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//I///Flil izszzz ROCHESTER GAS AND ELECTRIC.lE gyp'ORPORATION o 89 EAST AVENUE, ROCHESTER, N.Y.14649-0001 ROGER W.KOBER VlCC PRCSIDCNT ELECTRIC&STEAM PRODUCTION TCLCPHONC ARcA coDc Tld 546-2700 September 19I 1984 Dr.Thomas E.Murleyi Regional Administrator U.S.Nuclear Regulatory Commission Region I 631 Park Avenue King of Prussiai Pennsylvania 19406  
        //I///Flil   izszzz                                                           gyp'ORPORATION ROCHESTER GAS AND ELECTRIC                                 o 89 EAST AVENUE, ROCHESTER, N.Y. 14649-0001 ROGER W. KOBER VlCC PRCSIDCNT                                                                                       TCLCPHONC ELECTRIC & STEAM PRODUCTION                                                       ARcA coDc Tld           546-2700 September   19I 1984 Dr. Thomas E. Murleyi Regional Administrator U.S. Nuclear Regulatory Commission Region I 631 Park Avenue King of Prussiai                       Pennsylvania   19406


==Subject:==
==Subject:==
Post Accident Sampling System R.E.Ginna Nuclear Power Plant Docket No.50-244  
Post Accident Sampling System R.E. Ginna Nuclear Power Plant Docket No. 50-244


==Dear Mr.Hurley:==
==Dear Mr. Hurley:==
In our letter to you dated June 28I 1984I we explained that the testing of the Post Accident Sampling System (PASS)would be completed by the end of July with the ensuing data evaluation and closeout of the test program to be completed by the end of August.The system testing has been completed successfully with two exceptions.
 
Those exceptions are the determination of dissolved gasses in reactor coolant and the determination of pH in reactor coolant under normal operating conditions.
In our letter to you dated June 28I 1984I we explained that the testing of the Post Accident Sampling System (PASS) would be completed by the end of July with the ensuing data evaluation and closeout of the test program to be completed by the end of August.
Measurement of dissolved hydrogen or gross activity in the coolant is required for determination of core damage and corrosion potential.
The system testing has been completed successfully with two exceptions. Those exceptions are the determination of dissolved gasses in reactor coolant and the determination of pH in reactor coolant under normal operating conditions.
Our design provides for gas sampling by gas stripping and analysis for hydrogen with a gas chromatograph and for gross activity by isotopic analysis.In attempting to determine the dissolved hydrogen in reactor coolant by employing the gas stripping methodi results indicate a repeatability deviation of more than 10%.This is beyond the limits established by NUREG-0737 for dissolved hydrogen.In our test program>we have demonstrated that we can determine total gaseous activity of stripped gas samples taken from the PASS within a factor of 2.We have informed the manufacturer of the system of the test results and he is currently scheduled to be on-site in the near future to evaluate the situation.
Measurement of dissolved hydrogen or gross activity in the coolant is required for determination of core damage and corrosion potential. Our design provides for gas sampling by gas stripping and analysis for hydrogen with a gas chromatograph and for gross activity                       by isotopic analysis.
Until such time that the manufacturer of our PASS can determine the cause for poor dissolved H2 resultsc we propose to rely on a total gas determination.
In attempting to determine the dissolved hydrogen in reactor coolant by employing the gas stripping methodi results indicate a repeatability deviation of more than 10%. This is beyond the limits established by NUREG-0737 for dissolved hydrogen. In our test program> we have demonstrated that we can determine total gaseous activity of stripped gas samples taken from the PASS within a factor of 2. We have informed the manufacturer of the system of the test results and he is currently scheduled to be on-site in the near future to evaluate the situation. Until such time that the manufacturer of our PASS can determine the cause for poor dissolved H2 resultsc we propose to rely on a total gas determination.
8<<<<~o"9 S00024~'~'<091~DZ qDOCX 0 P+)p l.)
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SHEET NO ROCHESTER GAS AND ELECTRIFEORP.
                                                ' ~'<091~
."<;September 19I 1984 Dr.Thomas E.Murley I~Measurement of reactor coolant pH is also required.When test'ing with standard solutions>
DZ P
the monitor is accurate within the requirements of the NUREG 0737.Howeveri when measuring the pH of-'the reactor coolant during normal operationi the PASS monitor does not respond with the required accuracy.Based on testing>our chemists have confirmed that this is due to the low ionic activity of the coolant during normal operation.
                                                                                                                    + )p
During an emergency situation with failed fuel when the PASS must be used due to radiation exposure considerationsi it is expected the ionic activity of coolant would be sufficient to provide accurate pH measurement.
 
