ML17334B521
| ML17334B521 | |
| Person / Time | |
|---|---|
| Site: | Cook  |
| Issue date: | 04/13/1994 |
| From: | FITZPATRICK E INDIANA MICHIGAN POWER CO. (FORMERLY INDIANA & MICHIG |
| To: | HICKMAN J B NRC OFFICE OF INFORMATION RESOURCES MANAGEMENT (IRM) |
| References | |
| AEP:NRC:1208B, NUDOCS 9412070157 | |
| Download: ML17334B521 (690) | |
Text
{{#Wiki_filter:IndianaMichiganPowerCompanyOneSummitSquare,P.O.Box60FortWayne,IN468012194252111CERTIFIEDMAIL4P37890l729IItIDIAItIANICHIGANPOWERMr.J.B.Beauboeuf-WasteManagementDivisionMichiganDepartmentofNaturalResourcesJohnHannahBuildingP.0.Box30241Lansing,MI48909Marchll,1994
DearMr.Beauboeuf:
RE:DonaldC.CookNuclear.PlantGroundwaterDischargePermitApplicationEnclosedpleasefindagroundwaterdischargepermitapplicationfortheCookNuclearPlantlocatedinBridgman,Michigan,BerrienCounty.AsrequestedbyMr.ScottRossduringourmeetingonNovember10,1993,alsoenclosedisastudywhichcomparesthequalityoftheeffluentfromtheTurbineRoomSump(TRS)dischargetothatoftheabsorptionponddischargetogroundwater.Includedwiththepermitapplicationisadescriptionofthechangesscheduledtobemadetofurtherreducetheconcentrationsofimpuritiesdischargedintotheabsorptionpond.Pleasenote,alsoasrequestedbyMr.ScottRoss,thatthisapplicationaddressesonlytheCookNuclearPlant'sdischargestothegroundwater.AnapplicationforrenewaloftheNPDESsurfacewaterdischargepermitMI0005827willbesubmittedbyApril1,1994.Theattachedstudyindicatestheabsorptionpondprovidesexcellentmixing,withamixing/dilutionfactorofapproximately20:1.Furthermore,theactual.waterenteringthegroundmeetsalloftheproposedgroundwatereffluentlimitswiththeexceptionofaluminum.Thealuminumdischargeistheresultoftheuseofaluminumsulfate(alum)asaflocculentinthemakeupwaterplant.Thereplacementofalumiscurrentlybeingpursued,asdescribedinAttachment4.AdditionalchangesplannedfortheCookNuclearPlantwillresultinfurtherreductionoftheconcentrationsofimpuritiestotheabsorptionpond.Attachments1and2describethemakeupplantneutralizationsystemandsequencingbatchreactorsrespectively,whichwillresultinimprovedeffluentwaterquality. March11,1994Mr.J.B.BeauboeufPage2Attachment3isadescriptionofthepresentzebramussel-controlstrategyasitaffectsthegroundwaterdischargeaswellassomeoftheoptionsbeingevaluatedforfutureimprovements.Attachment5isadescriptionof'hemicalcorrosioncontroladditiveswhichwillbeusedinvariousplantsystems.Theseadditiveswillbechosenontheirreducedenvironmentaltoxicityaswellascorrosioncontrolperformance.Finally,weoffertotheagencythefollowingproposalsforestablishingcompliancewiththeproposedgroundwatereffluentstandards:*Weproposetocontinuecompliancemonitoring.attheturbineroomsumpdischarge.Theabsorptionpondstudyhas.demonstratedthatthewaterenteringtheaquifermeetstheproposed.groundwatereffluentlimitsforboron,sulfates,sodium,andtotaldissolvedsolids.Therefore,weproposeamonthlycompositesamplemadeupof24hourdailycompositesamplesbeutilizedforcompliancemonitoring.*WerequestthataluminumberegulatedbytotalpoundsreleasedasproposedbyMr.RossinourNovembermeeting,ratherthanbyconcentrationintheabsorptionpond.Theproposedpoundagelimitisamaximum125poundsalumperday.ShouldyouhaveanyquestionsontheattachedmaterialpleasecontactJohnCarlson,CookNuclearPlantEnvironmentalSupervisor,at(616)465-5901ext.1153ormeat(219)425-2118.Wewouldbehappytomeetwithyouatyourconveniencetodiscusstheapplicationifyoubelievethatwouldbehelpful.Verytrulyyours,DonaldL.BakerEnvironmentalAffairsDirectorDLB/sdb/046,042Enclosure March11,1994Mr.J.B.BeauboeufPage3bc:W.A.S.D.E.D.ToN.D'Onofrio/M.A.Bailey/J.L.HugheyA.BlindJ.BrewerM.Fitzgerald/J.P.CarlsonE.FitzpatrickW.Kemp/K.D.MackE.Webb/J.P.Novotny Attachment1MakeupDemineralizerRegenerationWasteNeutralizationSystemTheCookPlantisinstallingasystemtocollectandtreatmakeupdemineralizerregenerationwastestomeetproposedpHpermitlimits.ThecurrentpracticeistoisolatetheTurbineRoomSump(TRS),accumulatethewasteswithintheTRS,neutralizethewastewithsulfuricacidorsodiumhydroxide,thendischargetheneutralizedcontentsoftheTRStotheAbsorptionPond.BecausetheregenerationwastesarenottheonlysourceofwaterbeingcollectedintheTRS,ahighwaterlevelwithintheTRSmayrequirethedischargeofthesumpcontentspriortothewastesbeingcompletelyneutralized.ThenewsystemwillallowcollectionandneutralizationoftheregenerationwastesapartfromtheTRS.TheholdingtankforthewastewillalsobethepointoftreatmentwiththecapabilitytoaddandmixsulfuricacidorsodiumhydroxidewiththewastepriortometeringtheneutralmixturetotheTRS.ThetotalcostoftheMakeupDemineralizationWasteSystemis$3,600,000.00.ThesystemistargetedforcompletionbyJanuaryof1995,withsystemstartuptooccurthereafter. Attachment2SequencingBatchReactorsTheCookPlantiscurrentlyrequestingquotationstoinstallapairofpre-engineeredsequencingbatchreactors(SBR)tomeettheproposedgroundwatereffluentlimits.Thenewsystemwilloperateatadesignflowof50,000GPDwithamaximumflowof60,000GPD.TheSouthExtendedAerationPackagePlantwillbeutilizedasaretentiontanktoensureefficientSBRoperation.Effluentfromthenewsystemwillcontinuetobedischargedintooneofthetwoseepagelagoons.ThenewsystemwillbeinstalledandoperationalbyDecemberof1995. Attachment3ZebraMusselControlStrategyZebramusselsareamenacetoanyindustrialormunicipalprocessdrawingwaterfromLakeMichigan.Ourcurrentcontrolplanistochlorinateandperformperiodicshockchemicaltreatmentsutilizingaproprietarychemicalformulation.ThePlanthasalsochangedthesourcewaterforthefireprotectionsystemtoapotablesupplyfromLakeTownship.Thismethodofcontrolwasdevelopedforshorttermrelieffromtheeffectsofzebramusselinfestation.BasedonoverthreeyearsexperienceindealingwiththemusselsatCookPlantandotherGreatLakesfacilities,anewstrategyisbeingproposedtoourcorporatemanagementforapprovaltoprotectalloperationsfroginfestation.ThenewstrategyincorporatesintermittentoxidizingbiocidetreatmentsofthecirculatingwatersystembeginningattheintakestructuresinLakeMichigan,continuousoxidizingbiocidetreatmentoftheessentialservicewaterandnon-essentialservicewatersystems,additionofsodiumbisulfitetoreduceanyresidualoxidizingbiocidepriortodischargetothelake,and,ifnecessary,shocktreatmentsutilizingproprietarychemicalformulations.Thegoaloftheprogramisto(1)eradicateexistingpopulationsandcontrolfurthersettlementofzebramusselswithintheplantsystemsutilizinglakewater,(2)treattheresidualoxidantbeingdischargedtonon-detectablelevels,and(3)reduceoreliminatethenumberofremedialshocktreatmentsnecessarytokillsettledcoloniesofzebramussels.TheresultantzebramusselcontrolchangeswillultimatelyaffectdischargestotheTurbineRoomSumpfromplantsystemsthataresuppliedbymiscellaneoussealingandcoolingwaterandsystemsthatusenon-essentialservicewaterthatdischargedirectlytotheTRS. Attachment4AlumReplacementProgramAChemistryTaskForcehasbeenevaluatingchemicalflocculentreplacementsforalum(aluminumsulfate).Ourcorporatemanagementiscurrentlyreviewingvariousflocculents,takingbothgroundwatereffluentstandardsandreverseosmosissystemperformanceintoconsideration.Thereplacementscurrentlybeingreviewedaremainlypolymericflocculentwhichwillenhancetheremovalofsuspendedsolidsinthepre-filtersandmeetmanufacturerrecommendationsforthewaterenteringthereverseosmosissystem.Therecommendationsfromthetaskforce,onceapproved,willrequireadditionaltimetotestandimplement.TheenvironmentalbenefitofthisreviewisthereducedamountofaluminumwhichwillbedischargedtothegroundwaterthroughtheTurbineRoomSumpdischarge.Thescheduledtargetimplementationdatetouseanewflocculentisfovrthquarterof1994.
Attachment5ChemistryCorrosionControlAdditivesThePlantisevaluatingsubstitutesforthecurrentcorrosioncontroladditivesinthesteamgenerators,plantheatingboiler,feedwaterandcondensatesystems,andclosedheating/coolingsystems.Thesesubstituteswillincludecarbohydrazide,andotheravailableproductsfromchemicalcompaniessuchasBetzorNalco.Theenvironmentalbenefitsoftheseadditivesincludeutilizationofmorebenigncorrosioncontrolproductsorproductsrequiringlowereffectiveconcentrations.UseoftheseproductswillnecessitatedischargetotheTurbineRoomSumppathwayinconcentrationstobedetermineduponeffectiveoptimization.Consequently,higherconcentrationsorironandothersystemproductscaninitiallybeexpected. ComparativeStudyofTurbineRoomSumpDischargesandAbsorptionPondWaterChemistryCookNuclearPlantGroundwaterApplicationFebruary7,1994 INTRODUCTIONAstudywasconductedtocharacterizethewaterqualityintheCookNuclearPlantAbsorptionPondcomplexpriortodischargeintothegroundwater.ThiswasattherequestofMr.ScottRoss(MichiganDNR)duringourNovember1993meetinginLansing,MI.TheintentofthestudywastodeterminethemixinganddilutioneffectsoftheAbsorptionPondondischargesfromtheplant'sTurbineRoomSump(TRS).Thisreportpresentstheresultsofthestudy,dataanalysis,andgroundwaterimplications.WastewatergeneratedintheplanteitherdrainstotheTRSorispumpedtotheTRSfromlocalizedsumps.TheprimarysourcesofwastewaterincludeMakeupPlantdemineralizerregenerations,filterbackwashes,floordrains,chemistrylabwastes,variousequipmentandsystemdrains,andnon-contactcoolingwater.WateriscollectedintheTRS,'eutralizedasnecessary,andisperiodicallydischargedtoanonsiteAbsorptionPondcomplex.Thepondsarelocatedapproximately825feetsoutheastoftheplant(Figure1).TheAbsorptionPondcomplexconsistsoftheoriginalAbsorptionPondandanOverflowPondconnectedbya392footditch.ThepondshavereceivedanaverageTRSdischargeflowof301,000gallonsperdayduringthelastsixmonthsofplantoperation.BothpondsmaintainrelativelystablewaterlevelswiththeAbsorptionPondoverflowingcontinuouslytothedownstreamOverflowPond.ThepondwaterenteringthegroundeventuallyflowstoLakeMichiganbasedona1991hydrogeologystudy.MATERIALSANDMETHODS'heAbsorptionPondstudyconsistedofthreestages:1)apreliminaryconductivitysurveyandpondvolumedetermination,2)an18-daycomparisonofTRSandAbsorptionPondwaterchemistry,and3)dataanalysisandreportgeneration.ThepreliminaryconductivitysurveywasconductedtodeterminetheuniformityofwaterchemistrywithintheAbsorptionPondandtoobtainponddepthreadings.Thesubsequent18-daystudyincludedtwoMakeupPlantdemineralizerregenerationsandwasconductedwithbothplantunitsoperatingbetween70and100<power.Thesecondregenerationwas"forced"tocompressthestudytimeandprovideamoreconservativeevaluationoftheeffectsofregenerations.Theamountofacidandcausticusedintheregenerationswasmaintainedatnormallevels.Page1of20
PreliminarSurveAsamplinggridwasestablishedontheAbsorptionPondandOverflowPondon40footintervalsusingpermanentreferencepoints.Ateachpoint,aconductivitymeasurementwastakenatadepthofapproximately1.5feetusingaHachModel44600conductivitymeter.PonddepthswerealsotakenateachpointusinganImpulseModel4400depthfinder.Additionaldepthreadingsweretakenaroundtheperipheryofthepondstobetterdevelopdepthcontourmaps.TheareasofthetwopondsweredeterminedusingaNovember1993aerialphotographscaledto1inch=660feetandanelectronicplanimeter.Tenrepetitivemeasurementsweretakenoneachpond.Averageareaswerethencalculatedfortheponds.Thevolumesofthetwopondsandtheinterconnectingstreamwerecalculatedusingthedepthcontourmapsandareadata.Theareasbetweenthedepthcontourlinesweremultipliedbytheaveragedepthandaddedtoobtainthetotalpondvolumes.18-DaStudThestudywasdesignedtoobtaindailycompositesamplesfromtheTRSandAbsorptionPondcomplexduringaperiodencompassingtwodemineralizerregenerations.SampleswerecollectedonceperdayfromtheAbsorptionPond.TheNPDESautocompositorwasusedtoobtaindailyTRScompositesforthestudy.CookNuclearPlantpersonnelanalyzedthesamplesforpHandconductivity.HalliburtonNUSEnvironmentalLaboratoryanalyzedthesamplesforsulfate,chloride,sodium,totaldissolvedsolids,totalaluminum,dissolvedaluminum,totalboronanddissolvedboron.FoursamplelocationswereselectedtomakeupthedailycompositefortheAbsorptionPondcomplex.Twocentralpointswerelocatedat10footdepthsintheAbsorptionPondandtwocentralpointsattwofootdepthswerelocatedintheOverflowPond(Figure2).Tygontubingwassecuredateachsamplelocationandruntothepondshoresforsampling.Batteryoperatedperistalticpumpswereusedtopurgeanddrawthesamples.EqualquantitiesfromeachpointwerecombinedtomakeuptheAbsorptionPondcomposite.ATRSandAbsorptionPondstudyperiodcompositewasalsoanalyzedfortheaboveparameterswhichconsistedofequalquantitiesfromthe18dailycomposites.Thecompositeswereusedaschecksonthedailyanalyticaldata.Anadditionalsetofindependentgrabsampleswascollectedovera28hourperiodduringandaftertheseconddemineralizerregenerationtoprovidemoredetaileddataontheevent.GrabsampleswerecollectedeveryfourhoursfromtheTRSandcompositesamples(fourpoints)werecollectedeverysixhoursfromtheAbsorptionPond.Thesampleswereanalyzedforconductivitytoprovidearelativeindicationoftheshort-termeffectsofdemineralizerregenerations.Page2of20 DataAnalsisandReortThedatafromthestudywascomparedstatisticallyusingSystatsoftware.Thefollowingcomparisonsandcalculationswereperformedtoevaluatethedataandtestthevalidityofthestudy:-TheTRSandAbsorptionPonddatawerecomparedwithproposedgroundwaterdischargelimitstodetermineifthelimitswouldbemetduringdemineralizerregenerations.-TheTRSandAbsorptionPonddatawerecomparedgraphicallytoensurethepatternsmatchedmassbalancecalculations.-MassbalancesforselectedchemistryparameterswereperformedincludingcalculatedversusactualAbsorptionPondvaluecomparisons.-ThestudydatawerecomparedwiththeNPDESdischargemonitoringdatafrompastmonthstoensurethestudywasrepresentativeofplantoperations.Statisticalsignificanceisexpressedwithapercentconfidencelevelandmethod,whenappropriate.RESULTSPreliminarSurveandPondVolumesInitialconductivitymeasurementsindicatedthepondsweremixinguniformly.Conductivitiesrangedfrom310-328uSintheAbsorptionPondandfrom340-347uSintheOverflowPonds.ItwasconcludedthattheTRSdischargeplumewasmixingveryquicklyandthattheselectionofsamplepointscouldbebasedonrepresentingequalareasoftheAbsorptionPondcomplex.ThefoursamplepointsshowninFigure2wereselectedonthisbasis.Depthreadingswereobtainedat60locationsintheAbsorptionPondandat15locationsintheOverflowPond.Depthcontourmapsweredevelopedfromthisdataforthetwoponds(Figures3and4).ThemaximummeasureddepthoftheAbsorptionPondwas19.0feetand4.7feetfortheOverflowPond.PondsurfaceareasandvolumesareshowninTable1.Thetotalwatersurfaceareais2.21acreswithacombinedvolumeofapproximatelysixmilliongallons.ThisprovidesadailyTRSdilutionfactorofalmost20:1basedona301,000gpdaverageflowrate.Page3of20
18DaStudTheTRSwaterchemistryremainsrelativelyconstant(normalTDSrangeof130-170mg/1)exceptfollowingMakeupPlant(MUP)demineralizerregenerations.Thesulfuricacidandsodiumhydroxideusedtoregeneratethedemineralizerssharplyincreasethesulfate,sodium,conductivity,andTDSlevelsforapproximately12hours.Theregenerationsareconductedonanasneededbasisandaveragedonceper12daysduringthelastsixmonths.Thetrendistowardmoreinfrequentregenerationsasoperationofthereverseosmosis(RO)unitisrefined.Analysisresultsforthe18daysamplingperiodfortheTRSandAbsorptionPondarelistedinTable2.TheanalysisresultsfortheTRSandAbsorptionPondarecomparedgraphicallyinFigures5through14.Evenfollowingdemineralizerregenerations,thestudiedchemistryparametersremainedwellbelowtheproposedgroundwaterlimitsintheAbsorptionPondwiththeexceptionofdissolvedaluminum.Thesharpincreasesinconductivity,sulfate,sodium,boron,andTDSaredirectlycorrelatedwithMUPdemineralizerregenerations.Thetwoboronpeaksarethoughttobeduetothereleaseofboronfromthecationbedsduringtheregenerations.ALakeMichiganboronlevelof83ug/lwasreportedinour1990NPDESPermitapllication.Theamountofboronremovedfromprocessingapproximately4-5milliongallonsofLakeMichiganwaterbetweenregenerationswouldaccountforthepeaks.ThedissolvedaluminumexceededorequaledproposedgroundwaterdischargelimitsintheAbsorptionPondoneachday;dissolvedaluminumvaluesrangedfrom50-140ug/lcomparedtoalimitof50ug/l.AluminumlevelsintheTRSareelevatedduetotheuseofalum(aluminumsulfate)atanaveragerateof300poundsperweek.Higherratesareusedduringturbidlakeconditions.TherewasexcellentcorrelationbetweentheTRSandAbsorptionPondresultsforallparametersstudied.Table3liststhemultiplecorrelationcoefficients(R~),F-Ratiosforthelinearregressiontests,andsignificancelevel(p).Inmostcases,theprobabilityoftheTRSandAbsorptionPondchemistryparametersnotbeingrelatedislessthanO.l<.ThecorrelationbetweentheTRSandAbsorptionPondcouldbeimprovedslightlybycomparingAbsorptionPonddataonedaylaterthantheTRSdata("laggingoneday").Thisprobablyreflectsthesamplingtimedifference:1000hoursfortheAbsorptionPondand2200hoursfortheTRS.ThisindicatestheAbsorptionPonddataarereliableinassessingthetrueeffectsoftheTRSonAbsorptionPondwaterchemistry.Page4of20
Massbalanceswerealsoconductedfollowingtheregenerationeventstofurtherdefinethevalidityofthestudy.ThecalculatedconcentrationsfortheAbsorptionPondfollowingregenerationarereasonablyclosetotheactualconcentrationsobtainedfromanalysis.TheresultsarepresentedinTable4.Amoreintensiveshort-termstudyoftheeffectsofregenerationsonTRSandAbsorptionPondwaterchemistrywasconductedonJanuary4-5,1994.TheconductivityresultsareincludedinTable5andshowngraphicallyinFigure15.TheresultsindicatethattheTRSreturnstonormalwaterchemistryapproximately12hoursafterthestartofaregeneration.ThedataalsoindicatesthattheAbsorptionPondmixesveryquickly,therebybufferingTRSchemistryspikes.XnadditiontomeetingtheproposedlimitsfortheTRSdischarges,installationofthereverseosmosis(RO)unithasresultedinamarkedreductioninlevelsofgroundwatercontaminants.Figure16illustratesthewaterqualityeffectsofoperatingtheROunittoreducedemineralizerregenerationsontheTRSandgroundwaterWellf11,theclosestwelltotheAbsorptionPond.AstheplantbecomesmoreefficientatoperatingtheMakeupPlantandotherimprovementsaremade,weexpectthistrendtocontinue.CONCL'USZONSThequalityoftheAbsorptionPondwaterenteringtheaquiferwaswithintheproposedgroundwaterlimitsforalloftheparametersstudiedexceptfordissolvedaluminum.Thealuminumlevelswerestillverylowandwillbereducedbelowthe50ug/1limitonceplanstoreplacealumasaflocculantarecompleted.Therefore,theTRScompositorsamplecancontinuetobeusedfordischargemonitoringwithassurancethatthegroundwaterlimitswillbemet.MixinganddilutionofTRSdischargeswithAbsorptionPondcomplexwaterprovidedabufferingeffectresultinginstablepondwaterqualityevenduringdemineralizerregenerationperiods.Otherthanaluminum,theaverageconcentrationsofthechemicalparametersstudiedwereequaltoorlessthan60percentoftheproposedconcentrationlimits.Thisindicatesthat.thereis'substantialmarginagainstexceedancesshouldplantoperatingconditionsdeviatefromthenormalconditionsincludedinthisstudy.Fromthetrendsingroundwaterwelldataoverthelastyear,itisalsoapparentthattheCookNuclearPlanthasmadegreatstridesinimprovinggroundwaterdischargequality.WeexpectthistrendtocontinuewithfurtherrefinementsofourMakeupPlantandinstallationoftheneutralizationtankandnewsewagetreatmentfacility.Page5of20
Tablel-PondVolumesandAbsorptionAreasAreaVolumeLocationAbsorptionPondOverflowPondConnectingStreamTotalSq.Feet62,29130,0563,92096,267Acres1.430.690.092.21Cu.Feet704,60685,3963,920793,922Gallons5,270,453638,76229,3215,938,536page6of20
Table2-TRSandAbsorptionPondAnalyticalResults(mg/l)Day'ulfateSodiumChlorideTDSTotal-AlDissol-AlTotal-BDissol-BCond(uS)pHTRSAPTRSAPTRSAPTRSAPTRSAPTRSAPTRSAPTRSAPTRSAPTRSAP53NN10N150N0.50N0.10N0.04N0.05N261N7.22N53886.22210111502000.800.400.070.090.040.060.060.062633637.197.252964.848914.755908.59112310102310101502101502200.580.671602200.890.200.240.250.090:050.060.190.070.050.140.140.050.060.060.060.060.070.050.060.050.062672752653657.257.23727.167.23627267010121314851001649945555978.360925.94809419047110511106.353110521105.6511005.924101122101122111123101123111025111028111128103010103110101702100.901302101.601402001.201402000.757401901.101302200.911401900.971302100.981302101.601401901.500.220.260.250.320.310.230.360.330.350.500.090.150.060.11<.050.060.160.100.050.150.060.060.090.080.120.120.080.060.300.070.050.300.100.050.200.100.060.300.070.050.060.060.060.060.060.060.060.060.060.060.060.062810.050.062760.050.062750.030.062870.110.0611350.040.063060.060.043000.050.062690.050.053030.050.062513797.087.03816.997.1376706713657.607.23697.677.14157.447.24067.427.14067.727.44207.497.64257.607.615471105.51668011026017186513014N120NAvg.11310331Comp35011015091038N102610102911102810102710101501901.809602200.161602600.61N240N2232110.976002200.660.500.270.380.280.310.290.170.090.050.500.070.090.160.200.16N0.07N0.170.090.060.300.080.10.060.060.060.070.060.060.050.053030.090.0617000.150.06284N0.06N0.060.064060.110.069894107.307.03957.187.6450719703997.166.83427'07.13997.166.8Page7of20 0 Table2-ContinuedThefirstTRSsamplewascollectedatapproximately2200onDecember19,1993(Day0).TheDay0datawasincludedintheTable3linearregressionmodelwhenTRSdatawasshifteddown(lagged)oneday.ATRSsamplewasnotcollectedontheeveningofthefinaldayofthestudy,January6,1994.DemineralizerregenerationswereconductedonDay9(December28)andDay16(January4).2.StudycompositesamplesconsistedofcombiningequalquantitiesofthedailycompositesfromtheTRSandAP.ThemuchhigherthanexpectedanalyticalresultsfortheTRScompositearebelievedtohavebeencausedbytheinadvertentadditionofagrabsampleduringthe28-hourregenerationstudy.Page8of20 t' ~~~~r~~~~~~~~~~~~~~~II0~~IIIIIII~IIIIIIIII~II~I~~~~~III~~IIIII'I~~I~~~~--~~I~~~~~~~>~~I~II'~e~00I~~e'IIIIIII~II~~IIIIII~~III~I~I~I~~I~~-~~II~I+I~i~IIIIIIIIIIIIIIII~~0~~~~I~0~~~~~~~~0~~~IIIo--o0~~~~~~0~~~~~~00~~~I'.~~0~
0~.-~0=~~~-~e~~~~~~~e~e"R5RR.%5II~IIIIII~~~~~eIe~I~~~i~~iRRIII~I~~~II~~e~1~~~e~~~e~~e~e~e~~ee~e~eI~e~ee~eI~l~e~~e~~~~eeea're~.I~e~~~4rer4~e-I~el~e~~~~lee~.~~eee~~~0e
Table5-RegenerationEffectsonConductivity(uS)overa28-HourPeriodTime80010001200160020002200240040080010001200263NA6,8202,380367NA195200256NA245Abs.Pond395NA470NA447NA436NA445NA1.MakeupPlantdemineralizerregenerationdischargefromtheTRSbeganatapproximately1140hoursonOl/04/93.Page11of20 ~>g<>B1-CookNuclearPlant,AbsorptionPondComplexandWLL~~CRSL40tWPlant/)Cj-'L'~Llaw~v0OLP(LISverfloPONDI-~.'~~".Page12of20 Figu1e2-AbsorptionPondandOverflowPondSampleLocationsAbsorptionPondConnectingStream(392feet)OverflowCulvertp/y/IlgX=SampleLocationP=PumpLocationOverflowXPondPPage13of20 Figure3-AbsorptionPondDepthContours/go)PEtj>'rroFigure4-OverflowPondDepthContours41Page14of20 Figure5-conductivity200015001000O005000IIIoi2oisereoio>>iaisi4isieirieDAY----APTRSFigure6-pH1.00.9~ApH8.50.80.7~pH6.50i2s4sereoioii1213i4isieirieDAY----LOGAPLOGTRSLOGMAXLOGMINPage15of20 Figure7-Sulfate700600500O)4pp~300CO2001000120458189101'11215141518ll18OAY----APTRSLIMITFigure8-sodium3002000~~0001204587881011121814ld181718DAY----AP-TRSLIMITPage16of20 Figure9-Chloride300200l0Z0100012Q45018910111218)4151Sll18DAY----APTRSLIMITFigure10-TotalDissolvedSolids1000800600203P4002000120~55760101112181415151118DAY----APTRSLIMITPage,17of20 Figure11-TotalAluminum2.01.52i.00.50.00125455I8910111213141$15ll18----AP-TRSDAYFigure12-DissolvedAluminum0.6~04E0g0.2O0.0///~efIIA/NI----AP-TRSLIMIT0125455I89101112'51415151718DAYPage18of20 ]i Figure13-TotalBoron0.200.15ECo010OK00.05iI'iIII'iII'\IIIIIIIIIIII0.000i20~sersoioiii2iewisieiris----TRSAPDAYFigure14-DissolvedBoron0.150.10CQ0CCl~oQQ5O\IIIIIIII0IilIIIIIIII~~~IIIIIII0.00III0i204sdI8010ll12lslaisieil18----TRSAPLIMITDAYPage19of20 Figure15-EffectsofDemineralizerRegenerationsonTRSandAbsorptionPondConductivityOvera28-HourPeriod700060005000>,4000O3000O020001000I(IIIIIIIIIIIII\I\IIIIIIII0481216202428HOURSAPFigure16-Decreasesin1993ChemistryParametersforGroundwaterWellN11andtheTRSDuetoROUnitInstallationandReducedRegenerations15001000500123457101112MONTH"---""WELLSO4-------WELLNA---TRSS04-TRSTDSPage20of20
.~SEEINSTRUCTIONS'wNREVERSESIDEr"':SECTIONIrearllEPAI.D.NuMSERMID0'98647621NUMBER-~MI0005827APPLICATIONFORDISHARGEERMITIICOIFIQTICNEXI~IICINEIfIICREASEOUSEREISSUAtCE5t'00EI'--lTEMA.PARENTCOIPANY~CEPTI'ADER"-INDINMICHIGAN0WERCOMPAB.DIV./RmUN/APHYSICALLOCATIONADDRESSFeSlREEfIAISERoe'G,ISTREETNVECOOKLACCPLANfORFACILITYn"O'PK'PLANT'TM,",,E"L'"CTRICGE'ESTAIOARDIIEXISTRIALCLASSIFICATION(REFERTOTAREIII)L44911I~ANOINFORMATION'eCllYNA%RIGMANMlIeZIPCODE46'eTQIISNIPLKE%RIENCOeH4%CORISER~LeNt%OFAUIHXIIZEDCONTACTPERSON0NALDLBAKERNeTIllEENVAFFAIRSIR2194.25~211OeAIXRESS(IFDIFFEREHfFRIIABOVE)110EWAYNESTEETPeCITYNAIEonF0TWAYNEOeSTAlEReZIPCXE46802SelYPEOFTREATIEHTFACILITY(REFERTOTABLEII)~1L~1~2~3A~4GTePRXRAIIRNIEFFECTIVERESIDLNLSIIANG9%ÃfDATESLDNITTED0YES'HS'N.A,DATEIIPLIIEHIEDUeBACK~ICIERSOLRCEzVeFOUllfIONIIN:ICEHTPREVEHTIONPLAN11/18/92DATESIEHITTED906XelYPECFDISCHARGE~~QYeRIVIXINAVEACERTIFIEDOPERATCII?El~Cl0+D.H.Fetearalde,e,g~atr9~ro~4992ITEM2A>>tiVERBoNA%MENGEMAILINGADDRESSOFAPPLICANTCeSTREETABÃE%CRPOSTOFFICEBOX110EWDoCllYNVEFORTWYNESREETEeSTATE~INFeZIPaXE46802REOUIRIOSIGNATISIEI~theooollcsnt,<<ertltvunderDensltvotIsvthstIhoveoersonsllyexercisedondsootsnlliervlththeIntorsestlonsubeolttedInthisooDIIcstlonond~IIottsctveeentsondtn4t,bssedonovInoulryotthoseIndlvlduolslerooedlotelyresoonslbleforobtslnln9theIntoetootlon,Ibelieveth4ttheInteretioIstrue,occur4te4ndccslots.Ieoversth4ttheresre5lonlflcsntoenoltl~5rorsubnlttln9tolseInfection,Includln9theDO$5lblIltyotfinesndIeaorlsoevoent,SIGNATUREOFAPPLICANTch~.R.C.Mene~/<9(9'4>>.,PresidentSIGNATUREOFLOCALGOVERNIIIITALREPRESENTATIVE(SEENOTEONREVERSESIDE)TITL15 (~"'.v>>~\>a2'm~'I>j,INSTRUCI'IONSFORCCMPLETINGSECTIONIlIIi'r'(>(r"I"~'Th<5farmrequlreSInfcrmat(cnabOutthefaCllltyaddreSS>,di5ChargeIOCat(On,PlantCOntrOIS,tyPeOfdl5PO5alfaCIIltYandname.'""address,andsignatureoftheapplicant"'and'local'governmentalrepresentative.kEnterEnv(rorvrrentalProtectionAgency.lOcNumber-')favailable."'-,"-*"-"ENTERTHEPERMITN<MBERIN,THEBOXAT"THETOPOFTHISFORM.THEPERMITIAIMBERCANBEFOUNOONTHEFRONTPAGE,OFYOUREXPIRING',<<c,pERMIT.,lfthisis,anevornotpreviouslypermittedfacility,thenleaveblankandanumberwillbeasslqned.,>yZC>,rInthebox"ApplicationForOlschargaPermitIsycheckoneofthefivecategories(modification,existingunperm(tted>ne<<>Increaseduse,orrelssuance)<<hichyourpermitapplicationfallsInto(seepagel4fordefinitions).rrITEMIPHYSICALLOCATIONAOORESSANOIUFORMATIONr'A.-C.EnterthenamingInformationInaccordancewiththefollowing:Zew-ForIndustrialfacilities,provideTheparentocmpanyname(A.),thedivisionnew(8.),andtheplantname(c.).rr-Forfederalandstatefacilitiesp'rovldethedepartment.new(A.),thedivision,or.,thebureau.name(8.).andthefacilitynew(C.).il-Forcorrrwrclalfacilitiesprovidetheowner'5name,doing-businessas<d.b.a.)(A.)andthefacilitynew<C~)~f!""'O.Entertypeoffacility.Exeaoles'ofthisarecfoundry;highschool;autarratlccarwash;drycleaners;self-servelaundromat.~~.>E.RefertoTableIII(page5)forthelistofStandardIndustrialClassificationCode<SIC).Enterthecodenumberthatbestdescribesthemajorproductorserviceproduced.F.-l.EhterthePhySICalIOCatlanOfthefaCIllty.OONOTuaePOStOff(CabOXnrmrber..e't,Z)tJ.-K.Lo-RoU.VoEnterthetownshipandcountyInwhichthisfeellltyIslocated.ThecountycodenumbercanbetoundInTableI(page>5)~Enterthenew,title,addressandtelephonenrmrberofthefacility'sauthorizedcontactperson.ThisDersonshouldbethoroughlyferrlliarviththefactsreportedontheseformsInthe.eventthatcontactregardingthepermitapplIcationmustbemade.RefertoTableII(page5)forthelistofTreatmentFacilityTypes,enteruptofivemethodsusedbythefacilitytotreatthewastewater.F4'>MrIndicatewhetherthisfacilityhasa"ResidualsManagementPlan".Itso,enter'dateplanwa5submittedandthedatetilePlanwasorIstobelmplewnted.Suchaplanmaybeneededasdeemedappropriateby.theproperOlvlslon5taffIndicatevhetherthewastetreatmentfacilitieshaveaback-upsourceofpaverorwhetheremergencyprocedureshavebeendevelopedIncaseofapoweroutagetothewastetreatmentfacility.IfthewastetreatmentfeellltyIsnotdependentonasourceofpover,checkthe"NA"box.UJIndicatewhetherthisfocilityhassubmittedapollutionIncidentpreventionplanasrequiredundertheMichiganwaterResourcesCorrmlsslonPart5Rulesforthe"SplIlageofOlIandPollutingMaterials".J'ffacilityhassanitaryvastevater(voterusedfordawstlcpurposes;~,g.~toilets,,slnk5~shover5).enterthenurrrberofpeopleusingthisfacility.X.Checkthetypeofdischarge(s)franthisfacility.Indicatewhetheryourwastetreatmentorcontrolfacilitiesareunderthesupervisionofacertifiedoperator.Ifyes>pleaseprovidetheOerson'Snew,SOClalsecuritynrmrber,andcertificatenumberplustheccneany'Sfeellltynrmrber.ITEM2MAILINGAOORESSFORALLCORRESPONOENCEA.providethenewoftheaDDIIcant.Forthapurposesofth)5apol(cationtheapplicantIsdefinedastheDersonsigningbelowInaccordancewiththedirectionsprovidedonpageld.CorrespondenceregardingthisapplicationandfuturepermitmattersvlIIbesenttotheapplicant.B.providethenewofthefacility,company.ororganizationwhichtheapplicantIn"A."aboveusesforreceiptofmallc.~,providetheapplicant'saddresstobeusedforfuturecorrespondence.SIGNATUREOFLOCALGOVERQCENTALREPRESENTATIVENOTE:IfsanitarysavageIstobedischargedfromhousingdevelopments,apartmentbulldlngs,shoppingcenters.orothercorrrwrclaldevelopments,Into5systerrotherthananapprovedmunicipalsanitaryvestacollectionsystem,thisapplication5hallbeco-signedbyanauthorizedmunicipalofficialortownshipofficer.ItIstheruleoftheCarmlssicnthatapplicationsInvolvingthedl5po5alofsevaoeofhumanoriginfromanyentityotherthanlocalgovernmentshouldIncludethelocalgovernmentasaco-5lgnerofthestatement,andthatelIproceedlng5andhearingsagainstsaidentity<<IIIIncludethelocalunitofgovernmenta5apartybyappropriatenotice,andallpermits155uedas5re5ultof5uchhearlngsandproceedingsvllIbetIledjointlyagainstthesaidunitandentity<waterResourcesccnmlsslonpart5RulesR525.IO)8<5)andtheMichiganWaterResourcesCcnmlsslonAct245P.A.ofl929asamendedSection6<b)).Thisco-signaturerequlr<<rentIsonlyaDDllcabletosanitarysewagedischargesandIsnotforanynonsanltarywastestreamsfromthisfacility. SEEINSTRUCTIONSONREVERSESIDEA.IXXIICIPAL3BeQRFACEMATERINTAKESECTIONIPERMIT~MIppp5827NUMBERLAKETOWNSH~IPLAEMICIGAteeSOURCEOFWATERSUPPLYCePRIYAlENEILDeOlMEROUANnTY(we.)auveITY(NAx.)NA2651616000~NAITEMFACILITYWATERUSAGEoIjwrm(we.)A>>PROCESSMATERINCLIDI%CONTACTaXX.ImMATER)ouANTITY(BeH3NCONTACTCOOLI%MATEROOANTITY(we.)CeSANITARYMATERaewrTY.)DeOTIER6344000~DAY642112000SAIIDNs/DAY60000~DAYFIREPROTECTIONWTER3600000~DAYITEM5aewrmHYDRAZINE003020126500~TAEARCRITICALMATERIALS&PRIORITYPOLLUTANTSUSEDSTOREDPRODUCEDCLWTITYt4VKOFSIBSTANCEPARA%TERIAPSERONNTITYCHLORINESODIUMC07782505357500KYLENE013302~072500REFERTOTABLESIV&VTOLUENE00108831POUNDS2GALLONS3CUBICYARDS4TONSCL'lIAIOOANTITYLITHIUM(LithiumHdroxideform)CLASS02HYDROQUINONEL>>It>>PARAIETERIAPSERasorllYMERCURY00123319CLASS021u/YeROIMIfllY*L~J/YeRxTotalquantityunknown,containedinthermometers,barometersandmercoidswitcheslocatedthroughouttheplant. INSTRUCTIONSFORCOMPLETINGSECTIONIITEMS3,4,AND5ThisformrequiresInformationaboutthewatersupplytothefeelllty,thefeellltyrswaterusage,andcrltlcalmaterialsandprlorltypollutantsused,stored,orproducedatthisfeelllty.ENTERTHEPERMITICMBERINTHEBOXATTHETOPOFTHISFORM.THEPERMITNUMBERCANBEFOUNDONTHEFRONTPAGEOFYOUREXPIRINGPERMIT.IfthisIsanewornotpreviouslypermittedfeelllty,thenleaveblankandanumber'illbeassigned.ITEM3SCURCEOFMATERSUPPLYListallwatersuppliesused.Thevolrmremaybeestimatedfroyrwatersupplymeterreadingsorfrombllllngstatementsfroma~stersupplyutlllty.IfwaterIsnotmetered,estimatetrcmprmrpcapacity.MhereanameIsrequired,enternameofwatersupply;e.g.,Mudl.ake,HuronRiver,ortheCityofMillpond.ITEM4FACILITYMATERUSAGEListamountsofwatertobeusedforvariouspurpo5e5asrProcessMater-seeGlossarytordeflnltlonlpage48).NoncontactCoolingMater-seeGlossaryfordetlnltlon(page48).SanitaryMater-Materusedfordcmestlcpurposes;e.g..toilets,sinks,showers.IfwaterIsfirstusedfor'napurposeandthesrme~sterIssubsequentlyu5edforoneorInoreotherpurposes~IndicatethevolrmwrperdayottheInstdesignatedusebetoretreatmentand/ordischarge.Forexample,IfwaterIsInltlallyuseda5noncontactcoolingwaterendthenasprocesswater,thequantityot~stergivenshouldbeIndicatedasprocess~ster.ThetotalofItem4shouldequalthetotalofItem3.AnydifferenceInthesetotalsshouldbeexplainedInanattachedsheetofthisappllcatlon.ITEM5CRITICALMATERIALSANOPRIORITYPOLLUTANTSUSED,STOREDPRCOUCEDListallchemicalsubstanceswhichareInMlchlgan'sCrltlcalMaterialsRegisterTableIVlpage6)and/orU.S.EPA'sPrlorltyyetlWtLitttebley(beeyttbteeetlyM.t~.rKddbytbl~teblllty. SEEINSTRUCTIONSONREVERSESIDESECTIONIPERMIT~MI0005827NUMBERITEM3AeNltlCIPALSOURCEOFWATERSUPPLYPRIVAlEMElLouAttflTY(we.)ouANTITY(we.)aulnNs/DAvauUINs/DAvtTEM4FACILITYWATERUSAGEAsoautfITY(we.)PROCESSHATERINCLLDIt6CONfACTCCOLImHATER)OOANTITY(rMINCONTACTCXILIt6HATERtxtANTITY(we.)SANITARYHATEROTIER(we.)aulnNsJDAY~DAVGAllnNS/DAYaulnNs/DAvITFM5IOOOITITYMERCURICNITRATECLS+W/YEARCRITICALMATERIALSPRIORITYPOLLUTANTSUSEDSTOREDPRODUCEDKQJNIxNA%OFSISSTANCEPARA%TERtltSEROOANfllvNttKOFQSSTANCEMERCURICSULFATECLSSQ21CHROMICACIDCLASS015L~J/YEARREFERTOTABLESIVaVNAIEOFQBSTANCEPARAtETERMJSEROautfITYCHLOROFORM63XJ/YEAR1POUNDS2GALLONS3CUBICYARDS4TONSCLQlIAIXNAIEOFQEISTAM:EPARAtETERMPEIERoSutfllYCLASS017WITSLXI/YEARPARA%TERMJSERoUutfllYNAtKOFQSSTAtCEPARAIETERMHKRouANTITYSOS01332214T/mL~J/YEAR"Containedininsulation.throughoutplant;believednottobepresentinthedischarge.17 INSTRUCTIONSFORCOMPLETINGSECTIONIITEMS3,4,AND5ThisformrequiresInformationaboutthe~atersupplytothefeelllty,thefeelIlty'swaterusage,andcritteatmaterialsandprlorltypollutantsused,stored,orproducedatthIsfaclllty.IENTERTHEPERMITISMBERINTHEBOXATTHETOPOFTHISFORM.THEPERMITNIPRIERCANBEFCVNOONTHEFRONTPAGEOFYOUREXPIRINGpERHIT.IfthisIsanewornotpreviouslypen((lttedfeelllty,thenleaveblankandanumberwillbeassigned.ITEM3SOURCEOFWATERSUPPLYl.lstallwatersuppliesused.Thevolu((emaybeestimatedfrcmwatersupplymeterreadingsorfrcmbllllngstatementsfromawatersupplyutlllty.If~afarIsnotmetered,estimatefrompm((pcapacity.whereanaeeIsrequired,enternameof~atersupply;e.g.,MudLake,HuronRiver,ortheCityofMillpond.ITEM4FACILITYWATERUSAGEListamountsofwatertobeusedforvariouspurposesas:ProcessWater-seeGlossaryfordeflnltlonlpage48).NoncontactCooling'Water-seeGlossaryfordeflnltlonIpage48).SanitaryWater-Waterusedfordomesticpurposes;e.g.,toilets,sinks.showers.If~aterIsfirstusedforonepurposeandthesanewaterIssubsequently*usedforoneormoreotherpurposes,Indicatethevol(m>>perdayofthelastdesignatedusebeforetreatmentand/ordischarge,Forexample,IfwaterIsInltlallyusedasnoncontactcoolingwaterandthenas"processwater,thequa'ntltyofwatergivenshouldbeIndicatedasprocesswater.ThetotalofItem4ShouldequalthetotalofItem3.AnydifferenceInthesetotalsshouldbeexplainedInanattachedsheetofthisappllcatlon.ITEM5CRITICALMATERIALSANDPRIORITYPOLLUTANTSUSEDSTOREDPRCDUCEDListallchemicalsubstanceswhicharelnMlchlgan'sCrltlcalMaterialsRegisterTableIy(page6)and/orU.S.EpA'sPrlorltyPo((utt(((tT((V((((((7)((t(nt(y~.(~.(~d((y(((~((('((((y. SEEINSTRUCTIONSONREVERSESIDESECTIONIPERMIT~Mjppp5827NUMBER~EM3SOURCEOFWATERSUPPLYAee'VIICIPAI.BeSLRFACE'iJATERIteTAXEC~PRIVATEWELLD.OTnEReeIXI>>eITTYuVl~%OF'ee'TER'eIAV~MITITY"'AX,)".JAIITITveuM.)P>>FVIIiIIIGALLOteDAY'eALLCeDAYcAt'te'oAvITEiVI"UAIITITYuAX.)A~PROCESSWATER(IIJCLtXIIIJSCOIITACTCOOL!tlSWATER)>>LeAeITIVeB.IIOIICNITACTCCCLIMWATERQUAeYTITY(FAX.)~IIIIIite'DAvEA'";JS/DAYCALLNIS/OATFAGILITYWATERUSAGEC,SAIIITARYWATERO.OTHER".UAIITITYIFAX.)SP<4I>>eITITY'uAX.)BALI>>>>JS/DAY)TEM5CRITICALMATERIALS&PRIDRITYLLUTANTS'JSEDSTOREDIRODUCEDREFERTOTABLESIV&VIPOUNDS2GALLONS3CUBICYARDS4TONSIeIiIIelCetIlIAeZOFSUBST>>IJCEQUAtlTITYHAtlEOFSUBSTAIJCEPARAMETERtll'BEROUAIITITYtA%OFSUBSTANCEPARAIETERtILISEROUAI'llITYtIAuEOFSLSSTAIJCEeeETERtllSERCU"ITITYt~OFSL9STA'XEPARAuiPTERte?TSERtÃ%OFSUBSTAXCENICKELNITRATECLIAS.S022ANTIMONYPOTASSUMCLASSO10IIII~~/YEARIAIITS~/vEARuttlTS~!YEARWITSLJ/vEARLIIIOIiIIePARAtETERtlltSEROUUITITY:~uEOFSLSSTÃICEPARAMETERIll~IIIWITS~/YEARWITSLJ/VEAR17 I'ISTRUCTIONSFCRCCI~ZLETINGSECTICIIIITEMS3,4,<<ND5,his!cr.requiresinfomarlonabout!newatersuoplvtothefacility,thefacility'swater<<sage,andcriticaln'aterlalsandprlcrltvpollutantsused,stored>crproducedatth,isfociIltv.El)TERMEogc>>IT'dJ'cBQI)ITFEBOXATTFECPOFHISFCFM.'PERMITHU'VERCANBEFOU)d)C".wEcFONTc"'ŽOFYOUREXPIQING'ISIS0ewCrnotPrevlc'slyper<<Iec~pllivenleaveoianxan1urper<<'IoeassiITEM3""U-rc-NAQSU""Iv:s!all.<<atersuppliesused.Thevolueeb'avbeesrlnaredfronwatersupolytaterreaclncsc"'rcnbill(rgs-are,enrs'.rc~aware!spiv~IIlry.>5waterIsrorre!epee~es!Iare'npurpcapacity.<<hereanaeisrecui0c,enternaeo.watersupplv:e~~i"udLake,riuronRiver,ortheCityofMlllpcnd.ITE>>"ACILITv.CATER'JSAGE:.ourtsof<<arerrcoeusedforvariouspurposesas:Processeater-seeGlossaryforceflnltlon(page<<8).'icnccntac!Cooling)rater-seeGlossary'crdeflnltlcn(pagec8).SanirarvRater-'Aaterusedfordcresrlcourooses:e.c.,rollers.sinks.snowers.<<arerisfirsrusedfcroneourposeancthesme<<arerlssuosequenrlyusec'crcneor"creotherpurposes,lrclca!ehevclurecercavC.-helastcesicnarecusebeforetreatrenrand/orcischarce.ccrRxancie..'atet~sln(tlallvusedasrcncontacttpci'"c*s!ersnc"snssprccess'<<a<<er,;hequanri7of.<<a!er"ivans<<pulebeinclcatecas:recess<<ater.'e-taicflre<<:-'houldecualthetora)cfItw3.Anvc(fferenceinthese!ctalsshould=.exolainecIranattachedsheetofr<<lscoolication.ITc~a5PlICAL>>ATERIALSANOPRIORITYPOLLUTANTSUSED.SCRED.PPCOLCEDListallchenicalsubstances'<<nlchareinMichigan'sCritical>>aterlalsRegisterTableIV(page5)and/or"..EPA'sPriorityFolI>>tantListTableV(page7)thatarecurrenrlvused,stored,orproducedbythisfociIItv. SEEINSTRUCTIONSONREVERSESIDESECTIONIBER~~MI0005827rEM6AsPROVIDEABRIEFDESCRIPTIONANDLINEDIAGRAHSHXIIIDTHEHATERFUXITHROXIHYQBFACILITYFR%INTAKETODISCHARGEsSHGHALLOPERATIONSCONTRIBUTINGMASTEMATERsINCLUDINGPROCESSAtQPRODUCTIONAREAS>SANITARYFLOMSsCOOL!%MATERIANDSTtA%QTERRIPOFFsYOUHAYGIKXXSIHIIAROPERATIONSINIDASIIKsLEINITsllewMATERBAlANCESHXXJjSHXIAVERAGEFLOHS~QKHAU.SIGNIFICANTUSESCFMATERTOPROOUCTSsATQSPHREsANDDISCHARGEsYOUSHXLDUSEACTUALHEASLR9%NTSHIeIEVERAVAIIABLFJOTKRHISEUSEYOLBBESTESTIIQTEsDESCRIPTION(SeeattachedDescriptions)DIAGRANI19 INSTRUCTIONSFORCOMPLETINGSECTIONIITEM6)ThisformrequiresInfomationaboutthe~aterflowthroughyourfacilityfromIntaketodischarge.ENTERTHEPERMITNUMBERINTHEBOXATTHETOPOFTHISFORM.THEPERMITNWBERCANBEFOUNOONTHEFRONTPAGEOFYOUREXISTINGPERMIT.IfthisIsanewornotpreviouslypermittedfacility,thenleaveblankandanumberwillbeassigned.ITEM6DESCRIPTIONANOLINEDIAGRAMOFFACILITY'5PROCESSESANOTREATMENTSCHEMEA.Brieflydescribetheroutetakenby~aterInyourfacilityfromtheIntaketothedischargeandalsoprovidealinedrawing.ExampleDescriptionandOiaramNarrative:TherinsewaterfrcmthevariousplatingoperationsIscollectedlnoneofthetwo35,000gallontanks.calciumchlorideandalenareaddedtoassist'nfluorideremovalandaidIncoagulation.ThewaterIsadJustedtoapHofabout5.5usingdilutesulfuricacid.ThepHIsthenraisedtoapHofaboutIO.3<<lthlimetoprecipitatethemetalsashydroxide.PolymerIsaddedtoflocculatethemetalhydroxides.Thewastestreamflowsthroughaclarifier,themetalhydroxidesettlestothebottcmas"sludge".Thetreatedwaterflowsfrcmtheclarifiertoamanhole~hereItccnmlngleswithcontactcooling~aterfranthestripline.Thisccnmlngled~aterIsdischargedtotheBuckRiver.ThesludgefrcmtheclarifiergoestoavacuolefilterwhereItIsdewatered.ThesludgeIslatertakentoalandfill.CalciumChlorideAlumSulfuricAcidLimePolymerPlatingWastewater70.000GallonTankAcidificationNeutralizatioFlocculat1onBatchBumpsDumpTankSludgeThickenerClarifierHon-contactCoolingHaterCalciumChlorideAlmaSulfuricAcidLimeLandfillVacuNaFilterGondolaSludgeIiaterHanholeBuckR1veJohnOoe,Inc.,Oeertown,manufacturessleevebearingsforautoeotiveandtruckengines.ProductionIsdividedInto3phases.MetalpowderlsproducedInthefirstphase.Thisisacconpaniedbymeltingcopper>tinandleadIntoIngotsinanelectricfurnaceandapplyingaJetofwatertoquenchendsolidifythemeltingmetalIntopowderform.Thesecondphaseconsistsofadheringthefinemetalpowdertoacollofsteelbypassingthetioslowlythroughfurnaces,Waterusedtocoolthestripconstitutesthecontactcoolingwater.Bearingsarethenformedandmachinedfromthecoatedsteel.Inthethirdphase,mostbearingsreceiveanickelstrikeandlead,tincopperelectroplate.Theremainingbearingsarealuminumorbabbittandreceiveatinorleadplate.Rinsewaterbeforeandafterthevariousplatingoperationsconstitutestheprocesswater.HunicipalMaterSupp'lySanitaryFacility30,000gpdHunicipa1TreatmentStdfsafaterStr1peLine295.000gpdPowderHfg.4000gpdCoolingHater250,000gpdPlatingProcess40,000gpdMasteTreatmentPlant45,000gpduckR1ve20 AdditionalInformationSectionIItem6,SubpartACookNuclearPlantGroundwaterPermitApplicationOutfallOOD-DescritionofUtiliWasteWatersUtilitywastewaterfromwithintheplantisdischargedintoanon-siteabsorptionpond.TheultimatedispositionofthesewastewatersistothegroundwhichventstoLakeMichigan.Thewastewatersinclude:WASTEWATERFLOWDIAGRAM41Wastesfromthemakeupwatertreatmentsystem.Themaincontributorstothewastestreamare:themakeupplantdemineralizerregenerationwastes(avg.40,000gallonsperregeneration),degasifierpumpsealwater(108,000gpd),carbonfilterbackwashwater(avg.45,000gpd)andpre-filterbackwashwater(avg.72,000gpd).Theretentiontankperiodicallydischargesaverysmallvolumeofsolidmaterialremovedbysettling.Alum(aluminumsulfate)isaddedtothepre-filterinfluentasaflocculent.Thesepre-filtersarebackwashedtotheTRStoremovethesuspendedmattercapturedonthefiltermedia.TheAlumcontainedinthebackwashisdischargedtotheTRSintheformofinsolublealuminumhydroxide.CarbonfiltersarealsoperiodicallybackwashedtotheTRS.Thesefiltersprimarilyremoveorganics,chlorineandsmallamountsofiron.SulfuricacidandsodiumhydroxideusedbythemakeupdemineralizerstoregeneratetheresinarerinsedtotheTRSandgenerallyneutralizeeachotherinthesump,formingsodiumsulfatepriortodischarge.Non-essentialservicewaterisusedtosupplyvacuumdegasifierpumpswhichutilizeapproximately75gpmtotalviatwopumpstoremovedissolvedgases(primarilycarbondioxideandoxygen)fromthevacuumdegasifierandexhaustthemtotheatmosphere.Anewcomponentofthemakeupplant,areverseosmosis(RO)system,hasbeeninstalledtoremovethebulkofthedissolvedsolidsfromthelakewaterpriortodemineralization.NormalrejectwaterflowistoLakeMichigan.TheROsystemmustmaintainverycleanmembranestoassureefficientoperationandpurityofwater.Severalmethodsareusedtomaintainthislevelofcleanlinessfromscaleandbiofouling.Usinghydrochloricacidorsulfuricacid,thefeedwaterpHisloweredtoreducethescalingtendenciesofthewater.Approximatelyoncepermonthaflushisperformedusingapproximately0.5%hydrochloricacidandcaustictodissolveanyscalethatdepositsonthemembranes(avg.5000gallonspermonth).Achemicalcleaningisperformedwhentheperiodicacidwashesnolongerareeffective.19a AdditionalInformationSectionIItem6,SubpartACookNuclearPlantGroundwaterPermitApplicationWASTEWATERFLOWDIAGRAM41(cont.)Thechemicalcleaninginvolvesseveralstepsandmaycontaincitricacid,hydrochloricacid,phosphoricacid,sodiumhydroxideandaneutralpHdetergent(avg.10,000gallonsperevent).Also,toremovedeadbiologicalmatterfromthemembranes,asoakusingsodiumbisulfitemaybeperformedasnecessary,approximatelyonceperyear(avg.5000gallonsperevent).WASTEWATERFLOWDIAGRAM42Duringperiodswhennotinoperation,theheatingboilerisstoredfulloftreatedboilerwatercontainingatmost400ppmhydrazine(foroxygenscavenging)and50ppmammoniaor50ppmethanolamine(ETA)(forcorrosionprotection).Priortouse,this"wetlay-up"waterisdrainedtotheTRSfordischargeintotheAbsorptionPond.Thevolumedrainedisapproximately1600gallonsandmayoccur30timesperyear.Duringaunitoutage,thecondensersarecheckedforleaksbyfillingthesteam'idewithcondensatecontainingapproximately,1000gramsoffluoresceindisodiumsaltorRhodamineB.Thesedyesarefluorescentunderblacklightwhichaidsinthedetectionofjointandtubeleaksduringvisualinspection.Thevolumeofwaterdrainedfromthecondensersrangesfrom160,000upto1,000,000gallonsandmayoccuronetimeperyear.Inaddition,thecoolingwatersideofthecondensersaredrainedtotheTRSforgeneralmaintenanceperiodically(8condenserhalvesperunit,approximately25,000gallonsoflakewaterperhalf).Thecomponentcoolingwatersystem(CCW)isperiodicallydrainedtoallowforequipmentinspection,maintenanceorrepair.Thissystemusesdemineralizedwaterfromthemakeupplantasitssourceofmakeupwateralongwithamaximumof1200ppmnitrite(fromCalgonLCS60)and100ppmglutaraldehydeastreatmentchemicals.Theinfrequentdrainingsmayoccurandreleaseapproximately60,000gallonsoftreatedwatertotheTRSperyear.Thedieselgeneratorcoolingjacketwatersystem(DJW)alsoemploysthesamechemicalcontrolforcorrosionasinthecomponentcoolingwatersystemwithamaximumof2000ppmnitritesfromCalgonLCS60.19b
AdditionalInformationSectionIItem6,SubpartACookNuclearPlantGroundwaterPermitApplicationWASTEWATERFLOWDlAGRAMg2(cont.)Thissystemisdrainedto'thefloordrainstotheTRSwhenmaintenanceisperformedonthejacketwatersystem.Thesystemvolumeisapproximately1000gallons.Anyminorsystemleakswouldalsobedirectedtothefloordrainduringnormaloperations.Theessentialservicewatersystems(ESW)andnon-essentialservicewatersystems(NESW)arealsoperiodicallydrainedtoallowforequipmentinspection,maintenance,orrepair.Thesedrainsmaydischargeapproximately72,000gallonsofLakeMichiganwaterusedfornon-contactcoolingintotheTRS.Thiswateriseitherchlorinatedintermittentlyataresidualconcentrationof0.2mg/1TRCorcontinuouslyat0.036ppmtotalresidualchlorine.Duringsomespecialtreatmentperiods,thiswatermaycontainzebramussel,biocides,usedasamolluscicideforzebramusselcontrol.Periodically,componentsoftheESWorNESWsystemsmaybechemicallycleanedtoremoveirondepositsusingvendorsuppliedcleaningsolutionsuchasEDTA(ethylenediaminetetraaceticacid)orascorbicacid,aceticacidandammonia.ThesewastescouldeitherbedrainedtotheTRSorLakeMichigan.Thesteamgenerators(S/G)aredrainedforinspectionandmaintenanceduringscheduledunitoutages(approximatelyevery18months)andduringaneventwheresteamgeneratorfailureisdetectedthatrequiresaunitshutdown.Thesteamgenerators.utilize150ppbhydrazine,20ppmammonia,and2.5ppmETAtocontrolthewaterandsteamchemistrytobenon-aggressivetocyclecomponents.Unit1steamgeneratoralsoutilizes10ppmborontocontrolcorrosion.Asteamgeneratorvolumereleasedduringthedrainingisapproximately32,000gallonseach.Duringwetlay-uptheS/Gsarestoredfullofwaterwithupto400ppmofhydrazineand50ppmammoniaorETAareaddedforcorrosioncontrol.ThiswaterisnormallydrainedtosurfacewaterviaNPDESoutfallsOOAorOOB,butmaybedrainedtotheTRSinsomeinstances.ThemiscellaneousdraintankscanbealignedtodischargetotheTRS.Asmuchas350,000gallonsperdaymaybedirectedtotheTRStocontrolthe"chemistrylimitationsonthesecondarywatersystems.Waterchemistryisprimarilythesameassteamgenerators.Aroundtheplantmiscellaneoussumpscollectapproximately45,000gpdofwaterfromvariousequipmentdrains,leaks,pumpseals,steamjetairejectordrains,etc.19c ~9 AdditionalInformationSectionIItem6,SubpartACookNuclearPlantGroundwaterPermitApplicationWASTEWATERFLOWDIAGRAM42(cont.)Thefrequencyofdischargeandtypesofchemicalsusedinthisequipmenthavebeendescribedelsewhereinthisdescription.MiscellaneousfloordrainsarelocatedthroughouttheplanttoprovideasafeworkingenvironmentbyroutingspilledorleakedwatertotheTRS.Themajorchemicalinfluxintothesedrainsarefromthedetergentsandwaxesusedtomaintainthefloors.AlsoroutedtotheTRSthroughthefloordrainsarethechemicalfeedtankdrains,fireprotectionwater,drinkingwater,coolingwater,anddrainsfrombioboxesusedtomonitorthezebramusselcontrolmeasuresandotherchemicalcontrolmonitors.Thechemicalfeedtankswhichmaybedrainedcontainhydrazine,ammonia,boron,ETA,sodiumhypochlorite.Thebioboxeswilldischargechlorineand,duringzebramusseltreatments,zebramusselbiocides.Non-radiologicalchemicallabsinkandfloordrainsareroutedtotheTRSfordisposal.Thedrainscarrywaterandthewastesgeneratedwhileperforminganalysesandpreparinglaboratorystandardsincludingthoseontheattachedlist.Alsodischargedwillbeglasswareandnormallaboratorycleaningwastes.TheaveragevolumedirectedtotheTRSisestimatedtobe500-1000gpd.Secondary(steamgeneratororcondensate)samplewaterfromcontinuousanalyzersareroutedtodrainswhichdischargetotheTRS.Theanalyzersareonthecycleswhichmaycontainasmuchas10ppmboron,150ppbhydrazine,20ppmammonia,and2.5ppmethanolamine.Theanalyzersmeasurecorrosiontransportataaverageflowof8500gallonsperday.MiscellaneoussealingandcoolingwatersuppliescoolingandsealingwatertotheTRSpumps,condensateboosterpumps,circulatingwaterpumps,vacuumprimingpumps,drainsealreservoirtanksanddrainsamplecoolers.Theaverageflowperdayisapproximately150,000gallons.Non-essentialservicewatersuppliesapproximately53,000gpdofnon-contactcoolingwatertovarioussamplecoolersthroughouttheplant'sturbinebuildingincludingtheConductivityRoomandtheSteamJetAirEjectorsamplepoints.ChemicalspillsthatentertheTRSmaybeneutralizedwithinthesumptopreventadischargetotheenvironment.ThepotentialforspillstotheTRSexistsforthefollowingchemicalswiththeproposedneutralizerslisted:19d , AdditionalInformationSectionIItem6,SubpartACookNuclearPlantGroundwaterPermitApplicationWASTEWATERFLOWDIAGRAMg2(cont.)ChemicalSulfuricacidSodiumhydroxideSodiumhypochloriteHydrazineNeutralizerSodiumhydroxideSulfuricacidSodiumthiosulfateNESW(lakewater),HydrogenperoxideOutfallOOE-SanitarWasteDischaresWASTEWATERFLOWDIAGRAM43Sanitarywastesarepresentlysegregatedandroutedtotwoextendedaerationpackagetreatmentplants.Theexistingequipmentisdesignedtotreat50,000GPDandtheeffluentfromthesewagetreatmentplantsdischargeintooneofthetwoseepagelagoons.ThelagoonsdischargeintothegroundwaterwiththeultimatedispositionbeingLakeMichigan.ThesludgeremovedfromthesedimentationtankbasinsistakentoalocalPOTWfordisposalordewateredandstoredaslowlevelradioactivewaste,asappropriate.Plantsanitarywasteconsistsofshowerandrestroomfacilities,janitorwashbasinslocatedthroughouttheplantnon-radiologicalproperty.Kitchenwastesaregeneratedfromtheplantcafeteria,theEnergyInformationCenterandTrainingbuildings.Thechemistrytraininglaboratorydischargestothesewagetreatmentplantsviaalimestonebedneutralizationtank.Thechemistrylabisusedtotraintechniciansonanalysesperformedintheplant.Thedischargefromthelabcarrieswaterandwastesgeneratedwhileperforminganalysesandpreparinglaboratorystandardsincludingthoseontheattachedlist.Asmallphotolabinthetrainingbuildinguses(onaemergencybasis)smallquantitiesofhydroquinonetodevelopblackandwhitepicturesforplantuse.ThetrainingbuildingHVACsystemalsodrainstothelimestonebed.Aradiographylabintheplantalsodischargessmallquantitiesofprocessingchemicalsfornon-destructivetestingintheplant.Noneoftheproductsintheradiographylabcontaincriticalmaterialsorprioritypollutants.Allportabletoiletwastesontheplantsitearecollectedanddischargedtothepackageplants.Abiodegradabledeodorantisusedintheportabletoilets.Sludgeeffluentwastemayalsoberecycledthroughtheplantstodecreasetheamountofsludgeforprocessingwhenpossible.19e
AdditionalInformationSectionIItem6,SubpartACookNuclearPlantGroundwaterPermitApplicationWASTEWATERFLOWDIAGRAM43(cont.)Miscellaneousrinsingofwastereceptaclesandpossiblemiscellaneouscleaningoperationswasteutilizingvariousdetergentsmayberinsedtothesewagetreatmentplants.MiscellanousOutfallWASTEWATERFLOWDIAGRAM44Themainplanttransformersoneachunitarelocatedwithinconcreteberms.Thebermsareforspillcontainmentshouldacatastrophicfailureofatransformeroccur.Toprotectagainstoperationalandsafetyconcernswhichstemfrompondedwater,theseareasgravitydraintooil/waterseparatorsspecificforeachunit.Eachseparatorisabelowgroundconcretebasindesignedtoretainoilandreleasewatertoaseriesofdrywells.Alsodischargingintotheseparatorsaretheemergencydieselgeneratorpitsumps.Thesesumpscollectlimitedwaterandfueloil(lessthan500gallonsperyear)fromtheemergencydieselgeneratorroom.Periodically,theoil/waterseparatorsarepumpedcleantoremovetheaccumulatedoilforproperoff-sitedisposal.TheSecurityDieselGeneratorDaytankhasanoverflowlinethatconnectstotheUnitOnetransformerdeckcatchbasin.Dischargetothecatchbasinwouldonlyoccurifthedaytankwereoverfilled.Proceduresandlevelindicatorsareusedtopreventoverfilling. CHEMICALLABANALYSISAdditionalInformationSectionIItem6,SubpartACookNuclearPlantGroundwaterPermitApplicationPLANTCHEMISTRYLAB(toOutfallOOD)ChlorideFluorideHardnessHydrazineSilicaOil6GreasepHFreeMineralAcidityTotalPhosphorusChemicalOxygenDemandSulfateNitritesTotalResidualChlorineASTMD-512-81(1986)ASTMD-1179-80(1986)StandardMethods413B(1985)ASTMD-1126-80EPA-600-4-79-020Method130.2(1979)ASTMD-1385(1983)ASTMDPowerWaterAnalysisManualCH-41EPA-600-4-79-020Method413.1(1979)ASTMD-1293-84StandardMethods423(1985)ASTMD-1067-82MethodBEPA-600-4-79-020Method365.3(1979)EPA-600-4-79-020Method410.2(1979)ASTMD-516-82MethodA(1985)EPA-600-4-79-020Method375.3(1979)StandardMethods426A(1980)DeterminationofCorrosionInhibitionbyCalgonCorporationASTMD-1253(1986)StandardMethods(1980)TRAININGBUILDINGLAB'toOutfallOOE)BoronChlorideFluorideHaxdnessHydrazineSilicaOil&GreasepHTotalPhosphorusAtomicAbsorptionMetalsIonChromatographyWestinghouseChemicalAnalysisProcedureforPWRWCAD7333Rev.1(1973)ASTMD-512-81(1986)ASTMD-1179-80(1986)StandardMethods413B(1985)~ASTMD-1126-80EPA-600-4-79-020Method130.2(1979)ASTMD-1385(1983)ASTMPowerWaterAnalysisManualCH-41EPA-600-4-79-020Method413.1(1979)ASTMD-1293-84StandardMethods423(1985)EPA-600-4-79-020Method365.3(1979)StandardMethods302B,303A(1985)EPA-600-4-79-020Method215.1,220.1,242.1,249.1,273.1(1979)DionexSystemOperatorsManual WASTEWATERFLOWDIAGRAMPlMAKEUPPLANT'dditionalInformationSectionIItem6.SubpartACookNuclearPlantGroundwaterPermitApplicationLakeTownship(PotableWater)Non-essentialServiceWater(NESW)AlumAdditionPre-filterBackwash2xDayAug.eeeSodiumHypochlorite(IfNeeded)RetentionTankBlowDownIxDayOrAsNeededRejectWatertoLakeMichigan001-002SulfuricAcidorllydrochloricAcidAdditionReverseOsmosisCarbonFilterBackwash2xDayAvgOrAsNeededAcid/CausticRinseChemCleaningBiofoulingCleaningNESWwaterforsealsCationResinBedsRegenerationWasteDegasifierNESWcaaterNeutralizationTat)k(Installedby1-95)MixedBedsAnionResinBedsCausticegenerationtvastecid/CausticRegenerationWasteMakeupPlantWatertoPlantServicesTurbineRoomSumpFlowtoOOD 'E OUTFALL'ooiOUTFALL~002WASTEWATERFLOWDIAGRAMP2OUTFALL003AdditionalInformationSectionIItem6,SubpartACooknuclearPlantGroundwaterPermitApplicationUnit2Misc.CoolingUnit2DischargeIntakeForebayUnit1DischargeUnit1Misc.CoolingDyeChecksHeatExchangersSampleCoolersUnitsIP.2SJAEsDrainsCleaningWasteBioboxesUnit-2CondenserUnit-2ESWUnit-2SteamGeneratorIINESWiMakeupPlantFlowDiagramttlUnit-1CondenserUnit-1SteamGeneratorUnit-1ESWDyeChecksDrainsCleaningWastesBioboxesIn-lincMonitorsMisc.DrainsLayupDrainsU-2CCWDJWMakeupPlantRegenerationWastes(An.i)PlantHeatingBoilerU-1CCWDJWIn-lineMonitorsMisc.DrainsLayupDrainsChemFeedTankDrainsBarrelRinseNeutralizationTankInstalledBy1-95Misc.PlantSumpsNon-radLabDrainsMisc.FloorDrainsTurbineRoomSumppHMeterSodiumHydroxideSulfuricAcidMisc.ProcessedWastee.g.GlycolAutoCompositorHowMeterAbsorptionPondGROUNDWATER e WASTEWATERFLOWDIAGRAM83SEWAGETREATMENTPLANTAdditionalInformationSectionIItem6,SubpartACookNuclearPlantGroundwaterPermitApplicationFireProtection(Frusbingandsassingwaresisdirccscdsossorsnwascrand/orgroundwarcr).LakeTownshipPotableWaterSupplyPlantSiteSanitaryWaste&KitchenWasteRadiographProcessingLaboratoryWastePhotoLabTrainingBuildingChemistryLabWasteTrainingBuildingHVACSystemWastesPortableToiletWastesEastExtendedAerationPlantLimestoneBedNeutralizationTankEIIlucntNorthOutfallOOESeepageTankSouthOutfallOOESeepageTankMiscellaneousRinsingOperationslISouthExtendedAerationPlantSludgeEffluentgfProcegged)SludgeToaPOTWToGroundwater
WASTEWATERFLOWDIAGRAM-4DRYWELLSAdditionalInformationSectionIItem6,SubpartACookNuclearPlantGroundwaterPermitApplicationSecurityDieselGeneratorDayTankOverfiowUnit1MainTransformerDeckDrains(Stormwater)Unit1EmergencyGeneratorPitSumpUnit2MainTransformerDeckDrains(Stormwater)Unit2EmergencyGeneratorPitSumpUnit1CatchbasinOil/WaterSeparatorUnit2CatchbasinOil/WaterSeparatorUnit1DwellsUnit2DwellsGROUNDWATER SEEINSTRUCTIONSQNREVERSESIDESECT1ONINUMBER-~MI0005827EM7AoPROVIDEAttAPOFTHETREATMENTFACILITYUXATIOtbSCNlt6Tl%LOCATIONOF~DISCNARSEPOINT(S)AIOOTIERINRR%TICNRGXKSTEDONREVERSESIDEOFPAGEaLOCATIONAIAP(SeeAttachedMap)21 INSTRUCTIONSFORCOMPLETlt4SECTIONIITEM7Thisformrequiresalocationmapofthetreatmentfacilityshowingdischargepoint(s).ENTERTHEPER4HTNUMBERINTHEBOXATTHETOPOFTHISFOIa(.THEPERMITIas(BERCANBEFOUNOONTHEFRONTPAGEOFYOUREXPIRINGPERMIT.IfthlSISanewOrnOtPreVIOualyPermittedfaCIIlty,thenleaVeblankandanumber<<IIIbeaSSlgned.ITEM7LOCATIONMAPA.Provideadetailedlocationmanofthetreatmentfacility,showingthelocationofthedischargepoint(s)forallsurfacewaterandgroundwaterdischarges,andallknownsupplyanddrinkingwaterwellsofadjacentpropertiestothefacility.Forbothsurfaceandgroundwaterdischargeapplicants,IndicatethelocationandIdentlfIcatlonnumberofanygroundwatermonitoringwellsrelativetothefacilitywhicharecurrentlybeingusedbytheapplicanttomonitorthegroundwater.Also>Includethereceivingstream,lake,orstormsewerandthestreetsandroadsInthearea.22 SEEINSTRUCTIONSONREVERSESIDESECTIONINUMBERWMZ0005827.EM8CONCENTRATEDANIMALFEEDINGOPERATIONAeIQVCUTEACOtCEIIIRATEOANIFEEDIMIFJCILI(IFtOCONTItAKTOIIIIIQ)SeMJSBIOFACRESUSEDFOICOtFI%I%HTFEKDIMI?CeIF11%REISOPENCOIFI%1%NTeHASARtMFFDIVERSIONAtOCONIROLSYSIENMENCONSTR'?(IFMlsCONTI'OITEN9)DsWATISTI%IESIGNBASISKRTIECWiRKSYSTIH?C%CKNKOF1%RUJRIMIAtOEHIERMJSEROFII&KBOFRAIN?lDme,2IIMXRSIOFIIQ25YEA+2IIMXRSIORIIPOT%R(SPECIFY)~e~IICI%SIMIES~s~INC%SEeWATISTIEMJ%EROFAQKSOFCONmISUTIMIERAIQGE?F>WATISTIEDESIGNSAFEIYFACBXIIORTHISCONIROLSYSTEI(?~~~essesLJ~LJAeLISTlYPEOFANINLsN/A~LJLJITEIVI9TYPENUMBEROFANIMALSINOPENANDHOUSED.INEMENTIll4IIII4IelI4IOIBsGIVE'D%MJSBIOF1HISlYPEOFANINILINOPENCOKIMJ%NTeCeGIVEll%MJSEROFTHISlYPEOFANIIVILIHMXISEDIXtlFI%%NTeAsLISTlYPEOFAHINALeBsGIVETI%MISEROFTHISlYPEOFANItsALIKOPEN%IFll&%HTeCsGIVETIEMJSEROFTHISlYPEOFANINLIHMXNEDAeLISTTYPEOFANINLeBeGIVETI%MJSEROFTHISTYPEOFANINALINOPENCOIFIMJ%HTeCsGIVETI%MJSBIOFlHISlYPEOFAHULLINMNSEDCCtFII8%HTeAsLISTlYPEOFAHIHALsBeGIVE11%MJSEROFTHISTYI%OFANIHALINOPENCOtF1%%HTeCeGIVETIEMJSEROF'THISlYPEOFANIMALINMXSEDAeLISTlYPEOFANINALeBsGIVE1HEMJ%%ROFlHISlYPEOFANINALINIXsEHCO%1%I%HTsCeGIVE11%MJmBICFTHISlYPEOFANINLININUSEDCOtFAsLISTTYPEOFANINLeBeGIVE1%MJ%EROF1HISTYPEOFANINALIHOPENCOIFIMJ%NTeCeGIVE11%MJSEROF'THIS1YPEOFANINALIHMNSEDCCH'Il&%NTsAeLISTlYPEOFANINALeBeGIVETIEMJSBIOFTHISTYPEOFANINALIHQKHCeGIVETHEMJSEROFTHIS1YPEOFANINALININUSEDCCIFI%t%NTeAeLISTlYPEOFANINLsBsGIVETI%MJSEROFTHISlYPEOFANIISLIN0%NGXFIIBJ%HTeCeGIVE11%MJSKROFTHISlYPEOFAHINALINMXISEDCOM-1%%HI'e23 INSTRUCTIONSFORCOMPLETINGSECTIONIITEMS8ANO'P.Thisformrequiresinformationaboutthedesign,size,andtypeandnumbersofanimalsInaconcentratedanimalfeedlot.ENTERTHEPERMITNHBERINTHEBOXATTHETOPOFTHISFORM.THEPERMITNIÃBERCANBEFO(P4)ONTHEFRONTPAGEOFYOUREXPIRINGPERMIT.IfthisIssnewornotpreviouslypermittedfeelllty,thenleaveblankandnnumbervllIbeassigned.IGENERALINFORMATIONNotallanimalfeedingoperationsarerequiredtoobtainNpoEspermits.ExclusionsarebasedonsIteandoccurrenceofdischarge.Inparticular,foranimalfeedingoperations,thesizecutoffsdependonwhetherornotpollutantssradischargedthroughnmanmadedeviceorbydirectcontact<<Iththefacilityoranimals.AfacilityforlayinghensorbrollersIsnotrequiredtohaveapermitunlessIthnsnliquidmanurehandlingsystemorcontinuousoverflowwatering.Also,facilitieswhichdischargeonlyInthecaseofn25year,24hourstormeventarenotrequiredtohaveapermit.ITEM9-8Giveonlythearesusedfortheanimalconfinementorfeedingfacility.OonotInclude.snyareausedforgrowingoroperatingfeed.~0IITEM9-CVECheck"Yas"lfsnysystemforcollectionofrunoffhssbeenconstructed.SupplytheInformationunder0,E,andFtothebestofyourknowledge.ITEMIO-BANOC'ito,gI'!GivethemaximumnunberofeachtypeofanimalInopenconfinementorhouseduri'erroof(eitherpartiallyortotally)whichareheldntyourfacilityforstotalof45daysormoreInanyl2monthperiod.IUsethefollowingcategoriesfortypeofanimals:SlaughterCattle-FeederCattle-MatureDairyCattle(milkedordry)-Swine(eachweighingover55pounds)-Horses-Sheep-Lambs-Turkeys-LayingHensI-Broilars(DucksIApermitlsnotrequiredunlessthefacilityhassIlquldmanurehandlingsystemorcontinuousoverflowwatering.ANIMALFEEDINGOPERATIONmeansalotorfacility(otherthananaquaticanimalproductionfacility)wherethafollowingconditionsaremet:(A)Animals(otherthnnaquaticanimals)havebeen,are,orwillbestabledorconfinednndfedormaintainedforatotalof45daysormoreInanyI2monthperiod)and(8)Crops,vegetation,foragegrowth,orpost-harvestresiduesaranotsustainedinthenormalgrowingseasonoveranYportionofthelotorfacility.TwoormoreanimalfeedingopertlonsundercameoownershipnrensingleanimalfeedIngoperationlftheyadjoineachotherorIftheyuseaccnmonareaorsystemforthedisposalofwastes.ANIMALUNITmeansaunitofmeasurementforanyanimalfeedingoperationcalculatedbyaddingthefollowingnunbersfThenumberofslaughterandfeedercattlemultipliedby1.0;plusthenumberofmaturedairycattlemultipliedby1.4;plusthenumberofswineveighlngover25kllogrnms(approximately55pounds)multipliedby0.4;plusthenumberofsheepmultipliedbyO.l;plusthenumberofhorsesmultipliedby2.0.CONCENTRATEDANIMALFEEDINGOPERATIONmeansananimalfeedingoperationwhichmeetsthecriteriasetforthIneither(A)or(8)belowor<<hlchtheDirectordesignatesassuchonscase-by-casebasis.A.MorethanthenunbersofanimalsspecifiedInsnyofthefollowingcategoriessreconfined(REGARDLESSOFWHETHERASURFACEWATERDISCHARGEEXISTS):t.I.I,OOOslaughterorfeedercattle.2.700maturedairycattle(whethermllkedordrycows).3.2,500swineeachweighingover25kllogrnms(approximately55pounds).4.500horses.5.I0,000SheepOrlambe.6~55,000turkeys.7.I00,000layinghensorboilers(lfthefacilityhasscontinuousoverflowwatering).B.30,000layinghansorbrollers(Ifthefacilityhassliquidmanurehandlingsystem).9.5,000ducks.10.I,000animalunits.B.Morethanthefollowingnunbersandtypesofanimalsareconfined(WITHSURFACEWATERDISCHARGEASDESCRIBEDBELOw':I.300slaughterorfeedercattle.24 2~200maturedairycattle(whethermilkedordrycows).3.750swineeachweighingover25kllcgroas(approximately55pounds).4.I50horses.5.3,000SheepOrlambS.6.I6,500turkeys.30,000layinghensorbrollers(ifthefacilityhascontinuousoverflowwatering).8.9,000layinghensorbrollers(lfthefacilityhasaI)quidmanurehandlingsystem)~9.I,500ducks.IO.300animalunits."Eitheroneofthefollowingconditionsare'mat:pollutantsaredischargedIntowatersoftheUnitedStatesthrouchamamsadeditch,flushingsysteaorothersimilarmannadadevice(wmaenade"meansconstructedbymanandusedforthepurposeoftransportingwastes);orpollutantsaredischargeddirectlyintowatersoftheUnitedStates<<hlchoriginateoutsideofandpassover,across,orthroughthefacilityorotherwiseccmeIntodirectcontact<<IththeanimalsconfinedIntheoperation.provided,however,thatnoanimalfeedingoperationIsaconcentratedanimalfeedingoperationasdefinedabovelfsuchanimalfeedingoperatlcndischargesonlyIntheeventofa25year,24hourstormevent.N0TE:Thepermitteeshallcontinue<<IthSection,llandaddressItemsI,2,4,and5onpages3).33,and35. SEEINSTRUCTIONSONREVERSESIDESECTIONIPERMIT~ggppp5827EM10AOVATICANIMALPRODUTIONFACILITYtTEM't1SPECIESOFAQUATICANIMALSPRODUCEDATTHISFACILITYAsDOYOUOPERATEANAXIATICANIHALPRODUCTIONFACILITY?(IFtftsCCNfltAETOITBI12)BsINDICATETIETOTALtAtSEROFPON5sRACKHAYSAMISINILARSTRÃllRESATYOlRFACILITYsCsIN)ICATKINltIICHCALENDARtONIHtVtXItttIFEED1%OCQRIsD.MKRTtaTOTALIANBEROFPlXtKISOFPOCOFKDIXRImTHISAsISTHISSPECIEAHARNCRtXXDHATERSPECIE?g/pBsGIVETHEt4VEOFTHISSPECIEsCsMERTIETOTALHARVESTABLEHEIQITOFTHISSPECIEPRODUCEDBYTHISFACILITYPERYEARINRXMSsDsMERTIEHAXItttIHEIGHTPRESENTFORTHISSPECIEttIICHHEXADREPRESENTYMI8ÃNLOPERATIONsAsISTHISSPECKA1ARHORCOLDI%TERSPECIEB>>GIVETIEWEOFTHISSPECIEsCsEN1KRTIETOTALH4RVESTABLEHEIGHTOFTHISSPECIEPRmXDBYTHISFACILITYPERYEARINRXtOS>>DeMKRTIEHAXItltIttEIQITPRESE%RRTHISSPECIEttIICHHXADREPRESENTYOUItOAHALOPERATIONsA,15THISSPECIEAHARIICRGXDHATERSPECIE?gB~GIVETIENA%OFTHISSPECIEsVnCsMKRTHETOTALNRVESTABLENEIQITOFTHISSPECIEFDsENIERTHEtVUUttttHEIGHTPRESENTFORTHISSPECIEISICHICXU)REPRESENTVOIRNXHALCPERATIONsAsISTHISSPECIEAHARIIORCXDHATKRSPECIE?BsGIVETIENttEOFTHISSPECIEsCsENIKRTIETOTALHARVESTABIEHEIGNfOFTHISSPECIEPtmXH)BYTHISFACILITYPERYEIRINPOQOSeDsENIKRTIEHAXItMHEIGHTPRKSBIfFCRTHISSPECIEttIICHlORDRERIESENTYONtCNNLOPERATIONsAsISTHISSPKIEAHARtlCRCOLDHATERSPECIE?BsGIVETIEN4%OF'THISSPECIEsCeMKRTHETOTALNRVESTABLEHEIGHTOFTHISSPECIEPRQOUCEDBYTHISFACILITYPERYEARINPresDsEHIKRTIEHAXIt%MIEIGHTPRESENTFCRTHISSPECIEtSIOIlORDREPRESENTYQRtCÃNALOPERATIQlsAeISTHISSPECIEAHAttIOROXDHATERSPECIE?BsGIVETIEHttKOFTHISSPECIEsCsENfKRT%TOTALtVUIVESTABLEHEIGHTOFTHISSPECIEPRCQXEDBYTHSFACTYYNDsENTERTIEHLYIttttNEIGHfPRESENfFCRTHISSPECIEtttICHMXADREPRESENTYNRtCRPALOPKRATIONe INSTRUCTIONSFORCCMPLETINGSECTIONIITEMS10ANOIIThisformrequiresinfq{mationaboutthedesign,size,andtypeandnumbersofanimalsInanaquaticanŽalproductionfeellly.ENTERTHEPERMITNIA{BERINTHEBQXATTHETOPOFTHISFORMTHEPERMITNIPBERCANBEFOUNDONTHEFRONTPAGEOFYOUREXoIRINGPFRMIT.IfthlSISanewOrnOtpreVIOuSlype{mittedfaClllty,thenleaVeblankandanunberWillbeaSSigned.GENERALINFORMATIONNotailfishfarmsarerequiredtoobtainNPOESpermits.Exclusionsarebasedonsizeandoccurrenceofdischarge.Foraquaticanimalproductionfacilities,thesizecutoff5arebasedonwhetherthespeciesarewa{m~aterorcoldwater,ontheproductionweightperyearInharVeStabiePOundS,andOntheZmquntOffeedingInpaundSOffOOdIfOrCOld~ater5Pecie5).AISO~faCIlitleSwhichdischargelessthan30daysperyear,oronlydurlnoperiodsofexcessrunoffIforwarm~aterfish)arenotrequiredtohaveapermit.coNcENTRATEQAQUATlcANIMALpRQQUOTIQNFAQII,ITYmeansahatcnery,tishfern,orotherfacilitywhichcontains,growsorholdsaquaticanimalsIneitherOfthefollowingcateaorles,orwhichtheDirectordesianatesassuchonaca5e-by-caseba515~A.Coldwaterfishspeciesorothercold~ateraquaticanimalsIncluding,butnotlimitedto,theSalmonidaefamilyotfishIe.g..troutandsalmon)Inponds,racewaysorothersimilarstructures~blebdischargeatleast30daysperYearbutdoe5notInclude:I..Facilitieswhichproducelessthan9,090harvest~eightkllogramsIapproxlmateiy20,000pounds)otaquaticanimalsperyear.2.,Facilitieswhichfeedlessthan2,272kllograms(approximately5,0QQpounds)otfoodduringthecalendarmonthotmaximumfeeding.B.Harm~aterfishspeciesorotherwarmwateraquaticanimalsIncluding,butnotlimitedto,theAmelurldae,Cet{achldae,andCyprlnldaefamiliesotfish(e.g.,respectlveiy,catfish,sunfish,andminnows)Inponds,raceways,orothersimilarStruCtureSwhlChdiSChargeatleaat30dayaperyear,butdOeSnatInClude:I.Closedpondswhichdischargeonlyduringperiodsotexcessrunoff.2.Facilitieswhichproducelessthan45,454harvestweightkllog{ams{approximately100,000pounds)ofaquaticanimalsperyea{',ITEN10BGivethetotalnunberofdiscretepondsorracewaysInyourfacility..Under"other"giveadescriptivenameofanystructurewhich15notapondoraracewaybutwhichresultsIndischargetowatersoftheUnitedStates.ITEN10-DThevaluegIvenformaximummonthlypoundsoffoodshouldberepresentativeofyournormaloperation.ITEN118Thenameoffishspeciesshouldbeproper,c{mtnon,orscientificnames.ITENIlCANDDThevaluesgiventortotal~eightproducedbyyourfacilityperyearandthemaximum~eightpresentatanyonetimeshouldberepresentativeofyournormaloperation.NOTE:ThepermitteeshallcontinuewithSectionIIandaddressItemsI,2,4,and5onpages31,33,and35.28 SECTIONtMI0005827iTEM12LISTNAHEANDHAILINGADDRESSOFALLPROPERTY$4ERSALIACENTTOTIETREATMENTFACII.ITYANDORDISC%ROE/DISPOSALAREAsSeeattachedlist.MAILINGLISTOFADJACENTPROPERTYOWNERS29 SO MI0005827SectionI,Item12ADJACENTPROPERTYOWNERSEASTInterstateI-94(MichiganDept.ofStateHighways)SOUTHLakeTownshipc/oGeraldWaskoTownshipSupervisor1410ShawneeRoadBridgman,MI49106WESTLakeMichigan(StateofMichiganandUnitedStatesofAmerica)NORTHRosemaryBeach11-11-68000038-00-5Tengerstrom,EricH.;3415S.59th;Cicero,IL606500037-02-5Tengerstrom,EricH.;3415Cicero,IL60650S.59th;0037-01-7Merkel'sFloorCovering,Inc.;8314ScottdaleRd.;BerrienSprings,MI491030037-00-9Kraiss,Wilbur&Marilou;5004S.LongAve.;Chicago,IL60638I0036-00-2Temmel,EdwardP.&Kathleen;9617E.ShoreDr.;OakLawn,IL604530033-00-3Gilpin,Clark&Nancy;1005E.60thSt.;Chicago,IL606370032-01-'5Wittebort,RobertJ.,Jr.&NancyH.;3180N.LakeshoreDr.;Chicago,IL606570030-02-1Meier,Paul&LouiseG.;1357MadisonPark;Chicago,IL606150028-01-8Balka,RonaldA.&JanetM.;3334LouiseDr.;Lansing,IL60438 SectionI,Item12ADJACENTPROPERTYOWNERSPage211-1100060002-030004-000004-040004-010004-0211-11-00070013-000013-01MichiganDept.ofNaturalResources;P.O.Box30028;Lansing,MI48909FranklinRealEstateCo.;P.O.Box2000;St.Joseph,MI49085Temmel,EdwardP.;9617E.ShoreDr.;OakLawn,IL60453Caparo,WilliamE.6Oyler,KathrynE.;122S.EllsworthPl.;SouthBend,IN46635RosemaryBeachCorp.;c/oSecretary;3415S.59thSt.;Cicero,IL60650LakeCharterTwp.;ShawneeRd.;Bridgman,MI49106LakeCharterTwp.;ShawneeRd.;Bridgman,MI491060006-01IndianaMichiganPowerCompany0001-010004-0111-11-000500290036-010027-000036-000036-0211-11-0005-000201-611-11-00080041-000009-00LakeCharterTwp.;ShawneeRd.;Bridgman,MI49106LakeCharterTwp.;ShawneeRd.;Bridgman,MI49106Technisand,Inc.;11833RavennaRd.;Chardon,OH44024Ruff,TimothyW.;P.O.Box504Bridgman,MI49106Technisand,Inc.;11833RavennaRd.;Chardon,OH44024Emery,Martin;Hopkins,ElwoodJ.&MableN.;7499ThorntonDr.;Stevensville,MI49127IndianaMichiganPowerCompanyBankofAmericaTexasP.O.Box650380Dallas,TX75265MichiganDept.ofTransportation;Lansing,MI48900FranklinRealEstateCo.;P.O.Box2000;St.Joseph,MI49085
NARSULEX,'xQ(~iQIiMATERlALSAFETYDATASHEETSulfuricAcid1.PRODUCTANDCOMPANYIDENTIFICATION.ProductName:SulfuricAcidFormui:H,SO,MolecWarWeight:98.08ChemicalName:SulfuricAcidghemlcaiFamily:InorganicAcid~Su7664-93-9~Synonyms:SulphuricAcid,OilofVitriol,BatteryAcidproductUse:Usedtnmanufactureoffertilizers,explosives,otheracids,metalpicklingandpetroleumprocessing.MARSULEXinc.111GordonBakerRoadSuite300orthYork,ONTM2H3R1(416)496-9655MARSULEXInc.40RichardsAvenueP.O.Box5453Nofwalk,CT06856-5453(203)8544300EMERGENCYTELEPHONENUMBER(800)263-9502PreparedbyMARSULEXTechnicalSection(416)496-4164.2.COMPOSITION/INFORMATIONONINGREDIENTS-SulfuricAcidNn-WaterInt%byWt.70-100%OM%CASNumber7664-93-97732-1863.HA2'ARDINFORMATIONEMERGENCYOVERVIEW:/OangerlExtremelycorrosive.Causessevereburns.Reactsviolentlywithwater.Highlyreactiveandcapableofignitingcombustiblematerialsoncontact.Notflammable,butreactswithmostmetalstoformexplosivehydrogengas./SulfuricAcklhacolorlesstoamber,deartoslightlycloudy,oilyliquid.NationalRreProtectionAssochtlon(NFPA)RatingHazardousMaterialsIdentificationSystem(HMIS)RatingRREf04Extreme/Severe'3High/Serous~2Moderate1=Slight0=MinimumWWaterReactiveectNeDate:Februay,1993.Supefaedea:Februasy,1990MARSULEXMSOS4010EPage1of9 MATERIALSAFETYDATA'SHEET,SulfuricAcid3.HAZARDINFORMATtON(continued)POTENTIALHEALTHEFFECTS:ExposureLlmlts:SulfuricAcidACGIH(TLV)1mg/m'TWA)3mg/m'STEL)OSHA(PEL)1mg/8(TWA)Incontactwiththeskin:Concentratedsolutionmaycausepainandsevereburnstotheskinandbrownishoryellowstains.Prolongedandrepeatedexposuretodilutesolutionsmaycauseirritation,redness,paInanddryingandcrackingoftheskin.lncontactwiththeeyes:ImmediatepaIn,severeburnsandcornealdamagewhichmayresultinblindness.CInhaled:MistsandvaporsmaycauseIrritationoftheeyes,noseandrespiratorytract.MaycauseIncreased'ulmonaryresistance,transientcoughandbronchoconstrlctlon.SevereoverexposuremayresultInlungcollapseandpulmonaryedemawhichcanbefatal.Ingested:SevereburningandpainInthemouth,throatandabdomen.Vomiting,diarrheaandperforationoftheesophagusandstomachliningmayoccur.LongTermExposure:,Repeatedexposuremayproduceerosionanddiscolorationofteeth.~l'lthoughnodirectlinkhasbeenestablishedbetweenexposuretosulfuricacid,Itself,andcancerInman,theWorldHealthOrganization(WHO)InternationalAgencyforResearchonCancer(IARC)haveconcludedthatoccupationalexposuretostrongInorganicacidmistscontainingsulfuricacidiscarcinogenictoman,causingcancerofthelarynx(thevoicebox)and,toalesserextent,thelung.Exposuretoanymistoraerosolduringtheuseofthisproductshouldbeavokiedand,inanycase,keepexposuresbelowtheoccupationalexposurelimitforsulfuricacid.1Corrosiveeffectsontheskinandeyesmaybedelayed,anddamagemayoccurwithoutthesensationoronsetofpain.Repeatedoverexposuremayleadtocontactdermatitis,maycausebronchitiswithcough,phlegm,shortnessofbreathandemphysema,cancausechronicrunnynose,tearingoftheeyes,nosebleedsandstomachupsets.StrictadherencetofirstaidmeasuresfollowinganyexposureIsessential.ExistingMedicalConditionsPossiblyAggravatedByExposure:SkinIrritationmaybeaggravatedinIndividualswithexistingskinlesions.Breathingofvaporsorsprays.(mists)mayaggravateacuteorchronicasthmaandchronicpulmonarydiseasesuchasemphysemaandbronchitis.CarcinogenicityData:Althoughtherearereportslinkingexposuretosulfuricacidtocancer,thisproductIsnotclassifiedbyNTP(NationalToxicologyProgram),notregulatedascarcinogenicbyOSHA(OccupationalSafetyandHealthAdministration),andhasnotbeenevaluatedbyIARC(InternationalAgencyforResearchonCancer)orACGIH(AmericanConferenceofGovernmentalIndustrialHyglenlsts).(Seealso,LongTermExposure).EffectiveDate:February,1993Supersedes:February,1990MARSULEXMSDSk010EPage2of9 NATULEX,MATERIALSAFETYDATASHEETSulfuricAcid4.FlRSTAIDMEASURESPromptremovalofthismaterialfromcontactwiththebodyisofutmostimportance.&TARTFIRSTAIDATONCE.Precaution:Personsattendingthevictimshouldavoiddirectcontactwithheavilycontaminatedclothingandvomitus.Wearimperviousgloveswhiledecontaminatingskinandhair.Incontactwiththeskin:Flushskinwithrunningwaterforaminimumof20minutes.Startflushingwhileremovinggcontaminatedclothing.Ifirritationpersists,repeatflushing.ObtainmedicalattentionIMMEDIATELY.Donottransportvictimunlesstherecommendedflushingperiodiscompletedorflushingcanbecontinuedduring,transport.a,WhilethepatientIsbeingtransportedtoamedicalfacility,applycompressesofIcedwater.Ifmedicaltreatmentmustbedelayed,Immersetheaffectedareainicedwater.Ifimmersionisnotpractical,compressesofIcedwatercanbeapplied.Avoidfreezingtissues.Discardheavilycontaminatedclothingandshoeslnamannerwhichlimitsfurtherexposure.Otherwise,washclothingseparatelybeforereuse.lncontactwiththeeyes:Immediatelyflusheyeswithrunningwaterforaminimumof20minutes.Holdeyelidsopenduringflushing.IfIrritationpersists,repeatflushing.ObtainmedicalattentionIMMEDIATELY.Donottransport~~victimuntiltherecommendedflushingperiodIscompletedunlessflushingcanbecontinuedduringtransport.Inhaled:Movevictimtofreshair.GiveartmclalrespirationONLYIfbreathInghasstopped.GiveCardiopulmonaryflesuscltatlon(CPR)IftherelsnobreathingANDnopulse.ObtainrnedlcalattentionIMMEDIATELY.Ingested:Ifvictimlsalertandnotconvulsing,rinsemouthandgiveNto1glassofwatertodilutematerhl.Ifspontaneousvomitingoccurs,havevictimleanforwardwithheaddowntoavoidbreathinglnofvomitus,rinsefmouthandadministermorewater.IMMEDIATELYcontactlocalpoisoncontrolcenter.VomitingmayneedtobeInducedbutshouldbedirectedbyaphysicianorapoisoncontrolcenter.IMMEDIATELYtransportvictimtoanemergencyfacility.NotetoPhysician:Alltreatmentsshouldbebasedonobservedsignsandsymptomsofdistressinthepatient.Medicalconditionsthatmaybeaggravatedbyexposureindudeasthma,bronchitis,emphysemaandotherlungdiseasesandchronicnose,sinusorthroatconditions.Severityofthebumisgenerallydeterminedbytheconcentrationofthesolutionandthedurationofexposure.Intheeventofskinoreyecontact,lmmedhteandthoroughflushingisessential.Continuedwashingoftheeffectedareawithcoldoricedwaterwillbehelpfulinremovingthelasttracesofsulfuricacid.Creamorointmentsshouldnotbeappliedbeforeorduringthewashingphaseofthetreatment.5.FIREFtGHTINGMEASURESFshPoint(method):Notapplicable,productIsnon-flammableutolgnltlonTemperature:NotcombustibleRammabllityLimitsInair(%):UELNotapplicableLELNotapplicableEffectiveDate:February,1993Superaedea:February,1990MARSULEXMSDSfffetOEPage3of9 MATERIALSAFEIYDATASHEETSulfuricAcid5.FIREFIGHTINGMEASURES(continued)FireExtinguishingMedia:Forsmallfiresusedrychemicalorcarbondioxide.ForlargeAres,floodfireareawithwaterfromadistance.Expectviolentreactionwithwater.Donotgetsolidstreamofwateronspilledmaterial.SpecialFireFightingProcedures:WearaNIOSH/MSHAapprovedselfwontalnedbreathingapparatusIfvaporsormistsarepresentandfullprotectiveclothing.ForfightingfiresIncloseproximitytospillorvapors,useacid-resistantpersonalprotectiveequipment.EvacuateresidentswhoaredownwindofAre.PreventunauthorizedentrytoArearea,Dikeareatocontainrunoffandpreventcontaminationofwatersources.Neutralizerunoffwithlime,sodaashorothersuitableneutralizingagents(seeDeactivatingChemicals,Section6).Coolcontainersthatareexposedtoflamewithstreamsofwateruntilfireisout.OtherFireorExplosionHazards:Notflammablebuthighlyreactive.Capableofignitingfinelydivkledcombustiblematerhlsoncontact.Reactsviolentlywithwaterandorganicmaterialswithevolutionofheat.Extremelyhazardous.~incontactwithmanymaterials,particularlycarbides,chlorates,fulmlnates,nltratesandpicrates.Sulfuricacidreactswithmostmetals,especiallywhendilutetogiveflammable,potentiallyexplosivehydrogengas.Hydrogengascanaccumulatetoexplosiveconcentrationsinsideconfinedspaces.FollowapproprhteNFPAcodes.6.ACCIDENTALRELEASEMEASURESStepstobetakenIntheeventofaspillorleak:Removeallignitionsources.Ventilatearea.UseappropriatePersonalProtectionEquipment.Preventliquidfromenteringsewersorwatetways.Dikewithinertmaterial(sand,earth,etc.).Stoporreduceleakifsafetodoso.CollectIntocontainersforreclamationordisposalonlyifcontainer~r(ssuitabletowithstandthematerial.Consklerlnsituneutralizationanddisposal.Ensureadequatedecontaminationoftoolsandequipmentfollowingdeanup.ComplywithFederal,Provincial/Stateandlocalregulationsonreportingreleases.=:"DeactivatingChemicals:Ume,limestone,sodiumcarbonate(sodaash),sodiumbicarbonate,dilutesodium'hydroxide,diluteaquaammonia.WasteDisposalMethods:Disposeofwastematerialatanapprovedwastetreatment/disposalfacility,Inaccordancewithapplicableregulations.Donotdisposeofwastewithnormalgarbageortosewersystems.Note-Clean-upmaterialmaybeaRCRAHazardousWasteondisposal..-'SpillsaresubjecttoCERCLAreportingrequirements:RQ=1000lbs.7.HANDLINGANDSTORAGEPrecautions:WearappropriatePersonalProtectionEquipment.Donotbreathspraysormists.DonotIngest.DonotgetIneyes,onskinoronclothing.Keepignitionsourcesawayfromsulfuricacidstorage,handlingandtransportationequipment.HandlingProceduresandEquipment:Carbonsteelorstainlesssteelmaterialsaresuitableforuseforacidconcentrationsequaltoorgreaterthan93%.However,theeffectoflowerconcentrationsonthematerhlsofconstructioncanbeverycomplex.Contactproductsupplierforspecificrecommendatlonswhenhandlingsulfuricacidatstrengthslessthan77%.EffectiveOate:February,1993Supersedes:February,1990MARSULEXMSDS4010EPage4of9 NAILciULKK...MATERIALSAFETYDATASHEETSulfuricAcid7.HANDLINGANDSTORAGE(continued)StorageTemperature:Storeabovefreezingpoint(Section9).ElevatedtemperatureswillIncreasethecorrosion/rateofmostmetals.StorageRequirements:Storepackagedacidinadry,well,ventilatedlocationawayfromcombustibles,oxkllzers,bases,ormetallicpowders.Storagetanksshouldbeprotectedfromwateringress,bewellventilated,and'aintainedstructurallyinasafeandreliablecondition.OtherPrecautions:Sulfuricacidwillattacksomeformsofplasticsandcoatings.Alwaysaddacidtowater-notgwatertoacid.IfkeptInupperfloorsofbuilding,floorsshouldbeacklproofwithdrainstoarecoverytank.8.EXPOSURECONTROLS/PERSONALPROTECTION-'RecommendatlonslistedinthissectionIndicatethetypeofequipmentwhichwillprovkleprotectionagainstoverexposuretothisproductConditionsofuse,adequacyofengineeringorothercontrolmeasures,andactualexposureswilldictatetheneedforspecificprotectivedevicesatyourworkplace.~<EngineeringControls:Localexhaustventilationrequired.spiratoryProtection:ANIOSH/MSHAapprovedair-purifyingrespiratorequippedwithacidgas/fume,dust,mistcartridgesforconcentrationsupto10mg/nf'.Anair-suppliedrespiratorifconcentrationsarehigherorunknown.S)tinProtection:impervious(l.e.,neoprene,PVC)gloves,coveralls,bootsand/orotheracidresistantprotective~clothing.EyeProtection:Tight-fittingchemicalgogglesandfaceshield./OtherPersonalProtectiveEquipment:Wherethereisadangerofspillingorsplashing,acidresistantapronsorsuitsshouldbeworn.Trouserlegsshouldbewornoutside(nottuckedin)rubberboots.Safetyshowersand~eyewashfountainsshouldbeInstalledinstorageandhandlingareas.9.PHYSICALANDCHEMICALPROPERTIEShPhysicalState:LlqukfAppearanceandOdor.SulfuricacidIsacleartoamber,heavy,oilyliquidwhichmayhaveasharppenetratingodor..OdorThreshold:NodataBoilingPoint:77.67%:193'C(380'F);93.19%:276'C(529'F);98%:330'C(626'F)Melting/FreezingPoint:77.67%:-11.2'C(+11.6'F);93.19%:-29.5'C(-21.1'F);98%:-1.1'C(30'F)VaporPressureat40'C(102'F):77.67%:1.2mmHg;93.19%:0.0016mmHg;98%:.0.002mmHgSpecificGravityat16'C(60'F):77.67%:1.7059;93.19%:1.8354;98%:1.8437VaporDensity:(Air=1):3.4sulfuricacidcomponentBulkDensity:Notapplicable(seespecificgravity)ffecthreDate:February,1993Supersede@February,1990MARSULEXMSDS401OEPage5of9 MATERIALSAFETYDATASHEETSulfuricAcid9.PHYSICALANDCHEMICALPROPERTIES(continued)EvaporationRate:Notapplicable/~.Solubility:MiscibleInallproportionsInwater.Alsosolubleinalcohol.pH:0.3(1Nsolutionat25'C/78'F)10.STABILITYANDREACTIVITYStability:.~UnderNormalConditions:Stable,butreactsviolentlywithwaterandorganicmaterialswithevolutionofheat.UnderFireConditions:Decomposestoformsulfuroxides(SQ).ConditionstoAvoid:Temperatureswhichmayhaveanegativeeffectonthematerialsofconstructionusedlnequipment.MaterialstoAvoid:Contactwithorganicmaterials(suchaschlorates,carbldes,fulmlnatesandplcrates)maycause,fireandexpiosions.Contactwithmetalsmayproduceflammablehydrogengas.Whendiluting,addacidtowater.DoNOTaddwatertotheacid.nHazardousDecomposltlonorCombustionProducts:Toxicgasesandvapors(e.g.sulfurdioxide,sulfuricacid;vapors/mistsandsulfurtrloxkfe)maybereleasedwhensulfuricaciddecomposes.HazardousPolymerization:WIIInotoccur11.TOXICOLOGICALINFORMATIONToxicologicalData:.Lox,(oral,rat)2140mg/kgL+(inhalatlon,rat)=510mg/nt'or2hrsSkineffects(rabbit):SevereirritationEyeeffects(rabbit):SevereirritationCarcinogenicityData:Althoughtherearereportslinkingexposuretosulfuricacidtocancer,thisproductIsnot.classiedbyNTP(NationalToxicologyProgram),notregulatedascarcinogenicbyOSHA(OccupationalSafetyandHealthAdministration),andhasnotbeenevaluatedbyIARC(IntematlonalAgencyforResearchonCancer)orACGIH(AmericanConferenceofGovernmentalIndustrialHyglenlsts).SeeSection3.HazardInformation,regardingPotentialHealthEffects(LongTermExposure)forfurtherdiscussion.ReproductiveEffects:NoinformationIsavailableandnoadversereproductiveeffectsareanticipated.MutagenicityData:No'informationisavailableandnoadversemutageniceffectsareanticipated.,TeratogenicltyData:NoInformationisavailableandnoadverseteratogenIceffectsareanticipated.SynerglstlcMaterials:Noneknown/EffectiveOats:February,1993Supersedes:February,1990MARSULEXMSDS4010EPage6ef9 NIAII5ULKX,'ATERIALSAFETYDATASHEETSulfuricAcid12.ECOLOGICALINFORMATIONEcotoxlcEffects:Harmfultoaquaticlifelnverylowconcentrations.IjtiaybedangerousifitenterswaterIntake;Fishtoxicitycriticalconcentration10mg/L;7.34mg/L/48hrs-LymneaePalustrls-0-100%mortality,13.DISPOSALCONSIDERATIONS~Responsibilityforproperwastedisposallswiththeownerofthewaste.Workwiththeappropriateregulatorybodiestoensurecompliancewithregulations.~ConsiderthecollectionofresidualsulfuricacidIntocontainersforreclamationordisposalonlyifthecontainerIssuitabletowithstandthematerial.~Consklerlnsituneutralizationanddisposal.Clean-upmaterhlmaybeaRCRAHazardousWasteondisposal.~Provincial/StateorlocalregulationsorrestrictionsarecomplexandmaydifferfromFederalregulations.~Theinformationappliestothematerialasmanufactured;processing,neutralizing,useorcontaminationmaymaketheInformationinappropriate,InaccurateorIncomplete.14.TRANSPORTINFORMATIONU.S.(UnderDOT)//ShippingName:RQSulfuricacidHazardChssorDivision:8ProductIdentificationNo.(PIN):UN1830PackingGroup:IICanada(UnderTC)ShippingName:SulphuricacidChsslficatlon(s):Class8(9.2)ProductIdentificationNo.(PIN):UN1830PackingGroup:II16.REGULATORYINFORMATION.A.SARATitleIIIHAZARDCATEGORIESANDLISTSPrHtrlAcute(Immedhte)Health:Chronic(Delayed)Health:Rre:Reactivity:tSuddenReleaseofPressure:YesYesNoYesNo~UExtremelyHazardousSubstance(40CFR355,SARATitleIIISection302)CERCLAHazardousSubstance(40CFR302.4)ToxicChemical(40CFR372.65,SARATitleIIISection313)YesYesYesEffectiveDate:February,f993Supersedes:February,1990MARSULEXMSDS4010EPage7of9 MATERIALSAFETYDATA"SHEETSulfuricAcid15.REGULATORYINFORMATION(continued)ReportableQuantity(RQ)underU.S.EPACERCLA:RQ=1000IbTSCAInventoryStatus:Reported/Included/'~~aNaoa.WorkplaceHazardousMaterialsInformationSystem(WHMIS)WHMISClassification(s):ClassE-CorrosiveQassD1A-VeryToxicWHMISHealthEffectsIndex:AcuteLethality-verytoxic-ImmedhteCorrosivetoanimalskinWHMISingredientDisclosureList:ConfirmedA;Meetscrlterhfordisclosureat1%orgreater.ReportableQuantity(RQ)underTransportCanada-,TDG:RQ=5Iltres(orKg)IfItrepresentsadangertohealth,life,propertyortheenvironment.16.OTHERINFORMATIONAdditionalInformationandReferences1.Enviro-TIPSManual,'SulphuricAcidandOleum",EnvironmentCanada,February1984.2.Weast,R.C.(Ed.),"CRCHandbookofChemistryandPhysics',60thEdition(1980)3.Sax,N.l.,'DangerousPropertiesofIndustrialMaterials',7thEdition(1989)I4.ACGIH,ThresholdUmitValuesforChemicalSubstancesandPhysicalAgentsandBiologicalExposureIndices,1991-925.Sittig,Marshall,"HandbookofToxicaridHazardousChemicalsandCarclnogens",2ndEdition,1985RevisionIndicators:galntheleftmargInIndicatesarevisionoradditionofInformationsincethepreviousIssue.EffectivDate:February,1998supersedes:February,1990MARSULEXMSDS4410EPage8of9 NARSULKX,MATERIALSAFETYDATASHEETSulfuricAcid16.OTHERINFORMATION(continued)Legend:CAS8CERClACFRDOTEPAMSHANIOSHPELpvcRCRASARASTELTCTDGTLVTSCA'DNAUEL-ChemicalAbstractsServiceRegistryNumber-ComprehensiveEnvironmentalResponse,Compensation,andUabilltyAct-CodeofFederalRegulations-DepartmentofTransportation-EnvironmentalProtectionAgency-Theconcentrationofmaterialinairexpectedtokill50%ofagroupoftestanimals-LethalDoseexpectedtokill50%ofagroupoftestanimals-LowerExplosiveLimit-MineSafetyandHealthAdministration-NationalinstituteforOccupationalSafetyandHealth-PermissibleExposureLimit-Polyvinylchloride-ResourceConservationandRecoveryAct-SuperfundAmendmentsandReauthorlzatlonActoftheU.S.EPA-ShortTermExposureUmlt-TransportCanada-TransportationofDangerousGoodsAct/Regulations-ThresholdLimitValue-ToxicSubstancesControlAct-Time-WeightedAverage-UpperExplosiveLimitTheinformationcontainedhereinhasbeenpreparedbyMARSULEXInc.andisofferedonlyasaguidetothehandlingofthisspecificmaterhlandhasbeenpreparedIngoodfaithbytechnicallyknowledgeablepersonnel.ItIsnotIntendedtobeall-InclusiveandthemannerandconditionsofuseandhandlingmayInvolveotherandadditionalconslderatlons.Nowarrantyofanykind!sgivenorImpliedandMARSULEXInc.willnotbeliableforany.damages,losses,inJurlesorconsequentialdamageswhichmayresultfromtheuseorrelianceofanyInformationcontainedherein.EffecUveDate:February,1993Supersedes:February,1990MARSULEXMSDS4010EPage9of9
