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Environmental Protection Plan Report, Minor Permit Revision Request to Use Water Treatment Chemicals, Iww Permit No. FL0002208
	ML16187A188
Person / Time
Site:	Saint Lucie
Issue date:	06/15/2016
From:	Snyder M; Florida Power & Light Co
To:	; Document Control Desk, Office of Nuclear Reactor Regulation
References
	FL0002208, L-2016-125, VPPSL053
	Download: ML16187A188 (40)
	v • d • e

June 15, 2016 U.S. Nuclear Regulatory Commission Attn: Document Control Desk Washington, DC 20555 Re:

St. Lucie Units 1 and 2 Docket Nos. 50-335 and 50-389 Environmental Protection Plan Report L-2016-125 10 CFR 50.4 EPP 3.2.4 Minor Permit Revision Request to Use Water Treatment Chemicals IWW Permit No. FL0002208 Pursuant to Section 3.2.4 of the St. Lucie Environmental Protection Plan, Florida Power & Light Company (FPL) is hereby forwarding the enclosed copy of the permit revision request to the Industrial Wastewater Facility Permit (Permit Number FL0002208) as issued by the State of Florida Department of Environmental Protection on November 18, 2014.

Please contact Corey Spencer at (772) 467-7436 or Chrissi-Lee Williams at (772) 467-7228 should you have any questions on this matter.

Sincerely, lf(~s/;D Mic~:j{ Snyder Licensing Manager St. Lucie Plant MJS/tlt

Enclosure:

VPPSL053, Florida Power & Light Company - Plant St. Lucie*

IWW Permit No. FL0002208 - Minor Permit Request to Use Water Treatment Chemicals Florida Power & Light Company 6501 S. Ocean Drive, Jensen Beach, FL 34957

Enclosure VPPSL053 Florida Power & Light Company - Plant St. Lucie IWW Permit No. FL0002208 Minor Permit Request to Use Water Treatment Chemicals (39 pages)

L-2016-125 Enclosure

June 15, 2016 Mr. Marc Harris, P.E.

Florida Department of Environmental Protection 2600 Blair Stone Road Tallahassee, Florida 32399-2400 Re:

Florida Power & Light Company

Plant St. Lucie Wastewater Permit No. FL0002208 Minor Permit Revision Request to Use Water Treatment Chemicals

Dear Mr. Harris:

FPL St. Lucie Plant requests a Minor Permit Revision to Industrial Wastewater Permit No.

FL0002208 to authorize the use of water treatment chemicals to produce deionized water at the plant's vendor operated water treatment plant. The plant wishes to transition from using_

GE Water as a vendor to Evoqua Water Technologies. As such, the chemicals proposed for approval include the following:

Name Purpose D osage Frequency Vitec 3000 - Avista RO - Antiscalant 0-3 mg/L Continuous Sodium Bisulfite - Brenntag Feed water Dechlorination 0-3 mg/L Continuous Vitec 5100 -Avista RO - Antiscalant 3-5 mg/L Continuous It should be noted that Sodium Hydroxide will also be used in the Evoqua treatment train for pH adjustment; however, it is already on the list of approved chemicals in the site's NPDES permit.

Also, only one of the antiscalant products listed will be used at any given time. The water treatment plant Reverse Osmosis reject, which will contain small amounts of antiscalant byproducts, will be discharged into the storm drain system. The site storm drains are routed to the west storm water basin, which has a capacity of 11.2 million gallons. West basin overflow water travels into the south and southeast basins.

In order to prevent backflow and site flooding due to heavy rain, batch releases are discharged from the south pond through permitted outfall 1-008. Discharges from 1-008 flow into the intake canal, which is eventually discharged through outfall D-001 into the Atlantic Ocean.

Provided are the following items in pursuit of a minor permit revision:

1. Process Flow Diagram of the Evoqua permanent water treatment plant

2. Stream composition table for the permanent water treatment plant.

3. Process Flow Diagram of the Evoqua Temporary water treatment system

4. Stream composition table for the temporary water treatment system

5. Chemical Safety Data Sheets for each of the proposed chemicals

6. Minor permit revision application The temporary system will be used to produce DI water while the permanent system is being constructed. The number of discharges from 1-008 varies. Generally, during the rainy season there are 1-3 releases per month and during the dry season 0-1 releases per month. The RO reject flow rate will not increase - 111 gpm (avg. daily flow) projected for the Evoqua system.

Since the discharge is diluted with a very large volume of cooling water (avg 1,362 MGD), the dilution rate of reject to cooling water at the point of discharge (POD) is approximately 8,522 to

1. This dilution ratio is very conservative since 1-008 only discharges right before or during wet weather and ends up mixing with large volumes of stormwater. To demonstrate compliance with the toxicity standards, the following table shows the concentrations at the POD without the benefit of additional dilution during wet weather or degradation of the products.

Dosage Conc.@POD (mg/L)

(mg/L)

LCSO (mg/L)

IC25 (mg/L)

Vitec 3000 3

0.0004

>1,000 Vitec 5100 5

0.00d6 49 Na Bisulfite 3

0.0004 1.2*

Chronic Toxidty level listed iri PA DEP approved chemical additives listing.

Additionally, since the Department has recently implemented nutrient standards for surface waters, the following table shows calculated Total N and P increase in concentrations at the POD, again without the benefit of additional dilution or degradation.

The nutrient concentration for the products was provided by the manufacturer.

Increase in N Increase in P at Total N (%)

at POD (mg/L)

Total P (%)

POD (mg/L)

Vitec 3000 1.2%

0.000004 5.8%

0.000020 Vitec5100 0.2%

0.000001 2.8%

0.000016

We feel this information adequately demonstrates that use of the new chemicals will pose no concerns with either toxicity or nutrient standards. 'If you should have any questions or require additional information regarding' this permit revision request~ please feel free to contact Mr.

Corey Spencer at (772) 467-7436 or Ms. Chrissi-Lee Williams at (772) 467-7228 or via email at chri_ssi-lee. williams@fpl:co1_11.

Sincerely,

~~l &.,*?

Chrjst_opher R. Costanzo Site Vice President St. Lucie Plant VPPSL053

Enclosures:

Figures 1-4 (4 pages); Avista Vitec© 5100 SDS (11 pages); Avista Vitec© 3000 SDS (11 pages); BRENNTAGSDS (7 pages); Minor Revisi.on IWWW Permit Application (2 pages); FPL check #5000437720 payable to FDEP for $250.00 (1) cc:

FDEP-Southeast District Office FDEP "'"",Siting Coordination Office

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0.06 19:11 0.7156 0.056 25~7

.Notes:

"Gompos.ition rah.le reflects 4()(1 gpm DJ producl v,ra1erpumped furward iri.l*pa:ss mode wirh tlgpm DI produci: water recircufa1i011

M All.2"0 pass RO rnjeci.is wr;ycled ~o* *1<< pass feectw~rer.aari allo\\'e c11mpr:witioo retieets rn~ b.renlllit composJ1im1 1<lirll 1M inr:oming mr.mi wimr Figure 2 Permanent Evoqua System Stream Composition Table.

- Bisulfile*

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rn

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3.S 3.6 l'l.035 lUJ36

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0 0

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20Ai 1.21l4 1.294:

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0 0

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<ll.01

<-O.ll1

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7. Hi*

7.03 7.S 7.S 7.. 7'9 1.04 7.M 7.04 7.M 7.1l4 J.T Comiu<livity, uS/cm 456 436

~

4.

3 O.Dti ll.05*

.<l.Dlifio o._055 Q.05'6 1950 Notes~

Comp0&ilfon fable relfects 400 gpm D1 product water pumped forward ;ml 44 gpm.DI product wa.ter recirculated back to RO permeate tank

~ All 2"" pass RO reject ii; re eye.fed to 1" passieedwa te.r <1 nd above compG.Sition re:trects tfle bJe.nded compDSition with *lhe ina*oming muni wa.fer Figure 4 Temporary Evoqua System Str.eam Composition Table

Avista vitec© s100 TECH NO LOG I ES SAFETY DATA SHEET

t. Company and Product Identification 1.1 Identification - Product Name:

Vitec© 5100 1.2 1.3 1.4 1.5 Other means of identification Synonym:

Recommended Use Of The Chemical and Restrictions On Use:

Name, Address, And Telephone Number Of The Manufacturer, Or Other Responsible Party:

Competent Person email address 24 Hour Emergency No.:

Organo-phosphorous compounds

.Mixture, none Reverse osmosis membrane antiscalant Use only as directed on tbe label.

A VISTA TECHNOLOGIES 140 Bosstick Street San Marcos, CA 92069 (760) 744-0536 klindsey@avistatech.com 1-800-424-9300 (United States) 1-202-483-7616 (International Collect)

L*~

( NSE) DRINKING WATER TREATMENT ADDITIVES CLASSIFIED BY NSF

'C7 INTERNATIONAL TO ANSI/NSF 60 AS STANDARD DRINKING WATER G§D TREATMENT CHEMICAL FOR USE IN REVERSE OSMOSIS SYSTEMS AT A MAXIMUM LEVEL OF 13 mg/I.

2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: This product is amber to light yellow water-based solution with a light disinfectant odor. This product may irritate contaminated tissue. This product is neither reactive nor flammable.

Physical Hazards Summary None Potential Health Hazards Summary Skin corrosionfrrritation, Category 3 H315 Causes skin irritation H319 Causes serious eye irritation Potential Ecological Effects Summary None 2.1 Classification Of Product Skin, eye irritant U.S. OSHA classification Skin corrosion/irritation, Category 3 Oassification as per EC 1272/2008 H315 Causes skin irritation (CLP/GHS)

H319 Causes serious eye irritation WHMIS classification D2B - Poisonous and.infectious material - Other effects - Toxic VITEC 5100 PUBLIC GHS SOS PAGE1 OF11

Hazardous Materials Information System (HMIS) Rating 2.2 Label Elements OSHA/GHS General Warnings Signal Word.

Hazard statements Precautionary statements Hazard pictograrns PlOl P102 Pl03 WARNING!

H315 H319 H335 P27l P281 P312 P302/P352 P261 P305 + P351

+P338 2.3 Unclassified Hazards None 2.4 Ingredients with uilknovm acute None toxicity If medical advfoe is needed, have product container or label at hand.

Keep out of reach of children.

Read label before use Causes skin irritation Causes serious eye irritation May cause respiratory irritation Use only outdoors or in a well-ventilated area.

use personal protective equipment as required.

IF SW ALLOWEP: Call a POISON CENTER or doctor/physician if you feel unwell.

Avoid breathing.dust/ fume/ gas/ mist/ vapours/spray.

P305 + P351 + P338 :IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to.do.

Continue. rinsing.

3. COMPOSITION and INFORMATION ON INGREDIENTS Chemical name

%w/w US OSHA GHS/EUCLP WHMIS CAS#

EINECS#

Deflocculant & Sequestrant 10-20 Corrosive Skin corrosion/irritation, E, corrosive Proprietary Category 3 Proprietary H319 Causes serious eye irritation P305 + P351 + P338 IF IN EYES: Rinse.

cautiously with water for several minutes; Remove contact lenses, if present and easy to do. Continue rinsing.

Keep out of reaeh of VITEC© 5100 PUBLIC GHS SOS PAGE20F11

children.

Keep away from food, drink and animal feeding stuffs.

A void contact with skin.

Avoid contact with eyes.

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Wear.suitable protective clothing. If swallowed, seek medical advice immediately and show this container or label Phosphonic acid derivative 5-15 Corrosive Skin corrosion/irritation, E, corrosive Proprietary Category3 Proprietary H319 Causes serious eye irritation P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Keep out of reach of children.

Keep away from food, dririk and animal feeding stuffs.

A void contact with skill.

A void contact with eyes.

In case of contact with eyes, rinse immediately i

with plenty of water and seek medical advice.

Wear suitable protective clothing. If swallowed, seek medical advice immediately and show this container or label Because of pH adjustment, product is not corrosive, but is a skin/eye irritant NE= Not Established. C =Ceiling Limit. See Section 16 for Definitions of Terms Used.

VITEC 5100 PUBLIC GHS SOS PAGE30F11

4. FIRST-AID MEASURES 4.1 Description of Necessary Measures 4.2 4.3 Skin exposure: If this product contaminates the skin, immediately begin decontamination with running water. Remove exposed or contaminated clothing, taking care not to contamin;ite eyes. Victim should seek immediate medical attention if any adverse exposure symptoms develop.

Eye exposure: If this product enters the eyes, open victim's eyes while under gently running water. Use sufficientforce to open eyelids, Have victim "roll" eyes. Minimilm flushing is for 15 minutes. Victim must seek medical attention.

Inhalation: If vapors, mists, or sprays of this product are inhaled, remove victim to fresh air~

If necessary, use artificial respiration to support vital functions. Remove or cover gross contamination to avoid exposure to rescuers.

Ingestion: If this product is swallowed~ CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION. DO NOT INDUCE VOMITING. Have victim rinse mouth with water, if conscious. Never induce vomiting or-give a diluent(e.g., water) to someone who is un¢onscious, having convulsions, or unable to swallow. If contaminated individual is convulsing, Most Important Symptoms/Effects:

Indication Oflmmediate Medical Attentlon And Special T;reatment Needed, If Necessary:

mainta'in an open airway and obtain immediate medical attention.

Immediate: Inhalation exposure may cause coughing or sneezing. Symptoms of skin and eye contact may include redness and irritation. Ingestion may cause stomach pains, cramps, and gru.tritis.

Delayed: Prolonged or repeated skin overexposure to this product may cause dermatitis (dry, red skin). Symptom~ may include tingling, redness, and visible injury.

TARGET ORGANS: Acute: Skin, eyes.

Chronic: Skin.

Victims of chemical exposure must be taken for medical.attention if any adverse effects occur;.Rescuers should be taken for medical attention if necessary. Take a copy of label and MSDS to physician or health professional with victim.

5. FIRE-FIGHTING MEASURES Flammable properties Non-flammable aqueous solution Flash Point °C (°F): Not applicable.

NFPA FLAMMABILITY OTHER.

See Section 16 for definitions of ratings Autoignition Temperature °C (°F):

Not applicable.

VITEC© 5100 PUBLIC GHS SOS Flainmable Limits (in air by volume, % ):

Upper: Not applicable; Lower: Not applicable.

PAGE40F11

5.1 5.2 5.3 6.1 6.2 7.1 7.2 Suitable And Unsuitable Extinguishing This material will not contribute to the intensity of a fire. Use. extinguishing

t>.1edia:

material suitable to the surrounding fire.

Water spray YES Foam YES Halon YES Carbon dioxide Dry chemical Other YES YES YES Specific Hazards Arising From Chemical:

When involved in a fire, this material may decompose and produce irritating fumes and toxic gases (e.g., carbon monoxide, carbon dioxide, and phosphorous oxides).

Explosion Sensitivity to Mechanical Impact: Not sensitive.

Explosion Sensitivity to Static Discharge: Not sensitive.

Special Protective Equipment And Precautions For Fire-Fighters:

Incipient fire responders should wear eye protection. Structural firefighters must wear Self-Contained Breathing Apparatus and full protective equipment Move containers from fire area if it can be done without risk to personnel. If possible, prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive areas.

Personal Precautions

6. ACCIDENTAL RELEASE MEASURES Uncontrolled releases should be responded to by trained personnel using pre-planned procedures. Proper protective equipment should be used. In case of a spill, clear the affected area and protect people.

Protective equipment For small releases(< 5 gallons), clean up spilled liquid wearing gloves, goggies, faceshield, and suitable body protection. The minimum Personal Protective.

Equipment recommended for response to non-incidental releases (more than 5 gallons) should be Level B: triple-gloves (neoprene gloves and nitrile gloves over latex gloves), chemical resistant suit and boots, hard hat, and Self-Contained Breathing.Apparatus.

Emergency procedures Monitoring must indicate that exposure levels are below those provided in Section 3 (Composition and Information on Ingredients) and that oxygen levels are above 19.5% before anyone is permitted in the area without Self-Contained Breathing Apparatus.

Methods and Materials for Containment and OeaningUp Soak up or wet vacuum spilled liquid. Neutralize residue with sodium bicarbonate or other neutralizing agent for dilute acids. Decontaminate the area thoroughly. Test area with litmus paper to ensure neutralization. Place all spill residues in a suitable container. Dispose of in accordance with applicable U.S.

Federai, State, or local procedures, or appropriate local standards (see Section 13, Disposal Considerations).

Precautions for Safe Handling Conditions For Safe Storage

7. HANDLING and STORAGE All employees who handle this material should be trained to handle it safely. Open containers carefully ori a stable surface. Empty containers may contain residual liquid; therefore, empty containers should be handled with care.

As with all che1nicals, avoid getting this product ON YOU or IN YOl!. Wash thoroughly after handling this product Do not eat or drink while handling this material. A void generating mists and sprays of this product Remove contaminated clothing immediately.

During equipment maintenance follow practices indicated in Section 6 (Accidental Release Measures) to decontaminate equipment or clean-up small spills. Make certain that application equipment is locked and tagged-out safely if necessary. Collect all rinsates and dispose of according to applicable U.S. Federal, State, or local procedures or appropriate local standards.

Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store away from incompatible materials. Material should be stored in secondary containers, or in a diked area, as appropriate. Storage and use areas should be covered with impervious materials.. Keep container tightly closed when not in use.

If appropriate, post warning signs in storage and use areas. Inspect all incoming containers before storage, to ensure containers are properly labeled and riot damaged.

Incompatibilities Strong bases, strong oxidizers, very strong acids, water reactive materials.

VITEC© 5100 PUBLIC GHS SOS PAGE 5OF11

8. EXPOSURE CONTROLS - PERSONAL PROTECnON 8.1 Control Parameters EXPOSURE LIMITS JN AIR CHEMICAL NAME CAS#

%w/w ACGill-1LV OSHA"PEL NIOSH OTHER TWA STEL TWA STEL IDLH mg/m3 mg/m3.

mg!m3 mg/m3 mg/m3 mg/m3 Deflocculant &

Proprietary 10-20 NE NE NE NE

~

NE Sequestrant Phosphonic acid derivative Proprietary 5-15 NE NE NE NE

NE NE IW ater and other components which are present in None of the other components contnbute significant additional hazards at the concentration present in less than I percentccincentration (0.1 %

this product All pertinent hazard information has been provided in this document, per the requirements concentration for potential carcinogens, Balance of the Federal. Occupatignal Safety and Health Administration Standard (29 CPR 1910.1200), U.S.Sµte reproductive toxins, respiratory tract sensitizers equivalentStandards and Canadian Wor!..-place Hazardous Materials Identification System Standards and mutagens).

(CPR4).

8,.2 Appropriate Engineering Controls.

Use with adequate ventilation to ensure exposure levels are maintained below the limits provided in this Section or as low as reasonably achievable, Ensure eyewash/safety shower stations are available near areas where this product is used.

8.3 Personal Protective Equipment None needed under normal conditions of use. Use NIOSH approved respirators Appearance

,Odor Melting Point °C Initial Boiling Point °C Flammability Vapor Density (air = 1)

Solubility (in water)

Viscosity Respiratory protection: if ventilation is inadequate to control mists or vapor. If respiratory protection is needed, use only protection authorized in the U.S. Federal OSHA Standard (29 CFR 1910.134), applicable U.S. State regulations, or the applicable local standards. Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use of a full-face piece pressure/demand SCBA or a full-face piece, supplied air respirator with auxiliary self-contained air supply is required under OSHA's Respiratory Protection Standard (1910.134-1998).

Eye protection:

Use approved safety goggles or safety glasses, as described in OSHA 29 CFR 1910.133. Splash goggles with a faceshield may be needed if splash hazards exist.

Hand protectio11:

Wear chemical impervious gloves (e.g., Neoprene or Nitrile).

Body protection: If needed, use body protection appropriate for task (e.g., Tyvek suit, rubber apron) to protect from splashes and sprays.

9. PHYSICAL and CHEMICAL PROPERTIES This I>roductis a clear, amber liquid with a light disillfectant odor.

Light disinfectant odo~

Odor Threshold N/ A Similar to water pH (2% solutiori) 5.0 - 6.5 100 Non-flammable Similar to water Soluble Sltrrilar to WiJ.ter Boiling Point Range 0c Evaporation.Rate (water= 1)

Vapor Pressure mm Hg @ 20°C:

Relative density (water = 1)

Oil~Water Partition Coefficient NIA Similar to water 18 1.10 +/- 0.05 NIA Decomposition Temperature NIA How To Detect This Substance The color and odor may act as warning properties associated with this product (Warning Properties):

VITEC© 5100 PUBLIC GHS SOS PAGE 6 OF 11

10.1 10.2 10.3 10.4 10.5 10.6 11.1

10. ST ABILITY and REACTIVITY Reactivity Chemical Stability Possibility of hazardous reactions Conditions to avoid Incompatible Materials Hazardous Decomposition Products Not considered reactive.

Stable Hazardous polymerization will not occur.

Avoid mixing with incompatl"ble materials.

Strong bases, strong oxidizers, very strong acids, water reactive materials.

Thermal decomposition of this product may generate carbon monoxide, carbon dioxide, and phosphorus oxides.

11. TOXICOLOGICAL INFORMATION Information on Toxicological Effects Toxi,city data for Denn al Inhalation hazardous ingredients Orall.D50 mg/kg LD50mg/kg LD,omg/kg Deflocculant & Sequestrant lD50 (Oral-Rat) 2100 mg/kg Standard Draize Test (Skin-LD,0 (Skin-Rabbit)> 6310 mg/kg Rabbit) 500 mg/24 hours LD50 (Oral-Quail)> 2510 mg/kg Standard Draize Test (Eye:.

LD,0 (Oral-Duck) > 2510 mg/kg Rabbit) 100 mg: Moderate TDLo (Oral-Rat) 1302 mg/kg/31 days-NIA intermittent: Kidney, Urethra, Bladder: other changes in urine composition; Nutritional and Gi:oss Metabolic: weight loss or decreased weight gain, changes in sodium.

Phosphanic acid derivative NIA NIA NIA Potential routes of exposure Inhalation, skin contact, eye contact Potential effects of acute over-exposure Inhalation exposure may cause tingling, coughing, sneezing, and difficulty breathing. Symptoms of skin and eye contact may include redness and initati~n. fugestion may cause stomach pains, cramps, and gastritis.

Potential effects of chronic over-exposure Prolonged or repeated skin overexposure to this product may cause dermatitis (dry, red skin). Symptoms may inciude tingling, redness, and visible injury.

Symptoms of over-ex1msure Immediate: Inhalation exposure may cause tingling, coughing, sneezing, and difficulty breathing. Symptoms of skin and eye contact may include redness and irritation. lngestion may cause stomach pains, cramps,,and gastritis.

Delayed: PIDlonged or repeaioo skin overeJqiosure to this product may cause dermatitis (dry, red skin).

Symptoms may include tingling, redness, and visible injury.

Conditions a!(gr.ivated by over-expos'ure Preexisting dermatitis, other sl.in conditions, and respiratory conditions may be aggravated by exposures to this product Recommendations to physicians:

Treat symptoms and eliminate exposure.

Irritation YES This product can be iiritating to contaminated tissue.

Sensiti7.ation NO Carcinogenicity NTP

!ARC US OSHA CAL OSHA 67/548EEC Annex I NO NO NO NO NO Mutagen}ci!)'

NO Reproductive toxicity NO Biological Exposure Index NIA Olher potential health effects Currently, there are no Biological Exposure Indices (BEis) for any component of this product.

VITEC© 5100 PUBLIC GH$ SOS PAGE70F11

12. ECOLOGICAL INFORMATION ALL WORK PRACTICES MUST BE AIMED AT ELIM/NA TING ENVIRONMENTAL CONTAMINATION:

12.1 122 12.3 12.4 12.5 Ecotoxicity NOE~, ppm IC25, ppm (Inhibition Concentration)

Vitec©5100 Aquatic Ceriodaphnia dubia 25 49.0 Pimephales promelas > 1000

>1000 Terrestrial NIA NIA Persistence and Degradability The components of this product decompose in soil and water.

Bioaccumulative Potential The components of this product are not expected to bioaccmrn1late.

Mobility in.Soil Moderately mobile.

Other Adverse Ecological Effects This product may be harmful to aquatic life if large volumes of i~ are rel~!ISed jnto an aquatic environment.

13. DISPOSAL CONSIDERATIONS Preparing Wastes of this Product for Disposal Disposal of Contaminated Packaging U.S. EPA Waste Number Waste disposal must be in accordance with appropriate U.S. Federal, State, and local regulations or with local regulations. This product, if unaltered by the handling, may be disposed of.by treatment at a pennitted facility or as advised by your local wastt regulatory authority, Cleaned containers can be recycled or disposed of as non-contaminated waste, if authorized by your local authorities. Dispose of containers as required by local re~lations.

Not applicabie.

14. TRANSPORT INFORMATION THIS MATERIAL IS NOT HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF TRANSPORT AT/ON.

14.1 142 14.3 14.4 14.5 14.6 14.7 UN Number UN Proper Shipping Name Transport Hazard Class( es)

Transport label(s) required Packing Group Marine Pollutant NA Emergency Response Guide Number (2008)

Transport in Bulk (Annex II of MARPOL 73n8 and IBC Code)

Special Transport Precautions National Motor Freight Classification Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Notapplicable Not applicable Not applicable

70 International Air Transport Association UN Number Not applicable UN Proper Shipping Name Not applicable Transport Hazard Class( es)

Not applicable Transport label(s) required Not applicable Packing Group Not applicable IATA Emergency Response Code Not applicable Excepted Quantity Not applicable VITEC 5100 PUBLIC GHS SOS PAGE 8OF11

P..ackaging Instructions Not applicable International Maritime Organization UN Number UN Proper Shipping Name Transport Hazard Class( es)

Transport label(s) required Packing Group Marine Pollutant NA Emergency Response Guide Number (2008)

Transport in Bulk (Annex Il of MARPOL 73/78 and IBC Code)

Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable

15. SAFETY, HEAL TH and ENVIRONMENTAL REGULATIONS SPECIFIC FOR THE PRODUCT Clean Air Act Hazardous Air NO NO Pollutants Safe Drinking Water NO NO Act EPA Priority Pollutant NO NO RCRA F, K, P, U or NO NO D-lists SARA302 RQ NO NO SARA302 TP NO NO SARA 313 LISTED NO NO SARA CHEMICAL CATEGORIES SARA 311/312 ACUTE YES YES SARA 311/312 NO NO CHRONIC SARA 311/312 FIRE NO NO SARA 311/312 NO NO PRESSURE SARA311/312 NO NO REACTIVITY EPA EXTREMELY HAZARDOUS NO NO SUBSTANCE E,D2B E,D2B YES YES VITEC© 5100 PUBLIC GHS SOS PAGE90F11

NDSL NIA NIA REACH Prt<-registered YES YES List TSCA YES YES European Inventory of Existing Commercial YES YES Chemical Substances (EINECS)

EU No-Longer NO NO Polymers List (NLP)

EEC Classification Packaging, and Labeling Skin corrosion/irritation, Category 3 Skin corrosion/irritation, Category of Dangerous Substances(Annex 1)

Philippines Japan Australia Korea China New Zealand InventQry of Chemicals 16.1 16.2 16.3 16.4 Original Preparation Revision History Prepared by Date of Printing VITEC© 5100 PUBLIC GHS SOS 3

YES YES YES YES YES YES YES YES YES YES YES YES

16. OTHER INFORMATION Updated April 06, 2009, Revised 04c01-11, 16 Apr 2012 11 June.2013 Reformatted to GHS Requirements ADVANCED CHEMICAL SAFE'IY, Inc.

PO Box 152329 San Diego, CA 92195 (858)-874-5577 April 28, 2015 PAGE 100F 11

DEFINITIONS OF TERMS 16.5 A large number of abbreviations and acronyms appear on a MSDS. Some of these which are commonly used include lhe following:

Section2 GHS: Global Harmonization System OSHA: U.S. Occupational Safety and Health Administration.

CLP: Classification and Packaging WHMIS: Worlq>lace Hazardous Materials Information System STOT: Soecific Tamet Or""n Toxicitv Section3 CAS #: Chemical Abstract Service index number EINECS #: Eurooean Chemical Substances lnfonilation Svstem index number Sections 1\\"'FPA: Nation Fire Protection Association Health Hazard: 0 (material that on exposure under fire conditions would offer no hazard beyond that of ordinary *combustible materials); 1 (materials that on exposure under fire conditions could cause irritation or minor residual injury); 2 (materials.that on intense or continued exposure under fire conditions could cause temporary.incapacitation or possible residual injury); 3 (materials that can on short exposure could cause serious temporary or residual injury); 4 (materials that under very short exposure could cause death ormajor residual injury). Flammability Hazard Reactivity Hazard: Refer to definitions for "Hazardous Materials Identification System".

Flash Point Minimum temperature at which a liquid gives off ~ufficient vapors to f~ an ignitable mixture with air.

Autoignition Temperature: The minimum temperature required.to initiate combustion in air with no other source of ignition.

LEL: The lowest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. UEL: The highest percent of vapor in air, by volume, that will explode or i!!nite in the presence of an i!mition source.

Section 8 ACGffi - American Conference of Governmental Industrial Hygienists, a professional association which establishes exposure limits.

TL V - Threshold Limit Value - an airborne concentration of a substance which represents conditions under which it is generlilly believed that nearly all workers may he repeatedly exposed without adverse effect. *The duration must be considered, including the 8-hour Time Weighted Average (TWA), the 15-minute Short Term Exposure Limit, and the instantaneous Ceiling Level (C). Skin absorptiou effects must also be considered PEL - Permissible Exposure Limit - This exposure value means exactly the same as a TL V, except that it is enforceable by OSHA.

The OSHA Pennissible Exposure Limits are based in the 1989 PELs and the June, 1993 Air Contaminants Rule (Federal Recister: 58: 35338-35351 and 58: 40191). Both the current PELs and the vacated PELs are indicated. The phrase, "Vacated 1989 PEL,".is placed next to the PEL which was vacated by Court Order.

IDLH - Immediately Dangerous to life and Health - This level represents a concentration from which one can escape within 30-minutes without suffering escape-preventing or permanent injury. The DFG - MAK is the Republic of Germany's Maximum Exposure Level, ~-iillilar to the U.S, PEL NlOSH is lhe National Institute of Occupational Safety and Health, which is the research arm of the U.S. Occupational Safety and Health Administration (OSHA). 1'10SH issues exposure gilldelines called Recommended Exposure Levels (RELs).

When no exposure gilldelines are established, an entry of NE (Not Established) is made for reference.

