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| issue date = 04/20/1998
| issue date = 04/20/1998
| title = Forwards Application for Renewal of NPDES Permit M10001457 IAW License DPR-20,App B,Section 3.2.Application Submitted to Mi Dept of Environ Quality,Surface Water Quality Div,On 980330
| title = Forwards Application for Renewal of NPDES Permit M10001457 IAW License DPR-20,App B,Section 3.2.Application Submitted to Mi Dept of Environ Quality,Surface Water Quality Div,On 980330
| author name = HASKELL N L
| author name = Haskell N
| author affiliation = CONSUMERS ENERGY CO. (FORMERLY CONSUMERS POWER CO.),
| author affiliation = CONSUMERS ENERGY CO. (FORMERLY CONSUMERS POWER CO.),
| addressee name =  
| addressee name =  
Line 13: Line 13:
| document type = CORRESPONDENCE-LETTERS, INCOMING CORRESPONDENCE
| document type = CORRESPONDENCE-LETTERS, INCOMING CORRESPONDENCE
| page count = 227
| page count = 227
| project =
| stage = Request
}}
}}


=Text=
=Text=
{{#Wiki_filter:A CMS Energy Company Palisades Nuclear Plant Tel: 616 764 2276 27780 Blue Star Memorial Highway Fax: 616 764 2490 April 20, 1998 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, DC 20555 Covert, Ml 49043 DOCKET 50-255 -LICENSE DPR-20 -PALISADES PLANT Nathan L. Haskell Director, Licensing RENEWAL OF THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) PERMIT NUMBER MI0001457 This letter transmits a copy of the National Pollutant Discharge Elimination System (NPDES) application for renewal of permit number MI0001457, in accordance with Palisades License, DPR-20, Appendix B, Section 3.2. The application for renewal was. submitted to the Michigan Department of Environmental Quality, Surface Water Quality Division, on March 30, 1998.
{{#Wiki_filter:}}
 
==SUMMARY==
OF COMMITMENTS This letter contains no new commitments and no revisions to existing commitments.
athan L. Haskell irector, Licensing CC Administrator, Region Ill, USNRC* Project Manager, NRR, USNRC NRG Resident Inspector
-Palisades Enclosure 9804280100 980420 PDR ADOCK 05000255 P PDR )
RENEWAL OF THE NPDES PERMIT NUMBER Ml0001457 REC'D W?LTR DTD 04/20/98 .... 9804280100 -NOTICE-ATTACHED FILES ARE . OFFICAL RECORDS OF THE . OCIO/INFORMATION
' MANAGEMENT DIVISION.
THEY HAVE BEEN CHARGED TO YOU FOR A LIMITED TIME PERIOD AND MUSTBERETURNEDTOTHE RECORDS AND ARCHIVES SERVICES SECTION, T-5C3. PLEASE DO NOT SEND DOCUMENTS CHARGED OUT THROUGH THE MAIL. REMOVAL OF ANY PAGE(S) FROM DOCUMENTS FOR REPRODUCTION MUST BE REFERRED TO FILE PERSONNEL.. -NOTICE-
* *
* ENCLOSURE CONSUMERS ENERGY COMPANY PALISADES PLANT DOCKET 50-255 NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) RENEWAL APPLICATION FOR PERMIT NUMBER MI0001457 
*.;* * *
* Consumers Energy . -----------
-A CMS Energy Comoany March 30, 1998 Environmental
& Tecnmca1 Services Deoartment 1945 West Pama// Road Jackson, Ml 49201-8643 Michigan Department of Environmental Quality Surface Water Quality Division Attn: District Supervisor P.O. Box 355, M-89 Plainwell, MI 49080 CONSUMERS ENERGY COMPANY, PALISADES NUCLEAR PLANT NPDES PERMIT NO MI0001457 NPDES PERMIT RENEWAL APPLICATION
."ax: 517 788 2329 21EP10.l.3 The NPDES Permit for the Consumers Energy Company Palisades Nuclear Plant expires October 1, 1998. In accordance with Rule 323.2151 of Act 451, Part 31 and in response to the January 28, 1998 notification letter from Mr Kevin Cook (MDEQ Permits Section), an application for NPDES Permit renewal has been completed and is attached as Attachment
: 1. Pursuant to Mr Cook's directive, every applicable item of the 1/98 revised State of Michigan NPDES Permit Application has been completed.
The wastewater from Outfall 001 and internal Outfalls OOA-OOD, and OOF has been well characterized through the duration of the present and previous NPDES Permits .. Outfall 001 consists principally of noncontact cooling water and combined minimal volumes of miscellaneous low volume wastestreams.
Outfall 001 does not receive a pollutant loading as a result of plant operations for a number of parameters for which permit application reporting is requested.
Where there is minor loading, data show that it is minimal, if even detectable.
Parameter Waiver Request The Company requests the following waivers from certain data reporting requirements of Sectfon III B Item 6 of the application under provision Section 122.53 (d)(7)(i)(B), Subpart D, Part 122 of the Federal Regulations:
: 1. For Outfall 001, a waiver is requested from reporting data for the parameters of (a) BOD 5, (b) COD, (c) TDC, (e) Ammonia Nitrogen (as N), and (f) Total Suspended Solids. 00398-19.JAC 
* *
* Internal Outfalls OOA, OOB, & OOC -Request to Elfminate Monitoring and Reporting The Company requests elimination of monitoring and reporting at internal Outfalls ODA, DOB, and DOC. Outfall ODA, OOB, and OOC are principally noncontact cooling water providing the major source of water to Outfall 001 where, associated monitoring and reporting is provided.
The effluent from these three internal outfalls have been well characterized through the NPDES permitting term of the Plant. Data provided under previous permits have established average and maximum flows from each particular outfall. This request will reduce the monitoring and reporting administrative burdens on both the Plant and *the Department.
Water Treatment Additives Current A listing of water treatment additives used at the Palisades Plant is presented in Attachment
: 2. Most of the additives listed have been previously reviewed and approved by the Department through past permit development processes.
Current usage and discharge rates of these additives remain the same as previously reviewed.
Current usage and discharge rates of these additives also remain the same as previously reviewed.
However, several approved additive product names have changed to reflect a recent merger between product/chemical companies.
The additives effected by the merger and the new name changes are identified on the listing of water treatment additives.
During this permit renewal process, the Palisades Plant requests the approval to use two new water treatment additives, Alconox Detergent 8 and Betz Spectrus NXllOO. 2 Alconox Detergent 8 is a radiological decontaminate agent to be used in the reactor cavity to decontaminate the reactor cavity. The BetzDearborn Spectrus NXllOO is a biofouling control agent to be used in the radwaste filter tank to effectively control, clean, and to remove odors within the dirty radwaste The* Plant would like to be able to utilize the. Alconox Detergent 8 product during the next scheduled outage starting April 24, 1998. The usage of Alconox Detergent 8 would save the Plant up to $200,000 in cost if it could be used during the outage this year. Therefore, the Plant would appreciate it if the Department would expedite the approval for use of the Alconox Detergent 8 by providing it to the Company as soon as possible.
Attachment 3 provides detailed process descriptions on each additive.
Included in Attachment 3 are the associated Material Safety Data Sheets and aquatic toxicity data for each additive . We understand that potential effluent limits can be determined based upon provided aquatic toxicity data for the two new additives requested above. 00398-19.JAC 
* *
* Therefore, no potential effluent quality sampling was performed or is provided.
Outfall 001 Flow Increase -323.1098 Antidegradation Demonstration The Palisades Nuclear Plant is requesting an increase in use of water . ultimately increasing the authorized discharge flow volumes at internal Outfalls OOA and 008, and most importantly Outfall 001 in order to remain a competitive electric facility which is being forced by future deregulation.
Detailed information on the increase request is provided as Attachment A attached in the back of the permit application.
Attachment A is the supplementary information provided in response of the item in the Permit Application,.
Section I, 8. -"Reissuance of Permit" description section. 3 The Company feels that antidegradation only applies when an increase use results when an increase in loadings of pollutants occur. Essentially, increasing flow is "increased use", however, no increase in pollutant loadings will occur as a result of the Palisades Plant increase.
In fact, pollutant loadings associated with the operation of the Palisades Plant will be reduced because of the water volume increase.
The Company has evaluated the influence of the increase on the controlled parameters and has found that the Plant can continue to remain in compliance with current parameter limits applied at Outfall 001 without an increase in loadings.
Therefore, the Act 451 of the Public Acts of 1994, Part 31, Part 4, Rule 1098 antidegradation provisions should not apply in this case. However, the Plant will work with the Department in the future if circumstances arise where the Plant sees that the currently approved water treatment additives are not as effective due to the increase in flow. However, at this time, no modifications to the current treatment approvals are being considered.
Outfall OOE Elimination the last NPDES Permit issuance in 1994, the Palisades Plant has eliminated internal Outfall OOE, the neutralizer tank wastewater outfall. The neutralizer tank was removed from service during 1997 due to lack of use since the Plant no longer performs inhouse acid/caustic regeneration of the demineralizer system. Instead, the Plant contracts or leases trailers which contain cation, anion, and mixed bed resin vessels to supply high purity demineralized water for the Plant. When the trailer is spent, it is contracted offsite and replaced with a new one. All piping feeding and exiting the neutralizer tank have been capped. All associated equipment has been removed from service also . The elimination of the outfall or operational change is exempt from Part IIA2 "Change of Conditions 11 notification requirements because it does not result in a new, different, or increased discharge of pollutants, nor will it result in 00398-19.JAC
_,_ ., __ . * *
* the exceedance of the current effluent limitations specified in the permit. Therefore, a separate written notification beyond this letter will not be provided.
Storm Water Summary The Palisades Plant has a NPDES General Permit for Storm Water MIROOOOOO, Certificate of Coverage MIR70P002 issued November 10, 1994 and expiring January 31, 1999. 4 There are five storm water discharges at the Palisades Plant. Storm Water (SW) discharges SW-2, SW-3 and SW-5 discharge directly to the shoreline of Lake Michigan.
SW-4 discharges to Lake Michigan where it is observed and assessed daily recording total flow when the source (Groundwater Remediation Unit) authorized under the NPDES Permit MI0049131 is in operation.
SW-6 discharges directly to the mixing basin prior to dischargin*g at Outfall 001 to Lake Michigan.
The Palisades Plant is in compliance with the Certificate of Coverage storm water operator, storm water pollution prevention plan development, nonstructural and structural control implementation within the associated required time frames. Attachment 4 provides submittals to the Department verifying compliance with the dates and corresponding requirements.
Mark-Up Copy of The Current NPDES Permit As Attachment 5, the current Palisades NPDES permit is marked-up to include preliminary changes made for the renewed NPDES permit. We thought this may be helpful in defining the areas in the permit were operational changes have been made or will be made at the Plant, to better clarify the requests mentioned above, in the permit application, and the attached supplementary information.
If you have any questions or need additional information, please contact me at (517) 788-1469.
We are looking forward to working with the Department on the Palisades Plant permit renewal process.
,/' t:J A. Crawford Sr Environmental Planner 00398-19.JAC 
,, -D** .Ei.\ -. -Michigan Department of Environmental Quality-Surface Wate* ) WASTEWATER DISCHARGE PERMIT APPLICATION SECTION I -General Information
* (This information is required by the Part 21 Rules of Michigan Act 451, Public Ads of 1994, as amended, Part 31. A municipality, business, or industry which violates the Part 21 Rules may be enjoined by action commenced by the Attorney General in a court of competent jurisdiction.)
See the facing page for instructions on completing page 1. PLEASE TYPE OR PRINT 1. NPDES PERMrT or COC NUMBER MI0001457
: 2. APPLICANT NAME AND MAILING ADDRESS Consumers Energy Company Palisades Nuclear Plant plicant ame In ormation William L. Beckman treet 212 W. Michi an Avenue I P22-508A State ZIP Code MI 49201 517788-1 4 6 9 FACILITY NAME AND LOCATION Latitude (to the nearest 15 seconds) 42° 19' 23" Longitude (to tile nearest 15 seconds) 86° 18' 56" elephone (with area code) (616)764-2000
: 7. DISCHARGE MONrTORING REPORT (OMR) FORMS 4. FACILITY MAILING ADDRESS Street Address or P.O. Box (or check box to use address corresponding to item number 02 Palisades Nuclear Plant . . Box nformation
: 5. CONTACT PERSON Name Jennifer A. Crawford Sr Environmental Planner ADDRESS Street Address or P.O. Box (or check box to use address corresponding to item number 03 04) 1945 W. Parnall Road 4 6 9 3 2 9 0 No W003010 Ched( the box that corresponds to the address (above) to which Discharge Monitoring Reports (DMRs) should be mailed. 0 2 -Applicant Name & Mailing Address 0 3 -Facility Name & Location 0 4 -Facility Malling Address rsl 5 -Contact Person SEND DMRs TO THE ATTENTION OF: Kenneth F. Bieszke P22-534 8. PERMIT ACTION REQUESTED (Check one box only) 0 a NEW, proposed discharge
("New Usej: D an EXISTING discharge currently unpermitted. RElSSUANCE of current permit. Check here If the permit reissuance proposes an increased loading of pollutants to the surface waters of the state ("Increased Usej. Describe the proposed "increased use": Increased intake and discharge volume -See Attachment A in the back of this permit application 0 MODIFICATION of current permit. D Check here If the request includes an increased loading of pollutants to the surface waters of the state ("Increased Usej. Descnbe the proposed modification: . D GENERAL PERMIT COVERAGE:
Check here if you wish to be considered for coverage under a general permit. (see appendix Table 10) EQP 4659-A (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION I -General Information EASE TYPE OR PRINT .. ACILITY NAME Consumers Energy Company Palisades Nuclear Plant I NPDES PERMIT or CCC NUMBER MI0001457
: 9. RULE 1098 DEMONSTRATION In accordance with Rule 1098 of the Part 4 Rules, the permittee must submit a Rule 1098 Demonstration for any new or increased loadingof pollutants to the surface waters of the state. Has the "New", "Existing Unpermitted", or "Reissuance" (with increased use) or "Modification (with increased use) box in question 8 on page 1 been checked? g] Yes, Submit a 1098 demonstration (refer to Rule 1098 in the appendix for instructions).
Questions should be directed to the appropriate district office.
A-;.., '""L btt of pt.nt'I H &iff J,'c04.*fio"' . 0 No, Continue with Item 10. 10. OTHER ENVIRONMENTAL PERMITS Provide the information requested below for any other federal, state or local environmental permits in effect or applied for at the time of submittal of this application form; including, but not limited to, permits issued under any of the following programs:
Air Pollution Control, Hazardous Waste Management, Wetlands Protection, Soil Erosion and Sedimentation Control, and other NPDES permits. Include any additional information on 8 112" x 11" paper as an attachment to this application.
l...,;uinqA enc Pem1i1 or CO Nun1bE*r """"' T 'P MDEQ, Surface Water Quality MIR.70P002 Storm Water General Permit MDEQ, Air Quality 199600476 ROP Federal EPA, RCRA MI098644685 Hazardous Waste
* 11. WATER FLOW DIAGRAM AND NARRATIVE DESCRIPTION Provide a flow diagram (using 8 112" x 11" paper if possible) showing the wastewater flow through the facility including all treatment units, processes and bypass piping, and a narrative description of the water flow through the facility from intake to discharge.
Show all operations contributing wastewater and the locations of flow meters, chemical feeds and disdlarge points. The water balance shall show daily average flow rates at intake and discharge points and approximate daily flow rates between treatment units including influent and treatment rates. Use actual measurements whenever available, otherwise use your best estimate.
Show all significant losses of water to products, atmosphere and disdlarge.
Municipal Facilities
-Include a narrative that briefly describes the history of the wastewater treatment facility.
Include information describing when it was first constructed, what improvements have been made, future plans for upgrade, and other pertinent information . . Industrial and Commercial Facilities
-The line diagram shall include all operations contributing wastewater including process and production areas, sanitary flows, cooling water and storm water runoff. Include a narrative which provides a brief description of the manufacturing processes.
ATTACH THIS INFORMATION TO THIS APPLICATION
: 12. MAP OF FACILITY AND DISCHARGE LOCATION Provide a detailed map on 8 112* x 11" paper showing the location of the existing or proposed facility, wastewater treatment system(s), and wastewater disdlarge points into receiving waters (including bypasses).
Include the exact location of the wastewater discharge point(s) and all areas through which the discharge flows (e.g. wetlands, open drains, storm sewers), if applicable, between the discharge point and the receiving water. If the discharge is to a storm sewer, label the storm sewer and show its flow path to the receiving water. Also include the ' location of any water supply wells and groundwater monitoring wells. This map shall be a United States Geological Survey Quadrangle (7.5 minute series) or other map of comparable detail, scale and quality (which shows surface waterbodies, roads, and other pertinent landmarks).
The minimum area this map shall encompass is approximately one mile beyond property boundaries.
ATTACH THIS INFORMATION TO THIS APPLICATION 2 EQP 4659-A (Rev 1/98)
* Pl">! l"take 234.5 MGD I Outfall 001 1-----1 I to Lake Michigan EXIBIT 1-11 Schematic of Water Flow Consumers Energy company Palisades Nuclear Plant NPDES Permit MI0001457
____________________ .Q.Q9 ______________ , OOF i 251.78 MGD Al 00C I
* r I Mixing Basin -* I i.--------------1-1
: Turbine Sump Tank T-41 * *"i .. i Dilution Water Pumps Plant Intake Screens ... House Service Water System t I : I I I I I I I I
: : : OOA 008 : i I I I I I I I I I ______ _ I I -I 1 I I 'A' Cooling Tower Pump Suction Basin 'A' Cooling Tower .... ,, 'B' Cooling Tower Pump Suction Basin . *Ir 'B' Cooling Tower ----------
-----.-----
----_____ ,. ' Evaporation 8.640MGD ' ** Evaporation 8.640MGD Cooling Tower Slowdown I I I I I I I I I I I I I I I I I I I I I I I -1 I -I I I I I I I I . I I r I I I I I I I
* I I I I I I I I I I : I ' I I I I ....
* Turbine Condenser i.--j I I I Hot Well --Feedwater Heater Train ---14--------, I I I ----'"----1 Turbine Sump Oil Seperator I I I I I I a I I I ________ J Turbine Building sump ----1------1
'"' ... I Plant Heating System ....
Steam ----Generators
---I I ,. ' I I I I I I I Make-up Water System Deep welH---_.
Primary System Radwaste System Evapoators I I I I I I I I I I I I I I I I I ..__ _____
* Clean Dirty _l_ ______ L __ System System *-------------------
: I l + I I I Condensate Tank T-2 I I I I -I I *-+------...! I I I I I
---------..-:
---t---------------------1,---
Primary Make-up TankT-91 Domestic Water System Primary System Demineralized Storage Water Storage t..--Utility Water Storage TankT-91 Tank T-90 Tank T-939
* I I I Drain Field Continuous Flow lntermittant Flow----------..
Revised 3/27/98 KFBieszke i:;xh:i,bit I-12
* of Facility & Discharg ;
Nuclear Permit MI0001457
*.*:.** ... . . .. *** .. * *"*'"" .. '
.. .. * .. . .j"'*** ... .. ,,,. ..... ,., --....c:.-*-
-*
* Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION I -General Information .SE TYPE OR PRINT CILITYNAME PERMIT or COC NUMBER nsumers Energy Comoanv Palisades Nuclear Plant 0001457 13. LIST ADJACENT PROPERTY OWNERS List the names and addresses of all property adjacent to the facility, treatment systems, and discharge locations.
List this information in the space provided below or include the information as an attachment on 8 112" x 11* paper. If additional space is necessary, copy this blank page and attach this information to this application.
Name Street Address/P
.0. Box City State ZIP Code State of Michigan/Van Buren State Prlc 23 960 RUl'l'les Road South Haven MI 49090 Palisades Country Club/Harold Vandersalm II 1324 Meadow Brook Line Kalamazoo MI 49001 ' 3 EQP 4659-A (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION I -General Information CILITYNAME onsumers Ener 14. AL TERNA TE POWER SOURCE NPDES PERMIT or COC NUMBER 0001457 If you are applying for a New or Existing Unpennitted discharge, continue to Item 15. Applicants with an approved Alternate Power Source Report shall indicate any changes that have been made to the alternate power source serving the facility in the past 5 years. Submit the new information with the application and provide specific information regarding the appropriate pump station or treatment unit the alternate power source serves. A. Indicate if the facility has a back-up source of power and if emergency procedures have been developed in case of a power outage to the facility.
0 Yes, Continue to B. D No, Continue to Item 15. Not Applicable, Continue to Item 15. B. Has an Alternate Power Source Report been approved by the DEQ? D Yes, Continue to C. D No, Continue to Item 15. C. Have changes been made that have not been reported to DEQ since the Report was approved?
D Yes, Submit the information as an attachment to this application.
D No, Continue to Item 14. 15. RESIDUALS A. Are residuals (biosolids, sludges, ash, grit, etc.) generated as a result of wastewater treatment?
0 Yes, Continue to B. No, Continue with Section II or Section Ill. B. Are the residuals regulated under Michigan Ad 451, PA of 1994, as amended, Part 111 (Hazardous Waste Management) or Part 115 {Solid Waste Management)?
0 Yes, Continue to C. 0 No, Continue with Section II or Seetion Ill. C. Briefly describe the residuals stabilization processes and the final use or disposal method: ----------------
D. Has a Program for Effective Residuals Management (PERM) been approved by DEQ? 0 Yes 0 No E. Estimate the amount of residuals the facility generates (on a dry weight basis). ------tons per year F. Enter the volume of residual storage capacity at this facility.
0 million gallons or 0 cubic feet G. Submit a copy of the most recent residuals analyses (both nutrient and pollutant, if available).
H. Provide the name, address and telephone number of the Land Application Contractor used by the facility, if applicable.
Name of Contractor:
Address: City, State, Zip Code: Telephone Number: IS completes Section I. Facilities requesting authorization to only discharge sanitary wastewaters continue with tion II. Other facilities requesting authorization to discharge wastewater continue with Section Ill. Section I shall accompanied by either Section II or Section Ill of this application.
If you need assistance in determining the appropriate Sections to complete, contact the district office (see Pages 1 and 2 of the appendix for district office addresses and a map of district boundaries).
4 EQP 4659-A (Rev 1/98)
Dlt\ Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION
* SECTION Ill -Industrial and Commercial Wastewater A Facility Information Section Ill is to be completed by all facilities classified as Industrial or Commercial facilities.
Industrial and Commercial facilities include facilities that discharge or propose to discharge a wastewater generated by a production process or service provided or through a remediation project. Municipal and public facilities are not required to complete Section Ill (unless requesting authorization for discharges other than sanitary wastewater).
PLEASE TYPE OR PRINT FACILITY NAME Consumers Ener Com an Palisades Nuclear Plant 1. BUSINESS INFORMATION NPDES PERMIT or COC NUMBER 0001457 A. Provide up to four (4) Standard Industrial Classification (SIC) 11. 12. 1 3.* 1 4* codes, in order of economic importance, which best describe the major products or services provided by this facility.
* L.:4..:..9..::1..::1
___ --L------L-------L--------J B. Indicate if this facility is a primary industry (refer to Table 2 to determine if this facility is a primary industry). Yes, This facility is a primary industry.
Indicate the primary industry as identified in Table 2 in the appendix:
Steam Electric Generator 0 No, This facility is not a primary industry, continue with Item C. C. Do you operate a concentrated animal feeding operation or an aquatic animal production facility?
D Yes, Contact the appropriate district office (see Pages 2 and 3 in the appendix). No, Continue below. 2. WATER SUPPLY AND DISCHARGE TYPE A. List all water sources and provide average flows. The volume may be estimated from water supply meter readings, pump capacities, etc. Provide the name of the source where appropriate (i.e., Grand River, Lake Michigan, City of Millpond).
The units are as follows: MGD (million gallons per day), MGY (million gallons per year), GPO (gallons per day). If you are reporting in another unit, select the box with the blank following it and provide the units in the underlined area. If necessary, provide a written description as an attachment on 8 112" x 11" paper. Name of Source Averaae Volume or Flow Rate (indicate units) UMGD UMGY . Municipal Supply: NIA 0GPD D LJMGY Surface Water Intake: Lake Michigan 148.3 0GPD D UMGY Private Well: Groundwater
.053 0GPD D DMGY Other (specify) . Sanitary Wastewater
.053 DGPD D B. Identify water discharged by the facility and provide average flows. If water is first used for one purpose and then is subsequently used for another purpose, indicate the type and amount of the last use. For example, if water is initially used for noncontact cooling water and then for process water, indicate the amount of process water. The amount of water from sources should approximate the amount of water usage. If they are different.
provide an explanation Average Flow Rate Average Flow Rate MGY GWCU D_ GWCU -stands for Ground Water Clean-Up, HPTW -stands for Hydrostatic Pressure Test Water 15 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
* B. Outfall Information mplete a separate Section 111.B; -Outfall Information (pages 17-24) for each outfall at the facility.
Make copies of this blank section of the application if necessary.
PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT or COC NUMBER MI0001457
* Palisades Nuclear Plant Receiving Water A. Receiving Water: Lake Michigan County I Township Van Buren Covert B. County/Township:
C. State Planar Coordinates:
SE 1/41 NW 1/41 Section 05 I Town 028 I Range 17W Latitude I Longitude 42° 19' 31" 86° 19' 41" D. Latitude/Longitude:
E. Type of Wastewater Discharged (Check all that apply): 0 Contact Cooling 0 Noncontact Cooling 0 Sanitary Wastewater 0 Process Wastewater 0 Storm Water (regulated) other -specify Plant Intake 0 Storm Water (not regulated)
F. Is this a Seasonal Discharge?
0 Yes -List the discharge periods (by month) in the space provided below. From Through From From Through From G. Discharge Schedule (Yearly Average):
IN/A H. Expected or Proposed Discharge Flow Rates: Total Yearly Daily Minimum Daily Average NIA MGY MGD MGD I. The maximum discharge flow rate to be authorized in the permit _N_I A ___ _ J. Does this discharge contain storm water subject to effluent guidelines?
0 Yes -indicate under which category.
17 No -Continue with item G Through Through hours/day I days/year I Daily Maximum Maximum Design Flow Rate MGD MGD 0 GPO 0 MGD 0 MGY 0 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
* B. Outfall Information mplete a separate Section 111.B. -Outfall lnfonnation (pages 17-24) for each outfall at the facility.
s blank section of the application if necessary.
Make copies of PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT or COC NUMBER: OUTFALL NUMBER 000 Intake Consumers Energy Company, Palisades Nuclear Plant MI0001457
: 4. WATER TREATMENT ADDITIVES Intake ; i A Is there a discharge of any water treatment additives or chemicals used to treat water and/or wastewater used or generated by this facility ? No -Continue with Item 5. D Yes -Provide the following information for each additive.
Provide the Material Safety Data Sheets (MSDS) for each additive as an attachment to this application.
Enter the product name of the additive and name of the manufacturer.
Describe the function of the additive, e.g., biocide, corrosion inhibitor, etc. Provide the average and maximum proposed discharge concentrations of the additive.
Enter the concentrations of the proposed additives after all treatment has occurred.
If the actual proposed discharge concentrations are not known, an estimate shall be made using stoichiometry and/or a mass balance. Provide the proposed discharge frequency in hours per day and days per week or year. Discharge Concentrations Product Name/Name of Manufacturer Additive Function Average Maximum Discharge Frequency Uµgll Uµg11 hours/day Odays/wk OmgJI Omg11 0days/yr Uµg11 Uµgll hours/day Odayslwk Oman Omgn 0days/yr Uµgll Oµgll . hours/day Odays/wk Omgll Omg11 0days/yr Uµgll Uµgll hours/day Udays/wk Omg11 Omgll 0days/yr Uµgll Uµgll hours/day Udayslwk Omg11 Omg11 0days/yr Oµgll Uµg/I hours/day Udays/wk Omg11 Omg/I 0days/yr Oµgll Oµg11 hours/day Udays/wk Omg/I Oma/I . 0davs/vr Uµgll Oµg11 hours/day Odays/wk Omg11 Omg11 0days/yr B. Table 11 contains a list of the additives for which the DEQ currently has sufficient toxicological data. If the additive this facility is proposing to discharge is not included in Table 11, call the Surface Water Quality Division, Great Lake and Environmental Assessment section at 517-335-4184 to inquire about the status of the specific water treatment additive prior to providing any additional information.
If the DEQ does not have sufficient toxicological information for any additive being proposed for discharge at this facility, the applicant must provide a 48-hour EC50 for a North American planktonic crustacean (Daphnia SP** Ceriodaphnia sp. or Simocephalus sp.) and the results of a toxicity test for one other North American Freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards.
The water treatment additive will not be evaluated for discharge authoriZation unless the appropriate information is attached.
D Aquatic toxicity data is attached.
C. If the discharge is treated to remove any of the above additives prior to discharge, indicate which additive the treatment is for and briefly describe the treatment process: 18 EQP 4659-C (Rev 1/98) r, Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
*
* B. Outfall Information mplete a separate Section 111.B. -Outfall lnfoi'mation (pages 17-24) for each outfall at the facility.
s blank section of the application if necessary.
Make copies of PLEASE TYPE OR PRINT FACILITY NAME I NPDES PERMIT or COC NUMBER I OUTFALL NUMBER Consumers Energy Company, Palisades Nuclear Plant MI0001457 000 Intake 5. PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE Intake This information is used to determine the applicable federal regulations for this discharge.
The information required to be reported is dependent on the type of facility.
Page 11 of the appendix contains an abbreviated list of various industries and the types of information each shall report in this application.
Assistance can be received by calling the appropriate district office (see pages 1 and 2 of the appendix).
All industries shall provide the name of each process and the Standard Industrial Classification (SIC) code for the process. If the wastestream is not regulated under federal categorical standards, the applicant shall report all pollutants which have the reasonable potential to be present in the discharge.
PROCESS INFORMATION A. Name of the process contributing to the discharge:
NIA-Intake B. SICcede: C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
PROCESS INFORMATION A. Name of the process contributing to the discharge:
B. SIC cede: c. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
PROCESS INFORMATION A. Name of the process contributing to the discharge:
B. SIC cede: C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
PROCESS INFORMATION A. Name of the process contributing to the discharge:
B. SICcode: . C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
PROCESS INFORMATION A. Name of the process contributing to the discharge:
B. SIC cede: f C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
19 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
* . B. Outfall Information a separate Section 111.B.-Outfall Information (pages 17-24) for each outfall at the facility.
Make copies of ....ris blank section of the application if necessary.
PLEASE TYPE OR PRINT FACILITY NAME I NPDES or COC PERMIT NUMBER Consumers Energy Company, Palisades Nuclear Plant MI0001457
: 6. WASTEWATER CHARACTERISTICS
-CONVENTIONAL POLLUTANTS Instructions for completing this page are on the facing page. Check this box if additional information is included as an attachment.
Maximum Maximum Parameter Daily Monthly Concentration Concentration Biochemieal Oxygen Demand
* five day (800 5) *(2) COD (Chemical oxygen demand) *<2) TOC (Total organic carbon) *(2) Ammonia Nitrogen (as N) *(2) Total Suspended Solids *(2) Total Dissolved Solids *(2) Total Phosphorus (as P) *(2) .cal Coliform Bacteria maximum-7day
*(2) Total Residual Chlorine *(2) minimum daily Dissolved Oxygen *(2) pH minimum maximum (report maximum and minimum of individual samples) 7.8 *(l) 7.8 Temperature, Summer 54 *(l) 75 Temperature, Winter 46 *(l) 65 Oil & Grease *(2) *(l) Values are based onDMR data *(2) The Company is requesting a waiver from this reporting requirement 21 Units mg/I mg/I mg/I mall mg/I mg/I mg/I counts/100mf 0 mg/I 5(l &#xb5;a.II mg/I Standard Units *F D *c *F D *c mg/I ug/I mg/I I Outfall Number 000 Intake Intake Number of Analyses Sample Type D Grab D 24 Hr Comp LJ Grab D 24 Hr Comp [J Grab D 24 Hr Comp 0 Grab 0 24HrComp D Grab D 24 Hr Comp D Grab D 24HrComp LJ Grab C 24 Hr Comp Grab Grab Grab 1 Grab 3672 Grab 5088 Grab Grab LJ Grab D 24 Hr Comp LJ Grab D 24 Hr Comp 0 Grab D 24 Hr Comp LJ Grab D 24 Hr Comp LJ Grab D 24HrComp 0 Grab D 24 Hr Comp U Grab D 24 Hr Comp EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
: 8. Outfall Information a separate Section 111.B. -Outfall Information (pages 17-24) for each outfall at the facility.
Make copies of blank section of the application if necessary.
PLEASE TYPE OR PRINT FACILITY NAME Consumers Energy Company, Palisades Nuclear Plant NPDES or COC PERMIT NUMBER MI0001457 OUTFALL NUMBER 000 Intake 7. PRIMARY INDUSTRY TOXIC POLLUTANT INFORMATION Intake COMPLETE THIS ITEM ONLY IF THE FACILITY IS A PRIMARY INDUSTRY AS INDICATED IN ITEM 1 OF THIS SECTION. IF THIS IS NOT A PRIMARY INDUSTRY, CONTINUE WITH ITEM 8. For two or more substantially identical outfalls, permission may be requested from the appropriate district supervisor to sample and analyze only one outfall and submit the results of the analysis for other substantially identical outfall(s).
If the request is granted by the District Supervisor, attach a narrative describing which outfall was sampled, and describe why the outfalls which were not sampled are substantially similar to the outfall that was sampled. A. Indicate if the discharge from this outfall contains any process wastewater.
If the discharge from this outfall contains process wastewater, check YES and continue with B below. If the discharge from this outfall does not contain any process wastewater, check NO and continue with item 8. Does this outfall discharge contain any process wastewater?
D Yes, Continue with B. No, Continue with Item 8* See Intake 000 results, Attachment C of this application B. Primary Industries must submit test results for organic toxic pollutants.
Table 2 in the appendix contains a list of GC/MS fractions required by each industrial Category.
Indicate the GC/MS fractions required for the facility Industrial Category. Volatile Base/Neutral Acid D Pesticide Provide analytical data for each parameter of the GC/MS fraction checked above. The required parameters in each fraction are specified in Table 3 in the appendix.
Provide copies of the analytical results or record the information in Item 9. Additionally, all primary industries which discharge process wastewater shall provide quantitative data for the parameters specified in Table 4 in the appendix.
Applicants are not required to analyze for 2,3,7,8-TCDD (Dioxin) unless they believe it is present in the discharge.
ADDITIONAL TOXIC POLLUTANT INFORMATION A. If an applicant, regardless of the type of discharge, knows or has reason to believe that any pollutant listed in Tables 3, 4, 5, 7 and 8 is discharged from any outfall, then quantitative data shall be provided for those pollutants. Not Applicable/Believed Absent D Present -Data is attached or recorded in Item 9. B. If an applicant (primary or secondary industry), regardless of the type of discharge, knows or has reason to believe any pollutants listed in Table 6 are discharged from any outfall, the applicant shall describe reasons for the pollutant being present and provide any available quantitative data. Not Applicable/Believed Absent D Present -Data is attached or recorded in Item 9. C. All applicants (primary and secondary industries) who use or manufacture 2,4,5-trichlorophenoxy acetic acid (2,4,5-T);
2-(2,4,5-trichlorophenoxy) propanoic acid (Silvex);
2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloroproprionate (Erbon); 0,0-Dimethyl 0-(2,4,5-Trichlorophenyl)
Phosphorothioate (Ronnel);
2,4,5-trichlorophenol (TCP); or Hexachlorophene (HCP) must report data using standard analytical calibration procedures.
All surface water discharge applicants (primary and .secondary industries) who know or have reason to believe that 2,3, 7,8-Tetrachlorodibenzo-P-Dioxin (TCDD) is or may be present in their discharge must report qualitative data generated using a screening procedure not calibrated with analytical standards forTCDD. Not Applicable/Believed Absent D Present -Data is attached or recorded in Item 9. D. If the applicant knows or has reason to believe that biological tests (including WET tests) were made in the last three (3) years on any of the applicant's discharges or on a receiving water in relation to the discharge(s), provide this information as an attachment to this application. Not Applicable D Applicable
-Data is attached.
E. If a contract laboratory or consulting firm performed any of the analyses required by this application, provide the name and address of each laboratory or firm as an attachment to this application.
See Attachment B in the back of this D Not Applicable Applicable
-Information is provided.
Permit Application F. Does the facility discharge any other toxic or injurious chemical substances not listed in Tables 3 through 9 in the appendix? No. Continue with Section 111.C. 0 Yes. Data is attached or recorded in Item 9. 22 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater . B. Outfall Information mplete a separate Section 111.B. -Outfall Information (pages 17-24) for each outfall at the facility.
s blank section of the application if necessary.
Make copies of PLEASE TYPE OR PRINT FACILITY NAME I NPDES or COC PERMIT NUMBER I OUTFALL NUMBER Consumers Energy Company, Palisades Nuclear Plant: MI0001457 000 Intake 9. EFFLUENT CHARACTERISTICS
* TOXIC POLLUTANTS Intake This worksheet is to be used by applicants to record information on any Michigan Critical Material, EPA Priority Pollutant, or hazardous substance for which this application requires that data be provided.
This includes any substance from Table 3 which lists Organic Toxic Pollutants, Table 4, Other Toxic Pollutants, Table 5, Conventional and Nonconventional Pollutants, Table 6, Toxic Pollutants and Hazardous Substances, Table 7 the Michigan Critical Materials Register, or Table 8 the EPA Priority Pollutant Listing. If the applicant believes a pollutant may be present in the effluent that is not included in these lists, data shall be provided for that pollutant with this application.
This information may also be included as an attachment to this application on 8 112" x 11" paper. Page 12 of the appendix is a list of minimum testing requirements for various dischargers.
As a minimum applicants for those types of discharge must provide analytical data based on that list. Applicants shall use EPA approved analytical methods when conducting sampling.
For each parameter provide the name of the parameter as listed in the Tables, the maximum daily and monthly discharge concentrations, units, the number of analyses p_erformed, and the sample type. If analytical results for a composite sample are being provided and the sample is not a 24'-hour composite, include a description of the sample collection technique used as an attachment to this application on 8 112* x 11" paper . .When calculating an average where some values are detectable and others are nondetectable, either provide the actual data, or regard each nondetectable value as the detection level when calculating concentrations and indicate that the result is "less than" the value reported. (See definitions of "daily concentration" and "monthly concentration" in the general provisions at the front of this form.) Please include an explanation if "Pollution Prevention" is expected to provide reductions of pollutants. (See page ii and iii for sampling definitions, including, "daily concentration", and "monthly concentration".)
See Table 12 in the appendix for acceptable "Levels of Quantification". Check this box if additional information is included as an attachment.
