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| {{#Wiki_filter:Indiana Michigan Power Company One Summit Square | | {{#Wiki_filter:}} |
| , P.O. Box 60 Fort Wayne, IN 46801 219 425 2111 IItIDIAItIA NICHIGAN CERTIFIED MAIL 4 P 378 90l 729 POWER Mr. J. B. Beauboeuf Waste Management Division Michigan Department of Natural Resources John Hannah Building P. 0. Box 30241 Lansing, MI 48909 March ll, 1994
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| ==Dear Mr. Beauboeuf:==
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| RE: Donald C. Cook Nuclear .Plant Groundwater Discharge Permit Application Enclosed please find a groundwater discharge permit application for the Cook Nuclear Plant located in Bridgman, Michigan, Berrien County. As requested by Mr. Scott Ross during our meeting on November 10, 1993, also enclosed is a study which compares the quality of the effluent from the Turbine Room Sump (TRS) discharge to that of the absorption pond discharge to groundwater. Included with the permit application is a description of the changes scheduled to be made to further reduce the concentrations of impurities discharged into the absorption pond.
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| Please note, also as requested by Mr. Scott Ross, that this application addresses only the Cook Nuclear Plant's discharges to the groundwater. An application for renewal of the NPDES surface water discharge permit MI0005827 will be submitted by April 1, 1994.
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| The attached study indicates the absorption pond provides excellent mixing, with a mixing/dilution factor of approximately 20:1. Furthermore, the actual. water entering the ground meets all of the proposed groundwater effluent limits with the exception of aluminum. The aluminum discharge is the result of the use of aluminum sulfate (alum) as a flocculent in the makeup water plant. The replacement of alum is currently being pursued, as described in Attachment 4.
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| Additional changes planned for the Cook Nuclear Plant will result in further reduction of the concentrations of impurities to the absorption pond. Attachments 1 and 2 describe the makeup plant neutralization system and sequencing batch reactors respectively, which will result in improved effluent water quality.
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| March 11, 1994 Mr. J. B. Beauboeuf Page 2 Attachment 3 is a description of the present zebra mussel
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| -control strategy as it affects the groundwater discharge as well as some of the options being evaluated for future improvements.
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| Attachment 5 is a description of'hemical corrosion control additives which will be used in various plant systems. These additives will be chosen on their reduced environmental toxicity as well as corrosion control performance.
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| Finally, we offer to the agency the following proposals for establishing compliance with the proposed groundwater effluent standards:
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| * We propose to continue compliance monitoring
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| . at the turbine room sump discharge. The absorption pond study has . demonstrated that the water entering the aquifer meets the proposed .groundwater effluent limits for boron, sulfates, sodium, and total dissolved solids. Therefore, we propose a monthly composite sample made up of 24 hour daily composite samples be utilized for compliance monitoring.
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| * We request that aluminum be regulated by total pounds released as proposed by Mr. Ross in our November meeting, rather than by concentration in the absorption pond. The proposed poundage limit is a maximum 125 pounds alum per day.
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| Should you have any questions on the attached material please contact John Carlson, Cook Nuclear Plant Environmental Supervisor, at (616)465-5901 ext. 1153 or me at (219)425-2118.
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| We would be happy to meet with you at your convenience to discuss the application if you believe that would be helpful.
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| Very truly yours, Donald L. Baker Environmental Affairs Director DLB/sdb/046, 042 Enclosure
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| March 11, 1994 Mr. J. B. Beauboeuf Page 3 bc: W. N. D'Onofrio/M. A. Bailey/J. L. Hughey A. A. Blind S. J. Brewer D. M. Fitzgerald/J. P. Carlson E. E. Fitzpatrick D. W. Kemp/K. D. Mack To E. Webb/J. P. Novotny
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| Attachment 1 Makeup Demineralizer Regeneration Waste Neutralization System The Cook Plant is installing a system to collect and treat makeup demineralizer regeneration wastes to meet proposed pH permit limits. The current practice is to isolate the Turbine Room Sump (TRS), accumulate the wastes within the TRS, neutralize the waste with sulfuric acid or sodium hydroxide, then discharge the neutralized contents of the TRS to the Absorption Pond. Because the regeneration wastes are not the only source of water being collected in the TRS, a high water level within the TRS may require the discharge of the sump contents prior to the wastes being completely neutralized.
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| The new system will allow collection and neutralization of the regeneration wastes apart from the TRS. The holding tank for the waste will also be the point of treatment with the capability to add and mix sulfuric acid or sodium hydroxide with the waste prior to metering the neutral mixture to the TRS. The total cost of the Makeup Demineralization Waste System is $ 3,600,000.00.
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| The system is targeted for completion by January of 1995, with system startup to occur thereafter.
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| Attachment 2 Sequencing Batch Reactors The Cook Plant is currently requesting quotations to install a pair of pre-engineered sequencing batch reactors (SBR) to meet the proposed groundwater effluent limits. The new system will operate at a design flow of 50,000 GPD with a maximum flow of 60,000 GPD. The South Extended Aeration Package Plant will be utilized as a retention tank to ensure efficient SBR operation.
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| Effluent from the new system will continue to be discharged into one of the two seepage lagoons. The new system will be installed and operational by December of 1995.
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| Attachment 3 Zebra Mussel Control Strategy Zebra mussels are a menace to any industrial or municipal process drawing water from Lake Michigan. Our current control plan is to chlorinate and perform periodic shock chemical treatments utilizing a proprietary chemical formulation. The Plant has also changed the source water for the fire protection system to a potable supply from Lake Township. This method of control was developed for short term relief from the effects of zebra mussel infestation. Based on over three years experience in dealing with the mussels at Cook Plant and other Great Lakes facilities, a new strategy is being proposed to our corporate management for approval to protect all operations frog infestation.
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| The new strategy incorporates intermittent oxidizing biocide treatments of the circulating water system beginning at the intake structures in Lake Michigan, continuous oxidizing biocide treatment of the essential service water and non-essential service water systems, addition of sodium bisulfite to reduce any residual oxidizing biocide prior to discharge to the lake, and, if necessary, shock treatments utilizing proprietary chemical formulations. The goal of the program is to (1) eradicate existing populations and control further settlement of zebra mussels within the plant systems utilizing lake water, (2) treat the residual oxidant being discharged to non-detectable levels, and (3) reduce or eliminate the number of remedial shock treatments necessary to kill settled colonies of zebra mussels.
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| The resultant zebra mussel control changes will ultimately affect discharges to the Turbine Room Sump from plant systems that are supplied by miscellaneous sealing and cooling water and systems that use non-essential service water that discharge directly to the TRS.
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| Attachment 4 Alum Replacement Program A Chemistry Task Force has been evaluating chemical flocculent replacements for alum (aluminum sulfate). Our corporate management is currently reviewing various flocculents, taking both groundwater effluent standards and reverse osmosis system performance into consideration. The replacements currently being reviewed are mainly polymeric flocculent which will enhance the removal of suspended solids in the pre-filters and meet manufacturer recommendations for the water entering the reverse osmosis system. The recommendations from the task force, once approved, will require additional time to test and implement.
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| The environmental benefit of this review is the reduced amount of aluminum which will be discharged to the groundwater through the Turbine Room Sump discharge. The scheduled target implementation date to use a new flocculent is fovrth quarter of 1994.
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| Attachment 5 Chemistry Corrosion Control Additives The Plant is evaluating substitutes for the current corrosion control additives in the steam generators, plant heating boiler, feedwater and condensate systems, and closed heating/cooling systems. These substitutes will include carbohydrazide, and other available products from chemical companies such as Betz or Nalco. The environmental benefits of these additives include utilization of more benign corrosion control products or products requiring lower effective concentrations. Use of these products will necessitate discharge to the Turbine Room Sump pathway in concentrations to be determined upon effective optimization.
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| Consequently, higher concentrations or iron and other system products can initially be expected.
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| Comparative Study of Turbine Room Sump Discharges and Absorption Pond Water Chemistry Cook Nuclear Plant Groundwater Application February 7, 1994
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| INTRODUCTION A study was conducted to characterize the water quality in the Cook Nuclear Plant Absorption Pond complex prior to discharge into the groundwater. This was at the request of Mr. Scott Ross (Michigan DNR) during our November 1993 meeting in Lansing, MI. The intent of the study was to determine the mixing and dilution effects of the Absorption Pond on discharges from the plant's Turbine Room Sump (TRS). This report presents the results of the study, data analysis, and groundwater implications.
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| Wastewater generated in the plant either drains to the TRS or is pumped to the TRS from localized sumps. The primary sources of wastewater include Makeup Plant demineralizer regenerations, backwashes, floor drains, chemistry lab wastes, various equipment filter and system drains, and non-contact cooling water. Water is collected in the TRS, 'eutralized as necessary, and is periodically discharged to an onsite Absorption Pond complex. The ponds are located approximately 825 feet southeast of the plant (Figure 1).
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| The Absorption Pond complex consists of the original Absorption Pond and an Overflow Pond connected by a 392 foot ditch. The ponds have received an average TRS discharge flow of 301,000 gallons per day during the last six months of plant operation. Both ponds maintain relatively stable water levels with the Absorption Pond overflowing continuously to the downstream Overflow Pond. The pond water entering the ground eventually flows to Lake Michigan based on a 1991 hydrogeology study.
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| MATERIALS AND METHODS'he Absorption Pond study consisted of three stages: 1) a preliminary conductivity survey and pond volume determination, 2) an 18-day comparison of TRS and Absorption Pond water chemistry, and 3) data analysis and report generation. The preliminary conductivity survey was conducted to determine the uniformity of water chemistry within the Absorption Pond and to obtain pond depth readings. The subsequent 18-day study included two Makeup Plant demineralizer regenerations and was conducted with both plant units operating between 70 and 100< power. The second regeneration was "forced" to compress the study time and provide a more conservative evaluation of the effects of regenerations. The amount of acid and caustic used in the regenerations was maintained at normal levels.
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| Page 1 of 20
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| Preliminar Surve A sampling grid was established on the Absorption Pond and Overflow Pond on 40 foot intervals using permanent reference points. At each point, a conductivity measurement was taken at a depth of approximately 1.5 feet using a Hach Model 44600 conductivity meter.
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| Pond depths were also taken at each point using an Impulse Model 4400 depth finder. Additional depth readings were taken around the periphery of the ponds to better develop depth contour maps.
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| The areas of the two ponds were determined using a November 1993 aerial photograph scaled to 1 inch = 660 feet and an electronic planimeter. Ten repetitive measurements were taken on each pond.
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| Average areas were then calculated for the ponds.
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| The volumes of the two ponds and the interconnecting stream were calculated using the depth contour maps and area data. The areas between the depth contour lines were multiplied by the average depth and added to obtain the total pond volumes.
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| 18-Da Stud The study was designed to obtain daily composite samples from the TRS and Absorption Pond complex during a period encompassing two demineralizer regenerations. Samples were collected once per day from the Absorption Pond. The NPDES autocompositor was used to obtain daily TRS composites for the study. Cook Nuclear Plant personnel analyzed the samples for pH and conductivity.
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| Halliburton NUS Environmental Laboratory analyzed the samples for sulfate, chloride, sodium, total dissolved solids, total aluminum, dissolved aluminum, total boron and dissolved boron.
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| Four sample locations were selected to make up the daily composite for the Absorption Pond complex. Two central points were located at 10 foot depths in the Absorption Pond and two central points at two foot depths were located in the Overflow Pond (Figure 2).
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| Tygon tubing was secured at each sample location and run to the pond shores for sampling. Battery operated peristaltic pumps were used to purge and draw the samples. Equal quantities from each point were combined to make up the Absorption Pond composite.
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| A TRS and Absorption Pond study period composite was also analyzed for the above parameters which consisted of equal quantities from the 18 daily composites. The composites were used as checks on the daily analytical data.
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| An additional set of independent grab samples was collected over a 28 hour period during and after the second demineralizer regeneration to provide more detailed data on the event. Grab samples were collected every four hours from the TRS and composite samples (four points) were collected every six hours from the Absorption Pond. The samples were analyzed for conductivity to provide a relative indication of the short-term effects of demineralizer regenerations.
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| Page 2 of 20
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| Data Anal sis and Re ort The data from the study was compared statistically using Systat software. The following comparisons and calculations were performed to evaluate the data and test the validity of the study:
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| -The TRS and Absorption Pond data were compared with proposed groundwater discharge limits to determine be met during demineralizer regenerations.
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| if the limits would
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| -The TRS and Absorption Pond data were compared graphically to ensure the patterns matched mass balance calculations.
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| -Mass balances for selected chemistry parameters were performed including calculated versus actual Absorption Pond value comparisons.
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| -The study data were compared with the NPDES discharge monitoring data from past months to ensure the study was representative of plant operations.
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| Statistical significance is expressed with a percent confidence level and method, when appropriate.
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| RESULTS Preliminar Surve and Pond Volumes Initial conductivity measurements indicated the ponds were mixing uniformly. Conductivities ranged from 310-328 uS in the Absorption Pond and from 340-347 uS in the Overflow Ponds. It was concluded that the TRS discharge plume was mixing very quickly and that the selection of sample points could be based on representing equal areas of the Absorption Pond complex. The four sample points shown in Figure 2 were selected on this basis.
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| Depth readings were obtained at 60 locations in the Absorption Pond and at 15 locations in the Overflow Pond. Depth contour maps were developed from this data for the two ponds (Figures 3 and 4). The maximum measured depth of the Absorption Pond was 19.0 feet and 4.7 feet for the Overflow Pond.
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| Pond surface areas and volumes are shown in Table 1. The total water surface area is 2.21 acres with a combined volume of approximately six million gallons. This provides a daily TRS dilution factor of almost 20:1 based on a 301,000 gpd average flow rate.
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| Page 3 of 20
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| 18 Da Stud The TRS water chemistry remains relatively constant (normal TDS range of 130-170 mg/1) except following Makeup Plant (MUP) demineralizer regenerations. The sulfuric acid and sodium hydroxide used to regenerate the demineralizers sharply increase the sulfate, sodium, conductivity, and TDS levels for approximately 12 hours. The regenerations are conducted on an as needed basis and averaged once per 12 days during the last six months. The trend is toward more infrequent regenerations as operation of the reverse osmosis (RO) unit is refined.
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| Analysis results for the 18 day sampling period for the TRS and Absorption Pond are listed in Table 2. The analysis results for the TRS and Absorption Pond are compared graphically in Figures 5 through 14. Even following demineralizer regenerations, the studied chemistry parameters remained well below the proposed groundwater limits in the Absorption Pond with the exception of dissolved aluminum.
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| The sharp increases in conductivity, sulfate, sodium, boron, and TDS are directly correlated with MUP demineralizer regenerations.
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| The two boron peaks are thought to be due to the release of boron from the cation beds during the regenerations. A Lake Michigan boron level of 83 ug/l was reported in our 1990 NPDES Permit apllication. The amount of boron removed from processing approximately 4-5 million gallons of Lake Michigan water between regenerations would account for the peaks.
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| The dissolved aluminum exceeded or equaled proposed ground water discharge limits in the Absorption Pond on each day; dissolved aluminum values ranged from 50-140 ug/l compared to a limit of 50 ug/l. Aluminum levels in the TRS are elevated due to the use of alum (aluminum sulfate) at an average rate of 300 pounds per week.
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| Higher rates are used during turbid lake conditions.
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| There was excellent correlation between the TRS and Absorption Pond results for all parameters studied. Table 3 lists the multiple correlation coefficients (R~), F-Ratios for the linear regression tests, and significance level (p). In most cases, the probability of the TRS and Absorption Pond chemistry parameters not being related is less than O.l<. The correlation between the TRS and Absorption Pond could be improved slightly by comparing Absorption Pond data one day later than the TRS data ("lagging one day"). This probably reflects the sampling time difference: 1000 hours for the Absorption Pond and 2200 hours for the TRS. This indicates the Absorption Pond data are reliable in assessing the true effects of the TRS on Absorption Pond water chemistry.
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| Page 4 of 20
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| Mass balances were also conducted following the regeneration events to further define the validity of the study. The calculated concentrations for the Absorption Pond following regeneration are reasonably close to the actual concentrations obtained from analysis. The results are presented in Table 4.
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| A more intensive short-term study of the effects of regenerations on TRS and Absorption Pond water chemistry was conducted on January 4-5, 1994. The conductivity results are included in Table 5 and shown graphically in Figure 15. The results indicate that the TRS returns to normal water chemistry approximately 12 hours after the start of a regeneration. The data also indicates that the Absorption Pond mixes very quickly, thereby buffering TRS chemistry spikes.
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| Xn addition to meeting the proposed limits for the TRS discharges, installation of the reverse osmosis (RO) unit has resulted in a marked reduction in levels of groundwater contaminants. Figure 16 illustrates the water quality effects of operating the RO unit to reduce demineralizer regenerations on the TRS and groundwater Well f11, the closest well to the Absorption Pond. As the plant becomes more efficient at operating the Makeup Plant and other improvements are made, we expect this trend to continue.
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| CONCL'USZONS The quality of the Absorption Pond water entering the aquifer was within the proposed groundwater limits for all of the parameters studied except for dissolved aluminum. The aluminum levels were still very low and will be reduced below the 50 ug/1 limit once plans to replace alum as a flocculant are completed. Therefore, the TRS compositor sample can continue to be used for discharge monitoring with assurance that the groundwater limits will be met.
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| Mixing and dilution of TRS discharges with Absorption Pond complex water provided a buffering effect resulting in stable pond water quality even during demineralizer regeneration periods. Other than aluminum, the average concentrations of the chemical parameters studied were equal to or less than 60 percent of the proposed concentration limits. This indicates that. there is' substantial margin against exceedances should plant operating conditions deviate from the normal conditions included in this study.
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| From the trends in groundwater well data over the last year, it is also apparent that the Cook Nuclear Plant has made great strides in improving groundwater discharge quality. We expect this trend to continue with further refinements of our Makeup Plant and installation of the neutralization tank and new sewage treatment facility.
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| Page 5 of 20
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| Table l Pond Volumes and Absorption Areas Area Volume Location Sq. Feet Acres Cu. Feet Gallons Absorption Pond 62,291 1.43 704,606 5,270,453 Overflow Pond 30,056 0.69 85,396 638,762 Connecting Stream 3,920 0.09 3,920 29,321 Total 96,267 2.21 793,922 5,938,536 page 6 of 20
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| Table 2 TRS and Absorption Pond Analytical Results (mg/l)
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| Day'ulfate Sodium Chloride TDS Total-Al Dissol-Al Total-B Dissol-B Cond(uS) pH TRS AP TRS AP TRS AP TRS AP TRS AP TRS AP TRS AP TRS AP TRS AP TRS AP 53 N N 10 N 150 N 0.50 N 0.10 N 0.04 N 0. 05 N 261 N 7.22 N 53 88 6.2 22 10 11 150 200 0.80 0.40 0.07 0.09 0.04 0. 06 0.06 0.06 263 363 7.19 7.2 52 96 4.8 9 11 150 210 0.58 0.20 0.09 0:05 0.06 0.06 0.06 0.07 267 365 7.25 7.2 48 91 4.7 23 10 10 150 220 0.67 0.24 0.19 0.07 0.05 0.06 0.05 0.06 275 372 7.16 7.2 55 90 8.5 23 10 10 160 220 0.89 0.25 0.14 0.14 0.05 0.06 0.05 0.06 265 362 7 26 7 0 85 100 16 24 10 11 170 210 0.90 0.22 0.09 0.15 0.06 0.06 0.06 0.06 281 379 7.08 7.0 49 94 5 5 22 10 11 130 210 1.60 0.26 0.11 <.05 0.06 0.06 0.05 0.06 276 381 6.99 7.1 55 97 8.3 22 11 11 140 200 1.20 0.25 0.16 0.10 0.05 0.06 0.05 0.06 275 376 7 06 7 1 60 92 5.9 23 10 11 140 200 0.75 0.32 0.15 0.06 0.06 0.06 0.03 0.06 287 365 7.60 7.2 480 94 190 23 11 10 740 190 1. 10 0.31 0.09 0.08 0.12 0.06 0.11 0.06 1135 369 7.67 7.1 10 47 110 25 11 10 130 220 0. 91 0.23 0.12 0.08 0.06 0.06 0.05 0.06 269 415 7.44 7.2 51 110 6.3 28 11 11 140 190 0. 97 0.36 0.30 0.07 0.05 0.06 0.05 0.05 303 406 7.42 7.1 12 53 110 28 10 130 210 0.98 0.33 0.30 0.10 0.05 0. 06 0.05 0.06 251 406 7.72 7.4 13 52 110 5.6 30 10 10 130 210 1.60 0.35 0.20 0.10 0.06 0.06 0. 04 0. 06 306 420 7.49 7.6 14 51 100 5.9 31 10 10 140 190 1. 50 0.50 0.30 0.07 0.05 0. 06 0. 06 0. 04 300 425 7.60 7.6 15 47 110 5.5 28 10 10 150 190 1.80 0.50 0.17 0.09 0.05 0. 06 0.05 0.05 303 410 7.30 7.0 16 680 110 260 27 10 10 960 220 0.16 0.27 0.50 0.07 0.09 0.06 0.09 0.06 1700 395 7.18 7.6 17 65 130 14 9 10 160 260 0.61 0.38 0.16 0.20 0.16 0.06 0.15 0.06 284 450 7 19 7 0 18 N 120 N 38 N 10 N 240 N 0.28 N 0.07 N 0.07 N 0.06 N 399 7.16 6.8 Avg. 113 103 31 26 10 10 223 211 0.97 0.31 0.17 0.09 0.06 0.06 0.06 0.06 406 342 7 '0 7.1 350 110 150 29 11 10 600 220 0.66 0.29 0.30 0.08 0.1 0.06 0.11 0.06 989 399 7.16 6.8 Comp Page 7 of 20
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| 0 Table 2 Continued The first TRS sample was collected at approximately 2200 on December 19,1993 (Day 0) . The Day 0 data was included in the Table 3 linear regression model when TRS data was shifted down (lagged) one day.
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| A TRS sample was not collected on the evening of the final day of the study, January 6, 1994.
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| Demineralizer regenerations were conducted on Day 9 (December 28) and Day 16 (January 4).
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| : 2. Study composite samples consisted of combining equal quantities of the daily composites from the have TRS and AP. The much higher than expected analytical results for the TRS composite are believed to been caused by the inadvertent addition of a grab sample during the 28-hour regeneration study.
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| Page 8 of 20
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| Table 5 Regeneration Effects on Conductivity (uS)over a 28-Hour Period Time Abs.Pond 800 263 1000 NA 395 1200 6,820 NA 1600 2,380 470 2000 367 NA 2200 NA 447 2400 195 NA 400 200 436 800 256 NA 1000 NA 445 1200 245 NA
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| : 1. Makeup Plant demineralizer regeneration discharge from the TRS began at approximately 1140 hours on Ol/04/93.
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| Page 11 of 20
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| ~>g<>B 1 - Cook Nuclear Plant, Absorption Pond Complex and WLL
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| Figu1e 2 Absorption Pond and Overflow Pond Sample Locations Absorption Pond Overflow Culvert
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| Connecting Stream (392 feet)
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| /y X = Sample Location P = Pump Location Overflow X Pond P
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| Page 13 of 20
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| Figure 3 - Absorption Pond Depth Contours
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| >'r ro Figure 4 - Overflow Pond Depth Contours 41 Page 14 of 20
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| Figure 5 conductivity 2000 1500 1000 O
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| - LOGAP LOGTRS LOGMAX 0.7 LOGMIN 0 i 2 s 4 s e r e o io ii 12 13 i4 is ie ir ie DAY Page 15 of 20
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| Figure 7 Sul fate 700 600 500 O) 4pp
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| - AP 100 TRS LIMIT 0 1 2 0 4 5 8 1 8 9 10 1'1 12 15 14 15 18 ll 18 OAY Figure 8 sodium 300 200 0
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| ~ ~00 0 1 2 0 4 5 8 7 8 8 10 11 12 18 14 ld 18 17 18
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| - AP TRS LIMIT DAY Page 16 of 20
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| Figure 9 - Chloride 300 200 l
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| - AP TRS LIMIT 0 1 2 Q 4 5 0 1 8 9 10 11 12 18 )4 15 1S ll 18 DAY Figure 10 Total Dissolved Solids 1000 800 600 2
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| 03 P 400 200 - AP TRS LIMIT 0 1 2 0 ~ 5 5 7 6 0 10 11 12 18 14 15 15 11 18 DAY Page,17 of 20
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| Figure 11 - Total Aluminum 2.0 1.5 2
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| i.0 0.5 0.0 0 1 2 5 4 5 5 I 8 9 10 1 1 12 13 14 1$ 15 ll 18
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| - AP TRS DAY Figure 12 Dissolved Aluminum 0.6
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| / NI
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| ~ ef TRS 0.0 LIMIT 0 1 2 5 4 5 5 I 8 9 10 11 12 '5 14 15 15 17 18 DAY Page 18 of 20
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| ]i Figure 13 Total Boron 0.20 0.15 I I
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| I I
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| E i I I 'i I C
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| o 010 I I I O I K I I 'i I
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| I I '\
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| I 0 I 0.05
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| - TRS 0.00 AP 0 i 2 0 ~ s e r s o io ii i2 ie w is ie ir is DAY Figure 14 Dissolved Boron 0.15 I
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| I I
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| I I
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| I I
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| I 0.10 \
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| ~ ~ ~
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| I I
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| C I I
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| Q I 0 I I I
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| CCl I
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| I I I I I oQQ5
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| ~
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| I I
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| 0 O il
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| - TRS AP 0.00 I I I LIMIT 0 i 2 0 4 s d I 8 0 10 ll 12 ls la is ie il 18 DAY Page 19 of 20
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| Figure 15 Effects of Demineralizer Regenerations on TRS and Absorption Pond Conductivity Over a 28-Hour Period 7000 I(
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| I 6000 I I
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| 5000 I I
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| I
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| >, 4000 I I
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| I I O
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| I 3000 I I
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| \
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| O I \
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| 0 I 2000 I I
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| I AP I
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| 1000 I I
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| I 0 4 8 12 16 20 24 28 HOURS Figure 16 Decreases in 1993 Chemistry Parameters for Groundwater Well N11 and the TRS Due to RO Unit Installation and Reduced Regenerations 1500 1000 500
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| "--- "" WELLSO4 1 2 3 4 5 7 10 11 12
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| ------- WELLNA
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| - TRSS04 TRSTDS MONTH Page 20 of 20
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| | |
| r M ID 0'9 86 4 7 62
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| "': SECTION I EPA I.D.NuMSER NUMBER
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| ~ M I 0 0 0 5 8 2 7 1
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| .~ SEENREVERSE
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| 'w INSTRUCTIONS SIDE a
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| rll re APPLICATION FOR DIS HARGE ERMIT I ICOIFIQTICN EXI~IICI NEIf IICREASEO USE REISSUAtCE 5 t'0 0 EI I ND I IC HI GAN 0 WE CO PA
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| ~
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| A. PARENTCOIPANY~CEPTI'ADER"- N M
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| '-- R M lTEM B. DIV./RmU N / A C PLANf OR FACILITY n "
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| O' P K 'P LA NT E STAIOARD IIEXISTRIAL CLASSIFICATION (REFER TO TARE I I I)
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| PHYSICAL 'T M,",,E"L' "C T R IC G E' L44911I LOCATION Fe SlREEf IAISER G, I STREET NVE oe' ADDRESS COOK LAC CllY NA% Ie ZIP CODE ANO
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| 'e RI GMAN Ml 4 6 INFORMATION
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| ~
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| 'e TQIISNIP L K E COe H4%
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| %RIEN CO RISER Le Nt% OF AUIHXI IZED CONTACT PERSON Ne TIllE 0NAL D L BAK ER ENV AFFAIRS IR Oe AIXRESS (IF DIFFEREHf FRII ABOVE) 2 1 9 4.2 5 ~21 1 1 10 E WA YNE ST EET Pe CITY NAIE Oe STAlE Re ZIP CXE o n F 0 T WAYNE 4 680 2 Se lYPE OF TREATIEHT FACILITY Te PRXRAII RNI EFFECTIVE RES IDLNLS IIANG9%Ãf (REFER TO TABLE II)
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| ~1L BACK~ ICIER
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| ~1 ~2 ~3A ~4G 0 YES
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| 'HS 'N.A, DATE SLDNITTED DATE IIPLIIEHIED Ue SOLRCE Ve FOUllfION IIN:ICEHT PREVEHTION PLAN 11/18/92 z DATE SIEHITTED 906 Xe lYPE CF DISCHARGE
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| ~~ Q Ye RI VIXI NAVE A CERTIFIED OPERATCII?
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| D. H. Fete arald El ~
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| e,e,g~atr 9 Cl~ro0+
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| ~49 9 2 ITEM A>> tiVE R MEN GE 2 Bo NA%
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| MAILING ADDRESS OF Ce STREET ABÃE% CR POST OFFICE BOX APPLICANT 1 1 0 E W S REET Do CllY NVE Ee STATE Fe ZIP aXE F ORT W YNE ~IN 4 6802 REOUIRIO SIGNATISIE I the ooollcsnt, <<ertltv under Densltv ot Isv thst I hove oersonsl ly exercised ond soo tsnl lier vlth
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| ~
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| ond ~ I I ottsctveeents ond tn4t, bssed on ov Inoulry ot those Indlvlduols lerooedlotely resoonslble for the Intorsestlon subeoltted In this ooDIIcstlon Inter etio Is true, occur4te 4nd cc slots. I e overs th4t there sre 5lonlflcsnt oenoltl ~ 5 ror subnlttln9 obtslnln9 the Intoetootlon, I believe th4t the DO$ 5lbl I lty ot fine snd Ieaorlsoevoent, tolse Infection, Includln9 the SIGNATURE OF APPLICANT SIGNATURE OF LOCAL GOVERNIIIITAL REPRESENTATIVE (SEE NOTE ON REVERSE SIDE) ch ~/<9( 9'4
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| ~. R. C. Men e >> .,President TITL 15
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| | |
| ~ " ' .v> > ~ \>
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| ( a 2
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| ' m~
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| 'I
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| >j, INSTRUCI'IONS FOR CCMPLETING SECTION I i'r'(> "I l
| |
| .e II ( r "~
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| '" " Th<5 farm requlreS Infcrmat(cn applicant"'and abOut the faClllty addreSS>,di5Charge IOCat(On, Plant COntrOIS, tyPe Of dl5PO5al faCIIltY and name.
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| address, and signature of the 'local'governmental representative.
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| Enter Env(rorvrrental Protection Agency.l Oc Number-')f available. " '-, "-
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| * k 't,Z )
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| t
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| "-"ENTER THE PERMIT N<MBER IN,THE BOX AT"THE TOP OF THIS FORM. THE PERMIT IAIMBER CAN BE FOUNO ON THE FRONT PAGE, OF YOUR EXPIRING
| |
| ', <<c, pERMIT., lf this is,a nev or not previously permitted facility, then leave blank and a number will be asslqned.,
| |
| In the box "Application For Olscharga
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| >y Z C>,
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| Permit Isy check r
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| one of the five categories Increased use, or relssuance) <<hich your permit application falls Into (see page l4(modification, existing unperm(tted> ne<<>
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| for definitions).
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| rr ITEM I PHYSICAL LOCATION AOORESS ANO IUFORMATION r
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| 'A.-C. Enter the naming Information In accordancee with w the following:
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| Z
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| - For Industrial facilities, provide The parent ocmpany name (A.), the division new (8.), and the plant name (c.).
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| r r
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| - For federal and state facilities p'rovlde the department. new (A.), the division,or.,the bureau. name (8.). and the facility new (C.).
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| il
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| - For corrrwrclal facilities provide the owner'5 name, doing-business as <d.b.a.) (A.) and the facility new <C ~ ) ~
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| !" "' O. Enter type of facility. Exeaoles 'of this arec foundry; high school; autarratlc car wash; dry cleaners; f
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| self-serve laundromat.
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| ~~
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| . > E. Refer to Table III (page 5) for the list of Standard Industrial Classification Code <SIC). Enter the code number that best describes the major product or service produced.
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| F.-l. Ehter the PhySICal IOCatlan Of the faCI llty. OO NOT uae POSt Off(Ca bOX nrmrber.
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| J .-K. Enter the township and county In which this feel llty Is located. The county code number can be tound In Table I (page>5) ~
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| Lo-Ro Enter the new, title, address and telephone nrmrber of the facility's authorized contact person. This Derson should be thoroughly ferrl liar vith the facts reported on these forms In the. event that contact regarding the permit appl Ication must be made.
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| Refer to Table II (page 5) for the list of Treatment Facility Types, enter up to five methods used by the facility to treat the wastewater. F 4 '>Mr ''
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| Indicate whether this facility has a "Residuals Management Plan". It so, enter'date plan wa5 submitted and the date tile Plan was or Is to be lmplewnted. Such a plan may be needed as deemed appropriate by. the proper Olvlslon 5taff U. Indicate vhether the waste treatment facilities have a back-up source of paver or whether emergency procedures have been developed In case of a power outage to the waste treatment facility. If the waste treatment feel llty Is not dependent on a source of pover, check the "NA" box.
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| UJ Vo Indicate whether this foci lity has submitted a pollution Incident prevention plan as required under the Michigan water Resources Corrmlsslon Part 5 Rules for the "Spl I lage of Ol I and Polluting Materials".
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| J'f facility has sanitary vastevater (voter used for dawstlc purposes; ~,g. ~ toilets,, slnk5 ~ shover5). enter the nurrrber of people using this facility.
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| X. Check the type of discharge(s) fran this facility.
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| Indicate whether your waste treatment or control facilities are under the supervision of a certified operator. If yes>
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| please provide the Oerson'S new, SOClal security nrmrber, and certificate number plus the ccneany'S feel llty nrmrber.
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| ITEM 2 MAILING AOORESS FOR ALL CORRESPONOENCE A. provide the new of the aDDIIcant. For tha purposes of th)5 apol (cation the applicant Is defined as the Derson signing below In accordance with the directions provided on page ld. Correspondence regarding this permit matters vl I I be sent to the applicant. application and future B. provide the new of the facility, company. or organization which the applicant In "A." above uses for receipt of mall c.~, provide the applicant's address to be used for future correspondence.
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| SIGNATURE OF LOCAL GOVERQCENTAL REPRESENTATIVE NOTE: If sanitary savage Is to be discharged from housing developments, apartment bul ldlngs, centers. or other corrrwrclal developments, Into 5 systerr other than an approved municipal sanitary vesta collection system, shopping this application 5hall be co-signed by an authorized municipal official or township officer.
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| It Is the rule of the Carmlssicn that applications Involving the dl5po5al of sevaoe of human from any entity other than local government should Include the local government as a co-5lgner of the statement, and thatorigin el I proceedlng5 and hearings against said entity <<III Include the local unit of government a5 a party by appropriate notice, and all permits 155ued as 5 re5ult of 5uch hear lngs and proceedings vll I be tIled jointly against the said unit and entity <water Resources ccnmlsslon part 5 Rules R 525.IO)8<5) and the Michigan Water Resources Ccnmlsslon Act 245 P.A. of l929 as amended Section 6<b)). This co-signature requlr<<rent Is only aDDllcable to sanitary sewage discharges and Is not for any nonsanltary waste streams from this facility.
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| | |
| SEE INSTRUCTIONS ON REVERSE SIDE SECTION I PERMIT NUMBER ~ MI ppp5827 A. IXXIICIPAL LAKE TOWNSH I ~ P 3 te e Be QRFACE MATER INTAKE LAEMI C IGA SOURCE OF WATER Ce PRIYAlE NEIL OUANnTY (we.)
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| N A 2 6 5161 60 0 0~
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| SUPPLY auveITY (NAx.)
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| De OlMER N A oIjwrm (we.)
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| ITEM A>> PROCESS MATER aXX.Im MATER)
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| INCLIDI% CONTACT ouANTITY (
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| 6 3 4 40 0 0~DAY Be H3NCONTACT COOLI% MATER 6 4 2 1 1 2 0 0 0 OOANTITY (we.) SAIIDNs/DAY FACILITY Ce SANITARY MATER aewr TY .) 6 0 00 0~DAY WATER USAGE De OTIER F IR E P RO TEC TI ON WTE R 3 6 00 00 0 ~DAY HYDRAZINE ITEM 5 0 0 3020 12 aewrm 6 5 0 0 ~TAEAR CRITICAL MATERIALS CHLORINE SODIUM C PRIORITY 0 7 7 82 50 5 POLLUTANTS USED CLWTITY 357500 t4VK OF SIBSTANCE KYLENE STORED PARA%TER IAPSER 0 1 3 3 02~07 PRODUCED ONNTITY 2 50 0 REFER TOLUENE TO TABLES 0 01088 3 IV&V 1 POUNDS LITHIUM (Lithium H droxide form) 2 GALLONS 3 CUBIC CL'l I
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| IA CLASS02 OOANTITY YARDS 4 TONS HYDROQUINONE PARAIETER IAPSER 0 0 12 3 319 asorllY u/YeR MERCURY L>>It>> CLASS 02 1 OIMIfllY
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| * L~J/YeR x Total quantity unknown, contained in thermometers, barometers and mercoid switches located throughout the plant.
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| | |
| INSTRUCTIONS FOR COMPLETING SECTION I ITEMS 3, 4, AND 5 This form requires Information about the water supply to the feel llty, the feel lltyrs water usage, and crltlcal materials and prlorlty pollutants used, stored, or produced at this feel llty.
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| ENTER THE PERMIT ICMBER IN THE BOX AT THE TOP OF THIS FORM. THE PERMIT NUMBER CAN BE FOUND ON THE FRONT PAGE OF YOUR EXPIRING PERMIT. If this Is a new or not previously permitted feel llty, then leave blank and a number'ill be assigned.
| |
| ITEM 3 SCURCE OF MATER SUPPLY List all water supplies used. The volrmre may be estimated froyr water supply meter readings or from bl lllng statements from a ~ster supply utl llty. If water Is not metered, estimate trcm prmrp capacity. Mhere a name Is required, enter name of water supply; e.g.,
| |
| Mud l.ake, Huron River, or the City of Millpond.
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| ITEM 4 FACILITY MATER USAGE List amounts of water to be used for various purpo5e5 asr Process Mater - see Glossary tor deflnltlon lpage 48).
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| Noncontact Cooling Mater - see Glossary for detlnltlon (page 48).
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| Sanitary Mater - Mater used for dcmestlc purposes; e.g.. toilets, sinks, showers.
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| If water Is first used for'na purpose and the srme ~ster Is subsequently u5ed for one or Inore other purposes ~ Indicate the volrmwr per day ot the Inst designated use betore treatment and/or discharge. For example, If water Is Inltlally used a5 noncontact cooling water end then as process water, the quantity ot ~ster given should be Indicated as process ~ster .
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| The total of Item 4 should equal the total of Item 3. Any difference In these totals should be explained In an attached sheet of this appllcatlon.
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| ITEM 5 CRITICAL MATERIALS ANO PRIORITY POLLUTANTS USED, STORED PRCOUCED List all chemical substances which are In Mlchlgan's Crltlcal Materials Register Table IV lpage 6) and/or U.S. EPA's Prlorlty yet lW t Litt teble y (bee yt tb te e e tly M. t ~. rKd d by tbl ~ teblllty.
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| | |
| SEE INSTRUCTIONS ON REVERSE SIDE SECTION I PERMIT NUMBER ~ MI 0005827 NltlCIPAL ITEM Ae 3
| |
| SOURCE OF ouAttflTY (we.) aulnNs/DAv WATER PRIVAlE MElL SUPPLY ouANTITY (we.) auUINs/DAv oautfITY (we.) aulnNsJ DAY As PROCESS HATER INCLLDIt6 CONfACT tTEM CCOLIm HATER)
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| OOANTITY (r ~DAV t6 4 MINCONTACT CXILI SANITARY HATER HATER txtANTITY (we.) GAllnNS/DAY FACILITY aulnNs/DAv WATER OTIER USAGE (we.)
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| ITFM MERCURIC NITRATE 5 I OOOITITY C L S
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| +W/YEAR CRITICAL NA% OF SISSTANCE MATERIALS MERCURIC SULFATE K
| |
| PRIORITY I QJN PARA%TER tltSER CL SSQ 21 POLLUTANTS x OOANfllv USED NttK OF QSSTANCE CHROMIC ACID STORED C LASS 01 5 PRODUCED L~J/YEAR REFER NAIE OF QBSTANCE CHLOROFORM TO TABLES PARAtETER MJSER 6 3 IVaV Oautf ITY XJ/YEAR NAIE OF QEISTAM:E 1 POUNDS 2 GALLONS 3 CUBIC CL Ql IA PARAtETER MPEIER I C LASS01 7 X oSutf llY WITS YARDS LXI/YEAR 4 TONS PARA%TER MJSER oUutfllY T/m NAtK OF QSSTAtCE S OS PARAIETER MHKR 0 13 32 214 ouANTITY L~J/YEAR
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| " Contained in insulation .throughout plant; believed not to be present in the discharge.
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| 17
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| | |
| INSTRUCTIONS FOR COMPLETING SECTION I ITEMS 3, 4, AND 5 This form requires Information about the ~ater supply to the feel llty, the feel Ilty's water usage, and crit teat materials and prlorlty pollutants used, stored, or produced at thIs faclllty.
| |
| I ENTER THE PERMIT ISMBER IN THE BOX AT THE TOP OF THIS FORM. THE PERMIT NIPRIER CAN BE FCVNO ON THE FRONT PAGE OF YOUR EXPIRING pERHIT. If this Is a new or not previously pen((ltted feel llty, then leave blank and a number will be assigned.
| |
| ITEM 3 SOURCE OF WATER SUPPLY l.lst all water supplies used. The volu((e may be estimated frcm water supply meter readings or frcm bllllng statements from a water supply utlllty. If ~afar Is not metered, estimate from pm((p capacity. where a naee Is required, enter name of ~ater supply; e.g.,
| |
| Mud Lake, Huron River, or the City of Millpond.
| |
| ITEM 4 FACI LITY WATER USAGE List amounts of water to be used for various purposes as:
| |
| Process Water - see Glossary for deflnltlon lpage 48).
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| Noncontact Cooling 'Water - see Glossary for deflnltlon Ipage 48).
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| Sanitary Water - Water used for domestic purposes; e.g., toilets, sinks. showers.
| |
| If ~ater Is first used for one purpose and the sane water Is subsequently* used for one or more other purposes, Indicate the vol(m>>
| |
| per day of the last designated use before treatment and/or discharge, For example, If water Is Inltlally used as noncontact cooling water and then as" process water, the qua'ntlty of water given should be Indicated as process water.
| |
| The total of Item 4 Should equal the total of Item 3. Any difference In these totals should be explained In an attached sheet of this appllcatlon.
| |
| ITEM 5 CRITICAL MATERIALS AND PRIORITY POLLUTANTS USED STORED PRCDUCED List all chemical substances which are ln Mlchlgan's Crltlcal Materials Register Table Iy (page 6) and/or U.S. EpA's Prlorlty Po((ut t (((t T (( V (((((( 7) (( t ( nt(y ~. ( ~. (~ d ((y ((( ((('((((y.
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| ~
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| | |
| SEE INSTRUCTIONS ON REVERSE SIDE SECTION I PERMIT NUMBER ~ Mj pp p5827
| |
| ~EM Ae e'VI I C I PAI.
| |
| ee I I 3 Be SLRFACE 'iJATER IteTAXE IXI>>eIT TY u V GALLOte DAY l~% OF 'ee'TER'eIAV I I i I SOURCE OF ~MITITY "'AX, ) 'eALLCe DAY WATER C~ PRIVATE WELL SUPPLY ".JAIITITv e uM. ) cAt 'te'oAv D. OTnER P>> FV "UAIITITY uAX. ) te'DAv A~ PROCESS WATER (IIJCLtXIIIJS COIITACT ITEiVI B.
| |
| COOL! tlS WATER)
| |
| IIOIICNITACT CCCL I M WATER
| |
| >>LeAeIT I Ve
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| ~ I I I I I i EA' ";JS/DAY QUAeYT I TY (FAX. ) CALLNIS/OAT C, SAIIITARY WATER FAG IL IT Y ".UAIITITY I FAX. )
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| WATER O. OTHER SP<
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| USAGE 4 I >>eIT I TY 'uAX. ) BALI >>>> JS/DAY lIAeZ OF SUBST>>IJCE NICKEL NITRATE
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| )TEM i C L IA S 0 2 2 5 I IeI QUAtlTITY
| |
| .S
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| ~~/YEAR CRITICAL HAtlE OF SUBSTAIJCE MATERIALS ANTIMONY POTASS UM P RID R IT Y Iel Cet I
| |
| PARAMETER tll'BER C LASSO 1 0 OUAIITI TY LLUTANTS
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| 'JSED tA% OF SUBSTANCE STORED PARAIETER tILISER I RODUCED OUAI'llI TY IAI ITS
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| ~/vEAR REFER tIAuE OF SLSSTAIJCE TO TABLES eeETER tllSER I I I I IV&V uttl TS CU "ITI TY
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| ~!YEAR I POUNDS t~ OF SL9STA'XE 2 GALLONS PARAuiPTER te?TSER 3 CUBIC WITS YARDS LJ/vEAR 4 TONS tÃ% OF SUBSTAXCE LIIIO PARAt E TER tlltSER WITS OUUIT I TY
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| ~/YEAR
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| :~uE OF SLSSTÃICE IiIIe PARAMETER Ill~
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| WITS I I I LJ /VEAR 17
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| | |
| I'ISTRUCTIONS FCR CCI~ZLET I NG SECTICII I ITEMS 3, 4, <<ND 5
| |
| ,his !cr . requires infomarlon about !ne water suoplv to the facility, the facility's water <<sage, and critical n'aterlals and prlcrltv pollutants used, stored> cr produced at th,is foci I ltv.
| |
| El)TER ME ogc>>IT 'dJ'cB Q I)I TFE BOX AT TFE CP OF HIS FCFM. ' PERMIT HU'VER CAN BE FOU)d) C" .wE cFONT c"'' OF YOUR EXPIQING li en leave o ianx an 1urper << ' oe assi
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| ' IS IS 0 ew Cr not Prevlc 'sly per<< I ec ~ pl v I ITEM 3
| |
| ""U-rc - NA Q SU""Iv
| |
| .<<ater supplies used. The voluee b'av be esrlnared fron water supoly tater reaclncs c" 'rcn bill(rg s-are,enrs '.rc~ a ware!
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| s
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| :s! all piv ~ I I lry. >5 water Is ror re!epee "ud Lake, riuron River, or the City of Ml llpcnd.
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| ~ es! I are 'n purp capacity. <<here a na e is recui 0c, enter na e o. water supplv: e ~ ~ i I TE>>
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| "ACILITv .CATER 'JSAGE
| |
| :. ourts of <<arer rc oe used for various purposes as:
| |
| Process eater - see Glossary for ceflnltlon (page <<8).
| |
| 'icnccntac! Cooling )rater - see Glossary 'cr deflnltlcn (page c8).
| |
| Sanirarv Rater - 'Aater used for dcresrlc ourooses: e.c., rollers. sinks. snowers.
| |
| <<arer is f irsr used fcr one ourpose anc the sme <<arer ls suosequenrly usec 'cr cne or "cre other purposes, lrclca!e he vclure cer cav C. -he last cesicnarec use before treatrenr and/or cischarce. ccr Rxancie..'atet ~
| |
| s ln(tlal lv used as rcncontact tpci'"c *s!er snc "sn ss prccess '<<a<<er,;he quanri 7 of .<<a!er "ivan s<<pule be inclcatec as:recess <<ater.
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| 'e -tai cf lre<<: -'hould ecual the tora) cf Itw 3. Anv c(fference in these!ctals should =. exolainec Ir an attached sheet of r<<ls cool ication.
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| ITc~a 5 Pl ICAL>>ATERIALS ANO PRIORITY POLLUTANTS USED. S CRED. PPCOLCED List all chenical substances '<<nlch are in Michigan's Critical >>aterlals Register Table IV (page 5) and/or ".. EPA's Priority Fol I>>tant List Table V (page 7) that are currenrlv used, stored, or produced by this foci II tv.
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| | |
| SECTION I MI 0005827 BER~~
| |
| SEE INSTRUCTIONS ON REVERSE SIDE As PROVIDE A BRIEF DESCRIPTION AND LINE DIAGRAH SHXIIID THE HATER FUXI THROXIH YQB FACILITY FR% INTAKE TO DISCHARGEs SHGH ALL OPERATIONS rEM CONTRIBUTING MASTEMATERs INCLUDING PROCESS AtQ PRODUCTION AREAS> SANITARY FLOMSs COOL!% MATERI AND STtA%QTER RIPOFFs YOU HAY GIKXX SIHIIAR OPERATIONS INID A SIIKsLE INITs llew MATER BAlANCE SHXXJj SHXI AVERAGE FLOHS ~ QKH AU. SIGNIFICANT USES CF MATER TO PROOUCTSs ATQSPHREs AND DISCHARGEs YOU SHXLD USE ACTUAL HEASLR9%NTS HIeIEVER AVAIIABLFJ OTKRHISE USE YOLB BEST ESTIIQTEs 6
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| DESCRIPTION (See attached Descriptions)
| |
| DIAGRANI 19
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| | |
| INSTRUCTIONS FOR COMPLETING SECTION I ITEM 6
| |
| )
| |
| This form requires Infomation about the ~ater flow through your facility from Intake to discharge.
| |
| THE PERMIT NWBER CAN BE FOUNO ON THE FRONT PAGE OF YOUR EXISTING ENTER THE PERMIT NUMBER IN THE BOX AT THE TOP OF THIS FORM.
| |
| PERMIT. If this Is a new or not previously permitted facility, then leave blank and a number will be assigned.
| |
| ITEM 6 DESCRIPTION ANO LINE DIAGRAM OF FACILITY'5 PROCESSES ANO TREATMENT SCHEME by ~ater In your facility from the Intake to the discharge and also provide a line drawing.
| |
| A. Briefly describe the route taken Example Description and Oia ram Narrative: The rinse water frcm the various plating operations Is collected ln one of the two 35,000 gallon The water tanks. calcium chloride and alen are added to assist'n fluoride removal and aid In coagulation.
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| Is adJusted to a pH of about 5.5 using dilute sulfuric acid. The pH Is then raised to a pH of about IO.3
| |
| <<lth lime to precipitate the metals as hydroxide. Polymer Is added to f locculate the "sludge". metal hydroxides. The waste stream flows through a clarifier, the metal hydroxide settles to the bottcm as The treated water flows frcm the clarifier to a manhole ~here It ccnmlngles with contact cooling ~ater fran thetostrip line. This ccnmlngled ~ater Is discharged to the Buck River. The sludge frcm the clarifier goes a vacuole filter where It Is dewatered. The sludge Is later taken to a landfill.
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| Calcium Chloride Alum Sul furic Acid Lime Polymer Plating 70.000 Flocculat1on Wastewater Gallon Acidification Neutral izatio Tank Batch Bumps Dump Sludge Clarifier Hon-contact Tank Thickener Cooling Hater Calcium Chloride VacuNa Iiater Filter Alma Sul furic Acid Sludge Hanhol e Gondola Lime Landfill Buck R1ve John Ooe, Inc., Oeertown, manufactures sleeve bearings for autoeotive and truck engines. Production Is divided Into 3 phases. Metal powder ls produced In the first phase. This is acconpanied by melting copper> tin and lead Into Ingots in an electric furnace and applying a Jet of water to quench end solidify the melting metal Into powder form. The second phase consists of adhering the fine metal powder to a coll of steel by passing the tio slowly through furnaces, Water used to cool the strip constitutes the contact cooling water. Bearings are then formed and machined from the coated steel. In the third phase, most bearings receive a nickel strike and lead, tin copper electroplate. The remaining bearings are aluminum or babbitt and receive a tin or lead plate. Rinse water before and after the various plating operations constitutes the process water.
| |
| Huni ci pa 1 Huni ci pal Sanitary Treatment Mater Facility 30,000 gpd Supp'ly Std fsafa ter Str1pe Line Cooling Hater 250,000 gpd Maste Treatment uck R1ve 295.000 gpd Plant 45,000 gpd Powder Hfg. Plating Process 4 000 gpd 40,000 gpd 20
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| | |
| Additional Information Section I Item 6, Subpart A Cook Nuclear Plant Groundwater Permit Application Outfall OOD - Descri tion of Utili Waste Waters Utility waste water from within the plant is discharged into an on-site absorption pond. The ultimate disposition of these waste waters is to the ground which vents to Lake Michigan. The waste waters include:
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| WASTEWATER FLOW DIAGRAM 41 Wastes from the makeup water treatment system. The main contributors to the waste stream are: the makeup plant demineralizer regeneration wastes (avg. 40,000 gallons per regeneration), degasifier pump seal water (108,000 gpd),
| |
| carbon filter backwash water (avg. 45,000 gpd) and pre-filter backwash water (avg. 72,000 gpd). The retention tank periodically discharges a very small volume of solid material removed by settling. Alum (aluminum sulfate) is added to the pre-filter influent as a flocculent. These pre-filters are backwashed to the TRS to remove the suspended matter captured on the filter media. The Alum contained in the backwash is discharged to the TRS in the form of insoluble aluminum hydroxide. Carbon filters are also periodically backwashed to the TRS. These filters primarily remove organics, chlorine and small amounts of iron. Sulfuric acid and sodium hydroxide used by the makeup demineralizers to regenerate the resin are rinsed to the TRS and generally neutralize each other in the sump, forming sodium sulfate prior to discharge. Non-essential service water is used to supply vacuum degasifier pumps which utilize approximately 75 gpm total via two pumps to remove dissolved gases (primarily carbon dioxide and oxygen) from the vacuum degasifier and exhaust them to the atmosphere.
| |
| A new component of the makeup plant, a reverse osmosis (RO) system, has been installed to remove the bulk of the dissolved solids from the lake water prior to demineralization. Normal reject water flow is to Lake Michigan. The RO system must maintain very clean membranes to assure efficient operation and purity of water. Several methods are used to maintain this level of cleanliness from scale and biofouling. Using hydrochloric acid or sulfuric acid, the feed water pH is lowered to reduce the scaling tendencies of the water. Approximately once per month a flush is performed using approximately 0.5% hydrochloric acid and caustic to dissolve any scale that deposits on the membranes (avg. 5000 gallons per month). A chemical cleaning is performed when the periodic acid washes no longer are effective.
| |
| 19a
| |
| | |
| Additional Information Section I Item 6, Subpart A Cook Nuclear Plant Groundwater Permit Application WASTEWATER FLOW DIAGRAM 41 (cont.)
| |
| The chemical cleaning involves several steps and may contain citric acid, hydrochloric acid, phosphoric acid, sodium hydroxide and a neutral pH detergent (avg.
| |
| 10,000 gallons per event). Also, to remove dead biological matter from the membranes, a soak using sodium bisulfite may be performed as necessary, approximately once per year (avg. 5000 gallons per event).
| |
| WASTEWATER FLOW DIAGRAM 42 During periods when not in operation, the heating boiler is stored full of treated boiler water containing at most 400 ppm hydrazine (for oxygen scavenging) and 50 ppm ammonia or 50 ppm ethanolamine (ETA)(for corrosion protection). Prior to use, this "wet lay-up" water is drained to the TRS for discharge into the Absorption Pond. The volume drained is approximately 1600 gallons and may occur 30 times per year.
| |
| During a unit outage, the condensers are checked for leaks by filling the steam'ide with condensate containing approximately, 1000 grams of fluorescein disodium salt or Rhodamine B. These dyes are fluorescent under black light which aids in the detection of joint and tube leaks during visual inspection. The volume of water drained from the condensers ranges from 160,000 up to 1,000,000 gallons and may occur one time per year. In addition, the cooling water side of the condensers are drained to the TRS for general maintenance periodically (8 condenser halves per unit, approximately 25,000 gallons of lake water per half).
| |
| The component cooling water system (CCW) is periodically drained to allow for equipment inspection, maintenance or repair. This system uses demineralized water from the makeup plant as its source of makeup water along with a maximum of 1200 ppm nitrite (from Calgon LCS 60) and 100 ppm glutaraldehyde as treatment chemicals. The infrequent drainings may occur and release approximately 60,000 gallons of treated water to the TRS per year.
| |
| The diesel generator cooling jacket water system(DJW) also employs the same chemical control for corrosion as in the component cooling water system with a maximum of 2000 ppm nitrites from Calgon LCS 60.
| |
| 19b
| |
| | |
| Additional Information Section I Item 6, Subpart A Cook Nuclear Plant Groundwater Permit Application WASTEWATER FLOW DlAGRAM g2 (cont.)
| |
| This system is drained to'the floor drains to the TRS when maintenance is performed on the jacket water system. The system volume is approximately 1000 gallons. Any minor system leaks would also be directed to the floor drain during normal operations.
| |
| The essential service water systems (ESW) and non-essential service water systems (NESW) are also periodically drained to allow for equipment inspection, maintenance, or repair.
| |
| These drains may discharge approximately 72,000 gallons of Lake Michigan water used for non-contact cooling into the TRS. This water is either chlorinated intermittently at a residual concentration of 0.2 mg/1 TRC or continuously at 0.036 ppm total residual chlorine. During some special treatment periods, this water may contain zebra mussel
| |
| ,biocides, used as a molluscicide for zebra mussel control.
| |
| Periodically, components of the ESW or NESW systems may be chemically cleaned to remove iron deposits using vendor supplied cleaning solution such as EDTA (ethylenediaminetetraacetic acid) or ascorbic acid, acetic acid and ammonia. These wastes could either be drained to the TRS or Lake Michigan.
| |
| The steam generators (S/G) are drained for inspection and maintenance during scheduled unit outages (approximately every 18 months) and during an event where steam generator failure is detected that requires a unit shutdown. The steam generators .utilize 150 ppb hydrazine, 20 ppm ammonia, and 2.5 ppm ETA to control the water and steam chemistry to be non-aggressive to cycle components. Unit 1 steam generator also utilizes 10 ppm boron to control corrosion.
| |
| A steam generator volume released during the draining is approximately 32,000 gallons each.
| |
| During wet lay-up the S/Gs are stored full of water with up to 400 ppm of hydrazine and 50 ppm ammonia or ETA are added for corrosion control. This water is normally drained to surface water via NPDES outfalls OOA or OOB, but may be drained to the TRS in some instances.
| |
| The miscellaneous drain tanks can be aligned to discharge to the TRS. As much as 350,000 gallons per day may be directed to the TRS to control the"chemistry limitations on the secondary water systems. Water chemistry is primarily the same as steam generators.
| |
| Around the plant miscellaneous sumps collect approximately 45,000 gpd of water from various equipment drains, leaks, pump seals, steam jet air ejector drains, etc.
| |
| 19c
| |
| | |
| ~9 Additional Information Section I Item 6, Subpart A Cook Nuclear Plant Groundwater Permit Application WASTEWATER FLOW DIAGRAM 42 (cont.)
| |
| The frequency of discharge and types of chemicals used in this equipment have been described elsewhere in this description.
| |
| Miscellaneous floor drains are located throughout the plant to provide a safe working environment by routing spilled or leaked water to the TRS. The major chemical influx into these drains are from the detergents and waxes used to maintain the floors. Also routed to the TRS through the floor drains are the chemical feed tank drains, fire protection water, drinking water, cooling water, and drains from bioboxes used to monitor the zebra mussel control measures and other chemical control monitors. The chemical feed tanks which may be drained contain hydrazine, ammonia, boron, ETA, sodium hypochlorite. The bioboxes will discharge chlorine and, during zebra mussel treatments, zebra mussel biocides.
| |
| Non-radiological chemical lab sink and floor drains are routed to the TRS for disposal. The drains carry water and the wastes generated while performing analyses and preparing laboratory standards including those on the attached list.
| |
| Also discharged will be glassware and normal laboratory cleaning wastes. The average volume directed to the TRS is estimated to be 500-1000 gpd.
| |
| Secondary (steam generator or condensate) sample water from continuous analyzers are routed to drains which discharge to the TRS. The analyzers are on the cycles which may contain as much as 10 ppm boron, 150 ppb hydrazine, 20 ppm ammonia, and 2.5 ppm ethanolamine. The analyzers measure corrosion transport at a average flow of 8500 gallons per day.
| |
| Miscellaneous sealing and cooling water supplies cooling and sealing water to the TRS pumps, condensate booster pumps, circulating water pumps, vacuum priming pumps, drain seal reservoir tanks and drain sample coolers. The average flow per day is approximately 150,000 gallons.
| |
| Non-essential service water supplies approximately 53,000 gpd of non-contact cooling water to various sample coolers throughout the plant's turbine building including the Conductivity Room and the Steam Jet Air Ejector sample points.
| |
| Chemical spills that enter the TRS may be neutralized within the sump to prevent a discharge to the environment. The potential for spills to the TRS exists for the following chemicals with the proposed neutralizers listed: 19d
| |
| | |
| Additional Information Section I Item 6, Subpart A Cook Nuclear Plant Groundwater Permit Application WASTEWATER FLOW DIAGRAM g2 (cont.)
| |
| Chemical Neutralizer Sulfuric acid Sodium hydroxide Sodium hydroxide Sulfuric acid Sodium hypochlorite Sodium thiosulfate Hydrazine NESW (lake water), Hydrogen peroxide Outfall OOE - Sanitar Waste Dischar es WASTEWATER FLOW DIAGRAM 43 Sanitary wastes are presently segregated and routed to two extended aeration package treatment plants. The existing equipment is designed to treat 50,000 GPD and the effluent from the sewage treatment plants discharge into one of the two seepage lagoons. The lagoons discharge into the groundwater with the ultimate disposition being Lake Michigan. The sludge removed from the sedimentation tank basins is taken to a local POTW for disposal or dewatered and stored as low level radioactive waste, as appropriate.
| |
| Plant sanitary waste consists of shower and restroom facilities, janitor washbasins located throughout the plant non-radiological property. Kitchen wastes are generated from the plant cafeteria, the Energy Information Center and Training buildings.
| |
| The chemistry training laboratory discharges to the sewage treatment plants via a limestone bed neutralization tank. The chemistry lab is used to train technicians on analyses performed in the plant. The discharge from the lab carries water and wastes generated while performing analyses and preparing laboratory standards including those on the attached list. A small photo lab in the training building uses (on a emergency basis) small quantities of hydroquinone to develop black and white pictures for plant use. The training building HVAC system also drains to the limestone bed. A radiography lab in the plant also discharges small quantities of processing chemicals for non-destructive testing in the plant. None of the products in the radiography lab contain critical materials or priority pollutants.
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| All portable toilet wastes on the plant site are collected and discharged to the package plants. A biodegradable deodorant is used in the portable toilets. Sludge effluent waste may also be recycled through the plants to decrease the amount of sludge for processing when possible.
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| 19e
| |
| | |
| Additional Information Section I Item 6, Subpart A Cook Nuclear Plant Groundwater Permit Application WASTEWATER FLOW DIAGRAM 43 (cont.)
| |
| Miscellaneous rinsing of waste receptacles and possible miscellaneous cleaning operations waste utilizing various detergents may be rinsed to the sewage treatment plants.
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| Miscellanous Outfall WASTEWATER FLOW DIAGRAM 44 The main plant transformers on each unit are located within concrete berms. The berms are for spill containment should a catastrophic failure of a transformer occur. To protect against operational and safety concerns which stem from ponded water, these areas gravity drain to oil/water separators specific for each unit. Each separator is a below ground concrete basin designed to retain oil and release water to a series of drywells.
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| Also discharging into the separators are the emergency diesel generator pit sumps. These sumps collect limited water and fuel oil (less than 500 gallons per year) from the emergency diesel generator room. Periodically, the oil/water separators are pumped clean to remove the accumulated oil for proper off-site disposal.
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| The Security Diesel Generator Day tank has an overflow line that connects to the Unit One transformer deck catchbasin. Discharge to the catchbasin would only occur if the day tank were overfilled. Procedures and level indicators are used to prevent overfilling.
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| | |
| CHEMICAL LAB ANALYSIS Additional Information Section I Item 6, Subpart A Cook Nuclear Plant Groundwater Permit Application PLANT CHEMISTRY LAB (to Outfall OOD)
| |
| Chloride ASTM D-512-81 (1986)
| |
| Fluoride ASTM D-1179-80 (1986)
| |
| Standard Methods 413 B (1985)
| |
| Hardness ASTM D-1126-80 EPA-600-4-79-020 Method 130.2 (1979)
| |
| Hydrazine ASTM D-1385 (1983)
| |
| Silica ASTM D Power Water Analysis Manual CH-41 Oil 6 Grease EPA-600-4-79-020 Method 413.1 (1979) pH ASTM D-1293-84 Standard Methods 423 (1985)
| |
| Free Mineral Acidity ASTM D-1067-82 Method B Total Phosphorus EPA-600-4-79-020 Method 365.3 (1979)
| |
| Chemical Oxygen Demand EPA-600-4-79-020 Method 410.2 (1979)
| |
| Sulfate ASTM D-516-82 Method A (1985)
| |
| EPA-600-4-79-020 Method 375.3 (1979)
| |
| Standard Methods 426 A (1980)
| |
| Nitrites Determination of Corrosion Inhibition by Calgon Corporation Total Residual Chlorine ASTM D-1253 (1986)
| |
| Standard Methods (1980)
| |
| TRAINING BUILDING LAB'to Outfall OOE)
| |
| Boron Westinghouse Chemical Analysis Procedure for PWR WCAD 7333 Rev. 1 (1973)
| |
| Chloride ASTM D-512-81 (1986)
| |
| Fluoride ASTM D-1179-80 (1986)
| |
| Standard Methods 413 B (1985)
| |
| Haxdness ~ ASTM D-1126-80 EPA-600-4-79-020 Method 130. 2 (1979)
| |
| Hydrazine ASTM D-1385 (1983)
| |
| Silica ASTM Power Water Analysis Manual CH-41 Oil & Grease EPA-600-4-79-020 Method 413.1 (1979) pH ASTM D-1293-84 Standard Methods 423 (1985)
| |
| Total Phosphorus EPA-600-4-79-020 Method 365.3 (1979)
| |
| Atomic Absorption Metals Standard Methods 302B, 303A (1985)
| |
| EPA-600-4-79-020 Method 215.1, 220. 1, 242. 1, 249. 1, 273. 1 (1979)
| |
| Ion Chromatography Dionex System Operators Manual
| |
| | |
| WASTEWATER FLOW DIAGRAMPl 'dditional Information Section I Item 6. Subpart A MAKEUP PLANT Cook Nuclear Plant Groundwater Permit Application Lake Township Non-essential Service Water (Potable Water) (NESW)
| |
| Backwash 2x Day Aug.
| |
| Alum Addition Pre-filter ee e Sodium Hypochlorite (IfNeeded)
| |
| Blow Down I x Day Retention Tank Or As Needed Sulfuric Acid or llydrochloric Acid Addition Reject Water to Lake Michigan Reverse Osmosis 001-002 Acid/Caustic Rinse Chem Cleaning Biofouling Cleaning Backwash 2 x Day Avg Carbon Filter Or As Needed NESW Cation Resin Beds Regeneration water for Waste seals NESW Degasifier ca ater Caustic Anion Resin Beds egene ration tvaste Neutralization Tat)k (Installed by 1-95)
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| Mixed Beds cid/Caustic Regeneration Waste Turbine Room Sump Makeup Plant Water Flow to OOD to Plant Services
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| | |
| 'E WASTEWATER FLOW DIAGRAMP2 Additional Information Section I OUTFALL Item 6, Subpart A 003 Cook nuclear Plant OUTFALL OUTFALL Groundwater Permit Application
| |
| 'ooi
| |
| ~002 Unit 2 Misc. Unit 2 Intake Unit 1 Unit 1 Misc.
| |
| Cooling Discharge Forebay Discharge Cooling I
| |
| I Unit-2 NESW Unit-1 Dye Checks Dye Checks Condenser Condenser i
| |
| Heat Exchangers Sample Coolers Units IP.2 SJAEs Unit-2 Unit-1 ESW ESW Makeup Drains Plant Drains Unit-2 Flow Diagram tt l Unit-1 Cleaning Waste Steam Steam Cleaning Wastes Generator Generator Bioboxes Bioboxes U-2 U-1 CCW CCW In-linc Monitors DJW DJW In-line Monitors Makeup Misc. Drains Plant Plant Misc. Drains Regeneration Heating Layup Drains Wastes Boiler Layup Drains (An.i)
| |
| Chem Feed Misc. Plant Tank Drains Sumps Neutralization Tank Non-rad Barrel Rinse Installed By 1-95 Lab Drains Misc. Floor Drains Turbine Room Sump Sulfuric Sodium Acid pH Meter Hydroxide Auto Compositor Absorption Pond Misc.
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| Processed How Meter Waste e.g. Glycol GROUNDWATER
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| | |
| e WASTE WATER FLOW DIAGRAM83 Additional Information Section I SEWAGE TREATMENT PLANT Item 6, Subpart A Cook Nuclear Plant Groundwater Permit Application Fire Protection (Frusbing and sassing wares is dirccscd so ssorsnwascr Lake Township and/or groundwarcr). Potable Water Supply Plant Site Training Building Training Building Radiograph Sanitary Waste Processing Photo Lab Chemistry Lab HVAC
| |
| & Laboratory Waste Waste System Wastes Kitchen Waste Limestone Bed Neutralization Tank Portable Toilet Wastes North Outfall OOE SeepageTank EIIlucnt East Extended Aeration South Outfall Plant OOE SeepageTank South Miscellaneous Extended Aeration Rinsing Plant Operations l
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| Effluent I gf Procegged)
| |
| Sludge Sludge To a POTW To Groundwater
| |
| | |
| Additional Information Section I Item 6, Subpart A WASTE WATER FLOW DIAGRAM-4 Cook Nuclear Plant DRYWELLS Groundwater Permit Application Unit 1 Unit 1 Unit 2 Security Diesel Main Transformer Main Transformer Unit 2 Generator Day Tank Emergency Generator Emergency Generator Deck Drains Deck Drains Overfiow Pit Sump Pit Sump (Stormwater) (Stormwater)
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| Unit 1 Unit 2 Catchbasin Catchbasin Oil/Water Oil/Water Separator Separator Unit 1 Unit 2 Dwells Dwells GROUNDWATER
| |
| | |
| SEE INSTRUCTIONS SECT1ON I NUMBER
| |
| ~ MI 00058 27 QN REVERSE SIDE EM Ao PROVIDE A ttAP OF THE TREATMENT FACILITY UXATIOtb ON REVERSE SIDE OF PAGEa SCNlt6 Tl% LOCATION OF ~ DISCNARSE POINT(S) AIO OTIER INRR%TICN RGXKSTED 7
| |
| LOCATION (See Attached Map)
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| AIAP 21
| |
| | |
| INSTRUCTIONS FOR COMPLETlt4 SECTION I ITEM 7 This form requires a location map of the treatment facility showing discharge point(s).
| |
| ENTER THE PER4HT NUMBER IN THE BOX AT THE TOP OF THIS FOIa(. THE PERMIT Ias(BER CAN BE FOUNO ON THE FRONT PAGE OF YOUR EXPIRING PERMIT. If thlS IS a new Or nOt PreVIOualy Permitted faCIIlty, then leaVe blank and a number <<III be aSSlgned.
| |
| ITEM 7 LOCATION MAP A. Provide a detailed location man of the treatment facility, showing the location of the discharge point(s) for all surface water and groundwater discharges, and all known supply and drinking water wells of adjacent properties to the facility.
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| For both surface and groundwater discharge applicants, Indicate the location and Identlf Icatlon number of any groundwater monitoring wells relative to the facility which are currently being used by the applicant to monitor the groundwater. Also>
| |
| Include the receiving stream, lake, or storm sewer and the streets and roads In the area.
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| 22
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| | |
| SECTION I W
| |
| NUMBER MZ 0005827 SEE INSTRUCTIONS ON REVERSE SIDE Ae IQ VCU TE A COtCEIIIRATEO ANI FEEDIMI IIIIIQ)
| |
| FJCILI (IF tO CONTItAK TO EM 8 Se MJSBI OF ACRES USED FOI COtFI%I%HT FEKDIMI?
| |
| ~~
| |
| Ce IF 11%RE IS OPEN COIFI%1%NTe HAS A RtMFF DIVERSION AtO CONCEN CONIROL SYSIEN MEN CONSTR'? (IF Mls CONTI'O ITEN 9)
| |
| TRATED WAT IS TI% IESIGN BASIS KR TIE CWiRK SYSTIH? C%CK Ds NK OF 1% RUJRIMI AtO EHIER MJSER OF II&KBOF RAIN?
| |
| lD me, 2II MXR SIOFII e IICI%S ANIMAL FEEDING OPERATION Ee WAT IS TIE MJ%ER OF AQKS OF CONmISUTIMI ERAIQGE?
| |
| Q P OT%R (SPECIFY)
| |
| ~~
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| 25 YEA+ 2II MXR SIORII
| |
| ~
| |
| ~esses s
| |
| ~
| |
| IMIES INC%S F> WAT IS TIE DESIGN SAFEIY FACBXI IOR THIS CONIROL SYSTEI(?
| |
| LJ LJ
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| ~LJ
| |
| ~
| |
| Ae LIST lYPE OF ANINLs N/A LJ Ill ITEIVI 4 Bs GIVE 'D% MJSBI OF 1HIS lYPE OF ANINIL IN OPEN COKIMJ%NTe I
| |
| 9 Ce GIVE ll% MJSER IXtlFI%%NTe OF THIS lYPE OF ANIIVIL IH MXISED As LIST lYPE OF AHINALe TYPE Bs GIVE TI% MISER OF THIS lYPE OF ANItsAL IK OPEN
| |
| %IF ll&%HT e NUMBER OF Cs GIVE TIE MJSER OF THIS lYPE OF ANINL IH MXNED ANIMALS Ae LIST TYPE OF ANINLe IN III OPEN Be GIVE TI% MJSER OF THIS TYPE OF ANINAL IN OPEN 4Iel COIF IMJ%HTe AND I Cs GIVE TI% MJSBI OF lHIS lYPE OF AHULL IN MNSED HOUSED CCtF II8%HTe
| |
| .INE MENT As LIST lYPE OF AHIHALs Be GIVE 11% MJSER OF THIS TYI% OF ANIHAL IN OPEN COtF1%%HTe Ce GIVE TIE MJSER OF 'THIS lYPE OF ANIMAL IN MXSED Ae LIST lYPE OF ANINALe Bs GIVE 1HE MJ%%R OF lHIS lYPE OF ANINAL IN IXsEH CO%1%I%HTs Ce GIVE 11% MJmBI CF THIS lYPE OF ANINL IN INUSED COtF As LIST TYPE OF ANINLe Be GIVE 1% MJ%ER OF 1HIS TYPE OF ANINAL IH OPEN COIF I MJ%NTe Ce GIVE 11% MJSER OF 'THIS 1YPE OF ANINAL IH MNSED CCH'Il&%NTs Ae LIST lYPE OF ANINALe Be GIVE TIE MJSBI OF THIS TYPE OF ANINAL IH QKH Ce GIVE THE MJSER OF THIS 1YPE OF ANINAL IN INUSED CCIF I%t%NTe Ae LIST lYPE OF ANINLs Bs GIVE TI% MJSER OF THIS lYPE OF ANIISL IN 0%N 4IO GXFIIBJ%HTe I
| |
| Ce GIVE 11% MJSKR OF THIS lYPE OF AHINAL IN MXISED COM-1%%HI'e 23
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| | |
| INSTRUCTIONS FOR COMPLETING SECTION I ITEMS 8 ANO 'P.
| |
| This form requires information about the design, size, and type and numbers of animals In a concentrated animal feedlot.
| |
| ENTER THE PERMIT NHBER IN THE BOX AT THE TOP OF THIS FORM. THE PERMIT NIÃBER CAN BE FO(P4) ON THE FRONT PAGE OF YOUR EXPIRING PERMIT. If this Is s new or not previously permitted feel llty, then leave blank and n number vll I be assigned.
| |
| I GENERAL INFORMATION Not all animal feeding operations are required to obtain NpoEs permits. Exclusions are based on sIte and occurrence of discharge.
| |
| In particular, for animal feeding operations, the size cutoffs depend on whether or not pollutants sra discharged through n manmade device or by direct contact <<Ith the facility or animals. A facility for laying hens or brollers Is not required to have a permit unless It hns n liquid manure handling system or continuous overflow watering. Also, facilities which discharge only In the case of n 25 year, 24 hour storm event are not required to have a permit.
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| ITEM 9-8 Give only the ares used for the animal confinement or feeding facility. Oo not Include.sny area used for growing or operating feed.
| |
| ~0 I ITEM 9-C V E Check "Yas" lf sny system for collection of runoff hss been constructed. Supply the Information under 0, E, and F to the best of your knowledge.
| |
| ITEM IO-B ANO C
| |
| 'i to, I'!
| |
| (either partially or total ly) which are Give the maximum nunber of each type of animal In open confinement or housed uri'er roof g
| |
| held nt your facility for s total of 45 days or more In any l2 month period.
| |
| I Use the following categories for type of animals:
| |
| Slaughter Cattle - Lambs
| |
| - Feeder Cattle - Turkeys
| |
| - Mature Dairy Cattle (milked or dry) - Laying Hens I
| |
| - Swine (each weighing over 55 pounds) - Broi lars(
| |
| - Horses Ducks
| |
| - Sheep I
| |
| A permit ls not required unless the facility has s I lquld manure handling system or continuous overflow watering.
| |
| ANIMAL FEEDING OPERATION means a lot or facility (other than an aquatic animal production facility) where tha following conditions are met:
| |
| (A) Animals (other thnn aquatic animals) have been, are, or will be stabled or confined nnd fed or maintained for a total of 45 days or more In any I2 month period) and (8) Crops, vegetation, forage growth, or post-harvest residues ara not sustained in the normal growing season over anY portion of the lot or facility.
| |
| Two or more animal feeding opertlons under cameo ownership nre n single animal feedIng operation lf they adjoin each other or If they use a ccnmon area or system for the disposal of wastes.
| |
| ANIMAL UNIT means a unit of measurement for any animal feeding operation calculated by adding the following nunbersf The number of slaughter and feeder cattle multiplied by 1.0; plus the number of mature dairy cattle multiplied by 1.4; plus the number of swine veighlng over 25 kllogrnms (approximately 55 pounds) multiplied by 0.4; plus the number of sheep multiplied by O.l; plus the number of horses multiplied by 2.0.
| |
| CONCENTRATED ANIMAL FEEDING OPERATION means an animal feeding operation which meets the criteria set forth In either (A) or (8) below or <<hlch the Director designates as such on s case-by-case basis.
| |
| A. More than the nunbers of animals specified In sny of the following categories sre confined (REGARDLESS OF WHETHER A SURFACE WATER DISCHARGE EXISTS):
| |
| t.
| |
| I. I,OOO slaughter or feeder cattle.
| |
| : 2. 700 mature dairy cattle (whether ml lked or dry cows).
| |
| : 3. 2,500 swine each weighing over 25 kllogrnms (approximately 55 pounds).
| |
| : 4. 500 horses.
| |
| : 5. I0,000 Sheep Or lambe.
| |
| 6~ 55,000 turkeys.
| |
| : 7. I00,000 laying hens or boilers (lf the facility has s continuous overflow watering).
| |
| B. 30,000 laying hans or brollers (If the facility has s liquid manure handling system).
| |
| : 9. 5,000 ducks.
| |
| : 10. I,000 animal units.
| |
| following nunbers and types of animals are confined (WITH SURFACE WATER DISCHARGE AS DESCRIBED BELOw':
| |
| B. More than the I. 300 slaughter or feeder cattle.
| |
| 24
| |
| | |
| 2~ 200 mature dairy cattle (whether milked or dry cows).
| |
| : 3. 750 swine each weighing over 25 kllcgroas (approximately 55 pounds).
| |
| : 4. I50 horses.
| |
| : 5. 3,000 Sheep Or lambS.
| |
| : 6. I6,500 turkeys.
| |
| 30,000 laying hens or brollers (if the facility has continuous overflow watering).
| |
| : 8. 9,000 laying hens or brollers (lf the facility has a I)quid manure handling system) ~
| |
| : 9. I,500 ducks.
| |
| IO. 300 animal units.
| |
| "Either one of the following conditions are'mat: pollutants are discharged Into waters of the United States throuch a mamsade ditch, flushing systea or other similar mannada device (wmaenade" means constructed by man and used for the purpose of transporting wastes); or pollutants are discharged directly into waters of the United States <<hlch originate outside of and pass over, across, or through the facility or otherwise ccme Into direct contact <<Ith the animals confined In the operation.
| |
| provided, however, that no animal feeding operation Is a concentrated animal feeding operation as defined above lf such animal feeding operatlcn discharges only In the event of a 25 year, 24 hour storm event.
| |
| N0TE: The permittee shall continue <<Ith Section,ll and address Items I, 2, 4, and 5 on pages 3). 33, and 35.
| |
| | |
| SEE INSTRUCTIONS SECTION I PERMIT
| |
| ~ gg p p p 5827 ON REVERSE SIDE As DO YOU OPERATE AN AXIATIC ANIHAL PRODUCTION FACILITY?
| |
| (IF tfts CCNfltAE TO ITBI 12)
| |
| EM 10 Bs INDICATE TIE TOTAL tAtSER OF PON5s STRÃllRES AT YOlR FACILITYs RACKHAYS AMI SINILAR AO VATIC ANIMAL PRODUTION Cs IN)ICATK IN ltIICH CALENDAR tONIH tVtXItttI FEED1% OCQRIs FACILITY D. MKR Tta TOTAL IANBER OF PlXtKIS OF POCO FKD IXRIm THIS As IS THIS SPECIE A HARN CR tXXD HATER SPECIE?
| |
| g/p tTEM Bs GIVE THE t4VE OF THIS SPECIEs
| |
| 't1 Cs MER TIE TOTAL HARVESTABLE HEIQIT OF THIS SPECIE PRODUCED BY THIS FACILITY PER YEAR IN RXMSs Ds MER TIE HAXItttIHEIGHT PRESENT FOR THIS SPECIE ttIICH HEXAD REPRESENT YMI 8ÃNL OPERATIONs SPECIES As IS THIS SPECK A 1ARH OR COLD I%TER SPECIE OF AQUATIC B>> GIVE TIE WE OF THIS SPECIEs ANIMALS PRODUCED Cs EN1KR TIE TOTAL H4RVESTABLE HEIGHT OF THIS SPECIE AT THIS PRmXD BY THIS FACILITY PER YEAR IN RXtOS>>
| |
| FACILITY De MKR TIE HAXItltIttEIQIT PRESE% RR THIS SPECIE ttIICH HXAD REPRESENT YOUI tOAHAL OPERATIONs A, 15 THIS SPECIE A HARII CR GXD HATER SPECIE?
| |
| g B~ GIVE TIE NA% OF THIS SPECIEs Vn Cs MKR THE TOTAL NRVESTABLE NEIQIT OF THIS SPECIE F
| |
| Ds ENIER THE tVUUtttt HEIGHT PRESENT FOR THIS SPECIE ISICH ICXU) REPRESENT VOIR NXHAL CPERATI ONs As IS THIS SPECIE A HARII OR CXD HATKR SPECIE?
| |
| Bs GIVE TIE NttE OF THIS SPECIEs Cs ENIKR TIE TOTAL HARVESTABIE HEIGNf OF THIS SPECIE PtmXH) BY THIS FACILITY PER YEIR IN POQOSe Ds ENIKR TIE HAXI tM HEIGHT PRKSBIf FCR THIS SPECIE ttIICH lORD RERIESENT YON tCNNL OPERAT ION s As IS THIS SPKIE A HARtl CR COLD HATER SPECIE?
| |
| Bs GIVE TIE N4% OF 'THIS SPECIEs Ce MKR THE TOTAL NRVESTABLE HEIGHT OF THIS SPECIE PRQOUCED BY THIS FACILITY PER YEAR IN Pres Ds EHIKR TIE HAXIt%M IEIGHT PRESENT FCR THIS SPECIE tSIOI lORD REPRESENT YQR tCÃNAL OPERATIQls Ae IS THIS SPECIE A HAttI OR OXD HATER SPECIE?
| |
| Bs GIVE TIE HttK OF THIS SPECIEs Cs ENfKR T% TOTAL tVUIVESTABLE HEIGHT OF THIS SPECIE PRCQXED BY TH S FAC TY Y N Ds ENTER TIE HLYItttt NEIGHf PRESENf FCR THIS SPECIE tttICH MXAD REPRESENT YNR tCRPAL OPKRATIONe
| |
| | |
| INSTRUCTIONS FOR CCMPLETING SECTION I ITEMS 10 ANO I I This form requires infq{mation about the design, size, and type and numbers of animals In an aquatic an'al production feel ll y.
| |
| ENTER THE PERMIT NIA{BER IN THE BQX AT THE TOP OF THIS FORM THE PERMIT NIPBER CAN BE FOUND ON THE FRONT PAGE OF YOUR EXoIRING PFRMIT. If thlS IS a new Or nOt preVIOuSly pe{mitted faClllty, then leaVe blank and a nunber Will be aSSigned.
| |
| GENERAL INFORMATION Not ail fish farmsare required to obtain NPOES permits. Exclusions are based on size and occurrence of discharge. For aquatic animal production facilities, the size cutoff5 are based on whether the species are wa{m ~ater or cold water, on the production weight per year In harVeStabie POundS, and On the Zmqunt Of feeding In paundS Of fOOd IfOr COld ~ater 5Pecie5). AISO faCI litleS
| |
| ~
| |
| which discharge less than 30 days per year, or only durlno periods of excess runoff I for warm ~ater fish) are not required to have a permit.
| |
| coNcENTRATEQ AQUATlc ANIMAL pRQQUOTIQN FAQII,ITY means a hatcnery, tish fern, or other facility which contains, grows or holds aquatic animals In either Of the following cateaorles, or which the Director desianates as such on a ca5e-by-case ba515 ~
| |
| A. Cold water fish species or other cold ~ater aquatic animals Including, but not limited to, the Salmonidae family ot fish Ie.g.. trout and salmon) In ponds, raceways or other similar structures ~bleb discharge at least 30 days per Year but doe5 not Include:
| |
| I.. Facilities which produce less than 9,090 harvest ~eight kllograms Iapproxlmateiy 20,000 pounds) ot aquatic animals per year.
| |
| 2., Facilities which feed less than 2,272 kllograms (approximately 5,0QQ pounds) ot food during the calendar month ot maximum feeding.
| |
| B. Harm ~ater fish species or other warm water aquatic animals Including, but not limited to, the Amelurldae, Cet{achldae, and Cyprlnldae families ot fish (e.g., respectlveiy, catfish, sunfish, and minnows) In ponds, raceways, or other similar StruCtureS whlCh diSCharge at leaat 30 daya per year, but dOeS nat InClude:
| |
| I. Closed ponds which discharge only during periods ot excess runoff.
| |
| : 2. Facilities which produce less than 45,454 harvest weight kllog{ams {approximately 100,000 pounds) of aquatic animals per yea{',
| |
| ITEN 10 B Give the total nunber of discrete ponds or raceways In your facility.. Under "other" give a descriptive name of any structure which 15 not a pond or a raceway but which results In discharge to waters of the United States.
| |
| ITEN 10-D The value gIven for maximum monthly pounds of food should be representative of your normal operation.
| |
| ITEN 11 8 The name of fish species should be proper, c{mtnon, or scientific names.
| |
| ITEN Il C AND D The values given tor total ~eight produced by your facility per year and the maximum ~eight present at any one time should be representative of your normal operation.
| |
| NOTE: The permittee shall continue with Section II and address Items I, 2, 4, and 5 on pages 31, 33, and 35.
| |
| 28
| |
| | |
| SECTION t MI 0005827 LIST NAHE AND HAILING ADDRESS OF ALL PROPERTY $ 4ERS ALIACENT TO TIE TREATMENT FACII.ITY AND OR DISC%ROE/DISPOSAL AREAs i TEM 12 See attached list.
| |
| MAILING LIST OF ADJACENT PROPERTY OWNERS 29
| |
| | |
| SO MI0005827 Section I, Item 12 ADJACENT PROPERTY OWNERS EAST Interstate I-94 (Michigan Dept. of State Highways)
| |
| SOUTH Lake Township c/o Gerald Wasko Township Supervisor 1410 Shawnee Road Bridgman, MI 49106 WEST Lake Michigan (State of Michigan and United States of America)
| |
| NORTH Rosemary Beach 11-11-6800 0038-00-5 Tengerstrom, Eric H.; 3415 S. 59th; Cicero, IL 60650 0037-02-5 Tengerstrom, Eric H.; 3415 S. 59th; Cicero, IL 60650 0037-01-7 Merkel's Floor Covering, Inc.; 8314 Scottdale Rd.; Berrien Springs, MI 49103 0037-00-9 Kraiss, Wilbur & Marilou; 5004 S. Long Ave.; Chicago, IL 60638 I
| |
| 0036-00-2 Temmel, Edward P. & Kathleen; 9617 E.
| |
| Shore Dr.; Oak Lawn, IL 60453 0033-00-3 Gilpin, Clark & Nancy; 1005 E. 60th St.;
| |
| Chicago, IL 60637 0032-01-'5 Wittebort, Robert J., Jr. & Nancy H.;
| |
| 3180 N. Lakeshore Dr.; Chicago, IL 60657 0030-02-1 Meier, Paul & Louise G.; 1357 Madison Park; Chicago, IL 60615 0028-01-8 Balka, Ronald A. & Janet M.; 3334 Louise Dr.; Lansing, IL 60438
| |
| | |
| Section I, Item 12 ADJACENT PROPERTY OWNERS Page 2 11-110006 0002-03 Michigan Dept. of Natural Resources; P.O. Box 30028; Lansing, MI 48909 0004-00 Franklin Real Estate Co.; P.O. Box 2000; St. Joseph, MI 49085 0004-04 Temmel, Edward P.; 9617 E. Shore Dr.; Oak Lawn, IL 60453 0004-01 Caparo, William E. 6 Oyler, Kathryn E.;
| |
| 122 S. Ellsworth Pl.; South Bend, IN 46635 0004-02 Rosemary Beach Corp.; c/o Secretary; 3415 S. 59th St.; Cicero, IL 60650 11-11-0007 0013-00 Lake Charter Twp.; Shawnee Rd.; Bridgman, MI 49106 0013-01 Lake Charter Twp.; Shawnee Rd.; Bridgman, MI 49106 0006-01 Indiana Michigan Power Company 0001-01 Lake Charter Twp.; Shawnee Rd.; Bridgman, MI 49106 0004-01 Lake Charter Twp.; Shawnee Rd.; Bridgman, MI 49106 11-11-0005 0029 Technisand, Inc.; 11833 Ravenna Rd.;
| |
| Chardon, OH 44024 0036-01 Ruff, Timothy W.; P.O. Box 504 Bridgman, MI 49106 0027-00 Technisand, Inc.; 11833 Ravenna Rd.;
| |
| Chardon, OH 44024 0036-00 Emery, Martin; Hopkins, Elwood J. & Mable N.; 7499 Thornton Dr.; Stevensville, MI 49127 0036-02 Indiana Michigan Power Company 11-11-0005-0002 01-6 Bank of America Texas P.O. Box 650380 Dallas, TX 75265 11-11-0008 0041-00 Michigan Dept. of Transportation; Lansing, MI 48900 0009-00 Franklin Real Estate Co.; P.O. Box 2000; St. Joseph, MI 49085
| |
| | |
| (~ iQ Ii NARSULEX, MATERlALSAFETY DATA SHEET
| |
| 'xQ Sulfuric Acid
| |
| : 1. PRODUCT AND COMPANY IDENTIFICATION
| |
| . Product Name: Sulfuric Acid Formui: H,SO, Molec War Weight: 98.08 Chemical Name: Sulfuric Acid ghemlcai Family: Inorganic Acid ~Su 7664-93-9
| |
| ~Synonyms: Sulphuric Acid, Oil of Vitriol, Battery Acid product Use: Used tn manufacture of fertilizers, explosives, other acids, metal pickling and petroleum processing.
| |
| MARSULEX inc. MARSULEX Inc.
| |
| 111 Gordon Baker Road 40 Richards Avenue EMERGENCY TELEPHONE NUMBER Suite 300 P.O. Box 5453 orth York, ONT Nofwalk, CT (800) 263-9502 M2H 3R1 06856-5453 (416) 496-9655 (203) 8544300 Prepared by MARSULEX Technical Section (416) 496-4164.
| |
| : 2. COMPOSITION/INFORMATION ON INGREDIENTS
| |
| % by Wt. CAS Number
| |
| - Sulfuric Acid 70-100% 7664-93-9 N n- I nt Water OM% 7732-186
| |
| : 3. HA2'ARD INFORMATION EMERGENCY OVERVIEW:
| |
| /Oangerl Extremely corrosive. Causes severe burns. Reacts violently with water. Highly reactive and capable of igniting combustible materials on contact. Not flammable, but reacts with most metals to form explosive hydrogen gas.
| |
| /Sulfuric Ackl h a colorless to amber, dear to slightly cloudy, oily liquid.
| |
| National Rre Protection Assochtlon (NFPA) Rating Hazardous Materials Identification System (HMIS) Rating 4 Extreme/Severe
| |
| '3 High/Serous
| |
| ~ 2 Moderate RRE f 0 1 = Slight 0 = Minimum W Water Reactive ectNe Date: Februay, 1993 MARSULEX MSOS 4010E
| |
| . Supefaedea: Februasy, 1990 Page 1 of 9
| |
| | |
| MATERIALSAFETY DATA'SHEET, Sulfuric Acid
| |
| : 3. HAZARD INFORMATtON (continued)
| |
| POTENTIAL HEALTH EFFECTS:
| |
| Exposure Llmlts:
| |
| ACGIH (TLV) OSHA (PEL)
| |
| Sulfuric Acid 1 mg/m'TWA) 1 mg/8 (TWA) 3 mg/m'STEL)
| |
| In contact with the skin: Concentrated solution may cause pain and severe burns to the skin and brownish or yellow stains. Prolonged and repeated exposure to dilute solutions may cause irritation, redness, paIn and drying and cracking of the skin.
| |
| ln contact with the eyes: Immediate paIn, severe burns and corneal damage which may result in blindness.
| |
| C Inhaled: Mists and vapors may cause Irritation of the eyes, nose and respiratory tract. May cause Increased
| |
| 'ulmonary resistance, transient cough and bronchoconstrlctlon. Severe overexposure may result In lung collapse and pulmonary edema which can be fatal.
| |
| Ingested: Severe burning and pain In the mouth, throat and abdomen. Vomiting, diarrhea and perforation of the esophagus and stomach lining may occur.
| |
| Long Term Exposure:
| |
| , Repeated exposure may produce erosion and discoloration of teeth.
| |
| ~l'lthough no direct link has been established between exposure to sulfuric acid, Itself, and cancer In man, the World Health Organization (WHO) International Agency for Research on Cancer (IARC) have concluded that occupational exposure to strong Inorganic acid mists containing sulfuric acid is carcinogenic to man, causing cancer of the larynx (the voice box) and, to a lesser extent, the lung. Exposure to any mist or aerosol during the use of this product should be avokied and, in any case, keep exposures below the occupational exposure limit for sulfuric acid.
| |
| 1 Corrosive effects on the skin and eyes may be delayed, and damage may occur without the sensation or onset of pain. Repeated overexposure may lead to contact dermatitis, may cause bronchitis with cough, phlegm, shortness of breath and emphysema, can cause chronic runny nose, tearing of the eyes, nosebleeds and stomach upsets. Strict adherence to first aid measures following any exposure Is essential.
| |
| Existing Medical Conditions Possibly Aggravated By Exposure: Skin Irritation may be aggravated in Individuals with existing skin lesions. Breathing of vapors or sprays. (mists) may aggravate acute or chronic asthma and chronic pulmonary disease such as emphysema and bronchitis.
| |
| Carcinogenicity Data: Although there are reports linking exposure to sulfuric acid to cancer, this product Is not classified by NTP (National Toxicology Program), not regulated as carcinogenic by OSHA (Occupational Safety and Health Administration), and has not been evaluated by IARC (International Agency for Research on Cancer) or ACGIH (American Conference of Governmental Industrial Hyglenlsts). (See also, Long Term Exposure).
| |
| MARSULEX MSDS k010E Effective Date: February, 1993 Page 2of 9 Supersedes: February, 1990
| |
| | |
| NATU LEX, MATERIALSAFETY DATA SHEET Sulfuric Acid
| |
| : 4. FlRST AID MEASURES Prompt removal of this material from contact with the body is of utmost importance.
| |
| &TART FIRST AID AT ONCE.
| |
| Precaution: Persons attending the victim should avoid direct contact with heavily contaminated clothing and vomitus. Wear impervious gloves while decontaminating skin and hair.
| |
| In contact with the skin: Flush skin with running water for a minimum of 20 minutes. Start flushing while removing g contaminated clothing. If irritation persists, repeat flushing. Obtain medical attention IMMEDIATELY. Do not transport victim unless the recommended flushing period is completed or flushing can be continued during
| |
| , transport.
| |
| a, While the patient Is being transported to a medical facility, apply compresses of Iced water. If medical treatment must be delayed, Immerse the affected area in iced water. If immersion is not practical, compresses of Iced water can be applied. Avoid freezing tissues.
| |
| Discard heavily contaminated clothing and shoes ln a manner which limits further exposure. Otherwise, wash clothing separately before reuse.
| |
| ln contact with the eyes: Immediately flush eyes with running water for a minimum of 20 minutes. Hold eyelids open during flushing. If Irritation persists, repeat flushing. Obtain medical attention IMMEDIATELY.Do not transport
| |
| ~ ~ victim until the recommended flushing period Is completed unless flushing can be continued during transport.
| |
| Inhaled: Move victim to fresh air. Give artmclal respiration ONLY If breathIng has stopped. Give Cardiopulmonary flesuscltatlon (CPR) If there ls no breathing AND no pulse. Obtain rnedlcal attention IMMEDIATELY.
| |
| Ingested: If victim ls alert and not convulsing, rinse mouth and give N to 1 glass of water to dilute materhl. If spontaneous vomiting occurs, have victim lean forward with head down to avoid breathing ln of vomitus, rinse f mouth and administer more water. IMMEDIATELYcontact local poison control center. Vomiting may need to be Induced but should be directed by a physician or a poison control center. IMMEDIATELYtransport victim to an emergency facility.
| |
| Note to Physician: All treatments should be based on observed signs and symptoms of distress in the patient.
| |
| Medical conditions that may be aggravated by exposure indude asthma, bronchitis, emphysema and other lung diseases and chronic nose, sinus or throat conditions. Severity of the bum is generally determined by the concentration of the solution and the duration of exposure. In the event of skin or eye contact, lmmedhte and thorough flushing is essential. Continued washing of the effected area with cold or iced water will be helpful in removing the last traces of sulfuric acid. Cream or ointments should not be applied before or during the washing phase of the treatment.
| |
| : 5. FIRE FtGHTING MEASURES F sh Point (method): Not applicable, product Is non-flammable utolgnltlon Temperature: Not combustible Rammabllity Limits In air(%): UEL Not applicable LEL Not applicable MARSULEX MSDS fffetOE Effective Date: February, 1993 Page 3 of 9 Superaed ea: February, 1990
| |
| | |
| MATERIALSAFEIY DATASHEET Sulfuric Acid
| |
| : 5. FIRE FIGHTING MEASURES (continued)
| |
| Fire Extinguishing Media: For small fires use dry chemical or carbon dioxide. For large Ares, flood fire area with water from a distance. Expect violent reaction with water. Do not get solid stream of water on spilled material.
| |
| Special Fire Fighting Procedures: Wear a NIOSH/MSHA approved selfwontalned breathing apparatus If vapors or mists are present and full protective clothing. For fighting fires In close proximity to spill or vapors, use acid-resistant personal protective equipment. Evacuate residents who are downwind of Are. Prevent unauthorized entry to Are area, Dike area to contain runoff and prevent contamination of water sources. Neutralize runoff with lime, soda ash or other suitable neutralizing agents (see Deactivating Chemicals, Section 6). Cool containers that are exposed to flame with streams of water until fire is out.
| |
| Other Fire or Explosion Hazards: Not flammable but highly reactive. Capable of igniting finely divkled combustible materhls on contact. Reacts violently with water and organic materials with evolution of heat. Extremely hazardous
| |
| .~ in contact with many materials, particularly carbides, chlorates, fulmlnates, nltrates and picrates. Sulfuric acid reacts with most metals, especially when dilute to give flammable, potentially explosive hydrogen gas. Hydrogen gas can accumulate to explosive concentrations inside confined spaces. Follow approprhte NFPA codes.
| |
| : 6. ACCIDENTALRELEASE MEASURES Steps to be taken In the event of a spill or leak: Remove all ignition sources. Ventilate area. Use appropriate Personal Protection Equipment. Prevent liquid from entering sewers or watetways. Dike with inert material (sand, earth, etc.). Stop or reduce leak if safe to do so. Collect Into containers for reclamation or disposal only if container
| |
| ~r (s suitable to withstand the material. Conskler lnsitu neutralization and disposal. Ensure adequate decontamination of tools and equipment following dean up. Comply with Federal, Provincial/State and local regulations on reporting releases. =: "
| |
| Deactivating Chemicals: Ume, limestone, sodium carbonate (soda ash), sodium bicarbonate, dilute sodium
| |
| 'hydroxide, dilute aqua ammonia.
| |
| Waste Disposal Methods: Dispose of waste material at an approved waste treatment/disposal facility, In accordance with applicable regulations. Do not dispose of waste with normal garbage or to sewer systems.
| |
| Note - Clean-up material may be a RCRA Hazardous Waste on disposal.
| |
| .-'Spills are subject to CERCLA reporting requirements: RQ = 1000 lbs.
| |
| : 7. HANDLING AND STORAGE Precautions: Wear appropriate Personal Protection Equipment. Do not breath sprays or mists. Do not Ingest. Do not get In eyes, on skin or on clothing. Keep ignition sources away from sulfuric acid storage, handling and transportation equipment.
| |
| Handling Procedures and Equipment: Carbon steel or stainless steel materials are suitable for use for acid concentrations equal to or greater than 93%. However, the effect of lower concentrations on the materhls of construction can be very complex. Contact product supplier for specific recommendatlons when handling sulfuric acid at strengths less than 77%.
| |
| Effective Oate: February, 1993 MARSULEX MSDS 4010E Supersedes: February, 1990 Page 4 of 9
| |
| | |
| NAILciULKK... MATERIALSAFETY DATA SHEET Sulfuric Acid
| |
| : 7. HANDLINGAND STORAGE (continued)
| |
| Storage Temperature: Store above freezing point (Section 9). Elevated temperatures will Increase the corrosion
| |
| / rate of most metals.
| |
| Storage Requirements: Store packaged acid in a dry, well, ventilated location away from combustibles, oxkllzers, bases, or metallic powders. Storage tanks should be protected from water ingress, be well ventilated, and
| |
| 'aintained structurally in a safe and reliable condition.
| |
| Other Precautions: Sulfuric acid will attack some forms of plastics and coatings. Always add acid to water - not g water to acid. If kept In upper floors of building, floors should be ackl proof with drains to a recovery tank.
| |
| : 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
| |
| -'Recommendatlons listed in this section Indicate the type of equipment which will provkle protection against over exposure to this product Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific protective devices at your workplace.
| |
| Engineering Controls: Local exhaust ventilation required.
| |
| spiratory Protection: A NIOSH/MSHA approved air-purifying respirator equipped with acid gas/fume, dust, mist cartridges for concentrations up to 10 mg/nf'. An air-supplied respirator if concentrations are higher or unknown.
| |
| S)tin Protection: impervious (l.e., neoprene, PVC) gloves, coveralls, boots and/or other acid resistant protective
| |
| ~clothing.
| |
| /Eye Protection: Tight-fitting chemical goggles and face shield.
| |
| Other Personal Protective Equipment: Where there is a danger of spilling or splashing, acid resistant aprons or suits should be worn. Trouser legs should be worn outside (not tucked in) rubber boots. Safety showers and
| |
| ~ eyewash fountains should be Installed in storage and handling areas.
| |
| : 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Llqukf Appearance and Odor. Sulfuric acid Is a clear to amber, heavy, oily liquid which may have a sharp penetrating odor.
| |
| .Odor Threshold: No data Boiling Point: 77.67%:193'C(380'F); 93.19%: 276'C (529'F); 98%: 330'C (626'F)
| |
| Melting/Freezing Point: 77.67%: -11.2'C (+11.6'F); 93.19%: -29.5'C (-21.1'F); 98%: -1.1'C (30'F) h Vapor Pressure at 40'C (102'F): 77.67%: 1.2 mmHg; 93.19%: 0.0016 mmHg; 98%:.0.002 mmHg Specific Gravity at 16'C (60'F): 77.67%: 1.7059; 93.19%: 1.8354; 98%: 1.8437 Vapor Density: (Air=1): 3.4 sulfuric acid component Bulk Density: Not applicable (see specific gravity) ffecthre Date: February, 1993 MARSULEX MSDS 401 OE Supersede@ February, 1990 Page 5 of 9
| |
| | |
| MATERIALSAFETY DATA SHEET Sulfuric Acid
| |
| : 9. PHYSICAL AND CHEMICAL PROPERTIES (continued)
| |
| Evaporation Rate: Not applicable
| |
| /
| |
| ~. Solubility: Miscible In all proportions In water. Also soluble in alcohol.
| |
| pH: 0.3 (1N solution at 25'C/78'F)
| |
| : 10. STABILITYAND REACTIVITY Stability:
| |
| .~ Under Normal Conditions: Stable, but reacts violently with water and organic materials with evolution of heat.
| |
| Under Fire Conditions: Decomposes to form sulfur oxides(SQ).
| |
| Conditions to Avoid: Temperatures which may have a negative effect on the materials of construction used ln equipment.
| |
| Materials to Avoid: Contact with organic materials (such as chlorates, carbldes, fulmlnates and plcrates) may cause
| |
| , fire and expiosions. Contact with metals may produce flammable hydrogen gas. When diluting, add acid to water.
| |
| Do NOT add water to the acid.
| |
| n Hazardous Decomposltlon or Combustion Products: Toxic gases and vapors (e.g. sulfur dioxide, sulfuric acid
| |
| ; vapors/mists and sulfur trloxkfe) may be released when sulfuric acid decomposes.
| |
| Hazardous Polymerization: WIII not occur
| |
| : 11. TOXICOLOGICALINFORMATION Toxicological Data: . Lox, (oral, rat) 2140 mg/kg L+ (inhalatlon, rat) = 510 mg/nt'or 2 hrs Skin effects (rabbit): Severe irritation Eye effects (rabbit): Severe irritation Carcinogenicity Data: Although there are reports linking exposure to sulfuric acid to cancer, this product Is not
| |
| .classied by NTP (National Toxicology Program), not regulated as carcinogenic by OSHA (Occupational Safety and Health Administration), and has not been evaluated by IARC (Intematlonal Agency for Research on Cancer) or ACGIH (American Conference of Governmental Industrial Hyglenlsts). See Section 3. Hazard Information, regarding Potential Health Effects (Long Term Exposure) for further discussion.
| |
| Reproductive Effects: No information Is available and no adverse reproductive effects are anticipated.
| |
| Mutagenicity Data: No'information is available and no adverse mutagenic effects are anticipated.
| |
| , Teratogeniclty Data: No Information is available and no adverse teratogenIc effects are anticipated.
| |
| Synerglstlc Materials: None known
| |
| /
| |
| MARSULEX MSDS 4010E Effective Oats: February, 1993 Page 6 ef 9 Supersedes: February, 1990
| |
| | |
| NIAII5ULKX, 'ATERIAL SAFETY DATA SHEET Sulfuric Acid
| |
| : 12. ECOLOGICAL INFORMATION Ecotoxlc Effects: Harmful to aquatic life ln very low concentrations. Ijtiay be dangerous if it enters water Intake; Fish toxicity critical concentration 10 mg/L; 7.34 mg/L/48 hrs - Lymneae Palustrls 100% mortality,
| |
| : 13. DISPOSAL CONSIDERATIONS
| |
| ~ Responsibility for proper waste disposal ls with the owner of the waste. Work with the appropriate regulatory bodies to ensure compliance with regulations.
| |
| ~ Consider the collection of residual sulfuric acid Into containers for reclamation or disposal only if the container Is suitable to withstand the material.
| |
| ~ Conskler lnsitu neutralization and disposal.
| |
| Clean-up materhl may be a RCRA Hazardous Waste on disposal.
| |
| ~ Provincial/State or local regulations or restrictions are complex and may differ from Federal regulations.
| |
| ~ The information applies to the material as manufactured; processing, neutralizing, use or contamination may make the Information inappropriate, Inaccurate or Incomplete.
| |
| : 14. TRANSPORT INFORMATION U.S. (Under DOT) Canada (Under TC)
| |
| /
| |
| / Shipping Name: RQ Sulfuric acid Hazard Chss or Division: 8 Shipping Name: Sulphuric acid Chsslficatlon(s): Class 8 (9.2)
| |
| Product Identification No. (PIN): UN1830 Product Identification No. (PIN): UN1830 Packing Group: II Packing Group: II
| |
| : 16. REGULATORY INFORMATION
| |
| .A.
| |
| SARA Title III HAZARD CATEGORIES AND LISTS Pr H t rl ~U Acute (Immedhte) Health: Yes Extremely Hazardous Substance Yes t
| |
| Chronic (Delayed) Health: Yes (40 CFR 355, SARA Title III Section 302)
| |
| Rre: No CERCLA Hazardous Substance Yes Reactivity: Yes (40 CFR 302.4)
| |
| Sudden Release of Pressure: No Toxic Chemical Yes (40 CFR 372.65, SARA Title III Section 313)
| |
| Effective Date: February, f993 MARSULEX MSDS 4010E Supersedes: February, 1990 Page 7 of 9
| |
| | |
| MATERIALSAFETY DATA"SHEET Sulfuric Acid
| |
| : 15. REGULATORY INFORMATION (continued)
| |
| Reportable Quantity (RQ) under U.S. EPA CERCLA: RQ=1000 Ib TSCA Inventory Status: Reported/Included
| |
| /
| |
| '~~aNaoa .
| |
| Workplace Hazardous Materials Information System (WHMIS)
| |
| WHMIS Classification(s): Class E - Corrosive Qass D1A - Very Toxic WHMIS Health Effects Index: Acute Lethality - very toxic - Immedhte Corrosive to animal skin WHMIS ingredient Disclosure List: Confirmed A; Meets crlterh for disclosure at 1% or greater.
| |
| Reportable Quantity (RQ) under Transport Canada -, TDG:
| |
| RQ=5 Iltres (or Kg) If It represents a danger to health, life, property or the environment.
| |
| : 16. OTHER INFORMATION Additional Information and References
| |
| : 1. Enviro-TIPS Manual, 'Sulphuric Acid and Oleum", Environment Canada, February 1984.
| |
| : 2. Weast, R.C. (Ed.), "CRC Handbook of Chemistry and Physics', 60th Edition (1980)
| |
| : 3. Sax, N.l., 'Dangerous Properties of Industrial Materials', 7th Edition (1989)
| |
| I
| |
| : 4. ACGIH, Threshold Umit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, 1991-92
| |
| : 5. Sittig, Marshall, "Handbook of Toxic arid Hazardous Chemicals and Carclnogens", 2nd Edition, 1985 Revision Indicators:
| |
| Information since the previous Issue.
| |
| g a ln the left margIn Indicates a revision or addition of Effectiv Date: February, 1998 MARSULEX MSDS 441 0E supersedes: February, 1990 Page 8 of 9
| |
| | |
| NARSULKX, MATERIALSAFETY DATA SHEET Sulfuric Acid
| |
| : 16. OTHER INFORMATION (continued)
| |
| Legend:
| |
| CAS 8 - Chemical Abstracts Service Registry Number CERClA - Comprehensive Environmental Response, Compensation, and Uabillty Act CFR - Code of Federal Regulations DOT - Department of Transportation EPA - Environmental Protection Agency
| |
| - The concentration of material in air expected to kill 50% of a group of test animals
| |
| - Lethal Dose expected to kill 50% of a group of test animals
| |
| - Lower Explosive Limit MSHA - Mine Safety and Health Administration NIOSH - National institute for Occupational Safety and Health PEL - Permissible Exposure Limit pvc - Polyvinyl chloride RCRA - Resource Conservation and Recovery Act SARA - Superfund Amendments and Reauthorlzatlon Act of the U.S. EPA STEL - Short Term Exposure Umlt TC - Transport Canada TDG - Transportation of Dangerous Goods Act/Regulations TLV - Threshold Limit Value TSCA - Toxic Substances Control Act
| |
| 'DNA - Time-Weighted Average UEL - Upper Explosive Limit The information contained herein has been prepared by MARSULEX Inc. and is offered only as a guide to the handling of this specific materhl and has been prepared In good faith by technically knowledgeable personnel. It Is not Intended to be all-Inclusive and the manner and conditions of use and handling may Involve other and additional conslderatlons. No warranty of any kind!s given or Implied and MARSULEXInc. will not be liable for any .
| |
| damages, losses, inJurles or consequential damages which may result from the use or reliance of any Information contained herein.
| |
| EffecUve Date: February, 1993 MARSULEX MSDS 4010E Supersedes: February, 1990 Page 9 of 9
| |
| | |
| INSTRUCTIONS FOR CCMPLETI IIG SECTION I I ITEMS I AND 2 ThiS farm requires information on the facility's discharge location, discharge schedule, volume f low rate and water treatment additives.
| |
| FNTER THE PERMIT NUMBER IN THE BOX AT THE TOP OF THIS FORM. THE PERMIT NUMBER CAN BE FOUND ON THE FRONT PAGE OF YOUR EXPIRING pEIa(IT. If this Is a new or not previously permitted facility, then leave blank and a number will be assigned.
| |
| Enter the outfall number In space provided tor each page of sectIon I I. Far each Individual discharge point o separate set of Section Il forms must be filled out.
| |
| ITEM I DISCHARGE LOCATION SCHEDULE AND FLOW RATES A. Enter the location of discharge, this should Include quarter-quarter section, quarter section, section, to n, and range.
| |
| : 8. List nome of receiving water (If surface voter discharge).
| |
| C. Indicate whether foci )Ity discharges on a seasonal basis.
| |
| D. If yes, list discharge periods.
| |
| Provide the land application rates used or expected to be used In terms of inches per hour, hours pec day. and Inches p<< w<<".
| |
| F. Indicate the type of wastewater to be discharged fram this outfall. Refer to the wastewater type code given In the left margin More than one code may be applicable.
| |
| G. Provide the average number of hours per day In ~hich the facility discharges treated wastewater and the total number of days per year in whiah the d(SCharge OCCurS.
| |
| H. Provide current (from the last l2 months) or expected flow rates os requested. Refer to unit code divan In the lett margin far the appropriate flow units. )sly - million gallons per year; MGD - million gallons per day; GPD - gallons pec doy.
| |
| I. Provide the maximum discharge flow rate which you want to have authorized within the permit. NOTE: For NPOES permits on)Y.
| |
| the use of such a flow rate will not place on actual limit restriction on the flaw but will be the flaw rote used to develop ettluent limits. Also, when the Monthly Operating Reports are reviewed by Compliance staff It will help thee to determine If any new or Increased uses might have occurred at the facility.
| |
| J. Provide the design flow tor this specific outtall discharge (e.g. batch treatment system flaw, packaged treatment system flaw.
| |
| or sane other finite treatment system flaw).
| |
| ITEM 2 WATER TREATMENT ADO IT IVES A. Indicate ~bather discharge Is treated with conditioners, Inhibitors, or mlcrobloclde. If not, continue to Item 3.
| |
| B. Give name, function, and chemical composition of additives used.
| |
| C. Give nome and address of the monutacturer(s) ot the additives used.
| |
| D. Indicate expected minimis, overage and maxlcmxs discharge concentrations of the additive(s) tor this discharge.
| |
| Indicate whether you treat the discharge to remove the additive(s) before discharge of wastewater.
| |
| F. Indicate the removal efficiency of each additive from the wastewater ond the discharge frequency of each additive to the surface water or groundwater.
| |
| G. hOTE: It Is the responsibility ot the applicant to supply the product Information as requested In this Item 4. Information requested but not supplied may result In the application being returned to the applicant for ccmpletlon.
| |
| 32
| |
| | |
| SECTlON II PERMIT~~ "Cl 4005827 SEE INSTRUCTIONS ON REVERSE SIDE OJIFNI. IlfKR lTEM As LOCATION OF DISCNRGE
| |
| ~~< s'5E e. $ ErKfl I~05, 1M ~>< <, pA%E L11 5~
| |
| B. IVY RECEIVING HATER (IE. GROLIEWATER OR IPVE OF SIRFACE BSOPTIONOND DISCHARGE Cs DO (IF YW DISCHARGE SEASWILLY.
| |
| IOs CCNTIIAE TO E) Q~ QX ~
| |
| LOCATION D. IF YESe LIST DISCNRGE PERIODS N/A IOe / DAY IOe / DAY FLOW
| |
| ~ ~ u ~ 'u RATE WASTEWATER Ee (AND APPLICATION RATE N/A INs IR>>
| |
| ~ LJ IRs DAY
| |
| ~
| |
| INs/NKe
| |
| ~ KJ Nc(
| |
| 1 CONTACT COOUNG 2 NON CONTI(CT Fe Gs lYPE OF HASIEHATER DISCNRGE D ISOQRGE SOHlIE (YEARLY AVERAGE)
| |
| L3 L~J u W LJ LJ HG(RS/DAY COOLING 3 PROCESS Hs DISCHARGE FLOI RATE 4 9 W ITj C0DE 4 SANITARY 5 STORMWATER All time daily times 365.
| |
| maximum TOTAL YEARLY DAILY HINIMPI 2 .6 0 '2J DAILY NXIILPI ~2 1 MGY I ~ TIE NXDSPI DISCNRGE FLOV RATE TO BE AIRICRIZED IN PBPIIT>> ~ 6 WIT)OXK 2 MGD 3 QPD Je HAXlKPI DESIGN DISCHARGE FLOI RATEe 5- 2 u~
| |
| As DO YW USE (IF Ie.
| |
| HATER TREAllEHT ACOITIVES CCNTDAE TO IITH 3) lO TREAT YOLR DI~ DESIGN ITEM Bs, Nt% FWCTIONe AID OEHICAL COSOSITICN OF TAESE AIDITIVES e SULFURIC ACID H Neutralization*
| |
| SODIUM HYDROX WATER TREATMENT ADDITIVES
| |
| : c. rwE ao mmnrm~ ~~ SULFURI C ACID SODIUM HYDROXIDE MARSULEX, INC. HAVILAND PRODUCTS COMPANY 1 MQ/I 111 GORDON BAKER ROAD, SUITE 30 421 ANN ST., N.W.
| |
| 2 NORTH YORK, ONT M2H 3R1
| |
| ~
| |
| UQ/I GRAND RAPIDS, MI 49504 Ds EXPECTED AcoITIYE wvE ACOITIVE ACOI TIVE E.
| |
| F.
| |
| DO KVE HA%
| |
| DISCNRX COKENIRATION CF AIOITIVESe Sodium Sulfate YW TREAT lIE DISCHARGE lO ABOVE ACOITIVES?
| |
| l4KT IS lHE RBClVAL EFF ICIBCY AM) D ISONRGE PREOEHCY?
| |
| HIHIISJI
| |
| '0 WITS
| |
| ~s1 LJ'~
| |
| LJ; AVERAGE 3 0 0 WITS CXE
| |
| ~s 1
| |
| LJs M:
| |
| ~ NXDSPI 1 5 0 0 WITS aXE
| |
| ~1 LJ LJ N/A IRS s/DAY DAYS/HK>>
| |
| ACOITIVE HA%
| |
| LJ ACOITIVE HA%
| |
| ACDI TIVE HNE G AS AN ATTAtHsEHT lD THIS APPLICATIOI PROVIDE SPECIFIC NPRALIAN CR AQSLTIC lOXICOLOGICAL D(TA OI REFERENCE HHIOI ARE AVAILABLEAND INFNP(ATICN CN THE RATE OF DEGRADATICN OF lIE PRCOCIS FCR EKH ACOITIVEe MSDS attached.
| |
| * Approximately instantaneous neutralization upon mixing (New tank to be completed January of 1995 will ensure complete neutralization prior to discharge.)
| |
| S1
| |
| | |
| MATERIAL SAFETY DATA SHEET SODIUM HYDROXIDE 50%
| |
| ENDUSTREAL GRADE SECTION I IDENTIFICATION MANUFACTURER'S NAME............ Havi1 and Products Campany ADDRESS (STREET, CITY, STATE, Z IP) 421 Ann St., N.N., Grand Rapids, ME 49504 PHONE NUMBER e a > ~ s ~ ~ ~ ~ ~ a ~ ~ ~ ~ ~ ~ s (616) ~61-6691
| |
| ~
| |
| EMERGENCY PHONE NUMBER......... CHKMTREC (800) 424-9Z00 EFFECTIVE DATE................. 6/18/91 TRADE NAME................ .... SOD I UM HYDROXIDE 50%
| |
| ~
| |
| INDUSTRIAL GRADE CHEMICAL FAMILY..............-. Alkali, Base SECTION II HAZARDOUS INGREDIENTS HAZARDOUS COMPONENTS OSHA/PKL ACGIH/TLV (Units) PROD. CAS N Sodium Hydroxide (Caustic mg/m= 2 mg/m~ T4IA 1.10-73-2 Soda) TNA (48.5-51.0% by wt)
| |
| Sodium Chl aride (0. 8-1,.3% Nat Nat 7647-14-5 by xt) Estab 1 i shed Estab 1 i shed Mater (Balance) Not Nat 77~F2-18-5 Established Kstab 1 i shed SECTION III PHYSICAL DATA BOILING POINT ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ a ~ ~ .9~~ F (145 C)
| |
| FREEZ ING POINT ~ ~ e ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 60 F (15. 6 C)
| |
| VAPOR PRESSURE (mm Hg)........ 1.5 C~ 20 C VAPOR DENSITY (Air~i)......... Na Enlormation Available SOLUBILITY IN H20............. Completely APPEARANCE/ODOR a ~ Cl ear, Color) ess liquid; Odorless
| |
| )......
| |
| ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~
| |
| SPEC IF I C GRA V I TY (H20=1 1 52
| |
| ~
| |
| P Ha ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ s ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ Not Established SECTION IV FIRE AND EXPLOSION HAZARD DATA FLASH POINT.. ~..........-...........
| |
| LIMIT (% Valume)
| |
| Nat Flammable Nat Appl icable LONER EXPLOSIVE by UPPER EXPLOSIVE LIMIT (% by Volume) Nat Applicable EXTINGUISH MEDEA................... As far Surraunding Fires 07/.~0/1991
| |
| | |
| C'ATERIAL SAFETY DATA SHEET SODIUM HYDROXIDE 50/
| |
| ENDUSTRIAL GRADE SPECIAL FIRE FIGHTING PROCEDURES... Wear NIOSH/MSHA approved sel f cantained breathing appar atus and f ul 1 protective equipment when this material is involved in a fire.
| |
| UNUSUAL FIRE HAZARD........ ~....... En solution causti c can react wi th amphateric metals generating hydrogen which is flammable and/or e plosive if ignited.
| |
| SECTION V HEALTH HAZARD DATA CARCINOGENICITY............... None N TP ~ ~ ~ s ~ ~ ~ ~ ~ ~ ~ e ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ No I ARC ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ no OVER EXPOSURE EFFECTS......... Redness of Exposed Tissues with possible burns r esul ting in deep ulceration.
| |
| PRIMARY ROUTF (S) QF ENTRY..... Skin Contact FIRST AID PROCEDURES.......... If inhaled: Remove to fresh air. If nat breathing', give artif icial respiration, preferably mouth-to-mauth. If breathing is difficult, aive oxygen. Get medical attention.
| |
| In case of contact: Immedi atel y flush eyes ar skin with plenty af water for at least 15 minutes while removing contaminated clothing and shaes. Get medi cal attent i an. Wash c) othing bef or e reuse.
| |
| Ingestion: Do not induce vomiting.
| |
| Ef canscious, dilute by giving several glasses of water. Call a Physician Immediately.
| |
| EXPOSURE AGGRAVATED MEDECAL CONDITIONS None Currently Known SECTION VI REACTIVITY DATA CHEMICAL STABILITY............ Stable CONDITIONS TQ AVOID........... Nat App 1 i cab 1 e INCOMPATIBLE MATERIALS........ Acids DECOMPOSITION PRODUCTS........ None Current.l y Knawn HAZARDOUS POLYMERIZATION...... Wi 1 1 Not Occur POLYMERIZATION AVOID.......... Not Applicable SECTION VII SPILL QR LEAK PROCEDURE 07/~0/1991
| |
| | |
| I r
| |
| MATERIAL SAFETY DATA SHEET SODIUM HYDROXIDE 50/
| |
| INDUSTRIAL GRADE FOR SPILL ~ s ~ ~ ~ ~ w ~ i ~ a a > < ~ ~ a ~ s ~ Add non-reactive dry, absorbent such as diatomaceous earth. Shovel or sweep up and place in an approved DQT container and seal. Flush contaminated area and neutrali"=e with dilute acid.
| |
| WASTE DISPOSAL METHOD......... Dispose of spill,ed or waste product, contaminated soil and other contaminated materials in licensed landfill or treatment facility in accordance with all federal, state and local regulations.
| |
| SECTION V III SPECIAL PROTECTION RESPIRATORY PROTECTION....... Supplied air or sel f contained breathing apparatus with full face piece.
| |
| VENT I LATI ON ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ t o ~ ~ To maintain vapors below limits.
| |
| PROTECTIVE GLOVES............ Rubber or other impervious materials.
| |
| EYE PROTECTION............; .. Chemical splash proof goggles.
| |
| QTHER PROTECTIVE EQUIPMENT... A safety shower and eye bath should be available. For operations where spills or splashing may occur, use an impervious body covering and boots.
| |
| HANDLING AND STORAGE......... Store in cool, dry, well ventilated area.
| |
| Keep containers closed when not in use.
| |
| SECTION IX SPECIAL PRECAUTIONS HA Z ARD CLASS ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ Corr osi ve Material DOT SHIPPING NAME........... SODIUM HYDROXIDE, LILDUID VN NUMBER e ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ UN1 824 REPORTABLE QUANTITY (RQ) .'... 2000 lbs.
| |
| REFERENCES HMIS: H-3, F-O, R-1 SQDHYDOX 07/ 0/1991
| |
| | |
| SEE INSTRUCTIONS SECTlON II PERMIT NUMBER ~ IYI1 00005827 ON REVERSE SIDE OOD rEM Ae NctE OFY PROCESS ltttOUGH CotnRIBUTINI TO 1NE DISOIARGE lNIS OUIFAU. At@ SIC CODE STM LECT 491 3 B, PROCESS SCHHXLE (YEARLY AVERAGE) thorn/DAY ~4 ~65 M
| |
| c/t Ce PROCESS HASTKHATER FIDH RATE 1 1 1 .3 5 4 w~~T5jl See various contributing PROCESS cct TOTAL YEARLY STREAMS CONTRIBUTING OY 0cc waste streams in Section DAILY HINltttl
| |
| .090~6 TO j.6.A DAILV HAXItXH
| |
| . 683 ~6 OUTFALL DISCHARGE De PROCESS PRODUCTION RATE N/A WITS / TIIE N/A
| |
| ~
| |
| A. tUYE 0F PRocEss coNIRIBUTI% To TIE DIGQccRGK TNOIXiH 1NIS OUTFALL ANt SIC CODE Be PROCESS SCIEDIXE (YEARLY AVERAGE)
| |
| Uses/oev oevs/vsse c/t Ce PROCESS HASTEHATER FUXI RATE TOTAL YEARLY, O01 0
| |
| DAlLY HINWPI 1 POUNDS DAILY HAXIIXH 2 GALLONS WITS /TIHE D. PROCESS PRODUCTION RATE 3 CUBIC YARDS A NAtE OF PRXEss cotnRIBUTING To TIE DlsctFIRGE TIRCXXIH 1NIS OUIFALL AtQ SIC CODE N/A 4 TONS Be PROCESS SCIEDIAE (YEARLY AVERAGE) 5 MGY 6 MGD Ce PROCESS HASTKHATKR FUXI RATE 7 GPD TOTAL YEARLY DAII.Y HININPI DAILY HAXIHH D. PROCESS PRODUCTION RAlE WITS XTIHE TIME 1 HOUR A. NAtE OF PROCESS CenRIBUTING To TIE DISCHARGE AtD SIC CXXIE N/A 2 DAY 3 Be PROCESS SCIEIXLK (YEARLY AVERAGE)
| |
| WEEK 4 MONTH IHIT CODE 5 PROCESS tcASTBaTER FIDH RATE YEAR TOTAI. YEARLY DAlLY HINItSPI DAILY HAXItCPC De PROCESS PRNXX,TION RATE Wlls ~It%
| |
| N/A
| |
| ~
| |
| A. IIAtE DF PROCKss cottmrBUTING To TIE DlscHIRGK TI%GLXIH 1NIS OUIFAIL AND SIC CCCE Be PROCESS SctHXLE (YEARLY AVERAGE)
| |
| IOUII/SSY OSYS/YYSS c/t C, PROCESS HASTBtCTER FtlH RATE WIT CODE OcO TOTAL YEARLY LL 0
| |
| DAILY HINIIMI DAILY &XItXPI De PROCESS PROIXCTION RATE UNITS ~ TltE
| |
| | |
| INSTRUCTIONS FOR COMPLETING SECTION I I ITEM S Tt Is form requires Information on the process streams <<hlch contribute to this discharge.
| |
| ENTER THE PERMIT NLSIBER IN THE BOX AT THE TOP OF THIS FORM. THE PERMIT NISIBER CAN BE FOUNO ON THE FRONT PAGE OF YOUR EXPIRING PERMIT. I f this Is a new or not previously permitted facility, then leave blank and a number <<ill be assigned.
| |
| Enter outfall numaer in space provided for each page of Section II. For each Individual dlscharoe oint a seaarate set of Section II forms must be filled out.
| |
| PROCESS STREAMS CONTRIBUTING TO OISCHARGE: FOR EACH SEPARATE PROCESS PROVIDE THE FOLLOWING INFORMATIO'I A. Enter the name of the process <<hlch contributes to this discharge. Also provide the proper SIC code.
| |
| B. Indicate the yearly average process schedule Jn hours per day and days-per-year.
| |
| C Provide the process <<aste<<ster flow rate information as requested based on your last I2 months of operations. Refer to unit code given in the left margin for the appropriate flaw units ~
| |
| : 0. Process Production Rate - Certain permit limitations may be based on production rates. The production rates used to determine permit limits shall be represented by a reasonable measure of actual production of the facility, such as the production during the high month of the previous year, or the monthly averaqe for the highest of the previous five years. or other reasonable measure as stated In applicable U.S.E.P.A. categorical rules and regulations.
| |
| For new sources or new dlschargers, actual production shall be estimated using pro]ected production.
| |
| Record your production rates In the terms and units used in the applicable U.S.E.P.A. categorical rules and regulations for your type of facility.
| |
| 34
| |
| | |
| SECTION II PERMIT~
| |
| NUMBER IeIT 0005827 SEE INSTRUCTIONS ON REVERSE SIDE
| |
| ~OD E EM Ae IS THE DISCHARGE FROM 1HIS OUTFALL DIRECIKD TO lHE GRIXNO GROINDIATKRS? (IF tOP CCttfltAE TO ITBI 5)
| |
| OR C~I YES tO B. HAS A HYDROGEOLOGICAL STUDY OR ITS EQUIVALENf BEEN PKRFORtED OR IS TIMBRE SIFFICIKNT CURRENf HYKROGEO)re ICAL INFORHATION AVAILABLE g REOIRKD @V~HATER REQXE2CES g Re GROUNDWATER THIS EXISTI% OR PROPOSED DISCHARGE) IF YES AlTACH A COPY CF THE REPORTS Report Submitted 12/6/91 DISCHARGE Ce ARE YOU~RSTIHj AN EXKHPTICN FIKtl SIKPHTfltti A HITROGKOUXIICAL REPORT INOKR INFORMATION RULE RPX5e22II (Q(PAGE 56) OR FlKtl GRONDQTKR tSNITORItts gEOUIRBKNIS INDER RULE R. ZSP (5) (PAGE IIZ) OF TIE PART 22 RULES ~ IF YES ATTACH DOCLNKNTS AN) EXPIANATION TO DBSNSTRATK THAT YOLR DISCNRGE tEXAD OUALIFY FOR AN EXEtls ION.
