOSJXIOPROPICNAIK~(' 0,IrVTRIOLOIOPtENL (TCMPiORHEXAOLOROPIENE tHCPRI(AUDATAFCRTIEABOVEtKISTBEGENERATED USI%STA%ARDANALYfICALCALISRATICN PROCEDQIKS) ORKRISORHASREASON10BELIEVETHATTCCDISORHAYBEPRESENTINTIEIRDISCHARGEo ~REPORTtXIALITATIVK DATAeGKIERATKD l43ICHUSEDASCREENING PROC6XIIE KITCALIBRATED HITHANALYTICAL STAIKARDSi FOR6A/8i-TKIIIAOEOIROISEKKPP DIOXIN(TCCD)>>REIXIIAILDATAOMFOESPROVIDED(ITKHk)INTHISNOKLETIJIIFTIEQRFACEHATERDISOIARGE APPLICANT KM'RHASREASON10BELIEVE1HATBIOUXilCAI TOXICITYTESTSHEREHADEIN1HELASTTIRKEU)YEARSONAMYOFTIEAPPLICANT SDISCHARGES CRONARECEIV1%HATERINRELATION10ADISCHARGE PROVIDElHISIWÃHATION ASAttATTAOtENT TOTHISAPPLICATIONe KIIFACOMIRACTLABORATORY ORCONQLTI%FIRNPERFOR%DANYOFTIEAIKAYSESREQUIREDBY1HISAPPLICATION PROVIDETIENt%ANDAIXRESSOFEACHIABORATCRY ORFIRIA%THEAIQLYSESPKRFQttED ASAMATTACHMENT CFTHISAPPLICATICNI LIDQYOUDISCHARGE Ath'THERTOXICORINtIRIOUS DKHICALQSSTAMCES MTLISTKDINTARESIVPAGEDAlOIIAllttCAlVAPtV4S~~IIFYESsTANIDENTIEYTlEOellCALSUBSTANCES AMDESTIWLTKTIEFINALEFFUEHTCCNCENIIIATIOISI SIKFIITTHISItAAIATICN ASANATTAOtENT TO1HISAPPLICATION>> %TAPPLICABLE/SELI EYEDABSENTN/APRESENf/DATA ISAlTACHEDQNTAPPLICABLE/BELlEVKD ABSENTN/AQPRESENf/DATA IsATTAOEDg%TAPPLICABLE APPLICABLE/SKK ATTAQEDQ%TAPFLICASIZ gAPPLICABIZ/SEK ATTAOIEDQX%TAPPLICABLE APPLICASLEJSKK ATTAQIKD37 INSTRUCTIONS FORCCMPLETING SECTIONIIITEM6ThisformrequiresInformation onaspecificouttalldischarging tothesurfacewaters.ENTERTHEPEIBIITNUMBERINTHEBOXATTHETCPOFTHISFORM.THEPERMITNIPIBERCANBEFDNIDONTHEFRONTPAGEOFYOUREXPIRINGPERMIT.IfthisIsanewornotpreviously permItted

facility, thenleaveblankandanumberwillbeassigned.

EntertheoutfallnumberInthespaceprovidedforeachpageofSectionII.ForeachIndividual dlscharqe pointaseparatesetofSectionII,Item6formsmustbeflIledout.PRIORITYPOLLUTANTS ANDADDITIONAL INFORMATION ITEM6NOTE:Ifyouhavetwoormoresubstantially Indent)eel outfalls,youmayrequestpermission fromyourpermitting authority tosampleandanalyzeonlyoneoutfallandsubmittheresultsoftheanalysisforothersubstantially Identical outfalls.IfyourrequestIsgrantedbythepermitting authority, onaseparatesheetattachedtotheapplication formIdentifywhichoutfallyoudidtest,anddescribewhytheoutfallswhichyoudidnottestaresubstantially Identical totheoutfallwhichyoudidtest.NOTE:40CFRPartI22.2l(g)(8), Friday,AprilI,1983,providesforaSmallBusinessExemption fromthereporting ofquantitative datafororganictoxicpollutants andtoxicpollutants asrequiredbyPartI22.2)(g)(T)(ll)(A) orI22.2I(g)(7)(ill)(A). A.-C.Thesepartsareselfwxplanatory anddonotrequirefurtherInstructions. SimplygothrougheachparranddoasIndicated. andE.-J.0.SeveralIndustrial categorlssandsubcategories havebeenexemptedfransubmitting dataoncertainGC/MSFractions (40CFRPartl22,Vol.48,No.64,Friday,AprilI,l983,NotesI,2,and3).Reviewthefollowing listtodetermine whetheryourteellityqualifies tobeexemptfromreporting GC/MS(GasChrcmatogl aphy/MassSpectroscopy) Fractions. TextlleMlIIsIndustGC/MSFractIonTestingandReportIng Exemptions -AlItourGC/MSorganictractlons IntheGreigeMlIIsSubcategory. -Pesticide fractionInallothersubpartsofthisIndustry'. OreMlnlnandOresslIndust-Volatile, base/neutral, andpesticide fractions IntheBaseandPreciousMetalsSubcategory. -AlIfourGC/MSorganicfractions inelIothersubcategories ofthisIndustry. GusandWoodChemicals Industr-Pesticide fractionintheTallOilRosinSubcategory andtheRosinBasedDerivatives Subcategory. Pesticide andbase/neutral fractions in~IIothersubcategories ofthisIndustry. PulandPaperIndustr-Pesticide fractIonInPapergrade Sulfitesubcateqorles (subparts Jand0).-Base/neutral andpesticide fractions InDelnkSubpart0,Dissolving KrattSubpartF,andPaperboard fromWastePaperSubpartE.-Volatile, base/neutral, pesticide fractions IntheBCTBleachedKraftSubpartH,Semi-chemical Subparts8andC,andHonlntegrated-Fins PapersSubpartR.-Acid,base/neutral, andpesticide fractions inFineBleachedKraftSubpartI,Dissolving SulfitePulpSubpartK,Ground-woodFinePapersSubpart0,MarketBleachedKraftSubpartG,TissuefromWastepaper SubpartT,andNonlntegrated TissuePapersSubpartS.SteamElectricPowerPlantIndustr-Base/neutral fractionIntheOnceThroughCoolingWater,FlyAsh,andBottomAshTransport Waterprocesswastestreams. 38 SEEINSTRUCTIONS ONREVERSESIDESECTlONIIODDppp5827.EM7CRITICALMATERIALS TOXICPOLLUTJLNTS A,USETHISDATASHEEfTORECORDIHFCRMATION ASRECLJIRKD IN;(OKCXAPPROPRIATE BOXJORttIICHINFCRMATICN THISDATASHEETREPRESEMTSI) X1SECTIONIIgITEMMIGROLMXCLTKR DISOIARGE INFORMATION (PAGE35)DDX2.SECTIONllITEM6PRIORITYPOUJJTANfs IMSLRFACElATERDlscttVYZ (PAGE37)D~31BoBELOW:CRITICALMATERIALS (TABLEIV)INSLJLFACEHATBOXDISCHARGE (PAGE3J))HAZARDOUS SUBSTANCES INDISCHARGE BoLISTANYCRITICALMATERIAL(TABLEIVPJGE6)NOTADD!ESSED INSECTIONllITEM6PRIORITYPOLUJfAMTS !4IICHYLXJttOWORHAVEREASONTOBELIEVETOBEPRESENTINTIP.DISCHLRGEs SEEREVERSESIDEOFlHISPAGEFORFLJITIERDIRECTIONss XlerAPPUcASEAPPLICABLE (SEEBKLCtt)CCIII'AINLMEOFCRITICALMATERIALCRPRIORllYPOLUJTAMT BoAVERAGECCNCBIIRATIONJ SANTElYPEJItOFANALYSESCaHAXIISJICONCBIIRATICN A!OMASScHdrazine0WITCODELJLJOFANAlYSESWITCXENITCODEILIII'UNITSCODE1MQ/IUQ/ILBS/DAYKG/DAY~AMP~LT1GRAB224HR.COMP.CCIII'sQt%OFCRITICALHATERIALORPRIORllYPOLLIJTAMT BIAVKRJGECCICEMTRATICNJ SANDIETfPEJttOFANALYSESCIMAXIJLHCCNCENIRATION AJOMASSA>>NA%OFCRITICALMATBUALCRFRICRllYRXLUTAMfB.AYBLAGEcctcKMIRATICNJ senzTYPE;1IDFANALYSESCsMAXIMP!CctCENllLAT IONAt41MASSAINA%OFCRITICALMATERIALORPRIORllYPOLUJTANT BIAVERAGECOtCBIIRATICNJ QIANAlYPEJ0OFANALYSESCIHAXItMLCOtCIDI!RAT ICNAJOMASSAeQP%OFCRITIQLHATERIALCRPRICRllYFOLUJTANT BoAVERAGECNCBIIRATILXIJ QPRETYPEJJIOFANCLYSESCIMAX&PICCNCENIIIATICN AtOMASSAISV%OFCRITICALtVLTERIAL ORPRICRITYPOLUJTANT BIAVKRAGECCNCENIRATIONJ QIANATYPES0CFAMJLYSESC.HJNIJSJLCaLKMIILATICN AJOMASSANt%OFCRITICALMATERIALORPRIORllYPOUJJTANT B.AVERAGECONCBCIRATICNJ SAMPLETYPE,'JOFANALYSESC>>t%XIMPLCCCL'BIIRATION AtOHASSAINAMEOFCRITICALMATERIALORPRIORITYFOUlJTANT BoAVERAGECOMCKM!ILATIONJ SANTETYPEJJJOFANALYSESCJXEWITCODELJNITOXE54%LETYPEFOFANALYSESNITCQJESAINTlYPEOFANALYSESLJNITCCOEWITCCOELJ~~~LJLNITCCCE~lYPEJJOFANALYSESNITCODENITCODELJ~~~LJLJIITCCOEQJPLETYPEOFANALYSESLJWITCODEWITCOCKLJ~~~LJLJIITCXXEQWlKTYPEOFANALYSESLLLJLJWITCODELJIITCODELJ~~~LJNITCJXE~TYPEOFANALYSES"Chlorine(SodiumHochl!WLTCCXJESAIFLETYPEOFANALYSESLJNITCOXWITCOKECsMAXI'ctCBIIRAT IONAIOMASSWITCODENITCODELJ~~~LJHydrazine orSodiumHypochlorite arenotexpectedtobepresentindischarge butACDITICNAL PJGESOFTHISITEM7AREATTmmFORTIBRESTOFnaCRITICALClYESMATERIALS AJO/CRPRICRTIYPOUltrAMTS RECUIRKDTDBEREPORTED. ENOsmallquantities maybefoundintheTurbineRoomSumpbutwouldnotbeexpectedtobefoundintheactualdischarge flowtotheabsorption pond.39 INSTRUCTIONS FOR(XMPLETIIQSECTIONIIITEM7ThisformIstobeusedbybothsurfaceandgroundwater applicants torecordInformation onnnyHlchlgancriticalmnterlnl, E.P.A.prioritypollutant, orhazardous substance inwhichthisapplication requiresdatatobeprovided. ThiswouldIncludeonychemicalsubstance tromtheMichiganCriticalMaterials Register(TobleIV),theE.P.A.PriorityPollutant Listing(TableV),orTablesIIA-YAwhichIlatsOrganicToxicPollutants, OtherToxicPollutants, Conventlonnl andNonconventional Pollutants nndHazardous Substances. ITEH7CRITICALMATERIALS, PRIORITYPOLLUTANTS AND/ORHAZARDOUS SUDSTANCES INTHEDISCHARGE MaterialI23~..8A.Listthenomeofthechemlcolsubstance (critical

material, prioritypollutant, orhazardous substance) frrmrTablesIyyVondIIA-YAasrequiredInthebox<<hlchyoucheckedInA.l3.above.Entereachchemicalsubstancers,parameter numberaslistedInTablesIV,VandIIA-VAlfprovided.

8.Providetheaverageconcentration ofthechemicalsubstance namedinA.Indicatethesampletypeusednndthenumberofanalysesmodetoprovidetheconcentration dataforthechemicalsubstance namedInA.C.Providethemaximumconcentration nnddetermine themassloadingofthechemicalsubstance nrrrredInA.NOTESrI.Itonlyoneanalysiswasmodeforachemicalsubstance thenrecordthntdataasnmaximus,value. Itmorethanoneanalysishosbeenmodetorachemicalsubstance thenprovideanaveragevalueofthoseanalysesnndthemaxim'alue. 2.ThisSectionII,Item7,DataSheetprovidesspaceforrecording dntnfor8chemicalsubstances (Materials) ~Additional spaceforrecording ofdatatormorethon8Materials canbemadebymakingcopiesofthisItem7DataSheetasneeded.ItIsolsoImportant touseaseparatesetotOntoSheetsforeachapplicable reporting requirement aslistedInA.l-3.andforeachouttall.Refertotheleftmarginforthecodenumberrepresenting thesampletypeusedandtheappropriate unitcodes.40 LockheedAnalytical ServicesINDIANAMICHICANPOWERCOIWPANYSAMPLEANALYSISSUIVIIVIARY PACKAGEFORVOLATILEANDSEMI-VOLATILE

ORGANICS, PESTICIDE/PCBS,

CHLORIDE, NITRATE/NITRITE, SULFATE,FLUORIDE, CYANIDE,IVIETALS, ANDMERCURYLOG-INNUMBER:QUOTATION NUMBER:L1009Q331620DOCUMENTFILENUMBER:1229485

bloc/rheed Environmenta/ Systems6Techcgeyfe~ CoLockheedAnalytical Services975KellyJohnsonDriveLasVegas,Nevada89119Q705 Phone:(800)361-0220Fax:(702)361-6434February4,1994Mr.RockyBeemCookNuclearPlant1CookPlaceBridgeman, Ml49106RE:Log-inNo.:Quotation No.:DocumentFileNo.:L1009Q3316201229485Theattacheddatapackagecontainstheresultsofanalysesonsamplesthatweresubmitted toLockheedAnalytical ServicesonDecember29,1993.Thesampleswerereceivedat5'C.SUMMARYANALYSISSTATEMENT: Inorganics Allgroundwatersampleswerereceivedingoodcondition onDecember29,1993.Allsampleswereanalyzedwithinthemethod-specific holdingtimes.Themethodblankswerefreeofcontamination. AllInternalQualityControlwerewithinacceptance limitswiththefollowing exception: Thematrixspikerecoveries forbariumandseleniumwereslightlyoutsideofacceptance limits.Theacceptable recoveryoftheLaboratory ControlSamplessupportsthattheanalytical systemswereoperating withincontrollimits.Thereporting detection limitfornitritewasraisedto0.50mg/LforsampleS.SewagePlantEff.(L1009-4) duetointerferences fromchloride. OrganicsMethod8260Allcalibrations andqualitycontrolcriteriaweremetwiththefollowing exceptions: Allsampleswereanalyzedinitially withinholdingtimesbutfailedsurrogate recoveryQClimits.Thesampleswerereanalyzed onedaybeyondthemethodspecified holdingtimeandallsamplesmetsurrogate recoveryQClimits.Tentatively identified compoundsearcheswereperformed onallsubmitted samples.Onlythereanalyses arereported. 0 COOKNUCLEARFebruary4,1994PAGE2Method8010/8020 Allcalibrations andqualitycontrolcriteriaweremetwiththefollowing exceptions: Thematrixspikeandmatrixspikeduplicate precision for1,1-dichloroethene exceededtheQCcriteriaalthoughallpercentrecoverycriteriaweremet.Dataqualityisnoteffected. Method8270Allsampleswereextracted andanalyzedwithinthemethodspecified holdingtime.Allinitialandcontinuing calibration criteriaweremet.Bis(2-ethylhexyl)phthalate wasdetectedinthemethodblankat1.3ug/L.Therewasnoothercontamination detectedinthemethodblank.Percentrecoveries forallsurrogate compounds waswithinQClimitsforallsamplesanalyzed. Alaboratory controlsample(LCS)andlaboratory controlsampleduplicate (LCSDUP)waspreparedandanalyzedwiththissetofsamples.Thepercentrecoverycriteriaforallspikedcompounds waswithintheQClimitsaswastherelativepercentdifference betweenthetwo.Theresponseforbis(2-ethylhexyl)phthalate insampleTRANS.CATCHBASIN exceededthecalibration rangeintheinitialanalysis. Thesamplewasreanalyzed atadilutionof1:4andallcompounds fellwithinthecalibration range.Bothsetsofresultsarereported. Method8080Allsampleswereextracted andanalyzedwithinthemethodspecified holdingtime.Allinitialandcontinuing calibration criteriaweremet.Nocontamination wasfoundinthemethodblank.Fewofthesurrogate spikerecoveries werewithintheQClimitsduetoanapparentspikingsolutionproblem.Dataqualityisnoteffectedsinceallpercentrecoverycriteriaweremetforthelaboratory controlsampleandlaboratory controlsampleduplicate. Notargetcompounds weredetectedabovethereporting detection limitandtherewasnodilutionorreanalysis performed. Ifyouhaveanyquestions concerning theanalysisorthedatapleasedonothesitatetocontactJamesL.Jordan,(702)361-3955, ext.289.Releaseofthisdatareporthasbeenauthorized bytheLaboratory DirectorortheDirector's designeeasevidenced bythefollowing signature. JamesL.JodanClientServicesRepresentative JLJ/atcc:ClientServicesDocumentControlDepartment El bloc/r/reed LockheedAnalytical Services975KellyJohnsonOriveLasVegas.Nevada891194705 Phone:(800)582-7605Fax:(702)3618146February17,1994Mr.RockyBeemCookNuclearPlant1CookPlaceBridgman, Ml49106

DearRocky,

Peryourrequestduringourphoneconversation thismorning,thefollowing isanexplanation oftheprocedure usedforthedetermination ofthenon-standard organiccompounds inyourgroundwater samples.Thesampleswereanalyzedusinginstruments thatweresetupforstandardmethods8260and8270,Afewofthecompounds onyourlistsofanalytesarenotstandardmethod8260or8270compounds. Oncethesamplesareanalyzedandachromatogram wasobtainedforthesamples,allpeaksthatwerepresentinthesamplesthatdidnotcorrespond tooneofthecalibrated compounds wereinvestigated further.Thisinvolvedtakingthemassspectraobtainedfromthesepeaksandcomparing thespectratoanNISTlibraryofspectra.Thislibrarycontainsapproximately 52,000knownmassspectra.Themassspectraoftheadditional analytesofinteresttoyouarecontained withinthislibrary.Noneofthenon-standard analytesweredetectedinanyofyoursamples.Forthenextquartersroundofsampling, weareendeavoring toobtainthestandards forthesecompounds sothattheywillbecalibrated forintheanalysesofthosesamples.Ifyouhaveanyfurtherquestions orifIcanbeofanyfurtherassistance, pleasedonothesitatetocallmeat(702)361-1626ex.289.'ncerely, JamesL.rdanProjectManagercc:M.Butler

LockheedAnalytical ServicesDATAQUALIFIERS FORINORGANIC ANALYSES/Revised08/28/92) ForUseontheAnalytical DataReporting FormsDENX,Y,orZForCLPAnalysesOnly-Reportedvalueislessthanthecontractrequireddetection limit(CRDL)butgreaterthanorequaltotheinstrument detection limit(IDL).ForRoutine,Non-CLPAnalysesOnly-Anyconstituent thatwasalsodetectedintheassociated blankwhoseconcentration wasgreaterthanthereporting detection limit(RDL).Presenceofhighlevelsofinterfering constituents requireddilutionofsamplewhichincreased theRDLbythedilutionfactor.Estimated valueduetopresenceofinterference. Sampleanalysisperformed outsideofmethod-or client-specified maximumholdingtimerequirement. ForCLPAnalysesOnly-Duplicate injection precision criterion wasnotmet.Matrixspikerecoveryexceededacceptance limits.Reportedvaluewasdetermined fromthemethodofstandardaddition. ForCLPReporting Only-Constituent wasanalyzedforbutnotdetected(samplequantitation mustbecorrected fordilutionandpercentmoisture). ForAASOnly-Post-digestion spikeforFurnaceAASdidnotmeetacceptance criteriaandsampleabsorbance islessthan50%ofspikeabsorbance. Analyst-detined qualifier. Relativepercentdifference (RPD)forduplicate analysisexceededacceptance limits.Correlation coefficient (r)fortheMSAislessthan0.995.ForUseontheQCDataReporting FormsThespikerecoveryand/orRPDformatrixspikeandmatrixspikeduplicates cannotbeevaluated duetoinsufficient spikinglevelcomparedtotheelevatedsampleanalyteconcentration. TheRPDcannotbecomputedbecausethesampleand/orduplicate concentration wasbelowtheRDL.'sedasfootnotedesignations ontheQCsummaryform. LockheedAnalytical ServicesDATAQUALIFIERS FORORGANICANALYSES(Revised04/20/93J ForUseontheAnalytical DataReporting FormsDHX,Y,orZForCLPanalysesOnly-TheTICisasuspected aldol-condensation product.Anyconstituent thatwasalsodetectedintheassociated blankwhoseconcentration wasgreaterthanthepractical orreporting detection limit(PQLorRDL).Constituent contirmed byGC/MSanalysis. (pesticide/PCB analysesonly/Constituent detectedinthedilutedsample.Italsoindicates thatanaccuratequantitation isnotpossibledueto~surri~ate.beingdilutedoutofthesamplesduringthecourseoftheanalysis. Constituent concentration exceededthecalibration range.Thequantitation isnotgasolineordieselbutbelievedtobesomeothercombination ofhydrocarbons. Sampleanalysisperformed outsideofmethod-orclient-specified maximumholdingtimerequirement. Estimated value-(I)constituent detectedatalevellessthantheRDLorPQLandgreaterthanorequaltotheMDL;(2)estimated concentration forTICs(ForCLPReporting Only).ForCLPReporting Only-Tentatively identified constituents (TICs)identified basedonmassspectrallibrarysearch.ForCLPReporting Only-Thepercentdifference betweentheconcentrations detectedonbothGCcolumnswasgreaterthan25percent(pesticide/PCB analysesonly).ForCLPReporting Only-Constituent wasanalyzedforbutnotdetected(samplequantitation mustbecorrected fordilutionandpercentmoisture). Analyst-detined qualitier. ForUseon-theQCDataReporting FormsnIhlQCdata(i.e..percentrecoverydataformatrixspike,matrixspikeduplicate, laboratory <<iintrolstandard. orsurrogates: andRPDformatrixspikeduplicate orunspikedduplicate) exceededacceptance limits.Thespikerecoveryand/orRPDformatrixspikeandmatrixspikeduplicates cannotbeevaluated duetoinsufficient spikinglevelcomparedtothe,elevatedsampleanalyteconcentration. TheRPDcannothecomputedbecausethesampleand/orduplicate concentration wasbelowtheRDL.Useastootnotetesignations onthesummarytorm. VOLATILEORGANICANALYSISRESULTSGC/HALLANALYSESUSINGEPAMETHOD8010linamIID:TRDIId:2-DEDateAnalzed:04-JAN-94 Matrix:WATERAnalticalBatch¹:122093-801020-0-3 LALmIID:L1DRive:2-DE-DilutionFactor:1QCBatchID:122093-801020-0-3 BCMBFBrraRevero11492Limi65-12560-120Constituent DihlrdiflrmhnehlrmhnVinIchlorideBromomethane hlrhnTrihlrflrmhan11-Dichloroethene Methlenechloridern-12-Dihlrhn11-DihlrhnChloroform 111-Trichloroethane arnrhlrie12-DihlrhnTrichloro etheneTCE12-Dichloro roaneBrmoihlrmhan2-hlrhlvinlhrcis-13-Dichloro roenetrans-13-Dichloro roene112-Trihl rhnTrhlrhnPEDibromochlorome haneChlorobenzene Brmofrm1122Trhlrhn13-Dichlorobenzene 14-Dichlorobenzene 12-Dichlorobenzene Concentration (/Jg/L)<0.50<3<6<4<0.5<0.5<2Reporting Detection Limit/L0.50.50.5DataQualifier(sl LOCKHEEDANALYTICAL SERVICESAV~

VOLATILEORGANICANALYSISRESULTSGC/PIDANALYSESUSINGMETHOD8020linmIID:TRALmlID:L1DII-DEDRiv:29DEDateAnalzed:04-JAN-94 Matrix:WATERAnalticalBatch¹:122093-801020-0-3 DilutionFactor:1QCBatchID:122093-801020-0-3 TFTBFBrraRver9495Limi70-12075-120BenzeneTolnConstituent Concentration /L0.52Reporting Detection Limit/L0.5DataQualifier shlrnznEthIBenzenem-Xlene-Xlen1-Dihlrnzn14-Dichlorobenzene 12-Dichlorobenzene <2<2<2LOCKHEEDANALYTICAL SERVICESu4 VOLATILEORGANICANALYSISRESULTSGC/HALLANALYSESUSINGEPAMETHOD8010linmlID:TR-ADII:2-DEDateAnalzed:04-JAN-94 Matrix:WATERAnalticalBatch¹:122093-801020-0-3 ALmIID:LlDRiv:2-DDilutionFactor:1QCBatchID:122093-801020-0-3 BCMBFBurroaRvr12086QCLimi65-12560-120Constituent DihlriflrmhnehlrmhnVinIchlorideBromomethane hlrhnTrihlrfl'rmhn11-Dichloroethene MethIenechloridern-12-Dihl rhn11-DihlrhnChloroform 111-Trichloroethane rnrhlrid12-DihlrhnTrichloroethene TCE12-Dichloro roaneBrmihlrmhn2-hlrhlvinlhrcis-13-Dichloro roenetrans-13-Dichloro roene112-TrihlrhanTerahlrhnPEDibromochloromethane Chlorobenzene Brmfrm1122-Trhlrhn13-Dichlorobenzene 14-Dichlorobenzene 12-Dichlorobenzene Concentration (yg/L)<0.50<3<6<4<0.5<0.5<2Reporting Detection Limit/L0.50.50.5DataQualifier(s) LOCKHEEDANALYTICALSERVICESnr.1JV

VOLATILEORGANICANALYSISRESULTSGC/PIDANALYSESUSINGMETHOD8020linmlID:TR-ADII:2-DDateAnalzed:04-JAN-94 Matrix:WATERAnalticalBatch4:122093-801020-0-3 LALamIID;L1DaRiv:2-DE-9DilutionFactor:1QCBatchID:122093-801020-0-3 TFTBFBrraRevr9797QLimi70-12075-120BenzeneTInConstituent Concentration IL0.53Reporting Detection LimitIL0.5DataQualifier shlrnznEthIBenzenem-Xlene-XIn1-Dihlrbnzn14-Dichlorobenzene 12-Dichlorobenzene <2<2<2LOCKHEEOANALYTICALSERVICEShg linmIID:TRSVOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260LALmIID:L1-41Page1of2DateCollected: 28-DEC-93 Matrix:WATERAnIiIBh¹:114-2-F2QCBatchID:011094-8260-F2 DateReceived: 29-DEC-93 DateAnalzed:11-JAN-94 DilinFr:1SURROGATE RECOVERY12-Dihlrhn-d4TIn-4-Bromofluorobenzene 488QCLimits7-11486-115Constituent Chloromethane VinIhlriBrmmhnChloroethane Trichlorofluoromethane An11-DihlrhnCarbonDisulfide MethleneChlorideran-12-DichlrohnVinIAcae11-Dichloroethane 2-Butanoneis-12-Dihlrhnhlrfrm111-Trichloroethane CarbonTerachloride 12-DihlrhnBnznTrichloroethene TCE12-Dichloro roaneBromihlrmhn2-hlrhIVinIhr4-MethI-2-entanonecis-13-Dichloro roeneTolnrn-1-Dihlrrn2-Hexanone 112-Trichloroethane Tetrachloroethene PCEConcentration IL<5<5<5<5<5<10<5<10<5<5<5<5<2<10<5<10<5<5Reporting Detection LimitIL101010DataQualifier sLOCKHEEDANALYjICALSERVICESlu

ClientSamleID:TRSVOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260LALSamleID:L1009-41Page2of2Constituent Dibromochloromethane ChlrnznEhlnnm-Xleneo-XlenernBrmofrm1122-Tetrachloroethane 13-Dichlorobenzene 14-Dihlrnzn12-Dichlorobenzene Concentration IL<5<5<5<5<5<5Reporting Detection LimitILDataQualifier sLOCKHEEDANALYTICALSERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260TENTATIVELY IDENTIFIED COMPOUNDS ClientSampleID:TRSDateReceived: 29-DEC-93 Matrix:WATERAnalytical Batch:011094-8260-F2 LALSampleID:L1009-41DateAnalyzed: 11-JAN-94 Dilutiorl Factor:1QCBatchID:011094-8260-F2 NONETentatively Identified CompoundEstimated Concentration (yg/L)(10Retention Time(minutes) 0.00DataQualifier(sl LOCKHEEDANALYTICAL SERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260Page1of2linmlID:TR-ADateCollected: 28-DEC-93 Matrix:WATERAnIiIBh¹:114--FQCBatchID:011094-8260-F2 LALmleID:L1-43DateReceived: 29-DEC-93 DateAnalzed:11-JAN-94 DilinFr:1SURROGATE RECOVERY12-Dichloroe han-d4TIn-QCLimits7-1144-Bromofluorobenzene 8986-115Constituent Chloromethane VinIhlriBrmomhanChloroethane Trichlorofluorom ethaneAn11-DihlrhnCarbonDisulfide MethleneChloridern-1-DihlrhnVinIA11-Dichloroethane 2-Butanone i-12-Dihl rhnhlorfrm111-Trichloroethane CarbonTetrachloride 12-DihlrhnBnznTrichloroethene TCE12-Dichloro roaneBromihlrmhn2-hlrhIVinIEhr4-Methl-2-entanonecis-13-Dichloro roeneTInrn-1-Dihlrrne2-Hexanone 112-Trichloroethane Tetrachloroethene PCEConcentration IL<5<5<5<5<5<5<10<5<5<5<5<2<10<10<5<5Reporting Detection LimitIL101010DataQualifier sLOCKHEEDANALYTICAL SERVICESIB VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGIVIETHOD8260ClientSamleID:TRS-QALALSamleID:L1009-43Page2of2Constituent Dibromochloromethane hlrenznEhlnznm-Xleneo-XlenernBrmfrm1122-Tetrachloroethane 13-Dichlorobenzene 14-Dihlrenzn12-Dichlorobenzene Concentration IL<5<5<5<5<5Reporting Detection LimitILDataQualifier sLOCKHEEDANALYTICAL SERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260TENTATIVELY IDENTIFIED COMPOUNDS ClientSampleID:TRS-QADateReceived: 29-DEC-93 Matrix:WATERAnalytical Batch:011094-8260-F2 LALSampleID:L1009-43DateAnalyzed: 11-JAN-94 DilutionFactor:1QCBatchID:011094-8260-F2 NONETentatively Identified CompoundEstimated Concentration Ipg/L)(10Retention Time(minutes) 0.00DataQualifieris) LOCKHEEDANALYTICAL SERVICES SEMIVOLATILE ORGANICANALYSISRESULTS,FORGC/MSANALYSESUSINGMETHOD8270P1f2linmIID:TRDateCollected: 28-DEC-93 Matrix:WATERAnliIBh¹:1114-27-8QCBatchID:8270-SEMIVOLATILES-3964 LALmIID:L1-2DateReceived: 29-DEC-93 DilutionFactor:1DExra:4-AN-4DateAnalzed:11-JAN-94 2-FluorohenolPhenol-d, Nitrobenzene-d~ RRATEREVERY0/412659QCLimits21-10010-9435-1142-Fluorobi henI246-TrirmhnIp-Terphenyl-d,4 559943-1161-1233-141oniuenPhenolbis2-Chloroeth Iether2-hlrhnl1-Dihlrnn14-Dichlorobenzene BenzIalcohol12-Dihlrnzn2-'MhIhnIbis2-Chloroiso roIether4-MethIhenolN-Nir-Di-n-rIminHxhlrhnNitrobenzene Isohorone-NirhnI24-DimehIhnIBenzoicacidbis2-Chloroethox methane4-DihlrhnI124-TrihlrnznNahthalene4-Chloroaniline Hxhlrin4-hlr--mhlhnl2-MethInahthaleneHexachloroc cloentadiene Concentration L<10<10<10<10<10<10<10<10<50<10<10<10<10<10.Reporting Detection LimitL1010101010101010501010101010DLOCKHEEDAh/ALYTICAL SERVICES4w SEIVIIVOLATILE ORGANICANALYSISRESULTSFORGC/IVISANALYSESUSINGMETHOD8270ClientSamleID:TRSLALSamleID:L1009-25P2f2Constituent 24-TrihlrhnI4-TrihlrhnI2-Chlorona hthalene2-Nitroaniline DimhIhhalAnhhln26-Dinitrotoluene 3-Nitroaniline Anhhn24-Dinirhenol4-NitrohenolDibenzofuran 24-DinirInDihIhhI4-ChlorohenI-henletherFluorene4-Nirnilin4-Dinir-2mhIhnIN-Nitrosodi henlamine4-BromohenI-henletherHxhlrnznPnhlrhnlPhenanthrene Anthracene Di-n-IhhIFlrnhnPreneButIbenzIhthalate'-Dihlrnziin8nzonhrnChrsenebis2-Eth)hexIhthalateDi-n-IhhIBnzflrnhnBenzokfluoranthene BenzoareneInn12-crneDinzhnhrnBenzohierleneCarbazole Concentration IL)<10<25<10<25<25<25<10<10<10<2<2<10<10<2<10<101.4<10<10<2<10<101.5<10<10<10<10Reporting Detection Limit(IL)10251025252510101010101010101010101010'101010DataQualifier(s) JBLOCKHEEDANALYTICAL SERIIICES 30 VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8270TENTATIVELY IDENTIFIED COMPOUNDS ClientSampleID:TRSDateReceived: 29-DEC-93 Matrix:WATERAnalytical Batch:011194-8270-8 LALSampleID:L1009-25DateAnalyzed: 11-JAN-94 DilutionFactor:1QCBatchID:8270-SEMIVOLATILES-3964 UnknownUnknownTentatively Identified CompoundEstimated Concentration (pg/L)10020Retention Time(minutes) 6.4430.26DataQualifier(s) LOCKHEEDAIVALYTICALSERVICES3L SEIVIIVOLATILE ORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270P1f2linmlID:TR-ADateCollected: 28-DEC-93 Matrix:WATERAnIiIBhA':1114-27-BQCBatchID:8270-SEMIVOLATILES-3964 LALmleID:L10-27DateReceived: 29-DEC-93 DilutionFactor:1DaExrc:04-JAN-4DateAnalzed:11-JAN-94 2-FluorohenolPhenol-d, Nitrobenzene-d, RRATEREVERY0382661Limi21-10010-9435-1142-Fluorobi henI246-Tribromo hnolp-Terphenyl-d 569743-1161-1233-141PhenolninConcentration L<10Reporting Detection LimitL10Dbis2-Chloroeth Iether2-hlrhnI1-Dihlrnzn14-Dichlorobenzene BenzIalcohol12-Dihlrnzn2-MhIhnIbis2-Chloroiso roIether4-MethIhenolN-Nir-Di-n-rIminHxhlrhnNitrobenzene Isohorone2-NirhnI24DimhIhnIBenzoicacidbis2-Chloroethox mehane24-DihlrhnI124-TrihlrnznNahthalene4-Chloroaniline Hxhlrin4-hlr--mhlhnl2-MethInahthaleneHexachloroc cloentadiene <10<10<10<10<10<10<10<50<10<10<10<10<101010101010101010501010101010LOCKHEEDANALYTICAL SERVICES2 SEIVIIVOLATILE ORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270ClientSamleID:TRS-OALALSamleID:L1009-27P2f2Constituent 24-TrihlrhnI24-TrihlrhnI2-Chlorona hthalene2-Nitroaniline DimhIhhIAnhhln26-Dinitrotoluene 3-Nitroaniline Anhhen24-DinirhnI4-NitrohenolDibenzofuran 2'4-DinirInDihihhl4-ChlorohenI-henletherFluorene4-Niranilin4-Dinir-2mhIhnIN-Nitrosodi henlamine4-BromohenI-henletherHxhlrnznPnhlnIPhenanthrene Anthracene Di-n-IhhIFlrnhnPreneButIbenzIhthalate'-DihrnziinBnznhrnChrsenebis2-fthIhexIhthalateDi-n-IhhIBnzflrnhnBenzokfluoranthene Concentration IIL)<10<10<25<10<25<10<2<25<10<10<10<10<2<10<10<10<10<10<10<2<101.9<10Reporting Detection Limit(ILI1010251025251010101010101010101010101010DataQualifier(si J8BenzoareneInen12ren<101010DienzahanhrnBenzohierleneCarbazole <10<101010LOCKHEEOANALYTICAL SERVICES 0 VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8270TENTATIVELY IDENTIFIED COMPOUNDS ClientSampleID:TRS-QADateReceived: 29-DEC-93 Matrix:WATERAnalytical Batch:011194-8270-8 LALSampleID:L1009-27DateAnalyzed: 29-DEC-93 DilutionFactor:1QCBatchID:8270-SEIVIIVOLATILES-3964 UnknownUnknownTentatively Identified CompoundEstimated Concentration Iyg/L)4100Retention TimeIminutes)5.286.44DataQualifier(s) Hydrocarbon UnknownHydrocarbon Hydrocarbon Hydrocarbon 2029.9730.2631.9832.9433.86LOCKHEEOANALYTICAL SERIIICES ".4 PESTICIDE ANALYSESRESULTSBYGC/ECDUSINGMETHOD8080FORCOOKNUCLEARPLANTClienSamteID:TRSDaeColleced:28-DEC-93 DateExtracted: 04-JAN-94 Matrix:WATERAnalticalBatch¹:012094-8080-A-1 LALSamIeID:L1009-17DaeReived:29-JAN-94 DateAnalzed:21-JAN-94 DilutionFactor:1QCGrouID:8080PEST/PCBS 3965SURROGATE RECOVERYooQCLimitsTCMXDCB655260-15060-150A-BHCB-BHC-BHD-BHCConstituent Concentration IL<0.05.0<0.05Reporting Detection LimitIL0.050.0.05DataQualifier(s) HEPTACHLOR ALDRINHEPTACHLOR EPOXIDEG-CHLORDANE ENDOSULFAN IA-CHLORDANE 44'-DDE44'-DDTDIELDRINENDRINENDOSULFAN II44'-DDDENDRINALDEHYDEENDOLFANLFATEMETHOXYHLRTOXAPHENE PCB-1016PB-1221PCB-122PCB-1242PCB-1248PCB-124PCB-120TECHNICAL CHLORDANE MIREXTCMX-tetra-chloro-meta-xylene DCB-Deca-chloro-biphenyl <0.05<0.0<0.05<0.05<.05<0.1<0.1<0.1<0.1<0.1<5<2<0.10.050.050.050.050.10.10.10.10.1<0.1LOCKHEEDANALYTICAL SERVICES5f PESTICIDE ANALYSESRESULTSBYGC/ECDUSINGMETHOD8080FORCOOKNUCLEARPLANTClienSmleID:TR-QADaeColleced:28-DEC-93 DateExtracted: 04-JAN-94 Matrix:WATERAnalticalBatch¹:012094-8080-A-1 LALSmIID:L1009-19 DateReceived:29-JAN-94 DateAnalzed:21-JAN-94 DilutionFactor:1QCGrouID:8080PEST/PCBS 3965SURROGATE RECOVERYTCMXQCLimits60-150DCB4660-150A-BHCB-BHC-BHD-BHCConstituent Concentration /L<0.05<0.05Reporting Detection Limit/L0.050.05DataQualifier(s) HEPTACHLOR ALDRINHEPTAHLOREPOXIDEG-CHLORDANE ENDOSULFAN IA-CHLORDANE 44'-DDE44'-DDTDIELDRINENDRINENDOSULFAN II44'-DDDENDRINALDEHYDEENDOSULFAN SULFATEMETHOXYCHL RTOXAPHENE PCB-1016PCB-1221PCB-1232PCB-1242PCB-1248PB-124PCB-126TECHNICAL CHLORDANE MIREXTCMX-tetra-chloro-meta-xylene DCB-Deca-chloro-biphenyl <0.05<0.05<0.05<0.05<.05<0.1<0.1<0.1<0.1<0.1<5<2<0.10.050.050.050.050.10.10.10.10.10.<0.1LOCKHEEDANALYTICAL SERVICES52

IVIETALSRESULTSClie'n'tSam"leID:TRSLALBatchID(s):1220imDateCollected: 12-28-93DateReceived: 12-29-93Matrix:round'water P0¹69095-040-3N Constituents: .'Meth'odConcentration .(mIL)..Reporting Detection Limit(mIL)DataQualifier(s) DataAnalzedLALSamleID.AluminumAntimonArsenicBariumBeIliumBoronCadmiumChromiumCobaltCoerIronLeadManesiumMananeseMercuMolbdenumNickelSeleniumSilverSodiumThalliumTinTitaniumVanadiumZinc6010602060206020602060106020602060206020601060206010602074706020602060206020601060206020601060106020<0.20<0.060<0.010<0.20<0.0050.28<0.005<0.010<0.050<0.025<0.10<0.003180.026<0.0002<0.20<0.0400.0055<0.010900<0.010<0.20<0.10<0.050<0.0200.200.0600.0100.200.0050.200.0050.0100.0500.0250.100.0035.00.0150.00020.200.0400.0050.0105.00.0100.200.100.0500.02001-20-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-20-9401-27-9401-07-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-27-9401-20-9401-20-9401-27-94L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13Comments: LOCKHEEDAIVALVTICAL SERVICES 0 METALSRESULTS-ClientSamleID:TRS-OALALBatchID(s):1220imDate:Collected: 12-28-93DateReceived: 12-29-93Matrix:.roundwaterPOP'69095-040-3N

Constituents AluminumAntimonMethod60106020Concentration

{r'nIL'l<0.20<0.060Reporting Detection Limit{mIll0.200.060OatsDateQualtfier{s) .Analied01-20-9401-27-94LALSam'leID"L1009-14L1009-14ArsenicBariumBeIliumBoronCadmiumChromiumCobaltCoerIronLeadManesiumMananeseMercuMolbdenumNickelSeleniumSilverSodiumThalliumTinTitaniumVanadiumZinc60206020602060106020602060206020601060206010602074706020602060206020601060206020601060106020<0.010<0.20<0.0050.27<0.005<0.010<0.050<0.025<0.10<0.003170.027<0.0002<0.20<0.0400.0078<0.010890<0.010<0.20<0.10<0.0500.0220.0100.200.0050.200.0050.0100.0500.'0250.100.0035.00.0150.00020.200.0400.0050.0105.00.0100.200.100.0500.020NN01-27-9401-27-9401-27-9401-20-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-20-9401-27-9401-07-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-27-9401-20-9401-20-9401-27-94L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14Comments: LOCKHEEDANALYTICAL SERVICES 00 GENERALCHEMISTRY RESULTSClientSamleID:TRSLALBatchID(s):1229imDateCollected: 12-28-93Matrix:roundwaterDateReceived: 12-29-93PO¹69095-040-3N Constituent MethodResultReporting Detection LimitDataQualifierls) DateAnalzedLALSamieIDFluoride, inmILChloride, inmIL340.2300.00.29190.150.01601-24-94L1009-112-29-93L1009-1Nitrite.Nitroen,inm/LSulfate,inmIL300.0300.0Nitrate-Nitro en,inmIL300.00.91<0.01220000.0170.0120.59D(1:10)12-29-93L1009-112-29-93L1009-112-29-93L1009-1Ammonia-Nitrogen, inm/LTotalCyanide,inmg/L350.1335.23.4<0.0200.0500.02001-05-94L1009-501-03-94L1009-9Comments: LOCKHEEDANALYTICALSERVICES65 GENERALCHEMISTRY RESULTSClientSamle'ID:TRS-QALALBatchID(s):1229imDateCollected: 12-28-93DateReceived: 12-29-93Matrix:roundwaterP0469095-040-3N Constituent MethodResultReporting Detection LimitDataQualifier(s) DateAnalzedLALSamleIDFluoride, inmILChloride. inmILNitrate-Nitro en,inmILNitrite.Nitroen,inmILSulfate,inmILAmmonia-Nitrogen, inmILTotalCyanide,inmg/L340.2300.0300.0300.0300.0350.1335.20.31200.90<0.01222003,4<0.0200.150.0160.0170.0120.590.0500.020D(1:10l01-24-94L1009-212-29-93L1009-212-29-93L1009-212-29-93L1009-212-29-93L1009-201-05-94L1009-601-03-94L1009-10Comments: LOCKHEEDANALYTICAL SERVICES

GENERALCHEIVIISTRY QCDATASUIVIIVIARY .LALBatchID(s):1229imQCSamleAnalses.Constituent-

Fluoride, inm/LClient'Sample'D TRSL'ALSampleIDL1009-1DateAnalyzed01-24-94ReagentBlank<0.15MatrixDuplicate:

'SpikePrecision 'eco'very (9oRPD)(%)107Chloride, inm/LNitrate-Nitrogen, inm/LTRSTRSL1009-1L1009-112-29-9312-29-93'<0.0160.2<0.0179193Nitrite-Nitro en,inm/LSulfate,inm/LAmmonia-Nitrogen, inm/LTotalCyanide,inmg/LTRSTRSTRSTRSL1009-1L1009-1L1009-5L1009-912-29-9312-29-9301-05-9401-03-94<0.012<0.059<0.050<0.0200.10969612294"b"-TheRPDcannotbecomputed, becausethesampleortheduplicate concentration wasbelowtheDetection Limit.Comments: LOCKHEEDANALYTICAL SERVICES

onNUSa~aaw~~C0RP0RATI0NLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportHo.:00018939SectionAPage1CLIENTNAME:ADDRESS:ATTENTION: INDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAN, Ml49106-0000 MS.JENILEWIS-CHEMISTRY DEPT.HUSCLIENTNO:06630020'WORKORDERNO:55830VENDORNO:05411000CarbonCopy:SAMPLEID:HUSSAMPLENO:P.O.NO.:TURBINEROOMSUMP27476P025928469034-040.3N DATESAMPLED:30-DEC-93 DATERECEIVED: 05-JAN-94 APPROVEDBY:Kieda,ChuckTESTLHCODEDETERMINATION RESULTUNIT1I7302AHA'W3I1304I5905AALWSulfate,Turbidimetric (asS04)Sodiun,Total(Na)Chloride(asCl)Solids,Dissolved at180CAtunintm, Total(Al)51mg/L6.3mg/L11mg/L140mg/L0.97mg/LCOMMENTS:

/dhHBSUft011 NUSI~~~CPRPPRATIPNLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportHo.:00018939SectionAPage2CLIENTNAME:ADDRESS:ATTENTIOH: INDIANAMICHIGANPOWERCOMPANYOHECOOKPLACE.BRIDGMAN, Ml49106-0000 MS.JENILEWIS-CHEMISTRY DEPT.NUSCLIENTNO:06630020WORKORDERNO:55830VENDORHO:05411000CarbonCopy:SAMPLEID:HUSSAMPLEHO:P.O.HO.:TURBINEROOMSUMP27476/FILTEREDP025928569034-040-3N DATESAMPLED:30.DEC-93 DATERECEIVED: 05-JAH-94 APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMIHATIOH RESULTUNITS1AALFAtuninun, Dissotved (At)COMMEHTS:0.3mg/L

.".Halliburton NUS+++C0RP0RATI0NLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage3CLIENTNAME:ADDRESS:ATTEHTION: INDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAN, MI49106-0000 MS.JENILEWIS-CHEMISTRY DEPT.NUSCLIENTNO:06630020WORKORDERHO:55830VENDORNO:05411000CarbonCopy:SAMPLEID:NUSSAMPLENO:P.O.NO.:TURBINEROOMSUMP27503P025928669034-040-3N DATESAMPLED:31.DEC-93 DATERECEIVED: 05-JAN-94 APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMIHATIOHRESULTUNITS1I7302AHAW3I1304I5905AALWCOMMEHTS: Sulfate,Turbidimetric (asS04)Sodiun,Total(Na)Chloride(asCl)Solids,Dissolved at180CAtuninun, Total(Al)53mg/L6.0mg/L10mg/L130mg/L0.98mg/L

.-:H<b~on~S++++C0RP0RATI0NLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh,Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage4CLIENTNAME:ADDRESS:ATTENTION: INDIANAMICHIGAHPOWERCOMPANYONECOOKPLACEBRIDGMAH, MI49106.0000 MS.JEHILEWIS-CHEMISTRY DEPT.NUSCLIENTNO:06630020WORKORDERNO:55830VENDORHO:05411000CarbonCopy:SAMPLEID:HUSSAMPLENO:P.O.HO.:TURBINEROOMSUMP27503/FILTEREDP025928769034-040-3H DATESAMPLED:31-DEC.93 DATERECEIVED: OS-JAN.94 APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMINATION RESULTUNITS,1AALFAtminun,Dissolved (At)0.3mg/LCOMMENTS: i'Halliburton NUSI+++C0RP0RATI0NLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage5CLIENTNAME:ADDRESS:ATTENTION: INDIANAMICHIGANPOWERCOMPANYOHECOOKPLACEBRIDGMAN, MI49106-0000 MS.JENILEWIS-CHEMISTRY DEPT.NUSCLIENTNO:06630020WORKORDERNO:55830VENDORNO:05411000CarbonCopy:SAMPLEID:NUSSAMPLENO:P.O.NO.:TURBINEROOMSUMP27506P025928869034-040-3N DATESAMPLED:01-JAN.94 DATERECEIVED: 05-JAH94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMIHATIOH RESULTUNITS1I7302AHAW311304I5905AALWSulfate,Turbidimetric (asS04)Sodiua,Total(Ha)Chloride(asCl)Solids',Dissolved at180CAtuninun, Total(Al)52mg/L5.6mg/L10mg/L130mg/L1.6mg/LCOMMENTS:

h:Halliburton NUSCORPORATION LABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(4'12)747-2684January18,1994ReportHo.:00018939SectionAPage6'LIENI'AME: ADDRESS:ATTENTION: CarbonCopy:INDIAHAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAN, MI49106-0000 MS.JEHILEWIS-CHEMISTRY DEPT.NUSCLIEHTHO:06630020WORKORDERHO:55830VEHDORNO:05411000SAMPLEID:HUSSAMPLENO:P.O.NO.:TRUBIHEROOMSUMP27506/FILTEREDP025928969034-040-3H DATESAMPLED:01-JAH-94 DATERECEIVED: 05-JAH-94 APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMINATION RESULTUNITS1AALFAlumina,Dissolved (At)COMMENTS: 0.2mg/L ALHalliburton NUSI+C0RP0RATI0NLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage7CLIENTNAME:ADDRESS:ATTENTION: INDIANAMICHIGANPOWERCOHPANYONECOOKPLACEBRIDGHAN, Hi49106-0000 HS.JENILEWIS-CHEMISTRY DEPT.NUSCLIENTNO:06630020WORKORDERNO:55830VENDORNO:05411000CarbonCopy:SAMPLEID:NUSSAHPLENO:P.O.NO.:TURBINEROOHSUHP27509P025929069034-040-3N DATESAMPLED:02-JAN-94 DATERECEIVED: 05-JAN-94 APPROVEDBY:Kieda,ChuckTESTLNCODEDETERHINATION RESULTUNITS117302ANAW311304I5905AALW6I49071700Sulfate,Turbidimetric (asSO4)Bedizen,Total(Na)Chloride(asCl)Solids,Dissolved at180CAtuninun, Total(Al)pNSpecificConductance at25C51mg/L5.9mg/L10mg/L140mg/L1.5,mg/L7.6300umhos/cmCOHHENTS: ongJSI+C0RP0RATI0NLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage8CLIENTNAME:ADDRESS:ATTENTION: INDIANAHICNIGANPOWERCOHPANYONECOOKPLACEBRIDGHAN, Hl49106-0000 MS.JENILEWIS-CHEHISTRY DEPT.NUSCLIENTNO:06630020WORKORDERNO:55830VENDORNO:05411000CarbonCopy:SAHPLEID:TURBINEROOHSUHP27509/FILTEREDNUSSAHPLENO:P0259291P.O.NO.:69034-040-3N DATESAMPLED:02-JAN-94 DATERECEIVED: 05-JAN-94 APPROVEDBY:Kieda,ChuckTESTLNCODEDETERHINATION RESULTUNITS1AALF.Atuninun, Dissotved (At)COHMENTS: 0.3mg/L /4L:Halliburton NUS+C0RP0RATI0NLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage9CLIEHTNAME:INDIANAMICHIGANPOWERCOMPANYADDRESS:ONECOOKPLACEBRIDGMAN, MI49106-0000 ATTENTIOH: MS.JENILEWIS-CHEMISTRY DEPT.NUSCLIENTHO:06630020WORKORDERNO:55830VENDORNO:05411000CarbonCopy:SAMPLEID:ABSPONDCOMP.HUSSAMPLENO:P0259292P.O.NO.:69034-040-3H DATESAMPLED:31-0EC.93 DATERECEIVED: 05-JAH94APPROVEDBY:Kieda,ChuckTEST.LNCODEDETERMIHAT IONRESULTUNITS117302ANAW31130415905AALWSulfate,Turbidimetric (asS04)Sodiun,Total(Ha)Chloride(asCl)Solids,Dissolved at180CAtuninm,Total(Al)1102892100.33mg/Lmg/Lmg/Lmg/Lmg/LCOMMENTS: onNU$I++C0RP0RATI0NLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January1B,1994ReportNo.:0001B939SectionAPage10CLIENTNAME:ADDRESS:ATTENTION: CarbonCopy:INDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAN, Ml49106-0000 MS.JENILEWIS-CHEMISTRY DEPT.NUSCLIENTNo:06630020WORKORDERHO:55030VENDORNO:05411000SAMPLEID:ABSPONDCOMP./FILTEREDHUSSAMPLENO:P0259293P.O.NO.:69034-040-3N DATESAMPLED:31-DEC.93 DATERECEIVED: 05-JAH.94 APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMINATION RESULTUNITS1AALFCOMMENTS:

Atuninun, Dissotved iAI)0.099mg/L

4'.Halliburton NUS%%ENC0RP0RATI0NLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh,Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportHo.:00018939SectionAPage11CLIENTNAME:ADDRESS:ATTENTION:

INDIANAMICHIGANPOWERCOMPANYOHECOOKPLACEBRIDGMAN, Mi49106-0000 MS.JENILEWIS-CHEMISTRY DEPT.HUSCLIENTHO:06630020WORKORDERNO:55830VENDORHO:05411000CarbonCopy:SAMPLEID:HUSSAMPLEHO:P.O.HO.:ABSPOHDCOMP.P025929469034-040-3N DATESAMPLED:01-JAN94DATERECEIVED: 05-JAH-94 APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMIHATIOH RESULTUNITS117302AHAW3I1304I5905AALWSulfate,Turbidimetric (asS04)Sodiun,Total(Na)Chloride(asCl)Solids,Dissolved at180CAluminize, Total(Al)110mg/L30mg/L10mg/L210mg/L0.35mg/LCOMMENTS: i:Halliburton NUSI+++C0RP0RATI0NLABORATORY ANALYSISREPORTNUSLASORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage12CLIENTNAME:ADDRESS:ATTENTION: CarbonCopy:INDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAN, Ml49106-0000 MS.JEHILEWIS-CHEMISTRY DEPT.HUSCLIENTNO:06630020WORKORDERHO:55830VEHDORNO:05411000SAMPLEID:ABSPONDCOMP./FILTEREDHUSSAMPLEHO:P0259295P.O.HO.:69034-040-3N DATESAMPLED:01-JAN-94 DATERECEIVED: 05-JAN-94 APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMINATIONRESULT.UNITS1AALFAtuninua, Dissolved (At)0.10mg/LCOMMENTS:

L:Halliburton NUSI+++C0RP0RATI0NLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage13CLIENTNAME:ADDRESS:ATTENTION: INDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAH, MI49106-0000 MS.JEHILEWIS-CHEMISTRY DEPT.NUSCLIENTNO:06630020WORKORDERHO:55830VENDORNO:05411000CarbonCopy:SAMPLEID:NUSSAMPLEHO:P.O.NO.:ABSPONDCOMP.P025929669034-040-3N DATESAMPLED:02-JAN-94 DATERECEIVED: 05-JAN-94 APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMINATION RESULTUNITS1I7302ANAW31130415905AALW61700Sulfate,Turbidimetric (asS04)Sodiun,Total(Ha)Chloride(asCl)Solids,Dissolved at180CAlumina,Total(Al)SpecificConductance at25C10031101900.5400mg/Lmg/Lmg/Lmg/Lmg/Lumhos/cmCOMMENTS: .".Halliburton NUSI~~iC0RP0RATI0NLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage14CLIENTkAME:ADDRESS:ATTENTION: IHDIAHAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAN, Mi49106-0000 MS.JENILEWIS-CHEMISTRY DEPT.NUSCLIENTNO:06630020WORKORDERNO:55830VENDORNO:05411000CarbonCopy:SAMPLEID:ABSPOHDCOMP./FILTEREDNUSSAMPLENO:P0259297P.O.HO.:69034-040-3H DATESAMPLED:02-JAN.94 DATERECEIVED: 05-JAH-94 APPROVEDBY:Kieda,ChuckTESTLHCODEDETERMINATION RESULTUNITS1AALFAtuainun, Dissolved (At)0.072mg/LCOMMENTS: /4L'Halliburton NUS+++C0RP0RATI0NLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage15CLIENTHAME:ADDRESS:ATTENTIOH: INDIANAMICHIGANPOWERCOMPANYOHECOOKPLACEBRIDGMAN, MI49106-0000 MS.JEHILEWIS-CHEMISTRY DEPT.NUSCLIENTHO:06630020WORKORDERHO:55830VENDORHO:05411000CarbonCopy:SAMPLEID:ABSPONDCOMP66998NUSSAMPLENO:P0259298P.O.NO.:69034-040-3N DATESAMPLED:03JAN-94DATERECEIVED: 05-JAN-94 APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMINATION RESULTUNITS117302ANAW311304I5905AALW8I700COMMENTS: Sulfate,Turbidimetric (asSO4)Sodiun,Total(Na)Chloride(asCl)Solids,Dissolved at180CAtuninua, Total(Al)SpecificConductance at25CI11028101900.5410mg/Lmg/Lmg/Lmg/Lmg/Lumhos/cm .".Hallibu1tonNUSCORPORATION LABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage16CLIENTNAME:ADDRESS:ATTENTIOH: IHDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAH, MI49106-0000 MS.JENILEWIS-CHEMISTRY DEPT.NUSCLIENTNO:06630020'WORKORDERNO:55830VENDORNO:05411000CarbonCopy:SAMPLEID:NUSSAMPLENO:P.O.HO.:ABSPONDCOMP66998/FILTEREDP025929969034-040-3N DATESAMPLED:03-JAN-94 DATERECEIVED: 05-JAN-94 APPROVEDBY:Kieda,ChuckTESTLHCODEDETERMINATION RESULTUNITS1AALFAtuainua, Dissolved (Al)0.088mg/LCOMMENTS: SEEINSTRUCTIONS ONREVERSESIDESECTIONIINUMBERPERMIT~NIppp5827~OOEAsLOCATIONOFDISCHARGE ~~~t~EE~v,ernssi~00.EeDISCHARGE LOCATIONBN%RECEIVLNL HATER(IEsGROINLNATER CRNA%OFQRFACEMAC>>OO@XIDISCHARGE SEASCNALLY LLFMsCONTIIAKIOE)DsIFYESeLISI'ISCNRGE PERIODSIQs/DAYHL,/DAYSANITARYABSPONDFLOWRATEWASTEWATER JZKSQQF1CONTACTCOOUNG2NONCONTACT COOLNG3PROCESS4SANITARY5STORMWATER QQE1MGYMGD3GPDITEM2WATERTREATMENT ADDITIVES. LINLLSCODE1Mg/I2Ug/IEsLANDAPPLICATION RALEFsTYPEOFHASLEHALER DISCNRGEG~DISCNRGESOELXAE(YEARLYAVERAGE)oISCHARGEFUNŽENAINsHIeIRsDAYINs/NKsLLJ~LJLLJ~LJLLJ~LJQNU4L3JLJLJLJL-IHOURS/DAY ~4lOTALYEARLYDAILYHINIISHDAILYHAXIISNsvvlvsss*13.505~1 0372JeNXIILHDESIGNDISCNRGEFUNRATEsAs9)YOUUSE'KATER1REAL%NLACOITIVES TOlREATYIRDISOHKO(LFN).COILS@YOLTLH3)SeN%FINCTICNs AEIOEHICALCQSKSITICN OFTHESEALSIITIVESe DESIGN0.060pxC186KCalciumHochlorite forF'aeC>>N%AIEIAZCRESSOFH4MFACLLRERS OFLIAISEAIDITIVESe VANWATERSANDROGERS,INC.L600NORTONBUILDINGSEATTLE,WASHINGTON 98104-156 LslIENXDSNDISCNRGKFUNRATETOSEAIIIHCRLZED INPERIITe~LZpgpp6pINI)LODEDsEXPKTEDDISCNRSECQCEHIRATI(N OFALOLTIVESe HINIISHINILSAVERAGECLLKINITSNXIISNevevvvvsssevvTotalResidualChlorine0~,0ALOITIVENA%LJs~ALIITIVENA%EsDO%XITREATl%DLSCNRGElOROTEALOlT1VES? FsISN'TISlHKRBOVALEFFLCL8CY ANDDISCNRGEFRKLLKLCY7 ACOITIVENA%ALEITIVENA%ALOITIVENA%IRSs/OAYDAYS/'HK. LJLLJLJLJG,ASANATTACHMENT lOlHISAPPLLCATICN PROVIDESPKIFICHASQLIANCRACUATIClOXICOUSLCAL DATACRREFERENCE HHIOIAREAVAIIASLE NDINRRQTLCN CNlHERATEOFDKRAMTICN OFlIEPRXXCTSFCREACHALOITLVEi IYISDSAttachedCalciumHypochlorite isaddedtothemixedliquorandisuseduppriortodischarge. 31 INSTRUCTIONS FORCOMPLETING SECTIONIIITEMSIANO2ThisformrequiresIntormatlon onthefeelIity'sdischarge

location, discharge

schedule, volumeflovrateandwatertreatment additives.

ENTERTHEPERMITNUMBFRINTHEBOXATTHETOPOFTHISFOFM.THEPERMITNUMBERCANBEFCUNOONTHEFRONTPAGEOFYOUREXPIRINGPERMIT.IfthisIsanevornotpreviously permitted

facility, thenleaveblankandanumberwllIbeassigned.

EntertheouttaIInumberInspaceprovidedforeachpageo!SectionII.ForeachIndividual discharoe pointaseparatesetofSectionIIformsmustbefilledout.ITEMIDISCHARGE LOCATIONSCHEDULEAIOFLOWRATESA.Enterthelocationofdischarge, thisshouldIncludequarter-quarter section,quartersection,section.(own,andrange.B.ListnameofreceIving water(ifsurfacewaterdischarge). C.IndlCatewhethertaCilltydlSChargeS OnaSeaSOnalbaSIS.O.Ifyes,listdischarge periods.E.Providethelandapplication ratesusedorexpectedtobeusedIntermsofInchesperhour,houtsperday,andInchesperv<<k~F~Indicatethetypeofwastewater tobedischarged fromthisoutfall.Refertothewastewater typecodegivenIntheleftmargin.Morethanonecodemaybeappllcable.G~ProvidetheaveragenuxberofhoursperdayInwhichthefacilitydlschargeS treatedwastewater andthetotalnmxberofdaysperyearInwhichthedischarge occurs.H.Providecurrent(fromtheInstl2months)orexpectedflowratesasrequested. RefertounitcodeqlvenIntheleftmargin~fortheappropriate flowunits.MGY-milliongallonsperyear;MGO-milliongallonsperday)GPO-gallonsperday.I.Providethemaximumdischarge flowratewhichyouventtohaveauthorised withinthepermit.NOTE:ForNPOESpermitsonly.theuseofsuchaflowratewillnotplaceanactuallimitrestriction onthetlovbutwillbetheflowrateusedtodevelopetf(ventlimits.Also,whentheMonthlyOperating ReportsarereviewedbyCompliance staffItvillhelpthamtodetermine Itanynevorincreased usesmighthaveoccurredatthefacility. J.Providethedesignflowforthisspecificoutfalldischarge (e.g.batchtreatment systemflow,packagedtreatment systemflow.orscmeotherfinitetreatment systemflow).ITEM2WATERTREATMENT ADOITIYESA.Indicatewhetherdischarge Istreatedwithconditioners, Inhibitors, ormlcrobloclde. Ifnot,continuetoItem3.B.Givename,function, andchemicalccmposltlon ofadditives used.C.Givenameandaddressofthemanutacturer(s) ottheadditives used.o.Indicateexpectedmlnlxxxn, averageandmaxlaxxxdischarge concentrations oftheadditive(s) torthisdischarge. E.IndiCatevhetheryOutreatthed(SCharge tOremOVetheaddltlVe(S) betOrediSCharge OfWaSteVater. F.Indicatetheremovalettlclency ofeachadditivet(xxxthevastevater andthedischarge frequency ofeachadditivetothesurtacewaterorgroundwater. G.NOTE:ItIstheresponSlblllty oftheapplicant tosupplytheproductInformation asrequested InthisItem4.Information requested butnotsuppliedmayresultIntheapplication beingreturnedtotheapplicant forcompletion. 32 VANWAXEfisbROGERSXNC.NhrERXAI,".,AFE'l YnhrA:-"HEEr REF'('.)BTNLJI"IBER:971NSD!)H(3:PG0310IECIIVF.DATE:06/21/93PRODl)CrlCAI(.,XUNHYPOCHL(3RITE GRANI)I,.AIR f'A(3E.',001Vf:.RSIQH: 004(3RDERHQiPRQI3HOVAHWATFRS6ROGERSINC.,SLJBSXD3:ARY (3FUNXVAR6100CARXLIONP(3XNTKXRKLAHD(20/>)889-3400,WA98033ENERGENCY AS,.X.TAHCEF(3RENERGENCY ASSXSTAHCE INVOI.VXNGCHFiIXCALS CALI.-CHENTREC<800)424-9300 FORPRODUCTANDSAII=SXNFORNATION CONTACTYOURLOCAI.VANWATERSh,ROGERSBRANCHOFFICEATVWbRSOUTH.BEHD219-289-0321 SOUTHBEND,XNPRODLJCTNANE:CAL(::XUN HYPOCMIORITEGRAHLJLAR NSDSe:FGO31OCALCIUNHYPQCHLORXTE GRAHLJLAR DATI=:.'.'~7"05)',:L6'I',93'i "',.'-,-'i."i TRADENANEi,"..'.CAI..CXUH,'.HYPQCHLOR ITE6RANlJLAR(".HENHAilE/SYH~,".GAL;QYPP,'

PXTTCLOR, IN13(JCL(3R, REPAK,ZAPPITCHENXCALFANXLY~i-'

.:-"-'YfOCHLORXTE FQRN(JLA: CA(OCL)2CASHUNBER:007778-54-3 (J.S,DOTSHIPPINGNANEiCALCIUNHYPQCHLORXTE, HYDRATEDU,S.DQTHAZARDCLASS:5.1(QXXDXZER) SUBSIDXARY RISKH/AX.DENUNBFR:LJN2880~~~~KXHGGROlJP:XX.ORT*BLEQUANTITY: loLBS/4.5l<GXNQDESCRXPTXON: GALCXUNHYPOCHLORXTF, I-IYDRATED, CLASS5.1,UN2880,PACl<XHGGRQlJPXX,RQ,INDGCODEPAGE5138,

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EnteroutfallnumberInspaceprovidedforeachpageofSectionII.ForeachIndividual dlscharce ointaseparatesetcfSectionIIformsmustbefilledout.PROCESSSTREAMSCONTRIIRITING TODISCHARGE: FOREACHSEPARATEPROCESSPROVIDETHEFOLLOflf6 INFORMATION A.Enterthenameoftheprocess<<hlchcontributes tothisdischarge. AlsoprovidetheproperSICcode.B.IndicatetheyearlyaverageprocessscheduleInhoursperdayanddays-per-year. CProvidetheprocesswastewater firnrateInformation asrequested basedonyourlastl2monthsofoperations'efer tounitcodagivenintheleftmarginfortheappropriate flowunits.D.ProcessProductIon Rate-Certainpermitlimitations maybebasedonproduction rates.Theproduction ratesusedtodetermine permitlimitsshallberepresented byareasonable measureofactualproduction ofthefacility, suchastheproduction duringthehighmonthofthepreviousyear,orthemonthlyaveraqeforthehighestofthepreviousfiveyears,orOtherreasonable measureasstatedinapplicable U.S.E.P.A. categorical rulesandregulations. Fornewsourcesornewdlschargers, actualproduction shallbeestimated usingproJected production. Recordyourproduction ratesInthetermsandunitsusedIntheapplicable U.S.E.P.A. categorical rulesandregulations foryourtypeoffacility. 34 SEEINSTRUCTIONS ONREVERSESIDESECTIONIINUMBER~EM4GROUNDWATER DISCHARGE INFORMATION AeISTHEDISCHARGE FROMTHISOUTFALLDIRECIKDTOlHEGRa5DORGROQCWATERS? (IF%ACOttTINKTOITEM0)BeHASAHYDROGEOLOG ICALSTUDYORITSEQUIVALENT BEENPERFORMED ORISTHEREBIFFICIBITCURRENTHYDROGEQLQGICAL INFORMATION AVAllABLE ASREQUIREDBYTIEHATERRESIMICES atttlsstON PARTZ2GRONIDtATKR RIAESOFAuiUSTltlo19%RI525.2207 (PAGEILI)FORTHISEXISTI%ORPROPOSEDDISCHSRGET IFYESATTACHACCPYCFTHEREPORTSCeAREYOUREIXEST1% ANEXB1PTION FRCMSIBIITTI% AHYIIIQGEQUXIICAL REPORT%DERRLAERe323AZR7 (19}(PAGEQ)ORFROMGRIXNDtATKB tCEIIIORI% IIEOU)RBIENIS WDERRULERe525IZdS (5)(PAGE+OF1%PART22RLLES~IFYESATTACHDQat6ENTS ANDEXPIANATICN TODBXINSTRATK THATVIX'ISCHARGE MXADQUALIFYFORANEXBflONeDeAREYOURBXKSTI%AVARIANCEFIOIRULE323e2205(PAGEP(tOteEGRADATION) OFTHEHATERREstxwcEs cctt11ssIQN PART22GRQNIDIATER RILEs?IFYKS,ATTAOHSUOHDOQHBITSASNECESSAlà TODEMONSTRATE TIENEEDFCRAVARIANCEINTERMSOFTIECRITERIASPECIFIED INRIAE525e2210(PAGECF1HEPART2ZRRESAEeI,ISTAlp.CHEIIICAL SIBSTANCES HHICHAREINMICHIGANSCRITICALMATERIALS REGISTERTABLEIVLPAGED)AND/ORUeseEPA'SPRIORITYPOILUTANT LISTTABLEV(PAGE7)ORANYmtERSIBSTANCES ttIICHARECRHAYBECOMEIMHIOUSTOTIEEESIGNATKD USESOF1%GRXMlATKR ORTOTHEPUBLIC%ALTHlHATAREDISCHUIGED OREXPECTEDTOBEDISCHARGED TOTIERQXLIKX6ATKRAY 1HISFACILllYe ESTIMATETHEFINALEFFLUENTCONCENIRATIIXI NDRECORDALLDATAINITBI7OFSECTICNIIIN1HISBOOILETeTIEAPPLICANT HAYBERECUIREDlDDOAIXIITIONAL HASTEANALYSESA ~OOEEgYESX.S,Submitted 12/6/91YESXa-NOTAPPLICABtx/BELIEVED ABSENTPRESENTSDATAPROVIDEDINITBI7ElITENI5EXPECTEDWASlEWATER CHARAC-UNETSCODE1MQ/I2UQ/I3COUNTS/100ml4S.U.5F6LBS/DAYAeDISCHARGE CHARACTERISTICS 'TOC(TOTALORGANICCARBON)AtfCNIANITROGEN(ASN)TOTALSUSPB4KDSOLIDSTOTALPtDSPHOftUS (AsP)TOTALRESIIXIAL OUNINEDISSOLVED OXYGENMIN~6~4FECALCOLIFORtl BACTKRIA'TBmmltttE (sums)79%%RATINE (HINIKR)BQOI3(FIVEDAYBIOCteIICAL OXYGENDEHAIB)COD(CtetlCAL OXYGBIDEMAND)CCNCENIIIATI ONAVEHAX~40.~05~99.~6~~~QJ~ELlZ~~~5.~55'116,~0~73,~036~12.~05LLJ~LJ~~LJBeOTHERHASTKHATER CHUIACIKR ISTICSWITSCODE0ANALYSESSAtPLKTYPECOCEu1~l2~60~1~113~3u3~RAMPEZXBE1GRAB224KOURCOMPOSITE 0ILSGREASEn'c1cc.~65,~56~208,~0LJ~l~65RBXIIREDIIFOWATICN FIERYSINFACEHATERDISCHARGESe INSTRUCTIONS FORCOMPLETING SECTIONIIITEMS4ANO5ThistomrequiresInformation onsspecificoutfalldischarging toeitherthegroundwsters orthesurfacewaters.ENTERTHcPER4IIThlPIBERINTHEBOXATTHETDPOFTHISFORM.THEPERMITNl+IBERCANBEFOUNDONTHEFRONTPAGEOFYOUREXPIRINGPERMIT.IfthlSISSnewOrnOtpreVIOuSly permitted faCIllty,thenlenVeblankOndOnumber<<IIIbeSSSlgned. EntertheoutfallnumberInthespaceprovidedforeachDogeofSectionII.ForeachIndividual disehsroe pointasearetesetofSectionIIforms(Items4and5)mustbefilledout.ITEM4GRCUNDWATER DISCHARGE INFORMATION (00NOTINCLUDEDEEPWELLINJECTION INFORMATION INTHISITEM)A.-D.Theapplicant shalladdresseachofthesepartsIfthedischarge trcmthisoutfallIstotheqroundwoter. ITEM5EXISTINGOREXPECTED(FORANEWDISCHARGE) WASTEWATEP CHARACTERISTICS OFGROUNDWATER ORSURFACEWATERDISCHARGE (DONOTINCLUDE<<LLINJININNHA.Theapplicant shelIreportnvnilabledischarge data(realdataforexistingdischarge orexpecteddotsfornproposeddischarge) fortheDarnmeters aslisted.Theseparameters shallbeaddressed foreitherasurfaceraterdischarge orssaDDroDrlate forsgroundwater discharge. Forassistance Indetermining appropriate parameters aground~ster discharoe applicant msycontacttheGroundwater DualityDivision, permitsSectionortheapproprlateGroundwater punlityDivision's Districtoftlce.Theapplicant shalli'eportthesampletypecodebestdescribing eachreportedpieceofdots.seecodingontheleftmarginofthistofmIfthisoutfallIsnsurfacewaterdlschsrqe, theapplicant mustreportquantitative dotsforeachparameter Identified bonPPIty,",Ietd9dhelldptPo.Pheoettbe~ppdtedbydeopttiedI.dhodheelleptpttpht0thlpelltlB.IfdataIsavailable torotherparameters notlistedaboveInA.orotherpartsofthisapplication theapplicant shouldreDortthatdataIntheblankspacesprovidedInthispart.<OTEStI.Unitcodesforparameters reportedInportsAsnd8cnnbefoundontheletthandsideofthistore.2~GrabSnmoleShelIbeuSedtOSnolyZefarPH,temperature, tOtslPhenOIS,reSldualChlOrlne, Oilnndgrea5e~andfecalcoliformInnsvrtaeewaterdischarge unlessotherfrequency-snmD(e typeanalysesareavailable. SeeGlossary(pnge48)fordefinition otgrabSample.24-hourcomposite samplesshallbeusedtoanalyzeforTotal8005,COO,TDC,AmnonlnNitrogen, andTotalSusDended Solidsinosurface~sterdischarge unlessotherfrequency-sample typeanalysessreavailable. SeeGlossary(page48)tordefinition otcomDOSlte sample.4.REPORTING OFINTAKEDATA.Youarenotrequiredtoreportunlessyov<<Ishtodemonstrate youreligibility foro"net<<effluentlimitation foroneormorepollutants, thatIs,nneffluentlimitation odJustedbysubtracting theoveragelevelotthepollutant(s) presentInyourIntake~ster.NPOESregulations nl(ownetlimitations onlyIncertaincircumstances. Todemonstrate youreliglblllty,reporttheoverageoftheresultsotanalysesonyourintakewater(ifyour<<sterIstreatedbeforeuse,testthe~sterofterItIstreated), sndattachsseparateSheetcontninlng thefollowing toreachpollutant: (a)Astatement thattheIntake<<sterIsdrowntromthebodyot<<sterIntowhichthedischarge Ismode.(Otherwise, youorenoteligiblefornetlimitations.) (b)Astatement ottheextenttowhichthelevelofthepollutant Isreducedbytreatment ofyourwastewater .(Yovilimitations <<illbesdJustedonlytotheextentthatthepollutant Isnotremoved.) (c)Whenapplicable (forex(mpple, whenthepollutant represents acla55otcompounds), ndemonstration oftheextenttowhichthepollutants IntheIntakeveryphysically, chemically, orbiologically franthepollutants contained Inyoui'ischarge. (Yourlimitations <<illbeadjustedonlytotheextentthattheIntakepollutants donotvaryfrobbthedischarged Do)lvtants.) 5.Ifyouhavetwooi'oresubstantially Indentlcal

outfslls, youmsyrequestpermission tronyourpermitting OuthOrltv tosamplenndanalyzeonlyoneouttsllnndSubmittheresultsoftheanalysistorotherSubstantially Identical outfalls.

IfyourrequestIsgrantedbythepermlttlno authority, onsseparatesheetattachedtotheSDPIICstlOn fOrmIdentityWhlChOuttallydudidteSt,SnddeSerlbe<<hytheOutta(ISwh(ChyOudidnOtteStnresubstantially Identical totheovtfollwhichyoudidtest.'36 SEEINSTRUCTIONS ONREVERSESIDESECTIONIIPERMIT~IYIZ0005827NUMBEROOEeNI6PRIORITYPOLLUTANTS aNDADDITIONAL INFORMATION FORSURFACEWATERDISCHARGE ONLYTHEFOUXHI%REQUESTED INFOIVIATION ~ADCRESSED BYJILLQJIFACEHATERDISCHARGERSI IIGIEtNKHUSEDlSCHARGERS SUB'ROVIDE EXPECTEDVALIKSFORTHEQUANTITATIVE ANDQUALITATIVE INFORtllT IONREQUESTED BELOhloAIISTHISFACILllYAPRIMLYINIXSTR(. (REFERTOTABIEIAPPl<(IFtKJGOTOE)(IFYSGOTOB)BIINDICATETYPEOFPRIMARYINDUSTRYASLISTEDINTABIEIAPAGEQ(CONTI~HITHC~)CIICES1HISOUTFALLDISCHARGE CCttfAINANYPROCESSHASTEHATKR7 (IFNOrGOTOE)(IFYES.GOTOD)DetNDICATKltttCHGC/MSFRACflONS tKJSTBETESTEDFORe(REFERTOTABLEIAPJJ>EKQEIFOREACHQJMSFRACTIONCHECKEDrEAtHSPECIFICORGANICTOXtCPOUJJTAMT HITHINEAQIFRACTION55'KANALYZEDFOR(SEETABLEIIAPAGEQ,INADDITIONALLPRINARYIMXJSTRYAPPLIuWTS HITHAPROCESSHASTKHATER DISQURGE~PROVIDEQUWTITATIVE CATAFOREACHTOXICPOLUJfANT INTABLElllAPN499IRECORDALLDATAONFORMSPROVIDED(ITEM7)INTHISBOOKLETI(CQMTINEHITHEKBEUAt)QYESNOSTMEL'EPWR YES~XMODAnalysisperJ.B.Beauboeuf DBASK/NKUIRAL Groundwater DivisionACIDPESTICIDE EoIF~QJIFACEHATERDISQIARGE APPLICANT (PRINRYORSECNIDUIY IMIXJSTRY)r REGARDLESS OFTHETYPEOFDISCHARGEr KXHSORHASREASONTOBELIEVETlQTANYPOLLUTANT LISTEDINTABLEIIAANDIVAPAGKS~IsDISCHARGED FRQIAMYIXJIFAILr TIEQOWTITATIVE DATA~BEPROVIDED'EcoRD ALLDATA0NF0RMsPRQYIDED(ITKJI7)INTHIsBQQKLEf.F.IFAMYQRFACElATERDISCHARGE APPLICANT (PRIMLYORSECONDARY IMXJSTRY)r REGARDLESS OFTYPEOFDISQJUIGEr KIKXtsORHASREASONTOBELIEVEANYPOUJJTANIS LISTKDINTABLEVAPAGE+AREDISCHARCM FROMAMYIXJIFALLTIEAPPLICANT ~DESCRIBEREASONSFORTIEPOUJJTANf BEI%PRESENTANJPROVIDEANYAVAILABLE QUANTITATIVE DATAIRECORDNLKATAOMFOtttsPROVIDED(ITEM7)INTHISBOOKLET>NOTAPPI.ICABLE/BELIEVED ABSENf0N/AOPRESENT/DATA ISAlTACHEDQ%TAPPLICABLE/BELIEVED ABSENTN/AQPRESENT/CATA ISATTACHEDGIAILSIRFACEHATERDISC@AGEAPPLICANTS (PRIMARYAMDSECONDARY INDUSTRIES) %TAPPLICABLE/BEUEVKD AssatfQrVTRIQLOIIOPJE%L eTC~PlORHEXACtLONPIEJE ttCRPJ(AlLDATAFCRTIEABOVEtKJSTBEGENERATED US1%STANDARDAMAt.YTICAL CALISRATIIXI PROCEDIRES) CRKtKBtsORHASREASONTOBELIEVETHATTIXOISCRMAYBEPRESENTINTlEIRDISCNRGEr ~REPORTtBIALITATIVE SLTArGEJERATKD ltgIQIUSEDASCREEN!%PROCEDNE%TCALIBRATED Hl'tHANALYTICAL STANDAtmr FOR45r18rTKIIIAQLDRODIBENZO PDIOXIN(TCIXJ)~RECORDAILDATAONFORMSPROVIDED(ITBIf)INTHISBOOKLETrQPRESENT/DATA ISATTAQEDN/AJrIFTIESUIFACEHAlKRDISOIAAKAPPLICANT KJKXtsORWLSREASON10BELIEVETHATBIQUJGI~loxtcllYTKsfsHEREMADEINTHEIasfTtttEE(5)YEARsQNANY0FTlEAPPLtuWTSDISCHARGES ORONARECEIVI%HATERINRELATIOtt lDADISCHARGEr PROVIDETHISItAAQTION ASANATTAQtENT TOlHISAPPLICATIONI KIIFACtWIIRACT LABXIATORY ORCONQLTI%FIRMPERFORPKD ANYOFTltAtaaYSESREQUIREDBYTHISAPPLICATIOttr PROVIDETIENAMEANDADDRESSOFEAQItasORATCRY ORFIRMANJTHEANALYSESPERFQttED ASAMATTAQtKNT OFTHISAPPLICATIONa LIDOYCUDISCMUIGK ANYOTHERTOXiCORINJLJIIOUS (JKMICALSUBSTANCES %TLISTEDINTABLESIVPAGEttAtOIIATHOU%VAPJVM~~,IFYESTIKJIIDENTIEYTIECHBttCALQ8STAJKXS AMOESTIMATETIEFINALEFFUXMTCCNCEJttttaTICNsr SUttITTHISltFOtttATION ASANATTAQtEMT TOTHISAPPLICATIONs Q%TAPPLICABLE '/AQAPPLICABLE/SEE ATTAQIEDQMOTAPPLICABLE XAPPLicastE/SEK ATTAQIEDQ%TappLicasLE N/AQAPPLtues/SKK ATTAQIKD37 INSTRUCTIONS FORCCMPLETINGSECTIONIIITEM6ThisformrequiresInformation onaspecificouttnlIdischarging tothesurfacewaters.ENTERTHEPERMITNUMBERINTHEBOXATTHETCPOFTHISFORM.THEPERHITIRNBERCANBEFOUNDONTHEFRONTPAGEOFYOUREXPIRINGPERMIT.IfthlSiSOnewOrnOtpreVIOuSly permitted fOCIlity,thenlenVeblankandnnumberWllIbenSSlgned. EntertheoutfallnumberInthespaceprovidedforeachpageofSectionII.ForeachIndividual dlschorqe ointnseparatesetotSectionII,Item6formsmustbefIliedout.PRIORITYPOLLUTANTS ANOAGOITIONAL INFORMATION ITEH6NOTE:NOTE:Ifyouhavetwoormoresubstantially Indentlcal

outtnlls, youmayrequestpermission frcmyourpermitting authority tos<<cp(enndanalyzeonlyoneoutfnlIandsubmittheresultsottheanalysisforothersubstantially Identical outfolls.ItyourrequestIsgrantedbythepermitting authcrlty, onaseparatesheetattachedtotheappllcntlon formIdentifywhichoutfalIyoudidtest,anddescribewhytheoutfallawhichyoudidnottestoresubstantially Identical,to theoutfallwhichyoudidtest.40CFRPart122.21(g)(8),

Friday,AprlII,1983,providesforaSmalIBusinessExemption fromthereporting ofquantitative datatororganictoxicpollutants andtoxicpollutants asrequiredbyPort122.21(g)(7)(ll)(A) or122.21(g)(T)(ill)(A). A~-C.Theseportsareselfwxplanotory onddonotrequirefurtherInstructions. SimplygothrougheachpartanddonsIndicated. andE.-J.0.SeveralIndustrial cotegorlesandsubcategories hovebeenexemptedfransubmlttlngdotsoncertainGC/MSFractions (40CFRPort122,Vol.48,No.64,Friday,AptIII,1983,NotesI.2.and3).'eviewthefollowing listtodetermine whetheryourfacilityqualities tobeexemptfromreporting GC/MS(GasChrcmatography/ MossSpectroscopy) Fractions. GC/MSFrnctionTestingnndReporting Exemptions TextileMillsInduct-AllfourGC/MSorganictractlons IntheGreigeMIIIsSubcategory. -Pesticide tractionInoilothersubportsofthisIndustry. OreMininondBrasslIndust-Volatile, base/neutral, andpesticide fractions IntheBoseandPreciousMetalsSubcategory. -AllfourGC/MSorganIcfractions InallotherSubcategories ofthisIndustry. CueandMoodChemicals Industr-Pesticide fractionIntheTallOilRosinSubcategory andtheRosinBasedOerlvatlves Subcategory. -Pesticide andbase/neutral fractions Inallothersubcategories ofthisIndustry. PulandPaperInductPesticide fractionInPapergrade Sulfitesubcatcqories (subparts JandU).-Base/neutral andpesticide fractions inOelnkSubpartQ,Blssolvinq KraftSubpartF,andPaperboard fromMastsPaperSubpartE.lt-Volatile, base/neutral, pesticide fract(ons IntheSCTSleschcdKraftSubpartH,Saci-chemical Subparts8andC,andNonintegrated"Fine PapersSubpartR.-Acid,base/neutral, sndpesticide fractions inFineBleachedKraftSubpartI,Olssolvlng SulfitePulpSubpartK,Ground-woodFinePapersSubpart0,HarketBleachedKraftSubpart0,TissuefromMastepaper SubpartT,andNonlntegratcd TissuePapersSubpartS.SteamElectricPowerPlantIndust1-Base/neutral fractionIntheOnce-Through CoolingMater,FlyAsh,andBottomAshTransport Materprocesswsstestreams. 38 SEEINSTRUCTIONS ONREVERSESIDESECTIONIIMj.pop5827EM7CRITICALMATERIALS TOXICPOLLUTANTS ~OOEAeUSETHISDATASHEETTORECORDINFGLtLATIOM ASRECUIREDIN:(CHECKAPPROPRIATE BOXFINWICHIMFLJLMATICN THISDATASHEETREPRESEMTS ~)OXlsSECTIONIIEITEMMeGROMlLATER DISCHJJLGE INFCttULTION (PAGE35)2eSECTICNIIEITEM6ePRIORITYRXJlJTAMTS INSLRFACEHATERDISCHLWiE (PAGE3TlDX3eBsBELJJELLCRITICALMATERIALS (TABLElv)INSLJLFACEHATERDIMJLARGE (PAGE39)HAZARDOUS SUBSTANCES INDISCHARGE BeLISTANYCRITICALMATERIAL(TABLEIVPAGE6)NOTADCRESSED IMSECTICNIIITEH6PRIORllYPOLLJJTAMTS HHICHYOUtlat%ORHAVEREASONloBELIEVETOBEPRESENfINTIEDISCHLRGEI SEEREVERSESIDEOFTHISPAGEFORFLJLTIERDIRECTICNSE tOTAPPLICABLE APPLICABLE (SEEBELCN)UNITSCODE1MQ/ILUg/ILBS/DAYKG/DAY~AMPL~TYPg 1GRAB224HR.COMP.CEILLEILLJLetILELitteeIAeNLHEOFCRITICALMATERIALCRPRIORITYJOLLJJTANT BeAVERAGECNCEMIRATICNJ SAMPLETYPEJIIOFANALYSESCeMAXIt4NCCttCEtmLATICN AIOMASSAeNtt%OFCRITICALMATERIALCRPRIORllYPOLLUTANT BeAVERAGECCJJCEMIRATICNJ Qt%%ElYPEJJIOFANALYSESCeMAXIJLPICCNCENllVLTION AtOMASSAeH4%OFCRITICALHATERIALCRPRICRllYPOLLIJTANT BeAVERAGECotCEJIIRATICNJ QWETYPEJf.OFANALYSESCeMAXIJLNCOMXMIILATI ONAN)MASSAeNA%OFCRITICALMATERIALORPR!ORllYPCLLJJTANT BeAVERAGECOICEMTRATICNJ QtssLETYPEJJIOFANALYSESCeMAXIJLNCOtCEtmLATICN AtOHASSAeNA%CFCRITICALHATERIALCRPRIORITYPOLlltfANT BsAVERAGECXCEMTILATIONJ QJ4ELETYPEJJJOFANALYSESCeHAXD%NCOLCEMIILATION AJOMASSA>>NJ%OFCRITICALMATERIALCRPRICRllYPOUJJfANT BsAVERAGECCNCEMIRATIOIU SAtsLETYPEJf/OFANALYSESCHLXINJ1CCtCEMIILATINI AJOMASSAeNA%OFCRITICALMATERIALORPRICRllYPOLLLJTAMT BeAVERAGECONCEMIILATICNJ SA+tETYPEJffOFANALYSESCeHAXIJLJLCONXMIRATICN AJOMASSAsNA%OFCRITICALMATERIALORPRIORITYPCLLJJTANT BeAVERAGECPJCEtflRATIONJ QPPLETYPEJtJOFANALYSESHydrocIuinone

• WITCCDEQHPIETYPEOFANAlYSESuLNITCODELNITCODELJ~~LJLNITCCKSAMETYPEOFANALYSES~.LLLJLJLNITGXKLNITCODELJLNITCCDESAMPLETYPEOFANALYSESLNCXKLNITCODELNITCCOESAINTElYPEOFANALYSESLNITCXKLNITCODELJ~~~LJLNITCXKQtsELETYPEJfOFANALYSESLNITCCDELNITCODELJ~~~LJLNITCXKSAftELElYPEOFANALYSES~.LLLJLJUNITGXKLNITCOIKLJ~~~LJIIIIYIEEEEIEEIEYIYECsEEICYEEELNITGXKLNITCODELJ~~~LJLNITCXESWALElYPEOFANALYSESLJCeHAXIKJLCONCEMIRATIOM AtOHASSUNITCODELNITCODELJ+Smallonly.wouldADDITIONAL PAGESCFTHISITBl7AREATTAC%DFCR7%RESTOF~CRITICALE3YESMATERIALS AIO/CLPRICRTIYPLXWTAMTS RBXJIREDTDBEREPORTED.

KNOquantities ofHydroquinone maybeusedinblackandwhitefilmdeveloping inemergency situations Nofilmwasdeveloped in1993andnohydroquinone wasdischarged. Approximately oneliter beusedwhenprocessing isnecessary. 39 INSTRUCTIONSFORCOMPLETING SECTIONIIITEM7ThisformIstobeusedbybothsurtaceandground<<ater applicants torecordInformation onanyMichigancriticalmaterial, E.P.A.prioritypollutant, orhazardous substance In<<hichthisapplication requiresdatatobeprovided. This<<ovidIncludeanychemicalSubatanoe tramtheMIChlganCrltICalMaterlalS ReglSter(TableIV),theE.P.A.PrlOrltyPOllutant LIStlngITableY),OrTableSIIA-YA<<hlchIlstsOrganicToxicPollutants,OtherToxicPollutants,conventional andNonconventional PollutantsandHazardous Substances. ITEM7CRITICALMATERIALS PRIORITYPOLLUTANTS AND/ORHAZARDOUS SUBSTANCES INTHEDISCHARGE MaterialI2,3...8A.Listthenameofthechemicalsubstance icrltlcal

material, prioritypollutant, orhazardous substance) franTablesIv,VandIIA-YAasrequiredInthebox<<hlchyoucheckedInA.I-3.above.Entereachchemicalsubstance's parameter numberaslistedInTablesIV,YandIIA-VAItprovided.