INSTRUCTIONSFORCCMPLETIIIGSECTIONIIITEMSIAND2ThiSfarmrequiresinformationonthefacility'sdischargeadditives.location,dischargeschedule,volumeflowrateandwatertreatmentFNTERTHEPERMITNUMBERINTHEBOXATTHETOPOFTHISFORM.THEPERMITNUMBERCANBEFOUNDONTHEFRONTPAGEOFYOUREXPIRINGpEIa(IT.IfthisIsanewornotpreviouslypermittedfacility,thenleaveblankandanumberwillbeassigned.EntertheoutfallnumberInspaceprovidedtoreachpageofsectIonII.FareachIndividualdischargepointoseparatesetofSectionIlformsmustbefilledout.ITEMIDISCHARGELOCATIONSCHEDULEANDFLOWRATESA.Enterthelocationofdischarge,thisshouldIncludequarter-quartersection,quartersection,section,ton,andrange.8.Listnomeofreceivingwater(Ifsurfacevoterdischarge).C.Indicatewhetherfoci)Itydischargesonaseasonalbasis.D.Ifyes,listdischargeperiods.ProvidethelandapplicationratesusedorexpectedtobeusedIntermsofinchesperhour,hourspecday.andInchesp<<w<<".F.Indicatethetypeofwastewatertobedischargedframthisoutfall.RefertothewastewatertypecodegivenIntheleftmarginMorethanonecodemaybeapplicable.G.ProvidetheaveragenumberofhoursperdayIn~hichthefacilitydischargestreatedwastewaterandthetotalnumberofdaysperyearinwhiahthed(SChargeOCCurS.H.Providecurrent(fromthelastl2months)orexpectedflowratesosrequested.RefertounitcodedivanInthelettmarginfartheappropriateflowunits.)sly-milliongallonsperyear;MGD-milliongallonsperday;GPD-gallonspecdoy.I.Providethemaximumdischargeflowratewhichyouwanttohaveauthorizedwithinthepermit.NOTE:ForNPOESpermitson)Y.theuseofsuchaflowratewillnotplaceonactuallimitrestrictionontheflawbutwillbetheflawroteusedtodevelopettluentlimits.Also,whentheMonthlyOperatingReportsarereviewedbyCompliancestaffItwillhelptheetodetermineIfanyneworIncreasedusesmighthaveoccurredatthefacility.J.Providethedesignflowtorthisspecificouttalldischarge(e.g.batchtreatmentsystemflaw,packagedtreatmentsystemflaw.orsaneotherfinitetreatmentsystemflaw).ITEM2WATERTREATMENTADOITIVESA.Indicate~batherdischargeIstreatedwithconditioners,Inhibitors,ormlcrobloclde.Ifnot,continuetoItem3.B.Givename,function,andchemicalcompositionofadditivesused.C.Givenomeandaddressofthemonutacturer(s)ottheadditivesused.D.Indicateexpectedminimis,overageandmaxlcmxsdischargeconcentrationsoftheadditive(s)torthisdischarge.Indicatewhetheryoutreatthedischargetoremovetheadditive(s)beforedischargeofwastewater.F.Indicatetheremovalefficiencyofeachadditivefromthewastewaterondthedischargefrequencyofeachadditivetothesurfacewaterorgroundwater.G.hOTE:ItIstheresponsibilityottheapplicanttosupplytheproductInformationasrequestedInthisItem4.InformationrequestedbutnotsuppliedmayresultIntheapplicationbeingreturnedtotheapplicantforccmpletlon.32 SEEINSTRUCTIONSONREVERSESIDESECTlONIIPERMIT~~"Cl4005827lTEMOJIFNI.IlfKRAsLOCATIONOFDISCNRGE~~<s'5Ee.$ErKflI~05,1M~><<,pA%EL115~B.IVYRECEIVINGHATER(IE.GROLIEWATERORIPVEOFSIRFACEBSOPTIONONDDISCHARGELOCATIONCsDOYWDISCHARGESEASWILLY.(IFIOsCCNTIIAETOE)D.IFYESeLISTDISCNRGEPERIODSN/AIOe/DAYQ~QX~IOe/DAYFLOWRATEWASTEWATEREe(ANDAPPLICATIONRATEN/AINsIR>>~~LJIRsDAYINs/NKe~~u~~'uKJNc(1CONTACTCOOUNG2NONCONTI(CTCOOLING3PROCESS4SANITARY5STORMWATERFelYPEOFHASIEHATERDISCNRGEGsDISOQRGESOHlIE(YEARLYAVERAGE)HsDISCHARGEFLOIRATEAlltimedailymaximumtimes365.TOTALYEARLYDAILYHINIMPIDAILYNXIILPI49WITjC0DE0'2J2.6~2L3L~JuWLJLJHG(RS/DAY1MGY2MGD3QPDITEMJeHAXlKPIDESIGNDISCHARGEFLOIRATEeAsDOYWUSEHATERTREAllEHTACOITIVESlOTREATYOLRDI~(IFIe.CCNTDAETOIITH3)Bs,Nt%FWCTIONeAIDOEHICALCOSOSITICNOFTAESEAIDITIVESeDESIGNSULFURICACIDSODIUMHYDROX5-2u~HNeutralization*I~TIENXDSPIDISCNRGEFLOVRATETOBEAIRICRIZEDINPBPIIT>>~6WIT)OXKWATERTREATMENTADDITIVESc.rwEaommnrm~~~SULFURICACIDSODIUMHYDROXIDE1MQ/I2UQ/IMARSULEX,INC.111GORDONBAKERROAD,SUITE30NORTHYORK,ONTM2H3R1DsEXPECTEDDISCNRXCOKENIRATIONCFAIOITIVESeAcoITIYEwvESodiumSulfateACOITIVEKVEACOITIVEHA%E.DOYWTREATlIEDISCHARGElOABOVEACOITIVES?HAVILANDPRODUCTSCOMPANY421ANNST.,N.W.GRANDRAPIDS,MI49504HIHIISJIWITSAVERAGEWITSNXDSPIWITSCXEaXE'0130011500~1~s~sLJ;~LJs~LJLJ'~M:~LJF.l4KTISlHERBClVALEFFICIBCYAM)DISONRGEPREOEHCY?N/AACOITIVEHA%ACOITIVEHA%ACDITIVEHNEIRSs/DAYDAYS/HK>>LJGASANATTAtHsEHTlDTHISAPPLICATIOIPROVIDESPECIFICNPRALIANCRAQSLTIClOXICOLOGICALD(TAOIREFERENCEHHIOIAREAVAILABLEANDINFNP(ATICNCNTHERATEOFDEGRADATICNOFlIEPRCOCISFCREKHACOITIVEeMSDSattached.*Approximatelyinstantaneousneutralizationuponmixing-(NewtanktobecompletedJanuaryof1995willensurecompleteneutralizationpriortodischarge.)S1 MATERIALSAFETYDATASHEETSODIUMHYDROXIDE50%ENDUSTREALGRADESECTIONI-IDENTIFICATIONMANUFACTURER'SNAME............ADDRESS(STREET,CITY,STATE,ZIP)PHONENUMBERea>~s~~~~~~a~~~~~~sEMERGENCYPHONENUMBER.........EFFECTIVEDATE.................TRADENAME................~....CHEMICALFAMILY..............-.Havi1andProductsCampany421AnnSt.,N.N.,GrandRapids,ME49504(616)~61-6691CHKMTREC(800)424-9Z006/18/91SODIUMHYDROXIDE50%INDUSTRIALGRADEAlkali,BaseSECTIONII-HAZARDOUSINGREDIENTSHAZARDOUSCOMPONENTSOSHA/PKLACGIH/TLV(Units)PROD.CASNSodiumHydroxide(CausticSoda)(48.5-51.0%bywt)mg/m=TNA2mg/m~T4IA1.10-73-2SodiumChlaride(0.8-1,.3%byxt)Mater(Balance)NatEstab1ishedNotEstablishedNatEstab1ishedNatKstab1ished7647-14-577~F2-18-5SECTIONIII-PHYSICALDATABOILINGPOINT~~~~~~~~~~~~~~a~~FREEZINGPOINT~~e~~~~~~~~~~~~VAPORPRESSURE(mmHg)........VAPORDENSITY(Air~i).........SOLUBILITYINH20.............APPEARANCE/ODORa~~~~~~~~~~~~~~SPECIFICGRAVITY(H20=1)......Ha~~~~~~~~~~~~~~~~s~~~~~~~~~~P.9~~F(145C)60F(15.6C)1.5C~20CNaEnlormationAvailableCompletelyClear,Color)essliquid;Odorless1~52NotEstablishedSECTIONIV-FIREANDEXPLOSIONHAZARDDATAFLASHPOINT..~..........-...........NatFlammableLONEREXPLOSIVELIMIT(%byValume)NatApplicableUPPEREXPLOSIVELIMIT(%byVolume)NatApplicableEXTINGUISHMEDEA...................AsfarSurraundingFires07/.~0/1991 C'ATERIALSAFETYDATASHEETSODIUMHYDROXIDE50/ENDUSTRIALGRADESPECIALFIREFIGHTINGPROCEDURES...WearNIOSH/MSHAapprovedselfcantainedbreathingapparatusandful1protectiveequipmentwhenthismaterialisinvolvedinafire.UNUSUALFIREHAZARD........~.......Ensolutioncausticcanreactwithamphatericmetalsgeneratinghydrogenwhichisflammableand/oreplosiveifignited.SECTIONV-HEALTHHAZARDDATACARCINOGENICITY...............NoneNTP~~~s~~~~~~~e~~~~~~~~~~~~~~~NoIARC~~~~~~~~~~~~~~~~~~~~~~~~~~noOVEREXPOSUREEFFECTS.........RednessofExposedTissueswithpossibleburnsresultingindeepulceration.PRIMARYROUTF(S)QFENTRY.....SkinContactFIRSTAIDPROCEDURES..........Ifinhaled:Removetofreshair.Ifnatbreathing',giveartificialrespiration,preferablymouth-to-mauth.Ifbreathingisdifficult,aiveoxygen.Getmedicalattention.Incaseofcontact:Immediatelyflusheyesarskinwithplentyafwaterforatleast15minuteswhileremovingcontaminatedclothingandshaes.Getmedicalattentian.Washc)othingbeforereuse.Ingestion:Donotinducevomiting.Efcanscious,dilutebygivingseveralglassesofwater.CallaPhysicianImmediately.EXPOSUREAGGRAVATEDMEDECALCONDITIONSNoneCurrentlyKnownSECTIONVI-REACTIVITYDATACHEMICALSTABILITY............CONDITIONSTQAVOID...........INCOMPATIBLEMATERIALS........DECOMPOSITIONPRODUCTS........HAZARDOUSPOLYMERIZATION......POLYMERIZATIONAVOID..........StableNatApp1icab1eAcidsNoneCurrent.lyKnawnWi11NotOccurNotApplicableSECTIONVII-SPILLQRLEAKPROCEDURE07/~0/1991 IrMATERIALSAFETYDATASHEETSODIUMHYDROXIDE50/INDUSTRIALGRADEFORSPILL~s~~~~w~i~aa><~~a~s~WASTEDISPOSALMETHOD.........Addnon-reactivedry,absorbentsuchasdiatomaceousearth.ShovelorsweepupandplaceinanapprovedDQTcontainerandseal.Flushcontaminatedareaandneutrali"=ewithdiluteacid.Disposeofspill,edorwasteproduct,contaminatedsoilandothercontaminatedmaterialsinlicensedlandfillortreatmentfacilityinaccordancewithallfederal,stateandlocalregulations.SECTIONVRESPIRATORYPROTECTION.......VENTILATION~~~~~~~~~~~~~~to~~PROTECTIVEGLOVES............EYEPROTECTION............;..QTHERPROTECTIVEEQUIPMENT...HANDLINGANDSTORAGE.........III-SPECIALPROTECTIONSuppliedairorselfcontainedbreathingapparatuswithfullfacepiece.Tomaintainvaporsbelowlimits.Rubberorotherimperviousmaterials.Chemicalsplashproofgoggles.Asafetyshowerandeyebathshouldbeavailable.Foroperationswherespillsorsplashingmayoccur,useanimperviousbodycoveringandboots.Storeincool,dry,wellventilatedarea.Keepcontainersclosedwhennotinuse.SECTIONIX-SPECIALPRECAUTIONSHAZARDCLASS~~~~~~~~~~~~~~~~DOTSHIPPINGNAME...........VNNUMBERe~~~~~~~~~~~~~~~~~~REPORTABLEQUANTITY(RQ).'...CorrosiveMaterialSODIUMHYDROXIDE,LILDUIDUN18242000lbs.REFERENCESHMIS:H-3,F-O,R-1SQDHYDOX07/0/1991 SEEINSTRUCTIONSONREVERSESIDESECTlONIIPERMIT~IYI100005827NUMBERrEM3AeNctEOFYPROCESSCotnRIBUTINITO1NEDISOIARGEltttOUGHlNISOUIFAU.At@SICCODEB,PROCESSSCHHXLE(YEARLYAVERAGE)OODSTMLECTthorn/DAY~4491~65PROCESSSTREAMSCONTRIBUTINGTOOUTFALLDISCHARGEc/tMcctOY0ccCePROCESSHASTKHATERFIDHRATESeevariouscontributingwastestreamsinSectionj.6.ADePROCESSPRODUCTIONRATEN/AA.tUYE0FPRocEsscoNIRIBUTI%ToTIEDIGQccRGKN/ATNOIXiH1NISOUTFALLANtSICCODETOTALYEARLYDAILYHINltttlDAILVHAXItXH111.354w~~T5jl.090~6.683~6WITS/TIIE1POUNDS2GALLONS3CUBICYARDS4TONS5MGY6MGD7GPDTIME1HOUR2DAY3WEEK4MONTH5YEARBePROCESSSCIEDIXE(YEARLYAVERAGE)c/tCePROCESSHASTEHATERFUXIRATEO010D.PROCESSPRODUCTIONRATEANAtEOFPRXEsscotnRIBUTINGToTIEDlsctFIRGEN/ATIRCXXIH1NISOUIFALLAtQSICCODEBePROCESSSCIEDIAE(YEARLYAVERAGE)CePROCESSHASTKHATKRFUXIRATED.PROCESSPRODUCTIONRAlEA.NAtEOFPROCESSCenRIBUTINGToTIEDISCHARGEN/AAtDSICCXXIEBePROCESSSCIEIXLK(YEARLYAVERAGE)PROCESStcASTBaTERFIDHRATEDePROCESSPRNXX,TIONRATEA.IIAtEDFPROCKsscottmrBUTINGToTIEDlscHIRGKN/ATI%GLXIH1NISOUIFAILANDSICCCCEBePROCESSSctHXLE(YEARLYAVERAGE)c/tC,PROCESSHASTBtCTERFtlHRATEOcO0DePROCESSPROIXCTIONRATEUses/oev~oevs/vsseTOTALYEARLY,DAlLYHINWPIDAILYHAXIIXHTOTALYEARLYDAII.YHININPIDAILYHAXIHHTOTAI.YEARLYDAlLYHINItSPIDAILYHAXItCPCIOUII/SSY~OSYS/YYSSTOTALYEARLYDAILYHINIIMIDAILY&XItXPIWITS/TIHEWITSXTIHEIHITCODEWlls~It%WITCODELLUNITS~TltE INSTRUCTIONSFORCOMPLETINGSECTIONIIITEMSTtIsformrequiresInformationontheprocessstreams<<hlchcontributetothisdischarge.ENTERTHEPERMITNLSIBERINTHEBOXATTHETOPOFTHISFORM.THEPERMITNISIBERCANBEFOUNOONTHEFRONTPAGEOFYOUREXPIRINGPERMIT.IfthisIsanewornotpreviouslypermittedfacility,thenleaveblankandanumber<<illbeassigned.EnteroutfallnumaerinspaceprovidedforeachpageofSectionII.ForeachIndividualdlscharoeointaseaaratesetofSectionIIformsmustbefilledout.PROCESSSTREAMSCONTRIBUTINGTOOISCHARGE:FOREACHSEPARATEPROCESSPROVIDETHEFOLLOWINGINFORMATIO'IA.Enterthenameoftheprocess<<hlchcontributestothisdischarge.AlsoprovidetheproperSICcode.B.IndicatetheyearlyaverageprocessscheduleJnhoursperdayanddays-per-year.CProvidetheprocess<<aste<<sterflowrateinformationasrequestedbasedonyourlastI2monthsofoperations.Refertounitcodegivenintheleftmarginfortheappropriateflawunits~0.ProcessProductionRate-Certainpermitlimitationsmaybebasedonproductionrates.Theproductionratesusedtodeterminepermitlimitsshallberepresentedbyareasonablemeasureofactualproductionofthefacility,suchastheproductionduringthehighmonthofthepreviousyear,orthemonthlyaveraqeforthehighestofthepreviousfiveyears.orotherreasonablemeasureasstatedInapplicableU.S.E.P.A.categoricalrulesandregulations.Fornewsourcesornewdlschargers,actualproductionshallbeestimatedusingpro]ectedproduction.RecordyourproductionratesInthetermsandunitsusedintheapplicableU.S.E.P.A.categoricalrulesandregulationsforyourtypeoffacility.34 SEEINSTRUCTIONSONREVERSESIDESECTIONIIPERMIT~IeIT0005827NUMBEREEMGROUNDWATERDISCHARGEINFORMATIONAeISTHEDISCHARGEFROM1HISOUTFALLDIRECIKDTOlHEGRIXNOORGROINDIATKRS?(IFtOPCCttfltAETOITBI5)B.HASAHYDROGEOLOGICALSTUDYORITSEQUIVALENfBEENPKRFORtEDORISTIMBRESIFFICIKNTCURRENfHYKROGEO)reICALINFORHATIONAVAILABLEgREOIRKD@V~HATERREQXE2CESTHISEXISTI%ORPROPOSEDDISCHARGE)IFYESAlTACHACOPYCFTHEREPORTSCeAREYOU~RSTIHjANEXKHPTICNFIKtlSIKPHTflttiAHITROGKOUXIICALREPORTINOKRRULERPX5e22II(Q(PAGE56)ORFlKtlGRONDQTKRtSNITORIttsgEOUIRBKNISINDERRULER.ZSP(5)(PAGEIIZ)OFTIEPART22RULES~IFYESATTACHDOCLNKNTSAN)EXPIANATIONTODBSNSTRATKTHATYOLRDISCNRGEtEXADOUALIFYFORANEXEtlsION.DeAREYOUREQLESTIt6AVARIANCEFRANRtaK323e2205(PAGE99(tDNDKGRADATICN)OFTIEHATERRESIXNCESCCEfllSSIONPART22GRtXSDQTERR1LES2IFYESATTACHSIKHDOCU5BIISASNECESSARYTODQQNSIRATETIENEEDFCRAVARIANCEINTKPNSOFTIEcRllKRIA$PEclFIEDINRIAE5Dei210(PAGE0FTHEPART22RIAKs~~ODC~IYEStOgReReportSubmitted12/6/91LITEM5EXPECTEDWASTEWATERCHARACUNETSCODE1Mg/I2Ug/I3COUNTS/100ml4S.U.5FSLBS/GAYTIEAPPLICANI'AYBERECUIREDTODOAIXIITICIALHASTEANALYSESPAeDISCHARGECHAIIACTKRISTICSCONCBIIRATIONQXNOTAPPLICABLK/BELIEVEDABSBITRtKSENTPDATAPROVIDEDINl7817CIINITSCCOE0ANALYSESCODEBOO5(FIVEDAYBIOCteIICALOXYGENDKHAte)'COD(DeIICALOXYGBIDKHAND)'TOC(TOTALORGANICCARBCN)~5,~0,L00IAttsNIANITROGBI(ASN)TOTALSUSPEMKDSOLIDSTOTALPteSPICRUS(ASI)TOTALRESIlll4LOLORINEDISSOLVEDOXYGENHIN~.LJ~0.~020.~08PLJu>~52FECALCOLIFCRHBACTERIA'nmaaTIEIK(SIPtER)TBFERATINE(HINIER)LLJ~LJLJ~~LJBeOTIBRHASTEHATEROIERACTERISTICSu>LJ5LJEeIISTALLCte)ICALSISSTAtCESlIHIDIAREINNICHIGANSCRITICALHATKRIALSREGISTERTAKEIVcPAGEII)ANWORUS.EPASPRICRllYRXLUfANTLISTTAREV(PAGE7)ORANYOIIERSLBSTAtCESMICHAREOIHAYBKO%IMRIOUSTOTIEKESIGNATKDUSESOFTIEGIXNDN8eTKRCRTO7%PUKICtEALTHTHATAREDISCHARGEDOREXPECTEDTOBEDISCNRGKDTQTIEGRIXNDIATBL7IY1HISFACILllYeESTIHAlKTHKFINALEFFUENTCOMXNIRATIONANDREQRDALLDATAINITBI7OFSECflCNIIIN1HISBOOIUTP~SAWPEJXBF1GRAB224HOURCOMPOSITE0IL8GREASELCHLORIDE<ULFATELT;OETALIL~10,E99e~80,I00I0208~195,010;20~582925,~0~8~0~0~1~521~52~161u'LJ2~2LJLJ~LJLJRECUIREDItAAQTIINRNSt%FACEHATERDISONRGESPAnalyst.sperJ.B.Beauboeuf,TargetPermitEffluentLimitsList. INSTRUCTIONSFORCCMPLETINGSECTIONIIITEMS4ANO5ThisforpprequiresInformationonaspecificoutfalIdischargingtoeItherthegroundratersorthesurface~aters.ENTERTHEPERMITNPIBERINTHEBOXATTHETCPOFTHISFORM.THEPERMITN(D(BERCANBEFOUNDONTHEFRCNTPAGEOFYOUREXPIRINGPERMIT.IfthlSiSanerOrnOtpreVIOuSlypermittedfaCIllty,thenleaVeblankandanumberWillbeaSSlgned.EntertheoutfallnumberInthesDaceprovidedforeachpageofSectionII.ForeachIndividualdlscharoepointasearetesetofSectionIIforms(Iteypps4andS)mu5tbefilledout.ITEM4GROUfd)WATERDISCHARGEINFORMATION(DONOTINCLUDEDEEPWELLINJECT(OffINFORMATIONINTHISITEM)A.-O.TheaDDlicantshalladdresseachofthesepartslfthedischargefrcmthisoutfallIstotheoroundwater.ITEM5EXISTINGOREXPECTED(FORANEWDISCHARGE)WASTEWATEP.CHARACTERISTICSOFGROUNDWATERORSURFACEwATERDISCHARGE(00NOTINCLUDEwLLINJIININHA.Theapplicantshallreportavailabledischargedata(realdataforexistingdischargeorexpecteddataforaproposeddischarge)fortheparametersaslisted.TheseparametersshallbeaddressedforeitherasurfacewaterdischargeotasaDDroDrlateforagroundwaterdischarge.ForassistanceIndeterminingappropriateparametersagroundwaterdlscharoeapplleantmaycontacttheGroundraterQualltyDivision,PermitsSectionortheappropriateGroundraterQualityOlvlslcn'sDistrictoffice.TheapDI)cantshallreportthesampletypecodebestdescribingeachreportedplaceofdata.Seecodingontheleftmarginofthisform.IfthisoutfallIsasurfacewaterdlscharqe,theapplicantmustreportquantitativedataforeachparameterIdentifiedbanhppy,opttpdhodpt~b~,oheoPttbppotdbydedItl\,hbehdPttto4MttthloplltlB.IfdataIsavailableforotherparametersnotlIstedaboveInA.orotherpartsotthisapplicationtheapplicantshouldreportthatdataIntheblankspace5providedInthispart.NOTESlI.Unitcode5torparmppetersreportedInpartsAandBcanbefoundontheletthandsideofthisform.2.GrabsampleshallbeusedtoanalyzeforpH,temperature,totalphenols,residualchlorine,oilandgrease.andfecalcoliformInasurfacewaterdischargeunlessotherfrequency-sampletypeanalysesareavailable.SeeGlossary(page48)fordetlnitlonotgrabsample.3.24-hourcompositesamplesshallbeusedtoanalyzeforTotalBQos,coo,Toc,AnmonlaNitrogen,andTotalSuspendedSolidsInasurfacewaterdischargeunlessotherfrequency-stapletypeanalysesareavailable.SeeGlossary(page48)fordetlnltlonof'compositeseppple.4.REPORTINGOFINTAKEDATA.Youarenotrequiredtoreportunlessyourlshtodemonstrateyourellglbllltyforaunct"etfluentIlmltatiantOrOneOrmOrePOllutantSPthatIS,aneffluentllmltatlOnadjuatedbySubtraCtlngtheaveragelevelofthepollutant(s)presentInyourIntake~ater.NPDESregulationsallownetlimitationsonlyIncertainclrcumstance5.Todemonstrateyoureligibility,reporttheaverageoftheresultsofanalysesonyourIntakewater(Ifyourrateristreatedbeforeuse,testthewaterafterItIstreated),andattacha5eparateSheetcontainingthefollowingforeachpollutant:la)AstatementthattheIntake~aterIsdrawnfromthebodyofraterIntowhichthedischargeIsmade.(Otherwise,youarenoteligibletornetlimitations.)(b)AstatementottheextenttowhichthelevelofthepollutantIsreducedbytreatmentofyourwastewater.(Yourlimitationswillbeadjustedonlytotheextentthatthepollutantisnotremoved.)(c)WhenapDIlcable(forexsnple,whenthepollutantreDresentsaclassofccmppounds),ademonstrationottheextenttowhichthepollutantsIntheIntakeveryphysically,chemically,orbiologicallyfromthepollutantscontainedInyourdIscharge.(YourlimitationswillbeadjustedonlytotheextentthattheIntakepollutantsdonotvaryfromthedischargedpollutants.)5.IfyouhavetroormoresubstantiallyIndentlcalouttalls,youmayrequestpermissionfranyourpermittingauthoritvtosampleandanalyzeonlyoneoutfallandsubmittheresultsoftheanalysisforothersubstantiallyIdentloalOutfallS.IfyOurrequeStISgrantedbythepermittingauthOrlty,OnaSeparateSheetattaChedtOetheapplicationformIdentifywhichoutfallyoudidtest,anddescribewhytheoutfallsrhlchyoudidnottestareSubStantlallyIdentlCaltOtheOutfallrhlChyOudidteSt.36 SEEINSTRUCTIONSONREVERSESIDESECTIONIIPERMIT~IYIXQOQ5827NUMBERODDEM6PRIORITYPOLLUTANTSANDADDITIONALINFORMATIONFORSURFACEWATERDISCHARGEONLYTHEFQLIQtl%REQUESTED1%'ORHATION~rADQIESSED~MIFACEHATERDISCHARGERS~IDIEtNEWUSEDISOQRGERSQ5U.PROVIDEEXPECTEDVALIFORTHEQUANTITATIVEAMDQUALITATIVEINFORMATIONRECITEDBEIQteAIISTHISFACILllYAPRIWVIYINDUSTRY?(REFERTOTABLEIAPAf<g3(IF%,GOTOK)(IFYSGOTOB)BIINDICATETYPEOFPRIMARYINDUSlRYASLISTEDINTABLEIAPAGEgl.(CONTINUEWITHC.)CIDOESTHISOUTFA!LDISCHARGECONTAINANYPROCESS'HASTEHATKR?(IFNQ,GOTOE)(IFYESiGOTO0)DIINDICATElHICHGC/HSFRACTIONSHUSTSETESTEDFORI(REFERTOTABLEIAPAfKIII)IDIKIFORFAOIGC/HSFRACTIONCHECKEDsEACHSPECIFICORGANICTOXICPOILUTAttfHITHINEACHFRACTIONIBISIBEANALYZEDFOR(SEETABLEIIAPAGE02,INADDITION,AILPRll@RYINCUSTRYAPPLICANTSWITHAPROCESSWASTEHAlKRDISOIARGEQffPROVIDEQUUITITATIVEDATAFOREACHTOXICPOLUITAMTINTABLEIIIAPNK99IRECORDALLDATAOMFOILSPROVIDED(ITKH7)INTHISSOQKLETI(CXITItttEHITHE-KBEilH)E~IF~QIIFACEHATERDISCHARGEAPPLICANT(PRIMARYORSECCNDUIYINDUSTRY)sREGARDLESSOFTHETYPEOFDISCHARGEKttltsCRNSREASONTOBELIEVETHATANYPIXLUTAMTLISTEDINTAREIIAANDIVAPAGES~ISDISCHARGEDFRCHANYCIIFAL41tEQUUITITATIVKDATA~SEPROVIDED+RECXIDALLDATAONFNttSPROVIDED(ITKH7)INlHISBOOKLETeSTMLECWRXYESNOQ~nuAnalysisperQJ.B.BeauboeufTargetPermitQ~mEffluentLimitsQPESTICIDE%TAPPLICABLE/BELIEVEDABSENTN/AFaIFANYQRFACEMATERDISCHARGEAPPLICAMf(PRINRYORSECCNDUIYIMXISTRY)aREGARRESSOFTYPEOFDISOIARGGK%wsORHASREASQITOBELIEVEANYPOLUITAMISLISTEDINTABLEVAPACk+AREDISCHARfkDFRCttANYOUTFAlLTIEAPPLICANT~HDESCRIBERFASONSFORTIEPCLUTAMTBE1%PRESENTA%PROVIDEAMYAVAILABLEQUAMflTATIVEDATA'ECORDALLDATAOMF<ASPROVIDED(ITKH7)IMTHISSOQIGEfoG>>AILQRFACEHATERDlSCNRGEAPPLICANfS(PRIMARYA%SECCNDARYIIGXISTRIEs)ORACTIIIESLttifTRIQSIXIOPIE%XYACETICACID(2s4i5T)tTRloaoeeaaePROPANOICAclo(SILYKx,Kti,5,TP)4,WgI~aagaOXY)KIHYL2,2-DIOSJXIOPROPICNAIK~('0,IrVTRIOLOIOPtENL(TCMPiORHEXAOLOROPIENEtHCPRI(AUDATAFCRTIEABOVEtKISTBEGENERATEDUSI%STA%ARDANALYfICALCALISRATICNPROCEDQIKS)ORKRISORHASREASON10BELIEVETHATTCCDISORHAYBEPRESENTINTIEIRDISCHARGEo~REPORTtXIALITATIVKDATAeGKIERATKDl43ICHUSEDASCREENINGPROC6XIIEKITCALIBRATEDHITHANALYTICALSTAIKARDSiFOR6A/8i-TKIIIAOEOIROISEKKPPDIOXIN(TCCD)>>REIXIIAILDATAOMFOESPROVIDED(ITKHk)INTHISNOKLETIJIIFTIEQRFACEHATERDISOIARGEAPPLICANTKM'RHASREASON10BELIEVE1HATBIOUXilCAITOXICITYTESTSHEREHADEIN1HELASTTIRKEU)YEARSONAMYOFTIEAPPLICANTSDISCHARGESCRONARECEIV1%HATERINRELATION10ADISCHARGEPROVIDElHISIWÃHATIONASAttATTAOtENTTOTHISAPPLICATIONeKIIFACOMIRACTLABORATORYORCONQLTI%FIRNPERFOR%DANYOFTIEAIKAYSESREQUIREDBY1HISAPPLICATIONPROVIDETIENt%ANDAIXRESSOFEACHIABORATCRYORFIRIA%THEAIQLYSESPKRFQttEDASAMATTACHMENTCFTHISAPPLICATICNILIDQYOUDISCHARGEAth'THERTOXICORINtIRIOUSDKHICALQSSTAMCESMTLISTKDINTARESIVPAGEDAlOIIAllttCAlVAPtV4S~~IIFYESsTANIDENTIEYTlEOellCALSUBSTANCESAMDESTIWLTKTIEFINALEFFUEHTCCNCENIIIATIOISISIKFIITTHISItAAIATICNASANATTAOtENTTO1HISAPPLICATION>>%TAPPLICABLE/SELIEYEDABSENTN/APRESENf/DATAISAlTACHEDQNTAPPLICABLE/BELlEVKDABSENTN/AQPRESENf/DATAIsATTAOEDg%TAPPLICABLEAPPLICABLE/SKKATTAQEDQ%TAPFLICASIZgAPPLICABIZ/SEKATTAOIEDQX%TAPPLICABLEAPPLICASLEJSKKATTAQIKD37 INSTRUCTIONSFORCCMPLETINGSECTIONIIITEM6ThisformrequiresInformationonaspecificouttalldischargingtothesurfacewaters.ENTERTHEPEIBIITNUMBERINTHEBOXATTHETCPOFTHISFORM.THEPERMITNIPIBERCANBEFDNIDONTHEFRONTPAGEOFYOUREXPIRINGPERMIT.IfthisIsanewornotpreviouslypermIttedfacility,thenleaveblankandanumberwillbeassigned.EntertheoutfallnumberInthespaceprovidedforeachpageofSectionII.ForeachIndividualdlscharqepointaseparatesetofSectionII,Item6formsmustbeflIledout.PRIORITYPOLLUTANTSANDADDITIONALINFORMATIONITEM6NOTE:IfyouhavetwoormoresubstantiallyIndent)eeloutfalls,youmayrequestpermissionfromyourpermittingauthoritytosampleandanalyzeonlyoneoutfallandsubmittheresultsoftheanalysisforothersubstantiallyIdenticaloutfalls.IfyourrequestIsgrantedbythepermittingauthority,onaseparatesheetattachedtotheapplicationformIdentifywhichoutfallyoudidtest,anddescribewhytheoutfallswhichyoudidnottestaresubstantiallyIdenticaltotheoutfallwhichyoudidtest.NOTE:40CFRPartI22.2l(g)(8),Friday,AprilI,1983,providesforaSmallBusinessExemptionfromthereportingofquantitativedatafororganictoxicpollutantsandtoxicpollutantsasrequiredbyPartI22.2)(g)(T)(ll)(A)orI22.2I(g)(7)(ill)(A).A.-C.ThesepartsareselfwxplanatoryanddonotrequirefurtherInstructions.SimplygothrougheachparranddoasIndicated.andE.-J.0.SeveralIndustrialcategorlssandsubcategorieshavebeenexemptedfransubmittingdataoncertainGC/MSFractions(40CFRPartl22,Vol.48,No.64,Friday,AprilI,l983,NotesI,2,and3).ReviewthefollowinglisttodeterminewhetheryourteellityqualifiestobeexemptfromreportingGC/MS(GasChrcmatoglaphy/MassSpectroscopy)Fractions.TextlleMlIIsIndustGC/MSFractIonTestingandReportIngExemptions-AlItourGC/MSorganictractlonsIntheGreigeMlIIsSubcategory.-PesticidefractionInallothersubpartsofthisIndustry'.OreMlnlnandOresslIndust-Volatile,base/neutral,andpesticidefractionsIntheBaseandPreciousMetalsSubcategory.-AlIfourGC/MSorganicfractionsinelIothersubcategoriesofthisIndustry.GusandWoodChemicalsIndustr-PesticidefractionintheTallOilRosinSubcategoryandtheRosinBasedDerivativesSubcategory.Pesticideandbase/neutralfractionsin~IIothersubcategoriesofthisIndustry.PulandPaperIndustr-PesticidefractIonInPapergradeSulfitesubcateqorles(subpartsJand0).-Base/neutralandpesticidefractionsInDelnkSubpart0,DissolvingKrattSubpartF,andPaperboardfromWastePaperSubpartE.-Volatile,base/neutral,pesticidefractionsIntheBCTBleachedKraftSubpartH,Semi-chemicalSubparts8andC,andHonlntegrated-FinsPapersSubpartR.-Acid,base/neutral,andpesticidefractionsinFineBleachedKraftSubpartI,DissolvingSulfitePulpSubpartK,Ground-woodFinePapersSubpart0,MarketBleachedKraftSubpartG,TissuefromWastepaperSubpartT,andNonlntegratedTissuePapersSubpartS.SteamElectricPowerPlantIndustr-Base/neutralfractionIntheOnceThroughCoolingWater,FlyAsh,andBottomAshTransportWaterprocesswastestreams.38 SEEINSTRUCTIONSONREVERSESIDESECTlONIIODDppp5827.EM7CRITICALMATERIALSTOXICPOLLUTJLNTSA,USETHISDATASHEEfTORECORDIHFCRMATIONASRECLJIRKDIN;(OKCXAPPROPRIATEBOXJORttIICHINFCRMATICNTHISDATASHEETREPRESEMTSI)X1SECTIONIIgITEMMIGROLMXCLTKRDISOIARGEINFORMATION(PAGE35)DDX2.SECTIONllITEM6PRIORITYPOUJJTANfsIMSLRFACElATERDlscttVYZ(PAGE37)D~31BoBELOW:CRITICALMATERIALS(TABLEIV)INSLJLFACEHATBOXDISCHARGE(PAGE3J))HAZARDOUSSUBSTANCESINDISCHARGEBoLISTANYCRITICALMATERIAL(TABLEIVPJGE6)NOTADD!ESSEDINSECTIONllITEM6PRIORITYPOLUJfAMTS!4IICHYLXJttOWORHAVEREASONTOBELIEVETOBEPRESENTINTIP.DISCHLRGEsSEEREVERSESIDEOFlHISPAGEFORFLJITIERDIRECTIONssXlerAPPUcASEAPPLICABLE(SEEBKLCtt)CCIII'AINLMEOFCRITICALMATERIALCRPRIORllYPOLUJTAMTBoAVERAGECCNCBIIRATIONJSANTElYPEJItOFANALYSESCaHAXIISJICONCBIIRATICNA!OMASScHdrazine0WITCODELJLJOFANAlYSESWITCXENITCODEILIII'UNITSCODE1MQ/IUQ/ILBS/DAYKG/DAY~AMP~LT1GRAB224HR.COMP.CCIII'sQt%OFCRITICALHATERIALORPRIORllYPOLLIJTAMTBIAVKRJGECCICEMTRATICNJSANDIETfPEJttOFANALYSESCIMAXIJLHCCNCENIRATIONAJOMASSA>>NA%OFCRITICALMATBUALCRFRICRllYRXLUTAMfB.AYBLAGEcctcKMIRATICNJsenzTYPE;1IDFANALYSESCsMAXIMP!CctCENllLATIONAt41MASSAINA%OFCRITICALMATERIALORPRIORllYPOLUJTANTBIAVERAGECOtCBIIRATICNJQIANAlYPEJ0OFANALYSESCIHAXItMLCOtCIDI!RATICNAJOMASSAeQP%OFCRITIQLHATERIALCRPRICRllYFOLUJTANTBoAVERAGECNCBIIRATILXIJQPRETYPEJJIOFANCLYSESCIMAX&PICCNCENIIIATICNAtOMASSAISV%OFCRITICALtVLTERIALORPRICRITYPOLUJTANTBIAVKRAGECCNCENIRATIONJQIANATYPES0CFAMJLYSESC.HJNIJSJLCaLKMIILATICNAJOMASSANt%OFCRITICALMATERIALORPRIORllYPOUJJTANTB.AVERAGECONCBCIRATICNJSAMPLETYPE,'JOFANALYSESC>>t%XIMPLCCCL'BIIRATIONAtOHASSAINAMEOFCRITICALMATERIALORPRIORITYFOUlJTANTBoAVERAGECOMCKM!ILATIONJSANTETYPEJJJOFANALYSESCJXEWITCODELJNITOXE54%LETYPEFOFANALYSESNITCQJESAINTlYPEOFANALYSESLJNITCCOEWITCCOELJ~~~LJLNITCCCE~lYPEJJOFANALYSESNITCODENITCODELJ~~~LJLJIITCCOEQJPLETYPEOFANALYSESLJWITCODEWITCOCKLJ~~~LJLJIITCXXEQWlKTYPEOFANALYSESLLLJLJWITCODELJIITCODELJ~~~LJNITCJXE~TYPEOFANALYSES"Chlorine(SodiumHochl!WLTCCXJESAIFLETYPEOFANALYSESLJNITCOXWITCOKECsMAXI'ctCBIIRATIONAIOMASSWITCODENITCODELJ~~~LJHydrazineorSodiumHypochloritearenotexpectedtobepresentindischargebutACDITICNALPJGESOFTHISITEM7AREATTmmFORTIBRESTOFnaCRITICALClYESMATERIALSAJO/CRPRICRTIYPOUltrAMTSRECUIRKDTDBEREPORTED.ENOsmallquantitiesmaybefoundintheTurbineRoomSumpbutwouldnotbeexpectedtobefoundintheactualdischargeflowtotheabsorptionpond.39 INSTRUCTIONSFOR(XMPLETIIQSECTIONIIITEM7ThisformIstobeusedbybothsurfaceandgroundwaterapplicantstorecordInformationonnnyHlchlgancriticalmnterlnl,E.P.A.prioritypollutant,orhazardoussubstanceinwhichthisapplicationrequiresdatatobeprovided.ThiswouldIncludeonychemicalsubstancetromtheMichiganCriticalMaterialsRegister(TobleIV),theE.P.A.PriorityPollutantListing(TableV),orTablesIIA-YAwhichIlatsOrganicToxicPollutants,OtherToxicPollutants,ConventlonnlandNonconventionalPollutantsnndHazardousSubstances.ITEH7CRITICALMATERIALS,PRIORITYPOLLUTANTSAND/ORHAZARDOUSSUDSTANCESINTHEDISCHARGEMaterialI23~..8A.Listthenomeofthechemlcolsubstance(criticalmaterial,prioritypollutant,orhazardoussubstance)frrmrTablesIyyVondIIA-YAasrequiredInthebox<<hlchyoucheckedInA.l3.above.Entereachchemicalsubstancers,parameternumberaslistedInTablesIV,VandIIA-VAlfprovided.8.ProvidetheaverageconcentrationofthechemicalsubstancenamedinA.IndicatethesampletypeusednndthenumberofanalysesmodetoprovidetheconcentrationdataforthechemicalsubstancenamedInA.C.ProvidethemaximumconcentrationnnddeterminethemassloadingofthechemicalsubstancenrrrredInA.NOTESrI.Itonlyoneanalysiswasmodeforachemicalsubstancethenrecordthntdataasnmaximus,value.Itmorethanoneanalysishosbeenmodetorachemicalsubstancethenprovideanaveragevalueofthoseanalysesnndthemaxim'alue.2.ThisSectionII,Item7,DataSheetprovidesspaceforrecordingdntnfor8chemicalsubstances(Materials)~Additionalspaceforrecordingofdatatormorethon8MaterialscanbemadebymakingcopiesofthisItem7DataSheetasneeded.ItIsolsoImportanttouseaseparatesetotOntoSheetsforeachapplicablereportingrequirementaslistedInA.l-3.andforeachouttall.Refertotheleftmarginforthecodenumberrepresentingthesampletypeusedandtheappropriateunitcodes.40 LockheedAnalyticalServicesINDIANAMICHICANPOWERCOIWPANYSAMPLEANALYSISSUIVIIVIARYPACKAGEFORVOLATILEANDSEMI-VOLATILEORGANICS,PESTICIDE/PCBS,CHLORIDE,NITRATE/NITRITE,SULFATE,FLUORIDE,CYANIDE,IVIETALS,ANDMERCURYLOG-INNUMBER:QUOTATIONNUMBER:L1009Q331620DOCUMENTFILENUMBER:1229485
bloc/rheedEnvironmenta/Systems6Techcgeyfe~CoLockheedAnalyticalServices975KellyJohnsonDriveLasVegas,Nevada89119Q705Phone:(800)361-0220Fax:(702)361-6434February4,1994Mr.RockyBeemCookNuclearPlant1CookPlaceBridgeman,Ml49106RE:Log-inNo.:QuotationNo.:DocumentFileNo.:L1009Q3316201229485TheattacheddatapackagecontainstheresultsofanalysesonsamplesthatweresubmittedtoLockheedAnalyticalServicesonDecember29,1993.Thesampleswerereceivedat5'C.SUMMARYANALYSISSTATEMENT:InorganicsAllgroundwatersampleswerereceivedingoodconditiononDecember29,1993.Allsampleswereanalyzedwithinthemethod-specificholdingtimes.Themethodblankswerefreeofcontamination.AllInternalQualityControlwerewithinacceptancelimitswiththefollowingexception:Thematrixspikerecoveriesforbariumandseleniumwereslightlyoutsideofacceptancelimits.TheacceptablerecoveryoftheLaboratoryControlSamplessupportsthattheanalyticalsystemswereoperatingwithincontrollimits.Thereportingdetectionlimitfornitritewasraisedto0.50mg/LforsampleS.SewagePlantEff.(L1009-4)duetointerferencesfromchloride.OrganicsMethod8260Allcalibrationsandqualitycontrolcriteriaweremetwiththefollowingexceptions:AllsampleswereanalyzedinitiallywithinholdingtimesbutfailedsurrogaterecoveryQClimits.ThesampleswerereanalyzedonedaybeyondthemethodspecifiedholdingtimeandallsamplesmetsurrogaterecoveryQClimits.Tentativelyidentifiedcompoundsearcheswereperformedonallsubmittedsamples.Onlythereanalysesarereported. 0 COOKNUCLEARFebruary4,1994PAGE2Method8010/8020Allcalibrationsandqualitycontrolcriteriaweremetwiththefollowingexceptions:Thematrixspikeandmatrixspikeduplicateprecisionfor1,1-dichloroetheneexceededtheQCcriteriaalthoughallpercentrecoverycriteriaweremet.Dataqualityisnoteffected.Method8270Allsampleswereextractedandanalyzedwithinthemethodspecifiedholdingtime.Allinitialandcontinuingcalibrationcriteriaweremet.Bis(2-ethylhexyl)phthalatewasdetectedinthemethodblankat1.3ug/L.Therewasnoothercontaminationdetectedinthemethodblank.PercentrecoveriesforallsurrogatecompoundswaswithinQClimitsforallsamplesanalyzed.Alaboratorycontrolsample(LCS)andlaboratorycontrolsampleduplicate(LCSDUP)waspreparedandanalyzedwiththissetofsamples.ThepercentrecoverycriteriaforallspikedcompoundswaswithintheQClimitsaswastherelativepercentdifferencebetweenthetwo.Theresponseforbis(2-ethylhexyl)phthalateinsampleTRANS.CATCHBASINexceededthecalibrationrangeintheinitialanalysis.Thesamplewasreanalyzedatadilutionof1:4andallcompoundsfellwithinthecalibrationrange.Bothsetsofresultsarereported.Method8080Allsampleswereextractedandanalyzedwithinthemethodspecifiedholdingtime.Allinitialandcontinuingcalibrationcriteriaweremet.Nocontaminationwasfoundinthemethodblank.FewofthesurrogatespikerecoverieswerewithintheQClimitsduetoanapparentspikingsolutionproblem.Dataqualityisnoteffectedsinceallpercentrecoverycriteriaweremetforthelaboratorycontrolsampleandlaboratorycontrolsampleduplicate.Notargetcompoundsweredetectedabovethereportingdetectionlimitandtherewasnodilutionorreanalysisperformed.IfyouhaveanyquestionsconcerningtheanalysisorthedatapleasedonothesitatetocontactJamesL.Jordan,(702)361-3955,ext.289.ReleaseofthisdatareporthasbeenauthorizedbytheLaboratoryDirectorortheDirector'sdesigneeasevidencedbythefollowingsignature.JamesL.JodanClientServicesRepresentativeJLJ/atcc:ClientServicesDocumentControlDepartment El bloc/r/reedLockheedAnalyticalServices975KellyJohnsonOriveLasVegas.Nevada891194705Phone:(800)582-7605Fax:(702)3618146February17,1994Mr.RockyBeemCookNuclearPlant1CookPlaceBridgman,Ml49106
DearRocky,
Peryourrequestduringourphoneconversationthismorning,thefollowingisanexplanationoftheprocedureusedforthedeterminationofthenon-standardorganiccompoundsinyourgroundwatersamples.Thesampleswereanalyzedusinginstrumentsthatweresetupforstandardmethods8260and8270,Afewofthecompoundsonyourlistsofanalytesarenotstandardmethod8260or8270compounds.Oncethesamplesareanalyzedandachromatogramwasobtainedforthesamples,allpeaksthatwerepresentinthesamplesthatdidnotcorrespondtooneofthecalibratedcompoundswereinvestigatedfurther.ThisinvolvedtakingthemassspectraobtainedfromthesepeaksandcomparingthespectratoanNISTlibraryofspectra.Thislibrarycontainsapproximately52,000knownmassspectra.Themassspectraoftheadditionalanalytesofinteresttoyouarecontainedwithinthislibrary.Noneofthenon-standardanalytesweredetectedinanyofyoursamples.Forthenextquartersroundofsampling,weareendeavoringtoobtainthestandardsforthesecompoundssothattheywillbecalibratedforintheanalysesofthosesamples.IfyouhaveanyfurtherquestionsorifIcanbeofanyfurtherassistance,pleasedonothesitatetocallmeat(702)361-1626ex.289.'ncerely,JamesL.rdanProjectManagercc:M.Butler
LockheedAnalyticalServicesDATAQUALIFIERSFORINORGANICANALYSES/Revised08/28/92)ForUseontheAnalyticalDataReportingFormsDENX,Y,orZForCLPAnalysesOnly-Reportedvalueislessthanthecontractrequireddetectionlimit(CRDL)butgreaterthanorequaltotheinstrumentdetectionlimit(IDL).ForRoutine,Non-CLPAnalysesOnly-Anyconstituentthatwasalsodetectedintheassociatedblankwhoseconcentrationwasgreaterthanthereportingdetectionlimit(RDL).PresenceofhighlevelsofinterferingconstituentsrequireddilutionofsamplewhichincreasedtheRDLbythedilutionfactor.Estimatedvalueduetopresenceofinterference.Sampleanalysisperformedoutsideofmethod-orclient-specifiedmaximumholdingtimerequirement.ForCLPAnalysesOnly-Duplicateinjectionprecisioncriterionwasnotmet.Matrixspikerecoveryexceededacceptancelimits.Reportedvaluewasdeterminedfromthemethodofstandardaddition.ForCLPReportingOnly-Constituentwasanalyzedforbutnotdetected(samplequantitationmustbecorrectedfordilutionandpercentmoisture).ForAASOnly-Post-digestionspikeforFurnaceAASdidnotmeetacceptancecriteriaandsampleabsorbanceislessthan50%ofspikeabsorbance.Analyst-detinedqualifier.Relativepercentdifference(RPD)forduplicateanalysisexceededacceptancelimits.Correlationcoefficient(r)fortheMSAislessthan0.995.ForUseontheQCDataReportingFormsThespikerecoveryand/orRPDformatrixspikeandmatrixspikeduplicatescannotbeevaluatedduetoinsufficientspikinglevelcomparedtotheelevatedsampleanalyteconcentration.TheRPDcannotbecomputedbecausethesampleand/orduplicateconcentrationwasbelowtheRDL.'sedasfootnotedesignationsontheQCsummaryform. LockheedAnalyticalServicesDATAQUALIFIERSFORORGANICANALYSES(Revised04/20/93JForUseontheAnalyticalDataReportingFormsDHX,Y,orZForCLPanalysesOnly-TheTICisasuspectedaldol-condensationproduct.Anyconstituentthatwasalsodetectedintheassociatedblankwhoseconcentrationwasgreaterthanthepracticalorreportingdetectionlimit(PQLorRDL).ConstituentcontirmedbyGC/MSanalysis.(pesticide/PCBanalysesonly/Constituentdetectedinthedilutedsample.Italsoindicatesthatanaccuratequantitationisnotpossibledueto~surri~ate.beingdilutedoutofthesamplesduringthecourseoftheanalysis.Constituentconcentrationexceededthecalibrationrange.Thequantitationisnotgasolineordieselbutbelievedtobesomeothercombinationofhydrocarbons.Sampleanalysisperformedoutsideofmethod-orclient-specifiedmaximumholdingtimerequirement.Estimatedvalue-(I)constituentdetectedatalevellessthantheRDLorPQLandgreaterthanorequaltotheMDL;(2)estimatedconcentrationforTICs(ForCLPReportingOnly).ForCLPReportingOnly-Tentativelyidentifiedconstituents(TICs)identifiedbasedonmassspectrallibrarysearch.ForCLPReportingOnly-ThepercentdifferencebetweentheconcentrationsdetectedonbothGCcolumnswasgreaterthan25percent(pesticide/PCBanalysesonly).ForCLPReportingOnly-Constituentwasanalyzedforbutnotdetected(samplequantitationmustbecorrectedfordilutionandpercentmoisture).Analyst-detinedqualitier.ForUseon-theQCDataReportingFormsnIhlQCdata(i.e..percentrecoverydataformatrixspike,matrixspikeduplicate,laboratory<<iintrolstandard.orsurrogates:andRPDformatrixspikeduplicateorunspikedduplicate)exceededacceptancelimits.Thespikerecoveryand/orRPDformatrixspikeandmatrixspikeduplicatescannotbeevaluatedduetoinsufficientspikinglevelcomparedtothe,elevatedsampleanalyteconcentration.TheRPDcannothecomputedbecausethesampleand/orduplicateconcentrationwasbelowtheRDL.Useastootnotetesignationsonthesummarytorm. VOLATILEORGANICANALYSISRESULTSGC/HALLANALYSESUSINGEPAMETHOD8010linamIID:TRDIId:2-DEDateAnalzed:04-JAN-94Matrix:WATERAnalticalBatch¹:122093-801020-0-3LALmIID:L1DRive:2-DE-DilutionFactor:1QCBatchID:122093-801020-0-3BCMBFBrraRevero11492Limi65-12560-120ConstituentDihlrdiflrmhnehlrmhnVinIchlorideBromomethanehlrhnTrihlrflrmhan11-DichloroetheneMethlenechloridern-12-Dihlrhn11-DihlrhnChloroform111-Trichloroethanearnrhlrie12-DihlrhnTrichloroetheneTCE12-DichlororoaneBrmoihlrmhan2-hlrhlvinlhrcis-13-Dichlororoenetrans-13-Dichlororoene112-TrihlrhnTrhlrhnPEDibromochloromehaneChlorobenzeneBrmofrm1122Trhlrhn13-Dichlorobenzene14-Dichlorobenzene12-DichlorobenzeneConcentration(/Jg/L)<0.50<3<6<4<0.5<0.5<2ReportingDetectionLimit/L0.50.50.5DataQualifier(slLOCKHEEDANALYTICALSERVICESAV~
VOLATILEORGANICANALYSISRESULTSGC/PIDANALYSESUSINGMETHOD8020linmIID:TRALmlID:L1DII-DEDRiv:29DEDateAnalzed:04-JAN-94Matrix:WATERAnalticalBatch¹:122093-801020-0-3DilutionFactor:1QCBatchID:122093-801020-0-3TFTBFBrraRver9495Limi70-12075-120BenzeneTolnConstituentConcentration/L0.52ReportingDetectionLimit/L0.5DataQualifiershlrnznEthIBenzenem-Xlene-Xlen1-Dihlrnzn14-Dichlorobenzene12-Dichlorobenzene<2<2<2LOCKHEEDANALYTICALSERVICESu4 VOLATILEORGANICANALYSISRESULTSGC/HALLANALYSESUSINGEPAMETHOD8010linmlID:TR-ADII:2-DEDateAnalzed:04-JAN-94Matrix:WATERAnalticalBatch¹:122093-801020-0-3ALmIID:LlDRiv:2-DDilutionFactor:1QCBatchID:122093-801020-0-3BCMBFBurroaRvr12086QCLimi65-12560-120ConstituentDihlriflrmhnehlrmhnVinIchlorideBromomethanehlrhnTrihlrfl'rmhn11-DichloroetheneMethIenechloridern-12-Dihlrhn11-DihlrhnChloroform111-Trichloroethanernrhlrid12-DihlrhnTrichloroetheneTCE12-DichlororoaneBrmihlrmhn2-hlrhlvinlhrcis-13-Dichlororoenetrans-13-Dichlororoene112-TrihlrhanTerahlrhnPEDibromochloromethaneChlorobenzeneBrmfrm1122-Trhlrhn13-Dichlorobenzene14-Dichlorobenzene12-DichlorobenzeneConcentration(yg/L)<0.50<3<6<4<0.5<0.5<2ReportingDetectionLimit/L0.50.50.5DataQualifier(s)LOCKHEEDANALYTICALSERVICESnr.1JV
VOLATILEORGANICANALYSISRESULTSGC/PIDANALYSESUSINGMETHOD8020linmlID:TR-ADII:2-DDateAnalzed:04-JAN-94Matrix:WATERAnalticalBatch4:122093-801020-0-3LALamIID;L1DaRiv:2-DE-9DilutionFactor:1QCBatchID:122093-801020-0-3TFTBFBrraRevr9797QLimi70-12075-120BenzeneTInConstituentConcentrationIL0.53ReportingDetectionLimitIL0.5DataQualifiershlrnznEthIBenzenem-Xlene-XIn1-Dihlrbnzn14-Dichlorobenzene12-Dichlorobenzene<2<2<2LOCKHEEOANALYTICALSERVICEShg linmIID:TRSVOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260LALmIID:L1-41Page1of2DateCollected:28-DEC-93Matrix:WATERAnIiIBh¹:114-2-F2QCBatchID:011094-8260-F2DateReceived:29-DEC-93DateAnalzed:11-JAN-94DilinFr:1SURROGATERECOVERY12-Dihlrhn-d4TIn-4-Bromofluorobenzene488QCLimits7-11486-115ConstituentChloromethaneVinIhlriBrmmhnChloroethaneTrichlorofluoromethaneAn11-DihlrhnCarbonDisulfideMethleneChlorideran-12-DichlrohnVinIAcae11-Dichloroethane2-Butanoneis-12-Dihlrhnhlrfrm111-TrichloroethaneCarbonTerachloride12-DihlrhnBnznTrichloroetheneTCE12-DichlororoaneBromihlrmhn2-hlrhIVinIhr4-MethI-2-entanonecis-13-DichlororoeneTolnrn-1-Dihlrrn2-Hexanone112-TrichloroethaneTetrachloroethenePCEConcentrationIL<5<5<5<5<5<10<5<10<5<5<5<5<2<10<5<10<5<5ReportingDetectionLimitIL101010DataQualifiersLOCKHEEDANALYjICALSERVICESlu
ClientSamleID:TRSVOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260LALSamleID:L1009-41Page2of2ConstituentDibromochloromethaneChlrnznEhlnnm-Xleneo-XlenernBrmofrm1122-Tetrachloroethane13-Dichlorobenzene14-Dihlrnzn12-DichlorobenzeneConcentrationIL<5<5<5<5<5<5ReportingDetectionLimitILDataQualifiersLOCKHEEDANALYTICALSERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260TENTATIVELYIDENTIFIEDCOMPOUNDSClientSampleID:TRSDateReceived:29-DEC-93Matrix:WATERAnalyticalBatch:011094-8260-F2LALSampleID:L1009-41DateAnalyzed:11-JAN-94DilutiorlFactor:1QCBatchID:011094-8260-F2NONETentativelyIdentifiedCompoundEstimatedConcentration(yg/L)(10RetentionTime(minutes)0.00DataQualifier(slLOCKHEEDANALYTICALSERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260Page1of2linmlID:TR-ADateCollected:28-DEC-93Matrix:WATERAnIiIBh¹:114--FQCBatchID:011094-8260-F2LALmleID:L1-43DateReceived:29-DEC-93DateAnalzed:11-JAN-94DilinFr:1SURROGATERECOVERY12-Dichloroehan-d4TIn-QCLimits7-1144-Bromofluorobenzene8986-115ConstituentChloromethaneVinIhlriBrmomhanChloroethaneTrichlorofluoromethaneAn11-DihlrhnCarbonDisulfideMethleneChloridern-1-DihlrhnVinIA11-Dichloroethane2-Butanonei-12-Dihlrhnhlorfrm111-TrichloroethaneCarbonTetrachloride12-DihlrhnBnznTrichloroetheneTCE12-DichlororoaneBromihlrmhn2-hlrhIVinIEhr4-Methl-2-entanonecis-13-DichlororoeneTInrn-1-Dihlrrne2-Hexanone112-TrichloroethaneTetrachloroethenePCEConcentrationIL<5<5<5<5<5<5<10<5<5<5<5<2<10<10<5<5ReportingDetectionLimitIL101010DataQualifiersLOCKHEEDANALYTICALSERVICESIB VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGIVIETHOD8260ClientSamleID:TRS-QALALSamleID:L1009-43Page2of2ConstituentDibromochloromethanehlrenznEhlnznm-Xleneo-XlenernBrmfrm1122-Tetrachloroethane13-Dichlorobenzene14-Dihlrenzn12-DichlorobenzeneConcentrationIL<5<5<5<5<5ReportingDetectionLimitILDataQualifiersLOCKHEEDANALYTICALSERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260TENTATIVELYIDENTIFIEDCOMPOUNDSClientSampleID:TRS-QADateReceived:29-DEC-93Matrix:WATERAnalyticalBatch:011094-8260-F2LALSampleID:L1009-43DateAnalyzed:11-JAN-94DilutionFactor:1QCBatchID:011094-8260-F2NONETentativelyIdentifiedCompoundEstimatedConcentrationIpg/L)(10RetentionTime(minutes)0.00DataQualifieris)LOCKHEEDANALYTICALSERVICES SEMIVOLATILEORGANICANALYSISRESULTS,FORGC/MSANALYSESUSINGMETHOD8270P1f2linmIID:TRDateCollected:28-DEC-93Matrix:WATERAnliIBh¹:1114-27-8QCBatchID:8270-SEMIVOLATILES-3964LALmIID:L1-2DateReceived:29-DEC-93DilutionFactor:1DExra:4-AN-4DateAnalzed:11-JAN-942-FluorohenolPhenol-d,Nitrobenzene-d~RRATEREVERY0/412659QCLimits21-10010-9435-1142-FluorobihenI246-TrirmhnIp-Terphenyl-d,4559943-1161-1233-141oniuenPhenolbis2-ChloroethIether2-hlrhnl1-Dihlrnn14-DichlorobenzeneBenzIalcohol12-Dihlrnzn2-'MhIhnIbis2-ChloroisoroIether4-MethIhenolN-Nir-Di-n-rIminHxhlrhnNitrobenzeneIsohorone-NirhnI24-DimehIhnIBenzoicacidbis2-Chloroethoxmethane4-DihlrhnI124-TrihlrnznNahthalene4-ChloroanilineHxhlrin4-hlr--mhlhnl2-MethInahthaleneHexachloroccloentadieneConcentrationL<10<10<10<10<10<10<10<10<50<10<10<10<10<10.ReportingDetectionLimitL1010101010101010501010101010DLOCKHEEDAh/ALYTICALSERVICES4w SEIVIIVOLATILEORGANICANALYSISRESULTSFORGC/IVISANALYSESUSINGMETHOD8270ClientSamleID:TRSLALSamleID:L1009-25P2f2Constituent24-TrihlrhnI4-TrihlrhnI2-Chloronahthalene2-NitroanilineDimhIhhalAnhhln26-Dinitrotoluene3-NitroanilineAnhhn24-Dinirhenol4-NitrohenolDibenzofuran24-DinirInDihIhhI4-ChlorohenI-henletherFluorene4-Nirnilin4-Dinir-2mhIhnIN-Nitrosodihenlamine4-BromohenI-henletherHxhlrnznPnhlrhnlPhenanthreneAnthraceneDi-n-IhhIFlrnhnPreneButIbenzIhthalate'-Dihlrnziin8nzonhrnChrsenebis2-Eth)hexIhthalateDi-n-IhhIBnzflrnhnBenzokfluorantheneBenzoareneInn12-crneDinzhnhrnBenzohierleneCarbazoleConcentrationIL)<10<25<10<25<25<25<10<10<10<2<2<10<10<2<10<101.4<10<10<2<10<101.5<10<10<10<10ReportingDetectionLimit(IL)10251025252510101010101010101010101010'101010DataQualifier(s)JBLOCKHEEDANALYTICALSERIIICES30 VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8270TENTATIVELYIDENTIFIEDCOMPOUNDSClientSampleID:TRSDateReceived:29-DEC-93Matrix:WATERAnalyticalBatch:011194-8270-8LALSampleID:L1009-25DateAnalyzed:11-JAN-94DilutionFactor:1QCBatchID:8270-SEMIVOLATILES-3964UnknownUnknownTentativelyIdentifiedCompoundEstimatedConcentration(pg/L)10020RetentionTime(minutes)6.4430.26DataQualifier(s)LOCKHEEDAIVALYTICALSERVICES3L SEIVIIVOLATILEORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270P1f2linmlID:TR-ADateCollected:28-DEC-93Matrix:WATERAnIiIBhA':1114-27-BQCBatchID:8270-SEMIVOLATILES-3964LALmleID:L10-27DateReceived:29-DEC-93DilutionFactor:1DaExrc:04-JAN-4DateAnalzed:11-JAN-942-FluorohenolPhenol-d,Nitrobenzene-d,RRATEREVERY0382661Limi21-10010-9435-1142-FluorobihenI246-Tribromohnolp-Terphenyl-d569743-1161-1233-141PhenolninConcentrationL<10ReportingDetectionLimitL10Dbis2-ChloroethIether2-hlrhnI1-Dihlrnzn14-DichlorobenzeneBenzIalcohol12-Dihlrnzn2-MhIhnIbis2-ChloroisoroIether4-MethIhenolN-Nir-Di-n-rIminHxhlrhnNitrobenzeneIsohorone2-NirhnI24DimhIhnIBenzoicacidbis2-Chloroethoxmehane24-DihlrhnI124-TrihlrnznNahthalene4-ChloroanilineHxhlrin4-hlr--mhlhnl2-MethInahthaleneHexachloroccloentadiene<10<10<10<10<10<10<10<50<10<10<10<10<101010101010101010501010101010LOCKHEEDANALYTICALSERVICES2 SEIVIIVOLATILEORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270ClientSamleID:TRS-OALALSamleID:L1009-27P2f2Constituent24-TrihlrhnI24-TrihlrhnI2-Chloronahthalene2-NitroanilineDimhIhhIAnhhln26-Dinitrotoluene3-NitroanilineAnhhen24-DinirhnI4-NitrohenolDibenzofuran2'4-DinirInDihihhl4-ChlorohenI-henletherFluorene4-Niranilin4-Dinir-2mhIhnIN-Nitrosodihenlamine4-BromohenI-henletherHxhlrnznPnhlnIPhenanthreneAnthraceneDi-n-IhhIFlrnhnPreneButIbenzIhthalate'-DihrnziinBnznhrnChrsenebis2-fthIhexIhthalateDi-n-IhhIBnzflrnhnBenzokfluorantheneConcentrationIIL)<10<10<25<10<25<10<2<25<10<10<10<10<2<10<10<10<10<10<10<2<101.9<10ReportingDetectionLimit(ILI1010251025251010101010101010101010101010DataQualifier(siJ8BenzoareneInen12ren<101010DienzahanhrnBenzohierleneCarbazole<10<101010LOCKHEEOANALYTICALSERVICES 0 VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8270TENTATIVELYIDENTIFIEDCOMPOUNDSClientSampleID:TRS-QADateReceived:29-DEC-93Matrix:WATERAnalyticalBatch:011194-8270-8LALSampleID:L1009-27DateAnalyzed:29-DEC-93DilutionFactor:1QCBatchID:8270-SEIVIIVOLATILES-3964UnknownUnknownTentativelyIdentifiedCompoundEstimatedConcentrationIyg/L)4100RetentionTimeIminutes)5.286.44DataQualifier(s)HydrocarbonUnknownHydrocarbonHydrocarbonHydrocarbon2029.9730.2631.9832.9433.86LOCKHEEOANALYTICALSERIIICES".4 PESTICIDEANALYSESRESULTSBYGC/ECDUSINGMETHOD8080FORCOOKNUCLEARPLANTClienSamteID:TRSDaeColleced:28-DEC-93DateExtracted:04-JAN-94Matrix:WATERAnalticalBatch¹:012094-8080-A-1LALSamIeID:L1009-17DaeReived:29-JAN-94DateAnalzed:21-JAN-94DilutionFactor:1QCGrouID:8080PEST/PCBS3965SURROGATERECOVERYooQCLimitsTCMXDCB655260-15060-150A-BHCB-BHC-BHD-BHCConstituentConcentrationIL<0.05.0<0.05ReportingDetectionLimitIL0.050.0.05DataQualifier(s)HEPTACHLORALDRINHEPTACHLOREPOXIDEG-CHLORDANEENDOSULFANIA-CHLORDANE44'-DDE44'-DDTDIELDRINENDRINENDOSULFANII44'-DDDENDRINALDEHYDEENDOLFANLFATEMETHOXYHLRTOXAPHENEPCB-1016PB-1221PCB-122PCB-1242PCB-1248PCB-124PCB-120TECHNICALCHLORDANEMIREXTCMX-tetra-chloro-meta-xyleneDCB-Deca-chloro-biphenyl<0.05<0.0<0.05<0.05<.05<0.1<0.1<0.1<0.1<0.1<5<2<0.10.050.050.050.050.10.10.10.10.1<0.1LOCKHEEDANALYTICALSERVICES5f PESTICIDEANALYSESRESULTSBYGC/ECDUSINGMETHOD8080FORCOOKNUCLEARPLANTClienSmleID:TR-QADaeColleced:28-DEC-93DateExtracted:04-JAN-94Matrix:WATERAnalticalBatch¹:012094-8080-A-1LALSmIID:L1009-19DateReceived:29-JAN-94DateAnalzed:21-JAN-94DilutionFactor:1QCGrouID:8080PEST/PCBS3965SURROGATERECOVERYTCMXQCLimits60-150DCB4660-150A-BHCB-BHC-BHD-BHCConstituentConcentration/L<0.05<0.05ReportingDetectionLimit/L0.050.05DataQualifier(s)HEPTACHLORALDRINHEPTAHLOREPOXIDEG-CHLORDANEENDOSULFANIA-CHLORDANE44'-DDE44'-DDTDIELDRINENDRINENDOSULFANII44'-DDDENDRINALDEHYDEENDOSULFANSULFATEMETHOXYCHLRTOXAPHENEPCB-1016PCB-1221PCB-1232PCB-1242PCB-1248PB-124PCB-126TECHNICALCHLORDANEMIREXTCMX-tetra-chloro-meta-xyleneDCB-Deca-chloro-biphenyl<0.05<0.05<0.05<0.05<.05<0.1<0.1<0.1<0.1<0.1<5<2<0.10.050.050.050.050.10.10.10.10.10.<0.1LOCKHEEDANALYTICALSERVICES52
IVIETALSRESULTSClie'n'tSam"leID:TRSLALBatchID(s):1220imDateCollected:12-28-93DateReceived:12-29-93Matrix:round'waterP0¹69095-040-3NConstituents:.'Meth'odConcentration.(mIL)..ReportingDetectionLimit(mIL)DataQualifier(s)DataAnalzedLALSamleID.AluminumAntimonArsenicBariumBeIliumBoronCadmiumChromiumCobaltCoerIronLeadManesiumMananeseMercuMolbdenumNickelSeleniumSilverSodiumThalliumTinTitaniumVanadiumZinc6010602060206020602060106020602060206020601060206010602074706020602060206020601060206020601060106020<0.20<0.060<0.010<0.20<0.0050.28<0.005<0.010<0.050<0.025<0.10<0.003180.026<0.0002<0.20<0.0400.0055<0.010900<0.010<0.20<0.10<0.050<0.0200.200.0600.0100.200.0050.200.0050.0100.0500.0250.100.0035.00.0150.00020.200.0400.0050.0105.00.0100.200.100.0500.02001-20-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-20-9401-27-9401-07-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-27-9401-20-9401-20-9401-27-94L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13Comments:LOCKHEEDAIVALVTICALSERVICES 0 METALSRESULTS-ClientSamleID:TRS-OALALBatchID(s):1220imDate:Collected:12-28-93DateReceived:12-29-93Matrix:.roundwaterPOP'69095-040-3N:ConstituentsAluminumAntimonMethod60106020Concentration{r'nIL'l<0.20<0.060ReportingDetectionLimit{mIll0.200.060OatsDateQualtfier{s).Analied01-20-9401-27-94LALSam'leID"L1009-14L1009-14ArsenicBariumBeIliumBoronCadmiumChromiumCobaltCoerIronLeadManesiumMananeseMercuMolbdenumNickelSeleniumSilverSodiumThalliumTinTitaniumVanadiumZinc60206020602060106020602060206020601060206010602074706020602060206020601060206020601060106020<0.010<0.20<0.0050.27<0.005<0.010<0.050<0.025<0.10<0.003170.027<0.0002<0.20<0.0400.0078<0.010890<0.010<0.20<0.10<0.0500.0220.0100.200.0050.200.0050.0100.0500.'0250.100.0035.00.0150.00020.200.0400.0050.0105.00.0100.200.100.0500.020NN01-27-9401-27-9401-27-9401-20-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-20-9401-27-9401-07-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-27-9401-20-9401-20-9401-27-94L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14Comments:LOCKHEEDANALYTICALSERVICES 00 GENERALCHEMISTRYRESULTSClientSamleID:TRSLALBatchID(s):1229imDateCollected:12-28-93Matrix:roundwaterDateReceived:12-29-93PO¹69095-040-3NConstituentMethodResultReportingDetectionLimitDataQualifierls)DateAnalzedLALSamieIDFluoride,inmILChloride,inmIL340.2300.00.29190.150.01601-24-94L1009-112-29-93L1009-1Nitrite.Nitroen,inm/LSulfate,inmIL300.0300.0Nitrate-Nitroen,inmIL300.00.91<0.01220000.0170.0120.59D(1:10)12-29-93L1009-112-29-93L1009-112-29-93L1009-1Ammonia-Nitrogen,inm/LTotalCyanide,inmg/L350.1335.23.4<0.0200.0500.02001-05-94L1009-501-03-94L1009-9Comments:LOCKHEEDANALYTICALSERVICES65 GENERALCHEMISTRYRESULTSClientSamle'ID:TRS-QALALBatchID(s):1229imDateCollected:12-28-93DateReceived:12-29-93Matrix:roundwaterP0469095-040-3NConstituentMethodResultReportingDetectionLimitDataQualifier(s)DateAnalzedLALSamleIDFluoride,inmILChloride.inmILNitrate-Nitroen,inmILNitrite.Nitroen,inmILSulfate,inmILAmmonia-Nitrogen,inmILTotalCyanide,inmg/L340.2300.0300.0300.0300.0350.1335.20.31200.90<0.01222003,4<0.0200.150.0160.0170.0120.590.0500.020D(1:10l01-24-94L1009-212-29-93L1009-212-29-93L1009-212-29-93L1009-212-29-93L1009-201-05-94L1009-601-03-94L1009-10Comments:LOCKHEEDANALYTICALSERVICES
GENERALCHEIVIISTRYQCDATASUIVIIVIARY.LALBatchID(s):1229imQCSamleAnalses.Constituent-Fluoride,inm/LClient'Sample'DTRSL'ALSampleIDL1009-1DateAnalyzed01-24-94ReagentBlank<0.15MatrixDuplicate:'SpikePrecision'eco'very(9oRPD)(%)107Chloride,inm/LNitrate-Nitrogen,inm/LTRSTRSL1009-1L1009-112-29-9312-29-93'<0.0160.2<0.0179193Nitrite-Nitroen,inm/LSulfate,inm/LAmmonia-Nitrogen,inm/LTotalCyanide,inmg/LTRSTRSTRSTRSL1009-1L1009-1L1009-5L1009-912-29-9312-29-9301-05-9401-03-94<0.012<0.059<0.050<0.0200.10969612294"b"-TheRPDcannotbecomputed,becausethesampleortheduplicateconcentrationwasbelowtheDetectionLimit.Comments:LOCKHEEDANALYTICALSERVICES
onNUSa~aaw~~C0RP0RATI0NLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportHo.:00018939SectionAPage1CLIENTNAME:ADDRESS:ATTENTION:INDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAN,Ml49106-0000MS.JENILEWIS-CHEMISTRYDEPT.HUSCLIENTNO:06630020'WORKORDERNO:55830VENDORNO:05411000CarbonCopy:SAMPLEID:HUSSAMPLENO:P.O.NO.:TURBINEROOMSUMP27476P025928469034-040.3NDATESAMPLED:30-DEC-93DATERECEIVED:05-JAN-94APPROVEDBY:Kieda,ChuckTESTLHCODEDETERMINATIONRESULTUNIT1I7302AHA'W3I1304I5905AALWSulfate,Turbidimetric(asS04)Sodiun,Total(Na)Chloride(asCl)Solids,Dissolvedat180CAtunintm,Total(Al)51mg/L6.3mg/L11mg/L140mg/L0.97mg/LCOMMENTS:
/dhHBSUft011NUSI~~~CPRPPRATIPNLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportHo.:00018939SectionAPage2CLIENTNAME:ADDRESS:ATTENTIOH:INDIANAMICHIGANPOWERCOMPANYOHECOOKPLACE.BRIDGMAN,Ml49106-0000MS.JENILEWIS-CHEMISTRYDEPT.NUSCLIENTNO:06630020WORKORDERNO:55830VENDORHO:05411000CarbonCopy:SAMPLEID:HUSSAMPLEHO:P.O.HO.:TURBINEROOMSUMP27476/FILTEREDP025928569034-040-3NDATESAMPLED:30.DEC-93DATERECEIVED:05-JAH-94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMIHATIOHRESULTUNITS1AALFAtuninun,Dissotved(At)COMMEHTS:0.3mg/L
.".HalliburtonNUS+++C0RP0RATI0NLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage3CLIENTNAME:ADDRESS:ATTEHTION:INDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAN,MI49106-0000MS.JENILEWIS-CHEMISTRYDEPT.NUSCLIENTNO:06630020WORKORDERHO:55830VENDORNO:05411000CarbonCopy:SAMPLEID:NUSSAMPLENO:P.O.NO.:TURBINEROOMSUMP27503P025928669034-040-3NDATESAMPLED:31.DEC-93DATERECEIVED:05-JAN-94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMIHATIOHRESULTUNITS1I7302AHAW3I1304I5905AALWCOMMEHTS:Sulfate,Turbidimetric(asS04)Sodiun,Total(Na)Chloride(asCl)Solids,Dissolvedat180CAtuninun,Total(Al)53mg/L6.0mg/L10mg/L130mg/L0.98mg/L
.-:H<b~on~S++++C0RP0RATI0NLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage4CLIENTNAME:ADDRESS:ATTENTION:INDIANAMICHIGAHPOWERCOMPANYONECOOKPLACEBRIDGMAH,MI49106.0000MS.JEHILEWIS-CHEMISTRYDEPT.NUSCLIENTNO:06630020WORKORDERNO:55830VENDORHO:05411000CarbonCopy:SAMPLEID:HUSSAMPLENO:P.O.HO.:TURBINEROOMSUMP27503/FILTEREDP025928769034-040-3HDATESAMPLED:31-DEC.93DATERECEIVED:OS-JAN.94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMINATIONRESULTUNITS,1AALFAtminun,Dissolved(At)0.3mg/LCOMMENTS: i'HalliburtonNUSI+++C0RP0RATI0NLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage5CLIENTNAME:ADDRESS:ATTENTION:INDIANAMICHIGANPOWERCOMPANYOHECOOKPLACEBRIDGMAN,MI49106-0000MS.JENILEWIS-CHEMISTRYDEPT.NUSCLIENTNO:06630020WORKORDERNO:55830VENDORNO:05411000CarbonCopy:SAMPLEID:NUSSAMPLENO:P.O.NO.:TURBINEROOMSUMP27506P025928869034-040-3NDATESAMPLED:01-JAN.94DATERECEIVED:05-JAH94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMIHATIOHRESULTUNITS1I7302AHAW311304I5905AALWSulfate,Turbidimetric(asS04)Sodiua,Total(Ha)Chloride(asCl)Solids',Dissolvedat180CAtuninun,Total(Al)52mg/L5.6mg/L10mg/L130mg/L1.6mg/LCOMMENTS:
h:HalliburtonNUSCORPORATIONLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(4'12)747-2684January18,1994ReportHo.:00018939SectionAPage6'LIENI'AME:ADDRESS:ATTENTION:CarbonCopy:INDIAHAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAN,MI49106-0000MS.JEHILEWIS-CHEMISTRYDEPT.NUSCLIEHTHO:06630020WORKORDERHO:55830VEHDORNO:05411000SAMPLEID:HUSSAMPLENO:P.O.NO.:TRUBIHEROOMSUMP27506/FILTEREDP025928969034-040-3HDATESAMPLED:01-JAH-94DATERECEIVED:05-JAH-94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMINATIONRESULTUNITS1AALFAlumina,Dissolved(At)COMMENTS:0.2mg/L ALHalliburtonNUSI+C0RP0RATI0NLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage7CLIENTNAME:ADDRESS:ATTENTION:INDIANAMICHIGANPOWERCOHPANYONECOOKPLACEBRIDGHAN,Hi49106-0000HS.JENILEWIS-CHEMISTRYDEPT.NUSCLIENTNO:06630020WORKORDERNO:55830VENDORNO:05411000CarbonCopy:SAMPLEID:NUSSAHPLENO:P.O.NO.:TURBINEROOHSUHP27509P025929069034-040-3NDATESAMPLED:02-JAN-94DATERECEIVED:05-JAN-94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERHINATIONRESULTUNITS117302ANAW311304I5905AALW6I49071700Sulfate,Turbidimetric(asSO4)Bedizen,Total(Na)Chloride(asCl)Solids,Dissolvedat180CAtuninun,Total(Al)pNSpecificConductanceat25C51mg/L5.9mg/L10mg/L140mg/L1.5,mg/L7.6300umhos/cmCOHHENTS: ongJSI+C0RP0RATI0NLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage8CLIENTNAME:ADDRESS:ATTENTION:INDIANAHICNIGANPOWERCOHPANYONECOOKPLACEBRIDGHAN,Hl49106-0000MS.JENILEWIS-CHEHISTRYDEPT.NUSCLIENTNO:06630020WORKORDERNO:55830VENDORNO:05411000CarbonCopy:SAHPLEID:TURBINEROOHSUHP27509/FILTEREDNUSSAHPLENO:P0259291P.O.NO.:69034-040-3NDATESAMPLED:02-JAN-94DATERECEIVED:05-JAN-94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERHINATIONRESULTUNITS1AALF.Atuninun,Dissotved(At)COHMENTS:0.3mg/L /4L:HalliburtonNUS+C0RP0RATI0NLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage9CLIEHTNAME:INDIANAMICHIGANPOWERCOMPANYADDRESS:ONECOOKPLACEBRIDGMAN,MI49106-0000ATTENTIOH:MS.JENILEWIS-CHEMISTRYDEPT.NUSCLIENTHO:06630020WORKORDERNO:55830VENDORNO:05411000CarbonCopy:SAMPLEID:ABSPONDCOMP.HUSSAMPLENO:P0259292P.O.NO.:69034-040-3HDATESAMPLED:31-0EC.93DATERECEIVED:05-JAH94APPROVEDBY:Kieda,ChuckTEST.LNCODEDETERMIHATIONRESULTUNITS117302ANAW31130415905AALWSulfate,Turbidimetric(asS04)Sodiun,Total(Ha)Chloride(asCl)Solids,Dissolvedat180CAtuninm,Total(Al)1102892100.33mg/Lmg/Lmg/Lmg/Lmg/LCOMMENTS: onNU$I++C0RP0RATI0NLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January1B,1994ReportNo.:0001B939SectionAPage10CLIENTNAME:ADDRESS:ATTENTION:CarbonCopy:INDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAN,Ml49106-0000MS.JENILEWIS-CHEMISTRYDEPT.NUSCLIENTNo:06630020WORKORDERHO:55030VENDORNO:05411000SAMPLEID:ABSPONDCOMP./FILTEREDHUSSAMPLENO:P0259293P.O.NO.:69034-040-3NDATESAMPLED:31-DEC.93DATERECEIVED:05-JAH.94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMINATIONRESULTUNITS1AALFCOMMENTS:Atuninun,DissotvediAI)0.099mg/L
- 4'.HalliburtonNUS%%ENC0RP0RATI0NLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportHo.:00018939SectionAPage11CLIENTNAME:ADDRESS:ATTENTION:INDIANAMICHIGANPOWERCOMPANYOHECOOKPLACEBRIDGMAN,Mi49106-0000MS.JENILEWIS-CHEMISTRYDEPT.HUSCLIENTHO:06630020WORKORDERNO:55830VENDORHO:05411000CarbonCopy:SAMPLEID:HUSSAMPLEHO:P.O.HO.:ABSPOHDCOMP.P025929469034-040-3NDATESAMPLED:01-JAN94DATERECEIVED:05-JAH-94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMIHATIOHRESULTUNITS117302AHAW3I1304I5905AALWSulfate,Turbidimetric(asS04)Sodiun,Total(Na)Chloride(asCl)Solids,Dissolvedat180CAluminize,Total(Al)110mg/L30mg/L10mg/L210mg/L0.35mg/LCOMMENTS:
i:HalliburtonNUSI+++C0RP0RATI0NLABORATORYANALYSISREPORTNUSLASORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage12CLIENTNAME:ADDRESS:ATTENTION:CarbonCopy:INDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAN,Ml49106-0000MS.JEHILEWIS-CHEMISTRYDEPT.HUSCLIENTNO:06630020WORKORDERHO:55830VEHDORNO:05411000SAMPLEID:ABSPONDCOMP./FILTEREDHUSSAMPLEHO:P0259295P.O.HO.:69034-040-3NDATESAMPLED:01-JAN-94DATERECEIVED:05-JAN-94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMINATIONRESULT.UNITS1AALFAtuninua,Dissolved(At)0.10mg/LCOMMENTS:
L:HalliburtonNUSI+++C0RP0RATI0NLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage13CLIENTNAME:ADDRESS:ATTENTION:INDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAH,MI49106-0000MS.JEHILEWIS-CHEMISTRYDEPT.NUSCLIENTNO:06630020WORKORDERHO:55830VENDORNO:05411000CarbonCopy:SAMPLEID:NUSSAMPLEHO:P.O.NO.:ABSPONDCOMP.P025929669034-040-3NDATESAMPLED:02-JAN-94DATERECEIVED:05-JAN-94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMINATIONRESULTUNITS1I7302ANAW31130415905AALW61700Sulfate,Turbidimetric(asS04)Sodiun,Total(Ha)Chloride(asCl)Solids,Dissolvedat180CAlumina,Total(Al)SpecificConductanceat25C10031101900.5400mg/Lmg/Lmg/Lmg/Lmg/Lumhos/cmCOMMENTS: .".HalliburtonNUSI~~iC0RP0RATI0NLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage14CLIENTkAME:ADDRESS:ATTENTION:IHDIAHAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAN,Mi49106-0000MS.JENILEWIS-CHEMISTRYDEPT.NUSCLIENTNO:06630020WORKORDERNO:55830VENDORNO:05411000CarbonCopy:SAMPLEID:ABSPOHDCOMP./FILTEREDNUSSAMPLENO:P0259297P.O.HO.:69034-040-3HDATESAMPLED:02-JAN.94DATERECEIVED:05-JAH-94APPROVEDBY:Kieda,ChuckTESTLHCODEDETERMINATIONRESULTUNITS1AALFAtuainun,Dissolved(At)0.072mg/LCOMMENTS: /4L'HalliburtonNUS+++C0RP0RATI0NLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage15CLIENTHAME:ADDRESS:ATTENTIOH:INDIANAMICHIGANPOWERCOMPANYOHECOOKPLACEBRIDGMAN,MI49106-0000MS.JEHILEWIS-CHEMISTRYDEPT.NUSCLIENTHO:06630020WORKORDERHO:55830VENDORHO:05411000CarbonCopy:SAMPLEID:ABSPONDCOMP66998NUSSAMPLENO:P0259298P.O.NO.:69034-040-3NDATESAMPLED:03JAN-94DATERECEIVED:05-JAN-94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMINATIONRESULTUNITS117302ANAW311304I5905AALW8I700COMMENTS:Sulfate,Turbidimetric(asSO4)Sodiun,Total(Na)Chloride(asCl)Solids,Dissolvedat180CAtuninua,Total(Al)SpecificConductanceat25CI11028101900.5410mg/Lmg/Lmg/Lmg/Lmg/Lumhos/cm .".Hallibu1tonNUSCORPORATIONLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage16CLIENTNAME:ADDRESS:ATTENTIOH:IHDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAH,MI49106-0000MS.JENILEWIS-CHEMISTRYDEPT.NUSCLIENTNO:06630020'WORKORDERNO:55830VENDORNO:05411000CarbonCopy:SAMPLEID:NUSSAMPLENO:P.O.HO.:ABSPONDCOMP66998/FILTEREDP025929969034-040-3NDATESAMPLED:03-JAN-94DATERECEIVED:05-JAN-94APPROVEDBY:Kieda,ChuckTESTLHCODEDETERMINATIONRESULTUNITS1AALFAtuainua,Dissolved(Al)0.088mg/LCOMMENTS: SEEINSTRUCTIONSONREVERSESIDESECTIONIINUMBERPERMIT~NIppp5827~OOEAsLOCATIONOFDISCHARGE~~~t~EE~v,ernssi~00.EeDISCHARGELOCATIONBN%RECEIVLNLHATER(IEsGROINLNATERCRNA%OFQRFACEMAC>>OO@XIDISCHARGESEASCNALLYLLFMsCONTIIAKIOE)DsIFYESeLISI'ISCNRGEPERIODSIQs/DAYHL,/DAYSANITARYABSPONDFLOWRATEWASTEWATERJZKSQQF1CONTACTCOOUNG2NONCONTACTCOOLNG3PROCESS4SANITARY5STORMWATERQQE1MGYMGD3GPDITEM2WATERTREATMENTADDITIVES.LINLLSCODE1Mg/I2Ug/IEsLANDAPPLICATIONRALEFsTYPEOFHASLEHALERDISCNRGEG~DISCNRGESOELXAE(YEARLYAVERAGE)oISCHARGEFUNŽENAINsHIeIRsDAYINs/NKsLLJ~LJLLJ~LJLLJ~LJQNU4L3JLJLJLJL-IHOURS/DAY~4lOTALYEARLYDAILYHINIISHDAILYHAXIISNsvvlvsss*13.505~10372JeNXIILHDESIGNDISCNRGEFUNRATEsAs9)YOUUSE'KATER1REAL%NLACOITIVESTOlREATYIRDISOHKO(LFN).COILS@YOLTLH3)SeN%FINCTICNsAEIOEHICALCQSKSITICNOFTHESEALSIITIVESeDESIGN0.060pxC186KCalciumHochloriteforF'aeC>>N%AIEIAZCRESSOFH4MFACLLRERSOFLIAISEAIDITIVESeVANWATERSANDROGERS,INC.L600NORTONBUILDINGSEATTLE,WASHINGTON98104-156LslIENXDSNDISCNRGKFUNRATETOSEAIIIHCRLZEDINPERIITe~LZpgpp6pINI)LODEDsEXPKTEDDISCNRSECQCEHIRATI(NOFALOLTIVESeHINIISHINILSAVERAGECLLKINITSNXIISNevevvvvsssevvTotalResidualChlorine0~,0ALOITIVENA%LJs~ALIITIVENA%EsDO%XITREATl%DLSCNRGElOROTEALOlT1VES?FsISN'TISlHKRBOVALEFFLCL8CYANDDISCNRGEFRKLLKLCY7ACOITIVENA%ALEITIVENA%ALOITIVENA%IRSs/OAYDAYS/'HK.LJLLJLJLJG,ASANATTACHMENTlOlHISAPPLLCATICNPROVIDESPKIFICHASQLIANCRACUATIClOXICOUSLCALDATACRREFERENCEHHIOIAREAVAIIASLENDINRRQTLCNCNlHERATEOFDKRAMTICNOFlIEPRXXCTSFCREACHALOITLVEiIYISDSAttachedCalciumHypochloriteisaddedtothemixedliquorandisuseduppriortodischarge.31 INSTRUCTIONSFORCOMPLETINGSECTIONIIITEMSIANO2ThisformrequiresIntormatlononthefeelIity'sdischargelocation,dischargeschedule,volumeflovrateandwatertreatmentadditives.ENTERTHEPERMITNUMBFRINTHEBOXATTHETOPOFTHISFOFM.THEPERMITNUMBERCANBEFCUNOONTHEFRONTPAGEOFYOUREXPIRINGPERMIT.IfthisIsanevornotpreviouslypermittedfacility,thenleaveblankandanumberwllIbeassigned.EntertheouttaIInumberInspaceprovidedforeachpageo!SectionII.ForeachIndividualdischaroepointaseparatesetofSectionIIformsmustbefilledout.ITEMIDISCHARGELOCATIONSCHEDULEAIOFLOWRATESA.Enterthelocationofdischarge,thisshouldIncludequarter-quartersection,quartersection,section.(own,andrange.B.ListnameofreceIvingwater(ifsurfacewaterdischarge).C.IndlCatewhethertaCilltydlSChargeSOnaSeaSOnalbaSIS.O.Ifyes,listdischargeperiods.E.ProvidethelandapplicationratesusedorexpectedtobeusedIntermsofInchesperhour,houtsperday,andInchesperv<<k~F~Indicatethetypeofwastewatertobedischargedfromthisoutfall.RefertothewastewatertypecodegivenIntheleftmargin.Morethanonecodemaybeappllcable.G~ProvidetheaveragenuxberofhoursperdayInwhichthefacilitydlschargeStreatedwastewaterandthetotalnmxberofdaysperyearInwhichthedischargeoccurs.H.Providecurrent(fromtheInstl2months)orexpectedflowratesasrequested.RefertounitcodeqlvenIntheleftmargin~fortheappropriateflowunits.MGY-milliongallonsperyear;MGO-milliongallonsperday)GPO-gallonsperday.I.Providethemaximumdischargeflowratewhichyouventtohaveauthorisedwithinthepermit.NOTE:ForNPOESpermitsonly.theuseofsuchaflowratewillnotplaceanactuallimitrestrictiononthetlovbutwillbetheflowrateusedtodevelopetf(ventlimits.Also,whentheMonthlyOperatingReportsarereviewedbyCompliancestaffItvillhelpthamtodetermineItanynevorincreasedusesmighthaveoccurredatthefacility.J.Providethedesignflowforthisspecificoutfalldischarge(e.g.batchtreatmentsystemflow,packagedtreatmentsystemflow.orscmeotherfinitetreatmentsystemflow).ITEM2WATERTREATMENTADOITIYESA.IndicatewhetherdischargeIstreatedwithconditioners,Inhibitors,ormlcrobloclde.Ifnot,continuetoItem3.B.Givename,function,andchemicalccmposltlonofadditivesused.C.Givenameandaddressofthemanutacturer(s)ottheadditivesused.o.Indicateexpectedmlnlxxxn,averageandmaxlaxxxdischargeconcentrationsoftheadditive(s)torthisdischarge.E.IndiCatevhetheryOutreatthed(SChargetOremOVetheaddltlVe(S)betOrediSChargeOfWaSteVater.F.Indicatetheremovalettlclencyofeachadditivet(xxxthevastevaterandthedischargefrequencyofeachadditivetothesurtacewaterorgroundwater.G.NOTE:ItIstheresponSlbllltyoftheapplicanttosupplytheproductInformationasrequestedInthisItem4.InformationrequestedbutnotsuppliedmayresultIntheapplicationbeingreturnedtotheapplicantforcompletion.32 VANWAXEfisbROGERSXNC.NhrERXAI,".,AFE'lYnhrA:-"HEErREF'('.)BTNLJI"IBER:971NSD!)H(3:PG0310IECIIVF.DATE:06/21/93PRODl)CrlCAI(.,XUNHYPOCHL(3RITEGRANI)I,.AIRf'A(3E.',001Vf:.RSIQH:004(3RDERHQiPRQI3HOVAHWATFRS6ROGERSINC.,SLJBSXD3:ARY(3FUNXVAR6100CARXLIONP(3XNTKXRKLAHD(20/>)889-3400,WA98033ENERGENCYAS,.X.TAHCEF(3RENERGENCYASSXSTAHCEINVOI.VXNGCHFiIXCALSCALI.-CHENTREC<800)424-9300FORPRODUCTANDSAII=SXNFORNATIONCONTACTYOURLOCAI.VANWATERSh,ROGERSBRANCHOFFICEATVWbRSOUTH.BEHD219-289-0321SOUTHBEND,XNPRODLJCTNANE:CAL(::XUNHYPOCMIORITEGRAHLJLARNSDSe:FGO31OCALCIUNHYPQCHLORXTEGRAHLJLARDATI=:.'.'~7"05)',:L6'I',93'i"',.'-,-'i."iTRADENANEi,"..'.CAI..CXUH,'.HYPQCHLORITE6RANlJLAR(".HENHAilE/SYH~,".GAL;QYPP,'PXTTCLOR,IN13(JCL(3R,REPAK,ZAPPITCHENXCALFANXLY~i-'.:-"-'YfOCHLORXTEFQRN(JLA:CA(OCL)2CASHUNBER:007778-54-3(J.S,DOTSHIPPINGNANEiCALCIUNHYPQCHLORXTE,HYDRATEDU,S.DQTHAZARDCLASS:5.1(QXXDXZER)SUBSIDXARYRISKH/AX.DENUNBFR:LJN2880~~~~KXHGGROlJP:XX.ORT*BLEQUANTITY:loLBS/4.5l<GXNQDESCRXPTXON:GALCXUNHYPOCHLORXTF,I-IYDRATED,CLASS5.1,UN2880,PACl<XHGGRQlJPXX,RQ,INDGCODEPAGE5138,