| |
| De ARE YOU REQLESTIt6 A VARIANCE FRAN RtaK 323e2205 (PAGE 99 (tDNDKGRADATICN) OF TIE HATER RESIXNCES CCEfll SS ION PART 22 GRtXSDQTER R1LES2 IF YES ATTACH SIKH DOCU5BIIS AS NECESSARY TO DQQNSIRATE TIE NEED FCR A VARIANCE IN TKPNS OF TIE cRllKRIA $ PEclFIED IN RIAE 5Dei210 (PAGE 0F THE PART 22 RIAKs ~
| |
| Ee I IST ALL Cte)ICAL SISSTAtCES lIHIDI ARE IN NICHIGAN S CRITICAL HATKRIALS REGISTER TAKE IV cPAGE II) ANWOR U S. EPA S PRICRllY RXLUfANT LIST TARE V (PAGE 7) OR ANY OIIER SLBSTAtCES MICH ARE OI HAY BKO% IMRIOUS TO TIE KESIGNATKD USES OF TIE GIXNDN8eTKR CR TO 7% QX NOT APPLICABLK/BELIEVEDABSBIT PUKIC tEALTH THAT ARE DISCHARGED OR EXPECTED TO BE DISCNRGKD TQ TIE GRIXNDIATBL7IY1HIS FACILllYe ESTIHAlK THK FINAL EFFUENT COMXNIRATION AND REQRD ALL DATA IN ITBI 7 OF SECflCN II IN 1HIS BOOIUTP TIE APPLICANI'AY BE RECUIRED TO DO AIXIITICIALHASTE ANALYSESP CI RtKSENTP DATA PROVIDED IN l781 7 A e DISCHARGE CHAIIACTKRI ST I CS CONC BIIRATI ON INITS CCOE 0 ANALYSES CODE LITEM 5
| |
| EXPECTED BOO5
| |
| 'COD (F IVE DAY B IOCteI ICAL OXYGEN DKHAte)
| |
| (DeIICAL OXYGBI DKHAND) ~5, ~0 , L00I
| |
| 'TOC (TOTAL ORGANIC CARBCN)
| |
| WASTEWATER CHARAC AttsNIA NITROGBI (AS N) u>
| |
| ~0 TOTAL SUSPEMKD SOLIDS UNETS CODE 1 Mg/I TOTAL PteSPICRUS (AS I ) . ~02 0 .~08 ~52 2 Ug/ I TOTAL RESIlll4L OLORINE
| |
| ~.
| |
| 3 COUNTS/
| |
| 100 ml DISSOLVED OXYGEN HIN 4 S.U.
| |
| 5 F LJ PLJ S LBS/GAY FECAL COLIFCRH BACTERIA u>
| |
| 'nmaaTIEIK (SIPtER)
| |
| TBFERATINE (HINIER) ~
| |
| LLJ Be
| |
| ~
| |
| ~
| |
| LJ LJ OTIBR HASTEHATER OIERACTERISTICS LJ LJ5 LJ 0 I L 8 G R E A S E 1 0; , ~0 ~1 ~52 u'
| |
| ~SAWP E LCHLORI DE ~10, E99e 2 0 ~8 1 ~52 LJ 1
| |
| JXBF GRAB
| |
| <ULF ATE ~80, I00I ~58 2 ~0 ~1 6 1 2 2 24 HOUR COMPOSITE LT;OETA L I L 0208~195, 0 925 ~0 ~2 LJ LJ LJ
| |
| ~ LJ RECUIRED ItAAQTIINRN St%FACE HATER DISONRGESP Analyst.s per J. B. Beauboeuf, Target Permit Effluent Limits List.
| |
| | |
| INSTRUCTIONS FOR CCMPLETING SECTION I I ITEMS 4 ANO 5 This forpp requires Information on a specific outfal I discharging to eIther the groundraters or the surface ~aters.
| |
| ENTER THE PERMIT NPIBER IN THE BOX AT THE TCP OF THIS FORM. THE PERMIT N(D(BER CAN BE FOUND ON THE FRCNT PAGE OF YOUR EXPIRING PERMIT. If thlS iS a ner Or nOt preVIOuSly permitted faCI llty, then leaVe blank and a number Will be aSSlgned.
| |
| Enter the outfall number In the sDace provided for each page of Section II. For each Individual dlscharoe point a se arete set of Section II forms (Iteypps 4 and S) mu5t be filled out.
| |
| ITEM 4 GROUfd)WATER DISCHARGE INFORMATION (DO NOT INCLUDE DEEP WELL INJECT(Off INFORMATION IN THIS ITEM)
| |
| A.-O. The aDDlicant shall address each of these parts lf the discharge frcm this outfall Is to the oroundwater.
| |
| ITEM 5 EXISTING OR EXPECTED (FOR A NEW DISCHARGE) WASTEWATEP. CHARACTERISTICS OF GROUNDWATER OR SURFACE wATER DISCHARGE (00 NOT INCLUDE w LL INJ I IN I N H A. The applicant shall report available discharge data (real data for existing discharge or expected data for aas proposed discharge) aDDroDrlate for a for the parameters as listed. These parameters shall be addressed for either a surface water discharge ot groundwater discharge. For assistance In determining appropriate parameters a groundwater dlscharoe appl leant may contact the Groundrater Qual lty Division, Permits Section or the appropriate Groundrater Quality Olvlslcn's District off ice.
| |
| The apDI)cant shall report the sample type code best describing each reported place of data. See coding on the left margin of B.
| |
| this form.
| |
| If this outfall Is
| |
| ~, o h
| |
| h pp eo a
| |
| Pt tby, surface water dlscharqe, the applicant must report quantitative data for each parameter Identified b an ppotdby o
| |
| ded I tl p
| |
| \,tt p hbe d
| |
| h d Pt h
| |
| tto4Mtt o
| |
| thl If data Is available for other parameters not lIsted above In A. or other parts ot this application the applicant should report d p opll t
| |
| tl
| |
| ~ b that data In the blank space5 provided In this part.
| |
| NOTESl I. Unit code5 tor parmppeters reported In parts A and B can be found on the lett hand side of this form.
| |
| : 2. Grab sample shall be used to analyze for pH, temperature, total phenols, residual chlorine, oil and grease. and fecal coliform In a surface water discharge unless other frequency-sample type analyses are available. See Glossary (page 48) for detlnitlon ot grab sample.
| |
| : 3. 24-hour composite samples shall be used to analyze for Total BQos, coo, Toc, Anmonla Nitrogen, and Total Suspended Solids In a surface water discharge unless other frequency-staple type analyses are available. See Glossary (page 48) for detlnltlon of 'composite seppple.
| |
| : 4. REPORTING OF INTAKE DATA. You are not required to report unless you rlsh to demonstrate your ellglbl llty for a unct" etfluent Ilmltatian tOr One Or mOre POllutantSP that IS, an effluent llmltatlOn adjuated by SubtraCtlng the average level of the pollutant(s) present In your Intake ~ater. NPDES regulations allow net limitations only In certain clrcumstance5. To demonstrate your eligibility, report the average of the results of analyses on your Intake water (If your rater is treated before use, test the water after It Is treated), and attach a 5eparate Sheet containing the following for each pollutant:
| |
| la) A statement that the Intake ~ater Is drawn from the body of rater Into which the discharge Is made.
| |
| (Otherwise, you are not eligible tor net limitations.)
| |
| (b) A statement ot the extent to which the level of the pollutant Is reduced by treatment of your wastewater.
| |
| (Your limitations will be adjusted only to the extent that the pollutant is not removed.)
| |
| (c) When apDIlcable (for exsnple, when the pollutant reDresents a class of ccmppounds), a demonstration ot the extent to which the pollutants In the Intake very physically, chemical ly, or biologically from the pollutants contained In your dIscharge. (Your limitations will be adjusted only to the extent that the Intake pollutants do not vary from the discharged pollutants.)
| |
| : 5. If you have tro or more substantially Indentlcal outtalls, you may request permission fran your permitting authoritv to sample and analyze only one outfall and submit the results of the analysis for other substantially Identloal OutfallS. If yOur requeSt IS granted by the permitting authOrlty, On a Separate Sheet attaChed tOethe application form Identify which outfall you did test, and describe why the outfalls rhlch you did not test are SubStantlally IdentlCal tO the Outfall rhlCh yOu did teSt.
| |
| 36
| |
| | |
| SEE INSTRUCTIONS ON REVERSE SIDE SECTION II PERMIT NUMBER ~ IYIX QO Q 58 27 ODD EM THE FQLIQtl%
| |
| IDIEt NEW USE REQUESTED 1%'ORHAT ION ~r DISOQRGERS Q5U. PROVIDE EXPECTED ADQIESSED ~
| |
| VALI FOR MIFACE HATER DI SCHARGERS THE QUANTITATIVE AMD
| |
| ~
| |
| 6 QUALITATIVE INFORMATION RECITED BEIQte AI IS THIS FACILllY A PRIWVIY INDUSTRY? (REFER TO TABLE IA PAf< g3 (IF%,GOTOK) (IFYS GOTOB)
| |
| PRIORITY POLLUTANTS BI INDICATE TYPE OF PRIMARY INDUSlRY AS LISTED IN TABLE IA PAGE (CONTINUE WITH C.)
| |
| gl. STM LEC WR CI THIS OUTFA!L DISCHARGE CONTAIN ANY PROCESS 'HASTEHATKR?
| |
| AND DOES (IF NQ, GO TO E) (IF YESi GO TO 0)
| |
| X YES NO ADDITIONAL Q ~nu INFORMATION DI INDICATE lHICH GC/HS FRACTIONS HUST SE TESTED FOR I FOR (REFER TO TABLE IA PAfK III) Analysis per IDIKI FOR FAOI GC/HS FRACTION CHECKEDs EACH SPECIFIC ORGANIC TOXIC POILUTAttf HITHIN J.B. Beauboeuf SURFACE WATER EACH FRACTION IBISI BE ANALYZED FOR (SEE TABLE IIA PAGE INCUSTRY APPLICANTS WITH A PROCESS WASTEHAlKR DISOIARGE 02, Qff IN ADDITION, AIL PRll@RY PROVIDE QUUITITATIVE Q Target Permit DISCHARGE DATA FOR EACH TOXIC POLUITAMT IN TABLE II IA PNK 99 I Q ~m Effluent Limits ONLY RECORD ALL DATA OM FOILS PROVIDED (ITKH 7) IN THIS SOQKLETI (CXITItttE HITH E-K BEilH)
| |
| Q PESTICIDE
| |
| ~
| |
| E~
| |
| ~
| |
| IF IN TARE IIA AND IVA PAGES SE PROVIDED+
| |
| ~
| |
| QIIFACE HATER DISCHARGE APPLICANT (PRIMARY OR SECCNDUIY INDUSTRY)s REGARDLESS OF THE TYPE OF DISCHARGE Kttlts CR NS REASON TO BELIEVE THAT ANY PIXLUTAMT LISTED IS DISCHARGED FRCH ANY CIIFAL41tE QUUITITATIVK DATA
| |
| %T APPLICABLE/BELIEVED ABSENT N/A RECXID ALL DATA ON FNttS PROVIDED (ITKH 7) IN lHIS BOOKLETe Fa IF ANY QRFACE MATER DISCHARGE APPLICAMf (PRINRY OR SECCNDUIY IMXISTRY)a REGARRESS OF TYPE OF DISOIARGG K%ws OR HAS REASQI TO BELIEVE ANY POLUITAMIS LISTED IN %T APPLI CABLE/SELIEYED ABSENT TABLE VA PACk + ARE DISCHARfkD FRCtt ANY OUTFAlL TIE APPLICANT ~H RFASONS FOR TIE PCLUTAMT BE1% PRESENT A% PROVIDE AMY AVAILABLEQUAMflTATIVE DESCRIBE DATA'ECORD N/A ALL DATA OM F<AS PROVIDED (ITKH 7) IM THIS SOQIGEfo Q PRESENf/DATA IS AlTACHED G>> AIL QRFACE HATER Dl SCNRGE APPLICANfS (PRIMARY A% SECCNDARY IIGXISTRI Es)
| |
| NT APPLICABLE/BELlEVKDABSENT OR ACTIIIES L tti TRIQSIXIOPIE%XY ACETIC ACID (2s 4i 5 T)t TRloaoeeaae f PROPANOIC Aclo (SILYKx, K ti, 5, TP) 4, WgI~aagaOXY) KIHYL 2, 2-DIOSJXIOPROPICNAIK~(' 0, N/A IrVTRIOLOIOPtENL (TCMPi OR HEXAOLOROPIENE tHCPRI (AU DATA FCR TIE ABOVE tKIST BE GENERATED US I% STA%ARD ANALYfICAL CALISRATICN PROCEDQIKS) OR
| |
| ~
| |
| KRIS OR HAS REASON 10 BELIEVE THAT TCCD IS OR HAY BE PRESENT IN TIEIR DISCHARGEo REPORT tXIALITATIVKDATAe GKIERATKD l43ICH USED A SCREENING PROC6XIIE KIT CALIBRATED HITH ANALYTICALSTAIKARDSi FOR 6A / -
| |
| 8i TKIIIAOEOIROISEKKPP DIOXIN (TCCD)>> REIXII AIL DATA OM FOES PROVIDED (ITKH k) IN THIS NOKLETI Q PRESENf/DATA Is ATTAOED JI IF TIE QRFACE HATER DISOIARGE APPLICANT KM'R HAS REASON 10 BELIEVE 1HAT BIOUXilCAI TOXICITY TESTS HERE HADE IN 1HE LAST TIRKE U) YEARS ON AMY OF TIE APPLICANT S DISCHARGES CR ON A RECEIV1% HATER IN RELATION 10 A DISCHARGE PROVIDE lHIS IWÃHATION AS Att ATTAOtENT TO THIS APPLICATIONe g %T APPLICABLE APPLICABLE/SKK ATTAQED KI IF A COMIRACT LABORATORY OR CONQLTI% FIRN PERFOR%D ANY OF TIE AIKAYSES REQUIRED BY 1HIS APPLICATION PROVIDE TIE Nt% AND AIXRESS OF EACH IABORATCRY OR FIRI A% Q %T APFLICASIZ g
| |
| THE AIQLYSES PKRFQttED AS AM ATTACHMENT CF THIS APPLICATICNI APPLICABIZ/SEK ATTAOIED LI DQ YOU DISCHARGE Ath'THER TOXIC OR INtIRIOUS DKHICAL QSSTAMCES MT LISTKD IN TARES IV PAGE D AlO IIA llttCAlVA PtV4S OellCAL SUBSTANCES AMD ESTIWLTK TIE FINAL EFFUEHT
| |
| ~~I IF YESs TAN IDENTIEY TlE QX %T APPLICABLE CCNCENIIIATIOISI SIKFIIT THIS ItAAIATICNAS AN ATTAOtENT TO 1HIS APPLICATION>> APPLICASLEJSKK ATTAQIKD 37
| |
| | |
| INSTRUCTIONS FOR CCMPLETING SECTION I I ITEM 6 This form requires Information on a specific outtall discharging to the surface waters.
| |
| ENTER THE PEIBIIT NUMBER IN THE BOX AT THE TCP OF THIS FORM. THE PERMIT NIPIBER CAN BE FDNID ON THE FRONT PAGE OF YOUR EXPIRING PERMIT. If this Is a new or not previously permItted facility, then leave blank and a number will be assigned.
| |
| Enter the outfall number In the space provided for each page of Section II. For each Individual dlscharqe point a separate set of Section I I, Item 6 forms must be fl I led out.
| |
| ITEM 6 PRIORITY POLLUTANTS AND ADDITIONAL INFORMATION NOTE: If you have two or more substantially Indent)eel outfal ls, you may request permission from your permitting authority to sample and analyze only one outfall and submit the results of the analysis for other substantially Identical outfal ls.
| |
| If your request Is granted by the permitting authority, on a separate sheet attached to the application form Identify which outfall you did test, and describe why the outfalls which you did not test are substantially Identical to the outfall which you did test.
| |
| NOTE: 40 CFR Part I22.2l(g)(8), Friday, April I, 1983, provides for a Small Business Exemption from the reporting of quantitative data for organic toxic pollutants and toxic pollutants as required by Part I22.2)(g)(T)(ll)(A) or I22.2I(g)(7)(ill)(A).
| |
| A.-C. These parts are selfwxplanatory and do not require further Instructions. Simply go through each parr and do as Indicated.
| |
| and E.-J.
| |
| : 0. Several Industrial categor lss and subcategories have been exempted fran submitting data on certain GC/MS Fractions (40 CFR Part l22, Vol. 48, No. 64, Friday, April I, l983, Notes I, 2, and 3).
| |
| Review the following list to determine whether your teel lity qualifies to be exempt from reporting GC/MS (Gas Chrcmatogl aphy/
| |
| Mass Spectroscopy) Fractions.
| |
| GC/MS Fract Ion Testing and ReportIng Exemptions Text l le Ml I Is Indust
| |
| - Al I tour GC/MS organic tractlons In the Greige Ml I Is Subcategory.
| |
| - Pesticide fraction In all other subparts of this Industry'.
| |
| Ore Mlnln and Oressl Indust
| |
| - Volatile, base/neutral, and pesticide fractions In the Base and Precious Metals Subcategory.
| |
| - Al I four GC/MS organic fractions in el I other subcategories of this Industry.
| |
| Gus and Wood Chemicals Industr
| |
| - Pesticide fraction in the Tall Oil Rosin Subcategory and the Rosin Based Derivatives Subcategory.
| |
| Pesticide and base/neutral fractions in ~ II other subcategories of this Industry.
| |
| Pul and Paper Industr
| |
| - Pesticide fractIon In Papergrade Sulfite subcateqorles (subparts J and 0).
| |
| - Base/neutral and pesticide fractions In Delnk Subpart 0, Dissolving Kratt Subpart F, and Paperboard from Waste Paper Subpart E.
| |
| - Volatile, base/neutral, pesticide fractions In the BCT Bleached Kraft Subpart H, Semi-chemical Subparts 8 and C, and Honlntegrated-Fins Papers Subpart R.
| |
| - Acid, base/neutral, and pesticide fractions in Fine Bleached Kraft Subpart I, Dissolving Sulfite Pulp Subpart K, Ground-wood Fine Papers Subpart 0, Market Bleached Kraft Subpart G, Tissue from Wastepaper Subpart T, and Nonlntegrated Tissue Papers Subpart S.
| |
| Steam Electric Power Plant Industr
| |
| - Base/neutral fraction In the Once Through Cooling Water, Fly Ash, and Bottom Ash Transport Water process wastestreams.
| |
| 38
| |
| | |
| 31 SEE INSTRUCTIONS ON REVERSE SIDE EM 7
| |
| CRITICAL MATERIALS TOXIC POLLUTJLNTS HAZARDOUS SUBSTANCES A,
| |
| Bo USE THIS DATA SHEEf TO D
| |
| D D
| |
| X X
| |
| SECTlON RECORD IHFCRMATION AS RECLJIRKD 1
| |
| 2.
| |
| SECTION SECTION Bo BELOW:
| |
| ll II IIg IN; ITEM ITEM 6 MI (OKCX APPROPRIATE BOX JOR ttIICH PRIORITY POUJJTANfs IM SLRFACE lATER CRITICAL MATERIALS (TABLE IV) IN SLJLFACE LIST ANY CRITICAL MATERIAL (TABLE IV PJGE 6) NOT ADD!ESSED IN SECTION ll ITEM 6 PRIORITY POLUJfAMTS !4IICH YLXJ ttOW OR HAVE REASON TO BELIEVE TO BE PRESENT IN TIP. DISCHLRGEs SEE ODD GROLMXCLTKR DISOIARGE INFORMATION (PAGE HATBOX X
| |
| 35)
| |
| DlscttVYZ ppp5827 INFCRMATICN THIS DATA SHEET REPRESEMTSI)
| |
| (PAGE DISCHARGE (PAGE 3J))
| |
| ler APPUcASE 37)
| |
| IN REVERSE SIDE OF lHIS PAGE FOR FLJITIER DIRECTIONss DISCHARGE APPLICABLE (SEE BKLCtt)
| |
| AI NLME OF CRITICAL MATERIAL CR PRIORllY POLUJTAMT H drazine 0 c
| |
| CC WIT CODE OF ANAlYSES III Bo AVERAGE CCNCBIIRATIONJ SANTE lYPEJ It OF ANALYSES LJ LJ WIT CXE NIT CODE Ca HAXIISJI CONCBIIRATICN A!O MASS Qt% OF CRITICAL HATERIAL OR PRIORllY POLLIJTAMT " Chlorine (Sodium H ochl !
| |
| IL WLT CCXJE SAIFLE TYPE OF ANALYSES III' BI AVKRJGE CCICEMTRATICNJ SANDIE TfPEJ tt OF ANALYSES LJ NIT COX WIT COKE CI MAXIJLH CCNCENIRATION AJO MASS UNITS CODE A>> NA% OF CRITICAL MATBUALCR FRICRllY RXLUTAMf 1 MQ/ I NIT OXE 54%LE TYPE F OF ANALYSES B. AYBLAGE cctcKMIRATICNJ senz TYPE; 1I DF ANALYSES UQ/I CJXE WIT CODE LBS/DAY KG/DAY Cs MAXIMP! CctCENllLATION At41 MASS LJ
| |
| ~~ ~
| |
| AI NA% OF CRITICAL MATERIAL OR PRIORllY POLUJTANT NIT CQJE SAINT lYPE OF ANALYSES BI AVERAGE COtCBIIRATICNJ QIANA lYPEJ 0 OF ANALYSES LJ NIT CCOE WIT CCOE CI HAXItMLCOtCIDI!RATICN AJO MASS LJ ~ LJ
| |
| ~~
| |
| ~AMP~LT Ae QP% OF CRITIQL HATERIAL CR PRICRllY FOLUJTANT 1 GRAB LNIT CCCE lYPE JJ OF ANALYSES 2 24 HR.COMP. Bo AVERAGE CNCBIIRATILXIJ QPRE TYPEJ JI OF ANCLYSES NIT CODE NIT CODE CI MAX&PI CCNCENIIIATICN AtO MASS LJ ~ LJ
| |
| ~~
| |
| AI SV% OF CRITICAL tVLTERIAL OR PRICRITY POLUJTANT III's BI AVKRAGE CCNCENIRATIONJ QIANA TYPES 0 CF AMJLYSES LJIIT LJ CCOE QJPLE TYPE OF ANALYSES WIT CODE WIT COCK C. HJNIJSJLCaLKMIILATICN AJO MASS LJ ~ LJ
| |
| ~~ ~
| |
| A Nt% OF CRITICAL MATERIAL OR PRIOR llY POUJJTANT QWlK TYPE CC B. AVERAGE CONCBCIRATICNJ SAMPLE TYPE,'J OF ANALYSES LLLJ LJIIT CXXE LJ WIT CODE OF ANALYSES LJIIT CODE C>> t%XIMPL CCCL'BIIRATION AtO HASS LJ ~ LJ
| |
| ~~
| |
| AI NAME OF CRITICAL MATERIAL OR PRIORITY FOUlJTANT NIT CJXE TYPE OF ANALYSES Bo AVERAGE COMCKM!ILATIONJ SANTE TYPE J JJ OF ANALYSES WIT CODE NIT CODE Cs MAXI'ctCBIIRATION AIO MASS LJ ~ LJ Hydrazine or Sodium Hypochlorite are not expected to be present in discharge but ACDITICNAL PJGES OF THIS ITEM 7 ARE ATTmm FOR TIB REST OF na CRITICAL Cl YES MATERIALS AJO/CR PRICRTIY POUltrAMTS RECUIRKD TD BE REPORTED. E NO small quantities may be found in the Turbine Room Sump but would not be expected to be found in the actual discharge flow to the absorption pond.
| |
| 39
| |
| | |
| INSTRUCTIONS FOR (XMPLETIIQ SECT ION I I ITEM 7 This form Is to be used by both surface and groundwater applicants to record Information on nny Hlchlgan critical mnterlnl, chemical E.P.A.
| |
| priority pollutant, or hazardous substance in which this application requires data to be provided. Listing This would Include ony substance trom the Michigan Critical Materials Register (Toble IV), the E.P.A. Priority Pollutant (Table V), or Tables IIA-YA which Ilats Organic Toxic Pollutants, Other Toxic Pollutants, Conventlonnl and Nonconventional Pollutants nnd Hazardous Substances.
| |
| ITEH 7 CRITICAL MATERIALS, PRIORITY POLLUTANTS AND/OR HAZARDOUS SUDSTANCES IN THE DISCHARGE Material I 2 3 ~ . . 8 A. List the nome of the chemlcol substance (critical material, priority pollutant, or hazardous substance) frrmr Tables Iyy V ond IIA-YA as required In the box <<hlch you checked In A.l 3 . above. Enter each chemical substancers,parameter number as listed In Tables IV, V and IIA-VA lf provided.
| |
| : 8. Provide the average concentration of the chemical substance named in A. Indicate the sample type used nnd the number of analyses mode to provide the concentration data for the chemical substance named In A.
| |
| C. Provide the maximum concentration nnd determine the mass loading of the chemical substance nrrrred In A.
| |
| NOTESr I. It only one analysis was mode for a chemical substance then record thnt data as n maximus,value. It more than one analysis hos been mode tor a chemical substance then provide an average value of those analyses nnd the maxim'alue.
| |
| : 2. This Section II, Item 7, Data Sheet provides space for recording dntn for 8 chemical substances (Materials) ~
| |
| Additional space for recording of data tor more thon 8 Materials can be made by making copies of this Item 7 Data Sheet as needed. It Is olso Important to use a separate set ot Onto Sheets for each applicable reporting requirement as listed In A.l-3. and for each outtall.
| |
| Refer to the left margin for the code number representing the sample type used and the appropriate unit codes.
| |
| 40
| |
| | |
| Lockheed Analytical Services INDIANA MICHICANPOWER COIWPANY SAMPLE ANALYSIS SUIVIIVIARY PACKAGE FOR VOLATILE AND SEMI-VOLATILE ORGANICS, PESTICIDE/PCBS, CHLORIDE, NITRATE/NITRITE, SULFATE, FLUORIDE, CYANIDE, IVIETALS, AND MERCURY LOG-IN NUMBER: L1009 QUOTATION NUMBER: Q331 620 DOCUMENT FILE NUMBER: 1229485
| |
| | |
| bloc/rheed Environmenta/ Systems 6 Techcgeyfe~ Co Lockheed Analytical Services Phone: (800) 361-0220 975 Kelly Johnson Drive Fax: (702) 361-6434 Las Vegas, Nevada 89119Q705 February 4, 1994 Mr. Rocky Beem Cook Nuclear Plant 1 Cook Place Bridgeman, Ml 49106 RE: Log-in No.: L1009 Quotation No.: Q331620 Document File No.: 1229485 The attached data package contains the results of analyses on samples that were submitted to Lockheed Analytical Services on December 29, 1993. The samples were received at 5'C.
| |
| | |
| ==SUMMARY==
| |
| ANALYSIS STATEMENT:
| |
| Inorganics All ground water samples were received in good condition on December 29, 1993. All samples were analyzed within the method-specific holding times. The method blanks were free of contamination.
| |
| All Internal Quality Control were within acceptance limits with the following exception: The matrix spike recoveries for barium and selenium were slightly outside of acceptance limits.
| |
| The acceptable recovery of the Laboratory Control Samples supports that the analytical systems were operating within control limits.
| |
| The reporting detection limit for nitrite was raised to 0.50 mg/L for sample S. Sewage Plant Eff. (L1009-4) due to interferences from chloride.
| |
| Organics Method 8260 All calibrations and quality control criteria were met with the following exceptions:
| |
| All samples were analyzed initially within holding times but failed surrogate recovery QC limits. The samples were reanalyzed one day beyond the method specified holding time and all samples met surrogate recovery QC limits. Tentatively identified compound searches were performed on all submitted samples. Only the reanalyses are reported.
| |
| | |
| 0 COOK NUCLEAR February 4, 1994 PAGE 2 Method 8010/8020 All calibrations and quality control criteria were met with the following exceptions:
| |
| The matrix spike and matrix spike duplicate precision for 1,1-dichloroethene exceeded the QC criteria although all percent recovery criteria were met. Data quality is not effected.
| |
| Method 8270 All samples were extracted and analyzed within the method specified holding time. All initial and continuing calibration criteria were met. Bis(2-ethylhexyl)phthalate was detected in the method blank at 1.3 ug/L. There was no other contamination detected in the method blank.
| |
| Percent recoveries for all surrogate compounds was within QC limits for all samples analyzed.
| |
| A laboratory control sample (LCS) and laboratory control sample duplicate (LCS DUP) was prepared and analyzed with this set of samples. The percent recovery criteria for all spiked compounds was within the QC limits as was the relative percent difference between the two.
| |
| The response for bis(2-ethylhexyl)phthalate in sample TRANS. CATCHBASIN exceeded the calibration range in the initial analysis. The sample was reanalyzed at a dilution of 1:4 and all compounds fell within the calibration range. Both sets of results are reported.
| |
| Method 8080 All samples were extracted and analyzed within the method specified holding time. All initial and continuing calibration criteria were met. No contamination was found in the method blank. Few of the surrogate spike recoveries were within the QC limits due to an apparent spiking solution problem. Data quality is not effected since all percent recovery criteria were met for the laboratory control sample and laboratory control sample duplicate. No target compounds were detected above the reporting detection limit and there was no dilution or reanalysis performed.
| |
| If you have any questions concerning the analysis or the data please do not hesitate to contact James L. Jordan, (702) 361-3955, ext. 289.
| |
| Release of this data report has been authorized by the Laboratory Director or the Director's designee as evidenced by the following signature.
| |
| James L. Jo dan Client Services Representative JLJ/at cc: Client Services Document Control Department
| |
| | |
| El bloc/r/reed Lockheed Analytical Services Phone: (800) 582-7605 975 Kelly Johnson Orive Fax: (702) 361 8146 Las Vegas. Nevada 891194705 February 17, 1994 Mr. Rocky Beem Cook Nuclear Plant 1 Cook Place Bridgman, Ml 49106
| |
| | |
| ==Dear Rocky,==
| |
| | |
| Per your request during our phone conversation this morning, the following is an explanation of the procedure used for the determination of the non-standard organic compounds in your groundwater samples.
| |
| The samples were analyzed using instruments that were set up for standard methods 8260 and 8270, A few of the compounds on your lists of analytes are not standard method 8260 or 8270 compounds. Once the samples are analyzed and a chromatogram was obtained for the samples, all peaks that were present in the samples that did not correspond to one of the calibrated compounds were investigated further. This involved taking the mass spectra obtained from these peaks and comparing the spectra to an NIST library of spectra. This library contains approximately 52,000 known mass spectra. The mass spectra of the additional analytes of interest to you are contained within this library. None of the non-standard analytes were detected in any of your samples.
| |
| For the next quarters round of sampling, we are endeavoring to obtain the standards for these compounds so that they will be calibrated for in the analyses of those samples. If you have any further questions or if I can be of any further assistance, please do not hesitate to call me at (702) 361-1626 ex. 289.
| |
| 'ncerely, James L. rdan Project Manager cc: M. Butler
| |
| | |
| Lockheed Analytical Services DATA QUALIFIERS FOR INORGANIC ANALYSES
| |
| /Revised 08/28/92)
| |
| For Use on the Analytical Data Reporting Forms For CLP Analyses Only Reported value is less than the contract required detection limit (CRDL) but greater than or equal to the instrument detection limit (IDL).
| |
| For Routine, Non-CLP Analyses Only Any constituent that was also detected in the associated blank whose concentration was greater than the reporting detection limit (RDL).
| |
| D Presence of high levels of interfering constituents required dilution of sample which increased the RDL by the dilution factor.
| |
| E Estimated value due to presence of interference.
| |
| Sample analysis performed outside of method-or client-specified maximum holding time requirement.
| |
| For CLP Analyses Only Duplicate injection precision criterion was not met.
| |
| N Matrix spike recovery exceeded acceptance limits.
| |
| Reported value was determined from the method of standard addition.
| |
| For CLP Reporting Only Constituent was analyzed for but not detected (sample quantitation must be corrected for dilution and percent moisture).
| |
| For AAS Only Post-digestion spike for Furnace AAS did not meet acceptance criteria and sample absorbance is less than 50% of spike absorbance.
| |
| X, Y,orZ Analyst-detined qualifier.
| |
| Relative percent difference (RPD) for duplicate analysis exceeded acceptance limits.
| |
| Correlation coefficient (r) for the MSA is less than 0.995.
| |
| For Use on the QC Data Reporting Forms The spike recovery and/or RPD for matrix spike and matrix spike duplicates cannot be evaluated due to insufficient spiking level compared to the elevated sample analyte concentration.
| |
| The RPD cannot be computed because the sample and/or duplicate concentration was below the RDL.
| |
| 'sed as footnote designations on the QC summary form.
| |
| | |
| Lockheed Analytical Services DATA QUALIFIERS FOR ORGANIC ANALYSES (Revised 04/20/93J For Use on the Analytical Data Reporting Forms For CLP analyses Only The TIC is a suspected aldol-condensation product.
| |
| Any constituent that was also detected in the associated blank whose concentration was greater than the practical or reporting detection limit (PQL or RDL).
| |
| Constituent contirmed by GC/MS analysis. (pesticide/PCB analyses only/
| |
| D Constituent detected in the diluted sample. It also indicates that an accurate quantitation is not possible due to ~surr i~ate. being diluted out of the samples during the course of the analysis.
| |
| Constituent concentration exceeded the calibration range.
| |
| The quantitation is not gasoline or diesel but believed to be some other combination of hydrocarbons.
| |
| Sample analysis performed outside of method- or client-specified maximum holding time H requirement.
| |
| Estimated value (I) constituent detected at a level less than the RDL or PQL and greater than or equal to the MDL; (2) estimated concentration for TICs (For CLP Reporting Only).
| |
| For CLP Reporting Only Tentatively identified constituents (TICs) identified based on mass spectral library search.
| |
| For CLP Reporting Only The percent difference between the concentrations detected on both GC columns was greater than 25 percent (pesticide/PCB analyses only).
| |
| For CLP Reporting Only Constituent was analyzed for but not detected (sample quantitation must be corrected for dilution and percent moisture).
| |
| X, Y,orZ Analyst-detined qualitier.
| |
| For Use on -the QC Data Reporting Forms QC data (i.e.. percent recovery data for matrix spike, matrix spike duplicate, laboratory
| |
| <<iintrol standard. or surrogates: and RPD for matrix spike duplicate or unspiked duplicate) exceeded acceptance limits.
| |
| The spike recovery and/or RPD for matrix spike and matrix spike duplicates cannot be nI evaluated due to insufficient spiking level compared to the, elevated sample analyte concentration.
| |
| hl The RPD cannot he computed because the sample and/or duplicate concentration was below the RDL.
| |
| Use as tootnote t esignations on the summary torm.
| |
| | |
| VOLATILE ORGANIC ANALYSIS RESULTS GC/HALL ANALYSES USING EPA METHOD 8010 lin am I ID: TR LAL m I ID: L1 D II d: 2 -DE D R ive: 2-DE-Date Anal zed: 04-JAN-94 Dilution Factor: 1 Matrix: WATER QC Batch ID: 122093-801020-0-3 Anal tical Batch ¹: 122093-801020-0-3 rr a Re ver o Limi BCM 114 65-125 BFB 92 60-120 Reporting Constituent Concentration Detection Limit Data
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| (/Jg/L) /L Qualifier(sl Dihl r difl r m hne hlrm hn Vin I chloride <0.50 0.5 Bromomethane hlr hn Tri hl r fl r m han 1 1-Dichloroethene <3 Meth lene chloride <6 r n -1 2-Di hl r h n 11-Dihl r h n Chloroform 1 1 1-Trichloroethane <4 ar n r hl ri e 12-Dihl r hn Trichloro ethene TCE 1 2-Dichloro ro ane <0.5 0.5 Br mo i hl r m han 2- hlr hlvinl hr cis-1 3-Dichloro ro ene trans-1 3-Dichloro ro ene 112-Trihl r hn T r hlr hn P E Dibromochlorome hane Chlorobenzene <0.5 0.5 Br mof rm 1122T r hl r hn 1 3-Dichlorobenzene <2 1 4-Dichlorobenzene 1 2-Dichlorobenzene LOCKHEED ANALYTICALSERVICES A
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| V~
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| VOLATILE ORGANIC ANALYSIS RESULTS GC/PID ANALYSES USING METHOD 8020 lin m I ID: TR AL ml ID: L1 D II -DE D R iv: 29 DE Date Anal zed: 04-JAN-94 Dilution Factor: 1 Matrix: WATER QC Batch ID: 122093-801020-0-3 Anal tical Batch ¹: 122093-801020-0-3 rr a R ver Limi TFT 94 70-120 BFB 95 75-120 Reporting Concentration Detection Limit Data Constituent /L /L Qualifier s Benzene 0.52 0.5 Tol n hl r nz n Eth I Benzene m -X lene <2
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| -X len 1 -Dihl r nz n <2 1 4-Dichlorobenzene 1 2-Dichlorobenzene <2 LOCKHEED ANALYTICALSERVICES u4
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| VOLATILE ORGANIC ANALYSIS RESULTS GC/HALL ANALYSES USING EPA METHOD 8010 D
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| lin II:
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| ml ID: TR- A 2 -DE Date Anal zed: 04-JAN-94 D
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| AL R
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| m I ID:
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| iv:
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| Dilution Factor: 1 Ll 2 -D Matrix: WATER QC Batch ID: 122093-801020-0-3 Anal tical Batch ¹: 122093-801020-0-3 urro a R vr QC Limi BCM 120 65-125 BFB 86 60-120 Concentration Reporting Constituent Detection Limit Data (yg/L) /L Qualifier(s)
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| Dihl r ifl r m hne hlrm hn Vin I chloride < 0.50 0.5 Bromomethane hlr hn Trihl r fl 'r m h n 1 1-Dichloroethene <3 Meth Iene chloride <6 rn-12-Dihl r hn 11-Dihl r hn Chloroform 1 1 1-Trichloroethane <4 r n r hl rid 12-Dihl r hn Trichloroethene TCE 1 2-Dichloro ro ane <0.5 0.5 Brm ihlrm hn 2- hlr hlvinl hr cis-1 3-Dichloro ro ene trans-1 3-Dichloro ro ene 1 1 2-Tri hl r han Terahlr hn P E Dibromochloromethane Chlorobenzene <0.5 0.5 Brmfrm 1 1 2 2-T r hl r h n 1 3-Dichlorobenzene <2 1 4-Dichlorobenzene 1 2-Dichlorobenzene LOCKHEED ANALYTICAL SERVICES nr.
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| 1J V
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| VOLATILE ORGANIC ANALYSIS RESULTS GC/PID ANALYSES USING METHOD 8020 D
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| lin II:
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| ml ID: TR-2 -D Date Anal zed: 04-JAN-94 A LAL am Da R I ID; L1 iv:
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| Dilution Factor: 1 2 -DE -9 Matrix: WATER QC Batch ID: 122093-801020-0-3 Anal tical Batch 4: 122093-801020-0-3 rr a Re v r Q Limi TFT 97 70-120 BFB 97 75-120 Reporting Concentration Detection Limit Data Constituent IL IL Qualifier s Benzene 0.53 0.5 T I n hlr nzn Eth I Benzene m -X lene <2
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| -X I n 1 -Di hl r b nz n <2 1 4-Dichlorobenzene 1 2-Dichlorobenzene <2 LOCKHEEO ANALYTICAL SERVICES hg
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| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 1 of 2 li n m I ID: TRS LAL m I ID: L1 -41 Date Collected: 28-DEC-93 Date Received: 29-DEC-93 Matrix: WATER Date Anal zed: 11-JAN-94 An I i IB h¹: 11 4- 2 -F2 Dil inF r: 1 QC Batch ID: 011094-8260-F2 SURROGATE RECOVERY QC Limits 12-Dihl r h n -d4 4 7 -114 TI n-4-Bromofluorobenzene 88 86-115 Reporting Concentration Detection Limit Constituent IL IL Data Qualifier s Chloromethane <5 Vin I hl ri Brmm hn Chloroethane <5 Trichlorofluoromethane <5 A n 11-Dihl r h n Carbon Disulfide <5 Meth lene Chloride <5 ran -1 2-Dichl ro h n Vin IAc ae <10 1 1-Dichloroethane <5 2-Buta none <10 10 is-1 2-Di hl r h n hlrf rm 1 1 1-Trichloroethane <5 Carbon Te rachloride <5 12-Dihl r hn B nz n Trichloroethene TCE <5 1 2-Dichloro ro ane <5 Brom ihl r m hn 2- hl r hIVin I hr <2 4-Meth I entanone <10 10 cis-1 3-Dichloro ro ene <5 Tol n r n-1 -Dihl r r n 2-Hexanone <10 10 1 1 2-Trichloroethane <5 Tetrachloroethene PCE <5 LOCKHEED ANALY jICAL SERVICES lu
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| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 2 of 2 Client Sam le ID: TRS LAL Sam le ID: L1009-41 Reporting Concentration Detection Limit Constituent IL IL Data Qualifier s Dibromochloromethane <5 Chl r nz n Ehl n n m -X lene <5 o-X lene <5 r n Br mof rm 1 1 2 2-Tetrachloroethane <5 1 3-Dichlorobenzene <5 14-Dihl r nz n 1 2-Dichlorobenzene <5 LOCKHEED ANALYTICAL SERVICES
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| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 TENTATIVELYIDENTIFIED COMPOUNDS Client Sample ID: TRS LAL Sample ID: L1009-41 Date Received: 29-DEC-93 Date Analyzed: 11-JAN-94 Matrix: WATER Dilutiorl Factor: 1 Analytical Batch: 011094-8260-F2 QC Batch ID: 011094-8260-F2 Estimated Retention Concentration Time Data Tentatively Identified Compound (yg/L) (minutes) Qualifier(sl NONE (10 0.00 LOCKHEED ANALYTICALSERVICES
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| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 1 of 2 lin ml ID: TR - A LAL m le ID: L1 -43 Date Collected: 28-DEC-93 Date Received: 29-DEC-93 Matrix: WATER Date Anal zed: 11-JAN-94 An I i IB h¹: 11 4- -F Dil i nF r: 1 QC Batch ID: 011094-8260-F2 SURROGATE RECOVERY QC Limits 1 2-Dichloroe han -d4 7 -114 TI n-4-Bromofluorobenzene 89 86-115 Reporting Concentration Detection Limit Constituent IL IL Data Qualifier s Chloromethane <5 Vin I hl ri Br mom han Chloroethane <5 Trichlorofluorom ethane <5 A n 11-Dihl r hn Carbon Disulfide <5 Meth lene Chloride <5 rn-1 -Dihl r hn Vin I A 1 1-Dichloroethane <5 2-Butanone <10 10 i-12-Dihl r h n hlor f rm 1 1 1-Trichloroethane <5 Carbon Tetrachloride <5 12-Dihl r hn B nz n Trichloroethene TCE <5 1 2-Dichloro ro ane <5 Brom ihl r m hn 2- hl r h I Vin I E h r <2 4-Meth l entanone <10 10 cis-1 3-Dichloro ro ene T I n r n-1 -Dihl r r ne 2-Hexanone <10 10 1 1 2-Trichloroethane <5 Tetrachloroethene PC E <5 LOCKHEED ANALYTICALSERVICES IB
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| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING IVIETHOD 8260 Page 2 of 2 Client Sam le ID: TRS-QA LAL Sam le ID: L1009-43 Reporting Concentration Detection Limit Constituent IL IL Data Qualifier s Dibromochloromethane <5 hl r enz n Ehl nzn m -X lene o-X lene <5 r n Brmfrm 1 1 2 2-Tetrachloroethane <5 1 3-Dichlorobenzene <5 1 4-Di hl r enz n 1 2-Dichlorobenzene <5 LOCKHEED ANALYTICALSERVICES
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| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 TENTATIVELYIDENTIFIED COMPOUNDS Client Sample ID: TRS-QA LAL Sample ID: L1009-43 Date Received: 29-DEC-93 Date Analyzed: 11-JAN-94 Matrix: WATER Dilution Factor: 1 Analytical Batch: 011094-8260-F2 QC Batch ID: 011094-8260-F2 Estimated Retention Concentration Time Data Tentatively Identified Compound Ipg/L) (minutes) Qualifieris)
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| NONE (10 0.00 LOCKHEED ANALYTICALSERVICES
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| SEMIVOLATILE ORGANIC ANALYSIS RESULTS
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| ,FOR GC/MS ANALYSES USING METHOD 8270 P 1 f2 lin m I ID: TR LAL m I ID: L1 -2 Date Collected: 28-DEC-93 Date Received: 29-DEC-93 Matrix: WATER Dilution Factor: 1 Anl i IB h¹: 111 4- 27 -8 D Exra: 4- AN- 4 QC Batch ID: 8270-SEMIVOLATILES-3964 Date Anal zed: 11-JAN-94 RR ATE RE VERY 0/
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| QC Limits 2-Fluoro henol 41 21-100 Phenol-d, 26 10-94 Nitrobenzene-d~ 59 35-114 2-Fluorobi hen I 55 43-116 246-Tri r m hn I 1 -12 p-Terphenyl-d,4 99 33-141 Reporting Concentration Detection Limit on i uen L L D Phenol <10 10 bis 2-Chloroeth I ether <10 10 2- hlr hnl 1 -Dihl r n n 1 4-Dichlorobenzene <10 10 Benz I alcohol <10 10 1 2-Di hl r nz n 2-'M h I h n I bis 2-Chloroiso ro I ether <10 10 4-Meth I henol <10 10 N-Ni r -Di-n- r I min Hx hlr hn Nitrobenzene <10 10 Iso horone <10 10
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| -Ni r h n I 2 4-Dime h I h n I Benzoic acid <50 50 bis 2-Chloroethox methane <10 10 4-Dihl r hn I 1 24-Tri hl r nz n Na hthalene <10 10 4-Chloroaniline <10 10 Hx hlr in 4- hlr--m hlhnl 2-Meth Ina hthalene <10 10 Hexachloroc clo entadiene <10. 10 LOCKHEED Ah/ALYTICALSERVICES 4w
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| SEIVIIVOLATILEORGANIC ANALYSIS RESULTS FOR GC/IVIS ANALYSES USING METHOD 8270 P 2 f2 Client Sam le ID: TRS LAL Sam le ID: L1009-25 Reporting Concentration Detection Limit Constituent IL) ( IL) Data Qualifier(s) 24 -Trihl r hn I 4 -Trihl r h n I 2-Chlorona hthalene <10 10 2-Nitroaniline <25 25 Dim h I hhal A n hhln 2 6-Dinitrotoluene <10 10 3-Nitroaniline <25 25 A n hhn 2 4-Dini r henol <25 25 4-Nitro henol <25 25 Dibenzofuran <10 10 2 4-Dini r I n Di h I hh I 4-Chloro hen I- hen lether <10 10 Fluorene <10 10 4-Ni r nilin <2 4 -Dinir -2m h I h n I <2 N-Nitrosodi hen lamine <10 10 4-Bromo hen I- hen lether <10 10 Hx hlr nzn Pn hlr hnl <2 Phenanthrene <10 10 Anthracene <10 10 Di-n- I hh I 1.4 Fl r nhn P rene <10 10 But Ibenz I hthalate <10 10
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| '-Di hl r nzi in <2 8 nzo n hr n <10 Chr sene <10 10 bis 2-Eth )hex I hthalate 1.5 10 J B Di-n- I hh I Bnz fl rnhn 10 Benzo k fluoranthene <10 10 Benzo a rene <10 '10 In n 12 -c r ne Di nz h n hr n Benzo h i er lene <10 10 Carbazole <10 10 LOCKHEED ANALYTICALSERIIICES 30
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| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8270 TENTATIVELYIDENTIFIED COMPOUNDS Client Sample ID: TRS LAL Sample ID: L1009-25 Date Received: 29-DEC-93 Date Analyzed: 11-JAN-94 Matrix: WATER Dilution Factor: 1 Analytical Batch: 011194-8270-8 QC Batch ID: 8270-SEMIVOLATILES-3964 Estimated Retention Concentration Time Data Tentatively Identified Compound (pg/L) (minutes) Qualifier(s)
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| Unknown 100 6.44 Unknown 20 30.26 LOCKHEED AIVALYTICAL SERVICES 3L
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| SEIVIIVOLATILEORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 P 1 f2 lin ml ID: TR - A LAL m le ID: L10 -27 Date Collected: 28-DEC-93 Date Received: 29-DEC-93 Matrix: WATER Dilution Factor: 1 An I i IB hA': 111 4- 27 -B QC Batch ID: 8270-SEMIVOLATILES-3964 Da Ex r c: 04-JAN- 4 Date Anal zed: 11-JAN-94 RR ATE RE VERY 0 Limi 2-Fluoro henol 38 21-100 Phenol-d, 26 10-94 Nitro benzene-d, 61 35-114 2-Fluorobi hen I 56 43-116 2 4 6-Tribromo h nol 1 -12 p-Terphenyl-d 97 33-141 Reporting Concentration Detection Limit n i n L L D Phenol <10 10 bis 2-Chloroeth I ether <10 10 2- hl r hn I 1 -Di hl r nz n 1 4-Dichlorobenzene <10 10 Benz I alcohol <10 10 12-Dihl r nz n 2-M h I h n I 10 bis 2-Chloroiso ro I ether <10 10 4-Meth I henol <10 10 N-Ni r -Di-n- r I min Hx hlr hn Nitrobenzene <10 10 Iso horone <10 10 2-Nir h n I 24Dim h I hn I Benzoic acid <50 50 bis 2-Chloroethox me hane <10 10 24-Dihl r hn I 1 2 4-Tri hl r nz n Na hthalene <10 10 4-Chloroaniline <10 10 Hx hlr in 4- hlr--m hlhnl 2-Meth Ina hthalene <10 10 Hexachloroc clo entadiene <10 10 LOCKHEED ANALYTICALSERVICES 2
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| SEIVIIVOLATILEORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 P 2 f2 Client Sam le ID: TRS-OA LAL Sam le ID: L1009-27 Reporting Concentration Detection Limit Constituent I IL) ( ILI Data Qualifier(si 24 -Trihl r h n I 24 -Trihl r hn I <10 10 2-Chlorona hthalene <10 10 2-Nitroaniline <25 25 Dim h I hh I A n hhln 2 6-Dinitrotoluene <10 10 3-Nitroaniline <25 25 A n h hen <10 24-Dinir h n I <2 4-Nitro henol <25 25 Dibenzofuran <10 10 2'4-Dini r I n <10 Di hi hhl 4-Chloro hen I- hen lether <10 10 Fluorene <10 10 4-Ni r anilin <2 4 -Dinir -2m h I h n I N-Nitrosodi hen lamine <10 10 4-Bromo hen I- hen lether <10 10 Hx hlr nzn Pn hl n I Phenanthrene <10 10 Anthracene <10 10 Di-n- I hh I Fl r nhn P rene <10 10 But Ibenz I hthalate <10 10
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| '-Di h r nzi in <2 B nz nhr n 10 Chr sene <10 10 bis 2-fth Ihex I hthalate 1.9 10 J 8 Di-n- I hh I 10 Bnz fl rnhn Benzo k fluoranthene <10 10 Benzo a rene <10 10 In en 12 ren 10 Di enz a h an hr n Benzo h i er lene <10 10 Carbazole <10 10 LOCKHEEO ANALYTICALSERVICES
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| 0 VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8270 TENTATIVELYIDENTIFIED COMPOUNDS Client Sample ID: TRS-QA LAL Sample ID: L1009-27 Date Received: 29-DEC-93 Date Analyzed: 29-DEC-93 Matrix: WATER Dilution Factor: 1 Analytical Batch: 011194-8270-8 QC Batch ID: 8270-SEIVIIVOLATILES-3964 Estimated Retention Concentration Time Data Tentatively Identified Compound Iyg/L) I minutes) Qualifier(s)
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| Unknown 4 5.28 Unknown 100 6.44 Hydrocarbon 29.97 Unknown 20 30.26 Hydrocarbon 31.98 Hydrocarbon 32.94 Hydrocarbon 33.86 LOCKHEEO ANALYTICALSERIIICES
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| ".4
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| PESTICIDE ANALYSES RESULTS BY GC/ECD USING METHOD 8080 FOR COOK NUCLEAR PLANT Clien Sam te ID: TRS LAL Sam Ie ID: L1009-17 Da e Collec ed: 28-DEC-93 Da e R eived:29-JAN-94 Date Extracted: 04-JAN-94 Date Anal zed: 21-JAN-94 Matrix: WATER Dilution Factor: 1 Anal tical Batch ¹: 012094-8080-A-1 QC Grou ID: 8080 PEST/PCBS 3965 SURROGATE RECOVERY oo QC Limits TCMX 65 60-150 DCB 52 60-150 Reporting Constituent Concentration Detection Limit Data Qualifier(s)
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| IL IL A-BHC <0.05 0.05 B-BHC .0 0.
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| -BH D-BHC <0.05 0.05 HEPTACHLOR < 0.05 0.05 ALDRIN 0.05 HEPTACHLOR EPOXIDE <0.0 G-CHLORDANE <0.05 0.05 ENDOSULFAN I <0.05 0.05 A-CHLORDANE < .05 4 4'-DDE <0.1 4 4'-DDT <0.1 0.1 DIELDRIN <0.1 0.1 ENDRIN 0.1 ENDOSULFAN II 4 4'-DDD <0.1 0.1 ENDRIN ALDEHYDE <0.1 0.1 ENDO LFAN LFATE METHOXY HL R TOXAPHENE <5 PCB-1016 P B-1221 <2 PCB-12 2 PCB-1242 PCB-1248 PCB-12 4 PCB-12 0 TECHNICAL CHLORDANE MIREX <0.1 < 0.1 TCMX - tetra-chloro-meta-xylene DCB - Deca-chloro-biphenyl LOCKHEED ANALYTICALSERVICES 5f
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| PESTICIDE ANALYSES RESULTS BY GC/ECD USING METHOD 8080 FOR COOK NUCLEAR PLANT Clien S m le ID: TR -QA LAL S m I ID:L1009-19 Da e Collec ed: 28-DEC-93 Date Received:29-JAN-94 Date Extracted: 04-JAN-94 Date Anal zed: 21-JAN-94 Matrix: WATER Dilution Factor: 1 Anal tical Batch ¹: 012094-8080-A-1 QC Grou ID: 8080 PEST/PCBS 3965 SURROGATE RECOVERY QC Limits TCMX 60-150 DCB 46 60-150 Reporting Constituent Concentration Detection Limit Data Qualifier(s)
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| /L /L A-BHC <0.05 0.05 B-BHC
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| -BH D-BHC <0.05 0.05 HEPTACHLOR <0.05 0.05 ALDRIN <0.05 HEPTA HLOR EPOXIDE G-CHLORDANE <0.05 0.05 ENDOSULFAN I <0.05 0.05 A-CHLORDANE < .05 0.05 4 4'-DDE 4 4'-DDT < 0.1 0.1 DIELDRIN <0.1 0.1 ENDRIN < 0.1 ENDOSULFAN II 0.1 4 4'-DDD <0.1 0.1 ENDRIN ALDEHYDE < 0.1 0.1 ENDOSULFAN SULFATE METHOXYCHL R 0.
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| TOXAPHENE <5 PCB-1016 PCB-1221 <2 PCB-1232 PCB-1242 PCB-1248 P B-12 4 PCB-126 TECHNICAL CHLORDANE MIREX <0.1 <0.1 TCMX - tetra-chloro-meta-xylene DCB - Deca-chloro-biphenyl LOCKHEED ANALYTICALSERVICES 52
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| IVIETALS RESULTS Clie'n't Sam "le ID: TRS Date Collected: 12-28-93 Matrix: round'water LAL Batch ID(s): 1220 im Date Received: 12-29-93 P0¹69095-040-3N Reporting Concentration Detection Limit Data Data LAL Constituents: .' Meth'od .(m IL).. (m IL) Qualifier(s) Anal zed Sam le ID.
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| Aluminum 6010 <0.20 0.20 01-20-94 L1009-13 Antimon 6020 <0.060 0.060 01-27-94 L1009-13 Arsenic 6020 <0.010 0.010 01-27-94 L1009-13 Barium 6020 <0.20 0.20 01-27-94 L1009-13 Be Ilium 6020 <0.005 0.005 01-27-94 L1009-13 Boron 6010 0.28 0.20 01-20-94 L1009-13 Cadmium 6020 <0.005 0.005 01-27-94 L1009-13 Chromium 6020 <0.010 0.010 01-27-94 L1009-13 Cobalt 6020 <0.050 0.050 01-27-94 L1009-13 Co er 6020 <0.025 0.025 01-27-94 L1009-13 Iron 6010 <0.10 0.10 01-20-94 L1009-13 Lead 6020 <0.003 0.003 01-27-94 L1009-13 Ma nesium 6010 18 5.0 01-20-94 L1009-13 Man anese 6020 0.026 0.01 5 01-27-94 L1009-13 Mercu 7470 <0.0002 0.0002 01-07-94 L1009-13 Mol bdenum 6020 <0.20 0.20 01-27-94 L1009-13 Nickel 6020 <0.040 0.040 01-27-94 L1009-13 Selenium 6020 0.0055 0.005 01-27-94 L1009-13 Silver 6020 <0.010 0.010 01-27-94 L1009-13 Sodium 6010 900 5.0 01-20-94 L1009-1 3 Thallium 6020 <0.010 0.010 01-27-94 L1009-13 Tin 6020 <0.20 0.20 01-27-94 L1009-13 Titanium 6010 <0.10 0.10 01-20-94 L1009-13 Vanadium 6010 <0.050 0.050 01-20-94 L1009-13 Zinc 6020 <0.020 0.020 01-27-94 L1009-13 Comments:
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| LOCKHEED AIVALVTICALSERVICES
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| 0 METALS RESULTS
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| -Client Sam le ID: TRS-OA Date: Collected: 12-28-93 Matrix:. round water LAL Batch ID(s): 1220 im Date Received: 12-29-93 POP'69095-040-3N Reporting Concentration Detection Limit Oats Date LAL
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| :Constituents Method {r'n IL'l {m Ill Qualtfier{s) .Anal ied Sam'le ID" Aluminum 6010 <0.20 0.20 01-20-94 L1009-14 Antimon 6020 <0.060 0.060 01-27-94 L1009-14 Arsenic 6020 <0.010 0.010 01-27-94 L1009-14 Barium 6020 <0.20 0.20 N 01-27-94 L1009-14 Be Ilium 6020 <0.005 0.005 01-27-94 L1009-14 Boron 6010 0.27 0.20 01-20-94 L1009-14 Cadmium 6020 <0.005 0.005 01-27-94 L1009-14 Chromium 6020 <0.010 0.010 01-27-94 L1009-14 Cobalt 6020 <0.050 0.050 01-27-94 L1009-14 Co er 6020 <0.025 0.'025 01-27-94 L1009-14 Iron 6010 <0.10 0.10 01-20-94 L1009-14 Lead 6020 <0.003 0.003 01-27-94 L1 009-14 Ma nesium 6010 17 5.0 01-20-94 L1009-14 Man anese 6020 0.027 0.015 01-27-94 L1009-14 Mercu 7470 <0.0002 0.0002 01-07-94 L1009-14 Mol bdenum 6020 <0.20 0.20 01-27-94 L1009-14 Nickel 6020 <0.040 0.040 01-27-94 L1009-14 Selenium 6020 0.0078 0.005 N 01-27-94 L1 009-14 Silver 6020 <0.010 0.010 01-27-94 L1009-14 Sodium 6010 890 5.0 01-20-94 L1009-14 Thallium 6020 <0.010 0.010 01-27-94 L1009-14 Tin 6020 <0.20 0.20 01-27-94 L1009-14 Titanium 6010 <0.10 0.10 01-20-94 L1 009-14 Vanadium 6010 <0.050 0.050 01-20-94 L1009-14 Zinc 6020 0.022 0.020 01-27-94 L1009-14 Comments:
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| LOCKHEED ANALYTICALSERVICES
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| 0 0
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| GENERAL CHEMISTRY RESULTS Client Sam le ID: TRS Date Collected: 12-28-93 Matrix: round water LAL Batch ID(s): 1229 im Date Received: 12-29-93 PO¹69095-040-3N Reporting Data Date LAL Constituent Method Result Detection Limit Qualifierls) Anal zed Sam ie ID Fluoride, in m IL 340.2 0.29 0.15 01-24-94 L1 009-1 Chloride, in m IL 300.0 19 0.016 12-29-93 L1009-1 Nitrate-Nitro en, in m IL 300.0 0.91 0.01 7 1 2-29-93 L1 009-1 Nitrite.Nitro en, in m /L 300.0 <0.012 0.01 2 12-29-93 L1009-1 Sulfate, inm IL 300.0 2000 0.59 D(1:10) 12-29-93 L1009-1 Ammonia-Nitrogen, 350.1 3.4 0.050 01-05-94 L1009-5 in m /L Total Cyanide, in mg/L 335.2 <0.020 0.020 01-03-94 L1009-9 Comments:
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| LOCKHEED ANALYTICAL SERVICES 65
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| GENERAL CHEMISTRY RESULTS Client Sam le'ID: TRS-QA Date Collected: 12-28-93 Matrix: round water LAL Batch ID(s): 1229 im Date Received: 12-29-93 P0469095-040-3N Reporting Data Date LAL Constituent Method Result Detection Limit Qualifier(s) Anal zed Sam le ID Fluoride, in m IL 340.2 0.31 0.15 01-24-94 L1009-2 Chloride. in m IL 300.0 20 0.01 6 12-29-93 L1009-2 Nitrate-Nitro en, in m IL 300.0 0.90 0.01 7 12-29-93 L1009-2 Nitrite.Nitro en, in m IL 300.0 <0.012 0.01 2 12-29-93 L1009-2 Sulfate, in m IL 300.0 2200 0.59 D(1:10l 12-29-93 L1009-2 Ammonia-Nitrogen, 350.1 3,4 0.050 01-05-94 L1009-6 inm IL Total Cyanide, in mg/L 335.2 <0.020 0.020 01-03-94 L1009-10 Comments:
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| LOCKHEED ANALYTICALSERVICES
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| GENERAL CHEIVIISTRY QC DATA SUIVIIVIARY
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| . LAL Batch ID(s): 1229 im QC Sam le Anal ses.
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| Matrix Duplicate: Spike Client L'AL Date Reagent Precision 'eco'very Constituent- 'Sample'D Sample Analyzed Blank (9o RPD) (%)
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| ID Fluoride, in m /L TRS L1 009-1 01-24-94 <0.15 107 Chloride, in m /L TRS L1 009-1 1 2-29-93 '<0.016 0.2 91 Nitrate-Nitrogen, TRS L1 009-1 1 2-29-93 < 0.01 7 93 in m /L Nitrite-Nitro en, in m /L TRS L1 009-1 12-29-93 <0.012 96 Sulfate, in m /L TRS L1 009-1 12-29-93 < 0.059 0.1 96 Ammonia-Nitrogen, TRS L1 009-5 01-05-94 <0.050 0 122 in m /L Total Cyanide, in mg/L TRS L1 009-9 01-03-94 < 0.020 94 "b" - The RPD cannot be computed, because the sample or the duplicate concentration was below the Detection Limit.
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| Comments:
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| LOCKHEED ANALYTICALSERVICES
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| NUS LABORATORY Two Marquis Office Plaza, Suite 200 on NUS 5313 Campbells Run Road a~aaw~~ C 0 R P 0 R AT I0 N Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Report Ho.: 00018939 Section A Page 1 LABORATORY ANALYSIS REPORT CLIENT NAME: INDIANA MICHIGAN POWER COMPANY HUS CLIENT NO: 0663 0020 ADDRESS: ONE COOK PLACE 'WORK ORDER NO: 55830 BRIDGMAN, Ml 49106-0000 VENDOR NO: 05411000 ATTENTION: MS. JENI LEWIS - CHEMISTRY DEPT.
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| Carbon Copy:
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| SAMPLE ID: TURBINE ROOM SUMP 27476 DATE SAMPLED: 30-DEC-93 HUS SAMPLE NO: P0259284 DATE RECEIVED: 05-JAN-94 P.O. NO.: 69034-040.3N APPROVED BY: Kieda, Chuck TEST LH CODE DETERMINATION RESULT UNIT 1 I 730 Sulfate, Turbidimetric (as S04) 51 mg/L 2 AHA'W Sodiun, Total (Na) 6.3 mg/L 3 I130 Chloride (as Cl) 11 mg/L 4 I590 Solids, Dissolved at 180C 140 mg/L 5 AALW Atunintm, Total (Al) 0.97 mg/L COMMENTS:
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| NUS LABORATORY Two Marquis Office Plaza, Suite 200 I~~~ HBSUft011
| |
| /dh NUS 5313 Campbells Run Road C P R P P R AT IP N Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Report Ho.: 00018939 Section A Page 2 LABORATORY ANALYSIS REPORT CLIENT NAME: INDIANA MICHIGAN POWER COMPANY NUS CLIENT NO: 0663 0020 ADDRESS: OHE COOK PLACE WORK ORDER NO: 55830
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| .BRIDGMAN, Ml 49106-0000 VENDOR HO: 05411000 ATTENTIOH: MS. JENI LEWIS - CHEMISTRY DEPT.
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| Carbon Copy:
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| SAMPLE ID: TURBINE ROOM SUMP 27476 / FILTERED DATE SAMPLED: 30.DEC-93 HUS SAMPLE HO: P0259285 DATE RECEIVED: 05-JAH-94 P.O. HO.: 69034-040-3N APPROVED BY: Kieda, Chuck TEST LN CODE DETERMIHATIOH RESULT UNITS 1 AALF Atuninun, Dissotved (At) 0.3 mg/L COMME HTS:
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| .". Halliburton
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| +++ C 0 R P 0 R AT NUS I 0 N NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Report No.: 00018939 Section A Page 3 LABORATORY ANALYSIS REPORT CLIENT NAME: INDIANA MICHIGAN POWER COMPANY NUS CLIENT NO: 0663 0020 ADDRESS: ONE COOK PLACE WORK ORDER HO: 55830 BRIDGMAN, MI 49106-0000 VENDOR NO: 05411000 ATTEHTION: MS. JENI LEWIS - CHEMISTRY DEPT.
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| Carbon Copy:
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| SAMPLE ID: TURBINE ROOM SUMP 27503 DATE SAMPLED: 31.DEC-93 NUS SAMPLE NO: P0259286 DATE RECEIVED: 05-JAN-94 P.O. NO.: 69034-040-3N APPROVED BY: Kieda, Chuck TEST LN CODE DETERMI HAT IOH RESULT UNITS 1 I730 Sulfate, Turbidimetric (as S04) 53 mg/L 2 AHAW Sodiun, Total (Na) 6.0 mg/L 3 I 130 Chloride (as Cl) 10 mg/L 4 I590 Solids, Dissolved at 180C 130 mg/L 5 AALW Atuninun, Total (Al) 0.98 mg/L COMMEHTS:
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| .-: H<b~on
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| ++++ C 0 R P 0 R AT
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| ~S I 0 N NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pit tsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Report No.: 00018939 Section A Page 4 LABORATORY ANALYSIS REPORT CLIENT NAME: INDIANA MICHIGAH POWER COMPANY NUS CLIENT NO: 0663 0020 ADDRESS: ONE COOK PLACE WORK ORDER NO: 55830 BRIDGMAH, MI 49106.0000 VENDOR HO: 05411000 ATTENTION: MS. JEHI LEWIS - CHEMISTRY DEPT.
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| Carbon Copy:
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| SAMPLE ID: TURBINE ROOM SUMP 27503 / FILTERED DATE SAMPLED: 31-DEC.93 HUS SAMPLE NO: P0259287 DATE RECEIVED: OS-JAN.94 P.O. HO.: 69034-040-3H APPROVED BY: Kieda, Chuck TEST LN CODE DETERMINATION RESULT UNITS
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| ,1 AALF Atminun, Dissolved (At) 0.3 mg/L COMMENTS:
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| NUS LABORATORY i'Halliburton NUS I+++ C 0 Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road R P 0 R AT I 0 N Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Report No.: 00018939 Section A Page 5 LABORATORY ANALYSIS REPORT CLIENT NAME: INDIANA MICHIGAN POWER COMPANY NUS CLIENT NO: 0663 0020 ADDRESS: OHE COOK PLACE WORK ORDER NO: 55830 BRIDGMAN, MI 49106-0000 VENDOR NO: 05411000 ATTENTION: MS. JENI LEWIS - CHEMISTRY DEPT.
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| Carbon Copy:
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| SAMPLE ID: TURBINE ROOM SUMP 27506 DATE SAMPLED: 01-JAN.94 NUS SAMPLE NO: P0259288 DATE RECEIVED: 05-JAH 94 P.O. NO.: 69034-040-3N APPROVED BY: Kieda, Chuck TEST LN CODE DETERMIHATIOH RESULT UNITS 1 I 730 Sulfate, Turbidimetric (as S04) 52 mg/L 2 AHAW Sodiua, Total (Ha) 5.6 mg/L 3 1130 Chloride (as Cl) 10 mg/L 4 I 590 Solids', Dissolved at 180C 130 mg/L 5 AALW Atuninun, Total (Al) 1.6 mg/L COMMENTS:
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| NUS LABORATORY h: Halliburton NUS Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road CORPORATION Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (4'12) 747-2684 January 18, 1994 Report Ho.: 00018939 Section A Page LABORATORY ANALYSIS REPORT 6'L IENI'AME: IND IAHA MICHIGAN POWER COMPANY NUS CLIEHT HO: 0663 0020 ADDRESS: ONE COOK PLACE WORK ORDER HO: 55830 BRIDGMAN, MI 49106-0000 VEHDOR NO: 05411000 ATTENTION: MS. JEHI LEWIS - CHEMISTRY DEPT.
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| Carbon Copy:
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| SAMPLE ID: TRUBIHE ROOM SUMP 27506 / FILTERED DATE SAMPLED: 01-JAH-94 HUS SAMPLE NO: P0259289 DATE RECEIVED: 05-JAH-94 P.O. NO.: 69034-040-3H APPROVED BY: Kieda, Chuck TEST LN CODE DETERMINATION RESULT UNITS 1 AALF Alumina, Dissolved (At) 0.2 mg/L COMMENTS:
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| NUS LABORATORY AL I+ Halliburton C 0 R P 0 R AT I 0 N NUS Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Report No.: 00018939 Section A Page 7 LABORATORY ANALYSIS REPORT CLIENT NAME: INDIANA MICHIGAN POWER COHPANY NUS CLIENT NO: 0663 0020 ADDRESS: ONE COOK PLACE WORK ORDER NO: 55830 BRIDGHAN, Hi 49106-0000 VENDOR NO: 05411000 ATTENTION: HS. JENI LEWIS - CHEMISTRY DEPT.
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| Carbon Copy:
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| SAMPLE ID: TURBINE ROOH SUHP 27509 DATE SAMPLED: 02-JAN-94 NUS SAHPLE NO: P0259290 DATE RECEIVED: 05-JAN-94 P.O. NO.: 69034-040-3N APPROVED BY: Kieda, Chuck TEST LN CODE DETERHINATION RESULT UNITS 1 1730 Sulfate, Turbidimetric (as SO4) 51 mg/L 2 ANAW Bedizen, Total (Na) 5.9 mg/L 3 1130 Chloride (as Cl) 10 mg/L 4 I 590 Solids, Dissolved at 180C 140 mg/L 5 AALW Atuninun, Total (Al) 1.5, mg/L 6 I490 pN 7.6 7 1700 Specific Conductance at 25C 300 umhos/cm COHHENTS:
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| NUS LABORATORY I+ on gJS Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road C 0 R P 0 R AT I 0 N Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Report No.: 00018939 Section A Page 8 LABORATORY ANALYSIS REPORT CLIENT NAME: INDIANA HICNIGAN POWER COHPANY NUS CLIENT NO: 0663 0020 ADDRESS: ONE COOK PLACE WORK ORDER NO: 55830 BRIDGHAN, Hl 49106-0000 VENDOR NO: 05411000 ATTENTION: MS. JENI LEWIS - CHEHISTRY DEPT.
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| Carbon Copy:
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| SAHPLE ID: TURBINE ROOH SUHP 27509 / FILTERED DATE SAMPLED: 02-JAN-94 NUS SAHPLE NO: P0259291 DATE RECEIVED: 05-JAN-94 P.O. NO.: 69034-040-3N APPROVED BY: Kieda, Chuck TEST LN CODE DETERHINATION RESULT UNITS 1 AALF. Atuninun, Dissotved (At) 0.3 mg/L COHMENTS:
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| NUS LABORATORY
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| /4L:
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| +
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| Halliburton NUS Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road C 0 R P 0 R AT I 0 N Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Report No.: 00018939 Section A Page 9 LABORATORY ANALYSIS REPORT CLIEHT NAME: INDIANA MICHIGAN POWER COMPANY NUS CLIENT HO: 0663 0020 ADDRESS: ONE COOK PLACE WORK ORDER NO: 55830 BRIDGMAN, MI 49106-0000 VENDOR NO: 05411000 ATTENTIOH: MS. JENI LEWIS - CHEMISTRY DEPT.
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| Carbon Copy:
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| SAMPLE ID: ABS POND COMP. DATE SAMPLED: 31-0EC.93 HUS SAMPLE NO: P0259292 DATE RECEIVED: 05-JAH 94 P.O. NO.: 69034-040-3H APPROVED BY: Kieda, Chuck TEST
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| .LN CODE DETERMIHATION RESULT UNITS 1 1730 Sulfate, Turbidimetric (as S04) 110 mg/L 2 ANAW Sodiun, Total (Ha) 28 mg/L 3 1130 Chloride (as Cl) 9 mg/L 4 1590 Solids, Dissolved at 180C 210 mg/L 5 AALW Atuninm, Total (Al) 0.33 mg/L COMMENTS:
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| NUS LABORATORY I++ on NU$ Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road C 0 R P 0 R AT I 0 N Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 1B, 1994 Report No.: 0001B939 Section A Page 10 LABORATORY ANALYSIS REPORT CLIENT NAME: INDIANA MICHIGAN POWER COMPANY NUS CLIENT No: 0663 0020 ADDRESS: ONE COOK PLACE WORK ORDER HO: 55030 BRIDGMAN, Ml 49106-0000 VENDOR NO: 05411000 ATTENTION: MS. JENI LEWIS - CHEMISTRY DEPT.
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| Carbon Copy:
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| SAMPLE ID: ABS POND COMP. / FILTERED DATE SAMPLED: 31-DEC.93 HUS SAMPLE NO: P0259293 DATE RECEIVED: 05-JAH.94 P.O. NO.: 69034-040-3N APPROVED BY: Kieda, Chuck TEST LN CODE DETERMINATION RESULT UNITS 1 AALF Atuninun, Dissotved iAI) 0.099 mg/L COMMENTS:
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| NUS LABORATORY
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| :4'. Halliburton NUS Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road
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| %%EN C 0 R P 0 R AT I 0 N Pit tsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Report Ho.: 00018939 Section A Page 11 LABORATORY ANALYSIS REPORT CLIENT NAME: INDIANA MICHIGAN POWER COMPANY HUS CLIENT HO: 0663 0020 ADDRESS: OHE COOK PLACE WORK ORDER NO: 55830 BRIDGMAN, Mi 49106-0000 VENDOR HO: 05411000 ATTENTION: MS. JENI LEWIS - CHEMISTRY DEPT.
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| Carbon Copy:
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| SAMPLE ID: ABS POHD COMP. DATE SAMPLED: 01-JAN 94 HUS SAMPLE HO: P0259294 DATE RECEIVED: 05-JAH-94 P.O. HO.: 69034-040-3N APPROVED BY: Kieda, Chuck TEST LN CODE DETERMIHATIOH RESULT UNITS 1 1730 Sulfate, Turbidimetric (as S04) 110 mg/L 2 AHAW Sodiun, Total (Na) 30 mg/L 3 I 130 Chloride (as Cl) 10 mg/L 4 I590 Solids, Dissolved at 180C 210 mg/L 5 AALW Aluminize, Total (Al) 0.35 mg/L COMMENTS:
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| NUS LASORATORY i:
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| I+++ Halliburton C 0 R P 0 R AT I 0 NUS N
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| Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Report No.: 00018939 Section A Page 12 LABORATORY ANALYSIS REPORT CLIENT NAME: INDIANA MICHIGAN POWER COMPANY HUS CLIENT NO: 0663 0020 ADDRESS: ONE COOK PLACE WORK ORDER HO: 55830 BRIDGMAN, Ml 49106-0000 VEHDOR NO: 05411000 ATTENTION: MS. JEHI LEWIS - CHEMISTRY DEPT.
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| Carbon Copy:
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| SAMPLE ID: ABS POND COMP. / FILTERED DATE SAMPLED: 01-JAN-94 HUS SAMPLE HO: P0259295 DATE RECEIVED: 05-JAN-94 P.O. HO.: 69034-040-3N APPROVED BY: Kieda, Chuck TEST LN CODE DETERMI NATION RESULT . UNITS 1 AALF Atuninua, Dissolved (At) 0.10 mg/L COMMENTS:
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| NUS LABORATORY Two Marquis Office Plaza, Suite 200 L: Halliburton NUS I+++ 5313 Campbells Run Road C 0 R P 0 R AT I 0 N Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Report No.: 00018939 Section A Page 13 LABORATORY ANALYSIS REPORT CLIENT NAME: INDIANA MICHIGAN POWER COMPANY NUS CLIENT NO: 0663 0020 ADDRESS: ONE COOK PLACE WORK ORDER HO: 55830 BRIDGMAH, MI 49106-0000 VENDOR NO: 05411000 ATTENTION: MS. JEHI LEWIS - CHEMISTRY DEPT.
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| Carbon Copy:
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| SAMPLE ID: ABS POND COMP. DATE SAMPLED: 02-JAN-94 NUS SAMPLE HO: P0259296 DATE RECEIVED: 05-JAN-94 P.O. NO.: 69034-040-3N APPROVED BY: Kieda, Chuck TEST LN CODE DETERMINATION RESULT UNITS 1 I 730 Sulfate, Turbidimetric (as S04) 100 mg/L 2 ANAW Sodiun, Total (Ha) 31 mg/L 3 1130 Chloride (as Cl) 10 mg/L 4 1590 So l i ds, Dissolved at 180C 190 mg/L 5 AALW Alumina, Total (Al) 0.5 mg/L 6 1700 Specific Conductance at 25C 400 umhos/cm COMMENTS:
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| .". Halliburton NUS I~~iC0R P 0R AT 0N I NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Report No.: 00018939 Section A Page 14 LABORATORY ANALYSIS REPORT CLIENT kAME: IHDIAHA MICHIGAN POWER COMPANY NUS CLIENT NO: 0663 0020 ADDRESS: ONE COOK PLACE WORK ORDER NO: 55830 BRIDGMAN, Mi 49106-0000 VENDOR NO: 05411000 ATTENTION: MS. JENI LEWIS - CHEMISTRY DEPT.
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| Carbon Copy:
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| SAMPLE ID: ABS POHD COMP. / FILTERED DATE SAMPLED: 02-JAN.94 NUS SAMPLE NO: P0259297 DATE RECEIVED: 05-JAH-94 P.O. HO.: 69034-040-3H APPROVED BY: Kieda, Chuck TEST LH CODE DETERMINATION RESULT UNITS 1 AALF Atuainun, Dissolved (At) 0.072 mg/L COMMENTS:
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| NUS LABORATORY
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| /4L'Halliburton
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| +++
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| NUS Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road C 0 R P 0 R AT I 0 N Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Report No.: 00018939 Section A Page 15 LABORATORY ANALYSIS REPORT CLIENT HAME: INDIANA MICHIGAN POWER COMPANY NUS CLIENT HO: 0663 0020 ADDRESS: OHE COOK PLACE WORK ORDER HO: 55830 BRIDGMAN, MI 49106-0000 VENDOR HO: 05411000 ATTENTIOH: MS. JEHI LEWIS - CHEMISTRY DEPT.
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| Carbon Copy:
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| SAMPLE ID: ABS POND COMP 66998 DATE SAMPLED: 03 JAN-94 NUS SAMPLE NO: P0259298 DATE RECEIVED: 05-JAN-94 P.O. NO.: 69034-040-3N APPROVED BY: Kieda, Chuck TEST LN CODE DETERMINATION RESULT UNITS 1 1 730 Sulfate, Turbidimetric (as SO4) 110 mg/L 2 ANAW Sodiun, Total (Na) 28 mg/L 3 1130 Chloride (as Cl) 10 mg/L 4 I590 Solids, Dissolved at 180C 190 mg/L 5 AALW Atuninua, Total (Al) 0.5 mg/L 8 I700 Specific Conductance at 25C 410 umhos/cm I
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| COMMENTS:
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| .". Hallibu1 CORPORATION ton NUS NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Report No.: 00018939 Section A Page 16 LABORATORY ANALYSIS REPORT CLIENT NAME: IHDIANA MICHIGAN POWER COMPANY NUS CLIENT NO: 0663 0020 ADDRESS: ONE COOK PLACE 'WORK ORDER NO: 55830 BRIDGMAH, MI 49106-0000 VENDOR NO: 05411000 ATTENTIOH: MS. JENI LEWIS - CHEMISTRY DEPT.
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| Carbon Copy:
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| SAMPLE ID: ABS POND COMP 66998 / FILTERED DATE SAMPLED: 03-JAN-94 NUS SAMPLE NO: P0259299 DATE RECEIVED: 05-JAN-94 P.O. HO.: 69034-040-3N APPROVED BY: Kieda, Chuck TEST LH CODE DETERMINATION RESULT UNITS 1 AALF Atuainua, Dissolved (Al) 0.088 mg/L COMMENTS:
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| SEE INSTRUCTIONS ON REVERSE SIDE SECTION II PERMIT NUMBER ~ NI ppp5827
| |
| ~OO E As LOCATION OF DISCHARGE ~~~ t ~EE~ v, ernss i~00 . Ee B N%
| |
| MA RECEIVLNL HATER (IEs GROINLNATER CR NA% OF QRFACE SA NI TAR Y ABS PON D C>> OO @XI DISCHARGE SEASCNALLY DISCHARGE LLF Ms CONTIIAK IO E)
| |
| LOCATION Ds IF YESe LISI'ISCNRGE PERIODS IQs / DAY HL, / DAY FLOW RATE WASTEWATER IRs DAY JZKSQQF Es LAND APPLICATION RALE NA INs HIe LLJ LJ ~ LLJ ~ LJ LLJ LJINs/NKs
| |
| ~ Q N 1 CONTACT COOUNG Fs TYPE OF HASLEHALER DISCNRGE U4 L3J LJ LJ LJ L-I 2 NONCONTACT G~ DISCNRGE SOELXAE (YEARLY AVERAGE)
| |
| HOURS/DAY ~4 svvlvsss 3
| |
| 4 COOL NG PROCESS SANITARY o ISCHARGE FUN E
| |
| lOTAL YEARLY
| |
| *13.505~1 5 STORMWATER DAILY HINIISH QQE DAILY HAXIISN 037 2 1 MGY Ls lIE NXDSN DISCNRGK FUN RATE TO SE AIIIHCRLZED IN PERIITe
| |
| ~LZpg p p 6 p IN I
| |
| ) LODE 3
| |
| MGD GPD Je As NXIILHDESIGN 9)
| |
| DISCNRGE FUN RATEs DESIGN 0.060 YOU USE 'KATER 1REAL%NL ACOITIVES TO lREAT YIR DISOHKO (LF N). COILS@ YO LTLH 3) px C1 ITEM Se N% FINCTICNs AEI OEHICAL CQSKSITICN OF THESE ALSIITIVESe Calcium 86K H ochlorite for F' 2 ae WATER TREATMENT ADDITIVES.
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| C>> N% AIEI AZCRESS OF H4MFACLLRERS OF LIAISE AIDITIVESe LINLLS CODE VAN WATERS AND ROGERS, INC.
| |
| 1 Mg/I L600 NORTON BUILDING SEATTLE, WASHINGTON 98104-156
| |
| ~
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| 2 Ug/I HINIISH INILS AVERAGE IN ITS NXIISN Ds EXPKTED DISCNRSE CQCEHIRATI(N OF ALOLTIVESe CLLK evevvvvs ssevv Total Residual Chlorine 0 ~, 0 ALOITIVE NA% LJ s ALIITIVE NA%
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| Es DO %XI TREAT l% DLSCNRGE lO ROTE ALOlT1VES?
| |
| Fs ISN'T IS lHK RBOVAL EFFLCL8CY AND DISCNRGE FRKLLKLCY7 IRSs/OAY DAYS/'HK.
| |
| ACOI TIVE NA%
| |
| LJ ALE ITIVE NA%
| |
| LLJ LJ ALOITIVE NA% LJ G, AS AN ATTACHMENT lO lHIS APPLLCATICN PROVIDE SPKIFIC HASQLIAN CR ACUATIC lOXICOUSLCAL DATA CR REFERENCE HHIOI ARE AVAIIASLE ND INRRQTLCN CN lHE RATE OF DKRAMTICN OF lIE PRXXCTS FCR EACH ALOITLVEi IYISDS Attached Calcium Hypochlorite is added to the mixed liquor and is used up prior to discharge.
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| 31
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| INSTRUCTIONS FOR COMPLETING SECTION I I ITEMS I ANO 2 This form requires Intormatlon on the feel I ity's discharge location, discharge schedule, volume f lov rate and water treatment additives.
| |
| ENTER THE PERMIT NUMBFR IN THE BOX AT THE TOP OF THIS FOFM. THE PERMIT NUMBER CAN BE FCUNO ON THE FRONT PAGE OF YOUR EXPIRING PERMIT . If this Is a nev or not previously permitted facility, then leave blank and a number wll I be assigned.
| |
| Enter the outta II number In space provided for each page o! Section II. For each Individual discharoe point a separate set of Section II forms must be filled out.
| |
| ITEM I DISCHARGE LOCATION SCHEDULE AIO FLOW RATES A. Enter the location of discharge, this should Include quarter-quarter section, quarter section, section. (own, and range.
| |
| B. List name of receIving water (if surface water discharge).
| |
| C. IndlCate whether taCi llty dlSChargeS On a SeaSOnal baSIS.
| |
| O. If yes, list discharge periods.
| |
| E. Provide the land application rates used or expected to be used In terms of Inches per hour, hout s per day, and Inches per v<<k ~
| |
| F~ Indicate the type of wastewater to be discharged from this outfall. Refer to the wastewater type code given In the left margin. More than one code may be appl lcable.
| |
| G~ Provide the average nuxber of hours per day In which the facility dlschargeS treated wastewater and the total nmxber of days per year In which the discharge occurs.
| |
| H. Provide current (from the Inst l2 months) or expected flow rates as requested. Refer to unit code qlven In the left margin
| |
| ~ for the appropriate flow units. MGY - million gallons per year; MGO - million gallons per day) GPO - gallons per day.
| |
| I. Provide the maximum discharge flow rate which you vent to have authorised within the permit. NOTE: For NPOES permits only.
| |
| the use of such a flow rate will not place an actual limit restriction on the tlov but will be the flow rate used to develop etf (vent limits. Also, when the Monthly Operating Reports are reviewed by Compliance staff It vill help tham to determine It any nev or increased uses might have occurred at the facility.
| |
| J. Provide the design flow for this specific outfall discharge (e.g. batch treatment system flow, packaged treatment system flow.
| |
| or scme other finite treatment system flow).
| |
| ITEM 2 WATER TREATMENT ADO ITIYES A. Indicate whether discharge Is treated with conditioners, Inhibitors, or mlcrobloclde. If not, continue to Item 3.
| |
| B. Give name, function, and chemical ccmposltlon of additives used.
| |
| C. Give name and address of the manutacturer(s) ot the additives used.
| |
| : o. Indicate expected mlnlxxxn, average and maxlaxxx discharge concentrations of the additive(s) tor this discharge.
| |
| E. IndiCate vhether yOu treat the d(SCharge tO remOVe the addltlVe(S) betOre diSCharge Of WaSteVater.
| |
| F. Indicate the removal ettlclency of each additive t(xxx the vastevater and the discharge frequency of each additive to the surtace water or groundwater.
| |
| G. NOTE: It Is the responSlblllty of the applicant to supply the product Information as requested In this Item 4. Information requested but not supplied may result In the application being returned to the applicant for completion.
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| 32
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| | |
| REF'('.) BT NLJI"I BE R: 971 VAN WAXEfis b ROGERS XNC. f'A(3E .',
| |
| 001 NSD!) H(3: PG0310 NhrERXAI,".,AFE'lY nhrA:-"HEEr I
| |
| EC I VF. DATE: 06/21/93 Vf:.RSIQH: 004 PRODl)C rl CAI (.,XUN HYPOCHL(3RITE GRANI)I,.AIR I (3RDER HQ i P RQI3 HO VAH WATFRS 6 ROGERS INC., SLJBSXD3:ARY (3F UNXVAR ( 20/> ) 889-3400 6100 CARXLI ON P(3XNT KXRKLAHD , WA 98033 ENERGENCY AS,.X. TAHCE F(3R ENERGENCY ASSXSTAHCE INVOI. VXNG CHFiIXCALS CALI. CHENTREC
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| <800)424-9300 FOR PRODUCT AND SAII=S XNFORNATION CONTACT YOUR LOCAI. VAN WATERS h, ROGERS BRANCH OFFICE AT VWbR SOUTH. BEHD 219-289-0321 SOUTH BEND, XN PRODLJCT NANE:
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| CAL(::XUN HYPOCMI ORITE GRAHLJLAR NSDS e: F GO31O CALCIUN HYPQCHLORXTE GRAHLJLAR D A T I=: . '.'~7"05)',:L6'I',93'i "',. '-,-'i."i TRADE NANE i,"..'. CAI..CXUH,'.HYPQCHLORI TE 6 RANlJLAR
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| (".HEN HAilE/SYH~,".GAL;QYPP,' PXTTCLOR, IN13(JCL(3R, REPAK, ZAPPIT CHENXCAL FANXLY~i''-' .:-"-'YfOCHLORXTE FQRN(JLA: CA(OCL)2 CAS HUNBER: 007778-54-3 (J. S, DOT SHIPPING NANE i CALCIUN HYPQCHLORXTE, HYDRATED U,S. DQT HAZARD CLASS: 5. 1 (QXXDXZER)
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| SUBSIDXARY RISK H/A X.DE NUNBFR:
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| ~ LJN2880 KXHG GROlJP: ~ XX
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| . ORT*BLE QUANTITY: ~ lo LBS/4.5 ~ l<G XNQ DESCRXPTXON: GAL CXUN HYPOCHLORXTF, I-IYDRATED, CLASS 5. 1, UN2880, PACl<XHG GRQlJP XX, RQ, INDG CODE PAGE 5138,
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| r~a~.
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| i.-
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| . J 1
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| RF,P(3RT Hi,)FBI'-"R: 97:I. VAN WATI:.RS ~ r<(3('ACERB XNC. PAGI i(SI3S H(3: P60310 HATI'."RIAI... SAFETY I)ATA Sl-IEFT .'>Oc'FR')
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| '~'CTX VE DATE: 06/2i/93 X(lid; PR()i3(J(;,T; CALCXIJH HYPQCHLORXTE (3(<AHIJl AR ORDER Nn:
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| PROD HG SE(JTXOH ]. - PHYSICAL DATA l3(3II. XNG P(31NT 6 760 HH I-IG: DEC(3HPGSES m ceo C VAPOR DENSITY (AIR=::i ): H/A I
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| 8 P E C X F X C 6 R A V I T Y < H 2 (3'-'- ): H/A PH GF SGl.UTXGNB: ALKALXNE FIEEEZXN(3/HELTING POINT: N/A SOLUBILITY (WEIGHT % XN WATER): 21 7 G/L 8 27 C BULI< DENSITY: 65-67 l. BS/CIJ FT, .
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| VOLUHE % VOLATILE: H/A VAP(3R PRESSURE: N/A EVAPORAT3:QH RATE: H/A HFAT OF SQLUT ION: SLXGHTI. Y FXOTI-Il"-..RHIC APPEARANCE AND ODOR:
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| WHITE POWDER WITH SLXGHT CHLORINE ODOR
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| ~ ~
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| SFCTXOH 2 XNGREI3XENTS HATERXAL PERCENT CAI CIUH HYP(3CHI ORXTE <65% AVAXLABLE CHLORXNE) 65 XHERT ( XHCLUDES 5 i l0% HOISTURE) 35 SECTXGH 3 FIRE/EXPLOSION HAZARD DATA PLASH POINT <NETH(3(3..USEb)P, NONE FLAHNABI F LXHITG;'XN'g'l,R<('%BY VOLUHE)
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| UEL: N/A EXTXNGUXSHXNG IREDIA:
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| WATER ONLY! SMOTHERING INEFFECTIVE-PRGDIJCT SUPPLXES OWN OXYGFH SPECTAL FIRE FXGHTXNG PRO("EDURES l F I RE F I GI-ITERS HUST WEAR HXOSH/HSI-IA AP P ROVED, P REBBURF DEHAN 9 SELF-CONTAINED
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| 'RFATI-IXNG APPARATUS WITH F ULL FACE PIFCE FOR PQSSXBI E EXPOSURE TO
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| .AZARDOUS GASES.
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| UNUSUAL FIRF AND EXPLOSXON HAZARDS:
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| DECOMPOSE, AT 1SO C RELEASING OXYGEN GAS I CONTAINERS HAY RUPTURE.
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| REr>OVT NI>>IeEf . VAN WATERS X RQGEI<,":> XHC, f>A(>>[' 00 '3 HBI'IS>. HO: P(303'l0 MATERIAL SAFETY DATA Sl-IEI"'T "E(;TIVE DATE: oe/2X/93 2 VERSION.'0II PRODIGY(;T; CALCIUM HYPQCI<LORITE GRANULAR ORDER NO:
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| PROD NQ SECT ION 0 I.IFAI Tl-I I IAZARI3 DATA TOXICITY DATA; I.,C,.r0 X HI-IALATX OH: < RAT) HO HORTAI..ITY 8 3 5 HG>/L
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| ~ < J. I.IR )
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| L I350 DE IRIDAL: <IPABBXT) >1.000 HG/KG SKIN/EYE IRRXT*TXOH: SEE SECTXON 5 L l350 INGI'=ST I (3N; SLF t ( I X(3N FXSI.I,LC50 <LETHAL COHCENTRATXON): TLH 96 HR.: 3.0-i PPH CI.ASBXFICATXON; XHHALATIQH: IRRXTATXHG Sl<XH: :.i>)Bi' >ri-SLIGHTLY TOXXC BI<IN/EYE: CORROSIVE
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| 'I:HGFSTXOH: SLXGHTLY TOXIC AQUATIC: HXGHLY TOXIC SECTION 5 EFFECTS (3F OVEREXPOSURE XB CHEHXCAL LISTED AS A C*RCXHOGEH OR POTEHTTAL CARCINOGEN:
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| NTP HQ XARC NQ OSHA NO HEDICAL COHDXTXOHB GENERALLY AGGRAVATFD BY, EXPOSURE:
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| NONE KNOWN PERMISSIBLE EXPBQQURP LXHXTP'I~
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| HONE ESTABL'AAEI3J">8&~6%H'AN:Cv,(-,"'ACGIH FOR THIS PRODUCT, P P6 INTERNAL'~~KPHX'.4,B;I,"BE".E/EXPOSURE L X HIT < PEL ): I 3. HG/CU 8
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| ~ ., 8-HOUR TWA
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| <TTNE UExl>'HTEogASER>tBEi>'ig2 NB/BU.N. BTEL (BNl>RT-TERN FxPQBURE LTNTT> .
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| X HI-IALATX OH: X HHALATION OF CALC IUH I.IY POCI.ILO R X TE DUST AN D DE POSITION OF PARTICLES XN Tl-IE RESPXRATORY TRACT CAN I EAD TO IRRXTATIOH OF TIIE TISSUE AND CAUSE A VARIETY OF EFFECTS ~ Tl-IESE EFFECTS ARE DEPENDENT OH CONCEN-TRATION *NI3 XH(>>l IJDE: UPPER RFSPXRAT(3RY TRACT TRRXTATXON, NASAL CQHGES"-
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| TXON, CQU(>HING, BORE THROAT, LARYNGITXS AND Sl-IORTHEBS QF BREATH IH
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| 'E RAT XOHS WHE RE Tl-IE RE ARE HX GI-I CONCI"=NT RAT XOHS OF RESP I RA BLE PA RT XCIJ-
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| ~
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| .ATES, PULHOHARY EDEIIA <FLUID IN THE LIJHG) NAY fIE PRODUCED ~ IF NOT TREATI=D IHNEDXATI-"LY, PULHONARY EDEHA CAH BE LXFE THREATENING. ~ SXHCF TKXS PRODUCT XS XN GRANULAR FQRN, PARTICLES QF'ESPIRABLE SIZE ARE NOT
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| (.rF.NFRAI I. Y ENC(3UN TERED,
| |
| | |
| 3 REP()RT N(JMBEre; 9ZX VAH WA l i".-.:RS 6 ROGERS IHC.
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| STREET PA()ED 004 MSDS N(3 '. PG033.0 MATERIA(.. SAP E r V DA rA
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| 'E(ITIVE DATE: 06/21/93 VER<<:3(3N; <:~')
| |
| PRQDU(:T: CALCIUil IHYPQCIII (3RXTE Gl,AH(JI..AR l
| |
| ORDER HO:
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| P RQI3 HO EYF/8 I< XH: CALC IU> f HY P ..)CM(.Q RITE X S COR RQS EVE TC) Tl IE EYES ~ CONTACT OF CALCIUM ((YPOC()) ORXTF DU.'.T WXTW TJ<E EYE,>, EVEN A MXN(JTE AMOUNT FOR A SIIORT DURATXQN, CAN CAUSE SEVERE XRRXTAT~IOH AND EVEN BLINDNESS ~
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| CONTACT WX TIN Tl-IF 8 K XH MAY CAUSE,>>EVE RE I RRXTATX(3H, BURHS, QR TISSUE DFSTRUCTXOH, XN STUDIES UTILlZXNG RABBXTS, TI-JE,. l<XH IRR1TATXQN SCORE WAS 8/8 AHD Tl-IL. EYE XRRXTATXQH SCQRI:.."WAS 98. 5/1:LO. TidE CLASSXFICATXOH FOR BOTH Ol=
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| THESE XS CORRQSXVF ~
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| XHGESTXQN: CALCIUM I.IYPOCIILQRXTE, XF SWALLOWED, CAUSES SEVERE BURNS TO Tl-IE DIGESTIVE TRACT AiHI3 CAN BE FATAL ~
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| 4+-=
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| .4 g 'HRONIC:
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| GEHQTOXICXTY: ~ CALCIUM I-IYPOCHLORXTE PRODUCED POSXTIVE RESPONSES IN' XH-VITRO ASSAYS USING BACTERXAL SYSTEM ) <TI-IE AMES TEST> AND CHROMOSOMAL 3FRRATXQNS IH CHINESE )HAMSTER FXBRQRLASTS. XN A WHOLE ANIMAL EXPERIMENT
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| ~
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| < MOUSE L MICRQHUCLEUS TEST), EXPOSURES RANGIHG FROM 20 TQ 160 MG/l<G PRODUCED NQ COMPOUND RFI ATED CHROMOS>(3MAL ABNQRMAI. XTXES, CARCINOGEHISIS: ALTHOUGI-I HO STUDY llAS BEEN COHDUCTED WITH CALCIUM HYPOCHLQRITE, THE CARCINQ(GENIC POTEHTXAL OF SODIUM HYPQCHLORITE WAS STUDIED IH F344 RATS. AFTER 104 WFEKS OF DRXHKXNG WATER CONTAINXHG UP TQ 000 PPM SODXUM HYPOCHLQRITE, THERE WAS NO FVXDEHCE THAT THIS CHEMXCAl PRODUCED ANY CARCXNQGEN3;C RESPONSE ~ XN ADDXTXON, TI.IIS EXPOSURE DXD NOT RESUI T XN ANY ADVERSE EFFI."CTS IH BLOOD, CLXNXCAL CHEMISTRY, OR QTI.IER TARGET ORGANS.
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| ONE OF THE MAJORUSES .OQ,.CALCIUM I-IYPOCI-ILORXTE XS AS A SOURCE QF CHLORINE FOR MATERt"SAN1jT'ItZAjTLXOH"X>i+i,DRXNI(XNG ANI> IXECIEEATXONAL MATER BTMOXES IIAVE IIEEN CONGO/YES.jlOrt'P+TERHXHE, TIRE L.ONG-TERH EFFECTS OF CHLORXNATEO ORXNKXNG MIJTERi+ SEVE(I'::GLENEKRATXONB OF IEATS MERE GXVEN:l00 PPH CHLORXNE I
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| IH THE R DR>I'NKX'$9gQATjER',+'HO D 3: FF E REN CF.. IN FF RT ILIT Y, G ROWTH, 8 LOG D PARAMETERS',Pg'QR~~+PEGXF~LC- O'RGAN TQXICXTY WAS OBSERVED BETWEEN CONTROL ANI)
| |
| EXPOSED AHIMAi"S'".--"k~iWOiSEPA'RATE ANIMA( STUDIES CONDUCTED BY DIFFERENT GOVERNMENT AGENCIES l3ETERMXNED THAT THE CHLORINATION OF MUNICIPAL DRXHl<XHG WATER DXD HQT RESUI T XN TQXXCXTY TO TIIE DEVELOPXHG MOUSE FETLJS SAF(= HAHDLXNG OF Tl-lXS MATERIAL ON A I QHG-TERM BASIS SHOULD EMPHASIZE MXN3:MIZXHG REPEATED ACUTE EXPQSURFS.
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| EMERGENCY AND FIRSV hID f RQCEDURES IHHALATION:
| |
| REMOVE TO FRESH AXR, XF HQT BREATJ-IXHG, G1VE ARTXFXCXAL RESPXRATXQH,
| |
| | |
| t rcEr f) R i NUMBER:
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| Ms (3$ Ho: P60310
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| '(., (:
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| PROI3(J(,T; i'I VE DATE: 06/21/93 CALCXUM HYPOCHLORITE GRANU(...AR VAH WATERS> b MATERIAL sAFFTY DA(A fkf)(3r:,,P('.> IHC sl<r:::~::r f.) R DER P ROI3 Vl: R Ha:
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| Ha PATE:
| |
| lx()N 0(>".:i
| |
| '04 PREFERABl,.Y MOUTl(-Ta- MOUTH. 3:F BREATI(IN''2 DXFFICULT,
| |
| > GXVE OXYGEN.
| |
| CAI. L A Pi'IYSXCIAH ~
| |
| EYE OR SKIN CONTACT:
| |
| FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, WHXLE REMOVXNG
| |
| (.;(3HTAMIHATEI3 CI OTHXH(3 AND .>I.IQES. F(3R EYE CONTACT, GET XMMEDIATE MFDXCAL ATTENTION. XF SKXN XRRXTATXON OCCURS, GFT MEDXCAL ATTENTXQN.
| |
| IHGLST ION:
| |
| 3:F CQHSCI()US, DRXHK LARGE QUANTITIES OF WATER AND AHY COMMON Caa(<I46
| |
| < VEGETABI E> OIL, IF AVAXI ABI E. Do H(3T XHDUCE VOMXTXHG. TAKE IMMEOXATEL'Y Ta A HaspxTAL are f HYsxcxhN ~ xF uNcaHscxaus, OR xN To A HOSP ITAl .
| |
| coNvuLSXOHS,:,TAi<F...'MMEDIATELY Do NOT ATTEMPT To INDUCE VQM X TING OR-,;GIVE',;,
| |
| AHYTHXHG BY MOUTH To AN UNCONSCIOUS PERSON.
| |
| NOTES To PHYSXCX*N < INCLUDING ANTI(30TES):
| |
| TREAT SYMPTOMATICALLY, SECTI(3N 6 REACTXVXTY DATA STABII. XTY:
| |
| UNSTABLE coNDxTxaNs To AvnxD:
| |
| CONTAMXNATION OR EXCESSIVE HEAT ABQVE 177 C HAZARDOUS POLYMFRXZATION: WXLL HOT OCCUR COHDXTIONS Ta AVOID: NONE-WXLL NOT POLYMERIZE X H(.;0M PAT I 8 IL,X'TY....<'8AYERX'Al",g'(-"TO;,AVo I D ):
| |
| ACIDS, COMBUSTXBL'E'. MATgRIAt S, ORGAHXCS, REDUCING AGENTS HAZARDOUS DECOMPOSITION"PRQDQCTS:
| |
| ACIDS OR AMMUHQQ:~CQNIQQXHA'TXON WXLL RELEASE TOXIC GASES, EXCESSIVE MEAT WXLL CAUSE .DFLOMPPSX'TX(3H RESULTING XN THE RELEASE OF OXYGEN AND CHLORINE GAS ~
| |
| SFCTION 7 SPXLL OR LEAK PROCEDURES Ps To BE TAKEN XF MATERIAL XS SPXLLED OR RELEASED:
| |
| .QTE: USE EXTREME CAUTXON XN HANDLIHG SPXLLED MATERIAL ~ CQNTAMINATXON WITIH ORGANIC OR COMBUSTIBLE MATERIAL MAY CAUSE FIRE OR VXOLENT DECOMPQSXTION. XF FxRF aR DECOMPosxTxoN OccuRs xN ARFA aF SPILL, xMMEDxATELY DousE WxTH PLENTY OF WATER. OTHERWISE, SWEEP UP ALL VXSIBLE MATERIAL USXNG A CLEAN, DRY SI.IQVEL AND BROOM AHD DXSSOLVE MATERXAL IN WATI=R DISPOSE OF WASTE MATERIAL AS
| |
| | |
| PEP() RT NUMBER: 971 VAN MATE R!') A R(')( E I'<s I Hr'.. PA(',~i".: 00/)
| |
| MS I.')!3 H(3: PG0310 MATr,:.RIAL IAFETY DATA .: 1<F< I "E(: TI VE l3ATE: 06/21/93 Vr;::RSXGN: 004 I'R(39(.JCT: CALCXUM HYPOCHLORXTE (3RANUI.AR ORDER HG:
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| P R(30 HQ
| |
| ()UTLXNEO BELOW.
| |
| WASTE DXBPGSAL METHOD:
| |
| ,":)PILLED MATERXAL TI.IAT I.IAS BEEN SWEPT (JP AHO DXBSOLVED XH WATER SHOULD BE IJ, ED XMMEDXATELY XN THE NGRMAl APPLXC*TXOH FOR WHXCH CALCXUM HYPGCHLGRITE XS BEING caHSUMEO XF THIS Xs HOT POBS1BLE:, CAREFULLY NEUTRALIZE DXSSGLVED M*TERXAL BY ADDING HYDROGEN PEROXIDE (QNE PXNT OF 35/ HYDROGEN PEROXIDE SOLUTIQN PER POUND OF CALCXUM HYPGCHLQRITE To BE NEUTRALIZED)
| |
| THEN DXLUTE THE HEUTR*LXZED MATERXAL WITH PLENTY GF WATER AHD FLIJBH TO SFWER. NGTF.: ONLY PROPERLY NEUTRALIZED MATERXAL SHOULD BE FLUSHEI3 To
| |
| 'E:WER. UNNEUTRALIZED M*TERXAL CAN CAUSE EHVXRONMEHTAL DAM*BE To RECEIVlHG WATER OR CAN INTERFERE WXTH TREATMENT PLANT OPERATION.
| |
| FGR OH-SXTE NEUTRALXZATION, C*REFULLY AHD SLOWLY POUR THE APPRQPRIATF.,
| |
| QUANTITY GF 35/ HYDROGEN PERQXXDE SOLUTION OVER ALL SPXLLED M*TERIAL THFN FLUSH AREA WITH PLENTY OF WATER.
| |
| COMMENTS'ARE MUST BE T*KEN WHEN USXHG QR DXSPOSXNG OF CI.IEMXCAL MATFRXALs AHO/aR THEIR coHTAxNERS To PREVENT ENVIRONMENTAL CQH'LAMINATION.
| |
| Xs YOUR DUTY Ta OXSPOBE QF THE CHEMICAL MATERIALS AND/OR THEIR L',OHTAINERS IH ACCORDANCE MXTH THE CLEAN AXR ACT, THE CLEAN MATER ACT, THE RESOURCE CONSERVATION ANO RECOVERY ACT, FIFRA, AS MELL AS ANY OTHER RELEVANT FEDERAL, ST*TE, OR LOC*L LAWS/REGULATXONS REGARDING DISPOSAL, SECTION 8 SPECIAL PROTECTION XHFORMATION RESPIRATORY PROTECTION l IF DUSTY CQNDXTIQNS ARE ENCOUNTERED, USE HXOSH/MSH* APPROVEO RESPXRATOR WXTH ACXD GAS CARTRXDGE AHO DUST PREFXLTER. THE RESPIRATOR USE LXMXTATIONS BPECIFXED BY HXO. H/MSHA OR THE MANUFACTURER MUST BE OBSERVED, RESPIRATORY PROTECTION PRQt3RAM8 M(JST BE. XH ACCORDANCE WITH 29 CFR 1910, 134.
| |
| VENTILATIOH<TYPE3; HoHE, uNLESB. OusTY coNDITIGHB ARE EHcouHTFRED.
| |
| EYE PROTECTION:
| |
| CHEMXCAL SAFETY GOGGLES GLOVES'ATUR*L GR BYNTHETXC RUBBER OTHER P RGTECTI VE EQUIPMEHT I "ooTs, Ar RGNs, oR CHEMICAt suxTS sHouLD BE usEO WHEN HEcEssARY Ta PREVENT RXN CONTACT> PERSONAL PROTECTXVE CLOTHXHG AND USE OF EQUIPMENT MUST BF.
| |
| XH ACCORDANCE MITH 29 CFR 1910, 132 ANO 29 CFR 1910. 133,
| |
| | |
| REPORT HI JM BE R: 97 i VAH WATERS A ROGERS 1H(::, PA(3E: 007 MSDS NO: PG03i0 MATERXAL SAFFTY D*TA BHFET
| |
| " ECTIVE OATEN'S/~i/93 VERSION: 00<
| |
| I ROD(JCT: CALCXUM HYPQCHLQRXTF GRAH(JLAR ORDER HO:
| |
| PROD NO SECTION 9 - SPECIAL PRECAU'1'XGHB PRECA IJTXGNB TQ BE TAKEN DURING HANOLIHG AND BTORXHG .'Q HOT GET XN EYFB, ON SKIN OR ON CLOTHXNG, l<EEP IN ORIGXNAL CONTAINER IN
| |
| * COOL, DRY PI..ACE, KEEP CONTAXNFR CLOSFD WHEN NGT IH USF..
| |
| KEEP AWAY FROM HEAT SOURCES, SPARKS, OPEN FL*MES AND LXGHTEO TOBACCO PRODUCTS.
| |
| USE ONLY A CLEAN, DRY SCOOP MADE QF METAL OR PLASTIC EACH TXME THXS P ROD(JCT XB TA I<FN FROM CON TA INF R, DO HOT *OD THIS PRODUCT TO ANY DISPFNSING DEUICE CONTAXNING REMNANTS OF *NY OTHER PRODUCT'. SUCH USE MAY CAUSE VIQLEHT REACTION LEAOXNG TO FIRE OR EXPLOSION, ADO THXS PRODUCT ONLY TO WATER MAY CAUSE FIRE OR EXPLOSIOH XF MIXED WITH OTHER CHFMXCALS.
| |
| FXRE MAY RESULT XF CQHTAMIHATEO WITH ACIDS OR EASILY COMBUSTIBLE MATERIAL SUCH AB OXL, KFROBFNE, GASOLINE, PAINT PRODUCTS AND MOST OTHER ORGANXC MATERXALS, WASH HANDS AFTER HANDLXNG DO NOT REUSE CQNTAIHER, RESIDUAL MATERXAL REMAXHXHG IH EMPTY DRUM CAN RE*CT TO CAUSE FIRE, THQROUGHI Y FLUSH EMPTY CONTAXNER WXTH WATER THEN DESTROY BY PLACXNG IN TRASH COLLECTION. DO NQT CONTAMINATE WATERp FOOD, QR FEED BY STORAGE QR DISPOSAL.
| |
| OTHER PRECAUTIONS'EEP GUT OF RE*CH QF CHXLDREH STRONG OXIDIZER FXRE MAY REBUL.T FROM CONTACT WXTH HEATi ACXOSp ORGANXC OR CQMBUSTXBLE MATTER.
| |
| MAY BE FATAL OR HARMFUL XF SWALLOWED, MAY CAUSE ("HEMXCAL BURNS.
| |
| XRRXTATXNG TG HOSE AHD, TlfROAT AUQXD BREATHIHG DUST, COMMENTS:
| |
| TSCA CALCIUM HYPQCHLQRXTF. XS QN THF TBCA INVENTORY UNDER CAB e777e-S4-3 ~
| |
| SARA TITLE XXX A) 3ii/3i2 CATEGQRXES ACUTE AHD REACTIVITY, 8) HQT LISTED IN SECTION 3i3, C) NGT LXBTED AS AN "EXTREMELY HAZARDOUS SUBST*NCE" l
| |
| XN SECTION 302, CERCLA LXSTED XN TABLE 302.4 QF 40 CFR PART 302 AS A I"IAZARDQUS SUBSTANCE WITH A REPORTABLE QUANTITY QF i0 POUNDS RELEASES TQ AXR p LAND QR WATER
| |
| 'HXCH EXCEED THE RQ MUST BE REPORTED TQ Tl-1E NATXONAL RESPONSE CENTER, 00-<2~-SS02.
| |
| RCRA WASTE CALCIUM HYPOCHLQRXTE AHD CONTAMXNATEO SQXLS/MATERIALS FROM SPILL CLEANUP ARE 000K HAZ*ROOUS WASTE AS PER 40 CFR 26i,2i <A) <4) AND MIJST BE OXSPOSFD OF ACCORDXHGLY UNDER RCRA,
| |
| | |
| RE( OR r NUMBER: 971 VAN WATE RS b RO()ERB XNC. PAGE: 008 HSI3S Nn: P(-'0310 HATI.=..RIAL SAFETY l3ATA SHEET
| |
| 'CTXVF. DATE: 06/2i/93 VERBJQN: 004 i R(3DUCT: CALCIUM HYPOCHLORXTE (iRANIJI..AR ORDER NO:
| |
| PROD NG F1FRA CALCXUH HYPOCIILQRITE XS REGISTERED WXTH EPA AB A PEBTICXOE ~
| |
| NSI'= PPG CAI CIUH HYPOCHI GRITE IS CFRTIFXED FOR HAXXMUH USE AT 46 HG/L (JNDER ANSI/NBF STANDARD 60, REVXBXQNS HADE TO 7/28/92, 3RD EDXTXQN: D*TE, EDITXON, AODITXQN QF NBF STATEMENT.
| |
| FOR ADDITIONAL XNFORHATION HL CONTACT: HSDS COORDINATOR DURING BUSXNESS HOURS, VW6R SOUTH BEND PACXFXC TIME <206>889-3406 A
| |
| 02/:L7/94 12:21 PRODUCT: CUST NO: ORDER 8{3.( 'F."
| |
| NOTICE VAN WATERS b, ROGERS INC, ("VW6R") EXPRESSLY DXSCLAIHS ALL EXPRESS QR XHPLXED WARRANTIES QF HERCHANTABXLXTY AND FITNESS FOR A PARTXCULAR PURPOSE, WXTH RESPECT TQ THE PRODUCT QR INFORM*TIQN PROVIDED HEREIN ~ **
| |
| ALL XNFQRHATION APPEARXNC HEREXN XS BASED UPON DATA t3BTAINED FROM THE H*NUFACTURER .,AN0$ 05>>.RFCOLGNXZED TECHNICAL SOURCES WHXLE THE XNFORHATXQN 18 BELXEVEO TQi jgg".':-'QCCl'lRA fF'j","VLfhR'AKES NO REP RESENTATXONS *S TO XTS ACCURACY Q R SUFFICIENCY C(NOXTT0$8'F,: Ui>>PE ARE BEYOND VWARS CONTROL AND THEREFORE USER,.
| |
| ARE RESPONSIBLE",'O" VEQXFY TtgPXB'AT* UNDER THEIR QWN OPERATXNG CGNDXTXONS T(3 OETERHXNE WHETHER,,'-TflF':,PPUDUCl'.,'XS BUXTAB1 E FOR THEIR PARTXCULAR PURPOSES AND TI.IEY ABSUHE ALL';RIQICS";OTF!,'THEIR.,:USE~ H*NOLING, *NO OXBPOBAL OF THE PROOUCT, OR FROH THE PUBLXCALTXON;,:OR','USE'F.,::.GR'ELIANCE UPON, XNFORHATION CONTAINER HEREXN.
| |
| THIS INFORHAT1ON" RELATES'NLY TO THE PROOUCT OEBIGNATEO HEREXN. ANO OOEB N(XT RELATE TQ ITS USE XN COHBINATXON WXTH ANY OTI.IER MATERIAL OR XN ANY OTHER PROCESS'+ENDQFHSDS*a.*
| |
| | |
| SEE INSTRUCTIONS ON REVERSE SIDE SECTION fl PERMIT NUMBER ~ IYI1 0005827
| |
| ~OO E IEM As NatE OF PROCESS CONTRIBUTING TNOUSI THIS OUTFALL Ate SIC TO THE DISCHARGE CODE SANTTARYW TER 4911 3 Be PRXESS SCHEDLLE (YEARLY AVERAGE)
| |
| PROCESS Ch CO Cit Ce PRCCESS ICCSTEHATKR FLD/I RATE TOTAL YEARLY 8 5 7 7 wIT~
| |
| Os STREAMS 0CE CONTRIBUTING CL DAILY MINIt/LTC 0 11 ~6 TO 037~6
| |
| ~i DAILY HAXIttti OUTFALL DISCHARGE De PROCESS PRODUCTION RATE N/A WITS TI%
| |
| LJ
| |
| ~
| |
| Ae NA% OF PROCESS CONIRIBUTM TO TIE DISQCLRGE TIRLXXIH THIS OUIFALL Ate SIC CODE g/A B. PROCESS SOGXIE (YEARLY AVERAGE) esses/sev ssvs/vses C/I C. PROCESS HASTEHATER FLDH RATE Oili TOTAL YEARLY 0
| |
| DAILY HINIIRII 1 POUNDS DAILY I/AXIPLPI 2 GALLONS WITS /TIIE ReCESS PRODUCTICN RaTE 3 CUBIC YARDS A'E oF PRxEss coNIIBUTIID To TIE DlscHARGE TIROUGH lHIS OUTFALL AtCI SIC CLXE g/A 4 TONS Be PROCESS SQEDLAE (YEARLY AVERAGE) 5 MGY 6 MGD Cs PROCESS HLSTEHATER FLDH RATE 7 GPD TOTAL YEARLY DAlLY HININtl DAILY HAX It%PI TIME De PROCESS PRODLCTI ON RATE WITS PTltE HOUR 1
| |
| 2 DAY As NAIE OF PROCESS CONTRIBUTING TO TIE DISCHAR%
| |
| TH Ate SIC CLXE g/A 3 WEEK Be PROCESS SQEDLLE (YEARLY AVERAGE) 4 MONTH Cs PRXESS HASTENCTER FLDH RATE WIT CODE 5 YEAR TOTAL YEARLY DAILY HI HI%PI DAILY HAXIMM De PROCESS PteDUCTION RATE WITS MIHK Hat% oF PtecEss TIROUIH coNIRIBUTING To TLE DlmARGE lHIS OUIFALL AND SIC CODE g/A Bs PRXESS SCHEDLLE (YEARLY AVERAGE) ssvs/vsse CO Ce PROCESS HASTEHATER FLOH RATE WIT CODE TOTAL YEARLY CE CL DAILY HINIIEtl DAILY HAXItLPI De PRXESS PRODUCTION RATE W~NITS TIIE 33
| |
| | |
| INSTRUCTIONS FOR COMPLETING SECTION I I ITEM 3 Tr is form requires Information on the proceas streamS which contribute to this discharge.
| |
| ENTER THE PERMIT NLSIBER IN THE BOX AT THE TOP OF THIS FORM. THE PERMIT NISIBER CAN BE FOUhTI ON THE FRONT PAGE OF YOUR EXPIRING PERMIT. If thlS IS a naw Or nOt PreVIOuSly Permitted faClllty, then leaVe blank and a number <<ill be aSSlgned.
| |
| Enter outfall number In space provided for each page of Section II. For each Individual dlscharce oint a separate set cf Section II forms must be filled out.
| |
| PROCESS STREAMS CONTRIIRITING TO DISCHARGE: FOR EACH SEPARATE PROCESS PROVIDE THE FOLLOflf6 INFORMATION A. Enter the name of the process <<hlch contributes to this discharge. Also provide the proper SIC code.
| |
| B. Indicate the yearly average process schedule In hours per day and days-per-year.
| |
| C Provide the process wastewater firn rate Information as requested based on your last l2 months of operations'efer to unit coda given in the left margin for the appropriate flow units.
| |
| D. Process ProductIon Rate - Certain permit limitations may be based on production rates. The production rates used to determine permit limits shall be represented by a reasonable measure of actual production of the facility, such as the production during the high month of the previous year, or the monthly averaqe for the highest of the previous five years, or Other reasonable measure as stated in applicable U.S.E.P.A. categorical rules and regulations.
| |
| For new sources or new dlschargers, actual production shall be estimated using proJected production.
| |
| Record your production rates In the terms and units used In the applicable U.S.E.P.A. categorical rules and regulations for your type of facility.
| |
| 34
| |
| | |
| SECTION II SEE INSTRUCTIONS NUMBER~
| |
| ON REVERSE SIDE
| |
| ~OO E EM Ae IS THE DISCHARGE FROM THIS OUTFALL DIRECIKD TO lHE GRa5D GROQCWATERS? (IF %A COttTINK TO ITEM 0)
| |
| OR Eg YES 4 Be HAS A HYDROGEOLOG ICAL STUDY OR ITS EQUIVALENT BEEN PERFORMED OR IS THERE BIFF ICI BIT CURRENT HYDROGEQLQGICAL INFORMATION AVAllABLEAS REQUIRED BY TIE HATER RESIMICES X .S, atttlsstON PART Z2 GRONIDtATKR RIAES OF AuiUST ltlo 19% RI525.2207 (PAGE ILI) FOR GROUNDWATER THIS EXISTI% OR PROPOSED DISCHSRGET IF YES ATTACH A CCPY CF THE REPORTS Submitted 12/6/91 DISCHARGE Ce ARE YOU REIXEST1% AN EXB1PTION FRCM SIBIITTI% A HYIIIQGEQUXIICALREPORT %DER INFORMATION RLAE Re323AZR7 (19} (PAGE Q) OR FROM GRIXNDtATKB tCEIIIORI% IIEOU)RBIENIS YES X WDER RULE Re525IZdS (5) (PAGE + OF 1% PART 22 RLLES ~ IF YES ATTACH DQat6ENTS AND EXPIANATICN TO DBXINSTRATK THAT VIX'ISCHARGE MXAD QUALIFY FOR AN EXBf lONe De ARE YOU RBXKSTI% A VARIANCE FIOI RULE 323e2205 (PAGE THE HATER REstxwcEs cctt11ssIQN PART 22 GRQNIDIATER RILEs?
| |
| P (tOteEGRADATION) OF IF YKS, ATTAOH SUOH DOQHBITS AS NECESSAlà TO DEMONSTRATE TIE NEED FCR A VARIANCE IN TERMS OF TIE CRITERIA SPECIFIED IN RIAE 525e2210 (PAGE CF 1HE PART 2Z RRESA a-Ee I,IST Alp. CHEIIICAL SIBSTANCES HHICH ARE IN MICHIGAN S CRITICAL MATERIALS REGISTER LPAGE D) AND/OR Uese EPA'S PRIORITY POILUTANT TABLE IV LIST TABLE V (PAGE 7) OR ANY mtER SIBSTANCES ttIICH ARE CR HAY BECOME IMHIOUS TO TIE EESIGNATKD USES OF 1% GRXMlATKR NOT APPLICABtx/BELIEVED ABSENT OR TO THE PUBLIC %ALTH lHAT ARE DISCHUIGED OR EXPECTED TO BE DISCHARGED TO TIE RQXLIKX6ATKRAY FACILllYe ESTIMATE THE FINAL EFFLUENT CONCENIRATIIXI ND RECORD ALL DATA IN ITBI OF1HIS SECTICN II IN 1HIS BOOILETe 7
| |
| TIE APPLICANT HAY BE RECUIRED lD DO AIXIITIONALHASTE ANALYSESA El PRESENTS DATA PROVIDED IN ITBI 7 Ae DISCHARGE CHARACTERISTICS CCNCENIIIATION WITS CODE 0 ANALYSES SAtPLK TYPE ITENI ~40 AVE
| |
| ~05 ~99 HAX COCE 5 BQOI3 (FIVE DAY BIOCteIICAL OXYGEN DEHAIB) . . ~6
| |
| ~
| |
| COD (CtetlCAL OXYGBI DEMAND) u1 EXPECTED
| |
| ~~
| |
| 'TOC (TOTAL ORGANIC CARBON)
| |
| WASlEWATER CHARAC-AtfCNIA NITROGEN (AS N) ~ QJ~ ELlZ~
| |
| '11 6, ~0
| |
| ~
| |
| TOTAL SUSPB4KD SOLIDS 5 .~55 ~l 2~60 UNETS CODE 1 MQ/I TOTAL PtDSPHOftUS (As P) ~73, ~03 6 ~12 . ~05 2 UQ/ I TOTAL RESIIXIAL OUNINE 3 COUNTS/
| |
| 100 ml DISSOLVED OXYGEN MIN ~1 4 S.U.
| |
| 5 F
| |
| ~6 ~4 ~1 1 3 6 LBS/DAY FECAL COLIFORtl BACTKRIA ~3
| |
| 'TBmmltttE (sums) 79%%RATINE (HINIKR)
| |
| Be
| |
| ~
| |
| LLJ ~
| |
| ~
| |
| LJ LJ OTHER HASTKHATER CHUIACIKRI STICS u3 0 I L S G R E A S E LJ
| |
| ~RAMP E n'c 1 cc. ~65 , ~56 ~20 8, ~0 ~l ~65 ZXBE 1 GRAB 2 24 KOUR COMPOSITE RBXIIRED IIFOWATICN FIERY SINFACE HATER DISCHARGESe
| |
| | |
| INSTRUCTIONS FOR COMPLETING SECTION I I ITEMS 4 ANO 5 This tom requires Information on s specific outfall discharging to either the groundwsters or the surface waters.
| |
| ENTER THc PER4IIT hlPIBER IN THE BOX AT THE TDP OF THIS FORM. THE PERMIT Nl+IBER CAN BE FOUND ON THE FRONT PAGE OF YOUR EXPIRING PERMIT. If thlS IS S new Or nOt preVIOuSly permitted faCI llty, then lenVe blank Ond O number <<II I be SSSlgned.
| |
| Enter the outfall number In the space provided for each Doge of Section II. For each Individual disehsroe point a se arete set of Section II forms (Items 4 and 5) must be filled out.
| |
| ITEM 4 GRCUNDWATER DISCHARGE INFORMATION (00 NOT INCLUDE DEEP WELL INJECTION INFORMATION IN THIS ITEM)
| |
| A.-D. The applicant shall address each of these parts If the discharge trcm this outfall Is to the qroundwoter.
| |
| ITEM 5 EXISTING OR EXPECTED (FOR A NEW DISCHARGE) WASTEWATEP CHARACTERISTICS OF GROUNDWATER OR SURFACE WATER DISCHARGE (DO NOT INCLUDE
| |
| <<LL INJ I N IN N H A. The applicant shel I report nvni lable discharge data (real data for existing discharge or expected dots for n proposed discharge) for the Darnmeters as listed. These parameters shall be addressed for either a surface rater discharge or ss aDDroDrlate for s groundwater discharge. For assistance In determining appropriate parameters a ground~ster discharoe applicant msy contact the Groundwater Duality Division, permits Section or the appropr late Groundwater punl ity Division's District oftlce.
| |
| The applicant shall i'eport the sample type code best describing each reported piece of dots. see coding on the left margin of this tofm If this outfall Is n surface water dlschsrqe, the applicant must report quantitative dots for each parameter Identified b on PPI t y, " , etd 9 d h ell d p t P t t be ~ ppd ted by deo pt tied I . d h odh e ell ept p ttp h t 0 thl pell tl I
| |
| : o. P h eo e B. If data Is available tor other parameters not listed above In A. or other parts of this application the applicant should reDort that data In the blank spaces provided In this part.
| |
| <OTESt I. Unit codes for parameters reported In ports A snd 8 cnn be found on the lett hand side of this tore.
| |
| 2~ Grab Snmole Shel I be uSed tO SnolyZe far PH, temperature, tOtsl PhenOIS, reSldual ChlOrlne, Oil nnd grea5e ~ and fecal coliform In n svrtaee water discharge unless other frequency-snmD(e type analyses are available. See Glossary (pnge 48) for definition ot grab Sample.
| |
| 24-hour composite samples shall be used to analyze for Total 8005, COO, TDC, Amnonln Nitrogen, and Total SusDended Solids in o surface ~ster discharge unless other frequency-sample type analyses sre available. See Glossary (page 48) tor definition ot comDOSlte sample.
| |
| : 4. REPORTING OF INTAKE DATA. You are not required to report unless yov <<Ish to demonstrate your eligibility for o "net<< effluent limitation for one or more pollutants, that Is, nn effluent limitation odJusted by subtracting the overage level ot the pollutant(s) present In your Intake ~ster. NPOES regulations nl (ow net limitations only In certain circumstances. To demonstrate your eliglbl llty, report the overage of the results ot analyses on your intake water (if your <<ster Is treated before use, test the ~ster ofter It Is treated), snd attach s separate Sheet contninlng the following tor each pollutant:
| |
| (a) A statement that the Intake <<ster Is drown trom the body ot <<ster Into which the discharge Is mode.
| |
| (Otherwise, you ore not eligible for net limitations.)
| |
| (b) A statement ot the extent to which the level of the pollutant Is reduced by treatment of your wastewater .
| |
| (Yovi limitations <<ill be sdJusted only to the extent that the pollutant Is not removed.)
| |
| (c) When applicable (for ex(mpple, when the pollutant represents a cla55 ot compounds), n demonstration of the extent to which the pollutants In the Intake very physically, chemically, or biologically fran the pollutants contained In youi'ischarge. (Your limitations <<ill be adjusted only to the extent that the Intake pollutants do not vary frobb the discharged Do)lvtants.)
| |
| : 5. If you have two oi'ore substantially Indentlcal outfslls, you msy request permission tron your permitting OuthOrltv to sample nnd analyze only one outtsll nnd Submit the results of the analysis tor other Substantially Identical outfalls. If your request Is granted by the permlttlno authority, on s separate sheet attached to the SDPIICstlOn fOrm Identity WhlCh Outtall ydu did teSt, Snd deSerlbe <<hy the Outta(IS wh(Ch yOu did nOt teSt nre substantially Identical to the ovtfoll which you did test.
| |
| '36
| |
| | |
| SEE INSTRUCTIONS ON REVERSE SIDE SECTION II PERMIT NUMBER ~ IYIZ 0005827 6
| |
| eNI THE FOUXHI% REQUESTED INFOIVIATION QUALITATIVE INFORtllT ION REQUESTED BELOhlo
| |
| ~ ADCRESSED BYJILL QJIFACE HATER DISCHARGERSI IIGIEt NKH USE Dl SCHARGERS SUB'ROVIDE EXPECTED VALIKS FOR THE QUANTITATIVE AND OOE AI IS THIS FACILllY A PRIMLY INIXSTR(.
| |
| (IF tKJ GO TO E) (IF Y S GO TO B)
| |
| (REFER TO TABIE IA PPl<
| |
| Q YES NO PRIORITY POLLUTANTS BI INDICATE TYPE OF PRIMARY INDUSTRY AS LISTED IN TABIE IA PAGE (CONTI~ HITH C ) ~
| |
| Q STMEL'EPWR aND CI ICES 1HIS OUTFALL DISCHARGE CCttfAIN ANY PROCESS HASTEHATKR7 (IF NOr GO TO E) (IF YES. GO TO D) YES ~X MO ADDITIONAL INFORMATION De tNDICATK ltttCH GC/MS FRACflONS tKJST BE TESTED FORe Analysis per FOR (REFER TO TABLE IA PJJ>E KQEI FOR EACH QJMS FRACTION CHECKEDr EAtH SPECIFIC ORGANIC TOXtC POUJJTAMT HITHIN D J.B. Beauboeuf Groundwater SURFACE WATER DISCHARGE EAQI FRACTION 55'K ANALYZED FOR (SEE TABLE I IA PAGE IMXJSTRY APPLIuWTS HITH A PROCESS HASTKHATER DISQURGE CATA FOR EACH TOXIC POLUJfANT IN TABLE lllA PN4 99 I
| |
| ~
| |
| Q, IN ADDITION ALL PRINARY PROVIDE QUWTITATIVE D BASK/NKUIRAL ACID Division ONLY RECORD ALL DATA ON FORMS PROVIDED (ITEM 7) IN THIS BOOKLETI (CQMTINE HITH E K BEUAt) PESTICIDE
| |
| ~
| |
| Eo IF
| |
| ~
| |
| IN TABLE IIA AND IVA PAGKS BE PROVIDED'EcoRD
| |
| ~
| |
| QJIFACE HATER DISQIARGE APPLICANT (PRINRY OR SECNIDUIY IMIXJSTRY)r REGARDLESS OF THE TYPE OF DISCHARGEr KXHS OR HAS REASON TO BELIEVE TlQT ANY POLLUTANT LISTED Is DISCHARGED FRQI AMY IXJIFAILrTIE QOWTITATIVE DATA 0 NOT APPI.I CABLE/BELIEVED ABSENf N/A ALL DATA 0N F0RMs PRQYIDED (ITKJI 7) IN THIs BQQKLEf.