B.Providetheaverageconcentration ofthechemicalsubstance namedInA.Indicatethesanpletypeusedandthenumberofanalysesmadetoprovidetheconcentration dataforthechemicalsubstance namedInA.C.Providethemaximusconcentration anddetermine themassloadingotthechemicalsubstance nmsedInA.NDTEs:I.Ifonlyoneanalysis<<asmadeforachenlcalsubstance thenrecordthatdataasamaxlmvnvalue.Itmorethanoneanalysishasbeenmadeforachemicalsubstance thenprovideanaveragevalueofthoseanalysesandthemaxlmmavalue.2.ThisSectionII,Item7.DataSheetprovidesspaceforrecording datafor8chemicalsubstances (Haterlals). Additional spaceforrecording ofdataformorethan8Materials canbemadebymakingcopiesofthisItem7DataSheetasneeded.ItIsalsoImportant touseaseparatesetotDataSheetsforeachapplicable reporting requirement aslistedInA.I-3.andforeachoutfall'efer tothelettmarginforthecodenumberrepresenting thesenpletypeusedandtheappropriate unitcodes.40 VOLATILEORGANICANALYSISRESULTSGC/HALLANALYSESUSINGEPAMETHOD8010linmIID:.EWAPLANTEFFLDoil'-DE-3DateAnalzed:05-JAN-94 Matrix:WATERAnalticalBatch¹:.122093-801020-0-3 LALSamleID:L100-DRiv;2-DEDilutionFactor:1QCBatchID:122093-801020-0-3 BCMBFBrrtRvr10885QCLimis65-12560-120Constituent DihlriflormhnhlrmhnVinIchlorideBromomethane hlrhnTrihirflrmhn11-Dichloroethene Methlenechlorideran-12-Dihlrohne11-DihlrhnChloroform 111-Trichloroethane arbnrhlride12-DihlrhnTrichloroethene TCE12-Dichloro roaneBrmihlrmhn2-hlrhIvinIhercis-13-Dichloro roenetrans-13-Dichloro roene11-TrihlrhnTerhirhnPEDibromochloro methaneChlorobenzene Bromform1122-Trhlrhn13-Dichlorobenzene 14-Dichlorobenzene 12-Dichlorobenzene Concentration Iyg/LI<0.50<3<6<4<0.<0.5<0.5<2Reporting Detection Limit/L0.50.50.5DataQualifierls) LOCKHEEDANALYTICAL SERVICEShg

VOLATILEORGANICANALYSISRESULTSGC/PIDANALYSESUSINGIVIETHOD8020linmIID:.EWAEPANTFFLDIIce:28DE-9DateAnalzed:04-JAN-94 Matrix:WATERAnalticalBatch4':122093-801020-0-3 ALmlID:L109-DaRiv:2-DE-DilutionFactor:1QCBatchID:122093-801020-0-3 TFTBFBurrRvr93101QLimis70-12075-120BenzeneTInConstituent Concentration IL<0.5<0Reporting Detection LimitIL0.5DataQualifier shlrnznEthIBenzenem-Xlene-Xln1-Dihlrnzen14-Dichlorobenzene 12-Dichlorobenzene <2<2<2LOCKHEEDAIVALVTICAL SERVICES$0 VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260Page1of2linmIID:.EWAEPLANTEFFLDateCollected: 28-DEC-93 Matrix:WATERAnaliIBah0114-2-F2QCBatchID:011094-8260-F2 LALmIID;L1-47DateReceived: 29-DEC-93 DateAnalzed:11-JAN-94 DilinFcr:1SURROGATE RECOVERY12-Dihlrhn-4Tln-QCLimits7-1144-Bromofluorobenzene 8686-115Constituent Ghloromethane VinIhlridBrmomhnChloroethane Trichlorofluoromethane An11-DihlrhnCarbonDisulfide MethleneChloriderans-12-DihlrhnVinIA11-Dichloroethane 2-Butanone i-12-Dihlrhenhlrfrm111-Trichloroethane CarbonTetrachloride 12-DihirhnBnnTrichloroethene TCE12-Dichloro roaneBromodihlrmhn2-hlrohIVinIEhr4-MethI-2-entanonecis-13-Dichloro roeneTInrn-1-Dihlrrn2-Hexanone 112-Trichloroethane-Tetrachloroethene PCEConcentration IL<5<5<5<5<5<5<10<5<5<5<5<2<10<5<10<5<5Reporting Detection LimitIL101010DataQualifier sLOCKHEEDANALYTICAL SERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260Page2of2ClientSamleID:S.SEWAGEPLANTEFFL.LALSamleID:L1009-47Constituent Dibromochloromethane hirnznEhlnznm-Xleneo-XlenernBrmfrm1122-Tetrachloroethane 13-Dichlorobenzene 14-Dihlorenzne12-Dichiorobenzene Concentration IL<5<5<5<5<5Reporting Detection LimitILDataQualifier sLOCKHEEDANALYTICAL SERVICES22 VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260TENTATIVELY IDENTIFIED COMPOUNDS ClientSampleID:S.SEWAGEPLANTEFFLDateReceived: 29-DEC-93 Matrix:WATERAnalytical Batch:011094-8260-F2 LALSampleID:L1009-47DateAnalyzed: 11-JAN-94 DilutionFactor:1QCBatchID:011094-8260-F2 Tentatively Identified CompoundUNKNOWNSULFURCOMPOUNDUNKNOWNEstimated Concentration Iyg/L)3728Retention Time(minutes) 4.479.70DataQualifierls) LOCKHEEOANALYTICAL SERVICES SEMIVOLATILE ORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270linmIID:.EWAEPANTEFFLDateCollected: 28-DEC-93 Matrix:WATERAnIiIBch¹':1114-827-BQCBatchID:8270-SEMIVOLATILES-3964 IALmIID:L1-1DateReceived: 29-DEC-93 DiluionFactor:1DExr:4-JAN-4DateAnalzed:11-JAN-94 P1f22-FluorohenolRRATEREVERY026Limi21-100Phenol-d, Nitrobenzene-d, 2-Fluorobi henI24-Tribromo henolp-Terphenyl-d,4 1861547610-9435-11443-1161-1233-141niuenPhenolbis2-Chloroeth Iether2-hlrhnI1-Dihlrnzn14-Dichlorobenzene BenzIalcohol12-Dihlrbenzne2-MhIhnolbis2-Chloroiso roIether4-MethIhenolN-Nir-Di-n-rIminHxhlrhnNitrobenzene Isohorone-NirhnI24-DimehIhnIBenzoicacidbis2-Chloroethox methane24DihlrhnI124-TrihlrnznNahthalene4-Chloroaniline Hxhlrin4-hlr--mhIhnI2-MethInahthaleneHexachloroc cloentadiene Concentration L<10<10<10<10<10<10<10<10<50<10<10<10<10<10Reporting Detection LimitIL10101010101010101010501010101010DaaalifirsLOCKHEEDANALYTICAL SERVICES SEIViIVOLATILE ORGANICANALYSISRESULTSFORGC/IVISANALYSESUSINGIVIETHOD8270ClientSamleID:S.SEWAGEPLANTEFFLLALSamleID:L1009-31Pa2f2Constituent 24-TrihlrhnI24-TrihlrhnI2-Chlorona hthalene2-Nitroaniline DimhIhhIAnhhln26-Dinitrotoluene 3-Nitroaniline Anhhn24DinirhnI4-NitrohenolDibenzofuran 24DinirInDihlhhl4-ChlorohenI-henletherFluorene4-Nirnilin4-Dinir--mhIhnIN-Nitrosodi henlamine4-BromohenI-henletherHxhlrnznPnhlrhnlPhenanthrene Anthracene Din-IhhIFlurnhenePreneButIbenzIhthalate'-Dihlrnziin8n'hrnChrsenebis2-EthIhexIhthalateDi-n-IhhIBnzflrnhnBenzokfluoranthene BenzoareneInn1-rnDinzhnhrnBenzohierleneCarbazole Concentration (IL)<10<25<10<10<25<2<25<10<10<10<2<2<10<10<2<10<10<10<10<2<101.3<10<10<10<10Reporting Detection LimitIIL)102510102525101010101010101010101010101010DataQualifieris) JBLOCKHEEDAItIALYTICAL SERVICES4J. VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD'8270 TENTATIVELY IDENTIFIED COMPOUNDS ClientSampleID:S.SEWAGEPLANTEFFLDateReceived: 29-DEC-93 Matrix:WATERAnalytical Batch:011194-8270-8 LALSampleID:L1009-31DateAnalyzed: 11-JAN-94 DilutionFactor:1QCBatchID:8270-SEIVIIVOLATILES-3964 Tentatively Identified CompoundBenzaldehyde UnknownUnknownUnknownHydrocarbon Hydrocarbon Estimated Concentration (yg/L)10Retention Time(minutes) 7.8525.0527.4630.2531.9933.87DataQualifier(s) LOCKHEEDANALYTICAL SERVICES42 PESTICIDE ANALYSESRESULTSBYGC/ECDUSINGMETHOD8080FORCOOKNUCLEARPLANTClienSamleID:S.SEWAGEPLANTEFFLDateColleced:28-DEC-93 DateExtracted: 04-JAN-94 Matrix:WATERAnalticalBatch4:012094-8080-A-1 LALSmleID:L109-2DeReived:29-JAN-94 DateAnalzed:21-JAN-94 DilutionFactor:1QCGrouID:8080PEST/PCBS 3965SURROGATE RECOVERYOoQCLimitsTCMXDCB705060-15060-150A-BHCB-BHCG-BHCD-BHCConstituent Concentration /L<0.05.05<0.05Reporting Detection Limit/L0.05.050.05DataQualifier(s) HEPTACHLOR ALDRINHEPTACHLOR EPOXIDEG-CHLORDANE ENDOSULFAN IA-CHLORDANE 44'-DDE44'-DDTDIELDRINENDRINENDOSULFAN II44'-DDDENDRINALDEHYDEENDOSULFAN SULFATEMETHOXYCHLOR TOXAPHENE PCB-1016PCB-1221PB-122PCB-1242PCB-1248PCB-124PCB-1260TECHNICAL CHLORDANE MIREXTCMX-tetra-chloro-meta-xylene DCB-Deca-chloro-biphenyl <0.05.5.0<0.05<0.05<.05<0.1<0.1<0.1<0.1<0.1<5<2<0.10.05.00.050.050.10.10.10.10.10.10.10.5<0.1LOCKHEEDANALYTICAL SERVICES METALSRESULTSClientSamle'D:S..SEWAGE.'.PLANT. EFF,DateCollected. '12-28-93, Matrix:.round.waterLALBatchID(s):1220imDateReceived: 12-29-93PO¹69095-040-3N -.Constituents MethodConcentration -imIL)Reporting Detection. UmitlmIL)DataQualifierls) DateAnalzedLAL'amleIDAluminumAntimonArsenicBariumBeIliumBoronCadmiumChromiumCobaltCoerIronLeadManesiumMananeseMercuMolbdenumNickelSeleniumSilverSodiumThalliumTinTitaniumVanadiumZinc6010602060206020602060106020602060206020601060206010602074706020602060206020601060206020601060106020<0.20<0.060<0.010<0.20<0.005<0.20<0.005<0.010<0.050<0.025<0.10<0.003140.025<0.0002<0.20<0.040<0.005<0.01034<0.010<0.20<0.10<0.0500.0470.200.0600.0100.200.0050.200.0050.0100.0500.0250.100.0035.00.0150.00020.200.0400.0050.0105.00.0100.200.100.0500.02001-20-94L1009-1601-27-94L1009-1601-27-94L1009-1601-27-94L1009-1601-27-94L1009-1601-20-94L1009-1601-27-94L1009-1601-27-94L1009-16-01-27-94 L1009-1601-27-94L1009-1601-20-94L1009-1601-27-94L1009-1601-20-94L1009-1601-27-94L1009-1601-07-94L1009-1601-27-94L1009-1601-27-94L1009-1601-27-94L1009-1601-27-94L1009-1601-20-94L1009-1601-27-94L1009-1601-27-94L1009-1601-20-94L1009-1601-20-94L1009-1601-27-94L1009-16Comments: LOCKHEEDANALYTICAL SERVICES

GENERALCHEIVIISTRY RESULTSClientSamle(D:S.SEWAGEPLANTEFFLDateCollected: 12-28-93Matrix:roundwaterLALBatch(D(s):1229imDateReceived: 12-29-93POP69095-040-3N Constituent

Fluoride, inmILChloride, inm/LNitrate-Nitro en,inmILNitrite-Nitro en,inm/LSulfate,inmILAmmonia-Nitrogen, inm/LTotalCyanide,inmg/LMethod340.2300.0300.0300.0300.0350.1335.2Result<0.1512024<0.503924<0.020Reporting Detection Limit0.150.0160.0170.500.0590.500.020DataQualifier(s)

D(1:10)DateAnalzed01-24-9412-29-9312-29-9312-29-9312-29-9301-05-9401-03-94LALSamle'IDL1009-4L1009-4L1009-4L1009-4L1009-4L1009-8.L1009-12Comments:

LOCKHEEDANALYTICAL SERVICES SEEINSTRUCTIONS ONREVERSESIDESECTIONIINUMSEAPERMIT~!ailppp5827iEMtAeUXATIONOFDISCHARGE B>>H4%RECEIVING HATER(IE>>GROIKWATER CRIU<%OFSIRFACEDRYWES~NA~SW<~SPjSEtTIII~P6TM~jJQJRAKEDISCHARGE LOCATIONCel}0YOUDISCHARGE S~Y(IFIO>>CNTIIAETOE)DeIFYES>>LISTDISCHARGE PERIODStO>>/DAYYEStO>>/DAYFLOWRATEWASTEWATER ZXHMEK.1CONTACTCOOUNQ2NONCONTBCT COOLINQ3PROCESS4SANITARY5STORMWATER E>>LANDAPPLICATION RAlEF>>lYPEOFHASTKHATKR DISCHARGE GeDISCHtRGE SCIHlIE(YEARLYAVERAGE)H>>DISCHARGE FIENRATEIN>~~LJIR>>DAY,IN>>/WK>>~~'wIOURS/DAY lOTALYEARLYDAILYHINIttHDAILYSWINII~25:0,~00WIT1CCCE~3~3WASTBIATKR TYPECODE~3~51MQY2MQD3QPDITEM2WATERTREATMENT ADDITIVES JeHIXIIEPIDESIGNDISCHijRGE FUNRATE<AeISYOUUSEWAlKRTREATISEAEOITIVES TOTRFATYNRDI~(IFtOCNTIIAKTOITBI3)Bet&%FWCTION>>AtOCIKIIICAL CPASITINOFTIIESEAISITIVES>> DESIGNCeHit%AIOAEORKSSOFHAIAFACTIRERS OFTIESEAISITIVES>> IelIENXIMPlDISCHIIRGE FlOtRATETOBEAUMRIZEDIHPEBIIT>>WlGXK1MQ/I2UQ/ID>>EXPECTEDDISCHARGE CCtCKIIIRATIOH CFAEOITIVES>>AEOITIVEIU%ACOITIVEIU%AISITIVEHA%EeDOVIXITREATTIEDISCHARGE TORBOVEAISITIVES? FeHIATISTHERBOVALEFFICIBICY NDDIKHARGEFRECEEIICY? HINIMIIWITSAVERAGEWITSHAXIISPIWITSCQECOCKMs~LJg~LJLJI~LJI~LJLJ'LJ'LJAID!TIVEHA%AISITIVENA%AEOITIVEtWEtRS>>/DAYDAYS/WK>>G.ASAHATTACttEHT TOTHISAPPLICATIN f%0VIOESPECIFICMPH%.IANORAOUATICTOXICOUXIICAL DATACRREFB\BICE WHIOIAREAVAILAREANDINRRIATIN CNTHERATECFDKGRAOATIN OFTIEPA0RCGFCREACHAISITIVE>> 31 INSTRUCTIONS FORCOMPI.ETING SECTIONIIITEMSIANO2tThisformrequiresInformation onthetacility's discharge

location, discharge

schedule, volumetlowrateandvotertreatment additives.

ENTERTHEPERMITIAP(8ERINTHEBOXATTHETOPOFTHISFORM.THEPERMITINM8ERCANBEFOUNDONTHEFRONTPAGEOFYOUREXPIRINGPERMIT.IfthisIsanerornotpreviously permitted

facility, thenleaveblankandanumbervillbeassigned.

EntertheoutfallnmberInspaceprovidedtoreachpageofSectionII.ForeachIndividual discharge pointaseparatesetofSectionIIformsmustbefilledovt.ITEMIDISCHARGE LOCATIONSCHEDULEANOFLOHRATESA.Enterthelocationofdischarge, thisshouldIncludeqvarter-quarter section,quartersectIon,section~town,sndrange.B.Listnameofreceiving water(ifsurfacevoterdischarge). C.IndlCntewhetherfOCllltydlSChargeS OnOSenSOnalbnSIS.O.Ifyes,listdischarge periods.E.ProIdethelandapplication ratesusedorexpectedtobeusedIntermsofInchesperhour,hoursperdoy,nndInchesperweek.F~Indicatethetypeofwastewater tobedlschnrged franthisoutfall.Refertothewasterster typecodegivenInthelettmngin.Morethanonecodemaybeapplicable. G~ProvidetheaveragenvnberofhoursperdayInwhichthefacilitydischarges treatedwastevnter ondthetotalnumberofdaysperyearInrhiChthedischarge occurs.H.Providecurrent(frantheInstl2months)ot'xpected flowratesssrequested. RefertounitcodeqlvenInthelettmarginfortheappropriate flowunits.MGY-milliongallonsperyear;MGD-milliongallonsperdoyiGPD-gallonsperday.I.Providethemaximumdischarge flowratewhichyouwanttohaveauthorized withinthepermit.NOTE:ForNPDESpermitsonly,theuseotsuchstlowrotevillnotploceanactuallimitrestriction ontheflowbutvillbetheflowroteusedtodevelopeffluentlimits.Also,whentheMonthlyoperating Reportsarerevie~edbyccmpllsnce staffIt<<IIIhelpthentodetermine ifnnynerorincreased usesmighthaveoccurredstthetaclllty. J.Providethedesignflorforthisspecificouttslldischarge (e.g.botchtreatment systemflow,packagedtreatment systemtlo,orsaneotherfinitetreatment systemflow)~ITEM2MATERTREATMENT ADOITIVESA.Indicate~netherdischarge Istreatedvlthconditioners, inhibitors, ormlcrobloclde. Ifnot,continuetoItemS.B.Givenome,function, sndchemicalcomposition ofadditives used.C.Givenameandaddressotthemnnutscturer(s) oftheadditives used.O.IndicateexpectedmlnlmNn,sverngeandmaximumdischarge concentrations oftheadditive(s) forthisdischarge. E.Indicate~batheryoutreatthedischarge toremovetheadditive(s) beforedischarge ofwastewater. F.,Indicate theremovaleftlclency ofeachadditive{remthevastcwster andthedischarge trequency oteachadditivetothesurfacevoterorgroundwater. G,NOTE:ItIsTheresponsibility oftheapplicant tosupplytheproductInformation asrequested In'hisItem4.Information requested butnotsuppliedmsyresultIntheapplication beingreturnedtotheapplicant torcompletion. 32 SEEINSTRUCTIONS ONREVERSESIDE-SECTtONIIPERMIT~Ivil0005827NUMBERA~NPKOFPROCESSCONIRIBUTING TOTHEDISCHARGE THOROUGHTHISOUTFAILAttOSICCODEBePRXESSSCHGXAE(YEARLYAVERAGE)*~N~ATRANSDECKDRN4911PROCESSSTREAMSCONTRIBUTING TOOUTFALLDISCIIARGE t/94/tOs0CCCLCePROCESSHASTEHAT8I FUX4RATEDePROCESSPRODUCTION RATETOTAI.YEARLYDAILYMINIMADAILYMAXIM'~212000~2WITSlTIME~LJJlHIL'Uc5HK TPOUNDS2GALLONS3CUBICYARDS4TONS5MGY6MGD7GPDttt4/tOcv0AeNAtEOFPROCESSCXIIIBUTIt6 TOTIEDISCHARGE TlFOIGHTHISOUTFALL9%SICCCÃBePROCESSSCIETXLE(YEARLYAVERAGE)**CeIROCESSHASTEHATER FLOWRATE**DePROCESSPRODUCTION RATEAeNA%OFPROCESSCONTRIBUTING TOTIEDISCNRGETIROXIHTHISOUIFAILAteSICGXEBePROCESSSCtHXXE(YEARLYAVERAGE)**AC.PROCESSQSEHteTER FlatRATE*4'*/esse/sev ~seve/vses TOTAI.YEARLYDAILYMINItXT4DAILYtVNItTT4WITSJ'TIFEESELOILTK~4911esses/sev ~srs/vsesTOTALYEARLYDAILYMINWHDAILYNXIltNDIESELSUMPS4911HOUR2DAY3WEEK4MONTH5YEARDePROCESSPRODICTICN RATE***AeNA%OFPROCESSCOtnRIBUTit4 TDTIEDISCHARGE AN)SICOXEB~PROCESSSCIEIXXE(YEARLYAVERAGE)PROCESSHASTEtliTER PIONRATED.PROCESSPIOXXTION RATEAeNA%OFPROCESSCONTRIBUTII6 TOT%DISCBUIGE ITttXXBTHISOUIFALLANDSICOXEBePRXESSSCIEDIXE(YEARI.YAVERAGE)CePROCESSHASTEttATER FUJIRATEDePROCESSPRODUCTION RATETOTALYEARLYDAILYMINIISTIDAILYtVNIt994TOTALYEARLYDAlLYMIHIISTIDAILYMAXINBWITS/TIMEWITCCOEWITSMIMEWITCODEUNITS/TIMEPrimarily basedonrainfallfrequency andduration. Delugetestingwouldbe3-30min/day fornomorethan10days.**EDGsumpdischarges volumesareinsignificant.

• • • Noknowndischarges 33 INSTRUCTIONS FORCOMPLETING SECTIONIIITEM3Trlstormrequiresinformation ontheprocessstreams<<hlehcontrlbvte tothisdischarge.

ENTERTHEPERMITNWBERINTHEBOXATTHETOPOFTHISFORM.THEPERMITNISIBERCANBEFOUNOONTHEFRONTPAGEOFYOUREXPIRINGPERMIT.\fthisIsanewornotpreviously permitted

facility, thenleaveblankandanumber<<illbeassigned.

EnteroutfnlInvmoerlnsonceprovidedtoreachpageotSectionII.ForeachIndividual discharge ointnseparatesetcfSectionIIforr>>smustbefilledout.ITEM3PROCESSSTREAMSCONTRIBUTING TOOISCHARGErFOREACHSEPARATEPROCESSPROVIOETHECOLL(PING INFORMATION A.Enterthenomeoftheprocesswhichcontributes tothisdischarge. AlsoprovidetheproperSICcode.B.IndicatetneyearlyaverageprocessscheduleInhoursperdoyonddays>>per-year. C~providetheprocesswastewater flowrateinformation asrequested basedonyourinstI2monthsofoperations. Refertounitcodegivenintheleftmarginfortheappropriate flowunits.O.ProcessProduction RoteCertainpermitItm/totlons maybebasedonproduction rates.Theproduction ratesusedtodetermine permitlimitsshallberepresented byareasonnble measureofactualproduction ofthefacility, suchastheproduction duringthehighmonthofthepreviousyear,orthemonthlynveroqeforthehighestofthepreviousfiveyears,orotherreasonable measurensstatedinapplicable U.S.E.P.A. categorical rulesandregulations. Fornewsourcesornewdlschargers, actunlproduction shellbeestlmoted usingprojected production. Recordyourproduction rateslnthetermsnndunitsusedIntheapplicable U.S.E.P.A. categorical rulesandregulations foryourtypeotfacility, 34 SEEINSTRUCTIONS ONREVERSESIDESECT(ONIIPERMIT~MT0005827NUMBERJEM4GROUNDWATER DISCHARGE INFORMATION A.ISTHEDISCHARGE FROMTHISOUIFALLDIRECIEDTOlHEGRCNIDORGROIWDtATERSZ (IFtCI>>CCttTIIAE TOITBIP)BeHASAHYDROGEOUXIICAL STUDYORITSEQUIVALENT BEENPERFORtKXI ORISTHEREBIFFICIENTCURRENI'YCROGEOLOGICAL INFORMATION AVAILABLE ASREQUIREDBYTIEMATERR~CCttIISSION PART22GRONIDtATER RULE/OFAISUST14>>1%9R>>5ZS>>Z?07 (PAGEILI)FORlHISEXISTI%ORPROPOSEDDISCHARGE! IFYESATTADIACCPYOFTHEREPCRT>>CeAREYOURBXKSTIMI ANEXPPTICNFRCMSIKHITTII6 AHYIIIOGEOUXiICAL REPORTIXKIERRIAER>>X5>>22F(Q(PAGEt15)CRFRCMGROL59IATKR MGNITORIgi IIEQUJREMENTS LIBERRIAERe25>>(5)(PAGEOFTIEPART22BILES>>IFYESATTACHCOQttENIS AN)EXPLANATION TODEIDNSTRATE THATYIXRDISCHARGE ICtIDQUALIFYFCRANEXEtPION>>DeAREYOUREQLKSTI% AVARIANCEFIOIRULE323>>2205(PAGE5)(NXIDEGRADATICN) OFTHEHATERREQXRCESCCt%ISSIONPARTZi?~TERRIIESZIFYES>>ATTACHSUCHDOCU'ANTS ASNECESSARY TODEMtINSTRATK TIENEEDFORAVARIANCEINTERMSOFTIECRITERIASPECIFIED IN'RIDX5>>2210(PAGE+OFTHEPART2ZRULES>>EeI,ISTAlp.CIKHICALSIBSTANCES HHICHAREIHM1CHIGANSCRITICALMATERIALS REGISTERTABLEIVIPAGEII)AND/ORU>>S>>EPASPRIORIIYFIXLUTANT LISTTABIKV(PAGE7)ORANYOTIERQSSTANCES NIICHAREORMAYBOXPEINXRIOUSTOT%:DESIGNATED USESOFTIEG(IXNDHATKR IXITOTIEPUBLICHEALTHTHATAREDISCHARGED OREXPECTEDTOBEDISCHARGED TOTIERRIXtCltATERJIY THISFACILITY>> ESTIMATETHEFINALEFFIleITCOCBIIRATION AtORENDAILDATAINITBI7OFSECTIIXIIIINTHISBOOST>>~~YESK0Submitted 12/6/91YESPgtOQYESQglNOTAPPLICABLE/BELIEVED ABSENTT%APPLICANT MAYBEREQIIREDTODOACDITICNAL HASTEANALYSES>> A>>DISCHARGE CHARACTKRISTICS CONCDIIRATI ONPRESENT>>DATAPROVIDEDINITKM70ITEM5EXPECTEDWASTEWATER CHARAC'I>>>>lesUNiTSCODE1Mg/I2UO/I3COUNTS/100ml4S.U.5F6LBS/DAYTOC(TOTALORGANICCARBON)AtttGNIANITRIXiEN (ASH)TOTALSUSPEMKDSOLIDSTOTALPteSPHORUS (ASP)TOTALRESIRNLCttDRINEDISSOLVED OXYGENHIH~.LJFECALCOLIFORMBACTERIA~TINE(QPPER)TKtPERATINE (KINIER)BCO5(FIVEDAYBIOCteIICAL OXYGENBEMA%)COD(OeIICALCEIYGEHDEMAND)AVE>>~~LJ~~LJBeOIIKRHLSTBWKRCHIIIACIKRISTICS >>LJLJ5~5LJLJLJLJLJLJLJSAMPLEJXEF1GRAB224HOURCOMPOSITE 0ILIlGREASEi<>>PCBAYtTOCLJ~LJLJ~LJLJLJ~LJLJ~LJLJ~LJREOIIREDIIFIXPIAT ICNRXIQRFACEHATKRDISCHARGES ~Seeattachedsampleanalysis INSTRUCTIO'IS FORCCMPLETING SECTIONIIITEMS4ANO5ThisforrtrequiresInformation onaspecificoutfalldischarging toeitherthegroundraters orthesurface~aters.ENTERTHCPERMITNLSIBERINTHEBOXATTHETCPOFTHISFORM.THEPERMIThWBERCANBEFOUNDOt(THEFRONTPAGEOFYOUREXPIRINGpERMIT.Ifthislsane>>ornotpreviously permitted feeillty,thenleaveblankandanumberwllIbeassigned. EntertheoutfallnumberinthespaceprovidedforeachpaaeofSectionII.ForeachIndividual discharepointaseparatesetofSectionIIforms(Items4and5)mustbefIliedout.ITEM4GROUNDWATER DISCHARGE INFORMATION (00NOTIIICLUOEDEEPWELLIIUECTION INFORMATION INTHISITEM)A.-O.Theapplicant shalladdresseachofthesepartsIfthedischarge franthisoutfalIIstothearoundwater. ITEM5EXISTINGOREXPECTED(FORANEWDISCHARGE) WASTEWATEP. CHARACTERISTICS OFGROUNDWATER ORSURFACEWATERDISCHARGE (00NOTINCLUDEWLLIN)IININHA.Theapplicant shelIreportavailable discharge data(realdataforexistingdischarge orexpecteddataforaproposeddischarge) fortheparameters aslisted.Theseparameters shallbeaddressed foreitherasurfaceraterdischarge orasappropriate foragroundwater discharge. Forassistance Indetermining appropriate parameters agroundrater dlscharaeappIleantmaycontacttheGroundwater DualityDivision, Permitssectionortheappropriate Groundwater DualityDivision's Districtoffice.Theapplicant shallreporrthesampletypecodebestdescribing eachreportedpieceofdata.Seecodingontheleftmarginofthisform.IfthisoutfallIsasurfacewaterdischarge, theapplicant mustreportquantitative dataforeachparameter identified baneely",I~e9d"eb'e~.bbeeettbebbtdbydeettlbI,tlbbdbdbttt<<etttbl~ebllebtl8.IfdataIsavailable forotherparameters notlistedaboveInA.orotherpartsofthisapplication theapplicant shouldreportthatdataintheblankspacesprovidedInthispart.I'OTES:I.Unitcodesforparmreters reportedInpartsAand8canbefoundontheletthandsideofthisfotta.2.GrabsampleshallbeusedtoanalyzeforpH,temperature, tote)phenols,residualchlorine, oilandgrease.andfecalcoliformInasurfacewaterdischarge unlessotherfrequency-sample typeanalysesareavailable. SeeGlossarY(page48)fordefinition ofgrabsample.24-hourcomposite samplesshallbeusedtoanalyzeforTotalB005,ccD,Toc,AmnonlaNitrogen, andTotalSuspended SolidsInasurface~aterdischarge unlessotherfrequency>>sample typeanalysesareavailable. SeeGlossary(page4B)fordefinition ofcomposite sample.4.REpoRTING 0FINTAKEDATA.Youarenotrequiredtoreport'unlessyouwishtodemonstrate yourel)glbllltyforametreffluentIimltatiOn farOneOrmOrepOllutantS, thatIS,aneffluentllmltatlOn adjuStedbySubtraCtlng theaveragelevelofthepollutant(s) presentInyourIntakewater.NPOESregulations allownetlimitations onlyIncertaincircumstances. Todemonstrate youreligibility, reporttheaverageoftheresultsofanalysesonyourIntakewater(lfyourrateristreatedbeforeuse,testthewaterafteritIstreated), andattachaseparatesheetcontaining thefolloring foreacnpollutant: (a)Astatement thattheIntake~aterIsdrawnfromthebodyofwaterintowhichthedischarge Ismade.(Otherrlseb youarenoteligiblefornetlimitations.) (b)Astatement oftheextenttowhichthelevelofthepollutant Isreducedbytreatment ofyourwastewater. (Yourlimitations rillbeadjustedonlytotheextentthatthepollutant isnotremoved.) (c)'whenapplicable (forexample,whenthepollutant represents aclassofcompounds), ademonstration oftheextenttowhichthepollutants IntheIntakeveryphysically, chemically, orbiologically fromthepollutants contained Inyourdischarge. (Yourlimitations wlIIbeadjustedonlytotheextentthattheintakepollutants donotvaryfrowthedischarged pollutants.) 5.Ifyouhavetwoormoresubstantially Indentlcal

outfalls, youmayrequestpermission franyourpermitting authoritv tosampleandanalyzeonlyoneoutfalIandsubmittheresultsoftheanalysisforothersubstantially Identical outfalls.

Ifyourreauestisgrantedbythepermittlna authority, onaseparatesheetattachedtotheapplication formIdentifywhichoutfallyoudidtest,anddescribewhytheoutfalls>>hichyoudidnottestareSubStantlally ldentlCal tOtheOutfallwhlChyOudidteSt.36 .>L.H<b~On]gJ$aarCORPORATIONLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(4'12)747-2684January11,1994ReportNo.:00018818SectionAPage2CLIEHTNAME:ADDRESS:ATTENTION: INDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGEMAN, MI49106-MR.ROLAHDBEENHUSCLIENTNO:06630018WORKORDERHO:55830VEHOORHO:05411000CarbonCopy:SAMPLEID:OIL/WATER SEPARATOR HUSSAMPLENO:P0258839P.O.NO.:69034-040-3N DATESAMPLED:28-OEC-93 DATERECEIVED: 29.DEC.93 APPROVEDBY:Kieda,ChuckTESTLNCODEOETERMINATIOH RESULTUNITS1G122W311064168051490PCBANALYSISPCB-1016PCB-1221PCB-1232PCB-1242PCB-1248PCB-1254PCB-1260Carbon,Organic-Nonpurgeable OilandGrease,Gravimetric pH<0.05ug/L<0.05ug/L<0.05ug/L<0.05ug/L<0.05ug/L<1.0ug/L<1.0ug/L6mg/L3mg/L7.4COMMENTS: SEEINSTRUCTIONS ONREVERSESIDESECTIONIIPERMIT~>>IVIzppp5827NUMBERiEM6PRIORITYPOLLUTANTS ANDADDITIONAL INFORMATION FORSURFACEWATERDISCHARGE ONLYREQUESTED INFCRt47ICH ~~ADCRESSED ~QRFACEHATERDISCHARGERS. IDIEtNEWUSEDISCHUIGERS 2IIIILPROVIDEEXPECTEDVALIESFORTHECUAMflTATIVE ANDQUALITATIVE INFCRHATIONREOIKSTKD BEUWeA.ISTHISFACILllYAPRItVVIYINDUS1RY? (REFERTOTABLEIAPar<gJ)(IFtOeGO70E)(IFY5GOTOB)BeIMIICATElYPEOFPRIIVUIYINDUSTRYASLISTEDINTABlEIAPAGoKQ,(CONTIN%WITHC.)C.DOES1HI5CUIFALLDISCHARGE CctlTAINANYPROCESSWASTEWATER? (IFNOeGOTOE)(IFYKSeGO70D)DoINDICATEHlICHGC/tmFRACflONS FttSTBETESTEDFCR~(REFERTQTABLEIaPate9DKIIE!FOREACHGC/HSFRACTIONOIECKKDeKAOI SPECIFICORGANICTOXICPOLunaNTHITHINEacHFRACTIQNt55IBEAMALYIKDFOR(5EETABLEIIAPAGE92,IMADDITIQNe ALLFRIARYIMXISTRYAPPLICANTS WITHAPROCESSWASTEWATER DISCHARGE'~ PROVIDEQUAtnITATIVEDATAFOREACHTOXICPOLLUTAMT INTAKEIIIAPA%Q)eRECORDALLDATAONFCRHSPROVIDED(ITKH7)INTHISBQ)KLETe(CctnttUE HllHEKBELCH)~NAVOLATILEQBASE/NElm4L DcelePESTICIDEAnalysisperJ.B.Beauboeuf TargetPermitEffluentLimitsYESMOSTME'LECPWRXYESNOEeIF~QRFACEHATERDISCHARGE APPLICAtn (PRIMARYORSKCOGI4RY IMIXISTRY)e REGARDLE% OFTHElYPEOFDISCHUIGKe KMHSORHASREASONTQBELIEVETHATAHYPOLLUTANT LISTEDINTAREIIAANDIVAPAGES~ISDISCHARGED FIKttANYQITFAILeltE QIAtntTATIVE DATAISgif,BEPROVIDEDe RECCRDAILDATAONFORtSPROVIDED(ITKH7)IN1HISBOOKLETeFeIFANYQRFACEHATERDISOIARGK APPLICAMT (PRIMARYORSECONDLYIMXISTRY)e REGARDLESS OFlYPEOFDISCIIARGKe KMXtsORHASREASONTOBELIEVEANYPOLLUTANTS LISTEDINTABLEVAPAGE+AREDISCHARCM FRCHANYQnFAILTIEAPPLICANT Ltd(IDESCRIBEREASONSFORTIEPQLlnaMTBEINGPRESenAMIPROVIDEAMYAVAILABLE QIAMTITATIVE DATAeRECORDALLDATAONFOIVtsPROVIDED(ITKH7)INTHISBCOKLETeterAPPLICABLE/BELIEVED ABSENtN/ADPRESENT/DATA ISATTACHEDQMOTAPPLICABLE/BELIEVED assenN/APRESENT/DATA I5ATTACHEDDGeAILSIRFACEHATERDISCHARGE APPLICANIS (PRIMARYAMlSECCN04RY IMXITRIES) QR~actIRKS24.)-TRtosfxtfPtEMDIY AcET!cAclD(2,4,5-7):-.4,~7RtoIuwoPIEMIKY) PRQPAMQIC AOID(SILYKx,Z,4,5,TP)TRI04xRQPtERx. (TcMPJ0RHExacMJIRQPtEIE tHCPSJ(ALLDATAFcRTIEABOVEMISTBEGENERATED USINGSTAMFORDANALYTICAL CALIIRATICN PROCBXRES) QRKREISORHASREASCN1QBELIEVETHATTCKQISCRtlkYBEPRESBITIN7%IRDISOIARGEe ~REPORTtXIALITATIVE IVITAGENERATED %IOIUSEDASCREENING PROCHXREtOTCALIBRATED HllHAt4LYTICAL STAleatme FOR2De78e-TEIIIAOLORODI~DIOXIN (TCKD)eREQRDAILDATAQtFOttsPROVIDED(tlttt5INTHISBOOKLETeJeIFTtEQRFACEHATERDISCHARGE APPLICAtn KMX6CRHASREASONlQBELIEVETHATBIQDGICAI, TOXICITYTESTSWEREHADEINTHEtasrTIREK(5)YEARSONAHYQFTIEAPPLICANT 5Dl~ORCNARECEIVIMGHATERINREIATIONlQADISOIARGEe PROVIDETHISltFORHATION ASAMATTAOFENT TQTHISAPPLICATIOMe KeIFACOtnRACTLABORATORY ORCQIQLTIMG FIRNPERFCR%DPetrOFTIEAMAYSESRECUIREDBYTHISAPPLICATIOMe PROVIDETIEt4V%AHDAICRESSOFEAOtLABORATTRY ORFlirtAM)ttEANtLYSESPERFCR%DASAMATTAOtEtn OFTHISAPPLICATIONe LeDOYCUDISCHARGE ANYOTIERTOXICORIMJIRIOUS CteIICALQBSTAHCES NOTLISTEDINTABLESIVPAGEttAMIIIATtRQFtlVAPA4S~~,IFYESTANIDEtntNYTIEOKttICALQISTANCES ANDESTIHATE7%FINALEFFURITCctK:em47ICNS, SlstttrTHISIHFORQTIOH ASAMATTAOPEtn TQTHISAPPLICATION> wrAPPLICABLE/BELIEVED allenN/AQPRESENT/DATA IsATTAOEDQterAPPLICABLE N/AQAPPLICABLE/SKE ATTACHEDQtOTAPPLICABLE pgAPPLICABLK/SEE ATTACHEDMOTAPPLICABLE0APPLICABLK/sEE ATTADIKDN/A37 IHSTRUCTIQNS FORCCMPLETING SECTIONIIITEM6ThisformrequiresInformation onaspecificoutfalldischarging tothesurfacewaters.ENTERTHEPEIB(ITNUMBERINTHEBOXATTHETCPOFTHISFCRM.THEPERMITN(P(BERCANBEFOUNOONTHEFRONTPAGEOFYOUREXPIRINGpERMIT.IfthisIsanewornotpreviously permitted

facility, thenleaveblankandanumber<<IIIbeosslqned.

EntertheoutfallnumberinthespaceprovidedforeachpageofSectionII.ForeachIndividual dlscharoe pointoseparatesetofSectionIl,Item6formsmustbef1liedout.ITEM6PRIORITYPOLLUTANTS ANOAOOITIONAL INFO(a(ATION NOTE:IfyOuhaVetwOOrmOreSubatantlal lyIndentlCal

OutfallS, yOumayrequeStpermlSSIOn frCmyOurpermitting authOrlty tOsomp(eandanalyzeonlyoneoutfallandsubmittheresultsoftheanalysisforothersubstantially Identical outfalls.

IfyourrequestIsgrantedbythepermitting authority, onaseparatesheetattachedtotheapplication formIdentifywhichoutfallyoudidtest,anddescribewhytheoutfallswhichyoudidnottestaresubstantially ident)col totheoutfallwhlChyOudidteSt.NOTE:A.-C.ondE.-J.O.40CFRPortI22.2)(g)(8), Friday,AprilI,l983,providesforaSmallBusinessExemption fromthereporting ofquantitative datafororgonlctoxicpollutants andtoxicpollutants asrequiredbyPart122.2I(g)(7)(il)(A) orI22.21(g)(7)(ill)(A). Thesepartsareselfwxplonatory anddonotrequirefurtherInstructions, SimplygothrougheachpartanddoasIndicated. SeveralIndustrial categories andsubcategories hovebeenexemptedfransubmitting dotsoncertainGC/MSFractions (40CFRPertl22,Vol.48,No.64,Friday,AprilI,l983,NotesI,2,ond3).Reviewthefollowing listtodetermine whetheryourfacilityqualifies tobeexemptfromreporting GC/MS(GasChrcmatographY/ MossSpectroscopy) Fractions. GC/MSFractionTestingandReporting Exemptions TextileMIIIsIndust-AllfourGC/MSorganicfractIons IntheGreigeMIIIsSubcategory. -Pesticide fractionInoilothersvbportsofthisIndustry. OreMlnlnandDress(Indust-Volatile, base/neutral, andpesticide fractions IntheBoseandPreclovsMetalsSubcategory. -AllfourGC/MSorganicfractions lnallothersubcategories ofthisIndustry. GumandMoodChem(cols Industr-Pesticide fractionIntheTallOilRosinSubcategory andtheRosinBasedOerlvatlves Subcategory. Pesticide andbase/neutral fractions In~IIothersubcategories ofthisIndustry. PvlandPaperIndust-Pesticide fractionInPapergrade Sulfitesubcateqorles (subparts JandU).-Base/neutral andpesticide fractions inOelnkSubpartQ,Olssolvlnq KraftSubpartF,andPaperboard fromMastePaperSubpartE.-Volatile, base/neutral, pesticide fracttons IntheBCTBleachedKraftSubpartH,Sam(-chemical Subparts8andC,andNonlntegrated.F(ne PapersSubpartR.-Acid,base/neutral, andpesticide fractions (nFineBleachedKraftSubpartI,Dissolving SulfitePulpSubpartK,Ground-woodFinePapersSubpart0,HarketbleachedKraftSubpartC,TissuefromMastepaper SubpartT,andNonlntegrated TissuePapersSubpartS.SteamElectricPowerPlantIndustr-Base/neutral fractionIntheOnce-Through CoolingMater,FlyAsh,andBottomAshTransport Materprocesswastestreams. 38 SEEINSTRUCTIONS ONREVERSESIDESECTIONIIPERMIT~Ml0005827CRmCALMATERIALS TOXICPOLLUTANTS A.USETHISDATASHEETIORECORDINRXVIATION ASRECJIREDIN:(DECKAPPROPRIATE BOXIORtttICHINRÃHATICN THISDl>>TASHEEfREPRESBffs>>) Q1>>SECflOM1riIIEIIM>>GRIJ&AIER DISCHARGE IMFCVIATION (PJGE33)O2>>SECTICNII>>ITEN6>>PRICRIIYRXIUTAMTS IHSNFACEIIAIERDISCHIVttK (PAGE37)O3.B.BEUXI:CRITICALHAIERIALS (TABLEIV)INSIXIFACEHATERDISaaeK(PAX39)HAZARDOUS SUBSTANCES INDISCHARGE B>>LlsTAMvcRITlcALHATERIAL(TABLEIvPAGE6)MDTADDREssED INsEcTIcttIIIIEH6PRIDRllYPOLUJTAMTS INICHYCJIOXXIORHAVEREASONTOBELIEVETOBEPRESENTINIIEDISCHUIGE>> SEEREVERSESIDEOF'THISPAGEFORFIJIIIERDIRECTICNS>> zAPPLICABIE (SEEBEUXI)A>>NVKOFCRITICALHATERIALCRPRIORITYPOLUJTAMT FI>>B>>AVERAGECXCEIIIRATIONJ QPRElYPEJ¹OFJNALYSESC>>HAXPSltCXCENIRATICN AIOHASSWITCCKSAWLElYPEOFANALYSESLJWITCXKWITCODEA>>MJt%OFCRITICALHATERIALCRPRIORllYRXLUTANTwc>>IB.AVERAGECXCENIRATICIJ QFFLETYPES¹OFANALYSESC>>HAXPeltCNCEIIIRAT IONAJOHASSNIITCXKSWEETYPEOFANALYSES~.LLLJLJWITCXKWITCXEUNITSCODE1My/IUy/I3S/DAYKQ/DAYGRAB224HR.COMRA>>NJJ%OFCRITICALHAIERIALCRPRICRtlYPOLUJTANT wnB,AVBIAGECXCBIIRATIIXIJ SWLEIYPE18OFANALYSESIC>>HAXPMICOICEIIIRATICN AIOHASSA>>Mt%CFCRITICALHAIERIJI. CRPRIORllYRJUJJTANT B>>AVERJGECDICEIIIRATIONJ QtPLEIYPEJ¹OFANALYSESCHAXPtltCNCEIIIRATIIXI AJOHASSA>>NA%OFCRITICALHATERIALCRPRIORITYAXLJJTAMT B>>AVERAGECXCENlltATIIXI JQfREIYPEJ¹OFANALYSESIC>>HAXPSNCXCBIIRATION AJOHASSWITCOEQIVLETYPEIKANALYSESINWITCXKWITCXKQPAETYPEINITCODEtillT.CXKLJ~~~LJWlrCCKaVezTYPE¹OFANALYSESLJINITCOEINITCODEA>>HAIKOFCRITICALHATERIALCRPRICRIIYPOLUJfANT weBAVERAGECNCENIRATIOtU Q%LETYPEJ¹OFANALYSESC.HAXPSPICOCBIIRATICN AJOMSSWITCXKQJFIKTYPEOFANALYSESLJWITCODEINITCOIKA>>NJPKOFCIITICALHAIERIJLCtPRIORIIYRXLllfAMT wI>>',AVBIJGECXCBAltATIOI JALEIYIEI¹OFANALYSESIC>>HAXIISPICXCENIIIATICN AJOHASSA.NVKOFCRITICALHAIERIALORPRIORllYRXUJTAMTweB>>AVERAGECXXXJIIRATIONJ SAPFLETYPEJ¹OFAlWYSESC,HAXPSHCaCIIIIRAIICtt AIOHASSIPIITCCKQtl>>LElYPE¹OFANALYSESLJINITCXKINICODELJINIICXK~TYPEOFANALYSESLJWlrCXKWITCODELJ~~~LJADDITreuL PJGESoFTHrsIIEH7AREAIIActEDPORIIERESTDFIIKcRITrcALClYEsHAIERIALS Jva/CtPRrarIYPCLIJJTJttfs RECIJIRED TOBERERXIIED, EJO39 INSTRUCTIONS FORCI7ZPLETING SECTIONIIITEN7ThistormIstobeusedbybothsurfaceandgroundvater applicants torecordinformation onanyMichigancriticalmaterial, E.P.A.prioritypollutant, orhazardous substance Invhichthisapplication requiresdatatobeprovided. ThisvouldIncludeanychemicalsubstance fromtheHlchlganCriticalMaterials RegisterITableIV),theE.p.A.priorityPollutant ListingITableV),orTablesIIh-VhwhichIistsOrganicToxicPollutants,OtherToxicPollutants,Conventional andNonconventional PollutantsandHazardous Substances. ITEN7CRITIChLMhTERIALS PRIORITYPOLLUTANTS AND/ORHAZARDOUS SU8STANCES INTHEDISCHARGE MaterialI23...8A.Listthenameofthechemicalsubstance Icrltlcal materlal,prioritypollutant, orhazardous substance) tronTablesIV."andIIA-VAasreoulredIntheboxvhlchyoucheckedInA.I-3.above.Entereachchemicalsubstance's parameter numberaslistedInTablesIV,VandIIA-VAIfprovided. 8.Providetheaverageconcentration ofthechemicalsubstance namedInA.Indicatethesampletypeusedandthenumberofanalysesmadetoprovidetheccncentratlon dataforthechemicalsubstance nmnedInA.nC.Providethemaximusconcentration anddetermine themassloadingofthechemicalsubstance naeedInA.I~Ifonlyoneanalysiswasmadeforachealcalsubstance thenrecordthatdataasamaximusvalue.Itmorethenoneanalysishasbeenmadeforachemicalsubstance thenprovideanaveragevalueofthoseanalysesandthemaxlmmavalue~2.ThisSectionII,Iten7,DataSheetprovidesspacetorrecording datafor8chemicalsubstances (Materlalsl ~Additional spaceforrecording ofdatatormorethan8Materials canbemadebymakingcopiesofthisItem7DataSheetasneeded.ItIsalsoImportant touseaseparatesetofDataSheetsforeachapplicable reporting reaulrmnent aslistedInA.l-3.andtoreachoutfall.3~Refertotheleftmargintorthecodenumberrepresenting the'smapl~typeusedandtheappropriate unitcodes.40 VOLATILEORGANICANALYSISRESULTSGC/HALLANALYSESUSINGEPAMETHOD8010linmIID:TRANATHBAINDII2-DEDaeAnalzed:05-JAN-94 MatrixWATERAnalticalBatch4:122093-801020-0-3 LALmIID:L1-7DRiv:2-DEDilutionFactor:1QCBatchID:122093-801020-0-3 BCIVIBFBSrroRvr9976Limi65-12560-120Constituent DihlriflrmhnhlrmhnVinIchlorideBromomethane hlrhnTrihlrflrmhne11-Dichloroethene Methlenechloridern-12-Dihirhn11-DihlrhnChloroform 111-Trichloroethane rnrhlrid12-DihlrhnTrichloroethene TCE12-Dichloro roaneBrmihlrmhn2-hlrhlvinIhrcis-13-Dichloro roenetrans-13-Dichloro roene112-Trihl rhnTrhirhnPEDibromochlorometh aneChlorobenzene Brmfrm1122Trhlrhan13-Dichlorobenzene 14-Dichlorobenzene 12-Dichlorobenzene Concentration (yg/L)<0.50<3<6<4.5<0.5<0.5<2Reporting Detection Limit/L0.50.50.5DataQualifieris) LOCKHEEDANALYTICALSERVICESh7 VOLATILEORGANICANALYSISRESULTSGC/PIDANALYSESUSINGIVIETHOD8020linmIID:TRANATHBAINDII:2-DEDateAnalzed:04-JAN-94 Matrix:WATERAnalticalBatchII:122093-801020-0-3 LALmlID:L1-7DRiv:2-DEC-DilutionFactor:1QCBatchID:122093-801020-0-3 TFTBFBrrRvr8989QLimis70-12075-120BenzeneTIneConstituent Concentration IL<0.5Reporting Detection LimitIL0.5DataQualifier shlrnnEthIBenzenem-XIene-XIn1-Dihlrnn14-Dichlorobenzene 12-Dichlorobenzene <2<2LOCKHEEDANALYTICAL SERVICES SEIVIIVOLATILE ORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270P1f2linmIID:TRAN.ATHBAINDateCollected: 28-DEC-93 Matrix:WATERAnIiIBh¹':1114-27-8QCBatchID:8270-SEMIVOLATILES-3964 LALmIID:L1-2DateReceived: 29-DEC-93 DilutionFactor:1DExr:4-AN-4DateAnalzed:11-JAN-94 2-FluorohenolPhenol-d, Nitrobenzene-d, RROATEREVERY382859Limi21-10010-9435-1142-Fluorobi henI24-TribromhnIp-Terphenyl-d 628443-1161-1233-141PhenolnInConcentration LReporting Detection LimitLDalifirbis2-Chloroeth Iether2-hlrhnI1-Dihlrnzn14-Dichlorobenzene BenzIalcohol12Dihlrnzn2-MhIhnIbis2-Chloroiso roIether4-MethIhenolN-Nir-Di-n-rIminHxhlrhnNitrobenzene Isohorone2-NirhnI24-DimhIhnIBenzoicacidbis2-hloroethox mehane24-DihlrhnI14TrihlrnznNahthalene4-Chloroaniline Hxhlrin4-hlr--mhlhnl2-MethInahthaleneHexachloroc cloentadiene <5555LOCKHEEDANALYTICAL SERVICESU5 SEMIVOLATILE ORGANICANALYSISRESULTSFORGC/IVISANALYSESUSINGIVIETHOD8270ClientSamleID:TRANS.CATCHBASIN LALSamleID:L1009-29P2f2Constituent 24-TrihlrhnI24-TrihlrhnI2-Chlorona hthalene2-NitroanilineDimhIhhIAnhhln26-Dinitrotoluene 3-Nitroaniline Anhhn24-DinirhnI4-NitrohenolDibenzofuran 24-DinirInDihIhh(4-ChlorohenI-henletherFluorene4-Nirnilin4-Dinir-2-mhIhnIN-Nitrosodi henlamine4-BromohenI-henletherHxhlrnznPnhlrhnlPhenanthrene Anthracene Di-n-IhhIFlrnhnPreneButIbenzIhthalate'-DihlrnziinBnznhrnChrsenebis2-EthIhexIhthalateDi-n-IhhI8nzflrnhnBenzokfluoranheneBenzoareneInn12-rnDinzhnhrnBenzohierleneCarbazole Concentration (IL)<28<28<2<28<2<2<2<22280Reporting Detection Limit(IL)28282822DataQualifier(s) EBLOCKHEEDANALYTICAL SERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8270TENTATIVELY IDENTIFIED COMPOUNDS ClientSampleID:TRANS.CATCHBASIN DateReceived: 29-DEC-93 Matrix:WATERAnalytical Batch:011194-8270-B LALSampleID:L1009-29DateAnalyzed: 114AN-94DilutionFactor:1QCBatchID:8270-SEMIVOLATILES-3964 Tentatively Identified CompoundHydrocarbon Hydrocarbon UnknownHydrocarbon UnknownHydrocarbon UnknownHydrocarbon UnknownUnknownHydrocarbon Hydrocarbon Hydrocarbon Hydrocarbon UnknownHydrocarbon Hydrocarbon Hydrocarbon Hydrocarbon Hydrocarbon Estimated Concentration (pg/L)1020102010301010303030201010,Retention Time(minutes) 14.5015.0015.8316.7517.5817.7918.0118.4019.1719.2519.4219.9621.4321.5122.3222.9524.1724.5425.4326.65DataQualifier(s) LOCKHEEDANALYTICAL SERVICES7uI SEIVllVOLATILE ORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270linmIID:TRAN.ATHBAINDIIMatrix:WATER-DAnalticalBatchII'11194-8270-B QCBatchID:8270-SEMI VOLATILES-3964 LALmIID:L1-2REDRiv'-DEDiluionFactor:4DateExtracted: 04-JAN-94 DateAnalzed:18-JAN-94 Pae1of2SURROGATE RECOVERYQLimis2-FlrhnIPhenol-d, Nitrobenzene-d, 2-Fluorobi henI246-Tribromo henolp-Terphenyl-d,4 42285666767221-110-9435-11443-11610-12333-141PhnIniunConcentration L<4Reporting Detection LimitLDbis2-Chloroeth Iether2-Chlorohenol1-Dihlrnzn14DihlrnznBenzIalcohol12-Dichlorobenzene 2-MhIhnIi2-hlrirIhr4-MethIhenolN-Nitroso-Di-n-rolamineHxhlrhnNirnznIsohorone2-Nitrohenol24-DimhIhnIBniibis2-Chloroethox methane24-Dichloro hanoi124TrihlrnnNhhln4-Chloroaniline Hexachlorobutadiene 4-hlr--mhlhnl2-MhInahhalnHexachloroc cloentadiene <40<40<4<40<40<40<4<4<40<40<4<4<40<40<4<40<40<4<4<40<40<4<4<4040404040404040404040404040LOCKHEEDANALYTICAL SERVICES SEIVIIVOLATILE ORGANICANALYSISRESULTSFORGC/IVISANALYSESUSINGMETHOD8270ClientSamleID:TRANS.CATCHBASIN LALSamleID:L1009-29RE P2f2Constituent 24-TrihirhnI24-TrihlrhnI2-Chlorona hthalene2-Nitroaniline DimhIhhIAnhhln26-Dinirooluene3-Nitroaniline Anhhn24-DinirhnI4-NitrohenolDibenzofuran 24-DinirlunDihlhhl4-ChlorohenI-henletherFluorene4-Nirnilin4-Dinir-2-mhIhnIN-Nitrosodi henlamine'-Bromo henI-henletherHxhlrnnPnhirhnlPhenanthrene Anthracene Din-IhhIFlrnhnPreneButIbenzIhthalate'-DihlrniinBnznhrnChrsenebis2-EthIhexIhthalateDi-n-IhhIBnzflrnhnBenzokfluoranthene Concentration (IL)<4<4<40<100<4<4<40<100<4<100<40<4<4<40<40<40<40<4<40<40<4<4<40<40<4<40350<4<4<40Reporting Detection Limit(IL)4Q1004Q1001004Q4p4Q4Q40404Q4p4040404p"40DataQualifier(s) BenzoareneInn12rn<40<440DinzhnhrnBenzohierleneCarbazole <4<40<404040LOCKHEEDANALYTICAL SERVICES PESTICIDE ANALYSESRESULTSBYGC/ECDUSINGMETHOD8080FORCOOKNUCLEARPLANTClienSamleID:TRANSCATCHBASIN DaeColleced:28-DEC-93 DateExtracted: 04-JAN-94 Matrix:WATERAnalticalBatch4:012094-8080-A-1 LALSamIeID:L1009-21DeReceived:29-JAN-94 DateAnalzed:21-JAN-94 DilutionFactor:1QCGrouID:8080PEST/PCBS 3965SURROGATE RECOVERYoTCMXDCB8540QCLimits60-15060-150A-'BHCB-BHCG-BHD-BHCConstituent Concentration /L<0.05<0.05Reporting Detection Limit/L0.05.00.05DataQualifier(s) HEPTACHLOR ALDRINHEPTACHLOR EPOXIDEG-CHLORDANE ENDOSULFAN IA-CHLORDANE 44'-DDE44'-DDTDIELDRINENDRINENDOSULFAN II44'-DDDENDRINALDEHYDEENDOSULFAN SULFATEMETHOXYCHLOR TOXAPHENE PCB-1016PCB-1221PCB-1232PCB-1242PCB-1248PCB-1254PCB-120TECHNICAL CHLORDANE MIREXTCMX-tetra-chloro-meta-xylene DCB-Deca-chloro-biphenyl <0.05<0.5<0.05<0.05<0.05<0.1<0.1<0.1<0.1<0.1<0.5<5<2<0.10.050.50.050.050.00.10.10.10.10.1<0.1LOCKHEEDANALYTICAL SERVICESghVV METALSRESULTSClientSamleID:TRANS.CATCHBASIN DateCollected: 12-28-93Matrix:round"water:LALBatchID(s):1220imDateReceived: 12-29-93POP69095-040-3N .Conitituents-AluminumAntimonArsenicBariumBeIliumBoronCadmiumChromiumCobaltCoertronLeadManesiumMananeseMercuMolbdenumNickelSeleniumSilverSodiumThalliumTinTitaniumVanadiumZinc.Method6010602060206020602060106020602060206020601060206010602074706020602060206020601060206020601060106020Concentration .{mIL)<0.20<0.060<0.010<0.20<0.005<0.20<0.005<0.010<0.060<0.0250.54<0.0031.60.059<0.0002<0.20<0.040<0.005<0.010<5.0<0.010<0.20<0.10<0.0500.15Reporting Detection Umitlm/L)0.200.0600.0100.200.0050.200.0060.0100.0600.0250.100.0035.00.0150.00020.200.0400.0050.0105.00.0100.200.100.0500.020DataQualifieris) Date:AL.Analzed;.:-SamleID01-20-94L1009-1501-27-94L1009-1601-27-94L1009-1501-27-94L1009-1501-27-94L1009-1501-20-94L1009-1501-27-94L1009-1501-27-94L1009-1501-27-94L1009-1501-27-94L1009-1501-27-94L1009-1501-27-94L1009-1501-20-94L1009-1501-27-94L1009-1501-07-94L1009-1501-27-94L1009-1501-27-94L1009-1601-27-94L1009-1501-27-94L1009-1501-20-94L1009-1501-27-94L1009-1501-27-94L1009-1501-20-94L1009-1501-20-94L1009-1501-27-94L1009-15Comments: LOCKHEEDANALYTICALSERVICES GENERALCHEMiSTRY RESULTSClientSamleID:TRANS.CATCHBASIN DateCollected: 12-28-93Matrix:roundwaterLALBatchIDIs):1229imDateReceived: 12-29-93PO¹69095-040-3N Constituent MethodResultReporting Detection LimitDataQualifierlsl DateAnalzedLALSamleIDFluoride, inm/LChloride, inmILNitrate-Nitro en,inmILNitrite.Nitroen,inmILSulfate,inmILAmmonia-Nitrogen, inmILTotalCyanide,inmg/L340.2300.0300.0300.0300.0350.1335.2<0.150.52<0.017<0.0124.713<0.0200.150.0160.0170.0120.0590.500.020DI1:10)01-24-94L1009-312-29-93L1009-312-29-93L1009-312-29-93L1009.312-29-93L1009-301-05-94L1009-701-03-94L1009-11Comments: LOCKHEEDANALYTICAL SERVICES VOLATILEORGANICANALYSISRESULTSGC/HALLANALYSESUSINGEPAMETHOD8010linmIID:BLANKDColl'ADateAnalzed:04-JAN-94 Matrix:WATERAnalticalBatch4:122093-801020-0-3 LAmIID:AD17DRiv:NADilutionFactor:1QCBatchID:122093-801020-0-3 BCMBFBurroaeRecover9494Limis65-12560-120Constituent DihlriflormehnehlrmhnVinIchlorideBromomethane hlrhnTrihlrflrmhn11-Dichloroethene Methlenechloridern-12-Dihlrhn11-DihlrhnChloroform 111-Trichloroethane rnrhlri12-DihlrhnTrichloroethene TCE12-Dichloro roaneBromihlromehn2-hlrhlvinlhrcis-13-Dichloro roenetrans-13-Dichloro roene11-TrihlrhanTrhlrhnPEDibromochlorom ethaneChlorobenzene Brmfrm1122-Trahlrohan13-Dichlorobenzene 14-Dichlorobenzene 12-Dichlorobenzene Concentration (yg/L)<0.50<3<6<4<0.<0.5<0.5<2Reporting Detection LimitIL0.50.50.5DataQualifier(s) LOCKHEEDANALYTICALSERVICES VOLATILEORGANICANALYSISRESULTSGC/PIDANALYSESUSINGIVlETHOD8020linmIID:BLANKDeliee:NADateAnalzed:04-JAN-94 Matrix:WATERAnalticalBatch¹:122093-801020-0-3 LALmlID:AD17DRiv:NADilutionFactor:1QCBatchID:122093-801020-0-3 TFTBFBrrRvr10299QCLimi70-12075-120BenzeneTInConstituent Concentration /L<0.5Reporting Detection Limit/L0.5DataQualifier shlrnznEthIBenzenem-Xlene-XIn1-Dihlrnzn14-Dichlorobenzene 12-Dichlorobenzene <2<2<2LOCKHEEDANALYTICALSERVICESt,'Z AQUEOUSMATRIXSPIKEDATASUMMARYFORVOLATILEORGANICANALYSISUSINGEPAIVIETHOD8010ClientSampleID:MATRIXSPIKE/DUPLICATE Analytical Batch4:.122093-801020-0-3 QCBatchID:122093-801020-0-3 LALSampleID:L1012-7DateAnalyzed: 05-JAN-94 Constituent 1,1-Dichloroethene Trichloroethene Chlorobenzene SpikeAddedlpg/L)151515SampleConcentration tpg/L)NDNDNDIVlatrixSpikeConcentration lyg/L)7.3014.512.6Recovery499784QCLimitsRecovery28-16735-14638-150QCLimitsConstituent 1,1-Dichloroethene Trichloroethene Chlorobenzene SpikeAddedlyg/L)151515MatrixSpikeDuplicate Concentration (pg/L)11.414.512.6Recovery769784RPD43+RPD202020Recovery28-16735-14638-150LOCKHEEDANALYTICAL SERVICESIl AQUEOUSMATRIXSPIKEDATASUMMARYFORVOLATILEORGANICANALYSISUSINGEPAMETHOD8020ClientSampleID:MATRIXSPIKE/DUPLICATE Analytical Batch¹:122093-801020-0-3 QCBatchID:122093-801020-0-3 LALSampleID:L1012-7DateAnalyzed: 05-JAN-94 Constituent BenzeneTolueneChloroben zeneSpikeAdded(yg/L)151515SampleConcentration (yg/L)NDNDNDMatrixSpikeConcentration (yg/L)12.912.512.6Recovery868384QCLimitsRecovery39-15046-14855-135QCLimitsConstituent BenzeneTolueneChlorobenzene SpikeAddedlyg/L)151515MatrixSpikeDuplicate Concentration (yg/L)12.412.012.6Recovery838084RPDRPD202020Recovery39-15046-14855-135LOCKHEEDANALYTICAL SERVICES12 LCSDATASUNIMARYFORVOLATILEORGANICANALYSISUSINGEPAMETHOD8010ClientSampleID:LCSAnalytical Batch¹:122093-801020-0-3 QCBatchID:122093-801020-0-3 LALSampleID:AD5177DateAnalyzed: 04-JAN-94 Constituent 1,1-Dichloroethene Trichloroethene Chiorobenzene SpikeAdded(yg/L)151515BlankConcentration I/Ig/L)NDNDNDLCSConcentration Iyg/L)9.115.012.2Recovery10081QCLimitsRecovery28-16735-14638-150LOCKHEEOAIVALV7'ICALSERVICES LCSDATASUIVIMARY FORVOLATILEORGANICANALYSISUSINGEPAMETHOD8020ClientSampleID:LCSAnalytical Batch//:122093-801020-0-3 QCBatchID:122093-801020-0-3 LALSampleID:AD5177DateAnalyzed: 04-JAN-93 Constituent BenzeneTolueneChlorobenzene SpikeAddedIpg/L)151515BlankConcentration (yg/L)NDNDNDLCSConcentration (/Ig/L)14.914.114.4Recovery999496QCLimitsRecovery39-15046-14855-135LOCKHEEDANALyTICAL SERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260Page1of2linamIID:BLANKDateCollected: NAMatrix:WATERAnliIBh¹:114-2-F2QCBatchID:011094-8260-F2 LALmleID:AD214DateReceived: N/ADateAnalzed:11-JAN-94 DilinFr:1SURROGATE RECOVERY12-Dihlrhn-4Tlen-84-Bromofluorobenzene 1294QCLimits7-11486-115Constituent Chloromethane VinIhlriBromomhnChloroethane Trichlorofluoro methaneAn11-DihlrhnCarbonDisulfide MethleneChlorideran-12-DihlrohnVinIA11-Dichloroethane 2-Butanone i-12-Dihlrhnhlrfrm111-Trichloroethane CarbonTetrachloride 12DihirhnBenzneTrichloroethene TCE12-Dichioro roaneBromihlromhn2ChlrhIVinIhr4-Meth1-2-entanonecis-13-Dichloro roeneTolnrn-1-Dihlrrn2-Hexanone 112-Trichloroethane Tetrachloroethene PCEConcentration /L<5<5<5<5<5<5<10<5<5<5<5<2<10<5<10<5<5Reporting Detection Limit/L101010DataQualifier sLOCKHEEDANALYTICALSERVICESCqg VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260Page2of2ClientSamleID:BLANKLALSamleID:AD5214Constituent Dibromochloromethane hlrnzenEhlnznm-Xleneo-XlenernBrmfrm1122-Tetrachloroethane 13-Dichlorobenzene 14-Dihlrnzn12-Dichlorobenzene Concentration IL<5<5<5<5<5Reporting Detection LimitILDataQualifier sLOCKHEEDAIVALYTICAL SERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260TENTATIVELY IDENTIFIED COMPOUNDS ClientSampleID:BLANKDateReceived: N/AMatrix:WATERAnalytical Batch:011094-8260-F2 LALSampleID:AD5412DateAnalyzed: 11-JAN-94 DilutionFactor:1QCBatchID:011094-8260-F2 NONETentatively Identified CompoundEstimated Concentration (yg/L)(10Retention Time(minutes) 0.00DataQualifierls) LOCKHEEDANALYTICALSERVICESr.6 WATERMATRIXSPIKEDATASUMMARYFORVOLATILEORGANICANALYSISUSINGEPAMETHOD8260ClientSampleID:MATRIXSPIKE/DUPLICATE Analytical Batch:011294-8260-F2 QCBatchID:011294-8260-F2 LALSampleID:L968-27MS/MSD DateAnalyzed: 124AN-94Constituent 1,1-Dichloroethene BenzeneTrichloroethene TolueneChlorobenzene SpikeAdded(yg/L)5050505050SampleConcentration (yg/L)1.21.41.21.7MatrixSpikeConcentration (yg/L)51525254Recovery9999102101106QCLimitsRecovery62-12467-12760-12072-13268-128Constituent 1,1-Dichloroethene BenzeneTrichloroethene TolueneChlorobenzene SpikeAdded.(yg/L)5050505050MatrixSpikeDuplicate Concentration (yg/L)49505153Recovery96999899104RPDRPD14141313QCLimitsRecovery62-12467-12760-12072-13268-128LOCKHEEDANALYTICALSERVICES2( WATERLCSDATASUMMARYFORVOLATILEORGANICANALYSISUSINGEPAMETHOD8260ClientSampleID:LCSAnalytical Batch:011094-8260-F2 QCBatchID:011094-8260-F2 LALSampleID:AD5213DateAnalyzed: 11-JAN-94 Constituent 1,1-Dichloroethene BenzeneTrichloroethene TolueneChiorobenzeneLCSRecovery100108110117QCLimitsRecovery62-12467-12760-12072-13268-128LOCKHEEDAIVALYTICALSERVICES SEIVllVOLATILE ORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270ClienamIID:BLANKDateCollected: N/AMatrix:WATERAnliIBh¹:1114-27-BQCBatchID:8270-SEMIVOLATILES-3964 LALSamIeID:94MBDateReceived: N/ADilutionFactor:1DExr:4-AN-4DateAnalzed:11-JAN-94 P1f2URRGATERECOVERYI2-FluorohenolPhenol-d, Nitrobenzene-d, 2-Fluorobi henI246-Tribr mhnIp-Terphenyl-d 4327666486CLimi21-10010-9435-11443-1161-1233-141CnsienPhenolbis2-Chloroeth Iether2-hirhnl1-Dihlrnzn14-Dichlorobenzene BenzIalcohol12-Dihlrnzn2MhIhnIbis2-Chioroiso roIether4-MethIhenolN-Nir-Di-n-rIminHxhlrhnNitrobenzene Isohorone2-NirhnI24-DimhIhenIBenzoicacidbis2-Chloroethox methane24-DichlrhnI'124-TrihlrnznNahthalene4-Chloroaniline Hexhlrinc4-hlr--mhIhnI2-MethInahthaleneHexachloroc cloentadiene Concentration /L<10<10<10<10<10<10<10<10<10<50<10<10<10<10<10<10<10Reporting Detection Limit/L101010101010101050101010101010DaaualifierLOCKHEEDAIVALYTICALSERVICES p,t SEIVIIVOLATILE ORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270ClientSamleID:BLANKLALSamfeID:3964MBP2f2Constituent 24-TrihlrhnI24-TrihlrhnI2-Chlorona hthalene2-Nitroaniline DimhIhhIAnhhln26-Dinitrotoluene 3-Nitroaniline Anhhn24-DinirhnI4-NitrohenolDibenzofuran 24DinirInDihIhhIe4-ChlorohenI-henletherFluorene4-Nirnilin4-Dinir-2-mhIhnIN-Nitrosodi henlamine4-BromohenI-henletherHxhlrnznPnhlrhnlPhenanthrene Anthracene Di-n-uIhhIFlrnhnPreneButIbenzIhthalate'-Dihlrnziin8nznhrnChrsenebis2-EhIhexIhhalateDi-n-IhhIBnzflrnhnBenzokfluoranthene BenzoareneInn12-rnDinzhnhrnBenzohierleneCarbazole Concentration IIL)<10<25<10<10<25<2<25<10<10<10'2<2<10<10<10<10<10<10<2<101.3<10<10<10<10Reporting Detection Limit(IL)1025102525101010101010101010101010101010DataQualifierls) LOCKHEEDANALYTICAL SERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8270TENTATIVELY IDENTIFIED COMPOUNDS ClientSampleID:BLANKDateReceived: N/AMatrix:WATERAnalytical Batch:011194-8270-B LALSampleID:3964MBDateAnalyzed: 11-JAN-94 DilutionFactor:1QCBatchID:8270-SEMIVOLATILES-3964 NoneTentatively Identified CompoundEstimated Concentration iyg/LIRetention Timelminutesl DataQualifier(s) LOCKHEEDANALYTICAL SERVICES SEIVIIVOLATILE ORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270P1f2linmiID:LDateCollected: N/AMatrix:WATERAnalialBh¹:1114-27-BQCBatchID:8270-SEMIVOLATILES-3964 LALmIID:4DateReceived: N/ADilutionFactor:1DExra:04-AN-4DateAnalzed:11-JAN-94 2-FluorohenolPhenol-d, Nitrobenzene-d, 2-Fluorobi henIRRATERECOVERY37266060Limi21-10010-9435-11443-116246-TriromhnIp-Terphenyl-d 8033-141PhenolninConcentration L40Reporting Detection Limit/L10Dbis2-Chloroeth Iether2-hlrhnl1-Dihlrnzn14-Dichlorobenzene BenzIalcohol12-Dihlrnzn2-Mhlhnlbis2-Chloroiso roIether4-MethIhenolN-Nir-Di-n-rIminHxhlrhnNitrobenzeneIsohorone2-NirhenI24-DimehIhnolBenzoicacidbis2-Chloroethox methane4-DihlrhnI124-TrihlrnznNahhalene4-Chloroaniline Hxhlrin4-hlr--mhlhnl2-MehInahthaleneHexachloroc cloentadiene <1039<10<10<10<10<10<50<10<10<10100<10<1010101010101010101010501010101010LOCKHEEDANALy'TICAL SERVICES SEMIVOLATILE ORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270ClientSamleID:LCSLALSamleID:3964LCSPa2f2Constituent 24-TrihlrhnI24-TrihlrhnI2-Chlorona hthalene2-Nitroaniline DimhIhhIAnhhln26-Dinitrotoluene 3-Nitroaniline Anhhn24-DinirhnI4-NitrohenolDibenzofuran 24-DinirInDihIhhI4-ChlorohenI-henletherFluorene4-Nirnilin4-Dinir-2-mhIhnIN-Nitrosodi henlamine4-BromohenI-henletherHxhlrnnPnhlorhnIPhenanthrene Anthracene Di-n-IhhIFluornhnPreneButIbenzIhthalate'-DihirnziinBnznhrnChrsenebis2-EthIhexIhthalateDin-IhhI8nzobfluoranhenBenzokfluoranthene BenzoareneInn12-rnDibnzhanhracnBenzohierleneCarbazole Concentration IL)<10<10<25<10<25<222<10<10<10<2-<2<10<1017<10<10100<10<2<10<10<10<10<10<10<10<10Reporting Detection LimitIIL)102510251025101010101010101010101010101010101010DataQualifier(s) LOCKHEEDANALYTICAL SERVICES SEIVIIVOLATILE ORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270Pae1f2linmIID:DateCollected: NADPLAmlID:4DPDateReceived: N/AMatrix:WATERAnIiIBh¹:1114-27-BQCBatchID:8270-SEMIVOLATILES-3964 DilutionFactor:1DaExred:4-AN-4DateAnalzed:11-JAN-94 2-FluorohenolPhenol-de Nitrobenzene-d, RROATERECVERY312462Limi21-10010-9435-1142-Fluorobi henI24-TrirmhnIp-Terphenyl-d,4 628543-1161-1233-141PhenolninConcentration L39Reporting Detection LimitL10Dbis2-Chloroe hIether2-hlrhenI1-Dihlrnzn14-Dichlorobenzene BenzIalcohol12-Dihlrnzn2-MhIhnIbis2-Chloroiso roIether4-MethIhenolN-Nir-Di-n-rIminHxhlrhnNitrobenzene Isohorone2-NirhnI24-DimhIhnIBenzoicacidbis2-Chloroethox methane24DihlrhnI*124-TrihlrnznNahthalene4-Chloroaniline Hxhlrin4-hlr--mhlhnl2-MethInahthaleneHexachloroc cloentadiene <1041<10<10<1074<10<10<10<50<10<10<10<10<101010101010101050101010~1010LOCKHEEDANALYTICAL SERV/CES SEIVlIVOLATILE ORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270ClientSamIeID:LCSDUPLALSamleID:3964LCSDUPP2f2Constituent 24-TrihlrhnI24-TrihlrhnI2-Chlorona hthalene2-Nitroaniline DimhlhhlaAnhhln26-Dinitrotoluene 3-Nitroaniline Aenhhn24-DinirhnI4-NitrohenolDibenzofuran 24-DinirolnDihIhhI4-ChlorohenI-henletherFluorene4-Nirnilin4-Dinir-2-mehIhnIN-Nitrosodi henlamine4-BromohenI-henletherHxhlrnznPnhlrhnolPhenanthrene Anthracene Di-n-IhhIFlranhnPreneButIbenzIhthalate'-DihlrniinBnznhrnChrsenebis2-fthIhexIhthalateDi-n-IhhI8nzflrnhnBenzokfluoranthene BenzoareneInn1-rnDinzhnhranBenzohierleneConcentration IL)<10<25<10<10<25<235<10<10<10.<2<2<10<10<10<10100<10<10<10<10<10<10<10Reporting Detection LimitIIL)101025251010101010101010101010101010101010DataQualifierls) LOCKHEEDANALYTICAL SERVICES SEMIVOLATILE ORGANICSQUALITYCONTROLDATASUMMARYFORMETHOD8270ClientSampleID:LCSAnalytical Batch¹:011194-8270-B QCBatchID:8270-SENIIVOLATILES-3964 LALSampleID:3964LCS/LCS DUPDateAnalyzed: 11-JAN-94 'CLimitsPhenolCompoundSpike%Recovery27SpikeDuplicate %Recovery26RPDRecovery5-112RPD422-Chlorophenol 1,4-Dichlorobenzene N-Nitroso-di-n-propylamine 1,2,4-Trichlorobenzene 4-Chloro-3-methylphenol Acenaphthene 4-Nitrophenol 2,4-Dinitrotoluene Pentachlorophenol Pyrene573978456868811015341745266692379121101144223-13420-124D-23044-14222-14747-145D-13239-13914-17652-11540283828423150385031LOCKHEEDANALYTICAL SERVICES" PESTICIDE ANALYSESRESULTSBYGC/ECDUSINGMETHOD8080FORCOOKNUCLEARPLANTClienSamleID:METHODBLANKDColleced:NADateExtracted: 04-JAN-94 Matrix:WATERAnalticalBatch¹:012094-8080-A-1 LALSamieID:3965MBDaeReeiv:NADateAnalzed:21-JAN-94 DilutionFactor:1QCGrouID:8080PEST/PCBS 3965SURROGATE RECOVERY0QCLimitsTCMXDCB46"2360-15060-150A-BHCB-BHCConstituent Concentration /L<0.05Reporting Detection Limit/L0.05DataQualifier(s) G-BHCD-BHCHEPTACHLOR ALDRINHEPTAHLREPOXIDEG-CHLORDANE ENDOSULFAN IA-CHLORDANE 44'-DDE44'-DDTDIELDRINENDRINENDOSULFAN II44'-DDDENDRINALDEHYDEENDOSULFAN SULFATEMETHOXYCHLOR TOXAPHENE PCB-1016PCB-1221PCB-1232PCB-1242PCB-1248PCB-124PCB-1260TECHNICAL CHLORDANE MIREXTCMX-tetra-chloro-meta-xylene DCB-Deca-chioro-biphenyl <0.05<0.05<0.<0.<0.05<0.05<0.<0.1<0.1<0.1<0.1<0.1<0.1<0.1<0.<5<2<0.10.050.050.050.050.10.10.10.1<0.1LOCKHEEDANALYTICAL SERVICES PESTICIDE ANALYSESRESULTSBYGC/ECDUSINGMETHOD8080FORCOOKNUCLEARPLANTClienSamleID:LABCONTROLSAMPLEDaClledNADateExtracted: 04-JAN-94 Matrix:WATERAnalticalBatch¹:012094-8080-A-1 LALSamleID:3965LCSDeRecive:NADateAnalzed:21-JAN-94 DilutionFactor:1QCGrouID:8080PEST/PCBS 3965SURROGATE RECOVERYooTCMXDCB6029QCLimits60-15060-150A-BHCB-BHCG-BHCD-BHCConstituent Concentration IL<0.050.88<0.05Reporting Detection LimitIL0.050.00.05DataQualifier(s) HEPTACHLOR ALDRINHEPTACHLOR EPOXIDEG-CHLORDANE ENDOSULFAN IA-CHLORDANE 44'-DDE44'-DDTDIELDRINENDRINENDOSULFAN II44'-DDDENDRINALDEHYDEENDULFANSLFATEMETHOXYCHLOR TOXAPHENE PCB-1016PCB-1221PCB-122PCB-1242PCB-1248PCB-124PCB-12TECHNICAL CHLORDANE MIREXTCMX-tetra-chloro-meta-xylene DCB-Deca-chloro-biphenyl 0.70<0.05<0.05<0.05<0.<0.11.851.811.91<0.1<0.1<0.1<5<2<0.10.050.050.050.10.10.10.10.10.10.1<0.1LOCKHEEDAIVALYTICAL SERVICESer 1 PESTICIDE ANALYSESRESULTSBYGC/ECDUSINGMETHOD8080FORCOOKNUCLEARPLANTClienSamleID:LABCONTROLSAMPLEDUPDColleced:NADateExtracted: 04-JAN-94 Matrix:WATERAnalticalBatch¹:012094-8080-A-1 LALSamIeID:3965LCSDDeReive:NADateAnalzed:21-JAN-94 DilutionFactor:1QCGrouID:8080PEST/PCBS 3965SURROGATE RECOVERYoTCIVIXDCB54"20QCLimits60-15060-150A-BHCB-BHG-BHCD-BHCConstituent Concentration /L<0.05.0<0.05Reporting Detection Limit/L0.050.0.05DataQualifier(s) HEPTACHLOR ALDRINHEPTACHLOR EPOXIDEG-CHLORDANE ENDOSULFAN IA-CHLRDANE44'-DDE44'-DDTDIELDRINENDRINENDOSULFAN II44'-DDDENDRINALDEHYDEENDOSULFAN SULFATEMETHOXYCHLOR TOXAPHENE PCB-1016PCB-1221PCB-1232PCB-1242PCB-1248PCB-124PCB-120TECHNICAL CHLORDANE MIREXTCMX-tetra-chloro-meta-xylene DCB-Deca-chloro-biphenyl 0.66.5<0.05<0.055<0.11.801.851.94<0.1<0.1<0.5<5<2<0.10.050.050.050.050.10.10.10.10.10.10.10.5<0.1LOCKHEEDANALYTICAL SERVICES PESTICIDES QUALITYCONTROLDATASUMMARYFORMETHOD8080ClientSampleID:LABCONTROLSAMPLEAnalytical Batch4':012094-8080-C-1 QCBatchID:8080PES/PCBS3965LALSampleID:3965LCSDateAnalyzed: 21VAN-94Matrix:WATERSURROGATE RECOVERY(%)TCMXDCB6029"QCLimits60-15060-150Constituent G-BHC(Lindane) Heptachlor Aldrin4,4'-DDTDieldrinEndrinSpikeAdded(yg/L)LCSConcentration (yg/L)0.880.700.601.851.81Recovery887060929096QCLimitsRecovery56-12340-13140-12038-12752-12656-121LOCKHEEDANALYTICAL SERVICES58 PESTICIDES QUALITYCONTROLDATASUMMARYFORMETHOD8080ClientSampleID:LABCONTROLSAMPLEAnalytical Batch¹:012094-8080-C-1 QCBatchID:8080PEST/PCBS 3965LALSampleID:3965LCS/LCSDDateAnalyzed: 21-JAN-94 Constituent G-BHC(Lindane) Heptachlor Aldrin4,4'-DDTDieldrinSpikeAdded(yg/L)SampleConcentration (yg/L)MatrixSpikeConcentration (yg/L)0.880.700.601.851.811.91Recovery88'7060929096QCLimitsRecovery32-12734-11142-12225-16036-14630-147Constituent G-BHC(Lindane) Heptachlor Aldrin4,4'-DDTDieldrinEndrinSpikeAdded(yg/L)MatrixSpikeDuplicate Concentration (yg/L)0.880.660.551.81.851.94Recovery886655909397RPDRPD152022271821QCLimitsRecovery32-12734-11142-12225-16036-14630-147LOCKHEEDAIVALYTICALSERVICES58 0 METALSQCDATASUMMARY'LALBatchID(s):.1220.:im QCSamleAnalses'.,'onstituent .AluminumAntimonArsenicBariumBeIliumBoronCadmiumChromiumCobaltCoerIronLeadManesiumMananeseMercuMolbdenumNickelSeleniumSilverSodiumThalliumTlnTitaniumVanadiumZincClient"Sample'IDTRSTRSTRSTRSTRSTRSTRSTRSTRSTRSTRSTRSTRSTRSTRS-QATRSTRSTRSTRSTRSTRSTRSTRSTRSTRSLALSample,ID;L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-14L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13DateA'nalyxed 01-20-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-20-9401-27-9401-07-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-27-9401-20-9401-20-9401-27-94ReagentBlank(mIL)<0.20<0.060<0.010<0.20<0.005<0.20<0.005<0.010<0.050<0.025<0.10<0.003<5.0<0.015<0.0002<0.20<0.040<0.005<0.010<5.0<0.010<0.20<0.20<0.050<0.020Duplicate P,.recision (%RPD)MatrixSpike-Recovery"(%)10410411074978810098969710184102981061069413798103104NA10794~Ibw~NATheRPDcannotbecomputed, becausethesampleortheduplicate concentration wasbelowtheReporting Detection Limit.Thematrixspikerecoveryisnotreported. Thesampleconcentration wasgreaterthanfourtimesthespikinglevel.Titaniumisnotincludedinthespikingsolution. LOCKHEEDANALYTICALSERVICES l'0~~RRRRHIRRH ~lIyPJ..~~~ >iIiAiA.II'j")A)f)t,el'<,'Il"I.IA)bP. .<IIAI<<.'.P;Ah:Al:I)lIl<I')tlatI'AQ<)I')I,I,I.II:>'pII'I'i<):Ii;I')A)'J'li)(I('I'I'i ):i'!('(iI')ll(',~(I,Aii'>I;<il'It<<,IiiI<r<<)I,<((<'I<!I)i",I,i,I.<i<'Ii)<(.":I)'("ll(iI'IV(f:<(i(~',.IA('("I.)< II<('.VIAIA~I)'Q Vl~lIIII.()V.VVX()I(')'I:<'(Ji'A)I'":I.d ~))'.I1Ii(<)<(l.'I.I'l)I'I~)I',(<')IlllilIi%:IIV:i),l P(.(i)I.(~(< 0 ~'0'<v<.5,).imp3)j'I'!I"j)j-l'/sXI--I,'//J.".I.'4J.X>'"l'-Ili')J.-.Lu"'5'I;I;/ljA-J.uuJ.-l:juxh-J.uuX5-:-l:5:ji'II.:I'Ii') J.u/Il:j.">x)>"IubXj'-I.:J:)i)l'i-lubI'-l:5'/I'u-J.3uXI--I:5:5JJA-iudl'h-l:5JJJAl40'-l/I<)J.4Ll'II.I'h-IRANN0-l'I'/hlJ-J.5'/)=I)'-I.:)ilHC-JulW-I.'5'/HLi-"VuKA-..b'J:H-'2:jr U-'/uugpAt1-"/I5,I<i,Il)>'Ii'II(>!ilI(il>)I'IP(I'.<<J)<>0:l~'/I,/I',!'/.I')i'<)r'5/I;,I(i/,'I II,lf>.'5~'J:I(>>(>>/(>>>)i~ReIJwlf>i'l',i(>>..0J)2'J~I5'jHJ..()0rl:55'Nd~(>>0/!'/0l,'//I;Iu/)'/();Ili">0/II'.I/I4J/>))'r'<>'.)f>J0/;I:..0/ b<>I.,I>.')I:(>>J(>>'...I",>\4:).u:pl)"J<>J)0.',<;/l'I>.'I'Iw~l,Irj4I/5JI.(I,l".'/I,I.)<>:5').'5 I,-;/'/>)<>'/'.I.7<)(>>0':);<J')lJ:5.le(l;IJ;!0I.<)<>.I,:5gIJ<1IIA(I>I1/II),)l~I'.)l;.h-vuI~/:"i'J)'Vul/'/<)lh-OuI-vu<>I'Jl)h-0'/ 5-0(>>/;J-0'/l'Jr<4".>h-Ou J"(J::::I:-0u'-:5'I'/:Sh-Vu '>I"'llew J:"Oul~2'I'/f>h-0'/ 5I"l(lIvu')~'/i!.p'/h-Q/("':>J'/):- 0/l~5'/II'0'/I'/"IIII,'-vu('ilpuh-vb J.'/I:(>>/II-.Oul.'5'/<)iII."-vuJ~".();'5;-Oble'/<>0',/I-0~JvJ',>',>l<J: ~~0(>l-:5'IllI-:-Ou')'IJJ5'-Vul.I>:5:8;.'h-Vu 0//~(>>5~-vbI.(:5>n):-ou J-vb/)/,'5 -0/'I-<>42'/h-ou w'<>>II0J>)5'u'I-:5."))5'/h-Vu I-(:/"'.)5 -Ou<>~(')0/Ih-Vu 5-'/QI'5:,--Qu r(I.Luh-Ou'<~">'/'.)J):.-Ou'I-'Jbo<)h-Ou"">I"p'/5:-vu ).):l>Uh-OuI<~/I,'>;IIJ-Qu 11II)),AII>hl Ilk'e>~e~e,,'eIcr>r',eWl'l,Ple(l>(repeal))e)IeIIJ)5'e(}()/e)(Ir)>crt>I>.'e"<:etyI~<~eISQP>>e'>e,lIepe}Ietee(}e~>J>>elIeel-'IHA-;!>>!HA-"<<IL;I..-:I'Ir,-tvAt(-'II.~5\'-<<IbL'K-)\(1H'-b<<tl1H'-:)I>I"I.I-V'/L'lJ-:)il k>h-')~3L'.l-80t'II-b4Hl-b:)ZH-ba'/.H-b")i'I 8h'-'/5AU-'/r>IJH-8'<<IJK->>5<<tl(K-UvV)K-'I:)i'I >>-Ubi(->>I')i1 RK-8'/)iA'-~ledKCJ-88X-I'58Rt5-8")l1I.J-')0UH-DlX-"J"X-')IH8-'J<<tHI5-"):)ZK-i)bHLC-~)'/'/.H-'2'/l1II-')')'I:L'-'JiJ(1KU-(0:1HH-l0+KI.J-l0')HU-I.vbL;I)-l0')Ab-lIvl1UH-I.\:IJJCIl.';3I>e',I.'>>Ir)IJt'.~e0'<<0'I'/~:50')~'/t'.'/.<<I~~Tee~pI.'/.'<<0JV.ly<<!0..4:J.'<<0J:)'/.J.l~'<<>>P<<ll>.,5P;I<<!'/.)'<<ep'/./.l:I,e>e(>>"i'),l<<I~l)I)rl).J'eiIi("I"I)>(ez~s'Lg)<<e'/'/pCi'.Il'!'/>>t.)>>IJ"'bt:J<<,'(eVt'J\'<<!"):I'r)<<t II,V',>J:5)!0.,0~I'I'll).'/:))'!'!~0(>>'5I.O~'/I)J0'I'IlII<<'t')I;cr,;,Pl)V I.'t:5(.CI>>tIJ)e),;>'<<!'t5'I'!('<<)~(>>l):))').lv~~e~bee'<<e!I'Il.')0'>J'.'I'Il:)l,\!J;)J;IP'.I'.)I)')<<IV<<!P',it,rl)r>.5.!It"Ib~0)l!J:lr>.0 l50"5.t'tl".:)'/.".5>>t )0<<.'r.;:0

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V'/:I~05")\I'-0'/5.t"/(t'J00l.:5'5<<lr) I;-08'/.'.I'/tl'<<! J:,"Vb't.0<<!'/'/I;-08 b~Ib(>bl~-'087')8")I--0'/t';.!I"IJ'"0'/'!.')l'/'/h-0'/ l~l>b<<CbJ:" 08l'I't<<")I'-OUr."'t".<J "VU:5.>>I')ldh-0'/I'I'/t"IJ'-OUl'!')b'II.;-08~(/'.IJ:-08l0')ll'/h-OU '/,;e<<;bt:I:-08\.:I'!bith-0'/ 5,!I'I))I"0'/')et')'9h-0'/ J,(>>r.,<<CIJ:-08l~:)'l';)'" OU:!~<<!(>>"e(>>I:-'08 .'i.Halliburton NUS+++C0RP0RATI0NDUALITYCONTROLREPORTSUPPLEMENTAL INFORMATION NUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January11,1994ReportNo.:00018818Section8Page1------------ SAMPLEPREPARATION------------

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SAMPLEANALYSIS-----------------.- TESTLR-LNCODEBATCHMETHODDATE/TIHE ANALYSTLR-METNODDATE/TIME ANLSANALYSTBATCHINSTRUMENI'AMPLE ID:SEWAGEPLANTNUSSAMPLENO:P02588381ASNW2303602-4'.303-JAH-94 0730RAW2105023039NA3I61023014NA4I49023050NAR2-200.707-JAN-94808JWC03-50703-JAN-93 700DB02-160.230.DEC-93 700EDB02-150.103-JAN-93 715DB03560000LRMethodLiterature Reference 02EPA-Methods forChemicalAnalysisofWater&Wastes,1984.03APNA-Standard MethodsfortheExamination ofWaterandWastewater, 16theditionR2Inductively CoupledPlasma-Atomic EmissionSpectrometric MethodforTraceElemenSAMPLEID:OIL/WATER SEPARATOR 1G122W2298705-60829-DEC-93 0800PS3I10623061NA4I68023097NA5I49023050NANUSSAMPLENO:P02588392298700005-60830.0EC-93 1146JC02-415.104-JAN-94 1000JJH02-413.103-JAN-93 1230TM02-150.103-JAN-93 715DBLRMethodLiterature Reference 02EPA-Methods forChemicalAnalysisofWater8Wastes,1984.05EPA-40CFR136,October26,1984. 4'alliburton NUS++C0RP0RATI0NOUALITYCONTROLREPORTSURROGATE STANDARDRECOVERYNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(4'12)747-2580FAX:(412)747-2684January11,1994ReportNo.:00018818SectionCPage1TESTSURROGATE LNCODECOMPOUNDPERCENTRECOVERYACCEPTANCE LIMITSREFLNSAMPLEID:OIL/WATER SEPARATOR NUSSAMPLENO:P0258S392SPCBWPCBSURROGATE nonachtorobiphenyt