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SEEINSTRUCTIONSONREVERSESIDESECTIONflPERMIT~IYI10005827NUMBERIEM3AsNatEOFPROCESSCONTRIBUTINGTOTHEDISCHARGETNOUSITHISOUTFALLAteSICCODEBePRXESSSCHEDLLE(YEARLYAVERAGE)~OOESANTTARYWTER4911PROCESSSTREAMSCONTRIBUTINGTOOUTFALLDISCHARGEChCOCitOs0CECLCePRCCESSICCSTEHATKRFLD/IRATEDePROCESSPRODUCTIONRATEN/ATOTALYEARLYDAILYMINIt/LTCDAILYHAXIttti8577wIT~011~6037~6WITSiTI%~LJ1POUNDS2GALLONS3CUBICYARDS4TONS5MGY6MGD7GPDTIME1HOUR2DAY3WEEK4MONTH5YEARC/IOili0AeNA%OFPROCESSCONIRIBUTMTOTIEDISQCLRGEg/ATIRLXXIHTHISOUIFALLAteSICCODEB.PROCESSSOGXIE(YEARLYAVERAGE)C.PROCESSHASTEHATERFLDHRATEReCESSPRODUCTICNRaTEA'EoFPRxEsscoNIIBUTIIDToTIEDlscHARGEg/ATIROUGHlHISOUTFALLAtCISICCLXEBePROCESSSQEDLAE(YEARLYAVERAGE)CsPROCESSHLSTEHATERFLDHRATEDePROCESSPRODLCTIONRATEAsNAIEOFPROCESSCONTRIBUTINGTOTIEDISCHAR%g/ATHAteSICCLXEBePROCESSSQEDLLE(YEARLYAVERAGE)CsPRXESSHASTENCTERFLDHRATEesses/sev~ssvs/vsesTOTALYEARLYDAILYHINIIRIIDAILYI/AXIPLPITOTALYEARLYDAlLYHININtlDAILYHAXIt%PITOTALYEARLYDAILYHIHI%PIWITS/TIIEWITSPTltEWITCODECOCECLDePROCESSPteDUCTIONRATEHat%oFPtecEsscoNIRIBUTINGToTLEDlmARGEg/ATIROUIHlHISOUIFALLANDSICCODEBsPRXESSSCHEDLLE(YEARLYAVERAGE)CePROCESSHASTEHATERFLOHRATEDePRXESSPRODUCTIONRATEDAILYHAXIMMTOTALYEARLYDAILYHINIIEtlDAILYHAXItLPIssvs/vsseWITSMIHKWITCODEW~NITSTIIE33 INSTRUCTIONSFORCOMPLETINGSECTIONIIITEM3TrisformrequiresInformationontheproceasstreamSwhichcontributetothisdischarge.ENTERTHEPERMITNLSIBERINTHEBOXATTHETOPOFTHISFORM.THEPERMITNISIBERCANBEFOUhTIONTHEFRONTPAGEOFYOUREXPIRINGPERMIT.IfthlSISanawOrnOtPreVIOuSlyPermittedfaClllty,thenleaVeblankandanumber<<illbeaSSlgned.EnteroutfallnumberInspaceprovidedforeachpageofSectionII.ForeachIndividualdlscharceointaseparatesetcfSectionIIformsmustbefilledout.PROCESSSTREAMSCONTRIIRITINGTODISCHARGE:FOREACHSEPARATEPROCESSPROVIDETHEFOLLOflf6INFORMATIONA.Enterthenameoftheprocess<<hlchcontributestothisdischarge.AlsoprovidetheproperSICcode.B.IndicatetheyearlyaverageprocessscheduleInhoursperdayanddays-per-year.CProvidetheprocesswastewaterfirnrateInformationasrequestedbasedonyourlastl2monthsofoperations'efertounitcodagivenintheleftmarginfortheappropriateflowunits.D.ProcessProductIonRate-Certainpermitlimitationsmaybebasedonproductionrates.Theproductionratesusedtodeterminepermitlimitsshallberepresentedbyareasonablemeasureofactualproductionofthefacility,suchastheproductionduringthehighmonthofthepreviousyear,orthemonthlyaveraqeforthehighestofthepreviousfiveyears,orOtherreasonablemeasureasstatedinapplicableU.S.E.P.A.categoricalrulesandregulations.Fornewsourcesornewdlschargers,actualproductionshallbeestimatedusingproJectedproduction.RecordyourproductionratesInthetermsandunitsusedIntheapplicableU.S.E.P.A.categoricalrulesandregulationsforyourtypeoffacility.34 SEEINSTRUCTIONSONREVERSESIDESECTIONIINUMBER~EM4GROUNDWATERDISCHARGEINFORMATIONAeISTHEDISCHARGEFROMTHISOUTFALLDIRECIKDTOlHEGRa5DORGROQCWATERS?(IF%ACOttTINKTOITEM0)BeHASAHYDROGEOLOGICALSTUDYORITSEQUIVALENTBEENPERFORMEDORISTHEREBIFFICIBITCURRENTHYDROGEQLQGICALINFORMATIONAVAllABLEASREQUIREDBYTIEHATERRESIMICESatttlsstONPARTZ2GRONIDtATKRRIAESOFAuiUSTltlo19%RI525.2207(PAGEILI)FORTHISEXISTI%ORPROPOSEDDISCHSRGETIFYESATTACHACCPYCFTHEREPORTSCeAREYOUREIXEST1%ANEXB1PTIONFRCMSIBIITTI%AHYIIIQGEQUXIICALREPORT%DERRLAERe323AZR7(19}(PAGEQ)ORFROMGRIXNDtATKBtCEIIIORI%IIEOU)RBIENISWDERRULERe525IZdS(5)(PAGE+OF1%PART22RLLES~IFYESATTACHDQat6ENTSANDEXPIANATICNTODBXINSTRATKTHATVIX'ISCHARGEMXADQUALIFYFORANEXBflONeDeAREYOURBXKSTI%AVARIANCEFIOIRULE323e2205(PAGEP(tOteEGRADATION)OFTHEHATERREstxwcEscctt11ssIQNPART22GRQNIDIATERRILEs?IFYKS,ATTAOHSUOHDOQHBITSASNECESSAlÃTODEMONSTRATETIENEEDFCRAVARIANCEINTERMSOFTIECRITERIASPECIFIEDINRIAE525e2210(PAGECF1HEPART2ZRRESAEeI,ISTAlp.CHEIIICALSIBSTANCESHHICHAREINMICHIGANSCRITICALMATERIALSREGISTERTABLEIVLPAGED)AND/ORUeseEPA'SPRIORITYPOILUTANTLISTTABLEV(PAGE7)ORANYmtERSIBSTANCESttIICHARECRHAYBECOMEIMHIOUSTOTIEEESIGNATKDUSESOF1%GRXMlATKRORTOTHEPUBLIC%ALTHlHATAREDISCHUIGEDOREXPECTEDTOBEDISCHARGEDTOTIERQXLIKX6ATKRAY1HISFACILllYeESTIMATETHEFINALEFFLUENTCONCENIRATIIXINDRECORDALLDATAINITBI7OFSECTICNIIIN1HISBOOILETeTIEAPPLICANTHAYBERECUIREDlDDOAIXIITIONALHASTEANALYSESA~OOEEgYESX.S,Submitted12/6/91YESXa-NOTAPPLICABtx/BELIEVEDABSENTPRESENTSDATAPROVIDEDINITBI7ElITENI5EXPECTEDWASlEWATERCHARAC-UNETSCODE1MQ/I2UQ/I3COUNTS/100ml4S.U.5F6LBS/DAYAeDISCHARGECHARACTERISTICS'TOC(TOTALORGANICCARBON)AtfCNIANITROGEN(ASN)TOTALSUSPB4KDSOLIDSTOTALPtDSPHOftUS(AsP)TOTALRESIIXIALOUNINEDISSOLVEDOXYGENMIN~6~4FECALCOLIFORtlBACTKRIA'TBmmltttE(sums)79%%RATINE(HINIKR)BQOI3(FIVEDAYBIOCteIICALOXYGENDEHAIB)COD(CtetlCALOXYGBIDEMAND)CCNCENIIIATIONAVEHAX~40.~05~99.~6~~~QJ~ELlZ~~~5.~55'116,~0~73,~036~12.~05LLJ~LJ~~LJBeOTHERHASTKHATERCHUIACIKRISTICSWITSCODE0ANALYSESSAtPLKTYPECOCEu1~l2~60~1~113~3u3~RAMPEZXBE1GRAB224KOURCOMPOSITE0ILSGREASEn'c1cc.~65,~56~208,~0LJ~l~65RBXIIREDIIFOWATICNFIERYSINFACEHATERDISCHARGESe INSTRUCTIONSFORCOMPLETINGSECTIONIIITEMS4ANO5ThistomrequiresInformationonsspecificoutfalldischargingtoeitherthegroundwstersorthesurfacewaters.ENTERTHcPER4IIThlPIBERINTHEBOXATTHETDPOFTHISFORM.THEPERMITNl+IBERCANBEFOUNDONTHEFRONTPAGEOFYOUREXPIRINGPERMIT.IfthlSISSnewOrnOtpreVIOuSlypermittedfaCIllty,thenlenVeblankOndOnumber<<IIIbeSSSlgned.EntertheoutfallnumberInthespaceprovidedforeachDogeofSectionII.ForeachIndividualdisehsroepointasearetesetofSectionIIforms(Items4and5)mustbefilledout.ITEM4GRCUNDWATERDISCHARGEINFORMATION(00NOTINCLUDEDEEPWELLINJECTIONINFORMATIONINTHISITEM)A.-D.TheapplicantshalladdresseachofthesepartsIfthedischargetrcmthisoutfallIstotheqroundwoter.ITEM5EXISTINGOREXPECTED(FORANEWDISCHARGE)WASTEWATEPCHARACTERISTICSOFGROUNDWATERORSURFACEWATERDISCHARGE(DONOTINCLUDE<<LLINJININNHA.TheapplicantshelIreportnvnilabledischargedata(realdataforexistingdischargeorexpecteddotsfornproposeddischarge)fortheDarnmetersaslisted.TheseparametersshallbeaddressedforeitherasurfaceraterdischargeorssaDDroDrlateforsgroundwaterdischarge.ForassistanceIndeterminingappropriateparametersaground~sterdischaroeapplicantmsycontacttheGroundwaterDualityDivision,permitsSectionortheapproprlateGroundwaterpunlityDivision'sDistrictoftlce.Theapplicantshalli'eportthesampletypecodebestdescribingeachreportedpieceofdots.seecodingontheleftmarginofthistofmIfthisoutfallIsnsurfacewaterdlschsrqe,theapplicantmustreportquantitativedotsforeachparameterIdentifiedbonPPIty,",Ietd9dhelldptPo.Pheoettbe~ppdtedbydeopttiedI.dhodheelleptpttpht0thlpelltlB.IfdataIsavailabletorotherparametersnotlistedaboveInA.orotherpartsofthisapplicationtheapplicantshouldreDortthatdataIntheblankspacesprovidedInthispart.<OTEStI.UnitcodesforparametersreportedInportsAsnd8cnnbefoundontheletthandsideofthistore.2~GrabSnmoleShelIbeuSedtOSnolyZefarPH,temperature,tOtslPhenOIS,reSldualChlOrlne,Oilnndgrea5e~andfecalcoliformInnsvrtaeewaterdischargeunlessotherfrequency-snmD(etypeanalysesareavailable.SeeGlossary(pnge48)fordefinitionotgrabSample.24-hourcompositesamplesshallbeusedtoanalyzeforTotal8005,COO,TDC,AmnonlnNitrogen,andTotalSusDendedSolidsinosurface~sterdischargeunlessotherfrequency-sampletypeanalysessreavailable.SeeGlossary(page48)tordefinitionotcomDOSltesample.4.REPORTINGOFINTAKEDATA.Youarenotrequiredtoreportunlessyov<<Ishtodemonstrateyoureligibilityforo"net<<effluentlimitationforoneormorepollutants,thatIs,nneffluentlimitationodJustedbysubtractingtheoveragelevelotthepollutant(s)presentInyourIntake~ster.NPOESregulationsnl(ownetlimitationsonlyIncertaincircumstances.Todemonstrateyoureliglblllty,reporttheoverageoftheresultsotanalysesonyourintakewater(ifyour<<sterIstreatedbeforeuse,testthe~sterofterItIstreated),sndattachsseparateSheetcontninlngthefollowingtoreachpollutant:(a)AstatementthattheIntake<<sterIsdrowntromthebodyot<<sterIntowhichthedischargeIsmode.(Otherwise,youorenoteligiblefornetlimitations.)(b)AstatementottheextenttowhichthelevelofthepollutantIsreducedbytreatmentofyourwastewater.(Yovilimitations<<illbesdJustedonlytotheextentthatthepollutantIsnotremoved.)(c)Whenapplicable(forex(mpple,whenthepollutantrepresentsacla55otcompounds),ndemonstrationoftheextenttowhichthepollutantsIntheIntakeveryphysically,chemically,orbiologicallyfranthepollutantscontainedInyoui'ischarge.(Yourlimitations<<illbeadjustedonlytotheextentthattheIntakepollutantsdonotvaryfrobbthedischargedDo)lvtants.)5.Ifyouhavetwooi'oresubstantiallyIndentlcaloutfslls,youmsyrequestpermissiontronyourpermittingOuthOrltvtosamplenndanalyzeonlyoneouttsllnndSubmittheresultsoftheanalysistorotherSubstantiallyIdenticaloutfalls.IfyourrequestIsgrantedbythepermlttlnoauthority,onsseparatesheetattachedtotheSDPIICstlOnfOrmIdentityWhlChOuttallydudidteSt,SnddeSerlbe<<hytheOutta(ISwh(ChyOudidnOtteStnresubstantiallyIdenticaltotheovtfollwhichyoudidtest.'36 SEEINSTRUCTIONSONREVERSESIDESECTIONIIPERMIT~IYIZ0005827NUMBEROOEeNI6PRIORITYPOLLUTANTSaNDADDITIONALINFORMATIONFORSURFACEWATERDISCHARGEONLYTHEFOUXHI%REQUESTEDINFOIVIATION~ADCRESSEDBYJILLQJIFACEHATERDISCHARGERSIIIGIEtNKHUSEDlSCHARGERSSUB'ROVIDEEXPECTEDVALIKSFORTHEQUANTITATIVEANDQUALITATIVEINFORtllTIONREQUESTEDBELOhloAIISTHISFACILllYAPRIMLYINIXSTR(.(REFERTOTABIEIAPPl<(IFtKJGOTOE)(IFYSGOTOB)BIINDICATETYPEOFPRIMARYINDUSTRYASLISTEDINTABIEIAPAGEQ(CONTI~HITHC~)CIICES1HISOUTFALLDISCHARGECCttfAINANYPROCESSHASTEHATKR7(IFNOrGOTOE)(IFYES.GOTOD)DetNDICATKltttCHGC/MSFRACflONStKJSTBETESTEDFORe(REFERTOTABLEIAPJJ>EKQEIFOREACHQJMSFRACTIONCHECKEDrEAtHSPECIFICORGANICTOXtCPOUJJTAMTHITHINEAQIFRACTION55'KANALYZEDFOR(SEETABLEIIAPAGEQ,INADDITIONALLPRINARYIMXJSTRYAPPLIuWTSHITHAPROCESSHASTKHATERDISQURGE~PROVIDEQUWTITATIVECATAFOREACHTOXICPOLUJfANTINTABLElllAPN499IRECORDALLDATAONFORMSPROVIDED(ITEM7)INTHISBOOKLETI(CQMTINEHITHEKBEUAt)QYESNOSTMEL'EPWRYES~XMODAnalysisperJ.B.BeauboeufDBASK/NKUIRALGroundwaterDivisionACIDPESTICIDEEoIF~QJIFACEHATERDISQIARGEAPPLICANT(PRINRYORSECNIDUIYIMIXJSTRY)rREGARDLESSOFTHETYPEOFDISCHARGErKXHSORHASREASONTOBELIEVETlQTANYPOLLUTANTLISTEDINTABLEIIAANDIVAPAGKS~IsDISCHARGEDFRQIAMYIXJIFAILrTIEQOWTITATIVEDATA~BEPROVIDED'EcoRDALLDATA0NF0RMsPRQYIDED(ITKJI7)INTHIsBQQKLEf.F.IFAMYQRFACElATERDISCHARGEAPPLICANT(PRIMLYORSECONDARYIMXJSTRY)rREGARDLESSOFTYPEOFDISQJUIGErKIKXtsORHASREASONTOBELIEVEANYPOUJJTANISLISTKDINTABLEVAPAGE+AREDISCHARCMFROMAMYIXJIFALLTIEAPPLICANT~DESCRIBEREASONSFORTIEPOUJJTANfBEI%PRESENTANJPROVIDEANYAVAILABLEQUANTITATIVEDATAIRECORDNLKATAOMFOtttsPROVIDED(ITEM7)INTHISBOOKLET>NOTAPPI.ICABLE/BELIEVEDABSENf0N/AOPRESENT/DATAISAlTACHEDQ%TAPPLICABLE/BELIEVEDABSENTN/AQPRESENT/CATAISATTACHEDGIAILSIRFACEHATERDISC@AGEAPPLICANTS(PRIMARYAMDSECONDARYINDUSTRIES)%TAPPLICABLE/BEUEVKDAssatfQrVTRIQLOIIOPJE%LeTC~PlORHEXACtLONPIEJEttCRPJ(AlLDATAFCRTIEABOVEtKJSTBEGENERATEDUS1%STANDARDAMAt.YTICALCALISRATIIXIPROCEDIRES)CRKtKBtsORHASREASONTOBELIEVETHATTIXOISCRMAYBEPRESENTINTlEIRDISCNRGEr~REPORTtBIALITATIVESLTArGEJERATKDltgIQIUSEDASCREEN!%PROCEDNE%TCALIBRATEDHl'tHANALYTICALSTANDAtmrFOR45r18rTKIIIAQLDRODIBENZOPDIOXIN(TCIXJ)~RECORDAILDATAONFORMSPROVIDED(ITBIf)INTHISBOOKLETrQPRESENT/DATAISATTAQEDN/AJrIFTIESUIFACEHAlKRDISOIAAKAPPLICANTKJKXtsORWLSREASON10BELIEVETHATBIQUJGI~loxtcllYTKsfsHEREMADEINTHEIasfTtttEE(5)YEARsQNANY0FTlEAPPLtuWTSDISCHARGESORONARECEIVI%HATERINRELATIOttlDADISCHARGErPROVIDETHISItAAQTIONASANATTAQtENTTOlHISAPPLICATIONIKIIFACtWIIRACTLABXIATORYORCONQLTI%FIRMPERFORPKDANYOFTltAtaaYSESREQUIREDBYTHISAPPLICATIOttrPROVIDETIENAMEANDADDRESSOFEAQItasORATCRYORFIRMANJTHEANALYSESPERFQttEDASAMATTAQtKNTOFTHISAPPLICATIONaLIDOYCUDISCMUIGKANYOTHERTOXiCORINJLJIIOUS(JKMICALSUBSTANCES%TLISTEDINTABLESIVPAGEttAtOIIATHOU%VAPJVM~~,IFYESTIKJIIDENTIEYTIECHBttCALQ8STAJKXSAMOESTIMATETIEFINALEFFUXMTCCNCEJttttaTICNsrSUttITTHISltFOtttATIONASANATTAQtEMTTOTHISAPPLICATIONsQ%TAPPLICABLE'/AQAPPLICABLE/SEEATTAQIEDQMOTAPPLICABLEXAPPLicastE/SEKATTAQIEDQ%TappLicasLEN/AQAPPLtues/SKKATTAQIKD37 INSTRUCTIONSFORCCMPLETINGSECTIONIIITEM6ThisformrequiresInformationonaspecificouttnlIdischargingtothesurfacewaters.ENTERTHEPERMITNUMBERINTHEBOXATTHETCPOFTHISFORM.THEPERHITIRNBERCANBEFOUNDONTHEFRONTPAGEOFYOUREXPIRINGPERMIT.IfthlSiSOnewOrnOtpreVIOuSlypermittedfOCIlity,thenlenVeblankandnnumberWllIbenSSlgned.EntertheoutfallnumberInthespaceprovidedforeachpageofSectionII.ForeachIndividualdlschorqeointnseparatesetotSectionII,Item6formsmustbefIliedout.PRIORITYPOLLUTANTSANOAGOITIONALINFORMATIONITEH6NOTE:NOTE:IfyouhavetwoormoresubstantiallyIndentlcalouttnlls,youmayrequestpermissionfrcmyourpermittingauthoritytos<<cp(enndanalyzeonlyoneoutfnlIandsubmittheresultsottheanalysisforothersubstantiallyIdenticaloutfolls.ItyourrequestIsgrantedbythepermittingauthcrlty,onaseparatesheetattachedtotheappllcntlonformIdentifywhichoutfalIyoudidtest,anddescribewhytheoutfallawhichyoudidnottestoresubstantiallyIdentical,totheoutfallwhichyoudidtest.40CFRPart122.21(g)(8),Friday,AprlII,1983,providesforaSmalIBusinessExemptionfromthereportingofquantitativedatatororganictoxicpollutantsandtoxicpollutantsasrequiredbyPort122.21(g)(7)(ll)(A)or122.21(g)(T)(ill)(A).A~-C.TheseportsareselfwxplanotoryonddonotrequirefurtherInstructions.SimplygothrougheachpartanddonsIndicated.andE.-J.0.SeveralIndustrialcotegorlesandsubcategorieshovebeenexemptedfransubmlttlngdotsoncertainGC/MSFractions(40CFRPort122,Vol.48,No.64,Friday,AptIII,1983,NotesI.2.and3).'eviewthefollowinglisttodeterminewhetheryourfacilityqualitiestobeexemptfromreportingGC/MS(GasChrcmatography/MossSpectroscopy)Fractions.GC/MSFrnctionTestingnndReportingExemptionsTextileMillsInduct-AllfourGC/MSorganictractlonsIntheGreigeMIIIsSubcategory.-PesticidetractionInoilothersubportsofthisIndustry.OreMininondBrasslIndust-Volatile,base/neutral,andpesticidefractionsIntheBoseandPreciousMetalsSubcategory.-AllfourGC/MSorganIcfractionsInallotherSubcategoriesofthisIndustry.CueandMoodChemicalsIndustr-PesticidefractionIntheTallOilRosinSubcategoryandtheRosinBasedOerlvatlvesSubcategory.-Pesticideandbase/neutralfractionsInallothersubcategoriesofthisIndustry.PulandPaperInductPesticidefractionInPapergradeSulfitesubcatcqories(subpartsJandU).-Base/neutralandpesticidefractionsinOelnkSubpartQ,BlssolvinqKraftSubpartF,andPaperboardfromMastsPaperSubpartE.lt-Volatile,base/neutral,pesticidefract(onsIntheSCTSleschcdKraftSubpartH,Saci-chemicalSubparts8andC,andNonintegrated"FinePapersSubpartR.-Acid,base/neutral,sndpesticidefractionsinFineBleachedKraftSubpartI,OlssolvlngSulfitePulpSubpartK,Ground-woodFinePapersSubpart0,HarketBleachedKraftSubpart0,TissuefromMastepaperSubpartT,andNonlntegratcdTissuePapersSubpartS.SteamElectricPowerPlantIndust1-Base/neutralfractionIntheOnce-ThroughCoolingMater,FlyAsh,andBottomAshTransportMaterprocesswsstestreams.38 SEEINSTRUCTIONSONREVERSESIDESECTIONIIMj.pop5827EM7CRITICALMATERIALSTOXICPOLLUTANTS~OOEAeUSETHISDATASHEETTORECORDINFGLtLATIOMASRECUIREDIN:(CHECKAPPROPRIATEBOXFINWICHIMFLJLMATICNTHISDATASHEETREPRESEMTS~)OXlsSECTIONIIEITEMMeGROMlLATERDISCHJJLGEINFCttULTION(PAGE35)2eSECTICNIIEITEM6ePRIORITYRXJlJTAMTSINSLRFACEHATERDISCHLWiE(PAGE3TlDX3eBsBELJJELLCRITICALMATERIALS(TABLElv)INSLJLFACEHATERDIMJLARGE(PAGE39)HAZARDOUSSUBSTANCESINDISCHARGEBeLISTANYCRITICALMATERIAL(TABLEIVPAGE6)NOTADCRESSEDIMSECTICNIIITEH6PRIORllYPOLLJJTAMTSHHICHYOUtlat%ORHAVEREASONloBELIEVETOBEPRESENfINTIEDISCHLRGEISEEREVERSESIDEOFTHISPAGEFORFLJLTIERDIRECTICNSEtOTAPPLICABLEAPPLICABLE(SEEBELCN)UNITSCODE1MQ/ILUg/ILBS/DAYKG/DAY~AMPL~TYPg1GRAB224HR.COMP.CEILLEILLJLetILELitteeIAeNLHEOFCRITICALMATERIALCRPRIORITYJOLLJJTANTBeAVERAGECNCEMIRATICNJSAMPLETYPEJIIOFANALYSESCeMAXIt4NCCttCEtmLATICNAIOMASSAeNtt%OFCRITICALMATERIALCRPRIORllYPOLLUTANTBeAVERAGECCJJCEMIRATICNJQt%%ElYPEJJIOFANALYSESCeMAXIJLPICCNCENllVLTIONAtOMASSAeH4%OFCRITICALHATERIALCRPRICRllYPOLLIJTANTBeAVERAGECotCEJIIRATICNJQWETYPEJf.OFANALYSESCeMAXIJLNCOMXMIILATIONAN)MASSAeNA%OFCRITICALMATERIALORPR!ORllYPCLLJJTANTBeAVERAGECOICEMTRATICNJQtssLETYPEJJIOFANALYSESCeMAXIJLNCOtCEtmLATICNAtOHASSAeNA%CFCRITICALHATERIALCRPRIORITYPOLlltfANTBsAVERAGECXCEMTILATIONJQJ4ELETYPEJJJOFANALYSESCeHAXD%NCOLCEMIILATIONAJOMASSA>>NJ%OFCRITICALMATERIALCRPRICRllYPOUJJfANTBsAVERAGECCNCEMIRATIOIUSAtsLETYPEJf/OFANALYSESCHLXINJ1CCtCEMIILATINIAJOMASSAeNA%OFCRITICALMATERIALORPRICRllYPOLLLJTAMTBeAVERAGECONCEMIILATICNJSA+tETYPEJffOFANALYSESCeHAXIJLJLCONXMIRATICNAJOMASSAsNA%OFCRITICALMATERIALORPRIORITYPCLLJJTANTBeAVERAGECPJCEtflRATIONJQPPLETYPEJtJOFANALYSESHydrocIuinone*WITCCDEQHPIETYPEOFANAlYSESuLNITCODELNITCODELJ~~LJLNITCCKSAMETYPEOFANALYSES~.LLLJLJLNITGXKLNITCODELJLNITCCDESAMPLETYPEOFANALYSESLNCXKLNITCODELNITCCOESAINTElYPEOFANALYSESLNITCXKLNITCODELJ~~~LJLNITCXKQtsELETYPEJfOFANALYSESLNITCCDELNITCODELJ~~~LJLNITCXKSAftELElYPEOFANALYSES~.LLLJLJUNITGXKLNITCOIKLJ~~~LJIIIIYIEEEEIEEIEYIYECsEEICYEEELNITGXKLNITCODELJ~~~LJLNITCXESWALElYPEOFANALYSESLJCeHAXIKJLCONCEMIRATIOMAtOHASSUNITCODELNITCODELJ+Smallonly.wouldADDITIONALPAGESCFTHISITBl7AREATTAC%DFCR7%RESTOF~CRITICALE3YESMATERIALSAIO/CLPRICRTIYPLXWTAMTSRBXJIREDTDBEREPORTED.KNOquantitiesofHydroquinonemaybeusedinblackandwhitefilmdevelopinginemergencysituationsNofilmwasdevelopedin1993andnohydroquinonewasdischarged.Approximatelyoneliterbeusedwhenprocessingisnecessary.39 INSTRUCTIONSFORCOMPLETINGSECTIONIIITEM7ThisformIstobeusedbybothsurtaceandground<<aterapplicantstorecordInformationonanyMichigancriticalmaterial,E.P.A.prioritypollutant,orhazardoussubstanceIn<<hichthisapplicationrequiresdatatobeprovided.This<<ovidIncludeanychemicalSubatanoetramtheMIChlganCrltICalMaterlalSReglSter(TableIV),theE.P.A.PrlOrltyPOllutantLIStlngITableY),OrTableSIIA-YA<<hlchIlstsOrganicToxicPollutants,OtherToxicPollutants,conventionalandNonconventionalPollutantsandHazardousSubstances.ITEM7CRITICALMATERIALSPRIORITYPOLLUTANTSAND/ORHAZARDOUSSUBSTANCESINTHEDISCHARGEMaterialI2,3...8A.Listthenameofthechemicalsubstanceicrltlcalmaterial,prioritypollutant,orhazardoussubstance)franTablesIv,VandIIA-YAasrequiredInthebox<<hlchyoucheckedInA.I-3.above.Entereachchemicalsubstance'sparameternumberaslistedInTablesIV,YandIIA-VAItprovided.B.ProvidetheaverageconcentrationofthechemicalsubstancenamedInA.IndicatethesanpletypeusedandthenumberofanalysesmadetoprovidetheconcentrationdataforthechemicalsubstancenamedInA.C.ProvidethemaximusconcentrationanddeterminethemassloadingotthechemicalsubstancenmsedInA.NDTEs:I.Ifonlyoneanalysis<<asmadeforachenlcalsubstancethenrecordthatdataasamaxlmvnvalue.Itmorethanoneanalysishasbeenmadeforachemicalsubstancethenprovideanaveragevalueofthoseanalysesandthemaxlmmavalue.2.ThisSectionII,Item7.DataSheetprovidesspaceforrecordingdatafor8chemicalsubstances(Haterlals).Additionalspaceforrecordingofdataformorethan8MaterialscanbemadebymakingcopiesofthisItem7DataSheetasneeded.ItIsalsoImportanttouseaseparatesetotDataSheetsforeachapplicablereportingrequirementaslistedInA.I-3.andforeachoutfall'efertothelettmarginforthecodenumberrepresentingthesenpletypeusedandtheappropriateunitcodes.40 VOLATILEORGANICANALYSISRESULTSGC/HALLANALYSESUSINGEPAMETHOD8010linmIID:.EWAPLANTEFFLDoil'-DE-3DateAnalzed:05-JAN-94Matrix:WATERAnalticalBatch¹:.122093-801020-0-3LALSamleID:L100-DRiv;2-DEDilutionFactor:1QCBatchID:122093-801020-0-3BCMBFBrrtRvr10885QCLimis65-12560-120ConstituentDihlriflormhnhlrmhnVinIchlorideBromomethanehlrhnTrihirflrmhn11-DichloroetheneMethlenechlorideran-12-Dihlrohne11-DihlrhnChloroform111-Trichloroethanearbnrhlride12-DihlrhnTrichloroetheneTCE12-DichlororoaneBrmihlrmhn2-hlrhIvinIhercis-13-Dichlororoenetrans-13-Dichlororoene11-TrihlrhnTerhirhnPEDibromochloromethaneChlorobenzeneBromform1122-Trhlrhn13-Dichlorobenzene14-Dichlorobenzene12-DichlorobenzeneConcentrationIyg/LI<0.50<3<6<4<0.<0.5<0.5<2ReportingDetectionLimit/L0.50.50.5DataQualifierls)LOCKHEEDANALYTICALSERVICEShg
VOLATILEORGANICANALYSISRESULTSGC/PIDANALYSESUSINGIVIETHOD8020linmIID:.EWAEPANTFFLDIIce:28DE-9DateAnalzed:04-JAN-94Matrix:WATERAnalticalBatch4':122093-801020-0-3ALmlID:L109-DaRiv:2-DE-DilutionFactor:1QCBatchID:122093-801020-0-3TFTBFBurrRvr93101QLimis70-12075-120BenzeneTInConstituentConcentrationIL<0.5<0ReportingDetectionLimitIL0.5DataQualifiershlrnznEthIBenzenem-Xlene-Xln1-Dihlrnzen14-Dichlorobenzene12-Dichlorobenzene<2<2<2LOCKHEEDAIVALVTICALSERVICES$0 VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260Page1of2linmIID:.EWAEPLANTEFFLDateCollected:28-DEC-93Matrix:WATERAnaliIBah0114-2-F2QCBatchID:011094-8260-F2LALmIID;L1-47DateReceived:29-DEC-93DateAnalzed:11-JAN-94DilinFcr:1SURROGATERECOVERY12-Dihlrhn-4Tln-QCLimits7-1144-Bromofluorobenzene8686-115ConstituentGhloromethaneVinIhlridBrmomhnChloroethaneTrichlorofluoromethaneAn11-DihlrhnCarbonDisulfideMethleneChloriderans-12-DihlrhnVinIA11-Dichloroethane2-Butanonei-12-Dihlrhenhlrfrm111-TrichloroethaneCarbonTetrachloride12-DihirhnBnnTrichloroetheneTCE12-DichlororoaneBromodihlrmhn2-hlrohIVinIEhr4-MethI-2-entanonecis-13-DichlororoeneTInrn-1-Dihlrrn2-Hexanone112-Trichloroethane-TetrachloroethenePCEConcentrationIL<5<5<5<5<5<5<10<5<5<5<5<2<10<5<10<5<5ReportingDetectionLimitIL101010DataQualifiersLOCKHEEDANALYTICALSERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260Page2of2ClientSamleID:S.SEWAGEPLANTEFFL.LALSamleID:L1009-47ConstituentDibromochloromethanehirnznEhlnznm-Xleneo-XlenernBrmfrm1122-Tetrachloroethane13-Dichlorobenzene14-Dihlorenzne12-DichiorobenzeneConcentrationIL<5<5<5<5<5ReportingDetectionLimitILDataQualifiersLOCKHEEDANALYTICALSERVICES22 VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260TENTATIVELYIDENTIFIEDCOMPOUNDSClientSampleID:S.SEWAGEPLANTEFFLDateReceived:29-DEC-93Matrix:WATERAnalyticalBatch:011094-8260-F2LALSampleID:L1009-47DateAnalyzed:11-JAN-94DilutionFactor:1QCBatchID:011094-8260-F2TentativelyIdentifiedCompoundUNKNOWNSULFURCOMPOUNDUNKNOWNEstimatedConcentrationIyg/L)3728RetentionTime(minutes)4.479.70DataQualifierls)LOCKHEEOANALYTICALSERVICES SEMIVOLATILEORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270linmIID:.EWAEPANTEFFLDateCollected:28-DEC-93Matrix:WATERAnIiIBch¹':1114-827-BQCBatchID:8270-SEMIVOLATILES-3964IALmIID:L1-1DateReceived:29-DEC-93DiluionFactor:1DExr:4-JAN-4DateAnalzed:11-JAN-94P1f22-FluorohenolRRATEREVERY026Limi21-100Phenol-d,Nitrobenzene-d,2-FluorobihenI24-Tribromohenolp-Terphenyl-d,41861547610-9435-11443-1161-1233-141niuenPhenolbis2-ChloroethIether2-hlrhnI1-Dihlrnzn14-DichlorobenzeneBenzIalcohol12-Dihlrbenzne2-MhIhnolbis2-ChloroisoroIether4-MethIhenolN-Nir-Di-n-rIminHxhlrhnNitrobenzeneIsohorone-NirhnI24-DimehIhnIBenzoicacidbis2-Chloroethoxmethane24DihlrhnI124-TrihlrnznNahthalene4-ChloroanilineHxhlrin4-hlr--mhIhnI2-MethInahthaleneHexachloroccloentadieneConcentrationL<10<10<10<10<10<10<10<10<50<10<10<10<10<10ReportingDetectionLimitIL10101010101010101010501010101010DaaalifirsLOCKHEEDANALYTICALSERVICES SEIViIVOLATILEORGANICANALYSISRESULTSFORGC/IVISANALYSESUSINGIVIETHOD8270ClientSamleID:S.SEWAGEPLANTEFFLLALSamleID:L1009-31Pa2f2Constituent24-TrihlrhnI24-TrihlrhnI2-Chloronahthalene2-NitroanilineDimhIhhIAnhhln26-Dinitrotoluene3-NitroanilineAnhhn24DinirhnI4-NitrohenolDibenzofuran24DinirInDihlhhl4-ChlorohenI-henletherFluorene4-Nirnilin4-Dinir--mhIhnIN-Nitrosodihenlamine4-BromohenI-henletherHxhlrnznPnhlrhnlPhenanthreneAnthraceneDin-IhhIFlurnhenePreneButIbenzIhthalate'-Dihlrnziin8n'hrnChrsenebis2-EthIhexIhthalateDi-n-IhhIBnzflrnhnBenzokfluorantheneBenzoareneInn1-rnDinzhnhrnBenzohierleneCarbazoleConcentration(IL)<10<25<10<10<25<2<25<10<10<10<2<2<10<10<2<10<10<10<10<2<101.3<10<10<10<10ReportingDetectionLimitIIL)102510102525101010101010101010101010101010DataQualifieris)JBLOCKHEEDAItIALYTICALSERVICES4J. VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD'8270TENTATIVELYIDENTIFIEDCOMPOUNDSClientSampleID:S.SEWAGEPLANTEFFLDateReceived:29-DEC-93Matrix:WATERAnalyticalBatch:011194-8270-8LALSampleID:L1009-31DateAnalyzed:11-JAN-94DilutionFactor:1QCBatchID:8270-SEIVIIVOLATILES-3964TentativelyIdentifiedCompoundBenzaldehydeUnknownUnknownUnknownHydrocarbonHydrocarbonEstimatedConcentration(yg/L)10RetentionTime(minutes)7.8525.0527.4630.2531.9933.87DataQualifier(s)LOCKHEEDANALYTICALSERVICES42 PESTICIDEANALYSESRESULTSBYGC/ECDUSINGMETHOD8080FORCOOKNUCLEARPLANTClienSamleID:S.SEWAGEPLANTEFFLDateColleced:28-DEC-93DateExtracted:04-JAN-94Matrix:WATERAnalticalBatch4:012094-8080-A-1LALSmleID:L109-2DeReived:29-JAN-94DateAnalzed:21-JAN-94DilutionFactor:1QCGrouID:8080PEST/PCBS3965SURROGATERECOVERYOoQCLimitsTCMXDCB705060-15060-150A-BHCB-BHCG-BHCD-BHCConstituentConcentration/L<0.05.05<0.05ReportingDetectionLimit/L0.05.050.05DataQualifier(s)HEPTACHLORALDRINHEPTACHLOREPOXIDEG-CHLORDANEENDOSULFANIA-CHLORDANE44'-DDE44'-DDTDIELDRINENDRINENDOSULFANII44'-DDDENDRINALDEHYDEENDOSULFANSULFATEMETHOXYCHLORTOXAPHENEPCB-1016PCB-1221PB-122PCB-1242PCB-1248PCB-124PCB-1260TECHNICALCHLORDANEMIREXTCMX-tetra-chloro-meta-xyleneDCB-Deca-chloro-biphenyl<0.05.5.0<0.05<0.05<.05<0.1<0.1<0.1<0.1<0.1<5<2<0.10.05.00.050.050.10.10.10.10.10.10.10.5<0.1LOCKHEEDANALYTICALSERVICES METALSRESULTSClientSamle'D:S..SEWAGE.'.PLANT.EFF,DateCollected.'12-28-93,Matrix:.round.waterLALBatchID(s):1220imDateReceived:12-29-93PO¹69095-040-3N-.ConstituentsMethodConcentration-imIL)ReportingDetection.UmitlmIL)DataQualifierls)DateAnalzedLAL'amleIDAluminumAntimonArsenicBariumBeIliumBoronCadmiumChromiumCobaltCoerIronLeadManesiumMananeseMercuMolbdenumNickelSeleniumSilverSodiumThalliumTinTitaniumVanadiumZinc6010602060206020602060106020602060206020601060206010602074706020602060206020601060206020601060106020<0.20<0.060<0.010<0.20<0.005<0.20<0.005<0.010<0.050<0.025<0.10<0.003140.025<0.0002<0.20<0.040<0.005<0.01034<0.010<0.20<0.10<0.0500.0470.200.0600.0100.200.0050.200.0050.0100.0500.0250.100.0035.00.0150.00020.200.0400.0050.0105.00.0100.200.100.0500.02001-20-94L1009-1601-27-94L1009-1601-27-94L1009-1601-27-94L1009-1601-27-94L1009-1601-20-94L1009-1601-27-94L1009-1601-27-94L1009-16-01-27-94L1009-1601-27-94L1009-1601-20-94L1009-1601-27-94L1009-1601-20-94L1009-1601-27-94L1009-1601-07-94L1009-1601-27-94L1009-1601-27-94L1009-1601-27-94L1009-1601-27-94L1009-1601-20-94L1009-1601-27-94L1009-1601-27-94L1009-1601-20-94L1009-1601-20-94L1009-1601-27-94L1009-16Comments:LOCKHEEDANALYTICALSERVICES
GENERALCHEIVIISTRYRESULTSClientSamle(D:S.SEWAGEPLANTEFFLDateCollected:12-28-93Matrix:roundwaterLALBatch(D(s):1229imDateReceived:12-29-93POP69095-040-3NConstituentFluoride,inmILChloride,inm/LNitrate-Nitroen,inmILNitrite-Nitroen,inm/LSulfate,inmILAmmonia-Nitrogen,inm/LTotalCyanide,inmg/LMethod340.2300.0300.0300.0300.0350.1335.2Result<0.1512024<0.503924<0.020ReportingDetectionLimit0.150.0160.0170.500.0590.500.020DataQualifier(s)D(1:10)DateAnalzed01-24-9412-29-9312-29-9312-29-9312-29-9301-05-9401-03-94LALSamle'IDL1009-4L1009-4L1009-4L1009-4L1009-4L1009-8.L1009-12Comments:LOCKHEEDANALYTICALSERVICES SEEINSTRUCTIONSONREVERSESIDESECTIONIINUMSEAPERMIT~!ailppp5827iEMtAeUXATIONOFDISCHARGEB>>H4%RECEIVINGHATER(IE>>GROIKWATERCRIU<%OFSIRFACEDRYWES~NA~SW<~SPjSEtTIII~P6TM~jJQJRAKEDISCHARGELOCATIONCel}0YOUDISCHARGES~Y(IFIO>>CNTIIAETOE)DeIFYES>>LISTDISCHARGEPERIODStO>>/DAYYEStO>>/DAYFLOWRATEWASTEWATERZXHMEK.1CONTACTCOOUNQ2NONCONTBCTCOOLINQ3PROCESS4SANITARY5STORMWATERE>>LANDAPPLICATIONRAlEF>>lYPEOFHASTKHATKRDISCHARGEGeDISCHtRGESCIHlIE(YEARLYAVERAGE)H>>DISCHARGEFIENRATEIN>~~LJIR>>DAY,IN>>/WK>>~~'wIOURS/DAYlOTALYEARLYDAILYHINIttHDAILYSWINII~25:0,~00WIT1CCCE~3~3WASTBIATKRTYPECODE~3~51MQY2MQD3QPDITEM2WATERTREATMENTADDITIVESJeHIXIIEPIDESIGNDISCHijRGEFUNRATE<AeISYOUUSEWAlKRTREATISEAEOITIVESTOTRFATYNRDI~(IFtOCNTIIAKTOITBI3)Bet&%FWCTION>>AtOCIKIIICALCPASITINOFTIIESEAISITIVES>>DESIGNCeHit%AIOAEORKSSOFHAIAFACTIRERSOFTIESEAISITIVES>>IelIENXIMPlDISCHIIRGEFlOtRATETOBEAUMRIZEDIHPEBIIT>>WlGXK1MQ/I2UQ/ID>>EXPECTEDDISCHARGECCtCKIIIRATIOHCFAEOITIVES>>AEOITIVEIU%ACOITIVEIU%AISITIVEHA%EeDOVIXITREATTIEDISCHARGETORBOVEAISITIVES?FeHIATISTHERBOVALEFFICIBICYNDDIKHARGEFRECEEIICY?HINIMIIWITSAVERAGEWITSHAXIISPIWITSCQECOCKMs~LJg~LJLJI~LJI~LJLJ'LJ'LJAID!TIVEHA%AISITIVENA%AEOITIVEtWEtRS>>/DAYDAYS/WK>>G.ASAHATTACttEHTTOTHISAPPLICATINf%0VIOESPECIFICMPH%.IANORAOUATICTOXICOUXIICALDATACRREFB\BICEWHIOIAREAVAILAREANDINRRIATINCNTHERATECFDKGRAOATINOFTIEPA0RCGFCREACHAISITIVE>>31 INSTRUCTIONSFORCOMPI.ETINGSECTIONIIITEMSIANO2tThisformrequiresInformationonthetacility'sdischargelocation,dischargeschedule,volumetlowrateandvotertreatmentadditives.ENTERTHEPERMITIAP(8ERINTHEBOXATTHETOPOFTHISFORM.THEPERMITINM8ERCANBEFOUNDONTHEFRONTPAGEOFYOUREXPIRINGPERMIT.IfthisIsanerornotpreviouslypermittedfacility,thenleaveblankandanumbervillbeassigned.EntertheoutfallnmberInspaceprovidedtoreachpageofSectionII.ForeachIndividualdischargepointaseparatesetofSectionIIformsmustbefilledovt.ITEMIDISCHARGELOCATIONSCHEDULEANOFLOHRATESA.Enterthelocationofdischarge,thisshouldIncludeqvarter-quartersection,quartersectIon,section~town,sndrange.B.Listnameofreceivingwater(ifsurfacevoterdischarge).C.IndlCntewhetherfOCllltydlSChargeSOnOSenSOnalbnSIS.O.Ifyes,listdischargeperiods.E.ProIdethelandapplicationratesusedorexpectedtobeusedIntermsofInchesperhour,hoursperdoy,nndInchesperweek.F~Indicatethetypeofwastewatertobedlschnrgedfranthisoutfall.RefertothewasterstertypecodegivenInthelettmngin.Morethanonecodemaybeapplicable.G~ProvidetheaveragenvnberofhoursperdayInwhichthefacilitydischargestreatedwastevnterondthetotalnumberofdaysperyearInrhiChthedischargeoccurs.H.Providecurrent(frantheInstl2months)ot'xpectedflowratesssrequested.RefertounitcodeqlvenInthelettmarginfortheappropriateflowunits.MGY-milliongallonsperyear;MGD-milliongallonsperdoyiGPD-gallonsperday.I.Providethemaximumdischargeflowratewhichyouwanttohaveauthorizedwithinthepermit.NOTE:ForNPDESpermitsonly,theuseotsuchstlowrotevillnotploceanactuallimitrestrictionontheflowbutvillbetheflowroteusedtodevelopeffluentlimits.Also,whentheMonthlyoperatingReportsarerevie~edbyccmpllsncestaffIt<<IIIhelpthentodetermineifnnynerorincreasedusesmighthaveoccurredstthetaclllty.J.Providethedesignflorforthisspecificouttslldischarge(e.g.botchtreatmentsystemflow,packagedtreatmentsystemtlo,orsaneotherfinitetreatmentsystemflow)~ITEM2MATERTREATMENTADOITIVESA.Indicate~netherdischargeIstreatedvlthconditioners,inhibitors,ormlcrobloclde.Ifnot,continuetoItemS.B.Givenome,function,sndchemicalcompositionofadditivesused.C.Givenameandaddressotthemnnutscturer(s)oftheadditivesused.O.IndicateexpectedmlnlmNn,sverngeandmaximumdischargeconcentrationsoftheadditive(s)forthisdischarge.E.Indicate~batheryoutreatthedischargetoremovetheadditive(s)beforedischargeofwastewater.F.,Indicatetheremovaleftlclencyofeachadditive{remthevastcwsterandthedischargetrequencyoteachadditivetothesurfacevoterorgroundwater.G,NOTE:ItIsTheresponsibilityoftheapplicanttosupplytheproductInformationasrequestedIn'hisItem4.InformationrequestedbutnotsuppliedmsyresultIntheapplicationbeingreturnedtotheapplicanttorcompletion.32 SEEINSTRUCTIONSONREVERSESIDE-SECTtONIIPERMIT~Ivil0005827NUMBERA~NPKOFPROCESSCONIRIBUTINGTOTHEDISCHARGETHOROUGHTHISOUTFAILAttOSICCODEBePRXESSSCHGXAE(YEARLYAVERAGE)*~N~ATRANSDECKDRN4911PROCESSSTREAMSCONTRIBUTINGTOOUTFALLDISCIIARGEt/94/tOs0CCCLCePROCESSHASTEHAT8IFUX4RATEDePROCESSPRODUCTIONRATETOTAI.YEARLYDAILYMINIMADAILYMAXIM'~212000~2WITSlTIME~LJJlHIL'Uc5HKTPOUNDS2GALLONS3CUBICYARDS4TONS5MGY6MGD7GPDttt4/tOcv0AeNAtEOFPROCESSCXIIIBUTIt6TOTIEDISCHARGETlFOIGHTHISOUTFALL9%SICCCÃBePROCESSSCIETXLE(YEARLYAVERAGE)**CeIROCESSHASTEHATERFLOWRATE**DePROCESSPRODUCTIONRATEAeNA%OFPROCESSCONTRIBUTINGTOTIEDISCNRGETIROXIHTHISOUIFAILAteSICGXEBePROCESSSCtHXXE(YEARLYAVERAGE)**AC.PROCESSQSEHteTERFlatRATE*4'*/esse/sev~seve/vsesTOTAI.YEARLYDAILYMINItXT4DAILYtVNItTT4WITSJ'TIFEESELOILTK~4911esses/sev~srs/vsesTOTALYEARLYDAILYMINWHDAILYNXIltNDIESELSUMPS4911HOUR2DAY3WEEK4MONTH5YEARDePROCESSPRODICTICNRATE***AeNA%OFPROCESSCOtnRIBUTit4TDTIEDISCHARGEAN)SICOXEB~PROCESSSCIEIXXE(YEARLYAVERAGE)PROCESSHASTEtliTERPIONRATED.PROCESSPIOXXTIONRATEAeNA%OFPROCESSCONTRIBUTII6TOT%DISCBUIGEITttXXBTHISOUIFALLANDSICOXEBePRXESSSCIEDIXE(YEARI.YAVERAGE)CePROCESSHASTEttATERFUJIRATEDePROCESSPRODUCTIONRATETOTALYEARLYDAILYMINIISTIDAILYtVNIt994TOTALYEARLYDAlLYMIHIISTIDAILYMAXINBWITS/TIMEWITCCOEWITSMIMEWITCODEUNITS/TIMEPrimarilybasedonrainfallfrequencyandduration.Delugetestingwouldbe3-30min/dayfornomorethan10days.**EDGsumpdischargesvolumesareinsignificant.***Noknowndischarges33 INSTRUCTIONSFORCOMPLETINGSECTIONIIITEM3Trlstormrequiresinformationontheprocessstreams<<hlehcontrlbvtetothisdischarge.ENTERTHEPERMITNWBERINTHEBOXATTHETOPOFTHISFORM.THEPERMITNISIBERCANBEFOUNOONTHEFRONTPAGEOFYOUREXPIRINGPERMIT.\fthisIsanewornotpreviouslypermittedfacility,thenleaveblankandanumber<<illbeassigned.EnteroutfnlInvmoerlnsonceprovidedtoreachpageotSectionII.ForeachIndividualdischargeointnseparatesetcfSectionIIforr>>smustbefilledout.ITEM3PROCESSSTREAMSCONTRIBUTINGTOOISCHARGErFOREACHSEPARATEPROCESSPROVIOETHECOLL(PINGINFORMATIONA.Enterthenomeoftheprocesswhichcontributestothisdischarge.AlsoprovidetheproperSICcode.B.IndicatetneyearlyaverageprocessscheduleInhoursperdoyonddays>>per-year.C~providetheprocesswastewaterflowrateinformationasrequestedbasedonyourinstI2monthsofoperations.Refertounitcodegivenintheleftmarginfortheappropriateflowunits.O.ProcessProductionRoteCertainpermitItm/totlonsmaybebasedonproductionrates.Theproductionratesusedtodeterminepermitlimitsshallberepresentedbyareasonnblemeasureofactualproductionofthefacility,suchastheproductionduringthehighmonthofthepreviousyear,orthemonthlynveroqeforthehighestofthepreviousfiveyears,orotherreasonablemeasurensstatedinapplicableU.S.E.P.A.categoricalrulesandregulations.Fornewsourcesornewdlschargers,actunlproductionshellbeestlmotedusingprojectedproduction.RecordyourproductionrateslnthetermsnndunitsusedIntheapplicableU.S.E.P.A.categoricalrulesandregulationsforyourtypeotfacility,34 SEEINSTRUCTIONSONREVERSESIDESECT(ONIIPERMIT~MT0005827NUMBERJEM4GROUNDWATERDISCHARGEINFORMATIONA.ISTHEDISCHARGEFROMTHISOUIFALLDIRECIEDTOlHEGRCNIDORGROIWDtATERSZ(IFtCI>>CCttTIIAETOITBIP)BeHASAHYDROGEOUXIICALSTUDYORITSEQUIVALENTBEENPERFORtKXIORISTHEREBIFFICIENTCURRENI'YCROGEOLOGICALINFORMATIONAVAILABLEASREQUIREDBYTIEMATERR~CCttIISSIONPART22GRONIDtATERRULE/OFAISUST14>>1%9R>>5ZS>>Z?07(PAGEILI)FORlHISEXISTI%ORPROPOSEDDISCHARGE!IFYESATTADIACCPYOFTHEREPCRT>>CeAREYOURBXKSTIMIANEXPPTICNFRCMSIKHITTII6AHYIIIOGEOUXiICALREPORTIXKIERRIAER>>X5>>22F(Q(PAGEt15)CRFRCMGROL59IATKRMGNITORIgiIIEQUJREMENTSLIBERRIAERe25>>(5)(PAGEOFTIEPART22BILES>>IFYESATTACHCOQttENISAN)EXPLANATIONTODEIDNSTRATETHATYIXRDISCHARGEICtIDQUALIFYFCRANEXEtPION>>DeAREYOUREQLKSTI%AVARIANCEFIOIRULE323>>2205(PAGE5)(NXIDEGRADATICN)OFTHEHATERREQXRCESCCt%ISSIONPARTZi?~TERRIIESZIFYES>>ATTACHSUCHDOCU'ANTSASNECESSARYTODEMtINSTRATKTIENEEDFORAVARIANCEINTERMSOFTIECRITERIASPECIFIEDIN'RIDX5>>2210(PAGE+OFTHEPART2ZRULES>>EeI,ISTAlp.CIKHICALSIBSTANCESHHICHAREIHM1CHIGANSCRITICALMATERIALSREGISTERTABLEIVIPAGEII)AND/ORU>>S>>EPASPRIORIIYFIXLUTANTLISTTABIKV(PAGE7)ORANYOTIERQSSTANCESNIICHAREORMAYBOXPEINXRIOUSTOT%:DESIGNATEDUSESOFTIEG(IXNDHATKRIXITOTIEPUBLICHEALTHTHATAREDISCHARGEDOREXPECTEDTOBEDISCHARGEDTOTIERRIXtCltATERJIYTHISFACILITY>>ESTIMATETHEFINALEFFIleITCOCBIIRATIONAtORENDAILDATAINITBI7OFSECTIIXIIIINTHISBOOST>>~~YESK0Submitted12/6/91YESPgtOQYESQglNOTAPPLICABLE/BELIEVEDABSENTT%APPLICANTMAYBEREQIIREDTODOACDITICNALHASTEANALYSES>>A>>DISCHARGECHARACTKRISTICSCONCDIIRATIONPRESENT>>DATAPROVIDEDINITKM70ITEM5EXPECTEDWASTEWATERCHARAC'I>>>>lesUNiTSCODE1Mg/I2UO/I3COUNTS/100ml4S.U.5F6LBS/DAYTOC(TOTALORGANICCARBON)AtttGNIANITRIXiEN(ASH)TOTALSUSPEMKDSOLIDSTOTALPteSPHORUS(ASP)TOTALRESIRNLCttDRINEDISSOLVEDOXYGENHIH~.LJFECALCOLIFORMBACTERIA~TINE(QPPER)TKtPERATINE(KINIER)BCO5(FIVEDAYBIOCteIICALOXYGENBEMA%)COD(OeIICALCEIYGEHDEMAND)AVE>>~~LJ~~LJBeOIIKRHLSTBWKRCHIIIACIKRISTICS>>LJLJ5~5LJLJLJLJLJLJLJSAMPLEJXEF1GRAB224HOURCOMPOSITE0ILIlGREASEi<>>PCBAYtTOCLJ~LJLJ~LJLJLJ~LJLJ~LJLJ~LJREOIIREDIIFIXPIATICNRXIQRFACEHATKRDISCHARGES~Seeattachedsampleanalysis INSTRUCTIO'ISFORCCMPLETINGSECTIONIIITEMS4ANO5ThisforrtrequiresInformationonaspecificoutfalldischargingtoeitherthegroundratersorthesurface~aters.ENTERTHCPERMITNLSIBERINTHEBOXATTHETCPOFTHISFORM.THEPERMIThWBERCANBEFOUNDOt(THEFRONTPAGEOFYOUREXPIRINGpERMIT.Ifthislsane>>ornotpreviouslypermittedfeeillty,thenleaveblankandanumberwllIbeassigned.EntertheoutfallnumberinthespaceprovidedforeachpaaeofSectionII.ForeachIndividualdischarepointaseparatesetofSectionIIforms(Items4and5)mustbefIliedout.ITEM4GROUNDWATERDISCHARGEINFORMATION(00NOTIIICLUOEDEEPWELLIIUECTIONINFORMATIONINTHISITEM)A.-O.TheapplicantshalladdresseachofthesepartsIfthedischargefranthisoutfalIIstothearoundwater.ITEM5EXISTINGOREXPECTED(FORANEWDISCHARGE)WASTEWATEP.CHARACTERISTICSOFGROUNDWATERORSURFACEWATERDISCHARGE(00NOTINCLUDEWLLIN)IININHA.TheapplicantshelIreportavailabledischargedata(realdataforexistingdischargeorexpecteddataforaproposeddischarge)fortheparametersaslisted.Theseparametersshallbeaddressedforeitherasurfaceraterdischargeorasappropriateforagroundwaterdischarge.ForassistanceIndeterminingappropriateparametersagroundraterdlscharaeappIleantmaycontacttheGroundwaterDualityDivision,PermitssectionortheappropriateGroundwaterDualityDivision'sDistrictoffice.Theapplicantshallreporrthesampletypecodebestdescribingeachreportedpieceofdata.Seecodingontheleftmarginofthisform.IfthisoutfallIsasurfacewaterdischarge,theapplicantmustreportquantitativedataforeachparameteridentifiedbaneely",I~e9d"eb'e~.bbeeettbebbtdbydeettlbI,tlbbdbdbttt<<etttbl~ebllebtl8.IfdataIsavailableforotherparametersnotlistedaboveInA.orotherpartsofthisapplicationtheapplicantshouldreportthatdataintheblankspacesprovidedInthispart.I'OTES:I.UnitcodesforparmretersreportedInpartsAand8canbefoundontheletthandsideofthisfotta.2.GrabsampleshallbeusedtoanalyzeforpH,temperature,tote)phenols,residualchlorine,oilandgrease.andfecalcoliformInasurfacewaterdischargeunlessotherfrequency-sampletypeanalysesareavailable.SeeGlossarY(page48)fordefinitionofgrabsample.24-hourcompositesamplesshallbeusedtoanalyzeforTotalB005,ccD,Toc,AmnonlaNitrogen,andTotalSuspendedSolidsInasurface~aterdischargeunlessotherfrequency>>sampletypeanalysesareavailable.SeeGlossary(page4B)fordefinitionofcompositesample.4.REpoRTING0FINTAKEDATA.Youarenotrequiredtoreport'unlessyouwishtodemonstrateyourel)glbllltyforametreffluentIimltatiOnfarOneOrmOrepOllutantS,thatIS,aneffluentllmltatlOnadjuStedbySubtraCtlngtheaveragelevelofthepollutant(s)presentInyourIntakewater.NPOESregulationsallownetlimitationsonlyIncertaincircumstances.Todemonstrateyoureligibility,reporttheaverageoftheresultsofanalysesonyourIntakewater(lfyourrateristreatedbeforeuse,testthewaterafteritIstreated),andattachaseparatesheetcontainingthefolloringforeacnpollutant:(a)AstatementthattheIntake~aterIsdrawnfromthebodyofwaterintowhichthedischargeIsmade.(Otherrlsebyouarenoteligiblefornetlimitations.)(b)AstatementoftheextenttowhichthelevelofthepollutantIsreducedbytreatmentofyourwastewater.(Yourlimitationsrillbeadjustedonlytotheextentthatthepollutantisnotremoved.)(c)'whenapplicable(forexample,whenthepollutantrepresentsaclassofcompounds),ademonstrationoftheextenttowhichthepollutantsIntheIntakeveryphysically,chemically,orbiologicallyfromthepollutantscontainedInyourdischarge.(YourlimitationswlIIbeadjustedonlytotheextentthattheintakepollutantsdonotvaryfrowthedischargedpollutants.)5.IfyouhavetwoormoresubstantiallyIndentlcaloutfalls,youmayrequestpermissionfranyourpermittingauthoritvtosampleandanalyzeonlyoneoutfalIandsubmittheresultsoftheanalysisforothersubstantiallyIdenticaloutfalls.Ifyourreauestisgrantedbythepermittlnaauthority,onaseparatesheetattachedtotheapplicationformIdentifywhichoutfallyoudidtest,anddescribewhytheoutfalls>>hichyoudidnottestareSubStantlallyldentlCaltOtheOutfallwhlChyOudidteSt.36 .>L.H<b~On]gJ$aarCORPORATIONLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(4'12)747-2684January11,1994ReportNo.:00018818SectionAPage2CLIEHTNAME:ADDRESS:ATTENTION:INDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGEMAN,MI49106-MR.ROLAHDBEENHUSCLIENTNO:06630018WORKORDERHO:55830VEHOORHO:05411000CarbonCopy:SAMPLEID:OIL/WATERSEPARATORHUSSAMPLENO:P0258839P.O.NO.:69034-040-3NDATESAMPLED:28-OEC-93DATERECEIVED:29.DEC.93APPROVEDBY:Kieda,ChuckTESTLNCODEOETERMINATIOHRESULTUNITS1G122W311064168051490PCBANALYSISPCB-1016PCB-1221PCB-1232PCB-1242PCB-1248PCB-1254PCB-1260Carbon,Organic-NonpurgeableOilandGrease,GravimetricpH<0.05ug/L<0.05ug/L<0.05ug/L<0.05ug/L<0.05ug/L<1.0ug/L<1.0ug/L6mg/L3mg/L7.4COMMENTS: SEEINSTRUCTIONSONREVERSESIDESECTIONIIPERMIT~>>IVIzppp5827NUMBERiEM6PRIORITYPOLLUTANTSANDADDITIONALINFORMATIONFORSURFACEWATERDISCHARGEONLYREQUESTEDINFCRt47ICH~~ADCRESSED~QRFACEHATERDISCHARGERS.IDIEtNEWUSEDISCHUIGERS2IIIILPROVIDEEXPECTEDVALIESFORTHECUAMflTATIVEANDQUALITATIVEINFCRHATIONREOIKSTKDBEUWeA.ISTHISFACILllYAPRItVVIYINDUS1RY?(REFERTOTABLEIAPar<gJ)(IFtOeGO70E)(IFY5GOTOB)BeIMIICATElYPEOFPRIIVUIYINDUSTRYASLISTEDINTABlEIAPAGoKQ,(CONTIN%WITHC.)C.DOES1HI5CUIFALLDISCHARGECctlTAINANYPROCESSWASTEWATER?(IFNOeGOTOE)(IFYKSeGO70D)DoINDICATEHlICHGC/tmFRACflONSFttSTBETESTEDFCR~(REFERTQTABLEIaPate9DKIIE!FOREACHGC/HSFRACTIONOIECKKDeKAOISPECIFICORGANICTOXICPOLunaNTHITHINEacHFRACTIQNt55IBEAMALYIKDFOR(5EETABLEIIAPAGE92,IMADDITIQNeALLFRIARYIMXISTRYAPPLICANTSWITHAPROCESSWASTEWATERDISCHARGE'~PROVIDEQUAtnITATIVEDATAFOREACHTOXICPOLLUTAMTINTAKEIIIAPA%Q)eRECORDALLDATAONFCRHSPROVIDED(ITKH7)INTHISBQ)KLETe(CctnttUEHllHEKBELCH)~NAVOLATILEQBASE/NElm4LDcelePESTICIDEAnalysisperJ.B.BeauboeufTargetPermitEffluentLimitsYESMOSTME'LECPWRXYESNOEeIF~QRFACEHATERDISCHARGEAPPLICAtn(PRIMARYORSKCOGI4RYIMIXISTRY)eREGARDLE%OFTHElYPEOFDISCHUIGKeKMHSORHASREASONTQBELIEVETHATAHYPOLLUTANTLISTEDINTAREIIAANDIVAPAGES~ISDISCHARGEDFIKttANYQITFAILeltEQIAtntTATIVEDATAISgif,BEPROVIDEDeRECCRDAILDATAONFORtSPROVIDED(ITKH7)IN1HISBOOKLETeFeIFANYQRFACEHATERDISOIARGKAPPLICAMT(PRIMARYORSECONDLYIMXISTRY)eREGARDLESSOFlYPEOFDISCIIARGKeKMXtsORHASREASONTOBELIEVEANYPOLLUTANTSLISTEDINTABLEVAPAGE+AREDISCHARCMFRCHANYQnFAILTIEAPPLICANTLtd(IDESCRIBEREASONSFORTIEPQLlnaMTBEINGPRESenAMIPROVIDEAMYAVAILABLEQIAMTITATIVEDATAeRECORDALLDATAONFOIVtsPROVIDED(ITKH7)INTHISBCOKLETeterAPPLICABLE/BELIEVEDABSENtN/ADPRESENT/DATAISATTACHEDQMOTAPPLICABLE/BELIEVEDassenN/APRESENT/DATAI5ATTACHEDDGeAILSIRFACEHATERDISCHARGEAPPLICANIS(PRIMARYAMlSECCN04RYIMXITRIES)QR~actIRKS24.)-TRtosfxtfPtEMDIYAcET!cAclD(2,4,5-7):-.4,~7RtoIuwoPIEMIKY)PRQPAMQICAOID(SILYKx,Z,4,5,TP)TRI04xRQPtERx.(TcMPJ0RHExacMJIRQPtEIEtHCPSJ(ALLDATAFcRTIEABOVEMISTBEGENERATEDUSINGSTAMFORDANALYTICALCALIIRATICNPROCBXRES)QRKREISORHASREASCN1QBELIEVETHATTCKQISCRtlkYBEPRESBITIN7%IRDISOIARGEe~REPORTtXIALITATIVEIVITAGENERATED%IOIUSEDASCREENINGPROCHXREtOTCALIBRATEDHllHAt4LYTICALSTAleatmeFOR2De78e-TEIIIAOLORODI~DIOXIN(TCKD)eREQRDAILDATAQtFOttsPROVIDED(tlttt5INTHISBOOKLETeJeIFTtEQRFACEHATERDISCHARGEAPPLICAtnKMX6CRHASREASONlQBELIEVETHATBIQDGICAI,TOXICITYTESTSWEREHADEINTHEtasrTIREK(5)YEARSONAHYQFTIEAPPLICANT5Dl~ORCNARECEIVIMGHATERINREIATIONlQADISOIARGEePROVIDETHISltFORHATIONASAMATTAOFENTTQTHISAPPLICATIOMeKeIFACOtnRACTLABORATORYORCQIQLTIMGFIRNPERFCR%DPetrOFTIEAMAYSESRECUIREDBYTHISAPPLICATIOMePROVIDETIEt4V%AHDAICRESSOFEAOtLABORATTRYORFlirtAM)ttEANtLYSESPERFCR%DASAMATTAOtEtnOFTHISAPPLICATIONeLeDOYCUDISCHARGEANYOTIERTOXICORIMJIRIOUSCteIICALQBSTAHCESNOTLISTEDINTABLESIVPAGEttAMIIIATtRQFtlVAPA4S~~,IFYESTANIDEtntNYTIEOKttICALQISTANCESANDESTIHATE7%FINALEFFURITCctK:em47ICNS,SlstttrTHISIHFORQTIOHASAMATTAOPEtnTQTHISAPPLICATION>wrAPPLICABLE/BELIEVEDallenN/AQPRESENT/DATAIsATTAOEDQterAPPLICABLEN/AQAPPLICABLE/SKEATTACHEDQtOTAPPLICABLEpgAPPLICABLK/SEEATTACHEDMOTAPPLICABLE0APPLICABLK/sEEATTADIKDN/A37 IHSTRUCTIQNSFORCCMPLETINGSECTIONIIITEM6ThisformrequiresInformationonaspecificoutfalldischargingtothesurfacewaters.ENTERTHEPEIB(ITNUMBERINTHEBOXATTHETCPOFTHISFCRM.THEPERMITN(P(BERCANBEFOUNOONTHEFRONTPAGEOFYOUREXPIRINGpERMIT.IfthisIsanewornotpreviouslypermittedfacility,thenleaveblankandanumber<<IIIbeosslqned.EntertheoutfallnumberinthespaceprovidedforeachpageofSectionII.ForeachIndividualdlscharoepointoseparatesetofSectionIl,Item6formsmustbef1liedout.ITEM6PRIORITYPOLLUTANTSANOAOOITIONALINFO(a(ATIONNOTE:IfyOuhaVetwOOrmOreSubatantlallyIndentlCalOutfallS,yOumayrequeStpermlSSIOnfrCmyOurpermittingauthOrltytOsomp(eandanalyzeonlyoneoutfallandsubmittheresultsoftheanalysisforothersubstantiallyIdenticaloutfalls.IfyourrequestIsgrantedbythepermittingauthority,onaseparatesheetattachedtotheapplicationformIdentifywhichoutfallyoudidtest,anddescribewhytheoutfallswhichyoudidnottestaresubstantiallyident)coltotheoutfallwhlChyOudidteSt.NOTE:A.-C.ondE.-J.O.40CFRPortI22.2)(g)(8),Friday,AprilI,l983,providesforaSmallBusinessExemptionfromthereportingofquantitativedatafororgonlctoxicpollutantsandtoxicpollutantsasrequiredbyPart122.2I(g)(7)(il)(A)orI22.21(g)(7)(ill)(A).ThesepartsareselfwxplonatoryanddonotrequirefurtherInstructions,SimplygothrougheachpartanddoasIndicated.SeveralIndustrialcategoriesandsubcategorieshovebeenexemptedfransubmittingdotsoncertainGC/MSFractions(40CFRPertl22,Vol.48,No.64,Friday,AprilI,l983,NotesI,2,ond3).ReviewthefollowinglisttodeterminewhetheryourfacilityqualifiestobeexemptfromreportingGC/MS(GasChrcmatographY/MossSpectroscopy)Fractions.GC/MSFractionTestingandReportingExemptionsTextileMIIIsIndust-AllfourGC/MSorganicfractIonsIntheGreigeMIIIsSubcategory.-PesticidefractionInoilothersvbportsofthisIndustry.OreMlnlnandDress(Indust-Volatile,base/neutral,andpesticidefractionsIntheBoseandPreclovsMetalsSubcategory.-AllfourGC/MSorganicfractionslnallothersubcategoriesofthisIndustry.GumandMoodChem(colsIndustr-PesticidefractionIntheTallOilRosinSubcategoryandtheRosinBasedOerlvatlvesSubcategory.Pesticideandbase/neutralfractionsIn~IIothersubcategoriesofthisIndustry.PvlandPaperIndust-PesticidefractionInPapergradeSulfitesubcateqorles(subpartsJandU).-Base/neutralandpesticidefractionsinOelnkSubpartQ,OlssolvlnqKraftSubpartF,andPaperboardfromMastePaperSubpartE.-Volatile,base/neutral,pesticidefracttonsIntheBCTBleachedKraftSubpartH,Sam(-chemicalSubparts8andC,andNonlntegrated.F(nePapersSubpartR.-Acid,base/neutral,andpesticidefractions(nFineBleachedKraftSubpartI,DissolvingSulfitePulpSubpartK,Ground-woodFinePapersSubpart0,HarketbleachedKraftSubpartC,TissuefromMastepaperSubpartT,andNonlntegratedTissuePapersSubpartS.SteamElectricPowerPlantIndustr-Base/neutralfractionIntheOnce-ThroughCoolingMater,FlyAsh,andBottomAshTransportMaterprocesswastestreams.38 SEEINSTRUCTIONSONREVERSESIDESECTIONIIPERMIT~Ml0005827CRmCALMATERIALSTOXICPOLLUTANTSA.USETHISDATASHEETIORECORDINRXVIATIONASRECJIREDIN:(DECKAPPROPRIATEBOXIORtttICHINRÃHATICNTHISDl>>TASHEEfREPRESBffs>>)Q1>>SECflOM1riIIEIIM>>GRIJ&AIERDISCHARGEIMFCVIATION(PJGE33)O2>>SECTICNII>>ITEN6>>PRICRIIYRXIUTAMTSIHSNFACEIIAIERDISCHIVttK(PAGE37)O3.B.BEUXI:CRITICALHAIERIALS(TABLEIV)INSIXIFACEHATERDISaaeK(PAX39)HAZARDOUSSUBSTANCESINDISCHARGEB>>LlsTAMvcRITlcALHATERIAL(TABLEIvPAGE6)MDTADDREssEDINsEcTIcttIIIIEH6PRIDRllYPOLUJTAMTSINICHYCJIOXXIORHAVEREASONTOBELIEVETOBEPRESENTINIIEDISCHUIGE>>SEEREVERSESIDEOF'THISPAGEFORFIJIIIERDIRECTICNS>>zAPPLICABIE(SEEBEUXI)A>>NVKOFCRITICALHATERIALCRPRIORITYPOLUJTAMTFI>>B>>AVERAGECXCEIIIRATIONJQPRElYPEJ¹OFJNALYSESC>>HAXPSltCXCENIRATICNAIOHASSWITCCKSAWLElYPEOFANALYSESLJWITCXKWITCODEA>>MJt%OFCRITICALHATERIALCRPRIORllYRXLUTANTwc>>IB.AVERAGECXCENIRATICIJQFFLETYPES¹OFANALYSESC>>HAXPeltCNCEIIIRATIONAJOHASSNIITCXKSWEETYPEOFANALYSES~.LLLJLJWITCXKWITCXEUNITSCODE1My/IUy/I3S/DAYKQ/DAYGRAB224HR.COMRA>>NJJ%OFCRITICALHAIERIALCRPRICRtlYPOLUJTANTwnB,AVBIAGECXCBIIRATIIXIJSWLEIYPE18OFANALYSESIC>>HAXPMICOICEIIIRATICNAIOHASSA>>Mt%CFCRITICALHAIERIJI.CRPRIORllYRJUJJTANTB>>AVERJGECDICEIIIRATIONJQtPLEIYPEJ¹OFANALYSESCHAXPtltCNCEIIIRATIIXIAJOHASSA>>NA%OFCRITICALHATERIALCRPRIORITYAXLJJTAMTB>>AVERAGECXCENlltATIIXIJQfREIYPEJ¹OFANALYSESIC>>HAXPSNCXCBIIRATIONAJOHASSWITCOEQIVLETYPEIKANALYSESINWITCXKWITCXKQPAETYPEINITCODEtillT.CXKLJ~~~LJWlrCCKaVezTYPE¹OFANALYSESLJINITCOEINITCODEA>>HAIKOFCRITICALHATERIALCRPRICRIIYPOLUJfANTweBAVERAGECNCENIRATIOtUQ%LETYPEJ¹OFANALYSESC.HAXPSPICOCBIIRATICNAJOMSSWITCXKQJFIKTYPEOFANALYSESLJWITCODEINITCOIKA>>NJPKOFCIITICALHAIERIJLCtPRIORIIYRXLllfAMTwI>>',AVBIJGECXCBAltATIOIJALEIYIEI¹OFANALYSESIC>>HAXIISPICXCENIIIATICNAJOHASSA.NVKOFCRITICALHAIERIALORPRIORllYRXUJTAMTweB>>AVERAGECXXXJIIRATIONJSAPFLETYPEJ¹OFAlWYSESC,HAXPSHCaCIIIIRAIICttAIOHASSIPIITCCKQtl>>LElYPE¹OFANALYSESLJINITCXKINICODELJINIICXK~TYPEOFANALYSESLJWlrCXKWITCODELJ~~~LJADDITreuLPJGESoFTHrsIIEH7AREAIIActEDPORIIERESTDFIIKcRITrcALClYEsHAIERIALSJva/CtPRrarIYPCLIJJTJttfsRECIJIREDTOBERERXIIED,EJO39 INSTRUCTIONSFORCI7ZPLETINGSECTIONIIITEN7ThistormIstobeusedbybothsurfaceandgroundvaterapplicantstorecordinformationonanyMichigancriticalmaterial,E.P.A.prioritypollutant,orhazardoussubstanceInvhichthisapplicationrequiresdatatobeprovided.ThisvouldIncludeanychemicalsubstancefromtheHlchlganCriticalMaterialsRegisterITableIV),theE.p.A.priorityPollutantListingITableV),orTablesIIh-VhwhichIistsOrganicToxicPollutants,OtherToxicPollutants,ConventionalandNonconventionalPollutantsandHazardousSubstances.ITEN7CRITIChLMhTERIALSPRIORITYPOLLUTANTSAND/ORHAZARDOUSSU8STANCESINTHEDISCHARGEMaterialI23...8A.ListthenameofthechemicalsubstanceIcrltlcalmaterlal,prioritypollutant,orhazardoussubstance)tronTablesIV."andIIA-VAasreoulredIntheboxvhlchyoucheckedInA.I-3.above.Entereachchemicalsubstance'sparameternumberaslistedInTablesIV,VandIIA-VAIfprovided.8.ProvidetheaverageconcentrationofthechemicalsubstancenamedInA.IndicatethesampletypeusedandthenumberofanalysesmadetoprovidetheccncentratlondataforthechemicalsubstancenmnedInA.nC.ProvidethemaximusconcentrationanddeterminethemassloadingofthechemicalsubstancenaeedInA.I~Ifonlyoneanalysiswasmadeforachealcalsubstancethenrecordthatdataasamaximusvalue.Itmorethenoneanalysishasbeenmadeforachemicalsubstancethenprovideanaveragevalueofthoseanalysesandthemaxlmmavalue~2.ThisSectionII,Iten7,DataSheetprovidesspacetorrecordingdatafor8chemicalsubstances(Materlalsl~Additionalspaceforrecordingofdatatormorethan8MaterialscanbemadebymakingcopiesofthisItem7DataSheetasneeded.ItIsalsoImportanttouseaseparatesetofDataSheetsforeachapplicablereportingreaulrmnentaslistedInA.l-3.andtoreachoutfall.3~Refertotheleftmargintorthecodenumberrepresentingthe'smapl~typeusedandtheappropriateunitcodes.40 VOLATILEORGANICANALYSISRESULTSGC/HALLANALYSESUSINGEPAMETHOD8010linmIID:TRANATHBAINDII2-DEDaeAnalzed:05-JAN-94MatrixWATERAnalticalBatch4:122093-801020-0-3LALmIID:L1-7DRiv:2-DEDilutionFactor:1QCBatchID:122093-801020-0-3BCIVIBFBSrroRvr9976Limi65-12560-120ConstituentDihlriflrmhnhlrmhnVinIchlorideBromomethanehlrhnTrihlrflrmhne11-DichloroetheneMethlenechloridern-12-Dihirhn11-DihlrhnChloroform111-Trichloroethanernrhlrid12-DihlrhnTrichloroetheneTCE12-DichlororoaneBrmihlrmhn2-hlrhlvinIhrcis-13-Dichlororoenetrans-13-Dichlororoene112-TrihlrhnTrhirhnPEDibromochloromethaneChlorobenzeneBrmfrm1122Trhlrhan13-Dichlorobenzene14-Dichlorobenzene12-DichlorobenzeneConcentration(yg/L)<0.50<3<6<4.5<0.5<0.5<2ReportingDetectionLimit/L0.50.50.5DataQualifieris)LOCKHEEDANALYTICALSERVICESh7 VOLATILEORGANICANALYSISRESULTSGC/PIDANALYSESUSINGIVIETHOD8020linmIID:TRANATHBAINDII:2-DEDateAnalzed:04-JAN-94Matrix:WATERAnalticalBatchII:122093-801020-0-3LALmlID:L1-7DRiv:2-DEC-DilutionFactor:1QCBatchID:122093-801020-0-3TFTBFBrrRvr8989QLimis70-12075-120BenzeneTIneConstituentConcentrationIL<0.5ReportingDetectionLimitIL0.5DataQualifiershlrnnEthIBenzenem-XIene-XIn1-Dihlrnn14-Dichlorobenzene12-Dichlorobenzene<2<2LOCKHEEDANALYTICALSERVICES SEIVIIVOLATILEORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270P1f2linmIID:TRAN.ATHBAINDateCollected:28-DEC-93Matrix:WATERAnIiIBh¹':1114-27-8QCBatchID:8270-SEMIVOLATILES-3964LALmIID:L1-2DateReceived:29-DEC-93DilutionFactor:1DExr:4-AN-4DateAnalzed:11-JAN-942-FluorohenolPhenol-d,Nitrobenzene-d,RROATEREVERY382859Limi21-10010-9435-1142-FluorobihenI24-TribromhnIp-Terphenyl-d628443-1161-1233-141PhenolnInConcentrationLReportingDetectionLimitLDalifirbis2-ChloroethIether2-hlrhnI1-Dihlrnzn14-DichlorobenzeneBenzIalcohol12Dihlrnzn2-MhIhnIbis2-ChloroisoroIether4-MethIhenolN-Nir-Di-n-rIminHxhlrhnNitrobenzeneIsohorone2-NirhnI24-DimhIhnIBenzoicacidbis2-hloroethoxmehane24-DihlrhnI14TrihlrnznNahthalene4-ChloroanilineHxhlrin4-hlr--mhlhnl2-MethInahthaleneHexachloroccloentadiene<5555LOCKHEEDANALYTICALSERVICESU5 SEMIVOLATILEORGANICANALYSISRESULTSFORGC/IVISANALYSESUSINGIVIETHOD8270ClientSamleID:TRANS.CATCHBASINLALSamleID:L1009-29P2f2Constituent24-TrihlrhnI24-TrihlrhnI2-Chloronahthalene2-NitroanilineDimhIhhIAnhhln26-Dinitrotoluene3-NitroanilineAnhhn24-DinirhnI4-NitrohenolDibenzofuran24-DinirInDihIhh(4-ChlorohenI-henletherFluorene4-Nirnilin4-Dinir-2-mhIhnIN-Nitrosodihenlamine4-BromohenI-henletherHxhlrnznPnhlrhnlPhenanthreneAnthraceneDi-n-IhhIFlrnhnPreneButIbenzIhthalate'-DihlrnziinBnznhrnChrsenebis2-EthIhexIhthalateDi-n-IhhI8nzflrnhnBenzokfluoranheneBenzoareneInn12-rnDinzhnhrnBenzohierleneCarbazoleConcentration(IL)<28<28<2<28<2<2<2<22280ReportingDetectionLimit(IL)28282822DataQualifier(s)EBLOCKHEEDANALYTICALSERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8270TENTATIVELYIDENTIFIEDCOMPOUNDSClientSampleID:TRANS.CATCHBASINDateReceived:29-DEC-93Matrix:WATERAnalyticalBatch:011194-8270-BLALSampleID:L1009-29DateAnalyzed:114AN-94DilutionFactor:1QCBatchID:8270-SEMIVOLATILES-3964TentativelyIdentifiedCompoundHydrocarbonHydrocarbonUnknownHydrocarbonUnknownHydrocarbonUnknownHydrocarbonUnknownUnknownHydrocarbonHydrocarbonHydrocarbonHydrocarbonUnknownHydrocarbonHydrocarbonHydrocarbonHydrocarbonHydrocarbonEstimatedConcentration(pg/L)1020102010301010303030201010,RetentionTime(minutes)14.5015.0015.8316.7517.5817.7918.0118.4019.1719.2519.4219.9621.4321.5122.3222.9524.1724.5425.4326.65DataQualifier(s)LOCKHEEDANALYTICALSERVICES7uI SEIVllVOLATILEORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270linmIID:TRAN.ATHBAINDIIMatrix:WATER-DAnalticalBatchII'11194-8270-BQCBatchID:8270-SEMIVOLATILES-3964LALmIID:L1-2REDRiv'-DEDiluionFactor:4DateExtracted:04-JAN-94DateAnalzed:18-JAN-94Pae1of2SURROGATERECOVERYQLimis2-FlrhnIPhenol-d,Nitrobenzene-d,2-FluorobihenI246-Tribromohenolp-Terphenyl-d,442285666767221-110-9435-11443-11610-12333-141PhnIniunConcentrationL<4ReportingDetectionLimitLDbis2-ChloroethIether2-Chlorohenol1-Dihlrnzn14DihlrnznBenzIalcohol12-Dichlorobenzene2-MhIhnIi2-hlrirIhr4-MethIhenolN-Nitroso-Di-n-rolamineHxhlrhnNirnznIsohorone2-Nitrohenol24-DimhIhnIBniibis2-Chloroethoxmethane24-Dichlorohanoi124TrihlrnnNhhln4-ChloroanilineHexachlorobutadiene4-hlr--mhlhnl2-MhInahhalnHexachloroccloentadiene<40<40<4<40<40<40<4<4<40<40<4<4<40<40<4<40<40<4<4<40<40<4<4<4040404040404040404040404040LOCKHEEDANALYTICALSERVICES SEIVIIVOLATILEORGANICANALYSISRESULTSFORGC/IVISANALYSESUSINGMETHOD8270ClientSamleID:TRANS.CATCHBASINLALSamleID:L1009-29REP2f2Constituent24-TrihirhnI24-TrihlrhnI2-Chloronahthalene2-NitroanilineDimhIhhIAnhhln26-Dinirooluene3-NitroanilineAnhhn24-DinirhnI4-NitrohenolDibenzofuran24-DinirlunDihlhhl4-ChlorohenI-henletherFluorene4-Nirnilin4-Dinir-2-mhIhnIN-Nitrosodihenlamine'-BromohenI-henletherHxhlrnnPnhirhnlPhenanthreneAnthraceneDin-IhhIFlrnhnPreneButIbenzIhthalate'-DihlrniinBnznhrnChrsenebis2-EthIhexIhthalateDi-n-IhhIBnzflrnhnBenzokfluorantheneConcentration(IL)<4<4<40<100<4<4<40<100<4<100<40<4<4<40<40<40<40<4<40<40<4<4<40<40<4<40350<4<4<40ReportingDetectionLimit(IL)4Q1004Q1001004Q4p4Q4Q40404Q4p4040404p"40DataQualifier(s)BenzoareneInn12rn<40<440DinzhnhrnBenzohierleneCarbazole<4<40<404040LOCKHEEDANALYTICALSERVICES PESTICIDEANALYSESRESULTSBYGC/ECDUSINGMETHOD8080FORCOOKNUCLEARPLANTClienSamleID:TRANSCATCHBASINDaeColleced:28-DEC-93DateExtracted:04-JAN-94Matrix:WATERAnalticalBatch4:012094-8080-A-1LALSamIeID:L1009-21DeReceived:29-JAN-94DateAnalzed:21-JAN-94DilutionFactor:1QCGrouID:8080PEST/PCBS3965SURROGATERECOVERYoTCMXDCB8540QCLimits60-15060-150A-'BHCB-BHCG-BHD-BHCConstituentConcentration/L<0.05<0.05ReportingDetectionLimit/L0.05.00.05DataQualifier(s)HEPTACHLORALDRINHEPTACHLOREPOXIDEG-CHLORDANEENDOSULFANIA-CHLORDANE44'-DDE44'-DDTDIELDRINENDRINENDOSULFANII44'-DDDENDRINALDEHYDEENDOSULFANSULFATEMETHOXYCHLORTOXAPHENEPCB-1016PCB-1221PCB-1232PCB-1242PCB-1248PCB-1254PCB-120TECHNICALCHLORDANEMIREXTCMX-tetra-chloro-meta-xyleneDCB-Deca-chloro-biphenyl<0.05<0.5<0.05<0.05<0.05<0.1<0.1<0.1<0.1<0.1<0.5<5<2<0.10.050.50.050.050.00.10.10.10.10.1<0.1LOCKHEEDANALYTICALSERVICESghVV METALSRESULTSClientSamleID:TRANS.CATCHBASINDateCollected:12-28-93Matrix:round"water:LALBatchID(s):1220imDateReceived:12-29-93POP69095-040-3N.Conitituents-AluminumAntimonArsenicBariumBeIliumBoronCadmiumChromiumCobaltCoertronLeadManesiumMananeseMercuMolbdenumNickelSeleniumSilverSodiumThalliumTinTitaniumVanadiumZinc.Method6010602060206020602060106020602060206020601060206010602074706020602060206020601060206020601060106020Concentration.{mIL)<0.20<0.060<0.010<0.20<0.005<0.20<0.005<0.010<0.060<0.0250.54<0.0031.60.059<0.0002<0.20<0.040<0.005<0.010<5.0<0.010<0.20<0.10<0.0500.15ReportingDetectionUmitlm/L)0.200.0600.0100.200.0050.200.0060.0100.0600.0250.100.0035.00.0150.00020.200.0400.0050.0105.00.0100.200.100.0500.020DataQualifieris)Date:AL.Analzed;.:-SamleID01-20-94L1009-1501-27-94L1009-1601-27-94L1009-1501-27-94L1009-1501-27-94L1009-1501-20-94L1009-1501-27-94L1009-1501-27-94L1009-1501-27-94L1009-1501-27-94L1009-1501-27-94L1009-1501-27-94L1009-1501-20-94L1009-1501-27-94L1009-1501-07-94L1009-1501-27-94L1009-1501-27-94L1009-1601-27-94L1009-1501-27-94L1009-1501-20-94L1009-1501-27-94L1009-1501-27-94L1009-1501-20-94L1009-1501-20-94L1009-1501-27-94L1009-15Comments:LOCKHEEDANALYTICALSERVICES GENERALCHEMiSTRYRESULTSClientSamleID:TRANS.CATCHBASINDateCollected:12-28-93Matrix:roundwaterLALBatchIDIs):1229imDateReceived:12-29-93PO¹69095-040-3NConstituentMethodResultReportingDetectionLimitDataQualifierlslDateAnalzedLALSamleIDFluoride,inm/LChloride,inmILNitrate-Nitroen,inmILNitrite.Nitroen,inmILSulfate,inmILAmmonia-Nitrogen,inmILTotalCyanide,inmg/L340.2300.0300.0300.0300.0350.1335.2<0.150.52<0.017<0.0124.713<0.0200.150.0160.0170.0120.0590.500.020DI1:10)01-24-94L1009-312-29-93L1009-312-29-93L1009-312-29-93L1009.312-29-93L1009-301-05-94L1009-701-03-94L1009-11Comments:LOCKHEEDANALYTICALSERVICES VOLATILEORGANICANALYSISRESULTSGC/HALLANALYSESUSINGEPAMETHOD8010linmIID:BLANKDColl'ADateAnalzed:04-JAN-94Matrix:WATERAnalticalBatch4:122093-801020-0-3LAmIID:AD17DRiv:NADilutionFactor:1QCBatchID:122093-801020-0-3BCMBFBurroaeRecover9494Limis65-12560-120ConstituentDihlriflormehnehlrmhnVinIchlorideBromomethanehlrhnTrihlrflrmhn11-DichloroetheneMethlenechloridern-12-Dihlrhn11-DihlrhnChloroform111-Trichloroethanernrhlri12-DihlrhnTrichloroetheneTCE12-DichlororoaneBromihlromehn2-hlrhlvinlhrcis-13-Dichlororoenetrans-13-Dichlororoene11-TrihlrhanTrhlrhnPEDibromochloromethaneChlorobenzeneBrmfrm1122-Trahlrohan13-Dichlorobenzene14-Dichlorobenzene12-DichlorobenzeneConcentration(yg/L)<0.50<3<6<4<0.<0.5<0.5<2ReportingDetectionLimitIL0.50.50.5DataQualifier(s)LOCKHEEDANALYTICALSERVICES VOLATILEORGANICANALYSISRESULTSGC/PIDANALYSESUSINGIVlETHOD8020linmIID:BLANKDeliee:NADateAnalzed:04-JAN-94Matrix:WATERAnalticalBatch¹:122093-801020-0-3LALmlID:AD17DRiv:NADilutionFactor:1QCBatchID:122093-801020-0-3TFTBFBrrRvr10299QCLimi70-12075-120BenzeneTInConstituentConcentration/L<0.5ReportingDetectionLimit/L0.5DataQualifiershlrnznEthIBenzenem-Xlene-XIn1-Dihlrnzn14-Dichlorobenzene12-Dichlorobenzene<2<2<2LOCKHEEDANALYTICALSERVICESt,'Z AQUEOUSMATRIXSPIKEDATASUMMARYFORVOLATILEORGANICANALYSISUSINGEPAIVIETHOD8010ClientSampleID:MATRIXSPIKE/DUPLICATEAnalyticalBatch4:.122093-801020-0-3QCBatchID:122093-801020-0-3LALSampleID:L1012-7DateAnalyzed:05-JAN-94Constituent1,1-DichloroetheneTrichloroetheneChlorobenzeneSpikeAddedlpg/L)151515SampleConcentrationtpg/L)NDNDNDIVlatrixSpikeConcentrationlyg/L)7.3014.512.6Recovery499784QCLimitsRecovery28-16735-14638-150QCLimitsConstituent1,1-DichloroetheneTrichloroetheneChlorobenzeneSpikeAddedlyg/L)151515MatrixSpikeDuplicateConcentration(pg/L)11.414.512.6Recovery769784RPD43+RPD202020Recovery28-16735-14638-150LOCKHEEDANALYTICALSERVICESIl AQUEOUSMATRIXSPIKEDATASUMMARYFORVOLATILEORGANICANALYSISUSINGEPAMETHOD8020ClientSampleID:MATRIXSPIKE/DUPLICATEAnalyticalBatch¹:122093-801020-0-3QCBatchID:122093-801020-0-3LALSampleID:L1012-7DateAnalyzed:05-JAN-94ConstituentBenzeneTolueneChlorobenzeneSpikeAdded(yg/L)151515SampleConcentration(yg/L)NDNDNDMatrixSpikeConcentration(yg/L)12.912.512.6Recovery868384QCLimitsRecovery39-15046-14855-135QCLimitsConstituentBenzeneTolueneChlorobenzeneSpikeAddedlyg/L)151515MatrixSpikeDuplicateConcentration(yg/L)12.412.012.6Recovery838084RPDRPD202020Recovery39-15046-14855-135LOCKHEEDANALYTICALSERVICES12 LCSDATASUNIMARYFORVOLATILEORGANICANALYSISUSINGEPAMETHOD8010ClientSampleID:LCSAnalyticalBatch¹:122093-801020-0-3QCBatchID:122093-801020-0-3LALSampleID:AD5177DateAnalyzed:04-JAN-94Constituent1,1-DichloroetheneTrichloroetheneChiorobenzeneSpikeAdded(yg/L)151515BlankConcentrationI/Ig/L)NDNDNDLCSConcentrationIyg/L)9.115.012.2Recovery10081QCLimitsRecovery28-16735-14638-150LOCKHEEOAIVALV7'ICALSERVICES LCSDATASUIVIMARYFORVOLATILEORGANICANALYSISUSINGEPAMETHOD8020ClientSampleID:LCSAnalyticalBatch//:122093-801020-0-3QCBatchID:122093-801020-0-3LALSampleID:AD5177DateAnalyzed:04-JAN-93ConstituentBenzeneTolueneChlorobenzeneSpikeAddedIpg/L)151515BlankConcentration(yg/L)NDNDNDLCSConcentration(/Ig/L)14.914.114.4Recovery999496QCLimitsRecovery39-15046-14855-135LOCKHEEDANALyTICALSERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260Page1of2linamIID:BLANKDateCollected:NAMatrix:WATERAnliIBh¹:114-2-F2QCBatchID:011094-8260-F2LALmleID:AD214DateReceived:N/ADateAnalzed:11-JAN-94DilinFr:1SURROGATERECOVERY12-Dihlrhn-4Tlen-84-Bromofluorobenzene1294QCLimits7-11486-115ConstituentChloromethaneVinIhlriBromomhnChloroethaneTrichlorofluoromethaneAn11-DihlrhnCarbonDisulfideMethleneChlorideran-12-DihlrohnVinIA11-Dichloroethane2-Butanonei-12-Dihlrhnhlrfrm111-TrichloroethaneCarbonTetrachloride12DihirhnBenzneTrichloroetheneTCE12-DichiororoaneBromihlromhn2ChlrhIVinIhr4-Meth1-2-entanonecis-13-DichlororoeneTolnrn-1-Dihlrrn2-Hexanone112-TrichloroethaneTetrachloroethenePCEConcentration/L<5<5<5<5<5<5<10<5<5<5<5<2<10<5<10<5<5ReportingDetectionLimit/L101010DataQualifiersLOCKHEEDANALYTICALSERVICESCqg VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260Page2of2ClientSamleID:BLANKLALSamleID:AD5214ConstituentDibromochloromethanehlrnzenEhlnznm-Xleneo-XlenernBrmfrm1122-Tetrachloroethane13-Dichlorobenzene14-Dihlrnzn12-DichlorobenzeneConcentrationIL<5<5<5<5<5ReportingDetectionLimitILDataQualifiersLOCKHEEDAIVALYTICALSERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260TENTATIVELYIDENTIFIEDCOMPOUNDSClientSampleID:BLANKDateReceived:N/AMatrix:WATERAnalyticalBatch:011094-8260-F2LALSampleID:AD5412DateAnalyzed:11-JAN-94DilutionFactor:1QCBatchID:011094-8260-F2NONETentativelyIdentifiedCompoundEstimatedConcentration(yg/L)(10RetentionTime(minutes)0.00DataQualifierls)LOCKHEEDANALYTICALSERVICESr.6 WATERMATRIXSPIKEDATASUMMARYFORVOLATILEORGANICANALYSISUSINGEPAMETHOD8260ClientSampleID:MATRIXSPIKE/DUPLICATEAnalyticalBatch:011294-8260-F2QCBatchID:011294-8260-F2LALSampleID:L968-27MS/MSDDateAnalyzed:124AN-94Constituent1,1-DichloroetheneBenzeneTrichloroetheneTolueneChlorobenzeneSpikeAdded(yg/L)5050505050SampleConcentration(yg/L)1.21.41.21.7MatrixSpikeConcentration(yg/L)51525254Recovery9999102101106QCLimitsRecovery62-12467-12760-12072-13268-128Constituent1,1-DichloroetheneBenzeneTrichloroetheneTolueneChlorobenzeneSpikeAdded.(yg/L)5050505050MatrixSpikeDuplicateConcentration(yg/L)49505153Recovery96999899104RPDRPD14141313QCLimitsRecovery62-12467-12760-12072-13268-128LOCKHEEDANALYTICALSERVICES2( WATERLCSDATASUMMARYFORVOLATILEORGANICANALYSISUSINGEPAMETHOD8260ClientSampleID:LCSAnalyticalBatch:011094-8260-F2QCBatchID:011094-8260-F2LALSampleID:AD5213DateAnalyzed:11-JAN-94Constituent1,1-DichloroetheneBenzeneTrichloroetheneTolueneChiorobenzeneLCSRecovery100108110117QCLimitsRecovery62-12467-12760-12072-13268-128LOCKHEEDAIVALYTICALSERVICES SEIVllVOLATILEORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270ClienamIID:BLANKDateCollected:N/AMatrix:WATERAnliIBh¹:1114-27-BQCBatchID:8270-SEMIVOLATILES-3964LALSamIeID:94MBDateReceived:N/ADilutionFactor:1DExr:4-AN-4DateAnalzed:11-JAN-94P1f2URRGATERECOVERYI2-FluorohenolPhenol-d,Nitrobenzene-d,2-FluorobihenI246-TribrmhnIp-Terphenyl-d4327666486CLimi21-10010-9435-11443-1161-1233-141CnsienPhenolbis2-ChloroethIether2-hirhnl1-Dihlrnzn14-DichlorobenzeneBenzIalcohol12-Dihlrnzn2MhIhnIbis2-ChioroisoroIether4-MethIhenolN-Nir-Di-n-rIminHxhlrhnNitrobenzeneIsohorone2-NirhnI24-DimhIhenIBenzoicacidbis2-Chloroethoxmethane24-DichlrhnI'124-TrihlrnznNahthalene4-ChloroanilineHexhlrinc4-hlr--mhIhnI2-MethInahthaleneHexachloroccloentadieneConcentration/L<10<10<10<10<10<10<10<10<10<50<10<10<10<10<10<10<10ReportingDetectionLimit/L101010101010101050101010101010DaaualifierLOCKHEEDAIVALYTICALSERVICES p,t SEIVIIVOLATILEORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270ClientSamleID:BLANKLALSamfeID:3964MBP2f2Constituent24-TrihlrhnI24-TrihlrhnI2-Chloronahthalene2-NitroanilineDimhIhhIAnhhln26-Dinitrotoluene3-NitroanilineAnhhn24-DinirhnI4-NitrohenolDibenzofuran24DinirInDihIhhIe4-ChlorohenI-henletherFluorene4-Nirnilin4-Dinir-2-mhIhnIN-Nitrosodihenlamine4-BromohenI-henletherHxhlrnznPnhlrhnlPhenanthreneAnthraceneDi-n-uIhhIFlrnhnPreneButIbenzIhthalate'-Dihlrnziin8nznhrnChrsenebis2-EhIhexIhhalateDi-n-IhhIBnzflrnhnBenzokfluorantheneBenzoareneInn12-rnDinzhnhrnBenzohierleneCarbazoleConcentrationIIL)<10<25<10<10<25<2<25<10<10<10'2<2<10<10<10<10<10<10<2<101.3<10<10<10<10ReportingDetectionLimit(IL)1025102525101010101010101010101010101010DataQualifierls)LOCKHEEDANALYTICALSERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8270TENTATIVELYIDENTIFIEDCOMPOUNDSClientSampleID:BLANKDateReceived:N/AMatrix:WATERAnalyticalBatch:011194-8270-BLALSampleID:3964MBDateAnalyzed:11-JAN-94DilutionFactor:1QCBatchID:8270-SEMIVOLATILES-3964NoneTentativelyIdentifiedCompoundEstimatedConcentrationiyg/LIRetentionTimelminuteslDataQualifier(s)LOCKHEEDANALYTICALSERVICES SEIVIIVOLATILEORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270P1f2linmiID:LDateCollected:N/AMatrix:WATERAnalialBh¹:1114-27-BQCBatchID:8270-SEMIVOLATILES-3964LALmIID:4DateReceived:N/ADilutionFactor:1DExra:04-AN-4DateAnalzed:11-JAN-942-FluorohenolPhenol-d,Nitrobenzene-d,2-FluorobihenIRRATERECOVERY37266060Limi21-10010-9435-11443-116246-TriromhnIp-Terphenyl-d8033-141PhenolninConcentrationL40ReportingDetectionLimit/L10Dbis2-ChloroethIether2-hlrhnl1-Dihlrnzn14-DichlorobenzeneBenzIalcohol12-Dihlrnzn2-Mhlhnlbis2-ChloroisoroIether4-MethIhenolN-Nir-Di-n-rIminHxhlrhnNitrobenzeneIsohorone2-NirhenI24-DimehIhnolBenzoicacidbis2-Chloroethoxmethane4-DihlrhnI124-TrihlrnznNahhalene4-ChloroanilineHxhlrin4-hlr--mhlhnl2-MehInahthaleneHexachloroccloentadiene<1039<10<10<10<10<10<50<10<10<10100<10<1010101010101010101010501010101010LOCKHEEDANALy'TICALSERVICES SEMIVOLATILEORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270ClientSamleID:LCSLALSamleID:3964LCSPa2f2Constituent24-TrihlrhnI24-TrihlrhnI2-Chloronahthalene2-NitroanilineDimhIhhIAnhhln26-Dinitrotoluene3-NitroanilineAnhhn24-DinirhnI4-NitrohenolDibenzofuran24-DinirInDihIhhI4-ChlorohenI-henletherFluorene4-Nirnilin4-Dinir-2-mhIhnIN-Nitrosodihenlamine4-BromohenI-henletherHxhlrnnPnhlorhnIPhenanthreneAnthraceneDi-n-IhhIFluornhnPreneButIbenzIhthalate'-DihirnziinBnznhrnChrsenebis2-EthIhexIhthalateDin-IhhI8nzobfluoranhenBenzokfluorantheneBenzoareneInn12-rnDibnzhanhracnBenzohierleneCarbazoleConcentrationIL)<10<10<25<10<25<222<10<10<10<2-<2<10<1017<10<10100<10<2<10<10<10<10<10<10<10<10ReportingDetectionLimitIIL)102510251025101010101010101010101010101010101010DataQualifier(s)LOCKHEEDANALYTICALSERVICES SEIVIIVOLATILEORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270Pae1f2linmIID:DateCollected:NADPLAmlID:4DPDateReceived:N/AMatrix:WATERAnIiIBh¹:1114-27-BQCBatchID:8270-SEMIVOLATILES-3964DilutionFactor:1DaExred:4-AN-4DateAnalzed:11-JAN-942-FluorohenolPhenol-deNitrobenzene-d,RROATERECVERY312462Limi21-10010-9435-1142-FluorobihenI24-TrirmhnIp-Terphenyl-d,4628543-1161-1233-141PhenolninConcentrationL39ReportingDetectionLimitL10Dbis2-ChloroehIether2-hlrhenI1-Dihlrnzn14-DichlorobenzeneBenzIalcohol12-Dihlrnzn2-MhIhnIbis2-ChloroisoroIether4-MethIhenolN-Nir-Di-n-rIminHxhlrhnNitrobenzeneIsohorone2-NirhnI24-DimhIhnIBenzoicacidbis2-Chloroethoxmethane24DihlrhnI*124-TrihlrnznNahthalene4-ChloroanilineHxhlrin4-hlr--mhlhnl2-MethInahthaleneHexachloroccloentadiene<1041<10<10<1074<10<10<10<50<10<10<10<10<101010101010101050101010~1010LOCKHEEDANALYTICALSERV/CES SEIVlIVOLATILEORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270ClientSamIeID:LCSDUPLALSamleID:3964LCSDUPP2f2Constituent24-TrihlrhnI24-TrihlrhnI2-Chloronahthalene2-NitroanilineDimhlhhlaAnhhln26-Dinitrotoluene3-NitroanilineAenhhn24-DinirhnI4-NitrohenolDibenzofuran24-DinirolnDihIhhI4-ChlorohenI-henletherFluorene4-Nirnilin4-Dinir-2-mehIhnIN-Nitrosodihenlamine4-BromohenI-henletherHxhlrnznPnhlrhnolPhenanthreneAnthraceneDi-n-IhhIFlranhnPreneButIbenzIhthalate'-DihlrniinBnznhrnChrsenebis2-fthIhexIhthalateDi-n-IhhI8nzflrnhnBenzokfluorantheneBenzoareneInn1-rnDinzhnhranBenzohierleneConcentrationIL)<10<25<10<10<25<235<10<10<10.<2<2<10<10<10<10100<10<10<10<10<10<10<10ReportingDetectionLimitIIL)101025251010101010101010101010101010101010DataQualifierls)LOCKHEEDANALYTICALSERVICES SEMIVOLATILEORGANICSQUALITYCONTROLDATASUMMARYFORMETHOD8270ClientSampleID:LCSAnalyticalBatch¹:011194-8270-BQCBatchID:8270-SENIIVOLATILES-3964LALSampleID:3964LCS/LCSDUPDateAnalyzed:11-JAN-94'CLimitsPhenolCompoundSpike%Recovery27SpikeDuplicate%Recovery26RPDRecovery5-112RPD422-Chlorophenol1,4-DichlorobenzeneN-Nitroso-di-n-propylamine1,2,4-Trichlorobenzene4-Chloro-3-methylphenolAcenaphthene4-Nitrophenol2,4-DinitrotoluenePentachlorophenolPyrene573978456868811015341745266692379121101144223-13420-124D-23044-14222-14747-145D-13239-13914-17652-11540283828423150385031LOCKHEEDANALYTICALSERVICES" PESTICIDEANALYSESRESULTSBYGC/ECDUSINGMETHOD8080FORCOOKNUCLEARPLANTClienSamleID:METHODBLANKDColleced:NADateExtracted:04-JAN-94Matrix:WATERAnalticalBatch¹:012094-8080-A-1LALSamieID:3965MBDaeReeiv:NADateAnalzed:21-JAN-94DilutionFactor:1QCGrouID:8080PEST/PCBS3965SURROGATERECOVERY0QCLimitsTCMXDCB46"2360-15060-150A-BHCB-BHCConstituentConcentration/L<0.05ReportingDetectionLimit/L0.05DataQualifier(s)G-BHCD-BHCHEPTACHLORALDRINHEPTAHLREPOXIDEG-CHLORDANEENDOSULFANIA-CHLORDANE44'-DDE44'-DDTDIELDRINENDRINENDOSULFANII44'-DDDENDRINALDEHYDEENDOSULFANSULFATEMETHOXYCHLORTOXAPHENEPCB-1016PCB-1221PCB-1232PCB-1242PCB-1248PCB-124PCB-1260TECHNICALCHLORDANEMIREXTCMX-tetra-chloro-meta-xyleneDCB-Deca-chioro-biphenyl<0.05<0.05<0.<0.<0.05<0.05<0.<0.1<0.1<0.1<0.1<0.1<0.1<0.1<0.<5<2<0.10.050.050.050.050.10.10.10.1<0.1LOCKHEEDANALYTICALSERVICES PESTICIDEANALYSESRESULTSBYGC/ECDUSINGMETHOD8080FORCOOKNUCLEARPLANTClienSamleID:LABCONTROLSAMPLEDaClledNADateExtracted:04-JAN-94Matrix:WATERAnalticalBatch¹:012094-8080-A-1LALSamleID:3965LCSDeRecive:NADateAnalzed:21-JAN-94DilutionFactor:1QCGrouID:8080PEST/PCBS3965SURROGATERECOVERYooTCMXDCB6029QCLimits60-15060-150A-BHCB-BHCG-BHCD-BHCConstituentConcentrationIL<0.050.88<0.05ReportingDetectionLimitIL0.050.00.05DataQualifier(s)HEPTACHLORALDRINHEPTACHLOREPOXIDEG-CHLORDANEENDOSULFANIA-CHLORDANE44'-DDE44'-DDTDIELDRINENDRINENDOSULFANII44'-DDDENDRINALDEHYDEENDULFANSLFATEMETHOXYCHLORTOXAPHENEPCB-1016PCB-1221PCB-122PCB-1242PCB-1248PCB-124PCB-12TECHNICALCHLORDANEMIREXTCMX-tetra-chloro-meta-xyleneDCB-Deca-chloro-biphenyl0.70<0.05<0.05<0.05<0.<0.11.851.811.91<0.1<0.1<0.1<5<2<0.10.050.050.050.10.10.10.10.10.10.1<0.1LOCKHEEDAIVALYTICALSERVICESer 1 PESTICIDEANALYSESRESULTSBYGC/ECDUSINGMETHOD8080FORCOOKNUCLEARPLANTClienSamleID:LABCONTROLSAMPLEDUPDColleced:NADateExtracted:04-JAN-94Matrix:WATERAnalticalBatch¹:012094-8080-A-1LALSamIeID:3965LCSDDeReive:NADateAnalzed:21-JAN-94DilutionFactor:1QCGrouID:8080PEST/PCBS3965SURROGATERECOVERYoTCIVIXDCB54"20QCLimits60-15060-150A-BHCB-BHG-BHCD-BHCConstituentConcentration/L<0.05.0<0.05ReportingDetectionLimit/L0.050.0.05DataQualifier(s)HEPTACHLORALDRINHEPTACHLOREPOXIDEG-CHLORDANEENDOSULFANIA-CHLRDANE44'-DDE44'-DDTDIELDRINENDRINENDOSULFANII44'-DDDENDRINALDEHYDEENDOSULFANSULFATEMETHOXYCHLORTOXAPHENEPCB-1016PCB-1221PCB-1232PCB-1242PCB-1248PCB-124PCB-120TECHNICALCHLORDANEMIREXTCMX-tetra-chloro-meta-xyleneDCB-Deca-chloro-biphenyl0.66.5<0.05<0.055<0.11.801.851.94<0.1<0.1<0.5<5<2<0.10.050.050.050.050.10.10.10.10.10.10.10.5<0.1LOCKHEEDANALYTICALSERVICES PESTICIDESQUALITYCONTROLDATASUMMARYFORMETHOD8080ClientSampleID:LABCONTROLSAMPLEAnalyticalBatch4':012094-8080-C-1QCBatchID:8080PES/PCBS3965LALSampleID:3965LCSDateAnalyzed:21VAN-94Matrix:WATERSURROGATERECOVERY(%)TCMXDCB6029"QCLimits60-15060-150ConstituentG-BHC(Lindane)HeptachlorAldrin4,4'-DDTDieldrinEndrinSpikeAdded(yg/L)LCSConcentration(yg/L)0.880.700.601.851.81Recovery887060929096QCLimitsRecovery56-12340-13140-12038-12752-12656-121LOCKHEEDANALYTICALSERVICES58 PESTICIDESQUALITYCONTROLDATASUMMARYFORMETHOD8080ClientSampleID:LABCONTROLSAMPLEAnalyticalBatch¹:012094-8080-C-1QCBatchID:8080PEST/PCBS3965LALSampleID:3965LCS/LCSDDateAnalyzed:21-JAN-94ConstituentG-BHC(Lindane)HeptachlorAldrin4,4'-DDTDieldrinSpikeAdded(yg/L)SampleConcentration(yg/L)MatrixSpikeConcentration(yg/L)0.880.700.601.851.811.91Recovery88'7060929096QCLimitsRecovery32-12734-11142-12225-16036-14630-147ConstituentG-BHC(Lindane)HeptachlorAldrin4,4'-DDTDieldrinEndrinSpikeAdded(yg/L)MatrixSpikeDuplicateConcentration(yg/L)0.880.660.551.81.851.94Recovery886655909397RPDRPD152022271821QCLimitsRecovery32-12734-11142-12225-16036-14630-147LOCKHEEDAIVALYTICALSERVICES58 0 METALSQCDATASUMMARY'LALBatchID(s):.1220.:imQCSamleAnalses'.,'onstituent.AluminumAntimonArsenicBariumBeIliumBoronCadmiumChromiumCobaltCoerIronLeadManesiumMananeseMercuMolbdenumNickelSeleniumSilverSodiumThalliumTlnTitaniumVanadiumZincClient"Sample'IDTRSTRSTRSTRSTRSTRSTRSTRSTRSTRSTRSTRSTRSTRSTRS-QATRSTRSTRSTRSTRSTRSTRSTRSTRSTRSLALSample,ID;L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-14L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13L1009-13DateA'nalyxed01-20-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-20-9401-27-9401-07-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-27-9401-20-9401-20-9401-27-94ReagentBlank(mIL)<0.20<0.060<0.010<0.20<0.005<0.20<0.005<0.010<0.050<0.025<0.10<0.003<5.0<0.015<0.0002<0.20<0.040<0.005<0.010<5.0<0.010<0.20<0.20<0.050<0.020DuplicateP,.recision(%RPD)MatrixSpike-Recovery"(%)10410411074978810098969710184102981061069413798103104NA10794~Ibw~NATheRPDcannotbecomputed,becausethesampleortheduplicateconcentrationwasbelowtheReportingDetectionLimit.Thematrixspikerecoveryisnotreported.Thesampleconcentrationwasgreaterthanfourtimesthespikinglevel.Titaniumisnotincludedinthespikingsolution.LOCKHEEDANALYTICALSERVICES l'0~~RRRRHIRRH~lIyPJ..~~~ >iIiAiA.II'j")A)f)t,el'<,'Il"I.IA)bP..<IIAI<<.'.P;Ah:Al:I)lIl<I')tlatI'AQ<)I')I,I,I.II:>'pII'I'i<):Ii;I')A)'J'li)(I('I'I'i):i'!('(iI')ll(',~(I,Aii'>I;<il'It<<,IiiI<r<<)I,<((<'I<!I)i",I,i,I.<i<'Ii)<(.":I)'("ll(iI'IV(f:<(i(~',.IA('("I.)<II<('.VIAIA~I)'QVl~lIIII.()V.VVX()I(')'I:<'(Ji'A)I'":I.d~))'.I1Ii(<)<(l.'I.I'l)I'I~)I',(<')IlllilIi%:IIV:i),lP(.(i)I.(~(< 0 ~'0'<v<.5,).imp3)j'I'!I"j)j-l'/sXI--I,'//J.".I.'4J.X>'"l'-Ili')J.-.Lu"'5'I;I;/ljA-J.uuJ.-l:juxh-J.uuX5-:-l:5:ji'II.:I'Ii')J.u/Il:j.">x)>"IubXj'-I.:J:)i)l'i-lubI'-l:5'/I'u-J.3uXI--I:5:5JJA-iudl'h-l:5JJJAl40'-l/I<)J.4Ll'II.I'h-IRANN0-l'I'/hlJ-J.5'/)=I)'-I.:)ilHC-JulW-I.'5'/HLi-"VuKA-..b'J:H-'2:jrU-'/uugpAt1-"/I5,I<i,Il)>'Ii'II(>!ilI(il>)I'IP(I'.<<J)<>0:l~'/I,/I',!'/.I')i'<)r'5/I;,I(i/,'III,lf>.'5~'J:I(>>(>>/(>>>)i~ReIJwlf>i'l',i(>>..0J)2'J~I5'jHJ..()0rl:55'Nd~(>>0/!'/0l,'//I;Iu/)'/();Ili">0/II'.I/I4J/>))'r'<>'.)f>J0/;I:..0/b<>I.,I>.')I:(>>J(>>'...I",>\4:).u:pl)"J<>J)0.',<;/l'I>.'I'Iw~l,Irj4I/5JI.(I,l".'/I,I.)<>:5').'5I,-;/'/>)<>'/'.I.7<)(>>0':);<J')lJ:5.le(l;IJ;!0I.<)<>.I,:5gIJ<1IIA(I>I1/II),)l~I'.)l;.h-vuI~/:"i'J)'Vul/'/<)lh-OuI-vu<>I'Jl)h-0'/5-0(>>/;J-0'/l'Jr<4".>h-OuJ"(J::::I:-0u'-:5'I'/:Sh-Vu'>I"'llewJ:"Oul~2'I'/f>h-0'/5I"l(lIvu')~'/i!.p'/h-Q/("':>J'/):-0/l~5'/II'0'/I'/"IIII,'-vu('ilpuh-vbJ.'/I:(>>/II-.Oul.'5'/<)iII."-vuJ~".();'5;-Oble'/<>0',/I-0~JvJ',>',>l<J:~~0(>l-:5'IllI-:-Ou')'IJJ5'-Vul.I>:5:8;.'h-Vu0//~(>>5~-vbI.(:5>n):-ouJ-vb/)/,'5-0/'I-<>42'/h-ouw'<>>II0J>)5'u'I-:5."))5'/h-VuI-(:/"'.)5-Ou<>~(')0/Ih-Vu5-'/QI'5:,--Qur(I.Luh-Ou'<~">'/'.)J):.-Ou'I-'Jbo<)h-Ou"">I"p'/5:-vu).):l>Uh-OuI<~/I,'>;IIJ-Qu 11II)),AII>hlIlk'e>~e~e,,'eIcr>r',eWl'l,Ple(l>(repeal))e)IeIIJ)5'e(}()/e)(Ir)>crt>I>.'e"<:etyI~<~eISQP>>e'>e,lIepe}Ietee(}e~>J>>elIeel-'IHA-;!>>!HA-"<<IL;I..-:I'Ir,-tvAt(-'II.~5\'-<<IbL'K-)\(1H'-b<<tl1H'-:)I>I"I.I-V'/L'lJ-:)ilk>h-')~3L'.l-80t'II-b4Hl-b:)ZH-ba'/.H-b")i'I8h'-'/5AU-'/r>IJH-8'<<IJK->>5<<tl(K-UvV)K-'I:)i'I>>-Ubi(->>I')i1RK-8'/)iA'-~ledKCJ-88X-I'58Rt5-8")l1I.J-')0UH-DlX-"J"X-')IH8-'J<<tHI5-"):)ZK-i)bHLC-~)'/'/.H-'2'/l1II-')')'I:L'-'JiJ(1KU-(0:1HH-l0+KI.J-l0')HU-I.vbL;I)-l0')Ab-lIvl1UH-I.\:IJJCIl.';3I>e',I.'>>Ir)IJt'.~e0'<<0'I'/~:50')~'/t'.'/.<<I~~Tee~pI.'/.'<<0JV.ly<<!0..4:J.'<<0J:)'/.J.l~'<<>>P<<ll>.,5P;I<<!'/.)'<<ep'/./.l:I,e>e(>>"i'),l<<I~l)I)rl).J'eiIi("I"I)>(ez~s'Lg)<<e'/'/pCi'.Il'!'/>>t.)>>IJ"'bt:J<<,'(eVt'J\'<<!"):I'r)<<tII,V',>J:5)!0.,0~I'I'll).'/:))'!'!~0(>>'5I.O~'/I)J0'I'IlII<<'t')I;cr,;,Pl)VI.'t:5(.CI>>tIJ)e),;>'<<!'t5'I'!('<<)~(>>l):))').lv~~e~bee'<<e!I'Il.')0'>J'.'I'Il:)l,\!J;)J;IP'.I'.)I)')<<IV<<!P',it,rl)r>.5.!It"Ib~0)l!J:lr>.0l50"5.t'tl".:)'/.".5>>t)0<<.'r.;:0:)')'/.:)'/!I;"Cr>>,<<;(,<<!I)I>.')0'/V<<!.(;i;I/I>')./')'/:i(>>.'/>>'>:)'/.")0l'CO~:)l.I<<)0,"))'I')'/.0CI;IJCCVV'/<<l't:)0(>>;<<JPt:<<;el~I,():I(>>'</>')e>(>>e'I,lIIIIIA(>II.X/f1L}V/l~')'J5l>h-08',etlr,C,'I08')..'/>>ll)>0I-0'/I'I~eIeIe'e'le0/l,/:)r,)I;-0/J.tlr'i<<!I:"08\~\)0'/I-0'/I~e~"lb'/I08t..:5500h-0'/I>'I5Vl-'08I..<<I:<<50ÃI-08',!,'/Ie'l',il"VU\.:500")I;-08('e"(>>',<'/'/R-(}bI>.')>50>5h-0'/i!p'/<<"./'e)J:-eV8>>!~l8'/')h-08I;I>;I',(J-;"08:I<<!/I.'/h-08<<!~50"I5I-08:.5.0:900h-Ob~.',Crtlvl:-Vb')~I'JlI-08l.ril>t:(>>I:-OL<:5.:I:Il)I)h-0'/<<I'bv'/('el',-V'/:I~05")\I'-0'/5.t"/(t'J00l.:5'5<<lr)I;-08'/.'.I'/tl'<<!J:,"Vb't.0<<!'/'/I;-08b~Ib(>bl~-'087')8")I--0'/t';.!I"IJ'"0'/'!.')l'/'/h-0'/l~l>b<<CbJ:"08l'I't<<")I'-OUr."'t".<J"VU:5.>>I')ldh-0'/I'I'/t"IJ'-OUl'!')b'II.;-08~(/'.IJ:-08l0')ll'/h-OU'/,;e<<;bt:I:-08\.:I'!bith-0'/5,!I'I))I"0'/')et')'9h-0'/J,(>>r.,<<CIJ:-08l~:)'l';)'"OU:!~<<!(>>"e(>>I:-'08 .'i.HalliburtonNUS+++C0RP0RATI0NDUALITYCONTROLREPORTSUPPLEMENTALINFORMATIONNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January11,1994ReportNo.:00018818Section8Page1------------SAMPLEPREPARATION-------------------------------SAMPLEANALYSIS-----------------.-TESTLR-LNCODEBATCHMETHODDATE/TIHEANALYSTLR-METNODDATE/TIMEANLSANALYSTBATCHINSTRUMENI'AMPLEID:SEWAGEPLANTNUSSAMPLENO:P02588381ASNW2303602-4'.303-JAH-940730RAW2105023039NA3I61023014NA4I49023050NAR2-200.707-JAN-94808JWC03-50703-JAN-93700DB02-160.230.DEC-93700EDB02-150.103-JAN-93715DB03560000LRMethodLiteratureReference02EPA-MethodsforChemicalAnalysisofWater&Wastes,1984.03APNA-StandardMethodsfortheExaminationofWaterandWastewater,16theditionR2InductivelyCoupledPlasma-AtomicEmissionSpectrometricMethodforTraceElemenSAMPLEID:OIL/WATERSEPARATOR1G122W2298705-60829-DEC-930800PS3I10623061NA4I68023097NA5I49023050NANUSSAMPLENO:P02588392298700005-60830.0EC-931146JC02-415.104-JAN-941000JJH02-413.103-JAN-931230TM02-150.103-JAN-93715DBLRMethodLiteratureReference02EPA-MethodsforChemicalAnalysisofWater8Wastes,1984.05EPA-40CFR136,October26,1984. 4'alliburtonNUS++C0RP0RATI0NOUALITYCONTROLREPORTSURROGATESTANDARDRECOVERYNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(4'12)747-2580FAX:(412)747-2684January11,1994ReportNo.:00018818SectionCPage1TESTSURROGATELNCODECOMPOUNDPERCENTRECOVERYACCEPTANCELIMITSREFLNSAMPLEID:OIL/WATERSEPARATORNUSSAMPLENO:P0258S392SPCBWPCBSURROGATEnonachtorobiphenyt 1'HalliburtonNUSCORPORATIONQUALITYCONTROLREPORTLABORATORYCONTROLSAMPLERECOVERYNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January11,1994ReportNo.:00018818SectionDPage1TESTCODEDETERMINATIONPERCENTRECOVERYDUPLICATERECOVERYRPDACCEPTANCELIMITSBATCH:23036SAMPLEID:LabControlSampleASNNTin,Total(Sn)BATCH:23039SAMPLEID:LabControlSample92'NUSSAMPLENO:P0259637NANUSSAMPLENO:P0259643I050BOO(02)-5dayBOD(02)-5day¹2BOD(02)-5day¹3BOO(02)-5day¹4101~79499104NANANANABATCH:23050SAMPLEID:LabControlSampleHUSSAMPLENO:P02596581490pHpH¹2pH¹3100.510099.1NANANABATCH:23061SAMPLEID:LabControlSampleHUSSAMPLENO:P02596731106Carbon,Organic-.NonpurgeableCarbon,Organic-Nonpurgeable¹2Carbon,Organic-Honpurgeable¹311096.3106HANANABATCH:23097SAMPLEID:LabControlSampleI680OilandGrease,Gravimetric84.8HUSSAMPLENO:P025972883.81.19 .'iHalliburtonNUS++++C0RP0RATI0NQUALITYCONTROLREPORTMETHODBLANKDATANUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January11,1994ReportNo.:00018818SectionEPage1TESTCODEDeterminationRESULTUNITSBATCH:22987SAMPLEID:MethodBlankNUSSAMPLENO:P0259059G122'NPCBANALYSISPCB-1016PCB-1221PCB-1232PCB-1242PCB-1248PCB-1254PCB-1260<0.50<0.50<0.50<0.50<0.50<1.0<1.0ug/Lug/Lug/Lug/Lug/Lug/Lug/LBATCH:23014SAMPLEID:MethodBlankHUSSAMPLEHO:P0259602I610Solids,Suspendedat103CBATCH:23036SAMPLEID:MethodBtank<10mg/LNUSSAMPLENO:P0259638ASNMTin,Total(Sn)<0.1mg/LBATCH:23039SAMPLEID:MethodBlankI050BOD(02)-5dayBATCH:23061SAHPLEID:HethodBlank0.63mg/LNUSSAHPLENO:P0259674NUSSAHPLENO:P02596441106Carbon,Organic-Nonpurgeable<1mg/LBATCH:23097SAMPLEID:MethodBlankHUSSAHPLENO:P02597291680OilandGrease,Gravimetric<3mg/L '.HalliburtonNUSIaarC0RP0RATI0NQUALITYCONTROLREPORTDUPLICATEANDMATRIXSPIKEDATANUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(4'12)747-2580FAX:(412)747-2684January11,1994ReportNo.:00018818SectionFPage1PREPBATCH:23050HUSSAHPLENO:P0258838TESTDETERMINATION1490pHORIGINALDUPLICATERESULTRESULT6.86'7RANGE/UNITSRPD~02UNITSHSMS%RESULTRCVRYPREPBATCH:23014HUSSAHPLEHO:P0258810TESTDETERMINATION1610Solids,Suspendedat103CORIGINALDUPLICATERANGE/HSHSHRESULTRESULTUNITSRPDUHITSRESULTRCVRY1213mg/L1mg/LPREPBATCH:23036NUSSAMPLENO:P0259167TESTDETERMINATIONASNlJTin,Total(Sn)ORIGINALDUPLICATERESULTRESULT0.40.4RANGE/UNITSRPOmg/L1.98UNITSmg/LRESULT2.28RCVRY94.0HSMS/.PREPBATCH:23039HUSSAMPLENO:P0258780TESTDETERHINATIONI050BOD(02)-5dayORIGINALDUPLICATERESULTRESULT53.81RANGE/UNITSRPDmg/L1UNITSmg/LHSMSyoRESULTRCVRYPREPBATCH:23061HUSSAMPLENO:P0258851TESTDETERHINATIONI106Carbon,Organic-NonpurgeableORIGIMALDUPLICATERESULTRESULT76.86RANGE/UNITSRPDmg/L3.82UNITSmg/LHSHSKRESULTRCVRY57.7101 '.HallibuIItonNUS+++C0RP0RATl0NINUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January11,1994ReportNo.:00018818SectionHPage1QUALITYCONTROLREPORTMATRIXSPIKEANDMATRIXSPIKEDUPLICATEDATAANLSBATCH:22987NUSSAMPLENO:P0258792TESTG122WPCB-1242G122WPCB-1260DETERMINATIONMSRESULT4'74.T5MSDRESULT4.55'.73UNITSug/Lug/LMSPCTMSDPCTRPDRECOVERYRECOVERY0.49191095950' NPDESSTORMWATERDRAINAGEPERMITAPPLICATIOND.C.COOKNUCLEARPLANTONECOOKPLACEBRIDGMAN,MI49106 ELI I'ICCTCVII~~~VlITVr'"~(fill-inareasarespacedforeliterype,i.e.,12characrers/inch(.U.S,tHVIROHMCHTAIPIIOTCCTIOHAOBHCYriiniirlpplovro.ITITIII~Iv.rvrv'ITvrvrlpIVIITCIrrpllrrrVImvGENERALI.EPAI.D.NUMBRill).FACILITYAMEACILITY'AILINADDRESSVIFACIL'ITY'OCATIONGENERALINFORMATIONConsolideredPemlireProgram()leadlhe"Generalinllriieilons"beforeIrarrrne.lPEASEPLCLABELINTHISSPACI.EPAI.D.NUMBERFIIID098647621POCHBRALINSTRUCTIONSItaprsprintedlabelhssbeenprovided,affixltinthedesignatedspace.Reviewtheinform.~lioncarefully;ifsnyofItIsincorrect.crossthroughitsndenterthacorrectdataIntheappropriatefill-insrabelow.Also,ifsnyofthsplePrintsddstsisabsent(dissre~rodi~leftofdi~labelspacelisledi~informationdistshouldsppasrl,pleaseprovideItInthaproperfill-insiss(s)below.Ifthelabells'compl~Iltandcorrect,youneednotcompleteItemsI,III,V,shdVl(ixceprVlBwfikhmustbecompleltdrsgerdless/.CompletesllRemsifnolabelhssbeenprovided.AetertotheInnrucllonstordetailedItemdescrip-tionssndforthelegalsuthorisationsunderwhichthisdatalscollected.II.POLLUTANTCHARACTERISTICSINSTRUCTIONS:CompleteAthroughJtodeterminewhetheryouneedtasubmitanypermitapplicationformstothaFPA.Ifyauanswer"yes"toanyquestions,youmustsubmitthisformandthasupplementalformlistedintheparenthesisfallowingthequestion,Mark"X"intheboxinthathirdcolumltifthesupplementalformisattached,Ifyouanswer"no"toeachquestion,youneednotsubmitanyoftheseforms.Youmayanswer"no"ifyouractivityisexcludedfrompermitrequirements;seeSectionCoftheinstructions.Seaalso,Section0oftheInstluctionsfordefinitionsofbold-facedterms.SPKCIPICDUCSTIOHS~OPTIapcclpicDUtsTIDNsITVACIICroryCD0ATTACIICO,IsIissscililvwhichcunenlvresulsinIscsrgcslowslsrsoftheU.S.olherahonIhqtsdescribedinXAorBabove)2NForm2bIIisapropossciityoersnostascnInAorBshovelwhichwillresultin~dischargelowst~tthsUS7FRM2IA.Isthisfacilityspubliclyownedtreatmentworks8.Doesorwillthisfacility(eitherexist(nporproposcdlwhichresuIIIinsdischargelowatersofthsU.S.)includesconcentratedanimalfadlhgoperationorIFORM2A)~qusslcanimalproductionfacilitywhichresultsinadischargelowssslsoftheU$2IFOAM28)~~I~~~XE.Doesorwillthisfacilitytress,store,ordisposeofhszsrI)ouswsnssfIFORM3)oyouorwiyouihleclslIissoilyshyproucwaterorotherfluidswhichsrabroughttothesurfaceinconnectionwithconventionaloilornaturalgsspro.duction,injecttluidsusedforenhancedrecoveryofoilornaturalgss,orihjeC!fluidsforstorageofliquidhdrocsrbohstIFORM4)~5lllissciily~proposessssiohsrysourcew>>soneofthe28industrialcategorieslistedinthein-structionssndwhichwillpotentiallyemit100tonspsryearofanyairpollutantregulatedundertheCleanAirAclandIhaySffeCtOrbelocatedinsnsnsihmcntarcs)IFORMSlIII.NAMEOFFACILITY15<<PD.C,COOKNUCLEARPLANTF.Doyouorwillyouinjectatthisfacilityindustrialormunicipaleffluentbelowtha.lowermoststratumcon-X~taining,withinonequartermileofthewellbort,undergroundsourcesotdrinkingwater?IFOAM4)H,DoyouorwillyouinjectstthisfacilitytluidsforspscislprocessessuchasminingotsulfurbylhsFraschprocess,solutionminingofminerals,insitucombus.tlonoffossilfuel,orrecoveryotgeothermalensrgytIFORM4)~Ilisaciity~propnsiysourcewhicisNOToneottht28industrialcategorieslinedintheInstructionsandwhichwillpotentiallyemit250tonsperyearofanyeirpollutantregulatedundertheCleanAirActsndmayaffectorbelocatedInansttalnmeIIS~Ies)IFORM5)XXT~I~I~'lXIV.FACILITYCONTACTA,NAMtSITITLC(loll,(lNI,IallllelC2BAKERD.L.FnvironmentalAffairsDirectorB,I'HDNCfaTCCcodekno.l2194252118V.FACILITYMAILINGADDRESS3P0BOX60ASTRttTORP.OBOX4FORTWAYNE~.CITYORTOWNC,STATtD,ZIPCODCIN4680Vl.FACILITYLOCATIONASTRtCTIROUTCHOOROTHCRSPtCIPICIDtNTIPICR5ONECOOK"PLACEBERRIENBlCOUNTYNAMt6BRIDGOINC.CITYORTOWNDSTATtClZIPCODS416EPAForm3610.1IRsv.104I0)CONTINUEONREVEASE TINEDFROMTHEFRNTVlf,SICCODES(4<ipit.Jnorderofpr(orlrvJAoFltt5T911"""fyJSTEAMELECTRICPOriZR(specifyI~,SCCONOC.'rNIItO(specifyI7~~~i~VIII.OPERATORINFORMATIONIC8NDIANAMICHIGANPOR0~IAoNAMC(specifyIO,FOURTH.IsthanamelistedInItemVIII.A~lathsownersK3YESC3NOsa,I~t~cSTATU5oForcRAToR(EnterthcapproprlatclcncrIntothcanstrcrooxtlf-Other",spcclfy.lo.rNotte(areacodeano.l~aALS~STATEP~PRIVATEONECOOKPLACEULI(otherthanfcdcralorstateJ(specifyJ0~OTHER(IpeclfyJPC,5TRCCT0tlF.OISOXA61665901~~I~I~~~~sBRIDGMANI,CITYORTOWN~e~I~I~'~IIsthefacilitylocatedonIndianlandstOYESCBNOaaX.EXISTINGENVIRONMENTALPERMITSA.IIIois(DischargestoSurfaceWaterJigNMI00058275.UIC(undergroundIn/cationofFluldsl9U(Ho.rso(A4EmlsslonsfromproposedSourcesJ'r~9PC.oTNcR(specifyI(IfyJFirPermit'applicat;insamatte(spealfyJ9R9~~~411'I'I~I~~~~~~~~I~XI.MAPAttachtothisapplicationatopographicmapoftheareaextendingtoatleastonemilebeyondpropertybounderies.Themapmustshowtheoutlineofthefacility,thelocationofeachofitsexistingandproposedintakeanddischargestructures,eachofitshazardouswastetreatment,storage,ordisposalfacilities,andeachwellwhereitinjectsfluidsunderground.Includeellsprings,riversandothersurfacewaterbodiesinthemaparea.Seeinstructionsforpreciserequirements.XII.NATUREOFBUSINESS(provide~aria(descriptionTheCookNuclearPlantisa2130Mt4steamelectricgeneratingstationsituatedin6*beltofsanddunesonthesoutheasternshoreofLakeMichiganbetweenStevensvilleandBridgman.Preparationofthesiteforconstructionoftheplantbeganin1968.Unit1wasoperat-tionalin1975andUnit2in1978.XIII.CERTIFICATION(seeinsuvcdonslIcertifyunderpenaltyoflawthatIhavepersonallyexaminedandamfamiliarwirhtheinformatlonsubmittedinthisapplicationendallattachmentsandchat,basedonmyinquiryofthosepersonsimmediarelymsponsibleforobtainingtheInformationcontainedintheapplication,Ibelievethattheinformationistrue,accurateandcomplete.Iamawarethatthemamsignificantpenaltiesforsubmittingfalseinformation,includingthepossibilityoffineandimprisonment.AMcIsoFFIcIALTITLc(typeorprlnIIR.C.Menge,President9SIGNATURCC,OATCOMMENTSFOROFFICIALUSEONLYCCEPAForm3510.1{Rav.1080)ReverserrrrlartarattireII9SS 'I Severalofthesectionsinthispermitapplication(Form2F)arecompletedviatheuseofattachments.Thesesectionsreferencetheappropriateattachment.Pleasecarefullyreadeachsectiontoavoidanyconfusion. FormApproved.OMBNo.20404086Approvalexpires541.92UnitedtatesEnvironmentaProtectionAgencyWashington,DC20460Appi!cat!onforPerm!ttoD!schprgeStormY/at~rOischaresAssociatedwithindustrialActiviForm2FI.,kEPAIDNumber(copyfromitemiofFormi)PleaseprintortypeintheunshadedareasonlyHLD098647621I.OutfaiiLocatIonForeachoutlalllistthelatitudeandlonitudeofitslocationtothenearest15secondsandthenameoftherecolvinwater.AOutfallNumberist~D.ReceivingWaternameB.LatitudeC.Lonitude1S415850863400LakeHichi'2S415845863400LakeMich41'843863400LakeHichian415843863400LakeHichiPaperworlrReductionActNotice,PublicrepoNnIIburdenforthisap'plicationisestimatedtoaverage28.6hoursperapplication,includ!ngtimeforreviewinginstructions,-searchingexistingdatasources,gatheringandmaintainingthedataneeded,andcompletingandreviewingthecollectionofinformation.Sendcommentsregardingtheburdenestimate,anyotheraspectofthiscollectionofinformation,orsuggestionsforIhtprovingthisform,includingsuagostionswhichmayIncreaseorreducethisburdento:Chief,InformationPolicyBranch,pM-223,U.S.EnvironmentalProtectionAgency,401MBt.,SW,Washington,DC20460,orDirector,OfficeofInformationandRegulatoryAffaire,OfficeofManagementandBudget,Washington,DC2C503II.ImrovementsA.AreyounowrequiredbyanyFederal,State,orlocalauthoritytomeetanyImplementationschedulefortheconstruction,upgradingoroperationofwastewatertreatmentequlpmontorpracticesoranyotherenvironmentalprogramswhichmayatfectthedischargesdescribedinthisapplication2Thisincludes,butisnotlimitedto,permitconditions,administrativeorenforcementorders,enforcementcompliancescheduleletters,stipulations,courtorders,ahdgrantorloanconditions.N/A1.IdentificationofConditions,reements.Etc.number2.AffectedOutfallssourceofdischare3.BriefDescritionofProect4.FinalComlianceDateb.ro.a.re.ContinueonPage2Page1of3EPAForm35102F(Rev.1.92)youmayattachadditionalsheetsdescribinganyadditional'waterpollution(orotherenvironmentalprojectswhichmayaffectyourdischarges)younowhaveunderwayorwhichyouplan.Indicatewhethereachprogramisnowunderwayorplanned,andindicateyouractualorplannedschedulesforconstructionRefertoAttachmentA.!I.SiteDraInaeMa""achasitemapshowingtopography(orindicatingtheoutlineofdrainageareasservedbytheoutfall(s)coveredintheapplicationifagr~phiCmapiSuiavailable)depiCtingthefaCilityinCIuding:eaChOfitSintakeanddiSChargeStruCtureS;thedrainageareaOfeaChStOrm""'"'u"all:pavedareasandbuildingswithinthedrainageareaofeachstormwateroutfall,eachknownpastorpresentareasusedforoutdoor'oiagoor<<<posalofsignificantmaterials,eachexistingstructuralcontrolmeasuretoreducepollutantsinstormwaterrunoff,materialsloadingan<<c~ssareas.areaswherepesticides,horbicides,soilconditionersandfertilizersareapplied;eachofitshazardouswastetreatment,""-rags<<disposaluni:s(includingeachareanotrequiredtohaveaRCRApermitwhichisusedforaccumulatinghazardouswasteunder40<'"26234):eachweilwherefluidsfromthefacilityareinjectodunderground;springe,andothersurfacewaterbodieswhichreceivestormr.a!or",sc.'