.Section 11 LDso : Lethal Dose (solids & liquids) which kills 50% of the exposed animals; LC~ : Lethal Concentration (gases) which kills 50% of the exposed animals; ppm: Concentration expressed in parts of material per million parts of air or water; mg/m3 : Concentration expressed in weight of substance per volume of air; mg/kg: Quantity of material, by weight, administered to a test subject, based on their body weight in kg IARC - the International Agency for Research on Cancer; NTP - the National Toxicology Program, RTECS-the Registry of Toxic.Effects of Chemical. Substances, OSHA and CAL/OSHA.

IARC and NTP rate chemicals on a scale of decreasing potential to cause human cancer with rankings from 1 to 4. Subrankings (2A, 2B, etc.) are also used.

TD Lo, the lowest dose to cause a symptom and TC..~o the lowest concentration to cause a symptom; TDo, LDLo, and LDo, or TC, TCo, LCLo, and LCo, the lowest dose (or concentration) to cause lethal or tcixic effects.

BEI - Biological Exposure Indices, represent the levels of determinants which are most likely to be observed in. specimens collected from a healthy worker who has been exposed to chemicals to the same exteut as a worker with inhalation exposure to theTLV.

Section 12 LC50: The lowest concentration iii water which kills 50% of the test*subjects.

ECso: The Effect Concentration in water at which 50% of the test species if affected.

Section 13 US EPA Hazardou5 Waste Codes: refer to 40 CFR 261.20 Section 14 DOT: US Department of Transportation IA TA: International Air Transport Association Th10: International Maritime Organization

MARPOL: International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978 IBC Code: Merchant Shipping Code Section 15 RCRA: US Resource Conservation and Recovery Act SARA: US Superfund Amendments and Reauthorization Act PSM: US OSHA Process Safety Management CF A TS: US Department of Homeland Security Chemical Facility Anti-terrorism Standard DSL: Canadian Domestic Substances List l'<'DSL: Canadian Non-Domestic Substances Llst REACH: European Registration, Evaluation, Authorization and Restriction of Chemicals list TSCA: US Toxic Substances Control Act VITEC© 5100 PUBLIC GHS SOS PAGE 11OF11 I

I

Vitec 3000 SAFETY DATA SHEET

1. Company and Product Identification Ll Identification~ Product Name:

Vitec 3000 1.2 1.3.

1.4 1.5 Other means of identification Synonym:

Recommended Use OfThe Chemical and Restrictions On Use:

Name, Address, And Telephone Number Of The 1\\llantifacturer, Ot Other Responsible Party:

Competent Person email address 24 Hour Emergency No.:

Organo-pbospborous compounds Mixture, none Reverse osmosis membrane antiscalant Use only as directed on the label.

A VISTA TECHNOLOGIES 140 Bosstick Street San Marcos, CA 92069 (760) 744-0536 klindsey@avistatech.com 1-800-424-9300 (United States) l-703 527-~887 (International Collect)

(uN~*

. I:

CERTIFIED BY NSF INTERNATIONAL TO NSF/ANSI 60 AS

\\~

STANDARD DRINKING WATER TREATMENT CHEMICAL

~

FOR USE JN REVERSE OSMOSIS SYSTEMS AT A MAXIMUM

~

L;EVELOF 7 mg/I.

2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: This product is amber to light yellow water-based solution with a light disinfectant odor. This product may irritate contaminated tissue. This prod1.1ct is neither reactive nor flammable.

Physical Hazards Summary None Potential Health Hazards s11rnmary Skin corrosion/irritation, Category 2 H315 Causes skininitation H3J9 Causes serious eye irritation Potential ECological Eft"e<;;ts. Summary None.

2.1 Classification Of PrQd11¢t Skin, eye ii:ritant U.S. OSHAclassification Skin corrosion/irri~tlon; Category 2 Classification as per EC 1272i2008 g315 Causes skin iI:r.itation (CLP/GHS)

H319 Causes serious eye irritation E, corrosive WHMIS classification D2B-Poisonous and infectious material - Oi:her effects - Toxic VITEC 3000 GHS SOS PAGE10F11

Hazardous Materials Information System (IlliIS) Rating 2.2 Label Elements OSHA/GHS 2.3 2.4 General Warnings PlOl Pl02 Pl03 Signal Word Hazard statements Precautionary statements Hazard pictograms WARNING!

H315 H319 H335 P271 P281 P312 P302/P352 P261 P305 + P351

+P338 Unclassified Hazards None Ingredients with unknown acute None toxicity If medical advice is needed, have product container or label at hand.

Keep out of reach of children.

Read label before use Causes skin irritation Causes serious eye irritation May cause respiratory irritation Use only oµtdoors or in a well-ventilated area.

Use personal protective equipment as required.

IF SW AI.LOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.

Continue rinsing.

.IT'

\\lJ

3. COMPOSITION and INFORMATION ON INGREDIENTS Chemical name

%w/w US OSHA GHS/EUCLP WHMIS CAS#

EINECS#

Deflocculant & Sequestrant 20-30 Irritant Skin corrosionfrrritation, E, corrosive Proprietary Category2 D2B - Poisonous H315 Causes skin and infectious

.irritation material - Other H319 Causes serious eye effects - Toxic irritation H335 May cause respiratory irritation P261 Avoid breathing dust/ fume/ gas/ mist/

vapors/ spray.

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for VITEC 3000 GHS SOS PAGE20F11

several minutes. Remove contact lenses, if present and easy to do~ Continue rinsing.

Keep out of reach of children.

Keep away from food, drink and animal feeding stuffs.

A void contact with skin.

A void contact with eyes.

In case of contact with eyes; rinse immediately with plenty of water and seek medical advice.

Wear suitable protective clothing. If swallowed, seek medical advice immediately and show this container orlabel Chelate Agent 10-20 Corrosive Skin corrosion/irritation, E, corrosive Proprietary Category2 H319 Causes serious-eye irritation P305 + P351 + P338 JF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Keep out of reach of children.

Keep away from food, drink and animal feeding stuffs.

Avoid contactwith skin.

Avoid contact with eyes.

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Wear suitable protective clothing. If swallowed, seek medical advice immediately and show this container or label

_pH adjustment agent 20-30 Low Hazard H314 Causes severe Not regulated Proprietary bums 1'305 +P351 +P338lF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Keep out of reach of children.

Keep away from food, drink and animal feeding VITEC 3000 GHS SOS PAGE30F11

stuffs.

Ayoid contact with skin, Avoid eontaet with eyes.

In case of contact with eyes,. rinse immediately with plenty of water and seek medical advice.

Wear suitable protective clothing. If swallowed, seek medical advice immediately and show this container or label Water or other chemicals do not balance NIA N/A N/A contribute to any additional hazards of this product NE= Not Established. C =Ceiling Llmit. See Section 16 for Definitions of Terms Used.

4. FIRST-AID MEASURES-4.1 Description of Necessary Measures 4.2 4.3 Skin exposure:

Eye exposure:

Inhalation:

Ingestion:

Most Important Symptoms/Effects:

Indication Of Immediate Medical Attention And Special Treatment Needed, If Necessary:

If this product contaminates the skin, immediately begin decontamination with running water. Remove exposed or contaminated clothing, taking care not to contaminate eyes. Victim should seek immediate medical attention if any adverse exposure symptoms develop.

H this product enters the eyes, open victim's eyes_ while und~r gently running water. Use sufficient force to open eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. Victim must seek medical attention.

If vapors, mists, or sprays of this product are inhaled, remove victim to fresh air.

H necessary, use artificial respiration to support vital functions. Remove or cover gross contamination to avoid exposure to rescuers.

If this product is swallowed, CALL PHYSICIAN OR POISON CONIROL CENTER FOR MOST CURRENT INFORMATION. DO NOT INDUCE VOMITING. Have vietlm rinse.mouth with water, if conscious. Never induce vomiting or give a diluent (e.g., water) to someone who is unconscious, having convulsions, or unable to swallow. If contaminated individual is convulsing, maintain an open airway and obtain immediate medical attention.

Immediate: Inhalation exposure may cause coughing or sneezing; Symptoms of skin and eye contact may include redness and irritation. Ingestion may cause stomach pains, cramps, and gastritis.

Delayed: Prolonged or repeated skin overexposure to this product may cause dermatitis (dcy, red skin). Symptoms may include tingling, redness, and visible irijury.

TARGET ORGANS: Acute: Skin, eyes, Chronic: Skin.

Victims of chemical exposure must be taken for medical attention if any adverse effects occur. Rescuers should be taken for medical attention if necessary. Take a copy of label and MSDS to physician or health professional with victim.

VITEC 3000 GHS SOS PAGE40f 11

5.1 5.2 5.3

5. FIRE-FIGHTING MEASURES Flammable properties Non-flammable aqueous solution NFPA FLAMMABILITY Suitable And Unsuitable Extinguishing Media:

Specific Hazards Arising From Chemical:

Special Protective Equipment And Precautions For Fire-Fighters:

OTHER See Section 16 for defuii.tions of ratings Flash Point °C (

0F): Not applicable.

Autoignition Temperature °C (°F):

Not applicable.

Flammable Limits (in air by volume, % ):

Upper: Not applicable.

Lower:

Not applicable.

This material will not contribute to the intensity of a fire. Use extinguishing material suitable to the surrounding fire.

Water spray YES Foam YES Halon YES Carbon dioxide Dry chemical Other YES YES YEs When involved in a fire, this material may decompose and produce irritating fumes and toxic gases (e.g., carbon monoxide, carbon dioxide, and phosphorous oxides).

Explosion Sensitivitv to Mechanical Impact Not sensitive.

Explosion Sensitivity to Static Discharge: Not sensitive.

Incipient fire responders should wear eye protection. Structural firefighters must wear Self-Contained Breathing Apparatus and full protective equipment Move containers from fire area if it can be done without risk to personnel. If possible, prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive areas.

6. ACCIDENTAL RELEASE MEASURES 6.1 Personal Precautions Uncontrolled releases should be responded to by trained personnel using pre-planned procedures.. Proper protective equipment should be used. In case of a spill, clear tl:te affected area and protect people.

6.2 Protective equipment For small releases ( < 5 gallons), clean up spilled liquid wearing gloves, gog_gles, faceshield, and suitable body protection. The minimum Personal Protective Equipment recommended for response to non-incidental releases (more than 5 gallons) should be Level B: triple-gloves (neoprene gloves and nitrile gloves

-0ver latex gloves), chemical resistant suit and boots, hard hat, and Self-Contained Breathing Apparatus.

Emergency procedures Mouitoring must indicate that exposure levels are below those provided in Section 3 (Composition and Information on Ingredients) and that oxygen.levels are above 19.5% before anyone is permitted in the area without Self-Contained Breathing Apparatus.

Methods and Materials for Containment and Cleaning Up Soak up or wet vacuum spilled liquid. Neutralize residue with sodium bicarbonate or other neutralizing ?gent for dilute acids. Decontaminate the area thoroughly. Test area with litmus paper to ensure neutralization. Place all spill residues in a suitable container. Dispose of in accordance with applicable U.S.

Federal, State, or local procedures, or appropriate local standards (see Section 13, Disposal Considerations).

VITEC 3000 GHS SOS PAGES OF11

7.1 7.2 Precautions for Safe Handling Conditions For Safe Storage

7. HANDLING and STORAGE All employees who handle this material should be trained to handle it safely. Open containers.

carefully on a stable surface. Empty containers may contain residual liquid; therefore, empty containers should be handled with care.

As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash thoroughly after handling this product. Do not eat or drink while handling this material.

A void generating mists and sprays of this product. Remove contaminated clothing immediately.

During equipment maintenance follow practices indicated in Section 6 (Accidental Release Measures) to decontaminate equipment or clean-up *small spills. Make certain that application equipment is locked and tagged-out safely if necessary. Collect all rinsates and dispose of according to applicable U.S. Federal, State, or local procedures or appropriate local stan9ards.

Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store away from incompatible materials. Material should be stored in. secondary containers, or in a diked area, as appropriate. Storage and use areas should be covered with impervious materials. Keep container tightly closed when not in use.

If appropriate, post warning signs in storage and use areas, Inspect all incoming containers before storage, to ensure containers are _properly labeled and not damaged.

Incompatibilities Strong bases, strong oxidizers, very strong acids1 water reactive materials.

8. EXPOSURE CONTROLS - PERSONAL PROTECTION 8.1 Control Parameters 8.2 8.3 CHEMICAL NAME CAS#

EXPOSURE LIMITS IN AIR ACGJH-TLV OSHA-PEL TWA STEL TWA STEL IDLH OTHER mg/m3 mg/m3 mglm3 mg/m mg/IIl mg/m3 3

3 Deflocculant & Sequestrant Proprietary NE NE NE NE NE NE Chelate agent Proprietary NE NE NE NE NE NE pH adjustment agent Proprietary NE 2mg/m3 C 2mg/m3 C NE NE NIOSHREL 2ing/m3 C NE= Not Established. C =Ceiling LimiL See Section 16 for Definitions ofTenns Used.

Appropriate Engineering Controls.

Use with adequate ventilation to ensure exposure levels are maintained below the limits provided in this Section or as low as reasonably achievable. Ensure eyewash/safety shower stations are available near areas where. this product is used.

Personal Protective Equipment None needed under normal conditions of use. Use.NIOSH approved respirators Respiratory protection: if ventilation is inadequate to control mists or vapor. If respiratory protection is needed, use only protection authorized in the U.S. Federal OSHA Standard (29 CFR 1910.134), applicable U.S. State regulatioi;is, or the applicable local standards: Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use of a full-face piece pressure/demand SCBA or a full-face piece, supplied airrespirator with auxiliary self-contained air supply is required under OSHA' s Respiratory Protection Standard ( 1910.134-1998).

Eye protection:

Use approved safety goggles or safety glasses, as described in OSHA 29 CFR 1910.133. Splash goggles with a faceshield may be needed if splash hazards exist.

Hand protection:

Wear chemical impervious gloves (e.g., Neoprene or Nitrile).

Body protection:

If needed, use body protection appropriate for task (e.g., Tyvek suit, rubber apron) to protect from splashes and sprays.

VITEC 3000 GHS SOS

PAGE 6 OF 11

Appearance' Odor

9. PHYSICAL and CHEMICAL PROPERTIES This product 1s a clear, amber liquid with a light disiilrectant odor.

Light disinfectant odor Odor Threshold Similar to water pH 100 Boiling Point Range °C ("F)

NIA.

10.7-11.8 NIA Melting Point°C (°F)

Initial Boiling Point °C ("F)

Flammability Vapor Density (air= 1)

Solubility (in water)

Viscosity Non-flalilIIlable Evaporation Rate (water= 1)

Similar to water Vapor Pressure mm Hg@ 20°C:

Similar to water 18 Decomposition Temperature How To Detect This Substance (Warning Properties):

Reactivity Chemical Stability Soluble Relative density (water= 1) 1.2-1.3 Si,milar to water Oil-Water Partition Coefficient NIA NIA

'l)le color and odor may act as warning properties associated with this product.

10. ST ABILiTY and REACTIVITY Not considered reactive.

Stable Hazardous polymerization will not occur.

A void mixing with incompatible materials.

10.1 10.2 10.3 10.4 10.5 10.6 Possibility of hazardous reactions Conditions to avoid Incompatible Materials Strong bases, strong o,xidizers, very strong acids, water reactive materials.

Hazardous Decomposition Products Thermal decomposition.of this product may generate carbon monoxide, carbon dioxide, and phosphorus oxides.

11. TOXICOLOGICAL INFORMATION 11.1.

Information on Toxicological Effects Toxicity data for hazardous ingredients Deflocculant& Sequestrant

Chelate agent pH adjustment agent VITEC 3000 GHS SOS Oral 1D50 mg/kg NIA LD5o (Oral-Rat) 2100 mgikg LD5o (Skin-Rabbit)> 6310 mg/kg LD50 (Oral-Quail)> 2510 mg/kg LD5o (dral-Duck) > 2510 mg/kg IDLo (Oral-Rat) 1302 mg/kg/31 days-intennittent:

Kidney, Urethra, Bladder: other changes in urine composition; Nutritional and Gross Metabolic: weight loss or decreased weight gain, changes in sodium.

LD50 (lntraperitoneal-Mouse) 40 mg/kg LDLo (Oral-Rabbit) 500 mg/kg Cytogenetic AnalysiS (Parenteral-Grasshopper) 20mg Cytogenetic Analysis (Hamster-Lung) I 0 mmol/L Cytogenetic Analysis (Hamster-Ovary) 16' mmol/L NIA Dermal LDso mg/kg Standard Draize Test (Skin-Rabbit) 500 mg/24 hours Standard Draize Test (Eye-Rabbit) 100 mg: Moderate Standard Draizc Test (Eye-

.Monkey) 1 %/24 hom:s:

Severe Standard Draize Test (Skin-Rabbit) 500 mg/24 hours:

Severe Standard Draize Test (Eye-Rabbit) 400 '"g: Mild Standard Draize Test. (Eye-Rabbit) 1 %: Severe Standard Draize Test (Eye~

Rabbit) 50 *g/24 hours:

Severe Standard Draize Test (Eye-Rabbit) 1 mg/24 hours:

Severe Rinsed with water,(Eye-Rabbit) 1 mg/30 seconds:

Severe PAGE70F11

~----

Inhalation LDsomg/kg NIA NIA NIA

Potential routes of exposure Inhalation, skin contact, eye contact Potential effects of acute overc Inhalation exposure may cause tingling, coughing, sneezing, and difficulty breathing.

exposure Symptoms of skin and eye contact may include redness and irritatioIL Ingestion may cause stomach pains, cramps, and gastritis.

Potential effects of chronic over-Prolonged or repeated skin overexposure to this product may cause dermatitis (dry, red exposure skin).. Symptoms may include tingling, redness, and visible injury.

Symptoms of over-exposure Immediate: Inhalation exposure may cause tingling, coughing, sneezing, and difficulty breathing. Symptoms of skin and eye contact may include redness and irritatio11:

Ingestion may cause stomach pains, cramps, and gastritis.

Delayed: Prolonged or repeated skin overexposure to this product may cause dermatitis (dry, red skin). Symptoms.may fuclude tingling, redness, and visible injury.

Conditions aggravated by over-Preexisting dermatitis, other skin conditions, and respiratory conditions may be exposure aggravated by exposures to this product.

Recommendations to physicians:

Treat symptoms and.eliminate exposure, Irritation YES This product can be irritating to contaminated tissue.

Sensitization NO Carcinogenicity NTP NO Mutagenicity NO Reproductive toxicity NO Biological Expostire Index N/ A IARC US OSHA CAL OSHA NO NO NO 67/548 EEC Annexl NO Other potential health effects Currently, there are no Biological Exposure Indices (BEis) for ariy component of this product.

12. ECOLOGICAL INFORMATION ALL WORK PRACTICES Ml,.JST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.

12.1 Ecotoxicity LCso,mg/L ECso, mg/L Vitec 3000 NSF Aquatic; LCSO (Mysidopsis bahaz) > 1000 mg!L 7 days EC50 (Daphnia magna) 48honrs==>1000 mg!L NOEC (Daphnia magna) 48 hour5.555556e-4 days <br />0.0133 hours <br />7.936508e-5 weeks <br />1.8264e-5 months <br />s== 1000 mg!L Terrestrial N/A NIA 12.2 Persistence and Degradability The components of this product decompose in soil and water.

12.3 12.4 12.5 Bioaccumu1ative Potential Mobility in Soil Other Adverse Ecological Effects The components of this product are not expected to bioaccumulate.

Moderately mobile.

This product may be harmful to aquatic life if large volumes of it are released into an aquatic environment.

13. DISPOSAL CONSIDERATIONS Preparing Wastes of this Product for Disposal Disposal of Contaminated Packaging U.S, EPA Waste Number VITEC 3000 GHS SOS Waste disposal must be in accordance with appropriate U.S. Federal, State, and local regulations or with local regulations. This product, if unaltered by the handling, may be disposed of by treatment at a permitted facility or as advii;ed by your local waste regulatory authority.

Cleaned containers can be recycled or disposed of as non-contaminated waste, if authorized by your local authorities. Dispose of containers as required by local.

regulations.

Not applicable.

PAGEBOF11

14. TRANSPORTATION INFORMATION THIS MATERIAL IS NOT HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF TRANSPORTATION.

14.1 14.2 14.3 14.4 14.5 14.6 14.7 UN Number UN Proper Shipping Name Transport Hazard Class( es)

Transport label(s) required Packing Group Marine Pollutant NA Emergency Response Guide Number (2008)

Transport in Bulk (Annex II of MARPOL 73/78 and IBC Code)

Special Transport Precautions National Motor Freight Classification Not applicable Not applicable*

Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable

70

.International Air Transport Association UN Number Not applicable UN Proper Shipping Name Not applicable Transport Hazard Class( es)

Not applicable Transport label(s) required* Not applicable Packing Group Not applicable IA TA Emergency Response Code Not applicable Excepted Quantity Not applicable Packaging Instructions Not applicable International Maritime Organization UN Number UN Proper Shipping Name Transport Hazard Class( es)

Transport label( s) required Packing Group Marine Pollutant NA Emergency Response Guide Number (2008)

Transport in Bulk (Annex II of MARPOL 73/78 and IBC Code)

Not applicable Not applicable Not applicable Not applicable Not applicable Not applicabie Not applicable Not applicable

15. SAFETY, HEALTH and ENVIRONMENTAL REGULATIONS SPECIFIC FOR THE PRODUCT Clean Air Act Hi~zardous NO NO Air Pollutants Safe Drinking Water Act NO NO RCRAF, K, P, U or No NO D-lists SARA302 RQ NO NO SARA302 TPQ NO NO SARA 313 LISTED NO NO SARA CHEMICAL CATEGORIES SARA 311/312 ACUTE YES YES VITEC 3000 GHS SDS PAGE90F11 NO NO D002 lOOOlbs NO NO NO

SARA 311/312 NO NO NO CHRONIC SARA 311/312 FIRE NO NO NO SARA311/312 NO NO NO PRESSURE SARA 311/312 NO NO NO REACTIVITY EPA EXTREMELY HAZARDOUS NO NO NO SUBSTANCE Substances

'il" :: *; - "

WHMIS NO NO E

DSL YES YES YES NDSL NIA NIA NIA REACH Pre-registered YES YES YES List TSCA YES YES YES European Inventory of Existing Commercial YES YES YES Chemical Substances (EINECS)

EU No-Longer Polymers NO NO NP List (NLP)

EEC Classification Packaging, and Labeling Skin corrosion/irritation, Category Skin corrosion/irritation, Skin corrosioofuritation, of Dangerous Substances(Annex 1)

Philippines Japan Australia Korea China New Zealand Inventory of Chemicals 16.1 16.2 163 16.4 Original Preparation Revision History Prepared by Date of Printing VITEC 3000 GHS SOS Category2 Category2 YES YES YES YES YES YES YES YES NO NO YES YES

16. OTHER INFORMATION 14 Nov 2005; update 20 February 2014 13 March 2013 Reformatted to GHS Requirements ADVANCED CHEMICAL SAFETY, Inc.

PO Box 152329 San Diego, CA 92195 (858)-874-5577 February 4, 2015 PAGE 100F 11 YES YES YES YES YES YES

DEFINITIONS OF TERMS 16.5 A large number*of abbreviations and acronyms appear on a MSDS. Some of these which are co=only nsed include the following:

Section 2 GHS: Global Harmonization System OSHA: U.S. Occupational Safety and Health Adrriinistration.

CLP: Classification and Packaging WHMJS: Workplace Hazardous Materials Information System STOT: Specific Target Organ Toxicity Section3 CAS #: Chemical Abstract Service index number EINECS #: Eurooean Chemical Substances Information Svstem index number Sections NFPA: Nation Fire Protection Association Health Ha7.ard: 0 (material that on exposure under fire conditions would offer no hazard beyond that of ordinary combusuble materials); 1 (materials that on exposure under fire conditions coald cause irritation or minor residual injury); 2 (materilils that on intense or continued exposure under fire conditions could cause 'temporary incapacitation or possible residual injury); 3 (materials that can on short exposure could cause serious temporary or residual injury); 4 (materials that under very short exposure could cause death or major residual injury). Flammability Hazard Reactivity Hazard: Refer to definitions for Hazardous Materials Identification System".

Flash Point Minimum temperature at which a liquid gives off sufficient vapors to form an ignitable mixture with air.

Autoignition Temperature: The minimum temperature required to initiate combustion in air with no other source of ignition.

LEL: The lowest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. UEL: The highest percent of vapor in air, by volume, that will explode or ignite in the oresence of an ignition source.

Section 8 ACGJH - American Conference* ofGovernrnental Indnstrial Hygienists, a professional association which establishes exposure limits.

TL Y-Threshold Limit Value - an airborne concentration of a substance which represeµts conditions under which it is generally believed that nearly all workers may be repeatedly exposed without adverse effect. The duration must be considered, including the 8-hour Time Weighted Average (TWA), the 15-minute Short Term Exposure Limit, and the instantaneous Ceiling Level (C). Skin absorption effects must also be considered PEL - Permissible Exposure Llmit - This exposure value means exactly the same as a TLV, except that it is enforceable by OSHA.

The OSHA Permissible Exposure; Limits are based in the 1989 PELs and the June, 1993 Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 40191). Both the current PELs and the vacated PELs are indicated The phrase, "Vacated 1989 PEL," is placed next to the PEL which was vacated by Court Order.

IDLH -.Immediately Dangerous to Life and Health - This 'level represents a concentration from which one can escape within 30-minntes without suffering escape-preventing or permanent injury. The DFG - MAK is the Republic of Germany's Maximum Exposure Level, similar to the U.S. PEL. NIOSH is the National Institute of Occupational Safety and Health, which is the research arm of the U.S. Occupational Bafety and Health Administration (OSHA). NIOSH issues exposure guidelines called Recommended Exposure Levels (RELs).

When no exposure guidelines are established, an entry of NE (Not Established) is made forreference.

Section 11 LD50 : Lethal Dose (solids & liquids) which kills 50% of the exposed animals; LC5'J : Lethal Concentration (gases) which kills 50% of the exposed animal~;

ppm: Concentration expressed in parts of material per million parts of air or water; niglm3 : Concentration expressed in weight of substance per volume of air; mg/kg: Quantity of material, by weight, adminisiered to a test subject, based on their body weight in kg IARC - the International Agency for Research on Cancer; NTP - the National Toxicology Program, RTECS - the Registry of Toxic Effects of Chemical Substances, OSHA and CALJOSHA.

IARC and NTP rate,chemicals on a scale of decreasing potential to cause hnman cancer with rankings from 1 to 4. Subrankings (2A, 2B, etc.) are also used.

TDLo, the lowest dose to cause a symptom and TCLo the lowest concentration to. cause a symptom; TDo, LDLo, and LDo, or TC, TCo, LCLo, and LCo, the lowest dose (or concentration) to cause lethal or toxic effects.

BEI - Biological Exposure Indices, represent the levels of determinants which are most likely to be observed in specimens collected,from a healthy worker who has been exposed to chemicals to the same extent as a worker with inhalation expmfure to thelLV.

Section 12 LC50: The lowest concentration in water which kills 50% of the test subjects.

EC50: The Effect Concentration in water at which 50% of the test species if affected.

Section 13 US EPA Hazardous Waste Codes: refer to 40 CFR 261.20 Section 14 DOT:' US Department of Transportation IA TA: International Air Transport Association IJ\\.-10: International Maritime Organization 1\\-fARPOL: International Convention for the Prevention of Pollution From Ships, 1973 as,modified by the Protocol of 1978 IBC Code : Merchant Shiooing Code Section 15 RCRA: US Resource Conservation and Recovery Act SARA: US Superfund Amendments and Reauthorization.Act PSM: US OSHA Process Safety Management CFATS: US Department ofHomeland Security Chemical Facility Anti-terrorism Standard DSL: Canadian Domestic Substances List NDSL: Canadian Non-Domestic*Substances List REACH: European Registration, Evaluation, Authorization and Restriction ofChemicals list TSCA: US Toxic Substances Control Act VITEC 3000 GHS SOS PAGE 11OF11

1. Identification Product identifier Other means of identification Recommended use Recommended restrictions SAFETY DATA SHEET SODIUM BISULFITE 40%

None.

ALL PROPER AND LEGAL PURPOSES None known.

Manufacturer/Importer/Supplier/Distributor infonnation Manufacturer Company name Address Telephone E-mail Emergency phone number

2. Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements.

Signal word Hazard statement Precautionary statement Prevention

Response

Storage Disposal Hazard(s) not otherwise classified (HNOC)

Supplemental information Brenntag Mid-South, Inc.

1405Highway136, West Henderson, KY 42420 270-830-1222 Not available.

800-424-9300 Not classified, Acute toxicity, oral Skin corrosion/irritation Cf-:IEMTREC Category 4 Category2 Serious eye damage/eye irritation Category 1 Specific target organ toxicity, single exposure Category 3 respiratory tract.irritation Not classified.

Not classified:

Danger Harmful if swallowed. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation.

Avoid breathing mist or vapor. Wash thoroughly after handling. Do riot eat, drink or smoke when using this product. Use only outc;loors or in a well-ventilated area. Wear protective gloves. Wear eye/face protection.

If swallowed: Call a poison center/doctor if yell feel unwell. If on skin: Wash with plenty of water. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.

Continue rinsing. Immediately call a poison center/doctor. Rinse mouth. lfskiri irritation occurs:

Get medical advice/attention. Take pff contaminated clothing and wash before reuse.

Store in a well-ventilated place. Keep container tightly closed. Store locked up.

Dispose of contents/container in accordance with local/regional/national/international regulations.

None known.

None.

3. Composition/information on ingredients Mixtures Material name: SODIUM BISULFITE 40%

566657 Version#: 01 Issue date: 04-11-2015 sos us 117

Chemical name DISULFUROUS ACID, SODIUM SALT (1 :2)

Common name and synonyms CAS number 7681-57-4 40 Other components below reportable levels 60

nesignates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and speciai treatment needed General information

5. Fire-fighting measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.

Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse.

Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately.

Rinse mouth. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.

Get medical advice/attention if you feel unwell.

Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye da!J1age including blindness could result. May cause respiratory irritation.

Skin irritation. May cause redness arid pain.

Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim unde*r observation. Symptoms may be delayed.

If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance.

Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (C02).

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.

media Specific hazards arising from During fire, gases hazardous to health may be formed.

the chemical Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

and precautions for firefighters Fire fighting Move containers from fire area if you can do so without risk.

equipment/instructions Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.

General fire hazards No unusual fire or explosion hazards noted.