1'Halliburton NUSCORPORATION QUALITYCONTROLREPORTLABORATORY CONTROLSAMPLERECOVERYNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January11,1994ReportNo.:00018818SectionDPage1TESTCODEDETERMINATION PERCENTRECOVERYDUPLICATE RECOVERYRPDACCEPTANCE LIMITSBATCH:23036SAMPLEID:LabControlSampleASNNTin,Total(Sn)BATCH:23039SAMPLEID:LabControlSample92'NUSSAMPLENO:P0259637NANUSSAMPLENO:P0259643I050BOO(02)-5dayBOD(02)-5day¹2BOD(02)-5day¹3BOO(02)-5day¹4101~79499104NANANANABATCH:23050SAMPLEID:LabControlSampleHUSSAMPLENO:P02596581490pHpH¹2pH¹3100.510099.1NANANABATCH:23061SAMPLEID:LabControlSampleHUSSAMPLENO:P02596731106Carbon,Organic-.Nonpurgeable Carbon,Organic-Nonpurgeable ¹2Carbon,Organic-Honpurgeable ¹311096.3106HANANABATCH:23097SAMPLEID:LabControlSampleI680OilandGrease,Gravimetric 84.8HUSSAMPLENO:P025972883.81.19 .'iHalliburton NUS++++C0RP0RATI0NQUALITYCONTROLREPORTMETHODBLANKDATANUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January11,1994ReportNo.:00018818SectionEPage1TESTCODEDetermination RESULTUNITSBATCH:22987SAMPLEID:MethodBlankNUSSAMPLENO:P0259059G122'NPCBANALYSISPCB-1016PCB-1221PCB-1232PCB-1242PCB-1248PCB-1254PCB-1260<0.50<0.50<0.50<0.50<0.50<1.0<1.0ug/Lug/Lug/Lug/Lug/Lug/Lug/LBATCH:23014SAMPLEID:MethodBlankHUSSAMPLEHO:P0259602I610Solids,Suspended at103CBATCH:23036SAMPLEID:MethodBtank<10mg/LNUSSAMPLENO:P0259638ASNMTin,Total(Sn)<0.1mg/LBATCH:23039SAMPLEID:MethodBlankI050BOD(02)-5dayBATCH:23061SAHPLEID:HethodBlank0.63mg/LNUSSAHPLENO:P0259674NUSSAHPLENO:P02596441106Carbon,Organic-Nonpurgeable <1mg/LBATCH:23097SAMPLEID:MethodBlankHUSSAHPLENO:P02597291680OilandGrease,Gravimetric <3mg/L '.Halliburton NUSIaarC0RP0RATI0NQUALITYCONTROLREPORTDUPLICATE ANDMATRIXSPIKEDATANUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(4'12)747-2580FAX:(412)747-2684January11,1994ReportNo.:00018818SectionFPage1PREPBATCH:23050HUSSAHPLENO:P0258838TESTDETERMINATION 1490pHORIGINALDUPLICATE RESULTRESULT6.86'7RANGE/UNITSRPD~02UNITSHSMS%RESULTRCVRYPREPBATCH:23014HUSSAHPLEHO:P0258810TESTDETERMINATION 1610Solids,Suspended at103CORIGINALDUPLICATE RANGE/HSHSHRESULTRESULTUNITSRPDUHITSRESULTRCVRY1213mg/L1mg/LPREPBATCH:23036NUSSAMPLENO:P0259167TESTDETERMINATION ASNlJTin,Total(Sn)ORIGINALDUPLICATE RESULTRESULT0.40.4RANGE/UNITSRPOmg/L1.98UNITSmg/LRESULT2.28RCVRY94.0HSMS/.PREPBATCH:23039HUSSAMPLENO:P0258780TESTDETERHINATIONI050BOD(02)-5dayORIGINALDUPLICATE RESULTRESULT53.81RANGE/UNITSRPDmg/L1UNITSmg/LHSMSyoRESULTRCVRYPREPBATCH:23061HUSSAMPLENO:P0258851TESTDETERHINAT IONI106Carbon,Organic-Nonpurgeable ORIGIMALDUPLICATE RESULTRESULT76.86RANGE/UNITSRPDmg/L3.82UNITSmg/LHSHSKRESULTRCVRY57.7101 '.HallibuIIton NUS+++C0RP0RATl0NINUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January11,1994ReportNo.:00018818SectionHPage1QUALITYCONTROLREPORTMATRIXSPIKEANDMATRIXSPIKEDUPLICATE DATAANLSBATCH:22987NUSSAMPLENO:P0258792TESTG122WPCB-1242G122WPCB-1260DETERMINATION MSRESULT4'74.T5MSDRESULT4.55'.73UNITSug/Lug/LMSPCTMSDPCTRPDRECOVERYRECOVERY0.49191095950' NPDESSTORMWATERDRAINAGEPERMITAPPLICATION D.C.COOKNUCLEARPLANTONECOOKPLACEBRIDGMAN, MI49106 ELI I'ICCTCVII~~~VlITVr'"~(fill-inareasarespacedforeliterype,i.e.,12characrers/inch(.U.S,tHVIROHMCHTAI PIIOTCCTIOH AOBHCYriiniirlpplovro. ITITIII~Iv.rvrv'ITvrv rlpIVIITCI rrpllrrrVImvGENERALI.EPAI.D.NUMBRill).FACILITYAMEACILITY'AILINADDRESSVIFACIL'ITY 'OCATIONGENERALINFORMATION ConsolideredPemlireProgram()leadlhe"Generalinllriieilons" beforeIrarrrne.l PEASEPLCLABELINTHISSPACI.EPAI.D.NUMBERFIIID098647621 POCHBRALINSTRUCTIONS Itaprsprinted labelhssbeenprovided, affixltinthedesignated space.Reviewtheinform.~lioncarefully; ifsnyofItIsincorrect. crossthroughitsndenterthacorrectdataIntheappropriate fill-insrabelow.Also,ifsnyofthsplePrintsd dstsisabsent(dissre~rodi~leftofdi~labelspacelisledi~information distshouldsppasrl,pleaseprovideItInthaproperfill-insiss(s)below.Ifthelabells'compl~Iltandcorrect,youneednotcompleteItemsI,III,V,shdVl(ixceprVlBwfikhmustbecompleltd rsgerdless/. CompletesllRemsifnolabelhssbeenprovided. AetertotheInnrucllons tordetailedItemdescrip-tionssndforthelegalsuthorisations underwhichthisdatalscollected. II.POLLUTANT CHARACTERISTICS INSTRUCTIONS: CompleteAthroughJtodetermine whetheryouneedtasubmitanypermitapplication formstothaFPA.Ifyauanswer"yes"toanyquestions, youmustsubmitthisformandthasupplemental formlistedintheparenthesis fallowing thequestion, Mark"X"intheboxinthathirdcolumltifthesupplemental formisattached, Ifyouanswer"no"toeachquestion, youneednotsubmitanyoftheseforms.Youmayanswer"no"ifyouractivityisexcludedfrompermitrequirements; seeSectionCoftheinstructions. Seaalso,Section0oftheInstluctions fordefinitions ofbold-faced terms.SPKCIPICDUCSTIOHS ~OPTIapcclpicDUtsTIDNs ITVACIICroryCD0ATTACIICO ,IsIissscililvwhichcunenlvresulsinIscsrgcslowslsrsoftheU.S.olherahon Ihqtsdescribed inXAorBabove)2NForm2bIIisapropossciityoersnostascnInAorBshovelwhichwillresultin~discharge lowst~tthsUS7FRM2IA.Isthisfacilityspubliclyownedtreatment works8.Doesorwillthisfacility(eitherexist(nporproposcdl whichresuIIIinsdischarge lowatersofthsU.S.)includesconcentrated animalfadlhgoperation orIFORM2A)~qusslcanimalproduction facilitywhichresultsinadischarge lowssslsoftheU$2IFOAM28)~~I~~~XE.Doesorwillthisfacilitytress,store,ordisposeofhszsrI)ous wsnssfIFORM3)oyouorwiyouihleclslIissoilyshyproucwaterorotherfluidswhichsrabroughttothesurfaceinconnection withconventional oilornaturalgsspro.duction,injecttluidsusedforenhancedrecoveryofoilornaturalgss,orihjeC!fluidsforstorageofliquidhdrocsrbohst IFORM4)~5lllissciily~proposessssiohsry sourcew>>soneofthe28industrial categories listedinthein-structions sndwhichwillpotentially emit100tonspsryearofanyairpollutant regulated undertheCleanAirAclandIhaySffeCtOrbelocatedinsnsnsihmcnt arcs)IFORMSlIII.NAMEOFFACILITY15<<PD.C,COOKNUCLEARPLANTF.Doyouorwillyouinjectatthisfacilityindustrial ormunicipal effluentbelowtha.lowermost stratumcon-X~taining,withinonequartermileofthewellbort,underground sourcesotdrinkingwater?IFOAM4)H,Doyouorwillyouinjectstthisfacilitytluidsforspscislprocesses suchasminingotsulfurbylhsFraschprocess,solutionminingofminerals, insitucombus.tlonoffossilfuel,orrecoveryotgeothermal ensrgytIFORM4)~Ilisaciity~propnsiysourcewhicisNOToneottht28industrial categories linedintheInstructions andwhichwillpotentially emit250tonsperyearofanyeirpollutant regulated undertheCleanAirActsndmayaffectorbelocatedInansttalnmeIIS ~Ies)IFORM5)XXT~I~I~'lXIV.FACILITYCONTACTA,NAMtSITITLC(loll,(lNI,IallllelC2BAKERD.L.Fnvironmental AffairsDirectorB,I'HDNCfaTCCcodekno.l2194252118V.FACILITYMAILINGADDRESS3P0BOX60ASTRttTORP.OBOX4FORTWAYNE~.CITYORTOWNC,STATtD,ZIPCODCIN4680Vl.FACILITYLOCATIONASTRtCTIROUTCHOOROTHCRSPtCIPICIDtNTIPICR 5ONECOOK"PLACEBERRIENBlCOUNTYNAMt6BRIDGOINC.CITYORTOWNDSTATtClZIPCODS416EPAForm3610.1IRsv.104I0)CONTINUEONREVEASE TINEDFROMTHEFRNTVlf,SICCODES(4<ipit.Jnorderofpr(orlrvJ AoFltt5T911"""fyJSTEAMELECTRICPOriZR(specifyI~,SCCONOC.'rNIItO(specifyI7~~~i~VIII.OPERATORINFORMATION IC8NDIANAMICHIGANPOR0~IAoNAMC(specifyIO,FOURTH.IsthanamelistedInItemVIII.A~lathsownersK3YESC3NOsa,I~t~cSTATU5oForcRAToR(Enterthcapproprlatc lcncrIntothcanstrcrooxtlf-Other",spcclfy.l o.rNotte(areacodeano.l~aALS~STATEP~PRIVATEONECOOKPLACEULI(otherthanfcdcralorstateJ(specifyJ0~OTHER(IpeclfyJ PC,5TRCCT0tlF.OISOXA61665901~~I~I~~~~sBRIDGMANI,CITYORTOWN~e~I~I~'~IIsthefacilitylocatedonIndianlandstOYESCBNOaaX.EXISTINGENVIRONMENTAL PERMITSA.IIIois(Discharges toSurfaceWaterJigNMI00058275.UIC(underground In/cation ofFluldsl9U(Ho.rso(A4Emlsslons fromproposedSourcesJ'r~9PC.oTNcR(specifyI(IfyJFirPermit'applicat;i nsamatte(spealfyJ9R9~~~411'I'I~I~~~~~~~~I~XI.MAPAttachtothisapplication atopographic mapoftheareaextending toatleastonemilebeyondpropertybounderies. Themapmustshowtheoutlineofthefacility, thelocationofeachofitsexistingandproposedintakeanddischarge structures, eachofitshazardous wastetreatment, storage,ordisposalfacilities, andeachwellwhereitinjectsfluidsunderground. Includeellsprings,riversandothersurfacewaterbodiesinthemaparea.Seeinstructions forpreciserequirements. XII.NATUREOFBUSINESS(provide~aria(description TheCookNuclearPlantisa2130Mt4steamelectricgenerating stationsituatedin6*beltofsanddunesonthesoutheastern shoreofLakeMichiganbetweenStevensville andBridgman. Preparation ofthesiteforconstruction oftheplantbeganin1968.Unit1wasoperat-tionalin1975andUnit2in1978.XIII.CERTIFICATION (seeinsuvcdonsl IcertifyunderpenaltyoflawthatIhavepersonally examinedandamfamiliarwirhtheinformatlon submitted inthisapplication endallattachments andchat,basedonmyinquiryofthosepersonsimmediarely msponsible forobtaining theInformation contained intheapplication, Ibelievethattheinformation istrue,accurateandcomplete. Iamawarethatthemamsignificant penalties forsubmitting falseinformation, including thepossibility offineandimprisonment. AMcIsoFFIcIALTITLc(typeorprlnIIR.C.Menge,President 9SIGNATURC C,OATCOMMENTSFOROFFICIALUSEONLYCCEPAForm3510.1{Rav.1080)ReverserrrrlartarattireII9SS 'I Severalofthesectionsinthispermitapplication (Form2F)arecompleted viatheuseofattachments. Thesesectionsreference theappropriate attachment. Pleasecarefully readeachsectiontoavoidanyconfusion. FormApproved. OMBNo.20404086Approvalexpires541.92UnitedtatesEnvironmenta Protection AgencyWashington, DC20460Appi!cat!on forPerm!ttoD!schprge StormY/at~rOischaresAssociated withindustrial ActiviForm2FI.,kEPAIDNumber(copyfromitemiofFormi)PleaseprintortypeintheunshadedareasonlyHLD098647621 I.OutfaiiLocatIonForeachoutlalllistthelatitudeandlonitudeofitslocationtothenearest15secondsandthenameoftherecolvinwater.AOutfallNumberist~D.Receiving WaternameB.LatitudeC.Lonitude1S415850863400LakeHichi'2S415845863400LakeMich41'843863400LakeHichian415843863400LakeHichiPaperworlr Reduction ActNotice,PublicrepoNnIIburdenforthisap'plication isestimated toaverage28.6hoursperapplication, includ!ng timeforreviewing instructions, -searching existingdatasources,gathering andmaintaining thedataneeded,andcompleting andreviewing thecollection ofinformation. Sendcommentsregarding theburdenestimate, anyotheraspectofthiscollection ofinformation, orsuggestions forIhtproving thisform,including suagostions whichmayIncreaseorreducethisburdento:Chief,Information PolicyBranch,pM-223,U.S.Environmental Protection Agency,401MBt.,SW,Washington, DC20460,orDirector, OfficeofInformation andRegulatory Affaire,OfficeofManagement andBudget,Washington, DC2C503II.Imrovements A.AreyounowrequiredbyanyFederal,State,orlocalauthority tomeetanyImplementation schedulefortheconstruction, upgrading oroperation ofwastewater treatment equlpmont orpractices oranyotherenvironmental programswhichmayatfectthedischarges described inthisapplication2 Thisincludes, butisnotlimitedto,permitconditions, administrative orenforcement orders,enforcement compliance scheduleletters,stipulations, courtorders,ahdgrantorloanconditions. N/A1.Identification ofConditions, reements. Etc.number2.AffectedOutfallssourceofdischare3.BriefDescritionofProect4.FinalComlianceDateb.ro.a.re.ContinueonPage2Page1of3EPAForm35102F(Rev.1.92)youmayattachadditional sheetsdescribing anyadditional'water pollution (orotherenvironmental projectswhichmayaffectyourdischarges) younowhaveunderwayorwhichyouplan.Indicatewhethereachprogramisnowunderwayorplanned,andindicateyouractualorplannedschedules forconstruction RefertoAttachment A.!I.SiteDraInaeMa""achasitemapshowingtopography (orindicating theoutlineofdrainageareasservedbytheoutfall(s) coveredintheapplication ifagr~phiCmapiSuiavailable) depiCting thefaCilityinCIuding: eaChOfitSintakeanddiSCharge StruCtureS; thedrainageareaOfeaChStOrm""'"'u"all: pavedareasandbuildings withinthedrainageareaofeachstormwateroutfall,eachknownpastorpresentareasusedforoutdoor'oiagoor<<<posalofsignificant materials, eachexistingstructural controlmeasuretoreducepollutants instormwaterrunoff,materials loadingan<<c~ssareas.areaswherepesticides, horbicides, soilconditioners andfertilizers areapplied;eachofitshazardous wastetreatment, ""-rags<<disposal uni:s(including eachareanotrequiredtohaveaRCRApermitwhichisusedforaccumulating hazardous wasteunder40<'"26234):eachweilwherefluidsfromthefacilityareinjectodunderground; springe,andothersurfacewaterbodieswhichreceivestormr.a!or",sc.'.aosficm!"efacili Continued fromtheFrontForeachoutfall,provideanestimateofthearea(includeunits)ofImpervious surfaces(Including pavedareasaridbuildingroofs)drainedtotheoutfall,andanestimateofthototalsurfaoeareadrainedbYtheoutfall.SeeAttaChment: BOutfallAreaofImpervious SurfaceTotalAreaDrainedAreaofknpelvlous SuflaceTotalAreaDrainedB.provideanarrative description ofsignificant materials thatarecurrentlyorin thepastthroeyearshavebeerrtreatod, storedordispcsedlnamannertoallowexposuretostormwater;methodoftreatment, storage,ordisposal; pastandpresentmaterials management practices employedtominimizecontactbythesematerials withstormwaterrunoff;materials kedingandaocesaareas;andthelocation, manner,andfrequency inwhichpesticides, herbicides, soilconditioners, andfertilizers areapplied.1.SeeAttachment Bforsignificant materials SeeAtt.achment B-1forHerbicide Information SeeAttachment B-2forotherpotential exposures tostorlhwater C.Foreachoutfall,providethelocationandadescription ofexistingstructural andnonstructural controlmeasurestoreducepollutants instormwaterrunoff;andadescription ofthetreatment thestormwaterreceives, Including theschedul~andtypeofmaintenance forcontrolUstCodesfromSeeAttachment' V.Nonstorrnwater DlscharesAIcenifyunderpenaltyoflawthattheoutfall(s) ooveredbythisapplication havebeentestedorevaluated forthepresenceofnonstormwater discharqes, andthatallnonstormwater dischargee fromtheseoutfall(s) aroidentified inoitheranaccompanying Form2CorForm2EiNameandOfficialTitle(typeorprint)D.L.Bakeri'.AffairsDirector, DateSigned3b-ggB.Provideadescription ofthemethodused,thedateofanytesting,andtheonsltodrainagepointsthatweredirectlyobservedduringatest.Samplesprocuredandanalyzedasperapplicable guidelines. Outfall003Ssampledbeforeandaftermixingwithgroundwater. Vl.SlnlficantLeaksorSillsProvideexistingInformation regarding thehistoryofsignificant leaksorspillsoftoxicorhazardous pollutants atthefacilityinthelastthreeyears,Including theapproximate dateandlocationofthespillorleak,andthetypeandamountofmaterialreleased. SeeAttachment CEPAForm3510.2F(Aev.1-92)Page2of3ContinueonPage3 ler-'"Kx~&5%IS~ Continued fromPage2EPAlDNumber(copyfiom itemiofForm1)HID098647621 AB.G.4D:seeInstructions beforeproceeding. completeonesetoflablesforeachoutfall.Annotatetheoutlallnumberintheapaceprovided. TablesVll.A.Vll-B,andV!LCareincludedonsearetesheetsnumberedVll-1andVil2.E.Potential discharges notcoveredbyanalysis~isanytoxicpollutant listedintable2F.2,2F4or2F<,asubstance oracomponant olasubstance whichyoucurrently useormanufacture asanintermediate orfinalproductorbyproduct? YeslistailsuchiiurantsbelowNootoSectionDoyouhaveanyknowledge orreasontobelievethatanybiological testforacuteorchronictoxicityhasbeenmadeonanyofyourdischarges oronareceiving waterinrelationtoyourdischarge withinthelast3years?YesistallsuchiiuranrsbelowNoofoSectionN/AvrereanyoftheanalysisreportedinitemVllperformed byacontractlaboratory orconsulting firm?XYes(listthename,address,andtelephone numberof,andpollutants No(gotoSection?r) A.NameB.AddressC.AreaCodeif,PhoneNo.D.Pollutants AnaledLockheedAnalytical Services975KellyJohnsonDr.1(800)361-0220LasVegas,Nevada89119-3705 W.W.Engineering tfScienceGlenwoodHillsParkway1(616)942-9600P.O.Box874GrandRapids,HI49588-0874 Inorganic sOrganicsRadiochemistry BOD5(Biological OxygenDemand)Surfactants Icertifyunderpenaltyoflawthatthisdocumentandallattachments werepreparedundermydirection orsupervr'sion inaccordance witha'ystemdesignedtoassurethatqualified personnel properlygatherandevaluatetheinformation submitted. Basedonmyinquiry ofthepersonorpersonswhomanagethesystemorthosepersonsdirectlyresponsible forgathering theinforma;ion, theinformation submitted is,tothebestofmyknowledge andbelief,true,accurate, andcomplete. Iamawarethattherearesignificant penalties forsubmitting falseinformation, including thepossibility offineandimprisonment forknowingviolations. ANamelfOtficialTitle(~orpn'nr)R.C.Henge,President is+1~~river~Page3of3B.AreaCodeandPhoneNo.(219)425-2118 D.DateSigneds/su/qg 'EPAlDNumber(copyfromrremIofFormt)tiMID098647621IVll.DischareInformation (Confrnued (romae3ofForm2FFormApproved. OMBNo.204046)NIPart-Youmustprovideth~resultsofatleastoneanalysisloreverypollutant inthistable.Compl~leonetabl~foreachcurtail.erne.instructions foradditional details.Pollutant andCASNumber(ifavailable) GrabSampleTakenOuhngFirst30MinutesFlow-weighted Composite MaximumValues(includevnns)GrabSampl~TakenDuringFirst30MinutesRow-weighted Composite AverageValues(includeunits)NumberofStormEventsSampledSourcesofPollutants O'IandGreaseBiOlOgiCal OxygenDemand(8005)ChemicalOxygenDemandlCODlTotalSuspended Sokds(TSS)TotalKjefdahtNitroenNitrat~plusINitriteNitroenTotalPhcschorus Minimum'.taxirrurnREFERTOATTACHMENT DMinimumMaximumpart8-t.isteachpollutant thatisumitedinanetfluentguideknewnicnthetacivtyissuolecttooranypoilutant listedinthetacuitysNFDEspermitforits'process wastewater lilthelaciktyisoperating underanexistingNpDESpermnl.Completeonetableioreacnoutfait,hinIIi~Pollutant andCASNumber(ifavailable) GrabSamoleTakenDuringFirst30MinutesRowweightedComposite MaximumValues(includeunits)GrabSampf~TakenOunngFirst30MinutesFlow.weignted Composit~AverageValues(includeunits)NumberofStormEventsSampledSourcesofPonutants REFERTOATTACHMENT DEPAForm3510-2F~~PageVa.lContinueonReverse Continued fromtheFrontPertC-Usteachpollutant showninTables2F-2,2F4,and2'hatyouknoworhavereasontobelieveispresent.Seetheinstructions foradditional detailsandrequirements. Completeonetableforeachoutfall..Pollutant andCASNumberfifavailable) GrabSampleTakenDunngFirst20MinutesFlow~ighted Composite MaximumValues(incfudeunits)GrabSampleTa'anDuringFirst20MinutesRow~fghted Composite AverageValuesffncfudeunits)NumberofStormEventsSampledSourcesofPollutants REFERTOATTACHMENT DPertD-Providedataforthestormeventswhichresultedinthemaximumvaluesforthe.owweihtedcornsitesamle.DateofStormEvent2DurationofStormEventinminutes3.Totalrainfallduringstormeventininches4.Numberofhoursbetweenbeginning ofstormmeas-uredandendofpreviousmeasurable rainevent5.Maximumflowrateduringrainevent(gallons/minute orsecunits6.Totalflowfromraineventallonsors ec'nitsDec.18194210min.0.14inches280.5hours(RefertoAttachmntDforStormEv2liters/min. ntDescription) 1,260liters210min.x1.5I./min.x4outfalls=1260liters7.Provideadescritionofthemethodofflowmeasurement orestimate. Onelitercontainer usedinconjuction vithastopvatch.EPAForm3510-2F(Rev.1-P2)PageVll.2 Instructions -Form2FApplication forPermittoDischarge StormWaterAssociated withIndustrial ActivityWhoMustFileForm2FForm2Fmustbecompleted byoperators offacilities whichdischarge stormwaterassociated withindustrial activityorbyoperators ofstormwaterdischarges thatEPAisevaluating fordesignation asasignificant contributor ofpollutants towatersoftheUnitedStates,orascontributing toaviolation ofawaterqualitystandard. Operators ofdischarges v'hicharecomposedentirelyofstormwatermustcompleteForm2F(EPAForm3510-2F)inconjunction withForm1(EPAForm3510-1).Operators ofdischarges ofstormwaterwhicharecombinedwithprocesswastewater (processwastewater iswaterthatcomesintodirectcontactwithorresultsfromtheproduction oruseofanyrawmaterial, interme-diateproduct,finishedproduct,byproduct, wasteproduct,orwastewater) mustcompleteandsubmitForm2F,Form1,andForm2C(EPAForm3510-2C). Operators ofdischarges ofstormwaterwhicharecombinedwithnonprocess wastewater (nonprocess wastewater includesnoncontact coolingwaterandsanitarywasteswhicharenotregulated byeffluentguide-linesoranewsourceperformance

standard, exceptdischarges byeducational, medical,orcommercial chemicallaboratories) mustcompleteForm1~Form2F,andForm2E(EPAForm3510.2E).

Operators ofnewsourcesornewdischarges ofstormwaterassociated withindustrial activitywhich'will becombinedwithothernonstormwater newsourcesornewdischarges mustsubmitForm1,Form2F,andForm2D(EPAForm3510-2D). WheretoFileApplications Theapplication formsshouldbesenttotheEPARegionalOfficewhichcoverstheStateinwhichthefacilityislocated.Form2FmustbeusedonlywhenapplyingforpermitsinStateswheretheNPDESpermitsprogramisadministered byEPA.Forfacilities locatedinStateswhichareapprovedtoadminister theNPDESpermitsprogram,theState'nvironmental agencyshouldbecontacted forproperpermitapplication formsandinstructions. Information onwhetheraparticular programisadministered byEPAorbyaStateagencycanbeobtainedfromyourEPARegionalOffice.Form1~Table1ofthe"GeneralInstructions" liststheaddresses ofEPA,RegionalOfficesandtheStateswithinthejurisdiction ofeachOffice.Completeness Yotirapplication willnotbeconsidered completeunlessyouanswereveryquestiononthisformandonForm1.Ifanitemdoesnotapplytoyou,enter"NA(fornotapplicable) toshowthatyouconsidered thequestion. PublicAvailability ofSubmitted Information Youmaynotclaimasconfidential anyinformation requiredbythisformorForm1~whethertheinformation isreportedontheformsorinanattachment. Section402(j)oftheCleanWaterActrequiresthatallpermitapplications willbeavailable tothepublic.Thisinformation willbemadeavailable tothepublicuponrequest.Anyinformation yousubmittoEPAwhichgoesbeyondthatrequiredbythisform,Form1,orForm2Cyoumayclaimasconfidential, butclaimsforinformation whichareeffluentdatawillbedenied.lfyoudonotassertaclaimofconfidentiality atthetimeofsubmitting theinformation, EPAmaymaketheinformation publicwithoutfurthernoticetoyou.Claimsofconfidentiality willbehandledinaccordance withEPA'sbusinessconfidentiality regulations at40CFRPart2.Definitions Allsignificant termsusedintheseinstructions andintheformaredefinedintheglossaryfoundintheGeneralInstructions whichaccompany Form1.EPAIDNumberFillinyourEPAICentification Numberatthetopofeachodd-numbered pageofForm2F.Youmaycopythisiiumberd:rectly'.omitemIofForml. ATTACHMENT A ATTACHMENT AII.Improvements B.TheD.C.CookNuclearPlantispursuingthefollowing watertreatment projects: MakeupDemineralizer Regeneration WasteNeutralization SystemTheCookPlantisinstalling asystemtocollectandtreatmakeupdemineralizer regeneration wastestomeetproposedpHpermitlimits.ThecurrentpracticeistoisolatetheTurbineRoomSump(TRS),accumulate thewasteswithintheTRS,neutralize thewastewithsulfuricacidorsodiumhydroxide, thendischarge theneutralized contentsoftheTRStotheAbsorption Pond.Becausetheregeneration wastesarenottheonlysourceofwaterbeingcollected intheTRS,ahighwaterlevelwithintheTRSmayrequirethedischarge ofthesumpcontentspriortothewastesbeingcompletely neutralized. Thenewsystemwillallowcollection andneutralization oftheregeneration wastesapartfromtheTRS.Theholdingtankforthewastewillalsobethepointoftreatment withthecapability toaddandmixsulfuricacidorsodiumhydroxide withthewastepriortometeringtheneutralmixturetotheTRS.Thesystemistargetedforcompletion byJanuaryof1995,withsystemstart-uptooccurthereafter. Sequencing BatchReactorsTheCookPlantiscurrently requesting quotations toinstallapairofpre-engineered sequencing batchreactors(SBR)tomeettheproposedgroundwater effluentlimits.Thenewsystemwilloperateatadesignflowof50,000GPDwithamaximumflowof60,000GPD.TheSouthExtendedAerationPackagePlantwillbeutilizedasaretention tanktoensureefficient SBRoperation. Effluentfromthenewsystemwillcontinuetobedischarged intooneofthetwoseepagelagoons.Thenewsystemwillbeinstalled andoperational byDecemberof1995.3.AlumReplacement ProgramAChemistry TaskForceisevaluating chemicalflocculent replacements foralum(aluminum sulfate), takingbothgroundwater effluentstandards andreverseosmosissystemperformance intoconsideration. Thereplacements currently beingreviewedarepofymeric flocculents that.willenhancetheremovalofsuspended solidsinthepre-filters andmeetmanufacturer's recommendations forthewater ATTACHMENT A(Cont.)enteringthereverseosmosissystem.Therecommendations fromthetaskforce,onceapproved, willrequireadditional timetotestandimplement. Theenvironmental benefitofthisreviewisthereducedamountofaluminumthatwillbedischarged tothegroundwater throughtheTurbineRoomSumpdischarge. Thescheduled implementation datetouseanewflocculent isfourthquarterof1994.ZebraMusselControlStrategyThecurrentcontrolplanemployschlorination andperiodicshockchemicaltreatments utilizing aproprietary chemicalformulation. ThePlanthasalsochangedthesourcewaterforthefireprotection systemtoapotablesupplyfromLakeTownship. Thismethodofcontrolwasdeveloped forshorttermrelieffromtheeffectsofzebramusselinfestation. Basedonoverthreeyearsofexperience indealingwiththemusselsatthePlantandotherGreatLakesfacilities', anewstrategyisbeingevaluated toprotectalloperations frominfestation. Thenewstrategyincorporates intermittent oxidizing biocidetreatments ofthecirculating watersystembeginning attheintakestructures inLakeMichigan, continuous oxidizing biocidetreatment oftheessential servicewaterandnon-essential servicewatersystems,andadditionofsodiumbisulflite toreduceanyresidualoxidizing biocidepriortodischarge tothelake.Ifnecessary, shocktreatments utilizing proprietary chemicalformulations willbeadministered. Thegoaloftheprogramisto(l)eradicate existingpopulations andcontrolfurthersettlement ofzebramusselswithintheplantsystemswhichutilizelakewater,(2)treattheresidualoxidantbeingdischarged tonon-detectable levels,and(3)reduceoreliminate thenumberofremedialshocktreatments necessary tokillsettledcoloniesofzebramussels.5.Chemistry Corrosion ControlAdditives ThePlantisevaluating substitutes forthecurrentcorrosion controladditives inthesteamgenerators, plantheatingboiler,feedwater andcondensate systems,andclosedheating/cooling systems.Thesesubstitutes willincludecarbohydrazide, andotheravailable productsfromchemicalcompanies suchasBetzorNalco.Theenvironmental benefitsoftheseadditives includeutilization ofmorebenigncorrosion controlproductsorproductsrequiring lowereffective concentrations. Theseproductswilldischarge totheTurbineRoomSumpinconcentrations tobedetermined upontreatment optimization. ATTACHMENT B ATTACHMENT BIV.Narrative Description ofPollutant SourcesattheD.C.CookNuclearPlantinBridgman, Michigan. A.Approximate SurfaceArea(inft')ofImpervious SurfaceandTotalAreaDrained(Impervious andPervious) byOutfallNumber:OUTFALLPSURFACEAREATOTALAREADRAINEDImervious8cPervious001S002S003S004S1,400,000 400,000150,0004,0001,800,000 800,000450,000300,000B.Significant Materials -Treated,Stored,orDisposedof:Specificchemicals thatarestoredorusedinawaythatmaypotentially exposethemtotheyarddrainagesystemareasfollows:FuelOil-Storedinseveralunderground andabovegroundstoragetanksthroughout thesite.Allfillareasarewithinacontainment areaandoverfillalarmsareinstalled foreachtank.Yarddrainbasinsareinstalled withavalvewhichisclosedduringthefillingprocess.Intheunlikelyeventaspilldoesoccur,freeproductisheldwithinthecontainment. Anyandallfreeproductisproperlyremovedbyqualified andtrainedpersonnel priortotheopeningofthebasinvalve.Strictprocedures areoutlinedbythecompanyforproper"fillingprocedures intheseareas.Duringmaintenance periods,smalltankscontaining dieselfuelarelocatedaroundtheplantsitetofuelgenerators, compressors, andotherauxiliary equipment. Thesetanksarebermedanddeliveries tothemareinsmallquantities. Spillswhichcouldoccurareimmediately cleanedupwithabsorbent material. ATTACHMENT B(cont.)SulfuricAcid-Storedina10,000gallontankwhichisbermedwithinalinedconcretestructure designedtohold150%ofit'scontentsintheeventoftankoverfillorrupture.Thesulfuricacidinthistankisusedfordemineralizer regenerations andpHneutralization. Thetankandit'containment structure arelocatedoutsideanddirectlyadjacenttotheUnit1TurbineBuilding. Thistank,likeallotherbulkchemicalandfueloilstoragetanks,hasanoverfillalarmsystemtohelppreventspilleventswhilefillingthetank.ThefillforthistankislocatedalongthewestwalloftheUnit1TurbineBuildingandsharesalinedconcretespillbasinlocatedwithintheNorthChemicalUnloading Areawiththeheatingboilerfueloiltankvents.NOTE:TheNorthChemicalUnloading Areaisabermedtanktruckunloading areatypicalofotherunloading areasontheplantsite.Theareaisslightlydepressed andslopedtoasinglestormdrain.Thisdrainisoutfitted withavalvetoisolatethecontainment fromthestormdrainagesystem.Theoperation ofthisvalve,andotherslikeitwithincontainment areasaroundtheplantsitearecontrolled byplantprocedures. Sulfuricacidisalsousedtoregenerate themembranes inthereverseosmosis(RO)unitusedforwaterpurification. TheROunitislocatedoutsideintheroadwaydirectlywestoftheScreenhouse. Thesulfuricacidisstoredin55gallondrumswhicharebermedwithinacontainment systemadjacenttothereverseosmosisunit.Thesedrumsarechangedunderthedirection oftheROunitoperator. Plansaretoupgradethisbulkstoragetoabermedtanksystem.Hydrochloric acidasasubstitute forthesulfuricacidisbeingevaluated. SodiumHydroxide -Storedina10,000gallontankwhichisvaultedinthebasementoftheUnit1TurbineBuilding. Thistankhasanoverfillalarmsystem.Leaksandspillsfromthetankandpipingarecontained withinthevaultandroutedtotheturbineroomsumpforneutralization. ThefillforthistankislocatednexttothefillforthesulfuricacidtanklocatedwithintheNorthChemicalUnloading Area.Transformer Oil-Transformers containing mineraloilcontaminated withlowlevelPCB's(<50ppm)whicharenotroutedtooilwaterseparators, arebermedandcontainashutoffvalveormanuallycontrolled sumppump.Thesecontainments areinspected andreleasedbyatrainedoperatorontotheroadways, whicheventually entertheyarddrainsystem.Anycontamination thatisfoundwithinthecontainment areasisremovedprior ATTACHMENT B(cont.)toreleaseofthematerialtotheroadwaysandyarddrainsystem.Thetransformers areroutinely drainedformaintenance andrefilledontheplantsite.Trucksandpipingarebermedduringtransferring operations. IAMtransmission/distribution crewsmaintainthetransformers ontheplantsiteinaccordance withcompanyprocedures. SodiumHypochlorite (Chlorine) -UnloadedattheSouthChemicalUnloading AreawhichissimilarindesigntotheNorthChemicalUnloading Area.Yarddrainbasinsinthisarea,areinstalled withavalve,whichisclosedduringtheoffloadprocess.Intheunlikelyeventaspilldoesoccur,allfreeproductisheldwithinthecontainment. Anyrunoffthatenterstheyarddrainsystemisretainedbythevalveatthebasin.Anyandallfreeproductisproperlyremovedpriortotheopeningofthebasinvalve.Clam-trol CT-1(orotherzebramusselcontrolbiocides) -AreappliedviatankertrucksstagedattheNorthChemicalUnloading Area.Yarddrainbasinsinthisareaareinstalled withavalve,whichisclosedduringtheapplication process.Intheunlikelyeventaspilldoesoccur,allfreeproductisretainedwithinthecontainment. Anyrunoffthatenterstheyarddrainsystemisretainedbythevalveatthebasin.Anyandallfreeproductisproperlyremovedpriortotheopeningofthebasinvalve.Companyprocedures areusedtoapplythischemical. Basindrainsinthevicinityofthechemicalspargersaredikedtopreventreleaseofthischemicaltotheyarddrainsystem.Herbicides -Thesematerials areusedinvariousareasthroughout theCookPlantproperty. Nobulkquantities ofthesematerials arestoredonsite.Allquantities. areorderedandmixedbeforeapplications providedbyanoffsitevendor.Attachment B-Iliststheherbicide reportsforthepastthreeyears.Thesereportsdescribeapplication locations,

quantity, andtypeofmaterialused.

ATTACHMENT B(cont.)Non-radioactive WasteOilandNon-Hazardous Wastes-Anaboveground2,000gallonconcretevaulted(Convault) wasteoiltankislocatedwithinacontainment areadirectlynorthoftheNorthChemicalUnloading Area.Thestormwater basinwithinthisareaiscoveredwitharubbergasketedsteelcover.Drainingofstormwater, andloadingandunloading ofwasteoilinthisarea,isperformed byqualified personnel. Barrelsofwasteoilsandothernon-hazardous wastesincluding hydraulic oil,EPA2000andglycolwaitingprocessing arealsoaccumulated inthisarea.Radioactive WasteOil-One1,500gallonradioactive wasteoiltankislocatedintheNorthChemicalUnloading Area.Radioactive wasteoilisprocessed inaccordance withplantprocedures. Spillsfromthistankwouldbecontained withintheNorthChemicalUnloading Area.SodiumNitrite(CalgonLCS-60)-Addedasacorrosion inhibitor inmanyofthePlant'sclosedcoolingsystems.Theseincludethecomponent coolingwatersystem,dieseljacketcoolingwatersystem,andairconditioning andheatingsystemsontheplantsite.Thepotential ofsodiumnitritecontaminating thestormwatersystemismostlikelyintheofficebuildingHVACsystemswheresmallamountsofsodiumnitritesolutionmayleaktocondensate drainsandintooutfall001S.Storageofthischemicalisinbulkdrumsvyhichposenothreattothestormwater system.EthyleneGlycol-Usedasarefrigerant intheplant'scontainment icecondenser systemandalsointhetrainingsimulator chillersystem.Leaksfromtheplant'scontainment icecondenser systemarecontained andcollected withintheconfinesoftheauxiliary buildingandreactorcontainments. Leaksfromthetrainingsimulator chillersystemarecontained anddrummed.Theresulting ethyleneglycol/water solutions canalsobecollected inthetemporary glycolstoragetanklocatedwithintheNorthChemicalUnloading Area.Periodically, atemporary processing unitiserectedontheplantsitetoprocessthecollected ethyleneglycol/water solution. Theprocessisasfollows:Hydrogenperoxide(35%)foroxidation andsodiumhydroxide (50%)forpHbalanceareaddedtotheglycol/water solutionandintroduced intoaUVlightcell.Ethyleneglycolisbrokendownintocarbondioxideandorganicacids.Theprocessing unitiscompletely bermedandprocessing isperformed undercontinuous supervision oftheprocessing contractor withoversight fromplantstaff. ATTACHMENT B(cont.)Make-upPlantRegeneration Waste-AfterJanuary1995,acidicandcausticwastesolutions producedfromregeneration oftheMake-upPlantresin'beds willberoutedtotheMake-upPlantNeutralization Tanklocatedimmediately westoftheUnit2TurbineBuilding. SulfuricAcidorsodiumhydroxide areaddedtoneutralize thewastesinthetankbeforetheyareeventually drainedandpumpedtotheturbineroomsumpforreleasetotheonsiteabsorption pond.Thetankisofadouble-walled construction withbothwallshavingbeenhydro-tested. Theinnertankisequippedwithlevelalarminstrumentation. Theoverflowfortheinnertankisroutedtotheinterstitial spacebetweenthetankwalls.Thisspacecanbevisuallyinspected anddrainedunderplantsupervision. Pipingisabovegroundandheattraced.Anyleakinthispipingwouldbeeasilydetectedandrepaired. LowLevelRadioactive Corrosion Products-Duringoutageperiods,lowlevelradioactive corrosion productsaresludge-lanced fromthesteamgenerators. Ahighpressuredemineralized waterhoseisusedtocleanoutthecorrosion productswhichcollectatthetubesheet.Theresulting solutionisremovedandprocessed byacontractor withoversight byplantpersonnel. Thesludge-lance unitandauxiliary equipment arecompletely bermedwiththeprobability ofareleasefromthissystemtothestormwater systemunlikely. SewageSludge-Sewagesludgeiscollected inatemporary tanklocatedatthesouthendoftheSouthSewageTreatment Plant.Transferring ofsludgeisperformed bythesewagewastecontractor underthesupervision ofplantpersonnel. o.Chemicals AwaitingStorage-Forbriefperiods,portablebulktanksandpalletscontaining chemicals indrumsareoff-loaded ontotheloadingdockintheshippingandreceiving areauntiltheycanbeplacedintostorage.Deliveries aremadetotheplantprotected areaviatrucksandforklifts, andplacedinside'theTurbineBuildingorotherareaswhereneeded.p.ChemicalCleaningofHeatExchangers 4Piping-Oxidizers andorganicacidsareusedtocleanheatexchangers andpipingaroundtheplantsite.Thecleaningequipment iscontained andoperatedbycontractors withoversight byplantsupervision. Allotherchemicalmaterials arestoredwithintheconfinesofvariousbuildings andarenotconsidered tobeathreattotheyarddrainagesystem. ATTACHMENT B(cont.)C.ControlMethodsbyOutfall(refertotable2F-1forcodes)001S&002S-Containment areasandbasinvalvesarestructural andmechanical controlmeasuresinplaceforthesetwooutfalls. 'naddition, containment oilboomsarestrategically placedattheoutletsofthesetwooutfalls. Theseboomswillaidinthecontainment andabsorption ofanycontaminants shouldothercontainment systemsfail.Theseboomsareinspected andreplacedroutinely. Treatment Code:4-A(discharge toopenwater)003S&004S-Riskofcontaminants fromthesetwooutfallsisnegligible, therefore, nocontrolmeasuresareinplaceatthistime.Treatment Code:4-A(discharge toopenwater) ATTACHMENT B-1 ATTACHMENT B-1D.C.CookPlantSUMMARYOFPROGRAM-1991Herbicide SprayReportFromApril22-May1,1991,TownsendTreeServiceappliedamixtureofKarmex,AmizineandOusttocontrolweedgrowthonthePlantSite.Atotalof48lbs.ofKarmex,560lbs.ofAmizineand2IbsofOustwasappliedover36acres.Thefollowing areaswereinspected andtreatedforweeds:l.2.3.45.6.7.8.9.10.11.12.13.14.15.16.17.18.19.SewagePondsRoadtoAbsorption Pond765KvSwitchgear Yard345KvSwitchgear YardRailroadTrackseastofTrainingCenterParkinglotB69KvSwitchgear YardNorthProtected AreaFenceSouthProtected AreaFenceEastProtected AreaFenceICMSOfficeTrailerICMSFabShopSouthwest sideofTurbineBuildingSouthendofTurbineBuildingUnit1RWSTAreaUnit2RWSTAreaHydrogen/Nitrogen StorageTankAreaConstruction FabShopRoadtoMeteorological TowersBaseduponreviewofapplication recordsandobservations ofthetreatedareas,itappearsthattheherbicides wereappliedinaccordance withherbicide labelrequirements, andnoadverseenvironmental effectsoccurred. ATTACHMENT B-1(cont.)SUMMARYOFPROGRAM-1992Herbicide SprayReportFromJune3-7,1992,TownsendTreeServiceappliedamixtureofStompandOusttocontrolweedgrowthonthePlantSite.Atotalof91.2quartsofStompand91.2ouncesofOustwereappliedover36acres.Themanufacturer's labelrecommends thatStompbeappliedatarateofbetween2-4quartsperacre.Stompwasappliedatarateof2.7quartsperacre.Themanufacturer's labelrecommends thatOustbeappliedupto12ouncesperacre.Oustwasappliedatarateof2.7ouncesperacre.Thefollowing areaswereinspected andtreatedforweeds:l.2.3.45.6.7.8.9.10.11.12.13.14.15.16.17.18.19.SewagePondsRoadtoAbsorption Pond765KvSwitchgear Yard345KvSwitchgear YardRailroadTrackseastofTrainingCenterParkinglotB69KvSwitchgear YardNorthProtected AreaFenceSouthProtected AreaFenceEastProtected AreaFenceICMSOfficeTrailerICMSFabShopSouthwest sideofTurbineBuildingSouthendofTurbineBuildingUnit1RWSTAreaUnit2RWSTAreaHydrogen/Nitrogen StorageTankAreaConstruction FabShopRoadtoMeteorological TowersBaseduponreviewofapplication recordsandobservations ofthetreatedareas,itappearsthattheherbicides wereappliedinaccordance withherbicide labelrequirements, andnoadverseenvironmental effectsoccurred. ATTACHMENT B-1(cont.)SUMMARYOFPROGRAM-1993Herbicide SprayReportFromMarch8-October5,1993,variouscontractors haveappliedamixtureofTrimec899,Orthene75s,Stomp,Oust,Roundup,andTri-power tocontrolweedgrowthonthePlantSite.Atotalof270ouncesofTrimec899,2lbs.ofOrthene75s,103.5quartsofStomp,103.5ouncesofOust,214ouncesofRoundup,and298.4ozofTri-power wereappliedover36acres.Allwereappliedaspermanufacturers'abels recommendations. Thefollowing areaswereinspected andtreatedforweeds:l.2.3.45.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.SewagePondsRoadtoAbsorption Pond765KvSwitchgear Yard345KvSwitchgear YardRailroadTrackseastofTrainingCenterParkinglotB69KvSwitchgear YardNorthProtected AreaFenceSouthProtected AreaFenceEastProtected AreaFenceICMSOfficeTrailerICMSFabShopSouthwest sideofTurbineBuildingSouthendofTurbineBuildingUnit1RWSTAreaUnit2RWSTAreaHydrogen/Nitrogen StorageTankAreaConstruction FabShopRoadtoMeteorological TowersEnergyInformation. CenterLawnBaseduponreviewofapplication recordsandobservations ofthetreatedareas,itappearsthattheherbicides wereappliedinaccordance withherbicide labelrequirements, andnoadverseenvironmental effectsoccurred. ATTACHMENT B-2 ATTACHMENT B-2THERPOTENTIAL EXPOURESTOTORMWATER Thereareseven(7)potential areasofconcernwhichapplytothissectionwhichareasfollows:1.LubeOilVaporExtractors -locatedatvarioussitesontheroofoftheturbinebuilding. Smallamountsofoilvapordroplets(MobileDTE797)havethepotential tobespilledontotheroof.Duringrainperiodsthisoilmaterialwouldeventually bewashedintotheroofdrainsystem.FromthispointitwouldentertheyarddrainsandbereleasedtoLakeMichiganasdepictedinthefollowing diagram:. Col~TwgINV~Dwtlrl~yIH~Awe~LootSnla~~IW4%1oVe4WwtTIEtinelol1RloW2.SteamGenerator Blowdowns -Two(2)blowdownoutletsarelocatedontheeastsideoftheAuxiliary Building. Thesteamgenerators arepurgedofcorrosion productsperiodically topreventdegradation tothesteamgenerator tubes.Largeamountsofsteam,whichmaycontaintraceamountsoforganics, ethanolamine, andboricacidarereleasedintotheairoutsidetheplant.Theproductsinthesteamprecipitate tothegroundandeventually entertheyarddrainsystemasdemonstrated inthefollowing diagram:Note:Waterusedinthissystem(toformthesteam)isultra-purified lakewater.Thiswaterundergoes stringent purification processbeforeitentersthesystem. 3.DumpsterCleaning-DumpsterCleaningMaincondenser coolingwaterisscreenedthrough3/8"meshtraveling screensbeforepassingthroughthemaincirc.waterpumpandservicewaterpumpinlets.Materials impingedonthesescreensincluding sticks,leaves,zebramussels,andfish,areroutinely backwashed into,atrenchandsluicedtobothendsoftheScreenhouse intodebriscollection baskets.Thesecollection basketsarethendumpedintodumpsters whicharehauledofFtheplantsitebyalocal.wastehauler.Forpublichealthreasons,thesedumpsters arecleanedoutperiodically. Pathfinder, alowsudscleaner,isusedwithwatertowashoutthesedumpsters. Thewashwaterflowsdownayarddrainandoutoutfall001S.Outfall001aBar.IaLsk0Mictagata ~NSteanDcaaa~IOucataaaiIXIANgp'alctPip~ 4.RoadwaysandParkingLots-Automobiles, trucks,andheavyequipment requiregasoline, dieselfuel,coolants, hydraulic oil,andlubricants fortheiroperation. Smallleakscaneventually bewasheddownthestormdrainstoOutfalls001S,002S,003S,and004S.5.GaronDe-Icer95%CalciumChlorideand4%SodiumChloride. Gran-U-Thaw: 90%Carbonyldiamine, NitrogenCompounds-Urea. SafeStepAirportIceControl:Potassium

Chloride, SodiumChloride, Urea,andMethylglucoside.

Manufacturer tradesecret,percentages unavailable. Usedonroads,andsidewalks throughout thefacility. Thismaterialwithprecipitation willeventually entertheyarddrainsystemthatflowstoLakeMichiganthroughoutfalls001S,002S,003Sand004S.Theseroadsaltcompounds tendtoleachoilsfromtheasphaltpavementwhicharewashedintotheyarddrainagesystem.UppernmplopaotartloSLoi +MemtalDrahapaCgTralslspBsUSiaptarplspLoi~7thaihroaaRosaSMaraaltC>5UpphSssdkaaairlsS tarlls5LosVlrlmitartlspLsiStormDralaa~ 6.FireProtection Systems-Toeliminate thethreatofzebramusselinfestation initsfireprotection system,theplantconverted fromlakewatertoachlorinated municipal watersupply.Two650,000gallontankslocatedsouthoftheplantsiteprovidestorageforthefireprotection water.Thetanksareequippedwithanalarmsystem.TheoverflowanddrainageforthesetanksaretotheyarddrainagesystemOutfall003S.Onoccasionthesetanksaredrainedtoperformrepairs.Periodically, thefireprotection systemheaderandhydrantsareflowtestedwiththewaterbeingdirected'to theyarddrainsystem.Outfalls001S,002S,003S,and004Sareimpactedbythesebythistestingprocedure. Thefollowing diagramillustrates thetestinganddrainingprocess:FkePrccccaca WacrTcrkeBeneToYardDrainS)rtpl))careIBoreTotakeMictatna7.LawnSprinkler System-Theplantlawnsprinkler systemisoperatedusingbothcirculating waterandmunicipal watersupplies. Smallamountsofchlorinearecontained inthemunicipal waterandinthecirculating waterwhichcanenterthestormwaterdrainagesystemandOutfall001S.Refertothefollowing diagramforfurtherinformation. TramnaCornerPoetIOaeManOonrdBonneEncrtyInfonnaioa CornerOf5ceBai)dmSLekeMictntnaWaerScrotaW~PornpRhtcrrnkt~C)dorimtcd FromDr~tTannelBoerToYcrdDreinS)rtemDac~ToLake'ceOOIS)bkorinaed WacrFromLateTocrnetop ATTACHMENT C ATTACHMENT CINIFIANTLEAKSORSPILLS(pastthreeyears)OnFebruary15,March4,andMarch22,1993,CookPlantpersonnel observedaslightsheenonthesurfaceofLakeMichigan, adjacenttotheplant'sstormwaterdischarges. Subsequent investigation ofplantoilsystemsandoperations provedthesourcetobeoilresiduefromemployeevehiclesenteringthestormwatercollection systemfromparkinglotrunofKAttemptsweremadetopreventadditional oilfromenteringthecatchbasinsbytheuseofabsorbent boomsonallthreeoccasions. Asummaryofeacheventisasfollows:February15,1993March4,1993OilsheenfromOutfalls001Sand002SOilsheenfromOutfall001SMarch22,1993OilsheenfromOutfall001S ATTACHMENT D(ANALYTICAL RESULTS) ATTACHMENT D**DESCRIPTION OFRAINFALLEVENT**Fourteenone-hundredths ofaninch(0.14)ofrainfellonDecember18,1993.Theeventstartedat0630hrs.and.terminated at1000hrs.Outfalls001S,002S,003S,and004Scontinued toflowatarateof1-2liters/min. until1100hrs.Theprevioussignificant eventterminated at1400hrs.onDecember6,1993foratotalelapsedtimeof280.5hrs.betweenevents.**SAMPLINGMETHOD**Bothgrabandflowcomposite samplesweretakenduringthesinglestormeventofDecember18,1993.Stormwater outfalls001S,002S,and003Sweresampled.Sincetheoutfallcharacteristics ofOutfall003Sand004Sareessentially identical, andinverycloseproximity, Outfall004Swasnotsampled.BothOutfall003Sand004Sreceivegroundwater whichemergesfromthebaseofaduneandcollectsinatrencheastoftheoutfalls. Thisgroundwater mixeswithstormwater runofffromtheparkinglotsandroadwayssouthoftheplantandflowsthroughoutfalls003Sand004StoLakeMichigan. Forpurposesofthischaracterization study,samplesweretakenofOutfall003Sbothbeforeandaftermixingwithgroundwater duringthestormevent.Theresultsoftheanalysesareshowninthefollowing pages. ATTACHMENT DVII.Discharge Information PARTA0TFALL001SMaximumValuesAverageValuesPollutant andCASNumber(ifavailable) GrabSampleTakenDuringFirst30MinutesFlow-weighted Composite GrabSampleTakenDuringFirst30MinutesFlow-wcightcd Composite NumberofStormEventsSampledSourcesofPollutants OilandGreaseBiological OxygenDemand(BOD5)3.6mg/I2.8mg/I4.8mg/I3.2mg/I3.6mg/I4.8mg/I2.8mg/I3.2mg/IStormwaterrunoffStormwaterrunoffChemicalOxygenDemand(COD)TotalSuspended Solids(TSS)37mg/I34mg/I<18mg/I13mg/I37mg/I34mg/I<18mg/I13mg/IStormwaterrunoffStormwaterrunoffTotalKjeldahlNitrogenNitrateplusNitriteNitrogenTotalPhosphorus 4.9mg/I3.7mg/I1.5mg/I1.8mg/I0.19mg/I0.11mg/I4.9mg/I1.5mg/I0.19mg/I3.7mg/I1.8mg/I0.11mg/IStormwaterrunoffStormwaterrunoffStormwaterrunoffpHMinimum7.4Maximum7.4 XTYACHMENT D(cont.)PartAOUTFALL002SMaximumValuesAverageValuesPollutant andCASNumber(ifavailable) GrabSampleTakenDuringFirst30MinutesFlow-weighted Composite GrabSampleTakenDuringFirst30MinutesFlow-weighted Composite NumberofStormEventsSampledSourcesofPollutants OilandGreaseBiological OxygenDemand(BOD5)ChemicalOxygenDemand(COD)TotalSuspended Solids(TSS)<1mg/I<1mg/I1.5mg/I2.9mg/I<12mal<12mg/I<18mg/I<18mg/I<Img/I1.5mg/I<18mg/I<12mg/I<1mg/I2.9mg/I<18mg/I<12mg/IStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffTotalKjeldahlNitrogen20mg/I13mg/I20mg/I13mg/IStormwaterrunoffNitrateplusNitriteNitrogenTotalPhosphorus 5.6mg/I3.2mg/I0.14mg/I0.20mg/I5.6mg/I0.14mg/I3.2mg/I0.20mg/IStormwaterrunoffStormwaterrunoffpHMinimum7.9Maximum8.4 ATTACHMENT D(cont.)'PartAOUTFALL003S(Beforemixingwithgroundwater) MaximumValuesAverageValuesPollutant andCASNumber(ifavailable) GrabSampleTakenDuringFirst30MinutesFlow-weighted Composite GrabSampleTakenDuringFirst30MinutesFlow-weighted Composite NumberofStormEventsSampledSourcesofPollutants 'ilandGreaseBiological OxygenDemand(BOD5)2.1mg/12.7mg/11.8mg/12.6mg/12.1mg/11.8mg/12.7mg/12.6mg/1StormwaterrunoffStormwaterrunoffChemicalOxygenDemand(COD)18mg/119mg/118mg/119mg/1'tormwaterrunoffTotalSuspended Solids(TSS)TotalKjeldahlNitrogenNitrateplusNitriteNitrogenTotalPhosphorus 23mg/12.0mg/10.78mg/10.29mg/I15mg/12.1mg/I1.0mg/10.36mg/123mg/115mg/12.0mg/12.1mg/10.78mg/11.0mg/10.29mg/10.36mg/1StormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffpHMinimum7.5Maximum7.5 <<.TTACHMEI<<IT D(cont.)PartAOUTFALL003S(Aftermixingwithgroundwater)MaximumValuesAverageValuesPollutant andCASNumber(ifavailable) GrabSampleTakenDuringFirst30MinutesFlow-weighted Composite GrabSampleTakenDuringFirst30MinutesFlow-weighted Composite NumberofStormEventsSampledSourcesofPollutants OilandGreaseBiological OxygenDemand(BODS)2.2mg/I1.8mg/I2.2mg/I2.9mg/I1.8mg/I2.9mg/I1.8mg/I1.8mg/IStormwaterrunoffStormwaterrunoffChemicalOxygenDemand(COD)TotalSuspended Solids(TSS)26mg/I19mg/I<18mg/I<12mg/I26mg/I19mg/I<18mg/I<12mg/IStormwaterrunoffStormwaterrunoffTotalKjeldahlNitrogenNitrateplusNitriteNitrogenTotalPhosphorus 1.6mg/I0.90mg/I1.6mg/I1.1mg/I2.2mg/I1.1mg/I0.23mg/I0.13mg/I0.23mg/I0.90mg/I2.2mg/I0.13mg/IStormwaterrunoffStormwaterrunoffStormwaterrunoffpHMinimum7.7Maximum8.0 .O'TACHMENT D(cont.)VII.Discharge Information PARTBOUTFALL001SMaximumValuesAverageValuesPollutant andCASNumber(ifavailable) GrabSampleTakenDuringFirst30MinutesFlow-weighted Composite GrabSampleTakenDuringFirst30MinutesFlow-weighted Composite NumberofStormEventsSampledSourcesofPollutants Cadmium<.005mg/I<.005mg/I<.005mg/I<.005mg/IStormwaterrunoffChlorideChlorine(totalresidual) 36mg/I<0.02ppm46mg/I36mg/I<0.02ppm46mg/IStormwaterrunoffStormwaterrunoffCopperSulfate13mg/I16mg/I13mg/I<.025mg/I<.025mg/I<.025mg/I<.025mg/I16mg/IStormwaterrunoffStormwaterrunoffTotalDissolved Solids(TDS)93mg/I160mg/I93mg/I160mg/IStormwaterrunoffZinc0.31mg/I0.21mg/I0.31mg/I0.21mg/IStormwaterrunoff TTACHMENT D(cont.)PARTBOUTFALL002SMaximumValuesAverageValuesPollutant an'dCASNumber(ifavailable) GmbSampleTakenDuringFirst30MinutesFlow-weighted Composite GrabSampleTakenDuringFirst30MinutesFlow-weighted Composite NumberofStormEventsSampledSourcesofPollutants CadmiumChloride<.005mg/I<.005mg/I<.005mg/I2.9mg/I3.4mg/I2.9mg/I<.005mg/I3.4mg/IStormwaterrunoffStormwaterrunoffChlorine(totalresidual) <0.02ppm<0.02ppmStormwaterrunoffCopperSulfateTotalDissolved Solids(TDS)Zinc18mg/I26mg/I18mg/I83mg/I100mg/I83mg/I0.46mg/I0.22mg/I0.46mg/I0.029mg/I<.025mg/I0.029mg/I<.025mg/I26mg/I100mg/I0.22mg/IStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoff <<TTACHMENT D(cont.)PARTB"OUTFALL003S(beforemixingwithgroundwater) MaximumValuesAverageValuesPollutant andCASNumber(ifavailable) GrabSampleTakenDuringFirst30MinutesFlow-weighted Composite GrabSampleTakenDuringFirst30MinutesFlow-weighted Composite NumberofStormEventsSampledSourcesofPollutants CadmiumChlorideChlorine(totalresidual) CopperSulfateTotalDissolved Solids(TDS)Zine<.025mg/I<.025mg/I3.4mg/I4.0mg/I88mg/I93mg/I0.28mg/I0.29mg/I<.005mg/I<.005mg/I0.75mg/I0.86mg/I<0.02ppm<.005mg/I0.75mg/I<0.02ppm<.025mg/I3.4mg/I88mg/I0.28mg/I<.005mg/I0.86mg/I<.025mg/I4.0mg/I93mg/I0.29mg/IStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoff 4.TTACHMENT D(cont.).PARTBOUTFALL003S(aftermixingwithgroundwater)MaximumValuesAverageValuesPollutant andCASNumber(ifavailable) GrabSampleTakenDuringFirst30MinutesFlow-weighted Composite GrabSampleTakenDuringFirst30MinutesFlow-weighted Composite NumberofStormEventsSampledSourcesofPollutants CadmiumChlorideChlorine(totalresidual) Copper<.005mg/I1.5mg/I<0.02ppm<.025mg/I<.005mg/I<.005mg/I<.005mg/I4.5mg/I1.5mg/I4.5mg/I<0.02ppm<.025mg/I<.025mg/I<.025mg/IStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffSulfate25mg/I120mg/I25mg/I120mg/IStormwaterrunoffTotalDissolved Solids(TDS)97mg/I370mg/I97mg/I370mg/IStormwaterrunoffZinc0.25mg/I0.13mg/I0.25mg/I0.13mg/IStormwaterrunoff ',TTACHMENT D(cont.)VII.Discharge Information PARTCOUTFALL001SMaximumValuesAverageValuesPollutant andCASNumber(ifavailable) GrabSampleTakenDuringFirst30MinutesFlow-weighted Composite GrabSampleTakenDuringFirst30MinutesFlow-weighted Composite NumberofStormEventsSampledSourcesofPollutants AluminumBariumBoronCobalt0.79mg/I0.41mg/I<.20mg/I<.20mg/I<.20mg/I<.20mg/I<0.05mg/I<0.05mg/I0.79mg/I<.20mg/I<.20mg/I<0.05mg/I0.41mg/I<.20mg/I<.20mg/I<0.05mg/IStormwaterrunoff.StormwaterrunoffStormwaterrunoffStormwaterrunoffIron1.6mg/I0.7mg/I1.6mg/I0.7mg/IStormwaterrunoffLeadMagnesium Molybdenum Surfactants SulfideTinRadioactivity (alpha)Radioactivity (beta)6.9pCi/14.3pCi/I0.049mg/I0.016mg/I<5.0mg/I<5.0mg/I<0.2mg/I<0.2mg/I0.060mg/I0.029mg/I<3.0mg/I<3.0mg/I<0.2mg/I<0.2mg/I2.1pCi/10.69pCi/10.049mg/I<5.0mg/I<0.2mg/I0.060mg/I<3.0mg/I<0.2mg/I2.1pCi/I6.9pCi/I0.016mg/I<5.0mg/I<0.2mg/I0.029mg/II<3.0mg/I<0.2mg/I0.69pCifl4.3pCi/IStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoff10 ATTACHMENT D(cont.)PA'RTCOUTFALL002SMaximumValuesAverageValuesPollutant andCASNumber(ifavailable) GrabSampleTakenDuringFirst30MinutesFlow-weighted Composite GrabSampleTakenDuringFirst30MinutesFlow-weighted Composite NumberofStormEventsSampledSourcesofPollutants AluminumBariumBoronCobaltIronLeadMagnesium Molybdenum Surfactants SulfideRadioactivity (alpha)0.26mg/I<0.20mg/I0.26mg/I<0.20mg/I<0.20mg/I<0.20mg/I<0.20mg/I<0.20mg/I<0.20mg/I<0.05mg/I<0.05mg/I<0.05mg/I0.73mg/I0.40mg/I0.73mg/I0.0048mg/I0.0032mg/I0.0048mg/I<5.0mg/I<5.0mg/I<5.0mg/I<0.2mg/I<0.2mg/I<0.2mg/I0.029mg/I0.031mg/I0.029mg/I<3.0mg/I<3.0mg/I<3.0mg/I<0.2mg/I<0.2mg/I<0.2mg/I0.54pCi/I0.64pCi/I0.54pCi/I<0.20mg/I<0.20mg/I<0.20mg/I<0.05mg/I0.40mg/I0.0032mg/I<5.0mg/I<0.2mg/I0.031mg/I<3.0mg/I<0.2mg/I0.64pCi/IStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffRadioactivity (beta)7.0pCi/I4.7pCi/I7.0pCi/I4.7pCi/1Stormwaterrunoff11 ,TTACHMENT D(cont.)PARTCOUTFALL003S(beforemixingwithgroundwater)MaximumValuesAverageValuesPollutant alldCASNumber(ifavailable) GrabSampleTakenDuringFirst30MinutesFlow-weighted Composite GrabSampleTakenDuringFirst30MinutesFlow-weighted Composite NumberofStormEventsSampledSourcesofPollutants AluminumBariumBoronCobaltIronLeadMagnesium Molybdenum Surfactants SulfideTlnRadioactivity (alpha)1.2mg/I0.85mg/I1.2mg/I<0.20mg/I<0.20mg/I<0.20mg/I<0.20mg/I<0.20mg/I<0.20mg/I<0.05mg/I<0.05mg/I<0.05mg/I2.5mg/I1.7mg/I2.5mg/I0.0096mg/I0.0063mg/I0.0096mg/I<5.0mg/I<5.0mg/I<5.0mg/I<0.2mg/I<0.2mg/I<0.2mg/I0.043mg/I0.049mg/I0.043mg/I<3.0mg/I<3.0mg/I<3.0mg/I<0.2mg/I<0.2mg/I<0.2mg/I1.63pCi/I0.73pCi/11.63pCi/10.85mg/I<0.20mg/I<0.20mg/I<0.05mg/I1.7mg/I0.0063mg/I<5.0mg/I<0.2mg/I0.049.mg/I <3.0mg/I<0.2mg/I0.73pCi/IStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffRadioactivity (beta)5.2pCi/I3.1pCi/I5.2pCi/I3.1pCi/1Stormwaterrunoff12 ~.TTACHMENT D(cont.)PARTC"OUTFALL003S(aftermixingwithgroundwater)MaximumValuesAverageValuesPollutant andCASNumber(ifavailable) GrabSampleTakenDuringFirst30MinutesFlow-weighted Composite GrabSampleTakenDuringFirst30MinutesFlow-wcightcd Composite NumberofStormEventsSampledSourci:sofPollutants AluminumBariumBoronCobaltLeadMagnesium Molybdenum Surfactants SulfideRadioactivity (alpha)Radioactivity (beta)1.2mg/I<0.20mg/I<0.20mg/I<0.05mg/I0.0082mg/I<5.0mg/I<0.2mg/I0.031mg/I<3.0mg/I<0.2mg/I1.2pCi/15.0pCin1.1pCi/11.2pCi/11.1pCin4.3pCi/I5.0pCi/I4.3pCi/I0.46mg/I1.2mg/I0.46mg/I<0.20mg/I<0.20mg/I<0.20mg/I<0.20mg/I<0.20mg/I<0.20mg/I<0.05mg/I<0.05mg/I<0.05mg/I0.94mg/I2.3mg/I0.94mg/I0.0031mg/I0.0082mg/I0.0031mg/I14.0mg/I<5.0mg/I'4.0mg/I<0.2mg/I<0.2mg/I<0.2mg/I0.031mg/I0.031mg/I0.031mg/I<3.0mg/I<3.0mg/I<3.0mg/I<0.2mg/I<0.2mg/I<0.2mg/IStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoff13 ATTACHMENT E(DRAWINGS) DRAWINGNUMBERDESCRIPTION 0102030405060708091011A11BENTIREPROPERTYPLANTWITH001S&002SPLANTWITH001SONLYPLANTWITH002SONLYTRAININGCENTERANDROADAREA(OUTFALL001S)SOUTHAREAWITH003S2004SENERGYINFORMATION CENTERAREAPOST1GUARDHOUSEAREAPERVIOUS/IMPERVIOUS DRAINAGEAREASHERBICIDE APPLICATION AREASTOPOMAP(BRIDGMAN) TOPOMAP(COOKPLANT) IndianaMichiganPowerCompanyO."eSLrnninSoearePaBox60For;'Boynelixed.'6691 219'252111CERTIFIED MAILfZ756046675liltINDIANANICHIGiAN POWERMr.WilliamE.McCracken SurfaceWaterQualityDivisionPermitsSectionDepartment ofNaturalResources P.0.Box30028Lansing,MI48909March31,1994

DearMr.McCracken:

Sub)ect:IndianaMichiganPowerCompanyDonaldC.CooknuclearPlantNPDESPermitNo.MI0005827RenewalApplication EnclosedistheIndustrial andCommeicial Wastewater Discharge Application forrenewaloftheCookNuclearPlantNPDESPermit.Alsoenclosed, isfor2PforrenewaloftheCookNuclearPlantStormWaterDischarge Permit.Theseapplications arebeingsubmitted 180dayspriortotheexpiration ofthepresentpermit.CookNuclearPlantalsohassubmitted aseparategroundwater permitapplication totheagency'sgroundwater division; theinformation isalsoenclosedwiththisapplication. Duringthetermofthepresentpermit,severalpermitmodifications weremadetoimproveCookNuclearPlantoperations. Weappreciate youreffortsinthesepermitmodifications. Additional changesareunderdevelopment whichwillaffectCookNuclearplantoperations. Information regarding theseimprovements isenclosedwiththefollowing attachments: Attachment DescritionMakeupDemineralizer Regeneration WasteNeutralization SystemSequencing BatchReactorsZebraMusselControlStrategyAlumReplacement ProgramChemistry Corrosion ControlAdditives ThermalEffluentShouldyouhaveanyquestions regarding theserenewalapplications, pleasecontactJohnCarlson,CookNuclearPlant March31,1994Mr.WilliamE.McCracken Page2Environmental Supervisor, at(616)465-5901 ext.1153,ormeat(219)425-2118. Wewouldbehappytomeetwithyouatyourconvenience todiscusstheapplication. verytrulyyours,DonaldL.BakerEnvironmental AffairsDirectorDLB/sdb/065,66 Attachments certifyunderpenaltyoflawthatIhavepersonally examinedand'amfamiliarwiththeinformation submitted onthisandallattacheddocuments; andbasedonmyinquiryofthoseindividuals immediately responsible forobtaining theinformation, Ibelievethesubmitted information istrue,accurateandcomplete. Iamawarethattherearesignificant penalties forsubmitting falseinformation, including thepossibility offineandimprisonment. DonaldL.Baker March31,1994Mr.WilliamE.McCracken Page3bc:W.N.D'Onofrio/M. A.Bailey/J. L.HugheyA.A.BlindS.J.BrewerD.M.Fitzgerald/J. P.CarlsonE.E.Fitzpatrick D.W.Kemp/K.D.HackT.E.Webb/J.P.Novotony

Attachment 1MakeupDemineralizer Regeneration WasteNeutralization SystemCookNuclearPlantisinstalling asystemtocollectandtreatmakeupdemineralizer regeneration wastestomeetproposedpHpermitlimits.ThecurrentpracticeistoisolatetheTurbineRoomSump(TRS),accumulate thewasteswithintheTRS,neutralize thewastewithsulfuricacidorsodiumhydroxide, andthendischarge theneutralized contentsof.theTRStotheAbsorption Pond.Becausetheregeneration wastesarenottheonlysourceofwaterbeingcollected intheTRS,ahighwaterlevelwithintheTRSmayrequirethedischarge ofthesumpcontentspriortothewastesbeingcompletely neutralized. IThenewsystemvillallowcollection andneutralization oftheregeneration wastesapartfromtheTRS.Theholdingtankforthewastewillalsobethepoint.oftreatment withthecapability toaddandmixsulfuricacidorsodiumhydroxide withthewastepriortometeringtheneutralmixturetotheTRS.ThetotalcostoftheMakeupDemineralization WasteSystemis$3,600,000.00. Thesystemistargetedforcompletion byJanuaryof1995,withsystemstart-uptooccurthereafter. Attachment 2Sequencing BatchReactorsCookNuclearPlantiscurrently requesting quotations toinstallapairofpre-engineered sequencing batchreactors(SBR)tomeettheproposedgroundwater effluentlimits.Thenewsystemwilloperateatadesignflowof50,000GPDwithamaximumflowof60,000GPD.TheSouthExtendedAerationPackagePlantwillbeutilizedasaretention tanktoensureefficient SBRoperation. Effluentfromthenewsystemwillcontinuetobedischarged intooneofthetwoseepagelagoons.Thenewsystemwillbeinstalled andoperational byDecemberof1995. Attachment 3ZebraMusselControlStrategyZebramusselsareamenacetoanyindustrial ormunicipal processdrawingwaterfromLakeMichigan. Ourcurrentcontrolplanistochlorinate andperformperiodicshockchemicaltreatments utilizing proprietary chemicalformulations. Thismethodofcontrolwasdeveloped forshorttermrelieffromtheeffectsofzebramusselinfestation. Wehavealsochangedoursourcewaterforourfireprotection systemtoapotablesupplyfromLakeTownship. Afterfouryearsofexperience indealingwithzebramusselsatCookNuclearPlantandotherGreatLakefacilities, anewstrategyisunderconsideration toprotectalloperations frominfestation. Thenewstrategyincorporates intermittent oxidizing biocidetreatments ofthecirculating watersystembeginning attheintakestructures inLakeMichigan, continuous oxidizing biocidetreatment oftheessential servicewaterandnon-essential servicewatersystems,additionofsodiumbisulfate toreduceanyresidualoxidizing biocidepriortodischarge toLakeMichigan, andifnecessary, shocktreatments utilizing proprietary chemicalformulations. Thegoaloftheprogramisto(1)eradicate existingpopulations andcontrolfurthersettlement ofzebramusselswithinplantsystemsthatutilizelakewater,(2)reducetheresidualoxidantbeingdischarged tonon-detectable levels,and(3)reduceoreliminate thenumberofremedialshocktreatments necessary tokillsettledcoloniesofzebramussels.Theproposedoxidizing biocidetreatment usessodiumbromideandsodiumhypochlorite, oraproprietary mixturesuchasNalcoActi-Brom,toretardveligersettlement andmaintainmicrobiological control.Shouldnon-oxidizing biocidesberequired, weplantouseeitherBetzCT-2,BetzCT-4,CalgonH-130M,orNalco9210.Werequesttheflexibility touseanyFIFRA(FederalInsecticide, Fungicide, andRodenticide Agency)approvednon-oxidizing biocide.Theconcentration ofanyofthetreatment chemicals willbebroughttowithinthewaterqualitybasedeffluentlimits,asrequired, usingformulations ofbentonite clayorotherappropriate material. Theresultant chemicalchangeswillultimately affectdischarges toLakeMichiganviaESW,NESW,andthecirculating watersystems,anddischarges tothegroundwater throughtheturbineroomsump,frompumpsealsandequipment drainsofthetreatedsystems.Wemaybeginportionsoftheplan,suchascontinuous oxidizing biocidetreatments oftheESWandNESWsystems,in1994.Portionsoftheplan,wherenewsystemsrequirecapitalexpenditures alongwithdesignandinstallation oftheequipment, willtakelonger.Therefore, theplanmaynotbefullyimplemented forseveralyears.WewillcontinuetoinformtheMDNRofplannedoperational changesastheyarefinalized. Attachment 4AlumReplacement ProgramAChemistry TaskForceisevaluating chemicalflocculent replacements foralum(aluminum sulfate)toimproveperformance ofthemakeupwatersystem.Thereplacements beingreviewedaremainlypolymeric 'flocculents whichwillenhancetheremovalofsuspended solidsinthepre-filters andmeetmanufacturer recommendations forthewaterenteringthereverseosmosissystem.Therecommendations fromthetaskforce,onceapproved, willrequireadditional timetotestandimplement. Theenvironmental benefitofproductsubstitution isthereducedamountofaluminumwhichwillbedischarged tothegroundwater throughtheturbineroomsump.Thescheduled targetimplementation datetouseanewflocculent isthefourthquarterof1994. Attachment 5Chemistry Corrosion ControlAdditives CookNuclearPlantisevaluating substitutes forthecurrentcorrosion controladditives inthesteamgenerators, plantheatingboiler,feedwater andcondensate systems,andclosedheating/cooling systems.Thesesubstitutes willincludecarbohydrazide, andotheravailable productsfromchemicalcompanies suchasBetzorNalco.Theenvironmental benefitsoftheseadditives includeutilization ofmorebenigncorrosion controlproductsorproductsrequiring lowereffective concentrations. Useoftheseproductswillnecessitate discharge toOutfalls001,002,003,OOA,OOB,OOCandOODinconcentrations tobedetermined uponeffective optimization. Consequently, higherconcentrations ofironandothersystemproductsmaybeseentemporarily. Attachment 6Therma1EffluentThecurrentthermaleffluentlimitforthecirculating watersystemdischarging toLakeMichiganis15.5X10'TU/hr. Thisiscalculated frommeasurements takenatOutfalls001and002forUnits1and2,respectively. Atthislimit,theunitsareoperating withcalculated maximumtemperature differentials of22.3and18.3degreesFforUnits1and2,respectively. Theunitsarehavebeenrequiredtoreduceloadfrom1004duringthehottestsummermonthstomaintainthethermaldischarge withxnlimits.Inordertomaintain1004loadthroughout theentireyear,including thehotsummermonths,weproposeincreasing thethermaldischarge limitto16.25X10'TU/hr. Attheproposedthermaldischarge, thetemperature differentials arecalculated tobeapproximately 1degreeFgreater<or23.4and19.3degreesFforUnits1and2respectively, usingthesameconditions asintheabovecalculations. Theincreaseinheatloadanddischarge temperature toLakeMichiganareminimalandarenotexpectedtoresultinadverseenvironmental harminandaroundtheplantdischarges. Asinthepast,themaximuminlettemperature whichtheunitscanoperateatfullpoweris87.5degreesF,becauseofthelimitations onthecontrolroomairconditioning system.Themaximumeffluenttemperatures during1993were98.7and89.7degreesFforUnits1and2,respectively. NotethatUnit2operatedat704loadduringmostof1993toincreasethetimebetweenrefueling outagesofthetwoCookNuclearPlantUnits.IndianaMichiganPowerCompanyfundedoneofthemostextensive aquaticecological researchprojectsontheGreatLakesfrom1973through1982attheCookNuclearPlant.IndianaMichiganPowerCompany's contractor, TheUniversity ofMichigan, CenterforGreatLakesResearchCenter(thentheGreatLakesResearchDivision), published abookin1986thatwasacompilation ofthephysical,

chemical, andbiological studiesconducted underthedirection ofDr.JohnC.Ayers.Amongotherconclusions, thesestudiesdocumented thelackofadverseimpactsfromthethermaldischarge.

Thetitlepage,tableofcontents, andlistofpublications generated fromtheresearchwerecopiedfromthebookandareattachedtothispermitapplication. Thermalplumemapsweremadeduringdifferent seasonsoftheyeartodetermine theimpactoftheCookNuclearPlantthermaleffluentonLakeMichigan. Thesemapsshowedthesurfaceareaoftheplumewaswellwithinthe570acremixingzonespecified intheNPDESPermitissuedforCookNuclearPlantonDecember27,1974,andmodifiedApril4,1978.Eveninthesimplistic assumption thata54increaseintheheatrejection rateresultedinasimilarincreaseofthethermalplumesurfacearea,theresulting plumewouldstillbewellwithinthemixingzonelimit.ThesmallincreaseinthemaximumdeltaTwillnotmeasurably alterthethermalregimethatalreadyexistsintheimmediate vicxnityofthehighvelocitydischarge. Thethermaldischarge fromCookNuclearPlantwasgrantedavariancefrommeetingbestavailable treatment technology underSection316(a)oftheFederalWaterPollution ControlActof1972bytheWaterResources Commission inMay,1977. GREATLAKESRESEARCHDIYISION/PUBLICATION 22SOUTHEASTERN NEARSHORE LAKEMICHIGAN: IMPACTOFTHEDONALDC.COOKNUCLEARPLANTEditedbyRonaldRossmannGREATLAKESRESEARCHDIVISIONTheUniversity ofMichiganAnnArbor,Michigan48109AFINALREPORTTOINDIANA&MICHIGANELECTRICCOMPANY1986 4plCONTENTSINTRODUCTlON RonaldRossmannSEDIMENTS OFSOUTHEASTERN NEARSHORE ~LAKEMICHIGANRonaldRossmann, Kjel/A.Johansen, andErwinSeibel............... WATERSOFSOUTHEASTERN NEARSHORE LAKEMICHIGANRonaldRossmannIMPACTOFTHEDONALDC.COOKNUCLEARPLANTONPHYTOPLANKTON RonaldRossmann, WilliamY.B.Chang,JamesA.Bowers,LaurieFeldt,andJamesBarresPHYTOPLANKTON POPULATIONS OFSOUTHEAST LAKEMICHIGAN1974-1982 JamesA.Bowers,RonaldRossmann, JamesBarres,andWilliamY.B.ChangIMPACTOFTHEDONALDC.COOKNUCLEARPLANTONZOOPLANKTON INSOUTHEASTERN LAKEMICHIGANMarleneS.EvansandGlennJ.WarrenEFFECTSOFTHEDONALDC.COOKNUCLEARPLANTON'ACROZOOBENTHOS INNEARSHORE SOUTHEASTERN LAKEMICHIGANDavidS.White,MichaelWinnell,Catherine Zawacki,RogerLaDronka, ThomasZdeba,andSamuelMozleyECOLOGYOFTHEMACROZOOBENTHOS INTHEVICINITYOFTHEDONALDC.COOKNUCLEARPLANTDavid.S.White,MichaelWinnell,Catherine Zawacki,RogerLaDronka, ThomasZdeba,andSamuelMozleyIMPACTOFTHEDONALDC.COOKNUCLEARPLANTONFISH.DavidJ.Jude,DavidBimber,NancyThurber,FrankTesar,LauraNogucht', PamelaMansfield, HeangTin,PaulRagoECOLOGYOFFISHINNEARSHORE SOUTHEASTERN LAKEMICHIGAN, 1973-1982 FrankTesar,DavidJ.Jude,He'angTin,PamelaMansfield ............ LAKEANDSHOREICECONDITIONS ONSOUTHEASTERN LAKEMICHIGANErwinSeibel.135187141169207253285353401 INTRODUCTION RonaldRossmannTheLaurentian GreatLakesserveasasourceofcoolingwaterforbothfossil-andnuclear-fueled powerplants.Intheearly1960s,projected heavyutilization ofthisfreshwater resourcebypowerplantsraisedconcernsabouttheenvironmental impactofpowerplantsonthelakes.Suchpublic,governmental, andindustrial concernsledtothefederalrequirement thatenvironmental impactstudiesbecon-ductedatallproposedornewlyconstructed powerplants,especially nuclearpowerplants.TheGreatLakesResearchDivisionofTheUniversity ofMichiganwascontracted byIndiana&MichiganElectricCompanytoconductanenvironmental" impactstudyoftheDonaldC.CookNuclearPlant,investigating theareathroughthepre-operational yearsofconstruction andintotheperiodofplantoperation. DONALDC.COOKNUCLEARPLANTTheDonaldC.CookNuclearPlantisa2,200MWsteamelectricgenerating stationsituatedinabeltofsanddunesonthesoutheastern shoreofLakeMichiganabout18kmsouthwest ofSt.Joseph,Michigan(Indiana&MichiganElectricCom-panyandIndiana&,MichiganPowerCompany1973)(Fig.I).Preparation ofthesiteforconstruction oftheplantbeganin1968.UnitIwasoperational in1975andUnit2in1978.Theplantwasbuiltatatimewhenpublicconcernfortheenviron-mentreacheditszenith.Atfulloperation, theplantusesroughly6,300m'flakewaterperminuteinonce-through coolingofitscondensers; thewaterreturnedtothelakeis9-12C'bove theintaketemperature. Wateriswithdrawn fromthelakethroughthreeintakecribslocatedatawaterdepthof7.3mapproximately 686moffshore(Fig.2).Theintakestructures extend2mabovethelakebottom.Maximumwatervelocityis1.8m/swithinthethree4.9-mdiameterintakepipes.Condenser coolingwaterisreturnedtothelakethroughtwodischarge pipeslocatedatawaterdepthof5.5mapproximately 366moffshore. Riprapbedsofcrushedlimestone weredeposited aroundtheintakeanddischarge structures topreventerosionandscourofthelakebottom.Duringwinter,waterisonlydrawnintotheplantthroughthetwoouterintakecribs.Heatedwaterisdischarged throughthecenterintake,whichisturnedintoadischarge topreventiceformation aroundtheotherintakestructures. Withinthescreenhouse, trashbars6.6cmapartpreventlargepiecesofdebris.fromenteringtheintakeforebay.Verticaltraveling 9.5-mmbarmeshscreenswithintheforebayimpingetrashandfishtoolargetopassthroughthecondensers. HISTORYOFTHEENVIRONMENTAL IMPACTSTUDYThoughtheGreatLakesResearchDivision's environmental impactstudyincludedphysicalandchemicalstudiesofnearshore southeastern LakeMichigan, itfocused 2D.C.COOKiVUCLEARPLAtVTIMPACTMILWAUKEEMUSKEGONKtlometero CHICAGOST.JOSEPHCOOKPLANTFIGUREI.LocationoftheDonaldC.CookNuclearPlantonthesoutheastern shoreline ofLakeMichigan. onmajorbiological components oftheecosystem (benthos, phytoplankton, zoo-plankton, fish)andshoreline erosion.Preoperational surveysbeganin1966.Until1970,theyweresporadicandconsisted mainlyofphytoplankton enumerations andsomebenthosandzooplankton enumerations. Between1970and1972,seasonalsurveys,primarily ofphytoplankton andsecondarily ofzooplankton andbenthos,wereconducted. Beginning in19'72andcontinuing iltto1982,samplingfrequency andintensity increased andequaleffortwasgiventostudiesofphytoplankton, zooplankton, andbenthos.Fisherystudiesbeganin1972.Theyrepresented roughly50oloofthestudyeffortbetween1973and1982.Until1974,allstudieswerecarriedoutonnearshore southeastern LakeMichigan. ln1974,preliminary studiesoftheentrainment oforganisms throughtheplantandtheirimpingement ontheplant'straveling screensbegan.Whenunit1oftheplantbecameoperational in1975,full-scale entrainment studiesofphytoplankton, zoo-IIVTRODUCTlON 3PITAKEStdepttrS)SOUTHDISCHARGE tdepth~6m) IIORTHDISCHARGE tdeptli6m)LcdAtichipnTRASHBARSWIT2DISCHARGE FOREBAYTRAVELING SCREEIISptTAKEFOREtutftetII876SesTICIRCILATPIQ TERPINPSPITAKESALPUIIGLOCATIOIIS IIUNTIOSCHARGEFOREBAYDISCHARGE AAIAPLPIG CONDENSER WIT2COIE)ENSER LNITIFIGURE2.Schematic representation oftheDonaldC.CookhluclearPlantcircu-latingwatersystem.plankton, benthos,fisheggs,andfishlarvaebegan.Atthesametime,impingement offishandbenthosonthetraveling screenswasmonitored. Allfieldstudiesceasedin1982.Thisbookrepresents thehighlights ofthefindingsfromtheimpactstudy.Fordetailsofeachfacetofthestudy,thereaderisreferredtothelistofallprojectreports(TableI).Theseareavailable uponrequest.y),y).d)tTABLEl.ReportsontheDonaldC.CookNuclearPlantenvironmental impactstudy.Ayers,J.C.,andJ.C.K.Huang.1967.Generalstudies.PartI,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.31pp.Ayers,J.C.,A.E.Strong,C.F.Powers,andR.Rossmann. 1967.Studiesoflocalwindsandalongshore currents. PartII,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.45ppAyers.J.C.,R.F.Anderson, N.W.O'ara,andC.Kidd.1970.CookPlantpreaperational studiesl969.PartIV,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.92pp.Ayers,J.C..D.E.Arnold,R.F.Anderson, andH.K.Soo.1971.CookPlantpreaperational sludiesl970.PartVII,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.85pp.Ayers.J.C.,N.W.O'ara,andW.L.Yocum.1971.fYinteroperations 1970-1971. Part

4D.C.COOKNUCLEARPLANTIMPACTVill.BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.41pp.Ayers,J.C..W.L.Yocum,H.K.Soo,T.W.Bottrell, S.C.Mozley,andL.C.Garcia.1971.Thebiological surveyof10July1970.PartIX,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision. TheUniversity ofMichigan, AnnArbor,Mich.72pp.Ayers,J.C.,H.K.Soo,andW.L.Yocum.1972.CookPlantpreoperational studies1971.PartX,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.152pp.Ayers,J.C.,andW.L.Yocum.1972.IVinteroperations 1971-1972. PartXI,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.26pp.Ayers,J.C.;andE.Seibel(eds.).1973.CookPlantpreoperational studies1972.PartXlll.BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.281pp.Ayers,J.C.,W.L.Yocum,andE.Seibel.1973.IYinteroperations 1972-1973. PartXIV,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.22pp.Ayers.J.C.,S.C.Mozley,andJ.C.Roth.1973.Thebiological surveyof12iVovember 1970.PartXV,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.69pp.Ayers,J.C.,andE.Seibel(eds.).1973.ProgramofaquaticstudiesrelatedtotheDonaldC.CookNuclearPlant.PartXVII,BentonHarborPowerPlantLimnological Studies,Spe-cialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.57pp.Ayers.J.C.,S.C.Mozley,andJ.A.Stewart.1974.Theseasonalbiological surveysof1971.PartXIX,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.181pp.Ayers,J.C.1975.Bacteriaandphytoplankton oftheseasonalsurveysof1972and1973.PartXXI,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.153pp.Ayers,J.C.1975.Thephytoplankton oftheCookPlantmonthlyminimalsurveysduringthepreoperational years1972,1973and1974.SpecialReport59,GreatLakesResearchDivi-sion,TheUniversity ofMichigan, AnnArbor,Mich.51pp.Ayers.J.C.,N.V.Southwick, andD.G.Robinson. 1977.Phytoplankton oftheseasonalsurveysof1974and197Sandinitialpre-vs.post-operational comparisons atCookNuclearPlant.PartXXIII,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.279pp.Ayers,J.C.1978.Phytoplankton oftheseasonalsurveysof1976,ofSeptember 1970,andpre-vs.post-operational comparison atCookNuclearPlant.PartXXV,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.258pp.Ayers,J.C.,andS.J.Wiley.1979.Phytoplankton oftheseasonalsurveysof1977,andfurtherpre-vs.post-operational comparisons atCookNuclearPlant.PartXXVII,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision. TheUniversity ofMichigan, AnnArbor,Mich.92pp.,plusAppendixof3microfiche cards(122pp.).Ayers,J.C.,andL.E.Feldt.1982.Phytoplankton oftheseasonalsurveysof1978and1979,andfurtherpre-vs.post-operational comparisons atCookNuclearPlant.PartXXIX,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.70pp.,plusAppendi-cesof9microfiche cards(256pp.).Ayers,J.C.,andL.E.Feldt.1983.Phytoplankton oftheseasonalsurveysof1980,1981,andApril1982andfurtherpre-vs.postoperational comparisons atCookNuclearPlant.Part INTRODUCTION 5"l.ataltktlh.nd>ofhendonchf379,IX,kesidt-XXXI,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.91pp.,plusAppendi-cesof5microfiche cards(268pp.).Barres,J.,L.Feldt,W.Chang,andR.Rossmann. 1984.Entrainment ofphytoplank(on attheDonaldC.CooklVuclearPlant-1980-19B2. PartXXXII,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUni-versityofMichigan, AnnArbor,Mich.92pp.,plusAppendices of7microfiche cards(486pp).Bimber,D.L.,M.Perrone,Jr.,1.Noguchi,andD.J.Jude.1984.Fielddistribution andentrainment offishlarvaeandeggsattheDonaldC.CookNuclearPowerPlant,south-easternLakeMichigan, 1973-1979. Special-Report 105.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.320pp.Chang,W.,R.Rossmann, J.Pappas,andW.L.Yocum.1981.En(rainmen( ofphyto-planktonat(heDonaldC.CookNuclearPlant-1978. PartXXVlll,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.106pp.,plusAppendixof4microfiche cards(180pp.).Chang,W.Y.B.,andM.S.Shahraray. 1986.Interactive databasemanagemen( systemforecological studiesrela(edtotheDonaldC.Cook¹clearPowerPlant.SpecialReport119.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.158pp.Dorr,J.A.,III,andT.J.Miller.1975.Underwater opera(ionsin southeastern LakeMichiganneartheDonaldC.Cook(VuclearPlantduring1974.PartXXII,-Benton HarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUni-versityofMichigan, AnnArbor,Mich.32pp.Dorr,J.A.,lll,andD.J.Jude.1986.Diverassessment of(heinshoresou(heastern LakeMichiganenvironment neartheD.C.CookiVuclearPlant,1973-82.SpecialReport120.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.Evans,M.S.1975.The1975preoperational zooplank(on investigations relativetotheDonaldC.CookNuclearPowerPlant.SpecialReport58.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.187pp.Evans,M.S.,T.E.Wurstcr,andB.E.Hawkins.1978.The1975and1976operational

ooplankton inves(igations relativetotheDonaldC.CookiVuctearPowerPlam,withtestsforplanteffects(1971-197(f).

SpecialReport64.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.166pp.,plusAppendixof4microfiche cards(236pp.).Evans,M.S.,D.W.Sell,andD.I.Page.1982.Zooplankton studiesin 1977and1978at'theDonaldC.CookNuclearPowerPlant;comparisons ofpreoperational (1971-/974) andopera(ional (197$-1978)population chare(eristics. SpecialReport89.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.235pp.,plusAppendixof5microfiche cards(222pp.).Evans,M.S.,G.J.Warren,D.I.Page,andL.F.Flath.1986.Zooplankton studiesattheDonaldC.CookNuclearPowerPlant:1979-1982 investigations including preoperational (1971-1974) andoperational (1975-1982) comparisons. SpecialReport111.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.Johnston, E.M.1973.Effectofathermaldischarge onbenthospopulations: Statistical methodsforassessing theimpactoftheCookNuclearPlant.PartXVIII,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan. AnnArbor,Mich.20pp.Johnston. E.M.1974.Statistical po~erofaproposedmethodfordetecting theeffectofwasteheatonbenthospopulations. PartXX,BentonHarborPowerPlantLimnological Studies,Specia!Report44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.29pp.Jude,D.J-,T.W.Bottrell, J.A.DorrIII,andT.J.Miller.1973.S(udiesofthefishpopulation neartheDonaldC.CookNuclearpowerplant,1972.PartXlt,Benton 6D.C.COOKNUCLEARPLANTIMPACTHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.115pp.Jude,D.J.,F.J.Tcsar,J.A.DorrIII,T.J.Miller,P.J.Rago,andD.J.Stewart.1975.InshoreLakeMichiganfishpopulations neartheDonaldC.CookNuclearPowerPlan(,l973.SpecialReport52.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.267pp.Jude,D.J.,F.J.Tesar,J.C.Tomlinson, T.J.Miller,N.J.Thurber,G.G.Godun,andJ.A.Dorrlll.1979.InshoreLakeMichiganfishpopulations neartheD.C.CookNuclearPlan(duringpreopera(ional years-l973,l974.SpecialReport71.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.529pp.Kidd,C.C.1970.Pontoporcia affinis(Crus(acea, Amphipoda) asamoni(orofradionuclides released(oLakeMichigan. PartVI,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.71pp.Krezoski, J.R.1969.Someeffectsofpowerplantwas(eheatontheecologyofLakeMichi-gan.Partlll,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.78pp.LaDronka, R.M.1984.Oligochae(a. Part3:Ecologyofthezoobenthos ofsoutheastern LakeMichiganneartheD.C.CookNuclearPowerPlant.SpecialReport103.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.290pp.Lauritsen, D.D.,andD.S.White.1981.Compara(ives(udies ofthezoobenthos ofana(uralandaman-maderockyhabi(a(ontheeas(em'shore ofLakeMichigan. SpecialReport74.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.65pp.Mozley,S.C.1975.Preopera(ional investigations ofzoobenthos insoutheastern LakeMichi-ganneartheCookNuclearPlan(.SpecialReport56.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.132pp.Noguchi,L.S.,D.L.Bimber,H.T.Tin,P.J.Mansfield, andD.J.Jude.1985.Fielddis(ribu(ion anden(rainmen( offishlarvaeandeggsa((heDonaldC.CookNuclearPowerPlant,sou(heas(em LakeMichigan, l980-l982. SpecialRcport116.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.251pp.O'ara,N.W.,R.F.Anderson, W.L.Yocum,andJ.C.Ayers.1970.Winteropera(ions, Marchl970.PartV,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, ThcUniversity ofMichigan, AnnArbor,Mich.17pp.Rossmann, R.1975.Chemis(ry ofnearshore sur/icial sediments fromsou(heas(em LakeMichigan. SpecialReport57.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.62pp.Rossmann, R.,N.M.Miller,andD.G.Robinson. 1977.Entrainment ofphy(oplank(on a(theDonaldC.CookNuclearPlan(-l97S. PartXXIV,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.265pp.Rossmann, R.,L.D.Damaske,andN.M.Miller.1979.Entrainment ofphy(oplank(on a(theDonaldC.CookNuclearPlan(-l976. PartXXVI,BentonHarborPowerPlantLimno-logicalStudies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.88pp.,plusAppendixof3microfiche cards(154pp.).Rossmann, R.,W.Chang,L.D.Damaske,andW.L.Yocum.1980.Entrainment ofphy(o-plank(ona(theDonaldC.CookNuclearPlan(-/977. SpecialReport67.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.180pp.,plusAppendixof2microfiche cards(118pp.).Rossmann, R.,W.Chang,andJ.Barres.1982.En(rainmen( ofphy(oplank(on a(theDonaldC.CookNuclearPlan(-l979. PartXXX,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor.Mich.98pp.,plusAppendixof4microfiche cards(156pp.).Seibel,E..J.C.Roth,J.A.Stewart,S.L.Williams. 1973.Psammoli((oral inves(iga(ion 1972.PartXVI,BentonHarborPowerPlantLimnological Studies,SpecialReport44.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.63pp. INTRODUCTION 7.rch>75.znt,Xnnandookikcsideslies,Annchi-rcat.akcskes'uralThe~ield~iwerarch~ns,pof'tPP,akegan,inat'lant:rsityrtthemno-tyof)hyto-akescndixScibcl,E.,andJ.C.Ayers(cds.).1974.Thebiological,

chemical, andphysicalcharacter ofLakeMichiganinthevicinityof(heDonaldC.CookNuclearPlant.SpecialReport51.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.475pp.Scibcl,E.,C.T.Carlson,andJ.W.Maresca,Jr.1975.Lakeandshoreiceconditions onsoutheastern LakeMichiganinthevicinityoftheDonaldC.CookNuclearPlant:~interl973-74.SpecialReport55.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.62pp.Tcsar,F.J.,andD.J.Jude.1985.Adul(andjuvenilefishpopulations ofinshoresoutheast-ernLakeMichiganneartheCookNuclearPowerPlantduringl973-82.SpecialReport106.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.94pp.,plusAppendices of5microfiche cards(301pp.).Tesar,F.J.,D.Einhousc, H.T.Tin,D.L.Bimber,andD.J.Jude.1985.Adultandjuvenilefishpopulations neartheD.C.CookNuclearPowerPlantsoutheastern LakeMichiganduringpreoperational (I973-74) andoperational (l97$-79)years.SpecialReport109.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.341pp.Thurber,N..andD.J.Jude.1984.Impingement lossesattheD.C.CookiVuclearPlantduringl975-l979 withadiscussion offac(orsresponsible andrela(ionships tofieldcatches.SpecialReport104.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.24pp.,plusAppendix(75pp.).Thurber,N.,andD.J.Jude.1985.Impingement lossesattheD.C.CooklVuclearPlantduringl975-l982 withadiscussion offactorsresponsible andpossibleimpac(onlocalpopulations.

SpecialReport115.GreatLakesResearchDivision, TheUniversity ofMichi-gan,AnnArbor,Mich.70pp.,plusAppendix(88pp.).White,D.S.,andM.H.Winncll.1986.Introduction. Part1:Ecologyofthezoobenthos ofsoutheastern LakeMichigannearthcD.C.CookNuclearPovverPlant.SpecialReport122.GreatLakesResearchDivision, ThcUniversity ofMichigan. AnnArbor,Mich.Winncll,M.H.1984.Malacostraca (Amphipoda, Mysidacea, Isopoda,andDecapoda). Part5:Ecologyofthezoobenthos ofsoutheastern LakeMichiganneartheD.C.CookNuclearPowerPlant.SpecialReport99.GreatLakesResearchDivision, TheUniversity ofMichi-gan,AnnArbor,Mich.94pp.Winncll,M.H.1984.Chironomidae (andotherDiptera). Part6:Ecologyofthezoobenthos ofsoutheastern LakeMichiganneartheD.C.CookNuclearPouterPlant.SpecialReport100.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.177pp.Zawacki,C.M.1985.Minortaxa(Hydrozoa, Turbellaria, Hirudinea, Arachnoidea, non-Dip(eraninsects,Gastropoda, andzoobenthic meiofauna). Part2:Ecologyofthezooben-thosofsoutheastern LakeMichiganneartheD.C.CookNuclearPowerPlant.SpecialReport112.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.201pp.Zdeba,T.W.,andD.S.White.1985.Pisidiidae. Part4:Ecologyofthezoobenthos ofsoutheastern LakeMichiganneartheD.C.CookNuclearPowerPlant.SpecialReport113.GreatLakesResearchDivision, TheUniversity ofMichigan, AnnArbor,Mich.85pp.onaldagicaluigan.at,)PPThisbookhasbeenstructured sothateachchapterdealingwithaspecificfacetofthestudywillbecompleteinitself,andcanbereadasaseparateentitybythosewhowish.Tofamiliarize thereaderwiththeregionofsoutheastern LakeMichiganwheretheplantissituated, adescription ofthearea'scharacteristics follows. 8D.C.COOKhIUCLEARPLANTIMPACTDepthContoursINTERVAL= 2hKTERSSXJOSEPH~12~4DONALDC.COOKNUCLEARPLANTFIGURE3.Bathymetry ofnearshore southeastern LakeMichigan. DESCRIPTION OFTHESOUTHEASTERN LAKEMICHIGANREGIONLAKEBOTTOMTOPOGRAPHY Thetopography ofthelakebottomwithintheregionofstudyslopestowardthenorthwest withgreatestdepthsinexcessof38m(Fig.3).Atdepthsgreaterthan20m,aseriesofridgesandrunnelsperpendicular toshoreoccurs(Rossmann 1975).