| |
| O PRESENT/DATA IS AlTACHED F. IF AMY QRFACE lATER DISCHARGE APPLICANT (PRIMLY OR SECONDARY IMXJSTRY)r REGARDLESS OF TYPE OF DISQJUIGEr KIKXts OR HAS REASON TO BELIEVE ANY POUJJTANIS LISTKD IN TABLE VA PAGE + ARE DISCHARCM FROM AMY IXJIFALL TIE APPLICANT REASONS FOR TIE POUJJTANf BEI% PRESENT ANJ PROVIDE ANY AVAILABLEQUANTITATIVEDATAI
| |
| ~ DESCRIBE Q %T APPLICABLE/BELIEVED ABSENT RECORD NL KATA OM FOttts PROVIDED (ITEM 7) IN THIS BOOKLET> N/A Q PRESENT/CATA IS ATTACHED GI AIL SIRFACE HATER DISC@AGE APPLICANTS (PRIMARY AMD SECONDARY INDUSTRIES)
| |
| %T APPLICABLE/BEUEVKD Assatf QrVTRIQLOIIOPJE%L eTC~Pl OR HEXACtLONPIEJE ttCRPJ (AlL DATA FCR TIE ABOVE tKJST BE GENERATED US1% STANDARD AMAt.YTICALCALISRATIIXI PROCEDIRES) CR N/A
| |
| ~KtKBts OR HAS REASON TO BELIEVE THAT TIXO IS CR MAY BE PRESENT IN TlEIR DISCNRGEr REPORT tBIALITATIVE SLTAr GEJERATKD ltg IQI USED A SCREEN!% PROCEDNE %T CALIBRATED Hl'tH ANALYTICALSTANDAtmr FOR 4 5r 1 8r TKIIIAQLDRODIBENZOPDIOXIN Q PRESENT/DATA IS ATTAQED (TCIXJ) ~ RECORD AIL DATA ON FORMS PROVIDED (ITBI f) IN THIS BOOKLETr Jr IF TIE SUIFACE HAlKR DISOIAAK APPLICANT KJKXts OR WLS REASON 10 BELIEVE THAT BIQUJGI~ loxtcllY TKsfs HERE MADE IN THE Iasf TtttEE (5) YEARs QN ANY 0F TlE APPLtuWT S DISCHARGES OR ON A RECEIVI% HATER IN RELATIOtt lD A DISCHARGEr PROVIDE Q %T APPLICABLE
| |
| '/A THIS ItAAQTION AS AN ATTAQtENT TO lHIS APPLICATIONI Q APPLICABLE/SEE ATTAQIED KI IF A CtWIIRACT LABXIATORYOR CONQLTI% FIRM PERFORPKD ANY OF Tlt BY THIS APPLICATIOttr PROVIDE TIE NAME AND ADDRESS OF EAQI tasORATCRY OR FIRM ANJ THE ANALYSES PERFQttED AS AM ATTAQtKNT OF THIS APPLICATIONa AtaaYSES REQUIRED Q MOT APPLICABLE X APPLicastE/SEK ATTAQIED LI DO YCU DISCMUIGK ANY OTHER TOXiC OR INJLJIIOUS TABLES IV PAGE tt AtO IIA THOU% VA PJVM ~~, (JKMICAL SUBSTANCES %T LISTED IN IF YES TIKJI IDENTIEY TIE CHBttCAL Q8STAJKXS AMO ESTIMATE TIE FINAL EFFUXMT CCNCEJttttaTICNsr SUttIT THIS Q %T appLicasLE N/A ltFOtttATION AS AN ATTAQtEMT TO THIS APPLICATIONs Q APPLtues/SKK ATTAQIKD 37
| |
| | |
| INSTRUCTIONS FOR CCMPLET I NG SECTION I I ITEM 6 This form requires Information on a specific outtnl I discharging to the surface waters.
| |
| ENTER THE PERMIT NUMBER IN THE BOX AT THE TCP OF THIS FORM. THE PERHIT IRNBER CAN BE FOUND ON THE FRONT PAGE OF YOUR EXPIRING PERMIT. If thlS iS O new Or nOt preVIOuSly permitted fOCI lity, then lenVe blank and n number Wll I be nSSlgned.
| |
| Enter the outfall number In the space provided for each page of Section II. For each Individual dlschorqe oint n separate set ot Section II, Item 6 forms must be f I lied out.
| |
| ITEH 6 PRIORITY POLLUTANTS ANO AGOITIONAL INFORMATION NOTE: If you have two or more substantially Indentlcal outtnlls, you may request permission frcm your permitting authority to s<<cp(e nnd analyze only one outfnl I and submit the results ot the analysis for other substantially Identical outfol ls.
| |
| It your request Is granted by the permitting authcrlty, on a separate sheet attached to the appllcntlon form Identify which outfal I you did test, and describe why the outfalla which you did not test ore substantially Identical,to the outfall which you did test.
| |
| NOTE: 40 CFR Part 122.21(g)(8), Friday, Aprl I I, 1983, provides for a Smal I Business Exemption from the reporting of quantitative data tor organic toxic pollutants and toxic pollutants as required by Port 122.21(g)(7)(ll)(A) or 122.21(g)(T)(ill)(A).
| |
| A ~ -C. These ports are selfwxplanotory ond do not require further Instructions. Simply go through each part and do ns Indicated.
| |
| and E.-J.
| |
| : 0. Several Industrial cotegor les and subcategories hove been exempted fran submltt lng dots on certain GC/MS Fractions (40 CFR Port 122, Vol. 48, No. 64, Friday, Apt II I, 1983, Notes I. 2. and 3).
| |
| the following list to determine whether your facility qualities to be exempt from
| |
| 'eview reporting GC/MS (Gas Chrcmatography/
| |
| Moss Spectroscopy) Fractions.
| |
| GC/MS Frnct ion Testing nnd Reporting Exemptions Textile Mills Induct
| |
| - All four GC/MS organic tractlons In the Greige MII Is Subcategory.
| |
| - Pesticide traction In oil other subports of this Industry.
| |
| Ore Mini n ond Brass l Indust
| |
| - Volatile, base/neutral, and pesticide fractions In the Bose and Precious Metals Subcategory.
| |
| - All four GC/MS organIc fractions In all other Subcategories of this Industry.
| |
| Cue and Mood Chemicals Industr
| |
| - Pesticide fraction In the Tall Oil Rosin Subcategory and the Rosin Based Oerlvatlves Subcategory.
| |
| - Pesticide and base/neutral fractions In all other subcategories of this Industry.
| |
| Pul and Paper Induct Pesticide fraction In Papergrade Sulfite subcatcqories (subparts J and U) .
| |
| - Base/neutral and pesticide fractions in Oelnk Subpart Q, Blssolvinq Kraft Subpart F, and Paperboard from Masts Paper Subpart E. lt
| |
| - Volatile, base/neutral, pesticide fract(ons In the SCT Sleschcd Kraft Subpart H, Saci-chemical Subparts 8 and C, and Nonintegrated"Fine Papers Subpart R.
| |
| - Acid, base/neutral, snd pesticide fractions in Fine Bleached Kraft Subpart I, Olssolvlng Sulfite Pulp Subpart K, Ground-wood Fine Papers Subpart 0, Harket Bleached Kraft Subpart 0, Tissue from Mastepaper Subpart T, and Nonlntegratcd Tissue Papers Subpart S.
| |
| Steam Electric Power Plant Indust 1
| |
| - Base/neutral fraction In the Once-Through Cooling Mater, Fly Ash, and Bottom Ash Transport Mater process wsstestreams.
| |
| 38
| |
| | |
| SECTION II Mj. pop5827 SEE INSTRUCTIONS ON REVERSE SIDE
| |
| ~OO E EM Ae USE THIS DATA SHEET TO RECORD INFGLtLATIOMAS RECUIRED IN: (CHECK APPROPRIATE BOX FIN WICH IMFLJLMATICN THIS DATA SHEET REPRESEMTS ~ )
| |
| 7 O X ls SECTION IIE ITEM Me GROMlLATER DISCHJJLGE INFCttULTION (PAGE 35)
| |
| CRITICAL 2e SECTICN I IE ITEM 6e PRIORITY RXJlJTAMTS IN SLRFACE HATER DISCHLWiE (PAGE 3Tl MATERIALS TOXIC D X 3e Bs BELJJELL CRITICAL MATERIALS (TABLE lv) IN SLJLFACE HATER DIMJLARGE (PAGE 39)
| |
| POLLUTANTS HAZARDOUS SUBSTANCES Be LIST ANY CRITICAL MATERIAL (TABLE IV PAGE 6) NOT ADCRESSED IM SECTICN I I ITEH 6 PRIORllY tOT APPLICABLE POLLJJTAMTS HHICH YOU tlat% OR HAVE REASON lo BELIEVE TO BE PRESENf IN TIE DISCHLRGEI SEE IN REVERSE SIDE OF THIS PAGE FOR FLJLTIER DIRECTICNSE DISCHARGE APPLICABLE (SEE BELCN)
| |
| HydrocIuinone *
| |
| ~~
| |
| Ae NLHE OF CRITICAL MATERIAL CR PRIORITY JOLLJJTANT CE ILLE I
| |
| Be AVERAGE CNCEMIRATICNJ SAMPLE TYPEJ II OF ANALYSES WIT CCDE QHPIE u TYPE OF ANAlYSES
| |
| ~
| |
| LNIT CODE LNIT CODE Ce MAXIt4N CCttCEtmLATICN AIO MASS LJ LJ Ae Ntt% OF CRITICAL MATERIAL CR PRIORllY POLLUTANT CCK SAME LLJ Let I
| |
| Be AVERAGE CCJJCEMIRATICNJ Qt%%E lYPEJ JI OF ANALYSES
| |
| . LLLJ LN IT LJ TYPE OF ANALYSES LNIT CODE LNIT GXK Ce MAXIJLPI CCNCENllVLTION AtO MASS LJ UNITS CODE Ae H4% OF CRITICAL HATERIAL CR PRICRllY POLLIJTANT 1 MQ/I LNIT CCDE SAMPLE TYPE OF ANALYSES Be AVERAGE CotCEJIIRATICNJ QWE TYPEJ f. OF ANALYSES Ug/I LBS/DAY L LN CXK LNIT CODE Ce MAXIJLN COMXMIILATI ON AN) MASS KG/DAY
| |
| ~~
| |
| Ae NA% OF CRITICAL MATERIAL OR PR !OR llY PCLLJJTANT LNIT CCOE SAINTE lYPE OF ANALYSES Be AVERAGE COICEMTRATICNJ QtssLE TYPEJ JI OF ANALYSES LNIT CXK LNIT CODE Ce MAXIJLN COtCEtmLATICN AtO HASS LJ ~ LJ
| |
| ~~
| |
| ~AMPL~TYPg Ae NA% CF CRITICAL HATERIAL CR PRIORITY POLlltfANT 1 GRAB LNIT CXK QtsELE TYPE Jf OF ANALYSES 2 24 HR.COMP. Bs AVERAGE CXCEMTILATIONJ QJ4ELE TYPEJ JJOF ANALYSES
| |
| ~
| |
| LNIT CCDE LNIT CODE Ce HAXD%N COLCEMIILATION AJO MASS LJ ~ LJ
| |
| ~~
| |
| A>> NJ% OF CRITICAL MATERIAL CR PRICRllY POUJJfANT Bs AVERAGE CCNCEMIRATIOIU SAtsLE TYPEJ f/OF ANALYSES
| |
| . LLLJ LN IT CXK LJ UNIT GXK SAftELE lYPE OF ANALYSES HLXINJ1 CCtCEMIILATINIAJO MASS LNIT COIK C
| |
| LJ ~ LJ
| |
| ~~
| |
| Ae NA% OF CRITICAL MATERIAL OR PRICRllY POLLLJTAMT LE IIIIY IEEE EIEEIE YIYE Cs EEICYEEE Littee Be AVERAGE CONCEMIILATICNJ SA+tE TYPE J ff OF ANALYSES I
| |
| LNIT GXK LNIT CODE Ce HAXIJLJL CONXMIRATICN AJO MASS LJ ~ LJ As NA% OF CRITICAL MATERIAL OR PRIORITY PCLLJJTANT LNIT CXE SWALE lYPE OF ANALYSES Be AVERAGE CPJCEtflRATIONJ QPPLE TYPEJ tJ OF ANALYSES LJ UNIT CODE LNIT CODE HAXIKJL CONCEMIRATIOM AtO HASS Ce LJ ADDITIONAL PAGES CF THIS ITBl 7 ARE ATTAC%D FCR 7% REST OF ~ CRITICAL E3 YES MATERIALS AIO/CL PRICRTIY PLXWTAMTS RBXJIRED TD BE REPORTED. K NO
| |
| + Small quantities of Hydroquinone may be used in black and white film developing in emergency situations onl y. No film was developed in 1993 and no hydroquinone was discharged. Approximately oneliter would be used when processing is necessary.
| |
| 39
| |
| | |
| INSTRUCT I ONS FOR COMPLETING SECTION I I ITEM 7 This form Is to be used by both surtace and ground<<ater applicants to record Information on any Michigan critical material, E.P.A.
| |
| provided. This <<ovid Include any chemical priority pollutant, or hazardous substance In <<hich this application requires data to be POllutant Subatanoe tram the MIChlgan CrltICal MaterlalS ReglSter (Table IV), the E.P.A. PrlOrlty LIStlng ITable Y), Or TableS I IA-YA <<hlch I lsts Organic Toxic Pol lutants, Other Toxic Pol lutants, conventional and Nonconventional Pol lutants and Hazardous Substances.
| |
| ITEM 7 CRITICAL MATERIALS PRIORITY POLLUTANTS AND/OR HAZARDOUS SUBSTANCES IN THE DISCHARGE Material I 2, 3... 8 A. List the name of the chemical substance icrltlcal material, priority pollutant, or hazardous substance) fran Tables Iv, V and IIA-YA as required In the box <<hlch you checked In A.I-3 . above. Enter each chemical substance's parameter number as listed In Tables IV, Y and IIA-VA It provided.
| |
| B. Provide the average concentration of the chemical substance named In A. Indicate the sanple type used and the number of analyses made to provide the concentration data for the chemical substance named In A.
| |
| C. Provide the maximus concentration and determine the mass loading ot the chemical substance nmsed In A.
| |
| NDTEs: I. If only one analysis <<as made for a chenlcal substance then record that data as a maxlmvn value. It more than one analysis has been made for a chemical substance then provide an average value of those analyses and the maxlmma value.
| |
| : 2. This Section II, Item 7. Data Sheet provides space for recording data for 8 chemical substances (Haterlals).
| |
| Additional space for recording of data for more than 8 Materials can be made by making copies of this Item 7 Data Sheet as needed. It Is also Important to use a separate set ot Data Sheets for each applicable reporting requirement as listed In A.I-3 . and for each outfall'efer to the lett margin for the code number representing the senple type used and the appropriate unit codes.
| |
| 40
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| | |
| VOLATILE ORGANIC ANALYSIS RESULTS GC/HALL ANALYSES USING EPA METHOD 8010 li n m I ID: . EWA PLANT EFFL LAL Sam le ID: L100-D oil ' -DE - 3 D R iv; 2 -DE Date Anal zed: 05-JAN-94 Dilution Factor: 1 Matrix: WATER QC Batch ID: 122093-801020-0-3 Anal tical Batch ¹: . 122093-801020-0-3 rr t R vr QC Limi s BCM 108 65-125 BFB 85 60-120 Concentration Reporting Constituent Detection Limit Data Iyg/LI /L Qualifierls)
| |
| Dihl r ifl orm hn hlrm hn Vin I chloride <0.50 0.5 Bromomethane hl r hn Trihir fl rm hn 1 1-Dichloroethene <3 Meth lene chloride <6 ran -1 2-Di hl ro h ne 11-Dihl r hn Chloroform 1 1 1-Trichloroethane <4 arb n r hl ride <0.
| |
| 12-Dihl r hn Trichloroethene TCE 1 2-Dichloro ro ane < 0.5 0.5 Brm ihlrm hn 2- hl r h Ivin I her cis-1 3-Dichloro ro ene trans-1 3-Dichloro ro ene 11 -Trihlr hn Ter hir hn P E Dibromochloro methane Chlorobenzene <0.5 0.5 Brom form 1 1 2 2-T r hl r h n 1 3-Dichlorobenzene <2 1 4-Dichlorobenzene 1 2-Dichlorobenzene LOCKHEED ANALYTICALSERVICES hg
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| | |
| VOLATILE ORGANIC ANALYSIS RESULTS GC/PID ANALYSES USING IVIETHOD 8020 li n m I ID: . EWA EP ANT FFL AL ml ID: L1 09-D II ce: 28DE -9 Da R iv: 2-DE-Date Anal zed: 04-JAN-94 Dilution Factor: 1 Matrix: WATER QC Batch ID: 122093-801020-0-3 Anal tical Batch 4': 122093-801020-0-3 urr R v r Q Limi s TFT 93 70-120 BFB 101 75-120 Reporting Concentration Detection Limit Data Constituent IL IL Qualifier s Benzene <0.5 0.5 T I n <0 hl r nz n Eth I Benzene m -X lene <2
| |
| -Xln 1 -Di hl r nzen <2 1 4-Dichlorobenzene 1 2-Dichlorobenzene <2 LOCKHEED AIVALVTICALSERVICES
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| $ 0
| |
| | |
| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 1 of 2 li n m I ID: . EWA E PLANT EFFL LAL m I ID; L1 -47 Date Collected: 28-DEC-93 Date Received: 29-DEC-93 Matrix: WATER Date Anal zed: 11-JAN-94 Anal i I Ba h 0 11 4- 2 -F2 Dil inFc r: 1 QC Batch ID: 011094-8260-F2 SURROGATE RECOVERY QC Limits 1 2-Di hl r h n - 4 7 -114 Tl n-4-Bromofluorobenzene 86 86-115 Reporting Concentration Detection Limit Constituent IL IL Data Qualifier s Ghloromethane <5 Vin I hl rid Br mom hn Chloroethane <5 Trichlorofluoromethane <5 A n 11-Dihl r hn <5 Carbon Disulfide Meth lene Chloride <5 rans-1 2-Di hl r h n Vin I A 1 1-Dichloroethane <5 2-Butanone <10 10 i -1 2-Di hl r hen hlrfrm 1 1 1-Trichloroethane <5 Carbon Tetrachloride <5 12-Dihi r hn B n n Trichloroethene TCE <5 1 2-Dichloro ro ane <5 Bromodi hl r m h n 2- hl ro h IVin IEh r <2 4-Meth I entanone <10 10 cis-1 3-Dichloro ro ene <5 T I n r n-1 -Dihl r r n 2-Hexanone <10 10 1 1 2-Trichloroethane- <5 Tetra chloroethene PCE <5 LOCKHEED ANALYTICALSERVICES
| |
| | |
| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 2 of 2 Client Sam le ID: S. SEWAGE PLANT EFFL. LAL Sam le ID: L1009-47 Reporting Concentration Detection Limit Constituent IL IL Data Qualifier s Dibromochloromethane <5 hir nzn Ehl nz n m -X lene <5 o-X lene <5 r n Br m f rm 1 1 2 2-Tetrachloroethane 1 3-Dichlorobenzene <5 1 4-Di hlor enz ne 1 2-Dichiorobenzene <5 LOCKHEED ANALYTICALSERVICES 22
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| | |
| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 TENTATIVELYIDENTIFIED COMPOUNDS Client Sample ID: S. SEWAGE PLANT EFFL LAL Sample ID: L1009-47 Date Received: 29-DEC-93 Date Analyzed: 11-JAN-94 Matrix: WATER Dilution Factor: 1 Analytical Batch: 011094-8260-F2 QC Batch ID: 011094-8260-F2 Estimated Retention Concentration Time Data Tentatively Identified Compound Iyg/L) (minutes) Qualifierls)
| |
| UNKNOWN SULFUR COMPOUND 37 4.47 UNKNOWN 28 9.70 LOCKHEEO ANALYTICALSERVICES
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| | |
| SEMIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 P 1 f2 li n m I ID: . EWA EP ANT EFFL IAL m I ID: L1 - 1 r:
| |
| Date Collected: 28-DEC-93 Date Received: 29-DEC-93 Matrix: WATER Dilu ion Factor: 1 An I i I B ch ¹': 111 4-827 -B D Ex 4-JAN- 4 QC Batch ID: 8270-SEMIVOLATILES-3964 Date Anal zed: 11-JAN-94 RR ATE RE VERY 0 Limi 2-Fluoro henol 26 21-100 Phenol-d, 18 10-94 Nitrobenzene-d, 61 35-114 2-Fluorobi hen I 54 43-116 2 4 -Tribromo henol 1 -12 p-Terphenyl-d,4 76 33-141 Reporting Concentration Detection Limit n i uen L IL Da a alifi r s Phenol <10 10 bis 2-Chloroeth I ether <10 10 2- hl r hn I 1 -Di hl r nz n 1 4-Dichlorobenzene <10 10 Benz I alcohol <10 10 1 2-Di hl r benz ne 10 2-M h I h nol 10 bis 2-Chloroiso ro I ether <10 10 4-Meth I henol <10 10 N-Ni r -Di-n- r I min Hx hlr hn Nitrobenzene <10 10 Iso horone <10 10
| |
| -Ni r h n I 24-Dimeh I h n I Benzoic acid <50 50 bis 2-Chloroethox methane <10 10 24Dihl r hn I 1 24-Tri hl r nz n Na hthalene <10 10 4-Chloroaniline <10 10 Hx hlr in 4- hl r - -m h I h n I 2-Meth Ina hthalene <10 10 Hexachloroc clo entadiene <10 10 LOCKHEED ANALYTICALSERVICES
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| | |
| SEIViIVOLATILEORGANIC ANALYSIS RESULTS FOR GC/IVIS ANALYSES USING IVIETHOD 8270 Pa 2 f2 Client Sam le ID: S. SEWAGE PLANT EFFL LAL Sam le ID: L1009-31 Reporting Concentration Detection Limit Constituent ( IL) I IL) Data Qualifieris) 24 -Trihl r h n I 24 -Trihl r h n I 2-Chlorona hthalene <10 10 2-Nitroaniline <25 25 Dim h I hh I <10 A n hhln 10 2 6-Dinitrotoluene <10 10 3-Nitroaniline <25 25 A n hhn 2 4 Dini r h n I <2 4-Nitro henol <25 25 Dibenzofuran <10 10 24Dinir I n Di hlhhl 4-Chloro hen I- hen lether <10 10 Fluorene <10 10 4-Ni r nilin <2 4 -Dinir - -m h I h n I <2 N-Nitrosodi hen lamine <10 10 4-Bromo hen I- hen lether <10 10 Hx hlr nzn Pn hlr hnl <2 Phenanthrene <10 10 Anthracene <10 10 Din- I hh I Flu r n hene P rene <10 10 But Ibenz I hthalate <10 10 8 n'hr
| |
| '-Di hl r Chr sene nzi in n
| |
| <2
| |
| <10 10 bis 2-Eth Ihex I hthalate 1.3 10 JB Di-n- I hh I Bnz fl rnhn Benzo k fluoranthene <10 10 Benzo a rene <10 10 In n 1 - rn Di nz h n hr n Benzo h i er lene <10 10 Carbazole <10 10 LOCKHEED AItIALYTICALSERVICES 4 J.
| |
| | |
| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD'8270 TENTATIVELYIDENTIFIED COMPOUNDS Client Sample ID: S. SEWAGE PLANT EFFL LAL Sample ID: L1009-31 Date Received: 29-DEC-93 Date Analyzed: 11-JAN-94 Matrix: WATER Dilution Factor: 1 Analytical Batch: 011194-8270-8 QC Batch ID: 8270-SEIVIIVOLATILES-3964 Estimated Retention Concentration Time Data Tentatively Identified Compound (yg/L) (minutes) Qualifier(s)
| |
| Benzaldehyde 7.85 Unknown 25.05 Unknown 10 27.46 Unknown 30.25 Hydrocarbon 31.99 Hydrocarbon 33.87 LOCKHEED ANALYTICALSERVICES 42
| |
| | |
| PESTICIDE ANALYSES RESULTS BY GC/ECD USING METHOD 8080 FOR COOK NUCLEAR PLANT Clien Sam le ID: S. SEWAGE PLANT EFFL LAL S m le ID: L10 9-2 Date Collec ed: 28-DEC-93 D e R eived:29-JAN-94 Date Extracted: 04-JAN-94 Date Anal zed: 21-JAN-94 Matrix: WATER Dilution Factor: 1 Anal tical Batch 4: 012094-8080-A-1 QC Grou ID: 8080 PEST/PCBS 3965 SURROGATE RECOVERY Oo QC Limits TCMX 70 60-150 DCB 50 60-1 50 Reporting Constituent Concentration Detection Limit Data Qualifier(s)
| |
| /L /L A-BHC <0.05 0.05 B-BHC G-BHC .05 .05 D-BHC <0.05 0.05 HEPTACHLOR <0.05 0.05 ALDRIN . 5 HEPTACHLOR EPOXIDE .0 .0 G-CHLORDANE <0.05 0.05 ENDOSULFAN I <0.05 0.05 A-CHLORDANE < .05 4 4'-DDE < 0.1 0.1 4 4'-DDT < 0.1 0.1 DIELDRIN <0.1 0.1 ENDRIN 0.1 ENDOSULFAN II 0.1 4 4'-DDD < 0.1 0.1 ENDRIN ALDEHYDE < 0.1 0.1 ENDOSULFAN SULFATE METHOXYCHLOR 0.5 TOXAPHENE <5 PCB-101 6 PCB-1 221 <2 P B-12 2 PCB-1242 PCB-1 248 PCB-12 4 PCB-1 260 TECHNICAL CHLORDANE MIREX <0.1 < 0.1 TCMX - tetra-chloro-meta-xylene DCB - Deca-chloro-biphenyl LOCKHEED ANALYTICALSERVICES
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| | |
| METALS RESULTS Client Sam le'D: S..SEWAGE.'.PLANT. EFF, Date Collected. '12-28-93, Matrix:. round. water LAL Batch ID(s): 1220 im Date Received: 12-29-93 PO¹69095-040-3N Reporting Concentration Detection. Umit Data Date LAL'am
| |
| -. Constituents Method -im IL) lm IL) Qualifierls) Anal zed le ID Aluminum 6010 <0.20 0.20 01-20-94 L1009-16 Antimon 6020 <0.060 0.060 01-27-94 L1009-16 Arsenic 6020 <0.010 0.010 01-27-94 L1009-16 Barium 6020 <0.20 0.20 01-27-94 L1009-16 Be Ilium 6020 <0.005 0.005 01-27-94 L1009-16 Boron 6010 <0.20 0.20 01-20-94 L1009-16 Cadmium 6020 <0.005 0.005 01-27-94 L1009-16 Chromium 6020 <0.010 0.010 01-27-94 L1009-16 Cobalt 6020 <0.050 0.050 27-94 L1 009-16 Co er 6020 <0.025 0.025 01-27-94 L1 009-16 Iron 6010 <0.10 0.10 01-20-94 L1009-16 Lead 6020 <0.003 0.003 01-27-94 L1009-16 Ma nesium 6010 14 5.0 01-20-94 L1009-16 Man anese 6020 0.025 0.01 5 01-27-94 L1009-16 Mercu 7470 <0.0002 0.0002 01-07-94 L1009-16 Mol bdenum 6020 <0.20 0.20 01-27-94 L1009-16 Nickel 6020 <0.040 0.040 01-27-94 L1009-16 Selenium 6020 <0.005 0.005 01-27-94 L1 009-1 6 Silver 6020 <0.010 0.010 01-27-94 L1 009-1 6 Sodium 6010 34 5.0 01-20-94 L1009-16 Thallium 6020 <0.010 0.010 01-27-94 L1009-16 Tin 6020 <0.20 0.20 01-27-94 L1009-16 Titanium 6010 <0.10 0.10 01-20-94 L1009-16 Vanadium 6010 <0.050 0.050 01-20-94 L1009-16 Zinc 6020 0.047 0.020 01-27-94 L1009-16 Comments:
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| LOCKHEED ANALYTICALSERVICES
| |
| | |
| GENERAL CHEIVIISTRY RESULTS Client Sam le (D: S. SEWAGE PLANT EFFL Date Collected: 12-28-93 Matrix: round water LAL Batch (D(s): 1229 im Date Received: 12-29-93 POP69095-040-3N Reporting Data Date LAL Constituent Method Result Detection Limit Qualifier(s) Anal zed Sam le'ID Fluoride, in m IL 340.2 <0.15 0.15 01-24-94 L1 009-4 Chloride, in m /L 300.0 120 0.01 6 12-29-93 L1 009-4 Nitrate-Nitro en, in m IL 300.0 24 0.01 7 12-29-93 L1 009-4 Nitrite-Nitro en, in m /L 300.0 <0.50 0.50 12-29-93 L1 009-4 Sulfate, in m IL 300.0 39 0.059 12-29-93 L1 009-4 Ammonia-Nitrogen, 350. 1 24 0.50 D(1: 10) 01-05-94 L1009-8 .
| |
| in m /L Total Cyanide, in mg/L 335.2 < 0.020 0.020 01-03-94 L1009-12 Comments:
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| LOCKHEED ANALYTICALSERVICES
| |
| | |
| SEE INSTRUCTIONS ON REVERSE SIDE SECTION II PERMIT NUMSEA ~ !ail ppp5827
| |
| ~NA i EM t
| |
| Ae B>>
| |
| UXATION OF DISCHARGE H4%
| |
| ~SW <
| |
| RECEIVING HATER (IE>> GROIKWATER CR IU<% OF SIRFACE
| |
| ~SP j DR Y SEtTI I I ~P6 WE TM S
| |
| ~jJQJ RAKE Ce l}0 YOU DISCHARGE (IF IO>>
| |
| S~Y CNTIIAE TO E) YES DISCHARGE LOCATION De IF YES>> LIST DISCHARGE PERIODS tO>> / DAY tO>> / DAY FLOW
| |
| ~ ~
| |
| RATE WASTEWATER ZXHMEK. E>> LAND APPLICATION RAlE IN< tR>>
| |
| ~ LJ IR>> DAY, IN>>/WK>>
| |
| ~
| |
| 'w 1 CONTACT WASTBIATKR TYPE CODE F>> lYPE OF HASTKHATKR DISCHARGE ~3 COOUNQ ~5 2 NONCONTBCT Ge DISCHtRGE SCIHlIE (YEARLY AVERAGE)
| |
| IOURS/DAY COOLINQ 3 PROCESS H>> DISCHARGE FIEN RATE WIT1CCCE lOTAL YEARLY 4 SANITARY 5 STORMWATER 1 MQY I e lIE NXIMPl DISCHIIRGE FlOt RATE TO BE AUMRIZED IH PEBIIT>>
| |
| DAILY HINIttH DAILY SWINII ~25: 0, ~00
| |
| ~3
| |
| ~3 Wl GXK 2 MQD 3 QPD Je HIXIIEPI DESIGN DISCHijRGE FUN RATE<
| |
| Ae IS YOU USE WAlKR TREATISE AEOITIVES TO TRFAT YNR (IF tO CNTIIAK TO ITBI 3)
| |
| DI~ DESIGN ITEM Be t&% FWCTION>> AtO CIKIIICALCPASITIN OF TIIESE AISITIVES>>
| |
| 2 WATER TREATMENT ADDITIVES Ce Hit% AIO AEORKSS OF HAIAFACTIRERS OF TIESE AISITIVES>>
| |
| ~~
| |
| 1 MQ/I 2 UQ/I D>> EXPECTED DISCHARGE CCtCKIIIRATIOH CF AEOIT IVES>>
| |
| HINIMII WITS AVERAGE WITS HAXIISPI WITS CQE COCK AEOITIVE IU%
| |
| M s LJ g LJ ACOITIVE IU%
| |
| LJ I LJI LJ AISITIVE HA%
| |
| LJ '
| |
| LJ ' LJ Ee DO VIXI TREAT TIE DISCHARGE TO RBOVE AISITIVES?
| |
| Fe HIAT IS THE RBOVAL EFFICIBICY ND DIKHARGE FRECEEIICY?
| |
| tRS>>/DAY DAYS/WK>>
| |
| AID!TIVE HA%
| |
| AIS ITIVE NA%
| |
| AEOITIVE tWE G. AS AH ATTACttEHT TO THIS APPLICATIN f%0VIOE SPECIFIC MPH%.IAN OR AOUATIC TOXICOUXIICALDATA CR REFB\BICE WHIOI ARE AVAILAREAND INRRIATIN CN THE RATE CF DKGRAOATIN OF TIE PA0RCG FCR EACH AISITIVE>>
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| 31
| |
| | |
| This form requires Information on the additives.
| |
| ENTER THE PERMIT IAP(8ER PERMIT.
| |
| INSTRUCTIONS FOR COMPI.ETING SECTION I I tacility's IN THE BOX AT THE TOP OF THIS FORM.
| |
| ITEMS I ANO 2 discharge location, discharge schedule, volume tlow rate and voter treatment THE PERMIT INM8ER CAN BE FOUND ON THE FRONT PAGE OF YOUR If this Is a ner or not previously permitted facility, then leave blank and a number vill be assigned.
| |
| Enter the outfall nmber In space provided tor each page of Section II. For each Individual discharge point a EXPIRING separate set of t
| |
| Section II forms must be filled ovt.
| |
| ITEM I DISCHARGE LOCATION SCHEDULE ANO FLOH RATES A. Enter the location of discharge, this should Include qvarter-quarter section, quarter sectIon, section ~ town, snd range.
| |
| B. List name of receiving water (if surface voter discharge).
| |
| C. IndlCnte whether fOClllty dlSChargeS On O SenSOnal bnSIS.
| |
| O. If yes, list discharge periods.
| |
| E. Pro Ide the land application rates used or expected to be used In terms of Inches per hour, hours per doy, nnd Inches per week.
| |
| F~ Indicate the type of wastewater to be dlschnrged fran this outfall. Refer to the wasterster type code given In the lett mn gin. More than one code may be applicable.
| |
| G~ Provide the average nvnber of hours per day In which the facility discharges treated wastevnter ond the total number of days per year In rhiCh the discharge occurs.
| |
| H. Provide current (fran the Inst l2 months) ot'xpected flow rates ss requested. Refer to unit code qlven In the lett margin for the appropriate flow units. MGY - million gallons per year; MGD - million gallons per doyi GPD - gallons per day.
| |
| I. Provide the maximum discharge flow rate which you want to have authorized within the permit. NOTE: For NPDES permits only, the use ot such s t low rote vill not ploce an actual limit restriction on the flow but vill be the flow rote used to develop effluent limits. Also, when the Monthly operating Reports are revie~ed by ccmpllsnce staff It <<III help then to determine if nny ner or increased uses might have occurred st the taclllty.
| |
| J. Provide the design f lor for this specific outtsll discharge (e.g. botch treatment system flow, packaged treatment system t lo ,
| |
| or sane other finite treatment system flow) ~
| |
| ITEM 2 MATER TREATMENT ADO IT IVES A. Indicate ~nether discharge Is treated vlth conditioners, inhibitors, or mlcrobloclde. If not, continue to Item S.
| |
| B. Give nome, function, snd chemical composition of additives used.
| |
| C. Give name and address ot the mnnutscturer(s) of the additives used.
| |
| O. Indicate expected mlnlmNn, svernge and maximum discharge concentrations of the additive(s) for this discharge.
| |
| E. Indicate ~bather you treat the discharge to remove the additive(s) before discharge of wastewater.
| |
| F. ,Indicate the removal eftlclency of each additive {rem the vastcwster and the discharge trequency ot each additive to the surface voter or groundwater.
| |
| G, NOTE: It Is The responsibility of the applicant to supply the product Information as requested In'his Item 4. Information requested but not supplied msy result In the application being returned to the applicant tor completion.
| |
| 32
| |
| | |
| SEE INSTRUCTIONS SECTtON II PERMIT NUMBER ~ Ivil 0005827 ON REVERSE SIDE
| |
| ~N~A A~ NPK OF PROCESS THOROUGH CONIRIBUTING TO THE DISCHARGE THIS OUTFAIL AttO SIC CODE TRANS DECK DRN 4911 Be PRXESS SCHGXAE (YEARLY AVERAGE) t/9 4/t Ce PROCESS HASTEHAT8I FUX4 RATE PROCESS TOTAI. YEARLY Os STREAMS 0CC DAILY MINIMA ~2 CONTRIBUTING CL TO 1 20 00
| |
| ~l DAILY MAXIM' ~2 OUTFALL WITS TIME DISCIIARGE De PROCESS PRODUCTION RATE LJ I ESE L
| |
| ~ SU MPS NAtE OF PROCESS CXIIIBUTIt6TO TIE DISCHARGE Ae TlFOIGH THIS OUTFALL 9% SIC CCÃ D 4 9 1 1 Be PROCESS SCIETXLE (YEARLY AVERAGE) ** /esse/sev seve/vses ttt 4/t Ce IROCESS HASTEHATER FLOW RATE ** TOTAI. YEARLY Ocv 0
| |
| DAILY MINItXT4 JlHIL'Uc5HK T POUNDS DAILY tVNItTT4 2 GALLONS WITS J'TIFE De PROCESS PRODUCTION RATE 3 CUBIC OI LTK
| |
| ~
| |
| ES EL ~49 11 Ae NA% OF PROCESS CONTRIBUTING TO TIE DISCNRGE YARDS TIROXIH THIS OUIFAIL Ate SIC GXE 4 TONS 5 MGY Be PROCESS SCtHXXE (YEARLY AVERAGE) **A esses/sev srs/vses 6 MGD 7 GPD C. PROCES SQSEHteTER Flat RATE *4'* TOTAL YEARLY DAILY MINWH DAILY NXIltN De PROCESS PRODICTICN RATE *** WITS /TIME HOUR Ae NA% OF PROCESS COtnRIBUTit4 TD TIE DISCHARGE AN) SIC OXE 2 DAY 3 WEEK B~ PROCESS SCIEIXXE (YEARLY AVERAGE) 4 MONTH WIT CCOE PROCESS HASTEtliTER PION RATE 5 YEAR TOTAL YEARLY DAILY MINIISTI DAILY tVNIt994 WITS MIME D. PROCESS PIOXXTION RATE Ae NA% OF PROCESS CONTRIBUTII6 TO T% DISCBUIGE ITttXXB THIS OUIFALL AND SIC OXE Be PRXESS SCIEDIXE (YEARI.Y AVERAGE)
| |
| Ce PROCESS HASTEttATER FUJI RATE WIT CODE TOTAL YEARLY DAlLY MIHIISTI DAILY MAXINB De PROCESS PRODUCTION RATE UNITS / TIME Primarily based on rainfall frequency and duration. Deluge testing would be 3-30min/day for no more than 10 days.
| |
| ** EDG sump discharges
| |
| *** No known discharges volumes are insignificant.
| |
| 33
| |
| | |
| INSTRUCTIONS FOR COMPLETING SECTION I I ITEM 3 Tr ls torm requires information on the process streams <<hleh contrlbvte to this discharge.
| |
| ENTER THE PERMIT NWBER IN THE BOX AT THE TOP OF THIS FORM. THE PERMIT NISIBER CAN BE FOUNO ON THE FRONT PAGE OF YOUR EXPIRING PERMIT. \f this Is a new or not previously permitted facility, then leave blank and a number <<ill be assigned.
| |
| Enter outfnl I nvmoer ln sonce provided tor each page ot Section II. For each Individual discharge oint n separate set cf Section II forr>>s must be filled out.
| |
| ITEM 3 PROCESS STREAMS CONTRIBUTING TO OI SCHARGEr FOR EACH SEPARATE PROCESS PROVIOE THE COLL(PING INFORMATION A. Enter the nome of the process which contributes to this discharge. Also provide the proper SIC code.
| |
| B. Indicate tne yearly average process schedule In hours per doy ond days>>per-year.
| |
| C~ provide the process wastewater flow rate information as requested based on your inst I2 months of operations. Refer to unit code given in the left margin for the appropriate flow units.
| |
| O. Process Production Rote Certain permit Itm/totlons may be based on production rates. The production rates used to determine permit limits shall be represented by a reasonnble measure of actual production of the facility, such as the production during the high month of the previous year, or the monthly nveroqe for the highest of the previous five years, or other reasonable measure ns stated in applicable U.S.E.P.A. categorical rules and regulations.
| |
| For new sources or new dlschargers, actunl production shell be estlmoted using projected production.
| |
| Record your production rates ln the terms nnd units used In the applicable U.S.E.P.A. categorical rules and regulations for your type ot facility, 34
| |
| | |
| SECT(ON II PERMIT~
| |
| NUMBER MT 0005827 SEE INSTRUCTIONS ON REVERSE SIDE J EM A. IS THE DISCHARGE FROM THIS OUIFALL DIRECIED TO GROIWDtATERSZ (IF tCI>> CCttTIIAE TO ITBI P) lHE GRCNID OR
| |
| ~~ YES 4 Be HAS A HYDROGEOUXIICAL STUDY OR ITS EQUIVALENT BEEN PERFORtKXI OR IS THERE CURRENI'YCROGEOLOGICAL INFORMATION AVAILABLEAS REQUIRED BY TIE MATER R~ BIFF ICIENT K'' 0 CCttIISSION PART 22 GRONIDtATER RULE/ OF AISUST 14>> 1%9 R>>5ZS>>Z?07 (PAGE ILI) FOR GROUNDWATER lHIS EXISTI% OR PROPOSED DISCHARGE! IF YES ATTADI A CCPY OF THE REPCRT>> Submitted 12/6/91 DISCHARGE INFORMATION Ce ARE YOU RBXKSTIMI AN EXPPTICN FRCM SIKHITTII6 A HYIIIOGEOUXiICALREPORT IXKIER RIAE R>>X5>>22F (Q(PAGE t15) CR FRCM GROL59IATKR MGNITORIgi IIEQUJREMENTS LIBER RIAE Re 25>> (5) (PAGE OF TIE PART 22 BILES>> IF YES ATTACH YES Pg tO COQttENIS AN) EXPLANATION TO DEIDNSTRATE THAT YIXR DISCHARGE ICtID QUALIFY FCR AN EXEtP ION>>
| |
| 5)
| |
| De ARE YOU REQLKSTI% A VARIANCE FIOI RULE 323>>2205 (PAGE THE HATER REQXRCES CCt%ISS ION PART Zi? ~TER (NXIDEGRADATICN) OF RIIESZ IF YES>> ATTACH SUCH DOCU'ANTS AS NECESSARY TO DEMtINSTRATK TIE NEED FOR A VARIANCE IN TERMS OF TIE Q YES Q gl CRITERIA SPECIFIED IN'RID X5>>2210 (PAGE + OF THE PART 2Z RULES>>
| |
| Ee I,IST Alp. CIKHICAL SIBSTANCES HHICH ARE IH M1CHIGAN S CRITICAL MATERIALS REGISTER TABLE IV IPAGE II) AND/OR U>>S>> EPA S PRIORIIY FIXLUTANT LIST TABIK V (PAGE
| |
| : 7) OR ANY OTIER NIICH ARE OR MAY BOXPE INXRIOUS TO T%: DESIGNATED USES OF TIE G(IXNDHATKR IXI TOQSSTANCES TIE NOT APPLICABLE/BELIEVED ABSENT PUBLIC HEALTH THAT ARE DISCHARGED OR EXPECTED TO BE DISCHARGED TO TIE RRIXtCltATERJIY THIS FACILITY>> ESTIMATE THE FINAL EFFIleIT COCBIIRATION AtO REND AIL DATA IN ITBI OF 7
| |
| SECTIIXI I I IN THIS BOOST>>
| |
| T% APPLICANT MAY BE REQIIRED TO DO ACDITICNALHASTE ANALYSES>> 0 PRESENT>> DATA PROVIDED IN ITKM 7 A>> DISCHARGE CHARACTKRISTICS CONCDIIRATION ITEM AVE 5 BCO5 (FIVE DAY BIOCteIICAL OXYGEN BEMA%) LJ COD (OeIICAL CEIYGEH DEMAND) LJ EXPECTED WASTEWATER TOC (TOTAL ORGANIC CARBON) LJ CHARAC
| |
| 'I>>>>les AtttGNIA NITRIXiEN (AS H) LJ TOTAL SUSPEMKD SOLIDS LJ UNiTS CODE TOTAL PteSPHORUS (AS P) 1 Mg/I 2 UO/I TOTAL RESIRNL CttDRINE 3 COUNTS/
| |
| 4 S.U.
| |
| 5 F 100 ml DISSOLVED OXYGEN
| |
| ~. HIH LJ >>LJ 6 LBS/DAY FECAL COLIFORM BACTERIA
| |
| ~TINE (QPPER)
| |
| TKtPERATINE (KINIER)
| |
| ~
| |
| ~ ~
| |
| ~
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| LJ LJ LJ5
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| ~5 LJ LJ SAMPLE JXEF i<>>PCB 0 I L Il G R E A S E Be OIIKR HLSTBWKR CHIIIACIKRISTICS LJ LJ
| |
| ~
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| ~ LJ LJ T
| |
| ~
| |
| AYt O C 1 GRAB LJ 2 24 HOUR COMPOSITE LJ LJ LJ LJ
| |
| ~
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| ~ LJ LJ REOIIRED IIFIXPIATICN RXI QRFACE HATKR DISCHARGES ~
| |
| See attached sample analysis
| |
| | |
| INSTRUCTIO'IS FOR CCMPLETING SECTION I I ITEMS 4 ANO 5 This forrt requires Information on a specific outfall discharging to either the groundraters or the surface ~aters.
| |
| ENTER THC PERMIT NLSIBER IN THE BOX AT THE TCP OF THIS FORM. THE PERMIT hWBER CAN BE FOUND Ot( THE FRONT PAGE OF YOUR EXPIRING pERMIT. If this ls a ne>> or not previously permitted feei llty, then leave blank and a number wll I be assigned.
| |
| Enter the outfall number in the space provided for each paae of Section I I. For each Individual dischar e point a separate set of Section I I forms ( Items 4 and 5) must be f I lied out.
| |
| ITEM 4 GROUNDWATER DISCHARGE INFORMATION (00 NOT IIICLUOE DEEP WELL IIUECTION INFORMATION IN THIS ITEM)
| |
| A.-O. The applicant shall address each of these parts If the discharge fran this outfal I Is to the aroundwater.
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| ITEM 5 EXISTING OR EXPECTED (FOR A NEW DISCHARGE) WASTEWATEP. CHARACTERISTICS OF GROUNDWATER OR SURFACE WATER DISCHARGE (00 NOT INCLUDE W LL IN) I IN IN H A. The applicant shel I report available discharge data (real data for existing discharge or expected data for a proposed discharge)a for the parameters as listed. These parameters shall be addressed for either a surface rater discharge or as appropriate for the groundwater discharge. For assistance In determining appropriate parameters a groundrater dl scharae app I leant may contact Groundwater Duality Division, Permits section or the appropriate Groundwater Duality Division's District office.
| |
| The applicant shall reporr the sample type code best describing each reported piece of data. See coding on the left margin of this form.
| |
| surface water discharge, the applicant must report quantitative data for each parameter identified an
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| ~
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| If this outfall Is
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| . b b ee eel a
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| et tby ebbtdby dee t tlb I ~ e I, 9 tlb bdb d "
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| d bt tt e
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| <<ett b ' e tbl ~ ebllebtl b
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| : 8. If data Is available for other parameters not listed above In A. or other parts of this application the applicant should report that data in the blank spaces provided In this part.
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| I'OTES: I. Unit codes for parmreters reported In parts A and 8 can be found on the lett hand side of this fotta.
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| : 2. Grab sample shall be used to analyze for pH, temperature, tote) phenols, residual chlorine, oil and grease. and fecal coliform In a surface water discharge unless other frequency-sample type analyses are available. See GlossarY (page 48) for definition of grab sample.
| |
| 24-hour composite samples shall be used to analyze for Total B005, ccD, Toc, Amnonla Nitrogen, and Total Suspended Solids In a surface ~ater discharge unless other frequency>>sample type analyses are available. See Glossary (page 4B) for definition of composite sample.
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| : 4. REpoRTING 0F INTAKE DATA. You are not required to report 'unless you wish to demonstrate your el)glbl llty for a metr effluent IimltatiOn far One Or mOre pOllutantS, that IS, an effluent llmltatlOn adjuSted by SubtraCtlng the average level of the pollutant(s) present In your Intake water. NPOES regulations allow net limitations only In certain circumstances. To demonstrate your eligibility, report the average of the results of analyses on your Intake water (lf your rater is treated before use, test the water after it Is treated), and attach a separate sheet containing the folloring for eacn pollutant:
| |
| (a) A statement that the Intake ~ater Is drawn from the body of water into which the discharge Is made.
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| (Otherrlseb you are not eligible for net limitations.)
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| (b) A statement of the extent to which the level of the pollutant Is reduced by treatment of your wastewater.
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| (Your limitations rill be adjusted only to the extent that the pollutant is not removed.)
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| (c) 'when applicable (for example, when the pollutant represents a class of compounds), a demonstration of the extent to which the pollutants In the Intake very physically, chemically, or biologically from the pollutants contained In your discharge. (Your limitations wl I I be adjusted only to the extent that the intake pollutants do not vary frow the discharged pollutants.)
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| : 5. If you have two or more substantially Indentlcal outfalls, you may request permission fran your permitting authoritv to sample and analyze only one outfal I and submit the results of the analysis for other substantially Identical outfalls. If your reauest is granted by the permittlna authority, on a separate sheet attached to the application form Identify which outfall you did test, and describe why the outfal ls>>hich you did not test are SubStantlally ldentlCal tO the Outfall whlCh yOu did teSt.
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| 36
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| | |
| NUS LABORATORY
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| .>L. H<b~On ]gJ$ Two Marquis Office Plaza, Suite 200 aarCOR POR AT I ON 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (4'12) 747-2684 January 11, 1994 Report No.: 00018818 Section A Page 2 LABORATORY ANALYSIS REPORT CLIEHT NAME: INDIANA MICHIGAN POWER COMPANY HUS CLIENT NO: 0663 0018 ADDRESS: ONE COOK PLACE WORK ORDER HO: 55830 BRIDGEMAN, MI 49106- VEHOOR HO: 05411000 ATTENTION: MR. ROLAHD BEEN Carbon Copy:
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| SAMPLE ID: OIL/WATER SEPARATOR DATE SAMPLED: 28-OEC-93 HUS SAMPLE NO: P0258839 DATE RECEIVED: 29.DEC.93 P.O. NO.: 69034-040-3N APPROVED BY: Kieda, Chuck TEST LN CODE OETERMINATIOH RESULT UNITS 1 G122W PCB ANALYSIS PCB-1016 < 0.05 ug/L PCB-1221 < 0.05 ug/L PCB-1232 < 0.05 ug/L PCB-1242 < 0.05 ug/L PCB-1248 < 0.05 ug/L PCB-1254 < 1.0 ug/L PCB-1260 < 1.0 ug/L 3 1106 Carbon, Organic - Nonpurgeable 6 mg/L 4 1680 Oil and Grease, Gravimetric 3 mg/L 5 1490 pH 7.4 COMMENTS:
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| | |
| SEE INSTRUCTIONS SECTION II PERMIT NUMBER
| |
| ~>> IVIz p p p 5827 ON REVERSE SIDE
| |
| ~NA i EM 6
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| REQUESTED INFCRt47ICH IDIEt NEW USE DISCHUIGERS 2IIIIL
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| ~~ ADCRESSED ~ QRFACE HATER DISCHARGERS.
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| PROVIDE EXPECTED VALIES FOR THE CUAMflTATIVEAND QUALITATIVE INFCRHAT ION REOIKSTKD BEUWe A. IS THIS FACILllY A PRItVVIY INDUS1RY? (REFER TO TABLE IA Par< gJ)
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| (IF tOe GO 70 E) (IF Y 5 GO TO B) YES MO PRIORITY POLLUTANTS Be IMIICATE lYPE OF PRIIVUIY INDUSTRY AS LISTED IN TABlE IA (CONTIN% WITH C.)
| |
| PAGoK Q, STM E'LE C PWR AND C. DOES 1HI5 CUIFALL DISCHARGE CctlTAIN ANY PROCESS WASTEWATER?
| |
| (IF NOe GO TO E) (IF YKSe GO 70 D) X YES NO ADDITIONAL INFORMATION Do INDICATE HlICH GC/tm FRACflONS FttST BE TESTED FCR (REFER TQ TABLE Ia Pate 9D
| |
| ~
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| VOLATILE Analysis per FOR KIIE! FOR EACH GC/HS FRACTION OIECKKDeKAOI SPECIFIC ORGANIC TOXIC POLunaNT HITHIN J.B. Beauboeuf SURFACE EacH FRACTIQN t55I BE AMALYIKDFOR (5EE TABLE I IA PAGE 92, IM ADDITIQNe ALL FRIARY Q BASE/NElm4L Target Permit WATER DISCHARGE IMXISTRY APPLICANTS WITH A PROCESS WASTEWATER DISCHARGE'~ PROVIDE QUAtnITATIVE DATA FOR EACH TOXIC POLLUTAMT IN TAKE IIIA PA% Q) e Effluent ONLY RECORD ALL DATA ON FCRHS PROVIDED (ITKH 7) IN THIS BQ)KLETe D cele Limits (CctnttUE HllH E K BELCH) PESTI CIDE
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| ~
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| Ee IF OF THE IN TARE IIA AND IVA PAGES ISgif, BE PROVIDEDe
| |
| ~
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| QRFACE HATER DISCHARGE APPLICAtn (PRIMARY OR SKCOGI4RY IMIXISTRY)e REGARDLE%
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| lYPE OF DISCHUIGKe KMHS OR HAS REASON TQ BELIEVE THAT AHY POLLUTANT LISTED IS DISCHARGED FIKtt ANY QITFAILeltE QIAtntTATIVE DATA ter APPLI CABLE/BELIEVED ABSENt N/A RECCRD AIL DATA ON FORtS PROVIDED (ITKH 7) IN 1HIS BOOKLETe D PRESENT/DATA IS ATTACHED Fe IF ANY QRFACE HATER DISOIARGK APPLICAMT (PRIMARY OR SECONDLY IMXISTRY)e REGARDLESS OF lYPE OF DISCIIARGKe KMXts OR HAS REASON TO BELIEVE ANY POLLUTANTS LISTED IN TABLE VA PAGE + ARE DISCHARCM FRCH ANY QnFAIL TIE APPLICANT Ltd(I DESCRIBE REASONS FOR TIE PQLlnaMT BEING PRESen AMI PROVIDE AMY AVAILABLEQIAMTITATIVEDATAe Q MOT APPLICABLE/BELIEVED assen N/A RECORD ALL DATA ON FOIVts PROVIDED (ITKH 7) IN THIS BCOKLETe D PRESENT/DATA I 5 ATTACHED Ge AIL SIRFACE HATER DISCHARGE APPLICANIS (PRIMARY AMl SECCN04RY IMXITRIES)
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| QR ~actIRKS 2 4. - TRtosfxtfPtEMDIY AcET!c AclD (2, 4, 5-7): wr APPLICABLE/BELIEVED allen
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| - )
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| . 4,~7RtoIuwoPIEMIKY) PRQPAMQIC AOID (SILYKx, Z, 4, 5, TP)
| |
| N/A TRI04xRQPtERx. (TcMPJ 0R HExacMJIRQPtEIE tHCPSJ (ALL DATA FcR TIE ABOVE MIST BE GENERATED USING STAMFORD ANALYTICALCALIIRATICN PROCBXRES) QR
| |
| ~KREIS OR HAS REASCN 1Q BELIEVE THAT TCKQ IS CR tlkY BE PRESBIT IN 7%IR DISOIARGEe REPORT tXIALITATIVE IVITA GENERATED %IOI USED A SCREENING PROCHXRE tOT CALIBRATED HllH At4LYTICALSTAleatme FOR 2 De 7 8e - TEIIIAOLORODI~DIOXIN Q PRESENT/DATA Is ATTAOED
| |
| ~ (tlttt 5 (TCKD)e REQRD AIL DATA Qt FOtts PROVIDED IN THIS BOOKLETe Je IF TtE QRFACE HATER DISCHARGE APPLICAtn KMX6 CR HAS REASON lQ BELIEVE THAT BIQDGICAI, TOXICITY TESTS WERE HADE IN THE tasr TIREK (5) YEARS ON AHY QF TIE APPLICANT 5 Dl OR CN A RECE IVIMG HATER IN REIATION lQ A DISOIARGEe PROVIDE Q ter APPLICABLE N/A Ke THIS ltFORHATION AS AM ATTAOFENT TQ THIS APPLICATIOMe IF A COtnRACT LABORATORY OR CQIQLTIMG FIRN PERFCR%D Petr OF TIE AMAYSES RECUIRED Q APPLICABLE/SKE ATTACHED BY THIS APPLICATIOMe PROVIDE TIE t4V% AHD AICRESS OF EAOt LABORATTRY ttE ANtLYSES PERFCR%D AS AM ATTAOtEtn OF THIS APPLICATIONe OR Flirt AM) Q tOT APPLICABLE pg APPLICABLK/SEE ATTACHED Le DO YCU DISCHARGE ANY TABLES IV PAGE tt AMI OTIER TOXIC OR IMJIRIOUS CteIICAL QBSTAHCES NOT LISTED IN IIA TtRQFtl VA PA4S ~~, IF YES TAN IDEtntNY TIE OKttICAL QISTANCES AND ESTIHATE 7% FINAL EFFURIT CctK:em47ICNS, Slstttr THIS 0 MOT APPLI CABLE IHFORQTIOH AS AM ATTAOPEtn TQ THIS APPLICATION>
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| APPLICABLK/sEE ATTADIKD N/A 37
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| | |
| IHSTRUCTIQNS FOR CCMPLETING SECTION I I ITEM 6 This form requires Information on a specific outfall discharging to the surface waters.
| |
| ENTER THE PEIB(IT NUMBER IN THE BOX AT THE TCP OF THIS FCRM. THE PERMIT N(P(BER CAN BE FOUNO ON THE FRONT PAGE OF YOUR EXPIRING pERMIT. If this Is a new or not previously permitted facility, then leave blank and a number <<III be osslqned.
| |
| Enter the outfall number in the space provided for each page of Section II. For each Individual dlscharoe point o separate set of Section Il, Item 6 forms must be f1 lied out.
| |
| ITEM 6 PRIORITY POLLUTANTS ANO AOOITIONAL INFO(a(ATION NOTE: If yOu haVe twO Or mOre Subatantlal ly IndentlCal OutfallS, yOu may requeSt permlSSIOn frCm yOur permitting authOrlty tO somp(e and analyze only one outfall and submit the results of the analysis for other substantially Identical outfalls.
| |
| If your request Is granted by the permitting authority, on a separate sheet attached to the application form Identify which outfall you did test, and describe why the outfalls which you did not test are substantially ident)col to the outfall whlCh yOu did teSt.
| |
| NOTE: 40 CFR Port I22.2)(g)(8), Friday, April I, l983, provides for a Small Business Exemption from the reporting of quantitative data for orgonlc toxic pollutants and toxic pollutants as required by Part 122.2I(g)(7)(il)(A) or I22.21(g)(7)(ill)(A).
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| A.-C. These parts are selfwxplonatory and do not require further Instructions, Simply go through each part and do as Indicated.
| |
| ond E.-J.
| |
| O. Several Industrial categories and subcategories hove been exempted fran submitting dots on certain GC/MS Fractions (40 CFR Pert l22, Vol. 48, No. 64, Friday, April I, l983, Notes I, 2, ond 3).
| |
| Review the following list to determine whether your facility qualifies to be exempt from reporting GC/MS (Gas ChrcmatographY/
| |
| Moss Spectroscopy) Fractions.
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| GC/MS Fraction Testing and Reporting Exemptions Textile MIIIs Indust
| |
| - All four GC/MS organic fractIons In the Greige MIIIs Subcategory.
| |
| - Pesticide fraction In oil other svbports of this Industry.
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| Ore Mlnln and Dress( Indust
| |
| - Volatile, base/neutral, and pesticide fractions In the Bose and Preclovs Metals Subcategory.
| |
| - All four GC/MS organic fractions ln all other subcategories of this Industry.
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| Gum and Mood Chem(cols Industr
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| - Pesticide fraction In the Tall Oil Rosin Subcategory and the Rosin Based Oerlvatlves Subcategory.
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| Pesticide and base/neutral fractions In ~ II other subcategories of this Industry.
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| Pvl and Paper Indust
| |
| - Pesticide fraction In Papergrade Sulfite subcateqorles (subparts J and U).
| |
| - Base/neutral and pesticide fractions in Oelnk Subpart Q, Olssolvlnq Kraft Subpart F, and Paperboard from Maste Paper Subpart E.
| |
| - Volatile, base/neutral, pesticide fracttons In the BCT Bleached Kraft Subpart H, Sam(-chemical Subparts 8 and C, and Nonlntegrated.F(ne Papers Subpart R.
| |
| - Acid, base/neutral, and pesticide fractions (n Fine Bleached Kraft Subpart I, Dissolving Sulfite Pulp Subpart K, Ground-wood Fine Papers Subpart 0, Harket bleached Kraft Subpart C, Tissue from Mastepaper Subpart T, and Nonlntegrated Tissue Papers Subpart S.
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| Steam Electric Power Plant Industr
| |
| - Base/neutral fraction In the Once-Through Cooling Mater, Fly Ash, and Bottom Ash Transport Mater process wastestreams.
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| 38
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| | |
| SEE INSTRUCTIONS ON REVERSE SIDE SECTION II PERMIT
| |
| ~ Ml 0005827 A. USE THIS DATA SHEET IO RECORD INRXVIATIONAS RECJIRED IN: (DECK APPROPRIATE BOX IOR tttICH INRÃHATICN THIS Dl>>TA SHEEf REPRESBffs>>)
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| CRmCAL Q 1>> SECflOM 1ri IIEII M>> GRIJ&AIER DISCHARGE IMFCVIATION (PJGE 33)
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| MATERIALS O 2>> SECTICN I I >> ITEN 6>> PRICRIIY RXIUTAMTS IH SNFACE IIAIER DISCHIVttK (PAGE 37)
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| TOXIC O 3. B. BEUXI: CRITICAL HAIERIALS (TABLE IV) IN SIXIFACE HATER DISaaeK (PAX 39)
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| POLLUTANTS HAZARDOUS SUBSTANCES B>> LlsT AMv cRITlcAL HATERIAL (TABLE Iv PAGE 6) MDT ADDREssED IN sEcTIctt II IIEH 6 PRIDRllY IN POLUJTAMTS INICH YCJ IOXXI OR HAVE REASON TO BELIEVE TO BE PRESENT IN IIE DISCHUIGE>> SEE z REVERSE SIDE OF 'THIS PAGE FOR FIJIIIER DIRECTICNS>>
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| DISCHARGE APPLICABIE (SEE BEUXI)
| |
| A>> NVK OF CRITICAL HATERIAL CR PRIORITY POLUJTAMT WIT CCK SAWLE lYPE OF ANALYSES FI>> B>> AVERAGE CXCEIIIRATIONJ QPRE lYPEJ ¹ OF JNALYSES LJ
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| ~
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| C>> HAXPSlt CXCENIRATICN AIO HASS WIT CXK WIT CODE A>> MJt% OF CRITICAL HATERIAL CR PRIORllY RXLUTANT NIIT CXK SWEE wc>>I B. AVERAGE CXCENIRATICIJ QFFLE TYPES ¹ OF ANALYSES . LLLJ LJ TYPE OF ANALYSES WIT CXE C>> HAXPelt CNCEIIIRATION AJO HASS WIT CXK UNITS CODE A>> NJJ% OF CRITICAL HAIERIAL CR PRICRtlY POLUJTANT 1 My/I wn AVBIAGE CXCBIIRATIIXIJ SWLE IYPE1 WIT COE QIVLE TYPE IK ANALYSES B, 8 OF ANALYSES Uy/I I 3S/DAY C>> HAXPMI COICEIIIRATICN AIO HASS IN WIT CXK KQ/DAY
| |
| ~~
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| A>> Mt% CF CRITICAL HAIERIJI. CR PRIORllY RJUJJTANT WIT CXK QPAE B>> AVERJGE CDICEIIIRATIONJ QtPLE IYPEJ ¹ OF ANALYSES TYPE HAXPtlt CNCEIIIRATIIXIAJO INIT CODE tillT.CXK C HASS LJ ~ LJ A>> NA% OF CRITICAL HATERIAL CR PRIORITY AXLJJTAMT GRAB
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| ¹ OF ANALYSES Wlr CCK aVez TYPE ¹OF ANALYSES 2 24 HR.COMR I B>> AVERAGE CXCENlltATIIXIJ QfRE IYPEJ LJ C>> HAXPSN CXCBIIRATION AJO HASS INIT COE INIT CODE A>> HAIK OF CRITICAL HATERIAL CR PRICRIIY POLUJfANT WIT CXK QJFIK we B AVERAGE CNCENIRATIOtU Q%LE TYPE J ¹ OF ANALYSES LJ TYPE OF ANALYSES C. HAXPSPICOCBIIRATICN AJO MSS WIT CODE INIT COIK A>> NJPK OF CIITICAL HAIERIJL Ct PRIORIIY RXLllfAMT wI>>', ALE IYIEI ¹ OF ANALYSES IPIIT CCK Qtl>>LE lYPE ¹ OF ANALYSES I
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| AVBIJGE CXCBAltATIOIJ LJ IN I HAXIISPI CXCENIIIATICNAJO HASS INIT CXK CODE C>>
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| LJ
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| ~
| |
| ~~
| |
| A. NVK OF CRITICAL HAIERIAL OR PRIORllY RXUJTAMT we ¹ OF AlWYSES IN II CXK TYPE OF ANALYSES B>> AVERAGE CXXXJIIRATIONJ SAPFLE TYPEJ LJ HAXPSH CaCIIIIRAIICtt AIO HASS Wlr CXK WIT CODE C,
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| LJ ~
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| LJ ADDITreuL PJGES oF THrs IIEH 7 ARE AIIActED POR IIE REST DF IIK cRITrcAL Cl YEs HAIERIALS Jva/Ct PRrarIY PCLIJJTJttfs RECIJIRED TO BE RERXIIED, E JO 39
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| | |
| INSTRUCTIONS FOR CI7ZPLETING SECTION I I ITEN 7 This torm Is to be used by both surface and groundvater applicants to record information on any Michigan critical material, E.P.A.
| |
| priority pollutant, or hazardous substance In vhich this application requires data to be provided. This vould Include any chemical substance from the Hlchlgan Critical Materials Register ITable IV), the E.p.A. priority Pollutant Listing ITable V), or Tables I Ih-Vh which I ists Organic Toxic Pol lutants, Other Toxic Pol lutants, Conventional and Nonconventional Pol lutants and Hazardous Substances.
| |
| ITEN 7 CRITIChL MhTERIALS PRIORITY POLLUTANTS AND/OR HAZARDOUS SU8STANCES IN THE DISCHARGE Material I 2 3 . . . 8 A. List the name of the chemical substance Icrltlcal mater lal, priority pollutant, or hazardous substance) tron Tables IV. "
| |
| and IIA-VA as reoulred In the box vhlch you checked In A.I-3 . above. Enter each chemical substance's parameter number as listed In Tables IV, V and IIA-VA If provided.
| |
| : 8. Provide the average concentration of the chemical substance named In A. Indicate the sample type used and the number of analyses made to provide the ccncentratlon data for the chemical substance nmned In A.
| |
| n C. Provide the maximus concentration and determine the mass loading of the chemical substance naeed In A.
| |
| I ~ I f only one analysis was made for a chealcal substance then record that data as a maximus value. It more then one analysis has been made for a chemical substance then provide an average value of those analyses and the maxlmma value ~
| |
| : 2. This Section II, Iten 7, Data Sheet provides space tor recording data for 8 chemical substances (Materlalsl ~
| |
| Additional space for recording of data tor more than 8 Materials can be made by making copies of this Item 7 Data Sheet as needed. It Is also Important to use a separate set of Data Sheets for each applicable reporting reaulrmnent as listed In A.l-3. and tor each outfall.
| |
| 3~ Refer to the left margin tor the code number representing the 'smapl ~ type used and the appropriate unit codes.
| |
| 40
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| VOLATILE ORGANIC ANALYSIS RESULTS GC/HALL ANALYSES USING EPA METHOD 8010 li n m I ID: TRAN AT HBA IN LAL m I ID: L1 - 7 D II 2 -DE D R iv: 2 -DE Da e Anal zed: 05-JAN-94 Dilution Factor: 1 Matrix WATER QC Batch ID: 122093-801020-0-3 Anal tical Batch 4: 122093-801020-0-3 Srro R vr Limi BCIVI 99 65-125 BFB 76 60-1 20 Concentration Reporting Constituent Detection Limit Data (yg/L) /L Qualifieris)
| |
| Dihlr ifl r m hn hlrm hn Vin I chloride <0.50 0.5 Bromomethane hl r hn Tri hl r fl r m h ne 1 1-Dichloroethene <3 Meth lene chloride <6 r n -1 2-Di hi r h n 11-Dihl r hn Chloroform 1 1 1-Trichloroethane <4 r n r hl rid .5 12-Dihl r hn Trichloroethene TCE 1 2-Dichloro ro ane <0.5 0.5 Brm ihlrm hn 2- hl r hlvin I hr cis-1 3-Dichloro ro ene trans-1 3-Dichloro ro ene 112-Trihl r hn T r hir hn P E Dibromochlorometh an e Chlorobenzene <0.5 0.5 Brmfrm 1122T r hl r han 1 3-Dichlorobenzene <2 1 4-Dichlorobenzene 1 2-Dichlorobenzene LOCKHEED ANALYTICAL SERVICES h7
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| | |
| VOLATILE ORGANIC ANALYSIS RESULTS GC/PID ANALYSES USING IVIETHOD 8020 D
| |
| lin II:
| |
| m I ID: TRAN 2 -DE Date Anal zed: 04-JAN-94 AT HBA IN LAL D R ml iv:
| |
| ID: L1 Dilution Factor: 1 2 -DEC-
| |
| -7 Matrix: WATER QC Batch ID: 122093-801020-0-3 Anal tical Batch II: 122093-801020-0-3 rr R vr Q Limi s TFT 89 70-120 BFB 89 75-120 Reporting Concentration Detection Limit Data Constituent IL IL Qualifier s Benzene <0.5 0.5 T I ne hlr n n Eth I Benzene m -X Iene
| |
| -X I n 1 -Dihl r n n <2 1 4-Dichlorobenzene 1 2-Dichlorobenzene <2 LOCKHEED ANALYTICALSERVICES
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| SEIVIIVOLATILEORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 P 1 f2 li n m I ID: TRAN . AT HBA IN LAL m I ID: L1 -2 Date Collected: 28-DEC-93 Date Received: 29-DEC-93 Matrix: WATER Dilution Factor: 1 An I i IB h¹': 111 4- 27 -8 D Exr: 4- AN- 4 QC Batch ID: 8270-SEMIVOLATILES-3964 Date Anal zed: 11-JAN-94 RRO ATE RE VERY Limi 2-Fluoro henol 38 21-100 Phenol-d, 28 10-94 Nitro benzene-d, 59 35-114 2-Fluorobi hen I 62 43-116 2 4 -Tribrom h n I 1 -12 p-Terphenyl-d 84 33-141 Reporting Concentration Detection Limit n I n L L D alifi r Phenol bis 2-Chloroeth I ether 2- hl r hn I 1 -Di hl r nz n 1 4-Dichlorobenzene Benz I alcohol 12Dihl r nz n 2-M h I h n I bis 2-Chloroiso ro I ether 4-Meth I henol N-Ni r -Di-n- r I min Hx hlr hn Nitrobenzene Iso horone 2-Ni r h n I 2 4-Dim h I h n I Benzoic acid <55 55 bis 2- hloroethox me hane 24-Di hl r h n I 1 4Tri hl r nz n Na hthalene 4-Chloroaniline Hx hlr in 4- hlr--m hlhnl 2-Meth Ina hthalene Hexachloroc clo entadiene LOCKHEED ANALYTICALSERVICES U5
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| SEMIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/IVIS ANALYSES USING IVIETHOD 8270 P 2 f2 Client Sam le ID: TRANS. CATCHBASIN LAL Sam le ID: L1009-29 Reporting Concentration Detection Limit Constituent ( IL) ( IL) Data Qualifier(s) 24 -Trihl r hn I 24 -Trihl r h n I 2-Chlorona hthalene 2-Nitroa niline <28 28 Dim h I hh I A n hhln 2 6-Dinitrotoluene 3-Nitroaniline <28 28 A n hhn 24-Dinir h n I <2 4-Nitro henol <28 28 Dibenzofuran 2 4-Dini r I n Di h I hh(
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| 4-Chloro hen I- hen lether Fluorene 4-Ni r nilin <2 4 -Dini r m h I h n I <2 N-Nitrosodi hen lamine 4-Bromo hen I- hen lether Hx hlr nzn Pn hlr hnl <2 Phenanthrene Anthracene Di-n- I hh I Fl rnhn P rene But Ibenz I hthalate
| |
| '-Di hl r nzi in <22 22 B nz nhr n Chr sene bis 2-Eth Ihex I hthalate 280 EB Di-n- I hh I 8nz fl rnhn Benzo k fluoran hene Benzo a rene In n 12 - rn Di nz h n hr n Benzo h i er lene Carbazole LOCKHEED ANALYTICALSERVICES
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| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8270 TENTATIVELYIDENTIFIED COMPOUNDS Client Sample ID: TRANS. CATCHBASIN LAL Sample ID: L1009-29 Date Received: 29-DEC-93 Date Analyzed: 114AN-94 Matrix: WATER Dilution Factor: 1 Analytical Batch: 011194-8270-B QC Batch ID: 8270-SEMIVOLATILES-3964 Estimated Retention Concentration Time Data Tentatively Identified Compound (pg/L) (minutes) Qualifier(s)
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| Hydrocarbon 14.50 Hydrocarbon 10 1 5.00 Unknown 1 5.83 Hydrocarbon 20 1 6.75 Unknown 10 17.58 Hydrocarbon 20 17.79 Unknown 10 1 8.01 Hydrocarbon 30 18.40 Unknown 19.17 Unknown 10 1 9.25 Hydrocarbon 10 19.42 Hydrocarbon 30 19.96 Hydrocarbon 30 21.43 Hydrocarbon 30 21.51 Unknown 22.32 Hydrocarbon 20 22.95 Hydrocarbon 10 24.1 7 Hydrocarbon 24. 54 Hydrocarbon 10, 25.43 Hydrocarbon 26.65 LOCKHEED ANALYTICALSERVICES 7
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| u I
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| SEIVllVOLATILEORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Pa e1of2 lin m I ID: TRAN . AT HBA IN LAL m I ID: L1 -2 RE D II -D D R iv ' -DE Matrix: WATER Dilu ion Factor: 4 Anal tical Batch II'11194-8270-B Date Extracted: 04-JAN-94 QC Batch ID: 8270-SEMI VOLATILES-3964 Date Anal zed: 18-JAN-94 SURROGATE RECOVERY Q Limi s 2-Fl r h n I 42 21-1 Phenol-d, 28 10-94 Nitrobenzene-d, 56 35-114 2-Fluorobi hen I 66 43-116 2 4 6-Tribromo henol 76 10-123 p-Terphenyl-d,4 72 33-141 Reporting Concentration Detection Limit n iun L L D Phn I <4 bis 2-Chloroeth I ether <40 40 2-Chloro henol <40 40 1 -Dihl r nz n <4 14Dihl r nz n <40 Benz I alcohol <40 40 1 2-Dichlorobenzene <40 40 2-M h I h n I <4 i 2-hlri r I hr <4 4-Meth I henol <40 40 N-Nitroso-Di-n- ro lamine <40 40 Hx hlr hn <4 Ni r nz n <4 Iso horone <40 40 2-Nitro henol <40 40 24-Dim h I h n I <4 B n i i bis 2-Chloroethox methane <40 40 2 4-Dichloro hanoi <40 40 1 2 4Tri hl r n n <4 N hhln <4 4-Chloroaniline <40 40 Hexachlorobutadiene <40 40 4- hlr- -m hlhnl <4 2-M h Ina h hal n <4 Hexachloroc clo entadiene <40 40 LOCKHEED ANALYTICALSERVICES
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| SEIVIIVOLATILEORGANIC ANALYSIS RESULTS FOR GC/IVIS ANALYSES USING METHOD 8270 P 2 f2 Client Sam le ID: TRANS. CATCHBASIN LAL Sam le ID: L1009-29RE Reporting Concentration Detection Limit Constituent ( IL) ( IL) Data Qualifier(s) 24 -Trihi r h n I <4 24 -Trihl r hn I <4 2-Chlorona hthalene <40 4Q 2-Nitroaniline <100 100 Dim h I hh I <4 A n hhln <4 2 6-Dini ro oluene <40 4Q 3-Nitroaniline <100 100 A n hhn <4 2 4-Dini r h n I 4-Nitro henol < 100 100 Dibenzofuran <40 4Q 2 4-Dini r lu n <4 4p Di hlhhl <4 4-Chloro hen I- hen lether <40 4Q Fluorene <40 4Q 4-Ni r nilin 4 -Dini r m h I h n I N-Nitrosodi hen lamine'-Bromo
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| <40 40 hen I- hen lether <40 40 Hx hlr n n <4 Pn hir hnl Phenanthrene <40 4Q Anthracene <40 4p Din- I hh I <4 Fl rnhn <4 P rene <40 40 But Ibenz I hthalate <40 40
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| '-Dihl r ni in B nz n hr n <4 Chr sene <40 40 bis 2-Eth Ihex I hthalate 350 4p Di-n- I hh I <4 Bnz fl rnhn <4 Benzo k fluoranthene <40 "40 Benzo a rene <40 40 In n 12 r n <4 Di nz h n hr n <4 Benzo h i er lene <40 40 Carbazole <40 40 LOCKHEED ANALYTICALSERVICES
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| PESTICIDE ANALYSES RESULTS BY GC/ECD USING METHOD 8080 FOR COOK NUCLEAR PLANT Clien Sam le ID: TRANS CATCHBASIN LAL Sam Ie ID: L1009-21 Da e Collec ed: 28-DEC-93 D e Received:29-JAN-94 Date Extracted: 04-JAN-94 Date Anal zed: 21-JAN-94 Matrix: WATER Dilution Factor: 1 Anal tical Batch 4: 012094-8080-A-1 QC Grou ID: 8080 PEST/PCBS 3965 SURROGATE RECOVERY o QC Limits TCMX 85 60-150 DCB 40 60-150 Reporting Constituent Concentration Detection Limit Data Qualifier(s)
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| /L /L A-'BHC <0.05 0.05 B-BHC .0 G-BH D-BHC <0.05 0.05 HEPTACHLOR <0.05 0.05 ALDRIN <0. 5 0. 5 HEPTACHLOR EPOXIDE G-CHLORDANE <0.05 0.05 ENDOSULFAN I <0.05 0.05 A-CHLORDANE <0.05 0.0 4 4'-DDE 4 4'-DDT <0.1 0.1 DIELDRIN <0.1 0.1 ENDRIN ENDOSULFAN II 4 4'-DDD < 0.1 0.1 ENDRIN ALDEHYDE <0.1 0.1 ENDOSULFAN SULFATE < 0.1 0.1 METHOXYCHLOR <0.5 TOXAPHENE <5 PCB-1016 PCB-1221 <2 PCB-1232 PCB-1242 PCB-1248 PCB-1254 PCB-12 0 TECHNICAL CHLORDANE MIREX < 0.1 <0.1 TCMX - tetra-chloro-meta-xylene DCB - Deca-chloro-biphenyl LOCKHEED ANALYTICALSERVICES g h VV
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| METALS RESULTS Client Sam le ID: TRANS. CATCHBASIN Date Collected: 12-28-93 Matrix: round "water:
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| LAL Batch ID(s): 1220 im Date Received: 12-29-93 POP69095-040-3N
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| . Conitituents- . Method Concentration
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| .{m IL)
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| Reporting Detection Umit lm /L)
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| Data Qualifieris)
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| Date:
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| Anal zed;.:-
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| ''AL.
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| Sam le ID Aluminum 6010 <0.20 0.20 01-20-94 L1009-15 Antimon 6020 <0.060 0.060 01-27-94 L1009-16 Arsenic 6020 <0.010 0.010 01-27-94 L1009-15 Barium 6020 <0.20 0.20 01-27-94 L1009-15 Be Ilium 6020 <0.005 0.005 01-27-94 L1009-15 Boron 6010 <0.20 0.20 01-20-94 L1009-15 Cadmium 6020 <0.005 0.006 01-27-94 L1 009-1 5 Chromium 6020 <0.010 0.010 01-27-94 L1 009-1 5 Cobalt 6020 <0.060 0.060 01-27-94 L1 009-1 5 Co er 6020 <0.025 0.025 01-27-94 L1009-15 tron 6010 0.54 0.10 01-27-94 L1 009-15 Lead 6020 <0.003 0.003 01-27-94 L1009-15 Ma nesium 6010 1.6 5.0 01-20-94 L1 009-1 5 Man anese 6020 0.059 0.015 01-27-94 L1009-15 Mercu 7470 <0.0002 0.0002 01-07-94 L1009-15 Mol bdenum 6020 <0.20 0.20 01-27-94 L1009-15 Nickel 6020 <0.040 0.040 01-27-94 L1009-16 Selenium 6020 <0.005 0.005 01-27-94 L1009-15 Silver 6020 <0.010 0.010 01-27-94 L1 009-15 Sodium 6010 <5.0 5.0 01-20-94 L1 009-1 5 Thallium 6020 <0.010 0.010 01-27-94 L1 009-1 5 Tin 6020 <0.20 0.20 01-27-94 L1 009-15 Titanium 6010 < 0.10 0.10 01-20-94 L1 009-15 Vanadium 6010 <0.050 0.050 01-20-94 L1 009-1 5 Zinc 6020 0.15 0.020 01-27-94 L1 009-15 Comments:
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| LOCKHEED ANALYTICAL SERVICES
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| GENERAL CHEMiSTRY RESULTS Client Sam le ID: TRANS. CATCHBASIN Date Collected: 12-28-93 Matrix: round water LAL Batch IDIs): 1229 im Date Received: 12-29-93 PO¹69095-040-3N Reporting Data Date LAL Constituent Method Result Detection Limit Qualifierlsl Anal zed Sam le ID Fluoride, in m /L 340.2 <0.15 0.15 01-24-94 L1 009-3 Chloride, inm IL 300.0 0.52 0.016 12-29-93 L1009-3 Nitrate-Nitro en, in m IL 300.0 <0.017 0.01 7 12-29-93 L1009-3 Nitrite.Nitro en, in m IL 300.0 <0.012 0.01 2 1 2-29-93 L1009.3 Sulfate, inm IL 300.0 4.7 0.059 12-29-93 L1009-3 Ammonia-Nitrogen, 350. 1 13 0.50 DI1:10) 01-05-94 L1009-7 inm IL Total Cyanide, in mg/L 335.2 < 0.020 0.020 01-03-94 L1 009-1 1 Comments:
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| LOCKHEED ANALYTICALSERVICES
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| VOLATILE ORGANIC ANALYSIS RESULTS GC/HALL ANALYSES USING EPA METHOD 8010 li n m I ID: BLANK LA m I ID: AD 17 D Coll ' A D R iv: NA Date Anal zed: 04-JAN-94 Dilution Factor: 1 Matrix: WATER QC Batch ID: 122093-801020-0-3 Anal tical Batch 4: 122093-801020-0-3 urro a e Recover Limi s BCM 94 65-125 BFB 94 60-120 Concentration Reporting Constituent Detection Limit Data (yg/L) IL Qualifier(s)
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| Di hl r ifl or me h ne hlrm hn Vin I chloride <0.50 0.5 Bromomethane hlr hn Trihlrfl rm hn 1 1-Dichloroethene <3 Meth lene chloride <6 r n -1 2-Di hl r h n 11-Dihl r hn Chloroform 1 1 1-Trichloroethane <4 r n r hl ri <0.
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| 12-Dihl r hn Trichloroethene TCE 1 2-Dichloro ro ane <0.5 0.5 Brom i hl rome h n 2- hlr hlvinl hr cis-1 3-Dichloro ro ene trans-1 3-Dichloro ro ene 1 1 -Tri hl r han T r hlr hn P E Dibromochlorom ethane Chlorobenzene <0.5 0.5 Br m f rm 1 1 22-T ra hl ro han 1 3-Dichlorobenzene <2 1 4-Dichlorobenzene 1 2-Dichlorobenzene LOCKHEED ANALYTICAL SERVICES
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| VOLATILE ORGANIC ANALYSIS RESULTS GC/PID ANALYSES USING IVlETHOD 8020 li n m I ID: BLANK LAL ml ID: AD 17 D e lie e: NA D R iv: NA Date Anal zed: 04-JAN-94 Dilution Factor: 1 Matrix: WATER QC Batch ID: 122093-801020-0-3 Anal tical Batch ¹: 122093-801020-0-3 rr R vr QC Limi TFT 102 70-120 BFB 99 75-120 Reporting Concentration Detection Limit Data Constituent /L /L Qualifier s Benzene <0.5 0.5 T I n hlr nzn Eth I Benzene m -X lene <2
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| -X I n 1 -Di hl r nz n <2 1 4-Dichlorobenzene 1 2-Dichlorobenzene <2 LOCKHEED ANALYTICAL SERVICES t,'Z
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| AQUEOUS MATRIX SPIKE DATA
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| ==SUMMARY==
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| FOR VOLATILEORGANIC ANALYSIS USING EPA IVIETHOD 8010 Client Sample ID: MATRIX SPIKE/DUPLICATE LAL Sample ID: L1012-7 Analytical Batch 4:.122093-801020-0-3 Date Analyzed: 05-JAN-94 QC Batch ID: 122093-801020-0-3 QC Limits Spike Sample IVlatrix Spike Constituent Added Concentration Concentration lpg/L) tpg/L) lyg/L) Recovery Recovery 1,1-Dichloroethene 15 ND 7.30 49 28-167 Trichloroethene 15 ND 14.5 97 35-146 Chlorobenzene 15 ND 1 2.6 84 38-150 QC Limits Matrix Spike Spike Duplicate Constituent Added Concentration Recovery RPD RPD Recovery lyg/L) (pg/L) 1,1-Dichloroethene 15 11.4 76 43+ 20 28-167 Trichloroethene 15 14.5 97 20 35-146 Chlorobenzene 15 12.6 84 20 38-150 LOCKHEED ANALYTICALSERVICES Il
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| AQUEOUS MATRIX SPIKE DATA
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| ==SUMMARY==
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| FOR VOLATILE ORGANIC ANALYSIS USING EPA METHOD 8020 Client Sample ID: MATRIX SPIKE/DUPLICATE LAL Sample ID: L1012-7 Analytical Batch ¹: 122093-801020-0-3 Date Analyzed: 05-JAN-94 QC Batch ID: 122093-801020-0-3 QC Limits Spike Sample Matrix Spike Constituent Added Concentration Concentration (yg/L) (yg/L) (yg/L) Recovery Recovery Benzene 15 ND 12.9 86 39-1 50 Toluene 15 ND 12.5 83 46-148 Chloroben zen e 15 ND 12.6 84 55-135 QC Limits Matrix Spike Spike Duplicate Constituent Added Concentration Recovery RPD RPD Recovery lyg/L) (yg/L)
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| Benzene 15 12.4 83 20 39-150 Toluene 15 1 2.0 80 20 46-148 Chlorobenzene 15 12.6 84 20 55-135 LOCKHEED ANALYTICALSERVICES 12
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| LCS DATA SUNIMARY FOR VOLATILEORGANIC ANALYSIS USING EPA METHOD 8010 Client Sample ID: LCS LAL Sample ID: AD5177 Analytical Batch ¹: 122093-801020-0-3 Date Analyzed: 04-JAN-94 QC Batch ID: 122093-801020-0-3 QC Limits Spike Blank LCS Constituent Added Concentration Concentration (yg/L) I/Ig/L) Iyg/L) Recovery Recovery 1,1-Dichloroethene 15 ND 9.1 28-167 Trichloroethene 15 ND 1 5.0 100 35-146 Chio robenzene 15 ND 1 2.2 81 38-1 50 LOCKHEEO AIVALV7'ICAL SERVICES
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| LCS DATA SUIVIMARY FOR VOLATILEORGANIC ANALYSIS USING EPA METHOD 8020 Client Sample ID: LCS LAL Sample ID: AD5177 Analytical Batch //: 122093-801020-0-3 Date Analyzed: 04-JAN-93 QC Batch ID: 122093-801020-0-3 QC Limits Spike Blank LCS Constituent Added Concentration Concentration Ipg/L) (yg/L) (/Ig/L) Recovery Recovery Benzene 15 ND 14.9 99 39-150 Toluene 15 ND 14.1 94 46-148 Chlorobenzene 15 ND 14.4 96 55-135 LOCKHEED ANALyTICALSERVICES
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| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 1 of 2 li n am I ID: BLANK LAL m le ID: AD 214 Date Collected: N A Date Received: N/A Matrix: WATER Date Anal zed: 11-JAN-94 Anl i IB h¹: 11 4- 2 -F2 Dil inF r: 1 QC Batch ID: 011094-8260-F2 SURROGATE RECOVERY QC Limits 1 2-Di hl r h n - 4 7 -114 Tlen-8 1 2 4-Bromofluorobenzene 94 86-115 Reporting Concentration Detection Limit Constituent /L /L Data Qualifier s Chloromethane <5 Vin I hl ri Bromom h n Chloroethane <5 Trichlorofluoro methane <5 A n 11-Dihl r hn Carbon Disulfide <5 Meth lene Chloride <5 ran -1 2-Di hl ro h n Vin I A 1 1-Dichloroethane <5 2-Butanone <10 10 i Di hl r h n hl r f rm 1 1 1-Trichloroethane <5 Carbon Tetrachloride <5 12Dihi r hn Benz ne Trichloroethene TCE <5 1 2-Dichioro ro ane <5 Brom i hl rom h n 2Chl r h IVin I h r <2 4-Meth 1 entanone <10 10 cis-1 3-Dichloro ro ene <5 Tol n rn-1 -Dihlr r n 2-Hexanone <10 10 1 1 2-Trichloroethane <5 Tetrachloroethene PCE <5 LOCKHEED ANALYTICAL SERVICES Cq g
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| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 2 of 2 Client Sam le ID: BLANK LAL Sam le ID: AD5214 Reporting Concentration Detection Limit Constituent IL IL Data Qualifier s Dibromochloromethane <5 hl r nzen Ehl nzn m -X lene <5 o-X lene <5 r n Br m f rm 1 1 2 2-Tetrachloroethane <5 1 3-Dichlorobenzene 1 4-Di hl r nz n 1 2-Dichlorobenzene <5 LOCKHEED AIVALYTICALSERVICES
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| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 TENTATIVELYIDENTIFIED COMPOUNDS Client Sample ID: BLANK LAL Sample ID: AD5412 Date Received: N/A Date Analyzed: 11-JAN-94 Matrix: WATER Dilution Factor: 1 Analytical Batch: 011094-8260-F2 QC Batch ID: 011094-8260-F2 Estimated Retention Concentration Time Data Tentatively Identified Compound (yg/L) (minutes) Qualifierls)
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| NONE (10 0.00 LOCKHEED ANALYTICAL SERVICES r.6
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| WATER MATRIX SPIKE DATA
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| ==SUMMARY==
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| FOR VOLATILEORGANIC ANALYSIS USING EPA METHOD 8260 Client Sample ID: MATRIX SPIKE/DUPLICATE LAL Sample ID: L968-27MS/MSD Analytical Batch: 011294-8260-F2 Date Analyzed: 124AN-94 QC Batch ID: 011294-8260-F2 QC Limits Spike Sample Matrix Spike Constituent Added Concentration Concentration (yg/L) (yg/L) (yg/L) Recovery Recovery 1,1-Dichloroethene 50 1.2 99 62-1 24 Benzene 50 1.4 51 99 67-1 27 Trichloroethene 50 1.2 52 102 60-1 20 Toluene 50 1.7 52 101 72-132 Chlorobenzene 50 54 106 68-128 QC Limits Matrix Spike Spike Duplicate Constituent Added Concentration Recovery RPD RPD Recovery
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| . (yg/L) (yg/L) 1,1-Dichloroethene 50 49 96 14 62-124 Benzene 50 99 67-1 27 Trichloroethene 50 50 98 14 60-120 Toluene 50 51 99 13 72-132 Chlorobenzene 50 53 104 13 68-128 LOCKHEED ANALYTICAL SERVICES 2(
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| WATER LCS DATA
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| ==SUMMARY==
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| FOR VOLATILEORGANIC ANALYSIS USING EPA METHOD 8260 Client Sample ID: LCS LAL Sample ID: AD5213 Analytical Batch: 011094-8260-F2 Date Analyzed: 11-JAN-94 QC Batch ID: 011094-8260-F2 QC Limits LCS Constituent Recovery Recovery 1,1-Dichloroethene 100 62-124 Benzene 108 67-127 Trichloroethene 60-120 Toluene 110 72-132 Chio rob enzene 117 68-128 LOCKHEED AIVALYTICAL SERVICES
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| SEIVllVOLATILEORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 P 1 f2 Clien am I ID: BLANK LAL Sam Ie ID: 9 4MB Date Collected: N/A Date Received: N/A Matrix: WATER Dilution Factor: 1 Anl i IB h¹: 111 4- 27 -B QC Batch ID: 8270-SEMIVOLATILES-3964 D Exr: 4- AN- 4 Date Anal zed: 11-JAN-94 URR GATE RECOVERY I C Limi 2-Fluoro henol 43 21-100 Phenol-d, 27 10-94 Nitrobenzene-d, 66 35-114 2-Fluorobi hen I 64 43-116 246-Tribr m h n I 1 -12 p-Terphenyl-d 86 33-141 Reporting Concentration Detection Limit C ns i en /L /L Da a ualifier Phenol <10 10 bis 2-Chloroeth I ether <10 10 2- hir hnl 1 -Dihl r nz n 1 4-Dichlorobenzene <10 10 Benz I alcohol <10 10 12-Di hl r nz n 2M h I h n I bis 2-Chioroiso ro I ether <10 10 4-Meth I henol <10 10 N-Ni r -Di-n- r I min Hx hlr hn Nitrobenzene <10 10 Iso horone <10 10 2-Ni r h n I 2 4-Dim h I hen I <10 Benzoic acid <50 50 bis 2-Chloroethox methane <10 10 2 4-Dichl r h n I
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| '1 2 4-Tri hl r nz n <10 Na hthalene <10 10 4-Chloroaniline <10 10 Hex hl r inc <10 10 4- hl r - -m h I hn I 2-Meth Ina hthalene <10 10 Hexachloroc clo entadiene <10 10 LOCKHEED AIVALYTICAL SERVICES
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| p, t SEIVIIVOLATILEORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 P 2 f2 Client Sam le ID: BLANK LAL Sam fe ID: 3964MB Reporting Concentration Detection Limit Constituent I IL) ( IL) Data Qualifierls) 24 -Trihl r hn I 24 -Trihl r hn I 2-Chlorona hthalene <10 10 2-Nitroaniline <25 25 Dim h I hh I A n hhln <10 2 6-Dinitrotoluene <10 10 3-Nitroaniline <25 25 A n hhn 2 4-Dini r h n I <2 4-Nitro henol <25 25 Dibenzofuran <10 10 2 4Dini r I n Di h I hh I e 4-Chloro hen I- hen lether <10 10 Fluo rene < 10'2 10 4-Ni r nilin 4 -Dinir m h I h n I <2 N-Nitrosodi hen lamine <10 10 4-Bromo hen I- hen lether <10 10 Hx hlr nzn Pn hlr hnl Phenanthrene <10 10 Anthracene <10 10 Di-n- u I hh I Fl rnhn P rene <10 10 But Ibenz I hthalate <10 10
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| '-Di hl r nzi in <2 8 nz n hr n Chr sene <10 10 bis 2-E h Ihex I h halate 1.3 10 Di-n- I hh I Bnz fl rnhn Benzo k fluoranthene <10 10 Benzo a rene <10 10 In n 12 - rn Di nz h n hr n Benzo h i er lene <10 10 Carbazole <10 10 LOCKHEED ANALYTICALSERVICES
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| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8270 TENTATIVELYIDENTIFIED COMPOUNDS Client Sample ID: BLANK LAL Sample ID: 3964MB Date Received: N/A Date Analyzed: 11-JAN-94 Matrix: WATER Dilution Factor: 1 Analytical Batch: 011194-8270-B QC Batch ID: 8270-SEMIVOLATILES-3964 Estimated Retention Concentration Time Data Tentatively Identified Compound iyg/LI lminutesl Qualifier(s)
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| None LOCKHEED ANALYTICALSERVICES
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| SEIVIIVOLATILEORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 P 1 f2 lin mi ID: L LAL m I ID: 4 Date Collected: N/A Date Received: N/A Matrix: WATER Dilution Factor: 1 Anal i alB h¹: 111 4- 27 -B QC Batch ID: 8270-SEMIVOLATILES-3964 D Ex ra: 04- AN- 4 Date Anal zed: 11-JAN-94 RR ATE RECOVERY Limi 2-Fluoro henol 37 21-100 Phenol-d, 26 10-94 Nitro benzene-d, 60 35-114 2-Fluorobi hen I 60 43-1 1 6 246-Tri rom h n I p-Terphenyl-d 80 33-141 Reporting Concentration Detection Limit n i n L /L D Phenol 40 10 bis 2-Chloroeth I ether <10 10 2- hlr hnl 10 1 -Di hl r nz n 1 4-Dichlorobenzene 39 10 Benz I alcohol <10 10 12-Dihl r nz n 2-M hlhnl bis 2-Chloroiso ro I ether <10 10 4-Meth I henol <10 10 N-Ni r -Di-n- r I min Hx hlr hn Nitro benzene <10 10 Iso horone <10 10 2-Ni r hen I 10 2 4-Dime h I h nol 10 Benzoic acid <50 50 bis 2-Chloroethox methane <10 10 4-Dihl r hn I 1 2 4-Tri hl r nz n Na h halene <10 10 4-Chloroaniline <10 10 Hx hlr in 4- hlr--m hlhnl 100 2-Me h Ina hthalene <10 10 Hexachloroc clo entadiene <10 10 LOCKHEED ANALy'TICALSERVICES
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| SEMIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Pa 2 f2 Client Sam le ID: LCS LAL Sam le ID: 3964LCS Reporting Concentration Detection Limit Constituent IL) I IL) Data Qualifier(s) 24 -Trihl r hn I <10 24 -Trihl r h n I 2-Chlorona hthalene <10 10 2-Nitroaniline <25 25 Dim h I hh I A n hhln 2 6-Dinitrotoluene <10 10 3-Nitroaniline <25 25 A n hhn 10 2 4-Dini r h n I <2 4-Nitro henol 22 25 Dibenzofuran <10 10 2 4-Dini r I n 10 Di h I hh I 4-Chloro hen I- hen lether <10 10 Fluorene <10 10 4-Ni r nilin <2 4 -Dinir m h I h n I -<2 N-Nitrosodi hen lamine <10 10 4-Bromo hen I- hen lether <10 10 Hx hlr n n P n hlor hn I 17 Phenanthrene <10 10 Anthracene <10 10 Di-n- I h h I Fluor n h n 10 P rene 100 10 But Ibenz I hthalate <10 10
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| '-Di hi r nzi in <2 B nz n hr n <10 10 Chr sene <10 10 bis 2-Eth Ihex I hthalate <10 10 Di n- I h h I 8 nzo b fluoran hen <10 Benzo k fluoranthene <10 10 Benzo a rene <10 10 In n 12 - rn Dib nz h an hrac n Benzo h i er lene <10 10 Carbazole <10 10 LOCKHEED ANALYTICALSERVICES
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| SEIVIIVOLATILEORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Pa e1 f2 lin m I ID: D P LA ml ID: 4 D P Date Collected: N A Date Received: N/A Matrix: WATER Dilution Factor: 1 An I i IB h¹: 111 4- 27 -B Da Exr ed: 4- AN- 4 QC Batch ID: 8270-SEMIVOLATILES-3964 Date Anal zed: 11-JAN-94 RRO ATE REC VERY Limi 2-Fluoro henol 31 21-100 Phenol-de 24 10-94 Nitrobenzene-d, 62 35-114 2-Fluorobi hen I 62 43-116 24 -Tri r m h n I 1 -12 p-Terphenyl-d,4 85 33-141 Reporting Concentration Detection Limit n i n L L D Phenol 39 10 bis 2-Chloroe h I ether <10 10 2- hl r hen I 1 -Dihl r nz n 1 4-Dichlorobenzene 41 10 Benz I alcohol <10 10 12-Di hl r nz n 2-M h I hn I bis 2-Chloroiso ro I ether <10 10 4-Meth I henol <10 10 N-Ni r -Di-n- r I min 74 Hx hlr hn Nitrobenzene <10 10 Iso horone <10 10 2-Nir h n I 2 4-Dim h I h n I <10 Benzoic acid <50 50 bis 2-Chloroethox methane <10 10 24Dihl r hn I
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| *1 2 4-Tri hl r nz n Na hthalene <10 10 4-Chloroaniline <10 10 Hx hlr in 4- hlr--m hlhnl 2-Meth Ina hthalene <10 ~
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| 10 Hexachloroc clo entadiene <10 10 LOCKHEED ANALYTICALSERV/CES
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| SEIVlIVOLATILEORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 P 2 f2 Client Sam Ie ID: LCS DUP LAL Sam le ID: 3964LCS DUP Reporting Concentration Detection Limit Constituent IL) I IL) Data Qualifierls) 24 -Trihl r h n I 24 -Trihl r h n I 2-Chlorona hthalene <10 10 2-Nitroaniline <25 Dim hlhhla <10 A n hhln 2 6-Dinitrotoluene <10 10 3-Nitroaniline <25 25 A en hhn 24-Dinir h n I <2 4-Nitro henol 35 25 Dibenzofuran <10 10 2 4-Dini r ol n Di h I hh I 4-Chloro hen I- hen lether <10 10 Flu orene < 10. 10 4-Ni r nilin <2 4 -Dinir meh I h n I <2 N-Nitrosodi hen lamine <10 10 4-Bromo hen I- hen lether <10 10 Hx hlr nzn Pn hl r hnol Phenanthrene <10 10 Anthracene <10 10 Di-n- I hh I Fl ran h n 10 P rene 100 10 But Ibenz I hthalate <10 10
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| '-Dihl r ni in B nz n hr n Chr sene <10 10 bis 2-fth Ihex I hthalate <10 10 Di-n- I hh I 8 nz fl r nh n Benzo k fluoranthene <10 10 Benzo a rene <10 10 In n 1 - rn 10 Di nz h n hra n Benzo h i er lene <10 10
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| <10 10 LOCKHEED ANALYTICALSERVICES
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| SEMIVOLATILE ORGANICS QUALITY CONTROL DATA
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| ==SUMMARY==
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| | |
| FOR METHOD 8270 Client Sample ID: LCS LAL Sample ID: 3964LCS/LCS DUP
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| ¹:
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| 'C Analytical Batch 011194-8270-B Date Analyzed: 11-JAN-94 QC Batch ID: 8270-SENIIVOLATILES-3964 Limits Spike Spike Duplicate Compound % Recovery % Recovery RPD Recovery RPD Phenol 27 26 5-112 42 2-Chlorophenol 57 53 23-134 40 1,4-Dichlorobenzene 39 41 20-124 28 N-Nitroso-di-n-propylamine 78 74 D-230 38 1,2,4-Trichlorobenzene 45 52 14 44-142 28 4-Chloro-3-methylphenol 68 66 22-147 42 Acenaphthene 68 69 47-145 31 4-Nitrophenol 23 42 D-132 50 2,4-Dinitrotoluene 81 79 39-139 38 Pentachlorophenol 121 14-1 76 50 Pyrene 101 101 52-115 31 LOCKHEED ANALYTICALSERVICES
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| PESTICIDE ANALYSES RESULTS BY GC/ECD USING METHOD 8080 FOR COOK NUCLEAR PLANT Clien Sam le ID: METHOD BLANK LAL Sam ie ID: 3965MB D Collec ed: NA Da e Re eiv: NA Date Extracted: 04-JAN-94 Date Anal zed: 21-JAN-94 Matrix: WATER Dilution Factor: 1 Anal tical Batch ¹: 012094-8080-A-1 QC Grou ID: 8080 PEST/PCBS 3965 SURROGATE RECOVERY 0 QC Limits TCMX 46" 60-150 DCB 23 60-1 50 Reporting Constituent Concentration Detection Limit Data Qualifier(s)
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| /L /L A-BHC <0.05 0.05 B-BHC G-BHC D-BHC <0.05 0.05 HEPTACHLOR <0.05 0.05 ALDRIN <0.
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| HEPTA HL R EPOXIDE <0.
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| G-CHLORDANE <0.05 0.05 ENDOSULFAN I <0.05 0.05 A-CHLORDANE <0.
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| 4 4'-DDE 4 4'-DDT < 0.1 0.1 DIELDRIN <0.1 0.1 ENDRIN <0.1 ENDOSULFAN II <0.1 4 4'-DDD <0.1 0.1 ENDRIN ALDEHYDE <0.1 0.1 ENDOSULFAN SULFATE <0.1 METHOXYCHLOR <0.
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| TOXAPHENE <5 PCB-1016 PCB-1221 <2 PCB-1232 PCB-1242 PCB-1248 PCB-12 4 PCB-1260 TECHNICAL CHLORDANE MIREX < 0.1 < 0.1 TCMX - tetra-chloro-meta-xylene DCB - Deca-chioro-biphenyl LOCKHEED ANALYTICALSERVICES
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| PESTICIDE ANALYSES RESULTS BY GC/ECD USING METHOD 8080 FOR COOK NUCLEAR PLANT Clien Sam le ID:LAB CONTROL SAMPLE LAL Sam le ID: 3965 LCS Da Clle d NA D e Rec ive: NA Date Extracted: 04-JAN-94 Date Anal zed: 21-JAN-94 Matrix: WATER Dilution Factor: 1 Anal tical Batch ¹: 012094-8080-A-1 QC Grou ID: 8080 PEST/PCBS 3965 SURROGATE RECOVERY oo QC Limits TCMX 60 60-1 50 DCB 29 60-150 Reporting Constituent Concentration Detection Limit Data Qualifier(s)
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| IL IL A-BHC <0.05 0.05 B-BHC G-BHC 0.88 0.0 D-BHC <0.05 0.05 HEPTACHLOR 0.70 0.05 ALDRIN HEPTACHLOR EPOXIDE <0.05 G-CHLORDANE <0.05 0.05 ENDOSULFAN I <0.05 0.05 A-CHLORDANE <0.
| |
| 4 4'-DDE < 0.1 0.1 4 4'-DDT 1.85 0.1 DIELDRIN 1.81 0.1 ENDRIN 1.91 0.1 ENDOSULFAN II < 0.1 0.1 4 4'-DDD < 0.1 0.1 ENDRIN ALDEHYDE <0.1 0.1 END ULFAN S LFATE METHOXYCHLOR TOXAPHENE <5 PCB-101 6 PCB-1221 <2 PCB-12 2 PCB-1242 PCB-1248 PCB-12 4 PCB-12 TECHNICAL CHLORDANE MIREX <0.1 <0.1 TCMX - tetra-chloro-meta-xylene DCB - Deca-chloro-biphenyl LOCKHEED AIVALYTICALSERVICES er
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| 1 PESTICIDE ANALYSES RESULTS BY GC/ECD USING METHOD 8080 FOR COOK NUCLEAR PLANT Clien Sam le ID: LAB CONTROL SAMPLE DUP LAL Sam Ie ID: 3965 LCSD D Collec ed: NA D eR eive: NA Date Extracted: 04-JAN-94 Date Anal zed: 21-JAN-94 Matrix: WATER Dilution Factor: 1 Anal tical Batch ¹: 012094-8080-A-1 QC Grou ID: 8080 PEST/PCBS 3965 SURROGATE RECOVERY o QC Limits TCIVIX 54" 60-150 DCB 20 60-150 Reporting Constituent Concentration Detection Limit Data Qualifier(s)
| |
| /L /L A-BHC <0.05 0.05 B-BH .0 0.
| |
| G-BHC D-BHC <0.05 0.05 HEPTACHLOR 0.66 0.05 ALDRIN HEPTACHLOR EPOXIDE . 5 0.05 G-CHLORDANE <0.05 0.05 ENDOSULFAN I <0.05 0.05 A-CHL RDANE 5 4 4'-DDE <0.1 0.1 4 4'-DDT 1.80 0.1 DIELDRIN 1.85 0.1 ENDRIN 1.94 0.1 ENDOSULFAN II 4 4'-DDD <0.1 0.1 ENDRIN ALDEHYDE <0.1 0.1 ENDOSULFAN SULFATE 0.1 METHOXYCHLOR <0.5 0.5 TOXAPHENE <5 PCB-1016 PCB-1221 <2 PCB-1232 PCB-1242 PCB-1248 PCB-12 4 PCB-12 0 TECHNICAL CHLORDANE MIREX < 0.1 <0.1 TCMX - tetra-chloro-meta-xylene DCB - Deca-chloro-biphenyl LOCKHEED ANALYTICALSERVICES
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| PESTICIDES QUALITY CONTROL DATA
| |
| | |
| ==SUMMARY==
| |
| | |
| FOR METHOD 8080 Client Sample ID: LAB CONTROL SAMPLE LAL Sample ID: 3965 LCS Analytical Batch 4': 012094-8080-C-1 Date Analyzed: 21 VAN-94 QC Batch ID: 8080 PES/PCBS 3965 Matrix: WATER SURROGATE RECOVERY (%)
| |
| QC Limits TCMX 60 60-1 50 DCB 29" 60-1 50 QC Limits Spike LCS Constituent Added Concentration (yg/L) (yg/L) Recovery Recovery G-BHC (Lindane) 0.88 88 56-1 23 Heptachlor 0.70 70 40-131 Aldrin 0.60 60 40-120 4,4'-DDT 1.85 92 38-1 27 Dieldrin 1.81 90 52-1 26 Endrin 96 56-121 LOCKHEED ANALYTICALSERVICES 58
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| | |
| PESTICIDES QUALITY CONTROL DATA
| |
| | |
| ==SUMMARY==
| |
| | |
| FOR METHOD 8080 Client Sample ID: LAB CONTROL SAMPLE LAL Sample ID: 3965 LCS/LCSD Analytical Batch ¹: 012094-8080-C-1 Date Analyzed: 21-JAN-94 QC Batch ID: 8080 PEST/PCBS 3965 QC Limits Spike Sample Matrix Spike Constituent Added Concentration Concentration (yg/L) (yg/L) (yg/L) Recovery Recovery G-BHC (Lindane) 0.88 88 32-1 27 Heptachlor 0.70 '70 34-111 Aldrin 0.60 60 42-122 4,4'-DDT 1.85 92 25-1 60 Dieldrin 1.81 90 36-146 1.91 96 30-147 QC Limits Matrix Spike Spike Duplicate Constituent Added Concentration Recovery RPD RPD Recovery (yg/L) (yg/L)
| |
| G-BHC (Lindane) 0.88 88 15 32-127 Heptachlor 0.66 66 20 34-1 1 1 Aldrin 0.55 55 22 42-1 22 4,4'-DDT 1.8 90 27 25-160 Dieldrin 1.85 93 18 36-146 Endrin 1.94 97 21 30-147 LOCKHEED AIVALYTICAL SERVICES 58
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| | |
| 0 METALS QC DATA
| |
| | |
| ==SUMMARY==
| |
| | |
| 'LAL Batch ID(s):.1220.:im QC Sam le Anal ses Matrix Client LAL Reagent Duplicate Spike "Sample Sample Date Blank P,.recision -
| |
| Recovery
| |
| '.,'onstituent . 'ID , ID; A'nalyxed (m IL) (% RPD) "(%)
| |
| Aluminum TRS L1009-13 01-20-94 <0.20 104 Antimon TRS L1 009-13 01-27-94 < 0.060 104 Arsenic TRS L1 009-13 01-27-94 < 0.010 110 Barium TRS L1009-13 01-27-94 < 0.20 74 Be Ilium TRS L1009-13 01-27-94 <0.005 97 Boron TRS L1009-13 01-20-94 < 0.20 88 Cadmium TRS L1009-13 01-27-94 <0.005 100 Chromium TRS L1009-13 01-27-94 < 0.010 98 Cobalt TRS L1009-13 01-27-94 <0.050 96 Co er TRS L1009-13 01-27-94 < 0.025 97 Iron TRS L1009-13 01-20-94 < 0.10 101 Lead TRS L1009-13 01-27-94 <0.003 84 Ma nesium TRS L1009-13 01-20-94 <5.0 102 Man anese TRS L1009-13 01-27-94 <0.015 98 Mercu TRS-QA L1009-14 01-07-94 <0.0002 106 Mol bdenum TRS L1009-13 01-27-94 < 0.20 106 Nickel TRS L1 009-13 01-27-94 <0.040 94 Selenium TRS L1009-13 01-27-94 < 0.005 137 Silver TRS L1 009-13 01-27-94 < 0.010 98 Sodium TRS L1009-13 01-20-94 <5.0 Thallium TRS L1 009-13 01-27-94 <0.010 103 Tln TRS L1 009-13 01-27-94 <0.20 104 Titanium TRS L1 009-13 01-20-94 <0.20 NA Vanadium TRS L1009-13 01-20-94 <0.050 107 Zinc TRS L1009-13 01-27-94 <0.020 94
| |
| ~ Ibw The RPD cannot be computed, because the sample or the duplicate concentration was below the Reporting Detection Limit.
| |
| ~ NA The matrix spike recovery is not reported. The sample concentration was greater than four times the spiking level.
| |
| Titanium is not included in the spiking solution.
| |
| LOCKHEED ANALYTICALSERVICES
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| +++ 0 Halliburton NUS C R P 0 AT I 0 R N NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 11, 1994 Report No.: 00018818 Section 8 Page 1 DUALITY CONTROL REPORT SUPPLEMENTAL INFORMATION
| |
| ------------ SAMPLE PREPARATION------------ ------------------- SAMPLE ANALYSIS -----------------.-
| |
| TEST LR- LR- ANLS LN CODE BATCH METHOD DATE/TIHE ANALYST METNOD DATE/TIME ANALYST BATCH INSTRUMENI'AMPLE ID: SEWAGE PLANT NUS SAMPLE NO: P0258838 1 ASNW 23036 02-4 '.3 03-JAH-94 0730 RAW R2-200.7 07- JAN-94 808 JWC 0 3560 2 1050 23039 NA 03-507 03-JAN-93 700 DB 0 3 I 610 23014 NA 02-160.2 30.DEC-93 700 EDB 0 4 I 490 23050 NA 02-150.1 03-JAN-93 715 DB 0 LR Method Literature Reference 02 EPA-Methods for Chemical Analysis of Water & Wastes, 1984.
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| 03 APNA-Standard Methods for the Examination of Water and Wastewater, 16th edition R2 Inductively Coupled Plasma-Atomic Emission Spectrometric Method for Trace Elemen SAMPLE ID: OIL/WATER SEPARATOR NUS SAMPLE NO: P0258839 1 G122W 22987 05-608 29-DEC-93 0800 PS 05-608 30.0EC-93 1146 JC 22987 3 I106 23061 NA 02-415.1 04-JAN-94 1000 JJH 0 4 I680 23097 NA 02-413.1 03-JAN-93 1230 TM 0 5 I490 23050 NA 02-150.1 03-JAN-93 715 DB 0 LR Method Literature Reference 02 EPA-Methods for Chemical Analysis of Water 8 Wastes, 1984.
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| 05 EPA-40 CFR 136, October 26, 1984.
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| NUS LABORATORY 4'alliburton
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| ++ C 0 R 0 R AT I 0 N P
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| NUS Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (4'12) 747-2580 FAX: (412) 747-2684 January 11, 1994 Report No.: 00018818 Section C Page 1 OUALITY CONTROL REPORT SURROGATE STANDARD RECOVERY TEST SURROGATE PERCENT ACCEPTANCE REF LN CODE COMPOUND RECOVERY LIMITS LN SAMPLE ID: OIL/WATER SEPARATOR NUS SAMPLE NO: P0258S39 2 SPCBW PCB SURROGATE nonachtorobiphenyt
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| NUS LABORATORY 1'Halliburton NUS Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road CORPORATION Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 11, 1994 Report No.: 00018818 Section D Page 1 QUALITY CONTROL REPORT LABORATORY CONTROL SAMPLE RECOVERY TEST PERCENT DUPLICATE ACCEPTANCE CODE DETERMINATION RECOVERY RECOVERY RPD LIMITS BATCH: 23036 SAMPLE ID: Lab Control Sample NUS SAMPLE NO: P0259637 ASNN Tin, Total (Sn) 92 ' NA BATCH: 23039 SAMPLE ID: Lab Control Sample NUS SAMPLE NO: P0259643 I050 BOO (02) - 5 day 101 ~ 7 NA BOD (02) - 5 day ¹2 94 NA BOD (02) - 5 day ¹3 99 NA BOO (02) - 5 day ¹4 104 NA BATCH: 23050 SAMPLE ID: Lab Control Sample HUS SAMPLE NO: P0259658 1490 pH 100.5 NA pH ¹2 100 NA pH ¹3 99.1 NA BATCH: 23061 SAMPLE ID: Lab Control Sample HUS SAMPLE NO: P0259673 1106 Carbon, Organic -. Nonpurgeable 110 HA Carbon, Organic - Nonpurgeable ¹2 96.3 NA Carbon, Organic - Honpurgeable ¹3 106 NA BATCH: 23097 SAMPLE ID: Lab Control Sample HUS SAMPLE NO: P0259728 I680 Oil and Grease, Gravimetric 84.8 83.8 1.19
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| | |
| .'i Halliburton
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| ++++ C 0 R P 0 AT 0 R
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| NUS I N NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 11, 1994 Report No.: 00018818 Section E Page 1 QUALITY CONTROL REPORT METHOD BLANK DATA TEST CODE Determination RESULT UNITS BATCH: 22987 SAMPLE ID: Method Blank NUS SAMPLE NO: P0259059 G122'N PCB ANALYSIS PCB-1016 < 0.50 ug/L PCB-1221 < 0.50 ug/L PCB-1232 < 0.50 ug/L PCB-1242 < 0.50 ug/L PCB-1248 < 0.50 ug/L PCB-1254 < 1.0 ug/L PCB-1260 < 1.0 ug/L BATCH: 23014 SAMPLE ID: Method Blank HUS SAMPLE HO: P0259602 I610 Solids, Suspended at 103C < 10 mg/L BATCH: 23036 SAMPLE ID: Method Btank NUS SAMPLE NO: P0259638 ASNM Tin, Total (Sn) < 0.1 mg/L BATCH: 23039 SAMPLE ID: Method Blank NUS SAHPLE NO: P0259644 I050 BOD (02) - 5 day 0.63 mg/L BATCH: 23061 SAHPLE ID: Hethod Blank NUS SAHPLE NO: P0259674 1106 Carbon, Organic - Nonpurgeable < 1 mg/L BATCH: 23097 SAMPLE ID: Method Blank HUS SAHPLE NO: P0259729 1680 Oil and Grease, Gravimetric < 3 mg/L
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| Iaar Halliburton NUS NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road C 0 R P 0 R AT I 0 N Pittsburgh, Pennsylvania 15205 (4'12) 747-2580 FAX: (412) 747-2684 January 11, 1994 Report No.: 00018818 Section F Page 1 QUALITY CONTROL REPORT DUPLICATE AND MATRIX SPIKE DATA PREP BATCH: 23050 HUS SAHPLE NO: P0258838 ORIGINAL DUPLICATE RANGE / HS MS %
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| TEST DETERMINATION RESULT RESULT UNITS RPD UNITS RESULT RCVRY 1490 pH 6.8 6 '7 ~ 02 PREP BATCH: 23014 HUS SAHPLE HO: P0258810 ORIGINAL DUPLICATE RANGE / HS HS H TEST DETERMINATION RESULT RESULT UNITS RPD UHITS RESULT RCVRY 1610 Solids, Suspended at 103C 12 13 mg/L 1 mg/L PREP BATCH: 23036 NUS SAMPLE NO: P0259167 ORIGINAL DUPLICATE RANGE / HS MS /.
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| TEST DETERMINATION RESULT RESULT UNITS RPO UNITS RESULT RCVRY ASNlJ Tin, Total (Sn) 0.4 0.4 mg/L 1.98 mg/L 2.28 94.0 PREP BATCH: 23039 HUS SAMPLE NO: P0258780 ORIGINAL DUPLICATE RANGE / HS MS yo TEST DETERHI NATION RESULT RESULT UNITS RPD UNITS RESULT RCVRY I050 BOD (02) - 5 day 5 3.81 mg/L 1 mg/L PREP BATCH: 23061 HUS SAMPLE NO: P0258851 OR I G I MAL DUPLICATE RANGE / HS HS K TEST DETERHINATI ON RESULT RESULT UNITS RPD UNITS RESULT RCVRY I106 Carbon, Organic - Nonpurgeable 7 6.86 mg/L 3.82 mg/L 57.7 101
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| | |
| '. HallibuIIton
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| +++ C 0 R P 0 AT l 0 R
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| NUS N
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| NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 I
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| (412) 747-2580 FAX: (412) 747-2684 January 11, 1994 Report No.: 00018818 Section H Page 1 QUALITY CONTROL REPORT MATRIX SPIKE AND MATRIX SPIKE DUPLICATE DATA ANLS BATCH: 22987 NUS SAMPLE NO: P0258792 MS MSD MS PCT MSD PCT TEST DETERMINATION RESULT RESULT UNITS RPD RECOVERY RECOVERY G122W PCB-1242 4 '7 4.55 ug/L 0.4 91 91 G122W PCB-1260 4.T5 '.73 ug/L 0 95 95 0'
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| NPDES STORM WATER DRAINAGE PERMIT APPLICATION D.C. COOK NUCLEAR PLANT ONE COOK PLACE BRIDGMAN, MI 49106
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| E LI I'ICCTC VI I ~ ~ ~ Vl IT Vr ' " ~ riiniirlpplovro. ITITIII Iv. rvrv'ITvrvrlpIVIITCIrrpllrr r VI mv
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| ~
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| (fill-inareas are spaced for elite rype, i.e., 12 charac rers /inch(.
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| U.S, tHVIROHMCHTAI PIIOTCCTIOH AOBHCY I. EPA I.D. NUMBER GENERAL INFORMATION GENERAL Consoli dered Pemli re Program
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| ()lead lhe "General inllriieilons" before Irarrrne.l F IIID 098647621 P OCHBRAL INSTRUCTIONS It a prsprinted label hss been provided, affix I. EPA I.D. NUMB R lt in the designated space. Review the inform.
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| ~ lion carefully; if sny of It Is incorrect. cross ill). FACILITY AME through it snd enter tha correct data In the appropriate fill-in sra below. Also, if sny of ths plePrintsd dsts is absent (dis sre ~ ro di ~
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| ACILITY left of di ~ label space lisle di~ information
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| 'AILIN ADDRESS P EASE PL C LABEL IN THIS SPAC dist should sppasrl, please provide It In tha proper fill-in siss(s) below. If the label ls
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| 'compl ~ Ilt and correct, you need not complete Items I, III, V, shd Vl (ixcepr Vl B wfikh must be compleltd rsgerdless/. Complete sll FACIL'ITY Rems if no label hss been provided. Aeter to VI'OCATION the Innrucllons tor detailed Item descrip-tions snd for the legal suthorisations under which this data ls collected.
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| II. POLLUTANTCHARACTERISTICS INSTRUCTIONS: Complete A through J to determine whether you need ta submit any permit application forms to tha FPA. If yau answer "yes" to any questions, you must submit this form and tha supplemental form listed in the parenthesis fallowing the question, Mark "X"in the box in tha third columlt if the supplemental form is attached, If you answer "no" to each question, you need not submit any of these forms. You may answer "no" if your activity is excluded from permit requirements; see Section C of the instructions. Sea also, Section 0 of the Instluctions for definitions of bold-faced terms.
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| SPKCIPIC DUCSTIOHS ~ OP TI ITVACIIC apccl pic DUtsTIDNs CD rory 0 ATTACIICO A. Is this facility s publicly owned treatment works 8. Does or will this facility (either exist(np or proposcdl which resuIII in s discharge lo waters of ths U.S.) include s concentrated animal fadlhg operation or IFORM 2A) ~ qusslc animal production facility which results in a discharge lo wsssls of the U$ 2 IFOAM 28) ~ ~ I~ ~~
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| , Is I is s scililv which cunenl v resuls in Isc srgcs I I is a propos sciity o er sn ost ascn lo wslsrs of the U.S. olherahon Ihqts described in X In A or B shovel which will result in ~ discharge lo X A or Babove) 2N Form 2b wst ~ t ths U S 7 F RM 2 I F. Do you or will you inject at this facility industrial or E. Does or will this facility tress, store, or dispose of municipal effluent below tha.lowermost stratum con-hszsrI)ous wsnssf IFORM 3) X ~ taining, within one quarter mile of the well bort, X underground sources ot drinking water? IFOA M 4) o you or wi you ihlecl sl I is so ily shy pro uc water or other fluids which sra brought to the surface H, Do you or will you inject st this facility tluids for sps in connection with conventional oil or natural gss pro. cisl processes such as mining ot sulfur by lhs Frasch duction, inject tluids used for enhanced recovery of process, solution mining of minerals, in situ combus.
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| oil or natural gss, or ihjeC! fluids for storage of liquid tlon of fossil fuel, or recovery ot geothermal ensrgyt X h drocsrbohst IFORM 4) IFORM 4) I~ I~
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| ~ 5 lllis sci ily ~ propose ssssiohsry source w>>s ~ I l is aci ity ~ prop nsiy source whic is T~
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| one of the 28 industrial categories listed in the in- NOT one ot tht 28 industrial categories lined in the structions snd which will potentially emit 100 tons Instructions and which will potentially emit 250 tons 'l psr year of any air pollutant regulated under the per year of any eir pollutant regulated under the Clean Clean Air Acl and Ihay SffeCt Or be located in sn Air Act snd may affect or be located In an sttalnmeIIS X snsihmcnt arcs) IFORM Sl ~ Ies) IFORM 5)
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| III. NAME OF FACILITY 1
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| 5<<P D. C, COOK NUCLEAR PLANT IV. FACILITYCONTACT A, NAM t SI TITLC (loll, (lNI, Ia llllel B, I'HDNC faTCC code k no.l C
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| 2 BAKER D. L. Fnvironmental Affairs Director 2 1 9 425 2118 V. FACILITYMAILINGADDRESS A STRttT OR P.O BOX 3 P 0 BOX 60
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| ~ . CITY OR TOWN C,STATt D, ZIP CODC 4 FORT WAYNE IN 4680 Vl. FACILITYLOCATION A STRtCTI ROUTC HO OR OTHCR SPtCIPIC IDtNTIPICR 5 ONE COOK" PLACE Bl COUNTY NAMt BERRIEN C. CITY OR TOWN D STATt Cl ZIP CODS 6 BRIDGOIN 416 EPA Form 3610.1 IRsv. 104I0) CONTINUE ON REVEASE
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| TIN ED FROM THE FR NT Vlf, SIC CODES (4<ipit. Jn order of pr(orlrvJ Ao Fltt5T ~, SCCONO 9 1 1 """fyJ STEAM ELECTRIC POriZR (speci fyI C. 'rNIItO O, FOURTH (speci fyI (specify I 7
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| ~ ~ ~ i~
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| VIII.OPERATOR INFORMATION Ao NAMC . Is tha name listed In I
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| Item VIII.A~ la ths I C ~
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| owners 8 NDIANA MICHIGAN PO R 0 K3 YES C3 NO sa
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| ,I ~ t~
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| c STATU5 oF orcRAToR (Enter thc approprlatc lcncr Into thc anstrcr ooxtlf -Other", spcclfy.l o. r Notte (area code a no.l a AL U LI (other than fcdcral or state J (speci fyJ 616 901
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| ~
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| S ~ STATE P ~ PRIVATE 0 ~ OTHER (IpeclfyJ P A
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| ~ ~ I~ I~
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| 65 ~ ~ ~
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| C, 5TRCCT 0tl F.OI SOX ONE COOK PLACE I, CITY OR TOWN Is the facility located on Indian landst s BRIDGMAN Oaa YES CB NO
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| ~e ~I ~ I ~
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| ~I X. EXISTING ENVIRONMENTALPERMITS
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| 'I'I A. III ois (Discharges to Surface WaterJ o. rso (A4 Emlsslons from proposed Sources J
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| 'r ~
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| ig N MI 0005827 9 P
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| : 5. UIC (underground In/cation of Fluldsl C. oTNcR (specify I 9 U sa Fir Permit 'applicat;i matte n
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| (H (I fyJ (speal fyJ 9 R 9
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| ~ ~ ~ 4 11 ~ I~ ~ ~ ~ ~ ~ ~ ~ I~
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| XI. MAP Attach to this application a topographic map of the area extending to at least one mile beyond property bounderies. The map must show the outline of the facility, the location of each of its existing and proposed intake and discharge structures, each of its hazardous waste treatment, storage, or disposal facilities, and each well where it injects fluids underground. Include ell springs, rivers and other surface water bodies in the map area. See instructions for precise requirements.
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| XII. NATURE OF BUSINESS (provide ~ aria(description The Cook Nuclear Plant is a 2130 Mt4 steam electric generating station situated in 6*belt of sand dunes on the southeastern shore of Lake Michigan between Stevensville and Bridgman.
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| Preparation of the site for construction of the plant began in 1968. Unit 1 was operat-tional in 1975 and Unit 2 in 1978.
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| XIII. CERTIFICATION (seeinsuvcdonsl I certify under penalty of law that I have personally examined and am familiar wirh theinformatlon submitted in this application end all attachments and chat, based on my inquiry of those persons immediarely msponsible for obtaining the Information contained in the application, I believe that the information is true, accurate and complete. I am aware that them am significant penalties for submitting false information, including the possibility of fine andimprisonment.
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| A M c Is o F F I c I A L T I T L c (type or prln II 9 SIGNATURC C, OAT R. C. Menge, President COMMENTS FOR OFFICIAL USE ONLY C
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| C EPA Form 3510.1 {Rav. 10 80) Reverse rrrrlartar attire I I9SS
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| 'I Several of the sections in this permit application (Form 2F) are completed via the use of attachments. These sections reference the appropriate attachment. Please carefully read each section to avoid any confusion.
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| I., k EPAID Number (copy from item iof Form i) Form Approved. OMB No. 20404086 Please print or type in the unshaded areas only HLD098647621 Approval expires 541.92 United tates Environmenta Protection Agency Form Washington, DC 20460 2F Appi!cat!on for Perm!t to D!schprge Storm Y/at~r Oischar es Associated with industrial Activi Paperworlr Reduction Act Notice
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| , Public repoNnII burden for this ap'plication is estimated to average 28.6 hours per application, includ!ng time for reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing the collection of information. Send comments regarding the burden estimate, any other aspect of this collection of information, or suggestions for Ihtproving this form, including suagostions which may Increase or reduce this burden to: Chief, Information Policy Branch, pM-223, U.S. Environmental Protection Agency, 401 M Bt., SW, Washington, DC 20460, or Director, Office of Information and Regulatory Affaire, Office of Management and Budget, Washington, DC 2C503 I. Outfaii LocatIon For each outlall list the latitude and lon itude of its location to the nearest 15 seconds and the name of the recolvin water.
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| A Outfall Number D. Receiving Water ist~
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| 1S 41 B. Latitude 58 50 86 C. Lon itude 34 00 Lake Hichi' name 00 Lake Mich 2S 41 41 '858 45 43 86 86 34 34 00 Lake Hichi an 41 58 43 86 34 00 Lake Hichi II. Im rovements A. Are you now required by any Federal, State, or local authority to meet any Implementation schedule for the construction, upgrading or operation of wastewater treatment equlpmont or practices or any other environmental programs which may atfect the discharges described in this application2 This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters, stipulations, court orders, ahd grant or loan conditions. N/A
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| : 4. Final
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| : 1. Identification of Conditions, 2. Affected Outfalls Com liance Date reements. Etc. number source of dischar e 3. Brief Descri tion of Pro ect a.re . b. ro .