6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Environmental precautions

7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.

Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personai protection, see section 8 of the SOS.

Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.

Avoid discharge into drains, water courses or onto the ground.

Do not get this material in contact with eyes. Avoid breathing mist or vapor: Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or smoke. Provide adequate ventilation. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices.

Store locked up. Store -in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS).

Material name: SODIUM BISUL)=ITE 40%

566657 Version#: 01 Issue dale: 04-11-2015 sos us 217

8. Exposure controls/personal protection Occupational exposure limits US. ACGIH Threshold Limit Values Components DISULFUROUS ACID, SODIUM SALT (1 :2) (GAS 7681-57-4)

Type TWA US. NIOSH: Pocket Guide to Chemical Hazards Components Type DISULFUROUS ACID, SODIUM SALT (1 :2) (CAS 7681-57-4)

TWA Value 5 mg/m3 Value 5 mg/m3.

No biological exposure limits noted for the ingredient(s).

Biological limit values Appropriate engineering controls Good general ventilation (typically 1 O air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this pr-!lduct.

Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggl.es) and a face shield.

Skin protection Hand protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier.

Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.

Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. Chemical respirator with organic vapor cartridge.

Wear appropriate thermal protective clothing, when necessary.

Thermal hazards General hygiene considerations Keep away from food and drink. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/o.r smoking. Routinely wash work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties Appearance Physical state Form Color Odor Odor threshold pH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas)

Liquid.

Not available.

302 °F (150 °C) estimated/ 999 °F (537.22 °C) 212 °F (100 "C) estimated 999.0 "F (537.2 "C)

Not available.

Not applicable.

Upper/lower flammability or explosive llmits Flammability limit - lower Not available.

(%)

Flammability limit - upper Not available.

(%)

Explosive limit - lower(%)

Not available.

Explosive limit - upper(%)

Not available.

Vapor pressure 0.00001 hPa estimated Material name: SODIUM BISULFITE 40%

566657 Version#: 01 Issue date: 04-11-2015 SDS US 317

Vapor density Relative density Solubility(ies)

Solubility (water)

Partition coefficient (n-octanol/water)

Auto-ignition temperature Decomposition temperature Viscosity Other information Density Flammability class Percent volatile Specific gravity Not available.

Not available.

11.68 lbs/gal estimated Combustible 1118 estimated 60 % estimated 1.4 estimated

10. Stability and reactivity Reactivity Chemical stability The product is stable and non-reactive under normal conditions of use, storage and transport.

Material is stable under normal conditions.

Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products Hazardous polymerization does not occur.

Contact with incompatible materials.

.Strong oxidizing agents, No haz.ardous decomposition products are known.

11. Toxicological information lnformation*on likelyroutes ofexposure Inhalation May cause irritation to the respiratory system. Prolonged.inhalation may be harmful.

Skin contact Eye contact Ingestion Causes skin irritation.

Causes serious eye damage.

Harmful if swallowed.

Symptoms related to the physical, chemical and toxicological characteristics Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. May cause respiratory irritation.

Skin irritation. May cause redness and pain.

Information on toxicological effects Acute toxicity In high concentrations, vapors are anesthetic and may cause headache, fatigue, dizziness and central nervous system effects. Harmful if swallowed. May cause respiratory irritation.