INTRODUCTION 9Theridgesconsistofcoarsersediments thantherunnels(Rossmann andSeibel1977).Neartheshoreline, oneephemeral andtwopermanent sandbarsexist(Seibeletal.1976).Theephemeral barislocatedapproximately 47mfromtheshoreline. Theinnerandouterpermanent barsarelocated116and216mfromtheshoreline, respectively. Waterdepthsbetweentheinnerbarandshoreline andbetweenthetwopermanent barsare1.5to1.8mand3.7to4.0m,respectively (AyersandHuang1967).Thedepthofwateroverthecrestoftheinnerbaris1.2mandthatovertheouterbaris2.6m.SEDIMENTS Sediments varyfromcoarsetofinequartzsandsattheshoreline tocarbonate-rich veryfinesandsandsiltsoffshore{Rossmann andSeibel1977).Thesediments arederivedfromsanddunesandunconsolidated bluffsalongtheshoreline (Hands1970).Thebluffsareclay-rich andcontaincarbonates (Rossmann 1975).Duringtheearlytomid-l970s, severeshoreline erosionoccurredwithinthestudyarea(Davisetal.1973,Tanner1975).Materialderivedfromthiserosionaswellasfromrainrunoffandstreamtransport isresuspended andsortedbywavesandcurrents(SlyandThomas1974).Materials arefinallydeposited offshorewherewavesandcur-rentsareincapable oftransporting themfarther.CURRENTSThemajorlakecurrentwithintheregionofLakeMichiganiscalledtheBentonHarboreddy.Thiseddymovesinaclockwise direction withcurrentsmovingsouth-westwardalongtheshoreline (Ayersetal.1958,Bellaire1964).Inshoreofthiseddy,acounterclockwise eddywithcurrentsmovingnortheastward adjacenttotheshore-linewastentatively identified byAyersetal.{1958).BetweenMayandNovember, currentdirection betweentheinnerandoutersandbarsispredominantly tothenorthwest. Direction wasalwaystothenorth,north-west,orwestbetweenMayandJulyregardless ofwinddirection (Ayersetal.1967).Beginning inAugustwhenthewindwasbriskfromnortherly directions, currentsmovinginasouthward direction begantooccurwithincreased frequency. Smallervelocityandfrequency ofnortherly windswererequiredtoproducesouthward currentslaterinthefall.ForthemonthsofMaythroughOctoberin1967,over86Voofthetimecurrentdirection betweenthetwobarswasnorthward. Monthlymeancurrentvelocities rangedbetween31.7and69.8cm/sec.Inshoreoftheinnersandbar,currentdirection iscontrolled bywinddirection. Waterbetweenthebeachandinnerbarispostulated tobewaterspilledovertheinnerbarduringsurfaction.Itiscutofffromthemain-lake circulation bytheinnerbarandismovedinadownwinddirection (Ayersetal.1967).1the17WAVESWaveobservations havebeenreportedbyLiuandHousley(1969)forSt.Joseph,Michigan(Fig.1).Fortheperiodsof28September 1966to16December1966and21 10D.C.COOKNUCLEARPLANTIMPACTSeptember 1967to30December1967,maximumobservedwaveheightwasbetween3.6and3.0m.Maximumwaveperiodwasbetween7and8seconds.Themostfrequentwaveheightandperiodwere0.6to1.3mand5to6seconds,respectively. Wavesmostoftenapproached theshoreline fromthenorthwest orsouthwest. LOCALWINDSBaseduponobservations during1967,surfacewindsadjacenttotheshoreline aregreatlyinfluenced byabluffofsanddunes61mfromtheshoreline thatparalleltheshoreandruninanorth-northeast tosouth-southwest direction (Ayersetal.1967).Thesedunesservetoprotectnearshore watersfromwindsfromnorth-northeast, aroundthrougheastandsouth,tosouth-southwest. Theyalsochannelwindsfromnortherly andsoutherly directions intoaNNE-SSWdirection. BetweenMayandmid-November themostoftenrecordedwindswerefromtheNNE(14.2o/oofthetime)andSSW(22.6o/oofthetime).Averagewindvelocityrangedfrom9km/hinJuneto16km/hinNovember. Generalprevailing windsfortheregionarefromwesterlydirections throughout theyear.THERMALCYCLEOFWATERCOLUMNTheexacttimeofoccurrence ofvariouseventsinthethermalcycleisdependent upontherateatwhichthelakewarmsaswellastheseverityofawinter.Warmingofnearshore watersbeginsinspringwithsnowmeltandspringrains.Aslakewaterswarm,anearshore thermalbardevelopswhichisdelineated bythe4'Cisotherm. Asthelakecontinues towarm,thethermalbarprogresses fartheroffshore. Thether-malbarwasusuallyfoundwithinthestudyareaduringApril.Eventually, thethermalbarmovesoutofthestudyareaandathermally stratified watercolumndevelops. ThisusuallyoccursinMayorveryearlyJune.Thermalstratification usuallycontinues intoandoccasionally throughNovember. Forthecalendaryear,surfacewatertemperatures rangebetweenI.land26.9'C,whilethoseofthehypolimnion rangebetween5.0and6.5'C.Duringstratification, upwellings ofhypolimnion waterwithtemperatures aslowas6'Carecommonalongtheshoreline. Exceptduringupwellings, waterdepths((45.m)inthestudyareawereonlygreatenoughtopermitsamplinghypolimnetic wateratthosestationsfarthestoffshore. LITERATURE CITEDAyers,J.C.,D.C.Chandler, G.H.Lauff,C.F.Powers,andE.B.Henson.1958.CurrenlsandwafermassesofLakeMichigan. Publ.No.3,GreatLakesRes.Div.,Univ.Michigan, 116pp.Ayers,J.C.,andJ.C.K.Huang.1967.Ben(onHarborpowerplantstudies,PartI.Generalstudies.Spec.Rep.No.44,GreatLakesRes.Div.,Univ.Michigan, 37pp.Ayers,J.C.,A.E.Strong,C.F.Powers,andR.Rossmann. 1967.BentonHarborpowerplantstudies,PartII.Studiesoflocalwindsandalongshore currents. Spec.Rep.No.44,GreatLakesRes.Div.,Univ.Michigan, 20pp.

INTRODUCTION cIInstrete).t,mid>e~nnafrsXsBellaire, F.R.1964.Acomparison ofmethodsofcurrentdeterminations. InProc.7(hConf.GreatLakesRes.,pp.171-178GreatLakesRes.Div.,Univ.Michigan. Davis,R.A.,E.Seibel,andW.T.Fox.1973.CoastalerosionineasternLakeMichigan-causes andeffects.InProc.16thConf.GreatLakesRes.,pp.404-412.Internat. Assoc.GreatLakesRes.Hands,E.B.1970.Ageomorphic mapofLakeMichiganshoreline. InProc.16thConf.GreatLakesRes.,pp.250-265.Internat. Assoc.GreatLakesRes.Indiana&MichiganElectricCompanyandIndiana&MichiganPowerCompany.1973.Finalenvironmental statement relatedtooperation ofDonaldC.CookNuclearPlantUnitsIand2.Liu,P.D.,andJ.G.Housley.1969.Visualwaveobservations along'theLakeMichiganshore.InProc.12thConf.GreatLakesRes.,pp.608-621.Internat. Assoc.GreatLakesRes.Rossmann, R.1975.Chemisrry ofnearshore surficial sediments fromsoutheastern LakeMichigan. Spec.Rep.No.57,GreatLakesRes.Div.,Univ.Michigan, 62pp.Rossmann, R.,andE.Seibel.1977.Surficial sedimentredistribution bywaveenergy:element-grain sizerelationships. J.GreatLakesRes.3:258-262. Seibel,E.,C.T.Carlson,andJ.W.Maresca,Jr.1976.Iceridgeformation: proba-blecontrolbynearshore bars.J.GreatLakesRes.2:384-392. Sly,P.G.,andR.L.Thomas.1974.Reviewofgeological researchasitrelatestoanunderstanding ofGreatLakeslimnology. J.FishRes.BoardCan.31:795-825. Tanner,F.W.1975.Beachprocesses, BerrienCounty,Michigan. J.GreatLakesRes.I:171-178. .Ie1,ny15 SEEINSTRUCTIONS ONREVERSESIDESECTIONIEPAI.D.NUMBER MID0964761PERMITNUMBER~M10005827'APPLICATION FORDISCHARGE PERMITIS:tsm[FITIONEXITINGhEMItKREASED USEREISSIAIICE 0DHITEM1PHYSICALLOCATIONADDRESSC.PLAIITORFACILITYDCC00KPLANTD.TYPECFFACILITYSTMELECTREsSTANDARDINDUSTRI)[L C[ASSIFICATION(REFERTOTABLEII)GEN~qgfeSTREETtlHKRG~STREETBVKCOOKPLACEAP~~~~~'~~'ER INDIANAMICIGANPOWERCOMPNYB.DIV.i[NREAU NAANDINFORMATION HsCllY[[A%BRIDGMANJsTCWNSHIPLAKELeNA%OFAUDCRIZED CONTACTPERSONMlK>>CXNIY(REFERTOTABLEI)BERRIENHsTITLEI~ZIPCODE49106CO.IAPBER~>DONALDLBAKR O.AXRESS(IFDIFFERENT FR[V[ABOVE)NVAFFAIRSIR219~42~21PsCITYRVKFORTWAYEPOBOX60OeSTATEReZIPGXK468015~lYPEOFTREATMENT FACILITY(REFERTOTABLEll)~lL~ltr~2K~3A~4Gl'PROGRAMFOREFFECTIVE RES[DIALS HANAGE%WDATESLBHITTED YESCItaHN.A.DATEltPLEPENTED U>>BACK~POwERQXRCEYESMNAeVsPOLLUTION INCIDENTPREVENTION PLANDATESINVIITTED XVEStDNADATE[~[TED11/15/92MetltVIEROFEIVNJIVEES X.TYPEOFDISCIARGE ~~QQxYeDOYOUHAVEACERTIFIED OPERATOR? ElYESCIteD.M.FITZGERALD ee4~309~70~4802ITEM2MAILINGADDRESSOFAPPLICANT AsW%RCMENGEBet4VKINDIANAMICHIGANPOWERCMPCSTREET,AXRESS CRPOSTOFFICEBOXPBO60DeCllYt4V%FORTWAYNE PEOulDEOStctthrttt2E EeSTATEF>>ZIPCODEI.thedDDI[cant. cettllyunderpenaltyotIavthatIhavepersonalty erdhlnedanddmtdmltlat'lththeIntormatlon submitted InthisdDDtlcatt, andalIattachments anothat,basedonmyInoulryotthoseIndlvldudts Immediately respon51ble totobtalnlng theIntormatlon, Ibelievettdtttelhtormatlon Istrue,accurateandcomplete. Idmdvarethattheredre5[obit[cant petldlties'tor5ubmlttlng tdt5eIntotmdtloh Ihcludlflo DD55[biIItyottinednoImprlsotvsent. SIGNATURE OFAPPLICANT 3aoR4-SIGNATURE OFLOCALGOVERNMENTAL REPRESENTATIVE (SEENOTEONREVERSESIDE)R-C.MENGE.PRESIDENT T[TLEI15 SEEINSTRUCTIONS ONREVERSESIDESECTIONIRMIT~I0ITEM3SOURCEOFWATERSUPPLYAMWICI?AL3.SDRFiVEnATERIt>>AXEC~-FIXATEnEU.O.CT>IERNAMECFITATERHAV .M~>TlTY;>AX.).MAX.)DoorFuLAKET0NSIHIIPNAINIAr~>CJS/SAYC'LLOlJS/OAY IQALLrIts/r~yLAKEIMICHIIGANIITEiVI4L>>tITI>YIŽAX.)-maSS'ATER(IIICLUOrrts COITACT:OOLIlJOn'ER):!jAIJTITY>MAX.)B.'CttCOIITACT COOLItlG'nATERYTITY(uAX,)GAL>>XIS/CAY 63>4400OAI>ctq/n~y 2>642112000oAuotB/~y FACILITYWATERUSAGEC.SARITARY'>JATERDOTIERAJAttTITYI>SAX.)OUAttTTY(MAX.)FI60000CAL>>xts/BAY PROTE.CTIONWIT3600000oALLctts/BAy lTEM5CRITICALMATERIALS &PRIORITYPOLLUTANTSCCIJJ~IMJETIIE;,~EOFSUBSTAtJCE PARAMETER IAPZERCUAIITITyNA%OFSUBSTANCE PARA%TERtlH3ERCUANTITYHYDRAZINE Aueous0030201247oo<~ivySODIUMHYPOCHLORITE (12%)CLASS014ITS64894USEDSTOREDPRODUCEDREFERTOTABLESIVS>VttA"EOFSUBSTAlJCE PARA%TERtlPBERSIPUITITYMJREITERt>Lt%ER'U>UITITY:~OFSUBSTAIJCE XYLENETOLUENEOtl3>30207163T~/YEAR001088,8<tgTs699~1/YEARJlHlL'iCQE IPOUNDS2GALLONS3CUBICYARDS4TONSl>JIOIMJII:RUEOFit>MTAIJCE P~'%ac;R:AtSER QUAtttIlyttŽEOFSUBSTAttcE PARE>E.RIAPBERrRUAIITI>Yi""ECFSLBSTAIJCE DARAtETER:ltS>ERCLASS02HYDROUINONEITSIL/veMERCURY+ITS/YEARUNITSLLI/YEARLITHIUMasLITHIUMHYDROXIDE 17 ")$<<~at3<<"a3<<>>:I'/>>a><<r~I3'5<<aQtsa<<~r<<03<<II<<I$ 5ana3va3~<<'rI~e<<5$,ngru)3<<e,aronie5$e>><<3erIa=Iver,cr<<neItva~vra~~7"~I'c3>>3e5>>>>>p4aer<<3'r'3ere>>$3t<<a>>3I3ara3>>lnIa<<5<<<<ar<<<<aII5T"louhTSf<<atertooeu5ec>orvarIcusurcses351o"ccessTater-seeG>cssarv!Orceflnltrcr:ace -'-).'~nccntact "colin>><<hater -seeGl=ssarv3"Ta'I-:Tlc":oace C.).l<<nlta>>vaster<<ster]seararIrasI~r.5a$:a...Irat5,3~na5,Ir<<ars.sterls"rs-<<sea'cr3ecarcase3-r-"e5aaer135'.5ecrere)r.3ec'nr3e3--"5o-"erC.rccses, '"crea<<e-"evo>urei<<5.es',<<,ar,see're<<3e3,.:'-3r3a.=.qi)-e'3aI'-131>V~sar33rnacnta.:31'-3*3-er:-=en3$$$$<<ae,a:3>>'aar,eI3eI3$5<<e~Inoulcerut>>lsaoollcaTlcn ~:vCI'fereqce 1-ese-!Sls3culCeev>>Iainecrrsr3acqea3eetcfITiv5Tr"ATE~IAu5O'A)O'RIGIDITY ~1>>UT3~5rST3IICne)aal3COSTanceS <<nlCOareI-"In)C3-'3,>>.'-IC31 "sterl3IS cec)Stn"!Cle'>33ce"'>>a/Cr..8.=33'5arICr:tV=O>1utant I.esttaoleV(oace7)3'ratsrecurren.>V <<sea.storea~croroauceaOvTn)5>aaliIITv. 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".call".,dater-SeeGlcssarv'crseflnltlcc lsa>>te54lI'~ea'r"5959!l551<"5'<<45~5.4'""5-.595'5-:-e:;rccse 1-c--9sa>>e'll'al1439l'5"5%l"455*d>>4>>'55e9~le~494>>r59591~1a')4>>')I'(le>>]43154'54'Clc9~5~al54>>a!I.'1aI'r"aqa9SseI5~~5%edt5T3'.Mlol35.Ssala~of'9""111'l1'lterr"5+is-9".".lel",'.:Sce.'".4a/cr.~'I"IB~355I."I.I"..I.I.'5'I=.=-59"Icrltv SEEINSTRUCTIONS ONREVERSESIDESECTIONIPERMIT-~HI0005827ITEM3SOURCEOFWATERSUPPLYA~WNICIPALS.SURFACEHATERINTAXEC~PRIVATE'nELLD.OTHER~mTVI"'tA'BCFWLTERHAVrOAt(TITY (FAX.)".ttAt(TITV(~AX.)ITEM4FAGILITYWATERUSAGEITEM5CoSAN!TARTHATERDeOTIEROUANTITY(~)t~'6OFS(MTANCEOUANTTV(t(AX.)IOUANTITYO(IAt(TITY (tAX.)A.PRXESSHATER'(IttCLUDI% COt(TACTCOOL(taHATER).UANTITV(>AX~8~tQNCOt(TACT CCCEIt6HATER~VTITY(FAX,)0-Dichlorobenzene 00095501*OAuONS/DAV CALLO(IS/DAV acus(S/DAY CRITICALMATERIALS PRIORITYPOLLUTANTS USEDSTOREDPRODUCEDREFERTOTABLESIvavCCwc@tX+CCCUJ6)ICC~@tedNA%OFSUBSTANCE PARAIKTER MtBERouNITIlYOUMIIITVNA%OFS(BSTANCE PARA%TERhVSEROUANTtTYNAtEOFSUBSTAtCE AntimonPotassium TartratePentachloro henolLSITSLLI/YEARCLQt(TSM/YEARTrihen1hoshateEHC*ut(Ts4~1/YEARPolchlorinated BihenlsPCBIPOUNDS2GALLONS3CUBICYARDS4TONSCCUllANA%OFS(BSTANCE CLASSO84Trixlen1hoshateEHC*X/YEARCCQllO~COWPllYt(A%OFS(BSTAN:E ZincCLASS084u(ITs21000~1/YEARPARA%TERtAPBERIOOANTITVCLASS027WITS2700*Hydraulic Fluid ~Q~"Is'-r.-<<Cui-es4nfo~aticn aocut7-e<<ater)coiv-".<<5~)oilI)V,-e':"4(-v'5<<ate<<.sace.-'*-nssec5-r<<3-r)r""""e"---'S""'I:tv'<<el~)ls~f)(<<~"~($'l"-,u)TI(ivgc<q8pg:4',(<<vlc5'~l*<<<<<<I'e<<e3ve>~g4c<<<<roar<<a(if<<55("ace)<<I<<~uc'ate,(esIe<<<<e4Ie~(e45i~pP4<<<<<<ater<<<<<<~~<<I<<<<<<tI54~)<<<<5'<<ate<<~)e<<'S<<t<<<<<<Sa<<~>~3C~>r<<r<<S0545<<<<~~<<-arona(ver,crtneGitvofM(IIOCnc.:5t)"cunt)ctater-."Ceusec'o(v3rlouscurccses35crccessna<<er-seeGiossarvforceflni-Icn (cace38).'.once;-act co(ing<<ate>-seeGlossary'crCeflnlticn (cage38).:anltarvx!ter-Aeteruseofordomesticcurooses( e.o.,-oilet5,Sinks.)rovers.<<ater75'r)tvSecfarcnecuroOSeano7-e5(74e<<ateriS5.3Seouent:V .Se'Cr5-ecr-cre7"er:.r)CSeS. '-)(cae"evolute)<<)]it<<5Qsi)oljsecefPe<<<<<<<<e<<t)c/cr.'c"are.Tcr<<<<5T'e.'<<<<5III4vcsee)5~rcntact3-e"!"c-en)s:css<<ate(,T-eC.ant'-.:-<<aer-,'ven>>-cuic:e'-)ic)-ec )5:-ccess*a.er.<<<<C)nOu4Cao34tneterai'-em.'.Cnvci"tranceir--ese-)tais5-Culcce<<xclalnec I")n<<7-)CseaSneerof-<<ISaccliCTIOn.ITQ48!sT)IIccemicalsucstances <<nicearelnync<<l73n5rltlcal"aterials >eels)a<<able Iy(cace8)anclcr.~.=ca'5orlorltv<<IrbIi>tTableVlaaae7)that6eiei7,~,0IDi~itili SEEINSTRUCTIONS ONREVERSESIDESECTIONIPERMITMNI0005827I'TEMA,rrrrcrprL 3BrStttFACEHA'fERINfAKESOURCEOFWATERSUPPLYC~PRIVATEH'ELLDrOTHERltA%CFWATERWAY(uAX)OUAttflTv(we.)SP~DAYITEM4FACILITYWATERUSAGEITEM5.CRITICALMATERIALS PRIORITYPOLLUTANTS USEDSTOREDPRODUCEDREFERTOTABLESIVBrV1POUNDS2GALLONS3CUBICYARDS4TONStFtEOFSUBSTAttCE Tv(we.)CL'rrrCrtNrrPKOFSLSSTANCE PARAtETER tttSEROUANfllYNA%OFSUBSTANCE PPJJtETER MtSEROUANTllYNAPEOFSIBSTANCE PARt4%TER tAtSEROUANTllYNAPEOFSUBSTAttCE PARA%TERtAteERCCrrrIhrXOUANTITfNAIEOFS%STANCEPARAMETER IAAFrrrrOZOUANfllYoUANrITY(we.)ArPROCESSHATERIIIICUSIt6 COt(TACTaOLItoHATER)CUANTITv(we.B.ICNCONTACT COOLINSWATEROUANTITY(we.)C~SANITARYHATEROUAttfITY(we.)D.OTHEROAuDNS/DAY oAutm/DAY OAuDNS/DAY OAuDttS/DAY BenzeneGasoline000714327000Q/YEARTolueneGasoline00108883UNITS7000~1/YEARXleneGasoline01330207UNITSL1J/YEARUNITS~/YEARUNITS~/YEARUNITSLJ/YEARHAIKOFSISSTAtCE PARA%TERIAt%ERrOUUIfllYUNITSLJ/YEAR ~~cr=gtCTIrhIS PCRCvPLc.I~cE.IC'IIITEMS5,4,AhO5This.'Ormreoui,esit.atlnabcur5<<3~erS"pl'a5gIayorle>>l-vcollu.antsASed,Stored,crproducesat-nfs'llitv.~ewe3C'lV'S<<are>>Sade.SnCC-'-iCSI-3<<e>>ials and3E,'.llT. g.e5i53>>ewcrnotprevtcus<v cer"iecoilitv,-nenITUv8ER"AMEcCU'OC'I-""-nrvI,'W.Irgl';Gleavebianxar-3nurcec<<Iil-eassi"rec.tCatu>>c't<<ATEnSLppivListsli<<atersuppliesused."evol<<emavpeestimated ~roy3<<atersupplv>>eer>>eacings or'ranpiiiincS.are"ants 'ran3ware5<<plIAtlll,v.Iawateris>>.eterec,es,l>>areyrxpumpapacitv.aghere3nseesa%vireo,enter"3>>e"<<3er5ucply;uudLake,HuronRiver,ortheCItyotIAIIlpono.ITEM4PACILITyWATERiJSAGE'istamountsotwaterrobeusedforvariouspurposesas:processgfater-SeeGlossaryfordefinition lpage48)..'lonccntact CoolingWater-SeeGlossarytordefinition <page48).SanitaryWater-Waterusedtordcmesticpurposes; e.g.,toilets,sinxs,shoers.~f<<ateriS.IrStuSedfcrCnepurpOSeandtheSamewateriSSupSeduently SedaarCneCrareOtherpurpOSeS, indlCatetheVclu>>eercavotrheInstce5icnarec usepetorereatrentsnc/ogdischarge. -crRxa>>cie,ig<<aterl5inltlallv usedasnoncontact CCOlln"*aternohen3S->>"CeSS~ater,tneSuanlVCfarer~iVen5"Ouldbeinoioated SSOrOCeSSwater.Thetotalofitem4shouldecualthetotalofitem5.Anydlfterence intheserctalsshouldbeexplaineoinanattachedsheetotthisappllcarlon. ITEM5CRITICALMATERIALS AWOPRIORITYPOLLUTAiITS USED.TCREO.noCOUCEO'StallChemiCalSubatanCeS whiChareInMIChlgan'5 CrltlCaluaterlalS OegISterTableIVIP8ge6)and/OrU.S.EPA'SPrlOrltyhilttlitthiy(egeyitht eetiyd,ed,gaaey;hi~tediiity. SEEINSTRUCTIONS ONREVERSESIDESECTIONIPERMIT~~MI0005827TEM6DESCRIPTION A>>:gyIDEAPRIEFDESCRIPTIQN 4<<ILINEDIAGRAM(5+>INGlbE'<<ATER~'PWMI>>(TCURFACILlTYRCHINTAKE>>QiNATE.-~'.PA>>,l,'.5 ~iiRISUTING>>(ASic>>(AicR>> IllCU<<>>IIIG FHKESSAI<<>>FACDUCTICN AREASi5>><<iITARY FL>>'.>>>>(5>> CQQLING'HATER>>ANDSTQAATERRVCFF~,QU<<AYSAQPSINILARCPERATICNS INTOASINGLEUNIT>>TNEWATERBALA(iCESHDULOQCwAVERAGEFLQWS~SAWALLSIGNIFICANT QSSFS:F<<ATER~F>>~CQUCTS, APQSP(>>ERE>> 4(DDISCNARGE ~YQUSNQLLJUSEAC~>><<EAS(A(EVENTS '~NEVERAVAIlAELEI QTI>>ERNISE USEYQ(RSESTASTI"ATE.[SEEATTACHEDDESCRIPTION] ANODIAGRAM ~<<I85)<<"u8a<<<<t)Cili)y'rt""3<<8,'ISC>)r-* ~<<r"ey'uIa~treave<<I'~J~'tu<<~-ir~-.-i-go'8588<<"<<'8I~Vo<<J<<8)veSC"st'"8)"<<)5O"V<<3<<'t'sc.Ion)<<8Sct'<<,)r~<<.,3<<58<<88<<o<<t-<<.)r"3-,<<.-ersrin5'-~~8<<8<<8-e,oolin),)<<s.)I-'-Ior'i<<8)c3)<<)ec-!33'33'"tcr'ce<<<<cvst3c)'.'0-8tst.8<<8833'5~8<<"3Cf3)u...'SiC"'".43.'.-Sore.8"5"8>>")3Se,3.<<Ocur*8CI"as<<8835353.v8.IVer'5'C'Cut38"8<<8<<)I"YCt'tl.<<5~-)5e5-83~"o<<s-nro'."n3:~""'"er.-8-8)t"~s<<curseser-'es---esc--r,as<<st;cce<<. "e-<<3;ec<<8erI's<<5<<M<88!arl':er anrote<<8<<e'-sot<<<<tlngles <<snccn-ac-ol<<g8~8ro""85rtc'-e."iscon~--leo<<sve<<'5:isc-srsec -".--8B.cv)iver."esi.cce'<<st"-eclari"er-oesro!rscu~"'-8"<<ere'?5Ce<<ave-eo .-83.Cce'S-e<<-S.erCalciumChlorideSulfuricAcid1LimeIPolymerPlatingWastewater 70.000GalionTankAcidification Iieutralization'locculation BatChOuttlps~0umpTank.SludgenickenerClarifier Non-contact CoolingwaterCalciumChlorideyacuumFilterWaterSulfuricAcidI.imeLandfillGondolaSludgeIfanhoIeBuckRive.-".:e.'-;...Ser<<C<<h, an'C-.855leeve383<<":5'Ct'u!Cr"C-Ive a<<c<<<<uc>>encineS.-"CauclcnIS-SeS.Vo<<)*-Ce-5--""8"'-<<'r5---SSe-I5:5~-OncanieC Svei<<C::cser.-<<)-5ss'n--cc5")"etec---.'.-)ce)no.o<<'-g3er3~-srer3).encesnoic've-eiing-e<<al'"-.)ovoer'cr.-8lscctc)haseccnsis:ssfscnering"e~it:e"eraloo<<cer3Scilt3881SVOa))ihc<<8<<05o<<tv"<<'ur<<aceS.ta<<er.Sec-"COIsheSvrlcccnssi.u)85 Ctt<<<<88<<)83<<l5ar<<8"'3<<3<<<<i<<~~<<8)<<5set'"<<)58,55eatlncs~8Ceire)ic<<815.t~8Sr'8C..3388>>I38."8tei<<al"I<<<< sear'8OOITshcI8<<ei'Ie83nC<<aC)~<<,=:nSea-er:<<lore )<<Csf)en-<<8taricuS:33',-g338<<sions cons)iu.es3-e)recess<<).er.Municipal WaterSupplySanitaryFacility30,000gpdNunicipal Treatment Stripei.ine295.000gpdCoolinglfater250.000gpdiiasteTreatment Plant45,000gpdBuckRivePowderNfg.4.000gpdPlatingProcess40,000gpd20 SECTIONI,ITEM6,SUBPARTACont'dOUTFALLDESCRIPTIONS OUTFALL001-Unit1Circulatin WaterDischareOutfall001isanon-contact coolingwaterdischarge. Mostofthenon-contact coolingwaterisusedtocondensethesteamexhausting fromthesteamdriventurbines. Thecondenser coolingwaterisdrawnfromLakeMichigan, screenedtoremovelargeparticles entrained inthewater,routedthroughtheUnit1condensers andthendischarged toLakeMichigan. Outfall001alsoincludesSteamGenerator

Blowdown, PlantHeatingBoiler(described laterasinternalOutfallsOOA,OOBandOOCrespectively),

andtheReverseOsmosis(RO)system(described onpage10).Outfall001alsocontainstheeffluentflowfromtheEssential ServiceWater(ESW)system,Non-Essential ServiceWater(NESW)system,andmonitortankreleases. ESW(20,000GPMmaximum)isLakeMichiganwaterthatisusedtoprovidecoolingtoNuclearRegulatory Commission (NRC)definedsafety-related equipment andasanemergency backupwatersupply.NESW(9000GPMmaximum)isalsoLakeMichiganwaterusedfornon-contact cooling,asasourceofwaterforthedemineralized makeupsystem,andtosupplywaterforNRCdefinednon-safety relatedequipment. Monitortankreleases(-20,000gallonsperevent)areregulated bytheNRCandconsistofwastewatergenerated withintheAuxiliary Buildingthathasbeenprocessed priortobatchdischarge. Thenon-contact coolingwaterforthecirculating watersystem,theESWsystemandtheNESWsystemis.treatedforbiological controlusingliquidsodiumhypochlorite, withtreatments usuallybeginning inMayandterminating inNovember, depending onLakeMichigantemperatures. Thebiocideisaddedattheintakeforebayandtheaverageresidualmeasuredinthedischarge ismaintained atlessthan0.2mg/latOutfall001.Thetreatments lastfornomorethan160minutesperday.Ifcontinuous chlorination isutilized, theresidualmeasuredinthedischarge ismaintained atlessthan0.036mg/latOutfall001. Thissamewaterisperiodically treatedusinganon-oxidizing biocidetoeradicate thecoolingsystemsofzebramussels.Thebiocidesweareconsidering (BetzCT-1,BetzCT-2,BetzCT-4,CalgonH-130M,andNalco9210)areallpolyquats whichwillbedetoxified, asrequiredusingbentonite claytomeetwaterqualitybasedeffluentlimits.Thetreatments aredirectedtothecriticalplantsystemsfromtheintakestructures locatedaboutone-halfmileoutinLakeMichiganthroughtheentireplantcoolingsystem,including theESWandNESWsystems.Systemsaretreateddependent uponzebramusselinfestation. Concentrations andchemicalfeedpointsarechosentominimizetheamountofbiociderequiredandtomaximizethetreatment program.Thesystemsmaybetreatedatthesametimeorindividually toallowmoreefficient useofchemicals. Weplantotreatallsystemswithintheplantamaximumoftwiceperyear(sixapplications peryeartotal)toassuresafeoperation ofthenucleargenerating units.ThecurrentNPDESpermitincludestheuseofsodiumbromideandsodiumhypochlorite solutions fortreatment ofthecirculating watersystems.Thesesolutions, whicharethemajorconstituents ofmanyproprietary mixturessuchasNalcoActi-Brom, arepresently beingconsidered asthebasisoftheCookNuclearPlant'sstrategic plantocontrolzebramussels.Effective useoftheseoxidizing biocidesareexpectedtoreducethefrequency ofnon-oxidizing biocidetreatments. SeeAttachment 3ofthecoverletterformoredetailsregarding ourfuturezebramusselcontrolstrategy. Themonitortanksreceivetreatedwaterfromtheradioactive wasteremovalsystem.OnesystemhandlesthewasteforUnits1and2andtheAuxiliary Building. Thissystemtreatswastesgenerated fromthereactorcoolantpumpsealleakoffs, therefueling cavitywater,equipment leaks,floordrains,valvestemleakoffs, wastesamplesolutions andlaboratory wastesfromtheradiochemistry analysisinthehotchemicallaboratory, systemequipment drains,non-contact coolingwateranddecontamination processes. Thewastesarecollected inoneofseveraltanksandtreatedwhenenoughwateriscollected. Thetreatment utilizeseitheranevaporator systemorademineralizer systemtoremoveradioactive contaminants. Thetreatedwaterisaccumulated inthemonitortanksandsampledtoensurethewastemeetstheNuclearRegulatory Commission radiological requirements priortobeingdischarged intothecirculating watersystem.Periodically, duetoequipment leaksand/orsystemupsets,awastestreamisgenerated thatcontainsradioactively contaminated ethyleneglycolandwater.Thiswaterisprocessed on-sitepriortobeingreleasedtoOutfalls001,002or003.Sulfurhexafluoride gas(SF6)isutilizedinthenon.-contact coolingwatersystemsattheplanttodetectleaksinvariouscomponents suchasthecondensers. Thegasisinjectedinthecoolingwaterstreamanddischarged toOutfalls001,002or003atlessthan54ul/L.Duringupsetconditions itispossibletooverflowthecontentsoftheTurbineRoomSump(seeOutfallOOD)toOutfalls001,002and/or003iftheflowpathtotheon-siteabsorption pondcannotbeused.0tnWter'scareOutfall002isanon-contact coolingwaterdischarge. Mostofthenon-contact coolingwaterisusedtocondensethesteamexhausting fromthesteamdriventurbines. Thecondenser coolingwaterisdrawnfromLakeMichigan, screenedtoremovelargeparticles entrained inthewater,routedthroughtheUnit2condensers andthendischarged toLakeMichigan. Outfall002alsoincludesSteamGenerator

Blowdown, PlantHeatingBoiler(described laterasinternalOutfallsOOA,OOBand00Crespectively),

andtheReverseOsmosis(RO)system(described onpage.10).Outfall002alsocontainstheeffluentflowfromtheEssential ServiceWater(ESW)system,Non-Essential ServiceWater(NESW)system,andmonitortankreleases. ESW(20,000GPMmaximum)isLakeMichiganwaterthatisusedtoprovidecoolingtoNuclearRegulatory Commission (NRC)definedsafety-related equipment andasanemergency backupwatersupply. NESW(9000GPMmaximum)isalsoLakeMichiganwaterusedfornon-contactcooling,asasourceofwaterforthedemineralized makeupsystem,andtosupplywaterforNRCdefinednon-safety relatedequipment. Monitortankreleases(-20,000gallonsperevent)areregulated bytheNRCandconsistofwastewatergenerated withintheAuxiliary Buildingthathasbeenprocessed priortothebatchdischarge. Thenon-contact coolingwaterforthecirculating watersystem,theESWsystemandtheNESWsystemistreatedforbiological controlusingliquidsodiumhypochlorite, withtreatments usuallybeginning inMayandterminating inNovember, depending onLakeMichigantemperatures. Thebiocideisaddedattheintakeforebayandtheaverageresidualmeasuredinthedischarge ismaintained atlessthan0.2mg/latOutfall002.Thetreatments lastfornomorethan160minutesperday.Ifcontinuous chlorination isutilized, theresidualmeasuredinthedischarge ismaintained atlessthan0.036mg/latOutfall002.Thissamewaterisperiodically treatedusinganon-oxidizing biocidetoeradicate thecoolingsystemsofzebramussels.Thebiocidesweareconsidering (BetzCT-1,BetzCT-2,BetzCT-4,CalgonH-130M,andNalco9210)areallpolyquats whichwillbedetoxified asrequired, usingbentonite claytomeetwaterqualitybasedeffluentlimits.Thetreatments aredirectedtothecriticalsystemsfromtheintakestructures locatedaboutone-halfmileoutinLakeMichiganthroughtheentireplantcoolingsystem,including theESWandNESWsystems.Systemsaretreateddependent uponzebramusselinfestation. Concentrations andchemicalfeedpointsarechosentominimizetheamountofbiociderequiredandtomaximizethetreatment program.Thesystemsmaybetreatedatthesametimeorindividually toallowmoreefficient useofchemicals. Weplantotreatallsystemswithintheplantamaximumoftwiceperyear(sixapplications peryeartotal)toassuresafeoperation ofthenucleargenerating units.ThecurrentNPDESpermitincludestheuseofsodiumbromideandsodiumhypochlorite solutions fortreatment ofthecirculating watersystems. Thesesolutions, whicharethemajorconstituents ofmanyproprietary mixturessuchasNalcoActi-Brom, arepresently beingconsidered asthebasisoftheCookNuclearPlant'sstrategic plantocontrolzebramussels.Effective useofthese~xidizing biocidesareexpectedtoreducethefrequency ofnon-oxidizing biocidetreatments. SeeAttachment 3ofthecoverletterformoredetailsregarding ourfuturezebramusselcontrolstrategy. Themonitortanksreceivetreatedwaterfromtheradioactive wasteremovalsystem.OnesystemhandlesthewasteforUnits1and2andtheAuxiliary Building. Thissystemtreatswastesgenerated fromthereactorcoolantpumpsealleakoffs, therefueling cavitywater,equipment leaks,floordrains,valvestemleakoffs, wastesamplesolutions andlaboratory wastesfromtheradiochemistry analysisinthehotchemicallaboratory, systemequipment drains,non-contact coolingwateranddecontamination processes. Thewasteis'collected inoneofseveraltanksandtreatedwhenenoughwateriscollected. Thetreatment utilizeseitheranevaporator systemorademineralizer systemtoremoveradioactive contaminants. Thetreatedwaterisaccumulated inthemonitortanksandsampledtoensurethewastemeetstheNuclearRegulatory Commission radiological requirements priortobeingdischarged intothecirculating watersystem.Periodically, duetoequipment leaksand/orsystemupsets,awastestreamisgenerated thatcontainsradioactively contaminated ethyleneglycolandwater.Thiswaterisprocessed on-sitepriortobeingreleasedto~Outfalls001,002or003.Sulfurhexafluoride gas(SF6)isutilizedinthenon-contact coolingwatersystemsattheplanttodetectleaksinvariouscomponents suchasthecondensers. Thegasisinjectedinthecoolingwaterstreamanddischarged toOutfalls001,002or003atlessthan54ul/L.Duringupsetconditions itispossibletooverflowthecontentsoftheTurbineRoomSump(seeOutfallOOD)toOutfalls001,002and/or003iftheflowpathtotheon-siteabsorption pondcannotbeused. OUTFALL003-DeicinDischareOutfall003isadeicingdischarge whichisusedonalimitedbasis.AportionoftheflowfromOutfall001and/orOutfall002isdirectedthroughthecenterintaketunneltotempertheintakewaterandpreventicebuildupontheintakestructures whichwouldrestrictintakeflow.Useofthisdischarge isgenerally onlyrequiredduringtheperiodfromDecemberthroughAprildepending onwatertemperatures andicebuildupalongtheshoresofLakeMichigan. Thechemicalconstituent ofOutfall003isthesameasOutfalls001and002.OUTFALLOOA-Unit1SteamGenerator BlowdownThesteamgenerators requireultrahighpuritywaterforoperation. Makeupwaterusedinthesteamgenerators iswithdrawn fromtheintakeforebay(orfromLakeTownshipwatersupply)andessentially allnaturalimpurities areremovedthroughsedimentation, filtration, reverseosmosis,anddemineralization. Periodically, impurities enterthesteamgenerators throughsystemcorrosion transport mechanisms, themakeupwater,orsystemupsets(suchascondenser leakage)andmustberemovedtoprotectthesteamturbinesandheattransfersurfacesofthesteamgenerators. Theimpurities areremovedbydrainingaportionofthewaterfrom.thesteamgenerators. Inthesteamgenerator, steamisseparated fromthewater,furtherheated,andthenroutedtotheturbines. Whenthesteamseparates fromthewater,theimpurities remaininthewater,concentrating inthesteamgenerator. Blowdownconsistsoftwoforms,aliquidportion(700GPMmaximum)andawetsteamportionwhichisexhausted totheatmosphere. Theliquidportionofthesteamgenerator blowdownisdischarged tothescreenhouse forebayeitherdirectly, orafterprocessing throughmixedbeddemineralizers. Impurities inthisdischarge mayconsistofinsoluble ironandcopperandattimes,impurities fromthecoolingwater(LakeMichigan) usedtocoolthecondensers. Steamgenerator additives consistofammoniaand/ormonoethanolamine (ETA)forpHadjustment, hydrazine and/orcarbohydrazide foroxygenscavenging, andboricacidforcorrosion protection. .Periodically, sodiumnitriteisusedasatracertodetermine thesteamgenerator blowdownratethrougheachofitsblowdownvalves.Duringunitoutages,thesteamgenerators arestoredfullofwater,including treatment chemicals, toprotectagainstcorrosion duringstorage.Thislayupwaterisintermittently discharged (32,000gallonspersteamgenerator) throughOutfallOOAtoLakeMichigan. Thelayupwatercontainsamaximum.concentration of400ppmhydrazine and/or40ppmcarbohydrazide, 50ppmammoniaand/orETA,and20ppmboron.Thewastestrengthofthisdischarge isreducedthroughmixingwithOutfalls001,002or003bymorethan40,000times.Demineralized waterorsecondary waterisusedtopressurecleanthesteamgenerators duringoutageperiods.Thewaterisrecirculated throughtemporary filterstoremovesuspended solids.Themajorconstituent ofthesuspended solidsisironoxidefromthesteamgenerators. Thewateristhenreturnedtothesteamgenerators anddrainedtoOutfallsOOA,OOB,orOODviatheturbineroomsump.OUTFALLOOB-Unit2SteamGenerator BlowdownThesteamgenerators requireultrahighpuritywaterforoperation. Makeupwaterusedinthesteamgenerators iswithdrawn fromtheintakeforebay(orfromLakeTownshipwatersupply)andessentially allnaturalimpurities areremovedthroughsedimentation, filtration, reverseosmosis,anddemineralization. Periodically, impurities enterthesteamgenerators throughsystemcorrosion transport mechanisms, themakeupwater,orsystemupsets(suchascondenser leakage)andmustberemovedtoprotectthesteamturbinesandheattransfersurfacesofthesteamgenerators. Theimpurities areremovedbydrainingaportionofthewaterfromthesteamgenerator. Inthesteamgenerator steamisseparated .fromthewater,isfurtherheatedandthenroutedtotheturbines. Whenthesteamseparates fromthewater,theimpurities remaininthewater,concentrating inthesteamgenerator. Blowdownconsistsoftwoforms,aliquidportion(700GPMmaximum)andawetsteamportionwhichisexhausted totheatmosphere. Theliquidportionofthesteamgenerator blowdownisdischarged tothescreenhouse forebayeitherdirectly, orafterprocessing throughmixedbeddemineralizers. Impurities inthisdischarge mayconsistofinsoluble ironandcopperandattimes,impurities fromthecoolingwater(LakeMichigan) usedtocoolthecondenser. Steamgenerator additives consistofammoniaand/ormonoethanolamine (ETA)forpHadjustment, andhydrazine and/orcarbohydrazide foroxygenscavenging. Periodically, sodiumnitriteisusedasatracertodetermine thesteamgenerator blowdownratethrougheachofitsblowdownvalves.*Duringunitoutages,thesteamgenerators arestoredfullofwater,including treatment chemicals, toprotectagainstcorrosion duringstorage.Thelayupwaterisintermittently discharged (32,000gallonspersteamgenerator) throughOutfallOOBtoLakeMichigan. Thelayupwatercontainsamaximumconcentration of400ppmhydrazine and/or40ppmcarbohydrazide, and50ppmammoniaand/orETA.Thewastestrengthofthisdischarge isreducedthroughmixingwithOutfalls001,002or003bymorethan40,000times.Demineralized waterorsecondary waterisusedtopressurecleanthesteamgenerators duringoutageperiods.Thewaterisrecirculated throughtemporary filterstoremovesuspended solids.Themajorconstituent ofthesuspended solidsisironoxidefromthesteamgenerators. Thewateristhenreturnedtothesteamgenerators anddrainedtoOutfallsOOA,OOB,orOODviatheturbineroomsump.OUTFALLOOC-PlantHeatinBoilerAheatingboiler(150,000lb/hrcapacity) operatestosupplyplantheatingandauxiliary steamwhenUnit1and/orUnit2steamgenerators areoutofservice.

'Theboilerisalsofiredapproximately oncepermonthfortestingpurposestoensureitsavailability. Impurities fromtheboilerwaterconsisting primarily ofinsoluble ironandcopper,aredischarged (30GPMmaximum)totheintakeforebay.Boilerwatertreatment additives consistofammoniaand/orETAforpHadjustment andhydrazine and/orcarbohydrazide foroxygenscavenging. (SeeOutfallOODforwetlayupdrains)OUTFALLOOD-UtilitWasteWatersUtilitywastewaterfromwithintheplantisdischarged viatheturbineroomsump(TRS)intoanon-siteabsorption pond.Theultimatedisposition ofthesewastewatersistothegroundwhichventstoLakeMichigan. Thewastewatersinclude:Wastesfromthemakeupwatertreatment system.Themaincontributors tothewastestreamare:themakeupplantdemineralizer regeneration wastes(average40,000gallonsperregeneration), degasifier pumpsealwater(108,000GPD),carbonfilterbackwashwater(average45,000GPD)andpre-filterbackwashwater(average72,000GPD).Theretention tankperiodically discharges averysmallvolumeofsolidmaterialremovedbysettling. Alum(aluminum sulfate)isaddedtothepre-filter influentasaflocculent. Thesepre-filters arebackwashed totheTRStoremovethesuspended mattercapturedonthefiltermedia.Thealumcontained inthebackwashisdischarged totheTRSintheformofinsoluble aluminumhydroxide. Carbonfiltersarealsoperiodically backwashed totheTRS.Thesefiltersprimarily removeorganics, chlorineandsmallamountsofiron.Sulfuricacidandsodiumhydroxide usedbythemakeupdemineralizers toregenerate theresin,arerinsedtotheTRSandgenerally neutralize eachotherinthesumptoformsodiumsulfatepriortodischarge. Non-essential servicewaterisusedtosupplyvacuumdegasifier pumpswhichutilizeapproximately 75gpmtotalviatwopumpstoremovedissolved gases(primarily carbondioxideandoxygen)fromthevacuumdegasifier andexhaustthemtotheatmosphere. Anewcomponent ofthemakeupplant,areverseosmosis(RO)system,hasbeeninstalled toremovethebulkofthedissolved solidsfromthelakewaterpriortodemineralization. NormalrejectwaterflowistoLakeMichigan. TheROsystemmustmaintainverycleanmembranes toassureefficient operation andpurityofwater.Severalmethodsareusedtomaintainthislevelofcleanliness fromscaleandbiofouling. Usinghydrochloric acidorsulfuricacid,thefeedwaterpHisloweredtoreducethescalingtendencies ofthewater.Approximately oncepermonth,aflushisperformed usingapproximately 0.5%hydrochloric acidandcaustictodissolveanyscalethatdepositsonthemembranes (average5000gallonspermonth).Chemicalcleaningisperformed whentheaboveflushesarenolongerareeffective. Thechemicalcleaninginvolvesseveralstepsandmaycontaincitricacid,hydrochloric acid,phosphoric acid,sodiumhydroxide andaneutralpHdetergent (average10,000gallonsperevent).Also,toremovedeadbiological matterfromthemembranes, asoakusingsodiumbisulfite maybeperformed approximately onceperyear(average5000gallonsperevent).eDuringperiodswhennotinoperation, theheatingboilerisstoredfulloftreatedboilerwatercontaining atmost400ppmhydrazine or40ppmcarbohydrazide foroxygenscavenging and50ppmammoniaor50ppmethanolamine (ETA)(forcorrosion protection). Priortouse,this"wetlay-up"waterisdrainedtotheTRSfordischarge intotheabsorption pond.Thevolumedrainedisapproximately 1600gallonsandmayoccur30timesperyear.nDuringaunitoutage,thecondensers arecheckedforleaksbyfillingthesteamsidewithcondensate containing approximately 1000gramsoffluorescein disodiumsaltorRhodamine B.Thesedyes,whicharefluorescent underblacklight,aidinthedetection ofjointandtubeleaksduringvisualinspection. Thevolumeofwaterdrainedfromthecondensers rangesfrom160,000upto1,000,000 gallonsandmayoccuronetimeperyear.10 Znaddition, thecoolingwatersideofthecondensers areperiodically drainedtotheTRSforgeneralmaintenance periodically (8condenser halvesperunit,approximately 25,000gallonsoflakewaterperhalf).Thecomponent coolingwatersystem(CCW)isperiodically drainedtoallowforequipment inspection, maintenance orrepair.Thissystemusesdemineralized waterfromthemakeupplantasitssourceofmakeupwateralongwithamaximumof1200ppmnitrite(fromCalgonLCS60)and100ppmglutaraldehyde astreatment chemicals.. Theinfrequent drainings releaseapproximately 60,000gallonsoftreatedwatertotheTRSperyear.Thedieselgenerator coolingjacketwatersystem(DJW)employsthesamechemicalcontrolforcorrosion asinthecomponent coolingwatersystemwithamaximumof2000ppmnitritesfromCalgonLCS60.ThissystemisdrainedthroughthefloordrainstotheTRSwhenmaintenance isperformed. Thesystemvolumeisapproximately 1000gallons.Anyminorsystemleakswouldalsobedirectedtothefloordrainduringnormaloperations. Theessential servicewatersystems(ESW)andnon-essential servicewatersystems(NESW)arealsoperiodically drainedtoallowforequipment inspection, maintenance, orrepair.Thesedrainsmaydischarge approximately 72,000gallonsofLakeMichiganwaterusedfornon-contact coolingintotheTRS.Thiswateriseitherchlorinated intermittently ataresidualconcentration of0.2mg/1TRCorcontinuously at0.036mg/lTRC.Duringsomespecialtreatment periods,thiswatermaycontainzebramusselbiocides, usedasamolluscicide forzebramusselcontrol.Periodically, components oftheESWorNESWsystemsmaybechemically cleanedtoremoveirondepositsusingvendorsuppliedcleaningsolutionsuchasEDTA(ethylenediaminetetraacetic acid)orascorbicacid,aceticacidandammonia.ThesewastescouldeitherbedrainedtotheTRSorLakeMichigan. 11 Thesteamgenerators (S/G)aredrainedforinspection andmaintenance duringscheduled unitoutages(approximately every18months)andduringaneventwheresteamgenerator failureisdetectedthatrequiresaunitshutdown. Thesteamgenerators utilize150ppbhydrazine (fromeitherdirecthydrazine feedorasabreakdown productofcarbohydrazide), 20ppmammonia,and2.5ppmETAtocontrolthewaterandsteamchemistry tobenon-.aggressive tocyclecomponents. Unit1steamgenerators alsoutilize10ppmborontocontrolcorrosion. Asteamgenerator volumereleasedduringthedrainingisapproximately 32,000gallonseach.Duringwetlay-up,theS/Gsarestoredfullofwaterwithupto400ppmofhydrazine or40ppmcarbohydrazide and50ppmammoniaorETAareaddedforcorrosion control.ThiswaterisnormallydrainedtosurfacewaterviaNPDESOutfallsOOAorOOB,butmaybedrainedtotheTRSinsomeinstances. Themiscellaneous draintankscanbealignedtodischarge totheTRS.Asmuchas350,000gallonsperdaymaybedirectedtotheTRStocontrolthechemistry limitations onthesecondary watersystems.Waterchemistry isprimarily thesameasinthesteamgenerators. Aroundtheplant,miscellaneous sumpscollectapproximately 45,000GPDofwaterfromvariousequipment drains,leaks,pumpseals,andsteamjetairejectordrains.Thefrequency ofdischarge andtypesofchemicals usedinthisequipment havebeendescribed elsewhere inthisdescription. Mi.scellanoous floordrainsarelocatedthroughout theplanttoprovideasafeworkingenvironment byroutingspilledorleakedwatertotheTRS.Themajorchemicalinfluxintothesedrainsarefromthedetergents andwaxesusedtomaintainthefloors.AlsoroutedtotheTRSthroughthefloordrainsarethechemicalfeedtankdrains,fireprotection water,drinkingwater,coolingwater,anddrainsfrombioboxesusedtomonitorthezebramusselcontrolmeasuresandotherchemicalcontrolmonitors. Thechemicalfeedtankswhichmaybedrainedcontainhydrazine, ammonia,boron,ETA,carbohydrazide, andsodiumhypochlorite. Thebioboxeswilldischarge chlorineandzebramusselbiocidesduringtreatments. 12 Non-ra4iological chemicallabsinkandfloordrainsareroutedtotheTRSfordisposal. Thedrainscarrywaterandthewastesgenerated whileperforming analysesandpreparing laboratory standards including thoseontheattachedlist.Alsodischarged willbeglassware andnormallaboratory cleaningwastes.TheaveragevolumedirectedtotheTRSisestimated tobe500-1000GPD.8econdary (steamgenerator orcondensate) samplewaterfromcontinuous analyzers areroutedtodrainswhichdischarge totheTRSandthemiscellaneous draintank.Theanalyzers areonthecycleswhichmaycontainasmuchas10ppmboron,150ppbhydrazine (fromeitheradirectfeedorasabreakdown productofcarbohydrazide), 20ppmammonia,'nd2.5ppmethanolamine. Theanalyzers measurecorrosion transport ataaverageflowof8500gallonsperday.Mi.scellaneous sealingan4coolingwatersuppliescoolingandsealingwatertotheTRSpumps,condensate boosterpumps,circulating waterpumps,vacuumprimingpumps,drainsealreservoir tanksanddrainsamplecoolers.Theaverageflowperdayisapproximately 150,000gallons.Non-essential servicewatersuppliesapproximately 53,000GPDofnon-contact coolingwatertovarioussamplecoolersthroughout theplant'sturbinebuildingincluding theconductivity roomandthesteamjetairejectorsamplepoints.ChemicalspillsthatentertheTRSmaybeneutralized withinthesump'topreventadischarge totheenvironment. Thepotential forspillstotheTRSexistsforthefollowing chemicals withtheproposedneutralizers listed:~Ce~icaSulfuricacidSodiumhydroxide Sodiumhypochlorite Hydrazine EthyleneglycolNeutralizer Sodiumhydroxide SulfuricacidSodiumthiosulfate NESW(lakewater),Hydrogenperoxide13

OUTFALLOOE-SanitarWasteDischaresSanitarywastesarepresently segregated androutedtotwoextendedaerationpackagetreatment plants.Theexistingequipment isdesignedtotreat50,000GPDandtheeffluentfromthesewagetreatment plantsdischarge intooneofthetwoseepagelagoons.Thelagoonsdischarge intothegroundwater withtheultimatedisposition beingLakeMichigan. Thesludgeremovedfromthesedimentation tankbasinsistakentoalocalPOTW(publicownedtreatment works)fordisposalordewatered andstoredaslowlevelradioactive waste,asappropriate. 1Plantsanitarywasteconsistsofshowerandrestroomfacilities, andjanitorwashbasins locatedthroughout thePlant'snon-radiological property. Kitchenwastesaregenerated fromtheplantcafeteria, theCookEnergyXnformation CenterandTrainingbuildings. Thechemistry traininglaboratory discharges tothesewagetreatment plantsthroughalimestone bedneutralization tank.Thechemistry labisusedtotraintechnicians onanalysesperformed intheplant.Thedischarge fromthelabcarrieswaterandwastesgenerated whileperforming analysesandpreparing laboratory standards including thoseontheattachedlist.Asmallphotolab,inthetrainingbuilding, uses(onaemergency basis)smallquantities ofhydroquinone'o developblackandwhitepicturesforplantuse.ThetrainingbuildingHVACsystemalsodrainstothelimestone bed.Aradiography labintheplantalsodischarges smallquantities ofprocessing chemicals fornon-destructive testingintheplant.Noneoftheradiography .products containcriticalmaterials orprioritypollutants. Allportabletoiletwastesontheplantsitearecollected anddischarged tothepackageplants.Abiodegradable deodorant isusedintheportabletoilets.Sludgeeffluentwastemayalsoberecycledthroughtheplantstodecreasetheamountofsludgeforprocessing whenpossible. Miscellaneous rinsingofwastereceptacles andpossiblecleaningoperations waste,utilizing variousdetergents, mayberinsedtothesewagetreatment plants.14

Miscellaneous OutfallsThemainplanttransformers oneachunitarelocatedwithinconcreteberms.Thebermsareforspillcontainment shoulda~catastrophic failureofatransformer occur.Toprotectagainstoperational andsafetyconcernswhichstemfrompondedwater,these'areasgravitydraintooil/water separators specificforeachunit.Eachseparator isabelowgroundconcretebasindesignedtoretainoilandreleasewatertoaseriesofdrywells. Alsodischarging intotheseparators, aretheemergency dieselgenerator pitsumps.Thesesumpscollectlimitedwaterandfueloil(lessthan500gallonsperyear)fromtheemergency dieselgenerator room.Periodically, theoil/water separators arepumpedcleantoremovetheaccumulated oilforproperoff-sitedisposal. Thesecuritydieselgenerator daytankhasanoverflowlinethatconnectstotheUnitOnetransformer deckcatchbasin. Discharge tothe~catchbasin wouldonlyoccurifthedaytankwereoverfilled. Procedures andlevelindicators areusedtopreventoverfilling. 15

CHEMICALLABANALYSISAdditional Information SectionIItem6,SubpartACookNuclearPlantSurfaceWaterPermitApplication PLANTCHEMISTRY LAB(toOutfallOOD)ChlorideFluorideHardnessHydrazine SilicaOil6GreasepHFreeMineralAcidityTotalPhosphorus ChemicalOxygenDemandSulfateNitritesTotalResidualChlorineASTMD-512-81(1986)ASTMD-1179-80 (1986)StandardMethods413B(1985)ASTMD-1126-80 EPA-600-4-79-020 Method130.2(1979)ASTMD-1385(1983)ASTMDPowerWaterAnalysisManualCH-41EPA-600-4-79-020 Method413.1(1979)ASTMD-1293-84 StandardMethods423(1985)ASTMD-1067-82 MethodBEPA-600-4-79-020 Method365.3(1979)EPA-600-4-79-020 Method410.2(1979)ASTMD-516-82MethodA(1985)EPA-600-4"79-020 Method375.3(1979)StandardMethods426A(1980)Determination ofCorrosion Inhibition byCalgonCorporation ASTMD-1253(1986)StandardMethods(1980)TRAININGBUILDINGLAB(toOutfallOOE)BoronChlorideFluorideHardnessHydrazine SilicaOil6GreasepHTotalPhosphorus AtomicAbsorption MetalsIonChromatography Westinghouse ChemicalAnalysisProcedure forPWRWCAD7333Rev.1(1973)ASTMD-512-81(1986)ASTMD-1179-80 (1986)StandardMethods413B(1985)ASTMD-1126-80 EPA-600-4-79-020 Method130.2(1979)ASTMD-1385(1983)ASTMPowerWaterAnalysisManualCH-41EPA-600-4-79-020 Method413.1(1979)ASTMD-1293-84 StandardMethods423(1985)EPA-600-4-79-020 Method365.3(1979)StandardMethods302B,303A(1985)EPA-600-4-79-020 Method215F1,220.1,2421~2491g273'(1979)DionexSystemOperators Manual SEEINSTRUCTIONS QNREVERSESIOESECTlONIPERMITNUMBER~iII0005827~EM7'coVI"EA'FrE~cA~i.ElP=CN~ll4,.""E =RAidi"FccEIEGiAIKE?QIIIT(3) "Gi'c'P.".:"i ='H-"(AE'tE~SEsaEC~c<E.LOCATION[SEEATTACHEDDRAWING]MAP21 4~II~~4~I~'44~4'5~3I3)~~'4si))")1ssJ4~JI'~~")05s5))~~Cs3~]y))s4s40y'Cs4'8'y4~3QI'J~)~44IS~+IJP)454$5~44~sA44Vss))Is)444~fpsH\4)44) SEEINSTRUCTIONS ONREVERSESIOESECTIONINUMBERPERMIT-EM8CONCENTRATE0ANIMALFEEDINGOPERATION A,DQYCUOPERAicACQt~~TB>>'<<."Al, FElIttGFACII.IIY? 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I')B~3>>>>I>>'!5(1sh'R...!500'rd~',3'",i'3",5"0>>"nO<<$('ones,)CB<<av5,<<her}>>a>>)Ir.et<<resnichcischarge arIeasr.'0cavsceryear,=toesncrl<<c(uce}5!""$"(SCt'af'n<<I"4~!5CRSI'cu04$5>3n'3~415:e..!)r,~)I>>.'f}:TEr.ID-8-!-)-)I"moect0:scretex)onescr)ce<<avs53'9<<ay"'4$'-;O)Ci':V.noer-:<<er")I(eSCeSCt'icriVe name".'"VS<<arSOt-eniteC$-3eSIT8H1000~310".(Rnorax(>><<lnmonthlycun05I(OOC5nouic9!Cresentativ! 0.>>Cr<<ona(ccet'at~TE((I:8IIRj3<<0""BIt)mesII.CANO0434>>'~9'<<~!<<ar!}!>>0'>>0('<<<<--4">>X">>n<<0:-"--<<Se<<-~-5"V"9-<<->>)i"<<4<<iBC!II054<<~0$Iii~<<I<< SECTIONINUMBER~~LISTNA"4A,'6,"/tILIM ADNESSCiALL=~PPT/~'.EBSAL,~sT,O.W-VI~SNTiÃlL:~s"8CRDISCS*%w/DISP"iSAL '>~,[SEEATTACHEDLIST]MAILINGLISTOFADJACENTPROPERTYOWNERS SectionI,Item12ADJACENTPROPERTYOWNERSMI0005827 EASTInterstate I-94(Michigan Dept.ofStateHighways) SOUTHLakeTownshipc/oGeraldWaskoTownshipSupervisor 1410ShawneeRoadBridgman, MI49106WESTLakeMichigan(StateofMichiganandUnitedStatesofAmerica)NORTHRosemaryBeach11-11-6800 0038-00-5 Tengerstrom, EricH.;3415S.59th;Cicero,IL606500037-02-5 Tengerstrom, EricH.;3415S.59th;Cicero,IL606500037-01-7 Merkel'sFloorCovering, Inc.;8314Scottdale Rd.;BerrienSprings,MI491030037-00-9 Kraiss,Wilbur&Marilou;5004S.LongAve.;Chicago,IL606380036-00-2 Temmel,EdwardP.&Kathleen; 9617E.ShoreDr.;OakLawn,IL604530033-00-3 Gilpin,Clark&Nancy;1005E.60thSt.;Chicago,IL606370032-01-5 Wittebort, RobertJ.,Jr.&NancyH.;3180N.Lakeshore Dr.;Chicago,IL606570030-02-1 Meier,Paul&LouiseG.;1357MadisonPark;Chicago,IL606150028-01-8 Balka,RonaldA.&JanetM.;3334LouiseDr.;Lansing,IL60438 SectionI,Item12ADJACENTPROPERTYOWNERSPage211-110006 0002-030004-000004-040004-010004-0211-11-0007 0013-000013-010006-010001-010004-0111-11-0005 00290036-010027-000036-000036-0211-11-0005-0002 01-611-11-0008 MichiganDept.ofNaturalResources; P.O.Box30028;Lansing,MI48909FranklinRealEstateCo.;P.O.Box2000;St.Joseph,MI49085Temmel,EdwardP.;9617E.ShoreDr.;OakLawn,IL60453Caparo,WilliamE.&Oyler,KathrynE.;122S.Ellsworth Pl.;SouthBend,IN46635RosemaryBeachCorp.;c/oSecretary; 3415S.59thSt.;Cicero,IL60650LakeCharterTwp.;ShawneeRd.;Bridgman, MI49106LakeCharterTwp.;ShawneeRd.;Bridgman, MI49106IndianaMichiganPowerCompanyLakeCharterTwp.;ShawneeRd.;Bridgman, MI49106LakeCharterTwp.;ShawneeRd.;Bridgman, MI49106Technisand, Inc.;11833RavennaRd.;Chardon,OH44024Ruff,TimothyW.;P.O.Box504Bridgman, MI49106Technisand, Inc.;11833RavennaRd.;Chardon,OH44024Emery,Martin;Hopkins,ElwoodJ.&MableN.;7499ThorntonDr.;Stevensville, MI49127IndianaMichiganPowerCompanyBankofAmericaTexasP.O.Box650380Dallas,TX752650041-000009-00MichiganDept.ofTransportation; Lansing,MI48900FranklinRealEstateCo.;P.O.Box2000;St.Joseph,MI49085 0~0WI0,~~~I~~,~~~I~~~~~r~I~~tt~I~I'~~~C~~~I~~~~~~'st~~~'~I~~~~~'l~Jhl~t'I~rI~~tt~~I~I3~~~~a'0'~~I~~I'.It~~~~'I~~'~'5~I~~~~QII~'~.I~~~~~~~I~~I~~~~II~~~~~'~ItI1'~I~'~~~~~~~4~~~~'~~~C.I'~'I~~~~'~ 30 SEEINSTRUCTIONS ONREVERSESIDESECTIONIIPERMIT~qZpppgNUMBERLITEM3AIIFALL%lKDA~"~'4CFPRXESSCOltIRIBUTII4 IOEHEDISOIARGE e~THISCUAFALL~QSICCCDEB~?ROCFSSSCHEDULE(YEARLYAYERAGE)L~OCIO0LINGITRI49tCIXIS/DAY "AY/PROCESSSTREAMSCONTRIBUTING TOOUTFALLDISCHARGE 4/ILftO~00DePROCESSPRODUCTION RATENAC~I'SIOCESS HASTEtlATER FLQHRATEBasis:1993actualdatasubmitted DMRSTOTALYEARLYDAILYttINItXTI DAILYINAXINM38P227~5~61323~6LttlTS/TIHEII1POUNDS2GALLONS3CUBICYARDS4TONS5MGYMGD7GPDTIMEhatt4/tfitMcvOGLA,tl4tfEOFPRQCESSCONIRIBUTING TOTsfEDISCHARGE itFCUGHTHISOUTFALLAl4)SICCOTENABePROCESSSCHEDIAZ(YEARLYAVERAGE)CePROCESSHASTEHATER FLOHRATEDPROCESSPRODUCTIOI RATEA.IIAIEOFPROCESSCQNTRIBUTIIIG roTHEDISCHARGE TIIIQUGH1HISOUTFALLAISDSICCODEB.PROCESSSCIEDULE(YEARLYAVERAGE') C.PROCESSIASTEHATER FICttRATEDePROCESSPRODUCTION RATEHERS/DAY~DAYS/YENTOTALYEARI.YDAILYHINIHINDAILYHAXItuSEYES/DAY~DAYS/YENTOTALYEARLYDAILYHINIt%NDAILYMAXWNUNITSC'TIHE~LJ1HOUR2DAY3WEEK4MONTH5YEARAetIA%OFPROCESSCONTRIBUTINGIDTIEDISCHRRGENATHAtgSICCODEB~l%OCESSSCHHAAX(YEARLYAVERAGE)RECESSHASTEHATER FLOHRATEISAIAS/DAY ~SAYS/YENL-L-I-lTOTALYEARLYDAILYHINIIXPIDAILYA'AXItstPI LNII'ODE<h4/)OfftCttXDesrESSPRODUCTION RATEAetfAtEOFPROCESSCQNIRIBUTING TOTIEDISCHARGE TI4KXXBTHISOUIFALLAttDSICCODEBePRXESSSCHHXLE(YEARI.YAVERAGE)C,PROCESSHASTEIIATER FLCttRATED,PROCESSPRODUCTION RATETOTAI.YEARLYDAII.YNINIIXTIDAII.YtAAXWNDAYS/YSNUAIITS/T(HE<<IITC<<"EIUNITS/TIPE 5"'l"I'er5555ros~sI'4IS3;<<)4=4';t'-E"-CxAt-==-~4Cc-.-IEcgcu.'-=4Eoul>".iynCRAIIEE49.'tQCNfiEPCNTRAGE=r'4EXPIRI"B553ew,rrev'5I5Arl,e~33I~v,renleavecIsnAa,.d31ulper~III:eassicnec.d5~3lI,e~5ace4video~eac.daceEecTIcn<<I,creachtrdlvlvaldlsc1arce saint3Secara~3serc"e5usreciIlaa,IC3"CJTh,tICg4CarllC',riCccaltc'j'gII~IhFuATIC'IE"-ec--e-m='1eprocess<<nlcnccnrn'cures "IsSiscnarae. <<Isoprovide-"eprccerICc-ae."caloe-reveallv3verageprocessScneauleInhours:ercavanadays-cer-veer. Providet14prcde55<<35tcwater flowrateinfornation 35reaueSted baseaonyourlast12lnanthsofoperationS. Refertounitcodegivenintheleftmarginfortheappropriate flowunits.orpcessprcauction pate-certaindemitlimitations maybebasedcnproduction la.es..hecroductlcn ratesusedtoceter1lne demitl'nitsSrallce.eprese"-ec bv3reascl,acle caesurac'.cruelproduction c',he<scllltv, svchasthe:rccvct!cn during~he1ign"anthc'"epreviousveer,rT1enOnthlvaverade',CrtnehighestcfTheplevlcusfiveyears',orCT1er.eaSOnable "easureasstated,'nsdpi:Cable d.E.E.4.A. categoriCal rulesanareaulaticns. "ew3uresr"ewpl5c13ror5'~taver513s=eastiatec.Sir=crclected crcductlcn ReCCrdy"rC"Cd;C-'Cn rateSIn-re-er.SsnC.nlrS.Sea'nme334<loadie ~.E.E.P.A. CateacriCal iuleSandreduiaricnS fdl'4 SEEINSTRUCTIONS 'NREVERSESIDESECTlONtIPERMIT~eII0005827NUMBERCBEMOJIFkLIU'FEA.ISeeIEDISCHARGE FROMTHISOUTFALLDIRECTEDTOTHEGRCUt41CRGRQVtCWATERS2 IIFtoeCONTINUETQITEM5)YESAOtleGROUNDWATER DISCHARGE INFORMATION B.TWASAstYDROGECLCGICAL STVDYORITSEQUIVALENT BEENPERFORMED ORISTHERESIFFICIENT CURRENTHYDROGEQLQGICAL INFORMATION AVAIIABLE ASREQUIREDBYDEwATERRESOURCES H~ISSICNPART22GRCVADWATER RNPSCFAUGUST141%6R,$23,22O7(PAGE4Q)FQRDttsEXISTINGCiRPROPOSEDDISCHARGE. 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ESTIMATE1HEFINALEFFLUENTCONCEtttRATION AADRECORDALLDATAINITEN7OFSECTIONllIN1HISBODICE~SAATRLR2222.1GRAB224HOURCOMPOSIyE 0II.BCeREASEI-LJLJLJLJ~LJLJ~LJLJLJDMRSREQUIREDINFQI4tATI(Xt FCRSURFACEWATERDISCHARGEse LJSEEATTACHEDSHEETSFORANALYSISDATA*Basis:1993actualdatasubmitted onuu35 8'r'rcraii~>>c~~>7Ev5'"'05sr<<.8>>Jiresnrcr.dticncn338>>ri<<TiIrI,rscdr'gingei"BrI'8grcuncwnters rTr'85ur.dcB<<dters.VI7'."BE>>ru7RE~X3~iE0rF7i(5CRY.PEEBI7IASvBERCAVEEFCvNOCrlTpEFPCT(7PAGECFyCQREAPIR(r;5 533ne>>crnctprevious:v cermlttec'dciIitv,-henledveblankdnd3hurberwlIIbeassicned. I<<<<-.:8>>'"7"85:3>>B3>>av:sec'3>>sdr>>".dceor5ec-(cn',I.=crBachindlviduni d(sc>dree cc>>5separa-eset"ei<<Eid3~,c'rcv>>t ii'r'3*E(.ii'JcIC'rrhBCFBAI'IIrrirl5I~Eu)SCCI.'cdr,t Shallsdcresseacha!-nese=artsI'eciscndrce '-an-.".IsoutfnlI:5TaThegrauhc<<nte>>. I'7E4I=.I5~l'.G".P.KaEC.E"(FCRAKE)rO(5CHARGE) rr35EhATERC!ACACTEPI57lrg 5<PROV\O'irATER CR5I'RFACE'rrATERO(5CP'RGE ("O'!07lrCI.UOE.-C.I'<ru,'RvA7III~irl>ruI7heapplicant shallreportavailable discharge dnt:(realdatatorex(stingdischarge orexpecteddatafor3proposeddischarge) tcrTheparnrre<<ers dsIi5ted.74838parameters shallbeaddressed fareither3surfacewaterdischarge orssappropriate tor3:raurCwaterCISCndrge. FOrSSSIStanCe Indetermining apprOpriate barnmeterS 3grOundWater d(SCharCe nppl)Cnnt mnyCantdCtThe~rcurc<<dter gua)itvOlvlsicn, Permits5BC;icncrThedcorcprlate GraundwdTer QudlitvOivislan'5 Oi5trlcta!flee.",.<<ocr)cant 5"all>>Boar."esdmoletvpecedebestsescribirg BdchreparRdoleceofdata.Seecad(rcant"eleftmarginofn:5!err."is:'T!3:I53surface<<sterl5Cr',8dept~cant-ust-Boer"."antiTntivedatafcredenparameter Identified bvanTs,er3<<.;8dppiicdnt mav,however,, dcqest--dt-nerepor-hca:dtdcrcneormareoTneserecuirecparsreters be<<diveC.Cn8".'BSTustbe5'opal'.BC bvSCBcudte3(Chare.dkBSucharecueSTdnattachment TOthisapplication. '3,3~5Svdiidb'8 tcrotherpara>>ieters rCTI~stecSbavein'.Crotherpdr'TsofThi5dcpllcatioh Thesap()cant 5havldrepor'T-dt"3rdinTre:rdnxSPacescrovlcedlnthispart.rg7E5.r)nitcodesforparameters reportedInoartsAdndBcanbefoundontheletthandsideofthisform.:rnb53BO(eSnaileuSeot"Sra(VZe'OrCrr~Temberature, TO<<dlPhenO(S,reSidualChlarlre, OiISndgredSe,nndfecalcoliformInasur!dcewaterdiscnnrce unlessother!recuencv-sample typeanalysessreavaable.SeeGlossary(pace48)fardetlnitlon otgrabsample.'3-i)ourcompos(!8 samplessnailbeusedtoanalyzercr.otalBM>>,coo,7cc,Ammon(aIlitrogen. dndiotdlSuspended EalicsIn3surface<<sterclscnarre unlessother'recuency-sample tvoeanalysesareavailable. 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Your:miTat*5-5<<':r38SC'.Ste-CriyTaTreBXtent-dtTreIrTd<<eColli)tanTS:3natvary!romthedlscndraeo PailvtanTS.: ic'.naveto>>-cre).cst>>"id)icr'vTcsameidSncd>>5Iv[8g55"~dllvICPntcdia>>P'I~'"Centred I."53.,3~Tv>>8uast=er,isslon Ir~vcur:erlttlrr,~v"8cvdrI}.5<<bml885<<I5arned<<atvs)5irarBrSupstdrtin(Iyst3:>>3"-o1:i "838~i--'"c duthcri:,crdsepsr3teshee-3-Sc"Bctc.<<we-CIes:-:benv-.ecuridilshier.Cu"C-Ct-eStdre SEEINSTRUCTIONS ONREVERSESIDE0IIt.kLNXBSECTlONllPERMIT~MI0005827NUMBER~001eTEM6PRIORITYPOLLUTANTS ANDADDITIONAL INFORMATION FORSURFACEWATEROISCHARGE ONLY<ATEFCI'OWING REQUESTED INFORt'ATIOtt ~c>><ccA"DRESSED ~~SIRFACEWATERDISCHARGERS> IIQIEI.'>EwUSEDISCHARGERS e~>>PRQYICEggECTEDVALUESFQRThEQUAIITITATIVE AttDQ~lTATIVE IhFOR"ATICN REQUESTED BELCH,A.ISTHISFACILllYAPRit>PRYIIKLSTRY2 (REFGITOTABLEIAPAGE4+t>c>C,GQTQE)(tFVESGQTG8)8INDICATETYPEGFPRIMARYINDUSTRYASLls~INTABLEIAPAGE49~<CCtlfttNKWITHC~)C>XESTHISCUfFALLDISCHARGE CCttfAIMANYPROCESSWASTKWATKR2 (>FNQ>GQTOE)'IIFYES,GOTQD)NDICATEWHICHC/YSFRACT'CNS MUSTBE>FSTEDFOR(REFERTOTABLEtAPCiE4~tIIQIE!FCREACHGC/t'SFRACTIONCHECKED,EACHSPECIFICORGANICTOXICPOI'TAMTWITHINEACHFRACTIONf2!!5JBEAIIALYZED FQR(SEETABLEI(APAGE92.IHADitITICM> ALLPRIPARYttKXISTRY APPLICANTS WITHAPRQCESSWASTEWATER DISCHARGE ~PROVIDEQUAMflTATIVE DATAFOREACHTOXICPOLLUTANT INTABLElllAPA;EQ)>RECCRDAU.DATAGNFCRMSPROVIDED(ITEM7)INTHISBCOXLET>(CQNTIIAIE WITHE-t(BELOW)XYEsSTMELECPtMRXYESQ>oXVIXATILEQXBASE/NFUTRAL XACIDPESTICIDE

• '.IF~SURFACEWATERDISOIARGE APPLICAMT (PRIMlRYQRSECCNCARY INDUSTRY),

REGARDLESS OFTHETYPEOFDISCHARGE> KtCWSORHASREASONTOBELIEVETHATANYPIXLUfANT LISTEDINTABLEIIAANDIVAPAGES~ISDISCHARGED FRCMANYOUTFAU.>THEQUANTITATIVE DATA~BKPROVIDED> RECORDALLDATAONFORMSPROVIDED(ITK>t7)INTHISBOOKLET>NQTAPPLICABLE/BEI.IEVED ABSENTOOXPRESENT/CATA ISATTAOlKDF.IFANYSURFACEWATERDISOURGEAPPLICAVT (PRIMARYORSECONDARY ltGXJSTRY)> REGARDLESS OFTYPEQFDISCIIUIGE> KtCHSORHASREASONTOBELtEVEANYPOLLUTANTS USTEDINTABLEVAPAGE+AREDISCHARGED FRtYIANYOUTFALLTHEAPPLICANT ~>DESCRIBEREASONSFORTHEPOLLUTANT BEtt5PRESENTANDPROVIDEANYAVAILAB(E QUANTITATIVE DATA>RECORDALLDATAONFORMSPROVIDED(ITEM7)INTHISBOOKLET.G>ALLSNFACEWATERDISCHARGE APPLICAMTS (PRIMARYANDSECONDARY INDUSTRIES) WHO'QRHAMIX'ACTMES 2,4,5-TRICILCACPHENQXf ACETICACID(2,4,5-T);(>4>5TRIOkDROPHENQXY) PROPANQIC ACID(SILVEX>2>4>5>TP)'I%7HYLU(2>4>5TRICRDROPHENYL) PNSPHQROTHIOATE (ROWEL)'TRICtLQRQPHEIOL (TOPI'RHEXACHJOROPHEt>E (KP)'ALLDATAFORTHEABOVEPI/STBEGENERATED USIt6STANDARDANALYTICAL CALIBRAlIONPROCKDIRES) QRKt4WSORHASREASONTQBELIEVETHATTCCDISORMAYBEPRESEMfIMTHEIRDISCHARGE>> ~REPORT%ALITATIVE DATA>GENERATED WHICIIgjEDASCREENING PROCKDNENQTCALIBRATED WITHANALYTICAL STAIIDARDS, FQR2,5,/)8,-TKTRACHLORQDIBENZO PDIOXIN(TcDD)~REcQRDALLcATA0NFQRMsPRovlDED(ITEMk)IMTHtsBQoxLET.J~IFThESURFACEWATERDISCHARGE APPLICA'g KtCWSCRHASREASONTQBELIEYK>>ATBIQUXIICAI TQXICtTYTESTSwERE."ACEINTHELASTTHREE(5)YSlRSQttAtttOFTt>E<<FLIC"'tf 5DISOIARGES QRONARECEIVING WATERlitRELATIQtt TQADISCHARGE> FROVIDETHISIt>FORhATICN ASANATTACHMENT TQTHISAPPLICATIOM> tFACONDUCTVBQRATORY ORCONSll.TING FIRMPERFORMED AtftOFTteANLAYSESREQUIREDBYTHISAPPLICATION> PROVIDETHENAMEANDADDRESSOFEACHVBGRATORY ORFIRMANDTHEANALYSESPERFORMED ASANATTAQC%HT OFTHISAPPLICATIQtt ~COYQUDISCHARGE ANYOTHERTOXICCRINJIRIOUS CHEMICALSISSTANCES NQTLISTEDIttTABLESIVPAGE(IAtKIttATHIOUt4lVAPAtiES~~+~'>c+ES>THENIDENTlcYTHEICALSUBSTANCES ANDESTIMATETHEFtttALEFFLUEMTCCNCENTRATIONS. SLKttITTHISthFOBATICN ASANAITAt&%lP TOTHISAPPLICATION> QXNQTAPPLICABLE/BELIEVED ABSENTPRESENT/DATA ISATTACHEDOXNQTAPPLICABLE/BELIEVED ABSENTQPRESENT/CATA ISATTACHEDNQTAPPLICABLE ClQXAPPLICABLE/SKE ATTACHEDQNOTAPPLICABLE XAPPLICABLE/SEE ATTACHEDXNQTAPPI.ICABLEClAPPI.ICABLE/SEE ATTACHED*Pesticide dataisnotrequired; however,itisprovided. vIIv)~'-es'"=-5'".."Pn3)cec'.'Ic out<<5)I-'scnarc) "ctc-"es>>rfece<<aters."Jv='==7<<5."",nl5FCRu~'"5egos<IT"tt3BEPCAN":cg.t(OCNT>>BorNTe<(:eOFv"(.'Rexoip('.c )5:53;e>>ornctcrevicuslv perltteciaciIl-v,tnenleaveblanxanc3nunoer<<:IIbe3ssicnec. <<"espaceDv'ofcredc,"ageieticn.'.-<<escn're<vidual ciscnarce coin35e"arete51ustsai'ec>>t~T=4l5'TOTS:"'ouhave.<<ocr'iore5ub5tantlal lvIncenzlcai outfalls.vou"avreccestcenlssicn !rmvourcere!tt(naauthor(tv -cIaxpleancsnalvecrlyoneoutfelIanosufittheresultsctheandlvsi5orhersubs'tanti elivicen.I-alu.fbiIs.(vous"ec<<estIsorantecby."epe~it<<lng authorltv, onaseparatesheetatachedtctheapplication fc~)centifv<<nicno'.ail,ouictest.anccase.ice>>nvtheoutfallsinichvouCICrottestsresubstantial lvicentlcal -otheoutfall<<n(CnycuCidte5t.e~anoartI".I<c)(B),Fricav,AprlII~IBB3,provicesicraSea<I='siness:xemptlon !.onthereporting ofcuantltative cataIcrorganictoxicpollutants anctoxicpollutants asrecuiredbv>artl22.I(q)<7)(ll)<A) or122.2I<c)<7)(ill)(A). hesepartsareself-exolanatory ancconotrequirefurherinstructions. Siplygothrougheachportanccoaslndlcatec. Severalndustrl'sl categories ancsuocsteccrles navepeenexeotec'rx5uo.I~t'"cCatacncertainriG/usFractions

30CeqPart)22,/OI.JB,"O.".-',=".IC3V,'Pr'llI.)793,'.OteSI.,)no3:.Revie>>thefo(ic<<ing i(sttocetemine>>nethervourfacilitycubi)lies toceexemptfreereporting G/NS<tasChr<xnatograonv/

uassSpectrosccpy) .=ractlons. TextilePillsIncustrvGC/u5FractlcnTestingandRepor,IrgExemptions -All'ourGC/uSorganicfractions lntheGreiqeu(ilsSuocategory. -Pesticide fractioninailothersubpartsofthisIncu5try. OreMinlnoandQresslnoIndustry-lolatlle, base/neutral, andpesticlce fractions IntieBaseancpreciousuetalssubcategory. -AlltourGc/usorqanicfractions Inallothersubcategories ofthisIndustrv. GunandWoodChenicals Industry-Pesticide FractionintheTalIOiIRosinSubcategory andtheRosinBasedOerivatives Subcategory. .Pesticide andbase/neutral fractions InallotherSubcateqories ofthisindustry. PulpandPaperIndustry.Pesticide fractioninPaperqrade sulfitesubcateoories (subparts JandU)..Base/neutral andpe5ticlde fractions inOeinkSubpartQ,Dissolvina KraftSubpartF,andPaperboard frc<<3MastePaperSubpartE.-Vole!ile. base/neutral, pesticide fractions intheBCTBleacnedKraftSubpartH,Sem(-chemical SuboartsBandC,andNonintegrated FinePaperSSubpartR.-Acid,base/neutral, andpesticide Fractions inFineBleachedKraftSubpartI,Olssolvlnq SulfitePuloSubpartK,Ground-woodFinePaperSSubpartO.HarketBleachedKraftSubpartG,TissuefrtxeMastepaper SubpartT,andNoninteqrated TissuePapersSubpart5,Stean<<ElectricPo>>erPlantIndustry.Base/neutral fractionintheOnce-Through cooling'uater,FlyAsh.andBottc<<nAshTransport Materprocess<<astestrear<<s. 38 SEEINSTRUCTIONS ONREVERSESIDESECTIONIINUMBER~i~fI00058279JIFkLelJKI~00!CRITICALPIATERIALS TOXIC)LLUTANTS USETHISDATASHEETTORECORDINFORMATION ASREQJIREDINl(CHECKAPPROPRIATE BOXFORttlICHItIFCRtIATICN THIS""TASITEETRE'ESFJITS ~)SECTIONIlpITEMII-EeGROWDWATER DISCHARGE INFORMATION (PAGE59CIO2eSECTICNIIpITD!6ePRIORITYPOLLUTANf SINSIJIFACEWATERDISCH4RGE (PAGE~~X3.B.BELOW:CRITICALMATERIALS (TABLEIV)INSURFACEWATERDISCHARGE (PAGE39)ZARDOUSJBSTANCES IN3ISCHARGE BeLISTAtA'RITICAL tATERIAL(TABLEIVPAGE6)NOTADDRESSED INSECTIONIIITEMF'RIORllY POLUJTWifs 'eettICHYOUIeete4tORHAVEREASONTOBELIEVETOEEPRESEIITINT%DISOARGEP SEEREVERSESIDEOFTHISPAGEFORFUJAFRDIRECTIats. NOTAPPLICABLE XAPPLICABLE (SEEBELOII)K144~IAeNAMEOFCRITICALMATERIALCRPRIORITYIXJLLUTA'8 B.AVERAGECCNCEJnRATICNJ SAMPLETYPE;¹OFANALYSESC.AAXIWCaiCENTRAT IONAtoMASSAeN/tAZCFCRITeiCAL AIATERIAL ORPRIORITYPOLLUTAttf BAVERAGECaICENIRATIONJ SAMPLElYPEl¹OFANALYSESc..AXItlftcaICENTRATION eoMASS*SodiumHypochlorite .CLASS01/4~0~gj~]~LJ~FV~0~20'~1~178~4"'~3WITCODESAMPLETYPEOFANALYSESLJWITCODEWITCODENITSCODEMg/IUg/II~/DAY~/DaVIAPEETYPEGRAB24HR.COMP.AetIAMEOFCRITICALMATERIALORPRICRllYPOuJJTANT B~AVERAGECCtICENIRATIONJ SAMPLETYPE;¹OFANALYSESCeNAXINNCONCENIRATICN ANDMASSAeNAMEOFCRITICALMATERIALCRPRIORllYPOLLUTANT B.AVERAGECC:ICENTPATION; SAMPLETYPEJ".OFANALYSESC~MAXIMACctCENIRATICN ANDMASSAetIAe%OFCRITICALMATERIetL CRPRIORITYPOLLUTANT BeAVERAGECatCENTRATICNJ QPAETYPEJ¹OFANALYSESC~i'AAXIMYWCCtlCENTRAT ICtlAJYDMASSWITCCDEQIANATYPERAFANALYSESWTCODEWITCODEWIT4XXJESAtPLETYPEJJOFANALYSESWITCODEUNITCODELJ~~~LJWITCODESAtFLETfPE¹OFANALYSESWITCODEWITIX'GEAetIAMEOFCRITICALMATERIALORPRICRllYPOLLUfANT 441<!7BAVERAGECaJCENIRATION; SAMPLETYPE;OFANALYSESC~~AXltlf8'CXICENTRATION AtOMASSAeNAMEOFCRITICALMATERIALORPR(CRITYPOU.UTANT 3.AvERAGECaICENIRATICN; SAMPLETYPEJ¹CFANALYSESI~CeMAXlttNCCICENIRAT IONAt@IMASSWITCODESAJFLElYPEiP'FANALYSESLJIIVITCODEWITCODELJUeufCODESAMPLETYPE0OFANALYSESLJatlTCODEWlfCODEAetIAMECFCRITICAL, MATERIALORPRICRITYPOLLUTANT ~AVEPAGECO'KENTRATIONJ SAMPLETYPEJ¹OFANALYSESC~',~AXI"AP. CaticENTRATION A'ClMASS*Discharged astotalresidualchlorine. WITCODESAMPLEIYPEOFANALYSESLJWITCCDEWITCODELJ~~~LJ**Basis:ADDITIONAL PAGESCFTHISI~7AREATTACIEDFORT)ERESTOFTHECRITICALClYESMtelERIALS AND/CRPRICRITYPCLLUTANTS REQJIREDTOBEREPORTEDeElNO1993actualdatasubmitted onDMRS.Averageconcentration basedondatafromMaytoDecember. 39 EVS>NO'4<<5r<<)n0<<i~i~3is~i<<:.5-lcn~)isc"arse sc-ecuie, ici.-e.Ic>>ra-8sncaver-rear"ent -=""IT'K.VEERI'iTI'EBDXATTE,CPrFTh(SF"Rs."isi531<<>>C!CVVr<<viou>>lverI<<>>~3<<;(curtail;>ocrlnscaceorovicea'credencaie"'Ior...S .S.CeiIledCuv.i(E<<Eou(T'<NBERCAl(BEFQ.'~DCNTREFRONT?AGE CFYODREXPIRINGvv,~"enleave0(snxsnas-4-oer<<Ill08ssslcnea. 0Sectionli.=cr!sc)<<civicalaischsrce cin.5separatesercfEnrer-neIccaticnotdlscnsrge. Tn(ssnouicinc)uce.ual'<<BriuditerSBC.icn,Suan,ei'8c Icn.5BC(ion.(own.Sndrange~2.C:srnameotrecelvinc water(ltsurfacewaveraiscnarce) ',<a(CatB wnBTner(SCIIi~Vdi5Cnaraes Cn55BSSndl"OSiS.I!yes.))stalscnarge periods.E.?rcV)dethelandSOp)ICar(On rateSuSeaOreXOBCVeaVOOeuSeaInVermSOfinCneSOer(.Our,rOurSperday,SndinCneSperweek.:ndicstethetypeotwastewater tooeaischarqea frommlscurtail.oeferothewastewdter tyoecodegivenIntheleft.45rgin..4orethanonecoaenayoesoolicdoIB ~orcvice-neaveragenunoerothoursoei:avinRienvne'ac)i)Tvaiscnarces treatedwasvewsver snd-hercralnumoerofcayscervest.n<<nlcnvhealscnarce occurs.orovldecurrent(franthelastl2ncnrhs)crexoecteaficwratesasrecuesred. ceferrounitcodeaivenInrhelettmarginfcrvnesoorcoriste tlcwunirs."GY-ni(l:cnoallcnSOer.gear:'GD-n))l)Cngallonsoerasy;GPO-gallonsoerCsV.Rovicetnemaximumclscnslge flowI'atB<<nlcnvoudnTcnavBsuTnorlzea withinvheoennit.'x)TEirorNpDEsoernltscnlv,rheuseotsuchsflowrate>>ii)nctplocesnactual)(nitiesrricrlcn onvhetlowbutw)IIbetheiIcwrateusedtocevelocettluentlimits.Also,<<hentneivcnthlyDoerstlng Reoortssrereviewedbycompliance staffitwillhelothemtocetermlne itdnynewOrinCreased uSesmiqhthaveoCcurredatthefaaility. rovldeThedesignflowforthissoeai!Iccuvfalialsahdrae (e.g.odtcn+rearmenr SySTemflow,packagedtreatment SyStemflow,orsomeothertinitetreatment syStemtlow).ITE42XATERTOEATS'IENT ADDITIVES 'no)care>>netherdischarge Isresrec>>lvh:cn<<:tlcners,

nnlbircrs

~0<<nicrcolcclce. Itnot,continuevoItemS.B.Givename,function, sndchenicdlcompos)tion ofadditives used.Givenamesndaddressofthemanufacturer(s) otvneadditives used.'<<d)caveBxoecteamin)r~in, sveraaeana-ax)mumciscnsrce ccncenvrations otvheacai.lve(s) forthisalscnsrae. .~CiarewneTherVouVt'BdtVhediSCnarie VOr<<moVB"8dialIVB(5)beiot'8CiSCharae O.Wds~BWarer~.no(catenereovaletticlencv oiedenscaitivetronthe<<ssrewater sna<<>8Cischarae trecuenCV Ofeachsdai+Ivetothe5>>rface<<sterorgrcuna<<ster. 'IDTEiIvIsmeresocnslbllltv ofrheaoolicsnr vosuoplytneproductinformation ssreauested inthisItens.Information reauesrea outnor5uooliBdmsvresultlnthesoollcstion bairdreturnedtothBdoolicsnt 'foicop(BT)cn,32 'oiGREATLAKESENVIRONMENTAL CENTER6i6i941-22'0i530KingAvenueCc(UniDUs. Ct'lo432l2Phonei61~l297.6801Faxi61<)297.8666October12,1993Mr.JohnCarlsonIndianaMichiganPowerCompanyCookNuclearPlantOneCookPlaceBridgman, MI49106

DearJohn:

TOXICITYTESI'EPORT FORSULFURHEXAFLUORIDE GAS(SF6)Wehavecompleted ouranalysesofthe48-hour+dgPghgia ~and96-hourfatheadminnowilhi~grggpgggstaticrenewal-acute toxicitytestsperformed withsulfurhexafluoride (SF6)gasinLakeMichiganwater.TheLakeMichiganwatersamplewascollected byIndianaMichiganCompanypersonnel onSeptember 28,1993.Thesamplewastransported overnight toGreatLakesEnvironmental Center(GLEC),andwereceivedthesampleingoodcondition onSeptember 29,1993.Theg.~d'ndfatheadminnowtestswereconducted inaccordance withGLECStandardOperating Procedures, whicharebasedonprocedures developed byU.S.EPA(PeltierandWeber,1990,rMTxi'nFrhwM'm,Fourth Edition,EPA/600/4-90/027) andASTMiv,E729-88a, 1993).TiiTwiItisourunderstanding thattheCookNuclearPlantcurrently injectsSF6intoapproximately 690,000gpmofnoncontact coolingwateratarateof5cfm,whichisequivalent toarateof54pl/LofSF6gas.Thefatheadminnowacutetoxicitytestwasinitiated onOctober1,1993,usinganundiluted LakeMichiganwatersamplethatwasinjectedwithsulfurhexafluoride gasatarateof108pl/L(twicetheplant'sinjection rate).Thegaswasinjectedintoasealedairtightchamberusingagasinjection syringe.Afterinjection, thesamplewasshakenandthoroughly mixedforoneminute.Thissamplewasthenusedasthehighesttestconcentration. Areconstituted laboratory water(Hardness =172mg/LCaCO>)wasusedtopreparenominaltestconcentrations of54,27,14,and7pl/LSF6gas.Twentyfatheadminnows(3daysoldattestinitiation) wereexposedfor96hoursingroupsoften,in250mlglassbeakers,eachcontaining 200mloftestsolution(65x60mmofsolutioninthebeakers). Eachdaythetestsolutions werecarefully renewedbysiphoning mostoftheoldsolutions fromthebeakers;freshlypreparedsolutions wereaddedbacktoeachtestchamberdailyandthenumberofsurviving fishwasrecorded. TheSF6concentrations inthetestchamberswerenotmeasuredanalytically. ~AppliedWaterQualityandEnvironmental SciencesQ))AEVIC Mr.JohnCarlsonIndianaMichiganPowerCompanyOctober12,1993The~r~h~ni~acutetoxicitytestwasinitiated simultaneously withthefatheadminnowtestusingidentical exposureconcentrations. Ineachg~testconcentration weexposed20animals((24hoursoldattestinitiation) ingroupsoffivein30mlglassbeakers,eachcontaining 25mlsoftestsolution(40x45mmofsolutioninthebeakers). After24hourstheanimalsweretransferred tofreshsolutions usingawideborepipet,andthenumberofsurviving ordeadanimalswasrecorded. Thereconstituted waterusedinQ,~andfatheadminnowtoxicitytestingispreparedaccording toEPAmethods frMrineAcuTiiffflnFhwrMinQrgg~,FourthEdition,EPA/600/4-90/027). Weuseddechlorinated reverseosmosis(R/0)treatedmunicipal waterforthecultureoffatheadminnows,and.Boardman Riverwater(headwaters) forculturing ourQ,~.Deionized reversewsmosis (R/0)treatedmunicipal wateristhebasewater,towhichreagent-grade saltsareaddedtoprepareeachbatchofreconstituted water.TheresultsoftheQ.~andfatheadminnowtestsindicatethatthesulfurhexafluoride gasinjectedintotheLakeMichiganwatersamplewasnotacutelytoxic.Therewas100percentsurvivaloftheQ.inthe7,14,27,and108pl/LSF6concentrations, and95percentsurvivalinthelaboratory watercontrolsandthe54pl/LSF6concentration (Table1).Therefore, the48-hourLC~~valuewasgreaterthan108pl/LSF6gas.Thewaterchemistry datafortheg.~testaresummarized inTable2.Inthefatheadminnowtesttherewas100percentsurvivalinthe7,54,and108pl/LSF6concentrations andinthelaboratory watercontrolsgable3).Therewas95percentsurvivalinthe14and27pl/Ltestconcentrations. Becausetherewaslessthan50percentmortality inthe108pl/Ltestconcentration, the96-hourLCforfatheadminnowswasalsogreaterthan108pl/LSF6gas.Thewaterchemistry dataforthefatheadminnowtestaresummarized inTable4.Insummary,neitherQ,~duinorfatheadminnowsurvivalwasaffectedbyanyoftheSF6concentrations wetested,including the108pl/L(highesttestconcentration) and54pl/L(presentapplication ofSF6)testconcentrations. Copiesoftherawdatasheetsandstandardreference toxicantdatafortheacuteeffluenttoxicitytestsareincludedwiththisreportinAppendices AandB.Ifyouhaveanyquestions orcommentsconcerning theresultsofthesetoxicitytests,pleasecontacteithermeorMickDeGraeveat(616)941-2230. Thankyoufortheopportunity toprovidethisservicetotheIndianaMichiganPowerCompany.Weappreciate yourbusinessandhopewecanbeoffurtherservicetoyouinthefuture.Iwillbeincontactwithyoutoarrangeforthevisitwehavediscussed. 'erely,;,~.,;~-//0~~DennisJ.McCauleyResearchScientist DJM:dmEnclosures TABLE1.RESIILTSOF6ARRM!~CIOAPXR6EUUASTATICREIIEIIAL ACU'IETOXICITYTESTIIITRSULFURSEXAFLUORIOE RASISFAIIRJECIEOIRISASAHPLEOFLAKEIIICHIGAN MATER(GLCB1765)RECEIVEDOHSEPTEHBER 28,1993,FROHCOOKNUCLEARPLANTNEARBRIDGHAN, HICHIGANUSINGRECONSTITUTED LABORATORY MATERASDILUTIOHMATER(TESTDATES:OCTOBER1-3,1993)TestConcentration (AI/L)eIce'tSUIYvalEs024hr48hrLaboratory MaterControl7/Ll/L14HI/L27RI/L54HI/L108pl/L95100100100100951001001009510048-hourLC~valuewasnotcalculable (greaterthan108HI/L). TABLE2.IIAIERCHEIIISTRT UHHIARTFORA48-IIOUR~CEROOAPHUHASTATICREIIEIIAL ACUTETOXICITTTESTIIITHSULFURHEXAFLUORIOE SASISFAIINJECTEDIHTOASAHPLEOFLAKEkICHIGANMATER(GLCB1765)RECEIVEDOHSEPTEHBER 28,1993,FROHCOOKNUCLEARPOMERPLANTNEARBRIDGHAN, kICHIGAHUSINGRECONSTITUTED LABORATORY MATERASDILUTIONMATER(TESTDATES:OCTOBER1-3,1993)TestConcentrat ion(NI/L)keenRangekeenRange0issolved'xygen LTeaperature'C keenRangeSpecificConductivity oscmkeen~AIAlhIJI8PdIIAA(mg/LCaCOs)(mg/LCaCO>)Laboratory MaterControl7NI/L8.2(8.1-8.4) 8.3(8.2-8.4) 8.6(8.0-9.0) 8.6(8.0.9.0) 24.6(24.1-25.0) 24.6(24.1-25.0) 53755714pl/L8.3(8.2-8.4) 8.6(8.0.9.2) 24.6(24.1-25.0) 54327NI/L54pi/L8.3(8.3-8.4) 8.3(8.2-8.4) 8.7(8.0-9.4) 8.7(8.0-9.4) 24.6(24.1-25.0) 24.7(24.2.25.0) 511445108AI/L8.2(8.1-8.4) 9.0(8.0-9.8) 24.8(24.3-25.0) 128keasurements veremadedailyineachtestcharber.Asinglemeasurement Hasmadeatthebeginning ofthetestonacoaposite saapiebeforedistribution tothetestchacbersandattheendofthetestonacceposite sample.Alkalinity andhardnessmeasurements veremadeuponpreparation ofthereconstituted laboratory Materanduponarrivalatthelaboratory oftheeffluent.