.aosficm!"efacili ContinuedfromtheFrontForeachoutfall,provideanestimateofthearea(includeunits)ofImpervioussurfaces(Includingpavedareasaridbuildingroofs)drainedtotheoutfall,andanestimateofthototalsurfaoeareadrainedbYtheoutfall.SeeAttaChment:BOutfallAreaofImperviousSurfaceTotalAreaDrainedAreaofknpelvlousSuflaceTotalAreaDrainedB.provideanarrativedescriptionofsignificantmaterialsthatarecurrentlyorinthepastthroeyearshavebeerrtreatod,storedordispcsedlnamannertoallowexposuretostormwater;methodoftreatment,storage,ordisposal;pastandpresentmaterialsmanagementpracticesemployedtominimizecontactbythesematerialswithstormwaterrunoff;materialskedingandaocesaareas;andthelocation,manner,andfrequencyinwhichpesticides,herbicides,soilconditioners,andfertilizersareapplied.1.SeeAttachmentBforsignificantmaterialsSeeAtt.achmentB-1forHerbicideInformationSeeAttachmentB-2forotherpotentialexposurestostorlhwaterC.Foreachoutfall,providethelocationandadescriptionofexistingstructuralandnonstructuralcontrolmeasurestoreducepollutantsinstormwaterrunoff;andadescriptionofthetreatmentthestormwaterreceives,Includingtheschedul~andtypeofmaintenanceforcontrolUstCodesfromSeeAttachment'V.NonstorrnwaterDlscharesAIcenifyunderpenaltyoflawthattheoutfall(s)ooveredbythisapplicationhavebeentestedorevaluatedforthepresenceofnonstormwaterdischarqes,andthatallnonstormwaterdischargeefromtheseoutfall(s)aroidentifiedinoitheranaccompanyingForm2CorForm2EiNameandOfficialTitle(typeorprint)D.L.Bakeri'.AffairsDirector,DateSigned3b-ggB.Provideadescriptionofthemethodused,thedateofanytesting,andtheonsltodrainagepointsthatweredirectlyobservedduringatest.Samplesprocuredandanalyzedasperapplicableguidelines.Outfall003Ssampledbeforeandaftermixingwithgroundwater.Vl.SlnlficantLeaksorSillsProvideexistingInformationregardingthehistoryofsignificantleaksorspillsoftoxicorhazardouspollutantsatthefacilityinthelastthreeyears,Includingtheapproximatedateandlocationofthespillorleak,andthetypeandamountofmaterialreleased.SeeAttachmentCEPAForm3510.2F(Aev.1-92)Page2of3ContinueonPage3 ler-'"Kx~&5%IS~ContinuedfromPage2EPAlDNumber(copyfiomitemiofForm1)HID098647621AB.G.4D:seeInstructionsbeforeproceeding.completeonesetoflablesforeachoutfall.Annotatetheoutlallnumberintheapaceprovided.TablesVll.A.Vll-B,andV!LCareincludedonsearetesheetsnumberedVll-1andVil2.E.Potentialdischargesnotcoveredbyanalysis~isanytoxicpollutantlistedintable2F.2,2F4or2F<,asubstanceoracomponantolasubstancewhichyoucurrentlyuseormanufactureasanintermediateorfinalproductorbyproduct?YeslistailsuchiiurantsbelowNootoSectionDoyouhaveanyknowledgeorreasontobelievethatanybiologicaltestforacuteorchronictoxicityhasbeenmadeonanyofyourdischargesoronareceivingwaterinrelationtoyourdischargewithinthelast3years?YesistallsuchiiuranrsbelowNoofoSectionN/AvrereanyoftheanalysisreportedinitemVllperformedbyacontractlaboratoryorconsultingfirm?XYes(listthename,address,andtelephonenumberof,andpollutantsNo(gotoSection?r)A.NameB.AddressC.AreaCodeif,PhoneNo.D.PollutantsAnaledLockheedAnalyticalServices975KellyJohnsonDr.1(800)361-0220LasVegas,Nevada89119-3705W.W.EngineeringtfScienceGlenwoodHillsParkway1(616)942-9600P.O.Box874GrandRapids,HI49588-0874InorganicsOrganicsRadiochemistryBOD5(BiologicalOxygenDemand)SurfactantsIcertifyunderpenaltyoflawthatthisdocumentandallattachmentswerepreparedundermydirectionorsupervr'sioninaccordancewitha'ystemdesignedtoassurethatqualifiedpersonnelproperlygatherandevaluatetheinformationsubmitted.Basedonmyinquiryofthepersonorpersonswhomanagethesystemorthosepersonsdirectlyresponsibleforgatheringtheinforma;ion,theinformationsubmittedis,tothebestofmyknowledgeandbelief,true,accurate,andcomplete.Iamawarethattherearesignificantpenaltiesforsubmittingfalseinformation,includingthepossibilityoffineandimprisonmentforknowingviolations.ANamelfOtficialTitle(~orpn'nr)R.C.Henge,Presidentis+1~~river~Page3of3B.AreaCodeandPhoneNo.(219)425-2118D.DateSigneds/su/qg 'EPAlDNumber(copyfromrremIofFormt)tiMID098647621IVll.DischareInformation(Confrnued(romae3ofForm2FFormApproved.OMBNo.204046)NIPart-Youmustprovideth~resultsofatleastoneanalysisloreverypollutantinthistable.Compl~leonetabl~foreachcurtail.erne.instructionsforadditionaldetails.PollutantandCASNumber(ifavailable)GrabSampleTakenOuhngFirst30MinutesFlow-weightedCompositeMaximumValues(includevnns)GrabSampl~TakenDuringFirst30MinutesRow-weightedCompositeAverageValues(includeunits)NumberofStormEventsSampledSourcesofPollutantsO'IandGreaseBiOlOgiCalOxygenDemand(8005)ChemicalOxygenDemandlCODlTotalSuspendedSokds(TSS)TotalKjefdahtNitroenNitrat~plusINitriteNitroenTotalPhcschorusMinimum'.taxirrurnREFERTOATTACHMENTDMinimumMaximumpart8-t.isteachpollutantthatisumitedinanetfluentguideknewnicnthetacivtyissuolecttooranypoilutantlistedinthetacuitysNFDEspermitforits'processwastewaterlilthelaciktyisoperatingunderanexistingNpDESpermnl.Completeonetableioreacnoutfait,hinIIi~PollutantandCASNumber(ifavailable)GrabSamoleTakenDuringFirst30MinutesRowweightedCompositeMaximumValues(includeunits)GrabSampf~TakenOunngFirst30MinutesFlow.weigntedComposit~AverageValues(includeunits)NumberofStormEventsSampledSourcesofPonutantsREFERTOATTACHMENTDEPAForm3510-2F~~PageVa.lContinueonReverse ContinuedfromtheFrontPertC-UsteachpollutantshowninTables2F-2,2F4,and2'hatyouknoworhavereasontobelieveispresent.Seetheinstructionsforadditionaldetailsandrequirements.Completeonetableforeachoutfall..PollutantandCASNumberfifavailable)GrabSampleTakenDunngFirst20MinutesFlow~ightedCompositeMaximumValues(incfudeunits)GrabSampleTa'anDuringFirst20MinutesRow~fghtedCompositeAverageValuesffncfudeunits)NumberofStormEventsSampledSourcesofPollutantsREFERTOATTACHMENTDPertD-Providedataforthestormeventswhichresultedinthemaximumvaluesforthe.owweihtedcornsitesamle.DateofStormEvent2DurationofStormEventinminutes3.Totalrainfallduringstormeventininches4.Numberofhoursbetweenbeginningofstormmeas-uredandendofpreviousmeasurablerainevent5.Maximumflowrateduringrainevent(gallons/minuteorsecunits6.Totalflowfromraineventallonsorsec'nitsDec.18194210min.0.14inches280.5hours(RefertoAttachmntDforStormEv2liters/min.ntDescription)1,260liters210min.x1.5I./min.x4outfalls=1260liters7.Provideadescritionofthemethodofflowmeasurementorestimate.Onelitercontainerusedinconjuctionvithastopvatch.EPAForm3510-2F(Rev.1-P2)PageVll.2 Instructions-Form2FApplicationforPermittoDischargeStormWaterAssociatedwithIndustrialActivityWhoMustFileForm2FForm2FmustbecompletedbyoperatorsoffacilitieswhichdischargestormwaterassociatedwithindustrialactivityorbyoperatorsofstormwaterdischargesthatEPAisevaluatingfordesignationasasignificantcontributorofpollutantstowatersoftheUnitedStates,orascontributingtoaviolationofawaterqualitystandard.Operatorsofdischargesv'hicharecomposedentirelyofstormwatermustcompleteForm2F(EPAForm3510-2F)inconjunctionwithForm1(EPAForm3510-1).Operatorsofdischargesofstormwaterwhicharecombinedwithprocesswastewater(processwastewateriswaterthatcomesintodirectcontactwithorresultsfromtheproductionoruseofanyrawmaterial,interme-diateproduct,finishedproduct,byproduct,wasteproduct,orwastewater)mustcompleteandsubmitForm2F,Form1,andForm2C(EPAForm3510-2C).Operatorsofdischargesofstormwaterwhicharecombinedwithnonprocesswastewater(nonprocesswastewaterincludesnoncontactcoolingwaterandsanitarywasteswhicharenotregulatedbyeffluentguide-linesoranewsourceperformancestandard,exceptdischargesbyeducational,medical,orcommercialchemicallaboratories)mustcompleteForm1~Form2F,andForm2E(EPAForm3510.2E).Operatorsofnewsourcesornewdischargesofstormwaterassociatedwithindustrialactivitywhich'willbecombinedwithothernonstormwaternewsourcesornewdischargesmustsubmitForm1,Form2F,andForm2D(EPAForm3510-2D).WheretoFileApplicationsTheapplicationformsshouldbesenttotheEPARegionalOfficewhichcoverstheStateinwhichthefacilityislocated.Form2FmustbeusedonlywhenapplyingforpermitsinStateswheretheNPDESpermitsprogramisadministeredbyEPA.ForfacilitieslocatedinStateswhichareapprovedtoadministertheNPDESpermitsprogram,theState'nvironmentalagencyshouldbecontactedforproperpermitapplicationformsandinstructions.InformationonwhetheraparticularprogramisadministeredbyEPAorbyaStateagencycanbeobtainedfromyourEPARegionalOffice.Form1~Table1ofthe"GeneralInstructions"liststheaddressesofEPA,RegionalOfficesandtheStateswithinthejurisdictionofeachOffice.CompletenessYotirapplicationwillnotbeconsideredcompleteunlessyouanswereveryquestiononthisformandonForm1.Ifanitemdoesnotapplytoyou,enter"NA(fornotapplicable)toshowthatyouconsideredthequestion.PublicAvailabilityofSubmittedInformationYoumaynotclaimasconfidentialanyinformationrequiredbythisformorForm1~whethertheinformationisreportedontheformsorinanattachment.Section402(j)oftheCleanWaterActrequiresthatallpermitapplicationswillbeavailabletothepublic.Thisinformationwillbemadeavailabletothepublicuponrequest.AnyinformationyousubmittoEPAwhichgoesbeyondthatrequiredbythisform,Form1,orForm2Cyoumayclaimasconfidential,butclaimsforinformationwhichareeffluentdatawillbedenied.lfyoudonotassertaclaimofconfidentialityatthetimeofsubmittingtheinformation,EPAmaymaketheinformationpublicwithoutfurthernoticetoyou.ClaimsofconfidentialitywillbehandledinaccordancewithEPA'sbusinessconfidentialityregulationsat40CFRPart2.DefinitionsAllsignificanttermsusedintheseinstructionsandintheformaredefinedintheglossaryfoundintheGeneralInstructionswhichaccompanyForm1.EPAIDNumberFillinyourEPAICentificationNumberatthetopofeachodd-numberedpageofForm2F.Youmaycopythisiiumberd:rectly'.omitemIofForml. ATTACHMENTA ATTACHMENTAII.ImprovementsB.TheD.C.CookNuclearPlantispursuingthefollowingwatertreatmentprojects:MakeupDemineralizerRegenerationWasteNeutralizationSystemTheCookPlantisinstallingasystemtocollectandtreatmakeupdemineralizerregenerationwastestomeetproposedpHpermitlimits.ThecurrentpracticeistoisolatetheTurbineRoomSump(TRS),accumulatethewasteswithintheTRS,neutralizethewastewithsulfuricacidorsodiumhydroxide,thendischargetheneutralizedcontentsoftheTRStotheAbsorptionPond.BecausetheregenerationwastesarenottheonlysourceofwaterbeingcollectedintheTRS,ahighwaterlevelwithintheTRSmayrequirethedischargeofthesumpcontentspriortothewastesbeingcompletelyneutralized.ThenewsystemwillallowcollectionandneutralizationoftheregenerationwastesapartfromtheTRS.TheholdingtankforthewastewillalsobethepointoftreatmentwiththecapabilitytoaddandmixsulfuricacidorsodiumhydroxidewiththewastepriortometeringtheneutralmixturetotheTRS.ThesystemistargetedforcompletionbyJanuaryof1995,withsystemstart-uptooccurthereafter.SequencingBatchReactorsTheCookPlantiscurrentlyrequestingquotationstoinstallapairofpre-engineeredsequencingbatchreactors(SBR)tomeettheproposedgroundwatereffluentlimits.Thenewsystemwilloperateatadesignflowof50,000GPDwithamaximumflowof60,000GPD.TheSouthExtendedAerationPackagePlantwillbeutilizedasaretentiontanktoensureefficientSBRoperation.Effluentfromthenewsystemwillcontinuetobedischargedintooneofthetwoseepagelagoons.ThenewsystemwillbeinstalledandoperationalbyDecemberof1995.3.AlumReplacementProgramAChemistryTaskForceisevaluatingchemicalflocculentreplacementsforalum(aluminumsulfate),takingbothgroundwatereffluentstandardsandreverseosmosissystemperformanceintoconsideration.Thereplacementscurrentlybeingreviewedarepofymericflocculentsthat.willenhancetheremovalofsuspendedsolidsinthepre-filtersandmeetmanufacturer'srecommendationsforthewater ATTACHMENTA(Cont.)enteringthereverseosmosissystem.Therecommendationsfromthetaskforce,onceapproved,willrequireadditionaltimetotestandimplement.TheenvironmentalbenefitofthisreviewisthereducedamountofaluminumthatwillbedischargedtothegroundwaterthroughtheTurbineRoomSumpdischarge.Thescheduledimplementationdatetouseanewflocculentisfourthquarterof1994.ZebraMusselControlStrategyThecurrentcontrolplanemployschlorinationandperiodicshockchemicaltreatmentsutilizingaproprietarychemicalformulation.ThePlanthasalsochangedthesourcewaterforthefireprotectionsystemtoapotablesupplyfromLakeTownship.Thismethodofcontrolwasdevelopedforshorttermrelieffromtheeffectsofzebramusselinfestation.BasedonoverthreeyearsofexperienceindealingwiththemusselsatthePlantandotherGreatLakesfacilities',anewstrategyisbeingevaluatedtoprotectalloperationsfrominfestation.ThenewstrategyincorporatesintermittentoxidizingbiocidetreatmentsofthecirculatingwatersystembeginningattheintakestructuresinLakeMichigan,continuousoxidizingbiocidetreatmentoftheessentialservicewaterandnon-essentialservicewatersystems,andadditionofsodiumbisulflitetoreduceanyresidualoxidizingbiocidepriortodischargetothelake.Ifnecessary,shocktreatmentsutilizingproprietarychemicalformulationswillbeadministered.Thegoaloftheprogramisto(l)eradicateexistingpopulationsandcontrolfurthersettlementofzebramusselswithintheplantsystemswhichutilizelakewater,(2)treattheresidualoxidantbeingdischargedtonon-detectablelevels,and(3)reduceoreliminatethenumberofremedialshocktreatmentsnecessarytokillsettledcoloniesofzebramussels.5.ChemistryCorrosionControlAdditivesThePlantisevaluatingsubstitutesforthecurrentcorrosioncontroladditivesinthesteamgenerators,plantheatingboiler,feedwaterandcondensatesystems,andclosedheating/coolingsystems.Thesesubstituteswillincludecarbohydrazide,andotheravailableproductsfromchemicalcompaniessuchasBetzorNalco.Theenvironmentalbenefitsoftheseadditivesincludeutilizationofmorebenigncorrosioncontrolproductsorproductsrequiringlowereffectiveconcentrations.TheseproductswilldischargetotheTurbineRoomSumpinconcentrationstobedeterminedupontreatmentoptimization. ATTACHMENTB ATTACHMENTBIV.NarrativeDescriptionofPollutantSourcesattheD.C.CookNuclearPlantinBridgman,Michigan.A.ApproximateSurfaceArea(inft')ofImperviousSurfaceandTotalAreaDrained(ImperviousandPervious)byOutfallNumber:OUTFALLPSURFACEAREATOTALAREADRAINEDImervious8cPervious001S002S003S004S1,400,000400,000150,0004,0001,800,000800,000450,000300,000B.SignificantMaterials-Treated,Stored,orDisposedof:Specificchemicalsthatarestoredorusedinawaythatmaypotentiallyexposethemtotheyarddrainagesystemareasfollows:FuelOil-Storedinseveralundergroundandabovegroundstoragetanksthroughoutthesite.Allfillareasarewithinacontainmentareaandoverfillalarmsareinstalledforeachtank.Yarddrainbasinsareinstalledwithavalvewhichisclosedduringthefillingprocess.Intheunlikelyeventaspilldoesoccur,freeproductisheldwithinthecontainment.Anyandallfreeproductisproperlyremovedbyqualifiedandtrainedpersonnelpriortotheopeningofthebasinvalve.Strictproceduresareoutlinedbythecompanyforproper"fillingproceduresintheseareas.Duringmaintenanceperiods,smalltankscontainingdieselfuelarelocatedaroundtheplantsitetofuelgenerators,compressors,andotherauxiliaryequipment.Thesetanksarebermedanddeliveriestothemareinsmallquantities.Spillswhichcouldoccurareimmediatelycleanedupwithabsorbentmaterial. ATTACHMENTB(cont.)SulfuricAcid-Storedina10,000gallontankwhichisbermedwithinalinedconcretestructuredesignedtohold150%ofit'scontentsintheeventoftankoverfillorrupture.ThesulfuricacidinthistankisusedfordemineralizerregenerationsandpHneutralization.Thetankandit'containmentstructurearelocatedoutsideanddirectlyadjacenttotheUnit1TurbineBuilding.Thistank,likeallotherbulkchemicalandfueloilstoragetanks,hasanoverfillalarmsystemtohelppreventspilleventswhilefillingthetank.ThefillforthistankislocatedalongthewestwalloftheUnit1TurbineBuildingandsharesalinedconcretespillbasinlocatedwithintheNorthChemicalUnloadingAreawiththeheatingboilerfueloiltankvents.NOTE:TheNorthChemicalUnloadingAreaisabermedtanktruckunloadingareatypicalofotherunloadingareasontheplantsite.Theareaisslightlydepressedandslopedtoasinglestormdrain.Thisdrainisoutfittedwithavalvetoisolatethecontainmentfromthestormdrainagesystem.Theoperationofthisvalve,andotherslikeitwithincontainmentareasaroundtheplantsitearecontrolledbyplantprocedures.Sulfuricacidisalsousedtoregeneratethemembranesinthereverseosmosis(RO)unitusedforwaterpurification.TheROunitislocatedoutsideintheroadwaydirectlywestoftheScreenhouse.Thesulfuricacidisstoredin55gallondrumswhicharebermedwithinacontainmentsystemadjacenttothereverseosmosisunit.ThesedrumsarechangedunderthedirectionoftheROunitoperator.Plansaretoupgradethisbulkstoragetoabermedtanksystem.Hydrochloricacidasasubstituteforthesulfuricacidisbeingevaluated.SodiumHydroxide-Storedina10,000gallontankwhichisvaultedinthebasementoftheUnit1TurbineBuilding.Thistankhasanoverfillalarmsystem.Leaksandspillsfromthetankandpipingarecontainedwithinthevaultandroutedtotheturbineroomsumpforneutralization.ThefillforthistankislocatednexttothefillforthesulfuricacidtanklocatedwithintheNorthChemicalUnloadingArea.TransformerOil-TransformerscontainingmineraloilcontaminatedwithlowlevelPCB's(<50ppm)whicharenotroutedtooilwaterseparators,arebermedandcontainashutoffvalveormanuallycontrolledsumppump.Thesecontainmentsareinspectedandreleasedbyatrainedoperatorontotheroadways,whicheventuallyentertheyarddrainsystem.Anycontaminationthatisfoundwithinthecontainmentareasisremovedprior ATTACHMENTB(cont.)toreleaseofthematerialtotheroadwaysandyarddrainsystem.Thetransformersareroutinelydrainedformaintenanceandrefilledontheplantsite.Trucksandpipingarebermedduringtransferringoperations.IAMtransmission/distributioncrewsmaintainthetransformersontheplantsiteinaccordancewithcompanyprocedures.SodiumHypochlorite(Chlorine)-UnloadedattheSouthChemicalUnloadingAreawhichissimilarindesigntotheNorthChemicalUnloadingArea.Yarddrainbasinsinthisarea,areinstalledwithavalve,whichisclosedduringtheoffloadprocess.Intheunlikelyeventaspilldoesoccur,allfreeproductisheldwithinthecontainment.Anyrunoffthatenterstheyarddrainsystemisretainedbythevalveatthebasin.Anyandallfreeproductisproperlyremovedpriortotheopeningofthebasinvalve.Clam-trolCT-1(orotherzebramusselcontrolbiocides)-AreappliedviatankertrucksstagedattheNorthChemicalUnloadingArea.Yarddrainbasinsinthisareaareinstalledwithavalve,whichisclosedduringtheapplicationprocess.Intheunlikelyeventaspilldoesoccur,allfreeproductisretainedwithinthecontainment.Anyrunoffthatenterstheyarddrainsystemisretainedbythevalveatthebasin.Anyandallfreeproductisproperlyremovedpriortotheopeningofthebasinvalve.Companyproceduresareusedtoapplythischemical.Basindrainsinthevicinityofthechemicalspargersaredikedtopreventreleaseofthischemicaltotheyarddrainsystem.Herbicides-ThesematerialsareusedinvariousareasthroughouttheCookPlantproperty.Nobulkquantitiesofthesematerialsarestoredonsite.Allquantities.areorderedandmixedbeforeapplicationsprovidedbyanoffsitevendor.AttachmentB-Iliststheherbicidereportsforthepastthreeyears.Thesereportsdescribeapplicationlocations,quantity,andtypeofmaterialused. ATTACHMENTB(cont.)Non-radioactiveWasteOilandNon-HazardousWastes-Anaboveground2,000gallonconcretevaulted(Convault)wasteoiltankislocatedwithinacontainmentareadirectlynorthoftheNorthChemicalUnloadingArea.Thestormwaterbasinwithinthisareaiscoveredwitharubbergasketedsteelcover.Drainingofstormwater,andloadingandunloadingofwasteoilinthisarea,isperformedbyqualifiedpersonnel.Barrelsofwasteoilsandothernon-hazardouswastesincludinghydraulicoil,EPA2000andglycolwaitingprocessingarealsoaccumulatedinthisarea.RadioactiveWasteOil-One1,500gallonradioactivewasteoiltankislocatedintheNorthChemicalUnloadingArea.Radioactivewasteoilisprocessedinaccordancewithplantprocedures.SpillsfromthistankwouldbecontainedwithintheNorthChemicalUnloadingArea.SodiumNitrite(CalgonLCS-60)-AddedasacorrosioninhibitorinmanyofthePlant'sclosedcoolingsystems.Theseincludethecomponentcoolingwatersystem,dieseljacketcoolingwatersystem,andairconditioningandheatingsystemsontheplantsite.ThepotentialofsodiumnitritecontaminatingthestormwatersystemismostlikelyintheofficebuildingHVACsystemswheresmallamountsofsodiumnitritesolutionmayleaktocondensatedrainsandintooutfall001S.Storageofthischemicalisinbulkdrumsvyhichposenothreattothestormwatersystem.EthyleneGlycol-Usedasarefrigerantintheplant'scontainmenticecondensersystemandalsointhetrainingsimulatorchillersystem.Leaksfromtheplant'scontainmenticecondensersystemarecontainedandcollectedwithintheconfinesoftheauxiliarybuildingandreactorcontainments.Leaksfromthetrainingsimulatorchillersystemarecontainedanddrummed.Theresultingethyleneglycol/watersolutionscanalsobecollectedinthetemporaryglycolstoragetanklocatedwithintheNorthChemicalUnloadingArea.Periodically,atemporaryprocessingunitiserectedontheplantsitetoprocessthecollectedethyleneglycol/watersolution.Theprocessisasfollows:Hydrogenperoxide(35%)foroxidationandsodiumhydroxide(50%)forpHbalanceareaddedtotheglycol/watersolutionandintroducedintoaUVlightcell.Ethyleneglycolisbrokendownintocarbondioxideandorganicacids.Theprocessingunitiscompletelybermedandprocessingisperformedundercontinuoussupervisionoftheprocessingcontractorwithoversightfromplantstaff. ATTACHMENTB(cont.)Make-upPlantRegenerationWaste-AfterJanuary1995,acidicandcausticwastesolutionsproducedfromregenerationoftheMake-upPlantresin'bedswillberoutedtotheMake-upPlantNeutralizationTanklocatedimmediatelywestoftheUnit2TurbineBuilding.SulfuricAcidorsodiumhydroxideareaddedtoneutralizethewastesinthetankbeforetheyareeventuallydrainedandpumpedtotheturbineroomsumpforreleasetotheonsiteabsorptionpond.Thetankisofadouble-walledconstructionwithbothwallshavingbeenhydro-tested.Theinnertankisequippedwithlevelalarminstrumentation.Theoverflowfortheinnertankisroutedtotheinterstitialspacebetweenthetankwalls.Thisspacecanbevisuallyinspectedanddrainedunderplantsupervision.Pipingisabovegroundandheattraced.Anyleakinthispipingwouldbeeasilydetectedandrepaired.LowLevelRadioactiveCorrosionProducts-Duringoutageperiods,lowlevelradioactivecorrosionproductsaresludge-lancedfromthesteamgenerators.Ahighpressuredemineralizedwaterhoseisusedtocleanoutthecorrosionproductswhichcollectatthetubesheet.Theresultingsolutionisremovedandprocessedbyacontractorwithoversightbyplantpersonnel.Thesludge-lanceunitandauxiliaryequipmentarecompletelybermedwiththeprobabilityofareleasefromthissystemtothestormwatersystemunlikely.SewageSludge-SewagesludgeiscollectedinatemporarytanklocatedatthesouthendoftheSouthSewageTreatmentPlant.Transferringofsludgeisperformedbythesewagewastecontractorunderthesupervisionofplantpersonnel.o.ChemicalsAwaitingStorage-Forbriefperiods,portablebulktanksandpalletscontainingchemicalsindrumsareoff-loadedontotheloadingdockintheshippingandreceivingareauntiltheycanbeplacedintostorage.Deliveriesaremadetotheplantprotectedareaviatrucksandforklifts,andplacedinside'theTurbineBuildingorotherareaswhereneeded.p.ChemicalCleaningofHeatExchangers4Piping-Oxidizersandorganicacidsareusedtocleanheatexchangersandpipingaroundtheplantsite.Thecleaningequipmentiscontainedandoperatedbycontractorswithoversightbyplantsupervision.Allotherchemicalmaterialsarestoredwithintheconfinesofvariousbuildingsandarenotconsideredtobeathreattotheyarddrainagesystem. ATTACHMENTB(cont.)C.ControlMethodsbyOutfall(refertotable2F-1forcodes)001S&002S-Containmentareasandbasinvalvesarestructuralandmechanicalcontrolmeasuresinplaceforthesetwooutfalls.'naddition,containmentoilboomsarestrategicallyplacedattheoutletsofthesetwooutfalls.Theseboomswillaidinthecontainmentandabsorptionofanycontaminantsshouldothercontainmentsystemsfail.Theseboomsareinspectedandreplacedroutinely.TreatmentCode:4-A(dischargetoopenwater)003S&004S-Riskofcontaminantsfromthesetwooutfallsisnegligible,therefore,nocontrolmeasuresareinplaceatthistime.TreatmentCode:4-A(dischargetoopenwater) ATTACHMENTB-1 ATTACHMENTB-1D.C.CookPlantSUMMARYOFPROGRAM-1991HerbicideSprayReportFromApril22-May1,1991,TownsendTreeServiceappliedamixtureofKarmex,AmizineandOusttocontrolweedgrowthonthePlantSite.Atotalof48lbs.ofKarmex,560lbs.ofAmizineand2IbsofOustwasappliedover36acres.Thefollowingareaswereinspectedandtreatedforweeds:l.2.3.45.6.7.8.9.10.11.12.13.14.15.16.17.18.19.SewagePondsRoadtoAbsorptionPond765KvSwitchgearYard345KvSwitchgearYardRailroadTrackseastofTrainingCenterParkinglotB69KvSwitchgearYardNorthProtectedAreaFenceSouthProtectedAreaFenceEastProtectedAreaFenceICMSOfficeTrailerICMSFabShopSouthwestsideofTurbineBuildingSouthendofTurbineBuildingUnit1RWSTAreaUnit2RWSTAreaHydrogen/NitrogenStorageTankAreaConstructionFabShopRoadtoMeteorologicalTowersBaseduponreviewofapplicationrecordsandobservationsofthetreatedareas,itappearsthattheherbicideswereappliedinaccordancewithherbicidelabelrequirements,andnoadverseenvironmentaleffectsoccurred. ATTACHMENTB-1(cont.)SUMMARYOFPROGRAM-1992HerbicideSprayReportFromJune3-7,1992,TownsendTreeServiceappliedamixtureofStompandOusttocontrolweedgrowthonthePlantSite.Atotalof91.2quartsofStompand91.2ouncesofOustwereappliedover36acres.Themanufacturer'slabelrecommendsthatStompbeappliedatarateofbetween2-4quartsperacre.Stompwasappliedatarateof2.7quartsperacre.Themanufacturer'slabelrecommendsthatOustbeappliedupto12ouncesperacre.Oustwasappliedatarateof2.7ouncesperacre.Thefollowingareaswereinspectedandtreatedforweeds:l.2.3.45.6.7.8.9.10.11.12.13.14.15.16.17.18.19.SewagePondsRoadtoAbsorptionPond765KvSwitchgearYard345KvSwitchgearYardRailroadTrackseastofTrainingCenterParkinglotB69KvSwitchgearYardNorthProtectedAreaFenceSouthProtectedAreaFenceEastProtectedAreaFenceICMSOfficeTrailerICMSFabShopSouthwestsideofTurbineBuildingSouthendofTurbineBuildingUnit1RWSTAreaUnit2RWSTAreaHydrogen/NitrogenStorageTankAreaConstructionFabShopRoadtoMeteorologicalTowersBaseduponreviewofapplicationrecordsandobservationsofthetreatedareas,itappearsthattheherbicideswereappliedinaccordancewithherbicidelabelrequirements,andnoadverseenvironmentaleffectsoccurred. ATTACHMENTB-1(cont.)SUMMARYOFPROGRAM-1993HerbicideSprayReportFromMarch8-October5,1993,variouscontractorshaveappliedamixtureofTrimec899,Orthene75s,Stomp,Oust,Roundup,andTri-powertocontrolweedgrowthonthePlantSite.Atotalof270ouncesofTrimec899,2lbs.ofOrthene75s,103.5quartsofStomp,103.5ouncesofOust,214ouncesofRoundup,and298.4ozofTri-powerwereappliedover36acres.Allwereappliedaspermanufacturers'abelsrecommendations.Thefollowingareaswereinspectedandtreatedforweeds:l.2.3.45.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.SewagePondsRoadtoAbsorptionPond765KvSwitchgearYard345KvSwitchgearYardRailroadTrackseastofTrainingCenterParkinglotB69KvSwitchgearYardNorthProtectedAreaFenceSouthProtectedAreaFenceEastProtectedAreaFenceICMSOfficeTrailerICMSFabShopSouthwestsideofTurbineBuildingSouthendofTurbineBuildingUnit1RWSTAreaUnit2RWSTAreaHydrogen/NitrogenStorageTankAreaConstructionFabShopRoadtoMeteorologicalTowersEnergyInformation.CenterLawnBaseduponreviewofapplicationrecordsandobservationsofthetreatedareas,itappearsthattheherbicideswereappliedinaccordancewithherbicidelabelrequirements,andnoadverseenvironmentaleffectsoccurred. ATTACHMENTB-2 ATTACHMENTB-2THERPOTENTIALEXPOURESTOTORMWATERThereareseven(7)potentialareasofconcernwhichapplytothissectionwhichareasfollows:1.LubeOilVaporExtractors-locatedatvarioussitesontheroofoftheturbinebuilding.Smallamountsofoilvapordroplets(MobileDTE797)havethepotentialtobespilledontotheroof.Duringrainperiodsthisoilmaterialwouldeventuallybewashedintotheroofdrainsystem.FromthispointitwouldentertheyarddrainsandbereleasedtoLakeMichiganasdepictedinthefollowingdiagram:.Col~TwgINV~Dwtlrl~yIH~Awe~LootSnla~~IW4%1oVe4WwtTIEtinelol1RloW2.SteamGeneratorBlowdowns-Two(2)blowdownoutletsarelocatedontheeastsideoftheAuxiliaryBuilding.Thesteamgeneratorsarepurgedofcorrosionproductsperiodicallytopreventdegradationtothesteamgeneratortubes.Largeamountsofsteam,whichmaycontaintraceamountsoforganics,ethanolamine,andboricacidarereleasedintotheairoutsidetheplant.Theproductsinthesteamprecipitatetothegroundandeventuallyentertheyarddrainsystemasdemonstratedinthefollowingdiagram:Note:Waterusedinthissystem(toformthesteam)isultra-purifiedlakewater.Thiswaterundergoesstringentpurificationprocessbeforeitentersthesystem. 3.DumpsterCleaning-DumpsterCleaningMaincondensercoolingwaterisscreenedthrough3/8"meshtravelingscreensbeforepassingthroughthemaincirc.waterpumpandservicewaterpumpinlets.Materialsimpingedonthesescreensincludingsticks,leaves,zebramussels,andfish,areroutinelybackwashedinto,atrenchandsluicedtobothendsoftheScreenhouseintodebriscollectionbaskets.ThesecollectionbasketsarethendumpedintodumpsterswhicharehauledofFtheplantsitebyalocal.wastehauler.Forpublichealthreasons,thesedumpstersarecleanedoutperiodically.Pathfinder,alowsudscleaner,isusedwithwatertowashoutthesedumpsters.Thewashwaterflowsdownayarddrainandoutoutfall001S.Outfall001aBar.IaLsk0Mictagata~NSteanDcaaa~IOucataaaiIXIANgp'alctPip~ 4.RoadwaysandParkingLots-Automobiles,trucks,andheavyequipmentrequiregasoline,dieselfuel,coolants,hydraulicoil,andlubricantsfortheiroperation.SmallleakscaneventuallybewasheddownthestormdrainstoOutfalls001S,002S,003S,and004S.5.GaronDe-Icer95%CalciumChlorideand4%SodiumChloride.Gran-U-Thaw:90%Carbonyldiamine,NitrogenCompounds-Urea.SafeStepAirportIceControl:PotassiumChloride,SodiumChloride,Urea,andMethylglucoside.Manufacturertradesecret,percentagesunavailable.Usedonroads,andsidewalksthroughoutthefacility.ThismaterialwithprecipitationwilleventuallyentertheyarddrainsystemthatflowstoLakeMichiganthroughoutfalls001S,002S,003Sand004S.Theseroadsaltcompoundstendtoleachoilsfromtheasphaltpavementwhicharewashedintotheyarddrainagesystem.UppernmplopaotartloSLoi+MemtalDrahapaCgTralslspBsUSiaptarplspLoi~7thaihroaaRosaSMaraaltC>5UpphSssdkaaairlsStarlls5LosVlrlmitartlspLsiStormDralaa~ 6.FireProtectionSystems-Toeliminatethethreatofzebramusselinfestationinitsfireprotectionsystem,theplantconvertedfromlakewatertoachlorinatedmunicipalwatersupply.Two650,000gallontankslocatedsouthoftheplantsiteprovidestorageforthefireprotectionwater.Thetanksareequippedwithanalarmsystem.TheoverflowanddrainageforthesetanksaretotheyarddrainagesystemOutfall003S.Onoccasionthesetanksaredrainedtoperformrepairs.Periodically,thefireprotectionsystemheaderandhydrantsareflowtestedwiththewaterbeingdirected'totheyarddrainsystem.Outfalls001S,002S,003S,and004Sareimpactedbythesebythistestingprocedure.Thefollowingdiagramillustratesthetestinganddrainingprocess:FkePrccccacaWacrTcrkeBeneToYardDrainS)rtpl))careIBoreTotakeMictatna7.LawnSprinklerSystem-Theplantlawnsprinklersystemisoperatedusingbothcirculatingwaterandmunicipalwatersupplies.SmallamountsofchlorinearecontainedinthemunicipalwaterandinthecirculatingwaterwhichcanenterthestormwaterdrainagesystemandOutfall001S.Refertothefollowingdiagramforfurtherinformation.TramnaCornerPoetIOaeManOonrdBonneEncrtyInfonnaioaCornerOf5ceBai)dmSLekeMictntnaWaerScrotaW~PornpRhtcrrnkt~C)dorimtcdFromDr~tTannelBoerToYcrdDreinS)rtemDac~ToLake'ceOOIS)bkorinaedWacrFromLateTocrnetop ATTACHMENTC ATTACHMENTCINIFIANTLEAKSORSPILLS(pastthreeyears)OnFebruary15,March4,andMarch22,1993,CookPlantpersonnelobservedaslightsheenonthesurfaceofLakeMichigan,adjacenttotheplant'sstormwaterdischarges.SubsequentinvestigationofplantoilsystemsandoperationsprovedthesourcetobeoilresiduefromemployeevehiclesenteringthestormwatercollectionsystemfromparkinglotrunofKAttemptsweremadetopreventadditionaloilfromenteringthecatchbasinsbytheuseofabsorbentboomsonallthreeoccasions.Asummaryofeacheventisasfollows:February15,1993March4,1993OilsheenfromOutfalls001Sand002SOilsheenfromOutfall001SMarch22,1993OilsheenfromOutfall001S ATTACHMENTD(ANALYTICALRESULTS) ATTACHMENTD**DESCRIPTIONOFRAINFALLEVENT**Fourteenone-hundredthsofaninch(0.14)ofrainfellonDecember18,1993.Theeventstartedat0630hrs.and.terminatedat1000hrs.Outfalls001S,002S,003S,and004Scontinuedtoflowatarateof1-2liters/min.until1100hrs.Theprevioussignificanteventterminatedat1400hrs.onDecember6,1993foratotalelapsedtimeof280.5hrs.betweenevents.**SAMPLINGMETHOD**BothgrabandflowcompositesamplesweretakenduringthesinglestormeventofDecember18,1993.Stormwateroutfalls001S,002S,and003Sweresampled.SincetheoutfallcharacteristicsofOutfall003Sand004Sareessentiallyidentical,andinverycloseproximity,Outfall004Swasnotsampled.BothOutfall003Sand004Sreceivegroundwaterwhichemergesfromthebaseofaduneandcollectsinatrencheastoftheoutfalls.Thisgroundwatermixeswithstormwaterrunofffromtheparkinglotsandroadwayssouthoftheplantandflowsthroughoutfalls003Sand004StoLakeMichigan.Forpurposesofthischaracterizationstudy,samplesweretakenofOutfall003Sbothbeforeandaftermixingwithgroundwaterduringthestormevent.Theresultsoftheanalysesareshowninthefollowingpages. ATTACHMENTDVII.DischargeInformationPARTA0TFALL001SMaximumValuesAverageValuesPollutantandCASNumber(ifavailable)GrabSampleTakenDuringFirst30MinutesFlow-weightedCompositeGrabSampleTakenDuringFirst30MinutesFlow-wcightcdCompositeNumberofStormEventsSampledSourcesofPollutantsOilandGreaseBiologicalOxygenDemand(BOD5)3.6mg/I2.8mg/I4.8mg/I3.2mg/I3.6mg/I4.8mg/I2.8mg/I3.2mg/IStormwaterrunoffStormwaterrunoffChemicalOxygenDemand(COD)TotalSuspendedSolids(TSS)37mg/I34mg/I<18mg/I13mg/I37mg/I34mg/I<18mg/I13mg/IStormwaterrunoffStormwaterrunoffTotalKjeldahlNitrogenNitrateplusNitriteNitrogenTotalPhosphorus4.9mg/I3.7mg/I1.5mg/I1.8mg/I0.19mg/I0.11mg/I4.9mg/I1.5mg/I0.19mg/I3.7mg/I1.8mg/I0.11mg/IStormwaterrunoffStormwaterrunoffStormwaterrunoffpHMinimum7.4Maximum7.4 XTYACHMENTD(cont.)PartAOUTFALL002SMaximumValuesAverageValuesPollutantandCASNumber(ifavailable)GrabSampleTakenDuringFirst30MinutesFlow-weightedCompositeGrabSampleTakenDuringFirst30MinutesFlow-weightedCompositeNumberofStormEventsSampledSourcesofPollutantsOilandGreaseBiologicalOxygenDemand(BOD5)ChemicalOxygenDemand(COD)TotalSuspendedSolids(TSS)<1mg/I<1mg/I1.5mg/I2.9mg/I<12mal<12mg/I<18mg/I<18mg/I<Img/I1.5mg/I<18mg/I<12mg/I<1mg/I2.9mg/I<18mg/I<12mg/IStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffTotalKjeldahlNitrogen20mg/I13mg/I20mg/I13mg/IStormwaterrunoffNitrateplusNitriteNitrogenTotalPhosphorus5.6mg/I3.2mg/I0.14mg/I0.20mg/I5.6mg/I0.14mg/I3.2mg/I0.20mg/IStormwaterrunoffStormwaterrunoffpHMinimum7.9Maximum8.4 ATTACHMENTD(cont.)'PartAOUTFALL003S(Beforemixingwithgroundwater)MaximumValuesAverageValuesPollutantandCASNumber(ifavailable)GrabSampleTakenDuringFirst30MinutesFlow-weightedCompositeGrabSampleTakenDuringFirst30MinutesFlow-weightedCompositeNumberofStormEventsSampledSourcesofPollutants'ilandGreaseBiologicalOxygenDemand(BOD5)2.1mg/12.7mg/11.8mg/12.6mg/12.1mg/11.8mg/12.7mg/12.6mg/1StormwaterrunoffStormwaterrunoffChemicalOxygenDemand(COD)18mg/119mg/118mg/119mg/1'tormwaterrunoffTotalSuspendedSolids(TSS)TotalKjeldahlNitrogenNitrateplusNitriteNitrogenTotalPhosphorus23mg/12.0mg/10.78mg/10.29mg/I15mg/12.1mg/I1.0mg/10.36mg/123mg/115mg/12.0mg/12.1mg/10.78mg/11.0mg/10.29mg/10.36mg/1StormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffpHMinimum7.5Maximum7.5 <<.TTACHMEI<<ITD(cont.)PartAOUTFALL003S(Aftermixingwithgroundwater)MaximumValuesAverageValuesPollutantandCASNumber(ifavailable)GrabSampleTakenDuringFirst30MinutesFlow-weightedCompositeGrabSampleTakenDuringFirst30MinutesFlow-weightedCompositeNumberofStormEventsSampledSourcesofPollutantsOilandGreaseBiologicalOxygenDemand(BODS)2.2mg/I1.8mg/I2.2mg/I2.9mg/I1.8mg/I2.9mg/I1.8mg/I1.8mg/IStormwaterrunoffStormwaterrunoffChemicalOxygenDemand(COD)TotalSuspendedSolids(TSS)26mg/I19mg/I<18mg/I<12mg/I26mg/I19mg/I<18mg/I<12mg/IStormwaterrunoffStormwaterrunoffTotalKjeldahlNitrogenNitrateplusNitriteNitrogenTotalPhosphorus1.6mg/I0.90mg/I1.6mg/I1.1mg/I2.2mg/I1.1mg/I0.23mg/I0.13mg/I0.23mg/I0.90mg/I2.2mg/I0.13mg/IStormwaterrunoffStormwaterrunoffStormwaterrunoffpHMinimum7.7Maximum8.0 .O'TACHMENTD(cont.)VII.DischargeInformationPARTBOUTFALL001SMaximumValuesAverageValuesPollutantandCASNumber(ifavailable)GrabSampleTakenDuringFirst30MinutesFlow-weightedCompositeGrabSampleTakenDuringFirst30MinutesFlow-weightedCompositeNumberofStormEventsSampledSourcesofPollutantsCadmium<.005mg/I<.005mg/I<.005mg/I<.005mg/IStormwaterrunoffChlorideChlorine(totalresidual)36mg/I<0.02ppm46mg/I36mg/I<0.02ppm46mg/IStormwaterrunoffStormwaterrunoffCopperSulfate13mg/I16mg/I13mg/I<.025mg/I<.025mg/I<.025mg/I<.025mg/I16mg/IStormwaterrunoffStormwaterrunoffTotalDissolvedSolids(TDS)93mg/I160mg/I93mg/I160mg/IStormwaterrunoffZinc0.31mg/I0.21mg/I0.31mg/I0.21mg/IStormwaterrunoff TTACHMENTD(cont.)PARTBOUTFALL002SMaximumValuesAverageValuesPollutantan'dCASNumber(ifavailable)GmbSampleTakenDuringFirst30MinutesFlow-weightedCompositeGrabSampleTakenDuringFirst30MinutesFlow-weightedCompositeNumberofStormEventsSampledSourcesofPollutantsCadmiumChloride<.005mg/I<.005mg/I<.005mg/I2.9mg/I3.4mg/I2.9mg/I<.005mg/I3.4mg/IStormwaterrunoffStormwaterrunoffChlorine(totalresidual)<0.02ppm<0.02ppmStormwaterrunoffCopperSulfateTotalDissolvedSolids(TDS)Zinc18mg/I26mg/I18mg/I83mg/I100mg/I83mg/I0.46mg/I0.22mg/I0.46mg/I0.029mg/I<.025mg/I0.029mg/I<.025mg/I26mg/I100mg/I0.22mg/IStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoff <<TTACHMENTD(cont.)PARTB"OUTFALL003S(beforemixingwithgroundwater)MaximumValuesAverageValuesPollutantandCASNumber(ifavailable)GrabSampleTakenDuringFirst30MinutesFlow-weightedCompositeGrabSampleTakenDuringFirst30MinutesFlow-weightedCompositeNumberofStormEventsSampledSourcesofPollutantsCadmiumChlorideChlorine(totalresidual)CopperSulfateTotalDissolvedSolids(TDS)Zine<.025mg/I<.025mg/I3.4mg/I4.0mg/I88mg/I93mg/I0.28mg/I0.29mg/I<.005mg/I<.005mg/I0.75mg/I0.86mg/I<0.02ppm<.005mg/I0.75mg/I<0.02ppm<.025mg/I3.4mg/I88mg/I0.28mg/I<.005mg/I0.86mg/I<.025mg/I4.0mg/I93mg/I0.29mg/IStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoff 4.TTACHMENTD(cont.).PARTBOUTFALL003S(aftermixingwithgroundwater)MaximumValuesAverageValuesPollutantandCASNumber(ifavailable)GrabSampleTakenDuringFirst30MinutesFlow-weightedCompositeGrabSampleTakenDuringFirst30MinutesFlow-weightedCompositeNumberofStormEventsSampledSourcesofPollutantsCadmiumChlorideChlorine(totalresidual)Copper<.005mg/I1.5mg/I<0.02ppm<.025mg/I<.005mg/I<.005mg/I<.005mg/I4.5mg/I1.5mg/I4.5mg/I<0.02ppm<.025mg/I<.025mg/I<.025mg/IStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffSulfate25mg/I120mg/I25mg/I120mg/IStormwaterrunoffTotalDissolvedSolids(TDS)97mg/I370mg/I97mg/I370mg/IStormwaterrunoffZinc0.25mg/I0.13mg/I0.25mg/I0.13mg/IStormwaterrunoff ',TTACHMENTD(cont.)VII.DischargeInformationPARTCOUTFALL001SMaximumValuesAverageValuesPollutantandCASNumber(ifavailable)GrabSampleTakenDuringFirst30MinutesFlow-weightedCompositeGrabSampleTakenDuringFirst30MinutesFlow-weightedCompositeNumberofStormEventsSampledSourcesofPollutantsAluminumBariumBoronCobalt0.79mg/I0.41mg/I<.20mg/I<.20mg/I<.20mg/I<.20mg/I<0.05mg/I<0.05mg/I0.79mg/I<.20mg/I<.20mg/I<0.05mg/I0.41mg/I<.20mg/I<.20mg/I<0.05mg/IStormwaterrunoff.StormwaterrunoffStormwaterrunoffStormwaterrunoffIron1.6mg/I0.7mg/I1.6mg/I0.7mg/IStormwaterrunoffLeadMagnesiumMolybdenumSurfactantsSulfideTinRadioactivity(alpha)Radioactivity(beta)6.9pCi/14.3pCi/I0.049mg/I0.016mg/I<5.0mg/I<5.0mg/I<0.2mg/I<0.2mg/I0.060mg/I0.029mg/I<3.0mg/I<3.0mg/I<0.2mg/I<0.2mg/I2.1pCi/10.69pCi/10.049mg/I<5.0mg/I<0.2mg/I0.060mg/I<3.0mg/I<0.2mg/I2.1pCi/I6.9pCi/I0.016mg/I<5.0mg/I<0.2mg/I0.029mg/II<3.0mg/I<0.2mg/I0.69pCifl4.3pCi/IStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoff10 ATTACHMENTD(cont.)PA'RTCOUTFALL002SMaximumValuesAverageValuesPollutantandCASNumber(ifavailable)GrabSampleTakenDuringFirst30MinutesFlow-weightedCompositeGrabSampleTakenDuringFirst30MinutesFlow-weightedCompositeNumberofStormEventsSampledSourcesofPollutantsAluminumBariumBoronCobaltIronLeadMagnesiumMolybdenumSurfactantsSulfideRadioactivity(alpha)0.26mg/I<0.20mg/I0.26mg/I<0.20mg/I<0.20mg/I<0.20mg/I<0.20mg/I<0.20mg/I<0.20mg/I<0.05mg/I<0.05mg/I<0.05mg/I0.73mg/I0.40mg/I0.73mg/I0.0048mg/I0.0032mg/I0.0048mg/I<5.0mg/I<5.0mg/I<5.0mg/I<0.2mg/I<0.2mg/I<0.2mg/I0.029mg/I0.031mg/I0.029mg/I<3.0mg/I<3.0mg/I<3.0mg/I<0.2mg/I<0.2mg/I<0.2mg/I0.54pCi/I0.64pCi/I0.54pCi/I<0.20mg/I<0.20mg/I<0.20mg/I<0.05mg/I0.40mg/I0.0032mg/I<5.0mg/I<0.2mg/I0.031mg/I<3.0mg/I<0.2mg/I0.64pCi/IStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffRadioactivity(beta)7.0pCi/I4.7pCi/I7.0pCi/I4.7pCi/1Stormwaterrunoff11 ,TTACHMENTD(cont.)PARTCOUTFALL003S(beforemixingwithgroundwater)MaximumValuesAverageValuesPollutantalldCASNumber(ifavailable)GrabSampleTakenDuringFirst30MinutesFlow-weightedCompositeGrabSampleTakenDuringFirst30MinutesFlow-weightedCompositeNumberofStormEventsSampledSourcesofPollutantsAluminumBariumBoronCobaltIronLeadMagnesiumMolybdenumSurfactantsSulfideTlnRadioactivity(alpha)1.2mg/I0.85mg/I1.2mg/I<0.20mg/I<0.20mg/I<0.20mg/I<0.20mg/I<0.20mg/I<0.20mg/I<0.05mg/I<0.05mg/I<0.05mg/I2.5mg/I1.7mg/I2.5mg/I0.0096mg/I0.0063mg/I0.0096mg/I<5.0mg/I<5.0mg/I<5.0mg/I<0.2mg/I<0.2mg/I<0.2mg/I0.043mg/I0.049mg/I0.043mg/I<3.0mg/I<3.0mg/I<3.0mg/I<0.2mg/I<0.2mg/I<0.2mg/I1.63pCi/I0.73pCi/11.63pCi/10.85mg/I<0.20mg/I<0.20mg/I<0.05mg/I1.7mg/I0.0063mg/I<5.0mg/I<0.2mg/I0.049.mg/I<3.0mg/I<0.2mg/I0.73pCi/IStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffRadioactivity(beta)5.2pCi/I3.1pCi/I5.2pCi/I3.1pCi/1Stormwaterrunoff12 ~.TTACHMENTD(cont.)PARTC"OUTFALL003S(aftermixingwithgroundwater)MaximumValuesAverageValuesPollutantandCASNumber(ifavailable)GrabSampleTakenDuringFirst30MinutesFlow-weightedCompositeGrabSampleTakenDuringFirst30MinutesFlow-wcightcdCompositeNumberofStormEventsSampledSourci:sofPollutantsAluminumBariumBoronCobaltLeadMagnesiumMolybdenumSurfactantsSulfideRadioactivity(alpha)Radioactivity(beta)1.2mg/I<0.20mg/I<0.20mg/I<0.05mg/I0.0082mg/I<5.0mg/I<0.2mg/I0.031mg/I<3.0mg/I<0.2mg/I1.2pCi/15.0pCin1.1pCi/11.2pCi/11.1pCin4.3pCi/I5.0pCi/I4.3pCi/I0.46mg/I1.2mg/I0.46mg/I<0.20mg/I<0.20mg/I<0.20mg/I<0.20mg/I<0.20mg/I<0.20mg/I<0.05mg/I<0.05mg/I<0.05mg/I0.94mg/I2.3mg/I0.94mg/I0.0031mg/I0.0082mg/I0.0031mg/I14.0mg/I<5.0mg/I'4.0mg/I<0.2mg/I<0.2mg/I<0.2mg/I0.031mg/I0.031mg/I0.031mg/I<3.0mg/I<3.0mg/I<3.0mg/I<0.2mg/I<0.2mg/I<0.2mg/IStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoffStormwaterrunoff13 ATTACHMENTE(DRAWINGS) DRAWINGNUMBERDESCRIPTION0102030405060708091011A11BENTIREPROPERTYPLANTWITH001S&002SPLANTWITH001SONLYPLANTWITH002SONLYTRAININGCENTERANDROADAREA(OUTFALL001S)SOUTHAREAWITH003S2004SENERGYINFORMATIONCENTERAREAPOST1GUARDHOUSEAREAPERVIOUS/IMPERVIOUSDRAINAGEAREASHERBICIDEAPPLICATIONAREASTOPOMAP(BRIDGMAN)TOPOMAP(COOKPLANT) IndianaMichiganPowerCompanyO."eSLrnninSoearePaBox60For;'Boynelixed.'6691219'252111CERTIFIEDMAILfZ756046675liltINDIANANICHIGiANPOWERMr.WilliamE.McCrackenSurfaceWaterQualityDivisionPermitsSectionDepartmentofNaturalResourcesP.0.Box30028Lansing,MI48909March31,1994
DearMr.McCracken:
Sub)ect:IndianaMichiganPowerCompanyDonaldC.CooknuclearPlantNPDESPermitNo.MI0005827RenewalApplicationEnclosedistheIndustrialandCommeicialWastewaterDischargeApplicationforrenewaloftheCookNuclearPlantNPDESPermit.Alsoenclosed,isfor2PforrenewaloftheCookNuclearPlantStormWaterDischargePermit.Theseapplicationsarebeingsubmitted180dayspriortotheexpirationofthepresentpermit.CookNuclearPlantalsohassubmittedaseparategroundwaterpermitapplicationtotheagency'sgroundwaterdivision;theinformationisalsoenclosedwiththisapplication.Duringthetermofthepresentpermit,severalpermitmodificationsweremadetoimproveCookNuclearPlantoperations.Weappreciateyoureffortsinthesepermitmodifications.AdditionalchangesareunderdevelopmentwhichwillaffectCookNuclearplantoperations.Informationregardingtheseimprovementsisenclosedwiththefollowingattachments:AttachmentDescritionMakeupDemineralizerRegenerationWasteNeutralizationSystemSequencingBatchReactorsZebraMusselControlStrategyAlumReplacementProgramChemistryCorrosionControlAdditivesThermalEffluentShouldyouhaveanyquestionsregardingtheserenewalapplications,pleasecontactJohnCarlson,CookNuclearPlant March31,1994Mr.WilliamE.McCrackenPage2EnvironmentalSupervisor,at(616)465-5901ext.1153,ormeat(219)425-2118.Wewouldbehappytomeetwithyouatyourconveniencetodiscusstheapplication.verytrulyyours,DonaldL.BakerEnvironmentalAffairsDirectorDLB/sdb/065,66AttachmentscertifyunderpenaltyoflawthatIhavepersonallyexaminedand'amfamiliarwiththeinformationsubmittedonthisandallattacheddocuments;andbasedonmyinquiryofthoseindividualsimmediatelyresponsibleforobtainingtheinformation,Ibelievethesubmittedinformationistrue,accurateandcomplete.Iamawarethattherearesignificantpenaltiesforsubmittingfalseinformation,includingthepossibilityoffineandimprisonment.DonaldL.Baker March31,1994Mr.WilliamE.McCrackenPage3bc:W.N.D'Onofrio/M.A.Bailey/J.L.HugheyA.A.BlindS.J.BrewerD.M.Fitzgerald/J.P.CarlsonE.E.FitzpatrickD.W.Kemp/K.D.HackT.E.Webb/J.P.Novotony
Attachment1MakeupDemineralizerRegenerationWasteNeutralizationSystemCookNuclearPlantisinstallingasystemtocollectandtreatmakeupdemineralizerregenerationwastestomeetproposedpHpermitlimits.ThecurrentpracticeistoisolatetheTurbineRoomSump(TRS),accumulatethewasteswithintheTRS,neutralizethewastewithsulfuricacidorsodiumhydroxide,andthendischargetheneutralizedcontentsof.theTRStotheAbsorptionPond.BecausetheregenerationwastesarenottheonlysourceofwaterbeingcollectedintheTRS,ahighwaterlevelwithintheTRSmayrequirethedischargeofthesumpcontentspriortothewastesbeingcompletelyneutralized.IThenewsystemvillallowcollectionandneutralizationoftheregenerationwastesapartfromtheTRS.Theholdingtankforthewastewillalsobethepoint.oftreatmentwiththecapabilitytoaddandmixsulfuricacidorsodiumhydroxidewiththewastepriortometeringtheneutralmixturetotheTRS.ThetotalcostoftheMakeupDemineralizationWasteSystemis$3,600,000.00.ThesystemistargetedforcompletionbyJanuaryof1995,withsystemstart-uptooccurthereafter. Attachment2SequencingBatchReactorsCookNuclearPlantiscurrentlyrequestingquotationstoinstallapairofpre-engineeredsequencingbatchreactors(SBR)tomeettheproposedgroundwatereffluentlimits.Thenewsystemwilloperateatadesignflowof50,000GPDwithamaximumflowof60,000GPD.TheSouthExtendedAerationPackagePlantwillbeutilizedasaretentiontanktoensureefficientSBRoperation.Effluentfromthenewsystemwillcontinuetobedischargedintooneofthetwoseepagelagoons.ThenewsystemwillbeinstalledandoperationalbyDecemberof1995. Attachment3ZebraMusselControlStrategyZebramusselsareamenacetoanyindustrialormunicipalprocessdrawingwaterfromLakeMichigan.Ourcurrentcontrolplanistochlorinateandperformperiodicshockchemicaltreatmentsutilizingproprietarychemicalformulations.Thismethodofcontrolwasdevelopedforshorttermrelieffromtheeffectsofzebramusselinfestation.WehavealsochangedoursourcewaterforourfireprotectionsystemtoapotablesupplyfromLakeTownship.AfterfouryearsofexperienceindealingwithzebramusselsatCookNuclearPlantandotherGreatLakefacilities,anewstrategyisunderconsiderationtoprotectalloperationsfrominfestation.ThenewstrategyincorporatesintermittentoxidizingbiocidetreatmentsofthecirculatingwatersystembeginningattheintakestructuresinLakeMichigan,continuousoxidizingbiocidetreatmentoftheessentialservicewaterandnon-essentialservicewatersystems,additionofsodiumbisulfatetoreduceanyresidualoxidizingbiocidepriortodischargetoLakeMichigan,andifnecessary,shocktreatmentsutilizingproprietarychemicalformulations.Thegoaloftheprogramisto(1)eradicateexistingpopulationsandcontrolfurthersettlementofzebramusselswithinplantsystemsthatutilizelakewater,(2)reducetheresidualoxidantbeingdischargedtonon-detectablelevels,and(3)reduceoreliminatethenumberofremedialshocktreatmentsnecessarytokillsettledcoloniesofzebramussels.Theproposedoxidizingbiocidetreatmentusessodiumbromideandsodiumhypochlorite,oraproprietarymixturesuchasNalcoActi-Brom,toretardveligersettlementandmaintainmicrobiologicalcontrol.Shouldnon-oxidizingbiocidesberequired,weplantouseeitherBetzCT-2,BetzCT-4,CalgonH-130M,orNalco9210.WerequesttheflexibilitytouseanyFIFRA(FederalInsecticide,Fungicide,andRodenticideAgency)approvednon-oxidizingbiocide.Theconcentrationofanyofthetreatmentchemicalswillbebroughttowithinthewaterqualitybasedeffluentlimits,asrequired,usingformulationsofbentoniteclayorotherappropriatematerial.TheresultantchemicalchangeswillultimatelyaffectdischargestoLakeMichiganviaESW,NESW,andthecirculatingwatersystems,anddischargestothegroundwaterthroughtheturbineroomsump,frompumpsealsandequipmentdrainsofthetreatedsystems.Wemaybeginportionsoftheplan,suchascontinuousoxidizingbiocidetreatmentsoftheESWandNESWsystems,in1994.Portionsoftheplan,wherenewsystemsrequirecapitalexpendituresalongwithdesignandinstallationoftheequipment,willtakelonger.Therefore,theplanmaynotbefullyimplementedforseveralyears.WewillcontinuetoinformtheMDNRofplannedoperationalchangesastheyarefinalized. Attachment4AlumReplacementProgramAChemistryTaskForceisevaluatingchemicalflocculentreplacementsforalum(aluminumsulfate)toimproveperformanceofthemakeupwatersystem.Thereplacementsbeingreviewedaremainlypolymeric'flocculentswhichwillenhancetheremovalofsuspendedsolidsinthepre-filtersandmeetmanufacturerrecommendationsforthewaterenteringthereverseosmosissystem.Therecommendationsfromthetaskforce,onceapproved,willrequireadditionaltimetotestandimplement.Theenvironmentalbenefitofproductsubstitutionisthereducedamountofaluminumwhichwillbedischargedtothegroundwaterthroughtheturbineroomsump.Thescheduledtargetimplementationdatetouseanewflocculentisthefourthquarterof1994. Attachment5ChemistryCorrosionControlAdditivesCookNuclearPlantisevaluatingsubstitutesforthecurrentcorrosioncontroladditivesinthesteamgenerators,plantheatingboiler,feedwaterandcondensatesystems,andclosedheating/coolingsystems.Thesesubstituteswillincludecarbohydrazide,andotheravailableproductsfromchemicalcompaniessuchasBetzorNalco.Theenvironmentalbenefitsoftheseadditivesincludeutilizationofmorebenigncorrosioncontrolproductsorproductsrequiringlowereffectiveconcentrations.UseoftheseproductswillnecessitatedischargetoOutfalls001,002,003,OOA,OOB,OOCandOODinconcentrationstobedetermineduponeffectiveoptimization.Consequently,higherconcentrationsofironandothersystemproductsmaybeseentemporarily. Attachment6Therma1EffluentThecurrentthermaleffluentlimitforthecirculatingwatersystemdischargingtoLakeMichiganis15.5X10'TU/hr.ThisiscalculatedfrommeasurementstakenatOutfalls001and002forUnits1and2,respectively.Atthislimit,theunitsareoperatingwithcalculatedmaximumtemperaturedifferentialsof22.3and18.3degreesFforUnits1and2,respectively.Theunitsarehavebeenrequiredtoreduceloadfrom1004duringthehottestsummermonthstomaintainthethermaldischargewithxnlimits.Inordertomaintain1004loadthroughouttheentireyear,includingthehotsummermonths,weproposeincreasingthethermaldischargelimitto16.25X10'TU/hr.Attheproposedthermaldischarge,thetemperaturedifferentialsarecalculatedtobeapproximately1degreeFgreater<or23.4and19.3degreesFforUnits1and2respectively,usingthesameconditionsasintheabovecalculations.TheincreaseinheatloadanddischargetemperaturetoLakeMichiganareminimalandarenotexpectedtoresultinadverseenvironmentalharminandaroundtheplantdischarges.Asinthepast,themaximuminlettemperaturewhichtheunitscanoperateatfullpoweris87.5degreesF,becauseofthelimitationsonthecontrolroomairconditioningsystem.Themaximumeffluenttemperaturesduring1993were98.7and89.7degreesFforUnits1and2,respectively.NotethatUnit2operatedat704loadduringmostof1993toincreasethetimebetweenrefuelingoutagesofthetwoCookNuclearPlantUnits.IndianaMichiganPowerCompanyfundedoneofthemostextensiveaquaticecologicalresearchprojectsontheGreatLakesfrom1973through1982attheCookNuclearPlant.IndianaMichiganPowerCompany'scontractor,TheUniversityofMichigan,CenterforGreatLakesResearchCenter(thentheGreatLakesResearchDivision),publishedabookin1986thatwasacompilationofthephysical,chemical,andbiologicalstudiesconductedunderthedirectionofDr.JohnC.Ayers.Amongotherconclusions,thesestudiesdocumentedthelackofadverseimpactsfromthethermaldischarge.Thetitlepage,tableofcontents,andlistofpublicationsgeneratedfromtheresearchwerecopiedfromthebookandareattachedtothispermitapplication.ThermalplumemapsweremadeduringdifferentseasonsoftheyeartodeterminetheimpactoftheCookNuclearPlantthermaleffluentonLakeMichigan.Thesemapsshowedthesurfaceareaoftheplumewaswellwithinthe570acremixingzonespecifiedintheNPDESPermitissuedforCookNuclearPlantonDecember27,1974,andmodifiedApril4,1978.Eveninthesimplisticassumptionthata54increaseintheheatrejectionrateresultedinasimilarincreaseofthethermalplumesurfacearea,theresultingplumewouldstillbewellwithinthemixingzonelimit.ThesmallincreaseinthemaximumdeltaTwillnotmeasurablyalterthethermalregimethatalreadyexistsintheimmediatevicxnityofthehighvelocitydischarge.ThethermaldischargefromCookNuclearPlantwasgrantedavariancefrommeetingbestavailabletreatmenttechnologyunderSection316(a)oftheFederalWaterPollutionControlActof1972bytheWaterResourcesCommissioninMay,1977. GREATLAKESRESEARCHDIYISION/PUBLICATION22SOUTHEASTERNNEARSHORELAKEMICHIGAN:IMPACTOFTHEDONALDC.COOKNUCLEARPLANTEditedbyRonaldRossmannGREATLAKESRESEARCHDIVISIONTheUniversityofMichiganAnnArbor,Michigan48109AFINALREPORTTOINDIANA&MICHIGANELECTRICCOMPANY1986 4plCONTENTSINTRODUCTlONRonaldRossmannSEDIMENTSOFSOUTHEASTERNNEARSHORE~LAKEMICHIGANRonaldRossmann,Kjel/A.Johansen,andErwinSeibel...............WATERSOFSOUTHEASTERNNEARSHORELAKEMICHIGANRonaldRossmannIMPACTOFTHEDONALDC.COOKNUCLEARPLANTONPHYTOPLANKTONRonaldRossmann,WilliamY.B.Chang,JamesA.Bowers,LaurieFeldt,andJamesBarresPHYTOPLANKTONPOPULATIONSOFSOUTHEASTLAKEMICHIGAN1974-1982JamesA.Bowers,RonaldRossmann,JamesBarres,andWilliamY.B.ChangIMPACTOFTHEDONALDC.COOKNUCLEARPLANTONZOOPLANKTONINSOUTHEASTERNLAKEMICHIGANMarleneS.EvansandGlennJ.WarrenEFFECTSOFTHEDONALDC.COOKNUCLEARPLANTON'ACROZOOBENTHOSINNEARSHORESOUTHEASTERNLAKEMICHIGANDavidS.White,MichaelWinnell,CatherineZawacki,RogerLaDronka,ThomasZdeba,andSamuelMozleyECOLOGYOFTHEMACROZOOBENTHOSINTHEVICINITYOFTHEDONALDC.COOKNUCLEARPLANTDavid.S.White,MichaelWinnell,CatherineZawacki,RogerLaDronka,ThomasZdeba,andSamuelMozleyIMPACTOFTHEDONALDC.COOKNUCLEARPLANTONFISH.DavidJ.Jude,DavidBimber,NancyThurber,FrankTesar,LauraNogucht',PamelaMansfield,HeangTin,PaulRagoECOLOGYOFFISHINNEARSHORESOUTHEASTERNLAKEMICHIGAN,1973-1982FrankTesar,DavidJ.Jude,He'angTin,PamelaMansfield............LAKEANDSHOREICECONDITIONSONSOUTHEASTERNLAKEMICHIGANErwinSeibel.135187141169207253285353401 INTRODUCTIONRonaldRossmannTheLaurentianGreatLakesserveasasourceofcoolingwaterforbothfossil-andnuclear-fueledpowerplants.Intheearly1960s,projectedheavyutilizationofthisfreshwaterresourcebypowerplantsraisedconcernsabouttheenvironmentalimpactofpowerplantsonthelakes.Suchpublic,governmental,andindustrialconcernsledtothefederalrequirementthatenvironmentalimpactstudiesbecon-ductedatallproposedornewlyconstructedpowerplants,especiallynuclearpowerplants.TheGreatLakesResearchDivisionofTheUniversityofMichiganwascontractedbyIndiana&MichiganElectricCompanytoconductanenvironmental"impactstudyoftheDonaldC.CookNuclearPlant,investigatingtheareathroughthepre-operationalyearsofconstructionandintotheperiodofplantoperation.DONALDC.COOKNUCLEARPLANTTheDonaldC.CookNuclearPlantisa2,200MWsteamelectricgeneratingstationsituatedinabeltofsanddunesonthesoutheasternshoreofLakeMichiganabout18kmsouthwestofSt.Joseph,Michigan(Indiana&MichiganElectricCom-panyandIndiana&,MichiganPowerCompany1973)(Fig.I).Preparationofthesiteforconstructionoftheplantbeganin1968.UnitIwasoperationalin1975andUnit2in1978.Theplantwasbuiltatatimewhenpublicconcernfortheenviron-mentreacheditszenith.Atfulloperation,theplantusesroughly6,300m'flakewaterperminuteinonce-throughcoolingofitscondensers;thewaterreturnedtothelakeis9-12C'bovetheintaketemperature.Wateriswithdrawnfromthelakethroughthreeintakecribslocatedatawaterdepthof7.3mapproximately686moffshore(Fig.2).Theintakestructuresextend2mabovethelakebottom.Maximumwatervelocityis1.8m/swithinthethree4.9-mdiameterintakepipes.Condensercoolingwaterisreturnedtothelakethroughtwodischargepipeslocatedatawaterdepthof5.5mapproximately366moffshore.Riprapbedsofcrushedlimestoneweredepositedaroundtheintakeanddischargestructurestopreventerosionandscourofthelakebottom.Duringwinter,waterisonlydrawnintotheplantthroughthetwoouterintakecribs.Heatedwaterisdischargedthroughthecenterintake,whichisturnedintoadischargetopreventiceformationaroundtheotherintakestructures.Withinthescreenhouse,trashbars6.6cmapartpreventlargepiecesofdebris.fromenteringtheintakeforebay.Verticaltraveling9.5-mmbarmeshscreenswithintheforebayimpingetrashandfishtoolargetopassthroughthecondensers.HISTORYOFTHEENVIRONMENTALIMPACTSTUDYThoughtheGreatLakesResearchDivision'senvironmentalimpactstudyincludedphysicalandchemicalstudiesofnearshoresoutheasternLakeMichigan,itfocused 2D.C.COOKiVUCLEARPLAtVTIMPACTMILWAUKEEMUSKEGONKtlometeroCHICAGOST.JOSEPHCOOKPLANTFIGUREI.LocationoftheDonaldC.CookNuclearPlantonthesoutheasternshorelineofLakeMichigan.onmajorbiologicalcomponentsoftheecosystem(benthos,phytoplankton,zoo-plankton,fish)andshorelineerosion.Preoperationalsurveysbeganin1966.Until1970,theyweresporadicandconsistedmainlyofphytoplanktonenumerationsandsomebenthosandzooplanktonenumerations.Between1970and1972,seasonalsurveys,primarilyofphytoplanktonandsecondarilyofzooplanktonandbenthos,wereconducted.Beginningin19'72andcontinuingiltto1982,samplingfrequencyandintensityincreasedandequaleffortwasgiventostudiesofphytoplankton,zooplankton,andbenthos.Fisherystudiesbeganin1972.Theyrepresentedroughly50oloofthestudyeffortbetween1973and1982.Until1974,allstudieswerecarriedoutonnearshoresoutheasternLakeMichigan.ln1974,preliminarystudiesoftheentrainmentoforganismsthroughtheplantandtheirimpingementontheplant'stravelingscreensbegan.Whenunit1oftheplantbecameoperationalin1975,full-scaleentrainmentstudiesofphytoplankton,zoo-IIVTRODUCTlON3PITAKEStdepttrS)SOUTHDISCHARGEtdepth~6m)IIORTHDISCHARGEtdeptli6m)LcdAtichipnTRASHBARSWIT2DISCHARGEFOREBAYTRAVELINGSCREEIISptTAKEFOREtutftetII876SesTICIRCILATPIQTERPINPSPITAKESALPUIIGLOCATIOIISIIUNTIOSCHARGEFOREBAYDISCHARGEAAIAPLPIGCONDENSERWIT2COIE)ENSERLNITIFIGURE2.SchematicrepresentationoftheDonaldC.CookhluclearPlantcircu-latingwatersystem.plankton,benthos,fisheggs,andfishlarvaebegan.Atthesametime,impingementoffishandbenthosonthetravelingscreenswasmonitored.Allfieldstudiesceasedin1982.Thisbookrepresentsthehighlightsofthefindingsfromtheimpactstudy.Fordetailsofeachfacetofthestudy,thereaderisreferredtothelistofallprojectreports(TableI).Theseareavailableuponrequest.y),y).d)tTABLEl.ReportsontheDonaldC.CookNuclearPlantenvironmentalimpactstudy.Ayers,J.C.,andJ.C.K.Huang.1967.Generalstudies.PartI,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.31pp.Ayers,J.C.,A.E.Strong,C.F.Powers,andR.Rossmann.1967.Studiesoflocalwindsandalongshorecurrents.PartII,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.45ppAyers.J.C.,R.F.Anderson,N.W.O'ara,andC.Kidd.1970.CookPlantpreaperationalstudiesl969.PartIV,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.92pp.Ayers,J.C..D.E.Arnold,R.F.Anderson,andH.K.Soo.1971.CookPlantpreaperationalsludiesl970.PartVII,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.85pp.Ayers.J.C.,N.W.O'ara,andW.L.Yocum.1971.fYinteroperations1970-1971.Part
4D.C.COOKNUCLEARPLANTIMPACTVill.BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.41pp.Ayers,J.C..W.L.Yocum,H.K.Soo,T.W.Bottrell,S.C.Mozley,andL.C.Garcia.1971.Thebiologicalsurveyof10July1970.PartIX,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision.TheUniversityofMichigan,AnnArbor,Mich.72pp.Ayers,J.C.,H.K.Soo,andW.L.Yocum.1972.CookPlantpreoperationalstudies1971.PartX,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.152pp.Ayers,J.C.,andW.L.Yocum.1972.IVinteroperations1971-1972.PartXI,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.26pp.Ayers,J.C.;andE.Seibel(eds.).1973.CookPlantpreoperationalstudies1972.PartXlll.BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.281pp.Ayers,J.C.,W.L.Yocum,andE.Seibel.1973.IYinteroperations1972-1973.PartXIV,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.22pp.Ayers.J.C.,S.C.Mozley,andJ.C.Roth.1973.Thebiologicalsurveyof12iVovember1970.PartXV,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.69pp.Ayers,J.C.,andE.Seibel(eds.).1973.ProgramofaquaticstudiesrelatedtotheDonaldC.CookNuclearPlant.PartXVII,BentonHarborPowerPlantLimnologicalStudies,Spe-cialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.57pp.Ayers.J.C.,S.C.Mozley,andJ.A.Stewart.1974.Theseasonalbiologicalsurveysof1971.PartXIX,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.181pp.Ayers,J.C.1975.Bacteriaandphytoplanktonoftheseasonalsurveysof1972and1973.PartXXI,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.153pp.Ayers,J.C.1975.ThephytoplanktonoftheCookPlantmonthlyminimalsurveysduringthepreoperationalyears1972,1973and1974.SpecialReport59,GreatLakesResearchDivi-sion,TheUniversityofMichigan,AnnArbor,Mich.51pp.Ayers.J.C.,N.V.Southwick,andD.G.Robinson.1977.Phytoplanktonoftheseasonalsurveysof1974and197Sandinitialpre-vs.post-operationalcomparisonsatCookNuclearPlant.PartXXIII,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.279pp.Ayers,J.C.1978.Phytoplanktonoftheseasonalsurveysof1976,ofSeptember1970,andpre-vs.post-operationalcomparisonatCookNuclearPlant.PartXXV,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.258pp.Ayers,J.C.,andS.J.Wiley.1979.Phytoplanktonoftheseasonalsurveysof1977,andfurtherpre-vs.post-operationalcomparisonsatCookNuclearPlant.PartXXVII,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision.TheUniversityofMichigan,AnnArbor,Mich.92pp.,plusAppendixof3microfichecards(122pp.).Ayers,J.C.,andL.E.Feldt.1982.Phytoplanktonoftheseasonalsurveysof1978and1979,andfurtherpre-vs.post-operationalcomparisonsatCookNuclearPlant.PartXXIX,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.70pp.,plusAppendi-cesof9microfichecards(256pp.).Ayers,J.C.,andL.E.Feldt.1983.Phytoplanktonoftheseasonalsurveysof1980,1981,andApril1982andfurtherpre-vs.postoperationalcomparisonsatCookNuclearPlant.Part INTRODUCTION5"l.ataltktlh.nd>ofhendonchf379,IX,kesidt-XXXI,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.91pp.,plusAppendi-cesof5microfichecards(268pp.).Barres,J.,L.Feldt,W.Chang,andR.Rossmann.1984.Entrainmentofphytoplank(onattheDonaldC.CooklVuclearPlant-1980-19B2.PartXXXII,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUni-versityofMichigan,AnnArbor,Mich.92pp.,plusAppendicesof7microfichecards(486pp).Bimber,D.L.,M.Perrone,Jr.,1.Noguchi,andD.J.Jude.1984.FielddistributionandentrainmentoffishlarvaeandeggsattheDonaldC.CookNuclearPowerPlant,south-easternLakeMichigan,1973-1979.Special-Report105.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.320pp.Chang,W.,R.Rossmann,J.Pappas,andW.L.Yocum.1981.En(rainmen(ofphyto-planktonat(heDonaldC.CookNuclearPlant-1978.PartXXVlll,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.106pp.,plusAppendixof4microfichecards(180pp.).Chang,W.Y.B.,andM.S.Shahraray.1986.Interactivedatabasemanagemen(systemforecologicalstudiesrela(edtotheDonaldC.Cook¹clearPowerPlant.SpecialReport119.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.158pp.Dorr,J.A.,III,andT.J.Miller.1975.Underwateropera(ionsinsoutheasternLakeMichiganneartheDonaldC.Cook(VuclearPlantduring1974.PartXXII,-BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUni-versityofMichigan,AnnArbor,Mich.32pp.Dorr,J.A.,lll,andD.J.Jude.1986.Diverassessmentof(heinshoresou(heasternLakeMichiganenvironmentneartheD.C.CookiVuclearPlant,1973-82.SpecialReport120.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.Evans,M.S.1975.The1975preoperationalzooplank(oninvestigationsrelativetotheDonaldC.CookNuclearPowerPlant.SpecialReport58.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.187pp.Evans,M.S.,T.E.Wurstcr,andB.E.Hawkins.1978.The1975and1976operational:ooplanktoninves(igationsrelativetotheDonaldC.CookiVuctearPowerPlam,withtestsforplanteffects(1971-197(f).SpecialReport64.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.166pp.,plusAppendixof4microfichecards(236pp.).Evans,M.S.,D.W.Sell,andD.I.Page.1982.Zooplanktonstudiesin1977and1978at'theDonaldC.CookNuclearPowerPlant;comparisonsofpreoperational(1971-/974)andopera(ional(197$-1978)populationchare(eristics.SpecialReport89.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.235pp.,plusAppendixof5microfichecards(222pp.).Evans,M.S.,G.J.Warren,D.I.Page,andL.F.Flath.1986.ZooplanktonstudiesattheDonaldC.CookNuclearPowerPlant:1979-1982investigationsincludingpreoperational(1971-1974)andoperational(1975-1982)comparisons.SpecialReport111.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.Johnston,E.M.1973.Effectofathermaldischargeonbenthospopulations:StatisticalmethodsforassessingtheimpactoftheCookNuclearPlant.PartXVIII,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan.AnnArbor,Mich.20pp.Johnston.E.M.1974.Statisticalpo~erofaproposedmethodfordetectingtheeffectofwasteheatonbenthospopulations.PartXX,BentonHarborPowerPlantLimnologicalStudies,Specia!Report44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.29pp.Jude,D.J-,T.W.Bottrell,J.A.DorrIII,andT.J.Miller.1973.S(udiesofthefishpopulationneartheDonaldC.CookNuclearpowerplant,1972.PartXlt,Benton 6D.C.COOKNUCLEARPLANTIMPACTHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.115pp.Jude,D.J.,F.J.Tcsar,J.A.DorrIII,T.J.Miller,P.J.Rago,andD.J.Stewart.1975.InshoreLakeMichiganfishpopulationsneartheDonaldC.CookNuclearPowerPlan(,l973.SpecialReport52.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.267pp.Jude,D.J.,F.J.Tesar,J.C.Tomlinson,T.J.Miller,N.J.Thurber,G.G.Godun,andJ.A.Dorrlll.1979.InshoreLakeMichiganfishpopulationsneartheD.C.CookNuclearPlan(duringpreopera(ionalyears-l973,l974.SpecialReport71.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.529pp.Kidd,C.C.1970.Pontoporciaaffinis(Crus(acea,Amphipoda)asamoni(orofradionuclidesreleased(oLakeMichigan.PartVI,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.71pp.Krezoski,J.R.1969.Someeffectsofpowerplantwas(eheatontheecologyofLakeMichi-gan.Partlll,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.78pp.LaDronka,R.M.1984.Oligochae(a.Part3:EcologyofthezoobenthosofsoutheasternLakeMichiganneartheD.C.CookNuclearPowerPlant.SpecialReport103.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.290pp.Lauritsen,D.D.,andD.S.White.1981.Compara(ives(udiesofthezoobenthosofana(uralandaman-maderockyhabi(a(ontheeas(em'shoreofLakeMichigan.SpecialReport74.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.65pp.Mozley,S.C.1975.Preopera(ionalinvestigationsofzoobenthosinsoutheasternLakeMichi-ganneartheCookNuclearPlan(.SpecialReport56.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.132pp.Noguchi,L.S.,D.L.Bimber,H.T.Tin,P.J.Mansfield,andD.J.Jude.1985.Fielddis(ribu(ionanden(rainmen(offishlarvaeandeggsa((heDonaldC.CookNuclearPowerPlant,sou(heas(emLakeMichigan,l980-l982.SpecialRcport116.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.251pp.O'ara,N.W.,R.F.Anderson,W.L.Yocum,andJ.C.Ayers.1970.Winteropera(ions,Marchl970.PartV,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,ThcUniversityofMichigan,AnnArbor,Mich.17pp.Rossmann,R.1975.Chemis(ryofnearshoresur/icialsedimentsfromsou(heas(emLakeMichigan.SpecialReport57.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.62pp.Rossmann,R.,N.M.Miller,andD.G.Robinson.1977.Entrainmentofphy(oplank(ona(theDonaldC.CookNuclearPlan(-l97S.PartXXIV,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.265pp.Rossmann,R.,L.D.Damaske,andN.M.Miller.1979.Entrainmentofphy(oplank(ona(theDonaldC.CookNuclearPlan(-l976.PartXXVI,BentonHarborPowerPlantLimno-logicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.88pp.,plusAppendixof3microfichecards(154pp.).Rossmann,R.,W.Chang,L.D.Damaske,andW.L.Yocum.1980.Entrainmentofphy(o-plank(ona(theDonaldC.CookNuclearPlan(-/977.SpecialReport67.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.180pp.,plusAppendixof2microfichecards(118pp.).Rossmann,R.,W.Chang,andJ.Barres.1982.En(rainmen(ofphy(oplank(ona(theDonaldC.CookNuclearPlan(-l979.PartXXX,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor.Mich.98pp.,plusAppendixof4microfichecards(156pp.).Seibel,E..J.C.Roth,J.A.Stewart,S.L.Williams.1973.Psammoli((oralinves(iga(ion1972.PartXVI,BentonHarborPowerPlantLimnologicalStudies,SpecialReport44.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.63pp. INTRODUCTION7.rch>75.znt,Xnnandookikcsideslies,Annchi-rcat.akcskes'uralThe~ield~iwerarch~ns,pof'tPP,akegan,inat'lant:rsityrtthemno-tyof)hyto-akescndixScibcl,E.,andJ.C.Ayers(cds.).1974.Thebiological,chemical,andphysicalcharacterofLakeMichiganinthevicinityof(heDonaldC.CookNuclearPlant.SpecialReport51.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.475pp.Scibcl,E.,C.T.Carlson,andJ.W.Maresca,Jr.1975.LakeandshoreiceconditionsonsoutheasternLakeMichiganinthevicinityoftheDonaldC.CookNuclearPlant:~interl973-74.SpecialReport55.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.62pp.Tcsar,F.J.,andD.J.Jude.1985.Adul(andjuvenilefishpopulationsofinshoresoutheast-ernLakeMichiganneartheCookNuclearPowerPlantduringl973-82.SpecialReport106.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.94pp.,plusAppendicesof5microfichecards(301pp.).Tesar,F.J.,D.Einhousc,H.T.Tin,D.L.Bimber,andD.J.Jude.1985.AdultandjuvenilefishpopulationsneartheD.C.CookNuclearPowerPlantsoutheasternLakeMichiganduringpreoperational(I973-74)andoperational(l97$-79)years.SpecialReport109.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.341pp.Thurber,N..andD.J.Jude.1984.ImpingementlossesattheD.C.CookiVuclearPlantduringl975-l979withadiscussionoffac(orsresponsibleandrela(ionshipstofieldcatches.SpecialReport104.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.24pp.,plusAppendix(75pp.).Thurber,N.,andD.J.Jude.1985.ImpingementlossesattheD.C.CooklVuclearPlantduringl975-l982withadiscussionoffactorsresponsibleandpossibleimpac(onlocalpopulations.SpecialReport115.GreatLakesResearchDivision,TheUniversityofMichi-gan,AnnArbor,Mich.70pp.,plusAppendix(88pp.).White,D.S.,andM.H.Winncll.1986.Introduction.Part1:EcologyofthezoobenthosofsoutheasternLakeMichigannearthcD.C.CookNuclearPovverPlant.SpecialReport122.GreatLakesResearchDivision,ThcUniversityofMichigan.AnnArbor,Mich.Winncll,M.H.1984.Malacostraca(Amphipoda,Mysidacea,Isopoda,andDecapoda).Part5:EcologyofthezoobenthosofsoutheasternLakeMichiganneartheD.C.CookNuclearPowerPlant.SpecialReport99.GreatLakesResearchDivision,TheUniversityofMichi-gan,AnnArbor,Mich.94pp.Winncll,M.H.1984.Chironomidae(andotherDiptera).Part6:EcologyofthezoobenthosofsoutheasternLakeMichiganneartheD.C.CookNuclearPouterPlant.SpecialReport100.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.177pp.Zawacki,C.M.1985.Minortaxa(Hydrozoa,Turbellaria,Hirudinea,Arachnoidea,non-Dip(eraninsects,Gastropoda,andzoobenthicmeiofauna).Part2:Ecologyofthezooben-thosofsoutheasternLakeMichiganneartheD.C.CookNuclearPowerPlant.SpecialReport112.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.201pp.Zdeba,T.W.,andD.S.White.1985.Pisidiidae.Part4:EcologyofthezoobenthosofsoutheasternLakeMichiganneartheD.C.CookNuclearPowerPlant.SpecialReport113.GreatLakesResearchDivision,TheUniversityofMichigan,AnnArbor,Mich.85pp.onaldagicaluigan.at,)PPThisbookhasbeenstructuredsothateachchapterdealingwithaspecificfacetofthestudywillbecompleteinitself,andcanbereadasaseparateentitybythosewhowish.TofamiliarizethereaderwiththeregionofsoutheasternLakeMichiganwheretheplantissituated,adescriptionofthearea'scharacteristicsfollows. 8D.C.COOKhIUCLEARPLANTIMPACTDepthContoursINTERVAL=2hKTERSSXJOSEPH~12~4DONALDC.COOKNUCLEARPLANTFIGURE3.BathymetryofnearshoresoutheasternLakeMichigan.DESCRIPTIONOFTHESOUTHEASTERNLAKEMICHIGANREGIONLAKEBOTTOMTOPOGRAPHYThetopographyofthelakebottomwithintheregionofstudyslopestowardthenorthwestwithgreatestdepthsinexcessof38m(Fig.3).Atdepthsgreaterthan20m,aseriesofridgesandrunnelsperpendiculartoshoreoccurs(Rossmann1975).
INTRODUCTION9Theridgesconsistofcoarsersedimentsthantherunnels(RossmannandSeibel1977).Neartheshoreline,oneephemeralandtwopermanentsandbarsexist(Seibeletal.1976).Theephemeralbarislocatedapproximately47mfromtheshoreline.Theinnerandouterpermanentbarsarelocated116and216mfromtheshoreline,respectively.Waterdepthsbetweentheinnerbarandshorelineandbetweenthetwopermanentbarsare1.5to1.8mand3.7to4.0m,respectively(AyersandHuang1967).Thedepthofwateroverthecrestoftheinnerbaris1.2mandthatovertheouterbaris2.6m.SEDIMENTSSedimentsvaryfromcoarsetofinequartzsandsattheshorelinetocarbonate-richveryfinesandsandsiltsoffshore{RossmannandSeibel1977).Thesedimentsarederivedfromsanddunesandunconsolidatedbluffsalongtheshoreline(Hands1970).Thebluffsareclay-richandcontaincarbonates(Rossmann1975).Duringtheearlytomid-l970s,severeshorelineerosionoccurredwithinthestudyarea(Davisetal.1973,Tanner1975).Materialderivedfromthiserosionaswellasfromrainrunoffandstreamtransportisresuspendedandsortedbywavesandcurrents(SlyandThomas1974).Materialsarefinallydepositedoffshorewherewavesandcur-rentsareincapableoftransportingthemfarther.CURRENTSThemajorlakecurrentwithintheregionofLakeMichiganiscalledtheBentonHarboreddy.Thiseddymovesinaclockwisedirectionwithcurrentsmovingsouth-westwardalongtheshoreline(Ayersetal.1958,Bellaire1964).Inshoreofthiseddy,acounterclockwiseeddywithcurrentsmovingnortheastwardadjacenttotheshore-linewastentativelyidentifiedbyAyersetal.{1958).BetweenMayandNovember,currentdirectionbetweentheinnerandoutersandbarsispredominantlytothenorthwest.Directionwasalwaystothenorth,north-west,orwestbetweenMayandJulyregardlessofwinddirection(Ayersetal.1967).BeginninginAugustwhenthewindwasbriskfromnortherlydirections,currentsmovinginasouthwarddirectionbegantooccurwithincreasedfrequency.Smallervelocityandfrequencyofnortherlywindswererequiredtoproducesouthwardcurrentslaterinthefall.ForthemonthsofMaythroughOctoberin1967,over86Voofthetimecurrentdirectionbetweenthetwobarswasnorthward.Monthlymeancurrentvelocitiesrangedbetween31.7and69.8cm/sec.Inshoreoftheinnersandbar,currentdirectioniscontrolledbywinddirection.Waterbetweenthebeachandinnerbarispostulatedtobewaterspilledovertheinnerbarduringsurfaction.Itiscutofffromthemain-lakecirculationbytheinnerbarandismovedinadownwinddirection(Ayersetal.1967).1the17WAVESWaveobservationshavebeenreportedbyLiuandHousley(1969)forSt.Joseph,Michigan(Fig.1).Fortheperiodsof28September1966to16December1966and21 10D.C.COOKNUCLEARPLANTIMPACTSeptember1967to30December1967,maximumobservedwaveheightwasbetween3.6and3.0m.Maximumwaveperiodwasbetween7and8seconds.Themostfrequentwaveheightandperiodwere0.6to1.3mand5to6seconds,respectively.Wavesmostoftenapproachedtheshorelinefromthenorthwestorsouthwest.LOCALWINDSBaseduponobservationsduring1967,surfacewindsadjacenttotheshorelinearegreatlyinfluencedbyabluffofsanddunes61mfromtheshorelinethatparalleltheshoreandruninanorth-northeasttosouth-southwestdirection(Ayersetal.1967).Thesedunesservetoprotectnearshorewatersfromwindsfromnorth-northeast,aroundthrougheastandsouth,tosouth-southwest.TheyalsochannelwindsfromnortherlyandsoutherlydirectionsintoaNNE-SSWdirection.BetweenMayandmid-NovemberthemostoftenrecordedwindswerefromtheNNE(14.2o/oofthetime)andSSW(22.6o/oofthetime).Averagewindvelocityrangedfrom9km/hinJuneto16km/hinNovember.Generalprevailingwindsfortheregionarefromwesterlydirectionsthroughouttheyear.THERMALCYCLEOFWATERCOLUMNTheexacttimeofoccurrenceofvariouseventsinthethermalcycleisdependentupontherateatwhichthelakewarmsaswellastheseverityofawinter.Warmingofnearshorewatersbeginsinspringwithsnowmeltandspringrains.Aslakewaterswarm,anearshorethermalbardevelopswhichisdelineatedbythe4'Cisotherm.Asthelakecontinuestowarm,thethermalbarprogressesfartheroffshore.Thether-malbarwasusuallyfoundwithinthestudyareaduringApril.Eventually,thethermalbarmovesoutofthestudyareaandathermallystratifiedwatercolumndevelops.ThisusuallyoccursinMayorveryearlyJune.ThermalstratificationusuallycontinuesintoandoccasionallythroughNovember.Forthecalendaryear,surfacewatertemperaturesrangebetweenI.land26.9'C,whilethoseofthehypolimnionrangebetween5.0and6.5'C.Duringstratification,upwellingsofhypolimnionwaterwithtemperaturesaslowas6'Carecommonalongtheshoreline.Exceptduringupwellings,waterdepths((45.m)inthestudyareawereonlygreatenoughtopermitsamplinghypolimneticwateratthosestationsfarthestoffshore.LITERATURECITEDAyers,J.C.,D.C.Chandler,G.H.Lauff,C.F.Powers,andE.B.Henson.1958.CurrenlsandwafermassesofLakeMichigan.Publ.No.3,GreatLakesRes.Div.,Univ.Michigan,116pp.Ayers,J.C.,andJ.C.K.Huang.1967.Ben(onHarborpowerplantstudies,PartI.Generalstudies.Spec.Rep.No.44,GreatLakesRes.Div.,Univ.Michigan,37pp.Ayers,J.C.,A.E.Strong,C.F.Powers,andR.Rossmann.1967.BentonHarborpowerplantstudies,PartII.Studiesoflocalwindsandalongshorecurrents.Spec.Rep.No.44,GreatLakesRes.Div.,Univ.Michigan,20pp.