~~00~

~~

~~~

DISULFUROUS ACID, SODIUM SALT (1 :2) (CAS 7681-57-4)

Ac lite Oral LD25 Sheep 2.375 g/kg LOSO Sheep 2.515 g/kg LD75 Sheep 2.675 g/kg

Estimates for product may be based on additional component data not shown.

skin corrosion/irritation Causes skin irritation.

Serious eye damagefeye Causes serious eye damage.

irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer.

Skin sensitization This product is not expected to cause skin sensitization.

Material name: SODIUM BISULFITE 40%-

566657 Version#: 01 Issue date: 04-11-2015 sos us 417

Germ cell mutagenicity No data a'vailable to indicate product or any components present at greater than 0.1 % are mutagenic or genotoxic.

Carcinogenicity This product is not considered to be a carcinogen by !ARC, ACGIH, NTP, or OSHA.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

Reproductive toxicity This product is not expected to cause reproductive or developmental effects.

Specific target organ toxicity -

May cause respiratory irritation.

single exposure Specific target organ toxicity -

Not Classified.

repeated exposure Aspiration ha:tard Not an aspiration hazard.

Chronic effects Prolonged inhalation may be harmful.

12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility thaflarge or frequent spills can have a harmful or damaging effect on the environment.

Persistence and degradability Bioaccumulative potential Mobility in soil Other*adverse effects No data is available on the degradability of this product.

.No data available.

No data available.

No other adverse environmental' effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in ac_cordance with local/regional/nationallintemational regulations.

Dispose in accordance with all applicable regulations.

Local disposal regulations Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company.

Waste from residues I unused products Dispose of in accordance with local regulations. Empfy containers orliners may retain some product residues. This material and its container must be disposed of in a safe manner (see:

Disposal instructions).

Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.

14. Transport information DOT UN number UN proper shipping name Transport hazard class(es)

Class Subsidiary risk UN2693 BISULFITES, AQUEOUS SOLUTIONS, N.O.S. ( RQ = RQ) 80 Packing group Ill Special precautions for user Read safety instructions, SOS and emergency procedures before handling.

ERG number 154 DOT information on packaging may be different from that listed.

15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by.the OSHA Hazard Communication Standard, 29 CFR 1910.1200.

All components are on the U.S. EPA TSCA Inventory List.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

CERCLA Hazardous Substance List (40 CFR 302.4)

Not listed.

SARA 304 Emergency release notification Not regulated.

Material name: SODIUM BISULFITE 40%

566657 Version#: 01 Issue date: 04-11-2015 SDSUS 517

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

Superfund Amendments and Reauthorization Actof 1986 (SARA).

Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremeiy hazardous substance Not listed.

SARA 311/312 Hazardous chemical SARA313 (TRI reporting)

Not regulated.

Other federal regulations No Clean Air Act {CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Not regulated.

Safe Drinking Water Act (SOWA)

US state regulations Not regulated.

US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)

Not listed.

US. Massachusetts RTK - Substance List DISULFUROUS ACID, SODIUM SALT (1 :2) (CAS 7681-57-4)

US. New Jersey Worker and Community Right-to-Know Act DISULFUROUS ACID, SODIUM SALT (1 :2) (CAS768h57-4)

US. Pennsylvania Worker and Community Right-to-Know Law DISULFUROUS ACID, SODIUM SALT (1 :2) (CAS 7681-57-4)

US. Rhode Island RTK Not regulated.

US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 6S): This mat.erial is not l{nown. to contain.

any chemicals currently listed as carcinogens or reproductive toxins.

International Inventories Country(s) or region Austrafia Canada Canada China Europe Europe Japan Korea New Zealand Philippines

United States & Puerto Rico Inventory name Australian Inventory of Chemical Substances (AICS)

Domestic Substances List (DSL)

Non-Domestic Substances List (NDSL)

Inventory of Existing Chemical Substances in China (IECSC)

European Inventory of Existing Commercial Chemical Substances (EINECS)

European List.of Notified Chemical Substances (ELINCS)

Inventory of Existing and New Chemical Substances (ENCS)

Existing Chemicals List (ECL)

New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS)

Toxic Substances Control Act (TSCA) Inventory On inventory (yes/no)*

Yes Yes No Yes Yes No Yes Yes Yes Yes Yes

A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

A "No" indicates that one or more components of the product are not listed,or exempt from listing on the inventory administered by the governing country(s)_

16, Other information, including date of preparation or last revision Issue date 04-11-2015 Material name: SODIUM BISULFITE 40%

566657 Version#: 01 Issue date: 04-11-2015 SOS US 617

Version#

HMIS ratings NFPA ratings Disclaimer 01 Health: 3 Flammability: 0 Physical hazard: 0 Health: 3 Flammability: 0 Instability: O BNA carinot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used, It is the user's responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability.

for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available.

Material name: SODIUM BISULFITE 40%

566657 Version#: 01 Issue date: 04-11-2015 sos us 717

APPLICATION FOR A lVIlNOR REVISION TO A WASTEWATERFACILITYORACTIVITY PERMIT

1. Instructions

a. fn accordance '\\\\~th Rule 62~620.325, F.A.C., this form must be submitted to the appropriate Department district office or approved local program when requests for minorrevisiol1s to a permit or minor modifications to a facility are made by a pe1mittee, except for transfer of a permit to a new permittee and addition of a major user of reclaimed water to a Part III reuse system. Application for transfer of a pennit to a new perrnittee shall be made on DEP Form 62-620.910(11). Application for addition of'a major user ofreclaimed water shall be made on DEP Form 62-610.300(4)(a)l.

b. Each applicable item must be completed in full in order to avoid delay in processing of this form. Where attached sheets or other technical documentation are provided, indicate appropriate cross-references.

c. Three (3) copies of this application with supporting documentation shall be submitted with this form.

d. All infonnation is to be typed or printed in ink. Dates are to be entered in MM/DD/YR fonnat.

e. This application and attachments shaU be signed in accordance with Rule 62-6,20.305, F.A.C. Also, as applicable, this application and all attachments shall be signed and sealed by a professional engineer registered in Florida in accordance with Rule 62-620.310, F.A.C.

2. Facility Information

a. Permit Number:

FL00022os

b. Facility Identification Number:

FL0002208

c. Project/Facility Name:

Florida Power and Light St. Lucie Plant

d. ContactName:

ChristopherCostanzo

~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~

Number and Street:

6501 Ocean Drive City/State/Zip Code:

Jensen Beach, FL 34957 Telephone 772-465-3550

3. Type of Revision Ocorrcct Typographical Errors1 - Submit one copy of each pag;e of the permit showing revisions being requested.

Dchange Improvement Schedulc1 - Provide a description of the improvement, a list of the dates to be revised, and a reason for the proposed change in each date.

Ochange Expiration Date of Permit1 - Provide the current and proposed expiration dates for the permit and the reasons for the proposed change.

DChange Staffing Requirements2-Describe the proposed change and submit justification for the change in accordance with Chapter 62-699, F.A.C.

1 A processing fee is not required.

2A processing fee is required with the application in accordance with Ruic 62-4.050, F.A.C.

DEP Fonn 62*620.910(9)

Effective October 23. 2000

D Change.Monitoring and Reporting Requirements2 - Describe the proposed change and submit justification for the change in accordance with Chapter 62-601, F.A.C.

D Modify Approved Pretreatment Program1 - Describe the proposed modification and provide the information required byRule 62-625.540, F.A.C D Delete Point Source Outfan1

Identify the outfall and explain why the outfall is being eliminated.

D Modify or Expand Approved Residuals Land Application Sites2 - Attach a new or updated Agricultural Use or Dedicated Site Plan as required by Chapter 62-640, F.A.C..

I./ I Minor Modification to the Facility2 - Provide a description of the proposed modification. If applicable, attach i;my reports, plans, and specifications which have been developed to implement this modification.

D Other - Provide appropriate documentation. Describe.

4. Certifications a Applicant or Authorized Representative I certify under penalty of law that I have personally examined and am familiar with the infonnation submitted in this application and all attachments and that, based on my inquiry of persons immediately responsible for obtaining the information contained in the application, I believe that the inf01mation is true, accurate and complete.. I am aware that there are significant penalties for submitting false infmmation, including the possibili fine and imprisonment.

"b..,.}'--I_*~.,.._,'/.'-~-* ----------

(D~f'f-7 Name (please type)

Christopher Costanzo Company Name Florida Power and Light Title Sl Lucie Plant Vice President Company Address:

_s_so_1_s_o_c_ea_n_D_n_*v_e _________ _

Phone:

772-467-1100 City/State/Zip Code:

_J_en_s_en_B_e_a_ch_,_FL_3_4_s_s1 ________ _

Email (optional): christopher.costanzo@fpl.com

b. Professional Engineer Registered in Florida I certifv that the engineering features ofthis project have been (designed) (examined) by me and found to conform to engineering principles applicable to such projects. fo my professional judgemen~ this facility, when properly constructed, operated, and maintained, will comply with all applicable statutes of the State ofFlorida and rules of the Department Name (please type):

TimothyW. Powell Florida Registration Nuri1ber:

51477

~---------

Company Name:

Florida Power & Light Company Address:

700 Universe Blvd, GTNJB City/State/Zip Code: Juno Beach, FL 33408 Phone Number:

Email (optional):

Jlf signed hy the ~futhorized repr~enlative, attach a letter of authorization in accordance Rule 62-620.305, F.A C.

timothy.powell@fpl.com (Seal, 2

DEP Form 62-620. 910(9)

Elrective October 23,.2000

L-2016-125, Environmental Protection Plan Report, Minor Permit Revision Request to Use Water Treatment Chemicals, Iww Permit No. FL0002208: Difference between revisions

Latest revision as of 22:01, 9 January 2025

Contents

Text

Enclosure:

Dear Mr. Harris:

Enclosures:

Response

Navigation menu

@@ Line 16: / Line 16: @@
 =Text=
-{{#Wiki_filter:June 15, 2016 L-2016-125 10 CFR 50.4 EPP 3.2.4 U.S. Nuclear Regulatory Commission Attn: Document Control Desk Washington, DC 20555 Re:      St. Lucie Units 1 and 2 Docket Nos. 50-335 and 50-389 Environmental Protection Plan Report Minor Permit Revision Request to Use Water Treatment Chemicals IWW Permit No. FL0002208 Pursuant to Section 3.2.4 of the St. Lucie Environmental Protection Plan, Florida Power & Light Company (FPL) is hereby forwarding the enclosed copy of the permit revision request to the Industrial Wastewater Facility Permit (Permit Number FL0002208) as issued by the State of Florida Department of Environmental Protection on November 18, 2014.
+{{#Wiki_filter:June 15, 2016 U.S. Nuclear Regulatory Commission Attn: Document Control Desk Washington, DC 20555 Re:
+St. Lucie Units 1 and 2 Docket Nos. 50-335 and 50-389 Environmental Protection Plan Report L-2016-125 10 CFR 50.4 EPP 3.2.4 Minor Permit Revision Request to Use Water Treatment Chemicals IWW Permit No. FL0002208 Pursuant to Section 3.2.4 of the St. Lucie Environmental Protection Plan, Florida Power & Light Company (FPL) is hereby forwarding the enclosed copy of the permit revision request to the Industrial Wastewater Facility Permit (Permit Number FL0002208) as issued by the State of Florida Department of Environmental Protection on November 18, 2014.
 Please contact Corey Spencer at (772) 467-7436 or Chrissi-Lee Williams at (772) 467-7228 should you have any questions on this matter.
-Sincerely, lf(~s/;D Mic~:j{        Snyder Licensing Manager St. Lucie Plant MJS/tlt
+Sincerely, lf(~s/;D Mic~:j{ Snyder Licensing Manager St. Lucie Plant MJS/tlt
 ==Enclosure:==
 VPPSL053, Florida Power & Light Company - Plant St. Lucie*
 IWW Permit No. FL0002208 - Minor Permit Request to Use Water Treatment Chemicals Florida Power & Light Company 6501 S. Ocean Drive, Jensen Beach, FL 34957
-L-2016-125 Enclosure Enclosure VPPSL053 Florida Power & Light Company - Plant St. Lucie IWW Permit No. FL0002208 Minor Permit Request to Use Water Treatment Chemicals (39 pages)
+Enclosure VPPSL053 Florida Power & Light Company - Plant St. Lucie IWW Permit No. FL0002208 Minor Permit Request to Use Water Treatment Chemicals (39 pages)
+L-2016-125 Enclosure
 June 15, 2016 Mr. Marc Harris, P.E.
-Florida Department of Environmental Protection 2600 Blair Stone Road Tallahassee, Florida 32399-2400 Re:      Florida Power & Light Company
+Florida Department of Environmental Protection 2600 Blair Stone Road Tallahassee, Florida 32399-2400 Re:
-* Plant St. Lucie Wastewater Permit No. FL0002208 Minor Permit Revision Request to Use Water Treatment Chemicals
+Florida Power & Light Company
+* Plant St. Lucie Wastewater Permit No. FL0002208 Minor Permit Revision Request to Use Water Treatment Chemicals
 ==Dear Mr. Harris:==
 FPL St. Lucie Plant requests a Minor Permit Revision to Industrial Wastewater Permit No.
 FL0002208 to authorize the use of water treatment chemicals to produce deionized water at the plant's vendor operated water treatment plant. The plant wishes to transition from using_
 GE Water as a vendor to Evoqua Water Technologies. As such, the chemicals proposed for approval include the following:
-Name                        Purpose                Dosage               Frequency Vitec 3000 - Avista            RO - Antiscalant         0-3 mg/L              Continuous 0-3 mg/L              Continuous Sodium Bisulfite - Brenntag   Feed water Dechlorination 3-5 mg/L              Continuous Vitec 5100 -Avista             RO - Antiscalant It should be noted that Sodium Hydroxide will also be used in the Evoqua treatment train for pH adjustment; however, it is already on the list of approved chemicals in the site's NPDES permit.
+Name Purpose D osage Frequency Vitec 3000 - Avista RO - Antiscalant 0-3 mg/L Continuous Sodium Bisulfite - Brenntag Feed water Dechlorination 0-3 mg/L Continuous Vitec 5100 -Avista RO - Antiscalant 3-5 mg/L Continuous It should be noted that Sodium Hydroxide will also be used in the Evoqua treatment train for pH adjustment; however, it is already on the list of approved chemicals in the site's NPDES permit.
-Also, only one of the antiscalant products listed will be used at any given time. The water treatment plant Reverse Osmosis reject, which will contain small amounts of antiscalant byproducts, will be discharged into the storm drain system. The site storm drains are routed to the west storm water basin, which has a capacity of 11.2 million gallons. West basin overflow water travels into the south and southeast basins. In order to prevent backflow and site flooding due to heavy rain, batch releases are discharged from the south pond through permitted outfall 1-008. Discharges from 1-008 flow into the intake canal, which is eventually discharged through outfall D-001 into the Atlantic Ocean.
+Also, only one of the antiscalant products listed will be used at any given time. The water treatment plant Reverse Osmosis reject, which will contain small amounts of antiscalant byproducts, will be discharged into the storm drain system. The site storm drains are routed to the west storm water basin, which has a capacity of 11.2 million gallons. West basin overflow water travels into the south and southeast basins.
+In order to prevent backflow and site flooding due to heavy rain, batch releases are discharged from the south pond through permitted outfall 1-008. Discharges from 1-008 flow into the intake canal, which is eventually discharged through outfall D-001 into the Atlantic Ocean.
 Provided are the following items in pursuit of a minor permit revision:
 : 1. Process Flow Diagram of the Evoqua permanent water treatment plant
-: 2. Stream composition table for the permanent water treatment plant .
+: 2. Stream composition table for the permanent water treatment plant.
 : 3. Process Flow Diagram of the Evoqua Temporary water treatment system
 : 4. Stream composition table for the temporary water treatment system
@@ Line 46: / Line 49: @@
 Since the discharge is diluted with a very large volume of cooling water (avg 1,362 MGD), the dilution rate of reject to cooling water at the point of discharge (POD) is approximately 8,522 to
 : 1. This dilution ratio is very conservative since 1-008 only discharges right before or during wet weather and ends up mixing with large volumes of stormwater. To demonstrate compliance with the toxicity standards, the following table shows the concentrations at the POD without the benefit of additional dilution during wet weather or degradation of the products.
-Dosage         Conc.@POD (mg/L)             (mg/L)    LCSO (mg/L)     IC25 (mg/L)
+Dosage Conc.@POD (mg/L)
-Vitec 3000          3              0.0004        >1,000 Vitec 5100          5              0.00d6                          49 Na Bisulfite         3              0.0004                         1.2*
+(mg/L)
+LCSO (mg/L)
+IC25 (mg/L)
+Vitec 3000 3
+.0004
+>1,000 Vitec 5100 5
+.00d6 49 Na Bisulfite 3
+.0004 1.2*
 * Chronic Toxidty level listed iri PA DEP approved chemical additives listing.
-* Additionally, since the Department has recently implemented nutrient standards for surface waters, the following table shows calculated Total N and P increase in concentrations at the POD, again without the benefit of additional dilution or degradation. The nutrient concentration for the products was provided by the manufacturer.
+* Additionally, since the Department has recently implemented nutrient standards for surface waters, the following table shows calculated Total N and P increase in concentrations at the POD, again without the benefit of additional dilution or degradation.
-Increase in N               Increase in P at Total N (%)    at POD (mg/L)   Total P (%)    POD (mg/L)
+The nutrient concentration for the products was provided by the manufacturer.
-Vitec 3000        1.2%           0.000004        5.8%         0.000020 Vitec5100         0.2%           0.000001        2.8%         0.000016
+Increase in N Increase in P at Total N (%)
+at POD (mg/L)
+Total P (%)
+POD (mg/L)
+Vitec 3000 1.2%
+.000004 5.8%
+.000020 Vitec5100 0.2%
+.000001 2.8%
+.000016
 We feel this information adequately demonstrates that use of the new chemicals will pose no concerns with either toxicity or nutrient standards. 'If you should have any questions or require additional information regarding' this permit revision request~ please feel free to contact Mr.
 Corey Spencer at (772) 467-7436 or Ms. Chrissi-Lee Williams at (772) 467-7228 or via email at chri_ssi-lee. williams@fpl:co1_11.
 Sincerely,
-~~l                           &.,*?
+~~l &.,*?
 Chrjst_opher R. Costanzo Site Vice President St. Lucie Plant VPPSL053
 ==Enclosures:==
-Figures 1-4 (4 pages); Avista Vitec&#xa9; 5100 SDS (11 pages); Avista Vitec&#xa9; 3000 SDS (11 pages); BRENNTAGSDS (7 pages); Minor Revisi.on IWWW Permit Application (2 pages); FPL check #5000437720 payable to FDEP for $250.00 (1) cc:       FDEP- Southeast District Office FDEP "'"",Siting Coordination Office
+Figures 1-4 (4 pages); Avista Vitec&#xa9; 5100 SDS (11 pages); Avista Vitec&#xa9; 3000 SDS (11 pages); BRENNTAGSDS (7 pages); Minor Revisi.on IWWW Permit Application (2 pages); FPL check #5000437720 payable to FDEP for $250.00 (1) cc:
+FDEP-Southeast District Office FDEP "'"",Siting Coordination Office
-ROP.*ct RO-CCmtarner #1                                                   Fl,,w: B:iJ - \I~* gpm 1Q PRV        1----lol               2-p1m, or 1-p<IS$
+PRV RO-CCmtarner #1 1----lol 2-p1m, or 1-p<IS$
-                                              _ _""""" PolishLoor:
+'Mun i;:ipal Witter: 460 u S.1'cni RO Container 111 Pr~1.1~ure:75-~5 p~i!l 111 1 2-pm ot 1-pa3s ROP.*ct Fl,,w: B:iJ - \\I~* gpm 1Q 1
-'Mun i;:ipal Witter: 460 u S.1'cni                       RO Container 111                                                                                                      - - - MalnP;Q~:;s Pr~1.1~ure:75-~5 p~i!l         **...- -      111 1  2-pm          ot 1-pa3s                                                                                                ---------- lnlfmltteni
+.f-------~-----------
-                                                                            ..f-------~-----------
+MOD:: 1Tra11e) 3CDgpm ii''"'*
-                                                                                                                                                                    --P.. Baclt1\'aE.f:l E!llmm t.
+:::n::Y :*\\ *> * 'C : ***:~.f.. :*.*,"
-Flow:42Jg!)m
+Jn1; Si;n;, inc.11 8
-                                                             ,............ _..1 I
+Lire Material CS Sch 40 532 (2-p*as.s)
+Flow Hate, gprn rna.x 9,30 (1~p*ass)
+Flow Rate. fps max 6
+Temperaiure, *f 65 -85 Pressure, psig 45-90 Ccrrc:@sO "f, usrcrn 45&
+ph@50 *f 7r.
+.~
+C02 @50 *F, ppm 2-7 1
+I
+.*,,.y> 2, :**,;
+CS Sd14[*
+i4 (2-pass}
+*ra. (1-pass}
+~:3
+*65 -85 2lJ wJQ 3
+l.E:
+< G.1'
+*"''.~.;'\\'*"'.', ~"*:.} T'I**~~ T Si:i,
+'0 6
+0
+SS Sch *10.
+PVC PVC PVC 44-'*!i:-pm)
+O{t-;ia.s~)
+HL {'1-pass} 300 (1-pass}
+L4 4Dil 7.~*
+.7
+'5.5 5
+-85 fJ.'.:* -85*
+- 85.
+-85
+<5 BO 70 6.6 3
+0.06 0.06' 1;e rn 7
+<-:: 0.1
+< 0.1
+<'}J)1
+<O.Ot
+""""" PolishLoor:
+MalnP;Q~:;s
+---------- lnlfmltteni
+--P.. Baclt1\\'aE.f:l E!llmm t.
+','1:(,,.;.
+PVC
+,:;!1-44 2
+* ~85 60
+< 0;06 7
+<0:1}1 Flow:42Jg!)m
 * Ch~m r~.em in RQ C*.mtaii1er'1 "Mel? mContl1iiuer lil
-* 01tclli!e Analyze rs C1>ntaiutr #j 2-paSc(; RD        Re.coverr~ !H.5%
+* 01tclli!e Analyze rs C1>ntaiutr #j 2-paSc(; RD Re.coverr~ !H.5%
 COi Re~C*'l!'JSty= 9Q -.95%
 System Rtm;*111e1y:= 75+'%
-MOD:: 1Tra11e)                                                                                                                                                             ffaalFmluct\'l'it!lf, 3CDgpm                                                                                                                                                                 Pre1m1ra1 > ~o.1isrg F.l:J'ilr..4tiC1gpm,111a*~
+.. _~.. ::v~,a:, *.:.
-ii''"'* :::n::Y :*\ *> * 'C :         ***:~.f ..   :*.*,"  .* ,,.y> 2, :** ,;   *"''      .~.;'\'*"'.', ~"*:.} T'I**~~ T ,,,,-Si:i,         ,'        ' ','1:(,,.;.     ,. _~. ::v~,a:, *.:. i*J;i:.:.9/*;;,, : . ;; *:1,ll;fa!.,;~*
+SS Sch 10 4CO (2-pass) 7 co ~1-pass) 7
-Jn1; Si;n;, inc.11                       8                          6                   '0                    6             6                  0            3                    6                 6                6 Lire Material                      CS Sch 40                 CS Sd14[*         SS Sch *10.                 PVC            PVC                 PVC         PVC            SS Sch 10               P'lC              PVC 88 (2-pass>
+: 65. - 85 60
-(2-p*as.s) 4i4 (2-pass} 44-'*!i:-pm) O{t-;ia.s~)                                                                                 4CO (2-pass)                          1.90 (1-pas.s1 Flow Hate, gprn rna.x             9,30 (1~p*ass) *ra. (1-pass} HL {'1-pass} 300 (1-pass}                                   4L4                4Dil       ,:;!1-44      7co ~1-pass)               400         !:flO(i.WBW}
+< 0.06 7
-Flow Rate. fps max                        6                         ~:3               7.~*                    3.7          '5.5                 5             2                  7                  5               63 Temperaiure, *f                      65 -85                     *65 -85          65-85                  fJ.'.:* -85*     65 - 85.            65-85      55* ~85               65. - 85        65* -85             55 - E5 Pressure, psig                      45-90                        2lJ wJQ               <5                     BO            70                 6.6           60                  60               <5               > 60 Ccrrc:@sO "f, usrcrn                   45&                           3                    3                    3          0.06                0.06'     < 0;06                < 0.06          < 0*.'D5'            1930 ph@50 *f                               '
+<0.01 ffaalFmluct\\'l'it!lf, Pre1m1ra1 > ~o.1isrg F.l:J'ilr..4tiC1gpm,111a*~
-r.
+i*J;i:.:.9/*;;,, :.. ;; *:1,ll;fa!.,;~*
-                                               .~                       l.E:               1;e                     rn             7                  7             7                  7                  7                 8 C02 @50 *F, ppm                        2-7                        < G.1'           <-::   0.1             < 0.1           <'}J)1             <O.Ot        <0:1}1               <0.01            <0.01               2.5 Figure1 Permanent Evoqud System Process Flow Diagram*
+6
+P'lC PVC 88 (2-pass>
+.90 (1-pas.s1 400
+!:flO(i.WBW}
+63 65* -85 55 - E5
+<5
+> 60
+< 0*.'D5' 1930 7
+<0.01 2.5 Figure1 Permanent Evoqud System Process Flow Diagram*
-                                        ,::~c
+*2
-:      *2       .3        *.it . ., . . *:* . *s: . . *.:   ... n    : 7. :...
+.3
-::*::** ..*. .,,B.:>>:***
+*.it...,
-:y,...*: *.![.;. r*:B.::!***:* *:: . ~o::.
+.... *:*.. *s:... *.:
-f.eed l..paH                                                                            Filla! D.I               DI Protrui:t Muni            mend to                        GAC     Fsedfo         Feed to            UV"CDI       C[ll                                                            RO Parameter                                                    RO                                                                       Prodlict to                     Re~irc to Fe~d           pt pass                     Emuent     l\.1001        UV..(:01          Pro.um: t  ReJec.t                                                      ReJe*::t RQd Pemm11e                                                                              FIJ'.&L               P.olish Loop Ca as ppm CaC01                453'              .L3             1012      0:0~:2   'J.012           C.0~2:           < .LJ~OOG    0.'.12     <It2 ppb                     <. 0.2 ppb            285 Mg as ppm caco3                25.S              24              \lOD7     0.007    !J.OJ7          '0.G0:7           < *D_;D06    C*.07      <{1,2 ppb                    <0:.2 ppb              155 Na a.s FPm CaCOJ                108              10               *O~E.9    0.39       0.89            0.:39           <<0*.01       8:9     <oC*.05 ppb <D.O!:* pp!J                              677 Kas.ppmQl003                   JJ              3.G             J0:3B     O:C'35   *J.0.35          C*.C'35*          < 0.01      C\35           < O.Ol                        <*0.01          23;5 S~ 3S   ppm:CaCD,;            0.37             0.34                 *D       0          0                 0           < 0*.0:1   <OJ             < IJ.0:1                      <0.:M              23 H:03 a~ ppm C;;CCI=                1~.9'           1RO                O;:;Q    0.JO       0.50*           0.50            < O.ot        5:           < 0.0:1:                      < 0.01            12:i
+: 7. :...
-:S04:is p~mCaC03                 45.6:            4l6              *:toD7    0,;007    *J.OJi'         O.GOT            < ~tuOG    < G.C'7      <D.2. ppb                     <0.2 pph              WD Cl 3'.;ppmCaCD;                114              107              -0.1:8-   0.28       0.2B            0.28            *C0.01      2'.fl     < \t2ppb                      < 0.2 ppb             703 NG~ as         ppm caco:i        2.19             2.*15              0.14     0.14       0.~4           D.1:4           < '0.0l       l4            <0.Ul                        < 0.0*1              14 Fas ppm CaC03                '15'.J            1.4               O.f:2    0;;)2     *0.02            J.rD2          < 0:*01      0.15       ;: *J.2.*ppb                 -< 0.2 ppb              '35 C02 3S ppm CaCO;                    0.1           0.9               O.CQ     0.1D2      0.02            0.02           .( *0.01     0.19           < O.OJ                        < o.oi             :).~
+...,,B.:>>:***
-SrG2 es i::;pm*CaC05             5.14              4.8             0~014     O*.:C'14 1 J.*0*14         G.01,4            < 0'.01      o*.1         < O:DC'l                     <'J.002               32:
+*.![.;. r*:B.::!***:* *::.. ~o::.
-TCIC; {mg-C/I}                 5           *US               D.Cti     0.02       0.02.           D:D2             O.Oi       0.04          <      O.*D15.               : : iJJ)i5            30  1 TUrbid ity NTU          < O.~*            < C*.1             '=OJ.    *< 0:.11   <; 0.1         *<0.1              <Oj.      <DJ                < C1.1                      <! 0.1'        <*D.5 TSS (mgl!}                  0 i:,        -0.4.!i         -.( 0;11~  ~  0. 10 < 0.110          <0.10             <-0.05    -< O.C!S-        < 0.05                        < 0.05'           *<'!
+... n
-pH                  *8..5           7.6              7.81      7.8:1. T.81            731.             7.02.      7.8ii              7.02                        7.(12.           ;3,'1 Conductivity, u5/cm                  456*            430                2.t      1:!i       2.1             2*.*~           0.06       19:11            0.7156                       0.056          25~7
+. :.,.,::~c
-.Notes:
+:y,
-"Gompos.ition rah.le reflects 4()(1 gpm DJ producl v,ra1erpumped furward iri .l*pa:ss mode wirh tlgpm DI produci: water recircufa1i011
+* f.eed l..paH Filla! D.I DI Protrui:t Muni mend to GAC Fsedfo Feed to UV"CDI C[ll RO Parameter Fe~d pt pass RO Emuent l\\.1001 UV..(:01 Pro.um: t ReJec.t Prodlict to Re~irc to ReJe*::t RQd Pemm11e FIJ'.&L P.olish Loop Ca as ppm CaC01 453'
-*M All .2" pass RO rnjeci .is wr;ycled ~o* *1<< pass feectw~rer.aari allo\'e c11mpr:witioo retieets rn~ b.renlllit composJ1im1 1<lirll 1M inr:oming mr.mi wimr 0
+.L3 1012 0:0~:2
-Figure 2 Permanent Evoqua System Stream Composition Table.
+'J.012 C.0~2:
+<.LJ~OOG 0.'.12
+< It2 ppb
+<. 0.2 ppb 285 Mg as ppm caco3 25.S 24
+\\lOD7 0.007
+!J.OJ7
+'0.G0:7
+< *D_;D06 C*.07
+< {1,2 ppb
+< 0:.2 ppb 155 Na a.s FPm CaCOJ 108 10
+*O~E.9 0.39 0.89 0.:39
+<<0*.01 8:9
+<oC*.05 ppb < D.O!:* pp!J 677 Kas.ppmQl003 JJ 3.G J0:3B O:C'35
+*J.0.35 C*.C'35*
+< 0.01 C\\35
+< O.Ol
+<*0.01 23;5 S~ 3S ppm:CaCD,;
+.37 0.34
+*D 0
+0
+< 0*.0:1
+<OJ
+< IJ.0:1
+<0.:M 23 H :03 a~ ppm C;;CCI=
+~.9' 1RO O;:;Q 0.JO 0.50*
+.50
+< O.ot 5:
+< 0.0:1:
+< 0.01 12:i
+:S04:is p~mCaC03 45.6:
+l6
+*:toD7 0,;007
+*J.OJi' O.GOT
+< ~tuOG
+< G.C'7
+< D.2. ppb
+< 0.2 pph WD Cl 3'.;ppmCaCD; 114 107
+-0.1:8-0.28 0.2B 0.28
+*C0.01 2'.fl
+< \\t2ppb
+< 0.2 ppb 703 NG~ as ppm caco:i 2.19 2.*15 0.14 0.14 0.~4 D.1:4
+< '0.0l l4
+<0.Ul
+< 0.0*1 14 Fas ppm CaC03
+'15'.J 1.4 O.f:2 0;;)2
+*0.02 J.rD2
+< 0:*01 0.15
+;: *J.2.*ppb
+-< 0.2 ppb
+'35 C02 3S ppm CaCO; 0.1 0.9 O.CQ 0.1D2 0.02 0.02
+.( *0.01 0.19
+< O.OJ
+< o.oi
+:).~
+SrG2 es i::;pm*CaC05 5.14 4.8 0~014 O*.:C'14 1J.*0*14 G.01,4
+< 0'.01 o*.1
+< O:DC'l
+< 'J.002 32:
+TCIC; {mg-C/I}
+*US D.Cti 0.02 0.02.
+D:D2 O.Oi 0.04
+< O.*D15.
+:::: iJJ)i5 301 TUrbid ity NTU
+< O.~*
+< C*.1
+'=OJ.
+*< 0:.11
+<; 0.1
+*<0.1
+<Oj.
+<DJ
+< C1.1
+<! 0.1'
+<*D.5 TSS (mgl!}
+i:,
+-0.4.!i
+-.( 0;11~
+~ 0.. 10
+< 0.110
+< 0.10
+<-0.05
+-< O.C!S-
+< 0.05
+< 0.05' pH
+*8.. 5 7.6 7.81 7.8:1.
+T.81 731.
+.02.
+.8ii 7.02 7.(12.
+;3,'1 Conductivity, u5/cm 456*
+2.t 1:!i 2.1 2*.*~
+.06 19:11 0.7156 0.056 25~7
+.Notes:
+"Gompos.ition rah.le reflects 4()(1 gpm DJ producl v,ra1erpumped furward iri.l*pa:ss mode wirh tlgpm DI produci: water recircufa1i011
+*M All.2"0 pass RO rnjeci.is wr;ycled ~o* *1<< pass feectw~rer.aari allo\\'e c11mpr:witioo retieets rn~ b.renlllit composJ1im1 1<lirll 1M inr:oming mr.mi wimr Figure 2 Permanent Evoqua System Stream Composition Table.
-                                                                           *MU~l'F!!edwater*
+**Bisulfile*
-                                                                                     !i:'l:t*wm
+-,.o~';j Antiscalant -'-- 1.
-                     **Bisulfile*                                                                                              9
+.I I
-                                         -,.o~';j Antiscalant -'-- 1                .       .:
+*Ro c-0ntainor* #t.
-                                     .I             I twc{.:l;I                     TW<>j2).                   a"
+.21.d '.";iir!~11#~;i:
-                                                                                                                                           ~1011rr.rsn.r
+:-~- -~;--~ flO CG1itl!ln~*112;
-:Paralkll    i---...._,~-'.Dl P.rorluat .Wate. r
+. ~ici 9i>;it.. t.f:J<-'17a.:-P-i>>
-                       *Ro c-0ntainor* #t .                              .:SU:   i.;1 ..                                                     2f1ii apl!l                              1'ara11!J!
+~ "
-:40*0 gpm
+~
-                        .21.d '.";iir!~11#~;i:                           Par11illil
+*N-aOH 1+
-* 3.                                                                                       :J.iem.                    .. c~i.
+*:*::":,\\'::*'
-RO
+UneSize, inch
-   ":-~- -~;--~ flO CG1itl!ln~*112; 2     Adlvatoo P/litM>n                  ~
+!,:ine Material
+_Flo\\'1Rate, gpfr! max:
+fl~\\'{ Rate, fps max Tenip~rature, ~F Pres.sure, psig Cond@50 *f, uS/cm pH@50~F CO;; @50 *f, ppin
+*MU~l'F!!edwater*
+!i:'l:t*wm 9
+~1011rr.rsn.r
+.:SU: i.;1..
+f1ii apl!l twc{.:l;I 1'ara11!J!
+:J.iem.
+TW<>j2).
+:Paralkll a"
+i---...._,~-'.Dl P.rorluat.Wate.. r Par11illil *
+: 3.
+Adlvatoo P/litM>n l'ilrtal>le Ali.~*1~~~
+RO
+~
 Braal<
+T11!1~*
-                                                                                                                                          *i1001 :rrat191
-                                                                                                                                            .*llia. gpni l'<lrla1>1" l'ilrtal>le               T11!1~*
+*i1001 :rrat191
-    *                 . ~ici 9i>;it..t.f:J<-'17a.:-P-i>>                Ali.~*1~~~
+.*llia. gpni l'<lrla1>1"
-    ~
+.. c~i.
-  "~
+:40*0 gpm
-*N-aOH
+'1 D*
-                                                            .___ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ __.__ _ _ _ _ _-"--~-----
+.~91'~Jecny.rt,":
-                                                                                                                                                                                                           '1 D*                        .~91'~Jecny.rt,":
+-"--~-----
 ::111'gpiTI, fyp*
-                                                                                                                                                                                                                                 *311 gi)m; a\aic intermittent 1+
+*311 gi)m; a\\aic intermittent 1
-         *:*::":,\'::*'                  .*...              1       ..       .;*
+.. **.*~**.
-                                                                                  ..  **.*~**.
+*
-*   .*_..*.   .:r* 4   ':*:
+.:r* 4 ':*:
-                                                                                                                                                   !"'    :*.5\.'::.:
+: *. 5\\.'::.:
-                                                                                                                                                                      ,"?
+,"?
-:*:: ;6: .........      .:r._;; :   **:*   : F*  H:*::B"::  ::;!="*
+:*:: ;6:
-                                                                                                                                                                                                                                        -~*"*
+. :r._;; : **:* : F*
-:::*::''.'*'It:;:**::; Y. ,..
+H:*::B"::
-::rn    '****
+::;!="*
-UneSize, inch                                     6                           6                     s                   5                         .6                  6'                   s*                          6                            ti                      ::s
+:::*::''.'*'It:;:**::; Y.,..
-          !,:ine Material                                 PVC.                       PVC                   PVC                 PV9                        pyC                PVC..                 PVC'                        PVC                         PVC                      PVC 111 (ty_n)'
+-~*"*
-_Flo\'1Rate, gpfr!             max:              511                         40D                   400.               400                       -400                  400-                400                          400                         400                 3.11 {max) fl~\'{ Rate,        fps max                      6.3                          5                  2.l:l                  5                          5                  5                    5.,                         5                            s                       3.8 Tenip~rature, ~F                               '65 - 8'5                55.~      85             65-135            6p--B5                     65*. 85            55.*85                 55 ~as.*                    65-l:l!;;                :65- 65                    *65-85 Pres.sure, psig                               46-'"EiO                 2_0-JD.                    <.5                  9'0                        70                  BB'                *oo                          60                          *<"5                    '.>> &#xa3;<1)*
+6
-Cond@50 *f, uS/cm                               ;\56                          3                    3                   3                       '!J:DS              t\06                <O.Oo                       *<0.05.'                . <(*'0.00:                   "1930 pH@50~F                                          7.2                        7.8;                  .7,8'              7.8                           7                  T                    T                           7                            *7                        8 CO;; @50 *f, ppin                                2.7                   *<0.1                     <0:*1.             :.:o.t                     <0.01             '<O.QY                 .<&#xa2;.0;~1                    *<D,Q*1                     <0,01                       2.5 0
+s 5
-Figure 3 Temporary Evoqud System Process Flow Diagram
+.6 6'
+s*
+ti PVC.
+PVC PVC PV9 pyC PVC..
+PVC' PVC PVC 511 40D 400.
+-400 400-400 400 400 6.3 5
+.l:l 5
+5
+.,
+s
+'65 - 8'5 55.~ 85 65-135 6p--B5 65*.. 85 55.*85 55 ~as.*
+-l:l!;;
+:65-65 46-'"EiO 2_0-JD.
+<.5 9'0 70 BB'
+*oo 60
+*<"5
+;\\56 3
+3
+'!J:DS t\\06
+<O.Oo
+*<0.05.'
+. <(*'0.00:
+.2 7.8;
+.7,8' 7.8 7
+T T
+*7 2.7
+*<0.1
+<0:*1.
+:.:o.t
+<0.01
+'<O.QY
+.<&#xa2;.0;~1
+*<D,Q*1
+<0,01 Figure 3 Temporary Evoqud System Process Flow Diagram
+::rn
+::s PVC 111 (ty_n)'
+.11 {max) 3.8
+*65-85
+'.>> &#xa3;<1)*
+"1930 8
+.5 0
 Stream Ct>ll1PDSltion Table*
-                                                          .... .,.,,, .. *, ,.. *.    ::* 2,. ::',:':                *'.*:*,.