TABLE3.RESULTSOFA96-HQJRFATHEADHIHHOMSTATICREHEMALACUTETOXICITYTESTMITHSULFURHEXAFLUORIDE GAS(SF6)INJECTEDIHTOASAHPLEOFLAKEIIICHIGAN MATER(GLCB1765)RECEIVEDOHSEPTEHBER 28,1993,FROHCOOKNUCLEARPOMERPLANTNEARBRIDGHAN, ilICHIGAH USINGRECONSTITUTED LABORATORT MATERASDILUTIOHMATER(TESTDATES:OCTOBER1-5,1993)TestConcentration (aI/L)24hreceSuvvalH~048hr72hr96hrLaboratory MaterControl7HI/L14HI/L27HI/L54HI/L108III/L10010010010010010010010010010010010010095100100100100959510010096-hourLCsovalueuasnotcalculable (greaterthan108HI/L). TABLE4.MATERCHENISTRY SLNB(ARYFORA96-HOURFATHEADHINNOMSTATICRENEMALACUTETOXICITYTESTMl'lHSULFURHEXAFLUORIDE GASINJECTEDINTOALAKENICHIGANMATERSANPLE(GLECN1765)RECEIVEDONSEPTENBER 28,1993,FRONCOOKNUCLEARPLANTNEARBRIDGHAN, NICHIGANUSINGRECONSTITUTED LABORATORY MATERASDILUTIONMAIER(TESTDATES:OCIOBER1-5,1993)TestConcentration (NL/L)OldDissolved'xygen LOLdTeaperature' NeuOLclSpecific'onductivity oscmNeuOLd~kkkIk~rdn(mg/LCaCO>)(mg/LCaCO>)Laboiatoly MaterControl7NL/L1CliL/L27NL/L54lil/L108ltL/L8.2(8.2-e.C) 8.1(7.9-e.2) 8.3(8.2.8.3) 8.2(8.2-8.3) 8.1(S.1-8.2) 8.1(8.0.8.2) 8.1(8.1-8.2) 8.0(7.C.8.2) 8.38.1(8.2-8.C) (7.9-8.2) 8.38.2(8.2-8.3) (8.1.8.2) B.S(8.8.8.9) 8.9(8.8-9.0) 9.0(9.0.9.2) 9.1(8.9.9.4) 9.2(9.0-9.4) 9.8(9.6-10.2) 6.9(6.2-7.5) 7.5(7.1-8.0) 7.4(6.6-e.o) 7.1(6.5-8.0) 7.2(6.9-7.6) 7.5(7.4-7.6) 25.0(25.0.25.0) 24.6(24.2-25.1) 25.024.6(25.0-25.0) (24.3-25.1) 25.024.6(25.0.25.0) (24.0-25.1) 25.024.6(25.0-25.0) (24.1-25.2) 25.024.6(25.0-25.0) (24.2-.25.3) 25.024.6(25.0-25.0) (24.2-25.2) 537(494-566) 556(537-587) 539(531-557) 514(502-516) 444(4C0.450) 311(303-316) 539(539-539) 547(547-547) 531(531.531) 502(502-516) 438(438-438) 304(304-304) 104(104-104) 106(106-106) 172(172-172) 128(128-128) Ileasurements ueremadeonneutestsolutions andoldtestsolutions. Thenurbersrepresent themeanandrange(inparentheses) ofmeasurements observedduringthetest.Alkalinity andhardnessmeasurements Meremadeuponpreparation ofthereconstituted laboratory eateranduponarrivalofthesample. APPENDIXARA~VDATASHEET C'RS~w~a'atSRSRIRlhRl688888888RlklhlRlbbRRf 5HRHRlHHHHIWRRSHpHHRRHSHHHHH5 WRWRRERSWESRRESRRSISWSRRIRE 0~Iay~~e~RHKSKRHRRERRRI RHRRIRQ'5SRHRRfREI RKKIRHRSSSHSHRIHIHSIHHHRRRHWWWRS 5ERRSQERQE5$ %85$ldl'5$5QRRE 'I'cathlslco~t: )'lsjINu..IcstSIII~klwihlllWjlk.QAILfPEA)2~i-'I-FlSal96-llOURSTA;tJQTypeofTest:0No.Fish/Chantbcr: 0No.ofChambers: AgcofFish:CUTETOXlClTYTESTDilutiunWater:GLCand/orBatchNo.:jlTcntpcraturc: c)ncubalor 4:2c~"c,O'irj6/(IIauTestDayTech.)nil.Trcsltncnl vclRcplicatc Number.ControlTcmcraturcDOmiILS.Cond.umhos/cmNo.Live10(0JOICI/0g'0Obsarvausnsj05ossI'i70II).Q~)70gl7d,z'tC'JIDOm'ILTclncralurcNo.LiveDOm/L17VRZZg2lg.QLl.Z00fg'17]g2>.vqn.78-+~f/l~l'll'ryOTcmcralurcNo.LiveObscrvaltons TcmcralurcNo.LiveObservations DOmII.S.Cord.umhos/cnt 0IOIO2g7./,f'.0T.0rj~7n1lCfaS.C7,IzoC//+rfjvrz>,/~nCK-/0t)hicrvstuu< hcy:DOS-DrieOuluuScsLcrPM-Paniculstc MsucrERR-ErraticSwimminRcvicwcdby:FS-FilmonSurfaceF-Floater)MM-bnmobilc ~. EFFLUENTAi%)RECEIVING WATERCHECK-INFORMClient:(t"C I-'4'ICI00-4 projectNo,:Investigators: INITIALWATERCHEMISTRY (UPONRECEIPT)DateInitialsGLCNo.Collection Date(timeinterval) Temperature pa~WATERCHEMISTRY ATTESTTEMPERATURES Date:GLCNo.Temperature pHDissolved Oxygen(mg/L)Conductivity (umhos's/cm) Hardness(mg/L)Alkalinity (mg/L)TotalChlorine(mg/L)*TotalAmmonia(mg/L)*InitialsCcnCtutjcl<zY/7$'~/DQCheckwithprojectmanagertoseeifnecessary

LrekeeEnvirnnrnenkrl CenlerC739ItastingsStreetTrarerseCity,MI49684Phone:(616)941-2239Fax:(616)941-22AOCHANCOFCUSTODYRKCO14B9OBECOMPLETED ON-S)TEANDSUBMITI'ED Wm)SAMPLES)Facility: .C~+++'/~~~+./c4.Location; re~~~~ee.'rfc'p&re.AM&ContactPerson:~-~C>r.~~-aPhoneNumber:rea&~~So~Co0ector: DateWitness:Date:-z-.s-'V3rz1ciOSAMPLEID(8-ZggC./q,4nrgDATE/I'IME OFSAMPLEi.;.-~S/ioVOLUMESAMPLESAMPLECOLLECTED COLLECTOR CONTAIN)UK .(I--M.c~e~~aDESCRIPTION (Typeofsample,source,physicalcharacteristics) PRESERYATIONANALYSESREQUIREDver>7rrCrTRANSFEROFSAMPLES:(Firstsignature issampler,lustsilenature isauthorized laboratory representative.) 1.2e5LHXF)L~~iP~r'-zs-g3V7~niifmlln<<iIPtif($~(Airii~) APPENDIXBM)ARDREFERENETXICANTDATA GREATLAKESENVIRONMENTAL CENTERSodiumChloride(NaCI)ToxicityData1992"1993grams/Liter 3.532.51.50.50APRMAYJUNJULAUGOGTOGTNOVDEGJANFEBMARAPRMAYJUNJULAUGSEPI1992I1993I48-hourLG50~Meanplus2S.D.~Meanplus1S.D.~Meanminus2S.D.Meanminus1S.D.Ceriodaphnia dubiaSurvival GREATLAKESENVIRONMENTAL CENTERSodiumChloride(NaCI)ToxicityData1992-1993grams/Liter l2100APRMAYJUNJULAUGOGTOGTNOVDEGJANFEBMARAPRMAYJUNJULAUGSEPI1992I1993I48-hourLG50Meanplus2S.D.~Meanplus1S.D.Meanminus2S.D.Meanminus1S.D.FatheadMinnowSurvival ATTAC~NT4REPORTONTHEWHOLEEFFLUENTTOXICITYTESTFORDETOXIFIED CLAM-TROL EFFLUENTATDONALDC.COOKNUCLEARPLANTAmericanElectricPowerServiceCorporation andIndianaMichiganPowerCompanyFebruary22,1993

WHOLEEFFLUENTTOXICITYTESTIntroduction TheMichiganDepartment ofNaturalResources (MDNR)issuedalettermodifica-tionfortheDonaldC.CookNuclearPlantapproving theuseofthepropri-etarymolluscicide Clam-Trol, CT-1(BetzIndustrial). Theletter,datedApril24,1992,fromMr.FredMorleytoMr.DonaldBaker,IndianaMichiganPowerCompany(I&M),allowedtheuseofClam-Trol iftheeffluentcontained Clam-Trol concentrations equaltoorlessthan0.05mg/1.Sincethedetec-tionlimitforClam-Trol is0.2mg/l,theMDNRrequiredwholeeffluenttoxicity(WET)testingtoassurecompliance withthestatewaterqualitystandardprovision prohibiting thedischarge oftoxicmaterials intoxicamounts.TheMDNRalsorequiredZ&Mtosubmitastudyplandescribing howtheWETtestingwouldbeperformed. Mr.BakersentZ&M'sstudyplantoMr.MorleybyletterdatedJune9,1992.I&M'sstudyplandescribed howandwheretheeffluentstreamswouldbesampledfromOutfalls001and002,andhowthesampleswouldbeshipped,analyzed, andreportedtotheMDNR.Thisplanalsodescribed howthedatawouldbeevaluated andspecified testingtobecon-ductedshouldanysingletestproduceanEC>0lessthan100Keffluent., Thelettermodification oftheCookPlantNPDESPermitwasconditional onthestudyplanbeingapprovedbytheMDNR.MDNRnotifiedZ&MbyletterdatedJuly16,1992thatthestudyplanwasacceptable. Treatment oftheCookPlantforzebramusselcontrolhasevolvedfromattemptstotreattheentireplantinoneoperation totreatingcomponents oftheplantinseparateoperations. Theintaketunnelsaretreatedindividu-ally,thecirculating watersystemistreatedasonesystemandcomponents oftheessential servicewater(ESW)and'on-essential servicewater(NESW)systemsaretreatedasneeded.Treatment ProramComletedIn1992ThenorthandcenterintakewatertunnelsweretreatedwithClam-Trol onAugust12and13andSeptember 11and12,1992,respectively. Thecircula-tingwatersystemwastreatedonSeptember 16withClam-Trol. Watersampleswerecollected duringeachofthesethreeperiodsasdescribed intheap-provedstudyplan.Thesesamplesofdetoxified effluentweresplitandthenshippedtoacontractlaboratory andtotheMDNRtoxicitytestinglaboratory foranalyses. Thecontractlaboratory conducted a48-houracutetoxicitytestusing~pahniafulexoneachofthethreewatersamples.Atthesametimethedetoxified effluentsampleswerebeinganalyzed, aseriesofben-toniteclaysolutions werebeingtestedforimpactonthetestorganisms. ~Dahniasp.andotherzooplankters canbeadversely affectedbymechanical (ratherthanchemically toxic)meanswhenexposedtoexcessive amountsofsuspended clay.Theseclayblanktestserieswereconducted usingLakeMichiganwaterandthesameclayusedtodetoxifytheClam-Trol. LakeMichiganwaterusedfordilutionofthedetoxified effluenttestsandtheclayblanktestswascollected beforetheClam-Trol treatments began. ~' Methods0Watersampleswerecollected fromthedischarge tunnelmanwaysusingasubmerged pumpatthebeginning ofthetreatment, atthefourthhour,attheeighthhourandatthetwelfthhouroftreatment. Sampleswerecollected fromUnit2discharge manwayandcomposited inonecontainer. Attheendofthetest,asamplewasremovedfromthecomposited samplecontainer andshippedtothecontractlaboratory. Duringtreatments tothenorthandcenterintaketunnelsonAugust12-13andSeptember 11-12,1992,therewasnoeffluentfromtheUnit1discharge .tunnel.Duringthecirculating watersystemtreatment onSeptember 16,sampleswerecollected fromboththeUnit1andUnit2discharge tunnelmanwaysandcomposited intoonecontainer, fromwhichthewaterforWETtestingwastaken.Thelaboratory followedtheprocedure forconducting 48-hourEC50acutetoxicitytestsaccording totheEPAprotocol, "MethodforMeasuring theAcuteToxicityofEffluenttoFreshwater andMarineOrganisms," EPA/600/4-85/013. Adilutionseriesof100X,50X,25X,12.5X,6.25XandOX(control) effluentwassetup.LakeMichiganwaterfilteredtoremovenativezooplankton wasusedfordilution. Four30mlbeakersweresetupforeachtestconcentra-cionand25uloitestsolutionuasputineachbeakerpive.~DahniaDulexjuveniles (<24hoursold)wereplacedineachbeaker.Temperature was.~maintained at25'+1C.Temperature, DO,andconductivity weremeasuredevery24hours.Theeffectswererecordedevery24hours.Organisms thatfailedtoremaininthewatercolumnforfivesecondsafteragentleprodorswirlingthebeakerwereconsidered effected. Resultsarereportedasacute48-hourEC5values. Atestseriesofbentonite clayblankswasconducted thesameasthedetoxi-fiedClam-Trol effluent. t'iltered LakeMichiganwaterwasmixedwiththesameconcentration ofbentonite clayusedtodetoxifytheClam-Trol. Thisconcentration ofbentonite claywastestedat100X,50X,25X,12.5X,6.25XandOZ(control). ResultsWholeEffluentToxicitytestswereconducted August15through17,September 13through15,andSeptember 17through19,1992.Table1showstheimmobility percentages ofthedetoxified Clam-Trol effluentandthebentonite clayblanktestconcentrations. Immobility resultsexceededtheEC50for100Zeffluentatalldetoxified effluentandclayblanktestconcen-trations. Thehighestimmobility resultwas30Zforthedetoxified Clam-Trol effluentsamplesand25Xforthebentonite clayblanksatthe100Xeffluentconcentration. Onetestserieswastechnically invalidbecausethecontrol(OXeffluent) had>10Ximmobility. Exceptfortheimmobility observedatthecontrolconcentration inthedetoxified effluenttestconducted onSeptember 13-15,toxicitywaslowandtheimmobilities thatwereobservedfollowedasimilarpatternastheclayblanktestseries.Immobility per-centagedifferences betweenthedetoxified Clam-Trol andclayblanktestconcentrations wereusually5Zorless.Discussion The70Ximmobility valueobtainedforthecontroltestonSeptember l.3-15wouldappeartobeananomolous value,sincethebentonite clayblankcontrol e usingLakeMichiganwatersuppliedtothecontractlaboratory inthesameshipmentshowedOXimmobilitye Threeofthefourcontrolreplicates showedallornearlyalltestorganisms vereimmobilized andinoneofthefourreplicates noneoftheorganisms wereimmobilized duringthe48-hourtest.Anexamination ofthelaboratory sheetforthetreatment concentrations showsthattheorganisms inthereplicates wereimmobilized innearlyequalnum-bers,e.g.,the50Xand100Xeffluentreplicates hadoneortwoimmobilized eorganisms. Noneofthetreatment replicates individually accounted foralloftheimmobilities, whichwouldindicateacontaminated replicate. Theimmobilities wereequallydistributed amongthereplicates. Thereisnowaterqualityparameter thatvasmeasuredbefore,during,orafterthetoxicitytestthatindicates aproblemfor~Dahniapulex'swellbeing.Giventhegenerallackofimmobilization responseoforganisms inthedif-ferenttreatment concentrations testedonanygivendateandthesimilarity oftestresultsfromonetestdatetothenest,therevaslittledifference betweenthedetoxified Clam-Trol effluentandthebentonite clayblankseffectsonthetestorganisms. Alltestswereincompliance withthere-quirement thatthe48-hourECfor~pahniaexceed100Zeffluent. inothervordsthetestsshovedthateffluenttoxicityvaslessthanthetoxicityneededtoproduceanEC>0in100Xeffluent. Thelackoftoxicityindicates thedetoxified effluenthadlittleimpactontheLakeMichiganaquaticcommunity.

TABLE1~Dahniapulex48-hourPereenrImmoblllry ValuesObtainedfromWholeEffluentToxicityTestsConducted withDetoxified Clam-Trol inLakeMichiganWaterandBentonite ClayBlankTestRuninLakeMichiganWater(clayblankimmobility percentages inparentheses) TestDateControl(OX)6.25X12.5X252502l002Aug15-17OX(OX)OX(OZ)OX(10X)15X(OX)OX25X(10X)(5X)Sep13-1570Z(OX)OX(5X)15X(10X)20X(25X)30X(20X)30X(25X)Sep17-19OX(5Z)OZ(5Z)10X(5X)10X(5X)5X(OX)15X(5X) ANALYTXCAL REPORTCookNuclearProj:WasteWaterAnalysisSubm:Jan26SamplesSubmittal Number:29609-3Location: Contact:RayV.BuhlPhone:(616)942-9600Outfall001Outfall002Circ.IntakeDetection UnitsLimitWWESSampleNo:7837178372'8373BOD,(5-Day)Sampledby:DateSampled:TimeSampled:DateReceived: TimeReceived: (1.001/26/94000001/27/9413:30(1.001/26/94000001/27/9413:30(1.001/26/94000001/27/9413:301.0mg/1.)')).)(II<'11N'<l<)d llllisIarkKvalSI'I'()l3<)'><874.(IraadRapids.Ill49588-0874. 6I6/942-<J600 I'0%9-!2-li~! llllInV>Ctrl>F-Snl'ru'e iillllllllli (.)IIII/Allo STATEMENT OFDATAQUALIFICATIONS CLIENT:CookNuclearSUBMITTAL: 29609-3Allanalyseshavebeenvalidated andcomplywithourQualityControlProgram.Noqualifications required. Thefollowing analyseshavebeenqualiTied forthereasonscited.KEYl.2.3.4,5.6.7.8.9.10.Sampleintegrity suspectuponreceipt(explain). Analysisperformed beyondEPAestablished maximumallowable holdingtime.Detection limitelevatedduetomatrixinterferences. Laboratory controlsamplevalueoutsideestablished acceptable limits.Matrixspikesamplevalueoutsideestablished acceptable limits.Duplicate analysisvalueoutsideestablished acceptable limits.Surrogate/internal standardrecoveries outsideestablished acceptable limits.Datapointsuspectduetopotential laboratory contamination (explain). Coeluteswiththecompoundcited.Resultmayrepresent acombination ofbothcompounds. Other(explain). NolerThisdocumentisincludedaspartoftheAnalytical Reportfortheabovereferenced andshouldberetainedasapermanent recordthereof.5555GlenwoodIllllsParkwaySt',.t'0Box874.()randRapids.Atl49588-08?4. 6l6/942-9600 t'nx9t'-'-6.l99

lt'11'n<~ul((I'uI~~8-'(7('ll('(' .~nlnnn(<ann+.in'I.l'I'(:XI,5I:.I'I(.':..ANALYTICAL REPORTCookNuclearProj:WasteWaterAnalysisSubm:JanuarySamplesSubmittal Number:29609-4Location: Contact:RayV.BuhlPhone:(616)942-9600OutfallOutfall001-Circ002-CircWaterDschWaterDschCircWaterDetection UnitsIntakeLimitWWESSampleNo:785327853378534.Surfactants,-.NBAS

Coliform, FecalColor(Apparent)

Sampledby:DateSampled:TimeSampled:DateReceived: TimeReceived: <0.0252<5V.Shah01/26/94000001/28/940000.<0.025<1<5V.Shah01/26/94'0'00 01/28/940000<0.0254<5V.Shah01/28/9400000.02515mg/1cl/100mlepH5555(Ilenn'()n(l IiillsPurkwaySE.POBox874.(IrdndRnPids.All49588-0874. 6I6/942-9600 I';>xllI2-(i.l9I

1V1VI:rg>mar<<~>&Sne<<cei.v>>>>1>N( 4>>>>p>j>lSTATEMENT OFDATAQUALIFICATIONS A5AI,Y'I'(:,KI,8l'.RtI(:f'CLIENT:CookNuclearSUBMITTAL: 29if09<Allanalyseshavebeenvalidated andcomplywithourQualityControlProgram.Noqualifications required. Thefollowing analyseshavebeenqualiTied forthereasonscited.SampleNo.(s):Explanation: Reason:~KEYl.2.3.4.5.6.7.8.9.10.Sampleintegrity suspectuponreceipt(explain). Analysisperformed beyondEPAestablished maximumallowable holdingtime.Detection limitelevatedduetomatrixinterferences. Laboratory controlsamplevalueoutsideestablished acceptable limits.Matrixspikesamplevalueoutsideestablished acceptable limits.Duplicate analysisvalueoutsideestablished acceptable limits.Surrogate/internal standardrecoveries outsideestablished acceptable limits.Datapointsuspectduetopotential laboratory contamination (explain). Coeluteswiththecompoundcited.Resultmayrepresent acombination ofbothcompounds. Other(explain). Note:ThisdocumentisincludedaspartoftheAnalytical Reportfortheabovereferenced andshouldberetainedasapermanent recordthereof.5555(ileum>od ltIllsParkwaySt,".POBox874.(irandRapids.Itl49588-0874 ~616/942-9600 Vas9-t2>-tijou

LockheedAnalytical ServicesDATAQUALIFIERS FORINORGANIC ANALYSES(Revised08/28/92J BDEHMNUX,Y,orZalbiForUseontheAnalytical DataReporting FormsForCLPAnalysesOnly-Reportedvalueislessthanthecontractrequireddetection limit(CRDL)butgreaterthanorequaltotheinstrument detection limit(iDL).ForRoutine,Non-CLPAnalysesOnly-Anyconstituent thatwasalsodetectedintheassociated blankwhoseconcentration wasgreaterthanthereporting detection limit(RDL).Presenceofhighlevelsofinterfering constituents requireddilutionofsamplewhichincreased theRDLbythedilutionfactor.Estimated valueduetopresenceofinterference. Sampleanalysisperformed outsideofmethod-or client-specified maximumholdingtimerequirement. ForCLPAnalysesOnly-Duplicate injection precision criterion wasnotmet.Matrixspikerecoveryexceededacceptance limits.Reportedvaluewasdetermined fromthemethodofstandardaddition. ForCLPReporting Only-Constituent wasanalyzedforbutnotdetected(samplequantitation mustbecorrected fordilutionandpercentmoisture). ForAASOnly-Post-digestion spikeforFurnaceAASdidnotmeetacceptance criteriaandsampleabsorbance islessthan50%ofspikeabsorbance. Analystdefined qualifier. Relativepercentdifference (RPD)forduplicate analysisexceededacceptance limits.Correlation coefficient (r)fortheMSAislessthan0.995.'-..ForUseontheQCDataReporting Forms'hespikerecoveryand/orRPDformatrixspikeandmatrixspikeduplicates cannotbeevaluated duetoinsufficient spikinglevelcomparedtotheelevatedsampleanalyteconcentration. TheRPDcannotbecomputedbecausethesampleand/orduplicate concentration wasbelowtheRDL.'sedasfootnotedesignations ontheQCsummaryform. LockheedAnalytical ServicesDATAQVALIFIERS FORORGANICANALYSESfgÃvkaf:;:"Og/X98$ 94JForUseOnTheAnalytical DataReporting FormsABHNUX,Y,orZN/A(%Moisture) ForCLPanalysesOnly-TheTICisasuspected aldol-condensation product.Anyconstituent thatwasalsodetectedintheassociated blankwhoseconcentration wasgreaterthanthepractical orreporting detection limit(PQLorRDL).Constituent confirmed byGC/MSanalysis. Ipesticide/PCB analysesonlyJConstituent detectedinthedilutedsample.Italsoindicates thatanaccuratequantitation isnotpossibleduetog~rggg~beingdilutedoutofthesamplesduringthecourseoftheanalysis. Constituent concentration exceededthecalibration range.Thequantitation isnotgasolineordieselbutbelievedtobesomeothercombination ofhydrocarbons. Sampleanalysisperformed outsideofmethod-orclient-specified maximumholdingtimerequirement. Estimated value-(1)constituent detectedatalevellessthantheRDLorPQLandgreaterthanorequaltotheMDL;(2)estimated concentration forTICs(ForCLPReporting Only).ForCLPReporting Only-Tentatively identified constituents PICs)identified basedonmassspectrallibrarysearch.ForCLPReporting Only-Thepercentdifference betweentheconcentrations detectedonbothGCcolumnswasgreaterthan25percent/pesticide/PCB analysesonlyJ.ForCLPReporting Only-Constituent wasanalyzedforbutnotdetected(samplequantitation mustbecorrected fordilutionandpercentmoisture). Analyst-defined qualifier. N/Ainthe%moisturecellindicates thatdataarereportedonan"asreceived" basis.Avalueinthe%moisturecellindicates thatdataarereportedbasedona"dryweight"basis.Fornon-CLPwort,RDLsarenotadjustedfor%moistureevenwhendataarereportedona"dryweight"basis.al...;:.:=:, -For;UseOnTheQCDataReporting FormsQCdata(i.e.,percentrecoverydataformatrixspike,matrixspikeduplicate, laboratory controlstandard, orsurrogates; andRPDformatrixspikeduplicate orunspikedduplicate) exceededacceptance limits.Thespikerecoveryand/orRPDformatrixspikeandmatrixspikeduplicates cannotbeevaluated duetoinsufficient spikinglevelcomparedtotheelevatedsampleanalyteconcentration. TheRPDcannotbecomputedbecausethesampleand/orduplicate concentration wasbelowtheRDL.'sedasfootnotedesignations ontheQCSummaryForm. LockheedAnalytical ServicesDATAQUALIFIERS FORRADIOCHEMICAL ANALYSES/Revised08/28/92J BHalbiForUseontheAnalytical DataReporting FormsAnyconstituent thatwasalsodetectedintheassociated blankwhoseconcentration wasgreaterthanthereporting detection limit(RDL)and/orminimumdetectable activity(MDA),PresenceofhighTDSinsamplerequiredreduction ofsamplesizewhichincreased theMDA.Constituent detectedinthedilutedsample.Constituent concentration exceededthecalibration orattenuation curverange.ForAlphaSpectrometry Only-FWHMexceededacceptance limits.Sampleanalysisperformed outsideofmethod-specified maximumholdingtimerequirement. Chemicalyieldexceededacceptance limits.';.-':ForUseon'theQC'DataReporting ForIns'," ...',"',',"','Cdata(i.e.,percentrecoverydataforlaboratory controlstandardandmatrixspike;andRPDforreplicate analyses) exceededacceptance limits.Thespikerecoveryand/orRPDformatrixspikeandduplicates cannotbeevaluated duetoinsufficient spikinglevelcomparedtotheelevatedsampleanalyteconcentration. TheRPDcannotbecomputedbecausethesampleand/orduplicate concentration wasbelowtheMDA.'sedasfootnotedesignations ontheQCsummaryform. GENERALCHEMlSTRY RESULTSClientSamleID:OUTFALL001DateCollected: 01-24-94Matrix:waterLALBatchID(s):126imDateReceived: 01-26-94PO469095-040-3N Constituent MethodResultReporting Detection UmltDataQualiflarls) DateAnalzadLALSamlaIDFluoride, inmILBromide,inmILNitrite-Nitrate-Nitrogen, inmIL340.2<0.15353.20.35300.0'0.0500.150.0500.05003-02-94L1131-801-28-94L1131-1602-11-94L1131-21Sulfate,inmILTotalCanide,inmILTotalPhenolics, inmILSulfide,inmIL300.0335.2420.1376.122<0.020<0.15<1.00.0590.0200.151.001-27-94L1131-1601-27-94L1131-2502-08-94L1131-3001-27-94L1131-11Comments: GENERALCHEMISTRY RESULTSClientSampleID:OUTFALL001CIRCWATERLALBatchID(s):126im,127imDateCollected: 01-26-94DateReceived: 01-27-94Matrix:whterP0469095-040-3N Constituent TotalPhosphorus, inm/LAmmoniaNitrogen, inmILTotalSuspended Solids,inmILTotalOrganicCarbon,inmILChemicalOxygenDemand,inmILTotalKjeldahlNitrogen, inm/LMethod365.2350.1160.2415.2410.2351.2Result(0.030<0.050(121.8(180.20Reporting Detection Umlt0.0300.050121.0180.10DetoOuellflerls) DateAnaled02-08-9402-01-9402-02-9402-16-9401-28-9403-03-94LALSemleIDL1142-5L1142-5L1142-9L1142-1L1142-1Ll142-5Comments: GENERALCHEIVllSTRY RESULTSClientSamleID:OUTFALL001DateCollected: 01-27-94Matrix:waterLALBatchID(s):128imDateReceived: 01-28-94PO469095-040-3N Constituent MethodResultReporting Detection UmltDataQualifie(s) DateAnaledLALSamleIDColorSulfite,inrng/L110.3377.1<5.0<1.05.01.001-28-94L1151-101-29-94L1151-1Comments: CQC METALSRESULTSClientSamleID:OUTFALL001LALBatchID(s):126imDateCollected: 01-24-94DateReceived: 01-26-94Matrix:waterPOI)'69095-040-3N Constituente MethodConcentration (mIL)Reporting Detection umitlmlL)DateQualifier)a) DateAnalzedLALSamleIDAluminumAntimonArsenicBariumBerIliumBoronCadmiumChromiumCobaltCoerIronLeadManesiumMananeseMercurMolbdenumNickelPhoshorusSeleniumSilverStrontium ThalliumTinTitaniumUraniumVanadiumZinc601060107060601060106010601060106010601060107421601060107470601060106010774060106010784160106010602060106010<0.20<0.060<0.010<0.20<0.005<0.20<0.005<0.010<0.050<0.025<0.10<0.00312<0.015<0.0002<0.067<0.040<0.050<0.005<0.0100.13<0.010<0.20<0.10<0.001<0.050<0.0200.200.0600.0100.200.0050.200.0050.0100.0500.0250.100.0035.00.0150.00020.0670.0400.0500.0050.0100.100.0100.200.100.0010.0500.02002-22-94L1131-9402-22-94L1131-9402-20-94L1131-9402-22-94L1131-9402-22-94L1131-9402-22-94L1131-9402-22-94L1131-9402-22-94L1131-9402-22-94L1131-9402-22-94L1131-9402-22-94L1131-9402-23-94L1131-9402-22-94L1131-9402-22-94L1131-9402-09-94L1131-9402-22-94L1131-9402-22-94L1131-9402-22-94L1131-9402-25-94L1131-9402-22-94L1131-9402-22-94L1131-9402-28-94L1131-9402-22-94L1131-9402-22-94L1131-9403-07-94L1131-9402-22-94L1131-9402-22-94L1131-94Comments: VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260Page1of2ClienSmIID:TFALL01DeClleced:24-AN-4Matrix:WATERAnalticalBatch¹:020394-8260-J-2 QCBatchID:020394-8260 LALSmIID:L111-41Dae.Receive: 2-JAN-4DateAnalzed:03-FEB-94 DilutionFactor:1SURROATERECOVERYoQCLimits12-Dichloroethane-d4 Tolene-d4-Bromofluorobenzene 989776-11486-115ContieChloromethane VinIChlorideBrmmhnhirhnTrichlorofluoromethane Acetone11-DihlrhnrnDiIfiMethleneChloridetrans-12-Dichloroe heneVinIA11-Dihlrhn2-Butanone cis-12-Dichloroe henehlrfrm111-Trihi rhnCarbonTetrachloride 12-Dichloroethane BnznTrih12-Dichloro roneBromodichlorome hnehlrhIVinIhr4-Mhl--ncis-13-Dichloro roeneToluenern-1-Dihlrrn-Hxnn112-Trichloroethane Tetrachloroethene PCEConcentration L<5<5<5<10<5<5<10<5<5<5<5<5<2<5<5<5<5Reporting Detection LimitL1010DeQ'ifier14LLOCKHEEDAIVALYTICAL SERVICES

VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGIVIETHOD8260ClientSamleID:OUTFALL01LALSamleID:L1131-41Page2of2Constituent Dibromochloromethane hlrnnhInnm-Xleneo-XleneConcentration IL<5<5<5Reporting Detection LimitILDataQualifier sSrmfrm1122-Tetrachloroethane 13-Dichlorobenzene 14-Dihlrnzn12-Dichlorobenzene <5<5<5LOCKHEEDAhfALYTICAL SERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260TENTATIVELY IDENTIFIED COMPOUNDS ClientSampleID:OUTFALL001DateReceived: 264AN-94Matrix:WATERAnalytical Batch:020394-82604-2 LALSampleID:L1131%1DateAnalyzed: 03-FEB-94 DilutionFactor:1QCBatchID:020394-8260 Tentatively Identified CompoundNOCOMPOUNDS IDENTIFIED Estimated Concentration Iyg/L)Retention Timelminutes) DataQualifier(s) LOCKHEEDAIVALYTICAL SERVICES SEIVIIVOLATILE ORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270Pae1of2ClienSmIID:OUTFALL001DateCollected: 24-JAN-94Matrix:WATERAnliIBh4':24-7-AQCBatchID:8270-SEMIVOLATILE 4825LALSamIID:L1131-55DateReceived: 26-JAN-94 DilutionFactor:1DaExr:1-JAN-4DateAnalzed:03-FEB-94 SURROATEREOVERYY2-FluorohanoiPhenol-d, Nitrobenzene-d, 2-Fluorobi henI24-TrirmohnIp-Terphenyl-d 2722645748370Limi21-10010-9435-11443-11633-141Phenoln'Concentration L<10Reporting Detection Limit10Delifisbis2-Chloroe hIetherhlrhnl1-Dihlrnzn14-Dichlorobenzene BenzIalcohol1-Dihlrn-MhIhnIbis2-Chloroiso roIeher4-MehIhenolN-Nir-Di-n-rIinHxhlrhnNitrobenzeneIsohorone-NirhnI4-DimBenzoicacidbis2-Chloroethox mehane4-DihirhnI14-TrihlrnnNahhalene4-Chloroaniline Hhlrin4-hlr--mhlhnl2-MethInahhaleneHexachloroc cloentadiene <10<10<10<10<10<10<10<50<10<10<10<10<10'0101010101010501010101010LOCKHEEDANALYTICAL SERVICES SEMIVOLATILE ORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270ClientSamleID:OUTFALL.001 LALSamleID:L1131-55Pae2of2Constituent 24-TrihlrhnI4-TrihlrhnI2-Chlorona hthalene2-Nitroaniline DimhIhhIAnhhin26-Dinitrotoluene 3-Nitroaniline Anhhn4-DinirhnI4-NitrohenolDibenzofuran '4-DinirInihlhhl4-ChlorohenI-henleherFluorene4-Nirnilin4-Dinir--mIhnIN-Nitrosodi henlamine4-BromohenI-henleherHxhlrnznPnhlrhnlPhenanthrene AnhracenerIDi-n-IhhIFluoranhenePrene8InIhhI'-DihrBenzoaanhracnChrsenei-hlhxDi-n-IhhIBenzobfluoranthene Benzokfluoranthene BnzrnConcentration IIL)<10<25<10<25<25<10<10<10<10<10<10<10<10<10<10<10<10<10Reporting Detection LimitIIL)102510252510101010101010101010101010DataQualifierls) Inn1rnDibenzahanthracene Benzolhi)erlene<10<101010LOCKHEEDANALYTICAL SERVICES

SEMI-VOLATILE ORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8270TENTATIVELY IDENTIFIED COMPOUNDS ClientSampleID:OUTFALL001DateReceived: 264AN-94Matrix:WATERAnalytical Batch:020394-8270-A LALSampleID:L1131-55DateAnalyzed: 03-FEB-94 DilutionFactor:1QCBatchID:8270SEMIVOLATILE 4825Tentatively Identified CompoundNOCOMPOUNDS DETECTEDEstimated Concentration (yg/L)Retention Time(minutes) DataQualifierls) LOCKHEEDAIVALVTICAL SERVICES

OILANDGREASEEXTRACTABLES ANAIYSISRESULTSBYFT/IRUSINGMETHOD413.2ClientSamleID:OUTFALL001DateCollected: 24-JAN-94 DRiv:2-AN-4MrixWAnalticalBatch¹:020494-413.2 LALSamleID:L1131-75DateAnalzed:07-FEB-94 DilinFr1Dr-FB-4QCBatchID:020294-413.2 Constituent OilandGreaseConcentration mLReporting Detection LimitDataQualifier(s) LOCKHEEDANALYTICAL SERVICES PESTICIDE ANALYSESRESULTSBYGC/ECDUSINGMETHOD8080linSmIID:TFALL-01Doil:4-AN-4DateExtracted: 31-JAN-94 Matrix:WATERAnalytical Batch¹:013194-.8080-E-4 LALmIID:L111-DeReeiv:2-AN-94DateAnalzed:01-FEB-94 DilutionFactor:1QCGroupID:8080PEST/PCBS 4822SRROATERECVERYTCMXDCB5039QCLimits60-15060-150Constituent Concentration Reporting Detection LimitDataQualifier(s) A-BHB-BHCG-BHCD-BHHPTAHLRALDRINHEPTACHLOR EPOXIDEHLRDANEENDFANIA-CHLORDANE 44'-DDE44'-DDTDILDRINENDRINENDOSULFAN II4'-DDDNDRIADHYDENDOSULFAN SULFATEMETHOXYCHLOR TXAPHNEP-11PCB-1221PCB-1232PB-142PB-14PCB-1254PCB-1260TECHNICAL CHLORDANE <0.05<0.05<0.05<0.05<0.05<0.1<0.1<0.1<0.1<0.5<20.050.050.050.050.050.10.10.10.10.514.LOCKHEEDANALYl'ICALSERVICES RAOOATAREPORT(ra01)IndianaHichiganPomrCo.eBridgman,NI OrganicandInorganic Contaeinanta (ProjectC(XX.JENI) ClientSangriaIO:OITFALL001LALSanplaIO:L1131.b5HatrixtllaterOateCollected: 24.JAN.94 OateReceived! 26.JANE94LoginNuaber:L113'I8%3FCo()akl ttientg""44Mi@KN~>w "~Anal)Iaed:"' SetcIT~<-~5~~i'"" Qi'F:."'<~)'..'".""."Acti Vf>Q',5.'rotg~gj'N@:-:. ~~i>Oatmeal':::~lUnita;."., '.GrossAlphaGrosaBeta23-FEB94GRALP/BETALAL~0060475623.FEB.94 GRALP/BETALAL.006047560.43.21.11.522.2pCi/LpCi/LPage6 RADDATAREPOP.T(ra01)lndfanalffchfgan P~rCo.~Brfdgman,NI Organfcandlnorganfc Contaninanta (ProjectCNX.JEkf) lfatrfx:RaterCIfentSarpfelOsOUTFALL00'IDateCollected: 24.JAk.94 LALSaepfeID:L1131-89OctaRecefvedt 26.JAk.94 LogfnktnhertL'l13'IRa-226Ra-22822-FEB-94 RA226LAL-0073477123-FEB.94 RA228LAL-007455030.0201102230.440.59pCI/LpCI/LPage10 PHMeterCPC/PlOL-CaldatedueSampleTimeSamplegSampleDateCDMEnteredbyPHAnalysis(LAB.079) Outfall0010po~K=5.3.56)SampleC/ph(priortocorrection) 7)NH3pHcorrection .9EgO2.7e75.3.68))ampleresultsC/pH(after'7.7PNHCorrection) 3SampleSampleTimeSample$jSampleDateCDMEnteredby5.3.56)SampleC/ph(priortocorrection) 7)NH3pHcorrection 5.3.68)Sampleresults'C/pH(afterCorrection) 9)LAB.041SpecsVerifiedby:h/IRSupervisor Review/Date ~W+l&Formpreparedby/DateFormapprovedby/Date12THPLAB.041.25s Revision1 Outfall001Determination ofTotal(Lab170)ChlorineInstrument CPG(j50~StandardICN-CIDj( 2-5I~Technician Sample/Standard SamplegDateTimeCDMEnteredby3D1)Absorbance 6.112)Results,ppmC.w3}Dilutions made4)Results,ppm((I2*83)5)1AB.041SpecsVerifiedby:~)9Supervisor Review/Dote~MR tFormpreparedby/DateFormapprovedby/Date12THPLAB.041-25]l Revision0 SEEINSTRUCTIONS ONREYERSESIDESECTIONIINUMBERPERMIT~NZ0005827A~LCCATIQIOFDlSCHARGE~002~SWe,~Wi,we-(TIWIe~06,iiNS~0,6STJIISE~l9WDISCHARGE LOCATIONSCHEDULEDeIFYESeI.ISTDISCHARGE PERIODSNAB.WCFRECK!vltO WATERi!E.'RcuWATER CRNAECSLRFACENC.OOYOUDISCHARGE SEASQtTALLYY (IFNQeCcttt!tATE TOE)e'Oe/%YYESLiAKiEi4TZCiHTZGANeOe/DAYFLOWRATEWASTEWATER ~TY~DCONTACTCOOLINGNONCONTACT COOLINGPROCESSSANITARYSTORMWATER ~NITc001MGY2MGD3GPDITEM2WATERTREATMENT ADDITIVES EeLS/iDAPPLICATION RATEF>>TYPEOFWASTEWATER DISCHARGE GeDISOIARGESCHEDULE(YEARLYAVERAGE)INe/tR.WRe/DAYINe/WKe~~LJLLJ~LJ~~~EINWASTEIIATER IYPECOCEL~JIOISIS/DAY ~24eeevzweeHeDISCHARGE FIDHRATETOTALYEARLYDAILYMINItTPIIXTILYMAXIPAMpp!NIT~CODE 0~21820~2e"AXISDES!BIDISCHSRGE FLDIRATE~AeCOYOUUSEHATERTREATIENT ACDITIVES TOTREATYTXRDISCHARGE? (IFte,CONT!tAETOITBI3)8~NAtEFutct!CN, ANDc!EHICALCOMPOSITION CFTHESEAlXIITIVESe wIEQXIEDESIGN1820NACert/MEANDADCRESSOFMAIAFACTIRERS OFTIESEACOITIVESe I~,HEMAXIMKADISCHARGE FIDttRATETOBEAUIHCRIZED INPE%IT.18202UNITSCODE1Mg/I2Ug/INAD.EXPECTEDDISCHARGE CctCENIRAT IONCFAIDIT!YES.NAADDITIVENAtEMININDIUNITSAVERAGECODEIttITSMAXltSPICODEAcolTIYENSr%ADDITIVENAtEE,DOYmtTREATTIEDISOURCTE 10RBQVEACOITIVES? 'NAF.wHITISTHERBQVALEFFICIENCY ANDDISCHARGE FREILKNCY. NAADDITIVENAIEADDITIVENAMEADDITIVKNAtEQYESKRBOVALLJ/~LJHRS/DAYDAYS/W.LJG~ASANAITACttENT TOIHI5APPLICATICN PROVIDESPECIFICMA!tVTLIAN CRAOUSeTICTOXICOUIGICAL DATACRREFKRBICE WHICHAREAVAIIABIE ANDINFOBQTICN ONTHERATEOFDEGRADATION OFTIEPROIXCTSFOREACHA!OITIVKe NA 30 SEEINSTRUCTIONS ONREVERSESIDESECTIONIIPERMIT~Mypppg827AIII'ALLtUKRA~%4KOFPROCESSCCttlRIBUTING TOTHEDISCHARGE /ROUGHTHISOUTFALL<<8SICCCCEB~PROCESSSCHEDULE(YEARLYAVERAGE)tOLRS/DAY ~24I~OI~2WTR49II~/vPROCESSSTREAMSCONTRIBUTING TOOUTFALLDISCHARGE IhIhIAICt~0C.PROCESSWASTEWATER FLCWRATEBasis:1993actualdatasubmitted OnDMRSD.PROCESSPRODUCTION RATEAvAX<<"EGFPROCFSSCCttmIBUTltIG TOTHEDISCHARGE THROUGHTHISOUTFALLAIIDSICCA/DENATOTALYEARLYDAILYMINIMADAILYMAXIP%B48,0844~5u61743~61POUNDS2GALLONS3CUBICYARDS4TONS5MGY6MGD7GPDTIME1HOUR2DAY3WEEK4MONTH5YEARIhIh00I0C',0B.PROCESSSCIEDULE(YE/UILYAVERAGE)CAPROCESSWASTEWATER FLOWRATE'.PROCESSPRODUCTION RATEAIIAtEOFPROCESSCONTRIBUTItIG TOTHEDISCHARGE IHIOUGHTHISOUIFALLAtiDSICCODEBAPROCESSSQELX1Z(YEARLYAVERAGE)C.PROCESSWASTEWATER FlOWRATED.PROCESSPRODUCTION RATEA.NA%OFPROCESSCONTRIBUTIttSTOTIEDISCHARGE NATHANDSICCODEB.PROCESSSCHXILE(YEARLYAvERAGE)CvPROCESSWASTEWATER FLOWRATEDvPROCESSPRODUCTION RATEAANAtEOFPROCESSCONTRIBUTING TOIIEDISOIARGE ,THOROUGHTHISOUTFALLAND-SICCODEB~PRXESSSCHEDILE(YEARLYAVERAGE)CvPROCESSWASTEWATER FU)/tRATED.PROCESSPRODUCTION RATEAVYAVY/OAY ~DAYY/VYAATOI'ALYEARI.YDAILYMINltRHDAlLYM4XItulTOTALYEARLYDAILYMINIMMDAII.YMAXI'vvAVY/AAV ~AAVY/VYAA TOTALYEARLYDAILYMININNDAILY."AXINJ4AAVY/VVAA TOTALYEARI.YDAII.YMINIONDAILYMAX!ANUNITS/TIMEINITCODEWITS/TIPEUNIT~UNITS/TIVE33 <<$<<<<3~3~1<<<<J~I3$<<rn,SCal83OC(8~I8JWra8aC<<ater<<3,8<<'5ahJI-'=,=:=<<I:='.=".>>==SoulT'.'"=RAh":=C:bh0"E;R"!Jt oAGE7YCIIREXPIC't'r l3<<*8Si8J8<<<<3ItVen.SaveIaf<<<<\<<~<<~5$)cA<<w<<x<<555COVi<<OCi8<<13CBSecIcnI'.=cr<<ac-:"<<Iv'a< c:scharce Ccint3Secarate3~3c'1<<'~'~IS~38353,~"Iuce".'r.et'var OrSecCtJ.'atet'8C,io1,38CC~Cn.(Own,andrange~JsT<<.8ece"vi.g<<8elIifsulI)ce<<atefo:sc,al<<8).'1CicaTO<<hetter'3ci.Tvcischarces ",",358351albasis.(fyes,iIStCIscnarcecarleds.-rovlCe-"e331COCR)Ication rateScseecrOxbectedtobeusedInterrSCt'nCneSCer"our,~curSCerdav,andIncresper<<eex.Indicate-ne<<vceofwastewaT8I obeisc..reedfrcnthiscutfall.nefectothewastewater tvaececaoivenIntneleft-atgln.VOre-CanOneCOCemayOeaabliCable. 3":vice--eOverseenvnbercf"ours.Ot:av:r<<nic.8xclli~v3cnat'$~ea<<c<<asOwater38Tainumberofdayser,ear<<t,<<<<StO3"OVICOC.rtant:frcnthe185tI"nontnS)CrOXOeo,eo3ICWrateS85reoueSTed. RefertOunitCedeOiVenIntheleftmarginFOrThe3cbroariate flowunits.'4Y-millionca)lot5derveer:'40-milliongatlonsDerCay;N)-gallonSOerday.o-ovlce-te-axi"umcisc1arge ftowratewnlchvouant31waveauthorIted'<<itl'In18bernlt.'J0T~:mor'JnoEsbermitsonlv,"eusefSuch3flowrate<<illnctblacoanactualJlnltrestriction ontheflewutwillbetneflawrateusedtodevelooeffluentIin(ts.3)so,<<nentneIvcnthiyCberating Rebortsarereviewedbvconoltance staffItwillhelothamtodetermine ifanyneworincreasec usesmlohthaveoocurreoatthefacility,. !.nrov)det"edesign'Io>>forthissoeciflcoutfalldiscnarce Ie.g.batch<<reatnent svstemflow,cackaoedtreatment systemflew,orsoretnerfinitetreatment systemflow).TIATSRTREAT'IS'lT PDOITIVES 'ncicate<<netherclscharce Istreatec<<a'tnonc)tloners,inn)bitors~orm)crob)deice. tInoT,continuetoitem3.:ivename,,;nCticn, andChemicalCcncOSitionOfaddltlues <<Sed..)Je13J83ncNcress1'8nanufac3o\5)oftheadditivnsused."c)cateJ<<cec<<ecn)nimun,averaoe81<<."Sxi-umdiscnarce ccncent<<atlons of318adoitlveis) 'cr-1ls:Ischarce. -c'Ira-8-<<<<er.Cu-<<3--"8$'.Sc~!rce ".-~ve-"8Scc-)veis):o',cre clscrarce o'stewater. '"dicate"8removal8'ftc:Oncv.<<achacditivefrcn.heastewater andthedischaroe frocuencv ofeachaddit>>Jetothe3'rtaoe<<3,8<<'-'I-8resocnsibili vc'.-TeaecJtcant Tosuoolvthearocuct'.nfottta!Ion asrecuested InthisItem4.Information rdues>>cbct-otSvbbliec~avresultl1t"8aboIlcat)81bel"or<<Tur18cto~heaoolicant 'orcomoiet)cn. 32 SEEINSTRUCTIONS ONREVERSESIDESECTIONIIPERMIT~Mt0005827NUMBERGROUNDWATER DISCHARGE INFORMATION %IF%.IlÃBA.ISISEDISCHUIGE FRCMTHISCUTFALLDIREC1EDTOBIEGRQNsDGRGRQU7CWATERS? (tFtO,CONTlttUE TOITEM5)B~HASAHYDRQGEQLCGICAI. STUDYGRITSEQUIVALENT BEENPERFGIYED ORISTHERESIFFICIENTcURRENTHYDRGGEQLQGlcAl. INFORMATION AYAttaBLE AsREQUIREDBYTI4wATERREsQURcE's CGtltISSINI PART22GROlGIWATER RULESOFADJUST1s1980R52322O7(PAGE<<Q)THISEXIS'TING ORPROPOSEDDISCHARGE? IFYESATTACHACOPYCFTHEREPORT.C.AREYQUREQUESIIOANEXEMPTIGN FRCMSUBMITTtt2G AHYDROGEQLOGICAL REPORTUt2QERRILER.323.22(I7 (7{})(PAGEg)ORFROMGROLCIDwATER MONITORING t)EQUrtREMENTS LNDERRULER.523.24'5) (PAGEUg)QFTHEPART22RLLEs.IFYEsATTAcHDOQRENTSANDEXPtattATICtt TODBONSTRATE THATY(XFIDISCHARGE HEXADQUAt.lFYFORANEXPION.DsAREYGUREQUEsTlto AvaRIattcE FRcMRIAE323.22(5(PAGEL~)(NQtmEGRADATIGN) 0FTHEWATERRESOURCES CCtltISSICN PART22GRIEtDWATER RULES?IFYESATTACHSUCHDOCUMENTS ASNECESSARY TODEMON@RATE THENEEDFORAVARIANCEINTERMSOFBEcRITERIAsPEcIFIED INRIAL525s~o(PAGE~0FTHEPART22RULEssNANANA~0.02YESCI:EsYESXNQEsI,ISTAIJ.CtetICALSu)STANCES WHICHAREINMICHIGANSCRITICALMATERIALS REGISTERTABLEIV(PAGEtt)AND/QRUss~EPAsPRIcRITYPQILUTANT LlsTTABLEv(PAGE7)cRANY0THERslssTANGEs HIICHAREORHAYBECCAINJIHIOUS TOBEDESIGNATED USESOFBEGSXSQHATER ORIDTHEPUBLICHEALTHTHATAREDISGORGED OREXPKTEDTOBEDISCHARGED TQTHEGRQUIDtATERAY THISFACILllYs ESTIMATEBIEFINALEFFLUENTCONCENBIATION ANDRECCRDALLDATAINITEM7OFSECTIONIIINTHISBOO@ET.NQTAPPLICABLE/BELIEVED ABSENTNACOD(OetICALOXYGENDEMAttD)TOC(TOTALORGANICCARBON)'un'aNITRQGEN(asN)TOTALSUSPENDED SOLIDSEXPECTEDWASTEWATER CHARAC-slcsUNiTSCODE~TOTALhOSPHNUS(ASP)BEAPPLICANT MAYBERECUIREDTODOADDITIGttAL HASTEANAL'(SESs AsDISCHARGE CHARACTERISTICS tTEM5BQD5(FIVEDAYBIOCIEHICAL OXYGENDEMAt4t)CONCENTRATION PRESENTiDATAPROVtDEDINITEM7u1uluLJu1u1uwtTScQDEIIANALYsES~TYPECODE1Mg/I2Ug/I3COUNTS/100ml.4S.U.5'F6LBS/DAYTOTALRESIDUALCH.CRINEDISSO!.VED OXYGEN'PHFECALCOLIFORMBACTERIA~ERATU2E(sue+)1~iERATIRE (wINTER)MIN~7~0~73,u5~60u4~89u7ulu3u5u5u1ulBsOTHERWASTEWATER CHAIIACTER ISTICSSAMPLEZXEF1GRAB224HOURCOMPOSITE 0ILttGREASEuIuuuLJu~SEEATTACHEDSHEETSFORANALYSISDATA*Basis:1993actualdatasubmitted onDMRSRECIIIRED INFORMATICN FORSURFACEHATERDISCHARGES ~35 II~resJ"asrsC"es35$lS3rS"""r'S5ISCa(ielfSrvIsr',Sc'.tv.-",en'esvs:'nk0-c3nvrcerwiIIOs355rchec.-.-Cer"SCSCes5eJIrevfcstrskssssITCH3=creac-'sdlv:dual Iscnarceccirt3searaesetcfrJJoCCC53'llu+CTJsfr-',I.PCcuATIC .3"-er-"e"3"s'"eprcCeSS<<niC"Cc"~"'C.tes --sIS5SCnalCe.--"vrce--e"""er-IC-""e"clca-e-;evearlvSverageprocessS=heculer"cutscercavnccavs-:er-lear. .~providetneprocesswastewater flowrateinformation asrecuestec basedonyourlastl2rrrcnthsofoperations. rtefertounitcodegivenintheleftnatcinfortheappropriate flowunits.pocessproduction cate-certainperritI:rritatlons lrravoecasedcnproduction rates.Theproduction ratesusedtoletsrnlne CernitlimitsShallerepTsSen-ed >V3reaSCnapie rSeasureC<<C-ualCrCCVCtiOn CfthefaCIIISV,SVCnaS:t""otic"ccln""e"icnrent%cJ"ecre'llcu5 'lea.~crneerrcnthlvaveraceforthenirihestof,reorevlcusfiveyears,ortne..lasonaple "easvreas5~steorn30>re'.-,.-'..-eccr'csr -resSrc"scvlations. rew5Jp(escr'swciscnar'cel 5~a.<elTtn5sar),eestfeatsSIncrolecsedproduction .Cr3-CCVClcnrs-esin--s-SrstSno..'-5.Se',ntroSCCIJcac,e,.=.=.;.A. Cate"Orioal ruieSSndneouiaticnS Cr' SEEINSTRUCTIONS ONREVERSESIDESEGTlONIIPERMIT~ME0005827NUMBERlM6PRIORITYPOLLUTANTS ANDADDITIONAL iNFORMATION FORSURFACEWATERDISCHARGE ONLY(NFJILLMBr>>>>EFQUDWIMGREQUESTED INFORMATION e~rADDRESSED ava>>'URFACE WATERDISCHARGERS, 6'>>JUSEDISCHARGERS ~s>>'RQVICE EJECTEDVALUESFCRIHEQUANTITATIVE AMQUALITATIVE It<FORlQTIQM REQUESTED BKLQW.A.:STHISFACILI1YAPRIMARYIl<DUSTRY? (REFERTOTABLEIAPAGE4+SQTOE)(tFv<sGQTO3)B.INDICATETYPECFPRIORYINDUSTRYASLISTEDINTABLEtAPACiE4+.JuratAJEWITHC.)CXESIRISOUTFALLDISCHARGE VlaAINAllYPROCESSWASTE'>>JATER? (IFMGOTOE)(IFYESGQTOO)O>>NDICATK WHICHGC/tYJFRACTIONS WsfBETFSTEDFOR~(REFERTOTABLEIAP4%U~IJQIEIFcREAcHGc/HsFRAcTIQNcHEcKED,EAcHsPKclFIcQRGANlcToxicPOLLUTANT 'WITHIN~MHFRAcTtQN~BEANALYzEDF0R(sEETABLEIIAPAGEIJ2,INADQITIQN>> AU.PRIMARYIMUSTRYAPPLICANTS. WITHaPROCESSwasTKWATKR otsoURGE~PRQVioEQUAMTITATtVE DATAFOREACHTOXICPOUIJTAMT IMTABLEIIIAPal<4+~RECORDALLDATAONFORMSPROVIDED(ITKH7)INTHISBOOKLET>>(CCNTttAJE 'WITHEKBOX')~002YE<JQSTMELECPMRXYESXvQLATILEXBasE/MEUIRAL ACIDCIPESTICIDE

• • E~IF~<SURFACEWATERDISOIARGE APPLICANT (PRIIVUIY ORSECCNDARY IMIVSTRY)>>

REGARDLESS OFTHETYPEOFDISCHARGE>> KMWSORHASREASONToBELIEVETHATANYPOILUTAMT LISTEDINTABLEIIAANDIVAPAGES~IsDISCHARGED FROIANYOJTFALLTHEQUANTITATIVE DATA~BEPROVIDED>> RECCRDAU.CATAONFORMSPROVIDED(ITKH7)INTHISBOOKLET>>wr.APPLICABLE/BELIEVED ABSENrOXPRESENT/DATA ISATTACHEDF.IFJUJYSURFACEWATERDISCHARGE APPLICANT (PRIHARYORSECONDARY INDUSTRY), REGARDLESS QFTYPEQFDISOIARGE>> IQJQWSORHASREASONTOBELIEVEANYPOultfANTS LISTEDINTABLEVAPAGE~QAREDISCHARGED FRotANYCtffFALLTHEAPPLICJUIT t~DESCRIBEREASONSFORTHEPIKLUTANT BEINGPRESENTANOPROVIDEANYAVAILABLE QUANTITATIVE DATA>>RECCRDALLDATAONF(XttSPROVIDED(ITEN7)INTHISBOOKLET>>XMTAPPLICABLE/BELIEVED ABSENTG>>AU.SIRFACEWATERDISCHARGE APPLICANTS (PRINRYANDSECONDUIY IMXJSTRIES) ~QRHAMLFActutES 2,4,j-TtttostxtQPIEMKY AQETtcActo(2,4,5-r);-(l,4,5-TRIQHLDRQPWEMxY PRQPAMICacto(SILYEx,2,4,5,TP)>>4>>&IRIotJxtcPHEML (TcP);0RHExAcKoRQPtK% (HP);(ALLDATAF0RTHEABOVEi%STBEGENERATED USINGSTJUIQARD ANALYTICAL CALIBRATION PROCEIXRES) ORKilty'sORHASREASONTQBELIEVETHATTCDDtSORHAYBEPRESENTtNTKIRDtsCHARGE>> ~REPORTQIALITATIVE DATA>>GEIERATED leIOIUSEDASCREENIWPROCEDNEMTcALIBRATKD 'WITHANALYTlcAL sfANDARDs, F0R2.5./8>>-TKtttaotoRQDIBEMzo-P DloxlN(TCDD)>>RECORDALLDATAONFORFARPROVIDED(ITEM)INTHISBOOKLET<~',Fr>>'ESURFACEWATERDISIHARGE APPLICA<VT KMWSORHASREASONTQBELIEVE1>>ar3IQLGGI(AI a~xlcllYTEsTs'WEREMADEINTHELAsTTHREE(5)YEARs0NAttr0FTHE4VLICAVTSDISCHUIGES CRONARECEIVING HATERINRELATION10ADISCHARGE>> PROVIDETHISINFQRHATICN ASANATTAotEMT TOTHISAPPLICATION>>

FACQMIRACTLU}QRATCRY CRCQNSLLTIW FIRNPERFORMED ANYOFTIE<UAAYSESREQUIREDBYTHISAPPLICATION>>

PROVIDETHENAMEANDADCRESSOFEACHLABCRATQRY ORFIRNAMTHEJVJALYSES PERFCAKDASANATTAOtENT OFTHISAPPLICATION>> QQYQUDlscHARGE ANY0THERToxicQRIMURIQUs{KHIQALsutsTAMQEs NQTLIBTEDINTABLESIVPAGE(IAIOIIATHIQU4tVAPAGES~~<t~vES>>THENIDENTICTHE~MAGICALSUBSTANCES JVJDESTIMATETHEFINALEFFUJENTCONCENTRATICNS. SIEPIITTHISt<VQRHATICN ASANATTAOt%MT TOTHISAPPLICATION>> XwrAPPLIQABLE/BELIEYED ABSENTQPRESENT/DATA isarraoEDMrAPPLICABLE APPLICABLE/SEE ATTACHED*QMTAPPLICABLE XaPPLIQABLE/SEE arfacHEDMTAPPLICABLE APPLICABLE/SEE ATTAOIED*SeewholeeffluenttestdataattachedtoOutfall001.**Pesticide dataisnotrequired;. however,itisprovided. ~>>o>>>>--u855~35'ce5rce*ate('540n53"e>>cr"""ev~---e5-a-e5<<'5-'--ehleaveb>>anx31c3"u,oet<<>>IIceasslcrea. asa$e<>JSCCSV'slSCbt>>a<<<<>>5e<<a8>>5>>-3.e-.O:"CreSubeta"TIble5.3"Ss'rsv:lel"sourSc.eST"S,,rantea bv--*1sal.aa55t.'.,'.v'"cent'.asc.tassts~~uav'vestcermiss(cn 'raravcur=e<<~-'""avt"cr'Tv 33<<5tsl54Sus5.eahaaVS>>5IToes5JbstantlasIsIen3.3(utfSIIS.5ca~it-Iran autncrl-v,:n asecarates"eetettac1ec-."."eaaotlcaticn t"t'=enrvcaser.erv-"eS.taslIS*niC1vCucic1OT-eSTstdS.ostarrias Ivlcenti5(TOtheOut'.alIcrzrerictoxiccollurantS 3Is~8'3aas3ass'5~e55%e<<action ~.r.Tte~ecs'cctsflTITatsveSnaTCXICOSluranTSSSreauireabymarta22~Zl(a)(7)(Ii)(A)OrIZZ~2l(8)(7)(IiI)(A).vaseoart53reself<<exolanarcrv Snaonotreauire'>>.rttetInst(ucticrs.Slmclva)oTt'tcuanebencarp3<<a.oassncicated. 53".5'3>>3ear>>esaI<<er'855/5ee<<e>>>>COe>5'5Cn~<<sin'9/a+"3<<ICns>>IVI>>t>>"<<SOS<<l<<C5l5TOCet>>3"SssScectrtscccs. ='racrions. 9<>etre<<~l'.'3'v5<<as35".eg>>amersg<<e<<cr5<<:,>>'s'rcraaroarabrv/ Sr/VS=racticne5Ti:lcanaReocrtlna =xemotlcns axtileallissrcustrv-<<llsourr>>C/VSSrtanicfracrlo1s !"rT"erreiqe":Ils'catecorv ~-=eSTICICe <<aCriOnanallOthetSubbartSCfThlSIrCuSrry.:rela'lin(na anaCresslnaIndustry/latI!c~case/"cuts'al, 5>>a=e5'::e"3.Icrs-RBasea>>a~lecic'u3talsSubcateaorv. -all'r""/"Srganscaractacns 'sl-t"ersubcareaories ofthisincustrv. .umanaStnaaChemicals Industry-SSCSCIC(de fraCtiansntheTallQ(lWOSInSubCateaarV anOtheRasinSaseaOeriVatiVes Subaatea)ary. -tscsticiae andbase/neutral Fractions inallocherSubcaceaories ofthisinduscry. 3atoandoaocrS<<avstrv-aCS(iC:de fraCCianInPaOeraraae SulfiteSVOCateCOries (SubOarCS JandU).~3}sct-cut>>.3i 3-cscsticsae lcttc-4~<<ocinxsuboart'),olssolvina KrastsuboartF,anapaoerboara frc<<castea)ocrSuooas't8,valetile.baSC/neuCral, OeSCiCiaefraatianSs1CleBCTSleaaneaKrafCSubOartSI.Semi-ChemiCal SubOarCS8andC.andyonintcaratca.c(ne PaoersSuboarte.<<csa.Sascttcutral, anaocst~cacfractions anF~neBleacneaKraftSubOartI.Oissolvsna SulfitePaloSubaart'(.",~rauna-aoap:ncssaoerssuboarto.marxecBleacncaKraftsuooarco.TissuefromMastcoaoer suboartT.andNonsncearaced Ti55ueeaoersSuboartS.StcamElectr(cPo>>erPlantInduscrvBasctneucral tractionsntheOnce-Throua)n Coolinqdater.tivAsh.anaSoctomAshTransoort 'Maccrorncess>>astescreams.

38 SEEINSTRUCTIONS ONREVERSESIDESECTIONIINUMBFRWi4II00058279JIFRLMB~002USETHISDATASJEETTORECORDINFORMATIGN ASRECUIREDIN:(CHEQ<APPROPRIATE BOXFCRIttICHINFORMATION THISDATASHEETREPRESFDJTS

~)CRITICALMATERIALS l.SECTIONlliITDI4E~GROLttDLLATKR DISCH/>>RGE INFORMATION (PAGE55)X2.SECTIONII.ITEMb.PRIORITYPGLLJJTANTS INSLRFACEHATERDISCHARGE (PAGE37)TOXICPOLLUTANTS HAZARDOUS SUBSTANCES INDISCHARGE BiLISTANYCRITICALt"ATERIAL (TABLEIVPAGE6)NOTADIJ2ESSED INSECTICttIIITEMFP,RIORITYPCLLUTANTS MILCHYOUJGXJPtORHAVEREASGNTLLBELIEVETOBEPRESENTINTIEDISCHARGE>> SEEREVERSESIDEGFTHISPAGEFGRFUJ7TIERDIRECTIONS>> t2OTAPPLICABLE APPLICABLE(SEEBEL7at)UNITSCODE1Mg/I2Ug/ILBS/DAYKG/DAY~P>>MPLEi>>P1GRAB224HR.COMP.LJLit~I~PLAiNAMEOFCRITICAl. MATERIALCRPRIORITYPOLLJJTANT BiAVERAGECCNCEJIIRATICNJ SAMPLElYPEJIIIOFANALYSESC~MAXILJtCatCENIRATICN AJOt'ASSA.NAMEOFCRITICALMATERIALORPRIORITYPOLLUTAJIT 8AYERAGECCttCENTPATICN; SAMPLETYPEJttOFAttALYSES C.JLlLXIttltCCNCENIRAT IONAt4)MASSA.ttAMEOFCRITICALMATERIALCRPRICRITYPOLLUTANT B.AYERAGECONCENIRATION; SJMPLKlYPE;l'FANALYSESC.MILXItllL CONCKNIRAT IONANDMASSA~NAMEOFCRITICALMATERIALORPRIORITYPOLUJTA%'. AVERAGKCONCENTRATIONJ SAPLETYPE'>>OFAttALYSES C"AXIttltCO'CENIRAT IONANDMASSA.ttAJECFCRITICALMATERIALCRPRIORllYPOLLUTANT S~AVERAGECGNCEJITRATION; SAMETYPEJ~OFANALYSESC.~AXIMLttCGNCENIRATION AMJMASSAJA%GFCRITICAL"ATK7IIAL ORPRIORITYPOLLUTAVT

• SodiumHochloride t.ASS014IUNITCODESV'PLKTYPEOFANALYSESLJWITCODEUt!TCOCKLJLNITCODESAMPLETYPELJFANALYSESWITCODEWITCODELJWITCCDESAMPLETYPEOFAJLALYSES WITCODEWITCODELJ~.~LJWITCODESAJYPLETYPEJJOFANALYSESLJLltITCODEWITCODELJ~~~LJWITCCDESAMPLETYPEOFANALYSES~.LJJ~~L>J~~~*~0,~23~1~273.~~V2~B.AVEJLAGEcatcENTRATIGN; SAMPLETYPE;I"GFANALYSESc.AXI~cONCEJILATlal AJ4JMASSA.%PEOFCRITICALMATERIALORPRIORllYPOLLUTANT 3.AVERAGECONCKNIRATION; SJMPLKlYPE:JtOFANALYSESC>>,MAXlttP.

CCttCENIRATICN AttDMASSWITCODE'AMPLETYPEOFANALYSESUNITCODEWITCODELJLhllTCODESA'LPLETYPEJJOFAttALYSES LLLJWITCODEWITCODEA.:>>AMKOFCRITICALi"ATERIAL ORPRICRITYPOLLPJTJVLT BiAvEPAGEcatcENIRATIGNJ SA>>LPLETYPE;>>It0FANALYsEsc.MAXIMJJLcatcENTRATION AJ4)MAssSJVLPLETYPEOFAtLALYSES LJUNITCODEWITCODELJ*Discharged astotalresidualchlorine**Basis:ADDITIONAL PAGESOFTHISITEIL7AREATTAOEDFORTteRESTOFTHECRITICALCIYESMATERIALS Ata/CRPRICRITYPLXLUTANTS RECUIREDTOBKREPORTED. QXNO1993actualdatasubmitted onDMRs.Averageconcentration basedondatafromMaytoDecember. 39 I'S!,'"'S"R"rdzPL:TEu7raistor.Isrobeusedbvbothsurfaceandgroundworer aoplicants torecordlnformorlon onanvmichigancrltlcaimaterial, E.p.A.Z-"C<<IPcflu-onr. =.nazarccus svas-ance In<<nice-'sTool!car!on requirescata-Obeprovided. his<<ou!CinCluceanvchemico!.:-csancee"icnlgancritico!"arer.ais egisreri,ab)eI'/).TheE.p.A.p~icrltvpolluran. 'sr!noITable'/).-rTablesA-<<<<nion!ISTS<<rgan!CTOXICPOllutanTS, OtherTOXICuqllutantS, "nVentlcnal andNcnqqnVenricnal POI+tantS OndNOZardcuS S.bsrances. ITmz7:.ITIC/I."ATEPIALS,=RIORITYQLLUTANTS, AND/ORHAZARDOUS SUBSTANCES INTHEOISCHAPGE vaterialI,2.3...8Listrhenoneotthechemicalsubstance Icritlcal

material, priorlrvpollutant, ornazardous substance) fromTablesIV,VonoIIA-VAosrequiredIntnebox<<nlcnyoucheckedInA.l-3.abbve.EntereachchemiCOIsubstanCe'S parameter numberoslistedInTablesIV,.VandIIA-VAitprovided.

B.orovldetheaverageconcentration ofthechemicalsubstance namedInA.Indicatethesampletypeusedandthenumberofanalysesmodetoprovidetheconcentration dataforthechemicalsubstance namedinA.Providethemaximumconcentration anddetermine themassloadingofthechemicalsubstance namedInA.NOTES:I.Ifonlyoneanalysiswasmodeforachemicalsubstance thenrecordthatdataosamaximumvalue.IfmorethanoneanalysishasbeenmaceforachemicalsubsTance Thenprovideanaveragevalueotthoseanalysesandthemaximumvalue.2.ThisSectionII,Item7,DataSheetprovidesspaceforrecording catafor8chemicalsubstances IMoterlals). Addlticnal SbOCe<OrreCOrqlng OfdatatOrmererhan8MarerlalS CanbemadebymakingCOPleSOfthlSItem.7DataSheetosneeded.Itisalsoimporront touseaseparateserofDataSheeTsforeachapplicable reporting requirement aslistedInA.I-3.andforeachoutfall.3.Refertotheleftmarginforthecodenumberrepresenting theSamPletypeusedandtheappropriate unitcodes.40 ANALYTICAL REPORTCookNuclearProj:WasteWaterAnalysisSubm:Jan26SamplesSubmittal Number:29609-3Location: Contact:RayV.BuhlPhone:(616)942-9600Outfall001Outfall002Circ.IntakeDetection UnitsLimitWWESSampleNo:783717837278373BOD,(5-Day)Sampledby:DateSampled:TimeSampled:DateReceived: TimeReceived: <1.001/26/9400:0001/27/9413:30<1.001/26/94000001/27/9413:30<1.001/26/94000001/27/9413:301.0mg/1:>')~)')(II('ll'6rlr)rlIIIIIHIale'h5alt8I'.I()lkrl5874.(II'rlll(lRrlpl(IH.11III)5880874.8I8/I)420I)00I'rl'r0I~2III8 llll/lIIn('(I'BI i6.S'(7nI('( 1~emu@(('>Ilvallll STATEMENT OFDATAQUALIFICATIONS CLIENT:CookNuclearSUBMITTAL '9609-3Allanalyseshavebeenvalidated andcomplywithourQualityControlProgram.Noqualifications required. Thefollowing analyseshavebeenqualified forthereasonscited.KEYl.2.3.4.5.6.7.8.9.10.Sampleintegrity suspectuponreceipt(explain). Analysisperformed beyondEPAestablished maximumallowable holdingtime.Detection limitelevatedduetomatrixinterferences. Laboratory controlsamplevalueoutsideestablished acceptable limits.Matrixspikesamplevalueoutsideestablished acceptable limits.Duplicate analysisvalueoutsideestablished acceptable limits.Surrogate/internal standardrecoveries outsideestablished acceptable limits.Datapointsuspectduetopotential laboratory contamination (explain). Coeluteswiththecompoundcited.Resultmayrepresent acombination ofbothcompounds. Other(explain). Note:ThisdocumentisincludedaspartoftheAnalytical Reportfortheabovereferenced andshouldbe.retainedasapermanent recordthereof.)'>')>(llenwond IllllsParkwaySI'.POBox874.(Iran(lRnpl(ls.Xtl49588-0874. 8IG/842-8800 !'ax0-I2-8In! tl1!'En)e(no!E-'.')n(n(7 l,iatnmi( (nmp,vnXl1II(XlslI'KI(IANALYTICAL REPORTCookNuclearProj:WasteWaterAnalysisSubm:JanuarySamples29609-4RayV.Buhl(616)942-9600Submittal Number:Location: Contact:Phone:OutfallOutfall001-Circ002-CircWaterDschWaterDschCircWaterDetection UnitsIntakeLimitWWESSampleNo:7853278533'8534Surfactants, MBASColiform, FecalColor(Apparent) Sampledby:DateSampled:TimeSampled:DateReceived: TimeReceived: (0.0252<5V.Shah01/26/9400'0001/28/940000<0.025<1<5V.Shah01/26/94000001/28/940000(0.025<5V.Shah01/28/9400000.02515mg/1cl/100ml6pH5:)55(II(.'nivn()(l II!IlsPnrkivnySE.POBox874.(I('nn(lRnpl(ls.III49588>>0874. 616/902-9()00 I'nx9I'-6I!)9 lHVErt,>ateelVn >f-SneBCett.s>>>>>>>>i Ic:rt>>>p'>>>t STATEMENT OFDATAQUALIFICATIONS

4XAl.'>'I'(l5I.,'bI'.R'tIt

t!:CLIENT:CookNuclearSUBMITTALr 29609MAllanalyseshavebeenvalidated andcomplywithourQualityControlProgram.Noqualifications required.

Thefollowing analyseshavebeenqualiTied forIhereasonscited.SampleNo.(s):Explanation: Parameter: KEYl.2.3.4.5.6.7.8.9.10.Sampleintegrity suspectuponreceipt(explain). Analysisperformed beyondEPAestablished maximumallowable holdingtime.Detection limitelevatedduetomatrixinterferences. Laboratory controlsamplevalueoutsideestablished acceptable limits.Matrixspikesamplevalueoutsideestablished acceptable limits.Duplicate analysisvalueoutsideestablished acceptable limits.Surrogate/internal standardrecoveries outsideestablished acceptable limits.Datapointsuspectduetopotential laboratory contamination (explain). Coeluteswiththecompoundcited.Resultmayrepresent acombination ofbothcompounds. Other(explain). Note:ThisdocumentisincludedaspartoftheAnalytical Reportfortheabovereferenced andshouldberetainedasapermanent recordthereof.5555(s'tenwood ttlllsParkwaySE.POBox874.(>randRapids,Mt49588-0874. 616/942-9600 t'ax!)4'>-t!4!)s GENERALCHElVIISTRY RESULTSClientSamieID:OUTFALL002LALBatchIDls):126imDateCollected: 01-24-94DateReceived: 01-26-94Matrix:waterPO¹69095-040-3N Constituent MetoaResultReporting Detection LimitDateQuelifierfs) DataAnalzedLALSemIeIDFluoride, inmILBromide.inmILNitrite-Nitrate-Nitrogen, inmILSulfate,inmILTotalCanide,inmILTotalPhenolics, inmILSulfide,inmIL340.2300.0353.2300.0335.2420.1376.1<0.15<0.0500.3423<0.020<0.15<1.00.150.0500.0500.0590.0200.151.003-02-94L1131-901-28-94L1131-1702-11-94L1131-2201-27-94L1131-1701-27-94L1131-2602-08-94L1131-3201-27-94L1131-12Comments: GENERALCHEIVllSTRY RfSULTSClientSampleID:OUTFALL002-CWDISCHLALBatchID(s):126im,127imDateCollected: 01-26-94DateReceived: 01-27-94Matrix:waterPO¹69095-040-3N Constituent TotalPhosphorus, inmILAmmonia-Nitrogen, inmILTotalSuspended Solids,inmILTotalOrganicCarbon,inmILChemicalOxygenDemand,inmILTotalKjeldahlNitrogen, inmILMethod365.2350.1160.2415.2410.2351.2Result<0.030<0.050<122.0<18<0.10Reporting Detection Limit0.0300.050121.0180.10DataQualifier(s) DateAnalzed02-08-9402-01-9402-02-9402-16-9401-28-9403-03-94LALSamleIDL1142.6L1142.6L1142-10L1142-2L1142-2L1142-6Comments: GENERALCHEMISTRY RESULTSClientSamleID:OUTFALL002LALBatchID(s):128imDateCollected: 01-27-94DateReceived: 01-28-94Matrix:waterP0469095-040-3N ColorConstituent Sultite,inmg/LMetod110.3377.1Result(5.0(1.0Reporting DataDetection LimitQuallflerls) 5.01.0DateAnalzed01-28-9401-29-94LALSamleIDL1151-2L1151-2Comments: METALSRESULTSClientSamIeID:OUTFALL002LALBatch)DIs): 126imDateCollected: 01-24-94DateReceived: 01-26-94Matrix:waterPO¹69095-040-3N Constituents MethodConcentration ImIL)Reporting Detection Limit(mIL)DataQualifierls) DateAnalsedLALSemleIDAluminumAntimonArsenicBariumBerIliumBoronCadmiumChromiumCobaltCoerIronLeadManesiumMananeseMercurMolbdenumNickelPhoshorusSeleniumSilverStrontium ThalliumTinTitaniumUraniumVanadiumZinc601060107060601060106010601060106010601060107421601060107470601060106010774060106010784160106010602060106010<0.20<0.060<0.010<0.20<0.005<0.20<0.005<0.010<0.050<0.025<0.10<0.00312<0.015<0.0002<0.067<0.040<0.050<0.005<0.0100.13<0.010<0.20<0.10<0.001<0.050<0.0200.200.0600.0100.200.0050.200.0050.0100.0500.0250.100.0035.00.0150.00020.0670.0400.0500.0050.0100.100.0100.200.100.0010.0500.02002-22-94L1131-9502-22-94L1131-9502-20-94L1131-9502-22-94L1131-9502-22-94L1131-9502-22-94L1131-9502-22-94L1131-9502-22-94L1131-9502-22-94L1131-9502-22-94L1131-9502-22-94L1131-9502-23-94L1131-9502-22-94L1131-9502-22-94L1131-9502-09-94L1131-9502-22-94L1131-9502-22-94L1131-9502-22-94L1131-9502-25-94L1131-9502-22-94L1131-9502-22-94L1131-9502-28-94L1131-9502-22-94L1131-9502-22-94L1131-9503-07-94L1131-9502-22-94L1131-9502-22-94L1131-95Comments: VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260Page1of2linamleID:OUTFALL00DII:4-AN-4Matrix:WATERAnalticalBatch¹:020394-8260-J-2 QCBatchID:020394-8260 LALamleID:L1131-44DRiv2-AN-4DateAnalzed:03-FEB-94 DilutionFactor:1RRTEREOVERYQCLimits12-Dichloroethene-d4 Tn4-Bromofluorobenzene 99149776-11486-115Chloromethane VinIChlorideBrmmehnhrhnTrichlorofluoro methaneAcone11-DiIrhnnDiIfiMethleneChloridetrans-12-Dichloroe beneVinIA11-DiIrhn2-Butanone cis-12-Dichloroethene hlrfrm111-rihlrhCarbonTetrachloride 12-Dichloroe han8nnTrihirhn12-Dichloro roanBromodichlorome haneConcentration L<5<5<10<5<5<10<5<5<5<5<5Reporting Detection Limit1010DhlIVinr4Mhl--ennncis-13-Dichloro roeneToluenern-1-Dihlrrn2-Hxnn112-Trichloroethane Tetrachloroethene PCE<5<5<5<5LOCKHEEDANALYTICAL SERVICES .VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260Page2of2ClientSamleID:OUTFALL002LALSamleID:L1131-44Constituent Dibromochlo romethanehlrnnEhInnm-Xlenao-XlenernBrmfrm1122-Tetrachloroe hane13-Dichlorobenzene 14-Dihlrnn12-Dichlorobenzene Concentration /L<5<5<5<5<5<5Reporting Detection Limit/LDataQualifier sZCGLOCKHEEDAIVALYTICAL SERVICES VOL'ATILE ORGANICANALYSISRESULTSFORANALYSESUSINGIVIETHOD8260TENTATIVELY IDENTIFIED COMPOUNDS ClientSampleID:OUTFALL002DateReceived: 264AN-94Matrix:WATERAnalytical Batch:020394-8260-J-2 LALSampleID:L1131~DateAnalyzed: 03-FEB-94 DilutionFactor:1QCBatchID:020394-8260 Tentatively Identified CompoundNOCOMPOUNDS IDENTIFIED Estimated Concentration Iyg/L)Retention Time(minutes) DataQualifier(s) LCGLOCKHEEDAIVALYTICALSERVICES

SEMIVOLATILE ORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGViETIIOD827pClienSamleID:OUTFALL02DateCollected: 24-JAN-94'atrix: WATERAnliIBh4'.24-7-AQCBatchID:8270-SEMIVOLATILE 4825LALSamleID:L1131-57DateReceived: 26-JAN-94 DilutionFactor:1DExrd31-AN-4DateAnalzed:03-FEB-94 PeIof2SRRGATEREOVERY0Limi2-FluorohenolPhenol-d, Nitrobenzene-d, 2-Fluorobi henI24-TriromhnIp-Terphenyl-d 27206758484121-10010-9435-11443-11633-141Phenolbis2-Chloroeth IeherhlrhnI1-Dihlrnzn14-Dichlorobenzene BenzIalcohol1-Dihlrnzn2-MhlhnIbis2-Chloroiso roIether4-MethIhenolN-Nir-Di-n-rIminHexhlrhaneNitrobenzene Isohorone-NirhnI4-DimhIhBenzoicacidbis2-Chloroethox mehane4-Dihlrhn14-TrihlrnnNahthalene4-Chloroaniline Hxrin4-hlr--mhlhnl2-MethInahthaleneHexachloroc cloentadiene Concentration L<10<10<10<10<10<10<10<10<50<10<10<10<10<10Reporting Detection Limit10101010101010105p1010101010DLOCKHEEDANALYTICAL SERVICES 0 SEMIVOLATILE ORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270ClientSamleID:OUTFALL002LALSamleID:L1131-57Pae2of2Constituent 4-TrihlrhenI4-TrihlrhenI2-Chlorona hthalene2-Nitroaniline DimhIhhIAnhhln26-Dinitrotoluene 3-Niroaniline Anhhen4-DinirhnI4-NitrohenolDibenzofuran 4-DinirInDihlhhl4-ChlorohenI-henletherFluorene.4-Nirnilin4-Dinir--mhIhnIN-Nitrosodi henlamine4-BromohenI-henletherHxhlrnznPnhlrhnPhenanthrene Anthracene Concentration IIL)<10<25<10<25<25<10<10<10<2<2<10<10<10<10Reporting Detection LimitIIL)102510252510101010101010DataQualifierls) Di-n-IhIFluoranthene PreneBInIh'-DihlrnBenzoaanthracnChrsenei2-hIhIDi-n-IhhIBenzobfluoranthene Benzokfluoranthene <10<10<10<10<10<10101010101010BnrnInn1rnDibenzahanhraceneBenzohi)elene<10<101010LOCKHEEDAIVALYTICAL SERVICES SEMI-VOLATILE ORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8270TENTATIVELY IDENTIFIED COMPOUNDS ClientSampleID:OUTFALL002DateReceived: 26-JAN-94 Matrix:WATERAnalytical Batch:020394-8270-A LALSampleID:L1131-57DateAnalyzed: 03-FEB-94 DilutionFactor:1QCBatchID:8270SEMIVOLATILE 4825Tentatively Identified CompoundUNKNOWNKETONEEstimated Concentration Iyg/L)9.3Retention TlrneIminutes) 4.80DataQualifierls) CLOCKHEEDAIVALYTICAL SERVICES OILANDGREASEEXTRACTABLES ANALYSISRESULTSBYFT/IRUSINGMETHOD413.2ClientSamIeID:OUTFALL002DII:4-AN-4DRiv:-AN-4Matrix:WATERAnalticalBatch¹:020494-413.2 LALSamleID:L1131-77DAnl:7FB-4DilinFr:1DateExracted:02-FEB-94 QCBatchID:020294-413.2 Constituent OilandGreaseConcentration mLReporting Detection LimitmDataQualifier(s) LOCKHEEDAIVALYTICALSERVICES PESTICIDE ANALYSESRESULTSBYGC/ECDUSINGMETHOD8080lienmleID:TFALL-2DaII:4-AN-4DateExtracted: 31-JAN-94 Matrix:WATERAnalytical Batch¹:013194-8080-E-4 LALSamIID:L111-7DRiv:2-JAN-4DateAnalzed:01-FEB-94 DilutionFactor:1QCGroupID:8080PEST/PCBS 4822TCMXDCBRRATEREVERY6345"QCLimits60-15060-150A-BHB-BHCG-BHCD-BHConstituent Concentration L<0.05<0.05Reporting Detection Limit0.050.05DataQualifier(s) HEPTAHLRALDRINHEPTACHLOR EPOXIDEHRDANENDLFANIA-CHLORDANE 44'-DDE44'-DDTDIELDRINENDRINENDOSULFAN II44'-DDDENDRINALDEHYDENDOSULFAN SULFATEMETHOXYCHLORTXAPHENPB11PCB-1221PCB-1232PB14PB-1PCB-1254PCB-1260TECHNICAL CHLORDANE TCMX-tetra-chloro-meta-xylene DCB-Deca-chloro-biphenyl <0.05<0.05<0.05<0.1<0.1<0.1<0.1<0.5<20.00.050.050.10.10.10.10.5l44LOCKHEEDANALYTICAL SERVICES RADDATAREPORT(ra01)IndianaHichiganPoverCo.~Bridgman,HI .OrganicandInorganic Contaminants (ProjectCOOK-JENI) Hatrixt'listerClientSampleID:OUTFALL002DateCollected; 24-JAN-94 LALSar@leID:L113+86DateReceivedt 26.JAN-94 LoginN+4ertL1131s"""'"" ><"'Anal~ed 'Babb'"""<" ~"""'-'-': "l'"-'"""""-"":<':-'-'~~~Act Mty@"O'For'~~IB)IL~~".~: -'a'tagual'-'Infts-"'ross AlphaGrossBeta23FEB-94GRALP/BETALAL~0060475623-FEB94GRALP/BETALAL006047560.331.9O.M1.31.72.2pCi/LpCI/LPage7

RADDATAREPORT(ra01)IndianaHIchiganPcwerCo.eBridyaan,HI Organicandinorganic Contaeinanta (ProjectCOXJENl)Hatrlx:llaterClientSeep(aID:QITFALL002DateCollected: 24.JAN-94 LALSanctalD:L1131-90DateReceived: 26-JAN-94 LoglnKwhr:L1131QP~Coni't Ra-226Ra.22822.FEB.94 RA.226LAL.0073477123-FEB.94 RA-228LAL.007455030.0160.520.0560.120.340.55pCI/LpCI/LPage11 PHMeterCPC9JomCdateduePHAnalysis(LAB.079) Outfall002SampleSampleTimeSamplePSampleDateCDMEnteredby05.3.56)SampleC/ph(priortocorrection) 7)NHzpHcorrection 5.3.6SampleSampleTimeSample$jSampleDateCDMEnteredby8))ampleresultsC/pH"(aftert.~gNHCorrection) 3P2e3acb)c-P'4~(6/7>ooU2/L-3oo5.3.56)SampleC/ph(priortocorrection) 7)NH3pHcorrection 5.3'8)Sampleresults'C/pH(afterCorrection) 9)IAB.041SpecsVerifiedby:hl/8Rwpeevieee Review/Deee ~&+I~Formpreparedby/DateFormapprovedby/Date12THPLAB.041.25s Revision1 Outfall002Determination ofTotal(Lab170)ChlorineInstrument CPCIj50~""""'"'~s'echnician Sample/Standard SamplegDateTimeCDHEnteredby1)Absorbance 6.112)Results,ppm(~c~3}Dilutions madeCHW4)Results,ppm(III2*83)5)LAB.041SpecsVerifiedby:~)9vperviaor Revi'ev/Date~MR~ parapreparedby/Date/~f+Formapprovedby/Date12THPLAB.041-25)l Revision0

SEEINSTRUCTIONS ONREVERSESIDEGlIFALL'KKRSECTIONIIPERMIT~MIpppg827~003j'j~iVIDISCHARGE LOCATIONSCHEDULEFLOWRATEA~LOCATIONOFDISCHeVIGE CFRECEIVING WATER(IE.GRC(tGHATER CRtisV6EGFSIRFACECsDOYCUDISCHARGE S~Y.(IFtO.CCNTttAIE TOE)DsIFYESeLISTDISCHARGE PERIODSLAKIEMICHIGANXYEStes/IRY~12~01te,/DAY~04~30~SW('s,~NWV,KCIIWIi~6,i0II~066~IJII06~IWASTEWATER ~I~ggE.LUIDAPPLICATION RATECONTACTCOOLING?NONCONTACT COOLING3PROCESSSSANITARYBSTORMWATER FeTYPEQFWASTEHATER DISCHUIGEG~DISCHARGE SOEDIAE(YEARLYAVERAGE)HeDISOIARGE FLOtRATEIOURS/DAY ssv/vsse~12I(tIITCOCETOTALYEARLYDAILYHINI~DAILYHAXItSPI/NITCygneIMGY2MGOGPOI.'MFAXINGDISCH6RGE RlwRATETOBEAUIHOIIZED INPERIIT.*uIITCCDE(NITOXELJJsHAXtt(ttDESIGNDISCNRGEFIOIRATEs*DESIGNClYESAeCOYOUUSEHATERIREATHEHT ACOITIVES TOTREATYOIRDISCH6RZ? (IFMt,ccNTIN(zToITet3)BeNA%FutCTICN, AtOOettCALCCt&KITICN OFlAESEACOITIVESe lTEM2WATERNATREATMENTAODITIVES CeN4%AteADCRESSOFHAIAS'ACTIRERS OFIHESEADDITIVESe INe/WReHR~CAYIN./wK~~u~.'~KIIAWASTDIATER 1YPECOCE~3uM.MLJUNITSCODEIMgrl2UgrtDsEXPECTEDDISQQRGECCtCEHIRATICN CFAIOITIVESe NANAHINit%8AVERAGECODEIHITSHAXINtt(ODEWITSCODEAIXIITIVEHA%ADDITIVENA%ADDITIVENA%LJ;~M;~LJEsDOY(XITREATTIEDISCHARGE IOREteVEADDITIVES? NAF.tAIATIS1HERseVALEFFICIENCY ANODISCHARGE FREQUENCY ADOITIVENtt%ACOITIVENA%ACOITIVENAt%IReeVe.tRS./DAYDAYs/wx.G~ASAHATTAOf%Ãf TOTHISAPPLICATICN PROVIDESPECIFICNWVLIAHCRACUATICTOXICOUF)ICAL DATACRREFERENCE HHICHAREAVAIIAELE ANDINFOR(ATICN CNTHERATEOFDEGRADATICN OFT%RRCIXICTS FCREACHAIOITIVEs

• Theflowforthisoutfallisnotmonitored separately fromOutfalls001and002 r341~'\j1'8)<<'14<<4~<<p~4~1~'<<'14~~15'418~re~g1C5<<l14)scil4O34I\~<<'<<R'l4)1414<<r3)rrtt$3+I18-.rRrat4rSecI,.-)r-4)5ric",lectton.)Own.d1orant)cSt18$<<BI"BTB<<'21'<<~SCci"re<<1et.Br'<<ci.:Tv:)scnarces