See Attachment C in the back of this permit application Maximum Maximum Dally Monthly Quantification Number Concentration Concentration Level of Sample Toxic Pollutant (uQ/ll tualn Analyses TvDe LJ Grab NIA-Intake 0 24 Hr Comp 0 Grab 0 24 Hr Comp D Grab D 24 Hr Comp LJ Grab 0 24HrComp LJ Grab 0 24HrComp LJ Grab 0 24 Hr Comp 0 Grab 0 24HrComp 0 Grab 0 24 Hr Comp LJ Grab 0 24 Hr Comp LJ Grab 0 24 Hr Comp 0 Grab 0 24HrComp 0 Grab 0 24 Hr Comp ' LJ Grab D 24HrComp 0 Grab 0 24 Hr Comp 23 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
* B. Outfall Information omplete a separate Section 111.B.-Outfall Information (pages 17-24) for each outfall at the facility.
Make copies of this blank section of the application if necessary.
PLEASE TYPE OR PRINT FACILITY NAME I NPDES or COC PERMIT NUMBER I OUTFALL NUMBER Consumers Energy Company, Palisades Nuclear Plant MI0001457 000 Intake 10. TOXIC POLLUTANT REASONABLE POTENTIAL EFFLUENT DATA Intake In addition to the above information and in accordance with Rule 1211 of the Part 8 Rules (see pages 7-10 in the appendix}, for each toxic substance which is or may be discharged from the facility, the applicant must provide individual sample data to determine if Water Quality Based Effluent Limits (WQBELs) are necessary.
WQBELs for toxic pollutants are incorporated into an NPDES permit when the, DEQ has determined that a substance is or may be discharged into the waters of the state at a level that has a reasonable potential to exceed the substance's water quality value. The determination is made by developing a preliminary effluent limit (PEL) and comparing it to the potential effluent quality (PEQ) of the discharge.
The DEQ will determine the PELs for every toxic substance the permittee reports as being present in their discharge.
The PEQ for each toxic substance will be developed using individual sample results provided by the permittee.
If the permittee provides at least 10 representative facility-specific effluent samples that are greater than the detection limit, the maximum PEQ shall equal the upper 95th percentile of all the representative daily discharge concentrations and the average PEQ shall equal the upper 95th percentile of all the representative 30-day average concentrations.
Reasonable potential for the discharge of a toxic substance to cause or contribute to an excursion above any water quality value will be considered to exist if the average or maximum PEQ exceeds any of the chronic or acute PELs, respectively.
If the permittee is unable to provide 10 effluent samples that are greater than the detection level, the PEQ shall be .determined by identifying the total number of representative effluent samples, both detectable and nondetectable, and multiplying the maximum reported value by a multiplying factor found in Table 3 of Rule 1211, (see page 8 in the appendix).
List both detectable and nondetectable results. Where a result is nondetectable indicate the detection level. Reasonable potential for the discharge of a toxic substance to cause or contribute to an excursion above any water quality value will be considered to exist if the PEQ for a pollutant exceeds its PEL. Attach additional sheets where there are more than ten (1 O) analytical results. If it is determined that the toxic substance concentration has a reasonable potential to cause or contribute to an excursion above any water quality value, then a WQBEL for that substance will be incorporated into the NPDES permit Samples (ug/I) Toxic Pollutant I 2 3 4 5 6 7 8 9 10 NIA -Intake Are any of the above listed toxic pollutants present in the facility's supply water? D No, Continue to next question.
D Yes, Please read below In accordance with Rule 1211 (7) facilities whose supply water contains toxic pollutants that are withdrawn from and discharged to the same body of ater may qualify for intake credits for those toxic pollutants.
See Rule 1211 (7) for qualification and demonstration requirements.
24 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
-B. Outfall Information mplete a separate Section 111.B.-Outfall Information (pages 17-24) for each outfall at the facility.
t s blank section of the application if necessary.
Make copies of PLEASE TYPE OR PRINT FACIUlY NAME I NPDES or COC PERMIT NUMBER I OUTFALL NUMBER Consumers Energy Company, Palisades Nuclear Plant MI0001457 ooc 10. TOXIC POLLUTANT REASONABLE POTENTIAL EFFLUENT DATA CTBlowdown In addition to the above information and in accordance with Rule 1211 of the Part 8 Rules (see pages 7-10 in the appendix), for each toxic substance which is or may be discharged from the facility, the applicant must provide individual sample data to determine if Water Quality Based Effluent Limits (WQBELs) are necessary.
WQBELs for toxic pollutants are incorporated into an NPDES permit when the DEC has determined that a substance is or may be discharged into the waters of the state at a level that has a reasonable potential to exceed the substance's water quality value. The determination is made by developing a preliminary effluent limit (PEL) and comparing it to the potential effluent quality (PEC) of the discharge.
The DEC will determine the PELs for every toxic substance the permittee reports as being present in their discharge.
The PEQ for each toxic substance will be developed using individual sample results provided by the permittee.
If the permittee provides at least 10 representative facility-specific effluent samples that are greater than the detection limit, the maximum PEC shall equal the upper 95th percentile of all the representative daily discharge concentrations and the average PEQ shall equal the upper 95th percentile of all the representative 3Ck:lay average concentrations.
Reasonable potential for the discharge of a toxic substance to cause or contribute to an excursion above any water quality value will be considered to exist if the average or maximum PEQ exceeds any of the chronic or acute PELs, respectively.
If the permittee is unable to provide 10 effluent samples that are greater than the detection level, the PEQ shall be determined by identifying the total number of representative effluent samples, both detectable and nondetectable, and multiplying the maximum reported value by a multiplying factor found in Table 3 Rule 1211, (see page 8 in the appendix).
List both detectable and nondetectable results. Where a result is nondetectable indicate the detection level. Reasonable potential for the discharge of a toxic substance to cause or contribute to an excursion above any water quality value will be considered to exist if the PEQ for a pollutant exceeds its PEL. Attach additional sheets where there are more than ten (10) analytical results. If it is determined that the toxic substance concentration has a reasonable potential to cause or contribute to an excursion above any water quality value, then a WCBEL for that substance will be incorporated into the NPDES permil Samples (ug/I) Toxic Pollutant I 2 3 4 5 6 7 8 9 10 NIA-Internal Outfall Are any of the above listed toxic pollutants present in the facility's supply water? D No, Continue to next question.
D Yes, Please read below In accordance with Rule 1211 (7) facilities whose supply water contains toxic pollutants that are withdrawn from and discharged to the same body of water may qualify for intake credits for those toxic pollutants.
See Rule 1211 (7) for qualification and demonstration requirements.
24 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
* B. Outfall Information mplete a separate Section 111.B. -Outfall Information (pages 17-24) for each outfall at the facility.
1s blank section of the application if necessary.
Make copies of PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT or COC NUMBER MI0001457 OUTFALi-NUMBER OOD
* Palisades Nuclear Plant Rad waste Receiving Water A. Receiving Water: NI A (Internal discharge to Mixing Basin) County I Township Van Buren Covert B. County/Township:
C. State Planar Coordinates:
SE 1/41 NW 1/41 Section 05 I Town 02S I Range 17W Latitude I Longitude 42&deg; 19' 23" 86&deg; 18' 56" D. Latitude/Longitude:
E. Type of Wastewater Discharged (Check all that apply): 0 Contact Cooling D Noncontact Cooling 0 Sanitary Wastewater Process Wastewater 0 Storm Water (regulated) 0 Other -specify --------0 Storm Water (not regulated)
F. Is this a Seasonal Discharge?
0 Yes -List the discharge periods (by month) in the space provided below. From Through From From Through From G. Discharge Schedule (Yearly Average):
Variable H. Expected or Proposed Discharge Flow Rates: Total Yearly Daily Minimum Daily Average Variable MGY 0 MGD 0 MGD I. The maximum discharge flow rate to be authorized in the pennit: __ O_. l __ _ J. Does this discharge contain storm water subject to effluent guidelines?
0 Yes -indicate under which category.
17 No -Continue with item G Through Through hours/day I Variable days/year , . Daily Maximum Maximum Design Flow Rate 0.1 MGD 0.1 MGD D GPO MGD 0.MGY 0 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
* B. Outfall Information mplete a separate Section 111.B. -Outfall lnfonnation (pages 17-24) for each outfall at the facility.
s blank section of the application if necessary.
PLEASE TYPE OR PRINT Make copies of FACILITY NAME Consumers Energy Company, Palisades Nuclear Plant NPDES PERMIT or COC NUMBER: MI0001457 OUTFALL NUMBER OOD 4. Vl(ATER TREATMENT ADDITIVES Rad waste A. Is there a discharge of any water treatment additives or chemicals used to treat water and/or wastewater used or generated by this facility ? 0 No -Continue with Item 5. Yes -Provide the following information for each additive.
Provide the Material Safety Data Sheets (MSDS) for each additive as an attachment to this application.
Enter the product name of the additive and name of the manufacturer.
Describe the function of the additive, e.g., biocide, corrosion inhibitor, etc. Provide the average and maximum proposed discharge concentrations of the additive.
*Enter the concentrations of the proposed additives after all treatment has occurred.
If the actual proposed discharge concentrations are not known, an estimate shall be made using stoichiometry and/or a mass balance. Provide the proposed discharge frequency in hours per day and days per week or year. Discharge Concentrations Product Name/Name of Manufacturer Additive Function Average Maximum Discharge Frequency U&#xb5;gll U&#xb5;gtl hours/day Odaystwk
* Spectrus NXllOO Biocide
* Omg11
* Omg11
* 0dayslyr
* O&#xb5;g11
* U&#xb5;gll hours/day Odays1wk
* Alconox Detergent 8 Decontamination Soap Dmgn Omgn
* 0days/yr O&#xb5;g11 Ll&#xb5;g/1 hours/day 0days/wk Omg11 Omgn 0days/yr Ll&#xb5;g/1 U&#xb5;gll hours/day Odaystwk Omgn Omgn 0dayslyr lJ&#xb5;g/1 lJ&#xb5;gtl hours/day Odays/wk Omg11 Omg11 0davs/yr U&#xb5;gll lJ&#xb5;g/I hours/day Odays/wk Omgtl Omg/I 0davs/yr U&#xb5;gn U&#xb5;g11 hours/day 0days/wk Omgtl Omg/I 0days/yr U&#xb5;g11 U&#xb5;g11 hours/day 0days/wk Omgn Omg11 0days/yr 8. Table 11 contains a list of the additives for which the DEQ currently has sufficient toxicological data. If the additive this facility is proposing to discharge is not included in Table 11, call the Surface Water Quality Division, Great Lake and Environmental Assessment section at 517-335-4184 to inquire about the status of the specific water treatment additive prior to providing any additional information.
If the DEQ does not have sufficient toxicological information for any additive being proposed for discharge at this facility, the applicant must provide a 48-hour EC50 for a North American planktonic crustacean (Daphnia sp., Ceriodaphnia sp. or Simocephalus sp.) and the results of a toxicity test for one other North American Freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards.
The water treatment additive will not be evaluated for discharge authoriZation unless the appropriate information is attached.
181 Aquatic toxicity data is attached.
Requesting approval for use in this permit application C. If the discharge is treated to remove any of the above additives prior to discharge, indicate which additive the treatment is for and briefly describe the treatment process: No treatment will occur to remove either additive.
Both additives are believed to be removed by system demand prior to discharging from the internal Outfall to the mixing basin eventually reaching Outfall 001.
* See Attachment 3 of the-transmittal letter permit renewal application package for detailed information.
18 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
* * *
* B. Outfall Information mplete a separate Section 111.8. -Outfall lnfonnation (pages 17-24) for each outfall at the facility.
s blank section of the application if necessary.
* Make copies of PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT or COC NUMBER OUTFALL NUMBER Consumers Energy Company, Palisades Nuclear Plant MI0001457 OOD 5. PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE Radwaste This information is used to determine the applicable federal regulations for this discharge.
The information required to be reported is dependent on the type of facility.
Page 11 of the appendix contains an abbreviated list of various industries and the types of information each shall report in this application.
Assistance can be received by calling the appropriate district office (see pages 1 and 2 of the appendix).
All industries shall provide the name of each process and the Standard Industrial Classification (SIC) code for the process. If the wastestream is not regulated under federal categorical standards, the applicant shall report all pollutants which have the reasonable potential to be present in the discharge.
PROCESS INFORMATION A. Name of the process contributing to the discharge:
_Ra_d_w_as_te_W_as_t_ew_at_e_r
____________________
_ 8. SIC code: _4_9_11 _____ _ C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
This process removes suspended solids and radioactivity by collection, evaporation distillation and demineralization prior to discharging at Outfall OOD. See Section I, Exhibit I-11 for detailed flow informatioit
* PROCESS INFORMATION A. Name of the process contributing to the discharg_e:
_N_l_A ___________________________
_ B. SIC code:--------
C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
PROCESS INFORMATION A. Name of the process contributing to the discharge:
-----------------------------
B. SIC code:--------
C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
PROCESS INFORMATION A. Name of the process contributing to the discharge:
-----------------------------
B. SIC code:--------
C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
PROCESS INFORMATION A. Name of the process contributing to the discharge:
-----------------------------
B. SIC code:--------
C. Describe the process and provide measures of production (see the instructions to detennine the appropriate infonnation to be reported):
19 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater B. Outfall Information a separate Section 111.B.-Outfall Information (pages 17-24) for each outfall at the facility.
Make copies of ..
section of the application if necessary.
PLEASE TYPE OR PRINT FACILITY NAME I NPDES or COC PERMIT NUMBER I Outfall Number Consumers Energy Company, Palisades Nuclear Plant MI0001457 OOD 6. WASTEWATER CHARACTERISTICS
-CONVENTIONAL POLLUTANTS Rad waste Instructions for completing this page are on the facing page. 0 Check this box if additional information is included as an attachment.
Maximum Maximum Number Parameter Daily Monthly of Concentration Concentration Units Analyses Sample Type D Grab Biochemical Oxygen Demand -five day (800 5)
* mgn D 24 Hr Comp LJ Grab COD (Chemical oxygen demand)
* mg/I 0 24HrComp lJ Grab TOC (Total organic carbon)
* mg/I 0 24 Hr Comp 0 Grab Ammonia Nitrogen (as N)
* mg/I 0 24HrComp D Grab Total Suspended Solids O** 0 mg/I 19 0 24 Hr Comp LJ Grab Total Dissolved Solids
* mg/I 0 24HrComp LJ Grab Total Phosphorus (as P)
* mg/I C 24 Hr Comp .cal Coliform Bacteria maximum-7day NIA counts/1 OOml Grab D mgt1 Total Residual Chlorine
* 1)(1 &#xb5;a/I Grab minimum daily Dissolved Oxygen
* mg/I Grab pH minimum maximum (report maximum and minimum of individual samples)
* Standard Units Grab Temperature, Summer * *F 0 *c Grab Temperature, Winter * *F 0 *c Grab Oil & Grease
* mg/I Grab 1J Grab ugn 0 24 Hr Comp LJ Grab mg/I 0 24 Hr Comp D Grab 0 24HrComp 1J Grab 0 24 Hr Comp 1J Grab D 24HrComp 0 Grab . 0 24HrComp : < 0 Grab 0 24HrComp The Company is requesting a waiver from this reportmg reqmrement
**::
on 1997 DMR data 21 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
-8. Outfall Information
*mplete a separate Section 111.B. -Outfall Information (pages 17-24) for each outfall at the facility.
Make copies of IS blank section of the application if necessary.
PLEASE TYPE OR PRINT FACILITY NAME Consumers Energy Company, Palisades Nuclear Plant NPDES or COC PERMIT NUMBER MI0001457 OUTFALL NUMBER OOD 7. PRIMARY INDUSTRY TOXIC POLLUTANT INFORMATION Radwaste COMPLETE THIS ITEM ONLY IF THE FACILITY IS A PRIMARY INDUSTRY AS INDICATED IN ITEM 1 OF THIS SECTION. IF THIS IS NOT A PRIMARY INDUSTRY, CONTINUE WITH ITEM 8. For two or more substantially identical outfalls, permission may be requested from the appropriate district supervisor to sample and analyze only one outfall and submit the results of the analysis for other substantially identical outfall(s).
If the request is granted by the District Supervisor, attach a narrative describing which outfall was sampled, and describe why the outfalls which were not sampled are substantially similar to the outfall that was sampled. A. Indicate if the discharge from this outfall contains any process wastewater.
If the discharge from this outfall contains process wastewater, check YES and continue with B below. If the discharge from this outfall does not contain any process wastewater, check NO and continue with item 8. Does this outfall discharge contain any process wastewater? Yes, Continue with B. D No, Continue with Item 8. See Outfall 001 results Attachment c ' B. Primary Industries must submit test results for organic toxic pollutants.
Table 2 in the appendix contains a list of GC/MS fractions required by each industrial Category.
Indicate the GC/MS fractions required for the facility Industrial Category.
0 Volatile 0 Base/Neutral 0 Acid 0 Pesticide Provide analytical data for each parameter of the GC/MS fraction checked above. The required parameters in each fraction are specified in Table 3 in the appendix.
Provide copies of the analytical results or record the information in Item 9. Additionally, all primary industries which discharge process wastewater shall provide quantitative data for the parameters specified in Table 4 in the appendix.
Applicants are not required to analyze for 2,3,7,8-TCDD (Dioxin) unless they believe it is present in the discharge.
ADDITIONAL TOXIC POLLUTANT INFORMATION A. If an applicant, regardless of the type of discharge, knows or has reason to believe that any pollutant listed in Tables 3, 4, 5, 7 and 8 is discharged from any outfall, then quantitative data shall be provided for those pollutants.
D Not Applicable/Believed Absent Present -Data is attached or recorded in Item 9. See Outfall 001 results, Attachment C B. If an applicant (primary or secondary industry), regardless of the type of discharge, knows or has reason to believe any pollutants listed in Table 6 are discharged from any outfall, the applicant shall describe reasons for the pollutant being present and provide any available quantitative data. Not Applicable/Believed Absent 0 Present -Data is attached or recorded in Item 9. C. All applicants (primary and secondary industries) who use or manufacture 2,4,5-trichlorophenoxy acetic acid (2,4,5-T);
2-(2,4,5-trichlorophenoxy) propanoic acid (Silvex);
2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloroproprionate (Erbon); 0,0-Dimethyl 0-(2,4,5-Trichlorophenyl)
Phosphorothioate (Ronnel);
2,4,5-trichlorophenol (TCP); or Hexachlorophene (HCP) must report data using standard analytical calibration procedures.
All surface water discharge applicants (primary and secondary industries) who know or have reason to believe that 2,3,7,8-Tetrachlorodibenzo-P-Dioxin (TCDD) is or may be present in their discharge must report qualitative data generated using a screening procedure not calibrated with analytical standards for TCDD. Not Applicable/Believed Absent D Present -Data is attached or recorded in Item 9. D. If the applicant knows or has reason to believe that biological tests (including WET tests) were made in the last three (3) years on any of the applicant's discharges or on a receiving water in relation to the discharge(s), provide this information as an attachment to this application. Not Applicable 0 Applicable
-Data is attached.
E. If a contract laboratory or consulting firm performed any of the analyses required by this application, provide the name and address of each laboratory or firm as an attachment to this_ application.
See Attachment B in the back of this D Not Applicable Applicable
-Information is provided.
Permit Application F. Does the facility discharge any other toxic or injurious chemical substances not listed in Tables 3 through 9 in the appendix ? 18 No. Continue with Section 111.C. D Yes. Data is attached or recorded in Item 9. 22 EQP 4659-C (Rev 1198)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
* . B. Outfall Information mplete a separate Section 111.B. -Outfall lnfonnation (pages 17-24) for each outfall at the facility.
s blank section of the application if necessary.
Make copies of PLEASE TYPE OR PRINT FACILllY NAME I NPDES or COC PERMIT NUMBER I OUTFALL NUMBER Consumers Energy Company, Palisades Nuclear Plant MI0001457 OOD 9. EFFLUENT CHARACTERISTICS
*TOXIC POLLUTANTS Rad waste This worksheet is to be used by applicants to record information on any Michigan Critical Material, EPA Priority Pollutant, or hazardous substance for which this application*
requires that data be provided.
This includes any substance from Table 3 which lists Organic Toxic Pollutants, Table 4, Other Toxic Pollutants, Table 5, Conventional and Nonconventional Pollutants, Table 6, Toxic Pollutants and Hazardous Substances, Table 7 the Michigan Critical Materials Register, or Table 8 the EPA Priority Pollutant Listing. If the applicant believes a pollutant may be present in the effluent that is not included in these lists, data shall be provided for that pollutant with this application.
This information may also be included 'as an attachment to this application on 8 112" x 11" paper. Page 12 of the appendix is a list of minimum testing requirements for various dischargers.
As a minimum applicants for those types of discharge must provide analytical data based on that list. Applicants shall use EPA approved analytical methods when conducting sampling.
For each parameter provide the name of the parameter as listed in the Tables, the maximum daily and monthly discharge concentrations, units, the number of analyses performed, and the sample type. If analytical results for a composite sample are being provided and the sample is not a 24-hour composite, include a description of the sample collection teChnique used as an attachment to this application on 8 112" x 11" paper. When calculating an average where some values are detectable and others are nondetectable, either provide the actual data, or regard each nondetectable value as the detection level when calculating concentrations and indicate that the result is "less than" the value reported. (See definitions of "daily concentration" and "monthly concentration" in the general provisions at the front of this form.) Please include an explanation if "Pollution Prevention" is expected to provide reductions of pollutants. (See page ii and iii for sampling definitions, including, "daily concentration", and "monthly concentration".)
See Table 12 in the appendix for acceptable "Levels of Quantification".
0 Check this box if additional information is included as an attachment.
Maximum Maximum Dally Monthly Quantification Number Concentration Concentration Level of Sample Toxic Pollutant fuam funll\ fua/I) Analvses Type U Grab
* NI A -Internal Outfall D 24HrComp LJ Grab D 24HrComp LJ Grab 0 24HrComp 0 Grab D 24HrComp LJ Grab D 24HrComp LJ Grab D 24HrComp LJ Grab 0 24HrComp lJ Grab 0 24HrComp LJ Grab 0 24 Hr Comp LJ Grab 0 24 Hr Comp 0 Grab 0 24HrComc 0 Grab 0 24HrComp ' 0 Grab 0 24HrComp 0 Grab 0 24HrComp
* See Outfall 001 23 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
-B. Outfall Information . mplete a separate Section 111.8.-Outfall Information (pages 17-24) for each outfall at the facility.
s blank section of the application if necessary.
Make copies of PLEASE TYPE OR PRINT FACILITY NAME I NPOES or COC PERMIT NUMBER I OUTFALL NUMBER Consumers Energy Company, Palisades Nuclear Plant MI0001457 OOD 10. TOXIC POLLUTANT REASONABLE POTENTIAL EFFLUENT DATA Rad waste In addition to the above information and in accordance With Rule 1211 of the Part B Rules (see pages 7-10 in the appendix), for each toxic substance which is or may be discharged from the facility, the applicant must provide individual sample data to determine if Water Quality Based Effluent Limits (WQBELs) are necessary.
-WQBELs for toxic pollutants are incorporated into an NPDES permit when the DEQ has determined that a substance is.or may be discharged into the waters of the state at a level that has a reasonable potential to exceed the substance's water quality value. The determination is made by developing a preliminary effluent limit (PEL) and comparing it to the potential effluent quality.(PEQ) of the discharge.
The OEQ will determine the PELs for every toxic substance the permittee reports as being present in their discharge.
The PEQ for each toxic substance Will be developed using individual sample results provided by the permittee.
If the permittee provides at least 1 O representative facility-specific effluent samples that are greater than the detection limit, the maximum PEQ shall equal the upper 95th percentile of all the representative daily discharge concentrations and the average PEQ shall equal the upper 95th percentile of all the representative 3o-day average concentrations.
Reasonable potential for the discharge of a toxic substance to cause or contribute to an excursion above any water quality value will be considered to exist if the average or maximum PEQ exceeds any of the chronic or acute PELs, respectively.
If the permittee is unable to provide 1 o effluent samples that are greater than the detection level, the PEQ shall be determined by identifying the total number of representative effluent samples, both detectable and nondetectable, and multiplying the maximum reported value by a multiplying factor found in Table 3 of Rule 1211, (see page Bin the appendix).
List both detectable and nondetectable results. Where a result is n!)ndetectable indicate the detection level Reasonable potential for the discharge of a toxic substance to cause or contribute to an excursion above any water quality value Will be considered to exist if the PEQ for a pollutant exceeds its PEL Attach additional sheets where there are more than ten (10) analytical results. If it is determined that the toxic substance concentration has a reasonable potential to cause or contribute to an excursion above any water quality value, then a WQBEL for that substance will be incorporated into the NPDES permit. Samples (ug/I) Toxic Pollutant 1 2 J 4 5 6 7 8 9 10 NI A -Internal Outfall Are any of the above listed toxic pollutants present in the facility's supply water? D No, Continue to next question.
D Yes, Please read below In accordance with Rule 1211 (7) facilities whose supply water contains toxic pollutants that are Withdrawn from and discharged to the same bOdy of ater may qualify for intake credits for those toxic pollutants.
See Rule 1211 (7) for qualification and demonstration requirements.
24 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
* B. Outfall Information mplete a separate Section 111.B. *Outfall Information (pages 17-24) for each outfall at the facility.
Make copies of 1s blank section of the application if necessary.
PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT or COC NUMBER MI0001457 OUTFALL NUMBER OOF
* Palisades Nuclear Plant Turbine Sump Receiving Water A. Receiving Water: NI A (Internal discharge to Mixing Basin) County I Township Van Buren Covert B. County/Township:
C. State Planar Coordinates:
SE 1/41 NW 1/41 Section 05 I Town 02S I Range 17W Latitude I Longitude 42&deg; 19' 23" . 86&deg; 18' 56" D. Latitude/Longitude:
E. Type of Wastewater Discharged (Check all that apply): 0 Contact Cooling 0 Noncontact Cooling D Sanitary Wastewater 181 Process Wastewater 0 Stonn Water (regulated) 0 Other -specify 0 Stonn Water (not regulated)
F. Is this a Seasonal Discharge?
0 Yes -List the discharge periods (by month) in the space provided below. From Through From From Through From G. Discharge Schedule (Yearly Average):
24 H. Expected or Proposed Discharge Flow Rates: Total Yearly Daily Minimum Daily Average 36.5 MGY 0 MGD 0.11 MGD I. The maximum discharge flow rate to be authorized in the permit: __ O_. l __ _ J. Does this discharge contain stonn water subject to effluent guidelines?
0 Yes -indicate under which category.
17 No -Continue with item G Through, Through hours/day I 365 I Daily Maximum Maximum Design Flow Rate 0.1 MGD 0.1 MGD D GPO MGD D MGY 0 181 No EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
* B. Outfall Information mplete a separate Section 111.B. -Outfall lnfonnation (pages 17-24) for each outfall at the facility.
s blank section of the application if necessary.
PLEASE TYPE OR PRINT Make copies of FACILITY NAME Consumers Energy Company, Palisades Nuclear Plant NPDES PERMIT or COC NUMBER: MI0001457 OUTFALL NUMBER OOF 4. WATER TREATMENT ADDITIVES Turbine Sump A. Is there a discharge of any water treatment additives or chemicals used to treat water and/or wastewater used or generated by this facirlty ? 0 No -Continue with Item 5. Yes -Provide the following information for each additive.
Provide the Material Safety Data Sheets (MSDS) for each additive as ari attachment to th!s application.
Enter the product name.of the additive and name of the manufacturer.
Describe the function of the additive, e.g., biocide, corrosion inhibitor, etc. Provide the average and maximum proposed discharge concentrations of the additive.
Enter the concentrations of the proposed additives after all treatment has occurred.
If the actual proposed discharge concentrations are not known, an estimate shall be made using stoichiometry and/or a mass balance. Provide the proposed discharge frequency in hours per day and days per week or year. Discharge Concentrations Product Name/Name of Manufaciturer Additive Function Average Maximum Discharge Frequency U&#xb5;.g11 IXI &#xb5;.g/I hours/day OdayS/wk Sodium Hypochlorite
*
* Omg11
* Omg11
* 0daystyr O&#xb5;g11 U&#xb5;gll hours/day 0days/wk Dmgn Omgn 0days/yr O&#xb5;g11 0&#xb5;.g/I hours/day 0dayS/wk Omgn Omgn 0days/yr U&#xb5;gll U&#xb5;gll hours/day UdayS/wk Omgn Omgll 0davstvr U&#xb5;.g11 U&#xb5;g/I hours/day OdayS/wk Omg11 Dmg11 0days/yr U&#xb5;.gll U&#xb5;.gll hours/day OdayS/wk Omg/I Omg/I 0days/yr U&#xb5;gll U&#xb5;.g11 hours/day OdayS/wk Dme11 Omg/I 0davs/yr U&#xb5;.gll u &#xb5;.g/I hours/day 0days/wk Omgn Omg11 0days/yr B. Table 11 contains a list of the additives for which the DEQ currently has sufficient toxicological data. If the additive this facility is proposing to discharge is not included in Table 11, call the Surface Water Quality Division, Great Lake and Environmental Assessment section at 517-335-4184 to inquire about the status of the specific water treatment additive prior to providing any additional information.
If the DEQ does not have sufficient toxicological information for any additive being proposed for discharge at this facility, the applicant must provide a 48-hour EC50 for a North American planktonic crustacean (Daphnia sp., Ceriodaphnia sp. or Simocephalus sp.) and the results of a toxicity test for one other North American Freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards.
The water treatment additive will not be evaluated for discharge authoriZation the appropriate information is attached.
D Aquatic toxicity data is attached.
See Attachment 2 to the transmittal letter C. If the discharge is treated to remove any of the above additives prior to discharge, indicate which additive the treatment is for and briefly describe the treatment process: We believe the additive will not be present in the Outfall 001 discharge primarily based on demand and is used up in the turbine sump system prior to discharging at Outfall 001.
* Sodium Hypochlorite concentrations are monitored at Outfall 001 18 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
.. B. Outfall Information mplete a separate Section 111.B. -Outfall Information (pages 17-24) for each outfall at the facility.
s blank section of the application if necessary.
PLEASE TYPE OR PRINT Make copies of FACILITY NAME NPDES PERMIT or COC NUMBER OUTFALL NUMBER Consumers Energy Company, Palisades Nuclear Plant MI0001457 OOF 5. PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE Twbine Sump This information is used to determine the applicable federal regulations for this discharge.
The information required to be reported is dependent on the type of facility.
Page 11 of the appendix contains an abbreviated list of various industries and the types of information each shall report in this application.
Assistance can be received by calling the appropriate district office (see pages 1 and 2 of the appendix).
All industries shall provide the name of each process and the Standard Industrial Classification (SIC) code for the process. If the wastestream is not regulated under federal categorical standards, the applicant shall report all pollutants which have the reasonable potential to be present in the discharge.
PROCESS INFORMATION A. Name of the process contributing to the discharge:
_T_wb_in_e_B_uil_*
_din_* -=g'-S_um_._P
___________________
_ B. SIC code: 4911 --------C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
The twbine building sump collects filtered floor drainage from the twbine building which is treated by the oil/water separator prior to discharging to Outfall OOF. See Section I, Exhibit I-11 flow diagram. PROCESS INFORMATION A. Name of the process contributing to the discharge:
_N_l_A ___________________________
_ B. SIC code:--------
C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
PROCESS INFORMATION A. Name of the process contributing to the discharge:
-----------------------------
B. SIC code:--------
C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
PROCESS INFORMATION A. Name of the process contributing to the discharge:
-----------------------------
: 8. SIC code:--------
C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
PROCESS INFORMATION A. Name of the process contributing to the discharge:
-----------------------------
: 8. _______ _ C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
19 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater B. Outfall Information
*mplete a separate Section 111.B.-Outfall Information (pages 17-24) for each outfall at the facility.
Make copies of s blank section of the application if necessary.
PLEASE TYPE OR PRINT FACILITY NAME Consumers Energy Company, Palisades Nuclear Plant I NPDES or COC PERMIT NUMBER MI0001457
: 6. WASTEWATER CHARACTERISTICS
-CONVENTIONAL POLLUTANTS Instructions for completing this page are on the facing page. D Check this box if additional information is included as an attachment.
Maximum Maximum Parameter Daily Monthly Concentration Concentration Biochemical Oxygen Demand -five day (800 5) *(2) COD (Chemical oxygen demand) *(2) TOC (Total organic carbon) *(2) Ammonia Nitrogen (as N) *(2) Total Suspended Solids *(2) Total Dissolved Solids *(2) Total Phosphorus (as P) NIA maximum-7day
*cal Coliform Bacteria NIA Total Residual Chlorine *(2) minimum daily Dissolved Oxygen *(2) pH minimum maximum (report maximum and minimum of individual samples) *(2) Temperature, Summer *(2) Temperature, Winter *(2) Oil & Grease 14 .. 7 *(l) 9.2 *(l) Values.are based on 1997 DMR data *(2) The Company is requesting a waiver from this reporting requirement 21 .. '.,,, ..
* Units mg/1 mg/I mg/I ma/I ma/I mg/I mg/I counts/1 OOml D mg/I mg/I Standard Units *F D *c *F D *c mg/I ug/1 mg/I I Outfall Number OOF Tmbine Sump Number of Analyses Sample Type D Grab D 24 Hr Comp LJ Grab 0 24 Hr Comp LJ Grab D 24 Hr Comp LJ Grab D 24 Hr Comp LJ Grab 0 24 Hr Comp LJ Grab D 24HrComp D Grab C 24 Hr Comp Grab Grab Grab Grab Grab Grab 24 Grab D Grab 0 24HrComp D Grab 0 24 Hr Comp LJ Grab 0 24HrComp LJ Grab D 24 Hr Comp LJ Grab D 24HrComp LJ Grab D 24HrComp LJ Grab 0 24 Hr Comp EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
* 8. Outfall Information a separate Section 111.B. -Outfall Information (pages 17-24) for each outfall at the facility.
Make copies of blank section of the application if necessary.
PLEASE TYPE OR PRINT FACILITY NAME Consumers Energy Company, Palisades Nuclear Plant NPDES or COC PERMIT NUMBER MI0001457 OUTFALL NUMBER OOF 7. PRIMARY INDUSTRY TOXIC POLLUTANT INFORMATION Turbine Sump COMPLETE THIS ITEM ONLY IF THE FACILITY IS A PRIMARY INDUSTRY AS INDICATED IN ITEM 1 OF THIS SECTION. IF THIS IS NOT A PRIMARY INDUSTRY, CONTINUE WITH ITEM 8. For two or more substantially identical outfalls, permission may be requested from the appropriate district supervisor to sample and analyze only one outfall and submit the results of the analysis for other substantially identical outfall(s).
If the request is granted by the District Supervisor, attach a narrative describing which outfall was sampled, and describe why the outfalls which were not sampled are substantially similar to the outfall that was sampled. A. Indicate if the discharge from this outfall contains any process wastewater.
If the discharge from this outfall contains process wastewater, check YES and continue with B below. If the discharge from this outfall does not contain any process wastewater, check NO and continue with item 8. Does this outfall discharge contain any process wastewater? Yes, Continue with 8. D No, Continue with Item 8. See Outfall 001 results Attachment C , B. Primary Industries must submit test results for organic toxic pollutants.
Table 2 in the appendix contains a list of GC/MS fractions required by each industrial Category.
Indicate the GC/MS fractions required for the facility Industrial Category.
D Volatile D Base/Neutral D Acid D Pesticide Provide analytical data for each parameter of the GC/MS fraction checked above. The required parameters in each fraction are specified in Table 3 in the appendix.
Provide copies of the analytical results or record the information in Item 9. Additionally, all primary industries which discharge process wastewater shall provide quantitative data for the parameters specified in Table 4 in the appendix.
Applicants are not required to analyze for 2,3,7,8-TCDD (Dioxin) unless they believe it is present in the discharge.
ADDITIONAL TOXIC POLLUTANT INFORMATION A. If an applicant, regardless of the type of discharge, knows or has reason to believe that any pollutant listed in Tables 3, 4, 5, 7 and 8 is discharged from any outfall, then quantitative data shall be provided for those pollutants.
D Not Applicable/Believed Absent Present -Data is attached or recorded in Item 9. See Outfall 001 results Attachment C . , B. If an applicant (primary or secondary industry), regardless of the type of discharge, knows or has reason to believe any pollutants listed in Table 6 are discharged from any outfall, the applicant
!!!fill describe reasons for the pollutant being present and provide any available quantitative data. Not Applicable/Believed Absent D Present -Data is attached or recorded in Item 9. C. All applicants (primary and secondary industries) who use or manufacture 2,4,5-trichlorophenoxy acetic acid (2,4,5-T);
2-(2,4,5-trichlorophenoxy) propanoic acid (Silvex);
2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloroproprionate (Erben); 0,0-Dimethyl 0-(2,4,5-Trichlorophenyl)
Phosphorothioate (Ronne!);
2,4,5-trichlorophenol (TCP); or Hexachlorophene (HCP) must report data using standard analytical calibration procedures.
All surface water discharge applicants (primary and secondary industries) who know or have reason to believe that 2,3,7,B-Tetrachlorodibenzo-P-Dioxin (TCDD) is or may be present in their discharge must report qualitative data generated using a screening procedure not calibrated with analytical standards for TCDD. Not Applicable/Believed Absent D Present -Data is attached or recorded in Item 9. D. If the applicant knows or has reason to believe that biological tests (including WET tests) were made in the last three (3) years on any of the applicant's discharges or on a receiving water in relation to the discharge(s), provide this information as an attachment to this application. Not Applicable D Applicable
-Data is attached.
E. If a contract laboratory or consulting firm performed any of the analyses required by this application, provide the name and address of each laboratory or firm as an attachment to this application.
See Attachment B in the back of this D Not Applicable Applicable
-Information is provided.
Pennit Application F. Does the facility discharge any other toxic or injurious chemical substances not listed in Tables 3 through 9 in the appendix ? No. Continue with Section 111.C. D Yes. Data is attached or recorded in Item 9. 22 EQP 4659-C (Rev 1/98)
* Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
'
* B. Outfall Information mplete a separate Section 111.B. -Outfall Information
{pages 17-24) for each outfall at the facility.
s blank section of the application if necessary.