+,>'>*. !L':
-* 4      *.,
+::* 2,. ::',:':
-                 .... **"**                      . !L':                                                                                            !> :                              .*7            ""+      8
+.* *3 *.
-                                          ,>'>*                                                                                                           ,:     :.6 .,.*::'"'::                                       *, "" .9 ..:.. .;,: ..      '.lO
+*'.*:*,..
-;''  .... :;,,;,            ~:.,                                , ......,                                  .* *3 *.                    ""  ;t                                                "'..:;
+* 4
-c:. "'/*
+;t
-Feedwater
+:.6.,.*::'"'::
-                                                                                                      "'"                                                                                               Final DI DI Pmduct Muni                               :2-pass RO                                MODL               :MQDJ                            Post.MB Parameter                                      Blend ta f<l                                 GAC Effluent.                                          Post-UV                                  f'roductto       Recirc te> RO          RO Reject Feedwaler                              P@nneat:e                           Feedwate.r            Product                             Polish Pass Rou                                                                                                                                       Storage       Permeate Tank Ca as ppm C:aCO,                           46.:r       4:3.1                    ll.1J12             0:.1)12            {l.011           <0.006         <O.om;              <{).OIJ!i              <0.006              <-O.liilti           2'16 Mg as ppm          eaco,                  25.{i        2.J,7                    0.0{)7              :O.. -OlJ7         1l.006           <1J'.00f:i*    <0.0{16             <0.006                 <0.0*06            <-0.01Hi              1.18 NaasppmCaCO,                               1oa        105.2                      1.661               1.ti51            1.495             *< Oc01        <1):.0:1            < ll.01                *< 0.01             ~0 ..0*1            521 K as ppm C.'i!CO,.                         3.S         3.6                     l'l.035             lUJ36              -0.-032            <0.0'1        <OJJ1               *"-0.01                 <0.01             <0.01                  1S Sr :as ppm caco,                          0~372         0.3                         0                     0                 0            < D.O'l        <0.01               < 0.01                  <0.01             <0Jl1                 1.T HC03 as ppm taco,                            11l.'9*     20Ai                      1.21l4              1.294:             1.Hl5             <0.01         <0.01               <0.1)1                 *<0.01             *:<.0.01             'l\10 SQ4 ai; ppm C:aC.O;                          46Al:       43.'S                    0.007               *0.007             >D.. 006         <0.006         <0 .. 00i'i          <O.U05                <0.006              <1J.006             :2*19 Cl ;is ppm cseo,                            114        HR7                        {),27               {l,27             0.24             <0.01          <0.01               <0.01                  < il.01            <D.1l1              535 N03 as ppm           c~co,                  2.19        2. Hi                      0.13                0.13*            {).117            <0.01          <0.01               <'IJ.0*1               <0.{)1             <{IAJ1                10 Fas ppm eaco,                             1.53         1.4                     0:014               0.0*14             0.013             <.{).01        <{l,()*1             <1J.0*1               <1L01              <'.{l.{)1                T C02     >-S p pm Cl!CO,                     UiB          3.ll                    0.049                0.049             {);042            <-0.0*1        <1l;01              <0.01                  <{);01             <0.0'1                3.S SlOZ as ,ppm CaCO,                           5.H          4.B                      {).012              0.{1'12           1J.1l1 '1          <0.01         <DJH                .... 0.01               <{J.{)'1           <1J.{)1            23.. E TOC, (mg-C/1)                             5          4.9                       .0.01                0.112            0.02               0.:02         D.-01                 lJ.01                 0.01               1l.IH               22 T'urbidity NTU                          <i:lJ.5      -<0.5                        0                     0                 0                0              {)                    0                    {)                 0               <{J.5 TSS[mg/I)                                                                 "-0.lll              <{l.01           *<QJ)1              < D.IJ1       <O.lJ*1              "-0.01                 <ll.01             <-O.ll1            <ll.1 pH                             7. Hi*      7.03                        7.S                  7.S             7 .. 7'9           1.04          7.M                    7.04                 7.M                7.1l4               J.T Comiu<livity, uS/cm                          456          436                          *~                   4.                3              O.Dti         ll.05*             .<l.Dlifio              o._055             Q.05'6             1950 Notes~
+.*7
-* Comp0&ilfon fable relfects 400 gpm D1 product water pumped forward ;ml 44 gpm .DI product wa.ter recirculated back to RO permeate tank
+""+
- *~   All 2"" pass RO reject ii; re eye.fed to 1" passieedwa te.r <1 nd above compG.Sition re:trects tfle bJe.nded compDSition with *lhe ina*oming muni wa.fer Figure 4 Temporary Evoqua System Str.eam Composition Table
+*, "".9.. :...;,:..
+'.lO
+~:., c:. "'/*
+Muni Feedwater
+:2-pass RO MODL
+:MQDJ Post.MB Final DI DI Pmduct Parameter Feedwaler Blend ta f<l P@nneat:e GAC Effluent.
+Feedwate.r Product Post-UV Polish f'roductto Recirc te> RO RO Reject Pass Rou Storage Permeate Tank Ca as ppm C:aCO, 46.:r 4:3.1 ll.1J12 0:.1)12
+{l.011
+<0.006
+<O.om;
+<{).OIJ!i
+<0.006
+<-O.liilti 2'16 Mg as ppm eaco, 25.{i 2.J,7 0.0{)7
+:O.. -OlJ7 1l.006
+<1J'.00f:i*
+<0.0{16
+<0.006
+<0.0*06
+<-0.01Hi 1.18 NaasppmCaCO, 1oa 105.2 1.661 1.ti51 1.495
+*< Oc01
+<1):.0:1
+< ll.01
+*< 0.01
+~0.. 0*1 521 K as ppm C.'i!CO,.
+.S 3.6 l'l.035 lUJ36
+-0.-032
+<0.0'1
+<OJJ1
+*"-0.01
+<0.01
+<0.01 1S Sr :as ppm caco, 0~372 0.3 0
+0
+< D.O'l
+<0.01
+< 0.01
+<0.01
+<0Jl1 1.T HC03 as ppm taco, 11l.'9*
+Ai 1.21l4 1.294:
+.Hl5
+<0.01
+<0.01
+<0.1)1
+*<0.01
+*:<.0.01
+'l\\10 SQ4 ai; ppm C:aC.O; 46Al:
+.'S 0.007
+*0.007
+>D.. 006
+<0.006
+<0.. 00i'i
+<O.U05
+<0.006
+<1J.006
+:2*19 Cl ;is ppm cseo, 114 HR7
+{),27
+{l,27 0.24
+<0.01
+<0.01
+<0.01
+< il.01
+<D.1l1 535 N03 as ppm c~co, 2.19
+: 2. Hi 0.13 0.13*
+{).117
+<0.01
+<0.01
+<'IJ.0*1
+<0.{)1
+<{IAJ1 10 Fas ppm eaco, 1.53 1.4 0:014 0.0*14 0.013
+<.{).01
+<{l,()*1
+<1J.0*1
+<1L01
+<'.{l.{)1 T
+C02 >-S p pm Cl!CO, UiB 3.ll 0.049 0.049
+{);042
+<-0.0*1
+<1l;01
+<0.01
+<{);01
+<0.0'1 3.S SlOZ as,ppm CaCO, 5.H 4.B
+{).012 0.{1'12 1J.1l1 '1
+<0.01
+<DJH
+.... 0.01
+<{J.{)'1
+<1J.{)1 23.. E TOC, (mg-C/1) 5 4.9
+.0.01 0.112 0.02 0.:02 D.-01 lJ.01 0.01 1l.IH 22 T'urbidity NTU
+<i:lJ.5
+-<0.5 0
+0
+{)
+{)
+<{J.5 TSS[mg/I)
+"-0.lll
+<{l.01
+*<QJ)1
+< D.IJ1
+<O.lJ*1
+"-0.01
+<ll.01
+<-O.ll1
+<ll.1 pH
+: 7. Hi*
+.03 7.S 7.S 7.. 7'9 1.04 7.M 7.04 7.M 7.1l4 J.T Comiu<livity, uS/cm 456 436
+*~
+: 4.
+O.Dti ll.05*
+.<l.Dlifio o._055 Q.05'6 1950 Notes~
+* Comp0&ilfon fable relfects 400 gpm D1 product water pumped forward ;ml 44 gpm.DI product wa.ter recirculated back to RO permeate tank
+*~ All 2"" pass RO reject ii; re eye.fed to 1" passieedwa te.r <1 nd above compG.Sition re:trects tfle bJe.nded compDSition with *lhe ina*oming muni wa.fer Figure 4 Temporary Evoqua System Str.eam Composition Table
-Avista TECH NO LOG I ES vitec&#xa9; s100 SAFETY DATA SHEET
+Avista vitec&#xa9; s100 TECH NO LOG I ES SAFETY DATA SHEET
-: t. Company and Product Identification 1.1       Identification - Product Name:                                 Vitec&#xa9; 5100 Other means of identification                                  Organo-phosphorous compounds
+: t. Company and Product Identification 1.1 Identification - Product Name:
+Vitec&#xa9; 5100 1.2 1.3 1.4 1.5 Other means of identification Synonym:
-===1.2 Synonym===
+Recommended Use Of The Chemical and Restrictions On Use:
-                                                     .Mixture, none Recommended Use Of The Chemical                                Reverse osmosis membrane antiscalant 1.3 and Restrictions On Use:                                       Use only as directed on tbe label.
+Name, Address, And Telephone Number Of The Manufacturer, Or Other Responsible Party:
-Name, Address, And Telephone Number Of                         AVISTA TECHNOLOGIES The Manufacturer, Or Other Responsible Party:                  140 Bosstick Street 1.4                                                                      San Marcos, CA 92069 (760) 744-0536 Competent Person email address                                 klindsey@avistatech.com 24 Hour Emergency No.:                                         1-800-424-9300 (United States) 1.5 1-202-483-7616 (International Collect)
+Competent Person email address 24 Hour Emergency No.:
+Organo-phosphorous compounds
+.Mixture, none Reverse osmosis membrane antiscalant Use only as directed on tbe label.
+A VISTA TECHNOLOGIES 140 Bosstick Street San Marcos, CA 92069 (760) 744-0536 klindsey@avistatech.com 1-800-424-9300 (United States) 1-202-483-7616 (International Collect)
 L*~
-(NSE)    DRINKING WATER TREATMENT ADDITIVES CLASSIFIED BY NSF
+( NSE) DRINKING WATER TREATMENT ADDITIVES CLASSIFIED BY NSF
- 'C7 INTERNATIONAL TO ANSI/NSF 60 AS STANDARD DRINKING WATER G&sect;D TREATMENT CHEMICAL FOR USE IN REVERSE OSMOSIS SYSTEMS AT A
+'C7 INTERNATIONAL TO ANSI/NSF 60 AS STANDARD DRINKING WATER G&sect;D TREATMENT CHEMICAL FOR USE IN REVERSE OSMOSIS SYSTEMS AT A MAXIMUM LEVEL OF 13 mg/I.
-  .  . MAXIMUM LEVEL OF 13 mg/I.
 : 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: This product is amber to light yellow water-based solution with a light disinfectant odor. This product may irritate contaminated tissue. This product is neither reactive nor flammable.
-Physical Hazards Summary     None Potential Health Hazards Summary     Skin corrosionfrrritation, Category 3 H315 Causes skin irritation H319 Causes serious eye irritation Potential Ecological Effects Summary    None 2.1        Classification Of Product Skin, eye irritant U.S. OSHA classification Skin corrosion/irritation, Category 3 Oassification as per EC 1272/2008     H315 Causes skin irritation       *
+Physical Hazards Summary None Potential Health Hazards Summary Skin corrosionfrrritation, Category 3 H315 Causes skin irritation H319 Causes serious eye irritation Potential Ecological Effects Summary None 2.1 Classification Of Product Skin, eye irritant U.S. OSHA classification Skin corrosion/irritation, Category 3 Oassification as per EC 1272/2008 H315 Causes skin irritation (CLP/GHS)
-(CLP/GHS)   H319 Causes serious eye irritation WHMIS classification   D2B - Poisonous and .infectious material - Other effects - Toxic VITEC 5100 PUBLIC GHS SOS                                                                      PAGE1 OF11
+H319 Causes serious eye irritation WHMIS classification D2B - Poisonous and.infectious material - Other effects - Toxic VITEC 5100 PUBLIC GHS SOS PAGE1 OF11
-Hazardous Materials Information System (HMIS) Rating 2.2         Label Elements OSHA/GHS General Warnings     PlOl           If medical advfoe is needed, have product container or label at hand.
+Hazardous Materials Information System (HMIS) Rating 2.2 Label Elements OSHA/GHS General Warnings Signal Word.
-P102           Keep out of reach of children.
+Hazard statements Precautionary statements Hazard pictograrns PlOl P102 Pl03 WARNING!
-Pl03           Read label before use Signal Word . WARNING!
+H315 H319 H335 P27l P281 P312 P302/P352 P261 P305 + P351
-Hazard statements    H315           Causes skin irritation H319           Causes serious eye irritation H335           May cause respiratory irritation Precautionary statements   P27l           Use only outdoors or in a well-ventilated area.
++P338 2.3 Unclassified Hazards None 2.4 Ingredients with uilknovm acute None toxicity If medical advfoe is needed, have product container or label at hand.
-P281           use personal protective equipment as required.
+Keep out of reach of children.
-P312           IF SWALLOWEP: Call a POISON CENTER or doctor/physician if P302/P352      you feel unwell.
+Read label before use Causes skin irritation Causes serious eye irritation May cause respiratory irritation Use only outdoors or in a well-ventilated area.
-P261           Avoid breathing.dust/ fume/ gas/ mist/ vapours/spray.
+use personal protective equipment as required.
-P305 + P351    P305 + P351 + P338 :IF IN EYES: Rinse cautiously with water for
+IF SW ALLOWEP: Call a POISON CENTER or doctor/physician if you feel unwell.
-                                                 +P338          several minutes. Remove contact lenses, if present and easy to .do.
+Avoid breathing.dust/ fume/ gas/ mist/ vapours/spray.
+P305 + P351 + P338 :IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to.do.
 Continue. rinsing.
-Hazard pictograrns 2.3                       Unclassified Hazards   None 2.4            Ingredients with uilknovm acute   None toxicity
+: 3. COMPOSITION and INFORMATION ON INGREDIENTS Chemical name
-: 3. COMPOSITION and INFORMATION                              ON INGREDIENTS Chemical name                             %w/w         US OSHA                  GHS/EUCLP                    WHMIS CAS#
+%w/w US OSHA GHS/EUCLP WHMIS CAS#
 EINECS#
-Deflocculant & Sequestrant                10-20        Corrosive                Skin corrosion/irritation,   E, corrosive Proprietary                                                                     Category 3 Proprietary                                                                     H319 Causes serious eye irritation P305 + P351 + P338 IF IN EYES: Rinse .
+Deflocculant & Sequestrant 10-20 Corrosive Skin corrosion/irritation, E, corrosive Proprietary Category 3 Proprietary H319 Causes serious eye irritation P305 + P351 + P338 IF IN EYES: Rinse.
 cautiously with water for several minutes; Remove contact lenses, if present and easy to do. Continue rinsing.
-Keep out of reaeh of VITEC&#xa9; 5100 PUBLIC GHS SOS                                                                         PAGE20F11
+Keep out of reaeh of VITEC&#xa9; 5100 PUBLIC GHS SOS PAGE20F11
 children.
@@ Line 184: / Line 524: @@
 Avoid contact with eyes.
 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
-Wear.suitable protective clothing. If swallowed, seek medical advice immediately and show this container or label Phosphonic acid derivative                      5-15                  Corrosive              Skin corrosion/irritation,    E, corrosive Proprietary                                                                                  Category3 Proprietary                                                                                  H319 Causes serious eye irritation P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
+Wear.suitable protective clothing. If swallowed, seek medical advice immediately and show this container or label Phosphonic acid derivative 5-15 Corrosive Skin corrosion/irritation, E, corrosive Proprietary Category3 Proprietary H319 Causes serious eye irritation P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
 Keep out of reach of children.
 Keep away from food, dririk and animal feeding stuffs.
 A void contact with skill.
 A void contact with eyes.
-In case of contact with eyes, rinse immediately                           i with plenty of water and seek medical advice.
+In case of contact with eyes, rinse immediately i
+with plenty of water and seek medical advice.
 Wear suitable protective clothing. If swallowed, seek medical advice immediately and show this container or label Because of pH adjustment, product is not corrosive, but is a skin/eye irritant NE= Not Established. C =Ceiling Limit. See Section 16 for Definitions of Terms Used.
-VITEC 5100 PUBLIC GHS SOS                                                                                      PAGE30F11
+VITEC 5100 PUBLIC GHS SOS PAGE30F11
-: 4. FIRST-AID MEASURES 4.1         Description of Necessary Measures Skin exposure:    If this product contaminates the skin, immediately begin decontamination with running water. Remove exposed or contaminated clothing, taking care not to contamin;ite eyes. Victim should seek immediate medical attention if any adverse exposure symptoms develop.
+: 4. FIRST-AID MEASURES 4.1 Description of Necessary Measures 4.2 4.3 Skin exposure: If this product contaminates the skin, immediately begin decontamination with running water. Remove exposed or contaminated clothing, taking care not to contamin;ite eyes. Victim should seek immediate medical attention if any adverse exposure symptoms develop.
-Eye exposure:     If this product enters the eyes, open victim's eyes while under gently running water. Use sufficientforce to open eyelids, Have victim "roll" eyes. Minimilm flushing is for 15 minutes. Victim must seek medical attention.
+Eye exposure: If this product enters the eyes, open victim's eyes while under gently running water. Use sufficientforce to open eyelids, Have victim "roll" eyes. Minimilm flushing is for 15 minutes. Victim must seek medical attention.
-Inhalation:   If vapors, mists, or sprays of this product are inhaled, remove victim to fresh air~
+Inhalation: If vapors, mists, or sprays of this product are inhaled, remove victim to fresh air~
 If necessary, use artificial respiration to support vital functions. Remove or cover gross contamination to avoid exposure to rescuers.
-Ingestion:   If this product is swallowed~ CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION. DO NOT INDUCE VOMITING. Have victim rinse mouth with water, if conscious. Never induce vomiting or-give a diluent(e.g., water) to someone who is un&#xa2;onscious, having convulsions, or unable to swallow. If contaminated individual is convulsing, mainta'in an open airway and obtain immediate medical attention.
+Ingestion: If this product is swallowed~ CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION. DO NOT INDUCE VOMITING. Have victim rinse mouth with water, if conscious. Never induce vomiting or-give a diluent(e.g., water) to someone who is un&#xa2;onscious, having convulsions, or unable to swallow. If contaminated individual is convulsing, Most Important Symptoms/Effects:
-.2         Most Important Symptoms/Effects:               Immediate: Inhalation exposure may cause coughing or sneezing. Symptoms of skin and eye contact may include redness and irritation. Ingestion may cause stomach pains, cramps, and gru.tritis.
+Indication Oflmmediate Medical Attentlon And Special T;reatment Needed, If Necessary:
+mainta'in an open airway and obtain immediate medical attention.
+Immediate: Inhalation exposure may cause coughing or sneezing. Symptoms of skin and eye contact may include redness and irritation. Ingestion may cause stomach pains, cramps, and gru.tritis.
 Delayed: Prolonged or repeated skin overexposure to this product may cause dermatitis (dry, red skin). Symptom~ may include tingling, redness, and visible injury.
-.3        Indication Oflmmediate Medical                  TARGET ORGANS: Acute: Skin, eyes.                  Chronic: Skin.
+TARGET ORGANS: Acute: Skin, eyes.
-Attentlon And Special T;reatment Needed, If Necessary:
+Chronic: Skin.
-Victims of chemical exposure must be taken for medical .attention if any adverse effects occur; .Rescuers should be taken for medical attention if necessary. Take a copy of label and MSDS to physician or health professional with victim.
+Victims of chemical exposure must be taken for medical.attention if any adverse effects occur;.Rescuers should be taken for medical attention if necessary. Take a copy of label and MSDS to physician or health professional with victim.
-: 5. FIRE-FIGHTING MEASURES Flammable properties      Non-flammable aqueous solution                       NFPA FLAMMABILITY OTHER.
+: 5. FIRE-FIGHTING MEASURES Flammable properties Non-flammable aqueous solution Flash Point &deg;C (&deg;F): Not applicable.
-See Section 16 for definitions of ratings Flash Point &deg;C (&deg;F): Not applicable.
+NFPA FLAMMABILITY OTHER.
-Autoignition Temperature &deg;C (&deg;F):      Not applicable.
+See Section 16 for definitions of ratings Autoignition Temperature &deg;C (&deg;F):
-Flainmable Limits (in air by volume, % ):
+Not applicable.
+VITEC&#xa9; 5100 PUBLIC GHS SOS Flainmable Limits (in air by volume, % ):
 Upper: Not applicable; Lower: Not applicable.
-VITEC&#xa9; 5100 PUBLIC GHS SOS                                                                               PAGE40F11
+PAGE40F11
-.1   Suitable And Unsuitable Extinguishing           This material will not contribute to the intensity of a fire. Use. extinguishing
+.1 5.2 5.3 6.1 6.2 7.1 7.2 Suitable And Unsuitable Extinguishing This material will not contribute to the intensity of a fire. Use. extinguishing
 :t>.1edia:
-* material suitable to the surrounding fire.
+material suitable to the surrounding fire.
-Water spray           YES                 Carbon dioxide     YES Foam                  YES                Dry chemical       YES Halon                 YES                Other              YES 5.2   Specific Hazards Arising From Chemical:         When involved in a fire, this material may decompose and produce irritating fumes and toxic gases (e.g., carbon monoxide, carbon dioxide, and phosphorous oxides).
+Water spray YES Foam YES Halon YES Carbon dioxide Dry chemical Other YES YES YES Specific Hazards Arising From Chemical:
+When involved in a fire, this material may decompose and produce irritating fumes and toxic gases (e.g., carbon monoxide, carbon dioxide, and phosphorous oxides).
 Explosion Sensitivity to Mechanical Impact: Not sensitive.
 Explosion Sensitivity to Static Discharge: Not sensitive.
-.3   Special Protective Equipment And                Incipient fire responders should wear eye protection. Structural firefighters must Precautions For Fire-Fighters:                  wear Self-Contained Breathing Apparatus and full protective equipment Move containers from fire area if it can be done without risk to personnel. If possible, prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive areas.
+Special Protective Equipment And Precautions For Fire-Fighters:
-: 6. ACCIDENTAL RELEASE MEASURES 6.1   Personal Precautions                           Uncontrolled releases should be responded to by trained personnel using pre-planned procedures. Proper protective equipment should be used. In case of a spill, clear the affected area and protect people.
+Incipient fire responders should wear eye protection. Structural firefighters must wear Self-Contained Breathing Apparatus and full protective equipment Move containers from fire area if it can be done without risk to personnel. If possible, prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive areas.
-Protective equipment     For small releases(< 5 gallons), clean up spilled liquid wearing gloves, goggies, faceshield, and suitable body protection. The minimum Personal Protective.
+Personal Precautions
+: 6. ACCIDENTAL RELEASE MEASURES Uncontrolled releases should be responded to by trained personnel using pre-planned procedures. Proper protective equipment should be used. In case of a spill, clear the affected area and protect people.
+Protective equipment For small releases(< 5 gallons), clean up spilled liquid wearing gloves, goggies, faceshield, and suitable body protection. The minimum Personal Protective.
 Equipment recommended for response to non-incidental releases (more than 5 gallons) should be Level B: triple-gloves (neoprene gloves and nitrile gloves over latex gloves), chemical resistant suit and boots, hard hat, and Self-Contained Breathing.Apparatus.
-Emergency procedures       Monitoring must indicate that exposure levels are below those provided in Section 3 (Composition and Information on Ingredients) and that oxygen levels are above 19.5% before anyone is permitted in the area without Self-Contained Breathing Apparatus.
+Emergency procedures Monitoring must indicate that exposure levels are below those provided in Section 3 (Composition and Information on Ingredients) and that oxygen levels are above 19.5% before anyone is permitted in the area without Self-Contained Breathing Apparatus.
-.2   Methods and Materials for Containment and       Soak up or wet vacuum spilled liquid. Neutralize residue with sodium OeaningUp                                       bicarbonate or other neutralizing agent for dilute acids. Decontaminate the area thoroughly. Test area with litmus paper to ensure neutralization. Place all spill residues in a suitable container. Dispose of in accordance with applicable U.S.
+Methods and Materials for Containment and OeaningUp Soak up or wet vacuum spilled liquid. Neutralize residue with sodium bicarbonate or other neutralizing agent for dilute acids. Decontaminate the area thoroughly. Test area with litmus paper to ensure neutralization. Place all spill residues in a suitable container. Dispose of in accordance with applicable U.S.
 Federai, State, or local procedures, or appropriate local standards (see Section 13, Disposal Considerations).
-: 7. HANDLING and STORAGE 7.1   Precautions for Safe Handling       All employees who handle this material should be trained to handle it safely. Open containers carefully ori a stable surface. Empty containers may contain residual liquid; therefore, empty containers should be handled with care.
+Precautions for Safe Handling Conditions For Safe Storage
+: 7. HANDLING and STORAGE All employees who handle this material should be trained to handle it safely. Open containers carefully ori a stable surface. Empty containers may contain residual liquid; therefore, empty containers should be handled with care.
 As with all che1nicals, avoid getting this product ON YOU or IN YOl!. Wash thoroughly after handling this product Do not eat or drink while handling this material. A void generating mists and sprays of this product Remove contaminated clothing immediately.
 During equipment maintenance follow practices indicated in Section 6 (Accidental Release Measures) to decontaminate equipment or clean-up small spills. Make certain that application equipment is locked and tagged-out safely if necessary. Collect all rinsates and dispose of according to applicable U.S. Federal, State, or local procedures or appropriate local standards.
-.2   Conditions For Safe Storage        Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store away from incompatible materials. Material should be stored in secondary containers, or in a diked area, as appropriate. Storage and use areas should be covered with impervious materials .. Keep container tightly closed when not in use.
+Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store away from incompatible materials. Material should be stored in secondary containers, or in a diked area, as appropriate. Storage and use areas should be covered with impervious materials.. Keep container tightly closed when not in use.
 If appropriate, post warning signs in storage and use areas. Inspect all incoming containers before storage, to ensure containers are properly labeled and riot damaged.
-Incompatibilities  Strong bases, strong oxidizers, very strong acids, water reactive materials.
+Incompatibilities Strong bases, strong oxidizers, very strong acids, water reactive materials.
-VITEC&#xa9; 5100 PUBLIC GHS SOS                                                                           PAGE 5OF11
+VITEC&#xa9; 5100 PUBLIC GHS SOS PAGE 5OF11
-: 8. EXPOSURE CONTROLS - PERSONAL PROTECnON 8.1      Control Parameters EXPOSURE LIMITS JN AIR CHEMICAL NAME                      CAS#              %w/w                  ACGill-1LV                        OSHA"PEL                   NIOSH                OTHER TWA           STEL             TWA             STEL               IDLH mg/m3        mg/m3 .           mg!m 3 mg/m  3 mg/m3                mg/m3 Deflocculant &
+: 8. EXPOSURE CONTROLS - PERSONAL PROTECnON 8.1 Control Parameters EXPOSURE LIMITS JN AIR CHEMICAL NAME CAS#
-Sequestrant                       Proprietary          10-20              NE              NE             NE             NE                 ~                 NE Phosphonic acid derivative        Proprietary          5-15               NE              NE             NE             NE                 :NE               NE IWater and other components which are present in                         None of the other components contnbute significant additional hazards at the concentration present in less than I percentccincentration (0.1 %                                this product All pertinent hazard information has been provided in this document, per the requirements concentration for potential carcinogens,                 Balance        of the Federal. Occupatignal Safety and Health Administration Standard (29 CPR 1910.1200), U.S.S&#xb5;te reproductive toxins, respiratory tract sensitizers                      equivalentStandards and Canadian Wor!..-place Hazardous Materials Identification System Standards and mutagens).                                                          (CPR4).
+%w/w ACGill-1LV OSHA"PEL NIOSH OTHER TWA STEL TWA STEL IDLH mg/m3 mg/m3.
-,.2     Appropriate Engineering Controls.                                 Use with adequate ventilation to ensure exposure levels are maintained below the limits provided in this Section or as low as reasonably achievable, Ensure eyewash/safety shower stations are available near areas where this product is used.
+mg!m3 mg/m3 mg/m3 mg/m3 Deflocculant &
-.3      Personal Protective Equipment                                      None needed under normal conditions of use. Use NIOSH approved respirators Respiratory protection:          if ventilation is inadequate to control mists or vapor. If respiratory protection is needed, use only protection authorized in the U.S. Federal OSHA Standard (29 CFR 1910.134), applicable U.S. State regulations, or the applicable local standards. Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use of a full-face piece pressure/demand SCBA or a full-face piece, supplied air respirator with auxiliary self-contained air supply is required under OSHA's Respiratory Protection Standard (1910.134-1998).
+Proprietary 10-20 NE NE NE NE
-Eye protection:        Use approved safety goggles or safety glasses, as described in OSHA 29 CFR 1910.133. Splash goggles with a faceshield may be needed if splash hazards exist.
+~
-Hand protectio11:        Wear chemical impervious gloves (e.g., Neoprene or Nitrile).
+NE Sequestrant Phosphonic acid derivative Proprietary 5-15 NE NE NE NE
-Body protection:         If needed, use body protection appropriate for task (e.g., Tyvek suit, rubber apron) to protect from splashes and sprays.
+:NE NE IW ater and other components which are present in None of the other components contnbute significant additional hazards at the concentration present in less than I percentccincentration (0.1 %
-: 9. PHYSICAL and CHEMICAL PROPERTIES Appearance                                       This I>roductis a clear, amber liquid with a light disillfectant odor.
+this product All pertinent hazard information has been provided in this document, per the requirements concentration for potential carcinogens, Balance of the Federal. Occupatignal Safety and Health Administration Standard (29 CPR 1910.1200), U.S.S&#xb5;te reproductive toxins, respiratory tract sensitizers equivalentStandards and Canadian Wor!..-place Hazardous Materials Identification System Standards and mutagens).
-   ,Odor                                            Light disinfectant odo~           Odor Threshold                                 N/A Melting Point &deg;C                                 Similar to water                  pH (2% solutiori)                              5.0 - 6.5 Initial Boiling Point &deg;C                         100                               Boiling Point Range 0 c                        NIA Flammability                                     Non-flammable                     Evaporation.Rate (water= 1)                    Similar to water Vapor Density (air = 1)                          Similar to water                  Vapor Pressure mm Hg @ 20&deg;C:                   18 Solubility (in water)                            Soluble                           Relative density (water = 1)                   1.10 +/- 0.05 Viscosity                                        Sltrrilar to WiJ.ter              Oil~Water Partition Coefficient                NIA Decomposition Temperature                        NIA How To Detect This Substance                     The color and odor may act as warning properties associated with this product (Warning Properties):
+(CPR4).
-VITEC&#xa9; 5100 PUBLIC GHS SOS                                                                                                        PAGE 6 OF 11
+,.2 Appropriate Engineering Controls.
-: 10. STABILITY and REACTIVITY 10.1   Reactivity                                      Not considered reactive.
+Use with adequate ventilation to ensure exposure levels are maintained below the limits provided in this Section or as low as reasonably achievable, Ensure eyewash/safety shower stations are available near areas where this product is used.
-.2   Chemical Stability                              Stable 10.3   Possibility of hazardous reactions              Hazardous polymerization will not occur.
+.3 Personal Protective Equipment None needed under normal conditions of use. Use NIOSH approved respirators Appearance
-.4   Conditions to avoid                             Avoid mixing with incompatl"ble materials.
+,Odor Melting Point &deg;C Initial Boiling Point &deg;C Flammability Vapor Density (air = 1)
-.5   Incompatible Materials                          Strong bases, strong oxidizers, very strong acids, water reactive materials.
+Solubility (in water)
-.6   Hazardous Decomposition Products                Thermal decomposition of this product may generate carbon monoxide, carbon dioxide, and phosphorus oxides.
+Viscosity Respiratory protection: if ventilation is inadequate to control mists or vapor. If respiratory protection is needed, use only protection authorized in the U.S. Federal OSHA Standard (29 CFR 1910.134), applicable U.S. State regulations, or the applicable local standards. Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use of a full-face piece pressure/demand SCBA or a full-face piece, supplied air respirator with auxiliary self-contained air supply is required under OSHA's Respiratory Protection Standard (1910.134-1998).
-: 11. TOXICOLOGICAL INFORMATION 11.1   Information on Toxicological Effects Toxi,city data for                                                                                       Dennal                           Inhalation Orall.D50 mg/kg hazardous ingredients                                                                                    LD50mg/kg                        LD,omg/kg Deflocculant & Sequestrant                     lD50  (Oral-Rat) 2100 mg/kg                              Standard Draize Test (Skin-LD,0 (Skin-Rabbit)> 6310 mg/kg                           Rabbit) 500 mg/24 hours LD50 (Oral-Quail)> 2510 mg/kg                            Standard Draize Test (Eye:.
+Eye protection:
-LD,0 (Oral-Duck) > 2510 mg/kg                            Rabbit) 100 mg: Moderate TDLo (Oral-Rat) 1302 mg/kg/31 days-NIA intermittent: Kidney, Urethra, Bladder: other changes in urine composition; Nutritional and Gi:oss Metabolic: weight loss or decreased weight gain, changes in sodium.
+Use approved safety goggles or safety glasses, as described in OSHA 29 CFR 1910.133. Splash goggles with a faceshield may be needed if splash hazards exist.
-Phosphanic acid derivative                      NIA                                                      NIA                              NIA Potential routes of exposure                    Inhalation, skin contact, eye contact Potential effects of acute over-exposure        Inhalation exposure may cause tingling, coughing, sneezing, and difficulty breathing. Symptoms of skin and eye contact may include redness and initati~n. fugestion may cause stomach pains, cramps, and gastritis.
+Hand protectio11:
-Potential effects of chronic over-exposure      Prolonged or repeated skin overexposure to this product may cause dermatitis (dry, red skin). Symptoms may inciude tingling, redness, and visible injury.
+Wear chemical impervious gloves (e.g., Neoprene or Nitrile).
-Symptoms of over-ex1msure                       Immediate: Inhalation exposure may cause tingling, coughing, sneezing, and difficulty breathing. Symptoms of skin and eye contact may include redness and irritation. lngestion may cause stomach pains, cramps, ,and gastritis.
+Body protection: If needed, use body protection appropriate for task (e.g., Tyvek suit, rubber apron) to protect from splashes and sprays.
+: 9. PHYSICAL and CHEMICAL PROPERTIES This I>roductis a clear, amber liquid with a light disillfectant odor.
+Light disinfectant odo~
+Odor Threshold N/ A Similar to water pH (2% solutiori) 5.0 - 6.5 100 Non-flammable Similar to water Soluble Sltrrilar to WiJ.ter Boiling Point Range 0c Evaporation.Rate (water= 1)
+Vapor Pressure mm Hg @ 20&deg;C:
+Relative density (water = 1)
+Oil~Water Partition Coefficient NIA Similar to water 18 1.10 +/- 0.05 NIA Decomposition Temperature NIA How To Detect This Substance The color and odor may act as warning properties associated with this product (Warning Properties):
+VITEC&#xa9; 5100 PUBLIC GHS SOS PAGE 6 OF 11
+.1 10.2 10.3 10.4 10.5 10.6 11.1
+: 10. ST ABILITY and REACTIVITY Reactivity Chemical Stability Possibility of hazardous reactions Conditions to avoid Incompatible Materials Hazardous Decomposition Products Not considered reactive.
+Stable Hazardous polymerization will not occur.
+Avoid mixing with incompatl"ble materials.
+Strong bases, strong oxidizers, very strong acids, water reactive materials.
+Thermal decomposition of this product may generate carbon monoxide, carbon dioxide, and phosphorus oxides.
+: 11. TOXICOLOGICAL INFORMATION Information on Toxicological Effects Toxi,city data for Denn al Inhalation hazardous ingredients Orall.D50 mg/kg LD50mg/kg LD,omg/kg Deflocculant & Sequestrant lD50 (Oral-Rat) 2100 mg/kg Standard Draize Test (Skin-LD,0 (Skin-Rabbit)> 6310 mg/kg Rabbit) 500 mg/24 hours LD50 (Oral-Quail)> 2510 mg/kg Standard Draize Test (Eye:.
+LD,0 (Oral-Duck) > 2510 mg/kg Rabbit) 100 mg: Moderate TDLo (Oral-Rat) 1302 mg/kg/31 days-NIA intermittent: Kidney, Urethra, Bladder: other changes in urine composition; Nutritional and Gi:oss Metabolic: weight loss or decreased weight gain, changes in sodium.
+Phosphanic acid derivative NIA NIA NIA Potential routes of exposure Inhalation, skin contact, eye contact Potential effects of acute over-exposure Inhalation exposure may cause tingling, coughing, sneezing, and difficulty breathing. Symptoms of skin and eye contact may include redness and initati~n. fugestion may cause stomach pains, cramps, and gastritis.
+Potential effects of chronic over-exposure Prolonged or repeated skin overexposure to this product may cause dermatitis (dry, red skin). Symptoms may inciude tingling, redness, and visible injury.