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LDOYQUDISOLLRGK AMYOTICTOXICORINJURIQIJS OfPIICALSLBSTANCES NQTLISTEDINTABLESIVPAGEttAteI[ATHIOLAIVAPAf<s~<~[4YES,THENIDEttf[0YTIEOrEMICALSUBSTANCES ANDESTIMATETHEFttlALEFFLUENTCCttCEMIRATICNS ~SLKYIITTHISti&QRMATICN ASANATTAOMEMT TOTHISAPPLICATIONS XNQTAPPL[caBLE/BEL[EYKD ABSENTPRESENT/DATA ISATTAOK)NQTAPPLICABLE APP[.[CABLE/SEE AlTACHED0%.~PL[~QAPPLICABLE/SEE ATTACHEDtOTAPPLICABLE QAPPLICABLE/SEE ATTACHED*Waterdischarged forDe-IcingisthesameasOutfalls001and002.IndianaMichiganPowerrequestspermission tousethescreening dataforOutfall001and002tocharacterize thisdischarge. 37 SEEINSTRUCTIONS ONREVERSESIDESECTIONIINUMBER~MI00058278IIFALLINKR~00ITEM7CRITICALMATERIALS 'OXICPOLLUTANTS AeUSETHISGATASHEETToRECORDINFORMATION ASREDJIREDIN:(CHECKAPPROPRIATE BOXRJRWHICHIMFC@1ATION THISCATASHEETRKPRESF2tTse) oSECTIONII,ITENIEeGROLIGJWATER DISOIARGE INFQJTUlTION (PAGf.59CIX2SECTIONIteITDI6ePRIORITYPOLLUTANTS INSlRPACEWATERDISCHAIY)E (PAGE'7)0X3,B.BElow:CRITIQAL.ATKRIALS (TABLEtv)IMsvRFACEwaTERDts(HARGK (PAGE39)HAZARDOUS SUBSTANCES INDISCHARGE B~LlsTAhYcRITlcALMATERIAL(TABLElvPAGE6)NQTADDREssED IMsEQTIGNIIITKHRPRIQRITYPOLLUTANTS wHICHYCVKNowORHAVEREASONT>BELIEVEToBEPRESENTIMTIEDISCHARGE. SEEREVERSESIDEOFTHISPAGEfORFURRDIRECTtals ~NOTAPPI.ICABLEXAPPLICABLE (SEEBEUJW)*AeNAJefOFCRITICALMATERIALORPRICRITYPOLL%ANTBeAVERAGECCNCEMIRATIONJ SAMPLETYPEJtICFAu0LYSKSc..Axl~caJCKMTRATIQN AJDHassIPJITCODESatlPLETYPEOFANAIYSESWITCODEUNITCODELJillCeJAeJJJJeEOfCRITICALMATERIALORPRIORITYPOLLUTANT B.AVERAGECaJCEMTRATICNJ SA'usafTYPEJstOFANALYSESUNITCQGESJETYPEOFANALYSESUNITSCODE1Mg/I2Ug/I3LBS/DAY4KG/DAYAMPLETYPE1GRAB224HR.COMP.c.HaxtnflcaJCKMIRATtoN eoMassAeJJAHEOFCRITICALJIATERIAL CRPRICRITYPOLLlTANT B,AVERAGECQNQEMTRATIONJ SAPLETYPEJIOFANALYSESCeHAXIJ4PICaCEMIRATICN A%MASSAeW%GFCRITICALHATKRIALORPRIORITYPOLIJJTANT B~AVERAGECOJJQEIITRATlotlJ SWPLETYPEJteOFANALYSESc.Haxtt1plcowcKMIRATtat AJ4)FASSAJAPEQFCRITICALHATERIALCRPRIORITYPOLLUTANT B.AYERAGECCNCDITRATION; SatuufTYPE;JJ0FANALYSEsCePAXIPIJICaJCEMIRATIat tuDMASSAe,'A"ECFCRITICALHATERIALCRPCIIQRITYPOLLUTANT B~AVERAGECCNCEMTRATIONJ SAMPLETYPEJPeOFtuIALYSES C~eVUIINH'CONCEMIRAT IONAJDMASSAeNA%OFCRITICALMATERIALORPRIORllYPOLLUTANT UNITCODElNITCQGELJUNITCODESJVePLKTYPEOFANALYSESWITCODEWITQXELJ~~~LJWITCOOK~LKTYPEOFANALYSESLJWITCODEWITCODEWITCODESAWLETYPEfOFANALYSESLJLJNITCODENITCODELJ~~~LJUNITCODEStuPLETltPEOFANALYSESLJUNITCCDENtiCODELJ~~~LeuJJB.AVERAGECmreetaTICN; SAHPLKTYPE:A'FANALYSESICeMAXIM'aCKMIRAT IONANDIVESlhlITCODESAMPLETYPEJJOFANALYSESLJWITCODEWITCODEa.NAMEOFCRITICALMATERIALoRPRIORITYPOLLUTANT IBeAVERAGECaJCEMIIIATIOMJ SAMPLETYPEJIICFANALYSESCe~AXIHUlCONCENTRATION AJ4JMASSUNITCXESA~TYPEOFA'IALYSES LJlJNITCODENITCQQKLJ*SEENOTEONPAGE37,OUTFALL003.ADDITIONAL PAGESQFTHISITKH7AREATTACHEDFQRT%RESTQFTHECRITICALC3YESMATERIALS atft/CRPRIORITYPOLLUTANTS REQUIREDToBEREPORTED, ElNO SEEINONREVSTRUCTIONS ERSESIDESECTIONIIPERMITTEMAeIDCATIONOFDISCHARGE ~00A~SWs,~NW4,6ECIIWI)~06,IM~0666PAI06III-IDISCHARGE LOCATIONSCHEDULEDeIFYESsLISTDISCHARGE PERIODSNABstIA%DFREcEIvttg HATER(IE~GRGUIDIATER oRt'ai%oFsUIFAcEwACsDOYOUDISCHUIGE SEASONAILY ~(IFNOsCONTItAIE TOE)LAKEMIMO./DAVYESXNOn./DAVFLOWRATEWASTEWATER EeLANAPPLICATION RATEHRs/DAYIN,/wK~.u~.'mEINrIINIHRs~~~WASTEIIATER lYPECCCEL~JLJLJLJLJLJ1CONTACTCOOLING2NONCONTACT COOLING3-PROCESS4SANITARY5STORMWATER ~NITgg1MGY2MGD-3GPDFslYPEOFWASTEHATER DISCHARGE GeDISOIARGE SO%DULE(YEARLYAVBUGE)HXNS/DAY~24essesess~36HeDISOQRGEFLlAIRATE'OTAL YEARLYDAILYMINIONDAILYMAXINII121.54gwipcoDE0~20.333'2leIHEMAXIISNDISCHARGE FUtitRATETOBEAUIHORIZED INPEfBITe1WIT=CODEJ.PAXIPLHDESIGNDISCHARGE FLOIRATEeA>>IXIYOUUSEHATERTREAlHENT ADDITIVES TOTREATYNRDISCHARGE? (IFNOCONTIIAKTOITBI5)WIT2COPEDESIGNYESlTEM2BeNA%FWCTICNsANDCHEMICALCPRSITION OFTAESEAITIITIVESe WATERTREATMENT ADDITIVES CeNAHEAMIACOIESSOFMAIAS'ACTINERS OF7%SEADOITIVESsNAUNITSCODE1MQ/I2UQ/INAD.EXPECTEDDISCHARGE COICENIRATICN OFACOITIVES. NAACOITIVENA%ANITIVENA%ADDITIVENA%E~COYOUTREAT1%DISCHARGE TORENIVEAIXIITIVES? NAUNITSAVERAGECODEYESWITSMAXlttNWITSCODECODEFe~TISlHERBSVALEFFICIENCY AIIDDISCHARGE FREQUENCY? ACOITIVENA%AEOITIVEN6%ACOITIVEtiVELREIOVALHIS./DAYDAYS/WKeLJLJLJGeASANAITACHIENT TOTHISAPPLICATION PROVIDESPECIFIC/%1%.IANCRAOUATICTOXICOUIGICAL DATACRREFERENCE WHIOIAREAVAILABLE ANDINFORUITION CNTHERATEOFDEGRADATICN OFT%PRODUCTSFOREACHAISITIVENA31 SEEINSTRUCTIONS ONREVERSESIDESECTIONIIPERMIT~MI0005827NUMBERIITEMPROCESSSTREAMSCONTRIBUTING TOOUTFALLDISCHARGE POUNDS2GALLONS3CUBICYARDS4TONS5MGY6MGD7GPDI/2IUOr00Ih6/2IAIOcvtOA.IUPEOFPROCESSIXXIIRIBUTIIIG TOTHEDISCHARGE 'ESITHISOUTFALL~DSICCODEBePROCESSSCHEDILE(YEARLYAVERAGE)C~PROCESSWASTEIIATER FLOWRATEBasis:1993actualdatasubmitted onDMRsDePROCESSPRODUCTIOttRATENAC.PROCESSWASTEWATER FLOWRATEDePROCESSPRODUCTION RATEA.tIAtEOFPROCESSCCIIIRIBUTIta TOTHEDISCHARGE THOROUGHTHISOUTFALLAlQSICCODEBePROCESSSQEIXAE(YEARLYAVERAGE)C.PROCESSHLSTEWATER FIDWRATEAeNAEOFPROCESSCONTRIBUTltJG TOTIEDISOIARGE NATHOUGHTHISOUTFALLA'8SICCODEBePROCESS~(YEARLYAVERAGE)TOTALYEARLYDAILYMININGDAlLYMAXI'0LTIITSZTI"ELJsaws/svv~seve/vsaTOTALYEARLYDAILYMININHDAILYtQXWtIears/ssv~seve/aaTOTALYEARLYDAILYMINI@MDAILYMAXI'~OOAU,lBLOWBOW,Ni~4>911IOIIS/DAY ~24y~36236117wlT5LoTIME1HOUR2DAY3WEEK4MONTH5YEARI/IthOWIO0DPROCESSPRODUCTION RATEA.NAMEOFPROCESSCONTRIBUTING TOTHEDISCHARGE NATHAISSICCODEB~PROCESSSCHEIXLE(YEARI.YAVERAGE)C>>PROCESSWASTEWATER FI.OWRATEDePROCESSPRODUCTIOtt RATEAeHASEOFPROCESSCONIRIBUTING TOIIEDISCHARGE THOROUGHTHISOUTFALLA'IDSICCCOENABePROCESSSCHGXLE(YEARLYAVERAGE)CePROCESSHASTEIIATER FLOWRATEDePROCESSPRODUCTION RATEeases/sev ~seve/vasTOTALYEARLYCAILYMINIFYDAILYMAXI'svs/vas TOTALYEARLYDAILYMININIIDAILYM/Nit%PIUNITSCTIMEUIITCODEWITSCTIMEWITS/TIME33 "STRTI2;.'5sSR"<<"DELETING SEGTICNIIITEI-1SIAi<O2"iscrmrecuires'-<crationcntne!ac!<(tv's clscnarce ~coat(en, lscnarceso<ecule,vol.<<eflowrareand<<atertreatrent =":ITFRTHEP"@ITNbuBERI:ITHEBOXATTHETPGF<HISFGfr<.THEpERMIT)AetBERCA%BEFCUNOrtlTHEFRONTPAGEGFYOUREXPIRING"'nls'ssne<<ornct:revlousiv "er-ifecfscil'tv, "enleave.lankencanuper<<~Iibeasslcned. E",-e<-necut!allr(macrlnspaceprovided!creachcagec!sectionII.roreachIndividual clscnarce point3separatesetofformS.Ste'(liedOut.'TE'AIVATIC'I,=.nE'vJLE<I<<)LOWP>TESEnterthelccaticnofdischarge, thissnoulcinclucecuarter-cuarter section,cuartersect)nn,sec(ion.town.andrange.3.u)StnameOfreCelVlnc <<ate<<(ifSurfaCe<<aterd(SCna.oe) G.InCioatewnether!cellltydlscharceS cnaSeaScnalbasis.Ifyes~Iistdlscnarge periods.providethelaneapplication ratesusedorexcectedtobeusedintermsofinc),esperI,our,nourspe<cav,andinchespe<week.F.Indicatethetypeofwastewater topedischarged fromthisoutfall.=afarto~hewastewater tvaecodedivanIntheleftrgin.)<orethanOneCodemaybeapplicaple. ProvidetheaveracenumberofhoursperdayInwnlchthefacllltvdlscnarges treatedwastewater andthetotalnumpe<ofdaysperyearInwnlchhecischarce occurs.urovicecurrent(!romtnelastl2mcnths)orexpectedflowratesasrecuested. Refertounitcodeoivenlntheleftmarginfortheappropriate flowunits.'GY-mllllcncalicnsperyear;'4lO-.Illlcngallonspercay;GPO-gallonspercay.provideherax)~umdischarge flowrate<<nlcnvou<<ant.ohaveauthorized withinthepermit.';0TE:ucrN>Espermitsonly,.heuseofsucha!Iowratewillnotplaceanactuallimitrestrlc.lon ontheflowbutwillbetneflowrateusedtodevelopeffluentlimits.Also,<<nentheI'onthlyOperating ReportsarerevieweCbvCompliance staffitwillhelpthemtodetermine (fanyneworIncreased usesmlchthaveoccurredatthefacility'. !.Providethedesign'lowforthisspeci!leotfaildlscharce (e.g.oatentreatment systemflow,packaoedtreatment systemflow,orsomeotherfinitetreatment systemflow).ITEMi2'xATERTREATF1ENT AOOITIYES 'ndicatewnetner;ischa<ge <streatec<<Ith:cndltloners. Inntb)ters,crnicrcpfocICe. 1'ct,contirue<<oitem3.B.Givename,functlcn, andchemicalccmposltlcn ofacditives used.lvename5ndascasso.'",emanutac';<<"',S)O<-"e<<<<<<!ITS.Sed.'"cicateexpected<<inl<,.<m. averaaesncmaxi~urnClscharce CnCent<<atlons o!tneadditive(s) 'cr-nlsclscnarce. '"cicatewnetner,c treattneolscna<ce tr~vetheace(.Ive(s<"e!creciscnarne of<<astewate<. '<dicate<<her6OVSIef!IcienCV C.eaohaCCit!Ve<rcmthe<<aStewater'Snd theCISCharae !reCuenCy OfeaCnaddltiVetOthe)urface<<atercr..dune<<ate< .'.")E:IIstnerespcnslbll(ty o'.theapplicant tosupplytheproductinformation asrecuested InthisIten4.infer<ration reauested butroSuaaliedmayreSV)tintheapplioatlon heinereturneetotheapplicant 'c<completlcn. SEEINSTRUCTIONS ONREVERSESIDESECTIONIIt4UMBER~M20005827PERMIT~00ATEM4GROUNDWATER DISCHARGE INFORMATION ISTHEDISCHARGE FRCMTHISOUTFALLDIRECjEDToTHEGRIXÃIDORGROUNDtATERS7 I!FtoCCtttlt2UE ToITEM))BaWASAHYDROGEOLOGICAL STUDYCRITSEQUIVALENT BEENPERRRKDORlsTHERESIFFICIENT cURRENTHYDROGEQCQGIcaL ItFQIY4ATICN AYAllaBLE AsREQUIREDBYTl6'wATERREsoURcEs CotMISSIOtt PARTZZGRQViDWATER RULESOFAUIUSTltt>lcMR.>23.ZZ()7 (PAGEGQ)FORTHISEXISTMORPROPOSEDDISCHARGEZ IFYESATTACHACOPYOF1HEREPCRTeCIAREYQUREQUESTlt6 attEXEt'PTIC;< FRCMSUBMITTING AHYDROGEOLOG ICALREPORTUttDERRIXER323,@It(l0)(PAGELa)QRFRQMGRoutcwatER MQNITCRING IIEQUpEMENts UtlDERRULER.Z5IZ4UI(5)(PAGEII/)OFTHEPARTZZRULES>>IFYESATTACHDOCUMENTS ANDEXPI/Utattott TODEISNSTRAIE THATYORDISCHARGE WQLADQUALIFYFORANEXEPPION.DIAREYQUREQUEsTING 4vaRIattcE FRQMRULE32312205(PAGEQ(tQNDEGRADATIctt) 0FTHEwATERREsculcEs cotttlsstetPARTZZGRolfcwATER RIAEBTIFYEsiATTAcHsUcHDQIXPtENTS ASNECESSARY TODEMOttsTRAIE WcNEEDFCRAVARIANCElttTERMSCFTtecRITERIAsPEclFIED INRILE>Z3IZZ10(PAGEtl7)0F1HEPARTZZRULEs~NANANAYES"ESQYESYESNONON)EsI,ISTALLCHEttICAL$%stattCES WHICHAREINMICHIGANSCRITICALMATERIALS REGISlERTAB!EIVlPAGED)AND/QRViseEPAsPRICRITYPQILUTANT LlsTTABLEv(PAGE7)0RANYGTHERsUBsTANcEs wlcHAREoRHavBEcctEINJURIOUS toTIEDESIGNATED USEsOFTIEcArwowtER oRTOTHEPUILICHEALTHTHATAREDISCH4RGED QREXPECTEDToBEDISCHARGED ToTHEGROUIDWATERAY 1HISFACILITY, ESTIMATETHEFINALEFFLUENI'ONCENIRATION attDRECORDAILDATAINITEM/OFSECTta<<tINTHISBCOasr.TIEAPPLICANT MAYBEREQUIREDToDOADDITIONAL WASTEANALYSES. QNQTAPPLICABLE/BELIEVED ABSENTNAPRESENTiDATAPROVIDEDINITEM7ITEM5EXPECTEDWASTEWATER CHARAC"TERISTICSUNiTSCODE1Mg/I2Ug/I3COUNTS/100ml4S.U.5'F6LBS/DAYAIDISCHARGE CHARACTER ISTICSPtSNIANITROGEN(AsN)TOTALSUSPENDED SOLIDStotaLptY)SFHQRUS (asp)TOTALRESIDUALCtLCRINEDISSOLVEDOXYGENMIN~.LJFECALCOLIFORMBACTERIATEKERATlRE (SIJY4ER) TEtfiERATURE (WINTER)BO05(FIVEDAYBIOCHEMICAL OXYGENDB'AND)cQD(CHEMICAL QXYGEttDerVD)TOC(TOTALORGANICCARBON)CottCENTRAT ICttBIOTHERWASTEWATER CHARAC'STICSMax4~LJutttSCODE4ANALYSESSA~TYPECODEu1ul~3~5~5SAMPLEZXBF1GRAB224HOURCOMPOSITC 0ILBGREasELJLJ~LJLJ~LJLJ~LJ'J~LJSEEATTACHEDSHEETSFORANALYSISDATAREQUIREDINFOIY4ATICN FQRSURFACEWATERDISCHARGEss

• Basis:1993actualdatasubmitted onDMRS

'-.--Sc.res'~'c~atlcn cntnecrccess3-"easniceocrtclouse-"-~'.3tlscbar"8 ..TE=E-=='-""".UBERINTPEBCXAT'-'="f-IE.CR4.--=cEo!IIT'"trABEOCI'IBECCUI'0C;ITPEfRQNTOSGECFYCUIIEXPIRING--"S'S3"eWCr-3-:reVIC.S< ~38~"-~r'~"IlitV. -renleaVe"landand3numberrillbeOSSICnec. E";er;.-Is ~~-.-er'"3"ace-.Cvicec':esc-.338crEecticn<I.=OreccnIncivIduai ciscnarce point3seoara.esetcfITE'Alr'ngfotj~~'r~rE"-er-8"a~"'",eOrOCeSS<<nlcnConrlautea -O,.hiSOISCnarae. ~ISOCrOVide3"eOroberSICCOCencica-8--evearlvsveracecrccessscrecuie'""ourscercavanodays-cer-veer. ?rovldetneorOCCSSwaStewater ficwrateinformatiOn aSrequeSteo basedonyourlast12monthsofooerations. Referto.nitcodegivenintheleftmaroinfortneaooropriate flowunits.=.Ocessorcductlon Rate-.ertain"armis'Imltatlcns mavbebasedcnorcductlcn rates.heoroduct'Icn ratesusedtotate~>.8cermltI'~I~Ssailberecresen-ec bv3reasonable measureofsctua<crocuct:noftbefeellltv,suchastle,irr'nn>retiousiear,.8rCOtnlV3'eraCe~ne.Ines~C8SVICOSiV8yearS~CrI;ner8sonableassureasstated'3scoiicble'E.E.P.A. Catecorlcal r'essnoreou>a-,lens. =cr~ewSurCeSornewOIscnarcers, actualcrcouction snailbeestimated vSIngorojectec =rcduCticn. uc.I1rates1~"8er<s3nounitsusedintheabolicaoleu5~~.A~ateoolicalrulesandreculations for SEEINSTRUCTIONS ONREVERSESIDE(NFNl.IVERSECTiawIIPERMIT~MIpppg827NUMBER~00AITEM6PRIORITYPOLLUTANTS ANDADDITIONAL INFORMATION FORSURFACEWATERDISCHARGE ONLYTHEFOLLOWING REQUESTED lt>>FC{V{ATIGlt ~e">0eAXRESSED~A>>eNFACE'ATER DISCHARGERS ~RHEIt>>EWUSEDISCHARGERS ~s>>PROVIDE~eECTEDVALUESFORTtECUAVflTATIVE ANDQUALITATIVE INFORMATIGNREQUESTFD BELCH>>A>>ISTHISFACILITYAPRltARYItt{XSTF(. (REFERTOTABLEIAPAGE+{IFNO>>GOTOE)(IFVES>>GOTOB)B~IhDICATETYPEGFPRIMARYltOUSTRVASLISTEDINTABLEIAPAGE<>~(CQttftttUE WITHC.)C.DOESTHISOUTFALLDISQ{ARGE CCtffAINAr{YPROCESSWASTB{ATER. (IFNO>>GOTOE)(IFVES>>GOTOD)D>>INDICATEWHICHGC/r'SFRACTIQr{S>>MUST BETESTEDFOR~(REFERTOTABLEIAPA">>E~tIIQIEIFCREACHGC/MSFRACTIONCHECKED>>EACH SPECIFICORGANICTOXICPOLLUTANT WllHINEAGHFRAGTINtQADIBEAt{ALYEMFGR(sEETABLEIIAPAGEtt2.It(ADDITION, ALLPRIMARYIt>>DUSTRV APPLICANTS WITHAPROCESSWASTEWATER DISCHARGE ~PROVIDEQUANTITATIVE DATAFOREACHTOXICPOLLUTANT IttTABLEIIIAPAGE.RECORDALLDATAOMFORMSPROVIDED(ITEM7)INTHISBOOKLET.(CONTINUE WITHEKBELCH)VEStOSTMEILECPWRXYEStOV{XATILEBASE/NEUTRAL ACIDPESTICIDE

• EDIF~SLIPPAGEWATERDISCHARGE APPLICANT (PRIMARYORSECCr{DARY it{DUSTRY)>>

REGARDLESS OFTHElYPEOFDISCHARGE>> KIKWSCRt>>ASREASONTOBELIEVETHATAttfPOLLVfAMT LISTEDINTABLEIIAANDIVAPAGES~ISDISCHARGED FRCMANYOUTFALL>>THEQUANTITATIVE DATABEPROVIDEDRECORDALLDATAONFORMSPROVIDED(ITS>>t7)INTHISBOOKLET>>>>tOTAPPLICABLE/BELIEVED ABSENTOXPRESENT/DATA ISATTACHEDF~IFANYSURFACEWATERDISCHARGE APPLICANT (PRIMARYORSECONDARY INDUSTRY)>> REGARDLESS OFTYPEOFDISCSUIGE>> KIOWSORHASREASONTOBELIEVEANYPOLLUTANTS LISTEDIttTABLEVAPAGE{I>>>>AREDISCHARGED FRQ{ANYCUTFALLTHEAPPLICAVT VII'ESCRIBE REASONSFORTHEPOLLUTANT BEINGPRESEttfAt{DPROVIDEANYAVAILABLE QUANTITATIVE DATA>>RECORDAILDATAGNFGIV{SPROVIDED(ITEM7)INTHISBOOK!ET>>XtOTAPPLICABLE/BELIEVED ABSENTPRESEMT/DATA ISATTAQ{EDG.AILS{IIFACEWATERDISCHARGE APPLICANTS (PRIMARYAttDSECONDARY INDUSTRIES) E)CRMANIA-ACTNES 2.4i)-TRIQKDRGPHEIOXV ACEftgACID(2.4i5-T)l-I),.5-)AtO4>>5TRICHLGROPHEIOXV PROPANOIC ACtD(SILVEX2>>4>>5>>TP)'Z.4.>IRIQ{LGRGPHEtOXV) ETHYL2,2-DICHLGRGPRGPIGMATE (ERBGMt;0,4NTRICHOROPHE{OL (TCP)>>ORHEXAQl.OROPHENE (HCP)t(AILDATAFORTHEABOVEt>>USTBEGEhERATED USINGSTANDARDAt{ALYTICAL CALIBRATION PROCHXRES) ORKIOWSCRHASREASONTOBELIEVETHATTCDDISCRMAYBEPRESENTINTHEIRDISCHARGE>> ~REPORT9IALITATIVE DATA,GEIERATED WHICttUSEDASCREENltO PROCHXREtOTCALIBRATED WITHAVALYTICAL STAt{DARDS>> FGR2.>>>/8>>TETRACHLORODIBENZO PDIOXIN(TCDD)>>RECGRDALLDATAONFORMSPROVIDED(ITEM))IMTHISBOOKLET>>J~IFTHESURFACEWATERDISCHARGE APPLICAMf KtOWSCRHASREASONTOBELIEVElHATBIOLOGICAI TOXtCITYTESTSwHIEvADEINTHELASTTWEE(5)YEARSOMANYOFTHEAPPLtCArlT SDISCHARGES ORCNARECEIVINS WATERINREIATINtTOADISCHARGE. PROVIDETHISINFORMATION ASAVA1TAQI{EMT TOTHISAPPLICATION>> KIFACONTRACTLABORATORY ORCCrtSULTING FIRMPERFCRMED Ath'FTHEAIN{YSESREQUIREDBYTHISAPPLICATION, PROVIDETHENAMEANDADDRESSOFEACHLABORATCRY ORFIRMANDTHEANALYSESPERP'"HtASAVATTACHMENT OFTHISAPPI.ICATtON>> 'L.DOYOUDISCHARGE ANOTHERTOXICORINJ(PIOUS CHEMICALS{8STANCES tOTLISTEDINTABLESIVPAGE(IAl>>DIIATHROU4lVAPAGESV~A+>>cYES>>THENIDENTICHEMICALSUBSTANCES A'OESTIMATETHEFtt{ALEFFLUEttf CCtKENTRATICr{S. SUIT{ITTHISIhFORMATION ASAVATTAQteENT TOTHISAPPLICATIGN>> NOTAPPLICABLE/BELIEVED ABSENTPRESH{f/DATA tSATfACHEDNOTAPPLICABLE APPLICABLE/SEr AlTACHEDNOTAPPLICABLE XAPPLICABLE/SEE AlTACHEDXtOTAPPLICABLE APPLICABLE/SEE ATTACHED*Pesticide dataisnotrequired; however,itisprovided. 37 IIISTROCTIONS .OoCCfJPLETI'/3 SECTIC!IIIITEMS4ANOS.hisformreculresInforration onaspeci!iccut!alllscnarglng toeither,he grouncwaters orThesurfacewaTBrs.rENTERTHEPozz(TNLSIBERINTHEBOXATTHETWCFTHISFCRM.THEPEIB(ITNONBERCANBEFOUNDOiTHEFRONTPAGEOFYCOREXPIR(tfg CERuli~:.',~5(S(SarewOrnOtpreV(cuS(V permitted faCII(ty,ThenleaVeblankandanumberWillbeBSSICred. nter-Bcu~fa(IumberInThespaceprovidedfcrebenpaceofSectionII.Foreacnindividual dlscharce pointaseparateset"'n-T!Bn!','"rms(Items'nc)must=efilledout.ITE)l4SBDJ;.WA==DISCHARGE INFCiJAT(CN(00N"TiNCLCCEDEEPWFL(.I"JECTIONINFC"NATION I'ITHISITEvl)A.-D.heapplicant shalladdresseachofthesepartslftheclscnarce fromthisoutfallistotheoroundwater. ITEM5<ISTI"GCREXPCTED~FORANEWO(SCHARGE) <<ASTFWATER CHAoACTERISTICS CFSRv'4)WATER ORSI'RFACEWATEoDISCHARGE (DO"OT'NCLUDE hcLLINJ3ICNINRNAI'IINHrVITheapplicant shallreportavailable discharge data(realdataAorexistingdischarge orexpecteddataforaprcposedd(scharge) fcrtheparameters aslisted.Theseparameters shallbeaddressed foreitherasurtace~aterdischarge orasappropriate foragroundwater dlscrarge. Forassistance indetermlnlno abproorlate par~tersaorcundwater dlscharce applicant maycontactthe<<Arouncwater Dual(tvolvlslcn, permitssectionortneappropriate Grouncwater Dualityoiv(s(on's Districtoffice.Theapplicant shallreportthesama(eTypecodebestdescribing eachreportedpieceofdata.Seecodingontheleftmarginofthisform.IfThisoutfal(lsasurfacewaterciscnarce. tneapplicant mustrepor-ouantitative dataforeachparameter Identified bvanasterisk. ,heappicantmay,however,recuestThat-nereportnco,cata<<orcneormoreo~hesereouiredoarai.eters be<<aivec.Suchrecuestmustbesupported byacecuato<<atlcnale. i'akesucharecuestanattachment .othisapplication. 'I'ataisavailabke fcretherparameters notIisTBdabovB(nA.oretherpartsotthisapplication theapplicant shouldreporthatcatalnTheblankspacesprovldea:nthispart.I"OTES:I.Onttcodesforparameters reportedInpartsAand8canbefoundontheletthandsideofthIsform.GrabsamolesnailbeusedTcanalyzetorpH,Temperature, totalohenols,residualchlorine, oilandgrease,andfecalcol)formInasurfacewaterdischarge unlessotherfrecuencv-sample typeanalysesareavailable. SeeGlossary(pace48)fordefinition ofgrabsample.24-hour~pcs(tesamplesshallbousedtoanalvzeforTotalBMs,CCO,TOC,Armon(aIlltrcgen, andTotalSuspended SO(iCSin4SurfaCewaterCisCnarge un(BSSO~herfreauenoy-Sample typeanalySeSareBVBI(able.SeeGIOSSary(page48)fordefinition ofcompos(te sanole.REPORT(l)G CFINTAKECATA.'5uarenotreruiredToreOCr.unlessyouwishtodemcnStrate yOurellciblllty for4"retwsffIentl(mltat(cn 'CrOneOrmerePOllutantS, thatIS,aneffluentlimitat(On adjuStedbySubtraCtlng theaveragelevelo!thecollutantfs) presentInyourIntakewater.NPOESregulations allownetI(mltatlons onlyIncertaincirctmstances. ccnronstraTe vourellclbllitv,-eporTtheaveracooftheresui3ofanalvsesonyour3I)r*uii').BB'CBie,B<<.eare<<sfBr'.IST.eated)~\53,sebaratB"BBT"cnt!ningTrefc)lcin@fcrBachoiiutanT: (5)<stateentT"at-"BIntakewater'3drawn'rcmTrecccvofwater.(ntowhichthed(scnarqe Is~ace.('.Therlse,'ouare-;:ellcible!crneti:m(tat(ons.) ib)>state"ent o!eBxront.which.neleveloftne.IfutantisreducedbvTreatment ofycur<<astewater. (Your"Im(tationa <<illpeaajuStecOnlyTCTheeXTentTeatthepCI(utant 3SnctremOVed~)<<'C)ahenacplicao)e (tcrexample,<<hen.nepollutant represents aclassofcompounds), ademcnStrat(cn ofthe<xtent<<o.<<wlc"~ii<<tc(33tants ine(~~ekeveryp";3'caiIv,chemicallv,'biological(v 'romT"epc(lutants contained Invourclscrarge. (Your(in(tat)cna <<IllbeadjustedonlyTOtheextentThattneintakepollutanTS donotvaryfromtned(scnargeo pollutants.) vcunavet'<<oor-crei.stantiallyLcantle<<'utfs ~fs,,cumavrecuestcer..isslon frompeurper-,ittinc 5urnoritv Tcsa<<aieanoari)!vzeon'v.-.ecut!elIsncsuc.I-"Bresul3oftheanalvslsfcrethersuostantlal lyCB'it3C51 cut!5(ls. '>>urr<<ciest~3Trente)bv-hepe~i-(noausncrltv, cnaseoaratesheetat-ac"Bdto.the3.""Icatlci. cr<<ifcenT<<(*nilnut'5l'i,.u dieest,5.c:ascribe wnvneourfails<<Bien.ucid.cTBSTaresusT5nialIVldenticai zo-reouT!allwnlchvouJ(dTes SEEINSTRUCTIONS ONREVERSESIDESECTIONIIPERMIT~MI0005827NUMBEREMCRITICALMATERIALS TOXICPOLLUTANTS A.USETHISDATASHEETTORECCRDIt(FORMATION ASREOUIREDIN:(CHEQ(APPROPRIATE BOXFORWHICHItiFORMATICN THISDATASHEETREPRESEIITS )1eSECTIONIIPITEM4EeGROWDWATER DISCHARGE ltIFCNATION(PAGE55)2.SECTIONIIPITEM6.PRIORITYPOLlJITANTS IttSURFACEWATERDISCHARIZ (PAGE37)OX3eB.BEIDW:CRITICALYATERIALS (TABLEIV)INSURFACEWATBIDISOIARGE (PAGE2)HAZARDOUS SUBSTANCES INDISCHARGE BeLISTAttYCRITICALYATERIAL(TABLEIVPAGE6)NOTADDRESSED Itl'SECTION IIITEMFePRIOIIITY FOLUITAIITS WHICHYOUKNOWORHAVEREASONTOBELIEVETOBEPRESENTItlTIEDISCHARGEP SEEREVERSESIDECFTHISPAGEFORFUItTIFRDIRECTIONS ~NOTAPPLICABLE APPLICABLE (SEEBaDW)AeNAPEOFCRITICALMATERIALORPRIORITYPOLUITANT

• Hdra'zinc00302012UNITSCODElMg/I2UQ/ILBS/DAYKG/DAYItLIt~IBsAVERAGECONCENIRATIONI SAIPLETYPE;IIOFAIALYSESC>>teAXI.'VI CCttCENIRATI ONAtaYASSAsePYYEOFCRITICALMATERIALORPRIORITYPOLLUTANT BsAVERAGECONCENTRATION; SAMPLETYPEllIIOFANALYSESCeYAKIF'NCENNIRIATION AttDMASSAettAIIEOFCRITICALMATERIALORPRICRllYPOLU/TANT BeAVERAGECOICENIRATICNI SAMPLElYPEittOFANALYSESCeMAXI'ONCENIRATION ANDMASSAeNAMEOFCRITICALMATERIALCRPRIORITYPOLUITANI'IT CODESAMPLETYPECFANALYSESLJII.LJJJLJLJWITCODEWITCODELJ~~~LJUNITCODESAYPLETYPEOFANALYSES~.LLLJLJWITCODEWITCODELJWITCODESAMPLETYPEOFANALYSESLJWll'ODEWITCODELJ~~~LJ3.AVERAGECOtICENTPATICNP SA"PLETYPEIIIOFAIIALYSES WITCCDE~LETYPELJOFANALYSESCeYAXltulCOtLENTRAT IONANDMASS~PMPLYYPlGRAB224HR.COMP.AsNAtEOFCRITICALMATERIALORPRIORITYPOLLllTAttT CeeMAXIYUYI COtlCENIRATIOtt AtoYASSAettA'IEOFCRITICALMATERIAI.

ORPRICRITYPOLLUTAIIT 3~AVERAGECCttCENTRATIONI SAMPLETYPEpeeOFANAI.YSES Ce"AX!le'COIICENTRATIOI AteYASSB,AVERAGECCIICENIRATIONl SAMPLETYPE;IttOFANALYSESIUNITCODEWITCODELJ~~~LJWITCXESAtPLETYPEIIOFANALYSESLJWITCODEWITCODELJ~~~LJWITCODESVPLETYPEhOFANALYSESLJWITCODEWITCODEAetIAYEOFCRITICALYATERIALCRPRIORllYPOILUTANT 3.AVBVGECOttCENIRATICtt; SA~TYPE:ttOFANALYSESILtlITCODESAtPLElYPEOFANALYSESCeYAXIMNCONCENIRAT IONANDMASSAetIAYEOFCRITICALMATERIALORPRIORITYPOLUJTAeVT WITCODEWITCODELJ3~AVEPAGEOIWCENIRATIONI SAMPLETYPEIIIOFANALYSESCeMAXIYLMCONCENTRATICN AttDMASSWITCCOESAYPLETYPEOFAttALYSES LJWITCODEWITCODELJADDITIONAL PAGESOFTHISITEN7AREATTACIEDFORTIERESTOFTHECRITICALC3YESMATERIALS AND/CRPRICRITYPOLLUTANTS RECUIREDTOBEREPORTEDi ElNO+Hydrazine isnotexpectedtobepresentindischarge butsmallquantities maybefoundinthesteamgenerators butwouldnotbeexpectedtobefoundintheactualdischarge flowtoOutfalls001or002.39

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iscnorql"c rothesur!oce<<oters.:"IEcPEpERFIIT'4,'~'J)ER liiTHEBOXATHET&CFHISPCS..fEPEPMIT':WMSERCANEEFOvh0CNTHEFRONTPAGEOFVCvpEXPiRINGoERMIT.'Iroisisonewornotpreviously permitted feellitv,,hen leaveplonkanaonuroerwliIbeosslaned.

eeu~foiInumberinthespaceprovidedfcreachpageo'ectionII..oreachinaivicuol dlscnorce point4separateserSacr!cn:'I. item6formsnusroefilledour.iTEM6opICRIr"cx)ll.UTAH(TS ANOACOITICIIAI. I'IFCRMATION 'IOTE:A~Ionalfvouhovet<<oarmoresubstanrlol lyindenricoi ourfoiIs,youmayreavestpermission fromvourperm(trina outnorlty tosampleondanalyzeonlyoneoutfallandsubmitrheresultsoftheonoiyslsforothersubstantially Identical cutfalls. IfyourreauestIsgrantedbyrhepermitting outnoritv, onaseparatesheetattachedtorheapplication formIdentify<<hlCnOutfalIycualdteor,OnddeSCrlbewnyti.eOutfallSwnlahyaudidrOtreStOreSWPStantlal lyIdenrlaal -OtheOutfall<<nichYouoldrest.40CFRPartI22.2l(g)<8), Friday,AbriII,l983~providesforoSmailBusinessExemoticn fromthereporrlrg ofauontitotlve aotafororganictoxicpollutants ondtcxlcpollutants osreaulredbyport122.2I(g)<T)<il)(A) or122.21(q)(7)<ili)(A). Thesepartsoreself-explanatory anddonotrequirefurrherInstrucrions. S(molyoohrougheachparranddoosIndicated. SeveralIndustrial categories andsubcategories hovebeen.exemptedfrcmsubmitting doraoncertainGC/iusFroctlons (40CFRPart(22,Vol.48,lio.64,Friday,AprilI,l983,IiotesI,2,and3).Reviewthefollowing listtodetermine whetheryourfacilityqualifies tobeexemptfromreportlna Gc/Ms(Goschromotoarephy/ MossSpectroscopy) Fractions. TextileMIIIsIndustryGCIMSFractionTestingondpeporrlng Exempt(cns -AII!ourGC/MSorganicfractions inrheGreigeMIIIsSubcategory. -Pesriclde fractionInailothersubporrsofthisIndustry. OreMininaandDressingIndustry-volatile, bose/neutral, ondpesticide fractions InrheBaseondpreciousMetalssubcategory. -AIIfourGC/MSorqonicfractions inollothersubcategories ofthisIndustry. Gumand'WoodChemicals Industry-Pesticide fractionintheTallOlIRosinSubcategory andtheRosinBasedDerivatives Subcategory. -Pesticide andbase/neutral fractions inallothersubcateaories ofthisIndustry. euloandPaperIndustry-Pesticide fractioninPapergrade Sulfitesubcateaories (subparts JandU).-Base/neutral andoesticlde fractions inDeinkSubpartq,Oissolvlna KraftSuboartF,andpaperboard fromWastePaoerSubpartE..volatile, base/neutrals pesticide I'rectlonsIntheBGTBleachedKraftSuboartH,Semi-chemical Subparts8andC.andNonintegrated-Fine PapersSubpartR.-Acid,base/neutral, andpesticide fractions InFineBleachedKraftSuboartI,Oissolvinq SulfitePuloSubpartK.Ground-wOOdFinepaperSSubpart0,HarketBleaChedKraftSubpartG~TiSSuefrOm'WaStepaper SubpartT~andNOnintegrated TISSuePapersSubpartS.SteamElectricPowerPlantIndustr-Base/neutral fractionIntheOnce-Through CoolingwaterFlyAsh.andBottomAshTransport waterorocesswastestreams. 38 GENERALCHEMISTRY RESULTSClientSampleID:OUTFALLOOA-VI)-SLOWDOWNLALBatchID(s):126im,127im,128imDateCollected: 01-26-94Matrix:waterDateReceived: 01-28-94P0469095-040-3N 'Constltuerit FluorideinmILBromide,inmILNitrite-Nitrate-Nitrogen, inmILSulfateinmILTotalCanide,inmILColorTotalPhenolics, inmILSulfideinrnILSulfite,inmILMethod340.2300.0353.2300.0335.2110.3420.1376.1377.1Result<0.15<0.050<0.050<0.059<0.020<5.0<0.15<1.0<1.0Reporting,,','";. Detection'Umlt'.15 0.0500.0500.0590.0205.00.151.01.0..-,,;Date QualNer(s) DateAnalzed03-02-9402-17-9402-11-9403-05-9402-07-9401-28-9402-08-9401-29-9401-29-94LALSamlelDL1150-3L1150-12L1150-15L1150-12L1150-18L1160-3L1150-24L1150-9L1160-6Comments: 0 GENERALCHEMISTRY RESULTSClientSampleiD:OUTFALLOOABLOWDOWNLALBatchID(s):126im,127imDateCollected: 01-26-94Matrix:waterDateReceived: 01-27-94PO¹69095-040-3N Constituent TotalPhosphorus, inm/LAmmonia-Nitrogen, inmILTotalSuspended Solids,inmILTotalOrganicCarbon,inmILChemicalOxygenDemand,inmILTotalKjeldahlNitrogen, inm/LMethod365.2350.1160.2415.2410.2351.2Result<0.030<0.050<121.8<182.4Reporting Detection Limit0.0300.050121.0180.10DataQualifieris) DateAnaledLALSamleID02-08-94L1142-802-01-94L1142-802-16-94L1142-401-28-94L1142-403-03-94L1142-80242-94L1142-12Comments:

METALSRESULTSClientSampleID:OUTFALLOOA-U/I-BLOWDOWNLALBatchID(s):126imDateCollected: 01-26-94DateReceived: 01-26-94Matrix:waterPO469095-040-3N Constituents MethodConcentration lmIL)Reporting Detection UmltImIL)DataQualif)eris)DateAnalzedLALSamleIDAluminumAntimonArsenicBariumBeiliumBoronCadmiumChromiumCobaltCoerIronLeadManesiumMananeseMercurMolbdenumNickelPhoshorusSeleniumSilverStrontium ThalliumTinTitaniumUraniumVanadiumZinc60106010706060106010601060106010601060106010742160106010747060106010601077406010'.6010784160106010602060106010<0.20<0.060<0.010<0.20<0.005<0.005<0.010<0.050<0.025<0.10<0.003<5.0<0.015<0.0002<0.067<0.040<0.050<0.005~<0.010<0.10<0.010<0.20<0.10<0.001<0.050<0.0200.200.0600.0100.200.0050.200.0050.0100.0500.0250.100.0035.00.0150.00020.0670.0400.0500.0050.0100.100.0100.200.100.0010.0500.02002-22-94L1150-5202-22-94L1150-5202-20-94L1150-5202-22-94L1150-5202-22-94L1150-5202-22-94L1150-5202-22-94L1150-5202-22-94L1150-5202-22-94L1150-5202-22-94L1150-5202-22-94L1150-5202-23-94L1150-5202-22-94L1150-5202-22-94L1150-5202-09-94L1150-5202-22-94L1150-5202-22-94L1150-5202-22-94L1150-5202-25-94L1150-5202-22-94L1150-5202-22-94L1150-5202-28-94L1150-5202-22-94L1150-5202-22-94L1150-5203-07-94L1150-5202-22-94L1150-5202-22-94L1150-52Comments:

VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260Page1of2linmleID:TFALLA-IBLWDWNDateCollected: 31-JAN-94 Matrix:WATERAnliIB¹:244--1QCBatchID:020494-8260-C1 LALmIID:L117-2DateReceived: 01-FEB-94 DateAnalzed:04-FEB-94 DilinFr1SURROGATE RECOVERY12-Dihlhn-4Toln-QCLimits7-114-1104-Bromofluorobenzene 11086-115Constituent Chloromethane VinIhlriBrmmhnChloroethane Trichlorofluoromethane An11-DihlrhnCarbonDisulfide MethleneChloridern-12-Dihl rhnVinIA11-Dichloroethane 2-Butanone i-12-Dihl rhnhlrfrm111-Trichloroethane CarbonTetrachloride 12-DihlrhBnznTrichloroethene TCE12-Dichloro roaneBrmihlrmhn2-hlrhIVinIEhr4-Meth1-2-entanonecis-13-Dichloro roeneTInrn-1-Dihlrrn2-Hexanone 112-Trichloroethane Tetrachloroethene PCEConcentration IL<5<5<5<5<5<5<10<5<5<5<5<2<10<5<10<5<5Reporting Detection LimitIL101010DataQualifier sLOCKHEEDANALYTICAL SERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260ClientSamleID:OUTFALLOOA-U/IBLOWDOWNLALSamleID:L1175-23Page2of2Constituent Dibromochioromethane hlrnznEhInnm-Xleneo-XIenernrmfrm1122-Tetrachloroethane 13-Dichlorobenzene 14-Dihlrnzn12-Dichlorobenzene Concentration IL<5<5<5<5<5<5Reporting Detection LimitILDataQualifier sLOCKHEEDAIVALYTICAL SERVICES SEIVIIVOLATILE ORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270Pa1of2linSamIID:TFALLA-UIBLOWDWNDateCollected: 26-JAN-94 Matrix:WATERAnliIBh¹:24-27-AQCBatchID:8270SEMIVOLATILES 4825LALSmlID:L11DateReceived: 28-JAN-94 DilutionFactor:1DExrd:1-AN-4DateAnalyzed: 04-FEB-94 SURROGATE REVERY002-FluorohanoiPhenol-d, Nitrobenzene-d, 2-Floro'enI24-Trirmonp-Terphenyl-d,4 42308438QCLimits21-10010-9435-1144-1133-141PhenolConstituent Concentration IL<10Reporting Detection LimitIL10DataQualifier si2-hlrhIhrhirhnl13-Dichlorobenzene 14-Dichiorobenzene BnzlIhl1-Dihlrnzn2-MehIhenoibis2-Chloroiso roIether4MhIhnIN-Nir-Di-n-rIinHexachloroethane Nitrobenzene Ihrn-NirhnI24-DimethIhenolBenzoicacidi2-hlrhxmhn24-DihlrhnI124-Trichlorobenzene Nahthalene4-hlrnilinHxhlruin4-Chloro-3-me hIhenol2-MethInahthaleneHexachloroc cloentadiene <10<10<10<10<10<10<10<50<10<10<10<10<10<1010101010101010501010101010LOCKHEEDANALYTICAL SERVICES I SEIVIIVOLATILE ORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270ClientSamleID:OUTFALLOOA-U/IBLOWDOWNLALSamleID:L1150-30Pae2of2Constituent 24-Trihlorohanoi4-TrihlrhnI2-Chlorona hthalene2-Nitroaniline DimhIhhIAnhhln26-Dinirotoluene 3-Nitroaniline Anhhn24-Dinirhnoi4-NitrohenolDibenzofuran 24-DinirIenDihIhhI4-ChlorohenI-henletherFluorene4-Nirnilin4-Dinir-2-mhIhnIN-Nitrosodi henlamine4-BromohenI-henleherHxhlrnnPnhlrhnIPhenanthrene AnthracenerzIDi-n-IhhIFluoranthene PreneBInzI'hhI3'-DihlrnziinBenzoaanthracene Chrsenei2-EhlhxlhIDi-n-IhhIBenzobfluoranthene Benzokfluoranthene BnrnConcentration (/L)<10<25<10<25<2<25<10<10<10<2<10<10<2<10<10<10<10<20<10<10<10<10Reporting Detection LimitI/L)1010102510102525101010121010101010102010101010DataQualifierls) Inn12rnDibenzahanthracene Benzohierlene<10<101010LOCKHEEDANALYTICAL SERVICES SEMI-VOLATILE ORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8270TENTATIVELY IDENTIFIED COMPOUNDS ClientSampleID:OUTFALLOOA-U/IBLOWDOWNLALSampleID:L1150-30DateReceived: 28-JAN-94 Matrix:WATERAnalytical Batch:020394-8270-A DateAnalyzed: 04-FEB-94 DilutionFactor:1QCBatchID:8270SEMIVOLATILES 4825Tentatively Identified CompoundUnknowmOrganicAcidEstimated Concentration (yg/L)Retention Time(minutes) 25.24DataQualifier(s) fCnLOCKHEEDANALYTICAL SERVICES

OILANDGREASEEXTRACTABLES ANALYSISRESULTSBYFT/IRUSINGIVIETHOD413.2linmIID:TFAL-IBLWDWNDIlc:2-AN-4 DateReceived: NAMatrix:WATERAnalticalBatch¹:020494-413.2 AmIID:11.42DAnIz:7-FEB-4DilutionFacor:1DaeExtracted: 02-FEB-94 QCBatchID:020294-413.2 Constituent OilandGreaseConcentration m/LReporting Detection LimitmILDataQualifierIs) LOCKHEEDANALYTICAL SERVICES PESTICIDE ANALYSESRESULTSBYGC/ECDUSINGMETHOD8080ClinSmieID:TFALL0A-UIBLWDOWNDaColle:2-AN-4DateExtracted: 31-JAN-94 Matrix:WATERAnalytical BatchII:013194-8080-E-4 LAL'SmIID:L11DRive:2-AN-4 DateAnalzed:01-FEB-94 DilutionFactor:1QCGroupID:8080-PEST/PCBS 4822SURROATERECOVERYoQCLimitsTCMXDCB6927"'0-15060-150A-BHB-BHCG-BHCD-BHConstituent rConcentration L<0.05<0.05Reporting Detection LimitL0.050.05DataQualifier(s) HEPTAHRALDRINHEPTACHLOR EPOXIDEHLRDANEENDULFANIA-CHLORDANE 44'-DDE44'-DDTDIELDRINENDRINENDOSULFAN II44'-DDDENDRINALDEHYDEENDOSULFAN SULFATE'ETH OXYCHLORTXAPHENEPB-11PCB-1221PCB-1232PB-14PCB-124PCB-1254PCB-1260TECHNICAL CHLORDANE TCMX-tetra-chloro-meta-xylene DCB-Deca-chloro-biphenyl <0.05<0.05<0.05<0.1<0.1<0.1<0.1<0.5<20.050.050.050.10.10.10.10.5LOCKHEEDAIVALYTICAL SERVICES RADDATAREPORT(ra01)IndianaNichiganPouerCo.eBridgman,HI OrganicandInorganic Contaminants (projectCOOK.JENI) ClientSampleID:OU'IFALLOOA-U/IBLOlDOMNDateCollected: 26-JAN-94 LALSampleID:L1150-46iDateReceived: 28-JAN-94 HatrixtMaterLoginNumber:L1150GrossAlphaGrossBeta23-FEB-94 GRALP/BETALAL-0060475623-FEB.94 GRALP/BETALAL-00604756030.20.693.21.53.1pCI/LpCi/LPage6nag<v'5

RADDATAREPORT(ra01)IndianaNichiganParerCo.*Bridgman,NI OrganicandInorganic Contaninanta (ProjectCOOK.JENI) HatrixtWaterClientSangriaID:OUTFALL00A-U/IBLOUDOMNDateCollected: 26-JAN-94 LALSaapieID:L1150-49DateReceived: 28-JAN-94 LoginNmhertL1150Ra-226Ra-22822-FEB.94 RA-226LAL.0073477123.FEB-94 RA-228LAL-0074550300.620.140.34pCI/L0.560.91pCI/LgPage9 h~I PHMetercpcy-lo~CaldatedueSampleTimeSampl'egSampleDateCDMEnteredbyPHAnalysis(LAB.079) OutfallOOA0PD5.3.56)SampleC/ph(priortocorrection) 7)NH3pHcorrection goz.5.3'SampleSampleTimeSamplejjSampleDateCDMEnteredby8))ampleresultsC/pH(after'7.7gNHCorrection) 3+boamcux-p'-4~/+/7>+U+/LZoo5.3.56)SampleC/ph(priortocorrection) 7)NH3pHcorrection 5.3.68)SampleresultsC/pH(afterCorrection) 9)LAB.041SpecsVerifiedby:hl/8Supervisor Review/Date ~W+IWFormpreparedby/DateFormapprovedby/Date12THPLAB.041.25s Revision1 --4OutfallOOASample/Standard SamplegDateTimeCDMEnteredby)SoDetermination ofTotalChlorine(Lab170)/0~~'~~(y~~/'/Instrument CPCf)Technician Vil)Absorbance 6.112)Results,ppm3)Dilutions made4)Results,ppm(I)2~03)zoC51LAB.041SpecsVerifiedby:~NFlluperirvRsecview/Bere~~HI +Formpreparedby/DateFormapprovedby/Date~~~12THPLAB.041-25)l Revision0 SEEINSTRUCTIONS ONREVERSESIDESECTIONIIPERMIT~gZppp582~%tSIy~A.LOCATIOtt OFDISCHARGE ASSti,~Wi,>>ZCTIUNt~06,iUPN~06S,iTTUE~i9WDISCHARGE 8>>tIA%RECEIVlttG HATERIIE>>GROItZHATER ORNAPEOFSIRFACEHAC>>DOYCUDISCHARGE SEASOttALLY>> (IFttOPCCIIT!t@E TOE)LAIKEMICHIYESXtaLOCATIOND.IFYES>>I.ISTDISCHARGE PERIODSNANt./DAYNt./DAYSCHEDULECONTACTCOOLINGF>>TYPEOFHASTEHATER DISCHARGE FLOWRATEWASTEWATER ~TypSEE.EAtSAPPAIIATI>>ti IIATENAIN>>HReHR>>DAYIN>>/WK>>~~M~~M~~~0NHASTBIATER lYPECOKEL~JLJLJLJLJLJNONCONTACT G~DISCHARGE SCHZUIE(YEARLYAVERAGE)COOLINGPROCESSHeDISCHARGE FLCHRATESANITARYSTORMWATER U~NITGUSHOURS/DAY ~24TOTALYEARLYDAILYHININIIDAILYHAXINNa>>>>PS>>>>~36157.68p~20.432~21MGY2MGDSGPDITEM2WATERTREATMENT ADDITIVES IeTHENXINNDISCHARGE FIDHRATETOBEAUIHCRIZEDINPERHIT>>Je>>"AXING DESIGNDISCNRGEFIMRATE>>A>>IX)YOUUSEHAlERTREATHENT AKDITIVES TOTREATYONDISCHARGE? (IFNO,CCNTINIETOITBI3)BiNtNEFIICTIOtt>> At%ICHEHICALCOMPOSITION OFlAESEAKDITIVES>> NACeNAMEANDADKRESSOFHAIAFACTIRERS OFlHESEAISLEITIVESeDESIGNUNITSCODE1Mg/I2Ug/INAD.EXPECTEDDISCHARGE CCtCENTRATION OFAIKIITIVES ~NAADDITIVENA%AKDITIVENA%HININNUNITSAVERAGECODEWITSHAXINttCODEWITSCODEADDITIVENA%EDOYOUTREATTHEDISCHARGE lQRENIVEADDITIVES? NAQYESLJ:~LJFHHATISIHERENIVALEFFICIENCY ANDDISCHARGE FREOUENCY NAADDITIVENt4%ADDITIVENAHEADDITIVENA%KRENIVALNS>>/DAYKAYS/WK~LJGeASAttATTACIPENT TDlHISAPPLICATION PROVIDESPECIFICÃtNVLIAVCRAOUATICTOXICOUYilCAL KATAORREFERBICE HHICHAREAVAIIAIRE NDINFORHATION ONTHERATEOFDEGRADATION OFTHEPRODUCTSFOREACHADDITIVE~NA31 >>VSTr~XTI".'IS ERCCMPL~:IQ SECT:"'IIIITEM7'.isfselsto'eusedovbothsurfaCeandgrcunc~ater aap((cents tcrecordin!crratlcn onanvMichigancriticalmaterial, E.P.A.:rlcri-vollu.ant~crnazarcous substance In>>>>nlchtnlsapp(ication reouirescatatobeprovided. Thisvouldincludeanychemicalsubstance fromtheMichiganCrItlcalMaterials Register(TableIV),theE.P,A.PriorityPollutant Listing(Tablev),orTables~.A->>zn(cnliatS"rganiCToxiccol~rants..ther axlePollutants, Conventional andNonconventional Pollutants andHazardous psa",ces,',Tel7"R!Tl"LuATEPIAIS. op(DR(TVPDLL~F<rITS. ~ID/CRuAZARDNSSL>>BSTAMCES IWTHEDISCHARGE "'a-erIs>>I';stthenameofthecnemlcalsubstance (crltlca)

material, prioritypollutant, ornazardous substance) fromTablesIV,V-noIIA-viasreauirealntheooxwhichycucnecxeoinA.(-3.above.Entereachcnemlcalsubstance's parameter numberas(lstedinTablesIV,VandIIA-VAItprovided.

--ovldetrsaieraceccncenrra.icn -..'-ecnemicaisupstance rarao:nA.'-c(catetresembletypeusedandtnenumberofZnalySeSracetOprCVldetheCCnCentratlCn dataIOr.heCnemlCalSubStanoe namedInA.C.Providethemaximumconcentration anddetermine themassloadingofthechemicalsubstance namedInA'>>DTES:l.(tcnlvoneanalysisvasmacetoracher>>ical substance thenrecord+hatdataasamaximumvalue.(fmorethanoneanalysisnasbeenmadetorachemicalsubstance thenprovideanaveraoevalueofthoseanalysesandthemaximumvalue~Z.,hisSectionII,Item7,ataSl.eetprov(desspacefcrrecording catator8chemicalsubStanceS (Materials). zcsitlcnal space'ort"cr"ing.catarcrmorethan8"arorials cncemacebymaxingcbiescfthisitem7DataSheetaSneeded.it>>SalSOrpOrtanttOuSeaSeparateSetOtDataSl.eetafcreaonapplloable repcrtlng requirement aslistedInA.l-3.andforaacnoutfall."eferIoTheleftmarolnforthecodenumberrepresenting tnesampletypeusedandtheappropriate unitcodes.40 SEEINSTRUCTIONS ONREVERSESIDESECTIONIIPERMIT~MI0005827NUMBERNIFALLtltKRAstIAPEOFPRXESSCOIIIRIBUTIIIG TOTHEDISCHARGE TlROUGHTHISOUTFALLA'QSICCODEBPROCESSSCHHXLE(YEARLYAVERAGE)U2BLOWIDOWINIDURS/DAY L224Iv/v~till,PROCESSSTREAMSCONTRIBUTING TOOUTFALLDISCHARGE I/IC/IIIIOE0IIDsPROCESSPRODUCTION RATENACsPROCESSWASTEWATER FLOWRATEBasis:1993actualdatasubmitted onDMRsTOTALYEARLYDAILYHlttINttDAILYHAXII/IN22QJi0.234~6UNITS/TIPE1POUNDS2GALLONS3CUBICYARDS4TONS6MGY6MGD7GPD!ME1HOUR2DAY3WEEK4MONTH5YEARIttIttOustCIKI/IIIIOMtO0A>>ttA%OFPROCESSCONIRIBUTIIG TOTHEDISCHARGE TIROUGHTHISOIIFALLAtEISICCOPEBePROCESSSCIEIXAE(YEARLYAVERAGE)C.PROCESSWASTEWATER FLOWRATEDsPROCESSPRODUCTION RATEAetIAt%OFPROCESSCOIIIRIBUTIt4 TOTHEDISCHULETHOROUGHTHISOUTFALLAttOSICCODEBsPROCESS~(YEARLYAVERAGE)CePRXESSWASTEWATER FISHRATED.PROCESSPRODUCTION RATEA.NAHEOFPRXESSCONIRIBUTING TOTIEDISCHARGE NATHAtIDSICCODEB.PROCESSSCHEDULE(YEARLYAVERAGE)CsPROCESSWASTGATER FLOWRATED.PROCESSPRODUCTIOIIRATEsssvM/Osv ~sEvs/vEMTOTALYEARLYDAILYMININGDAILYI/AXIPINEsrs/Er~Esvs/vs@TOTALYEARLYDAILYHINIPINDAILYHAXINPI!EEE/ssv~seve/vs!I! TOTALYEARLYDAILYMININNDAILYHAXltlNWITSSTIPEWITCODEWITS/TINEA.VW%OFPROCESSCONTRIBUTING TOTIEDISOQRGENATIROUGHTHISOUTFALLANDSICCCDEBePROCESSSCHHXAE(YEARLYAVERAGE)CePROCESSWASTEttATER FLCHRATEDePROCESSPRODUCTION RATETOTALYEARLYDAILYHlNltXNDAILYHAXINNvevs/vsMWIT%DEUNITS/TltE33 INSTRUCTIONS FCP.CCIsPI.ETING SECTICNIIITEM3T~ISfarnrequireSinfarmetlCn OntreOrCCeSSS-reamSWhiChCantrlbute TOthiSdlSCnerge. NTEot"EPEP'4ITNlPIBERINTHEBOXAT.HETCPCFTHISFCRAITHEPEPSITIeIMBERCANSEFOUNDCNTHEFRONTPAGEOFyCUREXPIRING<<Rui.IfrnisIsenewori,atpreviously "emit,edfacility, thenleaveblankendanumberwillbeassigned. Enter'~~31InumaerinSOaCeOrOViCedfOreaCnOaqeOfSeCtianII~mareeCnindiVICual diSCherCe painteSeparateSetCfSecticnil'ormsmustoefilledout.ITEM3PROCESSSTREAMSCCNTRIBLITING TCQISCHARGE: <CREACHSEPARAT"FPOCESSPROVIDETHEFCLLCNIISI INFCONATICii A,Entertnehereoftheprccesswhichcontributes tothisdischarge. AlsoorovldeheprcoerSICcode.S.IndicateTheyearlyaverageprocessscheduleinhoursperdayanddays-per-year. Providecneorocesswascewacer fiihvraceinformation asrequested basedonyourlastl2monthsofoperations. RefertounitcodegivenIntheleftmarginfortheappropriate flowunits.O.ProcessProduction Rate-Certainpernltlinitatlons meybebasedonproduction rates.Theproduction ratesusedtodetermlre oernitlinltsshellbereoresented byareasonable measureofactualproduction ofthefacility, suchastheproduction curingtherignncnthcfthepreviousyear,orthenanthlyaveracefortnehiahestofthepreviousfiveyears,orotherreasonable measuceasstatedInaoolicabie U.STE.P.A.categorical rulesandregulations .=crnewsourcesarnewdlschergers, actualraduction shallbeestimated usingprojected oroduc.ian. Reccrdyour-.ocuctlcnratesIntneternsanounitsusedintneeoolicaole V.S.E.P.A. csteaarical rulesandre-ulations foriourtvpeoffacility. SEEINSTRUCTIONS ONREVERSESIDESECTIONII74UMBER~MI0005827~008GROUNDWATER DISCHARGE INFORMATION AeISTHEDISCHARGE FROMTHISOUTFALLDIRECTEDToTHEGRONIDORGRSNWATERS? (IFttOeCCttTlttUE TosTEM5)BeHASAHYDROGEOLOGICAL STUDYORITSEQUIVALEIIT BEENPERFORMED ORtSThERESIFFICIENT CURRENI'ÃXOGEOLOGICAL thFONATICN AVAILABLE ASREQUIREDBYTIEWATERRESOURCES Cotttlsstott PART22GROUNDWATER RULESOFAUIUSTltl41980R~523eZ707(PAGEQ)FORTHISEXIST!t7GORPROPOSEDDISCHARGE. IFYESATTACHACOPYOFTWEREPORT.CeAREYCUREQUESTttg ANEXP'PTICN FRI¹tSUBMITTlt4 AHYCROGEOLOG ICALREPORTl5DERRULER.323.22F (Q(PAGEt15)ORFRCMGRONGtwATER MONITORING I)EQUJREYSNlS UIIERRULER.Z5e(>)(PAGEfQ)OFTHEPARTRRILES>>IFYESATTACHDOQNEIITS ANDEXPlA'VLTION ToDEIONSTRATE THATYOURDISCHARGE WOULDQUALIFYFCRANEXPIRElothDeAREYOUREQUESTING AVARIANCEFRCttRULE323.2205(PAGE5)(tgNDEGRADATION) OfTHEWATERRESIX¹ICES COB%ISSIONPART22GRONG5ATER RULESTtFYESATTACHSUCHDOCI¹'EATS ASh'ECESSARY ToDEMONSTRATE THENEEDFORAVARIANCEIttTERMSOFTHECRITERIASPECIFIED INRIIE5'DeQ10(PAGE+OFTHEPART22RULESeNANANAYESleeYESYESITEM5EXPECTEDWASTEWATER CHARAC-TERISTICS UCOOE1Mg/I2Ug/I3COUNTS/100ml4S.U.5F6LBS/DAYTIEAPPLICANT MAYBEREQUIRED'IDDoADDITICtIAL WASTEANALYSESe AeDISCHARGE CHARACTERISTICS COIICENIRAT IONBOD5(FIVEDAYBIOCtetICAL OXYGENDEMAIO)'COD(CHEMICAL OXYGENDEMAND)TOC(TOTALORGANICCARBON)NOTAPPLICABLE/BELIEVED ABSENTNAPRESENTSDATAPROVIDEDINITEM7I¹IITSCODEltANALYSES~TYPECODEu1ulenntaNITROGEN(AsN)TOTALSUSPENDED SOLIDSTOTALFHQSFHOIIUS (asp)TOTALRESIDUALCtiXR!ttEDISSOLVED OXYGENPHHIM~.LJ~8,~6~LJu1u1~uFECALCOLIFORMBACTERIATEMPERATI¹IE (Su¹4ER)TEtPERATI¹IE (WlttTER) ~~u~~uBeOIHERWASTEHaTER CHARACTERISTICS u5u5E~IISTALLCHEIIICAL SISSTANCES WHICHAREINMICHIGANSCRITICALPATERIALS REGISTERTABLEIVIPAGED)ANWORUeSeEPASPRIORITYPouUTANTLISTTABLEV(PAGE7)ORANYOIIKRSUBSTANCES NltcHARE0RHAYBEcot%INJI¹IIQUs ToTIEDEBIGNATEDUsEs0FTIEGI(tx¹GIHaTER 0RToTHEPUBLICHEALTHTHATAREDISCHARGED OREXPECTEDToBEDISCHBRGED ToTHEGRtX5DWATERAY THISFACILITY. ESTIMATETHEFINALEFFLLENTCottCENIRATICN AttoRECORDALLDATAINITEM7OFSECI'IONIIINTHISBooleLET. SAMPLEZYRF1GRAB224HOURCOMPOSITE 0ILItGREASEuuLAJuuu~uLJSEEATTACHEDSHEETSFORANALYSISDATAREQUIREDINFORMATION FORSURFACEWATERDISCHARGES.

• Basis:1993actualdatasubmitted onDMRS35 INSTRUCTICNSFCRCCIZPLET>taS SECTIONIIITEMS4ANO5his!ormrecuiresInformation cnaspecificou.aa>Idischarging toeitherthegrouncwaters orthesu!face>>aters.NTERT,EPRMITIIPIBERIf<THEBOXATTHETCPCFTHISORM.THEPERMITNUMBERCANBEFOUNDONTHEFRONTPAGEOFYOUREXPIRING"OMITSlfTn)SISane>>OrnOtDreVIOuSly permitted

faClllty, thenleaVeblankandanumbers<<illbeaSSlcned.

Enter-"eumfallnumberinthesoaCeprovidedforeacnDadeOfSectiOnII.Foreacnindividual dIscharcepointaseparatesetSeTInII!brms(Items4anc5)mustbe!Illedout.ITEM4ROJlO'".ATEP DISCHARGE INFCRuaTIC.'I (OONOTll>CLsJDE DEEP'HELLINJECTION INFORMATICN INTHISITEVI)A.-O.TheaoploCant ShalladdreSSeaChOftheSecartalfthedlSCharge frcmth>SOutfallIStOTheOrcund>>ater. ITEM55'<ISI'6CPE<PECTEO(FgoANENDISCHARGE) NASTENATEa CHaRaCTERISTICS QFGROUIC>HATER CRSURFaCE><ATEoDISCI!ARGE (00.<OTINCLUDEIt>>>uwsIONIsnRvasls!NIt<sHlaF>>MTheapplicant shallreportavailable discharge data(realdataforexistingdischarge orexpecteddataforaproposeddischarge) fortheparameters aslisted.Theseparameters shallbeaddressed foreitherasurfacewaterdischarge orasappropriate foragrcundwater dlscnarge. Forassistance indetermining aoproprlate parameters agroundwater dlscnarce applicant maycontactthe".roundwater Quality0>vision, PermitsSec.IonorTheapproorlate Groundwater QualityOlvlslon's Districtoffice.Theapplicant shallreportthesampletvpecodebestdescribing eachreportedoleceofdata.SeecodingontheleftmarginofTnlsfern.IfThisoutfallisasurface<<atercischarce. Theecol>cant mustreportnuantltatlve dataforeachparameter Identified bvanoot<<-.t.er,;sa"....e*oaSareomseoaao>>ee~oe*.o..'.o.saoaaotsaat*I-"s.:tts'esetst..siasiaIfdataiSaVal>ablefC<OtherparameterS nOtI!StedabOVeInA.OrCtherOarTSOfth(SaopliCatlOn TreaopliCant ShculdrepartThatdataintheblankspacesprovidedlnthispart.ssOTES:I.UnitCOdeSfcrparameterS repcrtedInpartSAandBCanbefcundOOthelefthandSideOfth>SfOTTn.2.GrabsamoleshallbeusedtoanalyzeforpH,tempe<ature, Totalohenols,res(dualchlorine~oilandgrease,andfecalcoliforminasurfacewaterdischarge unlessotherfrequency-sample typeanalysesareavailable. SeeGlossary<page48)tordefinition ofgrabsample.3.24-hourccmposlte samplesshallbeusedtoanalyzeforTotal9005,COO,TOC,armeniaNitrogen, andTotalSuspended SolidsInaSurfacewaterdiScharge unlessotherfrecuency-Sample typeanalysesareavallable.SeeGlossary<page48)tordefinlt'lon ofcomposite sample.REFQRTI'a<<DF >i<TAKEDATA.YouarenotrecuirectoreocrtunlessyouwishTodemonstrate yourellclbllityfora<<net"effluentlimitation fcroneormorepollutants, thatIs,aneffluentlimitation adJustedbysubtracting theaveragelevelofthepollutant(s) presentinyourintakewater.NPOESregulations allownetlimitations onlyincertainc(rcumstances. Tocemonstrate youreliclblllty,reporttheaverageoftheresultsofanalysesonyourintake<<ater(Ifyourwate>>isT.eatedbeforeuse,.esttnewaterafterItIstreated), ancattachaseparatesheetcontaining thefcllo<<ipo fo!eachpollutant: (a)astateentThatt"eintake<<ater'sdrawn!rcmtrebodyofwaterintownichthedischarge Ismace.(Cthe!<<ise,youare",ce!Iolblefcrratlimitations,) astate"ent of'".ee<<tentTc<<nlchthelevelcfTheDollutant IsreducedbvTreatment ofycur<<astewater. (You!limitations <<IllbeadJustedonlyToTneextentthattnepollutant isnotremoved.) (c)'whenaDDllcaole <forexample,whenthepollutant represents aclassofccmpounds), ademonstration oftheexten~towhichtnepollutants <ntheinta'keve!yphvslcally, chemlcallv, orololo<>icallv fr@-.Taopollutants Contenec.-VCurCISCbarre. <<YCurs:mitat(cnS <<:IIbead!uSTedC!Iy-"TneeXTe~tT>>atThelrtakeDOllutantS Conotvaryfrcmtnedlscnarceo pollutants.) <avouhavet"oormoresuosTantlally incentlcal

cutfalls, youmhvreauestpermission fromyourDer...lttlng author:Tv csa-:D!eancanalveon!vn<cufallandsuan(T<<neresultsofneanalvs(s'.crothersubstantially centcIuT~alis,'cu-ec!esTlsraneoyTneperm>.~IncauTholItv~cnasepalaTesheeaTTacrecTotl'eTopi>ca>>cn form(centi!ywhichcutfallyouclctest,andcescribewnvTheoutfallswnichvouc(dnottestareSuOSTantially IdentlCal TOTheOutfallwn<CnVcuOldteST.

SEEINSTRUCTIONS ONREVERSESIDESECTIONIIPERMITNUMSERHI0005827,PRIORITYPOLLUTANTS ANDAOOITIONAL INFORMATION FORSURFACEWATERDISCHARGE ONLYTHEFOLLCWING REOUESTED IPJFORYATION c~>socADDRESSED ~SURFACEWATERDISCHARGERS. KIIE!JJEWUSEDISCHARGERS ~e"PROVIDEEXPECTEDVALUESFORTHEOUAMTITATIVEANDOVALITATIVEIPJFOJUATIONREOUESTED BELOWIAIISTHISFACILIIYAPRIMARYI'JDUSIRY? (REFERTOTABLEIAPAf<4J)(IFtQ,GOTOE)(IFYES,GOTOBIB.IPJDICATE TYPEOFPRIMARYIPJDUSTRY ASLISTEDINTABIEIAPAPJE491(CCPJTIMJE WITHC.)C.DOESTHISOUTFALLDISCHARGE CCPJTAINAth'ROCESS WASTEWATER? (IFNO>GOTOE)(IFYES'OTOD)DIItJDICATE WHICHGC/MSFRACTIOtJS MUSTBETESTEDFCR~(REFERTOTABLEIAPAGE4~IKIIE.FOREACHGC/MSFRACTIONCHECKEDYEACHSPECIFICORGANICTOXICPOU.iffANf 'HITHINMHFRACTIOti 557BEAPJALYZED FOR(SEETABLEIIAPAGE42,INADDITIOPJ ALLPRlt"ARYINDUSTRYAPPLICANTS WITHAPROCESSWASTEWATER DISCHARGE ~PROVIDEOUAMTITATIVE DATAFOREACHTOXICPOLLUTANT INTABLElllAPN4JI3aRECORDALLDATAONFORMSPROVIDED(ITEM7)INTHISBOOKIES'I (CONTINJE WITHE-KBEUJW)XYESJJOELECPWRXYESJJOXvJXATILEBASE/NEUTRAL ACIDPESTICIDE

• E~IF~SURFACEHATERDISCHARGE APPLICANT (PRIMARYORSECONDUIY INDUSTRY),

REGARDLESS OFTHETYPEOFDISCHARGE KPJOWSCRHASRFASOPITOBELIEVETIVEANYPOlLUTAMf LISTEDINTABLEIIAANDIVAPAGES~ISDISCHARGED FRCMANYOUTFALL'HE OUANTITATIVE DATA~BEPROVIDEDI RECORDALLDATAOMFORMSPROVIDED(ITEM7)ItiTHISBOOKLETSPKJTAPPLICABLE/BELIEVED ABSENTOXPRESEtif/DATA ISATTACHEDF.IFAVYSURFACEWATERDISCHARGE APPLICANT (PRIMARYORSECONDARY INDUSTRY)g REGARDLESS OFTYPEOFDIS(595Ep KPJCWSORHASREASONTOBELIEVEAttfPOLLUfANTS LISTEDINTABLEVAPAGE+AREDISCHARGED FRJXIANYOUfFALLTHEAPPLICJPIT ~P'ESCRIBE REASONSFCRTHEPOLLUTANT BEINGPRESENTAPJDPROVIDEAMYAVAILABLE CUJUJTITATIVE DATAIRECORDALLDATAONFORMSPROVIDED(ITEM7)INTHISBOOKlEToXNOTAPPLICABLE/BELIEVED ABSENTPRESEMf/DATA ISATTACHEDGAILSURFACEWATERDISCHARGE APPLICANTS (PRIMARYANDSECCNKARY INDUSTRIES) WHO:)ORMAPJUFACTIRES ZeIip5TRICPKDJPOPHBJOXY ACETICACID(2p45T)I-(I,JI,5-TRIOIIORDPk teXY)PRCPAPICACID(SILVEX,2,JI,5,TP)IrTTRICPLORCPHBKPL (TCPPJORHEXACHLOROPHENE (HCP/J(AILDATAFORTHEABOVEMUSTBEGENERATED USIIJGSTAPJDARD APJALYTICAL CALIBRATION PROCBXPIES) ORKNXJSORHASREASONTOBELIEVETHATTCDDISORMAYBEPRESENTINTHEIRDISCHARGEa ~REPORTJXIALITATIVE DATJ4GENERATED WHICHUSEDASCREENING PROCGXRENOTCALIBRATED 'WITHANALYTICAL STAJJDJIRDS, FOR2.5z/8r-TETRACHLDRODIBENZO PDIOXIN(TCDD)~RECORDALLDATAONFCRMSPROVIDED(ITEM3)INTHISBOOKLETeJ~IF~QSFACEWATERDISCHARGE APPLICANT KPQIJSORHASREASCMTOBELIEVETHATBIOLOGICAI TOXICITYTESTSWEREVADEINTHELASTTIFJEE(5)YEARSONANYOFTHEAPI'LICAMT SDISCHUJGES OROiARECEIVIP6 WATERINRELATIOPJ TOADISCHARGE, PROVIDETJISItifORMATICN ASAVAITACPPJEMT TOTHISAPPLICATIOMI XNOTAPPLICABLE/BELIEVED ABSENTPRESENT/DATA ISATTACHEDNOTAPPLICABLE APPLICABLE/SEE ATTACHEDK.IFACONTRACTIABCRATORY ORCONSULTIPJG FIRMPERFORMED ANYOFTHEAVLAYSESRECUIREDBYTHISAPPLICATION PROVIDETHENAMEANDAXRESSOFEACHLABORATCRY ORFIRMAMDTHEANIJLYSES PERFORMED ASA'IATTACPMEMT OFTHISAPPLICATIOMI XPJOTAPPLICABLE APPLICABLE/SEE ATTACHEDLIDOYOUDISCHARGE ANYOTHERTOXICORINJURIOUS CHEMICALSUBSTANCES PJOTLISTEDINTABLESIVPAGEIIAP4)IIATPIPJXJ%VAPN;ES~A,lcvES,THENIDENTlcYTHECHEMICALSUBSTANCES ANDESTIMATETHEFINALEFFLUENTCONCENTRATICPJS ~SQUITTHISINFCRMATIONASANATTACPMEMT TOTHISAPPLICATIGNIXmfAPPLICABLE APPLICABLE/SEE ATTACHED*Pesticide dataisnotrequired; however,itisprovided. I'STRCGT!".S =RG""PEEP:/7SEC-':Ii!%PcIDc&4!7o.-.("Bs(~fora'cnC1ssteel!>c cut(all-ischa,"in"tct,"esurfaceaters.c=cu!.'4~'BEp!"InE20KA~-=..-""FI!ISFC?'~.!EFERSIITGvitBER2g22=RllOCII7+EFCOIITPAGEOFYOCoE>oIRII4"fthisisanewornotprevious! verh(ttecfac!I(tv,thenleaveb!Bnxanca1urberwiiIbeasslcned. eBete"-"ecv-fa!I"'.macr(1ThespaceCV.:ec!CrBach"aceotSect)en','.-~eachI"dividual dlscnarce pointase"gratesetIT=i!5*ATEtvcuhsvB~'O.mcleSUPS'tanT la!Iincent(cai CvtfalIs,vouavrBIBstPermission lcmvcurperm(=inCauTCCrityTOsamplea1danalvzeonlyonecuttal)ahcsubmittheresultsc'.heanaivsisforothersubstantially identical outfalls. ifyour,ecuest Isgrantedby-1eperilttlng authority, onaseparatesneetat.achedtotheapplication formidentifywhichoutfalIyoudidtest,ancdose,ibewnvtheoutfallswnichyoud!c-ot,estaresubstantial lvIdentical totheoutfalI<<n(Ch)PudidTBSPC.sncCO"FRPartI2.2I(g)(B), Frlcav,-"I,!323,rcvldes'raimall=.siness=xemoticn 'r"-1therepelt!rgcf-.antltatlve ..atafororganictoxicpollutants ancoxlcpollutants asrecuiredby"arl22.21<g)(7)(il)(A) orI22.2((c)(7)(lii)<A). thesepartsareself-explanatcry ancconotrequirefurtnerinstructlchs. Slmolvgothrcucneachpar,.and"."asindicated. S=everai!nduStrlal CategorieS CCS.csateCCrleS havebeenBXempTBC'r~S"bml--I"CCataCr,CertainGG/VSFwaetlonS 0"FRpart'!2~yo(.BB,llc.".-',T"'.av,'or!i!,;BBT,'.aTes:,",s".3)..Bvlewt"efollcwlnolisttoceternlrewhethervcurfacilitycue!i'ies --peexe,ot'rcmrecon.IncG"/"S',Gashrcmatocraohv/ "assSpectroscopy) Fract(ons. M/.'-'SFree.icn.est(noancRepcrtlrc Exemptions .extileM!IIsIndustry-Al!fourX/ISSCrganiCftaCTIO1S I"xheGreige"illSSuCCategcry. -Pesticide fractionInallornersupartsofthisIndustry. Orea!In!noandOresslncIndustry-volatile. base/neutral, and"estlc':e fractions intheBaseanopreclcspetalssubcategory. -AlltaurGC/!4SOrgan(CfraCTICnS IailOtherSuPCateccrieS Ofth(SiwCuStrV. GumandMoodChemicals Industry-Pesticide fractionintheTallOllRosinSubcategory andtheRosinBasedDerivatives Subcategory. -Pesticide andbase/neutral fractions inallothersubcatecories ofthisindustry. PulpandPaperIndustryPesticide fraCtiOninPapergrade SulfiteSubcatecoriBS (Subparts JandU).-Base/neutral andpesticide fractions inoeinksuboartQ,oissolvinc KraftsuboartF.andPaperboard fromMastePaperSubpartE.".olatiicebase/neutral, Castle(de ractionslntheBcTBleacnedKraftsuboartu.semI-chem(ca) suboarts8andc,andNonintegrateo-Fine PapersSuboartR.Acid,base/neutral. andpest(cide fractions inFineBleachedKraftSuboarti.oissolving SulfitePulpSubpartK,Ground-woodFinePapersSubpart0,I(arketBleachedKraftSubpart0,Tissuefrom'uastepaper SuboartT,andNonintegrated TissuePapersSuboartS.SteamElectricPowerPlantIndustry-Base/neutral fractionIntheonce-Through coolingMater,FlyAsh.andBottomAshTransport Materprocesswastestreams. 38 SEEINSTRUCTIONS ONREVERSESIDESECTIONIINUMBER~MI0005827(3HFkLIU'R9USETHISDATASHEET0RECCRDINFO'"ATION ASREQUIREDltl:(CHECKAPPI(SPRIAT BOXFQRWHICHIIIFOR"ATICN THISDATASHEETREP"ESSITS ~'RITICAL'lIATERIALS TOXICOLLUTANTS SECTI(XIlliITEN(I-E~GROItlDWATER DISCHARGE I!<FOPAATIO!t(PAGE55)X'ECTIQIIleITC~O.PRICRITYIPOLutTA'<TS INSIIIFACEWATERDISCH((RGE (PAGE57)D3.3~BELQH:cRIilcALNATERIALs (TABLEIv)ItlsURFAcEwATstDlscHARGE (PAGE8)~IZARDOUSUSSTANCES INDISCHARGE 3~LISTA'YCRITICA'"ATERIAL (TABLEIVPt<'AE6)teOTADDRESSED ItlSECTIQIIIITEYIRKIQRITYA~XUTA'ITSWHICHYOUICIQ(tORHAVEREASQIToBELIEVETOBEPRESBITINTHEDISCHARGE ~SFEREVERSESIDEOFTHISPAGEFCRFUI(ETHER DIRECTIQ5 eNOTAPPLICABLE XAPPLICABLE (SEEBELOw)(1(eAeI!A<<EQFCRITICALPATERIALORPRICRITYPOLUJTANT BeAVERAGECQICENTRATIONI SA<<ZLETYPE;tTOFe(VIALYSES

• Hydrazine 00302012!PIITCODEGM'PLETYPEi7OFAIAIYSFSCe.<<AXECQJCSiiRATION AlePASSA.'A"ECFCRITIC'L<<ATERIALORPRIORITYPO(J.VTATIT WITCODEIPNTCODEK((JCe(B.AVERAGECQKEIITRATIQI; SA"PLE(YPEPi(OFA!IALYSES C.FAXItlttCQXBT((AT IQlA'Dt"ASSWITCCQE~GTYPEOFANALYSESLJWITCODEWITCOBENITSCODEMg/IUg<I/DAYDAYA(P(ETYPEGRAB24HR.COMRA,;N;EOFCRITICALt(ATERIAL CRPRICRITYPOL((~TAt<T'9.AVERAGECQCENIRATIOtV SA".PLETYPES'"CFAtIALYEES CpI'AXItltt COtlCEtm!ATICtt A'(Di<<ASSA.;u(<<ZOFCRITICALPATERIALCRPRIORITYPOLLIITAtIT 3.AVERAGECveiCE,ITPATIQN Se<<"PLETYPEI(/OF/L,'IALYS SC.<<AXItlPICQJCBA'RAT IQIA'4)PASS'IAECFCRITICALuATERI>>CR-"RIORITYPCLLVTAlii 3.AVERAGECQICSITRATIQI; BAFLE(<PE;"OFA'NLYSESC.<<AXI~PICQICE.'iTPATICtt "DPASSA.IIA<<EOFCRITICALNATERIALCRPGIICRIIY PCILVTA!Ii 3~AVERAGECQICSITPAT ION!SA<<PLETYPE;iiC(:A'IALYSES C.<<AXIS'ltt'CQICEIITPATIQI ANDi<<ASSle~'!APECFCRITICAL<<ATERIALCRP>IQRITYPQLLVTAtIT eAVF4GECQltCEtt((ATIQlt S'<<PLETYPE:e:CFA'IALYSES C,<<AXItlttCCICEINPAT IQIAD<<ASSUIITCODESA<<PLETYPEFOFAt!ALYSES LJWliCODEWITCODELJ~~LJWITCCDEVVPLETYPEttQFAtIALYSES UtlliCODEWITCCCELJ~~~LJWITCODESA<<<PLETYPE=.OFA!IALYSES et<ITCODEWITCODEQIITCODES'PLEIYPEv'FANALYSESQIITCODEWITCOCELJJ;ITCCQESA(PLEi<PE<<QFAt<ALYSES LJWITCODEWliCODEA:IA<<EQFCRITICALl<<ATERIAL CR""RIORITY POLL(JTP(tti BeAVEPACmCOAICDANRATION; SA<<EGLE(YPE;tIOFAtlALYSES C~<<AXIS'It<

CUE'Pi&TIQI AY<<)X(ASSWITCODESA<<PLETYPERTOFA'IALYSES QNTCODEWITCCOELJ'~~LJ~~~LlADDITIONAL PAGESCFTHISIiI7AREATTACHEDFORT((ReSTCFTHECRITICAL6YES<<ATERIALS At<D/ORPRICRITYKAL(JTA%'S REQUIREDTOBEREPORTED( EIa*Hydrazine isexpectedtobepresentindischarge butsmallquantities maybefoundinthesteamgenerators butwouldnotbeexpectedtofoundintheactualdischarge flowtoOutfalls001or002. 'ENERALCHEIVIISTRY RESULTSClientSampleID:OUTFALLOOS-U/2SLOWDOWNLALBatchID(s):126im,128im.201imDateCollected: 01-31-94Matrix:waterDateReceived: 02-01-94PO¹69095-040-3N Constltuent -'ethod-'esult'-.,;,"Rep'ortlng;:,.- 'Data-Detection UmitQualifier(s) 'Date-AnalzedLALSamleIDFluoride, inmILBromide.inmILNitrite-Nitrate-Nitrogen, inmILSulfateinmILTotalCsnide,inmILColor\TotalPhenolics. inmILSulfideinmILSulfite,inmIL340.2300.0353.2300.0335.2110.3420.1376.1377.1<0.15<0.050<0.0500.12<0.020<5.0<0.15<1.01.20.150.0500.0500.0590.0205.00.151.01.003-02-94L1175-102-17-94L1175-402-11-94L1175-503-05-94L1175-402-07-94L1175-602-01-94L1175-102-08-94L1175-702-03-94L1175-102-01-94L1175-2Comments:

IVIETALSRESULTSClientSampleID:OUTFALLOOB-U/2BLOWDOWNLALBatchID(s):126imDateCollected: 01-31-94DateReceived: 02-01-94Matrix:waterPO469096-040-3N Constltuenta AluminumAntimonArsenicBariumBeriliumBoronCadmiumChromiumCobaltCoerIronLeadManesiumMananeseMercurMolbdenumNickelPhoshorusSeleniumSilverStrontium ThalliumTinTitaniumUraniumVanadiumZincMethod60106010706060106010601060106010601060106010742160106010747060106010601077406010'010784160106010602060106010Concentration lmIL)<0.20<0.060<0.010<0.20<0.005<0.20<0.005<0.010<0.050<0.0250.15<0.003<5.0<0.015<0.0002<0.067<0.040<0.050<0.005<0.010<0.10<0.010<0.20<0.10<0.001<0.050<0.020Reporting Detection LimitImIL)0.200.0600.0100.200.0050.200.0050.0100.0500.0250.100.0035.00.0150.00020.0670.0400.0500.0050.0100.100.0100.200.100.0010.0500.020Data~Qualifier(a) Date'nal@ed02-22-9402-22-9402-20-9402-22-9402-22-9402-22-9402-22-9402-22-9402-22-9402-22-9402-22-9402-23-9402-22-9402-22-9402-09-9402-22-9402-22-9402-22-9402-25-9402-22-9402-22-9402-28-9402-22-9402-22-9403-07-9402-22-9402-22-94LALSamIeIDL1175-17L1175-17L1175-17L1175-17L1175-17L1175.17L1175-17L1175-17L1175-17L1175-17L1175-17L1175-17L1175-17L1175.17L1175-17L1175-17L1175-17L1175-17L1175-17L1175-17L1175-17L1175-17L1175-17L1175-17L1175-17L1175-17L1175-17Comments: VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260Page1of2lienmIID:TFALLB-BLWDWNDateCollected: 31-JAN-94 Matrix:WATERAniiIBh¹:244-2-1QCBatchID:020494-8260-C1 LALmIID:117-2DateReceived: 01-FEB-94 DateAnalzed:04-FEB-94 DilinFr:1SURROGATE RECOVERY12-Dirh-4Tln-4-Bromofluorobenzene 14106QCLimits7-11486-115Constituent Chloromethane VinIhlriBrmmhnChloroethane Trichlorofluoro methaneAen11-DihlrhCarbonDisulfide MethleneChloridern-12-Dihlr hnVinIA11-Dichloroethane 2-Butanone i-12-Dihlrhnhlrfrm111-Trichloroethane CarbonTetrachloride 12-DihlrhBnznTrichloroethene TCE12-Dichioro roanBrmihlrmhn2-hlrhIVinIEhr4-Methl-2-entanonecis-13-Dichloro roeneTInrn-1-Dihlrrn2-Hexanone 112-Trichloroethane Tetrachloroethene PCEConcentration IL<5<5<5<5<5<10<5<5<5<5<2<10<5<10<5Reporting Detection LimitIL101010DataQualifier sLOCKHEEDAiVALYTICAL SERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260Page2of2ClientSamIeID:OUTFALLOOB-U/2BLOWDOWNLALSamfeID:L1175-20nInDirmhlrmhnChlorobenzene EthIbenzenem-Xln-XInStreneBromoform 1122-Trhlrhn1-Dihlrzn14-Dichlorobenzene 12-Dichlorobenzene Concentration L<5<5<5<5<5<5Reporting Detection LimitILDalifirsLOCKHEEDAIVALYTICAL SERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260TENTATIVELY IDENTIFIED COMPOUNDS ClientSampleID:OUTFALLOOB-U/2BLOWDOWNDateCollected: 314AN-94DateReceived: 01-FEB-94 Matrix:WATERAnalytical Batch:020494-8260-C1 QCBatchID:020494-8260-C1 LALSampleID:L1175-20DateAnalyzed: 04-FEB-94 DilutionFactor:1SampleWeight:N/ANo.ofTICs:0Tentatively Identified CompoundEstimated Concentration (yg/L)Retention Time(minutes) DataQualifier(s) LOCKHEEDANALYTICAL SERVICES SEIVIIVOLATILE ORGANICANALYSISRESULTSFORGC/IVISANALYSESUSINGMETHOD8270Paelof2linmIID:TFALL8-U2BLWDWNDII:1-AN-4.Matrix:WATERAnalticalBatch¹:021094-8270-A QCBatchID:8270-SVOA-4903 LALmIID:L117-DRiv:1-FEB-4DilutionFactor:1DateExtracted: 03-FEB-94 DateAnalzed:10-FEB-94 SURROGATE RECOVERYo0Limi2-FlorohnIPhenol*de Nitrobenzene-d, 2-Fluorobi henI246-Tribromo henolp-Terphenyl-d,i 227067604121-110-9435-11443-11610-12333-141PhnIConConcentration LReporting Detection LimitLDbis2-Chloroeth Iether2-Chlorohenol1-Dihlrnn14DiIrnnBenzIalcohol12-Dichlorobenzene 2-Mhlhnli2-hlrirIhr4-MethIhenolN-Nitroso-Di-n-rolamineHhlrhNirnnIsohorone2-Nitrohenol'-Dim hIhBnziibis2-Chloroetho mehane24-Dichloro henol14-TrihlrnnNhhl4-Chloroaniline Hexachlorobutadiene 4-hlr--mhlhnl-MhInhhInHexachloroc cloentadiene <10<10<10<10<10<10<10<10<10<10<10<10<1010101010101010101010101010LOCKHEEDANALYTICAL SERVICES SEMIVOLATILE ORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270ClientSamle)D:OUTFALLOOB-U/2BLOWDOWNLALSamleID:L1175-9P2of2Constituent 4-TrihlrhnI245-Trihlrohenol2-Chlorona hthalene2-Nitroaniline DimhIhhIAnhhln26-Dinitrotoluene 3-Nitroaniline Anhhn4-DinirhnI4-NitrohenolDibenzofuran 4-DinirIDihIhhI4-ChlorohenI-henIeherFluorene4-Nirnilin4-Dinir--mhIhnIN-Nitrosodi henlamine4-BromohenI-henleherHxhlrnznPnhirhnlPhenanthrene Anthracene Concentration (/L)<10<10<25<10<25<25<10<10<10<10<10<10<10Reporting Detection Limit(/L)102510252510101010101010DataQualifier(s) Di-n-IhhIFluoranhenePreneBIzIhI'-DihlBenzoaanthracene Chrsenei2-EhIhDi-n-IhBenzobfluoranthene BenzokflurantheneBnr<10<10<10<10<10<10101010101010Inn2rnDibenzahanthracene Benzohierlane<10<101010LOCKHEEDANALYTICAL SERVICES

SEMI-VOLATILE ORGANICANALYSISRESULTSC~FORANALYSESUSINGIVIETHOD8270TENTATIVELY IDENTIFIED COIVIPOUNDS ClientSampleID:OUTFALL00B-U/2BLOWDOWNLALSampleID:L1175-9DateReceived: 01-FEB-94 Matrix:WATERAnalytical Batch:021094-8270-A DateAnalyzed: 10-FEB-94 DilutionFactor:1QCBatchID:8270-SVOAP903 Tentatively Identified CompoundSubstituted Hexanedoic AcidEstimated Concentration Iyg/L)270Retention Time(minutes) 30.3DataQualifier{a) LOCKHEEDANALYTICAL SERVICES OILANDGREASEEXTRACTABLES ANALYSISRESULTSBYFT/IRUSINGMETHOD413.2ClientSamleID:OUTFALLOOB-U2BLOWDOWNLALSamleID:L1175-13DateCollected: 31-JAN-94 DRiv:1-FB-4Mrix:WATERAnalticalBatch¹:020994-413.2 DateAnalzed:09-FEB-94 DilinFr1DExr:-FEB-4QCBatchID:020894-413.2 Constituent OilandGreaseConcentration mLReporting Detection LimitmLDataQualifier(s) LOCKHEEDAItIALYTICAL SERVICES PESTICIDE .ANALYSES RESULTSBYGC/ECDUSINGMETHOD8080ClienSamleID:UTFALL0B-U2BLOWDOWNDaCIleed:31-JAN-94 DateExtracted: 07-JAN-94 Matrix:WATERAnalytical Batch¹:021294-8080-E-3 LALSmIID:L117-11DReiv:1-FEB94DateAnalzed:14-FEB-94 DilutionFactor:1QCGroupID:8080PEST/PCB5054SURROGATE REOVERY00QCLimitsTCIVIXDCB648660-15060-150A-BHB-BHCG-BHCConstituent Concentration L<0.05<0.05Reporting Detection LimitL0.050.05DataQualifierls) D-BHCHEPTAHLRALDRINHEPTACHLOR EPOXIDEHLRDANEENDLFANIA-CHLORDANE 44'-DDE44'-DDTDIELDRINENDRINENDOSULFAN II44'-DDDENDRINALDEHYDEENDOSULFAN SULFATE'ETHOXYCHLOR TXAPHENPCB-1016PCB-1221PCB-1232PB-124PB-124PCB-1254PCB-1260TECHNICAL CHLORDANE TCMX-tetra-chloro-meta-xylene DCB-Deca-chloro-biphenyl <0.05<0.05<0.05<0.1<0.1<0.1<0.1<0.5<20.050.05.050.050.10.10.10.10.5LOCKHEEDANALYTICAL SERVICES