INTRODUCTIONcIInstrete).t,mid>e~nnafrsXsBellaire,F.R.1964.Acomparisonofmethodsofcurrentdeterminations.InProc.7(hConf.GreatLakesRes.,pp.171-178GreatLakesRes.Div.,Univ.Michigan.Davis,R.A.,E.Seibel,andW.T.Fox.1973.CoastalerosionineasternLakeMichigan-causesandeffects.InProc.16thConf.GreatLakesRes.,pp.404-412.Internat.Assoc.GreatLakesRes.Hands,E.B.1970.AgeomorphicmapofLakeMichiganshoreline.InProc.16thConf.GreatLakesRes.,pp.250-265.Internat.Assoc.GreatLakesRes.Indiana&MichiganElectricCompanyandIndiana&MichiganPowerCompany.1973.FinalenvironmentalstatementrelatedtooperationofDonaldC.CookNuclearPlantUnitsIand2.Liu,P.D.,andJ.G.Housley.1969.Visualwaveobservationsalong'theLakeMichiganshore.InProc.12thConf.GreatLakesRes.,pp.608-621.Internat.Assoc.GreatLakesRes.Rossmann,R.1975.ChemisrryofnearshoresurficialsedimentsfromsoutheasternLakeMichigan.Spec.Rep.No.57,GreatLakesRes.Div.,Univ.Michigan,62pp.Rossmann,R.,andE.Seibel.1977.Surficialsedimentredistributionbywaveenergy:element-grainsizerelationships.J.GreatLakesRes.3:258-262.Seibel,E.,C.T.Carlson,andJ.W.Maresca,Jr.1976.Iceridgeformation:proba-blecontrolbynearshorebars.J.GreatLakesRes.2:384-392.Sly,P.G.,andR.L.Thomas.1974.ReviewofgeologicalresearchasitrelatestoanunderstandingofGreatLakeslimnology.J.FishRes.BoardCan.31:795-825.Tanner,F.W.1975.Beachprocesses,BerrienCounty,Michigan.J.GreatLakesRes.I:171-178..Ie1,ny15 SEEINSTRUCTIONSONREVERSESIDESECTIONIEPAI.D.NUMBERMID0964761PERMITNUMBER~M10005827'APPLICATIONFORDISCHARGEPERMITIS:tsm[FITIONEXITINGhEMItKREASEDUSEREISSIAIICE0DHITEM1PHYSICALLOCATIONADDRESSC.PLAIITORFACILITYDCC00KPLANTD.TYPECFFACILITYSTMELECTREsSTANDARDINDUSTRI)[LC[ASSIFICATION(REFERTOTABLEII)GEN~qgfeSTREETtlHKRG~STREETBVKCOOKPLACEAP~~~~~'~~'ERINDIANAMICIGANPOWERCOMPNYB.DIV.i[NREAUNAANDINFORMATIONHsCllY[[A%BRIDGMANJsTCWNSHIPLAKELeNA%OFAUDCRIZEDCONTACTPERSONMlK>>CXNIY(REFERTOTABLEI)BERRIENHsTITLEI~ZIPCODE49106CO.IAPBER~>DONALDLBAKRO.AXRESS(IFDIFFERENTFR[V[ABOVE)NVAFFAIRSIR219~42~21PsCITYRVKFORTWAYEPOBOX60OeSTATEReZIPGXK468015~lYPEOFTREATMENTFACILITY(REFERTOTABLEll)~lL~ltr~2K~3A~4Gl'PROGRAMFOREFFECTIVERES[DIALSHANAGE%WDATESLBHITTEDYESCItaHN.A.DATEltPLEPENTEDU>>BACK~POwERQXRCEYESMNAeVsPOLLUTIONINCIDENTPREVENTIONPLANDATESINVIITTEDXVEStDNADATE[~[TED11/15/92MetltVIEROFEIVNJIVEESX.TYPEOFDISCIARGE~~QQxYeDOYOUHAVEACERTIFIEDOPERATOR?ElYESCIteD.M.FITZGERALDee4~309~70~4802ITEM2MAILINGADDRESSOFAPPLICANTAsW%RCMENGEBet4VKINDIANAMICHIGANPOWERCMPCSTREET,AXRESSCRPOSTOFFICEBOXPBO60DeCllYt4V%FORTWAYNEPEOulDEOStctthrttt2EEeSTATEF>>ZIPCODEI.thedDDI[cant.cettllyunderpenaltyotIavthatIhavepersonaltyerdhlnedanddmtdmltlat'lththeIntormatlonsubmittedInthisdDDtlcatt,andalIattachmentsanothat,basedonmyInoulryotthoseIndlvldudtsImmediatelyrespon51bletotobtalnlngtheIntormatlon,IbelievettdtttelhtormatlonIstrue,accurateandcomplete.Idmdvarethattheredre5[obit[cantpetldlties'tor5ubmlttlngtdt5eIntotmdtlohIhcludlfloDD55[biIItyottinednoImprlsotvsent.SIGNATUREOFAPPLICANT3aoR4-SIGNATUREOFLOCALGOVERNMENTALREPRESENTATIVE(SEENOTEONREVERSESIDE)R-C.MENGE.PRESIDENTT[TLEI15 SEEINSTRUCTIONSONREVERSESIDESECTIONIRMIT~I0ITEM3SOURCEOFWATERSUPPLYAMWICI?AL3.SDRFiVEnATERIt>>AXEC~-FIXATEnEU.O.CT>IERNAMECFITATERHAV.M~>TlTY;>AX.).MAX.)DoorFuLAKET0NSIHIIPNAINIAr~>CJS/SAYC'LLOlJS/OAYIQALLrIts/r~yLAKEIMICHIIGANIITEiVI4L>>tITI>YIŽAX.)-maSS'ATER(IIICLUOrrtsCOITACT:OOLIlJOn'ER):!jAIJTITY>MAX.)B.'CttCOIITACTCOOLItlG'nATERYTITY(uAX,)GAL>>XIS/CAY63>4400OAI>ctq/n~y2>642112000oAuotB/~yFACILITYWATERUSAGEC.SARITARY'>JATERDOTIERAJAttTITYI>SAX.)OUAttTTY(MAX.)FI60000CAL>>xts/BAYPROTE.CTIONWIT3600000oALLctts/BAylTEM5CRITICALMATERIALS&PRIORITYPOLLUTANTSCCIJJ~IMJETIIE;,~EOFSUBSTAtJCEPARAMETERIAPZERCUAIITITyNA%OFSUBSTANCEPARA%TERtlH3ERCUANTITYHYDRAZINEAueous0030201247oo<~ivySODIUMHYPOCHLORITE(12%)CLASS014ITS64894USEDSTOREDPRODUCEDREFERTOTABLESIVS>VttA"EOFSUBSTAlJCEPARA%TERtlPBERSIPUITITYMJREITERt>Lt%ER'U>UITITY:~OFSUBSTAIJCEXYLENETOLUENEOtl3>30207163T~/YEAR001088,8<tgTs699~1/YEARJlHlL'iCQEIPOUNDS2GALLONS3CUBICYARDS4TONSl>JIOIMJII:RUEOFit>MTAIJCEP~'%ac;R:AtSERQUAtttIlyttŽEOFSUBSTAttcEPARE>E.RIAPBERrRUAIITI>Yi""ECFSLBSTAIJCEDARAtETER:ltS>ERCLASS02HYDROUINONEITSIL/veMERCURY+ITS/YEARUNITSLLI/YEARLITHIUMasLITHIUMHYDROXIDE17 ")$<<~at3<<"a3<<>>:I'/>>a><<r~I3'5<<aQtsa<<~r<<03<<II<<I$5ana3va3~<<'rI~e<<5$,ngru)3<<e,aronie5$e>><<3erIa=Iver,cr<<neItva~vra~~7"~I'c3>>3e5>>>>>p4aer<<3'r'3ere>>$3t<<a>>3I3ara3>>lnIa<<5<<<<ar<<<<aII5T"louhTSf<<atertooeu5ec>orvarIcusurcses351o"ccessTater-seeG>cssarv!Orceflnltrcr:ace-'-).'~nccntact"colin>><<hater-seeGl=ssarv3"Ta'I-:Tlc":oaceC.).l<<nlta>>vaster<<ster]seararIrasI~r.5a$:a...Irat5,3~na5,Ir<<ars.sterls"rs-<<sea'cr3ecarcase3-r-"e5aaer135'.5ecrere)r.3ec'nr3e3--"5o-"erC.rccses,'"crea<<e-"evo>urei<<5.es',<<,ar,see're<<3e3,.:'-3r3a.=.qi)-e'3aI'-131>V~sar33rnacnta.:31'-3*3-er:-=en3$$$$<<ae,a:3>>'aar,eI3eI3$5<<e~Inoulcerut>>lsaoollcaTlcn~:vCI'fereqce1-ese-!Sls3culCeev>>Iainecrrsr3acqea3eetcfITiv5Tr"ATE~IAu5O'A)O'RIGIDITY~1>>UT3~5rST3IICne)aal3COSTanceS<<nlCOareI-"In)C3-'3,>>.'-IC31"sterl3IScec)Stn"!Cle'>33ce"'>>a/Cr..8.=33'5arICr:tV=O>1utantI.esttaoleV(oace7)3'ratsrecurren.>V<<sea.storea~croroauceaOvTn)5>aaliIITv. SEEINSTRUCTIONSONREVERSESIDESECTIONIPERMIT~qZpppg827NUMBERITEM3SOURCEOFWATERSUPPLYAri'TNICIPALBrSURFACErrATERItateECrPRIVATE'rrEILD.DINERrLrAratra'~'5CFWATERWAYalTY(tAx.)ITVttrAX,)carrFyITEiVI4OUAtaITY(tAX.)A.PROCESSRATER(ItCLUDltJGCOtaACTNSNATER)Tvlt3~NCttCOtaACTCOOLItlGWATER".UAtatTv(we.)C.SANITARY'HATERGAuDttS/DAvGALIDNS/DAYFACILITYWATERUSAGEITEM5CRITICALMATERIALSPRIORITYIPOLLUTANTSUSEDSTOREDD0TIERtlVKCFSUMTAtCEPARAIKTERR!%EROUVallYN4%OFSUBSTANCEPARAtETERtAMKROUANTllvNVKOFQSSTANCEnuamtTv(we.)SPOUrVaTV(We.)MercuricNitrateCadmiumCLAss013EthleneDichlorideWITSL1J/YEARWlTS~1/YEARPRODUCEDREFERTOTABLESIVSrVJLHlLiCQEIPOUNDS2GALLONS3CUBICYARDS4TONSITYNAtEOFQBSTANCEPAPA"ETERlAtSERtgrEOFQrMTAttCEPAIUVETERtttteEROUAtallvtA%OFSIISTANCEPARA%TERtlHKROUANl'ITYle%OFSIISTAtCE0010706226~TChloroformppp67663WITS/VEARLead01332214WI'TS44QJ/YEARCLSS019WITS300~1/YEARTriarlPhoshateEsterEHC*CLSS084WITS21000~1/YEARAsbestos*HydraulicFluid17 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~Q~"Is'-r.-<<Cui-es4nfo~aticnaocut7-e<<ater)coiv-".<<5~)oilI)V,-e':"4(-v'5<<ate<<.sace.-'*-nssec5-r<<3-r)r""""e"---'S""'I:tv'<<el~)ls~f)(<<~"~($'l"-,u)TI(ivgc<q8pg:4',(<<vlc5'~l*<<<<<<I'e<<e3ve>~g4c<<<<roar<<a(if<<55("ace)<<I<<~uc'ate,(esIe<<<<e4Ie~(e45i~pP4<<<<<<ater<<<<<<~~<<I<<<<<<tI54~)<<<<5'<<ate<<~)e<<'S<<t<<<<<<Sa<<~>~3C~>r<<r<<S0545<<<<~~<<-arona(ver,crtneGitvofM(IIOCnc.:5t)"cunt)ctater-."Ceusec'o(v3rlouscurccses35crccessna<<er-seeGiossarvforceflni-Icn(cace38).'.once;-actco(ing<<ate>-seeGlossary'crCeflnlticn(cage38).:anltarvx!ter-Aeteruseofordomesticcurooses(e.o.,-oilet5,Sinks.)rovers.<<ater75'r)tvSecfarcnecuroOSeano7-e5(74e<<ateriS5.3Seouent:V.Se'Cr5-ecr-cre7"er:.r)CSeS.'-)(cae"evolute)<<)]it<<5Qsi)oljsecefPe<<<<<<<<e<<t)c/cr.'c"are.Tcr<<<<5T'e.'<<<<5III4vcsee)5~rcntact3-e"!"c-en)s:css<<ate(,T-eC.ant'-.:-<<aer-,'ven>>-cuic:e'-)ic)-ec)5:-ccess*a.er.<<<<C)nOu4Cao34tneterai'-em.'.Cnvci"tranceir--ese-)tais5-Culcce<<xclalnecI")n<<7-)CseaSneerof-<<ISaccliCTIOn.ITQ48!sT)IIccemicalsucstances<<nicearelnync<<l73n5rltlcal"aterials>eels)a<<ableIy(cace8)anclcr.~.=ca'5orlorltv<<IrbIi>tTableVlaaae7)that6eiei7,~,0IDi~itili SEEINSTRUCTIONSONREVERSESIDESECTIONIPERMITMNI0005827I'TEMA,rrrrcrprL3BrStttFACEHA'fERINfAKESOURCEOFWATERSUPPLYC~PRIVATEH'ELLDrOTHERltA%CFWATERWAY(uAX)OUAttflTv(we.)SP~DAYITEM4FACILITYWATERUSAGEITEM5.CRITICALMATERIALSPRIORITYPOLLUTANTSUSEDSTOREDPRODUCEDREFERTOTABLESIVBrV1POUNDS2GALLONS3CUBICYARDS4TONStFtEOFSUBSTAttCETv(we.)CL'rrrCrtNrrPKOFSLSSTANCEPARAtETERtttSEROUANfllYNA%OFSUBSTANCEPPJJtETERMtSEROUANTllYNAPEOFSIBSTANCEPARt4%TERtAtSEROUANTllYNAPEOFSUBSTAttCEPARA%TERtAteERCCrrrIhrXOUANTITfNAIEOFS%STANCEPARAMETERIAAFrrrrOZOUANfllYoUANrITY(we.)ArPROCESSHATERIIIICUSIt6COt(TACTaOLItoHATER)CUANTITv(we.B.ICNCONTACTCOOLINSWATEROUANTITY(we.)C~SANITARYHATEROUAttfITY(we.)D.OTHEROAuDNS/DAYoAutm/DAYOAuDNS/DAYOAuDttS/DAYBenzeneGasoline000714327000Q/YEARTolueneGasoline00108883UNITS7000~1/YEARXleneGasoline01330207UNITSL1J/YEARUNITS~/YEARUNITS~/YEARUNITSLJ/YEARHAIKOFSISSTAtCEPARA%TERIAt%ERrOUUIfllYUNITSLJ/YEAR ~~cr=gtCTIrhISPCRCvPLc.I~cE.IC'IIITEMS5,4,AhO5This.'Ormreoui,esit.atlnabcur5<<3~erS"pl'a5gIayorle>>l-vcollu.antsASed,Stored,crproducesat-nfs'llitv.~ewe3C'lV'S<<are>>Sade.SnCC-'-iCSI-3<<e>>ialsand3E,'.llT.g.e5i53>>ewcrnotprevtcus<vcer"iecoilitv,-nenITUv8ER"AMEcCU'OC'I-""-nrvI,'W.Irgl';Gleavebianxar-3nurcec<<Iil-eassi"rec.tCatu>>c't<<ATEnSLppivListsli<<atersuppliesused."evol<<emavpeestimated~roy3<<atersupplv>>eer>>eacingsor'ranpiiiincS.are"ants'ran3ware5<<plIAtlll,v.Iawateris>>.eterec,es,l>>areyrxpumpapacitv.aghere3nseesa%vireo,enter"3>>e"<<3er5ucply;uudLake,HuronRiver,ortheCItyotIAIIlpono.ITEM4PACILITyWATERiJSAGE'istamountsotwaterrobeusedforvariouspurposesas:processgfater-SeeGlossaryfordefinitionlpage48)..'lonccntactCoolingWater-SeeGlossarytordefinition<page48).SanitaryWater-Waterusedtordcmesticpurposes;e.g.,toilets,sinxs,shoers.~f<<ateriS.IrStuSedfcrCnepurpOSeandtheSamewateriSSupSeduentlySedaarCneCrareOtherpurpOSeS,indlCatetheVclu>>eercavotrheInstce5icnarecusepetorereatrentsnc/ogdischarge.-crRxa>>cie,ig<<aterl5inltlallvusedasnoncontactCCOlln"*aternohen3S->>"CeSS~ater,tneSuanlVCfarer~iVen5"OuldbeinoioatedSSOrOCeSSwater.Thetotalofitem4shouldecualthetotalofitem5.Anydlfterenceintheserctalsshouldbeexplaineoinanattachedsheetotthisappllcarlon.ITEM5CRITICALMATERIALSAWOPRIORITYPOLLUTAiITSUSED.TCREO.noCOUCEO'StallChemiCalSubatanCeSwhiChareInMIChlgan'5CrltlCaluaterlalSOegISterTableIVIP8ge6)and/OrU.S.EPA'SPrlOrltyhilttlitthiy(egeyithteetiyd,ed,gaaey;hi~tediiity. SEEINSTRUCTIONSONREVERSESIDESECTIONIPERMIT~~MI0005827TEM6DESCRIPTIONA>>:gyIDEAPRIEFDESCRIPTIQN4<<ILINEDIAGRAM(5+>INGlbE'<<ATER~'PWMI>>(TCURFACILlTYRCHINTAKE>>QiNATE.-~'.PA>>,l,'.5~iiRISUTING>>(ASic>>(AicR>>IllCU<<>>IIIGFHKESSAI<<>>FACDUCTICNAREASi5>><<iITARYFL>>'.>>>>(5>>CQQLING'HATER>>ANDSTQAATERRVCFF~,QU<<AYSAQPSINILARCPERATICNSINTOASINGLEUNIT>>TNEWATERBALA(iCESHDULOQCwAVERAGEFLQWS~SAWALLSIGNIFICANTQSSFS:F<<ATER~F>>~CQUCTS,APQSP(>>ERE>>4(DDISCNARGE~YQUSNQLLJUSEAC~>><<EAS(A(EVENTS'~NEVERAVAIlAELEIQTI>>ERNISEUSEYQ(RSESTASTI"ATE.[SEEATTACHEDDESCRIPTION]ANODIAGRAM ~<<I85)<<"u8a<<<<t)Cili)y'rt""3<<8,'ISC>)r-*~<<r"ey'uIa~treave<<I'~J~'tu<<~-ir~-.-i-go'8588<<"<<'8I~Vo<<J<<8)veSC"st'"8)"<<)5O"V<<3<<'t'sc.Ion)<<8Sct'<<,)r~<<.,3<<58<<88<<o<<t-<<.)r"3-,<<.-ersrin5'-~~8<<8<<8-e,oolin),)<<s.)I-'-Ior'i<<8)c3)<<)ec-!33'33'"tcr'ce<<<<cvst3c)'.'0-8tst.8<<8833'5~8<<"3Cf3)u...'SiC"'".43.'.-Sore.8"5"8>>")3Se,3.<<Ocur*8CI"as<<8835353.v8.IVer'5'C'Cut38"8<<8<<)I"YCt'tl.<<5~-)5e5-83~"o<<s-nro'."n3:~""'"er.-8-8)t"~s<<curseser-'es---esc--r,as<<st;cce<<."e-<<3;ec<<8erI's<<5<<M<88!arl':er-8-anrote<<8<<e'-sot<<<<tlngles<<snccn-ac-ol<<g8~8ro""85rtc'-e."iscon~--leo<<sve<<'5:isc-srsec-".--8B.cv)iver."esi.cce'<<st"-eclari"er-oesro!rscu~"'-8"<<ere'?5Ce<<ave-eo.-83.Cce'S-e<<-S.erCalciumChlorideSulfuricAcid1LimeIPolymerPlatingWastewater70.000GalionTankAcidificationIieutralization'locculationBatChOuttlps~0umpTank.SludgenickenerClarifierNon-contactCoolingwaterCalciumChlorideyacuumFilterWaterSulfuricAcidI.imeLandfillGondolaSludgeIfanhoIeBuckRive.-".:e.'-;...Ser<<C<<h,an'C-.855leeve383<<":5'Ct'u!Cr"C-Ivea<<c<<<<uc>>encineS.-"CauclcnIS-SeS.Vo<<)*-Ce-5--""8"'-<<'r5---SSe-I5:5~-OncanieCSvei<<C::cser.-<<)-5ss'n--cc5")"etec---.'.-)ce)no.o<<'-g3er3~-srer3).encesnoic've-eiing-e<<al'"-.)ovoer'cr.-8lscctc)haseccnsis:ssfscnering"e~it:e"eraloo<<cer3Scilt3881SVOa))ihc<<8<<05o<<tv"<<'ur<<aceS.ta<<er.Sec-"COIsheSvrlcccnssi.u)85Ctt<<<<88<<)83<<l5ar<<8"'3<<3<<<<i<<~~<<8)<<5set'"<<)58,55eatlncs~8Ceire)ic<<815.t~8Sr'8C..3388>>I38."8tei<<al"I<<<<sear'8OOITshcI8<<ei'Ie83nC<<aC)~<<,=:nSea-er:<<lore)<<Csf)en-<<8taricuS:33',-g338<<sionscons)iu.es3-e)recess<<).er.MunicipalWaterSupplySanitaryFacility30,000gpdNunicipalTreatmentStripei.ine295.000gpdCoolinglfater250.000gpdiiasteTreatmentPlant45,000gpdBuckRivePowderNfg.4.000gpdPlatingProcess40,000gpd20 SECTIONI,ITEM6,SUBPARTACont'dOUTFALLDESCRIPTIONSOUTFALL001-Unit1CirculatinWaterDischareOutfall001isanon-contactcoolingwaterdischarge.Mostofthenon-contactcoolingwaterisusedtocondensethesteamexhaustingfromthesteamdriventurbines.ThecondensercoolingwaterisdrawnfromLakeMichigan,screenedtoremovelargeparticlesentrainedinthewater,routedthroughtheUnit1condensersandthendischargedtoLakeMichigan.Outfall001alsoincludesSteamGeneratorBlowdown,PlantHeatingBoiler(describedlaterasinternalOutfallsOOA,OOBandOOCrespectively),andtheReverseOsmosis(RO)system(describedonpage10).Outfall001alsocontainstheeffluentflowfromtheEssentialServiceWater(ESW)system,Non-EssentialServiceWater(NESW)system,andmonitortankreleases.ESW(20,000GPMmaximum)isLakeMichiganwaterthatisusedtoprovidecoolingtoNuclearRegulatoryCommission(NRC)definedsafety-relatedequipmentandasanemergencybackupwatersupply.NESW(9000GPMmaximum)isalsoLakeMichiganwaterusedfornon-contactcooling,asasourceofwaterforthedemineralizedmakeupsystem,andtosupplywaterforNRCdefinednon-safetyrelatedequipment.Monitortankreleases(-20,000gallonsperevent)areregulatedbytheNRCandconsistofwastewatergeneratedwithintheAuxiliaryBuildingthathasbeenprocessedpriortobatchdischarge.Thenon-contactcoolingwaterforthecirculatingwatersystem,theESWsystemandtheNESWsystemis.treatedforbiologicalcontrolusingliquidsodiumhypochlorite,withtreatmentsusuallybeginninginMayandterminatinginNovember,dependingonLakeMichigantemperatures.Thebiocideisaddedattheintakeforebayandtheaverageresidualmeasuredinthedischargeismaintainedatlessthan0.2mg/latOutfall001.Thetreatmentslastfornomorethan160minutesperday.Ifcontinuouschlorinationisutilized,theresidualmeasuredinthedischargeismaintainedatlessthan0.036mg/latOutfall001. Thissamewaterisperiodicallytreatedusinganon-oxidizingbiocidetoeradicatethecoolingsystemsofzebramussels.Thebiocidesweareconsidering(BetzCT-1,BetzCT-2,BetzCT-4,CalgonH-130M,andNalco9210)areallpolyquatswhichwillbedetoxified,asrequiredusingbentoniteclaytomeetwaterqualitybasedeffluentlimits.Thetreatmentsaredirectedtothecriticalplantsystemsfromtheintakestructureslocatedaboutone-halfmileoutinLakeMichiganthroughtheentireplantcoolingsystem,includingtheESWandNESWsystems.Systemsaretreateddependentuponzebramusselinfestation.Concentrationsandchemicalfeedpointsarechosentominimizetheamountofbiociderequiredandtomaximizethetreatmentprogram.Thesystemsmaybetreatedatthesametimeorindividuallytoallowmoreefficientuseofchemicals.Weplantotreatallsystemswithintheplantamaximumoftwiceperyear(sixapplicationsperyeartotal)toassuresafeoperationofthenucleargeneratingunits.ThecurrentNPDESpermitincludestheuseofsodiumbromideandsodiumhypochloritesolutionsfortreatmentofthecirculatingwatersystems.Thesesolutions,whicharethemajorconstituentsofmanyproprietarymixturessuchasNalcoActi-Brom,arepresentlybeingconsideredasthebasisoftheCookNuclearPlant'sstrategicplantocontrolzebramussels.Effectiveuseoftheseoxidizingbiocidesareexpectedtoreducethefrequencyofnon-oxidizingbiocidetreatments.SeeAttachment3ofthecoverletterformoredetailsregardingourfuturezebramusselcontrolstrategy.Themonitortanksreceivetreatedwaterfromtheradioactivewasteremovalsystem.OnesystemhandlesthewasteforUnits1and2andtheAuxiliaryBuilding.Thissystemtreatswastesgeneratedfromthereactorcoolantpumpsealleakoffs,therefuelingcavitywater,equipmentleaks,floordrains,valvestemleakoffs,wastesamplesolutionsandlaboratorywastesfromtheradiochemistryanalysisinthehotchemicallaboratory,systemequipmentdrains,non-contactcoolingwateranddecontaminationprocesses.Thewastesarecollectedinoneofseveraltanksandtreatedwhenenoughwateriscollected.Thetreatmentutilizeseitheranevaporatorsystemorademineralizersystemtoremoveradioactivecontaminants. ThetreatedwaterisaccumulatedinthemonitortanksandsampledtoensurethewastemeetstheNuclearRegulatoryCommissionradiologicalrequirementspriortobeingdischargedintothecirculatingwatersystem.Periodically,duetoequipmentleaksand/orsystemupsets,awastestreamisgeneratedthatcontainsradioactivelycontaminatedethyleneglycolandwater.Thiswaterisprocessedon-sitepriortobeingreleasedtoOutfalls001,002or003.Sulfurhexafluoridegas(SF6)isutilizedinthenon.-contactcoolingwatersystemsattheplanttodetectleaksinvariouscomponentssuchasthecondensers.ThegasisinjectedinthecoolingwaterstreamanddischargedtoOutfalls001,002or003atlessthan54ul/L.DuringupsetconditionsitispossibletooverflowthecontentsoftheTurbineRoomSump(seeOutfallOOD)toOutfalls001,002and/or003iftheflowpathtotheon-siteabsorptionpondcannotbeused.0tnWter'scareOutfall002isanon-contactcoolingwaterdischarge.Mostofthenon-contactcoolingwaterisusedtocondensethesteamexhaustingfromthesteamdriventurbines.ThecondensercoolingwaterisdrawnfromLakeMichigan,screenedtoremovelargeparticlesentrainedinthewater,routedthroughtheUnit2condensersandthendischargedtoLakeMichigan.Outfall002alsoincludesSteamGeneratorBlowdown,PlantHeatingBoiler(describedlaterasinternalOutfallsOOA,OOBand00Crespectively),andtheReverseOsmosis(RO)system(describedonpage.10).Outfall002alsocontainstheeffluentflowfromtheEssentialServiceWater(ESW)system,Non-EssentialServiceWater(NESW)system,andmonitortankreleases.ESW(20,000GPMmaximum)isLakeMichiganwaterthatisusedtoprovidecoolingtoNuclearRegulatoryCommission(NRC)definedsafety-relatedequipmentandasanemergencybackupwatersupply. NESW(9000GPMmaximum)isalsoLakeMichiganwaterusedfornon-contactcooling,asasourceofwaterforthedemineralizedmakeupsystem,andtosupplywaterforNRCdefinednon-safetyrelatedequipment.Monitortankreleases(-20,000gallonsperevent)areregulatedbytheNRCandconsistofwastewatergeneratedwithintheAuxiliaryBuildingthathasbeenprocessedpriortothebatchdischarge.Thenon-contactcoolingwaterforthecirculatingwatersystem,theESWsystemandtheNESWsystemistreatedforbiologicalcontrolusingliquidsodiumhypochlorite,withtreatmentsusuallybeginninginMayandterminatinginNovember,dependingonLakeMichigantemperatures.Thebiocideisaddedattheintakeforebayandtheaverageresidualmeasuredinthedischargeismaintainedatlessthan0.2mg/latOutfall002.Thetreatmentslastfornomorethan160minutesperday.Ifcontinuouschlorinationisutilized,theresidualmeasuredinthedischargeismaintainedatlessthan0.036mg/latOutfall002.Thissamewaterisperiodicallytreatedusinganon-oxidizingbiocidetoeradicatethecoolingsystemsofzebramussels.Thebiocidesweareconsidering(BetzCT-1,BetzCT-2,BetzCT-4,CalgonH-130M,andNalco9210)areallpolyquatswhichwillbedetoxifiedasrequired,usingbentoniteclaytomeetwaterqualitybasedeffluentlimits.Thetreatmentsaredirectedtothecriticalsystemsfromtheintakestructureslocatedaboutone-halfmileoutinLakeMichiganthroughtheentireplantcoolingsystem,includingtheESWandNESWsystems.Systemsaretreateddependentuponzebramusselinfestation.Concentrationsandchemicalfeedpointsarechosentominimizetheamountofbiociderequiredandtomaximizethetreatmentprogram.Thesystemsmaybetreatedatthesametimeorindividuallytoallowmoreefficientuseofchemicals.Weplantotreatallsystemswithintheplantamaximumoftwiceperyear(sixapplicationsperyeartotal)toassuresafeoperationofthenucleargeneratingunits.ThecurrentNPDESpermitincludestheuseofsodiumbromideandsodiumhypochloritesolutionsfortreatmentofthecirculatingwatersystems. Thesesolutions,whicharethemajorconstituentsofmanyproprietarymixturessuchasNalcoActi-Brom,arepresentlybeingconsideredasthebasisoftheCookNuclearPlant'sstrategicplantocontrolzebramussels.Effectiveuseofthese~xidizingbiocidesareexpectedtoreducethefrequencyofnon-oxidizingbiocidetreatments.SeeAttachment3ofthecoverletterformoredetailsregardingourfuturezebramusselcontrolstrategy.Themonitortanksreceivetreatedwaterfromtheradioactivewasteremovalsystem.OnesystemhandlesthewasteforUnits1and2andtheAuxiliaryBuilding.Thissystemtreatswastesgeneratedfromthereactorcoolantpumpsealleakoffs,therefuelingcavitywater,equipmentleaks,floordrains,valvestemleakoffs,wastesamplesolutionsandlaboratorywastesfromtheradiochemistryanalysisinthehotchemicallaboratory,systemequipmentdrains,non-contactcoolingwateranddecontaminationprocesses.Thewasteis'collectedinoneofseveraltanksandtreatedwhenenoughwateriscollected.Thetreatmentutilizeseitheranevaporatorsystemorademineralizersystemtoremoveradioactivecontaminants.ThetreatedwaterisaccumulatedinthemonitortanksandsampledtoensurethewastemeetstheNuclearRegulatoryCommissionradiologicalrequirementspriortobeingdischargedintothecirculatingwatersystem.Periodically,duetoequipmentleaksand/orsystemupsets,awastestreamisgeneratedthatcontainsradioactivelycontaminatedethyleneglycolandwater.Thiswaterisprocessedon-sitepriortobeingreleasedto~Outfalls001,002or003.Sulfurhexafluoridegas(SF6)isutilizedinthenon-contactcoolingwatersystemsattheplanttodetectleaksinvariouscomponentssuchasthecondensers.ThegasisinjectedinthecoolingwaterstreamanddischargedtoOutfalls001,002or003atlessthan54ul/L.DuringupsetconditionsitispossibletooverflowthecontentsoftheTurbineRoomSump(seeOutfallOOD)toOutfalls001,002and/or003iftheflowpathtotheon-siteabsorptionpondcannotbeused. OUTFALL003-DeicinDischareOutfall003isadeicingdischargewhichisusedonalimitedbasis.AportionoftheflowfromOutfall001and/orOutfall002isdirectedthroughthecenterintaketunneltotempertheintakewaterandpreventicebuildupontheintakestructureswhichwouldrestrictintakeflow.UseofthisdischargeisgenerallyonlyrequiredduringtheperiodfromDecemberthroughAprildependingonwatertemperaturesandicebuildupalongtheshoresofLakeMichigan.ThechemicalconstituentofOutfall003isthesameasOutfalls001and002.OUTFALLOOA-Unit1SteamGeneratorBlowdownThesteamgeneratorsrequireultrahighpuritywaterforoperation.Makeupwaterusedinthesteamgeneratorsiswithdrawnfromtheintakeforebay(orfromLakeTownshipwatersupply)andessentiallyallnaturalimpuritiesareremovedthroughsedimentation,filtration,reverseosmosis,anddemineralization.Periodically,impuritiesenterthesteamgeneratorsthroughsystemcorrosiontransportmechanisms,themakeupwater,orsystemupsets(suchascondenserleakage)andmustberemovedtoprotectthesteamturbinesandheattransfersurfacesofthesteamgenerators.Theimpuritiesareremovedbydrainingaportionofthewaterfrom.thesteamgenerators.Inthesteamgenerator,steamisseparatedfromthewater,furtherheated,andthenroutedtotheturbines.Whenthesteamseparatesfromthewater,theimpuritiesremaininthewater,concentratinginthesteamgenerator.Blowdownconsistsoftwoforms,aliquidportion(700GPMmaximum)andawetsteamportionwhichisexhaustedtotheatmosphere.Theliquidportionofthesteamgeneratorblowdownisdischargedtothescreenhouseforebayeitherdirectly,orafterprocessingthroughmixedbeddemineralizers.Impuritiesinthisdischargemayconsistofinsolubleironandcopperandattimes,impuritiesfromthecoolingwater(LakeMichigan)usedtocoolthecondensers. Steamgeneratoradditivesconsistofammoniaand/ormonoethanolamine(ETA)forpHadjustment,hydrazineand/orcarbohydrazideforoxygenscavenging,andboricacidforcorrosionprotection..Periodically,sodiumnitriteisusedasatracertodeterminethesteamgeneratorblowdownratethrougheachofitsblowdownvalves.Duringunitoutages,thesteamgeneratorsarestoredfullofwater,includingtreatmentchemicals,toprotectagainstcorrosionduringstorage.Thislayupwaterisintermittentlydischarged(32,000gallonspersteamgenerator)throughOutfallOOAtoLakeMichigan.Thelayupwatercontainsamaximum.concentrationof400ppmhydrazineand/or40ppmcarbohydrazide,50ppmammoniaand/orETA,and20ppmboron.ThewastestrengthofthisdischargeisreducedthroughmixingwithOutfalls001,002or003bymorethan40,000times.Demineralizedwaterorsecondarywaterisusedtopressurecleanthesteamgeneratorsduringoutageperiods.Thewaterisrecirculatedthroughtemporaryfilterstoremovesuspendedsolids.Themajorconstituentofthesuspendedsolidsisironoxidefromthesteamgenerators.ThewateristhenreturnedtothesteamgeneratorsanddrainedtoOutfallsOOA,OOB,orOODviatheturbineroomsump.OUTFALLOOB-Unit2SteamGeneratorBlowdownThesteamgeneratorsrequireultrahighpuritywaterforoperation.Makeupwaterusedinthesteamgeneratorsiswithdrawnfromtheintakeforebay(orfromLakeTownshipwatersupply)andessentiallyallnaturalimpuritiesareremovedthroughsedimentation,filtration,reverseosmosis,anddemineralization.Periodically,impuritiesenterthesteamgeneratorsthroughsystemcorrosiontransportmechanisms,themakeupwater,orsystemupsets(suchascondenserleakage)andmustberemovedtoprotectthesteamturbinesandheattransfersurfacesofthesteamgenerators.Theimpuritiesareremovedbydrainingaportionofthewaterfromthesteamgenerator. Inthesteamgeneratorsteamisseparated.fromthewater,isfurtherheatedandthenroutedtotheturbines.Whenthesteamseparatesfromthewater,theimpuritiesremaininthewater,concentratinginthesteamgenerator.Blowdownconsistsoftwoforms,aliquidportion(700GPMmaximum)andawetsteamportionwhichisexhaustedtotheatmosphere.Theliquidportionofthesteamgeneratorblowdownisdischargedtothescreenhouseforebayeitherdirectly,orafterprocessingthroughmixedbeddemineralizers.Impuritiesinthisdischargemayconsistofinsolubleironandcopperandattimes,impuritiesfromthecoolingwater(LakeMichigan)usedtocoolthecondenser.Steamgeneratoradditivesconsistofammoniaand/ormonoethanolamine(ETA)forpHadjustment,andhydrazineand/orcarbohydrazideforoxygenscavenging.Periodically,sodiumnitriteisusedasatracertodeterminethesteamgeneratorblowdownratethrougheachofitsblowdownvalves.*Duringunitoutages,thesteamgeneratorsarestoredfullofwater,includingtreatmentchemicals,toprotectagainstcorrosionduringstorage.Thelayupwaterisintermittentlydischarged(32,000gallonspersteamgenerator)throughOutfallOOBtoLakeMichigan.Thelayupwatercontainsamaximumconcentrationof400ppmhydrazineand/or40ppmcarbohydrazide,and50ppmammoniaand/orETA.ThewastestrengthofthisdischargeisreducedthroughmixingwithOutfalls001,002or003bymorethan40,000times.Demineralizedwaterorsecondarywaterisusedtopressurecleanthesteamgeneratorsduringoutageperiods.Thewaterisrecirculatedthroughtemporaryfilterstoremovesuspendedsolids.Themajorconstituentofthesuspendedsolidsisironoxidefromthesteamgenerators.ThewateristhenreturnedtothesteamgeneratorsanddrainedtoOutfallsOOA,OOB,orOODviatheturbineroomsump.OUTFALLOOC-PlantHeatinBoilerAheatingboiler(150,000lb/hrcapacity)operatestosupplyplantheatingandauxiliarysteamwhenUnit1and/orUnit2steamgeneratorsareoutofservice.
'Theboilerisalsofiredapproximatelyoncepermonthfortestingpurposestoensureitsavailability.Impuritiesfromtheboilerwaterconsistingprimarilyofinsolubleironandcopper,aredischarged(30GPMmaximum)totheintakeforebay.Boilerwatertreatmentadditivesconsistofammoniaand/orETAforpHadjustmentandhydrazineand/orcarbohydrazideforoxygenscavenging.(SeeOutfallOODforwetlayupdrains)OUTFALLOOD-UtilitWasteWatersUtilitywastewaterfromwithintheplantisdischargedviatheturbineroomsump(TRS)intoanon-siteabsorptionpond.TheultimatedispositionofthesewastewatersistothegroundwhichventstoLakeMichigan.Thewastewatersinclude:Wastesfromthemakeupwatertreatmentsystem.Themaincontributorstothewastestreamare:themakeupplantdemineralizerregenerationwastes(average40,000gallonsperregeneration),degasifierpumpsealwater(108,000GPD),carbonfilterbackwashwater(average45,000GPD)andpre-filterbackwashwater(average72,000GPD).Theretentiontankperiodicallydischargesaverysmallvolumeofsolidmaterialremovedbysettling.Alum(aluminumsulfate)isaddedtothepre-filterinfluentasaflocculent.Thesepre-filtersarebackwashedtotheTRStoremovethesuspendedmattercapturedonthefiltermedia.ThealumcontainedinthebackwashisdischargedtotheTRSintheformofinsolublealuminumhydroxide.CarbonfiltersarealsoperiodicallybackwashedtotheTRS.Thesefiltersprimarilyremoveorganics,chlorineandsmallamountsofiron.Sulfuricacidandsodiumhydroxideusedbythemakeupdemineralizerstoregeneratetheresin,arerinsedtotheTRSandgenerallyneutralizeeachotherinthesumptoformsodiumsulfatepriortodischarge.Non-essentialservicewaterisusedtosupplyvacuumdegasifierpumpswhichutilizeapproximately75gpmtotalviatwopumpstoremovedissolvedgases(primarilycarbondioxideandoxygen)fromthevacuumdegasifierandexhaustthemtotheatmosphere. Anewcomponentofthemakeupplant,areverseosmosis(RO)system,hasbeeninstalledtoremovethebulkofthedissolvedsolidsfromthelakewaterpriortodemineralization.NormalrejectwaterflowistoLakeMichigan.TheROsystemmustmaintainverycleanmembranestoassureefficientoperationandpurityofwater.Severalmethodsareusedtomaintainthislevelofcleanlinessfromscaleandbiofouling.Usinghydrochloricacidorsulfuricacid,thefeedwaterpHisloweredtoreducethescalingtendenciesofthewater.Approximatelyoncepermonth,aflushisperformedusingapproximately0.5%hydrochloricacidandcaustictodissolveanyscalethatdepositsonthemembranes(average5000gallonspermonth).Chemicalcleaningisperformedwhentheaboveflushesarenolongerareeffective.Thechemicalcleaninginvolvesseveralstepsandmaycontaincitricacid,hydrochloricacid,phosphoricacid,sodiumhydroxideandaneutralpHdetergent(average10,000gallonsperevent).Also,toremovedeadbiologicalmatterfromthemembranes,asoakusingsodiumbisulfitemaybeperformedapproximatelyonceperyear(average5000gallonsperevent).eDuringperiodswhennotinoperation,theheatingboilerisstoredfulloftreatedboilerwatercontainingatmost400ppmhydrazineor40ppmcarbohydrazideforoxygenscavengingand50ppmammoniaor50ppmethanolamine(ETA)(forcorrosionprotection).Priortouse,this"wetlay-up"waterisdrainedtotheTRSfordischargeintotheabsorptionpond.Thevolumedrainedisapproximately1600gallonsandmayoccur30timesperyear.nDuringaunitoutage,thecondensersarecheckedforleaksbyfillingthesteamsidewithcondensatecontainingapproximately1000gramsoffluoresceindisodiumsaltorRhodamineB.Thesedyes,whicharefluorescentunderblacklight,aidinthedetectionofjointandtubeleaksduringvisualinspection.Thevolumeofwaterdrainedfromthecondensersrangesfrom160,000upto1,000,000gallonsandmayoccuronetimeperyear.10 Znaddition,thecoolingwatersideofthecondensersareperiodicallydrainedtotheTRSforgeneralmaintenanceperiodically(8condenserhalvesperunit,approximately25,000gallonsoflakewaterperhalf).Thecomponentcoolingwatersystem(CCW)isperiodicallydrainedtoallowforequipmentinspection,maintenanceorrepair.Thissystemusesdemineralizedwaterfromthemakeupplantasitssourceofmakeupwateralongwithamaximumof1200ppmnitrite(fromCalgonLCS60)and100ppmglutaraldehydeastreatmentchemicals..Theinfrequentdrainingsreleaseapproximately60,000gallonsoftreatedwatertotheTRSperyear.Thedieselgeneratorcoolingjacketwatersystem(DJW)employsthesamechemicalcontrolforcorrosionasinthecomponentcoolingwatersystemwithamaximumof2000ppmnitritesfromCalgonLCS60.ThissystemisdrainedthroughthefloordrainstotheTRSwhenmaintenanceisperformed.Thesystemvolumeisapproximately1000gallons.Anyminorsystemleakswouldalsobedirectedtothefloordrainduringnormaloperations.Theessentialservicewatersystems(ESW)andnon-essentialservicewatersystems(NESW)arealsoperiodicallydrainedtoallowforequipmentinspection,maintenance,orrepair.Thesedrainsmaydischargeapproximately72,000gallonsofLakeMichiganwaterusedfornon-contactcoolingintotheTRS.Thiswateriseitherchlorinatedintermittentlyataresidualconcentrationof0.2mg/1TRCorcontinuouslyat0.036mg/lTRC.Duringsomespecialtreatmentperiods,thiswatermaycontainzebramusselbiocides,usedasamolluscicideforzebramusselcontrol.Periodically,componentsoftheESWorNESWsystemsmaybechemicallycleanedtoremoveirondepositsusingvendorsuppliedcleaningsolutionsuchasEDTA(ethylenediaminetetraaceticacid)orascorbicacid,aceticacidandammonia.ThesewastescouldeitherbedrainedtotheTRSorLakeMichigan.11 Thesteamgenerators(S/G)aredrainedforinspectionandmaintenanceduringscheduledunitoutages(approximatelyevery18months)andduringaneventwheresteamgeneratorfailureisdetectedthatrequiresaunitshutdown.Thesteamgeneratorsutilize150ppbhydrazine(fromeitherdirecthydrazinefeedorasabreakdownproductofcarbohydrazide),20ppmammonia,and2.5ppmETAtocontrolthewaterandsteamchemistrytobenon-.aggressivetocyclecomponents.Unit1steamgeneratorsalsoutilize10ppmborontocontrolcorrosion.Asteamgeneratorvolumereleasedduringthedrainingisapproximately32,000gallonseach.Duringwetlay-up,theS/Gsarestoredfullofwaterwithupto400ppmofhydrazineor40ppmcarbohydrazideand50ppmammoniaorETAareaddedforcorrosioncontrol.ThiswaterisnormallydrainedtosurfacewaterviaNPDESOutfallsOOAorOOB,butmaybedrainedtotheTRSinsomeinstances.ThemiscellaneousdraintankscanbealignedtodischargetotheTRS.Asmuchas350,000gallonsperdaymaybedirectedtotheTRStocontrolthechemistrylimitationsonthesecondarywatersystems.Waterchemistryisprimarilythesameasinthesteamgenerators.Aroundtheplant,miscellaneoussumpscollectapproximately45,000GPDofwaterfromvariousequipmentdrains,leaks,pumpseals,andsteamjetairejectordrains.Thefrequencyofdischargeandtypesofchemicalsusedinthisequipmenthavebeendescribedelsewhereinthisdescription.Mi.scellanoousfloordrainsarelocatedthroughouttheplanttoprovideasafeworkingenvironmentbyroutingspilledorleakedwatertotheTRS.Themajorchemicalinfluxintothesedrainsarefromthedetergentsandwaxesusedtomaintainthefloors.AlsoroutedtotheTRSthroughthefloordrainsarethechemicalfeedtankdrains,fireprotectionwater,drinkingwater,coolingwater,anddrainsfrombioboxesusedtomonitorthezebramusselcontrolmeasuresandotherchemicalcontrolmonitors.Thechemicalfeedtankswhichmaybedrainedcontainhydrazine,ammonia,boron,ETA,carbohydrazide,andsodiumhypochlorite.Thebioboxeswilldischargechlorineandzebramusselbiocidesduringtreatments.12 Non-ra4iologicalchemicallabsinkandfloordrainsareroutedtotheTRSfordisposal.Thedrainscarrywaterandthewastesgeneratedwhileperforminganalysesandpreparinglaboratorystandardsincludingthoseontheattachedlist.Alsodischargedwillbeglasswareandnormallaboratorycleaningwastes.TheaveragevolumedirectedtotheTRSisestimatedtobe500-1000GPD.8econdary(steamgeneratororcondensate)samplewaterfromcontinuousanalyzersareroutedtodrainswhichdischargetotheTRSandthemiscellaneousdraintank.Theanalyzersareonthecycleswhichmaycontainasmuchas10ppmboron,150ppbhydrazine(fromeitheradirectfeedorasabreakdownproductofcarbohydrazide),20ppmammonia,'nd2.5ppmethanolamine.Theanalyzersmeasurecorrosiontransportataaverageflowof8500gallonsperday.Mi.scellaneoussealingan4coolingwatersuppliescoolingandsealingwatertotheTRSpumps,condensateboosterpumps,circulatingwaterpumps,vacuumprimingpumps,drainsealreservoirtanksanddrainsamplecoolers.Theaverageflowperdayisapproximately150,000gallons.Non-essentialservicewatersuppliesapproximately53,000GPDofnon-contactcoolingwatertovarioussamplecoolersthroughouttheplant'sturbinebuildingincludingtheconductivityroomandthesteamjetairejectorsamplepoints.ChemicalspillsthatentertheTRSmaybeneutralizedwithinthesump'topreventadischargetotheenvironment.ThepotentialforspillstotheTRSexistsforthefollowingchemicalswiththeproposedneutralizerslisted:~Ce~icaSulfuricacidSodiumhydroxideSodiumhypochloriteHydrazineEthyleneglycolNeutralizerSodiumhydroxideSulfuricacidSodiumthiosulfateNESW(lakewater),Hydrogenperoxide13
OUTFALLOOE-SanitarWasteDischaresSanitarywastesarepresentlysegregatedandroutedtotwoextendedaerationpackagetreatmentplants.Theexistingequipmentisdesignedtotreat50,000GPDandtheeffluentfromthesewagetreatmentplantsdischargeintooneofthetwoseepagelagoons.ThelagoonsdischargeintothegroundwaterwiththeultimatedispositionbeingLakeMichigan.ThesludgeremovedfromthesedimentationtankbasinsistakentoalocalPOTW(publicownedtreatmentworks)fordisposalordewateredandstoredaslowlevelradioactivewaste,asappropriate.1Plantsanitarywasteconsistsofshowerandrestroomfacilities,andjanitorwashbasinslocatedthroughoutthePlant'snon-radiologicalproperty.Kitchenwastesaregeneratedfromtheplantcafeteria,theCookEnergyXnformationCenterandTrainingbuildings.Thechemistrytraininglaboratorydischargestothesewagetreatmentplantsthroughalimestonebedneutralizationtank.Thechemistrylabisusedtotraintechniciansonanalysesperformedintheplant.Thedischargefromthelabcarrieswaterandwastesgeneratedwhileperforminganalysesandpreparinglaboratorystandardsincludingthoseontheattachedlist.Asmallphotolab,inthetrainingbuilding,uses(onaemergencybasis)smallquantitiesofhydroquinone'odevelopblackandwhitepicturesforplantuse.ThetrainingbuildingHVACsystemalsodrainstothelimestonebed.Aradiographylabintheplantalsodischargessmallquantitiesofprocessingchemicalsfornon-destructivetestingintheplant.Noneoftheradiography.productscontaincriticalmaterialsorprioritypollutants.Allportabletoiletwastesontheplantsitearecollectedanddischargedtothepackageplants.Abiodegradabledeodorantisusedintheportabletoilets.Sludgeeffluentwastemayalsoberecycledthroughtheplantstodecreasetheamountofsludgeforprocessingwhenpossible.Miscellaneousrinsingofwastereceptaclesandpossiblecleaningoperationswaste,utilizingvariousdetergents,mayberinsedtothesewagetreatmentplants.14
MiscellaneousOutfallsThemainplanttransformersoneachunitarelocatedwithinconcreteberms.Thebermsareforspillcontainmentshoulda~catastrophicfailureofatransformeroccur.Toprotectagainstoperationalandsafetyconcernswhichstemfrompondedwater,these'areasgravitydraintooil/waterseparatorsspecificforeachunit.Eachseparatorisabelowgroundconcretebasindesignedtoretainoilandreleasewatertoaseriesofdrywells.Alsodischargingintotheseparators,aretheemergencydieselgeneratorpitsumps.Thesesumpscollectlimitedwaterandfueloil(lessthan500gallonsperyear)fromtheemergencydieselgeneratorroom.Periodically,theoil/waterseparatorsarepumpedcleantoremovetheaccumulatedoilforproperoff-sitedisposal.ThesecuritydieselgeneratordaytankhasanoverflowlinethatconnectstotheUnitOnetransformerdeckcatchbasin.Dischargetothe~catchbasinwouldonlyoccurifthedaytankwereoverfilled.Proceduresandlevelindicatorsareusedtopreventoverfilling.15
CHEMICALLABANALYSISAdditionalInformationSectionIItem6,SubpartACookNuclearPlantSurfaceWaterPermitApplicationPLANTCHEMISTRYLAB(toOutfallOOD)ChlorideFluorideHardnessHydrazineSilicaOil6GreasepHFreeMineralAcidityTotalPhosphorusChemicalOxygenDemandSulfateNitritesTotalResidualChlorineASTMD-512-81(1986)ASTMD-1179-80(1986)StandardMethods413B(1985)ASTMD-1126-80EPA-600-4-79-020Method130.2(1979)ASTMD-1385(1983)ASTMDPowerWaterAnalysisManualCH-41EPA-600-4-79-020Method413.1(1979)ASTMD-1293-84StandardMethods423(1985)ASTMD-1067-82MethodBEPA-600-4-79-020Method365.3(1979)EPA-600-4-79-020Method410.2(1979)ASTMD-516-82MethodA(1985)EPA-600-4"79-020Method375.3(1979)StandardMethods426A(1980)DeterminationofCorrosionInhibitionbyCalgonCorporationASTMD-1253(1986)StandardMethods(1980)TRAININGBUILDINGLAB(toOutfallOOE)BoronChlorideFluorideHardnessHydrazineSilicaOil6GreasepHTotalPhosphorusAtomicAbsorptionMetalsIonChromatographyWestinghouseChemicalAnalysisProcedureforPWRWCAD7333Rev.1(1973)ASTMD-512-81(1986)ASTMD-1179-80(1986)StandardMethods413B(1985)ASTMD-1126-80EPA-600-4-79-020Method130.2(1979)ASTMD-1385(1983)ASTMPowerWaterAnalysisManualCH-41EPA-600-4-79-020Method413.1(1979)ASTMD-1293-84StandardMethods423(1985)EPA-600-4-79-020Method365.3(1979)StandardMethods302B,303A(1985)EPA-600-4-79-020Method215F1,220.1,2421~2491g273'(1979)DionexSystemOperatorsManual 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SectionI,Item12ADJACENTPROPERTYOWNERSPage211-1100060002-030004-000004-040004-010004-0211-11-00070013-000013-010006-010001-010004-0111-11-000500290036-010027-000036-000036-0211-11-0005-000201-611-11-0008MichiganDept.ofNaturalResources;P.O.Box30028;Lansing,MI48909FranklinRealEstateCo.;P.O.Box2000;St.Joseph,MI49085Temmel,EdwardP.;9617E.ShoreDr.;OakLawn,IL60453Caparo,WilliamE.&Oyler,KathrynE.;122S.EllsworthPl.;SouthBend,IN46635RosemaryBeachCorp.;c/oSecretary;3415S.59thSt.;Cicero,IL60650LakeCharterTwp.;ShawneeRd.;Bridgman,MI49106LakeCharterTwp.;ShawneeRd.;Bridgman,MI49106IndianaMichiganPowerCompanyLakeCharterTwp.;ShawneeRd.;Bridgman,MI49106LakeCharterTwp.;ShawneeRd.;Bridgman,MI49106Technisand,Inc.;11833RavennaRd.;Chardon,OH44024Ruff,TimothyW.;P.O.Box504Bridgman,MI49106Technisand,Inc.;11833RavennaRd.;Chardon,OH44024Emery,Martin;Hopkins,ElwoodJ.&MableN.;7499ThorntonDr.;Stevensville,MI49127IndianaMichiganPowerCompanyBankofAmericaTexasP.O.Box650380Dallas,TX752650041-000009-00MichiganDept.ofTransportation;Lansing,MI48900FranklinRealEstateCo.;P.O.Box2000;St.Joseph,MI49085 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SEEINSTRUCTIONS'NREVERSESIDESECTlONtIPERMIT~eII0005827NUMBERCBEMOJIFkLIU'FEA.ISeeIEDISCHARGEFROMTHISOUTFALLDIRECTEDTOTHEGRCUt41CRGRQVtCWATERS2IIFtoeCONTINUETQITEM5)YESAOtleGROUNDWATERDISCHARGEINFORMATIONB.TWASAstYDROGECLCGICALSTVDYORITSEQUIVALENTBEENPERFORMEDORISTHERESIFFICIENTCURRENTHYDROGEQLQGICALINFORMATIONAVAIIABLEASREQUIREDBYDEwATERRESOURCESH~ISSICNPART22GRCVADWATERRNPSCFAUGUST141%6R,$23,22O7(PAGE4Q)FQRDttsEXISTINGCiRPROPOSEDDISCHARGE.IFYESATTACHACOPYOFIHEREPORT.C*REYCVREQUESTINGANEXEMPTICttFRCMSUBMITTINGAHYDROGEOLOGICALREPCRTVteDERRULER.323.22(I(Lo)(PAJGEtttt)QRFROMGRQLNDWLTERHQIIITORtttsI)EQVJREHEttTSVNDERRULER'>Zse/JUICE(5)(PAGELl)OFTHEPART22RIES~IF'ESATTACHCOON'S441EXPLANATtONTQDEttQNSTRAIETHATYAHDISCHARGEWIXaDQUALIFYFORANEXEt1sIQtt.DeAREYOUREQUESTtttlAVARIAttCEFRCMRULE323e2205(PAGE5)(ttQttDEGRADATICN)OFTHEWATERREsoURcEscQtTttssIONPART22GRQUNDtATERRULEs2IFYEs,ATTAcHsUcHDQCVtENTSAStiECESSARYTODEMONSTRATETHENEEDFCRAYARIANCEINTERMSQFTttCRITERIASPECIFIEDINRIAE325.2210(PAGE~CFTHEPART22RULES~NANA'es:cYESITEM5EXPECTEDWASTEWATSIICHARAC-ISTICSUsi..aCODE1Mg/I2Ug/I3COUNTS/100mt4S.U.5F6LBS/DAY11%APF1.ICANTIAAYBERECUIRED10DOADDITIONALWASTEANALYSESeA>>DISCHARGECHARACTERISTICSCQNCEttTRATICttQNQTAPPLICABLE/BELIEVEDABSENTNAPRESENTSCATAPROVIDEDINITEM7NITSCODEttANALYSESSA"PLETYPECODEBQD5(FIYEDAYB1octetlcALoxYGENDETAAttD)CQD(CHEMICALOXYGENDEMAND)TOC(TOTALORGANICCARBON)AtfEXIIANITROGEN(ASN)TOTALSUSPENDEDSOLIDSTOTALPt42SPtCRUS(ASP)TOTALRESIDUALCtLORINEDISSOLVEDOXYGENPHHIN~7~0FECALCOLIFORMBACTERIATEMPERATURE(SttttER)mdivTEE(WINTER)~0,~ll8l.u3~65,~5~0~20~8~2~83~4ulLlJ~uul~uululululu3u3BeOTHERWASTEWATERCHARACTERISTICSEeI,ISTAI,LCHSIICALSIBSTANCESWHICHAREINMICHIGAN'SCRITICALMATERIALSREGISTERTABLEIV'LPAGEII)AND/QRUSeEPASPRIORITYPIXLUTANTLISTTABLEV(PAGE7)ORANYOTHERSIISTANCESNIICHAREORtAAYBKQKINJUIICUSTO1%DESIGNIITEDUSESOFT%GSXNDWATERORTOTHEPUBLICHEALTH1HATAREDISCHARGEDOREXPECTEDTOBEDISCHSIIGEDTO11%GROutDWATERAYTHISFACILITY.ESTIMATE1HEFINALEFFLUENTCONCEtttRATIONAADRECORDALLDATAINITEN7OFSECTIONllIN1HISBODICE~SAATRLR2222.1GRAB224HOURCOMPOSIyE0II.BCeREASEI-LJLJLJLJ~LJLJ~LJLJLJDMRSREQUIREDINFQI4tATI(XtFCRSURFACEWATERDISCHARGEseLJSEEATTACHEDSHEETSFORANALYSISDATA*Basis:1993actualdatasubmittedonuu35 8'r'rcraii~>>c~~>7Ev5'"'05sr<<.8>>Jiresnrcr.dticncn338>>ri<<TiIrI,rscdr'gingei"BrI'8grcuncwntersrTr'85ur.dcB<<dters.VI7'."BE>>ru7RE~X3~iE0rF7i(5CRY.PEEBI7IASvBERCAVEEFCvNOCrlTpEFPCT(7PAGECFyCQREAPIR(r;5533ne>>crnctprevious:vcermlttec'dciIitv,-henledveblankdnd3hurberwlIIbeassicned.I<<<<-.:8>>'"7"85:3>>B3>>av:sec'3>>sdr>>".dceor5ec-(cn',I.=crBachindlvidunid(sc>dreecc>>5separa-eset"ei<<Eid3~,c'rcv>>tii'r'3*E(.ii'JcIC'rrhBCFBAI'IIrrirl5I~Eu)SCCI.'cdr,tShallsdcresseacha!-nese=artsI'eciscndrce'-an-.".IsoutfnlI:5TaThegrauhc<<nte>>.I'7E4I=.I5~l'.G".P.KaEC.E"(FCRAKE)rO(5CHARGE)rr35EhATERC!ACACTEPI57lrg5<PROV\O'irATERCR5I'RFACE'rrATERO(5CP'RGE("O'!07lrCI.UOE.-C.I'<ru,'RvA7III~irl>ruI7heapplicantshallreportavailabledischargednt:(realdatatorex(stingdischargeorexpecteddatafor3proposeddischarge)tcrTheparnrre<<ersdsIi5ted.74838parametersshallbeaddressedfareither3surfacewaterdischargeorssappropriatetor3:raurCwaterCISCndrge.FOrSSSIStanCeIndeterminingapprOpriatebarnmeterS3grOundWaterd(SCharCenppl)CnntmnyCantdCtThe~rcurc<<dtergua)itvOlvlsicn,Permits5BC;icncrThedcorcprlateGraundwdTerQudlitvOivislan'5Oi5trlcta!flee.",.<<ocr)cant5"all>>Boar."esdmoletvpecedebestsescribirgBdchreparRdoleceofdata.Seecad(rcant"eleftmarginofn:5!err."is:'T!3:I53surface<<sterl5Cr',8dept~cant-ust-Boer"."antiTntivedatafcredenparameterIdentifiedbvanTs,er3<<.;8dppiicdntmav,however,,dcqest--dt-nerepor-hca:dtdcrcneormareoTneserecuirecparsretersbe<<diveC.Cn8".'BSTustbe5'opal'.BCbvSCBcudte3(Chare.dkBSucharecueSTdnattachmentTOthisapplication.'3,3~5Svdiidb'8tcrotherpara>>ietersrCTI~stecSbavein'.Crotherpdr'TsofThi5dcpllcatiohThesap()cant5havldrepor'T-dt"3rdinTre:rdnxSPacescrovlcedlnthispart.rg7E5.r)nitcodesforparametersreportedInoartsAdndBcanbefoundontheletthandsideofthisform.:rnb53BO(eSnaileuSeot"Sra(VZe'OrCrr~Temberature,TO<<dlPhenO(S,reSidualChlarlre,OiISndgredSe,nndfecalcoliformInasur!dcewaterdiscnnrceunlessother!recuencv-sampletypeanalysessreavaable.SeeGlossary(pace48)fardetlnitlonotgrabsample.'3-i)ourcompos(!8samplessnailbeusedtoanalyzercr.otalBM>>,coo,7cc,Ammon(aIlitrogen.dndiotdlSuspendedEalicsIn3surface<<sterclscnarreunlessother'recuency-sampletvoeanalysesareavailable.SeeGlossnry(pace4B)fordefinitioncfccr.casitesdmole.ceo<<7"rur:FI'rTAKE373.'Ci,3rdnatrecviredTcreccr'.Classycv<<isnTodemonstratevourBllcibilltytcra"eterrluentlimitation'c"cnecrcreallvtdnts,ThsTis~dneffluentlimitationadjustedbysubtractingthedverdcelevelattheoollutdnt(s)presentInyourIntakewater.VpoESregulationsa(lawnetlimitationsonlyin:ertainerrcumstnnces.acercnstrdzevourBlicibili.v,repor.-hesverdceofTr'eresultsotdnalvsesonyour'nts<<e<<ster(itvour<<ster35TentedberCre<<Se,BS.-neaTeratterltistreated),3cattaCnaSeparate3>>BBT=5-Sining-8rCIIC<<ircrar83Ch:Crrutsnt:(5)'<<3-<<Bnt"ST<<"8r>>make<<dter'5drawni>>cm"8cccv=<<sternta<<nlcn<<heci5cndrceis<<ade.,Ther>>ISBw>>u3r'B>>cT8iiib)ercrBT'>>I3lans.)Std<<8>>entCi<<"8BXTBnt.a>>hi.",>>8'BVBlC~TneCalrutnrT(5rBrluCBCbyTreatmentCt'rCur<<35TBWdtBr.-vcurlinlt3T(onswi(IceadjustedonlyTcTheextentthatThepcrlvtdnt:5nctreeved.)fc)xhenapplicable(torexdmpte,whentneoollutantrepresents3classotco.pounds)~3demonststionottheextent<<awlIcri<<hepollutantsiqhel>>take.Brvt"vs(ca!Iv,8<<lcd(!v,>>rb)alacics'Ivra~"8cc(lu3"TsIcntnl"BcivcurCi5cndt'CB.Your:miTat*5-5<<':r38SC'.Ste-CriyTaTreBXtent-dtTreIrTd<<eColli)tanTS:3natvary!romthedlscndraeoPailvtanTS.:ic'.naveto>>-cre).cst>>"id)icr'vTcsameidSncd>>5Iv[8g55"~dllvICPntcdia>>P'I~'"CentredI."53.,3~Tv>>8uast=er,isslonIr~vcur:erlttlrr,~v"8cvdrI}.5<<bml885<<I5arned<<atvs)5irarBrSupstdrtin(Iyst3:>>3"-o1:i"838~i--'"cduthcri:,crdsepsr3teshee-3-Sc"Bctc.<<we-CIes:-:benv-.ecuridilshier.Cu"C-Ct-eStdre SEEINSTRUCTIONSONREVERSESIDE0IIt.kLNXBSECTlONllPERMIT~MI0005827NUMBER~001eTEM6PRIORITYPOLLUTANTSANDADDITIONALINFORMATIONFORSURFACEWATEROISCHARGEONLY<ATEFCI'OWINGREQUESTEDINFORt'ATIOtt~c>><ccA"DRESSED~~SIRFACEWATERDISCHARGERS>IIQIEI.'>EwUSEDISCHARGERSe~>>PRQYICEggECTEDVALUESFQRThEQUAIITITATIVEAttDQ~lTATIVEIhFOR"ATICNREQUESTEDBELCH,A.ISTHISFACILllYAPRit>PRYIIKLSTRY2(REFGITOTABLEIAPAGE4+t>c>C,GQTQE)(tFVESGQTG8)8INDICATETYPEGFPRIMARYINDUSTRYASLls~INTABLEIAPAGE49~<CCtlfttNKWITHC~)C>XESTHISCUfFALLDISCHARGECCttfAIMANYPROCESSWASTKWATKR2(>FNQ>GQTOE)'IIFYES,GOTQD)NDICATEWHICHC/YSFRACT'CNSMUSTBE>FSTEDFOR(REFERTOTABLEtAPCiE4~tIIQIE!FCREACHGC/t'SFRACTIONCHECKED,EACHSPECIFICORGANICTOXICPOI'TAMTWITHINEACHFRACTIONf2!!5JBEAIIALYZEDFQR(SEETABLEI(APAGE92.IHADitITICM>ALLPRIPARYttKXISTRYAPPLICANTSWITHAPRQCESSWASTEWATERDISCHARGE~PROVIDEQUAMflTATIVEDATAFOREACHTOXICPOLLUTANTINTABLElllAPA;EQ)>RECCRDAU.DATAGNFCRMSPROVIDED(ITEM7)INTHISBCOXLET>(CQNTIIAIEWITHE-t(BELOW)XYEsSTMELECPtMRXYESQ>oXVIXATILEQXBASE/NFUTRALXACIDPESTICIDE*'.IF~SURFACEWATERDISOIARGEAPPLICAMT(PRIMlRYQRSECCNCARYINDUSTRY),REGARDLESSOFTHETYPEOFDISCHARGE>KtCWSORHASREASONTOBELIEVETHATANYPIXLUfANTLISTEDINTABLEIIAANDIVAPAGES~ISDISCHARGEDFRCMANYOUTFAU.>THEQUANTITATIVEDATA~BKPROVIDED>RECORDALLDATAONFORMSPROVIDED(ITK>t7)INTHISBOOKLET>NQTAPPLICABLE/BEI.IEVEDABSENTOOXPRESENT/CATAISATTAOlKDF.IFANYSURFACEWATERDISOURGEAPPLICAVT(PRIMARYORSECONDARYltGXJSTRY)>REGARDLESSOFTYPEQFDISCIIUIGE>KtCHSORHASREASONTOBELtEVEANYPOLLUTANTSUSTEDINTABLEVAPAGE+AREDISCHARGEDFRtYIANYOUTFALLTHEAPPLICANT~>DESCRIBEREASONSFORTHEPOLLUTANTBEtt5PRESENTANDPROVIDEANYAVAILAB(EQUANTITATIVEDATA>RECORDALLDATAONFORMSPROVIDED(ITEM7)INTHISBOOKLET.G>ALLSNFACEWATERDISCHARGEAPPLICAMTS(PRIMARYANDSECONDARYINDUSTRIES)WHO'QRHAMIX'ACTMES2,4,5-TRICILCACPHENQXfACETICACID(2,4,5-T);(>4>5TRIOkDROPHENQXY)PROPANQICACID(SILVEX>2>4>5>TP)'I%7HYLU(2>4>5TRICRDROPHENYL)PNSPHQROTHIOATE(ROWEL)'TRICtLQRQPHEIOL(TOPI'RHEXACHJOROPHEt>E(KP)'ALLDATAFORTHEABOVEPI/STBEGENERATEDUSIt6STANDARDANALYTICALCALIBRAlIONPROCKDIRES)QRKt4WSORHASREASONTQBELIEVETHATTCCDISORMAYBEPRESEMfIMTHEIRDISCHARGE>>~REPORT%ALITATIVEDATA>GENERATEDWHICIIgjEDASCREENINGPROCKDNENQTCALIBRATEDWITHANALYTICALSTAIIDARDS,FQR2,5,/)8,-TKTRACHLORQDIBENZOPDIOXIN(TcDD)~REcQRDALLcATA0NFQRMsPRovlDED(ITEMk)IMTHtsBQoxLET.J~IFThESURFACEWATERDISCHARGEAPPLICA'gKtCWSCRHASREASONTQBELIEYK>>ATBIQUXIICAITQXICtTYTESTSwERE."ACEINTHELASTTHREE(5)YSlRSQttAtttOFTt>E<<FLIC"'tf5DISOIARGESQRONARECEIVINGWATERlitRELATIQttTQADISCHARGE>FROVIDETHISIt>FORhATICNASANATTACHMENTTQTHISAPPLICATIOM>tFACONDUCTVBQRATORYORCONSll.TINGFIRMPERFORMEDAtftOFTteANLAYSESREQUIREDBYTHISAPPLICATION>PROVIDETHENAMEANDADDRESSOFEACHVBGRATORYORFIRMANDTHEANALYSESPERFORMEDASANATTAQC%HTOFTHISAPPLICATIQtt~COYQUDISCHARGEANYOTHERTOXICCRINJIRIOUSCHEMICALSISSTANCESNQTLISTEDIttTABLESIVPAGE(IAtKIttATHIOUt4lVAPAtiES~~+~'>c+ES>THENIDENTlcYTHEICALSUBSTANCESANDESTIMATETHEFtttALEFFLUEMTCCNCENTRATIONS.SLKttITTHISthFOBATICNASANAITAt&%lPTOTHISAPPLICATION>QXNQTAPPLICABLE/BELIEVEDABSENTPRESENT/DATAISATTACHEDOXNQTAPPLICABLE/BELIEVEDABSENTQPRESENT/CATAISATTACHEDNQTAPPLICABLEClQXAPPLICABLE/SKEATTACHEDQNOTAPPLICABLEXAPPLICABLE/SEEATTACHEDXNQTAPPI.ICABLEClAPPI.ICABLE/SEEATTACHED*Pesticidedataisnotrequired;however,itisprovided. vIIv)~'-es'"=-5'".."Pn3)cec'.'Icout<<5)I-'scnarc)"ctc-"es>>rfece<<aters."Jv='==7<<5."",nl5FCRu~'"5egos<IT"tt3BEPCAN":cg.t(OCNT>>BorNTe<(:eOFv"(.'Rexoip('.c)5:53;e>>ornctcrevicuslvperltteciaciIl-v,tnenleaveblanxanc3nunoer<<:IIbe3ssicnec.<<"espaceDv'ofcredc,"ageieticn.'.-<<escn're<vidualciscnarcecoin35e"arete51ustsai'ec>>t~T=4l5'TOTS:"'ouhave.<<ocr'iore5ub5tantlallvIncenzlcaioutfalls.vou"avreccestcenlssicn!rmvourcere!tt(naauthor(tv-cIaxpleancsnalvecrlyoneoutfelIanosufittheresultsctheandlvsi5orhersubs'tantielivicen.I-alu.fbiIs.(vous"ec<<estIsorantecby."epe~it<<lngauthorltv,onaseparatesheetatachedtctheapplicationfc~)centifv<<nicno'.ail,ouictest.anccase.ice>>nvtheoutfallsinichvouCICrottestsresubstantiallvicentlcal-otheoutfall<<n(CnycuCidte5t.e~anoartI".I<c)(B),Fricav,AprlII~IBB3,provicesicraSea<I='siness:xemptlon!.onthereportingofcuantltativecataIcrorganictoxicpollutantsanctoxicpollutantsasrecuiredbv>artl22.I(q)<7)(ll)<A)or122.2I<c)<7)(ill)(A).hesepartsareself-exolanatoryancconotrequirefurherinstructions.Siplygothrougheachportanccoaslndlcatec.Severalndustrl'slcategoriesancsuocsteccrlesnavepeenexeotec'rx5uo.I~t'"cCatacncertainriG/usFractions:30CeqPart)22,/OI.JB,"O.".-',=".IC3V,'Pr'llI.)793,'.OteSI.,)no3:.Revie>>thefo(ic<<ingi(sttocetemine>>nethervourfacilitycubi)liestoceexemptfreereportingG/NS<tasChr<xnatograonv/uassSpectrosccpy).=ractlons.TextilePillsIncustrvGC/u5FractlcnTestingandRepor,IrgExemptions-All'ourGC/uSorganicfractionslntheGreiqeu(ilsSuocategory.-PesticidefractioninailothersubpartsofthisIncu5try.OreMinlnoandQresslnoIndustry-lolatlle,base/neutral,andpesticlcefractionsIntieBaseancpreciousuetalssubcategory.-AlltourGc/usorqanicfractionsInallothersubcategoriesofthisIndustrv.GunandWoodChenicalsIndustry-PesticideFractionintheTalIOiIRosinSubcategoryandtheRosinBasedOerivativesSubcategory..Pesticideandbase/neutralfractionsInallotherSubcateqoriesofthisindustry.PulpandPaperIndustry.PesticidefractioninPaperqradesulfitesubcateoories(subpartsJandU)..Base/neutralandpe5ticldefractionsinOeinkSubpartQ,DissolvinaKraftSubpartF,andPaperboardfrc<<3MastePaperSubpartE.-Vole!ile.base/neutral,pesticidefractionsintheBCTBleacnedKraftSubpartH,Sem(-chemicalSuboartsBandC,andNonintegratedFinePaperSSubpartR.-Acid,base/neutral,andpesticideFractionsinFineBleachedKraftSubpartI,OlssolvlnqSulfitePuloSubpartK,Ground-woodFinePaperSSubpartO.HarketBleachedKraftSubpartG,TissuefrtxeMastepaperSubpartT,andNoninteqratedTissuePapersSubpart5,Stean<<ElectricPo>>erPlantIndustry.Base/neutralfractionintheOnce-Throughcooling'uater,FlyAsh.andBottc<<nAshTransportMaterprocess<<astestrear<<s.38 SEEINSTRUCTIONSONREVERSESIDESECTIONIINUMBER~i~fI00058279JIFkLelJKI~00!CRITICALPIATERIALSTOXIC)LLUTANTSUSETHISDATASHEETTORECORDINFORMATIONASREQJIREDINl(CHECKAPPROPRIATEBOXFORttlICHItIFCRtIATICNTHIS""TASITEETRE'ESFJITS~)SECTIONIlpITEMII-EeGROWDWATERDISCHARGEINFORMATION(PAGE59CIO2eSECTICNIIpITD!6ePRIORITYPOLLUTANfSINSIJIFACEWATERDISCH4RGE(PAGE~~X3.B.BELOW:CRITICALMATERIALS(TABLEIV)INSURFACEWATERDISCHARGE(PAGE39)ZARDOUSJBSTANCESIN3ISCHARGEBeLISTAtA'RITICALtATERIAL(TABLEIVPAGE6)NOTADDRESSEDINSECTIONIIITEMF'RIORllYPOLUJTWifs'eettICHYOUIeete4tORHAVEREASONTOBELIEVETOEEPRESEIITINT%DISOARGEPSEEREVERSESIDEOFTHISPAGEFORFUJAFRDIRECTIats.NOTAPPLICABLEXAPPLICABLE(SEEBELOII)K144~IAeNAMEOFCRITICALMATERIALCRPRIORITYIXJLLUTA'8B.AVERAGECCNCEJnRATICNJSAMPLETYPE;¹OFANALYSESC.AAXIWCaiCENTRATIONAtoMASSAeN/tAZCFCRITeiCALAIATERIALORPRIORITYPOLLUTAttfBAVERAGECaICENIRATIONJSAMPLElYPEl¹OFANALYSESc..AXItlftcaICENTRATIONeoMASS*SodiumHypochlorite.CLASS01/4~0~gj~]~LJ~FV~0~20'~1~178~4"'~3WITCODESAMPLETYPEOFANALYSESLJWITCODEWITCODENITSCODEMg/IUg/II~/DAY~/DaVIAPEETYPEGRAB24HR.COMP.AetIAMEOFCRITICALMATERIALORPRICRllYPOuJJTANTB~AVERAGECCtICENIRATIONJSAMPLETYPE;¹OFANALYSESCeNAXINNCONCENIRATICNANDMASSAeNAMEOFCRITICALMATERIALCRPRIORllYPOLLUTANTB.AVERAGECC:ICENTPATION;SAMPLETYPEJ".OFANALYSESC~MAXIMACctCENIRATICNANDMASSAetIAe%OFCRITICALMATERIetLCRPRIORITYPOLLUTANTBeAVERAGECatCENTRATICNJQPAETYPEJ¹OFANALYSESC~i'AAXIMYWCCtlCENTRATICtlAJYDMASSWITCCDEQIANATYPERAFANALYSESWTCODEWITCODEWIT4XXJESAtPLETYPEJJOFANALYSESWITCODEUNITCODELJ~~~LJWITCODESAtFLETfPE¹OFANALYSESWITCODEWITIX'GEAetIAMEOFCRITICALMATERIALORPRICRllYPOLLUfANT441<!7BAVERAGECaJCENIRATION;SAMPLETYPE;OFANALYSESC~~AXltlf8'CXICENTRATIONAtOMASSAeNAMEOFCRITICALMATERIALORPR(CRITYPOU.UTANT3.AvERAGECaICENIRATICN;SAMPLETYPEJ¹CFANALYSESI~CeMAXlttNCCICENIRATIONAt@IMASSWITCODESAJFLElYPEiP'FANALYSESLJIIVITCODEWITCODELJUeufCODESAMPLETYPE0OFANALYSESLJatlTCODEWlfCODEAetIAMECFCRITICAL,MATERIALORPRICRITYPOLLUTANT~AVEPAGECO'KENTRATIONJSAMPLETYPEJ¹OFANALYSESC~',~AXI"AP.CaticENTRATIONA'ClMASS*Dischargedastotalresidualchlorine.WITCODESAMPLEIYPEOFANALYSESLJWITCCDEWITCODELJ~~~LJ**Basis:ADDITIONALPAGESCFTHISI~7AREATTACIEDFORT)ERESTOFTHECRITICALClYESMtelERIALSAND/CRPRICRITYPCLLUTANTSREQJIREDTOBEREPORTEDeElNO1993actualdatasubmittedonDMRS.AverageconcentrationbasedondatafromMaytoDecember.39 EVS>NO'4<<5r<<)n0<<i~i~3is~i<<:.5-lcn~)isc"arsesc-ecuie,ici.-e.Ic>>ra-8sncaver-rear"ent-=""IT'K.VEERI'iTI'EBDXATTE,CPrFTh(SF"Rs."isi531<<>>C!CVVr<<viou>>lverI<<>>~3<<;(curtail;>ocrlnscaceorovicea'credencaie"'Ior...S.S.CeiIledCuv.i(E<<Eou(T'<NBERCAl(BEFQ.'~DCNTREFRONT?AGECFYODREXPIRINGvv,~"enleave0(snxsnas-4-oer<<Ill08ssslcnea.0Sectionli.=cr!sc)<<civicalaischsrcecin.5separatesercfEnrer-neIccaticnotdlscnsrge.Tn(ssnouicinc)uce.ual'<<BriuditerSBC.icn,Suan,ei'8cIcn.5BC(ion.(own.Sndrange~2.C:srnameotrecelvincwater(ltsurfacewaveraiscnarce)',<a(CatBwnBTner(SCIIi~Vdi5CnaraesCn55BSSndl"OSiS.I!yes.))stalscnargeperiods.E.?rcV)dethelandSOp)ICar(OnrateSuSeaOreXOBCVeaVOOeuSeaInVermSOfinCneSOer(.Our,rOurSperday,SndinCneSperweek.:ndicstethetypeotwastewatertooeaischarqeafrommlscurtail.oeferothewastewdtertyoecodegivenIntheleft.45rgin..4orethanonecoaenayoesoolicdoIB~orcvice-neaveragenunoerothoursoei:avinRienvne'ac)i)Tvaiscnarcestreatedwasvewsversnd-hercralnumoerofcayscervest.n<<nlcnvhealscnarceoccurs.orovldecurrent(franthelastl2ncnrhs)crexoecteaficwratesasrecuesred.ceferrounitcodeaivenInrhelettmarginfcrvnesoorcoristetlcwunirs."GY-ni(l:cnoallcnSOer.gear:'GD-n))l)Cngallonsoerasy;GPO-gallonsoerCsV.RovicetnemaximumclscnslgeflowI'atB<<nlcnvoudnTcnavBsuTnorlzeawithinvheoennit.'x)TEirorNpDEsoernltscnlv,rheuseotsuchsflowrate>>ii)nctplocesnactual)(nitiesrricrlcnonvhetlowbutw)IIbetheiIcwrateusedtocevelocettluentlimits.Also,<<hentneivcnthlyDoerstlngReoortssrereviewedbycompliancestaffitwillhelothemtocetermlneitdnynewOrinCreaseduSesmiqhthaveoCcurredatthefaaility.rovldeThedesignflowforthissoeai!Iccuvfalialsahdrae(e.g.odtcn+rearmenrSySTemflow,packagedtreatmentSyStemflow,orsomeothertinitetreatmentsyStemtlow).ITE42XATERTOEATS'IENTADDITIVES'no)care>>netherdischargeIsresrec>>lvh:cn<<:tlcners,:nnlbircrs~0<<nicrcolcclce.Itnot,continuevoItemS.B.Givename,function,sndchenicdlcompos)tionofadditivesused.Givenamesndaddressofthemanufacturer(s)otvneadditivesused.'<<d)caveBxoecteamin)r~in,sveraaeana-ax)mumciscnsrceccncenvrationsotvheacai.lve(s)forthisalscnsrae..~CiarewneTherVouVt'BdtVhediSCnarieVOr<<moVB"8dialIVB(5)beiot'8CiSCharaeO.Wds~BWarer~.no(catenereovaletticlencvoiedenscaitivetronthe<<ssrewatersna<<>8CischaraetrecuenCVOfeachsdai+Ivetothe5>>rface<<sterorgrcuna<<ster.'IDTEiIvIsmeresocnslbllltvofrheaoolicsnrvosuoplytneproductinformationssreauestedinthisItens.Informationreauesreaoutnor5uooliBdmsvresultlnthesoollcstionbairdreturnedtothBdoolicsnt'foicop(BT)cn,32 'oiGREATLAKESENVIRONMENTALCENTER6i6i941-22'0i530KingAvenueCc(UniDUs.Ct'lo432l2Phonei61~l297.6801Faxi61<)297.8666October12,1993Mr.JohnCarlsonIndianaMichiganPowerCompanyCookNuclearPlantOneCookPlaceBridgman,MI49106
DearJohn:
TOXICITYTESI'EPORTFORSULFURHEXAFLUORIDEGAS(SF6)Wehavecompletedouranalysesofthe48-hour+dgPghgia~and96-hourfatheadminnowilhi~grggpgggstaticrenewal-acutetoxicitytestsperformedwithsulfurhexafluoride(SF6)gasinLakeMichiganwater.TheLakeMichiganwatersamplewascollectedbyIndianaMichiganCompanypersonnelonSeptember28,1993.ThesamplewastransportedovernighttoGreatLakesEnvironmentalCenter(GLEC),andwereceivedthesampleingoodconditiononSeptember29,1993.Theg.~d'ndfatheadminnowtestswereconductedinaccordancewithGLECStandardOperatingProcedures,whicharebasedonproceduresdevelopedbyU.S.EPA(PeltierandWeber,1990,rMTxi'nFrhwM'm,FourthEdition,EPA/600/4-90/027)andASTMiv,E729-88a,1993).TiiTwiItisourunderstandingthattheCookNuclearPlantcurrentlyinjectsSF6intoapproximately690,000gpmofnoncontactcoolingwateratarateof5cfm,whichisequivalenttoarateof54pl/LofSF6gas.ThefatheadminnowacutetoxicitytestwasinitiatedonOctober1,1993,usinganundilutedLakeMichiganwatersamplethatwasinjectedwithsulfurhexafluoridegasatarateof108pl/L(twicetheplant'sinjectionrate).Thegaswasinjectedintoasealedairtightchamberusingagasinjectionsyringe.Afterinjection,thesamplewasshakenandthoroughlymixedforoneminute.Thissamplewasthenusedasthehighesttestconcentration.Areconstitutedlaboratorywater(Hardness=172mg/LCaCO>)wasusedtopreparenominaltestconcentrationsof54,27,14,and7pl/LSF6gas.Twentyfatheadminnows(3daysoldattestinitiation)wereexposedfor96hoursingroupsoften,in250mlglassbeakers,eachcontaining200mloftestsolution(65x60mmofsolutioninthebeakers).Eachdaythetestsolutionswerecarefullyrenewedbysiphoningmostoftheoldsolutionsfromthebeakers;freshlypreparedsolutionswereaddedbacktoeachtestchamberdailyandthenumberofsurvivingfishwasrecorded.TheSF6concentrationsinthetestchamberswerenotmeasuredanalytically.~AppliedWaterQualityandEnvironmentalSciencesQ))AEVIC Mr.JohnCarlsonIndianaMichiganPowerCompanyOctober12,1993The~r~h~ni~acutetoxicitytestwasinitiatedsimultaneouslywiththefatheadminnowtestusingidenticalexposureconcentrations.Ineachg~testconcentrationweexposed20animals((24hoursoldattestinitiation)ingroupsoffivein30mlglassbeakers,eachcontaining25mlsoftestsolution(40x45mmofsolutioninthebeakers).After24hourstheanimalsweretransferredtofreshsolutionsusingawideborepipet,andthenumberofsurvivingordeadanimalswasrecorded.ThereconstitutedwaterusedinQ,~andfatheadminnowtoxicitytestingispreparedaccordingtoEPAmethodsfrMrineAcuTiiffflnFhwrMinQrgg~,FourthEdition,EPA/600/4-90/027).Weuseddechlorinatedreverseosmosis(R/0)treatedmunicipalwaterforthecultureoffatheadminnows,and.BoardmanRiverwater(headwaters)forculturingourQ,~.Deionizedreversewsmosis(R/0)treatedmunicipalwateristhebasewater,towhichreagent-gradesaltsareaddedtoprepareeachbatchofreconstitutedwater.TheresultsoftheQ.~andfatheadminnowtestsindicatethatthesulfurhexafluoridegasinjectedintotheLakeMichiganwatersamplewasnotacutelytoxic.Therewas100percentsurvivaloftheQ.inthe7,14,27,and108pl/LSF6concentrations,and95percentsurvivalinthelaboratorywatercontrolsandthe54pl/LSF6concentration(Table1).Therefore,the48-hourLC~~valuewasgreaterthan108pl/LSF6gas.Thewaterchemistrydatafortheg.~testaresummarizedinTable2.Inthefatheadminnowtesttherewas100percentsurvivalinthe7,54,and108pl/LSF6concentrationsandinthelaboratorywatercontrolsgable3).Therewas95percentsurvivalinthe14and27pl/Ltestconcentrations.Becausetherewaslessthan50percentmortalityinthe108pl/Ltestconcentration,the96-hourLCforfatheadminnowswasalsogreaterthan108pl/LSF6gas.ThewaterchemistrydataforthefatheadminnowtestaresummarizedinTable4.Insummary,neitherQ,~duinorfatheadminnowsurvivalwasaffectedbyanyoftheSF6concentrationswetested,includingthe108pl/L(highesttestconcentration)and54pl/L(presentapplicationofSF6)testconcentrations.CopiesoftherawdatasheetsandstandardreferencetoxicantdatafortheacuteeffluenttoxicitytestsareincludedwiththisreportinAppendicesAandB.Ifyouhaveanyquestionsorcommentsconcerningtheresultsofthesetoxicitytests,pleasecontacteithermeorMickDeGraeveat(616)941-2230.ThankyoufortheopportunitytoprovidethisservicetotheIndianaMichiganPowerCompany.Weappreciateyourbusinessandhopewecanbeoffurtherservicetoyouinthefuture.Iwillbeincontactwithyoutoarrangeforthevisitwehavediscussed.'erely,;,~.,;~-//0~~DennisJ.McCauleyResearchScientistDJM:dmEnclosures TABLE1.RESIILTSOF6ARRM!~CIOAPXR6EUUASTATICREIIEIIALACU'IETOXICITYTESTIIITRSULFURSEXAFLUORIOERASISFAIIRJECIEOIRISASAHPLEOFLAKEIIICHIGANMATER(GLCB1765)RECEIVEDOHSEPTEHBER28,1993,FROHCOOKNUCLEARPLANTNEARBRIDGHAN,HICHIGANUSINGRECONSTITUTEDLABORATORYMATERASDILUTIOHMATER(TESTDATES:OCTOBER1-3,1993)TestConcentration(AI/L)eIce'tSUIYvalEs024hr48hrLaboratoryMaterControl7/Ll/L14HI/L27RI/L54HI/L108pl/L95100100100100951001001009510048-hourLC~valuewasnotcalculable(greaterthan108HI/L). TABLE2.IIAIERCHEIIISTRTUHHIARTFORA48-IIOUR~CEROOAPHUHASTATICREIIEIIALACUTETOXICITTTESTIIITHSULFURHEXAFLUORIOESASISFAIINJECTEDIHTOASAHPLEOFLAKEkICHIGANMATER(GLCB1765)RECEIVEDOHSEPTEHBER28,1993,FROHCOOKNUCLEARPOMERPLANTNEARBRIDGHAN,kICHIGAHUSINGRECONSTITUTEDLABORATORYMATERASDILUTIONMATER(TESTDATES:OCTOBER1-3,1993)TestConcentration(NI/L)keenRangekeenRange0issolved'xygenLTeaperature'CkeenRangeSpecificConductivityoscmkeen~AIAlhIJI8PdIIAA(mg/LCaCOs)(mg/LCaCO>)LaboratoryMaterControl7NI/L8.2(8.1-8.4)8.3(8.2-8.4)8.6(8.0-9.0)8.6(8.0.9.0)24.6(24.1-25.0)24.6(24.1-25.0)53755714pl/L8.3(8.2-8.4)8.6(8.0.9.2)24.6(24.1-25.0)54327NI/L54pi/L8.3(8.3-8.4)8.3(8.2-8.4)8.7(8.0-9.4)8.7(8.0-9.4)24.6(24.1-25.0)24.7(24.2.25.0)511445108AI/L8.2(8.1-8.4)9.0(8.0-9.8)24.8(24.3-25.0)128keasurementsveremadedailyineachtestcharber.AsinglemeasurementHasmadeatthebeginningofthetestonacoapositesaapiebeforedistributiontothetestchacbersandattheendofthetestonaccepositesample.AlkalinityandhardnessmeasurementsveremadeuponpreparationofthereconstitutedlaboratoryMateranduponarrivalatthelaboratoryoftheeffluent.
TABLE3.RESULTSOFA96-HQJRFATHEADHIHHOMSTATICREHEMALACUTETOXICITYTESTMITHSULFURHEXAFLUORIDEGAS(SF6)INJECTEDIHTOASAHPLEOFLAKEIIICHIGANMATER(GLCB1765)RECEIVEDOHSEPTEHBER28,1993,FROHCOOKNUCLEARPOMERPLANTNEARBRIDGHAN,ilICHIGAHUSINGRECONSTITUTEDLABORATORTMATERASDILUTIOHMATER(TESTDATES:OCTOBER1-5,1993)TestConcentration(aI/L)24hreceSuvvalH~048hr72hr96hrLaboratoryMaterControl7HI/L14HI/L27HI/L54HI/L108III/L10010010010010010010010010010010010010095100100100100959510010096-hourLCsovalueuasnotcalculable(greaterthan108HI/L). TABLE4.MATERCHENISTRYSLNB(ARYFORA96-HOURFATHEADHINNOMSTATICRENEMALACUTETOXICITYTESTMl'lHSULFURHEXAFLUORIDEGASINJECTEDINTOALAKENICHIGANMATERSANPLE(GLECN1765)RECEIVEDONSEPTENBER28,1993,FRONCOOKNUCLEARPLANTNEARBRIDGHAN,NICHIGANUSINGRECONSTITUTEDLABORATORYMATERASDILUTIONMAIER(TESTDATES:OCIOBER1-5,1993)TestConcentration(NL/L)OldDissolved'xygenLOLdTeaperature'NeuOLclSpecific'onductivityoscmNeuOLd~kkkIk~rdn(mg/LCaCO>)(mg/LCaCO>)LaboiatolyMaterControl7NL/L1CliL/L27NL/L54lil/L108ltL/L8.2(8.2-e.C)8.1(7.9-e.2)8.3(8.2.8.3)8.2(8.2-8.3)8.1(S.1-8.2)8.1(8.0.8.2)8.1(8.1-8.2)8.0(7.C.8.2)8.38.1(8.2-8.C)(7.9-8.2)8.38.2(8.2-8.3)(8.1.8.2)B.S(8.8.8.9)8.9(8.8-9.0)9.0(9.0.9.2)9.1(8.9.9.4)9.2(9.0-9.4)9.8(9.6-10.2)6.9(6.2-7.5)7.5(7.1-8.0)7.4(6.6-e.o)7.1(6.5-8.0)7.2(6.9-7.6)7.5(7.4-7.6)25.0(25.0.25.0)24.6(24.2-25.1)25.024.6(25.0-25.0)(24.3-25.1)25.024.6(25.0.25.0)(24.0-25.1)25.024.6(25.0-25.0)(24.1-25.2)25.024.6(25.0-25.0)(24.2-.25.3)25.024.6(25.0-25.0)(24.2-25.2)537(494-566)556(537-587)539(531-557)514(502-516)444(4C0.450)311(303-316)539(539-539)547(547-547)531(531.531)502(502-516)438(438-438)304(304-304)104(104-104)106(106-106)172(172-172)128(128-128)Ileasurementsueremadeonneutestsolutionsandoldtestsolutions.Thenurbersrepresentthemeanandrange(inparentheses)ofmeasurementsobservedduringthetest.AlkalinityandhardnessmeasurementsMeremadeuponpreparationofthereconstitutedlaboratoryeateranduponarrivalofthesample. APPENDIXARA~VDATASHEET C'RS~w~a'atSRSRIRlhRl688888888RlklhlRlbbRRf5HRHRlHHHHIWRRSHpHHRRHSHHHHH5WRWRRERSWESRRESRRSISWSRRIRE0~Iay~~e~RHKSKRHRRERRRIRHRRIRQ'5SRHRRfREIRKKIRHRSSSHSHRIHIHSIHHHRRRHWWWRS5ERRSQERQE5$%85$ldl'5$5QRRE 'I'cathlslco~t:)'lsjINu..IcstSIII~klwihlllWjlk.QAILfPEA)2~i-'I-FlSal96-llOURSTA;tJQTypeofTest:0No.Fish/Chantbcr:0No.ofChambers:AgcofFish:CUTETOXlClTYTESTDilutiunWater:GLCand/orBatchNo.:jlTcntpcraturc:c)ncubalor4:2c~"c,O'irj6/(IIauTestDayTech.)nil.TrcsltncnlvclRcplicatcNumber.ControlTcmcraturcDOmiILS.Cond.umhos/cmNo.Live10(0JOICI/0g'0Obsarvausnsj05ossI'i70II).Q~)70gl7d,z'tC'JIDOm'ILTclncralurcNo.LiveDOm/L17VRZZg2lg.QLl.Z00fg'17]g2>.vqn.78-+~f/l~l'll'ryOTcmcralurcNo.LiveObscrvaltonsTcmcralurcNo.LiveObservationsDOmII.S.Cord.umhos/cnt0IOIO2g7./,f'.0T.0rj~7n1lCfaS.C7,IzoC//+rfjvrz>,/~nCK-/0t)hicrvstuu<hcy:DOS-DrieOuluuScsLcrPM-PaniculstcMsucrERR-ErraticSwimminRcvicwcdby:FS-FilmonSurfaceF-Floater)MM-bnmobilc ~. EFFLUENTAi%)RECEIVINGWATERCHECK-INFORMClient:(t"CI-'4'ICI00-4projectNo,:Investigators:INITIALWATERCHEMISTRY(UPONRECEIPT)DateInitialsGLCNo.CollectionDate(timeinterval)Temperaturepa~WATERCHEMISTRYATTESTTEMPERATURESDate:GLCNo.TemperaturepHDissolvedOxygen(mg/L)Conductivity(umhos's/cm)Hardness(mg/L)Alkalinity(mg/L)TotalChlorine(mg/L)*TotalAmmonia(mg/L)*InitialsCcnCtutjcl<zY/7$'~/DQCheckwithprojectmanagertoseeifnecessary
LrekeeEnvirnnrnenkrlCenlerC739ItastingsStreetTrarerseCity,MI49684Phone:(616)941-2239Fax:(616)941-22AOCHANCOFCUSTODYRKCO14B9OBECOMPLETEDON-S)TEANDSUBMITI'EDWm)SAMPLES)Facility:.C~+++'/~~~+./c4.Location;re~~~~ee.'rfc'p&re.AM&ContactPerson:~-~C>r.~~-aPhoneNumber:rea&~~So~Co0ector:DateWitness:Date:-z-.s-'V3rz1ciOSAMPLEID(8-ZggC./q,4nrgDATE/I'IMEOFSAMPLEi.;.-~S/ioVOLUMESAMPLESAMPLECOLLECTEDCOLLECTORCONTAIN)UK.(I--M.c~e~~aDESCRIPTION(Typeofsample,source,physicalcharacteristics)PRESERYATIONANALYSESREQUIREDver>7rrCrTRANSFEROFSAMPLES:(Firstsignatureissampler,lustsilenatureisauthorizedlaboratoryrepresentative.)1.2e5LHXF)L~~iP~r'-zs-g3V7~niifmlln<<iIPtif($~(Airii~) APPENDIXBM)ARDREFERENETXICANTDATA GREATLAKESENVIRONMENTALCENTERSodiumChloride(NaCI)ToxicityData1992"1993grams/Liter3.532.51.50.50APRMAYJUNJULAUGOGTOGTNOVDEGJANFEBMARAPRMAYJUNJULAUGSEPI1992I1993I48-hourLG50~Meanplus2S.D.~Meanplus1S.D.~Meanminus2S.D.Meanminus1S.D.CeriodaphniadubiaSurvival GREATLAKESENVIRONMENTALCENTERSodiumChloride(NaCI)ToxicityData1992-1993grams/Literl2100APRMAYJUNJULAUGOGTOGTNOVDEGJANFEBMARAPRMAYJUNJULAUGSEPI1992I1993I48-hourLG50Meanplus2S.D.~Meanplus1S.D.Meanminus2S.D.Meanminus1S.D.FatheadMinnowSurvival ATTAC~NT4REPORTONTHEWHOLEEFFLUENTTOXICITYTESTFORDETOXIFIEDCLAM-TROLEFFLUENTATDONALDC.COOKNUCLEARPLANTAmericanElectricPowerServiceCorporationandIndianaMichiganPowerCompanyFebruary22,1993
WHOLEEFFLUENTTOXICITYTESTIntroductionTheMichiganDepartmentofNaturalResources(MDNR)issuedalettermodifica-tionfortheDonaldC.CookNuclearPlantapprovingtheuseofthepropri-etarymolluscicideClam-Trol,CT-1(BetzIndustrial).Theletter,datedApril24,1992,fromMr.FredMorleytoMr.DonaldBaker,IndianaMichiganPowerCompany(I&M),allowedtheuseofClam-TroliftheeffluentcontainedClam-Trolconcentrationsequaltoorlessthan0.05mg/1.Sincethedetec-tionlimitforClam-Trolis0.2mg/l,theMDNRrequiredwholeeffluenttoxicity(WET)testingtoassurecompliancewiththestatewaterqualitystandardprovisionprohibitingthedischargeoftoxicmaterialsintoxicamounts.TheMDNRalsorequiredZ&MtosubmitastudyplandescribinghowtheWETtestingwouldbeperformed.Mr.BakersentZ&M'sstudyplantoMr.MorleybyletterdatedJune9,1992.I&M'sstudyplandescribedhowandwheretheeffluentstreamswouldbesampledfromOutfalls001and002,andhowthesampleswouldbeshipped,analyzed,andreportedtotheMDNR.Thisplanalsodescribedhowthedatawouldbeevaluatedandspecifiedtestingtobecon-ductedshouldanysingletestproduceanEC>0lessthan100Keffluent.,ThelettermodificationoftheCookPlantNPDESPermitwasconditionalonthestudyplanbeingapprovedbytheMDNR.MDNRnotifiedZ&MbyletterdatedJuly16,1992thatthestudyplanwasacceptable. TreatmentoftheCookPlantforzebramusselcontrolhasevolvedfromattemptstotreattheentireplantinoneoperationtotreatingcomponentsoftheplantinseparateoperations.Theintaketunnelsaretreatedindividu-ally,thecirculatingwatersystemistreatedasonesystemandcomponentsoftheessentialservicewater(ESW)and'on-essentialservicewater(NESW)systemsaretreatedasneeded.TreatmentProramComletedIn1992ThenorthandcenterintakewatertunnelsweretreatedwithClam-TrolonAugust12and13andSeptember11and12,1992,respectively.Thecircula-tingwatersystemwastreatedonSeptember16withClam-Trol.Watersampleswerecollectedduringeachofthesethreeperiodsasdescribedintheap-provedstudyplan.ThesesamplesofdetoxifiedeffluentweresplitandthenshippedtoacontractlaboratoryandtotheMDNRtoxicitytestinglaboratoryforanalyses.Thecontractlaboratoryconducteda48-houracutetoxicitytestusing~pahniafulexoneachofthethreewatersamples.Atthesametimethedetoxifiedeffluentsampleswerebeinganalyzed,aseriesofben-toniteclaysolutionswerebeingtestedforimpactonthetestorganisms.~Dahniasp.andotherzooplankterscanbeadverselyaffectedbymechanical(ratherthanchemicallytoxic)meanswhenexposedtoexcessiveamountsofsuspendedclay.TheseclayblanktestserieswereconductedusingLakeMichiganwaterandthesameclayusedtodetoxifytheClam-Trol.LakeMichiganwaterusedfordilutionofthedetoxifiedeffluenttestsandtheclayblanktestswascollectedbeforetheClam-Troltreatmentsbegan. ~' Methods0Watersampleswerecollectedfromthedischargetunnelmanwaysusingasubmergedpumpatthebeginningofthetreatment,atthefourthhour,attheeighthhourandatthetwelfthhouroftreatment.SampleswerecollectedfromUnit2dischargemanwayandcompositedinonecontainer.Attheendofthetest,asamplewasremovedfromthecompositedsamplecontainerandshippedtothecontractlaboratory.DuringtreatmentstothenorthandcenterintaketunnelsonAugust12-13andSeptember11-12,1992,therewasnoeffluentfromtheUnit1discharge.tunnel.DuringthecirculatingwatersystemtreatmentonSeptember16,sampleswerecollectedfromboththeUnit1andUnit2dischargetunnelmanwaysandcompositedintoonecontainer,fromwhichthewaterforWETtestingwastaken.Thelaboratoryfollowedtheprocedureforconducting48-hourEC50acutetoxicitytestsaccordingtotheEPAprotocol,"MethodforMeasuringtheAcuteToxicityofEffluenttoFreshwaterandMarineOrganisms,"EPA/600/4-85/013.Adilutionseriesof100X,50X,25X,12.5X,6.25XandOX(control)effluentwassetup.LakeMichiganwaterfilteredtoremovenativezooplanktonwasusedfordilution.Four30mlbeakersweresetupforeachtestconcentra-cionand25uloitestsolutionuasputineachbeakerpive.~DahniaDulexjuveniles(<24hoursold)wereplacedineachbeaker.Temperaturewas.~maintainedat25'+1C.Temperature,DO,andconductivityweremeasuredevery24hours.Theeffectswererecordedevery24hours.Organismsthatfailedtoremaininthewatercolumnforfivesecondsafteragentleprodorswirlingthebeakerwereconsideredeffected.Resultsarereportedasacute48-hourEC5values. Atestseriesofbentoniteclayblankswasconductedthesameasthedetoxi-fiedClam-Troleffluent.t'ilteredLakeMichiganwaterwasmixedwiththesameconcentrationofbentoniteclayusedtodetoxifytheClam-Trol.Thisconcentrationofbentoniteclaywastestedat100X,50X,25X,12.5X,6.25XandOZ(control).ResultsWholeEffluentToxicitytestswereconductedAugust15through17,September13through15,andSeptember17through19,1992.Table1showstheimmobilitypercentagesofthedetoxifiedClam-Troleffluentandthebentoniteclayblanktestconcentrations.ImmobilityresultsexceededtheEC50for100Zeffluentatalldetoxifiedeffluentandclayblanktestconcen-trations.Thehighestimmobilityresultwas30ZforthedetoxifiedClam-Troleffluentsamplesand25Xforthebentoniteclayblanksatthe100Xeffluentconcentration.Onetestserieswastechnicallyinvalidbecausethecontrol(OXeffluent)had>10Ximmobility.ExceptfortheimmobilityobservedatthecontrolconcentrationinthedetoxifiedeffluenttestconductedonSeptember13-15,toxicitywaslowandtheimmobilitiesthatwereobservedfollowedasimilarpatternastheclayblanktestseries.Immobilityper-centagedifferencesbetweenthedetoxifiedClam-Trolandclayblanktestconcentrationswereusually5Zorless.DiscussionThe70XimmobilityvalueobtainedforthecontroltestonSeptemberl.3-15wouldappeartobeananomolousvalue,sincethebentoniteclayblankcontrol e usingLakeMichiganwatersuppliedtothecontractlaboratoryinthesameshipmentshowedOXimmobilityeThreeofthefourcontrolreplicatesshowedallornearlyalltestorganismsvereimmobilizedandinoneofthefourreplicatesnoneoftheorganismswereimmobilizedduringthe48-hourtest.Anexaminationofthelaboratorysheetforthetreatmentconcentrationsshowsthattheorganismsinthereplicateswereimmobilizedinnearlyequalnum-bers,e.g.,the50Xand100Xeffluentreplicateshadoneortwoimmobilizedeorganisms.Noneofthetreatmentreplicatesindividuallyaccountedforalloftheimmobilities,whichwouldindicateacontaminatedreplicate.Theimmobilitieswereequallydistributedamongthereplicates.Thereisnowaterqualityparameterthatvasmeasuredbefore,during,orafterthetoxicitytestthatindicatesaproblemfor~Dahniapulex'swellbeing.Giventhegenerallackofimmobilizationresponseoforganismsinthedif-ferenttreatmentconcentrationstestedonanygivendateandthesimilarityoftestresultsfromonetestdatetothenest,therevaslittledifferencebetweenthedetoxifiedClam-Troleffluentandthebentoniteclayblankseffectsonthetestorganisms.Alltestswereincompliancewiththere-quirementthatthe48-hourECfor~pahniaexceed100Zeffluent.inothervordsthetestsshovedthateffluenttoxicityvaslessthanthetoxicityneededtoproduceanEC>0in100Xeffluent.ThelackoftoxicityindicatesthedetoxifiedeffluenthadlittleimpactontheLakeMichiganaquaticcommunity.
TABLE1~Dahniapulex48-hourPereenrImmoblllryValuesObtainedfromWholeEffluentToxicityTestsConductedwithDetoxifiedClam-TrolinLakeMichiganWaterandBentoniteClayBlankTestRuninLakeMichiganWater(clayblankimmobilitypercentagesinparentheses)TestDateControl(OX)6.25X12.5X252502l002Aug15-17OX(OX)OX(OZ)OX(10X)15X(OX)OX25X(10X)(5X)Sep13-1570Z(OX)OX(5X)15X(10X)20X(25X)30X(20X)30X(25X)Sep17-19OX(5Z)OZ(5Z)10X(5X)10X(5X)5X(OX)15X(5X) ANALYTXCALREPORTCookNuclearProj:WasteWaterAnalysisSubm:Jan26SamplesSubmittalNumber:29609-3Location:Contact:RayV.BuhlPhone:(616)942-9600Outfall001Outfall002Circ.IntakeDetectionUnitsLimitWWESSampleNo:7837178372'8373BOD,(5-Day)Sampledby:DateSampled:TimeSampled:DateReceived:TimeReceived:(1.001/26/94000001/27/9413:30(1.001/26/94000001/27/9413:30(1.001/26/94000001/27/9413:301.0mg/1.)')).)(II<'11N'<l<)dllllisIarkKvalSI'I'()l3<)'><874.(IraadRapids.Ill49588-0874.6I6/942-<J600I'0%9-!2-li~! llllInV>Ctrl>F-Snl'ru'eiillllllllli(.)IIII/AlloSTATEMENTOFDATAQUALIFICATIONSCLIENT:CookNuclearSUBMITTAL:29609-3AllanalyseshavebeenvalidatedandcomplywithourQualityControlProgram.Noqualificationsrequired.ThefollowinganalyseshavebeenqualiTiedforthereasonscited.KEYl.2.3.4,5.6.7.8.9.10.Sampleintegritysuspectuponreceipt(explain).AnalysisperformedbeyondEPAestablishedmaximumallowableholdingtime.Detectionlimitelevatedduetomatrixinterferences.Laboratorycontrolsamplevalueoutsideestablishedacceptablelimits.Matrixspikesamplevalueoutsideestablishedacceptablelimits.Duplicateanalysisvalueoutsideestablishedacceptablelimits.Surrogate/internalstandardrecoveriesoutsideestablishedacceptablelimits.Datapointsuspectduetopotentiallaboratorycontamination(explain).Coeluteswiththecompoundcited.Resultmayrepresentacombinationofbothcompounds.Other(explain).NolerThisdocumentisincludedaspartoftheAnalyticalReportfortheabovereferencedandshouldberetainedasapermanentrecordthereof.5555GlenwoodIllllsParkwaySt',.t'0Box874.()randRapids.Atl49588-08?4.6l6/942-9600t'nx9t'-'-6.l99
lt'11'n<~ul((I'uI~~8-'(7('ll('('.~nlnnn(<ann+.in'I.l'I'(:XI,5I:.I'I(.':..ANALYTICALREPORTCookNuclearProj:WasteWaterAnalysisSubm:JanuarySamplesSubmittalNumber:29609-4Location:Contact:RayV.BuhlPhone:(616)942-9600OutfallOutfall001-Circ002-CircWaterDschWaterDschCircWaterDetectionUnitsIntakeLimitWWESSampleNo:785327853378534.Surfactants,-.NBASColiform,FecalColor(Apparent)Sampledby:DateSampled:TimeSampled:DateReceived:TimeReceived:<0.0252<5V.Shah01/26/94000001/28/940000.<0.025<1<5V.Shah01/26/94'0'0001/28/940000<0.0254<5V.Shah01/28/9400000.02515mg/1cl/100mlepH5555(Ilenn'()n(lIiillsPurkwaySE.POBox874.(IrdndRnPids.All49588-0874.6I6/942-9600I';>xllI2-(i.l9I
1V1VI:rg>mar<<~>&Sne<<cei.v>>>>1>N(4>>>>p>j>lSTATEMENTOFDATAQUALIFICATIONSA5AI,Y'I'(:,KI,8l'.RtI(:f'CLIENT:CookNuclearSUBMITTAL:29if09<AllanalyseshavebeenvalidatedandcomplywithourQualityControlProgram.Noqualificationsrequired.ThefollowinganalyseshavebeenqualiTiedforthereasonscited.SampleNo.(s):Explanation:Reason:~KEYl.2.3.4.5.6.7.8.9.10.Sampleintegritysuspectuponreceipt(explain).AnalysisperformedbeyondEPAestablishedmaximumallowableholdingtime.Detectionlimitelevatedduetomatrixinterferences.Laboratorycontrolsamplevalueoutsideestablishedacceptablelimits.Matrixspikesamplevalueoutsideestablishedacceptablelimits.Duplicateanalysisvalueoutsideestablishedacceptablelimits.Surrogate/internalstandardrecoveriesoutsideestablishedacceptablelimits.Datapointsuspectduetopotentiallaboratorycontamination(explain).Coeluteswiththecompoundcited.Resultmayrepresentacombinationofbothcompounds.Other(explain).Note:ThisdocumentisincludedaspartoftheAnalyticalReportfortheabovereferencedandshouldberetainedasapermanentrecordthereof.5555(ileum>odltIllsParkwaySt,".POBox874.(irandRapids.Itl49588-0874~616/942-9600Vas9-t2>-tijou
LockheedAnalyticalServicesDATAQUALIFIERSFORINORGANICANALYSES(Revised08/28/92JBDEHMNUX,Y,orZalbiForUseontheAnalyticalDataReportingFormsForCLPAnalysesOnly-Reportedvalueislessthanthecontractrequireddetectionlimit(CRDL)butgreaterthanorequaltotheinstrumentdetectionlimit(iDL).ForRoutine,Non-CLPAnalysesOnly-Anyconstituentthatwasalsodetectedintheassociatedblankwhoseconcentrationwasgreaterthanthereportingdetectionlimit(RDL).PresenceofhighlevelsofinterferingconstituentsrequireddilutionofsamplewhichincreasedtheRDLbythedilutionfactor.Estimatedvalueduetopresenceofinterference.Sampleanalysisperformedoutsideofmethod-orclient-specifiedmaximumholdingtimerequirement.ForCLPAnalysesOnly-Duplicateinjectionprecisioncriterionwasnotmet.Matrixspikerecoveryexceededacceptancelimits.Reportedvaluewasdeterminedfromthemethodofstandardaddition.ForCLPReportingOnly-Constituentwasanalyzedforbutnotdetected(samplequantitationmustbecorrectedfordilutionandpercentmoisture).ForAASOnly-Post-digestionspikeforFurnaceAASdidnotmeetacceptancecriteriaandsampleabsorbanceislessthan50%ofspikeabsorbance.Analystdefinedqualifier.Relativepercentdifference(RPD)forduplicateanalysisexceededacceptancelimits.Correlationcoefficient(r)fortheMSAislessthan0.995.'-..ForUseontheQCDataReportingForms'hespikerecoveryand/orRPDformatrixspikeandmatrixspikeduplicatescannotbeevaluatedduetoinsufficientspikinglevelcomparedtotheelevatedsampleanalyteconcentration.TheRPDcannotbecomputedbecausethesampleand/orduplicateconcentrationwasbelowtheRDL.'sedasfootnotedesignationsontheQCsummaryform. LockheedAnalyticalServicesDATAQVALIFIERSFORORGANICANALYSESfgÃvkaf:;:"Og/X98$94JForUseOnTheAnalyticalDataReportingFormsABHNUX,Y,orZN/A(%Moisture)ForCLPanalysesOnly-TheTICisasuspectedaldol-condensationproduct.Anyconstituentthatwasalsodetectedintheassociatedblankwhoseconcentrationwasgreaterthanthepracticalorreportingdetectionlimit(PQLorRDL).ConstituentconfirmedbyGC/MSanalysis.Ipesticide/PCBanalysesonlyJConstituentdetectedinthedilutedsample.Italsoindicatesthatanaccuratequantitationisnotpossibleduetog~rggg~beingdilutedoutofthesamplesduringthecourseoftheanalysis.Constituentconcentrationexceededthecalibrationrange.Thequantitationisnotgasolineordieselbutbelievedtobesomeothercombinationofhydrocarbons.Sampleanalysisperformedoutsideofmethod-orclient-specifiedmaximumholdingtimerequirement.Estimatedvalue-(1)constituentdetectedatalevellessthantheRDLorPQLandgreaterthanorequaltotheMDL;(2)estimatedconcentrationforTICs(ForCLPReportingOnly).ForCLPReportingOnly-TentativelyidentifiedconstituentsPICs)identifiedbasedonmassspectrallibrarysearch.ForCLPReportingOnly-ThepercentdifferencebetweentheconcentrationsdetectedonbothGCcolumnswasgreaterthan25percent/pesticide/PCBanalysesonlyJ.ForCLPReportingOnly-Constituentwasanalyzedforbutnotdetected(samplequantitationmustbecorrectedfordilutionandpercentmoisture).Analyst-definedqualifier.N/Ainthe%moisturecellindicatesthatdataarereportedonan"asreceived"basis.Avalueinthe%moisturecellindicatesthatdataarereportedbasedona"dryweight"basis.Fornon-CLPwort,RDLsarenotadjustedfor%moistureevenwhendataarereportedona"dryweight"basis.al...;:.:=:,-For;UseOnTheQCDataReportingFormsQCdata(i.e.,percentrecoverydataformatrixspike,matrixspikeduplicate,laboratorycontrolstandard,orsurrogates;andRPDformatrixspikeduplicateorunspikedduplicate)exceededacceptancelimits.Thespikerecoveryand/orRPDformatrixspikeandmatrixspikeduplicatescannotbeevaluatedduetoinsufficientspikinglevelcomparedtotheelevatedsampleanalyteconcentration.TheRPDcannotbecomputedbecausethesampleand/orduplicateconcentrationwasbelowtheRDL.'sedasfootnotedesignationsontheQCSummaryForm. LockheedAnalyticalServicesDATAQUALIFIERSFORRADIOCHEMICALANALYSES/Revised08/28/92JBHalbiForUseontheAnalyticalDataReportingFormsAnyconstituentthatwasalsodetectedintheassociatedblankwhoseconcentrationwasgreaterthanthereportingdetectionlimit(RDL)and/orminimumdetectableactivity(MDA),PresenceofhighTDSinsamplerequiredreductionofsamplesizewhichincreasedtheMDA.Constituentdetectedinthedilutedsample.Constituentconcentrationexceededthecalibrationorattenuationcurverange.ForAlphaSpectrometryOnly-FWHMexceededacceptancelimits.Sampleanalysisperformedoutsideofmethod-specifiedmaximumholdingtimerequirement.Chemicalyieldexceededacceptancelimits.';.-':ForUseon'theQC'DataReportingForIns',"...',"',',"','Cdata(i.e.,percentrecoverydataforlaboratorycontrolstandardandmatrixspike;andRPDforreplicateanalyses)exceededacceptancelimits.Thespikerecoveryand/orRPDformatrixspikeandduplicatescannotbeevaluatedduetoinsufficientspikinglevelcomparedtotheelevatedsampleanalyteconcentration.TheRPDcannotbecomputedbecausethesampleand/orduplicateconcentrationwasbelowtheMDA.'sedasfootnotedesignationsontheQCsummaryform. GENERALCHEMlSTRYRESULTSClientSamleID:OUTFALL001DateCollected:01-24-94Matrix:waterLALBatchID(s):126imDateReceived:01-26-94PO469095-040-3NConstituentMethodResultReportingDetectionUmltDataQualiflarls)DateAnalzadLALSamlaIDFluoride,inmILBromide,inmILNitrite-Nitrate-Nitrogen,inmIL340.2<0.15353.20.35300.0'0.0500.150.0500.05003-02-94L1131-801-28-94L1131-1602-11-94L1131-21Sulfate,inmILTotalCanide,inmILTotalPhenolics,inmILSulfide,inmIL300.0335.2420.1376.122<0.020<0.15<1.00.0590.0200.151.001-27-94L1131-1601-27-94L1131-2502-08-94L1131-3001-27-94L1131-11Comments: GENERALCHEMISTRYRESULTSClientSampleID:OUTFALL001CIRCWATERLALBatchID(s):126im,127imDateCollected:01-26-94DateReceived:01-27-94Matrix:whterP0469095-040-3NConstituentTotalPhosphorus,inm/LAmmoniaNitrogen,inmILTotalSuspendedSolids,inmILTotalOrganicCarbon,inmILChemicalOxygenDemand,inmILTotalKjeldahlNitrogen,inm/LMethod365.2350.1160.2415.2410.2351.2Result(0.030<0.050(121.8(180.20ReportingDetectionUmlt0.0300.050121.0180.10DetoOuellflerls)DateAnaled02-08-9402-01-9402-02-9402-16-9401-28-9403-03-94LALSemleIDL1142-5L1142-5L1142-9L1142-1L1142-1Ll142-5Comments: GENERALCHEIVllSTRYRESULTSClientSamleID:OUTFALL001DateCollected:01-27-94Matrix:waterLALBatchID(s):128imDateReceived:01-28-94PO469095-040-3NConstituentMethodResultReportingDetectionUmltDataQualifie(s)DateAnaledLALSamleIDColorSulfite,inrng/L110.3377.1<5.0<1.05.01.001-28-94L1151-101-29-94L1151-1Comments:CQC METALSRESULTSClientSamleID:OUTFALL001LALBatchID(s):126imDateCollected:01-24-94DateReceived:01-26-94Matrix:waterPOI)'69095-040-3NConstituenteMethodConcentration(mIL)ReportingDetectionumitlmlL)DateQualifier)a)DateAnalzedLALSamleIDAluminumAntimonArsenicBariumBerIliumBoronCadmiumChromiumCobaltCoerIronLeadManesiumMananeseMercurMolbdenumNickelPhoshorusSeleniumSilverStrontiumThalliumTinTitaniumUraniumVanadiumZinc601060107060601060106010601060106010601060107421601060107470601060106010774060106010784160106010602060106010<0.20<0.060<0.010<0.20<0.005<0.20<0.005<0.010<0.050<0.025<0.10<0.00312<0.015<0.0002<0.067<0.040<0.050<0.005<0.0100.13<0.010<0.20<0.10<0.001<0.050<0.0200.200.0600.0100.200.0050.200.0050.0100.0500.0250.100.0035.00.0150.00020.0670.0400.0500.0050.0100.100.0100.200.100.0010.0500.02002-22-94L1131-9402-22-94L1131-9402-20-94L1131-9402-22-94L1131-9402-22-94L1131-9402-22-94L1131-9402-22-94L1131-9402-22-94L1131-9402-22-94L1131-9402-22-94L1131-9402-22-94L1131-9402-23-94L1131-9402-22-94L1131-9402-22-94L1131-9402-09-94L1131-9402-22-94L1131-9402-22-94L1131-9402-22-94L1131-9402-25-94L1131-9402-22-94L1131-9402-22-94L1131-9402-28-94L1131-9402-22-94L1131-9402-22-94L1131-9403-07-94L1131-9402-22-94L1131-9402-22-94L1131-94Comments: VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260Page1of2ClienSmIID:TFALL01DeClleced:24-AN-4Matrix:WATERAnalticalBatch¹:020394-8260-J-2QCBatchID:020394-8260LALSmIID:L111-41Dae.Receive:2-JAN-4DateAnalzed:03-FEB-94DilutionFactor:1SURROATERECOVERYoQCLimits12-Dichloroethane-d4Tolene-d4-Bromofluorobenzene989776-11486-115ContieChloromethaneVinIChlorideBrmmhnhirhnTrichlorofluoromethaneAcetone11-DihlrhnrnDiIfiMethleneChloridetrans-12-DichloroeheneVinIA11-Dihlrhn2-Butanonecis-12-Dichloroehenehlrfrm111-TrihirhnCarbonTetrachloride12-DichloroethaneBnznTrih12-DichlororoneBromodichloromehnehlrhIVinIhr4-Mhl--ncis-13-DichlororoeneToluenern-1-Dihlrrn-Hxnn112-TrichloroethaneTetrachloroethenePCEConcentrationL<5<5<5<10<5<5<10<5<5<5<5<5<2<5<5<5<5ReportingDetectionLimitL1010DeQ'ifier14LLOCKHEEDAIVALYTICALSERVICES
VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGIVIETHOD8260ClientSamleID:OUTFALL01LALSamleID:L1131-41Page2of2ConstituentDibromochloromethanehlrnnhInnm-Xleneo-XleneConcentrationIL<5<5<5ReportingDetectionLimitILDataQualifiersSrmfrm1122-Tetrachloroethane13-Dichlorobenzene14-Dihlrnzn12-Dichlorobenzene<5<5<5LOCKHEEDAhfALYTICALSERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260TENTATIVELYIDENTIFIEDCOMPOUNDSClientSampleID:OUTFALL001DateReceived:264AN-94Matrix:WATERAnalyticalBatch:020394-82604-2LALSampleID:L1131%1DateAnalyzed:03-FEB-94DilutionFactor:1QCBatchID:020394-8260TentativelyIdentifiedCompoundNOCOMPOUNDSIDENTIFIEDEstimatedConcentrationIyg/L)RetentionTimelminutes)DataQualifier(s)LOCKHEEDAIVALYTICALSERVICES SEIVIIVOLATILEORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270Pae1of2ClienSmIID:OUTFALL001DateCollected:24-JAN-94Matrix:WATERAnliIBh4':24-7-AQCBatchID:8270-SEMIVOLATILE4825LALSamIID:L1131-55DateReceived:26-JAN-94DilutionFactor:1DaExr:1-JAN-4DateAnalzed:03-FEB-94SURROATEREOVERYY2-FluorohanoiPhenol-d,Nitrobenzene-d,2-FluorobihenI24-TrirmohnIp-Terphenyl-d2722645748370Limi21-10010-9435-11443-11633-141Phenoln'ConcentrationL<10ReportingDetectionLimit10Delifisbis2-ChloroehIetherhlrhnl1-Dihlrnzn14-DichlorobenzeneBenzIalcohol1-Dihlrn-MhIhnIbis2-ChloroisoroIeher4-MehIhenolN-Nir-Di-n-rIinHxhlrhnNitrobenzeneIsohorone-NirhnI4-DimBenzoicacidbis2-Chloroethoxmehane4-DihirhnI14-TrihlrnnNahhalene4-ChloroanilineHhlrin4-hlr--mhlhnl2-MethInahhaleneHexachloroccloentadiene<10<10<10<10<10<10<10<50<10<10<10<10<10'0101010101010501010101010LOCKHEEDANALYTICALSERVICES SEMIVOLATILEORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270ClientSamleID:OUTFALL.001LALSamleID:L1131-55Pae2of2Constituent24-TrihlrhnI4-TrihlrhnI2-Chloronahthalene2-NitroanilineDimhIhhIAnhhin26-Dinitrotoluene3-NitroanilineAnhhn4-DinirhnI4-NitrohenolDibenzofuran'4-DinirInihlhhl4-ChlorohenI-henleherFluorene4-Nirnilin4-Dinir--mIhnIN-Nitrosodihenlamine4-BromohenI-henleherHxhlrnznPnhlrhnlPhenanthreneAnhracenerIDi-n-IhhIFluoranhenePrene8InIhhI'-DihrBenzoaanhracnChrsenei-hlhxDi-n-IhhIBenzobfluorantheneBenzokfluorantheneBnzrnConcentrationIIL)<10<25<10<25<25<10<10<10<10<10<10<10<10<10<10<10<10<10ReportingDetectionLimitIIL)102510252510101010101010101010101010DataQualifierls)Inn1rnDibenzahanthraceneBenzolhi)erlene<10<101010LOCKHEEDANALYTICALSERVICES
SEMI-VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8270TENTATIVELYIDENTIFIEDCOMPOUNDSClientSampleID:OUTFALL001DateReceived:264AN-94Matrix:WATERAnalyticalBatch:020394-8270-ALALSampleID:L1131-55DateAnalyzed:03-FEB-94DilutionFactor:1QCBatchID:8270SEMIVOLATILE4825TentativelyIdentifiedCompoundNOCOMPOUNDSDETECTEDEstimatedConcentration(yg/L)RetentionTime(minutes)DataQualifierls)LOCKHEEDAIVALVTICALSERVICES
OILANDGREASEEXTRACTABLESANAIYSISRESULTSBYFT/IRUSINGMETHOD413.2ClientSamleID:OUTFALL001DateCollected:24-JAN-94DRiv:2-AN-4MrixWAnalticalBatch¹:020494-413.2LALSamleID:L1131-75DateAnalzed:07-FEB-94DilinFr1Dr-FB-4QCBatchID:020294-413.2ConstituentOilandGreaseConcentrationmLReportingDetectionLimitDataQualifier(s)LOCKHEEDANALYTICALSERVICES PESTICIDEANALYSESRESULTSBYGC/ECDUSINGMETHOD8080linSmIID:TFALL-01Doil:4-AN-4DateExtracted:31-JAN-94Matrix:WATERAnalyticalBatch¹:013194-.8080-E-4LALmIID:L111-DeReeiv:2-AN-94DateAnalzed:01-FEB-94DilutionFactor:1QCGroupID:8080PEST/PCBS4822SRROATERECVERYTCMXDCB5039QCLimits60-15060-150ConstituentConcentrationReportingDetectionLimitDataQualifier(s)A-BHB-BHCG-BHCD-BHHPTAHLRALDRINHEPTACHLOREPOXIDEHLRDANEENDFANIA-CHLORDANE44'-DDE44'-DDTDILDRINENDRINENDOSULFANII4'-DDDNDRIADHYDENDOSULFANSULFATEMETHOXYCHLORTXAPHNEP-11PCB-1221PCB-1232PB-142PB-14PCB-1254PCB-1260TECHNICALCHLORDANE<0.05<0.05<0.05<0.05<0.05<0.1<0.1<0.1<0.1<0.5<20.050.050.050.050.050.10.10.10.10.514.LOCKHEEDANALYl'ICALSERVICES RAOOATAREPORT(ra01)IndianaHichiganPomrCo.eBridgman,NIOrganicandInorganicContaeinanta(ProjectC(XX.JENI)ClientSangriaIO:OITFALL001LALSanplaIO:L1131.b5HatrixtllaterOateCollected:24.JAN.94OateReceived!26.JANE94LoginNuaber:L113'I8%3FCo()aklttientg""44Mi@KN~>w"~Anal)Iaed:"'SetcIT~<-~5~~i'""Qi'F:."'<~)'..'".""."ActiVf>Q',5.'rotg~gj'N@:-:.~~i>Oatmeal':::~lUnita;.".,'.GrossAlphaGrosaBeta23-FEB94GRALP/BETALAL~0060475623.FEB.94GRALP/BETALAL.006047560.43.21.11.522.2pCi/LpCi/LPage6 RADDATAREPOP.T(ra01)lndfanalffchfganP~rCo.~Brfdgman,NIOrganfcandlnorganfcContaninanta(ProjectCNX.JEkf)lfatrfx:RaterCIfentSarpfelOsOUTFALL00'IDateCollected:24.JAk.94LALSaepfeID:L1131-89OctaRecefvedt26.JAk.94LogfnktnhertL'l13'IRa-226Ra-22822-FEB-94RA226LAL-0073477123-FEB.94RA228LAL-007455030.0201102230.440.59pCI/LpCI/LPage10 PHMeterCPC/PlOL-CaldatedueSampleTimeSamplegSampleDateCDMEnteredbyPHAnalysis(LAB.079)Outfall0010po~K=5.3.56)SampleC/ph(priortocorrection)7)NH3pHcorrection.9EgO2.7e75.3.68))ampleresultsC/pH(after'7.7PNHCorrection)3SampleSampleTimeSample$jSampleDateCDMEnteredby5.3.56)SampleC/ph(priortocorrection)7)NH3pHcorrection5.3.68)Sampleresults'C/pH(afterCorrection)9)LAB.041SpecsVerifiedby:h/IRSupervisorReview/Date~W+l&Formpreparedby/DateFormapprovedby/Date12THPLAB.041.25sRevision1 Outfall001DeterminationofTotal(Lab170)ChlorineInstrumentCPG(j50~StandardICN-CIDj(2-5I~TechnicianSample/StandardSamplegDateTimeCDMEnteredby3D1)Absorbance6.112)Results,ppmC.w3}Dilutionsmade4)Results,ppm((I2*83)5)1AB.041SpecsVerifiedby:~)9SupervisorReview/Dote~MRtFormpreparedby/DateFormapprovedby/Date12THPLAB.041-25]lRevision0 SEEINSTRUCTIONSONREYERSESIDESECTIONIINUMBERPERMIT~NZ0005827A~LCCATIQIOFDlSCHARGE~002~SWe,~Wi,we-(TIWIe~06,iiNS~0,6STJIISE~l9WDISCHARGELOCATIONSCHEDULEDeIFYESeI.ISTDISCHARGEPERIODSNAB.WCFRECK!vltOWATERi!E.'RcuWATERCRNAECSLRFACENC.OOYOUDISCHARGESEASQtTALLYY(IFNQeCcttt!tATETOE)e'Oe/%YYESLiAKiEi4TZCiHTZGANeOe/DAYFLOWRATEWASTEWATER~TY~DCONTACTCOOLINGNONCONTACTCOOLINGPROCESSSANITARYSTORMWATER~NITc001MGY2MGD3GPDITEM2WATERTREATMENTADDITIVESEeLS/iDAPPLICATIONRATEF>>TYPEOFWASTEWATERDISCHARGEGeDISOIARGESCHEDULE(YEARLYAVERAGE)INe/tR.WRe/DAYINe/WKe~~LJLLJ~LJ~~~EINWASTEIIATERIYPECOCEL~JIOISIS/DAY~24eeevzweeHeDISCHARGEFIDHRATETOTALYEARLYDAILYMINItTPIIXTILYMAXIPAMpp!NIT~CODE0~21820~2e"AXISDES!BIDISCHSRGEFLDIRATE~AeCOYOUUSEHATERTREATIENTACDITIVESTOTREATYTXRDISCHARGE?(IFte,CONT!tAETOITBI3)8~NAtEFutct!CN,ANDc!EHICALCOMPOSITIONCFTHESEAlXIITIVESewIEQXIEDESIGN1820NACert/MEANDADCRESSOFMAIAFACTIRERSOFTIESEACOITIVESeI~,HEMAXIMKADISCHARGEFIDttRATETOBEAUIHCRIZEDINPE%IT.18202UNITSCODE1Mg/I2Ug/INAD.EXPECTEDDISCHARGECctCENIRATIONCFAIDIT!YES.NAADDITIVENAtEMININDIUNITSAVERAGECODEIttITSMAXltSPICODEAcolTIYENSr%ADDITIVENAtEE,DOYmtTREATTIEDISOURCTE10RBQVEACOITIVES?'NAF.wHITISTHERBQVALEFFICIENCYANDDISCHARGEFREILKNCY.NAADDITIVENAIEADDITIVENAMEADDITIVKNAtEQYESKRBOVALLJ/~LJHRS/DAYDAYS/W.LJG~ASANAITACttENTTOIHI5APPLICATICNPROVIDESPECIFICMA!tVTLIANCRAOUSeTICTOXICOUIGICALDATACRREFKRBICEWHICHAREAVAIIABIEANDINFOBQTICNONTHERATEOFDEGRADATIONOFTIEPROIXCTSFOREACHA!OITIVKeNA 30 SEEINSTRUCTIONSONREVERSESIDESECTIONIIPERMIT~Mypppg827AIII'ALLtUKRA~%4KOFPROCESSCCttlRIBUTINGTOTHEDISCHARGE/ROUGHTHISOUTFALL<<8SICCCCEB~PROCESSSCHEDULE(YEARLYAVERAGE)tOLRS/DAY~24I~OI~2WTR49II~/vPROCESSSTREAMSCONTRIBUTINGTOOUTFALLDISCHARGEIhIhIAICt~0C.PROCESSWASTEWATERFLCWRATEBasis:1993actualdatasubmittedOnDMRSD.PROCESSPRODUCTIONRATEAvAX<<"EGFPROCFSSCCttmIBUTltIGTOTHEDISCHARGETHROUGHTHISOUTFALLAIIDSICCA/DENATOTALYEARLYDAILYMINIMADAILYMAXIP%B48,0844~5u61743~61POUNDS2GALLONS3CUBICYARDS4TONS5MGY6MGD7GPDTIME1HOUR2DAY3WEEK4MONTH5YEARIhIh00I0C',0B.PROCESSSCIEDULE(YE/UILYAVERAGE)CAPROCESSWASTEWATERFLOWRATE'.PROCESSPRODUCTIONRATEAIIAtEOFPROCESSCONTRIBUTItIGTOTHEDISCHARGEIHIOUGHTHISOUIFALLAtiDSICCODEBAPROCESSSQELX1Z(YEARLYAVERAGE)C.PROCESSWASTEWATERFlOWRATED.PROCESSPRODUCTIONRATEA.NA%OFPROCESSCONTRIBUTIttSTOTIEDISCHARGENATHANDSICCODEB.PROCESSSCHXILE(YEARLYAvERAGE)CvPROCESSWASTEWATERFLOWRATEDvPROCESSPRODUCTIONRATEAANAtEOFPROCESSCONTRIBUTINGTOIIEDISOIARGE,THOROUGHTHISOUTFALLAND-SICCODEB~PRXESSSCHEDILE(YEARLYAVERAGE)CvPROCESSWASTEWATERFU)/tRATED.PROCESSPRODUCTIONRATEAVYAVY/OAY~DAYY/VYAATOI'ALYEARI.YDAILYMINltRHDAlLYM4XItulTOTALYEARLYDAILYMINIMMDAII.YMAXI'vvAVY/AAV~AAVY/VYAATOTALYEARLYDAILYMININNDAILY."AXINJ4AAVY/VVAATOTALYEARI.YDAII.YMINIONDAILYMAX!ANUNITS/TIMEINITCODEWITS/TIPEUNIT~UNITS/TIVE33
<<$<<<<3~3~1<<<<J~I3$<<rn,SCal83OC(8~I8JWra8aC<<ater<<3,8<<'5ahJI-'=,=:=<<I:='.=".>>==SoulT'.'"=RAh":=C:bh0"E;R"!JtoAGE7YCIIREXPIC't'rl3<<*8Si8J8<<<<3ItVen.SaveIaf<<<<\<<~<<~5$)cA<<w<<x<<555COVi<<OCi8<<13CBSecIcnI'.=cr<<ac-:"<<Iv'a<c:scharceCcint3Secarate3~3c'1<<'~'~IS~38353,~"Iuce".'r.et'varOrSecCtJ.'atet'8C,io1,38CC~Cn.(Own,andrange~JsT<<.8ece"vi.g<<8elIifsulI)ce<<atefo:sc,al<<8).'1CicaTO<<hetter'3ci.Tvcischarces",",358351albasis.(fyes,iIStCIscnarcecarleds.-rovlCe-"e331COCR)IcationrateScseecrOxbectedtobeusedInterrSCt'nCneSCer"our,~curSCerdav,andIncresper<<eex.Indicate-ne<<vceofwastewaT8Iobeisc..reedfrcnthiscutfall.nefectothewastewatertvaececaoivenIntneleft-atgln.VOre-CanOneCOCemayOeaabliCable.3":vice--eOverseenvnbercf"ours.Ot:av:r<<nic.8xclli~v3cnat'$~ea<<c<<asOwater38Tainumberofdayser,ear<<t,<<<<StO3"OVICOC.rtant:frcnthe185tI"nontnS)CrOXOeo,eo3ICWrateS85reoueSTed.RefertOunitCedeOiVenIntheleftmarginFOrThe3cbroariateflowunits.'4Y-millionca)lot5derveer:'40-milliongatlonsDerCay;N)-gallonSOerday.o-ovlce-te-axi"umcisc1argeftowratewnlchvouant31waveauthorIted'<<itl'In18bernlt.'J0T~:mor'JnoEsbermitsonlv,"eusefSuch3flowrate<<illnctblacoanactualJlnltrestrictionontheflewutwillbetneflawrateusedtodevelooeffluentIin(ts.3)so,<<nentneIvcnthiyCberatingRebortsarereviewedbvconoltancestaffItwillhelothamtodetermineifanyneworincreasecusesmlohthaveoocurreoatthefacility,.!.nrov)det"edesign'Io>>forthissoeciflcoutfalldiscnarceIe.g.batch<<reatnentsvstemflow,cackaoedtreatmentsystemflew,orsoretnerfinitetreatmentsystemflow).TIATSRTREAT'IS'lTPDOITIVES'ncicate<<netherclscharceIstreatec<<a'tnonc)tloners,inn)bitors~orm)crob)deice.tInoT,continuetoitem3.:ivename,,;nCticn,andChemicalCcncOSitionOfaddltlues<<Sed..)Je13J83ncNcress1'8nanufac3o\5)oftheadditivnsused."c)cateJ<<cec<<ecn)nimun,averaoe81<<."Sxi-umdiscnarceccncent<<atlonsof318adoitlveis)'cr-1ls:Ischarce.-c'Ira-8-<<<<er.Cu-<<3--"8$'.Sc~!rce".-~ve-"8Scc-)veis):o',creclscrarceo'stewater.'"dicate"8removal8'ftc:Oncv.<<achacditivefrcn.heastewaterandthedischaroefrocuencvofeachaddit>>Jetothe3'rtaoe<<3,8<<'-'I-8resocnsibilivc'.-TeaecJtcantTosuoolvthearocuct'.nfottta!IonasrecuestedInthisItem4.Informationrdues>>cbct-otSvbbliec~avresultl1t"8aboIlcat)81bel"or<<Tur18cto~heaoolicant'orcomoiet)cn.32 SEEINSTRUCTIONSONREVERSESIDESECTIONIIPERMIT~Mt0005827NUMBERGROUNDWATERDISCHARGEINFORMATION%IF%.IlÃBA.ISISEDISCHUIGEFRCMTHISCUTFALLDIREC1EDTOBIEGRQNsDGRGRQU7CWATERS?(tFtO,CONTlttUETOITEM5)B~HASAHYDRQGEQLCGICAI.STUDYGRITSEQUIVALENTBEENPERFGIYEDORISTHERESIFFICIENTcURRENTHYDRGGEQLQGlcAl.INFORMATIONAYAttaBLEAsREQUIREDBYTI4wATERREsQURcE'sCGtltISSINIPART22GROlGIWATERRULESOFADJUST1s1980R52322O7(PAGE<<Q)THISEXIS'TINGORPROPOSEDDISCHARGE?IFYESATTACHACOPYCFTHEREPORT.C.AREYQUREQUESIIOANEXEMPTIGNFRCMSUBMITTtt2GAHYDROGEQLOGICALREPORTUt2QERRILER.323.22(I7(7{})(PAGEg)ORFROMGROLCIDwATERMONITORINGt)EQUrtREMENTSLNDERRULER.523.24'5)(PAGEUg)QFTHEPART22RLLEs.IFYEsATTAcHDOQRENTSANDEXPtattATICttTODBONSTRATETHATY(XFIDISCHARGEHEXADQUAt.lFYFORANEXPION.DsAREYGUREQUEsTltoAvaRIattcEFRcMRIAE323.22(5(PAGEL~)(NQtmEGRADATIGN)0FTHEWATERRESOURCESCCtltISSICNPART22GRIEtDWATERRULES?IFYESATTACHSUCHDOCUMENTSASNECESSARYTODEMON@RATETHENEEDFORAVARIANCEINTERMSOFBEcRITERIAsPEcIFIEDINRIAL525s~o(PAGE~0FTHEPART22RULEssNANANA~0.02YESCI:EsYESXNQEsI,ISTAIJ.CtetICALSu)STANCESWHICHAREINMICHIGANSCRITICALMATERIALSREGISTERTABLEIV(PAGEtt)AND/QRUss~EPAsPRIcRITYPQILUTANTLlsTTABLEv(PAGE7)cRANY0THERslssTANGEsHIICHAREORHAYBECCAINJIHIOUSTOBEDESIGNATEDUSESOFBEGSXSQHATERORIDTHEPUBLICHEALTHTHATAREDISGORGEDOREXPKTEDTOBEDISCHARGEDTQTHEGRQUIDtATERAYTHISFACILllYsESTIMATEBIEFINALEFFLUENTCONCENBIATIONANDRECCRDALLDATAINITEM7OFSECTIONIIINTHISBOO@ET.NQTAPPLICABLE/BELIEVEDABSENTNACOD(OetICALOXYGENDEMAttD)TOC(TOTALORGANICCARBON)'un'aNITRQGEN(asN)TOTALSUSPENDEDSOLIDSEXPECTEDWASTEWATERCHARAC-slcsUNiTSCODE~TOTALhOSPHNUS(ASP)BEAPPLICANTMAYBERECUIREDTODOADDITIGttALHASTEANAL'(SESsAsDISCHARGECHARACTERISTICStTEM5BQD5(FIVEDAYBIOCIEHICALOXYGENDEMAt4t)CONCENTRATIONPRESENTiDATAPROVtDEDINITEM7u1uluLJu1u1uwtTScQDEIIANALYsES~TYPECODE1Mg/I2Ug/I3COUNTS/100ml.4S.U.5'F6LBS/DAYTOTALRESIDUALCH.CRINEDISSO!.VEDOXYGEN'PHFECALCOLIFORMBACTERIA~ERATU2E(sue+)1~iERATIRE(wINTER)MIN~7~0~73,u5~60u4~89u7ulu3u5u5u1ulBsOTHERWASTEWATERCHAIIACTERISTICSSAMPLEZXEF1GRAB224HOURCOMPOSITE0ILttGREASEuIuuuLJu~SEEATTACHEDSHEETSFORANALYSISDATA*Basis:1993actualdatasubmittedonDMRSRECIIIREDINFORMATICNFORSURFACEHATERDISCHARGES~35 II~resJ"asrsC"es35$lS3rS"""r'S5ISCa(ielfSrvIsr',Sc'.tv.-",en'esvs:'nk0-c3nvrcerwiIIOs355rchec.-.-Cer"SCSCes5eJIrevfcstrskssssITCH3=creac-'sdlv:dualIscnarceccirt3searaesetcfrJJoCCC53'llu+CTJsfr-',I.PCcuATIC.3"-er-"e"3"s'"eprcCeSS<<niC"Cc"~"'C.tes--sIS5SCnalCe.--"vrce--e"""er-IC-""e"clca-e-;evearlvSverageprocessS=heculer"cutscercavnccavs-:er-lear..~providetneprocesswastewaterflowrateinformationasrecuestecbasedonyourlastl2rrrcnthsofoperations.rtefertounitcodegivenintheleftnatcinfortheappropriateflowunits.pocessproductioncate-certainperritI:rritatlonslrravoecasedcnproductionrates.TheproductionratesusedtoletsrnlneCernitlimitsShallerepTsSen-ed>V3reaSCnapierSeasureC<<C-ualCrCCVCtiOnCfthefaCIIISV,SVCnaS:t""otic"ccln""e"icnrent%cJ"ecre'llcu5'lea.~crneerrcnthlvaveraceforthenirihestof,reorevlcusfiveyears,ortne..lasonaple"easvreas5~steorn30>re'.-,.-'..-eccr'csr-resSrc"scvlations.rew5Jp(escr'swciscnar'cel5~a.<elTtn5sar),eestfeatsSIncrolecsedproduction.Cr3-CCVClcnrs-esin--s-SrstSno..'-5.Se',ntroSCCIJcac,e,.=.=.;.A.Cate"OrioalruieSSndneouiaticnSCr' SEEINSTRUCTIONSONREVERSESIDESEGTlONIIPERMIT~ME0005827NUMBERlM6PRIORITYPOLLUTANTSANDADDITIONALiNFORMATIONFORSURFACEWATERDISCHARGEONLY(NFJILLMBr>>>>EFQUDWIMGREQUESTEDINFORMATIONe~rADDRESSEDava>>'URFACEWATERDISCHARGERS,6'>>JUSEDISCHARGERS~s>>'RQVICEEJECTEDVALUESFCRIHEQUANTITATIVEAMQUALITATIVEIt<FORlQTIQMREQUESTEDBKLQW.A.:STHISFACILI1YAPRIMARYIl<DUSTRY?(REFERTOTABLEIAPAGE4+SQTOE)(tFv<sGQTO3)B.INDICATETYPECFPRIORYINDUSTRYASLISTEDINTABLEtAPACiE4+.JuratAJEWITHC.)CXESIRISOUTFALLDISCHARGEVlaAINAllYPROCESSWASTE'>>JATER?(IFMGOTOE)(IFYESGQTOO)O>>NDICATKWHICHGC/tYJFRACTIONSWsfBETFSTEDFOR~(REFERTOTABLEIAP4%U~IJQIEIFcREAcHGc/HsFRAcTIQNcHEcKED,EAcHsPKclFIcQRGANlcToxicPOLLUTANT'WITHIN~MHFRAcTtQN~BEANALYzEDF0R(sEETABLEIIAPAGEIJ2,INADQITIQN>>AU.PRIMARYIMUSTRYAPPLICANTS.WITHaPROCESSwasTKWATKRotsoURGE~PRQVioEQUAMTITATtVEDATAFOREACHTOXICPOUIJTAMTIMTABLEIIIAPal<4+~RECORDALLDATAONFORMSPROVIDED(ITKH7)INTHISBOOKLET>>(CCNTttAJE'WITHEKBOX')~002YE<JQSTMELECPMRXYESXvQLATILEXBasE/MEUIRALACIDCIPESTICIDE**E~IF~<SURFACEWATERDISOIARGEAPPLICANT(PRIIVUIYORSECCNDARYIMIVSTRY)>>REGARDLESSOFTHETYPEOFDISCHARGE>>KMWSORHASREASONToBELIEVETHATANYPOILUTAMTLISTEDINTABLEIIAANDIVAPAGES~IsDISCHARGEDFROIANYOJTFALLTHEQUANTITATIVEDATA~BEPROVIDED>>RECCRDAU.CATAONFORMSPROVIDED(ITKH7)INTHISBOOKLET>>wr.APPLICABLE/BELIEVEDABSENrOXPRESENT/DATAISATTACHEDF.IFJUJYSURFACEWATERDISCHARGEAPPLICANT(PRIHARYORSECONDARYINDUSTRY),REGARDLESSQFTYPEQFDISOIARGE>>IQJQWSORHASREASONTOBELIEVEANYPOultfANTSLISTEDINTABLEVAPAGE~QAREDISCHARGEDFRotANYCtffFALLTHEAPPLICJUITt~DESCRIBEREASONSFORTHEPIKLUTANTBEINGPRESENTANOPROVIDEANYAVAILABLEQUANTITATIVEDATA>>RECCRDALLDATAONF(XttSPROVIDED(ITEN7)INTHISBOOKLET>>XMTAPPLICABLE/BELIEVEDABSENTG>>AU.SIRFACEWATERDISCHARGEAPPLICANTS(PRINRYANDSECONDUIYIMXJSTRIES)~QRHAMLFActutES2,4,j-TtttostxtQPIEMKYAQETtcActo(2,4,5-r);-(l,4,5-TRIQHLDRQPWEMxYPRQPAMICacto(SILYEx,2,4,5,TP)>>4>>&IRIotJxtcPHEML(TcP);0RHExAcKoRQPtK%(HP);(ALLDATAF0RTHEABOVEi%STBEGENERATEDUSINGSTJUIQARDANALYTICALCALIBRATIONPROCEIXRES)ORKilty'sORHASREASONTQBELIEVETHATTCDDtSORHAYBEPRESENTtNTKIRDtsCHARGE>>~REPORTQIALITATIVEDATA>>GEIERATEDleIOIUSEDASCREENIWPROCEDNEMTcALIBRATKD'WITHANALYTlcALsfANDARDs,F0R2.5./8>>-TKtttaotoRQDIBEMzo-PDloxlN(TCDD)>>RECORDALLDATAONFORFARPROVIDED(ITEM)INTHISBOOKLET<~',Fr>>'ESURFACEWATERDISIHARGEAPPLICA<VTKMWSORHASREASONTQBELIEVE1>>ar3IQLGGI(AIa~xlcllYTEsTs'WEREMADEINTHELAsTTHREE(5)YEARs0NAttr0FTHE4VLICAVTSDISCHUIGESCRONARECEIVINGHATERINRELATION10ADISCHARGE>>PROVIDETHISINFQRHATICNASANATTAotEMTTOTHISAPPLICATION>>:FACQMIRACTLU}QRATCRYCRCQNSLLTIWFIRNPERFORMEDANYOFTIE<UAAYSESREQUIREDBYTHISAPPLICATION>>PROVIDETHENAMEANDADCRESSOFEACHLABCRATQRYORFIRNAMTHEJVJALYSESPERFCAKDASANATTAOtENTOFTHISAPPLICATION>>QQYQUDlscHARGEANY0THERToxicQRIMURIQUs{KHIQALsutsTAMQEsNQTLIBTEDINTABLESIVPAGE(IAIOIIATHIQU4tVAPAGES~~<t~vES>>THENIDENTICTHE~MAGICALSUBSTANCESJVJDESTIMATETHEFINALEFFUJENTCONCENTRATICNS.SIEPIITTHISt<VQRHATICNASANATTAOt%MTTOTHISAPPLICATION>>XwrAPPLIQABLE/BELIEYEDABSENTQPRESENT/DATAisarraoEDMrAPPLICABLEAPPLICABLE/SEEATTACHED*QMTAPPLICABLEXaPPLIQABLE/SEEarfacHEDMTAPPLICABLEAPPLICABLE/SEEATTAOIED*SeewholeeffluenttestdataattachedtoOutfall001.**Pesticidedataisnotrequired;.however,itisprovided.