Make copies of PLEASE TYPE OR PRINT FACILITY NAME A. Receiving Water: B. County/Township:
Palisades Nuclear Plant Receiving Water NPDES PERMIT or COC NUMBER MI0001457 NI A (Internal discharge to Mixing Basin) County I Township Van Buren Covert OUTFALL NUMBER OOA South CT Oveiflow C. State Planar Coordinates:
SE 1/41 NW 1/41 Section 05 I Town 02S I Range 17W Latitude I Longitude 42&deg; 19' 23" 86&deg; 18' 56" D. Latitude/Longitude:
E. Type of Wastewater Discharged (Check all that apply): D Contact Cooling D Sanitary Wastewater D Process Wastewater 0 Storm Water (regulated)
D Other -specify --------Noncontact Cooling 0 Storm Water (not regulated)
F. Is this a Seasonal Discharge?
D Yes -List the discharge periods (by month) in the space provided below. From Through From From Through From G. Discharge Schedule (Yearly Average):
24 H. Expected or Proposed Discharge Flow Rates: Total Yearly Daily Minimum Daily Average 29.3 MGY 8.64 MGD 70 MGD I. The maximum discharge flow rate to be authorized in the permit: ___ 8_1 __ J. Does this discharge contain storm water subject to effluent guidelines?
0 indicate under which category.
17 l'8l No -Continue with item G Through Through hours/day I 365 days/year I Daily Maximum Maximum Design Flow Rate 81 MGD 81 MGD D GPO MGD D MGY 0 l'8J No EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater B. Outfall Information
*mplete a separate Section 111.B. -Outfall Information (pages 17-24) for each outfall at the facility.
Make copies of s blank section of the application if necessary.
PLEASE TYPE OR PRINT FACILITY NAME Consumers Energy Company, Palisades Nuclear Plant 4. WATER TREATMENT ADDITIVES NPDES PERMIT or COC NUMBER: MI0001457 OUTFALL NUMBER OOA South CT Overflow A. Is there a discharge of any water treatment additives or chemicals used to treat water and/or wastewater used or generated by this facility ? 0 No -Continue with Item 5. Yes -Provide the following information for each additive.
Provide the Material Safety Data Sheets (MSDS) for each additive as an attachment to this application.
Enter the product name of the additive and name of the manufacturer.
Describe the function of the additive, e.g., biocide, corrosion inhibitor, etc. Provide the average and maximum proposed discharge concentrations of the additive.
Enter the concentrations of the proposed additives after all treatment has occurred.
If the actual proposed discharge concentrations are not known; an estimate shall be made using stoichiometry and/or a mass balance. Provide the proposed discharge frequency in hours per day and days per week or year. Discharge Concentrations Product Name/Name of Manufacturer Additive Function Average Maximum Discharge Frequency O&#xb5;g11 O&#xb5;g11 hours/day Sodium Hypochlorite
*
* Omg/I
* OmgJI
* 0days/yr O&#xb5;g11 TI&#xb5;gll hours/day lJdaysJwk Omgn Omgll 0days/yr O&#xb5;g11 TI&#xb5;gll hours/day lJdaysJwk Oman Omgll 0days/yr O&#xb5;gll O&#xb5;gll hours/day Udayslwk Omgll Omgll 0days/yr O&#xb5;g/I O&#xb5;gll hours/day Udayslwk Omg11 Omg11 0days/yr O&#xb5;gll O&#xb5;g/I hours/day Udayslwk Omg/I Omg/I 0days/yr U&#xb5;gll O&#xb5;gJI hours/day Udayslwk Omg/I Omo/I 0days/yr O&#xb5;gll O&#xb5;g11 hours/day Odays/wk Orngn Omg11 0days/yr B. Table 11 contains a list of the additives for which the OEQ currently has sufficient toxicological data. If the additive this facility is proposing to discharge is not included in Table 11, call the Surface Water Quality Division, Great Lake and Environmental Assessment section at 517-3354184 to inquire about the status of the specific water treatment additive prior to providing any additional information.
If the DEQ does not have sufficient toxicological information for any additive being proposed for discharge at this facility, the applicant must provide a 48-hour EC50 for a North American planktonic crustacean (Oaphnia sp., Ceriodaphnia sp. or Simocephalus sp.) and the results of a toxicity test for one other North American Freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards.
The water treatment additive will not be evaluated for discharge authoriZation unless the appropriate information is attached.
D Aquatic toxicity data is attached.
See Attachment 2 of the transmittal letter C. If the discharge is treated to remove any of the above additives prior to discharge, indicate which additive the treatment is for and briefly describe the treatment process:
* Sodium Hypochlorite concentrations are mollitored at Outfall 001 18 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
.. B. Outfall Information mplete a separate Section 111.B. -Outfall lnfonnation (pages 17-24) for each outfall at the facility.
is blank section of the application if necessary.
Make copies of PLEASE TYPE OR PRINT FACILITY NAME Consumers Energy Company, Palisades Nuclear Plant NPDES PERMIT or COC NUMBER l\110001457 OUTFALL NUMBER OOA 5. PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE South CT Overflow This information is used to determine the applicable federal regulations for this discharge.
The information required to be reported is dependent on the type of facility.
Page 11 of the appendix contains an abbreviated list of various industries and the types of information each shall report in this application.
Assistance can be received by calling the appropriate district office (see pages 1 and 2 of the appendix).
All industries shall provide the name of each process and the Standard Industrial Classification (SIC) code for the process. If the wastestream is not regulated under federal categorical standards, the applicant shall report all pollutants which have the reasonable potential to be present in the discharge.
PROCESS INFORMATION A. Name of the process contributing to the discharge:
_N_l_A_-_N_o_n_c_on_ta_ct_C_o_olin_._g..__
_________________
_ B. SIC code:--------
C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
PROCESS INFORMATION A. Name of the process contributing to the discharge:
-----------------------------
B. SIC code:--------
C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
PROCESS INFORMATION A. Name of the process contributing to the discharge:
-----------------------------
B. SIC code:--------
C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
PROCESS INFORMATION A. Name of the process contributing to the discharge:
-----------------------------
B. SIC code:--------
C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
PROCESS INFORMATION A. Name of the process contributing to the discharge:
-----------------------------
B. SIC code:--------
C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
19 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater B. Outfall Information
*mplete a separate Section 111.B.* Outfall Information (pages 17-24) for each outfall at the facility.
Make copies of s blank section of the application if necessary.
PLEASE TYPE OR PRINT FACILITY NAME I NPDES or coc PERMIT NUMBER I Outfall Number Consumers Energy Company, Palisades Nuclear Plant MI0001457 OOA 6. WASTEWATER CHARACTERISTICS
-CONVENTIONAL POLLUTANTS South CT Overflow Instructions for completing this page are on the facing page. 0 Check this box if additional information is included as an attachment.
Maximum Maximum Number Parameter Daily Monthly of Concentration Concentration Units Analyses Sample Type D Grab Biochemical Oxygen Demand -five day (BOD 5)
* mg/I D 24 Hr Comp LJ Grab COD (Chemical oxygen demand)
* mg/I D 24HrComp D Grab TOC (Total organic carbon)
* mg/I D 24 Hr Comp LJ Grab Ammonia Nitrogen (as N)
* mall 0 24HrComp LJ Grab Total Suspended Solids
* mg/I D 24 Hr Comp LJ Grab Total Dissolved Solids
* mg/I D 24HrComp LJ .Grab Total Phosphorus (as P) NIA mg/I C 24 Hr Comp .cal Coliform Bacteria maximum-7day NIA counts/1 OOml Grab D mg11 Total Residual Chlorine NIA &#xb5;g/I Grab minimum daily Dissolved Oxygen NIA mg/I Grab pH minimum maximum (report maximum and minimum of individual samples) Standard Units Grab Temperature, Summer
* D 0 c Grab Temperature, Winter
* D *c Grab Oil & Grease
* mg/I Grab LJ Grab ug/I D 24HrComp LJ Grab mg/I D 24HrComp D Grab D 24HrComp LJ Grab D 24HrComp D Grab D 24HrComp LJ Grab D 24HrComp LJ Grab D 24 Hr Comp The Company 1s requesting a waiver from this reporting reqmrement 21 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
* 8. Outfall Information mplete a separate Section 111.B. -Outfall lnfonnation (pages 17-24) for each outfall at the facility.
1s blank section of the application if necessary.
PLEASE TYPE OR PRINT Make copies of FACILITY NAME Consumers Energy Company, Palisades Nuclear Plant NPDES or COC PERMIT NUMBER MI0001457 OUTFALL NUMBER OOA 7. PRIMARY INDUSTRY TOXIC POLLUTANT INFORMATION South CT Overflow COMPLETE THIS ITEM ONLY IF THE FACILITY IS A PRIMARY INDUSTRY AS INDICATED IN ITEM 1 OF THIS SECTION. IF THIS IS NOT A PRIMARY INDUSTRY, CONTINUE WITH ITEM 8. For two or more substantially identical outfalls, permission may be requested from the appropriate district supervisor to sample and analyze only one outfall and submit the results of the analysis for other substantially identical outfall(s).
If the request is granted by the District Supervisor, attach a narrative describing which outfall was sampled, and describe why the outfalls which were not sampled are substantially similar to the outfall that was sampled. A. Indicate if the discharge from this outfall contains any process wastewater.
If the discharge from this outfall contains process wastewater, check YES and continue with B below. If the discharge from this outfall does not contain any proi:ess wastewater, check NO and continue with item 8. Does this outfall discharge contain any process wastewater?
D Yes, Continue with B. No, Continue with Item 8. B. Primary Industries must submit test results for organic toxic pollutants.
Table 2 in the appendix contains a list of GC/MS fractions required
* by each industrial Category.
Indicate the GC/MS fractions required for the facility Industrial Category.
D Volatile D Base/Neutral 0 Acid 0 Pesticide Provide analytical data for each parameter of the GC/MS fraction checked above. The required parameters in each fraction are specified in Table 3 in the appendix.
Provide copies of the analytical results or record the information in Item 9. Additionally, all primary industries which discharge process wastewater shall provide quantitative data for the parameters specified in Table 4 in the appendix.
Applicants are not required to analyze for 2,3, 7,8-TCDD (Dioxin) unless they believe it is present in the discharge.
ADDITIONAL TOXIC POLLUTANT INFORMATION A. If an applicant, regardless of the type of discharge, knows or has reason to believe that any pollutant listed in Tables 3, 4, 5, 7 and 8 is discharged from any outfall, then quantitative data shall be provided for those pollutants.
D Not Applicable/Believed Absent Present -Data is attached or recorded in Item 9. B. If an applicant (primary or secondary industry).
regardless of the type of discharge, knows or has reason to believe any pollutants listed in Table 6 are discharged from any outfall, the applicant shall describe reasons for the pollutant being present and provide any available quantitative data. Not Applicable/Believed Absent D Present
* Data is attached or recorded in Item 9. C. All applicants (primary and secondary industries) who use or manufacture 2,4,5-trichlorophenoxy acetic acid (2,4,5-T);
2-(2,4,5-trichlorophenoxy) propanoic acid (Silvex);
2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloroproprionate (Erbon); 0,0-Dimethyl 0-(2,4,5-Trichlorophenyl)
Phosphorothioate (Ronnel);
2,4,5-trichlorophenol (TCP); or Hexachlorophene (HCP) must report data using standard analytical calibration procedures.
All surface water discharge applicants (primary and secondary industries) who know or have reason to believe that 2,3, 7,8-Tetrachlorodibenzo-P-Dioxin (TCDD) is or may be present in their discharge must report qualitative data generated using a screening procedure not calibrated with analytical standards forTCDD. igj Not Applicable/Believed Absent D Present -Data is attached or recorded in Item 9. D. If the applicant knows or has reason to believe that biological tests (including WET tests) were made in the last three (3) years on any of the applicant's discharges or on a receiving water in relation to the discharge(s), provide this information as an attachment to this application.
igj Not Applicable D Applicable
-Data is attached.
E. If a contract laboratory or consulting firm performed any of the analyses required by this application, provide the name and address of each laboratory or firm as an attachment to this application.
See Attachment B in the back of this D Not Applicable Applicable
-Information is provided.
Permit Application F. Does the facility discharge any other toxic or injurious chemical substances not listed in Tables 3 through 9 in the appendix ? No. Continue with Section 111.C. D Yes. Data is attached or recorded in Item 9. 22 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
* B. Outfall Information mplete a separate Section 111.B. -Outfall Information (pages 17-24) for each outfall at the facility.
1s blank section of the application if necessary.
Make copies of PLEASE TYPE OR PRINT FACILllY NAME I NPDES or COC PERMIT NUMBER I OUTFALL NUMBER Consumers Energy Company, Palisades Nuclear Plant MI0001457 OOA 9. EFFLUENT CHARACTERISTICS
*TOXIC POLLUTANTS South CT Overflow This worksheet is to be used by applicants to record infonnation on any Michigan Critical Material, EPA Priority Pollutant, or hazardous substance for which this application requires that data be provided.
This includes any substance from Table 3 which lists Organic Toxic Pollutants, Table 4, Other Toxic Pollutants, Table 5, Conventional and Nonconventional Pollutants, Table 6, Toxic Pollutants and Hazardous Substances, Table 7 the Michigan Critical Materials Register, or Table 8 the EPA Priority Pollutant Listing. If the applicant believes a pollutant may be present in the effluent that is not included in these lists, data shall be provided for that pollutant with this application.
This infonnation may also be included as an attachment to this application on 8 112" x 11" paper. Page 12 of the appendix is a list of minimum testing requirements for various dischargers.
As a minimum applicants for those types of discharge must provide analytical data based on that list. Applieants shall use EPA approved analytical methods when conducting sampling.
For each parameter provide the name of the parameter as listed in the Tables, the maximum daily and monthly discharge concentrations, units, the number of analyses perfonned, and the sample type. If analytical results for a composite sample are being provided and the sample is not a 24-hour composite, include a description of the sample collection technique used as an attachment to this application on 8 112" x 11" paper. When calculating an average where some values are detectable and others are nondetectable, either provide the actual data, or regard each nondetectable value as the detection level when calculating concentrations and indicate that the result is "less than" the value reported. (See definitions of "daily concentration" and "monthly concentration" in the general provisions at the front of this fonn.) Please include an explanation if "Pollution Prevention" is expected to provide reductions of pollutants. (See page ii and iii for sampling definitions, including, "daily concentration", and "monthly concentration".)
See Table 12 in the appendix for acceptable "Levels of Quantification".
D Check this box if additional infonnation is included as an attachment.
Maximum Maximum Dally Monthly Quantification Number Concentration Concentration Level of Sample Toxic Pollutant fun/I\ fua/ll fun/I) Analvses Type U Grab
* NI A -Internal Outfall 0 24HrComp LJ Grab 0 24HrComp LJ Grab 0 24HrComp D Grab 0 24HrComp lJ Grab 0 24HrComp LJ Grab 0 24HrComp D Grab 0 24HrComp 0 Grab 0 24 Hr Comp lJ Grab 0 24 Hr Comp U Grab 0 24 Hr Comp D Grab 0 24HrComp LJ Grab 0 24 Hr Comp ' D Grab 0 24HrComp D Grab 0 24 Hr Comp
* See Outfall 00 I 23 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
-B. Outfall Information mplete a separate Section 111.B.-Outfall Information (pages 17-24) for each outfall at the facility.
s blank section of the application if necessary.
Make copies of PLEASE TYPE OR PRINT FACILITY NAME I NPDES or COC PERMIT NUMBER I OUTFALL NUMBER Consumers Energy Company, Palisades Nuclear Plant MI0001457 OOA 10. TOXIC POLLUTANT REASONABLE POTENTIAL EFFLUENT DATA South CT Overflow In addition to the above information and in accordance with Rule 1211 of the Part 8 Rules (see pages 7-10 in the appendix), for each toxic substance which is or may be discharged from the facility, the applicant must provide individual sample data to determine if Water Quality Based Effluent Limits (WQBELs) are necessary.
WQBELs for toxic pollutants are incorporated into an NPDES permit when the DEQ has determined that a substance is or may be discharged into the waters of the state at a level that has a reasonable potential to exceed the substance's water quality value. The determination is made by developing a preliminary effluent limit (PEL) and comparing it to the potential effluent quality (PEQ) of the discharge.
The DEQ will determine the PELs for every toxic substance the permittee reports as being present in their discharge.
The PEQ for each toxic substance will be developed using individual sample results provided by the permittee.
If the permittee provides at least 10 representative facility-specific effluent samples that are greater than the detection limit, the maximum PEQ shall equal the upper 95th percentile of all the representative daily discharge concentrations and the average PEQ shall equal the upper 95th percentile of all the representative 3Ck:lay average concentrations.
Reasonable potential for the discharge of a toxic substance to cause or contribute to an excursion above any water quality value will be considered to exist if the average or maximum PEQ exceeds any of the chronic or acute PELs, respectively.
If the permittee is unable to provide 1 o effluent samples that are greater than the detection level, the PEQ shall be determined by identifying the total number of representative effluent samples, both detectable and nondetectable, and multiplying the maximum reported value by a multiplying factor found in Table 3 of Rule 1211, (see page 8 in the appendix).
List both detectable and nondetectable results. Where a result is nondetectable indicate the detection level. Reasonable potential for the discharge of a toxic substance to cause or contribute to an excursion above any water quality. value will be considered to exist if the PEQ for a pollutant exceeds its PEL. Attach additional sheets where there are more than ten (10) analytical results. If it is determined that the toxic substance concentration has a reasonable potential to cause or contribute to an excursion above any water quality value, then a WQBEL for that substance will be incorporated into the NPDES permit. Samples (ug/I) Toxic Pollutant 1 l 3 4 s 6 7 8 9 10 NI A -Internal Outfall Are any of the above listed toxic pollutants present in the facility's supply water? D No, Continue to next question.
D Yes, Please read below In accordan'ce with Rule 1211 (7) facilities whose supply water contains toxic pollutants that are withdrawn from and discharged to the same bOdy of ater may qualify for intake credits for those toxic pollutants.
See Rule 1211 (7) for qualification and demonstration requirements.
**: : *' 24 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER orsCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
.. -B. Outfall Information mplete a separate Section 111.B. -Outfall Information (pages 17-24) for each outfall at the facility.
1s blank section of the application if necessary.
Make copies of PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT or COC NUMBER MI0001457 OUTFALL NUMBER OOB
* Palisades Nuclear Plant North CT Overflow Receiving Water A Receiving Water: NI A (Internal discharge to Mixing Basin) County I Township Van Buren . Covert B. County/Township:
C. State Planar Coordinates:
SE 1/4. I NW 1/41 Section 05 I Town 02S I Range 17W Latitude I Longitude 42&deg; 19' 23" 86&deg; 18' 56" D. Latitude/Longitude:
E. Type of Wastewater Discharged (Check all that apply): 0 Contact Cooling Noncontact Cooling D Sanitary Wastewater D Process Wastewater 0 Storm Water (regulated) 0 Other -specify --------0 Storm Water (not regulated)
F. Is this a Seasonal Discharge?
0 Yes -List the discharge periods (by month) in the space provided below. 18 No -Continue with item G From Through From Through From Through From Through G. Discharge Schedule (Yearly Average):
24 hours/day I 365 days/year I H. Expected or Proposed Discharge Flow Rates: Total Yearly Daily Minimum Daily Average Daily Maximum Maximum Design Flow Rate 29.3 MGY 8.64 MGD 70 MGD 81 MGD 81 MGD I. The maximum discharge flow rate to be in the permit: ___ 8_1 __ D GPO MGD D MGY 0 J. Does this discharge contain storm water subject to effluent guidelines?
D Yes -indicate under which category . 17 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
* B. Outfall Information mplete a separate Section 111.B. -Outfall Information (pages 17-24) for each outfall at the facility.
s blank section of the application if necessary.
Make copies of PLEASE TYPE OR PRINT FACILITY NAME Consumers Energy Company, Palisades Nuclear Plant NPDES PERMIT or COC NUMBER: MI0001457 OUTFALL NUMBER OOB 4. WATER TREATMENT ADDITIVES North CT Overllow A. Is there a discharge of any water treatment additives or chemicals used to treat water and/or wastewater used or generated by this facility ? 0 No -Continue with Item 5. Yes -Provide the following information for each additive.
Provide the Material Safety Data Sheets (MSDS) for each additive as an attachment to this application.
Enter the product name of the additive and name of the manufacturer.
Describe the function of the additive, e.g., biocide, corrosion inhibitor, etc. Provide the average and maximum proposed discharge concentrations of the additive.
Enter the concentrations of the proposed additives after all treatment has occurred.
If the actual proposed discharge concentrations are not known, an estimate shall be made using stoichiometry and/or a mass balance. Provide the proposed discharge frequency in hours per day and days per week or year. Discharge Concentrations Product Name/Name of Manufacturer Additive Function Average Maximum Discharge Frequency U&#xb5;gll U&#xb5;gn hours/day Sodium Hypochlorite
*
* Dmg11
* Omg11
* 0days/yr U&#xb5;gn U&#xb5;gll hours/day Udayslwk Omgn Omg/I 0days/yr U&#xb5;gn U&#xb5;gn hours/day Udaystwk Omgn Omg/I 0days/yr U&#xb5;gll U&#xb5;gll hours/day Odaystwk Omg11 Omg1J 0days/yr U&#xb5;gll U&#xb5;gll hours/day Udays/wk Dmg11 Omg11 0days/yr U&#xb5;gll U&#xb5;gll hours/day Udays/wk Omg/I Omgn 0days/yr U&#xb5;gll U&#xb5;gll hours/day Udays/wk Omg/I Omgll 0days/yr lJ&#xb5;g/I lJ&#xb5;gll hours/day lJdays/wk Dmsn Omg11 0dayS/yr 8. Table 11 contains a list of the additives for which the OEQ currently has sufficient toxicological data. If the additive this facility is proposing to discharge is not included in Table 11, call the Surface Water Quality Division, Great Lake and Environmental Assessment section at 517-335-4184 to inquire about the status of the specific water treatment additive prior to providing any additional information.
If the DEQ does not have sufficient toxicological information for any additive being proposed for discharge at this facility, the applicant must provide a 48-hour EC50 for a North American planktonic crustacean (Oaphnia sp., Ceriodaphnia sp. or Simocephalus sp.) and the results of a toxicity test for one other North American Freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards.
The water treatment additive will not be evaluated for discharge authorii:ation unlei;s the appropriate information is attached.
D Aquatic toxicity data is attached.
See Attachment 2 of transmittal letter C. If the discharge is treated to remove any of the above additives prior to discharge, indicate which additive the treatment is for and briefly describe the treatment process:
* Sodium Hy[ochlorite concentrations are monitored at Outfall 001 18 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
* B. Outfall Information mplete a separate Section 111.B. -Outfall lnfonnation (pages 17-24) for each outfall at the facility.
is blank section of the.application if necessary.
Make copies of PLEASE TYPE OR PRINT FACILITY NAME I NPDES PERMIT or COC NUMBER I OUTFALL NUMBER Consumers Energy Company, Palisades Nuclear Plant MI0001457 OOB 5. PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE North CT Overllow This infonnation is used to detennine the applicable federal regulations for this discharge.
The infonnation required to be reported is dependent on the type of facility.
Page 11 of the appendix contains an abbreviated list of various industries and the types of infonnation each shall report in this application.
Assistance can be received by calling the appropriate district office (see pages 1 and 2 of the appendix).
All industries shall provide the name of each process and the Standard Industrial Classification (SIC) code for the process. If the wastestream is not regulated under federal categorical standards, the applicant shall report all pollutants which have the reasonable potential to be present in the discharge.
PROCESS INFORMATION A. Name of the process contributing to the discharge:
NI A -Noncontact Cooling B. SIC code: C. Describe the process and provide measures of production (see the instructions to detennine the appropriate infonnation to be reported):
PROCESS INFORMATION A. Name of the process contributing to the discharge:
B. SIC code: C. Describe the process and provide measures of production (see the instructions to detennine the appropriate infonnation to be reported):
PROCESS INFORMATION A. Name of the process contributing to the discharge:
B. SIC code: C. Describe the process and provide measures of production (see the instructions to detennine the appropriate infonnation to be reported):
PROCESS INFORMATION A. Name of the process contributing to the discharge:
B. SICcode: . C. Describe the process and provide measures of production (see the instructions to detennine the appropriate infonnation to be reported):
PROCESS INFORMATION A. Name of the process contributing to the discharge:
B. SICcode: ' c. Describe the process and provide measures of production (see the instructions to detennine the appropriate infonnation to be reported):
19 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater B. Outfall Information
*mplete a separate Section 111.B.-Outfall Information (pages 17-24) for each outfall at the facility.
Make copies of s blank section of the application If necessary.
* PLEASE TYPE OR PRINT FACILITY NAME I NPDES or COC PERMIT NUMBER I Outfall Number Consumers Energy Company, Palisades Nuclear Plant MI0001457 OOB 6. WASTEWATER CHARACTERISTICS
-CONVENTIONAL POLLUTANTS North CT Overflow Instructions for completing this page are on the facing page. 0 Check this box if additional information is included as an attachment.
Maximum Maximum Number Parameter Daily Monthly of Concentration Concentration Units Analyses Sample Type D Grab Biochemical Oxygen Demand -five day (BOD 5)
* mg/I D 24 Hr Comp LJ Grab COD (Chemical oxygen demand)
* mg/I D 24HrComp LJ Grab TOC (Total organic carbon)
* mg/I 0 24 Hr Comp 0 Grab Ammonia Nitrogen (as N)
* mg/I 0 24HrComp D Grab Total Suspended Solids
* mg/I 0 24 Hr Comp LJ Grab Total Dissolved Solids
* mg/I D 24HrComp LJ Grab Total Phosphorus (as P) NIA mg/I C 24 Hr Comp .cal Coliform Bacteria maximum-7day NIA counts/1 OOml Grab 0 mg/I Total Residual Chlorine NIA 5(1 &#xb5;gll Grab minimum daily Dissolved Oxygen NIA mg/I Grab pH minimum maximum (report maximum and minimum of individual samples) Standard Units Grab Temperature, Summer * *F D *c Grab Temperature, Winter * *F D *c Grab Oil &Grease
* mg/I Grab LJ Grab ug/I D 24HrComp D Grab mg/I D 24 Hr Comp LJ Grab 0 24HrComp D Grab 0 24 Hr Comp LJ Grab 0 24HrComp LJ Grab 0 24HrComp lJ Grab 0 24 Hr Comp The Company is requesting a waiver from this reporting reqwrement 21 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
*
* B. Outfall Information omplete a separate Section 111.B. -Outfall Information
{pages 17-24) for each outfall at the facility.
Make copies of is blank section of the application if necessary. . PLEASE TYPE OR PRINT FACILITY NAME NPDES or CCC PERMIT NUMBER OUTFAU NUMBER Consumers Energy Company, Palisades Nuclear Plant MI0001457 OOB 7. PRIMARY INDUSTRY TOXIC POLLUTANT INFORMATION North CT Overflow COMPLETE THIS ITEM ONLY IF THE FACILITY IS A PRIMARY INDUSTRY AS INDICATED IN ITEM 1 OF THIS SECTION. IF THIS IS NOT A PRIMARY INDUSTRY, CONTINUE WITH ITEM 8. For two or more substantially identical outfalls, permission may be requested from the appropriate district supervisor to sample and analyze only one outfall and submit th.e results of the analysis for other substantially identical outfall(s).
If the request is granted by the District Supervisor, attach a narrative describing which outfall was sampled, and describe why the outfalls which were not sampled are substantially similar to the outfall that was sampled. A. Indicate if the discharge from this outfall contains any process wastewater.
If the discharge from this outfall contains process wastewater, check YES and continue with B below. If the discharge from this outfall does not contain any process wastewater, check NO and continue with item 8. Does this outfall discharge contain any process wastewater?
0 Yes, Continue with 8. No, Continue with Item 8. B. Primary Industries must submit test results for organic toxic pollutants.
Table 2 in the appendix contains a list of GC/MS fractions required by each.industrial Category.
Indicate the GC/MS fractions required for the facility Industrial Category.
0 Volatile 0 Base/Neutral*
0 Acid 0 Pesticide Provide analytical data for each parameter of the GC/MS fraction checked above. The required parameters in each fraction are specified in Table 3 in the appendix.
Provide copies of the analytical results or record the information in Item 9. Additionally, all primary industries which discharge process wastewater shall provide quantitative data for the parameters specified in Table 4 in the appendix.
Applicants are not required to analyze for 2,3,7,8-TCDD (Dioxin) unless they believe it is present in the discharge.
ADDITIONAL TOXIC POLLUTANT INFORMATION A. If an applicant, regardless of the type of discharge, knows or has reason to believe that any pollutant listed in Tables 3, 4, 5, 7 and 8 is discharged from any outfall, then quantitative data shall be provided for those pollutants.
D Not Applicable/Believed Absent Present -Data is attached or recorded in Item 9. B. If an applicant (primary or secondary industry), regardless of the type of discharge, knows or has reason to believe any pollutants listed in Table 6 are discharged from any outfall, the applicant shall describe reasons for the pollutant being present and provide any available quantitative data. Not Applicable/Believed Absent 0 Present -Data is attached or recorded in Item 9. C. All applicants (primary and secondary industries) who use or manufacture 2,4,5-trichlorophenoxy acetic acid (2,4,5-T);
2-(2,4,5-trichlorophenoxy) propanoic acid (Silvex);
2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichioroproprionate (Erbon); 0,0-Dimethyl 0-(2,4,5-Trichlorophenyl)
Phosphorothioate (Ronne!);
2,4,5-trichlorophenol (TCP); or Hexachlorophene (HCP) must report data using standard analytical calibration procedures.
All surface water discharge applicants (primary and secondary industries) who know or have reason to believe that 2,3,7,8-Tetrachloroclibenzo-P-Dioxin (TCDD) is or may be present in their discharge must report qualitative data generated using a screening procedure not calibrated with analytical standards for TCDD. Not Applicable/Believed Absent 0 Present -Data is attached or recorded in Item 9. D. If the applicant knows or has reason to believe that biological tests (including WET tests) were made in the last three (3) years on any of the applicant's discharges or on a receiving water in relation to the discharge(s), provide this information as an attachment to this application. Not Applicable
* 0 Applicable
-Data is attached.
E. If a contract laboratory or consulting firm performed any of the analyses required by this application, provide the name and address of each laboratory or firm as an attachment to this application.
S Atta hm B
* th b k f thi ee c ent m e ac o s 0 Not Applicable Applicable
-Information is provided.
Pennit Application F. Does the facility discharge any other toxic or injurious chemical substances not listed in Tables 3 through 9 in the appendix ? No. Continue with Section 111.C. 0 Yes. Data is attached or recorded in Item 9. 22 EQP 4659-C (Rev 1198)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
* B. Outfall Information mplete a separate Section 111.B. -Outfall Information (pages 17-24) for each outfall at the facility.
s blank section of the application if necessary.
Make copies of PLEASE TYPE OR PRINT FACILITY NAME I NPDES or COC PERMIT NUMBER l OUTFALL NUMBER Consumers Energy Company, Palisades Nuclear Plant MI0001457 OOB 9. EFFLUENT CHARACTERISTICS
-TOXIC POLLUTANTS North CT Overflow This worksheet.
is to be used by applicants to record information on any Michigan Critical Material, EPA Priority Pollutant, or hazardous substance for which this application requires that data be provided.
This includes any substance from Table 3 which lists Organic Toxic Pollutants, Table 4, Other Toxic Pollutants, Table 5, Conventional and Nonconventional Pollutants, Table 6, Toxic Pollutants and Hazardous Substances, Table 7 the Michigan Critical Materials Register, or Table 8 the EPA Priority Pollutant Listing. If the applicant believes a pollutant may be present in the effluent that is not included in these lists, data shall be provided for that pollutant with this application.
This information may also be included as an attachment to this application on 8 112* x 11" paper. Page 12 of the appendix is a list of minimum testing requirements for various dischargers.
As a minimum applicants for those types of discharge must provide analytical data based on that list. Applicants shall use EPA approved analytical methods when conducting sampling.
For each parameter provide the name of the parameter as listed in the Tables, the maximum daily and monthly discharge concentrations, units, the number of analyses performed, and the sample type. If analytical results for a composite sample are being provided and the sample is not a 24-hour composite, include a description of the sample collection technique used as an attachment to this application on 8 112* x 11
* paper. When calculating an average where some values are detectable and others are nondetectable, either provide the actual data, or regard each nondetectable value as the detection level when calculating concentrations and indicate that the result is "less than* the value reported. (See definitions of "daily concentration" and "monthly concentration" in the general provisions at the front of this form.) Please include an explanation if "Pollution Prevention*
is expected to provide reductions of pollutants. (See page ii and iii for sampling definitions, including, 'daily concentration", and "monthly concentration".)
See Table 12 in the appendix for acceptable "Levels of Quantification".
0 Check this box if additional information is included as an attachment.
Maximum Maximum Dally Monthly Quantification Number Concentration Concentration Level of Sample Toxic Pollutant (ua/I) fua/I) (ua/I) Analv59S Type LJ Grab
* NI A -Internal Outfall D 24HrComp LJ Grab D 24 Hr Comp LJ Grab D 24 Hr Comp D Grab D 24HrComp D Grab D 24HrComp LJ Grab 0 24HrComp LJ Grab D 24HrComo U Grab 0 24 Hr Comp LJ Grab 0 24 Hr Comp D Grab 0 24 Hr Comp LJ Grab 0 24 Hr Como LJ Grab ' D 24 Hr Comp ' LJ Grab D 24HrComp U Grab 0 24HrComp * ' See Outfall 001 23 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
-B. Outfall Information mplete a separate Section 111.B.-Outfall lnfonnation (pages 17-24) for each outfall at the facility.
s blank section of the application if necessary.
* Make copies of PLEASE TYPE OR PRINT FACILITY NAME I NPDES or COC PERMIT NUMBER I OUTFALL NUMBER Consumers Energy Company, Palisades Nuclear Plant MI0001457 OOB 10. TOXIC POLLUTANT REASONABLE POTENTIAL EFFLUENT DATA North CT Overflow In addition to the above information and in accordance with Rule 1211 of the Part 8 Rules (see pages 7-10 in the appendix), for each toxic substance which is or may be discharged from the facility, the applicant must provide individual sample data to determine if Water Quality Based Effluent Limits (WQBELs) are necessary.
' WQBELs for toxic pollutants are incorporated into an NPDES permit when the DEQ has determined that a substance is or may be discharged into the waters of the state at a level that has a reasonable potential to exceed the substance's water quality value. The determination is made by developing a preliminary effluent limit (PEL) and comparing it to the potential effluent quality (PEQ) of the discharge.
The DEQ will determine the PELs for every toxic substance the permittee reports as being present in their discharge.
The PEQ for each toxic substance will be developed using individual sample results provided by the permittee.
If the permittee provides at least 10 representative facility-specific effluent samples that are greater than the detection limit, the maximum PEQ shall equal the upper 95th percentile of all the representative dally discharge concentrations and the average PEQ shall equal the upper 95th percentile of all the representative 3()-day average concentrations.
Reasonable potential for the discharge of a toxic substance to cause or contribute to an excursion above any water quality value will be considered to exist if the average or maximum PEQ exceeds any of the chronic or acute PELs, respectively.
If the permittee is unable to provide 10 effluent samples that are greater than the detection level, the PEQ shall be determined by identifying the total number of representative effluent samples, both detectable and nondetectable, and multiplying the maximum reported value by a multiplying factor found in Table 3 of Rule 1211, (see page 8 in the appendix).
List both detectable and nondetectable results. Where a result is nondetectable indicate the detection level. Reasonable potential for the discharge of a toxic substance to cause or contribute to an excursion above any water quarrty value will be considered to exist if the PEQ for a pollutant exceeds its PEL Attach additional sheets where there are more than ten (10) analytical results. If it is determined that the toxic substance concentration has a reasonable potential to cause or contribute to an excursion above any water quality value, then a WQBEL for that substance will be incorporated into the NPDES permil Samples (ug/I) Toxic Pollutant I 2 3 4 5 6 7 8 9 IO NI A -Internal Outfall Are any of the above listed toxic pollutants present in the facility's supply water? D No, Continue to next question.
D Yes, Please read below In accordance with Rule 1211 (7) facilities whose supply water contains toxic pollutants that are withdrawn from and discharged to the same body of ter may qualify for intake credits for those toxic pollutants.
See Rule 1211 (7) for qualification and demonstration requirements.
24 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
* * *
* B. Outfall Information mplete a separate Section 111.B. -Outfall Information (pages 17-24) for each outfall at the facility.
s blank section of the application if necessary.
PLEASE TYPE OR PRINT Make copies of FACILITY NAME NPDES PERMIT or COC NUMBER MI0001457 OUTFALL NUMBER ooc Consumers Ene Com an , Palisades Nuclear Plant 3. OUTFALL INFORMATION CTBlowdown
* Receiving Water A. Receiving Water: NI A (Internal discharge to Mixing Basin) County I Township Van Buren Covert 1/41 1/41 Section I Town l Range SE NW 05 02S . 17W B. County/Township:
C. State Planar Coordinates:
Latitude I Longitude 42&deg; 19' 23" 86&deg; 18' 56" D. Latitude/Longitude:
E. Type of Wastewater Discharged (Check all that apply): 0 Contact Cooling Noncontact Cooling 0 Sanitary Wastewater 0 Process Wastewater 0 Storm Water (regulated) 0 other -specify --------0 Storm Water (not regulated)
F. Is this a Seasonal Discharge?
0 Yes -List the discharge periods (by month) in the space provided below. No -Continue with item G From Through From Through From Through From Through G. Discharge Schedule (Yearly Average):
24 hours/day I 365 days/year I H Expected or Proposed Discharge Flow Rates* Total Yearly Daily Minimum Daily Average Daily Maximum Maximum Design Flow Rate 31390 MGY 0 MGD 0 MGD 86 MGD 86 MGD I. The maximum discharge flow rate to be authorized in the permit: __ 8_6 __ __ 0 GPO MGD 0 MGY 0 J. Does this discharge contain storm water subject to effluent guidelines?
D Yes -indicate under which category. 17 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
* B. Outfall Information
* mplete a separate Section 111.B. -Outfall Information (pages 17-24) for each outfall at the facility.
1s blank section of the application if necessary.
PLEASE TYPE OR PRINT Make copies of FACILITY NAME NPDES PERMIT or COC NUMBER: OUTFALL NUMBER Consumers Energy Company, Palisades Nuclear Plant MI0001457 OOC 4. WATER TREATMENT ADDITIVES CT Blowdown . A. Is there a discharge of any water treatment additives or chemicals used to treat water and/or wastewater used or generated by this facility ? D No -Continue with Item 5. Yes -Provide the following information for each additive.
Provide the Material Safety Data Sheets (MSDS) for *each additive as an attachment to this application.
Enter the product name of the additive and name of the manufacturer.
Describe the function of the additive, e.g., biocide, corrosion inhibitor, etc. Provide the average and maximum proposed discharge concentrations of the additive.
Enter the concentrations of the proposed additives after all treatment has occurred.