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| you may attach additional sheets describing any additional'water pollution (or other environmental projects which may affect your discharges) you now have under way or which you plan. Indicate whether each program is now under way or planned, and indicate your actual or planned schedules for construction Re fer to Attachment A
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| .!I. Site DraIna e Ma
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| ""ach a site map showing topography (or indicating the outline of drainage areas served by the outfall(s) covered in the application if a gr~phiC map iS ui available) depiCting the faCility inCIuding: eaCh Of itS intake and diSCharge StruCtureS; the drainage area Of eaCh StOrm
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| ""'"'u"all:paved areas and buildings within the drainage area of each storm water outfall, each known past or present areas used for outdoor
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| 'oiago or <<<posal of significant materials, each existing structural control measure to reduce pollutants in storm water runoff, materials loading an<<c~ss areas. areas where pesticides, horbicides, soil conditioners and fertilizers are applied; each of its hazardous waste treatment,
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| ""-rags <<disposal uni:s (including each area not required to have a RCRA permit which is used for accumulating hazardous waste under 40
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| <'" 26234): each weil where fluids from the facility are injectod underground; springe, and other surface water bodies which receive storm r.a!or ",sc.'.a os ficm!"e facili EPA Form 3510 2F (Rev. 1.92) Page 1 of 3 Continue on Page 2
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| Continued from the Front For each outfall, provide an estimate of the area (include units) of Impervious surfaces (Including paved areas arid building roofs) drained to the outfall, and an estimate of tho total surfaoe area drained bY the outfall. See At taChment: B Outfall Area of Impervious Surface Total Area Drained Area of knpelvlous Suflace Total Area Drained B. provide a narrative description of significant materials that are currentlyorin the past throe years have beerrtreatod, stored or dispcsed ln a manner to allow exposure to storm water; method of treatment, storage, or disposal; past and present materials management practices employed to minimize contact by these materials with storm water runoff; materials keding and aocesa areas; and the location, manner, and frequency in which pesticides, herbicides, soil conditioners, and fertilizers are applied.
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| 1 See Attachment B for significant materials See Att.achment B-1 for Herbicide Information See Attachment B-2 for other potential exposures to storlhwater C. For each outfall, provide the location and a description of existing structural and nonstructural control measures to reduce pollutants in storm water runoff; and a description of the treatment the storm water receives, Including the schedul ~ and type of maintenance for control Ust Codes from See Attachment' V. Nonstorrnwater Dlschar es A I cenify under penalty of law that the outfall(s) oovered by this application have been tested or evaluated for the presence of nonstormwater discharqes, and that all nonstormwater dischargee from these outfall(s) aro identified in oither an accompanying Form 2C or Form 2E i
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| Name and Official Title (type or print) Date Signed D.L. Baker i'. Affairs Director, 3b- gg B. Provide a description of the method used, the date of any testing, and the onslto drainage points that were directly observed during a test.
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| Samples procured and analyzed as per applicable guidelines. Outfall 003S sampled before and after mixing with groundwater.
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| Vl. Sl nlficant Leaks orS ills Provide existing Information regarding the history of significant leaks or spills of toxic or hazardous pollutants at the facility in the last three years, Including the approximate date and location of the spill or leak, and the type and amount of material released.
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| See Attachment C EPA Form 3510.2F (Aev. 1-92) Page 2 of 3 Continue on Page 3
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| ler-'"Kx~&5%IS~ EPA lD Number (copyfiom item iofForm 1)
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| Continued from Page 2 HID098647621 AB.G. 4 D: see Instructions before proceeding. complete one set of lables for each outfall. Annotate the outlall number in the apace provided.
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| Tables Vll.A. Vll-B, and V!LC are included on se arete sheets numbered Vll-1 and Vil 2.
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| E. Potential discharges not covered by analysis ~ is any toxic pollutant listed in table 2F.2, 2F4 or 2F<, a substance or a componant ol a substance which you currently use or manufacture as an intermediate or final product or byproduct?
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| Yes list ail such iiurants below No o to Section Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years?
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| Yes istall such iiuranrs below No o fo Section N/A vrere any of the analysis reported in item Vll performed by a contract laboratory or consulting firm?
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| X Yes (list the name, address, and telephone number of, and pollutants No (go to Section?r)
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| A. Name B. Address C. Area Code if, Phone No. D. Pollutants Anal ed Lockheed Analytical Services 975 Kelly Johnson Dr. 1(800) 361-0220 Inorganic s Las Vegas, Nevada Organics 89119-3705 Radiochemistry W.W. Engineering tf Science Glenwood Hills Parkway 1(616) 942-9600 BOD 5 P.O. Box 874 (Biological iver Grand Rapids, HI Oxygen 49588-0874 Demand)
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| Surfactants I certify under penalty of law that this document and all attachments were prepared under my direction or supervr'sion in accordance with a'ystem designed to assure that qualified personnel properly gather and evaluate theinformation submitted. Based on myinquiry of the person or persons who manage the system or those persons directly responsible for gathering the informa;ion, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.
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| A Name lf Otficial Title (~ or pn'nr) B. Area Code and Phone No.
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| R.C. Henge, President (219)425-2118 D. Date Signed s/su/qg is + 1 r
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| ~ ~
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| ~
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| Page 3 of 3
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| 'EPA lD Number (copy from rrem I of Form t) Form Approved. OMB No.
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| 20404 I
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| 6 tiMID 0 9 8 6 4 7 6 2 1 )NI Vll. Dischar Part e Information (Confrnued (rom a e 3 of Form 2F
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| - You must provide th ~ results of at least one analysis lor every pollutant in this table. Compl ~ le one tabl ~ for each curtail. erne
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| . instructions for additional details.
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| Maximum Values Average Values Number Pollutant (include vnns) (include units) of and Grab Sample Grab Sampl ~ Storm Taken Ouhng Taken During CAS Number First 30 Flow-weighted Row-weighted Events First 30 (ifavailable) Minutes Composite Minutes Composite Sampled Sources of Pollutants O'I and Grease BiOlOgiCal Oxygen Demand (8005)
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| Chemical Oxygen Demand lCODl REFER TO ATTACHMENTD Total Suspended Sokds (TSS)
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| Total Kjefdaht Nitro en Nitrat ~ plus I
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| Nitrite Nitro en Total Phcschorus Minimum '.taxirr urn Minimum Maximum part 8- t.ist each pollutant that is umited in an etfluent guidekne wnicn the tacivty is suolect to or any poilutant listed in the tacuity s NFDEs permit for its'process wastewater lil the lacikty is operating under an existing NpDES permnl. Complete one table ior eacn outfait, h in I I i~
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| Maximum Values Average Values Number Pollutant (include units) (include units) of and Grab Samole Grab Sampf ~ Storm Taken During Taken Ounng CAS Number First 30 Row weighted First 30 Flow.weignted Events (ifavailable) Minutes Composite Minutes Composit ~ Sampled Sources of Ponutants REFER TO ATTACHMENT D EPA Form 3510-2F ~~ Page Va.l Continue on Reverse
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| Continued from the Front Pert C - Ust each pollutant shown in Tables 2F-2, 2F4, and 2'hat you know or have reason to believe is present. See the instructions for additional details and requirements. Complete one table for each outfall.
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| Maximum Values Average Values Number
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| . Pollutant (incfude units) ffncfude units) of and Grab Sample Grab Sample Storm Taken Dunng Ta'an During CAS Number First 20 Flow~ighted First 20 Row~fghted Events fifavailable) Minutes Composite Minutes Composite Sampled Sources of Pollutants REFER TO ATTACHMENTD Pert D - Provide data for the storm event s which resulted in the maximum values for the. ow wei hted corn site sam le.
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| 2 3. 4. 5. 6.
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| Date of Duration Total rainfall Number of hours between Maximum flow rate during Total flow from Storm of Storm Event during storm event beginning of storm meas- rain event rain event ured and end of previous (gallons/minute or Event in minutes in inches measurable rain event s ec units allonsors ec'nits Dec. 210 min. 0.14 inches 18 280.5 hours 2 liters/min. 1,260 liters 194 210 min. x 1.5 I./
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| min. x 4 outfalls = 1260 (Refer to Attachm nt D for Storm Ev nt Description) liters
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| : 7. Provide a descri tion of the method of flow measurement or estimate.
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| One liter container used in conjuction vith a stop vatch.
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| EPA Form 3510-2F (Rev. 1-P2) Page Vll.2
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| Instructions - Form 2F Application for Permit to Discharge Storm Water Associated with Industrial Activity Who Must File Form 2F Form 2F must be completed by operators of facilities which discharge storm water associated with industrial activity or by operators of storm water discharges that EPA is evaluating for designation as a significant contributor of pollutants to waters of the United States, or as contributing to a violation of a water quality standard.
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| Operators of discharges v'hich are composed entirely of storm water must complete Form 2F (EPA Form 3510-2F) in conjunction with Form 1 (EPA Form 3510-1).
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| Operators of discharges of storm water which are combined with process wastewater (process wastewater is water that comes into direct contact with or results from the production or use of any raw material, interme-diate product, finished product, byproduct, waste product, or wastewater) must complete and submit Form 2F, Form 1, and Form 2C (EPA Form 3510-2C).
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| Operators of discharges of storm water which are combined with nonprocess wastewater (nonprocess wastewater includes noncontact cooling water and sanitary wastes which are not regulated by effluent guide-lines or a new source performance standard, except discharges by educational, medical, or commercial chemical laboratories) must complete Form 1 Form 2F, and Form 2E (EPA Form 3510.2E).
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| Operators of new sources or new discharges of storm water associated with industrial activity which'will be combined with other nonstormwater new sources or new discharges must submit Form 1, Form 2F, and Form 2D (EPA Form 3510-2D).
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| Where to File Applications The application forms should be sent to the EPA Regional Office which covers the State in which the facility is located. Form 2F must be used only when applying for permits in States where the NPDES permits program is administered by EPA. For facilities located in States which are approved to administer the NPDES permits program, the State'nvironmental agency should be contacted for proper permit application forms and instructions.
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| Information on whether a particular program is administered by EPA or by a State agency can be obtained from your EPA Regional Office. Form 1 Table 1 of the "General Instructions" lists the addresses of EPA
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| , Regional Offices and the States within the jurisdiction of each Office.
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| Completeness Yotir application will not be considered complete unless you answer every question on this form and on Form
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| : 1. If an item does not apply to you, enter "NA (for not applicable) to show that you considered the question.
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| Public Availability of Submitted Information You may not claim as confidential any information required by this form or Form 1 whether the information
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| is reported on the forms or in an attachment. Section 402(j) of the Clean Water Act requires that all permit applications will be available to the public. This information will be made available to the public upon request.
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| Any information you submit to EPA which goes beyond that required by this form, Form 1, or Form 2C you may claim as confidential, but claims for information which are effluent data will be denied.
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| lf you do not assert a claim of confidentiality at the time of submitting the information, EPA may make the information public without further notice to you. Claims of confidentiality will be handled in accordance with EPA's business confidentiality regulations at 40 CFR Part 2.
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| Definitions All significant terms used in these instructions and in the form are defined in the glossary found in the General Instructions which accompany Form 1.
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| EPA ID Number Fill in your EPA ICentification Number at the top of each odd-numbered page of Form 2F. You may copy this iiumber d:rectly om item I of Form l.
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| ATTACHMENT A ATTACHMENTA II. Improvements B. The D.C. Cook Nuclear Plant is pursuing the following water treatment projects:
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| Makeup Demineralizer Regeneration Waste Neutralization System The Cook Plant is installing a system to collect and treat makeup demineralizer regeneration wastes to meet proposed pH permit limits. The current practice is to isolate the Turbine Room Sump (TRS), accumulate the wastes within the TRS, neutralize the waste with sulfuric acid or sodium hydroxide, then discharge the neutralized contents of the TRS to the Absorption Pond. Because the regeneration wastes are not the only source of water being collected in the TRS, a high water level within the TRS may require the discharge of the sump contents prior to the wastes being completely neutralized.
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| The new system will allow collection and neutralization of the regeneration wastes apart from the TRS. The holding tank for the waste will also be the point of treatment with the capability to add and mix sulfuric acid or sodium hydroxide with the waste prior to metering the neutral mixture to the TRS. The system is targeted for completion by January of 1995, with system start-up to occur thereafter.
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| Sequencing Batch Reactors The Cook Plant is currently requesting quotations to install a pair of pre-engineered sequencing batch reactors (SBR) to meet the proposed groundwater effluent limits. The new system will operate at a design flow of 50,000 GPD with a maximum flow of 60,000 GPD. The South Extended Aeration Package Plant will be utilized as a retention tank to ensure efficient SBR operation. Effluent from the new system will continue to be discharged into one of the two seepage lagoons. The new system will be installed and operational by December of 1995.
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| : 3. Alum Replacement Program A Chemistry Task Force is evaluating chemical flocculent replacements for alum (aluminum sulfate), taking both groundwater effluent standards and reverse osmosis system performance into consideration. The replacements currently being reviewed are pofymeric flocculents that. will enhance the removal of suspended solids in the pre-filters and meet manufacturer's recommendations for the water
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| ATTACHMENTA (Cont.)
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| entering the reverse osmosis system. The recommendations from the task force, once approved, will require additional time to test and implement. The environmental benefit of this review is the reduced amount of aluminum that will be discharged to the groundwater through the Turbine Room Sump discharge. The scheduled implementation date to use a new flocculent is fourth quarter of 1994.
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| Zebra Mussel Control Strategy The current control plan employs chlorination and periodic shock chemical treatments utilizing a proprietary chemical formulation. The Plant has also changed the source water for the fire protection system to a potable supply from Lake Township. This method of control was developed for short term relief from the effects of zebra mussel infestation. Based on over three years of experience in dealing with the mussels at the Plant and other Great Lakes facilities', a new strategy is being evaluated to protect all operations from infestation.
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| The new strategy incorporates intermittent oxidizing biocide treatments of the circulating water system beginning at the intake structures in Lake Michigan, continuous oxidizing biocide treatment of the essential service water and non-essential service water systems, and addition of sodium bisulflite to reduce any residual oxidizing biocide prior to discharge to the lake. If necessary, shock treatments utilizing proprietary chemical formulations will be administered. The goal of the program is to (l) eradicate existing populations and control further settlement of zebra mussels within the plant systems which utilize lake water, (2) treat the residual oxidant being discharged to non-detectable levels, and (3) reduce or eliminate the number of remedial shock treatments necessary to kill settled colonies of zebra mussels.
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| : 5. Chemistry Corrosion Control Additives The Plant is evaluating substitutes for the current corrosion control additives in the steam generators, plant heating boiler, feedwater and condensate systems, and closed heating/cooling systems. These substitutes will include carbohydrazide, and other available products from chemical companies such as Betz or Nalco. The environmental benefits of these additives include utilization of more benign corrosion control products or products requiring lower effective concentrations.
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| These products will discharge to the Turbine Room Sump in concentrations to be determined upon treatment optimization.
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| ATTACHMENT B ATTACHMENT B IV. Narrative Description of Pollutant Sources at the D.C. Cook Nuclear Plant in Bridgman, Michigan.
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| A. Approximate Surface Area (in ft') of Impervious Surface and Total Area Drained (Impervious and Pervious) by Outfall Number:
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| SURFACE AREA TOTAL AREA DRAINED OUTFALLP Im ervious 8c Pervious 001S 1,400,000 1,800,000 002S 400,000 800,000 003S 150,000 450,000 004S 4,000 300,000 B. Significant Materials - Treated, Stored, or Disposed of:
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| Specific chemicals that are stored or used in a way that may potentially expose them to the yard drainage system are as follows:
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| Fuel Oil - Stored in several underground and above ground storage tanks throughout the site. All fill areas are within a containment area and overfill alarms are installed for each tank. Yard drain basins are installed with a valve which is closed during the filling process. In the unlikely event a spill does occur, free product is held within the containment. Any and all free product is properly removed by qualified and trained personnel prior to the opening of the basin valve. Strict procedures are outlined by the company for proper" filling procedures in these areas. During maintenance periods, small tanks containing diesel fuel are located around the plant site to fuel generators, compressors, and other auxiliary equipment. These tanks are bermed and deliveries to them are in small quantities. Spills which could occur are immediately cleaned up with absorbent material.
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| ATTACHMENT B (cont.)
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| Sulfuric Acid - Stored in a 10,000 gallon tank which is bermed within a lined concrete structure designed to hold 150% of it's contents in the event of tank overfill or rupture. The sulfuric acid in this tank is used for demineralizer regenerations and pH neutralization. The tank and it' containment structure are located outside and directly adjacent to the Unit 1 Turbine Building. This tank, like all other bulk chemical and fuel oil storage tanks, has an overfill alarm system to help prevent spill events while filling the tank. The fill for this tank is located along the west wall of the Unit 1 Turbine Building and shares a lined concrete spill basin located within the North Chemical Unloading Area with the heating boiler fuel oil tank vents.
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| NOTE: The North Chemical Unloading Area is a bermed tank truck unloading area typical of other unloading areas on the plant site. The area is slightly depressed and sloped to a single storm drain. This drain is outfitted with a valve to isolate the containment from the storm drainage system. The operation of this valve, and others like it within containment areas around the plant site are controlled by plant procedures.
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| Sulfuric acid is also used to regenerate the membranes in the reverse osmosis (RO) unit used for water purification. The RO unit is located outside in the roadway directly west of the Screenhouse. The sulfuric acid is stored in 55 gallon drums which are bermed within a containment system adjacent to the reverse osmosis unit. These drums are changed under the direction of the RO unit operator. Plans are to upgrade this bulk storage to a bermed tank system. Hydrochloric acid as a substitute for the sulfuric acid is being evaluated.
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| Sodium Hydroxide - Stored in a 10,000 gallon tank which is vaulted in the basement of the Unit 1 Turbine Building. This tank has an overfill alarm system. Leaks and spills from the tank and piping are contained within the vault and routed to the turbine room sump for neutralization. The fill for this tank is located next to the fill for the sulfuric acid tank located within the North Chemical Unloading Area.
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| Transformer Oil - Transformers containing mineral oil contaminated with low level PCB's (<50 ppm) which are not routed to oil water separators, are bermed and contain a shutoff valve or manually controlled sump pump.
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| These containments are inspected and released by a trained operator onto the roadways, which eventually enter the yard drain system. Any contamination that is found within the containment areas is removed prior
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| ATTACHMENT B (cont.)
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| to release of the material to the roadways and yard drain system.
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| The transformers are routinely drained for maintenance and refilled on the plant site. Trucks and piping are bermed during transferring operations.
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| IAMtransmission/distribution crews maintain the transformers on the plant site in accordance with company procedures.
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| Sodium Hypochlorite (Chlorine) - Unloaded at the South Chemical Unloading Area which is similar in design to the North Chemical Unloading Area. Yard drain basins in this area, are installed with a valve, which is closed during the offload process. In the unlikely event a spill does occur, all free product is held within the containment. Any runoff that enters the yard drain system is retained by the valve at the basin. Any and all free product is properly removed prior to the opening of the basin valve.
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| Clam-trol CT-1 (or other zebra mussel control biocides) - Are applied via tanker trucks staged at the North Chemical Unloading Area. Yard drain basins in this area are installed with a valve, which is closed during the application process. In the unlikely event a spill does occur, all free product is retained within the containment. Any runoff that enters the yard drain system is retained by the valve at the basin. Any and all free product is properly removed prior to the opening of the basin valve.
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| Company procedures are used to apply this chemical. Basin drains in the vicinity of the chemical spargers are diked to prevent release of this chemical to the yard drain system.
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| Herbicides - These materials are used in various areas throughout the Cook Plant property. No bulk quantities of these materials are stored on site.
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| All quantities. are ordered and mixed before applications provided by an offsite vendor.
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| Attachment B-I lists the herbicide reports for the past three years. These reports describe application locations, quantity, and type of material used.
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| ATTACHMENT B (cont.)
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| Non-radioactive Waste Oil and Non-Hazardous Wastes - An above ground 2,000 gallon concrete vaulted (Convault) waste oil tank is located within a containment area directly north of the North Chemical Unloading Area.
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| The stormwater basin within this area is covered with a rubber gasketed steel cover. Draining of stormwater, and loading and unloading of waste oil in this area, is performed by qualified personnel. Barrels of waste oils and other non-hazardous wastes including hydraulic oil, EPA 2000 and glycol waiting processing are also accumulated in this area.
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| Radioactive Waste Oil - One 1,500 gallon radioactive waste oil tank is located in the North Chemical Unloading Area. Radioactive waste oil is processed in accordance with plant procedures. Spills from this tank would be contained within the North Chemical Unloading Area.
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| Sodium Nitrite (Calgon LCS-60) - Added as a corrosion inhibitor in many of the Plant's closed cooling systems. These include the component cooling water system, diesel jacket cooling water system, and air conditioning and heating systems on the plant site. The potential of sodium nitrite contaminating the storm water system is most likely in the office building HVAC systems where small amounts of sodium nitrite solution may leak to condensate drains and into outfall 001S. Storage of this chemical is in bulk drums vyhich pose no threat to the stormwater system.
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| Ethylene Glycol - Used as a refrigerant in the plant's containment ice condenser system and also in the training simulator chiller system. Leaks from the plant's containment ice condenser system are contained and collected within the confines of the auxiliary building and reactor containments. Leaks from the training simulator chiller system are contained and drummed. The resulting ethylene glycol/water solutions can also be collected in the temporary glycol storage tank located within the North Chemical Unloading Area.
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| Periodically, a temporary processing unit is erected on the plant site to process the collected ethylene glycol/water solution. The process is as follows: Hydrogen peroxide (35%) for oxidation and sodium hydroxide (50%) for pH balance are added to the glycol/water solution and introduced into a UV light cell. Ethylene glycol is broken down into carbon dioxide and organic acids. The processing unit is completely bermed and processing is performed under continuous supervision of the processing contractor with oversight from plant staff.
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| ATTACHMENT B (cont.)
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| Make-up Plant Regeneration Waste - After January 1995, acidic and caustic waste solutions produced from regeneration of the Make-up Plant resin'beds will be routed to the Make-up Plant Neutralization Tank located immediately west of the Unit 2 Turbine Building. Sulfuric Acid or sodium hydroxide are added to neutralize the wastes in the tank before they are eventually drained and pumped to the turbine room sump for release to the on site absorption pond. The tank is of a double-walled construction with both walls having been hydro-tested. The inner tank is equipped with level alarm instrumentation. The overflow for the inner tank is routed to the interstitial space between the tank walls. This space can be visually inspected and drained under plant supervision. Piping is above ground and heat traced. Any leak in this piping would be easily detected and repaired.
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| Low Level Radioactive Corrosion Products - During outage periods, low level radioactive corrosion products are sludge-lanced from the steam generators. A high pressure demineralized water hose is used to clean out the corrosion products which collect at the tube sheet. The resulting solution is removed and processed by a contractor with oversight by plant personnel. The sludge-lance unit and auxiliary equipment are completely bermed with the probability of a release from this system to the stormwater system unlikely.
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| Sewage Sludge - Sewage sludge is collected in a temporary tank located at the south end of the South Sewage Treatment Plant. Transferring of sludge is performed by the sewage waste contractor under the supervision of plant personnel.
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| : o. Chemicals Awaiting Storage - For brief periods, portable bulk tanks and pallets containing chemicals in drums are off-loaded onto the loading dock in the shipping and receiving area until they can be placed into storage.
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| Deliveries are made to the plant protected area via trucks and forklifts, and placed inside 'the Turbine Building or other areas where needed.
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| : p. Chemical Cleaning of Heat Exchangers 4 Piping - Oxidizers and organic acids are used to clean heat exchangers and piping around the plant site.
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| The cleaning equipment is contained and operated by contractors with oversight by plant supervision.
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| All other chemical materials are stored within the confines of various buildings and are not considered to be a threat to the yard drainage system.
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| ATTACHMENT B (cont.)
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| C. Control Methods by Outfall (refer to table 2F-1 for codes) 001S & 002S- Containment areas and basin valves are structural and mechanical control measures in place for these two outfalls.
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| 'n addition, containment oil booms are strategically placed at the outlets of these two outfalls. These booms will aid in the containment and absorption of any contaminants should other containment systems fail. These booms are inspected and replaced routinely.
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| Treatment Code: 4-A (discharge to open water) 003S & 004S- Risk of contaminants from these two outfalls is negligible, therefore, no control measures are in place at this time.
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| Treatment Code: 4-A(discharge to open water)
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| ATTACHMENT B-1 ATTACHMENT B-1 D.C. Cook Plant
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| ==SUMMARY==
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| OF PROGRAM - 1991 Herbicide Spray Report From April 22-May 1, 1991, Townsend Tree Service applied a mixture of Karmex, Amizine and Oust to control weed growth on the Plant Site.
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| A total of 48 lbs. of Karmex, 560 lbs. of Amizine and 2 Ibs of Oust was applied over 36 acres.
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| The following areas were inspected and treated for weeds:
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| : l. Sewage Ponds
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| : 2. Road to Absorption Pond
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| : 3. 765 Kv Switchgear Yard 4 345 Kv Switchgear Yard
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| : 5. Railroad Tracks east of Training Center
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| : 6. Parking lot B
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| : 7. 69 Kv Switchgear Yard
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| : 8. North Protected Area Fence
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| : 9. South Protected Area Fence
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| : 10. East Protected Area Fence
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| : 11. ICMS Office Trailer
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| : 12. ICMS Fab Shop
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| : 13. Southwest side of Turbine Building
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| : 14. South end of Turbine Building
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| : 15. Unit 1 RWST Area
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| : 16. Unit 2 RWST Area
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| : 17. Hydrogen/Nitrogen Storage Tank Area
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| : 18. Construction Fab Shop
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| : 19. Road to Meteorological Towers Based upon review of application records and observations of the treated areas, it appears that the herbicides were applied in accordance with herbicide label requirements, and no adverse environmental effects occurred.
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| ATTACHMENT B-1 (cont.)
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| ==SUMMARY==
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| OF PROGRAM - 1992 Herbicide Spray Report From June 3 - 7, 1992, Townsend Tree Service applied a mixture of Stomp and Oust to control weed growth on the Plant Site.
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| A total of 91.2 quarts of Stomp and 91.2 ounces of Oust were applied over 36 acres. The manufacturer's label recommends that Stomp be applied at a rate of between 2-4 quarts per acre.
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| Stomp was applied at a rate of 2.7 quarts per acre. The manufacturer's label recommends that Oust be applied up to 12 ounces per acre. Oust was applied at a rate of 2.7 ounces per acre.
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| The following areas were inspected and treated for weeds:
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| : l. Sewage Ponds
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| : 2. Road to Absorption Pond
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| : 3. 765 Kv Switchgear Yard 4 345 Kv Switchgear Yard
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| : 5. Railroad Tracks east of Training Center
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| : 6. Parking lot B
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| : 7. 69 Kv Switchgear Yard
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| : 8. North Protected Area Fence
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| : 9. South Protected Area Fence
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| : 10. East Protected Area Fence
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| : 11. ICMS Office Trailer
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| : 12. ICMS Fab Shop
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| : 13. Southwest side of Turbine Building
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| : 14. South end of Turbine Building
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| : 15. Unit 1 RWST Area
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| : 16. Unit 2 RWST Area
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| : 17. Hydrogen/Nitrogen Storage Tank Area
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| : 18. Construction Fab Shop
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| : 19. Road to Meteorological Towers Based upon review of application records and observations of the treated areas, it appears that the herbicides were applied in accordance with herbicide label requirements, and no adverse environmental effects occurred.
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| ATTACHMENT B-1 (cont.)
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| ==SUMMARY==
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| OF PROGRAM - 1993 Herbicide Spray Report From March 8 - October 5, 1993, various contractors have applied a mixture of Trimec 899, Orthene 75s, Stomp, Oust, Roundup, and Tri-power to control weed growth on the Plant Site.
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| A total of 270 ounces of Trimec 899, 2 lbs. of Orthene 75s, 103.5 quarts of Stomp, 103.5 ounces of Oust, 214 ounces of Roundup, and 298.4 oz of Tri-power were applied over 36 acres. All were applied as per manufacturers'abels recommendations.
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| The following areas were inspected and treated for weeds:
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| : l. Sewage Ponds
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| : 2. Road to Absorption Pond
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| : 3. 765 Kv Switchgear Yard 4 345 Kv Switchgear Yard
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| : 5. Railroad Tracks east of Training Center
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| : 6. Parking lot B
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| : 7. 69 Kv Switchgear Yard
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| : 8. North Protected Area Fence
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| : 9. South Protected Area Fence
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| : 10. East Protected Area Fence
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| : 11. ICMS Office Trailer
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| : 12. ICMS Fab Shop
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| : 13. Southwest side of Turbine Building
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| : 14. South end of Turbine Building
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| : 15. Unit 1 RWST Area
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| : 16. Unit 2 RWST Area
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| : 17. Hydrogen/Nitrogen Storage Tank Area
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| : 18. Construction Fab Shop
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| : 19. Road to Meteorological Towers
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| : 20. Energy Information. Center Lawn Based upon review of application records and observations of the treated areas, it appears that the herbicides were applied in accordance with herbicide label requirements, and no adverse environmental effects occurred.
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| ATTACHMENT B-2 ATTACHMENTB-2 THER POTENTIAL EXPO URES TO TORMWATER There are seven (7) potential areas of concern which apply to this section which are as follows:
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| : 1. Lube Oil Vapor Extractors - located at various sites on the roof of the turbine building. Small amounts of oil vapor droplets (Mobile DTE 797) have the potential to be spilled onto the roof.
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| During rain periods this oil material would eventually be washed into the roof drain system. From this point it would enter the yard drains and be released to Lake Michigan as depicted in the following diagram:.
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| IN V~ Dwtlrl ~ y Col~ Twg IH ~ Awe ~
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| Loot Snla ~~
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| IW4%1 o Ve4 Wwt TIE tin e lol1 RloW
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| : 2. Steam Generator Blowdowns - Two (2) blowdown outlets are located on the east side of the Auxiliary Building. The steam generators are purged of corrosion products periodically to prevent degradation to the steam generator tubes. Large amounts of steam, which may contain trace amounts of organics, ethanolamine, and boric acid are released into the air outside the plant. The products in the steam precipitate to the ground and eventually enter the yard drain system as demonstrated in the following diagram:
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| Note: Water used in this system (to form the steam) is ultra-purified lake water. This water undergoes stringent purification process before it enters the system.
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| : 3. Dumpster Cleaning - Dumpster Cleaning Main condenser cooling water is screened through 3/8" mesh traveling screens before passing through the main circ. water pump and service water pump inlets. Materials impinged on these screens including sticks, leaves, zebra mussels, and fish, are routinely backwashed into,a trench and sluiced to both ends of the Screenhouse into debris collection baskets. These collection baskets are then dumped into dumpsters which are hauled ofF the plant site by a local. waste hauler. For public health reasons, these dumpsters are cleaned out periodically. Pathfinder, a low suds cleaner, is used with water to wash out these dumpsters. The wash water flows down a yard drain and out outfall 001S.
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| Outfall 001 a Bar.Ia Lsk0Mictagata ~ N Oucataaa XIANg pI i
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| Stean Dcaaa
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| ~
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| I
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| 'alct Pip~
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| : 4. Roadways and Parking Lots- Automobiles, trucks, and heavy equipment require gasoline, diesel fuel, coolants, hydraulic oil, and lubricants for their operation. Small leaks can eventually be washed down the storm drains to Outfalls 001S, 002S, 003S, and 004S.
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| : 5. Garon De-Icer 95% Calcium Chloride and 4% Sodium Chloride.
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| Gran-U-Thaw: 90% Carbonyldiamine, Nitrogen Compounds-Urea.
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| Safe Step Airport Ice Control: Potassium Chloride, Sodium Chloride, Urea, and Methylglucoside. Manufacturer trade secret, percentages unavailable.
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| Used on roads, and sidewalks throughout the facility. This material with precipitation will eventually enter the yard drain system that flows to Lake Michigan through outfalls 001S, 002S, 003S and 004S.
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| These road salt compounds tend to leach oils from the asphalt pavement which are washed into the yard drainage system.
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| Cg UppernmplopaotartloSLoi + Memtal Drahapa Tralslsp BsUSiap tarplsp Loi 5 U pphS ssd kaaairlsS tarlls5 Los SMara alt C>
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| thai hroaa Rosa
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| ~7 Vlrlmitartlsp Lsi Storm Dralaa ~
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| : 6. Fire Protection Systems - To eliminate the threat of zebra mussel infestation in its fire protection system, the plant converted from lake water to a chlorinated municipal water supply.
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| Two 650,000 gallon tanks located south of the plant site provide storage for the fire protection water. The tanks are equipped with an alarm system. The overflow and drainage for these tanks are to the yard drainage system Outfall 003S. On occasion these tanks are drained to perform repairs.
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| Periodically, the fire protection system header and hydrants are flow tested with the water being directed'to the yard drain system. Outfalls 001S, 002S, 003S, and 004S are impacted by these by this testing procedure. The following diagram illustrates the testing and draining process:
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| Fke Prccccaca Wacr Tcrke Bene To Yard Drain S)rt pl ) )care I
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| Bore To take Mictatna
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| : 7. Lawn Sprinkler System- The plant lawn sprinkler system is operated using both circulating water and municipal water supplies. Small amounts of chlorine are contained in the municipal water and in the circulating water which can enter the storm water drainage system and Outfall 001S. Refer to the following diagram for further information.
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| Tramna Corner Encrty Infonnaioa Corner Poet I Oae Of5ce Bai)dmS Man Oonrd Bonne htcrrnkt~C)dorimtcd Leke Mictntna Waer From Dr~t Tannel Scrota W~Pornp R
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| )bkorinaed Wacr From Late Tocrnetop Dac 'ce Boer To Ycrd Drein S)rtem
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| ~ To Lake OO IS
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| ATTACHMENT C ATTACHMENTC I NIFI ANT LEAKS OR SPILLS (past three years)
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| On February 15, March 4, and March 22, 1993, Cook Plant personnel observed a slight sheen on the surface of Lake Michigan, adjacent to the plant's storm water discharges. Subsequent investigation of plant oil systems and operations proved the source to be oil residue from employee vehicles entering the storm water collection system from parking lot runofK Attempts were made to prevent additional oil from entering the catch basins by the use of absorbent booms on all three occasions.
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| A summary of each event is as follows:
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| February 15, 1993 Oil sheen from Outfalls 001S and 002S March 4, 1993 Oil sheen from Outfall 001S March 22, 1993 Oil sheen from Outfall 001S
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| ATTACHMENT D (ANALYTICALRESULTS)
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| ATTACHMENT D
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| *
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| * DESCRIPTION OF RAINFALLEVENT *
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| * Fourteen one-hundredths of an inch (0.14) of rain fell on December 18, 1993. The event started at 0630 hrs. and.terminated at 1000 hrs. Outfalls 001S, 002S, 003S, and 004S continued to flow at a rate of 1-2 liters/min. until 1100 hrs. The previous significant event terminated at 1400 hrs.
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| on December 6, 1993 for a total elapsed time of 280.5 hrs. between events.
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| *
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| * SAMPLING METHOD *
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| * Both grab and flow composite samples were taken during the single storm event of December 18, 1993. Stormwater outfalls 001S, 002S, and 003S were sampled. Since the outfall characteristics of Outfall 003S and 004S are essentially identical, and in very close proximity, Outfall 004S was not sampled. Both Outfall 003S and 004S receive groundwater which emerges from the base of a dune and collects in a trench east of the outfalls. This groundwater mixes with stormwater runoff from the parking lots and roadways south of the plant and flows through outfalls 003S and 004S to Lake Michigan. For purposes of this characterization study, samples were taken of Outfall 003S both before and after mixing with groundwater during the storm event. The results of the analyses are shown in the following pages.
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| ATTACHMENT D VII. Discharge Information PART A 0 TFALL 001S Maximum Values Average Values Number Pollutant of and Storm CAS Number Grab Sample Grab Sample Events (if available) Taken During Flow-weighted Taken During Flow-wcightcd Sampled First 30 Composite First 30 Composite Sources of Pollutants Minutes Minutes Oil and Grease 3.6 mg/I 2.8 mg/I 3.6 mg/I 2.8 mg/I Storm water runoff Biological 4.8 mg/I 3.2 mg/I 4.8 mg/I 3.2 mg/I Storm water runoff Oxygen Demand (BOD5)
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| Chemical 37 mg/I <18 mg/I 37 mg/I <18 mg/I Storm water runoff Oxygen Demand (COD)
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| Total Suspended 34 mg/I 13 mg/I 34 mg/I 13 mg/I Storm water runoff Solids (TSS)
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| Total Kjeldahl 4.9 mg/I 3.7 mg/I 4.9 mg/I 3.7 mg/I Storm water runoff Nitrogen Nitrate plus 1.5 mg/I 1.8 mg/I 1.5 mg/I 1.8 mg/I Storm water runoff Nitrite Nitrogen Total 0.19 mg/I 0.11 mg/I 0.19 mg/I 0.11 mg/I Storm water runoff Phosphorus pH Minimum 7.4 Maximum 7.4
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| XTYACHMENTD (cont.)
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| Part A OUTFALL 002S Maximum Values Average Values Number Pollutant of and Storm CAS Number Grab Sample Grab Sample Events (if available) Taken During Flow-weighted Taken During Flow-weighted Sampled First 30 Composite First 30 Composite Sources of Pollutants Minutes Minutes Oil and Grease <1 mg/I <1 mg/I <I mg/I <1 mg/I Storm water runoff Biological 1.5 mg/I 2.9 mg/I 1.5 mg/I 2.9 mg/I Storm water runoff Oxygen Demand (BOD5)
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| Chemical <18 mg/I <18 mg/I <18 mg/I <18 mg/I Storm water runoff Oxygen Demand (COD)
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| Total Suspended <12 mal <12 mg/I <12 mg/I <12 mg/I Storm water runoff Solids (TSS)
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| Total Kjeldahl 20 mg/I 13 mg/I 20 mg/I 13 mg/I Storm water runoff Nitrogen Nitrate plus 5.6 mg/I 3.2 mg/I 5.6 mg/I 3.2 mg/I Storm water runoff Nitrite Nitrogen Total 0.14 mg/I 0.20 mg/I 0.14 mg/I 0.20 mg/I Storm water runoff Phosphorus pH Minimum 7.9 Maximum 8.4
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| ATTACHMENTD (cont.)
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| 'Part A OUTFALL 003S (Before mixing with groundwater)
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| Maximum Values Average Values Number Pollutant of and Storm CAS Number Grab Sample Grab Sample Events (ifavailable) Taken During Flow-weighted Taken During Flow-weighted Sampled First 30 Composite First 30 Composite Sources of Pollutants Minutes Minutes
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| 'il and Grease 2.1 mg/1 1.8 mg/1 2.1 mg/1 1.8 mg/1 Storm water runoff Biological 2.7 mg/1 2.6 mg/1 2.7 mg/1 2.6 mg/1 Storm water runoff Oxygen Demand (BOD5)
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| Chemical 18 mg/1 19 mg/1 18 mg/1 19 mg/1 'torm water runoff Oxygen Demand (COD)
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| Total Suspended 23 mg/1 15 mg/1 23 mg/1 15 mg/1 Storm water runoff Solids (TSS)
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| Total Kjeldahl 2.0 mg/1 2.1 mg/I 2.0 mg/1 2.1 mg/1 Storm water runoff Nitrogen Nitrate plus 0.78 mg/1 1.0 mg/1 0.78 mg/1 1.0 mg/1 Storm water runoff Nitrite Nitrogen Total 0.29 mg/I 0.36 mg/1 0.29 mg/1 0.36 mg/1 Storm water runoff Phosphorus pH Minimum 7.5 Maximum 7.5
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| <<.TTACHMEI<<IT D (cont.)
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| Part A OUTFALL 003S (After mixing with ground water)
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| Maximum Values Average Values Number Pollutant of and Storm CAS Number Grab Sample Grab Sample Events (if available) Taken During Flow-weighted Taken During Flow-weighted Sampled First 30 Composite First 30 Composite Sources of Pollutants Minutes Minutes Oil and Grease 2.2 mg/I 1.8 mg/I 2.2 mg/I 1.8 mg/I Storm water runoff Biological 2.9 mg/I 1.8 mg/I 2.9 mg/I 1.8 mg/I Storm water runoff Oxygen Demand (BODS)
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| Chemical 26 mg/I <18 mg/I 26 mg/I <18 mg/I Storm water runoff Oxygen Demand (COD)
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| Total Suspended 19 mg/I <12 mg/I 19 mg/I <12 mg/I Storm water runoff Solids (TSS)
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| Total Kjeldahl 1.6 mg/I 0.90 mg/I 1.6 mg/I 0.90 mg/I Storm water runoff Nitrogen Nitrate plus 1.1 mg/I 2.2 mg/I 1.1 mg/I 2.2 mg/I Storm water runoff Nitrite Nitrogen Total 0.23 mg/I 0.13 mg/I 0.23 mg/I 0.13 mg/I Storm water runoff Phosphorus pH Minimum 7.7 Maximum 8.0
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| .O'TACHMENT D (cont.)
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| VII. Discharge Information PART B OUTFALL 001S Maximum Values Average Values Number Pollutant of and Storm CAS Number Grab Sample Grab Sample Events Taken During Taken During Flow-weighted (ifavailable) Flow-weighted Sampled First 30 Composite First 30 Composite Sources of Pollutants Minutes Minutes Cadmium <.005 mg/I <.005 mg/I <.005 mg/I <.005 mg/I Storm water runoff Chloride 36 mg/I 46 mg/I 36 mg/I 46 mg/I Storm water runoff Chlorine <0.02 ppm <0.02 ppm Storm water runoff (total residual)
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| Copper <.025 mg/I <.025 mg/I <.025 mg/I <.025 mg/I Storm water runoff Sulfate 13 mg/I 16 mg/I 13 mg/I 16 mg/I Storm water runoff Total Dissolved 93 mg/I 160 mg/I 93 mg/I 160 mg/I Storm water runoff Solids (TDS)
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| Zinc 0.31 mg/I 0.21 mg/I 0.31 mg/I 0.21 mg/I Storm water runoff
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| | |
| TTACHMENT D (cont.)
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| PART B OUTFALL 002S Maximum Values Average Values Number Pollutant of an'd Storm CAS Number Gmb Sample Grab Sample Events (if available) Taken During Flow-weighted Taken During Flow-weighted Sampled First 30 Composite First 30 Composite Sources of Pollutants Minutes Minutes Cadmium <.005 mg/I <.005 mg/I <.005 mg/I <.005 mg/I Storm water runoff Chloride 2.9 mg/I 3.4 mg/I 2.9 mg/I 3.4 mg/I Storm water runoff Chlorine <0.02 ppm <0.02 ppm Storm water runoff (total residual)
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| Copper 0.029 mg/I <.025 mg/I 0.029 mg/I <.025 mg/I Storm water runoff Sulfate 18 mg/I 26 mg/I 18 mg/I 26 mg/I Storm water runoff Total Dissolved 83 mg/I 100 mg/I 83 mg/I 100 mg/I Storm water runoff Solids (TDS)
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| Zinc 0.46 mg/I 0.22 mg/I 0.46 mg/I 0.22 mg/I Storm water runoff
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| <<TTACHMENT D (cont.)
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| PART B OUTFALL 003S (before mixing with groundwater)
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| Maximum Values Average Values Number Pollutant of and Storm CAS Number Grab Sample Grab Sample Events (if available) Taken During Flow-weighted Taken During Flow-weighted Sampled First 30 Composite First 30 Composite Sources of Pollutants Minutes Minutes Cadmium <.005 mg/I <.005 mg/I <.005 mg/I <.005 mg/I Storm water runoff Chloride 0.75 mg/I 0.86 mg/I 0.75 mg/I 0.86 mg/I Storm water runoff Chlorine <0.02 ppm <0.02 ppm Storm water runoff (total residual)
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| Copper <.025 mg/I <.025 mg/I <.025 mg/I <.025 mg/I Storm water runoff Sulfate 3.4 mg/I 4.0 mg/I 3.4 mg/I 4.0 mg/I Storm water runoff Total Dissolved 88 mg/I 93 mg/I 88 mg/I 93 mg/I Storm water runoff Solids (TDS)
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| Zine 0.28 mg/I 0.29 mg/I 0.28 mg/I 0.29 mg/I Storm water runoff
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| | |
| 4.TTACHMENT D (cont.)
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| . PART B OUTFALL 003S (after mixing with ground water)
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| Maximum Values Average Values Number Pollutant of and Storm CAS Number Grab Sample Grab Sample Events (if available) Taken During Flow-weighted Taken During Flow-weighted Sampled First 30 Composite First 30 Composite Sources of Pollutants Minutes Minutes Cadmium <.005 mg/I <.005 mg/I <.005 mg/I <.005 mg/I Storm water runoff Chloride 1.5 mg/I 4.5 mg/I 1.5 mg/I 4.5 mg/I Storm water runoff Chlorine <0.02 ppm <0.02 ppm Storm water runoff (total residual)
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| Copper <.025 mg/I <.025 mg/I <.025 mg/I <.025 mg/I Storm water runoff Sulfate 25 mg/I 120 mg/I 25 mg/I 120 mg/I Storm water runoff Total Dissolved 97 mg/I 370 mg/I 97 mg/I 370 mg/I Storm water runoff Solids (TDS)
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| Zinc 0.25 mg/I 0.13 mg/I 0.25 mg/I 0.13 mg/I Storm water runoff
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| ',TTACHMENT D (cont.)
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| VII. Discharge Information PART C OUTFALL 001S Maximum Values Average Values Number Pollutant of and Storm CAS Number Grab Sample Grab Sample Events Taken During Taken During Flow-weighted (if available) Flow-weighted Sampled First 30 Composite First 30 Composite Sources of Pollutants Minutes Minutes Aluminum 0.79 mg/I 0.41 mg/I 0.79 mg/I 0.41 mg/I Storm water runoff .
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| Barium <.20 mg/I <.20 mg/I <.20 mg/I <.20 mg/I Storm water runoff Boron <.20 mg/I <.20 mg/I <.20 mg/I <.20 mg/I Storm water runoff Cobalt <0.05 mg/I <0.05 mg/I <0.05 mg/I <0.05 mg/I Storm water runoff Iron 1.6 mg/I 0.7 mg/I 1.6 mg/I 0.7 mg/I Storm water runoff Lead 0.049 mg/I 0.016 mg/I 0.049 mg/I 0.016 mg/I Storm water runoff Magnesium <5.0 mg/I <5.0 mg/I <5.0 mg/I <5.0 mg/I Storm water runoff Molybdenum <0.2 mg/I <0.2 mg/I <0.2 mg/I <0.2 mg/I Storm water runoff Surfactants 0.060 mg/I 0.029 mg/I 0.060 mg/I 0.029 mg/I I Storm water runoff Sulfide <3.0 mg/I <3.0 mg/I <3.0 mg/I <3.0 mg/I Storm water runoff Tin <0.2 mg/I <0.2 mg/I <0.2 mg/I <0.2 mg/I Storm water runoff Radioactivity 2.1 pCi/1 0.69 pCi/1 2.1 pCi/I 0.69 pCifl Storm water runoff (alpha)
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| Radioactivity 6.9 pCi/1 4.3 pCi/I 6.9 pCi/I 4.3 pCi/I Storm water runoff (beta) 10
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| | |
| ATTACHMENT D (cont.)
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| PA'RT C OUTFALL 002S Maximum Values Average Values Number Pollutant of and Storm CAS Number Grab Sample Grab Sample Events Taken During Taken During Flow-weighted (if available) Flow-weighted Sampled First 30 Composite First 30 Composite Sources of Pollutants Minutes Minutes Aluminum 0.26 mg/I <0.20 mg/I 0.26 mg/I <0.20 mg/I Storm water runoff Barium <0.20 mg/I <0.20 mg/I <0.20 mg/I <0.20 mg/I Storm water runoff Boron <0.20 mg/I <0.20 mg/I <0.20 mg/I <0.20 mg/I Storm water runoff Cobalt <0.05 mg/I <0.05 mg/I <0.05 mg/I <0.05 mg/I Storm water runoff Iron 0.73 mg/I 0.40 mg/I 0.73 mg/I 0.40 mg/I Storm water runoff Lead 0.0048 mg/I 0.0032 mg/I 0.0048 mg/I 0.0032 mg/I Storm water runoff Magnesium <5.0 mg/I <5.0 mg/I <5.0 mg/I <5.0 mg/I Storm water runoff Molybdenum <0.2 mg/I <0.2 mg/I <0.2 mg/I <0.2 mg/I Storm water runoff Surfactants 0.029 mg/I 0.031 mg/I 0.029 mg/I 0.031 mg/I Storm water runoff Sulfide <3.0 mg/I <3.0 mg/I <3.0 mg/I <3.0 mg/I Storm water runoff
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| <0.2 mg/I <0.2 mg/I <0.2 mg/I <0.2 mg/I Storm water runoff Radioactivity 0.54 pCi/I 0.64 pCi/I 0.54 pCi/I 0.64 pCi/I Storm water runoff (alpha)
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| Radioactivity 7.0 pCi/I 4.7 pCi/I 7.0 pCi/I 4.7 pCi/1 Storm water runoff (beta) 11
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| | |
| ,TTACHMENT D (cont.)
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| PART C OUTFALL 003S (before mixing with ground water)
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| Maximum Values Average Values Number Pollutant of alld Storm CAS Number Grab Sample Grab Sample Events Taken During Taken During Flow-weighted (if available) Flow-weighted Composite Sampled First 30 Composite First 30 Sources of Pollutants Minutes Minutes Aluminum 1.2 mg/I 0.85 mg/I 1.2 mg/I 0.85 mg/I Storm water runoff Barium <0.20 mg/I <0.20 mg/I <0.20 mg/I <0.20 mg/I Storm water runoff Boron <0.20 mg/I <0.20 mg/I <0.20 mg/I <0.20 mg/I Storm water runoff Cobalt <0.05 mg/I <0.05 mg/I <0.05 mg/I <0.05 mg/I Storm water runoff Iron 2.5 mg/I 1.7 mg/I 2.5 mg/I 1.7 mg/I Storm water runoff Lead 0.0096 mg/I 0.0063 mg/I 0.0096 mg/I 0.0063 mg/I Storm water runoff Magnesium <5.0 mg/I <5.0 mg/I <5.0 mg/I <5.0 mg/I Storm water runoff Molybdenum <0.2 mg/I <0.2 mg/I <0.2 mg/I <0.2 mg/I Storm water runoff Surfactants 0.043 mg/I 0.049 mg/I 0.043 mg/I 0.049.mg/I Storm water runoff Sulfide <3.0 mg/I <3.0 mg/I <3.0 mg/I <3.0 mg/I Storm water runoff Tln <0.2 mg/I <0.2 mg/I <0.2 mg/I <0.2 mg/I Storm water runoff Radioactivity 1.63 pCi/I 0.73 pCi/1 1.63 pCi/1 0.73 pCi/I Storm water runoff (alpha)
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| Radioactivity 5.2 pCi/I 3.1 pCi/I 5.2 pCi/I 3.1 pCi/1 Storm water runoff (beta) 12
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| | |
| ~.TTACHMENT D (cont.)
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| PART C OUTFALL 003S (after mixing with ground water)
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| Maximum Values Average Values Number Pollutant of and Storm CAS Number Grab Sample Grab Sample Events (if available) Taken During Flow-weighted Taken During Flow-wcightcd Sampled First 30 Composite First 30 Composite Sourci:s of Pollutants Minutes Minutes Aluminum 1.2 mg/I 0.46 mg/I 1.2 mg/I 0.46 mg/I Storm water runoff Barium <0.20 mg/I <0.20 mg/I <0.20 mg/I <0.20 mg/I Storm water runoff Boron <0.20 mg/I <0.20 mg/I <0.20 mg/I <0.20 mg/I Storm water runoff Cobalt <0.05 mg/I <0.05 mg/I <0.05 mg/I <0.05 mg/I Storm water runoff 0.94 mg/I 2.3 mg/I 0.94 mg/I Storm water runoff Lead 0.0082 mg/I 0.0031 mg/I 0.0082 mg/I 0.0031 mg/I Storm water runoff Magnesium <5.0 mg/I 14.0 mg/I <5.0 mg/I'4.0 mg/I Storm water runoff Molybdenum <0.2 mg/I <0.2 mg/I <0.2 mg/I <0.2 mg/I Storm water runoff Surfactants 0.031 mg/I 0.031 mg/I 0.031 mg/I 0.031 mg/I Storm water runoff Sulfide <3.0 mg/I <3.0 mg/I <3.0 mg/I <3.0 mg/I Storm water runoff
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| <0.2 mg/I <0.2 mg/I <0.2 mg/I <0.2 mg/I Storm water runoff Radioactivity 1.2 pCi/1 1.1 pCi/1 1.2 pCi/1 1.1 pCin Storm water runoff (alpha)
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| Radioactivity 5.0 pCin 4.3 pCi/I 5.0 pCi/I 4.3 pCi/I Storm water runoff (beta) 13
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| ATTACHMENT E (DRAWINGS)
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| DRAWING NUMBER DESCRIPTION 01 ENTIRE PROPERTY 02 PLANT WITH 001S & 002S 03 PLANT WITH 001S ONLY 04 PLANT WITH 002S ONLY 05 TRAINING CENTER AND ROAD AREA (OUTFALL 001S) 06 SOUTH AREA WITH 003S 2 004S 07 ENERGY INFORMATION CENTER AREA 08 POST 1 GUARD HOUSE AREA 09 PERVIOUS/IMPERVIOUS DRAINAGE AREAS 10 HERBICIDE APPLICATION AREAS 11A TOPO MAP (BRIDGMAN) 11B TOPO MAP (COOK PLANT)
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| Indiana Michigan Power Company O."e SLrnnin Soeare Pa Box60 For; 'Boyne lixed.'6691
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| '25 219 2111 lilt INDIANA NICHIGiAN POWER CERTIFIED MAIL f Z 756 046 675 Mr. William E. McCracken Surface Water Quality Division Permits Section Department of Natural Resources P. 0. Box 30028 Lansing, MI 48909 March 31, 1994
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| ==Dear Mr. McCracken:==
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| Sub)ect: Indiana Michigan Power Company Donald C. Cook nuclear Plant NPDES Permit No. MI 0005827 Renewal Application Enclosed is the Industrial and Commeicial Wastewater Discharge Application for renewal of the Cook Nuclear Plant NPDES Permit.
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| Also enclosed, is for 2P for renewal of the Cook Nuclear Plant Storm Water Discharge Permit. These applications are being submitted 180 days prior to the expiration of the present permit. Cook Nuclear Plant also has submitted a separate groundwater permit application to the agency's groundwater division; the information is also enclosed with this application.
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| During the term of the present permit, several permit modifications were made to improve Cook Nuclear Plant operations. We appreciate your efforts in these permit modifications. Additional changes are under development which will affect Cook Nuclear plant operations. Information regarding these improvements is enclosed with the following attachments:
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| Attachment Descri tion Makeup Demineralizer Regeneration Waste Neutralization System Sequencing Batch Reactors Zebra Mussel Control Strategy Alum Replacement Program Chemistry Corrosion Control Additives Thermal Effluent Should you have any questions regarding these renewal applications, please contact John Carlson, Cook Nuclear Plant
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| March 31, 1994 Mr. William E. McCracken Page 2 Environmental Supervisor, at (616)465-5901 ext. 1153, or me at (219)425-2118. We would be happy to meet with you at your convenience to discuss the application.
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| very truly yours, Donald L. Baker Environmental Affairs Director DLB/sdb/065,66 Attachments certify under penalty of law that I have personally examined and 'am familiar with the information submitted on this and all attached documents; and based on my inquiry of those individuals immediately responsible for obtaining the information, I believe the submitted information is true, accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment.
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| Donald L. Baker
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| March 31, 1994 Mr. William E. McCracken Page 3 bc: W. N. D'Onofrio/M. A. Bailey/J. L. Hughey A. A. Blind S. J. Brewer D. M. Fitzgerald/J. P. Carlson E. E. Fitzpatrick D. W. Kemp/K. D. Hack T. E. Webb/J. P. Novotony
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| Attachment 1 Makeup Demineralizer Regeneration Waste Neutralization System Cook Nuclear Plant is installing a system to collect and treat makeup demineralizer regeneration wastes to meet proposed pH permit limits. The current practice is to isolate the Turbine Room Sump (TRS), accumulate the wastes within the TRS, neutralize the waste with sulfuric acid or sodium hydroxide, and then discharge the neutralized contents of .the TRS to the Absorption Pond. Because the regeneration wastes are not the only source of water being collected in the TRS, a high water level within the TRS may require the discharge of the sump contents prior to the wastes being completely neutralized.
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| The new system vill allow collection and neutralization of the I
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| regeneration wastes apart from the TRS. The holding tank for the waste will also be the point. of treatment with the capability to add and mix sulfuric acid or sodium hydroxide with the waste prior to metering the neutral mixture to the TRS. The total cost of the Makeup Demineralization Waste System is $ 3,600,000.00. The system is targeted for completion by January of 1995, with system start-up to occur thereafter.
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| Attachment 2 Sequencing Batch Reactors Cook Nuclear Plant is currently requesting quotations to install a pair of pre-engineered sequencing batch reactors (SBR) to meet the proposed groundwater effluent limits. The new system will operate at a design flow of 50,000 GPD with a maximum flow of 60,000 GPD.
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| The South Extended Aeration Package Plant will be utilized as a retention tank to ensure efficient SBR operation. Effluent from the new system will continue to be discharged into one of the two seepage lagoons. The new system will be installed and operational by December of 1995.
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| Attachment 3 Zebra Mussel Control Strategy Zebra mussels are a menace to any industrial or municipal process drawing water from Lake Michigan. Our current control plan is to chlorinate and perform periodic shock chemical treatments utilizing proprietary chemical formulations. This method of control was developed for short term relief from the effects of zebra mussel infestation. We have also changed our source water for our fire protection system to a potable supply from Lake Township. After four years of experience in dealing with zebra mussels at Cook Nuclear Plant and other Great Lake facilities, a new strategy is under consideration to protect all operations from infestation.
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| The new strategy incorporates intermittent oxidizing biocide treatments of the circulating water system beginning at the intake structures in Lake Michigan, continuous oxidizing biocide treatment of the essential service water and non-essential service water systems, addition of sodium bisulfate to reduce any residual oxidizing biocide prior to discharge to Lake Michigan, and necessary, shock treatments utilizing proprietary chemical if formulations. The goal of the program is to (1) eradicate existing populations and control further settlement of zebra mussels within plant systems that utilize lake water, (2) reduce the residual oxidant being discharged to non-detectable levels, and (3) reduce or eliminate the number of remedial shock treatments necessary to kill settled colonies of zebra mussels.
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| The proposed oxidizing biocide treatment uses sodium bromide and sodium hypochlorite, or a proprietary mixture such as Nalco Acti-Brom, to retard veliger settlement and maintain microbiological control. Should non-oxidizing biocides be required, we plan to use either Betz CT-2, Betz CT-4, Calgon H-130M, or Nalco 9210. We request the flexibility to use any FIFRA (Federal Insecticide, Fungicide, and Rodenticide Agency) approved non-oxidizing biocide.
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| The concentration of any of the treatment chemicals will be brought to within the water quality based effluent limits, as required, using formulations of bentonite clay or other appropriate material.
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| The resultant chemical changes will ultimately affect discharges to Lake Michigan via ESW, NESW, and the circulating water systems, and discharges to the groundwater through the turbine room sump, from pump seals and equipment drains of the treated systems.
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| We may begin portions of the plan, such as continuous oxidizing biocide treatments of the ESW and NESW systems, in 1994. Portions of the plan, where new systems require capital expenditures along with design and installation of the equipment, will take longer.
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| Therefore, the plan may not be fully implemented for several years.
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| We will continue to inform the MDNR of planned operational changes as they are finalized.
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| Attachment 4 Alum Replacement Program A Chemistry Task Force is evaluating chemical flocculent replacements for alum (aluminum sulfate) to improve performance of the makeup water system. The replacements being reviewed are mainly polymeric 'flocculents which will enhance the removal of suspended solids in the pre-filters and meet manufacturer recommendations for the water entering the reverse osmosis system.
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| The recommendations from the task force, once approved, will require additional time to test and implement. The environmental benefit of product substitution is the reduced amount of aluminum which will be discharged to the groundwater through the turbine room sump. The scheduled target implementation date to use a new flocculent is the fourth quarter of 1994.
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| Attachment 5 Chemistry Corrosion Control Additives Cook Nuclear Plant is evaluating substitutes for the current corrosion control additives in the steam generators, plant heating boiler, feedwater and condensate systems, and closed heating/cooling systems. These substitutes will include carbohydrazide, and other available products from chemical companies such as Betz or Nalco. The environmental benefits of these additives include utilization of more benign corrosion control products or products requiring lower effective concentrations. Use of these products will necessitate discharge to Outfalls 001, 002, 003, OOA, OOB, OOC and OOD in concentrations to be determined upon effective optimization. Consequently, higher concentrations of iron and other system products may be seen temporarily.
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| Attachment 6 Therma1 Effluent The current thermal effluent limit for the circulating water system discharging to Lake Michigan is 15.5 X 10'TU/hr. This is calculated from measurements taken at Outfalls 001 and 002 for Units 1 and 2, respectively. At this limit, the units are operating with calculated maximum temperature differentials of 22.3 and 18.3 degrees F for Units 1 and 2, respectively. The units are have been required to reduce load from 1004 during the hottest summer months to maintain the thermal discharge withxn limits. In order to maintain 1004 load throughout the entire year, including the hot summer months, we propose increasing the thermal discharge limit to 16.25 X 10'TU/hr.
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| At the proposed thermal discharge, the temperature differentials are calculated to be approximately 1 degree F greater< or 23.4 and 19.3 degrees F for Units 1 and 2 respectively, using the same conditions as in the above calculations. The increase in heat load and discharge temperature to Lake Michigan are minimal and are not expected to result in adverse environmental harm in and around the plant discharges. As in the past, the maximum inlet temperature which the units can operate at full power is 87.5 degrees F, because of the limitations on the control room air conditioning system. The maximum effluent temperatures during 1993 were 98.7 and 89.7 degrees F for Units 1 and 2, respectively. Note that Unit 2 operated at 704 load during most of 1993 to increase the time between refueling outages of the two Cook Nuclear Plant Units.
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| Indiana Michigan Power Company funded one of the most extensive aquatic ecological research projects on the Great Lakes from 1973 through 1982 at the Cook Nuclear Plant. Indiana Michigan Power Company's contractor, The University of Michigan, Center for Great Lakes Research Center (then the Great Lakes Research Division),
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| published a book in 1986 that was a compilation of the physical, chemical, and biological studies conducted under the direction of Dr. John C. Ayers. Among other conclusions, these studies documented the lack of adverse impacts from the thermal discharge.
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| The title page, table of contents, and list of publications generated from the research were copied from the book and are attached to this permit application.
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| Thermal plume maps were made during different seasons of the year to determine the impact of the Cook Nuclear Plant thermal effluent on Lake Michigan. These maps showed the surface area of the plume was well within the 570 acre mixing zone specified in the NPDES Permit issued for Cook Nuclear Plant on December 27, 1974, and modified April 4, 1978. Even in the simplistic assumption that a 54 increase in the heat rejection rate resulted in a similar increase of the thermal plume surface area, the resulting plume would still be well within the mixing zone limit. The small increase in the maximum delta T will not measurably alter the thermal regime that already exists in the immediate vicxnity of the high velocity discharge. The thermal discharge from Cook Nuclear Plant was granted a variance from meeting best available treatment technology under Section 316(a) of the Federal Water Pollution Control Act of 1972 by the Water Resources Commission in May, 1977.
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| GREAT LAKES RESEARCH DIYISION / PUBLICATION 22 SOUTHEASTERN NEARSHORE LAKE MICHIGAN:
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| IMPACT OF THE DONALD C. COOK NUCLEAR PLANT Edited by Ronald Rossmann GREAT LAKES RESEARCH DIVISION The University of Michigan Ann Arbor, Michigan 48109 A FINAL REPORT TO INDIANA & MICHIGAN ELECTRIC COMPANY 1986
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| 4 pl CONTENTS INTRODUCTlON Ronald Rossmann SEDIMENTS OF SOUTHEASTERN NEARSHORE ~
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| LAKE MICHIGAN Ronald Rossmann, Kjel/ A. Johansen, and Erwin Seibel ............... 13 WATERS OF SOUTHEASTERN NEARSHORE LAKE MICHIGAN Ronald Rossmann 51 IMPACT OF THE DONALD C. COOK NUCLEAR PLANT ON PHYTOPLANKTON Ronald Rossmann, William Y. B. Chang, James A. Bowers, Laurie Feldt, and James Barres 87 PHYTOPLANKTON POPULATIONS OF SOUTHEAST LAKE MICHIGAN 1974-1982 James A. Bowers, Ronald Rossmann, James Barres, and William Y. B. Chang 141 IMPACT OF THE DONALD C. COOK NUCLEAR PLANT ON ZOOPLANKTON IN SOUTHEASTERN LAKE MICHIGAN Marlene S. Evans and Glenn J. Warren 169 EFFECTS OF THE DONALD C. COOK NUCLEAR PLANT ON IN NEARSHORE SOUTHEASTERN 'ACROZOOBENTHOS LAKE MICHIGAN David S. White, Michael Winnell, Catherine Zawacki, Roger LaDronka, Thomas Zdeba, and Samuel Mozley 207 ECOLOGY OF THE MACROZOOBENTHOS IN THE VICINITYOF THE DONALD C. COOK NUCLEAR PLANT David. S. White, Michael Winnell, Catherine Zawacki, Roger LaDronka, Thomas Zdeba, and Samuel Mozley 253 IMPACT OF THE DONALD C. COOK NUCLEAR PLANT ON FISH.
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| David J. Jude, David Bimber, Nancy Thurber, Frank Tesar, Laura Nogucht', Pamela Mansfield, Heang Tin, Paul Rago 285 ECOLOGY OF FISH IN NEARSHORE SOUTHEASTERN LAKE MICHIGAN, 1973-1982 Frank Tesar, David J. Jude, He'ang Tin, Pamela Mansfield ............ 353 LAKE AND SHORE ICE CONDITIONS ON SOUTHEASTERN LAKE MICHIGAN Erwin Seibel . 401
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| INTRODUCTION Ronald Rossmann The Laurentian Great Lakes serve as a source of cooling water for both fossil- and nuclear-fueled power plants. In the early 1960s, projected heavy utilization of this freshwater resource by power plants raised concerns about the environmental impact of power plants on the lakes. Such public, governmental, and industrial concerns led to the federal requirement that environmental impact studies be con-ducted at all proposed or newly constructed power plants, especially nuclear power plants. The Great Lakes Research Division of The University of Michigan was contracted by Indiana & Michigan Electric Company to conduct an environmental" impact study of the Donald C. Cook Nuclear Plant, investigating the area through the pre-operational years of construction and into the period of plant operation.
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| DONALD C. COOK NUCLEAR PLANT The Donald C. Cook Nuclear Plant is a 2,200 MW steam electric generating station situated in a belt of sand dunes on the southeastern shore of Lake Michigan about 18 km southwest of St. Joseph, Michigan (Indiana & Michigan Electric Com-pany and Indiana &, Michigan Power Company 1973) (Fig. I). Preparation of the site for construction of the plant began in 1968. Unit I was operational in 1975 and Unit 2 in 1978. The plant was built at a time when public concern for the environ-ment reached its zenith.
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| At full operation, the plant uses roughly 6,300 m'f lake water per minute in once-through cooling of its condensers; the water returned to the lake is 9-12C'bove the intake temperature. Water is withdrawn from the lake through three intake cribs located at a water depth of 7.3 m approximately 686 m offshore (Fig. 2).
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| The intake structures extend 2 m above the lake bottom. Maximum water velocity is 1.8 m/s within the three 4.9-m diameter intake pipes. Condenser cooling water is returned to the lake through two discharge pipes located at a water depth of 5.5 m approximately 366 m offshore. Riprap beds of crushed limestone were deposited around the intake and discharge structures to prevent erosion and scour of the lake bottom. During winter, water is only drawn into the plant through the two outer intake cribs. Heated water is discharged through the center intake, which is turned into a discharge to prevent ice formation around the other intake structures.
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| Within the screenhouse, trash bars 6.6 cm apart prevent large pieces of debris .
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| from entering the intake forebay. Vertical traveling 9.5-mm bar mesh screens within the forebay impinge trash and fish too large to pass through the condensers.
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| HISTORY OF THE ENVIRONMENTALIMPACT STUDY Though the Great Lakes Research Division's environmental impact study included physical and chemical studies of nearshore southeastern Lake Michigan, it focused
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| 2 D. C. COOK iVUCLEAR PLAtVT IMPACT MUSKEGON MILWAUKEE Ktlometero ST. JOSEPH COOK PLANT CHICAGO FIGURE I. Location of the Donald C. Cook Nuclear Plant on the southeastern shoreline of Lake Michigan.
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| on major biological components of the ecosystem (benthos, phytoplankton, zoo-plankton, fish) and shoreline erosion. Preoperational surveys began in 1966. Until 1970, they were sporadic and consisted mainly of phytoplankton enumerations and some benthos and zooplankton enumerations. Between 1970 and 1972, seasonal surveys, primarily of phytoplankton and secondarily of zooplankton and benthos, were conducted. Beginning in 19'72 and continuing iltto 1982, sampling frequency and intensity increased and equal effort was given to studies of phytoplankton, zooplankton, and benthos. Fishery studies began in 1972. They represented roughly 50olo of the study effort between 1973 and 1982.
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| Until 1974, all studies were carried out on nearshore southeastern Lake Michigan.
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| ln 1974, preliminary studies of the entrainment of organisms through the plant and their impingement on the plant's traveling screens began. When unit 1 of the plant became operational in 1975, full-scale entrainment studies of phytoplankton, zoo-
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| IIVTRODUCTlON 3 PITAKES tdepttr S )
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| IIORTH SOUTH DISCHARGE DISCHARGE tdeptli 6m) tdepth~6m)
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| Lcd Atichipn PITAKE SALPUIIG LOCATIOIIS I I ptTAKE FOREtutf TRASH BARS WIT 2 DISCHARGE tet II 8 7 6S es T I UNT I OSCHARGE FOREBAY FOREBAY TRAVELING SCREEIIS DISCHARGE AAIAPLPIG CIRCILATPIQ TER PINPS CONDENSER WIT 2 COIE)ENSER LNIT I FIGURE 2. Schematic representation of the Donald C. Cook hluclear Plant circu-lating water system.
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| plankton, benthos, fish eggs, and fish larvae began. At the same time, impingement of fish and benthos on the traveling screens was monitored. All field studies ceased in 1982. This book represents the highlights of the findings from the impact study.
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| For details of each facet of the study, the reader is referred to the list of all project reports (Table I). These are available upon request.
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| TABLE l. Reports on the Donald C. Cook Nuclear Plant environmental impact study.
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| Ayers, J. C., and J. C. K. Huang. 1967. General studies. Part I, Benton Harbor Power Plant Limnological Studies, Special Report 44. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 31 pp.
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| Ayers, J. C., A. E. Strong, C. F. Powers, and R. Rossmann. 1967. Studies of local winds and alongshore currents. Part II, Benton Harbor Power Plant Limnological Studies, Special Report 44. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.
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| y 45 pp
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| ), Ayers. J. C., R. F. Anderson, N. W. O'ara, and C. Kidd. 1970. Cook Plant preaperational y studies l969. Part IV, Benton Harbor Power Plant Limnological Studies, Special Report
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| : 44. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 92 pp.
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| ). Ayers, J. C.. D. E. Arnold, R. F. Anderson, and H. K. Soo. 1971. Cook Plant preaperational d sludies l970. Part VII, Benton Harbor Power Plant Limnological Studies, Special Report
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| )t 44. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 85 pp.
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| Ayers. J. C., N. W. O'ara, and W. L. Yocum. 1971. fYinter operations 1970-1971. Part
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| 4 D. C. COOK NUCLEAR PLANT IMPACT Vill. Benton Harbor Power Plant Limnological Studies, Special Report 44. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 41 pp.
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| Ayers, J. C.. W. L. Yocum, H. K. Soo, T. W. Bottrell, S. C. Mozley, and L. C. Garcia. 1971.
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| The biological survey of 10 July 1970. Part IX, Benton Harbor Power Plant Limnological Studies, Special Report 44. Great Lakes Research Division. The University of Michigan, Ann Arbor, Mich. 72 pp.
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| Ayers, J. C., H. K. Soo, and W. L. Yocum. 1972. Cook Plant preoperational studies 1971.
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| Part X, Benton Harbor Power Plant Limnological Studies, Special Report 44. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 152 pp.
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| Ayers, J. C., and W. L. Yocum. 1972. IVinter operations 1971-1972. Part XI, Benton Harbor Power Plant Limnological Studies, Special Report 44. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 26 pp.
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| Ayers, J. C.; and E. Seibel (eds.). 1973. Cook Plant preoperational studies 1972. Part Xlll.
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| Benton Harbor Power Plant Limnological Studies, Special Report 44. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 281 pp.
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| Ayers, J. C., W. L. Yocum, and E. Seibel. 1973. IYinter operations 1972-1973. Part XIV, Benton Harbor Power Plant Limnological Studies, Special Report 44. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 22 pp.
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| Ayers. J. C., S. C. Mozley, and J. C. Roth. 1973. The biological survey of 12 iVovember 1970.
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| Part XV, Benton Harbor Power Plant Limnological Studies, Special Report 44. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 69 pp.
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| Ayers, J. C., and E. Seibel (eds.). 1973. Program of aquatic studies related to the Donald C.
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| Cook Nuclear Plant. Part XVII, Benton Harbor Power Plant Limnological Studies, Spe-cial Report 44. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 57 pp.
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| Ayers. J. C., S. C. Mozley, and J. A. Stewart. 1974. The seasonal biological surveys of 1971.
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| Part XIX, Benton Harbor Power Plant Limnological Studies, Special Report 44. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 181 pp.
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| Ayers, J. C. 1975. Bacteria and phytoplankton of the seasonal surveys of 1972 and 1973. Part XXI, Benton Harbor Power Plant Limnological Studies, Special Report 44. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 153 pp.
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| Ayers, J. C. 1975. The phytoplankton of the Cook Plant monthly minimal surveys during the preoperational years 1972, 1973 and 1974. Special Report 59, Great Lakes Research Divi-sion, The University of Michigan, Ann Arbor, Mich. 51 pp.
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| Ayers. J. C., N. V. Southwick, and D. G. Robinson. 1977. Phytoplankton of the seasonal surveys of 1974 and 197S and initial pre- vs. post-operational comparisons at Cook Nuclear Plant. Part XXIII, Benton Harbor Power Plant Limnological Studies, Special Report 44. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.
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| 279 pp.
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| Ayers, J. C. 1978. Phytoplankton of the seasonal surveys of 1976, of September 1970, and pre- vs. post-operational comparison at Cook Nuclear Plant. Part XXV, Benton Harbor Power Plant Limnological Studies, Special Report 44. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 258 pp.
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| Ayers, J. C., and S. J. Wiley. 1979. Phytoplankton of the seasonal surveys of 1977, and further pre- vs. post-operational comparisons at Cook Nuclear Plant. Part XXVII,Benton Harbor Power Plant Limnological Studies, Special Report 44. Great Lakes Research Division. The University of Michigan, Ann Arbor, Mich. 92 pp., plus Appendix of 3 microfiche cards (122 pp.).
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| Ayers, J. C., and L. E. Feldt. 1982. Phytoplankton of the seasonal surveys of 1978 and 1979, and further pre- vs. post-operational comparisons at Cook Nuclear Plant. Part XXIX, Benton Harbor Power Plant Limnological Studies, Special Report 44. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 70 pp., plus Appendi-ces of 9 microfiche cards (256 pp.).
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| Ayers, J. C., and L. E. Feldt. 1983. Phytoplankton of the seasonal surveys of 1980, 1981, and April 1982 and further pre- vs. postoperational comparisons at Cook Nuclear Plant. Part
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| INTRODUCTION 5 XXXI, Benton Harbor Power Plant Limnological Studies, Special Report 44. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 91 pp., plus Appendi-ces of 5 microfiche cards (268 pp.).
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| Barres, J., L. Feldt, W. Chang, and R. Rossmann. 1984. Entrainment of phytoplank(on at the Donald C. Cook lVuclear Plant-1980-19B2. Part XXXII, Benton Harbor Power Plant Limnological Studies, Special Report 44. Great Lakes Research Division, The Uni-versity of Michigan, Ann Arbor, Mich. 92 pp., plus Appendices of 7 microfiche cards (486 pp ).
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| Bimber, D. L., M. Perrone, Jr., 1. Noguchi, and D. J. Jude. 1984. Field distribution and entrainment offish larvae and eggs at the Donald C. Cook Nuclear Power Plant, south-eastern Lake Michigan, 1973-1979. Special-Report 105. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 320 pp.
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| Chang, W., R. Rossmann, J. Pappas, and W. L. Yocum. 1981. En(rainmen( of phyto-plankton at (he Donald C. Cook Nuclear Plant-1978. Part XXVlll, Benton Harbor Power Plant Limnological Studies, Special Report 44. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 106 pp., plus Appendix of 4 microfiche cards (180 pp.).
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| Chang, W. Y. B., and M. S. Shahraray. 1986. Interactive data base managemen( system for ecological studies rela(ed to the Donald C. Cook ¹clear Power Plant. Special Report 119.
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| Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 158 pp.
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| Dorr, J. A., II I, and T. J. Miller. 1975. Underwater opera(ionsin southeastern Lake Michigan near the Donald C. Cook (Vuclear Plant during 1974. Part XXII,-Benton Harbor Power l.
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| Plant Limnological Studies, Special Report 44. Great Lakes Research Division, The Uni-versity of Michigan, Ann Arbor, Mich. 32 pp.
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| Dorr, J. A., lll, and D. J. Jude. 1986. Diver assessment of (he inshore sou(heastern Lake Michigan environment near the D. C. Cook iVuclear Plant, 1973-82. Special Report 120.
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| at Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.
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| Evans, M. S. 1975. The 1975 preoperational zooplank(on investigations relative to the Donald C. Cook Nuclear Power Plant. Special Report 58. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 187 pp.
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| Evans, M. S., T. E. Wurstcr, and B. E. Hawkins. 1978. The 1975 and 1976 operational
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| :ooplankton inves(igations relative to the Donald C. Cook iVuctear Power Plam, with tests for plant effects (1971-197(f). Special Report 64. Great Lakes Research Division, The al University of Michigan, Ann Arbor, Mich. 166 pp., plus Appendix of 4 microfiche cards (236 pp.).
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| tk tl Evans, M. S., D. W. Sell, and D. I. Page. 1982. Zooplankton studiesin 1977 and 1978 at'the
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| : h. Donald C. Cook Nuclear Power Plant; comparisons of preoperational (1971-/974) and opera(ional (197$ -1978) population chare(eristics. Special Report 89. Great Lakes nd Research Division, The University of Michigan, Ann Arbor, Mich. 235 pp., plus Appendix
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| >of of 5 microfiche cards (222 pp.).
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| he Evans, M. S., G. J. Warren, D. I. Page, and L. F. Flath. 1986. Zooplankton studies at the Donald C. Cook Nuclear Power Plant: 1979-1982 investigations including preoperational nd (1971-1974) and operational (1975-1982) comparisons. Special Report 111. Great Lakes on Research Division, The University of Michigan, Ann Arbor, Mich.
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| ch Johnston, E. M. 1973. Effect of a thermal discharge on benthos populations: Statistical f3 methods for assessing the impact of the Cook Nuclear Plant. Part XVIII,Benton Harbor Power Plant Limnological Studies, Special Report 44. Great Lakes Research Division, The 79, University of Michigan. Ann Arbor, Mich. 20 pp.
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| IX, Johnston. E. M. 1974. Statistical po~er of a proposed method for detecting the effect of kes waste heat on benthos populations. Part XX, Benton Harbor Power Plant Limnological idt- Studies, Specia! Report 44. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 29 pp.
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| Jude, D. J-, T. W. Bottrell, J. A. Dorr III, and T. J. Miller. 1973. S(udies of the fish population near the Donald C. Cook Nuclear power plant, 1972. Part Xlt, Benton
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| 6 D. C. COOK NUCLEAR PLANT IMPACT Harbor Power Plant Limnological Studies, Special Report 44. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 115 pp.
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| Jude, D. J., F. J. Tcsar, J. A. Dorr III, T. J. Miller, P. J. Rago, and D. J. Stewart. 1975.
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| Inshore Lake Michigan fish populations near the Donald C. Cook Nuclear Power Plan(,
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| l973. Special Report 52. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 267 pp.
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| Jude, D. J., F. J. Tesar, J. C. Tomlinson, T. J. Miller, N. J. Thurber, G. G. Godun, and J. A. Dorr lll. 1979. Inshore Lake Michigan fish populations near the D. C. Cook Nuclear Plan( during preopera(ional years- l973, l974. Special Report 71. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 529 pp.
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| Kidd, C. C. 1970. Pontoporcia af finis (Crus(acea, Amphipoda) as a moni(or of radionuclides released (o Lake Michigan. Part VI, Benton Harbor Power Plant Limnological Studies, Special Report 44. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 71 pp.
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| Krezoski, J. R. 1969. Some effects of power plant was(e heat on the ecology of Lake Michi-gan. Part lll, Benton Harbor Power Plant Limnological Studies, Special Report 44. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 78 pp.
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| LaDronka, R. M. 1984. Oligochae(a. Part 3: Ecology of the zoobenthos of southeastern Lake Michigan near the D. C. Cook Nuclear Power Plant. Special Report 103. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 290 pp.
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| Lauritsen, D. D., and D. S. White. 1981. Compara(ives(udies of the zoobenthos of a na(ural and a man-made rocky habi(a( on the eas(em'shore of Lake Michigan. Special Report 74.
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| Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 65 pp.
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| Mozley, S. C. 1975. Preopera(ional investigations of zoobenthos in southeastern Lake Michi-gan near the Cook Nuclear Plan(. Special Report 56. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 132 pp.
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| Noguchi, L. S., D. L. Bimber, H. T. Tin, P. J. Mansfield, and D. J. Jude. 1985. Field dis(ribu(ion and en(rainmen( offish larvae and eggs a( (he Donald C. Cook Nuclear Power Plant, sou(heas(em Lake Michigan, l980-l982. Special Rcport 116. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 251 pp.
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| O'ara, N. W., R. F. Anderson, W. L. Yocum, and J. C. Ayers. 1970. Winter opera(ions, March l970. Part V, Benton Harbor Power Plant Limnological Studies, Special Report
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| : 44. Great Lakes Research Division, Thc University of Michigan, Ann Arbor, Mich. 17 pp.
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| Rossmann, R. 1975. Chemis(ry of nearshore sur/icial sediments from sou(heas(em Lake Michigan. Special Report 57. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 62 pp.
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| Rossmann, R., N. M. Miller, and D. G. Robinson. 1977. Entrainment of phy(oplank(on a(
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| the Donald C. Cook Nuclear Plan(-l97S. Part XXIV, Benton Harbor Power Plant Limnological Studies, Special Report 44. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 265 pp.
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| Rossmann, R., L. D. Damaske, and N. M. Miller. 1979. Entrainment ofphy(oplank(on a( the Donald C. Cook Nuclear Plan(-l976. Part XXVI, Benton Harbor Power Plant Limno-logical Studies, Special Report 44. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 88 pp., plus Appendix of 3 microfiche cards (154 pp.).
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| Rossmann, R., W. Chang, L. D. Damaske, and W. L. Yocum. 1980. Entrainment of phy(o-plank(on a( the Donald C. Cook Nuclear Plan(-/977. Special Report 67. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 180 pp., plus Appendix of 2 microfiche cards (118 pp.).
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| Rossmann, R., W. Chang, and J. Barres. 1982. En(rainmen( ofphy(oplank(on a( the Donald C. Cook Nuclear Plan(-l979. Part XXX, Benton Harbor Power Plant Limnological Studies, Special Report 44. Great Lakes Research Division, The University of Michigan, Ann Arbor. Mich. 98 pp., plus Appendix of 4 microfiche cards (156 pp.).
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| Seibel, E.. J. C. Roth, J. A. Stewart, S. L. Williams. 1973. Psammoli((oral inves(iga(ion 1972. Part XVI, Benton Harbor Power Plant Limnological Studies, Special Report 44.
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| Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 63 pp.
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| INTRODUCTION 7
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| .rch Scibcl, E., and J. C. Ayers (cds.). 1974. The biological, chemical, and physical character of Lake Michigan in the vicinity of (he Donald C. Cook Nuclear Plant. Special Report 51.
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| >75. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 475 pp.
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| znt, Scibcl, E., C. T. Carlson, and J. W. Maresca, Jr. 1975. Lake and shore ice conditions on Xnn southeastern Lake Michigan in the vicinity of the Donald C. Cook Nuclear Plant: ~inter l973-74. Special Report 55. Great Lakes Research Division, The University of Michigan, and Ann Arbor, Mich. 62 pp.
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| ook Tcsar, F. J., and D. J. Jude. 1985. Adul( and juvenile fish populations ofinshore southeast-ikcs ern Lake Michigan near the Cook Nuclear Power Plant during l973-82. Special Report 106. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.
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| ides 94 pp., plus Appendices of 5 microfiche cards (301 pp.).
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| lies, Tesar, F. J., D. Einhousc, H. T. Tin, D. L. Bimber, and D. J. Jude. 1985. Adult and juvenile Ann fish populations near the D. C. Cook Nuclear Power Plant southeastern Lake Michigan during preoperational (I973-74) and operational (l97$ -79) years. Special Report 109.
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| chi- Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 341 pp.
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| rcat Thurber, N.. and D. J. Jude. 1984. Impingement losses at the D. C. Cook iVuclear Plant during l975-l979 with a discussion of fac(ors responsible and rela(ionships to field
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| .akc catches. Special Report 104. Great Lakes Research Division, The University of Michigan, skes Ann Arbor, Mich. 24 pp., plus Appendix (75 pp.).
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| 'ural Thurber, N., and D. J. Jude. 1985. Impingement losses at the D. C. Cook lVuclear Plant during l975-l982 with a discussion of factors responsible and possible impac( on local populations. Special Report 115. Great Lakes Research Division, The University of Michi-gan, Ann Arbor, Mich. 70 pp., plus Appendix (88 pp.).
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| The White, D. S., and M. H. Winncll. 1986. Introduction. Part 1: Ecology of the zoobenthos of southeastern Lake Michigan near thc D. C. Cook Nuclear Povver Plant. Special Report
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| ~ield 122. Great Lakes Research Division, Thc University of Michigan. Ann Arbor, Mich.
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| ~
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| iwer Winncll, M. H. 1984. Malacostraca (Amphipoda, Mysidacea, Isopoda, and Decapoda). Part arch 5: Ecology of the zoobenthos of southeastern Lake Michigan near the D. C. Cook Nuclear Power Plant. Special Report 99. Great Lakes Research Division, The University of Michi-
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| ~ns, gan, Ann Arbor, Mich. 94 pp.
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| pof't Winncll, M. H. 1984. Chironomidae (and other Diptera). Part 6: Ecology of the zoobenthos PP of southeastern Lake Michigan near the D. C. Cook Nuclear Pouter Plant. Special Report
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| ,ake 100. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.
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| gan, 177 pp.
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| Zawacki, C. M. 1985. Minor taxa (Hydrozoa, Turbellaria, Hirudinea, Arachnoidea, non-in at Dip(eran insects, Gastropoda, and zoobenthic meiofauna). Part 2: Ecology of the zooben-
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| 'lant thos of southeastern Lake Michigan near the D. C. Cook Nuclear Power Plant. Special
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| :rsity Report 112. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich. 201 pp.
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| rt the Zdeba, T. W., and D. S. White. 1985. Pisidiidae. Part 4: Ecology of the zoobenthos of mno- southeastern Lake Michigan near the D. C. Cook Nuclear Power Plant. Special Report ty of 113. Great Lakes Research Division, The University of Michigan, Ann Arbor, Mich.
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| ) 85 pp.
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| hyto-akes cndix onald agical This book has been structured so that each chapter dealing with a specific facet of uigan. the study will be complete in itself, and can be read as a separate entity by those who at, wish. To familiarize the reader with the region of southeastern Lake Michigan where the plant is situated, a description of the area's characteristics follows.
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| )PP
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| 8 D. C. COOK hIUCLEAR PLANT IMPACT Depth Contours INTERVAL= 2 hKTERS SX JOSEPH
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| ~12~4 DONALD C. COOK NUCLEAR PLANT FIGURE 3. Bathymetry of nearshore southeastern Lake Michigan.
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| DESCRIPTION OF THE SOUTHEASTERN LAKE MICHIGAN REGION LAKE BOTTOM TOPOGRAPHY The topography of the lake bottom within the region of study slopes toward the northwest with greatest depths in excess of 38 m (Fig. 3). At depths greater than 20 m, a series of ridges and runnels perpendicular to shore occurs (Rossmann 1975).
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| INTRODUCTION 9 The ridges consist of coarser sediments than the runnels (Rossmann and Seibel 1977).
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| Near the shoreline, one ephemeral and two permanent sand bars exist (Seibel et al.
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| 1976). The ephemeral bar is located approximately 47 m from the shoreline. The inner and outer permanent bars are located 116 and 216 m from the shoreline, respectively. Water depths between the inner bar and shoreline and between the two permanent bars are 1.5 to 1.8 m and 3.7 to 4.0 m, respectively (Ayers and Huang 1967). The depth of water over the crest of the inner bar is 1.2 m and that over the outer bar is 2.6 m.
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| SEDIMENTS Sediments vary from coarse to fine quartz sands at the shoreline to carbonate-rich very fine sands and silts offshore {Rossmann and Seibel 1977). The sediments are derived from sand dunes and unconsolidated bluffs along the shoreline (Hands 1970). The bluffs are clay-rich and contain carbonates (Rossmann 1975). During the early to mid-l970s, severe shoreline erosion occurred within the study area (Davis et al. 1973, Tanner 1975). Material derived from this erosion as well as from rain runoff and stream transport is resuspended and sorted by waves and currents (Sly and Thomas 1974). Materials are finally deposited offshore where waves and cur-rents are incapable of transporting them farther.
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| CURRENTS The major lake current within the region of Lake Michigan is called the Benton Harbor eddy. This eddy moves in a clockwise direction with currents moving south-westward along the shoreline (Ayers et al. 1958, Bellaire 1964). Inshore of this eddy, a counterclockwise eddy with currents moving northeastward adjacent to the shore-line was tentatively identified by Ayers et al. {1958).
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| Between May and November, current direction between the inner and outer sand bars is predominantly to the northwest. Direction was always to the north, north-west, or west between May and July regardless of wind direction (Ayers et al. 1967).
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| Beginning in August when the wind was brisk from northerly directions, currents moving in a southward direction began to occur with increased frequency. Smaller velocity and frequency of northerly winds were required to produce southward currents later in the fall. For the months of May through October in 1967, over 86Vo of the time current direction between the two bars was northward. Monthly mean current velocities ranged between 31.7 and 69.8 cm/sec.
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| Inshore of the inner sand bar, current direction is controlled by wind direction.
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| Water between the beach and inner bar is postulated to be water spilled over the inner bar during surf action. It is cut off from the main-lake circulation by the inner bar and is moved in a downwind direction (Ayers et al. 1967).
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| WAVES 1 the Wave observations have been reported by Liu and Housley (1969) for St. Joseph, 17 Michigan (Fig. 1). For the periods of 28 September 1966 to 16 December 1966 and 21
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| 10 D. C. COOK NUCLEAR PLANT IMPACT September 1967 to 30 December 1967, maximum observed wave height was between 3.6 and 3.0 m. Maximum wave period was between 7 and 8 seconds. The most frequent wave height and period were 0.6 to 1.3 m and 5 to 6 seconds, respectively.
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| Waves most often approached the shoreline from the northwest or southwest.
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| LOCAL WINDS Based upon observations during 1967, surface winds adjacent to the shoreline are greatly influenced by a bluff of sand dunes 61 m from the shoreline that parallel the shore and run in a north-northeast to south-southwest direction (Ayers et al. 1967).
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| These dunes serve to protect nearshore waters from winds from north-northeast, around through east and south, to south-southwest. They also channel winds from northerly and southerly directions into a NNE-SSW direction. Between May and mid-November the most often recorded winds were from the NNE (14.2o/o of the time) and SSW (22.6o/o of the time). Average wind velocity ranged from 9 km/h in June to 16 km/h in November. General prevailing winds for the region are from westerly directions throughout the year.
| |
| THERMAL CYCLE OF WATER COLUMN The exact time of occurrence of various events in the thermal cycle is dependent upon the rate at which the lake warms as well as the severity of a winter. Warming of nearshore waters begins in spring with snowmelt and spring rains. As lake waters warm, a nearshore thermal bar develops which is delineated by the 4'C isotherm. As the lake continues to warm, the thermal bar progresses farther offshore. The ther-mal bar was usually found within the study area during April.
| |
| Eventually, the thermal bar moves out of the study area and a thermally stratified water column develops. This usually occurs in May or very early June. Thermal stratification usually continues into and occasionally through November. For the calendar year, surface water temperatures range between I.l and 26.9'C, while those of the hypolimnion range between 5.0 and 6.5'C. During stratification, upwellings of hypolimnion water with temperatures as low as 6'C are common along the shoreline. Except during upwellings, water depths ((45.m) in the study area were only great enough to permit sampling hypolimnetic water at those stations farthest offshore.
| |
| LITERATURE CITED Ayers, J. C., D. C. Chandler, G. H. Lauff, C. F. Powers, and E. B. Henson. 1958.
| |
| Currenls and wafer masses of Lake Michigan. Publ. No. 3, Great Lakes Res.
| |
| Div., Univ. Michigan, 116 pp.
| |
| Ayers, J. C., and J. C. K. Huang. 1967. Ben(on Harbor power plant studies, Part I.
| |
| General studies. Spec. Rep. No. 44, Great Lakes Res. Div., Univ. Michigan, 37 pp.
| |
| Ayers, J. C., A. E. Strong, C. F. Powers, and R. Rossmann. 1967. Benton Harbor power plant studies, Part II. Studies of local winds and alongshore currents.
| |
| Spec. Rep. No. 44, Great Lakes Res. Div., Univ. Michigan, 20 pp.
| |
| | |
| INTRODUCTION cI I n Bellaire, F. R. 1964. A comparison of methods of current determinations. In Proc.
| |
| st 7(h Conf. Great Lakes Res., pp. 171-178 Great Lakes Res. Div., Univ. Michigan.
| |
| Davis, R. A., E. Seibel, and W. T. Fox. 1973. Coastal erosion in eastern Lake Michigan-causes and effects. In Proc. 16th Conf. Great Lakes Res., pp.
| |
| 404-412. Internat. Assoc. Great Lakes Res.
| |
| Hands, E. B. 1970. A geomorphic map of Lake Michigan shoreline. In Proc. 16th Conf. Great Lakes Res., pp. 250-265. Internat. Assoc. Great Lakes Res.
| |
| Indiana & Michigan Electric Company and Indiana & Michigan Power Company.
| |
| re 1973. Final environmental statement related to operation of Donald C. Cook te Nuclear Plant Units I and 2.
| |
| ). Liu, P. D., and J. G. Housley. 1969. Visual wave observations along 'the Lake t, Michigan shore. In Proc. 12th Conf. Great Lakes Res., pp. 608-621. Internat.
| |
| m Assoc. Great Lakes Res.
| |
| id Rossmann, R. 1975. Chemisrry of nearshore surficial sediments from southeastern
| |
| >e Lake Michigan. Spec. Rep. No. 57, Great Lakes Res. Div., Univ. Michigan,
| |
| ~
| |
| n 62 pp.
| |
| n Rossmann, R., and E. Seibel. 1977. Surficial sediment redistribution by wave energy: element-grain size relationships. J. Great Lakes Res. 3:258-262.
| |
| Seibel, E., C. T. Carlson, and J. W. Maresca, Jr. 1976. Ice ridge formation: proba-ble control by nearshore bars. J. Great Lakes Res. 2:384-392.
| |
| Sly, P. G., and R. L. Thomas. 1974. Review of geological research as it relates to an understanding of Great Lakes limnology. J. Fish Res. Board Can. 31:795-825.
| |
| Tanner, F. W. 1975. Beach processes, Berrien County, Michigan. J. Great Lakes af Res. I:171-178.
| |
| rs Xs
| |
| .I e
| |
| 1, n
| |
| y 15
| |
| | |
| EPA I.D.NUMBER M I D 0 9 6 4 7 6 1 SECTION I PERMIT NUMBER ~
| |
| APPLICATION FOR DISCHARGE PERMIT IS:
| |
| M100 05827 SEE INSTRUCTIONS ON REVERSE SIDE tsm[F I TION EXI TING hEM ItKREASED USE RE ISSIAIICE ITEM AP~~~~~'~~'ER B. DIV.i[NREAU N A INDIANA M I C I GAN POWER COMP 0 D H NY 1 C. PLAIITOR FACILITY D C C 0 0 K P L A N T Es STANDARD INDUSTRI)[L C[ASSIF ICATION (REFER TO TABLE II)
| |
| PHYSICAL L D. TYPE CF FACILITY S T M E E C T R G E N ~qg LOCATION f e STREET tlHKR G~ STREET BVK ADDRESS COOK P LAC E Hs CllY [[A% I~ ZIP CODE AND INFORMATION BRI DGMAN Ml 491 06 J s TCWNSHIP K>> CXNIY (REFER TO TABLE I)
| |
| LAKE BERRIEN CO. IAPBER ~>
| |
| Le NA% OF AUDCRIZED CONTACT PERSON Hs TITLE DONALDLBAKR NV AFFAIRS I R O. AXRESS (IF DIFFERENT FR[V[ ABOVE) 2 1 9 ~42 ~21 POBOX60 Ps CITY RVK Oe STATE Re ZIP GXK FORT WAY E 468 01 5~ lYPE OF TREATMENT FACILITY l' PROGRAM FOR EFFECTIVE RES[DIALS HANAGE%W (REFER TO TABLE ll) DATE SLBHITTED
| |
| ~lL ~ltr ~2K ~3A ~4G YES CI ta HN.A. DATE ltPLEPENTED U>> BACK~ POwER QXRCE Vs POLLUTION INCIDENT PREVENTION PLAN Me tltVIER OF EIVNJIVEES DATE SINVIITTED M N Ae X VES tD N A DATE [~[TED 1 1 /1 5/92
| |
| ~~
| |
| YES X. TYPE OF DISCIARGE Q Ye DO YOU HAVE A CERTIFIED OPERATOR?
| |
| D.M.FITZGERALD El~30 YES 9
| |
| CI te
| |
| ~70 ~48 0 2 ee 4 Qx ITEM As W%
| |
| RCMENGE 2 Be t4VK MAILING ADDRESS IND I ANAMI CHI GAN POWER CMP OF APPLICANT C
| |
| P BO60 STREET,AXRESS CR POST OFFICE BOX De CllY t4V% Ee STATE F>> ZIP CODE FORTWAYNE PEOulDEO Stctthrttt2E I. the dDDI[cant. cettlly under penalty ot Iav that I have personalty erdhlned and dm tdml tlat'lth the Intormatlon submitted In this dDDtlcatt, and al I attachments ano that, based on my Inoulry ot those Indlvldudts Immediately respon51ble tot obtalnlng the Intormatlon, I believe ttdt tte lhtormatlon Is true, accurate and complete. I dm dvare that there dre 5[obit[cant petldl ties 'tor 5ubmlttlng tdt5e Intotmdtloh Ihcludlflo DD55[bi I Ity ot tine dno Imprlsotvsent.
| |
| SIGNATURE OF APPLICANT SIGNATURE OF LOCAL GOVERNMENTAL REPRESENTATIVE (SEE NOTE ON REVERSE SIDE) 3 ao R4-R- C. MENGE .PRESIDENT T[TLEI 15
| |
| | |
| SEE INSTRUCTIONS ON REVERSE SIDE SECTION I RMIT
| |
| ~ I 0 ITEM A MWIC I?AL L A K E T 0 N SIHI I P 3 I QALLr Its/r~y SOURCE
| |
| : 3. SDRFiVE nATER It>>AXE NAME CF ITATERHAV L A K E IM I C H II G A N I OF .M>Tl TY;>AX.)
| |
| ~
| |
| r~>C JS/SAY WATER C~ -FIXATE nEU.
| |
| SUPPLY .MAX. ) NA I C 'LLOlJS/OAY O. CT>IER Door Fu NI A L>>tITI >Y I'AX.) GAL>>XIS/CAY
| |
| -maSS 'ATER (IIICLUOrrts CO ITACT n'ER)
| |
| ITEiVI :OOLIlJO :!jAIJTITY >MAX. ) 6 3> 4 4 0 0 OAI>ctq/n~y 4 B.
| |
| C.
| |
| 'CttCOIITACT COOL I tlG 'nATER SARI TARY '>JATER YTITY (uAX,) 2> 6 4 2 1 1 2 0 0 0 oAuotB/~y FACILITY AJAttTITY I>SAX. ) 6 0 0 0 0 CAL>>xts/BAY WATER USAGE D O TIER F I P R OTE.CT IO N WIT OUAttT TY (MAX.) 3 6 0 0 0 0 0 oALLctts/BAy
| |
| ;,~E OF SUBSTAtJCE lTEM HYDRAZINE A ueous 5
| |
| CC IJJ I
| |
| ~ PARAMETER IAPZER 0 03020 12 CUAIITITy 47o o <~ivy CRITICAL NA% OF SUBSTANCE MATERIALS SODIUM HYPOCHLORITE (12%)
| |
| PRIORITY MJ ETI I
| |
| PARA%TER tlH3ER C LASS 01 4 POLLU TANTS USED E CUANTITY 6489 4 ITS ttA"E OF SUBSTAlJCE XYLENE STORED PARA%TER tlPBER Otl 3>3 02 0 7 PRODUCED SIPUIT I TY 1 6 3 T~/YEAR REFER :~ OF SUBSTAIJCE TOLUENE TO TABLES MJ RE I
| |
| TER t>Lt%ER 0 01088,8 IVS> V <tg Ts
| |
| 'U>UITI TY 6 9 9 ~1/YEAR JlHlL'iCQE :RUE OF it>MTAIJCE LITHIUM as LITHIUM HYDROXIDE I POUNDS 2 GALLONS 3 CUBIC P~'%ac;R:AtSER C LASS 0 2 ITS QUAttt I ly YARDS IL/ve 4 TONS tt'E OF SUBSTAttcE HYDRO UINONE l>J IO PARE>E.R IAPBER I
| |
| rRUAIITI > Y
| |
| +ITS
| |
| /YEAR i""E CF SLBSTAIJCE MERCURY MJ I DARAtE TER:lt S>ER I
| |
| UN I TS LLI/YEAR 17
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| I 5T "louhTS f <<ater to oe u5ec >or var Icus ur cses 351 o"ccess Tater - see G>cssarv !Or ceflnltrcr:ace -'-).
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| SEE INSTRUCTIONS ON REVERSE SIDE SECTION I PERMIT NUMBER ~ qZ pppg827 i'TNICIPAL ITEM Ar 3 Br SURFACE rrATER ItateE r LrAra
| |
| '~'5 tra CF WATERWAY SOURCE OF alTY (tAx.)
| |
| WATER Cr PRIVATE 'rrEIL SUPPLY ITV ttrAX,)
| |
| D. DINER carr Fy OUAtaITY (t AX.)
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| A. PROCESS RATER ( ItCLUDltJG COtaACT ITEiVI NS NATER) Tv lt GAuDttS/DAv 4 3~
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| C.
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| NCttCOtaACT COOLItlG WATER SANITARY 'HATER
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| ".UAtat Tv (we.) GALIDNS/DAY FACILITY nuamt Tv (we.)
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| WATER D 0 TIER SP USAGE OUrVa TV (We.)
| |
| tlVK CF SUMTAtCE Mercuric Nitrate ITEM 5 PARAIKTER OUVallY R!%ER WITS L1J/YEAR CR IT ICA L N4% OF MATERIALS SUBSTANCE Cadmium PRIORITY PARAtETER t AMKR CL Ass 01 3 I OUANTllv Wl TS POLLUTANTS
| |
| ~1/YEAR USED NVK OF QSSTANCE Eth lene Dichloride STORED 00 107 062 PRODUCED I TY 26 ~T REFER NAtE OF QBSTANCE Chloroform TO TABLES PAPA"ETER lAtSER ppp 6766 3 IV Sr V WITS
| |
| /VEAR JLHlLiCQE tgrE OF QrMTAttCE Lead I POUNDS 2 GALLONS 3 CUBIC PAIUVETER tttteER CLSS 019 WITS OUAtallv 3 0 0 YARDS ~1 /YEAR 4 TONS tA% OF SIISTANCE Triar l Phos hate Ester EHC
| |
| * PARA %TER tlHKR CL S S 084 WITS OUANl'ITY 2 1 0 0 0 ~1/YEAR le% OF SIISTAtCE Asbestos 0 13322 14 W I 'TS 4 4 QJ/YEAR
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| *Hydraulic Fluid 17
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| SEE INSTRUCTIONS SECTION I PERMIT ~ HI 0005827 ON REVERSE SIDE ITEM A~ WNICIPAL 3 S. SURFACE HATER INTAXE
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| ~m TV I"
| |
| 'tA'B CF WLTERHAV SOURCE OF rOAt(TITY (FAX. )
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| WATER C~ PRIVATE 'nELL SUPPLY ".ttAt(TI TV (~AX. )
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| t~'6 OF S(MTANCE ITEM 0-Dichlorobenzene 5 I 000 955 01
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| * OUANTITY CRITICAL MATERIALS NA% OF SUBSTANCE Antimon Potassium Tartrate
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| @ted CC wc@
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| PARAIKTER MtBER t
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| I C L PRODUCED OUMIIITV Qt(TS M/YEAR REFER NA% OF S(BSTANCE Pol chlorinated Bi hen ls PCB TO CC TABLES ~ PARA%TER hVSER Ivav ut(Ts OUANTtTY 4 ~1/YEAR I POUNDS NAtE OF SUBSTAtCE Tri hen 1 hos hate EHC
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| * 2 GALLONS 3 CUBIC CC Ul lA CLA SSO 84 YARDS X/YEAR 4 TONS NA% OF S(BSTANCE Trix len 1 hos hate EHC
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| ~ C CLA SS08 4 OWP llY u(ITs 2 1 0 0 0 ~1/YEAR t(A% OF S(BSTAN:E Zinc I
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| PARA%TER tAPBER CLAS S0 2 7 WITS OOANTITV 27 00
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| |
| '.once;-act co(ing <<ate> - see Glossary 'cr Ceflnlticn (cage 38).
| |
| :anltarv x!ter - Aeter useo for domestic curooses( e.o., -oilet5, Sinks. )rovers.
| |
| <<ater 75 'r)t vSec far cne curoOSe ano 7-e 5(74e <<ater iS 5.3Seouent:V .Se 'Cr 5-e cr -cre 7"er :.r)CSeS. '-)(ca e "e volute
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| -<<IS accliC TIOn.
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| ITQ4 8
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| ) I I ccemical sucstances rb Ii>t Table V laaae
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| <<nice are ln ync<<l 73n
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| |
| | |
| SEE INSTRUCTIONS SECTION I PERMIT M NI 0005827 ON REVERSE SIDE I 'T E A, rrrrcrprL M
| |
| 3 Br StttFACE HA'fER INfAKE ltA% CF WATERWAY SOURCE OF (uAX ) ~DAY WATER C~ PRIVATE H'ELL SUPPLY OUAttflTv (we.)
| |
| Dr OTHER SP oUANrITY (we.) OAuDNS/DAY Ar PROCESS HATER IIIICUSIt6 COt(TACT ITEM aOLIto HATER)
| |
| CUANTITv (we. oAutm/DAY 4 B.
| |
| C~
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| |
| tFtE OF SUBSTAttCE Benzene Gasoline ITEM
| |
| : 5. 00071432 7 0 0 0 Q/YEAR CR ITICAL MATERIALS NrrPK OF SLSSTANCE Toluene Gasoline PRIORITY CL' rrr Crt PARAtETER tttSER 0 01088 83 OUANfllY UNI TS POLLUTANTS 7 0 0 0 ~1/YEAR USED NA% OF SUBSTANCE X lene Gasoline STORED PPJJtETER MtSER 0133 0 207 PRODUCED OUANTllY UNITS L1J /YEAR REFER NAPE OF SIBSTANCE TO TABLES PARt4%TER tAtSER IVBr V UNITS OUANTllY ~/YEAR NAPE OF SUBSTAttCE 1 POUNDS CC 2 GALLONS rrr Ih PARA%TER t AteER r
| |
| 3 CUBIC X UNI TS OUANTITf YARDS ~/YEAR 4 TONS NAIE OF S%STANCE rrr rO PARAMETER IAAF Z OUANfllY UNITS LJ/YEAR HAIK OF SISSTAtCE PARA%TER IAt%ER r
| |
| UN I TS OUUIfllY LJ /YEAR
| |
| | |
| ~ ~ cr=gtCTIrhIS PCR C vPLc. I~ cE . IC'I I ITEMS 5, 4, AhO 5 5 <<3 er S" pl'a ewe 3C' l V'S <<are>> Sade. C-'-iCSI -3<<e>>ials and This .'Orm reoui, orle>>l-v col lu.ants es i t ASed,
| |
| .atl n abcur ~
| |
| Stored, cr produces at -nfs 'llitv.
| |
| 5 g I a y ~
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| SnC IT Uv8ER "AM E cCU'O C'I - "" - nr v I,'W. Irgl';G 3E,'.llT. g . e5 i5 3>>ew cr not prevtcus<v cer" i ec oil i tv, -nen leave bianx ar - 3 nurcec <<I il -e assi "rec.
| |
| tCatu>>c' t<<ATEn SLppiv List sli <<ater supplies used. "e vol <<e mav pe estimated ~roy3 <<ater supplv>>e er>>eacings or 'ran piii inc S.are"ants 'ran 3 ware 5<<pl I Atlll,v. Ia water is>>. eterec, es, l>>are yrx pump apacitv. aghere 3 ns e es a%vireo, enter "3>>e " <<3 er 5ucply; uud Lake, Huron River, or the CIty ot IAII lpono.
| |
| ITEM 4 PACILITy WATER iJSAGE
| |
| 'ist amounts ot water ro be used for various purposes as:
| |
| process gfater - See Glossary for definition lpage 48).
| |
| .'lonccntact Cooling Water - See Glossary tor definition <page 48).
| |
| Sanitary Water - Water used tor dcmestic purposes; e.g., toilets, sinxs, sho ers.
| |
| f <<ater iS .IrSt uSed fcr Cne purpOSe and the Same water iS SupSeduently Sed aar Cne Cr are Other purpOSeS, indlCate the Vclu>>e er cav ot rhe Inst ce5icnarec use petore reatrent snc/og discharge. -cr Rxa>>cie, ig <<ater l5 inltlallv used as noncontact
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| ~
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| CCOlln" *ater no hen 3S ->>"CeSS ~ater, tne Suan l V Cf arer ~iVen 5"Ould be inoioated SS OrOCeSS water.
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| The total of item 4 should ecual the total of item 5. Any dlfterence in these rctals should be exp laineo in an attached sheet ot this appllcarlon.
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| ITEM 5 CRITICAL MATERIALS AWO PRIORITY POLLUTAiITS USED. TCREO. noCOUCEO
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| 'St all In MIChlgan'5 CrltlCal uaterlalS OegISter Table IV IP8ge 6) and/Or U.S. EPA'S PrlOrlty hilt tlitthi y(egeyithtare ChemiCal SubatanCeS whiCh e etiy d,e d, g a aey;hi ~ tediiity.
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| | |
| SEE INSTRUCTIONS SECTION I PERMIT
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| ~~ MI 0005827 ON REVERSE SIDE A>>:gyIDE A PRIEF DESCRIPTIQN 4<<I LINE DIAGRAM( 5+>ING lbE '<<ATER ~ 'P WMI>>( TCUR FACILlTY RCH INTAKE>>Q i NATE. -~ '.PA>>,l,'.5
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| ~iiRISUTING>>(ASic>>(AicR>> IllCU<<>>IIIG FHKESS AI<<>> FACDUCTICN AREASi 5>><<iITARY FL>>'.>>>>(5>> CQQLING 'HATER>> AND STQAATER RVCFF ~,QU <<AY SAQP TEM SINILAR CPERATICNS INTO A SINGLE UNIT>> TNE WATER BALA(iCE SHDULO QCw AVERAGE FLQWS ~ SAW ALL SIGNIFICANT QSSFS:F <<ATER ~ F>>~CQUCTS, APQSP(>>ERE>> 4(D DISCNARGE ~ YQU SNQLLJ USE AC~>> <<EAS(A(EVENTS '~NEVER AVAIlAELEI QTI>>ERNISE USE YQ(R SEST ASTI "ATE.
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| 6
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| [SEE ATTACHED DESCRIPTION]
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| DESCRIPTION ANO DIAGRAM
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| '-e. "is con~ --leo <<sve<< '5:isc-srsec -". --8 B.cv )iver. "e si.cce '<<st" -e clari "er -oes ro ! rscu ~
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| " '-8" << ere ' ?5 Ce<<ave-eo . -8 3 .Cce ' S-e<< -S.er Calcium Chloride Sulfuric Acid Lime Polymer 1 I Plating 70. 000 Wastewater Gal ion Acidification Iieutral ization 'locculation Tank Ba tCh Outtlps ~ 0ump Sludge Clarifier Non-contact Tank. nickener Cooling water Calcium Chloride yacuum Water Filter Sulfuric Acid Sludge Ifanho I e I. ime Gondola Landfill Buck Rive
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| -" .:e. '-;.. 'C-. 5leeve 383<< ":5 'Ct'u!Cr"C-Ive a<<c <<<<uc>> encineS. -"Cauc lcn IS
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| )ovoer 'cr . -8 lscct c )hase ccnsis:s sf scnering "e ~ it:e "eral oo<<cer ta<<er .Sec -" COI she Svrlc ccnssi.u)85 3 Scil t 3 881 SV Oa))ihc << 8 <<0 5 o<<tv "<< '
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| )58, 55 eatlncs 8Cei re ) ic<<81 5.t ~ 8 Sr'8C .
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| ~
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| : 33',-g 338<<sions cons)i u.es 3-e )recess <<).er.
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| Municipal Sanitary Nunicipal Water Facility Treatment Supply 30,000 gpd Stripe i.ine Cooling lfater 250.000 gpd iiaste Treatment Buck Rive 295.000 gpd Plant 45,000 gpd Powder Nfg. Plating Process 4.000 gpd 40,000 gpd 20
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| SECTION I, ITEM 6, SUBPART A OUTFALL DESCRIPTIONS Cont'd OUTFALL 001 Unit 1 Circulatin Water Dischar e Outfall 001 is a non-contact cooling water discharge. Most of the non-contact cooling water is used to condense the steam exhausting from the steam driven turbines. The condenser cooling water is drawn from Lake Michigan, screened to remove large particles entrained in the water, routed through the Unit 1 condensers and then discharged to Lake Michigan. Outfall 001 also includes Steam Generator Blowdown, Plant Heating Boiler (described later as internal Outfalls OOA, OOB and OOC respectively), and the Reverse Osmosis (RO) system (described on page 10).
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| Outfall 001 also contains the effluent flow from the Essential Service Water (ESW) system, Non-Essential Service Water (NESW) system, and monitor tank releases. ESW (20,000 GPM maximum) is Lake Michigan water that is used to provide cooling to Nuclear Regulatory Commission (NRC) defined safety-related equipment and as an emergency backup water supply. NESW (9000 GPM maximum) is also Lake Michigan water used for non-contact cooling, as a source of water for the demineralized makeup system, and to supply water for NRC defined non-safety related equipment. Monitor tank releases
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| (-20,000 gallons per event) are regulated by the NRC and consist of waste water generated within the Auxiliary Building that has been processed prior to batch discharge.
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| The non-contact cooling water for the circulating water system, the ESW system and the NESW system is .treated for biological control using liquid sodium hypochlorite, with treatments usually beginning in May and terminating in November, depending on Lake Michigan temperatures. The biocide is added at the intake forebay and the average residual measured in the discharge is maintained at less than 0.2 mg/l at Outfall 001. The treatments last for no more than 160 minutes per day. If continuous chlorination is utilized, the residual measured in the discharge is maintained at less than 0.036 mg/l at Outfall 001.
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| This same water is periodically treated using a non-oxidizing biocide to eradicate the cooling systems of zebra mussels. The biocides we are considering (Betz CT-1, Betz CT-2, Betz CT-4, Calgon H-130M, and Nalco 9210) are all polyquats which will be detoxified, as required using bentonite clay to meet water quality based effluent limits. The treatments are directed to the critical plant systems from the intake structures located about one-half mile out in Lake Michigan through the entire plant cooling system, including the ESW and NESW systems. Systems are treated dependent upon zebra mussel infestation. Concentrations and chemical feed points are chosen to minimize the amount of biocide required and to maximize the treatment program. The systems may be treated at the same time or individually to allow more efficient use of chemicals.
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| We plan to treat all systems within the plant a maximum of twice per year (six applications per year total) to assure safe operation of the nuclear generating units.
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| The current NPDES permit includes the use of sodium bromide and sodium hypochlorite solutions for treatment of the circulating water systems. These solutions, which are the major constituents of many proprietary mixtures such as Nalco Acti-Brom, are presently being considered as the basis of the Cook Nuclear Plant's strategic plan to control zebra mussels. Effective use of these oxidizing biocides are expected to reduce the frequency of non-oxidizing biocide treatments. See Attachment 3 of the cover letter for more details regarding our future zebra mussel control strategy.
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| The monitor tanks receive treated water from the radioactive waste removal system. One system handles the waste for Units 1 and 2 and the Auxiliary Building. This system treats wastes generated from the reactor coolant pump seal leakoffs, the refueling cavity water, equipment leaks, floor drains, valve stem leakoffs, waste sample solutions and laboratory wastes from the radiochemistry analysis in the hot chemical laboratory, system equipment drains, non-contact cooling water and decontamination processes. The wastes are collected in one of several tanks and treated when enough water is collected. The treatment utilizes either an evaporator system or a demineralizer system to remove radioactive contaminants.
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| The treated water is accumulated in the monitor tanks and sampled to ensure the waste meets the Nuclear Regulatory Commission radiological requirements prior to being discharged into the circulating water system.
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| Periodically, due to equipment leaks and/or system upsets, a waste stream is generated that contains radioactively contaminated ethylene glycol and water. This water is processed on-site prior to being released to Outfalls 001, 002 or 003.
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| Sulfur hexafluoride gas (SF6) is utilized in the non.-contact cooling water systems at the plant to detect leaks in various components such as the condensers. The gas is injected in the cooling water stream and discharged to Outfalls 001, 002 or 003 at less than 54 ul/L.
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| During upset conditions it is possible to overflow the contents of the Turbine Room Sump (see Outfall OOD) to Outfalls 001, 002 and/or 003 if the flow path to the on-site absorption pond cannot be used.
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| 0 t n W ter 'sc ar e Outfall 002 is a non-contact cooling water discharge. Most of the non-contact cooling water is used to condense the steam exhausting from the steam driven turbines. The condenser cooling water is drawn from Lake Michigan, screened to remove large particles entrained in the water, routed through the Unit 2 condensers and then discharged to Lake Michigan. Outfall 002 also includes Steam Generator Blowdown, Plant Heating Boiler (described later as internal Outfalls OOA, OOB and 00C respectively), and the Reverse Osmosis (RO) system (described on page .10).
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| Outfall 002 also contains the effluent flow from the Essential Service Water (ESW) system, Non-Essential Service Water (NESW) system, and monitor tank releases. ESW (20,000 GPM maximum) is Lake Michigan water that is used to provide cooling to Nuclear Regulatory Commission (NRC) defined safety-related equipment and as an emergency backup water supply.
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| NESW (9000 GPM maximum) is also Lake Michigan water used for non-contact cooling, as a source of water for the demineralized makeup system, and to supply water for NRC defined non-safety related equipment. Monitor tank releases (-20,000 gallons per event) are regulated by the NRC and consist of waste water generated within the Auxiliary Building that has been processed prior to the batch discharge.
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| The non-contact cooling water for the circulating water system, the ESW system and the NESW system is treated for biological control using liquid sodium hypochlorite, with treatments usually beginning in May and terminating in November, depending on Lake Michigan temperatures. The biocide is added at the intake forebay and the average residual measured in the discharge is maintained at less than 0.2 mg/l at Outfall 002. The treatments last for no more than 160 minutes per day. If continuous chlorination is utilized, the residual measured in the discharge is maintained at less than 0.036 mg/l at Outfall 002.
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| This same water is periodically treated using a non-oxidizing biocide to eradicate the cooling systems of zebra mussels. The biocides we are considering (Betz CT-1, Betz CT-2, Betz CT-4, Calgon H-130M, and Nalco 9210) are all polyquats which will be detoxified as required, using bentonite clay to meet water quality based effluent limits. The treatments are directed to the critical systems from the intake structures located about one-half mile out in Lake Michigan through the entire plant cooling system, including the ESW and NESW systems. Systems are treated dependent upon zebra mussel infestation. Concentrations and chemical feed points are chosen to minimize the amount of biocide required and to maximize the treatment program. The systems may be treated at the same time or individually to allow more efficient use of chemicals. We plan to treat all systems within the plant a maximum of twice per year (six applications per year total) to assure safe operation of the nuclear generating units.
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| The current NPDES permit includes the use of sodium bromide and sodium hypochlorite solutions for treatment of the circulating water systems.
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| These solutions, which are the major constituents of many proprietary mixtures such as Nalco Acti-Brom, are presently being considered as the basis of the Cook Nuclear Plant's strategic plan to control zebra mussels. Effective use of these ~xidizing biocides are expected to reduce the frequency of non-oxidizing biocide treatments. See Attachment 3 of the cover letter for more details regarding our future zebra mussel control strategy.
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| The monitor tanks receive treated water from the radioactive waste removal system. One system handles the waste for Units 1 and 2 and the Auxiliary Building. This system treats wastes generated from the reactor coolant pump seal leakoffs, the refueling cavity water, equipment leaks, floor drains, valve stem leakoffs, waste sample solutions and laboratory wastes from the radiochemistry analysis in the hot chemical laboratory, system equipment drains, non-contact cooling water and decontamination processes. The waste is
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| 'collected in one of several tanks and treated when enough water is collected. The treatment utilizes either an evaporator system or a demineralizer system to remove radioactive contaminants. The treated water is accumulated in the monitor tanks and sampled to ensure the waste meets the Nuclear Regulatory Commission radiological requirements prior to being discharged into the circulating water system.
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| Periodically, due to equipment leaks and/or system upsets, a waste stream is generated that contains radioactively contaminated ethylene glycol and water. This water is processed on-site prior to being released to Outfalls 001, 002 or 003.
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| ~
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| Sulfur hexafluoride gas (SF6) is utilized in the non-contact cooling water systems at the plant to detect leaks in various components such as the condensers. The gas is injected in the cooling water stream and discharged to Outfalls 001, 002 or 003 at less than 54 ul/L.
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| During upset conditions it is possible to overflow the contents of the Turbine Room Sump (see Outfall OOD) to Outfalls 001, 002 and/or 003 if the flow path to the on-site absorption pond cannot be used.
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| OUTFALL 003 Deicin Dischar e Outfall 003 is a deicing discharge which is used on a limited basis. A portion of the flow from Outfall 001 and /or Outfall 002 is directed through the center intake tunnel to temper the intake water and prevent ice buildup on the intake structures which would restrict intake flow.
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| Use of this discharge is generally only required during the period from December through April depending on water temperatures and ice buildup along the shores of Lake Michigan. The chemical constituent of Outfall 003 is the same as Outfalls 001 and 002.
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| OUTFALL OOA Unit 1 Steam Generator Blowdown The steam generators require ultra high purity water for operation.
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| Makeup water used in the steam generators is withdrawn from the intake forebay (or from Lake Township water supply) and essentially all natural impurities are removed through sedimentation, filtration, reverse osmosis, and demineralization. Periodically, impurities enter the steam generators through system corrosion transport mechanisms, the makeup water, or system upsets (such as condenser leakage) and must be removed to protect the steam turbines and heat transfer surfaces of the steam generators. The impurities are removed by draining a portion of the water from. the steam generators.
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| In the steam generator, steam is separated from the water, further heated, and then routed to the turbines. When the steam separates from the water, the impurities remain in the water, concentrating in the steam generator. Blowdown consists of two forms, a liquid portion (700 GPM maximum) and a wet steam portion which is exhausted to the atmosphere. The liquid portion of the steam generator blowdown is discharged to the screenhouse forebay either directly, or after processing through mixed bed demineralizers.
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| Impurities in this discharge may consist of insoluble iron and copper and at times, impurities from the cooling water (Lake Michigan) used to cool the condensers.
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| Steam generator additives consist of ammonia and/or monoethanolamine (ETA) for pH adjustment, hydrazine and/or carbohydrazide for oxygen scavenging, and boric acid for corrosion protection. .Periodically, sodium nitrite is used as a tracer to determine the steam generator blowdown rate through each of its blowdown valves.
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| During unit outages, the steam generators are stored full of water, including treatment chemicals, to protect against corrosion during storage. This layup water is intermittently discharged (32,000 gallons per steam generator) through Outfall OOA to Lake Michigan.
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| The layup water contains a maximum .concentration of 400 ppm hydrazine and/or 40 ppm carbohydrazide, 50 ppm ammonia and/or ETA, and 20 ppm boron. The waste strength of this discharge is reduced through mixing with Outfalls 001, 002 or 003 by more than 40,000 times.
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| Demineralized water or secondary water is used to pressure clean the steam generators during outage periods. The water is recirculated through temporary filters to remove suspended solids.
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| The major constituent of the suspended solids is iron oxide from the steam generators. The water is then returned to the steam generators and drained to Outfalls OOA, OOB, or OOD via the turbine room sump.
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| OUTFALL OOB Unit 2 Steam Generator Blowdown The steam generators require ultra high purity water for operation.
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| Makeup water used in the steam generators is withdrawn from the intake forebay (or from Lake Township water supply) and essentially all natural impurities are removed through sedimentation, filtration, reverse osmosis, and demineralization. Periodically, impurities enter the steam generators through system corrosion transport mechanisms, the makeup water, or system upsets (such as condenser leakage) and must be removed to protect the steam turbines and heat transfer surfaces of the steam generators. The impurities are removed by draining a portion of the water from the steam generator.
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| In the steam generator steam is separated .from the water, is further heated and then routed to the turbines. When the steam separates from the water, the impurities remain in the water, concentrating in the steam generator. Blowdown consists of two forms, a liquid portion (700 GPM maximum) and a wet steam portion which is exhausted to the atmosphere. The liquid portion of the steam generator blowdown is discharged to the screenhouse forebay either directly, or after processing through mixed bed demineralizers.
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| Impurities in this discharge may consist of insoluble iron and copper and at times, impurities from the cooling water (Lake Michigan) used to cool the condenser. Steam generator additives consist of ammonia and/or monoethanolamine (ETA) for pH adjustment, and hydrazine and/or carbohydrazide for oxygen scavenging.
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| Periodically, sodium nitrite is used as a tracer to determine the steam generator blowdown rate through each of its blowdown valves.
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| During unit outages, the steam generators are stored full of water, including treatment chemicals, to protect against corrosion during storage. The layup water is intermittently discharged (32,000 gallons per steam generator) through Outfall OOB to Lake Michigan.
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| The layup water contains a maximum concentration of 400 ppm hydrazine and/or 40 ppm carbohydrazide, and 50 ppm ammonia and/or ETA. The waste strength of this discharge is reduced through mixing with Outfalls 001, 002 or 003 by more than 40,000 times.
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| Demineralized water or secondary water is used to pressure clean the steam generators during outage periods. The water is recirculated through temporary filters to remove suspended solids.
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| The major constituent of the suspended solids is iron oxide from the steam generators. The water is then returned to the steam generators and drained to Outfalls OOA, OOB, or OOD via the turbine room sump.
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| OUTFALL OOC Plant Heatin Boiler A heating boiler (150,000 lb/hr capacity) operates to supply plant heating and auxiliary steam when Unit 1 and/or Unit 2 steam generators are out of service.
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| 'The boiler is also fired approximately once per month for testing purposes to ensure its availability.
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| Impurities from the boiler water consisting primarily of insoluble iron and copper, are discharged (30 GPM maximum) to the intake forebay. Boiler water treatment additives consist of ammonia and/or ETA for pH adjustment and hydrazine and/or carbohydrazide for oxygen scavenging. (See Outfall OOD for wet layup drains)
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| OUTFALL OOD Utilit Waste Waters Utility waste water from within the plant is discharged via the turbine room sump (TRS) into an on-site absorption pond. The ultimate disposition of these waste waters is to the ground which vents to Lake Michigan. The waste waters include:
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| Wastes from the makeup water treatment system. The main contributors to the waste stream are: the makeup plant demineralizer regeneration wastes (average 40,000 gallons per regeneration), degasifier pump seal water (108,000 GPD),
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| carbon filter backwash water (average 45,000 GPD) and pre-filter backwash water (average 72,000 GPD). The retention tank periodically discharges a very small volume of solid material removed by settling. Alum (aluminum sulfate) is added to the pre-filter influent as a flocculent.
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| These pre-filters are backwashed to the TRS to remove the suspended matter captured on the filter media. The alum contained in the backwash is discharged to the TRS in the form of insoluble aluminum hydroxide. Carbon filters are also periodically backwashed to the TRS. These filters primarily remove organics, chlorine and small amounts of iron. Sulfuric acid and sodium hydroxide used by the makeup demineralizers to regenerate the resin, are rinsed to the TRS and generally neutralize each other in the sump to form sodium sulfate prior to discharge. Non-essential service water is used to supply vacuum degasifier pumps which utilize approximately 75 gpm total via two pumps to remove dissolved gases (primarily carbon dioxide and oxygen) from the vacuum degasifier and exhaust them to the atmosphere.
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| A new component of the makeup plant, a reverse osmosis (RO) system, has been installed to remove the bulk of the dissolved solids from the lake water prior to demineralization. Normal reject water flow is to Lake Michigan. The RO system must maintain very clean membranes to assure efficient operation and purity of water. Several methods are used to maintain this level of cleanliness from scale and biofouling. Using hydrochloric acid or sulfuric acid, the feed water pH is lowered to reduce the scaling tendencies of the water.
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| Approximately once per month, a flush is performed using approximately 0.5% hydrochloric acid and caustic to dissolve any scale that deposits on the membranes (average 5000 gallons per month). Chemical cleaning is performed when the above flushes are no longer are effective.
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| The chemical cleaning involves several steps and may contain citric acid, hydrochloric acid, phosphoric acid, sodium hydroxide and a neutral pH detergent (average 10,000 gallons per event). Also, to remove dead biological matter from the membranes, a soak using sodium bisulfite may be performed approximately once per year (average 5000 gallons per event).
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| During periods when not in operation, the heating boiler is stored full of treated boiler water containing at most 400 ppm hydrazine or 40 ppm carbohydrazide for oxygen scavenging and 50 ppm ammonia or 50 ppm ethanolamine (ETA) (for corrosion protection). Prior to use, this "wet lay-up" water is drained to the TRS for discharge into the absorption pond. The volume drained is approximately 1600 gallons and may occur 30 times per year.
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| n During a unit outage, the condensers are checked for leaks by filling the steam side with condensate containing approximately 1000 grams of fluorescein disodium salt or Rhodamine B. These dyes, which are fluorescent under black light, aid in the detection of joint and tube leaks during visual inspection. The volume of water drained from the condensers ranges from 160,000 up to 1,000,000 gallons and may occur one time per year.
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| e 10
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| Zn addition, the cooling water side of the condensers are periodically drained to the TRS for general maintenance periodically (8 condenser halves per unit, approximately 25,000 gallons of lake water per half).
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| The component cooling water system (CCW) is periodically drained to allow for equipment inspection, maintenance or repair. This system uses demineralized water from the makeup plant as its source of makeup water along with a maximum of 1200 ppm nitrite (from Calgon LCS 60) and 100 ppm glutaraldehyde as treatment chemicals.. The infrequent drainings release approximately 60,000 gallons of treated water to the TRS per year.
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| The diesel generator cooling jacket water system (DJW) employs the same chemical control for corrosion as in the component cooling water system with a maximum of 2000 ppm nitrites from Calgon LCS 60.
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| This system is drained through the floor drains to the TRS when maintenance is performed. The system volume is approximately 1000 gallons. Any minor system leaks would also be directed to the floor drain during normal operations.
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| The essential service water systems (ESW) and non-essential service water systems (NESW) are also periodically drained to allow for equipment inspection, maintenance, or repair. These drains may discharge approximately 72,000 gallons of Lake Michigan water used for non-contact cooling into the TRS.
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| This water is either chlorinated intermittently at a residual concentration of 0.2 mg/1 TRC or continuously at 0.036 mg/l TRC. During some special treatment periods, this water may contain zebra mussel biocides, used as a molluscicide for zebra mussel control. Periodically, components of the ESW or NESW systems may be chemically cleaned to remove iron deposits using vendor supplied cleaning solution such as EDTA (ethylenediaminetetraacetic acid) or ascorbic acid, acetic acid and ammonia. These wastes could either be drained to the TRS or Lake Michigan.