+Symptoms of over-ex1msure Immediate: Inhalation exposure may cause tingling, coughing, sneezing, and difficulty breathing. Symptoms of skin and eye contact may include redness and irritation. lngestion may cause stomach pains, cramps,,and gastritis.
 Delayed: PIDlonged or repeaioo skin overeJqiosure to this product may cause dermatitis (dry, red skin).
 Symptoms may include tingling, redness, and visible injury.
-Conditions a!(gr.ivated by over-expos'ure       Preexisting dermatitis, other sl.in conditions, and respiratory conditions may be aggravated by exposures to this product Recommendations to physicians:                  Treat symptoms and eliminate exposure.
+Conditions a!(gr.ivated by over-expos'ure Preexisting dermatitis, other sl.in conditions, and respiratory conditions may be aggravated by exposures to this product Recommendations to physicians:
-Irritation                                      YES This product can be iiritating to contaminated tissue.
+Treat symptoms and eliminate exposure.
-Sensiti7.ation                                  NO Carcinogenicity                                 NTP                 !ARC                   US OSHA                       CAL OSHA                67/548EEC Annex I NO                  NO                     NO                            NO                      NO Mutagen}ci!)'                                   NO Reproductive toxicity                           NO Biological Exposure Index                       NIA Olher potential health effects                  Currently, there are no Biological Exposure Indices (BEis) for any component of this product.
+Irritation YES This product can be iiritating to contaminated tissue.
-VITEC&#xa9; 5100 PUBLIC GH$ SOS                                                                                                PAGE70F11
+Sensiti7.ation NO Carcinogenicity NTP
+!ARC US OSHA CAL OSHA 67/548EEC Annex I NO NO NO NO NO Mutagen}ci!)'
+NO Reproductive toxicity NO Biological Exposure Index NIA Olher potential health effects Currently, there are no Biological Exposure Indices (BEis) for any component of this product.
+VITEC&#xa9; 5100 PUBLIC GH$ SOS PAGE70F11
 : 12. ECOLOGICAL INFORMATION ALL WORK PRACTICES MUST BE AIMED AT ELIM/NA TING ENVIRONMENTAL CONTAMINATION:
-.1     Ecotoxicity                                              NOE~,   ppm                       IC25 , ppm (Inhibition Concentration)
+.1 122 12.3 12.4 12.5 Ecotoxicity NOE~, ppm IC25, ppm (Inhibition Concentration)
-Vitec&#xa9;5100 Aquatic   Ceriodaphnia dubia 25                         49.0 Pimephales promelas >1000                     >1000 Terrestrial  NIA                                          NIA 122      Persistence and Degradability             The components of this product decompose in soil and water.
+Vitec&#xa9;5100 Aquatic Ceriodaphnia dubia 25 49.0 Pimephales promelas > 1000
-.3     Bioaccumulative Potential                 The components of this product are not expected to bioaccmrn1late.
+>1000 Terrestrial NIA NIA Persistence and Degradability The components of this product decompose in soil and water.
-.4     Mobility in.Soil                          Moderately mobile.
+Bioaccumulative Potential The components of this product are not expected to bioaccmrn1late.
-.5     Other Adverse Ecological Effects          This product may be harmful to aquatic life if large volumes of i~ are rel~!ISed jnto an aquatic environment.
+Mobility in.Soil Moderately mobile.
-: 13. DISPOSAL CONSIDERATIONS Preparing Wastes of this Product for      Waste disposal must be in accordance with appropriate U.S. Federal, State, and local Disposal                                  regulations or with local regulations. This product, if unaltered by the handling, may be disposed of .by treatment at a pennitted facility or as advised by your local wastt regulatory authority, Disposal of Contaminated Packaging        Cleaned containers can be recycled or disposed of as non-contaminated waste, if authorized by your local authorities. Dispose of containers as required by local re~lations.
+Other Adverse Ecological Effects This product may be harmful to aquatic life if large volumes of i~ are rel~!ISed jnto an aquatic environment.
-U.S. EPA Waste Number                     Not applicabie.
+: 13. DISPOSAL CONSIDERATIONS Preparing Wastes of this Product for Disposal Disposal of Contaminated Packaging U.S. EPA Waste Number Waste disposal must be in accordance with appropriate U.S. Federal, State, and local regulations or with local regulations. This product, if unaltered by the handling, may be disposed of.by treatment at a pennitted facility or as advised by your local wastt regulatory authority, Cleaned containers can be recycled or disposed of as non-contaminated waste, if authorized by your local authorities. Dispose of containers as required by local re~lations.
-: 14. TRANSPORT INFORMATION THIS MATERIAL IS NOT HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF TRANSPORTAT/ON.
+Not applicabie.
-.1     UN Number                                Not applicable 142      UN Proper Shipping Name                  Not applicable 14.3     Transport Hazard Class(es)               Not applicable Transport label(s) required   Not applicable 14.4     Packing Group                            Not applicable 14.5     Marine Pollutant                         Not applicable NA Emergency Response Guide         Notapplicable Number (2008) 14.6     Transport in Bulk (Annex II of           Not applicable MARPOL 73n8 and IBC Code) 14.7     Special Transport Precautions            Not applicable National Motor Freight     #70 Classification International Air Transport Association UN Number Not applicable UN Proper Shipping Name Not applicable Transport Hazard Class(es)     Not applicable Transport label(s) required   Not applicable Packing Group     Not applicable IATA Emergency Response Code          Not applicable Excepted Quantity     Not applicable VITEC 5100 PUBLIC GHS SOS                                                                            PAGE 8OF11
+: 14. TRANSPORT INFORMATION THIS MATERIAL IS NOT HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF TRANSPORT AT/ON.
+.1 142 14.3 14.4 14.5 14.6 14.7 UN Number UN Proper Shipping Name Transport Hazard Class( es)
+Transport label(s) required Packing Group Marine Pollutant NA Emergency Response Guide Number (2008)
+Transport in Bulk (Annex II of MARPOL 73n8 and IBC Code)
+Special Transport Precautions National Motor Freight Classification Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Notapplicable Not applicable Not applicable
+#70 International Air Transport Association UN Number Not applicable UN Proper Shipping Name Not applicable Transport Hazard Class( es)
+Not applicable Transport label(s) required Not applicable Packing Group Not applicable IATA Emergency Response Code Not applicable Excepted Quantity Not applicable VITEC 5100 PUBLIC GHS SOS PAGE 8OF11
-P..ackaging Instructions Not applicable International Maritime Organization UN Number                              Not applicable UN Proper Shipping Name                Not applicable Transport Hazard Class(es)             Not applicable Transport label(s) required  Not applicable Packing Group                          Not applicable Marine Pollutant                       Not applicable NA Emergency Response Guide       Not applicable Number (2008)
+P..ackaging Instructions Not applicable International Maritime Organization UN Number UN Proper Shipping Name Transport Hazard Class( es)
-Transport in Bulk (Annex Il of         Not applicable MARPOL 73/78 and IBC Code)
+Transport label(s) required Packing Group Marine Pollutant NA Emergency Response Guide Number (2008)
-: 15. SAFETY, HEALTH and ENVIRONMENTAL REGULATIONS SPECIFIC FOR THE PRODUCT Clean Air Act Hazardous Air                                NO              NO Pollutants Safe Drinking Water NO               NO Act EPA Priority Pollutant                       NO              NO RCRA F, K, P, U or NO               NO D-lists SARA302            RQ                        NO              NO SARA302            TP                        NO              NO SARA 313 LISTED                              NO               NO SARA CHEMICAL CATEGORIES SARA 311/312 ACUTE                          YES              YES SARA 311/312 NO               NO CHRONIC SARA 311/312 FIRE                            NO               NO SARA 311/312 NO               NO PRESSURE SARA311/312 NO              NO REACTIVITY EPA EXTREMELY HAZARDOUS                                    NO               NO SUBSTANCE E,D2B             E,D2B YES              YES VITEC&#xa9; 5100 PUBLIC GHS SOS                                               PAGE90F11
+Transport in Bulk (Annex Il of MARPOL 73/78 and IBC Code)
+Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable
+: 15. SAFETY, HEAL TH and ENVIRONMENTAL REGULATIONS SPECIFIC FOR THE PRODUCT Clean Air Act Hazardous Air NO NO Pollutants Safe Drinking Water NO NO Act EPA Priority Pollutant NO NO RCRA F, K, P, U or NO NO D-lists SARA302 RQ NO NO SARA302 TP NO NO SARA 313 LISTED NO NO SARA CHEMICAL CATEGORIES SARA 311/312 ACUTE YES YES SARA 311/312 NO NO CHRONIC SARA 311/312 FIRE NO NO SARA 311/312 NO NO PRESSURE SARA311/312 NO NO REACTIVITY EPA EXTREMELY HAZARDOUS NO NO SUBSTANCE E,D2B E,D2B YES YES VITEC&#xa9; 5100 PUBLIC GHS SOS PAGE90F11
-NDSL                                           NIA                                       NIA REACH Prt<-registered YES                                       YES List TSCA                                           YES                                       YES European Inventory of Existing Commercial YES                                       YES Chemical Substances (EINECS)
+NDSL NIA NIA REACH Prt<-registered YES YES List TSCA YES YES European Inventory of Existing Commercial YES YES Chemical Substances (EINECS)
-EU No-Longer NO                                        NO Polymers List (NLP)
+EU No-Longer NO NO Polymers List (NLP)
-EEC Classification Packaging, and Labeling      Skin corrosion/irritation, Category 3        Skin corrosion/irritation, Category of Dangerous                                                              3 Substances(Annex 1)
+EEC Classification Packaging, and Labeling Skin corrosion/irritation, Category 3 Skin corrosion/irritation, Category of Dangerous Substances(Annex 1)
-Philippines                                    YES                                       YES Japan                                          YES                                       YES Australia                                      YES                                       YES Korea                                          YES                                       YES China                                          YES                                       YES New Zealand InventQry YES                                       YES of Chemicals
+Philippines Japan Australia Korea China New Zealand InventQry of Chemicals 16.1 16.2 16.3 16.4 Original Preparation Revision History Prepared by Date of Printing VITEC&#xa9; 5100 PUBLIC GHS SOS 3
-: 16. OTHER INFORMATION 16.1       Original Preparation                         Updated April 06, 2009, Revised 04c01-11, 16 Apr 2012 16.2        Revision History                              11 June.2013 Reformatted to GHS Requirements 16.3       Prepared by                                   ADVANCED CHEMICAL SAFE'IY, Inc.
+YES YES YES YES YES YES YES YES YES YES YES YES
-PO Box 152329 San Diego, CA 92195 (858)-874-5577 16.4       Date of Printing                              April 28, 2015 VITEC&#xa9; 5100 PUBLIC GHS SOS                                                                              PAGE 100F 11
+: 16. OTHER INFORMATION Updated April 06, 2009, Revised 04c01-11, 16 Apr 2012 11 June.2013 Reformatted to GHS Requirements ADVANCED CHEMICAL SAFE'IY, Inc.
+PO Box 152329 San Diego, CA 92195 (858)-874-5577 April 28, 2015 PAGE 100F 11
-DEFINITIONS OF TERMS 16.5    A large number of abbreviations and acronyms appear on a MSDS. Some of these which are commonly used include lhe following:
+DEFINITIONS OF TERMS 16.5 A large number of abbreviations and acronyms appear on a MSDS. Some of these which are commonly used include lhe following:
-Section2                        GHS: Global Harmonization System OSHA: U.S. Occupational Safety and Health Administration.
+Section2 GHS: Global Harmonization System OSHA: U.S. Occupational Safety and Health Administration.
-CLP: Classification and Packaging WHMIS: Worlq>lace Hazardous Materials Information System STOT: Soecific Tamet Or""n Toxicitv Section3                         CAS #: Chemical Abstract Service index number EINECS #: Eurooean Chemical Substances lnfonilation Svstem index number Sections                        1\"'FPA: Nation Fire Protection Association Health Hazard: 0 (material that on exposure under fire conditions would offer no hazard beyond that of ordinary *combustible materials); 1 (materials that on exposure under fire conditions could cause irritation or minor residual injury); 2 (materials.that on intense or continued exposure under fire conditions could cause temporary .incapacitation or possible residual injury); 3 (materials that can on short exposure could cause serious temporary or residual injury); 4 (materials that under very short exposure could cause death ormajor residual injury). Flammability Hazard Reactivity Hazard: Refer to definitions for "Hazardous Materials Identification System".
+CLP: Classification and Packaging WHMIS: Worlq>lace Hazardous Materials Information System STOT: Soecific Tamet Or""n Toxicitv Section3 CAS #: Chemical Abstract Service index number EINECS #: Eurooean Chemical Substances lnfonilation Svstem index number Sections 1\\"'FPA: Nation Fire Protection Association Health Hazard: 0 (material that on exposure under fire conditions would offer no hazard beyond that of ordinary *combustible materials); 1 (materials that on exposure under fire conditions could cause irritation or minor residual injury); 2 (materials.that on intense or continued exposure under fire conditions could cause temporary.incapacitation or possible residual injury); 3 (materials that can on short exposure could cause serious temporary or residual injury); 4 (materials that under very short exposure could cause death ormajor residual injury). Flammability Hazard Reactivity Hazard: Refer to definitions for "Hazardous Materials Identification System".
 Flash Point Minimum temperature at which a liquid gives off ~ufficient vapors to f~ an ignitable mixture with air.
 Autoignition Temperature: The minimum temperature required.to initiate combustion in air with no other source of ignition.
 LEL: The lowest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. UEL: The highest percent of vapor in air, by volume, that will explode or i!!nite in the presence of an i!mition source.
-Section 8                       ACGffi - American Conference of Governmental Industrial Hygienists, a professional association which establishes exposure limits.
+Section 8 ACGffi - American Conference of Governmental Industrial Hygienists, a professional association which establishes exposure limits.
-TLV - Threshold Limit Value - an airborne concentration of a substance which represents conditions under which it is generlilly believed that nearly all workers may he repeatedly exposed without adverse effect. *The duration must be considered, including the 8-hour Time Weighted Average (TWA), the 15-minute Short Term Exposure Limit, and the instantaneous Ceiling Level (C). Skin absorptiou effects must also be considered PEL - Permissible Exposure Limit - This exposure value means exactly the same as a TLV, except that it is enforceable by OSHA. The OSHA Pennissible Exposure Limits are based in the 1989 PELs and the June, 1993 Air Contaminants Rule (Federal Recister: 58: 35338-35351 and 58: 40191). Both the current PELs and the vacated PELs are indicated. The phrase, "Vacated 1989 PEL," .is placed next to the PEL which was vacated by Court Order.
+TL V - Threshold Limit Value - an airborne concentration of a substance which represents conditions under which it is generlilly believed that nearly all workers may he repeatedly exposed without adverse effect. *The duration must be considered, including the 8-hour Time Weighted Average (TWA), the 15-minute Short Term Exposure Limit, and the instantaneous Ceiling Level (C). Skin absorptiou effects must also be considered PEL - Permissible Exposure Limit - This exposure value means exactly the same as a TL V, except that it is enforceable by OSHA.
-IDLH - Immediately Dangerous to life and Health - This level represents a concentration from which one can escape within 30-minutes without suffering escape-preventing or permanent injury. The DFG - MAK is the Republic of Germany's Maximum Exposure Level, ~-iillilar to the U.S, PEL NlOSH is lhe National Institute of Occupational Safety and Health, which is the research arm of the U.S. Occupational Safety and Health Administration (OSHA). 1'10SH issues exposure gilldelines called Recommended Exposure Levels (RELs). When no exposure gilldelines are established, an entry of NE (Not Established) is made for reference.
+The OSHA Pennissible Exposure Limits are based in the 1989 PELs and the June, 1993 Air Contaminants Rule (Federal Recister: 58: 35338-35351 and 58: 40191). Both the current PELs and the vacated PELs are indicated. The phrase, "Vacated 1989 PEL,".is placed next to the PEL which was vacated by Court Order.
-       .Section 11                      LDso : Lethal Dose (solids & liquids) which kills 50% of the exposed animals; LC~ : Lethal Concentration (gases) which kills 50% of the exposed animals; ppm: Concentration expressed in parts of material per million parts of air or water; mg/m3 : Concentration expressed in weight of substance per volume of air; mg/kg: Quantity of material, by weight, administered to a test subject, based on their body weight in kg IARC - the International Agency for Research on Cancer; NTP - the National Toxicology Program, RTECS- the Registry of Toxic.Effects of Chemical. Substances, OSHA and CAL/OSHA.
+IDLH - Immediately Dangerous to life and Health - This level represents a concentration from which one can escape within 30-minutes without suffering escape-preventing or permanent injury. The DFG - MAK is the Republic of Germany's Maximum Exposure Level, ~-iillilar to the U.S, PEL NlOSH is lhe National Institute of Occupational Safety and Health, which is the research arm of the U.S. Occupational Safety and Health Administration (OSHA). 1'10SH issues exposure gilldelines called Recommended Exposure Levels (RELs).
+When no exposure gilldelines are established, an entry of NE (Not Established) is made for reference.
+.Section 11 LDso : Lethal Dose (solids & liquids) which kills 50% of the exposed animals; LC~ : Lethal Concentration (gases) which kills 50% of the exposed animals; ppm: Concentration expressed in parts of material per million parts of air or water; mg/m3 : Concentration expressed in weight of substance per volume of air; mg/kg: Quantity of material, by weight, administered to a test subject, based on their body weight in kg IARC - the International Agency for Research on Cancer; NTP - the National Toxicology Program, RTECS-the Registry of Toxic.Effects of Chemical. Substances, OSHA and CAL/OSHA.
 IARC and NTP rate chemicals on a scale of decreasing potential to cause human cancer with rankings from 1 to 4. Subrankings (2A, 2B, etc.) are also used.
-TDLo, the lowest dose to cause a symptom and TC..~o the lowest concentration to cause a symptom; TDo, LDLo, and LDo, or TC, TCo, LCLo, and LCo, the lowest dose (or concentration) to cause lethal or tcixic effects.
+TD Lo, the lowest dose to cause a symptom and TC..~o the lowest concentration to cause a symptom; TDo, LDLo, and LDo, or TC, TCo, LCLo, and LCo, the lowest dose (or concentration) to cause lethal or tcixic effects.
 BEI - Biological Exposure Indices, represent the levels of determinants which are most likely to be observed in. specimens collected from a healthy worker who has been exposed to chemicals to the same exteut as a worker with inhalation exposure to theTLV.
-Section 12                      LC50: The lowest concentration iii water which kills 50% of the test*subjects.
+Section 12 LC50: The lowest concentration iii water which kills 50% of the test*subjects.
 ECso: The Effect Concentration in water at which 50% of the test species if affected.
-Section 13                       US EPA Hazardou5 Waste Codes: refer to 40 CFR 261.20 Section 14                       DOT: US Department of Transportation IATA: International Air Transport Association Th10: International Maritime Organization
+Section 13 US EPA Hazardou5 Waste Codes: refer to 40 CFR 261.20 Section 14 DOT: US Department of Transportation IA TA: International Air Transport Association Th10: International Maritime Organization
-:MARPOL: International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978 IBC Code: Merchant Shipping Code Section 15                      RCRA: US Resource Conservation and Recovery Act SARA: US Superfund Amendments and Reauthorization Act PSM: US OSHA Process Safety Management CFA TS: US Department of Homeland Security Chemical Facility Anti-terrorism Standard DSL: Canadian Domestic Substances List l'<'DSL: Canadian Non-Domestic Substances Llst REACH: European Registration, Evaluation, Authorization and Restriction of Chemicals list TSCA: US Toxic Substances Control Act VITEC&#xa9; 5100 PUBLIC GHS SOS                                                                                                    PAGE 11OF11 I
+:MARPOL: International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978 IBC Code: Merchant Shipping Code Section 15 RCRA: US Resource Conservation and Recovery Act SARA: US Superfund Amendments and Reauthorization Act PSM: US OSHA Process Safety Management CF A TS: US Department of Homeland Security Chemical Facility Anti-terrorism Standard DSL: Canadian Domestic Substances List l'<'DSL: Canadian Non-Domestic Substances Llst REACH: European Registration, Evaluation, Authorization and Restriction of Chemicals list TSCA: US Toxic Substances Control Act VITEC&#xa9; 5100 PUBLIC GHS SOS PAGE 11OF11 I
-_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _                                                                                     I
+I
 Vitec 3000 SAFETY DATA SHEET
-: 1. Company and Product Identification Ll         Identification~ Product Name:                                      Vitec 3000 Other means of identification                                     Organo-pbospborous compounds
+: 1. Company and Product Identification Ll Identification~ Product Name:
+Vitec 3000 1.2 1.3.
-===1.2 Synonym===
+.4 1.5 Other means of identification Synonym:
-Mixture, none Recommended Use OfThe Chemical                                    Reverse osmosis membrane antiscalant 1.3.
+Recommended Use OfThe Chemical and Restrictions On Use:
-and Restrictions On Use:                                          Use only as directed on the label.
+Name, Address, And Telephone Number Of The 1\\llantifacturer, Ot Other Responsible Party:
-Name, Address, And Telephone Number Of                             AVISTA TECHNOLOGIES The 1\llantifacturer, Ot Other Responsible Party:                 140 Bosstick Street 1.4                                                                           San Marcos, CA 92069 (760) 744-0536 Competent Person email address klindsey@avistatech.com 24 Hour Emergency No.:                                            1-800-424-9300 (United States) 1.5 l-703 527-~887 (International Collect)
+Competent Person email address 24 Hour Emergency No.:
-(uN~*.I:
+Organo-pbospborous compounds Mixture, none Reverse osmosis membrane antiscalant Use only as directed on the label.
-\~
+A VISTA TECHNOLOGIES 140 Bosstick Street San Marcos, CA 92069 (760) 744-0536 klindsey@avistatech.com 1-800-424-9300 (United States) l-703 527-~887 (International Collect)
-CERTIFIED BY NSF INTERNATIONAL TO NSF/ANSI 60 AS STANDARD DRINKING WATER TREATMENT CHEMICAL
+(uN~*
-~ FOR USE JN REVERSE OSMOSIS SYSTEMS AT A MAXIMUM
+. I:
-~ L;EVELOF 7 mg/I.
+CERTIFIED BY NSF INTERNATIONAL TO NSF/ANSI 60 AS
+\\~
+STANDARD DRINKING WATER TREATMENT CHEMICAL
+~
+FOR USE JN REVERSE OSMOSIS SYSTEMS AT A MAXIMUM
+~
+L;EVELOF 7 mg/I.
 : 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: This product is amber to light yellow water-based solution with a light disinfectant odor. This product may irritate contaminated tissue. This prod1.1ct is neither reactive nor flammable.
-Physical Hazards Summary       None s
+Physical Hazards Summary None Potential Health Hazards s11rnmary Skin corrosion/irritation, Category 2 H315 Causes skininitation H3J9 Causes serious eye irritation Potential ECological Eft"e<;;ts. Summary None.
-Potential Health Hazards 11rnmary       Skin corrosion/irritation, Category 2 H315 Causes skininitation H3J9 Causes serious eye irritation Potential ECological Eft"e<;;ts. Summary  None.                   **
+.1 Classification Of PrQd11&#xa2;t Skin, eye ii:ritant U.S. OSHAclassification Skin corrosion/irri~tlon; Category 2 Classification as per EC 1272i2008 g315 Causes skin iI:r.itation (CLP/GHS)
-.1          Classification Of PrQd11&#xa2;t Skin, eye ii:ritant U.S. OSHAclassification Skin corrosion/irri~tlon; Category 2 Classification as per EC 1272i2008      g 315 Causes skin iI:r.itation (CLP/GHS)   H319 Causes serious eye irritation E, corrosive WHMIS classification D2B- Poisonous and infectious material - Oi:her effects - Toxic VITEC 3000 GHS SOS                                                                                  PAGE10F11
+H319 Causes serious eye irritation E, corrosive WHMIS classification D2B-Poisonous and infectious material - Oi:her effects - Toxic VITEC 3000 GHS SOS PAGE10F11
-Hazardous Materials Information System (IlliIS) Rating 2.2         Label Elements OSHA/GHS General Warnings     PlOl            If medical advice is needed, have product container or label at hand.
+Hazardous Materials Information System (IlliIS) Rating 2.2 Label Elements OSHA/GHS 2.3 2.4 General Warnings PlOl Pl02 Pl03 Signal Word Hazard statements Precautionary statements Hazard pictograms WARNING!
-Pl02            Keep out of reach of children.
+H315 H319 H335 P271 P281 P312 P302/P352 P261 P305 + P351
-Pl03            Read label before use Signal Word    WARNING!
++P338 Unclassified Hazards None Ingredients with unknown acute None toxicity If medical advice is needed, have product container or label at hand.
-Hazard statements    H315            Causes skin irritation H319            Causes serious eye irritation H335            May cause respiratory irritation Precautionary statements   P271            Use only o&#xb5;tdoors or in a well-ventilated area.
+Keep out of reach of children.
-P281            Use personal protective equipment as required.
+Read label before use Causes skin irritation Causes serious eye irritation May cause respiratory irritation Use only o&#xb5;tdoors or in a well-ventilated area.
-P312            IF SWAI.LOWED: Call a POISON CENTER or doctor/physician if P302/P352       you feel unwell.
+Use personal protective equipment as required.
-P261            Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
+IF SW AI.LOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
-P305 + P351     P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for
+Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
-                                                 +P338           several minutes. Remove contact lenses, if present and easy to do.
+P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
 Continue rinsing.
-Hazard pictograms
+.IT'
-                                                                   .IT'
+\\lJ
-                                                                   \lJ 2.3                       Unclassified Hazards   None 2.4            Ingredients with unknown acute    None toxicity
+: 3. COMPOSITION and INFORMATION ON INGREDIENTS Chemical name
-: 3. COMPOSITION and INFORMATION ON INGREDIENTS Chemical name                            %w/w          US OSHA                    GHS/EUCLP                  WHMIS CAS#
+%w/w US OSHA GHS/EUCLP WHMIS CAS#
 EINECS#
-Deflocculant & Sequestrant                   20-30        Irritant               Skin corrosionfrrritation,      E, corrosive Proprietary                                                                      Category2 D2B - Poisonous H315 Causes skin and infectious
+Deflocculant & Sequestrant 20-30 Irritant Skin corrosionfrrritation, E, corrosive Proprietary Category2 D2B - Poisonous H315 Causes skin and infectious
-                                                                                 .irritation material - Other H319 Causes serious eye effects - Toxic irritation H335 May cause respiratory irritation P261 Avoid breathing dust/ fume/ gas/ mist/
+.irritation material - Other H319 Causes serious eye effects - Toxic irritation H335 May cause respiratory irritation P261 Avoid breathing dust/ fume/ gas/ mist/
 vapors/ spray.
-P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for VITEC 3000 GHS SOS                                                                                  PAGE20F11
+P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for VITEC 3000 GHS SOS PAGE20F11
 several minutes. Remove contact lenses, if present and easy to do~ Continue rinsing.
@@ Line 339: / Line 726: @@
 A void contact with eyes.
 In case of contact with eyes; rinse immediately with plenty of water and seek medical advice.
-Wear suitable protective clothing. If swallowed, seek medical advice immediately and show this container orlabel Chelate Agent       10-20 Corrosive  Skin corrosion/irritation, E, corrosive Proprietary                           Category2 H319 Causes serious-eye irritation P305 + P351 + P338 JF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
+Wear suitable protective clothing. If swallowed, seek medical advice immediately and show this container orlabel Chelate Agent 10-20 Corrosive Skin corrosion/irritation, E, corrosive Proprietary Category2 H319 Causes serious-eye irritation P305 + P351 + P338 JF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
 Keep out of reach of children.
 Keep away from food, drink and animal feeding stuffs.
@@ Line 346: / Line 733: @@
 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
 Wear suitable protective clothing. If swallowed, seek medical advice immediately and show this container or label
-_pH adjustment agent 20-30 Low Hazard H314 Causes severe         Not regulated Proprietary                           bums 1'305 +P351 +P338lF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
+_pH adjustment agent 20-30 Low Hazard H314 Causes severe Not regulated Proprietary bums 1'305 +P351 +P338lF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
 Keep out of reach of children.
-Keep away from food, drink and animal feeding VITEC 3000 GHS SOS                                      PAGE30F11
+Keep away from food, drink and animal feeding VITEC 3000 GHS SOS PAGE30F11
 stuffs.
 Ayoid contact with skin, Avoid eontaet with eyes.
 In case of contact with eyes,. rinse immediately with plenty of water and seek medical advice.
-Wear suitable protective clothing. If swallowed, seek medical advice immediately and show this container or label Water or other chemicals do not                     balance               NIA                       N/A                          N/A contribute to any additional hazards of this product NE= Not Established. C =Ceiling Llmit. See Section 16 for Definitions of Terms Used.
+Wear suitable protective clothing. If swallowed, seek medical advice immediately and show this container or label Water or other chemicals do not balance NIA N/A N/A contribute to any additional hazards of this product NE= Not Established. C =Ceiling Llmit. See Section 16 for Definitions of Terms Used.
-: 4. FIRST-AID MEASURES-4.1        Description of Necessary Measures Skin exposure:         If this product contaminates the skin, immediately begin decontamination with running water. Remove exposed or contaminated clothing, taking care not to contaminate eyes. Victim should seek immediate medical attention if any adverse exposure symptoms develop.
+: 4. FIRST-AID MEASURES-4.1 Description of Necessary Measures 4.2 4.3 Skin exposure:
-Eye exposure:         H this product enters the eyes, open victim's eyes_ while und~r gently running water. Use sufficient force to open eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. Victim must seek medical attention.
+Eye exposure:
-Inhalation:       If vapors, mists, or sprays of this product are inhaled, remove victim to fresh air.
+Inhalation:
+Ingestion:
+Most Important Symptoms/Effects:
+Indication Of Immediate Medical Attention And Special Treatment Needed, If Necessary:
+If this product contaminates the skin, immediately begin decontamination with running water. Remove exposed or contaminated clothing, taking care not to contaminate eyes. Victim should seek immediate medical attention if any adverse exposure symptoms develop.
+H this product enters the eyes, open victim's eyes_ while und~r gently running water. Use sufficient force to open eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. Victim must seek medical attention.
+If vapors, mists, or sprays of this product are inhaled, remove victim to fresh air.
 H necessary, use artificial respiration to support vital functions. Remove or cover gross contamination to avoid exposure to rescuers.
-Ingestion:       If this product is swallowed, CALL PHYSICIAN OR POISON CONIROL CENTER FOR MOST CURRENT INFORMATION. DO NOT INDUCE VOMITING. Have vietlm rinse.mouth with water, if conscious. Never induce vomiting or give a diluent (e.g., water) to someone who is unconscious, having convulsions, or unable to swallow. If contaminated individual is convulsing, maintain an open airway and obtain immediate medical attention.
+If this product is swallowed, CALL PHYSICIAN OR POISON CONIROL CENTER FOR MOST CURRENT INFORMATION. DO NOT INDUCE VOMITING. Have vietlm rinse.mouth with water, if conscious. Never induce vomiting or give a diluent (e.g., water) to someone who is unconscious, having convulsions, or unable to swallow. If contaminated individual is convulsing, maintain an open airway and obtain immediate medical attention.
-.2        Most Important Symptoms/Effects:                         Immediate: Inhalation exposure may cause coughing or sneezing; Symptoms of skin and eye contact may include redness and irritation. Ingestion may cause stomach pains, cramps, and gastritis.
+Immediate: Inhalation exposure may cause coughing or sneezing; Symptoms of skin and eye contact may include redness and irritation. Ingestion may cause stomach pains, cramps, and gastritis.
 Delayed: Prolonged or repeated skin overexposure to this product may cause dermatitis (dcy, red skin). Symptoms may include tingling, redness, and visible irijury.
-.3        Indication Of Immediate Medical                          TARGET ORGANS: Acute: Skin, eyes,                  Chronic: Skin.
+TARGET ORGANS: Acute: Skin, eyes, Chronic: Skin.
-Attention And Special Treatment Needed, If Necessary:
 Victims of chemical exposure must be taken for medical attention if any adverse effects occur. Rescuers should be taken for medical attention if necessary. Take a copy of label and MSDS to physician or health professional with victim.
-VITEC 3000 GHS SOS                                                                                               PAGE40f 11
+VITEC 3000 GHS SOS PAGE40f 11
-: 5. FIRE-FIGHTING MEASURES Flammable properties  Non-flammable aqueous solution                        NFPA FLAMMABILITY OTHER See Section 16 for defuii.tions of ratings Flash Point &deg;C (0 F): Not applicable.
-Autoignition Temperature &deg;C (&deg;F):        Not applicable.
+.1 5.2 5.3
-Flammable Limits (in air by volume, %):
+: 5. FIRE-FIGHTING MEASURES Flammable properties Non-flammable aqueous solution NFPA FLAMMABILITY Suitable And Unsuitable Extinguishing Media:
+Specific Hazards Arising From Chemical:
+Special Protective Equipment And Precautions For Fire-Fighters:
+OTHER See Section 16 for defuii.tions of ratings Flash Point &deg;C (
+F): Not applicable.
+Autoignition Temperature &deg;C (&deg;F):
+Not applicable.
+Flammable Limits (in air by volume, % ):
 Upper: Not applicable.
-Lower: Not applicable.
+Lower:
-.1   Suitable And Unsuitable Extinguishing      This material will not contribute to the intensity of a fire. Use extinguishing Media:                                      material suitable to the surrounding fire.
+Not applicable.
-Water spray              YES                 Carbon dioxide         YES Foam                     YES                Dry chemical            YES Halon                   YES                 Other                  YEs 5.2   Specific Hazards Arising From Chemical:    When involved in a fire, this material may decompose and produce irritating fumes and toxic gases (e.g., carbon monoxide, carbon dioxide, and phosphorous oxides).
+This material will not contribute to the intensity of a fire. Use extinguishing material suitable to the surrounding fire.
+Water spray YES Foam YES Halon YES Carbon dioxide Dry chemical Other YES YES YEs When involved in a fire, this material may decompose and produce irritating fumes and toxic gases (e.g., carbon monoxide, carbon dioxide, and phosphorous oxides).
 Explosion Sensitivitv to Mechanical Impact Not sensitive.
 Explosion Sensitivity to Static Discharge: Not sensitive.
-.3  Special Protective Equipment And            Incipient fire responders should wear eye protection. Structural firefighters must Precautions For Fire-Fighters:              wear Self-Contained Breathing Apparatus and full protective equipment Move containers from fire area if it can be done without risk to personnel. If possible, prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive areas.
+Incipient fire responders should wear eye protection. Structural firefighters must wear Self-Contained Breathing Apparatus and full protective equipment Move containers from fire area if it can be done without risk to personnel. If possible, prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive areas.
-: 6. ACCIDENTAL RELEASE MEASURES 6.1  Personal Precautions                        Uncontrolled releases should be responded to by trained personnel using pre-planned procedures..Proper protective equipment should be used. In case of a spill, clear tl:te affected area and protect people.
+: 6. ACCIDENTAL RELEASE MEASURES 6.1 Personal Precautions Uncontrolled releases should be responded to by trained personnel using pre-planned procedures.. Proper protective equipment should be used. In case of a spill, clear tl:te affected area and protect people.
-Protective equipment For small releases (< 5 gallons), clean up spilled liquid wearing gloves, gog_gles, faceshield, and suitable body protection. The minimum Personal Protective Equipment recommended for response to non-incidental releases (more than 5 gallons) should be Level B: triple-gloves (neoprene gloves and nitrile gloves
+.2 Protective equipment For small releases ( < 5 gallons), clean up spilled liquid wearing gloves, gog_gles, faceshield, and suitable body protection. The minimum Personal Protective Equipment recommended for response to non-incidental releases (more than 5 gallons) should be Level B: triple-gloves (neoprene gloves and nitrile gloves
-                                                 -0ver latex gloves), chemical resistant suit and boots, hard hat, and Self-Contained Breathing Apparatus.
+-0ver latex gloves), chemical resistant suit and boots, hard hat, and Self-Contained Breathing Apparatus.