If the actual proposed discharge concentrations are not known, an estimate shall be made using stoichiometry and/or a mass balance. Provide the proposed discharge frequency in hours per day and days per week or year. Discharge Concentrations Product Name/Name of Manufacturer Additive Function Average Maximum Discharge Frequency O&#xb5;gll D11g11 hours/day Odays/wk Sodium Hynocholrite
*
* Omg11
* Omg11
* 0dayslyr 0.12 U&#xb5;g11 0.35 O&#xb5;gll hours/day OdaysJwk Betz Dearborn Depositrol BL5301 Antiscalent 24 365 U&#xb5;g11 O&#xb5;gll hours/day 0days/wk Omg11 Omgn 0dayslyr U&#xb5;g11 U&#xb5;gll hours/day Udays/wk Omg11 Omgll 0dayslyr U&#xb5;g11 U&#xb5;gll hours/day Udayslwk Omg11 Omg11 0dayslyr U&#xb5;g11 U&#xb5;gll hours/day Odays/wk Omg/I Omg/I 0days/yr O&#xb5;gll U&#xb5;g11 hours/day Udays/wk Dl'l'1Q/I Dm11/I 0days/yr O&#xb5;g/I O&#xb5;g11 hours/day Udays/wk Omg11 Omg11 0days/yr B. Table 11 contains a list of the additives for which the OEQ currently has sufficient toxicological data. If the additive this facility is proposing to discharge is not included in Table 11, call the Surface Water Quality Division, Great Lake and Environmental Assessment section at 517-335-4184 to inquire about the status of the specific water treatment additive prior to providing any additional information.
If the DEQ does not have sufficient toxicological information for any additive being proposed for discharge at this facility, the applicant must provide a 48-hour EC50 for a North American planktonic crustacean (Oaphnia sp., Ceriodaphnia sp. or Simocephalus sp.) and the results of a toxicity test for one other North American Freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards.
The water treatment additive will not be evaluated for discharge authoriZation unless the appropriate information is attached. Aquatic toxicity data is attached.
NaHcl data see Attach 2; BL5301 data see it's MSDS C. If the discharge is treated to remove any of the above additives prior to discharge, indicate which additive the treatment is for and briefly describe the treatment process:
* Sodium Hypochlorite concentrations are monitored at Outfall 001 18 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
* B. Outfall Information
* mplete a separate Section 111.B. -Outfall Information (pages 17-24) for each outfall at the facility.
s blank section of the application if necessary.
Make copies of PLEASE TYPE OR PRINT FACILITY NAME Consumers Energy Company, Palisades Nuclear Plant NPDES PERMIT or CCC NUMBER MI0001457 OUTFALL NUMBER ooc 5. PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE CT Blowdown This information is used to determine the applicable federal regulations for this discharge.
The infonnation required to be reported is dependent on the type of facility.
Page 11 of the appendix contains an abbreviated list of various industries and the types of information each shall report in this application.
Assistance can be received by calling the appropriate district office (see pages 1 and 2 of the appendix).
All industries shall provide the name of each* process and the Standard Industrial Classification (SIC) code for the process. If the wastestream is not regulated under federal categorical standards, the applicant shall report all pollutants which have the reasonable potential to be present in the discharge.
PROCESS INFORMATION A. Name of the process contributing to the discharge:
__ N_l_A_-_N_o_n_co_n_ta_ct_C_oo_I_in_,g..._
_________________
_ B. SIC code:--------
C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
PROCESS INFORMATION A. Name of the process contributing to the discharge:
-----------------------------
B. SIC code: _______ _ C. Describe the process and provide measures*
of production (see the instructions to determine the appropriate information to be reported):
PROCESS INFORMATION A. Name of the process contributing to the discharge:
-----------------------------
B. SIC code:--------
C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
PROCESS INFORMATION A. Name of the process contributing to the discharge:
-----------------------------
B. SIC code:--------
C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
PROCESS INFORMATION
*A. Name of the process contributing to the discharge:
-----------------------------
B. SIC code:--------
C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
19 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION 111-lndustdal and Commercial Wastewater
* B. Outfall Information mplete a separate Section 111.B.-Outfall Information (pages 17-24) for each outfall at the facility.
s blank section of the application if necessary.
PLEASE TYPE OR PRINT Make copies of FACILITY NAME I NPDES or COC PERMIT NUMBER I Outfall Number Consumers Energy Company, Palisades Nuclear Plant MI0001457 ooc 6. WASTEWATER CHARACTERISTICS
-CONVENTIONAL POLLUTANTS Instructions for completing this page are on the facing page. CTBlowdown 0 Check this box if additional information is included as an attachment.
Maximum Maximum Number Parameter Daily Monthly of Concentration , Concentration Units Analyses Sample Type D Grab Biochemical Oxygen Demand -five day (800 5)
* mgn D 24HrComp LJ Grab COD (Chemical oxygen demand)
* mg/I D 24 Hr Comp LJ Grab TOC (Total organic carbon)
* mgn D 24 Hr Comp LJ Grab Ammonia Nitrogen (as N)
* mQ/I 0 24HrComp 0 Grab Total Suspended Solids
* mg/I D 24 Hr Comp 0 Grab Total Dissolved Solids
* mgn 0 24HrComp U Grab Total Phosphorus (as P) NIA mg/I C 24 Hr Comp .cal Coliform Bacteria maximum-7day NIA counts/1 OOml Grab LJ mg/I Total Residual Chlorine NIA 5!Cj &#xb5;g/I Grab minimum daily ' Dissolved Oxygen
* mg/I Grab pH minimum maximum (report maximum and minimum of individual samples)
* Standard Units Grab Temperature, Summer * *F 0 *c Grab Temperature, Winter * *F D *c Grab Oil & Grease
* mg/I Grab LJ Grab ugn 0 24 Hr Comp 0 Grab mgn 0 24 Hr Comp D Grab 0 24HrComp LJ Grab D 24 Hr Comp 0 Grab 0 24HrComp LJ Grab ,, D 24 Hr Comp LJ Grab 0 24HrComp
* The Company 1s requesting a wruver from this reporting reqmrernent 21 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
.. B. Outfall Information mplete a separate Section 111.B. -Outfall Information (pages 17-24) for each outfall at the facility.
s blank section of the application if necessary.
Make copies of **j PLEASE TYPE OR PRINT FACILITY NAME NPDES or COC PERMIT NUMBER MI0001457 OUTFALL NUMBER ooc Consumers Energy Company, Palisades Nuclear Plant 7. PRIMARY INDUSTRY TOXIC POLLUTANT INFORMATION CT Blowdown COMPLETE THIS ITEM ONLY IF THE FACILITY IS A PRIMARY INDUSTRY AS INDICATED IN ITEM 1 OF THIS SECTION. IF THIS IS NOT A PRIMARY INDUSTRY, CONTINUE WITH ITEM 8. ... For two or more substantially identical outfalls, permission may be requested from the appropriate district supervisor to sample and analyze only one outfall and submit the results of the analysis for other substantially identical outfall(s).
If the request is granted by the District Supervisor, attach a narrative describing which outfall was sampled, and describe why the outfalls which were not sampled are substantially similar to the outfall that was sampled. A. Indicate if the discharge from this outfall contains any process wastewater.
If the discharge from this outfall contains process wastewater, check YES and continue with B below. If the discharge from this outfall does not contain any process wastewater, check NO and continue with item 8. Does this outfall discharge contain any process wastewater?
0 Yes, Continue with B. No, Continue with Item 8. B. Primary Industries must submit test results for organic toxic pollutants.
Table 2 in the appendix contains a list of GC/MS fractions required by each industrial Category.
Indicate the GC/MS fractions required for the facility Industrial Category.
0 Volatile 0 Base/Neutral 0 Acid 0 Pesticide Provide analytical data for each parameter of the GC/MS fraction checked above. The required parameters in each fraction are specified in Table 3 in the appendix.
Provide copies of the analytical results or record the information in Item 9. Additionally, all primary industries which discharge process wastewater shall provide quantitative data for the parameters specified in Table 4 in the appendix.
Applicants are not required to analyze for 2,3,7,8-TCDD (Dioxin) unless they believe it is present in the discharge.
ADDITIONAL TOXIC POLLUTANT INFORMATION A. If an applicant, regardless of the type of discharge, knows or has reason to believe that any pollutant listed in Tables 3, 4, 5, 7 and 8 is discharged from any outfall, then quantitative data shall be provided for those pollutants. Not Applicable/Believed Absent 0 Present -Data is attached or recorded in Item 9. B. If an applicant (primary or secondary industry), regardless of the type of discharge, knows or has reason to believe any pollutants listed in Table 6 are discharged from any outfall, the applicant shall describe reasons for the pollutant being present and provide any available quantitative data. Not Applicable/Believed Absent D Present -Data is attached or recorded in Item 9. C. All applicants (primary and secondary industries) who use or manufacture 2,4,5-trichlorophenoxy acetic acid (2,4,5-T);
2-(2,4,5-trichlorophenoxy) propanoic acid (Silvex);
2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloroproprionate (Erben); 0,0-Dimethyl 0-(2,4,5-Trichlorophenyl)
Phosphorothioate (Ronnel);
2,4,5-trichlorophenol (TCP); or Hexachlorophene (HCP) must report data using standard analytical calibration procedures.
All surface water discharge applicants (primary and secondary industries) who know or have reason to believe that 2,3, 7,8-Tetrachlorodibenzo-P-Dioxin (TCDD) is or may be present in their discharge must report qualitative data generated using a screening procedure not calibrated with analytical standards for TCDD. , Not Applicable/Believed Absent 0 Present -Data is attached or recorded in Item 9. D. If the applicant knows or has reason to believe that biological tests (including WET tests) were made in the last three (3) years on any of the applicant's discharges or on a receiving water in relation to the discharge(s), provide this information as an attachment to this application. Not Applicable D Applicable
-Data is attached.
E. If a contract laboratory or consulting firm performed any of the analyses required by this application, provide the name and address of each laboratory or firm as an attachment to this application.
S Atta hm t B
* th b k f thi ee c en m e ac o s 0 Not Applicable Applicable
-Information is provided.
Permit Application F: Does the facility discharge any other toxic or injurious chemical substances not listed in Tables 3 through 9 in the appendix 7 No. Continue with Section 111.C. 0 Yes. Data is attached or recorded in Item 9. 22 EQP 4659-C (Rev l/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
* B. Outfall Information mplete a separate Section 111.B. -Outfall lnfonnation (pages 17-24) for each outfall at the facility.
s blank section of the application if necessary.
Make copies of PLEASE TYPE OR PRINT FACILITY NAME I NPDES or COC PERMIT NUMBER I OUTFALL NUMBER Consumers Energy Company, Palisades Nuclear Plant MI0001457 ooc 9. EFFLUENT CHARACTERISTICS
-TOXIC POLLUTANTS CTBlowdown This worksheet is to be used by applicants to record information on any Michigan Critical Material, EPA Priority Pollutant, or hazardous substance for which this application requires that data be provided.
This includes any substance from Table 3 which lists Organic Toxic Pollutants, Table 4, Other Toxic Pollutants, Table 5, Conventional and Nonconventional Pollutants, Table 6, Toxic Pollutants and Hazardous Substances, Table 7 the Michigan Critical Materials Register, or Table 8 the EPA Priority Pollutant Listing. If the applicant believes a pollutant may be present in the effluent that is not included in these lists, data shall be provided for that pollutant with this application.
This information may also be included as an attachment to this application on 8 112" x 11" paper. Page 12 of the appendix is a list of minimum testing requirements for various dischargers.
As a minimum applicants for those types of discharge must provide analytical data based on that list. Applicants shall use EPA approved analytical methods when conducting sampling.
For each parameter provide the name of the parameter as listed in the Tables, the maximum daily and monthly discharge concentrations, units, the number of analyses performed, and the sample type. If analytical results for a composite sample are being provided and the sample is not a 24-hour composite, include a description of the sample collection technique used as an attachment to this application on 8 112* x 11" paper. When calculating an average where some values are detectable and others are nondetectable, either provide the actual data, or regard each nondetectable value as the detection level when calculating concentrations and indicate that the result is "less than" the value reported. (See definitions of "daily concentration" and "monthly concentration" in the general provisions at the front of this form.) Please include an explanation if "Pollution Prevention" is expected to provide reductions of pollutants. (See page ii and iii for sampling definitions, including, "daily concentration", and "monthly concentration".)
See Table 12 in the appendix for acceptable "Levels of Quantification".
0 Check this box if additional information is included as an attachment.
Maximum Maximum Dally Monthly Quantification Number Concentration Concentration Level of Sample Toxic Pollutant fug/I) fua/I) fua/I) Analyses Type lJ Grab
* NI A -Internal Outfall 0 24HrComp lJ Grab 0 24HrComp [J Grab 0 24HrComp D Grab D 24HrComp LJ Grab D 24HrComp LJ Grab D 24HrComp lJ Grab 0 24HrComp D Grab 0 24 Hr Comp lJ Grab 0 24 Hr Comp lJ Grab 0 24 Hr Comp D Grab 0 24HrComp lJ Grab 0 24 Hr Comp ' lJ Grab 0 24HrComp lJ Grab 0 24HrComp
* See Outfall 001 23 EQP 4659-C (Rev 1198)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
*
* B. Outfall Information mplete a separate Section 111.B. -Outfall Information (pages 17-24) for each outfall at the facility.
s blank section of the application if necessary.
Make copies of PLEASE TYPE OR PRINT FACILITY NAME I NPDES or CCC PERMIT NUMBER l OUTFALL NUMBER Consumers Energy Company, Palisades Nuclear Plant MI0001457 OOF 9. EFFLUENT CHARACTERISTICS
-TOXIC POLLUTANTS Tmbine Sump This worksheet is to be used by applicants to record infonnation on any Michigan Critical Material, EPA Priority Pollutant, or hazardous substance for which this application requires that data be provided.
This includes any substance from Table 3 which lists Organic Toxic Pollutants, Table 4, Other Toxic Pollutants, Table 5, Conventional and Nonconventional Pollutants, Table 6, Toxic Pollutants and Hazardous Substances, Table 7 the Michigan Critical Materials Register, or Table 8 the EPA Priority Pollutant Listing. If the applicant believes a pollutant may be present in the effluent that is not included in these lists, data shall be provided for that pollutant with this application.
This information may also be included as an attachment to this application on 8 1/2" x 11" paper. Page 12 of the appendix is a list of minimum testing requirements for various dischargers.
As a minimum applicants for those types of discharge must provide analytical data based on that list. AppHcants shall use EPA approved analytical methods when conducting sampling.
For each parameter provide the name of the parameter as listed in the Tables, the maximum daily and monthly discharge concentrations, units, the number of analyses perfonned, and the sample type. If analytical results for a composite sample are being provided and the sample is not a 24-hour composite, include a description of the sample collection technique used as an attachment to this application on 8 112* x 11" paper. When calculating an average where some values are detectable and others are nondetectable, either provide the actual data, or regard each nondetectable value as the detection level when calculating concentrations and indicate that the result is "less than" the value reported. (See definitions of "daily concentration" and "monthly concentration" in the general provisions at the front of this fonn.) Please include an explanation if "Pollution Prevention*
is expected to provide reductions of pollutants. (See page ii and iii for sampling definitions, including, "daily concentration", and "monthly concentration".)
See Table 12 in the appendix for acceptable "Levels of Quantification".
0 Check this box if additional information is included as an attachment.
Maximum Maximum Dally Monthly Quantification Number Concentration Concentration Level of Sample Toxic Pollutant fuam fuall) (nnlll Analvses Type Oil & Grease 14.7 mg/I 9.2 mg/I -24 0 24 Hr Comp LJ Grab
* See Outfall 001 D 24 Hr Comp 0 Grab. D 24 Hr Comp LJ Grab D 24HrComp LJ Grab D 24HrComp LJ Grab D 24HrComp 0 Grab 0 24 Hr Comp 0 Grab 0 24 Hr Comp LJ Grab D 24 Hr Comp U Grab D 24 Hr Comp D Grab D 24 Hr Comp 0 Grab D 24 Hr Comp ' LJ Grab D 24HrComp U Grab 0 24HrComp 23 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
-B. Outfall Information mplete a separate Section 111.B.-Outfall Information (pages 17-24) for each outfall at the facility.
s blank section of the application if necessary.
Make copies of PLEASE TYPE OR PRINT
* FACILITY NAME I NPDES or COC PERMIT NUMBER I OUTFALL NUMBER Consumers Energy Company, Palisades Nuclear Plant 1\110001457 OOF 10. TOXIC POLLUTANT REASONABLE POTENTIAL EFFLUENT DATA Tmbine Sump In addition to the above information and in accordance with Rule 1211 of the Part 8 Rules (see pages 7-10 in the appendix), for each toxic substance which is or may be discharged from the facility, the applicant must provide individual sample data to determine if Water Quality Based Effluent Limits (WQBELs) are necessary.
WQBELs for toxic pollutants are incorporated into an NPDES permit when the DEQ has determined that a substance is or may be discharged into the waters of the state at a level that has a reasonable potential to exceed the substance's water quality value. The determination is made by developing a preliminary effluent limit (PEL) and comparing it to the potential effluent quality (PEQ) of the discharge.
The DEQ will determine the PELs for every toxic substance the permittee reports as being present in their discharge.
The PEQ for each toxic substance will be developed using individual sample results provided by the permittee.
If the permittee provides at least 1 O representative facility-specific effluent samples that are greater than the detection limit, the maximum PEQ shall equal the upper 95th percentile of all the representative daily discharge concentrations and the average PEQ shall equal the upper 95th percentile of all the representative 3o-day average concentrations.
Reasonable potential for the discharge of a toxic substance to cause or contribute to an excursion above any water quality value will be considered to exist if the average or maximum PEQ exceeds any of the chronic or acute PELs, respectively.
If the permittee is unable to provide 10 effluent samples that are greater than the detection level, the PEQ shall be determined by identifying the total number of representative effluent samples, both detectable and nondetectable, and multiplying the maximum reported value by a multiplying factor found in Table 3 of Rule 1211, (see page 8 in the appendix).
List both detectable and nondeteclable results. Where a result is nondetectable indicate the detection level. Reasonable potential for the discharge of a toxic substance to cause or contribute to an excursion above any water quality value will be considered to exist if the PEQ for a pollutant exceeds its PEL. Attach additional sheets where there are more than ten (10) analytical results. If it is determined that the toxic substance concentration has a reasonable potential to cause or contribute to an excursion above any water quality value, then a WQBEL for that substance will be incorporated into the NPDES permit Samples (ug/I) Toxic Pollutant I 2 3 4 s 6 7 8 9 10 NI A -Internal Outfall Are any of the listed toxic pollutants present in the facility's supply waler? No, Continue to next question.
D Yes, Please read below In accordance with Rule 1211 (7) facilities whose supply water contains toxic pollutants that are withdrawn from and discharged to the same body of ater may qualify for intake credits for those toxic pollutants.
See Rule 1211 (7) for qualification and demonstration requirements.
24 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
-B. Outfall Information mplete a separate Section 111.B. -Outfall Information (pages 17-24) for each outfall at the facility.
Make copies of s blank section of the application if necessary.
PLEASE TYPE OR PRINT FACILITY NAME Palisades Nuclear Plant Receiving Water A. Receiving Water: Lake Michigan County B. County/Township:
Van Buren NPDES PERMIT or COC NUMBER MI0001457 I Township Covert OUTFALL NUMBER 001 Mixing Basin C. State Planar Coordinates:
SE 1/41 NW 1/41 Section 05 I Town 02S l Range 17W Latitude I Longitude 42&deg; 19' 23" 86&deg; 18' 56" D. Latitude/Longitude:
E. Type of Wastewater Discharged (Check all that apply): 181 Contact Cooling D Sanitary Wastewater 181 Process Wastewater 181 Storm Water (regulated)
D other -specify --------Nonconta.ct Cooling 0 Storm Water (not regulated)
F. Is this a Seasonal Discharge?
0 Yes -List the discharge periods (by month) in the space provided below. 181 No -Continue with item G From Through From Through From Through From Through G. Discharge Schedule (Yearly Average):
24 hours/day I 365 days/year I H. Expected or Proposed Discharge Flow Rates: Total Yearty Daily Minimum Daily Average Daily Maximum Maximum Design Flow Rate 85600 MGY .006 MGD 140 MGD 148.3 MGD 234.5 MGD I. The maximum discharge flow rate to be authorized in the permit: __ 2_3_4._5 __ 0 GPO MGD D MGY 0 J. Does this discharge contain storm water subject to effluent guidelines?
8J Yes -indicate under which category.
Stearn Electric D No 17 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
* B. Outfall Information
' mplete a separate Section 111.B. -Outfall lnfonnation (pages 17-24) for each outfall at the facility.
Make copies of s blank section of the application if necessary.
PLEASE TYPE OR PRINT FACILITY NAME Consumers Energy Company, Palisades Nuclear Plant NPDES PERMIT or COC NUMBER: MI0001457 OUTFALL NUMBER 001 4. WATER TREATMENT ADDITIVES Mixing Basin A. Is there a discharge of any water treatment additives or chemicals used to treat water and/or wastewater used or generated by this faciDty ? 0 No -Continue with Item 5. Yes -Provide the following infonnation for each additive.
Provide the Material Safety Data Sheets (MSDS) for each additive as an attachment to this application.
Enter the product name of the additive and name of the manufacturer.
Describe the function of the additive, e.g., biocide, corrosion inhibitor, etc. Provide the average and maximum proposed discharge concentrations of the additive.
Enter the concentrations of the proposed additives after all treatment has occurred.
If the actual proposed discharge concentrations are not known, an estimate shall be made using stoichiometry and/or a mass balance. Provide the proposed discharge frequency in hours per day and days per week or year. Discharge Concentrations Product Name/Name of Manufacturer Additive Function Average Maximum Discharge Frequency U&#xb5;g11 U&#xb5;g11 hours/day Odaystwk
* Omg11 Omg11 0dayslyr U&#xb5;g11 U&#xb5;gll hours/day Odays!wk Omgn. Omgn 0days/yr U&#xb5;gll U&#xb5;gll hours/day 0days/wk Omgn Omg/I 0days/yr lJ&#xb5;g/I lJ&#xb5;gll hours/day lJdays/wk Omgn Omg/I 0days/yr O&#xb5;gll O&#xb5;gll hours/day lJdays/wk Omg11 Omg11 0days/yr O&#xb5;gll O&#xb5;gll hours/day Odaystwk Omg/I Omg/I 0days/yr U&#xb5;gll O&#xb5;g11 hours/day 0days/wk Omg/I Omgll 0days/yr lJ&#xb5;g/I U&#xb5;g11 hours/day Udaystwk Omgn Dmg11 0days/yr B. Table 11 contains a list of the additives for which the DEQ currently has sufficient toxicological data. If the additive this facility is proposing to discharge is not included in Table 11, call the Surface Water Quality Division, Great Lake and Environmental Assessment section at 517-335-4184 to inquire about the status of the specific water treatment additive prior to providing any additional information.
If the DEQ does not have sufficient toxicological information for any additive being proposed for discharge at this facility, the applicant must provide a 48-hour EC50 for a North American planktonic crustacean (Daphnia sp., Ceriodaphnia sp. or Simocephalus sp.) and the results of a toxicity test for one other North American Freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards.
The water treatment additive will not be evaluated for discharge authoriZation unless the appropriate information is attached.
D Aquatic toxicity data is attached.
* C. If the discharge is treated to remove any of the above additives prior to discharge, indicate which additive the treatment is for and briefly describe the treatment process:
* See Attachment 2 of the transmittal letter 18 EQP 4659*C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
* B. Outfall Information
' rnplete a separate Section 111.B. -Outfall lnfonnation (pages 17-24) for each outfall at the facility.
1s blank section of the application if necessary.
Make copies of PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT or COC NUMBER OUTFALL NUMBER Consumers Energy Company, Palisades Nuclear Plant :MI0001457 001 5. PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE Mixing Basin This information is used to determine the applicable federal regulations for this discharge.
The.information required to be reported is dependent on the type of facility.
Page 11 of the appendix contains an abbreviated list of various industries and the types of information each shall report in this application.
Assistance can be received by calling the appropriate district office (see pages 1 and 2 of the appendix}.
All industries shall provide the name of each process and the Standard Industrial Classification (SIC) code for the process. If the wastestream is not regulated under federal categorical standards, the applicant shall report all pollutants which have the reasonable potential to be present in the discharge.
PROCESS INFORMATION A. Name of the process contributing to the discharge:
__ C_o_o_lin
........ g_W_at_e_r_B_lo_w_d_o_w_n
_ _,(._O_u_tf:_hll_O_O_C.,,_)
___________
_ B. SIC code: 4911 --------C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
The cooling towers typically provide cooled water to the condensor.
Periodically, a portion of the cooling tower flow rate is discharged directly to the mixing basin where flow is recorded and reported during discharge
.. PROCESS INFORMATION A. Name of the process contributing to the discharge:
Treated Miscellaneous Low Volume Wastewater B. SIC code: _4_9_1_1 ____ _ C. Describe the process and provide measures of.production (see the instructions to determine the appropriate information to be reported):
TML V waste consist of steam generator blowdown, demineralizer backwash and regeneration waste, reverse osmosis filter backwash, tmbine .sump drainage, floor drain, lab waste, and radwaste wastewater.
PROCESS INFORMATION A. Name of the process contributing to the discharge:
__
____ __, ________ _ B. SIC code: 4911 --------C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
This process removes suspendid solids and radioactivity by collection, evaporation distillation and demineralizer prior to discharging at Outfall OOD. See Section I, Exhibit 1-11 for detailed flow information.
PROCESS INFORMATION A. Name of the process contributing to the discharge:
_T_mb __ in_e_S_um__.p,__D_rai_*_na_,g"'"e_(,_O_u...;tf:_hl_l_O_O_F_,,)
______________
_ B. SIC code: 4911 --------C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
The turbine building sump collects filtered floor drainage from the turbine building which is treated by the oil/water separator prior to discharging to Outfall OOF. See Section I, Exhibit 1-11 for detailed flow information.
PROCESS INFORMATION A. Name of the process contributing to the discharge:
__ F_l_o_or_D_rama_*__,g"'"e---------------------
B. SIC code: 4911 --------C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
Floor drainage from Plant secondary system is drained to the turbine sump. Auxilliruy building floor drainage is processed through the rad waste system eventually to Outfall OOD. See Section I, Exhibit 1-11 flow diagram. 19 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
*
* B. Outfall Information mplete a separate Section 111.B. -Outfall Information (pages 17-24) for each outfall at the facility.
1s blank section of the application if necessary.
PLEASE TYPE OR PRINT Make copies of FACILITY NAME NPDES PERMIT or COC NUMBER MI0001457 OUTFALL NUMBER Consumers Ener Com an Palisades Nuclear Plant 5. PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE This information is used to determine the applicable federal regulations for this discharge.
The information required to be reported is dependent on the type of facility.
Page 11 of the appendix contains an abbreviated list of various industries and the types of information each shall report in this application.
Assistance can be received by calling the appropriate district office (see pages 1 and 2 of the appendix).
All industries shall provide the name of each process and the Standard Industrial Classification (SIC) code for the process. If the wastestream is not regulated under federal categorical standards, the applicant shall report all pollutants which have the reasonable potential to be present in the discharge.
PROCESS INFORMATION A. Name of the process contributing to the discharge:
___ U_ns_pL..e_c_ifi_1_ed_am_o_unt_o_f_S.:..t;;.;;o_rm_W__;,a;...te_r
_____________
_ B. SIC code: _4_9_1_1 ____ _ C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
An unspecified amount of storm water is discharged to the mixing basin prior to discharging at Outfall 001 to Lake Michigan.
PROCESS INFORMATION A. Name of the process contributing to the discharge:
___ N_IA ________________________
_ B. SIC code:--------
C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
PROCESS INFORMATION A. Name of the process contributing to the discharge:
-----------------------------
B. SIC code:--------
C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
PROCESS INFORMATION A. Name of the process contributing to the discharge:
-----------------------------
B. SIC cOde: --------C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
PROCESS INFORMATION A. Name of the process contributing to the discharge:
-----------------------------
B. SIC code: _______ _ C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):
19 EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater B. Outfall Information
**mplete a separate Section 111.8.-Outfall Information (pages 17-24) for each outfall at the facility.
Make copies of 1s blank section of the application if necessary.
PLEASE TYPE OR PRINT FACILITY NAME I NPDES or COC PERMIT NUMBER Consumers Energy Company, Palisades Nuclear Plant MI0001457
: 6. WASTEWATER CHARACTERISTICS
-CONVENTIONAL POLLUTANTS Instructions for completing this page are on the facing page. 0 Check this box if additional information is included as an attachment.
Maximum Maximum Parameter Daily Monthly Concentration Concentration Biochemical Oxygen Demand -five day (800 5) <2 *(l) COD (Chemical oxygen demand) 8 *(l) TDC (Total organic carbon) 2.5 *(l) Ammonia Nitrogen (as N) .02 *(l) Total Suspended Solids .6 *(l) Total Dissolved Solids NIA *fl) Total Phosphorus (as P) .08 *(l) .cal Coliform Bacteria maximum-7day NIA *(l) Total Residual Chlorine 27 80 minimum daily Dissolved Oxygen 6.8 *(1) pH minimum maximum (report maximum and minimum of individual samples) 7.85 *(2) 8.86 *(2) Temperature, Summer 101 *(2) 110 *(2) Temperature, Winter 87 *(2) 95 *(2) Oil & Grease NIA *(1) *(l) The Company is requestrng a wru.verfrom this reporting reqmrement.
*(2) Values are based on DMR data 21 Units mg/1 mg/1 mg/1 mg/I mg/I mg/1 mg/I counts/1 OOml U mg/I 5'i &#xb5;g/I mg/I Standard Units i8l *F D *c l8j *F 0 *c mg/I ug/1 mg/I I Outfall Number 001 Mixing Basin Number of Analyses Sample Type I D 24 Hr Comp 5'l Grab I 0 24HrComp iJ Grab 1 0 24HrComp bCJ Grab 1 0 24HrComp I D 24 Hr Comp Grab 0 24HrComp I C 24 Hr Comp Grab 132 Grab 1 Grab 8760 Grab 3672 Grab 5088 Grab Grab LJ Grab 0 24HrComp D Grab 0 24 Hr Comp LJ Grab 0 24HrComp LJ Grab 0 24 Hr Comp D Grab 0 24 Hr Comp LJ Grab 0 24HrComp
* U Grab 0 24 Hr Comp EQP 4659-C (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill ... Industrial and Commercial Wastewater
* 8. Outfall Information mplete a separate Section 111.B. -Outfall lnfonnation (pages 17-24) for each outfall at the facility.
1s blank section of the application if necessary.
PLEASE TYPE OR PRINT Make copies of FACILITY NAME NPDES or CCC PERMIT NUMBER OUTFALL NUMBER Consumers Energy Company, Palisades Nuclear Plant MIOOO 1457 001 7. PRIMARY INDUSTRY TOXIC POLLUTANT INFORMATION Mixing Basin COMPLETE THIS ITEM ONLY IF THE FACILITY IS A PRIMARY INDUSTRY AS INDICATED IN ITEM 1 OF THIS SECTION. IF THIS IS NOT A PRIMARY INDUSTRY, CONTINUE WITH ITEM 8. For two or more substantially identical outfalls, permission may be requested from the appropriate district supervisor to sample and analyze only one outfall and submit the results of the analysis for other substantially identical outfall(s).
If the request is granted by the District Supervisor, attach a narrative describing which outfall was sampled, and describe why the outfalls which were not sampled are substantially similar to the outfall that was sampled. A. Indicate if the discharge from this outfall contains any process wastewater.
If the discharge from this outfall contains process wastewater, check YES and continue with B below. If the discharge from this outfall does not contain any process wastewater, check NO and continue with item 8. Does this outfall discharge contain any process wastewater? Yes, Continue with B. 0 No, Continue with Item 8. See Outfall 001 results Attachment c ' B. Primary Industries must submit test results for organic toxic pollutants.
Table 2 in the appendix contains a list of GC/MS fractions required by each industrial Category.
Indicate the GC/MS fractions required for the facility Industrial Category.
See Attachment C Volatile Base/Neutral Acid 0 Pesticide Provide analytical data for each parameter of the GC/MS fraction checked above. The required parameters in each fraction are specified in Table 3 in the appendix.
Provide copies of the analytical results or record the information in Item 9. Additionally, all primary industries which discharge process wastewater shall provide quantitative data for the parameters specified in Table 4 in the appendix.
Applicants are not required to analyze for 2,3,7,8-TCDD (Dioxin) unless they believe it is present in the discharge.
ADDITIONAL TOXIC POLLUTANT INFORMATION A. If an applicant, regardless of the type of discharge, knows or has reason to believe that any pollutant listed in Tables 3, 4, 5, 7 and 8 is discharged from any outfall, then quantitative data shall be provided for those pollutants.
0 Not Applicable/Believed Absent Present -Data is attached or recorded in Item 9. B. If an applicant (primary or secondary industry), regardless of the type of discharge, knows or has reason to believe any pollutants listed in Table 6 are discharged from any outfall, the applicant shall describe reasons for the pollutant being present and provide any available quantitative data. 0 Not Applicable/Believed Absent Present -Data is attached or recorded in Item 9. C. All applicants (primary and secondary industries) who use or manufacture 2,4,5-trichlorophenoxy acetic acid (2,4,5-T);
2-(2,4,5-trichlorophenoxy) propanoic acid (Silvex);
2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloroproprionate (Erben); 0,0-Dimethyl 0-(2,4,5-Trichlorophenyl)
Phosphorothioate (Ronne!);
2,4,5-trichlorophenol (TCP); or Hexachlorophene (HCP) must report data using standard analytical calibration procedures.
All surface water discharge applicants (primary and secondary industries) who know or have reason to believe that 2,3,7,8-Tetrachlorodibenzo-P-Dioxin (TCDD) is or may be present in their discharge must report qualitative data generated using a screening procedure not calibrated with analytical standards for TCDD. Not Applicable/Believed Absent 0 Present -Data is attached or recorded in Item 9. D. If the applicant knows or has reason to believe that biological tests (including WET tests) were made in the last three (3) years on any of the applicant's discharges or on a receiving water in relation to the discharge(s), provide this information as an attachment to this application.
0 Not Applicable Applicable
-Data is attached.
See Attachment D E. If a contract laboratory or consulting firm performed any of the analyses required by this application, provide the name and address of each laboratory or firm as an attachment to this application.
See Attachment B in the back of this D Not Applicable Applicable
-Information is provided.
Permit Application F. Does the facility discharge any other toxic or injurious chemical substances not listed in Tables 3 through 9 in the appendix ? No. Continue with Section 111.C. 0 Yes. Data is attached or recorded in Item 9. 22 EQP 4659-C (Rev 1/98) 
" Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater B. Outfall Information mplete a separate Section 111.B. -Outfall Information (pages 17-24) for each outfall at the facility.
s blank section of the application if necessary.
Make copies of PLEASE TYPE OR PRINT FACILllY NAME I NPDES or COC PERMIT NUMBER I OUTFALL NUMBER Consumers Energy Company, Palisades Nuclear Plant MI0001457 001 9. . EFFLUENT CHARACTERISTICS
-TOXIC POLLUTANTS Mixing Basin This worksheet is to be used by applicants to record information on any Michigan Critical Material, EPA Priority Pollutant, or hazardous substance for which this application requires that data be provided.
This includes any substance from Table 3 which lists Organic Toxic Pollutants, Table 4, Other Toxic Pollutants, Table 5, Conventional and Nonconventional Pollutants, Table 6, Toxic Pollutants and Hazardous Substances, Table 7 the Michigan Critical Materials Register, or Table 8 the EPA Priority Pollutant Listing. If the applicant believes a pollutant may be present in the effluent that is not included in these lists, data shall be provided for that pollutant with this application.
This information may also be included as an attachment to this application on 8 112" x 11" paper. Page 12 of the appendix is a list of minimum testing requirements for various dischargers.
As a minimum applicants for those types of discharge must provide analytical data based on that list. Applicants shall use EPA approved analytical methods when conducting sampling.
For each parameter provide the name of the parameter as listed in the Tables, the maximum daily and monthly discharge concentrations, units, the number of analyses performed, and the sample type. If analytical results for a composite sample are being provided and the sample is not a 24-hour composite, include a description of the sample collection technique used as an attachment to this application on 8 112* x 11" paper. When calculating an average where some values are detectable and others are nondetectable, either provide the actual data, or regard each nondetectable value as the detection level when calculating concentrations and indicate that the result is "less than" the value reported. (See definitions of "daily concentration" and "monthly concentration" in the general provisions at the front of this form.) Please include an explanation if "Pollution Prevention*
is expected to provide reductions of pollutants. (See page ii and iii for sampling definitions, including, "daily concentration", and "monthly concentration".)
See Table 12 in the appendix for acceptable
'Levels of Quantification".
ig Check this box if additional information is included as an attachment.
Maximum Maximum Dally Monthly Quantification Number Concentration Concentration Level of Sample Toxic Pollutant (ua/ll (uQ/I) luQ/ll Analvses Type D Grab Hydrazine Nondetect Nondetect U!!ll 4 0 24HrComp Sodium Hypochlorite 27 80 ug/l 1132 0 24HrComp LJ Grab 0 24HrComp D Grab 0 24 Hr Comp LJ Grab 0 24HrComp 0 Grab 0 24HrComp LJ Grab 0 24 Hr Comp U Grab 0 24 Hr Comp LJ Grab D 24 Hr Comp 0 Grab 0 24 Hr Comp U Grab 0 24HrComp LJ Grab 0 24 Hr Comp ' U Grab 0 24HrComp U Grab 0 24HrComp 23 EQP 4659-C (Rev 1/98)
* Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION Ill -Industrial and Commercial Wastewater
-B. Outfall Information mplete a separate Section_ 111.B.-Outfall Information (pages 17-24) for each outfall at the facility.
s blank section of the application if necessary.
Make copies of PLEASE TYPE OR PRINT FACILITY NAME I NPDES or COC PERMIT NUMBER I OUTFALL NUMBER Consumers Energy Company, Palisades Nuclear Plant MI0001457 001 10. TOXIC POLLUTANT REASONABLE POTENTIAL EFFLUENT DATA Mixing Basin In addition to the above information and in accordance with Rule 1211 of the Part 8 Rules (see pages 7-10 in the appendix), for each toxic substance which is or may be discharged from the facility, the applicant must provide individual sample data to determine if Water Quality Based Effluent Limits (WQBELs) are necessary.
WQBELs for toxic pollutants are incorporated into an NPDES permit when the DEQ has determined that a substance is or may be discharged into the waters of the state at a level that has a reasonable potential to exceed the substance's water quality value. The determination is made by developing a preliminary effluent limit (PEL) and comparing it to the potential effluent quality (PEQ) of the discharge.
The DEQ will determine the PELs for every toxic substance the permittee reports as being present in their discharge.
The PEQ for each toxic substance will be developed using individual sample results provided by the permittee.