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| 11
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| The steam generators (S/G) are drained for inspection and maintenance during scheduled unit outages (approximately every 18 months) and during an event where steam generator failure is detected that requires a unit shutdown. The steam generators utilize 150 ppb hydrazine (from either direct hydrazine feed or as a breakdown product of carbohydrazide),
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| 20 ppm ammonia, and 2.5 ppm ETA to control the water and steam chemistry to be non-.aggressive to cycle components. Unit 1 steam generators also utilize 10 ppm boron to control corrosion. A steam generator volume released during the draining is approximately 32,000 gallons each.
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| During wet lay-up, the S/Gs are stored full of water with up to 400 ppm of hydrazine or 40 ppm carbohydrazide and 50 ppm ammonia or ETA are added for corrosion control. This water is normally drained to surface water via NPDES Outfalls OOA or OOB, but may be drained to the TRS in some instances.
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| The miscellaneous drain tanks can be aligned to discharge to the TRS. As much as 350,000 gallons per day may be directed to the TRS to control the chemistry limitations on the secondary water systems. Water chemistry is primarily the same as in the steam generators.
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| Around the plant, miscellaneous sumps collect approximately 45,000 GPD of water from various equipment drains, leaks, pump seals, and steam jet air ejector drains. The frequency of discharge and types of chemicals used in this equipment have been described elsewhere in this description.
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| Mi.scellanoous floor drains are located throughout the plant to provide a safe working environment by routing spilled or leaked water to the TRS. The major chemical influx into these drains are from the detergents and waxes used to maintain the floors. Also routed to the TRS through the floor drains are the chemical feed tank drains, fire protection water, drinking water, cooling water, and drains from bioboxes used to monitor the zebra mussel control measures and other chemical control monitors. The chemical feed tanks which may be drained contain hydrazine, ammonia, boron, ETA, carbohydrazide, and sodium hypochlorite. The bioboxes will discharge chlorine and zebra mussel biocides during treatments.
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| 12
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| Non-ra4iological chemical lab sink and floor drains are routed to the TRS for disposal. The drains carry water and the wastes generated while performing analyses and preparing laboratory standards including those on the attached list.
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| Also discharged will be glassware and normal laboratory cleaning wastes. The average volume directed to the TRS is estimated to be 500-1000 GPD.
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| 8econdary (steam generator or condensate) sample water from continuous analyzers are routed to drains which discharge to the TRS and the miscellaneous drain tank. The analyzers are on the cycles which may contain as much as 10 ppm boron, 150 ppb hydrazine (from either a direct feed or as a breakdown product of carbohydrazide), 20 ppm ammonia, 'nd 2.5 ppm ethanolamine. The analyzers measure corrosion transport at a average flow of 8500 gallons per day.
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| Mi.scellaneous sealing an4 cooling water supplies cooling and sealing water to the TRS pumps, condensate booster pumps, circulating water pumps, vacuum priming pumps, drain seal reservoir tanks and drain sample coolers. The average flow per day is approximately 150,000 gallons.
| |
| Non-essential service water supplies approximately 53,000 GPD of non-contact cooling water to various sample coolers throughout the plant's turbine building including the conductivity room and the steam jet air ejector sample points.
| |
| Chemical spills that enter the TRS may be neutralized within the sump 'to prevent a discharge to the environment. The potential for spills to the TRS exists for the following chemicals with the proposed neutralizers listed:
| |
| ~Ce ~ica Neutralizer Sulfuric acid Sodium hydroxide Sodium hydroxide Sulfuric acid Sodium hypochlorite Sodium thiosulfate Hydrazine NESW (lake water), Hydrogen peroxide Ethylene glycol 13
| |
| | |
| OUTFALL OOE Sanitar Waste Dischar es Sanitary wastes are presently segregated and routed to two extended aeration package treatment plants. The existing equipment is designed to treat 50,000 GPD and the effluent from the sewage treatment plants discharge into one of the two seepage lagoons.
| |
| The lagoons discharge into the groundwater with the ultimate disposition being Lake Michigan. The sludge removed from the sedimentation tank basins is taken to a local POTW (public owned treatment works) for disposal or dewatered and stored as low level radioactive waste, as appropriate.
| |
| 1 Plant sanitary waste consists of shower and rest room facilities, and janitor washbasins located throughout the Plant's non-radiological property. Kitchen wastes are generated from the plant cafeteria, the Cook Energy Xnformation Center and Training buildings.
| |
| The chemistry training laboratory discharges to the sewage treatment plants through a limestone bed neutralization tank. The chemistry lab is used to train technicians on analyses performed in the plant. The discharge from the lab carries water and wastes generated while performing analyses and preparing laboratory standards including those on the attached list. A small photo lab, in the training building, uses (on a emergency basis) small quantities of hydroquinone'o develop black and white pictures for plant use.
| |
| The training building HVAC system also drains to the limestone bed.
| |
| A radiography lab in the plant also discharges small quantities of processing chemicals for non-destructive testing in the plant.
| |
| None of the radiography .products contain critical materials or priority pollutants.
| |
| All portable toilet wastes on the plant site are collected and discharged to the package plants. A biodegradable deodorant is used in the portable toilets. Sludge effluent waste may also be recycled through the plants to decrease the amount of sludge for processing when possible.
| |
| Miscellaneous rinsing of waste receptacles and possible cleaning operations waste, utilizing various detergents, may be rinsed to the sewage treatment plants.
| |
| 14
| |
| | |
| Miscellaneous Outfalls The main plant transformers on each unit are located within concrete berms. The berms are for spill containment should a~ catastrophic failure of a transformer occur. To protect against operational and safety concerns which stem from ponded water, these 'areas gravity drain to oil/water separators specific for each unit. Each separator is a below ground concrete basin designed to retain oil and release water to a series of drywells. Also discharging into the separators, are the emergency diesel generator pit sumps. These sumps collect limited water and fuel oil (less than 500 gallons per year) from the emergency diesel generator room. Periodically, the oil/water separators are pumped clean to remove the accumulated oil for proper off-site disposal.
| |
| The security diesel generator day tank has an overflow line that connects to the Unit One transformer deck catchbasin. Discharge to the
| |
| ~
| |
| catchbasin would only occur if the day tank were overfilled. Procedures and level indicators are used to prevent overfilling.
| |
| 15
| |
| | |
| CHEMICAL LAB ANALYSIS Additional Information Section I Item 6, Subpart A Cook Nuclear Plant Surface Water Permit Application PLANT CHEMISTRY LAB (to Outfall OOD)
| |
| Chloride ASTM D-512-81 (1986)
| |
| Fluoride ASTM D-1179-80 (1986)
| |
| Standard Methods 413 B (1985)
| |
| Hardness ASTM D-1126-80 EPA-600-4-79-020 Method 130.2 (1979)
| |
| Hydrazine ASTM D-1385 (1983)
| |
| Silica ASTM D Power Water Analysis Manual CH-41 Oil 6 Grease EPA-600-4-79-020 Method 413.1 (1979) pH ASTM D-1293-84 Standard Methods 423 (1985)
| |
| Free Mineral Acidity ASTM D-1067-82 Method B Total Phosphorus EPA-600-4-79-020 Method 365.3 (1979)
| |
| Chemical Oxygen Demand EPA-600-4-79-020 Method 410.2 (1979)
| |
| Sulfate ASTM D-516-82 Method A (1985)
| |
| EPA-600-4"79-020 Method 375.3 (1979)
| |
| Standard Methods 426 A (1980)
| |
| Nitrites Determination of Corrosion Inhibition by Calgon Corporation Total Residual Chlorine ASTM D-1253 (1986)
| |
| Standard Methods (1980)
| |
| TRAINING BUILDING LAB (to Outfall OOE)
| |
| Boron Westinghouse Chemical Analysis Procedure for PWR WCAD 7333 Rev. 1 (1973)
| |
| Chloride ASTM D-512-81 (1986)
| |
| Fluoride ASTM D-1179-80 (1986)
| |
| Standard Methods 413 B (1985)
| |
| Hardness ASTM D-1126-80 EPA-600-4-79-020 Method 130.2 (1979)
| |
| Hydrazine ASTM D-1385 (1983)
| |
| Silica ASTM Power Water Analysis Manual CH-41 Oil 6 Grease EPA-600-4-79-020 Method 413.1 (1979) pH ASTM D-1293-84 Standard Methods 423 (1985)
| |
| Total Phosphorus EPA-600-4-79-020 Method 365.3 (1979)
| |
| Atomic Absorption Metals Standard Methods 302B, 303A (1985)
| |
| EPA-600-4-79-020 Method 215 1, 220.1, F
| |
| 242 1~ 249 1g 273 ' (1979)
| |
| Ion Chromatography Dionex System Operators Manual
| |
| | |
| SEE INSTRUCTIONS SECTlON I PERMIT NUMBER ~ iII 00058 27 QN REVERSE SIOE
| |
| ' ' C''N ~ll4,.""E =RA i'c'P.".:"i 'H-
| |
| ~EM coVI"E A
| |
| "( AE'tE~SE sa E F
| |
| C~
| |
| rE ~cA~i.
| |
| c<E.
| |
| ElP =' ' idi "F ccE IEGiAIKE?QIIIT(3) "G =
| |
| 7 LOCATION [SEE ATTACHED DRAWING]
| |
| MAP 21
| |
| | |
| 4
| |
| ~ I I
| |
| ~ ~
| |
| 4 ~5 I~ ~ '
| |
| 4 4 ~ 4 '
| |
| 3 I3 ) ~ ~ '4 si) 1 s s J 4 ~ JI ' y 4
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| )" ~ ~ ") 0 5 s 5) ) ~ ~ ~3 QI'J ~ ) 4 ~ sA V 44
| |
| ) C s 3 ~ ] y ) ) s 4 s ~ 4 4 I S ~ ss))I s ) 44
| |
| +I JP )4 4 ~ f ps H \ 4 4 0 y ' Cs4 ' 8 ' 5 4$ 5 ~4 )44)
| |
| | |
| SECTION I PERMIT NUMBER SEE INSTRUCTIONS ON REVERSE SIOE A, DQ YCU OPERAic A CQt~~TB>>'<<."Al, FEl IttG FACII.IIY? (IF NQ tCCtCiltAtE TG I,-ts J~))
| |
| -EM 8 B~ MISER OF ACRES USED FOR CQttFINBENT FEDltG? NA 'tES C~ sF ittRE IS OPEN 0)NFIM'TNT> rerS A erlrCFF DIVERSICN AIQ CONCEN OQNIRQL SYSi~l BEEN CONS'si>K? (IF tO, CCttiltAIE TQ I icP1 '3) NA YES NO TR ATE 0 ANIMAL D '~T ONE CF IS BE DESIGN BASIS FQR l% C"NTROL SYSTEN? CIECK BE FQLI WING AIID ENTER:AIBER OF IttCIES OF RAIN?
| |
| 10 ~, 2II HrxR sTDFN ItrCtE3 FEEDING OPERATION TYPE E. ~T I I IS IHE MPSKR OF ACRES CF r"4IRIBUTltrG KAItQGE?
| |
| NA 25 YEAR. 2II tOR OBKR (SPECIFY)
| |
| STCRN
| |
| ~ ~~eeftES
| |
| ~
| |
| ~
| |
| INCHES INCHES Fs >trAT IS IHE DESIGtr SAFER FACTS'R THIS Ce>IIIRGL SYSisH NA A, I.!ST 'SSE OF ANIHALS NA llr ITEM 4 I
| |
| 3~ GIVE IHE MPBKR GF THIS T~K OF>>4lt>AL IN CPBI CONF I trK)ENT.
| |
| 9 C. GIVE IHE MPSER CF THIS CONF I teENT.
| |
| ~ >PE OF Alii<<AL l>4 HQU'ED Ae LIST TYPE OF ANIIVlLS TYPE lit 4r4 3~ GIVE ~EE "ASSER OF THIS, '~ OF Attl."AL I:I CPE4 GCttFIN9%NTE NUMBER I OF
| |
| . ~ GIVE &E tlPKR QF >sIS '-K t F 4'IINL ltl HCUSED rQNF I 4T.
| |
| ANIMALS Ae LIST TTPE CF ANIS4ALS IN llr 3~ GIVE Mt%9 =3 QF>>SINAL It: QP.'I OPEN 4n TE E INK)SP.
| |
| OF TEEIS AND I C GIVE BE MtSKR OF 'IHIS > APE OF ANIMAL Itr tOUSED HOUSEO XNF MKBf e IFINEMENT A. LIST TYPE OF ANItVlLS 4 3. GIVE THE WBKR OF THIS T>~ OF ANIHAL ltt OPEN 0>NF I%ANTE I
| |
| E E IAPBER QF TEEIS =K QF ANI'QL'lr ~KD r
| |
| A~ LIST '>>PE QF ANIHAL. ~ ~
| |
| : 3. GIVE EHE USER GF IS>IS +E CF ANIHAL ~ W OPEN "QrF I>CW>IT.
| |
| GIVE BEE tAPSKR CF THIS .YPE OF ANIMAL Itr HOUSED Q)tF I N Ae 'ST TYPE OF AtrIHALS I l I l
| |
| : 3. GIVE TrE MISER QF THIS ~ (=E QF ANIHAL Ite <<PEN COIF IhK%NT~
| |
| C, GIVE IEE NW3ER OF THIS ~ IPE OF ANIHAL lrr HXISED rQtr Ireen.
| |
| A. LIST iYPE OF ANINALS 3~ GIVE BE NW3ER OF BIIS s rPE OF ANIr>AL IN OPEN C. GIVE THE MHKR OF BIIS e >~E OF ANP'AL IW HOUSED CAF IIEHENT>
| |
| Ae LIST TYPE OF ANIMALS GIVE BSE MICR QF ee>IS,=E QF ANIS>AL Iti GPK4 MF I'SK"Beti C, GIVE TEEE MPSIER GF THIS ~ C<<E GF A4IHAL Itr tOISK CAF I t6%NT'e 23
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| | |
| Iin ' t ~
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| u5 3 )hD g 4"vlf'Bs,hfc, 3>>l n ))cut "8 0854 h, 5' ~
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| :S '5 ) -8<<cr "-. BvI uSlV 8 <I 80 '30 I 4, - Bn 4)se )fan>> 310 3 hfisber .<<Ill be assigned ~
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| ~ i ), 4<<ei>> Aer) f rs sre iabuj ter I- 'lo"KB "er114). =xclusicrs )re Aasec cn si:e ahc bceuf-thee cf 3:sc1ar-e.
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| :.,)r, 4:f ) '-3< 4840<-0 lber)tlcns, >>he sl:8 0;tc '5:ebehc ~
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| cn <<he-rer ct "ot )offutants are Cisc1aried =rrbuc1 )
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| ) ~ 4 ~ 4 r 4 s 8 ) < ~ )r )nl-a<$ . 'sc'll t 'cr l)viho -enS br .tel ters ls -0 Bcu'0 -. )ve sSB W Bai -'- r )--- Bfeh- ~ fe ""- -8" )free Ar cch;I-ucus cvorf<cw <<ate<<AC.
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| A)r$ 85 <<CKS
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| ~ I r<<i .- OSS "4 4)C! I:-Y .)5 ) Icui>> shura hanoi inc Svst<rh Cr Continuous overflCw <<atering
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| ) . )r )0 \ V Bt "3" 3" siuatl ahiial )rcCCC) 01 ~ )Ci '. ~ ty) <<bere>>'le fbi I wing CCOCI<<iCn5 re 8 ital Bi )3 31i 3<5 )Ye BBA, )re, <<I < a)<80 br 1f <<80 310 80 r "lalntalnec for )t)l
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| <)4
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| | |
| SEE INSTRUCTIONS SECTION I PERMIT NUMBER ~ ZZ pppg827 ON REVERSE SIDE DC M CFc=<<:sc AN ACUATtC
| |
| ~ ZltMAL PROCUCTI tt FACILI~<<
| |
| ilF tO lesilAK TO: 2I X
| |
| AO VATIC ANIMAL PROOUTION B.
| |
| CD DesstCATE 3>>s>>UCT>>DES
| |
| :pcripv It>>DICA<<c '~
| |
| .=E .OTAL tAlIER CF PDtCS<<RACEWAYS A'>>D
| |
| '7 (CUI FACILITY.
| |
| >>>>WICH CALBBAR tCNik, AXI<<tlI FEEDI,'IG OCCURS SIMIM NA NA
| |
| ~ . see<<sess FACILITY
| |
| ~?
| |
| BPi<<R i<<E TOTAL MPSER OF POtl<<DS CF . OOD . ED DlRtttG TrllS A. IS THIS 3PECIE A scUIM CR CCLD WATER SPECIE?
| |
| NA lTEM Bi C.
| |
| GIVE >>>>E NAME CF 1HIS SPECIE.
| |
| ENTER TrE TOTAL HARVESTABLE WEIGHT OF THIS SPECIE
| |
| ~ BY THIS FACIL.'TY PER YEAR IN PCLhDS ~
| |
| D BITER T.-E MAX!MLS WEIGHT PRESENT FOR THIS SPECIE sttICH
| |
| '<<CULD RE. RESENT YtXR KRMAL OPERATION<< I I SPECIES iS ani3 SPECIE A 'ASM CR C LD ssAIER SPECIE.
| |
| OF AQUATIC B. 3IVE .rE NtME OF THIS SPECIE>>
| |
| ANIMALS PROOUCEO C~ ENTER HE TOTAL HAIIVESTABLE WEIGHT CF TrtlS SPECIE PcCDUCED BY THtS FACILITY PER YEAR IN POtl4)S.
| |
| AT THIS FAG I LIT Y D Biicc E st<<AXIPV1 WEIGHT PRESBIT FOR IHIS SPECIE WHICH OIA" cEPRESENT YEA tCRMAL CPBIATIOtt
| |
| :S Tssi3 SPECIE A WARM CR COLD WATER SPECIE?
| |
| HcRM B~ 'zi'>>E 'PFE CF THIS SPECiE ~ s ~
| |
| C~ EIIIER ~E TOTAL HARVESTABLE s>>EIGrIT CF iest3 SPE>> >>E
| |
| <<3Y TH FAC TY P R Y N A
| |
| D.
| |
| ~
| |
| BIIF ..s E AX!NitWEIGHT PcESENT FOR THIS SPECIE WHICH
| |
| ~
| |
| cEPRESENT YCUI MRMAL CPERA'TICN.
| |
| IS >>HIS SPECIE A >>08M CR COLD WATER SPECIE. cess B. GIVE =E IA'E OF IHIS 3PcCIE.
| |
| c'<<TEc ~E TOTAL HARVESTABI c wEIGHT OF THIS SPEC:-
| |
| ccOCUCE ~
| |
| BY DilS FACILI Y >ER 'EAR IN PCIl>>DS.
| |
| "~ ='>>T= =E MAXIMWEIGHT -,ESB>>T =CR IRIS SPEC:E itttCH
| |
| ~'4 cEcRESBiT YOUR tsCRe'AL SocoATICN, I i I DOlg@S rt3 SPECIE A 'RM OR COLD stATER SPECIE.
| |
| B..i>>E =E LIAME OF THIS SPECIE>>
| |
| ' !~ OTAL MARVESTABLE *EI5'T DF THIS ircC; ccGC~ - BY er'.IS ACILITv >cEP <<BB Irt cCQQS
| |
| ~
| |
| ='iTER <<< MAXIMcH l>>EIGrIT PRESENT FOR THIS SPECIE MICH
| |
| '="RESENT YON l4ÃMAL CERATION>>
| |
| As ~:3 s".'3 SPECIE
| |
| * WARM CR COLD WATER SPECSE.
| |
| 3~ st<<K scE NAt% OF THIS SPECIE<<
| |
| c.'sicR '?E TOTAL <<IARVESTABLE WEIGHT OF THIS SPECIE ccCCUC D BY TH I S FACILITY PER YEAR I N Kc lCIS ~
| |
| D. E.'ii-R =c MAXIMWEIGHT PRESEtiT FOR THIS 3PEC>>E +ICH tAA c=cCESENT YOIR N?RMAL GPBIATION.
| |
| 27
| |
| | |
| ~ ~ ~ ~ >>0(>> ~ ~ ~ >>
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| | |
| SECTION I NUMBER ~~
| |
| LIST NA"4 A,'6,"/tILIMADNESS Ci ALL =~PPT/ ~'.EBS AL,~sT,O .W -V I~SNT iÃlL:~s "8 CR DISCS*%w/DISP"iSAL '>~,
| |
| [SEE ATTACHED LIST]
| |
| MAILING LIST OF ADJACENT PROPERTY OWNERS
| |
| | |
| MI0005827 Section I, Item 12 ADJACENT PROPERTY OWNERS EAST Interstate I-94 (Michigan Dept. of State Highways)
| |
| SOUTH Lake Township c/o Gerald Wasko Township Supervisor 1410 Shawnee Road Bridgman, MI 49106 WEST Lake Michigan (State of Michigan and United States of America)
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| NORTH Rosemary Beach 11-11-6800 0038-00-5 Tengerstrom, Eric H.; 3415 S. 59th; Cicero, IL 60650 0037-02-5 Tengerstrom, Eric H.; 3415 S. 59th; Cicero, IL 60650 0037-01-7 Merkel's Floor Covering, Inc.; 8314 Scottdale Rd.; Berrien Springs, MI 49103 0037-00-9 Kraiss, Wilbur & Marilou; 5004 S. Long Ave.; Chicago, IL 60638 0036-00-2 Temmel, Edward P. & Kathleen; 9617 E.
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| Shore Dr.; Oak Lawn, IL 60453 0033-00-3 Gilpin, Clark & Nancy; 1005 E. 60th St.;
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| Chicago, IL 60637 0032-01-5 Wittebort, Robert J., Jr. & Nancy H.;
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| 3180 N. Lakeshore Dr.; Chicago, IL 60657 0030-02-1 Meier, Paul & Louise G.; 1357 Madison Park; Chicago, IL 60615 0028-01-8 Balka, Ronald A. & Janet M.; 3334 Louise Dr.; Lansing, IL 60438
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| Section I, Item 12 ADJACENT PROPERTY OWNERS Page 2 11-110006 0002-03 Michigan Dept. of Natural Resources; P.O. Box 30028; Lansing, MI 48909 0004-00 Franklin Real Estate Co.; P.O. Box 2000; St. Joseph, MI 49085 0004-04 Temmel, Edward P.; 9617 E. Shore Dr.; Oak Lawn, IL 60453 0004-01 Caparo, William E. & Oyler, Kathryn E.;
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| 122 S. Ellsworth Pl.; South Bend, IN 46635 0004-02 Rosemary Beach Corp.; c/o Secretary; 3415 S. 59th St.; Cicero, IL 60650 11-11-0007 0013-00 Lake Charter Twp.; Shawnee Rd.; Bridgman, MI 49106 0013-01 Lake Charter Twp.; Shawnee Rd.; Bridgman, MI 49106 0006-01 Indiana Michigan Power Company 0001-01 Lake Charter Twp.; Shawnee Rd.; Bridgman, MI 49106 0004-01 Lake Charter Twp.; Shawnee Rd.; Bridgman, MI 49106 11-11-0005 0029 Technisand, Inc.; 11833 Ravenna Rd.;
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| Chardon, OH 44024 0036-01 Ruff, Timothy W.; P.O. Box 504 Bridgman, MI 49106 0027-00 Technisand, Inc.; 11833 Ravenna Rd.;
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| Chardon, OH 44024 0036-00 Emery, Martin; Hopkins, Elwood J. & Mable N.; 7499 Thornton Dr.; Stevensville, MI 49127 0036-02 Indiana Michigan Power Company 11-11-0005-0002 01-6 Bank of America Texas P.O. Box 650380 Dallas, TX 75265 11-11-0008 0041-00 Michigan Dept. of Transportation; Lansing, MI 48900 0009-00 Franklin Real Estate Co.; P.O. Box 2000; St. Joseph, MI 49085
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| 30 SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I PERMIT NUMBER ~ qZ pppg AIIFALL%lKD L~O A~
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| e~
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| "~'4 CF PRXESS COltIRIBUTII4 IO EHE DISOIARGE THIS CUAFALL ~Q SIC CCDE CIO0L I NG I TRI 49 LITEM 3 B~ ?ROCFSS SCHEDULE (YEARLY AYERAGE) tCIXIS/DAY "AY /
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| PROCESS 4/I Lft O~
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| C ~ I'SIOCESS HASTEtlATER FLQH RATE actual data submitted TOTAL YEARLY 38P227~5 STREAMS 0 Basis: 1993 CONTRIBUTING 0 DMRS DAILY ttINItXTI ~6 TO 1323 ~6 OUTFALL DISCHARGE De PROCESS PRODUCTION RATE NA DAILY INAXINM Lttl TS / I TIHE I
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| ~
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| A, tl4tfE OF PRQCESS CONIRIBUTING TO TsfE DISCHARGE itFCUGH THIS OUTFALL Al4) SIC COTE NA Be PROCESS SCHEDIAZ (YEARLY AVERAGE)
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| HERS/DAY DAYS/YEN hatt 4/t Ce PROCESS HASTEHATER FLOH RATE fit TOTAL YEARI.Y Mcv O
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| GL DAILY HINIHIN 1 POUNDS DAILY HAXItuS 2 GALLONS D PROCESS PRODUCTIOI RATE 3 CUBIC
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| ~
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| A. IIAIE OF PROCESS CQNTRIBUTIIIG ro THE DISCHARGE YARDS TIIIQUGH 1HIS OUTFALL AISD SIC CODE 4 TONS B. PROCESS SCIEDULE (YEARLY AVERAGE')
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| 5 MGY EYES/DAY DAYS/YEN MGD C. PROCESS IASTEHATER FICtt RATE 7 GPD TOTAL YEARLY DAILY HINIt%N
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| ~
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| DAILY MAXWN UNITS C'TIHE TIME De PROCESS PRODUCTION RATE LJ
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| ~
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| 1 HOUR Ae tIA% OF PROCESS CONTR I BUT ING ID TIE D I SCHRRGE TH Atg SIC CODE NA 2 DAY L-LI B~ l%OCESS SCHHAAX (YEARLY AVERAGE) 3 WEEK ISAIAS/DAY SAYS/YEN l 4 MONTH LNII'ODE 5 YEAR RECESS HASTEHATER FLOH RATE TOTAL YEARLY DAILY H INIIXPI DAILY A'AXItstPI UAIITS /T(HE De srESS PRODUCTION RATE Ae tfAtE OF PROCESS CQNIRIBUTING TO TIE DISCHARGE TI4KXXB THIS OUIFALL AttD SIC CODE Be PRXESS SCHHXLE (YEARI.Y AVERAGE)
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| DAYS/YSN
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| <h 4/) C, PROCESS HASTEIIATER FLCtt RATE
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| <<II T C<<"E TOTAI. YEARLY I Offt Ct tX DAII.Y NINIIXTI D, PROCESS PRODUCTION RATE DAII.Y tAAXWN UNITS / TIPE
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| 5
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| " ' l "I' e r 555 5 ros~s I ' 4 IS 3
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| ; <<)4=4 '; t'-E "-Cx At -== -~4 Cc -.-IE cgcu. '-= 4Eoul ".iynCR AII EE 49.'tQ CN fi E PCNT RAGE = r'4 EXPIRI "B I:e ev'5I 5~ 3l I, c"e 5
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| video ~
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| 5 Ar l, e~ 3 3 I eac. dace EecTIcn
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| ~ v, ren
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| <<I, leave c I snA a,.d 3 1ul per ~ I I cr each trdlvl val dlsc1arce saint ass icnec.
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| 3 d
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| Secara 3 ser
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| ~
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| , I C 3"C JTh, t IC g 4 Carll C ', riC cc alt ''c 'j 'gII~ IhF uATIC'I E"-ec --e - m ='1e process <<nlcn ccnrn'cures -3 -"Is Siscnarae. <<Iso provide -"e prccer IC c-ae.
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| "calo e -re veal lv 3verage process Scneaule In hours:er cav ana days-cer-veer.
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| Provide t14 prcde55 <<35tcwater flow rate infornation 35 reaueSted basea on your last 12 lnanths of operationS. Refer to unit code given in the left margin for the appropriate flow units.
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| orpcess prcauction pate - certain demit limitations may be based cn production la.es. .he croductlcn rates used tothe ceter1lne demit l'nits Sr all ce . eprese"-ec bv 3 reascl,acle caesura c'. cruel production c', he <scllltv, svch as
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| :rccvct!cn during ~he 1ign "anth c'"e previous veer, r T1e nOnthlv averade ',Cr tne highest cf The plevlcus five years', or CT1er . eaSOnable "easure as stated ,'n sdpi:Cable d .E.E.4.A. categoriCal rules ana reaulaticns.
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| "ew 3 ur es r "ew pl5c13r or5 '~ tave r 513s =e asti atec .Sir = crclected crcductlcn ReCCrd y" r C"Cd;C-'Cn rateS In -re -er. S snC .nlrS .Sea 'n me 334<loadie ~.E.E.P.A. CateacriCal iuleS and reduiaricnS fdl'4
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| SECTlON tI PERMIT~
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| NUMBER eII 0005827
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| 'N SEE INSTRUCTIONS REVERSE SIDE OJIFkL IU'FE AO t le CBEM A. IS eeIE DISCHARGE FROM GRQVtCWATERS2 THIS OUTFALL DIRECTED TO THE GRCUt41 CR I IF toe CONTINUE TQ ITEM 5) YES B. TWAS A stYDROGECLCGICAL STVDY OR ITS EQUIVALENT BEEN PERFORMED OR IS THERE SIFFICIENT CURRENT HYDROGEQLQGICAL INFORMATION AVAIIABLEAS REQUIRED BY DE wATER RESOURCES
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| 'es :c H~ISSICN PART 22 GRCVADWATER RN PS CF AUGUST 14 1%6 R,$ 23,22O7 (PAGE 4Q) FQR GROUNDWATER Dtts EXISTING CiR PROPOSED DISCHARGE. IF YES ATTACH A COPY OF IHE REPORT.
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| DISCHARGE C *RE YCV REQUESTING AN EXEMPTICtt FRCM SUBMITTING A HYDROGEOLOGICAL REPCRT VteDER INFORMATION RULE R.323.22(I (Lo) (PAJGE tttt) QR FROM GRQLNDWLTER HQIIITORttts I)EQVJREHEttTS VNDER RULE R'>Zse/JUICE (5) (PAGE Ll) OF THE PART 22 RIES ~ IF 'ES ATTACH COON'S 441 EXPLANATtON TQ DEttQNSTRAIE THAT YAH DISCHARGE WIXaD QUALIFY FOR NA AN EXEt1s IQtt.
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| De ARE YOU REQUESTtttl A VARIAttCE FRCM RULE 323e2205 (PAGE 5) (ttQttDEGRADATICN) OF YES THE WATER REsoURcEs cQtTt tss ION PART 22 GRQUNDtATER RULEs2 IF YEs, ATTAcH sUcH DQCVtENTS AS tiECESSARY TO DEMONSTRATE THE NEED FCR A YARIANCE IN TERMS QF Ttt CRITERIA SPECIFIED IN RIAE 325.2210 (PAGE ~ CF THE PART 22 RULES ~
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| NA Ee I,IST AI,L CHSIICAL SIBSTANCES WHICH ARE IN MICHIGAN'S CRITICAL MATERIALS REGISTER TABLE IV
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| 'LPAGE II) AND/QR U Se EPA S PRIORITY PIXLUTANT LIST TABLE V (PAGE 7) OR ANY OTHER SIISTANCES NIICH ARE OR tAAY BKQK INJUIICUS TO 1% DESIGNIITED USES OF T% GSXNDWATER OR TO THE PUBLIC HEALTH 1HAT ARE DISCHARGED OR EXPECTED TO BE DISCHSIIGED TO 11% GROutDWATERAY THIS Q NQT APPLICABLE/BELIEVED ABSENT FACILITY. ESTIMATE 1HE FINAL EFFLUENT CONCEtttRATION AAD RECORD ALL DATA IN ITEN 7 OF NA SECTION ll IN 1HIS BODICE ~
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| PRESENTS CATA PROVIDED IN ITEM 7 11% APF1.ICANT IAAY BE RECUIRED 10 DO ADDITIONAL WASTE ANALYSESe A>> DISCHARGE CHARACTERISTICS CQNCEttTRATICtt NITS CODE tt ANALYSES SA"PLE TYPE CODE ITEM (F I YE DAY B 1 octet lcAL oxYGEN 5 BQD5 DETAAttD)
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| EXPECTED WASTE WATS CHARAC-II CQD TOC (CHEMICAL OXYGEN DEMAND)
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| (TOTAL ORGANIC CARBON)
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| AtfEXIIANITROGEN (AS N) ul LlJ ul
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| ~
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| ~ u u
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| ISTICS TOTAL SUSPENDED SOLIDS ul ul
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| ~0, ~ll ~0 Usi..a CODE TOTAL Pt42SPtCRUS (AS P)
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| Mg/I 1
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| 2 Ug/ I TOTAL RESIDUAL CtLORINE
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| ~20 ul 3 COUNTS/
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| 100 mt D I SSOLVED OXYGEN HIN ul 4 S.U.
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| 5 F PH
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| ~7 ~0 ~8 ~2 6 LBS/DAY FECAL COLIFORM BACTERIA u3 TEMPERATURE (SttttER) 8 l.u3 u3 mdiv TEE (WINTER) ~65, ~5 ~83 ~4 Be OTHER WASTEWATER CHARACTERISTICS 0 I I. B Ce R E A S E I LJ LJ SAATRLR 1
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| 2222.
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| GRAB 2 24 HOUR LJ LJ
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| ~
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| ~
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| LJ LJ LJ COMPOSIyE LJ u LJ LJ u SEE ATTACHED SHEETS FOR ANALYSIS DATA
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| * Basis: 1993 actual data submitted on DMRS REQUIRED INFQI4tATI(Xt FCR SURFACE WATER DISCHARGEse 35
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| 8 'r ' rc rai i ~ >> c ~
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| ~
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| >7Ev5 '"'0 5 s r<< . 8>>Jires nrcr. dticn cn 3 3 8>> ri <<Ti Ir I,rsc dr'ging ei "Br I'8 grcuncwnters r Tr'8 5ur . dcB <<dters.
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| VI 7 '. "BE>> ru 7RE ~X 3 i E 0 rF 7i (5 CRY. PE EBI7 IASvBER CAV EE FCvNO Crl TpE FPCT(7 PAGE CF
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| ~
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| yCQR EAPIR(r;5 5 3 3 ne>> cr nct previous:v cerml ttec 'dci I i tv, -hen ledve blank dnd 3 hurber wl I I be assicned.
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| I
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| <<<< -.:8>> '" 7"8 5:3>>B 3>>av:sec '3>> sdr>> ".dce or 5ec-(cn I. =cr Bach indlviduni d(sc>dree cc>>
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| ', 5 separa-e set i <<Eid 3
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| ~,c'rcv>>t i ' ' i ' r' 3 *E(.i i'Jc IC'r rhBCFBA I 'I Irr irl 5 I ~ Eu)
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| "e SCCI.'cdr,t Shall sdcress each a! -nese =arts I'e ciscndrce '-an -.".Is outfnl I:5 Ta The grauhc<<nte>>.
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| I '7E4I
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| =.I5 l'.G
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| ~ ".P. KaEC.E" (FCR A KE)r O(5CHARGE) rr35 EhATER C! ACACTEPI57lrg 5< PROV\O'irATER CR 5I'RFACE 'rrATER O(5CP'RGE
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| ("O '!07 lrCI.UOE
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| .' '-C.I '< ru,'RvA7 I I I ~ irl> ru I 7he applicant shall report available discharge dnt: (real data tor ex(sting discharge or expected data for 3 proposed discharge) tcr The parnrre<<ers ds Ii5ted. 74838 parameters shall be addressed far either 3 surface water discharge or ss appropriate tor 3
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| :raur Cwater CISCndrge. FOr SSSIStanCe In determining apprOpriate barnmeterS 3 grOundWater d(SCharCe nppl)Cnnt mny CantdCt The
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| ~rcurc<<dter gua) itv Olvlsicn, Permits 5BC;icn cr The dcorcprlate GraundwdTer Qudlitv Oivislan'5 Oi5trlct a!flee.
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| ",. <<ocr)cant 5"all >>Boar . "e sdmole tvpe cede best sescribirg Bdch repar Rd olece of data. See cad(rc an t"e left margin of n:5 !err .
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| "is: 'T!3: I 5 3 surface <<ster l5C r', 8 dept cant -ust -Boer
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| ~ ". "anti Tntive data fcr eden parameter Identified bv an Ts,er 3<<. ;8 dppiicdnt mav, however,, dcqest --dt -ne repor- hc a :dtd cr cne or mare o Tnese recuirec parsreters be
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| <<diveC. Cn 8".'BST ust be 5 'opal'.BC bv SCBcudte 3 (Chare. dkB Such a recueST dn attachment TO this application.
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| '3,3 ~ 5 Svdiidb'8 tcr other para>>ieters r CT I stec Sbave in ~ '. Cr other pdr'Ts of Thi5 dcpllcatioh The sap()cant 5havld repor'T
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| -dt "3rd in Tre :rdnx SPaces crovlced ln this part.
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| rg7E5. r)nit codes for parameters reported In oarts A dnd B can be found on the lett hand side of this form.
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| :rnb 53BO(e Snail e uSeo t" Sr a(VZe 'Or Crr Temberature, TO<<dl PhenO(S, reSidual Chlarlre, Oi I
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| ~
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| Snd gredSe, nnd fecal coliform In a sur!dce water discnnrce unless other !recuencv-sample type analyses sre ava able. See Glossary (pace 48) far detlnitlon ot grab sample.
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| '3-i)our compos(!8 samples snail be used to analyze rcr .otal BM>>, coo, 7cc, Ammon(a Ilitrogen. dnd iotdl Suspended Ealics In 3 surface <<ster clscnarre unless other 'recuency-sample tvoe analyses are available. See Glossnry (pace 4B) for definition cf ccr.casite sdmole.
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| ceo<<7 "rur:F I'rTAKE 373. 'Ci, 3rd nat recvired Tc reccr'.Class ycv <<isn To demonstrate vour Bllcibillty tcr a "et err luent limitation 'c" cne cr cre al lvtdnts, ThsT is dn ef fluent limitation adjusted by subtracting the
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| ~
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| dverdce level at the ool lutdnt(s) present In your Intake water. VpoES regulations a(law net limitations only in
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| :ertain err cumstnnces. a cercnstrdze vour Blicibili.v, repor. -he sverdce of Tr'e results ot dnalvses on your
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| 'nts<<e <<ster (it vour <<ster 35 Tented berCre <<Se, BS. -ne aTer atter lt is treated), 3 c attaCn a Separate 3>>BBT = 5-Sining -8 rCIIC<<irc rar 83Ch:Crrutsnt:
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| (5) '<<3-<<Bnt "ST <<"8 r>>make <<dter '5 drawn i>>cm "8 cccv = <<ster nta <<nlcn <<he ci5cndrce is <<ade.
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| , Ther>>ISB w>>u 3r'B>>cT 8i i ib)e rcr BT '>>I 3 lans.)
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| Std<<8>>ent Ci <<"8 BXTBnt .a>>hi .", >>8 'BVBl C ~ Tne Cal rutnr T (5 rBrluCBC by Treatment Ct 'rCur <<35TBWdtBr.
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| -vcur linlt3T(ons wi (I ce adjusted only Tc The extent that The pcr lvtdnt:5 nct reeved.)
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| fc) xhen applicable (tor exdmpte, when tne oollutant represents 3 class ot co.pounds) ~ 3 demonst stion ot the extent <<a wl Icri <<he pollutants iq he l>>take .Brv t"vs(ca! Iv, 8<<lcd(!v, >>r b)alacics'Iv ra "8 cc(lu 3"Ts
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| ~
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| Icntnl "Bc ivcur Ci5cndt'CB. Your:mi Tat*5-5 <<': r 38 SC'. Ste- Criy Ta Tre BXtent - dt Tre Ir Td<<e Col li)tanTS
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| :3 nat vary !rom the dlscndraeo Pai lvtanTS.:
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| ic'. nave t o>> -cre ).cst>>" id 'I '"Centred I."5 3.,3~ Tv>>8 uast =er,isslon Ir~ vcur:er lttlrr, ne d<<atvs)5 i r a r Br Supstdr tin( Iy
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| ~
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| )i cr'v Tc same id Snc d>>5 Iv[8 ~
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| v " 8 cv dr I } 5<<bml . 8 85<<I 5 ar st 3 :>>3"-o1:i "8 38~i--'"c duthcri :, cr d sepsr3te shee- 3-Sc"Bc tc.<<we g
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| -C Ies:-:be nv .e curidils hier .Cu "C -Ct -eSt dre 5 5" ~ dl lv ICPnt cdi a>>P
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| SEE INSTRUCTIONS ON REVERSE SIDE SECTlON ll PERMIT NUMBER ~ MI 0005827 eTEM 6
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| 0IIt.kL NXB
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| <ATE IIQIEI FCI'OWING REQUESTED INFORt'ATIOtt ~c>>
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| Q~lTATIVE
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| .'>Ew USE DISCHARGERS e~>>
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| < cc A"DRESSED ~ ~
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| SIRFACE WATER DISCHARGERS>
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| PRQYICE ggECTED VALUES FQR ThE QUAIITITATIVEAttD IhFOR"ATICN REQUESTED BELCH,
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| ~00 1 A. IS THIS FACILllY A PRit>PRY IIKLSTRY2 t>c >C, (REFGI TO TABLE IA PAGE 4+ X YEs GQ TQ E) (tF VES GQ TG 8)
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| PRIORI T Y 8 INDICATE TYPE GF PRIMARY INDUSTRY AS Lls~ IN TABLE IA PAGE 49 ~
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| STM EL EC PtMR POLLUTANTS <CCtlf ttNK WITH C ~ )
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| AND ADDITIONAL C> XES THIS CUfFALL DISCHARGE CCttfAIM ANY
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| (>F NQ> GQ TO E) 'IIF YES, GO TQ D)
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| PROCESS WASTKWATKR2 X YES Q >o INFORMATION NDICATE WHICH C/YS FRACT'CNS MUST BE >FSTED FOR (REFER TO TABLE tA PCiE 4~t X VIXATI LE FOR IIQIE! FCR EACH GC/t'S FRACTION CHECKED, EACH SPECIFIC ORGANIC TOXIC POI 'TAMT WITHIN SURFACE WATER OISCHARGE EACH FRACTION f2!!5J BE AIIALYZED FQR (SEE TABLE I(A PAGE ttKXISTRY APPLICANTS WITH A PRQCESS WASTEWATER DISCHARGE DATA FOR EACH TOXIC POLLUTANT IN TABLE lllA PA;E Q) >
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| ~
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| : 92. IH ADitITICM> ALL PRIPARY PROVIDE QUAMflTATIVE QX X
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| BASE/NFUTRAL ACID ONLY RECCRD AU. DATA GN FCRMS PROVIDED (ITEM 7) IN THIS BCOXLET>
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| (CQNTIIAIE WITH E-t( BELOW) PESTICIDE *
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| ~
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| ~
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| IF IN TABLE IIA AND IVA PAGES BK PROVIDED>
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| ~
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| SURFACE WATER DISOIARGE APPLICAMT (PRIMlRY QR SECCNCARY INDUSTRY), REGARDLESS OF THE TYPE OF DISCHARGE> KtCWS OR HAS REASON TO BELIEVE THAT ANY PIXLUfANT LISTED IS DISCHARGED FRCM ANY OUTFAU.> THE QUANTITATIVE DATA O NQT APPLICABLE/BEI.IEVED ABSENT ALL DATA ON (ITK>t 7) IN THIS BOOKLET>
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| RECORD FORMS PROVIDED O X PRESENT/CATA IS ATTAOlKD F. IF ANY SURFACE WATER DISOURGE APPLICAVT (PRIMARY OR SECONDARY ltGXJSTRY)> REGARDLESS OF TYPE QF DISCIIUIGE> KtCHS OR HAS REASON TO BELtEVE ANY POLLUTANTS USTED IN QX NQT APPLICABLE/BELIEVED ABSENT TABLE VA PAGE + ARE DISCHARGED FRtYI ANY OUTFALL THE APPLICANT ~>
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| REASONS FOR THE POLLUTANT BEtt5 PRESENT AND PROVIDE ANY AVAILAB(EQUANTITATIVE DATA>
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| DESCRIBE RECORD ALL DATA ON FORMS PROVIDED (ITEM 7) IN THIS BOOKLET.
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| O PRESENT/DATA IS ATTACHED G> ALL SNFACE WATER DISCHARGE APPLICAMTS (PRIMARY AND SECONDARY INDUSTRIES)
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| WHO'
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| - X NQT APPLICABLE/BELIEVED ABSENT QR HAMIX'ACTMES 2, 4, 5 TRICILCACPHENQXf ACETIC ACID (2, 4, 5-T);
| |
| ( > 4> 5 TRIOkDROPHENQXY) PROPANQIC ACID (SILVEX> 2> 4> 5> TP)
| |
| U (2> 4> 5 TRICRDROPHENYL) PNSPHQROTHIOATE (ROWEL)' 'I%7HYL TRICtLQRQPHEIOL (TOPI'R HEXACHJOROPHEt>E (KP)'ALL DATA FOR THE ABOVE PI/ST BE GENERATED US It6 STANDARD ANALYTICALCALIBRAlION PROCKDIRES) QR
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| ~Kt4WS OR HAS REASON TQ BELIEVE THAT TCCD IS OR MAY BE PRESEMf IM THEIR DISCHARGE>>
| |
| REPORT %ALITATIVE DATA> GENERATED WHICII gjED A SCREENING PROCKDNE NQT CALIBRATED WITH ANALYTICALSTAIIDARDS, FQR 2, 5,
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| /) 8, -
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| (TcDD) ~ REcQRD ALL cATA 0N FQRMs PRovlDED (ITEM k) IM THts BQoxLET.
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| TKTRACHLORQDIBENZO P DIOXIN Q PRESENT/CATA IS ATTACHED J ~ IF ThE SURFACE WATER DISCHARGE APPLICA'g KtCWS CR HAS REASON TQ BELIEYK >>AT BIQUXIICAI TQXICtTY TESTS wERE ."ACE IN THE LAST THREE (5) YSlRS Qtt Attt OF Tt>E
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| <<FLIC"'tf 5 DISOIARGES QR ON A RECEIVING WATER lit RELATIQtt TQ A DISCHARGE> FROVIDE Cl NQT APPLICABLE THIS It>FORhATICN AS AN ATTACHMENT TQ THIS APPLICATIOM> APPLICABLE/SKE ATTACHED QX tF A CONDUCT VBQRATORY OR CONSll.TING FIRM PERFORMED Atft OF Tte ANLAYSES REQUIRED BY THIS APPLICATION> PROVIDE THE NAME AND ADDRESS OF EACH VBGRATORY OR FIRM AND THE ANALYSES PERFORMED AS AN ATTAQC%HT OF THIS APPLICATIQtt~
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| Q NOT APPLICABLE X APPLICABLE/SEE ATTACHED CO YQU DISCHARGE ANY OTHER TOXIC CR INJIRIOUS CHEMICAL SISSTANCES NQT LISTED Itt TABLES IV PAGE (I AtKI t tA THIOUt4l VA PAtiES ~~+ ~
| |
| '>c +ES> THEN IDENT lcY THE ICAL SUBSTANCES AND ESTIMATE THE FtttAL EFFLUEMT CCNCENTRATIONS. SLKttIT THIS ClX NQT APPI. I CABLE thFOBATICN AS AN AITAt&%lP TO THIS APPLICATION> APPI.ICABLE/SEE ATTACHED
| |
| * Pesticide data is not required; however, it is provided.
| |
| | |
| '-es '" =-5 '".." Pn 3 )cec'.'Ic out<<5) I -'scnarc) "c tc -"e s>>rfece <<aters.
| |
| vI v
| |
| ) ~
| |
| I
| |
| )5:5 "Jv = '= =' '7 <<5 ." ", nl5 FCRu ~
| |
| '"5 egos<IT "tt3BEP CAN ": cg.t(O CN T>>B 3;e>> or nct crevicuslv per lttec iaci Il-v, tnen leave blanx anc 3 nunoer <<:I I orNT e<(:e OF v"(.'R be 3ssicnec.
| |
| exoip('.c
| |
| << "e space Dv'o fcr edc, "age ie ticn .'. - <<escn 're<vidual ciscnarce coin 3 5e"arete 5 1ust sa i 'ec>>t ~
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| T=4l 5
| |
| 'TOTS: "'ou have .<<o cr 'iore 5ub5tantlal lv Incenzlcai outfal ls. vou "av reccest cenlssicn !rm vour cere! tt(na author(tv -c Iaxp le anc snalv e cr ly one outfel I ano sufi t the results ct he and lvsi 5 or her subs'tanti el iv icen. I-al u.fbi Is.
| |
| ( vous "ec<<est Is orantec by ."e pe~it<<lng authorltv, on a separate sheet at ached tc the application fc~ )centi fv
| |
| <<nicn o'. ail,ou ic test. anc case. ice>>nv the outfal ls inich vou CIC rot test sre substantial lv icentlcal -o the outfall
| |
| <<n(Cn ycu Cid te5t.
| |
| e ~
| |
| art I" . I<c)(B), Fricav, Aprl I I IBB3, provices icr a Sea< I = 'siness:xemptlon !.on the reporting of cuantltative cata Icr organic toxic pollutants anc
| |
| ~
| |
| toxic pollutants as recuired bv >art l22. I(q)<7)(ll)<A) or 122.2I<c)<7)(ill)(A).
| |
| hese parts are self-exolanatory anc co not require furher instructions. Si ply go through each port anc co as lndlcatec.
| |
| ano Several ndustrl'sl categories anc suocsteccrles nave peen exe otec
| |
| :30 Ceq Part )22, /OI. JB, "O. ".-', =". IC3V, 'Pr'll I. )793, '.OteS I.
| |
| 'rx 5uo .I ~ t'"c Cata cn certain riG/us Fractions
| |
| , )no 3:.
| |
| Revie>> the fo(ic<<ing i(st to cetemine >>nether vour facility cubi)lies to ce exempt free reporting G /NS <tas Chr<xnatograonv/
| |
| uass Spectrosccpy) .=ractlons.
| |
| GC/u5 Fractlcn Testing and Repor, Irg Exemptions Textile Pills Incustrv
| |
| - All 'our GC/uS organic fractions ln the Greiqe u(ils Suocategory.
| |
| - Pesticide fraction in ail other subparts of this Incu5try.
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| Ore Minlno and Qresslno Industry
| |
| - lolatlle, base/neutral, and pesticlce fractions In tie Base anc precious uetals subcategory.
| |
| - All tour Gc/us orqanic fractions In all other subcategories of this Industrv.
| |
| Gun and Wood Chenicals Industry
| |
| - Pesticide Fraction in the TalI Oi I Rosin Subcategory and the Rosin Based Oerivatives Subcategory.
| |
| . Pesticide and base/neutral fractions In all other Subcateqories of this industry.
| |
| Pulp and Paper Industry
| |
| . Pesticide fraction in Paperqrade sulfite subcateoories (subparts J and U) .
| |
| . Base/neutral and pe5ticlde fractions in Oeink Subpart Q, Dissolvina Kraft Subpart F, and Paperboard frc<<3 Maste Paper Subpart E.
| |
| - Vole!ile. base/neutral, pesticide fractions in the BCT Bleacned Kraft Subpart H, Sem(-chemical Suboarts B and C, and Nonintegrated Fine PaperS Subpart R.
| |
| - Acid, base/neutral, and pesticide Fractions in Fine Bleached Kraft Subpart I, Olssolvlnq Sulfite Pulo Subpart K, Ground-wood Fine PaperS Subpart O. Harket Bleached Kraft Subpart G, Tissue frtxe Mastepaper Subpart T, and Noninteqrated Tissue Papers Subpart 5, Stean<< Electric Po>>er Plant Industry
| |
| . Base/neutral fraction in the Once-Through cooling 'uater, Fly Ash. and Bottc<<n Ash Transport Mater process <<astestrear<<s.
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| 38
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| | |
| SEE INSTRUCTIONS ON REVERSE SIDE SECTION II NUMBER ~ i~fI 0005827 9JIFkL elJKI ~00 !
| |
| USE THIS DATA SHEET TO RECORD INFORMATION AS REQJIRED INl (CHECK APPROPRIATE BOX FOR ttlICH ItIFCRtIATICN THIS ""TA SITEET RE'ESFJITS ) ~
| |
| 59 CI SECTION Ilp ITEM II-Ee GROWDWATER DISCHARGE INFORMATION (PAGE CRITICAL PIATERIALS O 2e SECT ICN I I p ITD! 6e PRIORITY POLLUTANfS IN SIJIFACE WATER DISCH4RGE (PAGE X 3.~ B.~ BELOW: CRITICAL MATERIALS (TABLE IV) IN SURFACE WATER DISCHARGE (PAGE 39)
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| TOXIC
| |
| )LLUTANTS ZARDOUS JBSTANCES Be LIST AtA'RITICALtATERIAL (TABLE IV PAGE 6) NOT ADDRESSED IN SECTION II ITEM F'RIORllY NOT APPLICABLE POLUJTWifs 'eettICH YOU Ieete4t OR HAVE REASON TO BELIEVE TO EE PRESEIIT IN T% DISOARGEP SEE IN REVERSE SIDE OF THIS PAGE FOR FUJAFR DIRECTIats.
| |
| 3ISCHARGE X APPLICABLE (SEE BELOII)
| |
| Ae NAME OF CRITICAL MATERIAL CR PRIORITY IXJLLUTA'8 *Sodium Hypochlorite C L A S S 0 1 /4
| |
| ~0 K
| |
| 144 ~ B. AVERAGE CCNCEJnRATICNJ SAMPLE TYPE; ¹ OF ANALYSES
| |
| ~gj ~] ~LJ ~FV
| |
| ~0 I
| |
| C. AAXI W CaiCENTRAT ION Ato MASS ~20 '~1 ~17 8 ~4 "'~3 Ae N/tAZ CF CRITeiCAL AIATERIAL OR PRIORITY POLLUTAttf WIT CODE SAMPLE TYPE OF ANALYSES B AVERAGE CaICENIRATIONJ SAMPLE lYPEl ¹ OF ANALYSES LJ c.. AXItlftcaICENTRATION eo MASS WIT CODE WIT CODE NITS CODE Ae tIAME OF CRITICAL MATERIAL OR PRICRllY POuJJTANT Mg/ I WIT QIANA TYPE R AF ANALYSES Ug/I B~ AVERAGE CCtICENIRATIONJ SAMPLE TYPE; ¹ OF ANALYSES CCDE I ~/DAY Ce NAXINN CONCENIRATICN AND MASS W T CODE WIT CODE
| |
| ~/DaV
| |
| ~~
| |
| Ae NAME OF CRITICAL MATERIAL CR PRIORllY POLLUTANT WIT 4XXJE SAtPLE TYPE JJ OF ANALYSES B. AVERAGE CC:ICENTPATION; SAMPLE TYPEJ ". OF ANALYSES WIT CODE UNIT CODE MAXIMACctCENIRATICN AND MASS C~
| |
| LJ ~ LJ IAPEE TYPE Ae tIAe% OF CRITICAL MATERIetL CR PRIORITY POLLUTANT GRAB 24 HR.COMP. Be AVERAGE CatCENTRATICNJ QPAE TYPEJ ¹ OF ANALYSES WIT CODE SAtFLE TfPE ¹ OF ANALYSES C~ i'AAXIMYW CCtlCENTRAT ICtl AJYD MASS WIT CODE WIT IX'GE Ae tIAME OF CRITICAL MATERIAL OR PRICRllY POLLUfANT WIT CODE SAJFLE lYPE iP'F ANALYSES 441<!7 B AVERAGE CaJCENIRATION; SAMPLE TYPE; OF ANALYSES LJ
| |
| ~AXltlf8'CXICENTRATIONAtO MASS IIVIT CODE WIT CODE C~
| |
| LJ Ae NAME OF CRITICAL MATERIAL OR PR(CRITY POU.UTANT Ueuf CODE 0 OF ANALYSES I~
| |
| : 3. AvERAGE CaICENIRATICN; SAMPLE TYPEJ ¹ CF ANALYSES LJ SAMPLE TYPE atlT CODE Wlf CODE Ce MAX lttN CCICENIRATION At@I MASS
| |
| ~~
| |
| Ae tIAME CF CRITICAL, MATERIAL OR PRICRITY POLLUTANT WIT CODE SAMPLE IYPE OF ANALYSES
| |
| ~ AVEPAGE CO'KENTRATIONJ SAMPLE TYPE J ¹ OF ANALYSES LJ WIT CCDE WIT CODE C~ ',~AXI"AP. CaticENTRATION A'Cl MASS LJ ~ LJ
| |
| * Discharged as total residual chlorine.
| |
| ADDITIONAL PAGES CF THIS I~ 7 ARE ATTACIED FOR T)E REST OF THE CRITICAL Cl YES MtelERIALS AND/CR PRICRITY PCLLUTANTS REQJIRED TO BE REPORTED e El NO
| |
| ** Basis: 1993 actual data submitted on DMRS. Average concentration based on data from May to December.
| |
| 39
| |
| | |
| EVS >NO '
| |
| 4 <<5 r <<) n 0 << i~ i ~
| |
| 3 is ~ i << :.5-lcn )isc"arse sc-ecuie, ici.-e .Ic>> ra-8
| |
| ~ snc aver -rear"ent
| |
| -=""IT 'K.VEER I'i TI'E BDX AT T E,CP rF Th(S F"Rs. i(E <<Eou(T '<NBER CAl( BE FQ.'~D CN TRE FRONT?AGE CF YODR EXPIRING "is i 5 3 1<<>> C! CV Vr<<viou>> lv er I <<>> ~ 3<<; ( vv, ~ "en leave 0(snx sna s oer <<Ill 08 ssslcnea.
| |
| 0 curtail; >ocr ln scace orovicea 'cr eden caie Section li. =cr !sc )<<civic al aischsrce cin. 5 separate ser cf
| |
| .S. Ce iI led Cuv. "'Ior...S Enrer -ne Iccaticn ot dlscnsrge. Tn(s snouic inc)uce .ual'<<Br iudi ter SBC.icn, Suan,ei'8c Icn. 5BC(ion. (own. Snd range ~
| |
| : 2. C:sr name ot recelvinc water (lt surface waver aiscnarce)
| |
| ',<a(CatB wnBTner (SCI Ii ~ V di5Cnaraes Cn 5 5BSS ndl "OSiS.
| |
| I! yes. ) )st alscnarge periods.
| |
| E. ?rcV)de the land SOp)ICar(On rateS uSea Or eXOBCVea VO Oe uSea In VermS Of inCneS Oer (.Our, rOurS per day, Snd inCneS per week.
| |
| :ndicste the type ot wastewater to oe aischarqea from mls curtail. oefer o the wastewdter tyoe code given In the left
| |
| .45rgin. .4ore than one coae nay oe soolicdoIB ~
| |
| orcvice -ne average nunoer ot hours oei :av in Rien vne 'ac)i)Tv aiscnarces treated wasvewsver snd -he rcral numoer of cays cer vest .n <<nlcn vhe alscnarce occurs.
| |
| orovlde current (fran the last l2 ncnrhs) cr exoectea ficw rates as recuesred. cefer ro unit code aiven In rhe lett margin fcr vne soorcoriste tlcw unirs. "GY - ni(l:cn oallcnS Oer .gear: 'GD - n))l)Cn gallons oer asy; GPO - gallons oer CsV.
| |
| R ovice tne maximum clscnslge flow I'atB <<nlcn vou dnT c navB suTnorlzea within vhe oennit. 'x)TEi ror NpDEs oernlts cnlv, rhe use ot such s flow rate >>i i) nct ploce sn actual )(nit iesrricrlcn on vhe tlow but w)II be the i Icw rate used to ceveloc ettluent limits. Also, <<hen tne ivcnthly Doerstlng Reoorts sre reviewed by compliance staff it will helo them to cetermlne it dny new Or inCreased uSes miqht have oCcurred at the faaility.
| |
| rovlde The design flow for this soeai!Ic cuvfali alsahdrae (e.g. odtcn +rearmenr SySTem flow, packaged treatment SyStem flow, or some other tinite treatment syStem tlow).
| |
| ITE4 2 XATER TOEATS'IENT ADDITIVES
| |
| 'no)care >>nether discharge Is resrec >> lvh :cn<<:tlcners, :nnlbircrs ~ 0<< nicrcolcclce. It not, continue vo Item S.
| |
| B. Give name, function, snd chenicdl compos)tion of additives used.
| |
| Give name snd address of the manufacturer(s) ot vne additives used.
| |
| '<<d)cave Bxoectea min)r~in, sveraae ana -ax)mum ciscnsrce ccncenvrations ot vhe acai.lve(s) for this alscnsrae.
| |
| .~ Ci are wneTher Vou Vt'Bdt Vhe diSCnarie VO r<<moVB "8 dial IVB(5) beiot'8 CiSCharae O. Wds BWarer ~
| |
| ~
| |
| .no(cate ne re oval etticlencv oi eden scaitive tron the <<ssrewater sna <<>8 Cischarae trecuenCV Of each sdai+Ive to the 5>>rface <<ster or grcuna<<ster.
| |
| 'IDTEi Iv Is me resocnslbllltv of rhe aoolicsnr vo suoply tne product information ss reauested in this Iten s. Information reauesrea out nor 5uooliBd msv result ln the soollcstion baird returned to thB doolicsnt 'foi co p(BT)cn, 32
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| | |
| 'oi GREAT LAKES ENVIRONMENTAL CENTER i530 King Avenue Cc(UniDUs. Ct'lo 432 l 2 Phone i61~l 297.6801 6i6i 941-22 '0 Fax i61<) 297.8666 October 12, 1993 Mr. John Carlson Indiana Michigan Power Company Cook Nuclear Plant One Cook Place Bridgman, MI 49106
| |
| | |
| ==Dear John:==
| |
| | |
| TOXICITYTESI'EPORT FOR SULFUR HEXAFLUORIDE GAS (SF6)
| |
| We have completed our analyses of the 48-hour +dgPghgia ~ and 96-hour fathead minnow ilhi~ grggpggg static renewal-acute toxicity tests performed with sulfur hexafluoride (SF6) gas in Lake Michigan water. The Lake Michigan water sample was collected by Indiana Michigan Company personnel on September 28, 1993. The sample was transported overnight to Great Lakes Environmental Center (GLEC), and we received the sample in good condition on September 29, 1993.
| |
| The g. ~d'nd fathead minnow tests were conducted in accordance with GLEC Standard Operating Procedures, which are based on procedures developed by U.S. EPA (Peltier and Weber, 1990, rM T xi ' n Fr hw M 'm,Fourth Edition, EPA/600/4-90/027) and ASTM v
| |
| i E729-88a, 1993).
| |
| T ii T wi It is our understanding that the Cook Nuclear Plant currently injects SF6 into approximately 690,000 gpm of noncontact cooling water at a rate of 5 cfm, which is equivalent to a rate of 54 pl/L of SF6 gas. The fathead minnow acute toxicity test was initiated on October 1, 1993, using an undiluted Lake Michigan water sample that was injected with sulfur hexafluoride gas at a rate of 108 pl/L (twice the plant's injection rate). The gas was injected into a sealed airtight chamber using a gas injection syringe. After injection, the sample was shaken and thoroughly mixed for one minute. This sample was then used as the highest test concentration. A reconstituted laboratory water (Hardness =
| |
| 172 mg/L CaCO>) was used to prepare nominal test concentrations of 54, 27, 14, and 7 pl/L SF6 gas.
| |
| Twenty fathead minnows (3 days old at test initiation) were exposed for 96 hours in groups of ten, in 250 ml glass beakers, each containing 200 ml of test solution (65 x 60 mm of solution in the beakers). Each day the test solutions were carefully renewed by siphoning most of the old solutions from the beakers; freshly prepared solutions were added back to each test chamber daily and the number of surviving fish was recorded. The SF6 concentrations in the test chambers were not measured analytically.
| |
| ~
| |
| Applied Water Quality and Environmental Sciences Q) )AEVI C
| |
| | |
| Mr. John Carlson Indiana Michigan Power Company October 12, 1993 The ~r~h~ni ~ ~
| |
| acute toxicity test was initiated simultaneously with the fathead minnow test using identical exposure concentrations. In each g test concentration we exposed 20 animals
| |
| ((24 hours old at test initiation) in groups of five in 30 ml glass beakers, each containing 25 mls of test solution (40 x 45 mm of solution in the beakers). After 24 hours the animals were transferred to fresh solutions using a wide bore pipet, and the number of surviving or dead animals was recorded.
| |
| The reconstituted water used in Q, EPAmethods f
| |
| ~ and fathead minnow toxicity testing is prepared according to rM rin eAcu T i i f ffl n F hw r M in Qrgg~, Fourth Edition, EPA/600/4-90/027). We used dechlorinated reverse osmosis (R/0) for culturing our Q, ~.
| |
| treated municipal water for the culture of fathead minnows, and.Boardman River water (headwaters)
| |
| Deionized reversewsmosis (R/0) treated municipal water is the base water, to which reagent-grade salts are added to prepare each batch of reconstituted water.
| |
| The results of the Q. ~ and fathead minnow tests indicate that the sulfur hexafluoride gas injected into the Lake Michigan water sample was not acutely toxic. There was 100 percent survival of the Q.
| |
| in the 7, 14, 27, and 108 pl/L SF6 concentrations, and 95 percent survival in the laboratory greater than 108 pl/L SF6 gas. The water chemistry data for the g.
| |
| Table 2.
| |
| ~
| |
| water controls and the 54 pl/L SF6 concentration (Table 1). Therefore, the 48-hour LC~~ value was test are summarized in In the fathead minnow test there was 100 percent survival in the 7, 54, and 108 pl/L SF6 concentrations and in the laboratory water controls g able 3). There was 95 percent survival in the 14 and 27 pl/L test concentrations. Because there was less than 50 percent mortality in the 108 pl/L test concentration, the 96-hour LC for fathead minnows was also greater than 108 pl/L SF6 gas.
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| The water chemistry data for the fathead minnow test are summarized in Table 4.
| |
| In summary, neither Q, ~du i nor fathead minnow survival was affected by any of the SF6 concentrations we tested, including the 108 pl/L (highest test concentration) and 54 pl/L (present application of SF6) test concentrations.
| |
| Copies of the raw data sheets and standard reference toxicant data for the acute effluent toxicity tests are included with this report in Appendices A and B.
| |
| If you have any questions or comments concerning the results of these toxicity tests, please contact either me or Mick DeGraeve at (616) 941-2230.
| |
| Thank you for the opportunity to provide this service to the Indiana Michigan Power Company. We appreciate your business and hope we can be of further service to you in the future. I will be in contact with you to arrange for the visit we have discussed.
| |
| 'erely,
| |
| ;,~.,;~ / /0 Dennis J. McCauley Research Scientist
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| ~~
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| DJM:dm Enclosures
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| | |
| TABLE 1. RESIILTS OF 6 AR RM! ~CIOAPXR 6 EUUA STATIC REIIEIIAL ACU'IE TOXICITY TEST IIITR SULFUR SEXAFLUORIOE RAS ISFAI IRJECIEO IRIS A SAHPLE OF LAKE IIICHIGAN MATER (GLCB 1765) RECEIVED OH SEPTEHBER 28, 1993, FROH COOK NUCLEAR PLANT NEAR BRIDGHAN, HICHIGAN USING RECONSTITUTED LABORATORY MATER AS DILUTIOH MATER (TEST DATES: OCTOBER 1-3, 1993)
| |
| Test Concentration eI ce 't SUI Y val Es 0 (AI/L) 24hr 48hr Laboratory Mater Control 95 95 7 /Ll/L 100 100 14 HI/L 100 100 27 RI/L 100 100 54 HI/L 95 108 pl/L 100 100 48-hour LC~ value was not calculable (greater than 108 HI/L).
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| | |
| TABLE 2. IIAIER CHEIIISTRT UHHIART FOR A 48-IIOUR ~CER OOAPH UH A STATIC REIIEIIAL ACUTE TOXICITT TEST IIITH SULFUR HEXAFLUORIOE SAS ISFAI INJECTED IHTO A SAHPLE OF LAKE kICHIGAN MATER (GLCB 1765) RECEIVED OH SEPTEHBER 28, 1993, FROH COOK NUCLEAR POMER PLANT NEAR BRIDGHAN, kICHIGAH USING RECONSTITUTED LABORATORY MATER AS DILUTION MATER (TEST DATES: OCTOBER 1-3, 1993) 0 i ssol Specific Test ved'xygen Teaperature'C Conductivity Concentrat ion L os cm ~AI Al h I JI8PdII AA (NI/L) keen Range keen Range keen Range keen (mg/L CaCOs) (mg/L CaCO>)
| |
| Laboratory 8.2 (8.1-8.4) 8.6 (8.0-9.0) 24.6 (24.1-25.0) 537 Mater Control 7 NI/L 8.3 (8.2-8.4) 8.6 (8.0.9.0) 24.6 (24.1-25.0) 557 14 pl/L 8.3 (8.2-8.4) 8.6 (8.0.9.2) 24.6 (24.1-25.0) 543 27 NI/L 8.3 (8.3-8.4) 8.7 (8.0-9.4) 24.6 (24.1-25.0) 511 54 pi/L 8.3 (8.2-8.4) 8.7 (8.0-9.4) 24.7 (24.2.25.0) 445 108 AI/L 8.2 (8.1-8.4) 9.0 (8.0-9.8) 24.8 (24.3-25.0) 128 keasurements vere made daily in each test charber.
| |
| A single measurement Has made at the beginning of the test on a coaposite saapie before distribution to the test chacbers and at the end of the test on a cceposite sample.
| |
| Alkalinity and hardness measurements vere made upon preparation of the reconstituted laboratory Mater and upon arrival at the laboratory of the effluent.
| |
| | |
| TABLE 3. RESULTS OF A 96-HQJR FATHEAD HIHHOM STATIC REHEMAL ACUTE TOXICITY TEST MITH SULFUR HEXAFLUORIDE GAS (SF6) INJECTED IHTO A SAHPLE OF LAKE IIICHIGAN MATER (GLCB 1765) RECEIVED OH SEPTEHBER 28, 1993, FROH COOK NUCLEAR POMER PLANT NEAR BRIDGHAN, ilICHIGAH USING RECONSTITUTED LABORATORT MATER AS DILUTIOH MATER (TEST DATES: OCTOBER 1-5, 1993)
| |
| Test Concentration ece Suvval H~ 0 (aI/L) 24hr 48hr 72hr 96hr Laboratory Mater Control 100 100 100 100 7 HI/L 100 100 100 100 14 HI/L 100 95 27 HI/L 100 100 95 95 54 HI/L 100 100 100 100 108 III/L 100 100 100 100 96-hour LCso value uas not calculable (greater than 108 HI/L).
| |
| | |
| TABLE 4. MATER CHENISTRY SLNB(ARY FOR A 96-HOUR FATHEAD HINNOM STATIC RENEMAL ACUTE TOXICITY TEST Ml'lH SULFUR HEXAFLUORIDE GAS INJECTED INTO A LAKE NICHIGAN MATER SANPLE (GLECN 1765) RECEIVED ON SEPTENBER 28, 1993, FRON COOK NUCLEAR PLANT NEAR BRIDGHAN, NICHIGAN USING RECONSTITUTED LABORATORY MATER AS DILUTION MAIER (TEST DATES: OCIOBER 1-5, 1993)
| |
| Dissolved'xygen Speci f Test Teaperature' ic'onductivity Concentration L os cm ~kkk I k ~rdn (NL/L) Old OLd Neu OLcl Neu OLd (mg/L CaCO>) (mg/L CaCO>)
| |
| Laboiatoly 8.2 8.1 B.S 6.9 25.0 24.6 537 539 104 172 Mater Control (8.2-e.C) (7.9-e.2) (8.8.8.9) (6.2-7.5) (25.0-25.0) (24.2-.25.3) (494-566) (539-539) (104-104) (172-172) 7 NL/L 8.3 8.1 8.9 7.5 25.0 24.6 556 547 (8.2-8.C) (7.9-8.2) (8.8-9.0) (7.1-8.0) (25.0-25.0) (24.2-25.2) (537-587) (547-547) 1C liL/L 8.3 8.2 9.0 7.4 25.0 24.6 539 531 (8.2-8.3) (8.1.8.2) (9.0.9.2) (6.6-e.o) (25.0.25.0) (24.2-25.1) (531-557) (531.531) 27 NL/L 8.3 8.1 9.1 7.1 25.0 24.6 514 502 (8.2.8.3) (8.0.8.2) (8.9.9.4) (6.5-8.0) (25.0-25.0) (24.3-25.1) (502-516) (502-516) 54 lil/L 8.2 8.1 9.2 7.2 25.0 24.6 444 438 (8.2-8.3) (8.1-8.2) (9.0-9.4) (6.9-7.6) (25.0.25.0) (24.0-25.1) (4C0.450) (438-438) 108 ltL/L 8.1 8.0 9.8 7.5 25.0 24.6 311 304 106 128 (S.1-8.2) (7.C.8.2) (9.6-10.2) (7.4-7.6) (25.0-25.0) (24.1-25.2) (303-316) (304-304) (106-106) (128-128)
| |
| Ileasurements uere made on neu test solutions and old test solutions. The nurbers represent the mean and range (in parentheses) of measurements observed during the test.
| |
| Alkalinity and hardness measurements Mere made upon preparation of the reconstituted laboratory eater and upon arrival of the sample.
| |
| | |
| APPENDIX A RA~V DATA SHEET
| |
| | |
| C' w~a 'a t
| |
| ~
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| RS SRSRIRlhRl688888888RlklhlRlbbRRf 5 HRHRlHHHHIWRRSHpHHRRHSHHHHH5 WRWRRERSWESRRESRRSISWSRRIRE 0 ~ I a y
| |
| ~ ~ e ~
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| RHKSKRHRRERRRI RHRRIRQ RKKIR '5SRHRRfREI HRSSSHSHRIHIHSIHHHRRRHWWWRS 5ERRSQERQE5$ %85$ ldl'5$ 5QRRE
| |
| | |
| QA L f I PE A) 2 ~i-'I- ,O'i FlSal 96-llOUR STA; CUTE TOXlClTYTEST rj 6/ (I
| |
| 'I'cat hlslco~t: tJQ Type of Test: Dilutiun Water:
| |
| )'ls j I Nu.. 0 No. Fish/Chantbcr: 0 GLC and/or Batch No.:
| |
| I cst SII I~ k No. of Chambers: jl Tcntpcraturc: 2c~ "c c
| |
| lwihlll Wjlk. Agc of Fish: )ncubalor 4:
| |
| Iau Test Tech. Trcsltncnl vcl . Control Day )nil. Rcplicatc Number Tcm craturc DO miIL S .Cond. umhos/cm 10 (0 JO I CI /0 g'0 No. Live Obsarvau sns j 05 oss I'i7 0 II ).Q ~)7 0 gl7 C'J I d,z't DO m'IL RZ . 7 8-+
| |
| 1 V 7 Zg lg.Q L l.Z 2>.v ~f/
| |
| Tcln cralurc No. Live 0 2
| |
| 0 f qn g'17 ] g DO m/L n 1 l n Tcm cralurc ~
| |
| l~l'll'r No. Live 0 IO
| |
| /+ rfjvrz>, /
| |
| yO Obscrvaltons
| |
| ,f'. 0 K- /0
| |
| : 7. / T. 0 rj ~ 7 Cf 7, I Tcm cralurc 2g aS.C No. Live IO Observations zo C/
| |
| DO m II.
| |
| S .Cord. umhos/cnt C
| |
| - Erratic Swimmin FS - Film on Surface F - Floater )MM - bnmobilc t)hicrvstuu< hcy: DOS - Drie Oul uu ScsLcr PM - Paniculstc Msucr ERR Rcvicwcd by:
| |
| | |
| ~ .
| |
| EFFLUENT Ai%) RECEIVING WATER CHECK-IN FORM Client:(t"C I-'4'ICI00-4 project No,:
| |
| Investigators:
| |
| INITIALWATER CHEMISTRY (UPON RECEIPT)
| |
| Date Initials GLC No.
| |
| Collection Date (time interval)
| |
| Temperature pa~
| |
| WATER CHEMISTRY AT TEST TEMPERATURES Date: Initials CcnC tutjcl<z Y GLC No. /7 Temperature pH $
| |
| Dissolved Oxygen (mg/L)
| |
| Conductivity (umhos's/cm)
| |
| Hardness (mg/L)
| |
| Alkalinity (mg/L) ~ /DQ Total Chlorine (mg/L)*
| |
| Total Ammonia (mg/L)*
| |
| Check with project manager to see if necessary
| |
| | |
| C Lrekee Envirnnrnenkrl Cenler 739 I tastings Street CHANC OF CUSTODY RKCO14B Trarerse City, MI 49684 9 O BE COMPLETED ON-S)TE AND SUBMITI'ED Wm) SAMPLES)
| |
| Phone: (616) 941-2239 Fax: (616) 941-22AO Facility: . C~+ ++'/~~ ~+ . /c4. Co0ector:
| |
| Location; re ~~~ ~e e.' rfc'p &re. AM& Date - z-.s-'V3 c iO Contact Person: ~ -~ C>r. ~~-a Witness:
| |
| Phone Number: re a&~ ~So~ Date: r z 1 SAMPLE DATE/I'IME VOLUME SAMPLE SAMPLE DESCRIPTION PRESE RYATION ANALYSES ID OF SAMPLE COLLECTED COLLECTOR CONTAIN)UK (Type of sample, REQUIRED source, physical characteristics)
| |
| (8-ZggC. /q,4nr g i.;.-~S/ io . (I-- M. c~e~~a rr ver >7 Cr TRANSFER OF SAMPLES:
| |
| P~r'-zs (First signature is sampler, lust silenature is authorized laboratory representative.)
| |
| 5LHXF)L
| |
| : 1. ~~i -g3 2e V7~
| |
| nii f ml l n <<i Ptif($ ~
| |
| ( Ai ri I
| |
| i ~)
| |
| | |
| APPENDIX B M)ARD REFEREN E T XICANT DATA
| |
| | |
| GREAT LAKES ENVIRONMENTAL CENTER Sodium Chloride (NaCI) Toxicity Data 1992 " 1993 grams/Liter 3.5 3
| |
| 2.5 1.5 0.5 0
| |
| APR MAY JUN JUL AUG OGT OGT NOV DEG JAN FEB MAR APR MAY JUN JUL AUG SEP I 1992 I 1993 I 48-hour LG50 ~ Mean plus S.D. Mean minus S.D.
| |
| ~ Mean plus 2 S.D. ~ 1 Mean minus 2 S.D.
| |
| 1 Ceriodaphnia dubia Survival
| |
| | |
| GREAT LAKES ENVIRONMENTAL CENTER Sodium Chloride (NaCI) Toxicity Data 1992 - 1993 grams/Liter l2 10 0
| |
| APR MAY JUN JUL AUG OGT OGT NOV DEG JAN FEB MAR APR MAY JUN JUL AUG SEP I 1992 I 1993 I 48-hour LG50 ~ Mean plus 1 S.D. Mean minus 1 S.D.
| |
| Mean plus 2 S.D. Mean minus 2 S.D.
| |
| Fat head Minnow Sur v ival
| |
| | |
| ATTAC~NT 4 REPORT ON THE WHOLE EFFLUENT TOXICITY TEST FOR DETOXIFIED CLAM-TROL EFFLUENT AT DONALD C. COOK NUCLEAR PLANT American Electric Power Service Corporation and Indiana Michigan Power Company February 22, 1993
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| | |
| WHOLE EFFLUENT TOXICITY TEST Introduction The Michigan Department of Natural Resources (MDNR) issued a letter modifica-tion for the Donald C. Cook Nuclear Plant approving the use of the propri-etary molluscicide Clam-Trol, CT-1 (Betz Industrial). The letter, dated April 24, 1992, from Mr. Fred Morley to Mr. Donald Baker, Indiana Michigan Power Company (I&M), allowed the use of Clam-Trol if the effluent contained Clam-Trol concentrations equal to or less than 0.05 mg/1. Since the detec-tion limit for Clam-Trol is 0.2 mg/l, the MDNR required whole effluent toxicity (WET) testing to assure compliance with the state water quality standard provision prohibiting the discharge of toxic materials in toxic amounts.
| |
| The MDNR also required Z&M to submit a study plan describing how the WET testing would be performed. Mr. Baker sent Z&M's study plan to Mr. Morley by letter dated June 9, 1992. I&M's study plan described how and where the effluent streams would be sampled from Outfalls 001 and 002, and how the samples would be shipped, analyzed, and reported to the MDNR. This plan also described how the data would be evaluated and specified testing to be con-ducted should any single test produce an EC>0 less than 100K effluent.,
| |
| The letter modification of the Cook Plant NPDES Permit was conditional on the study plan being approved by the MDNR. MDNR notified Z&M by letter dated July 16, 1992 that the study plan was acceptable.
| |
| | |
| Treatment of the Cook Plant for zebra mussel control has evolved from attempts to treat the entire plant in one operation to treating components of the plant in separate operations. The intake tunnels are treated individu-ally, the circulating water system is treated as one system and components of the essential service water (ESW) and'on-essential service water (NESW) systems are treated as needed.
| |
| Treatment Pro ram Com leted In 1992 The north and center intake water tunnels were treated with Clam-Trol on August 12 and 13 and September 11 and 12, 1992, respectively. The circula-ting water system was treated on September 16 with Clam-Trol. Water samples were collected during each of these three periods as described in the ap-proved study plan. These samples of detoxified effluent were split and then shipped to a contract laboratory and to the MDNR toxicity testing laboratory for analyses. The contract laboratory conducted a 48-hour acute toxicity test using ~pa hnia fulex on each of the three water samples. At the same time the detoxified effluent samples were being analyzed, a series of ben-tonite clay solutions were being tested for impact on the test organisms.
| |
| ~Da hnia sp. and other zooplankters can be adversely affected by mechanical (rather than chemically toxic) means when exposed to excessive amounts of suspended clay. These clay blank test series were conducted using Lake Michigan water and the same clay used to detoxify the Clam-Trol. Lake Michigan water used for dilution of the detoxified effluent tests and the clay blank tests was collected before the Clam-Trol treatments began.
| |
| | |
| ~
| |
| | |
| Methods 0
| |
| Water samples were collected from the discharge tunnel manways using a submerged pump at the beginning of the treatment, at the fourth hour, at the eighth hour and at the twelfth hour of treatment. Samples were collected from Unit 2 discharge manway and composited in one container. At the end of the test, a sample was removed from the composited sample container and shipped to the contract laboratory. During treatments to the north and center intake tunnels on August 12-13 and September 11-12, 1992, there was no effluent from the Unit 1 discharge .tunnel. During the circulating water system treatment on September 16, samples were collected from both the Unit 1 and Unit 2 discharge tunnel manways and composited into one container, from which the water for WET testing was taken.
| |
| The laboratory followed the procedure for conducting 48-hour EC50 acute toxicity tests according to the EPA protocol, "Method for Measuring the Acute Toxicity of Effluent to Freshwater and Marine Organisms," EPA/600/4-85/013.
| |
| A dilution series of 100X, 50X, 25X, 12.5X, 6.25X and OX (control) effluent was set up. Lake Michigan water filtered to remove native zooplankton was used for dilution. Four 30 ml beakers were set up for each test concentra-cion and 25 ul oi test solution uas put in each beaker pive .~Da hnia Dulex juveniles (<24 hours old) were placed in each beaker. Temperature was. ~
| |
| maintained at 25'+ 1 C. Temperature, DO, and conductivity were measured every 24 hours. The effects were recorded every 24 hours. Organisms that failed to remain in the water column for five seconds after a gentle prod or swirling the beaker were considered effected. Results are reported as acute 48-hour EC5 values.
| |
| | |
| A test series of bentonite clay blanks was conducted the same as the detoxi-fied Clam-Trol effluent. t'iltered Lake Michigan water was mixed with the same concentration of bentonite clay used to detoxify the Clam-Trol. This concentration of bentonite clay was tested at 100X, 50X, 25X, 12.5X, 6.25X and OZ (control).
| |
| Results Whole Effluent Toxicity tests were conducted August 15 through 17, September 13 through 15, and September 17 through 19, 1992. Table 1 shows the immobility percentages of the detoxified Clam-Trol effluent and the bentonite clay blank test concentrations. Immobility results exceeded the EC50 for 100Z effluent at all detoxified effluent and clay blank test concen-trations. The highest immobility result was 30Z for the detoxified Clam-Trol effluent samples and 25X for the bentonite clay blanks at the 100X effluent concentration. One test series was technically invalid because the control (OX effluent) had >10X immobility. Except for the immobility observed at the control concentration in the detoxified effluent test conducted on September 13-15, toxicity was low and the immobilities that were observed followed a similar pattern as the clay blank test series. Immobility per-centage differences between the detoxified Clam-Trol and clay blank test concentrations were usually 5Z or less.
| |
| Discussion The 70X immobility value obtained for the control test on September l.3-15 would appear to be an anomolous value, since the bentonite clay blank control
| |
| | |
| e using Lake Michigan water supplied to the contract laboratory in the same shipment showed OX immobilitye Three of the four control replicates showed all or nearly all test organisms vere immobilized and in one of the four replicates none of the organisms were immobilized during the 48-hour test.
| |
| An examination of the laboratory sheet for the treatment concentrations shows that the organisms in the replicates were immobilized in nearly equal num-bers, e.g., the 50X and 100X effluent replicates had one or two immobilized e
| |
| organisms. None of the treatment replicates individually accounted for all of the immobilities, which would indicate a contaminated replicate. The immobilities were equally distributed among the replicates. There is no water quality parameter that vas measured before, during, or after the toxicity test that indicates a problem for ~Da hnia pulex's well being.
| |
| Given the general lack of immobilization response of organisms in the dif-ferent treatment concentrations tested on any given date and the similarity of test results from one test date to the nest, there vas little difference between the detoxified Clam-Trol effluent and the bentonite clay blanks effects on the test organisms. All tests were in compliance with the re-quirement that the 48-hour EC for ~pa hnia exceed 100Z effluent. in other vords the tests shoved that effluent toxicity vas less than the toxicity needed to produce an EC>0 in 100X effluent. The lack of toxicity indicates the detoxified effluent had little impact on the Lake Michigan aquatic community.
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| | |
| TABLE 1
| |
| ~Da hnia pulex 48-hour Pereenr Immoblllry Values Obtained from Whole Effluent Toxicity Tests Conducted with Detoxified Clam-Trol in Lake Michigan Water and Bentonite Clay Blank Test Run in Lake Michigan Water (clay blank immobility percentages in parentheses)
| |
| Control Test Date (OX) 6. 25X 12.5X 252 502 l002 Aug 15-17 OX OX OX 15X OX 25X (OX) (OZ) (10X) ( OX) (10X) ( 5X)
| |
| Sep 13-15 70Z OX 15X 20X 30X 30X (OX) (5X) (10X) (25X) (20X) (25X)
| |
| Sep 17-19 OX OZ 10X 10X 5X 15X (5Z) (5Z) ( 5X) ( 5X) ( OX) ( 5X)
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| | |
| ANALYTXCAL REPORT Cook Nuclear Submittal Number: 29609- 3 Proj: Waste Water Analysis Location:
| |
| | |
| ==Contact:==
| |
| Ray V. Buhl Subm: Jan 26 Samples Phone: (616) 942-9600 Outfall Outfall Circ. Detection Units 001 002 Intake Limit WWES Sample No: 78371 78372 '8373 BOD, (5- Day) (1.0 (1.0 (1.0 1.0 mg/1 Sampled by:
| |
| Date Sampled: 01/26/94 01/26/94 01/26/94 Time Sampled: 00 00 00 00 00 00 Date Received: 01/27/94 01/27/94 01/27/94 Time Received: 13:30 13:30 13:30
| |
| .)') ).) (II<'11N'<l<)d llllis I arkKval SI' I'() l3<)'>< 874. (Iraad Rapids. Ill 49588-0874. 6 I 6/942-<J600 I'0% 9-!2-li~!
| |
| | |
| llll I n V>Ctrl> F-Snl'ru'e i illllllllli(.)IIII/Allo STATEMENT OF DATA QUALIFICATIONS CLIENT: Cook Nuclear SUBMITTAL:29609-3 All analyses have been validated and comply with our Quality Control Program. No qualifications required.
| |
| The following analyses have been qualiTied for the reasons cited.
| |
| KEY
| |
| : l. Sample integrity suspect upon receipt (explain).
| |
| : 2. Analysis performed beyond EPA established maximum allowable holding time.
| |
| : 3. Detection limit elevated due to matrix interferences.
| |
| 4, Laboratory control sample value outside established acceptable limits.
| |
| : 5. Matrix spike sample value outside established acceptable limits.
| |
| : 6. Duplicate analysis value outside established acceptable limits.
| |
| : 7. Surrogate/internal standard recoveries outside established acceptable limits.
| |
| : 8. Data point suspect due to potential laboratory contamination (explain).
| |
| : 9. Coelutes with the compound cited. Result may represent a combination of both compounds.
| |
| : 10. Other (explain).
| |
| Noler This document is included as part of the Analytical Report for the above referenced and should be retained as a permanent record thereof.
| |
| 5555 Glenwood Illlls Parkway St',. t'0 Box 874. ()rand Rapids. Atl 49588-08?4. 6 l6/942-9600 t'nx 9 t'-'-6.l99
| |
| | |
| lt 'n<~ul(( I'uI 8-'(7('ll('('
| |
| '1 1
| |
| ~~
| |
| .~nlnnn( < ann+.in' I. l 'I' (: X I, 5 I:. I' I (.':..
| |
| ANALYTICAL REPORT Cook Nuclear Submittal Number: 29609- 4 Proj: Waste Water Analysis Location:
| |
| | |
| ==Contact:==
| |
| Ray V. Buhl Subm: January Samples Phone: (616) 942-9600 Outfall Outfall Circ Water Detection Units 001-Circ 002-Circ Intake Limit Water Dsch Water Dsch WWES Sample No: 78532 78533 78534
| |
| .Surfactants,-.NBAS <0.025 . <0. 025 <0.025 0.025 mg/1 Coliform, Fecal 2 <1 4 1 cl/100ml Color (Apparent) <5 <5 <5 5 e pH Sampled by: V. Shah V. Shah V. Shah Date Sampled: 01/26/94 01/26/94'0'00 Time Sampled: 00 00 Date Received: 01/28/94 01/28/94 01/28/94 Time Received: 00 00 00 00 00 00 5555 (Ilenn'()n(l Iiills Purkway SE. PO Box 874. (Irdnd RnPids. All 49588-0874. 6I6/942-9600 I';>x ll I2-(i.l9I
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| | |
| 1V1V I:rg>mar <<~ >
| |
| & Sne<<ce i.v>>>>1>N( 4>>>>p >j>l A 5 A I, Y 'I' (:,K I, 8 l'. R t I (: f' STATEMENT OF DATA QUALIFICATIONS CLIENT: Cook Nuclear SUBMITTAL:29if09<
| |
| All analyses have been validated and comply with our Quality Control Program. No qualifications required.
| |
| The following analyses have been qualiTied for the reasons cited.
| |
| Sample No. (s): Reason:~
| |
| Explanation:
| |
| KEY
| |
| : l. Sample integrity suspect upon receipt (explain).
| |
| : 2. Analysis performed beyond EPA established maximum allowable holding time.
| |
| : 3. Detection limit elevated due to matrix interferences.
| |
| : 4. Laboratory control sample value outside established acceptable limits.
| |
| : 5. Matrix spike sample value outside established acceptable limits.
| |
| : 6. Duplicate analysis value outside established acceptable limits.
| |
| : 7. Surrogate/internal standard recoveries outside established acceptable limits.
| |
| : 8. Data point suspect due to potential laboratory contamination (explain).
| |
| : 9. Coelutes with the compound cited. Result may represent a combination of both compounds.
| |
| : 10. Other (explain).
| |
| Note: This document is included as part of the Analytical Report for the above referenced and should be retained as a permanent record thereof.
| |
| 5555 (ileum>od lt Ills Parkway St,". PO Box 874. (irand Rapids. Itl 49588-0874 616/942-9600
| |
| ~ Vas 9-t2>-tijou
| |
| | |
| Lockheed Analytical Services DATA QUALIFIERS FOR INORGANIC ANALYSES (Revised 08/28/92J For Use on the Analytical Data Reporting Forms For CLP Analyses Only Reported value is less than the contract required detection B limit (CRDL) but greater than or equal to the instrument detection limit (iDL).
| |
| For Routine, Non-CLP Analyses Only Any constituent that was also detected in the associated blank whose concentration was greater than the reporting detection limit (RDL).
| |
| D Presence of high levels of interfering constituents required dilution of sample which increased the RDL by the dilution factor.
| |
| E Estimated value due to presence of interference.
| |
| Sample analysis performed outside of method-or client-specified maximum holding time H requirement.
| |
| M For CLP Analyses Only Duplicate injection precision criterion was not met.
| |
| N Matrix spike recovery exceeded acceptance limits.
| |
| Reported value was determined from the method of standard addition.
| |
| For CLP Reporting Only Constituent was analyzed for but not detected (sample U quantitation must be corrected for dilution and percent moisture).
| |
| For AAS Only Post-digestion spike for Furnace AAS did not meet acceptance criteria and sample absorbance is less than 50% of spike absorbance.
| |
| X, Y,orZ Analystdefined qualifier.
| |
| Relative percent difference (RPD) for duplicate analysis exceeded acceptance limits.
| |
| Correlation coefficient (r) for the MSA is less than 0.995.
| |
| '-.. For Use on the QC Data Reporting Forms
| |
| 'he al spike recovery and/or RPD for matrix spike and matrix spike duplicates cannot be evaluated due to insufficient spiking level compared to the elevated sample analyte concentration.
| |
| bi The RPD cannot be computed because the sample and/or duplicate concentration was below the RDL.
| |
| 'sed as footnote designations on the QC summary form.
| |
| | |
| Lockheed Analytical Services DATA QVALIFIERS FOR ORGANIC ANALYSES fgÃvkaf:;:"Og/X98$94J For Use On The Analytical Data Reporting Forms A For CLP analyses Only The TIC is a suspected aldol-condensation product.
| |
| Any constituent that was also detected in the associated blank whose concentration was B greater than the practical or reporting detection limit (PQL or RDL).
| |
| Constituent confirmed by GC/MS analysis. Ipesticide/PCB analyses onlyJ Constituent detected in the diluted sample. It also indicates that an accurate quantitation is not possible due to g~rggg~ being diluted out of the samples during the course of the analysis.
| |
| Constituent concentration exceeded the calibration range.
| |
| The quantitation is not gasoline or diesel but believed to be some other combination of hydrocarbons.
| |
| Sample analysis performed outside of method- or client-specified maximum holding time H requirement.
| |
| Estimated value (1) constituent detected at a level less than the RDL or PQL and greater than or equal to the MDL; (2) estimated concentration for TICs (For CLP Reporting Only).
| |
| For CLP Reporting Only Tentatively identified constituents PICs) identified based on N mass spectral library search.
| |
| For CLP Reporting Only The percent difference between the concentrations detected on both GC columns was greater than 25 percent /pesticide/PCB analyses onlyJ.
| |
| For CLP Reporting Only Constituent was analyzed for but not detected (sample U quantitation must be corrected for dilution and percent moisture).
| |
| X, Y,orZ Analyst-defined qualifier.
| |
| N/A in the % moisture cell indicates that data are reported on an "as received" basis. A N/A value in the % moisture cell indicates that data are reported based on a "dry weight"
| |
| (% Moisture) basis. For non-CLP wort, RDLs are not adjusted for % moisture even when data are reported on a "dry weight" basis.
| |
| ...;:.:=:, - For;Use On The QC Data Reporting Forms QC data (i.e., percent recovery data for matrix spike, matrix spike duplicate, laboratory control standard, or surrogates; and RPD for matrix spike duplicate or unspiked duplicate) exceeded acceptance limits.
| |
| The spike recovery and/or RPD for matrix spike and matrix spike duplicates cannot be al evaluated due to insufficient spiking level compared to the elevated sample analyte concentration.
| |
| The RPD cannot be computed because the sample and/or duplicate concentration was below the RDL.
| |
| 'sed as footnote designations on the QC Summary Form.
| |
| | |
| Lockheed Analytical Services DATA QUALIFIERS FOR RADIOCHEMICALANALYSES
| |
| /Revised 08/28/92J For Use on the Analytical Data Reporting Forms Any constituent that was also detected in the associated blank whose B concentration was greater than the reporting detection limit (RDL) and/or minimum detectable activity (MDA),
| |
| Presence of high TDS in sample required reduction of sample size which increased the MDA.
| |
| Constituent detected in the diluted sample.
| |
| Constituent concentration exceeded the calibration or attenuation curve range.
| |
| For Alpha Spectrometry Only- FWHM exceeded acceptance limits.
| |
| H Sample analysis performed outside of method-specified maximum holding time requirement.
| |
| Chemical yield exceeded acceptance limits.
| |
| '; -': ''For Use on'the QC'Data Reporting ForIns'," ... ',"',', " ',
| |
| 'C data (i.e., percent recovery data for laboratory control standard and matrix spike; and RPD for replicate analyses) exceeded acceptance limits.
| |
| al The spike recovery and/or RPD for matrix spike and duplicates cannot be evaluated due to insufficient spiking level compared to the elevated sample analyte concentration.
| |
| bi The RPD cannot be computed because the sample and/or duplicate concentration was below the MDA.
| |
| 'sed as foot note designations on the QC summary form.
| |
| | |
| GENERAL CHEMlSTRY RESULTS Client Sam le ID: OUTFALL 001 Date Collected: 01-24-94 Matrix: water LAL Batch ID(s): 126 im Date Received: 01-26-94 PO469095-040-3N Reporting Data Date LAL Constituent Method Result Detection Umlt Qualiflarls) Anal zad Sam la ID Fluoride, in m IL 340.2 <0.15 0.15 03-02-94 L11 31-8 Bromide, inm IL 300.0 '0.050 0.050 01-28-94 L1 131-16 Nitrite-Nitrate-Nitrogen, 353.2 0.35 0.050 02-1 1-94 L1 1 31-21 inm IL Sulfate, inm IL 300.0 22 0.059 01-27-94 L1 1 31-1 6 Total C anide, inm IL 335.2 <0.020 0.020 01-27-94 L1131-25 Total Phenolics, in m IL 420.1 <0.15 0.15 02-08-94 L1131-30 Sulfide, inm IL 376.1 <1.0 1.0 01-27-94 L1131-11 Comments:
| |
| | |
| GENERAL CHEMISTRY RESULTS Client Sample ID: OUTFALL 001 CIRC Date Collected: 01-26-94 Matrix: whter WATER LAL Batch ID(s): 126 im, 127 im Date Received: 01-27-94 P0 469095-040-3N Reporting Deto Date LAL Constituent Method Result Detection Umlt Ouellflerls) Anal ed Sem le ID Total Phosphorus, 365.2 (0.030 0.030 02-08-94 L1142-5 in m /L Ammonia Nitrogen, 350.1 <0.050 0.050 02-01-94 L1142-5 inm IL Total Suspended Solids, 160.2 (12 12 02-02-94 L1 142-9 inm IL Total Organic Carbon, 415.2 1.8 1.0 02-16-94 L1142-1 in m IL Chemical Oxygen 410.2 (18 18 01-28-94 L1142-1 Demand, inm IL Total Kjeldahl Nitrogen, 351.2 0.20 0.10 03-03-94 Ll 142-5 in m /L Comments:
| |
| | |
| GENERAL CHEIVllSTRY RESULTS Client Sam le ID: OUTFALL 001 Date Collected: 01-27-94 Matrix: water LAL Batch ID(s): 128 im Date Received: 01-28-94 PO469095-040-3N Reporting Data Date LAL Constituent Method Result Detection Umlt Qualifie(s) Anal ed Sam le ID Color 1 10.3 < 5.0 5.0 01-28-94 L1151-1 Sulfite, in rng/L 377.1 < 1.0 1.0 01-29-94 L1151-1 Comments:
| |
| CQC
| |
| | |
| METALS RESULTS Client Sam le ID: OUTFALL 001 Date Collected: 01-24-94 Matrix: water LAL Batch ID(s): 126 im Date Received: 01-26-94 POI)'69095-040-3N Reporting Concentration Detection umit Date Date LAL Constituente Method (m IL) lm lL) Qualifier)a) Anal zed Sam le ID Aluminum 6010 <0.20 0.20 02-22-94 L1 1 31-94 Antimon 6010 <0.060 0.060 02-22-94 L1 131-94 Arsenic 7060 <0.010 0.010 02-20-94 L1 131-94 Barium 6010 <0.20 0.20 02-22-94 L1 131-94 Ber Ilium 6010 <0.005 0.005 02-22-94 L1 1 31-94 Boron 6010 <0.20 0.20 02-22-94 L11 31-94 Cadmium 6010 <0.005 0.005 02-22-94 L1 131-94 Chromium 6010 < 0.010 0.010 02-22-94 L1 131-94 Cobalt 6010 <0.050 0.050 02-22-94 L1131-94 Co er 6010 <0.025 0.025 02-22-94 L1131-94 Iron 6010 <0.10 0.10 02-22-94 L1 131-94 Lead 7421 <0.003 0.003 02-23-94 L1 131-94 Ma nesium 6010 12 5.0 02-22-94 L11 31-94 Man anese 6010 < 0.015 0.015 02-22-94 L1 131-94 Mercur 7470 <0.0002 0.0002 02-09-94 L1 131-94 Mol bdenum 6010 <0.067 0.067 02-22-94 L1131-94 Nickel 6010 <0.040 0.040 02-22-94 L11 31-94 Phos horus 6010 <0.050 0.050 02-22-94 L1 131-94 Selenium 7740 <0.005 0.005 02-25-94 L1131-94 Silver 6010 <0.010 0.010 02-22-94 L1 131-94 Strontium 6010 0.13 0.10 02-22-94 L1 131-94 Thallium 7841 <0.010 0.010 02-28-94 L1 1 31-94 Tin 6010 <0.20 0.20 02-22-94 L1 131-94 Titanium 6010 <0.10 0.10 02-22-94 L1131-94 Uranium 6020 <0.001 0.001 03-07-94 L1131-94 Vanadium 6010 <0.050 0.050 02-22-94 L1 1 31-94 Zinc 6010 <0.020 0.020 02-22-94 L1131-94 Comments:
| |
| | |
| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 1 of 2 Clien S m I ID: TFALL 0 1 LAL S m I ID: L11 1-41 D e C llec ed: 24- AN- 4 Da e.Receive: 2 -JAN- 4 Matrix: WATER Date Anal zed: 03-FEB-94 Anal tical Batch ¹: 020394-8260-J-2 Dilution Factor: 1 QC Batch ID: 020394-8260 SURRO ATE RECOVERY o QC Limits 1 2-Dichloroethane-d4 98 76-114 Tol ene-d 4-Bromofluorobenzene 97 86-115 Reporting Concentration Detection Limit Con ti e L L De Q 'ifier Chloromethane <5 Vin I Chloride <5 Brmm hn hir hn Trichlorofluoromethane <5 Acetone <10 10 11-Di hl r h n r n Di Ifi Meth lene Chloride <5 trans-1 2-Dichloroe hene <5 Vin I A 11-Di hl r h n 2-Butanone <10 10 cis-1 2-Dichloroe hene <5 hlr frm 111-Trihi r h n Carbon Tetrachloride <5 1 2-Dichloroethane <5 B nz n Tri h 1 2-Dichloro ro ne <5 Bromodichlorome h ne <5 hl r h IVin I h r <2 4-M hl- - n cis-1 3-Dichloro ro ene <5 Toluene <5 rn-1 -Dihl r r n
| |
| -H x n n 1 1 2-Trichloroethane <5 Tetrachloroethene PCE <5 14 L LOCKHEED AIVALYTICALSERVICES
| |
| | |
| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING IVIETHOD 8260 Page 2 of 2 Client Sam le ID: OUTFALL 01 LAL Sam le ID: L1131-41 Reporting Concentration Detection Limit Constituent IL IL Data Qualifier s Dibromochloromethane <5 hlr n n h I n n m -X lene <5 o-X lene <5 Srmfrm 1 1 2 2-Tetrachloroethane <5 1 3-Dichlorobenzene 14-Dihl r nz n <5 1 2-Dichlorobenzene <5 LOCKHEED AhfALYTICALSERVICES
| |
| | |
| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 TENTATIVELYIDENTIFIED COMPOUNDS Client Sample ID: OUTFALL 001 LAL Sample ID: L1131%1 Date Received: 264AN-94 Date Analyzed: 03-FEB-94 Matrix: WATER Dilution Factor: 1 Analytical Batch: 020394-82604-2 QC Batch ID: 020394-8260 Identified Estimated Retention Concentration Time Data Tentatively Compound Iyg/L) lminutes) Qualifier(s)
| |
| NO COMPOUNDS IDENTIFIED LOCKHEED AIVALYTICALSERVICES
| |
| | |
| SEIVIIVOLATILEORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Pa e 1 of 2 Clien S m I ID: OUTFALL 001 LAL Sam I ID: L1131-55 Date Collected: 24- JAN-94 r:
| |
| Date Received: 26-JAN-94 Matrix: WATER Dilution Factor: 1 Anl i IB h4': 2 4- 7 -A Da Ex 1-JAN- 4 QC Batch ID: 8270-SEMIVOLATILE 4825 Date Anal zed: 03-FEB-94 SURRO ATE RE OVERY Y 0 Limi 2-Fluoro hanoi 27 21-100 Phenol-d, 22 10-94 Nitrobenzene-d, 64 35-114 2-Fluorobi hen I 57 43-116 24 -Tri r mo h n I 48 p-Terphenyl-d 37 33-141 Reporting
| |
| ' Concentration Detection Limit n L De lifi s Phenol <10 10 bis 2-Chloroe h I ether <10 hlr hnl 1 -Dihl r nz n 1 4-Dichlorobenzene <10 10 Benz I alcohol <10 10 1 -Dihl r n
| |
| -M h I h n I bis 2-Chloroiso ro I e her <10 10 4-Me h I henol <10 10 N-Ni r -Di-n- r I in Hx hlr hn Nitro benzene <10 10 Iso horone <10 10
| |
| -Nir h n I 4-Dim Benzoic acid <50 50 bis 2-Chloroethox 1
| |
| 4-Dihi r 4-Trihl Na h halene 4-Chloroaniline r
| |
| h n n
| |
| I me hane n 10'0
| |
| <10
| |
| <10
| |
| <10 10 10 10 H hlr in 4- hlr--m hlhnl 2-Meth Ina h halene <10 10 Hexachloroc clo entadiene < 10 LOCKHEED ANALYTICALSERVICES
| |
| | |
| SEMIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Pa e2of2 Client Sam le ID: OUTFALL.001 LAL Sam le ID: L1131-55 Reporting Concentration Detection Limit Constituent I IL) I IL) Data Qualifierls) 24 -Trihl r hn I 4 -Trihlr hn I 2-Chlorona hthalene <10 10 2-Nitroaniline <25 25 Dim h I h h I A n hhin 2 6-Dinitrotoluene <10 10 3-Nitroaniline <25 25 A n hhn 4-Dini r h n I 4-Nitro henol <25 25 Dibenzofuran <10 10
| |
| '4-Dini r I n i hlhhl 4-Chloro hen I- hen le her <10 10 Fluorene <10 10 4-Ni r nilin 4 -Dinir - -m I h n I N-Nitrosodi hen lamine <10 10 4-Bromo hen I- hen le her <10 10 Hx hlr nzn Pn hlr hnl Phenanthrene <10 10 An hracene <10 10 r I Di-n- I hh I Fluoran hene <10 10 P rene <10 10 8 I n I hh I
| |
| '-Di h r Benzo a an hrac n <10 10 Chr sene <10 10 i - hlhx Di-n- I hh I Benzo b fluoranthene <10 10 Benzo k fluoranthene <10 10 Bnz rn In n 1 r n Dibenz a h anthracene <10 10 Benzol h i) er lene <10 10 LOCKHEED ANALYTICALSERVICES
| |
| | |
| SEMI-VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8270 TENTATIVELYIDENTIFIED COMPOUNDS Client Sample ID: OUTFALL 001 LAL Sample ID: L1131-55 Date Received: 264AN-94 Date Analyzed: 03-FEB-94 Matrix: WATER Dilution Factor: 1 Analytical Batch: 020394-8270-A QC Batch ID: 8270 SEMIVOLATILE 4825 Estimated Retention Concentration Time Data Tentatively Identified Compound (yg/L) (minutes) Qualifierls)
| |
| NO COMPOUNDS DETECTED LOCKHEED AIVALVTICALSERVICES
| |
| | |
| OIL AND GREASE EXTRACTABLES ANAI YSIS RESULTS BY FT/IR USING METHOD 413.2 Client Sam le ID: OUTFALL 001 LAL Sam le ID: L1131-75 Date Collected: 24-JAN-94 Date Anal zed: 07-FEB-94 D R iv:2 -AN-4 Dil inF r 1 M rix W D r -F B- 4 Anal tical Batch ¹: 020494-413.2 QC Batch ID: 020294-413.2 Reporting Constituent Concentration Detection Limit Data Qualifier(s) m L Oil and Grease LOCKHEED ANALYTICALSERVICES
| |
| | |
| PESTICIDE ANALYSES RESULTS BY GC/ECD USING METHOD 8080 TFALL-0 D oil:
| |
| li n S m I ID:
| |
| 4- AN- 4 Date Extracted: 31-JAN-94 1 LAL D e Re m I eiv:
| |
| ID: L11 2 -
| |
| 1-AN-94 Date Anal zed: 01-FEB-94 Matrix: WATER Dilution Factor: 1 Analytical Batch ¹: 013194-.8080-E-4 QC Group ID: 8080 PEST/PCBS 4822 S RRO ATE REC VERY QC Limits TCMX 50 60-1 50 DCB 39 60-150 Reporting Constituent Concentration Detection Limit Data Qualifier(s)
| |
| A-BH B-BHC <0.05 0.05 G-BHC <0.05 0.05 D-BH H PTA HL R ALDRIN <0.05 0.05 HEPTACHLOR EPOXIDE <0.05 0.05 HL R DANE END FAN I A-CHLORDANE <0.05 0.05 4 4'-DDE <0.1 0.1 4 4'-DDT DI LDRIN ENDRIN <0.1 0.1 ENDOSULFAN II <0.1 0.1 4 '-DDD NDRI A D HYD ENDOSULFAN SULFATE <0.1 0.1 METHOXYCHLOR <0.5 0.5 T XAPH NE P -1 1 PCB-1221 <2 PCB-1232 P B-1 42 P B-1 4 PCB-1254 PCB-1260 TECHNICAL CHLORDANE 14.
| |
| LOCKHEED ANALYl'ICAL SERVICES
| |
| | |
| RAO OATA REPORT (ra01)
| |
| Indiana Hichigan Pomr Co. e Bridgman,NI Organic and Inorganic Contaeinanta (Project C(XX.JENI)
| |
| Client Sangria IO: OITFALL 001 LAL Sanpla IO: L1131.b5 Oate Collected: 24.JAN.94 Oate Received! 26.JANE 94 Hatrixt llater Login Nuaber: L113'I 8%3F''Co()akl ttientg""44Mi@KN~>w"~Anal)Iaed:"' SetcIT~<-~5~~i'"" Qi'F:."'<~)'..'".""."ActiVf>Q',5.'rotg~gj'N@:-:. ~~ i>Oatmeal':::~lUnita;."., '.
| |
| Gross Alpha 23-FEB 94 GR ALP/BETA LAL~ 0060 4756 0.4 1.1 2 pCi/L Grosa Beta 23.FEB.94 GR ALP/BETA LAL.0060 4756 3.2 1.5 2.2 pCi/L Page 6
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| | |
| RAD DATA REPOP.T (ra01) lndfana lffchfgan P~r Co. ~ Brfdgman,NI Organfc and lnorganfc Contaninanta (Project CNX.JEkf)
| |
| CI fent Sarpfe lOs OUTFALL 00'I LAL Saepfe ID: L1131-89 Date Collected: 24.JAk.94 Octa Recefvedt 26.JAk.94 lfatrfx: Rater Logfn ktnhert L'l13'I Ra-226 22-FEB-94 RA 226 LAL-0073 4771 0.02 0 11 0 22 pCI/L Ra-228 23-FEB.94 RA 228 LAL-0074 5503 3 0.44 0.59 pCI/L Page 10
| |
| | |
| PH Analysis (LAB.079)
| |
| PH Meter CPC /P lOL-Cal date due Outfall 001 Sample Time 0 p o Sample g Sample Date CDM Entered by ~K=
| |
| : 6) Sample C/ph (prior to .9E g O2. 7e 7 correction) 5.3.5 7) NH3 pH correction 5.3.6 8) )ample results C/pH (after '7.7 P NH 3
| |
| Correction)
| |
| Sample Sample Time Sample $j Sample Date CDM Entered by
| |
| : 6) Sample C/ph (prior to correction) 5.3.5 7) NH3 pH correction 5.3.6 8) Sample results
| |
| 'C/pH (after
| |
| ~
| |
| Correction)
| |
| : 9) LAB.041 Specs Verified by: h/IR Supervisor Review/Date W+l& Form prepared by/Date Form approved by/Date 12 THP LAB.041.25s Revision 1
| |
| | |
| Determination of Total Chlorine Instrument CPG(j 50 ~
| |
| (Lab 170) Standard ICN-CIDj( 2-5 I ~
| |
| Outfall 001 Technician Sample/Standard Sample g Date Time 3D CDM Entered by
| |
| : 1) Absorbance 6.11 2) Results, ppm C.w 3} Dilutions made
| |
| : 4) Results, ppm
| |
| ((I2
| |
| * 8 3)
| |
| : 5) 1AB.041 Specs Verified by:~)9 Supervisor Review/Dote~MR t Form prepared by/Date Form approved by/Date 12 THP LAB.041-25]l Revision 0
| |
| | |
| SEE INSTRUCTIONS ON REYERSE SIDE SECTION I I PERMIT NUMBER ~ NZ 0005827
| |
| ~00 2 A~ LCCAT IQI OF Dl SCHARGE
| |
| ~SW e, ~W i, we-(TIWI e~06, iiNS ~0,6 S TJIISE ~l9 W B. ''W CF RECK!vltO WATER i!E. 'RcuWATER CR NAE C SLRFACE LiA KiE i4TZ CiHTZ G A N N
| |
| C. OO YOU DISCHARGE SEASQtTALLYY DISCHARGE (IF NQe Ccttt!tATE TO E) YES LOCATION De IF YESe I.IST DISCHARGE PERIODS NA e'Oe / %Y eOe / DAY SCHEDULE FLOW
| |
| ~ ~~
| |
| RATE WASTEWATER INe/tR.
| |
| ~TY ~D Ee LS/iD APPLICATION RATE
| |
| ~ LJ LLJWRe/DAY
| |
| ~ LJ INe/WKe
| |
| ~ EI N CONTACT WASTEIIATER IYPE COCE F>> TYPE OF WASTEWATER DISCHARGE COOLING L~J NONCONTACT COOLING Ge D ISOIARGE SCHEDULE (YEARLY AVERAGE)
| |
| IOISIS/DAY ~24 eeevzwee DISCHARGE FIDH RATE !NIT~CODE PROCESS He TOTAL YEARLY p p SANITARY STORMWATER DAILY MINItTPI 0 ~2
| |
| ~NIT c 00 IXTILY MAXIPAM 1 820 ~2 1
| |
| 2 MGY MGD I ~,HE MAXIMKADISCHARGE FIDtt RATE TO BE AUIHCRIZED IN PE%IT. 1 820 2 3 GPD e"AXIS DES!BI DISCHSRGE FLDI RATE ~
| |
| DESIGN 1 820 wIE QXIE Ae CO YOU USE HATER TREATIENT ACDITIVES TO TREAT YTXR DISCHARGE?
| |
| (IF te, CONT!tAE TO ITBI 3)
| |
| ITEM 8~ NAtE Futct!CN, AND c!EHICAL COMPOSITION CF THESE AlXIITIVESe 2
| |
| WATER TREATMENT NA ADDITIVES Ce rt/ME AND ADCRESS OF MAIAFACTIRERS OF TIESE ACOITIVESe UNITS CODE 1 Mg/I 2 Ug/I NA
| |
| ~
| |
| MIN INDI UN I TS AVERAGE IttITS MAXltSPI D. EXPECTED DISCHARGE CctCENIRAT ION CF AID IT!YES. NA CODE CODE ADDITIVE NAtE AcolTIYE NSr%
| |
| ADDITIVE NAtE LJ/ LJ E, DO Ymt TREAT TIE DISOURCTE 10 RBQVE ACOITIVES? 'NA Q YES F. wHIT IS THE RBQVAL EFFICIENCY AND DISCHARGE FREILKNCY. NA K RBOVAL HRS /DAY DAYS/W.
| |
| ADDITIVE NAIE LJ ADDITIVE NAME ADDI T I VK NAtE G~ AS AN AITACttENT TO IHI5 APPLICATICN PROVIDE SPECIFIC MA!tVTLIANCR AOUSeTIC TOXICOUIGICAL DATA CR REFKRBICE WHICH ARE AVAIIABIEAND INFOBQTICN ON THE RATE OF DEGRADATION OF TIE PROIXCTS FOR EACH A!OITIVKe NA
| |
| | |
| 30 SEE INSTRUCTIONS SECTION I I PERMIT
| |
| ~ My pppg827 ON REVERSE SIDE AIII'ALLtUKR I ~OI ~2 A~ %4K OF PROCESS CCttlRIBUTING TO THE DISCHARGE
| |
| /ROUGH THIS OUTFALL <<8 SIC CCCE WTR 49 I I ~
| |
| B~ PROCESS SCHEDULE (YEARLY AVERAGE) tOLRS/DAY ~24 /v PROCESS Ih Ih IAI Ct~
| |
| C. PROCESS WASTEWATER FLCW RATE TOTAL YEARLY 48,0844 ~5 STREAMS 0 Basis: 1993 actual data submitted CONTRIBUTING On DMRS DAILY MINIMA u6 TO OUTFALL DAILY MAXIP%B 1743 ~6 D. PROCESS PRODUCTION RATE DISCHARGE
| |
| ~
| |
| Av AX<<"E GF PROCFSS CCttmIBUTltIG TO THE DISCHARGE THROUGH THIS OUTFALL AIID SIC CA/DE NA B. PROCESS SCIEDULE (YE/UILY AVERAGE)
| |
| AVYAVY/OAY DAYY/VYAA Ih Ih CA PROCESS WASTEWATER FLOW TOI'AL YEARI.Y 00I RATE'.
| |
| 0 C',
| |
| 0 DAILY MINltRH 1 POUNDS DAlLY M4XItul 2 GALLONS PROCESS PRODUCTION RATE 3 CUBIC A IIAtE OF PROCESS CONTRIBUTItIG TO THE DISCHARGE YARDS IHIOUGH THIS OUIFALL AtiD SIC CODE 4 TONS BA PROCESS SQELX1Z (YEARLY AVERAGE) 5 MGY 6 MGD C. PROCESS WASTEWATER FlOW RATE 7 GPD TOTAL YEARLY DAILY M INIMM DA I I.Y D. PROCESS PRODUCTION RATE UNITS /TIME TIME 1
| |
| 2 3
| |
| 4 5
| |
| HOUR DAY WEEK MONTH YEAR A.
| |
| B.
| |
| Cv NA% OF PROCESS PROCESS TH CONTR IBUTIttS TO TIE DISCHARGE AND SIC CODE SCHXILE (YEARLY AvERAGE)
| |
| PROCESS WASTEWATER FLOW RATE NA MAXI'vvAVY/AAV TOTAL YEARLY
| |
| ~ AAVY/VYAA INIT CODE DAILY M IN INN DAILY ."AXINJ4 WITS /TIPE Dv PROCESS PRODUCTION RATE AA NAtE OF PROCESS CONTRIBUTING TO IIE DISOIARGE
| |
| , THOROUGH THIS OUTFALL AND-SIC CODE PRXESS SCHEDILE (YEARLY AVERAGE)
| |
| ~
| |
| B~
| |
| AAVY/VVAA UNIT Cv PROCESS WASTEWATER FU)/t RATE TOTAL YEARI.Y DAII.Y MINION D. PROCESS PRODUCTION RATE DAILY MAX!AN UNITS / TIVE 33
| |
| | |
| <<$ <<<<3 ~ 3 ~
| |
| 1 <<<<J ~
| |
| I 3$ <<r n, SC al 8 3 OC (8 ~ I 8 J W ra 8 a C <<ater <<3, 8<<
| |
| '5 l <<*
| |
| ahJI -'=,=:= <<I: ='.=".
| |
| 8<<<<3 I t
| |
| >>= =Soul T '.'"=R Ah ":= C:bh0
| |
| <<<<\ ''"E;R"!Jt oAGE 7 YCIIR EXPIC't'r 3 8 Si 8 J V en .Save I af << ~
| |
| << ~ 5$ )c A<<
| |
| x w<< << 5 5CO Vi<<OC i 8<<1 3CB Sec Icn I'. =cr <<ac-:"<<Iv'a< c:scharce Ccint 3 Secarate 3~ 3 c' 5
| |
| 1<< ' ~ ' ~ IS ~ 3 8 35 3, ~ "Iuce ".'r.et'var Or Sec CtJ. 'at et'8C, io1, 38CC ~ Cn. (Own, and range ~
| |
| JsT << .8 ece" vi.g <<8 el Iif sul I )ce <<atef o:sc, al <<8).
| |
| '1CicaTO <<hetter '3ci. Tv cischarces ",", 3 5835 1al basis.
| |
| ( f yes, i I St C I scnarce car leds.
| |
| -rovlCe -"e 331C OCR)Ication rateS csee cr Oxbected to be used In terrS Ct'nCneS Cer "our, ~curS Cer dav, and Incres per <<eex.
| |
| Indicate -ne <<vce of wastewaT8I o be isc.. reed frcn this cutfall. nefec to the wastewater tvae ceca oiven In tne left
| |
| -atgln. VOre -Can One COCe may Oe aabliCable.
| |
| 3":vice --e :r clli er,ear << t, <<<<St Oversee nvnber cf "ours .Ot :av O
| |
| <<nic .8 x ~ v 3cnat'$ ~ ea <<c <<as Owater 3 8 Tai number of days 3"OVICO C.rt ant:frcn the 185t I" nontnS) Cr OXOeo,eo 3 ICW rateS 85 reoueSTed. Refer tO unit Cede OiVen In the left margin FOr The 3cbroariate flow units. '4Y - million ca)lot 5 der veer: '40 - million gat lons Der Cay; N) - gallonS Oer day.
| |
| o-ovlce -te -axi"um cisc1arge f tow rate wnlch vou ant 31 wave author I ted '<<itl'In 18 bernlt. 'J0T~: mor 'JnoEs bermits onlv, "e use f Such 3 flow rate <<ill nct blaco an actual Jlnlt restriction on the flew ut will be tne flaw rate used to develoo effluent Iin(ts. 3)so, <<nen tne Ivcnthiy Cberating Reborts are reviewed bv conoltance staff It will helo tham to determine if any new or increasec uses mloht have oocurreo at the facility,.
| |
| !. nrov)de t"e design 'Io>> for this soeciflc outfall discnarce Ie.g. batch <<reatnent svstem flow, cackaoed treatment system flew, or sore tner finite treatment system flow).
| |
| TIATSR TREAT'IS'lT PDOITIVES
| |
| 'ncicate <<nether clscharce Is treatec <<a'tn onc) tloners, inn)bi tors or m)crob)deice.
| |
| ~ t I noT, continue to item 3.
| |
| :ive name,,;nCticn, and Chemical CcncOSi tion Of addltlues <<Sed.
| |
| .) Je 13J 8 3nc Ncress 1'8 nanufac 3 o \5) of the addi tivns used.
| |
| "c)cate J<<cec<<ec n)nimun, averaoe 81<<. "Sxi-um discnarce ccncent<<atlons of 318 adoitlveis) 'cr -1ls:Ischarce.
| |
| -c'Ira-8 -<<<<er .Cu - <<3- -"8 $ '.Sc~!rce ". -~ve -"8 Scc -)veis):o',cre clscrarce o'stewater.
| |
| '"dicate "8 removal 8'f tc:Oncv . <<ach acdi tive frcn .he astewater and the discharoe frocuencv of each addit>> Je to the 3 'rtaoe <<3,8<<
| |
| '- 'I -8 resocnsibili v c'. -Te aecJtcant To suoolv the arocuct '.nfottta!Ion as recuested In this Item 4. Information r dues>>c bct -ot Svbbliec ~av result l1 t"8 abo Ilcat)81 bel"o r<<Tur18c to ~ he aoolicant 'or comoiet)cn.
| |
| 32
| |
| | |
| SECTION II PERMIT~
| |
| NUMBER Mt 0005827 SEE INSTRUCTIONS ON REVERSE SIDE
| |
| %IF%. IlÃB ~0.0 2 A. IS ISE DISCHUIGE FRCM THIS CUTFALL DIREC1ED TO BIE GRQNsD GR GRQU7CWATERS? (tF tO, CONTlttUE TO ITEM 5) YES X B ~ HAS A HYDRQGEQLCGICAI. STUDY GR ITS EQUIVALENT BEEN PERFGIYED OR IS THERE SIFF ICIENT cURRENT HYDRGGEQLQGlcAl. INFORMATION AYAttaBLE As REQUIRED BY TI4 wATER REsQURcE's CI:Es NQ CGtltISSINI PART 22 GROlGIWATER RULES OF ADJUST 1 s 1980 R 523 22O7 (PAGE <<Q)
| |
| GROUNDWATER THIS EXIS'TING OR PROPOSED DISCHARGE? IF YES ATTACH A COPY CF THE REPORT. NA DISCHARGE C. ARE YQU REQUES IIO AN EXEMPTIGN FRCM SUBMITTtt2G A HYDROGEQLOGICAL REPORT Ut2QER INFORMATION RILE R.323.22(I7 (7{}) (PAGE LNDER RULE R.523.24'5) g) OR FROM GROLCIDwATER MONITORING t)EQUrtREMENTS (PAGE Ug) QF THE PART 22 RLLEs. IF YEs ATTAcH DOQRENTS AND EXPtattATICtt TO DBONSTRATE THAT Y(XFI DISCHARGE HEXAD QUAt.lFY FOR NA AN EXP'' ION.
| |
| Ds ARE YGU REQUEsTlto A vaRIattcE FRcM RIAE 323.22(5 (PAGE L~) (NQtmEGRADATIGN) 0F THE WATER RESOURCES CCtltISSICN PART 22 GRIEtDWATER RULES? YES IF YES ATTACH SUCH DOCUMENTS AS NECESSARY TO DEMON@RATE THE NEED FOR A VARIANCE IN TERMS OF BE cRITERIA sPEcIFIED IN RIAL 525s~o (PAGE ~ 0F THE PART 22 RULEss NA Es I,IST AIJ. CtetICAL Su)STANCES WHICH ARE IN MICHIGAN S CRITICAL MATERIALS REGISTER TABLE IV (PAGE tt) AND/QR Uss EPA s PRIcRITY PQILUTANT LlsT TABLE v (PAGE 7) cR ANY 0THER
| |
| ~
| |
| slssTANGEs NQT APPLICABLE/BELIEVED ABSENT HIICH ARE OR HAY BECCA INJIHIOUS TO BE DESIGNATED USES OF BE GSXSQHATER OR ID THE PUBLIC HEALTH THAT ARE DISGORGED OR EXPKTED TO BE DISCHARGED TQ THE GRQUIDtATERAY THIS FACILllYs ESTIMATE BIE FINAL EFFLUENT CONCENBIATION AND RECCRD ALL DATA IN ITEM 7 OF NA SECTION I I IN THIS BOO@ET.
| |
| BE
| |
| ~
| |
| APPLICANT MAY BE RECUIRED TO DO ADDITIGttAL HASTE ANAL'(SESs PRESENTi DATA PROVtDED IN ITEM 7 As DISCHARGE CHARACTERISTICS CONCENTRATION wtTS cQDE II ANALYsES TYPE tTEM u1 CODE u
| |
| 5 BQD5 COD (FIVE (OetICAL DAY BIOCIEHICAL OXYGEN DEMAt4t)
| |
| OXYGEN DEMAttD) ul LJ EXPECTED TOC (TOTAL ORGANIC CARBON)
| |
| WASTEWATER CHARAC- 'un' a N I TRQGEN (as N) u1 slcs TOTAL SUSPENDED SOLIDS u1 u UNiTS CODE ~ TOTAL hOSPHNUS (AS P) 1 Mg/I 2 Ug/I TOTAL RESIDUAL CH.CRINE 3 COUNTS/
| |
| 100 ml DISSO!.VED OXYGEN MIN ul
| |
| .4 S.U.
| |
| 5 'F 'PH ~7 ~0 6 LBS/DAY FECAL COLIFORM BACTERIA u3
| |
| ~ERATU2E 1
| |
| (sue+) ~73, u5 ~89 u7 u5 u1
| |
| ~iERATIRE (wINTER) ~60 u4 u5 ul Bs OTHER WASTEWATER CHAIIACTERISTICS 0 I L tt G R E A S E u u u I SAMPLE 1
| |
| ZXEF GRAB 2 24 HOUR u
| |
| COMPOSITE SEE ATTACHED SHEETS FOR ANALYSIS DATA u ~ LJ
| |
| * Basis: 1993 actual data submitted on DMRS RECIIIRED INFORMATICN FOR SURFACE HATER DISCHARGES ~
| |
| 35
| |
| | |
| I I ~
| |
| J" "e s l "" " r 'S ISC a res asr s C 35$ S3rS 5 I
| |
| (
| |
| i elf Srv sr Sc'. tv. -", en 'esvs : 'nk 0-c 3 nvr cer wi II Os 355 rchec.
| |
| -.-Cer " SCSCe vfcst r sk ssss =cr eac- 'sdlv:dual Iscnarce ccir t 3 se ara e set cf e J I re s 5 ITCH 3 rJ Jo CCC 5 3 'll u+ CT J sf r- ',I.PCcuATIC .
| |
| 3"-er -"e "3"s '"e prcCeSS <<niC" Cc"~"'C.tes - -sIS 5 SCnalCe. --"vrce --e " ""er -IC -""e "clca-e -;e vearlv Sverage process S=hecule r "cuts cer cav nc cavs-:er-lear.
| |
| . ~ provide tne process wastewater flow rate information as recuestec based on your last l2 rrrcnths of operations. rtefer to unit code given in the left natcin for the appropriate flow units .
| |
| p ocess production cate - certain per rit I:rritatlons lrrav oe cased cn production rates. The production rates used to letsrnlne Cernit limits Shall e repTsSen-ed >V 3 reaSCnapie rSeasure C <<C-ual CrCCVCtiOn Cf the faCI orevlcus IISV, SVCn aS averace for the nirihest of,r e five years, or tne.. lasonaple "easvre as 5 steo rn 3 0>
| |
| ~ re '.-,
| |
| :t" "otic" ccln" "e "icn rent% cJ "e cre'llcu5 'lea. cr.-'..neer rcnthlv ~
| |
| -eccr'csr - res Src "scvlations.
| |
| r ew 5 Jp(es cr'sw ci scnar'cel 5 ~ a . <el T tn 5sar ), e est feats S Inc ro lecsed production
| |
| .C r 3-CCVC lcn rs-es in --s -Srst Sno ..'-5 .Se ',n tro SCCI Jcac,e,.=.=.;.A. Cate"Orioal ruieS Snd neouiaticnS Cr'
| |
| | |
| SEE INSTRUCTIONS ON REVERSE SIDE SEGTlON II PERMIT NUMBER ~ ME 0005827 (NFJILL MB ~00 2 lM r>>>>E FQUDWIMG REQUESTED INFORMATION 6'>>J USE DISCHARGERS ~s>>'RQVICE e~r ADDRESSED av a>>'URFACE WATER DISCHARGERS, EJECTED VALUES FCR IHE QUANTITATIVE AM 6 QUALITATIVE It<FORlQTIQM REQUESTED BKLQW.
| |
| A.:S THIS FACILI1Y A PRIMARY Il<DUSTRY? (REFER TO TABLE IA PAGE 4+ YE <JQ SQ TO E) (tF v<s GQ TO 3)
| |
| PRIORITY POLLUTANTS B. INDICATE TYPE CF PRIORY INDUSTRY AS LISTED IN TABLE tA PACiE 4+.
| |
| Jurat AJE WITH C.) STM ELEC PMR AND C XES IRIS OUTFALL DISCHARGE VlaAIN AllY PROCESS WASTE'>>JATER?