~>>o>>>>--u855~35'ce5rce*ate('540n53"e>>cr"""ev~---e5-a-e5<<'5-'--ehleaveb>>anx31c3"u,oet<<>>IIceasslcrea.asa$e<>JSCCSV'slSCbt>>a<<<<>>5e<<a8>>5>>-3.e-.O:"CreSubeta"TIble5.3"Ss'rsv:lel"sourSc.eST"S,,ranteabv--*1sal.aa55t.'.,'.v'"cent'.asc.tassts~~uav'vestcermiss(cn'raravcur=e<<~-'""avt"cr'Tv33<<5tsl54Sus5.eahaaVS>>5IToes5JbstantlasIsIen3.3(utfSIIS.5ca~it-Iranautncrl-v,:nasecarates"eetettac1ec-."."eaaotlcaticnt"t'=enrvcaser.erv-"eS.taslIS*niC1vCucic1OT-eSTstdS.ostarriasIvlcenti5(TOtheOut'.alIcrzrerictoxiccollurantS3Is~8'3aas3ass'5~e55%e<<action~.r.Tte~ecs'cctsflTITatsveSnaTCXICOSluranTSSSreauireabymarta22~Zl(a)(7)(Ii)(A)OrIZZ~2l(8)(7)(IiI)(A).vaseoart53reself<<exolanarcrvSnaonotreauire'>>.rttetInst(ucticrs.Slmclva)oTt'tcuanebencarp3<<a.oassncicated.53".5'3>>3ear>>esaI<<er'855/5ee<<e>>>>COe>5'5Cn~<<sin'9/a+"3<<ICns>>IVI>>t>>"<<SOS<<l<<C5l5TOCet>>3"SssScectrtscccs.='racrions.9<>etre<<~l'.'3'v5<<as35".eg>>amersg<<e<<cr5<<:,>>'s'rcraaroarabrv/Sr/VS=racticne5Ti:lcanaReocrtlna=xemotlcnsaxtileallissrcustrv-<<llsourr>>C/VSSrtanicfracrlo1s!"rT"erreiqe":Ils'catecorv~-=eSTICICe<<aCriOnanallOthetSubbartSCfThlSIrCuSrry.:rela'lin(naanaCresslnaIndustry/latI!c~case/"cuts'al,5>>a=e5'::e"3.Icrs-RBasea>>a~lecic'u3talsSubcateaorv.-all'r""/"Srganscaractacns'sl-t"ersubcareaoriesofthisincustrv..umanaStnaaChemicalsIndustry-SSCSCIC(defraCtiansntheTallQ(lWOSInSubCateaarVanOtheRasinSaseaOeriVatiVesSubaatea)ary.-tscsticiaeandbase/neutralFractionsinallocherSubcaceaoriesofthisinduscry.3atoandoaocrS<<avstrv-aCS(iC:defraCCianInPaOeraraaeSulfiteSVOCateCOries(SubOarCSJandU).~3}sct-cut>>.3i3-cscsticsaelcttc-4~<<ocinxsuboart'),olssolvinaKrastsuboartF,anapaoerboarafrc<<castea)ocrSuooas't8,valetile.baSC/neuCral,OeSCiCiaefraatianSs1CleBCTSleaaneaKrafCSubOartSI.Semi-ChemiCalSubOarCS8andC.andyonintcaratca.c(nePaoersSuboarte.<<csa.Sascttcutral,anaocst~cacfractionsanF~neBleacneaKraftSubOartI.OissolvsnaSulfitePaloSubaart'(.",~rauna-aoap:ncssaoerssuboarto.marxecBleacncaKraftsuooarco.TissuefromMastcoaoersuboartT.andNonsncearacedTi55ueeaoersSuboartS.StcamElectr(cPo>>erPlantInduscrvBasctneucraltractionsntheOnce-Throua)nCoolinqdater.tivAsh.anaSoctomAshTransoort'Maccrorncess>>astescreams.:38 SEEINSTRUCTIONSONREVERSESIDESECTIONIINUMBFRWi4II00058279JIFRLMB~002USETHISDATASJEETTORECORDINFORMATIGNASRECUIREDIN:(CHEQ<APPROPRIATEBOXFCRIttICHINFORMATIONTHISDATASHEETREPRESFDJTS~)CRITICALMATERIALSl.SECTIONlliITDI4E~GROLttDLLATKRDISCH/>>RGEINFORMATION(PAGE55)X2.SECTIONII.ITEMb.PRIORITYPGLLJJTANTSINSLRFACEHATERDISCHARGE(PAGE37)TOXICPOLLUTANTSHAZARDOUSSUBSTANCESINDISCHARGEBiLISTANYCRITICALt"ATERIAL(TABLEIVPAGE6)NOTADIJ2ESSEDINSECTICttIIITEMFP,RIORITYPCLLUTANTSMILCHYOUJGXJPtORHAVEREASGNTLLBELIEVETOBEPRESENTINTIEDISCHARGE>>SEEREVERSESIDEGFTHISPAGEFGRFUJ7TIERDIRECTIONS>>t2OTAPPLICABLEAPPLICABLE(SEEBEL7at)UNITSCODE1Mg/I2Ug/ILBS/DAYKG/DAY~P>>MPLEi>>P1GRAB224HR.COMP.LJLit~I~PLAiNAMEOFCRITICAl.MATERIALCRPRIORITYPOLLJJTANTBiAVERAGECCNCEJIIRATICNJSAMPLElYPEJIIIOFANALYSESC~MAXILJtCatCENIRATICNAJOt'ASSA.NAMEOFCRITICALMATERIALORPRIORITYPOLLUTAJIT8AYERAGECCttCENTPATICN;SAMPLETYPEJttOFAttALYSESC.JLlLXIttltCCNCENIRATIONAt4)MASSA.ttAMEOFCRITICALMATERIALCRPRICRITYPOLLUTANTB.AYERAGECONCENIRATION;SJMPLKlYPE;l'FANALYSESC.MILXItllLCONCKNIRATIONANDMASSA~NAMEOFCRITICALMATERIALORPRIORITYPOLUJTA%'.AVERAGKCONCENTRATIONJSAPLETYPE'>>OFAttALYSESC"AXIttltCO'CENIRATIONANDMASSA.ttAJECFCRITICALMATERIALCRPRIORllYPOLLUTANTS~AVERAGECGNCEJITRATION;SAMETYPEJ~OFANALYSESC.~AXIMLttCGNCENIRATIONAMJMASSAJA%GFCRITICAL"ATK7IIALORPRIORITYPOLLUTAVT*SodiumHochloridet.ASS014IUNITCODESV'PLKTYPEOFANALYSESLJWITCODEUt!TCOCKLJLNITCODESAMPLETYPELJFANALYSESWITCODEWITCODELJWITCCDESAMPLETYPEOFAJLALYSESWITCODEWITCODELJ~.~LJWITCODESAJYPLETYPEJJOFANALYSESLJLltITCODEWITCODELJ~~~LJWITCCDESAMPLETYPEOFANALYSES~.LJJ~~L>J~~~*~0,~23~1~273.~~V2~B.AVEJLAGEcatcENTRATIGN;SAMPLETYPE;I"GFANALYSESc.AXI~cONCEJILATlalAJ4JMASSA.%PEOFCRITICALMATERIALORPRIORllYPOLLUTANT3.AVERAGECONCKNIRATION;SJMPLKlYPE:JtOFANALYSESC>>,MAXlttP.CCttCENIRATICNAttDMASSWITCODE'AMPLETYPEOFANALYSESUNITCODEWITCODELJLhllTCODESA'LPLETYPEJJOFAttALYSESLLLJWITCODEWITCODEA.:>>AMKOFCRITICALi"ATERIALORPRICRITYPOLLPJTJVLTBiAvEPAGEcatcENIRATIGNJSA>>LPLETYPE;>>It0FANALYsEsc.MAXIMJJLcatcENTRATIONAJ4)MAssSJVLPLETYPEOFAtLALYSESLJUNITCODEWITCODELJ*Dischargedastotalresidualchlorine**Basis:ADDITIONALPAGESOFTHISITEIL7AREATTAOEDFORTteRESTOFTHECRITICALCIYESMATERIALSAta/CRPRICRITYPLXLUTANTSRECUIREDTOBKREPORTED.QXNO1993actualdatasubmittedonDMRs.AverageconcentrationbasedondatafromMaytoDecember.39 I'S!,'"'S"R"rdzPL:TEu7raistor.Isrobeusedbvbothsurfaceandgroundworeraoplicantstorecordlnformorlononanvmichigancrltlcaimaterial,E.p.A.Z-"C<<IPcflu-onr.=.nazarccussvas-anceIn<<nice-'sTool!car!onrequirescata-Obeprovided.his<<ou!CinCluceanvchemico!.:-csancee"icnlgancritico!"arer.aisegisreri,ab)eI'/).TheE.p.A.p~icrltvpolluran.'sr!noITable'/).-rTablesA-<<<<nion!ISTS<<rgan!CTOXICPOllutanTS,OtherTOXICuqllutantS,"nVentlcnalandNcnqqnVenricnalPOI+tantSOndNOZardcuSS.bsrances.ITmz7:.ITIC/I."ATEPIALS,=RIORITYQLLUTANTS,AND/ORHAZARDOUSSUBSTANCESINTHEOISCHAPGEvaterialI,2.3...8ListrhenoneotthechemicalsubstanceIcritlcalmaterial,priorlrvpollutant,ornazardoussubstance)fromTablesIV,VonoIIA-VAosrequiredIntnebox<<nlcnyoucheckedInA.l-3.abbve.EntereachchemiCOIsubstanCe'SparameternumberoslistedInTablesIV,.VandIIA-VAitprovided.B.orovldetheaverageconcentrationofthechemicalsubstancenamedInA.IndicatethesampletypeusedandthenumberofanalysesmodetoprovidetheconcentrationdataforthechemicalsubstancenamedinA.ProvidethemaximumconcentrationanddeterminethemassloadingofthechemicalsubstancenamedInA.NOTES:I.Ifonlyoneanalysiswasmodeforachemicalsubstancethenrecordthatdataosamaximumvalue.IfmorethanoneanalysishasbeenmaceforachemicalsubsTanceThenprovideanaveragevalueotthoseanalysesandthemaximumvalue.2.ThisSectionII,Item7,DataSheetprovidesspaceforrecordingcatafor8chemicalsubstancesIMoterlals).AddlticnalSbOCe<OrreCOrqlngOfdatatOrmererhan8MarerlalSCanbemadebymakingCOPleSOfthlSItem.7DataSheetosneeded.ItisalsoimporronttouseaseparateserofDataSheeTsforeachapplicablereportingrequirementaslistedInA.I-3.andforeachoutfall.3.RefertotheleftmarginforthecodenumberrepresentingtheSamPletypeusedandtheappropriateunitcodes.40 ANALYTICALREPORTCookNuclearProj:WasteWaterAnalysisSubm:Jan26SamplesSubmittalNumber:29609-3Location:Contact:RayV.BuhlPhone:(616)942-9600Outfall001Outfall002Circ.IntakeDetectionUnitsLimitWWESSampleNo:783717837278373BOD,(5-Day)Sampledby:DateSampled:TimeSampled:DateReceived:TimeReceived:<1.001/26/9400:0001/27/9413:30<1.001/26/94000001/27/9413:30<1.001/26/94000001/27/9413:301.0mg/1:>')~)')(II('ll'6rlr)rlIIIIIHIale'h5alt8I'.I()lkrl5874.(II'rlll(lRrlpl(IH.11III)5880874.8I8/I)420I)00I'rl'r0I~2III8 llll/lIIn('(I'BIi6.S'(7nI('(1~emu@(('>IlvallllSTATEMENTOFDATAQUALIFICATIONSCLIENT:CookNuclearSUBMITTAL'9609-3AllanalyseshavebeenvalidatedandcomplywithourQualityControlProgram.Noqualificationsrequired.Thefollowinganalyseshavebeenqualifiedforthereasonscited.KEYl.2.3.4.5.6.7.8.9.10.Sampleintegritysuspectuponreceipt(explain).AnalysisperformedbeyondEPAestablishedmaximumallowableholdingtime.Detectionlimitelevatedduetomatrixinterferences.Laboratorycontrolsamplevalueoutsideestablishedacceptablelimits.Matrixspikesamplevalueoutsideestablishedacceptablelimits.Duplicateanalysisvalueoutsideestablishedacceptablelimits.Surrogate/internalstandardrecoveriesoutsideestablishedacceptablelimits.Datapointsuspectduetopotentiallaboratorycontamination(explain).Coeluteswiththecompoundcited.Resultmayrepresentacombinationofbothcompounds.Other(explain).Note:ThisdocumentisincludedaspartoftheAnalyticalReportfortheabovereferencedandshouldbe.retainedasapermanentrecordthereof.)'>')>(llenwondIllllsParkwaySI'.POBox874.(Iran(lRnpl(ls.Xtl49588-0874.8IG/842-8800!'ax0-I2-8In!
tl1!'En)e(no!E-'.')n(n(7l,iatnmi((nmp,vnXl1II(XlslI'KI(IANALYTICALREPORTCookNuclearProj:WasteWaterAnalysisSubm:JanuarySamples29609-4RayV.Buhl(616)942-9600SubmittalNumber:Location:Contact:Phone:OutfallOutfall001-Circ002-CircWaterDschWaterDschCircWaterDetectionUnitsIntakeLimitWWESSampleNo:7853278533'8534Surfactants,MBASColiform,FecalColor(Apparent)Sampledby:DateSampled:TimeSampled:DateReceived:TimeReceived:(0.0252<5V.Shah01/26/9400'0001/28/940000<0.025<1<5V.Shah01/26/94000001/28/940000(0.025<5V.Shah01/28/9400000.02515mg/1cl/100ml6pH5:)55(II(.'nivn()(lII!IlsPnrkivnySE.POBox874.(I('nn(lRnpl(ls.III49588>>0874.616/902-9()00I'nx9I'-6I!)9 lHVErt,>ateelVn>f-SneBCett.s>>>>>>>>iIc:rt>>>p'>>>tSTATEMENTOFDATAQUALIFICATIONS;4XAl.'>'I'(l5I.,'bI'.R'tIt:t!:CLIENT:CookNuclearSUBMITTALr29609MAllanalyseshavebeenvalidatedandcomplywithourQualityControlProgram.Noqualificationsrequired.ThefollowinganalyseshavebeenqualiTiedforIhereasonscited.SampleNo.(s):Explanation:Parameter:KEYl.2.3.4.5.6.7.8.9.10.Sampleintegritysuspectuponreceipt(explain).AnalysisperformedbeyondEPAestablishedmaximumallowableholdingtime.Detectionlimitelevatedduetomatrixinterferences.Laboratorycontrolsamplevalueoutsideestablishedacceptablelimits.Matrixspikesamplevalueoutsideestablishedacceptablelimits.Duplicateanalysisvalueoutsideestablishedacceptablelimits.Surrogate/internalstandardrecoveriesoutsideestablishedacceptablelimits.Datapointsuspectduetopotentiallaboratorycontamination(explain).Coeluteswiththecompoundcited.Resultmayrepresentacombinationofbothcompounds.Other(explain).Note:ThisdocumentisincludedaspartoftheAnalyticalReportfortheabovereferencedandshouldberetainedasapermanentrecordthereof.5555(s'tenwoodttlllsParkwaySE.POBox874.(>randRapids,Mt49588-0874.616/942-9600t'ax!)4'>-t!4!)s GENERALCHElVIISTRYRESULTSClientSamieID:OUTFALL002LALBatchIDls):126imDateCollected:01-24-94DateReceived:01-26-94Matrix:waterPO¹69095-040-3NConstituentMetoaResultReportingDetectionLimitDateQuelifierfs)DataAnalzedLALSemIeIDFluoride,inmILBromide.inmILNitrite-Nitrate-Nitrogen,inmILSulfate,inmILTotalCanide,inmILTotalPhenolics,inmILSulfide,inmIL340.2300.0353.2300.0335.2420.1376.1<0.15<0.0500.3423<0.020<0.15<1.00.150.0500.0500.0590.0200.151.003-02-94L1131-901-28-94L1131-1702-11-94L1131-2201-27-94L1131-1701-27-94L1131-2602-08-94L1131-3201-27-94L1131-12Comments:
GENERALCHEIVllSTRYRfSULTSClientSampleID:OUTFALL002-CWDISCHLALBatchID(s):126im,127imDateCollected:01-26-94DateReceived:01-27-94Matrix:waterPO¹69095-040-3NConstituentTotalPhosphorus,inmILAmmonia-Nitrogen,inmILTotalSuspendedSolids,inmILTotalOrganicCarbon,inmILChemicalOxygenDemand,inmILTotalKjeldahlNitrogen,inmILMethod365.2350.1160.2415.2410.2351.2Result<0.030<0.050<122.0<18<0.10ReportingDetectionLimit0.0300.050121.0180.10DataQualifier(s)DateAnalzed02-08-9402-01-9402-02-9402-16-9401-28-9403-03-94LALSamleIDL1142.6L1142.6L1142-10L1142-2L1142-2L1142-6Comments:
GENERALCHEMISTRYRESULTSClientSamleID:OUTFALL002LALBatchID(s):128imDateCollected:01-27-94DateReceived:01-28-94Matrix:waterP0469095-040-3NColorConstituentSultite,inmg/LMetod110.3377.1Result(5.0(1.0ReportingDataDetectionLimitQuallflerls)5.01.0DateAnalzed01-28-9401-29-94LALSamleIDL1151-2L1151-2Comments:
METALSRESULTSClientSamIeID:OUTFALL002LALBatch)DIs):126imDateCollected:01-24-94DateReceived:01-26-94Matrix:waterPO¹69095-040-3NConstituentsMethodConcentrationImIL)ReportingDetectionLimit(mIL)DataQualifierls)DateAnalsedLALSemleIDAluminumAntimonArsenicBariumBerIliumBoronCadmiumChromiumCobaltCoerIronLeadManesiumMananeseMercurMolbdenumNickelPhoshorusSeleniumSilverStrontiumThalliumTinTitaniumUraniumVanadiumZinc601060107060601060106010601060106010601060107421601060107470601060106010774060106010784160106010602060106010<0.20<0.060<0.010<0.20<0.005<0.20<0.005<0.010<0.050<0.025<0.10<0.00312<0.015<0.0002<0.067<0.040<0.050<0.005<0.0100.13<0.010<0.20<0.10<0.001<0.050<0.0200.200.0600.0100.200.0050.200.0050.0100.0500.0250.100.0035.00.0150.00020.0670.0400.0500.0050.0100.100.0100.200.100.0010.0500.02002-22-94L1131-9502-22-94L1131-9502-20-94L1131-9502-22-94L1131-9502-22-94L1131-9502-22-94L1131-9502-22-94L1131-9502-22-94L1131-9502-22-94L1131-9502-22-94L1131-9502-22-94L1131-9502-23-94L1131-9502-22-94L1131-9502-22-94L1131-9502-09-94L1131-9502-22-94L1131-9502-22-94L1131-9502-22-94L1131-9502-25-94L1131-9502-22-94L1131-9502-22-94L1131-9502-28-94L1131-9502-22-94L1131-9502-22-94L1131-9503-07-94L1131-9502-22-94L1131-9502-22-94L1131-95Comments:
VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260Page1of2linamleID:OUTFALL00DII:4-AN-4Matrix:WATERAnalticalBatch¹:020394-8260-J-2QCBatchID:020394-8260LALamleID:L1131-44DRiv2-AN-4DateAnalzed:03-FEB-94DilutionFactor:1RRTEREOVERYQCLimits12-Dichloroethene-d4Tn4-Bromofluorobenzene99149776-11486-115ChloromethaneVinIChlorideBrmmehnhrhnTrichlorofluoromethaneAcone11-DiIrhnnDiIfiMethleneChloridetrans-12-DichloroebeneVinIA11-DiIrhn2-Butanonecis-12-Dichloroethenehlrfrm111-rihlrhCarbonTetrachloride12-Dichloroehan8nnTrihirhn12-DichlororoanBromodichloromehaneConcentrationL<5<5<10<5<5<10<5<5<5<5<5ReportingDetectionLimit1010DhlIVinr4Mhl--ennncis-13-DichlororoeneToluenern-1-Dihlrrn2-Hxnn112-TrichloroethaneTetrachloroethenePCE<5<5<5<5LOCKHEEDANALYTICALSERVICES
.VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260Page2of2ClientSamleID:OUTFALL002LALSamleID:L1131-44ConstituentDibromochloromethanehlrnnEhInnm-Xlenao-XlenernBrmfrm1122-Tetrachloroehane13-Dichlorobenzene14-Dihlrnn12-DichlorobenzeneConcentration/L<5<5<5<5<5<5ReportingDetectionLimit/LDataQualifiersZCGLOCKHEEDAIVALYTICALSERVICES VOL'ATILEORGANICANALYSISRESULTSFORANALYSESUSINGIVIETHOD8260TENTATIVELYIDENTIFIEDCOMPOUNDSClientSampleID:OUTFALL002DateReceived:264AN-94Matrix:WATERAnalyticalBatch:020394-8260-J-2LALSampleID:L1131~DateAnalyzed:03-FEB-94DilutionFactor:1QCBatchID:020394-8260TentativelyIdentifiedCompoundNOCOMPOUNDSIDENTIFIEDEstimatedConcentrationIyg/L)RetentionTime(minutes)DataQualifier(s)LCGLOCKHEEDAIVALYTICALSERVICES
SEMIVOLATILEORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGViETIIOD827pClienSamleID:OUTFALL02DateCollected:24-JAN-94'atrix:WATERAnliIBh4'.24-7-AQCBatchID:8270-SEMIVOLATILE4825LALSamleID:L1131-57DateReceived:26-JAN-94DilutionFactor:1DExrd31-AN-4DateAnalzed:03-FEB-94PeIof2SRRGATEREOVERY0Limi2-FluorohenolPhenol-d,Nitrobenzene-d,2-FluorobihenI24-TriromhnIp-Terphenyl-d27206758484121-10010-9435-11443-11633-141Phenolbis2-ChloroethIeherhlrhnI1-Dihlrnzn14-DichlorobenzeneBenzIalcohol1-Dihlrnzn2-MhlhnIbis2-ChloroisoroIether4-MethIhenolN-Nir-Di-n-rIminHexhlrhaneNitrobenzeneIsohorone-NirhnI4-DimhIhBenzoicacidbis2-Chloroethoxmehane4-Dihlrhn14-TrihlrnnNahthalene4-ChloroanilineHxrin4-hlr--mhlhnl2-MethInahthaleneHexachloroccloentadieneConcentrationL<10<10<10<10<10<10<10<10<50<10<10<10<10<10ReportingDetectionLimit10101010101010105p1010101010DLOCKHEEDANALYTICALSERVICES 0
SEMIVOLATILEORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270ClientSamleID:OUTFALL002LALSamleID:L1131-57Pae2of2Constituent4-TrihlrhenI4-TrihlrhenI2-Chloronahthalene2-NitroanilineDimhIhhIAnhhln26-Dinitrotoluene3-NiroanilineAnhhen4-DinirhnI4-NitrohenolDibenzofuran4-DinirInDihlhhl4-ChlorohenI-henletherFluorene.4-Nirnilin4-Dinir--mhIhnIN-Nitrosodihenlamine4-BromohenI-henletherHxhlrnznPnhlrhnPhenanthreneAnthraceneConcentrationIIL)<10<25<10<25<25<10<10<10<2<2<10<10<10<10ReportingDetectionLimitIIL)102510252510101010101010DataQualifierls)Di-n-IhIFluoranthenePreneBInIh'-DihlrnBenzoaanthracnChrsenei2-hIhIDi-n-IhhIBenzobfluorantheneBenzokfluoranthene<10<10<10<10<10<10101010101010BnrnInn1rnDibenzahanhraceneBenzohi)elene<10<101010LOCKHEEDAIVALYTICALSERVICES SEMI-VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8270TENTATIVELYIDENTIFIEDCOMPOUNDSClientSampleID:OUTFALL002DateReceived:26-JAN-94Matrix:WATERAnalyticalBatch:020394-8270-ALALSampleID:L1131-57DateAnalyzed:03-FEB-94DilutionFactor:1QCBatchID:8270SEMIVOLATILE4825TentativelyIdentifiedCompoundUNKNOWNKETONEEstimatedConcentrationIyg/L)9.3RetentionTlrneIminutes)4.80DataQualifierls)CLOCKHEEDAIVALYTICALSERVICES OILANDGREASEEXTRACTABLESANALYSISRESULTSBYFT/IRUSINGMETHOD413.2ClientSamIeID:OUTFALL002DII:4-AN-4DRiv:-AN-4Matrix:WATERAnalticalBatch¹:020494-413.2LALSamleID:L1131-77DAnl:7FB-4DilinFr:1DateExracted:02-FEB-94QCBatchID:020294-413.2ConstituentOilandGreaseConcentrationmLReportingDetectionLimitmDataQualifier(s)LOCKHEEDAIVALYTICALSERVICES PESTICIDEANALYSESRESULTSBYGC/ECDUSINGMETHOD8080lienmleID:TFALL-2DaII:4-AN-4DateExtracted:31-JAN-94Matrix:WATERAnalyticalBatch¹:013194-8080-E-4LALSamIID:L111-7DRiv:2-JAN-4DateAnalzed:01-FEB-94DilutionFactor:1QCGroupID:8080PEST/PCBS4822TCMXDCBRRATEREVERY6345"QCLimits60-15060-150A-BHB-BHCG-BHCD-BHConstituentConcentrationL<0.05<0.05ReportingDetectionLimit0.050.05DataQualifier(s)HEPTAHLRALDRINHEPTACHLOREPOXIDEHRDANENDLFANIA-CHLORDANE44'-DDE44'-DDTDIELDRINENDRINENDOSULFANII44'-DDDENDRINALDEHYDENDOSULFANSULFATEMETHOXYCHLORTXAPHENPB11PCB-1221PCB-1232PB14PB-1PCB-1254PCB-1260TECHNICALCHLORDANETCMX-tetra-chloro-meta-xyleneDCB-Deca-chloro-biphenyl<0.05<0.05<0.05<0.1<0.1<0.1<0.1<0.5<20.00.050.050.10.10.10.10.5l44LOCKHEEDANALYTICALSERVICES RADDATAREPORT(ra01)IndianaHichiganPoverCo.~Bridgman,HI.OrganicandInorganicContaminants(ProjectCOOK-JENI)Hatrixt'listerClientSampleID:OUTFALL002DateCollected;24-JAN-94LALSar@leID:L113+86DateReceivedt26.JAN-94LoginN+4ertL1131s"""'""><"'Anal~ed'Babb'"""<"~"""'-'-':"l'"-'"""""-"":<':-'-'~~~ActMty@"O'For'~~IB)IL~~".~:-'a'tagual'-'Infts-"'rossAlphaGrossBeta23FEB-94GRALP/BETALAL~0060475623-FEB94GRALP/BETALAL006047560.331.9O.M1.31.72.2pCi/LpCI/LPage7
RADDATAREPORT(ra01)IndianaHIchiganPcwerCo.eBridyaan,HIOrganicandinorganicContaeinanta(ProjectCOXJENl)Hatrlx:llaterClientSeep(aID:QITFALL002DateCollected:24.JAN-94LALSanctalD:L1131-90DateReceived:26-JAN-94LoglnKwhr:L1131QP~Coni'tRa-226Ra.22822.FEB.94RA.226LAL.0073477123-FEB.94RA-228LAL.007455030.0160.520.0560.120.340.55pCI/LpCI/LPage11 PHMeterCPC9JomCdateduePHAnalysis(LAB.079)Outfall002SampleSampleTimeSamplePSampleDateCDMEnteredby05.3.56)SampleC/ph(priortocorrection)7)NHzpHcorrection5.3.6SampleSampleTimeSample$jSampleDateCDMEnteredby8))ampleresultsC/pH"(aftert.~gNHCorrection)3P2e3acb)c-P'4~(6/7>ooU2/L-3oo5.3.56)SampleC/ph(priortocorrection)7)NH3pHcorrection5.3'8)Sampleresults'C/pH(afterCorrection)9)IAB.041SpecsVerifiedby:hl/8RwpeevieeeReview/Deee~&+I~Formpreparedby/DateFormapprovedby/Date12THPLAB.041.25sRevision1 Outfall002DeterminationofTotal(Lab170)ChlorineInstrumentCPCIj50~""""'"'~s'echnicianSample/StandardSamplegDateTimeCDHEnteredby1)Absorbance6.112)Results,ppm(~c~3}DilutionsmadeCHW4)Results,ppm(III2*83)5)LAB.041SpecsVerifiedby:~)9vperviaorRevi'ev/Date~MR~parapreparedby/Date/~f+Formapprovedby/Date12THPLAB.041-25)lRevision0
SEEINSTRUCTIONSONREVERSESIDEGlIFALL'KKRSECTIONIIPERMIT~MIpppg827~003j'j~iVIDISCHARGELOCATIONSCHEDULEFLOWRATEA~LOCATIONOFDISCHeVIGECFRECEIVINGWATER(IE.GRC(tGHATERCRtisV6EGFSIRFACECsDOYCUDISCHARGES~Y.(IFtO.CCNTttAIETOE)DsIFYESeLISTDISCHARGEPERIODSLAKIEMICHIGANXYEStes/IRY~12~01te,/DAY~04~30~SW('s,~NWV,KCIIWIi~6,i0II~066~IJII06~IWASTEWATER~I~ggE.LUIDAPPLICATIONRATECONTACTCOOLING?NONCONTACTCOOLING3PROCESSSSANITARYBSTORMWATERFeTYPEQFWASTEHATERDISCHUIGEG~DISCHARGESOEDIAE(YEARLYAVERAGE)HeDISOIARGEFLOtRATEIOURS/DAYssv/vsse~12I(tIITCOCETOTALYEARLYDAILYHINI~DAILYHAXItSPI/NITCygneIMGY2MGOGPOI.'MFAXINGDISCH6RGERlwRATETOBEAUIHOIIZEDINPERIIT.*uIITCCDE(NITOXELJJsHAXtt(ttDESIGNDISCNRGEFIOIRATEs*DESIGNClYESAeCOYOUUSEHATERIREATHEHTACOITIVESTOTREATYOIRDISCH6RZ?(IFMt,ccNTIN(zToITet3)BeNA%FutCTICN,AtOOettCALCCt&KITICNOFlAESEACOITIVESelTEM2WATERNATREATMENTAODITIVESCeN4%AteADCRESSOFHAIAS'ACTIRERSOFIHESEADDITIVESeINe/WReHR~CAYIN./wK~~u~.'~KIIAWASTDIATER1YPECOCE~3uM.MLJUNITSCODEIMgrl2UgrtDsEXPECTEDDISQQRGECCtCEHIRATICNCFAIOITIVESeNANAHINit%8AVERAGECODEIHITSHAXINtt(ODEWITSCODEAIXIITIVEHA%ADDITIVENA%ADDITIVENA%LJ;~M;~LJEsDOY(XITREATTIEDISCHARGEIOREteVEADDITIVES?NAF.tAIATIS1HERseVALEFFICIENCYANODISCHARGEFREQUENCYADOITIVENtt%ACOITIVENA%ACOITIVENAt%IReeVe.tRS./DAYDAYs/wx.G~ASAHATTAOf%ÃfTOTHISAPPLICATICNPROVIDESPECIFICNWVLIAHCRACUATICTOXICOUF)ICALDATACRREFERENCEHHICHAREAVAIIAELEANDINFOR(ATICNCNTHERATEOFDEGRADATICNOFT%RRCIXICTSFCREACHAIOITIVEs*TheflowforthisoutfallisnotmonitoredseparatelyfromOutfalls001and002 r341~'\j1'8)<<'14<<4~<<p~4~1~'<<'14~~15'418~re~g1C5<<l14)scil4O34I\~<<'<<R'l4)1414<<r3)rrtt$3+I18-.rRrat4rSecI,.-)r-4)5ric",lectton.)Own.d1orant)cSt18$<<BI"BTB<<'21'<<~SCci"re<<1et.Br'<<ci.:Tv:)scnarces-..)Seas=net:as."3.res~~is):iscnarce)Brloos=cvlce8)1C)Colic)rien)-8$.SeC=.-4VCRCea-::euSeai--BrS='"CneSe<<-cur,1aurSCerC)v,)naICC1eSOerweek.'1CIC).e5118C'ST4<<aTR<<,Ce:Isc-lrCeoI-Ž--IsovtfalI~)e<<der"--8<<aSreraTerTVOeCocaaiven)1t1eleft-ar<<r)n."Ore-<<anC1eCcaemaVOe)balllab'lr4"<<8<<.ORr<<Jr3I*~<<'\~~\1~5'34~4)3Rw)--4-.-5'.Cercfdays.v~Ce;.5-".44~))."S,I41)48-rwI)85)5recuestea.)0)8<<-.',1itOe)ivRn~r"8ler<<af'Cln".r-'18))Orcbr~ate.I.<<lr1lf5ry-~it':)"Callcns:Bryear;v%-million,atletscerSay;drO-latlanSOercay.bvl)88)x,tr)".SC')ar<<8flowr).enicn'rau)n-navBavtnari)BJ<<Ital<<.')cermlt.'CTE:-18useof)ucn)'Icwr)te<<i)I-ct"laceanactual')trestrlc,'cncnThe'Ic<<ou;<<ilIbetneentI'1)-$.)Iso,nen18"cntnlv.aeratingeocrtsarereviewedbvCamo)lancesraffitwill~IanvIle'lroli<<creasedu585mlahttraveoccurIeoattnefociIItv,~tar"8"CSerr<<itsonly,IlCwI'ateCSedtadave)OOnelotrentoCerermine"8cesi"rn'.wcrr'))$3ceciI"rf)ll:1scnaraete.g.C)rcn-neat.enrSvstemfla>>,cackaaeotreatmntSV5temflow,ct'erec)18r'l<<l)4-reatrentsrstemfIcw).)dr-'~'-"'Tltc<<alc)~4<<"8"4<<j)r8)3~r<<)BC<<>>1alI8<<$,'11)<<)frs~3<<liarCIcice~~1ctb"tltue~-I-41'4~81I1r4<<l\C$1<<'1RSjgt:.ite1areI"C))cRSS:1emanufaCture"IS)CI-"e<<coitiveSdsea.4<<eh11$4~<<I4~~<<35lr~4i4~4<<<<41<<,4,1<<I~tl14l341-1~-4-"4-4-"v)l8I'-tencv"4)c15)II"8r13<<ITR<<'a*i)4<<~4ast4<<af4<<~81$,)r8l<<<<evercvctR<<cnSaci1fe-"t.'le4$.5,"i)'",ICI)rIII4I")Cuarpati,.154.J8$)BOI'$~4PIC,.1'fcrmatlCn41IR5t<<a.T".!.)ct(eo4av<<<<suit<<8)oolic)ttc<<eel"c<<1)'t'1eoo"8)coif)...'"rcrtoteticn~
SEEINSTRUCTIONSONREVERSESIDESECTIONIINUMBERWHI0005827PROCESSSTREAMSCONTRIBUTINGTOOUTFALLDISCHARGEtft4/t44tOeCtQ.AeNtt%OFPSIQCESSCIXIIRIBUTII6mv/THEDISolARGETHOUGHTHISOUTFALL<<6SICCODEB.PRXESSSOtEIXLE(YEARLYAVEIU6E)C.RIQCESSWASTEMtITERFLOWRATEDePROCESSPRODUCTIONRATENA.DtE~003WITCOCETOTALYEARLYDAILYMINIMtMDAILYIAXISWITS/'TII"EIoios/oev~24Y~561POUNDS2GALLONS3CUBICYARDS4TONS5MGY6MGDstGPDTIME1HOUR2DAY3WEEK4MONTH5YEARAeNAMEOFPROCESSCONIRIBUTII6TOTHEDISCHARGENTHIQUGHTHISOUTFALLAtOSICCXAEBePROCESSSCIEDULE(YEARLYAVERAGE)C~PROCESSWASTEWATERFLOWRATEPROCESSPRODUCTIONRATEAeMAISOFPROCESSCQNIRIBUTlt6TOTIEDISCHARGENATHOROUGHTHISOUTFALLAttDSICCCOEBePROCESSSCHEME(YEARLYAVERAGE)CePROCESSWSTEWATERFLOWRATEDePROCESSPRODUCTIONRATEAeNAMEOFPROCESSCQNIRIBUTII6TOTHEDISCHARGENAAt6SICCODEB~PROCESSSCHZkAE(YEARLYAVERAGE'PROCESSWASTEWATERFLOWRATEDePROCESSPRODUCTIONRATEHOUIS/SAY~SAYS/VSASTOTALYEARLYDAILYMINIHMDAILYMAXIHMHIIOS/OAY~SAYS/YSASTQI'ALYEARLYDAILYMINIHMDAILYMINIHMHteelS/OAY~OAYA/YSAATOTALYEARLYDAILYMINIHMDAILYtAAXIBMWITSCTIMEWITCODEWITS/Tlt%AeNAPEOFPROCESSCONIRIBUTlt6TOTIEDISCHARGETHIQUGHTHISOUIFALLANDSICCODEB.ReCESSSCHULE(YEARI.YaVERAGE)CePROCFSSWASTEWATERFLCWRATEDePROCFSSPRODUCTIONRATETOTALYFARI.YDAILYMINIHMDAILYMAXIHMSIVA/VSAAUNI'TS/Tli"E*TheflovforthisoutfallisnotmonitoredseparatelyfromOutfalls001and00233 IPkc,<<35}:r<<555355Io)f5<<<<Ic1riteo,sIsobar~~~5'"I"I'5I>e5)gel'<iacl<<ra5e<<v<<lan<<<<3tg<<'(xl)cvrtAvqfCI>Ce3SSCreC.)i-.-"e-cace=<<ovlceccresc3qa<<teofsectioni'I,ccrebenInoivlcuatclscharceqoint3separatesetcft34=--3---<<-!-5-"-e-roceSS<<niCCCont-ICtes-q-nlSISCharCe.MISO"rCViCe-neCr""et=.ICCOCSe"e.cartsbier<<"eprocess5reculeinncurscercsvanccavs-ber-veer.Providet3Cprocess.wastewaterflowrateinformationasrecuestedbasedonyourlastIRmonthsofoperations.RefertoJnltCOdegivenIntneleftmarginfortheappropriateflowunits.-rocessqrccuctioncate-certainqermltI;mltatlonsmavbebasedcnproductionrates.Theqroducticnratesusedto:3e~'"ecar.'-~'-Issnail<<ereqr<<senec)vareascnable<<easurecfactual"rcducionofthefacilitv,suchasthe."-..."-'".-:.'-"-<<-Icn,entocf."ecreviustearercrt<<e<<onthlv3verace'crtnenichestofthecrevlcusf(vevears,or=-her"eascnsb.'eeas.reasstatectn3q>>cableJ.S.K.o.h.cat8gor!caIrulesandreoulaticns.ir45:lSC3arde<<s,33-.3~5"Cduc-Žr5>ail:eeStlate.is:no:roiec+eccrcduCiCn55<<e3<53c~rits5ec>53'I)Ie.t..c,h,3Brlcalrulesandreculatlcns'cr SEEINSTRUCTIONSONREVERSESIDE(UIFALLIUDSECTlQNIlM20003827~003GROUNDWATERDISCHARGEINFORMATIONISTHEDISCHARGEFROMTHISCflFALLDIRECIEDTOTHEGRCUt47ORGRON4WATERS?(IFNOeCCttTIhUETOIieetr)MAS*ttYDRCGEOLOGICALSTUDYORITSEOUIVALENTBEBIPERFORMEDORISTHERESLFFICIENTCNRENTHYDROGEOLOGICALINFOfitQTIONAVAIIABLEASRECUIREDBY~wATERRESOIIRCESCOtHISSIONPARi'2GRONIDWATERRULESOFAIIIUSTltte19m)R.525ZQJ7(PAGE4Q)FCRTHISEXISTltiGORPROPOSEDDISCHARGE?IFYESATTACHACOPYOFTHEREPCRTeC.AREYOUREOUESTINGANEXP'PTIONFRQtSUIPIITTINGAHYIXIOGEOLOGICALREPORTUteDERRULER.32$.27/(19}(PAGELtt)ORFRCMGRIX5DHATERMONITORINGI)EOUJREte~0UCERRULER25ZLV5(5)(PAGEQ)OFTHEPART22RILES~IFYESATTACHDOQBENTSAt43~TICNTODEIIONSTRAlETHATYORDISCHARGEWOULDOUALIFYFORANEXEtPION.DeAREYOUREOESTltttAVARIANCEFRCttRULE323e22(5(PAGE5)(NONOEGRADATION)OFTHEWATERRESIXRCESCCtttlsstONPART22GRONIDtATERRULES?IFYESeATTACHSUCHDOQPGPSASNECESSARYTODEWNSTRATETHENEEDFCRAVARIANCEINTEtiMSOFTtECRITERIASPECIFIEDINRtAE525e2210(PAGEIIL7)OFTHEPART22RULES>>NANANAYES'DIESYESYESe>>EeLISTAteeLCte)ICALSIBSTANCESWHICHAREINMICHIGANSCRITICALMATERIALSREGISTERTABLEIV(PAGEtt)AND/ORUeSeEPASPRICRITYPOILUTANTLISTTABLEV(PAGE7)ORANYOPERSI8STAtKESWHICHAREORMAYBECCA%INJINIOUSTOTIEIESIGNATEDUSESOFTIE68XNDWATERORTOTHEPUBLICHEALTHTHATAREDISCH8RGEDOREXPECTEDTOBEDISCHARGEDlDT}EGRIXNDWATERJIYTHISFACILITYESTIMATETHEFINALEFFLUENTCONCENII7ATICNANDRECORDALLDATAINITIN7OFSECTICNIIINTHISBOOILETet%APPLICANTMAYBERECUIREDTDDOADDITIONALHASTEANALYSEseNOTAPPLICABLEJBELIEVEDABSENTNAQRIESENT,DATAPROVIDEDINITII87ITEM5EXPECTEDWASTEWATERCHARAC-UNcsaCODElMg/I2Ug/I3COUNTS/100ml4S.U.5FSLBS/DAYAeDISCHARGECHARACTERISTICStV44XIIANITROGEN(AsN)TOTALSUSPENDEDSOLIDSlDTALPteSPHORUS(ASP)TOTALRESIDUALCt40RINEDISSOLVEDOXYGENMINFECALCOLIFORMBACTERtATEtPERATI4IE(SueCR)TEtPERATURE(WINTER)BOD5(FtVEDAYBIOOENICALOXYGENOP%74))COD(CtetICALOXYGENDEMAIO)'TOC(TOTALORGANICCARBON)COtKENTRATIONLLJ~LJ~~~LJ~~LJLJWITSCODEttANALYSESSAtPIETYPECODELJLJu1~uu>~lu>u~~5B~OTHERWASTEWATERCH8IUtCTERISTICSSAMPLEZXEFlGRAB224HOURCOMPOSITE0ILSGREASE*SEENOTEONPAGE37,Outfall003LJ~LJLJLJLJ~LJLJ~LJLJ~LJREQIIREDINFC848ATICNFQISINFACEHATERDISCH8RGESe35 8~)<<5r<<'158>>t'<<~I~'SC'>>','Qrh>><<385<<Srri>>8dttirsc*<<58Iiicsi,~Scc~I.i'4i4<<>>cvrl"h'tclI~>>-'5'5-8<<:r>>ctcrevrcisl~18>>-i<<I<<ctIiv,-nenleave3l'onx3rd3>>u-cer<<)li.eassicnec.*<<i<<Icer'""853>><<>>vise>>'.Bi358DiSec,Icni(.TCi81cnr"clv<<ualdisc"3r8"ci~5sBDorste$8iv"eacct'con-snollscaressBoc"'neseDor<<sI'8cischarget>>crt-"lsS.t'all'5--".-necrcvrc<<oter.ITEl(5lCl.l.'.)CilI'tihi<<>>rvhit<<tNI'tiwt3hch-""ucccED:SIGSTcihAT=-",oSt'DFB.8hATED-"I8"L'cqrcIG.'.".l>g(,EEreapplicantstolIreportavailablecischarceaa.a(realcataforexistlnccischdrgeorexpectedddtafor3Droooseddischarger'crtheDdrameTersasI5ed.TheseDararetersshallbeaddressedforeither3surfacewaterdlscharaeorasappropriate!oro;Duneothrcischorge.=Cr355(stance>>Btet'tnlnir.qabprcbriateDarsreterS3=raunCxdteralscharaeocolicanTtzycontact"e:"ovhc<<ate>>',i31itv~ivision,Dem(ts:Bctlcr".;-08ocorcbrl'dteSrovnaitdter.volIv<<Iv(5'M'5oi5trlcta!flee.hescclicontshall>>Sportttesrrloletvpe>>ccebestascribingeachreporteapieceofdata.Seeccdirocnt<<eleftmarqlnDfis-"'-t!<<tt'35-r."Sce<<ate>>.I'"<<.:8.--e<<Dpi'con<<vst-Bear-T.dn-l-1(vecato'.-.eocr'corameter(centi!ledbvonlsBr1<<.Ceacct.contmov,nc<<ever,-ecu85--"at-nerecorthsotcatoctc"ecrcreDthese>><<cvlreaDora>>etersce<<3Ivea~.I'c'lB>>ues<vstDO5'DDort9c3ricBDUBTQ1trst8~"dke5Ic,1re>>v85t1n'I~acht"ent0thisDDIIcatlcn,Ta~5variableror=therDardmetersnotI:scca3<<oveinA.CretherDar<<sDfhisacolicationTreapplicantshouldreportmatcatoinTneblonxspacesDroviaeainthisport."".TEc:'.CnitcodesfcrparametersreDOrtealnportSAanO8canDefcundcntnelefthandsideofthisform.:rabsampleshollDBusec-".iralv:e'cr3>>.temberoture,totalDrencls.resiaiaichlcrire,oilandgrease,andfecalcoliformIn3sur'.oce<<oterciscndrceunlessether'recuencv-sampletvpeSnalvsesareavailable.SeeGlossary(Dace48)toraefinitlonof,rabsample.'-nourccmcosltesamplessnailDeuseatoanalyzefcrTotal300c,KD,TGG,crmonlai'litrogen,andTctalsuspendeaSollaslnasurfacewater5)schorreunlesso~herireauency-samoletvoeanalysesareavoilable.SeeGlossary(caoe48)'orCeflnlticnc!Oc>>bcsitesomole.<<RED,RT)ttGtitTAKEGATA,vouareriott8>>vireotorebcrtunlessycu<<isntodemonstrateyourBlla(biIityfot'"Bt"Bfit"BntIlmi.]tlcnt.O>>ecrcrecollutants,nati5.BnelrIventliitatlonad)lustedbvsvDtractincthe1VBro>>BleretOttheDOIIC-'Snr(5)CreSBntInyourltltake<<atBr..CCES>>BCulatiCnSallcurett(rtltatlonSCniylnertdln=rc'mstances.-crtrcnstatevcvrhliclbll~tv,repcrthesveraceo(theresultsof3nalvsescnyour-.axe<<Otet',llVour*aT<<'5t,Bdteabe!ereiSB,-eST-<<e<<ater1!terit5treated).andaTtaCh3Separate)>>Betcn-55:c8~'t',<<a>>rrBs>>.-Oltto<<~~ill53-h<<nt<<3't8'a<<Q<<ot<<>>is>>rolenr>>~B>>cvTro<<eri'i.BBtsc'lat'cels]CQh>><<5>>v<<h8~*r8'ri1'rr>>of-.8<<x-hnt--rI-.r--h'>>vhi-i~<<8-clito-5sreavcecvtreat-ehtofvcvr<<aste<<ater.ns<<i8acjvsteaonlv-=TheBxrent<<<<at-<<8CotIvtdn+'5totre<ovea.)IiCobleirB>rrtole~<<henneOlIvtantrebrBSents3Classcf~ccunCS)~3CemorStratlcroftheBvte<<t-<<<<rICn-<<eDollutantslnThe)t<<>>dtteve>>V>><<'/5i>>3IIV,"8<<(cal.V,I'IC)cq:CSIIV<<re8C(lutsr~5Tc>tot"Bc'curcrs"arre.'c>>'t<<ST'1<<s<<:Ž8oc'ustes"v-:-reBxten<<--St5-e!rtaxecoiltan=5varffrantilesischdrceacollvtants.)'ite'<<o>>o<<>>~I~}<<'~5'ri885'5'5(n'c"r8I;.--Or'ti"shmielra1nolv=ecn;v3<<8Cu-ro.'I3rd5:tt~5--8-hs.i-s--e1>>dlvsis'",".tersubstant:allvCBn~.11v.f3IIs.=OvtB>>ve555<<ronBs<<v8B>>>>i--:ncovn"r'.:"8Serera.8Shee-arBC.BCtt>8I".-'-;'-~t-Bn"i.Dl~---"~-"-'c-hr--~',:<<.<<i--8:.-".Is"'3",cvc'c.estare51.'ll~i~,Brit~i'.3.<<tidr~<<nli,cit.<<5 SEEINSTRUCTIONSONREVERSESIDE(UIFALLMPSECTlONIIPERMIT~MI0005827NUMBER~003LITEM6PRIORITYPOLLUTANTSANDADDITIONALINFORMATIONFORSURFACEWATERDISCHARGEONLYTHEFOLLCWINGREQUESTEDItrFO@1ATIQN~e"0~AD[X[ESSED~rSLJIFACEWATrRDISCHARGERS~JZE!MEWUSEDISCHARGERS~PROYIQEExPECTEDvALUEsFORIHECUANTITAT[YEAtrDQUA[.[TAT[YEINFIDIOMREQUESTEDBELOWISTHISFaCILITYAPRIMARY[NDUSTRY?(REFERTOTABLE[APAGE4~[(IFrrQGQTQE)(IFYESGQTQB)B[MD[CATETYPEOFPRIMARYtNDUSTRYASLISTEDINTABLEfAPAGE4+.(CprrftttUEWITHC.)C.OQESTHISOUTFALLDISCHARGECCttfa[NAVYPROCFSSWASTEWATER?(IFtent,GQTOE)([FYES,'QTOD)DIt[DICATEWHICHGC/MSFRACT[CtrsMUSTBETESTEDFCRo(REFERTOTABLEIAPAGE4+1XIIK.FCREACHGC/MsFRACTIONOrECKEDiEACHSPECIFICORGANICTOXICPOLLUTANTwlTHINEACHFRACTIONQgrTBEANALYZEDFOR(SEETABLEI[APAGE42,INADDITICNiALLPR[trARYIttDLrsTRYAPPLICANTSWITHAPRQCKSSWASTEHATKRDISCHARGE~PROVIDEQUANTITATIVEDATAFCREACHTOXICPQLLUfAMTINTABLEII[APar<~$~RECORDALLDATAONFORMSPROVIDED(ITEM7)INTHISBQOKLETI(cQNT[tarEwlTHE-KBELow)XYES'rQSTMELECIPWRYEStrQVOLATILEBASE/MElflRALACIDPESTICIDEEeIFJII(KSLJIFACEWATERDISO[ARGEAPPLICANT(PRIMARYORSECONDARYINDUSTRY)iREGARDLESSOFTHETYPEOFDISCHARGE,KJJQWSORHASREASONTOBELIEVETHATANYPOLLUTANTLlslKDINTABLE[IAANDIVAPAGES~tSDISCHARGEDFRCMANYOU[FAL4THEQUANTITATIVEDATAZssL):BEPRQVIDEDIRECORDAL[.DATAOMFORMSPROVIDED(ITEM7)INTHISBOOKLETsQNOTAPPLICABLE/BELIEVEDABSENTOXPRESENT/DATAIsATfACHED*F.IFAIYSLJIFACEWATERDISCHARGEAPPLICANT(FR[JURYORSECONDARYINDUSTRY)iREGARDLESSOFTYPKOFDISC5LRGErKMWSORHASREASONTOBELIEVEAMYPOLLIJTANTSLISTEDINTABLEVAPAGE4QAREDISCHARGEDFRCMANYOUTFALLTIEAPPLICANT~DESCRIBEREASONSFORTHEPOLLUTANTBE[%PRESENTANDPROVIDEANYAVAILABLEQUANTITATIVEDATAIRECORDALLDATAONFONSPROVIDED(ITEM7)INTHISBQOKLKTsX%TAPPL[cABLE/BEL[EYEDABSENTPRESENT/DATAIsATTACHEDG>>ALLSU[FACEHATERDISCHARGKAPPLICAMTS(PRIMrjRYANDSECONDrUIYINDUSTRIES)EscRMAM[f'Act[REs2,4,5-TR[oL[x[QPHExxYacKT[cac[D(2.4,5-T);-(),4,gfR[cHLDRQPHEMQxYIPROPAMIN[cac[D(sl[.YEx,2,4,5,TP)~DIME(HYLRID,MoexoPHEMYL)P~IH[oaq(RQta~FJ'(94.XYIETHYL2-DtoaJXIQPROP[Ct[ATK(J0,TRICHAXIOPtetQL(TCP)JORHEXAOEGROPHE%(HCPJ(ALLDATAFORTHEABOVEPJJSTBEGEJJERATKD,US[%STAICARDANALYTICALCALIBRATIONPRQCGXRES)ORKXltsORHASREASONTOBELIEVETHATTCDDISORMAYBEPRESENTIMTHEIRDISCHARGEIrrLF[IREPORTrXJALITATIVKDafarGEJERATKDWHIC[tUSEDASCREEN[%PROCGXRE%TQK[BRATKD'WITHANAIYTICALSTANDARDSFOR2i5rI8iTETRACHLDRODIBENZQPDIOXIN(TCDD)eRECORDALLDATAONFORMSPROVIDED(ITEMl)INTHISBQOXLETa~IIFTIESURFACEWATERDISCHARGEAPPLICANTKtowsORHASREASONTOBELIEVEtHATBIOLOGICAITOXtCITYTESTSWKREMADEIN1HELASTTHREE(5)YEARSONANYOFTIEAPPLICANTSDISCHARGESCRONARECEIV[%WATERINRELATIONTDADISO[ARGEiPROVIDE[HIS[NFORMAT[CNASAMATTAOFlENTTO1HISAPPLICATIOM>>K.[FACCMIRACTLABORATORYORCONSULTINGFIRMPERFORMEDANYOFTJEAMLAYSESREQUIREDBYTHISAPPLICATIONSPROVIDETHEMJtrEANDADCRESSOFEAOILABORATORYORFIRMAN)THEANALYSESPERFCO%DASANATTACH%MTCFTHISAPPLICATION.LDOYQUDISOLLRGKAMYOTICTOXICORINJURIQIJSOfPIICALSLBSTANCESNQTLISTEDINTABLESIVPAGEttAteI[ATHIOLAIVAPAf<s~<~[4YES,THENIDEttf[0YTIEOrEMICALSUBSTANCESANDESTIMATETHEFttlALEFFLUENTCCttCEMIRATICNS~SLKYIITTHISti&QRMATICNASANATTAOMEMTTOTHISAPPLICATIONSXNQTAPPL[caBLE/BEL[EYKDABSENTPRESENT/DATAISATTAOK)NQTAPPLICABLEAPP[.[CABLE/SEEAlTACHED0%.~PL[~QAPPLICABLE/SEEATTACHEDtOTAPPLICABLEQAPPLICABLE/SEEATTACHED*WaterdischargedforDe-IcingisthesameasOutfalls001and002.IndianaMichiganPowerrequestspermissiontousethescreeningdataforOutfall001and002tocharacterizethisdischarge.37 SEEINSTRUCTIONSONREVERSESIDESECTIONIINUMBER~MI00058278IIFALLINKR~00ITEM7CRITICALMATERIALS'OXICPOLLUTANTSAeUSETHISGATASHEETToRECORDINFORMATIONASREDJIREDIN:(CHECKAPPROPRIATEBOXRJRWHICHIMFC@1ATIONTHISCATASHEETRKPRESF2tTse)oSECTIONII,ITENIEeGROLIGJWATERDISOIARGEINFQJTUlTION(PAGf.59CIX2SECTIONIteITDI6ePRIORITYPOLLUTANTSINSlRPACEWATERDISCHAIY)E(PAGE'7)0X3,B.BElow:CRITIQAL.ATKRIALS(TABLEtv)IMsvRFACEwaTERDts(HARGK(PAGE39)HAZARDOUSSUBSTANCESINDISCHARGEB~LlsTAhYcRITlcALMATERIAL(TABLElvPAGE6)NQTADDREssEDIMsEQTIGNIIITKHRPRIQRITYPOLLUTANTSwHICHYCVKNowORHAVEREASONT>BELIEVEToBEPRESENTIMTIEDISCHARGE.SEEREVERSESIDEOFTHISPAGEfORFURRDIRECTtals~NOTAPPI.ICABLEXAPPLICABLE(SEEBEUJW)*AeNAJefOFCRITICALMATERIALORPRICRITYPOLL%ANTBeAVERAGECCNCEMIRATIONJSAMPLETYPEJtICFAu0LYSKSc..Axl~caJCKMTRATIQNAJDHassIPJITCODESatlPLETYPEOFANAIYSESWITCODEUNITCODELJillCeJAeJJJJeEOfCRITICALMATERIALORPRIORITYPOLLUTANTB.AVERAGECaJCEMTRATICNJSA'usafTYPEJstOFANALYSESUNITCQGESJETYPEOFANALYSESUNITSCODE1Mg/I2Ug/I3LBS/DAY4KG/DAYAMPLETYPE1GRAB224HR.COMP.c.HaxtnflcaJCKMIRATtoNeoMassAeJJAHEOFCRITICALJIATERIALCRPRICRITYPOLLlTANTB,AVERAGECQNQEMTRATIONJSAPLETYPEJIOFANALYSESCeHAXIJ4PICaCEMIRATICNA%MASSAeW%GFCRITICALHATKRIALORPRIORITYPOLIJJTANTB~AVERAGECOJJQEIITRATlotlJSWPLETYPEJteOFANALYSESc.Haxtt1plcowcKMIRATtatAJ4)FASSAJAPEQFCRITICALHATERIALCRPRIORITYPOLLUTANTB.AYERAGECCNCDITRATION;SatuufTYPE;JJ0FANALYSEsCePAXIPIJICaJCEMIRATIattuDMASSAe,'A"ECFCRITICALHATERIALCRPCIIQRITYPOLLUTANTB~AVERAGECCNCEMTRATIONJSAMPLETYPEJPeOFtuIALYSESC~eVUIINH'CONCEMIRATIONAJDMASSAeNA%OFCRITICALMATERIALORPRIORllYPOLLUTANTUNITCODElNITCQGELJUNITCODESJVePLKTYPEOFANALYSESWITCODEWITQXELJ~~~LJWITCOOK~LKTYPEOFANALYSESLJWITCODEWITCODEWITCODESAWLETYPEfOFANALYSESLJLJNITCODENITCODELJ~~~LJUNITCODEStuPLETltPEOFANALYSESLJUNITCCDENtiCODELJ~~~LeuJJB.AVERAGECmreetaTICN;SAHPLKTYPE:A'FANALYSESICeMAXIM'aCKMIRATIONANDIVESlhlITCODESAMPLETYPEJJOFANALYSESLJWITCODEWITCODEa.NAMEOFCRITICALMATERIALoRPRIORITYPOLLUTANTIBeAVERAGECaJCEMIIIATIOMJSAMPLETYPEJIICFANALYSESCe~AXIHUlCONCENTRATIONAJ4JMASSUNITCXESA~TYPEOFA'IALYSESLJlJNITCODENITCQQKLJ*SEENOTEONPAGE37,OUTFALL003.ADDITIONALPAGESQFTHISITKH7AREATTACHEDFQRT%RESTQFTHECRITICALC3YESMATERIALSatft/CRPRIORITYPOLLUTANTSREQUIREDToBEREPORTED,ElNO SEEINONREVSTRUCTIONSERSESIDESECTIONIIPERMITTEMAeIDCATIONOFDISCHARGE~00A~SWs,~NW4,6ECIIWI)~06,IM~0666PAI06III-IDISCHARGELOCATIONSCHEDULEDeIFYESsLISTDISCHARGEPERIODSNABstIA%DFREcEIvttgHATER(IE~GRGUIDIATERoRt'ai%oFsUIFAcEwACsDOYOUDISCHUIGESEASONAILY~(IFNOsCONTItAIETOE)LAKEMIMO./DAVYESXNOn./DAVFLOWRATEWASTEWATEREeLANAPPLICATIONRATEHRs/DAYIN,/wK~.u~.'mEINrIINIHRs~~~WASTEIIATERlYPECCCEL~JLJLJLJLJLJ1CONTACTCOOLING2NONCONTACTCOOLING3-PROCESS4SANITARY5STORMWATER~NITgg1MGY2MGD-3GPDFslYPEOFWASTEHATERDISCHARGEGeDISOIARGESO%DULE(YEARLYAVBUGE)HXNS/DAY~24essesess~36HeDISOQRGEFLlAIRATE'OTALYEARLYDAILYMINIONDAILYMAXINII121.54gwipcoDE0~20.333'2leIHEMAXIISNDISCHARGEFUtitRATETOBEAUIHORIZEDINPEfBITe1WIT=CODEJ.PAXIPLHDESIGNDISCHARGEFLOIRATEeA>>IXIYOUUSEHATERTREAlHENTADDITIVESTOTREATYNRDISCHARGE?(IFNOCONTIIAKTOITBI5)WIT2COPEDESIGNYESlTEM2BeNA%FWCTICNsANDCHEMICALCPRSITIONOFTAESEAITIITIVESeWATERTREATMENTADDITIVESCeNAHEAMIACOIESSOFMAIAS'ACTINERSOF7%SEADOITIVESsNAUNITSCODE1MQ/I2UQ/INAD.EXPECTEDDISCHARGECOICENIRATICNOFACOITIVES.NAACOITIVENA%ANITIVENA%ADDITIVENA%E~COYOUTREAT1%DISCHARGETORENIVEAIXIITIVES?NAUNITSAVERAGECODEYESWITSMAXlttNWITSCODECODEFe~TISlHERBSVALEFFICIENCYAIIDDISCHARGEFREQUENCY?ACOITIVENA%AEOITIVEN6%ACOITIVEtiVELREIOVALHIS./DAYDAYS/WKeLJLJLJGeASANAITACHIENTTOTHISAPPLICATIONPROVIDESPECIFIC/%1%.IANCRAOUATICTOXICOUIGICALDATACRREFERENCEWHIOIAREAVAILABLEANDINFORUITIONCNTHERATEOFDEGRADATICNOFT%PRODUCTSFOREACHAISITIVENA31 SEEINSTRUCTIONSONREVERSESIDESECTIONIIPERMIT~MI0005827NUMBERIITEMPROCESSSTREAMSCONTRIBUTINGTOOUTFALLDISCHARGEPOUNDS2GALLONS3CUBICYARDS4TONS5MGY6MGD7GPDI/2IUOr00Ih6/2IAIOcvtOA.IUPEOFPROCESSIXXIIRIBUTIIIGTOTHEDISCHARGE'ESITHISOUTFALL~DSICCODEBePROCESSSCHEDILE(YEARLYAVERAGE)C~PROCESSWASTEIIATERFLOWRATEBasis:1993actualdatasubmittedonDMRsDePROCESSPRODUCTIOttRATENAC.PROCESSWASTEWATERFLOWRATEDePROCESSPRODUCTIONRATEA.tIAtEOFPROCESSCCIIIRIBUTItaTOTHEDISCHARGETHOROUGHTHISOUTFALLAlQSICCODEBePROCESSSQEIXAE(YEARLYAVERAGE)C.PROCESSHLSTEWATERFIDWRATEAeNAEOFPROCESSCONTRIBUTltJGTOTIEDISOIARGENATHOUGHTHISOUTFALLA'8SICCODEBePROCESS~(YEARLYAVERAGE)TOTALYEARLYDAILYMININGDAlLYMAXI'0LTIITSZTI"ELJsaws/svv~seve/vsaTOTALYEARLYDAILYMININHDAILYtQXWtIears/ssv~seve/aaTOTALYEARLYDAILYMINI@MDAILYMAXI'~OOAU,lBLOWBOW,Ni~4>911IOIIS/DAY~24y~36236117wlT5LoTIME1HOUR2DAY3WEEK4MONTH5YEARI/IthOWIO0DPROCESSPRODUCTIONRATEA.NAMEOFPROCESSCONTRIBUTINGTOTHEDISCHARGENATHAISSICCODEB~PROCESSSCHEIXLE(YEARI.YAVERAGE)C>>PROCESSWASTEWATERFI.OWRATEDePROCESSPRODUCTIOttRATEAeHASEOFPROCESSCONIRIBUTINGTOIIEDISCHARGETHOROUGHTHISOUTFALLA'IDSICCCOENABePROCESSSCHGXLE(YEARLYAVERAGE)CePROCESSHASTEIIATERFLOWRATEDePROCESSPRODUCTIONRATEeases/sev~seve/vasTOTALYEARLYCAILYMINIFYDAILYMAXI'svs/vasTOTALYEARLYDAILYMININIIDAILYM/Nit%PIUNITSCTIMEUIITCODEWITSCTIMEWITS/TIME33 "STRTI2;.'5sSR"<<"DELETINGSEGTICNIIITEI-1SIAi<O2"iscrmrecuires'-<crationcntne!ac!<(tv'sclscnarce~coat(en,lscnarceso<ecule,vol.<<eflowrareand<<atertreatrent=":ITFRTHEP"@ITNbuBERI:ITHEBOXATTHETPGF<HISFGfr<.THEpERMIT)AetBERCA%BEFCUNOrtlTHEFRONTPAGEGFYOUREXPIRING"'nls'ssne<<ornct:revlousiv"er-ifecfscil'tv,"enleave.lankencanuper<<~Iibeasslcned.E",-e<-necut!allr(macrlnspaceprovided!creachcagec!sectionII.roreachIndividualclscnarcepoint3separatesetofformS.Ste'(liedOut.'TE'AIVATIC'I,=.nE'vJLE<I<<)LOWP>TESEnterthelccaticnofdischarge,thissnoulcinclucecuarter-cuartersection,cuartersect)nn,sec(ion.town.andrange.3.u)StnameOfreCelVlnc<<ate<<(ifSurfaCe<<aterd(SCna.oe)G.InCioatewnether!cellltydlscharceScnaSeaScnalbasis.Ifyes~Iistdlscnargeperiods.providethelaneapplicationratesusedorexcectedtobeusedintermsofinc),esperI,our,nourspe<cav,andinchespe<week.F.Indicatethetypeofwastewatertopedischargedfromthisoutfall.=afarto~hewastewatertvaecodedivanIntheleftrgin.)<orethanOneCodemaybeapplicaple.ProvidetheaveracenumberofhoursperdayInwnlchthefacllltvdlscnargestreatedwastewaterandthetotalnumpe<ofdaysperyearInwnlchhecischarceoccurs.urovicecurrent(!romtnelastl2mcnths)orexpectedflowratesasrecuested.Refertounitcodeoivenlntheleftmarginfortheappropriateflowunits.'GY-mllllcncalicnsperyear;'4lO-.Illlcngallonspercay;GPO-gallonspercay.provideherax)~umdischargeflowrate<<nlcnvou<<ant.ohaveauthorizedwithinthepermit.';0TE:ucrN>Espermitsonly,.heuseofsucha!Iowratewillnotplaceanactuallimitrestrlc.lonontheflowbutwillbetneflowrateusedtodevelopeffluentlimits.Also,<<nentheI'onthlyOperatingReportsarerevieweCbvCompliancestaffitwillhelpthemtodetermine(fanyneworIncreasedusesmlchthaveoccurredatthefacility'.!.Providethedesign'lowforthisspeci!leotfaildlscharce(e.g.oatentreatmentsystemflow,packaoedtreatmentsystemflow,orsomeotherfinitetreatmentsystemflow).ITEMi2'xATERTREATF1ENTAOOITIYES'ndicatewnetner;ischa<ge<streatec<<Ith:cndltloners.Inntb)ters,crnicrcpfocICe.1'ct,contirue<<oitem3.B.Givename,functlcn,andchemicalccmposltlcnofacditivesused.lvename5ndascasso.'",emanutac';<<"',S)O<-"e<<<<<<!ITS.Sed.'"cicateexpected<<inl<,.<m.averaaesncmaxi~urnClscharceCnCent<<atlonso!tneadditive(s)'cr-nlsclscnarce.'"cicatewnetner,ctreattneolscna<cetr~vetheace(.Ive(s<"e!creciscnarneof<<astewate<.'<dicate<<her6OVSIef!IcienCVC.eaohaCCit!Ve<rcmthe<<aStewater'SndtheCISCharae!reCuenCyOfeaCnaddltiVetOthe)urface<<atercr..dune<<ate<.'.")E:IIstnerespcnslbll(tyo'.theapplicanttosupplytheproductinformationasrecuestedInthisIten4.infer<rationreauestedbutroSuaaliedmayreSV)tintheapplioatlonheinereturneetotheapplicant'c<completlcn.