If the permittee provides at least 1 O representative facility-specific effluent samples that are greater than the detection limit, the maximum PEQ shall equal the upper 95th percentile of all the representative daily discharge concentrations and the average PEO shall equal the upper 95th percentile of all the representative 3Q-day average concentrations.
Reasonable potential for the discharge of a toxic substance to cause or contribute to an excursion above any water quality value will be considered to exist if the average or maximum PEQ exceeds any of the chronic or acute PELs, respectively.
If the permittee is unable to provide 1 O effluent samples that are greater than the detection level, the PEQ shall be determined by identifying the total number of representative effluent samples, both detectable and nondetectable, and multiplying the maximum reported value by a multiplying factor found in Table 3 of Rule 1211, (see page 6 in the appendix).
List both delectable and nondetectable results. Where a result is nondetectable indicate the detection level. Reasonable potential for the discharge of a toxic substance to cause or contribute to an excursion above any water quality value will be considered to exist if the PEQ for a pollutant exceeds its PEL. Attach additional sheets where there are more than ten (1 O) analytical results. If it is determined that the toxic substance concentration has a reasonable potential to cause or contribute to an excursion above any water quality value, then a WQBEL for that substance will be incorporated into the NPDES permil Samples (ug/I) Toxic Pollutant 1 2 3 4 5 6 7 8 9 10
* Are any of the above listed toxic pollutants present in the facility's supply water? D No, Continue to next question.
D Yes, Please read below In accordanl:e with Rule 1211 (7) facilities whose supply water contains toxic pollutants that are withdrawn from and discharged to the same body of water-may qualify for intake credits for those toxic pollutants.
See Rule 1211 (7) for qualification and demonstration requirements .
* Aquatic toxicity data is provided for additives that may detect or suspect to detect toxic pollutantS in Outfall 00 I discharge . . However, additives suspect of toxic pollutants that have currently been approved for use through the previous NPDES permit renewal ** ' processes, may not include aqutaic toxity data on that particular additive.
Most often a limit has been applied by the Department on each particular additive of concern through individual approvals, a11d each limit has been met during treatment 24 'E(..!P (Rev 1/98)
Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION "ASE TYPE OR PRINT CILITYNAME SECTION Ill -Industrial and Commercial Wastewater C. Signature Page Consumers Ener Com anv Palisades Nuclear Plant NPDES or COC PERMIT NUMBER (existing pe""its only) 0001457 11. CERTIFICATION Rule 323.2114(1-4) of the Part 21 Rules of Michigan Act 451, Public Act of 1994, Part 31, as amended, requires that this application be signed as follows: A. For a corporation, by a principal executive officer of at least the level of vice president.
or their designated representative if the representative is responsible for the overall operation of the facility from which the discharge described in the pe""it application or other NPDES fo"" originates.
B. For a partnership, by a general partner. C. For a sole proprietorship, by the proprietor.
D. For a municipal, state, or other public facility, by either a principal executive officer, the mayor, village president, city or village manager or other duly authorized employee.
*1 certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified j)ersonnel properly gather and evaluate the information submitted.
Based on my inquiry of the person or persons wno manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief. true, accurate, and complete.
I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for having knOwledge of violations." Print Name: Thomas J. Palmisano rrtle: Site Vice President Representing Consumers Energy Company, Palisades Nuclear Plant Signature:
Date: This completes Section Ill. Section Ill must be completed for all applicants requesting authorization to discharge wastewater(s) from an industrial or commercial facility to a surface water of the State. When Section I and Ill are complete please the return application to the appropriate district office (see pages 2 and 3 of the appendix for district office addresses and a map of district boundaries).
If assistance is needed in determining the appropriate sections to complete or If assistance is needed completing this application contact the appropriate district office *
* 25 EQP 4659-C (Rev 1/98) 
* * * **;. .. , t ATTACHMENT.
A PALISADES NUCLEAR PLANT, NPDES PERMIT APPLICATION Section I, 8 -Reissuance of Permit Antidegradation Rule 1098-Increased Discharge Volume Purpose for the Increase The Consumers Energy Company, Palisades Nuclear Plant is requesting an increase in the use and authorized discharge flow volume for Outfall 001 in order to remain competitive in energy generation forced by deregulation.
The Plant is requesting to increase the volume of the intake dilution water pumps from a maximum design flow of 60,000 gpm to a maximum design flow of 120,000 gpm. By doubling the current dilution water make-up flow, an additional 5 MW output of electricity can be generated.
This will allow the Palisades Nuclear Plant to operate more competitively in the market of generating electricity.
Initially, the project is estimated to cost the Company $1.5 -2.2 million dollars. But, this project is a necessary benefit to the Palisades Plant in order for it to remain competitive in the future. Environmental Impact The higher make-up water flow will lower the concentration discharge of pollutants.
The in dilution water will essentially reduce concnetrqtions of existing loadings associated with the operation of the Plant. However, as shown in Attachment C that follows and also in Section III, B 6., Wastewater Characteristics results for Outfall 001, existing Outfall 001 pollutant loadings are already below water quality standards, and most are below detection supporting the waiver request for applicable parameters.
Impact on Outfall 001 Parameters of Concern The authorized discharge flow at Outfall 001 will increase from a maximum design flow of 135.2 MGD to 234.5 MGD. We anticipate that the increased flow will be in compliance with already existing Total Residual Oxidant daily maximum limits associated with continuous or intermittent chlorination, or during bromine application.
The previously approved sodium hypochlorite detailed treatment information may be altered but, details are not yet available.
For the present time, the Plant will continue to chlorinate according to the historical treatment approval.
The Plant will work with the Department if it is discovered that effective chlorination treatment cannot be attained as currently approved.
' The Plant will address the Betz Clamtrol CT-2 and 4 applications in the same manner. If the currently approved application of treatment has to be revised to reflect effectiveness then, the Plant will work with the Department to ensure that effective treatment is provided without exceeding associated permit limits while continuing protecting the aquatic life in the receiving water body. 
** *
* Temperature
-Heat Addition The Plant staff has investigated the temperature loadings associated with the dilution water increase using 1996-97 current discharge flows, intake and discharge temperatures, and heat addition.
Investigation shows that the increase in flow volume will not cause an exceedance of the current heat addition (BTU/Hr) NPDES Permit limit. Based on lake intake temperatures, the Plant can continue to operate under the existing Heat Addition BTU/Hour daily maximum limit of 21,000 MBTU/Hr. The higher flow will reduce temperature in the discharge.
The cooling towers will continue to be utilized and adjusted to accommodate the increased flow. Actually, the Plant anticipates a reduction in discharge temperature in the 1-5 degree range. These temperature reductions will mitigate potential impacts to the aquatic environment.
Rule 1098 -Antideqradation Exemption Based on the information provided above, the Consumers Energy Company, Palisades Nuclear Plant anticipates an increase in the flows at intake 000 and at discharge Outfall 001 to Lake Michigan.
However, the Plant does not expect any increase in pollutant loadings (nonBCC or BCC associated).
As a result of the increase in flow, the existing uses and water quality of Lake Michigan will remain protected.
* The Company feels the increase applies to several antidegradation exemptions stated by the following and do not constitute a lowering of water quality: Rule 1098 . Lake Michigan is not a listed designated Outstanding State Resource Water, (7)(d) Discharges of pollutant quantities from the intake water for the Palisades Nuclear Plant are not a lowering of water quality because the intake and the discharge are on the same body of water, Lake Michigan, (i) There will be no increased loadings of nonBCC's (heat) within the authbrized levels of a limit in the existing NPDES permit, (8)(a)(i)
The increased discharge will remain within the existing processes that are currently covered under the existing applicable control document such as a normal operational variability (including cooling tower operation), (iv) The increased discharge will result in an increase in electric MW generation.
However, the process will not change or increase and continue to remain as described under the current controlled document . Based on the information above, the Company requests the approval to increase the Intake 000 and Outfall 001 water flows accordingly without the need to develop and provide an antidegradation demonstration. 
* *
* ATTACHMENT 8 1 PALISADES NUCLEAR PLANT NPDES PERMIT APPLICATION Section III, B 8 (E) Laboratory Information The laboratories used for analysis of NPDES Permit testing requirements associated with the administration of this permit application including the chronic toxicity assessment results is: Consumers Energy Company, Trail St Laboratory 135 W. Trail Street Jackson, MI 49201 (517) 788-1251 GC/MS Fractions
& Conventional Michigan Department of Environmental Quality Laboratory P.O. Box 30630 Lansing, MI 48909-8130 Chronic Toxicity 
* * * *; ATTACHMENT C !* PALISADES NUCLEAR PLANT, NPDES PERMIT APPLICATION Section III, B 5 -
Characteristics
-Conventional Pollutants FOR Intake 000 and Outfall 001 
'* '* * *
* Palisades
'.\uclear Plant NPDES Pennit -Water Characteristics Analysis File Index: 529717-123-472 CRITICAL lVIATERIALS, TOXIC AND HAZARDOUS SUBSTANCES Samples Date: 7 {I0/97 OTHER TOXIC POLLUTANTS Intake Outfall Detection EPA Parameter Units 000 001 Limit* Method Cyanide, Total &#xb5;g!L <5 <5 5 335. 1 Cyanide, Amendable
&#xb5;g!L <5 <5 5 335. 1 Antimony, Total &#xb5;g!L <1 <1 I 204.2 Arsenic, Total &#xb5;g!L <1 <I I 206.2 Beryllium, Total &#xb5;g!L <I <1 50 210.2 Cadmium, Total &#xb5;g/L <0.2 <0.2 0.2 213.2 Chromium, Total &#xb5;g/L <IO <IO 10 218.2 Copper, Total &#xb5;g!L. 3 2 1 220.2 Lead, Total &#xb5;g/L 2 1 I 239.2 Mercury, Total &#xb5;g!L <0.2 <0.2. 0.2 245.1 Nickel, Total &#xb5;g/L <5 <5 5 249.2 Selenium, Total &#xb5;g!L <1 <I 2 270.2 Silver, Total &#xb5;g!L <0.5 <0.5 0.5 272.2 Thallium, Total &#xb5;g/L <l <l 1 279.l Zinc, Total &#xb5;g!L <10 <10 10 289.l *MDEQ. Required detection limit. OTHER QUANTITIES MEASURED Intake Outfall Detection Date EPA Parameter Units 000 001 Limit* Analyzed Method pH SU 7.8 8.2 0.1 07/10/97 150.l Hexavalent Chromium &#xb5;g/L <s <5 5 07/10/97 218.5 Specific Conductance
&#xb5;mho/cm 363 325 10 07/21197 120.l 0797-105-CHEM 13-BLS 
* *
* 3 Palisades Plant NPDES Pem1it -Water Characteristics Analysis File Index: 529717-123-4 72 CRITICAL MATERIALS, TOXIC POLLUTANTS AND HAZARDOUS SUBSTANCES VOLATILES Detection Parameter Units Results Limit* Acrolein &#xb5;g/L ND 10 Acrylonitrile
&#xb5;g/L ND 6 Benzene &#xb5;g!L ND I Bromoform
&#xb5;g!L ND 2 Carbon Tetrachloride
&#xb5;g!L ND 2 Chlorobenzene
&#xb5;g!L ND I Chlorodibromomethane
&#xb5;g!L ND 2 Chloroethane (75-00-3)
&#xb5;g!L ND 2 I, 1-Dichlorobromomethane
&#xb5;g/L ND I I, 1-Dichloroethane
&#xb5;g!L ND I 1,2-Dichloroethane
&#xb5;g!L ND I I, 1-Dichloroethylene
&#xb5;g/L ND I 1,2-Dichloropropane
&#xb5;g!L ND I 1,3-Dichloropropy lene &#xb5;g!L ND I Ethyl benzene &#xb5;g!L ND I Methyl Bromide &#xb5;g!L ND I Methyl Chloride &#xb5;g/L ND I Methylene Chloride &#xb5;g!L ND 5 I, 1,2,2-Tetrachloroethane
&#xb5;g!L ND I Tetrachloroethylene
&#xb5;g!L ND I Toluene &#xb5;g!L ND I 1,2-Trans-Dichloroethylene
&#xb5;g!L ND I I, I, I-Trichloroethane . &#xb5;g!L ND I I, 1,2-Trichloroethane
&#xb5;g!L ND I Trichloroethylene
&#xb5;g!L ND I Vinyl Chloride &#xb5;g!L ND I *MDEQ required detection limit ND =Not detected at MDEQ required detection limits 0797-I 05-CHEM 13-BLS 
* *
* 4 Palisades
:'\uclear Plant NPDES Pennit -Water Ch:i.racteristics Analysis File Index: 529717-123-472 CRITICAL MATERIALS, TOXIC POLLUTANTS AND HAZARDOUS SUBSTANCES BASE/NEUTRAL Detection Parameter . Units Results Limit* Acenaphthene (83-32-9)
&#xb5;g/L ND 1 Acenaphthylene (208-96-8)
&#xb5;.g/L' ND 1 Anthracene ( 120-12-7) &#xb5;.g/L ND 1 Benzidene (92-87-5)
&#xb5;.g/L ND 3 Benzo (a) Anthracene (56-55-3)
&#xb5;.g/L ND 1 . Benzo (a) Pyrene (50-32-8)
&#xb5;.g/L ND 1 3,4-Benzofluoranthene (205-99-2)
&#xb5;.g/L ND 2 Benzo (ghi) Perylene (191-24-2)
&#xb5;.g/L ND 3 Benzo (k) Fluoranthene (207-08-9)
&#xb5;.g/L ND 2 Bis (2-Chloroethoxy)
Methane (111-91-1)
&#xb5;.g/L ND 1 Bis (2-Chloroethyl)
Ether &#xb5;.g/L ND 1 Bis (2-Chloroisopropyl)
Ether (39638-32-9)
&#xb5;.g/L ND 2 Bis (2-Ethylhexyl)
Phthalate (117-81-7)
&#xb5;.g/L ND 5 Butylbeniyl Phthalate (85-68-7)
&#xb5;.g/L ND 1 2-Chloronaphthalene (91-58-7) &#xb5;.g/L ND 1 4-Chlorophenyl Phenyl Ether (7005-72-3)
&#xb5;.g/L ND 1 Chrysene (218-01-9)
*&#xb5;.g/L ND 1 Dibenzo (a,h) Anthracene (53-70-3)
&#xb5;.g/L ND 3 1,2-Dichlorobenzene (95-50-l) &#xb5;.g/L ND 1 1,3-Dichlorobenzene (541-73-1)
&#xb5;.g/L ND 1 1,4-Dichlorobenzene (106-46-7)
&#xb5;.g/L ND l 3,3-Dichlorobenzidene (91-94-1)
&#xb5;.g/L ND 3 Diethyl Phthalate (84-74-2)
&#xb5;.g/L ND l Dimethyl Phthalate (131-11-3)
&#xb5;.g/L ND 1 Di-N-Butyl Phthalate (84-74-2)
&#xb5;.g/L ND l 2,4-Dinitrotoluene (121-14-2)
&#xb5;.g/L ND 5 2,6-Dinitrotoluene (606-20-2)
&#xb5;.g/L ND 5 Di-N-Octyl Phthalate (117-84-0)
&#xb5;.g/L ND 1 1, 2-Dipheny
!hydrazine ( 122-66-7) &#xb5;.g/L ND 1 Fluoranthene (206-44-0)
&#xb5;.g/L ND 1 Fluorene (86-73-7) &#xb5;.g/L ND 1 Hexachlorobenzene ( 118-71-1) &#xb5;.g/L ND 1 Hexachlorobutadiene (87-68-3)
&#xb5;.g/L ND 1 Hexachlorocyclopentadiene (77-4 7-4) &#xb5;.g/L ND 1 Hexachloroethane ( 67-72-1) &#xb5;.g/L ND 1 lndeno (1, 1,3-cd) Pyrene (193-39-5)
&#xb5;.g/L ND 2 lsophorene (78-59-1)
&#xb5;.g/L ND 2 0797-105-CHEM 13-BLS 
,. ' I ,\ * * * , **,; . .. . Palisades Plant NPDES Permit -Water Characteristics Analysis File Index: 529717-123-472 CRITICAL MATERIALS, TOXIC POLLUTM'TS HAZARDOUS SUBSTANCES BASEf.\"EUTRAL (Cont'd) Detection Parameter Units Results Limit* Naphthalene (91-20-3)
&#xb5;g/L ND 1 Nitrobenzene (98-95-3)
&#xb5;g/L ND 1 N-Nitrosodimethylamine (62-75-9)
&#xb5;g/L ND 1 N-Nitrosodi-N-Propylamine (621-64-7)
&#xb5;g/L ND 3 N-Nitrosodiphenylamine (86-30-6)
&#xb5;g/L --ND 1 Phenamhrene (85-01-8)
&#xb5;g/L ND 1 Pyrene ( 129-00-0)
&#xb5;g/L ND -1 1,2,4-Trichlorobenzene (120-82-1) 1-1:g/L ND 1 *MDEQ required detection limit. ND = Not detected at MDEQ required detection limit. ACID COMPOUND Detection Parameter Units Results Limit 2-Chlorophenol
&#xb5;g/L ND 0.7 2,4-Dichlorophenol
&#xb5;g/L ND 0.7 2,4-Dimethylphenol
&#xb5;g/L ND 0.7 2,6-Dinitro-O-Cresol
&#xb5;g/L ND 1 2,4-Dinitrophenol
&#xb5;g/L ND 3 2-Nitrophenol
&#xb5;g/L ND 0.7 4-Nitrophenol
&#xb5;g/L ND 3 P-Chloro-M-Cresol
&#xb5;g/L ND 1 Pentachlorophenol
&#xb5;g/L ND 3 Phenol &#xb5;g/L ND 0.7 2, 4, 6-T richlorophenol
&#xb5;g/L ND 0.7 ND = Not detected One or more surrogates failed QA criteria . "Concentrations are therefore reported as ESTIMATED.
0797-105-CHEM 13-BLS I ** *
* ATTACHMENT D PALISADES NUCLEAR PLANT, NPDES PERMIT APPLICATION Section III, B 8 -001 Wastewater Characterization Outfall 001 Chronic Toxicity Assessment Results 
' , * *
* ECP 0100e (Rev. 10/96) STATE OF MICHIGAN . JOHN ENGLER, Governor DEPARTMENT OF ENVIRONMENTAL QUALITY Mr. Eric Dehn Consumer's Palisades Plant . 27780 Blue Star Highway Covert, Michigan 49043 HOLLISTER BUILDING, PO BOX 30473, LANSING Ml 411909-7973 INTERNET:
http:IJwww.deq.*tale.mlu*
RUSSELL J, HARDING, DIA!ICIDr November 7, 1997
 
==SUBJECT:==
Chronic Toxicity Report of 10/22/96
 
==Dear Dehn:==
REPLY TO: PlAINWEU.
DISTRICT OFFICE 1342 SR 89 W STE B Pl.AINWELL Ml 49080-1915 Enclosed for your records is the report from the chronic toxicity samples which were collected at your plant on October 22-29, 1996. The report found no problems at your facility during the days of the sampling.
Therefore, no reply is necessary . Congratulations on the good report, and thank you very much for your cooperation.
JV:cab Enclosure cc/enc: SWQD Permits Sincerely, Environmental Quality Analyst Plainwell District Office Surface Water Quality Division 616-692-6965 
' . .. * * **; Ml/DEQ/SWQ-96/140 MICHIGAN DEPARTMENT OF ENVIRONMENT AL QUALITY SURF ACE WATER QUALITY DIVISION DECEMBER 1996 STAFF REPORT CHRONIC TOXICITY ASSESSMENT OF CPCO-PALISADES POWERPLT OUTFALLOOlEFFLUENT COVERT, MICHIGAN OCTOBER 22-29, 1996 NPDES PERMIT NO. MI0001457 Staff of the Great Lakes and Environmental Assessment Section (GLEAS) performed a Ceriodaphnia dubia chronic toxicity test on grab samples of the CPCO-Palisades Pit outfall 00 l effluent from Oct0ber 22-29, 1996. The facility was operating normally when the samples were collected.
Toxicity testing was performed according to GLEAS Procedure
#54 (procedure available upon request).
The facility does chlorinate the effluent.
However, the facility was not chlorinating at the time of sample collection.
Therefore, dechlorination was not necessary.
The facility discharges cooling tower blow down, non-contact cooling water, and treated miscellaneous low volume wastewater consisting of steam generator blowdown, demineralizer backwash and regeneration waste, reverse osmosi:; filter backwash, turbine sump drainage, floor drainage, laboratory waste, radwaste wastewater to Lake Michigan (authorized discharge 135.2 mgd). The receiving water concentration (RWC) of the effluent is 100% effluent.
* 1.
 
==SUMMARY==
Water quality parameters met minimum test criteria (data available upon request), except on day 3, when temperatures fell slightly below recommended test temperatures (25&deg;+/-1&deg;).
However, we do not believe this had any impact on the test. 2. The effluent was not acutely or chronically toxic to Ceriodaphnia dubia (Table 1). 3. Based on the results of this study, the effluent was meeting the aquatic toxicity-related requirements of Rules 82 and 57 of the Michigan Water Quality Standards.
Test and report by: Diana Butler, Laboratory Technician Water Quality Appraisal Unit North Great Lakes and Environmental Assessment Section Reviewed by: William Dimond, Aquatic Biologist/Lead Worker Water Quality Appraisal Unit North Great Lakes and Environmental Assessment Section 1 
., * *
* Table 1. Mean reproduction and percent survival of Ceriodaphnia dubia exposed to select concentrations of CPCO-Palisades Power Pit outfall 001 effluent from October 22-29, 1996 . Percent Survival Percent Average Day Day Day Effluent Young/ 1 2 7 Adult Control* 21.7 100 100 100 6.25 26.8 100 100 100 12.5 27.2 100 100 100 25 29.0 100 100 100 50 29.9 100 100 100 *------100 26.4 100 100 90 *Control was moderately hard dilute mineral water. Table lb. Test Solution Control 100% Summary of water quality characteristics of fresh test solutions for the Ceriodaphnia dubia survival and reproduction test of CPCO-Palisades Power Pit outfall 001 eflluent.
pH Dissolved CS.U.l T emQerature(&deg;C) 7.72-7.92 7.9-8.0 24.0-24.9 8.00-8.31 7.6-8.6 24.1-25.0 2 
. *-.,
* t ATTACHMENT 2 ' * *Pcf1 of *2
* Palisades Plant-NPDES Permit No. MI0001457 Outfall Water Treatment Additives -Aquatic Toxicity Data None MSDS MSDS MSDS MSDS Chemical Name Sodium Hypochlorite Nalco ActiBrom Sodium Bisulfite DT1403) Betz-Dearborn CT-2 *(Spectrus CT 1300) Betz-Dearborn CT-4 Betz-Dearborn DTS *(Spectrus DT1400)
* name change only Application Chlorination of Condenser
& Cooling Water Biofouling Control Dechlorinating Agent Zebra Mussel and Asiatic Clam Control Zebra Mussel and Asiatic Clam Control Used to Detoxify CT-2,CT-4 Approval Status Outfall Approved in Current Permit OOA,B,C,F, 001 Approved in Current Permit OOA,B,C,001 Approved in Current Permit OOA,B,C,001 Approved in Current Permit OOA,B,C,001 Approved in Current Permit OOA,B,C,001 Approved in Current Permit OOA,B,C,001 Other Systems which may discharge into the combined Discharge of Outfall 001 Aquatic Toxicity MSDS None MSDS \System Steam Generators Chemical Hydrazine Morpholine Boric Acid Nalco 1250 .Plus Application Oxygen Scavenger used to control corrosion Used for pH control Corrosion Control Corrosion Control Approval StatusData Outfall Approved in Current Permit OOA,B,C,F and 001 Approved in Current Permit OOF, 001 Approved in Current Permit OOA,B,D, and 001 MDEQ approval letter dated OOA,B,D, 10-31-96 and 001
* Aquatic Toxicity Data MSDS System Application Cooling Towers Chemical BetzDearborn PAL02 Organic Scale Inhibitor
*(Depositrol BL5301) Component Cooling System None fJ011e MSbS t>lone Chemical Sodium Nitrite Reverse Osmosis Unit Chemical
* Aluminum Sulfate Makeup Demineralizer Chemical Sulfuric Acid Sodium Hydroxide Chemicals Pending Approval ***; MSDS MSDS BetzDearborn Spectrus Nxtt 00 Alconox Detergent 8 Rad Decon Agent *name change only .. ,. Corrosion Inhibitor Scale Control Demineralizer Resin Rinse Demineralizer Resin Rinse Radwaste tank Biofouling Control Primary & Radwaste System ATTACHMENT 2 Pg 2 of2 Approval Status MDNR approval letter dated 5-20-93 MDNR approval letter dated 6-7-93 MDNR approval letter dated 3-19-90 Approved in Current permit Approved in Current permit Request submitted 4-1-98 Request for approval Outfall OOA,B,C,001 000, 001 001 001 001 000, 001 000, 001 
. ! * *
* December 3, 1997 Mr.Enc Dehn Consumers Energy Palisades Nuclear Generating Station 27780 Blue Star Memorial Highway Covert, MI 49043 BetzDearborn Inc. Water Management Group Chicago District Office 900 Ridge Road, Suite J Munster, IN 46321-1722 800 688 0035 219 836 1452 Fax
 
==Reference:==
 
BetzDearborn World Class Technology (WCT) Product Conversion
 
==Dear Enc:==
As we have discussed in the past, BetzDearbom will be changing the names of the products used at Palisades Nuclear so that they coincide with our WCT product line. Fortunately, all of the products currently in use at Palisades have an identical WCT product and, therefore, only the name will change . BetzDearbom would like to make this transition painless, so we have notified the Michigan DEQ that our customers will be informing the state about these changes over the next few months. For your information, I have attached a copy of the letter that was sent to Mr. Russel J. Harding, Director MDEQ, discussing the conversion process. In addition, I have attached a sample letter that you may decide to use or alter in order to inform the state about the product name changes. The list that follows notes products that are in use at Palisades and the WCT product name that corresponds to each. I have also attached the Material Safety Data Sheets for each of the WCT products for your files and if you need to forward them to the state for any reason. 01 dName WCTName BetzD TS SPECTRUS DTl 400 ClamT rol CT-2 SPECTRUS CT1300 Powerl ine 1406 STEAMA TE PWR0240 Powerl ine 3682 SPECTRUS DT1403 Powerl ine PAL02 DEPOSITROL BL5301 Shaping the Future of Water & Process Treatment Description ClamTrol Detoxification Zebra Mussel Control Morpholine Hypochlorite Detoxification Scale Inhibitor Same Product Formulation (Name Change Only) Yes Yes Yes Yes Yes 1' I ,, * *
* CONSUMERS ENERGY World Class Technology Conversion December 3, 1997 Page Two BetzDearbom would like to thank you for your time and effort during this conversion process. If you have any questions or need additional information, please do not hesitate to call the Chicago . District office at 1-800-688-0035.
Respectfully, BetzDearborn Inc. Water Management Group . " Paul W. Olson District Representative Attachments:
Product MSDS' Sample letter to be used for MDEQ notification Letter sent to MDEQ cc: Tony Calloway -Palisades, Chemistry Lab Supervisor Eric Dehn -Palisades, Environmental Coordinator (All Attachments)
Ed Huss -Palisades, Purchasing Agent Rich Margol -Palisades, Chemistry Supervisor Joel McElrath-Palisades, Chemistry Team Leader Tracey Moore -Palisades, Chemistry Team Engineer Marcia Torrey -Palisades, Purchasing Agent Shaping the Future of Water & Process Treatment r ** BET,?DEARBORN MATERIAL SAFETY IJATA SHEET -----
-EFFECTIVE DATE: 29-JAN-1997 PRINTED DATE: 02-DEC-1997
* Bet:zDearborn PRODUCT AND COMPANY PRODUCT NAME :{ DEPOSITROL BL5301 J ( ttrz.. L) #../
PRODUCT APPLICATION AREA: WATER-BASED DEPOSIT CONTROL AGENT. COMPANY ADDRESS: BetzDearborn Inc. 4636 Somerton Road, Trevose, Pa. 19053 Information phone number: (215) -355-3300 . EMERGENCY TE.LEPHONE (HEALTH/ACCIDENT):
(800)-877-1940 (USA) 2) COMPOSITION/
INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the
* U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation:
HAZARDOUS INGREDIENTS:
CAS# 2809-21-4 CHEMICAL NAME PHOSPHONIC ACID, (1-HYDROXYETHYLIDINE)BIS-(HEDP) Corrosive (eyes) No component is considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the Occt;Jpational Safety and Health Administration at OSHA thresholds for carcinogens.
CONTINUED PRODUCT NAME : DEPOSlTROL BL5301 DA TE: 29-JAN-1997
: 3) HAZARDS IDENTIFICATION CAUTION May cause moderate irritation to the skin. May cause moderate irritation to the eyes. Mists/aerosols may cause irritation to upper respiratory tract. DOT hazard: Corrosive to steel Emergency Response Guide #153 Odor: Mild; Appearance:
Yellow, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media: . dry chemical, carbon dioxide, foam or water ********************************************************************************
* POTENTIAL HEAL TH EFFECTS ACUTE SKIN EFFECTS: Primary route of exposure; May cause moderate irritation to the skin. ACUTE EYE EFFECTS: May cause moderate irritation to the eyes . ACUTE RES Pl RA TORY EFFECTS: Mists/aerosols may cause irritation to upper respiratory tract. INGESTION EFFECTS: May cause gastrointestinal irritation with possible nausea, vomiting, abdominal discomfort and diarrhea.
TARGET ORGANS: No evidence of potential chronic effects. MEDICAL CONDITIONS AGGRAVATED:
Not known. SYMPTOMS OF EXPOSURE:
May cause redness or itching of skin, irritation, and/or tearing of eyes (direct contact).
CONTINUED PRODUCT NAME : DEPOSITROL BL5301 ,. EFFt;:CTIVE DATE: 29-JAN-1997
: 4) FIRST AID MEASURES
* SKIN CONTACT: Remove contaminated clothing.
Wash exposed area with a large quantity of soap solution or water for 15 minutes. EYE CONTACT: Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment.
INHALATION:
Remove victim from contaminated area to fresh air. Apply appropriate first aid treatment as necessary.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting.
Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water. 5) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type). EXTINGUISHING MEDIA: dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides. FLASH POINT: > 200F P-M(CC)
* MISCELLANEOUS:
Corrosive to steel UN3265;Emergency Response Guide #153 6) ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment.
Contain and absorb on absorbent material.
Place in waste disposal container.
Flush area with water. Wet area may be slippery.
Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreement.a permitted waste treatment facility or discharged under a permit. Product as is -Incinerate or land dispose in an approved landfill.
: 7) HANDLING AND STORAGE HANDLING:
Acidic. Do not mix with alkaline material.
STORAGE: Keep containers closed when not in use. Use approved containers only. Store in cool, well-vented area. Contact with metals may release flammable hydrogen gas. _GE 3 CONTINUED PRODUC1 NAiv1t:.:
KUL ol..5;jU1 DA TE: 29-JAN-1997
: 8) EXPOSURE CONTROLS/PERSONAL PROTECTION
* EXPOSURE LIMITS CHEMICAL NAME PHOSPHONIC ACID,(1-HYDROXYETHYLIDINE)BIS-(HEDP) PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED ENGINEERING CONTROLS:
adequate ventilation PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY*
PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use a respirator with dust/mist filters. SKIN PROTECTION:
rubber gloves-Wash off after each use. Replace as necessary.
EYE PROTECTION:
splash proof chemical goggles .* ) PHYSICAL AND CHEMICAL PROPERTIES
**j. Specific Grav. (70F) Freeze Point (F) Viscosity (cps 70F) Odor Appearance State Flash Point (F) 1.406 < -30.00 a.a pH As Is (approx.)
Evaporation Rate (Ether=l)
NA = not applicable ND = not determined
,'; Vapor Pressure (mmHG) Vapor Density (air=l) % Solubility (water) Mild Yellow Liquid > 2 0 0 P -M ( CC) < 1. 0 < 1. 00 CONTINUED
-18.0 < 1.00 100.0 PRODUCT NAME : DEPOSITROL BL5301 EFFECTIVE DATE: 29-JAN-1997
: 10) STABILITY AND REACTIVITY
* STABILITY:
1 Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur. INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides . . BETZ INTERNAL PUMPOUT/CLEANOUT CATEGORIES:
"8" 11) TOXICOLOGICAL INFORMATION Oral LDSO RAT: >4,000 mg/kg NOTE -Estimated value Dermal LDSO RABBIT: >4,000 mg/kg NOTE -Estimated value Eye Irritation Score RABBIT: 9.3 NOTE -Maximum score at 48 hr; completely reversible by day 14 12) ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY
* Fathead Minnow 48 Hour Static Screen Toxicity estimated from product with similar formulation at a pH of 6-9. 0% Mortality:
500 mg/L Daphnia magna 48 Hour Static Screen Toxicity estimated from product with similar formulation at a pH of 6-9. 0% Mortality:
500 mg/L . BIODEGRADATION . COD (mg/gm): 329 Calculated
* TOC (mg/gm): 89 Calculated 80D-5 (mg/gm):
* 3 Calculated 80D-28 (mg/gm): 7 Calculated CONTINUED 
--------------
--------PRODUCT NAME : DEPOSlTROL BL5301 EfFECTIVE DA TE: 29-JAN-1997
: 13) DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is : D002=Corrosive(pH, steel). Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations.
Consult state and local regulations regarding the proper disposal of this material.
: 14) TRANSPORT INFORMATION DOT HAZARD: Corrosive to steel UN / NA NUMBER: UN3265 DOT EMERGENCY-RESPONSE GUIDE#: 153 15) REGULATORY INFORMATION All components of this product are listed in the TSCA inventory.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ): No regulated constituent present at OSHA thresholds SARA SECTION 312 HAZARD CLASS: Immediate( acute) SARA SECTION 302 CHEMICALS:
* No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION
: 65) CHEMICALS PRESENT: No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION No regulated constitu_ent present at OSHA thresholds CONTINUED PRODUCT NAME : DEPOSITROL BL5301 * . EF,FECTIVE DATE: 29-JAN-1997
: 16) OTHER INFORMATION NFPA/HMIS CODE TRANSLATION
* Health *Fire Reactivity . Special 2 Moderate Hazard
* 1 Slight Hazard O Minimal Hazard CORR DOT corrosive (1) Protective Equipment B Goggles,Gloves (1) refer to section 8 of MSDS for additional protective equipment recommendations.
CHANGE LOG EFFECTIVE DATE MSDS status: 29-JAN-1997 REVISIONS TO SECTION: SUPER CEDES ** NEW ** 
----, .BF.TZDEARBORN MATERIAL SAFETY DATA SHEET . l .
* BetzDearborn DATE: 30-JAN-1997 PRINT6D DATE: 02-DEC-1997 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: STEAMATE PWR0240 PRODUCT APPLICATION AREA: NEUTRALIZING AMINE COMPANY ADDRESS: BetzDearborn Inc. 4636 Somerton Road, Trevose, Pa. 19053 Information phone number: (215) -355-3300 EMERGENCY (HEAL TH/ACCIDENT):
(800)-877-1940 (USA) 2) COMPOSITION
/ INFORMATION ON INGREDIENTS
* Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
HAZARDOUS INGREDIENTS:
CAS# CHEMICAL NAME 110-91-8 J MORPHOLINE 7 Flammable liquid; corrosive; toxic (by skin . absorption)
; potential liver and kidney toxin No component is considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the Occl:Jpational Safety and Health Administration at OSHA thresholds for carcinogens.
CONTINUED PRODUCT NAME : STEAMATE PWR0240 EFFE=CTIVE DATE: 30-JAN-1997 3) HAZARDS IDENTIFICATION DANGER Corrosive.
Absorbed by skin. Corrosive to the eyes. Irritation of the upper respiratory tract. Prolonged exposure may cause dizziness and headache.
DOT hazard: Corrosive to skin Emergency Response Guide #60 Odor: Amine; Appearance:
Colorless To Yellow, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media: dry chemical/C02/foam or water-Slippery condition; use sand/grit.
******************"!*************************************************************
POTENTIAL HEAL TH EFFECTS ACUTE SKIN EFFECTS: Primary route of exposure; Corrosive.
Absorbed by skin. ACUTE EYE EFFECTS: Corrosive to the eyes .
* ACUTE RES Pl RA TORY EFFECTS: Primary route of exposure; Irritation of the upper _respiratory tract. Prolonged exposure may cause dizziness and headache.
INGESTION EFFECTS: May cause severe irritation or burning of mouth, throat, and gastrointestinal tract with severe chest and abdominal pain, nausea, vomiting, diarrhea, lethargy and collapse.
Possible death when ingested in very large doses. TARGET ORGANS: Prolonged or repeated exposures may cause tissue necrosis and/or toxicity to the liver and kidney. MEDICAL CONDITIONS AGGRAVATED:
Not known. SYMPTOMS OF EXPOSURE:
Inhalation may cause lightheadedness, slurred speech, nausea, and/or vomiting (pulmonary edema may result). Skin contact can cause severe irritation or bums. CONTINUED PRODUCT NAMI: : STEAIVIATE i-'WRO:t!4U
* EFFECTIVE DATE: 30-JAN-1997 . 4) FIRST AID MEASURES *SKIN CONTACT: Remove clothing.
Wash area with large amounts of soap solution or water for 15 min. Immediately contact physician.
EYE CONTACT: Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment.
INHALATION:
Remove victim from contaminated area. Apply necessary first aid treatment.
Immediately contact a physici.an.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting.
Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water. 5) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type). EXTINGUISHING MEDIA: dry chemical/C02/foam or water--Slippery condition; use sand/grit.
HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides. FLASH POINT: > 200F > 93C P-M(CC) .
* MISCELLANEOUS:
Corrosive to skin NA1760;Emergency Response Guide #60 6) ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment.
Contain and absorb on absorbent material.
Place in waste disposal container.
Flush area with water. Wet area may be slippery.
Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility.in accordance with any local agreement.a permitted waste treatment facility or discharged under a permit. Product as is -Incinerate or land dispose in an approved landfill.
: 7) HANDLING AND STORAGE *HANDLING:
Alkaline.
Corrosive(Skin/eyes).
Do not mix with acidic material.
STORAGE: Keep containers closed when not in use. Store above 40f to prevent If storage is below 40f, warm and mix prior to use *' ,.to ensure homogeneity.
AGE 3 CONTINUED
.. , .*,
PRODUCl NAIVIE: Slt:AIVIA&deg;ft:
* EFFECTIVE DA TE: 30-JAN-1997 . . 8) EXPOSURE CONTROLS/PERSONAL PROTECTION
* EXPOSURE LIMITS CHEMICAL NAME MORPHOLINE PEL (OSHA): 20 PPM-SKIN(30PPM-STEL)
TLV (ACGIH): 20 PPM-SKIN(30PPM-STEL)
ENGINEERING CONTROLS:
Adequate ventilation to maintain air contaminants below exposure limits. PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use a respirator with organic vapor cartridges.