RADDATAREPORT(ra01)indianaMichiganPowrCo.~Bridgman,HI Organicandinorganic Contaninants (ProjectCOOK.JEMl) ClientSampleiO:OUTFALLOOB-U/2BLOSSOMLALSenile10:L1175-15KatrixtMaterDateCollected: 31-JAM-94DateReceived: 01-FEB-94 LoginMwhertL1175GrossAlphaGrossBeta23-FEB-94 GRALP/BETALAL-0060475623.FEB-94 GRALP/BETALAL.00604756-0.080.3B0.920.41.22.1pCi/LpCi/LPage2 RADDATAREPORT(ra01)IndianaHichiganPowerCo.*Bridgman,HI OrganicandInorganic Contamlnants (ProjectCOOK-JENI) Hatrix:WaterClientSampleID:OUTFALLDDB-U/2BLOWDateCollected: 31-JAN-94LALSea@leID:L1175-16DateReceived: 01-FEB-94 LoginNumber:L1175~~%'i:";":'(Cari stg't'tigj't:i.".':::::W"':N:::::.:AWII5ity'iel:; 'Igitgb;::::::::."'~ Ra-226Ra-22810.HAR-94 RA-226LAL-0073520125-FEB-94 RA-228LAL-007451990.620.030.280.370.310.65pCi/LpCi/LPage3 PHMeterCPCy-lO~CaldatedueSampleSampleTimeSample/jSampleDateCDMEnteredbyOutfallOOBgIC,J40ooPHAnalysis(LAB.079) 5.3.56)SampleC/ph(priortocorrection) 7)NH3pHcorrection 77P5.3.68))ampleresultsC/pH(aftert.7gNHCorrection) 3SampleSampleTimeSamplegSampleDateCDMEnteredby5.3.56)SampleC/ph(priortocorrection) 7)NH3pHcorrection 5.3.68)Sampleresults'C/pH(afterCorrection) 9)LAB.041SpecsVerifiedby:A(/8Rupewvieoz Review/Date ~W+IWFormpreparedby/DateFormapprovedby/Date12THPLAB.041.25s Revision1 Sample/Standard SamplejjDateTimeCDMEnteredbyOutfallOOBISg-7Determination ofTotalChlorine(Lab170)~~/q~/instrument CPC/jTechnician hl)Absorbance 6.112)Results,ppm3)Dilutions madeC.~C2MCZM4)Results,ppm(/I2*03)C511AB.DdlSpecsVerifiedby:~NRSupervisor Review/Date~~9I ~Formpreparedby/Date/~fŽFormapprovedby/Date12THPLAB.041-25)l Revision0 SEEINSTRUCTIONS ONREVERSESIDESECTIONIINUMBERPERMIT~i4I0005827(UIFkLrkPKR~000.MDISCHARGE LOCATIONAe~QCATIONOFDISCHARGE B~MMEcFREcEIYIttG HATER'{IEsGRQ{ttDHATER 0RNA'K0FsutFAcE<<ACeDOYCUDISCHARGE SEASQliALLY: {IFNO)CQVTltAIE TOE)MECH)IGANYEStaD,IFYES)LISTDISCHARGE PERIODSNAMOe/DAY./DAY~6e,~NWe,~e-DII0II~06,-0)lL006Ie)IDE~19)ISCHEDULEFLOWRATEWASTEWATER CONTACTCOOLING:NONCONTACT COOLINGPROCESSSANITARYSTORMWATER U~NIT0DIMGY2MGD3GPDITEMEsLAtrDAPPLICATIONRATEFeTYPEQFWASTEWATER DISCHARGE G~DISCHARGE ~(YEARLYAVERAGE)Irt./HR.HRe/DAYIN,/WK,ELJ~H~~wKIIIAwASTEIIATER TYPECOCE.LJHQ{Frs/DAY ~24Dsv/TeesL5365IHe0ISCM6RGEFLOWRATETOTALYEARLY**Basedonall-timedailymaximumtimesDAILYMIttIPut 365DAILYt'AXltttt 5.11)00.014UNITCODEL4~2~2JsMAXIISHDESIGVDISCHARGE FLOWRATE,AsCOYOUUSEWATERTREATMENT ADDITIVES TOTREATYQ{RDISCHARGE? (IFtrocQNTItt{E ToITEM3)BeNAMEFgtCTIQrte ANDCHEMICAL~SITIONOFTIIESEACOITlVEST DESIG'I0YES0.043~PIeIHEt)AXIts{M DISCHARGE flOWRATETOBEAUIHQRIZEDIttPERIITTpp43UNITRODEWATERTREATMENT ADDITIVES CeNA%ArtDADDRESSOFMAIAFACTLT)ERS QFlHESEADDITIVES ~NAUNITSCODE1Mg/I2UgzlDeXPECTEDDISCHARGE CCttCENIRATIQrt OFAITIITIVESs ADDITIVENAMENANAMINIM{f1UNITSAVERAGEutITSMAXIt%ttUNITSCODECODECODEACDITIVEtQ%ADDITIVEt5%E,DOYetTREATTHEDISCHARGE )sREMOVEADDITIVES? NALJLJ:~LJ:~LJYESF.WHA'TISTHERP9OVALEFFICIENCY AVDDISCHARGE FREQUENCY? NAADDITIVEtA%ADDITIVENAMEADDITIVEN6ME~REPCVALMRSe/DAYDAYS/WK~LJG,ASArtATTACHTENT TOTHISAPPLICATIQtt PROVIDESPECIFIC."Ast)ALIAS CRAQUATICTOXICOLOGICAL DATACRREFERBICE WMICHAREAVAILABLE ANDINFORMATICN CNTHERATEOFDEGRADATION OFTHEPRODUCTSFCREACHAll!TIVENA '~~4<<3~II50ea5IIe<<th4o>>t<<4AI'll~I~'nt"I~--tX-----'"--"wE"'ll'"""0"'IT}"vr"nEkIrllt'9,4,"'I,tInhv,514}'IA}.K40f)'er<<II4essicr40~45'I5II)tOut4}'lldl)5<<f'3>>IIA}<<4Set~'-I.:4;.}r-Ar-t I-a3!--'Cn.1.}r-e3+0I...lecticn.lawn.Snaranae~)ce4>>4~tI'<<eterIlfJh4}Tat1Sr~Aflt}04R>>etJhI'f0aiscn}"h5h$455"el')isfes~.:)t,scnarce cerlcasV~CP~e)~eacfi}.itf:.)RS551.0'laeCec}eIJseaIr~er5I.Cnestethaur,naurSOeranv,)0.-0105Derweak.~1cic}e--4<<Ice0<<nsteweter -:co,Ic-}t'000 fr--"lscutfelI.Ttet-.h1e<<estewdter -vcececaaiven~rTneleft-ertin.")ro-hen-neccaemevco<<aciIC}}fe. JI~I)IacrI)I4<<ClII~<<5h}+ns<<A<<5At~5'IJ~Ih<<avs'Jt~-"<<}5---"--'"4'ac-4-.>><<r}-es<<s4-es-ea=e'et-I"it"0"e"fvoni<<-4.eft<<eralnf,0)r}TeI<<JnlsI')f'e}r:vrhr--'l:ttneel~1scer"ny.F-.hflc"s-er"}v.)'4q5ateh4>>~lnevo0'5<<ftl4<<9I-"e'se:~Svc1)'IC>>rate<<tif"".-'}CeanectJ}l',it"estrlctlcn cntneflewbutwill'IAIent!'titS.}Isa,*1en-ne'CntfIVCeretlca}5CrtS}rereuieweC=;ramollanae StaffffnVnewCr'<<tro<<Sea uSeSmiant"eVe}>>Curreaf)t--5I}CllltV. beTneflewrateuseatoaevelacltwill"eiaTr~-0Cetermine -""fiaa"4'53'-III-etf'"-)III'.4fa"<<TC-"Aelont35At'I->>ef)teao<<4sfstotlfIw,5ta}1etffhlTe,.at}Trent5IstemITEV2}RTETCERTIJEfIT rDITISEE44~r4'4IIl5"fa1<<to~~;.CTIC. )nttbemiC}f: 03I."050~I"ASISeC~4e~rhCIh3~~4<<10lr4I"hf5h~f'lsIJset~'I~~~,III))Vefh4hII"I5'I5"Cah1$flPI5S~IS5(4J.,<<r=h)a')0';Ah)I'ol)~',}f'<<gsA<<e}4>>,a-e"4"h""V}f4'IC5<<CV-~'J<<I5l<<eAIAI<<)I4I4<<esto<<<<tot IhI5\hr<<IIJAI(0f6~I'4I'I14hsrec'eSTealI"5grl.'armetlan)$11T-}el!0}VAsu,%.I}CII0I0rhr>>ene}<<lhntJtf~)2 SEEINSTRUCTIONS ONREVERSESIDESECTIONIIPERMIT~MT.0005827NUMBER[IJII'M.IlfBEI(OFPDOCESSOC)ITRIBUTI[JG TQTHEDISCHARGE rROU%TYIISQUTFAU-~'DSICCCCE40~0>0DANN~4i9IIB=ROCESSSA-ED[LE(YEARLYAYRE)IOUS/DAY~24I"Avs/vePROCESSSTREAMSONTRIBUTING 'OOUTFALLDISCHARGE VIV9Or00C~=ROCESSWASTEYIATER FLOWRATEBasis:1993actualdatasubmitted onDMRsDePROCESSF0')CTIONRATETOTALYEARLYDAlLYMININNDAILYe<<AXINTI0.003~*II0,~60.002~6*utITS/TIMEIIIIIIIPOUNDS2GALLONS3CUBICYARDS4TONS5MGY6MGO7GPDVIVI0010VICC4LA.iVVZOFPDQCESSCONTRIBUTING TOTHEDISCHARGE DSQUGHTri[SOUTFALL~YT)SICC<<EB.PROCESS~(YEARLYAVERAGE)CePROCESS>IASTEWATER FLOWRATEDPROCESSFPODUCTIOtt RATEA.:VINEOFPRXESSCOtt[RIBUT[t)G TOTHEDISCHARGE TH[OUGHTHISOUTFALLA'IDSICCCCEBePROCESSSO'X)LE(YEARLYAVERAGE)C.PROCESSlQSTEYIATER FU)WRATEDePROCESSPPODUCTIOtt RATEIYADS/IDY ~DAYS/YSAII TOTAI.YEARLYDAILYMttl[NHDAILYNAXINNHADS/DAY~DAYS/VSAA TOTALYEARLYDAILYMININHDAILYPAXINTIUN[TS/TIMEIHOUR2OAY3WEEKMONTH5YEARVlVILt~QQ.AeNAWIEOFPROCESSCOIITRIBUT[tlG TOTHEDISCHARGE THAt&SICCOPEBPROCESSSC~DE(YEARLYAVERAGE)CePROCESSWASTEWATER FLOWRATE~'DAV~DAVS/VSAA TOTALYEARLYDAILYMININTILt[ITCODED.PROCESSPDQCUCTIQII RATEAeIW%OFPPQCESSCQt[IRIBUT[NG TOTHEDISCHARGE NgIlFAOUGHTHISOUTFALLAlIDSICCQCEB.PROCESSSOIEDRE(YEARLYAVGAS/iE) C.PROCESSWASTEIIATER FLOWRATEDePROCESSPRODUCTIOttRATEDAILY4'AX[t~IIQURS/DAY TOTALYEARLYDAtLY;I[NINADAILYWXINMUtttTS/TIPEIIIDAIS/YDYI UNITwX~IIUNITS/TIPE*Heatingboilerwasoutofserviceformaintenance duringmostof1993.33 a/<<<<Re'alar99"SSSI>5*n!C"r8'I-,.=gy.-.-=-~="==i"-.=:=..==n=.-.!It',.c-"=-.-'l=c=tI.';0:;I HEF;"CRITPtGE-".vCNC>PI!III'G '"Is'!.-Rwcrot-ov.st.3rnl--~c'sciltv,-Rn'eaveIsn~acanu>><<ce*ill"0assianec. cl~e5ace,vlcecRs59otPctclIoatIualc3.cecln5oelatesor'--5-5--O':IieC>>u-Ir55~~~<<~"pY(>>--9--9-eprocess<<n'C.Cc--"'c.-es "-i!s:Iscrs-co. -':-rcvl:e-9c-."Rr-.'.ccce-clca-0"9F45.I.Cyerscecrace!3ic-45<<io'--ourscorcsvR<<cccvs-:er-voa" aroviaet"eprocess<<aste~ater f!ourateInfornation asrecuesteo baseoonyourlast12..ontnsofoperations. RefertonitCOaeoiveninteeloftnaroinfortneacprOoriate flowunits~.=ocessproauctlor. Rate-certaincer"i;ti>>ltations navcecaseacncrccuctlcn rates."9crcauctlcn ra~Osuseao39;OrIr+CO>>>>',-'>ICS5naiICR>>R<<>>>SR--~C CV3rROScnaCle RaSureC'evealC"CauCC'C<< Cft"eIOCillV.5'CnCS"e'"n-"-"-~"~"-3oar"-o-"--"'~-->>"-"---9-'-"os--'"~--etic"s"9"earscr:--Rr-Rsscnac.o -9)sureass->>ocscc.':cle..=.-".a.R. -e:cr'I'osa~c9cta3."4<<S'r<<RS"r<<4>>ISCnar<<>>53~"'5aII954<<0)<<a\~~.<<'OC9>><<O5g5\\~!54\h*~9ri3$!95h]91,)3i>>f5f SEEINSTRUCTIONS ONREVERSESIDESECTIONIINUMBERPERMITMZ0005827>>BENI4GROUNDWATER ,DISCHARGE INFORMATION QJIFAU.NKRAeISIHEDISCHARG( FROMTHISCUTFALL3$REC1EDTOTHeGRONOORGRoutGWATERS7 4IFt>>O<<Ca>>TIMUEToIT&>>u)B.WASAHYDRQGEOLQGICAL STUDYORITSEQUIVALB>>T BEENPERFORMED ORISIHERESIFFICIEMT CURRENTHYDROGEOLOGICAL It<<FOIT>>ATIa>> AVAIIJ<<BLE ASREQUIREDBY~WATERRESOURCES cat>>tssla>> PART22GR>>xl>>owATER RULEScFAUGUsTlt>>e1%0R~5252D)7(PAGEQ)F0RIHISEXISTlt>>S ORPROPOSEDDISCHARGE! IFYESATTACHACOPYCFIHEREPORT.CAREYQUREQUESTIttl AttEXP'PTICN FRCMSUBMITTIt>>G AHYDROGEOLOGICAL REPORTut>>QERR>>AER.323<<22(I7 Q(PAGE$A)ORFRCMGR>>Xl>>DWATER MONIICRIt>>G I)EQU1REMB>>TS CiDERRULERR~23e(5)(PAGELg)OFTHEPART22R>>LESeIF'ESATTACHDQC>>l>>ENTS M)EXPIANATla>> ToDB)ot>>STRAIE THATYOURDISCHARGE Wa)LDQUALIFYFOREXBPlONeDeAREYouREQUEsTIt6 4vARtAt>>cE FRcMRULE323.2$)05(PAGE5)(NQNDEGRADATIQN) QFIHEwATERREsouRcEs cotHIsslcN PART22GRout>>DHAIER RuLEs!IFYEs,ATTAcHsucHDOC>>1'Et>>TS ASNECESSARY TODEM(INSTRAIE THENEEDFORAVARIAI>>CE INTEFMSOFTteCRITERIASPECIFIED INRIAL525Z10(PAGE>>I>>t)CFTHEPARTZdRULEseNA~00CYESCI':<<$'let>>O$>>e<<EeI,ISTAI,LCHEMICALSLBSTANCES WHICHAREINMICHIGAN'S CRITICAL<<MATERIALS REGISTERTABLEIV'>>PAGED)At>>D/cRU.s.EPAsPRI0RITYPQU.UTANT LlsfTABLEv(PAGE1)0RANY0THERSUBSTANcES WHICHAREORMAYBECCt%IIL>>URIa)s TOTHEDESIGNTED USESOFTHEGSXl>>DIETER ORTOTHEPUBLICH~THTHATAREDISCHARGED OREXPECTEDTOBEDISCHARGED ToTHEGRCu>>DWATER>Y IHISFACILITY. ESTIMATEIHEFttujLEFFWEMTCONCB>>IRATION At>>DRECORDALLDATAINtTEM/OFSECTIONitINTHISBOO)LET~THEAPPLIGWTMAYBEREQUIREDTODOADDITICt>>AL WASTEANALYSES. NOTAPPLICABLE/BELIEVED ABSB>>TNAPRESENT<<DATAPROVIDEDINITEM7ITEM5EXPECTEDWASTEWATER CHARAC-TERISTICS CODE1Mg/I2Ug/I3COUNTS/100mt4S.U.5F6LBS/DAYAeDISCHARGE CHARACTERISTICS COD(CHEMICAL OXYGB>>DEMAt>>D)TOC(TOTALORGA<<MICCARBa>>)AftSMIANIIROGEM(ASN)TOTALSUSPENDED SOLIDSToTALptcspHQRus (Asp)TOTALRESIDUALCH.CRINEDISSOLVED OXYGENPHMlt>>FECALCOLIFORMRACTERtAIEMPERAIURE (S>>ll4ER) TEMPERATURE (WINIER)BOD5(FtVEDAYBIOCHEHICAL OXYGEttDP'At>>D)Cot>>CEMIRAT Ia>>~~LJ~~LJ~~LJll>>ITSCODE$$>>At>>ALYSES ~LETYPECODE~3~5~5B.OIHERWASTEWATER Ct>>ARACIER 1STICSSAMPLEZXBF1GRAB224HOURCOMPOSITE 0IL)t,GREASELJILJLJLJ~LJLJLJLJ~SEEATTACHEDSHEETSFORANALYSISDTAe<<>>ECUIRED ItSORMATIa>> FORSURFACEWATERDISCHARGESe

• Basis:1993actualdatasubmitted onDMRS

~5.,v~4Sg<<>>PPiIi(4lh}irt=(S3",ngisCo)vires'"o.!~c<<.".'!3)ac'(-cu(4'I'cbarcic"atther'prof.nc}(ate, 5cr=E<<izI7'.""BECIhTHEBOXATI'o}EPCFT}}ISrCR!I.>EPE&IT'."J'ABER "A}lBE,DUI(0O'ITHE'".is~S)-e<<)hotb-OVicuslv cer,It!ed '<<oil}tv, !he<<leaveCI)nkanoarr."<<ber<<il(sr')ce<<arers.tF-Ct(TPAGECFv00RExoIRii<<4 beasstered.a-45()I.<<)or'43))COZr)v:C<<C(C<<e)c<<!)ce 'eo:,on}I=c<<>>cnI"dividual !Isc)rcooctn.a!eon}nto5(}-'crrs'Ie.s-)rc."-.stce.II!Ieccut.I'o~i~gi\~iii~<<g7ii'I~i~~Ichf~~'iIC}i)i'"e)ool:cant shall!Cdrosso)c"ese cartsI'ectscharce !A;-"Isout'nrl'5-=tbe:-curcwator. Evi5I".(c-EVPEcTED;FcP 'E(rIscHARBF) a)STE'r}ATEP cuARAcTEc'sT)cs 0"0'.0'4'ATEo cP40RFAcc'((ATECBtsciARriE(0i0TIt)I.UDEA.Theaoolicant shallre)ortavnllab(e discharge cata(realcataforexistincdischarge orexoecteddataforabrooosecdischarge) !crr}ebarn.eters as1}sted.iheseonraceters shatIbeccresseoforeitherasurfacewaterdiscr.arne orasnooroorlatercr!-,rcurchater C'sonar"e,-craSSIstnnco '"cater(,lnirc aoorcoriate ara"e-arS acrourC}rater CISCnarce abblicnnt .avcontact-"e'c<<aterCuntI,v'.,3ten,oe<<ItsSecticnortnea)ore)r:ate:rcu<<exeter .unl1"',(Ision'5Ci5,rlcto.f.'coiIiC)rl~5!It11'e5)ala'("eCOOstasCr')inr(q)c<<<<OOCr eOCOCntn,Saei,(ICrrtetertaf'CI<<$f'Irlr";!)Ct'nl}}5!I.rface<<ato":i!eh)rte. "-e!"<<}Ic)"-:5-rhcr".anr'-)tl.e Sa.afcrencn))rareter iden!Iftedbva<<)s<<er!w.",e)oo}5)".av~..*over,ncos;-"nt-"e.o-r->>,-c)t<<)r'ecrcreo,neserecu}r'Oc oarvetors oe<<a}vec..uc;, e).ost-;stbe3~boor-ec b()cecunte)t'5"aie. ~!ReS.c)rocuest)<<!7achrhont-".this)Colicntlcn.))-a:s)(n'}acre '>>t"erc)r~~to<<5 -Ot1'5-OC)oo.e'-A.Z5<<.er)),-5)'"'S)coilcatlcn -"eaoolicant 5<<auldrecrthatzat)Intre<<iinn<<scaCeS Orcviced:<<rniS Cart.'TES,;"I-codes'oars.oters reocrtaclnoortsA)rdBcanbofor.rccntheie'tnanosicecftaisfcf<<hsnO}a$>)II"eused-".)CalVZO'CrO"~te4)era-urn, tc-)It"e"Cr5~~eslcualC",.IC~ine, OiI)nd1:reaae~and'4)}<<',I)4r)Ze<<ate,.is)rCeesst"Or("4werc.5).'4.Voe)noiVSOSa,eavniIale~See"SsafV(once4B)'ceelirI-ionof,raosan)le.3.Ez-hou,c"oosltesar}alessnailbeusedtoann}vzefcrT>tat9&4,000~.cc,,~onia '.Itrogon, nndTotalsusoenced SolidsIrSurface<<aterClscnbrro unlessother;recueoCV-Sn oletvpeanalvsesareavnllable. SeeGlossary()ace48)'"rCe!Initicr. CfCt"OOStte Sn-.ble.A<<Cli}Pa<<cegrrai)r45<<*5OPonsra4y)r4Ilil'ivrcr'."qf(i4<<','I)fr'mreCciar;ts~<<n<<4,aar(t,q<<rlritatina"i'ustOCOVSuatf'OCtlro .eaveracele(e}c.'beboll.(tant(s) orosontInvourIntnxo>>nter. '.CQESeculaticns Olfe}(netltrhttaticns cnlvin:er-)<<!-t:.Stances.: ca~nst,).4 voure')Ib,:'l-v, e)cr--ne!Veraco cftr'erasut5of)halvsesonyour4(<<nti<<~4)vhd443445'}44+)'I4isan<<ac),)<<C)54afate$4hIhai54h<<en<<<<h1<<LO*era<<5'i*4'(<<i}ra<<*i}Ce5Latet!44<<3$~4i1'\iva<<4~agv*fi1aie,e<<$,44vt4)taltr(..-<<sto<<ater

• g)c",usedc<<Iv-:-<<eextent"!t-.ec;.--~tart'5nct<<hooved.)

~<<<<I)"ia<<ah"<i'"4<<<<esp<<~<<tJ}<<i14'iI)<<5e'4%i<<(I~il<<<<)r4+}~ai}I()43hh~<<<<I}4<<~,O<<IV<<t)5-,4.4-<<)---C!4<<e"i}4IOi'4I4<<t<<llI,'<<~(hiI~~4~~~4res-*r%344)a5eenr<<Cai,,4}$4""Cest SEEINSTRUCTIONS ONREVERSESIDESECTlONlINUMBER~MI0005827PERMITTEM6PRIORITYPOLLUTANTS ANDADDITIONAL INFORMATION FORSURFACEWATERDISCHARGE ONLYOlTF/ILLNEFBTHEFQUMAIMGREQUESTED ItÃGIL4ATIGtl ~4'cA"DRESSED ~<vSIRFACE'<<ATERDISCHARGERS. BZEI;eDJVSEDISCHARGERS c~PROVIDEBIPECTEDVALVESFORTHEQUANTITATIVE AIJDQUALITATIVE ItiFOJLeAT IGttREQUESTED BELQWeA.ISTnISFACILITYAPR!ueARYI'etXJSTRY? (REFERTOTABLEIAPAPE4+1(IFlf),GOTOE)(tFYES,GOTGB)BI:iDICATE TYPEQFPRIMARYIIISTRYASLISTEDIMTABLEIAPJJiEQeCG;titty)E WITHC.)Ce0ESTHISOUTFALLDISCHARGE CGtffAie4 J4IYPROCESSWASTEWATER? flFtJGeGGTOE)(IFYES.GOTO0)DINDICATEHHICHGC/PSFRACTIONS FJJSTBETESTEDFOR~<REFERTOTABLEIAP4iE4~1IJQIE)cQREACHGC/f'8FRACTIONCHECKEDeEACHSPECIFICORGANICTOXICPOLLUTANT WITHlttEACHFRACTIGtt ~BEAJJALYZED FOR(SEETABcIIAPAGE42,INADDITIOtte ALLPRIMARYIQJSTRYAPPLICAtftS WITHAPROCESSWASTEWATER DISCHARGE e~PROVIDEQUAJJTITATIVE DATAFCREACHTOXICPOLLUTANT ltlTABLE111APAI<99~RECORDALLDATAetFORMSPROVIDED(ITG47)IltTHISBQQKLETe(CONTINJE WITHE-KBELOW)~00CQXYESSTMELJECJ)PWRXYEStaVOLATILEBASE/I'e'FUTRAL XACIDPESTICIDE

• EIFJJtt)'.SURFACEWATERDISCHARGE APPLICA'ft (PRIHARYORSECCtiDARY IJIDVSTRY)e REGARDLESS GFTHETYPEOFDISCHARGE KJK)WSGRHASREASIXITOBELIEVETHATAJIYPIXLUTA'ft LISTEDINTABLEIIAANDIVAPAGES~ISDISCHVIGED FRCHAtJYIXJIFALlg THEQUANTITATIVE DATA~BEPRGVIDEDe RECORD~DATAONFCRMSPROVIDED(ITEM7)trtTHISBOOKLET.ttQTAPPLICABLE/BELIEVED ABSENTPRESBIT/DATA ISATTACHEDc,IFA4YSIJIFACEWATERDISCHARGE APPLICAtfi (PRIMARYGRSECGtJDARY ItCUSTRY),

REGARDLESS OFTYPEOF'ISCMIGEe KVJOWSORHASREASCttTOBELIEVEAIJYPOLLUTÃffS uSTEDINTABLEVAPAGE~AREDISOIARFED FRÃANYOVTCALLTHEAPPLICANT y~DESCRIBEREASQtiSFCRTHEPOILVTAtfi BEINGPRESENTANDPROVIDEANYAVAILABLE QUANTITATIVE CATAeREGQRDALLDATAQNFORMSPROVIDB)(ITE)t7)INTHISBGOKLETeNGTAPPLICABLE/BELIEVED ABSENTg,PRESENT/DATA tSATTA(BEDDG.ALLSIJIFACEWATERDISCHARGE APPLIC4JTS (PRIHARYAtfDSECCtGNRY INDUSTRIES) W)e:jGRJANUFACTVRES 2,4,5-TRICHJ)RGPHBK)XY ACETICACtD(2,4,5-t):l,4,5-TRICHLGRQPHBK)XY) PRGPANOIC ACID(SILVEX,1,45TP))DIJE)jf/L U-l2e4e5-TRICHLORGPHBWL) PHQSPteROTHIOATE (ROtfJEL)J >TRIOLHCPJEJIL (TCPJIORHEXACHJ)ROPHEteE (HCP)J(Au.DATAFORTHEPl)STBEGBiBQTEDVSItIGSTAG)ARDAttALYTICAL CAJ.IBRATIOJ PROCE"IRES) QRKJJQWSGRHASREASONTOBELIEVElHATTCDDISORHAYBEPRESENTIttTHEIRDISCHARGEe ~REPORTJXJALITATIVE DATAeGENERATED WHICH'SED ASCREENItJG PROCBXREMOT~<IBRATED WITHA4ALYTIG'4. STA'OARDSe FGR2.>e/LSe-TETRA:HLORQDIBEJJEO-P-DIOXItt (TCDDJ~RECGRDALLDATAOttFORDPROVIDED(ITFJI/)IttTHISBOQKLETe:FicESVRFACEwATERDISOIARGE APPLICAtfi gfXJSCR)ASREASONTOBELIEVEieATBIQLCGI+TOXICllYe-STS'<<EREJeADEItfIHELASTTHREE(5)YEARSgtA'h'FMiAPPLICA'll SDISCHARGES GRONARECEIVIMG WATERINRELAYICe4TOADISCHARGEi PROVIDEietISIteFGCATICM ASA4ATTAOf)Bft TO1HISAPPLIC)TIGMe K.:FACt)4TRACT LABORATORY ORCONSVLTltJG FIRMPERFORMED Ath'FTJEAteLAYSES REQUIREDBYTHiSWFLICATICNe PROVIDETHENAe%ANDADDRESSOFEAOIuBORATGRY ORFIRMANDte,EANALYSESPERFQRJ'ED ASANATTACWEtft GFTHIS*PPLICATIQMe 'DQYQUDISCHARGE Ath'THERtOXICQRIttJURIGVS CHEHICALSVBSTA4CES t)QT':)TEDlttSIVPAGeEIIAJ4)IIAleÃVAPA'ESJf/+Qelc"ESeTHENICBftlveeE"EHICA.c4!BSTANCES A'eDESTIMATEeHEFIJF4.EFFUJEJJT CCJJCEMTRATIGJJS. SVB4ITTHISFGRI'IATIeAJ ASA.'IATTAINTTGTHISAPPLICettlGM

• Pesticide dataisnotrequired; however,itisDeXtK)TJV'PLICABLE/BELIEVED ABSENTPRESENT/DATA ISATTACHEDMOTAPP'CABLE APPLICABLE/SEE ATTAOFJ)tJQTAPPLIABLE gAPPLImLciSEEATTAOIEDX~JOTAPPL'CABLE APPeLICABLciSEE ATTACHEDprovided.

"'lS"".CTICKS CRC.ttolETI",V: SECTICIIiIITEW6vis'ci,-ecires)-'c~at'cn cnaspec('Iccut(allciscnar-ino tothes'r'ace~aters.Eht=-"-=ER'IIT'.".::"-"= INTHEBOXATHE"-"=,THISECRU.THEPE?MIT,':V'ABER CA)IBEFrnNOCIITHE=p"."ITpAGECFYCUoRo(RING'!t"lsTsa"evcrnotpreviousiv Ce~lttecfocilltv,thenleaveblankendanuPer<<Il(beass(oned. En,e-ecu-falI'.erlnhespacecrcr'cec',crseenpageofSecticnI(.=oreacn'lvicua(clscnarce pointsseparatesetfiec-'cni.,-e"cr.smust=efVl~cs.-.ITEvi64.anCycu>ave-~oormoresubstantially .ncent(cai

outfalls, voumavreouestpormlsslcn fromvout'ermlttinc but"crlty to)a"O~eSncana)VZeOnlyOneOut(ail.""Supm(tthereeultSOftheanaiVSiSfOrotherSubStant(ai(V (Centi"a(

Outfal(S. vcurecuestiscrantedbytnepem(ttlno authorltv, cnaseparatesneetattecnoctc-"eacpllca-lcn foinide.rifv<nicnout,a(I,cuc(ctest,anccasercewnvtheutfalls~nlchyou<<Idnottestaresuostantia: Ivident(alto-neoutfalIxnlcnyoucictest.cOCFRpart"."I<c)(8), Fridav,-'"-I"I~tg83,provides',craSmallBusinessExeipricn xicmtnerepcrt(ng of"antitat(ve catafororganictoxicpo(lutants anctoxicpollutants asredo(redbypart122.2((q)(7)(il)(A) orl22~'l(o)(7)<i(I)(A). Thesepartsareself-explanatory anoconotreouirefurtherlnstructicns. Slnolvgo.Iicucneachcartsncc"asIndicated. Severalincus-laicategories a,.cs.:csteccr(es navebeenexemptec.ioi:submittln" catacrcar-sloTC/US"iactlcns ,'0:=ROar-'~VO(.,a8,lip.".-',C-'CSV,aprilI,)g83,'OteSI,2~and3)."eviexthefoiicxlno listtocete<tt(re xnetrervour(ac(((tvdual(!Iestobeexe.ct'romreport:nc SC/"SlgasChroatoorapnv/ uassSpecticscc=y) .Broctions. extIIe:aIIIsIncustrvSC/I',StractionTestingandReporting Exemptions -All'ourGC/vSorganicfractions ir-xeGreloetsiIIsSubcategorv. -Pesticlae fractionInallotnerS.ppartSOfthisIncustrv. Ore)1(nlnoancCress(noIndustr-volatile. base/neutral, andpestlcice fractions IntheBaseandpreciousuetalssubcateoory. -A(Ifourcc/vsorganicfractions inallothersubcategor lesofthisincustrv. GumandWoodChemicals Industry-Pesticide fractionintheTallOIIRosinSubcategory andtheRosinBasedDerivatives Subcateoory. -Pesticide andbase/neutral fractions Inallothersubcateuorles ofthisIndustry. ouloandPaperInduStrv-Pest(clde fractionInPapergrade Sulfitesubcatecories <subparts JandU).Base/neutral andpesticide fractions inOeinkSubpartQ,Disso(vino KraftSubpartF,andPaperboard fromWastePaperSubpartE.-volatile, base/neutral, pesticide fractions IntheBGTBleacnedKraftSubpartH.Sem(-chemical SuboartsBandC.andNonintegrateo-Fine PapersSubpartR.-Acid.base/neutral. andpesticide fractions inFineBleachedKraftSuboartI,olssolvlng SulfitePuloSuboartK.Ground-xoodFinepapersSubpart0.xarketBleachedKraftsubpartG,Tissuefromwastepaper suboartT.andNonlnteerated TissuePapertSubpartS.SteamElectricPowerPlantIndustry-Base/neutral fractioninthcOnce.ThroughCoolingWater,FlyAsh.andBottomAshTransport Waterprocesswastestreams. 38 SEEINSTRUCTIONS ONREVERSESIDESECTIONIIPERMIT~gZ0005827~00<0AeUSETHISDATASHEETTORECORDI"FORMATION ASREQUIREDItt'CHECX APPROPRIATE BOXFORYHICHINFQRHATIQI THISDATASHEEfREPRESBITSs) CRITICALMATERIALS 1SECTIIXIII,ITEN4-E.GRIXttDWATER DISCHARGE IttFQRYATIQtt (PAGE55)X2.sEcTIQIIIITBI6.PRI0RITYPQLUITAMfs INsIRFAQEHATERDlscHARGE (PAGE37)TOXICPOLLUTANTS HAZARDOUS SUBSTANCES INDISCHARGE LISTAIIYCRITICALtATERIAL(TABLEIVPAGE6)tNTADDRESSED INSECTIQIIIITBI6PRIORITYPIXLUTAMTS hHICHYOUXttQWORHAVEREASONTOBELIEVETOEEPRESENTIt>THEDISCHARGE. SEEREVERSESIDEOFTHISPAGEFQRclPvHPRDIRECTIQIS ~NOTAPPLICABLE XAPPLICABIE (SEEBELCH)UNITSCODE1Mg/I2Ug/ILBS/DAYKG/DAYLUeIA.NA<<EOFCRITICALI'ATERIAL ORPRIORITYPOLLUTANT B.AVERAGECQICENIRATION; SA"PLETYPEI(IOFANALYSESC.vAXItXNCQMCBIIRAT IQtAtavASSAeIIAtlEOFCRITICAL<<ATERIALCRPRIORITYPQLLUfAttf B.AVERAGECCNCENTRATIONI SNePLETYPE;4OFANALYSESC.YAXINNCQICEMTRAT IONAttD.ASSAsNAt'kOFCRITICALYATERIALORPRIORITYRXLIMANfBsAVERAGECQICENIRATIONI SA"PLETYPEIftOFA%LLYSESCePlAXINNCOtCENIRAT IONAtIDI'ASS*Hdraze00302012WITCODESts"RETYPEOFAttAIYSES WITCODE'IITCOCELJUNITCODEW"lPLETYPEOFAttALYSES UNITCODElttlTCODELJWITCODESAevPLETYPEPOFANALYSESLJQtll'ODEWITCQDELJAeNtYEOFCRITICALMATERIALQRPRIORITYPQLUffANT B.AVERAGECQNCBITRATIQII SA<<PsLETYPEe1fOFAttALYSES QIITCCDESA'PLETYPELJOFANALYSESSAMPLETYPE1GRAB224HR.COMP.C.MAXI'OttCEMIRATIQI AtsDI'ASSAeIIAHEQFCRITICALelATERIALQRPRIORllYPQLLUfAttf B.AVERAGECQtCENTRATIOMl ~~<<PLETYPE;>OFAltALYSES CeYAXIYIf4CQtCEMIRATIQI AtoYASSAsIIA'1ECFCRITICALYATERIALORPRIORllYPOLLUTANT su(oB.AVERAGECQICEIITRAT IQNlSAMPLETYPE;"OFAIALYSESC~<<AXItlN'CQICBITRATIQI AtDYASSWITCODEWITCODELJWITCODESA"PLETYPEffOFAttALYSES WITCODEWITCODELJUtITCODESA'tPLETYPEr'rOFANALYSESUltITCODEWITCCDE4~tUetlEOFCRITICALvATERIALCRPRIORITYPOLLUTANT m~WB,AVERAGECQICBITPAT IOMISA<<PLETYPE~IQFANALYSESCee"AXISCQLEIIIRATIQI AlBMASSUstlTCODESA'IPLETYPEffOFANALYSESWITCODEWITCQQEAsi%YEOFCRITICALYATERIALQRPRIORITYPOLUJTAttf B,AVEPAGECOsCEMIRATION; SA<<PLETYPE;fffOFANALYSESC.,<<AXIHWCONCENTRATION AttD"ASSWITCODESA'lPLETYPEffOFANALYSESLJQIITCODElftlTCODEADDITIONAL PAGESOFTHISITEM7AREATTACHEDFCRTKRESTOFTHECRITICAL0YESMATERIALS Atilt/CRPRICRITYPOLLUTANTS REQUIREDTOBEREPORTED~2MO*Hydrazine isnotexpectedtobepresentindischarge butsmallquantities maybefoundinthesteamgenerators butwouldnotbeexpectedtobefoundintheactualdischarge flowtoOutfalls001or002. '""STPSI'.--"RCC/LP<ET!)ISSECTIC)iII"ls'cr>>fsTobeusedbvbothsur'o.anccrouncwater <<:pl!cant T"recordIrfornatlon onanvuichlcancriticalmaterial, E.p.A.r-ycc>l.tan. cr>>a:arpcus <<:s->>rceln<<nicnr'sscollcatlcn recuiresCataTooecrcvlcec. This<<ovidincludeanvchemicalI.bcence'"w-"e"ic>>iganCr!Tic~"sterlais ~egister>>ble I'/).-'eE.P.A.P"lorl<<ypollute>>T 'stlno!TableV).CrTables<<>>lcrsTSCrganicToxiccollutants.'.herToxic-ellutnTS~"-nvenTlonal andNonconventional "cllutants andhazardous .,Csa>>ces~!TE's7n!QQITVcCL<'VTS,A'IQ/CnHAZARDSJSSTA.CESmaterialI.E.3...8'stTrenameofThecremicalsessence!critical

material, priorlty'ollutant

~orhazardous substance) fromTablesIv,v1cIl'A-/Aasreculrecinthebcx<<nlc1youchecked",A.I-3.above.E1tereachchemicalsubstance's parameter numberas!IstecInTablesIv,vandIIA<<//ifprovided. S.ProvideT>>eaverageconcentratlcn cfTnechemicalsucstance ne.edInA.IndicateTnesampletypeusedandThenumberofanalysesraceToprcvldetheconcentration catafor-"ec>>emlcalsubstance nenadlnA.Providethemaxlrtumconcentratlc1 andcetermlne theressloadlnoo!thecnemlcalsubstance namedinA.')8TES:I.Ifcnlyonea>>alysls'<<as>>ace!Crachemicals;bstance thenrecordthatdataasamaxlmunvalue.Ifmorethanoneanalysisnasbeenmade!orachemicalsubstance Thenorovideanaveracevalueofthoseanalysesandthemaximumvalue.2.>>IsSectionIf,lte.7,staSheetoroviCesspacefcr"eccrdlng cata!or8chemicalsubstances !Materials). -'dditlcnal spacefor"sccrcing ofdata!Cr~oreTran8"aterlals canbemacebymak!ngcopiescfthisIten7DataSheetas~ceded.itIsalsoI,porta>>TTouseseparatesetofOataSheetsforeachapplicable reporting reculrement asIlsedInAI3.andoreachout.alI3.deferToTheleftnaroinforThecodenumber<<eoresentlng thesampletypeusedandtheappropriate unitcodes.40 llGVBngineeiiag &ScienceISununitCuwpanpAX.KI,Y'I'(l.kI,'>llRKI(lI','>ANALYTICALREPORTCookNuclearProj:WasteWaterAnalysisSubm:Feb21Samples29609-7RayV.Buhl(616)942-9600Submittal Number:Location: Contact:Phone:OutfallOOCHtngBoilerDetection UnitsLimitWWESSampleNo:79691Surfactants, MBASColiform,'ecal BOD,(5-Day)Sampledby:DateSampled:TimeSampled:DateReceived: TimeReceived: (0.025(1(3102/21/9400:0002/22/9409:000.02511.0mg/lcl/100mlmg/le1-EndofAnalytical Report*BODsampleisbeingreanalyzed andwillbesubmitted aftertheresultsarereceived. 55:>>;Gloniroo(l IlllloI'nrkwnp'I,". I'0Box87I.(Iron(lRnl>lds,XIII9588-087 I,616/942-9600 I'nx9I2-6I9l ll'1VLagiBeeiiii &SCienCe"I!Amunil(~imp:vuSTATEMENT OFDATAQUALIFICATIONS ~%Y;KI,)"'I'l(l XliNI(V,KIt;I',sCLIENT:CookNuclearSUBMITTAL'9609-7 Allanalyseshavebeenvalidated andcomplywithourQualityControlProgram.Noqualifications required. Thefollowing analyseshavebeenqualified forthereasonscited.SampleNo.(s):Explanation: Parameter: Reason:~KEY1.2.3.4.5.6.7.8.9.10.Sampleintegrity suspectuponreceipt(explain). Analysisperformed beyondEPAestablished maximumallowable holdingtime.Detection limitelevatedduetomatrixinterferences. Laboratory controlsamplevalueoutsideestablished acceptable limits.Matrixspikesamplevalueoutsideestablished acceptable limits.Duplicate analysisvalueoutsideestablished acceptable limits.Surrogate/internal standardrecoveries outsideestablished acceptable limits.Datapointsuspectduetopotential laboratory contamination (explain). Coeluteswiththecompoundcited.Resultmayrepresent acombination ofbothcompounds. Other(explain). Note:ThisdocumentisincludedaspartoftheAnalytical Reportfortheabovereferenced andshouldberetainedasapermanent recordthereof.:>5:>50!enw<>nit ttlttstnrkwnySt;.t<>tt<>xn7.t.t;rnnuRnt>ilats..ill lo;>88-087 l.6t6/Ot>->>t>OOI:nxO-t>-O>.Bin

GENERALCHEMfSTRY RESULTS"ClientSa'mple'D: OUTFAL'L"',OOC- HEATlNG.BOILER:l'..,'..'AL BatchID(s):222imDate'Colic'cte'di '02-21-94!:: $DateReceived: 02-22-94"Matrix;, 'vol'ater: P0469095-040-3N s'.,':.'::.::i".':::'.".Constituent::: ".':::::.':.":: Meth'od':> ':.<:,Res'uft';";:!:.':" "".".'Detection Umlt"-"h<-'.,..;-,Datii';,,';,;.:,:,::: ".,;Date,,"....'Quallfierts)" """Anal'ed'-7;,'LALSam le"ID"FluorideinmILBromide,inmILNitrate-Nitro eninmILSulfate,inmILTotalPhosphorus, inmILTotalKjeldahlNitrogen, inmILTotalCanideinmILTotalSuspended Solids,inmILChemicalOxygenDemandinmILTotalOrganicCarbon,inmILAmmonia-Nitrogen, inm/LColorTotalPhenolics inmILSulfide,inm/LSulfite,inmg/L340.2300.0300.0300.0365.2351.2335.2160.3410.2415.2350.1110.3420.1376.1377.1<0.15<0.050<0.017<0.0590.0498.0<0.02012239.53.7<5.0<0.15<1.01.60.150.0500.0170.0590.0300.100.02012181.00.0505.00.151.01.003-08-9403-14-9403-11-9403-10-9402-24-9403-17-9403-01-9402-28-9402-26-9403-10-9403-21-9402-24-9403-08-9402-25-9402-23-94L1304-22L1304-22L1304-17L1304-22L1304-16L1304-16L1304-13L1304-21L1304-23L1304-23L1304-16L1304-18L1304-14L1304-19L1304-20Comments: Nitrite4lltrogen lsnotpresentinpreserved samples.LOCKHEEDANALYTICAL SERVICES METALSRESULTS',Client"Simple'D."OUTFALL" OOC-':;:;.,':, .;.:, 'EATINGBOILER". .".::":"-"-'.LALBatchIDls):222im'Date'Collecte'd '02-'21-94'.:

,DateReceived:

02-22-94Matrix:w'ater.PO¹69095-040-3N Conitltuentii:- AluminumAntimonArsenicBariumBeIliumBoronCadmiumChromiumCobaltCoerIronLeadManesiumMananeseMercuMolbdenumNickelPhoshorusSeleniumSilverStrontium ThalliumTinTitaniumUraniumVanadiumZinc@Method601060107060601060106010601060106010601060107421601060107470601060106010774060106010784160106010602060106010Con'ceiitratlo'n .,-:-.IinIL)..:-.<0.20<0.060<0.010<0.20<0.005<0.20<0.005<0.010<0.0500.0263.6<0.003<5.00.017<0.0002<0.067<o.oao<0.050<0.005<0.010<0.10<0.010<0.20<0.10<0.001<0.050<0.020;-Re'po'rtlnIj,;... .'Detection'mit .....,::.(m IL):,.0.200.0600.0100.200.0050.200.0050.0100.0500.0250.100.0035.00.0150.00020.067o.oao0.0500.0050.0100.100.0100.200.100.0010.0500.020":"'De't'e: ."::'-.'"'Date".'.'Quallflerls) '-.A'naled03-12-9403-12-9403-14-9403-12-9403-12-9403-12-9403-12-9403-12-9403-12-9403-12-9403-12-9403-22-9403-12-9403-12-'9403-04-9403-12-9403-12-9403-12-9403-22-9403-12-9403-12-9403-22-9403-12-9403-12-9403-11-9403-12-9403-12-94SamleIDL1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12Comments: LOCKHEEDANALYTICAL SERVICES

VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260Page1of2ClienSmleID:0TFALLOC-HEATING BOILERDateCollected: 21-FEB-94 Matrix:WATERAnalicalBach¹:022594-8260F1 QCBatchID:022594-8260F1 LALmIID:L134-1DateReceived: 22-FEB-94 DateAnalzed:25-FEB-94 DiluionFacor:1SURROGATE RECOVERY12-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene 103105109QCLimits76-11488-11086-115Constituent Chloromethane VinIChlrideBromomehnChloroethane Trichlorofluoromethane An11-DihlrhnCarbonDisulfide MethleneChloriderns-12-Dichloroe heneVinIAea11-Dichloroethane 2-Butanone is-12-Dichloroe heneChlrfrm111-Trichloroethane CarbonTetrachloride 12-DichlrohnBnzeneTrichloroethene TCE12-Dichloro roaneBrmihlrmehn2-ChlorhIVinIEhr4-MethI-2-entanonecis-13-Dichloro roeneTIenerns-1-Dichloro ren2-Hexanone112-Trichloroethane Tetrachloroethene PCEConcentration /L<5<5<5<5<10<5<5<10<5<10<5<5<5<5<5<2<10<5<5<10<5<5Reporting Detection Limit/L101010DataQualifier sLOCKHEEDAIVALYTICALSERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGIVIETHOD8260ClientSamleID:OUTFALLOOC-HEATING BOILERLALSamleID:L1304-1Page2of2Constituent Dibromochloromethane ChlrobnzenEhIbenzenem-Xleneo-XIeneSmeBromoform 1122-Tetrachloroethane 13-Dichlorobenzene 14-Dichlor enzene12-Dichlorobenzene Concentration /L<5<5<5<5<5<5Reporting Detection LimitILDataQualifier sLOCKHEEDANALYTICAL SERVICES SEIVllVOLATILE ORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD82701f2DII:21-FEB-4Mrix:WATERDRiv:22-FEB-4DilinFr:1QCBatchID:8270-SEMIVOLATILES-5616 DateAnalzed:04-MAR-94 RATEREVER2-FfrhnIPheno!4,Nitrobenzene-d, 2-FlrbihenI24216721-110-9435-11443-11p-Terphenyld 2133-141Concentration Reporting Detection LimitPhni-hlrhr14-DihlrnznBnzlIhi2-IrirIhr4MhIhnIirnznIhrn10Bnziii2-hlrhmhnNhhin4-hlrnilin2MhlnhhInHexachloroc cloentadiene <1010LOCKHEEDANALYTICAL SERVICES SEMIVOLATILE ORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270ClientSamleID:OUTFALLOOC-HEATING BOILERLALSamleID:L1304-4Pae2of2Constituent 246-Trihlrohenol245-Trichloro henol2-Chlorona hthalene2-Nitroaniline DimehIhhlaeAcenahthlene26-Dinitrotoluene 3-NirnilinAcnahhene24-Dinitro henol4-NitrohenolDibenzofrn24-DinirolueneDiethIhthalate4-ChlorohenI-henletherFlrene4-Niraniline46-Dinitro-2-meth IhenolN-Nitrosodi henlamine4-BromhenI-henleherHexhlrnznePentachloro henolPhenanthrene AnhrenerzleDi-n-butIhthalateFluoranthene PrnBIbnzIhhai33'-Dichlorobenzidine Benzoaanthracene Chrsaneis2-EhIhexIhhIDi-n-octIhthalateBenzobfluoranthene BnzkflranhneBenzorenIndeno123-cdreneDibenzahanthracene BenzohierleneConcentration (IL)<10<10<10<25<10<10<2<25<25<10<10<10<10<10<2<25<10<10<25<10<10<10<10<20<10<10<10<10<10<10<10<10~Reporting Detection Limit(IL1010102510101025102525101010101010102510101010102010101010101010101010DataQualifier(s) LOCKHEEDANALYTICAL SERVICES SEMIVOLATILE ORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270P1DII:1-FE-4Mrix:WATERIRmIDRiv:22-FEB-4DilinFr:1QCBatchID:8270-SEMIVOLATILES-5616 DateAnalzed:06-MAR-94 2-FlrhnIPhenol',NltrobenzeneM, 2-FIrihnl21196121-110-9435-1144-11p-Terphenyl-d 2133-141Concentration Reporting Detection Limithni-IIhr4-DihirnznBnzlIhli-hrirIhr4MhIhnINirnzIrnBnziii-rhhnNhhlnIrnili2MhInhhInHexachloroc cloentadiene <10<1010LOCKHEEDANALYTICAL SERVICES SEMIVOLATILE ORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270ClientSamleID:OUTFALLOOC-HEATING BOILERLALSamleID:L1304-4RE Pae2of2Constituent 246-Trichloro henol245-Trichlor henI2-Chlorona hthalene2-Nitroaniline DimehIhhaleAcenahhlen26-Dinitrotoluene 3-Nitroaniline Acenhhene24-DinirhenI4-NitrohenolDibenzofuran 24-DinirlueneDihIhhI4-ChlorohenI-henletherFluorene4-Nironiline46-Diniro-2-mehIhenIN-Nitrosodi henlamine4-BromohenI-henletherHxhlrenzenPenchlorohenolPhenanthrene AnthracenerzoleDi-n-uIhhaleFluoranthene PreneBuIenzIhhla33'-Dichlorobenzidine Benzoaanthracene Chrsenebis2-EhIhexIhhaleDin-cIhhIeBenzobfluoranthene Benzokfluoranthene BenzorneInden12-cdreneDibenzahanthracene Concentration I/L)<10<10<10<25<10<10<10<25<10<2<25<10<10<10<10<10<25<2<10<10<10<25<10<10<10<10<10<2<10<10<10<10<10<10<10<10Reporting Detection LimitI/L)101010251010102510252510101010101010251010101010101010101010101010DataQualifierls) LOCKHEEDANALYTICAL SERVICES LOCKHEEDANALYTICAL SERVICESLANDGREASEBYFTIRL3.2OILANDGREASEIndianaMichiganPowerCo."Bridgman,MZ Attn:Client

Reference:

(ProjectCOOK-JENZ) ClientSampleID:DateCollected! DateReceived: Matrix:Analytical Batchf:OUTFALLOOC-HEATING 21-FEB-94 22-FEB-94 Water030894-418.1 BOILERLALSampleID:DateAnalyzed: DateExtracted: DilutionFactor:QCBatchID<L1304-808-MAR-94 02-MAR-94' 413.2OILAND1TotalOilandGrease1.0 rPESTICIDE ANALYSESRESULTSBYGC/ECDUSINGMETHOD8080mI14-DEr:-FEB-4Mri:WATRAnalicalBatch¹:030390-8080-E-1 DAnIz-MAR-4DiiinFr:1QCGrouID:8080PEST/PCB5666TMXDCBRRAEREVERY97QCLimits60-150Constituent Concentration LReporting Detection LimitLDataQualifier(sl -H-HHEPTAHRPXIDEHLRDANE44'-DDE4'-DDTENDLFANII4IMETHXYHRXAPHENPB-122PB-4TECHNICAL CHLORDANE TCMX-tetra-chloro-meta-xylene DCB-Deca-chloro-biphenyl LOCKHEEDANALYTICAL SERVICES

RADDATAREPORT(ra01)IndianaHichiganPowerCo.*Bridgman,HI OrganicandInorganic Contaminants (ProjectCOOK-JEHI) Hatrix:listerClientSampleID:OUTFALLOOC-HEATING BOILERDateCollected: 21-FEB-94 LALSampleID:L1304-10DateReceived: 22-FEB-94 LoginHubertL1304GrossAlphaGrossBeta13HAR.94GRALP/BETALAL-0060590213-HAR-94 GRALP/BETALAL-006059020.240.10.51.20.922.1pCI/LpCI/LPage2

RADDATAREPORT(ra01)IndianaHichiganPowerCo.*Bridgman,HI OrganicandInorganic Contamfnants (ProjectCOOK-JEHI) Hatrix:MaterClientSampleID:OUTFALLOOC-HEATIHG BOILERDateCollected: 21-FEB-94 LALSampleID:L1304-11DateReceived: 22-FEB-94 LoginNumber:L1304Ra-226Ra-22821-HAR-94 RA-226LAL-0073587414-HAR-94 RA-228LAL-007458730'497.390.0550.50.0440.5pCI/LpCi/LPage3 PHMeterCPCy-le~Caldateduef+/SampleSampleTimeSample9SampleDateCDMEnteredbyPHAnalysis(LAB.079) OutfallOOC5.3.56)SampleC/ph(priortocorrection) 7)NH~pHcorrection 025.3.68))ampleresultsC/pH.(after 27'HCorrection) 3SampleSampleTimeSamplejjSampleDateCDMEnteredby5.3.56)SampleC/ph(priortocorrection) 7)NH3pHcorrection 5.3.68)Sampleresults'C/pH(afterCorrection) 9)LAS.041SpecsVerifiedby:~R'upervisor Review/Date ~~/+/~Formpreparedby/DateFormapprovedby/Date12THPLAB.041.25s Revision1 OutfallOOCDetermination ofTotal(Lab170)ChlorineInstrument CPC//S0~Technician Sample/Standard Samplej/DateTimeCDMEnteredby373i5Z~.I)Absorbance 6.112)Results,ppmC-A(~C~cm3)Dilutions madeC2C3CZM4)Results,ppm(82~83)c..W5)LAB.041SpecsVerifiedby:~HSupervisor Review/Dare~Mt~~ Porepreparedby/Dree/~f'+Formapprovedby/Date12THPLAB.041-25)l Revision0 SEE1NSTRUCTIONS ONREVERSESlDESECTIONIIPEŽT~.qZg006SZT0ODAoLOCATIONOFDISOWSIE~SWq~SEo,EZ00,,~06, zos~066,pj9E~19~DISCHARGE LOCATIONBoH4t%RECEIVIHI HATER(IEoGAOLtCWATER CRIQ%CFQRFACE'NACoOOYOUDISCNRGESEASIXRLLY (IFIOoCCNTItlKlOE)DoIFYESLISTDISOHKEPERIODSN/AIO./EAVtQo/DAYBSOPTIONONDFLOWRATEWASTEWATER ~p~gggEoIhM)APPLICATION RAlKN/AIHo/IRo~sLJIRo/DAYIHo/ICo~u~~'uKI+1CONTACTCOOUNQ2NONCOIIDICT COOLDIQ3PROCESSSANITARY5STORMWATER Fo1YPEOFHASIEHAIKR DISCHA%EGoDISEHU4ESOEnlK(YEARLYAVERNKIHoDISCHhRtK FUBIRATEAlltimedailymaximumtimes365.IDTALYEARLYDAILYHIHIIItlDAILYtQXIIItI49Itl+CXE0~22.6~2~2~uLJHXRS/DAYoovhooo1MQY2MQD3QPDJoHAXDltlDESIGNDISCHUSIE FUXRNKoAoIXIYCUUSEHATERTREAT%HEAIDITIVKS 101RFATVIXRDl~(IFHSoCCNTIIAK1DIT813)DESIGN5.2VloTIEHAXIPltlDISCHARGE FLDHRATETOBEAUDERIZED IHPBIIIToltllQCXKITEM2WATERTREATMENT ADDITIVES BoIW%RlCTlENoJUOOEIIICALIXPEOSITICN OFTABIEAIIITIVESo oFTIEBKITIYEs,SULFURICACIDSULFURICACIDSODIUMHNeutralization" SODIUMHYDROXIDE UNITSCODE1MQ/I2UQ/IMARSULEX, INC.111GORDONBAKERROAD,SUITE30NORTHYORK,ONTM2H3R1DoEXPECIEDDISCHUGECEIEEHIIIATICN OFAIDITIVESo AEDITIYE~SodiumSulfateAEDITIVEIWEAEOITIVKNh%E.DO51I1RFAT1IEDISONCElDRBOtEAISITIVEST HAVILANDPRODUCTSCOMPANY421ANNST.,N.W.GRANDRAPIDS,MI49504HINII%tlINITSAY8IIGEItlITSHAXIIEtlItUTSECCK~gag~COCK'0130011500~1 ~lWo~LJo~LJi~FoWLTISTHKRBEHALEFFICIBEY AHDDISCHARGE FR81EIC6N/AAEDITIVEHNEAESITIVEVIEAEDITIVEIWEIRSo/DAYDAYS/HH.LJG,ASAHATTICIP%HT 1D1HISAPPLICATICN PROVIIXSPECIFICHAPtQLIAH CRACULTICTOXICCUXIICAL DATAERREFERENCE HHICHAREAVAILABLE AHDIHPOI6ATICN IXIII%RATEOFDESRADATICN OFTIEfRXLCQFCRDCHAEDITIVEo MSDSattached.

• Approximately instantaneous neutralization uponmixing-(Newtanktobecompleted Januaryof1995willensurecompleteneutralization priortodischarge.)

31 INSTRUCTIONS FORCOMPLETING SECT)OfIIITEMSIANO2ThisformrequiresInformation onthefacility'5 dl5charge

location, discharge

schedule, volumetlovrateandvatertreatment addltIves.ENTERTHEPERHITNUMBERINTHEBOXATTHETOPOFTHISFBI.THEPERMITNUMBERCANBEFOUNOONTHEFRONTPAGEOFYOUREXPIRINGpERMIT.IttnlsIsanevornotpreviously perm)tted

facility, thenleaveblankandanumoerrillbeas5lgned.

EntertheouttallnuaberInspaceprovidedforeacnpageo'.SectionII.ForcaenIndividual dlscnaroe point5separatesetotSectionIIformsmustbefilledout.ITEMIOISCHARGE LCCATIONSCHEDULEANOFLOWRATESA.Enterthelocationotdischarge, thisshouldincludequarter~uarter section.quartersection,section,Iorniandrange.B.Listnameofreceiving water<Ifsurface~aterdischarge). C.Indicaternetnarfacilitydischarges onaseasonalbasis.O.Ifyei,listdlscnarge periods.E.providethelandapplication ratesusedorexpectedtobeusedIntermsofinchesperhour,hoursDerday,andInchesDerraex.F.Indicatethetypeofvastevater tobedischarged froathisoutfall.Ratertothewastewater typecodegivenInthelettmargin.MOrethanOneCOqemaybeapplICable. G.ProvidetheaveragenuroerofhoursperdayInvhlchthetacllltydlscnarges treatedwastewater andthetotalnumberotdaysperyearinmichThedl5cnarge occur5.H.providecurrent(frcmthelastl2months)orexpectedflowratesasrequested, RefertounitcodedivanInthelettmarginfortneappropriate tlowunits.MGY-milliongallonsperyear;MGomilliongallonsperday;GPOgallonsD>>day.I.Providethemaximumdischarge tlorratewhichyouranttohaveauthorised withintheDetmlt.NOTE:ForNPOESpermlt5allY.theuseotsuchatlorraterillnotplaceanactuallimitrestriction ontheflorbutvillbethetlowrateusedtodewlooettluentlimits.Also,whentheMonthlyoperating Reportsarereviewedbycompliance statfItvillhelptheatodetermine IfanynerorIncreased usesmighthaveoccurredatthetaclllty. J.Providethedesigntlowtorthisspecificoutfalldischarge (e.g.batchtreatment Systemflow,packagedtreatment syat~flowsoracmeotherfInltetreats>>nt systeaflow).ITOI2WATERTREATMENT AOOITIVES A.Indicaterhetherdl5Charge Istreatedvlthconditioners, Inhibitors, ormlcrobloclde. Ifnot,continuetoItem3.B.Givename,function, andchemicalccnoosltlon otadditives used.C.Givenameandaddressotthemanutactureris) ottheadditives used.0,Indicateexpectedmlnlaxxa, awrageandmaxlaxaadischarge concentrations ottheaddltlvels) torthisdl5char9e. Ind)CaternetneryOutreatthedlSCnarge tOramOVetheaddltlVela) befOred)SCharge Otraaterater. F~Indicatetheremovalefficiency oteachadditivefromthewastewater andthedischarge frequency oteachadditivetothesurfacewaterorgroundwater. G.NOTE:ltlstheresponsibility ottheapplicant tosupplytheproductIntormat)on asrequested, inthisitema.Information requested butnotsuDpliedmayre5ultIntheaDpllcatlonbeingreturnedtotheapDIleantforcompletion. 32 MATERIALSAFETYDATASHEETSODIUMHYDROXIDE50%INDUSTRIAL GRADEe33kSECTIQNI-IDENTIFICATIONMANUFACTURER SNAMEoo~~~~~~~~~~ADDRESS(STREET,CITY,STATE,ZIP)PHONENUMBERSa~~o~o~~~~~a~a~~~~EMERGENCY PHONENUMBER......... EFFECTIVKDATEs~a~~~~~~eo~e~~~~TRADENAMEo~~~~~~s~~~~~~~~~~~~~CHEMICALFAMELYHavilandProductsCompany421AnnSt.,N.W.,GrandRapids,MI49504(616)361-6691CHEMTREC(800)424-93006/18/91SODIUMHYDROXIDE 50%INDUSTREAL GRADKAlkali,BaseSECTIONII-HAZARDOUS INGREDIENTS HAZARDOUS COMPONENTS QSHA/PELACGIH/TLV (Units)PROD.CAS0SodiumHydra-ide(CausticSada)(48.5-51.0% bywt)SodiumChlaride(0.8-1.3%bywt)Water(Balance)2mg/m=TWANatKstab1ishedNatEstab1ished2mg/m~TWANotEstablished NatKstablished10-77647-14-5 7732-18-5 SECTIONIII-PHYSICALDATAMCXMMCCBOILINGPOINT................ 293F(145C)FREEZINGPOINT............... 60F(15.6C)VAPORPRESSURE(mmHg)........ 1.5C<20CVAPORDENSITY(Air~i)......... NaInformation Available SOLUBILITY INH20-~~.~~~.~....Campletely APPEARANCE/ODOR.' ~...~.~~..~~Clear,ColorlessLiquid;OdorlessSPECIFICGRAVITY(H20~i).....1.52PH............................ NatEstablished SECTIONIV-FIRKANDEXPLQSIQN HAZARDDATADRRRCtCDPCRCRZECZ RRKRCXRCDXZKRRCtCSRP KR%RDCIRC@FLASHPOINT..................'...... NatFlammable LOWEREXPLOSIVE LIMIT(%byVolume)NatApplicableUPPEREXPLOSIVE LIMIT(%byVolume)NatApplicable EXTENGUESH MEDIA................... AsfarSurrounding Fires07/30/1'F91

MATERIALSAFETYDATASHEETSODIUMHYDROXIDE 50%INDUSTRIAlGRADESPECIALFIREFIGHTINGPROCEDURES... UNUSUALFIREHAZARD................ NearNIOSH/MSHA approvedselfcontained breathing apparatus andfullprotective equipment whenthismaterialisinvolvedinafire.Insolutioncausticcanreactwithamphateric metalsgenerating hydrogenwhichisf1ammableand/ore:~plosiveifignitedoSECTIONV-HEALTHHAZARDDATACARCINOGENICITY............. NTP~~~~~~~~~~~~~~~~~~~~~~~~~IARC~~~~~~~~~~~~sss~~~~~~~~~OVEREXPOSUREEFFECTS....... PRIMARYROUTE(S)OFENTRY...FIRSTAIDPROCEDURES........ EXPOSUREAGGRAVATED MEDICALNoneNa~~noRednessofE:cposedTissueswithpassibleburnsresultingindeepulceration. SkinContact,Ifinhaled:Removetofreshair.Ifnotbreathing', giveartificialrespiratian, preferablymouth-to-mouth. Ifbreathing isdifficult,giveo-ygen.Getmedicalattention. Incaseofcontact:Immediately flush,eyesorskinwithplentyaf~aterforat1east15minuteswhileremovingcont,aminated clothingandshoes.Getmedicalattent.ion.NashclothingbeforereusedIngestion: Danotinducevomiting. Ifconscious, dilutebygivingseveralglassesafwater.CallaPhysician Immediately. CONDITIONS NoneCurrently KnownSECTIONVI-REACTIVITY DATAMZfMMMMMMMWCCCR&MMM MClMXtCHEMICALSTABILITY............ Stab1eCONDITIONS TQAVOID........... NatApplicable INCOMPATIBLE MATERIALS........ AcidsDECOMPOSITION PRODUCTS. ~~.~~~~NaneCurrentlyKnownHAZARDOUS POLYMERIZATION...... Ni11NatOccurPOLYMERIZATION AVOID.......... NatApplicable CkmRRRCECPCRRXtStRCJDR SX'CRCtR'CRPAR~QRgLRRRCSCCC5SECTIONVII-SPILLORLEAKPROCEDURE MATERIALSAFETYDATASHEETSODIUMHYDROXIDE 50/INDUSTRIAL GRADEFORSPILL~~~~~~~~~~~~as~~~~s~MASTKDISPOSALMETHOD..... i...Addnon-rcactivedry,absorbent suchasdiatomaceous earth.ShovelorsweepupandplaceinanapprovedDOTcontainer andseal.Flushcontaminated areaandneutrali"ewithdiluteacid.Disposeofspilledorwasteproduct,contaminated soilandothercontaminated materialsinlicensedlandfillortreatment facilityinaccordance withallfederal,stateandlocalregulations. SECTIONVIII-SPECIALPRQTECTION WCRRESPIRATORY PROTECTION........ Suppliedairorselfcontained breathing apparatua withfullfacepiece.VENTILATION.............,..... Tomaintainvaporsbelowlimits.PROTECTIVE GLOVES............. Rubberorotherimpervious materials. KYEPROTECTION............;... Chemicalsplashproofgoggles.OTHERPROTECTIVE EQUIPMENT.... Asafetyshowerandeyebathshouldbeavailable. Foroperations wherespillsorsplashing mayoccur,useanimpervious bodycoveringandboots.HANDLINGANDSTORAGE.......... Storeincool,dry,wellventilated area.Keepcontainers closedwhennot,inuse.SECTIONIX-SPECIALPRECAUTIONS CCMHAZARDCLASS...............:.. Corrosive MaterialDQTSHIPPINGNAMK......... ~..SODIUMHYDROXIDE, LILQUIDUNNUMBERe~~~~~~~~~~~~~~~~~~~~UN1824REPORTABLE QUANTITY(RQ)...... 2000lbs.REFERENCES HMIS:H-S,F-O,R-1SODHYDOX07/"0/19'P1 friARSULEX, r~(QI0"IIMATERIALSAFETYDATASHEET.SulfuricAcid1.PRODUCTANDCOMPANYIDENTIFICATION Molecular Weight:98.08vCASP7664-93-9 .ProductName:SulfuricAcid:Formula: H,SO,ChemicalName:SulfuricAcidchemicalFamily:Inorganic Acid~Synonyms: Sulphuric Acid,OilofVitriol,BatteryAcidProductUse:Usedtnmanufacture offertilizers, explosives, otherackls,metalplcldingandpetroleum processing. MARSULEXInc.111GordonBakerRoadulte300orthYork,ONTM2H3R1(416)496-9655MARSULEXinc.40RichardsAvenueP.O.Box5453Nofwalk,CT0685&6453 (203)8544300EMERGENCY TELEPHONE NUMBER(800)263-S502PreparedbyMARSULEXTechnical Section(416)49&4164.2.COMPOSITION/INFORMATION ONINGREDIENTS SulfuricAcklWater%byWt.70-100%CASNumber7664-93%7732-1863.HAZARDINFORMATION EMERGENCY OVERVlEW: /DangerlExtremelycorrosive. Causesseverebums. Reactsvlolentlywlthwater. Hlghlyreactlveand capable'fignitingcombustible materials oncontact.Notflammable, butreactswithmostmetalstoformexplosive hydrogengas./Sulfuric Addhacolorfess toamber,deartoslightlydoudy,oilyliquid.NationalRreProtection Association (NFPA)RatingHazardous Materials fdentNcatlon System(HMIS)RatingFlRE4Extreme/Severe .3High/Serious ~2Moderate1=Slight0~MinimumWWaterReactiveDate:February, 1993.Superaedea:

February, 1990MARSULEXMSDS4010EPage1of9 MPTERIALSAFETYDATASHEET, SulfuricAcid3.HAZARDINFORMATlON (continued)

POTENTIAL HEALTHEFFECTS:ExposureLimits:SWfuricAckiACGIH(TLV)1mg/m(TWA)3mg/m'STEL) OSHA(PEL)1mg/m'fWA) Incontactwiththeskin:Concentrated solutionmaycausepainandsevereburnstotheskinandbrownishoryellowstains.Prolonged andrepeatedexposuretodilutesolutions maycauseirritation, redness,painanddryingandcrackingoftheskin.lncontactwiththeeyes:Immediate pain,severeburnsandcornealdamagewhichmayresultInbllndnesa C~Inhaled:MistsandvaporsmaycauseIrritation oftheeyes,noseandrespiratory tract.MaycauseIncreased ~pulmonary resistance, transient coughandbronchoconstrlctlon. Severeoverexposure mayresultInlungcollapseandpWmonaryedemawhichcanbefatal.ingested: Severeburningandpainlnthemouth,throatandabdomen.Vomiting, dhrrheaandperforation oftheesophagus andstomachliningmayoccur.LongTermExposure: ~Repeated exposuremayproduceerosionanddiscoloration ofteeth.Althoughnodirectlinkhasbeenestablished betweenexposuretosulfuricacid,Itself,andcancerInman,theWorldHealthOrganization (WHO)Intematlonal AgencyforResearchonCancer(IARC)haveconcluded thatoccupational exposuretostrongInorganic acidmistscontaining sulfuricacidIscarcinogenic toman,causing,'ancerofthelarynx(thevoicebox)and,toalesserextent,thelung.ExposuretoanymistoraerosolduringtheuseofthisproductshoWdbeavoidedand,Inanycase,keepexposures belowtheoccupational exposurelimitforsulfuricacid.Corrosive effectsontheskinandeyesmaybedelayed,anddamagemayoccurwithoutthesensation oronsetofpain.Repeatedoverexposure mayleadtocontactdermatitis, maycausebronchitis withcough,phlegm,>'hortness ofbreathandemphysema, cancausechronicrunnynose,tearingoftheeyes,nosebleeds andstomachupsets.Strictadherence tofirstaklmeasuresfollowing anyexposureIsessenthl. ExistingMedicalCondNonsPossiblyAggravated ByExposure: Skinirritation maybeaggravated InIndMduals withexistingskinlesions.Breathing ofvaporsorsprays(mists)mayaggravate acuteorchronicasthmaandchronicpulmonary diseasesuchasemphysema andbronchitis. Carcinogenicity Data:Althoughtherearereportslinkingexposuretosulfuricackltocancer,thisproductIsnotclassified byNTP(National Toxicology Program), notregulated ascarcinogenic byOSHA(Occupational SafetyandHealthAdministration), andhasnotbeenevaluated byIARC(International AgencyforResearchonCancer)/orACGIH(American Conference ofGovernmental Industrial Hyglenlsts). (Seealso,LongTermExposure). NEffective Oate:February, 1993Supersedes:

February, 1990MARSULEXMSDS4010EPage2of9

NARSULEK, MATERIALSAFEIYDATASHEETSulfuricAcid,4.FIRSTAIDMEASURESPromptremovalofthismaterialfromcontactwiththebodylsofutmostImportance.

&TARTFIRSTAIDATONCE.Precaution: Personsattending thevictimshouldavoiddirectcontactwithheavilycontaminated dothlngand'omitus.Wearimpervious gloveswhiledecontaminating skinandhair.Incontactwiththeskin:Rushskinwithrunningwaterforaminimumof20minutes.Startflushingwhileremoving~contaminated dothlng.IfIrritation

persists, repeatflushing.

Obtainmedicalattention IMMEDIATELY. Donottransport victimunlesstherecommended flushingperiodlscompleted orflushingcanbecontinued duringtransport a/'hilethepatienttsbeingtransported toamedicalfacility, applycompresses ofIcedwater.Ifmedicaltreatment mustbedelayed,immersetheaffectedarealnicedwater.Ifimmersion lsnotpractical, compresses oficedwatercanbeapplied.Avoidfreezingtissues.Discardheavilycontaminated dothlngandshoesinamannerwhichlimitsfurtherexposure. Otherwise, wash/.dothtngseparately beforereuse.Incontactwiththeeyes:Immedhtely flusheyeswithrunningwaterforaminimumof20minutes.Holdeyelkfsopenduringflushing. Ifirritation

persists, repeatflushing.

Obtainmedicalattention IMMEDIATELY. Donottransport /victimuntiltherecommended flushingperiodIscompleted unlessflushingcanbecontinued duringtransport. .Inhaled:Movevictimtofreshair.Giveartlcialrespiration ONLYIfbreathing hasstopped.GiveCardiopulmonary flesuscltatlon (CPR)Iltherelsnobreathing ANDnopulse.Obtainmedicalattention IMMEDIATELY. Ingested: Ifvlctlmlsalertandnotconvulsing, rinsemouthandgiveTAto1glassofwatertodilutemateriaLIfspontaneous vomitingoccurs,havevictimleanforwardwithheaddowntoavoidbreathing Inofvomitus,rinsemouthandadminister morewater.IMMEDIATELY contactlocalpoisoncontrolcenter.Vomitingmayneedtobeinducedbutshouldbedirectedbyaphyslchnorapoisoncontrolcenter.IMMEDIATELY transport victimtoanemergency facility. h//NotetoPhysician: AIItreatments shouldbebasedonobservedsignsandsymptomsofdistressInthepatient.Medicalconditions thatmaybeaggravated byexposurelndudeasthma,bronchitis, emphysema andotherlungdiseasesandchronicnose,sinusorthroatconditions. SeverityofthebumIsgenerally determined bytheconcentration ofthesolutionandthedurationofexposure. Intheeventofskinoreyecontact,lmmedhteandthoroughflushingIsessential. Continued washingoftheeffectedareawithcoldorIcedwaterwIIIbehelpfulinremovingthelasttracesofsulfuricacid.Creamorointments shouldnotbeappliedbeforeorduringthewashingphaseofthetreatment. 5.FIREFIGHTINGMEASURESshPoint(method): Notapplicable, productIsnon-flammable utolgnltlon Temperature: Notcombustible Rammabllity Limitiinair(%):UELNotapplicable LELNotapplicable EeettlteDate:February, 1993Supersedes:

February, 1990MARSULEXMSDSItI010EPage3of9 MATERIALSAFETYDATASHEETSulfuricAcid5.FIREFIGHTINGMEASURES(continued)

FireExtinguishing Media:Forsmallfiresusedrychemicalorcarbondloxkie.Forlargefires,floodfireareawithr'aterfromadistance. Expectviolentreactionwithwater.Donotgetsolidstreamofwateronspilledmaterhl.SpecialFireFightingProcedures: WearaNIOSH/MSHA approvedself~ntalned breathing apparatus Ifvaporsormistsarepresentandfullprotective clothing. Forfightingfiresindoseproximity tospillorvapors,useacld-resistant personalprotective equipment. Evacuateresidents whoaredownwindoffir.Preventunauthorized entrytofirearea.Dikeareatocontainrunoffandpreventcontamination ofwatersources.Neutralize runoffwithlime,sodaashorothersuitableneutralizing agents(seeDeactivating Chemicals, Section6).Coolcontainers thatareexposedtoflamewithstreamsofwateruntilfirelsout.OtherFireorExplosion Hazards:Notflammable buthighlyreactive. CapableofIgnitingfinelydividedcombustible materhlsoncontact.Reactsviolently withwaterandorganicmaterials withevolution ofheat.Extremely hazardous Jincontactwithmanymaterials, particularly

carbldes, chlorates, fulminates, nitratesandplcrates.

Sulfuricacidreactswithmostmetals,espechlly whendilutetogiveflammable, potenthliy explosive hydrogengas.Hydrogengascanaccumulate toexplosive concentrations Inskleconflnedspaces.Followappropriate NFPAcodes.6.ACCIDENTAL RELEASEMEASURESStepstobetakenIntheeventofaspillorleak:RemoveallIgnitionsources.Ventilate areaUseapproprhte PersonalProtection Equipment. Preventliquidfromenteringsewersorwaterways. DikewithInertmaterial(sand,earth,etc.).Stoporreduceleaklfsafetodoso.CollectIntocontainers forreclamation ordisposalonlyifcontainer ~issuitabletowithstand thematerial. Considerinsituneutralization anddisposal. Ensureadequatedecontamination oftoolsandequipment following deanup.ComplywithFederal,Provincial/Stateand localregulations onreporting releases. Deactivating Chemicals:,Ume, limestone, sodiumcarbonate (sodaash),sodiumbicarbonate, dilutesodium+hydroxide, diluteaquaammonia.WasteDlsposaiMethods:Disposeofwastematerialatanapprovedwastetreatment/dtsposai

facility, lnaccordance withapplicable regulations.

Donotdisposeofwastewithnormalgarbageortosewersystems.V'ote-pean-upmaterfalmaybeaRCRAHazardous Wasteondhposal.rr'Spills aresubjecttoCERCLAreporting requirements: RQ1000lbs.7.HANDLINGANDSTORAGEPrecautions: Wearappropriate PersonalProtection Equipment. Donotbreathspraysormists.Donotingest.Do/notgetIneyes,onskinoronclothing. Keepignitionsourcesawayfromsulfuricacidstorage,handlingandtransportation equipment. HandlingProcedures andEquipment: Carbonsteelorstainless steelmaterials aresuitableforuseforacidconcentrations equaltoorgreaterthan93%.However,theeffectoflowerconcentrations onthematerhlsofconstruction canbeverycomplex.Contactproductsupplierforspecmcrecommendations whenhandlingsulfuricacidatstrengths lessthan77%.Effecffve Date:February, 1993Supersedes:

February, 1990MARSULEXMSDS0010EPage4of9 FJRSUI.EX, MATERIALSAFETYDATASHEETSulfuricAcid7.HANDLINGANDSTORAGE(continued)

StorageTemperature: Storeabovefreezingpoint(Section9).Elevatedtemperatures willincreasethecorrosion /rateofmostmetals.StorageRequirements: Storepackagedacidinadry,well,ventilated locationawayfromcombustibles, oxldlzers, bases,ormetallicpowders.Storagetanksshouldbeprotected fromwaterIngress,bewellventilated, andmaintained structurally inasafeandrelhbiecondition. OtherPrecautions: Sulfuricacklwillattacksomeformsofplasticsandcoatings. Alwaysaddacidtowater-notjwatertoacid.IfkeptInupperfloorsofbuilding, floorsshouldbeacidproofwithdrainstoarecoverytank.8.EXPOSURECONTROLS/PERSONAL PROTECTION -Recommendatlons listedInthissectionIndicatethetypeofequipment whichwillprovkleprotection againstoverexposuretothisproductConditions ofuse,adequacyofenglneerlng orothercontrolmeasures, andactualexposures willdictatetheneedforspecificprotective devicesatyourworkplace. ~Engineering Controls: LocalexhaustvenNation required. plratoryProtection: ANIOSH/MSHA approvedair-purifying respirator equippedwithacidgas/fume, dust,mistcartridges forconcentrations upto10mg/m.Anair-supplied respirator Ifconcentrations arehigherorunknown.S)tinProtection: Impervious (l.e.,neoprene, PVC)gloves,coveralls, bootsand/orotheracidresistant protective ~clothing. EyeProtection: Tight-fitting chemIcalgogglesandfaceshield./OtherPersonalProtective Equipment: WherethereIsadangerofspillingorsplashing, acidresistant apronsorqsuitsshouldbeworn.Trouserlegsshouldbewornoutside(nottuckedIn)rubberboots.Safetyshowersandleyewashfountains shouldbeinstalled instorageandhandlingareas.9.PHYSICALANDCHEMICALPROPERTIES hddhPhysicalState:VquldAppearance andOdor.SWfurlcacidIsacleartoamber,heavy,oilyliquidwhichmayhaveasharppenetrating odor.OdorThreshold: NodataBoilingPoint:77.67%:193'C(380'F);93.19%:278K(529'F);98%:330'C(626'F)I@citing/Freezing Point:77.67%:-11.2'C(+11.6'F); 93.19%:-29.5'C(-21.'I'); 98%:-1.1'C(30'F)VaporPressureat%PC(102'F):77.67%:1.2mmHg;93.19%:0.0016mmHg;98%:0.002mmHgSpecificGravityat15'C(60'F):77.67%:1.7059;93.19%:1.8354;98%:1.8437VaporDensity:(Air=1):3.4sulfuricacklcomponent BulkDensity:Notapplicable (seespecificgravity)ffecthreDate:February, 1993supersedes:

February, 1990MARSULEXMSDS40tOEPage5of9 MATERIALSAFETYDATASHEETSulfuricAcid9.PHYSICALANDCHEMICALPROPERTIES (continued)

Evaporation Rate:Notapplicable /Solubility: MiscibleInallproportions lnwater.AlsosolubleInalcohol.pH:0.3(1Nsolutionat25'C/78'F) 10.STABILITY ANDREACTWITY Stability: Under.NormalConditions: Stable,butreactsviolently withwaterandorganicmaterials withevolution ofheat.UnderFireConditions: Decomposes toformsulfuroxides(SQ,). Conditions toAvoid:Temperatures whichmayhaveanegativeeffectonthematerials ofconstruction usedInequipment. Materials toAvoid:Contactwithorganicmaterhls(suchaschlorates,

carbldes, fulmlnates andplcrates) maycause~flreandexplosions.

Contactwithmetalsmayproduceflammable hydrogengaLWhendiluting, addacidtowater.DoNOTaddwatertotheacid.Hazardous Decomposition orCombustion Products: Toxicgasesandvapors(e.g.sulfurdioxide,sulfuricacidpvapors/mists andsulfurtrioxide) maybereleasedwhensulfuricaciddecomposes. Hazardous Polymerization: Willnotoccur11.TOXICOLOGICAI INFORMATION Toxicological Data:,Lote(oral,rat)2140mg/kgL+(Inhahtion, rat)510mg/refor2hrsSkineffects(rabbit): SevereIrritation Eyeeffects(rabbit): Severeirritation Carcinogenicity Data:Althoughtherearereportslinkingexposuretosulfuricacidtocancer,thisproducthnot,dasslfled byNTP(National Toxicology Program), notregulated ascarcinogenic byOSHA(Occupational Safety'ndHealthAdmlnistratton), andhasnotbeenevaluated byIARC(International AgencyforResearchonCancer)orACGIH(American Conference ofGovernmental Industrhl Hyglenlsts). SeeSection3.HazardInformation, regarding PotenthlHealthEffects(LongTermExposure) forfurtherdiscussion. ~Reproductive Effects:NoInformation Isavailable andnoadversereproductive effectsareanticipated. ~Mutagenlclty Data:Noinformation h,available andnoadversemutagenic effectsareanticipated. <'reratogeniclty Data:NoInformation Isavailable andnoadverseteratogenic effectsareanticipated. Synerglstlc Materials: NoneknownEffective Oats:February, 1993Supersedes:

February, 1990MARSULEXMSDS4i010EPage8of9 NARSULH(,

'ATERlALSAFETYDATASHEETSulfuricAcid12.ECOLOGICAL INFORMATION -EcotoxlcEffects:Harmfultoaquaticlifeinverylowconcentrations. Maybedangerous ifItenterswaterIntake;Rshtoxicitycriticalconcentration 10mg/L;7.34mg/L/48hrs-LymneaePalustrls 100%mortality. 13.DISPOSALCONSIDERATIONS ~Responsibility forproperwastedisposalhwiththeownerofthewaste.Workwiththeappropriate regulatory bodiestoensurecomplhnce withregulations. ~Considerthecollection ofresidualsulfuricacidintocontainers forreclamation ordisposalonlyIfthecontainer Issuitabletowithstand thematerhl.~Considerlnsltuneutralization anddisposal. ~Qean-upmaterialmaybeaRCRAHazardous Wasteondisposal. ~Provincial/State orlocalregulations orrestrictions arecomplexandmaydifferfromFederalregulations. ~TheInformation applIestothematerhlasmanufactured; processing, neutralizing, useorcontamination maymaketheInformation tnapproprhte, Inaccurate orIncomplete. 14.TRANSPORT INFORMATION U.S.(UnderDOT)/'hipping Name:RQSWfurlcacklHazardClassorDivision: 8ProductIdentification No.(PIN):UN1830PackingGroup:IICanada(UnderTC)ShlpplngName:Sulphuric acidClassificatio(s): Qass8(9.2)ProductIdentlflcatlon No.(PIN):UN1830PackingGroup:II15.REGULATORY INFORMATION ..ASARATitlelllHAZARDCATEGORIES ANDLISTSp'cute(Immedhte) Health:Chronic(Delayed) Health:Fire:Reactivity: SuddenReleaseofPressure; YesYesNoYesNoExtremely Hazardous Substance (40CFR355,SARATitleIIISection302)CERCLAHazardous Substance (40CFR302.4)'oxicChemical(40CFR372.65,SARATitleIIISection313)YesEffecUveDate:February, 1993Supersedes:

February, 1990MARSULEXMSOS4010EPage7of9 MATERIALSAFETYDATA'SHEET Sulfur/cAcid15.REGULATORY INFORMATION (continued)

Reportable Quantity(RQ)underU.S.EPACERCLA:RQ=1000IbTSCAinventory Status:Reported/Included ~A~DWorkplace Hazardous Materials Information System(WHMIS)WHMISClassification(s): QassE-Corrosive QassD1A-VeryToxicWHMISHealthEffectsIndex:AcuteLethality -verytoxic-immedhteCorrosive toanimalskinWHMISIngredient Disclosure LIS:Confirmed A;Meetscriterhfordisclosure at1%orgreater.Reportable Quantity(RQ)underTransport Canada-TDG:RQ5lltres(orKg)Ifltrepresents adangertohealth,life,propertyortheenvironment. 16.OTHERINFORMATION Additional Information andReferences 1.Envlro-TIPS Manual,'SWphurlc AcidandOleum',Environment Canada,February1S84./2.Weast,R.C.(Ed.),'CRCHandbookofChemistry andPhysics', 60thEdition(1S80)3.Sax,N.l.,"Dangerous Properties ofIndustrhl Materhls', 7thEdition(1989)4.ACGIH,Threshold LimitValuesforChemicalSubstances andPhysicalAgentsandBiological ExposureIndices', 1S91-925.Slttlg,Marshall, 'Handbook ofToxicandHazardous Chemicals andCarclnogens", 2ndEdition,1985RevisionIndicators: JaIntheleftmarginIndicates arevhlonoradditionofinformation sincethepreviousIssue.ffeottlee Date:February, 199SSuporeodoL

February, 1990MARSULEXMSDSW10EPagosofg NARSULB(,

MATERlALSAFETYDATASHEETSulfuricAcid16.OTHERINFORMATION (continued) Legend:CAS8CERCIACFRDOTEPALCLELMSHANIOSHPELPVCRCRASARASTELTCTDGTSCATWAUEL-ChemicalAbstracts ServiceRegistryNumber'I-Comprehensive Environmental

Response, Compensation, andUabllityAct-CodeofFederalRegulations

-Department ofTransportation -Environmental Protection Agency-Theconcentration ofmaterhllnairexpectedtoldll50%ofagroupoftestanimals-LethalDoseexpectedtokill50%ofagroupoftestanimals-LowerExplosive Limit-MineSafetyandHealthAdministration -NationalInstitute'for Occupational SafetyandHealth-Permissible ExposureLimit-Polyvinyl chloride-ResourceConservation andRecoveryAct-Superfund Amendments andReauthorizatlon ActoftheU.S.EPA-ShortTermExposureLimit-Transport Canada-Transportation ofDangerous GoodsAct/Regulations -Threshold UmltValue-ToxicSubstances ControlAct-Time-Weighted Average-UpperExplosive UmitJTheinformation contained hereinhasbeenpreparedbyMARSULEXInc.andIsofferedonlyasagukietothehandlingofthisspecificmaterialandhasbeenpreparedlngoodfaithbytechnically knowledgeable personnel. ItIsnotIntendedtobeaII-Inclusive andthemannerandconditions ofuseandhandlingmayInvolveotherandadditional considerations. NowarrantyofanykindIsgivenorImpliedandMARSULEXInc.willnotbelIableforanydamages,losses,InJurlesorconsequenthl damageswhichmayresultfromtheuseorrelhnceofanyinformation contained herein.EffeeUveDate:February, 1993Superaedea:

February, 1990MARSULEXMSDSW10EPage9of9

~'~e\~~IC~~e~.~~~7~~eC.~.I'~~~ei.~co~C'~ejeeC~I<<C'e.~ej7)'~'IAce'~~~C'~7'~c~~'e7a~C'.~rI~~0~~ejA~7~~LII'cjc'~'ejAC'.~ej'c~~~'~ed%ocEa~~II~~7A~7C~C~I~C~ejx7~~C~~'ejx~~~'exx~c~r~C~C~C~e7\~7~~~,~e7%~e~'~~jA~~~ INSTRUCTIONS FORCOMPLETING SECTIONIIITEM3TrIsformrequiresinformation on,theprocessstreamsrhlchcontribute tothisdischarge. ENTERTHEPERMITNISIBERINTHEMXATTHETCPOFTHISFORM.THEPEIbIITNWBERCANBEFOUNDONTHEFRONTPAGEOFYOUREXPIRINGpEIpIIT.Ifthisisana>>ornotpreviously permitted

facility, thenleaveblankandanumber<<illbeassigned.

EnteroutfallnumberinspaceprovidedforeacnpageofSectionII.Forebenindividual discnaroe pointaseparatesetofSectionilformsmustbefIliedout.ITEM3PROCESSSTREAMSCONTRIBUTING TOOISCHARGE: FOREACHSEPARATEPROCESSPROVIOETHEFOLLOW'ING INFORMATION A.EntertnenameOftheprOCeSSuhlqnCOntributeS tOthlSdiSCharge. AISOprOVidetheprOperSICCOde.B.IndicatetneyearlyaverageprocessscneduleInhoursperdayanddays-peryear.C.Providetheprocesswastewater flowrateInfonaetion asrequested basedonyourlastI2monthsofoperations. RefertounitcodegivenIntheleftmarginfortheappropriate flowunits.0.processproduction Rate-Certainpermitlimitations maybebasedonproduction rates.Theproduction ratesusedtodetermine permitlimitsshallberepresented byareasonable measureofactualproduction ofthefacility, suchastheproduction duringthehighmontnoftnepreviousyear,orthemonthlyaveraqeforthehighestofthepreviousfiveyears,orotnerreasonable measureasstatedInapplicable U.s.E.P.A. categorical rulesandregulations. Forneusourcesorneudlschargers, actualproduction shallbeestimated usingprojected production. Recordyourproduction ratesinthetermsandunitsusedintheapplicable U.S.E.P.A. categorical rulesoneregulations foryoultypeoffeellitye SEEINSTRUCTIONS ONREVERSESIDESECTlONIlPERMIT~ts110005827NUMBER.:vGROUNDWATER DISCHARGE INR)RMATIDN AsISBEDISCHARGE FIEPITHISOUTFALLDIRECTEDTOBEGRCLBOORGROLSDQTTRS2 (IFMlsCCtITIIIE TOITBtlBJBsHASAHBNLXIKOUXIICAL SBBTYORITSEOJIVALENT BEENPERFORIEO ORISTHERESLFFICIENT CJRREHTHtlROGKQICAL IHFCttWTICN AVAILABLE gREOQUREDQ~HATERRESXRCESTHISDLISTIHIOR~DISCHARGE) IFYESATTAOIACOPYCFTHEREPCIITsCsAREYOURSTII41AHEXBPTICNFRLBISLttlllTI% AHYIROGIDUXIICAL REPORTLEKVARRLAERs(Q(PAGEQ)ORFRLBIGROLtEIWTEB KNITOII%IIEOUJRIBENIS LEGERELLERss(5)LPJGEQ)0F'nEPART22RLLKssIFYEsATTAcHDOCLIENIS ANJEXPLAIWTICN TODMt9STRATK TIWTYOLIIDISCHARGE IEXADOUILIFYFOIAM~ONsDsAREYLXJRBXESTIID AVARIANCEFRCNRULE3Bs2Z6(PJGE19(td%KIINATICN) OFBEHATERRESOLJEXS CCttllSSION PART22GRCLtGIWIKR RILESTIFYESsATTACHQXHDOCLtEHIS ASIECESSARY TOOQQN$7INTKTIENEEDRTIAVARIANCEINTBIBISOFTIECRITIRIASPKIFIEDINRLAEV5sZ?10 (PJGKCFBEPART22RLIESsEsI,ISTAlp,OEIIICALSLBSTAtCKS WIOIAREINNICHIGANSCRITICALHATERIALS REGISTERTABLEP/LPAGEII)ANVCRUsSsKPA'SPRIOIITYITXLLITANT LISTTABLEY(PAGE7)ORANYOBERSLBSTAJCES %lotAREcRtwYBEcoEIILABIIQJs ToBEBEBIQwTKD UBEs0FTIE6IIGLtEBwTER cRToTIEILSLICIEJILBITHATAREDISCHARGED OIEXPECTEDTOBKDISCHIRGED TOBEGROLtElWTKILBY THISFJCILIIYs ESTDWTKTHEFINALEFFLIENTCOIEXIIIRATIOI AIORECCRDALLDATAINITEN1OFSECTIOIIlIHlHISBCDILETsBEJPPLICJJII'AYBERKOJIREDTODOAIDITIOWL IWSIKAIWLYSKSs QXYESp~ReportSubmitted 12/6/91.Q~SPgXNOTAPPLICABLK/BKLIEYED ABSENTClPRESENTiDATAIROYIBEDINITTH7lTEM6AsDISOIUEIK OWRACIBRISTICSBCO5(FIVEDAYBIOOEIIICJIL OXYGENDEHJjtO)'CCD(OKIIICAL aLYGENIKIWIO)CCNBNBIATI Ol~5~0~18,~0~52EXPECTEDsssssswssssl SSSNSSC-~Usscass1lED/I2UO/I3COUNTS/100tnl4S.U.5'F5LSS/DAYIOC(TOTALOEANICCARBON)JJBCNIANITIOIEH(ASN)TOTALSUSPEIKED SLLUNTIALPICGPIOEJS (ASP)>>TOTALRESICUILOEJNINEDISSCQ%DOXIGENFECILLDLIRIBIBACTERIA'ntPBRABNK (SLttER)IEIPERATLIE (HINIBR)NDI~0.~02~0.~08LLJ~LJLJ~~LJBsOBERIWSTEIWTER OWRACIKRISTICS ~Iu>u5~52~SM~PLXRE.1GRAS224HOURCOllPOSITE 0IL4GREASELORIDEATEITOTALIL~10.~9~80,~00ID8~195.~010.,20~582925.~0~8~0~0~1~521521~611~6~122~2REQJIREDIIFOEWTICN FOISNIFACKIWTBRDIOIIA%ESs AnalysesperJ.B.Beauboeuf, TargetPermitEffluentLimitsList. INSTRUCTIONS FORC(y(PLETING SECTIONIIITEMS4ANO5ThistomrequiresInformation on4specificoutfalldischarging toeitherthegroundraters orthesurfacewaters.ENTERTHEPERMITNISIBERINTHEBOXATTHETCPOFTHISFORM.THEPERMITNQd)ERCANBEFOUNOONTHEFRONTPAGEOFYOUREXPIRINGPERMIT.Itthisis4nerornotpreviously permitted

facility, thenleaveblankand4numberrillbeassigned.