| |
| (IF X YES (IF M GO TO E) YES GQ TO O)
| |
| ADDITIONAL iNFORMATION O>>NDICATK WHICH GC/tYJ FRACTIONS Wsf BE TFSTED FOR ~
| |
| (REFER TO TABLE IA P4% U~I X vQLATILE FOR SURFACE WATER
| |
| ~MH FRAcTtQN ~
| |
| JQIEI FcR EAcH Gc/Hs FRAcTIQN cHEcKED, EAcH sPKclFIc QRGANlc Toxic POLLUTANT 'WITHIN
| |
| ~
| |
| BE ANALYzED F0R (sEE TABLE IIA PAGE IJ2, IN ADQITIQN>> AU. PRIMARY IMUSTRY APPLICANTS.WITH a PROCESS wasTKWATKR otsoURGE DATA FOR EACH TOXIC POUIJTAMT IM TABLE IIIA Pal< 4+~
| |
| PRQVioE QUAMTITATtVE X BasE/MEUIRAL DISCHARGE ACID ONLY RECORD ALL DATA ON FORMS PROVIDED (ITKH 7) IN THIS BOOKLET>>
| |
| PESTICIDE **
| |
| (CCNTttAJE 'WITH E K BOX')
| |
| CI E~
| |
| ~
| |
| IF ~< SURFACE WATER DISOIARGE APPLICANT (PRIIVUIY OR SECCNDARY IMIVSTRY)>> REGARDLESS OF THE TYPE OF DISCHARGE>> KMWS OR HAS REASON To BELIEVE THAT ANY POILUTAMT LISTED
| |
| ~IN TABLE I IA AND IVA PAGES BE PROVIDED>>
| |
| Is DISCHARGED FROI ANY OJTFALL THE QUANTITATIVE DATA wr. APPLICABLE/BELIEVED ABSENr RECCRD AU. CATA ON FORMS PROVIDED (ITKH 7) IN THIS BOOKLET>>
| |
| OX PRESENT/DATA IS ATTACHED F. IF JUJY SURFACE WATER DISCHARGE APPLICANT (PRIHARY OR SECONDARY INDUSTRY), REGARDLESS X MT APPLICABLE/BELIEVED ABSENT QF TYPE QF DISOIARGE>> IQJQWS OR HAS REASON TO BELIEVE ANY POultfANTS LISTED IN TABLE VA PAGE ~Q ARE DISCHARGED FRot ANY CtffFALL THE APPLICJUIT REASONS FOR THE PIKLUTANT BEING PRESENT ANO PROVIDE ANY AVAILABLEQUANTITATIVE DATA>>
| |
| t~ DESCRIBE RECCRD ALL DATA ON F(XttS PROVIDED (ITEN 7) IN THIS BOOKLET>>
| |
| G>> AU. SIRFACE WATER DISCHARGE APPLICANTS (PRINRY AND SECONDUIY IMXJSTRIES)
| |
| - X wr APPLIQABLE/BELIEYED ABSENT 2, 4, TtttostxtQPIEMKY AQETtc Acto (2, 4, 5-r);
| |
| -(l,
| |
| ~
| |
| QR HAMLFActutES j
| |
| 4, 5-TRIQHLDRQPWEMxY PRQPAMIC acto (SILYEx, 2, 4, 5, TP)
| |
| >> 4>> &IRIotJxtcPHEML (TcP); 0R HExAcKoRQPtK% (HP); (ALL DATA F0R THE ABOVE i%ST BE GENERATED USING STJUIQARD ANALYTICALCALIBRATION PROCEIXRES) OR
| |
| ~
| |
| Kilty's OR HAS REASON TQ BELIEVE THAT TCDD REPORT QIALITATIVE DATA>> GEIERATED cALIBRATKD 'WITH ANALYTlcAL sfANDARDs, F0R tS OR HAY BE PRESENT tN TKIR DtsCHARGE>>
| |
| le IOI USED A SCREENIW PROCEDNE MT
| |
| : 2. 5. / 8>> - TKtttaotoRQDIBEMzo-P DloxlN (TCDD)>> RECORD ALL DATA ON FORFAR PROVIDED (ITEM ) IN THIS BOOKLET<
| |
| Q PRESENT/DATA is arraoED
| |
| ~',F r>>'E SURFACE WATER DISIHARGE APPLICA<VT KMWS OR HAS REASON TQ BELIEVE 1>>ar Mr APPLICABLE 3IQLGGI(AI a~xlcllY TEsTs 'WERE MADE IN THE LAsT THREE (5) YEARs 0N Attr 0F THE 4VLICAVT S DISCHUIGES CR ON A RECEIVING HATER IN RELATION 10 A DISCHARGE>> PROVIDE THIS INFQRHATICN AS AN ATTAotEMT TO THIS APPLICATION>> APPLICABLE/SEE ATTACHED
| |
| :F A CQMIRACT LU}QRATCRY CR CQNSLLTIW FIRN PERFORMED ANY OF TIE <UAAYSES REQUIRED BY THIS APPLICATION>> PROVIDE THE NAME AND ADCRESS OF EACH LABCRATQRY OR FIRN AM THE JVJALYSES PERFCAKD AS AN ATTAOtENT OF THIS APPLICATION>>
| |
| Q MT APPLICABLE X aPPLIQABLE/SEE arfacHED QQ YQU DlscHARGE ANY 0THER Toxic QR IMURIQUs {KHIQALsutsTAMQEs NQT LIBTED IN TABLES IV PAGE (I AIO I IA THIQU4t VA PAGES ~~< t~ vES>> THEN IDENTIC THE MT APPLICABLE
| |
| ~MAGICAL SUBSTANCES JVJD ESTIMATE THE FINAL EFFUJENT CONCENTRATICNS. SIEPIIT THIS t<VQRHATICN AS AN ATTAOt%MT TO THIS APPLICATION>> APPLICABLE/SEE ATTAOIED
| |
| * See whole effluent test data attached to Outfall 001.
| |
| ** Pesticide data is not required;. however, it is provided.
| |
| | |
| ~ >>o>>
| |
| >>--u 8 5 5 ~ 35 'c e 5 r c e *ate('5 n
| |
| 5 3 "e>> cr "" "ev ~- -' --eh leave b>>anx 31c 3 "u, oet <<>>II ce asslcrea.
| |
| 4 0 - - e 5-a-e as a $ e<< I >> JSC CSV 'sl SC bt >>a <<<<>> 5e<<a 5 <<'5 8
| |
| >> 5>> -3.e -.O :" Cre Subeta"T '., '.v '"cent'. as c.tassts ~ u av 'vest cermiss(cn 'rara vcur =e<< ~ -'"" avt"cr'Tv I ble 5 . 3" Ss' rsv:le l" 3 3 <<5 tsl 5 4Sus
| |
| ~
| |
| 5 . e aha a VS>> 5 I Toes 5 Jbstantl as Is I en 3
| |
| .3( utf SI IS.
| |
| sour Sc.eST "S,,rantea bv-- 5 ca~it-Iran autncrl-v,:n a secarate s"eet ettac1ec -.". "e aaotlcaticn t"t '=enr''v caser. e rv -"e S.tasl IS *niC1 vCu cic 1OT -eST std S.ostarrias Iv lcenti 5( TO the Out'.al I
| |
| *1sal . a a 55t.
| |
| '3 3
| |
| I s
| |
| ~ 8 a as 3 as s '5 ~ e55 %e<<action ~ . r. Tte e cs' ~ c ct sflTI Tatsve cr zr eric toxic collurantS Sna TCXIC OS luranTS SS reauirea by mart a 22 Zl (a) (7) (I i ) (A) Or IZZ ~ 2l
| |
| ~ (8) (7) (I i I ) (A) .
| |
| vase oart5 3re self<<exolanarcrv Sna o not reauire '>>.rtt et Inst( ucticrs . Slmc lv a)o Tt'tcuan eben carp 3<<a .o as sncicated.
| |
| 53 ".''5 '3>> 3 ea r>>es a I <<er' 85 5/5 ee<<e>>>>C O e > 5 ' 5 Cn ~ <<sin '9/a+ " 3<< ICns
| |
| >>IVI>>t>> "<<SOS "Sss Scectrtscccs.
| |
| <<l<<C 5 l5T
| |
| ='racrions.
| |
| O Cet>>3 9 <<s>>etre<< ~ l'. '3 ' v 5<<as 35 ". e g>>amer s g <<e<<cr 5<<:,>> 's 'rcraaroarabrv/
| |
| Sr/VS =racticn e5Ti:lc ana Reocrtlna =xemotlcns axtile allis srcustrv
| |
| - <<ll sour r>>C/VS Srtanic fracrlo1s !"r T"e rreiqe ": Ils 'catecorv
| |
| - =eSTICICe <<aCriOn an all Othet SubbartS Cf ThlS IrCuSrry . ~
| |
| :re la'lin(na ana Cresslna Industry
| |
| - all 'r
| |
| / latI!c case/"cuts'al,
| |
| ~
| |
| "" /"S rgansc 5>>a =e5 aractacns
| |
| ':'sl:e "3 . Icrs -
| |
| R Base a>>a ~lecic' t"er subcareaories of this incustrv.
| |
| u3tals Subcateaorv.
| |
| .um ana Stnaa Chemicals Industry
| |
| - SSCSCIC(de fraCtian sn the Tall Q(l WOS In SubCateaarV anO the Rasin Sasea OeriVatiVes Subaatea)ary.
| |
| - tscsticiae and base/neutral Fractions in all ocher Subcaceaories of this induscry.
| |
| 3 ato and oaocr S<<avstrv
| |
| - aCS(iC:de fraCCian In PaOeraraae Sulfite SVOCateCOries (SubOarCS J and U) .
| |
| ~ 3}sct-cut>>.3i 3-c scsticsae lcttc-4 << ocinx suboart '), olssolvina Krast suboart
| |
| ~
| |
| F, ana paoerboara frc<< caste a)ocr Suooas't 8, i
| |
| valet le . baSC/neuCral, OeSC iCiae fraat ianS 1 Cl e BCT Sleaanea KrafC SubOart SI. Semi-ChemiCal SubOarCS 8 and C . and s
| |
| yonintcaratca.c(ne Paoers Suboart e.
| |
| <<csa. Sascttcutral, ana ocst ca c fractions an F ne Bleacnea Kraft SubOart I. Oissolvsna Sulfite Palo Subaart '(. rauna-
| |
| ~ ~ ", ~
| |
| aoa p:nc ssaoers suboart o. marxec Bleacnca Kraft suooarc o. Tissue from Mastcoaoer suboart T. and Nonsncearaced Ti55ue eaoers Suboart S.
| |
| Stcam Electr(c Po>>er Plant Induscrv Basctneucral traction sn the Once-Throua)n Coolinq dater. tiv Ash . ana Soctom Ash Transoort 'Maccr orncess >>astescreams.
| |
| :38
| |
| | |
| SECTION II W i4II 0005827 SEE INSTRUCTIONS NUMBFR ON REVERSE SIDE 9JIFRL MB ~00 2 USE THIS DATA SJEET TO RECORD INFORMATIGN AS RECUIRED IN: (CHEQ< APPROPRIATE BOX FCR IttICH INFORMATION THIS DATA SHEET REPRESFDJTS ~ )
| |
| : l. SECTION lli ITDI 4 E~ GROLttDLLATKR DISCH/>>RGE INFORMATION (PAGE 55)
| |
| CRITICAL X 2. SECTION I I. ITEM b. PRIORITY PGLLJJTANTS IN SLRFACE HATER DISCHARGE (PAGE 37)
| |
| MATERIALS TOXIC POLLUTANTS HAZARDOUS SUBSTANCES Bi LIST ANY CRITICAL t"ATERIAL (TABLE IV PAGE 6) NOT ADIJ2ESSED IN SECTICtt II ITEM FP, RIORITY t2OT APPLICABLE PCLLUTANTS MILCH YOU JGXJPt OR HAVE REASGN TLL BELIEVE TO BE PRESENT IN TIE DISCHARGE>> SEE IN REVERSE SIDE GF THIS PAGE FGR FUJ7TIER DIRECTIONS>>
| |
| ~~0, DISCHARGE APPL I CABLE (SEE BEL7at)
| |
| Ai NAME OF CRITICAl. MATERIAL CR PRIORITY POLLJJTANT *Sodium H ochloride t.ASS 014I WIT CCDE SAMPLE TYPE
| |
| .~ ~*
| |
| LJ OF ANALYSES Lit ~
| |
| I
| |
| ~ PL Bi AVERAGE CCNCEJIIRATICNJ SAMPLE lYPEJ III OF ANALYSES
| |
| . LJJ~~ L>J ~~
| |
| C~ MAXI LJt CatCENIRATICN AJO t'ASS
| |
| ~23 ~1 ~27 3 ~V A. NAME OF CRITICAL MATERIAL OR PRIORITY POLLUTAJIT UNIT CODE SV'PLK TYPE OF ANALYSES 8 AYERAGE CCttCENTPATICN; SAMPLE TYPEJ tt OF AttALYSES LJ C. Ittlt CCNCENIRAT ION At4) MASS WIT CODE Ut!T COCK JLlLX LJ UNITS CODE A. ttAME OF CRITICAL MATERIAL CR PRICRITY POLLUTANT 1 Mg/I l'F LN IT CODE SAMPLE TYPE LJF ANALYSES B. AYERAGE CONCENIRATION; SJMPLK lYPE; ANALYSES 2 Ug/I LBS/DAY WIT CODE WIT CODE C. MILXItllLCONCKNIRATION AND MASS KG/DAY LJ A~ CRITICAL MATERIAL OR PRIORITY
| |
| ~.~
| |
| NAME OF POLUJTA%'.
| |
| TYPE'>> WIT CCDE SAMPLE TYPE OF AJLALYSES AVERAGK CONCENTRATIONJ SA PLE OF AttALYSES "AXIttltCO'CENIRAT ION AND MASS WIT CODE WIT CODE C
| |
| LJ LJ MPLE i>>P
| |
| ~~
| |
| ~P>> A. ttAJE CF CRITICAL MATERIAL CR PRIOR llY POLLUTANT 1 GRAB WIT CODE SAJYPLE TYPE JJ OF ANALYSES SAME TYPEJ ~ OF ANALYSES 2 24 HR.COMP. S~ AVERAGE CGNCEJITRATION; LJ C. AXIMLtt CGNCENIRATION AMJ MASS Llt IT CODE WIT CODE
| |
| ~
| |
| LJ ~ LJ A JA% GF CRITICAL "ATK7IIALOR PRIORITY POLLUTAVT
| |
| ~ WIT CODE 'AMPLE TYPE OF ANALYSES 2 B. AVEJLAGEcatcENTRATIGN; SAMPLE TYPE; I" GF ANALYSES
| |
| : c. AXI~cONCEJILATlal AJ4J UNIT CODE WIT CODE MASS LJ A. %PE OF CRITICAL MATERIAL OR PRIORllY POLLUTANT
| |
| : 3. AVERAGE CONCKNIRATION; SJMPLK lYPE: Jt OF ANALYSES LLLJ LhllT WIT CODE CODE SA'LPLE TYPE JJ OF AttALYSES WIT CODE C>>,MAXlttP. CCttCENIRATICN AttD MASS A.:>>AMK OF CRITICAL i"ATERIAL OR PRICRITY POLLPJTJVLT SJVLPLE TYPE OF AtLALYSES Bi AvEPAGE catcENIRATIGNJ SA>>LPLE TYPE; >>It 0F ANALYsEs LJ UNIT CODE WIT CODE
| |
| : c. MAXIMJJL catcENTRATION AJ4) MAss LJ
| |
| * Discharged as total residual chlorine ADDITIONAL PAGES OF THIS ITEIL 7 ARE ATTAOED FOR Tte REST OF THE CRITICAL CI YES MATERIALS Ata/CR PRICRITY PLXLUTANTS RECUIRED TO BK REPORTED. QX NO
| |
| ** Basis: 1993 actual data submitted on DMRs. Average concentration based on data from May to December.
| |
| 39
| |
| | |
| I'S !,'" 'S " R "rdzPL
| |
| :TEu 7
| |
| .:-cs ance ''e rais tor . Is ro be used bv both surface and groundworer aoplicants to record lnformorlon on anv michigan crltlcai material, E.p.A.
| |
| Z-"C<< I Pcflu-onr. =. nazarccus svas-ance In <<nice -'s Tool!car!on requires cata -O be provided. his <<ou!C inCluce anv chemico!
| |
| "icnlgan critico! "arer.ais egisrer i,ab)e I'/). The E.p.A. p~icrltv polluran. 'sr!no ITable '/). -r Tables A-<<<<nion ! ISTS <<rgan!C TOXIC POllutanTS, Other TOXIC uqllutantS, "nVentlcnal and NcnqqnVenricnal POI+tantS Ond NOZardcuS S.bsrances.
| |
| ITmz 7
| |
| : .ITIC/I. "ATEPI ALS, =RIORITY QLLUTANTS, AND/OR HAZARDOUS SUBSTANCES IN THE OISCHAPGE vaterial I, 2. 3... 8 List rhe none ot the chemical substance Icritlcal material, priorlrv pollutant, or nazardous substance) from Tables IV, V ono I IA-VA os required In tne box <<nlcn you checked In A.l-3. abbve. Enter each chemiCOI substanCe'S parameter number os it listed In Tables IV,.V and I IA-VA provided.
| |
| B. orovlde the average concentration of the chemical substance named In A. Indicate the sample type used and the number of analyses mode to provide the concentration data for the chemical substance named in A.
| |
| Provide the maximum concentration and determine the mass loading of the chemical substance named In A.
| |
| NOTES: I. If only one analysis was mode for a chemical substance then record that data os a maximum value. If more than one analysis has been mace for a chemical subsTance Then provide an average value ot those analyses and the maximum value.
| |
| : 2. This Section II, Item 7, Data Sheet provides space for recording cata for 8 chemical substances IMoterlals).
| |
| Addlticnal SbOCe <Or reCOrqlng Of data tOr mere rhan 8 MarerlalS Can be made by making COPleS Of thlS Item.7 Data Sheet os needed. It is also imporront to use a separate ser of Data SheeTs for each applicable reporting requirement as listed In A.I-3. and for each outfall.
| |
| : 3. Refer to the left margin for the code number representing the SamPle type used and the appropriate unit codes.
| |
| 40
| |
| | |
| ANALYTICAL REPORT Cook Nuclear Submittal Number: 29609- 3 Proj: Waste Water Analysis Location:
| |
| | |
| ==Contact:==
| |
| Ray V. Buhl Subm: Jan 26 Samples Phone: (616) 942-9600 Outfall Outfall Circ. Detection Units 001 002 Intake Limit WWES Sample No: 78371 78372 78373 BOD, (5-Day) <1.0 <1. 0 <1.0 1.0 mg/1 Sampled by:
| |
| Date Sampled: 01/26/94 01/26/94 01/26/94 Time Sampled: 00:00 00 00 00 00 Date Received: 01/27/94 01/27/94 01/27/94 Time Received: 13:30 13:30 13:30
| |
| :>') ) ') (I I('ll'6 rlr)rl
| |
| ~ IIII IH I ale'h 5 alt 8 I'. I () lkrl 5 874. (I I'rl ll(l Rrl pl(IH. 11 I II)588 0874. 8 I 8/I) 4 2 0I)00 I'rl 'r 0 I ~2 II I 8
| |
| | |
| ll ll / lI In('(I'BI i 6.S'(7nI('(
| |
| 1 ~emu@( ('>Ilvallll STATEMENT OF DATA QUALIFICATIONS CLIENT: Cook Nuclear SUBMITTAL'9609-3 All analyses have been validated and comply with our Quality Control Program. No qualifications required.
| |
| The following analyses have been qualified for the reasons cited.
| |
| KEY
| |
| : l. Sample integrity suspect upon receipt (explain).
| |
| : 2. Analysis performed beyond EPA established maximum allowable holding time.
| |
| : 3. Detection limit elevated due to matrix interferences.
| |
| : 4. Laboratory control sample value outside established acceptable limits.
| |
| : 5. Matrix spike sample value outside established acceptable limits.
| |
| : 6. Duplicate analysis value outside established acceptable limits.
| |
| : 7. Surrogate/internal standard recoveries outside established acceptable limits.
| |
| : 8. Data point suspect due to potential laboratory contamination (explain).
| |
| : 9. Coelutes with the compound cited. Result may represent a combination of both compounds.
| |
| : 10. Other (explain).
| |
| Note: This document is included as part of the Analytical Report for the above referenced and should be
| |
| . retained as a permanent record thereof.
| |
| )'>') > (llenwond Illlls Parkway SI'. PO Box 874. (Iran(l Rnpl(ls. Xtl 49588-0874. 8 I G/842-8800 !'ax 0-I2-8 In!
| |
| | |
| tl1!'En )e(no!E-'.')n(n(7 l,iatnmi( (nmp,vn Xl 1 I I( Xl sl I'K I( I ANALYTICAL REPORT Cook Nuclear Submittal Number: 29609- 4 Proj: Waste Water Analysis Location:
| |
| | |
| ==Contact:==
| |
| Ray V. Buhl Subm: January Samples Phone: (616) 942-9600 Outfall Outfall Circ Water Detection Units 001-Circ 002-Circ Intake Limit Water Dsch Water Dsch WWES Sample No: 78532 78533 '8534 Surfactants, MBAS (0.025 <0.025 (0.025 0.025 mg/1 Coliform, Fecal 2 <1 1 cl/100ml Color (Apparent) <5 <5 <5 5 6 pH Sampled by: V. Shah V. Shah V. Shah Date Sampled: 01/26/94 01/26/94 Time Sampled: 00'00 00 00 Date Received: 01/28/94 01/28/94 01/28/94 Time Received: 00 00 00 00 00 00 5:)55 (II(.'nivn()(l II!Ils Pnr kivny SE. PO Box 874. (I('nn(l Rnpl(ls. III 49588>>0874. 616/902-9()00 I'nx 9 I'-6 I!)9
| |
| | |
| lHVErt,>ateelVn f- SneBCe tt.s>>>>>>>>i I c:rt>>>p'>>>t ;4 X A l. '>'I' (l 5 I.,'b I'. R 't I t: t!:
| |
| STATEMENT OF DATA QUALIFICATIONS CLIENT: Cook Nuclear SUBMITTALr29609M All analyses have been validated and comply with our Quality Control Program. No qualifications required.
| |
| The following analyses have been qualiTied for Ihe reasons cited.
| |
| Sample No.(s): Parameter:
| |
| Explanation:
| |
| KEY
| |
| : l. Sample integrity suspect upon receipt (explain).
| |
| : 2. Analysis performed beyond EPA established maximum allowable holding time.
| |
| : 3. Detection limit elevated due to matrix interferences.
| |
| : 4. Laboratory control sample value outside established acceptable limits.
| |
| : 5. Matrix spike sample value outside established acceptable limits.
| |
| : 6. Duplicate analysis value outside established acceptable limits.
| |
| : 7. Surrogate/internal standard recoveries outside established acceptable limits.
| |
| : 8. Data point suspect due to potential laboratory contamination (explain).
| |
| : 9. Coelutes with the compound cited. Result may represent a combination of both compounds.
| |
| : 10. Other (explain).
| |
| Note: This document is included as part of the Analytical Report for the above referenced and should be retained as a permanent record thereof.
| |
| 5555 (s'tenwood ttllls Parkway SE. PO Box 874. (>rand Rapids, Mt 49588-0874. 616/942-9600 t'ax !)4'>-t!4!)s
| |
| | |
| GENERAL CHElVIISTRY RESULTS Client Sam ie ID: OUTFALL 002 Date Collected: 01-24-94 Matrix: water LAL Batch IDls): 126 im Date Received: 01-26-94 PO¹ 69095-040-3N Reporting Date Data LAL Constituent Met oa Result Detection Limit Quelifierfs) Anal zed Sem Ie ID Fluoride, inm IL 340.2 <0.15 0.15 03-02-94 L1 131-9 Bromide. in m IL 300.0 <0.050 0.050 01-28-94 L11 31-17 Nitrite-Nitrate-Nitrogen, 353.2 0.34 0.050 02-11-94 L11 31-22 inm IL Sulfate, inm IL 300.0 23 0.059 01-27-94 L1131-17 Total C anide, inm IL 335.2 <0.020 0.020 01-27-94 L11 31-26 Total Phenolics, in m IL 420. 1 <0.15 0.15 02-08-94 L1131-32 Sulfide, inm IL 376.1 < 1.0 1.0 01-27-94 L1131-12 Comments:
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| | |
| GENERAL CHEIVllSTRY RfSULTS Client Sample ID: OUTFALL 002-CW Date Collected: 01-26-94 Matrix: water DISCH LAL Batch ID(s): 126 im, 127 im Date Received: 01-27-94 PO¹69095-040-3N Reporting Data Date LAL Constituent Method Result Detection Limit Qualifier(s) Anal zed Sam le ID Total Phosphorus, 365.2 <0.030 0.030 02-08-94 L1142.6 inm IL Ammonia-Nitrogen, 350.1 <0.050 0.050 02-01-94 L1 142.6 inm IL Total Suspended Solids, 160.2 <12 12 02-02-94 L1 142-10 inm IL Total Organic Carbon, 41 5.2 2.0 1.0 02-16-94 L1142-2 in m IL Chemical Oxygen 410.2 <18 18 01-28-94 L1142-2 Demand, in m IL Total Kjeldahl Nitrogen, 351.2 <0.10 0.10 03-03-94 L1 142-6 inm IL Comments:
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| | |
| GENERAL CHEMISTRY RESULTS Client Sam le ID: OUTFALL 002 Date Collected: 01-27-94 Matrix: water LAL Batch ID(s): 128 im Date Received: 01-28-94 P0469095-040-3N Reporting Data Date LAL Constituent Met od Result Detection Limit Quallflerls) Anal zed Sam le ID Color 1 10.3 (5.0 5.0 01-28-94 L1151-2 Sultite, in mg/L 377.1 (1.0 1.0 01-29-94 L1151-2 Comments:
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| | |
| METALS RESULTS Client Sam Ie ID: OUTFALL 002 Date Collected: 01-24-94 Matrix: water LAL Batch)DIs): 126 im Date Received: 01-26-94 PO¹69095-040-3N Reporting Concentration Detection Limit Data Date LAL Constituents Method Im IL) (m IL) Qualifierls) Anal sed Sem le ID Aluminum 6010 <0.20 0.20 02-22-94 L1 131-95 Antimon 6010 <0.060 0.060 02-22-94 L1 131-95 Arsenic 7060 <0.010 0.010 02-20-94 L1131-95 Barium 6010 <0.20 0.20 02-22-94 L1131-95 Ber Ilium 6010 <0.005 0.005 02-22-94 L1 1 31-95 Boron 6010 <0.20 0.20 02-22-94 L1 131-95 Cadmium 6010 <0.005 0.005 02-22-94 L1131-95 Chromium 6010 <0.010 0.010 02-22-94 L1131-95 Cobalt 6010 <0.050 0.050 02-22-94 L1 1 31-95 Co er 6010 <0.025 0.025 02-22-94 L11 31-95 Iron 6010 <0.10 0.10 02-22-94 L1 1 31-95 Lead 7421 <0.003 0.003 02-23-94 L1 1 31-95 Ma nesium 6010 12 5.0 02-22-94 L1131-95 Man anese 6010 < 0.01 5 0.01 5 02-22-94 L1 131-95 Mercur 7470 <0.0002 0.0002 02-09-94 L1 1 31-95 Mol bdenum 6010 <0.067 0.067 02-22-94 L11 31-95 Nickel 6010 <0.040 0.040 02-22-94 L1131-95 Phos horus 6010 <0.050 0.050 02-22-94 L1 131-95 Selenium 7740 <0.005 0.005 02-25-94 L1 131-95 Silver 6010 <0.010 0.010 02-22-94 L1131-95 Strontium 6010 0.13 0. 10 02-22-94 L1131-95 Thallium 7841 <0.010 0.010 02-28-94 L11 31-95 6010 <0.20 0.20 02-22-94 L11 31-95 Tin Titanium 6010 <0.10 0.10 02-22-94 L1131-95 6020 < 0.001 0.001 03-07-94 L1 1 31-95 Uranium Vanadium 6010 <0.050 0.050 02-22-94 L1131-95 6010 <0.020 0.020 02-22-94 L1 131-95 Zinc Comments:
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| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 1 of 2 D
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| li n II:
| |
| am le ID: OUTFALL 00 Matrix: WATER 4-AN- 4 LAL am le ID: L1131-44 D R iv 2 -AN-4 Date Anal zed: 03-FEB-94 Anal tical Batch ¹: 020394-8260-J-2 Dilution Factor: 1 QC Batch ID: 020394-8260 RR TE RE OVERY QC Limits 1 2-Dichloroethene-d4 99 76-1 14 T n 1 4 4-Bromofluorobenzene 97 86-1 1 5 Reporting Concentration Detection Limit L D Chloromethane <5 Vin I Chloride <5 Br mmehn h r h n Trichlorofluoro methane Ac one <10 10 11-Di I r h n n Di Ifi Meth lene Chloride <5 trans-1 2-Dichloroe bene <5 Vin I A 11-Di I r hn 2-Butanone <10 10 cis-1 2-Dichloroethene <5 hlrf rm 111- rihl r h Carbon Tetrachloride <5 1 2-Dichloroe han <5 8 n n Trihi r hn 1 2-Dichloro ro an <5 Bromodichlorome hane <5 hl I Vin r 4M hl--en nn cis-1 3-Dichloro ro ene <5 Toluene <5 rn-1 -Dihl r r n 2-Hxnn 1 1 2-Trichloroethane <5 Tetrachloroethene PCE <5 LOCKHEED ANALYTICALSERVICES
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| | |
| . VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 2 of 2 Client Sam le ID: OUTFALL 002 LAL Sam le ID: L1131-44 Reporting Concentration Detection Limit Constituent /L /L Data Qualifier s Dibromochlo rom ethane <5 hlr n n Eh I n n m -X lena <5 o-X lene <5 r n Br m f rm 1 1 2 2-Tetrachloroe hane <5 1 3-Dichlorobenzene <5 14-Di hl r n n 1 2-Dichlorobenzene <5 ZCG LOCKHEED AIVALYTICALSERVICES
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| | |
| VOL'ATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING IVIETHOD 8260 TENTATIVELYIDENTIFIED COMPOUNDS Client Sample ID: OUTFALL 002 LAL Sample ID: L1131~
| |
| Date Received: 264AN-94 Date Analyzed: 03-FEB-94 Matrix: WATER Dilution Factor: 1 Analytical Batch: 020394-8260-J-2 QC Batch ID: 020394-8260 Estimated Retention Concentration Time Data Tentatively Identified Compound Iyg/L) (minutes) Qualifier(s)
| |
| NO COMPOUNDS IDENTIFIED LCG LOCKHEED AIVALYTICAL SERVICES
| |
| | |
| SEMIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING ViETIIOD 827p P e I of2 Clien Sam le ID: OUTFALL 02 LAL Sam le ID: L1131-57 Date Collected: 24-JAN-94'atrix:
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| Date Received: 26-JAN-94 WATER Dilution Factor: 1 Anl i IB h4'. 2 4- 7 -A D Exr d 31- AN- 4 QC Batch ID: 8270-SEMIVOLATILE 4825 Date Anal zed: 03-FEB-94 S RR GATE RE OVERY 0 Limi 2-Fluoro henol 27 21-100 Phenol-d, 20 10-94 Nitrobenzene-d, 67 35-114 2-Fluorobi hen I 58 43-116 24 -Tri rom h n I 48 p-Terphenyl-d 41 33-141 Reporting Concentration Detection Limit L D Phenol <10 10 bis 2-Chloroeth I e her <10 10 hlr hn I 1 -Dihl r nz n 1 4-Dichlorobenzene <10 10 Benz I alcohol <10 10 1 -Dihl r nz n 2-M hl hn I bis 2-Chloroiso ro I ether <10 10 4-Meth I henol <10 10 N-Ni r -Di-n- r I min Hex hl r hane Nitrobenzene <10 10 Iso horone <10 10
| |
| -Ni r h n I 4-Dim h I h Benzoic acid <50 5p bis 2-Chloroethox me hane <10 10 4-Dihl r h n 1 4-Tri hl r n n Na hthalene <10 10 4-Chloroaniline <10 10 Hx r in 4- hlr--m hlhnl 2-Meth Ina hthalene <10 10 Hexachloroc clo entadiene <10 10 LOCKHEED ANALYTICALSERVICES
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| | |
| 0 SEMIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Pa e2of2 Client Sam le ID: OUTFALL 002 LAL Sam le ID: L1131-57 Reporting Concentration Detection Limit Constituent I IL) I IL) Data Qualifierls) 4 -Tri hl r hen I 4 -Tri hl r hen I 2-Chlorona hthalene <10 10 2-Nitroaniline <25 25 Dim h I hh I A n hhln 2 6-Dinitrotoluene <10 10 3-Ni roaniline <25 25 A n h hen 4-Dini r h n I 4-Nitro henol <25 25 Dibenzofuran <10 10 4-Dini r I n Di hlhhl 4-Chloro hen I- hen lether <10 10 Fluorene <10 10
| |
| .4-Ni r nilin <2 4 -Dinir - -m h I h n I <2 N-Nitrosodi hen lamine <10 10 4-Bromo hen I- hen lether <10 10 Hx hlr nzn Pn hlr hn Phenanthrene <10 10 Anthracene <10 10 Di-n- I h I Fluoranthene <10 10 P rene <10 10 B I n I h
| |
| '-Di hl r n Benzo a anthrac n <10 10 Chr sene <10 10 i 2- h Ih I Di-n- I hh I Benzo b fluoranthene <10 10 Benzo k fluoranthene <10 10 Bn rn In n 1 r n Dibenz a h an hracene <10 10 Benzo h i) e lene <10 10 LOCKHEED AIVALYTICALSERVICES
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| | |
| SEMI-VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8270 TENTATIVELYIDENTIFIED COMPOUNDS Client Sample ID: OUTFALL 002 LAL Sample ID: L1131-57 Date Received: 26-JAN-94 Date Analyzed: 03-FEB-94 Matrix: WATER Dilution Factor: 1 Analytical Batch: 020394-8270-A QC Batch ID: 8270 SEMIVOLATILE 4825 Estimated Retention Concentration Tlrne Data Tentatively Identified Compound Iyg/L) Iminutes) Qualifierls)
| |
| UNKNOWN KETONE 9.3 4.80 C
| |
| LOCKHEED AIVALYTICALSERVICES
| |
| | |
| OIL AND GREASE EXTRACTABLES ANALYSIS RESULTS BY FT/IR USING METHOD 413.2 D
| |
| D R II:
| |
| Client Sam Ie ID: OUTFALL 002 iv:
| |
| 4- AN- 4
| |
| -AN-4 LAL Sam le ID: L1131-77 D
| |
| Dil i Anl:
| |
| nF r:1 7F B- 4 Matrix: WATER Date Ex racted: 02-FEB-94 Anal tical Batch ¹: 020494-413.2 QC Batch ID: 020294-413.2 Reporting Constituent Concentration Detection Limit Data Qualifier(s) m L m Oil and Grease LOCKHEED AIVALYTICAL SERVICES
| |
| | |
| PESTICIDE ANALYSES RESULTS BY GC/ECD USING METHOD 8080 Da lien II:
| |
| m le ID: TFALL-4- AN- 4 Date Extracted: 31-JAN-94 2 LAL Sam D R I
| |
| iv:
| |
| ID: L11 1- 7 2 -JAN- 4 Date Anal zed: 01-FEB-94 Matrix: WATER Dilution Factor: 1 Analytical Batch ¹: 013194-8080-E-4 QC Group ID: 8080 PEST/PCBS 4822 RR ATE RE VERY QC Limits TCMX 63 60-150 DCB 45" 60-150 Reporting Constituent Concentration Detection Limit Data Qualifier(s)
| |
| L A-BH B-BHC <0.05 0.05 G-BHC <0.05 0.05 D-BH HEPTA HL R ALDRIN <0.05 0.0 HEPTACHLOR EPOXIDE <0.05 0.05 H RDANE ND LFAN I A-CHLORDANE <0.05 0.05 4 4'-DDE <0.1 0.1 4 4'-DDT DIELDRIN ENDRIN <0.1 0.1 ENDOSULFAN II <0.1 0.1 4 4'-DDD ENDRIN ALDEHYD ENDOSULFAN SULFATE <0.1 0.1 METHOXYCHLOR < 0.5 0.5 T XAPHEN P B1 1 PCB-1221 <2 PCB-1232 P B1 4 P B-1 PCB-1 254 PCB-1 260 TECHNICAL CHLORDANE TCMX - tetra-chloro-meta-xylene DCB - Deca-chloro-biphenyl l44 LOCKHEED ANALYTICALSERVICES
| |
| | |
| RAD DATA REPORT (ra01)
| |
| Indiana Hichigan Pover Co. ~ Bridgman,HI
| |
| .Organic and Inorganic Contaminants (Project COOK-JENI)
| |
| Client Sample ID: OUTFALL 002 LAL Sar@le ID: L113+86 Date Collected; 24-JAN-94 Date Receivedt 26.JAN-94 Hatrixt 'lister Login N+4ert L1131
| |
| ''s"""'"" ><"'Anal~ed 'Babb'"""<" ~"""'-'-': "l'"-'"""""-"":<':-'-'~~~ActMty@" O'For '~~IB)IL~~".~:
| |
| -'a'tagual'-'Infts-"'ross Alpha 23 FEB-94 GR ALP/BETA LAL~ 0060 4756 0.33 O.M 1.7 pCi/L Gross Beta 23-FEB 94 GR ALP/BETA LAL 0060 4756 1.9 1.3 2.2 pCI/L Page 7
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| | |
| RAD DATA REPORT (ra01)
| |
| Indiana HIchigan Pcwer Co. e Bridyaan,HI Organic and inorganic Contaeinanta (Project COX JENl)
| |
| Client Seep(a ID: QITFALL 002 LAL Sancta lD: L1131-90 Date Collected: 24.JAN-94 Date Received: 26-JAN-94 Hatrlx: llater Log ln Kwhr: L1131 QP~Coni't Ra-226 22.FEB.94 RA.226 LAL.0073 4771 0.016 0.056 0.12 pCI/L Ra.228 23-FEB.94 RA-228 LAL.0074 5503 0.52 0.34 0.55 pCI/L Page 11
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| | |
| PH Analysis (LAB.079)
| |
| PH Meter CPC 9 Jom Outfall 002 C date due Sample Sample Time 0 Sample P S amp le Date CDM Entered by
| |
| : 6) Sample C/ph (prior to correction) 5.3.5 7) NHz pH correction 5.3.6 8) )ample results C/pH "(after 2e3 t.~ g P Correction)
| |
| NH 3 a 4~( 6/7 cb)c-
| |
| >oo U 2 P'
| |
| /L-3oo Sample Sample Time Sample $j Sample Date CDM Entered by
| |
| : 6) Sample C/ph (prior to correction) 5.3.5 7) NH3 pH correction 5.3 ' 8) Sample results
| |
| 'C/pH (after
| |
| ~
| |
| Correction)
| |
| : 9) IAB.041 Specs Verified by: hl/8 Rwpeevieee Review/Deee &+I~ Form prepared by/Date Form approved by/Date 12 THP LAB.041.25s Revision 1
| |
| | |
| Determination of Total Chlorine Instrument CPCIj 50 ~
| |
| Outfall 002 (Lab 170)
| |
| """"'"'~s'echnician Sample/Standard Sample g Date Time CDH Entered by
| |
| : 1) Absorbance 6.11 2) Results, ppm (~ c~
| |
| 3} Dilutions made CH W
| |
| : 4) Results, ppm (III2
| |
| * 8 3)
| |
| : 5) LAB.041 Specs Verified by:~)9 vperviaor Revi'ev/Date~MR~ para prepared by/Date Form approved by/Date
| |
| /~f+
| |
| 12 THP LAB.041-25)l Revision 0
| |
| | |
| SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I PERMIT
| |
| ~ MI pppg827 GlIFALL 'KKR ~00 3 j'j~iVI A~ LOCATION OF DISCHeVIGE ~SW ( 's, ~NW V, KCIIWI i~6, i0II ~06 6 ~ IJII06 ~I CF RECEIVING WATER (IE. GRC(tGHATER CR tisV6E GF SIRFACE L AKIE MIC HIGA N Cs DO YCU DISCHARGE (IF tO.
| |
| S~Y.
| |
| CCNTttAIE TO E) X YES DISCHARGE LOCATION Ds IF YESe LIST DISCHARGE PERIODS tes / IRY te, / DAY SCHEDULE
| |
| ~12 ~01 ~04 ~30 FLOW
| |
| ~
| |
| RATE WASTEWATER
| |
| ~I~gg E. LUID APPLICATION RATE INe/WRe HR ~ CAY
| |
| ~ u ~.'~ IN./wK K IIA CONTACT COOLING Fe TYPE QF WASTEHATER D I SCHUIGE
| |
| ~3 u WASTDIATER 1YPE COCE M .M LJ
| |
| ? NONCONTACT G~ DISCHARGE SOEDIAE (YEARLY AVERAGE)
| |
| IOURS/DAY ssv/vsse ~12 I COOLING 3 PROCESS He DISOIARGE FLOt RATE (tIIT COCE TOTAL YEARLY S SANITARY B STORMWATER DAILY HINI~
| |
| DAILY HAXItSPI
| |
| /NIT Cygne I. 'M FAXING DISCH6RGE Rlw RATE uIIT CCDE I MGY TO BE AUIHOIIZED IN PERIIT.
| |
| * 2 MGO (NIT OXE GPO Js HAXtt(tt DESIGN DISCNRGE FIOI RATEs
| |
| * DESIGN LJ Ae CO YOU USE HATER IREATHEHT ACOITIVES TO TREAT YOIR DISCH6RZ?
| |
| (IF Mt, ccNTIN(z To ITet 3) Cl YES lTEM Be NA% FutCTICN, AtO OF lAESE ACOITIVESe OettCAL CCt&KITICN 2
| |
| WATER TR EAT ME NT NA AODITIVES Ce N4% Ate ADCRESS OF HAIAS'ACTIRERS OF IHESE ADDITIVESe UNITS CODE I Mgrl 2 Ugrt NA HI Nit%8 AVERAGE IHITS HAXINtt W I TS Ds EXPECTED DISQQRGE CCtCEHIRATICN CF AIOITIVESe NA CODE (ODE CODE AIXIITIVE HA%
| |
| ADDITIVE NA%
| |
| ADDITIVE NA%
| |
| LJ;~ M;~ LJ Es DO Y(XI TREAT TIE DISCHARGE IO REteVE ADDITIVES? NA F. tAIAT IS 1HE RseVAL EFFICIENCY ANO DISCHARGE FREQUENCY I ReeVe. tRS./DAY DAYs/wx.
| |
| ADO ITIVE Ntt%
| |
| ACOITIVE NA%
| |
| ACOITIVE NAt%
| |
| G~ AS AH ATTAOf%Ãf TO THIS APPLICATICN PROVIDE SPECIFIC NWVLIAH CR ACUATIC TOXICOUF)ICAL DATA CR REFERENCE HHICH ARE AVAIIAELEAND INFOR(ATICN CN THE RATE OF DEGRADATICN OF T% RRCIXICTS FCR EACH AIOITIVEs
| |
| * The flow for this outfall is not monitored separately from Outfalls 001 and 002
| |
| | |
| 41 ~
| |
| 1
| |
| '\ j '
| |
| 8 ) <<'1 4<<4 ~ <<p r3
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| l4 ) 1 4 14<<r St ci" 1 8 $ <<BI" re <<1et. Br '<<ci.:Tv :)scnarces 3
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| BTB<<
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| )r
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| '2 rt t$ 3+ I 1'<<
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| -.. ) Seas=net
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| ~
| |
| 1 SC 8 -.
| |
| :as."3.
| |
| r Rr at 4r Sec I, . - )r-4 )5 ric", lect ton. )Own. d1o rant)c res ~ ~ is) :iscnarce )Brloos
| |
| = cvlce 8 )1C )Colic)rien )-8$ .SeC =.- 4VCRC ea -: :e uSea i- -Br = '"CneS S e<< -cur, 1aurS Cer C)v, )na ICC1eS Oer week.
| |
| '1CIC).e 5 11 8 C'ST4<<aTR<<, Ce:I sc-lrCeo I-'-- Is ovtfal I )e<<der " --8 ~ <<aSreraTer TVOe Coca aiven )1 t1e left
| |
| -ar<<r)n. "Ore -<<an C1e Ccae maV Oe )balll ab
| |
| 'lr4" <<8 << .ORr <<Jr 3 5'3 4~ 4 )3 Rw) --4 -.-5'. Cer cf days I * ~
| |
| ~ << ~ \'\ 1 ~
| |
| .v Ce;. 5
| |
| - ".4 4 ~ )) . "S, I 41)4 8 -rw I ) 85 )5 recuestea. )0)8<< -. ',1it Oe )ivRn ~ r "8 ler<<af'Cln
| |
| ~it':)" Callcns:Br
| |
| ~
| |
| ".r -'18 ))Orcbr~ate .I.<< lr1lf5 ry - year; v% - million,at lets cer Say; drO - latlanS Oer cay.
| |
| bvl)8
| |
| -18 use of )ucn ) 'Icw 8 )x, tr) ".
| |
| ent I'1)-$ . )Iso, nen 18 "cntnlv .aerating SC')ar<<8 flow r).e nicn 'rau )n r)te <<i) I -ct "lace an actual ')t- restrlc,'cn navB avtnari)BJ <<Ital<<
| |
| eocrts are reviewed bv Camo)lance sraff
| |
| .') cermlt. 'CTE:
| |
| cn The 'Ic<<ou; <<il I be tne IlCw I'ate CSed ta dave)OO it tar "8"CS err<<its only, will nelo tren to Cerermine
| |
| ~ I anv Ile'lr ol i<<creased u585 mlaht trave occur Ieo at tne foci I I tv, ~
| |
| "8 cesi "rn '.w cr r'))$ 3ceci I " rf)ll:1scnarae te.g. C)rcn -neat.enr Svstem f la>>, cackaaeo treatmnt SV5tem flow, ct'ere c)18r 'l<<l)4 -reatrent srstem f Icw).
| |
| )dr - ' ~ '-" 'Tltc
| |
| <<alc) ~
| |
| 4 <<"8 "4<<j )r 8 )3 ~ r<<) BC <<>> 1al I 8<<$ , '11)<<)f rs ~ 3<<liar CI cice ~
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| ~
| |
| 1ct b"tltue ~ - I-41
| |
| '4
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| 8 1 I 1 r 4<<l \ C$ 1 << '1 RS jgt
| |
| :.ite 1are I"C ))c RSS: 1e manufaCture"IS) CI -"e <<coitiveS dsea.
| |
| 4 <<eh 1 1 $ 4 ~ <<I 4 ~ ~ <<3 5 lr
| |
| ~ 4 i 1 4 ~ 4 <<<<4 1<<, 4,1 <<I ~ tl ' '1 4 l3 4
| |
| -1 ~ "4 "v)l 8 I'-tencv " 4)c1 5 )I I"8 4 ast4<<af4<< ~ 8 1$ ,)r 8 l<<<<ever cv ct R<<cn Sac i 1 fe -" t.'le r 1 << ITR<< 'a*i) 4<<
| |
| I'$
| |
| 3 ~
| |
| .5," i )' ", ICI ) r I 4 I")Cuar ati,. 4.J8$ )BO 4PI C, .1'fcrmatlCn 41IR5t<<a .T ".
| |
| 4$
| |
| !.)ct(eo 4av <<<<suit <<8 I
| |
| )oolic)ttc<<eel "c I
| |
| <<1) 't'1eo o p
| |
| "8 )coif )...
| |
| 15
| |
| '"r crtoteticn ~
| |
| ~
| |
| | |
| SECTION SEE INSTRUCTIONS I I NUMBER W HI 0005827 ON REVERSE SIDE
| |
| ~00 3 Ae Ntt% OF PSIQCESS CIXIIRIBUTII6 mv/ THEDISolARGE THOUGH THIS OUTFALL <<6 SIC CODE .Dt E tft B. PRXESS SOtEIXLE (YEARLY AVEIU6E)
| |
| Ioios/oev ~24 Y ~56 WIT COCE 4/t C. RIQCESS WASTEMtITER FLOW RATE PROCESS 44t Oe TOTAL YEARLY STREAMS Ct CON TR I BUT IN G Q. DAILY MINIMtM TO OUTFALL DAILY I AXIS De PROCESS PRODUCTION RATE WITS /'TII"E DISCHARGE NA
| |
| ~
| |
| Ae NAME OF PROCESS CONIRIBUTII6 TO THE DISCHARGE THIQUGH THIS OUTFALL AtO SIC CXAE N Be PROCESS SCIEDULE (YEARLY AVERAGE)
| |
| HOUIS/SAY SAYS/VSAS C~ PROCESS WASTEWATER FLOW RATE TOTAL YEARLY DA ILY M IN IHM 1 POUNDS DAILY MAXIHM 2 GALLONS PROCESS PRODUCTION RATE 3 CUBIC
| |
| ~
| |
| Ae MAIS OF PROCESS CQNIRIBUT lt6 TO TIE DISCHARGE YARDS THOROUGH THIS OUTFALL AttD SIC CCOE NA 4 TONS Be PROCESS SCHEME (YEARLY AVERAGE) 5 MGY HIIOS/OAY SAYS/YSAS 6 MGD Ce PROCESS WSTEWATER FLOW RATE st GPD TQI'AL YEARLY DAILY MINIHM DAILY MINIHM De PROCESS PRODUCTION RATE WITS CTIME TIME
| |
| ~
| |
| 1 HOUR Ae NAME OF PROCESS CQNIRIBUTII6 TO THE DISCHARGE At6 SIC CODE NA 2 DAY 3 WEEK B~ PROCESS SCHZkAE (YEARLY AVERAGE' HteelS/OAY OAYA/YSAA 4 MONTH WIT CODE 5 PROCESS WASTEWATER FLOW RATE YEAR TOTAL YEARLY DA I LY M IN IHM DAILY tAAX IBM De PROCESS PRODUCTION RATE WITS /Tlt%
| |
| Ae NAPE OF PROCESS CONIRIBUTlt6 TO TIE DISCHARGE THIQUGH THIS OUIFALL AND SIC CODE B. ReCESS SCHULE (YEARI.Y aVERAGE)
| |
| SIVA/VSAA Ce PROCFSS WASTEWATER FLCW RATE TOTAL YFARI.Y DAILY MINIHM De PROCFSS PRODUCTION RATE DAILY MAXIHM UNI'TS / Tli"E
| |
| * The flov for this outfall is not monitored separately from Outfalls 001 and 002 33
| |
| | |
| IP kc, <<35 }: r <<5 5 5 355 I o)f 5 <<<< Ic1 ri te o,s Isobar 5
| |
| ~
| |
| I
| |
| ~~
| |
| > e 5) g el '< iacl 5
| |
| <<r a5 e<<v<<
| |
| I "
| |
| lan<<<<3 tg<<'(
| |
| I' Ce 3SS xl)c CreC.
| |
| vrt A vqfCI>
| |
| ) i -.-"e - cace =<<ovlcec cr esc3 qa<<te of section i'I, ccr eben Inoivlcuat clscharce qoint 3 separate set cf t 3 4
| |
| =- --<< -!-5 -" -e -roceSS <<niCC Cont-IC tes -q -nlS ISCharCe. MISO "rCViCe -ne Cr""et =.IC COCS e "e .carts bier<<"e process 5 recule in ncurs cer csv anc cavs-ber-veer.
| |
| tearer Provide t3C process .wastewater flow rate information as recuested based on your last IR months of operations. Refer to Jnlt COde given In tne left margin for the appropriate flow units.
| |
| -rocess qrccuction cate - certain qermlt I;mltatlons mav be based cn production rates. The qroducticn rates used to
| |
| :3 e~'"e car .'- ~'-I s snail <<e reqr<<sen ec )v a reascnable <<easure cf actual "rcduc ion of the facilitv, such as the
| |
| ."-..."-'".- :. '-" - << -Icn ,ento cf ."e crevi us cr t<<e <<onthlv 3verace 'cr tne nichest of the crevlcus f(ve vears, or
| |
| =-her "eascnsb.'e eas.re as statec tn 3 q>>cable J.S.K.o.h. cat8gor!caI rules and reoulaticns.
| |
| ir 45 :lSC3arde<<s, 33-.3 ~ 5"Cduc-'r 5>ail:e eStl ate. is:no :roiec+ec crcduC iCn 55 <<e 3< 5 3 c ~ ri ts 5ec > 5 3 'I
| |
| ) Ie . t..c,h, 3 B rlcal rules and reculatlcns 'cr
| |
| | |
| SECTlQN I l M2 0003827 SEE INSTRUCTIONS ON REVERSE SIDE (UIFALL IUD ~00 3 IS THE DISCHARGE FROM THIS CflFALL DIRECIED TO THE GRCUt47 OR 'DIES GRON4WATERS? (IF NOe CCttTIhUE TO Iieet r) YES MAS
| |
| * ttYDRCGEOLOGICAL STUDY OR ITS EOUIVALENT BEBI PERFORMED OR IS THERE SLFFICIENT CNRENT HYDROGEOLOGICAL INFOfitQTION AVAIIABLEAS RECUIRED BY ~ wATER RESOIIRCES COtHISSION PARi'2 GRONIDWATER RULES OF AIIIUST ltte 19m) R.525 ZQJ7 (PAGE 4Q) FCR NA e>>
| |
| GROUNDWATER THIS EXISTltiG OR PROPOSED DISCHARGE? IF YES ATTACH A COPY OF THE REPCRTe DISCHARGE C. ARE YOU REOUESTING AN EXP'PTION FRQt SUIPIITTING A HYIXIOGEOLOGICAL REPORT UteDER INFORMATION RULE R.32$ .27/ (19} (PAGE Ltt) OR FRCM GRIX5DHATER MONITORING I)EOUJREte~0 UCER RULE R 25 ZLV5 (5) (PAGE YES Q) OF THE PART 22 RILES ~ IF YES ATTACH DOQBENTS At43 AN EXEtP ION.
| |
| ~TICN TO DEIIONSTRAlE THAT YOR DISCHARGE WOULD OUALIFY FOR NA De ARE YOU REOESTlttt A VARIANCE FRCtt RULE 323e22(5 (PAGE THE WATER RESIXRCES CCtttlsstON PART 22 GRONIDtATER RULES?
| |
| : 5) (NONOEGRADATION) OF YES IF YESe ATTACH SUCH DOQPGPS AS NECESSARY TO DEWNSTRATE THE NEED FCR A VARIANCE IN TEtiMS OF TtE CRITERIA SPECIFIED IN RtAE 525e2210 (PAGE IIL7) OF THE PART 22 RULES>> NA Ee LIST AteeL Cte)ICAL SIBSTANCES WHICH ARE IN MICHIGAN S CRITICAL MATERIALS REGISTER TABLE IV (PAGE tt) AND/OR UeSe EPA S PRICRITY POILUTANT LIST TABLE V (PAGE 7) OR ANY OPER SI8STAtKES NOT APPLICABLEJBELIEVED ABSENT WHICH ARE OR MAY BECCA% INJINIOUS TO TIE IESIGNATED USES OF TIE 68XNDWATER OR TO THE PUBLIC HEALTH THAT ARE DISCH8RGED OR EXPECTED TO BE DISCHARGED lD T}E GRIXNDWATERJIY THIS FACILITY ESTIMATE THE FINAL EFFLUENT CONCENII7ATICN AND RECORD ALL DATA IN ITIN 7 OF NA SECTICN II IN THIS BOOILETe t% APPLICANT MAY BE RECUIRED TD DO ADDITIONALHASTE ANALYSEse Q RIESENT, DATA PROVIDED IN ITII8 7 Ae DISCHARGE CHARACTERISTICS COtKENTRATION WITS CODE tt ANALYSES SAtPIE TYPE ITEM CODE LJ 5 BOD5 COD (FtVE DAY BIOOENICAL OXYGEN OP%74))
| |
| (Ctet ICAL OXYGEN DEMAIO) LJ
| |
| ~
| |
| EXPECTED
| |
| 'TOC (TOTAL ORGANIC CARBON)
| |
| WASTEWATER CHARAC-tV44XIIA NITROGEN (As N) u1 u TOTAL SUSPENDED SOLIDS u>
| |
| UNcsa CODE lDTAL PteSPHORUS (AS P) ~l l Mg/I 2 Ug/I TOTAL RESIDUAL Ct40RINE 3 COUNTS/
| |
| 100 ml DISSOLVED OXYGEN MIN 4 S.U.
| |
| 5 F
| |
| ~
| |
| LJ S LBS/DAY FECAL COLIFORM BACTERtA TEtPERATI4IE (SueCR)
| |
| TEtPERATURE (WINTER) ~
| |
| LLJ ~
| |
| ~
| |
| LJ ~ ~ LJ LJ u>
| |
| u~
| |
| ~5 SAMPLE 0 I L S G R E A S E B~ OTHER WASTEWATER CH8IUtCTER I ST ICS LJ ~ LJ ZXEF l GRAB LJ 2 24 HOUR COMPOSITE LJ LJ ~
| |
| ~ LJ
| |
| * SEE NOTE ON PAGE 37, Outfall 003 LJ LJ ~ LJ LJ REQIIRED INFC848ATICN FQI SINFACE HATER DISCH8RGESe 35
| |
| | |
| 8 ~
| |
| ) <<5 r << ' 1 5 8>> t'<< ~
| |
| I
| |
| ~ 'SC '>> ','Qr h>> << 3 8 5 <<S rri>>8 dttirs
| |
| -'5 ' 5 c *
| |
| -8<<:r>>ct crevrcisl
| |
| <<5
| |
| ~ 18>>-i 8 I
| |
| <<I ii csi, ~
| |
| Scc
| |
| <<ct I i v, -nen leave 3l'onx 3rd
| |
| ~I .i' 3>>u-cer <<)
| |
| 4 li i4<<>>
| |
| .e assicnec.
| |
| c vrl"h 'tcl I~ >>
| |
| * << i<< I cer '" "8 5 3>><<>> vise>> '. Bi 358 Di Sec, Icn i(. TCi 81cn r "clv <<ual disc"3r 8 "ci~ 5 sBDorste $8 i v "e acct'con- snoll scaress Boc "'nese Dor<<s I'8 cischarge t>>crt -"ls S.t'all '5 --". -ne crcvrc<<oter.
| |
| ITEl( 5 hc h -" "uccc ED: S IGS Tc i hAT=- ",o St'DFB .8 hATED -"I "L'cqrc IG.
| |
| 8
| |
| '.". l>g(,''EE lCl.l. '.)C i l I't i hi<<>>rvhi t<<tN I't iwt 3 re applicant stol I report available cischarce aa.a (real cata for existlnc cischdrge or expected ddta for 3 Drooosed discharger
| |
| 'cr the DdrameTers as I 5 ed. These Darareters shall be addressed for either 3 surface water dlscharae or as appropriate !or o
| |
| ; Dune othr cischorge. =Cr 355(stance>> Btet'tnlnir.q abprcbriate DarsreterS 3 =raunCxdter alscharae ocolicanT tzy contact "e
| |
| :"ovhc<<ate>> ',i31i tv~i vision, Dem(ts:Bctlcr ".; -08 ocorcbrl'dte Srovnaitdter .vol I v <<Iv( 5'M'5 oi5trlct a!flee.
| |
| he scclicont shall >>Sport tte srrlole tvpe>>cce best ascribing each reportea piece of data. See ccdiro cn t<<e left marqln Df is
| |
| -" ' -t!<< tt ' 3 5-r ."Sce <<ate>> . I'"<<.:8 . --e <<Dpi 'con<< vst -Bear- T.dn-l -1 (ve cato '. -. eocr'corameter (centi!led bv on ls Br 1<<. Ce acct.cont mov, nc<<ever, -ecu85- -"at -ne recort hs ot cato ct c"e cr cre D these >><<cvlrea Dora>>eters ce
| |
| <<3 I vea ~ . I'c'l B>>ues <vst DO 5 'DDort9c 3 r icBDUBTQ 1t rs t8 ~ "dke 5I c, 1 re>>v85t 1n 'I acht"ent 0 this DD I I catlcn,
| |
| ~
| |
| Ta ~ 5 variable ror =ther Dardmeters not I: scca 3<<ove in A. Cr ether Dar<<s Df his acol ication Tre applicant should repor t mat cato in Tne blonx spaces Droviaea in this port.
| |
| "".TEc: '. Cnit codes fcr parameters reDOr tea ln portS A anO 8 can De fcund cn tne left hand side of this form.
| |
| :rab sample sholl DB usec -". iralv:e 'cr 3>>. temberoture, total Drencls. resiaiai chlcrire, oil and grease, and fecal coliform In 3 sur'.oce <<oter ciscndrce unless ether 'recuencv-sample tvpe Snalvses are available. See Glossary (Dace 48) tor aefinitlon of,rab sample.
| |
| '-nour ccmcoslte samples snail De usea to analyze fcr Total 300c, KD, TGG, crmonla i'litrogen, and Tctal suspendea Sollas ln a surface water 5)schorre unless o~her ireauency-samole tvoe analyses are avoilable. See Glossary (caoe 48) 'or Ceflnlticn c! Oc>>bcsite somole.
| |
| RED,RT)ttG titTAKE GATA, vou are riot t 8>>vireo to rebcrt unless ycu <<isn to demonstrate your Bl la(bi I ity fot'
| |
| " Bt" Bf it"Bnt Ilmi. ]tlcn t. O>>e cr cre collutants, nat i5. Bn elr Ivent li itatlon ad)lusted bv svDtractinc the 1VBro>>B leret Ot the DOIIC-'Snr(5) CreSBnt In your ltltake <<atBr..CCES>>BCulatiCnS allcu ret t(rtltatlonS Cniy ln ertdln = rc'mstances. - crtrcnst ate vcvr hliclbll tv, repcrt he sverace o( the results of 3nalvses cn your
| |
| ~
| |
| -. axe <<Otet ',ll Vour *aT<< i '5 t, Bdtea be!ere iSB, -eST -<<e <<ater 1!ter it 5 treated). and aTtaCh 3 Separate
| |
| )>>Bet cn-5 5: c 8 ~ 't',<<a>> r r Bs>> . -Oltto<<
| |
| ~
| |
| ~
| |
| ll 5 3-h <<nt <<3't 8 'a<<Q <<ot<<>> is>>rolen r>>~ B>>cv Tr o<<er i'i . BB tsc'lat'ce ls ]CQ h>><<5>> v <<h 8 ~
| |
| * r 8 'ri 1 'rr>>
| |
| of -.8 <<x-hnt -- r I-.r --h '>>vhi -i ~ <<8 -cli to-5 s reavcec v treat-eht of vcvr <<aste<<ater.
| |
| ns <<i 8 acjvstea onlv -= The Bxrent <<<<at -<<8 Cot Ivtdn+ '5 tot re<ovea.)
| |
| I iCoble i r B>rrto le <<hen ne Ol Ivtant rebrBSents 3 Class cf ~ccunCS) 3 Cemor Stratlcr of the
| |
| ~
| |
| Bvte<<t -<<<<r ICn -<<e Dollutants ln The )t<<>>dtte ve>>V>><<'/5i>>3IIV, " 8<<(cal.V, I'IC)cq:CSIIV <<re
| |
| ~
| |
| 8 C(lutsr 5
| |
| 'cur 'c>> 't<<ST'1<<s <<:'8 oc'ustes " v -: -re Bxten<< --St 5-e !rtaxe
| |
| ~
| |
| 'r Tc>tot "Bc crs "arre. coil tan=5 varf fran tile sischdrcea collvtants.)
| |
| ;.--Or'ti
| |
| 'ite '<<o>> o <<>> ~ I ~' '}<< '~ 5 i 8 85 '5 '5 ( n
| |
| --e 1>>dlvsis '",
| |
| 'c"r 8 I I
| |
| CBn
| |
| ~ .11 "shm ie lra 1nolv=e cn;v 3<<8 Cu-ro.'I 3rd
| |
| : v. f I s.
| |
| 3I
| |
| '-~ t-Bn" i
| |
| =
| |
| Ovt
| |
| .Dl - -
| |
| ~
| |
| B>>ve55
| |
| -" 5
| |
| ~
| |
| <<ron Bs <<v
| |
| -" -'c -hr-5:tt 8
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| ~ 5
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| ~
| |
| --8 -hs.i-s B>>>>i --: nc ov n"
| |
| ',:<< .<<i r'.:"
| |
| --8:.-".
| |
| 8 Ser Is era. 8
| |
| "'3",cv
| |
| ". ter substant:allv Shee- ar BC .BC t t>8 c'c. est are 5 1 . 'll ~ i ~,Brit i'.3
| |
| ~ .<< ' ''ti dr ~ <<nl i,c it . <<5
| |
| | |
| SEE INSTRUCTIONS ON REVERSE SIDE SECTlON II PERMIT NUMBER ~ MI 0005827 (UIFALL MP ~00 3
| |
| ~
| |
| THE FOLLCWING REQUESTED ItrFO@1ATIQN ~e" 0~ AD[X[ESSED ~r SLJIFACE WATrR DISCHARGERS LITEM
| |
| ~
| |
| JZE! MEW USE DISCHARGERS PROYIQE ExPECTED vALUEs FOR IHE CUANTITAT[YE AtrD 6 QUA[.[TAT[YE INF IDIOM REQUESTED BELOW IS THIS FaCILITY A PRIMARY [NDUSTRY? (REFER TO TABLE [A PAGE 4~[ X 'rQ (IF rrQ GQ TQ E) (IF YES GQ TQ B) YES PRIORITY B [MD[CATE TYPE OF PRIMARY tNDUSTRY AS LISTED IN TABLE fA PAGE 4+.
| |
| (CprrftttUE WITH C.)
| |
| S T M E L E C I P W R POLLUTANTS AND C. OQES THIS OUTFALL DISCHARGE CCttfa[N AVY PROCFSS WASTEWATER?
| |
| ADDITIONAL (IF tent, GQ TO E) ([F YES,'Q TO D) YES trQ INFORMATION D It[DICATE WHICH GC/MS FRACT[Ctrs MUST BE TESTED FCR o (REFER TO TABLE IA PAGE 4+1 VOLATILE FOR XIIK. FCR EACH GC/Ms FRACTION OrECKEDi EACH SPECIFIC ORGANIC TOXIC POLLUTANT wlTHIN SURFACE WATER DISCHARGE EACH FRACTION QgrT BE ANALYZED FOR (SEE TABLE I[A PAGE IttDLrsTRY APPLICANTS WITH A PRQCKSS WASTEHATKR DISCHARGE DATA FCR EACH TOXIC PQLLUfAMT IN TABLE II [A Par< ~$ ~
| |
| ~
| |
| 42, IN ADDITICNi ALL PR[trARY PROVIDE QUANTITATIVE BASE/MElflRAL ACID ONLY RECORD ALL DATA ON FORMS PROVIDED (ITEM 7) IN THIS BQOKLETI (cQNT[tarE wlTH E-K BELow) PESTICIDE Ee IN TABLE [IA ZssL): BE PRQVIDEDI AND IVA PAGES ~
| |
| IF JII(K SLJIFACE WATER DISO[ARGE APPLICANT (PRIMARY OR SECONDARY INDUSTRY)i REGARDLESS OF THE TYPE OF DISCHARGE, KJJQWS OR HAS REASON TO BELIEVE THAT ANY POLLUTANT LlslKD tS DISCHARGED FRCM ANY OU[FAL4 THE QUANT ITATIVE DATA Q NOT APPLICABLE/BELIEVED ABSENT RECORD AL[. DATA OM FORMS PROVIDED (ITEM 7) IN THIS BOOKLETs OX PRESENT/DATA Is ATfACHED
| |
| * F. IF A IY SLJIFACE WATER DISCHARGE APPLICANT (FR[JURY OR SECONDARY INDUSTRY)i REGARDLESS OF TYPK OF DISC5LRGEr KMWS OR HAS REASON TO BELIEVE AMY POLLIJTANTS LISTED IN TABLE VA PAGE 4Q ARE DISCHARGED FRCM ANY OUTFALL TIE APPLICANT REASONS FOR THE POLLUTANT BE[% PRESENT AND PROVIDE ANY AVAILABLEQUANTITATIVE DATAI
| |
| ~ DESCRIBE X %T APPL[cABLE/BEL[EYED ABSENT RECORD ALL DATA ON FONS PROVIDED (ITEM 7) IN THIS BQOKLKTs PRESENT/DATA Is ATTACHED G>> ALL SU[FACE HATER DISCHARGK APPLICAMTS (PRIMrjRY AND SECONDrUIY INDUSTRIES) 4, 5 - TR[oL[x[QPHExxY acKT[c ac[D (2. 4, 5-T);
| |
| X NQT APPL[caBLE/BEL[EYKD ABSENT Es cR MAM[f'Act[REs 2,
| |
| -(), 4, gfR[cHLDRQPHEMQxYI PROPAMIN[c ac[D (sl[.YEx, 2, 4, 5, TP)~
| |
| : 4. XYI ETHYL 2-DtoaJXIQPROP[Ct[ATK ( J 0, DIME(HYL RID, MoexoPHEMYL) P~IH[oaq (RQta~FJ TRICHAXIOPtetQL (TCP) J OR HEXAOEGROPHE% (HCP J (ALL DATA FOR THE
| |
| '(9 ABOVE PJJST BE GEJJERATKD,US[% STAICARD ANALYTICALCALIBRATION PRQCGXRES) OR KXlts OR HAS REASON TO BELIEVE THAT TCDD IS OR MAY BE PRESENT IM THEIR DISCHARGEI rrLF[I REPORT rXJALITATIVK Dafar GEJERATKD WHIC[t USED A SCREEN[% PROCGXRE %T PRESENT/DATA I S ATTAOK)
| |
| QK[BRATKD 'WITH ANAI YTICAL STANDARDS FOR 2i 5r I 8i TETRACHLDRODIBENZQ P DIOXIN (TCDD)e RECORD ALL DATA ON FORMS PROVIDED (ITEM l) IN THIS BQOXLETa
| |
| ~I IF TIE SURFACE WATER DISCHARGE APPLICANT Ktows OR HAS REASON TO BELIEVE tHAT NQT APPLICABLE BIOLOGICAI TOXtCITY TESTS WKRE MADE IN 1HE LAST THREE (5) YEARS ON ANY OF TIE APPLICANT S DISCHARGES CR ON A RECEIV[% WATER IN RELATION TD A DISO[ARGEi PROVIDE
| |
| [HIS [NFORMAT[CN AS AM ATTAOFlENT TO 1HIS APPLICATIOM>> APP[.[CABLE/SEE AlTACHED K. [F A CCMIRACT LABORATORY OR CONSULTING FIRM PERFORMED ANY OF TJE AMLAYSES REQUIRED BY THIS APPLICATIONS PROVIDE THE MJtrE AND ADCRESS OF EAOI LABORATORY OR FIRM AN)
| |
| THE ANALYSES PERFCO%D AS AN ATTACH%MT CF THIS APPLICATION.
| |
| 0 %. ~PL[~
| |
| Q APPLICABLE/SEE ATTACHED L DO YQU DISOLLRGK AMY TABLES OTIC TOXIC OR INJURIQIJS OfPIICAL SLBSTANCES NQT LISTED IN IV PAGE tt Ate I[A THIOLAI VA PAf<s ~< ~ [4 YES, THEN IDEttf[0Y TIE OrEMICAL SUBSTANCES AND ESTIMATE THE FttlAL EFFLUENT CCttCEMIRATICNS ~ SLKYIIT THIS Q tOT APPLICABLE ti&QRMATICN AS AN ATTAOMEMT TO THIS APPLICATIONS APPLICABLE/SEE ATTACHED
| |
| * Water discharged for De-Icing is the same as Outfalls 001 and 002.
| |
| Indiana Michigan Power requests permission to use the screening data for Outfall 001 and 002 to characterize this discharge.
| |
| 37
| |
| | |
| SEE INSTRUCTIONS SECTION II NUMBER ~ MI 0005827 ON REVERSE SIDE 8IIFALL INKR ~00 IT EM Ae USE THIS GATA SHEET To RECORD INFORMATION AS REDJIRED IN: (CHECK APPROPRIATE BOX RJR WHICH IMFC@1ATION THIS CATA SHEET RKPRESF2tTse) 7 CRITICAL o SECTION II, ITEN I Ee GROLIGJWATER DISOIARGE INFQJTUlTION (PAGf. 59 PRIORITY POLLUTANTS IN SlRPACE WATER DISCHAIY)E (PAGE'7)
| |
| MATERIALS CIX 2 SECTION I te ITDI 6e
| |
| 'OXIC POLLUTANTS 0 X 3, B. BElow: CRITIQAL.ATKRIALS (TABLE tv) IM svRFACE waTER Dts(HARGK (PAGE 39)
| |
| HAZARDOUS SUBSTANCES B~ LlsT AhY cRITlcAL MATERIAL (TABLE lv PAGE 6) NQT ADDREssED IM sEQTIGN I I ITKH R PR IQRITY NOT APPI. ICABLE POLLUTANTS wHICH YCV KNow OR HAVE REASON T> BELIEVE To BE PRESENT IM TIE DISCHARGE. SEE IN REVERSE SIDE OF THIS PAGE fOR FURR DIRECTtals ~
| |
| DISCHARGE X APPLICABLE (SEE BEUJW)
| |
| * Ae NAJef OF CRITICAL MATERIAL OR PRICRITY POLL%ANT IPJ IT CODE SatlPLE TYPE OF ANAIYSES Be AVERAGE CCNCEMIRATIONJ SAMPLE TYPE J tI CF Au0LYSKS WIT CODE c.. Axl~ caJCKMTRATIQN AJD Hass UNIT CODE LJ Ae JJJJeE Of CRITICAL MATERIAL OR PRIORITY POLLUTANT illCeJ B. AVERAGE CaJCEMTRATICNJ SA'usaf TYPEJ st OF ANALYSES UNIT CQGE SJE TYPE OF ANALYSES
| |
| : c. Haxtnfl caJCKMIRATtoN eo UNIT CODE lNIT CQGE Mass LJ
| |
| ~~
| |
| UNITS CODE Ae JJAHE OF CRITICAL JIATERIAL CR PRICRITY POLLlTANT 1 Mg/I B, AVERAGE CQNQEMTRATIONJ SA PLE TYPE J I OF ANALYSES UNIT CODE SJVePLK TYPE OF ANALYSES 2 Ug/I 3 WIT CODE WIT QXE LBS/DAY 4 KG/DAY Ce HAXIJ4PI CaCEMIRATICN A% MASS LJ ~ LJ Ae W% GF CRITICAL HATKRIALOR PRIORITY POLIJJTANT WIT COOK ~LK TYPE OF ANALYSES B~ AVERAGE COJJQEIITRATlotlJ SWPLE TYPEJ te OF ANALYSES LJ WIT CODE WIT CODE
| |
| : c. Haxtt1pl cowcKMIRATtat AJ4) FASS
| |
| ~~
| |
| AMPLE TYPE A JAPE QF CRITICAL HATER IAL CR PRIORITY POLLUTANT 1 GRAB WIT CODE SAWLE TYPE f OF ANALYSES 2 24 HR.COMP. B. AYERAGE CCNCDITRATION; Satuuf TYPE; JJ 0F ANALYSEs LJ LJ NIT CODE NIT CODE Ce PAXIPIJI CaJCEMIRATIat tuD MASS LJ ~ LJ
| |
| ~~
| |
| Ae,'A"E CF CRITICAL HATER IAL CR PCI IQR ITY POLLUTANT UNIT CODE StuPLE TltPE OF ANALYSES B~ AVERAGE CCNCEMTRATIONJ SAMPLE TYPEJ Pe OF tuIALYSES LJ UNIT CCDE Nti CODE C~ eVUI INH 'CONCEMIRATI ON AJD MASS LJ ~ Le Ae NA% OF CRITICAL MATERIAL OR PRIORllY POLLUTANT lhl IT CODE SAMPLE TYPE OF ANALYSES A'F ANALYSES JJ uJJ I
| |
| B. AVERAGE CmreetaTICN; SAHPLK TYPE:
| |
| LJ WIT WIT CODE CODE Ce MAXIM'aCKMIRATION AND IVES
| |
| : a. NAME OF CRITICAL MATERIAL oR PRIORITY POLLUTANT UNIT CXE SA~ TYPE OF A'IALYSES I
| |
| Be AVERAGE CaJCEMIIIATIOMJ SAMPLE TYPEJ II CF ANALYSES LJ lJN IT CODE NIT CQQK Ce ~ AX IHUl CONCENTRATION AJ4J MASS LJ
| |
| * SEE NOTE ON PAGE 37, OUTFALL 003.
| |
| ADDITIONAL PAGES QF THIS ITKH 7 ARE ATTACHED FQR T% REST QF THE CRITICAL C3 YES MATERIALS atft/CR PRIORITY POLLUTANTS REQUIRED To BE REPORTED, El NO
| |
| | |
| SECTION II PERMIT SEE INSTRUCTIONS ON REV ERSE SIDE
| |
| ~00 A TEM Ae IDCATION OF DISCHARGE t'ai%
| |
| ~SW s, ~NW 4, 6ECIIWI )~06, IM ~06 6
| |
| 6 PAI06 I I I- I Bs tIA% DF REcEIvttg HATER (IE ~ GRGUIDIATER oR wA oF sUIFAcE LAK E M I Cs DO YOU DISCHUIGE SEASONAILY~
| |
| (IF NOs CONTItAIE TO E) YES X NO DISCHARGE LOCATION De IF YESs LIST DISCHARGE PERIODS NA MO. / DAV n. / DAV SCHEDULE FLOW
| |
| ~ ~ ~. u RATE WASTEWATER CONTACT Ee LAN APPLICATION RATE INI HRs
| |
| ~
| |
| HR s/DAY WASTEIIATER lYPE CCCE
| |
| ~.'m IN,/wK EI Nr I 1
| |
| COOLING Fs lYPE OF WASTEHATER DISCHARGE L~J LJ LJ LJ LJ LJ
| |
| ~24 ~36 RATE'OTAL 2 NONCONTACT Ge DISOIARGE SO%DULE (YEARLY AVBUGE) HXNS/DAY esse sess COOLING 3 - PROCESS He DISOQRGE FLlAI YEARLY 121 . 5 4 g wipcoDE 4 SANITARY 5 STORMWATER
| |
| ~NIT gg DAILY MINION DAILY MAXINII 0. 333 0
| |
| '2 ~2 WIT=CODE 1 MGY le IHE MAXIISN DISCHARGE FUtit RATE TO BE AUIHORIZED IN PEfBITe 1 2 MGD WIT2COPE
| |
| -3 GPD J. PAXIPLH DESIGN DISCHARGE FLOI RATEe DESIGN A>> IXI YOU USE HATER TREAlHENT ADDITIVES TO TREAT YNR DISCHARGE?
| |
| (IF NO CONTIIAK TO ITBI 5) YES lTEM Be NA% FWCTICNs AND CHEMICAL CPRSITION OF TAESE AITIITIVESe 2
| |
| WATER TREATMENT NA ADDITIVES Ce NAHE AMI ACOIESS OF MAIAS'ACTINERS OF 7%SE ADO ITIVESs UNITS CODE 1 MQ/I 2 UQ/I NA UN I TS AVERAGE WITS MAXlttN WITS D. EXPECTED DISCHARGE COICENIRATICN OF ACOITIVES. NA CODE CODE CODE ACOITIVE NA%
| |
| ANITIVE NA%
| |
| ADDITIVE NA%
| |
| E~ CO YOU TREAT 1% DISCHARGE TO RENIVE AIXIITIVES? NA YES Fe ~T IS lHE RBSVAL EFFICIENCY AIID DISCHARGE FREQUENCY?
| |
| L REIOVAL HIS./DAY DAYS/WKe ACOI TIVE NA% LJ AEOI TIVE N6% LJ ACOITIVE tiVE LJ Ge AS AN AITACHIENT TO THIS APPLICATION PROVIDE SPECIFIC /%1%.IAN CR AOUATIC TOXICOUIGICAL DATA CR REFERENCE WHIOI ARE AVAILABLEAND INFORUITION CN THE RATE OF DEGRADATICN OF T% PRODUCTS FOR EACH AISITIVE NA 31
| |
| | |
| SEE INSTRUCTIONS ON REVERSE SIDE SECTION II PERMIT NUMBER ~ MI 0005827 A
| |
| IITEM A. IUPE
| |
| 'ESI OF PROCESS IXXIIRIBUTIIIGTO THE DISCHARGE THIS OUTFALL ~D SIC CODE U,l BLOW BOW,N i ~4>911 Be PROCESS SCHEDILE (YEARLY AVERAGE)
| |
| IOIIS/DAY ~24 y ~36 2 I/2 PROCESS IU C~ PROCESS WASTEIIATER FLOW RATE TOTAL YEARLY 3 6 1 1 7 wlT5Lo STREAMS Or 0 Basis: 1993 actual data submitted CONTRIBUTING 0 TO OUTFALL DISCHARGE De PROCESS on DMRs PRODUCT IOtt RATE NA DA I LY DAlLY MAXI'0 MINING LTIITS ZTI"E LJ Ih 6/2 IAI Ae Be C.
| |
| ~
| |
| NA E OF PROCESS CONTRIBUTltJG TO TIE DISOIARGE THOUGH THIS OUTFALL A'8 SIC CODE PROCESS (YEARLY AVERAGE)
| |
| PROCESS WASTEWATER FLOW RATE NA saws/svv TOTAL YEARLY
| |
| ~ seve/vsa Ocvt O
| |
| POUNDS MAXI'~OO DAILY MININH DAILY tQXWtI 2 GALLONS De PROCESS PRODUCTION RATE 3 CUBIC
| |
| ~
| |
| A. tIAtE OF PROCESS CCIIIRIBUTIta TO THE DISCHARGE YARDS THOROUGH THIS OUTFALL AlQ SIC CODE 4 TONS Be PROCESS SQEIXAE (YEARLY AVERAGE) 5 MGY ears/ssv seve/aa 6 MGD C. PROCESS HLSTEWATER FIDW RATE 7 GPD TOTAL YEARLY DAILY M INI@M DAILY D PROCESS PRODUCTION RATE UNITS CTIME TIME
| |
| ~
| |
| 1 HOUR A. NAME OF PROCESS CONTRIBUTING TO THE DISCHARGE NA TH AIS SIC CODE 2 DAY 3 WEEK B~ PROCESS SCHEIXLE (YEARI.Y AVERAGE) eases/sev seve/vas 4 MONTH UIIT CODE C>> PROCESS WASTEWATER FI.OW RATE 5 YEAR TOTAL YEARLY CAILY MINIFY DAILY De PROCESS PRODUCTIOtt RATE WITS CTIME Ae HASE OF PROCESS CONIRIBUTING TO THOROUGH THIS OUTFALL A'ID SIC CCOE IIE DISCHARGE NA MAXI'svs/vas Be PROCESS SCHGXLE (YEARLY AVERAGE)
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| I/I th Ce PROCESS HASTEIIATER FLOW RATE TOTAL YEARLY OWI O
| |
| 0 DAILY MININII De PROCESS PRODUCTION RATE DAILY M/Nit%PI WITS / TIME 33
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| | |
| "STR TI2;.'5 sSR "<<"DELETING SEGTICN I I ITEI-1S I Ai<O 2 "is crm recuires '-<cr ation cn tne !ac!<(tv's clscnarce ~coat(en, lscnarce so< ecule, vol.<<e flow rare and <<ater treatrent
| |
| =":ITFR THE P "@IT NbuBER I:I THE BOX AT THE TP GF <HIS FGfr<. THE pERMIT )AetBER CA% BE FCUNO rtl THE FRONT PAGE GF YOUR EXPIRING
| |
| "'nls 's ne<<or nct:revlousiv "er-if ec s fscil'tv, "en leave .lank enc a nu per << ~ Ii be asslcned.
| |
| E",-e< -ne cut!all r(macr ln space provided !cr each cage c! section II. ror each Individual clscnarce point 3 separate set of formS .St e '(lied Out.
| |
| 'TE'A I VATIC'I, =. nE'vJLE <I<<) LOW P>TES Enter the lccaticn of discharge, this snoulc incluce cuarter-cuarter section, cuarter sect)nn, sec(ion. town. and range.
| |
| : 3. u)St name Of reCelVlnc <<ate<< (if SurfaCe <<ater d(SCna.oe)
| |
| G. InCioate wnether !cell lty dlscharceS cn a SeaScnal basis.
| |
| If yes ~ I ist dlscnarge periods.
| |
| provide the lane application rates used or excected to be used in terms of inc),es per I,our, nours pe< cav, and inches pe< week.
| |
| F. Indicate the type of wastewater to pe discharged from this outfall. =afar to ~he wastewater tvae code divan In the left rgin. )<ore than One Code may be applicaple.
| |
| Provide the averace number of hours per day In wnlch the facllltv dlscnarges treated wastewater and the total numpe< of days per year In wnlch he cischarce occurs.
| |
| urovice current (!rom tne last l2 mcnths) or expected flow rates as recuested. Refer to unit code oiven ln the left margin for the appropriate flow units. 'GY - mllllcn calicns per year; '4lO - .Illlcn gallons per cay; GPO - gallons per cay.
| |
| provide he rax)~um discharge flow rate <<nlcn vou <<ant .o have authorized within the permit. ';0TE: ucr N>Es permits only,
| |
| .he use of such a !Iow rate will not place an actual limit restrlc.lon on the flow but will be tne flow rate used to develop effluent limits. Also, <<nen the I'onthly Operating Reports are revieweC bv Compliance staff it will help them to determine (f any new or Increased uses mlcht have occurred at the facility'.
| |
| !. Provide the design 'low for this speci!le o tfail dlscharce (e.g. oaten treatment system flow, packaoed treatment system flow, or some other finite treatment system flow).
| |
| ITEMi 2
| |
| 'xATER TREATF1ENT AOOITIYES
| |
| 'ndicate wnetner;ischa<ge <s treatec <<Ith:cndltloners. Inntb) ters, cr nicrcpfocICe. 1'ct, contirue <<o item 3.
| |
| B. Give name, functlcn, and chemical ccmposltlcn of acditives used.
| |
| lve name 5nd asc ass o.'",e manutac '; <<"',S) O< -"e <<<<<<! ITS .Sed.
| |
| '"cicate expected <<inl<,.<m. averaae snc maxi~urn Clscharce CnCent<<atlons o! tne additive(s) 'cr -nls clscnarce.
| |
| '"cicate wnetner,c treat tne olscna<ce t r~ve the ace(. Ive(s< "e!cre ciscnarne of <<astewate<.
| |
| '<dicate <<he r6 OVSI ef!IcienCV C. eaoh aCCit!Ve <rcm the <<aStewater'Snd the CISCharae !reCuenCy Of eaCn addltiVe tO the
| |
| )urface <<ater cr ..dune<<ate< .
| |
| '.") E: I Is tne respcnslbll(ty o'. the applicant to supply the product information as recuested In this Iten 4. infer<ration reauested but ro Suaalied may reSV)t in the applioatlon heine returnee to the applicant 'c< completlcn.
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| | |
| SECTION II PERMIT SEE INSTRUCTIONS t4UMBER~ M2 0005827 ON REVERSE SIDE
| |
| ~00 A TEM IS THE DISCHARGE FRCM THIS OUTFALL DIRECjED To THE GRIXÃID OR GROUNDtATERS7 I!F to CCtttlt2UE To ITEM )) YES NO 4 Ba WAS A HYDROGEOLOGICAL STUDY CR ITS EQUIVALENT BEEN PERRRKD OR ls THERE SIFFICIENT cURRENT HYDROGEQCQGIcaL ItFQIY4ATICN AYAllaBLE As REQUIRED BY Tl6 'wATER REsoURcEs "ES NO CotMISSIOtt PART ZZ GRQViDWATER RULES OF AUIUST ltt> lcM R.>23.ZZ()7 (PAGE GQ) FOR GROUNDWATER THIS EXISTM OR PROPOSED DISCHARGEZ IF YES ATTACH A COPY OF 1HE REPCRTe NA DISCHARGE CI att EXEt'PTIC;< FRCM SUBMITTING A HYDROGEOLOG ICAL REPORT UttDER INFORMATION ARE YQU REQUESTlt6 RIXE R 323,@It (l0) (PAGE La) QR FRQM GRoutcwatER MQNITCRING IIEQUpEMENts UtlDER RULE R. Z5IZ4UI (5) (PAGE II/) OF THE PART ZZ RULES>> IF YES ATTACH Q YES DOCUMENTS AND EXPI/Utattott TO DEISNSTRAIE THAT YOR DISCHARGE WQLAD QUALIFY FOR NA AN EXEPP ION.
| |
| DI ARE YQU REQUEsTING 4 vaRIattcE FRQM RULE 32312205 (PAGE THE wATER REsculcEs cotttlss tet Q (tQNDEGRADATIctt) 0F PART ZZ GRolfcwATER RIAEBT IF YEsi ATTAcH sUcH YES N)
| |
| DQIXPtENTS AS NECESSARY TO DEMOttsTRAIE Wc NEED FCR A VARIANCE ltt TERMS CF Tte cRITERIA sPEclFIED IN RILE >Z3IZZ10 (PAGE tl7) 0F 1HE PART ZZ RULEs ~ NA Es I,IST ALL CHEtt ICAL $ %stattCES WHICH ARE IN MICHIGAN S CRITICAL MATERIALS REGISlER TAB!E IV lPAGE D) AND/QR Vise EPA s PRICRITY PQILUTANT LlsT TABLE v (PAGE 7) 0R ANY GTHER sUBsTANcEs wlcH ARE oR Hav BEcctE INJURIOUS to TIE DESIGNATED USEs OF TIE cArwowtER oR TO THE PUILIC HEALTH THAT ARE DISCH4RGED QR EXPECTED To BE DISCHARGED To THE GROUIDWATERAY 1HIS NA Q NQT APPLICABLE/BELIEVED ABSENT FACILITY, ESTIMATE THE FINAL EFFLUENI'ONCENIRATION attD RECORD AIL DATA IN ITEM OF SECTta<<t IN THIS BCOasr.
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| /
| |
| TIE APPLICANT MAY BE REQUIRED To DO ADDITIONALWASTE ANALYSES. PRESENTi DATA PROVIDED IN ITEM 7 AI DISCHARGE CHARACTER I ST I CS CottCENTRAT ICtt utttS CODE 4 ANALYSES SA~ TYPE Max CODE ITEM u1 5 BO05 cQD (FIVE DAY BIOCHEMICAL OXYGEN DB'AND)
| |
| (CHEMICAL QXYGEtt Der VD) ul EXPECTED TOC (TOTAL ORGANIC CARBON)
| |
| WASTEWATER CHARAC" PtSNIA NITROGEN (As N)
| |
| TER ISTICS TOTAL SUSPENDED SOLIDS 4 UNiTS CODE totaL ptY)SFHQRUS (as p) 1 Mg/I 2 Ug/I TOTAL RES I DUAL CtLCR INE 3 COUNTS/
| |
| ~.LJ D I SSOLVED OXYGEN 100 ml MIN 4 S.U.
| |
| 5 'F ~ LJ 6 LBS/DAY FECAL COLIFORM BACTERIA ~3 TEKERATlRE (SIJY4ER) ~5 TEtfiERATURE (WINTER) ~5 BI OTHER WASTEWATER CHARAC' ST ICS SAMPLE 0 I L B G R E a s E LJ LJ ~
| |
| ~ LJ
| |
| ~
| |
| ZXBF 1 GRAB LJ LJ 2 24 HOUR COMPOSITC LJ
| |
| ~ LJ LJ
| |
| 'J SEE ATTACHED SHEETS FOR ANALYSIS DATA REQUIRED INFOIY4ATICN FQR SURFACE WATER DISCHARGEss
| |
| * Basis: 1993 actual data submitted on DMRS
| |
| | |
| '-.-Sc. res '~'c~atlcn cn tne crccess 3-"ea s nice ocr tc louse -" -~'.3 tlscbar"8
| |
| ..TE= E
| |
| -=='-" "".UBER IN TPE BCX AT '-'= " f IE .CR4. --= cEo!IIT '"trABEO C I'I BE CCUI'0 C;I TPE fRQNT OSGE CF YCUII EXPIRING lr'ng
| |
| --"S 'S 3 "eW Cr :reVIC.S< ~ 38~"-~r '~"IlitV. -ren leaVe "land and 3 number rill be OSSICnec.
| |
| E";er;.-Is ~ ~ -.-er '" 3"ace -. Cvicec ': esc-. 33 8 cr Eecticn < I. =Or eccn IncivIduai ciscnarce point 3 seoara.e set cf ITE'A fo tj ~ ~ 'r ~ r E"-er -8 "a~ "'",e OrOCeSS <<nlcn Conrlautea -O,.hiS OISCnarae. ~ ISO CrOVide 3"e Orober SIC COCe ncica-8 --e vearlv sverace crccess screcuie '" "ours cer cav ano days-cer-veer.
| |
| ?rovlde tne orOCCSS waStewater ficw rate informatiOn aS requeSteo based on your last 12 months of ooerations. Refer to
| |
| .nit code given in the left maroin for tne aooropriate flow units.
| |
| =. Ocess orcductlon Rate - .ertain "armis 'Imltatlcns mav be based cn orcductlcn rates. he oroduct'Icn rates used to tate~> .8 cermlt I'~I~S s ail be recresen-ec bv 3 reasonable measure of sctua< crocuct: n of tbe feel lltv, such as tl e
| |
| , irr 'n n > retious i ear, . 8 rCOtnlV 3'eraCe ~ ne . I nes ~ C 8 SVICOS iV8 year S ~ Cr I;ner 8 sonable assure as stated '3 scoiic ble 'E.E.P.A. Catecorlcal r'es sno reou>a-,lens.
| |
| =cr ~ew S urCeS or new OIscnarcers, actual crcouction snail be estimated vSIng orojectec =rcduCticn.
| |
| uc. I 1 rates 1 ~ "8 er<s 3no units used in the abol icaole u 5 ~ ~ .A ~ ateool ical rules and reculations for
| |
| | |
| SEE INSTRUCTIONS ON REVERSE SIDE SECTiaw II PERMIT NUMBER ~ MI pppg827 (NFNl. IVER ~00 A ITEM THE FOLLOWING REQUESTED lt>>FC{V{ATIGlt~e" >
| |
| RHEI t>>EW USE DISCHARGERS ~s>> PROVIDE 0e AXRESSED
| |
| ~eECTED VALUES
| |
| ~A>>
| |
| FOR Tt eNFACE'ATER DISCHARGERS ~
| |
| ECUAVflTATIVEAND 6 QUALITATIVE INFORMATIGN REQUESTFD BELCH>>
| |
| A>> IS THIS FACILITY A PRltARY Itt{XSTF(. (REFER TO TABLE IA PAGE +
| |
| {IF NO>> GO TO E) (IF VES>> GO TO B)
| |
| VES tO PRIORITY POLLUTANTS B~ IhDICATE TYPE GF PRIMARY ltOUSTRV AS LISTED IN TABLE IA PAGE <>
| |
| (CQttftttUE WITH C.)
| |
| ~
| |
| STM EIL EC PWR AND C. DOES THIS OUTFALL DISQ{ARGE CCtffAIN Ar{Y PROCESS WASTB{ATER.
| |
| (IF NO>> GO TO E) (IF VES>> GO TO D) X YES tO ADDITIONAL INFORMATION D>> INDICATE WHICH GC/r'S FRACTIQr{S>>MUST BE TESTED FOR ~
| |
| (REFER TO TABLE IA PA">>E ~t V{XATI LE FOR IIQIEI FCR EACH GC/MS FRACTION CHECKED>>EACH SPECIFIC ORGANIC TOXIC POLLUTANT WllHIN SURFACE WATER DISCHARGE EAGH FRAGTINt QADI BE At{ALYEMFGR (sEE TABLE I IA PAGE It>>DUSTRV APPLICANTS WITH A PROCESS WASTEWATER DISCHARGE DATA FOR EACH TOXIC POLLUTANT Itt TABLE I I IA PAGE .
| |
| ~
| |
| tt2. It( ADDITION, ALL PRIMARY PROVIDE QUANTITATIVE BASE/NEUTRAL ACID ONLY RECORD ALL DATA OM FORMS PROVIDED (ITEM 7) IN THIS BOOKLET.
| |
| (CONTINUE WITH E K BELCH) PESTICIDE
| |
| ~
| |
| ED IF OF THE IN TABLE I IA AND IVA PAGES BE PROVIDED
| |
| ~
| |
| SLIPPAGE WATER DISCHARGE APPLICANT (PRIMARY OR SECCr{DARY it{DUSTRY)>> REGARDLESS lYPE OF DISCHARGE>> KIKWS CR t>>AS REASON TO BELIEVE THAT Attf POLLVfAMT LISTED IS DISCHARGED FRCM ANY OUTFALL>> THE QUANTITATIVE DATA tOT APPLICABLE/BELIEVED ABSENT ALL DATA ON (ITS>>t 7) IN THIS BOOKLET>>
| |
| RECORD FORMS PROVIDED OX PRESENT/DATA I S ATTACHED F~ IF ANY SURFACE WATER DISCHARGE APPLICANT (PRIMARY OR SECONDARY INDUSTRY)>> REGARDLESS OF TYPE OF DISCSUIGE>> KIOWS OR HAS REASON TO BELIEVE ANY POLLUTANTS LISTED Itt X tOT APPLICABLE/BELIEVED ABSENT TABLE VA PAGE {I>>>> ARE DISCHARGED FRQ{ ANY CUTFALL THE APPLICAVT VII'ESCRIBE REASONS FOR THE POLLUTANT BEING PRESEttf At{D PROVIDE ANY AVAILABLEQUANTITATIVE DATA>>
| |
| RECORD AIL DATA GN FGIV{S PROVIDED (ITEM 7) IN THIS BOOK!ET>>
| |
| PRESEMT/DATA IS ATTAQ{ED G. AIL S{IIFACE WATER DISCHARGE APPLICANTS (PRIMARY AttD SECONDARY INDUSTRIES)
| |
| NOT APPLICABLE/BELIEVED ABSENT CR MANIA-ACTNES 2. 4i - TRIQKDRGPHEIOXV ACEftg ACID (2. 4i 5-T)l ACtD (SILVEX 2>> 4>> 5>> TP) '
| |
| E) 4>> 5- TRICHLGROPHEIOXV
| |
| -I), 5 ) AtO
| |
| . >IRIQ{LGRGPHEtOXV) PROPANOIC Z. 4. ETHYL 2, 2-DICHLGRGPRGPIGMATE (ERBGMt; 0, 4 NTRICH OROPHE{OL (TCP)>> OR HEXAQl.OROPHENE (HCP)t (AIL DATA FOR THE ABOVE t>>UST BE GEhERATED USING STANDARD At{ALYTICALCALIBRATION PROCHXRES) OR
| |
| ~
| |
| KIOWS CR HAS REASON TO BELIEVE THAT TCDD IS CR MAY BE PRESENT IN THEIR DISCHARGE>>
| |
| REPORT 9IALITATIVE DATA, GEIERATED WHICtt USED A SCREENltO PROCHXRE tOT CALIBRATED WITH AVALYTICALSTAt{DARDS>> FGR 2. >>>
| |
| (TCDD)>> RECGRD ALL DATA ON FORMS PROVIDED (ITEM
| |
| /
| |
| ))
| |
| 8>> TETRACHLORODIBENZO P DIOXIN IM THIS BOOKLET>>
| |
| PRESH{f/DATA tS ATfACHED J ~ IF THE SURFACE WATER DISCHARGE APPLICAMf KtOWS CR HAS REASON TO BELIEVE lHAT NOT APPLICABLE BIOLOGICAI TOXtCITY TESTS wHIE vADE IN THE LAST TWEE (5) YEARS OM ANY OF THE APPLtCArlT S DISCHARGES OR CN A RECEIVINS WATER IN REIATINt TO A DISCHARGE. PROVIDE THIS INFORMATION AS AV A1TAQI{EMT TO THIS APPLICATION>> APPLICABLE/SEr AlTACHED K IF A CONTRACT LABORATORY OR CCrtSULTING FIRM PERFCRMED Ath'F THE AIN{YSES REQUIRED NOT APPLICABLE BY THIS APPLICATION, PROVIDE THE NAME AND ADDRESS OF EACH LABORATCRY OR FIRM AND THE ANALYSES PERP'"Ht AS AV ATTACHMENT OF THIS APPI.ICATtON>>
| |
| X APPLICABLE/SEE AlTACHED
| |
| 'L. DO YOU DISCHARGE AN OTHER TOXIC OR INJ(PIOUS CHEMICAL S{8STANCES tOT LISTED IN TABLES IV PAGE (I Al>>D I IA THROU 4l VA PAGES V~A+>>c YES>> THEN IDENT I X tOT APPLICABLE CHEMICAL SUBSTANCES A'O ESTIMATE THE Ftt{AL EFFLUEttf CCtKENTRATICr{S. SUIT{IT THIS IhFORMATION AS AV ATTAQteENT TO THIS APPLICATIGN>> APPLICABLE/SEE ATTACHED
| |
| * Pesticide data is not required; however, it is provided.
| |
| 37
| |
| | |
| IIISTROCTIONS .Oo CCfJPLETI'/3 SECTIC!I I I ITEMS 4 ANO S
| |
| .his form reculres Inforration on a speci!ic cut!all lscnarglng to either,he grouncwaters or The surface waTBrs.
| |
| rENTER THE P ozz(T NLSIBER IN THE BOX AT THE TW CF THIS FCRM. THE PEIB(IT NONBER CAN BE FOUND Oi THE FRONT PAGE OF YCOR EXPIR(tfg CERuli ~:.', ~ 5(S (S a rew Or nOt preV(cuS(V permitted faCI I(ty, Then leaVe blank and a number Will be BSSICred.
| |
| nter -B cu~fa( I umber In The space provided fcr eben pace of Section II . For eacn individual dlscharce point a separate set
| |
| "'n-T!Bn !', '"rms (Items 'nc ) must =e filled out.
| |
| ITE)l 4 SBDJ;. WA == DISCHARGE INFCi JAT(CN (00 N"T iNCLCCE DEEP WFL(. I "JECTION INFC"NATION I'I THIS ITEvl)
| |
| A.-D. he applicant shall address each of these parts lf the clscnarce from this outfall is to the oroundwater.
| |
| ITEM 5
| |
| <ISTI "G CR EXP CTED ~ FOR A NEW O(SCHARGE) <<ASTFWATER CHAoACTERISTICS CF SR v'4)WATER OR SI'RFACE WATEo DISCHARGE (DO "OT'NCLUDE hcLL INJ 3ICN IN RNAI'I IN H r VI The applicant shall report available discharge data (real data Aor existing discharge or expected data for a prcposed d(scharge) fcr the parameters as listed. These parameters shall be addressed for either a surtace ~ater discharge or as appropriate for a groundwater dlscrarge. For assistance in determlnlno abproorlate par~ters a orcundwater dlscharce applicant may contact the
| |
| <<Arouncwater Dual (tv olvlslcn, permits section or tne appropriate Grouncwater Duality oiv(s(on's District office.
| |
| The applicant shall report the sama(e Type code best describing each reported piece of data. See coding on the left margin of this form.
| |
| If This outfal( ls a surface water ciscnarce. tne applicant must repor- ouantitative data for each parameter Identified bv an asterisk. ,he appi cant may, however, recuest That -ne report nc o, cata <<or cne or more o ~hese reouired oarai.eters be
| |
| <<aivec. Such recuest must be supported by acecuato <<atlcnale. i'ake such a recuest an attachment .o this application.
| |
| 'I'ata is availabke fcr ether parameters not IisTBd abovB (n A. or ether parts ot this application the applicant should report hat cata ln The blank spaces provldea :n this part.
| |
| I "OTES: I. Ontt codes for parameters reported In parts A and 8 can be found on the lett hand side of thIs form.
| |
| Grab samole snail be used Tc analyze tor pH, Temperature, total ohenols, residual chlorine, oil and grease, and fecal col)form In a surface water discharge unless other frecuencv-sample type analyses are available. See Glossary (pace 48) for definition of grab sample.
| |
| 24-hour ~pcs(te samples shall bo used to analvze for Total BMs, CCO, TOC, Armon(a Illtrcgen, and Total Suspended SO(iCS in 4 SurfaCe water CisCnarge un(BSS O~her freauenoy-Sample type analySeS are BVBI (able. See GIOSSary (page 48) for definition of compos(te sanole.
| |
| REPORT(l)G CF INTAKE CATA. '5u are not reruired To reOCr. unless you wish to demcnStrate yOur ellciblllty for 4 "retw sff I ent l(mltat(cn 'Cr One Or mere POllutantS, that IS, an effluent limitat(On adjuSted by SubtraCtlng the average level o! the col lutantfs) present In your Intake water. NPOES regulations al low net I (mltatlons only In certain circtmstances.
| |
| 3 I )r *u ii ').B c cnronstraTe vour ellclbl litv, -epor T the averaco of the resui 3 of analvses on your "BBT "cnt !ning Tre fc)lc in@ fcr Bach oiiutanT:
| |
| B'C B ie, B<<. e are<<sf Br '. IS T. eated) ~ \ 5 3, sebaratB (5) < state ent T"at -"B Intake water '3 drawn 'rcm Tre cccv of water. (nto which the d(scnarqe Is ~ace.
| |
| ('.Ther lse, 'ou are -;: ellcible !cr net i:m(tat(ons.)
| |
| ib) > state"ent o! e Bxront . which .ne level of tne . I futant is reduced bv Treatment of ycur <<astewater.
| |
| (Your "Im(tationa <<ill pe aajuStec Only TC The eXTent Teat the pCI(utant 3S nct remOVed ) ~
| |
| <<'C) ahen acplicao)e (tcr example, <<hen .ne pollutant represents a class of compounds), a demcnStrat(cn of the
| |
| <xtent <<o .<<wlc" ~ii<< tc(33tants i ne (~~eke very p";3'cai Iv, chemical lv, ' biological(v 'rom T"e pc(lutants contained In vour clscrarge. (Your (in(tat)cna <<Ill be adjusted only TO the extent That tne intake pollutanTS do not vary from tne d(scnargeo pollutants.)
| |
| vcu nave t'<<o or -cre i. stantial ly L cantle<<'utfs fs,,cu mav recuest cer..isslon from peur per-,ittinc
| |
| ~
| |
| 5urnoritv Tc sa<<aie ano ari)!vze on'v .-.e cut!el I snc suc. I- "B resul 3 of the analvsls fcr ether suostantlal ly CB'it3C51 cut!5(ls. '>>ur r<<ciest 3 Trente) bv -he pe~i- (no ausncrltv, cn a seoarate sheet at-ac"Bd to.the
| |
| ~
| |
| 3 ." "Icatlci. cr<<i fcenT<<( *ni ln ut'5l'i,.u die est, 5. c:ascribe wnv ne ourfai ls <<Bien . u cid .c TBST are su sT5n ial IV ldenticai zo -re ouT!all wnlch vou J(d Tes
| |
| | |
| SEE INSTRUCTIONS SECTION II PERMIT NUMBER ~ MI 0005827 ON REVERSE SIDE EM A. USE THIS DATA SHEET TO RECCRD It(FORMATION AS REOUIRED IN: (CHEQ( APPROPRIATE BOX FOR WHICH ItiFORMATICN THIS DATA SHEET REPRESEIITS )
| |
| 1e SECT ION I I P ITEM 4 Ee GROWDWATER DISCHARGE ltIFCNATION (PAGE 55)
| |
| CRITICAL 37)
| |
| : 2. SECTION IIP ITEM 6. PRIORITY POLlJITANTS Itt SURFACE WATER DISCHARIZ (PAGE MATERIALS TOXIC O X 3e B. BEIDW: CRITICAL YATERIALS (TABLE IV) IN SURFACE WATBI DISOIARGE (PAGE 2)
| |
| POLLUTANTS HAZARDOUS SUBSTANCES Be LIST AttY CRITICAL YATERIAL (TABLE IV PAGE 6) NOT ADDRESSED Itl'SECTION II ITEM Fe PRIOIIITY NOT APPLICABLE FOLUITAIITS WHICH YOU KNOW OR HAVE REASON TO BELIEVE TO BE PRESENT Itl TIE DISCHARGEP SEE IN REVERSE SIDE CF THIS PAGE FOR FUItTIFR DIRECTIONS ~
| |
| DISCHARGE APPLICABLE (SEE BaDW)
| |
| *H 00 30
| |
| ~~
| |
| Ae NAPE OF CRITICAL MATERIAL OR PRIORITY POLUITANT dr a'z inc 2 0 12 It LIt~
| |
| I Bs AVERAGE CONCENIRATIONI SAIPLE TYPE; II OF AIALYSES LJ I I.LJJ J LJ CODE SAMPLE TYPE LJ CF ANALYSES
| |
| ~
| |
| WIT CODE WIT CODE C>> teAXI.'VI CCttCENIRATION Ata YASS LJ ~ LJ As ePYYE OF CRITICAL MATERIAL OR PRIORITY POLLUTANT Bs AVERAGE CONCENTRATION; SAMPLE TYPEl lII OF ANALYSES
| |
| . LLLJ UNIT CODE LJ SAYPLE TYPE OF ANALYSES WIT CODE WIT CODE Ce YAK IF'NCENNIRIATION AttD MASS LJ
| |
| ~~
| |
| UNITS CODE Ae ttAIIE OF CRITICAL MATERIAL OR PR ICRllY POLU/TANT l Mg/I WIT SAMPLE TYPE OF ANALYSES POLUITANI'IT CODE 2 UQ/I Be AVERAGE COICENIRATICNI SAMPLE lYPEi tt OF ANALYSES LJ Wll'ODE WIT CODE LBS/DAY LJ KG/DAY Ce MAXI'ONCENIRATIONAND MASS LJ ~
| |
| ~~
| |
| Ae NAME OF CRITICAL MATERIAL CR PRIORITY WIT CCDE ~LE TYPE OF ANALYSES
| |
| : 3. AVERAGE COtICENTPATICNP SA"PLE TYPEI II OF AIIALYSES LJ UNIT CODE WIT CODE Ce YAXltul COtLENTRAT ION AND MASS LJ ~ LJ
| |
| ~~
| |
| ~PMPL YYP As NAtE OF CRITICAL MATERIAL OR PRIORITY POLLllTAttT l GRAB WIT CXE SAtPLE TYPE II OF ANALYSES 2 24 HR.COMP. I B, AVERAGE CCIICENIRATIONl SAMPLE TYPE; Itt OF ANALYSES LJ WIT CODE WIT CODE Ce eMAXIYUYI COtlCENIRATIOtt Ato YASS LJ ~ LJ Ae ttA'IE OF CRITICAL MATERIAI. OR PRICRITY POLLUTAIIT WIT CODE SVPLE TYPE h OF ANALYSES 3~ AVERAGE CCttCENTRATIONI SAMPLE TYPEp ee OF ANAI.YSES LJ WIT CODE WIT CODE Ce "AX!le'COIICENTRATIOIAte YASS Ae tIAYE OF CRITICAL YATERIAL CR PRIORllY POILUTANT LtlI T CODE SAtPLE lYPE OF ANALYSES I
| |
| : 3. AVBVGE COttCENIRATICtt; SA~ TYPE: tt OF ANALYSES WIT CODE WIT CODE Ce YAXIMNCONCENIRAT ION AND MASS LJ Ae tIAYE OF CRITICAL MATERIAL OR PRIORITY POLUJTAeVT WIT CCOE SAYPLE TYPE OF AttALYSES 3~ AVEPAGE OIWCENIRATIONI SAMPLE TYPEI II OF ANALYSES LJ WIT CODE WIT CODE Ce MAXIYLM CONCENTRATICN AttD MASS LJ ADDITIONAL PAGES OF THIS ITEN 7 ARE ATTACIED FOR TIE REST OF THE CRITICAL C3 YES MATERIALS AND/CR PRICRITY POLLUTANTS RECUIRED TO BE REPORTEDi El NO
| |
| + Hydrazine is not expected to be present in discharge but small quantities may be found in the steam generators but would not be expected to be found in the actual discharge flow to Outfalls 001 or 002.
| |
| 39
| |
| | |
| ;;iSTRVCTIr..'S c:q CCIip(.ETI r, SECTic;i I'TEM 6
| |
| his orm recuires Iniormarion on a specific ourfol I :iscnorql"c ro the sur!oce <<oters.
| |
| :"I Ec PE pERFIIT '4,'~'J)ER lii THE BOX A THE T& CF HIS PCS..fE PEPMIT ':WMSER CAN EE FOvh0 CN THE oERMIT. 'I rois is o new or not previously permitted feel litv,,hen leave plonk ana o nuroer wli I FRONT PAGE OF VCvp EXPiRING be osslaned.
| |
| e e u foi I number in the space provided fcr
| |
| ~
| |
| Sacr!cn:'I. item 6 forms nusr oe filled our.
| |
| each page o'ection II ..or each inaivicuol dlscnorce point 4 separate ser iTEM 6 opICRIr" cx)ll.UTAH(TS ANO ACOITICIIAI. I'IFCRMATION lf vou hove t<<o ar more substanrlol ly indenricoi ourfoi Is, you may reavest permission from vour perm(trina outnorlty to sample ond analyze only one outfall and submit rhe results of the onoiysls for other substantially Identical cutfalls.
| |
| If your reauest Is granted by rhe permitting outnoritv, on a separate sheet attached to rhe application form Identify
| |
| <<hlCn Outfal I ycu ald teor, Ond deSCrlbe wny ti.e OutfallS wnlah yau did rOt reSt Ore SWPStantlal ly Idenrlaal -O the Outfall
| |
| <<nich You old rest.
| |
| 'IOTE: 40 CFR Part I22.2l(g)<8), Friday, Abri I I, l983 provides for o Smail Business Exemoticn from the reporrlrg of auontitotlve
| |
| ~
| |
| aota for organic toxic pollutants ond tcxlc pollutants os reaulred by port 122.2I(g)<T)<il)(A) or 122.21(q)(7)<ili)(A).
| |
| A~ I These parts ore self-explanatory and do not require furrher Instrucrions. S(moly oo hrough each parr and do os Indicated.
| |
| ona Several Industrial categories and subcategories hove been. exempted frcm submitting dora on certain GC/ius Froctlons (40 CFR Part (22, Vol. 48, lio. 64, Friday, April I, l983, Iiotes I, 2, and 3).
| |
| Review the following list to determine whether your facility qualifies to be exempt from reportlna Gc/Ms (Gos chromotoarephy/
| |
| Moss Spectroscopy) Fractions.
| |
| GCIMS Fraction Testing ond peporrlng Exempt(cns Textile MIIIs Industry
| |
| - AII !our GC/MS organic fractions in rhe Greige MIIIs Subcategory.
| |
| - Pesriclde fraction In ail other subporrs of this Industry.
| |
| Ore Mi nina and Dressing Industry
| |
| - volatile, bose/neutral, ond pesticide fractions In rhe Base ond precious Metals subcategory.
| |
| - AII four GC/MS orqonic fractions in oll other subcategories of this Industry.
| |
| Gum and 'Wood Chemicals Industry
| |
| - Pesticide fraction in the Tall Ol I Rosin Subcategory and the Rosin Based Derivatives Subcategory.
| |
| - Pesticide and base/neutral fractions in all other subcateaories of this Industry.
| |
| eulo and Paper Industry
| |
| - Pesticide fraction in Papergrade Sulfite subcateaories (subparts J and U).
| |
| - Base/neutral and oesticlde fractions in Deink Subpart q, Oissolvlna Kraft Suboart F, and paperboard from Waste Paoer Subpart E.
| |
| . volatile, base/neutrals pesticide I'rect lons In the BGT Bleached Kraft Suboart H, Semi-chemical Subparts 8 and C. and Nonintegrated-Fine Papers Subpart R.
| |
| - Acid, base/neutral, and pesticide fractions In Fine Bleached Kraft Suboart I, Oissolvinq Sulfite Pulo Subpart K. Ground-wOOd Fine paperS Subpart 0, Harket BleaChed Kraft Subpart G ~ TiSSue frOm 'WaStepaper Subpart T and NOnintegrated TISSue
| |
| ~
| |
| Papers Subpart S.
| |
| Steam Electric Power Plant Industr
| |
| - Base/neutral fraction In the Once-Through Cooling water Fly Ash. and Bottom Ash Transport water orocess wastestreams.
| |
| 38
| |
| | |
| GENERAL CHEMISTRY RESULTS Client Sample ID: OUTFALL OOA-VI)- Date Collected: 01-26-94 Matrix: water SLOWDOWN LAL Batch ID(s): 126 im, 127 im, 128 im Date Received: 01-28-94 P0469095-040-3N Reporting,,','";. ..-,,;Date Date LAL
| |
| 'Constltuerit Method Result Detection'Umlt'.15 QualNer(s) Anal zed Sam le lD Fluoride in m IL 340.2 <0.15 03-02-94 L1 1 50-3 Bromide, inm IL 300.0 <0.050 0.050 02-17-94 L11 50-12 Nitrite-Nitrate-Nitrogen, 353.2 <0.050 0.050 02-11-94 L1150-15 inm IL Sulfate inm IL 300.0 <0.059 0.059 03-05-94 L1 1 50-12 Total C anide, in m IL 335.2 <0.020 0.020 02-07-94 L1150-18 Color 110.3 <5.0 5.0 01-28-94 L1160-3 Total Phenolics, in m IL 420.1 <0.15 0.15 02-08-94 L1 150-24 Sulfide in rn IL 376.1 <1.0 1.0 01-29-94 L1150-9 Sulfite, in m IL 377.1 < 1.0 1.0 01-29-94 L1160-6 Comments:
| |
| | |
| 0 GENERAL CHEMISTRY RESULTS Client Sample iD: OUTFALL OOA Date Collected: 01-26-94 Matrix: water BLOWDOWN LAL Batch ID(s): 126 im, 127 im Date Received: 01-27-94 PO¹69095-040-3N Reporting Data Date LAL Constituent Method Result Detection Limit Qualifieris) Anal ed Sam le ID Total Phosphorus, 365.2 <0.030 0.030 02-08-94 L11 42-8 in m /L Ammonia-Nitrogen, 350.1 <0.050 0.050 02-01-94 L1142-8 inm IL Total Suspended Solids, 160.2 <12 12 0242-94 L1 142-12 in m IL Total Organic Carbon, 415.2 1.8 1.0 02-16-94 L1 142-4 inm IL Chemical Oxygen 410.2 <18 18 01-28-94 L1142-4 Demand, in m IL Total Kjeldahl Nitrogen, 351.2 2.4 0.10 03-03-94 L1 142-8 in m /L Comments:
| |
| | |
| METALS RESULTS Client Sample ID: OUTFALL OOA-U/I- Date Collected: 01-26-94 Matrix: water BLOWDOWN LAL Batch ID(s): 126 im Date Received: 01-26-94 PO469095-040-3N Reporting Concentration Detection Umlt Data Date LAL Constituents Method lm IL) Im IL) Qualif)eris) Anal zed Sam le ID Aluminum 6010 <0.20 0.20 02-22-94 L1150-52 Antimon 6010 < 0.060 0.060 02-22-94 L1150-52 Arsenic 7060 <0.010 0.010 02-20-94 L1150-52 Barium 6010 <0.20 0.20 02-22-94 L1150-52 Be ilium 6010 <0.005 0.005 02-22-94 L1 150-52 Boron 6010 0.20 02-22-94 L1150-52 Cadmium 6010 <0.005 0.005 02-22-94 L1 150-52 Chromium 6010 <0.010 0.010 02-22-94 L1150-52 Cobalt 6010 <0.050 0.050 02-22-94 L1 150-52 Co er 6010 < 0.025 0.025 02-22-94 L11 50-52 Iron 6010 <0.10 0.10 02-22-94 L1 150-52 Lead 7421 <0.003 0.003 02-23-94 L1150-52 Ma nesium 6010 <5.0 5.0 02-22-94 L1 1 50-52 Man anese 6010 < 0.01 5 0.01 5 02-22-94 L11 50-52 Mercur 7470 <0.0002 0.0002 02-09-94 L1150-52 Mol bdenum 6010 <0.067 0.067 02-22-94 L1 150-52 Nickel 6010 <0.040 0.040 02-22-94 L1 150-52 Phos horus 6010 <0.050 0.050 02-22-94 L1150-52 Selenium 7740 <0.005 0.005 02-25-94 L1 150-52 Silver 6010 '. ~
| |
| <0.010 0.010 02-22-94 L1150-52 Strontium 6010 <0.10 0.10 02-22-94 L1150-52 Thallium 7841 <0.010 0.010 02-28-94 L1 1 50-52 Tin 6010 <0.20 0.20 02-22-94 L1 1 50-52 Titanium 6010 <0.10 0.10 02-22-94 L1 1 50-52 Uranium 6020 <0.001 0.001 03-07-94 L1 1 50-52 Vanadium 6010 <0.050 0.050 02-22-94 L1150-52 Zinc 6010 <0.020 0.020 02-22-94 L1150-52 Comments:
| |
| | |
| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 1 of 2 li n m le ID: TFALL A- I BL WD WN LAL m I ID: L117 -2 Date Collected: 31-JAN-94 Date Received: 01-FEB-94 Matrix: WATER Date Anal zed: 04-FEB-94 Anl i IB ¹: 244- -1 Dil inF r 1 QC Batch ID: 020494-8260-C1 SURROGATE RECOVERY QC Limits 1 2-Di hl h n - 4 7 -114 Tol n- -110 4-Bromofluorobenzene 110 86-115 Reporting Concentration Detection Limit Constituent IL IL Data Qualifier s Chloromethane <5 Vin I hl ri Brmm hn Chloroethane <5 Trichlorofluoromethane <5 A n 11-Di hl r h n Carbon Disulfide <5 Meth lene Chloride <5 r n-12-Dihl r hn Vin I A 1 1-Dichloroethane <5 2-Butanone <10 10 i-12-Dihl r h n hlrfrm 1 1 1-Trichloroethane <5 Carbon Tetrachloride <5 12-Dihl r h B nz n Trichloroethene TCE <5 1 2-Dichloro ro ane <5 Brm ihlrm hn 2- hl r h I Vin I E h r <2 4-Meth 1 entanone <10 10 cis-1 3-Dichloro ro ene <5 T I n r n-1 -Dihl r r n 2-Hexanone <10 10 1 1 2-Trichloroethane <5 Tetrachloroethene PCE <5 LOCKHEED ANALYTICALSERVICES
| |
| | |
| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 2 of 2 Client Sam le ID: OUTFALL OOA-U/I BLOWDOWN LAL Sam le ID: L1175-23 Reporting Concentration Detection Limit Constituent IL IL Data Qualifier s Dibromochioromethane <5 hl r nz n Eh I n n m -X lene <5 o-X Iene <5 r n r m f rm 1 1 2 2-Tetrachloroethane <5 1 3-Dichlorobenzene <5 1 4-Di hl r nz n 1 2-Dichlorobenzene <5 LOCKHEED AIVALYTICALSERVICES
| |
| | |
| SEIVIIVOLATILEORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Pa 1 of 2 li n Sam I ID: TFALL A-U I BLOWD WN LALSml ID: L11 Date Collected: 26-JAN-94 Date Received: 28-JAN-94 Matrix: WATER Dilution Factor: 1 Anl i IB h¹: 2 4- 27-A D Exr d: 1-AN- 4 QC Batch ID: 8270 SEMIVOLATILES 4825 Date Analyzed: 04-FEB-94 SURROGATE RE VERY 00 QC Limits 2-Fluoro hanoi 42 21-100 Phenol-d, 30 10-94 Nitrobenzene-d, 84 35-114 2-Fl oro 'en I 4 -11 24 -Tri r mo n p-Terphenyl-d,4 38 33-141 Reporting Concentration Detection Limit Constituent IL IL Data Qualifier s Phenol <10 10 i 2- hl r h I h r hir hnl 1 3-Dichlorobenzene <10 10 1 4-Dichiorobenzene <10 10 Bnzl I hl 1 -Di hl r nz n 2-Me h I henoi <10 10 bis 2-Chloroiso ro I ether <10 10 4M h I h n I N-Ni r -Di-n- r I in Hexachloroethane <10 10 Nitrobenzene <10 10 I hrn
| |
| -Nir h n I 2 4-Dimeth I henol <10 10 Benzoic acid <50 50 i 2-hlr hx m hn 24-Dihl r hn I 1 2 4-Trichlorobenzene <10 10 Na hthalene <10 10 4- hl r nilin <10 Hx hlr u in 4-Chloro-3-me h I henol <10 10 2-Meth Ina hthalene <10 10 Hexachloroc clo entadiene <10 10 LOCKHEED ANALYTICALSERVICES
| |
| | |
| I SEIVIIVOLATILEORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Pa e2of2 Client Sam le ID: OUTFALL OOA-U/I BLOWDOWN LAL Sam le ID: L1 1 50-30 Reporting Concentration Detection Limit Constituent ( /L) I /L) Data Qualifierls) 2 4 -Tri hloro hanoi 10 4 -Trihl r h n I 10 2-Chlorona hthalene <10 10 2-Nitroaniline <25 25 Dim h I hh I 10 A n hhln 2 6-Dini rotoluene <10 10 3-Nitroaniline <25 25 A n hhn 2 4-Dini r h noi <2 4-Nitro henol <25 25 Dibenzofuran <10 10 2 4-Dini r I en Di h I hh I 4-Chloro hen I- hen lether <10 10 Fluorene <10 10 4-Ni r nilin <2 1 2
| |
| 4 -Dinir m h I h n I N-Nitrosodi hen lamine <10 10 4-Bromo hen I- hen le her <10 10 Hx hlr n n Pn hlr hn I <2 Phenanthrene <10 10 Anthra cene <10 10 r z I Di-n- I hh I Fluoranthene <10 10 P rene <10 10 B I nz I'hh I 3'-Di hl r nzi in <20 20 Benzo a anthracene <10 10 Chr sene <10 10 i 2-Ehlhxl h I Di-n- I hh I Benzo b fluoranthene <10 10 Benzo k fluoranthene <10 10 Bn rn In n 12 r n Dibenz a h anthracene <10 10 Benzo h i er lene <10 10 LOCKHEED ANALYTICALSERVICES
| |
| | |
| SEMI-VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8270 TENTATIVELYIDENTIFIED COMPOUNDS Client Sample ID: OUTFALL OOA-U/I BLOWDOWN LAL Sample ID: L1150-30 Date Received: 28-JAN-94 Date Analyzed: 04-FEB-94 Matrix: WATER Dilution Factor: 1 Analytical Batch: 020394-8270-A QC Batch ID: 8270 SEMIVOLATILES 4825 Estimated Retention Concentration Time Data Tentatively Identified Compound (yg/L) (minutes) Qualifier(s)
| |
| Unknowm Organic Acid 25.24 f Cn LOCKHEED ANALYTICALSERVICES
| |
| | |
| OIL AND GREASE EXTRACTABLES ANALYSIS RESULTS BY FT/IR USING IVIETHOD 413.2 lin m I ID: TFAL - IBL WD WN A m I ID: 11 .42 D Ilc:2-AN-4 D An I z: 7-FEB- 4 Date Received: N A Dilution Fac or: 1 Matrix: WATER Da e Extracted: 02-FEB-94 Anal tical Batch ¹: 020494-413.2 QC Batch ID: 020294-413.2 Reporting Constituent Concentration Detection Limit Data QualifierIs) m /L m IL Oil and Grease LOCKHEED ANALYTICALSERVICES
| |
| | |
| PESTICIDE ANALYSES RESULTS BY GC/ECD USING METHOD 8080 Cli n S m ie ID: TFALL 0 A-U I BL WDOWN LAL'S m I ID: L11 Da Coll e:2 - AN- 4 D R ive:2-AN-4 Date Extracted: 31-JAN-94 Date Anal zed: 01-FEB-94 Matrix: WATER Dilution Factor: 1 Analytical Batch II: 013194-8080-E-4 QC Group ID: 8080-PEST/PCBS 4822 SURRO ATE RECOVERY o QC Limits TCMX DCB 69 27"
| |
| '0-150 60-1 50 r Reporting Constituent Concentration Detection Limit Data Qualifier(s)
| |
| L L A-BH B-BHC <0.05 0.05 G-BHC <0.05 0.05 D-BH HEPTA H R ALDRIN <0.05 0.05 HEPTACHLOR EPOXIDE <0.05 0.05 HL R DANE END ULFAN I A-CHLORDANE <0.05 0.05 4 4'-DDE <0.1 0.1 4 4'-DDT DIELDRIN ENDRIN <0.1 0.1 ENDOSULFAN II < 0.1 0.1 4 4'-DDD ENDRIN ALDEHYDE ENDOSULFAN SULFATE'ETH
| |
| <0.1 0.1 OXYCHLOR <0.5 0.5 T XAPHENE P B-1 1 PCB-1221 <2 PCB-1232 P B-1 4 PCB-124 PCB-1 254 PCB-1260 TECHNICAL CHLORDANE TCMX - tetra-chloro-meta-xylene DCB - Deca-chloro-biphenyl LOCKHEED AIVALYTICALSERVICES
| |
| | |
| RAD DATA REPORT (ra01)
| |
| Indiana Nichigan Pouer Co. e Bridgman,HI Organic and Inorganic Contaminants (project COOK.JENI)
| |
| Client Sample ID: OU'IFALL OOA-U/I BLOlDOMN LAL Sample ID: L1150-46 i
| |
| Date Collected: 26-JAN-94 Date Received: 28-JAN-94 Hatrixt Mater Login Number: L1150 Gross Alpha 23-FEB-94 GR ALP/BETA LAL-0060 4756 0 0.69 1.5 pC I/L Gross Beta 23-FEB.94 GR ALP/BETA LAL-0060 4756 30.2 3.2 3.1 pCi/L Page 6 nag
| |
| <v'5
| |
| | |
| RAD DATA REPORT (ra01)
| |
| Indiana Nichigan Parer Co.
| |
| * Bridgman,NI Organic and Inorganic Contaninanta (Project COOK.JENI)
| |
| Client Sangria ID: OUTFALL 00A-U/I BLOUDOMN LAL Saapie ID: L1150-49 Date Collected: 26-JAN-94 Date Received: 28-JAN-94 Hatrixt Water Login Nmhert L1150 Ra-226 22-FEB.94 RA-226 LAL.0073 4771 0 0.14 0.34 pCI/L Ra-228 23.FEB-94 RA-228 LAL-0074 5503 0.62 0.56 0.91 pCI/L g Page 9
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| | |
| h
| |
| ~
| |
| I
| |
| | |
| PH Analysis (LAB.079)
| |
| PH Meter cpc y- lo~ Outfall OOA Cal date due Sample Time 0 P D Sampl'e g Sample Date CDM Entered by
| |
| : 6) Sample C/ph (prior to g oz.
| |
| correction) 5.3.5 7) NH3 pH correction 5.3 ' 8) )ample results Sample NH C/pH 3
| |
| (after Correction)
| |
| '7. 7 g m cux-4~/ +/7 >+ U + /L p'-
| |
| +boa Zoo Sample Time Sample jj Sample Date CDM Entered by
| |
| : 6) Sample C/ph (prior to correction) 5.3.5 7) NH3 pH correction 5.3.6 8) Sample results C/pH (after
| |
| ~
| |
| Correction)
| |
| : 9) LAB.041 Specs Verified by: hl/8 Supervisor Review/Date W+IW Form prepared by/Date Form approved by/Date 12 THP LAB.041.25s Revision 1
| |
| | |
| --4 Determination of Total Chlorine Instrument CPCf)
| |
| (Lab 170)
| |
| Outfall OOA Technician Vi Sample/Standard Sample g
| |
| ) So /0 ~~'~ ~(y Date Time ~~/'/
| |
| CDM Entered by l) Absorbance 6.11 2) Results, ppm
| |
| : 3) Dilutions made
| |
| : 4) Results, ppm z oC (I)2 ~ 0 3) 51 LAB.041 Specs Verified by:~N Fl luperi rvRsecview/Bere~~HI + Form prepared by/Date Form approved by/Date ~
| |
| ~~
| |
| 12 THP LAB.041-25)l Revision 0
| |
| | |
| SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I PERMIT
| |
| ~ gZ ppp582
| |
| ~% tS Iy~ A. LOCATIOtt OF DISCHARGE ASSt i, ~W i, >>ZCTIUN t~06, iUPN ~06 S, iTTUE ~i9 W 8>> tIA%
| |
| HA RECEIVlttG HATER IIE>> GROItZHATER OR NAPE OF SIRFACE LAIKE MI C HI C>> DO YCU DISCHARGE SEASOttALLY>>
| |
| (IF ttOP CCIIT!t@E TO E) YES X ta DISCHARGE LOCATION D. IF YES>> I.I ST DISCHARGE PERIODS NA Nt. / DAY Nt. / DAY SCHEDULE FLOW
| |
| ~Typ RATE WASTEWATER CONTACT COOLING SE E.
| |
| F>>
| |
| EAtS APPAIIATI>>ti IIATE TYPE OF HASTEHATER DISCHARGE NA ~
| |
| L~ J IN>> HRe
| |
| ~ M LJ
| |
| ~
| |
| LJ HR>> DAY
| |
| ~ M HASTBIATER lYPE COKE LJ
| |
| ~~
| |
| LJ IN>>/WK>>
| |
| ~
| |
| LJ 0 N NONCONTACT G~ DISCHARGE SCHZUIE (YEARLY AVERAGE)
| |
| HOURS/DAY ~24 a>>>>PS>>>> ~36 COOLING PROCESS He DISCHARGE FLCH RATE TOTAL YEARLY 157 . 68 SANITARY STORMWATER DAILY HININII p ~2 U~NIT GUS DAILY HAXINN 0 . 432 ~2 1 MGY Ie THE NXINN DISCHARGE FIDH RATE TO BE AUIHCR IZED IN PERHIT>>
| |
| 2 MGD S GPD Je>>"AXING DESIGN DISCNRGE FIM RATE>> DESIGN A>> IX) YOU USE HAlER TREATHENT AKDITIVES TO TREAT YON DISCHARGE?