SKIN PROTECTION:
gauntlet-type rubber gloves, chemical resistant apron--Wash off after each use. Replace as necessary.
EYE PROTECTION:
splash proof chemical goggles, face shield 9s) PHYSICAL AND CHEMICAL PROPERTIES Specific Grav. (70F,21C)
Freeze Point (F) 1. 027 -6 Freeze Point (C) Viscosity(cps 70F,21C) Odor Appearance Physical State -21 Flash Point P-M(CC) pH As Is (approx.)
Evaporation Rate (Ether=l) 4 NA = not applicable ND = not determined Vapor Pressure (mmHG) Vapor Density (air=l) % Solubility (water) Amine Colorless To Yellow Liquid > 200F > 93C 12.1 < 1. 00 CONTINUED
-18.0 > 1.00 100.0 PRODUCT NAME : STEAMATE PWR0240 " EFFECTIVE DATE: 30-JAN-1997 . 10) STABILITY AND REACTIVITY
* STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur. INCOMPATIBILITIES:
May react with bases or string oxidixers.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides. BETZ INTERNAL PUMPOUT/CLEANOUT CATEGORIES: "C" 11) TOXICOLOGICAL INFORMATION Oral LD50 RAT: >2,500 mg/kg NOTE -Estimated value Dermal LD50 RABBIT: 1,250 NOTE -Estimated value Skin Irritation Score RABBIT: >2.8 NOTE -EPA category I: corrosive; DOT HM181 corrosive at 240 minutes but not 60 minutes Eye Irritation Score RABBIT: CORROSIVE NOTE -Estimated value 12) ECOLOGICAL INFORMATION
* AQUATIC TOXICOLOGY No Data Available.
BIODEGRADATION COD (mg/gm): 732 Calculated TOC (mg/gm): 208 Calculated BOD-5 (mg/gm): 0 Calculated BOD-28 (mg/gm): 363 Calculated
: 13) DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is : Not applicable.
Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations.
Consult state and local regulations regarding the proper disposal of this material.
CONTINUED PRODUCT NAMR: : SI t:..A1v1Aii:
* EFFECTIVE DATE: 30-JAN-1997
' .
* 14) TRANSPORT INFORMATION
* DOT HAZARD: Corrosive to skin UN / NA NUMBER: NA1760 DOT EMERGENCY RESPONSE GUIDE #: 60 15) REGULATORY INFORMATION TSCA: All components of this product are listed in the TSCA inventory.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ): No regulated constituent present at OSHA thresholds SARA SECTION 312 HAZARD CLASS: lmmediate(acute);Delayed(Chronic)
SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
* No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION
: 65) CHEMICALS PRESENT: No regulated constituent present at OSHA thresholds .ICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds CONTINUED 
,. PRODUCT NAME : STEAMATE PWR0240 EFFECTIVE DATE: 30-JAN-1997
: 16) OTHER INFORMATION
* NFPA/HMIS Health Fire Reactivity Special CODE TRANSLATION 3 Serious Hazard 1 Slight Hazard 0 Minimal Hazard CORR DOT corrosive (1) Protective Equipment D Goggles,Face Shield,Gloves,Apron
* (1) refer to section 8 of MSDS for additional protective equipment recommendations.
CHANGE LOG EFFECTIVE DATE MSDS status: 30-JAN-1997 REVISIONS TO SECTION: SUPERCEDES
** NEW ** 
" BF.T?:DEARBORN MATERIAL SA.FETf DATA SHEET -EFFECTIVE DATE: 18-NOV-1997 PRINTED DATE: 02-DEC-1997 ft BetzDearborn
-) CHEMICAL PRODUCT AND COMPANY IDENTIFICATIO!':!..A.
PRODUCT NAME {SPECTRUS CT1300 J L b-r..-z;.j PRODUCT APPLICATION AREA: WATER-BASED MICROBIAL CONTROL AGENT. COMPANY ADDRESS: BetzDearborn Inc. 4636 Somerton Road, Trevose, Pa. 19053 Information phone number: (215) -355-3300 EMERGENCY TE.LEPHONE (HEAL TH/ACCIDENT):
(800)-877-1940 (USA) 2) COMPOSITION
/INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
HAZARDOUS INGREDIENTS:
CAS#
* 68424-85-1 64-17-5 CHEMICAL NAME (C12-16)ALKYL DIMETHYL BENZYL AMMONIUM CHLORIDE Corrosive (eyes and skin) ETHYL ALCOHOL (ETHANOL)
Flammable liquid; irritant (eyes); potential liver and kidney toxin; may cause CNS depression No component is considered to be a carcinogen by the National Toxicology Program_, the International Agency for Research on Cancer, or the Occ1:.Jpat1onal Safety and Health Administration at OSHA thresholds for carcinogens.
CONTINUED PRODUCT NAME : SPECTRUS CT1300 Ef'.FEr..:TIVE DATE: 18-NOV-1997
: 3) HAZARDS IDENTIFICATION .
DANGER ' Severe irritant to the skin. Potential skin sensitizer.
Corrosive to the eyes. Vapors, gases, mists and/or aerosols may cause irritation to upper respiratory tract. DOT hazard: Combustible liquid Emergency Response Guide #27 Odor: Mild; Appearance:
Colorless To Yellow, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media: dry chemical, carbon dioxide, foam or water ********************************************************************************
POTENTIAL HEAL TH EFFECTS ACUTE SKIN EFFECTS: Primary route of exposure; Severe irritant to the skin. Potential skin sensitizer.
ACUTE EYE EFFECTS: Corrosive to the eyes .
* ACUTE RESPIRATORY EFFECTS: . . Vapors, gases, mists and/or aerosols may cause irritation to upper respiratory tract. INGESTION EFFECTS: Toxic; May cause severe irritation or burning of mouth, throat, and gastrointestinal tract with severe chest and abdominal pain, nausea, vomiting, diarrhea, lethargy and collapse.
Possible death when ingested in very large doses. TARGET ORGANS: Prolonged or repeated exposures may cause CNS depression, skin sensitization, and/or toxicity to the liver and kidney. MEDICAL CONDITIONS AGGRAVATED:
Not known. SYMPTOMS OF EXPOSURE:
Inhalation of vapors/mists/aerosols may cause eye, nose, throat and lung irritation.
Skin contact may cause severe irritation or burns. CONTINUED PRODUCT NAME : SPECTRUS CT1300 Ef'.FECTIVE DATE: 18-NOV-1997
: 4) FIRST AID MEASURES
* SKIN CONTACT: Remove clothing.
Wash area with large amounts of soap solution or water for 15 min. Immediately contact physician. . EYE CONTACT: Immediately flush eyes with water for 15 minutes. lmmeoiately contact a physician for additional treatment.
INHALATION:
Remove victim from contaminated area. Apply necessary first aid treatment.
Immediately contact a physician.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive victim. Dilute contents of stomach. Induce vomiting by one of the standard methods. Immediately contact a physician.
: 5) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
* Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type). EXTINGUISHING MEDIA: dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides. FLASH POINT: 130F 54C P-M(CC) MISCELLANEOUS:
Combustible liquid NA1993;Emergency Response Guide #27 6) ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment.
Contain and absorb on absorbent material.
Place in waste disposal container.
Remove ignition sources. Flush area with water. Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreement.a permitted waste treatment facility or discharged under a permit. Product as is -Dispose of in approved pesticide facility or according to label instructions.
CONTINUED PRODUCT NAME : SPECTRUS CT1300 DATE: 18-NOV-1997
: 7) HANDLING AND STORAGE
* HANDLING:
Combustible.
Do not use around sparks or flames. Bond containers during filling or discharge when performed at temperatures at or above the product flash point. STORAGE: Keep containers closed when not in use. Reasonable and safe chemical storage. Protect from freezing.
: 8) EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE LIMITS
* CHEMICAL NAME (C12-16)ALKYL DIMETHYL BENZVL AMMONIUM CHLORIDE PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED ETHYL ALCOHOL (ETHANOL)
PEL (OSHA): 1,000 PPM TLV (ACGIH): 1,000 PPM ENGINEERING CONTROLS:
Adequate ventilation to maintain air contaminants below exposure limits. PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESP IRA TOR'S USE. USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use a respirator with organic vapor cartridges and dust/mist prefilters.
SKIN PROTECTION:
neoprene gloves--Wash off after each use. Replace as necessary.
EYE PROTECTION:
splash proof chemical goggles CONTINUED PRODUCT NAME: SPECTRUS CT1300
* EF.FECTIVE DATE: 18-NOV-1997
: 9) PHYSICAL AND CHEMICAL PROPERTIES
*pecific Grav. (70F,21C) 0.965 reeze Point (F) -7 reeze Point (C) -22 Viscosity(cps 70F,21C) 73 Odor Appearance Physical State Flash Point P-M(CC) pH As Is (approx.)
Evaporation Rate (Ether=l)
NA = not applicable ND = not determined
: 10) STABILITY AND REACTIVITY STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur. INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
Vapor Pressure (mmHG) Vapor Density (air=l) % Solubility (water) Mild Colorless To Yellow Liquid 130F 54C 8.9 > 1.00 Thermal decomposition (destructive fires) yields elemental oxides .
* BETZ INTERNAL PUMPOUT/CLEANOUT CATEGORIES: "B" 11) TOXICOLOGICAL INFORMATION Oral LD50 RAT: Dermal LD50 RABBIT: 445 mg/kg >1,800 mg/kg CONTINUED 44.0 < 1.00 100.0 
-------P-RODUCT NAIVU:. :
I KUO) l.; I *1 Juu
* EFFECTIVE DATE: 18-NOV-1997
' 12) ECOLOGICAL INFORMATION
*AQUATIC TOXICOLOGY Fathead Minnow 96 Hour Flow-Thru Bioassay Test concentrations were analytically verified.
* **: ... LC50: . 72 mg/L No Effect Level: .41 mg/L Daphnia magna 48 Hour Flow-Thru Bioassay Test concentrations were analytically verified.
LC50: .04 mg/L No Effect Level: .026 mg/L Rainbow Trout 96 Hour Flow-Thru Bioassay Test concentrations were analytically verified.
LC50: 2 mg/L No Effect Level: 1.2 mg/L Mysid Shrimp 96 Hour Flow-Thru Bioassay Test concentrations were analytically verified.
LC50: .16 mg/L No Effect Level: .03 mg/L Sheepshead Minnow 96 Hour Flow-Thru Bioassay Test concentrations were analytically verified.
LC50: 1. 76 mg/L No Effect Level: 1 mg/L Menidia beryllina (Silversides) 96 Hour Flow-Thru 8ioassay Test concentrations were analytically verified.
LC50: .62 mg/L No Effect Level: .35 mg/L BIODEGRADATION COD (mg/gm): 1470 TOC (mg/gm): 380 80D-5 (mg/gm): 43 80D-28 (mg/gm): 156 CONTINUED PRODUCT NAIVlt:. :
l; 11
* EFFECTIVE DATE: 18-NOV-1997
' 13) DISPOSAL CONSIDERATIONS
* If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is : D001 =Ignitable.
Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations.
Consult state and local regulations regarding the proper disposal of this material.
: 14) TRANSPORT INFORMATION DOT HAZARD: Combustible liquid UN / NA NUMBER: NA1993 DOT EMERGENCY-RESPONSE GUIDE#: 27 15) REGULATORY INFORMATION TSCA: This is an EPA registered biocide and is exempt from TSCA inventory requirements.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ): No regulated constituent present at OSHA thresholds FIFRA REGISTRATION NUMBER: 3876-149
* POTABLE WATER APPROVAL:
NSF certified.
Maximum use for reverse osmosis 10 mg/L. FOOD AND DRUG ADMINISTRATION:
21 CFR 176.300 (slimicides for wet end use) When used in this specified application, all ingredients comprising this product are authorized by FDA for the manufacture of paper and paperboard that may contact aqueous and fatty foods as per 21 CFR 176.170(a)(4).
SARA SECTION 312 HAZARD CLASS: lmmediate(acute);Delayed(Chronic);Fire SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION
: 65) CHEMICALS PRESENT: No regulated constituent present at OSHA thresholds CONTINUED 
-PRODUCT NAME: SPECTRUS CT1300
* Ef:_FECTIVE DATE: 18-NOV-1997 MICHIGAN REGULATORY INFORMATION
* No regulated constituent present at OSHA thresholds
: 16) OTHER INFORMATION NFPA/HMIS CODE TRANSLATION Health Fire Reactivity Special 3 2 b NONE B Serious Hazard Moderate Hazard Minimal Hazard * (1) Protective Equipment No special Hazard Goggles,Gloves (1) refer to section 8 of MSDS for additional protective equipment recommendations.
* CHANGE LOG EFFECTIVE DATE MSDS status: 18-NOV-1997 REVISIONS TO SECTION: SUPER CEDES ** NEW ** 
* * * -SETZDEARBORN MATERIAL SAFETY DATA SHEET EFFECTIVE DATE:
PRINTED DATE: 05-MAR-1998 (t
: 1) CHEMICAL PRODUCT AND COMPANY 1DENTIF1CATION PRODUCT NAME f CLAM-TROL CT-4 J PRODUCT APPLICATION AREA: WATER-BASED M'CROB,AL CONTROL AGENT. COMPANY ADDRESS: BetzDearborn Inc. 4636 Somerton Road, Trevose, Pa. 19053 Information phone number: (215) -355-3300 EMERGENCY TELEPHONE (HEALTH/ACCIDENT):
(800)-877-1940 (USA) 2) COMPOSITION
/ INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
HAZARDOUS INGREDIENTS:
CAS# 68424-85-1 64-17-5 CHEMICA.L NAME (Cl2-16JALKYL DIMETHYL BENZYL AMMONr'UM CHLORIDE Corrosive (eyes and skin) ETHYL ALCOHOL (ETHANOL)
Flanunable liquid; irritant (eyes); potential liver and kidney toxin; may cause CNS depression No component is considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the Occvpationat Safety and Health Administration at OSHA thresholds for carcinogens.
PAGE 1 CONTINUED 
* **; .. t i'""KVUU .... I l._f\, .. ; vL..Mifl--l "V'-""1 """t Ef;FECTIVE DATE: 22.AUG-1995
: 3) HAZARDS IDENTIFICATION EMERGENCY OVERVIEW WARNING May cause moderate irritation to the skin. Severe irritant to the eyes. Mists/aerosols may cause irritation to upper respiratory tract DOT hazard is not applicable Emergency Response Guide is not applicable Odor. Slight; Appearance:
Colorless To Yellow, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media: dry chemical, carbon dioxide, foam or water *""******'**
.... ***........,,.*********
........ **** ... *** ...
.........
POTENTIAL HEAL TH EFFECTS ACUTE SKIN EFFECTS: Primary route of exposure; May cause moderate irritation to the skin. ACUTE EYE EFFECTS: Severe irritant to the eyes. ACUTE RESPIRATORY EFFECTS: Mists/aerosols may cause irritation to upper respiratory tract . INGESTION EFFECTS: May cause gastrointestinal irritation with possible nausea, vomiting, diarrhea, incoordination, mental confusion, dizziness and lethargy.
TARGET ORGANS: Prolonged or repeated exposures may cause CNS depression, skin sensitization, and/or toxicity to the tiver and kidney. MEDICAL CONDITIONS AGGRAVATED:
Not known. SYMPTOMS OF EXPOSURE:
Inhalation may cause irritation of the respiratory tract. Skin contact may cause itching and/or redness. PAGE 2 CONTINUED 
* *
* I" h-*wuw ..... ...,, *** ..:.. ....... ,.,,., ** I "-VL. "'I "4T EFFECTIVE DATE; 22-AUG-1995
: 4) FIRST AID MEASURES SKIN CONTACT: Remove contaminated clothing.
Wash exposed area with a large quantity of soap soiution or water for 15 minutes. EYE CONTACT: Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional trealmenl.
INHALATION:
Remove victim from contaminated area to fresh air. Apply appropriate first aid treatmant as necessary.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting.
Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water. 6) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self--contained breathing apparatus (full type). EXTINGUISHING MEDIA: . dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCiS:
Thermal decomposition (destructive fires) yields etemental oxides. FLASH
> 200F > 93C P-M(CC) 6) ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment.
Contain and absorb on absorbent material.
Place in waste disposal container.
Flush area with water. Wet area may be slippery.
Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facitity,in accordance with any local agreement.a permitted waste treatment facility or discharged under a permit. Product as is -Dispose of in approved pesticide facility or according to !abel instructions.
: 7) HANDLING AND STORAGE HANDL.ING:
Normal chemical handling.
STORAGE: Keep containers closed when not in use. Do not freez;e. if frozen, thaw and mix completely prior to usec PAGE 3 CONTINUED 
* *
* t"Kv&J1,.H.;."1 i",.j.\lwu:;
;
R.i.:.u .. ii...-1 .... Ef:'FECTIVE DATE: 22-AUG-1995
: 8) EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE LIMITS CHEMICAL NAME (C12-16)ALKYL DlMETHYL BENZYL AMMONIUM CHLORIDE PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED ETHYL ALCOHOL (ETHANOL)
PEL (OSHA): 1,000 PPM TLV (ACGIH): 1,000 PPM ENGINEERING CONTROLS:
Adequate ventilation to maintain air contaminants below exposure limits. PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUlREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDIT,ONS WARRANT A RESPIRATOR 1 S USE. USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator usa is appropriate, use a respirator with organic vapor cartridges and dust/mist prefilters.
SKIN PROTECTION:
neoprene gloves-Wash off after each use. Replace as necessary . EYE PROTECTION:
splash proof chemical goggles 9) PHYSICAL AND CHEMICAL PROPERTIES Specific Grav. (70F,21C)
Freeze i?oin-t ( F) Freeze Point (C) Viscosity{cps 70F,21Ci Odor Appearance Physical State 0.989 30 -1 10 Flash P-M(CC) pH As Is (approx.)
Evaporation Rat.e {Ether=l)
NA = not applicable ND = not determined PAGE 4 Vapor Pressure (mmHG) Vapor Density (air-1) * % Solubility (water)
* Slight Colorless To Yellow Liquid > 200F > 93C 8.1 < l. 00 CONTINUED
.... 18.0 < LOO 100.0 I I . ! 
* *
* r nviJw;,,, a &o;i"iifl.-:O u11..t"in-1 n..v ........ -, ...+ EFFECTIVE DATE: 22 .. .AUG-1995
: 10) STABILITY AND REACTIVITY STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur. INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS; Thermal decomposition (destructive fires) yields elemental oxides. BETZ INTERNAL PUMPOUT/CLEANOUT CATEGORIES: "B" 11) TOXICOLOGICAL INFORMATION Oral LOSO RAT: >2,000 mg/kg NOTE -
value based on test results on active ingredient Dermal LD50 .RABBIT: >2,000 mg/kg
-Estimated value based on test results on active ingredient PAGE 5 CONTINUED 
* *
* rn.\..;&.1'-'w a "-l-ttiVl-l l'\Y!,., \,.o I"'"" EFFECTIVE DATE: 22-AUG-1995
: 12) ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY Rainbow Trout 96 Hour Flow-Thru Bioassay Test concentrations were analytically verified.
LC50: 10 mg/L No Effect Level: 6 mg/L Fathead Minnow 96 Hour Flow-Thru Bioassay Test concentrations were analytically verified.
LC50: 4 mgll No Effect Level: 2 mg/L Oaphnia magna 48 Hour Flow-Thru Bioassay Test concentrations were analytically verified.
LC50: .2 mg/L No Effect Level: . 13 mg/L Mysid Shrimp 96 Hour Flow-Thru Bioassay Test concentrations were analytically verified.
LC50: .8 mgfl No Effect Level: .15 mg/L Sheepshead Minnow 96 Hour Flow-Thru Bioassay Test concentrations were analytically verified . LC50: 8.8 mg/L No Effect Level: 5 mg/L Menidia beryllina (Silversides) 96 Hour Flow-Thru Bioassay Test concentrations were analytically verified.
LC50: 3.1 mg/L No Effect Level: 1. 76 mg/L BIODEGRADATION COD (mg/gm): 36 Calculated TOC (mg/gm): 74 Calculated 800-5 (mg/gm): 8 Calculated BOD-28 (nigigm):
O Calculated PAGE 6 CONTINUED 
* * * --------** ,.,'\m;. * ...,..,...
__ a
* ._ *
.... *
.. -.. EFFECTIVE OATS; i2-AUG-1995
: 13) DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is : Not applicable.
Please be however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations.
Consult state and local regulations regarding the proper disposal of this material.
: 14) TRANSPORT INFORMATION DOT HAZARD: Not Applicable UN I NA NUMBER: Not applicable DOT EMERGENCY RESPONSE GUIDE #: Not applicable
: 16) REGULATORY INFORMATION TSCA: This is an EPA registered blocide and is exempt from TSCA inventory requirements. . CERCLA ANDiOR SARA REPORTABLE QUANTITY (RQ): No regulated constituent present at OSHA thresholds FIFRA REGJSTRA TION NUMBER; FOOD ANO DRUG ADMINISTRATION:
21 CFR 176.300 {sfimicides for wet end use) When used in this specified application, all ingredients comprising this product are authorized by FDA for the mam.1facture of paper and paperboard that may contact aqueous and fatty foods as per 21 CFR 176.170(a)(4).
SARA SECTION 312 HAZARD CLASS: lmmedlate(acute);Oelayed(Chronic)
SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION
: 65) CHEMICALS PRESENT: No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds PAGE 7 CONTINUED 
. , * ** **; ... *i*-..,...*wWy1r l'ilh1 .. a.:: .... ...-u .. 1-a. .. ,&#xa5;-..... ._., ... ..._. EFFECTIVE DATE:
,* 16) OTHER INFORMATION NFPAIHMIS Health Fire Reactivity Special (1)
Equipment CODE TRANSLATION 2 1 0 NONE B Moderate Haza.rd Slight Hazard Minimal Hazard No special Hazard Goggles,Gloves (1) refer to section 8 of MSDS for additional protective equipment recommendations.
CHANGE LOG EFFECTIVE.
DATE REVISIONS TO SECTION: SUPERCEDES MSDS status; 22-AUG-1995 REVISED FORlvlAT PAGE 8 BETZOEARBORN MATERIAL '1--SAPETY DATA SHEET EFFECTIVE DATE: 28-JUL-1997 PRINTED DATE: 02-DEC-1997
.. BeUDearborn
* ) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION rJ'O.t,J \1&deg;1"' PRODUCT NAME :[sPECTRUS DT1400 J cra..\-1-0 ,-sJ PRODUCT APPLICATION AREA: A DETOXIFYING AGENT COMPANY ADDRESS: Betz
 
==Dearborn Inc. 4636 Somerton Road,==
Trevose, Pa. 19053 Information phone number: (215) -355-3300 EMERGENCY (HEAL TH/ACCIDENT):
(800)-877-1940 (USA) 2) COMPOSITION
/ INFORMATION ON INGREDIENTS
* .. ,, . Information for specific product ingredients as required by the U.S .. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
HAZARDOUS INGREDIENTS:
CAS# 14464-46-1 14808-60-7 15468-32-3 CHEMICAL NAME RESPIRABLE CRISTOBALITE (CRYSTALLINE SILICA) Irritant (respiratory);
probable human carcinogen (IARC=2A; NTP=anticipated)
; may cause long term lung disease (silicosis)
RESPIRABLE QUARTZ (CRYSTALLINE SILICA) Irritant (respiratory);
probable human carcinogen (IARC=2A; NTP=anticipated)
; may cause long term lung disease (silicosis)
RESPIRABLE TRIDYMITE (CRYSTALLINE SILICA) Irritant (respiratory)
; probable human carcinogen (IARC=2A; NTP=anticipated);
may cause long term lung disease (silicosis)
CONTINUED PRODUCT NAME: SPECTRUS DT1400 EFFECTIVE DATE: 28-JUL-1997
: 3) HAZARDS IDENTIFICATION CAUTION May cause slight irritation to the skin. May cause moderate irritation to the eyes. Mists/aerosols may cause irritation to upper respiratory tract. DOT hazard is not applicable Emergency Response Guide is not applicable Odor: Slight; Appearance:
Green-Brown, Dispersion Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media: dry chemical, carbon dioxide, foam or water ********************************************************************************
* POTENTIAL HEAL TH EFFECTS ACUTE SKIN EFFECTS: Primary route of exposure; May cause slight irritation to the skin. ACUTE EYE EFFECTS: May cause moderate irritation to the eyes. ACUTE RES Pl RA TORY EFFECTS: Mists/aerosols may cause irritation to upper respiratory tract. INGESTION EFFECTS: May cause gastrointestinal irritation with possible nausea, vomiting, headache, dizziness, unconsciousness and injury to the kidneys and liver. Small amounts aspirated during ingestion/vomiting may cause lung injury, possibly death. TARGET ORGANS: Prolonged or repeated exposures may cause toxicity to the liver and/or kidney. MEDICAL CONDITIONS AGGRAVATED:
Not known. SYMPTOMS OF EXPOSURE:
May cause redness or itching of skin. CONTINUED 
----PRODUCT NAME: SPECTRUS DT1400 cFFECTIVE DATE: 28-JUL-1997
: 4) FIRST AID MEASURES
* SKIN CONTACT: Remove contaminated clothing.
Wash exposed area with a large quantity of soap solution or water for 15 minutes. EYE CONTACT: Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment.
INHALATION:
Remove victim from contaminated area to fresh air. Apply appropriate first aid treatment as necessary.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting.
Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water. 5) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type). EXTINGUISHING MEDIA: dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides. FLASH POINT: > 200F P-M(CC) .* 6) ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment.
Contain and absorb on absorbent material.
Place in waste disposal container.
Flush area with water. Wet area may be slippery.
Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreement.a permitted waste treatment facility or discharged under a permit. Product as is -Incinerate or land dispose in an approved landfill.
: 7) HANDLING AND STORAGE HANDLING:
Normal chemical handling.
STORAGE: Keep containers closed when not in use. Do not freeze. If frozen, thaw and mix completely prior to use. CONTINUED PRODUCT NAME: SPECTRUS DT1400 EFFECTIVE DATE: 28-JUL-1997
: 8) EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE LIMITS CHEMICAL NAME RESPIRABLE CRISTOBALITE (CRYSTALLINE SILICA) PEL (OSHA): 0.05 MG/M3 TLV (ACGIH): 0.05 MG/M3 RESPIRABLE QUARTZ (CRYSTALLINE SILICA) PEL (OSHA): 0.1 MG/M3 TLV (ACGIH): 0.1 MG/M3 RESPIRABLE TRIDYMITE (CRYSTALLINE SILICA) PEL (OSHA): 0.05 MG/M3 TLV (ACGIH): 0.05 MG/M3 ENGINEERING CONTROLS:
Adequate ventilation to maintain air contaminants below exposure limits. PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I RES Pl RA TORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
* USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED
* WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS . If air-purifying respirator use is appropriate, use a respirator with dust/mist filters. SKIN PROTECTION:
rubber gloves--Wash off after each use. Replace as necessary.
EYE PROTECTION:
splash proof chemical goggles 9) PHYSICAL AND CHEMICAL PROPERTIES Specific Grav. (70F) Freeze Point (F) Viscosity (cps 70F) Odor Appearance Physical State Flash Point (F) 1.186 32.00 2900 pH As Is (approx.)
Evaporation Rate (Ether=l)
NA = not applicable ND = not determined Vapor Pressure (mmHG) Vapor Density (air=l) % Solubility (water) Slight Green-Brown Dispersion
> 2 0 0 P -M ( CC) 7.0 < 1.00 .AGE 4 CONTINUED
-18.0 < 1.00 0.0 PRODUCT NAME: SPECTRUS DT1400 El=FECTIVE DATE: 28-JUL-1997
: 10) STABILITY AND REACTIVITY
* STABILITY:
'\ Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur. INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides. BETZ INTERNAL PUMPOUT/CLEANOUT CATEGORIES:
"8" 11) TOXICOLOGICAL INFORMATION Oral LDSO RAT: NOTE -Estimated value Dermal LDSO RABBIT: NOTE -Estimated value >2,000 mg/kg >2,000 mg/kg 12) ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY
* Fathead Minnow 96 Hour Static Screen 0% Mortality:
435 mg/L Daphnia magna 48 Hour Static Screen 0% Mortality:
435 mg/L BIODEGRADATION COD (mg/gm): 64 Calculated TOC (mg/gm): 26 Calculated 80D-5 (mg/gm): 0 Calculated 80D-28 (mg/gm): 2 Calculated
: 13) DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is : Not applicable . . Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations.
Consult state and local regulations regarding the proper disposal of this material.
CONTINUED PRODUCT NAME: SPECTRUS DT1400 EFFECTIVE DATE: 28-JUL-1997
: 14) TRANSPORT INFORMATION
* DOT HAZARD: Not Applicable UN / NA NUMBER: Not applicable DOT EMERGENCY RESPONSE GUIDE #: Not applicable
: 15) REGULATORY INFORMATION TSCA: All components of this product are listed in the TSCA inventory.
CERCLA A.ND/OR SARA REPORTABLE QUANTITY (RQ): Treat as oil spill SARA SECTION 312 HAZARD CLASS: Delayed(Chronic)
SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
*No regulated constituent present at OSHA thresholds CALIFORNIA REGULA TORY*INFORMATION
* CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION
: 65) CHEMICALS PRESENT: This product contains these chemicals known to the state of California to cause cancer or reproductive toxicity:
CAS# CHEMICAL NAME 14464-46-1 RESPIRABLE CRISTOBALITE (CRYSTALLINE SILICA) 14808-60-7 RESPIRABLE QUARTZ (CRYSTALLINE SILICA) 15468-32-3 RESPIRABLE TRIDYMITE (CRYSTALLINE SILICA) MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds CONTINUED 
--PRODUCT NAME : -SPE.CTRUS Dl1400 EFFECTIVE DATE: 28-JUL-1997
: 16) OTHER INFORMATION
* NFPA/HMIS CODE TRANSLATION 1 Slight Hazard 1 Slight Hazard O Minimal Hazard Health Fire Reactivity Special NONE No special Hazard * ... i a ..... (1) Protective Equipment B Goggles,Gloves (1) refer to section 8 of MSDS for additional protective equipment recommendations.
CHANGE LOG EFFECTIVE DATE MSDS status: 28-JUL-1997 REVISIONS TO SECTION: SUPER CEDES ** NEW ** 
*
* I::. P ri n ' ' ***. *-* \I v* 1::* . T;* r .,..., T ' ' ..._. '**I Y ;::* n r: i.: i r11:;: *1* .. _ 1 . * .... -* _, L I I I 1 I I *-. L;-* . .J ..... *'* .__. 11 , . 1 ...... 1 I 1 ...... , * *
* I r... J MANUFACTURER:
ALEXANDER CHEMICAL CORPORATION STREET: PO BOX 248 STATE: IL ZIP CODE: 60439 PHDNE: 312 2579330 PHONE: ST(:;TUS:
sr-:iF"E USE:
... V: CITY: LEMDNT CPCO-CL: G CEIL.INC:
STEL: CHEMICAL FAMILY: OXIDIZING AGENT CHYPOCHLORITE>
--------CHEMICAL SODIUM HYPOCHLORITE I NAOCL ---------SYNONYM NAMES JAVEL WATER BLEACH, SODABLEACH
********PHYSICAL.
!=='DINT:
'::*; ""i"]"\Jf'.'.
1::*(i"""\IT
* *******I
.... I.I-.' . ::iTEP SOLUE<L.E:
CHARACTERISTICS
***************
COMPLE:TE 110 C FOR 15% NAOCL ... J I L I NC F' 0 I !-..! T : \it1F'OF:
PF:E::SSUF.:E:
V.P. OF WATER PLUS DE:COMPOSITION PRODUCT V.P. SEE ADDITIONAL T[XT. ,: l..1 ***:: {""; ..... *. *., ;::* ,".\ f'" f'.:1i ...... ; .*.\ ('.: .*; /_\ ,:\ :**!'":I *'. :i .*i ..... : .. 1**, ;
PH:**.* . .
* OTHEP: * {'1 P P i:;: 0 ::< I j**1 (:1 TEL. '{ *j ;;2 MOLECULAR WEIGHT: .. :.1 /1 /i 1.::: t **y **. ***i *** **
L I GHT YELLOW-GREEN, PUNGENT ODOR LIKE CHLORINE . * *** INGREDIENT SECTION *************************
------INGREDIENT NAME SODIUM HYPDCHLDRITE ( SE:E f'.'.'1:0DITIDl-...!t1L.
TE\T .. :*) "./ . . 'u
* BHR-PEL: CEILING: 8HR-TL.V:
STEL: OTHEF'. F'EI...: SODIUM HYPOCHLORITE MANUF_ID:
i736 MSDS-ID * 
* * * *** FIRE EXPLOSION
*****************************
AUTOIGNITION TEMP: FLASH POINT DEGREES: FLASH POINT SCALE: FLASH POINT METHOD USED: LOWER EXPLOSION LIMIT: UPPEF: EXP!...OSIUN LIMIT: ------EXTINGUISHING MEDIA ---------------------
------FIRE FIGHTING INSTRUCTIONS SEE ADDITIONAL TEXT. ------FIRE EXPLOSION HAZARDS SEE ADDITIONAL TEXT. *** REACTIVITY
*********************************
STt1BL.E:
------UNSTABLE CONDITIONS SEE ADDITIONAL TEXT. ------MATERIALS TO AVOID ----------------------
**'--***'*-*****-*****
Ht;Z(:,i:;:nous
:o::::cDMPDSI TI ON SEE ADDITIONAL TEXT. ------HAZARDDUS POLYMERIZATION
----------------
**; : .. ------CONDITIONS TO AVOID ---------------------
...........................*.....*......
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'lX31 lVNOiliaav 33S 'JNilUNVH/3JVdOlS JNilQNVH 0NV 3JVdOlS *** ***********************
-----------------------
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S3A3 arv lSJIJ ------"HIV HS3HJ 01 NOSH3d 3AOW3d --------------------
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'lNV1IdJI
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------,. *::* *:1 J f"I I I I\ I '""' I T '*! *'*I ]" I i\I ;..i I <:* *r.,1 f'"I ,..i * <;* I ****1 *::1 **I . .1 *::1 ***1 *1* \I f""' '*I l**l '**1 ... \I i""J *1* I 1-J I ]" '"I "*I *1* *::1 '<-I '" ::1 *;**
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: 1. '** 1.. * **** I * *.* ,. .... 1.: ** -* **** * ........ **-*** 1 ..... J *** * ****. I .... ..I 1.. 'I.,. I... .. . . --**; **-. *-'** . . ..:z 1 ** _] I I .. J 1.:* --------------------------
S3A3 ------*.-
01 .LN 1;;J llddI lNVlSNOJ :slJ3JJ3 JINOJHJ "NOilnlOS Q3JDlS AlJ3dOJd WOJJ 0JVZVH 311111 AJ3A "S3NVd8W3W snoJnW 01 JNilVlIJJI Ad3A 3JV SllidS WOdJ 'SJWnJ -* **** -** --**** **-**** **** **** **-*-* **---*-* **--** **--** -* -N Cl I J_
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..
ION CONDITION; I.E., SPILLS OR ACIDIC CONDITIONS
* . .
RESPIRATORY PROTECTION
--------WHEM FUMES ARE PRESENT USE NIOSH APPROVED RESPIRATOR WITH ACID TYPE CA
* NISTEF: ...
-------EYES---------------------------
GOGGLES WHEN DISPENSING SOLUTIONS STRONGER THAN HOUSEHOLD BLEACH C7%). ------OTHER PROTECTION
--------------
SEE ADDITIONAL TEXT. ------WORK/HYGIENE
------------------
SEE ADDITIONAL TEXT. *** SPILL LEAK WASTE DISPOSAL ******************
------RELEASE OR SPILL PROCEDURES .FLUSH WITH WATER TO DILUTE AS MUCH AS POSSIBLE, AVOID HEAT AND CONTAMI NATION WITH ACID MATERIALS.
DO NOT USE COMBUSTIBLE MATERIALS SUCH AS S AWDUST TD ABSORB
------WASTE DISPOSAL METHOD ---------REDUCE WITH CHEMICALS LISTED BELOW. KEEP ON ALKALINE SIDE & DILUTE WIT H COPIOUS QUANTITIES OF WATER. MAIN END PRODUCT IS SALT WATER. CNACL>. ------DDT INFORMATION
---------------
SEE ADDITIONAL TEXT. SODIUM HYPOCHLORITE MANUF_ID:
1736 MSDS-ID * *** ADDITIONAL TEXT-INGREDIENTS
************
SODIUM HYPOCHLORITE IS MANUFACTURED ONLY IN SOLUTION FORM. "HOUSEHOLD BLEACH" CONTAINS NOT MORE THAN 7% AVAILABLE CHLORINE (=6.67 WT. %NAOCL> WITH ABOUT 0.3 TO 0.5% EXCESS NAOH FOR STABILITY CONTROL. INDUSTRIAL BLEACH CONTAINS FROM 7% -i5% AVAILABLE CHLORINE C6.67 -13.06 WEIGHT % NAOCL) WITH ABOUT 0.05 TO 0.85% EXCESS NAOH FOR STABILITY CONTROL. *** ADDITIONAL TEXT-PHYSICAL CHARACTERISTICS
************
% VOLATILE CBY VOLUME): VARIABLE -WATER VAPOR PLUS PRODUCTS OF DECOMPOSITION.