EntertheouttallnumberInthespaceprovidedforeachDaaeofsectionII.ForeachIndividual discharge point4separatesetotSectionIIterms(items4ano5)mustbeflliedout.ITO(4QROUhOWATER OISCHARGE INFOCMATION(OONOTINCLUOEDEEPWELLINJECTION INFORMATION INTHISITEM>A.-O.Theapplicant shalladdresseachofthesepartsIfthedischarge tronthisouttalIlstotnearoundrater. ITEM5EXISTINGOREXPECTEO(FORANEWOISCHARGE) WASTEWATER CHARACTERISTICS OFGRCUNOWATER CRSURFACEWATERDISCHARGE (OONOTINCLUOErLLINJINININHA.TheaDDIleantshallreportavailable discharge data(realdataforexistingdischarge orexoecteddatafor4Droooseddischarge) fortneDareneters aslisted.Theseparameters shallbeaddressed foreither4surfacewaterdischarge orasappropriate foregroundwater dlscnarge. Forassistance indetermining appropriate parameters 4groundwater dlscharoe applicant maycontacttheGroundwater Oualityolvlsion, Pe(mitsSectionortheappropriate Groundwater oualltyolvlslon'5 OlstrlctotfIce.Theapplicant shallreportthesampletypecodebestdescglblng eachreportedplaceofdata.seecodingonthelettmarginofthistore.ItthisouttallIs4su>faceraterdischaroe. theapplicant mustreportquantitative dataforeachparameter Identified 4anov..eaoomtovesaaa~a~.so:aolsttae~oaotvoevesaetlatl.aao~aaaostasteevetttal~aoolloatlo .B.Ifdatalsavailable forotherparameterS notlistedaboveInA.orotherpartsotthisaDPlicatlon theapplicant shouldreportthatdataIntheblankspacesprovidedInthl5part.NOTES:I.Unitcodestorparaneters reportedInpartsAand8canbetoundontheletthandsideotthisform.2.GrabsampleshallbeusedtoanalysetorpH,temoerature, totalphenols,residualchlorine, oilandgre4se,andfecalcoliformIn4surfacevaterdischarge unlessotherfrequency-smnpl ~typeanalysesareavallabl~~SeeGlossary(page48)tordetlnltlon otgrabsample.24-hourcomposite samplesshelIbeusedtoanalysetorTotalB005,coo,Toc,AnmonlaNitrogen, andTotalSuspended SolidsIna5urtaoevaterdischarge unlessothertrequency-sample typeanalysesareavallabia.seeGloss4ry(page48)tordefinition ofcomposite sawple.4.REPORTING OFINTAKEOATA.Youarenotrequiredtoreportunlessyouvishtodemonstrate yourellqlbllltytor4"net"effluentIimitation toroneot'orepollutants, thatIs,anetfluentlimitation adJustedbysubtracting theaveragelevelofthepollutant(s) DresentInyourIntakevater.NpOESregulations allownetlimitations onlyIncertainclrclastances. Todemonstrate youreligibility, reporttheavertx)eoftheresultsotanalysesonyourIntakerater(Ifyourvaterl5tre4tedbeforeuse,testthevateratterItIstreated), andattach4separatesneercontaining thetollovingtorebenpollutant:(4)A5taten>>nt thattheIntakeraterl5drawnfrohthebodyofvaterIntowhichthedlsch4rge Ismade.(Otherwise, youarenoteligibletornetlimitations.) Ib)Astatement ottheextenttowhichthelevelotthepollutant lsreducedbytreatment ofyourwastewater. (Yourlimitations villbeadJustedonlytotheextentth4tthepollutant Isnotremoved.) (c)vnenapDllcable (forexampl~,whenthepollutant represents 4classofccmpounds), 4demonstration ottheextenttornlcntheDollutant5 IntheIntakeveryphyslc4!Iy,chemically, orbiologically tranthepollutant5contained Inyourdischarge. (Yourlimitations riIIbeadJusteoonlytotheextentthattheIntakepollutants dOndtVaryfraathedlSCharged DOIlutentS~)Ifyouhavetroormoresubstantially indentlcal outta(15, youmavrequestpermission franyourpermitting authority tosmnpleandanalyzeonlyoneouttalland5ubmlttheresultsottheanalysistorothersubstantially ~dentlqaiOutfallS. IfyaurrequeatISgrantedbythepermitting authqrity, OnaSeparateSheetattaChedtOtheapplication termtdentifyvhlchoutfallyoudidtest,anddescribevhytheouttallawhichyoudidnottestaresubstantially identical totheoutfallwhichyoudldtest.36 SEEINSTRUCTIONS ONREVERSESIDESECT1ONlIPERMIT~MIOQOS827NUMBEROODoPRIORITYPOLLUTANTS ANDADDITIONAL INFORMATION FORSURFACEWATERDISCHARGE ONLYTHEFOLI&IINtt RSXESTKDIIHRWTION ~sAIXJIESSED SEJMQJIFACEHATERDISDWJXIKRS>> EJTE)NBfUSKDISOwXIERS 2JBLLPROVICEKPPKCIKDVALIKSFCRTHEIXJANflTATIVE ANDIXWLITATIVE INFORIWTICN REIXKSTED BEIJJI>>AeISTHISFACILllVAPRIMARYIMXJSTRY? (RKFBITOTABIEIAPJGK+(IFW,GOVO )(IFYSGOTOB)BeINDICATETYPECFPRIIWIYIMXJSIRYASLISTEDINTABJEIAPA%Q.ICCNTIMKHIIHC.)CeGOESTHISOUIFALLDISCHARGE CNTAIKANYPROCESSHASTKHATKR? (IFMrGOTOE)(IFYES>GOTOD)DeIWICATKNIICHGt'JHSFRACTICNS MJSTBETESTEDFOR>>(RKRRTOTABLEIAPJVKJII)IDIEIFCREACHGt'JHSFRACflONOtKCXKD>EAOISPECIFICORGANICTOXICPOUJJTANT HIIHINEACHFRACTIONt$5JBEANALYZEDFOR(SEETABLEIIAPAGE92~INADOITI0I> ALLPRII>>ARYIIClJSTRY APPLICANIS HITHAPROCESSIWSTKHATKR DISCHARGE ggJPROVIDEOSWTITATIVE IWTAFCREARTHTOXICPOLJJJTANT IHlAKEIIIAPAfE~~eRKcRDAIJ.DlrAoNF0YtsPROVIDED(ITEM7)INTHISBoozer.(CNTIMKHITHEKBKIJBI)LECWRQ~>>emAnalysisPerQer>dere>re J.B.Beauboeuf TargetPermitPre,eEffluentLimitsPESTICIDE KeIFJKg,QRFJcEHATERDrsowRGKAPPLIGANT (PRIIwRY0R$Kc06NYIMxrsTRY)> RKGARKLEss OFTHEIVPEOFDISCHJJYIK>r EM'RIWSREASONTOBKUKVKTIWTANYPOIJJJTAHT LISTKDINTAKEIIAANOIVAPAGES4JL9XlsDISCHARGED FR0tJHYOJIFAL4TIC IXJWTITATIYE DATAggjfBKPRKIVIWhRECRDALLDATA01PORCPROVIDED(ITKH7)IN1HIS$00ZkT>>FeIFNfQRFJCKlWTKRDISCJWRGE APPLICANT (PRIIWIYORSEQÃCNIYIIKtJSIRY)> RKGJJOXKSS OFTYPEOFDISCNVIGK> IMEfsORHISREISCNTOBKUEVEAHYPOIJJJTJHIB USTEDINTAKEVAPAGE~AREDrsftwXMFR01ANYtJJfFAJJ. TIEAPPUCJItf rrrKL(DESCRIBEREASONSI0tTIEPOIJJJTJHT BEI16PRKSBITJJKJPROVIDEJJIIAVAILABLK QOWTITATIVE DATA>>REcRDILLDATA01F0wsIROYIKED(ITBI7)INTHlsBOOLEY>>GeAIJ.SLRFACEIW18tDISCHNXIE APPUCJNIS (PRIMARYAWSKCOIJJtf IHIXISlRIKS) 0RfgFAcrtNKs 2>4>f~lllrcJKJ$ 4%%wxYAcKrrcAcID(2>4>M)J.JI,WIRIDKJxtsPINwxr PR0Ic(srLttKx, 2,rr,5,TP)~Pr>TRIKMJXKPIEMN (T~KPIcRHBIAaacl4%1RK Nfr(AIJDlTAF0tTl%AlotKISJSTBEGIMRATKDIIIMISTAwJRDawmcALCJUIYIAT10t ProCBXNKS) ORl0l$tsORHA5REASCNTOBELIEVETHlrTCKD1$0tHIYBEPRKSBITINT%1RDISCHARGE>> RKP0IT>>XJAUTATIVE DATA>GE%RATKDHfrCHtgiKDASCRKKHlwPwCKDIJIK wTTKDHITHAJWLmCJLSTAwARDS, FORz.a,I8,-TKIRJCJKJJIKXJIM~IOXIN (TCD)eRECISIDALLDATA0lF0YtsPROVIDED(ITBI5INTHISBOOLEY>>IFIIEQJIFACEHATERDISCJWRGE APPLICJWf XMloORIWSRKISCNTOMUEVK%lrBIOIJXIICAt TOXICITYTESTSHEREHADEINll%LASTlINEE(5)YEARSOIANICFTIEAPPLICANT 5DISOWNIKS ORONARKCEIVIWHATBtINRKLAT10ITOADISCIWSKs PROVIDETHtsIIRNHAT104 ASANATTAOIKÃf TOTH15APPUCAT101>> XIFACNRACtthtCRAT0IY CRKKYIILTIW Fl&PBRÃIEDJJN'OFT%AMAVSKSRKIXJIRKD BYTHISAPPLICAT101> PRCNIDETIENt%AMJAKKNESSOFEAOILAB0IATDIY ORFIIIIAWTIEAWLYSESPKRFIR%DASANATTAKJI%HT OFTHISAPPLICATION>> 1.>>00VIXIDISOWEIKANYOIIERTOXICCRIILXNIIXJS DKHICALSlaSTJNCKS WrLISTEDIHTAKESIYPAGEttAWIIATINOAIVAPIPES~~IFVK5>TISHIOBIflsYTIEIJKMICALQSISTAWKS AOESTIHATETIEFINILKFFLIKHTC0CBIIRAT10IS ~QJ>>HITTHISIIARQTICN ASANAITAOtKtlT IO'HISAPPUCATION> Qrrrrrr>uoar/ear>>re remrr.N/AaPRESKHf/DATA lsATTAIMDwrAPPUCABLdBKLIEYKD ABSBITN/A0PRESENT/DATA ISATTADEDwrAPPUCJBLFJBKUEVKD ABSENTN/AQPRESENT/DATA ISATTADEDgwrAppucABLE QAPPuCABLE?'SKE AITADED.QwrAppucABtz g]APPLICJBLe'SKE ATTADNDQXwrJppucABtz APPLICABts/SKE ATTAKJND INSTRUCTIONS FORC04PLETING SECTIONIIITEM6ThisformrequiresInformation onasoeciflcoutfalIdischarging tothesurface>>stere. ENTERTHEPERMITNUMBERINTHEBOXATTHETCPOFTHISFORM.THEPERMITNWBERCANBEFOUNDCNTHEFRONTPAGEOFYOUREXPIRINGpERHIT.Itthisisane>>ornotorevlously permitted

facility, thenleaveblankandanuroer>>ill beassigned.

EntertheoutfallnumberInthespaceorovldedforeachpageofSectionII.ForeachIndividual discharge pointaseparatesetofSectionII,Item6formsmustbefilledout.ITEM6PRIORITYPOLLUTANTS ANOADOITIONALINFOPHATIONNOTE:NOTE:lfyouhavetroormoresubstantially Indentical outfalls,youmayrequestpermission frcmyourpermitting authority tosamoleandanalyzeonlyoneoutfallandsubmittheresultsoftheanalysisforothersubstantially Identical outfalls. Ityourrequest159rantedbythepermitting authority, onaseoaratesheetattaChadtotheapplication formIdentifyrhlchoutfallyoudidtest,anddescribemytheoutfallsrhlchyoudidnottestaresubstantially Identical totheoutfallrhlchyoudidtest.40CFRPartI22.2l(g)(8), Friday,AbriII,l98S,providesforaSmallBusinessExemption fromthereporting ofquantitative datafororganictoxicpollutants andtoxicpollutants asrequiredbyPertl22.2I(g)(7)(ll)(A) or122.2I(g)(7)(lil)(A). A.K.Thesepartsareself-explanatory anddonotrequirefurtherInstructions. SimplygothrougheachpartanddoasIndicated. andE.-J.0.SeveralIndustrial categories andsubcategories havebeenexemotedfrtmsubmitting dataoncertainGC/MSFractions (40CFRPartl22,Vol.48,No.64,Friday,AprilI,lgBS,NotesI,2,andS).~Revle>>thefolio>>lng listtodetermine>>bather yourfacilityqualifies tobeexceptfreereporting GC/MS(GssChrcnetogrsphy/ MassSpectroscopy) Fractions. GC/MSFractionTestingandReporting Exemptions TextIIeillIIsIndustry-AllfourGC/HSorganicfractions IntheGreigeHillsSubcategory. -Pesticide fractionInelIothersuboartsofthisIndustry. OreHlnlnandOresslIndust-Volatile, base/neutral, andpesticide fractions IntheBaseandPreciousHetalsSubcategory. -AllfourGC/HSorganicfractions Inallothersubcategories ofthisIndustry. GunandUoodChemical~Industrpesticide fractionintheTaliOilRosinSubcategory andthehos(nBasedOerlvatlves Subcategory. -pesticide andbase/neutral fractions in~liothersubcategories ofthisindustry. PulandPaperIndust-Pesticide fractionInPaoergrsde Sulfitesubcsteqorles (suboarts Jand0).-base/neutral andpesticide fractions lnoeinksuboart0,olssolvinq KraftsubpartF,andPaperboard fromvast<<Paper SubpartE.4-Volatll~,base/neutral ~pesticide fractions IntheOCT8)cachedKraftSubOartN,Seelmhcmical Subparts8andC.,andNonlntegrated FinePaoersSubpartR.'c-Acid,base/neutral, andoestlclde fractions InFine4)cachedKraftSubosrtI.oissolvlng sulfitePuloSuboartK,Ground->>OOdFinePapertSubOart0~NarketOleaChedKraftSubpart0,TISSuefraeUaStepaper SubpartT,andNOnlntegrated QSSuePapersSubpartS.'teamElectricPo>>eraslantIndustHaterFlyAshandOottt4eAshTransport Materprocess>>astestreams 38 oi'~~~'lI~~~~~',~~'~C'.~~O'~'I~~'~O'~~~'I~)I~;r'~Ol~~I)'~'I'~~l~'I%)I)~~~~~~'~~'j)BE~~IIII'I~)~I~~~\'I~o~~I~~I~1~'~'~IIJj~~I~~I~)~'~~I~~~~~~'I~r~I~1~I~((I.~C~~I~1'~I~~''I~1~I~~I~1'~I~~~~~C~I~~I~~I~1~I~~I'~I~1~I~~Ie'~~'~I~~~~C'~~1~I~~Ie)~I~I~~I~~~~~I~1~I~~I~~II~I'~~~~~~~~~~rj.~~~'~e)I~'IW~'~~I)lS>;I~~~~~~III~~~~~~~~~~~~~~~~~ INSTRUCTIONS FORCCMPLETIHG SECTIONIIITEM7ThisformIstobeusedbybothSurfaceandgroundvater applicants torecordInformation onanyHlchlgancriticalmaterial, E.P.A.prioritypollutant,orhazardous substance InvhlchthisappIlcationrequiresdatatobeprovided. ThisvouldIncludeanychemicalsubstance frantneHlchlganCriticalMaterials RegisterITabl~IV),theE.P.A.PriorityPollutant Listing(TableV),orTablesIIA-VAvhlonIlatSOrganlCTOXICPOIlutantS,OtherTOXICPOIlutantS,COnVentlOnal andHcnocnVentlonal POIlutantSandHaZardOuS Substances. ITEM7CRITICALMATERIALS, PRIORITVPOLLUTANTS AHO/ORHAZAROOUS SUBSTANCES INTHEDISCHARGE MaterialI,2,3...8A.Listthinameotthechemicalsubstance (critical

material, prioritypollutant, orhazardous substance) franTablesIV,VandIIA-VAasreoulradIntneboxmichyoucheekedInA.I-3,above.Entereachchemicalsubstance's paneeternumberaslistedInTablesIV,VandIIA-VAlfProvided.

B.Providetheaverageconcentration otthechemicalsubstance nanedInA.Indicatethesampletypeusedandthenumberofanalysesmadetoprerldetheconcentration dataforthechemicalsubstance nmnedInA.C.Providethemaximumconcentration anddetermine themassloadingotthechemicalsubstance nmmzdInA.HOTES:I.2.Itonlyoneanalysisuasmadeforachemicalsubstance thenrecordthatdataasamaxisxzsvalue.Itmorethanoneanalysishasbeenmadetorachemicalsubstance thenprovideanaveragevalueotthoseanalysesandthemaximusvalue~ThisSectionII,Itea1,OataSheetprovidesspaceforrecording datafor8chemicalsubstances IMaterlals). Additional spacetorrecording ofdataformorethan8Materials canbemadebymakingcopiesofthisItem1OatsSheetasneeded.Itlsalsoimportant touseaseparatesetofOataSheetsfoteachappllcabl ~reporting reculrmaent aslistedInA.l3.andtoreachouttali~3.Ratertothelettmargintorthecodenumberrepresenting thesmapl~typeusedandtheappropriate unitcodes. Loci<heed Analytical ServicesINDIANAMICHICANPOWERCOMPANYSAIVIPLEANALYSISSUMMARYPACKAGEFORVOLATILEANDSEIVII-VOLATILE

ORGANICS,

-PESTICIDE/PCBS,

CHLORIDE, NITRATE/NITRITE, SULFATE,FLUORIDE, CYANIDE,IVIETALS, ANDMERCURYLOG-INNUMBER:QUOTATION NUMBER:L1009Q331620DOCUMENTFILENUMBER:1229485

~toe/rheed elL'/a~a7rllce~rv"l.s)'ar~-r"<<~~~~~~LockheedAnalytical Services975KellyJohnsonOriveLasVegas,Nevada891194705 Phone:(800)3614220Fax:(702)361~February4,1994Mr.RockyBeemCookNuclearPlant1CookPlaceBridgeman, Ml49106RE:Log-inNo.:Quotation No.:DocumentFileNo.:L1009Q3316201229485Theattacheddatapackagecontainstheresultsofanalysesonsamplesthatweresubmitted toLockheedAnalytical ServicesonDecember29,1993.Thesampleswerereceivedat5'C.SUMIVIARY ANALYSISSTATEMENT: Inorganics Allgroundwatersampleswerereceivedingoodcondition, onDecember29,1993.Allsampleswereanalyzedwithinthemethod-specific holdingtimes.Themethodblankswerefreeofcontamination. AllInternalQualityControlwerewithinacceptance limitswiththefollowing exception: Thematrixspikerecoveries forbariumandseleniumwereslightlyoutsideofacceptance limits.Theacceptable recoveryoftheLaboratory ControlSamplessupportsthattheanalytical systemswereoperating withincontrollimits.Thereporting detection limitfornitritewasraisedto0.50mg/LforsampleS.SewagePlantEff.(L1009-4) duetointerferences fromchloride. OrganicsMethod8260Allcalibrations andqualitycontrolcriteriaweremetwiththefollowing exceptions: Allsampleswereanalyzed, initially withinholdingtimesbutfailedsurrogate recoveryQClimits.Thesampleswerereanalyzed onedaybeyondthemethodspecified holdingtimeandallsamplesmetsurrogate recoveryQClimits.Tentatively identified compoundsearcheswereperformed onallsubmitted samples.Onlythereanalyses arereported. COOKNUCLEARFebruary4,1994PAGE2Method8010/8020 Allcalibrations andqualitycontrolcriteriaweremetwiththefollowing exceptions: Thematrixspikeandmatrixspikeduplicate precision for1,1-dichloroethene exceededtheQCcriteriaalthoughallpercentrecoverycriteriaweremet.Dataqualityisnoteffected. Method8270Allsampleswereextracted andanalyzedwithinthemethodspecified holdingtime.Allinitialandcontinuing calibration criteriaweremet.Bis(2-ethylhexyl)phthalate wasdetectedinthemethodblankat1.3ug/L.Therewasnoothercontamination detectedinthemethodblank.Percentrecoveries forallsurrogate compounds waswithinQClimitsforallsamplesanalyzed. Alaboratory controlsample(LCS)andlaboratory controlsampleduplicate (LCSDUP)waspreparedandanalyzedwiththissetofsamples.Thepercentrecoverycriteriaforallspikedcompounds waswithintheQClimitsaswastherelativepercentdifference betweenthetwo.Theresponseforbis(2-ethylhexyl)phthalate insampleTRANS.CATCHBASIN exceededthecalibration rangeintheinitialanalysis. Thesamplewasreanalyzed atadilutionof1:4andallcompounds fellwithinthecalibration range.Bothsetsofresultsarereported. Method8080AIIsampleswereextracted andanalyzedwithinthemethodspecified holdingtime.Allinitialandcontinuing calibration criteriaweremet.Nocontamination wasfoundinthemethodblank.Fewofthesurrogate spikerecoveries werewithintheQClimitsduetoanapparentspikingsolutionproblem.Dataqualityisnoteffectedsinceallpercentrecoverycriteriaweremetforthelaboratory controlsampleandlaboratory controlsampleduplicate. Notargetcompounds weredetectedabovethereporting detection limitandtherewasnodilutionorreanalysis performed. Ifyouhaveanyquestions concerning theanalysisorthedatapleasedonothesitatetocontactJamesL.Jordan,(702)361-3955. ext.289.Releaseofthisdatareporthasbeenauthorized bytheLaboratory DirectorortheDirector's designeeasevidenced bythefollowing signature. ncerely,JamesL.JodanClientServicesRepresentative JLJ/atcc:ClientServicesDocumentControlDepartment ~Wc/rheed LockheedAnalytical Services975KellyJohnsonDriveLasVegas.Nevada89119-3705 Phone:(800)582-7605Fax:(702)361%146February17,1994Mr.RockyBeemCookNuclearPlant1CookPlaceBridgman, Ml49106

DearRocky,

Peryourrequestduringourphoneconversation thismorning,thefollowing isanexplanation oftheprocedure usedforthedetermination ofthenon-standard organiccompounds inyourgroundwater samples.Thesampleswereanalyzedusinginstruments thatweresetupforstandardmethods8260and8270.Afewofthecompounds onyourlistsofanalytesarenotstandardmethod8260or8270compounds. Oncethesamplesareanalyzedandachromatogram wasobtainedforthesamples,allpeaksthatwerepresentinthesamplesthatdidnotcorrespond tooneofthecalibrated compounds wereinvestigated further.Thisinvolvedtakingthemassspectraobtainedfromthesepeaksandcomparing thespectratoanNISTlibraryofspectra.Thislibrarycontainsapproximately 52,000knownmassspectra.Themassspectraoftheadditional analytesofinteresttoyouarecontained withinthislibrary.Noneofthenon-standard analytesweredetectedinanyofyoursamples.Forthenextquartersroundofsampling, weareendeavoring toobtainthestandards forthesecompounds sothattheywillbecalibrated forintheanalysesofthosesamples.Ifyouhaveanyfurtherquestions orifIcanbeofanyfurtherassistance, pleasedonothesitatetocallmeat(702)361-1626ex.289.'ncerely, JamesL.rdanProjectManagercc:M.Butler I~4~4gIg~~~Ir~IIr~'ll~I'll'I'I~..I'.~I'I~I'III~I'~~~~'~,III~I'II~II~~~II'I~~~I~I'I'Ir'III.I~I.IIIII~~~II~I'~~~I~I'II'.~~I~~~~~~~~~~~~~I~I~~r~~~I'~~~~~~~~~~I~'~r~II~~~I~~~'~~ ai~a~~~~~~~~I~III'~'~I~~~~I~III~'~~~~'II'~II'II~'~I'~~~III~I~II~~II~III'~I~I~II'III~IIII'I~~~~~~~.II~~II~II'III'I~~IIII~~'II'II~~~~~~I~~~II~~~'~I~~~~II~ VOLATILEORGANICANALYSISRESULTSGC/HALLANALYSESUSINGEPAMETHOD8010linmIID:TRDaoil:2-DDateAnalzed:04-JAN-94 Matrix:WATERAnalticalBatch¹:122093-801020-0-3 LALmlID:L1DRiv:-DDilutionFactor:1QCBatchID:122093-801020-0-3 BCMBFBrroRvr11492Limi65-12560-120Constituent DihlriflrmhanhlrmhnVinIchlorideBrompmethanehirhnTrihlrflrmhn11-Dichloroethene Methlenechlorideran-1-Dihlrhn11-DichlrhanChloroform 111-Trichloroethane rnrhlri12-DihlrhnTrichloroethene TCE12-Dichloro roaneBrmihlrmhn2-hlrhIvinIhercis-13-Dichloro roenetrans-13-Dichloro roene11-TrihlrhnTerhlrhnPDibromochloro methaneChlorobenzene Brmfrm112-TrIrhn13-Dichlorobenzene 14-Dichlorobenzene 12-Dichlorobenzene Concentration Iyg/L)<0.50<3<6<4<0.5<0.5<0.5<2Reporting Detection LimitIL0.50.50.5DataQualifier(sl LOCKHEEDANALYTICAL SERVICESAVsJ VOLATILEORGANICANAlYSISRESULTSGC/PIDANALYSESUSINGMETHOD8020linmIID:TRDII:2-DEDateAnalzed:04-JAN-94 Matrix:WATERAnalticalBatch¹:122093-801020-0-3 LALmIID:L1DRiv:2-DEDilutionFactor:1QCBatchID:122093-801020-0-3 TFTBFBrroRever9495Limi70-12075-120BenzeneT'InConstituent Concentration IL0.52Reporting Detection LimitIL0.5DataQualifier shirnnEthIBenzenem-Xlene-XIn1-'n14-Dichlorobenzene 12-Dichlorobenzene <2<2LOCKHEEDANALYTICAL SERVICESh4 VOLATILEORGANICANALYSISRESULTSGC/HALLANALYSESUSINGEPAMETHOD8010linmlID:TR-ADII'-DEDateAnalzed:04-JAN-94 Matrix:WATERAnalticalBatch¹:122093-801020-0-3 LALmIID:L1DR'v:2-DDilutionFactor:1QCBatchID:122093-801020-0-3 BCMBFBrrRvr'/12086QLimi65-12560-120Constituent DihloriflurmhanhlrmhnVinIchlorideBromomethane hlrhnTrihlrflrmhn11-Dichloroe henMethlenechloridern-1-Dihlrhn11-DihlrhChloroform 111-Trichloroethane rnrhlri'l2DihlrhnTrichloroethene TCE12-Dichloro roaneBrmoihlrm hn2-hlrhlvinlhrcis-13-Dichloro roenetrans-13-Dichloro roene112-TrihlrhnTerhlorhnPEDibrornochlorome haneChlorobenzene Brmfrm11-Trhlrhn13-Dichlorob nzene14-Dichlorobenzene 12-Dichlorobenzene Concentration (yg/L)<0.50<3<6<4<0.5<0.5<2Reporting Detection Limit/L0.50.50.5DataQualifier(s) LOCKHEEDANALYTICAL SERVICESnr.Vv VOLATILEORGANICANALYSISRESULTSGC/PIDANALYSESUSINGIVlETHOD8020linmIID;TRS-AALmlID:1DII-DEDRiv:2-DDateAnalzed:04-JAN-94 Matrix:WATERAnalticalBatch4'22093-801020-0-3 DilutionFactor:1QCBatchID:122093-801020-0-3 TFTBFBrrRvr97QLimi70-12075-120BenzeneTiunConstituent Concentration IL0.53Reporting Detection Limit/L0.5DataQualifier shlrnnEthIBenzenem-Xlene-Xin1-Dihlrnn14-Dichlorobenzene 12-Dichlorobenzene <2<2LOCKHEEDANALYTICAL SERVICES06 ~~i~~~a~~o~~~~~~.~~..~~.~o~~~~....~~~~I'~~'~e.I~'>e~~~~0s.)~I>o~~~~~~I~~~J~~~'~~~I~~~~~~~~~~~~~~~..~~..~~~~~~~~~~~~~~~~~~~~~~~~o~~~~s~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~-~~~~~!~~~~ VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260ClientSamleID:TRSLALSamleID:L1009-41Page2of2Constituent Dibromochloromethane hlrnznEhInznm-Xleneo-XlenernBromfrm1122-Tetrachloroethane 13-Dichlorobenzene 14-Dihlornzn12-Dichlorobenzene Concentration IL<5<5<5<5<5<5Reporting Detection LimitILDataQualifier sLOCKHEEDANALYTICAL SERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260TENTATIVELY IDENTIFIED COMPOUNDS ClientSampleID:TRSDateReceived: 29-DEC-93 Matrix:WATERAnalytical Batch:011094-8260-F2 LALSampleID:L1009%1DateAnalyzed: 114AM-94DilutionFactor:1QCBatchID:011094-8260-F2 Tentatively Identified CompoundEstimated Concentration Iyg/L)(10Retention TimeIminutes) 0.00DataQualifierls) LOCKHEEDAIVALYTICALSERVICES ~0JI+aa~~I~~~-~~III'.~-~~~~.....~~I~~~~~~.~~I.~I~I~~~~~~a~'~~~I~~~~~~~~~~~~~-~~~~~~s~~~~~~~~I~~-~~~~~~'~~-~~~.s~~~~~~~~~~~~~~~~~~~~~~I0~~~~~~~~I~~~~~~~~~~I~~~~ ~i~~J~~~~LJ~~~~I~-~~'--~~~~~~~~a~~~~~~~~~~~~~~~~- VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260TENTATIVELY IDENTIFIED COIVIPOUNDS ClientSampleID:TRS-QADateReceived: 29-DEC-93 Matrix:WATERAnalytical Batch:011094-8260-F2 LALSampleID:L1009%3DateAnalyzed: 114AN-94DilutionFactor:1QCBatchID:011094-8260-F2 NONETentatively Identified CompoundEstimated Concentration Iyg/L)(10Retention Time(minutes) 0.00DataQualifier(s) LOCKHEEDANALYTICALSERVICES20 SElVllVOLATILE ORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270IinmIID:TRDateCollected: 28-DEC-93 Matrix:WATERAnIiIBh¹:ill4-7-8QCBatchID:8270-SEMI VOLATILES-3964 LAmIID:1-2DateReceived: 29-DEC-93 DilutionFactor:1Dxr4-AN-4DateAnalzed:11-JAN-94 P1f2SURROGATE RECVERY0/2-FluorohenolPhenol-d, Nitrobenzene-d, 2-FIuorobi henI24-TribrmhnIp-Terphenyl-d,4 4126595599QCLimits21-10010-9435-11443-1161-1233-141PhenolninConcentration L<10Reporting Detection LimitL10DQbis2-Chloroeth Iether2-hlrhnl1-Dihlrnzn14-Dichlorobenzene BenzIalcohol1-Dihlrnn2MhIhnIbis2-Chloroiso roIether4-MethIhenolN-Nir-Di-n-roIminHxhlrhnNitrobenzeneIsohorone-NirhnI24DimehIhnIBenzoicacidbis2-Chloroethox methane4DihlrhnI14-TrihlrnznNahthalene4-Chloroaniline Hxhlrin4-hlr--mhIhnI2-MethInahthaleneHexachloroc cloentadiene <10<10<10<10<10<10<10<10<10<50<10<10<10<10<1010101010101010501010101010LOCKHEEDANALYTICAL SERVICES4v ~e~~J~I~~:~~.I~I'~~.~~~~~~~~II~~~~~~~~~e~~~I~~~~~~~~-~~~~~~~~~I~~~0~~~~~~~~~~~~~~~~~o~~~e~~~~~~e~~~~~~~~'~P VOLATlLEORGANICANALYSlSRESULTSFORANALYSESUSINGIVIETHOD8270TENTATIVELY IDENTIFIED COIVIPOUNDS ClientSampleID:TRSDateReceived: 29-DEC-93 Matrix:WATERAnalytical Batch:011194-8270-B LALSampleID:L1009-25DateAnalyzed: 11-JAN-94 DilutionFactor:1QCBatchID:8270-SEIVIIVOLATILES-3964 UnknownUnknownTentatively Identified CompoundEstimated Concentration (yg/L)10020Retention Time(minutesl6.4430.26Data-Qualifier(sl LOCKHEEDANALYTICALSERVICES31 ~i~P~~J~~PI~'~-~~a~I'.-~.~~~-...~~~.~~)~~~PI~~a~~~~P.~a~)P~~~~\I~~~'~~~~~~~~~~~~~~~~~~;:~~:.~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~s~~~~~~~~~~~~~~~~~~~I~~~~~~~ ~k~0li~~~~IP~~)~~'~I~~~~~..~~~~~~'~~~'~~~~~~~~~~~~~e~~~~~~.~~~~I~~~~~~~~~~~~~~~~~I~~a-~~'~I~~~~0~~~~~~~~ VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8270TENTATIVELY IDENTIFIED COMPOUNDS ClientSampleID:TRS-QADateReceived: 29-DEC-93 Matrix:WATERAnalytical Batch:011194-8270-8 LALSampleID:L1009-27DateAnalyzed: 29-DEC-93 DilutionFactor:1QCBatchID:8270-SEMIVOLATILES-3964 UnknownUnknownTentatively Identified CompoundEstimated Concentration (yg/L)100Retention Time(minutes) 5.286.44Data..Qualifier(s) Hydrocarbon UnknownHydrocarbon Hydrocarbon Hydrocarbon 2029.9730.2631.9832.9433.86LOCKHEEDANALYTICAL SERVICES PESTlclDE ANALYSESRESULTSBYGC/ECDUSINGMETHOD8080FORCOOKNUCLEARPLANTClienSamleID:TRDaeColleed:28-DE-9DateExtracted: 04-JAN-94 Matrix:WATERAnalticalBatch¹:012094-8080-A-1 LALmIID:I1-17DaeReceive:29-JAN-4DateAnalzed:21-JAN-94 DilutionFactor:1QCGrouID:8080PEST/PCBS 3965SURROGATE RECOVERYooTCMXDCB52'CUmits60-15060-150A-BHCB-BHC-BHD-BHCConstituent Concentration /L<0.05<0.05Reporting Detection Limit/L0.050.0.05DataQualifier(s) HEPTACHLOR ALDRINHEPTAHLOREPOXIDEG-CHLORDANE ENDOSULFAN IA-CHLRDANE44'-DDE44'-DDTDIELDRINENDRINENDOSLFANII44'-DDDENDRINALDEHYDEENDOLFANLFATEMETHOXYCHLOR TOXAPHENE PCB-1016PCB-1221PCB-12PCB-1242PCB-1248-PCB-124PCB-120TECHNICAL CHLORDANE MIREXTCMX-tetra-chloro-meta-xylene DCB-Deca-chloro-biphenyl <0.05<0.05<0.05.5<0.1<0.1<0.1<0.1<0.<5<0.10.050.050.050.0.10.10.10.10.10.<0.1LOCKHEEDANALYTICAL SERVICES5' ~II~~~~~III~0~~-~e~~.III'..~-.~~~~~'~~e~~'~I~~~~~I~~~~~~~~~~I~II~I~I'~~~I~~III~I~I~~~~~~~~'I~~~~~~~~~~~~~~~~~~I~I~I~I~I~~~I~I~~~~~~~~~~'~~~~~~~ ~~~..~~~.::::~~~~~'~~~~R5%gggg~gpss~%%~55%~gggg$gg~55%~55%~gpss~55%R55%RE%R55%g$gg~gpssR5%R%%~55%g$@g555%R55%R5%~~~~~~~~~~~I~~I~~~~I~~II~~~~~~I~~~~~~~~~~'I~~~~~'~~~~~~~~~II~~~~~~~~~~~~~~~~~I~~~I~~I~~I~~I~~II~~~~~II~~~~~~~I~~~~~~I~~I~~~~~.o:~~~'~~~~~~~~'~'~~I'~~I'~~~~~'~'~~~'~'~~~'~~~~~'0~~~~'lIll'~0~~II'I~'~'I'~'~l' METALSRESULTSClientSamle'ID!'TRS-QA LALBatchID(s):1220imDate.Collected: 12-28-93DateReceived: 12-29-93Matrix:,round;water. '0469095-040-3N .<<?,')'yCo'nstitu antsAluminumAntimonArsenicBariumBeiliumBoronCadmiumChromiumCobaltCoerIronLeadManesiumMananeseMercuMolbdenumNickelSeleniumSilverSodiumThalliumTinTitaniumVanadiumZinc-."Method 6010602060206020602060106020602060206020601060206010602074706020602060206020601060206020601060106020Concentration" imILl<0.20<0.060<0.010<0.20<0.0050.27<0.005<0.010<0.050<0.025<0.10<0.003170.027<0.0002<0.20<0.0400.0078<0.010890<0.010<0.20<0.10<0.0500.022Reeportlng Detection" UmltlmILl0.200.0600.0100.200.0050.200.0050.0100.0500.0250.100.0035.00.0150.00020.200.0400.0050.0105.00.0100.200.100.0500.020Data~QualWer(s) NNDate'.~'-A'naled,N01-20-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-20-9401-27-9401-07-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-27-9401-20-9401-20-9401-27-94?0':;;:;.L'ALcr.""S"le'1D)L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14Comments: LOCKHEEDANALYTICAL SERVICES 0~..~:-~~~~~~~~I~~~~~~~tggRRQiittgQiittggpitiigQiittg~~~~~~~~~I~~~~~tt~~~~~~~~~~~~~~~~NIIRÃ8~~'~~'~~~~~~~~~~~~~~~~'~~'~~~'~~~' GENERALCHEMISTRY RESULTSClientSamleID:TRS-QALALBatchID(s):1229imDateCollected: 12-28-93Matrix:roundwaterDateReceived: 12-29-93PO¹69095-040-3N Constituent Fluoride. inmILChloride. inm/LNitrate-Nitro en,inm/LNitrite-Nitro en,inmILSulfate.inm/LAmmonia.Nitrogen, himILTotalCyanide.inmg/LMethod340.2300.0300.0300.0300.0350.1335.2Result0.31200.90<0.01222003.4<0.020Reporting Detection Limit0.150.0160.0170.0120.590.0500.020DataQualifieris) D(1:10)DateAnalzed,01-24-9412-29-9312-29-9312-29-9312-29-9301-05-9401-03-94LALSamleIDL1009-2L1009-2L1009-2L1009-2L1009-2L1009-6L1009-10Comments: LOCKHEEDANALYTICAL SERVICES66 GENERALCHEMISTRY QCDATASUMMARYLALBatch}D(s}: 1229imQC'SamleAnalses-Constituent ClientSample,IDLALSampleIDDateAnalyzedReagentBlankDuplicate Precision (%RPD}Matrix"Spike.Recovery(%}Fluoride, inm/LChloride, inmg/LNitrate-Nitrogen, inm/LNitrite-Nitro en,inm/LSulfate,inm/LAmmonia-Nitrogen, inm/LTotalCyanide,inmg/LTRSTRSTRSTRSTRSTRSTRSL1009-1L1009-1L1009-1L1009-1L1009-1L1009-5L1009-901-24-94<0.1512-29-93<0.01612-29-93<0.01712-29-93<0.01212-29-93<0.05901-05-94<0.05001-03-94<0.0200.20.11079193969612294NbltTheRPDcannotbec'omputed. becausethesampleortheduplicate concentration wasbelowtheDetection Limit.Comments: LOCKHEEDANALYTICAL SERVICES6n .".Halliburton NUSX5FJ++C0RP0RATI0NLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbeiis RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPageICLIENTNAME:ADDRESS:ATTENTIOH: INDIANAMICHIGANPOWERCOMPANYOHECOOKPLACEBRIDGMAN, MI49106-0000 MS.JEHILEWIS-CHEMISTRY DEPT.HUSCLIENTNO:06630020WORKORDERNO:55830VEHDORNO:05411000CarbonCopy:SAMPLEID:HUSSAMPLENO:P.O.NO.:TURBIHEROOMSUMP27476P025928469034-040-3H DATESAMPLED:30-DEC-93 DATERECEIVED: 05-JAN-94 APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMIHATIOH RESULTUNIT117302AHAW31130415905AALWSulfate,Turbidimetric (asS04)Sodilsllt Total(Na)Chloride(asCl)Solids,Dissolved at180CAtuminun, Total(Al)51mg/L6.3mg/L11mg/L140mg/L0.97mg/LCOMMENTS: A;"';Halliburton NUSCORPORATION LABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportHo.:00018939SectionAPage2CLIENTNAME:ADDRESS:ATTENTION: INDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAN, MI491060000MS.JENILEWIS-CHEMISTRY DEPT.HUSCLIENTHO:06630020WORKORDERNO:55830VEHDORHO:05411000CarbonCopy:SAMPLEID:NUSSAMPLENO:P.O.NO.:TURBINEROOMSUMP27476/FILTEREDP025928569034-040-3N DATESAMPLED:30DEC-93DATERECEIVED: 05'JAN-94 APPROVEDBY:Kieda,ChuckTESTLNCODEOETERMIHATIONRESULTUNITS1AALFAtuainua, Dissolved (At)~0.3mg/LCOMMENTS:. L'Hallibullton NUS%1K++++C0RP0RATI0NLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage3CLIENTHAME:ADDRESS:ATTENTION: INDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAH, MI49106-0000 MS.JEHILEWIS-CHEMISTRY DEPT.NUSCLIENTNO:06630020WORKORDERHO:55830VENDORHO:05411000CarbonCopy:SAMPLEID:NUSSAMPLENO:P.O.HO.:TURBINEROOMSUMP27503P025928669034-040-3N DATESAMPLED:31-DEC-93 DATERECEIVED: 05-JAN-94 APPROVEDBY:Kieda,ChuckTESTLHCODEDETERMINATION RESULTUHITS1I7302ANAW311304I5905AALWSulfate,Turbidimetric (asSO4)Sodiun,Total(Ha)Chloride(asCl)Solids,Dissolved at180CAtuminun, Total(Al)53mg/L6.0mg/L10mg/L130mg/L0.98mg/LCOMMENTS: "'.Halhburton NUSimper+++C0RP0RATI0NLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684,January18,1994ReportNo.:00018939SectionAPage4CLIENTNAME:ADDRESS:ATTENTIOH: INDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAH, MI49106-0000 MS.JEHILEWIS-CHEMISTRY DEPT.NUSCLIENTNO:06630020WORKORDERHO:55830VEHDORNO:05411000CarbonCopy:SAMPLEID:TURBINEROOMSUMP27503/FILTEREDHUSSAMPLEHOP0259287P.O.NO.:69034-040-3N DATESAMPLED:31-DEC.93 DATERECEIVED: 05-JAN-94 APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMIHATIONRESULTUHITS1AALFAluninun, Dissolved (AI)0.3mg/LCOMMEHTSt

dL'Halliburton NUSwaarC0RP0RATI0NLABORATORY ANALYSISREPORT"NUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportHo.:00018939SectionAPage5CLIENTNAME:ADDRESS:ATTENTION:

INDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAH, MI49106-0000 MS.JEHILEWIS-CHEMISTRY DEPT.HUSCLIENTHO:06630020WORKORDERHO:55830VENDORNO:05411000CarbonCopy:SAMPLEID:HUSSAMPLEHO:P.O.NO.:TURBINEROOMSUMP27506P025928869034-040-3N DATESAMPLED:01-JAH-94 DATERECEIVED: 05-JAH94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMIHAT IONRESULTUNITS1l7302AHA'W311304l5905AALWSulfate,Turbidimetric (asS04)Sodiun,Total(Na)Chloride(asCl)Solids,Dissolved at180CAtuninua, Total(Al)52mg/L5.6mg/L10mg/L130mg/L1.6mg/LCOMMENTS: h:HallibulIton NUS>mrs+++C0RP0RATI0NLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportHo.:00018939SectionAPage6CLIENTNAME:INDIANAMICHIGANPOWERCOMPANYADDRESS:ONECOOKPLACEBRIDGMAN, MI49106-0000 ATTEHTIOH: MS.JEHILEWIS-CHEMISTRY DEPT.HUSCLIENTNO:06630020WORKORDERHO:55830VEHDORNO:05411000CarbonCopy:SAMPLEID:TRUBINEROOMSUMP27506/FILTEREDHUSSAMPLEHO:P0259289P.O.NO.:69034-040-3N DATESAMPLED:01-JAN-94DATERECEIVED: 05-JAH94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMINATION RESULTUNITS1AALFAtuntram, Dissolved (At)0.2mg/LCNNENTS: '.Halliburton NUS~%F1CORPORATION LABORATORY ANALYSISREPORTNUSLA8ORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684. January1B,1994ReportNo.:0001B939SectionAPage7CLIENTNAME:ADDRESS:ATTENTION: IHDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAN, Ml49106-0000 MS.JENILEWIS-CHEMISTRY DEPT.HUSCLIENTHO:06630020WORKORDERNO:55030VENDORNO:05411000CarbonCopy:SAMPLEID:HUSSAMPLEHO:P.O.HO.:TURBINEROOMSUMP27509P025929069034-040.3N DATESAMPLED:02-JAH94DATERECEIVED: 05-JAH-94 APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMINATIONIRESULTUNITS117302AHAW311304l5905AALW6I4907l700Sulfate,Turbidimetric (asSO4)Sodiun,Total(Ha)Chloride(asCl)Solids,Dissolved at1BDCAtuninun, Total(Al)pHSpecificConductance at25C51mg/L5.9mg/L10mg/L140mg/L1.5mg/L7.6300umhos/cmCOMMENTS: '.Halliburton NUS++C0RP0RATI0NLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage8CLIENTNAME:ADDRESS:ATTENTION: INDIANAMICHIGANPOWERCOMPANYOHECOOKPLACEBRIDGMAN, Ml49106-0000 MS.JENILEWIS-CHEMISTRY DEPT~HUSCLIENTNO:06630020WORKORDERNo:55830VEHDORHO:05411000CarbonCopy:SAMPLE10:HUSSAMPLENO:P.O.NO.:TURBINEROOMSUMP27509/FILTEREDP0259291690340403HDATESAMPLED:02-JAH-94 DATERECEIVED: 05-JAH-94 APPROVEDBY:Kieda,ChuckTESTLHCODEDETERMINAT IOHRESULTUNITS1AALFAtuninun, Dissolved (At)0.3mg/LCOMMENTS: "Halliburton NUS%118+++C0RP0RATI0NLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlea,Suite2005313CampbeHsRunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage9CLIENTNAME:ADDRESS:ATTENTIOH: INDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAHt MI491060000MS.JEHILEWIS-CHEMISTRY DEPT.HUSCLIENTNO:06630020WORKORDERHO:55830VENDORHO:05411000CarbonCopy:SAMPLEID:HUSSAMPLENO:P.O.NO.:ABSPONDCCMP.P025929269034-040-3N DATESAMPLED:31.DEC.93 DATERECEIVED: 05-JAH94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMINATION RESULTUNITS1I7302ANA'W31130415905AALWSulfate,Turbidimetric (asSodiua,Total(Na)Chloride(asCl)Solids,Dissolved at180CAtuainua, Total(Al)S04)110mg/L28mg/L9mg/L210mg/L0.33mg/LCOMMENTS: .4i.Halliburton NUS%1K'++C0RP0RATI0NLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh,Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage10CLIENTNAME:ADDRESS:ATTEHTIOH: INDIANAMICHIGANPOWERCOMPAHYOHECOOKPLACEBRIDGMAN, MI49106-0000 MS.JEHILEWIS-CHEMISTRY DEPT.NUSCLIENTHo:06630020WORKORDERHO:55B30VEHDORNO:05411000CarbonCopy:SAMPLEID:NUSSAMPLEHO:P.O.HO.:ABSPONDCOMP./FILTEREDF025929369034-040-3H DATESAMPLED:31-DEC-93 DATERECEIVED: 05-JAN.94 APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMIHATIONRESULTUNITS1AALFAtuninua, Dissolved (At)0.099mg/LCOIMEHTS: '.Halliburton NUS+~~~~C0RP0RATI0NLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(4'12)747-2684January18,1994ReportNo.:00018939SectionAPage11CLIENTHAME:ADDRESS:ATTENTIOH: INDIANAMICHIGANPSlERCOMPAHYOHECOOKPLACEBRIDGMAH, Ml49106-0000 MS.JEHILE'LIIS-CHEMISTRY DEPT.NUSCLIENTHO:06630020'IQRKORDERNO:55830VEHDORHO:05411000CarbonCopy:SAMPLEID:HUSSAMPLENO:P.O.HO.:ABSPONDCOMP~P025929469034-040-3N DATESAMPLEDI01.JAN.94 DATERECEIVED: 05-JAN.94 APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMINATION RESULTUNITS1l7302ANAII311304l5905AALUSulfate,Turbidimetric (asS04)Sodiun,Total(Ha)Chloride(asCt)Solids,Dissolved at180CAtuninun, Total(At)110my/L30my/L10my/L210mg/L0.35my/LCCMHENTS: .".Halliburton NUS~i@'++C0RP0RATI0NLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage12CLIENTNAME:INDIANAMICHIGANPOWERCOMPANYADDRESS:ONECOOKPLACEBRIOGMAN, MI49106-0000 ATTENTION: MS.JENILEWIS-CHEMISTRY DEPT.NUSCLIENTHO:06630020WORKORDERNO:55830VEHDORNO:05411000CarbonCopy:SAMPLEID:ABSPONDCOMP./FILTEREDNUSSAMPLEHO:P0259295P.O.NO.:69034-040-3N DATESAMPLED:01-JAN94DATERECEIVED: 05-JAN.94 APPROVEDBY:Kieda,ChuckTESTLHCODEDETERMINATION RESULTUNITS1AALFAtuninua, Dissolved (At).0.10my/LCINMEHTSt '.Halliburton NUS~%fE+++~C0RP0RATI0NLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportHo.:00018939SectionAPage13CLIENTNAME:ADDRESS:ATTENTION: INDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAN, MI49106-0000 MS.JENILE'WIS-CNEMISTRY DEPT.NUSCLIEHTNO:06630020WORKORDERHO:55830VEHDORHO:05411000CarbonCopy:SAMPLEID:HUSSAMPLEHO:P.O.NO.:ABSPONDCOMP.P025929669034-040-3H DATESAMPLED:02-JAN.94 DATERECEIVED: 05JAH94APPROVEDBY:Kieda,ChuckTESTLHCODEDETERMIHATION RESULTUNITS'II7302ANAW3I1304I5905AALW6I700Sulfate,Turbidimetric (asSO4)Sodiun,Total(Na)Chloride(asCl)Solids,Dissolved at180CAtuslnua, Total(Al)SpecificConductance at25C10031101900.5400mg/Lmg/Lmg/Lmg/Lmg/Lthos/cmCOMMENTS: ""Halliburton NUS%1gJ'+C0RP0RATI0NLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January1B,1994ReportHo.:0001B939SectionAPage14CLIENTNAME:ADDRESS:ATTEHTIOH: INDIANAMICHIGANPOWERCOMPANYOHECOOKPLACEBRIDGMAH, Ml49106-0000 Ms.JEHILEWIS-CHEMISTRY DEPT.NUSCLIENTHO:06630020WORKORDERNO:55B30VENDORNO:05411000CarbonCopy:SAMPLEID:NUSSAMPLEHO:P.O.NO.:ABSPONDCOMP./FILTEREDP025929769034.040-3H DATESAMPLED:02-JAH-94 DATERECEIVED: 05JAN94APPROVEDBY:Kieda,ChuckTESTLHCODEDETERMIHATIONRESULTUNITS1AALFAluainun, Dissolved iAI)0.072mg/LCOMMENTS: "'alliburton NUS~lP'~>~CORPORATION LABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh, Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage15CLIENTNAHE:ADDRESS:ATTENTION: INDIANAMICHIGANPOWERCOMPANYOHECOOKPLACEBRIDGHAH, Nl49106-0000 NS.JEHILEWIS-CHEMISTRY DEPT.HUSCLIENTNO:06630020WORKORDERNO:55830VEHDORNO:05411000CarbonCopy:SAMPLEID:NUSSAMPLENO:P.O.NO.:ABSPONDCOMP66998P025929869034-040-3H DATESAHPLED:03-JAM-94 DATERECEIVED: 05-JAH.94 APPROVEDBY:Kieda,ChuckTESTLNCODEDETERNINATIOM RESULTUNITS117302AMAW3I130,415905AALW8l700Sulfate,Turbidimetric (asSO4)Sodius,Total(Ha)Chloride(asCl)Solids,Dissolved at180CAtuainua, Total(Al)SpecificCohductance at25C11028101900.5410mg/Lmg/Lmg/Lmg/Lmg/Lmoos/cmCOMMENTS: ""Halliburton NUS%%TEI++C0RP0RATI0NLABORATORY ANALYSISREPORTNUSLABORATORY TwoMarquisOfficePlaza,Suite2005313Campbells RunRoadPittsburgh,Pennsylvania 15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage16CLIENTNANE:ADDRESS:ATTENTION: INDIANAHICHIGANPOWERCOHPAHYONECOOKPLACEBRIDGHAN, HI49106-0000 HS.JEHILEWIS-CHEHISTRY DEPT.NUSCLIENTNO:06630020WORKORDERHO:55830VENDORNO:054'11000 CarbonCopy:SAMPLEID:HUSSANPLEHO:P.O.HO:ABSPONDCOHP66998/FILTEREDP025929969034-040-3H DATESANPLEDI03-JAH-94 DATERECEIVED: 05JAN-94APPROVEDBY:Kieda,ChuckTESTLHCODEDETERNINATIONRESULTUNITS1AALFAluninun, Dissolved (At)COHNEHTSr 0.088mg/L SEEINSTRUCTIONS ONREVERSESIDESECTIONIIPERMIT~MI0005827~OOEEMAeLOCATIONOFDISCHLRGE S,~RECEIVIIO HATER(IE.GAOWDQTER CRN4%OFMLFACEWASANITAR2t'BSPOND.~SWt~SEJi,SOI0Ii~06.\I~065,SSE~19WDISCHARGE LOCATIONSCHEDULECIDOYOUDlSOLLRGESEASCNALLY (IFIOJCONTIIAKIOEIDeIFYESaLISTDISONKEPERIODSM)o/DLYIon/DAYFLOWRATEWASTEWATER JXBKSiQQE 1CONTACTCOOUNQ2NONCONTRCT COOLWQ3PROCESS4SANITARY5STORMWATERllHUUcQDE 1MQY2MQD3QPD[TENEIIhtDAPPLICATIONRATE,FoTYPEOFHASIBGLTER DISCHLKEGoDISCNRKSOERLE(YE/RLYAVER/GE)NAINI/HleHIe/DAYIH,/NN.~~u~~u~.'W0)IF'4~~wuLJNOLNS/DAY ~4equi~H,DISCHHLGEFUSIRATE aseona-arneTOTALYEARLYDAILYHINIISSIDAILYILLXWPI13505020372JoHAXDQIDESIQIDL5CNAXFIDIRATEeAoIEIYOLIUSEHATERTREAIIRNT AIDITIVES 1DTREATYOIRDISCNK4.(IFHG.ccNTDAEToITBI3)SeNIKFBCTICNp110OKNCALCStOSITIlS OFlfC5EAISIITIVB4DESIGNo.o6oleGtKZJQL.CalciumHochlorite forIITIE$0(DSIIDISCHVSIE FUSIRATETOSEAUllERIZEDIHPEBIITeo.o6oTREATMENT ADDITIVES 1MQ/I2UQ/ICaWICAMIACCRESSOFIWAFACARERS CFTMSEAISITIVESP VANWATERSANDROGERS,INC.1600NORTONBUILDINGSEATTLE,WASHINGTON 98104-156 DeEXPKIEDDISCHLRKCBCEHIRATICN OFAIDITIVESaHIHIISPIWITSAVIRAGEaEE~LNITSHAXIISSIWITSQXE~axK~,~0LJi~LJJ~M3~LJsanewe*TotalResidualChlorine0LJ,0ACDITIYEwteADDITIVEHL/KEaDO511TlKIT1%DINARTORBOltEAISIITIVEST FsY6IATISTIERBIVALEFFICIBCY AleDISTR%FRBSESCY2 ACOITIVEVIEIRBBVALINSo/DAYDLYS/W.,LJG,ASANATTAOPEIIT TOTHISAPPLICATICN PRESIDESPECIFICHJtNALIAH CRAQILTICTOXICDUDICAL DLTACRRERREHCENHICHAREAVAIIAILE AHDl%TSPLATIBI CNTIERATEOFDEWADATICH OFTIEPIEXICTSRSIEKHACOITIVEi b1SDSAttachedCalciumHypochlorite isaddedtothemixedliquorandisuseduppriortodischarge. INSTRUCTIONS FORCOCPLETING SECTIOIIIITEMSIANO2ThisfomrequiresInformation onthefacility's dlscnarge

location, discharge

scnedule, volumeflowrateandvotertreatment additives

.ENTERTHEPERMITIAP(B\RINTHEBOXATTHETOPOFTHISFCIOI.THEPERMITNIP(BERCAMBEFOUNOOMTHEFRONTPAGEOFYCUREXPIRINGPERMIT.IfthisIsane>>ornotpreviously permitted

facility, thenleaveblankendsnumberwillbeassigned.

EntertneoutfallncxxaarInspaceprovidedforescnpageofsectionII.ForcoonIndividual discharge pointaseparatesetofSectionliformsmustbefilledOut.ITEMIDISCHARGE LOCATIONSCHEOULEA%)FLOHRATESA.Enterthelocationofdlscnorga, thisshouldIncludequarter-quarter section,quartersection,section,town,sndrange.B.Listnameofreceiving voter(lfsurfacewaterdischarge). C.Indicatevnether(scil)tydischarges onaseasonalbasis.O.Ifyes.listdischarge periods.E.Provide'thelandappl)cation ratesusedorexpectedtobeusedintermsofInchesperhour,hoursperdoy,sndInchesperweek.Indicatethetypeofwastewater tobedischarged fromthisoutfall.Refertotherostevoter typecodegivenInthelettmargin.Morethsnonecodemoybeapplicable. G.ProvidetheaveragenurserofhoursperdovInwhichthefacilitydischarges treatedwastewater ondthetotalnumberofdaysperyearinvnlchthadlscnsrge occurs.H.Providecurrent(framthelostl2months)orexpectedflowratesssrequested. RefertounitcodedivanIntheleftmarginfortheappropriate flowunits.HGY-milliongallonsperyear)MGO-milliongallonsparday)GPO-gallonsperdsy.I.Providetnemaximumdischarge flowratewhichyourenttohaveauthorized withinthepermit.N0TE:ForNPOESpermitsonlY.theuseofsuchaflowratevillnotplaceanactuallimitrestriction ontheflowbutvillbetheflowroteusedtodevelopeffluentlimits.Also,>>nentheMonthlyOperating ReportsarereviewedbyCcmpllance staffItvillhelptheatodetermine ifanynevorincreased usesmighthaveoccurredatthefacility. J.Providethedesignflowforthisspecificoutfalldischarge (e.g.batchtreatment systemflow~packagedtreatment systemflow.orsaneotherfinitetreatment systemflow),ITEN1vATERTREATMENT AOOITIVESA.Indicatevnetherdlscnsrge Istreatedwithconditioners, inhibitors, ocmicrobiocide. Ifnot,continuetoItem3.B.Givename.function, andchemicalcomposition ofadditives used.C.Givenameandaddressofthemanufacturer(s) oftheadditives used.O.Indicateexpectedmlnlmcxe, averageandmax)mesodischarge ccncantratlons oftheadditive(s) forthisdischarge ~E.Indicatewnetneryoutreatthedischorge toremovethesddltlvelsl beforedischarge ofwastewater. F~Indlcotethereaovslefficiency ofeachadditivefranthevastevatec'nd thedischarge frequency ofeachadditivetothesurfacevoterorgroundvater. G.N0TE:ltIstheresponsibility oftheapplicant tosupplytheproductInformation ssrequested InthisItens.Information requested butnotsuppliedmayresultIntheapplication beingreturnedtothesap)Ident forcanpletlon. 32 VAHMATER.'>i~ROGERSIi(C.SAI.EI<IAlS!~r-ETYDATAS>HEFTREPORT'"JLJHBFR'7'JiISDSi'iQ:PG03J.O~="ECTIVE'!ATE:OF/2"/93.>6DIJ(.s'.r',,AlCIUi'(HYPOCi~ll0RXTE6I<AHIJI!4lkPAGE:00%VERSIOH:00~)(3RDERNO:PR(3I3HQvANWATI".RShROGERSXHC.,SLJBSXDIARYQFLINGVARi".>3.00CARIIL(3HP(3IiHTKXRKLAHD<206>889-.i400 WA98033Ei(ERGEHCYAS>8X8>TAHCEI'3REi(ERGENCYAS,TSTAHCEXO'VOLVXHGCIHFiRICALSCAIL-(".HEI'lT REC<800>42>4-9300 I=ORVICQ(3IJCTAHI3S!'.IES:r.HFORNATI(3HCONTACTYOLJRLOCA(..VANWATERSb,ROGER.>BRANCHOFFICEATVWhlkSOUTI(.I3EHI3~'L9-'i89-03~ 1~OUTHP-HllIHPRQI3LJCTNAIVE:CALCILJHHYPOCIIIORITE6RAHLJIARH.>i!8'"r::PG0:31.0CAlCIUHi-IYP0CI-Il.QRXTE6RAHULARl)A>E:rDITX(3N:1'ADEHARE:i.,'l-ICiIi-rI'iiiE/8YN:'~~0/'l93nowCALCIL)i(HYPOCHLORITE(iRA)'IL)LAi<CALl-IYP3,PTT'iCl..(3R,.".Hll(JCLO R,REPAK,.:APPXTCIIEIIXCAL FAHILY:I-IYPOCI-ILORXTEF(3f~iilJLA: !:A<(3CI..>2CABHLJHBER:007778-54-'IJ,8~DOTSHIPPIHGHAHE:CALCIUHHYPQCI-ILORITE,HYDRATEDIJ~S~DOTHAZARDCl.ASS:.'r,J.<OXXDXZER>"-;IJI)ST.i3IARYRI8K:i'I/AI.n.NLJVJ3I=.R:LJN2880A(".,I<IH(38>ROlJP:XX:.~QRTAIll'=QIJAHTTTY::L0LI38/4~-l<6I;Hf)DESCRIPTIQH:CAL.CILIAiIYPQCHLORXTE,HYDRATED, CLASS'3.,UH2880,PA(.i<".I'IG> 8RQIJPII,RA,XHOG(;Ql3EPAGI=.rl38~

VAHMATERS6ROGERSXHC.is>>TI:RXAI SAr-ETYI3ArASl-IELTI'-'.E"">r'". I'LJHI3FR: 97J"'-:I;.'i 'I:):P60310"-'FrEC!".VE.".)ATE:()b/23./93 GCALCIUDHYP(3CI-IL(3 RITEL'rRAHLJLARPAGE:002.VERSXOH:004ORDERHO:PRODHQSECTXQH1.-PflYSXCAI... DATA3(31I...XHR P(3XHT67i~>0ANI-l(3:PORDENSITY(AXR=-J.): ')PECIFXC GRAVITY(H2O=X):'PHrJFSQIIJTXQHS:FREEZXH(3/HFLTXHG POIHT:Br)LUBXLXTY (AEXGf!T%):HMATE(2DEC(3VPQSES ezenCN/AH/AALKALINEH/AG/Le2rC!3EHDIi'('OLL)HE %VOI..ATXlE:VAPOR'(>RESSlJRE: EVAPORATION RASE:I.IEATOFS(3IIJTXON:APPEARANCE AHDODOR:WHXTEP(3WI3ERWXTHSlXGHT65-~>7i.BS/(3U.FT.H/AH/AN/ASLXGHTI..Y EXOTHERHXC CI.ILORINE0DORSEC;I(3H;"-INGREDIENTS

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TI.XP!I'RTXf.X..-.DFOR<<IA/X>h!Utg IJSEAT-'.,g:,"I8/I IINDERr)HSX/HSF STAN()ARD ~'>0..r~F..';XSXOHS h!ADETO//28/9... SRr)EDX~XON:'lTATrHI=N>,DATE,EDXTXQt<, A!3f)XTXGH OFHSFFOR'DDXTXGHAI... XHFf)R~I!ATTGH ")ii'>~":lI'I3DS>;QQRI3Xi'lA'> (3R<>>.I<'~R R(3(JT'ri REtiDD(JRXHGBUSXHFSSHQIJRSPACXFXCTXIIE(20'>)889-':400 02/!.7/">>~),I.2; 2J.PRGI3UCT: (IJS>TH(3:GRI3I=..R HO:H'PP'\~'TX'4LJ.'GALE~Xf<)AH')ATERSAAGGERSXi!C.';"V()6R")E)(PILI=..SSI..Y (3XSCLAXHS Al.LFXPIRESSORXHPLXE!3'!ARRAHTXES OF)'!ER(;I'ANTARXI..XTY ANI3IES>SFGRAI>ARTX(3(JI ARP(JRPGSE, P':":.H'"".=-'-".,'.-.( >8'.l-IF.PR(3i3U(.,'f'3R .h(F(3RHATX()H PR(39Xi')!XI3!-!I;;;!<I".".XH ~;~I'..".NFGRI<ATXGN AP~EARXVI'iERFXH 'rSBASED!)POHDATAOBTA(HEDFROhIri!E,,~N),'g".,'~'(IRER lych>D/OR P<Cg>Ha'FD7,',"'<>NX(.".,I 8(')I'>i,,fi'P>, ))I-If,',I"!>>XNFGRIIQTXOH XS')EL;.-""..'.> I>AI=',:;CURAT"::. )Wr":RriAl<..SNGR,=,fRFSEI'IT>-'>TXQH3 A,:i'>"0.i(CURACY3R.!!Fi"'.i'!O':.".GHDX XGHS8>-LISE'>REBEYONDilhcR"'ONTROL AHDriEREFGRF. (IS>ERS','-RP)".!l":l. f)l..i.;.:"G l)E!"-XFY";-IXS)A'.')Nl)ER;:.-!r.=.X f<)!,;Nr>PERATXH6 >;GHDXTXQHS >(3~.'.Ri'!.Hi-..i-If.'VjERTHF".'(3f)(ICT,,'5 ')XTAfI!. EFI>R'"('E,"~PAR7XC(J>.AR !'>IJRPOSE"> AHf)t'!IE";8:li'>"'". 'II">XS!iS>"FTi-ii:':.RU."">F--'.".N>,)L,i'i>j .ANC)DXSPGS>~!.. GF"'-IEO'RGI3!JC"', (3RFIROhI"liEi'>JBLXCATXQH >3R.(JSEGF,6)RRKI,.X'HCE UPONXtif=GICIRATXOH COIMTAXHED iIEREXH."Vi".'-:) .."i'GRlI*TX )NREI"ES<.:h(lY'.")')"I-IEPRQ!3(JCT >')!X",:fGHATEDIi.REXi'i,AHDDOESN(37i(F;.'."""'~!3:TSUSFXN<""!I"IBXNATXQt'I <ii.'TilANY".)TIIEP, iiATERXAI '">R":hlANYllTIIERi"R(1(Fr-8I)y>fA\)~gp. SEEINSTRUCTIONS ONREVERSESIDESECTIONIIPERMIT~IYII0005827NUMBEREM3A>>NA%OFPROCESSCONIRIBUTI IIITOTHEDISOIARGE TICEXXNTHISOUIFALLAM)SICCODEBsPROCESSSOCEDLLE(YFsVCLYAVERAGE)mum/DtLV~24~365~OOESANITARYWTER4911PROCESSSTREAMSCONTRIBUTING TOOUTFALLDISCHARGE nthCCCOr0CC0C~PRXESSHASTEN%TER FUXIRATEDsPROCESSPRCXXXTION RATEN/ATOTALYEARLYDAILYHINII%NDAILYHAXII%NLNITgXXIE0ll~6037~6LNITSPTIHE~LJJlIIIZQZc!2JK 1POUNDS2GALLONS3CUBICYARDS4TONSSMGY6MGD.7GPDTIME1HOUR2DAYWEEK4MONTH5YEARcvCllnOCC9OCECLAsf4'%FPROCESSCONIRIBVTIICI TOllEDISOLUCGE g/ATIROUGHTHISOVIFALLAIDSICCLXEBsPROCESSSDEDLIE(YEARLYAVERAGECsPROCESSHLSTEHATER FUXCRATEDsPROCESSPRXLICTIOH RATEAsHAIEOFPROCESSaXIIIBVTIHT TOTIEDISCHCRGE g/ATICBXXIHTHISOUIFALLJUOSICOXEBsPROCESSSQEDLIE(YEARLYAVERAGE)CsPROCESSHLSTKHATER FUBIRATED.PIXXXSSPRXXCf1ONRAlEAstQPEOFPROCESSCCNIRIBVTIIC lOTIEDISCHARGE g/AAM)SICCTEEBsPROCESSSOERIE(YEARLYAVBLAGE)RLXKSSHASTDNTKR FUXCRATEA.HHEOFmCKSSCCNIRIIXITIW TOTIEDImeaaN/ATI%%XCIHTHISOUIFALLANOSICCODEBsPRXESSSOEDIE(YEARLYAVERSE)C.PROCESSHAST8%CTKR FLDCRATEDsPRXESSPRXXCTION RATETOTALYEARLYDAlLYHIHII%NDEWILYHLXII%MTOTALYEARLYDAILYHIHII%NDAILYHAXIltNTOTALYEARLYDAlLYHINIJ%NDAILYHLXIHEClOTALYEARLYDAILYHIHII%NDAlLYHAXII%NLNITS/TINELNITaXKLJLNITSnIHELNITS/TIHE INSTRUCTIONS FORCOIL'LETING SECTIONIIITEM3TfisformreauiresInformation ontneprocessstreams<<hlchcontribute tothisdlscnarge. ENTERTHEPERMITIl'ABERINTHEBOXATTHETOPOFTHISFORM.THEPERMITNIWIBERCANBEFOUNOONTHEFRONTPAGEOFYOUREXPIRINGFERMIT.Ifthisisanewornororeviousiy permitted

facility, thenleavealan<andanumber<<illbea5signed.

EnteroutfaiinumberinspaceprovidedforeacnpageofSectionII.Foreacnindividual dlscharce pointaseparatesetofSectionII'OrmsmuStbefiIlegout.ITEMSPROCESSSTREAMSCONTRIBUTING TOOISCHARGE: FOREACHSEPARATE'ROCESS PROVIDETHEFOLLOHING INFORMATION A.Entertnenameoftheprocess<<nichcontributes tothisdischarge. AlsoprovidetheproperSICcode.B.Indicatetneyearlyaverageproce55ScneduleinhOurSOcrdayanddays-oer-year. C.Providetheprocesswastewater flowrateinformation asrequested ba5edonyourlastl2monthsofoperations. Ilefertounitcodegivenintheleftmargin(ortheappropriate flowunits.0.ProcessProduction Rate-Certainpermitlimitations mavbebasedonproduction rates.Theproduction ratesusedtodetermine permitlimitssnailberepresented byareasonable measureofactualproduction ofthefacility, suchastheproauctlon aurlngthehighmonthoftneoreviousyear,orthemonthlyaverageforthehighestofthepreviousfiveyears,orotherreasonable measureasstatedinapplicable U.S.E.P.A. categorical rulesandregulations. Fornewsourcesornewdlscharaers, actualproduction 5hallbeestimated u5ingprojected production. Recorayourproduction ratesinthetermSanaunitSuSeaIntheapplicable V.S.E.P.A. categorical rulesanaregulations foryourtypeoffacility. SEEINSTRUCTIONS. ONREVERSESIDESECTIONIIePERMIT~LNIOit05827NUMBER~OO:EGROUNDWATER DISCHARGE INFORMATION AeIS1HEDISCHARGE FRCNTHISOUTFALLDIRECTEDTOTHEGRONOORGRONDtATKRS2 llFtDPCCttTltiE TOITEMO)BeHASAHYC62OIBXDGICAL STIXT/ORITSEOJIVAIENT BEEHPKRFORPED ORISTHERESIFFICIEHT cNIREHTHfÃGGEQ+GIaL INFOIHATION AYAILABlE ASRE0UIRKDBYTteHATERRstxxstcEs alttISSICM PARTZZRAIXltD6ATER RIIESOFAIDUST14PlRURP525PZ/W (PAGEFCRTHISEXISTI%ORPROPOSEDDISCH6RGE/ IFYESAlTAOIACOPYCFlHEREPCRTPCeAREYCURBXESTI%ANEXBGTTICN FRCMSIKPIITT1% AHYCRCGKOLOGIaL REPCRTtltDKRRISER.323P221}l (l0}(PAGEtt5)OtFR(MGRIXPIXtATKR N5ttITQRI% IIKOUJRIMEHIS tltCERRLAKRP525PZIU5 (5)(PAGEt(73OFTIEPARTZlRLLESPIFYESATTACHDXIMKHTSAM)EXPLANATICN TODOIGCTIATKTHATYIXRDISOQf6ENXADOUALIFYRXI~CNPDeAREYOURBXESTI%AVARIANCEFRtttRULE323e2Z6(PAGE5)(%tKXDIIADATICN) OFTIEHATERRESIXl2CES CCWISSION PARTZZGRXXtttlATKR RIALSPAIFYESPATTACHSIXHDOQMKHTSASNECESSARY TOCQQtSTRATK TIEHEEDFCRAVARIANCEINTKIYtSCFTIECRITERIASPECIFIED IHRIAL5Z5P2210(PAGEOFTHEPARTZLRILESPEeI,ISTALLCteIICALSIBSTAICES HHICHAREINMICHIGANSCRITICALMATERIALS REGISTKRTAKEIVlPAGK{j)OtUPSPEPA'SPRICRITYRXll/TANT LISTTAKEV(PAGE1)ORANYOIIERSIBSTMXStHIOIAREOtNAYBHXPEINXIIIIXS 1DTIEEESIGNATED USESOFTIEGNIXIKltATER OR19TIEPUBLICIEALTHTHATAREDISCM6RGED OREXPECIEDTOBEDISCH6RGKD TOTIEMX!KXIATKR~ THISFJCILITYP ESTIHATETHEFINALEFFLIEHTCOtCEHB4TICN AtKIRKCCRDAII.DteTAINITBl1OFSECTIONIlIHTHISIO)NEfeTIEAPPLIa7IT HAYBEREIXIIRKD 1ODOACOITIOIAL HASTEJIUI.YSESP z->>-a.Submitted 12/6Y91INTAPPUaBLE/BELlKVKD ABSENTPRESENTSDATAIQOVIDKDINITBI7ITEM5AeDISCH8RGE CHAIIACIKRISTICS BGDI7(FIYEDAYBloctetlaL oxYGEHDKMAIKI)'coD(OKttlaLc0DGENcetAto)CCNCEHIRATICtt AVENAX~40.~05~99.~6WITSCIXKltANALYSESSAtPIKTYPECIXEu1~uEXPECTEDWASTEWATER CHARAC1Mp/I2UQ/I3COUNTS/100ml4S.U.5'FeI.BS/OAYANCNIAHITRIXIKH (ASH)TOTALSUSPKNXDSCUDSTOTALPIOSPta2US (ASP)TOTALRESIIXIAL OURIHEDISSOLVED OXIGKHNIN~6~4FECALCGUFXINBACTERIA~TINE(SUPER)TDPERATISK (HINTER)TOC(TOTALORGANICaRNXt)~25.~55~116,~0~7~.~036~12~~05S78~~uLJ~~uBeODKRINSTKHATKR CM6RACIKRISTICS ul2~60ul~65u1u1~113u5u5u1u1~SAHPTXBF1GRAB224HOURCOMPOSITE 0ILBGREASEciro.~65.~56~208,~0LJu1~65RECUIRKDIWXP5ATICN FITSINFACEHATERDISCHNGVP INSTRUCTIONS FORC(5IPLETING SECTIONIIITEMS4ANO55forr,require ntmatioIionaspecificoutfalldischarging toeitherthegroundwaters orthesurfaceWaters.5?(Isortorequr~e-q(ERTWEDcq)f(T'h BERIIITHEBOXATTHETCPOFTHISFORM.THEPERMITNIDIBERCANBEFOUNDONTHEFRONTPAGEOFYOUREXPIRINGoER??IT.z+thi+5anettornotpreviously permitted

facility, thenleaveplonkandanumber<<illbeassiqned.

Perr(leOucfalInumaerIntheSpacePrOvidedtoreacnDaceofSectionII.ForedenIndividual discharge pointaseparatesetecVIotl'D~torm'5(It's4ana5)nustaeIiliedout.DP/ITEM4IlG"OUNDWATED DISCHARGE INFORMATION(00NOTINCLUDEDEEPWELLINJECTION INFORMATION INTHISITEM)A.-D.Theapplicant shalladdresseachotthaqeoartsIfthedischarge franthisouttallIstothegroundwater. ITEM5EXISTINGOREXPECTED(FORANEWDISCHARGE) WASTEWATEP. CHARACTERISTICS OFGROUNDWATER ORSURFACEWATERDISCHARGE (DONOTINCLUDEW>>LLINJtINININH,?JPTheapplicant shallreportavailable discharge data(realdataforexistingdischarge orexpecteddataforaoroposeddischarge) fortheDard>>eters dslisted.TheseDarameter5 shallbeaddressed foIeitherasurfacewaterdl5charge orasaDpropriate foragrounovater dlscnarge. Forassistance Indetermining appropriate parameters agroundvater dlscharoe apollcant maycontacttheGrounovater DualityDivision, PermitsSectionortheapproorlate Grounorater pualltvDivision's Districtoffice.Theapplicant shallreporttheSaneletypecodebestdescribing edenreportedplaceofdate.Seecodingontheleftmarginofthisform.II'hisouttallIsasurfaceWaterdlscnarae. theaop?icantmustreportquantitative dataforeachDard>>eter Identified bvan5"~OCDODDODOD ~.I*CCDtt5~5555OtDOOItlI,III5OCO5DttCWINDtttOI~DDIICtlt9.Itdatalsavailable forotherparameters notlistedaboveinA.orotherpartsotthisapplication theaDpllcant 5houldreDortthatdataIntheblank5DacesprovidedInthisDart.NOTESII.Unitcodestorparaneters reportedInpartsAandBcanbetoundontheletthandsideotthistorm.2.GrabsampleshallbeusedtoanalyzeforpH,tenoerature, totalphenols,residualchlorine, oilandgrease,andfecalcolltormInasurtacewaterdischarge unlessotherfrequency-sanple typeanalysesareavailabl~.SeeGlossary(page48)forddtlnltlonofgrabsandie.24-hourcomooslte samolesshallbeusedtoanalyzeforTotal8005,coo,Toc,Am>>onlaNitrogen, andTotalSuspended SolidsInd5urtaceWaterd)5charge unle55otherfrequency-sample typeanalysesareavailable. SeeGI055dry(page4B)tordefinition ofccmooslte sa>>pie,REPORTI)6 OFINTAKEDATA~Youarenotrequiredtoreportunle55,youvishtodemonstrate youreligibility foId"net"effluentlimitation toroneormorepollutants, tnatIs,anettluantlimitation adjustedbysubtracting theaveragelevelotthepollutant(s) presentInyourintakeWater.NDDEsregulations allownetlimitations onlyIncertaincircumstances. Todemonstrate youreligibility, reporttheaverageottheresult5otanalyse5onyourintakevaterllfyourWaterIstreatedbetoreuse,testthevoteratterItIstreated). andattacha5epdlatesneercontaining thetollovingforeachDo?lutant?(a)Astatement thattheIntakeveterI5dravntramtnebodyofvaterIntorh)chthedl5chdrge Ismade.(OthervIse, youarenoteligibletornetlimitations.) (b)Astatement ottheextenttoWhichtheleveloftheoollutant isreducedbytreatment otyourvastevdter ~(Yourlimitations WI)Ibeddju5tedonlytotheextentthatthepollutant Isnotremoved.) (c)whenapDI)cable (torexonple,Whenthepollutant represents aclassotca>>pounds), ddemonstration oftheextenttoWhichthepollutants IntheIntakeveryphysically, chemically, orbiologically treethepollutants contained inyourdischarge. (Yourlimitations villbeadjustedonlytotneextentthattheIntakeDollutant5donotvaryfrcmthedischarged oollutants.) ltyouhavetwoormoresubstantially Indentlcal outtalls,youmayrequestpermission tranyourpermitting authoritv tosampleandanalyzeonlyoneouttalIandsubmittheresultsottheanalysistorothersub5tdntlally identical outtalls. Ityourreque5tisgrantedDythepermittlno authority, onaseparate5heetattachedtootheaapIlcatlonto?mIdentityvhlchouttallyoudldtest,anddescribewhytheouttalls<<nichyouoldnotte5tdresubstantially identical totheoutfall>>hichyoudidtest. SEEItISTRUCTIONS ONREVERSESIDESECTlONIIPERMIT~glQpp5827NUMBERIPRIORITYPOLLUTANTS ANDADDffIONAL INFORMATION FORSURFACEWATERDISCHARGE ONLYTHEFOLLJSI1% REOLESTKD INFORMATION ~eADNESSED~QHFACEHATOtDISCHARGERS. IOZEIMDIUSEDISCHARGE% BALLLPROVIDEEXPECIKDVALLESFORlHEOUlUITITATIVE ANDQUALITATIVE INFNHLTION REOLKSTED BELCHeA.tsTHISFACILIlYAPRIMARYIIOUSTRY? (REFERTOTABLEIAPAfg9D(IFWGOTOE)(IFY5GOTOB)BeIWICATETYPEOFPRIMARYINDUSTRYASLISTEDIMTABLEtAPACEQeICONTIN'ITH C.)C>COESTHISOUIFALLDISCHARGE CCtITAIMANYPROCESSHASTKHATER? (tFW,GOTOE)(IFYKS.GOTOD)DeINDICATEttIICHGC/tnFRACTIONS NJSTBETESTEDFCR~(REFERTOTABLEIAPJIK(II)IOZEIFCREACHGC/HsFRACTIONCHECKKDeEACHSPECIFICORGANICTOXICPOLLIJfAMT HllHIHKAOIFRACTIONtl5IBEANALYZEDFCR(SEETABLEIIAPAGEQ,INAODITIOMi ALLPRIIVLRYINLXJSTRY APPLICANTS )IITHAPROCESSHAS19IATER DISCHARGE'~ PRCNIDEOLJLMTITATIVE DATAFOREACHTOXICIOLJJJfAMT INTABLEIIIAPA%gPeRHXRDALLDATAONFCRHSPROVIDED(ITBL7)INTHISBOOKLETe(CCttfltAE HtlHK,KBKLJBI)OOESTHELEWRDAnalysisperJ.B.Beauboeuf DBASE/MEUIRAL GrOundWater Division0eeeePESTICIIXEeIFgg,QJIFACEl4LTERDISC%ROEJPPLICAMf (PRINRYORSECCtOUIY IIJJSIRY)e RKGAJICLESS OFTHETYPEOFDISCHARGEi KMlISORHASREASONTOBELIEVETHATAMYPOLLUTANT LlslKDINTABLEIIAAMDIVAPJGKS~ISDISCHARGED FROIANYIXJIFALZiT)E OUMITITATIVE DATA~BEPROVIIKDe RECNDALLDATAONFOIVISPROVIDED(ITKH7)INTHISBOOKLETeFeIFAMYSLJIFACEHATERDISCHARGE APPLICANT (PRIMARYORSECOtOARY INXJSTRY)e REGJRKESS OFTYPEOFDISCHLRGKe XMASORILLSREASCNTOBELIEVEJIFFYPOLLJJTAMTS LISTEDINTAREVAPAGE+AREDISCHIRMFRLttAMYOLJIFALLl)EAPPLICJJIf ~DESCRIBERKASONSFCR1%,PLXJJJTJtlf BEltOPRESEHTJJOPROVIDEAHYAVAIUBLEOUANTITATIVE DATAeRKCNDALLDATAONFCtttsPROVIDED(ITOI7)IH1HISBOOILEfeWTAPPLICABLE/BELIEVI ABSOITN/A0PRESOIT/DATA lsATTACHEDWfAPPLICABLE/BELIEVED ABSOITN/APRESOIT/DATA IsATTJUMDGeALLQRFACEHATOtDISCHARGE APPLICAMIS (PRIMARYAIOSECCtOARY IIGXJSTRIES) ttOJcRHAIKFAclLSLEs 24ifTRIctslstpetEwxf AcETIGAGID(2e4i5-T)Ji4ietTRIOKJSOPIHWXY PRCPAWICACID(SILVEXiZsIi5iTP)JDI%PIYLVPCi4ilTRILJLJJRCP)KDIYL) PIOSPKIIOTHIOATK (RCtNEL)J >IRICJKJSIOPLEML (TCP)JORHEXJOLNGPIEJE (ICP)J(ALLDATAFNT)EABOVEtlJSTBEGKMIIATED USt%STAIOARDAIHLYTICIL CALItttATICH PIOCOXJLKS) ORKtslOCRHLSREASON1DBKLIEVETHATTELOISORHAYBEPRESBITINT)EIRDISCHJJKIEe ~RKPNTQUALITATIVE DATAiGOERATKDl431tttUSEDASCRKKHIIO PIOCOXJLE WfCALIBRATED HITHANALYTICAL STAIOARDSe FNLDi1SiTKTJIAOKJSKXJIBEHZ~DIOXIH (TCZXJ)eRKCNDALLDATAONFNttsPROVIDED(ITBLf)INTHISBOOKLEfeJeIF~1lEQJLFACEHATERDISCHARGE APPLICAMf K)KHSNHASREASON1DBELIEVETHATBIOLOGI~TOXICllYTESTSHOLEHADEIHlHELASTT)ttEE(9)YEARSCNJJtfOFT)EAPPLICANT SDISCHL%ES ORONARECEIV1%HATERINRELATIONlDADISCHARGEi PROVIDETHISItFNHATION ASJJIATTACttHIT TO1HISJPPLICATIONe KeIFAOIIIRACTLABNATORY ORCSStLTI%FttttPBRÃtKDJttfOFTIEANAYSESREQUIREDBYTHISAPPLICATICIL PROVIDETIENAtEANDACNESSOFEAIHLABORATNY ORFIIVIAtO1)EANALYSESPOIFCRtED ASAMATTACttEMT CF'IHISAPPLICATIONe COYOUDISCHL%EANYOI)ERTOXICORINJLRIOLJS CteHCALSLSSTANCES tOTLISTEDINTABLESIVPJGEttAIOIIAlWOAIVAPPP4$~~IFYEsiTlENIOEHTIEYTIECJKPIICAL QSLSTANCES AWKSTIJLETE TIEFINALEFFLLEttf IXYCEHIIIATHYISe SLKPIITTHISIIFCALLTICN ASANATTAC)tENT TOTHISAPPI.ICATIONe WrAPPLICABLE/BELIEVED ABSENTN/AQPRESOIT/DATA ISATTAC)EDN/AQAPPLICLBLE/SEE AITACIEDQWTAPPLICABLE QX~IIE/SEKAn~QtOTAPPLICABLE N/AAPPLICABLE/SKE ATTAOED INSTRUCTIONS FOR.CCMPLETING SECTIONIIITEM6ThisformreaviresInformation onsspeCifiCOutfalldlsCharglng tothesurface>>sterS. ENTERTHEPERMITNUMBERINTHEBOXATTHETCPOFTHISFCRM.THEPERMITN(S48ERCANBEFOUNOONTHEFRONTPAGEOFTOUREXPIRINGpERMIT.Ifthisissnerornotpreviously permitted

facility, thenleaveblanksnasnumber>>i(I beass(oned.

EntertneoutfallnumberInthespaceorovldedfortachpageofSectionII.ForebenIndividual discharge pointsseparatesetofSectionII.Item6formsmustbefilledout.ITEM6PRIORITYPOU.UTANTS ANOAOOITIONAL INFORMATION NOTE:Ifyouhavet>>oormoresubstantial lyindenticsl outfslls,youmsyrequestpermission fromyourpermitting authorItytosssplesnaanalyzeonlyoneoutfallsnasvcmlttheresultsoftheanalysisforothersubstantially Identical outfslis.lfVourrequestIsgrantedbytnepermitting authority, onsseparatesneetsttscnedtotheapplication,form Identify>>nichoutfslIyouaidtest,snadescribe>>ny tneoutfslls>>nlch youaidnottestaresubstantially Identical totneoutfall>>nlchyoudidtest,NOTE:A.-C.snoE.-J.40CFRPartl22.2((g)(8), Friday,AprilI,lg83,provlaesforssmellBusinessExemption fromtheresorting ofquantitative aptsfororganictoxicpollutants snatoxicpollutants ssrequiredbyPortI22.2((g)(7)(ll)(A) orI22.2((g)(7)(ill)(A), TheseDortssreself-explanatory snddonotrequirefurtherInstructions. simplygothrougheachpartsnddossindicated. 0.SeveralIndustrial categories sndsubcategories havebeenexemoteafrcmsubmitting dotsoncertainGC/MSFractions (40CFRPertl22,vol.'48,No.64,Friday,AprilI,1983,NotesI,2,sna3)."Revle>>thefolio>>lng listtodetermine>>nether yourfacilityqualifies tobeexemptfromreporting Gc/HS(GssChrcmstogrspnv/ MossSpectroscopy) Fractions. GC/MSFractionTestingsndReporting Exenetlons TextileMillsIndustryAllfourGC/HSorganicfractions lntheGreigeMillsSubcategory. -Pesticide fractionInellothersupportsofthisIndustry. OreMlnlnsndOresslnoIndust-Volatile. base/neutral, sndpesticide fractions IntheBasesndPreciousltetslsSubcategory. -AIIfourGc/MSorganicfractions Insllothersubcategories ofthisIndustry. Cu>>andVoodChemicals Industry-Pesclclde fraccionIntheTallOilRosinSubcateqory andtheRosinbasedDerivatives Subcatsgofy. -Pesticide andbase/neutral fractions inallothersubcategories ofth(sIndustry. PulpandPaperIndustry-Pesticide fractionInPaoerqrade Sulfitesubcateaorles {subparts Jand0).-Sass/neutral andpesciclde fractions inOeinkSubpartQ,Olssolvlnq KraftSubparcF,andPaperboard fromVestaPaoerSubpartE.-Volaclle, base/neutral, pesticide fracclons intheBCTbleachedKraftSubpartH,Semi-chem(cal Subparts8andC.andNonlnceqrated-Fine PapersSubpartR.Acid,base/neucral. andpesticide fraccions lnFine8)cachedKraftSubpartI,Olssolvlng SulfitePulpSubpartK,Ground>>oodFinePaDersSubpart0~MarketBleachedKraftSubpart0,TissuefrcxaVastepaper subpartT~andNonlnteqrated TissuePapersSubparcS.SteamElectricPeerPlantInduct-Base/neucral fractionintheOnceThroughCoolingVater,FlyAsh,andBoctomAshTransport Vaterorocess>>astestreams. 38 leeI~~')~'1~II~'~e;~-~'~~I1l)~e1I"~.'c~~'~~'~~1'e~~')'~r'l~~~~~~I'~~II'~NI~)II~~~'~~~1~e~~~e)~~~I~~el~~'~I~)~~~I~1~I~I~~I~~~~~~c'Ie)~I~IC~~I~)~I~~I~~~~1I~I~e~~I~)~~~~Ie~~'I~~~~~I~)~~~I~~el~~~')l~1~I~~I~~II~~e~~~~~)~I~~I~1~I~I~~II~~.~r~I~-~I~~I~1~I~~I~~~~C'~)l~'IW~~~~~~~~'~~'~~~~~~~c)I~"ll~'~~~~ INSTRUCTIONS FORCCHPLETING SECTIONIIITEN7ThlformIstobeusedbvbothsurfaceandgroundrater applicants torecordInformation onanvHlchlgancriticalmaterial, E.P.A.prlorltvpollutant ~ornatardous substance inxhicntnlsapplication recuiresdatatobeprovided. ThisvouldIncludeanychamcaarm~IIsubstance frcmtneHlchlganCriticalHaterlals Register<TableIv),theE.P.A.prioritypollutant t.lstlngITableV).orTablesIIAVAvhlonIIStSOrgan)CTOXICPOIlutantS~OtherTOXICPOIlutantS~CcnVentlanal andNOnCOnyentlOnal POIlutantSandHasardcua Substances ~ITEN7CRITICALMATERIALS* PRIORITYPOLLUTANTS ~ANO/ORHAZAROOUS SUBSTANCES INTHEOISCHARGE MaterielI.2.3...8A.Listthenameofthechemicalsubstance Icrltlcal

material, prioritypollutant, orhasardous substance) frcmTablesIV.VandIIA-YAasreculredIntneaoxvnicnyoucnecxedInA.I-3.above.Entereacnchemicalsubstance

'sparameter nmnberaslistedInTablesIV,VandIIA-VAItprovided. 8.Providetheaverageconcentration ofthechemicalsubstance hewedInA.Indicatethesmnpletypeusedandthenumberofanalysesmadetoprovidetheconcentration cataforthechemicalsubstance namedInA.C,Pl+videthemaximusconcentration anddetermine themassloadingofthechemicalsubstance namedInA.I'fonlyoneanalysisuasmadeforachemicalsubstance thenrecordthatdataesamaximusvalue.Ifmorethanoneanalysishasbeenmadeforacnemlcalsubstance thenprovideenaveragevalueofthoseanalysesandthemaximusvalue.2.ThisSectionII,Item7,OataSheetprovidesspaceforrecording datafor8chemicalsubstances IHaterlals). Additional spaceforrecording ofdataformorethan8Haterlals canbemadebymakingcopiesofthisItem7Oatasheetesneeded.ItIsalsoImportant touseeseparatesetofoatasheetsforeachapplicable reporting reculrmnent aslistedInA.)-3.endforeachoutfall.Refertothelettmarginforthecodenumberrepresenting thesampletypeusedendtheappropriate unitcodes.40 0iI~~~~oIIo~.~~~'.-~..~~~~~~~o~~~e~o.~'~~~~~'I~I~~~'~I~~~I~~~~~~~~~~~o~~~o~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~t~~~~~~~'~~~~I~~~~~~~ ~l~0L~~~~LL~~~~I~.I~.~-ee~~~l~~~~o~~~a.e-~~~'~~~~'~~I~~~'~~~~.-~~~~~~~~~~~~~~~~~g~~ ~l~~o~sIa~j~~'.~~~Q~~..---~~~s~I)~~~~o.~IIe~I0~~~0~~~~~'~~~~~o~~~~~~~~-~~~..~~~~~o~I~~~~~I~~~~I~~I~~~~~~~~~~~~~~~~0~~~~~o~~~~~~',~~~~~t~~~~o~t~~~~

VOLATILEORGANICANALYSISRESULTSFORANALYSESUSiNGMETHOD8260Page2of2ClientSamleID:S.SEWAGEPLANTEFFL.LALSamleID:L1009-47Constituent Dibromochloromethane hlrnznhlnznm-Xleneo-XlenernBrmfrm1122-Tetrachloroethane 13-Dichlorobenzene 14-Dichlrnzen12-Dichlorobenzene Concentration IL<5<5<5<5<5<5<5Reporting Detection LimitILDataQualifier sLOCKHEEDANALYTICAL SERVICES42 VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260TENTATIVELY IDENTIFIED COMPOUNDS ClientSampleID:S.SEWAGEPLANTEFFLDateReceived: 29-DEC-93 Matrix:WATERAnalytical Batch:011094-8260-FZ LALSampleID:L1009%7DateAnalyzed: 114AN-94DilutionFactor:1QCBatchID:011094-8260-F2 Tentatively Identified CompoundUNKNOWNSULFURCOMPOUNDUNKNOWNEstimated Concentration (pg/L)3728Retention TimeIminutes) 4.47,9.70Data.Qualifierls) LOCKHEEDANALYTICAL SERVICES ~~J~1ll~~eI~~s.~~~'~s~~~~y~~~.--~~~.~~I'~~~w~~~a.~o~~a~~~~~~'~~~~~~~~~~~~~~~~~~.-~~..~~~~~~'~~~~e-~~~~~~~~~~~~~'~~0~~~~~~~~~I~~~~~~~'~~~~~~~~~~~~~~~~~~~~00 ~0~e~~I~~~.~e.~~~'~~-~~~ee~~~~~~~~~~'~~,~~~~~~~~~~~~~~~~~~~~.~~~~~~~~~e~~s~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~e~~~~~ ~e~+~~~~~~~~.~I~~II~~~~~~~I'~~~~.~~~~~~~~g~ ~~~~~~IIe~~~~'-~~~~~~~..'-~II'i~III~~~I~I~~I~~II~II~'I~~~I~~:;s~~~~0~~~~~'~'II~~~~~I~~~I~~~~~~~~~~~~~~~~~~~~~~~~~'~-~~~~~~J~~ METALSRESULTSClient-Sam le-ID':S;...SENfAGE PLANT'EFF-LALBatchID(s):1220imDate:Collected: 12-28-93. DateReceived: 12-29-93Matrix::round',water~: 'O¹69095-040-3N Constituents", AluminumAntimonArsenicBariumBeIliumBoronCadmiumChromiumCobaltCoerIronLeadManesiumMananeseMercuMolbdenumNickelSeleniumSilverSodiumThalliumTinTitaniumVanadiumZincMethod."60106020'0206020602060106020602060206020601060206010602074706020602060206020601060206020601060106020Co'ncentratlon lmILl<0.20<0.060<0.010<0.20<0.005(0.20<0.005<0.010<0.050<0.025<0.10<0.0030.025<0.0002<0.20<0.040<0.005<0.01034<0.010<0.20(0.10<0.0500.047Reporting 0'atection Umit{mILl0.200.0600.0100.200.0050.200.0050.0100.0500.0250.100.0035.00.0150.00020.200.0400.0050.0105.00.0100.200.100.0500.020Data'uallfierls) NDate;A'nalzed."01-20-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-20-9401-27-9401-07-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-27-9401-20-9401-20-9401-27-94=',.-.;,LA4.;-",-. "'S"'le"lD':L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16LOCKHEEDANALYTICAL SERVICES~

GENERALCHEMISTRY RESULTSClient-Sam leID.'S.,SEWAGEPLANTEFFLLALBatchID(s):1229imDateCollected: 12-28-93DateReceived: 12-29-93Matrix:roundwater.PO469095-040-3N Constituent MethodResultReporting Detection Limit'ata'ualifier is)."DateAnalzedLAL,.Samle'IDFluoride, inmILChloride, inmIL340.2300.0Nitrate.Nitroen,inmIL300.0<0.15120240.150.0160.01701-24-94L1009-412-29-93L1009-412-29-93L1009-4Nitrite-Nitro en,inmILSulfate.inmILAmmonia-Nitrogen, inmILTotalCyanide.inmg/L300.0300.0350.1335.2<0.503924<0.0200.500.0590.500.020Dl1:10)12-29-93L1009-412-29-93L1009-401-05-94L1009-801-03-94L1009-12Comments: LOCKHEEDANALYTICAL SERVICES

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