SEEINSTRUCTIONSONREVERSESIDESECTIONIIt4UMBER~M20005827PERMIT~00ATEM4GROUNDWATERDISCHARGEINFORMATIONISTHEDISCHARGEFRCMTHISOUTFALLDIRECjEDToTHEGRIXÃIDORGROUNDtATERS7I!FtoCCtttlt2UEToITEM))BaWASAHYDROGEOLOGICALSTUDYCRITSEQUIVALENTBEENPERRRKDORlsTHERESIFFICIENTcURRENTHYDROGEQCQGIcaLItFQIY4ATICNAYAllaBLEAsREQUIREDBYTl6'wATERREsoURcEsCotMISSIOttPARTZZGRQViDWATERRULESOFAUIUSTltt>lcMR.>23.ZZ()7(PAGEGQ)FORTHISEXISTMORPROPOSEDDISCHARGEZIFYESATTACHACOPYOF1HEREPCRTeCIAREYQUREQUESTlt6attEXEt'PTIC;<FRCMSUBMITTINGAHYDROGEOLOGICALREPORTUttDERRIXER323,@It(l0)(PAGELa)QRFRQMGRoutcwatERMQNITCRINGIIEQUpEMENtsUtlDERRULER.Z5IZ4UI(5)(PAGEII/)OFTHEPARTZZRULES>>IFYESATTACHDOCUMENTSANDEXPI/UtattottTODEISNSTRAIETHATYORDISCHARGEWQLADQUALIFYFORANEXEPPION.DIAREYQUREQUEsTING4vaRIattcEFRQMRULE32312205(PAGEQ(tQNDEGRADATIctt)0FTHEwATERREsculcEscotttlsstetPARTZZGRolfcwATERRIAEBTIFYEsiATTAcHsUcHDQIXPtENTSASNECESSARYTODEMOttsTRAIEWcNEEDFCRAVARIANCElttTERMSCFTtecRITERIAsPEclFIEDINRILE>Z3IZZ10(PAGEtl7)0F1HEPARTZZRULEs~NANANAYES"ESQYESYESNONON)EsI,ISTALLCHEttICAL$%stattCESWHICHAREINMICHIGANSCRITICALMATERIALSREGISlERTAB!EIVlPAGED)AND/QRViseEPAsPRICRITYPQILUTANTLlsTTABLEv(PAGE7)0RANYGTHERsUBsTANcEswlcHAREoRHavBEcctEINJURIOUStoTIEDESIGNATEDUSEsOFTIEcArwowtERoRTOTHEPUILICHEALTHTHATAREDISCH4RGEDQREXPECTEDToBEDISCHARGEDToTHEGROUIDWATERAY1HISFACILITY,ESTIMATETHEFINALEFFLUENI'ONCENIRATIONattDRECORDAILDATAINITEM/OFSECTta<<tINTHISBCOasr.TIEAPPLICANTMAYBEREQUIREDToDOADDITIONALWASTEANALYSES.QNQTAPPLICABLE/BELIEVEDABSENTNAPRESENTiDATAPROVIDEDINITEM7ITEM5EXPECTEDWASTEWATERCHARAC"TERISTICSUNiTSCODE1Mg/I2Ug/I3COUNTS/100ml4S.U.5'F6LBS/DAYAIDISCHARGECHARACTERISTICSPtSNIANITROGEN(AsN)TOTALSUSPENDEDSOLIDStotaLptY)SFHQRUS(asp)TOTALRESIDUALCtLCRINEDISSOLVEDOXYGENMIN~.LJFECALCOLIFORMBACTERIATEKERATlRE(SIJY4ER)TEtfiERATURE(WINTER)BO05(FIVEDAYBIOCHEMICALOXYGENDB'AND)cQD(CHEMICALQXYGEttDerVD)TOC(TOTALORGANICCARBON)CottCENTRATICttBIOTHERWASTEWATERCHARAC'STICSMax4~LJutttSCODE4ANALYSESSA~TYPECODEu1ul~3~5~5SAMPLEZXBF1GRAB224HOURCOMPOSITC0ILBGREasELJLJ~LJLJ~LJLJ~LJ'J~LJSEEATTACHEDSHEETSFORANALYSISDATAREQUIREDINFOIY4ATICNFQRSURFACEWATERDISCHARGEss*Basis:1993actualdatasubmittedonDMRS
'-.--Sc.res'~'c~atlcncntnecrccess3-"easniceocrtclouse-"-~'.3tlscbar"8..TE=E-=='-""".UBERINTPEBCXAT'-'="f-IE.CR4.--=cEo!IIT'"trABEOCI'IBECCUI'0C;ITPEfRQNTOSGECFYCUIIEXPIRING--"S'S3"eWCr-3-:reVIC.S<~38~"-~r'~"IlitV.-renleaVe"landand3numberrillbeOSSICnec.E";er;.-Is~~-.-er'"3"ace-.Cvicec':esc-.338crEecticn<I.=OreccnIncivIduaiciscnarcepoint3seoara.esetcfITE'Alr'ngfotj~~'r~rE"-er-8"a~"'",eOrOCeSS<<nlcnConrlautea-O,.hiSOISCnarae.~ISOCrOVide3"eOroberSICCOCencica-8--evearlvsveracecrccessscrecuie'""ourscercavanodays-cer-veer.?rovldetneorOCCSSwaStewaterficwrateinformatiOnaSrequeSteobasedonyourlast12monthsofooerations.Referto.nitcodegivenintheleftmaroinfortneaooropriateflowunits.=.OcessorcductlonRate-.ertain"armis'Imltatlcnsmavbebasedcnorcductlcnrates.heoroduct'Icnratesusedtotate~>.8cermltI'~I~Ssailberecresen-ecbv3reasonablemeasureofsctua<crocuct:noftbefeellltv,suchastle,irr'nn>retiousiear,.8rCOtnlV3'eraCe~ne.Ines~C8SVICOSiV8yearS~CrI;ner8sonableassureasstated'3scoiicble'E.E.P.A.Catecorlcalr'essnoreou>a-,lens.=cr~ewSurCeSornewOIscnarcers,actualcrcouctionsnailbeestimatedvSIngorojectec=rcduCticn.uc.I1rates1~"8er<s3nounitsusedintheabolicaoleu5~~.A~ateoolicalrulesandreculationsfor SEEINSTRUCTIONSONREVERSESIDE(NFNl.IVERSECTiawIIPERMIT~MIpppg827NUMBER~00AITEM6PRIORITYPOLLUTANTSANDADDITIONALINFORMATIONFORSURFACEWATERDISCHARGEONLYTHEFOLLOWINGREQUESTEDlt>>FC{V{ATIGlt~e">0eAXRESSED~A>>eNFACE'ATERDISCHARGERS~RHEIt>>EWUSEDISCHARGERS~s>>PROVIDE~eECTEDVALUESFORTtECUAVflTATIVEANDQUALITATIVEINFORMATIGNREQUESTFDBELCH>>A>>ISTHISFACILITYAPRltARYItt{XSTF(.(REFERTOTABLEIAPAGE+{IFNO>>GOTOE)(IFVES>>GOTOB)B~IhDICATETYPEGFPRIMARYltOUSTRVASLISTEDINTABLEIAPAGE<>~(CQttftttUEWITHC.)C.DOESTHISOUTFALLDISQ{ARGECCtffAINAr{YPROCESSWASTB{ATER.(IFNO>>GOTOE)(IFVES>>GOTOD)D>>INDICATEWHICHGC/r'SFRACTIQr{S>>MUSTBETESTEDFOR~(REFERTOTABLEIAPA">>E~tIIQIEIFCREACHGC/MSFRACTIONCHECKED>>EACHSPECIFICORGANICTOXICPOLLUTANTWllHINEAGHFRAGTINtQADIBEAt{ALYEMFGR(sEETABLEIIAPAGEtt2.It(ADDITION,ALLPRIMARYIt>>DUSTRVAPPLICANTSWITHAPROCESSWASTEWATERDISCHARGE~PROVIDEQUANTITATIVEDATAFOREACHTOXICPOLLUTANTIttTABLEIIIAPAGE.RECORDALLDATAOMFORMSPROVIDED(ITEM7)INTHISBOOKLET.(CONTINUEWITHEKBELCH)VEStOSTMEILECPWRXYEStOV{XATILEBASE/NEUTRALACIDPESTICIDE*EDIF~SLIPPAGEWATERDISCHARGEAPPLICANT(PRIMARYORSECCr{DARYit{DUSTRY)>>REGARDLESSOFTHElYPEOFDISCHARGE>>KIKWSCRt>>ASREASONTOBELIEVETHATAttfPOLLVfAMTLISTEDINTABLEIIAANDIVAPAGES~ISDISCHARGEDFRCMANYOUTFALL>>THEQUANTITATIVEDATABEPROVIDEDRECORDALLDATAONFORMSPROVIDED(ITS>>t7)INTHISBOOKLET>>>>tOTAPPLICABLE/BELIEVEDABSENTOXPRESENT/DATAISATTACHEDF~IFANYSURFACEWATERDISCHARGEAPPLICANT(PRIMARYORSECONDARYINDUSTRY)>>REGARDLESSOFTYPEOFDISCSUIGE>>KIOWSORHASREASONTOBELIEVEANYPOLLUTANTSLISTEDIttTABLEVAPAGE{I>>>>AREDISCHARGEDFRQ{ANYCUTFALLTHEAPPLICAVTVII'ESCRIBEREASONSFORTHEPOLLUTANTBEINGPRESEttfAt{DPROVIDEANYAVAILABLEQUANTITATIVEDATA>>RECORDAILDATAGNFGIV{SPROVIDED(ITEM7)INTHISBOOK!ET>>XtOTAPPLICABLE/BELIEVEDABSENTPRESEMT/DATAISATTAQ{EDG.AILS{IIFACEWATERDISCHARGEAPPLICANTS(PRIMARYAttDSECONDARYINDUSTRIES)E)CRMANIA-ACTNES2.4i)-TRIQKDRGPHEIOXVACEftgACID(2.4i5-T)l-I),.5-)AtO4>>5TRICHLGROPHEIOXVPROPANOICACtD(SILVEX2>>4>>5>>TP)'Z.4.>IRIQ{LGRGPHEtOXV)ETHYL2,2-DICHLGRGPRGPIGMATE(ERBGMt;0,4NTRICHOROPHE{OL(TCP)>>ORHEXAQl.OROPHENE(HCP)t(AILDATAFORTHEABOVEt>>USTBEGEhERATEDUSINGSTANDARDAt{ALYTICALCALIBRATIONPROCHXRES)ORKIOWSCRHASREASONTOBELIEVETHATTCDDISCRMAYBEPRESENTINTHEIRDISCHARGE>>~REPORT9IALITATIVEDATA,GEIERATEDWHICttUSEDASCREENltOPROCHXREtOTCALIBRATEDWITHAVALYTICALSTAt{DARDS>>FGR2.>>>/8>>TETRACHLORODIBENZOPDIOXIN(TCDD)>>RECGRDALLDATAONFORMSPROVIDED(ITEM))IMTHISBOOKLET>>J~IFTHESURFACEWATERDISCHARGEAPPLICAMfKtOWSCRHASREASONTOBELIEVElHATBIOLOGICAITOXtCITYTESTSwHIEvADEINTHELASTTWEE(5)YEARSOMANYOFTHEAPPLtCArlTSDISCHARGESORCNARECEIVINSWATERINREIATINtTOADISCHARGE.PROVIDETHISINFORMATIONASAVA1TAQI{EMTTOTHISAPPLICATION>>KIFACONTRACTLABORATORYORCCrtSULTINGFIRMPERFCRMEDAth'FTHEAIN{YSESREQUIREDBYTHISAPPLICATION,PROVIDETHENAMEANDADDRESSOFEACHLABORATCRYORFIRMANDTHEANALYSESPERP'"HtASAVATTACHMENTOFTHISAPPI.ICATtON>>'L.DOYOUDISCHARGEANOTHERTOXICORINJ(PIOUSCHEMICALS{8STANCEStOTLISTEDINTABLESIVPAGE(IAl>>DIIATHROU4lVAPAGESV~A+>>cYES>>THENIDENTICHEMICALSUBSTANCESA'OESTIMATETHEFtt{ALEFFLUEttfCCtKENTRATICr{S.SUIT{ITTHISIhFORMATIONASAVATTAQteENTTOTHISAPPLICATIGN>>NOTAPPLICABLE/BELIEVEDABSENTPRESH{f/DATAtSATfACHEDNOTAPPLICABLEAPPLICABLE/SErAlTACHEDNOTAPPLICABLEXAPPLICABLE/SEEAlTACHEDXtOTAPPLICABLEAPPLICABLE/SEEATTACHED*Pesticidedataisnotrequired;however,itisprovided.37 IIISTROCTIONS.OoCCfJPLETI'/3SECTIC!IIIITEMS4ANOS.hisformreculresInforrationonaspeci!iccut!alllscnarglngtoeither,hegrouncwatersorThesurfacewaTBrs.rENTERTHEPozz(TNLSIBERINTHEBOXATTHETWCFTHISFCRM.THEPEIB(ITNONBERCANBEFOUNDOiTHEFRONTPAGEOFYCOREXPIR(tfgCERuli~:.',~5(S(SarewOrnOtpreV(cuS(VpermittedfaCII(ty,ThenleaVeblankandanumberWillbeBSSICred.nter-Bcu~fa(IumberInThespaceprovidedfcrebenpaceofSectionII.Foreacnindividualdlscharcepointaseparateset"'n-T!Bn!','"rms(Items'nc)must=efilledout.ITE)l4SBDJ;.WA==DISCHARGEINFCiJAT(CN(00N"TiNCLCCEDEEPWFL(.I"JECTIONINFC"NATIONI'ITHISITEvl)A.-D.heapplicantshalladdresseachofthesepartslftheclscnarcefromthisoutfallistotheoroundwater.ITEM5<ISTI"GCREXPCTED~FORANEWO(SCHARGE)<<ASTFWATERCHAoACTERISTICSCFSRv'4)WATERORSI'RFACEWATEoDISCHARGE(DO"OT'NCLUDEhcLLINJ3ICNINRNAI'IINHrVITheapplicantshallreportavailabledischargedata(realdataAorexistingdischargeorexpecteddataforaprcposedd(scharge)fcrtheparametersaslisted.Theseparametersshallbeaddressedforeitherasurtace~aterdischargeorasappropriateforagroundwaterdlscrarge.Forassistanceindetermlnlnoabproorlatepar~tersaorcundwaterdlscharceapplicantmaycontactthe<<ArouncwaterDual(tvolvlslcn,permitssectionortneappropriateGrouncwaterDualityoiv(s(on'sDistrictoffice.Theapplicantshallreportthesama(eTypecodebestdescribingeachreportedpieceofdata.Seecodingontheleftmarginofthisform.IfThisoutfal(lsasurfacewaterciscnarce.tneapplicantmustrepor-ouantitativedataforeachparameterIdentifiedbvanasterisk.,heappicantmay,however,recuestThat-nereportnco,cata<<orcneormoreo~hesereouiredoarai.etersbe<<aivec.Suchrecuestmustbesupportedbyacecuato<<atlcnale.i'akesucharecuestanattachment.othisapplication.'I'ataisavailabkefcretherparametersnotIisTBdabovB(nA.oretherpartsotthisapplicationtheapplicantshouldreporthatcatalnTheblankspacesprovldea:nthispart.I"OTES:I.OnttcodesforparametersreportedInpartsAand8canbefoundontheletthandsideofthIsform.GrabsamolesnailbeusedTcanalyzetorpH,Temperature,totalohenols,residualchlorine,oilandgrease,andfecalcol)formInasurfacewaterdischargeunlessotherfrecuencv-sampletypeanalysesareavailable.SeeGlossary(pace48)fordefinitionofgrabsample.24-hour~pcs(tesamplesshallbousedtoanalvzeforTotalBMs,CCO,TOC,Armon(aIlltrcgen,andTotalSuspendedSO(iCSin4SurfaCewaterCisCnargeun(BSSO~herfreauenoy-SampletypeanalySeSareBVBI(able.SeeGIOSSary(page48)fordefinitionofcompos(tesanole.REPORT(l)GCFINTAKECATA.'5uarenotreruiredToreOCr.unlessyouwishtodemcnStrateyOurellcibllltyfor4"retwsffIentl(mltat(cn'CrOneOrmerePOllutantS,thatIS,aneffluentlimitat(OnadjuStedbySubtraCtlngtheaveragelevelo!thecollutantfs)presentInyourIntakewater.NPOESregulationsallownetI(mltatlonsonlyIncertaincirctmstances.ccnronstraTevourellclbllitv,-eporTtheaveracooftheresui3ofanalvsesonyour3I)r*uii').BB'CBie,B<<.eare<<sfBr'.IST.eated)~\53,sebaratB"BBT"cnt!ningTrefc)lcin@fcrBachoiiutanT:(5)<stateentT"at-"BIntakewater'3drawn'rcmTrecccvofwater.(ntowhichthed(scnarqeIs~ace.('.Therlse,'ouare-;:ellcible!crneti:m(tat(ons.)ib)>state"ento!eBxront.which.neleveloftne.IfutantisreducedbvTreatmentofycur<<astewater.(Your"Im(tationa<<illpeaajuStecOnlyTCTheeXTentTeatthepCI(utant3SnctremOVed~)<<'C)ahenacplicao)e(tcrexample,<<hen.nepollutantrepresentsaclassofcompounds),ademcnStrat(cnofthe<xtent<<o.<<wlc"~ii<<tc(33tantsine(~~ekeveryp";3'caiIv,chemicallv,'biological(v'romT"epc(lutantscontainedInvourclscrarge.(Your(in(tat)cna<<IllbeadjustedonlyTOtheextentThattneintakepollutanTSdonotvaryfromtned(scnargeopollutants.)vcunavet'<<oor-crei.stantiallyLcantle<<'utfs~fs,,cumavrecuestcer..isslonfrompeurper-,ittinc5urnoritvTcsa<<aieanoari)!vzeon'v.-.ecut!elIsncsuc.I-"Bresul3oftheanalvslsfcrethersuostantlallyCB'it3C51cut!5(ls.'>>urr<<ciest~3Trente)bv-hepe~i-(noausncrltv,cnaseoaratesheetat-ac"Bdto.the3.""Icatlci.cr<<ifcenT<<(*nilnut'5l'i,.udieest,5.c:ascribewnvneourfails<<Bien.ucid.cTBSTaresusT5nialIVldenticaizo-reouT!allwnlchvouJ(dTes SEEINSTRUCTIONSONREVERSESIDESECTIONIIPERMIT~MI0005827NUMBEREMCRITICALMATERIALSTOXICPOLLUTANTSA.USETHISDATASHEETTORECCRDIt(FORMATIONASREOUIREDIN:(CHEQ(APPROPRIATEBOXFORWHICHItiFORMATICNTHISDATASHEETREPRESEIITS)1eSECTIONIIPITEM4EeGROWDWATERDISCHARGEltIFCNATION(PAGE55)2.SECTIONIIPITEM6.PRIORITYPOLlJITANTSIttSURFACEWATERDISCHARIZ(PAGE37)OX3eB.BEIDW:CRITICALYATERIALS(TABLEIV)INSURFACEWATBIDISOIARGE(PAGE2)HAZARDOUSSUBSTANCESINDISCHARGEBeLISTAttYCRITICALYATERIAL(TABLEIVPAGE6)NOTADDRESSEDItl'SECTIONIIITEMFePRIOIIITYFOLUITAIITSWHICHYOUKNOWORHAVEREASONTOBELIEVETOBEPRESENTItlTIEDISCHARGEPSEEREVERSESIDECFTHISPAGEFORFUItTIFRDIRECTIONS~NOTAPPLICABLEAPPLICABLE(SEEBaDW)AeNAPEOFCRITICALMATERIALORPRIORITYPOLUITANT*Hdra'zinc00302012UNITSCODElMg/I2UQ/ILBS/DAYKG/DAYItLIt~IBsAVERAGECONCENIRATIONISAIPLETYPE;IIOFAIALYSESC>>teAXI.'VICCttCENIRATIONAtaYASSAsePYYEOFCRITICALMATERIALORPRIORITYPOLLUTANTBsAVERAGECONCENTRATION;SAMPLETYPEllIIOFANALYSESCeYAKIF'NCENNIRIATIONAttDMASSAettAIIEOFCRITICALMATERIALORPRICRllYPOLU/TANTBeAVERAGECOICENIRATICNISAMPLElYPEittOFANALYSESCeMAXI'ONCENIRATIONANDMASSAeNAMEOFCRITICALMATERIALCRPRIORITYPOLUITANI'ITCODESAMPLETYPECFANALYSESLJII.LJJJLJLJWITCODEWITCODELJ~~~LJUNITCODESAYPLETYPEOFANALYSES~.LLLJLJWITCODEWITCODELJWITCODESAMPLETYPEOFANALYSESLJWll'ODEWITCODELJ~~~LJ3.AVERAGECOtICENTPATICNPSA"PLETYPEIIIOFAIIALYSESWITCCDE~LETYPELJOFANALYSESCeYAXltulCOtLENTRATIONANDMASS~PMPLYYPlGRAB224HR.COMP.AsNAtEOFCRITICALMATERIALORPRIORITYPOLLllTAttTCeeMAXIYUYICOtlCENIRATIOttAtoYASSAettA'IEOFCRITICALMATERIAI.ORPRICRITYPOLLUTAIIT3~AVERAGECCttCENTRATIONISAMPLETYPEpeeOFANAI.YSESCe"AX!le'COIICENTRATIOIAteYASSB,AVERAGECCIICENIRATIONlSAMPLETYPE;IttOFANALYSESIUNITCODEWITCODELJ~~~LJWITCXESAtPLETYPEIIOFANALYSESLJWITCODEWITCODELJ~~~LJWITCODESVPLETYPEhOFANALYSESLJWITCODEWITCODEAetIAYEOFCRITICALYATERIALCRPRIORllYPOILUTANT3.AVBVGECOttCENIRATICtt;SA~TYPE:ttOFANALYSESILtlITCODESAtPLElYPEOFANALYSESCeYAXIMNCONCENIRATIONANDMASSAetIAYEOFCRITICALMATERIALORPRIORITYPOLUJTAeVTWITCODEWITCODELJ3~AVEPAGEOIWCENIRATIONISAMPLETYPEIIIOFANALYSESCeMAXIYLMCONCENTRATICNAttDMASSWITCCOESAYPLETYPEOFAttALYSESLJWITCODEWITCODELJADDITIONALPAGESOFTHISITEN7AREATTACIEDFORTIERESTOFTHECRITICALC3YESMATERIALSAND/CRPRICRITYPOLLUTANTSRECUIREDTOBEREPORTEDiElNO+HydrazineisnotexpectedtobepresentindischargebutsmallquantitiesmaybefoundinthesteamgeneratorsbutwouldnotbeexpectedtobefoundintheactualdischargeflowtoOutfalls001or002.39
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- qCCIip(.ETIr,SECTic;iI'TEM6hisormrecuiresIniormariononaspecificourfolI
- iscnorql"crothesur!oce<<oters.:"IEcPEpERFIIT'4,'~'J)ERliiTHEBOXATHET&CFHISPCS..fEPEPMIT':WMSERCANEEFOvh0CNTHEFRONTPAGEOFVCvpEXPiRINGoERMIT.'Iroisisonewornotpreviouslypermittedfeellitv,,henleaveplonkanaonuroerwliIbeosslaned.eeu~foiInumberinthespaceprovidedfcreachpageo'ectionII..oreachinaivicuoldlscnorcepoint4separateserSacr!cn:'I.item6formsnusroefilledour.iTEM6opICRIr"cx)ll.UTAH(TSANOACOITICIIAI.I'IFCRMATION'IOTE:A~Ionalfvouhovet<<oarmoresubstanrlollyindenricoiourfoiIs,youmayreavestpermissionfromvourperm(trinaoutnorltytosampleondanalyzeonlyoneoutfallandsubmitrheresultsoftheonoiyslsforothersubstantiallyIdenticalcutfalls.IfyourreauestIsgrantedbyrhepermittingoutnoritv,onaseparatesheetattachedtorheapplicationformIdentify<<hlCnOutfalIycualdteor,OnddeSCrlbewnyti.eOutfallSwnlahyaudidrOtreStOreSWPStantlallyIdenrlaal-OtheOutfall<<nichYouoldrest.40CFRPartI22.2l(g)<8),Friday,AbriII,l983~providesforoSmailBusinessExemoticnfromthereporrlrgofauontitotlveaotafororganictoxicpollutantsondtcxlcpollutantsosreaulredbyport122.2I(g)<T)<il)(A)or122.21(q)(7)<ili)(A).Thesepartsoreself-explanatoryanddonotrequirefurrherInstrucrions.S(molyoohrougheachparranddoosIndicated.SeveralIndustrialcategoriesandsubcategorieshovebeen.exemptedfrcmsubmittingdoraoncertainGC/iusFroctlons(40CFRPart(22,Vol.48,lio.64,Friday,AprilI,l983,IiotesI,2,and3).ReviewthefollowinglisttodeterminewhetheryourfacilityqualifiestobeexemptfromreportlnaGc/Ms(Goschromotoarephy/MossSpectroscopy)Fractions.TextileMIIIsIndustryGCIMSFractionTestingondpeporrlngExempt(cns-AII!ourGC/MSorganicfractionsinrheGreigeMIIIsSubcategory.-PesricldefractionInailothersubporrsofthisIndustry.OreMininaandDressingIndustry-volatile,bose/neutral,ondpesticidefractionsInrheBaseondpreciousMetalssubcategory.-AIIfourGC/MSorqonicfractionsinollothersubcategoriesofthisIndustry.Gumand'WoodChemicalsIndustry-PesticidefractionintheTallOlIRosinSubcategoryandtheRosinBasedDerivativesSubcategory.-Pesticideandbase/neutralfractionsinallothersubcateaoriesofthisIndustry.euloandPaperIndustry-PesticidefractioninPapergradeSulfitesubcateaories(subpartsJandU).-Base/neutralandoesticldefractionsinDeinkSubpartq,OissolvlnaKraftSuboartF,andpaperboardfromWastePaoerSubpartE..volatile,base/neutralspesticideI'rectlonsIntheBGTBleachedKraftSuboartH,Semi-chemicalSubparts8andC.andNonintegrated-FinePapersSubpartR.-Acid,base/neutral,andpesticidefractionsInFineBleachedKraftSuboartI,OissolvinqSulfitePuloSubpartK.Ground-wOOdFinepaperSSubpart0,HarketBleaChedKraftSubpartG~TiSSuefrOm'WaStepaperSubpartT~andNOnintegratedTISSuePapersSubpartS.SteamElectricPowerPlantIndustr-Base/neutralfractionIntheOnce-ThroughCoolingwaterFlyAsh.andBottomAshTransportwaterorocesswastestreams.38 GENERALCHEMISTRYRESULTSClientSampleID:OUTFALLOOA-VI)-SLOWDOWNLALBatchID(s):126im,127im,128imDateCollected:01-26-94Matrix:waterDateReceived:01-28-94P0469095-040-3N'ConstltueritFluorideinmILBromide,inmILNitrite-Nitrate-Nitrogen,inmILSulfateinmILTotalCanide,inmILColorTotalPhenolics,inmILSulfideinrnILSulfite,inmILMethod340.2300.0353.2300.0335.2110.3420.1376.1377.1Result<0.15<0.050<0.050<0.059<0.020<5.0<0.15<1.0<1.0Reporting,,','";.Detection'Umlt'.150.0500.0500.0590.0205.00.151.01.0..-,,;DateQualNer(s)DateAnalzed03-02-9402-17-9402-11-9403-05-9402-07-9401-28-9402-08-9401-29-9401-29-94LALSamlelDL1150-3L1150-12L1150-15L1150-12L1150-18L1160-3L1150-24L1150-9L1160-6Comments:
0 GENERALCHEMISTRYRESULTSClientSampleiD:OUTFALLOOABLOWDOWNLALBatchID(s):126im,127imDateCollected:01-26-94Matrix:waterDateReceived:01-27-94PO¹69095-040-3NConstituentTotalPhosphorus,inm/LAmmonia-Nitrogen,inmILTotalSuspendedSolids,inmILTotalOrganicCarbon,inmILChemicalOxygenDemand,inmILTotalKjeldahlNitrogen,inm/LMethod365.2350.1160.2415.2410.2351.2Result<0.030<0.050<121.8<182.4ReportingDetectionLimit0.0300.050121.0180.10DataQualifieris)DateAnaledLALSamleID02-08-94L1142-802-01-94L1142-802-16-94L1142-401-28-94L1142-403-03-94L1142-80242-94L1142-12Comments:
METALSRESULTSClientSampleID:OUTFALLOOA-U/I-BLOWDOWNLALBatchID(s):126imDateCollected:01-26-94DateReceived:01-26-94Matrix:waterPO469095-040-3NConstituentsMethodConcentrationlmIL)ReportingDetectionUmltImIL)DataQualif)eris)DateAnalzedLALSamleIDAluminumAntimonArsenicBariumBeiliumBoronCadmiumChromiumCobaltCoerIronLeadManesiumMananeseMercurMolbdenumNickelPhoshorusSeleniumSilverStrontiumThalliumTinTitaniumUraniumVanadiumZinc60106010706060106010601060106010601060106010742160106010747060106010601077406010'.6010784160106010602060106010<0.20<0.060<0.010<0.20<0.005<0.005<0.010<0.050<0.025<0.10<0.003<5.0<0.015<0.0002<0.067<0.040<0.050<0.005~<0.010<0.10<0.010<0.20<0.10<0.001<0.050<0.0200.200.0600.0100.200.0050.200.0050.0100.0500.0250.100.0035.00.0150.00020.0670.0400.0500.0050.0100.100.0100.200.100.0010.0500.02002-22-94L1150-5202-22-94L1150-5202-20-94L1150-5202-22-94L1150-5202-22-94L1150-5202-22-94L1150-5202-22-94L1150-5202-22-94L1150-5202-22-94L1150-5202-22-94L1150-5202-22-94L1150-5202-23-94L1150-5202-22-94L1150-5202-22-94L1150-5202-09-94L1150-5202-22-94L1150-5202-22-94L1150-5202-22-94L1150-5202-25-94L1150-5202-22-94L1150-5202-22-94L1150-5202-28-94L1150-5202-22-94L1150-5202-22-94L1150-5203-07-94L1150-5202-22-94L1150-5202-22-94L1150-52Comments:
VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260Page1of2linmleID:TFALLA-IBLWDWNDateCollected:31-JAN-94Matrix:WATERAnliIB¹:244--1QCBatchID:020494-8260-C1LALmIID:L117-2DateReceived:01-FEB-94DateAnalzed:04-FEB-94DilinFr1SURROGATERECOVERY12-Dihlhn-4Toln-QCLimits7-114-1104-Bromofluorobenzene11086-115ConstituentChloromethaneVinIhlriBrmmhnChloroethaneTrichlorofluoromethaneAn11-DihlrhnCarbonDisulfideMethleneChloridern-12-DihlrhnVinIA11-Dichloroethane2-Butanonei-12-Dihlrhnhlrfrm111-TrichloroethaneCarbonTetrachloride12-DihlrhBnznTrichloroetheneTCE12-DichlororoaneBrmihlrmhn2-hlrhIVinIEhr4-Meth1-2-entanonecis-13-DichlororoeneTInrn-1-Dihlrrn2-Hexanone112-TrichloroethaneTetrachloroethenePCEConcentrationIL<5<5<5<5<5<5<10<5<5<5<5<2<10<5<10<5<5ReportingDetectionLimitIL101010DataQualifiersLOCKHEEDANALYTICALSERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260ClientSamleID:OUTFALLOOA-U/IBLOWDOWNLALSamleID:L1175-23Page2of2ConstituentDibromochioromethanehlrnznEhInnm-Xleneo-XIenernrmfrm1122-Tetrachloroethane13-Dichlorobenzene14-Dihlrnzn12-DichlorobenzeneConcentrationIL<5<5<5<5<5<5ReportingDetectionLimitILDataQualifiersLOCKHEEDAIVALYTICALSERVICES SEIVIIVOLATILEORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270Pa1of2linSamIID:TFALLA-UIBLOWDWNDateCollected:26-JAN-94Matrix:WATERAnliIBh¹:24-27-AQCBatchID:8270SEMIVOLATILES4825LALSmlID:L11DateReceived:28-JAN-94DilutionFactor:1DExrd:1-AN-4DateAnalyzed:04-FEB-94SURROGATEREVERY002-FluorohanoiPhenol-d,Nitrobenzene-d,2-Floro'enI24-Trirmonp-Terphenyl-d,442308438QCLimits21-10010-9435-1144-1133-141PhenolConstituentConcentrationIL<10ReportingDetectionLimitIL10DataQualifiersi2-hlrhIhrhirhnl13-Dichlorobenzene14-DichiorobenzeneBnzlIhl1-Dihlrnzn2-MehIhenoibis2-ChloroisoroIether4MhIhnIN-Nir-Di-n-rIinHexachloroethaneNitrobenzeneIhrn-NirhnI24-DimethIhenolBenzoicacidi2-hlrhxmhn24-DihlrhnI124-TrichlorobenzeneNahthalene4-hlrnilinHxhlruin4-Chloro-3-mehIhenol2-MethInahthaleneHexachloroccloentadiene<10<10<10<10<10<10<10<50<10<10<10<10<10<1010101010101010501010101010LOCKHEEDANALYTICALSERVICES I SEIVIIVOLATILEORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270ClientSamleID:OUTFALLOOA-U/IBLOWDOWNLALSamleID:L1150-30Pae2of2Constituent24-Trihlorohanoi4-TrihlrhnI2-Chloronahthalene2-NitroanilineDimhIhhIAnhhln26-Dinirotoluene3-NitroanilineAnhhn24-Dinirhnoi4-NitrohenolDibenzofuran24-DinirIenDihIhhI4-ChlorohenI-henletherFluorene4-Nirnilin4-Dinir-2-mhIhnIN-Nitrosodihenlamine4-BromohenI-henleherHxhlrnnPnhlrhnIPhenanthreneAnthracenerzIDi-n-IhhIFluoranthenePreneBInzI'hhI3'-DihlrnziinBenzoaanthraceneChrsenei2-EhlhxlhIDi-n-IhhIBenzobfluorantheneBenzokfluorantheneBnrnConcentration(/L)<10<25<10<25<2<25<10<10<10<2<10<10<2<10<10<10<10<20<10<10<10<10ReportingDetectionLimitI/L)1010102510102525101010121010101010102010101010DataQualifierls)Inn12rnDibenzahanthraceneBenzohierlene<10<101010LOCKHEEDANALYTICALSERVICES SEMI-VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8270TENTATIVELYIDENTIFIEDCOMPOUNDSClientSampleID:OUTFALLOOA-U/IBLOWDOWNLALSampleID:L1150-30DateReceived:28-JAN-94Matrix:WATERAnalyticalBatch:020394-8270-ADateAnalyzed:04-FEB-94DilutionFactor:1QCBatchID:8270SEMIVOLATILES4825TentativelyIdentifiedCompoundUnknowmOrganicAcidEstimatedConcentration(yg/L)RetentionTime(minutes)25.24DataQualifier(s)fCnLOCKHEEDANALYTICALSERVICES
OILANDGREASEEXTRACTABLESANALYSISRESULTSBYFT/IRUSINGIVIETHOD413.2linmIID:TFAL-IBLWDWNDIlc:2-AN-4DateReceived:NAMatrix:WATERAnalticalBatch¹:020494-413.2AmIID:11.42DAnIz:7-FEB-4DilutionFacor:1DaeExtracted:02-FEB-94QCBatchID:020294-413.2ConstituentOilandGreaseConcentrationm/LReportingDetectionLimitmILDataQualifierIs)LOCKHEEDANALYTICALSERVICES PESTICIDEANALYSESRESULTSBYGC/ECDUSINGMETHOD8080ClinSmieID:TFALL0A-UIBLWDOWNDaColle:2-AN-4DateExtracted:31-JAN-94Matrix:WATERAnalyticalBatchII:013194-8080-E-4LAL'SmIID:L11DRive:2-AN-4DateAnalzed:01-FEB-94DilutionFactor:1QCGroupID:8080-PEST/PCBS4822SURROATERECOVERYoQCLimitsTCMXDCB6927"'0-15060-150A-BHB-BHCG-BHCD-BHConstituentrConcentrationL<0.05<0.05ReportingDetectionLimitL0.050.05DataQualifier(s)HEPTAHRALDRINHEPTACHLOREPOXIDEHLRDANEENDULFANIA-CHLORDANE44'-DDE44'-DDTDIELDRINENDRINENDOSULFANII44'-DDDENDRINALDEHYDEENDOSULFANSULFATE'ETHOXYCHLORTXAPHENEPB-11PCB-1221PCB-1232PB-14PCB-124PCB-1254PCB-1260TECHNICALCHLORDANETCMX-tetra-chloro-meta-xyleneDCB-Deca-chloro-biphenyl<0.05<0.05<0.05<0.1<0.1<0.1<0.1<0.5<20.050.050.050.10.10.10.10.5LOCKHEEDAIVALYTICALSERVICES RADDATAREPORT(ra01)IndianaNichiganPouerCo.eBridgman,HIOrganicandInorganicContaminants(projectCOOK.JENI)ClientSampleID:OU'IFALLOOA-U/IBLOlDOMNDateCollected:26-JAN-94LALSampleID:L1150-46iDateReceived:28-JAN-94HatrixtMaterLoginNumber:L1150GrossAlphaGrossBeta23-FEB-94GRALP/BETALAL-0060475623-FEB.94GRALP/BETALAL-00604756030.20.693.21.53.1pCI/LpCi/LPage6nag<v'5
RADDATAREPORT(ra01)IndianaNichiganParerCo.*Bridgman,NIOrganicandInorganicContaninanta(ProjectCOOK.JENI)HatrixtWaterClientSangriaID:OUTFALL00A-U/IBLOUDOMNDateCollected:26-JAN-94LALSaapieID:L1150-49DateReceived:28-JAN-94LoginNmhertL1150Ra-226Ra-22822-FEB.94RA-226LAL.0073477123.FEB-94RA-228LAL-0074550300.620.140.34pCI/L0.560.91pCI/LgPage9 h~I PHMetercpcy-lo~CaldatedueSampleTimeSampl'egSampleDateCDMEnteredbyPHAnalysis(LAB.079)OutfallOOA0PD5.3.56)SampleC/ph(priortocorrection)7)NH3pHcorrectiongoz.5.3'SampleSampleTimeSamplejjSampleDateCDMEnteredby8))ampleresultsC/pH(after'7.7gNHCorrection)3+boamcux-p'-4~/+/7>+U+/LZoo5.3.56)SampleC/ph(priortocorrection)7)NH3pHcorrection5.3.68)SampleresultsC/pH(afterCorrection)9)LAB.041SpecsVerifiedby:hl/8SupervisorReview/Date~W+IWFormpreparedby/DateFormapprovedby/Date12THPLAB.041.25sRevision1 --4OutfallOOASample/StandardSamplegDateTimeCDMEnteredby)SoDeterminationofTotalChlorine(Lab170)/0~~'~~(y~~/'/InstrumentCPCf)TechnicianVil)Absorbance6.112)Results,ppm3)Dilutionsmade4)Results,ppm(I)2~03)zoC51LAB.041SpecsVerifiedby:~NFlluperirvRsecview/Bere~~HI+Formpreparedby/DateFormapprovedby/Date~~~12THPLAB.041-25)lRevision0 SEEINSTRUCTIONSONREVERSESIDESECTIONIIPERMIT~gZppp582~%tSIy~A.LOCATIOttOFDISCHARGEASSti,~Wi,>>ZCTIUNt~06,iUPN~06S,iTTUE~i9WDISCHARGE8>>tIA%RECEIVlttGHATERIIE>>GROItZHATERORNAPEOFSIRFACEHAC>>DOYCUDISCHARGESEASOttALLY>>(IFttOPCCIIT!t@ETOE)LAIKEMICHIYESXtaLOCATIOND.IFYES>>I.ISTDISCHARGEPERIODSNANt./DAYNt./DAYSCHEDULECONTACTCOOLINGF>>TYPEOFHASTEHATERDISCHARGEFLOWRATEWASTEWATER~TypSEE.EAtSAPPAIIATI>>tiIIATENAIN>>HReHR>>DAYIN>>/WK>>~~M~~M~~~0NHASTBIATERlYPECOKEL~JLJLJLJLJLJNONCONTACTG~DISCHARGESCHZUIE(YEARLYAVERAGE)COOLINGPROCESSHeDISCHARGEFLCHRATESANITARYSTORMWATERU~NITGUSHOURS/DAY~24TOTALYEARLYDAILYHININIIDAILYHAXINNa>>>>PS>>>>~36157.68p~20.432~21MGY2MGDSGPDITEM2WATERTREATMENTADDITIVESIeTHENXINNDISCHARGEFIDHRATETOBEAUIHCRIZEDINPERHIT>>Je>>"AXINGDESIGNDISCNRGEFIMRATE>>A>>IX)YOUUSEHAlERTREATHENTAKDITIVESTOTREATYONDISCHARGE?(IFNO,CCNTINIETOITBI3)BiNtNEFIICTIOtt>>At%ICHEHICALCOMPOSITIONOFlAESEAKDITIVES>>NACeNAMEANDADKRESSOFHAIAFACTIRERSOFlHESEAISLEITIVESeDESIGNUNITSCODE1Mg/I2Ug/INAD.EXPECTEDDISCHARGECCtCENTRATIONOFAIKIITIVES~NAADDITIVENA%AKDITIVENA%HININNUNITSAVERAGECODEWITSHAXINttCODEWITSCODEADDITIVENA%EDOYOUTREATTHEDISCHARGElQRENIVEADDITIVES?NAQYESLJ:~LJFHHATISIHERENIVALEFFICIENCYANDDISCHARGEFREOUENCYNAADDITIVENt4%ADDITIVENAHEADDITIVENA%KRENIVALNS>>/DAYKAYS/WK~LJGeASAttATTACIPENTTDlHISAPPLICATIONPROVIDESPECIFICÃtNVLIAVCRAOUATICTOXICOUYilCALKATAORREFERBICEHHICHAREAVAIIAIRENDINFORHATIONONTHERATEOFDEGRADATIONOFTHEPRODUCTSFOREACHADDITIVE~NA31 >>VSTr~XTI".'ISERCCMPL~:IQSECT:"'IIIITEM7'.isfselsto'eusedovbothsurfaCeandgrcunc~ateraap((centstcrecordin!crratlcnonanvMichigancriticalmaterial,E.P.A.:rlcri-vollu.ant~crnazarcoussubstanceIn>>>>nlchtnlsapp(icationreouirescatatobeprovided.ThisvouldincludeanychemicalsubstancefromtheMichiganCrItlcalMaterialsRegister(TableIV),theE.P,A.PriorityPollutantListing(Tablev),orTables~.A->>zn(cnliatS"rganiCToxiccol~rants..theraxlePollutants,ConventionalandNonconventionalPollutantsandHazardouspsa",ces,',Tel7"R!Tl"LuATEPIAIS.op(DR(TVPDLL~F<rITS.~ID/CRuAZARDNSSL>>BSTAMCESIWTHEDISCHARGE"'a-erIs>>I';stthenameofthecnemlcalsubstance(crltlca)material,prioritypollutant,ornazardoussubstance)fromTablesIV,V-noIIA-viasreauirealntheooxwhichycucnecxeoinA.(-3.above.Entereachcnemlcalsubstance'sparameternumberas(lstedinTablesIV,VandIIA-VAItprovided.--ovldetrsaieraceccncenrra.icn-..'-ecnemicaisupstancerarao:nA.'-c(catetresembletypeusedandtnenumberofZnalySeSracetOprCVldetheCCnCentratlCndataIOr.heCnemlCalSubStanoenamedInA.C.ProvidethemaximumconcentrationanddeterminethemassloadingofthechemicalsubstancenamedInA'>>DTES:l.(tcnlvoneanalysisvasmacetoracher>>icalsubstancethenrecord+hatdataasamaximumvalue.(fmorethanoneanalysisnasbeenmadetorachemicalsubstancethenprovideanaveraoevalueofthoseanalysesandthemaximumvalue~Z.,hisSectionII,Item7,ataSl.eetprov(desspacefcrrecordingcatator8chemicalsubStanceS(Materials).zcsitlcnalspace'ort"cr"ing.catarcrmorethan8"arorialscncemacebymaxingcbiescfthisitem7DataSheetaSneeded.it>>SalSOrpOrtanttOuSeaSeparateSetOtDataSl.eetafcreaonapplloablerepcrtlngrequirementaslistedInA.l-3.andforaacnoutfall."eferIoTheleftmarolnforthecodenumberrepresentingtnesampletypeusedandtheappropriateunitcodes.40 SEEINSTRUCTIONSONREVERSESIDESECTIONIIPERMIT~MI0005827NUMBERNIFALLtltKRAstIAPEOFPRXESSCOIIIRIBUTIIIGTOTHEDISCHARGETlROUGHTHISOUTFALLA'QSICCODEBPROCESSSCHHXLE(YEARLYAVERAGE)U2BLOWIDOWINIDURS/DAYL224Iv/v~till,PROCESSSTREAMSCONTRIBUTINGTOOUTFALLDISCHARGEI/IC/IIIIOE0IIDsPROCESSPRODUCTIONRATENACsPROCESSWASTEWATERFLOWRATEBasis:1993actualdatasubmittedonDMRsTOTALYEARLYDAILYHlttINttDAILYHAXII/IN22QJi0.234~6UNITS/TIPE1POUNDS2GALLONS3CUBICYARDS4TONS6MGY6MGD7GPD!ME1HOUR2DAY3WEEK4MONTH5YEARIttIttOustCIKI/IIIIOMtO0A>>ttA%OFPROCESSCONIRIBUTIIGTOTHEDISCHARGETIROUGHTHISOIIFALLAtEISICCOPEBePROCESSSCIEIXAE(YEARLYAVERAGE)C.PROCESSWASTEWATERFLOWRATEDsPROCESSPRODUCTIONRATEAetIAt%OFPROCESSCOIIIRIBUTIt4TOTHEDISCHULETHOROUGHTHISOUTFALLAttOSICCODEBsPROCESS~(YEARLYAVERAGE)CePRXESSWASTEWATERFISHRATED.PROCESSPRODUCTIONRATEA.NAHEOFPRXESSCONIRIBUTINGTOTIEDISCHARGENATHAtIDSICCODEB.PROCESSSCHEDULE(YEARLYAVERAGE)CsPROCESSWASTGATERFLOWRATED.PROCESSPRODUCTIOIIRATEsssvM/Osv~sEvs/vEMTOTALYEARLYDAILYMININGDAILYI/AXIPINEsrs/Er~Esvs/vs@TOTALYEARLYDAILYHINIPINDAILYHAXINPI!EEE/ssv~seve/vs!I!TOTALYEARLYDAILYMININNDAILYHAXltlNWITSSTIPEWITCODEWITS/TINEA.VW%OFPROCESSCONTRIBUTINGTOTIEDISOQRGENATIROUGHTHISOUTFALLANDSICCCDEBePROCESSSCHHXAE(YEARLYAVERAGE)CePROCESSWASTEttATERFLCHRATEDePROCESSPRODUCTIONRATETOTALYEARLYDAILYHlNltXNDAILYHAXINNvevs/vsMWIT%DEUNITS/TltE33 INSTRUCTIONSFCP.CCIsPI.ETINGSECTICNIIITEM3T~ISfarnrequireSinfarmetlCnOntreOrCCeSSS-reamSWhiChCantrlbuteTOthiSdlSCnerge.NTEot"EPEP'4ITNlPIBERINTHEBOXAT.HETCPCFTHISFCRAITHEPEPSITIeIMBERCANSEFOUNDCNTHEFRONTPAGEOFyCUREXPIRING<<Rui.IfrnisIsenewori,atpreviously"emit,edfacility,thenleaveblankendanumberwillbeassigned.Enter'~~31InumaerinSOaCeOrOViCedfOreaCnOaqeOfSeCtianII~mareeCnindiVICualdiSCherCepainteSeparateSetCfSecticnil'ormsmustoefilledout.ITEM3PROCESSSTREAMSCCNTRIBLITINGTCQISCHARGE:<CREACHSEPARAT"FPOCESSPROVIDETHEFCLLCNIISIINFCONATICiiA,Entertnehereoftheprccesswhichcontributestothisdischarge.AlsoorovldeheprcoerSICcode.S.IndicateTheyearlyaverageprocessscheduleinhoursperdayanddays-per-year.Providecneorocesswascewacerfiihvraceinformationasrequestedbasedonyourlastl2monthsofoperations.RefertounitcodegivenIntheleftmarginfortheappropriateflowunits.O.ProcessProductionRate-Certainpernltlinitatlonsmeybebasedonproductionrates.Theproductionratesusedtodetermlreoernitlinltsshellbereoresentedbyareasonablemeasureofactualproductionofthefacility,suchastheproductioncuringtherignncnthcfthepreviousyear,orthenanthlyaveracefortnehiahestofthepreviousfiveyears,orotherreasonablemeasuceasstatedInaoolicabieU.STE.P.A.categoricalrulesandregulations.=crnewsourcesarnewdlschergers,actualraductionshallbeestimatedusingprojectedoroduc.ian.Reccrdyour-.ocuctlcnratesIntneternsanounitsusedintneeoolicaoleV.S.E.P.A.csteaaricalrulesandre-ulationsforiourtvpeoffacility. SEEINSTRUCTIONSONREVERSESIDESECTIONII74UMBER~MI0005827~008GROUNDWATERDISCHARGEINFORMATIONAeISTHEDISCHARGEFROMTHISOUTFALLDIRECTEDToTHEGRONIDORGRSNWATERS?(IFttOeCCttTlttUETosTEM5)BeHASAHYDROGEOLOGICALSTUDYORITSEQUIVALEIITBEENPERFORMEDORtSThERESIFFICIENTCURRENI'ÃXOGEOLOGICALthFONATICNAVAILABLEASREQUIREDBYTIEWATERRESOURCESCotttlsstottPART22GROUNDWATERRULESOFAUIUSTltl41980R~523eZ707(PAGEQ)FORTHISEXIST!t7GORPROPOSEDDISCHARGE.IFYESATTACHACOPYOFTWEREPORT.CeAREYCUREQUESTttgANEXP'PTICNFRI¹tSUBMITTlt4AHYCROGEOLOGICALREPORTl5DERRULER.323.22F(Q(PAGEt15)ORFRCMGRONGtwATERMONITORINGI)EQUJREYSNlSUIIERRULER.Z5e(>)(PAGEfQ)OFTHEPARTRRILES>>IFYESATTACHDOQNEIITSANDEXPlA'VLTIONToDEIONSTRATETHATYOURDISCHARGEWOULDQUALIFYFCRANEXPIRElothDeAREYOUREQUESTINGAVARIANCEFRCttRULE323.2205(PAGE5)(tgNDEGRADATION)OfTHEWATERRESIX¹ICESCOB%ISSIONPART22GRONG5ATERRULESTtFYESATTACHSUCHDOCI¹'EATSASh'ECESSARYToDEMONSTRATETHENEEDFORAVARIANCEIttTERMSOFTHECRITERIASPECIFIEDINRIIE5'DeQ10(PAGE+OFTHEPART22RULESeNANANAYESleeYESYESITEM5EXPECTEDWASTEWATERCHARAC-TERISTICSUCOOE1Mg/I2Ug/I3COUNTS/100ml4S.U.5F6LBS/DAYTIEAPPLICANTMAYBEREQUIRED'IDDoADDITICtIALWASTEANALYSESeAeDISCHARGECHARACTERISTICSCOIICENIRATIONBOD5(FIVEDAYBIOCtetICALOXYGENDEMAIO)'COD(CHEMICALOXYGENDEMAND)TOC(TOTALORGANICCARBON)NOTAPPLICABLE/BELIEVEDABSENTNAPRESENTSDATAPROVIDEDINITEM7I¹IITSCODEltANALYSES~TYPECODEu1ulenntaNITROGEN(AsN)TOTALSUSPENDEDSOLIDSTOTALFHQSFHOIIUS(asp)TOTALRESIDUALCtiXR!ttEDISSOLVEDOXYGENPHHIM~.LJ~8,~6~LJu1u1~uFECALCOLIFORMBACTERIATEMPERATI¹IE(Su¹4ER)TEtPERATI¹IE(WlttTER)~~u~~uBeOIHERWASTEHaTERCHARACTERISTICSu5u5E~IISTALLCHEIIICALSISSTANCESWHICHAREINMICHIGANSCRITICALPATERIALSREGISTERTABLEIVIPAGED)ANWORUeSeEPASPRIORITYPouUTANTLISTTABLEV(PAGE7)ORANYOIIKRSUBSTANCESNltcHARE0RHAYBEcot%INJI¹IIQUsToTIEDEBIGNATEDUsEs0FTIEGI(tx¹GIHaTER0RToTHEPUBLICHEALTHTHATAREDISCHARGEDOREXPECTEDToBEDISCHBRGEDToTHEGRtX5DWATERAYTHISFACILITY.ESTIMATETHEFINALEFFLLENTCottCENIRATICNAttoRECORDALLDATAINITEM7OFSECI'IONIIINTHISBooleLET.SAMPLEZYRF1GRAB224HOURCOMPOSITE0ILItGREASEuuLAJuuu~uLJSEEATTACHEDSHEETSFORANALYSISDATAREQUIREDINFORMATIONFORSURFACEWATERDISCHARGES.*Basis:1993actualdatasubmittedonDMRS35 INSTRUCTICNSFCRCCIZPLET>taSSECTIONIIITEMS4ANO5his!ormrecuiresInformationcnaspecificou.aa>Idischargingtoeitherthegrouncwatersorthesu!face>>aters.NTERT,EPRMITIIPIBERIf<THEBOXATTHETCPCFTHISORM.THEPERMITNUMBERCANBEFOUNDONTHEFRONTPAGEOFYOUREXPIRING"OMITSlfTn)SISane>>OrnOtDreVIOuSlypermittedfaClllty,thenleaVeblankandanumbers<<illbeaSSlcned.Enter-"eumfallnumberinthesoaCeprovidedforeacnDadeOfSectiOnII.ForeacnindividualdIscharcepointaseparatesetSeTInII!brms(Items4anc5)mustbe!Illedout.ITEM4ROJlO'".ATEPDISCHARGEINFCRuaTIC.'I(OONOTll>CLsJDEDEEP'HELLINJECTIONINFORMATICNINTHISITEVI)A.-O.TheaoploCantShalladdreSSeaChOftheSecartalfthedlSChargefrcmth>SOutfallIStOTheOrcund>>ater.ITEM55'<ISI'6CPE<PECTEO(FgoANENDISCHARGE)NASTENATEaCHaRaCTERISTICSQFGROUIC>HATERCRSURFaCE><ATEoDISCI!ARGE(00.<OTINCLUDEIt>>>uwsIONIsnRvasls!NIt<sHlaF>>MTheapplicantshallreportavailabledischargedata(realdataforexistingdischargeorexpecteddataforaproposeddischarge)fortheparametersaslisted.Theseparametersshallbeaddressedforeitherasurfacewaterdischargeorasappropriateforagrcundwaterdlscnarge.Forassistanceindeterminingaoproprlateparametersagroundwaterdlscnarceapplicantmaycontactthe".roundwaterQuality0>vision,PermitsSec.IonorTheapproorlateGroundwaterQualityOlvlslon'sDistrictoffice.Theapplicantshallreportthesampletvpecodebestdescribingeachreportedoleceofdata.SeecodingontheleftmarginofTnlsfern.IfThisoutfallisasurface<<atercischarce.Theecol>cantmustreportnuantltatlvedataforeachparameterIdentifiedbvanoot<<-.t.er,;sa"....e*oaSareomseoaao>>ee~oe*.o..'.o.saoaaotsaat*I-"s.:tts'esetst..siasiaIfdataiSaVal>ablefC<OtherparameterSnOtI!StedabOVeInA.OrCtherOarTSOfth(SaopliCatlOnTreaopliCantShculdrepartThatdataintheblankspacesprovidedlnthispart.ssOTES:I.UnitCOdeSfcrparameterSrepcrtedInpartSAandBCanbefcundOOthelefthandSideOfth>SfOTTn.2.GrabsamoleshallbeusedtoanalyzeforpH,tempe<ature,Totalohenols,res(dualchlorine~oilandgrease,andfecalcoliforminasurfacewaterdischargeunlessotherfrequency-sampletypeanalysesareavailable.SeeGlossary<page48)tordefinitionofgrabsample.3.24-hourccmposltesamplesshallbeusedtoanalyzeforTotal9005,COO,TOC,armeniaNitrogen,andTotalSuspendedSolidsInaSurfacewaterdiSchargeunlessotherfrecuency-Sampletypeanalysesareavallable.SeeGlossary<page48)tordefinlt'lonofcompositesample.REFQRTI'a<<DF>i<TAKEDATA.YouarenotrecuirectoreocrtunlessyouwishTodemonstrateyourellclbllityfora<<net"effluentlimitationfcroneormorepollutants,thatIs,aneffluentlimitationadJustedbysubtractingtheaveragelevelofthepollutant(s)presentinyourintakewater.NPOESregulationsallownetlimitationsonlyincertainc(rcumstances.Tocemonstrateyoureliclblllty,reporttheaverageoftheresultsofanalysesonyourintake<<ater(Ifyourwate>>isT.eatedbeforeuse,.esttnewaterafterItIstreated),ancattachaseparatesheetcontainingthefcllo<<ipofo!eachpollutant:(a)astateentThatt"eintake<<ater'sdrawn!rcmtrebodyofwaterintownichthedischargeIsmace.(Cthe!<<ise,youare",ce!Iolblefcrratlimitations,)astate"entof'".ee<<tentTc<<nlchthelevelcfTheDollutantIsreducedbvTreatmentofycur<<astewater.(You!limitations<<IllbeadJustedonlyToTneextentthattnepollutantisnotremoved.)(c)'whenaDDllcaole<forexample,whenthepollutantrepresentsaclassofccmpounds),ademonstrationoftheexten~towhichtnepollutants<ntheinta'keve!yphvslcally,chemlcallv,orololo<>icallvfr@-.TaopollutantsContenec.-VCurCISCbarre.<<YCurs:mitat(cnS<<:IIbead!uSTedC!Iy-"TneeXTe~tT>>atThelrtakeDOllutantSConotvaryfrcmtnedlscnarceopollutants.)<avouhavet"oormoresuosTantlallyincentlcalcutfalls,youmhvreauestpermissionfromyourDer...lttlngauthor:Tvcsa-:D!eancanalveon!vn<cufallandsuan(T<<neresultsofneanalvs(s'.crothersubstantiallycentcIuT~alis,'cu-ec!esTlsraneoyTneperm>.~IncauTholItv~cnasepalaTesheeaTTacrecTotl'eTopi>ca>>cnform(centi!ywhichcutfallyouclctest,andcescribewnvTheoutfallswnichvouc(dnottestareSuOSTantiallyIdentlCalTOTheOutfallwn<CnVcuOldteST. SEEINSTRUCTIONSONREVERSESIDESECTIONIIPERMITNUMSERHI0005827,PRIORITYPOLLUTANTSANDAOOITIONALINFORMATIONFORSURFACEWATERDISCHARGEONLYTHEFOLLCWINGREOUESTEDIPJFORYATIONc~>socADDRESSED~SURFACEWATERDISCHARGERS.KIIE!JJEWUSEDISCHARGERS~e"PROVIDEEXPECTEDVALUESFORTHEOUAMTITATIVEANDOVALITATIVEIPJFOJUATIONREOUESTEDBELOWIAIISTHISFACILIIYAPRIMARYI'JDUSIRY?(REFERTOTABLEIAPAf<4J)(IFtQ,GOTOE)(IFYES,GOTOBIB.IPJDICATETYPEOFPRIMARYIPJDUSTRYASLISTEDINTABIEIAPAPJE491(CCPJTIMJEWITHC.)C.DOESTHISOUTFALLDISCHARGECCPJTAINAth'ROCESSWASTEWATER?(IFNO>GOTOE)(IFYES'OTOD)DIItJDICATEWHICHGC/MSFRACTIOtJSMUSTBETESTEDFCR~(REFERTOTABLEIAPAGE4~IKIIE.FOREACHGC/MSFRACTIONCHECKEDYEACHSPECIFICORGANICTOXICPOU.iffANf'HITHINMHFRACTIOti557BEAPJALYZEDFOR(SEETABLEIIAPAGE42,INADDITIOPJALLPRlt"ARYINDUSTRYAPPLICANTSWITHAPROCESSWASTEWATERDISCHARGE~PROVIDEOUAMTITATIVEDATAFOREACHTOXICPOLLUTANTINTABLElllAPN4JI3aRECORDALLDATAONFORMSPROVIDED(ITEM7)INTHISBOOKIES'I(CONTINJEWITHE-KBEUJW)XYESJJOELECPWRXYESJJOXvJXATILEBASE/NEUTRALACIDPESTICIDE*E~IF~SURFACEHATERDISCHARGEAPPLICANT(PRIMARYORSECONDUIYINDUSTRY),REGARDLESSOFTHETYPEOFDISCHARGEKPJOWSCRHASRFASOPITOBELIEVETIVEANYPOlLUTAMfLISTEDINTABLEIIAANDIVAPAGES~ISDISCHARGEDFRCMANYOUTFALL'HEOUANTITATIVEDATA~BEPROVIDEDIRECORDALLDATAOMFORMSPROVIDED(ITEM7)ItiTHISBOOKLETSPKJTAPPLICABLE/BELIEVEDABSENTOXPRESEtif/DATAISATTACHEDF.IFAVYSURFACEWATERDISCHARGEAPPLICANT(PRIMARYORSECONDARYINDUSTRY)gREGARDLESSOFTYPEOFDIS(595EpKPJCWSORHASREASONTOBELIEVEAttfPOLLUfANTSLISTEDINTABLEVAPAGE+AREDISCHARGEDFRJXIANYOUfFALLTHEAPPLICJPIT~P'ESCRIBEREASONSFCRTHEPOLLUTANTBEINGPRESENTAPJDPROVIDEAMYAVAILABLECUJUJTITATIVEDATAIRECORDALLDATAONFORMSPROVIDED(ITEM7)INTHISBOOKlEToXNOTAPPLICABLE/BELIEVEDABSENTPRESEMf/DATAISATTACHEDGAILSURFACEWATERDISCHARGEAPPLICANTS(PRIMARYANDSECCNKARYINDUSTRIES)WHO:)ORMAPJUFACTIRESZeIip5TRICPKDJPOPHBJOXYACETICACID(2p45T)I-(I,JI,5-TRIOIIORDPkteXY)PRCPAPICACID(SILVEX,2,JI,5,TP)IrTTRICPLORCPHBKPL(TCPPJORHEXACHLOROPHENE(HCP/J(AILDATAFORTHEABOVEMUSTBEGENERATEDUSIIJGSTAPJDARDAPJALYTICALCALIBRATIONPROCBXPIES)ORKNXJSORHASREASONTOBELIEVETHATTCDDISORMAYBEPRESENTINTHEIRDISCHARGEa~REPORTJXIALITATIVEDATJ4GENERATEDWHICHUSEDASCREENINGPROCGXRENOTCALIBRATED'WITHANALYTICALSTAJJDJIRDS,FOR2.5z/8r-TETRACHLDRODIBENZOPDIOXIN(TCDD)~RECORDALLDATAONFCRMSPROVIDED(ITEM3)INTHISBOOKLETeJ~IF~QSFACEWATERDISCHARGEAPPLICANTKPQIJSORHASREASCMTOBELIEVETHATBIOLOGICAITOXICITYTESTSWEREVADEINTHELASTTIFJEE(5)YEARSONANYOFTHEAPI'LICAMTSDISCHUJGESOROiARECEIVIP6WATERINRELATIOPJTOADISCHARGE,PROVIDETJISItifORMATICNASAVAITACPPJEMTTOTHISAPPLICATIOMIXNOTAPPLICABLE/BELIEVEDABSENTPRESENT/DATAISATTACHEDNOTAPPLICABLEAPPLICABLE/SEEATTACHEDK.IFACONTRACTIABCRATORYORCONSULTIPJGFIRMPERFORMEDANYOFTHEAVLAYSESRECUIREDBYTHISAPPLICATIONPROVIDETHENAMEANDAXRESSOFEACHLABORATCRYORFIRMAMDTHEANIJLYSESPERFORMEDASA'IATTACPMEMTOFTHISAPPLICATIOMIXPJOTAPPLICABLEAPPLICABLE/SEEATTACHEDLIDOYOUDISCHARGEANYOTHERTOXICORINJURIOUSCHEMICALSUBSTANCESPJOTLISTEDINTABLESIVPAGEIIAP4)IIATPIPJXJ%VAPN;ES~A,lcvES,THENIDENTlcYTHECHEMICALSUBSTANCESANDESTIMATETHEFINALEFFLUENTCONCENTRATICPJS~SQUITTHISINFCRMATIONASANATTACPMEMTTOTHISAPPLICATIGNIXmfAPPLICABLEAPPLICABLE/SEEATTACHED*Pesticidedataisnotrequired;however,itisprovided. I'STRCGT!".S=RG""PEEP:/7SEC-':Ii!%PcIDc&4!7o.-.("Bs(~fora'cnC1ssteel!>ccut(all-ischa,"in"tct,"esurfaceaters.c=cu!.'4~'BEp!"InE20KA~-=..-""FI!ISFC?'~.!EFERSIITGvitBER2g22=RllOCII7+EFCOIITPAGEOFYOCoE>oIRII4"fthisisanewornotprevious!verh(ttecfac!I(tv,thenleaveb!Bnxanca1urberwiiIbeasslcned.eBete"-"ecv-fa!I"'.macr(1ThespaceCV.:ec!CrBach"aceotSect)en','.-~eachI"dividualdlscnarcepointase"gratesetIT=i!5*ATEtvcuhsvB~'O.mcleSUPS'tanTla!Iincent(caiCvtfalIs,vouavrBIBstPermissionlcmvcurperm(=inCauTCCrityTOsamplea1danalvzeonlyonecuttal)ahcsubmittheresultsc'.heanaivsisforothersubstantiallyidenticaloutfalls.ifyour,ecuestIsgrantedby-1eperilttlngauthority,onaseparatesneetat.achedtotheapplicationformidentifywhichoutfalIyoudidtest,ancdose,ibewnvtheoutfallswnichyoud!c-ot,estaresubstantiallvIdenticaltotheoutfalI<<n(Ch)PudidTBSPC.sncCO"FRPartI2.2I(g)(B),Frlcav,-"I,!323,rcvldes'raimall=.siness=xemoticn'r"-1therepelt!rgcf-.antltatlve..atafororganictoxicpollutantsancoxlcpollutantsasrecuiredby"arl22.21<g)(7)(il)(A)orI22.2((c)(7)(lii)<A).thesepartsareself-explanatcryancconotrequirefurtnerinstructlchs.Slmolvgothrcucneachpar,.and"."asindicated.S=everai!nduStrlalCategorieSCCS.csateCCrleShavebeenBXempTBC'r~S"bml--I"CCataCr,CertainGG/VSFwaetlonS0"FRpart'!2~yo(.BB,llc.".-',T"'.av,'or!i!,;BBT,'.aTes:,",s".3)..Bvlewt"efollcwlnolisttoceternlrewhethervcurfacilitycue!i'ies--peexe,ot'rcmrecon.IncG"/"S',Gashrcmatocraohv/"assSpectroscopy)Fract(ons.M/.'-'SFree.icn.est(noancRepcrtlrcExemptions.extileM!IIsIndustry-Al!fourX/ISSCrganiCftaCTIO1SI"xheGreige"illSSuCCategcry.-PesticidefractionInallornersupartsofthisIndustry.Orea!In!noandOresslncIndustry-volatile.base/neutral,and"estlc':efractionsintheBaseanopreclcspetalssubcategory.-AlltaurGC/!4SOrgan(CfraCTICnSIailOtherSuPCateccrieSOfth(SiwCuStrV.GumandMoodChemicalsIndustry-PesticidefractionintheTallOllRosinSubcategoryandtheRosinBasedDerivativesSubcategory.-Pesticideandbase/neutralfractionsinallothersubcatecoriesofthisindustry.PulpandPaperIndustryPesticidefraCtiOninPapergradeSulfiteSubcatecoriBS(SubpartsJandU).-Base/neutralandpesticidefractionsinoeinksuboartQ,oissolvincKraftsuboartF.andPaperboardfromMastePaperSubpartE.".olatiicebase/neutral,Castle(deractionslntheBcTBleacnedKraftsuboartu.semI-chem(ca)suboarts8andc,andNonintegrateo-FinePapersSuboartR.Acid,base/neutral.andpest(cidefractionsinFineBleachedKraftSuboarti.oissolvingSulfitePulpSubpartK,Ground-woodFinePapersSubpart0,I(arketBleachedKraftSubpart0,Tissuefrom'uastepaperSuboartT,andNonintegratedTissuePapersSuboartS.SteamElectricPowerPlantIndustry-Base/neutralfractionIntheonce-ThroughcoolingMater,FlyAsh.andBottomAshTransportMaterprocesswastestreams.38 SEEINSTRUCTIONSONREVERSESIDESECTIONIINUMBER~MI0005827(3HFkLIU'R9USETHISDATASHEET0RECCRDINFO'"ATIONASREQUIREDltl:(CHECKAPPI(SPRIATBOXFQRWHICHIIIFOR"ATICNTHISDATASHEETREP"ESSITS~'RITICAL'lIATERIALSTOXICOLLUTANTSSECTI(XIlliITEN(I-E~GROItlDWATERDISCHARGEI!<FOPAATIO!t(PAGE55)X'ECTIQIIleITC~O.PRICRITYIPOLutTA'<TSINSIIIFACEWATERDISCH((RGE(PAGE57)D3.3~BELQH:cRIilcALNATERIALs(TABLEIv)ItlsURFAcEwATstDlscHARGE(PAGE8)~IZARDOUSUSSTANCESINDISCHARGE3~LISTA'YCRITICA'"ATERIAL(TABLEIVPt<'AE6)teOTADDRESSEDItlSECTIQIIIITEYIRKIQRITYA~XUTA'ITSWHICHYOUICIQ(tORHAVEREASQIToBELIEVETOBEPRESBITINTHEDISCHARGE~SFEREVERSESIDEOFTHISPAGEFCRFUI(ETHERDIRECTIQ5eNOTAPPLICABLEXAPPLICABLE(SEEBELOw)(1(eAeI!A<<EQFCRITICALPATERIALORPRICRITYPOLUJTANTBeAVERAGECQICENTRATIONISA<<ZLETYPE;tTOFe(VIALYSES*Hydrazine00302012!PIITCODEGM'PLETYPEi7OFAIAIYSFSCe.<<AXECQJCSiiRATIONAlePASSA.'A"ECFCRITIC'L<<ATERIALORPRIORITYPO(J.VTATITWITCODEIPNTCODEK((JCe(B.AVERAGECQKEIITRATIQI;SA"PLE(YPEPi(OFA!IALYSESC.FAXItlttCQXBT((ATIQlA'Dt"ASSWITCCQE~GTYPEOFANALYSESLJWITCODEWITCOBENITSCODEMg/IUg<I/DAYDAYA(P(ETYPEGRAB24HR.COMRA,;N;EOFCRITICALt(ATERIALCRPRICRITYPOL((~TAt<T'9.AVERAGECQCENIRATIOtVSA".PLETYPES'"CFAtIALYEESCpI'AXItlttCOtlCEtm!ATICttA'(Di<<ASSA.;u(<<ZOFCRITICALPATERIALCRPRIORITYPOLLIITAtIT3.AVERAGECveiCE,ITPATIQNSe<<"PLETYPEI(/OF/L,'IALYSSC.<<AXItlPICQJCBA'RATIQIA'4)PASS'IAECFCRITICALuATERI>>CR-"RIORITYPCLLVTAlii3.AVERAGECQICSITRATIQI;BAFLE(<PE;"OFA'NLYSESC.<<AXI~PICQICE.'iTPATICtt"DPASSA.IIA<<EOFCRITICALNATERIALCRPGIICRIIYPCILVTA!Ii3~AVERAGECQICSITPATION!SA<<PLETYPE;iiC(:A'IALYSESC.<<AXIS'ltt'CQICEIITPATIQIANDi<<ASSle~'!APECFCRITICAL<<ATERIALCRP>IQRITYPQLLVTAtITeAVF4GECQltCEtt((ATIQltS'<<PLETYPE:e:CFA'IALYSESC,<<AXItlttCCICEINPATIQIAD<<ASSUIITCODESA<<PLETYPEFOFAt!ALYSESLJWliCODEWITCODELJ~~LJWITCCDEVVPLETYPEttQFAtIALYSESUtlliCODEWITCCCELJ~~~LJWITCODESA<<<PLETYPE=.OFA!IALYSESet<ITCODEWITCODEQIITCODES'PLEIYPEv'FANALYSESQIITCODEWITCOCELJJ;ITCCQESA(PLEi<PE<<QFAt<ALYSESLJWITCODEWliCODEA:IA<<EQFCRITICALl<<ATERIALCR""RIORITYPOLL(JTP(ttiBeAVEPACmCOAICDANRATION;SA<<EGLE(YPE;tIOFAtlALYSESC~<<AXIS'It<CUE'Pi&TIQIAY<<)X(ASSWITCODESA<<PLETYPERTOFA'IALYSESQNTCODEWITCCOELJ'~~LJ~~~LlADDITIONALPAGESCFTHISIiI7AREATTACHEDFORT((ReSTCFTHECRITICAL6YES<<ATERIALSAt<D/ORPRICRITYKAL(JTA%'SREQUIREDTOBEREPORTED(EIa*HydrazineisexpectedtobepresentindischargebutsmallquantitiesmaybefoundinthesteamgeneratorsbutwouldnotbeexpectedtofoundintheactualdischargeflowtoOutfalls001or002. 'ENERALCHEIVIISTRYRESULTSClientSampleID:OUTFALLOOS-U/2SLOWDOWNLALBatchID(s):126im,128im.201imDateCollected:01-31-94Matrix:waterDateReceived:02-01-94PO¹69095-040-3NConstltuent-'ethod-'esult'-.,;,"Rep'ortlng;:,.-'Data-DetectionUmitQualifier(s)'Date-AnalzedLALSamleIDFluoride,inmILBromide.inmILNitrite-Nitrate-Nitrogen,inmILSulfateinmILTotalCsnide,inmILColor\TotalPhenolics.inmILSulfideinmILSulfite,inmIL340.2300.0353.2300.0335.2110.3420.1376.1377.1<0.15<0.050<0.0500.12<0.020<5.0<0.15<1.01.20.150.0500.0500.0590.0205.00.151.01.003-02-94L1175-102-17-94L1175-402-11-94L1175-503-05-94L1175-402-07-94L1175-602-01-94L1175-102-08-94L1175-702-03-94L1175-102-01-94L1175-2Comments:
IVIETALSRESULTSClientSampleID:OUTFALLOOB-U/2BLOWDOWNLALBatchID(s):126imDateCollected:01-31-94DateReceived:02-01-94Matrix:waterPO469096-040-3NConstltuentaAluminumAntimonArsenicBariumBeriliumBoronCadmiumChromiumCobaltCoerIronLeadManesiumMananeseMercurMolbdenumNickelPhoshorusSeleniumSilverStrontiumThalliumTinTitaniumUraniumVanadiumZincMethod60106010706060106010601060106010601060106010742160106010747060106010601077406010'010784160106010602060106010ConcentrationlmIL)<0.20<0.060<0.010<0.20<0.005<0.20<0.005<0.010<0.050<0.0250.15<0.003<5.0<0.015<0.0002<0.067<0.040<0.050<0.005<0.010<0.10<0.010<0.20<0.10<0.001<0.050<0.020ReportingDetectionLimitImIL)0.200.0600.0100.200.0050.200.0050.0100.0500.0250.100.0035.00.0150.00020.0670.0400.0500.0050.0100.100.0100.200.100.0010.0500.020Data~Qualifier(a)Date'nal@ed02-22-9402-22-9402-20-9402-22-9402-22-9402-22-9402-22-9402-22-9402-22-9402-22-9402-22-9402-23-9402-22-9402-22-9402-09-9402-22-9402-22-9402-22-9402-25-9402-22-9402-22-9402-28-9402-22-9402-22-9403-07-9402-22-9402-22-94LALSamIeIDL1175-17L1175-17L1175-17L1175-17L1175-17L1175.17L1175-17L1175-17L1175-17L1175-17L1175-17L1175-17L1175-17L1175.17L1175-17L1175-17L1175-17L1175-17L1175-17L1175-17L1175-17L1175-17L1175-17L1175-17L1175-17L1175-17L1175-17Comments: VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260Page1of2lienmIID:TFALLB-BLWDWNDateCollected:31-JAN-94Matrix:WATERAniiIBh¹:244-2-1QCBatchID:020494-8260-C1LALmIID:117-2DateReceived:01-FEB-94DateAnalzed:04-FEB-94DilinFr:1SURROGATERECOVERY12-Dirh-4Tln-4-Bromofluorobenzene14106QCLimits7-11486-115ConstituentChloromethaneVinIhlriBrmmhnChloroethaneTrichlorofluoromethaneAen11-DihlrhCarbonDisulfideMethleneChloridern-12-DihlrhnVinIA11-Dichloroethane2-Butanonei-12-Dihlrhnhlrfrm111-TrichloroethaneCarbonTetrachloride12-DihlrhBnznTrichloroetheneTCE12-DichiororoanBrmihlrmhn2-hlrhIVinIEhr4-Methl-2-entanonecis-13-DichlororoeneTInrn-1-Dihlrrn2-Hexanone112-TrichloroethaneTetrachloroethenePCEConcentrationIL<5<5<5<5<5<10<5<5<5<5<2<10<5<10<5ReportingDetectionLimitIL101010DataQualifiersLOCKHEEDAiVALYTICALSERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260Page2of2ClientSamIeID:OUTFALLOOB-U/2BLOWDOWNLALSamfeID:L1175-20nInDirmhlrmhnChlorobenzeneEthIbenzenem-Xln-XInStreneBromoform1122-Trhlrhn1-Dihlrzn14-Dichlorobenzene12-DichlorobenzeneConcentrationL<5<5<5<5<5<5ReportingDetectionLimitILDalifirsLOCKHEEDAIVALYTICALSERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260TENTATIVELYIDENTIFIEDCOMPOUNDSClientSampleID:OUTFALLOOB-U/2BLOWDOWNDateCollected:314AN-94DateReceived:01-FEB-94Matrix:WATERAnalyticalBatch:020494-8260-C1QCBatchID:020494-8260-C1LALSampleID:L1175-20DateAnalyzed:04-FEB-94DilutionFactor:1SampleWeight:N/ANo.ofTICs:0TentativelyIdentifiedCompoundEstimatedConcentration(yg/L)RetentionTime(minutes)DataQualifier(s)LOCKHEEDANALYTICALSERVICES SEIVIIVOLATILEORGANICANALYSISRESULTSFORGC/IVISANALYSESUSINGMETHOD8270Paelof2linmIID:TFALL8-U2BLWDWNDII:1-AN-4.Matrix:WATERAnalticalBatch¹:021094-8270-AQCBatchID:8270-SVOA-4903LALmIID:L117-DRiv:1-FEB-4DilutionFactor:1DateExtracted:03-FEB-94DateAnalzed:10-FEB-94SURROGATERECOVERYo0Limi2-FlorohnIPhenol*deNitrobenzene-d,2-FluorobihenI246-Tribromohenolp-Terphenyl-d,i227067604121-110-9435-11443-11610-12333-141PhnIConConcentrationLReportingDetectionLimitLDbis2-ChloroethIether2-Chlorohenol1-Dihlrnn14DiIrnnBenzIalcohol12-Dichlorobenzene2-Mhlhnli2-hlrirIhr4-MethIhenolN-Nitroso-Di-n-rolamineHhlrhNirnnIsohorone2-Nitrohenol'-DimhIhBnziibis2-Chloroethomehane24-Dichlorohenol14-TrihlrnnNhhl4-ChloroanilineHexachlorobutadiene4-hlr--mhlhnl-MhInhhInHexachloroccloentadiene<10<10<10<10<10<10<10<10<10<10<10<10<1010101010101010101010101010LOCKHEEDANALYTICALSERVICES SEMIVOLATILEORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270ClientSamle)D:OUTFALLOOB-U/2BLOWDOWNLALSamleID:L1175-9P2of2Constituent4-TrihlrhnI245-Trihlrohenol2-Chloronahthalene2-NitroanilineDimhIhhIAnhhln26-Dinitrotoluene3-NitroanilineAnhhn4-DinirhnI4-NitrohenolDibenzofuran4-DinirIDihIhhI4-ChlorohenI-henIeherFluorene4-Nirnilin4-Dinir--mhIhnIN-Nitrosodihenlamine4-BromohenI-henleherHxhlrnznPnhirhnlPhenanthreneAnthraceneConcentration(/L)<10<10<25<10<25<25<10<10<10<10<10<10<10ReportingDetectionLimit(/L)102510252510101010101010DataQualifier(s)Di-n-IhhIFluoranhenePreneBIzIhI'-DihlBenzoaanthraceneChrsenei2-EhIhDi-n-IhBenzobfluorantheneBenzokflurantheneBnr<10<10<10<10<10<10101010101010Inn2rnDibenzahanthraceneBenzohierlane<10<101010LOCKHEEDANALYTICALSERVICES
SEMI-VOLATILEORGANICANALYSISRESULTSC~FORANALYSESUSINGIVIETHOD8270TENTATIVELYIDENTIFIEDCOIVIPOUNDSClientSampleID:OUTFALL00B-U/2BLOWDOWNLALSampleID:L1175-9DateReceived:01-FEB-94Matrix:WATERAnalyticalBatch:021094-8270-ADateAnalyzed:10-FEB-94DilutionFactor:1QCBatchID:8270-SVOAP903TentativelyIdentifiedCompoundSubstitutedHexanedoicAcidEstimatedConcentrationIyg/L)270RetentionTime(minutes)30.3DataQualifier{a)LOCKHEEDANALYTICALSERVICES OILANDGREASEEXTRACTABLESANALYSISRESULTSBYFT/IRUSINGMETHOD413.2ClientSamleID:OUTFALLOOB-U2BLOWDOWNLALSamleID:L1175-13DateCollected:31-JAN-94DRiv:1-FB-4Mrix:WATERAnalticalBatch¹:020994-413.2DateAnalzed:09-FEB-94DilinFr1DExr:-FEB-4QCBatchID:020894-413.2ConstituentOilandGreaseConcentrationmLReportingDetectionLimitmLDataQualifier(s)LOCKHEEDAItIALYTICALSERVICES PESTICIDE.ANALYSESRESULTSBYGC/ECDUSINGMETHOD8080ClienSamleID:UTFALL0B-U2BLOWDOWNDaCIleed:31-JAN-94DateExtracted:07-JAN-94Matrix:WATERAnalyticalBatch¹:021294-8080-E-3LALSmIID:L117-11DReiv:1-FEB94DateAnalzed:14-FEB-94DilutionFactor:1QCGroupID:8080PEST/PCB5054SURROGATEREOVERY00QCLimitsTCIVIXDCB648660-15060-150A-BHB-BHCG-BHCConstituentConcentrationL<0.05<0.05ReportingDetectionLimitL0.050.05DataQualifierls)D-BHCHEPTAHLRALDRINHEPTACHLOREPOXIDEHLRDANEENDLFANIA-CHLORDANE44'-DDE44'-DDTDIELDRINENDRINENDOSULFANII44'-DDDENDRINALDEHYDEENDOSULFANSULFATE'ETHOXYCHLORTXAPHENPCB-1016PCB-1221PCB-1232PB-124PB-124PCB-1254PCB-1260TECHNICALCHLORDANETCMX-tetra-chloro-meta-xyleneDCB-Deca-chloro-biphenyl<0.05<0.05<0.05<0.1<0.1<0.1<0.1<0.5<20.050.05.050.050.10.10.10.10.5LOCKHEEDANALYTICALSERVICES
RADDATAREPORT(ra01)indianaMichiganPowrCo.~Bridgman,HIOrganicandinorganicContaninants(ProjectCOOK.JEMl)ClientSampleiO:OUTFALLOOB-U/2BLOSSOMLALSenile10:L1175-15KatrixtMaterDateCollected:31-JAM-94DateReceived:01-FEB-94LoginMwhertL1175GrossAlphaGrossBeta23-FEB-94GRALP/BETALAL-0060475623.FEB-94GRALP/BETALAL.00604756-0.080.3B0.920.41.22.1pCi/LpCi/LPage2 RADDATAREPORT(ra01)IndianaHichiganPowerCo.*Bridgman,HIOrganicandInorganicContamlnants(ProjectCOOK-JENI)Hatrix:WaterClientSampleID:OUTFALLDDB-U/2BLOWDateCollected:31-JAN-94LALSea@leID:L1175-16DateReceived:01-FEB-94LoginNumber:L1175~~%'i:";":'(Caristg't'tigj't:i.".':::::W"':N:::::.:AWII5ity'iel:;'Igitgb;::::::::."'~Ra-226Ra-22810.HAR-94RA-226LAL-0073520125-FEB-94RA-228LAL-007451990.620.030.280.370.310.65pCi/LpCi/LPage3 PHMeterCPCy-lO~CaldatedueSampleSampleTimeSample/jSampleDateCDMEnteredbyOutfallOOBgIC,J40ooPHAnalysis(LAB.079)5.3.56)SampleC/ph(priortocorrection)7)NH3pHcorrection77P5.3.68))ampleresultsC/pH(aftert.7gNHCorrection)3SampleSampleTimeSamplegSampleDateCDMEnteredby5.3.56)SampleC/ph(priortocorrection)7)NH3pHcorrection5.3.68)Sampleresults'C/pH(afterCorrection)9)LAB.041SpecsVerifiedby:A(/8RupewvieozReview/Date~W+IWFormpreparedby/DateFormapprovedby/Date12THPLAB.041.25sRevision1 Sample/StandardSamplejjDateTimeCDMEnteredbyOutfallOOBISg-7DeterminationofTotalChlorine(Lab170)~~/q~/instrumentCPC/jTechnicianhl)Absorbance6.112)Results,ppm3)DilutionsmadeC.~C2MCZM4)Results,ppm(/I2*03)C511AB.DdlSpecsVerifiedby:~NRSupervisorReview/Date~~9I~Formpreparedby/Date/~fŽFormapprovedby/Date12THPLAB.041-25)lRevision0 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SEEINSTRUCTIONSONREVERSESIDESECTIONIIPERMIT~MT.0005827NUMBER[IJII'M.IlfBEI(OFPDOCESSOC)ITRIBUTI[JGTQTHEDISCHARGErROU%TYIISQUTFAU-~'DSICCCCE40~0>0DANN~4i9IIB=ROCESSSA-ED[LE(YEARLYAYRE)IOUS/DAY~24I"Avs/vePROCESSSTREAMSONTRIBUTING'OOUTFALLDISCHARGEVIV9Or00C~=ROCESSWASTEYIATERFLOWRATEBasis:1993actualdatasubmittedonDMRsDePROCESSF0')CTIONRATETOTALYEARLYDAlLYMININNDAILYe<<AXINTI0.003~*II0,~60.002~6*utITS/TIMEIIIIIIIPOUNDS2GALLONS3CUBICYARDS4TONS5MGY6MGO7GPDVIVI0010VICC4LA.iVVZOFPDQCESSCONTRIBUTINGTOTHEDISCHARGEDSQUGHTri[SOUTFALL~YT)SICC<<EB.PROCESS~(YEARLYAVERAGE)CePROCESS>IASTEWATERFLOWRATEDPROCESSFPODUCTIOttRATEA.:VINEOFPRXESSCOtt[RIBUT[t)GTOTHEDISCHARGETH[OUGHTHISOUTFALLA'IDSICCCCEBePROCESSSO'X)LE(YEARLYAVERAGE)C.PROCESSlQSTEYIATERFU)WRATEDePROCESSPPODUCTIOttRATEIYADS/IDY~DAYS/YSAIITOTAI.YEARLYDAILYMttl[NHDAILYNAXINNHADS/DAY~DAYS/VSAATOTALYEARLYDAILYMININHDAILYPAXINTIUN[TS/TIMEIHOUR2OAY3WEEKMONTH5YEARVlVILt~QQ.AeNAWIEOFPROCESSCOIITRIBUT[tlGTOTHEDISCHARGETHAt&SICCOPEBPROCESSSC~DE(YEARLYAVERAGE)CePROCESSWASTEWATERFLOWRATE~'DAV~DAVS/VSAATOTALYEARLYDAILYMININTILt[ITCODED.PROCESSPDQCUCTIQIIRATEAeIW%OFPPQCESSCQt[IRIBUT[NGTOTHEDISCHARGENgIlFAOUGHTHISOUTFALLAlIDSICCQCEB.PROCESSSOIEDRE(YEARLYAVGAS/iE)C.PROCESSWASTEIIATERFLOWRATEDePROCESSPRODUCTIOttRATEDAILY4'AX[t~IIQURS/DAYTOTALYEARLYDAtLY;I[NINADAILYWXINMUtttTS/TIPEIIIDAIS/YDYIUNITwX~IIUNITS/TIPE*Heatingboilerwasoutofserviceformaintenanceduringmostof1993.33 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SEEINSTRUCTIONSONREVERSESIDESECTlONlINUMBER~MI0005827PERMITTEM6PRIORITYPOLLUTANTSANDADDITIONALINFORMATIONFORSURFACEWATERDISCHARGEONLYOlTF/ILLNEFBTHEFQUMAIMGREQUESTEDItÃGIL4ATIGtl~4'cA"DRESSED~<vSIRFACE'<<ATERDISCHARGERS.BZEI;eDJVSEDISCHARGERSc~PROVIDEBIPECTEDVALVESFORTHEQUANTITATIVEAIJDQUALITATIVEItiFOJLeATIGttREQUESTEDBELQWeA.ISTnISFACILITYAPR!ueARYI'etXJSTRY?(REFERTOTABLEIAPAPE4+1(IFlf),GOTOE)(tFYES,GOTGB)BI:iDICATETYPEQFPRIMARYIIISTRYASLISTEDIMTABLEIAPJJiEQeCG;titty)EWITHC.)Ce0ESTHISOUTFALLDISCHARGECGtffAie4J4IYPROCESSWASTEWATER?flFtJGeGGTOE)(IFYES.GOTO0)DINDICATEHHICHGC/PSFRACTIONSFJJSTBETESTEDFOR~<REFERTOTABLEIAP4iE4~1IJQIE)cQREACHGC/f'8FRACTIONCHECKEDeEACHSPECIFICORGANICTOXICPOLLUTANTWITHlttEACHFRACTIGtt~BEAJJALYZEDFOR(SEETABcIIAPAGE42,INADDITIOtteALLPRIMARYIQJSTRYAPPLICAtftSWITHAPROCESSWASTEWATERDISCHARGEe~PROVIDEQUAJJTITATIVEDATAFCREACHTOXICPOLLUTANTltlTABLE111APAI<99~RECORDALLDATAetFORMSPROVIDED(ITG47)IltTHISBQQKLETe(CONTINJEWITHE-KBELOW)~00CQXYESSTMELJECJ)PWRXYEStaVOLATILEBASE/I'e'FUTRALXACIDPESTICIDE*EIFJJtt)'.SURFACEWATERDISCHARGEAPPLICA'ft(PRIHARYORSECCtiDARYIJIDVSTRY)eREGARDLESSGFTHETYPEOFDISCHARGEKJK)WSGRHASREASIXITOBELIEVETHATAJIYPIXLUTA'ftLISTEDINTABLEIIAANDIVAPAGES~ISDISCHVIGEDFRCHAtJYIXJIFALlgTHEQUANTITATIVEDATA~BEPRGVIDEDeRECORD~DATAONFCRMSPROVIDED(ITEM7)trtTHISBOOKLET.ttQTAPPLICABLE/BELIEVEDABSENTPRESBIT/DATAISATTACHEDc,IFA4YSIJIFACEWATERDISCHARGEAPPLICAtfi(PRIMARYGRSECGtJDARYItCUSTRY),REGARDLESSOFTYPEOF'ISCMIGEeKVJOWSORHASREASCttTOBELIEVEAIJYPOLLUTÃffSuSTEDINTABLEVAPAGE~AREDISOIARFEDFRÃANYOVTCALLTHEAPPLICANTy~DESCRIBEREASQtiSFCRTHEPOILVTAtfiBEINGPRESENTANDPROVIDEANYAVAILABLEQUANTITATIVECATAeREGQRDALLDATAQNFORMSPROVIDB)(ITE)t7)INTHISBGOKLETeNGTAPPLICABLE/BELIEVEDABSENTg,PRESENT/DATAtSATTA(BEDDG.ALLSIJIFACEWATERDISCHARGEAPPLIC4JTS(PRIHARYAtfDSECCtGNRYINDUSTRIES)W)e:jGRJANUFACTVRES2,4,5-TRICHJ)RGPHBK)XYACETICACtD(2,4,5-t):l,4,5-TRICHLGRQPHBK)XY)PRGPANOICACID(SILVEX,1,45TP))DIJE)jf/LU-l2e4e5-TRICHLORGPHBWL)PHQSPteROTHIOATE(ROtfJEL)J>TRIOLHCPJEJIL(TCPJIORHEXACHJ)ROPHEteE(HCP)J(Au.DATAFORTHEPl)STBEGBiBQTEDVSItIGSTAG)ARDAttALYTICALCAJ.IBRATIOJPROCE"IRES)QRKJJQWSGRHASREASONTOBELIEVElHATTCDDISORHAYBEPRESENTIttTHEIRDISCHARGEe~REPORTJXJALITATIVEDATAeGENERATEDWHICH'SEDASCREENItJGPROCBXREMOT~<IBRATEDWITHA4ALYTIG'4.STA'OARDSeFGR2.>e/LSe-TETRA:HLORQDIBEJJEO-P-DIOXItt(TCDDJ~RECGRDALLDATAOttFORDPROVIDED(ITFJI/)IttTHISBOQKLETe:FicESVRFACEwATERDISOIARGEAPPLICAtfigfXJSCR)ASREASONTOBELIEVEieATBIQLCGI+TOXICllYe-STS'<<EREJeADEItfIHELASTTHREE(5)YEARSgtA'h'FMiAPPLICA'llSDISCHARGESGRONARECEIVIMGWATERINRELAYICe4TOADISCHARGEiPROVIDEietISIteFGCATICMASA4ATTAOf)BftTO1HISAPPLIC)TIGMeK.:FACt)4TRACTLABORATORYORCONSVLTltJGFIRMPERFORMEDAth'FTJEAteLAYSESREQUIREDBYTHiSWFLICATICNePROVIDETHENAe%ANDADDRESSOFEAOIuBORATGRYORFIRMANDte,EANALYSESPERFQRJ'EDASANATTACWEtftGFTHIS*PPLICATIQMe'DQYQUDISCHARGEAth'THERtOXICQRIttJURIGVSCHEHICALSVBSTA4CESt)QT':)TEDlttSIVPAGeEIIAJ4)IIAleÃVAPA'ESJf/+Qelc"ESeTHENICBftlveeE"EHICA.c4!BSTANCESA'eDESTIMATEeHEFIJF4.EFFUJEJJTCCJJCEMTRATIGJJS.SVB4ITTHISFGRI'IATIeAJASA.'IATTAINTTGTHISAPPLICettlGM*Pesticidedataisnotrequired;however,itisDeXtK)TJV'PLICABLE/BELIEVEDABSENTPRESENT/DATAISATTACHEDMOTAPP'CABLEAPPLICABLE/SEEATTAOFJ)tJQTAPPLIABLEgAPPLImLciSEEATTAOIEDX~JOTAPPL'CABLEAPPeLICABLciSEEATTACHEDprovided. "'lS"".CTICKSCRC.ttolETI",V:SECTICIIiIITEW6vis'ci,-ecires)-'c~at'cncnaspec('Iccut(allciscnar-inotothes'r'ace~aters.Eht=-"-=ER'IIT'.".::"-"=INTHEBOXATHE"-"=,THISECRU.THEPE?MIT,':V'ABERCA)IBEFrnNOCIITHE=p"."ITpAGECFYCUoRo(RING'!t"lsTsa"evcrnotpreviousivCe~lttecfocilltv,thenleaveblankendanuPer<<Il(beass(oned.En,e-ecu-falI'.erlnhespacecrcr'cec',crseenpageofSecticnI(.=oreacn'lvicua(clscnarcepointsseparatesetfiec-'cni.,-e"cr.smust=efVl~cs.-.ITEvi64.anCycu>ave-~oormoresubstantially.ncent(caioutfalls,voumavreouestpormlsslcnfromvout'ermlttincbut"crltyto)a"O~eSncana)VZeOnlyOneOut(ail.""Supm(tthereeultSOftheanaiVSiSfOrotherSubStant(ai(V(Centi"a(Outfal(S.vcurecuestiscrantedbytnepem(ttlnoauthorltv,cnaseparatesneetattecnoctc-"eacpllca-lcnfoinide.rifv<nicnout,a(I,cuc(ctest,anccasercewnvtheutfalls~nlchyou<<Idnottestaresuostantia:Ivident(alto-neoutfalIxnlcnyoucictest.cOCFRpart"."I<c)(8),Fridav,-'"-I"I~tg83,provides',craSmallBusinessExeipricnxicmtnerepcrt(ngof"antitat(vecatafororganictoxicpo(lutantsanctoxicpollutantsasredo(redbypart122.2((q)(7)(il)(A)orl22~'l(o)(7)<i(I)(A).Thesepartsareself-explanatoryanoconotreouirefurtherlnstructicns.Slnolvgo.Iicucneachcartsncc"asIndicated.Severalincus-laicategoriesa,.cs.:csteccr(esnavebeenexemptec.ioi:submittln"catacrcar-sloTC/US"iactlcns,'0:=ROar-'~VO(.,a8,lip.".-',C-'CSV,aprilI,)g83,'OteSI,2~and3)."eviexthefoiicxlnolisttocete<tt(rexnetrervour(ac(((tvdual(!Iestobeexe.ct'romreport:ncSC/"SlgasChroatoorapnv/uassSpecticscc=y).Broctions.extIIe:aIIIsIncustrvSC/I',StractionTestingandReportingExemptions-All'ourGC/vSorganicfractionsir-xeGreloetsiIIsSubcategorv.-PesticlaefractionInallotnerS.ppartSOfthisIncustrv.Ore)1(nlnoancCress(noIndustr-volatile.base/neutral,andpestlcicefractionsIntheBaseandpreciousuetalssubcateoory.-A(Ifourcc/vsorganicfractionsinallothersubcategorlesofthisincustrv.GumandWoodChemicalsIndustry-PesticidefractionintheTallOIIRosinSubcategoryandtheRosinBasedDerivativesSubcateoory.-Pesticideandbase/neutralfractionsInallothersubcateuorlesofthisIndustry.ouloandPaperInduStrv-Pest(cldefractionInPapergradeSulfitesubcatecories<subpartsJandU).Base/neutralandpesticidefractionsinOeinkSubpartQ,Disso(vinoKraftSubpartF,andPaperboardfromWastePaperSubpartE.-volatile,base/neutral,pesticidefractionsIntheBGTBleacnedKraftSubpartH.Sem(-chemicalSuboartsBandC.andNonintegrateo-FinePapersSubpartR.-Acid.base/neutral.andpesticidefractionsinFineBleachedKraftSuboartI,olssolvlngSulfitePuloSuboartK.Ground-xoodFinepapersSubpart0.xarketBleachedKraftsubpartG,TissuefromwastepapersuboartT.andNonlnteeratedTissuePapertSubpartS.SteamElectricPowerPlantIndustry-Base/neutralfractioninthcOnce.ThroughCoolingWater,FlyAsh.andBottomAshTransportWaterprocesswastestreams.38 SEEINSTRUCTIONSONREVERSESIDESECTIONIIPERMIT~gZ0005827~00<0AeUSETHISDATASHEETTORECORDI"FORMATIONASREQUIREDItt'CHECXAPPROPRIATEBOXFORYHICHINFQRHATIQITHISDATASHEEfREPRESBITSs)CRITICALMATERIALS1SECTIIXIII,ITEN4-E.GRIXttDWATERDISCHARGEIttFQRYATIQtt(PAGE55)X2.sEcTIQIIIITBI6.PRI0RITYPQLUITAMfsINsIRFAQEHATERDlscHARGE(PAGE37)TOXICPOLLUTANTSHAZARDOUSSUBSTANCESINDISCHARGELISTAIIYCRITICALtATERIAL(TABLEIVPAGE6)tNTADDRESSEDINSECTIQIIIITBI6PRIORITYPIXLUTAMTShHICHYOUXttQWORHAVEREASONTOBELIEVETOEEPRESENTIt>THEDISCHARGE.SEEREVERSESIDEOFTHISPAGEFQRclPvHPRDIRECTIQIS~NOTAPPLICABLEXAPPLICABIE(SEEBELCH)UNITSCODE1Mg/I2Ug/ILBS/DAYKG/DAYLUeIA.NA<<EOFCRITICALI'ATERIALORPRIORITYPOLLUTANTB.AVERAGECQICENIRATION;SA"PLETYPEI(IOFANALYSESC.vAXItXNCQMCBIIRATIQtAtavASSAeIIAtlEOFCRITICAL<<ATERIALCRPRIORITYPQLLUfAttfB.AVERAGECCNCENTRATIONISNePLETYPE;4OFANALYSESC.YAXINNCQICEMTRATIONAttD.ASSAsNAt'kOFCRITICALYATERIALORPRIORITYRXLIMANfBsAVERAGECQICENIRATIONISA"PLETYPEIftOFA%LLYSESCePlAXINNCOtCENIRATIONAtIDI'ASS*Hdraze00302012WITCODESts"RETYPEOFAttAIYSESWITCODE'IITCOCELJUNITCODEW"lPLETYPEOFAttALYSESUNITCODElttlTCODELJWITCODESAevPLETYPEPOFANALYSESLJQtll'ODEWITCQDELJAeNtYEOFCRITICALMATERIALQRPRIORITYPQLUffANTB.AVERAGECQNCBITRATIQIISA<<PsLETYPEe1fOFAttALYSESQIITCCDESA'PLETYPELJOFANALYSESSAMPLETYPE1GRAB224HR.COMP.C.MAXI'OttCEMIRATIQIAtsDI'ASSAeIIAHEQFCRITICALelATERIALQRPRIORllYPQLLUfAttfB.AVERAGECQtCENTRATIOMl~~<<PLETYPE;>OFAltALYSESCeYAXIYIf4CQtCEMIRATIQIAtoYASSAsIIA'1ECFCRITICALYATERIALORPRIORllYPOLLUTANTsu(oB.AVERAGECQICEIITRATIQNlSAMPLETYPE;"OFAIALYSESC~<<AXItlN'CQICBITRATIQIAtDYASSWITCODEWITCODELJWITCODESA"PLETYPEffOFAttALYSESWITCODEWITCODELJUtITCODESA'tPLETYPEr'rOFANALYSESUltITCODEWITCCDE4~tUetlEOFCRITICALvATERIALCRPRIORITYPOLLUTANTm~WB,AVERAGECQICBITPATIOMISA<<PLETYPE~IQFANALYSESCee"AXISCQLEIIIRATIQIAlBMASSUstlTCODESA'IPLETYPEffOFANALYSESWITCODEWITCQQEAsi%YEOFCRITICALYATERIALQRPRIORITYPOLUJTAttfB,AVEPAGECOsCEMIRATION;SA<<PLETYPE;fffOFANALYSESC.,<<AXIHWCONCENTRATIONAttD"ASSWITCODESA'lPLETYPEffOFANALYSESLJQIITCODElftlTCODEADDITIONALPAGESOFTHISITEM7AREATTACHEDFCRTKRESTOFTHECRITICAL0YESMATERIALSAtilt/CRPRICRITYPOLLUTANTSREQUIREDTOBEREPORTED~2MO*HydrazineisnotexpectedtobepresentindischargebutsmallquantitiesmaybefoundinthesteamgeneratorsbutwouldnotbeexpectedtobefoundintheactualdischargeflowtoOutfalls001or002. '""STPSI'.--"RCC/LP<ET!)ISSECTIC)iII"ls'cr>>fsTobeusedbvbothsur'o.anccrouncwater<<:pl!cantT"recordIrfornatlononanvuichlcancriticalmaterial,E.p.A.r-ycc>l.tan.cr>>a:arpcus<<:s->>rceln<<nicnr'sscollcatlcnrecuiresCataTooecrcvlcec.This<<ovidincludeanvchemicalI.bcence'"w-"e"ic>>iganCr!Tic~"sterlais~egister>>bleI'/).-'eE.P.A.P"lorl<<ypollute>>T'stlno!TableV).CrTables<<>>lcrsTSCrganicToxiccollutants.'.herToxic-ellutnTS~"-nvenTlonalandNonconventional"cllutantsandhazardous.,Csa>>ces~!TE's7n!QQITVcCL<'VTS,A'IQ/CnHAZARDSJSSTA.CESmaterialI.E.3...8'stTrenameofThecremicalsessence!criticalmaterial,priorlty'ollutant~orhazardoussubstance)fromTablesIv,v1cIl'A-/Aasreculrecinthebcx<<nlc1youchecked",A.I-3.above.E1tereachchemicalsubstance'sparameternumberas!IstecInTablesIv,vandIIA<<//ifprovided.S.ProvideT>>eaverageconcentratlcncfTnechemicalsucstancene.edInA.IndicateTnesampletypeusedandThenumberofanalysesraceToprcvldetheconcentrationcatafor-"ec>>emlcalsubstancenenadlnA.Providethemaxlrtumconcentratlc1andcetermlnetheressloadlnoo!thecnemlcalsubstancenamedinA.')8TES:I.Ifcnlyonea>>alysls'<<as>>ace!Crachemicals;bstancethenrecordthatdataasamaxlmunvalue.Ifmorethanoneanalysisnasbeenmade!orachemicalsubstanceThenorovideanaveracevalueofthoseanalysesandthemaximumvalue.2.>>IsSectionIf,lte.7,staSheetoroviCesspacefcr"eccrdlngcata!or8chemicalsubstances!Materials).-'dditlcnalspacefor"sccrcingofdata!Cr~oreTran8"aterlalscanbemacebymak!ngcopiescfthisIten7DataSheetas~ceded.itIsalsoI,porta>>TTouseseparatesetofOataSheetsforeachapplicablereportingreculrementasIlsedInAI3.andoreachout.alI3.deferToTheleftnaroinforThecodenumber<<eoresentlngthesampletypeusedandtheappropriateunitcodes.40 llGVBngineeiiag&ScienceISununitCuwpanpAX.KI,Y'I'(l.kI,'>llRKI(lI','>ANALYTICALREPORTCookNuclearProj:WasteWaterAnalysisSubm:Feb21Samples29609-7RayV.Buhl(616)942-9600SubmittalNumber:Location:Contact:Phone:OutfallOOCHtngBoilerDetectionUnitsLimitWWESSampleNo:79691Surfactants,MBASColiform,'ecalBOD,(5-Day)Sampledby:DateSampled:TimeSampled:DateReceived:TimeReceived:(0.025(1(3102/21/9400:0002/22/9409:000.02511.0mg/lcl/100mlmg/le1-EndofAnalyticalReport*BODsampleisbeingreanalyzedandwillbesubmittedaftertheresultsarereceived.55:>>;Gloniroo(lIlllloI'nrkwnp'I,".I'0Box87I.(Iron(lRnl>lds,XIII9588-087I,616/942-9600I'nx9I2-6I9l ll'1VLagiBeeiiii&SCienCe"I!Amunil(~imp:vuSTATEMENTOFDATAQUALIFICATIONS~%Y;KI,)"'I'l(lXliNI(V,KIt;I',sCLIENT:CookNuclearSUBMITTAL'9609-7AllanalyseshavebeenvalidatedandcomplywithourQualityControlProgram.Noqualificationsrequired.Thefollowinganalyseshavebeenqualifiedforthereasonscited.SampleNo.(s):Explanation:Parameter:Reason:~KEY1.2.3.4.5.6.7.8.9.10.Sampleintegritysuspectuponreceipt(explain).AnalysisperformedbeyondEPAestablishedmaximumallowableholdingtime.Detectionlimitelevatedduetomatrixinterferences.Laboratorycontrolsamplevalueoutsideestablishedacceptablelimits.Matrixspikesamplevalueoutsideestablishedacceptablelimits.Duplicateanalysisvalueoutsideestablishedacceptablelimits.Surrogate/internalstandardrecoveriesoutsideestablishedacceptablelimits.Datapointsuspectduetopotentiallaboratorycontamination(explain).Coeluteswiththecompoundcited.Resultmayrepresentacombinationofbothcompounds.Other(explain).Note:ThisdocumentisincludedaspartoftheAnalyticalReportfortheabovereferencedandshouldberetainedasapermanentrecordthereof.:>5:>50!enw<>nitttlttstnrkwnySt;.t<>tt<>xn7.t.t;rnnuRnt>ilats..illlo;>88-087l.6t6/Ot>->>t>OOI:nxO-t>-O>.Bin
GENERALCHEMfSTRYRESULTS"ClientSa'mple'D:OUTFAL'L"',OOC-HEATlNG.BOILER:l'..,'..'ALBatchID(s):222imDate'Colic'cte'di'02-21-94!::$DateReceived:02-22-94"Matrix;,'vol'ater:P0469095-040-3Ns'.,':.'::.::i".':::'.".Constituent:::".':::::.':."::Meth'od':>':.<:,Res'uft';";:!:.':""".".'DetectionUmlt"-"h<-'.,..;-,Datii';,,';,;.:,:,:::".,;Date,,"....'Quallfierts)""""Anal'ed'-7;,'LALSamle"ID"FluorideinmILBromide,inmILNitrate-NitroeninmILSulfate,inmILTotalPhosphorus,inmILTotalKjeldahlNitrogen,inmILTotalCanideinmILTotalSuspendedSolids,inmILChemicalOxygenDemandinmILTotalOrganicCarbon,inmILAmmonia-Nitrogen,inm/LColorTotalPhenolicsinmILSulfide,inm/LSulfite,inmg/L340.2300.0300.0300.0365.2351.2335.2160.3410.2415.2350.1110.3420.1376.1377.1<0.15<0.050<0.017<0.0590.0498.0<0.02012239.53.7<5.0<0.15<1.01.60.150.0500.0170.0590.0300.100.02012181.00.0505.00.151.01.003-08-9403-14-9403-11-9403-10-9402-24-9403-17-9403-01-9402-28-9402-26-9403-10-9403-21-9402-24-9403-08-9402-25-9402-23-94L1304-22L1304-22L1304-17L1304-22L1304-16L1304-16L1304-13L1304-21L1304-23L1304-23L1304-16L1304-18L1304-14L1304-19L1304-20Comments:Nitrite4lltrogenlsnotpresentinpreservedsamples.LOCKHEEDANALYTICALSERVICES METALSRESULTS',Client"Simple'D."OUTFALL"OOC-':;:;.,':,.;.:,'EATINGBOILER"..".::":"-"-'.LALBatchIDls):222im'Date'Collecte'd'02-'21-94'.::,DateReceived:02-22-94Matrix:w'ater.PO¹69095-040-3NConitltuentii:-AluminumAntimonArsenicBariumBeIliumBoronCadmiumChromiumCobaltCoerIronLeadManesiumMananeseMercuMolbdenumNickelPhoshorusSeleniumSilverStrontiumThalliumTinTitaniumUraniumVanadiumZinc@Method601060107060601060106010601060106010601060107421601060107470601060106010774060106010784160106010602060106010Con'ceiitratlo'n.,-:-.IinIL)..:-.<0.20<0.060<0.010<0.20<0.005<0.20<0.005<0.010<0.0500.0263.6<0.003<5.00.017<0.0002<0.067<o.oao<0.050<0.005<0.010<0.10<0.010<0.20<0.10<0.001<0.050<0.020;-Re'po'rtlnIj,;....'Detection'mit.....,::.(mIL):,.0.200.0600.0100.200.0050.200.0050.0100.0500.0250.100.0035.00.0150.00020.067o.oao0.0500.0050.0100.100.0100.200.100.0010.0500.020":"'De't'e:."::'-.'"'Date".'.'Quallflerls)'-.A'naled03-12-9403-12-9403-14-9403-12-9403-12-9403-12-9403-12-9403-12-9403-12-9403-12-9403-12-9403-22-9403-12-9403-12-'9403-04-9403-12-9403-12-9403-12-9403-22-9403-12-9403-12-9403-22-9403-12-9403-12-9403-11-9403-12-9403-12-94SamleIDL1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12L1304-12Comments:LOCKHEEDANALYTICALSERVICES
VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260Page1of2ClienSmleID:0TFALLOC-HEATINGBOILERDateCollected:21-FEB-94Matrix:WATERAnalicalBach¹:022594-8260F1QCBatchID:022594-8260F1LALmIID:L134-1DateReceived:22-FEB-94DateAnalzed:25-FEB-94DiluionFacor:1SURROGATERECOVERY12-Dichloroethane-d4Toluene-d84-Bromofluorobenzene103105109QCLimits76-11488-11086-115ConstituentChloromethaneVinIChlrideBromomehnChloroethaneTrichlorofluoromethaneAn11-DihlrhnCarbonDisulfideMethleneChloriderns-12-DichloroeheneVinIAea11-Dichloroethane2-Butanoneis-12-DichloroeheneChlrfrm111-TrichloroethaneCarbonTetrachloride12-DichlrohnBnzeneTrichloroetheneTCE12-DichlororoaneBrmihlrmehn2-ChlorhIVinIEhr4-MethI-2-entanonecis-13-DichlororoeneTIenerns-1-Dichlororen2-Hexanone112-TrichloroethaneTetrachloroethenePCEConcentration/L<5<5<5<5<10<5<5<10<5<10<5<5<5<5<5<2<10<5<5<10<5<5ReportingDetectionLimit/L101010DataQualifiersLOCKHEEDAIVALYTICALSERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGIVIETHOD8260ClientSamleID:OUTFALLOOC-HEATINGBOILERLALSamleID:L1304-1Page2of2ConstituentDibromochloromethaneChlrobnzenEhIbenzenem-Xleneo-XIeneSmeBromoform1122-Tetrachloroethane13-Dichlorobenzene14-Dichlorenzene12-DichlorobenzeneConcentration/L<5<5<5<5<5<5ReportingDetectionLimitILDataQualifiersLOCKHEEDANALYTICALSERVICES SEIVllVOLATILEORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD82701f2DII:21-FEB-4Mrix:WATERDRiv:22-FEB-4DilinFr:1QCBatchID:8270-SEMIVOLATILES-5616DateAnalzed:04-MAR-94RATEREVER2-FfrhnIPheno!4,Nitrobenzene-d,2-FlrbihenI24216721-110-9435-11443-11p-Terphenyld2133-141ConcentrationReportingDetectionLimitPhni-hlrhr14-DihlrnznBnzlIhi2-IrirIhr4MhIhnIirnznIhrn10Bnziii2-hlrhmhnNhhin4-hlrnilin2MhlnhhInHexachloroccloentadiene<1010LOCKHEEDANALYTICALSERVICES SEMIVOLATILEORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270ClientSamleID:OUTFALLOOC-HEATINGBOILERLALSamleID:L1304-4Pae2of2Constituent246-Trihlrohenol245-Trichlorohenol2-Chloronahthalene2-NitroanilineDimehIhhlaeAcenahthlene26-Dinitrotoluene3-NirnilinAcnahhene24-Dinitrohenol4-NitrohenolDibenzofrn24-DinirolueneDiethIhthalate4-ChlorohenI-henletherFlrene4-Niraniline46-Dinitro-2-methIhenolN-Nitrosodihenlamine4-BromhenI-henleherHexhlrnznePentachlorohenolPhenanthreneAnhrenerzleDi-n-butIhthalateFluoranthenePrnBIbnzIhhai33'-DichlorobenzidineBenzoaanthraceneChrsaneis2-EhIhexIhhIDi-n-octIhthalateBenzobfluorantheneBnzkflranhneBenzorenIndeno123-cdreneDibenzahanthraceneBenzohierleneConcentration(IL)<10<10<10<25<10<10<2<25<25<10<10<10<10<10<2<25<10<10<25<10<10<10<10<20<10<10<10<10<10<10<10<10~ReportingDetectionLimit(IL1010102510101025102525101010101010102510101010102010101010101010101010DataQualifier(s)LOCKHEEDANALYTICALSERVICES SEMIVOLATILEORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270P1DII:1-FE-4Mrix:WATERIRmIDRiv:22-FEB-4DilinFr:1QCBatchID:8270-SEMIVOLATILES-5616DateAnalzed:06-MAR-942-FlrhnIPhenol',NltrobenzeneM,2-FIrihnl21196121-110-9435-1144-11p-Terphenyl-d2133-141ConcentrationReportingDetectionLimithni-IIhr4-DihirnznBnzlIhli-hrirIhr4MhIhnINirnzIrnBnziii-rhhnNhhlnIrnili2MhInhhInHexachloroccloentadiene<10<1010LOCKHEEDANALYTICALSERVICES SEMIVOLATILEORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270ClientSamleID:OUTFALLOOC-HEATINGBOILERLALSamleID:L1304-4REPae2of2Constituent246-Trichlorohenol245-TrichlorhenI2-Chloronahthalene2-NitroanilineDimehIhhaleAcenahhlen26-Dinitrotoluene3-NitroanilineAcenhhene24-DinirhenI4-NitrohenolDibenzofuran24-DinirlueneDihIhhI4-ChlorohenI-henletherFluorene4-Nironiline46-Diniro-2-mehIhenIN-Nitrosodihenlamine4-BromohenI-henletherHxhlrenzenPenchlorohenolPhenanthreneAnthracenerzoleDi-n-uIhhaleFluoranthenePreneBuIenzIhhla33'-DichlorobenzidineBenzoaanthraceneChrsenebis2-EhIhexIhhaleDin-cIhhIeBenzobfluorantheneBenzokfluorantheneBenzorneInden12-cdreneDibenzahanthraceneConcentrationI/L)<10<10<10<25<10<10<10<25<10<2<25<10<10<10<10<10<25<2<10<10<10<25<10<10<10<10<10<2<10<10<10<10<10<10<10<10ReportingDetectionLimitI/L)101010251010102510252510101010101010251010101010101010101010101010DataQualifierls)LOCKHEEDANALYTICALSERVICES LOCKHEEDANALYTICALSERVICESLANDGREASEBYFTIRL3.2OILANDGREASEIndianaMichiganPowerCo."Bridgman,MZAttn:Client
Reference:
(ProjectCOOK-JENZ)ClientSampleID:DateCollected!DateReceived:Matrix:AnalyticalBatchf:OUTFALLOOC-HEATING21-FEB-9422-FEB-94Water030894-418.1BOILERLALSampleID:DateAnalyzed:DateExtracted:DilutionFactor:QCBatchID<L1304-808-MAR-9402-MAR-94'413.2OILAND1TotalOilandGrease1.0 rPESTICIDEANALYSESRESULTSBYGC/ECDUSINGMETHOD8080mI14-DEr:-FEB-4Mri:WATRAnalicalBatch¹:030390-8080-E-1DAnIz-MAR-4DiiinFr:1QCGrouID:8080PEST/PCB5666TMXDCBRRAEREVERY97QCLimits60-150ConstituentConcentrationLReportingDetectionLimitLDataQualifier(sl-H-HHEPTAHRPXIDEHLRDANE44'-DDE4'-DDTENDLFANII4IMETHXYHRXAPHENPB-122PB-4TECHNICALCHLORDANETCMX-tetra-chloro-meta-xyleneDCB-Deca-chloro-biphenylLOCKHEEDANALYTICALSERVICES
RADDATAREPORT(ra01)IndianaHichiganPowerCo.*Bridgman,HIOrganicandInorganicContaminants(ProjectCOOK-JEHI)Hatrix:listerClientSampleID:OUTFALLOOC-HEATINGBOILERDateCollected:21-FEB-94LALSampleID:L1304-10DateReceived:22-FEB-94LoginHubertL1304GrossAlphaGrossBeta13HAR.94GRALP/BETALAL-0060590213-HAR-94GRALP/BETALAL-006059020.240.10.51.20.922.1pCI/LpCI/LPage2
RADDATAREPORT(ra01)IndianaHichiganPowerCo.*Bridgman,HIOrganicandInorganicContamfnants(ProjectCOOK-JEHI)Hatrix:MaterClientSampleID:OUTFALLOOC-HEATIHGBOILERDateCollected:21-FEB-94LALSampleID:L1304-11DateReceived:22-FEB-94LoginNumber:L1304Ra-226Ra-22821-HAR-94RA-226LAL-0073587414-HAR-94RA-228LAL-007458730'497.390.0550.50.0440.5pCI/LpCi/LPage3 PHMeterCPCy-le~Caldateduef+/SampleSampleTimeSample9SampleDateCDMEnteredbyPHAnalysis(LAB.079)OutfallOOC5.3.56)SampleC/ph(priortocorrection)7)NH~pHcorrection025.3.68))ampleresultsC/pH.(after27'HCorrection)3SampleSampleTimeSamplejjSampleDateCDMEnteredby5.3.56)SampleC/ph(priortocorrection)7)NH3pHcorrection5.3.68)Sampleresults'C/pH(afterCorrection)9)LAS.041SpecsVerifiedby:~R'upervisorReview/Date~~/+/~Formpreparedby/DateFormapprovedby/Date12THPLAB.041.25sRevision1 OutfallOOCDeterminationofTotal(Lab170)ChlorineInstrumentCPC//S0~TechnicianSample/StandardSamplej/DateTimeCDMEnteredby373i5Z~.I)Absorbance6.112)Results,ppmC-A(~C~cm3)DilutionsmadeC2C3CZM4)Results,ppm(82~83)c..W5)LAB.041SpecsVerifiedby:~HSupervisorReview/Dare~Mt~~Porepreparedby/Dree/~f'+Formapprovedby/Date12THPLAB.041-25)lRevision0 SEE1NSTRUCTIONSONREVERSESlDESECTIONIIPEŽT~.qZg006SZT0ODAoLOCATIONOFDISOWSIE~SWq~SEo,EZ00,,~06,zos~066,pj9E~19~DISCHARGELOCATIONBoH4t%RECEIVIHIHATER(IEoGAOLtCWATERCRIQ%CFQRFACE'NACoOOYOUDISCNRGESEASIXRLLY(IFIOoCCNTItlKlOE)DoIFYESLISTDISOHKEPERIODSN/AIO./EAVtQo/DAYBSOPTIONONDFLOWRATEWASTEWATER~p~gggEoIhM)APPLICATIONRAlKN/AIHo/IRo~sLJIRo/DAYIHo/ICo~u~~'uKI+1CONTACTCOOUNQ2NONCOIIDICTCOOLDIQ3PROCESSSANITARY5STORMWATERFo1YPEOFHASIEHAIKRDISCHA%EGoDISEHU4ESOEnlK(YEARLYAVERNKIHoDISCHhRtKFUBIRATEAlltimedailymaximumtimes365.IDTALYEARLYDAILYHIHIIItlDAILYtQXIIItI49Itl+CXE0~22.6~2~2~uLJHXRS/DAYoovhooo1MQY2MQD3QPDJoHAXDltlDESIGNDISCHUSIEFUXRNKoAoIXIYCUUSEHATERTREAT%HEAIDITIVKS101RFATVIXRDl~(IFHSoCCNTIIAK1DIT813)DESIGN5.2VloTIEHAXIPltlDISCHARGEFLDHRATETOBEAUDERIZEDIHPBIIIToltllQCXKITEM2WATERTREATMENTADDITIVESBoIW%RlCTlENoJUOOEIIICALIXPEOSITICNOFTABIEAIIITIVESooFTIEBKITIYEs,SULFURICACIDSULFURICACIDSODIUMHNeutralization"SODIUMHYDROXIDEUNITSCODE1MQ/I2UQ/IMARSULEX,INC.111GORDONBAKERROAD,SUITE30NORTHYORK,ONTM2H3R1DoEXPECIEDDISCHUGECEIEEHIIIATICNOFAIDITIVESoAEDITIYE~SodiumSulfateAEDITIVEIWEAEOITIVKNh%E.DO51I1RFAT1IEDISONCElDRBOtEAISITIVESTHAVILANDPRODUCTSCOMPANY421ANNST.,N.W.GRANDRAPIDS,MI49504HINII%tlINITSAY8IIGEItlITSHAXIIEtlItUTSECCK~gag~COCK'0130011500~1~lWo~LJo~LJi~FoWLTISTHKRBEHALEFFICIBEYAHDDISCHARGEFR81EIC6N/AAEDITIVEHNEAESITIVEVIEAEDITIVEIWEIRSo/DAYDAYS/HH.LJG,ASAHATTICIP%HT1D1HISAPPLICATICNPROVIIXSPECIFICHAPtQLIAHCRACULTICTOXICCUXIICALDATAERREFERENCEHHICHAREAVAILABLEAHDIHPOI6ATICNIXIII%RATEOFDESRADATICNOFTIEfRXLCQFCRDCHAEDITIVEoMSDSattached.*Approximatelyinstantaneousneutralizationuponmixing-(NewtanktobecompletedJanuaryof1995willensurecompleteneutralizationpriortodischarge.)31 INSTRUCTIONSFORCOMPLETINGSECT)OfIIITEMSIANO2ThisformrequiresInformationonthefacility'5dl5chargelocation,dischargeschedule,volumetlovrateandvatertreatmentaddltIves.ENTERTHEPERHITNUMBERINTHEBOXATTHETOPOFTHISFBI.THEPERMITNUMBERCANBEFOUNOONTHEFRONTPAGEOFYOUREXPIRINGpERMIT.IttnlsIsanevornotpreviouslyperm)ttedfacility,thenleaveblankandanumoerrillbeas5lgned.EntertheouttallnuaberInspaceprovidedforeacnpageo'.SectionII.ForcaenIndividualdlscnaroepoint5separatesetotSectionIIformsmustbefilledout.ITEMIOISCHARGELCCATIONSCHEDULEANOFLOWRATESA.Enterthelocationotdischarge,thisshouldincludequarter~uartersection.quartersection,section,Iorniandrange.B.Listnameofreceivingwater<Ifsurface~aterdischarge).C.Indicaternetnarfacilitydischargesonaseasonalbasis.O.Ifyei,listdlscnargeperiods.E.providethelandapplicationratesusedorexpectedtobeusedIntermsofinchesperhour,hoursDerday,andInchesDerraex.F.Indicatethetypeofvastevatertobedischargedfroathisoutfall.RatertothewastewatertypecodegivenInthelettmargin.MOrethanOneCOqemaybeapplICable.G.ProvidetheaveragenuroerofhoursperdayInvhlchthetacllltydlscnargestreatedwastewaterandthetotalnumberotdaysperyearinmichThedl5cnargeoccur5.H.providecurrent(frcmthelastl2months)orexpectedflowratesasrequested,RefertounitcodedivanInthelettmarginfortneappropriatetlowunits.MGY-milliongallonsperyear;MGomilliongallonsperday;GPOgallonsD>>day.I.ProvidethemaximumdischargetlorratewhichyouranttohaveauthorisedwithintheDetmlt.NOTE:ForNPOESpermlt5allY.theuseotsuchatlorraterillnotplaceanactuallimitrestrictionontheflorbutvillbethetlowrateusedtodewlooettluentlimits.Also,whentheMonthlyoperatingReportsarereviewedbycompliancestatfItvillhelptheatodetermineIfanynerorIncreasedusesmighthaveoccurredatthetaclllty.J.Providethedesigntlowtorthisspecificoutfalldischarge(e.g.batchtreatmentSystemflow,packagedtreatmentsyat~flowsoracmeotherfInltetreats>>ntsysteaflow).ITOI2WATERTREATMENTAOOITIVESA.Indicaterhetherdl5ChargeIstreatedvlthconditioners,Inhibitors,ormlcrobloclde.Ifnot,continuetoItem3.B.Givename,function,andchemicalccnoosltlonotadditivesused.C.Givenameandaddressotthemanutactureris)ottheadditivesused.0,Indicateexpectedmlnlaxxa,awrageandmaxlaxaadischargeconcentrationsottheaddltlvels)torthisdl5char9e.Ind)CaternetneryOutreatthedlSCnargetOramOVetheaddltlVela)befOred)SChargeOtraaterater.F~Indicatetheremovalefficiencyoteachadditivefromthewastewaterandthedischargefrequencyoteachadditivetothesurfacewaterorgroundwater.G.NOTE:ltlstheresponsibilityottheapplicanttosupplytheproductIntormat)onasrequested,inthisitema.InformationrequestedbutnotsuDpliedmayre5ultIntheaDpllcatlonbeingreturnedtotheapDIleantforcompletion.32 MATERIALSAFETYDATASHEETSODIUMHYDROXIDE50%INDUSTRIALGRADEe33kSECTIQNI-IDENTIFICATIONMANUFACTURERSNAMEoo~~~~~~~~~~ADDRESS(STREET,CITY,STATE,ZIP)PHONENUMBERSa~~o~o~~~~~a~a~~~~EMERGENCYPHONENUMBER.........EFFECTIVKDATEs~a~~~~~~eo~e~~~~TRADENAMEo~~~~~~s~~~~~~~~~~~~~CHEMICALFAMELYHavilandProductsCompany421AnnSt.,N.W.,GrandRapids,MI49504(616)361-6691CHEMTREC(800)424-93006/18/91SODIUMHYDROXIDE50%INDUSTREALGRADKAlkali,BaseSECTIONII-HAZARDOUSINGREDIENTSHAZARDOUSCOMPONENTSQSHA/PELACGIH/TLV(Units)PROD.CAS0SodiumHydra-ide(CausticSada)(48.5-51.0%bywt)SodiumChlaride(0.8-1.3%bywt)Water(Balance)2mg/m=TWANatKstab1ishedNatEstab1ished2mg/m~TWANotEstablishedNatKstablished10-77647-14-57732-18-5SECTIONIII-PHYSICALDATAMCXMMCCBOILINGPOINT................293F(145C)FREEZINGPOINT...............60F(15.6C)VAPORPRESSURE(mmHg)........1.5C<20CVAPORDENSITY(Air~i).........NaInformationAvailableSOLUBILITYINH20-~~.~~~.~....CampletelyAPPEARANCE/ODOR.'~...~.~~..~~Clear,ColorlessLiquid;OdorlessSPECIFICGRAVITY(H20~i).....1.52PH............................NatEstablishedSECTIONIV-FIRKANDEXPLQSIQNHAZARDDATADRRRCtCDPCRCRZECZRRKRCXRCDXZKRRCtCSRPKR%RDCIRC@FLASHPOINT..................'......NatFlammableLOWEREXPLOSIVELIMIT(%byVolume)NatApplicableUPPEREXPLOSIVELIMIT(%byVolume)NatApplicableEXTENGUESHMEDIA...................AsfarSurroundingFires07/30/1'F91