*** ADDITIONAL TEXT-FIRE AND EXPLOSION SPECIAL FIRE FIGHTING PROCEDURES:
AVOID FUMES FROM SPILLED OR EXPOSED LIQUID, DILUTE COPIOUSLY, VENTILATE, AND BE PREPARED TO USE RESPIRATORY
', r1 T **:* ,.. .. -r T ***, *\1 *1* 1::* \11::* 1::* .,..., *::* P ***: .. , *1* ;**, i-. **1 \1 .... ;.,.. *** \J ..... **** *1* **1 \i l*I 1* 1 ' 1::.1:;* -1n1 1i"'1::* * ..*. 1 r. .. , .*. 1 ... l..*I *. .. I* ....*....
c ** l..._1 .* r!L ... ,.. . ... LI< I f11 I .I. I.!-! I .. L 1. ., ..... 1... ,l.. ........ , .. .. :RY IRRITATING FUMES SIMILAR TO CHLORINE GAS. _.!USUAL FIRE AND EXPLOSION HAZARDS: . BLEACH DECOMPOSES WHEN HEATED; DECOMPOSITION PRODUCTS MAY CAUSE CONTAINERS TO RUPTURE OR EXPLODE. VIGOROUS REACTION POSSIBLE WITH ORGANIC OR OXIDIZING 
; , !** AODITIONAL TEXT-REACTIVITY
************
UNSTABLE CONDITIONS:
SOLUTIONS OF SODIUM HYPOCHLORITE ARE FAIRLY STABLE IN &#xa3;0NCENTRATIONS BELOW 1%. STABILITY DECREASES WITH CONCENTRATION, HEAT, LIGHT EXPOSURE, DECREASE IN PH, *'ND 1 1.JITH HE:f.:1VY ME:Tt1l ... s,* SUCH NICl<E:L, DBALT, COPPER, AND IRON. ATERIALS TO AVOID: AVOID CONTAMINATION WITH HEAVY METALS (ACT AS CATALYSTS), REDUCING AGENTS, ORGANICS, ETHER, AMMONIA, ACIDS. HAZARDOUS DECOMPOSITION PRODUCTS:
HYPOCHLOROUS ACID CHOCL), CHLORINE, HYDROCHLORIC ACID. COMPOSITION DEPENDS UPON TEMPERATURE AND DECREASE IN PH. ADDITIONAL DECOMPOSITION PRODUCTS, WHICH DEPEND UPON PH, TEMPERATURE AND TIME, ARE SODIUM CHLORIDE, SODIUM CHLORATE AND OXYGEN. *** ADDITIONAL TEXT-HEALTH HAZARDS ************
ACUTE EFFECTS OF IRRITATING EFFECTS INCREASE WITH STRENGTH OF SOLUTION AND TIME OF EXPOSURE.
*** ADDITIONAL TEXT-HANDLING AND STORAGE ************
PRECAUTIONARY STATEMENTS:
NORMAL HANDLING OF HOUSEHOLD BOTTLED BLEACH REQUIRES SAFETY REQUIREMENTS AS STATED ON THE LABELS. FULL PROTECTION SHOULD BE PROVIDED WHEN HANDLING BULK SHIPMENTS OF CONCENTRATED, INDUSTRIAL BLEACH SOLUTIONS.
STORAGE & HANDLING REQUIREMENTS: .JD I UM H\'POCHl...OF.:ITE Mt1HUF ID: i 7:::;<'.;
MSDS**-ID STORE IN VENTED, CLOSED, CLEAN, NON-CORROSIVE CONTAINERS IN A COOL, DRY LOCATION, AWAY FROM DIRECT SUNLIGHT AND NOT ADJACENT TO CHEMICALS WHICH MAY REACT WITH THE BLEACH IF SPILL.AGE OCCURS. IF SHIPPED, MUST COMPLY WITH DOT, ETC. SHIPPING REGULATIONS.
IF CLOSED CONTAINERS BECOME HEATED, THE CONTAINERS SHOULD BE VENTED TO REL.EASE DECOMPOSITION PRODUCTS (MAINLY OXYGEN UNDER NORMAL DECOMPOSITION).
DD NOT MIX OR CONTAMINATE WITH AMMONIA, HYDROCARBONS, ACIDS, ALCOHOLS, ETHERS. *** ADDITIONAL TEXT-CONTROL MEASURES/PPE
************
GLUVE:S':
USE RUBBER DR PLASTIC GLOVES WHEN EXPOSED TO SOLUTIONS STRONGER THAN HOUSEHOLD BLEACH C7%). OTHEF:: USE RUBBER APRON, ETC. TO PRDTE:CT BODY FROM ANY SPLASHING CONDITIONS.
USE RUBBER PROTECTIVE SHOES IF SPILLS OCCUR. HYGIENIC PRACTICES:
SAFETY SHOWERS AND EYEWASH FOUNTAINS SHOULD BE: AVAILABLE IN STORAGE AND HANDLING AREA. * .. .. -) ....... I -*. J 'I .... !"" . .... .., 1** *1* 1 I I 1*** . . . I I ... , ""I'" ... *1* .. , 1* .. -.... I
* 1(* Pi .u .l.. .I. I .. u i\ r=*1 *-I ::. /. I **-**' . . . .. *-I... ::. Pi!{ "''' P1 :::. I 1:. .l.i .. ,;, **' u .::. Pi ... -)(* -J(* o*(* *)(* *)(* *)(* -)(* *)(* *)(* -)(* 1 1: SHIPPING NAME AND HAZARD CLASS: A. "HYPOCHLORITE SOLUTION CONTAINING MURE THAN 7% AVAILABLE CHLORINE BY WEIGHT" -CORROSIVE MATERIAL. 
? **** 0DDITIDNAL TEXT-MANUFACTURER
************
i '
* j\l{:,*r:rol'--.!(11...
FE:OER1=*,1...:
EPA PESTICIDE REGULATIONS APPLICABLE AND REGISTRATION AS A PESTICIDE:
REQUIRED WHEN USED FOR DISINFECTION PURPOSES .
* I T <;: r.:* 1:;* n n I Ir:.... .,. <;* I .,. <;: **** T n \) .... , .. , ,::* .... i'I v *1* r:
J <;:-* *:* \Jr: 1::* <;: j'" ... , h' -** 1:;* ... , l r: .... ...... 1 , ............
I ..............
I .. ) ... f I ... I ... r .................
1 til ...........
I ,L ... (t... I . -SCAl INVENTORY OF CHEMICAL SUBSTANCES . . 1)Ut1TIC TOXICITY (E.G ... , ?6 HI:;:,. Tl...i"'i):
NOT ESTABLISHED, BUT IF NOT DILUTE MAY SERIOUSLY AFFECT AQUATIC LIFE. DO NOT ALLOW SPILLED MATERIAL TO ENTER SEWERS OR STREAMS. NEUTRALIZING CHEMICALS:
REDUCING AGENTS SUCH AS BISULFITES OR FERROUS SALT SOLUTIONS; SOME HEAT WILL BE PRODUCED.
SODIUM HYPOCHLORITE MANUF_ID:
1736 MSDS-ID * * 
* *
* MATERIAL SAFETY DATA SHEET PRODUCT N ACTI-BROM 1338 BIODISPERSANT NALCO Emergency Telephone Number Medlcal (708) 920-151 O (24 hours) SECTION 1 PRODUCT IDENTIFICATION TRADE NAME:
1338 BIODISPERSANT
] DESCRIPTION:
An aqueous solution of bromide salt and an oxyalkylate NFPA 704M/HMIS RATING 1/1 HEALTH 1/1 FLAMMABILITY 0/0 REACTIVITY O=Insignif icant l=Slight 2=Moderate 3=High 4=Extreme SECTION 2 HAZARDOUS INGREDIENTS 0 OTHER Our hazard evaluation has identified the following chemical ingredient(s) as hazardous under OSHA's Hazard Communication Rule, 29 CFR 1910.1200.
Consult Section 14 for the nature of the hazard(s).
INGREDIENT(S)
CAS # APPROX.\ Sodium bromide 7647-15-6 42.8 SECTION 3 PRECAUTIONARY LABEL INFORMATION CAUTION: Harmful if swallowed.
Causes moderate eye irritation.
Do not get in eyes, on skin, or on clothing.
Wash thoroughly after handling.
SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION:
INHALATION:
Flush with water for 15 minutes. Call a physician.
Wash thoroughly with soap and rinse with water. Call a physician.
Induce vomiting.
Give water. Call a physician.
Remove to fresh air. Treat symptoms.
Call a physician.
NOTE TO PHYSICIAN:
No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition.
CAUTION: If unconscious, having trouble breathing or in convulsions, do not induce or give water. SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY ROUTE(S) OF EXPOSURE:
Eye, Skin EYE CONTACT: Can cause mild to moderate irritation.
SKIN CONTACT: May cause irritation with prolonged contact. SYMPTOMS OF EXPOSURE:
A review of available data does not identify any PAGE l OF 8 NALCD CHEMICAL CDMPANV ONE NALCO CENTER
* NAPERVILLE.
ILLINOIS 80583-1 1 88 AREA 708-305-1000 
* *
* PRODUCT N ACTI-BROM 1338 BIODISPERSANT NALCO Emergency Telephone Number Medical (708) 920*151 o (24 hours1 SECTION 5 HEALTH EFFECTS INFORMATION symptoms from exposure CONTINUED ) AGGRAVATION OF EXISTING CONDITIONS:
A review of* **available data not identify any worsening of existing conditions.
SECTION 6 TOXICOLOGY INFORMATION ACUTE TOXICITY STUDIES: Acute toxicity studies have been conducted on this product along with acute toxicity studies on a similar product. The results are shown below. ACUTE ORAL TOXICITY (ALBINO RATS): Similar product LD 50 = Greater than 5,000 mg/kg COMMENTS:
During the 14-day period following the dosing of 5,000 mg/kg to the rats, the clinical observations included ataxia, lethargy, decreased limb tone, low carriage, and anogenital staining.
ACUTE DERMAL TOXICITY (ALBINO RABBITS):
Similar product LD 50 = Greater than 2,000 mg/kg PRIMARY SKIN IRRITATION TEST (ALBINO RABBITS)&deg;:
SKIN IRRITATION INDEX DRAIZE RATING: 0.0/8.0 Similar product Non-irritating
* PRIMARY EYE IRRITATION TEST (ALBINO RABBITS):
Similar product EYE IRRITATION INDEX DRAIZE RATING: 16.0/110.0 (1-hour) Moderately irritating PRIMARY EYE IRRITATION TEST (ALBINO RABBITS):
EYE IRRITATION INDEX DRAIZE RATING: 10.8/110.0 Minimally irritating COMMENTS:
No corneal opacity was noted. Iridial irritation which cleared three days after contact was noted. Slight to moderate conjunctivitis which cleared 7 days after contact was also noted. Results suggest transient irritation.
SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Colorless DENSITY: SOLUBILITY IN WATER: SPECIFIC GRAVITY: pH <NEAT) = VISCOSITY:
FREEZE POINT: FORM: Liquid 12. 2 lbs/gal. Completely 1.46 @ 60 Degrees F 7.1 cps @ 72 Degrees F 16 Degrees F PAGE 2 OF 8 ODOR: None ASTM D-1298 ASTM E-70 ASTM D-2983 ASTM D-1177 NALCO CHEMICAL COMPANY ONE NALCO CENTER
* NAPERVILLE.
ILLINOIS 60563-1198 AREA 708-305-1000 I 
* * .*' MATERIAL SAFETY DATA SHEET N ACTI-BROM 1338 BIODISPERSANT PRODUCT NALCO Emergency Telephone Number Medical (708) 920-151 O (24 hours) SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES ( CONTINUED FLASH PO INT:
* None (PMCC) ASTM D-93 NOTE: These physical properties are typical values for this product. SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: None (PMCC) ASTM D-93 EXTINGUISHING MEDIA: Not applicable SECTION 9 REACTIVITY INFORMATION INCOMPATIBILITY:
Reducing agent. Do not mix this pesticide with acids or other oxidizing chemicals.
Mixing with acids or oxidizing chemicals may cause evolution of hydrogen bromide gas, which is poisonous and corrosive.
SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION:
Respiratory protection is not normally needed since the volatility and toxicity are low. If significant vapors, mists or aerosols are generated, wear a NIOSH approved or equivalent respirator.
For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is recommended.
VENTILATION:
General ventilation is recommended.
PROTECTIVE EQUIPMENT:
Use impermeable gloves and chemical splash goggles when attaching feeding equipment, doing maintenance or handling product. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONE NUMBER (708-920-1510)
SPILL CONTROL AND RECOVERY:
Small liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent.
Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal.
Refer to CERCLA in Section 14. PAGE 3 OF 8
* NALCC CHEMICAL CCMPANY ONE NALCO CENTER
* NAPERVILLE, ILLINOIS 60563-1198 AREA 708-305-1 000 
*
* N MA TEHIAL tiAFETY DA j A ::>Ht:t: I PRODUCT ACTI-BROM 1338 BIODISPERSANT NALCO Emergency Telephone Number Medical (708) 920*151 O (24 hours) SECTION 11 SPILL AND DISPOSAL INFORMATION ( CONTINUED ) Large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal.
Refer to CERCLA in Section 14. DISPOSAL:
If this product becomes a waste, it does not meet the criteria of a hazardous waste as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, nor is it listed under Subpart D. PESTICIDE DISPOSAL:
Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility.
CONTAINER DISPOSAL:
METAL CONTAINERS:
Triple rinse (or equivalent).
Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by other procedures approved by state and local authorities.
PLASTIC CONTAINERS:
Triple rinse (or equivalent).
Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or if allowed by state and local authorities, by burning. It burned, stay out of smoke. SECTION 12 ENVIRONMENTAL INFORMATION CHEMICAL OXYGEN DEMAND (COD): 53,000 mg/L TOTAL ORGANIC CARBON (TOC): 2,000 mg/L AQUATIC DATA: PRODUCT DATA:
* 96 hour static acute LC 50 to Bluegill Sunfish =Greater than 1,000 ppm 96 hour no observed effect concentration is 1,000 ppm based on no mortality or abnormal effects. 96 hour static acute LC 50 to Rainbow Trout = Greater than 1,000 ppm 96 hour no observed effect concentration is 1,000 ppm based on no mortality or abnormal effects. SODIUM BROMIDE DATA: 96 hour static acute LC 50 to Fathead Minnow = 16,479 ppm 96 hour static acute LC 50 to Poecilia reticulata
= 225 ppm
* 48 hour static acute LC 50 to Daphnia magna = 7,900 ppm PAGE 4 OF 8 NALCO CHEMICAL COMPANY ONE NALCO CENTER
* NAPERVILLE, ILLINDIS 60563-1 198 AREA 708-305-1000 
* *
* N MATERIAL SAFETY DATA SHEET PRODUCT ACTI-BROM 1338 BIODISPERSANT NALCO Emergency Telephone Number Medical (708) 920-1 51 0 (24 hours) SECTION 12 ENVIRONMENTAL INFORMATION HYPOBROMOUS ACID DATA: (acid generated from Sodium Bromide) 96 hour static acute LC, 0 to Bluegill Sunfish= 0.52 ppm (as Br 2) ( CONTINUED ) 96 hour no observed effect concentration is 0.30 ppm based on no mortality.
96 hour static acute LC 50 to Rainbow Trout = 0.23 ppm (as Br 2) 96 hour flow-through acute LC 50 to Sheepshead Minnow= 0.19 ppm (as Br 2) 96 hour no observed effect concentration is 0.08 ppm based on no mortality.
48 hour static acute LC, 0 to Daphnia magna = 0.71 ppm (as Br 2) 48 hour no observed effect concentration is 0.41 ppm based on no mortality.
96 hour flow-through acute EC 50 to Eastern Oysters = 0.54 ppm (as Br 2) 96 hour flow-through acute LC 50 to Mysid Shrimp = 0.17 ppm (as Br 2) If released into the environment, see CERCLA in Section 14
* SECTION 13 TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME/HAZARD CODE -PRODUCT IS NOT REGULATED DURING TRANSPORTATION SECTION 14 REGULATORY INFORMATION The following regulations apply to this product. FEDERAL REGULATIONS:
OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:
Based on our hazard evaluation, the following ingredient in this product is hazardous and the reason is shown below. Sodium bromide -Eye irritant CERCLA/SUPERFUND, 40 CFR 117, 302: Notification of spills of this product is not required.
SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 <TITLE III) -SECTIONS 302, 311, 312 AND 313: SECTION 302 -EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): This product does not contain ingr*edients listed in Appendix A and B as an Extremely Hazardous Substance . PAGE 5 OF 8 NALCC CHEMICAL CCMPANV ONE NALCO CENTER
* NAPERVILLE.
ILLINOIS 60563-1 1 98 AREA 709-305-1 000 
* * * * ., * ""
* i;;;. n * "" a.. ** ;n..,.,. r c.
* 1 &.J"" 1 "" w n i;;;. '-1 PRODUCT N ACTI-BROM 1338 BIODISPERSANT NALCO Emergency Telephone Number Medical (708) 920*151 O (24 hours) SECTION 14 REGULATORY INFORMATION ( CONTINUED ) SECTIONS 311 and 312 -MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found this product to be hazardous.
The product should be reported under the following EPA hazard categories:
xx Irmnediate (acute) health hazard Delayed (chronic) health hazard Fire hazard Sudden release of pressure hazard Reactive hazard SECTION 313 -LIST OF TOXIC CHEMICALS (40 CFR 372): This product does not contain ingredients (at a level of 1\ or greater) on the List of Toxic Chemicals.
TOXIC SUBSTANCES CONTROL ACT (TSCA): The chemical ingredients in this product are on the S(b) Inventory List (40 CFR 710). FEDERAL INSECTICIDE, FUNGICIDE AND RODENTICIDE ACT (FIFRA): EPA Reg. No. 1706-168.
This product is registered for use as a microorganism control chemical used . in industrial recirculating cooling water tower systems. In all cases follow instructions on the product label. RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261 SUBPART C & D: Consult Section 11 for RCRA classification.
FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CPR 401.15/ formerly Sec. 307, 40 CFR 116/formerly Sec. 311: None of the ingredients are specifically listed * . CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product does not contain ingredients cover.ed by the Clean Air Act. STATE REGULATIONS:
CALIFORNIA PROPOSITION 65: None of the chemicals on the current Proposition 65 list are known to be present in this product. MICHIGAN CRITICAL MATERIALS:
This product does not contain ingredients listed on the Michigan Critical Materials Register . PAGE 6 OF 8 NALCO CHEMICAL COMPANY ONE NALCO CENTER
* NAPERVILLE.
ILLINOIS 60563-1 198 AREA 708-305-1 ODO 
* *
* MATERIAL SAFETY DATA SHEET PRODUCT N ACTI-BROM 1338 BIODISPERSANT NALCO Emergency Telephone Number Medical (708) 920-151 O (24 hours) SECTION 14 REGULATORY INFORMATION STATE RIGHT TO KNOW LAWS: CONTINUED ) This product is regulated under FIFRA and is exempt from State Right to Know Laws. INTERNATIONAL REGULATIONS:
This is not a WHMIS controlled product under The House of Commons of Canada Bill C-70. SECTION 15 ADDITIONAL INFORMATION None SECTION 16 USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information.
The product is to be used in applications consistent with our product literature.
Individuals handling this product should be informed of the recommended safety precautions and should have access to this information.
For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations.
Please consult your local sales representative for any further information.
SECTION 17 BIBLIOGRAPHY ANNUAL REPORT ON CARCINOGENS, U.S. Department of Health and Human Services, Public Health Service, PB 33-135855, 1983. CASARETT AND DOULL'S TOXICOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J., Klaassen, c. D., and Adinur, M. o., eds., Macmillian Publishing Company, Inc., N. Y., 2nd edition, 1980. '* CHEMICAL HAZARDS OF THE WOI{KPLACF., Proctor, N. H., and Hughes, J. P., eds., J. P. Lipincott Company, N. Y.,
DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed., Van Nostrand Reinhold Company, N.Y., 6th edition, 1984. IARC MONOGRAPHS ON THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Health Organization, International Agency !or Research on Cancer, 1972-1977 . PAGE 7 OF 8 NALCO CHEMICAL COMPANY ONE NALCO CENTER
* NAPERVILLE.
ILLINOIS 60563-1 198 AREA 709-305-1 000 
* *
* N MATERIAL SAFETY DATA SHEET PRODUCT ACTI-BROM 1338 BIODISPERSANT NA.Lee SECTION 17 BIBLIOGRAPHY Emergency Telephone Number Medical (708) 920-1510 (24 hours) CONTINUED PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G.D., Clayton, F. E., eds., John Wiley and Sons, N. Y., 3rd edition, Vol. 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS ON CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, OH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE WORKROOM ENVIRONMENT WITH INTENDED CHANGES, Conference of Governmental Industrial Hygienists, OH. PREPARED BY: Ricky A. Stackhouse PhD., Toxicologist DATE CHANGED: 10/29/90 DATE PRINTED: 05/25/91 PAGE 8 OF 8 NALCC CHEMICAL CCMPANY ONE NALCO CENTER
* NAPERVILLE.
ILLINOIS 60563-1 1 98 AREA 708-305-1000 BETZDEARBORN MA TE RIAL SAFETY DATA SHEET
* BetzDearborn EFFECTIVE DATE: 14-AUG-1997 PRINTED DATE: 02-DEC-1997
.. ) CHEMICAL PRODUCT AND COMPANY IDENTIFICATIOrt.t:;.)
PRODUCT NAME: SPECTRUS DT1403 l JM \l?J svl PRODUCT APPLICATION AREA: WATER-BASED DECHLORINATION AGENT. COMPANY ADDRESS: BetzDearborn Inc. 4636 Somerton Road, Trevose, Pa. 19053 Information phone number: (215) -355-3300 EMERGENCY (HEALTH/ACCIDENT):
(80-0)-877-1940 (USA) 2) COMPOSITION
/ INFORMATION ON INGREDIENTS
* Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of thi.s MSDS for our assessment of the potential hazards of this formulation.
* HAZARDOUS INGREDIENTS:
CAS# 7631-90-5 CHEMICAL NAME lsoDIUM BISULFITiJ May be corrosive in aqueous solutions; .irritant; sensitizer (skin and respiratory)
; may generate S02 No component is considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the . Occl:Jpational Safety and Health Administration at OSHA thresholds for carcinogens.
CONTINUED PRODl:JCT NAME: SPECTRUS DT1403 EFFECTIVE DA TE: 14-AUG-1997
: 3) HAZARDS IDENTIFICATION DANGER May cause slight irritation to the skin. Skin sensitizer.
Severe irritant to the eyes. May cause irritation to mucous membranes.
Repeated exposure may result in respiratory sensitization.
DOT hazard: ORS (when container>
RQ) Emergency Response Guide #31 Odor: Strong; Appearance:
Colorless To Light Yellow, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media: dry chemical, carbon dioxide, foam or water ********************************************************************************
POTENTIAL HEAL TH EFFECTS ACUTE SKIN EFFECTS: Primary route of exposure; May cause slight irritation to the skin. Skin sensitizer.
ACUTE EYE EFFECTS: Severe irritant to the eyes .
* ACUTE RESPIRATORY EFFECTS: . May cause irritation to mucous membranes.
Repeated exposure may result in respiratory sensitization.
INGESTION EFFECTS: May cause gastrointestinal irritation.
Very large doses may cause diarrhea, depression, colic and death. May also cause severe allergic reactions in sensitive individuals.
TARGET ORGANS: Prolonged or repeated exposures may cause primary irritant dermatitis, skin sensitization, and/or allergic respiratory reactions.*
MEDICAL CONDITIONS AGGRAVATED:
Asthma. SYMPTOMS OF EXPOSURE:
May cause local irritation or a sensitization reaction upon direct contact with skin or respiratory tract. CONTINUED PRODUCT NAME : SPECTRUS DT1403 EFFECTIVE DATE: 14-AUG-1997
: 4) FIRST AID MEASURES .
* SKIN CONTACT: Remove contaminated clothing.
Wash exposed area with a large
* quantity of soap solution or water for 15 minutes. EYE CONTACT: Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment.
INHALATION:
Remove victim from contaminated area to fresh air. Apply appropriate first aid treatment as necessary.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting.
Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water. 5) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type). EXTINGUISHING MEDIA: dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides. FLASH POINT: > 200F SETA(CC)
* MISCELLANEOUS:
ORS (when container
> RQ) NA3082;Emergency Response Guide #31 6) ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment.
Contain and absorb on absorbent material.
Place in waste disposal container.
Flush area with water. Wet area may be slippery.
Spread sand/grit.
DISPOSAL INSTRUCTIONS: . Water contaminated with this product may be sent to a sanitary sewer treatment facility, in accordance with any local agreement.a permitted waste treatment facility or discharged under a permit. Product as is -Incinerate or land dispose in an approved landfill.
: 7) HANDLING AND STORAGE HANDLING:
Vent carefully before opening. Sulfur dioxide can be formed during the normal use and handling of this product. STORAGE: Keep containers closed w_tlen not in use. Reasonable and safe
* chemical storage. Protect :rem freezing.
AGE 3 ' CONTINUED.
PRODUCT NAME : SPECTRUS DT1403 EFFECTIVE DATE: 14-AUG-1997
: 8) EXPOSURE CONTROLS/PERSONAL PROTECTION
* EXPOSURE LIMITS CHEMICAL NAME SODIUM BISULFITE PEL (OSHA): 5 MG/M3 TLV (ACGIH): 5 MG/M3 ENGINEERING CONTROLS: . Adequate ventilation to maintain air contaminants below exposure limits. PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use a respirator with acid gas cartridges and dust/mist prefilters.
SKIN PROTECTION:
gauntlet-type neoprene gloves, chemical resistant Wash off after each use. Replace as necessary.
EYE PROTECTION:
splash proof chemical goggles, face shield . PHYSICAL AND CHEMICAL PROPERTIES Specific Grav. (70F) Freeze Point (F) Viscosity (cps 70F) Odor Appearance Physical State Flash Point (F) 1.261 18.00 6 pH As Is (approx.)
Evaporation Rate (Ether=l)
NA = not applicable ND = not determined .AGE4 **i Vapor Pressure (mmHG) Vapor Density (air=l) % Solubility (water) Strong Colorless To Light Yellow Liquid > 200 SETA(CC) 4.5 < 1.00 CONTINUED 18.0 < 1.00 .100.0 PRODUCT NAME: SPECTRUS DT1403 EFFECTIVE DATE: 14-AUG-1997
: 10) STABILITY AND REACTIVITY
* STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur. INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides. BETZ INTERNAL PUMPOUT/CLEANOUT CATEGORIES:
"8" 11) TOXICOLOGICAL INFORMATION Oral LDSO RAT: >2,000 mg/kg NOTE -Estimated value Dermal LDSO RABBIT: >2,000 mg/kg NOTE -Estimated value Skin Irritation Score RABBIT: 0 NOTE -NO ERYTHEMA OR EDEMA WAS OBSERVED IN TEST OF SIMILAR PRODUCT 12) ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY
* Rainbow Trout 48 Hour Static Screen 100% Mortality:
500 mg/L 0% Mortality:
100 mg/L Daphnia magna 48 Hour Static Screen 100% Mortality:
500 mg/L 0% Mortality:
10 mg/L BIODEGRADATION COD (mg/gm): 49 Calculated TOC (mg/gm): Inorganic, N/A 80D-5 (mg/gm): Inorganic, N/A 80D-28 (mg/gm): Inorganic, N/A CONTINUED PRODUCT NAME: SPECTRUS DT1403 EFFECTIVE DATE: 14-AUG-1997
: 13) DISPOSAL CONSIDERATIONS
* If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is : Not applicable.
Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations.
Consult state and local regulations regarding the proper disposal of this material.
: 14) TRANSPORT INFORMATION DOT HAZARD: ORS (when container
> RQ) UN / NA NUMBER: NA3082 DOT EMERGENCY.RESPONSE GUIDE #: 31 15) REGULATORY INFORMATION TSCA: All components of this product are listed in the TSCA inventory.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ): 1,583 gallons due to SODIUM BISULFITE; FOOD AND DRUG ADMINISTRATION:
21 CFR 176.170 (components of paper and paperboard in contact with aqueous and fatty foods)
* SARA SECTION 312 HAZARD CLASS: lmmediate(acute);Delayed(Chronic)
SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION
: 65) CHEMICALS PRESENT: No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds CONTINWED 
' ( PRODUCT NAME : SPECTRUS DT1403 EFFECTIVE DATE: 14-AUG-1997
: 16) OTHER INFORMATION
* NFPA/HMIS Health Fire Reactivity Special (1) Protective Equipment CODE TRANSLATION 2 Moderate Hazard O Minimal Hazard 0 Minimal Hazard NONE No special Hazard D Goggles,Face Shield,Gloves,Apron (1) refer to section 8 of MSDS for additiqnal protective equipment recommendations.
* CHANGE LOG EFFECTIVE DATE REVISIONS TO SECTION: MSDS status: 21-JUL-1997 14-AUG-1997 15 SUPER CEDES ** NEW ** 21-JUL-1997 
* *
* I
* Olin OCEAN NETWORK EMERGENCY PHONE 1-800-0LIN 911 THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD COMMUNICATION CFR 1910.1200.THIS PRODUCT MAY BE CONSIDERED TO BE A HAZARDOUS CHEMICAL UNDER THAT STANDARD.(REFER TO THE OSHA CLASSIFICATION IN SEC.I.)THIS INFORMATION IS REQUIRED TO BE DISCLOSED FOR SAFETY IN THE WORKPLACE.THE EXPOSURE TO THE COMMUNITY,IF ANY,IS QUITE DIFFERENT.
I. PRODUCT IDENTIFICATION REVISION NO : 30 REVISION DATE : 1/01/97 PRODUCT CODE CPE134000 FILE NUMBER : CPE00129.0001 PRODUCT NAME: SCAV-OX(R) 35% Hydrazine Solution SYNONYMS:
Hydrazine hydrate CHEMICAL FAMILY: Hydrazine FORMULA: N 2 H, (active ingredient)
DESCRIPTION:
Corrosion inhibitor for boilers OSHA HAZARD CLASSIFICATION:
Suspect human carcinogen; irritant; toxic; skin and eye hazard; sensitizer; liver, kidney, nervous system, blood and lung toxin I I
* COMPONENT DATA PRODUCT COMPOSITION Y,: CAS or CHEMICAL CAS NUMBER: 302-01-2 OC932 PERCENTAGE RANGE: 30-407. HAZARDOUS PER 29 CFR 1910.1200:
Yes EXPOSURE STANDARDS:
TWA: CEILING: STEL: ppm 1 OSHA(PEL) mg/cubic-meter 1.3 (skin) None None CAS or CHEMICAL NAME: Water CAS NUMBER: 7732-18-5 PERCENTAGE RANGE: 60-707. HAZARDOUS PER 29 CFR 1910.1200:
No EXPOSURE STANDARDS:
None Established ACGIH(TLV) ppm mg/cubic-meter 0.01 0.013 (skin) None None 
* *
* III. PRECAUTIONS FOR SAFE HANDLING AND STORAGE DO NOT TAKE INTERNALLY.
AVOID CONTACT WITH SKIN, EYES, AND CLOTHING.
UPON CONTACT WITH SKIN OR EYES, WASH OFF WITH WATER. AVOID BREATHING VAPOR OR MIST. STORAGE CONDITIONS:
Store away from heat, sparks, open flame, and oxidants*.
Store only in well-ventilated areas. Do not contaminate.
Although 35% hydrazine has no flash point, transfer lines and piping should be electrically grounded.
To avoid gradual oxidation of hydrazine in 35% solutions, maintain an inert atmosphere over the solutions at all times. Nitrogen has been adopted as the padding material of choice. DO NOT STORE AT TEMPERATURES ABOVE: _51 Deg.C (124 Deg.F) OTHER: Do not expose to direct light. PRODUCT STABILITY AND COMPATIBILITY SHELF LIFE LIMITATIONS:
5 years if not opened and exposed to the phere. Material older than 5 years should be retested before use. INCOMPATIBLE MATERIALS FOR PACKAGING:
Package only in Teflon(R);
high density polyethylene; or 304L, or 347 stainless steel; 316SS may be used at temperatures not exceeding 150 Deg.F. INCOMPATIBLE MATERIALS FOR STORAGE.OR TRANSPORT:
Oxidizing agents; acids; metal oxides; metals other than low-molybdenum
(<0.5%) stainless steel (see comments above on 316SS), Inconel, titanium, selected aluminum alloys, and chromium; and organic materials with high surface area such as rags, cotton waste, sawdust, etc. IV. PHYSICAL DATA APPEARANCE:
Clear, colorless liquid FREEZING POINT: -65 Deg.C (-85 Deg.F) BOILING POINT: 109 Deg.C (228 Deg.F) DECOMPOSITION TEMPERATURE:
>250 Deg.C (> 482 Deg.F) after removal of water SPECIFIC GRAVITY: 1.027 BULK DENSITY: 1.027 g/cc* pH@ 25 DEG.C: 10.1-10.7 (1% solutipn)
VAPOR PRESSURE @ 30 DEG.C: 22 mm Hg (total pressure) 1.0 mm Hg (partial pressure)
SOLUBILITY IN WATER: Completely miscible VOLATILES, PERCENT BY VOLUME: 100 EVAPORATION RATE: No Data VAPOR DENSITY: No Data MOLECULAR WEIGHT: 32.04 (active ingredient)
ODOR: Ammonia COEFFICIENT OF OIL/WATER DISTRIBUTION:
No Data PAGE 2 OF 12 CPE134000 
* * ** . . . ...... -:-.
.-.
... : ... -; '!: .. 4 -.-.... ***. -r-.. -.., t*.
V. PERSONAL PROTECTIVE EQUIPMENT REQUIREMENTS PERSONAL PROTECTION FOR ROUTINE USE OF PRODUCT: RESPIRATORY PROTECTION:
Wear a NIOSH/MSHA approved respirator if any exposure occurs. VENTILATION:
Use local exhaust ventilation to maintain levels to below the TLV. SKIN PROTECTIVE EQUIPMENT:
Wear gloves. boots, apron and a face shield with safety glasses. A full impermeable suit is recommended if exposure is possible to large portion of body. OTHER: Eye wash and safety shower must be available at or near work area. EQUIPMENT SPECIFICATIONS (WHEN APPLICABLE)
RESPIRATOR TYPE: NIOSH/MSHA approved positive pressure supplied air respirator.
PROTECTIVE CLOTHING TYPE (This includes:
gloves, boots, apron, protective suit): Butyl rubber VI. FIRE AND EXPLOSION HAZARD INFORMATION FLAMMABILITY DATA: FLAMMABLE:
COMBUSTIBLE:
PYROPHORIC:
FLASH POINT: AUTOIGNITION No No No Not Applicable
-aqueous solution, wilf not burn TEMPERATURE:
Not Applicable
-aqueous solution, will not burn FLAMMABLE LIMITS AT NORMAL ATMOSPHERIC TEMPERATURE AND PRESSURE (PERCENT VOLUME IN AIR): LEL -Not flammable UEL -Not flammable NFPA RATINGS: HMIS RATINGS: Health: Flammability:
Reactivity:
Not Established 2 0 0 EXTINGUISHING MEDIA: Not Applicable-Choose extinguishing media suitable for surrounding materials
* PAGE 3 OF 12 CPE134000 OC932 
* *
* FIRE FIGHTING TECHNIQUES AND COMMENTS:
Use water to cool containers exposed to fire. See Section XI for protective equipment for fire fighting.
VII. REACTIVITY INFORMATION CONDITIONS UNDER WHICH THIS PRODUCT MAY BE UNSTABLE:
TEMPERATURES ABOVE: 270 Deg.C (518 Deg.F), after removal of water MECHANICAL SHOCK OR IMPACT: No ELECTRICAL (STATIC) DISCHARGE:
No HAZARDOUS POLYMERIZATION:
Will not occur INCOMPATIBLE MATERIALS:
Avoid contact with strong oxidizers such as hydrogen peroxide, halogen fluorides,_
fuming nitric acid and hypochlorite solution (bleach).
Avoid contact with metal oxides such as those of iron, copper, lead, manganese, and molybdenum.
Such contact may lead to decomposition.
Avoid contact with organic materials having large surface areas or porous surfaces.
Absorption of hydrazine solution by rags, cotton waste, sawdust, or similar organic materials will eventually result in spontaneous combustion.
HAZARDOUS DECOMPOSITION PRODUCTS:
Ammonia, hydrogen OTHER CONDITIONS TO AVOID: Concentration of hydrazine solution by evaporation of water
 
==SUMMARY==
OF REACTIVITY:
OXIDIZER:
PYROPHORIC:
ORGANIC PEROXIDE:
WATER REACTIVE:
OTHER: No No No No Strong reducing agent VIII. FIRST AID EYES: Immediately flush with large amounts of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Call a physician at once. SKIN: Immediately flush with water for at least 15 minutes. Call a physician.
If clothing comes in contact with the product, the clothing should be removed immediately and should be laundered before re-use. INGESTION:
Immediately drink large quantities of water. Induce vomiting.
Call a physician at once. DO NOT give anything by mouth if the person is unconscious or if having convulsions.
INHALATION:
If person experiences nausea, headache or dizziness, person should stop work immediately and move to fresh air until these symptoms disappear.
If breathing is difficult, administer oxygen, keep the person warm and at rest. Call a physician
* PAGE 4 OF 12 CPE134000
(_ 
* * * . ... Olin In the event that an individual inhales enough vapor to lose consciousness, person should be moved to fresh air at once and a physician should be called immediately.
If breathing has stopped, artificial respiration should be given immediately.
In all cases, ensure adequate ventilation and provide respiratory protection before the person returns to work. IX. TOXICOLOGY AND HEALTH INFORMATION ROUTES OF ABSORPTION Inhalation, dermal and eye contact, oral ingestion WARNING STATEMENTS AND WARNING PROPERTIES HARMFUL IF INHALED, ABSORBED THROUGH SKIN OR SWALLOWED.
CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION.
CAN CAUSE LIVER, KIDNEY, BLOOD, LUNG AND NERVOUS SYSTEM DAMAGE. MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY CAUSE CANCER BASED ON ANIMAL DATA. HUMAN THRESHOLD RESPONSE DATA ODOR THRESHOLD:
3.7 ppm (anhydrous hydrazine)
IRRITATION THRESHOLD:
This value has not been established.
IMMEDIATELY DANGEROUS TO LIFE OR HEALTH: 50 ppm (anhydrous hydrazine)
SIGNS, SYMPTOMS, AND EFFECTS OF EXPOSURE INHALATION OC932 ACUTE: Toxic by inhalation and rapidly absorbed through the lungs. If inhaled, may cause moderate to severe irritation to the nose, throat, mucous membranes, upper respiratory tract and lungs. Irritation would be expected to be transient with no permanent damage expected.
Damage may also result to liver, kidneys and blood. High exposure may give rise to hemolysis of the blood cells. Vomiting, diarrhea, nausea, dizziness, cyanosis and convulsions may also occur. CHRONIC: The repeated inhalation of hydrazine may produce inflammation of the nasal, tracheal and bronchial tissue. Chronic bronchitis can result. Damage to the liver, kidneys, and blood'may also occur. Damage to blood may be characterized by hemolysis and reduction of packed cell volume. Repeated inhalation of hydrazine has produced cancer in laboratory animals
* PAGE 5 OF 12 CPE134000 
* *
* SKIN ACUTE: Hydrazine is rapidly absorbed through the skin and is highly toxic by this route which is dependent on exposed skin surface area and concentration of the solution.
Exposure to large areas of the skin may lead to a significant dose being absorbed causing systemic toxicity similar to the effects described for inhalation exposure.
Hydrazine can produce moderate to severe irritation.
Dermatitis may also occur. CHRONIC: EYE Repeated exposure can cause an allergic reaction resulting in dermatitis and a characteristic rash. Other effects would be similar to those described under chronic inhalation exposure.