-Emergency procedures   Mouitoring must indicate that exposure levels are below those provided in Section 3 (Composition and Information on Ingredients) and that oxygen .levels are above 19.5% before anyone is permitted in the area without Self-Contained Breathing Apparatus.
+Emergency procedures Mouitoring must indicate that exposure levels are below those provided in Section 3 (Composition and Information on Ingredients) and that oxygen.levels are above 19.5% before anyone is permitted in the area without Self-Contained Breathing Apparatus.
-.2  Methods and Materials for Containment and Soak up or wet vacuum spilled liquid. Neutralize residue with sodium Cleaning Up                                 bicarbonate or other neutralizing ?gent for dilute acids. Decontaminate the area thoroughly. Test area with litmus paper to ensure neutralization. Place all spill residues in a suitable container. Dispose of in accordance with applicable U.S.
+Methods and Materials for Containment and Cleaning Up Soak up or wet vacuum spilled liquid. Neutralize residue with sodium bicarbonate or other neutralizing ?gent for dilute acids. Decontaminate the area thoroughly. Test area with litmus paper to ensure neutralization. Place all spill residues in a suitable container. Dispose of in accordance with applicable U.S.
 Federal, State, or local procedures, or appropriate local standards (see Section 13, Disposal Considerations).
-VITEC 3000 GHS SOS                                                                                PAGES OF11
+VITEC 3000 GHS SOS PAGES OF11
-: 7. HANDLING and STORAGE 7.1   Precautions for Safe Handling          All employees who handle this material should be trained to handle it safely. Open containers .
+.1 7.2 Precautions for Safe Handling Conditions For Safe Storage
+: 7. HANDLING and STORAGE All employees who handle this material should be trained to handle it safely. Open containers.
 carefully on a stable surface. Empty containers may contain residual liquid; therefore, empty containers should be handled with care.
-As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash thoroughly after handling this product. Do not eat or drink while handling this material. A void generating mists and sprays of this product. Remove contaminated clothing immediately.
+As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash thoroughly after handling this product. Do not eat or drink while handling this material.
+A void generating mists and sprays of this product. Remove contaminated clothing immediately.
 During equipment maintenance follow practices indicated in Section 6 (Accidental Release Measures) to decontaminate equipment or clean-up *small spills. Make certain that application equipment is locked and tagged-out safely if necessary. Collect all rinsates and dispose of according to applicable U.S. Federal, State, or local procedures or appropriate local stan9ards.
-.2   Conditions For Safe Storage             Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store away from incompatible materials. Material should be stored in. secondary containers, or in a diked area, as appropriate. Storage and use areas should be covered with impervious materials. Keep container tightly closed when not in use.
+Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store away from incompatible materials. Material should be stored in. secondary containers, or in a diked area, as appropriate. Storage and use areas should be covered with impervious materials. Keep container tightly closed when not in use.
 If appropriate, post warning signs in storage and use areas, Inspect all incoming containers before storage, to ensure containers are _properly labeled and not damaged.
-Incompatibilities    Strong bases, strong oxidizers, very strong acids1 water reactive materials.
+Incompatibilities Strong bases, strong oxidizers, very strong acids1 water reactive materials.
-: 8. EXPOSURE CONTROLS - PERSONAL PROTECTION 8.1  Control Parameters CHEMICAL NAME                                   CAS#                                  EXPOSURE LIMITS IN AIR ACGJH-TLV                    OSHA-PEL TWA           STEL       TWA         STEL        IDLH        OTHER mg/m3         mg/m3      mglm3       mg/m        mg/IIl       mg/m3 3           3 Deflocculant & Sequestrant                     Proprietary           NE            NE         NE          NE          NE            NE Chelate agent                                 Proprietary           NE            NE         NE          NE          NE           NE pH adjustment agent                            Proprietary           NE         2mg/m3 C    2mg/m3 C      NE          NE       NIOSHREL 2ing/m3 C NE= Not Established. C =Ceiling LimiL See Section 16 for Definitions ofTenns Used.
+: 8. EXPOSURE CONTROLS - PERSONAL PROTECTION 8.1 Control Parameters 8.2 8.3 CHEMICAL NAME CAS#
-.2  Appropriate Engineering Controls.                        Use with adequate ventilation to ensure exposure levels are maintained below the limits provided in this Section or as low as reasonably achievable. Ensure eyewash/safety shower stations are available near areas where. this product is used.
+EXPOSURE LIMITS IN AIR ACGJH-TLV OSHA-PEL TWA STEL TWA STEL IDLH OTHER mg/m3 mg/m3 mglm3 mg/m mg/IIl mg/m3 3
-.3  Personal Protective Equipment                           None needed under normal conditions of use. Use .NIOSH approved respirators Respiratory protection:      if ventilation is inadequate to control mists or vapor. If respiratory protection is needed, use only protection authorized in the U.S. Federal OSHA Standard (29 CFR 1910.134), applicable U.S. State regulatioi;is, or the applicable local standards: Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use of a full-face piece pressure/demand SCBA or a full-face piece, supplied airrespirator with auxiliary self-contained air supply is required under OSHA' s Respiratory Protection Standard ( 1910.134-1998).
+Deflocculant & Sequestrant Proprietary NE NE NE NE NE NE Chelate agent Proprietary NE NE NE NE NE NE pH adjustment agent Proprietary NE 2mg/m3 C 2mg/m3 C NE NE NIOSHREL 2ing/m3 C NE= Not Established. C =Ceiling LimiL See Section 16 for Definitions ofTenns Used.
-Eye protection:      Use approved safety goggles or safety glasses, as described in OSHA 29 CFR 1910.133. Splash goggles with a faceshield may be needed if splash hazards exist.
+Appropriate Engineering Controls.
-Hand protection:      Wear chemical impervious gloves (e.g., Neoprene or Nitrile).
+Use with adequate ventilation to ensure exposure levels are maintained below the limits provided in this Section or as low as reasonably achievable. Ensure eyewash/safety shower stations are available near areas where. this product is used.
-Body protection:      If needed, use body protection appropriate for task (e.g., Tyvek suit, rubber apron) to protect from splashes and sprays.
+Personal Protective Equipment None needed under normal conditions of use. Use.NIOSH approved respirators Respiratory protection: if ventilation is inadequate to control mists or vapor. If respiratory protection is needed, use only protection authorized in the U.S. Federal OSHA Standard (29 CFR 1910.134), applicable U.S. State regulatioi;is, or the applicable local standards: Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use of a full-face piece pressure/demand SCBA or a full-face piece, supplied airrespirator with auxiliary self-contained air supply is required under OSHA' s Respiratory Protection Standard ( 1910.134-1998).
+Eye protection:
+Use approved safety goggles or safety glasses, as described in OSHA 29 CFR 1910.133. Splash goggles with a faceshield may be needed if splash hazards exist.
+Hand protection:
+Wear chemical impervious gloves (e.g., Neoprene or Nitrile).
+Body protection:
+If needed, use body protection appropriate for task (e.g., Tyvek suit, rubber apron) to protect from splashes and sprays.
 VITEC 3000 GHS SOS
 * PAGE 6 OF 11
-: 9. PHYSICAL and CHEMICAL PROPERTIES Appearance'                             This product 1s a clear, amber liquid with a light disiilrectant odor.
-Odor                                    Light disinfectant odor Odor Threshold                                              NIA.
+Appearance' Odor
-Melting Point&deg;C (&deg;F)                     Similar to water               pH                                                   10.7-11.8 Initial Boiling Point &deg;C ("F)            100                            Boiling Point Range &deg;C ("F)                         NIA Flammability                            Non-flalilIIlable               Evaporation Rate (water= 1)                          Similar to water Vapor Density (air= 1)                  Similar to water                Vapor Pressure mm Hg@ 20&deg;C:                          18 Solubility (in water)                    Soluble                        Relative density (water= 1)                          1.2-1.3 Viscosity                                Si,milar to water              Oil-Water Partition Coefficient                     NIA Decomposition Temperature               NIA How To Detect This Substance            'l)le color and odor may act as warning properties associated with this product.
+: 9. PHYSICAL and CHEMICAL PROPERTIES This product 1s a clear, amber liquid with a light disiilrectant odor.
-(Warning Properties):
+Light disinfectant odor Odor Threshold Similar to water pH 100 Boiling Point Range &deg;C ("F)
-: 10. STABILiTY and REACTIVITY 10.1      Reactivity                                   Not considered reactive.
+NIA.
-.2      Chemical Stability                           Stable 10.3      Possibility of hazardous reactions           Hazardous polymerization will not occur.
+.7-11.8 NIA Melting Point&deg;C (&deg;F)
-.4      Conditions to avoid                          Avoid mixing with incompatible materials.
+Initial Boiling Point &deg;C ("F)
-.5      Incompatible Materials                       Strong bases, strong o,xidizers, very strong acids, water reactive materials.
+Flammability Vapor Density (air= 1)
-.6      Hazardous Decomposition Products             Thermal decomposition .of this product may generate carbon monoxide, carbon dioxide, and phosphorus oxides.
+Solubility (in water)
-: 11. TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Toxicity data for                                                                           Dermal                  Inhalation Oral 1D50 mg/kg hazardous ingredients                                                                       LDso mg/kg                LDsomg/kg Deflocculant& Sequestrant                    NIA                                               NIA                              NIA
+Viscosity Non-flalilIIlable Evaporation Rate (water= 1)
-          *Chelate agent                               LD5 o (Oral-Rat) 2100 mgikg                       Standard Draize Test (Skin-LD5 o (Skin-Rabbit)> 6310 mg/kg                   Rabbit) 500 mg/24 hours LD50 (Oral-Quail)> 2510 mg/kg                     Standard Draize Test (Eye-Rabbit) 100 mg: Moderate LD5o (dral-Duck) > 2510 mg/kg IDLo      (Oral-Rat) 1302 mg/kg/31         days-                                   NIA intennittent: Kidney, Urethra, Bladder: other changes in urine composition; Nutritional and Gross Metabolic: weight loss or decreased weight gain, changes in sodium.
+Similar to water Vapor Pressure mm Hg@ 20&deg;C:
-pH adjustment agent                          LD50 (lntraperitoneal-Mouse) 40 mg/kg             Standard Draizc Test (Eye-LDLo (Oral-Rabbit) 500 mg/kg                     .Monkey) 1%/24 hom:s:
+Similar to water 18 Decomposition Temperature How To Detect This Substance (Warning Properties):
-Severe Cytogenetic AnalysiS (Parenteral-Grasshopper)     Standard Draize Test (Skin-20mg
+Reactivity Chemical Stability Soluble Relative density (water= 1) 1.2-1.3 Si,milar to water Oil-Water Partition Coefficient NIA NIA
-* Rabbit) 500 mg/24 hours:
+'l)le color and odor may act as warning properties associated with this product.
-Cytogenetic Analysis (Hamster-Lung) I 0           Severe mmol/L                                            Standard Draize Test (Eye-Cytogenetic Analysis (Hamster-Ovary) 16'          Rabbit) 400 '"g: Mild mmol/L                                            Standard Draize Test. (Eye-Rabbit) 1%: Severe               NIA Standard Draize Test (Eye~
+: 10. ST ABILiTY and REACTIVITY Not considered reactive.
+Stable Hazardous polymerization will not occur.
+A void mixing with incompatible materials.
+.1 10.2 10.3 10.4 10.5 10.6 Possibility of hazardous reactions Conditions to avoid Incompatible Materials Strong bases, strong o,xidizers, very strong acids, water reactive materials.
+Hazardous Decomposition Products Thermal decomposition.of this product may generate carbon monoxide, carbon dioxide, and phosphorus oxides.
+: 11. TOXICOLOGICAL INFORMATION 11.1.
+Information on Toxicological Effects Toxicity data for hazardous ingredients Deflocculant& Sequestrant
+*Chelate agent pH adjustment agent VITEC 3000 GHS SOS Oral 1D50 mg/kg NIA LD5o (Oral-Rat) 2100 mgikg LD5o (Skin-Rabbit)> 6310 mg/kg LD50 (Oral-Quail)> 2510 mg/kg LD5o (dral-Duck) > 2510 mg/kg IDLo (Oral-Rat) 1302 mg/kg/31 days-intennittent:
+Kidney, Urethra, Bladder: other changes in urine composition; Nutritional and Gross Metabolic: weight loss or decreased weight gain, changes in sodium.
+LD50 (lntraperitoneal-Mouse) 40 mg/kg LDLo (Oral-Rabbit) 500 mg/kg Cytogenetic AnalysiS (Parenteral-Grasshopper) 20mg Cytogenetic Analysis (Hamster-Lung) I 0 mmol/L Cytogenetic Analysis (Hamster-Ovary) 16' mmol/L NIA Dermal LDso mg/kg Standard Draize Test (Skin-Rabbit) 500 mg/24 hours Standard Draize Test (Eye-Rabbit) 100 mg: Moderate Standard Draizc Test (Eye-
+.Monkey) 1 %/24 hom:s:
+Severe Standard Draize Test (Skin-Rabbit) 500 mg/24 hours:
+Severe Standard Draize Test (Eye-Rabbit) 400 '"g: Mild Standard Draize Test. (Eye-Rabbit) 1 %: Severe Standard Draize Test (Eye~
 Rabbit) 50 *g/24 hours:
 Severe Standard Draize Test (Eye-Rabbit) 1 mg/24 hours:
-Severe Rinsed with water ,(Eye-Rabbit) 1 mg/30 seconds:
+Severe Rinsed with water,(Eye-Rabbit) 1 mg/30 seconds:
-Severe VITEC 3000 GHS SOS                                                                                               PAGE70F11
+Severe PAGE70F11
+--------~----
+Inhalation LDsomg/kg NIA NIA NIA
-Potential routes of exposure    Inhalation, skin contact, eye contact Potential effects of acute overc  Inhalation exposure may cause tingling, coughing, sneezing, and difficulty breathing.
+Potential routes of exposure Inhalation, skin contact, eye contact Potential effects of acute overc Inhalation exposure may cause tingling, coughing, sneezing, and difficulty breathing.
-exposure   Symptoms of skin and eye contact may include redness and irritatioIL Ingestion may cause stomach pains, cramps, and gastritis.
+exposure Symptoms of skin and eye contact may include redness and irritatioIL Ingestion may cause stomach pains, cramps, and gastritis.
-Potential effects of chronic over-   Prolonged or repeated skin overexposure to this product may cause dermatitis (dry, red exposure   skin) .. Symptoms may include tingling, redness, and visible injury.
+Potential effects of chronic over-Prolonged or repeated skin overexposure to this product may cause dermatitis (dry, red exposure skin).. Symptoms may include tingling, redness, and visible injury.
-Symptoms of over-exposure       Immediate: Inhalation exposure may cause tingling, coughing, sneezing, and difficulty breathing. Symptoms of skin and eye contact may include redness and irritatio11:
+Symptoms of over-exposure Immediate: Inhalation exposure may cause tingling, coughing, sneezing, and difficulty breathing. Symptoms of skin and eye contact may include redness and irritatio11:
 Ingestion may cause stomach pains, cramps, and gastritis.
 Delayed: Prolonged or repeated skin overexposure to this product may cause dermatitis (dry, red skin). Symptoms.may fuclude tingling, redness, and visible injury.
-Conditions aggravated by over-     Preexisting dermatitis, other skin conditions, and respiratory conditions may be exposure   aggravated by exposures to this product.
+Conditions aggravated by over-Preexisting dermatitis, other skin conditions, and respiratory conditions may be exposure aggravated by exposures to this product.
-Recommendations to physicians:       Treat symptoms and .eliminate exposure, Irritation YES This product can be irritating to contaminated tissue.
+Recommendations to physicians:
-Sensitization  NO Carcinogenicity    NTP             IARC             US OSHA                CAL OSHA             67/548 EEC Annexl NO              NO               NO                     NO                   NO Mutagenicity    NO Reproductive toxicity    NO Biological Expostire Index     N/A Other potential health effects   Currently, there are no Biological Exposure Indices (BEis) for ariy component of this product.
+Treat symptoms and.eliminate exposure, Irritation YES This product can be irritating to contaminated tissue.
+Sensitization NO Carcinogenicity NTP NO Mutagenicity NO Reproductive toxicity NO Biological Expostire Index N/ A IARC US OSHA CAL OSHA NO NO NO 67/548 EEC Annexl NO Other potential health effects Currently, there are no Biological Exposure Indices (BEis) for ariy component of this product.
 : 12. ECOLOGICAL INFORMATION ALL WORK PRACTICES Ml,.JST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
-.1  Ecotoxicity                                                 LCso,mg/L                                    ECso, mg/L Vitec 3000 NSF Aquatic;  LCSO (Mysidopsis bahaz) > 1000 mg!L 7 days    EC50 (Daphnia magna) 48honrs==>1000 mg!L NOEC (Daphnia magna) 48 hours== 1000 mg!L Terrestrial N/A                                           NIA 12.2  Persistence and Degradability              The components of this product decompose in soil and water.
+.1 Ecotoxicity LCso,mg/L ECso, mg/L Vitec 3000 NSF Aquatic; LCSO (Mysidopsis bahaz) > 1000 mg!L 7 days EC50 (Daphnia magna) 48honrs==>1000 mg!L NOEC (Daphnia magna) 48 hours== 1000 mg!L Terrestrial N/A NIA 12.2 Persistence and Degradability The components of this product decompose in soil and water.
-.3  Bioaccumu1ative Potential                  The components of this product are not expected to bioaccumulate.
+.3 12.4 12.5 Bioaccumu1ative Potential Mobility in Soil Other Adverse Ecological Effects The components of this product are not expected to bioaccumulate.
-.4  Mobility in Soil                           Moderately mobile.
+Moderately mobile.
-.5  Other Adverse Ecological Effects           This product may be harmful to aquatic life if large volumes of it are released into an aquatic environment.
+This product may be harmful to aquatic life if large volumes of it are released into an aquatic environment.
-: 13. DISPOSAL CONSIDERATIONS Preparing Wastes of this Product for       Waste disposal must be in accordance with appropriate U.S. Federal, State, and local Disposal                                   regulations or with local regulations. This product, if unaltered by the handling, may be disposed of by treatment at a permitted facility or as advii;ed by your local waste regulatory authority.
+: 13. DISPOSAL CONSIDERATIONS Preparing Wastes of this Product for Disposal Disposal of Contaminated Packaging U.S, EPA Waste Number VITEC 3000 GHS SOS Waste disposal must be in accordance with appropriate U.S. Federal, State, and local regulations or with local regulations. This product, if unaltered by the handling, may be disposed of by treatment at a permitted facility or as advii;ed by your local waste regulatory authority.
-Disposal of Contaminated Packaging         Cleaned containers can be recycled or disposed of as non-contaminated waste, if authorized by your local authorities. Dispose of containers as required by local.
+Cleaned containers can be recycled or disposed of as non-contaminated waste, if authorized by your local authorities. Dispose of containers as required by local.
 regulations.
-U.S, EPA Waste Number                      Not applicable.
+Not applicable.
-VITEC 3000 GHS SOS                                                                                  PAGEBOF11
+PAGEBOF11
 : 14. TRANSPORTATION INFORMATION THIS MATERIAL IS NOT HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF TRANSPORTATION.
-.1     UN Number                               Not applicable 14.2     UN Proper Shipping Name                 Not applicable*
+.1 14.2 14.3 14.4 14.5 14.6 14.7 UN Number UN Proper Shipping Name Transport Hazard Class( es)
-.3     Transport Hazard Class(es)              Not applicable Transport label(s) required  Not applicable 14.4     Packing Group                           Not applicable 14.5     Marine Pollutant                        Not applicable NA Emergency Response Guide        Not applicable Number (2008) 14.6     Transport in Bulk (Annex II of          Not applicable MARPOL 73/78 and IBC Code) 14.7     Special Transport Precautions           Not applicable National Motor Freight    #70 Classification
+Transport label(s) required Packing Group Marine Pollutant NA Emergency Response Guide Number (2008)
-.International Air Transport Association UN Number      Not applicable UN Proper Shipping Name       Not applicable Transport Hazard Class(es)    Not applicable Transport label(s) required* Not applicable Packing Group    Not applicable IATA Emergency Response Code         Not applicable Excepted Quantity    Not applicable Packaging Instructions    Not applicable International Maritime Organization UN Number                               Not applicable UN Proper Shipping Name                 Not applicable Transport Hazard Class(es)              Not applicable Transport label(s) required  Not applicable Packing Group                           Not applicable Marine Pollutant                        Not applicabie NA Emergency Response Guide        Not applicable Number (2008)
+Transport in Bulk (Annex II of MARPOL 73/78 and IBC Code)
-Transport in Bulk (Annex II of          Not applicable MARPOL 73/78 and IBC Code)
+Special Transport Precautions National Motor Freight Classification Not applicable Not applicable*
-: 15. SAFETY, HEALTH and ENVIRONMENTAL REGULATIONS SPECIFIC FOR THE PRODUCT Clean Air Act Hi~zardous NO          NO             NO Air Pollutants Safe Drinking Water Act                         NO          NO             NO RCRAF, K, P, U or D-lists No          NO            D002 SARA302           RQ                            NO          NO           lOOOlbs SARA302           TPQ                           NO          NO             NO SARA 313 LISTED                                 NO          NO             NO SARA CHEMICAL CATEGORIES SARA 311/312 ACUTE                              YES        YES             NO VITEC 3000 GHS SDS                                                    PAGE90F11
+Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable
+#70
+.International Air Transport Association UN Number Not applicable UN Proper Shipping Name Not applicable Transport Hazard Class( es)
+Not applicable Transport label(s) required* Not applicable Packing Group Not applicable IA TA Emergency Response Code Not applicable Excepted Quantity Not applicable Packaging Instructions Not applicable International Maritime Organization UN Number UN Proper Shipping Name Transport Hazard Class( es)
+Transport label( s) required Packing Group Marine Pollutant NA Emergency Response Guide Number (2008)
+Transport in Bulk (Annex II of MARPOL 73/78 and IBC Code)
+Not applicable Not applicable Not applicable Not applicable Not applicable Not applicabie Not applicable Not applicable
+: 15. SAFETY, HEALTH and ENVIRONMENTAL REGULATIONS SPECIFIC FOR THE PRODUCT Clean Air Act Hi~zardous NO NO Air Pollutants Safe Drinking Water Act NO NO RCRAF, K, P, U or No NO D-lists SARA302 RQ NO NO SARA302 TPQ NO NO SARA 313 LISTED NO NO SARA CHEMICAL CATEGORIES SARA 311/312 ACUTE YES YES VITEC 3000 GHS SDS PAGE90F11 NO NO D002 lOOOlbs NO NO NO
-SARA 311/312 NO                                      NO                       NO CHRONIC SARA 311/312 FIRE                                  NO                                      NO                       NO SARA311/312 NO                                      NO                       NO PRESSURE SARA 311/312 NO                                      NO                       NO REACTIVITY EPA EXTREMELY HAZARDOUS                                          NO                                      NO                       NO SUBSTANCE Substances
+SARA 311/312 NO NO NO CHRONIC SARA 311/312 FIRE NO NO NO SARA311/312 NO NO NO PRESSURE SARA 311/312 NO NO NO REACTIVITY EPA EXTREMELY HAZARDOUS NO NO NO SUBSTANCE Substances
-     'il" :: *; - "
+'il" :: *; - "
-WHMIS                                              NO                                      NO                         E DSL                                                YES                                    YES                       YES NDSL                                               NIA                                     NIA                      NIA REACH Pre-registered YES                                     YES                      YES List TSCA                                               YES                                    YES                       YES European Inventory of Existing Commercial YES                                    YES                       YES Chemical Substances (EINECS)
+WHMIS NO NO E
-EU No-Longer Polymers NO                                      NO                       NP List (NLP)
+DSL YES YES YES NDSL NIA NIA NIA REACH Pre-registered YES YES YES List TSCA YES YES YES European Inventory of Existing Commercial YES YES YES Chemical Substances (EINECS)
-EEC Classification Packaging, and Labeling        Skin corrosion/irritation, Category             Skin corrosion/irritation, Skin corrosioofuritation, of Dangerous                                                                   Category2                  Category2 Substances(Annex 1)
+EU No-Longer Polymers NO NO NP List (NLP)
-Philippines                                        YES                                    YES                       YES Japan                                              YES                                    YES                       YES Australia                                          YES                                    YES                       YES Korea                                              YES                                    YES                       YES China                                              NO                                      NO                       YES New Zealand Inventory YES                                    YES                       YES of Chemicals
+EEC Classification Packaging, and Labeling Skin corrosion/irritation, Category Skin corrosion/irritation, Skin corrosioofuritation, of Dangerous Substances(Annex 1)
-: 16. OTHER INFORMATION 16.1        Original Preparation                          14 Nov 2005; update 20 February 2014 16.2        Revision History                              13 March 2013 Reformatted to GHS Requirements 163         Prepared by
+Philippines Japan Australia Korea China New Zealand Inventory of Chemicals 16.1 16.2 163 16.4 Original Preparation Revision History Prepared by Date of Printing VITEC 3000 GHS SOS Category2 Category2 YES YES YES YES YES YES YES YES NO NO YES YES
-* ADVANCED CHEMICAL SAFETY, Inc.
+: 16. OTHER INFORMATION 14 Nov 2005; update 20 February 2014 13 March 2013 Reformatted to GHS Requirements ADVANCED CHEMICAL SAFETY, Inc.
-PO Box 152329 San Diego, CA 92195 (858)-874-5577 16.4        Date of Printing                              February 4, 2015 VITEC 3000 GHS SOS                                                                                       PAGE 100F 11
+PO Box 152329 San Diego, CA 92195 (858)-874-5577 February 4, 2015 PAGE 100F 11 YES YES YES YES YES YES
-DEFINITIONS OF TERMS 16.5  A large number*of abbreviations and acronyms appear on a MSDS. Some of these which are co=only nsed include the following:
+DEFINITIONS OF TERMS 16.5 A large number*of abbreviations and acronyms appear on a MSDS. Some of these which are co=only nsed include the following:
-Section 2                       GHS: Global Harmonization System OSHA: U.S. Occupational Safety and Health Adrriinistration.
+Section 2 GHS: Global Harmonization System OSHA: U.S. Occupational Safety and Health Adrriinistration.
-CLP: Classification and Packaging WHMJS: Workplace Hazardous Materials Information System STOT: Specific Target Organ Toxicity Section3                        CAS #: Chemical Abstract Service index number EINECS #: Eurooean Chemical Substances Information Svstem index number Sections                        NFPA: Nation Fire Protection Association Health Ha7.ard: 0 (material that on exposure under fire conditions would offer no hazard beyond that of ordinary combusuble materials); 1 (materials that on exposure under fire conditions coald cause irritation or minor residual injury); 2 (materilils that on intense or continued exposure under fire conditions could cause 'temporary incapacitation or possible residual injury); 3 (materials that can on short exposure could cause serious temporary or residual injury); 4 (materials that under very short exposure could cause death or major residual injury). Flammability Hazard Reactivity Hazard: Refer to definitions for ''Hazardous Materials Identification System".
+CLP: Classification and Packaging WHMJS: Workplace Hazardous Materials Information System STOT: Specific Target Organ Toxicity Section3 CAS #: Chemical Abstract Service index number EINECS #: Eurooean Chemical Substances Information Svstem index number Sections NFPA: Nation Fire Protection Association Health Ha7.ard: 0 (material that on exposure under fire conditions would offer no hazard beyond that of ordinary combusuble materials); 1 (materials that on exposure under fire conditions coald cause irritation or minor residual injury); 2 (materilils that on intense or continued exposure under fire conditions could cause 'temporary incapacitation or possible residual injury); 3 (materials that can on short exposure could cause serious temporary or residual injury); 4 (materials that under very short exposure could cause death or major residual injury). Flammability Hazard Reactivity Hazard: Refer to definitions for ''Hazardous Materials Identification System".
 Flash Point Minimum temperature at which a liquid gives off sufficient vapors to form an ignitable mixture with air.
 Autoignition Temperature: The minimum temperature required to initiate combustion in air with no other source of ignition.
 LEL: The lowest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. UEL: The highest percent of vapor in air, by volume, that will explode or ignite in the oresence of an ignition source.
-Section 8                       ACGJH - American Conference* ofGovernrnental Indnstrial Hygienists, a professional association which establishes exposure limits.
+Section 8 ACGJH - American Conference* ofGovernrnental Indnstrial Hygienists, a professional association which establishes exposure limits.
-TLY- Threshold Limit Value - an airborne concentration of a substance which represe&#xb5;ts conditions under which it is generally believed that nearly all workers may be repeatedly exposed without adverse effect. The duration must be considered, including the 8-hour Time Weighted Average (TWA), the 15-minute Short Term Exposure Limit, and the instantaneous Ceiling Level (C). Skin absorption effects must also be considered PEL - Permissible Exposure Llmit - This exposure value means exactly the same as a TLV, except that it is enforceable by OSHA. The OSHA Permissible Exposure; Limits are based in the 1989 PELs and the June, 1993 Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 40191). Both the current PELs and the vacated PELs are indicated The phrase, "Vacated 1989 PEL," is placed next to the PEL which was vacated by Court Order.
+TL Y-Threshold Limit Value - an airborne concentration of a substance which represe&#xb5;ts conditions under which it is generally believed that nearly all workers may be repeatedly exposed without adverse effect. The duration must be considered, including the 8-hour Time Weighted Average (TWA), the 15-minute Short Term Exposure Limit, and the instantaneous Ceiling Level (C). Skin absorption effects must also be considered PEL - Permissible Exposure Llmit - This exposure value means exactly the same as a TLV, except that it is enforceable by OSHA.
-IDLH - .Immediately Dangerous to Life and Health - This 'level represents a concentration from which one can escape within 30-minntes without suffering escape-preventing or permanent injury. The DFG - MAK is the Republic of Germany's Maximum Exposure Level, similar to the U.S. PEL. NIOSH is the National Institute of Occupational Safety and Health, which is the research arm of the U.S. Occupational Bafety and Health Administration (OSHA). NIOSH issues exposure guidelines called Recommended Exposure Levels (RELs). When no exposure guidelines are established, an entry of NE (Not Established) is made forreference.
+The OSHA Permissible Exposure; Limits are based in the 1989 PELs and the June, 1993 Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 40191). Both the current PELs and the vacated PELs are indicated The phrase, "Vacated 1989 PEL," is placed next to the PEL which was vacated by Court Order.
-Section 11                      LD50 : Lethal Dose (solids & liquids) which kills 50% of the exposed animals; LC5'J : Lethal Concentration (gases) which kills 50% of the exposed animal~;
+IDLH -.Immediately Dangerous to Life and Health - This 'level represents a concentration from which one can escape within 30-minntes without suffering escape-preventing or permanent injury. The DFG - MAK is the Republic of Germany's Maximum Exposure Level, similar to the U.S. PEL. NIOSH is the National Institute of Occupational Safety and Health, which is the research arm of the U.S. Occupational Bafety and Health Administration (OSHA). NIOSH issues exposure guidelines called Recommended Exposure Levels (RELs).
+When no exposure guidelines are established, an entry of NE (Not Established) is made forreference.
+Section 11 LD50 : Lethal Dose (solids & liquids) which kills 50% of the exposed animals; LC5'J : Lethal Concentration (gases) which kills 50% of the exposed animal~;
 ppm: Concentration expressed in parts of material per million parts of air or water; niglm3 : Concentration expressed in weight of substance per volume of air; mg/kg: Quantity of material, by weight, adminisiered to a test subject, based on their body weight in kg IARC - the International Agency for Research on Cancer; NTP - the National Toxicology Program, RTECS - the Registry of Toxic Effects of Chemical Substances, OSHA and CALJOSHA.
-IARC and NTP rate ,chemicals on a scale of decreasing potential to cause hnman cancer with rankings from 1 to 4. Subrankings (2A, 2B, etc.) are also used.
+IARC and NTP rate,chemicals on a scale of decreasing potential to cause hnman cancer with rankings from 1 to 4. Subrankings (2A, 2B, etc.) are also used.
 TDLo, the lowest dose to cause a symptom and TCLo the lowest concentration to. cause a symptom; TDo, LDLo, and LDo, or TC, TCo, LCLo, and LCo, the lowest dose (or concentration) to cause lethal or toxic effects.
 BEI - Biological Exposure Indices, represent the levels of determinants which are most likely to be observed in specimens collected,from a healthy worker who has been exposed to chemicals to the same extent as a worker with inhalation expmfure to thelLV.
-Section 12                      LC50: The lowest concentration in water which kills 50% of the test subjects.
+Section 12 LC50: The lowest concentration in water which kills 50% of the test subjects.
 EC50: The Effect Concentration in water at which 50% of the test species if affected.
-Section 13                      US EPA Hazardous Waste Codes: refer to 40 CFR 261.20 Section 14                      DOT:' US Department of Transportation IATA: International Air Transport Association IJ\.-10: International Maritime Organization 1\-fARPOL: International Convention for the Prevention of Pollution From Ships, 1973 as,modified by the Protocol of 1978 IBC Code : Merchant Shiooing Code Section 15                      RCRA: US Resource Conservation and Recovery Act SARA: US Superfund Amendments and Reauthorization .Act PSM: US OSHA Process Safety Management CFATS: US Department ofHomeland Security Chemical Facility Anti-terrorism Standard DSL: Canadian Domestic Substances List NDSL: Canadian Non-Domestic*Substances List REACH: European Registration, Evaluation, Authorization and Restriction ofChemicals list TSCA: US Toxic Substances Control Act VITEC 3000 GHS SOS                                                                                                        PAGE 11OF11
+Section 13 US EPA Hazardous Waste Codes: refer to 40 CFR 261.20 Section 14 DOT:' US Department of Transportation IA TA: International Air Transport Association IJ\\.-10: International Maritime Organization 1\\-fARPOL: International Convention for the Prevention of Pollution From Ships, 1973 as,modified by the Protocol of 1978 IBC Code : Merchant Shiooing Code Section 15 RCRA: US Resource Conservation and Recovery Act SARA: US Superfund Amendments and Reauthorization.Act PSM: US OSHA Process Safety Management CFATS: US Department ofHomeland Security Chemical Facility Anti-terrorism Standard DSL: Canadian Domestic Substances List NDSL: Canadian Non-Domestic*Substances List REACH: European Registration, Evaluation, Authorization and Restriction ofChemicals list TSCA: US Toxic Substances Control Act VITEC 3000 GHS SOS PAGE 11OF11
+: 1. Identification Product identifier Other means of identification Recommended use Recommended restrictions SAFETY DATA SHEET SODIUM BISULFITE 40%
+None.
+ALL PROPER AND LEGAL PURPOSES None known.
+Manufacturer/Importer/Supplier/Distributor infonnation Manufacturer Company name Address Telephone E-mail Emergency phone number
+: 2. Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements.
+Signal word Hazard statement Precautionary statement Prevention
-SAFETY DATA SHEET
+===Response===
-: 1. Identification Product identifier                 SODIUM BISULFITE 40%
+Storage Disposal Hazard(s) not otherwise classified (HNOC)
-Other means of identification      None.
+Supplemental information Brenntag Mid-South, Inc.
-Recommended use                    ALL PROPER AND LEGAL PURPOSES Recommended restrictions           None known.
+Highway136, West Henderson, KY 42420 270-830-1222 Not available.
-Manufacturer/Importer/Supplier/Distributor infonnation Manufacturer Company name                    Brenntag Mid-South, Inc.
+-424-9300 Not classified, Acute toxicity, oral Skin corrosion/irritation Cf-:IEMTREC Category 4 Category2 Serious eye damage/eye irritation Category 1 Specific target organ toxicity, single exposure Category 3 respiratory tract.irritation Not classified.
-Address                         1405Highway136, West Henderson, KY 42420 Telephone                       270-830-1222 E-mail                          Not available.
+Not classified:
-Emergency phone number          800-424-9300                       Cf-:IEMTREC
+Danger Harmful if swallowed. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation.
-: 2. Hazard(s) identification Physical hazards                   Not classified, Health hazards                     Acute toxicity, oral                               Category 4 Skin corrosion/irritation                          Category2 Serious eye damage/eye irritation                  Category 1 Specific target organ toxicity, single exposure    Category 3 respiratory tract .irritation Environmental hazards              Not classified.
+Avoid breathing mist or vapor. Wash thoroughly after handling. Do riot eat, drink or smoke when using this product. Use only outc;loors or in a well-ventilated area. Wear protective gloves. Wear eye/face protection.