MATERIALSAFETYDATASHEETSODIUMHYDROXIDE50%INDUSTRIAlGRADESPECIALFIREFIGHTINGPROCEDURES...UNUSUALFIREHAZARD................NearNIOSH/MSHAapprovedselfcontainedbreathingapparatusandfullprotectiveequipmentwhenthismaterialisinvolvedinafire.Insolutioncausticcanreactwithamphatericmetalsgeneratinghydrogenwhichisf1ammableand/ore:~plosiveifignitedoSECTIONV-HEALTHHAZARDDATACARCINOGENICITY.............NTP~~~~~~~~~~~~~~~~~~~~~~~~~IARC~~~~~~~~~~~~sss~~~~~~~~~OVEREXPOSUREEFFECTS.......PRIMARYROUTE(S)OFENTRY...FIRSTAIDPROCEDURES........EXPOSUREAGGRAVATEDMEDICALNoneNa~~noRednessofE:cposedTissueswithpassibleburnsresultingindeepulceration.SkinContact,Ifinhaled:Removetofreshair.Ifnotbreathing',giveartificialrespiratian,preferablymouth-to-mouth.Ifbreathingisdifficult,giveo-ygen.Getmedicalattention.Incaseofcontact:Immediatelyflush,eyesorskinwithplentyaf~aterforat1east15minuteswhileremovingcont,aminatedclothingandshoes.Getmedicalattent.ion.NashclothingbeforereusedIngestion:Danotinducevomiting.Ifconscious,dilutebygivingseveralglassesafwater.CallaPhysicianImmediately.CONDITIONSNoneCurrentlyKnownSECTIONVI-REACTIVITYDATAMZfMMMMMMMWCCCR&MMMMClMXtCHEMICALSTABILITY............Stab1eCONDITIONSTQAVOID...........NatApplicableINCOMPATIBLEMATERIALS........AcidsDECOMPOSITIONPRODUCTS.~~.~~~~NaneCurrentlyKnownHAZARDOUSPOLYMERIZATION......Ni11NatOccurPOLYMERIZATIONAVOID..........NatApplicableCkmRRRCECPCRRXtStRCJDRSX'CRCtR'CRPAR~QRgLRRRCSCCC5SECTIONVII-SPILLORLEAKPROCEDURE MATERIALSAFETYDATASHEETSODIUMHYDROXIDE50/INDUSTRIALGRADEFORSPILL~~~~~~~~~~~~as~~~~s~MASTKDISPOSALMETHOD.....i...Addnon-rcactivedry,absorbentsuchasdiatomaceousearth.ShovelorsweepupandplaceinanapprovedDOTcontainerandseal.Flushcontaminatedareaandneutrali"ewithdiluteacid.Disposeofspilledorwasteproduct,contaminatedsoilandothercontaminatedmaterialsinlicensedlandfillortreatmentfacilityinaccordancewithallfederal,stateandlocalregulations.SECTIONVIII-SPECIALPRQTECTIONWCRRESPIRATORYPROTECTION........Suppliedairorselfcontainedbreathingapparatuawithfullfacepiece.VENTILATION.............,.....Tomaintainvaporsbelowlimits.PROTECTIVEGLOVES.............Rubberorotherimperviousmaterials.KYEPROTECTION............;...Chemicalsplashproofgoggles.OTHERPROTECTIVEEQUIPMENT....Asafetyshowerandeyebathshouldbeavailable.Foroperationswherespillsorsplashingmayoccur,useanimperviousbodycoveringandboots.HANDLINGANDSTORAGE..........Storeincool,dry,wellventilatedarea.Keepcontainersclosedwhennot,inuse.SECTIONIX-SPECIALPRECAUTIONSCCMHAZARDCLASS...............:..CorrosiveMaterialDQTSHIPPINGNAMK.........~..SODIUMHYDROXIDE,LILQUIDUNNUMBERe~~~~~~~~~~~~~~~~~~~~UN1824REPORTABLEQUANTITY(RQ)......2000lbs.REFERENCESHMIS:H-S,F-O,R-1SODHYDOX07/"0/19'P1 friARSULEX,r~(QI0"IIMATERIALSAFETYDATASHEET.SulfuricAcid1.PRODUCTANDCOMPANYIDENTIFICATIONMolecularWeight:98.08vCASP7664-93-9.ProductName:SulfuricAcid:Formula:H,SO,ChemicalName:SulfuricAcidchemicalFamily:InorganicAcid~Synonyms:SulphuricAcid,OilofVitriol,BatteryAcidProductUse:Usedtnmanufactureoffertilizers,explosives,otherackls,metalplcldingandpetroleumprocessing.MARSULEXInc.111GordonBakerRoadulte300orthYork,ONTM2H3R1(416)496-9655MARSULEXinc.40RichardsAvenueP.O.Box5453Nofwalk,CT0685&6453(203)8544300EMERGENCYTELEPHONENUMBER(800)263-S502PreparedbyMARSULEXTechnicalSection(416)49&4164.2.COMPOSITION/INFORMATIONONINGREDIENTSSulfuricAcklWater%byWt.70-100%CASNumber7664-93%7732-1863.HAZARDINFORMATIONEMERGENCYOVERVlEW:/DangerlExtremelycorrosive.Causesseverebums.Reactsvlolentlywlthwater.Hlghlyreactlveandcapable'fignitingcombustiblematerialsoncontact.Notflammable,butreactswithmostmetalstoformexplosivehydrogengas./SulfuricAddhacolorfesstoamber,deartoslightlydoudy,oilyliquid.NationalRreProtectionAssociation(NFPA)RatingHazardousMaterialsfdentNcatlonSystem(HMIS)RatingFlRE4Extreme/Severe.3High/Serious~2Moderate1=Slight0~MinimumWWaterReactiveDate:February,1993.Superaedea:February,1990MARSULEXMSDS4010EPage1of9 MPTERIALSAFETYDATASHEET,SulfuricAcid3.HAZARDINFORMATlON(continued)POTENTIALHEALTHEFFECTS:ExposureLimits:SWfuricAckiACGIH(TLV)1mg/m(TWA)3mg/m'STEL)OSHA(PEL)1mg/m'fWA)Incontactwiththeskin:Concentratedsolutionmaycausepainandsevereburnstotheskinandbrownishoryellowstains.Prolongedandrepeatedexposuretodilutesolutionsmaycauseirritation,redness,painanddryingandcrackingoftheskin.lncontactwiththeeyes:Immediatepain,severeburnsandcornealdamagewhichmayresultInbllndnesaC~Inhaled:MistsandvaporsmaycauseIrritationoftheeyes,noseandrespiratorytract.MaycauseIncreased~pulmonaryresistance,transientcoughandbronchoconstrlctlon.SevereoverexposuremayresultInlungcollapseandpWmonaryedemawhichcanbefatal.ingested:Severeburningandpainlnthemouth,throatandabdomen.Vomiting,dhrrheaandperforationoftheesophagusandstomachliningmayoccur.LongTermExposure:~Repeatedexposuremayproduceerosionanddiscolorationofteeth.Althoughnodirectlinkhasbeenestablishedbetweenexposuretosulfuricacid,Itself,andcancerInman,theWorldHealthOrganization(WHO)IntematlonalAgencyforResearchonCancer(IARC)haveconcludedthatoccupationalexposuretostrongInorganicacidmistscontainingsulfuricacidIscarcinogenictoman,causing,'ancerofthelarynx(thevoicebox)and,toalesserextent,thelung.ExposuretoanymistoraerosolduringtheuseofthisproductshoWdbeavoidedand,Inanycase,keepexposuresbelowtheoccupationalexposurelimitforsulfuricacid.Corrosiveeffectsontheskinandeyesmaybedelayed,anddamagemayoccurwithoutthesensationoronsetofpain.Repeatedoverexposuremayleadtocontactdermatitis,maycausebronchitiswithcough,phlegm,>'hortnessofbreathandemphysema,cancausechronicrunnynose,tearingoftheeyes,nosebleedsandstomachupsets.StrictadherencetofirstaklmeasuresfollowinganyexposureIsessenthl.ExistingMedicalCondNonsPossiblyAggravatedByExposure:SkinirritationmaybeaggravatedInIndMdualswithexistingskinlesions.Breathingofvaporsorsprays(mists)mayaggravateacuteorchronicasthmaandchronicpulmonarydiseasesuchasemphysemaandbronchitis.CarcinogenicityData:Althoughtherearereportslinkingexposuretosulfuricackltocancer,thisproductIsnotclassifiedbyNTP(NationalToxicologyProgram),notregulatedascarcinogenicbyOSHA(OccupationalSafetyandHealthAdministration),andhasnotbeenevaluatedbyIARC(InternationalAgencyforResearchonCancer)/orACGIH(AmericanConferenceofGovernmentalIndustrialHyglenlsts).(Seealso,LongTermExposure).NEffectiveOate:February,1993Supersedes:February,1990MARSULEXMSDS4010EPage2of9 NARSULEK,MATERIALSAFEIYDATASHEETSulfuricAcid,4.FIRSTAIDMEASURESPromptremovalofthismaterialfromcontactwiththebodylsofutmostImportance.&TARTFIRSTAIDATONCE.Precaution:Personsattendingthevictimshouldavoiddirectcontactwithheavilycontaminateddothlngand'omitus.Wearimperviousgloveswhiledecontaminatingskinandhair.Incontactwiththeskin:Rushskinwithrunningwaterforaminimumof20minutes.Startflushingwhileremoving~contaminateddothlng.IfIrritationpersists,repeatflushing.ObtainmedicalattentionIMMEDIATELY.Donottransportvictimunlesstherecommendedflushingperiodlscompletedorflushingcanbecontinuedduringtransporta/'hilethepatienttsbeingtransportedtoamedicalfacility,applycompressesofIcedwater.Ifmedicaltreatmentmustbedelayed,immersetheaffectedarealnicedwater.Ifimmersionlsnotpractical,compressesoficedwatercanbeapplied.Avoidfreezingtissues.Discardheavilycontaminateddothlngandshoesinamannerwhichlimitsfurtherexposure.Otherwise,wash/.dothtngseparatelybeforereuse.Incontactwiththeeyes:Immedhtelyflusheyeswithrunningwaterforaminimumof20minutes.Holdeyelkfsopenduringflushing.Ifirritationpersists,repeatflushing.ObtainmedicalattentionIMMEDIATELY.Donottransport/victimuntiltherecommendedflushingperiodIscompletedunlessflushingcanbecontinuedduringtransport..Inhaled:Movevictimtofreshair.GiveartlcialrespirationONLYIfbreathinghasstopped.GiveCardiopulmonaryflesuscltatlon(CPR)IltherelsnobreathingANDnopulse.ObtainmedicalattentionIMMEDIATELY.Ingested:Ifvlctlmlsalertandnotconvulsing,rinsemouthandgiveTAto1glassofwatertodilutemateriaLIfspontaneousvomitingoccurs,havevictimleanforwardwithheaddowntoavoidbreathingInofvomitus,rinsemouthandadministermorewater.IMMEDIATELYcontactlocalpoisoncontrolcenter.Vomitingmayneedtobeinducedbutshouldbedirectedbyaphyslchnorapoisoncontrolcenter.IMMEDIATELYtransportvictimtoanemergencyfacility.h//NotetoPhysician:AIItreatmentsshouldbebasedonobservedsignsandsymptomsofdistressInthepatient.Medicalconditionsthatmaybeaggravatedbyexposurelndudeasthma,bronchitis,emphysemaandotherlungdiseasesandchronicnose,sinusorthroatconditions.SeverityofthebumIsgenerallydeterminedbytheconcentrationofthesolutionandthedurationofexposure.Intheeventofskinoreyecontact,lmmedhteandthoroughflushingIsessential.ContinuedwashingoftheeffectedareawithcoldorIcedwaterwIIIbehelpfulinremovingthelasttracesofsulfuricacid.Creamorointmentsshouldnotbeappliedbeforeorduringthewashingphaseofthetreatment.5.FIREFIGHTINGMEASURESshPoint(method):Notapplicable,productIsnon-flammableutolgnltlonTemperature:NotcombustibleRammabllityLimitiinair(%):UELNotapplicableLELNotapplicableEeettlteDate:February,1993Supersedes:February,1990MARSULEXMSDSItI010EPage3of9 MATERIALSAFETYDATASHEETSulfuricAcid5.FIREFIGHTINGMEASURES(continued)FireExtinguishingMedia:Forsmallfiresusedrychemicalorcarbondloxkie.Forlargefires,floodfireareawithr'aterfromadistance.Expectviolentreactionwithwater.Donotgetsolidstreamofwateronspilledmaterhl.SpecialFireFightingProcedures:WearaNIOSH/MSHAapprovedself~ntalnedbreathingapparatusIfvaporsormistsarepresentandfullprotectiveclothing.Forfightingfiresindoseproximitytospillorvapors,useacld-resistantpersonalprotectiveequipment.Evacuateresidentswhoaredownwindoffir.Preventunauthorizedentrytofirearea.Dikeareatocontainrunoffandpreventcontaminationofwatersources.Neutralizerunoffwithlime,sodaashorothersuitableneutralizingagents(seeDeactivatingChemicals,Section6).Coolcontainersthatareexposedtoflamewithstreamsofwateruntilfirelsout.OtherFireorExplosionHazards:Notflammablebuthighlyreactive.CapableofIgnitingfinelydividedcombustiblematerhlsoncontact.Reactsviolentlywithwaterandorganicmaterialswithevolutionofheat.ExtremelyhazardousJincontactwithmanymaterials,particularlycarbldes,chlorates,fulminates,nitratesandplcrates.Sulfuricacidreactswithmostmetals,espechllywhendilutetogiveflammable,potenthliyexplosivehydrogengas.HydrogengascanaccumulatetoexplosiveconcentrationsInskleconflnedspaces.FollowappropriateNFPAcodes.6.ACCIDENTALRELEASEMEASURESStepstobetakenIntheeventofaspillorleak:RemoveallIgnitionsources.VentilateareaUseapproprhtePersonalProtectionEquipment.Preventliquidfromenteringsewersorwaterways.DikewithInertmaterial(sand,earth,etc.).Stoporreduceleaklfsafetodoso.CollectIntocontainersforreclamationordisposalonlyifcontainer~issuitabletowithstandthematerial.Considerinsituneutralizationanddisposal.Ensureadequatedecontaminationoftoolsandequipmentfollowingdeanup.ComplywithFederal,Provincial/Stateandlocalregulationsonreportingreleases.DeactivatingChemicals:,Ume,limestone,sodiumcarbonate(sodaash),sodiumbicarbonate,dilutesodium+hydroxide,diluteaquaammonia.WasteDlsposaiMethods:Disposeofwastematerialatanapprovedwastetreatment/dtsposaifacility,lnaccordancewithapplicableregulations.Donotdisposeofwastewithnormalgarbageortosewersystems.V'ote-pean-upmaterfalmaybeaRCRAHazardousWasteondhposal.rr'SpillsaresubjecttoCERCLAreportingrequirements:RQ1000lbs.7.HANDLINGANDSTORAGEPrecautions:WearappropriatePersonalProtectionEquipment.Donotbreathspraysormists.Donotingest.Do/notgetIneyes,onskinoronclothing.Keepignitionsourcesawayfromsulfuricacidstorage,handlingandtransportationequipment.HandlingProceduresandEquipment:Carbonsteelorstainlesssteelmaterialsaresuitableforuseforacidconcentrationsequaltoorgreaterthan93%.However,theeffectoflowerconcentrationsonthematerhlsofconstructioncanbeverycomplex.Contactproductsupplierforspecmcrecommendationswhenhandlingsulfuricacidatstrengthslessthan77%.EffecffveDate:February,1993Supersedes:February,1990MARSULEXMSDS0010EPage4of9 FJRSUI.EX,MATERIALSAFETYDATASHEETSulfuricAcid7.HANDLINGANDSTORAGE(continued)StorageTemperature:Storeabovefreezingpoint(Section9).Elevatedtemperatureswillincreasethecorrosion/rateofmostmetals.StorageRequirements:Storepackagedacidinadry,well,ventilatedlocationawayfromcombustibles,oxldlzers,bases,ormetallicpowders.StoragetanksshouldbeprotectedfromwaterIngress,bewellventilated,andmaintainedstructurallyinasafeandrelhbiecondition.OtherPrecautions:Sulfuricacklwillattacksomeformsofplasticsandcoatings.Alwaysaddacidtowater-notjwatertoacid.IfkeptInupperfloorsofbuilding,floorsshouldbeacidproofwithdrainstoarecoverytank.8.EXPOSURECONTROLS/PERSONALPROTECTION-RecommendatlonslistedInthissectionIndicatethetypeofequipmentwhichwillprovkleprotectionagainstoverexposuretothisproductConditionsofuse,adequacyofenglneerlngorothercontrolmeasures,andactualexposureswilldictatetheneedforspecificprotectivedevicesatyourworkplace.~EngineeringControls:LocalexhaustvenNationrequired.plratoryProtection:ANIOSH/MSHAapprovedair-purifyingrespiratorequippedwithacidgas/fume,dust,mistcartridgesforconcentrationsupto10mg/m.Anair-suppliedrespiratorIfconcentrationsarehigherorunknown.S)tinProtection:Impervious(l.e.,neoprene,PVC)gloves,coveralls,bootsand/orotheracidresistantprotective~clothing.EyeProtection:Tight-fittingchemIcalgogglesandfaceshield./OtherPersonalProtectiveEquipment:WherethereIsadangerofspillingorsplashing,acidresistantapronsorqsuitsshouldbeworn.Trouserlegsshouldbewornoutside(nottuckedIn)rubberboots.Safetyshowersandleyewashfountainsshouldbeinstalledinstorageandhandlingareas.9.PHYSICALANDCHEMICALPROPERTIEShddhPhysicalState:VquldAppearanceandOdor.SWfurlcacidIsacleartoamber,heavy,oilyliquidwhichmayhaveasharppenetratingodor.OdorThreshold:NodataBoilingPoint:77.67%:193'C(380'F);93.19%:278K(529'F);98%:330'C(626'F)I@citing/FreezingPoint:77.67%:-11.2'C(+11.6'F);93.19%:-29.5'C(-21.'I');98%:-1.1'C(30'F)VaporPressureat%PC(102'F):77.67%:1.2mmHg;93.19%:0.0016mmHg;98%:0.002mmHgSpecificGravityat15'C(60'F):77.67%:1.7059;93.19%:1.8354;98%:1.8437VaporDensity:(Air=1):3.4sulfuricacklcomponentBulkDensity:Notapplicable(seespecificgravity)ffecthreDate:February,1993supersedes:February,1990MARSULEXMSDS40tOEPage5of9 MATERIALSAFETYDATASHEETSulfuricAcid9.PHYSICALANDCHEMICALPROPERTIES(continued)EvaporationRate:Notapplicable/Solubility:MiscibleInallproportionslnwater.AlsosolubleInalcohol.pH:0.3(1Nsolutionat25'C/78'F)10.STABILITYANDREACTWITYStability:Under.NormalConditions:Stable,butreactsviolentlywithwaterandorganicmaterialswithevolutionofheat.UnderFireConditions:Decomposestoformsulfuroxides(SQ,).ConditionstoAvoid:TemperatureswhichmayhaveanegativeeffectonthematerialsofconstructionusedInequipment.MaterialstoAvoid:Contactwithorganicmaterhls(suchaschlorates,carbldes,fulmlnatesandplcrates)maycause~flreandexplosions.ContactwithmetalsmayproduceflammablehydrogengaLWhendiluting,addacidtowater.DoNOTaddwatertotheacid.HazardousDecompositionorCombustionProducts:Toxicgasesandvapors(e.g.sulfurdioxide,sulfuricacidpvapors/mistsandsulfurtrioxide)maybereleasedwhensulfuricaciddecomposes.HazardousPolymerization:Willnotoccur11.TOXICOLOGICAIINFORMATIONToxicologicalData:,Lote(oral,rat)2140mg/kgL+(Inhahtion,rat)510mg/refor2hrsSkineffects(rabbit):SevereIrritationEyeeffects(rabbit):SevereirritationCarcinogenicityData:Althoughtherearereportslinkingexposuretosulfuricacidtocancer,thisproducthnot,dasslfledbyNTP(NationalToxicologyProgram),notregulatedascarcinogenicbyOSHA(OccupationalSafety'ndHealthAdmlnistratton),andhasnotbeenevaluatedbyIARC(InternationalAgencyforResearchonCancer)orACGIH(AmericanConferenceofGovernmentalIndustrhlHyglenlsts).SeeSection3.HazardInformation,regardingPotenthlHealthEffects(LongTermExposure)forfurtherdiscussion.~ReproductiveEffects:NoInformationIsavailableandnoadversereproductiveeffectsareanticipated.~MutagenlcltyData:Noinformationh,availableandnoadversemutageniceffectsareanticipated.<'reratogenicltyData:NoInformationIsavailableandnoadverseteratogeniceffectsareanticipated.SynerglstlcMaterials:NoneknownEffectiveOats:February,1993Supersedes:February,1990MARSULEXMSDS4i010EPage8of9 NARSULH(,'ATERlALSAFETYDATASHEETSulfuricAcid12.ECOLOGICALINFORMATION-EcotoxlcEffects:Harmfultoaquaticlifeinverylowconcentrations.MaybedangerousifItenterswaterIntake;Rshtoxicitycriticalconcentration10mg/L;7.34mg/L/48hrs-LymneaePalustrls-0-100%mortality.13.DISPOSALCONSIDERATIONS~Responsibilityforproperwastedisposalhwiththeownerofthewaste.Workwiththeappropriateregulatorybodiestoensurecomplhncewithregulations.~ConsiderthecollectionofresidualsulfuricacidintocontainersforreclamationordisposalonlyIfthecontainerIssuitabletowithstandthematerhl.~Considerlnsltuneutralizationanddisposal.~Qean-upmaterialmaybeaRCRAHazardousWasteondisposal.~Provincial/StateorlocalregulationsorrestrictionsarecomplexandmaydifferfromFederalregulations.~TheInformationapplIestothematerhlasmanufactured;processing,neutralizing,useorcontaminationmaymaketheInformationtnapproprhte,InaccurateorIncomplete.14.TRANSPORTINFORMATIONU.S.(UnderDOT)/'hippingName:RQSWfurlcacklHazardClassorDivision:8ProductIdentificationNo.(PIN):UN1830PackingGroup:IICanada(UnderTC)ShlpplngName:SulphuricacidClassificatio(s):Qass8(9.2)ProductIdentlflcatlonNo.(PIN):UN1830PackingGroup:II15.REGULATORYINFORMATION..ASARATitlelllHAZARDCATEGORIESANDLISTSp'cute(Immedhte)Health:Chronic(Delayed)Health:Fire:Reactivity:SuddenReleaseofPressure;YesYesNoYesNoExtremelyHazardousSubstance(40CFR355,SARATitleIIISection302)CERCLAHazardousSubstance(40CFR302.4)'oxicChemical(40CFR372.65,SARATitleIIISection313)YesEffecUveDate:February,1993Supersedes:February,1990MARSULEXMSOS4010EPage7of9 MATERIALSAFETYDATA'SHEETSulfur/cAcid15.REGULATORYINFORMATION(continued)ReportableQuantity(RQ)underU.S.EPACERCLA:RQ=1000IbTSCAinventoryStatus:Reported/Included~A~DWorkplaceHazardousMaterialsInformationSystem(WHMIS)WHMISClassification(s):QassE-CorrosiveQassD1A-VeryToxicWHMISHealthEffectsIndex:AcuteLethality-verytoxic-immedhteCorrosivetoanimalskinWHMISIngredientDisclosureLIS:ConfirmedA;Meetscriterhfordisclosureat1%orgreater.ReportableQuantity(RQ)underTransportCanada-TDG:RQ5lltres(orKg)Ifltrepresentsadangertohealth,life,propertyortheenvironment.16.OTHERINFORMATIONAdditionalInformationandReferences1.Envlro-TIPSManual,'SWphurlcAcidandOleum',EnvironmentCanada,February1S84./2.Weast,R.C.(Ed.),'CRCHandbookofChemistryandPhysics',60thEdition(1S80)3.Sax,N.l.,"DangerousPropertiesofIndustrhlMaterhls',7thEdition(1989)4.ACGIH,ThresholdLimitValuesforChemicalSubstancesandPhysicalAgentsandBiologicalExposureIndices',1S91-925.Slttlg,Marshall,'HandbookofToxicandHazardousChemicalsandCarclnogens",2ndEdition,1985RevisionIndicators:JaIntheleftmarginIndicatesarevhlonoradditionofinformationsincethepreviousIssue.ffeottleeDate:February,199SSuporeodoLFebruary,1990MARSULEXMSDSW10EPagosofg NARSULB(,MATERlALSAFETYDATASHEETSulfuricAcid16.OTHERINFORMATION(continued)Legend:CAS8CERCIACFRDOTEPALCLELMSHANIOSHPELPVCRCRASARASTELTCTDGTSCATWAUEL-ChemicalAbstractsServiceRegistryNumber'I-ComprehensiveEnvironmentalResponse,Compensation,andUabllityAct-CodeofFederalRegulations-DepartmentofTransportation-EnvironmentalProtectionAgency-Theconcentrationofmaterhllnairexpectedtoldll50%ofagroupoftestanimals-LethalDoseexpectedtokill50%ofagroupoftestanimals-LowerExplosiveLimit-MineSafetyandHealthAdministration-NationalInstitute'forOccupationalSafetyandHealth-PermissibleExposureLimit-Polyvinylchloride-ResourceConservationandRecoveryAct-SuperfundAmendmentsandReauthorizatlonActoftheU.S.EPA-ShortTermExposureLimit-TransportCanada-TransportationofDangerousGoodsAct/Regulations-ThresholdUmltValue-ToxicSubstancesControlAct-Time-WeightedAverage-UpperExplosiveUmitJTheinformationcontainedhereinhasbeenpreparedbyMARSULEXInc.andIsofferedonlyasagukietothehandlingofthisspecificmaterialandhasbeenpreparedlngoodfaithbytechnicallyknowledgeablepersonnel.ItIsnotIntendedtobeaII-InclusiveandthemannerandconditionsofuseandhandlingmayInvolveotherandadditionalconsiderations.NowarrantyofanykindIsgivenorImpliedandMARSULEXInc.willnotbelIableforanydamages,losses,InJurlesorconsequenthldamageswhichmayresultfromtheuseorrelhnceofanyinformationcontainedherein.EffeeUveDate:February,1993Superaedea:February,1990MARSULEXMSDSW10EPage9of9
~'~e\~~IC~~e~.~~~7~~eC.~.I'~~~ei.~co~C'~ejeeC~I<<C'e.~ej7)'~'IAce'~~~C'~7'~c~~'e7a~C'.~rI~~0~~ejA~7~~LII'cjc'~'ejAC'.~ej'c~~~'~ed%ocEa~~II~~7A~7C~C~I~C~ejx7~~C~~'ejx~~~'exx~c~r~C~C~C~e7\~7~~~,~e7%~e~'~~jA~~~ INSTRUCTIONSFORCOMPLETINGSECTIONIIITEM3TrIsformrequiresinformationon,theprocessstreamsrhlchcontributetothisdischarge.ENTERTHEPERMITNISIBERINTHEMXATTHETCPOFTHISFORM.THEPEIbIITNWBERCANBEFOUNDONTHEFRONTPAGEOFYOUREXPIRINGpEIpIIT.Ifthisisana>>ornotpreviouslypermittedfacility,thenleaveblankandanumber<<illbeassigned.EnteroutfallnumberinspaceprovidedforeacnpageofSectionII.ForebenindividualdiscnaroepointaseparatesetofSectionilformsmustbefIliedout.ITEM3PROCESSSTREAMSCONTRIBUTINGTOOISCHARGE:FOREACHSEPARATEPROCESSPROVIOETHEFOLLOW'INGINFORMATIONA.EntertnenameOftheprOCeSSuhlqnCOntributeStOthlSdiSCharge.AISOprOVidetheprOperSICCOde.B.IndicatetneyearlyaverageprocessscneduleInhoursperdayanddays-peryear.C.ProvidetheprocesswastewaterflowrateInfonaetionasrequestedbasedonyourlastI2monthsofoperations.RefertounitcodegivenIntheleftmarginfortheappropriateflowunits.0.processproductionRate-Certainpermitlimitationsmaybebasedonproductionrates.Theproductionratesusedtodeterminepermitlimitsshallberepresentedbyareasonablemeasureofactualproductionofthefacility,suchastheproductionduringthehighmontnoftnepreviousyear,orthemonthlyaveraqeforthehighestofthepreviousfiveyears,orotnerreasonablemeasureasstatedInapplicableU.s.E.P.A.categoricalrulesandregulations.Forneusourcesorneudlschargers,actualproductionshallbeestimatedusingprojectedproduction.RecordyourproductionratesinthetermsandunitsusedintheapplicableU.S.E.P.A.categoricalrulesoneregulationsforyoultypeoffeellitye SEEINSTRUCTIONSONREVERSESIDESECTlONIlPERMIT~ts110005827NUMBER.:vGROUNDWATERDISCHARGEINR)RMATIDNAsISBEDISCHARGEFIEPITHISOUTFALLDIRECTEDTOBEGRCLBOORGROLSDQTTRS2(IFMlsCCtITIIIETOITBtlBJBsHASAHBNLXIKOUXIICALSBBTYORITSEOJIVALENTBEENPERFORIEOORISTHERESLFFICIENTCJRREHTHtlROGKQICALIHFCttWTICNAVAILABLEgREOQUREDQ~HATERRESXRCESTHISDLISTIHIOR~DISCHARGE)IFYESATTAOIACOPYCFTHEREPCIITsCsAREYOURSTII41AHEXBPTICNFRLBISLttlllTI%AHYIROGIDUXIICALREPORTLEKVARRLAERs(Q(PAGEQ)ORFRLBIGROLtEIWTEBKNITOII%IIEOUJRIBENISLEGERELLERss(5)LPJGEQ)0F'nEPART22RLLKssIFYEsATTAcHDOCLIENISANJEXPLAIWTICNTODMt9STRATKTIWTYOLIIDISCHARGEIEXADOUILIFYFOIAM~ONsDsAREYLXJRBXESTIIDAVARIANCEFRCNRULE3Bs2Z6(PJGE19(td%KIINATICN)OFBEHATERRESOLJEXSCCttllSSIONPART22GRCLtGIWIKRRILESTIFYESsATTACHQXHDOCLtEHISASIECESSARYTOOQQN$7INTKTIENEEDRTIAVARIANCEINTBIBISOFTIECRITIRIASPKIFIEDINRLAEV5sZ?10(PJGKCFBEPART22RLIESsEsI,ISTAlp,OEIIICALSLBSTAtCKSWIOIAREINNICHIGANSCRITICALHATERIALSREGISTERTABLEP/LPAGEII)ANVCRUsSsKPA'SPRIOIITYITXLLITANTLISTTABLEY(PAGE7)ORANYOBERSLBSTAJCES%lotAREcRtwYBEcoEIILABIIQJsToBEBEBIQwTKDUBEs0FTIE6IIGLtEBwTERcRToTIEILSLICIEJILBITHATAREDISCHARGEDOIEXPECTEDTOBKDISCHIRGEDTOBEGROLtElWTKILBYTHISFJCILIIYsESTDWTKTHEFINALEFFLIENTCOIEXIIIRATIOIAIORECCRDALLDATAINITEN1OFSECTIOIIlIHlHISBCDILETsBEJPPLICJJII'AYBERKOJIREDTODOAIDITIOWLIWSIKAIWLYSKSsQXYESp~ReportSubmitted12/6/91.Q~SPgXNOTAPPLICABLK/BKLIEYEDABSENTClPRESENTiDATAIROYIBEDINITTH7lTEM6AsDISOIUEIKOWRACIBRISTICSBCO5(FIVEDAYBIOOEIIICJILOXYGENDEHJjtO)'CCD(OKIIICALaLYGENIKIWIO)CCNBNBIATIOl~5~0~18,~0~52EXPECTEDsssssswsssslSSSNSSC-~Usscass1lED/I2UO/I3COUNTS/100tnl4S.U.5'F5LSS/DAYIOC(TOTALOEANICCARBON)JJBCNIANITIOIEH(ASN)TOTALSUSPEIKEDSLLUNTIALPICGPIOEJS(ASP)>>TOTALRESICUILOEJNINEDISSCQ%DOXIGENFECILLDLIRIBIBACTERIA'ntPBRABNK(SLttER)IEIPERATLIE(HINIBR)NDI~0.~02~0.~08LLJ~LJLJ~~LJBsOBERIWSTEIWTEROWRACIKRISTICS~Iu>u5~52~SM~PLXRE.1GRAS224HOURCOllPOSITE0IL4GREASELORIDEATEITOTALIL~10.~9~80,~00ID8~195.~010.,20~582925.~0~8~0~0~1~521521~611~6~122~2REQJIREDIIFOEWTICNFOISNIFACKIWTBRDIOIIA%ESsAnalysesperJ.B.Beauboeuf,TargetPermitEffluentLimitsList. INSTRUCTIONSFORC(y(PLETINGSECTIONIIITEMS4ANO5ThistomrequiresInformationon4specificoutfalldischargingtoeitherthegroundratersorthesurfacewaters.ENTERTHEPERMITNISIBERINTHEBOXATTHETCPOFTHISFORM.THEPERMITNQd)ERCANBEFOUNOONTHEFRONTPAGEOFYOUREXPIRINGPERMIT.Itthisis4nerornotpreviouslypermittedfacility,thenleaveblankand4numberrillbeassigned.EntertheouttallnumberInthespaceprovidedforeachDaaeofsectionII.ForeachIndividualdischargepoint4separatesetotSectionIIterms(items4ano5)mustbeflliedout.ITO(4QROUhOWATEROISCHARGEINFOCMATION(OONOTINCLUOEDEEPWELLINJECTIONINFORMATIONINTHISITEM>A.-O.TheapplicantshalladdresseachofthesepartsIfthedischargetronthisouttalIlstotnearoundrater.ITEM5EXISTINGOREXPECTEO(FORANEWOISCHARGE)WASTEWATERCHARACTERISTICSOFGRCUNOWATERCRSURFACEWATERDISCHARGE(OONOTINCLUOErLLINJINININHA.TheaDDIleantshallreportavailabledischargedata(realdataforexistingdischargeorexoecteddatafor4Droooseddischarge)fortneDarenetersaslisted.Theseparametersshallbeaddressedforeither4surfacewaterdischargeorasappropriateforegroundwaterdlscnarge.Forassistanceindeterminingappropriateparameters4groundwaterdlscharoeapplicantmaycontacttheGroundwaterOualityolvlsion,Pe(mitsSectionortheappropriateGroundwateroualltyolvlslon'5OlstrlctotfIce.Theapplicantshallreportthesampletypecodebestdescglblngeachreportedplaceofdata.seecodingonthelettmarginofthistore.ItthisouttallIs4su>faceraterdischaroe.theapplicantmustreportquantitativedataforeachparameterIdentified4anov..eaoomtovesaaa~a~.so:aolsttae~oaotvoevesaetlatl.aao~aaaostasteevetttal~aoolloatlo.B.IfdatalsavailableforotherparameterSnotlistedaboveInA.orotherpartsotthisaDPlicatlontheapplicantshouldreportthatdataIntheblankspacesprovidedInthl5part.NOTES:I.UnitcodestorparanetersreportedInpartsAand8canbetoundontheletthandsideotthisform.2.GrabsampleshallbeusedtoanalysetorpH,temoerature,totalphenols,residualchlorine,oilandgre4se,andfecalcoliformIn4surfacevaterdischargeunlessotherfrequency-smnpl~typeanalysesareavallabl~~SeeGlossary(page48)tordetlnltlonotgrabsample.24-hourcompositesamplesshelIbeusedtoanalysetorTotalB005,coo,Toc,AnmonlaNitrogen,andTotalSuspendedSolidsIna5urtaoevaterdischargeunlessothertrequency-sampletypeanalysesareavallabia.seeGloss4ry(page48)tordefinitionofcompositesawple.4.REPORTINGOFINTAKEOATA.Youarenotrequiredtoreportunlessyouvishtodemonstrateyourellqlbllltytor4"net"effluentIimitationtoroneot'orepollutants,thatIs,anetfluentlimitationadJustedbysubtractingtheaveragelevelofthepollutant(s)DresentInyourIntakevater.NpOESregulationsallownetlimitationsonlyIncertainclrclastances.Todemonstrateyoureligibility,reporttheavertx)eoftheresultsotanalysesonyourIntakerater(Ifyourvaterl5tre4tedbeforeuse,testthevateratterItIstreated),andattach4separatesneercontainingthetollovingtorebenpollutant:(4)A5taten>>ntthattheIntakeraterl5drawnfrohthebodyofvaterIntowhichthedlsch4rgeIsmade.(Otherwise,youarenoteligibletornetlimitations.)Ib)Astatementottheextenttowhichthelevelotthepollutantlsreducedbytreatmentofyourwastewater.(YourlimitationsvillbeadJustedonlytotheextentth4tthepollutantIsnotremoved.)(c)vnenapDllcable(forexampl~,whenthepollutantrepresents4classofccmpounds),4demonstrationottheextenttornlcntheDollutant5IntheIntakeveryphyslc4!Iy,chemically,orbiologicallytranthepollutant5containedInyourdischarge.(YourlimitationsriIIbeadJusteoonlytotheextentthattheIntakepollutantsdOndtVaryfraathedlSChargedDOIlutentS~)Ifyouhavetroormoresubstantiallyindentlcaloutta(15,youmavrequestpermissionfranyourpermittingauthoritytosmnpleandanalyzeonlyoneouttalland5ubmlttheresultsottheanalysistorothersubstantially~dentlqaiOutfallS.IfyaurrequeatISgrantedbythepermittingauthqrity,OnaSeparateSheetattaChedtOtheapplicationtermtdentifyvhlchoutfallyoudidtest,anddescribevhytheouttallawhichyoudidnottestaresubstantiallyidenticaltotheoutfallwhichyoudldtest.36 SEEINSTRUCTIONSONREVERSESIDESECT1ONlIPERMIT~MIOQOS827NUMBEROODoPRIORITYPOLLUTANTSANDADDITIONALINFORMATIONFORSURFACEWATERDISCHARGEONLYTHEFOLI&IINttRSXESTKDIIHRWTION~sAIXJIESSEDSEJMQJIFACEHATERDISDWJXIKRS>>EJTE)NBfUSKDISOwXIERS2JBLLPROVICEKPPKCIKDVALIKSFCRTHEIXJANflTATIVEANDIXWLITATIVEINFORIWTICNREIXKSTEDBEIJJI>>AeISTHISFACILllVAPRIMARYIMXJSTRY?(RKFBITOTABIEIAPJGK+(IFW,GOVO)(IFYSGOTOB)BeINDICATETYPECFPRIIWIYIMXJSIRYASLISTEDINTABJEIAPA%Q.ICCNTIMKHIIHC.)CeGOESTHISOUIFALLDISCHARGECNTAIKANYPROCESSHASTKHATKR?(IFMrGOTOE)(IFYES>GOTOD)DeIWICATKNIICHGt'JHSFRACTICNSMJSTBETESTEDFOR>>(RKRRTOTABLEIAPJVKJII)IDIEIFCREACHGt'JHSFRACflONOtKCXKD>EAOISPECIFICORGANICTOXICPOUJJTANTHIIHINEACHFRACTIONt$5JBEANALYZEDFOR(SEETABLEIIAPAGE92~INADOITI0I>ALLPRII>>ARYIIClJSTRYAPPLICANISHITHAPROCESSIWSTKHATKRDISCHARGEggJPROVIDEOSWTITATIVEIWTAFCREARTHTOXICPOLJJJTANTIHlAKEIIIAPAfE~~eRKcRDAIJ.DlrAoNF0YtsPROVIDED(ITEM7)INTHISBoozer.(CNTIMKHITHEKBKIJBI)LECWRQ~>>emAnalysisPerQer>dere>reJ.B.BeauboeufTargetPermitPre,eEffluentLimitsPESTICIDEKeIFJKg,QRFJcEHATERDrsowRGKAPPLIGANT(PRIIwRY0R$Kc06NYIMxrsTRY)>RKGARKLEssOFTHEIVPEOFDISCHJJYIK>rEM'RIWSREASONTOBKUKVKTIWTANYPOIJJJTAHTLISTKDINTAKEIIAANOIVAPAGES4JL9XlsDISCHARGEDFR0tJHYOJIFAL4TICIXJWTITATIYEDATAggjfBKPRKIVIWhRECRDALLDATA01PORCPROVIDED(ITKH7)IN1HIS$00ZkT>>FeIFNfQRFJCKlWTKRDISCJWRGEAPPLICANT(PRIIWIYORSEQÃCNIYIIKtJSIRY)>RKGJJOXKSSOFTYPEOFDISCNVIGK>IMEfsORHISREISCNTOBKUEVEAHYPOIJJJTJHIBUSTEDINTAKEVAPAGE~AREDrsftwXMFR01ANYtJJfFAJJ.TIEAPPUCJItfrrrKL(DESCRIBEREASONSI0tTIEPOIJJJTJHTBEI16PRKSBITJJKJPROVIDEJJIIAVAILABLKQOWTITATIVEDATA>>REcRDILLDATA01F0wsIROYIKED(ITBI7)INTHlsBOOLEY>>GeAIJ.SLRFACEIW18tDISCHNXIEAPPUCJNIS(PRIMARYAWSKCOIJJtfIHIXISlRIKS)0RfgFAcrtNKs2>4>f~lllrcJKJ$4%%wxYAcKrrcAcID(2>4>M)J.JI,WIRIDKJxtsPINwxrPR0Ic(srLttKx,2,rr,5,TP)~Pr>TRIKMJXKPIEMN(T~KPIcRHBIAaacl4%1RKNfr(AIJDlTAF0tTl%AlotKISJSTBEGIMRATKDIIIMISTAwJRDawmcALCJUIYIAT10tProCBXNKS)ORl0l$tsORHA5REASCNTOBELIEVETHlrTCKD1$0tHIYBEPRKSBITINT%1RDISCHARGE>>RKP0IT>>XJAUTATIVEDATA>GE%RATKDHfrCHtgiKDASCRKKHlwPwCKDIJIKwTTKDHITHAJWLmCJLSTAwARDS,FORz.a,I8,-TKIRJCJKJJIKXJIM~IOXIN(TCD)eRECISIDALLDATA0lF0YtsPROVIDED(ITBI5INTHISBOOLEY>>IFIIEQJIFACEHATERDISCJWRGEAPPLICJWfXMloORIWSRKISCNTOMUEVK%lrBIOIJXIICAtTOXICITYTESTSHEREHADEINll%LASTlINEE(5)YEARSOIANICFTIEAPPLICANT5DISOWNIKSORONARKCEIVIWHATBtINRKLAT10ITOADISCIWSKsPROVIDETHtsIIRNHAT104ASANATTAOIKÃfTOTH15APPUCAT101>>XIFACNRACtthtCRAT0IYCRKKYIILTIWFl&PBRÃIEDJJN'OFT%AMAVSKSRKIXJIRKDBYTHISAPPLICAT101>PRCNIDETIENt%AMJAKKNESSOFEAOILAB0IATDIYORFIIIIAWTIEAWLYSESPKRFIR%DASANATTAKJI%HTOFTHISAPPLICATION>>1.>>00VIXIDISOWEIKANYOIIERTOXICCRIILXNIIXJSDKHICALSlaSTJNCKSWrLISTEDIHTAKESIYPAGEttAWIIATINOAIVAPIPES~~IFVK5>TISHIOBIflsYTIEIJKMICALQSISTAWKSAOESTIHATETIEFINILKFFLIKHTC0CBIIRAT10IS~QJ>>HITTHISIIARQTICNASANAITAOtKtlTIO'HISAPPUCATION>Qrrrrrr>uoar/ear>>reremrr.N/AaPRESKHf/DATAlsATTAIMDwrAPPUCABLdBKLIEYKDABSBITN/A0PRESENT/DATAISATTADEDwrAPPUCJBLFJBKUEVKDABSENTN/AQPRESENT/DATAISATTADEDgwrAppucABLEQAPPuCABLE?'SKEAITADED.QwrAppucABtzg]APPLICJBLe'SKEATTADNDQXwrJppucABtzAPPLICABts/SKEATTAKJND INSTRUCTIONSFORC04PLETINGSECTIONIIITEM6ThisformrequiresInformationonasoeciflcoutfalIdischargingtothesurface>>stere.ENTERTHEPERMITNUMBERINTHEBOXATTHETCPOFTHISFORM.THEPERMITNWBERCANBEFOUNDCNTHEFRONTPAGEOFYOUREXPIRINGpERHIT.Itthisisane>>ornotorevlouslypermittedfacility,thenleaveblankandanuroer>>illbeassigned.EntertheoutfallnumberInthespaceorovldedforeachpageofSectionII.ForeachIndividualdischargepointaseparatesetofSectionII,Item6formsmustbefilledout.ITEM6PRIORITYPOLLUTANTSANOADOITIONALINFOPHATIONNOTE:NOTE:lfyouhavetroormoresubstantiallyIndenticaloutfalls,youmayrequestpermissionfrcmyourpermittingauthoritytosamoleandanalyzeonlyoneoutfallandsubmittheresultsoftheanalysisforothersubstantiallyIdenticaloutfalls.Ityourrequest159rantedbythepermittingauthority,onaseoaratesheetattaChadtotheapplicationformIdentifyrhlchoutfallyoudidtest,anddescribemytheoutfallsrhlchyoudidnottestaresubstantiallyIdenticaltotheoutfallrhlchyoudidtest.40CFRPartI22.2l(g)(8),Friday,AbriII,l98S,providesforaSmallBusinessExemptionfromthereportingofquantitativedatafororganictoxicpollutantsandtoxicpollutantsasrequiredbyPertl22.2I(g)(7)(ll)(A)or122.2I(g)(7)(lil)(A).A.K.Thesepartsareself-explanatoryanddonotrequirefurtherInstructions.SimplygothrougheachpartanddoasIndicated.andE.-J.0.SeveralIndustrialcategoriesandsubcategorieshavebeenexemotedfrtmsubmittingdataoncertainGC/MSFractions(40CFRPartl22,Vol.48,No.64,Friday,AprilI,lgBS,NotesI,2,andS).~Revle>>thefolio>>lnglisttodetermine>>batheryourfacilityqualifiestobeexceptfreereportingGC/MS(GssChrcnetogrsphy/MassSpectroscopy)Fractions.GC/MSFractionTestingandReportingExemptionsTextIIeillIIsIndustry-AllfourGC/HSorganicfractionsIntheGreigeHillsSubcategory.-PesticidefractionInelIothersuboartsofthisIndustry.OreHlnlnandOresslIndust-Volatile,base/neutral,andpesticidefractionsIntheBaseandPreciousHetalsSubcategory.-AllfourGC/HSorganicfractionsInallothersubcategoriesofthisIndustry.GunandUoodChemical~IndustrpesticidefractionintheTaliOilRosinSubcategoryandthehos(nBasedOerlvatlvesSubcategory.-pesticideandbase/neutralfractionsin~liothersubcategoriesofthisindustry.PulandPaperIndust-PesticidefractionInPaoergrsdeSulfitesubcsteqorles(suboartsJand0).-base/neutralandpesticidefractionslnoeinksuboart0,olssolvinqKraftsubpartF,andPaperboardfromvast<<PaperSubpartE.4-Volatll~,base/neutral~pesticidefractionsIntheOCT8)cachedKraftSubOartN,SeelmhcmicalSubparts8andC.,andNonlntegratedFinePaoersSubpartR.'c-Acid,base/neutral,andoestlcldefractionsInFine4)cachedKraftSubosrtI.oissolvlngsulfitePuloSuboartK,Ground->>OOdFinePapertSubOart0~NarketOleaChedKraftSubpart0,TISSuefraeUaStepaperSubpartT,andNOnlntegratedQSSuePapersSubpartS.'teamElectricPo>>eraslantIndustHaterFlyAshandOottt4eAshTransportMaterprocess>>astestreams38 oi'~~~'lI~~~~~',~~'~C'.~~O'~'I~~'~O'~~~'I~)I~;r'~Ol~~I)'~'I'~~l~'I%)I)~~~~~~'~~'j)BE~~IIII'I~)~I~~~\'I~o~~I~~I~1~'~'~IIJj~~I~~I~)~'~~I~~~~~~'I~r~I~1~I~((I.~C~~I~1'~I~~''I~1~I~~I~1'~I~~~~~C~I~~I~~I~1~I~~I'~I~1~I~~Ie'~~'~I~~~~C'~~1~I~~Ie)~I~I~~I~~~~~I~1~I~~I~~II~I'~~~~~~~~~~rj.~~~'~e)I~'IW~'~~I)lS>;I~~~~~~III~~~~~~~~~~~~~~~~~ INSTRUCTIONSFORCCMPLETIHGSECTIONIIITEM7ThisformIstobeusedbybothSurfaceandgroundvaterapplicantstorecordInformationonanyHlchlgancriticalmaterial,E.P.A.prioritypollutant,orhazardoussubstanceInvhlchthisappIlcationrequiresdatatobeprovided.ThisvouldIncludeanychemicalsubstancefrantneHlchlganCriticalMaterialsRegisterITabl~IV),theE.P.A.PriorityPollutantListing(TableV),orTablesIIA-VAvhlonIlatSOrganlCTOXICPOIlutantS,OtherTOXICPOIlutantS,COnVentlOnalandHcnocnVentlonalPOIlutantSandHaZardOuSSubstances.ITEM7CRITICALMATERIALS,PRIORITVPOLLUTANTSAHO/ORHAZAROOUSSUBSTANCESINTHEDISCHARGEMaterialI,2,3...8A.Listthinameotthechemicalsubstance(criticalmaterial,prioritypollutant,orhazardoussubstance)franTablesIV,VandIIA-VAasreoulradIntneboxmichyoucheekedInA.I-3,above.Entereachchemicalsubstance'spaneeternumberaslistedInTablesIV,VandIIA-VAlfProvided.B.ProvidetheaverageconcentrationotthechemicalsubstancenanedInA.IndicatethesampletypeusedandthenumberofanalysesmadetoprerldetheconcentrationdataforthechemicalsubstancenmnedInA.C.ProvidethemaximumconcentrationanddeterminethemassloadingotthechemicalsubstancenmmzdInA.HOTES:I.2.Itonlyoneanalysisuasmadeforachemicalsubstancethenrecordthatdataasamaxisxzsvalue.Itmorethanoneanalysishasbeenmadetorachemicalsubstancethenprovideanaveragevalueotthoseanalysesandthemaximusvalue~ThisSectionII,Itea1,OataSheetprovidesspaceforrecordingdatafor8chemicalsubstancesIMaterlals).Additionalspacetorrecordingofdataformorethan8MaterialscanbemadebymakingcopiesofthisItem1OatsSheetasneeded.ItlsalsoimportanttouseaseparatesetofOataSheetsfoteachappllcabl~reportingreculrmaentaslistedInA.l3.andtoreachouttali~3.Ratertothelettmargintorthecodenumberrepresentingthesmapl~typeusedandtheappropriateunitcodes. Loci<heedAnalyticalServicesINDIANAMICHICANPOWERCOMPANYSAIVIPLEANALYSISSUMMARYPACKAGEFORVOLATILEANDSEIVII-VOLATILEORGANICS,-PESTICIDE/PCBS,CHLORIDE,NITRATE/NITRITE,SULFATE,FLUORIDE,CYANIDE,IVIETALS,ANDMERCURYLOG-INNUMBER:QUOTATIONNUMBER:L1009Q331620DOCUMENTFILENUMBER:1229485 ~toe/rheedelL'/a~a7rllce~rv"l.s)'ar~-r"<<~~~~~~LockheedAnalyticalServices975KellyJohnsonOriveLasVegas,Nevada891194705Phone:(800)3614220Fax:(702)361~February4,1994Mr.RockyBeemCookNuclearPlant1CookPlaceBridgeman,Ml49106RE:Log-inNo.:QuotationNo.:DocumentFileNo.:L1009Q3316201229485TheattacheddatapackagecontainstheresultsofanalysesonsamplesthatweresubmittedtoLockheedAnalyticalServicesonDecember29,1993.Thesampleswerereceivedat5'C.SUMIVIARYANALYSISSTATEMENT:InorganicsAllgroundwatersampleswerereceivedingoodcondition,onDecember29,1993.Allsampleswereanalyzedwithinthemethod-specificholdingtimes.Themethodblankswerefreeofcontamination.AllInternalQualityControlwerewithinacceptancelimitswiththefollowingexception:Thematrixspikerecoveriesforbariumandseleniumwereslightlyoutsideofacceptancelimits.TheacceptablerecoveryoftheLaboratoryControlSamplessupportsthattheanalyticalsystemswereoperatingwithincontrollimits.Thereportingdetectionlimitfornitritewasraisedto0.50mg/LforsampleS.SewagePlantEff.(L1009-4)duetointerferencesfromchloride.OrganicsMethod8260Allcalibrationsandqualitycontrolcriteriaweremetwiththefollowingexceptions:Allsampleswereanalyzed,initiallywithinholdingtimesbutfailedsurrogaterecoveryQClimits.ThesampleswerereanalyzedonedaybeyondthemethodspecifiedholdingtimeandallsamplesmetsurrogaterecoveryQClimits.Tentativelyidentifiedcompoundsearcheswereperformedonallsubmittedsamples.Onlythereanalysesarereported. COOKNUCLEARFebruary4,1994PAGE2Method8010/8020Allcalibrationsandqualitycontrolcriteriaweremetwiththefollowingexceptions:Thematrixspikeandmatrixspikeduplicateprecisionfor1,1-dichloroetheneexceededtheQCcriteriaalthoughallpercentrecoverycriteriaweremet.Dataqualityisnoteffected.Method8270Allsampleswereextractedandanalyzedwithinthemethodspecifiedholdingtime.Allinitialandcontinuingcalibrationcriteriaweremet.Bis(2-ethylhexyl)phthalatewasdetectedinthemethodblankat1.3ug/L.Therewasnoothercontaminationdetectedinthemethodblank.PercentrecoveriesforallsurrogatecompoundswaswithinQClimitsforallsamplesanalyzed.Alaboratorycontrolsample(LCS)andlaboratorycontrolsampleduplicate(LCSDUP)waspreparedandanalyzedwiththissetofsamples.ThepercentrecoverycriteriaforallspikedcompoundswaswithintheQClimitsaswastherelativepercentdifferencebetweenthetwo.Theresponseforbis(2-ethylhexyl)phthalateinsampleTRANS.CATCHBASINexceededthecalibrationrangeintheinitialanalysis.Thesamplewasreanalyzedatadilutionof1:4andallcompoundsfellwithinthecalibrationrange.Bothsetsofresultsarereported.Method8080AIIsampleswereextractedandanalyzedwithinthemethodspecifiedholdingtime.Allinitialandcontinuingcalibrationcriteriaweremet.Nocontaminationwasfoundinthemethodblank.FewofthesurrogatespikerecoverieswerewithintheQClimitsduetoanapparentspikingsolutionproblem.Dataqualityisnoteffectedsinceallpercentrecoverycriteriaweremetforthelaboratorycontrolsampleandlaboratorycontrolsampleduplicate.Notargetcompoundsweredetectedabovethereportingdetectionlimitandtherewasnodilutionorreanalysisperformed.IfyouhaveanyquestionsconcerningtheanalysisorthedatapleasedonothesitatetocontactJamesL.Jordan,(702)361-3955.ext.289.ReleaseofthisdatareporthasbeenauthorizedbytheLaboratoryDirectorortheDirector'sdesigneeasevidencedbythefollowingsignature.ncerely,JamesL.JodanClientServicesRepresentativeJLJ/atcc:ClientServicesDocumentControlDepartment ~Wc/rheedLockheedAnalyticalServices975KellyJohnsonDriveLasVegas.Nevada89119-3705Phone:(800)582-7605Fax:(702)361%146February17,1994Mr.RockyBeemCookNuclearPlant1CookPlaceBridgman,Ml49106
DearRocky,
Peryourrequestduringourphoneconversationthismorning,thefollowingisanexplanationoftheprocedureusedforthedeterminationofthenon-standardorganiccompoundsinyourgroundwatersamples.Thesampleswereanalyzedusinginstrumentsthatweresetupforstandardmethods8260and8270.Afewofthecompoundsonyourlistsofanalytesarenotstandardmethod8260or8270compounds.Oncethesamplesareanalyzedandachromatogramwasobtainedforthesamples,allpeaksthatwerepresentinthesamplesthatdidnotcorrespondtooneofthecalibratedcompoundswereinvestigatedfurther.ThisinvolvedtakingthemassspectraobtainedfromthesepeaksandcomparingthespectratoanNISTlibraryofspectra.Thislibrarycontainsapproximately52,000knownmassspectra.Themassspectraoftheadditionalanalytesofinteresttoyouarecontainedwithinthislibrary.Noneofthenon-standardanalytesweredetectedinanyofyoursamples.Forthenextquartersroundofsampling,weareendeavoringtoobtainthestandardsforthesecompoundssothattheywillbecalibratedforintheanalysesofthosesamples.IfyouhaveanyfurtherquestionsorifIcanbeofanyfurtherassistance,pleasedonothesitatetocallmeat(702)361-1626ex.289.'ncerely,JamesL.rdanProjectManagercc:M.Butler I~4~4gIg~~~Ir~IIr~'ll~I'll'I'I~..I'.~I'I~I'III~I'~~~~'~,III~I'II~II~~~II'I~~~I~I'I'Ir'III.I~I.IIIII~~~II~I'~~~I~I'II'.~~I~~~~~~~~~~~~~I~I~~r~~~I'~~~~~~~~~~I~'~r~II~~~I~~~'~~ ai~a~~~~~~~~I~III'~'~I~~~~I~III~'~~~~'II'~II'II~'~I'~~~III~I~II~~II~III'~I~I~II'III~IIII'I~~~~~~~.II~~II~II'III'I~~IIII~~'II'II~~~~~~I~~~II~~~'~I~~~~II~ VOLATILEORGANICANALYSISRESULTSGC/HALLANALYSESUSINGEPAMETHOD8010linmIID:TRDaoil:2-DDateAnalzed:04-JAN-94Matrix:WATERAnalticalBatch¹:122093-801020-0-3LALmlID:L1DRiv:-DDilutionFactor:1QCBatchID:122093-801020-0-3BCMBFBrroRvr11492Limi65-12560-120ConstituentDihlriflrmhanhlrmhnVinIchlorideBrompmethanehirhnTrihlrflrmhn11-DichloroetheneMethlenechlorideran-1-Dihlrhn11-DichlrhanChloroform111-Trichloroethanernrhlri12-DihlrhnTrichloroetheneTCE12-DichlororoaneBrmihlrmhn2-hlrhIvinIhercis-13-Dichlororoenetrans-13-Dichlororoene11-TrihlrhnTerhlrhnPDibromochloromethaneChlorobenzeneBrmfrm112-TrIrhn13-Dichlorobenzene14-Dichlorobenzene12-DichlorobenzeneConcentrationIyg/L)<0.50<3<6<4<0.5<0.5<0.5<2ReportingDetectionLimitIL0.50.50.5DataQualifier(slLOCKHEEDANALYTICALSERVICESAVsJ VOLATILEORGANICANAlYSISRESULTSGC/PIDANALYSESUSINGMETHOD8020linmIID:TRDII:2-DEDateAnalzed:04-JAN-94Matrix:WATERAnalticalBatch¹:122093-801020-0-3LALmIID:L1DRiv:2-DEDilutionFactor:1QCBatchID:122093-801020-0-3TFTBFBrroRever9495Limi70-12075-120BenzeneT'InConstituentConcentrationIL0.52ReportingDetectionLimitIL0.5DataQualifiershirnnEthIBenzenem-Xlene-XIn1-'n14-Dichlorobenzene12-Dichlorobenzene<2<2LOCKHEEDANALYTICALSERVICESh4 VOLATILEORGANICANALYSISRESULTSGC/HALLANALYSESUSINGEPAMETHOD8010linmlID:TR-ADII'-DEDateAnalzed:04-JAN-94Matrix:WATERAnalticalBatch¹:122093-801020-0-3LALmIID:L1DR'v:2-DDilutionFactor:1QCBatchID:122093-801020-0-3BCMBFBrrRvr'/12086QLimi65-12560-120ConstituentDihloriflurmhanhlrmhnVinIchlorideBromomethanehlrhnTrihlrflrmhn11-DichloroehenMethlenechloridern-1-Dihlrhn11-DihlrhChloroform111-Trichloroethanernrhlri'l2DihlrhnTrichloroetheneTCE12-DichlororoaneBrmoihlrmhn2-hlrhlvinlhrcis-13-Dichlororoenetrans-13-Dichlororoene112-TrihlrhnTerhlorhnPEDibrornochloromehaneChlorobenzeneBrmfrm11-Trhlrhn13-Dichlorobnzene14-Dichlorobenzene12-DichlorobenzeneConcentration(yg/L)<0.50<3<6<4<0.5<0.5<2ReportingDetectionLimit/L0.50.50.5DataQualifier(s)LOCKHEEDANALYTICALSERVICESnr.Vv VOLATILEORGANICANALYSISRESULTSGC/PIDANALYSESUSINGIVlETHOD8020linmIID;TRS-AALmlID:1DII-DEDRiv:2-DDateAnalzed:04-JAN-94Matrix:WATERAnalticalBatch4'22093-801020-0-3DilutionFactor:1QCBatchID:122093-801020-0-3TFTBFBrrRvr97QLimi70-12075-120BenzeneTiunConstituentConcentrationIL0.53ReportingDetectionLimit/L0.5DataQualifiershlrnnEthIBenzenem-Xlene-Xin1-Dihlrnn14-Dichlorobenzene12-Dichlorobenzene<2<2LOCKHEEDANALYTICALSERVICES06 ~~i~~~a~~o~~~~~~.~~..~~.~o~~~~....~~~~I'~~'~e.I~'>e~~~~0s.)~I>o~~~~~~I~~~J~~~'~~~I~~~~~~~~~~~~~~~..~~..~~~~~~~~~~~~~~~~~~~~~~~~o~~~~s~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~-~~~~~!~~~~ VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260ClientSamleID:TRSLALSamleID:L1009-41Page2of2ConstituentDibromochloromethanehlrnznEhInznm-Xleneo-XlenernBromfrm1122-Tetrachloroethane13-Dichlorobenzene14-Dihlornzn12-DichlorobenzeneConcentrationIL<5<5<5<5<5<5ReportingDetectionLimitILDataQualifiersLOCKHEEDANALYTICALSERVICES VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260TENTATIVELYIDENTIFIEDCOMPOUNDSClientSampleID:TRSDateReceived:29-DEC-93Matrix:WATERAnalyticalBatch:011094-8260-F2LALSampleID:L1009%1DateAnalyzed:114AM-94DilutionFactor:1QCBatchID:011094-8260-F2TentativelyIdentifiedCompoundEstimatedConcentrationIyg/L)(10RetentionTimeIminutes)0.00DataQualifierls)LOCKHEEDAIVALYTICALSERVICES ~0JI+aa~~I~~~-~~III'.~-~~~~.....~~I~~~~~~.~~I.~I~I~~~~~~a~'~~~I~~~~~~~~~~~~~-~~~~~~s~~~~~~~~I~~-~~~~~~'~~-~~~.s~~~~~~~~~~~~~~~~~~~~~~I0~~~~~~~~I~~~~~~~~~~I~~~~ ~i~~J~~~~LJ~~~~I~-~~'--~~~~~~~~a~~~~~~~~~~~~~~~~- VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260TENTATIVELYIDENTIFIEDCOIVIPOUNDSClientSampleID:TRS-QADateReceived:29-DEC-93Matrix:WATERAnalyticalBatch:011094-8260-F2LALSampleID:L1009%3DateAnalyzed:114AN-94DilutionFactor:1QCBatchID:011094-8260-F2NONETentativelyIdentifiedCompoundEstimatedConcentrationIyg/L)(10RetentionTime(minutes)0.00DataQualifier(s)LOCKHEEDANALYTICALSERVICES20 SElVllVOLATILEORGANICANALYSISRESULTSFORGC/MSANALYSESUSINGMETHOD8270IinmIID:TRDateCollected:28-DEC-93Matrix:WATERAnIiIBh¹:ill4-7-8QCBatchID:8270-SEMIVOLATILES-3964LAmIID:1-2DateReceived:29-DEC-93DilutionFactor:1Dxr4-AN-4DateAnalzed:11-JAN-94P1f2SURROGATERECVERY0/2-FluorohenolPhenol-d,Nitrobenzene-d,2-FIuorobihenI24-TribrmhnIp-Terphenyl-d,44126595599QCLimits21-10010-9435-11443-1161-1233-141PhenolninConcentrationL<10ReportingDetectionLimitL10DQbis2-ChloroethIether2-hlrhnl1-Dihlrnzn14-DichlorobenzeneBenzIalcohol1-Dihlrnn2MhIhnIbis2-ChloroisoroIether4-MethIhenolN-Nir-Di-n-roIminHxhlrhnNitrobenzeneIsohorone-NirhnI24DimehIhnIBenzoicacidbis2-Chloroethoxmethane4DihlrhnI14-TrihlrnznNahthalene4-ChloroanilineHxhlrin4-hlr--mhIhnI2-MethInahthaleneHexachloroccloentadiene<10<10<10<10<10<10<10<10<10<50<10<10<10<10<1010101010101010501010101010LOCKHEEDANALYTICALSERVICES4v ~e~~J~I~~:~~.I~I'~~.~~~~~~~~II~~~~~~~~~e~~~I~~~~~~~~-~~~~~~~~~I~~~0~~~~~~~~~~~~~~~~~o~~~e~~~~~~e~~~~~~~~'~P VOLATlLEORGANICANALYSlSRESULTSFORANALYSESUSINGIVIETHOD8270TENTATIVELYIDENTIFIEDCOIVIPOUNDSClientSampleID:TRSDateReceived:29-DEC-93Matrix:WATERAnalyticalBatch:011194-8270-BLALSampleID:L1009-25DateAnalyzed:11-JAN-94DilutionFactor:1QCBatchID:8270-SEIVIIVOLATILES-3964UnknownUnknownTentativelyIdentifiedCompoundEstimatedConcentration(yg/L)10020RetentionTime(minutesl6.4430.26Data-Qualifier(slLOCKHEEDANALYTICALSERVICES31 ~i~P~~J~~PI~'~-~~a~I'.-~.~~~-...~~~.~~)~~~PI~~a~~~~P.~a~)P~~~~\I~~~'~~~~~~~~~~~~~~~~~~;:~~:.~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~s~~~~~~~~~~~~~~~~~~~I~~~~~~~ ~k~0li~~~~IP~~)~~'~I~~~~~..~~~~~~'~~~'~~~~~~~~~~~~~e~~~~~~.~~~~I~~~~~~~~~~~~~~~~~I~~a-~~'~I~~~~0~~~~~~~~ VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8270TENTATIVELYIDENTIFIEDCOMPOUNDSClientSampleID:TRS-QADateReceived:29-DEC-93Matrix:WATERAnalyticalBatch:011194-8270-8LALSampleID:L1009-27DateAnalyzed:29-DEC-93DilutionFactor:1QCBatchID:8270-SEMIVOLATILES-3964UnknownUnknownTentativelyIdentifiedCompoundEstimatedConcentration(yg/L)100RetentionTime(minutes)5.286.44Data..Qualifier(s)HydrocarbonUnknownHydrocarbonHydrocarbonHydrocarbon2029.9730.2631.9832.9433.86LOCKHEEDANALYTICALSERVICES PESTlclDEANALYSESRESULTSBYGC/ECDUSINGMETHOD8080FORCOOKNUCLEARPLANTClienSamleID:TRDaeColleed:28-DE-9DateExtracted:04-JAN-94Matrix:WATERAnalticalBatch¹:012094-8080-A-1LALmIID:I1-17DaeReceive:29-JAN-4DateAnalzed:21-JAN-94DilutionFactor:1QCGrouID:8080PEST/PCBS3965SURROGATERECOVERYooTCMXDCB52'CUmits60-15060-150A-BHCB-BHC-BHD-BHCConstituentConcentration/L<0.05<0.05ReportingDetectionLimit/L0.050.0.05DataQualifier(s)HEPTACHLORALDRINHEPTAHLOREPOXIDEG-CHLORDANEENDOSULFANIA-CHLRDANE44'-DDE44'-DDTDIELDRINENDRINENDOSLFANII44'-DDDENDRINALDEHYDEENDOLFANLFATEMETHOXYCHLORTOXAPHENEPCB-1016PCB-1221PCB-12PCB-1242PCB-1248-PCB-124PCB-120TECHNICALCHLORDANEMIREXTCMX-tetra-chloro-meta-xyleneDCB-Deca-chloro-biphenyl<0.05<0.05<0.05.5<0.1<0.1<0.1<0.1<0.<5<0.10.050.050.050.0.10.10.10.10.10.<0.1LOCKHEEDANALYTICALSERVICES5' ~II~~~~~III~0~~-~e~~.III'..~-.~~~~~'~~e~~'~I~~~~~I~~~~~~~~~~I~II~I~I'~~~I~~III~I~I~~~~~~~~'I~~~~~~~~~~~~~~~~~~I~I~I~I~I~~~I~I~~~~~~~~~~'~~~~~~~ ~~~..~~~.::::~~~~~~~~~R5%gggg~gpss~%%~55%~gggg$gg~55%~55%~gpss~55%R55%RE%R55%g$gg~gpssR5%R%%~55%g$@g555%R55%R5%~~~~~~~~~~~I~~I~~~~I~~II~~~~~~I~~~~~~~~~~'I~~~~~'~~~~~~~~~II~~~~~~~~~~~~~~~~~I~~~I~~I~~I~~I~~II~~~~~II~~~~~~~I~~~~~~I~~I~~~~~.o:~~~'~~~~~~~~'~'~~I'~~I'~~~~~'~'~~~'~'~~~'~~~~~'0~~~~'lIll'~0~~II'I~'~'I'~'~l' METALSRESULTSClientSamle'ID!'TRS-QALALBatchID(s):1220imDate.Collected:12-28-93DateReceived:12-29-93Matrix:,round;water.'0469095-040-3N.<<?,')'yCo'nstituantsAluminumAntimonArsenicBariumBeiliumBoronCadmiumChromiumCobaltCoerIronLeadManesiumMananeseMercuMolbdenumNickelSeleniumSilverSodiumThalliumTinTitaniumVanadiumZinc-."Method6010602060206020602060106020602060206020601060206010602074706020602060206020601060206020601060106020Concentration"imILl<0.20<0.060<0.010<0.20<0.0050.27<0.005<0.010<0.050<0.025<0.10<0.003170.027<0.0002<0.20<0.0400.0078<0.010890<0.010<0.20<0.10<0.0500.022ReeportlngDetection"UmltlmILl0.200.0600.0100.200.0050.200.0050.0100.0500.0250.100.0035.00.0150.00020.200.0400.0050.0105.00.0100.200.100.0500.020Data~QualWer(s)NNDate'.~'-A'naled,N01-20-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-20-9401-27-9401-07-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-27-9401-20-9401-20-9401-27-94?0':;;:;.L'ALcr.""S"le'1D)L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14L1009-14Comments:LOCKHEEDANALYTICALSERVICES 0~..~:-~~~~~~~~I~~~~~~~tggRRQiittgQiittggpitiigQiittg~~~~~~~~~I~~~~~tt~~~~~~~~~~~~~~~~NIIRÃ8~~'~~'~~~~~~~~~~~~~~~~'~~'~~~'~~~' GENERALCHEMISTRYRESULTSClientSamleID:TRS-QALALBatchID(s):1229imDateCollected:12-28-93Matrix:roundwaterDateReceived:12-29-93PO¹69095-040-3NConstituentFluoride.inmILChloride.inm/LNitrate-Nitroen,inm/LNitrite-Nitroen,inmILSulfate.inm/LAmmonia.Nitrogen,himILTotalCyanide.inmg/LMethod340.2300.0300.0300.0300.0350.1335.2Result0.31200.90<0.01222003.4<0.020ReportingDetectionLimit0.150.0160.0170.0120.590.0500.020DataQualifieris)D(1:10)DateAnalzed,01-24-9412-29-9312-29-9312-29-9312-29-9301-05-9401-03-94LALSamleIDL1009-2L1009-2L1009-2L1009-2L1009-2L1009-6L1009-10Comments:LOCKHEEDANALYTICALSERVICES66 GENERALCHEMISTRYQCDATASUMMARYLALBatch}D(s}:1229imQC'SamleAnalses-ConstituentClientSample,IDLALSampleIDDateAnalyzedReagentBlankDuplicatePrecision(%RPD}Matrix"Spike.Recovery(%}Fluoride,inm/LChloride,inmg/LNitrate-Nitrogen,inm/LNitrite-Nitroen,inm/LSulfate,inm/LAmmonia-Nitrogen,inm/LTotalCyanide,inmg/LTRSTRSTRSTRSTRSTRSTRSL1009-1L1009-1L1009-1L1009-1L1009-1L1009-5L1009-901-24-94<0.1512-29-93<0.01612-29-93<0.01712-29-93<0.01212-29-93<0.05901-05-94<0.05001-03-94<0.0200.20.11079193969612294NbltTheRPDcannotbec'omputed.becausethesampleortheduplicateconcentrationwasbelowtheDetectionLimit.Comments:LOCKHEEDANALYTICALSERVICES6n .".HalliburtonNUSX5FJ++C0RP0RATI0NLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbeiisRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPageICLIENTNAME:ADDRESS:ATTENTIOH:INDIANAMICHIGANPOWERCOMPANYOHECOOKPLACEBRIDGMAN,MI49106-0000MS.JEHILEWIS-CHEMISTRYDEPT.HUSCLIENTNO:06630020WORKORDERNO:55830VEHDORNO:05411000CarbonCopy:SAMPLEID:HUSSAMPLENO:P.O.NO.:TURBIHEROOMSUMP27476P025928469034-040-3HDATESAMPLED:30-DEC-93DATERECEIVED:05-JAN-94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMIHATIOHRESULTUNIT117302AHAW31130415905AALWSulfate,Turbidimetric(asS04)SodilslltTotal(Na)Chloride(asCl)Solids,Dissolvedat180CAtuminun,Total(Al)51mg/L6.3mg/L11mg/L140mg/L0.97mg/LCOMMENTS: A;"';HalliburtonNUSCORPORATIONLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportHo.:00018939SectionAPage2CLIENTNAME:ADDRESS:ATTENTION:INDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAN,MI491060000MS.JENILEWIS-CHEMISTRYDEPT.HUSCLIENTHO:06630020WORKORDERNO:55830VEHDORHO:05411000CarbonCopy:SAMPLEID:NUSSAMPLENO:P.O.NO.:TURBINEROOMSUMP27476/FILTEREDP025928569034-040-3NDATESAMPLED:30DEC-93DATERECEIVED:05'JAN-94APPROVEDBY:Kieda,ChuckTESTLNCODEOETERMIHATIONRESULTUNITS1AALFAtuainua,Dissolved(At)~0.3mg/LCOMMENTS:. L'HallibulltonNUS%1K++++C0RP0RATI0NLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage3CLIENTHAME:ADDRESS:ATTENTION:INDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAH,MI49106-0000MS.JEHILEWIS-CHEMISTRYDEPT.NUSCLIENTNO:06630020WORKORDERHO:55830VENDORHO:05411000CarbonCopy:SAMPLEID:NUSSAMPLENO:P.O.HO.:TURBINEROOMSUMP27503P025928669034-040-3NDATESAMPLED:31-DEC-93DATERECEIVED:05-JAN-94APPROVEDBY:Kieda,ChuckTESTLHCODEDETERMINATIONRESULTUHITS1I7302ANAW311304I5905AALWSulfate,Turbidimetric(asSO4)Sodiun,Total(Ha)Chloride(asCl)Solids,Dissolvedat180CAtuminun,Total(Al)53mg/L6.0mg/L10mg/L130mg/L0.98mg/LCOMMENTS: "'.HalhburtonNUSimper+++C0RP0RATI0NLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684,January18,1994ReportNo.:00018939SectionAPage4CLIENTNAME:ADDRESS:ATTENTIOH:INDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAH,MI49106-0000MS.JEHILEWIS-CHEMISTRYDEPT.NUSCLIENTNO:06630020WORKORDERHO:55830VEHDORNO:05411000CarbonCopy:SAMPLEID:TURBINEROOMSUMP27503/FILTEREDHUSSAMPLEHOP0259287P.O.NO.:69034-040-3NDATESAMPLED:31-DEC.93DATERECEIVED:05-JAN-94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMIHATIONRESULTUHITS1AALFAluninun,Dissolved(AI)0.3mg/LCOMMEHTSt
- dL'HalliburtonNUSwaarC0RP0RATI0NLABORATORYANALYSISREPORT"NUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportHo.:00018939SectionAPage5CLIENTNAME:ADDRESS:ATTENTION:INDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAH,MI49106-0000MS.JEHILEWIS-CHEMISTRYDEPT.HUSCLIENTHO:06630020WORKORDERHO:55830VENDORNO:05411000CarbonCopy:SAMPLEID:HUSSAMPLEHO:P.O.NO.:TURBINEROOMSUMP27506P025928869034-040-3NDATESAMPLED:01-JAH-94DATERECEIVED:05-JAH94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMIHATIONRESULTUNITS1l7302AHA'W311304l5905AALWSulfate,Turbidimetric(asS04)Sodiun,Total(Na)Chloride(asCl)Solids,Dissolvedat180CAtuninua,Total(Al)52mg/L5.6mg/L10mg/L130mg/L1.6mg/LCOMMENTS:
h:HallibulItonNUS>mrs+++C0RP0RATI0NLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportHo.:00018939SectionAPage6CLIENTNAME:INDIANAMICHIGANPOWERCOMPANYADDRESS:ONECOOKPLACEBRIDGMAN,MI49106-0000ATTEHTIOH:MS.JEHILEWIS-CHEMISTRYDEPT.HUSCLIENTNO:06630020WORKORDERHO:55830VEHDORNO:05411000CarbonCopy:SAMPLEID:TRUBINEROOMSUMP27506/FILTEREDHUSSAMPLEHO:P0259289P.O.NO.:69034-040-3NDATESAMPLED:01-JAN-94DATERECEIVED:05-JAH94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMINATIONRESULTUNITS1AALFAtuntram,Dissolved(At)0.2mg/LCNNENTS: '.HalliburtonNUS~%F1CORPORATIONLABORATORYANALYSISREPORTNUSLA8ORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684.January1B,1994ReportNo.:0001B939SectionAPage7CLIENTNAME:ADDRESS:ATTENTION:IHDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAN,Ml49106-0000MS.JENILEWIS-CHEMISTRYDEPT.HUSCLIENTHO:06630020WORKORDERNO:55030VENDORNO:05411000CarbonCopy:SAMPLEID:HUSSAMPLEHO:P.O.HO.:TURBINEROOMSUMP27509P025929069034-040.3NDATESAMPLED:02-JAH94DATERECEIVED:05-JAH-94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMINATIONIRESULTUNITS117302AHAW311304l5905AALW6I4907l700Sulfate,Turbidimetric(asSO4)Sodiun,Total(Ha)Chloride(asCl)Solids,Dissolvedat1BDCAtuninun,Total(Al)pHSpecificConductanceat25C51mg/L5.9mg/L10mg/L140mg/L1.5mg/L7.6300umhos/cmCOMMENTS: '.HalliburtonNUS++C0RP0RATI0NLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage8CLIENTNAME:ADDRESS:ATTENTION:INDIANAMICHIGANPOWERCOMPANYOHECOOKPLACEBRIDGMAN,Ml49106-0000MS.JENILEWIS-CHEMISTRYDEPT~HUSCLIENTNO:06630020WORKORDERNo:55830VEHDORHO:05411000CarbonCopy:SAMPLE10:HUSSAMPLENO:P.O.NO.:TURBINEROOMSUMP27509/FILTEREDP0259291690340403HDATESAMPLED:02-JAH-94DATERECEIVED:05-JAH-94APPROVEDBY:Kieda,ChuckTESTLHCODEDETERMINATIOHRESULTUNITS1AALFAtuninun,Dissolved(At)0.3mg/LCOMMENTS: "HalliburtonNUS%118+++C0RP0RATI0NLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlea,Suite2005313CampbeHsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage9CLIENTNAME:ADDRESS:ATTENTIOH:INDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAHtMI491060000MS.JEHILEWIS-CHEMISTRYDEPT.HUSCLIENTNO:06630020WORKORDERHO:55830VENDORHO:05411000CarbonCopy:SAMPLEID:HUSSAMPLENO:P.O.NO.:ABSPONDCCMP.P025929269034-040-3NDATESAMPLED:31.DEC.93DATERECEIVED:05-JAH94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMINATIONRESULTUNITS1I7302ANA'W31130415905AALWSulfate,Turbidimetric(asSodiua,Total(Na)Chloride(asCl)Solids,Dissolvedat180CAtuainua,Total(Al)S04)110mg/L28mg/L9mg/L210mg/L0.33mg/LCOMMENTS: .4i.HalliburtonNUS%1K'++C0RP0RATI0NLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage10CLIENTNAME:ADDRESS:ATTEHTIOH:INDIANAMICHIGANPOWERCOMPAHYOHECOOKPLACEBRIDGMAN,MI49106-0000MS.JEHILEWIS-CHEMISTRYDEPT.NUSCLIENTHo:06630020WORKORDERHO:55B30VEHDORNO:05411000CarbonCopy:SAMPLEID:NUSSAMPLEHO:P.O.HO.:ABSPONDCOMP./FILTEREDF025929369034-040-3HDATESAMPLED:31-DEC-93DATERECEIVED:05-JAN.94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMIHATIONRESULTUNITS1AALFAtuninua,Dissolved(At)0.099mg/LCOIMEHTS: '.HalliburtonNUS+~~~~C0RP0RATI0NLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(4'12)747-2684January18,1994ReportNo.:00018939SectionAPage11CLIENTHAME:ADDRESS:ATTENTIOH:INDIANAMICHIGANPSlERCOMPAHYOHECOOKPLACEBRIDGMAH,Ml49106-0000MS.JEHILE'LIIS-CHEMISTRYDEPT.NUSCLIENTHO:06630020'IQRKORDERNO:55830VEHDORHO:05411000CarbonCopy:SAMPLEID:HUSSAMPLENO:P.O.HO.:ABSPONDCOMP~P025929469034-040-3NDATESAMPLEDI01.JAN.94DATERECEIVED:05-JAN.94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERMINATIONRESULTUNITS1l7302ANAII311304l5905AALUSulfate,Turbidimetric(asS04)Sodiun,Total(Ha)Chloride(asCt)Solids,Dissolvedat180CAtuninun,Total(At)110my/L30my/L10my/L210mg/L0.35my/LCCMHENTS: .".HalliburtonNUS~i@'++C0RP0RATI0NLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage12CLIENTNAME:INDIANAMICHIGANPOWERCOMPANYADDRESS:ONECOOKPLACEBRIOGMAN,MI49106-0000ATTENTION:MS.JENILEWIS-CHEMISTRYDEPT.NUSCLIENTHO:06630020WORKORDERNO:55830VEHDORNO:05411000CarbonCopy:SAMPLEID:ABSPONDCOMP./FILTEREDNUSSAMPLEHO:P0259295P.O.NO.:69034-040-3NDATESAMPLED:01-JAN94DATERECEIVED:05-JAN.94APPROVEDBY:Kieda,ChuckTESTLHCODEDETERMINATIONRESULTUNITS1AALFAtuninua,Dissolved(At).0.10my/LCINMEHTSt '.HalliburtonNUS~%fE+++~C0RP0RATI0NLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportHo.:00018939SectionAPage13CLIENTNAME:ADDRESS:ATTENTION:INDIANAMICHIGANPOWERCOMPANYONECOOKPLACEBRIDGMAN,MI49106-0000MS.JENILE'WIS-CNEMISTRYDEPT.NUSCLIEHTNO:06630020WORKORDERHO:55830VEHDORHO:05411000CarbonCopy:SAMPLEID:HUSSAMPLEHO:P.O.NO.:ABSPONDCOMP.P025929669034-040-3HDATESAMPLED:02-JAN.94DATERECEIVED:05JAH94APPROVEDBY:Kieda,ChuckTESTLHCODEDETERMIHATIONRESULTUNITS'II7302ANAW3I1304I5905AALW6I700Sulfate,Turbidimetric(asSO4)Sodiun,Total(Na)Chloride(asCl)Solids,Dissolvedat180CAtuslnua,Total(Al)SpecificConductanceat25C10031101900.5400mg/Lmg/Lmg/Lmg/Lmg/Lthos/cmCOMMENTS: ""HalliburtonNUS%1gJ'+C0RP0RATI0NLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January1B,1994ReportHo.:0001B939SectionAPage14CLIENTNAME:ADDRESS:ATTEHTIOH:INDIANAMICHIGANPOWERCOMPANYOHECOOKPLACEBRIDGMAH,Ml49106-0000Ms.JEHILEWIS-CHEMISTRYDEPT.NUSCLIENTHO:06630020WORKORDERNO:55B30VENDORNO:05411000CarbonCopy:SAMPLEID:NUSSAMPLEHO:P.O.NO.:ABSPONDCOMP./FILTEREDP025929769034.040-3HDATESAMPLED:02-JAH-94DATERECEIVED:05JAN94APPROVEDBY:Kieda,ChuckTESTLHCODEDETERMIHATIONRESULTUNITS1AALFAluainun,DissolvediAI)0.072mg/LCOMMENTS: "'alliburtonNUS~lP'~>~CORPORATIONLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage15CLIENTNAHE:ADDRESS:ATTENTION:INDIANAMICHIGANPOWERCOMPANYOHECOOKPLACEBRIDGHAH,Nl49106-0000NS.JEHILEWIS-CHEMISTRYDEPT.HUSCLIENTNO:06630020WORKORDERNO:55830VEHDORNO:05411000CarbonCopy:SAMPLEID:NUSSAMPLENO:P.O.NO.:ABSPONDCOMP66998P025929869034-040-3HDATESAHPLED:03-JAM-94DATERECEIVED:05-JAH.94APPROVEDBY:Kieda,ChuckTESTLNCODEDETERNINATIOMRESULTUNITS117302AMAW3I130,415905AALW8l700Sulfate,Turbidimetric(asSO4)Sodius,Total(Ha)Chloride(asCl)Solids,Dissolvedat180CAtuainua,Total(Al)SpecificCohductanceat25C11028101900.5410mg/Lmg/Lmg/Lmg/Lmg/Lmoos/cmCOMMENTS: ""HalliburtonNUS%%TEI++C0RP0RATI0NLABORATORYANALYSISREPORTNUSLABORATORYTwoMarquisOfficePlaza,Suite2005313CampbellsRunRoadPittsburgh,Pennsylvania15205(412)747-2580FAX:(412)747-2684January18,1994ReportNo.:00018939SectionAPage16CLIENTNANE:ADDRESS:ATTENTION:INDIANAHICHIGANPOWERCOHPAHYONECOOKPLACEBRIDGHAN,HI49106-0000HS.JEHILEWIS-CHEHISTRYDEPT.NUSCLIENTNO:06630020WORKORDERHO:55830VENDORNO:054'11000CarbonCopy:SAMPLEID:HUSSANPLEHO:P.O.HO:ABSPONDCOHP66998/FILTEREDP025929969034-040-3HDATESANPLEDI03-JAH-94DATERECEIVED:05JAN-94APPROVEDBY:Kieda,ChuckTESTLHCODEDETERNINATIONRESULTUNITS1AALFAluninun,Dissolved(At)COHNEHTSr0.088mg/L SEEINSTRUCTIONSONREVERSESIDESECTIONIIPERMIT~MI0005827~OOEEMAeLOCATIONOFDISCHLRGES,~RECEIVIIOHATER(IE.GAOWDQTERCRN4%OFMLFACEWASANITAR2t'BSPOND.~SWt~SEJi,SOI0Ii~06.\I~065,SSE~19WDISCHARGELOCATIONSCHEDULECIDOYOUDlSOLLRGESEASCNALLY(IFIOJCONTIIAKIOEIDeIFYESaLISTDISONKEPERIODSM)o/DLYIon/DAYFLOWRATEWASTEWATERJXBKSiQQE1CONTACTCOOUNQ2NONCONTRCTCOOLWQ3PROCESS4SANITARY5STORMWATERllHUUcQDE1MQY2MQD3QPD[TENEIIhtDAPPLICATIONRATE,FoTYPEOFHASIBGLTERDISCHLKEGoDISCNRKSOERLE(YE/RLYAVER/GE)NAINI/HleHIe/DAYIH,/NN.~~u~~u~.'W0)IF'4~~wuLJNOLNS/DAY~4equi~H,DISCHHLGEFUSIRATEaseona-arneTOTALYEARLYDAILYHINIISSIDAILYILLXWPI13505020372JoHAXDQIDESIQIDL5CNAXFIDIRATEeAoIEIYOLIUSEHATERTREAIIRNTAIDITIVES1DTREATYOIRDISCNK4.(IFHG.ccNTDAEToITBI3)SeNIKFBCTICNp110OKNCALCStOSITIlSOFlfC5EAISIITIVB4DESIGNo.o6oleGtKZJQL.CalciumHochloriteforIITIE$0(DSIIDISCHVSIEFUSIRATETOSEAUllERIZEDIHPEBIITeo.o6oTREATMENTADDITIVES1MQ/I2UQ/ICaWICAMIACCRESSOFIWAFACARERSCFTMSEAISITIVESPVANWATERSANDROGERS,INC.1600NORTONBUILDINGSEATTLE,WASHINGTON98104-156DeEXPKIEDDISCHLRKCBCEHIRATICNOFAIDITIVESaHIHIISPIWITSAVIRAGEaEE~LNITSHAXIISSIWITSQXE~axK~,~0LJi~LJJ~M3~LJsanewe*TotalResidualChlorine0LJ,0ACDITIYEwteADDITIVEHL/KEaDO511TlKIT1%DINARTORBOltEAISIITIVESTFsY6IATISTIERBIVALEFFICIBCYAleDISTR%FRBSESCY2ACOITIVEVIEIRBBVALINSo/DAYDLYS/W.,LJG,ASANATTAOPEIITTOTHISAPPLICATICNPRESIDESPECIFICHJtNALIAHCRAQILTICTOXICDUDICALDLTACRRERREHCENHICHAREAVAIIAILEAHDl%TSPLATIBICNTIERATEOFDEWADATICHOFTIEPIEXICTSRSIEKHACOITIVEib1SDSAttachedCalciumHypochloriteisaddedtothemixedliquorandisuseduppriortodischarge. INSTRUCTIONSFORCOCPLETINGSECTIOIIIITEMSIANO2ThisfomrequiresInformationonthefacility'sdlscnargelocation,dischargescnedule,volumeflowrateandvotertreatmentadditives.ENTERTHEPERMITIAP(B\RINTHEBOXATTHETOPOFTHISFCIOI.THEPERMITNIP(BERCAMBEFOUNOOMTHEFRONTPAGEOFYCUREXPIRINGPERMIT.IfthisIsane>>ornotpreviouslypermittedfacility,thenleaveblankendsnumberwillbeassigned.EntertneoutfallncxxaarInspaceprovidedforescnpageofsectionII.ForcoonIndividualdischargepointaseparatesetofSectionliformsmustbefilledOut.ITEMIDISCHARGELOCATIONSCHEOULEA%)FLOHRATESA.Enterthelocationofdlscnorga,thisshouldIncludequarter-quartersection,quartersection,section,town,sndrange.B.Listnameofreceivingvoter(lfsurfacewaterdischarge).C.Indicatevnether(scil)tydischargesonaseasonalbasis.O.Ifyes.listdischargeperiods.E.Provide'thelandappl)cationratesusedorexpectedtobeusedintermsofInchesperhour,hoursperdoy,sndInchesperweek.Indicatethetypeofwastewatertobedischargedfromthisoutfall.RefertotherostevotertypecodegivenInthelettmargin.Morethsnonecodemoybeapplicable.G.ProvidetheaveragenurserofhoursperdovInwhichthefacilitydischargestreatedwastewaterondthetotalnumberofdaysperyearinvnlchthadlscnsrgeoccurs.H.Providecurrent(framthelostl2months)orexpectedflowratesssrequested.RefertounitcodedivanIntheleftmarginfortheappropriateflowunits.HGY-milliongallonsperyear)MGO-milliongallonsparday)GPO-gallonsperdsy.I.Providetnemaximumdischargeflowratewhichyourenttohaveauthorizedwithinthepermit.N0TE:ForNPOESpermitsonlY.theuseofsuchaflowratevillnotplaceanactuallimitrestrictionontheflowbutvillbetheflowroteusedtodevelopeffluentlimits.Also,>>nentheMonthlyOperatingReportsarereviewedbyCcmpllancestaffItvillhelptheatodetermineifanynevorincreasedusesmighthaveoccurredatthefacility.J.Providethedesignflowforthisspecificoutfalldischarge(e.g.batchtreatmentsystemflow~packagedtreatmentsystemflow.orsaneotherfinitetreatmentsystemflow),ITEN1vATERTREATMENTAOOITIVESA.IndicatevnetherdlscnsrgeIstreatedwithconditioners,inhibitors,ocmicrobiocide.Ifnot,continuetoItem3.B.Givename.function,andchemicalcompositionofadditivesused.C.Givenameandaddressofthemanufacturer(s)oftheadditivesused.O.Indicateexpectedmlnlmcxe,averageandmax)mesodischargeccncantratlonsoftheadditive(s)forthisdischarge~E.Indicatewnetneryoutreatthedischorgetoremovethesddltlvelslbeforedischargeofwastewater.F~Indlcotethereaovslefficiencyofeachadditivefranthevastevatec'ndthedischargefrequencyofeachadditivetothesurfacevoterorgroundvater.G.N0TE:ltIstheresponsibilityoftheapplicanttosupplytheproductInformationssrequestedInthisItens.InformationrequestedbutnotsuppliedmayresultIntheapplicationbeingreturnedtothesap)Identforcanpletlon.32 VAHMATER.'>i~ROGERSIi(C.SAI.EI<IAlS!~r-ETYDATAS>HEFTREPORT'"JLJHBFR'7'JiISDSi'iQ:PG03J.O~="ECTIVE'!ATE:OF/2"/93.>6DIJ(.s'.r',,AlCIUi'(HYPOCi~ll0RXTE6I<AHIJI!4lkPAGE:00%VERSIOH:00~)(3RDERNO:PR(3I3HQvANWATI".RShROGERSXHC.,SLJBSXDIARYQFLINGVARi".>3.00CARIIL(3HP(3IiHTKXRKLAHD<206>889-.i400WA98033Ei(ERGEHCYAS>8X8>TAHCEI'3REi(ERGENCYAS,TSTAHCEXO'VOLVXHGCIHFiRICALSCAIL-(".HEI'lTREC<800>42>4-9300I=ORVICQ(3IJCTAHI3S!'.IES:r.HFORNATI(3HCONTACTYOLJRLOCA(..VANWATERSb,ROGER.>BRANCHOFFICEATVWhlkSOUTI(.I3EHI3~'L9-'i89-03~1~OUTHP-HllIHPRQI3LJCTNAIVE:CALCILJHHYPOCIIIORITE6RAHLJIARH.>i!8'"r::PG0:31.0CAlCIUHi-IYP0CI-Il.QRXTE6RAHULARl)A>E:rDITX(3N:1'ADEHARE:i.,'l-ICiIi-rI'iiiE/8YN:'~~0/'l93nowCALCIL)i(HYPOCHLORITE(iRA)'IL)LAi<CALl-IYP3,PTT'iCl..(3R,.".Hll(JCLOR,REPAK,.:APPXTCIIEIIXCALFAHILY:I-IYPOCI-ILORXTEF(3f~iilJLA:!:A<(3CI..>2CABHLJHBER:007778-54-'IJ,8~DOTSHIPPIHGHAHE:CALCIUHHYPQCI-ILORITE,HYDRATEDIJ~S~DOTHAZARDCl.ASS:.'r,J.<OXXDXZER>"-;IJI)ST.i3IARYRI8K:i'I/AI.n.NLJVJ3I=.R:LJN2880A(".,I<IH(38>ROlJP:XX:.~QRTAIll'=QIJAHTTTY::L0LI38/4~-l<6I;Hf)DESCRIPTIQH:CAL.CILIAiIYPQCHLORXTE,HYDRATED,CLASS'3.,UH2880,PA(.i<".I'IG>8RQIJPII,RA,XHOG(;Ql3EPAGI=.rl38~
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SEEINSTRUCTIONSONREVERSESIDESECTIONIIPERMIT~IYII0005827NUMBEREM3A>>NA%OFPROCESSCONIRIBUTIIIITOTHEDISOIARGETICEXXNTHISOUIFALLAM)SICCODEBsPROCESSSOCEDLLE(YFsVCLYAVERAGE)mum/DtLV~24~365~OOESANITARYWTER4911PROCESSSTREAMSCONTRIBUTINGTOOUTFALLDISCHARGEnthCCCOr0CC0C~PRXESSHASTEN%TERFUXIRATEDsPROCESSPRCXXXTIONRATEN/ATOTALYEARLYDAILYHINII%NDAILYHAXII%NLNITgXXIE0ll~6037~6LNITSPTIHE~LJJlIIIZQZc!2JK1POUNDS2GALLONS3CUBICYARDS4TONSSMGY6MGD.7GPDTIME1HOUR2DAYWEEK4MONTH5YEARcvCllnOCC9OCECLAsf4'%FPROCESSCONIRIBVTIICITOllEDISOLUCGEg/ATIROUGHTHISOVIFALLAIDSICCLXEBsPROCESSSDEDLIE(YEARLYAVERAGECsPROCESSHLSTEHATERFUXCRATEDsPROCESSPRXLICTIOHRATEAsHAIEOFPROCESSaXIIIBVTIHTTOTIEDISCHCRGEg/ATICBXXIHTHISOUIFALLJUOSICOXEBsPROCESSSQEDLIE(YEARLYAVERAGE)CsPROCESSHLSTKHATERFUBIRATED.PIXXXSSPRXXCf1ONRAlEAstQPEOFPROCESSCCNIRIBVTIIClOTIEDISCHARGEg/AAM)SICCTEEBsPROCESSSOERIE(YEARLYAVBLAGE)RLXKSSHASTDNTKRFUXCRATEA.HHEOFmCKSSCCNIRIIXITIWTOTIEDImeaaN/ATI%%XCIHTHISOUIFALLANOSICCODEBsPRXESSSOEDIE(YEARLYAVERSE)C.PROCESSHAST8%CTKRFLDCRATEDsPRXESSPRXXCTIONRATETOTALYEARLYDAlLYHIHII%NDEWILYHLXII%MTOTALYEARLYDAILYHIHII%NDAILYHAXIltNTOTALYEARLYDAlLYHINIJ%NDAILYHLXIHEClOTALYEARLYDAILYHIHII%NDAlLYHAXII%NLNITS/TINELNITaXKLJLNITSnIHELNITS/TIHE INSTRUCTIONSFORCOIL'LETINGSECTIONIIITEM3TfisformreauiresInformationontneprocessstreams<<hlchcontributetothisdlscnarge.ENTERTHEPERMITIl'ABERINTHEBOXATTHETOPOFTHISFORM.THEPERMITNIWIBERCANBEFOUNOONTHEFRONTPAGEOFYOUREXPIRINGFERMIT.Ifthisisanewornororeviousiypermittedfacility,thenleavealan<andanumber<<illbea5signed.EnteroutfaiinumberinspaceprovidedforeacnpageofSectionII.ForeacnindividualdlscharcepointaseparatesetofSectionII'OrmsmuStbefiIlegout.ITEMSPROCESSSTREAMSCONTRIBUTINGTOOISCHARGE:FOREACHSEPARATE'ROCESSPROVIDETHEFOLLOHINGINFORMATIONA.Entertnenameoftheprocess<<nichcontributestothisdischarge.AlsoprovidetheproperSICcode.B.Indicatetneyearlyaverageproce55ScneduleinhOurSOcrdayanddays-oer-year.C.Providetheprocesswastewaterflowrateinformationasrequestedba5edonyourlastl2monthsofoperations.Ilefertounitcodegivenintheleftmargin(ortheappropriateflowunits.0.ProcessProductionRate-Certainpermitlimitationsmavbebasedonproductionrates.Theproductionratesusedtodeterminepermitlimitssnailberepresentedbyareasonablemeasureofactualproductionofthefacility,suchastheproauctlonaurlngthehighmonthoftneoreviousyear,orthemonthlyaverageforthehighestofthepreviousfiveyears,orotherreasonablemeasureasstatedinapplicableU.S.E.P.A.categoricalrulesandregulations.Fornewsourcesornewdlscharaers,actualproduction5hallbeestimatedu5ingprojectedproduction.RecorayourproductionratesinthetermSanaunitSuSeaIntheapplicableV.S.E.P.A.categoricalrulesanaregulationsforyourtypeoffacility. SEEINSTRUCTIONS.ONREVERSESIDESECTIONIIePERMIT~LNIOit05827NUMBER~OO:EGROUNDWATERDISCHARGEINFORMATIONAeIS1HEDISCHARGEFRCNTHISOUTFALLDIRECTEDTOTHEGRONOORGRONDtATKRS2llFtDPCCttTltiETOITEMO)BeHASAHYC62OIBXDGICALSTIXT/ORITSEOJIVAIENTBEEHPKRFORPEDORISTHERESIFFICIEHTcNIREHTHfÃGGEQ+GIaLINFOIHATIONAYAILABlEASRE0UIRKDBYTteHATERRstxxstcEsalttISSICMPARTZZRAIXltD6ATERRIIESOFAIDUST14PlRURP525PZ/W(PAGEFCRTHISEXISTI%ORPROPOSEDDISCH6RGE/IFYESAlTAOIACOPYCFlHEREPCRTPCeAREYCURBXESTI%ANEXBGTTICNFRCMSIKPIITT1%AHYCRCGKOLOGIaLREPCRTtltDKRRISER.323P221}l(l0}(PAGEtt5)OtFR(MGRIXPIXtATKRN5ttITQRI%IIKOUJRIMEHIStltCERRLAKRP525PZIU5(5)(PAGEt(73OFTIEPARTZlRLLESPIFYESATTACHDXIMKHTSAM)EXPLANATICNTODOIGCTIATKTHATYIXRDISOQf6ENXADOUALIFYRXI~CNPDeAREYOURBXESTI%AVARIANCEFRtttRULE323e2Z6(PAGE5)(%tKXDIIADATICN)OFTIEHATERRESIXl2CESCCWISSIONPARTZZGRXXtttlATKRRIALSPAIFYESPATTACHSIXHDOQMKHTSASNECESSARYTOCQQtSTRATKTIEHEEDFCRAVARIANCEINTKIYtSCFTIECRITERIASPECIFIEDIHRIAL5Z5P2210(PAGEOFTHEPARTZLRILESPEeI,ISTALLCteIICALSIBSTAICESHHICHAREINMICHIGANSCRITICALMATERIALSREGISTKRTAKEIVlPAGK{j)OtUPSPEPA'SPRICRITYRXll/TANTLISTTAKEV(PAGE1)ORANYOIIERSIBSTMXStHIOIAREOtNAYBHXPEINXIIIIXS1DTIEEESIGNATEDUSESOFTIEGNIXIKltATEROR19TIEPUBLICIEALTHTHATAREDISCM6RGEDOREXPECIEDTOBEDISCH6RGKDTOTIEMX!KXIATKR~THISFJCILITYPESTIHATETHEFINALEFFLIEHTCOtCEHB4TICNAtKIRKCCRDAII.DteTAINITBl1OFSECTIONIlIHTHISIO)NEfeTIEAPPLIa7ITHAYBEREIXIIRKD1ODOACOITIOIALHASTEJIUI.YSESPz->>-a.Submitted12/6Y91INTAPPUaBLE/BELlKVKDABSENTPRESENTSDATAIQOVIDKDINITBI7ITEM5AeDISCH8RGECHAIIACIKRISTICSBGDI7(FIYEDAYBloctetlaLoxYGEHDKMAIKI)'coD(OKttlaLc0DGENcetAto)CCNCEHIRATICttAVENAX~40.~05~99.~6WITSCIXKltANALYSESSAtPIKTYPECIXEu1~uEXPECTEDWASTEWATERCHARAC1Mp/I2UQ/I3COUNTS/100ml4S.U.5'FeI.BS/OAYANCNIAHITRIXIKH(ASH)TOTALSUSPKNXDSCUDSTOTALPIOSPta2US(ASP)TOTALRESIIXIALOURIHEDISSOLVEDOXIGKHNIN~6~4FECALCGUFXINBACTERIA~TINE(SUPER)TDPERATISK(HINTER)TOC(TOTALORGANICaRNXt)~25.~55~116,~0~7~.~036~12~~05S78~~uLJ~~uBeODKRINSTKHATKRCM6RACIKRISTICSul2~60ul~65u1u1~113u5u5u1u1~SAHPTXBF1GRAB224HOURCOMPOSITE0ILBGREASEciro.~65.~56~208,~0LJu1~65RECUIRKDIWXP5ATICNFITSINFACEHATERDISCHNGVP INSTRUCTIONSFORC(5IPLETINGSECTIONIIITEMS4ANO55forr,requirentmatioIionaspecificoutfalldischargingtoeitherthegroundwatersorthesurfaceWaters.5?(Isortorequr~e-q(ERTWEDcq)f(T'hBERIIITHEBOXATTHETCPOFTHISFORM.THEPERMITNIDIBERCANBEFOUNDONTHEFRONTPAGEOFYOUREXPIRINGoER??IT.z+thi+5anettornotpreviouslypermittedfacility,thenleaveplonkandanumber<<illbeassiqned.Perr(leOucfalInumaerIntheSpacePrOvidedtoreacnDaceofSectionII.ForedenIndividualdischargepointaseparatesetecVIotl'D~torm'5(It's4ana5)nustaeIiliedout.DP/ITEM4IlG"OUNDWATEDDISCHARGEINFORMATION(00NOTINCLUDEDEEPWELLINJECTIONINFORMATIONINTHISITEM)A.-D.TheapplicantshalladdresseachotthaqeoartsIfthedischargefranthisouttallIstothegroundwater.ITEM5EXISTINGOREXPECTED(FORANEWDISCHARGE)WASTEWATEP.CHARACTERISTICSOFGROUNDWATERORSURFACEWATERDISCHARGE(DONOTINCLUDEW>>LLINJtINININH,?JPTheapplicantshallreportavailabledischargedata(realdataforexistingdischargeorexpecteddataforaoroposeddischarge)fortheDard>>etersdslisted.TheseDarameter5shallbeaddressedfoIeitherasurfacewaterdl5chargeorasaDpropriateforagrounovaterdlscnarge.ForassistanceIndeterminingappropriateparametersagroundvaterdlscharoeapollcantmaycontacttheGrounovaterDualityDivision,PermitsSectionortheapproorlateGrounoraterpualltvDivision'sDistrictoffice.TheapplicantshallreporttheSaneletypecodebestdescribingedenreportedplaceofdate.Seecodingontheleftmarginofthisform.II'hisouttallIsasurfaceWaterdlscnarae.theaop?icantmustreportquantitativedataforeachDard>>eterIdentifiedbvan5"~OCDODDODOD~.I*CCDtt5~5555OtDOOItlI,III5OCO5DttCWINDtttOI~DDIICtlt9.ItdatalsavailableforotherparametersnotlistedaboveinA.orotherpartsotthisapplicationtheaDpllcant5houldreDortthatdataIntheblank5DacesprovidedInthisDart.NOTESII.UnitcodestorparanetersreportedInpartsAandBcanbetoundontheletthandsideotthistorm.2.GrabsampleshallbeusedtoanalyzeforpH,tenoerature,totalphenols,residualchlorine,oilandgrease,andfecalcolltormInasurtacewaterdischargeunlessotherfrequency-sanpletypeanalysesareavailabl~.SeeGlossary(page48)forddtlnltlonofgrabsandie.24-hourcomoosltesamolesshallbeusedtoanalyzeforTotal8005,coo,Toc,Am>>onlaNitrogen,andTotalSuspendedSolidsInd5urtaceWaterd)5chargeunle55otherfrequency-sampletypeanalysesareavailable.SeeGI055dry(page4B)tordefinitionofccmoosltesa>>pie,REPORTI)6OFINTAKEDATA~Youarenotrequiredtoreportunle55,youvishtodemonstrateyoureligibilityfoId"net"effluentlimitationtoroneormorepollutants,tnatIs,anettluantlimitationadjustedbysubtractingtheaveragelevelotthepollutant(s)presentInyourintakeWater.NDDEsregulationsallownetlimitationsonlyIncertaincircumstances.Todemonstrateyoureligibility,reporttheaverageottheresult5otanalyse5onyourintakevaterllfyourWaterIstreatedbetoreuse,testthevoteratterItIstreated).andattacha5epdlatesneercontainingthetollovingforeachDo?lutant?(a)AstatementthattheIntakeveterI5dravntramtnebodyofvaterIntorh)chthedl5chdrgeIsmade.(OthervIse,youarenoteligibletornetlimitations.)(b)AstatementottheextenttoWhichtheleveloftheoollutantisreducedbytreatmentotyourvastevdter~(YourlimitationsWI)Ibeddju5tedonlytotheextentthatthepollutantIsnotremoved.)(c)whenapDI)cable(torexonple,Whenthepollutantrepresentsaclassotca>>pounds),ddemonstrationoftheextenttoWhichthepollutantsIntheIntakeveryphysically,chemically,orbiologicallytreethepollutantscontainedinyourdischarge.(YourlimitationsvillbeadjustedonlytotneextentthattheIntakeDollutant5donotvaryfrcmthedischargedoollutants.)ltyouhavetwoormoresubstantiallyIndentlcalouttalls,youmayrequestpermissiontranyourpermittingauthoritvtosampleandanalyzeonlyoneouttalIandsubmittheresultsottheanalysistorothersub5tdntlallyidenticalouttalls.Ityourreque5tisgrantedDythepermittlnoauthority,onaseparate5heetattachedtootheaapIlcatlonto?mIdentityvhlchouttallyoudldtest,anddescribewhytheouttalls<<nichyouoldnotte5tdresubstantiallyidenticaltotheoutfall>>hichyoudidtest. SEEItISTRUCTIONSONREVERSESIDESECTlONIIPERMIT~glQpp5827NUMBERIPRIORITYPOLLUTANTSANDADDffIONALINFORMATIONFORSURFACEWATERDISCHARGEONLYTHEFOLLJSI1%REOLESTKDINFORMATION~eADNESSED~QHFACEHATOtDISCHARGERS.IOZEIMDIUSEDISCHARGE%BALLLPROVIDEEXPECIKDVALLESFORlHEOUlUITITATIVEANDQUALITATIVEINFNHLTIONREOLKSTEDBELCHeA.tsTHISFACILIlYAPRIMARYIIOUSTRY?(REFERTOTABLEIAPAfg9D(IFWGOTOE)(IFY5GOTOB)BeIWICATETYPEOFPRIMARYINDUSTRYASLISTEDIMTABLEtAPACEQeICONTIN'ITHC.)C>COESTHISOUIFALLDISCHARGECCtITAIMANYPROCESSHASTKHATER?(tFW,GOTOE)(IFYKS.GOTOD)DeINDICATEttIICHGC/tnFRACTIONSNJSTBETESTEDFCR~(REFERTOTABLEIAPJIK(II)IOZEIFCREACHGC/HsFRACTIONCHECKKDeEACHSPECIFICORGANICTOXICPOLLIJfAMTHllHIHKAOIFRACTIONtl5IBEANALYZEDFCR(SEETABLEIIAPAGEQ,INAODITIOMiALLPRIIVLRYINLXJSTRYAPPLICANTS)IITHAPROCESSHAS19IATERDISCHARGE'~PRCNIDEOLJLMTITATIVEDATAFOREACHTOXICIOLJJJfAMTINTABLEIIIAPA%gPeRHXRDALLDATAONFCRHSPROVIDED(ITBL7)INTHISBOOKLETe(CCttfltAEHtlHK,KBKLJBI)OOESTHELEWRDAnalysisperJ.B.BeauboeufDBASE/MEUIRALGrOundWaterDivision0eeeePESTICIIXEeIFgg,QJIFACEl4LTERDISC%ROEJPPLICAMf(PRINRYORSECCtOUIYIIJJSIRY)eRKGAJICLESSOFTHETYPEOFDISCHARGEiKMlISORHASREASONTOBELIEVETHATAMYPOLLUTANTLlslKDINTABLEIIAAMDIVAPJGKS~ISDISCHARGEDFROIANYIXJIFALZiT)EOUMITITATIVEDATA~BEPROVIIKDeRECNDALLDATAONFOIVISPROVIDED(ITKH7)INTHISBOOKLETeFeIFAMYSLJIFACEHATERDISCHARGEAPPLICANT(PRIMARYORSECOtOARYINXJSTRY)eREGJRKESSOFTYPEOFDISCHLRGKeXMASORILLSREASCNTOBELIEVEJIFFYPOLLJJTAMTSLISTEDINTAREVAPAGE+AREDISCHIRMFRLttAMYOLJIFALLl)EAPPLICJJIf~DESCRIBERKASONSFCR1%,PLXJJJTJtlfBEltOPRESEHTJJOPROVIDEAHYAVAIUBLEOUANTITATIVEDATAeRKCNDALLDATAONFCtttsPROVIDED(ITOI7)IH1HISBOOILEfeWTAPPLICABLE/BELIEVIABSOITN/A0PRESOIT/DATAlsATTACHEDWfAPPLICABLE/BELIEVEDABSOITN/APRESOIT/DATAIsATTJUMDGeALLQRFACEHATOtDISCHARGEAPPLICAMIS(PRIMARYAIOSECCtOARYIIGXJSTRIES)ttOJcRHAIKFAclLSLEs24ifTRIctslstpetEwxfAcETIGAGID(2e4i5-T)Ji4ietTRIOKJSOPIHWXYPRCPAWICACID(SILVEXiZsIi5iTP)JDI%PIYLVPCi4ilTRILJLJJRCP)KDIYL)PIOSPKIIOTHIOATK(RCtNEL)J>IRICJKJSIOPLEML(TCP)JORHEXJOLNGPIEJE(ICP)J(ALLDATAFNT)EABOVEtlJSTBEGKMIIATEDUSt%STAIOARDAIHLYTICILCALItttATICHPIOCOXJLKS)ORKtslOCRHLSREASON1DBKLIEVETHATTELOISORHAYBEPRESBITINT)EIRDISCHJJKIEe~RKPNTQUALITATIVEDATAiGOERATKDl431tttUSEDASCRKKHIIOPIOCOXJLEWfCALIBRATEDHITHANALYTICALSTAIOARDSeFNLDi1SiTKTJIAOKJSKXJIBEHZ~DIOXIH(TCZXJ)eRKCNDALLDATAONFNttsPROVIDED(ITBLf)INTHISBOOKLEfeJeIF~1lEQJLFACEHATERDISCHARGEAPPLICAMfK)KHSNHASREASON1DBELIEVETHATBIOLOGI~TOXICllYTESTSHOLEHADEIHlHELASTT)ttEE(9)YEARSCNJJtfOFT)EAPPLICANTSDISCHL%ESORONARECEIV1%HATERINRELATIONlDADISCHARGEiPROVIDETHISItFNHATIONASJJIATTACttHITTO1HISJPPLICATIONeKeIFAOIIIRACTLABNATORYORCSStLTI%FttttPBRÃtKDJttfOFTIEANAYSESREQUIREDBYTHISAPPLICATICILPROVIDETIENAtEANDACNESSOFEAIHLABORATNYORFIIVIAtO1)EANALYSESPOIFCRtEDASAMATTACttEMTCF'IHISAPPLICATIONeCOYOUDISCHL%EANYOI)ERTOXICORINJLRIOLJSCteHCALSLSSTANCEStOTLISTEDINTABLESIVPJGEttAIOIIAlWOAIVAPPP4$~~IFYEsiTlENIOEHTIEYTIECJKPIICALQSLSTANCESAWKSTIJLETETIEFINALEFFLLEttfIXYCEHIIIATHYISeSLKPIITTHISIIFCALLTICNASANATTAC)tENTTOTHISAPPI.ICATIONeWrAPPLICABLE/BELIEVEDABSENTN/AQPRESOIT/DATAISATTAC)EDN/AQAPPLICLBLE/SEEAITACIEDQWTAPPLICABLEQX~IIE/SEKAn~QtOTAPPLICABLEN/AAPPLICABLE/SKEATTAOED INSTRUCTIONSFOR.CCMPLETINGSECTIONIIITEM6ThisformreaviresInformationonsspeCifiCOutfalldlsCharglngtothesurface>>sterS.ENTERTHEPERMITNUMBERINTHEBOXATTHETCPOFTHISFCRM.THEPERMITN(S48ERCANBEFOUNOONTHEFRONTPAGEOFTOUREXPIRINGpERMIT.Ifthisissnerornotpreviouslypermittedfacility,thenleaveblanksnasnumber>>i(Ibeass(oned.EntertneoutfallnumberInthespaceorovldedfortachpageofSectionII.ForebenIndividualdischargepointsseparatesetofSectionII.Item6formsmustbefilledout.ITEM6PRIORITYPOU.UTANTSANOAOOITIONALINFORMATIONNOTE:Ifyouhavet>>oormoresubstantiallyindenticsloutfslls,youmsyrequestpermissionfromyourpermittingauthorItytosssplesnaanalyzeonlyoneoutfallsnasvcmlttheresultsoftheanalysisforothersubstantiallyIdenticaloutfslis.lfVourrequestIsgrantedbytnepermittingauthority,onsseparatesneetsttscnedtotheapplication,formIdentify>>nichoutfslIyouaidtest,snadescribe>>nytneoutfslls>>nlchyouaidnottestaresubstantiallyIdenticaltotneoutfall>>nlchyoudidtest,NOTE:A.-C.snoE.-J.40CFRPartl22.2((g)(8),Friday,AprilI,lg83,provlaesforssmellBusinessExemptionfromtheresortingofquantitativeaptsfororganictoxicpollutantssnatoxicpollutantsssrequiredbyPortI22.2((g)(7)(ll)(A)orI22.2((g)(7)(ill)(A),TheseDortssreself-explanatorysnddonotrequirefurtherInstructions.simplygothrougheachpartsnddossindicated.0.SeveralIndustrialcategoriessndsubcategorieshavebeenexemoteafrcmsubmittingdotsoncertainGC/MSFractions(40CFRPertl22,vol.'48,No.64,Friday,AprilI,1983,NotesI,2,sna3)."Revle>>thefolio>>lnglisttodetermine>>netheryourfacilityqualifiestobeexemptfromreportingGc/HS(GssChrcmstogrspnv/MossSpectroscopy)Fractions.GC/MSFractionTestingsndReportingExenetlonsTextileMillsIndustryAllfourGC/HSorganicfractionslntheGreigeMillsSubcategory.-PesticidefractionInellothersupportsofthisIndustry.OreMlnlnsndOresslnoIndust-Volatile.base/neutral,sndpesticidefractionsIntheBasesndPreciousltetslsSubcategory.-AIIfourGc/MSorganicfractionsInsllothersubcategoriesofthisIndustry.Cu>>andVoodChemicalsIndustry-PesclcldefraccionIntheTallOilRosinSubcateqoryandtheRosinbasedDerivativesSubcatsgofy.-Pesticideandbase/neutralfractionsinallothersubcategoriesofth(sIndustry.PulpandPaperIndustry-PesticidefractionInPaoerqradeSulfitesubcateaorles{subpartsJand0).-Sass/neutralandpescicldefractionsinOeinkSubpartQ,OlssolvlnqKraftSubparcF,andPaperboardfromVestaPaoerSubpartE.-Volaclle,base/neutral,pesticidefracclonsintheBCTbleachedKraftSubpartH,Semi-chem(calSubparts8andC.andNonlnceqrated-FinePapersSubpartR.Acid,base/neucral.andpesticidefraccionslnFine8)cachedKraftSubpartI,OlssolvlngSulfitePulpSubpartK,Ground>>oodFinePaDersSubpart0~MarketBleachedKraftSubpart0,TissuefrcxaVastepapersubpartT~andNonlnteqratedTissuePapersSubparcS.SteamElectricPeerPlantInduct-Base/neucralfractionintheOnceThroughCoolingVater,FlyAsh,andBoctomAshTransportVaterorocess>>astestreams.38 leeI~~')~'1~II~'~e;~-~'~~I1l)~e1I"~.'c~~'~~'~~1'e~~')'~r'l~~~~~~I'~~II'~NI~)II~~~'~~~1~e~~~e)~~~I~~el~~'~I~)~~~I~1~I~I~~I~~~~~~c'Ie)~I~IC~~I~)~I~~I~~~~1I~I~e~~I~)~~~~Ie~~'I~~~~~I~)~~~I~~el~~~')l~1~I~~I~~II~~e~~~~~)~I~~I~1~I~I~~II~~.~r~I~-~I~~I~1~I~~I~~~~C'~)l~'IW~~~~~~~~'~~'~~~~~~~c)I~"ll~'~~~~ INSTRUCTIONSFORCCHPLETINGSECTIONIIITEN7ThlformIstobeusedbvbothsurfaceandgroundraterapplicantstorecordInformationonanvHlchlgancriticalmaterial,E.P.A.prlorltvpollutant~ornatardoussubstanceinxhicntnlsapplicationrecuiresdatatobeprovided.ThisvouldIncludeanychamcaarm~IIsubstancefrcmtneHlchlganCriticalHaterlalsRegister<TableIv),theE.P.A.prioritypollutantt.lstlngITableV).orTablesIIAVAvhlonIIStSOrgan)CTOXICPOIlutantS~OtherTOXICPOIlutantS~CcnVentlanalandNOnCOnyentlOnalPOIlutantSandHasardcuaSubstances~ITEN7CRITICALMATERIALS*PRIORITYPOLLUTANTS~ANO/ORHAZAROOUSSUBSTANCESINTHEOISCHARGEMaterielI.2.3...8A.ListthenameofthechemicalsubstanceIcrltlcalmaterial,prioritypollutant,orhasardoussubstance)frcmTablesIV.VandIIA-YAasreculredIntneaoxvnicnyoucnecxedInA.I-3.above.Entereacnchemicalsubstance'sparameternmnberaslistedInTablesIV,VandIIA-VAItprovided.8.ProvidetheaverageconcentrationofthechemicalsubstancehewedInA.IndicatethesmnpletypeusedandthenumberofanalysesmadetoprovidetheconcentrationcataforthechemicalsubstancenamedInA.C,Pl+videthemaximusconcentrationanddeterminethemassloadingofthechemicalsubstancenamedInA.I'fonlyoneanalysisuasmadeforachemicalsubstancethenrecordthatdataesamaximusvalue.Ifmorethanoneanalysishasbeenmadeforacnemlcalsubstancethenprovideenaveragevalueofthoseanalysesandthemaximusvalue.2.ThisSectionII,Item7,OataSheetprovidesspaceforrecordingdatafor8chemicalsubstancesIHaterlals).Additionalspaceforrecordingofdataformorethan8HaterlalscanbemadebymakingcopiesofthisItem7Oatasheetesneeded.ItIsalsoImportanttouseeseparatesetofoatasheetsforeachapplicablereportingreculrmnentaslistedInA.)-3.endforeachoutfall.Refertothelettmarginforthecodenumberrepresentingthesampletypeusedendtheappropriateunitcodes.40 0iI~~~~oIIo~.~~~'.-~..~~~~~~~o~~~e~o.~'~~~~~'I~I~~~'~I~~~I~~~~~~~~~~~o~~~o~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~t~~~~~~~'~~~~I~~~~~~~ ~l~0L~~~~LL~~~~I~.I~.~-ee~~~l~~~~o~~~a.e-~~~'~~~~'~~I~~~'~~~~.-~~~~~~~~~~~~~~~~~g~~ ~l~~o~sIa~j~~'.~~~Q~~..---~~~s~I)~~~~o.~IIe~I0~~~0~~~~~'~~~~~o~~~~~~~~-~~~..~~~~~o~I~~~~~I~~~~I~~I~~~~~~~~~~~~~~~~0~~~~~o~~~~~~',~~~~~t~~~~o~t~~~~
VOLATILEORGANICANALYSISRESULTSFORANALYSESUSiNGMETHOD8260Page2of2ClientSamleID:S.SEWAGEPLANTEFFL.LALSamleID:L1009-47ConstituentDibromochloromethanehlrnznhlnznm-Xleneo-XlenernBrmfrm1122-Tetrachloroethane13-Dichlorobenzene14-Dichlrnzen12-DichlorobenzeneConcentrationIL<5<5<5<5<5<5<5ReportingDetectionLimitILDataQualifiersLOCKHEEDANALYTICALSERVICES42 VOLATILEORGANICANALYSISRESULTSFORANALYSESUSINGMETHOD8260TENTATIVELYIDENTIFIEDCOMPOUNDSClientSampleID:S.SEWAGEPLANTEFFLDateReceived:29-DEC-93Matrix:WATERAnalyticalBatch:011094-8260-FZLALSampleID:L1009%7DateAnalyzed:114AN-94DilutionFactor:1QCBatchID:011094-8260-F2TentativelyIdentifiedCompoundUNKNOWNSULFURCOMPOUNDUNKNOWNEstimatedConcentration(pg/L)3728RetentionTimeIminutes)4.47,9.70Data.Qualifierls)LOCKHEEDANALYTICALSERVICES ~~J~1ll~~eI~~s.~~~'~s~~~~y~~~.--~~~.~~I'~~~w~~~a.~o~~a~~~~~~'~~~~~~~~~~~~~~~~~~.-~~..~~~~~~'~~~~e-~~~~~~~~~~~~~'~~0~~~~~~~~~I~~~~~~~'~~~~~~~~~~~~~~~~~~~~00 ~0~e~~I~~~.~e.~~~'~~-~~~ee~~~~~~~~~~'~~,~~~~~~~~~~~~~~~~~~~~.~~~~~~~~~e~~s~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~e~~~~~ ~e~+~~~~~~~~.~I~~II~~~~~~~I'~~~~.~~~~~~~~g~ ~~~~~~IIe~~~~'-~~~~~~~..'-~II'i~III~~~I~I~~I~~II~II~'I~~~I~~:;s~~~~0~~~~~'~'II~~~~~I~~~I~~~~~~~~~~~~~~~~~~~~~~~~~'~-~~~~~~J~~ METALSRESULTSClient-Samle-ID':S;...SENfAGEPLANT'EFF-LALBatchID(s):1220imDate:Collected:12-28-93.DateReceived:12-29-93Matrix::round',water~:'O¹69095-040-3NConstituents",AluminumAntimonArsenicBariumBeIliumBoronCadmiumChromiumCobaltCoerIronLeadManesiumMananeseMercuMolbdenumNickelSeleniumSilverSodiumThalliumTinTitaniumVanadiumZincMethod."60106020'0206020602060106020602060206020601060206010602074706020602060206020601060206020601060106020Co'ncentratlonlmILl<0.20<0.060<0.010<0.20<0.005(0.20<0.005<0.010<0.050<0.025<0.10<0.0030.025<0.0002<0.20<0.040<0.005<0.01034<0.010<0.20(0.10<0.0500.047Reporting0'atectionUmit{mILl0.200.0600.0100.200.0050.200.0050.0100.0500.0250.100.0035.00.0150.00020.200.0400.0050.0105.00.0100.200.100.0500.020Data'uallfierls)NDate;A'nalzed."01-20-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-20-9401-27-9401-07-9401-27-9401-27-9401-27-9401-27-9401-20-9401-27-9401-27-9401-20-9401-20-9401-27-94=',.-.;,LA4.;-",-."'S"'le"lD':L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16L1009-16LOCKHEEDANALYTICALSERVICES~
GENERALCHEMISTRYRESULTSClient-SamleID.'S.,SEWAGEPLANTEFFLLALBatchID(s):1229imDateCollected:12-28-93DateReceived:12-29-93Matrix:roundwater.PO469095-040-3NConstituentMethodResultReportingDetectionLimit'ata'ualifieris)."DateAnalzedLAL,.Samle'IDFluoride,inmILChloride,inmIL340.2300.0Nitrate.Nitroen,inmIL300.0<0.15120240.150.0160.01701-24-94L1009-412-29-93L1009-412-29-93L1009-4Nitrite-Nitroen,inmILSulfate.inmILAmmonia-Nitrogen,inmILTotalCyanide.inmg/L300.0300.0350.1335.2<0.503924<0.0200.500.0590.500.020Dl1:10)12-29-93L1009-412-29-93L1009-401-05-94L1009-801-03-94L1009-12Comments:LOCKHEEDANALYTICALSERVICES
r~ANSTECPPERTURCARD0C31,.0AlsoAvailabieon~Pe~UfeQgpdl'IIL/tIIIIIIttrft0tfII0004~Unit~1TronsforeterDeckDrains(5Dryvells)Outfoll0011200'ffshore3Intokes2250'ffshore/Oufoll003Oe-lainOischofe0nvner400=f=I=I=IctOrOtKKI,Clter-)fN'-'IIII~I/.I//~II~////er/~~co0'~~4~~/IEastSavageTreataentPlontSouthSavageTreattttentPlontSequenc)ng8otchReactorTreatvtentPlantOutfoll00211200'ffshoreNeutral)zotlanTonkUnlte2TransfornerDeckDrains(5tfryvells)StorsvaterOutfallS002StoretvategOutfallS003ttt00tfII0004~Iu12sitesops/site~.100envIvel30In')ldtert~M-'1j~i~<Ncipji;;%info)),00rl:;:",.4"..$).t".Qls"""'.)Poinh,,v.Or;,Rate'r,"Sprpttanound,')laterV,l~0:,.Ov~)av',"d,der,~r/Og~0I-~'G-rjj/jI//I/II/4r0 k~s4tp-~S<e0JeII OUTFALLDESCRIPTIONAVGMAKFLOwFLowIINMCD)%%%WASTEWATERFLOWDZAGRDONALDC.COOKNUCLEARP.I,MANT00IV-ICIRCwTRI042I393002V-2CIRCwTR003OEICEOOau-)SCBLOWOOwN008U-2SGBLOWDOWNOOCHTGBLRBLONDOXNOODTRSDISCHARGE)3lt.Ioo~098.305)743~2340I4.66TOOESEWAGETREATMENTPLANT024SOISTMWZRN.CATCHBASINS02STIIWTR.S.CAtCHBASIN503STMwtRS04sTMwtR.052PLANTSITESANITARY6KItCHENWAstERADIOGRAPHICPROCESSINGLABORATORYw~STEEASTExTENOEOAERATIONPLANTSoIFRDMMAKE-UPwATERPLANtEswCONDENSATESYSTEMDRAININCHEatINGBOILERLAYVPDRAINStoTURBINEROOMSIAJPOUTFALLOOCFR""PROT/ChONNORMALFLASHtANKAKETOWNSHIPTABLEWATERSUPPLYSZARTUPFLASHTANKPHOTOLABTRAININGBUILDINGCHEutstRYLABwastETRAININGBUILDINGHVACSYSTEMwASZELIkESTONEBEONEUTRALIZATIONTANKSCVTHExtENDEDAERATIONPLANTJ.SEQENCINCiiREACTORSIIIHSTALLAtIONDVEI2-95)OUTFALL00)UlCIRCULATINGWATERDISCHARGEl200'FFSHOREI3)INTAKECRIBS2250'FFSHOREUNI'tIDISCHARGEBAYINtaKEFOREBAYNESwMONIT(RUNITISTEAMCONDENSERPROCESSEDGLYCOLPROCESSEOAUXILIARYBLOC.WATERRoSYSTEMREJECTDRAININGOUTFALLOOAUNITICOuPONENZCOOLINGwatERDRAINING5CENLAYUPDRAINSTIXIBINEROOISIAWDAERCENCYOVERFLOWRECENERaTIONNEVTRALIzaTIONMAEUPTANKwaTEPLANTLNON-RADIOLOGICALCHEMIS'IRYLABDRAINSOUTFAQP)DABSORPTIONAXSTECAPERTURECARDAt~0AvailableonApertureCardNDN-EssENZIALsERvIcEwaTEROUTFALL002U2CIRCULATINGwaTERDIScHARGE)200'FFSHOREUNIT2DISCNARGEBAYUNIt2STEAMCo)CENSERMISC.LOADSDRAINIHCALLOUTF008LAYUPDRAINSVNIT2COMPONENTINPLANZSOSMISC.FLOORDRAINSEMERGENCYDIESELJACKETrAVERDRAINSLAKEMICHIGAN503ESwDRAINIHGNORMALFLASHTANK.START-VPFLASHTANKUugtI/UNIT2MAINTRANSFORMERDECKDRAINSISZORMWATER)Rqi~~MIs+-D3OUTFALL003OE-ICINGDISCHARGEwasusED56oatsIN)992/93FLUSHING6ZFSTINGwAtERlsDIRECTEDTOSTORuwaTERAND/ORGROVNOwATEROUTFALLSH<<wBASEDONDATASVBMITTEDIHl993D)4Z4.UNITI/UNI't2EMERGENCTCENERATORPItSIAPSSECURITvDIESELGENERATOROAYTANKOvERFLOWUNITI/UNIT2CATCHBASINOIL/waTERSEPARATORUNITL/uNIZ2ORY'WELLSGROUNDWATERINDIANAMICHIGANPOWERCO.WASTEWATERFLOWPgAQRAMvp~SZS/RFZ2-24-94U)2/wASTWTR.DCN IlI}}