| |
| (IF NO, CCNTINIE TO ITBI 3)
| |
| ITEM Bi NtNE FIICTIOtt>> At%I CHEHICAL COMPOSITION OF lAESE AKDITIVES>>
| |
| 2 WATER NA TREATMENT ADDITIVES Ce NAME AND ADKRESS OF HAIAFACTIRERS OF lHESE AISLE IT IVES e UNITS CODE 1 Mg/I NA 2 Ug/I H IN INN UNITS AVERAGE W ITS HAX INtt WITS D. EXPECTED DISCHARGE CCtCENTRATION OF AIKIITIVES~ NA CODE CODE CODE ADDITIVE NA%
| |
| AKDITIVE NA%
| |
| ADDITIVE NA%
| |
| E DO YOU TREAT THE DISCHARGE lQ RENIVE ADDITIVES? NA Q YES LJ:~ LJ F HHAT IS IHE RENIVAL EFFICIENCY AND DISCHARGE FREOUENCY NA K RENIVAL NS>>/DAY KAYS/WK~
| |
| ADDITIVE Nt4% LJ ADDITIVE NAHE ADDITIVE NA%
| |
| Ge AS Att ATTACIPENT TD lHIS APPLICATION PROVIDE SPECIFIC ÃtNVLIAVCR AOUATIC TOXICOUYilCALKATA OR REFERBICE HHICH ARE AVAIIAIREND INFORHATION ON THE RATE OF DEGRADATION OF THE PRODUCTS FOR EACH ADDITIVE~
| |
| NA 31
| |
| | |
| >>VSTr~XTI".'IS E R CCMPL~:IQ SECT:"'I I I ITEM 7
| |
| '.is fse ls to'e used ov both surfaCe and grcunc~ater aap((cents tc record in!crratlcn on anv Michigan critical material, E.P.A.
| |
| :rlcri-v ollu.ant cr nazarcous
| |
| ~ substance In>>>>nlch tnls app(ication reouires cata to be provided. This vould include any chemical substance from the Michigan Cr Itlcal Materials Register (Table IV), the E.P,A. Priority Pollutant Listing (Table v), or Tables
| |
| ~ .A->>z n(cn liatS "rganiC Toxic col~ rants..ther axle Pollutants, Conventional and Nonconventional Pollutants and Hazardous ps a",ces,
| |
| ',Tel 7 "R! Tl" L uATEPIAIS. op(DR(TV PDLL~F<rITS. ~
| |
| ID/CR uAZARDNS SL>>BSTAMCES IW THE DISCHARGE
| |
| "'a-er I s>> I '
| |
| ;st the name of the cnemlcal substance (crltlca) material, priority pollutant, or nazardous substance) from Tables IV, V
| |
| -no IIA-vi as reauirea ln the oox which ycu cnecxeo in A.(-3 . above. Enter each cnemlcal substance's parameter number as (lsted in Tables IV, V and IIA-VA It provided.
| |
| --ovlde trs aierace ccncenrra.icn -..'-e cnemicai supstance rarao :n A. '-c(cate tre semble type used and tne number of ZnalySeS race tO prCVlde the CCnCentratlCn data IOr .he CnemlCal SubStanoe named In A.
| |
| C. Provide the maximum concentration and determine the mass loading of the chemical substance named In A
| |
| '>>DTES: l. (t cnlv one analysis vas mace tor a cher>>ical substance then record +hat data as a maximum value. (f more than one analysis nas been made tor a chemical substance then provide an averaoe value of those analyses and the maximum value ~
| |
| Z.,his Section II, Item 7, ata Sl.eet prov(des space fcr recording cata tor 8 chemical subStanceS (Materials).
| |
| zcsitlcnal space 'or t"cr"ing . cata rcr more than 8 "arorials c n ce mace by maxing cbies cf this item 7 Data Sheet aS needed. it >>S alSO rpOrtant tO uSe a Separate Set Ot Data Sl.eeta fcr eaon applloable repcrtlng requirement as listed In A.l-3. and for aacn outfall.
| |
| "efer Io The left maroln for the code number representing tne sample type used and the appropriate unit codes.
| |
| 40
| |
| | |
| SEE INSTRUCTIONS ON REVERSE SIDE SECTION II PERMIT NUMBER ~ MI 0005827 NIFALL tltKR As B
| |
| tIAPE OF PRXESS COIIIRIBUTIIIG TO THE DISCHARGE TlROUGH THIS OUTFALL A'Q SIC CODE SCHHXLE (YEARLY AVERAGE)
| |
| U 2 BLOWID OWIN ~till PROCESS IDURS/DAY L224I v /v I/I C/I Cs PROCESS WASTEWATER FLOW RATE
| |
| ,PROCESS III OE TOTAL YEARLY 2 2 QJ STREAMS 0 Basis: 1993 actual data submitted CONTRIBUTING II DAILY HlttINtt on DMRs TO DAILY HAXII/IN i0 . 234 ~6 OUTFALL DISCHARGE Ds PROCESS PRODUCTION RATE NA UNI TS / T IPE
| |
| ~
| |
| A>> ttA% OF PROCESS CONIRIBUTIIG TO THE DISCHARGE TIROUGH THIS OIIFALL AtEI SIC COPE Be PROCESS SCIEIXAE (YEARLY AVERAGE) sssvM/Osv sEvs/vEM Itt Itt C. PROCESS WASTEWATER FLOW RATE TOTAL YEARLY Oust CI K
| |
| DAILY MINING 1 POUNDS DAILY I/AXI PIN 2 GALLONS Ds PROCESS PRODUCTION RATE
| |
| ~
| |
| 3 CUBIC
| |
| ~
| |
| Ae tIAt% OF PROCESS COIIIRIBUTIt4 TO THE DI SCHULE YARDS THOROUGH THIS OUTFALL AttO SIC CODE 4 TONS Bs PROCESS (YEARLY AVERAGE) 6 MGY Esrs/Er Esvs/vs@
| |
| 6 MGD Ce PRXESS WASTEWATER FISH RATE 7 GPD TOTAL YEARLY DAILY HINIPIN DAILY HAXINPI
| |
| ! ME D. PROCESS PRODUCTION RATE WITS STIPE
| |
| ~
| |
| 1 HOUR A. NAHE OF PRXESS CONIRIBUTING TO TIE DISCHARGE NA TH AtID SIC CODE 2 DAY 3 WEEK B. PROCESS SCHEDULE (YEARLY AVERAGE)
| |
| !EEE/ssv seve/vs!I!
| |
| 4 MONTH I/I WIT CODE III Cs PROCESS WASTGATER FLOW RATE 5 YEAR TOTAL YEARLY OMt O
| |
| 0 DAILY MININN DAILY HAXltlN D.
| |
| WITS /TINE PROCESS PRODUCT IOII RATE A. VW% OF PROCESS CONTRIBUTING TO TIE DISOQRGE NA TIROUGH THIS OUTFALL AND SIC CCDE Be PROCESS SCHHXAE (YEARLY AVERAGE) vevs/vsM Ce PROCESS WASTEttATER FLCH RATE WIT %DE TOTAL YEARLY DAILY Hl NltXN De PROCESS PRODUCTION RATE DAILY HAXINN UNITS / TltE 33
| |
| | |
| INSTRUCTIONS FCP. CCIsPI.ETING SECTICN I I ITEM 3 T~ IS farn requireS infarmetlCn On tre OrCCeSS S-reamS WhiCh Cantrlbute TO thiS dlSCnerge.
| |
| NTEo t" E PEP'4 I T NlPIBER IN THE BOX AT . HE TCP CF TH IS FCRAI THE PEPSI T IeIMBER CAN SE FOUND CN THE FRONT PAGE OF yCUR EXP I R ING
| |
| <<Rui . If rnis Is e new or i,at previously "emit,ed facility, then leave blank end a number will be assigned.
| |
| Enter ' ~ ~ 31 I numaer in SOaCe OrOViCed fOr eaCn Oaqe Of SeCtian I I ~ mar eeCn indiVICual diSCherCe paint e Separate Set Cf Secticn il 'orms must oe filled out.
| |
| ITEM 3 PROCESS STREAMS CCNTRIBLITING TC QISCHARGE: <CR EACH SEPARAT" FPOCESS PROVIDE THE FCLLCNIISI INFCONATICii A, Enter tne here of the prccess which contributes to this discharge. Also orovlde he prcoer SIC code.
| |
| S. Indicate The yearly average process schedule in hours per day and days-per-year.
| |
| Provide cne orocess wascewacer fiihv race information as requested based on your last l2 months of operations. Refer to unit code given In the left margin for the appropriate flow units.
| |
| O. Process Production Rate - Certain pernlt linitatlons mey be based on production rates. The production rates used to determlre oernit linlts shell be reoresented by a reasonable measure of actual production of the facility, such as the production curing the rign ncnth cf the previous year, or the nanthly averace for tne hiahest of the previous five years, or other reasonable measuc e as stated In aoolicabie U.ST E.P.A. categorical rules and regulations .
| |
| =cr new sources ar new dlschergers, actual raduction shall be estimated using projected oroduc.ian.
| |
| Reccrd your -. ocuctlcn rates In tne terns ano units used in tne eoolicaole V.S.E.P.A. csteaarical rules and re-ulations for iour tvpe of facility.
| |
| | |
| SECTION II SEE INSTRUCTIONS 74UMBER~ MI 0005827 ON REVERSE SIDE
| |
| ~00 8 Ae IS THE DISCHARGE FROM THIS OUTFALL DIRECTED To THE GRONID OR GRSNWATERS? (IF ttOe CCttTlttUE To sTEM 5) YES Be HAS A HYDROGEOLOGICAL STUDY OR ITS EQUIVALEIIT BEEN PERFORMED OR tS ThERE SIFFICIENT CURRENI'ÃXOGEOLOGICAL thFONATICN AVAILABLEAS REQUIRED BY TIE WATER RESOURCES lee Cotttlsstott PART 22 GROUNDWATER RULES OF AUIUST ltl4 1980 R ~ 523eZ707 (PAGE Q) FOR GROUNDWATER THIS EXIST!t7G OR PROPOSED DISCHARGE. IF YES ATTACH A COPY OF TWE REPORT. NA DISCHARGE Ce ARE YCU REQUESTttg AN EXP'PTICN FRI¹t SUBMITTlt4 A HYCROGEOLOG ICAL REPORT l5DER INFORMATION RULE R.323.22F (Q(PAGE t15) OR FRCM GRONGtwATER MONITORING I)EQUJREYSNlS YES UIIER RULE R. Z5e (>) (PAGE fQ) OF THE PART R RILES>> IF YES ATTACH NA DOQNEIITS AND EXPlA'VLTION To DEIONSTRATE THAT YOUR DISCHARGE WOULD QUALIFY FCR AN EXPIRE loth De ARE YOU REQUESTING A VARIANCE FRCtt RULE 323.2205 (PAGE 5) (tgNDEGRADATION) Of THE WATER RESIX¹ICES COB% I SS ION PART 22 GRONG5ATER RULEST tF YES ATTACH SUCH YES DOCI¹'EATS AS h'ECESSARY To DEMONSTRATE THE NEED FOR A VARIANCE Itt TERMS OF THE CRITERIA SPECIFIED IN RIIE 5'DeQ10 (PAGE + OF THE PART 22 RULESe NA E~ I IST ALL CHEIIICAL SISSTANCES WHICH ARE IN MICHIGAN S CRITICAL PATERIALS REGISTER TABLE IV IPAGE D) ANWOR UeSe EPA S PRIORITY Pou UTANT LIST TABLE V (PAGE
| |
| : 7) OR ANY OIIKR SUBSTANCES NOT APPLICABLE/BELIEVED ABSENT NltcH ARE 0R HAY BEcot% INJI¹IIQUs To TIE DEB IGNATED UsEs 0F TIE GI(tx¹GIHaTER 0R To THE PUBLIC HEALTH THAT ARE DISCHARGED OR EXPECTED To BE DISCHBRGED To THE GRtX5DWATERAY THIS FACILITY. ESTIMATE THE FINAL EFFLLENT CottCENIRATICN Atto RECORD ALL DATA IN ITEM 7 OF SECI'ION II IN THIS BooleLET. NA
| |
| ~
| |
| TIE APPLICANT MAY BE REQUIRED 'ID Do ADDITICtIALWASTE ANALYSESe PRESENTS DATA PROVIDED IN ITEM 7 Ae DISCHARGE CHARACTERISTICS COIICENIRATION I¹IITS CODE lt ANALYSES TYPE ITEM u1 CODE 5 BOD5
| |
| 'COD (FIVE DAY BIOCtetICAL OXYGEN DEMAIO)
| |
| (CHEMICAL OXYGEN DEMAND) ul EXPECTED TOC (TOTAL ORGANIC CARBON)
| |
| WASTEWATER CHARAC-TERISTICS ennta NITROGEN (As N)
| |
| ~8, U
| |
| 1 2
| |
| Mg/I Ug/ I COOE TOTAL SUSPENDED SOLIDS TOTAL FHQSFHOIIUS TOTAL RESIDUAL (as p)
| |
| CtiXR!ttE
| |
| ~6 u1 u1 ~ u 3 COUNTS/
| |
| ~.LJ 100 ml DISSOLVED OXYGEN HIM 4 S.U.
| |
| 5 F PH ~
| |
| LJ 6 LBS/DAY FECAL COLIFORM BACTERIA TEMPERATI¹IE (Su¹4ER)
| |
| TEtPERATI¹IE (WlttTER)
| |
| ~
| |
| ~u ~
| |
| ~
| |
| u u5 u5 Be OIHER WASTEHaTER CHARACTERISTICS SAMPLE 0 I L It G R E A S E u
| |
| 1 ZYRF GRAB u LAJ u u
| |
| ~
| |
| 2 24 HOUR COMPOSITE u u LJ SEE ATTACHED SHEETS FOR ANALYSIS DATA REQUIRED INFORMATION FOR SURFACE WATER DISCHARGES.
| |
| * Basis: 1993 actual data submitted on DMRS 35
| |
| | |
| INSTRUCT ICNS FCR CCIZPLET>taS SECTION I I ITEMS 4 ANO 5 his !orm recuires Information cn a specific ou. aa> I discharging to either the grouncwaters or the su! face >>aters .
| |
| NTER T,E P RMIT IIPIBER If< THE BOX AT THE TCP CF THIS ORM. THE PERMIT NUMBER CAN BE FOUND ON THE FRONT PAGE OF YOUR EXPIRING
| |
| " OMITS lf Tn)S IS a ne>> Or nOt DreVIOuSly permitted faClllty, then leaVe blank and a number s<<ill be aSSlcned.
| |
| Enter -"e umfall number in the soaCe provided for eacn Dade Of SectiOn II. For eacn individual d Ischarce point a separate set Se TI n II !brms (Items 4 anc 5) must be !Illed out.
| |
| ITEM 4 ROJlO'".ATEP DISCHARGE INFCRuaTIC.'I (OO NOT ll>CLsJDE DEEP 'HELL INJECTION INFORMATICN IN THIS ITEVI)
| |
| A.-O. The aoploCant Shall addreSS eaCh Of theSe carta lf the dlSCharge frcm th>S Outfall IS tO The Orcund>>ater.
| |
| ITEM 5 5'<IS I'6 CP E<PECTEO (Fgo A NEN DISCHARGE) NASTENATEa CHaRaCTERISTICS QF GROUIC>HATER CR SURFaCE ><ATEo DISCI!ARGE (00 .<OT INCLUDE It>>>uws ION Isn Rvas ls!N It< sHla F>>M The applicant shall report available discharge data (real data for existing discharge or expected data for a proposed discharge) for the parameters as listed. These parameters shall be addressed for either a surface water discharge or as appropriate for a grcundwater dlscnarge. For assistance in determining aoproprlate parameters a groundwater dlscnarce applicant may contact the
| |
| ".roundwater Quality 0>vision, Permits Sec. Ion or The approorlate Groundwater Quality Olvlslon's District office.
| |
| The applicant shall report the sample tvpe code best describing each reported olece of data. See coding on the left margin of Tnls fern.
| |
| If This outfall is a surface <<ater cischarce. The ecol>cant must report nuantltatlve data for each parameter Identified bv an oot << -. t. e r,;sa "... .e *oa S a re o m se oa a o >>e e ~ oe
| |
| * . o.. ' . o. s aoa a ot sa a t* I-" s . :t t s' es e t s t . .si asia If data iS aVal >able fC< Other parameterS nOt I!Sted abOVe In A. Or Cther OarTS Of th(S aopliCatlOn Tre aopliCant Shculd repart That data in the blank spaces provided ln this part.
| |
| ssOTES: I. Unit COdeS fcr parameterS repcrted In par tS A and B Can be fcund OO the left hand Side Of th>S fOTTn.
| |
| : 2. Grab samole shall be used to analyze for pH, tempe<ature, Total ohenols, res(dual chlorine oil and grease, and
| |
| ~
| |
| fecal coliform in a surface water discharge unless other frequency-sample type analyses are available. See Glossary
| |
| <page 48) tor definition of grab sample.
| |
| : 3. 24-hour ccmposlte samples shall be used to analyze for Total 9005, COO, TOC, armenia Nitrogen, and Total Suspended Solids In a Surface water diScharge unless other frecuency-Sample type analyses are aval lab le. See Glossary
| |
| <page 48) tor definlt'lon of composite sample.
| |
| REFQRTI'a<<DF >i<TAKE DATA. You are not recuirec to reocrt unless you wish To demonstrate your ellclbl lity for a
| |
| <<net" effluent limitation fcr one or more pollutants, that Is, an ef fluent limitation adJusted by subtracting the average level of the pollutant(s) present in your intake water. NPOES regulations allow net limitations only in certain c(rcumstances. To cemonstrate your eliclbl llty, report the average of the results of analyses on your intake <<ater (If your wate>> is T. eated before use, .est tne water after It Is treated), anc attach a separate sheet containing the fcllo<<ipo fo! each pollutant:
| |
| (a) a state ent That t"e intake <<ater 's drawn !rcm tr e body of water into wnich the discharge Is mace.
| |
| (Cthe! <<ise, you are ",c e!Iolb le fcr rat limitations,)
| |
| a state"ent of '".e e<<tent Tc <<nlch the level cf The Dollutant Is reduced bv Treatment of ycur <<astewater.
| |
| (You! limitations <<Ill be adJusted only To Tne extent that tne pollutant is not removed.)
| |
| (c) 'when aDDllcaole <for example, when the pollutant represents a class of ccmpounds), a demonstration of the exten~ to which tne pollutants <n the inta'ke ve!y phvslcally, chemlcallv, or ololo<>icallv fr@-. Tao pollutants Conte nec .- VCur CISCbarre. <<YCur s:mitat(cnS <<:II be ad!uSTed C! Iy -" Tne eXTe~t T>>at The lrtake DOllutantS Co not vary frcm tne dlscnarceo pollutants.)
| |
| <a vou have t"o or more suosTantlally incentlcal cutfalls, you mhv reauest permission from your Der...lttlng author:Tv c sa-:D!e anc analv e on!v n< cu fall and suan(T <<ne results of ne analvs(s '.cr other substantially cent c I uT alis, ~ 'cu - ec!esT ls ran eo y Tne perm>. Inc auThol Itv cn a sepal aTe shee aTTacrec To tl'e
| |
| ~ ~
| |
| Topi>ca>>cn form (centi!y which cutfall you clc test, and cescribe wnv The outfalls wnich vou c(d not test are SuOSTantially IdentlCal TO The Outfall wn<Cn Vcu Old teST.
| |
| | |
| SECTION II PERMIT HI 0005827, SEE INSTRUCTIONS NUMSER ON REVERSE SIDE THE FOLLCWING REOUESTED IPJFORYATION c~>s oc ADDRESSED KIIE! JJEW USE DISCHARGERS ~e"
| |
| ~ SURFACE WATER DISCHARGERS.
| |
| PROVIDE EXPECTED VALUES FOR THE OUAMTITAT IVE AND OVALI TATIVE IPJFOJU AT ION REOUESTED BELOW I AI IS THIS FACILIIY A PRIMARY I'JDUSIRY? (REFER TO TABLE IA PAf< 4J)
| |
| (IF tQ, GO TO E) (IF YES, GO TO BI X YES JJO PRIORITY POLLUTANTS B. IPJDICATE TYPE OF PRIMARY IPJDUSTRY AS LISTED IN TABIE (CCPJTIMJE WI TH C.)
| |
| IA PAPJE 491 ELEC PWR C. DOES THIS OUTFALL DISCHARGE CCPJTAIN Ath'ROCESS WASTEWATER?
| |
| AND X YES (IF NO> GO TO E) (IF YES'O TO D) JJO AOOITIONAL INFORMATION DI ItJDICATE WHICH GC/MS FRACTIOtJS MUST BE TESTED FCR ~
| |
| (REFER TO TABLE IA PAGE 4~I X vJXATILE FOR KIIE. FOR EACH GC/MS FRACTION CHECKEDY EACH SPECIFIC ORGANIC TOXIC POU.iffANf 'HITHIN SURFACE WATER DISCHARGE MH FRACTIOti 557 BE APJALYZED FOR (SEE TABLE I IA PAGE INDUSTRY APPLICANTS WITH A PROCESS WASTEWATER DISCHARGE DATA FOR EACH TOXIC POLLUTANT IN TABLE lllA PN4 JI3 a
| |
| ~
| |
| 42, IN ADDITIOPJ ALL PRlt"ARY PROVIDE OUAMTITATIVE BASE/NEUTRAL ACID ONLY RECORD ALL DATA ON FORMS PROVIDED (ITEM 7) IN THIS BOOKIES'I (CONTINJE WITH E-K BEUJW) PESTICIDE
| |
| ~
| |
| E~ IF
| |
| ~
| |
| IN TABLE IIA AND IVA PAGES BE PROVIDEDI
| |
| ~
| |
| SURFACE HATER DISCHARGE APPLICANT (PRIMARY OR SECONDUIY INDUSTRY), REGARDLESS OF THE TYPE OF DISCHARGE KPJOWS CR HAS RFASOPI TO BELIEVE TIVE ANY POlLUTAMf LISTED IS DISCHARGED FRCM ANY OUTFALL'HE OUANTITATIVE DATA PKJT APPLICABLE/BELIEVED ABSENT ALL DATA OM (ITEM 7) Iti THIS RECORD FORMS PROVIDED BOOKLETS OX PRESEtif/DATA IS ATTACHED F. IF AVY SURFACE WATER DISCHARGE APPLICANT (PRIMARY OR SECONDARY INDUSTRY)g REGARDLESS OF TYPE OF DIS(595Ep KPJCWS OR HAS REASON TO BELIEVE Attf POLLUfANTS LISTED IN X NOT APPLICABLE/BELIEVED ABSENT TABLE VA PAGE + ARE DISCHARGED FRJXI ANY OUfFALL THE APPLICJPIT ~P'ESCRIBE REASONS FCR THE POLLUTANT BEING PRESENT APJD PROVIDE AMY AVAILABLECUJUJTITATIVE DATAI RECORD ALL DATA ON FORMS PROVIDED (ITEM 7) IN THIS BOOKlETo PRESEMf/DATA IS ATTACHED G AIL SURFACE WATER DISCHARGE APPLICANTS (PRIMARY AND SECCNKARY INDUSTRIES)
| |
| WHO:
| |
| X NOT APPLICABLE/BELIEVED ABSENT OR MAPJUFACTIRES Ze Iip 5 TRICPKDJPOPHBJOXY ACETIC ACID (2p 4 5 T) I
| |
| -(I,
| |
| ) JI, 5-TRIOIIORDPkteXY) PRCPAP IC ACID (SILVEX, 2, JI, 5, TP)
| |
| IrTTRICPLORCPHBKPL (TCPP J OR HEXACHLOROPHENE (HCP/J (AIL DATA FOR THE ABOVE MUST BE GENERATED USIIJG STAPJDARD APJALYTICAL CALIBRATION PROCBXPIES) OR
| |
| ~
| |
| KNXJS OR HAS REASON TO BELIEVE THAT TCDD IS OR MAY BE PRESENT IN THEIR DISCHARGEa REPORT JXIALITATIVE DATJ4 GENERATED WHICH USED A SCREENING PROCGXRE NOT CALIBRATED 'WITH ANALYTICALSTAJJDJIRDS, FOR 2. 5z / 8r - TETRACHLDRODIBENZO P DIOXIN (TCDD) ~ RECORD ALL DATA ON FCRMS PROVIDED (ITEM 3) IN THIS BOOKLETe PRESENT/DATA IS ATTACHED J ~ IF ~ QSFACE WATER DISCHARGE APPLICANT KPQIJS OR HAS REASCM TO BELIEVE THAT BIOLOGICAI TOXICITY TESTS WERE VADE IN THE LAST TIFJEE (5) YEARS ON ANY OF THE NOT APPLICABLE API'LICAMT S DISCHUJGES OR Oi A RECEIVIP6 WATER IN RELATIOPJ TO A DISCHARGE, PROVIDE TJIS ItifORMATICN AS AV AITACPPJEMT TO THIS APPLICATIOMI APPLICABLE/SEE ATTACHED K. IF A CONTRACT IABCRATORY OR CONSULTIPJG FIRM PERFORMED ANY OF THE AVLAYSES RECUIRED P JOT APPLICABLE BY THIS APPLICATION PROVIDE THE NAME AND AXRESS OF EACH LABORATCRY OR FIRM AMD THE ANIJLYSES PERFORMED AS A'I ATTACPMEMT OF THIS APPLICATIOMI X APPLICABLE/SEE ATTACHED LI DO YOU DISCHARGE ANY OTHER TOXIC OR INJURIOUS CHEMICAL SUBSTANCES PJOT LISTED IN TABLES IV PAGE II AP4) I IA TPIPJXJ% VA PN;ES ~A, lc vES, THEN IDENTlcY THE CHEMICAL SUBSTANCES AND ESTIMATE THE FINAL EFFLUENT CONCENTRATICPJS ~
| |
| X mf APPLICABLE SQUIT THIS INFCRMATION AS AN ATTACPMEMT TO THIS APPLICATIGNI APPLICABLE/SEE ATTACHED
| |
| * Pesticide data is not required; however, it is provided.
| |
| | |
| I'STRCGT!".S = R G""PEEP: /7 SEC-':I i!
| |
| e steel!>c o.-. ("Bs (~for a 'cn C1 s cut(all -ischa, "in" tc t,"e surface aters.
| |
| %Pc I c=cu!. '4~'BEp !"I nE 20K A ~ -= ..-" "F I!IS FC?'~. ! E FERSIIT GvitBER 2 g 22 =RllO CII 7+E FCOIIT PAGE OF YOCo E>oIRII4 Dc&4! 7 "f this is a new or not previous! v erh(ttec fac! I(tv, then leave b!Bnx anc a 1urber wii I be asslcned.
| |
| Bete" -"e cv-fa! I "'.macr (1 The space CV.:ec !Cr Bach "ace ot Sect)en ','. - ~ each I "dividual dlscnarce point a se"grate set IT=i! 5
| |
| *ATEt vcu hsvB ' O. mcl e SUPS'tanT la! I incent(cai Cvtfal Is, vou av rB I Bst Permission
| |
| ~
| |
| lcm vcur perm( = inC auTCCri ty TO sample a1d analvze only one cuttal) ahc submit the results c'. he anaivsis for other if your,ecuest Is granted by -1e perilttlng authority, on a separate sneet at. ached substantially identical outfalls.
| |
| to the application form identify which outfal I you did test, anc dose, ibe wnv the outfal ls wnich you d!c -ot,est are substantial lv Identical to the outfal I
| |
| <<n(Ch )Pu did TBSP CO
| |
| ..ata "FR Part I 2.2I(g)(B), Frlcav, for organic toxic pollutants anc I, !323, rcvldes 'r a imall =.siness =xemoticn 'r"-1 the repel t!rg cf -. antltatlve oxlc pollutants as recuired by "ar l22.21<g)(7)(il)(A) or I22.2((c)(7)(lii)<A).
| |
| C. these parts are self-explanatcry anc co not require furtner instructlchs. Slmolv go thrcucn each par,. and "." as indicated.
| |
| snc S=everai !nduStrlal CategorieS CC S.csateCCrleS have been BXempTBC 'r~ S "bml --I "C Cata Cr, Certain GG/VS FwaetlonS
| |
| ''0 "FR part 2 yo(. BB, llc. ".-', T"'.av, 'or!i !,;BBT, '.aTes:, ", s". 3).
| |
| ~
| |
| .Bvlew t"e fol lcwlno list to ceternlr e whether vcur facility cue!i'ies -- pe exe,ot 'rcm recon. Inc G"/"S ',Gas hrcmatocraohv/
| |
| "ass Spectroscopy) Fract(ons.
| |
| M/.'-'S Free. icn
| |
| .est(no anc Repcrtlrc Exemptions
| |
| .exti le M! I Is Industry
| |
| - Al! four X/ISS CrganiC ftaCTIO1S I" xhe Greige "illS SuCCategcry.
| |
| - Pesticide fraction In all orner su parts of this Industry.
| |
| Ore a!In!no and Oresslnc Industry
| |
| - volatile. base/neutral, and "estlc':e fractions in the Base ano preclc s petals subcategory.
| |
| - All taur GC/!4S Organ(C fraCTICnS I ail Other SuPCateccrieS Of th(S iwCuStrV.
| |
| Gum and Mood Chemicals Industry
| |
| - Pesticide fraction in the Tall Oll Rosin Subcategory and the Rosin Based Derivatives Subcategory.
| |
| - Pesticide and base/neutral fractions in all other subcatecories of this industry.
| |
| Pulp and Paper Industry Pesticide fraCtiOn in Papergrade Sulfite SubcatecoriBS (Subparts J and U).
| |
| - Base/neutral and pesticide fractions in oeink suboart Q, oissolvinc Kraft suboart F . and Paperboard from Maste Paper Subpart E.
| |
| ".olat i ice base/neutral, Castle(de r actions ln the BcT Bleacned Kraft suboart u. semI-chem(ca) suboarts 8 and c, and Nonintegrateo-Fine Papers Suboart R.
| |
| Acid, base/neutral. and pest(cide fractions in Fine Bleached Kraft Suboart i. oissolving Sulfite Pulp Subpart K, Ground-wood Fine Papers Subpart 0, I(arket Bleached Kraft Subpart 0, Tissue from 'uastepaper Suboart T, and Nonintegrated Tissue Papers Suboart S.
| |
| Steam Electric Power Plant Industry
| |
| - Base/neutral fraction In the once-Through cooling Mater, Fly Ash . and Bottom Ash Transport Mater process wastestreams.
| |
| 38
| |
| | |
| SECTION II ~ MI 0005827 NUMBER SEE INSTRUCTIONS ON REVERSE SIDE (3HFkL IU'R9 USE THIS DATA SHEET 0 RECCRD INFO'"ATION AS REQUIRED ltl: (CHECK APPI(SPRIAT BOX FQR WHICH IIIFOR"ATICN THIS DATA SHEET REP"ESSITS ~
| |
| SECTI(XI lli ITEN (I-E ~ GROItlDWATER DISCHARGE I!<FOPA ATIO!t (PAGE 55)
| |
| 'RITICAL X 'ECT IQI I le ITC~ O. PRICRITY IPOLutTA'<TS IN SIIIFACE WATER DISCH((RGE (PAGE 57)
| |
| 'lIATERIALS TOXIC D 3. 3 ~ BELQH: cRIilcAL NATERIALs (TABLE Iv) Itl sURFAcE wATst DlscHARGE (PAGE 8)
| |
| OLLUTANTS
| |
| ~ IZARDOUS USSTANCES 3~ LIST A'Y CRITICA'"ATERIAL (TABLE IV Pt<'AE 6) teOT ADDRESSED Itl SECTIQI II ITEYI R KIQRITY NOT APPLICABLE A~X UTA'ITS WHICH YOU ICIQ(t OR HAVE REASQI To BELIEVE TO BE PRESBIT IN THE DISCHARGE ~ SFE IN REVERSE SIDE OF THIS PAGE FCR FUI(ETHER DIRECTIQ5 e DISCHARGE X APPLICABLE (SEE BELOw)
| |
| Ae I!A<<E QF CRITICAL PATER IAL OR PRICRITY POLUJTANT
| |
| * Hydrazine 00 3 0 2 012
| |
| !PI IT CODE GM'PLE TYPE i7 OF AIAIYSFS (1( e Be AVERAGE CQICENTRATIONI SA<<ZLE TYPE; tT OF e(VIALYSES
| |
| .<<AXE CQJCSiiRATION Ale WIT CODE IPNT CODE Ce PASS A. 'A"E CF CRITIC'L <<ATERIAL OR PRIORITY PO(J.VTATIT K WIT CCQE ~G TYPE OF ANALYSES
| |
| ((J Ce( B. AVERAGE CQKEIITRATIQI; SA"PLE (YPEP i( OF A!IALYSES LJ C. FAX Itltt CQXBT((ATIQl A'D t"ASS WIT CODE WIT COBE
| |
| ~~
| |
| NITS CODE A,;N; E OF CRITICAL t(ATERIAL CR PRICRITY POL((~ TAt<T Mg/I UIIT CODE SA<<PLE TYPE F OF At!ALYSES Ug< I
| |
| '9. AVERAGE CQCENIRATIOtV SA".PLE TYPES'" CF AtIALYEES LJ
| |
| /DAY I'AXItlttCOtlCEtm!ATICtt A'(D i<<ASS Wli CODE WIT CODE DAY Cp LJ LJ
| |
| ~~
| |
| A.;u(<<Z OF CRITICAL PATERIAL CR PRIORITY POLLIITAtIT WIT CCDE VVPLE TYPE tt QF AtIALYSES
| |
| : 3. AVERAGE CveiCE,ITPATIQN Se<<"PLE TYPEI (/OF /L,'IALYS S Utlli CODE WIT CCCE
| |
| <<AXItlPI CQJCBA'RAT IQI A'4)
| |
| C. PASS LJ ~ LJ A(P(E TYPE 'IA E CF CRITICAL uATERI>> CR -"RIOR ITY PCLLVTAlii GRAB WIT CODE SA<<<PLE TYPE =. OF A!IALYSES 24 HR.COMR 3. AVERAGE CQICSITRATIQI; BAFLE ( <PE; "OF A'NLYSES C. <<AXI~PI CQICE.'iTPATICtt "D PASS et<IT CODE WIT CODE A. IIA<<E OF CRITICAL NATERIAL CR PGIICRIIY PCILVTA!Ii QIIT CODE S'PLE IYPE v'F ANALYSES 3~ AVERAGE CQICSITPAT ION! SA<<PLE TYPE; ii C(: A'IALYSES C. <<AXIS'ltt'CQICEIITPATIQIAND i<<ASS QIIT CODE WIT COCE LJ le ~ '!APE CF CRITICAL <<ATERIAL CR P>IQRITY PQLLVTAtIT J;IT CCQE SA(PLE i<PE <<QF At<ALYSES e AVF4GE CQltCEtt((ATIQlt S'<<PLE TYPE: e: CF A'IALYSES LJ WIT CODE Wli CODE C, <<AXItltt CCICEINPAT IQI AD <<ASS
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| ~ ~~
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| A:IA<<E QF CRITICAL l<<ATERIAL CR ""RIORITY POLL(JTP(tti WIT CODE SA<<PLE TYPE RT OF A'IALYSES Be AVEPACm COAICDANRATION; SA<<EGLE (YPE; tI OF AtlALYSES QNT CODE WIT CCOE C~ <<AXIS'It< CUE'Pi&TIQI AY<<) X(ASS LJ ' ~
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| LJ ~ Ll ADDITIONAL PAGES CF THIS Ii I 7 ARE ATTACHED FOR T(( ReST CF THE CRITICAL 6 YES
| |
| <<ATERIALS At<D/OR PRICRITY KAL(JTA%'S REQUIRED TO BE REPORTED( EI a
| |
| * Hydrazine is expected to be present in discharge but small quantities may be found in the steam generators but would not be expected to found in the actual discharge flow to Outfalls 001 or 002.
| |
| | |
| 'ENERAL CHEIVIISTRY RESULTS Client Sample ID: OUTFALL OOS-U/2 Date Collected: 01-31-94 Matrix: water SLOWDOWN LAL Batch ID(s): 126 im, 128 im. 201 im Date Received: 02-01-94 PO¹69095-040-3N
| |
| '.,;,"Rep'ortlng;:,. ' Data- 'Date- LAL Constltuent -'ethod- 'esult'- '
| |
| Detection Umit Qualifier(s) Anal zed Sam le ID Fluoride, inm IL 340.2 <0.15 0.15 03-02-94 L1175-1 Bromide. in m IL 300.0 <0.050 0.050 02-17-94 L1175-4 Nitrite-Nitrate-Nitrogen, 353.2 <0.050 0.050 02-11-94 L1175-5 inm IL Sulfate in m IL 300.0 0.12 0.059 03-05-94 L11 75-4 Total C snide, in m IL 335.2 <0.020 0.020 02-07-94 L1175-6 Color 110.3 <5.0 5.0 02-01-94 L1 175-1
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| \
| |
| Total Phenolics. in m IL 420.1 <0.15 0.15 02-08-94 L1 175-7 Sulfide in m IL 376.1 < 1.0 1.0 02-03-94 L1175-1 Sulfite, inm IL 377.1 1.2 1.0 02-01-94 L11 75-2 Comments:
| |
| | |
| IVIETALS RESULTS Client Sample ID: OUTFALL OOB-U/2 Date Collected: 01-31-94 Matrix: water BLOWDOWN LAL Batch ID(s): 126 im Date Received: 02-01-94 PO469096-040-3N Reporting Concentration Detection Limit Data ~
| |
| Date'nal LAL Constltuenta Method lm IL) Im IL) Qualifier(a) @ed Sam Ie ID Aluminum 6010 <0.20 0.20 02-22-94 L1 175-17 Antimon 6010 <0.060 0.060 02-22-94 L11 75-17 Arsenic 7060 <0.010 0.010 02-20-94 L1175-17 Barium 6010 <0.20 0.20 02-22-94 L1 175-17 Ber ilium 6010 <0.005 0.005 02-22-94 L1175-17 Boron 6010 <0.20 0.20 02-22-94 L1175.17 Cadmium 6010 <0.005 0.005 02-22-94 L1 175-17 Chromium 6010 < 0.010 0.010 02-22-94 L1 175-17 Cobalt 6010 <0.050 0.050 02-22-94 L1175-17 Co er 6010 <0.025 0.025 02-22-94 L1175-17 Iron 6010 0.15 0.10 02-22-94 L1 175-17 Lead 7421 <0.003 0.003 02-23-94 L1 175-17 Ma nesium 6010 <5.0 5.0 02-22-94 L1175-17 Man anese 6010 <0.015 0.015 02-22-94 L1 1 75.1 7 Mercur 7470 <0.0002 0.0002 02-09-94 L1 1 75-17 Mol bdenum 6010 <0.067 0.067 02-22-94 L1 175-17 Nickel 6010 <0.040 0.040 02-22-94 L1 175-17 Phos horus 6010 <0.050 0.050 02-22-94 L1175-17 Selenium 7740 <0.005 0.005 02-25-94 L1 175-17 Silver 6010 <0.010 0.010 02-22-94 L1 175-17 Strontium
| |
| '010
| |
| <0.10 0.10 02-22-94 L1 175-17 Thallium 7841 <0.010 0.010 02-28-94 L1175-17 Tin 6010 <0.20 0.20 02-22-94 L1 175-17 Titanium 6010 <0.10 0.10 02-22-94 L1175-17 Uranium 6020 < 0.001 0.001 03-07-94 L1175-17 Vanadium 6010 <0.050 0.050 02-22-94 L11 75-17 Zinc 6010 <0.020 0.020 02-22-94 L1175-17 Comments:
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| | |
| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 1 of 2 lien m I ID: TFALL B- BL WD WN LAL m I ID: 117 -2 Date Collected: 31-JAN-94 Date Received: 01-FEB-94 Matrix: WATER Date Anal zed: 04-FEB-94 Ani i IB h¹: 244-2 - 1 Dil inF r: 1 QC Batch ID: 020494-8260-C1 SURROGATE RECOVERY QC Limits 1 2-Di r h - 4 1 4 7 -114 Tl n-4-Bromofluorobenzene 106 86-115 Reporting Concentration Detection Limit Constituent IL IL Data Qualifier s Chloromethane <5 Vin I hl ri Brmm hn Chloroethane <5 Trichlorofluoro meth ane A e n 11-Di hl r h Carbon Disulfide <5 Meth lene Chloride <5 rn-12-Dihlr hn Vin I A 1 1-Dichloroethane <5 2-Butanone <10 10 i -1 2-Di hl r h n hlrfrm 1 1 1-Trichloroethane <5 Carbon Tetrachloride <5 12-Dihl r h B nz n Trichloroethene TCE <5 1 2-Dichioro ro an <5 Brm ihlrm hn 2- hl r h I Vin I E h r <2 4-Meth l entanone <10 10 cis-1 3-Dichloro ro ene <5 T I n rn-1 -Dihl r r n 2-Hexanone <10 10 1 1 2-Trichloroethane <5 Tetrachloroethene PCE LOCKHEED AiVALYTICALSERVICES
| |
| | |
| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 2 of 2 Client Sam Ie ID: OUTFALL OOB-U/2 BLOWDOWN LAL Sam fe ID: L1175-20 Reporting Concentration Detection Limit n I n L IL D alifi r s Dirm hlrm hn Chlorobenzene <5 Eth Ibenzene <5 m -Xln
| |
| -X I n St rene <5 Bromoform <5 1122-T r hl r h n 1 -Dihlr zn 1 4-Dichlorobenzene <5 1 2-Dichlorobenzene <5 LOCKHEED AIVALYTICALSERVICES
| |
| | |
| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 TENTATIVELYIDENTIFIED COMPOUNDS Client Sample ID: OUTFALL OOB-U/2 BLOWDOWN LAL Sample ID: L1175-20 Date Collected: 314AN-94 Date Analyzed: 04-FEB-94 Date Received: 01-FEB-94 Dilution Factor: 1 Matrix: WATER Sample Weight: N/A Analytical Batch: 020494-8260-C1 No. of TICs: 0 QC Batch ID: 020494-8260-C1 Estimated Retention Concentration Time Data Tentatively Identified Compound (yg/L) (minutes) Qualifier(s)
| |
| LOCKHEED ANALYTICALSERVICES
| |
| | |
| SEIVIIVOLATILEORGANIC ANALYSIS RESULTS FOR GC/IVIS ANALYSES USING METHOD 8270 Pa el of2 D
| |
| li n Matrix: WATER II: m I ID: TFALL 1- AN- 4.
| |
| 8-U 2 BL WD WN LAL D R m I iv:
| |
| ID:
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| Dilution Factor: 1 L117-1-FEB- 4 Anal tical Batch ¹: 021094-8270-A Date Extracted: 03-FEB-94 QC Batch ID: 8270-SVOA-4903 Date Anal zed: 10-FEB-94 SURROGATE RECOVERY o 0 Limi 2-Fl oro h n I 21-1 Phenol*de 22 10-94 Nitrobenzene-d, 70 35-114 2-Fluorobi hen I 67 43-116 2 4 6-Tribromo henol 60 1 0-1 23 p-Terphenyl-d,i 41 33-141 Reporting Concentration Detection Limit Con L L D Phn I bis 2-Chloroeth I ether <10 10 2-Chloro henol <10 10 1 -Dihl r n n 14Di I r n n Benz I alcohol <10 10 1 2-Dichlorobenzene <10 10 2-M hlhnl i 2-hlri r I hr 4-Meth I henol <10 10 N-Nitroso-Di-n- ro lamine <10 10 H hlr h Nir n n Iso horone <10 10 2-Nitro henol'-Dim
| |
| <10 10 h I h Bnzi i bis 2-Chloroetho me hane <10 10 2 4-Dichloro henol <10 10 1 4-Trihl r n n N hhl 4-Chloroaniline <10 10 Hexachlorobutadiene <10 10 4- hlr--m hlhnl
| |
| -M h In hh I n Hexachloroc clo entadiene <10 10 LOCKHEED ANALYTICALSERVICES
| |
| | |
| SEMIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 P 2of2 Client Sam le)D: OUTFALL OOB-U/2 BLOWDOWN LAL Sam le ID: L1 1 75-9 Reporting Concentration Detection Limit Constituent ( /L) ( /L) Data Qualifier(s) 4 -Trihl r h n I 2 4 5-Tri hl ro henol <10 2-Chlorona hthalene <10 10 2-Nitroaniline <25 25 Dim h I hh I A n hhln 2 6-Dinitrotoluene <10 10 3-Nitroaniline <25 25 A n hhn 4-Dini r h n I 4-Nitro henol <25 25 Dibenzofuran <10 10 4-Dini r I Di h I hh I 4-Chloro hen I- hen Ie her <10 10 Fluo rene <10 10 4-Ni r nilin 4 -Dinir - -m h I h n I N-Nitrosodi hen lamine <10 10 4-Bromo hen I- hen le her <10 10 Hx hlr nzn Pn hir hnl Phenanthrene <10 10 Anthracene <10 10 Di-n- I hh I Fluoran hene <10 10 P rene <10 10 B I z I h I
| |
| '-Di hl Benzo a anthracene <10 10 Chr sene <10 10 i 2-Eh Ih Di-n- I h Benzo b fluoranthene <10 10 Benzo k flu ranthene <10 10 B n r In n 2 r n Dibenz a h anthracene <10 10 Benzo h i er lane <10 10 LOCKHEED ANALYTICALSERVICES
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| | |
| SEMI-VOLATILE ORGANIC ANALYSIS RESULTS C ~
| |
| FOR ANALYSES USING IVIETHOD 8270 TENTATIVELYIDENTIFIED COIVIPOUNDS Client Sample ID: OUTFALL 00B-U/2 BLOWDOWN LAL Sample ID: L1175-9 Date Received: 01-FEB-94 Date Analyzed: 10-FEB-94 Matrix: WATER Dilution Factor: 1 Analytical Batch: 021094-8270-A QC Batch ID: 8270-SVOAP903 Estimated Retention Concentration Time Data Tentatively Identified Compound Iyg/L) (minutes) Qualifier{a)
| |
| Substituted Hexanedoic Acid 270 30.3 LOCKHEED ANALYTICALSERVICES
| |
| | |
| OIL AND GREASE EXTRACTABLES ANALYSIS RESULTS BY FT/IR USING METHOD 413.2 Client Sam le ID: OUTFALL OOB-U 2 BLOWDOWN LAL Sam le ID: L1175-13 r:
| |
| Date Collected: 31-JAN-94 Date Anal zed: 09-FEB-94 D R iv: 1-F B-4 Dil inF r 1 M rix: WATER D Ex -FEB- 4 Anal tical Batch ¹: 020994-413.2 QC Batch ID: 020894-413.2 Reporting Constituent Concentration Detection Limit Data Qualifier(s) m L m L Oil and Grease LOCKHEED AItIALYTICALSERVICES
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| | |
| PESTICIDE .ANALYSES RESULTS BY GC/ECD USING METHOD 8080 Clien Sam le ID: UTFALL 0 B-U 2 BLOWDOWN LAL S m I ID: L117 -11 Da C Ile ed: 31-JAN-94 D R eiv: 1-FEB 94 Date Extracted: 07-JAN-94 Date Anal zed: 14-FEB-94 Matrix: WATER Dilution Factor: 1 Analytical Batch ¹: 021294-8080-E-3 QC Group ID: 8080 PEST/PCB 5054 SURROGATE RE OVERY 00 QC Limits TCIVIX 64 60-150 DCB 86 60-150 Reporting Constituent Concentration Detection Limit Data Qualifierls)
| |
| L L A-BH B-BHC <0.05 0.05 G-BHC <0.05 0.05 D-BHC HEPTA HL R ALDRIN <0.05 0.05 HEPTACHLOR EPOXIDE <0.05 0.05 HL R DANE END LFAN I .05 A-CHLORDANE <0.05 0.05 4 4'-DDE <0.1 0.1 4 4'-DDT DIELDRIN ENDRIN <0.1 0.1 ENDOSULFAN II <0.1 0.1 4 4'-DDD ENDRIN ALDEHYDE ENDOSULFAN < 0.1 0.1
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| < 0.5 0.5 SULFATE'ETHOXYCHLOR T XAPHEN PCB-1016 PCB-1221 <2 PCB-1232 P B-124 P B-124 PCB-1254 PCB-1260 TECHNICAL CHLORDANE TCMX - tetra-chloro-meta-xylene DCB - Deca-chloro-biphenyl LOCKHEED ANALYTICALSERVICES
| |
| | |
| RAD DATA REPORT (ra01) indiana Michigan Powr Co. ~ Bridgman,HI Organic and inorganic Contaninants (Project COOK.JEMl)
| |
| Client Sample iO: OUTFALL OOB-U/2 BLOSSOM LAL Senile 10: L1175-15 Date Collected: 31- JAM-94 Date Received: 01-FEB-94 Katrixt Mater Log in Mwhert L1175 Gross Alpha 23-FEB-94 GR ALP/BETA LAL-0060 4756 -0.08 0.3B 0.92 pCi/L Gross Beta 23.FEB-94 GR ALP/BETA LAL.0060 4756 0.4 1.2 2.1 pCi/L Page 2
| |
| | |
| RAD DATA REPORT (ra01)
| |
| Indiana Hichigan Power Co.
| |
| * Bridgman,HI Organic and Inorganic Contamlnants (Project COOK-JENI)
| |
| Client Sample ID: OUTFALL DDB-U/2 BLOW LAL Sea@le ID: L1175-16 Date Collected: 31- JAN-94 Date Received: 01-FEB-94 Hatrix: Water Log in Number: L1175
| |
| ~~%'i:";":'(Cari s tg't'tigj't:i.".':::::W"':N:::::.'':AWII5ity'iel:;'Igitgb;::::::::."'~
| |
| Ra-226 10.HAR-94 RA-226 LAL-0073 5201 0.62 0.28 0.31 pC i/L Ra-228 25-FEB-94 RA-228 LAL-0074 5199 0.03 0.37 0.65 pCi/L Page 3
| |
| | |
| PH Analysis (LAB.079)
| |
| PH Meter CPC y- lO~ Outfall OOB Cal date due Sample Sample Time g I C, 0
| |
| J4 o o Sample /j Sample Date CDM Entered by
| |
| : 6) Sample C/ph (prior to 7 7P correction) 5.3.5 7) NH3 pH correction 5.3.6 8) )ample results C/pH (after t.7g NH 3
| |
| Correction)
| |
| Sample Sample Time Sample g Sample Date CDM Entered by
| |
| : 6) Sample C/ph (prior to correction) 5.3.5 7) NH3 pH correction 5.3.6 8) Sample results
| |
| 'C/pH (after
| |
| ~
| |
| Correction)
| |
| : 9) LAB.041 Specs Verified by: A(/8 Rupewvieoz Review/Date W+IW Form prepared by/Date Form approved by/Date 12 THP LAB.041.25s Revision 1
| |
| | |
| Determination of Total Chlorine instrument CPC/j Outfall OOB (Lab 170) h
| |
| ~
| |
| Technician Sample/Standard I Sg Sample jj Date -7 Time ~~/q /
| |
| CDM Entered by l) Absorbance 6.11 2) Results, ppm C. ~
| |
| : 3) Dilutions made C2M CZ M
| |
| : 4) Results, ppm C
| |
| (/I2
| |
| * 0 3) 51 1AB.Ddl Specs Verified by:~N R Supervisor Review/Date~~9I ~ Form prepared by/Date /~f' Form approved by/Date 12 THP LAB.041-25)l Revision 0
| |
| | |
| SEE INSTRUCTIONS ON REVERSE SIDE SECTION II PERMIT NUMBER ~ i4I 0005827 (UIFkL rkPKR ~00 0
| |
| .M Ae ~
| |
| QCAT ION OF DISCHARGE
| |
| ~6 e, ~NW e, ~e-DII0I I~06, -0)l L006I e)IDE ~19 )I B~ MME cF REcEIYIttG HATER '{IEs GRQ{ttDHATER 0R NA'K 0F sutFAcE
| |
| <<A MECH)IG AN Ce DO YCU DISCHARGE SEASQliALLY:
| |
| {IF NO) CQVTltAIE TO E) YES ta DISCHARGE LOCATION D, IF YES) LIST DISCHARGE PERIODS NA MOe / DAY ./ DAY SCHEDULE FLOW
| |
| ~w RATE WASTEWATER Es LAtrD APPLI CAT ION RATE Irt./HR.
| |
| ELJ HRe/DAY
| |
| ~ H IN,/WK,
| |
| ~ KI IIA CONTACT COOLING
| |
| : NONCONTACT COOLING PROCESS Fe G~
| |
| He DISCHARGE 0 ISCM6RGE
| |
| ~
| |
| TYPE QF WASTEWATER DISCHARGE FLOW RATE (YEARLY AVERAGE)
| |
| HQ{Frs/DAY TOTAL YEARLY *
| |
| ~24 wASTEIIATER TYPE COCE Dsv/Tees
| |
| : 5. 11
| |
| .LJ L5365 I UNIT L4 CODE SANITARY STORMWATER
| |
| *Based on all-time daily maximum times DAILYMIttIPut ) 0 ~2 U~NIT 0 D 365 DAILY t'AXltttt 0 . 014 ~2 I MGY Ie IHE t)AXIts{M DISCHARGE flOW RATE TO BE AUIHQR IZED Itt PERIITT p p 4 3 UN I TRODE 2 MGD 3 GPD Js MAXIISH DESIGV DISCHARGE FLOW RATE, DES IG'I 0. 043 ~P As CO YOU USE WATER TREATMENT (IF tro cQNTItt{E To ITEM 3)
| |
| ADDITIVES TO TREAT YQ{R DISCHARGE?
| |
| 0 YES ITEM Be NAME FgtCTIQrte AND CHEMICAL OF TIIESE ACOITlVEST
| |
| ~S IT ION WATER TREATMENT NA ADDITIVES Ce NA% ArtD ADDRESS OF MAIAFACTLT)ERS QF lHESE ADDITIVES ~
| |
| UNITS CODE 1 Mg/I 2 Ugzl NA MI NIM{f1 UNI TS AVERAGE ut ITS MAXIt%tt UNITS De XPECTED DISCHARGE CCttCENIRATIQrt OF AITIITIVESs NA CODE CODE CODE ADDITIVE NAME ACDITIVE tQ%
| |
| ADDITIVE t5%
| |
| E, DO Yet TREAT THE DISCHARGE )s REMOVE ADDITIVES? NA LJ:~ LJ:~YES LJ LJ F. WHA'T IS THE RP9OVAL EFFICIENCY AVD DISCHARGE FREQUENCY? NA
| |
| ~ REPCVAL MRS e /DAY DAYS/WK~
| |
| ADDITIVE tA% LJ ADDITIVE NAME ADDITIVE N6ME G, AS Art ATTACHTENT TO THIS APPLICATIQtt PROVIDE SPECIFIC ."Ast)ALIAS CR AQUATIC TOXICOLOGICAL DATA CR REFERBICE WMICH ARE AVAILABLEAND INFORMATICN CN THE RATE OF DEGRADATION OF THE PRODUCTS FCR EACH All!TIVE NA
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| 'I AI ent !'titS. }Isa, *1en -ne 'Cntf IV Ceretlca }5 CrtS }re reuieweC =; ramollanae Staff lt will "eia Tr~ -0 Cetermine
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| )$ 1 1T - }el !0 }V Asu, % .I}CI I 0 I 0 rh r>>e ne hs
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| } <<l hnt Jtf rec 'eSTea l I " 5 grl .
| |
| ~ )2
| |
| | |
| SEE INSTRUCTIONS ON REVERSE SIDE SECTION I I PERMIT NUMBER ~ MT. 0005827
| |
| [IJII'M. IlfBEI(
| |
| 40~0> 0 OF PDOCESS OC)ITRIBUTI[JG TQ THE DISCHARGE rROU% TYIIS QUTFAU- ~'D SIC CCCE DAN N ~4i9 I I B =ROCESS SA -ED[LE (YEARLY AYRE)
| |
| IOUS/DAY ~24 I "Avs/v e PROCESS VI V9 Or C~ =ROCESS WASTEYIATER FLOW RATE TOTAL YEARLY 0 .003 ~*
| |
| STREAMS 0 Basis: 1993 actual data submitted ONTRIBUTING 0 on DMRs DAlLY M IN INN I I 0, ~6
| |
| 'O DAILY e<<AXINTI 0. 002 ~6*
| |
| OUTFALL DISCHARGE De PROCESS F0')CT ION RATE I I I I ut ITS / I T IME I
| |
| VI VI A.
| |
| B.
| |
| Ce iVVZ OF PROCESS ~
| |
| PDQCESS CONTRIBUTING TO THE DISCHARGE DSQUGH Tri[S OUTFALL ~YT) SIC C <<E (YEARLY AVERAGE)
| |
| PROCESS >IASTEWATER FLOW RATE IYADS/IDY TOTAI. YEARLY
| |
| ~ DAYS/YSAII 001 0
| |
| DAILY Mttl[NH I POUNDS DAILY NAXINN 2 GALLONS D PROCESS FPODUCTIOtt RATE 3 CUBIC
| |
| ~
| |
| A.:VINE OF PRXESS COtt[RIBUT[t)G TO THE DISCHARGE YARDS TH[OUGH THIS OUTFALL A'ID SIC CCCE 4 TONS Be PROCESS SO 'X)LE (YEARLY AVERAGE) 5 MGY HADS/DAY DAYS/VSAA 6 MGO VI C. PROCESS lQSTEYIATER FU)W RATE 7 GPD TOTAL YEARLY CC 4L DAILY MININH DAILY PAXINTI De PROCESS PPODUCTIOtt RATE UN[ TS /TIME
| |
| ~
| |
| I HOUR Ae NAWIE OF PROCESS COIITRIBUT[tlG TO THE DISCHARGE TH At& SIC COPE 2 OAY 3 WEEK B PROCESS SC~DE (YEARLY AVERAGE)
| |
| ~'DAV DAVS/VSAA MONTH Vl Lt[IT CODE VI Ce PROCESS WASTEWATER FLOW RATE 5 YEAR TOTAL YEARLY Lt~
| |
| Q Q. DAILY MININTI DAILY 4'AX[t~
| |
| D. PROCESS PDQCUCTIQII RATE UtttTS /TIPE I I I Ae IW% OF PPQCESS CQt[IRIBUT[NG TO THE DISCHARGE IlFAOUGH THIS OUTFALL AlID SIC CQCE Ng B. PROCESS SOIEDRE (YEARLY AVGAS/iE)
| |
| IIQURS/DAY DAIS/YDYI C. PROCESS WASTEIIATER FLOW RATE UNIT wX TOTAL YEARLY DA t LY;I [NINA ~
| |
| I I DAILY WXINM De PROCESS PRODUCT IOtt RATE UNITS / TIPE
| |
| * Heating boiler was out of service for maintenance during most of 1993.
| |
| 33
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| | |
| / a
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| <<<<Re 'a lar 9 9 " SSS I > 5 *n!C" r 8 'I
| |
| -,.= gy .-. - - ~ = "= =i"-. =:=.. == n=.-.!It ', .c-"= -.-'l =c = tI.';0:;I vCN C>PI!III'G
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| '"Is '! . -Rw cr ot - ov
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| =
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| .st. 3 rnl--~c 'scil tv, -Rn 'eave Isn~ a c a nu>><<ce HE F;"CRIT
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| assianec.
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| cl ace, vlcec 9 ot Pc tcl oa t I ual c 3. ce c ln 5o elate sor
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| '--5 -e 5- Rs
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| ~
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| 5 5 I
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| -O ':IieC>>u-Ir 5 5
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| ~ ~ ~ << ~ " p Y(>>
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| - -9 - e process <<n'C. Cc--"'c.-es " -i!s:Iscrs-co.units -': -rcvl:e -9 c-."Rr -.'. ccce
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| -clca-0 "9 F45. I. Cyersce crace!3 ic-45<<io '- -ours cor csv R<<c ccvs-:er-voa" aroviae t"e process <<aste~ater f!ou rate Infornation as recuesteo baseo on your last 12 ..ontns of operations. Refer to nit COae oiven in tee loft naroin for tne acprOoriate flow .
| |
| = ocess proauctlor. Rate - certain cer"i; ti>>ltations nav ce casea cn crccuctlcn rates. "9 crcauctlcn ra~Os usea o C'eveal ll 39;Or Ir+ CO>>>>',- '>ICS 5nai I
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| '"n - " "-
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| ~- ->> "-"- --9 -'-"os- -'"~ --etic"s "
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| C"CauCC'C<< Cf IOCi V. 5'Cn CS 9
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| "e "ears cr
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| :--Rr -Rsscnac.o -9)sure 9>>
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| "4<<S 'r<<RS "r <<4>>
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| 5
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| 95
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| ri 3$ !95 h ] 9 1,)3 i>>f 5 f
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| | |
| SECTION II PERMIT NUMBER MZ 0005827 SEE INSTRUCTIONS ON REVERSE SIDE QJIFAU. NKR ~00 C BENI Ae IS IHE DISCHARG(
| |
| GRoutGWATERS7 FROM THIS CUTFALL 3$ REC1ED TO THe GRONO OR 4IF t>>O<< Ca>>TIMUE To IT&>> u) YES 4 B. WAS A HYDRQGEOLQGICAL STUDY OR ITS EQUIVALB>>T BEEN PERFORMED OR IS IHERE SIFFICIEMT CURRENT HYDROGEOLOGICAL It<<FOIT>>ATIa>> AVAIIJ<<BLE AS REQUIRED BY ~ WATER RESOURCES CI ':<<$ 'le cat>>tssla>> PART 22 GR>>xl>>owATER RULES cF AUGUsT lt>>e 1%0 R ~ 525 2D)7 (PAGE Q) F0R GROUNDWATER IHIS EXISTlt>>S OR PROPOSED DISCHARGE! IF YES ATTACH A COPY CF IHE REPORT.
| |
| ,DISCHARGE C ARE YQU REQUESTIttl Att EXP'PTICN FRCM SUBMITTIt>>G A HYDROGEOLOGICAL REPORT ut>>QER INFORMATION R>>AE R.323<<22(I7 CiDER RULE RR ~ 23e DQC>>l>>ENTS M)
| |
| Q (PAGE $A) OR FRCM GR>>Xl>>DWATER MONIICRIt>>G I)EQU1REMB>>TS (5) (PAGE Lg) OF THE PART 22 R>>LESe IF 'ES EXPIANATla>> To DB)ot>>STRAIE THAT YOUR DISCHARGE Wa)LD QUALIFY FOR ATTACH t>>O EXBP lONe De ARE You REQUEsTIt6 4 vARtAt>>cE FRcM RULE 323.2$ )05 (PAGE 5) (NQNDEGRADATIQN) QF $ >>e<<
| |
| IHE wATER REsouRcEs cotHIsslcN PART 22 GRout>>DHAIER RuLEs! IF YEs, ATTAcH sucH DOC>>1'Et>>TS AS NECESSARY TO DEM(INSTRAIE THE NEED FOR A VARIAI>>CE IN TEFMS OF Tte CRITERIA SPECIFIED IN RIAL 525 Z10 (PAGE >>I>>t) CF THE PART Zd RULEse NA Ee I,IST AI,L CHEMICAL SLBSTANCES WHICH ARE IN MICHIGAN'S CRITICAL <<MATERIALS REGISTER TABLE IV
| |
| '>>PAGE D) At>>D/cR U.s. EPA s PRI0RITY PQU.UTANT Llsf TABLE v (PAGE 1) 0R ANY 0THER SUBSTANcES NOT APPLICABLE/BELIEVED ABSB>>T WHICH ARE OR MAY BECCt% IIL>>URIa)s TO THE DESIGNTED USES OF THE GSXl>>DIETER OR TO THE PUBLIC H~TH THAT ARE DISCHARGED OR EXPECTED TO BE DISCHARGED To THE GRCu>>DWATER>Y IHIS FACILITY. ESTIMATE IHE F ttujL EFFWEMT CONCB>>IRATION At>>D RECORD ALL DATA IN tTEM OF SECTION it IN THIS BOO)LET ~
| |
| / NA THE APPLIGWT MAY BE REQUIRED TO DO ADDITICt>>AL WASTE ANALYSES. PRESENT<< DATA PROVIDED IN ITEM 7 Ae DISCHARGE CHARACTERISTICS Cot>>CEMIRAT I a>> ll>>ITS CODE $$>> At>>ALYSES ~LE TYPE CODE ITEM (FtVE 5 BOD5 COD DAY BIOCHEHICAL OXYGEtt DP'At>>D)
| |
| (CHEMICAL OXYGB>> DEMAt>>D)
| |
| EXPECTED TOC (TOTAL ORGA<<M IC CARBa>>)
| |
| WASTEWATER CHARAC- AftSMIA NIIROGEM (AS N)
| |
| TERISTICS TOTAL SUSPENDED SOLIDS CODE ToTAL ptcspHQRus (As p) 1 Mg/I 2 Ug/I TOTAL RESIDUAL CH.CRINE 3 COUNTS/
| |
| 100 mt DISSOLVED OXYGEN Mlt>>
| |
| 4 S.U. PH 5 F 6 LBS/DAY FECAL COLIFORM RACTERtA IEMPERAIURE (S>>ll4ER)
| |
| TEMPERATURE (WINIER)
| |
| ~
| |
| ~ ~
| |
| ~
| |
| LJ
| |
| ~ ~
| |
| LJ LJ
| |
| ~3
| |
| ~5
| |
| ~5 B. OIHER WASTEWATER Ct>>ARACIER 1ST ICS SAMPLE ZXBF 1 GRAB 0 I L )t, G R E A S E LJ LJ ~
| |
| I LJ LJ LJ 2 24 HOUR COMPOSITE LJ SEE ATTACHED SHEETS FOR ANALYSIS D TA LJ ~ LJ e
| |
| <<>>ECUIRED ItSORMATIa>> FOR SURFACE WATER DISCHARGESe
| |
| * Basis: 1993 actual data submitted on DMRS
| |
| | |
| t
| |
| ~
| |
| 5 .,v ~ 4 S g <<>>P Pi Ii( 4 lh}i rt=(S 3 ",n g is C o)vires '" o. ! ~ c<< .". '! 3)ac'( - cu (4'I 'cbarci c " at ther' prof.nc}(ate, 5 cr s r')ce <<arers.
| |
| =E<<izI7 '.""BEC Ih THE BOX AT I'o } EP CF T}}IS r CR!I. >E PE&IT '."J'ABER "A}l BE, DUI(0 O'I THE F-Ct(T PAGE CF v00R ExoIRii<<4
| |
| '".is cer,It!ed '<<oil}tv, !he<< leave CI)nk <<il(
| |
| a - 4 5() I
| |
| 'crrs
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| ~ S ) -e<<)
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| .<<)or
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| 'I e .s
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| '4 -
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| hot b-OVicuslv
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| )r c 3))CO Zr)v: C<<C (C<<e)c<<!)ce 'eo:,on }I =c<<>>cn st ce .I I! Iec cut.
| |
| ano a rr."<<ber I "dividual be ass tered.
| |
| !Isc )rco octn. a !eon} nto 5(}-
| |
| I'o
| |
| ~ i ~ gi \~ i i i~ <<g 7 ii 'I ~ i ~ ~ I chf ~ ~ 'i IC } i ) i' "e )ool:cant shall !Cdross o)c''"ese carts I'e ctscharce !A; -"Is out'nrl '5 -= tbe:-curcwator.
| |
| Evi 5 I". ( c- EVPEcTED;FcP 'E(r IscHARBF) a)STE'r}ATEP cuARAcTEc'sT)cs 0 "0'.0'4'ATEo cP 40RFAcc '((ATEC Btsci ARriE (0 i0T It) I.UDE sion'5 A. The aoolicant shall re)ort avnllab(e discharge cata (real cata for existinc discharge or exoected data for a brooosec discharge)
| |
| !cr r}e barn.eters as 1}sted. ihese onraceters shat I be ccresseo for either a surface water discr.arne or as nooroor late rcr !
| |
| -,rcurchater C'sonar "e, -cr aSSIstnnco '" cater(,lnirc aoorcoriate ara"e-arS a crourC}rater CISCnarce abblicnnt .av contact -"e
| |
| ' c<<ater Cunt I, v '., 3 ten, oe<<Its Secticn or tne a)ore)r:ate:rcu<<exeter .unl " ', (I 1 Ci 5, rlct o. f .'co i I
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| f'I iC)rl ~ 5 !I t 1 1'e 5) ala '("e C O Ost asCr') inr( q)c<<<<OOCr e OCO Cntn, Sae i, (I Crr t e tert af'CI<<
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| rl r";! )Ct'nl } }5 ! I.rface <<ato":i!eh)rte. "-e !"<<}Ic)"-:5-rhc r ". anr'-)tl.e Sa.a fcr encn ))rareter iden!If ted bv a<<
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| )s<<er !w. ",e )oo} 5)" .av ..*over, nc os; -"nt -"e .o- r->>, - c)t<<)r'e cr cre o, nese recu}r'Oc oarvetors oe
| |
| <<a}vec..uc;, e).ost -;st be 3~boor-ec b( )cecunte )t'5"aie. !Re S.c ) rocuest )<<!7 achrhont -". this )Col icntlcn.
| |
| ~
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| ~
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| ))-a: s )(n'}acre ' >>t"er c)r~~to<<5 -Ot 1'5-OC )oo.e '- A. Z 5<<.er )), -5 )'"'S )coilcatlcn -"e aoolicant 5<<auld re cr that zat) In tre <<iinn<<scaCeS Orcviced:<<rniS Cart.
| |
| 'TES, ;"I- codes ' oars.oters reocr tac ln oor ts A )rd B can bo for.rc cn the ie't nano sice cf tais fcf<<h
| |
| '4 )}
| |
| sn O}a (once 4B)
| |
| << ', $ >)I I "e used -". )CalVZO 'Cr O" te4)era-urn, tc-)I t "e"Cr 5 I ) 4 r )Ze <<ate, . is )r Ce
| |
| 'c eel ir I-ion of,rao san)le.
| |
| ~
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| ess t" Or ("4 werc. 5). '4.
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| ~ ~ es lcual C",.IC~ine, Oi I )nd 1:reaae Voe )noiVSOS a, e avni I ale ~ See
| |
| ~ and
| |
| " Ssaf V
| |
| : 3. Ez-hou, c" ooslte sar}ales snail be used to ann}vze fcr T>tat 9&4, 000 .cc,,~onia '.Itrogon, nnd Total susoenced~
| |
| Solids Ir Surface <<ater Clscnbrro unless other;recueoCV-Sn ole tvpe analvses are avnllable. See Glossary
| |
| ()ace 48) '"r Ce!Initicr. Cf Ct"OOStte Sn-.ble.
| |
| A<<C l i }Pa <<ce grra i) r 4 5 <<*t,q<<r lriPons 5 O ra 4 y) r 4I lil'iv tati rcr'."
| |
| qf ( i 4<< ', ' I )fr mre Cci ar;ts ~ <<n <<4, a ar ( n a" i'ustOC OV Suatf'OCtlro . e averace le(e} c.'be boll.(tant(s) orosont vour Intnxo>>nter. '.CQES eculaticns Olfe}( net ltrhttaticns cnlv in
| |
| :er-)<<! -t:.Stances.: ca~nst,).4 vourIne ')Ib,:'l-v, e)cr- -ne!Veraco cf tr'e rasut 5 of )halvses on your 4 ( <<nt i<< ~
| |
| 4)vhd 4 4 34 45 '} 4 4+ )'I 4 is an<<ac ), ) <<C ) 54 af ate
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| $4 h I hai 5 4 h<<en<<<<h 1 <<LO *era<<5 i
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| 'i*
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| i 4 '( <<i}ra<<*i}C e 5 Lat e t ! 4 4 <<3$ ~ 4 1
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| '\
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| ,4
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| '<<<<I - <<)- }4
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| <<~, O
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| <<I V<<t) 5 h ~ . 4 4 I l<<<<)r 4+ ai}
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| 4 34 4 ) a 5 ee nr <<C ai, , 4 4 r *r% }$ 4" "C est
| |
| | |
| SEE INSTRUCTIONS ON REVERSE SIDE SECTlON lI PERMIT NUMBER ~ MI 0005827 OlTF/ILL NEFB ~00 C TEM THE FQUMAIMG REQUESTED ItÃGIL4ATIGtl BZEI;eDJ VSE DISCHARGERS c~ ~4'c A"DRESSED ~<v '' SIRFACE '<<ATER DISCHARGERS.
| |
| PROVIDE BIPECTED VALVES FOR THE QUANTITATIVE AIJD 6 QUALITATIVE ItiFOJLeAT IGtt REQUESTED BELQWe A. IS TnIS FACILITY A PR!ueARY I'etXJSTRY? (REFER TO TABLE IA PAPE 4+1 (IF lf), GO TO E) (tF YES, GO TG B) QX YES PRIORITY POLLUTANTS B I:iDICATE TYPE QF PRIMARY CG;titty)E WITH C. )
| |
| IIISTRY AS LISTED IM TABLE IA PJJiE Qe STM ELJECJ )PWR AND Ce 0 ES THIS OUTFALL DISCHARGE CGtffAie4 J4IY PROCESS WASTEWATER?
| |
| flF tJGe GG TO E) (IF YES. GO TO 0) X YES ta ADDITIONAL INFORMATION D INDICATE HHICH GC/PS FRACTIONS FJJST BE TESTED FOR ~
| |
| <REFER TO TABLE IA P4iE 4~1 VOLATILE FOR SURFACE WATER IJQIE) cQR EACH EACH FRACTIGtt ~ GC/f'8 FRACTION CHECKEDe EACH SPECIFIC ORGANIC TOXIC POLLUTANT WITHltt BE AJJALYZED FOR (SEE TAB c I IA PAGE I QJSTRY APPLICAtftS WITH A PROCESS WASTEWATER DISCHARGE ltl 42, e~
| |
| IN ADDITIOtte ALL PRIMARY PROVIDE QUAJJTITATIVE BASE/I'e'FUTRAL DISCHARGE DATA FCR EACH TOXIC POLLUTANT TABLE 111A PAI< 99 ~
| |
| X ACID ONLY RECORD ALL DATA et FORMS PROVIDED (ITG4 7) Ilt THIS BQQKLETe (CONTINJE WITH E-K BELOW) PESTICIDE E
| |
| ~IN TABLE I IA AND IVA PAGES BE PRGVIDEDe
| |
| ~
| |
| IF JJtt)'. SURFACE WATER DISCHARGE APPLICA'ft (PRIHARY OR SECCtiDARY IJIDVSTRY)e REGARDLESS GF THE TYPE OF DISCHARGE KJK)WS GR HAS REASIXI TO BELIEVE THAT AJIY PIXLUTA'ft LISTED IS DISCHVIGED FRCH AtJY IXJIFALlgTHE QUANTITATIVE DATA ttQT APPLICABLE/BELIEVED ABSENT RECORD ~ DATA ON FCRMS PROVIDED (ITEM 7) trt THIS BOOKLET.
| |
| PRESBIT/DATA IS ATTACHED c, IF A4Y SIJIFACE OF TYPE TABLE VA PAGE ~
| |
| WATER DISCHARGE APPLICAtfi (PRIMARY GR SECGtJDARY ItCUSTRY), REGARDLESS OF'ISCMIGEe KVJOWS OR HAS REASCtt TO BELIEVE AIJY POLLUTÃffS uSTED IN ARE DISOIARFED FRÃ ANY OVTCALL THE APPLICANT y~
| |
| REASQtiS FCR THE POILVTAtfi BEING PRESENT AND PROVIDE ANY AVAILABLEQUANTITATIVE CATAe DESCRIBE g, NGT APPLICABLE/BELIEVED ABSENT ALL DATA QN FORMS PROVIDB) (ITE)t 7) IN THIS BGOKLETe REGQRD D PRESENT/DATA tS ATTA(BED G. ALL SIJIFACE WATER DISCHARGE APPLIC4JTS (PRIHARY AtfD SECCtGNRY INDUSTRIES)
| |
| W)e: e j
| |
| l, GR JANUFACTVRES 4,
| |
| 2, 4, 5 TRICHJ)RGPHBK)XY ACETIC ACtD (2, 5-TRICHLGRQPHBK)XY) PRGPANOIC ACID (SILVEX, 1, 4 5 TP)'')
| |
| 4, 5-t): D X tK)T JV'PLICABLE/BELIEVED ABSENT DIJE)jf/L U-l2e 4e 5-TRICHLORGPHBWL) PHQSPteROTHIOATE (ROtfJEL)J
| |
| > TRIOLHCPJEJIL (TCPJ I OR HEXACHJ)ROPHEteE (HCP)J (Au. DATA FOR THE Pl)ST BE GBiBQTED VSItIG STAG)ARD AttALYTICALCAJ.IBRATIOJ PROCE"IRES) QR
| |
| ~
| |
| KJJQWS GR HAS REASON TO BELIEVE lHAT TCDD IS OR HAY BE PRESENT Itt THEIR DISCHARGEe REPORT JXJALITATIVE DATAe GENERATED WHICH'SED A SCREENItJG PROCBXRE MOT
| |
| ~<IBRATED WITH A4ALYTIG'4. STA'OARDSe FGR 2. >e /L Se - TETRA:HLORQDIBEJJEO-P-DIOXItt (TCDDJ ~ RECGRD ALL DATA Ott FORD PROVIDED (ITFJI /) Itt THIS BOQKLETe PRESENT/DATA IS ATTACHED
| |
| :F icE SVRFACE wATER DISOIARGE APPLICAtfi gfXJS CR )AS REASON TO BELIEVE ieAT APP'CABLE BIQLCGI+ TOXICllY e-STS '<<ERE JeADE Itf IHE LAST THREE (5) YEARS gt A'h'F Mi MOT APPLICA'll S DISCHARGES GR ON A RECEIVIMG WATER IN RELAYICe4 TO A DISCHARGEi PROVIDE ietIS IteFGCATICM AS A4 ATTAOf)Bft TO 1HIS APPLIC)TIGMe APPLICABLE/SEE ATTAOFJ)
| |
| K.:F A Ct)4TRACT LABORATORY OR CONSVLTltJG FIRM PERFORMED Ath'F TJE AteLAYSES REQUIRED tJQT APPLIABLE BY THiS WFLICATICNe PROVIDE THE NAe% AND ADDRESS OF EAOI uBORATGRY OR FIRM AND te,E ANALYSES PERFQRJ'ED AS AN ATTACWEtft GF THIS *PPLICATIQMe Ath'THER tOXIC QR IttJURIGVS CHEHICAL SVBSTA4CES t)QT ':)TED ltt g APPL ImLciSEE ATTAOIED DQ YQU DISCHARGE S IV PAGeE II AJ4) IIA leà VA PA'ES Jf/+Qe lc "ESe THEN ICBftl v eeE "EHICA. c4!BSTANCES A'eD ESTIMATE eHE F I JF4. EFFUJEJJT CCJJCEMTRATIGJJS. SVB4IT THIS X ~ JOT APPL'CABLE FGRI'IATIeAJ AS A.'I ATTAINT TG THIS APPLICettlGM APPeLICABLciSEE ATTACHED
| |
| * Pesticide data is not required; however, it is provided.
| |
| | |
| "'lS "".CTICKS CR C.ttolETI",V: SECTICII i I ITEW 6 vis 'ci, -ec ires )-'c~at'cn cn a spec('Ic cut(all ciscnar-ino to the s'r'ace ~aters.
| |
| Eht = -"- =ER'IIT '.".::"-"= IN THE "
| |
| - "=,
| |
| BOX A THE THIS ECRU. THE PE?MIT,':V'ABER CA)I BE FrnNO CII THE =p"."IT pAGE CF YCUo
| |
| '! t" ls Ts a "ev cr not previousiv Ce~lttec foci lltv, then leave blank end a nu Per <<Il ( be ass(oned.
| |
| Ro(RING En,e -e cu-fal I '. er ln he space crcr'cec ',cr seen page of Secticn I(. =or eacn 'lvicua( clscnarce point separate tf iec-'cn i''.,-e" cr. s must =e fV l~c s.-.
| |
| s se ITEvi 6 ycu >ave -~o or more substantially .ncent(cai outfalls, vou mav reouest pormlsslcn from vout'ermlttinc but"crlty to
| |
| )a"O~e Snc ana)VZe Only One Out(ail ."" Supm(t the reeultS Of the anaiVSiS fOr other SubStant(ai(V (Centi"a(
| |
| vcur ecuest is cranted by tne pem(ttlno authorltv, cn a separate sneet attecnoc tc -"e acpllca-lcn foin Outfal(S. ide. rifv
| |
| <nicn out, a(I ,cu c(c test, anc caser ce wnv the utfal ls ~nlch you <<Id not test are suostantia: Iv ident( al to -ne outfal I xnlcn you cic test.
| |
| cO CFR part "."I<c)(8), Fridav, -'"-I" I tg83, provides ',cr a Small Business Exeipricn xicm tne repcrt(ng of " antitat(ve
| |
| ~
| |
| cata for organic toxic po(lutants anc toxic pollutants as redo(red by part 122.2((q)(7)(il)(A) or l22 'l(o)(7)<i(I)(A). ~
| |
| : 4. These parts are self-explanatory ano co not reouire further lnstructicns. Slnolv go .Iicucn each cart c" anC snc as Indicated.
| |
| Several incus- lai categories a,.c s.:csteccr(es nave been exemptec ioi: submittln" cata cr car-slo TC/US "iactlcns Oar- '
| |
| '0:=R ~ VO(.,a8, lip. ".-', C-'CSV, april I, )g83, 'OteS I, 2 ~ and 3).
| |
| "eviex the foiicxlno list to cete<tt(re xnetrer vour (ac(((tv dual(! Ies to be exe.ct 'rom report:nc SC/"S lgas Chroatoorapnv/
| |
| uass Specticscc=y) .Broctions.
| |
| SC/I',S traction Testing and Reporting Exemptions ext I I e:a II Is Incustrv
| |
| - All 'our GC/vS organic fractions ir -xe Greloe tsi I Is Subcategorv.
| |
| - Pesticlae fraction In all otner S.ppartS Of this Incustrv.
| |
| Ore )1(nlno anc Cress(no Industr
| |
| - volatile. base/neutral, and pestlcice fractions In the Base and precious uetals subcateoory.
| |
| - A(I four cc/vs organic fractions in all other subcategor les of this incustrv.
| |
| Gum and Wood Chemicals Industry
| |
| - Pesticide fraction in the Tall OII Rosin Subcategory and the Rosin Based Derivatives Subcateoory.
| |
| - Pesticide and base/neutral fractions In all other subcateuorles of this Industry.
| |
| oulo and Paper InduStrv
| |
| - Pest(clde fraction In Papergrade Sulfite subcatecories <subparts J and U).
| |
| Base/neutral and pesticide fractions in Oeink Subpart Q, Disso(vino Kraft Subpart F, and Paperboard from Waste Paper Subpart E.
| |
| - volatile, base/neutral, pesticide fractions In the BGT Bleacned Kraft Subpart H. Sem(-chemical Suboarts B and C. and Nonintegrateo-Fine Papers Subpart R.
| |
| - Acid. base/neutral. and pesticide fractions in Fine Bleached Kraft Suboart I, olssolvlng Sulfite Pulo Suboart K. Ground-xood Fine papers Subpart 0 . xarket Bleached Kraft subpart G, Tissue from wastepaper suboart T. and Nonlnteerated Tissue Papert Subpart S.
| |
| Steam Electric Power Plant Industry
| |
| - Base/neutral fraction in thc Once. Through Cooling Water, Fly Ash. and Bottom Ash Transport Water process wastestreams.
| |
| 38
| |
| | |
| SEE INSTRUCTIONS SECTION II PERMIT
| |
| ~ gZ 0005827 ON REVERSE SIDE
| |
| ~00 <0 Ae USE THIS DATA SHEET TO RECORD I"FORMATION AS REQUIRED Itt'CHECX APPROPRIATE BOX FOR YHICH INFQRHATIQI THIS DATA SHEEf REPRESBITSs) 1 SECTIIXI II, ITEN 4-E. GRIXttDWATER DISCHARGE IttFQRYATIQtt (PAGE 55)
| |
| CRITICAL X 2. sEcTIQI II ITBI 6. PRI0RITY PQLUITAMfs IN sIRFAQE HATER DlscHARGE (PAGE 37)
| |
| MATERIALS TOXIC POLLUTANTS HAZARDOUS SUBSTANCES LIST AIIY CRITICAL tATERIAL (TABLE IV PAGE 6) tNT ADDRESSED IN SECTIQI II ITBI 6 PRIORITY NOT APPLICABLE PIXLUTAMTS hHICH YOU XttQW OR HAVE REASON TO BELIEVE TO EE PRESENT It> THE DISCHARGE. SEE IN REVERSE SIDE OF THIS PAGE FQR clPvHPR DIRECTIQIS ~
| |
| DISCHARGE X APPLICABIE (SEE BELCH)
| |
| A. NA<<E OF CRITICAL I'ATERIAL OR PRIORITY POLLUTANT
| |
| * H draz e 00 3 0 20 12 WIT CODE Sts"RE TYPE OF AttAIYSES LU e I
| |
| B.
| |
| C.
| |
| AVERAGE CQICENIRATION; SA"PLE TYPEI vAXItXN CQMCBIIRATI Qt Ata vASS (I OF ANALYSES WIT CODE'IITLJ COCE Ae IIAtlE OF CRITICAL <<ATERIAL CR PRIORITY PQLLUfAttf UNIT CODE W "lPLE TYPE OF AttALYSES B. AVERAGE CCNCENTRATIONI SNePLE TYPE; 4 OF ANALYSES UNIT lttlT CODE C. YAXINN CQICEMTRATION AttD . ASS CODE LJ UNITS CODE As NAt'k OF CRITICAL YATERIAL OR PRIORITY RXLIMANf 1 Mg/I WIT CODE SAevPLE TYPE P OF ANALYSES 2 Ug/I Bs AVERAGE CQICENIRATIONI SA"PLE TYPEI ft OF A%LLYSES LJ Qtll'ODE WIT CQDE LBS/DAY KG/DAY Ce PlAX INN COtCENIRAT ION AtID I'ASS LJ Ae NtYE OF CRITICAL MATERIAL QR PRIORITY PQLUffANT QIIT CCDE SA'PLE TYPE OF ANALYSES B. AVERAGE CQNCBITRATIQII SA<<PsLE TYPEe 1f OF AttALYSES LJ WIT CODE WIT CODE C. MAXI'OttCEMIRATIQIAtsD I'ASS LJ SAMPLE TYPE Ae IIAHE QF CRITICAL e lATERIAL QR PRIORllY PQLLUfAttf 1 GRAB WIT CODE SA"PLE TYPE ff OF AttALYSES B. AVERAGE CQtCENTRATIOMl ~~<<PLE TYPE; > OF AltALYSES 2 24 HR.COMP.
| |
| WIT CODE WIT CODE Ce YAX IYIf4 CQtCEMIRATIQI Ato YASS LJ As IIA'1E CF CRITICAL YATERIAL OR PRIORllY POLLUTANT su(o B. AVERAGE CQICEIITRATIQNl SAMPLE TYPE;
| |
| " OF A IALYSES Ut IT CODE SA'tPLE TYPE r'r OF ANALYSES UltIT CODE WIT CCDE C~ <<AXItlN'CQICBITRATIQIAtD YASS 4~ tUetlE OF CRITICAL vATER IAL CR PRIORITY POLLUTANT
| |
| ~
| |
| UstlT CODE SA'IPLE TYPE ff OF ANALYSES m~W B, AVERAGE CQICBITPAT IOMI SA<<PLE TYPE I QF ANALYSES WIT CODE WIT CQQE Ce e"AXIS CQLEIIIRATIQIAlB MASS As i%YE OF CRITICAL YATERIAL QR PRIORITY POLUJTAttf WIT CODE SA'lPLE TYPE ff OF ANALYSES B, AVEPAGE COsCEMIRATION; SA<<PLE TYPE; fff OF ANALYSES LJ lftlT CODE QIIT CODE C.,<<AX IHW CONCENTRATION AttD "ASS ADDITIONAL PAGES OF THIS ITEM 7 ARE ATTACHED FCR TK REST OF THE CRITICAL 0 YES MATERIALS Atilt/CR PRICRITY POLLUTANTS REQUIRED TO BE REPORTED ~ 2 MO
| |
| * Hydrazine is not expected to be present in discharge but small quantities may be found in the steam generators but would not be expected to be found in the actual discharge flow to Outfalls 001 or 002.
| |
| | |
| '""STPS I '.- -"
| |
| R CC/LP< ET!)IS SECTIC)i I I "ls 'cr>> fs To be used bv both sur' o. anc crouncwater <<:pl!cant T" record Irfornatlon on anv uichlcan critical material, E.p.A.
| |
| r -y cc>l.tan. cr>>a:arpcus <<:s->>rce ln <<nicn r's scollcatlcn -'e recuires Cata To oe crcvlcec. This <<ovid include anv chemical I.b cence '"w -"e "ic>>igan Cr!Tic "sterlais ~egister>>ble I'/).
| |
| ~ E.P.A. P"lorl<<y pollute>>T 'stlno !Table V). Cr Tables
| |
| <<>>lcr ''sTS Crganic Toxic col lutants. '.her Toxic -ellut nTS "-nvenTlonal and Nonconventional "cllutants and hazardous
| |
| ~
| |
| .,Cs a>>ces ~
| |
| !TE's 7 n!QQITV cCL< 'VTS, A'IQ/Cn HAZARDS JSSTA. CES material I. E. 3... 8
| |
| 'st Tre name of The cremical s essence !critical material, prior lty'ollutant or hazardous substance) from Tables Iv, v
| |
| ~
| |
| l'A-/A as reculrec in the bcx <<nlc1 you checked ", A. I-3. above. E1ter each chemical substance's parameter number as 1c I
| |
| ! Istec In Tables Iv, v and I IA<<// if provided.
| |
| S. Provide T>>e average concentratlcn cf Tne chemical sucstance ne.ed In A. Indicate Tne sample type used and The number of analyses race To prcvlde the concentration cata for -"e c>>emlcal substance nenad ln A.
| |
| Provide the maxlrtum concentratlc1 and cetermlne the ress loadlno o! the cnemlcal substance named in A.
| |
| ')8TES: I. If cnly one a>>alysls '<<as >>ace !Cr a chemical s;bstance then record that data as a maxlmun value. If more than one analysis nas been made !or a chemical substance Then orovide an averace value of those analyses and the maximum value.
| |
| : 2. >>Is Section If, lte. 7, sta Sheet oroviCes space fcr "eccrdlng cata !or 8 chemical substances !Materials).
| |
| -'dditlcnal space for "sccrcing of data !Cr ~ore Tran 8 "aterlals can be mace by mak!ng copies cf this Iten 7 Data Sheet as ~ceded. it Is also I, porta>>T To use separate set of Oata Sheets for each applicable reporting reculrement as I ls ed In A I 3. and or each out.al I
| |
| : 3. defer To The left naroin for The code number <<eoresentlng the sample type used and the appropriate unit codes.
| |
| 40
| |
| | |
| llGV Bngineeiiag & Science I Sununit Cuwpanp A X .K I, Y 'I' (l .k I,'> ll R K I (l I','>
| |
| ANALYTICAL REPORT Cook Nuclear Submittal Number: 29609- 7 Proj: Waste Water Analysis Location:
| |
| | |
| ==Contact:==
| |
| Ray V. Buhl Subm: Feb 21 Samples Phone: (616) 942-9600 Outfall Detection Units OOC Htng Limit Boiler WWES Sample No: 79691 Surfactants, MBAS (0.025 0.025 mg/l Coliform,'ecal (1 1 cl/100ml BOD, (5-Day) (31 1.0 mg/l Sampled by:
| |
| Date Sampled: 02/21/94 Time Sampled: 00:00 Date Received: 02/22/94 Time Received: 09:00 e 1 - End of Analytical Report
| |
| *BOD sample is being reanalyzed and will be submitted after the results are received.
| |
| 55:>>; Gloniroo(l Illllo I'nrkwnp'I,". I'0 Box 87 I. (Iron(l Rnl>lds, XII I9588-087 I, 616/942-9600 I'nx 9 I2-6 I9l
| |
| | |
| ll'1VLagiBeeiiii & SCienCe I!Amunil (~imp:vu ~ %Y;KI,)"'I'l(l Xli NI(V,K It;I',s STATEMENT OF DATA QUALIFICATIONS CLIENT: Cook Nuclear SUBMITTAL'9609-7 All analyses have been validated and comply with our Quality Control Program. No qualifications required.
| |
| The following analyses have been qualified for the reasons cited.
| |
| Sample No.(s): Parameter: Reason:~
| |
| Explanation:
| |
| KEY
| |
| : 1. Sample integrity suspect upon receipt (explain).
| |
| : 2. Analysis performed beyond EPA established maximum allowable holding time.
| |
| : 3. Detection limitelevated due to matrix interferences.
| |
| : 4. Laboratory control sample value outside established acceptable limits.
| |
| : 5. Matrix spike sample value outside established acceptable limits.
| |
| : 6. Duplicate analysis value outside established acceptable limits.
| |
| : 7. Surrogate/internal standard recoveries outside established acceptable limits.
| |
| : 8. Data point suspect due to potential laboratory contamination (explain).
| |
| : 9. Coelutes with the compound cited. Result may represent a combination of both compounds.
| |
| : 10. Other (explain).
| |
| Note: This document is included as part of the Analytical Report for the above referenced and should be retained as a permanent record thereof.
| |
| :>5:>5 0!enw<>nit ttltts t nrkwny St;. t <> tt<>x n7.t. t;rnnu Rnt>ilats..ill lo;>88-087 l. 6 t6/O t >->>t>OO I:nx O-t >-O>.Bin
| |
| | |
| GENERAL CHEMfSTRY RESULTS "Client Sa'mple'D: OUTFAL'L"',OOC-'' Date'Colic'cte'di '02-21''-94!:: "Matrix;, 'vol'ater:
| |
| HEATlNG. BOILER:l'..,'.''.'AL Batch ID(s): 222 im Date Received: 02-22-94 P0469095-040-3N h<-
| |
| '.,..;-,Datii';,,';,;.:,:,::: ".,; 'ed'-''7;,'LAL''Sam s'.,':.'::.::i".':::'.".Constituent::: ".':::::.':.":: Meth'od':> ': . <:,Res'uft';";:!:.':" "".".'Detection Umlt"-" """Anal Date,,"....'Quallfierts)"
| |
| le" ID" Fluoride inm IL 340.2 <0.15 0.15 03-08-94 L1 304-22 Bromide, inm IL 300.0 <0.050 0.050 03-14-94 L1 304-22 Nitrate-Nitro en inm IL 300.0 <0.017 0.017 03-11-94 L1304-17 Sulfate, inm IL 300.0 <0.059 0.059 03-10-94 L1 304-22 Total Phosphorus, 365.2 0.049 0.030 02-24-94 L1304-16 inm IL Total Kjeldahl Nitrogen, 351.2 8.0 0.10 03-17-94 L1304-16 inm IL Total C anide in m IL 335.2 <0.020 0.020 03-01-94 L1 304-13 Total Suspended Solids, 160.3 12 12 02-28-94 L1 304-21 inm IL Chemical Oxygen 410.2 23 18 02-26-94 L1 304-23 Demand inm IL Total Organic Carbon, in 415.2 9.5 1.0 03-10-94 L1 304-23 m IL Ammonia-Nitrogen, in 350.1 3.7 0.050 03-21-94 L1 304-16 m /L Color 110.3 <5.0 5.0 02-24-94 L1304-18 Total Phenolics in m IL 420.1 <0.15 0.15 03-08-94 L1 304-14 Sulfide, inm /L 376.1 <1.0 1.0 02-25-94 L1304-19 Sulfite, in mg/L 377.1 1.6 1.0 02-23-94 L1 304-20 Comments: Nitrite4lltrogen ls not present in preserved samples.
| |
| LOCKHEED ANALYTICALSERVICES
| |
| | |
| METALS RESULTS
| |
| ', Client" Simple'D."OUTFALL"OOC-':;:;.,':, .;.'':, 'Date 'Collecte'd '02-'21-94'.: :, Matrix: w'ater.
| |
| 'EATING BOILER".'' .".:: ":"-"-'.
| |
| LAL Batch IDls): 222 im Date Received: 02-22-94 PO¹69095-040-3N
| |
| ;- Re'po'rtlnIj,;...
| |
| ":"'De't'e: "::'-
| |
| Con'ceiitratlo'n . 'Detection'mit .
| |
| '-. A'nal Conitltuentii:- @Method ., -:-.Iin IL) ..:-. .....,::.(m IL):,. .'"'Date".'.'Quallflerls) ed Sam le ID Aluminum 6010 <0.20 0.20 03-12-94 L1 304-12 Antimon 6010 <0.060 0.060 03-12-94 L1304-12 Arsenic 7060 < 0.010 0.010 03-14-94 L1304-12 Barium 6010 <0.20 0.20 03-12-94 L1 304-12 Be Ilium 6010 <0.005 0.005 03-12-94 L1 304-12 Boron 6010 <0.20 0.20 03-12-94 L1 304-12 Cadmium 6010 <0.005 0.005 03-12-94 L1 304-12 Chromium 6010 <0.010 0.010 03-12-94 L1 304-12 Cobalt 6010 <0.050 0.050 03-12-94 L1304-12 Co er 6010 0.026 0.025 03-12-94 L1304-12 Iron 6010 3.6 0.10 03-12-94 L1304-12 Lead 7421 <0.003 0.003 03-22-94 L1304-12 Ma nesium 6010 <5.0 5.0 03-12-94 L1304-12 Man anese 6010 0.017 0.01 5 03-1 2-'94 L1304-12 Mercu 7470 <0.0002 0.0002 03-04-94 L1304-12 Mol bdenum 6010 <0.067 0.067 03-12-94 L1 304-12 Nickel 6010 <o.oao o.oao 03-12-94 L1 304-12 Phos horus 6010 <0.050 0.050 03-12-94 L1 304-12 Selenium 7740 <0.005 0.005 03-22-94 L1 304-12 Silver 6010 <0.010 0.010 03-12-94 L1304-12 Strontium 6010 <0.10 0.10 03-12-94 L1304-12 Thallium 7841 <0.010 0.010 03-22-94 L1 304-12 Tin 6010 <0.20 0.20 03-12-94 L1 304-12 Titanium 6010 <0.10 0.10 03-12-94 L1 304-12 Uranium 6020 <0.001 0.001 03-1 1-94 L1304-12 Vanadium 6010 <0.050 0.050 03-12-94 L1304-12 Zinc 6010 <0.020 0.020 03-12-94 L1304-12 Comments:
| |
| LOCKHEED ANALYTICALSERVICES
| |
| | |
| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 1 of 2 Clien S m le ID: 0 TFALL OC-HEATING BOILER LAL m I ID: L13 4-1 Date Collected: 21-FEB-94 Date Received: 22-FEB-94 Matrix: WATER Date Anal zed: 25-FEB-94 Anal ical Ba ch ¹: 022594-8260F1 Dilu ion Fac or: 1 QC Batch ID: 022594-8260F1 SURROGATE RECOVERY QC Limits 1 2-Dichloroethane-d4 103 76-114 Toluene-d8 105 88-1 10 4-Bromofluorobenzene 109 86-115 Reporting Concentration Detection Limit Constituent /L /L Data Qualifier s Chloromethane <5 Vin I Chl ride Bromome h n <5 Chloroethane <5 Trichlorofluoromethane <5 A n <10 11-Dihl r hn Carbon Disulfide <5 Meth lene Chloride <5 r ns-1 2-Dichloroe hene Vin IA ea <10 1 1-Dichloroethane <5 2-Butanone <10 10 is-1 2-Dichloroe hene <5 Chlrfrm 1 1 1-Trichloroethane <5 Carbon Tetrachloride <5 1 2-Dichl ro h n B nzene Trichloroethene TCE <5 1 2-Dichloro ro ane <5 Brm ihlrmehn 2-Chlor h I Vin I E h r <2 4-Meth I entanone <10 10 cis-1 3-Dichloro ro ene <5 T I ene <5 r ns-1 -Dichloro r en 2-Hexa none <10 10 1 1 2-Trichloroethane <5 Tetrachloroethene PCE <5 LOCKHEED AIVALYTICAL SERVICES
| |
| | |
| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING IVIETHOD 8260 Page 2 of 2 Client Sam le ID: OUTFALL OOC-HEATING BOILER LAL Sam le ID: L1304-1 Reporting Concentration Detection Limit Constituent /L IL Data Qualifier s Dibromochloromethane <5 Chl rob nzen E h Ibenzene m -X lene <5 o-X Iene <5 S me Bromoform 1 1 2 2-Tetrachloroethane <5 1 3-Dichlorobenzene <5 1 4-Dichlor enzene 1 2-Dichlorobenzene <5 LOCKHEED ANALYTICALSERVICES
| |
| | |
| SEIVllVOLATILEORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 1 f2 D II:
| |
| M rix: WATER 21-FEB- 4 D Dil R
| |
| inF iv: 22-FEB-r: 1 4
| |
| QC Batch ID: 8270-SEMIVOLATILES-5616 Date Anal zed: 04-MAR-94 R ATE RE VER 2-Ff r h n I 24 21-1 Pheno!4, 21 10-94 Nitrobenzene-d, 67 35-114 2-Fl r bi hen I 43-11 p-Terphenyld 21 33-141 Reporting Concentration Detection Limit Ph n i -hlr h r 1 4-Di hl r nz n Bnzl I h i 2- Iri r I hr 4M h I h n I ir nzn I hrn 10 Bnzi i i 2-hlr h m hn N hhin 4- hl r nilin 2M h ln hh I n Hexachloroc clo entadiene <10 10 LOCKHEED ANALYTICALSERVICES
| |
| | |
| SEMIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Pa e 2 of 2 Client Sam le ID: OUTFALL OOC-HEATING BOILER LAL Sam le ID: L1304-4 Reporting Concentration Detection Limit Constituent ( IL) ( IL Data Qualifier(s) 2 4 6-Tri hl ro henol <10 10 2 4 5-Trichloro henol <10 10 2-Chlorona hthalene <10 10 2-Nitroaniline <25 25 Dime h I h h la e 10 Acena hth lene <10 10 2 6-Dinitrotoluene <10 10 3-Ni r nilin <2 25 Ac na h hene 10 2 4-Dinitro henol <25 25 4-Nitro henol <25 25 Dibenzof r n <10 10 2 4-Dini r oluene <10 10 Dieth I hthalate <10 10 4-Chloro hen I- hen lether <10 10 Fl rene <10 10 4-Ni r aniline <2 4 6-Dinitro-2-meth I henol <25 N-Nitrosodi hen lamine <10 10 4-Brom hen I- hen le her Hex hl r nz ne <10 10 Pentachloro henol <25 25 Phenanthrene <10 10 An hr ene 10 r zle 10 Di-n-but I hthalate <10 10 Fluoranthene <10 10 Prn <10 B Ib nz I hhai 3 3'-Dichlorobenzidine <20 20 Benzo a anthracene <10 10 Chr sane <10 10 is 2-E h Ihex I h h I 10 Di-n-oct I hthalate <10 10 Benzo b fluoranthene <10 10 B nz kfl ranh ne <10 10 Benzo ren 10 Indeno 1 2 3-cd rene <10 10 Dibenz a h anthracene <10 10 Benzo h i er lene <10 ~ 10 LOCKHEED ANALYTICALSERVICES
| |
| | |
| SEMIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 P 1 D
| |
| M rix: WATER II: 1-FE - 4 I R D
| |
| Dil R
| |
| inF m I iv: 22-FEB-r: 1 4
| |
| QC Batch ID: 8270-SEMIVOLATILES-5616 Date Anal zed: 06-MAR-94 2-Fl r h n I 21 21-1 Phenol', 19 10-94 NltrobenzeneM, 61 35-114 2-FI r ihnl 4 -11 p-Terphenyl-d 21 33-141 Reporting Concentration Detection Limit hn i - I I h r 4-Di hi r nz n Bnzl I hl i -h ri r I hr 4M h I h n I Ni r nz I r n Bnzi i i - r h hn N hhln I r nili 2M h In hh I n <10 Hexachloroc clo entadiene <10 10 LOCKHEED ANALYTICALSERVICES
| |
| | |
| SEMIVOLATILE ORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 Pa e2of2 Client Sam le ID: OUTFALL OOC-HEATING BOILER LAL Sam le ID: L1304-4RE Reporting Concentration Detection Limit Constituent I /L) I /L) Data Qualifierls) 2 4 6-Trichloro henol <10 10 2 4 5-Trichlor hen I <10 10 2-Chlorona hthalene <10 10 2-Nitroaniline <25 25 Dime h I h hal e <10 10 Acena hh len <10 10 2 6-Dinitrotoluene <10 10 3-Nitroaniline <25 25 Acen h hene <10 10 2 4-Dini r hen I <2 25 4-Nitro henol <25 25 Dibenzofuran <10 10 2 4-Dini r luene <10 10 Di h I hh I <10 4-Chloro hen I- hen lether <10 10 Fluorene <10 10 4-Ni ro niline <25 4 6-Dini ro-2-me h I hen I <2 N-Nitrosodi hen lamine <10 10 4-Bromo hen I- hen lether <10 10 H x hl r enzen <10 10 Pen chloro henol <25 25 Phenanthrene <10 10 Anthra cene <10 10 r zole <10 Di-n- u I h hal e 10 Fluoranthene <10 10 P rene <10 10 Bu I enz I h h la 10 3 3'-Dichlorobenzidine <2 Benzo a anthracene <10 10 Chr sene <10 10 bis 2-E h Ihex I h hal e 10 Di n- c I h h I e <10 Benzo b fluoranthene <10 10 Benzo k fluoranthene <10 10 Benzo r ne Inden 1 2 -cd rene <10 10 Dibenz a h anthracene <10 10
| |
| <10 10 LOCKHEED ANALYTICALSERVICES
| |
| | |
| LOCKHEED ANALYTICAL SERVICES L AND GREASE BY FTIR L3.2 OIL AND GREASE Indiana Michigan Power Co. " Bridgman,MZ Attn:
| |
| Client
| |
| | |
| ==Reference:==
| |
| (Project COOK-JENZ)
| |
| Client Sample ID: OUTFALL OOC-HEATING BOILER LAL Sample ID: L1304-8 Date Collected! 21-FEB-94 Date Analyzed: 08-MAR-94 Date Received: 22-FEB-94 Date Extracted: 02-MAR-94' Matrix: Water Dilution Factor:
| |
| Analytical Batch f: 030894-418.1 QC Batch ID< 413.2 OIL AND 1 Total Oil and Grease 1.0
| |
| | |
| r PESTICIDE ANALYSES RESULTS BY GC/ECD USING METHOD 8080 4-r:
| |
| m I 1 D E -FEB- 4 D An I z -MAR- 4 M ri: WATR Dii inF r: 1 Anal ical Batch ¹: 030390-8080-E-1 QC Grou ID: 8080 PEST/PCB 5666 RR A E RE VERY QC Limits T MX DCB 97 60-150 Reporting Constituent Concentration Detection Limit Data Qualifier(sl L L
| |
| - H
| |
| - H HEPTA H R P XIDE HL R DANE 4 4'-DDE 4 '-DDT END LFAN II 4I METH XY H R XAPHEN P B-12 2 P B- 4 TECHNICAL CHLORDANE TCMX - tetra-chloro-meta-xylene DCB - Deca-chloro-biphenyl LOCKHEED ANALYTICALSERVICES
| |
| | |
| RAD DATA REPORT (ra01)
| |
| Indiana Hichigan Power Co.
| |
| * Bridgman,HI Organic and Inorganic Contaminants (Project COOK-JEHI)
| |
| Client Sample ID: OUTFALL OOC-HEATING BOILER LAL Sample ID: L1304-10 Date Collected: 21-FEB-94 Date Received: 22-FEB-94 Hatrix: lister Login Hubert L1304 Gross Alpha 13 HAR.94 GR ALP/BETA LAL-0060 5902 0.24 0.5 0.92 pCI/L Gross Beta 13-HAR-94 GR ALP/BETA LAL-0060 5902 0.1 1.2 2.1 pCI/L Page 2
| |
| | |
| RAD DATA REPORT (ra01)
| |
| Indiana Hichigan Power Co.
| |
| * Bridgman,HI Organic and Inorganic Contamfnants (Project COOK-JEHI)
| |
| Client Sample ID: OUTFALL OOC-HEATIHG BOILER LAL Sample ID: L1304-11 Date Collected: 21-FEB-94 Date Received: 22-FEB-94 Hatrix: Mater Login Number: L1304 Ra-226 21-HAR-94 RA-226 LAL-0073 5874 0 '49 0.055 0.044 pCI/L Ra-228 14-HAR-94 RA-228 LAL-0074 5873 7.39 0.5 0.5 pCi/L Page 3
| |
| | |
| PH Analysis (LAB.079)
| |
| PH Meter CPC y- le~ Outfall OOC Cal date due f+/
| |
| Sample Sample Time Sample 9 Sample Date CDM Entered by
| |
| : 6) Sample C/ph (prior to correction) 5.3.5 7) NH~ pH correction 02 5.3.6 8) )ample results C/pH.(after 2 3
| |
| Correction) 7'H Sample Sample Time Sample jj Sample Date CDM Entered by
| |
| : 6) Sample C/ph (prior to correction) 5.3.5 7) NH3 pH correction 5.3.6 8) Sample results
| |
| 'C/pH (after Correction)
| |
| ~
| |
| : 9) LAS.041 Specs Review/Date Verified by:
| |
| ~/+/~ ~R'upervisor Form prepared by/Date Form approved by/Date 12 THP LAB.041.25s Revision 1
| |
| | |
| Determination of Total Chlorine Instrument CPC// S0 ~
| |
| (Lab 170)
| |
| Outfall OOC Technician Sample/Standard 5 Z~.
| |
| Sample j/
| |
| Date 37 Time 3i CDM Entered by I) Absorbance 6.11 2) Results, ppm C -A (~ C~ cm
| |
| : 3) Dilutions made C2 C3 CZ M
| |
| : 4) Results, ppm (82 ~ 8 3) c.. W
| |
| : 5) LAB.041 Specs Verified by:~H Supervisor Review/Dare~Mt~~ Pore prepared by/Dree Form approved by/Date
| |
| /~f'+
| |
| 12 THP LAB.041-25)l Revision 0
| |
| | |
| SECTION II PE'T~ .qZ g006SZT SEE 1NSTRUCTIONS ON REVERSE SlDE 0 OD Ao LOCATION OF D I SOWSIE ~SW q ~SE o, EZ00,,~06, zos ~06 6, pj9E ~19~
| |
| Bo H4t%
| |
| 'NA RECEIVIHI HATER (IEo GAOLtCWATER CR IQ% CF QRFACE B SO PT ION OND Co OO YOU DISCNRGE SEASIXRLLY DISCHARGE (IF IOo CCNTItlK lO E)
| |
| LOCATION Do IF YES LIST DISOHKE PERIODS N/A IO. / EAV tQo / DAY FLOW 1
| |
| RATE WASTEWATER
| |
| ~p~ggg CONTACT COOUNQ Eo Fo IhM) APPLICATION RAlK 1YPE OF HASIEHAIKR DISCHA%E N/A ~s LJ IHo/IRo
| |
| ~2 ~ u IRo/DAY
| |
| ~ u ~ 'u LJ IHo/ICo
| |
| ~ KI +
| |
| 2 NONCOIIDICT Go DISEHU4E SOEnlK (YEARLY AVERNKI HXRS/DAY oovhooo COOLDIQ 3 Ho DISCHhRtK FUBI RATE 4 9 Itl+CXE PROCESS IDTAL YEARLY SANITARY 5 STORMWATER All time daily maximum DAILY HIHIIItl 0 ~2 times 365. DAILY tQXIIItI 2 .6 ~2 MQY PBIIITo ltllQCXK 1 lo TIE HAXIPltl DISCHARGE FLDH RATE TO BE AUDERIZED IH 2 MQD 3 QPD Jo HAXDltlDESIGN DISCHUSIE FUX RNKo 5 . 2 V Ao IXI YCU USE HATER TREAT%HE AIDITIVKS10 1RFAT VIXR (IF HSo CCNTIIAK 1D IT81 3)
| |
| Dl~ DESIGN ITEM Bo IW% RlCTlENo JUO OEIIICAL IXPEOSITICN OF TABIE AIIITIVESo SULFURIC ACID H Neutralization" 2 WATER SODIUM TREATMENT ADDITIVES oF TIEBK ITIYEs, SULFURI C ACID SODIUM HYDROXIDE UNITS CODE MARSULEX, INC. HAVILAND PRODUCTS COMPANY 1 MQ/I 111 GORDON BAKER ROAD, SUITE 30 421 ANN ST., N.W.
| |
| 2 UQ/I NORTH YORK, ONT M2H 3R1 GRAND RAPIDS, MI 49504
| |
| ~
| |
| HINII%tl INITS AY8IIGE ItlITS ~ HAXIIEtl ItUTS Do EXPECIED DISCHUGE CEIEEHIIIATICN OF AIDITIVESo
| |
| ~ Sodium Sulfate '0130011500~1 ECCK
| |
| ~
| |
| ~
| |
| gag COCK AEDITIYE AEDITIVE IWE AEOITIVK Nh%
| |
| Wo~ l LJo~ LJi E. DO 51I 1RFAT 1IE DISONCE lD RBOtE AISITIVEST Fo WLT IS THK RBEHAL EFFICIBEY AHD DISCHARGE FR81EIC6 N/A IRSo/DAY DAYS/HH.
| |
| AEDITIVE HNE LJ AESITIVE VIE AED ITIVE IWE G, AS AH ATTICIP%HT 1D 1HIS APPLICATICN PROVIIX SPECIFIC HAPtQLIAH CR ACULTIC TOXICCUXIICALDATA ER REFERENCE HHICH ARE AVAILABLEAHD IHPOI6ATICN IXI II% RATE OF DESRADATICN OF TIE fRXLCQ FCR DCH AEDITIVEo MSDS attached.
| |
| * Approximately instantaneous neutralization upon mixing - (New tank to be completed January of 1995 will ensure complete neutralization prior to discharge.)
| |
| 31
| |
| | |
| INSTRUCTIONS FOR COMPLETING SECT)Of I I ITEMS I ANO 2 This form requires Information on the facility'5 dl5charge location, discharge schedule, volume t lov rate and vater treatment add lt I ves.
| |
| IN THE BOX AT THE TOP OF THIS FBI. THE PERMIT NUMBER CAN BE FOUNO ON THE FRONT PAGE OF YOUR EXPIRING ENTER THE PERHIT NUMBER pERMIT. It tnls Is a nev or not previously perm)tted facility, then leave blank and a numoer rill be as5lgned.
| |
| for eacn page o'. Section I. For caen Individual dlscnaroe point 5 separate set ot Enter the outtall nuaber In space provided I Section II forms must be filled out.
| |
| ITEM I OISCHARGE LCCATION SCHEDULE ANO FLOW RATES A. Enter the location ot discharge, this should include quarter~uarter section. quarter section, section, Iorni and range.
| |
| B. List name of receiving water <If surface ~ater discharge).
| |
| C. Indicate rnetnar facility discharges on a seasonal basis.
| |
| O. If yei, list dlscnarge periods.
| |
| E. provide the land application rates used or expected to be used In terms of inches per hour, hours Der day, and Inches Der raex.
| |
| F. Indicate the type of vastevater to be discharged froa this outfall. Rater to the wastewater type code given In the lett margin. MOre than One COqe may be applICable.
| |
| G. Provide the average nuroer of hours per day In vhlch the taclllty dlscnarges treated wastewater and the total number ot days per year in mich The dl5cnarge occur5.
| |
| H. provide current (frcm the last l2 months) or expected f low rates as requested, Refer to unit code divan In the lett margin for tne appropriate t low units. MGY - million gallons per year; MGo million gallons per day; GPO gallons D>> day.
| |
| I. Provide the maximum discharge tlor rate which you rant to have authorised within the Detmlt. NOTE: For NPOES permlt5 allY.
| |
| the use ot such a tlor rate rill not place an actual limit restriction on the f lor but vill be the t low rate used to dewloo ett luent limits. Also, when the Monthly operating Reports are reviewed by compliance statf It vill help thea to determine If any ner or Increased uses might have occurred at the taclllty.
| |
| J. Provide the design t low tor this specific outfall discharge (e.g. batch treatment System flow, packaged treatment syat~ flows or acme other f Inlte treats>>nt systea flow).
| |
| ITOI 2 WATER TREATMENT AOOITIVES A. Indicate rhether dl5Charge Is treated vlth conditioners, Inhibitors, or mlcrobloclde. If not, continue to Item 3.
| |
| B. Give name, function, and chemical ccnoosltlon ot additives used.
| |
| C. Give name and address ot the manutactureris) ot the additives used.
| |
| 0, Indicate expected mlnlaxxa, awrage and maxlaxaa discharge concentrations ot the addltlvels) tor this dl5char9e.
| |
| Ind)Cate rnetner yOu treat the dlSCnarge tO ramOVe the addltlVela) befOre d)SCharge Ot raaterater.
| |
| F ~ Indicate the removal efficiency ot each additive from the wastewater and the discharge frequency ot each additive to the surface water or groundwater.
| |
| G. NOTE: lt ls the responsibility ot the applicant to supply the product Intormat)on as requested, in this item a. Information requested but not suDp lied may re5ult In the aDpl lcatlon being returned to the apDI leant for completion.
| |
| 32
| |
| | |
| MATERIAL SAFETY DATA SHEET e33k SODIUM HYDROX I DE 50%
| |
| INDUSTRIAL GRADE SECT QN I I I DENT IF I CATION MANUFACTURER S NAMEo o ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ Haviland Products Company ADDRESS (STREET, CITY, STATE, Z IP) 421 Ann St., N.W., Grand Rapids, MI 49504 PHONE NUMBERS a ~ ~ o ~ o ~ ~ ~ ~ a ~ a ~ ~ ~ ~ (616) 361-6691
| |
| ~
| |
| EMERGENCY PHONE NUMBER......... CHEMTREC (800) 424-9300 EFFECT I VK DATE s ~ a ~ ~ ~ ~ ~ e o ~ e ~ ~ ~ ~ 6/18/91
| |
| ~
| |
| TRADE NAMEo ~ ~ ~ ~ ~ ~ s ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ SODIUM HYDROXIDE 50%
| |
| INDUSTREAL GRADK CHEMICAL FAMELY Alkali, Base SECTION II HAZARDOUS INGREDIENTS HAZARDOUS COMPONENTS QSHA/PEL ACGIH/TLV (Uni ts) PROD. CAS 0 Sodium Hydra- ide (Caust i c 2 mg/m= 2 mg/m~ TWA 10-7 Sada) TWA (48.5-51.0% by wt)
| |
| Sodium Chlaride (0. 8-1.3% Nat Not 7647-14-5 by wt) Kst ab 1 i shed Established Water (Bal ance) Nat Nat 7732-18-5 Estab 1 i shed Kstab l i shed SECTION III PHYSICAL DATA MCXM MCC BOILING POINT................ 293 F (145 C)
| |
| FREEZING POINT ............... 60 F (15.6 C)
| |
| VAPOR PRESSURE (mm Hg)........ 1.5 C< 20 C VAPOR DENSITY (Air~i)......... Na Information Available SOLUBILITY IN H20- ~ ~ . ~ ~ ~ . ~.... Campletely APPEARANCE/ODOR.' ~... ~ . ~ .. Clear, Color less Liquid; Odorless SPECIFIC GRAVITY (H20~i ) .....
| |
| ~ ~ ~
| |
| : 1. 52 PH............................ Nat Established SECTION IV FIRK AND EXPLQSIQN HAZARD DATA D RR RCt C DPCRCRZECZ R R K RCXRCDXZKRRCtCSRP K R%R D CIRC@
| |
| FLASH POINT..................'...... Nat Flammable LOWER EXPLOSIVE LIMIT (% by Volume) Nat Appl i cabl e UPPER EXPLOSIVE LIMIT (% by Volume) Nat Applicable EXTENGUESH MEDIA................... As f ar Surrounding Fires 07/30/1'F91
| |
| | |
| MATERIAL SAFETY DATA SHEET SODIUM HYDROXIDE 50%
| |
| INDUSTR I Al GRADE SPECIAL FIRE FIGHTING PROCEDURES... Near NIOSH/MSHA approved self contained breathing apparatus and full protective equipment when this material is involved in a fire.
| |
| UNUSUAL FIRE HAZARD................ In solution caustic can react with amphateric metals generating hydrogen whi ch i s f 1ammabl e and/or e:~pl osi ve i f i gni ted o SECTION V HEALTH HAZARD DATA CARCINOGENICITY............. None NTP ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ Na I ARC ~ ~ ~ ~ ~ ~ ~
| |
| ~ ~ ~ ~ ~ s s s ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ no OVER EXPOSURE EFFECTS....... Redness of E:cposed Tissues with passible burns r esul ting in deep ulceration.
| |
| PRIMARY ROUTE (S ) OF ENTRY... Skin Contact, FIRST AID PROCEDURES........ If inhaled: Remove to fresh air. If not breathing', give artif icial respiratian, pref erably mouth-to-mouth. If breathing is difficult, give o-ygen. Get medical attention.
| |
| In case of contact: Immediately flush, eyes or skin with plenty af ~ater for at 1east 15 minutes while removing cont,aminated clothing and shoes. Get medi cal attent.i on. Nash cl othing bef ore reused Ingestion: Da not induce vomiting.
| |
| If conscious, dilute by giving several glasses af water. Call a Physician Immediately.
| |
| EXPOSURE AGGRAVATED MEDICAL CONDITIONS None Currently Known SECTION VI REACTIVITY DATA MZf MMMMMMMWCCCR&MMM MClMXt CHEMICAL STABILITY............ Stab 1 e CONDITIONS TQ AVOID........... Nat Applicable INCOMPATIBLE MATERI ALS........ Acids DECOMPOSITION PRODUCTS. ~ ~ . ~ ~ ~ ~ Nane Curr entl y Known HAZARDOUS POLYMERIZATION...... Ni 1 1 Nat Occur POLYMERIZATION AVOID.......... Nat Applicable Ckm RRRCECP C RRXtStRCJDR SX 'CRCt R'C R PAR ~ QR gLRR RCSCCC5 SECTION VII SPILL OR LEAK PROCEDURE
| |
| | |
| MATERIAL SAFETY DATA SHEET SODIUM HYDROXIDE 50/
| |
| INDUSTRIAL GRADE FOR SP ILL ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ a s ~ ~ ~ ~ s ~ Add non-r cacti ve dry, absorbent such as diatomaceous earth. Shovel or sweep up and place in an approved DOT container and seal. Flush contaminated area and neutrali "e with dilute acid.
| |
| MASTK DISPOSAL METHOD..... i... Dispose of spilled or waste product, contaminated soil and other contaminated mater ials in licensed landfill or treatment facility in accordance with all federal, state and local regulations.
| |
| SECTION VI II SPECIAL PRQTECTION WCR RESPIRATORY PROTECTION........ Supplied air or self contained breathing apparatua with ful l f ace piece.
| |
| VENTILATION.............,..... To maintain vapors below limits.
| |
| PROTECTIVE GLOVES............. Rubber or other impervious materials.
| |
| KYE PROTECTION............;... Chemical splash proof goggles.
| |
| OTHER PROTECTIVE EQUIPMENT.... A safety shower and eye bath should be available. For operations where spills or splashing may occur, use an impervious body covering and boots.
| |
| HANDLING AND STORAGE.......... Store in cool, dry, well ventilated area.
| |
| Keep containers closed when not, in use.
| |
| SECTION IX SPECIAL PRECAUTIONS CCM HAZARD CLASS...............:.. Corrosive Material DQT SHIPPING NAMK UN NUMBER e
| |
| ......... ~ ..
| |
| ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~
| |
| SODIUM HYDROXIDE, LILQUID UN 1 824 REPORTABLE QUANTITY (RQ)...... 2000 lbs.
| |
| REFERENCES HMIS: H-S, F-O, R-1 SODHYDOX 07/ " 0/ 1 9'P 1
| |
| | |
| r~(Q I 0 "I I friARSULEX, MATERIALSAFETY DATA SHEET Sulfuric Acid
| |
| : 1. PRODUCT AND COMPANY IDENTIFICATION
| |
| . Product Name: Sulfuric Acid :Formula: H,SO, Molecular Weight: 98.08 Chemical Name: Sulfuric Acid chemical Family: Inorganic Acid vCASP 7664-93-9
| |
| ~Synonyms: Sulphuric Acid, Oil of Vitriol, Battery Acid Product Use: Used tn manufacture of fertilizers, explosives, other ackls, metal plclding and petroleum processing.
| |
| MARSULEX Inc. MARSULEX inc.
| |
| 111 Gordon Baker Road 40 Richards Avenue EMERGENCY TELEPHONE NUMBER ulte 300 P.O. Box 5453 orth York, ONT Nofwalk, CT (800) 263-S502 M2H 3R1 0685&6453 (416) 496-9655 (203) 8544300 Prepared by MARSULEX Technical Section (416) 49&4164.
| |
| : 2. COMPOSITION/INFORMATION ON INGREDIENTS
| |
| % by Wt. CAS Number Sulfuric Ackl 70-100% 7664-93%
| |
| Water 7732-186
| |
| : 3. HAZARD INFORMATION EMERGENCY OVERVlEW:
| |
| 'f/Dangerl Extremelycorrosive. Causesseverebums. Reacts vlolentlywlthwater. Hlghlyreactlveand capable igniting combustible materials on contact. Not flammable, but reacts with most metals to form explosive hydrogen gas.
| |
| /Sulfuric Add h a colorfess to amber, dear to slightly doudy, oily liquid.
| |
| National Rre Protection Association (NFPA) Rating Hazardous Materials fdentNcatlon System (HMIS) Rating 4 Extreme/Severe
| |
| . 3 High/Serious
| |
| ~ 2 Moderate FlRE 1 = Slight 0 ~ Minimum W Water Reactive Date: February, 1993 MARSULEX MSDS 4010E
| |
| . Superaedea: February, 1990 Page 1 of 9
| |
| | |
| MPTERIAL SAFETY DATASHEET, Sulfuric Acid
| |
| : 3. HAZARD INFORMATlON (continued)
| |
| POTENTIAL HEALTH EFFECTS:
| |
| Exposure Limits:
| |
| ACGIH (TLV) OSHA (PEL)
| |
| SWfuric Acki 1 mg/m (TWA) 1 mg/m'fWA) 3 mg/m'STEL)
| |
| In contact with the skin: Concentrated solution may cause pain and severe burns to the skin and brownish or yellow stains. Prolonged and repeated exposure to dilute solutions may cause irritation, redness, pain and drying and cracking of the skin.
| |
| C~
| |
| ln contact with the eyes: Immediate pain, severe burns and corneal damage which may result In bllndnesa Inhaled: Mists and vapors may cause Irritation of the eyes, nose and respiratory tract. May cause Increased
| |
| ~ pulmonary resistance, transient cough and bronchoconstrlctlon. Severe overexposure may result In lung collapse and pWmonary edema which can be fatal.
| |
| ingested: Severe burning and pain ln the mouth, throat and abdomen. Vomiting, dhrrhea and perforation of the esophagus and stomach lining may occur.
| |
| Long Term Exposure:
| |
| ~Repeated exposure may produce erosion and discoloration of teeth.
| |
| Although no direct link has been established between exposure to sulfuric acid, Itself, and cancer In man, the World Health Organization (WHO) Intematlonal Agency for Research on Cancer (IARC) have concluded that occupational exposure to strong Inorganic acid mists containing sulfuric acid Is carcinogenic to man, causing
| |
| , 'ancer of the larynx (the voice box) and, to a lesser extent, the lung. Exposure to any mist or aerosol during the use of this product shoWd be avoided and, In any case, keep exposures below the occupational exposure limit for sulfuric acid.
| |
| Corrosive effects on the skin and eyes may be delayed, and damage may occur without the sensation or onset of pain. Repeated overexposure may lead to contact dermatitis, may cause bronchitis with cough, phlegm,
| |
| >'hortness of breath and emphysema, can cause chronic runny nose, tearing of the eyes, nosebleeds and stomach upsets. Strict adherence to first akl measures following any exposure Is essenthl.
| |
| Existing Medical CondNons Possibly Aggravated By Exposure: Skin irritation may be aggravated In IndMduals with existing skin lesions. Breathing of vapors or sprays (mists) may aggravate acute or chronic asthma and chronic pulmonary disease such as emphysema and bronchitis.
| |
| Carcinogenicity Data: Although there are reports linking exposure to sulfuric ackl to cancer, this product Is not classified by NTP (National Toxicology Program), not regulated as carcinogenic by OSHA (Occupational Safety and Health Administration), and has not been evaluated by IARC (International Agency for Research on Cancer)
| |
| / or ACGIH (American Conference of Governmental Industrial Hyglenlsts). (See also, Long Term Exposure).
| |
| N MARSULEX MSDS 4010E Effective Oate: February, 1993 Page 2 of 9 Supersedes: February, 1990
| |
| | |
| NARSULEK, MATERIALSAFE IY DATA SHEET Sulfuric Acid
| |
| , 4. FIRST AID MEASURES Prompt removal of this material from contact with the body ls of utmost Importance.
| |
| &TART FIRST AID AT ONCE.
| |
| Precaution: Persons attending the victim should avoid direct contact with heavily contaminated dothlng and
| |
| 'omitus. Wear impervious gloves while decontaminating skin and hair.
| |
| In contact with the skin: Rush skin with running water for a minimum of 20 minutes. Start flushing while removing
| |
| ~ contaminated dothlng. If Irritation persists, repeat flushing. Obtain medical attention IMMEDIATELY. Do not transport victim unless the recommended flushing period ls completed or flushing can be continued during transport a /'hile the patient ts being transported to a medical facility, apply compresses of Iced water. If medical treatment the affected area ln iced water. If immersion ls not practical, compresses of iced water must be delayed, immerse can be applied. Avoid freezing tissues.
| |
| Discard heavily contaminated dothlng and shoes in a manner which limits further exposure. Otherwise, wash
| |
| /. dothtng separately before reuse.
| |
| In contact with the eyes: Immedhtely flush eyes with running water for a minimum of 20 minutes. Hold eyelkfs open during flushing. If irritation persists, repeat flushing. Obtain medical attention IMMEDIATELY.Do not transport
| |
| / victim until the recommended flushing period Is completed unless flushing can be continued during transport.
| |
| . Inhaled: Move victim to fresh air. Give artlcial respiration ONLY If breathing has stopped. Give Cardiopulmonary flesuscltatlon (CPR) Il there ls no breathing AND no pulse. Obtain medical attention IMMEDIATELY.
| |
| Ingested: If vlctlm ls alert and not convulsing, rinse mouth and give TA to 1 glass of water to dilute materiaL If spontaneous vomiting occurs, have victim lean forward with head down to avoid breathing In of vomitus, rinse mouth and administer more water. IMMEDIATELYcontact local poison control center. Vomiting may need to be induced but should be directed by a physlchn or a poison control center. IMMEDIATELYtransport victim to an emergency facility.
| |
| h Note to Physician: AII treatments should be based on observed signs and symptoms of distress In the patient.
| |
| Medical conditions that may be aggravated by exposure lndude asthma, bronchitis, emphysema and other lung
| |
| / diseases and chronic nose, sinus or throat conditions. Severity of the bum Is generally determined by the
| |
| / concentration of the solution and the duration of exposure. In the event of skin or eye contact, lmmedhte and thorough flushing Is essential. Continued washing of the effected area with cold or Iced water wIII be helpful in removing the last traces of sulfuric acid. Cream or ointments should not be applied before or during the washing phase of the treatment.
| |
| : 5. FIRE FIGHTING MEASURES sh Point (method): Not applicable, product Is non-flammable utolgnltlon Temperature: Not combustible Rammabllity Limiti in air(%): UEL Not applicable LEL Not applicable MARSULEX MSDS ItI010E Eeettlte Date: February, 1993 February, 1990 Page 3 of 9 Supersedes:
| |
| | |
| MATERIALSAFETY DATA SHEET Sulfuric Acid
| |
| : 5. FIRE FIGHTING MEASURES (continued)
| |
| Fire Extinguishing Media: For small fires use dry chemical or carbon dloxkie. For large fires, flood fire area with r'ater from a distance. Expect violent reaction with water. Do not get solid stream of water on spilled materhl.
| |
| Special Fire Fighting Procedures: Wear a NIOSH/MSHA approved self~ntalned breathing apparatus If vapors or mists are present and full protective clothing. For fighting fires in dose proximity to spill or vapors, use acld-resistant personal protective equipment. Evacuate residents who are downwind of fir. Prevent unauthorized entry to fire area. Dike area to contain runoff and prevent contamination of water sources. Neutralize runoff with lime, soda ash or other suitable neutralizing agents (see Deactivating Chemicals, Section 6). Cool containers that are exposed to flame with streams of water until fire ls out.