-OSHA defined hazards               Not classified:
+If swallowed: Call a poison center/doctor if yell feel unwell. If on skin: Wash with plenty of water. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
-Label elements.
-Signal word                    Danger Hazard statement              Harmful if swallowed. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation.
-Precautionary statement Prevention              Avoid breathing mist or vapor. Wash thoroughly after handling. Do riot eat, drink or smoke when using this product. Use only outc;loors or in a well-ventilated area. Wear protective gloves. Wear eye/face protection.
-Response                If swallowed: Call a poison center/doctor if yell feel unwell. If on skin: Wash with plenty of water. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
 Continue rinsing. Immediately call a poison center/doctor. Rinse mouth. lfskiri irritation occurs:
 Get medical advice/attention. Take pff contaminated clothing and wash before reuse.
-Storage                 Store in a well-ventilated place. Keep container tightly closed. Store locked up.
+Store in a well-ventilated place. Keep container tightly closed. Store locked up.
-Disposal                Dispose of contents/container in accordance with local/regional/national/international regulations.
+Dispose of contents/container in accordance with local/regional/national/international regulations.
-Hazard(s) not otherwise            None known.
+None known.
-classified (HNOC)
+None.
-Supplemental information           None.
+: 3. Composition/information on ingredients Mixtures Material name: SODIUM BISULFITE 40%
-: 3. Composition/information on ingredients Mixtures Material name: SODIUM BISULFITE 40%                                                                                                 sos us 566657 Version#: 01 Issue date: 04-11-2015                                                                                           117
+Version#: 01 Issue date: 04-11-2015 sos us 117
-Chemical name                                 Common name and synonyms                      CAS number                      %
+Chemical name DISULFUROUS ACID, SODIUM SALT (1 :2)
-DISULFUROUS ACID, SODIUM                                                                      7681-57-4                    40 SALT (1 :2)
+Common name and synonyms CAS number 7681-57-4 40 Other components below reportable levels 60
-Other components below reportable levels                                                                                   60
 *nesignates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
-: 4. First-aid measures Inhalation                          Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
+: 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and speciai treatment needed General information
-Skin contact                        Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse.
+: 5. Fire-fighting measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
-Eye contact                         Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately.
+Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse.
-Ingestion                           Rinse mouth. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
+Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately.
+Rinse mouth. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
 Get medical advice/attention if you feel unwell.
-Most important                      Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred symptoms/effects, acute and         vision. Permanent eye da!J1age including blindness could result. May cause respiratory irritation.
+Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye da!J1age including blindness could result. May cause respiratory irritation.
-delayed                             Skin irritation. May cause redness arid pain.
+Skin irritation. May cause redness arid pain.
-Indication of immediate             Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim medical attention and speciai       unde*r observation. Symptoms may be delayed.
+Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim unde*r observation. Symptoms may be delayed.
-treatment needed General information                  If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance.
+If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance.
-: 5. Fire-fighting measures Suitable extinguishing media        Water fog. Foam. Dry chemical powder. Carbon dioxide (C02).
+Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (C02).
-Unsuitable extinguishing             Do not use water jet as an extinguisher, as this will spread the fire.
+Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
-media Specific hazards arising from        During fire, gases hazardous to health may be formed.
+media Specific hazards arising from During fire, gases hazardous to health may be formed.
-the chemical Special protective equipment        Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
+the chemical Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
-and precautions for firefighters Fire fighting                       Move containers from fire area if you can do so without risk.
+and precautions for firefighters Fire fighting Move containers from fire area if you can do so without risk.
-equipment/instructions Specific methods                     Use standard firefighting procedures and consider the hazards of other involved materials.
+equipment/instructions Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
-General fire hazards                 No unusual fire or explosion hazards noted.
+General fire hazards No unusual fire or explosion hazards noted.
-: 6. Accidental release measures Personal precautions,                Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear protective equipment and            appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do emergency procedures                 not touch damaged containers or spilled material unless wearing appropriate protective clothing.
+: 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Environmental precautions
+: 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
 Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personai protection, see section 8 of the SOS.
-Methods and materials for            Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is containment and cleaning up          possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water.
+Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water.
 Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.
 Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
-Environmental precautions            Avoid discharge into drains, water courses or onto the ground.
+Avoid discharge into drains, water courses or onto the ground.
-: 7. Handling and storage Precautions for safe handling        Do not get this material in contact with eyes. Avoid breathing mist or vapor: Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or smoke. Provide adequate ventilation. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices.
+Do not get this material in contact with eyes. Avoid breathing mist or vapor: Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or smoke. Provide adequate ventilation. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices.
-Conditions for safe storage,         Store locked up. Store -in original tightly closed container. Store away from incompatible materials including any incompatibilities      (see Section 10 of the SDS).
+Store locked up. Store -in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS).
-Material name: SODIUM BISUL)=ITE 40%                                                                                                     sos us 566657 Version#: 01 Issue dale: 04-11-2015                                                                                                 217
+Material name: SODIUM BISUL)=ITE 40%
-: 8. Exposure controls/personal protection Occupational exposure limits US. ACGIH Threshold Limit Values Components                                      Type                                    Value DISULFUROUS ACID,                               TWA                                     5 mg/m3 SODIUM SALT (1 :2) (GAS 7681-57-4)
+Version#: 01 Issue dale: 04-11-2015 sos us 217
-US. NIOSH: Pocket Guide to Chemical Hazards Components                                      Type                                    Value DISULFUROUS ACID,                               TWA                                     5 mg/m3.
+: 8. Exposure controls/personal protection Occupational exposure limits US. ACGIH Threshold Limit Values Components DISULFUROUS ACID, SODIUM SALT (1 :2) (GAS 7681-57-4)
-SODIUM SALT (1 :2) (CAS 7681-57-4)
+Type TWA US. NIOSH: Pocket Guide to Chemical Hazards Components Type DISULFUROUS ACID, SODIUM SALT (1 :2) (CAS 7681-57-4)
-Biological limit values               No biological exposure limits noted for the ingredient(s).
+TWA Value 5 mg/m3 Value 5 mg/m3.
-Appropriate engineering               Good general ventilation (typically 1O air changes per hour) should be used. Ventilation rates controls                              should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this pr-!lduct.
+No biological exposure limits noted for the ingredient(s).
-Individual protection measures, such as personal protective equipment Eye/face protection             Wear safety glasses with side shields (or goggl.es) and a face shield.
+Biological limit values Appropriate engineering controls Good general ventilation (typically 1 O air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this pr-!lduct.
-Skin protection Hand protection            Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier.
+Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggl.es) and a face shield.
-Other                      Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
+Skin protection Hand protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier.
-Respiratory protection          In case of insufficient ventilation, wear suitable respiratory equipment. Chemical respirator with organic vapor cartridge.
+Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
-Thermal hazards                  Wear appropriate thermal protective clothing, when necessary.
+Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. Chemical respirator with organic vapor cartridge.
-General hygiene                       Keep away from food and drink. Always observe good personal hygiene measures, such as considerations                        washing after handling the material and before eating, drinking, and/o.r smoking. Routinely wash work clothing and protective equipment to remove contaminants.
+Wear appropriate thermal protective clothing, when necessary.
-: 9. Physical and chemical properties Appearance Physical state                  Liquid.
+Thermal hazards General hygiene considerations Keep away from food and drink. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/o.r smoking. Routinely wash work clothing and protective equipment to remove contaminants.
-Form                            Liquid.
+: 9. Physical and chemical properties Appearance Physical state Form Color Odor Odor threshold pH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas)
-Color                            Not available.
+Liquid.
-Odor                                  Not available.
+Liquid.
-Odor threshold                        Not available.
+Not available.
-pH                                    Not available.
+Not available.
-Melting point/freezing point          302 &deg;F (150 &deg;C) estimated/ 999 &deg;F (537.22 &deg;C)
+Not available.
-Initial boiling point and boiling     212 &deg;F (100 "C) estimated range Flash point                           999.0 "F (537.2 "C)
+Not available.
-Evaporation rate                      Not available.
+&deg;F (150 &deg;C) estimated/ 999 &deg;F (537.22 &deg;C) 212 &deg;F (100 "C) estimated 999.0 "F (537.2 "C)
-Flammability (solid, gas)             Not applicable.
+Not available.
-Upper/lower flammability or explosive llmits Flammability limit - lower       Not available.
+Not applicable.
+Upper/lower flammability or explosive llmits Flammability limit - lower Not available.
 (%)
-Flammability limit - upper       Not available.
+Flammability limit - upper Not available.
 (%)
-Explosive limit - lower(%)       Not available.
+Explosive limit - lower(%)
-Explosive limit - upper(%)       Not available.
+Not available.
-Vapor pressure                        0.00001 hPa estimated Material name: SODIUM BISULFITE 40%                                                                                                   SDS US 566657    Version#: 01 Issue date: 04-11-2015                                                                                          317
+Explosive limit - upper(%)
+Not available.
+Vapor pressure 0.00001 hPa estimated Material name: SODIUM BISULFITE 40%
+Version#: 01 Issue date: 04-11-2015 SDS US 317
-Vapor density                          Not available.
+Vapor density Relative density Solubility(ies)
-Relative density                       Not available.
+Solubility (water)
-Solubility(ies)
+Partition coefficient (n-octanol/water)
-Solubility (water)               Not available.
+Auto-ignition temperature Decomposition temperature Viscosity Other information Density Flammability class Percent volatile Specific gravity Not available.
-Partition coefficient                   Not available.
+Not available.
-(n-octanol/water)
+Not available.
-Auto-ignition temperature              Not available.
+Not available.
-Decomposition temperature              Not available.
+Not available.
-Viscosity                              Not available.
+Not available.
-Other information Density                          11.68 lbs/gal estimated Flammability class               Combustible 1118 estimated Percent volatile                 60 % estimated Specific gravity                 1.4 estimated
+Not available.
-: 10. Stability and reactivity Reactivity                              The product is stable and non-reactive under normal conditions of use, storage and transport.
+.68 lbs/gal estimated Combustible 1118 estimated 60 % estimated 1.4 estimated
-Chemical stability                     Material is stable under normal conditions.
+: 10. Stability and reactivity Reactivity Chemical stability The product is stable and non-reactive under normal conditions of use, storage and transport.
-Possibility of hazardous                Hazardous polymerization does not occur.
+Material is stable under normal conditions.
-reactions Conditions to avoid                     Contact with incompatible materials.
+Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products Hazardous polymerization does not occur.
-Incompatible materials                 .Strong oxidizing agents, Hazardous decomposition                 No haz.ardous decomposition products are known.
+Contact with incompatible materials.
-products
+.Strong oxidizing agents, No haz.ardous decomposition products are known.
-: 11. Toxicological information lnformation*on likelyroutes ofexposure Inhalation                       May cause irritation   to the respiratory system. Prolonged .inhalation may be harmful.
+: 11. Toxicological information lnformation*on likelyroutes ofexposure Inhalation May cause irritation to the respiratory system. Prolonged.inhalation may be harmful.
-Skin contact                      Causes skin irritation.
+Skin contact Eye contact Ingestion Causes skin irritation.
-Eye contact                       Causes serious eye damage.
+Causes serious eye damage.
-Ingestion                         Harmful if swallowed.
+Harmful if swallowed.
-Symptoms related to the                 Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred physical, chemical and                 vision. Permanent eye damage including blindness could result. May cause respiratory irritation.
+Symptoms related to the physical, chemical and toxicological characteristics Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. May cause respiratory irritation.
-toxicological characteristics           Skin irritation. May cause redness and pain.
+Skin irritation. May cause redness and pain.
-Information on toxicological effects Acute toxicity                          In high concentrations, vapors are anesthetic and may cause headache, fatigue, dizziness and central nervous system effects. Harmful if swallowed. May cause respiratory irritation.
+Information on toxicological effects Acute toxicity In high concentrations, vapors are anesthetic and may cause headache, fatigue, dizziness and central nervous system effects. Harmful if swallowed. May cause respiratory irritation.
- ~~00~                                     ~~                                                      ~~~
+~~00~
+~~
+~~~
 DISULFUROUS ACID, SODIUM SALT (1 :2) (CAS 7681-57-4)
-Ac lite Oral LD25                           Sheep                                                   2.375 g/kg LOSO                           Sheep                                                   2.515 g/kg LD75                           Sheep                                                   2.675 g/kg
+Ac lite Oral LD25 Sheep 2.375 g/kg LOSO Sheep 2.515 g/kg LD75 Sheep 2.675 g/kg
-       *Estimates for product may be based on additional component data not shown.
+*Estimates for product may be based on additional component data not shown.
-*skin corrosion/irritation              Causes skin irritation.
+*skin corrosion/irritation Causes skin irritation.
-Serious eye damagefeye                 Causes serious eye damage.
+Serious eye damagefeye Causes serious eye damage.
-irritation Respiratory or skin sensitization Respiratory sensitization        Not a respiratory sensitizer.
+irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer.
-Skin sensitization               This product is not expected    to cause skin sensitization.
+Skin sensitization This product is not expected to cause skin sensitization.
-Material name: SODIUM BISULFITE 40%-                                                                                                 sos us 566657    Version#: 01  Issue date: 04-11-2015                                                                                        417
+Material name: SODIUM BISULFITE 40%-
+Version#: 01 Issue date: 04-11-2015 sos us 417
-Germ cell mutagenicity                  No data a'vailable to indicate product or any components present at greater than 0.1 % are mutagenic or genotoxic.
+Germ cell mutagenicity No data a'vailable to indicate product or any components present at greater than 0.1 % are mutagenic or genotoxic.
-Carcinogenicity                         This product is not considered to be a carcinogen by !ARC, ACGIH, NTP, or OSHA.
+Carcinogenicity This product is not considered to be a carcinogen by !ARC, ACGIH, NTP, or OSHA.
 OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
 Not listed.
-Reproductive toxicity                   This product is not expected to cause reproductive or developmental effects.
+Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
-Specific target organ toxicity -        May cause respiratory irritation.
+Specific target organ toxicity -
-single exposure Specific target organ toxicity -        Not Classified.
+May cause respiratory irritation.
-repeated exposure Aspiration ha:tard                      Not an aspiration hazard.
+single exposure Specific target organ toxicity -
-Chronic effects                         Prolonged inhalation may be harmful.
+Not Classified.
-: 12. Ecological information Ecotoxicity                             The product is not classified as environmentally hazardous. However, this does not exclude the possibility thaflarge or frequent spills can have a harmful or damaging effect on the environment.
+repeated exposure Aspiration ha:tard Not an aspiration hazard.
-Persistence and degradability           No data is available on the degradability of this product.
+Chronic effects Prolonged inhalation may be harmful.
-Bioaccumulative potential              .No data available.
+: 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility thaflarge or frequent spills can have a harmful or damaging effect on the environment.
-Mobility in soil                        No data available.
+Persistence and degradability Bioaccumulative potential Mobility in soil Other*adverse effects No data is available on the degradability of this product.
-Other*adverse effects                   No other adverse environmental' effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.
+.No data available.
-: 13. Disposal considerations Disposal instructions                   Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in ac_cordance with local/regional/nationallintemational regulations.
+No data available.
-Local disposal regulations              Dispose in accordance with all applicable regulations.
+No other adverse environmental' effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.
-Hazardous waste code                    The waste code should be assigned in discussion between the user, the producer and the waste disposal company.
+: 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in ac_cordance with local/regional/nationallintemational regulations.
-Waste from residues I unused            Dispose of in accordance with local regulations. Empfy containers orliners may retain some products                                product residues. This material and its container must be disposed of in a safe manner (see:
+Dispose in accordance with all applicable regulations.
-Disposal instructions).                               *
+Local disposal regulations Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company.
-* Contaminated packaging                  Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.
+Waste from residues I unused products Dispose of in accordance with local regulations. Empfy containers orliners may retain some product residues. This material and its container must be disposed of in a safe manner (see:
-: 14. Transport information DOT UN number                          UN2693 UN proper shipping name            BISULFITES, AQUEOUS SOLUTIONS, N.O.S. ( RQ = RQ)
+Disposal instructions).
-Transport hazard class(es)
+Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.
-Class                        80 Subsidiary risk Packing group                      Ill Special precautions for user        Read safety instructions, SOS and emergency procedures before handling.
+: 14. Transport information DOT UN number UN proper shipping name Transport hazard class(es)
-ERG number                         154 DOT information on packaging       may be different from that listed.
+Class Subsidiary risk UN2693 BISULFITES, AQUEOUS SOLUTIONS, N.O.S. ( RQ = RQ) 80 Packing group Ill Special precautions for user Read safety instructions, SOS and emergency procedures before handling.
-: 15. Regulatory information US federal regulations                  This product is a "Hazardous Chemical" as defined by .the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
+ERG number 154 DOT information on packaging may be different from that listed.
+: 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by.the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
 All components are on the U.S. EPA TSCA Inventory List.
 TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
@@ Line 615: / Line 1,059: @@
 Not listed.
 SARA 304 Emergency release notification Not regulated.
-Material name: SODIUM BISULFITE 40%                                                                                                  SDSUS 566657    Version#: 01   Issue date: 04-11-2015                                                                                       517
+Material name: SODIUM BISULFITE 40%
+Version#: 01 Issue date: 04-11-2015 SDSUS 517
 OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
 Not listed.
 Superfund Amendments and Reauthorization Actof 1986 (SARA).
-Hazard categories                   Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremeiy hazardous substance Not listed.
+Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremeiy hazardous substance Not listed.
-SARA 311/312 Hazardous              No chemical SARA313 (TRI reporting)
+SARA 311/312 Hazardous chemical SARA313 (TRI reporting)
 Not regulated.
-Other federal regulations Clean Air Act {CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated.
+Other federal regulations No Clean Air Act {CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated.
 Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
 Not regulated.
-Safe Drinking Water Act             Not regulated.
+Safe Drinking Water Act (SOWA)
-(SOWA)
+US state regulations Not regulated.
-US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
+US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
 Not listed.
 US. Massachusetts RTK - Substance List DISULFUROUS ACID, SODIUM SALT (1 :2) (CAS 7681-57-4)
@@ Line 636: / Line 1,081: @@
 US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 6S): This mat.erial is not l{nown. to contain.
 any chemicals currently listed as carcinogens or reproductive toxins.
-International Inventories Country(s) or region                Inventory name                                                                     On inventory (yes/no)*
+International Inventories Country(s) or region Austrafia Canada Canada China Europe Europe Japan Korea New Zealand Philippines
-Austrafia                           Australian Inventory of Chemical Substances (AICS)                                                        Yes Canada                              Domestic Substances List (DSL)                                                                            Yes Canada                              Non-Domestic Substances List (NDSL)                                                                        No China                               Inventory of Existing Chemical Substances in China (IECSC)                                                Yes Europe                              European Inventory of Existing Commercial Chemical                                                        Yes Substances (EINECS)
+* United States & Puerto Rico Inventory name Australian Inventory of Chemical Substances (AICS)
-Europe                              European List.of Notified Chemical Substances (ELINCS)                                                     No Japan                               Inventory of Existing and New Chemical Substances (ENCS)                                                  Yes Korea                               Existing Chemicals List (ECL)                                                                             Yes New Zealand                         New Zealand Inventory                                                                                     Yes Philippines                         Philippine Inventory of Chemicals and Chemical Substances                                                 Yes (PICCS)
+Domestic Substances List (DSL)
-* United States & Puerto Rico         Toxic Substances Control Act (TSCA) Inventory                                                             Yes
+Non-Domestic Substances List (NDSL)
-     *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
+Inventory of Existing Chemical Substances in China (IECSC)
+European Inventory of Existing Commercial Chemical Substances (EINECS)
+European List.of Notified Chemical Substances (ELINCS)
+Inventory of Existing and New Chemical Substances (ENCS)
+Existing Chemicals List (ECL)
+New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS)
+Toxic Substances Control Act (TSCA) Inventory On inventory (yes/no)*
+Yes Yes No Yes Yes No Yes Yes Yes Yes Yes
+*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
 A "No" indicates that one or more components of the product are not listed,or exempt from listing on the inventory administered by the governing country(s)_
-, Other information, including date of preparation or last revision Issue date                               04-11-2015 Material name: SODIUM BISULFITE 40%                                                                                                             SOS US 566657     Version#: 01   Issue date: 04-11-2015                                                                                                 617
+, Other information, including date of preparation or last revision Issue date 04-11-2015 Material name: SODIUM BISULFITE 40%
+Version#: 01 Issue date: 04-11-2015 SOS US 617
-Version#                             01 HMIS ratings                        Health: 3 Flammability: 0 Physical hazard: 0 NFPA ratings                         Health: 3 Flammability: 0 Instability: O Disclaimer                           BNA carinot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used, It is the user's responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability.
+Version#
+HMIS ratings NFPA ratings Disclaimer 01 Health: 3 Flammability: 0 Physical hazard: 0 Health: 3 Flammability: 0 Instability: O BNA carinot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used, It is the user's responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability.
 for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available.
-Material name: SODIUM BISULFITE 40%                                                                                                 sos us 566657    Version#: 01 Issue date: 04-11-2015                                                                                        717
+Material name: SODIUM BISULFITE 40%
+Version#: 01 Issue date: 04-11-2015 sos us 717
 APPLICATION FOR A lVIlNOR REVISION TO A WASTEWATERFACILITYORACTIVITY PERMIT
 : 1. Instructions
-: a. fn accordance '\\~th Rule 62~620.325, F.A.C., this form must be submitted to the appropriate Department district office or approved local program when requests for minorrevisiol1s to a permit or minor modifications to a facility are made by a pe1mittee, except for transfer of a permit to a new permittee and addition of a major user of reclaimed water to a Part III reuse system. Application for transfer of a pennit to a new perrnittee shall be made on DEP Form 62-620.910(11). Application for addition of'a major user ofreclaimed water shall be made on DEP Form 62-610.300(4)(a)l.
+: a. fn accordance '\\\\~th Rule 62~620.325, F.A.C., this form must be submitted to the appropriate Department district office or approved local program when requests for minorrevisiol1s to a permit or minor modifications to a facility are made by a pe1mittee, except for transfer of a permit to a new permittee and addition of a major user of reclaimed water to a Part III reuse system. Application for transfer of a pennit to a new perrnittee shall be made on DEP Form 62-620.910(11). Application for addition of'a major user ofreclaimed water shall be made on DEP Form 62-610.300(4)(a)l.
 : b. Each applicable item must be completed in full in order to avoid delay in processing of this form. Where attached sheets or other technical documentation are provided, indicate appropriate cross-references.
 : c. Three (3) copies of this application with supporting documentation shall be submitted with this form.
@@ Line 656: / Line 1,112: @@
 : e. This application and attachments shaU be signed in accordance with Rule 62-6,20.305, F.A.C. Also, as applicable, this application and all attachments shall be signed and sealed by a professional engineer registered in Florida in accordance with Rule 62-620.310, F.A.C.
 : 2. Facility Information
-: a. Permit Number: FL00022os                                       b. Facility Identification Number: FL0002208
+: a. Permit Number:
-: c. Project/Facility Name: Florida Power and Light St. Lucie Plant
+FL00022os
-: d. ContactName:                              ChristopherCostanzo
+: b. Facility Identification Number:
-                                                    ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
+FL0002208
-Number and Street:                       6501 Ocean Drive City/State/Zip Code:                     Jensen Beach, FL 34957 Telephone                                772-465-3550
+: c. Project/Facility Name:
+Florida Power and Light St. Lucie Plant
+: d. ContactName:
+ChristopherCostanzo
+~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
+Number and Street:
+Ocean Drive City/State/Zip Code:
+Jensen Beach, FL 34957 Telephone 772-465-3550
 : 3. Type of Revision Ocorrcct Typographical Errors1 - Submit one copy of each pag;e of the permit showing revisions being requested.
 Dchange Improvement Schedulc1 - Provide a description of the improvement, a list of the dates to be revised, and a reason for the proposed change in each date.
-Ochange Expiration Date of Permit 1 - Provide the current and proposed expiration dates for the permit and the reasons for the proposed change.
+Ochange Expiration Date of Permit1 - Provide the current and proposed expiration dates for the permit and the reasons for the proposed change.
-DChange Staffing Requirements2 -Describe the proposed change and submit justification for the change in accordance with Chapter 62-699, F.A.C.
+DChange Staffing Requirements2-Describe the proposed change and submit justification for the change in accordance with Chapter 62-699, F.A.C.
-A processing fee is not required.                                                                                     DEP Fonn 62*620.910(9) 2A processing fee is required with the application                                                                    Effective October 23. 2000 in accordance with Ruic 62-4.050, F.A.C.
+A processing fee is not required.
+A processing fee is required with the application in accordance with Ruic 62-4.050, F.A.C.
+DEP Fonn 62*620.910(9)
+Effective October 23. 2000
-D         Change.Monitoring and Reporting Requirements2 - Describe the proposed change and submit justification for the change in accordance with Chapter 62-601, F.A.C.
+D Change.Monitoring and Reporting Requirements2 - Describe the proposed change and submit justification for the change in accordance with Chapter 62-601, F.A.C.
-D required byRule Modify Approved Pretreatment Program1 -
+D Modify Approved Pretreatment Program1 - Describe the proposed modification and provide the information required byRule 62-625.540, F.A.C D Delete Point Source Outfan1
--625.540,    F.A.C Describe the proposed modification and provide the information D          Delete Point Source Outfan1
 * Identify the outfall and explain why the outfall is being eliminated.
-D or Dedicated Site Plan as required by Chapter F.A.C. Attach a new or updated Agricultural Use Modify or Expand Approved Residuals Land Application Sites 2 -
+D Modify or Expand Approved Residuals Land Application Sites2 - Attach a new or updated Agricultural Use or Dedicated Site Plan as required by Chapter 62-640, F.A.C..
--640, I./Ii;my                                                     2 Minor Modification to the Facility Provide a description of the proposed modification. If applicable, attach reports, plans, and specifications which have been developed to implement this modification.
+I./ I Minor Modification to the Facility2 - Provide a description of the proposed modification. If applicable, attach i;my reports, plans, and specifications which have been developed to implement this modification.
-D          Other - Provide appropriate documentation. Describe.
+D Other - Provide appropriate documentation. Describe.
-: 4. Certifications a Applicant or Authorized Representative I certify under penalty of law that I have personally examined and am familiar with the infonnation submitted in this application and all attachments and that, based on my inquiry of persons immediately responsible for obtaining the information contained in the application, I believe that the inf01mation is true, accurate and complete.. I am aware that there are significant penalties for submitting false infmmation, including the possibili               fine and imprisonment.                                   ----"b..,.}'--I_*~.,.._,'/.'-~-*- - - - - - - - - -
+: 4. Certifications a Applicant or Authorized Representative I certify under penalty of law that I have personally examined and am familiar with the infonnation submitted in this application and all attachments and that, based on my inquiry of persons immediately responsible for obtaining the information contained in the application, I believe that the inf01mation is true, accurate and complete.. I am aware that there are significant penalties for submitting false infmmation, including the possibili fine and imprisonment.
-(D~f'f-7 Name (please type) Christopher Costanzo                                   Company Name Florida Power and Light Title Sl Lucie Plant Vice President                                                                 --------------
+----"b..,.}'--I_*~.,.._,'/.'-~-* ----------
-Company Address: _s_so_1_s_o_c_ea_n_D_n_*v_e__________
+(D~f'f-7 Name (please type)
-Phone: 772-467-1100                                            City/State/Zip Code: _J_en_s_en_B_e_a_ch_,_FL_3_4_s_s1_________
+Christopher Costanzo Company Name Florida Power and Light Title Sl Lucie Plant Vice President Company Address:
+_s_so_1_s_o_c_ea_n_D_n_*v_e _________ _
+Phone:
+-467-1100 City/State/Zip Code:
+_J_en_s_en_B_e_a_ch_,_FL_3_4_s_s1 ________ _
 Email (optional): christopher.costanzo@fpl.com
-: b. Professional Engineer Registered in Florida I certifv that the engineering features ofthis project have been (designed) (examined) by me and found to conform to engineering principles applicable to such projects. fo my professional judgemen~ this facility, when properly constructed, operated, and maintained, will comply with all applicable statutes of the State ofFlorida and rules of the Department Name (please type):                              TimothyW. Powell Florida Registration Nuri1ber:                   51477
+: b. Professional Engineer Registered in Florida I certifv that the engineering features ofthis project have been (designed) (examined) by me and found to conform to engineering principles applicable to such projects. fo my professional judgemen~ this facility, when properly constructed, operated, and maintained, will comply with all applicable statutes of the State ofFlorida and rules of the Department Name (please type):
-                                                               ~---------
+TimothyW. Powell Florida Registration Nuri1ber:
-Company Name:                        Florida Power & Light Company Address: 700 Universe Blvd, GTNJB City/State/Zip Code: Juno Beach, FL 33408 Phone Number:
-(Seal, Email (optional):               timothy.powell@fpl.com Jlf signed hy the ~futhorized repr~enlative,                                      2                                                    DEP Form 62-620. 910(9) attach a letter of authorization in accordance                                                                                       Elrective October 23,.2000 Rule 62-620.305, F.A C.}}
+~---------
+Company Name:
+Florida Power & Light Company Address:
+Universe Blvd, GTNJB City/State/Zip Code: Juno Beach, FL 33408 Phone Number:
+Email (optional):
+Jlf signed hy the ~futhorized repr~enlative, attach a letter of authorization in accordance Rule 62-620.305, F.A C.
+timothy.powell@fpl.com (Seal, 2
+DEP Form 62-620. 910(9)
+Elrective October 23,.2000}}

L-2016-125, Environmental Protection Plan Report, Minor Permit Revision Request to Use Water Treatment Chemicals, Iww Permit No. FL0002208: Difference between revisions

Latest revision as of 22:01, 9 January 2025

Text

Enclosure:

Dear Mr. Harris:

Enclosures:

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