Based on comparison of PASS results with laboratory results of other samples>e.g.i boron concentration measurement resultsi we do not believe that the pH measurement discrepancy during normal operation is one of lack of representativeness of the sample.Although we believe the current situation is acceptable based on laboratory analyses of"clean" reactor coolant and PASS analysis of highly radioactive samples>we are continuing to explore this situation with the manufacturer.
l.)
Statistical analyses of the final data are in progressr having been delayed by the difficulties identified above.All analyses>except for the dissolved hydrogen and any that may be required by a change in the pH analysis methodology>
ROCHESTER GAS AND ELECTRIFEORP.                                   SHEET NO
will be complete by October 15.We have also experienced component failures recently.The failure rate has increased as the use of the PASS increases for training purposes and,may also be attributable in part to the developmental nature of the system.A generic problem in the design of a regulating valve for the specific intended function has been identified.
  ." <; September   19I 1984 Dr. Thomas E. Murley I
The manufacturer is supplying repair kits so that the system can be maintained operable and is pursuing other alternatives for this service.e truly yoursr R r W.Kober I O I T7 H~0}}
        ~ Measurement of reactor coolant pH is also required. When test'ing with standard solutions> the monitor is accurate within the requirements of the NUREG 0737. Howeveri when measuring the pH of-'the reactor coolant during normal operationi the PASS monitor does not respond with the required accuracy. Based on testing> our chemists have confirmed that this is due to the low ionic activity of the coolant during normal operation. During an emergency situation with failed fuel when the PASS must be used due to radiation exposure considerationsi       it is expected the ionic activity of coolant would be sufficient to provide accurate pH measurement.     Based on comparison of PASS results with laboratory results of other samples> e.g.i boron concentration measurement resultsi we do not believe that the pH measurement discrepancy during normal operation is one of lack of representativeness of the sample. Although we believe the current situation is acceptable based on laboratory analyses of "clean" reactor coolant and PASS analysis of highly radioactive samples> we are continuing to explore this situation with the manufacturer.
Statistical analyses of the final data are in progressr having been delayed by the difficulties identified above. All analyses> except for the dissolved hydrogen and any that may be required by a change in the pH analysis methodology> will be complete by October 15.
We have also experienced   component failures recently. The failure rate has increased as the use of the PASS increases for training purposes and,may also be attributable in part to the developmental nature of the system. A generic problem in the design of a regulating valve for the specific intended function has been identified. The manufacturer is supplying repair kits so that the system can be maintained operable and is pursuing other alternatives for this service.
e   truly yoursr R   r W. Kober
 
OI T7
  ~0 H
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Revision as of 18:50, 29 October 2019

Submits Evaluation of post-accident Sampling Sys.Sys Testing Completed Successfully W/Exception of Determination of Dissolved Gases in Reactor Coolant & Ph in Reactor Coolant Under Normal Operating Conditions
ML17254A982
Person / Time
Site: Ginna 
Issue date: 09/19/1984
From: Kober R
ROCHESTER GAS & ELECTRIC CORP.
To: Murley T
NRC OFFICE OF INSPECTION & ENFORCEMENT (IE REGION I)
References
RTR-NUREG-0737, RTR-NUREG-737 NUDOCS 8410120179
Download: ML17254A982 (4)


Text

I/ESP

.lE Ill/!gj///I!/ /II///I/t/I//

//I///Flil izszzz gyp'ORPORATION ROCHESTER GAS AND ELECTRIC o 89 EAST AVENUE, ROCHESTER, N.Y. 14649-0001 ROGER W. KOBER VlCC PRCSIDCNT TCLCPHONC ELECTRIC & STEAM PRODUCTION ARcA coDc Tld 546-2700 September 19I 1984 Dr. Thomas E. Murleyi Regional Administrator U.S. Nuclear Regulatory Commission Region I 631 Park Avenue King of Prussiai Pennsylvania 19406

Subject:

Post Accident Sampling System R.E. Ginna Nuclear Power Plant Docket No. 50-244

Dear Mr. Hurley:

In our letter to you dated June 28I 1984I we explained that the testing of the Post Accident Sampling System (PASS) would be completed by the end of July with the ensuing data evaluation and closeout of the test program to be completed by the end of August.

The system testing has been completed successfully with two exceptions. Those exceptions are the determination of dissolved gasses in reactor coolant and the determination of pH in reactor coolant under normal operating conditions.

Measurement of dissolved hydrogen or gross activity in the coolant is required for determination of core damage and corrosion potential. Our design provides for gas sampling by gas stripping and analysis for hydrogen with a gas chromatograph and for gross activity by isotopic analysis.

In attempting to determine the dissolved hydrogen in reactor coolant by employing the gas stripping methodi results indicate a repeatability deviation of more than 10%. This is beyond the limits established by NUREG-0737 for dissolved hydrogen. In our test program> we have demonstrated that we can determine total gaseous activity of stripped gas samples taken from the PASS within a factor of 2. We have informed the manufacturer of the system of the test results and he is currently scheduled to be on-site in the near future to evaluate the situation. Until such time that the manufacturer of our PASS can determine the cause for poor dissolved H2 resultsc we propose to rely on a total gas determination.

8<<<<~o"9 qDOCX 0 S00024~

' ~'<091~

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+ )p

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ROCHESTER GAS AND ELECTRIFEORP. SHEET NO

." <; September 19I 1984 Dr. Thomas E. Murley I

~ Measurement of reactor coolant pH is also required. When test'ing with standard solutions> the monitor is accurate within the requirements of the NUREG 0737. Howeveri when measuring the pH of-'the reactor coolant during normal operationi the PASS monitor does not respond with the required accuracy. Based on testing> our chemists have confirmed that this is due to the low ionic activity of the coolant during normal operation. During an emergency situation with failed fuel when the PASS must be used due to radiation exposure considerationsi it is expected the ionic activity of coolant would be sufficient to provide accurate pH measurement. Based on comparison of PASS results with laboratory results of other samples> e.g.i boron concentration measurement resultsi we do not believe that the pH measurement discrepancy during normal operation is one of lack of representativeness of the sample. Although we believe the current situation is acceptable based on laboratory analyses of "clean" reactor coolant and PASS analysis of highly radioactive samples> we are continuing to explore this situation with the manufacturer.

Statistical analyses of the final data are in progressr having been delayed by the difficulties identified above. All analyses> except for the dissolved hydrogen and any that may be required by a change in the pH analysis methodology> will be complete by October 15.

We have also experienced component failures recently. The failure rate has increased as the use of the PASS increases for training purposes and,may also be attributable in part to the developmental nature of the system. A generic problem in the design of a regulating valve for the specific intended function has been identified. The manufacturer is supplying repair kits so that the system can be maintained operable and is pursuing other alternatives for this service.

e truly yoursr R r W. Kober

OI T7

~0 H

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