| |
| Other Fire or Explosion Hazards: Not flammable but highly reactive. Capable of Igniting finely divided combustible materhls on contact. Reacts violently with water and organic materials with evolution of heat. Extremely hazardous Jin contact with many materials, particularly carbldes, chlorates, fulminates, nitrates and plcrates. Sulfuric acid reacts with most metals, espechlly when dilute to give flammable, potenthliy explosive hydrogen gas. Hydrogen gas can accumulate to explosive concentrations Inskle conflned spaces. Follow appropriate NFPA codes.
| |
| : 6. ACCIDENTAL RELEASE MEASURES Steps to be taken In the event of a spill or leak: Remove all Ignition sources. Ventilate area Use approprhte Personal Protection Equipment. Prevent liquid from entering sewers or waterways. Dike with Inert material (sand, earth, etc.). Stop or reduce leak lf safe to do so. Collect Into containers for reclamation or disposal only if container
| |
| ~is suitable to withstand the material. Consider insitu neutralization and disposal. Ensure adequate decontamination of tools and equipment following dean up. Comply with Federal, Provincial/Stateand local regulations on reporting releases.
| |
| Deactivating Chemicals:,Ume, limestone, sodium carbonate (soda ash), sodium bicarbonate, dilute sodium
| |
| +hydroxide, dilute aqua ammonia.
| |
| Waste Dlsposai Methods: Dispose of waste material at an approved waste treatment/dtsposai facility, ln accordance with applicable regulations. Do not dispose of waste with normal garbage or to sewer systems.
| |
| V'ote - pean-up materfal may be a RCRA Hazardous Waste on dhposal.
| |
| rr'Spills are subject to CERCLA reporting requirements: RQ 1000 lbs.
| |
| : 7. HANDLINGAND STORAGE Precautions: Wear appropriate Personal Protection Equipment. Do not breath sprays or mists. Do not ingest. Do
| |
| / not get In eyes, on skin or on clothing. Keep ignition sources away from sulfuric acid storage, handling and transportation equipment.
| |
| Handling Procedures and Equipment: Carbon steel or stainless steel materials are suitable for use for acid concentrations equal to or greater than 93%. However, the effect of lower concentrations on the materhls of construction can be very complex. Contact product supplier for specmc recommendations when handling sulfuric acid at strengths less than 77%.
| |
| Effecffve Date: February, 1993 MARSULEX MSDS 0010E Supersedes: February, 1990 Page 4 of 9
| |
| | |
| FJRSUI.EX, MATERIALSAFETY DATA SHEET Sulfuric Acid
| |
| : 7. HANDLINGAND STORAGE (continued)
| |
| Storage Temperature: Store above freezing point (Section 9). Elevated temperatures will increase the corrosion
| |
| / rate of most metals.
| |
| Storage Requirements: Store packaged acid in a dry, well, ventilated location away from combustibles, oxldlzers, bases, or metallic powders. Storage tanks should be protected from water Ingress, be well ventilated, and maintained structurally in a safe and relhbie condition.
| |
| Other Precautions: Sulfuric ackl will attack some forms of plastics and coatings. Always add acid to water - not j water to acid. If kept In upper floors of building, floors should be acid proof with drains to a recovery tank.
| |
| : 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
| |
| -Recommendatlons listed In this section Indicate the type of equipment which will provkle protection against over exposure to this product Conditions of use, adequacy of englneerlng or other control measures, and actual exposures will dictate the need for specific protective devices at your workplace.
| |
| Engineering Controls: Local exhaust venNation required.
| |
| ~
| |
| plratory Protection: A NIOSH/MSHA approved air-purifying respirator equipped with acid gas/fume, dust, mist cartridges for concentrations up to 10 mg/m . An air-supplied respirator If concentrations are higher or unknown.
| |
| S)tin Protection: Impervious (l.e., neoprene, PVC) gloves, coveralls, boots and/or other acid resistant protective
| |
| ~clothing.
| |
| /Eye Protection: Tight-fitting chemIcal goggles and face shield.
| |
| Other Personal Protective Equipment: Where there Is a danger of spilling or splashing, acid resistant aprons or q suits should be worn. Trouser legs should be worn outside (not tucked In) rubber boots. Safety showers and l eyewash fountains should be installed in storage and handling areas.
| |
| : 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Vquld Appearance and Odor. SWfurlc acid Is a clear to amber, heavy, oily liquid which may have a sharp penetrating odor.
| |
| Odor Threshold: No data h Boiling Point: 77.67%: 193'C (380'F); 93.19%: 278K (529'F); 98%: 330'C (626'F) d I@citing/Freezing Point: 77.67%: -11.2'C (+11.6'F); 93.19%: -29.5'C (-21.'I'); 98%: -1.1'C (30'F) d Vapor Pressure at %PC (102'F): 77.67%: 1.2 mmHg; 93.19%: 0.0016 mmHg; 98%: 0.002 mmHg h Specific Gravity at 15'C (60'F): 77.67%: 1.7059; 93.19%: 1.8354; 98%: 1.8437 Vapor Density: (Air=1): 3.4 sulfuric ackl component Bulk Density: Not applicable (see specific gravity) ffecthre Date: February, 1993 MARSULEX MSDS 40tOE supersedes: February, 1990 Page 5 of 9
| |
| | |
| MATERIALSAFETY DATA SHEET Sulfuric Acid
| |
| : 9. PHYSICAL AND CHEMICAL PROPERTIES (continued)
| |
| Evaporation Rate: Not applicable
| |
| /Solubility: Miscible In all proportions ln water. Also soluble In alcohol.
| |
| pH: 0.3 (1N solution at 25'C/78'F)
| |
| : 10. STABILITYAND REACTWITY S tability:
| |
| Under. Normal Conditions: Stable, but reacts violently with water and organic materials with evolution of heat.
| |
| Under Fire Conditions: Decomposes to form sulfur oxides(SQ,).
| |
| Conditions to Avoid: Temperatures which may have a negative effect on the materials of construction used In equipment.
| |
| Materials to Avoid: Contact with organic materhls (such as chlorates, carbldes, fulmlnates and plcrates) may cause
| |
| ~ flre and explosions. Contact with metals may produce flammable hydrogen gaL When diluting, add acid to water.
| |
| Do NOT add water to the acid.
| |
| Hazardous Decomposition or Combustion Products: Toxic gases and vapors (e.g. sulfur dioxide, sulfuric acid p vapors/mists and sulfur trioxide) may be released when sulfuric acid decomposes.
| |
| Hazardous Polymerization: Will not occur
| |
| : 11. TOXICOLOGICAI INFORMATION Toxicological Data:, Lote (oral, rat) 2140 mg/kg L+ (Inhahtion, rat) 510 mg/re for 2 hrs Skin effects (rabbit): Severe Irritation Eye effects (rabbit): Severe irritation Carcinogenicity Data: Although there are reports linking exposure to sulfuric acid to cancer, this product h not
| |
| ,dasslfled by NTP (National Toxicology Program), not regulated as carcinogenic by OSHA (Occupational Safety
| |
| 'nd Health Admlnistratton), and has not been evaluated by IARC (International Agency for Research on Cancer) or ACGIH (American Conference of Governmental Industrhl Hyglenlsts). See Section 3. Hazard Information, regarding Potenthl Health Effects (Long Term Exposure) for further discussion.
| |
| ~
| |
| Reproductive Effects: No Information Is available and no adverse reproductive effects are anticipated.
| |
| ~Mutagenlclty Data: No information h,available and no adverse mutagenic effects are anticipated.
| |
| <'reratogeniclty Data: No Information Is available and no adverse teratogenic effects are anticipated.
| |
| Synerglstlc Materials: None known MARSULEX MSDS 4i010E Effective Oats: February, 1993 Page 8 of 9 Supersedes: February, 1990
| |
| | |
| NARSULH(, 'ATERlAL SAFETY DATA SHEET Sulfuric Acid
| |
| : 12. ECOLOGICAL INFORMATION Ecotoxlc Effects: Harmful to aquatic life in very low concentrations. May be dangerous if It enters water Intake; Rsh toxicity critical concentration 10 mg/L; 7.34 mg/L/48 hrs - Lymneae Palustrls 100% mortality.
| |
| : 13. DISPOSAL CONSIDERATIONS
| |
| ~ Responsibility for proper waste disposal h with the owner of the waste. Work with the appropriate regulatory bodies to ensure complhnce with regulations.
| |
| ~ Consider the collection of residual sulfuric acid into containers for reclamation or disposal only If the container Is suitable to withstand the materhl.
| |
| ~ Consider lnsltu neutralization and disposal.
| |
| ~ Qean-up material may be a RCRA Hazardous Waste on disposal.
| |
| ~ Provincial/State or local regulations or restrictions are complex and may differ from Federal regulations.
| |
| ~ The Information applIes to the materhl as manufactured; processing, neutralizing, use or contamination may make the Information tnapproprhte, Inaccurate or Incomplete.
| |
| : 14. TRANSPORT INFORMATION U.S. (Under DOT) Canada (Under TC)
| |
| /'hipping Name: RQ SWfurlc ackl Shlpplng Name: Sulphuric acid Hazard Class or Division: 8 Classificatio(s): Qass 8 (9.2)
| |
| Product Identification No. (PIN): UN1830 Product Identlflcatlon No. (PIN): UN1830 Packing Group: II Packing Group: II
| |
| : 15. REGULATORY INFORMATION
| |
| ..A SARA Title lll HAZARD CATEGORIES AND LISTS p'cute Yes Extremely Hazardous Substance (Immedhte) Health:
| |
| Chronic (Delayed) Health: Yes (40 CFR 355, SARA Title III Section 302)
| |
| Fire: No CERCLA Hazardous Substance Reactivity: Yes (40 CFR 302.4)
| |
| Sudden Release of Pressure; No Chemical 'oxic Yes (40 CFR 372.65, SARA Title III Section 313)
| |
| EffecUve Date: February, 1993 MARSULEX MSOS 4010E Supersedes: February, 1990 Page 7 of 9
| |
| | |
| MATERIALSAFETY DATA'SHEET Sulfur/c Acid
| |
| : 15. REGULATORY INFORMATION (continued)
| |
| Reportable Quantity (RQ) under U.S. EPA CERCLA: RQ=1000 Ib TSCA inventory Status: Reported/Included
| |
| ~A~D Workplace Hazardous Materials Information System (WHMIS)
| |
| WHMIS Classification(s): Qass E - Corrosive Qass D1A - Very Toxic WHMIS Health Effects Index: Acute Lethality - very toxic - immedhte Corrosive to animal skin WHMIS Ingredient Disclosure LIS: Confirmed A; Meets criterh for disclosure at 1% or greater.
| |
| Reportable Quantity (RQ) under Transport Canada - TDG:
| |
| RQ 5 lltres (or Kg) If lt represents a danger to health, life, property or the environment.
| |
| : 16. OTHER INFORMATION Additional Information and References
| |
| : 1. Envlro-TIPS Manual, 'SWphurlc Acid and Oleum', Environment Canada, February 1S84.
| |
| / 2. Weast, R.C. (Ed.), 'CRC Handbook of Chemistry and Physics', 60th Edition (1S80)
| |
| : 3. Sax, N.l., "Dangerous Properties of Industrhl Materhls', 7th Edition (1989)
| |
| : 4. ACGIH, Threshold LimitValues for Chemical Substances and Physical Agents and Biological Exposure Indices',
| |
| 1S91-92
| |
| : 5. Slttlg, Marshall, 'Handbook of Toxic and Hazardous Chemicals and Carclnogens", 2nd Edition, 1985 Revision Indicators:
| |
| J a In the left margin Indicates a revhlon or addition of information since the previous Issue.
| |
| ffeottlee Date: February, 199S MARSULEX MSDS W10E SuporeodoL February, 1990 Pagosofg
| |
| | |
| NARSULB(, MATERlALSAFETY DATA SHEET Sulfuric Acid
| |
| : 16. OTHER INFORMATION (continued)
| |
| Legend:
| |
| CAS 8 - Chemical Abstracts Service Registry Number 'I CERCIA - Comprehensive Environmental Response, Compensation, and Uabllity Act CFR - Code of Federal Regulations DOT - Department of Transportation EPA - Environmental Protection Agency LC - The concentration of materhl ln air expected to ldll 50% of a group of test animals
| |
| - Lethal Dose expected to kill 50% of a group of test animals LEL - Lower Explosive Limit MSHA - Mine Safety and Health Administration NIOSH - National Institute'for Occupational Safety and Health PEL - Permissible Exposure Limit PVC - Polyvinyl chloride RCRA - Resource Conservation and Recovery Act SARA - Superfund Amendments and Reauthorizatlon Act of the U.S. EPA STEL - Short Term Exposure Limit TC - Transport Canada TDG - Transportation of Dangerous Goods Act/Regulations
| |
| - Threshold Umlt Value TSCA - Toxic Substances Control Act TWA - Time-Weighted Average UEL - Upper Explosive Umit The information contained herein has been prepared by MARSULEX Inc. and Is offered only as a gukie to the J handling of this specific material and has been prepared ln good faith by technically knowledgeable personnel. It Is not Intended to be aII-Inclusive and the manner and conditions of use and handling may Involve other and additional considerations. No warranty of any kind Is given or Implied and MARSULEX Inc. will not be lIable for any damages, losses, InJurles or consequenthl damages which may result from the use or relhnce of any information contained herein.
| |
| EffeeUve Date: February, 1993 MARSULEX MSDS W10E Superaedea: February, 1990 Page 9 of 9
| |
| | |
| ~ ' ~ e \~ ~ I C ~
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| | |
| INSTRUCTIONS FOR COMPLETING SECTION I I ITEM 3 Tr Is form requires information on, the process streams rhlch contribute to this discharge.
| |
| ENTER THE PERMIT NISIBER IN THE MX AT THE TCP OF THIS FORM. THE PEIbIIT NWBER CAN BE FOUND ON THE FRONT PAGE OF YOUR EXPIRING pEIpIIT. If this is a na>> or not previously permitted facility, then leave blank and a number <<ill be assigned.
| |
| Enter outfall number in space provided for eacn page of Section II. For eben individual discnaroe point a separate set of Section il forms must be f I lied out.
| |
| ITEM 3 PROCESS STREAMS CONTRIBUTING TO OISCHARGE: FOR EACH SEPARATE PROCESS PROVIOE THE FOLLOW'ING INFORMATION A. Enter tne name Of the prOCeSS uhlqn COntributeS tO thlS diSCharge. AISO prOVide the prOper SIC COde.
| |
| B. Indicate tne yearly average process scnedule In hours per day and days-per year.
| |
| C. Provide the process wastewater flow rate Infonaetion as requested based on your last I2 months of operations. Refer to unit code given In the left margin for the appropriate flow units.
| |
| : 0. process production Rate - Certain permit limitations may be based on production rates. The production rates used to determine permit limits shall be represented by a reasonable measure of actual production of the facility, such as the production during the high montn of tne previous year, or the monthly averaqe for the highest of the previous five years, or otner reasonable measure as stated In applicable U.s.E.P.A. categorical rules and regulations.
| |
| For neu sources or neu dlschargers, actual production shall be estimated using projected production.
| |
| Record your production rates in the terms and units used in the applicable U.S.E.P.A. categorical rules one regulations for youl type of feel litye
| |
| | |
| SECTlON I l PERMIT~
| |
| NUMBER ts11 0005827 SEE INSTRUCTIONS ON REVERSE SIDE
| |
| .:v As IS BE DISCHARGE FIEPI GROLSDQTTRS2 THIS OUTFALL DIRECTED TO
| |
| ( IF Mls CCtITIIIE TO ITBtl BJ BE GRCLBO OR QX YES GROUNDWATER DISCHARGE Bs THIS DLISTIHI OR ~
| |
| HAS A HBNLXIKOUXIICALSBBTY OR ITS EOJIVALENT BEEN PERFORIEO OR CJRREHT HtlROGKQICAL IHFCttWTICN AVAILABLE DISCHARGE) IF g REOQURED Q
| |
| IS THERE SLFFICIENT
| |
| ~HATER YES ATTAOI A COPY CF THE REPCIITs RESXRCES Report Submitted 12/6/91.
| |
| p~
| |
| INR)RMATIDN Cs ARE YOU R RLAE R LEGER ELLE Rs s
| |
| STII41 AH EXBPTICN (Q(PAGE Q) s (5) LPJGE FRLBI SLttlllTI% A HYIROGIDUXIICALREPORT LEKVAR OR FRLBI GROLtEIWTEB KNITOII% IIEOUJRIBENIS Q) 0F 'nE PART 22 RLLKss IF YEs ATTAcH Q ~S Pg DOCLIENIS ANJ EXPLAIWTICN TO DMt9STRATK TIWT YOLII DISCHARGE IEXAD OUILIFY FOI AM ~ONs Ds ARE YLXJ RBXESTIID A VARIANCE FRCN RULE 3Bs2Z6 (PJGE 19 (td%KIINATICN)OF BE HATER RESOLJEXS CCttllSSION PART 22 GRCLtGIWIKR RILEST IF YESs ATTACH QXH DOCLtEHIS AS IECESSARY TO OQQN$ 7INTK TIE NEED RTI A VARIANCE IN TBIBIS OF TIE CRITIRIA SPKIFIED IN RLAEV5sZ?10 (PJGK CF BE PART 22 RLIESs Es I,IST Alp, OEIIICAL SLBSTAtCKS WIOI ARE IN NICHIGAN S CRITICAL HATERIALS REGISTER TABLE P/
| |
| LPAGE II) ANVCR UsSs KPA'S PRIOIITY ITXLLITANTLIST TABLE Y (PAGE 7) OR ANY OBER SLBSTAJCES X NOT APPLICABLK/BKLIEYEDABSENT
| |
| %lot ARE cR twY BEcoE IILABIIQJs To BE BEBIQwTKD UBEs 0F TIE 6IIGLtEBwTER cR To TIE ILSLIC IEJILBI THAT ARE DISCHARGED OI EXPECTED TO BK DISCHIRGED TO BE GROLtElWTKILBYTHIS FJCILIIYs ESTDWTK THE FINAL EFFLIENT COIEXIIIRATIOIAIO RECCRD ALL DATA IN ITEN 1 OF SECTIOI Il IH lHIS BCDILETs BE JPPLI CJJII'AY BE RKOJIRED TO DO AIDITIOWLIWSIK AIWLYSKSs Cl PRESENTi DATA IROYIBED IN ITTH 7 As DISOIUEIK OWRACIBR I STICS CCNBNBIATIOl lTEM 6
| |
| EXPECTED BCO5
| |
| 'CCD (FIVE DAY BIOOEIIICJIL OXYGEN DEHJjtO)
| |
| (OKIIICALaLYGEN IKIWIO) ~5 ~0 ~18, ~0 ~52 IOC (TOTAL OEANIC CARBON) sssssswssssl SSSNSSC- JJBCNIA NITIOIEH (AS N)
| |
| ~Uss 1 lED/I c ass TOTAL SUSPEIKED SLLUN TIAL PICGPIOEJS (AS P) ~0 . ~02 ~0 . ~08 ~I ~52 2 UO/I >> TOTAL RESICUIL OEJNINE 3 COUNTS/
| |
| 100 tnl DISSCQ%D OXIGEN NDI u>
| |
| 4 S.U.
| |
| 5 'F 5 LSS/DAY FECIL LDLIRIBIBACTERIA
| |
| 'ntPBRABNK (SLttER)
| |
| IEIPERATLIE (HINIBR) ~
| |
| LLJ Bs
| |
| ~
| |
| ~
| |
| LJ LJ OBER IWSTEIWTER OWRACIKRISTICS LJ u5 0 I L 4 G R E A S E 1 0., . ~0 ~1 ~52 ~1
| |
| ~SM~P LORI DE ~10 . ~9 2 0 ~8 1 5 2 2 1
| |
| LXRE.
| |
| GRAS ATE ~80, ~0 ~58 2 ~0 1 ~61 2 2 24 HOUR I TOT A L I L 0 ID8~19 5 .~0 925 ~0 1 ~6 ~2 COllPOSITE REQJIRED IIFOEWTICN FOI SNIFACK IWTBR DIOIIA%ESs Analyses per J. B. Beauboeuf, Target Permit Effluent Limits List.
| |
| | |
| INSTRUCTIONS FOR C(y(PLETING SECTION I I ITEMS 4 ANO 5 This tom requires Information on 4 specific outfall discharging to either the groundraters or the surface waters.
| |
| ENTER THE PERMIT NISIBER IN THE BOX AT THE TCP OF THIS FORM. THE PERMIT NQd)ER CAN BE FOUNO ON THE FRONT PAGE OF YOUR EXPIRING PERMIT. It this is 4 ner or not previously permitted facility, then leave blank and 4 number rill be assigned.
| |
| Enter the outtall number In the space provided for each Daae of section I I . For each Individual discharge point 4 separate set ot Section II terms (items 4 ano 5) must be fl lied out.
| |
| ITO( 4 QROUhOWATER OISCHARGE INFOCMAT ION (OO NOT INCLUOE DEEP WELL INJECTION INFORMATION IN THIS ITEM>
| |
| A.-O. The applicant shall address each of these parts If the discharge tron this outtal I ls to tne aroundrater.
| |
| ITEM 5 EXISTING OR EXPECTEO (FOR A NEW OISCHARGE) WASTEWATER CHARACTERISTICS OF GRCUNOWATER CR SURFACE WATER DISCHARGE (OO NOT INCLUOE r LL INJ I N IN IN H A. The aDDI leant shall report available discharge data (real data for existing discharge or exoected data for 4 Drooosed discharge) for tne Dareneters as listed. These parameters shall be addressed for either 4 surface water discharge or as appropriate for e groundwater dlscnarge. For assistance in determining appropriate parameters 4 groundwater dlscharoe applicant may contact the Groundwater Ouality olvlsion, Pe(mits Section or the appropriate Groundwater ouallty olvlslon'5 Olstrlct otf Ice.
| |
| The applicant shall report the sample type code best descglblng each reported place of data. see coding on the lett margin of this tore.
| |
| ~
| |
| It this outtall Is
| |
| . so:a o
| |
| ol st 4 su>
| |
| t v..
| |
| face ae rater discharoe. the applicant
| |
| ~
| |
| ea oaotv o ev esa e tlat oo must report l .
| |
| m tov a ao ~
| |
| quantitative data for a a ao st a steeve each parameter es a t t tal ~
| |
| aa Identified aoolloatlo
| |
| ~
| |
| a 4 an B. If data ls available for other parameterS not listed above In A. or other parts ot this aDPlicatlon the applicant should report that data In the blank spaces provided In thl5 part.
| |
| NOTES: I. Unit codes tor paraneters reported In parts A and 8 can be tound on the lett hand side ot this form.
| |
| : 2. Grab sample shall be used to analyse tor pH, temoerature, total phenols, residual chlorine, oil and gre4se, and fecal coliform In 4 surface vater discharge unless other frequency-smnpl ~ type analyses are avallabl ~ ~ See Glossary (page 48) tor detlnltlon ot grab sample.
| |
| 24-hour composite samples shel I be used to analyse tor Total B005, coo, Toc, Anmonla Nitrogen, and Total Suspended Solids In a 5urtaoe vater discharge unless other trequency-sample type analyses are aval labia. see Gloss4ry (page 48) tor definition of composite sawple.
| |
| : 4. REPORTING OF INTAKE OATA. You are not required to report unless you vish to demonstrate your ellqlbl llty tor 4 "net" effluent I imitation tor one ot'ore pollutants, that Is, an etfluent limitation adJusted by subtracting the average level of the pollutant(s) Dresent In your Intake vater. NpOES regulations allow net limitations only In certain clrclastances. To demonstrate your eligibility, report the avertx)e of the results ot analyses on your Intake rater (If your vater l5 tre4ted before use, test the vater atter It Is treated), and attach 4 separate sneer containing the tol loving tor eben pol lutant:
| |
| (4) A 5taten>>nt that the Intake rater l5 drawn froh the body of vater Into which the dlsch4rge Is made.
| |
| (Otherwise, you are not eligible tor net limitations.)
| |
| Ib) A statement ot the extent to which the level ot the pollutant ls reduced by treatment of your wastewater.
| |
| (Your limitations vill be adJusted only to the extent th4t the pollutant Is not removed.)
| |
| (c) vnen apDllcable (for exampl ~, when the pollutant represents 4 class of ccmpounds), 4 demonstration ot the extent to rnlcn the Dollutant5 In the Intake very physlc4! Iy, chemically, or biologically tran the pol lutant5 contained In your discharge. (Your limitations ri I I be adJusteo only to the extent that the Intake pollutants dO ndt Vary fraa the dlSCharged DOI lutentS ~ )
| |
| If you have tro or more substantially indentlcal outta(15, you mav request permission fran your permitting authority to smnple and analyze only one outtall and 5ubmlt the results ot the analysis tor other substantially
| |
| ~ dentlqai OutfallS. If yaur requeat IS granted by the permitting authqrity, On a Separate Sheet attaChed tO the application term tdentify vhlch outfall you did test, and describe vhy the outtal la which you did not test are substantially identical to the outfall which you dld test.
| |
| 36
| |
| | |
| SEE INSTRUCTIONS ON REVERSE SIDE SECT1ON lI PERMIT NUMBER ~ MI OQOS827 OOD THE FOLI&IINtt RSXESTKD IIHRWTION ~s AIXJIESSED SEJM QJIFACE HATER DISDWJXIKRS>>
| |
| EJTE) NBf USK DISOwXIERS 2JBLL PROVICE KPPKCIKD VALIKS FCR THE IXJANflTATIVEAND o IXWLITATIVE INFORIWTICN REIXKSTED BEIJJI>>
| |
| Ae IS THIS FACILllV A PRIMARY IMXJSTRY? (RKFBI TO TABIE IA PJGK +
| |
| (IFW,GOVO ) (IF YS GOTOB)
| |
| PRIORITY POLLUTANTS Be INDICATE TYPE CF PRIIWIY IMXJSIRY AS LISTED IN TABJE IA PA%
| |
| ICCNTIMK HIIH C.)
| |
| Q. LEC WR AND Ce GOES THIS OUIFALL DISCHARGE CNTAIK ANY PROCESS HASTKHATKR?
| |
| (IF Mr GO TO E) (IF YES> GO TO D)
| |
| ADDITIONAL INFORMATION De IWICATK NIICH Gt'JHS FRACTICNS MJST BE TESTED FOR>>
| |
| ~>>em FOR (RKRR TO TABLE IA PJVK JII)
| |
| Q Analysis Per SURFACE IDIEI FCR EACH Gt'JHS FRACflON OtKCXKD> EAOI SPECIFIC ORGANIC TOXIC POUJJTANT HIIHIN J.B. Beauboeuf WATER EACH FRACTION t$ 5J BE ANALYZED FOR (SEE TABLE I IA PAGE 92 IN ADOITI0I> ALL PRII>>ARY IIClJSTRY APPLICANIS HITH A PROCESS IWSTKHATKR DISCHARGE ggJ
| |
| ~
| |
| PROVIDE OSWTITATIVE Q er>dere>re Target Permit DISCHARGE IWTA FCR EARTH TOXIC POLJJJTANT IH lAKE I I IA PAfE ~~ e RKcRD AIJ. DlrA oN F0Yts PROVIDED (ITEM 7) IN THIS Boozer. P re,e Effluent Limits ONLY (CNTIMK HITH E K BKIJBI) PESTICIDE Ke IF JKg, QRFJcE HATER DrsowRGK APPLIGANT (PRIIwRY 0R $ Kc06NY IMxrsTRY)> RKGARKLEss OF THE IVPE OF DISCHJJYIK>r IN TAKE IIA ggjf BK PRKIVIWh ANO IVA PAGES EM'R IWS REASON TO BKUKVK TIWT ANY POIJJJTAHT 4JL9X ls DISCHARGED LISTKD FR0t JHY OJIFAL4TIC IXJWTITATIYE DATA Q rrrr rr>u oar/ear>>re remrr.
| |
| N/A RECRD ALL DATA 01 PORC PROVIDED (ITKH 7) IN 1HIS $ 00ZkT>>
| |
| a PRESKHf/DATA ls ATTAIMD Fe IF Nf QRFJCK lWTKR DISCJWRGE APPLICANT (PRIIWIY OR SEQÃCNIY IIKtJSIRY)> RKGJJOXKSS OF TYPE OF DISCNVIGK> IMEfs OR HIS REISCN TO BKUEVE AHY POIJJJTJHIB USTED IN wr APPUCABLdBKLIEYKDABSBIT TAKE VA PAGE REASONS I0t
| |
| ~ ARE DrsftwXM FR01 ANY tJJfFAJJ. TIE APPUCJItf rrrKL( DESCRIBE TIE POIJJJTJHT BEI16 PRKSBIT JJKJ PROVIDE JJII AVAILABLKQOWTITATIVE DATA>>
| |
| N/A REcRD ILL DATA 01 F0ws IROYIKED (ITBI 7) IN THls BOOLEY>>
| |
| 0 PRESENT/DATA IS ATTADED Ge AIJ. SLRFACE IW18t DISCHNXIE APPUCJNIS (PRIMARY AW SKCOIJJtf IHIXISlRIKS) 0R fgFAcrtNKs 2> 4> ~ lllrcJKJ$4%%wxY AcKrrc AcID (2> 4> M)J wr APPUCJBLFJBKUEVKD ABSENT
| |
| . JI,WIRIDKJxtsPINwxr PR0 f Ic (srLttKx, 2, rr, 5, TP)
| |
| N/A
| |
| ~Pr >TRIKMJXKPIEMN (T~KP AlotK ISJST I cR HBIAaacl4%1RK Nfr (AIJ DlTA F0t Tl%
| |
| BE GIMRATKD IIIMISTAwJRD aw mcAL CJUIYIAT10t ProCBXNKS) OR l0l$ts OR HA5 REASCN TO BELIEVE THlr TCKD 1$ 0t HIY BE PRKSBIT IN T%1R DISCHARGE>>
| |
| RKP0IT>>XJAUTATIVE DATA> GE%RATKD HfrCH tgiKD A SCRKKHlw PwCKDIJIK wT TKD HITH AJWLmCJL STAwARDS, FOR z. a, I -
| |
| 8, TKIRJCJKJJIKXJIM~IOXIN Q PRESENT/DATA IS ATTADED (TCD)e RECISID ALL DATA 0l F0Yts PROVIDED (ITBI 5 IN THIS BOOLEY>>
| |
| IF IIE QJIFACE HATER DISCJWRGE APPLICJWf XMlo OR IWS RKISCN TO MUEVK %lr BIOIJXIICAt TOXICITY TESTS HERE HADE IN ll% LAST lINEE (5) YEARS OI ANI CF TIE APPLICANT 5 DISOWNIKS OR ON A RKCEIVIW HATBt IN RKLAT10I TO A DISCIWSKs PROVIDE g wr AppucABLE X
| |
| THts IIRNHAT104 AS AN ATTAOIKÃfTO TH15 APPUCAT101>>
| |
| IF A CNRACt thtCRAT0IY CR KKYIILTIW Fl& PBRÃIED JJN'OF T% AMAVSKS RKIXJIRKD Q APPuCABLE?'SKE AITADED BY THIS APPLICAT101> PRCNIDE TIE Nt% AMJ AKKNESS OF EAOI LAB0IATDIYOR F TIE AWLYSES PKRFIR%D AS AN ATTAKJI%HT OF THIS APPLICATION>>
| |
| IIII AW Q wr AppucABtz 1.>> 00 VIXI DISOWEIK ANY OIIER TOXIC CR IILXNIIXJS DKHICAL SlaSTJNCKS Wr LISTED IH g] APPLICJBLe'SKE ATTADND TAKES IY PAGE tt AW IIA TINOAI VA PIPES ~~ IF VK5> TISH IOBIflsY TIE QX wr JppucABtz IJKMICAL QSISTAWKS AO ESTIHATE TIE FINIL KFFLIKHT C0CBIIRAT10IS ~ QJ>>HIT THIS IIARQTICN AS AN AITAOtKtlTIO 'HIS APPUCATION>
| |
| APPLICABts/SKE ATTAKJND
| |
| | |
| INSTRUCTIONS FOR C04PLETING SECTION I I ITEM 6 This form requires Information on a soeciflc outfal I discharging to the surface>>stere.
| |
| ENTER THE PERMIT NUMBER IN THE BOX AT THE TCP OF THIS FORM. THE PERMIT NWBER CAN BE FOUND CN THE FRONT PAGE OF YOUR EXPIRING pERHIT. It this is a ne>> or not orevlously permitted facility, then leave blank and a nuroer>>ill be assigned.
| |
| Enter the outfall number In the space orovlded for each page of Section II. For each Individual discharge point a separate set of Section II, Item 6 forms must be filled out.
| |
| ITEM 6 PR I ORITY POLLUTANTS ANO ADO IT I ONAL INFOPHAT I ON NOTE: lf you have tro or more substantially Indentical outfal ls, you may request permission frcm your permitting authority to samole and analyze only one outfall and submit the results of the analysis for other substantially Identical outfalls.
| |
| It your request 15 9ranted by the permitting authority, on a seoarate sheet attaChad to the application form Identify rhlch outfall you did test, and describe my the outfalls rhlch you did not test are substantially Identical to the outfall rhlch you did test.
| |
| NOTE: 40 CFR Part I22.2l(g)(8), Friday, Abri I I, l98S, provides for a Small Business Exemption from the reporting of quantitative data for organic toxic pollutants and toxic pollutants as required by Pert l22.2I(g)(7)(ll)(A) or 122.2I(g)(7)(lil)(A).
| |
| A.K. These parts are self-explanatory and do not require further Instructions. Simply go through each part and do as Indicated.
| |
| and E.-J.
| |
| : 0. Several Industrial categories and subcategories have been exemoted frtm submitting data on certain GC/MS Fractions (40 CFR Part l22, Vol. 48, No. 64, Friday, April I, lgBS, Notes I, 2, and S). ~
| |
| Revle>> the folio>>lng list to determine>>bather your facility qualifies to be except free reporting GC/MS (Gss Chrcnetogrsphy/
| |
| Mass Spectroscopy) Fractions.
| |
| GC/MS Fraction Testing and Reporting Exemptions Text I I e illI Is Industry
| |
| - All four GC/HS organic fractions In the Greige Hills Subcategory.
| |
| - Pesticide fraction In el I other suboarts of this Industry.
| |
| Ore Hlnln and Oressl Indust
| |
| - Volatile, base/neutral, and pesticide fractions In the Base and Precious Hetals Subcategory.
| |
| - All four GC/HS organic fractions In all other subcategories of this Industry.
| |
| Gun and Uood Chemical ~ Industr pesticide fraction in the Tali Oil Rosin Subcategory and the hos(n Based Oerlvatlves Subcategory.
| |
| - pesticide and base/neutral fractions in ~ li other subcategories of this industry.
| |
| aslant Pul and Paper Indust
| |
| - Pesticide fraction In Paoergrsde Sulfite subcsteqorles (suboarts J and 0).
| |
| - base/neutral and pesticide fractions ln oeink suboart 0, olssolvinq Kraft subpart F, and Paperboard from vast<<Paper Subpart E. 4
| |
| - Volatll~, base/neutral ~ pesticide fractions In the OCT 8)cached Kraft SubOart N, Seelmhcmical Subparts 8 and C., and Nonlntegrated Fine Paoers Subpart R. 'c
| |
| - Acid, base/neutral, and oestlclde fractions In Fine 4)cached Kraft Subosrt I. oissolvlng sulfite Pulo Suboart K, Ground-
| |
| >>OOd Fine Papert SubOart 0 ~ Narket OleaChed Kraft Subpart 0, TISSue frae UaStepaper Subpart T, and NOnlntegrated QSSue Papers Subpart S.'team Electric Po>>er Indust Hater Fly Ash and Oottt4e Ash Transport Mater process >>astestreams 38
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| | |
| INSTRUCTIONS FOR CCMPLETIHG SECTION I I ITEM 7 This form Is to be used by both Surface and groundvater applicants to record Information on any Hlchlgan critical material, E.P.A.
| |
| priority pol lutant, or hazardous substance In vhlch this app I l cation requires data to be provided. This vould Include any chemical substance fran tne Hlchlgan Critical Materials Register ITabl ~ IV), the E.P.A. Priority Pollutant Listing (Table V), or Tables I IA-VA vhlon I latS OrganlC TOXIC POI lutantS, Other TOXIC POI lutantS, COnVentlOnal and HcnocnVentlonal POI lutantS and HaZardOuS Substances.
| |
| ITEM 7 CRITICAL MATERIALS, PRIORITV POLLUTANTS AHO/OR HAZAROOUS SUBSTANCES IN THE DISCHARGE Material I, 2, 3... 8 A. List thi name ot the chemical substance (critical material, priority pollutant, or hazardous substance) fran Tables IV, V and I IA-VA as reoulrad In tne box mich you cheeked In A. I-3, above. Enter each chemical substance's paneeter number as listed In Tables IV, V and IIA-VA lf Provided.
| |
| B. Provide the average concentration ot the chemical substance naned In A. Indicate the sample type used and the number of analyses made to prerlde the concentration data for the chemical substance nmned In A.
| |
| C. Provide the maximum concentration and determine the mass loading ot the chemical substance nmmzd In A.
| |
| HOTES: I . It only one analysis uas made for a chemical substance then record that data as a maxisxzs value. It more than one analysis has been made tor a chemical substance then provide an average value ot those analyses and the maximus value ~
| |
| : 2. This Section II, Itea 1, Oata Sheet provides space for recording data for 8 chemical substances IMaterlals).
| |
| Additional space tor recording of data for more than 8 Materials can be made by making copies of this Item 1 Oats Sheet as needed. It ls also important to use a separate set of Oata Sheets fot each appllcabl ~ reporting reculrmaent as listed In A.l 3. and tor each outtali ~
| |
| : 3. Rater to the lett margin tor the code number representing the smapl ~ type used and the appropriate unit codes.
| |
| | |
| Loci<heed Analytical Services INDIANA MICHICANPOWER COMPANY SAIVIPLE ANALYSIS
| |
| | |
| ==SUMMARY==
| |
| PACKAGE FOR VOLATILE AND SEIVII-VOLATILEORGANICS,
| |
| - PESTICIDE/PCBS, CHLORIDE, NITRATE/NITRITE, SULFATE, FLUORIDE, CYANIDE, IVIETALS, AND MERCURY LOG-IN NUMBER: L1009 QUOTATION NUMBER: Q331 620 DOCUMENT FILE NUMBER: 1229485
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| | |
| ~toe/rheed ''
| |
| elL'/a ~a 7rllce rv"l
| |
| ~ . s)' a r ~ -r"<< ~ ~ ~ ~ ~
| |
| ~
| |
| Lockheed Analytical Services Phone: (800) 3614220 975 Kelly Johnson Orive Fax: (702) 361~
| |
| Las Vegas, Nevada 891194705 February 4, 1994 Mr. Rocky Beem Cook Nuclear Plant 1 Cook Place Bridgeman, Ml 49106 RE: Log-in No.: L1009 Quotation No.: Q331620 Document File No.: 1229485 The attached data package contains the results of analyses on samples that were submitted to Lockheed Analytical Services on December 29, 1993. The samples were received at 5'C.
| |
| SUMIVIARY ANALYSIS STATEMENT:
| |
| Inorganics All ground water samples were received in good condition, on December 29, 1993. All samples were analyzed within the method-specific holding times. The method blanks were free of contamination.
| |
| All Internal Quality Control were within acceptance limits with the following exception: The matrix spike recoveries for barium and selenium were slightly outside of acceptance limits.
| |
| The acceptable recovery of the Laboratory Control Samples supports that the analytical systems were operating within control limits.
| |
| The reporting detection limit for nitrite was raised to 0.50 mg/L for sample S. Sewage Plant Eff. (L1009-4) due to interferences from chloride.
| |
| Organics Method 8260 All calibrations and quality control criteria were met with the following exceptions:
| |
| All samples were analyzed, initially within holding times but failed surrogate recovery QC limits. The samples were reanalyzed one day beyond the method specified holding time and all samples met surrogate recovery QC limits. Tentatively identified compound searches were performed on all submitted samples. Only the reanalyses are reported.
| |
| | |
| COOK NUCLEAR February 4, 1994 PAGE 2 Method 8010/8020 All calibrations and quality control criteria were met with the following exceptions:
| |
| The matrix spike and matrix spike duplicate precision for 1,1-dichloroethene exceeded the QC criteria although all percent recovery criteria were met. Data quality is not effected.
| |
| Method 8270 All samples were extracted and analyzed within the method specified holding time. All initial and continuing calibration criteria were met. Bis(2-ethylhexyl)phthalate was detected in the method blank at 1.3 ug/L. There was no other contamination detected in the method blank.
| |
| Percent recoveries for all surrogate compounds was within QC limits for all samples analyzed.
| |
| A laboratory control sample (LCS) and laboratory control sample duplicate (LCS DUP) was prepared and analyzed with this set of samples. The percent recovery criteria for all spiked compounds was within the QC limits as was the relative percent difference between the two.
| |
| The response for bis(2-ethylhexyl)phthalate in sample TRANS. CATCHBASIN exceeded the calibration range in the initial analysis. The sample was reanalyzed at a dilution of 1:4 and all compounds fell within the calibration range. Both sets of results are reported.
| |
| Method 8080 AII samples were extracted and analyzed within the method specified holding time. All initial and continuing calibration criteria were met. No contamination was found in the method blank. Few of the surrogate spike recoveries were within the QC limits due to an apparent spiking solution problem. Data quality is not effected since all percent recovery criteria were met for the laboratory control sample and laboratory control sample duplicate. No target compounds were detected above the reporting detection limit and there was no dilution or reanalysis performed.
| |
| If you have any questions concerning the analysis or the data please do not hesitate to contact James L. Jordan, (702) 361-3955. ext. 289.
| |
| Release of this data report has been authorized by the Laboratory Director or the Director's designee as evidenced by the following signature.
| |
| ncerely, James L. Jo dan Client Services Representative JL J/at cc: Client Services Document Control Department
| |
| | |
| ~Wc/rheed Lockheed Analytical Services Phone: (800) 582-7605 975 Kelly Johnson Drive Fax: (702) 361%146 Las Vegas. Nevada 89119-3705 February 17, 1994 Mr. Rocky Beem Cook Nuclear Plant 1 Cook Place Bridgman, Ml 49106
| |
| | |
| ==Dear Rocky,==
| |
| | |
| Per your request during our phone conversation this morning, the following is an explanation of the procedure used for the determination of the non-standard organic compounds in your groundwater samples.
| |
| The samples were analyzed using instruments that were set up for standard methods 8260 and 8270. A few of the compounds on your lists of analytes are not standard method 8260 or 8270 compounds. Once the samples are analyzed and a chromatogram was obtained for the samples, all peaks that were present in the samples that did not correspond to one of the calibrated compounds were investigated further. This involved taking the mass spectra obtained from these peaks and comparing the spectra to an NIST library of spectra. This library contains approximately 52,000 known mass spectra. The mass spectra of the additional analytes of interest to you are contained within this library. None of the non-standard analytes were detected in any of your samples.
| |
| For the next quarters round of sampling, we are endeavoring to obtain the standards for these compounds so that they will be calibrated for in the analyses of those samples. If you have any further questions or if I can be of any further assistance, please do not hesitate to call me at (702) 361-1626 ex. 289.
| |
| 'ncerely, James L. rdan Project Manager cc: M. Butler
| |
| | |
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| VOLATILE ORGANIC ANALYSIS RESULTS GC/HALL ANALYSES USING EPA METHOD 8010 lin ml Da oil:
| |
| m I ID: TR Date Anal zed: 04-JAN-94 2 -D LAL D R ID: L1 iv:
| |
| Dilution Factor: 1
| |
| -D Matrix: WATER QC Batch ID: 122093-801020-0-3 Anal tical Batch ¹: 122093-801020-0-3 rro R v r Limi BCM 114 65-125 BFB 92 60-120 Concentration Reporting Constituent Detection Limit Data Iyg/L) IL Qualifier(sl Dihl r ifl r m han hlrm hn Vin I chloride <0.50 0.5 Brompm ethane hir hn Trihlrfl rm hn 1 1-Dichloroethene <3 Meth lene chloride <6 ran-1 -Dihl r hn 1 1-Dichl r han Chloroform 1 1 1-Trichloroethane <4 r n r hl ri 12-Dihl r hn Trichloroethene TCE 1 2-Dichloro ro ane <0.5 0.5 Brm ihlrm hn 2- hl r h Ivin I her cis-1 3-Dichloro ro ene trans-1 3-Dichloro ro ene 11 -Trihl r hn Ter hlr hn P < 0.5 Dibromochloro methane Chlorobenzene < 0.5 0.5 Brmfrm 1 1 2-T r I r h n 1 3-Dichlorobenzene <2 1 4-Dichlorobenzene 1 2-Dichlorobenzene LOCKHEED ANALYTICALSERVICES A
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| V sJ
| |
| | |
| VOLATILE ORGANIC ANAlYSIS RESULTS GC/PID ANALYSES USING METHOD 8020 D
| |
| li n II:
| |
| m I ID: TR 2 -DE Date Anal zed: 04-JAN-94 LAL D R m I ID: L1 iv: 2 -DE Dilution Factor: 1 Matrix: WATER QC Batch ID: 122093-801020-0-3 Anal tical Batch ¹: 122093-801020-0-3 rro Re ver Limi TFT 94 70-120 BFB 95 75-120 Reporting Concentration Detection Limit Data Constituent IL IL Qualifier s Benzene 0.52 0.5 T'I n hir n n Eth I Benzene m -X lene <2
| |
| -X I n 1 - ' n 1 4-Dichlorobenzene 1 2-Dichlorobenzene <2 LOCKHEED ANALYTICALSERVICES h4
| |
| | |
| VOLATILE ORGANIC ANALYSIS RESULTS GC/HALL ANALYSES USING EPA METHOD 8010 lin ml ID: TR- A LAL m ID: L1 D II ' -DE D R 'v:
| |
| I 2 -D Date Anal zed: 04-JAN-94 Dilution Factor: 1 Matrix: WATER QC Batch ID: 122093-801020-0-3 Anal tical Batch ¹: 122093-801020-0-3 rr R v r '/
| |
| Q Limi BCM 120 65-125 BFB 86 60-120 Concentration Reporting Constituent Detection Limit Data (yg/L) /L Qualifier(s)
| |
| Di hlor iflu r m han hlrm hn Vin I chloride < 0.50 0.5 Bromomethane hlr hn Trihlrfl rm hn 1 1-Dichloroe hen <3 Meth lene chloride <6 rn-1 -Dihlr hn 11-Dihl r h Chloroform 1 1 1-Trichloroethane <4 r n r hl ri
| |
| 'l2Dihlr hn Trichloroethene TCE 1 2-Dichloro ro ane <0.5 0.5 Brmoihlrm hn 2- hlr hlvinl hr cis-1 3-Dichloro ro ene trans-1 3-Dichloro ro ene 1 1 2-Tri hl r h n Ter hlor h n P E Dibrornochlorome hane Chlorobenzene <0.5 0.5 Br m f rm 11 -T r hlr hn 1 3-Dichlorob nzene <2 1 4-Dichlorobenzene 1 2-Dichlorobenzene LOCKHEED ANALYTICALSERVICES nr.
| |
| Vv
| |
| | |
| VOLATILE ORGANIC ANALYSIS RESULTS GC/PID ANALYSES USING IVlETHOD 8020 li n m I ID; TRS- A AL ml ID: 1 D II -DE D R iv: 2 -D Date Anal zed: 04-JAN-94 Dilution Factor: 1 Matrix: WATER QC Batch ID: 122093-801020-0-3 Anal tical Batch 4'22093-801020-0-3 rr R vr Q Limi TFT 97 70-120 BFB 75-1 20 Reporting Concentration Detection Limit Data Constituent IL /L Qualifier s Benzene 0.53 0.5 Tiun hl r n n Eth Benzene I
| |
| m -X lene <2
| |
| -X in 1 -Dihl r n n 1 4-Dichlorobenzene 1 2-Dichlorobenzene <2 LOCKHEED ANALYTICALSERVICES 06
| |
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| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 Page 2 of 2 Client Sam le ID: TRS LAL Sam le ID: L1009-41 Reporting Concentration Detection Limit Constituent IL IL Data Qualifier s Dibromochloromethane <5 hlr nzn Eh I nz n m -X lene <5 o-X lene <5 r n Brom f rm 1 1 2 2-Tetrachloroethane <5 1 3-Dichlorobenzene <5 1 4-Di hlor nz n 1 2-Dichlorobenzene <5 LOCKHEED ANALYTICALSERVICES
| |
| | |
| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 TENTATIVELYIDENTIFIED COMPOUNDS Client Sample ID: TRS LAL Sample ID: L1009%1 Date Received: 29-DEC-93 Date Analyzed: 114AM-94 Matrix: WATER Dilution Factor: 1 Analytical Batch: 011094-8260-F2 QC Batch ID: 011094-8260-F2 Estimated Retention Concentration Time Data Tentatively Identified Compound Iyg/L) Iminutes) Qualifierls)
| |
| (10 0.00 LOCKHEED AIVALYTICAL SERVICES
| |
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| |
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| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 TENTATIVELYIDENTIFIED COIVIPOUNDS Client Sample ID: TRS-QA LAL Sample ID: L1009%3 Date Received: 29-DEC-93 Date Analyzed: 114AN-94 Matrix: WATER Dilution Factor: 1 Analytical Batch: 011094-8260-F2 QC Batch ID: 011094-8260-F2 Estimated Retention Concentration Time Data Tentatively Identified Compound Iyg/L) (minutes) Qualifier(s)
| |
| NONE (10 0.00 LOCKHEED ANALYTICAL SERVICES 20
| |
| | |
| SElVllVOLATILEORGANIC ANALYSIS RESULTS FOR GC/MS ANALYSES USING METHOD 8270 P 1 f 2 Iin m I ID: TR LA m I ID: 1 -2 Date Collected: 28-DEC-93 Date Received: 29-DEC-93 Matrix: WATER Dilution Factor: 1 An I i IB h¹: ill 4- 7 -8 D xr 4-AN-4 QC Batch ID: 8270-SEMI VOLATILES-3964 Date Anal zed: 11-JAN-94 SURROGATE REC VERY 0/
| |
| QC Limits 2-Fluoro henol 41 21-100 Phenol-d, 26 10-94 Nitrobenzene-d, 59 35-114 2-FIuorobi hen I 55 43-1 1 6 24 -Tribr m h n I 1 -12 p-Ter phenyl-d,4 99 33-141 Reporting Concentration Detection Limit n i n L L D Q Phenol <10 10 bis 2-Chloroeth I ether <10 10 2- hlr hnl 1 -Di hl r nz n 1 4-Dichlorobenzene <10 10 Benz I alcohol <10 10 1 -Dihl r n n 2M h I h n I bis 2-Chloroiso ro I ether <10 10 4-Meth I henol <10 10 N-Ni r -Di-n- ro I min <10 Hx hlr hn Nitro benzene <10 10 Iso horone <10 10
| |
| -Nir h n I 24Dimeh I h n I <10 Benzoic acid <50 50 bis 2-Chloroethox methane <10 10 4Dihl r hn I 1 4-Tri hl r nz n Na hthalene <10 10 4-Chloroaniline <10 10 Hx hlr in 4- hl r - -m h I h n I 2-Meth Ina hthalene <10 10 Hexachloroc clo entadiene <10 10 LOCKHEED ANALYTICALSERVICES 4v
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| VOLATlLE ORGANIC ANALYSlS RESULTS FOR ANALYSES USING IVIETHOD 8270 TENTATIVELYIDENTIFIED COIVIPOUNDS Client Sample ID: TRS LAL Sample ID: L1009-25 Date Received: 29-DEC-93 Date Analyzed: 11-JAN-94 Matrix: WATER Dilution Factor: 1 Analytical Batch: 011194-8270-B QC Batch ID: 8270-SEIVIIVOLATILES-3964 Estimated Retention Concentration Time Data-Tentatively Identified Compound (yg/L) (minutes l Qualifier(sl Unknown 100 6.44 Unknown 20 30.26 LOCKHEED ANALYTICALSERVICES 31
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| | |
| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8270 TENTATIVELYIDENTIFIED COMPOUNDS Client Sample ID: TRS-QA LAL Sample ID: L1009-27 Date Received: 29-DEC-93 Date Analyzed: 29-DEC-93 Matrix: WATER Dilution Factor: 1 Analytical Batch: 011194-8270-8 QC Batch ID: 8270-SEMIVOLATILES-3964 Estimated Retention Concentration Time Data ..
| |
| Tentatively Identified Compound (yg/L) (minutes) Qualifier(s)
| |
| Unknown 5.28 Unknown 100 6.44 Hydrocarbon 29.97 Unknown 20 30.26 Hydrocarbon 31.98 Hydrocarbon 32.94 Hydrocarbon 33.86 LOCKHEED ANALYTICALSERVICES
| |
| | |
| PESTlclDE ANALYSES RESULTS BY GC/ECD USING METHOD 8080 FOR COOK NUCLEAR PLANT Clien Sam le ID: TR LAL m I ID: I 1 -17 Da e Colle ed: 28-DE -9 Da e Receive:29-JAN- 4 Date Extracted: 04-JAN-94 Date Anal zed: 21-JAN-94 Matrix: WATER Dilution Factor: 1 Anal tical Batch ¹: 012094-8080-A-1 QC Grou ID: 8080 PEST/PCBS 3965 SURROGATE RECOVERY oo TCMX DCB 52'C Umits 60-1 50 60-150 Reporting Constituent Concentration Detection Limit Data Qualifier(s)
| |
| /L /L A-BHC <0.05 0.05 B-BHC 0.
| |
| -BH D-BHC <0.05 0.05 HEPTACHLOR <0.05 0.05 ALDRIN HEPTA HLOR EPOXIDE G-CHLORDANE <0.05 0.05 ENDOSULFAN I <0.05 0.05 A-CHL RDANE . 5 0.
| |
| 4 4'-DDE 4 4'-DDT <0.1 0.1 DIELDRIN < 0.1 0.1 ENDRIN 0.1 ENDOS LFAN II 4 4'-DDD < 0.1 0.1 ENDRIN ALDEHYDE < 0.1 0.1 ENDO LFAN L FATE METHOXYCHLOR <0. 0.
| |
| TOXAPHENE <5 PCB-1016 PCB-1221 PCB-1 2 PCB-1242 PCB-1248-PCB-12 4 PCB-12 0 TECHNICAL CHLORDANE MIREX <0.1 <0.1 TCMX - tetra-chloro-meta-xylene DCB - Deca-chloro-biphenyl LOCKHEED ANALYTICALSERVICES 5'
| |
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| |
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| |
| ~ gpss ~ ~ ~ ~ ' ~
| |
| ~ %% I ~ ~ ~ ~ ~ '' ~ ~
| |
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| |
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| |
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| |
| | |
| METALS RESULTS Client Sam le'ID!'TRS-QA Date. Collected: 12-28-93 Matrix:, round;water.
| |
| '0 LAL Batch ID(s): 1220 im Date Received: 12-29-93 469095-040-3N
| |
| . <<?,
| |
| ')'y Reeportlng Concentration" Detection" Umlt Data~ Date'.~ ?0 ':;;:;.
| |
| L'ALcr.
| |
| Co'nstitu ants -."Method im ILl lm ILl QualWer(s) '-A'nal ed,N ""S" le'1D )
| |
| Aluminum 6010 <0.20 0.20 01-20-94 L1009-14 Antimon 6020 <0.060 0.060 01-27-94 L1009-14 Arsenic 6020 <0.010 0.010 01-27-94 L1009-14 Barium 6020 <0.20 0.20 N 01-27-94 L1009-14 Be ilium 6020 <0.005 0.005 01-27-94 L1009-14 Boron 6010 0.27 0.20 01-20-94 L1009-14 Cadmium 6020 <0.005 0.005 01-27-94 L1009-14 Chromium 6020 <0.010 0.010 01-27-94 L1009-14 Cobalt 6020 <0.050 0.050 01-27-94 L1009-14 Co er 6020 <0.025 0.025 01-27-94 L1009-14 Iron 6010 <0.10 0.10 01-20-94 L1009-14 Lead 6020 <0.003 0.003 01-27-94 L1009-14 Ma nesium 6010 17 5.0 01-20-94 L1009-14 Man anese 6020 0.027 0.015 01-27-94 L1 009-14 Mercu 7470 <0.0002 0.0002 01-07-94 L1009-14 Mol bdenum 6020 <0.20 0.20 01-27-94 L1009-14 Nickel 6020 <0.040 0.040 01-27-94 L1009-14 Selenium 6020 0.0078 0.005 N 01-27-94 L1009-14 Silver 6020 <0.010 0.010 01-27-94 L1009-14 Sodium 6010 890 5.0 01-20-94 L1 009-14 Thallium 6020 <0.010 0.010 01-27-94 L1009-14 Tin 6020 <0.20 0.20 01-27-94 L1009-14 Titanium 6010 <0.10 0.10 01-20-94 L1009-14 Vanadium 6010 <0.050 0.050 01-20-94 L1009-14 Zinc 6020 0.022 0.020 01-27-94 L1009-14 Comments:
| |
| LOCKHEED ANALYTICALSERVICES
| |
| | |
| 0
| |
| ~ .. ~: - ~ ~ ~ ~
| |
| ~
| |
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| |
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| |
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| |
| | |
| GENERAL CHEMISTRY RESULTS Client Sam le ID: TRS-QA Date Collected: 12-28-93 Matrix: round water LAL Batch ID(s): 1229 im Date Received: 12-29-93 PO¹69095-040-3N Reporting Data Date LAL Constituent Method Result Detection Limit Qualifieris) Anal zed, Sam le ID Fluoride. in m IL 340.2 0.31 0.15 01-24-94 L1 009-2 Chloride. in m /L 300.0 20 0.01 6 1 2-29-93 L1 009-2 Nitrate-Nitro en, in m /L 300.0 0.90 0.01 7 1 2-29-93 L1 009-2 Nitrite-Nitro en, in m IL 300.0 <0.012 0.01 2 1 2-29-93 L1 009-2 Sulfate. in m /L 300.0 2200 0.59 D(1:10) 12-29-93 L1 009-2 Ammonia. Nitrogen, 350. 1 3.4 0.050 01-05-94 L1 009-6 him IL Total Cyanide. in mg/L 335.2 < 0.020 0.020 01-03-94 L1009-10 Comments:
| |
| LOCKHEED ANALYTICALSERVICES 66
| |
| | |
| GENERAL CHEMISTRY QC DATA
| |
| | |
| ==SUMMARY==
| |
| | |
| LAL Batch}D(s}: 1229 im QC'Sam le Anal ses-Matrix" Duplicate Spike.
| |
| Client LAL Date Reagent Precision Recovery Constituent Sample, Sample Analyzed Blank (% RPD} (%}
| |
| ID ID Fluoride, in m /L TRS L1 009-1 01-24-94 < 0.1 5 107 Chloride, in mg/L TRS L1 009-1 1 2-29-93 < 0.01 6 0.2 91 Nitrate-Nitrogen, TRS L1 009-1 1 2-29-93 < 0.017 93 in m /L Nitrite-Nitro en, in m /L TRS L1 009-1 1 2-29-93 < 0.01 2 96 Sulfate, in m /L TRS L1 009-1 1 2-29-93 < 0.059 0.1 96 Ammonia-Nitrogen, TRS L1 009-5 01-05-94 < 0.050 122 in m /L Total Cyanide, in mg/L TRS L1 009-9 01-03-94 < 0.020 94 N lt b The RPD cannot be c'omputed. because the sample or the duplicate concentration was below the Detection Limit.
| |
| Comments:
| |
| LOCKHEED ANALYTICALSERVICES 6n
| |
| | |
| .". Halliburton
| |
| ++ 0 0 R AT I NUS 0 N NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbeiis Run Road Pittsburgh, Pennsylvania 15205 X5FJ C R P (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Report No.: 00018939 Section A Page I LABORATORY ANALYSIS REPORT CLIENT NAME: INDIANA MICHIGAN POWER COMPANY HUS CLIENT NO: 0663 0020 ADDRESS: OHE COOK PLACE WORK ORDER NO: 55830 BRIDGMAN, MI 49106-0000 VEHDOR NO: 05411000 ATTENTIOH: MS. JEHI LEWIS - CHEMISTRY DEPT.
| |
| Carbon Copy:
| |
| SAMPLE ID: TURBIHE ROOM SUMP 27476 DATE SAMPLED: 30-DEC-93 HUS SAMPLE NO: P0259284 DATE RECEIVED: 05-JAN-94 P.O. NO.: 69034-040-3H APPROVED BY: Kieda, Chuck TEST LN CODE DETERMIHATIOH RESULT UNIT 1 1730 Sulfate, Turbidimetric (as S04) 51 mg/L 2 AHAW Sodilsllt Total (Na) 6.3 mg/L 3 1130 Chloride (as Cl) 11 mg/L 4 1590 Solids, Dissolved at 180C 140 mg/L 5 AALW Atuminun, Total (Al) 0.97 mg/L COMMENTS:
| |
| | |
| A NUS LABORATORY
| |
| ;"'; Halliburton CORPORATION NUS Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Report Ho.: 00018939 Section A Page 2 LABORATORY ANALYSIS REPORT CLIENT NAME: INDIANA MICHIGAN POWER COMPANY HUS CLIENT HO: 0663 0020 ADDRESS: ONE COOK PLACE WORK ORDER NO: 55830 BRIDGMAN, MI 49106 0000 VEHDOR HO: 05411000 ATTENTION: MS. JENI LEWIS - CHEMISTRY DEPT.
| |
| Carbon Copy:
| |
| SAMPLE ID: TURBINE ROOM SUMP 27476 / FILTERED DATE SAMPLED: 30 DEC-93 NUS SAMPLE NO: P0259285 DATE RECEIVED: 05'JAN-94 P.O. NO.: 69034-040-3N APPROVED BY: Kieda, Chuck TEST LN CODE OETERMI HAT ION RESULT UNITS 1 AALF Atuainua, Dissolved (At) ~ 0.3 mg/L COMMENTS:.
| |
| | |
| NUS LABORATORY L'Hallibullton NUS
| |
| ++++ C 0 R Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road
| |
| %1K P 0 R AT I 0 N Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Repor t No.: 00018939 Section A Page 3 LABORATORY ANALYSIS REPORT CLIENT HAME: INDIANA MICHIGAN POWER COMPANY NUS CLIENT NO: 0663 0020 ADDRESS: ONE COOK PLACE WORK ORDER HO: 55830 BRIDGMAH, MI 49106-0000 VENDOR HO: 05411000 ATTENTION: MS. JEHI LEWIS - CHEMISTRY DEPT.
| |
| Carbon Copy:
| |
| SAMPLE ID: TURBINE ROOM SUMP 27503 DATE SAMPLED: 31-DEC-93 NUS SAMPLE NO: P0259286 DATE RECEIVED: 05-JAN-94 P.O. HO.: 69034-040-3N APPROVED BY: Kieda, Chuck TEST LH CODE DETERMINATION RESULT UH ITS 1 I 730 Sulfate, Turbidimetric (as SO4) 53 mg/L 2 ANAW Sodiun, Total (Ha) 6.0 mg/L 3 1130 Chloride (as Cl) 10 mg/L 4 I 590 Solids, Dissolved at 180C 130 mg/L 5 AALW Atuminun, Total (Al) 0.98 mg/L COMMENTS:
| |
| | |
| "'. Halhburton
| |
| +++ C 0 R P 0 AT 0 R
| |
| NUS I N NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 imper (412) 747-2580 FAX: (412) 747-2684
| |
| ,January 18, 1994 Report No.: 00018939 Section A Page 4 LABORATORY ANALYSIS REPORT CLIENT NAME: INDIANA MICHIGAN POWER COMPANY NUS CLIENT NO: 0663 0020 ADDRESS: ONE COOK PLACE WORK ORDER HO: 55830 BRIDGMAH, MI 49106-0000 VEHDOR NO: 05411000 ATTENTIOH: MS. JEHI LEWIS - CHEMISTRY DEPT.
| |
| Carbon Copy:
| |
| SAMPLE ID: TURBINE ROOM SUMP 27503 / FILTERED DATE SAMPLED: 31-DEC.93 HUS SAMPLE HO P0259287 DATE RECEIVED: 05-JAN-94 P.O. NO.: 69034-040-3N APPROVED BY: Kieda, Chuck TEST LN CODE DETERMI HAT ION RESULT UHI TS 1 AALF Aluninun, Dissolved (AI) 0.3 mg/L COMMEHTSt
| |
| | |
| "NUS LABORATORY
| |
| :dL'Halliburton waar NUS Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road C 0 R P 0 R AT I 0 N Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Report Ho.: 00018939 Section A Page 5 LABORATORY ANALYSIS REPORT CLIENT NAME: INDIANA MICHIGAN POWER COMPANY HUS CLIENT HO: 0663 0020 ADDRESS: ONE COOK PLACE WORK ORDER HO: 55830 BRIDGMAH, MI 49106-0000 VENDOR NO: 05411000 ATTENTION: MS. JEHI LEWIS - CHEMISTRY DEPT.
| |
| Carbon Copy:
| |
| SAMPLE ID: TURBINE ROOM SUMP 27506 DATE SAMPLED: 01-JAH-94 HUS SAMPLE HO: P0259288 DATE RECEIVED: 05-JAH 94 P.O. NO.: 69034-040-3N APPROVED BY: Kieda, Chuck TEST LN CODE DETERMIHATI ON RESULT UNITS 1 l 730 Sulfate, Turbidimetric (as S04) 52 mg/L 2 AHA'W Sodiun, Total (Na) 5.6 mg/L 3 1130 Chloride (as Cl) 10 mg/L 4 l590 Solids, Dissolved at 180C 130 mg/L 5 AALW Atuninua, Total (Al) 1.6 mg/L COMMENTS:
| |
| | |
| NUS LABORATORY h: HallibulIton NUS
| |
| +++ C 0 R Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road
| |
| >mrs P 0 R AT I 0 N Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Report Ho.: 00018939 Section A Page 6 LABORATORY ANALYSIS REPORT CLIENT NAME: INDIANA MICHIGAN POWER COMPANY HUS CLIENT NO: 0663 0020 ADDRESS: ONE COOK PLACE WORK ORDER HO: 55830 BRIDGMAN, MI 49106-0000 VEHDOR NO: 05411000 ATTEHTIOH: MS. JEHI LEWIS - CHEMISTRY DEPT.
| |
| Carbon Copy:
| |
| SAMPLE ID: TRUBINE ROOM SUMP 27506 / FILTERED DATE SAMPLED: 01- JAN-94 HUS SAMPLE HO: P0259289 DATE RECEIVED: 05-JAH 94 P.O. NO.: 69034-040-3N APPROVED BY: Kieda, Chuck TEST LN CODE DETERMINATION RESULT UNITS 1 AALF Atuntram, Dissolved (At) 0.2 mg/L CNNENTS:
| |
| | |
| '. Halliburton CORPORATION NUS NUS LA8ORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205
| |
| ~%F1 (412) 747-2580 FAX: (412) 747-2684.
| |
| January 1B, 1994 Report No.: 0001B939 Section A Page 7 LABORATORY ANALYSIS REPORT CLIENT NAME: IHDIANA MICHIGAN POWER COMPANY HUS CLIENT HO: 0663 0020 ADDRESS: ONE COOK PLACE WORK ORDER NO: 55030 BRIDGMAN, Ml 49106-0000 VENDOR NO: 05411000 ATTENTION: MS. JENI LEWIS - CHEMISTRY DEPT.
| |
| Carbon Copy:
| |
| SAMPLE ID: TURBINE ROOM SUMP 27509 DATE SAMPLED: 02-JAH 94 HUS SAMPLE HO: P0259290 DATE RECEIVED: 05-JAH-94 P.O. HO.: 69034-040.3N APPROVED BY: Kieda, Chuck TEST I LN CODE DETERMI NAT ION RESULT UNITS 1 1730 Sulfate, Turbidimetric (as SO4) 51 mg/L 2 AHAW Sodiun, Total (Ha) 5.9 mg/L 3 1130 Chloride (as Cl) 10 mg/L 4 l 590 Solids, Dissolved at 1BDC 140 mg/L 5 AALW Atuninun, Total (Al) 1.5 mg/L 6 I490 pH 7.6 7 l 700 Specific Conductance at 25C 300 umh os/cm COMMENTS:
| |
| | |
| ++
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| '. HalliburtonA TNUS NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road C 0 R P 0 R I 0 N Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Report No.: 00018939 Section A Page 8 LABORATORY ANALYSIS REPORT CLIENT NAME: INDIANA MICHIGAN POWER COMPANY HUS CLIENT NO: 0663 0020 ADDRESS: OHE COOK PLACE WORK ORDER No: 55830 BRIDGMAN, Ml 49106-0000 VEHDOR HO: 05411000 ATTENTION: MS. JENI LEWIS - CHEMISTRY DEPT ~
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| Carbon Copy:
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| SAMPLE 10: TURBINE ROOM SUMP 27509 / FILTERED DATE SAMPLED: 02-JAH-94 HUS SAMPLE NO: P0259291 DATE RECEIVED: 05-JAH-94 P.O. NO.: 69034 040 3H APPROVED BY: Kieda, Chuck TEST LH CODE DETERMINATIOH RESULT UNITS 1 AALF Atuninun, Dissolved (At) 0.3 mg/L COMMENTS:
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| " Halliburton NUS
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| +++ C 0 R NUS LABORATORY Two Marquis Office Plea, Suite 200 5313 CampbeHs Run Road
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| %1 18 P 0 R AT I 0 N Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Repor t No.: 00018939 Section A Page 9 LABORATORY ANALYSIS REPORT CLIENT NAME: INDIANA MICHIGAN POWER COMPANY HUS CLIENT NO: 0663 0020 ADDRESS: ONE COOK PLACE WORK ORDER HO: 55830 BRIDGMAHt MI 49106 0000 VENDOR HO: 05411000 ATTENTIOH: MS. JEHI LEWIS - CHEMISTRY DEPT.
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| Carbon Copy:
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| SAMPLE ID: ABS POND CCMP. DATE SAMPLED: 31.DEC.93 HUS SAMPLE NO: P0259292 DATE RECEIVED: 05-JAH 94 P.O. NO.: 69034-040-3N APPROVED BY: Kieda, Chuck TEST LN CODE DETERMINATION RESULT UNITS 1 I 730 Sulfate, Turbidimetric (as S04) 110 mg/L 2 ANA'W Sodiua, Total (Na) 28 mg/L 3 1130 Chloride (as Cl) 9 mg/L 4 1590 Solids, Dissolved at 180C 210 mg/L 5 AALW Atuainua, Total (Al) 0.33 mg/L COMMENTS:
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| NUS LABORATORY
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| .4i. Halliburton
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| %1K'++ C 0 R P 0 R AT I 0 N NUS Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pit tsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Report No.: 00018939 Section A Page 10 LABORATORY ANALYSIS REPORT CLIENT NAME: INDIANA MICHIGAN POWER COMPAHY NUS CLIENT Ho: 0663 0020 ADDRESS: OHE COOK PLACE WORK ORDER HO: 55B30 BRIDGMAN, MI 49106-0000 VEHDOR NO: 05411000 ATTEHTIOH: MS. JEHI LEWIS - CHEMISTRY DEPT.
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| Carbon Copy:
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| SAMPLE ID: ABS POND COMP. / FILTERED DATE SAMPLED: 31-DEC-93 NUS SAMPLE HO: F0259293 DATE RECEIVED: 05-JAN.94 P.O. HO.: 69034-040-3H APPROVED BY: Kieda, Chuck TEST LN CODE DETERMI HAT ION RESULT UNITS 1 AALF Atuninua, Dissolved (At) 0.099 mg/L COIMEHTS:
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| '. Halliburton 0 0 A I0 R T NUS N
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| NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road
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| +~~~~ C R P Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (4'12) 747-2684 January 18, 1994 Report No.: 00018939 Section A Page 11 LABORATORY ANALYSIS REPORT CLIENT HAME: INDIANA MICHIGAN PSlER COMPAHY NUS CLIENT HO: 0663 0020 ADDRESS: OHE COOK PLACE 'IQRK ORDER NO: 55830 BRIDGMAH, Ml 49106-0000 VEHDOR HO: 05411000 ATTENTIOH: MS. JEHI LE'LIIS - CHEMISTRY DEPT.
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| Carbon Copy:
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| SAMPLE ID: ABS POND COMP ~ DATE SAMPLEDI 01.JAN.94 HUS SAMPLE NO: P0259294 DATE RECEIVED: 05-JAN.94 P.O. HO.: 69034-040-3N APPROVED BY: Kieda, Chuck TEST LN CODE DETERMINATION RESULT UNITS 1 l730 Sulfate, Turbidimetric (as S04) 110 my/L 2 ANAII Sodiun, Total (Ha) 30 my/L 3 1130 Chloride (as Ct) 10 my/L 4 l590 Solids, Dissolved at 180C 210 mg/L 5 AALU Atuninun, Total (At) 0.35 my/L CCMHENTS:
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| .". Halliburton
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| ~i@'++ C 0 R P 0 R AT I NUS 0 N NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Report No.: 00018939 Section A Page 12 LABORATORY ANALYSIS REPORT CLIENT NAME: INDIANA MICHIGAN POWER COMPANY NUS CLIENT HO: 0663 0020 ADDRESS: ONE COOK PLACE WORK ORDER NO: 55830 BRIOGMAN, MI 49106-0000 VEHDOR NO: 05411000 ATTENTION: MS. JENI LEWIS - CHEMISTRY DEPT.
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| Carbon Copy:
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| SAMPLE ID: ABS POND COMP. / FILTERED DATE SAMPLED: 01-JAN 94 NUS SAMPLE HO: P0259295 DATE RECEIVED: 05-JAN.94 P.O. NO.: 69034-040-3N APPROVED BY: Kieda, Chuck TEST LH CODE DETERMINATION RESULT UNITS 1 AALF Atuninua, Dissolved (At). 0.10 my/L CINMEHTSt
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| '. Halliburton NUS
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| +++~ 0 R P 0 AR TI 0 N NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road
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| ~%fE C Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Report Ho.: 00018939 Section A Page 13 LABORATORY ANALYSIS REPORT CLIENT NAME: INDIANA MICHIGAN POWER COMPANY NUS CLIEHT NO: 0663 0020 ADDRESS: ONE COOK PLACE WORK ORDER HO: 55830 BRIDGMAN, MI 49106-0000 VEHDOR HO: 05411000 ATTENTION: MS. JENI LE'WIS - CNEMISTRY DEPT.
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| Carbon Copy:
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| SAMPLE ID: ABS POND COMP. DATE SAMPLED: 02-JAN.94 HUS SAMPLE HO: P0259296 DATE RECEIVED: 05 JAH 94 P.O. NO.: 69034-040-3H APPROVED BY: Kieda, Chuck TEST LH CODE DETERMIHATION RESULT UNITS
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| 'I I730 Sulfate, Turbidimetric (as SO4) 100 mg/L 2 ANAW Sodiun, Total (Na) 31 mg/L 3 I130 Chloride (as Cl) 10 mg/L 4 I 590 Solids, Dissolved at 180C 190 mg/L 5 AALW Atuslnua, Total (Al) 0.5 mg/L 6 I 700 Specific Conductance at 25C 400 thos/cm COMMENTS:
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| ""Halliburton NUS NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road
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| %1gJ'+ C 0 R P 0 R AT I 0 N Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 1B, 1994 Report Ho.: 0001B939 Section A Page 14 LABORATORY ANALYSIS REPORT CLIENT NAME: INDIANA MICHIGAN POWER COMPANY NUS CLIENT HO: 0663 0020 ADDRESS: OHE COOK PLACE WORK ORDER NO: 55B30 BRIDGMAH, Ml 49106-0000 VENDOR NO: 05411000 ATTEHTIOH: Ms. JEHI LEWIS - CHEMISTRY DEPT.
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| Carbon Copy:
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| SAMPLE ID: ABS POND COMP. / FILTERED DATE SAMPLED: 02-JAH-94 NUS SAMPLE HO: P0259297 DATE RECEIVED: 05 JAN 94 P.O. NO.: 69034.040-3H APPROVED BY: Kieda, Chuck TEST LH CODE DETERMI HAT ION RESULT UNITS 1 AALF Aluainun, Dissolved iAI) 0.072 mg/L COMMENTS:
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| NUS LABORATORY
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| "'alliburton
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| ~lP'~>~CORPORATION NUS Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road Pittsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Report No.: 00018939 Section A Page 15 LABORATORY ANALYSIS REPORT CLIENT NAHE: INDIANA MICHIGAN POWER COMPANY HUS CLIENT NO: 0663 0020 ADDRESS: OHE COOK PLACE WORK ORDER NO: 55830 BRIDGHAH, Nl 49106-0000 VEHDOR NO: 05411000 ATTENTION: NS. JEHI LEWIS - CHEMISTRY DEPT.
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| Carbon Copy:
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| SAMPLE ID: ABS POND COMP 66998 DATE SAHPLED: 03-JAM-94 NUS SAMPLE NO: P0259298 DATE RECEIVED: 05-JAH.94 P.O. NO.: 69034-040-3H APPROVED BY: Kieda, Chuck TEST LN CODE DETERNINATIOM RESULT UNITS 1 1730 Sulfate, Turbidimetric (as SO4) 110 mg/L 2 AMAW Sodius, Total (Ha) 28 mg/L 3 I130, Chloride (as Cl) 10 mg/L 4 1590 Solids, Dissolved at 180C 190 mg/L 5 AALW Atuainua, Total (Al) 0.5 mg/L 8 l 700 Specific Cohductance at 25C 410 moos/cm COMMENTS:
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| I++ Halliburton NUS NUS LABORATORY Two Marquis Office Plaza, Suite 200 5313 Campbells Run Road
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| %%TE C 0 R P 0 R AT I 0 N Pit tsburgh, Pennsylvania 15205 (412) 747-2580 FAX: (412) 747-2684 January 18, 1994 Report No.: 00018939 Section A Page 16 LABORATORY ANALYSIS REPORT CLIENT NANE: INDIANA HICHIGAN POWER COHPAHY NUS CLIENT NO: 0663 0020 ADDRESS: ONE COOK PLACE WORK ORDER HO: 55830 BRIDGHAN, HI 49106-0000 VENDOR NO: 054'11000 ATTENTION: HS. JEHI LEWIS - CHEHISTRY DEPT.
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| Carbon Copy:
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| SAMPLE ID: ABS POND COHP 66998 / FILTERED DATE SANPLEDI 03-JAH-94 HUS SANPLE HO: P0259299 DATE RECEIVED: 05 JAN-94 P.O. HO : 69034-040-3H APPROVED BY: Kieda, Chuck TEST LH CODE DETERNI NAT ION RESULT UNITS 1 AALF Aluninun, Dissolved (At) 0.088 mg/L COHNEHTSr
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| SECTION II PERMIT~ MI 0005827 SEE INSTRUCTIONS ON REVERSE SIDE
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| ~OO E EM Ae LOCATION OF DISCHLRGE ~SW t ~SEJ i, SOI0I i~06. \I ~06 5, SSE ~19 W S, ~
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| WA RECEIVIIO HATER (IE. GAOWDQTER CR N4% OF MLFACE SA NI TAR 2t'BS PON D.
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| CI DO YOU Dl SOLLRGE SEASCNALLY DISCHARGE (IF IOJ CONTIIAK IO EI LOCATION De IF YESa LIST DISONKE PERIODS M)o / DLY Ion / DAY SCHEDULE FLOW
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| ~u ~
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| RATE WASTEWATER JXBKSiQQE EI IhtD APPLI CATION RATE, NA INI/Hle
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| ~
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| HIe/DAY
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| ~ u ~.'W IH,/NN.
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| 0 w u
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| )IF'4 1 CONTACT COOUNQ Fo TYPE OF HASIBGLTER DISCHLKE
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| ~~ LJ 2 NONCONTRCT COOLWQ Go DISCNRK SOERLE (YE/RLY AVER/GE)
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| - NOLNS/DAY ~4 equi~
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| ase on a 3
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| 4 PROCESS SANITARY H, DISCHHLGEFUSIRATE arne TOTAL YEARLY 13 505 5 STORM WATER DAILY HINIISSI 0 2 llHUUcQDE DAILY ILLXWPI 037 2 1
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| 2 MQY MQD I I TIE $ 0(DSII DISCHVSIE FUSI RATE TO SE AUllERIZED IH PEBIITe o. o6o 3 QPD Jo Ao HAXDQI DESIQI DL5CNAX FIDI RATEe IEI YOLI USE HATER TREAIIRNT AIDITIVES 1D TREAT YOIR DESIGN o.o6o DISCNK4.
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| (IF HG. ccNTDAE To ITBI 3)
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| [TEN Se NIK FBCTICNp 110 OKNCAL CStOSITIlS OF lfC5E AISIITIVB4 Calcium leH ochlorite for GtKZJQL.
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| TREATMENT ADDITIVES Ca WIC AMI ACCRESS OF IWAFACARERS CF TMSE AISITIVESP VAN WATERS AND ROGERS, INC.
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| 1 MQ/I 1600 NORTON BUILDING SEATTLE, WASHINGTON 98104-156
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| ~
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| 2 UQ/I
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| ~
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| HIHIISPI WITS
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| ~0 De EXPKIED D ISCHLRK CBCEHIRATICN OF AIDITIVES a AVIRAGE LNITS HAXIISSI WITS aEE ~
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| QXE ~
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| axK sane we* Total Residual Chlorine 0 LJ, 0 ~,
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| ACDITIYE wte LJi ADDITIVE HL/K LJ J M3 LJ Ea DO 511 TlKIT 1% DINAR TO RBOltE AISIITIVEST Fs Y6IAT IS TIE RBIVAL EFFICIBCY Ale DISTR% FRBSESCY2 I RBBVAL INSo/DAY DLYS/W.,
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| ACOITIVE VIE LJ G, AS AN ATTAOPEIIT TO THIS APPLICATICN PRESIDE SPECIFIC HJtNALIAH CR AQILTIC TOXICDUDICAL DLTA CR RERREHCE NHICH ARE AVAIIAILEAHD l%TSPLATIBI CN TIE RATE OF DEWADATICH OF TIE PIEXICTS RSI EKH ACOITIVEi b1SDS Attached Calcium Hypochlorite is added to the mixed liquor and is used up prior to discharge.
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| INSTRUCTIONS FOR COCPLETING SECTIOI II ITEMS I ANO 2 This fom requires Information on the facility's dlscnarge location, discharge scnedule, volume flow rate and voter treatment additives .
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| ENTER THE PERMIT IAP(B\R IN THE BOX AT THE TOP OF THIS FCIOI. THE PERMIT NIP(BER CAM BE FOUNO OM THE FRONT PAGE OF YCUR EXPIRING PERMIT. If this Is a ne>> or not previously permitted facility, then leave blank end s number will be assigned.
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| Enter tne outfall ncxxaar In space provided for escn page of section II. For coon Individual discharge point a separate set of Section li forms must be filled Out.
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| ITEM I DISCHARGE LOCATION SCHEOULE A%) FLOH RATES A. Enter the location of dlscnorga, this should Include quarter-quarter section, quarter section, section, town, snd range.
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| B. List name of receiving voter (lf surface water discharge).
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| C. Indicate vnether (scil)ty discharges on a seasonal basis.
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| O. If yes. list discharge periods.
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| E. Provide 'the land appl)cation rates used or expected to be used in terms of Inches per hour, hours per doy, snd Inches per week.
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| Indicate the type of wastewater to be discharged from this outfall. Refer to the rostevoter type code given In the lett margin. More thsn one code moy be applicable.
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| G. Provide the average nurser of hours per dov In which the facility discharges treated wastewater ond the total number of days per year in vnlch tha dlscnsrge occurs.
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| H. Provide current (fram the lost l2 months) or expected flow rates ss requested. Refer to unit code divan In the left margin for the appropriate flow units. HGY - million gallons per year) MGO - million gallons par day) GPO - gallons per dsy.
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| I. Provide tne maximum discharge flow rate which you rent to have authorized within the permit. N0TE: For NPOES permits onlY.
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| the use of such a flow rate vill not place an actual limit restriction on the flow but vill be the flow rote used to develop effluent limits. Also, >>nen the Monthly Operating Reports are reviewed by Ccmpllance staff It vill help thea to determine if any nev or increased uses might have occurred at the facility.
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| J . Provide the design flow for this specific outfall discharge (e.g. batch treatment system flow~ packaged treatment system flow.
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| or sane other finite treatment system flow),
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| ITEN 1 vATER TREATMENT AOOIT IVES A. Indicate vnether dlscnsrge Is treated with conditioners, inhibitors, oc microbiocide. If not, continue to Item 3.
| |
| B. Give name. function, and chemical composition of additives used.
| |
| C. Give name and address of the manufacturer(s) of the additives used.
| |
| O. Indicate expected mlnlmcxe, average and max)meso discharge ccncantratlons of the additive(s) for this discharge ~
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| E. Indicate wnetner you treat the dischorge to remove the sddltlvelsl before discharge of wastewater.
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| F~ Indlcote the reaovsl efficiency of each additive fran the vastevatec'nd the discharge frequency of each additive to the surface voter or groundvater.
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| G. N0TE: lt Is the responsibility of the applicant to supply the product Information ss requested In this Iten s. Information requested but not supplied may result In the application being returned to the sap)Ident for canpletlon.
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| 32
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| REPORT '"JLJHBF R '7'J VAH MATER.'> i~ ROGERS I i(C . PAGE: 00 %
| |
| i IS DS i'iQ: PG03 J.O SA I.EI< I Al S!~r- E T Y DA TA S>HEF T
| |
| ~ =" ECTIVE '!ATE: OF /2" /93 VERS IOH: 00~)
| |
| .>6 DIJ(. s '. r',,Al C IUi'( HY POCi~ll 0 R X TE 6 I<AHIJI !4 lk (3 R DER NO:
| |
| P R(3I3 HQ vAN WATI".RS i".> 3. 00 CAR II h ROGERS L(3H P(3 IiHT X HC ., KX RKLAHD I
| |
| SLJ BSX D A RY QF LING VAR < 206 889-.i400 WA 98033 Ei(E RGEHCY AS>8 X 8> TAHCE I'3 R Ei(E RGENCY AS, T STAHCE X O'VOLV X HG CIHFiR ICAL S CAI L (".HEI'lTREC
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| < 800 > 42>4-9300 I= O R V IC Q (3 IJ CT A H I3 S!'. I E S:r. H F O R N A T I (3 H CONTACT YOLJR LOCA(.. VAN WATERS b, ROGER.> BRANCH OFF ICE AT VWhlk SOUTI(. I3EHI3 ~'L9-'i89-03~ 1 ~OUTH P - Hll IH P RQ I3LJCT NAIVE:
| |
| CALC ILJH HYPOCI II OR I TE 6 RAHLJI A R H. i!8 >
| |
| '"r:: P G 0:3 1. 0 C Al C I UH i-I Y P 0 C I-I l. Q R X T E 6 R A HULA R l)A>E:
| |
| I r'' D T X (3 N:
| |
| '~~0/
| |
| now
| |
| 'l 93 1'A DE HARE: CALC IL)i( HY POCHLO R I TE (i RA)'IL)L A i<
| |
| i.,'l-IC i I i-r I'i i i E / 8 YN: CAL l-IYP 3, P T T'i Cl..(3 R, .".Hll(JCLO R, RE PA K, .:A P P XT C IIEIIXCAL FAHIL Y: I-IYPOCI-ILO R X TE F(3 f~iilJLA: !:A < (3CI.. > 2 CAB HLJH BE R: -
| |
| 0 0 7 7 7 8 5 4 -'
| |
| IJ, 8 ~ DOT SHI P P I HG HAHE: CALC I UH HY PQCI-ILO R I TE, HY D RATE D IJ S DOT HAZARD Cl.ASS: .'r, J. < OX X D XZER >
| |
| /
| |
| ~ ~
| |
| "-; IJ I ) S T. i3 I A R Y R I 8 K: i'I A I . n . N LJ V J3 R: I=. LJN2880 A("., I< IH(3 8> ROlJ P:
| |
| :.~Q R TA Ill'= QI JAH T T T I;Hf) DESCRI P T I QH:
| |
| Y::L XX 0 L I38/4 - l<6 ~
| |
| CAL.C ILIA i I Y PQCHLOR X TE, HYDRATED, CLASS ' 3., UH2880, PA(. i< ''".I'IG> 8 RQIJP I I, RA, X HOG (;Q l3E PAGI= .r l 38 ~
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| I'-'.E"">r'". I'LJHI3FR: 97 J VAH MATERS 6 ROGERS XHC. PAGE: 002.
| |
| "'-:I;.'i 'I:): P60310 is>>TI:RXAI SAr-ETY I3ArA Sl-IELT
| |
| "-'Fr EC! ". VE .".)ATE: ()b/23./93 VERSXOH: 004 CALC IUD HY P(3CI-IL(3 RITE G L'r RAHLJLAR ORDER HO:
| |
| PROD HQ SECTXQH 1. PflYSXCAI... DATA 3(31I...XHR P(3XHT 6 7i~>0 AN I-l(3: DEC(3VPQSES e zen C POR DENSITY (AXR=-J.): N/A
| |
| ')PECIFXC GRAVITY (H2O=X ): H/A
| |
| 'PH rJF SQI IJTXQHS: ALKALINE FREEZXH(3/HFLTXHG POIHT: H/A Br)LUBXLXTY ( AEXGf!T % ):H MATE(2 G/L e 2r C
| |
| !3EH DI i 65-~>7 i.BS/(3U . FT .
| |
| % VOI..ATX l
| |
| '('OLL)HE E: H/A VAPOR '(>RESSlJRE: H/A EVAPORATION RASE: N/A I.IEAT OF S(3I IJTXON: SLXGHTI..Y EXOTHERHXC APPEARANCE AHD ODOR:
| |
| WHXTE P(3WI3ER WXTH Sl XGHT CI.ILO R I NE 0 DO R SEC; I(3H;" INGREDIENTS
| |
| :.RXAI PERCENT CA( (3IUiI JJYP()(.",HI QRITE < ~~5% AVAXI A8l E CHLORINE> 65 IIERT <XHCLUDES 5..> 1.0% HQXSTURF) 3iJ SECTXQH 3 FIRE/EXPLOSXOH HAZARD DATA
| |
| ;>I"I l>(3XHT (I";ETH(3D IJSI=D >:
| |
| Ni",) id I ".
| |
| FI..AIIHAI)I..E LXHITS XH AXR (% BY VOLUHE)
| |
| '.'=l..: -
| |
| iH/A J JEI,..: N/A
| |
| ""'T'lO>LJXSI-IXH(."-. I(I=DIA; MATFR ONLY! SilOTHERING XHEFFECTXVE-PRODUCT SUPPLIES OWN QXYGEH
| |
| '~Fr:,-'.I.. F .. RE I IGHTIHG PROCEDURES:
| |
| RE FIGHTI.-",iRS JUST WEi'iP. HXOSII/IISIIA APPROVI':D, PRESSLJRE [)EJ'IAND SEl F-CQHTAIHED I I I R A I I'I H(r A P PA I'FLATUS VJ TH FLJLL FA("E P ECE F(3 R I I OSS I BLE LX PQSU Rl'" TQ i iAZ'.IRDOUG GAS>ES, r'- Pr=.;;.,HI3 E:< PLOS ION '<AZ>-'> P. I3$ :
| |
| !I r)SE'> !""s l' G>0 !s ! >." i '>&XI!IL') i JX i GI H GAS>! CQII1 ! 13 Hlr R > > IH '( tcL>( TURL ~
| |
| | |
| RFP!.) I>7 ';IUilBER: 771 )AH WA7ERS 6 ROBE!RS 3:HC PAGE: 003 HA 'r-031.0 i:iATERXAI. SAr-iETV DATA SHI.=I.=,
| |
| i" FFr" r 7 .'iF )ATE 'r>>/21/r! 3 Vt;RSXOH: 00<
| |
| ~
| |
| ,.rl)~rr r i CAI. CXLJH IHVI'()CI<L(3RXTE GRAHULAIE ORt)ER No:
| |
| PROD NO SECT X(3H ~) IIFAI Tl-I HAZARD DATA TOXIC:t TV DATA:
| |
| LC.:r0 XHHALATXOiN: (RAT) HQ HQRTAI ITY 8 3 ~ r HG/I ('J. HR)
| |
| L}350 DERHAL: ( RABB:tT) > 1000 il6/l<6 S)KTH/EYE IRRTTATXOH: B)EE S)ECTXOH 5 l,.t)50 'f.NGEBT't(3N: SEE SECT ION 5)
| |
| FIB}I,LC50 (l ETIIAL CoiHCFHTRAT3:ON ): TLH r))h I-IR.: 3.0-'J. PPH
| |
| (.,L(')SS IFICATI(3N:
| |
| XNHALATXOH: IRRITATING BI<IN: Sl.XGHTl V rOXIC Sl<lN/EYE: CORROBXVE IHGI=BTION: SLXGHTLY TOXX(
| |
| AQUATIC: HXGHLY TOXXC P
| |
| SFCT X OH 5 EFFI=CTS OF OVF REX POSU RF IS CI }FHXCA} I L I STED AS A CA RC IHQGFiH OR POTENT AL CARCXHOGEH'?
| |
| NTP - HQ XARC - NQ ()S)HA -- Ho
| |
| ' "Tl:"D BY l':Xf O. LJRE:
| |
| eIFDXC.'r ... CoiQDXTXOiis t)EidEiRr" '66r<r' H(3iHF. I<iH(3lJN Pl.-".RHXBBX BLE CXPASLJRE L3:HT. TS:
| |
| r Iol ll ESTABLISHED l3Y OSI IA 0 R Ac(' I"I FOR Tl'3 Is P R(3 I3UCT I I
| |
| rr)6 XHTERNAI.;)ERHXSSXB}..t>> lXPOSLJRE i..XHXT <Xr EL>: 3. HG/CLJ.II., a-HOUR TWA (TXHE lJEIGHTED AVERAGE); . I}6/("U H. STEL (SH(3RT-TERH EXPOSIJRF LXHXT> .
| |
| ~
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| ACLJTE:
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| THI-IALATIOH: XHHALATIQN OF (.,AL(.,XLJH I-IYPOCI-ILORXTE t)UST AHD DEPOSITION OF I'ARTXCLES XN THE RFSPXRATORY 'l RACT CAN I I=AD TO XRRXTATION OF THF. TISSUE A>>D cAusF A VARxETv AF EFFECTS. THFsF EFFFcTs ARE DEPFiNDCHT OH coHcFN-RA I .ON AND .'.iii(.LUDI.: iJ PI IXR Rf.-:SP IRAT(3RY TRACT T RRITATI(3N, iiABAI. CQNGES-TXOH, COUGIIIHG, BORE TIIRAAT, LARVN63:TIS AHf) $ }IORTNEBS t)F BREATII. IH i) Pl;. RAT XoiN() !JI IERE THE iRE r'E I I I Gl I COHCEN 7 RAT I AHS .3}= RESP I RA BLE PART I ClJ-I,A fES r PULHOHARY EDFi}A (FLUXD Irl THE LIJHG) HAY BE PRODLJCED ~ IF HOT
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| r~F..';XSXOHS h!ADE TO //28/9... SRr) EDX~XON: DATE, EDXTXQt<, A!3f)XTXGH OF HSF
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| ;~I '.. ".NFGRI<ATXGN AP~EARXVI'iERFXH 'rS BASED !)POH DATA OBTA(HED FROhI ri!E
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| ".,'~'(IRER lych>D/OR P< Cg >H 'FD 7,',"'<>NX(.".,I 8(')I '>i,,fi'P>, f,',
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| ','-RP)".!l":l. f)l..i.;.:"G l)E!"-XFY ";-IXS )A '.
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| ~ .'.Ri'! ''.Hi-.. ''i-If .'VjER THF ".'(3f)(ICT,,'5 ')XTAfI!.E FI>R '"('E ,"~ PAR7XC(J>.AR !'>IJRPOSE"> AHf) t'! IE
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| ";8:li'>"'". ' I I ">XS!iS> "F Ti-ii: ':.R U."">F --'.".N>,)L,''i'i>j . ANC) DXSPGS>~!.. GF "'-IE O'RGI3!JC"', (3R FIROhI "liE i'>JBLXCATXQH >3R .(JSE GF, 6)R RKI,.X'HCE UPON Xtif=GICIRATXOH COIMTAXHED iIEREXH.
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| "Vi".'-:) .."i'GRlI*TX )N REI " ES <.:h(l Y '. ") ')" I-IE PRQ!3(JCT >')!X",: fGHATED Ii .REXi'i, AHD DOES N(37 i(F; .'.""" '~! 3:TS USF XN <""!I"IBXNATXQt'I <ii.'Til ANY ".)TIIEP, iiATERXAI '">R ":hl ANY llTIIER i" R(1( Fr-8 I) y >
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| f A \) ~ g p.
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| | |
| SEE INSTRUCTIONS ON REVERSE SIDE SECTION II PERMIT NUMBER ~ IYII 0005827
| |
| ~OO E EM A>> NA% OF PROCESS CONIRIBUTIIII TO THE DISOIARGE TICEXXN THIS OUIFALL AM) SIC CODE SANITARY W TER 4911 3 Bs PROCESS SOCEDLLE (YFsVCLY AVERAGE) mum/DtLV ~24 ~36 5 n
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| th LN I TgXXIE ll C~ PRXESS HASTEN%TER FUXI RATE PROCESS CCC Or TOTAL YEARLY STREAMS 0CC DAILY HINII%N 0 ~6 CONTRIBUTING 0 TO 0 3 7 ~6
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| ~
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| DAILY HAXII%N OUTFALL DISCHARGE Ds PROCESS PRCXXXTION RATE N/A LNITS PTIHE LJ As f4'%F CONIRIBVTIICI TO llE DISOLUCGE PROCESS TIROUGH THIS OVIFALL AID SIC CLXE g/A Bs PROCESS SDEDLIE (YEARLY AVERAGE DEWILY Cs PROCESS HLSTEHATER FUXC RATE TOTAL YEARLY cv DAlLY HIHII%N JlIIIZQZc!2JK 1 POUNDS HLXII%M 2 GALLONS Ds PROCESS LN ITS /TINE PRXLICTIOH RATE 3 CUBIC YARDS As HAIE OF PROCESS aXIIIBVTIHTTO TIE DISCHCRGE TICBXXIH THIS OUIFALL JUO SIC OXE g/A 4 TONS Bs PROCESS SQEDLIE (YEARLY AVERAGE)
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| S MGY 6 MGD Cs PROCESS HLSTKHATER FUBI RATE
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| .7 GPD TOTAL YEARLY DAILY H I HII%N DAILY HAXIltN D. PIXXXSS PRXXCf1 ON RAlE TIME 1
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| 2 HOUR DAY As tQPE OF PROCESS CCNIRIBVTIIC lO TIE DISCHARGE AM) SIC CTEE g/A WEEK Bs PROCESS SOERIE (YEARLY AVBLAGE) 4 MONTH RLXKSS HASTDNTKR FUXC RATE LNIT aXK 5 YEAR TOTAL YEARLY LJ DAlLY HINIJ%N DAILY HLXIHEC LNITS nIHE A. HHE OF mCKSS CCNIRIIXITIWTO TIE TI%%XCIH THIS OUIFALL ANO SIC CODE DImeaa N/A Bs PRXESS SOEDIE (YEARLY AVERSE)
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| Cll n C. PROCESS HAST8%CTKR FLDC RATE OCC9 lOTAL YEARLY O
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| CE CL DAILY HIHII%N DAlLY HAXII%N Ds PRXESS PRXXCTION RATE LNITS / TIHE
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| | |
| INSTRUCTIONS FOR COIL'LETING SECTION I I ITEM 3 Tf is form reauires Information on tne process streams <<hlch contribute to this dlscnarge.
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| ENTER THE PERMIT Il'ABER IN THE BOX AT THE TOP OF THIS FORM. THE PERMIT NIWIBER CAN BE FOUNO ON THE FRONT PAGE OF YOUR EXPIRING FERMIT. If this is a new or nor oreviousiy permitted facility, then leave alan< and a number <<ill be a5signed.
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| Enter outfaii number in space provided for eacn page of Section II. For eacn individual dlscharce point a separate set of Section I I 'Orms muSt be f i I leg out.
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| ITEM S PROCESS STREAMS CONTRIBUTING TO OISCHARGE: FOR EACH SEPARATE'ROCESS PROVIDE THE FOLLOHING INFORMATION A. Enter tne name of the process <<nich contributes to this discharge. Also provide the proper SIC code.
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| B. Indicate tne yearly average proce55 Scnedule in hOurS Ocr day and days-oer-year.
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| C. Provide the process wastewater flow rate information as requested ba5ed on your last l2 months of operations. Ilefer to unit code given in the left margin (or the appropriate flow units.
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| : 0. Process Production Rate - Certain permit limitations mav be based on production rates. The production rates used to determine permit limits snail be represented by a reasonable measure of actual production of the facility, such as the proauctlon aurlng the high month of tne orevious year, or the monthly average for the highest of the previous five years, or other reasonable measure as stated in applicable U.S.E.P.A. categorical rules and regulations.
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| For new sources or new dlscharaers, actual production 5hall be estimated u5ing projected production.
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| Recora your production rates in the termS ana unitS uSea In the applicable V.S.E.P.A. categorical rules ana regulations for your type of facility.
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| e SEE INSTRUCTIONS.
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| SECTION II PERMIT NUMBER ~LNI Oit05827 ON REVERSE SIDE
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| ~OO: E Ae IS 1HE DISCHARGE FRCN THIS OUTFALL DIRECTED TO THE GRONO OR GRONDtATKRS2 llF tDP CCttTltiE TO ITEM O)
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| Be HAS A HYC62OIBXDGICAL STIXT/ OR cNIREHT ITS EOJIVAIENT BEEH PKRFORPED OR IS THERE SIFFICIEHT HfÃGGEQ+GIaL INFOIHATION AYAILABlEAS RE0UIRKD BY Tte HATER RstxxstcEs alttISSICM PART ZZ RAIXltD6ATER RIIES OF AIDUST 14P lRU RP525PZ/W (PAGE FCR z->>- a.
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| GROUNDWATER THIS EXISTI% OR PROPOSED DISCH6RGE/ IF YES AlTAOI A COPY CF lHE REPCRTP Submitted 12/6Y91 DISCHARGE Ce ARE YCU RBXESTI% AN EXBGTTICN FRCM SIKPIITT1% A HYCRCGKOLOGIaL REPCRT tltDKR INFORMATION RISE R.323P221}l (l0} (PAGE tt5) Ot FR(M GRIXPIXtATKR N5ttITQRI% IIKOUJRIMEHIS tltCER RLAK RP525PZIU5 (5) (PAGE t(73 OF TIE PART Zl RLLESP IF YES ATTACH DXIMKHTS AM) EXPLANATICN TO DOIGCT IATK THAT YIXR DISOQf6E NXAD OUALIFY RXI
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| ~CNP De ARE YOU RBXESTI% A VARIANCE FRttt RULE 323e2Z6 (PAGE 5) (%tKXDIIADATICN)OF TIE HATER RESIXl2CES CCWISSION PART ZZ GRXXtttlATKR RIALSPA IF YESP ATTACH SIXH DOQMKHTS AS NECESSARY TO CQQtSTRATK TIE HEED FCR A VARIANCE IN TKIYtS CF TIE CRITERIA SPECIFIED IH RIAL 5Z5P2210 (PAGE OF THE PART ZL RILESP Ee I,IST ALL CteIICAL SIBSTAICES HHICH ARE IN MICHIGAN S CRITICAL MATERIALS REGISTKR TAKE IV lPAGK {j) Ot UPSP EPA'S PRICRITY RXll/TANT LIST TAKE V (PAGE 1) OR ANY OIIER SIBSTMXS INT APPUaBLE/BELlKVKD ABSENT tHIOI ARE Ot NAY BHXPE INXIIIIXS1D TIE EESIGNATED USES OF TIE GNIXIKltATER OR 19 TIE PUBLIC IEALTH THAT ARE DISCM6RGED OR EXPECIED TO BE DISCH6RGKD TO TIE MX!KXIATKR~THIS FJCILITYP ESTIHATE THE FINAL EFFLIEHT COtCEHB4TICN AtKI RKCCRD AII. DteTA IN ITBl 1 OF SECTION Il IH THIS IO)NEfe TIE APPLIa7IT HAY BE REIXIIRKD 1O DO ACOITIOIALHASTE JIUI.YSESP PRESENTS DATA IQOVIDKD IN ITBI 7 Ae DISCH8RGE CHAIIACIKRISTICS CCNCEHIRATICtt WITS CIXK lt ANALYSES SAtPIK TYPE CIXE ITEM AVE NAX 5
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| EXPECTED WASTEWATER BGDI7
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| 'coD TOC (FIYE DAY BloctetlaL oxYGEH DKMAIKI)
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| (OKttlaL c0DGEN cetAto)
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| (TOTAL ORGANIC aRNXt)
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| ~40 . ~05 ~99 . ~6 u1 ~ u CHARAC ANCNIA HITRIXIKH (AS H)
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| TOTAL SUSPKNXD SCUDS ~25 . ~55 ~11 6, ~0 ul 2~60 u1 1 Mp/I TOTAL PIOSPta2US (AS P) ~7~ . ~03 6 ~12 ~ ~05 ul ~65 u1 2 UQ/ I TOTAL RESIIXIAL OURIHE u1 3 COUNTS/
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| 100 ml DISSOLVED OXIGKH NIN u1 4 S.U.
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| 5 'F
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| ~6 ~4 S7 8 ~1 1 3 e I.BS/OAY FECAL CGUFXIN BACTERIA
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| ~TINE (SUPER)
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| TDPERATISK (HINTER)
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| ~
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| ~u ~
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| ~
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| u LJ u5 u5 Be ODKR INSTKHATKR CM6RACIKRISTICS 0 I L B G E A S R E LJ
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| ~SAHP c i ro. ~65 . ~56 ~20 8, ~0 u1 ~65 TXBF 1 GRAB 2 24 HOUR COMPOSITE RECUIRKD IWXP5ATICN FIT SINFACE HATER DISCHNGVP
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| | |
| INSTRUCTIONS FOR C(5IPLETING SECTION I I ITEMS 4 ANO 5 5
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| 5?(Is forr,require orto r equ r~e n tmatioIi on a specific outfall discharging to either the groundwaters or the surface Waters.
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| -q(ER TWE Dcq)f(T'h BER III THE BOX AT THE TCP OF THIS FORM. THE PERMIT NIDIBER CAN BE FOUND ON THE FRONT PAGE OF YOUR EXPIRING oER??IT. z+thi+ 5 a nett or not previously permitted facility, then leave plonk and a number <<ill be assiqned.
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| Per r (le Ouc fal I numaer In the Space PrOvided tor eacn Dace of Section II . For eden Individual discharge point a separate set DP ecVIotl 'D~ torm'5 (It's 4 ana 5) nust ae I i lied out.
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| /
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| ITEM 4 Il G"OUNDWATED DISCHARGE INFORMAT ION (00 NOT INCLUDE DEEP WELL INJECTION INFORMATION IN THIS ITEM)
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| A.-D. The applicant shall address each ot thaqe oarts If the discharge fran this outtall Is to the groundwater.
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| ITEM 5 EXISTING OR EXPECTED (FOR A NEW DISCHARGE) WASTEWATEP. CHARACTERISTICS OF GROUNDWATER OR SURFACE WATER DISCHARGE (DO NOT INCLUDE
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| ,?JP W>>LL INJt I N IN IN H The applicant shall report available discharge data (real data for existing discharge or expected data for a oroposed discharge) for the Dard>>eters ds listed. These Darameter5 shall be addressed foI either a surface water dl5charge or as aDpropriate for a grounovater dlscnarge. For assistance In determining appropriate parameters a groundvater dlscharoe apollcant may contact the 5" OCDODDODOD Grounovater Duality Division, Permits Section or the approorlate Grounorater pualltv Division's District office.
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| The applicant shall report the Sanele type code best describing eden reported place of date. See coding on the left margin of this form.
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| II'his outtall Is a surface Water dlscnarae. the aop? icant must report quantitative data for each Dard>>eter Identified bv an
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| ~ . I* CC Dt t 5 ~ 555
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| ~
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| 5 Ot DOOI tl I, II I 5OCO 5 Dt t CWIND tt tOI ~ DDIIC tlt
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| : 9. It data ls available for other parameters not listed above in A. or other parts ot this application the aDpllcant 5hould reDort that data In the blank 5Daces provided In this Dart.
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| NOTESI I. Unit codes tor paraneters reported In parts A and B can be tound on the lett hand side ot this torm.
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| : 2. Grab sample shall be used to analyze for pH, tenoerature, total phenols, residual chlorine, oil and grease, and fecal col ltorm In a surtace water discharge unless other frequency-sanple type analyses are availabl ~ . See Glossary (page 48) for ddt lnltlon of grab sandie.
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| 24-hour comooslte samoles shall be used to analyze for Total 8005, coo, Toc, Am>>onla Nitrogen, and Total Suspended Solids In d 5urtace Water d)5charge unle55 other frequency-sample type analyses are available. See GI055dry (page 4B) tor definition of ccmooslte sa>>pie, You are not required to report unle55, you vish to demonstrate your "net" effluent limitation tor one or more pollutants, tnat Is, an ettluant limitation adjusted eligibility REPORTI)6 OF INTAKE DATA~ foI d by subtracting the average level ot the pollutant(s) present In your intake Water. NDDEs regulations allow net limitations only In certain circumstances. To demonstrate your eligibility, report the average ot the result5 ot analyse5 on your intake vater llf your Water Is treated betore use, test the voter atter It Is treated). and attach a 5epdl ate sneer containing the tol loving for each Do? lutant?
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| (a) A statement that the Intake veter I5 dravn tram tne body of vater Into rh)ch the dl5chdrge Is made.
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| (OthervIse, you are not eligible tor net limitations.)
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| (b) A statement ot the extent to Which the level of the oollutant is reduced by treatment ot your vastevdter ~
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| (Your limitations WI) I be ddju5ted only to the extent that the pollutant Is not removed.)
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| (c) when apDI)cable (tor exonple, When the pollutant represents a class ot ca>>pounds), d demonstration of the extent to Which the pollutants In the Intake very physically, chemically, or biologically tree the pollutants contained in your discharge. (Your limitations vill be adjusted only to tne extent that the Intake Dol lutant5 do not vary frcm the discharged oollutants.)
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| lt you have two or more substantially Indentlcal outtal ls, you may request permission tran your permitting authoritv to sample and analyze only one outtal I and submit the results ot the analysis tor other sub5tdntlally identical outtalls. It your reque5t is granted Dy the permittlno authority, on a separate 5heet attached toothe aap Ilcatlon to?m Identity vhlch outtall you dld test, and describe why the outtalls <<nich you old not te5t dre substantially identical to the outfall >>hich you did test.
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| | |
| SEE It ISTRUCTIONS ON REVERSE SIDE SECTlON II PERMIT NUMBER ~ gl Qpp5827 I THE FOLLJSI1% REOLESTKD INFORMATION IOZEI A.
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| ~e ADNESSED MDI USE DISCHARGE% BALLL PROVIDE EXPECIKD VALLES FOR QUALITATIVE INFNHLTION REOLKSTED BELCHe ts THIS FACILIlY A PRIMARY IIOUSTRY?
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| ~
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| (REFER TO TABLE QHFACE HATOt DISCHARGERS.
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| lHE OUlUITITATIVE AND IA PAfg 9D OOE (IF W GOTO E) (IF Y 5 GO TOB)
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| PRIORITY POLLUTANTS Be IWICATE TYPE OF PRIMARY INDUSTRY AS LISTED IM TABLE tA I CONTIN'ITH C. )
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| PACE Qe S TH ELE W R AND C> COES THIS OUIFALL DISCHARGE CCtITAIM ANY PROCESS HASTKHATER?
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| (tF W, GOTO E) (IF YKS. GOTOD)
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| ADDffIONAL INFORMATION De INDICATE ttIICH GC/tn FRACTIONS NJST BE TESTED FCR Analysis per D
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| ~
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| (REFER TO TABLE IA PJIK (II)
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| FOR IOZEI FCR EACH GC/Hs FRACTION CHECKKDe EACH SPECIFIC ORGANIC TOXIC POLLIJfAMT HllHIH J.B. Beauboeuf SURFACE KAOI FRACTION tl5I BE ANALYZED FCR (SEE TABLE I IA PAGE Q, IN AODITIOMi ALL PRIIVLRY D BASE/MEUIRAL GrOundWater WATER INLXJSTRY APPLICANTS )IITH A PROCESS HAS19IATER DISCHARGE'~ PRCNIDE OLJLMTITATIVE Division DISCHARGE ONLY DATA FOR EACH TOXIC IOLJJJfAMT IN TABLE IIIA PA% gP e RHXRD ALL DATA ON FCRHS PROVIDED (ITBL 7) IN THIS BOOKLETe 0 eeee (CCttfltAE HtlH K, K BKLJBI) PESTI C IIX Ee
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| ~
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| IF gg, IN TABLE IIA AMD IVA PJGKS BE PROVIIKDe
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| ~
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| QJIFACE l4LTER DISC%ROE JPPLICAMf (PRINRY OR SECCtOUIY I IJJSIRY)e RKGAJICLESS OF THE TYPE OF DISCHARGEi KMlIS OR HAS REASON TO BELIEVE THAT AMY POLLUTANT LlslKD IS DISCHARGED FROI ANY IXJIFALZiT)E OUMITITATIVE DATA WT APPLICABLE/BELIEVIABSOIT N/A RECND ALL DATA ON FOIVIS PROVIDED (ITKH 7) IN THIS BOOKLETe 0 PRESOIT/DATA ls ATTACHED Fe IF AMY SLJIFACE HATER DISCHARGE APPLICANT (PRIMARY OR SECOtOARY INXJSTRY)e REGJRKESS TARE VA PAGE ARE DISCHIRM FRLtt AMY OLJIFALL APPLICJJIf ~
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| OF TYPE OF DISCHLRGKe XMAS OR ILLS REASCN TO BELIEVE JIFFY POLLJJTAMTS LISTED IN
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| + l)E DESCRIBE RKASONS FCR 1%, PLXJJJTJtlf BEltO PRESEHT JJO PROVIDE AHY AVAIUBLEOUANTITATIVEDATAe Wf APPLICABLE/BELIEVED ABSOIT RKCND ALL DATA ON FCttts PROVIDED (ITOI 7) IH 1HIS BOOILEfe N/A PRESOIT/DATA Is ATTJUMD Ge ALL QRFACE HATOt DISCHARGE APPLICAMIS (PRIMARY AIO SECCtOARY IIGXJSTRIES) ttOJ Wr APPLICABLE/BELIEVEDABSENT cR HAIKFAclLSLEs 2 4i TRIctslstpetEwxf AcETIG AGID (2e 4i 5-T)J i 4i et f TRIOKJSOPIHWXY PRCPAWIC ACID (SILVEXi Zs Ii 5i TP)J DI%PIYL V PCi 4i l TRILJLJJRCP)KDIYL) PIOSPKIIOTHIOATK (RCtNEL)J
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| >IRICJKJSIOPLEML (TCP) J OR HEXJOLNGPIEJE (ICP) J (ALL DATA FN T)E N/A ABOVE tlJST BE GKMIIATED USt% STAIOARD AIHLYTICILCALItttATICH PIOCOXJLKS) OR
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| ~
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| KtslO CR HLS REASON 1D BKLIEVE THAT TELO IS OR HAY BE PRESBIT IN T)EIR DISCHJJKIEe RKPNT QUALITATIVE DATAi GOERATKD l431ttt USED A SCRKKHIIO PIOCOXJLE CALIBRATED HITH ANALYTICALSTAIOARDSe FN L Di 1 Si Wf TKTJIAOKJSKXJIBEHZ~DIOXIH Q PRESOIT/DATA IS ATTAC)ED (TCZXJ)e RKCND ALL DATA ON FNtts PROVIDED (ITBL f) IN THIS BOOKLEfe Je IF ~1lE QJLFACE HATER DISCHARGE APPLICAMf K)KHS N HAS REASON 1D BELIEVE THAT BIOLOGI~ TOXICllY TESTS HOLE HADE IH lHE LAST T)ttEE (9) YEARS CN JJtf OF T)E APPLICANT S DISCHL%ES OR ON A RECEIV1% HATER IN RELATION lD A DISCHARGEi PROVIDE N/A THIS ItFNHATION AS JJI ATTACttHIT TO 1HIS JPPLICATIONe IF A OIIIRACT LABNATORY OR CSStLTI% Ftttt PBRÃtKD Jttf OF TIE ANAYSES REQUIRED Q APPLICLBLE/SEE AITACIED Ke BY THIS APPLICATICIL PROVIDE TIE NAtE AND ACNESS OF EAIH LABORATNY OR F IIVI AtO 1)E ANALYSES POIFCRtED AS AM ATTACttEMT CF 'IHIS APPLICATIONe Q WT APPLICABLE QX ~IIE/SEK An~
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| CO YOU DISCHL%E ANY OI)ER TOXIC OR INJLRIOLJS CteHCAL SLSSTANCES tOT LISTED IN TABLES IV PJGE tt AIO IIA lWOAI VA PPP4$ ~~ IF YEsi TlEN IOEHTIEY TIE CJKPIICAL QSLSTANCES AW KSTIJLETE TIE FINAL EFFLLEttf IXYCEHIIIATHYISe SLKPIIT THIS Q tOT APPLICABLE N/A IIFCALLTICNAS AN ATTAC)tENT TO THIS APPI.ICATIONe APPLICABLE/SKE ATTAOED
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| | |
| INSTRUCTIONS FOR.CCMPLETING SECTION II ITEM 6 This form reavires Information on s speCifiC Outfall dlsCharglng to the surface>>sterS.
| |
| ENTER THE PERMIT NUMBER IN THE BOX AT THE TCP OF THIS FCRM. THE PERMIT N(S48ER CAN BE FOUNO ON THE FRONT PAGE OF TOUR EXPIRING pERMIT. If this is s ner or not previously permitted facility, then leave blank sna s number>>i(I be ass(oned.
| |
| Enter tne outfall number In the space orovlded for tach page of Section II. For eben Individual discharge point s separate set of Section II. Item 6 forms must be filled out.
| |
| ITEM 6 PRIORITY POU.UTANTS ANO AOOITIONAL INFORMATION NOTE: If you have t>>o or more substantial ly indenticsl outfsl ls, you msy request permission from your permitting author Ity to sssple sna analyze only one outfall sna svcmlt the results of the analysis for other substantially Identical outfsl is.
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| lf Vour request Is granted by tne permitting authority, on s separate sneet sttscned to the application,form Identify
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| >>nich outfsl I you aid test, sna describe>>ny tne outfslls>>nlch you aid not test are substantially Identical to tne outfall
| |
| >>nlch you did test, NOTE: 40 CFR Part l22.2((g)(8), Friday, April I, lg83, provlaes for s smell Business Exemption from the resorting of quantitative apts for organic toxic pollutants sna toxic pollutants ss required by Port I22.2((g)(7)(ll)(A) or I22.2((g)(7)(ill)(A),
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| A.-C. These Dorts sre self-explanatory snd do not require further Instructions. simply go through each part snd do ss indicated.
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| sno E.-J.
| |
| : 0. Several Industrial categories snd subcategories have been exemotea frcm submitting dots on certain GC/MS Fractions (40 CFR Pert l22, vol.'48, No. 64, Friday, April I, 1983, Notes I, 2, sna 3). "
| |
| Revle>> the folio>>lng list to determine>>nether your facility qualifies to be exempt from reporting Gc/HS (Gss Chrcmstogrspnv/
| |
| Moss Spectroscopy) Fractions.
| |
| GC/MS Fraction Testing snd Reporting Exenetlons Textile Mills Industry All four GC/HS organic fractions ln the Greige Mills Subcategory.
| |
| - Pesticide fraction In ell other supports of this Industry.
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| Ore Mlnln snd Oresslno Indust
| |
| - Volatile. base/neutral, snd pesticide fractions In the Base snd Precious ltetsls Subcategory.
| |
| - AII four Gc/MS organic fractions In sll other subcategories of this Industry.
| |
| Cu>> and Vood Chemicals Industry
| |
| - Pesclclde fraccion In the Tall Oil Rosin Subcateqory and the Rosin based Derivatives Subcatsgofy.
| |
| - Pesticide and base/neutral fractions in all other subcategories of th(s Industry.
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| Pulp and Paper Industry
| |
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| - Sass/neutral and pesciclde fractions in Oeink Subpart Q, Olssolvlnq Kraft Subparc F, and Paperboard from Vesta Paoer Subpart E.
| |
| - Volaclle, base/neutral, pesticide fracclons in the BCT bleached Kraft Subpart H, Semi-chem(cal Subparts 8 and C. and Nonlnceqrated-Fine Papers Subpart R.
| |
| Acid, base/neucral. and pesticide fraccions ln Fine 8)cached Kraft Subpart I, Olssolvlng Sulfite Pulp Subpart K, Ground
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| >>ood Fine PaDers Subpart 0 Market Bleached Kraft Subpart 0, Tissue frcxa Vastepaper subpart T and Nonlnteqrated Tissue
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| ~ ~
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| Papers Subparc S.
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| Steam Electric Peer Plant Induct
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| - Base/neucral fraction in the Once Through Cooling Vater, Fly Ash, and Boctom Ash Transport Vater orocess >>astestreams.
| |
| 38
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| INSTRUCTIONS FOR CCHPLETING SECTION I I ITEN 7 Thl arm Is form to be used bv both surface and groundrater applicants to record Information on anv Hlchlgan critical material, E.P.A.
| |
| prlorltv pollutant or~ natardous substance in xhicn tnls application recuires data to be provided. This vould Include any cham I ca I substance frcm tne Hlchlgan Critical Haterlals Register <Table Iv), the E.P.A. priority pollutant t.lstlng ITable V). or Tables I IA VA vhlon IIStS Organ)C TOXIC POI lutantS ~ Other TOXIC POI lutantS ~ CcnVentlanal and NOnCOnyentlOnal POI lutantS and Hasardcua Substances ~
| |
| ITEN 7 CRITICAL MATERIALS* PRIORITY POLLUTANTS ~ ANO/OR HAZAROOUS SUBSTANCES IN THE OISCHARGE Materiel I. 2. 3... 8 A. List the name of the chemical substance Icrltlcal material, priority pollutant, or hasardous substance) frcm Tables IV. V and IIA-YA as reculred In tne aox vnicn you cnecxed In A. I-3 . above. Enter eacn chemical substance 's parameter nmnber as listed In Tables IV, V and IIA-VA It provided.
| |
| : 8. Provide the average concentration of the chemical substance hewed In A. Indicate the smnple type used and the number of analyses made to provide the concentration cata for the chemical substance named In A.
| |
| Pl+vide the maximus concentration and determine the loading of the chemical substance C,
| |
| I'f mass named In A.
| |
| only one analysis uas made for a chemical substance then record that data es a maximus value. If more than one analysis has been made for a cnemlcal substance then provide en average value of those analyses and the maximus value.
| |
| : 2. This Section II, Item 7, Oata Sheet provides space for recording data for 8 chemical substances IHaterlals).
| |
| Additional space for recording of data for more than 8 Haterlals can be made by making copies of this Item 7 Oata sheet es needed. It Is also Important to use e separate set of oata sheets for each applicable reporting reculrmnent as listed In A.)-3. end for each outfall.
| |
| Refer to the lett margin for the code number representing the sample type used end the appropriate unit codes.
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| 40
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| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USiNG METHOD 8260 Page 2 of 2 Client Sam le ID: S. SEWAGE PLANT EFFL. LAL Sam le ID: L1009-47 Reporting Concentration Detection Limit Constituent IL IL Data Qualifier s Dibromochloromethane <5 hl r nzn hl nzn <5 m -X lene o-X lene <5 r n Br m f rm 1 1 2 2-Tetrachloroethane <5 1 3-Dichlorobenzene <5 1 4-Dichl r nzen <5 1 2-Dichlorobenzene <5 LOCKHEED ANALYTICALSERVICES 42
| |
| | |
| VOLATILE ORGANIC ANALYSIS RESULTS FOR ANALYSES USING METHOD 8260 TENTATIVELYIDENTIFIED COMPOUNDS Client Sample ID: S. SEWAGE PLANT EFFL LAL Sample ID: L1009%7 Date Received: 29-DEC-93 Date Analyzed: 114AN-94 Matrix: WATER Dilution Factor: 1 Analytical Batch: 011094-8260-FZ QC Batch ID: 011094-8260-F2 Estimated Retention Concentration Time Data .
| |
| Tentatively Identified Compound (pg/L) Iminutes) Qualifierls)
| |
| UNKNOWN SULFUR COMPOUND 37 4.47 UNKNOWN 28 , 9.70 LOCKHEED ANALYTICALSERVICES
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| METALS RESULTS Client-Sam le- ID': S;...SENfAGE PLANT'EFF- Date: Collected: 12-28-93. Matrix:: round',water~:
| |
| LAL Batch ID(s): 1220 im Date Received: 12-29-93 'O¹69095-040-3N Reporting Co'ncentratlon 0'atection Umit Date; =',.-.;, LA4.;-",-.
| |
| Method." Data'uallfierls) A'nal zed''." "'S " 'le"lD':
| |
| Constituents", lm ILl {m ILl Aluminum 6010 <0.20 0.20 01-20-94 L1009-16 Antimon 6020 <0.060 0.060 01-27-94 L1009-16 Arsenic
| |
| '020
| |
| <0.010 0.010 01-27-94 L1009-16 Barium 6020 <0.20 0.20 N 01-27-94 L1009-16 Be Ilium 6020 <0.005 0.005 01-27-94 L1009-16 Boron 6010 (0.20 0.20 01-20-94 L1009-16 Cadmium 6020 <0.005 0.005 01-27-94 L1009-16 Chromium 6020 <0.010 0.010 01-27-94 L1009-16 Cobalt 6020 <0.050 0.050 01-27-94 L1 009-1 6 Co er 6020 <0.025 0.025 01-27-94 L1009-16 Iron 6010 <0.10 0.10 01-20-94 L1009-16 Lead 6020 <0.003 0.003 01-27-94 L1009-16 Ma nesium 6010 5.0 01-20-94 L1009-16 Man anese 6020 0.025 0.015 01-27-94 L1009-16 Mercu 7470 <0.0002 0.0002 01-07-94 L1009-1 6 Mol bdenum 6020 <0.20 0.20 01-27-94 L1009-16 Nickel 6020 <0.040 0.040 01-27-94 L1009-16 Selenium 6020 <0.005 0.005 01-27-94 L1009-16 Silver 6020 <0.010 0.010 01-27-94 L1009-16 Sodium 6010 34 5.0 01-20-94 L1009-16 Thallium 6020 <0.010 0.010 01-27-94 L1009-16 Tin 6020 <0.20 0.20 01-27-94 L1009-16 Titanium 6010 (0.10 0.10 01-20-94 L1009-16 Vanadium 6010 <0.050 0.050 01-20-94 L1009-16 Zinc 6020 0.047 0.020 01-27-94 L1009-16 LOCKHEED ANALYTICALSERVICES ~
| |
| | |
| GENERAL CHEMISTRY RESULTS Client-Sam le ID.'S., SEWAGE PLANT EFFL Date Collected: 12-28-93 Matrix: round water.
| |
| LAL Batch ID(s): 1229 im Date Received: 12-29-93 PO469095-040-3N Reporting Date LAL,.
| |
| Constituent Method Result Detection Limit'ata'ualifier is)." Anal zed Sam le'ID Fluoride, in m IL 340.2 <0.15 0.15 01-24-94 L1009-4 Chloride, in m IL 300.0 120 0.01 6 12-29-93 L1009-4 Nitrate. Nitro en, in m IL 300.0 24 0.017 1 2-29-93 L1009-4 Nitrite-Nitro en, in m IL 300.0 <0.50 0.50 12-29-93 L1009-4 Sulfate. in m IL 300.0 39 0.059 1 2-29-93 L1 009-4 Ammonia-Nitrogen, 350. 1 24 0.50 Dl1:10) 01-05-94 L1 009-8 inm IL Total Cyanide. in mg/L 335.2 <0.020 0.020 01-03-94 L1 009-12 Comments:
| |
| LOCKHEED ANALYTICALSERVICES
| |
| | |
| r~
| |
| ANSTEC PPERTUR CARD Also Availabie on
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| Unit ~1 ttrf t Tronsforeter Deck Drains (5 Dryvells) 0 tf II 0004 Outfoll
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| ~M- '1 j~ / j I Outfoll 002 1 Sprpttan 1200'f fshore O g ~
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| / /
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| |
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| |
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| South Savage :, .Ov~)av'," r Treattttent Plont Sequenc)ng 8otch Reactor Storetvateg Outfall S003 jj Tr eatvtent Plant tt t 00tf II 0004 I
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| V'',
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| WASTEWATER FLOW DZAGR M DONALD C. COOK NUCLEAR P. ANT AVG MAK I, FLOw FLow OUTFALL DESCRIPTION I IN MCD) %%%
| |
| 00 I V-I CIRC wTR I 042 I 393 002 V-2 CIRC wTR )3lt )743 003 OE ICE OOa u-) SC BLOWOOwN . Ioo 008 U-2 SG BLOWDOWN ~ 098 ~ 234 OOC HTG BLR BLONDOXN 0 I4 OOD TRS DISCHARGE . 305 . 66T OOE SEWAGE TREATMENT PLANT 024 .052 PLANT SITE SANITARY EAST SOI STM WZR N. CATCH BASIN ExTENOEO 6 KItCHEN WAstE S02 STII WTR.S. CAtCH BASIN AERATION PLANT 503 STM wtR RADIOGRAPHIC S04 sTM wtR PROCESSING LABORATORY w~STE PHOTO LAB FR"" AKE TOWNSHIP LIkE STONE FRDM MAKE-UP wATER PLANt CONDENSATE SYSTEM HEatING BOILER PROT/ChON TABLE WATER SUPPLY BEO NEUTRALIZATION TANK SCVTH ExtENDED J.
| |
| TRAINING BUILDING CHEutstRY LAB AERATION SEQENCINCi LAYVP DRAINS wastE PLANT to TURBINE i REACTORS I
| |
| ROOM SIAJP I IHSTALLAtION DVE I 2-95)
| |
| TRAINING BUILDING HVAC SYSTEM wASZE So I OUTFALL NORMAL SZART UP OOC FLASH tANK FLASH TANK Esw DRAININC NESw OUTFALL 00)
| |
| Ul CIRCULATING WATER DISCHARGE UNIT I DRAINING l200'FFSHORE UNI't I STEAM DISCHARGE BAY CONDENSER AXSTEC UNIT I COuPONENZ COOLING watER APERTURE DRAINING PROC ESSED GLYCOL 5
| |
| LAYUP DRAINS CARD PROCESSEO OUTFALL CEN MONIT(R AUXILIARY OOA BLOC.
| |
| WATER NON-RADIOLOGICAL CHEMIS'IRY LAB At~0 Available on DRAINS I 3) INTAKE CRIBS INtaKE DAERCENCY OVERFLOW Aperture Card 2250'FFSHORE FOREBAY RECENERaTION NEVTRALIzaTION Ro SYSTEM REJECT OUTFAQ P)D MA E UP waTE PLANT L TANK TIXIBINE ROOI SIAW ABSORPTION NDN-EssENZIAL sERvIcE waTER EMERGENCY MISC. DIESEL JACKET LOADS rAVER DRAINS LAYUP DRAINS VNIT 2 COMPONENT IN PLANZ SOS OUTF ALL MISC. FLOOR DRAINS OUTFALL 002 008 U2 CIRCULATING waTER DIScHARGE
| |
| )200'FFSHORE UNIT 2 UNIt 2 DRAINIHC DISCNARGE BAY STEAM Co)CENSER LAKE MICHIGAN ESw DRAINIHG NORMAL START-VP Rqi~~M s+-D3 I FLASH TANK. FLASH TANK Uugt I/UNIT 2 MAIN TRANSFORMER 503 DECK DRAINS ISZORMWATER)
| |
| OUTFALL 003 OE-ICING DISCHARGE UNIT I/UNI't 2 EMERGENCT UNIT I/UNIT 2 was usED 56 oats IN )992/93 CENERATOR CATCHBASIN UNIT L/uNIZ 2 GROUNDWATER PIt OIL/waTER ORY 'WELLS FLUSHING 6 ZFSTING wAtER ls SIAPS SEPARATOR DIRECTED TO STORuwaTER AND/OR GROVNOwATER OUTFALLS H<<w BASED ON DATA SVBMITTED IH SECURITv DIESEL l993 D)4Z4. GENERATOR OAY TANK OvERFLOW INDIANA MICHIGAN POWER CO.
| |
| WASTEWATER FLOW PgAQRAM SZS/RFZ 2-24-94 U)2 /wASTWTR.DCN vp ~
| |
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| I}}
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