Exposure can cause moderate to severe irritation consisting of inflammation, swelling, redness and discharge.
Temporary blindness can occur. INGESTION ACUTE: Toxic by ingestion.
Ingestion may cause moderate to severe irritation of the GI tract and may also cause gastrointestinal discomfort with any or all of the following symptoms:
nausea, vomiting, lethargy and diarrhea.
The other effects would be similar as stated under inhalation exposure.
CHRONIC: Inflammation to the gastrointestinal tract can occur. Other effects would be similar as stated under inhalation exposure.
Chronic ingestion of hydrazine has caused cancer in laboratory animals. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
Diseases of the liver, kidneys and blood, as well as asthma, cardiovascular disease, and nervous system disorders.
INTERACTIONS WITH OTHER CHEMICALS WHICH ENHANCE TOXICITY:
None known or reported ANIMAL TOXICOLOGY ACUTE TOXICITY:
Inhalation LC 50: Approximately 1600 ppm (4 hr. exposure, rat) Dermal LD 50: 420 mg/kg (rabbit) Oral LD 50: 185 mg/kg (rat) Irritation:
Irritant to skin and eyes ACUTE TARGET ORGAN TOXICITY:
Damage to lungs, liver, kidneys, blood and central nervous system
* PAGE 6 OF 12 CPE134000 ( \__ 
* **
* Olin CHRONIC TARGET ORGAN TOXICITY:
Repeated exposure to hydrazine has produced damage to the lungs, liver, kidneys, blood and nervous system. Cancer has also been observed in laboratory animals. REPRODUCTIVE AND DEVELOPMENTAL TOXICITY:
High concentrations of hydrazine have produced embryolethality and fetal malformations to the offspring of animals exposed during pregnancy.
These findings were only observed at concentrations that cause significant maternal toxicity.
Under industrial use conditions where exposures are kept at or below the recommended occupational exposure standards, exposure to this product should not pose a reproductive or developmental toxicity hazard. CARCINOGENICITY:
Hydrazine is recognized as a cancer-causing agent in animals by !ARC and OSHA. It is considered a suspect carcinogen in humans by these two organizations
* MUTAGENICITY:
Hydrazine has been shown to cause DNA and chromosomal damage in a number of test systems. It considered mutagenic.
AQUATIC TOXICITY:
The 96-hour LCS.O for rainbow trout (Salmo gairdneri) exposed to this product is 4.3mg/l. The 96-hour LCSO for bluegill (Lepomis macrochirus) exposed to this product is 4.2mg/l. . The 48-hour LCSO for the Water flea (Daphnia magna) exposed to this product is 0.46mg/1.
X. TRANSPORTATION INFORMATION THIS MATERIAL IS REGULATED AS A DOT HAZARDOUS MATERIAL.
DOT DESCRIPTION FROM THE HAZARDOUS MATERIALS TABLE 49 CFR 172.101: LAND (U.S. DOT) : *HYDRAZINE AQUEOUS SOLUTION, 6. 1, UN 3293, PG III (WITH NOT MORE THAN 374 HYDRAZINE BY MASS) WATER (IMO): SAME AS ABOVE AIR (IATA/ICAO):
SAME AS ABOVE HAZARD LABEL/PLACARD:
TOXIC REPORTABLE QUANTITY:
1 lb (Per 49 CFR 172.101, Appendix)
EMERGENCY GUIDE NO: 152 PAGE 7 OF 12 oc 932 CPE134000 
* *
* XI. SPILL AND LEAKAGE PROCEDURES FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC AT 800-424-9300
* REPORTABLE QUANTITY:
This product is subject to a Reportable Quantity with respect to hydrazine.
RQs are subject to change and reference should be made to 40 CFR 302.4 for the current requirements SPILL MITIGATION PROCEDURES:
Evacuation procedures must be placed into effect. Rope off spill area and evacuate all non-essential personnel.
Hazardous concentrations in air may be found in local spill area and immediately downwind.
Utilize emergency response personal protective equipment prior to the start of any response.
Remove all sources of ignition.
Stop source of spill as soon as possible and notify appropriate personnel.
* AIR RELEASE: Vapors may be suppressed by the use of water fog. Contain all liquid for treatment and/or disposal as a (potential) hazardous waste. WATER RELEASE: This material is heavier than and soluble in water. Notify all downstream water users of possible contamination.
Divert water flow around spill if possible and safe to do so. LAND SPILL: Create a dike or trench to contain materials.-Dilute spilled hydrazine to about 10% with water. Neutralize the diluted hydrazine by slowly adding a 5-8% calcium hypochlorite solution until all the hydrazine has been reacted. Steam and nitrogen gas will be evolved. DO NOT ADD DRY CALCIUM HYPOCHLORITE TO A HYDRAZINE SPILL, A VIOLENT REACTION MAY RESULT. The neutralized material may be absorbed-using clay, sand or commercial absorbent.
Do not place spill.materials back in their original containers.
Containerize and label all spill materials properly.
Decontaminate all clothing and the spill area using strong detergent and flush with large amounts of water. NOTE: Hydrazine can not be removed from leather. All contaminated leather articles should be rinsed with water and discarded.
SPILL RESIDUES:
Dispose of per guidelines under Section XII, WASTE DISPOSAL.
This material may be neutralized for disposal; you are requested to contact OCEAN at SOO-OLIN-911 before beginning any such operation.
PERSONAL PROTECTION FOR EMERGENCY SPILL AND FIRE-FIGHTING SITUATIONS:
In case of fire, use normal fire fighting equipment.
PAGE 8 OF 12 CPE134000
,* ( 
* *
* Olin Additional respiratory protection is necessary when a spill or fire involving this product occurs. You are recommended to use a self-contained breathing apparatus (SCBA) positive pressure unit. Additional protective clothing must be worn to prevent personal contact with this material.
Those items include but are not limited to boots, gloves, hard hat, splash-proof goggles, full face shield and impervious clothing, i.e., chemically impermeable suit, or a full encapsulated suit. Compatible material for response to this material is butyl rubber. XII. WASTE DISPOSAL *If this product becomes a waste, it meets the criteria of a hazardous waste as defined under 40 CFR 261 and would have the following EPA hazardous waste number: Ul33. If this product becomes a waste, it. will* be a hazardous waste which is subject to the Land Disposal Restrictions under 40 CFR 268 and must be managed accordingly.
As a hazardous liquid waste, it must. be disposed of in accordance with local, state and federal regulations in a permitted hazardous waste treatment, storage and disposal facility by incineration.
CARE MUST BE TAKEN TO PREVENT ENVIRONMENTAL CONTAMINATION FROM THE USE OF THIS MATERIAL.
THE USER OF THIS.MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF UNUSED MATERIAL, RESIDUES AND CONTAINERS IN COMPLIANCE WITH ALL RELEVANT LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS REGARDING TREATMENT, STORAGE AND DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS WASTES. XIII. ADDITIONAL REGULATORY STATUS INFORMATION TOXIC SUBSTANCES CONTROL.ACT:
The components of this product are listed on the Toxic Substance Control Act inven:t_ory. . CALIFORNIA SAFE DRINKING WATER AND TOXIC ENfORCEMENT ACT OF 1986 -PROPOSITION 65: OC932 "WARNING:
This product contains detectable amounts of a chemical known to the State of California to cause cancer and birth defects or <'ther reproductive harm." PAGE 9 OF 12 CPE134000 
* *
* SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT TITLE III: HAZARD CATEGORIES, PER 40 CFR 370.2: HEALTH: Immediate (Acute) Delayed (Chronic)
PHYSICAL:
None EMERGENCY PLANNING AND COMMUNITY RIGHT TO KNOW, PER 40 CFR 355, APP.A: EXTREMELY HAZARDOUS SUBSTANCE
-THRESHOLD PLANNING QUANTITY:
1000 lbs. as hydrazine SUPPLIER NOTIFICATION REQUIREMENTS, PER 40 CFR 372.45: This mixture or tradename product contains a toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR 372. CHEMICALS LISTED ARE: Hydrazine XIV. ADDITIONAL INFORMATION MSDS REVISION STATUS: Emergency guide number revised in Section X. (10) 1. 2. 3. 4. 5. 6. 7. 8. 9. XV. MAJOR REFERENCES Roe, F.J.C. 1977. Clinical and Epidemiological Studies on Men Exposed to Hydrazine in the Course of its Manufacture or Use. Wimbledon, London, England
* Haun, C. C., and E. R. Kinkead. January 1975. Chronic tion Toxicity of Hydrazine.
University of California,-Irvine, Toxic Hazards Research Unit, Dayton, Ohio. Mac Ewen, J. D., et al. June 1981. Chronic Inhalation Toxicity of Hydrazine:
Oncogenic Effects. Air Force Aerospace Medical Research Laboratory, Wright-Patterson Air Force Base, Ohio. Sotaniemi, E., et al. 1971. Hydrazine Toxicity in the Human. Report of a Fatal Case. Annals of Clinical Research 3:30-33. Vernet, E. H., et al. 1985. Long-Term Inhalation Toxicity of Hydrazine.
Fundamental and Applied Toxicology, 5, 1050-1064.
Lee, S. H. and H. Aleyassine.
November 1970. Hydrazine Toxicity in Pregnant Rats. Arch. Environ. Health. Vol. 21. Wald, N., et al. 1984. Occupational exposure to hydrazine and subsequent risk of cancer. British Journal of Industrial cine. 41: 31-34. Lyng, R. D., et al. March 1980. Effects of Hydrazine on Pregnant ICR Mice. Air Force Aerospace Medical Research Laboratory, Wright-Patterson Air Force Base, Ohio 45433. Keller, W. C., et al. August 1982. Evaluation of the icity of Hydrazine in Rats. Air Force Aerospace Medical Research Laboratory, Wright-Patterson Air Force Base, Ohio 45433
* PAGE 10 OF 12 CPE134000 I . 
* *
* OC932 I' Jin " . 10. Toth, B. 1988. Toxicities of Hydrazines:
A Review. In Vivo. 11. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 2:209-242.
United Nations Environment Programme, International Labour sation, and World Health Organization.
1987. Environmental Health Criteria 68. World Health Organization.
Report on Acute Dermal Toxicity in Rabbits, 357. Hydrazine tion, H.B. Research Laboratories,.
Inc., Spinnerstown, PA, Project #HB76-1139, Hay 14, 1976. Report on Acute Toxicity of SCAV-OX to Rainbow Trout (Salmo gairdneri), EG&G Bionomics Aquatic Toxicity Laboratory, Wareham, MA, Report #BW-80-9-738, September 1980. Report on Acute Toxicity of SCAV-OX to Bluegill (Lepomis chirus), EG&G Bionomics Aquatic Toxicity Laboratory, Wareham, MA, Report #BW-80-9-740, September 1980. Report on Acute Toxicity of SCAV-OX (357. Hydrazine solution) to the Water Flea (Daphnia magna), EG&G Bionomics Aquatic Toxicity Laboratory, Wareham, MA, Report #BW-80-9-739, September 1980. Report on Primary Dermal Irritation in Rabbits, 357. Hydrazine solution, H.B. Research Laboratories, Inc., Spinnerstown, PA, Project #HB76-1139, April 16, 1976
* Report on Rabbit Eye Irritation, 357. Hydrazine solution, M.B. Research Laboratories, Inc., Spinnerstown, PA, Project #HB76-1139, April 16, 1976. DOT Rabbit Test for Material Corrosivity, SCAV-OX, 357. Hydrazine solution, H.B. Research Laboratories, Inc., Spinnerstown, PA, Project #HB-78-2536, March 3, 1978. Report on Oral LOSO in Rats, 357. Hydrazine solution, H.B. Research Laboratories, Inc., Spinnerstown, PA, Project #HB76-1139, Apr{l 16, 1976. J. G. Burtle, Vapor Pressure-Composition Measurements on Aqueous Hydrazine Solutions, Ind. Eng. Chem., vol. 44, 1952. H. W. Schiess!, "Hydrazine and It's Derivatives," in Kirk-Othmer Encyclopedia of Chemical Technology, 3rd ed., Hark et al eds., John Wiley and Sons, New York, NY, 1980. Olin Product Data, Code 731009R2, "Hydrazine, Storage of Aqueous Solutions,"*
Olin Corporation, Stamford, CT., c1982. E. W. Schmidt, Hydrazine and It's Derivatives, John Wiley and Sons, New York, NY, 1984
* PAGE 11 OF 12 CPE134000 A 
* * ... THE INFORMATION IN THIS MATERIAL SAFETY DATA SHEET SHOULD BE PROVIDED TO ALL WHO WILL USE, HANDLE, STORE, TRANSPORT, OR OTHERWISE BE EXPOSED TO THIS PRODUCT. THIS INFORMATION HAS BEEN PREPARED FOR THE GUIDANCE OF PLANT ENGINEERING, OPERATIONS AND MANAGEMENT AND FOR PERSONS WORKING WITH OR HANDLING THIS PRODUCT. OLIN BELIEVES THIS INFORMATION TO BE RELIABLE AND UP TO DATE AS OF THE DATE OF PUBLICATION, BUT MAKES NO WARRANTY THAT IT IS. ADDITIONALLY, IF THIS MATERIAL SAFETY DATA SHEET IS MORE THAN THREE YEARS OLD, YOU SHOULD CONTACT OLIN AT THE PHONE NUMBER LISTED BELOW TO MAKE CERTAIN THAT THIS SHEET IS CURRENT. OLIN MSDS CONTROL GROUP Olin Corporation 501 Merritt } P.O. Box 4500 Norwalk, CT 06856-4500 Phone Number: (800) 511-MSDS OLIN CORPORATION SUBSIDIARIES AND AFFILIATED ENTITIES:
ASAHI-OLIN LTD., BRIDGEPORT BRASS CORPORATION, OLIN AEROSPACE COMPANY, A.u. OSTER COMPANY, OLIN FABRICATED METAL PRODUCTS.INC., OLIN HUNT SPECIALTY PRODUCTS.INC., OLIN SPECIALTY METALS CORPORATION, GENERAL DEFENSE CORPORATION, NIACHLOR, PHYSICS INTERNATIONAL COMPANY, SUPERIOR POOL PRODUCTS, INC., ETOXYL, C.A., OCG MICROELECTRONIC MATERIALS, INC., OLIN ENGINEERED SYSTEMS, INC., YAMAHA-OLIN METAL CORPORATION, NORDESCLOR, S.A . PAGE 12 OF 12 CPE134000 
* * * .. ' Olin. OCEAN NETWORK EMERGENCY PHONE 1-800-0LIN-911 z22 -JO THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD COMMUNICATION STANDARD,29 CFR 1910.1200.THIS PRODUCT MAY BE CONSIDERED TO BE A HAZARDOUS CHEMICAL UNDER THAT STANDARD. (REFER TO THE OSHA CLASSIFICATION IN SEC.I.)THIS INFORMATION IS REQUIRED TO BE DISCLOSED FOR SAFETY IN THE WORKPLACE.THE EXPOSURE TO THE COMHUNITY,IF ANY,IS QUITE DIFFERENT.
I. PRODUCT IDENTIFICATION REVISION NO 14 REVISION DATE 10/20/95 PRODUCT CODE CPE109110 FILE NUMBER CPE00031.0006 PRODUCT NAME: CAUSTIC SODA SOLUTION SYNONYMS:jSodium hydroxip;J Caustic, Alkali, Caustic lye CHEMICAL FAMILY: Alkali, Base FORMULA: NaOH (active ingredient)
DESCRIPTION:
Neutralizing agent, sodium source OSHA CLASSIFICATION:
Corrosive, eye and skin hazard, lung toxin II. COMPONENT DATA PRODUCT COMPOSITION CAS or CHEMICAL NAME: Sodium hydroxide CAS NUMBER: 1310-73-2 PERCENTAGE RANGE: 45-50% HAZARDOUS PER 29 CFR 1910.1200:
Yes EXPOSURE STANDARDS:
ppm TWA: CEILING: STEL: OSHA(PEL) mg/cubic-meter 2 None None CAS or CHEMICAL NAME: Water CAS NUMBER: 7732-18-5 PERCENTAGE RANGE: 45-55% HAZARDOUS PER 29 CFR 1910.1200:
No EXPOSURE STANDARDS:
None Established ACGIH(TLV) ppm mg/cubic-meter None 2 None 
* * * . ; ... III. PRECAUTIONS FOR SAFE HANDLING AND STORAGE DO NOT TAKE INTERNALLY.
AVOID CONTACT WITH SKIN, EYES AND CLOTHING.
UPON CONTACT WITH SKIN OR EYES, WASH OFF WITH WATER. STORAGE CONDITIONS:
DO NOT STORE AT TEMPERATURES ABOVE: 130 Deg.C (266 Deg.F) PRODUCT STABILITY AND COMPATIBILITY SHELF LIFE LIMITATIONS:
Indefinite if in closed container.
INCOMPATIBLE MATERIALS FOR PACKAGING:
Aluminum, zinc, tin, wood, paper INCOMPATIBLE MATERIALS FOR STORAGE OR TRANSPORT:
Acids, nitrogen containing organics, phosphorous, explosives, organic peroxides, tin, halogenated hydrocarbons IV. PHYSICAL DATA APPEARANCE:
Clear, viscous liquid FREEZING POINT: 10-12 Deg.C (50-54 Deg.F) BOILING POINT: 130-140 Deg.C (266-284 Deg.F) DECOMPOSITION TEMPERATURE:
None SPECIFIC GRAVITY: 1.482-1.53 BULK DENSITY: Not Applicable pH @ 25 DEG.C: 13 (0.54 Solution)
VAPOR PRESSURE @ 25 DEG.C: Approximately equal to
-*-* SOLUBILITY IN WATER: Miscible VOLATILES, PERCENT BY VOLUME: 45-55 EVAPORATION RATE: No Data VAPOR DENSITY: No Data MOLECULAR WEIGHT: 40.01 (Active agent) ODOR: None COEFFICIENT OF OIL/WATER DISTRIBUTION:
No Data
* V. PERSONAL PROTECTIVE EQUIPMENT REQUIREMENTS PERSONAL PROTECTION FOR ROUTINE USE OF PRODUCT: RESPIRATORY PROTECTION:
Respiratory protection not normally needed. If vapors, mists, or aerosols are generated, wear a NIOSH/ MSHA approved dust/mist respirator.
VENTILATION:
Use Local exhaust ventilation to maintain levels to below the TLV. SKIN PROTECTIVE EQUIPMENT:
Wear gloves, boots, face shield with chemical goggles, apron or impermeable suit to avoid skin and eye contact
* PAGE 2 OF 10 CPE109110 
* *
* Olin. MATERIAL SAFETY DATA OTHER: Safety showers and eyewashes must be available in the immediate area when handling product. EQUIPMENT SPECIFICATIONS:
RESPIRATOR TYPE: NIOSH/HSHA HEPA filter respirator GLOVE TYPE: Neoprene BOOT TYPE: Neoprene APRON TYPE: Neoprene PROTECTIVE SUIT: Neoprene VI. FIRE AND EXPLOSION HAZARD INFORMATION FLAHHABILITY DATA: FLAMMABLE:
No
* COMBUSTIBLE:
No PYROPHORIC:
No FLASH POINT: Not Applicable AUTOIGNITION TEMPERATURE:
Not Applicable FLAMMABLE LIMITS AT NORMAL ATMOSPHERIC TEMPERATURE AND PRESSURE (PERCENT VOLUME IN .UR): Not Applicable NFPA RATINGS: Health: Flammabi 1 i ty: Reactivity:
HMIS RATINGS: Health: Flammability:
Reactivity:
3 0 1 3 0 1 EXTINGUISHING MEDIA: Not Applicable FIRE FIGHTING TECHNIQUES AND COMMENTS:
Use water to cool containers exposed to fire. Contact with reactive metals, e.g., aluminum may result in the generation of flammable hydrogen gas. See Section XI for protective equipment for fire fighting.
Sodium Hydroxide may react with water. (See Section VII). On small fires, use dry chemical, carbon dioxide, water spray, or foam. On large fires, use water flooding quantities as a fog
* PAGE 3 OF 10 CPE109110 l'(. 932 
* *
* VII. REACTIVITY INFORMATION CONDITIONS UNDER WHICH THIS PRODUCT MAY BE UNSTABLE:
TEMPERATURES ABOVE: None MECHANICAL SHOCK OR IMPACT: No ELECTRICAL (STATIC) DISCHARGE:
No OTHER: Contact with carbohydrates, aluminum, zinc, tin. HAZARDOUS POLYMERIZATION:
Will not occur INCOMPATIBLE MATERIALS:
Acids, nitrogen containing organics, explosives, carbohydrates, phosphorous, organic peroxides, halogenated hydrocarbons HAZARDOUS DECOMPOSITION PRODUCTS:
None OTHER CONDITIONS TO AVOID: Dilution with water except under controlled conditions.
Very high heat of dilution will cause boiling and spattering.
 
==SUMMARY==
OF REACTIVITY:
OXIDIZER:
No PYROPHORIC:
No ORGANIC PEROXIDE:
No WATER REACTIVE:
No CORROSIVE:
Yes VIII. FIRST AID EYES: Immediately flush with large amounts of water for at least 15 minutes, occasionally lifting the.upper and lower eyelids. Call a physician at once
* SKIN: Immediately flush with water for at least 15 minutes. Call a physician.
If clothing comes in.contact with the product, the clothing should be removed immediately and should be laundered before re-use. INGESTION:
Immediately drink large quantities of water. DO NOT induce vomiting.
Call a physician at once. DO NOT give anything by mouth if the person is unconscious or if having convulsions.
INHALATION:
If person experiences nausea, headache or dizziness, person should stop work immediately and move to fresh air until these symptoms disappear.
If breathing is difficult, administer oxygen, keep the person warm and at rest. Call a physician.
In the event that an individual inhales enough vapor to lose consciousness, person should be moved to fresh air at once and a physician should be called immediately.
If breathing has stopped, artificial respiration should be given immediately.
In all cases, ensure adequate ventilation and provide respiratory protection before the person returns to work
* PAGE 4 OF 10 CPE109110 
* *
* Olin ..
SAFETY DATA IX. TOXICOLOGY AND HEALTH INFORMATION ROUTES OF ABSORPTION Inhalation, skin and eye contact, ingestion WARNING STATEMENTS AND WARNING PROPERTIES HARMFUL IF SWALLOWED.
CAUSES SKIN, EYE, DIGESTIVE TRACT AND RESPIRATORY TRACT BURNS. HUMAN THRESHOLD RESPONSE DATA ODOR THRESHOLD:
There is no data for odor threshold.
IRRITATION THRESHOLD:
There is no data for irritation threshold.
IMMEDIATELY DANGEROUS TO LIFE OR HEALTH: The IDLH level for sodium hydroxide is 10 mg/cubic-meter.
SIGNS, SYMPTOMS, AND EFFECTS OF EXPOSURE INHALATION ACUTE: Inhalation of ti1is material is irritating to the nose, mouth, throat and lungs. It may also cause burns to the respiratory tract which can result in shortness of breath, wheezing, choking, chest pain, and impairment of lung function.
Inhalation of high concentrations can result in permanent lung damage. CHRONIC: Chronic (repeated) inhalation exposure may cause impairment of lung function and permanent lung damage. SKIN ACUTE: Dermal exposure can cause severe irritation and/or burns characterized by redness, swelling and scab formation.
Prolonged skin exposure may cause permanent damage. CHRONIC: Effects from chronic skin exposure would be similar to those from single exposure except for effects secondary to tissue destruction.
EYE OC 932 Severe irritation and/or burns can occur following eye exposure.
Direct contact may cause of vision and corneal damage
* PAGE 5 OF 10 CPE109110 
* *
* INGESTION ACUTE: Irritation and/or burns can occur to the entire gastrointestinal tract, including the stomach and intestines, characterized by nausea, vomiting, diarrhea, abdominal pain, bleeding and/or tissue ulceration.
Ingestion causes severe damage to the gastrointestinal tract with the potential to cause perforation.
CHRONIC: There are no known or reported effects from chronic exposure.
Chronic ingestion of significant amounts of this product is unlikely because of its acute corrosive action. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Asthma, respiratory and cardiovascular disease INTERACTIONS WITH OTHER CHEMICALS WHICH ENHANCE TOXICITY There are no chemicals known to enhance the toxicity of the product .. ANIMAL TOXICOLOGY ACUTE TOXICITY:
Inhalation LC 50: No Data Oral LD 50: Believed to be 300 -500 mg/kg. (rat); harmful if swallowed Dermal LD 50: Believed to be > 2 g/kg. (rabbit) Irritation:
Causes burns to eyes and skin. ACUTE TARGET ORGAN TOXICITY:
This product is corrosive to all tissues contacted and upon inhalation, may cause irritation to mucous membranes and respiratory tract. CHRONIC TARGET ORGAN TOXICITY:
There are no known or reported effects from repeated exposure except those secondary to burns. REPRODUCTIVE AND DEVELOPMENTAL TOXICITY There are no known or reported effects on reproductive function or fetal development from exposure to this product. CARCINOGENICITY:
This product is not known or reported to be carcinogenic by any reference source including
!ARC, OSHA, NTP, or EPA. Ingestion of massive doses of sodium hydroxide has led to the development of tumors of the esophagus.
The relevance of these findings to cancer is unknown due to repeated tissue destruction and scar formation as a result of the corrosive nature of sodium hydroxide
* PAGE 6 OF 10 CPE109110 
* *
* Olin MUTAGENICITY:
Sodium has been tested and was found to be non-mutagenic in the Ames assay, a bacterial DNA-repair test and in the Syrian hamster embryo (SA7/SHE) cell transformation assay. AQUATIC TOXICITY Caustic soda is not lethal to fully developed fish in natural fresh waters until the pH becomes greater than 9.0: Lethal pH for Goldfish:
10.9 Lethal pH for Bluegill sunfish: 10.5 Gambusia affinis fish), 96 hr. LC50: 125 mg/l Bluegill, 48 hr. LC50: 99 mg/l X. TRANSPORTATION INFORMATION THIS MATERIAL IS REGULATED AS A DOT HAZARDOUS MATERIAL
* DOT DESCRIPTION FROM THE HAZARDOUS MATERIALS TABLE 49 CFR 172.101: LAND (U.S. DOT): SODIUM HYDROXIDE SOLUTION, 8, uN1824, PG II WATER (IMO) : SAME AS AB.OVE AIR (IATA/ICAO):
SAME AS ABOVE HAZARD LABEL/PLACARD:
CORROSIVE REPORTABLE QUANTITY:
1000 lbs. (Per 49 CFR 172.101, Appendix)
EMERGENCY GUIDE NO: 60 XI. SPILL AND LEAKAGE PROCEDURES FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC AT 800-424-9300.
REPORTABLE QUANTITY:
1000 lbs. (Per 40 CFR 302.4) SPILL MITIGATION PROCEDURES:
Hazardous concentrations in air may be found in local spill area in the form of a mist which may cause skin irritation and breathing problems.
Stop source of spill as soon as possible, if safe to do so
* PAGE 7 OF 10 CPE109110 oc 932 
* *
* AIR RELEASE: Will normally be found in a mist form and evacuation from the mist area is the only advisable approach.
Correction of the source of mist is of the utmost importance.
WATER RELEASE: This material is heavier than and is soluble in water. This material is subject to emulsification and must be removed via a vacuum system or neutralized and absorbed as necessary, with various commercial absorbents which are available.
Notify all downstream industrial, municipal and public operation of this spill and advise them to monitor until otherwise notified.
LAND SPILL: Dike or divert flow of material to a diked area as soon as possible.
If necessary create an excavat.ion large enough to contain the spill and associated neutralization materials.
To reduce environmental damage, line the excavated surface with a material to which it is compatible and begin neutralization process or remove by vacuum, or pumping. This spill materials may be absorbed in: Saw dust, sand, clay soil, vermiculite or commercial absorbents.
SPILL RESIDUES:
Dispose of per guidelines under Section XII, WASTE DISPOSAL.
This material may be neutralized for disposal; you are requested to contact OCEAN at 800-0LIN-911 before beginning any such operation
* PERSONAL PROTECTION FOR EMERGENCY SPILL AND FIRE-FIGHTING SITUATIONS:
In case of fire use normal fire fighting equipment (including self contained breathing apparatus:
SCBA). A hazardous physical characteristic of this product is: corrosive XI I. WASTE DISPOSAL If this product becomes a waste, it meets the criteria of a hazardous waste as defined under 40 CFR 261 and would have the following EPA hazardous waste number: D002. If this product becomes a waste, it will be a hazardous waste which is subject to the Land Disposal Restrictions under 40 CFR 268 and must be managed accordingly.
As a hazardous liquid waste, it must be disposed of in accordance with local, state and federal regulations in a permitt.ed hazardous waste treatment, storage and disposal facility by treatment
* PAGE 8 OF 10 CPE109110 
* *
* Olin. MATERIAL SAFETY DATA CARE HUST BE TAKEN TO PREVENT ENVIRONMENTAL CONTAMINATION FROM THE USE OF THIS MATERIAL.
THE USER OF THIS MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF UNUSED MATERIAL, RESIDUES AND CONTAINERS IN COMPLIANCE WITH ALL RELEVANT LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS REGARDING TREATMENT, STORAGE AND DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS WASTES. XIII. ADDITIONAL REGULATORY STATUS INFORMATION TOXIC SUBSTANCES CONTROL ACT: This substance is listed on the Toxic Substances Control Act inventory.
NSF LIMITS: NSF Maximum Drinking Water Use Concentration
-100 mg/l SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT TITLE III:. HAZARD CATEGORIES, PER 40 CFR 370.2: HEALTH: Immediate (Acute) PHYSICAL:
None EMERGENCY PLANNING AND COMMUNITY RIGHT TO KNOW, PER 40 CFR 355, APP.A: EXTREMELY HAZARDOUS SUBSTANCE
-THRESHOLD PLANNING QUANTITY:
None Established SUPPLIER NOTIFICATION REQUIREMENTS, PER 40 CFR 372.45: None Established XJ. V. AilDI T IOi'fAL J. uN MSDS REVISION STATUS: Revision to Sections:
II, III, V, VII, IX, XI and XV oc 932 XV. MAJOR REFERENCES
: 1. DeFlora, Silvio, et al., Genotoxic Activity and Potency of 135 Compounds in the Ames Reversion Test and in a Bacterial DNA-Repair Test. Mutation Research, Vol. 133, pp. 161-198, 1984. 2. ACGIH Documentation of the Threshold Limit Values and Biological Exposure Indices, Sixth Edition, 1991. American Conference of Governmental Industrial Hygienists, Inc., Cincinnati, OH. 3. Federal Register, Vol. 53, No. 237, Friday, December 8, 1988, 49688-49690.
40 CFR Part 372, Sodium Hydroxide:
Toxic Chemical Release Reporting, Community Right-to-Know . PAGE 9 OF 10 CPE109110 
* *
* 4. AQUIRE Database (aquatic toxicity), Chemical Information Systems, Inc. (a division of PSI International, Inc.), Towson, HD. 5. TOXNET Database, U.S. National Library of Medicine, Bethesda, HD
* 6. Forsberg, K., and S.Z. Mansdorf, Quick Selection Guide to Chemical Protective Clothing, Second Edition, Van Nostrand Reinhold, N.Y., 1993. 7. 3M 1995 Respirator Selection Guide. 3M Occupational Health and Environmental Safety Division, St. Paul, MN., 1995. Other References are available upon request. THE INFORMATION IN THIS MATERIAL SAFETY DATA SHEET SHOULD BE PROVIDED TO ALL WHO WILL USE, HANDLE, STORE, TRANSPORT, OR OTHERWISE BE EXPOSED TO THIS PRODUCT. THIS INFORMATION HAS BEEN PREPARED FOR THE GUIDANCE OF PLANT ENGINEERING, OPERATIONS AND MANAGEMENT AND FOR' PERSONS WORKING WITH OR HANDLING THIS PRODUCT. OLIN BELIEVES THIS INFORMATION TO BE RELIABLE AND UP TO DATE AS OF THE DATE OF PUBLICATION, BUT MAKES NO WARRANTY THAT IT IS. ADDITIONALLY, IF THIS MATERIAL SAFETY DATA SHEET IS HORE THAN THREE YEARS OLD, YOU SHOULD CONTACT OLIN AT THE PHONE NUMBER LISTED BELOW TO MAKE CERTAIN THAT THIS SHEET IS CURRENT. OLIN MSDS CONTROL GROUP Olin Corporation 120 Long R1dge Road Stamford, CT 06904 Phone Number: (203) 356-3449 OLIN CORPORATION SUBSIDIARIES AND AFFILIATED ENTITIES:
ASAHI-OLIN*
LTD .* BRIDGEPORT BRASS CORPORATION, OLIN AEROSPACE COMPANY, A.u. OSTER COMPANY, OLIN FABRICATED METAL PRODUCTS.INC., OLIN HUNT SPECIALTY PRODUCTS;INC., OLIN SPECIALTY METALS CORPORATION, GENERAL DEFENSE CORPORATION, NIACHLOR, PHYSICS INTERNATIONAL COMPANY, SUPERIOR POOL PRODUCTS, INC., ETOXYL, C.A., OCG MICROELECTRONIC INC., OLIN ENGINEERED SYSTEMS, INC., YAMAHA-OLIN METAL CORPORATION, NORDESCLOR, S.A. PAGE 10 OF 10 CPE109110 
** t:.lf *: . ** 
..... .. *. . * * :; . r;-:=nt:" MSDS FOR:CALGON CORPORATION MANUF-ID:
000053 LCS-60 MSDS-ID: 11 
 
.. ' ,J;;***; F:I RST /A ID. *******************************3.E
"!,\'tt ti
------FIRST AID EYES
'ci'fINYCASE:10F::coNTACT">:IMMEDIATEL y ;'FLUSH';
ITW*Pl l ;wo .
.. . * **
"**** iF' rniiucE
* voMniNG ir\/' GIVING* iwb' GLAssEs
* oF WAT ING FINGER DOWN THROAT. CALL A PHYSICIAN.
NEVER GIVE ANYTHING TO AN UNCONSCIOUS PERSON. ------FIRST AID SKIN --------------------------
*::*,:*IN
''CASE*; OF:'i'CONTACT;::':c FLUSH:: WITH PLENTY;*:,ofr;:,WATER:.),F,ORTAT'.L:EASJ:;us*
f P . . . . . ..... . ; .*
HANDLING!:
.* .* .:..:.;..:..:'.::::::.:...
STORAGE/HANDLING.,';..;.;:;;;;.:.:;.:::::.:.::::.:.:.:..::.::;;;.::::.::::
.,,.,,,., .. ,, ...........
'*' "''"", . SEE ADDITIONAL TEXT ------OTHER PRECAUTIONS
-------------
MSDS FQR:CALGON CORPORATION MANUF-ID:
000053 LCS-60 MSDS-ID: 11
* CHRONIC STUDIES HAVE SHOWN THE MATERIAL TO BE CARCINOGENIC TO LABORATORY ANIMALS. TESTING WITH EUKARYOTIC AND PROKARYOT IC SYSTEMS HAVE SHOWN THE MATERIAL TO BE MUTAGENIC AND CAUSE REPRODUCTIVE(''EFFECTS
*IN iLABORATORY:ANIMAl.:S
:'?PREGNANT/:WOMEN'.'.7?;
INEMA *1:PROl ONGED::i EXPOSURE>
MAY.; RESULTi IN 1 METHEMOGLOBI NEMIA/'AN D , EFFECTS:Yto\i<[H fi;f.CA RDIO\/ASCU IJARli SY,51'.EM Ef,L . TI c .* SYSTEM :,, .. ''*'** ....... ,,,;i1x. ... **** ;n., ..... , .. ;r, *. ,,,,"" ,,,,,,.,,,,*,
""'' '"* ** .... . *** ADDITIONAL TEXT-HANDLING AND STORAGE ************
STORAGE 0'1'ANJ)7HANDLI NG.ff*;HARMFUL7*
I FT SWAL L BI.: Ei'CANCER s MAYCCREAT SK;n);QV.ERE);<
li FACE SHIELD WHEN HANDLING.
USE WITH ADEQUATE VENTILATION.
WASH THOROUGHLY AFTER HANDLING.
KEEP CONTAINER CLOSED WHEN NOT IN USE. **
* 06-16-95 01:22ff HAY I LAliI.* a*
*-/37-ll, * > ... *--* .. . ,.
* MATERIAL SAFETY DATA SHEET ALUMINUM SlJl.IA"IE LIQUID **
* SECTION I -IDENTIFICATION MANUFACTURER'S NAME ............
Haviland Products Company .ADDRESS (STREET.CITY.STATE.ZIP>
421 Ann St., N.W., Grand Rapids. MI 49504 PHONE NUMBER. . . . . . . . . . . . . ( 616) 361-6691 EMERGENCY PHONE NUMBER .........
CHEMTREC t600) 424-9300 EFFECTIVE DATF. .................
09/29il993 TRADE NAME ...................
,, ALUMINUM SULfATE LIQUID CHEMICAL FAMILY ........*.......
Miscellaneous Blend SECTION II -HAZARDOUS INGREDIENTS HAZARDOUS COMPONENTS Aluminum Sulfate OSHA1 PEL Not Established ACGIH!ILV (Units) 2mg (as AR)/m 3 SECTION I 11 -PHYSICAL DATA PROD. CAS # 10043-01-3
=============:=======
==-*===============================================
BOILING POINT ............... . FREEZING POINT .............. . VAPOR PRESSURE <mm Hg) ....... . VAPOR DENSITY tAir=l) ........ . SOLUBILITY IN H20 .*...... APPEARANCE/ODOR
...... *.*....* SPECIFIC GRAVITY (H20=1). '?H **** * ***..*.***********
213.8&deg;F (101&deg;C) 3.2&deg;F (-16&deg;C) No Information Available No Information Completely Clear. Light Green or Amber 1. 3 3 5 Not Established Liquid; Odorless SECTION IV -FIRE AND EXPLOSION HAZARD DATA FLASH POINT .................*......
Will Not Burn LOWER LIMIT <%by Volume> Not Appltcable UPPER EXPLOSIVE LIMIT <%by Volume) Not Applicable EXTINGUISH MEDIA ...................
As for Surrounding Fires SPECIAL FIRE FIGHTING PROCEDURES
... Wear breathing apparatus by NIOSH. water spray to keep coQl. UNUSUAL FIRE HAZARD ................
Toxic and corrosive gases are evolved when heated dryness at temperatures above I ( 760DC)
* SECTION V -HEALTH HAZARD DATA CARCINOGENICITr
..... None NTP. . . . . . . . . .
.. . . . . . . . . . . . . . . . .
* 0 6-16-9 5 IJ l : 2 P!*:i !'UUj/ UU4 . *. * * * ... ' MATERIAL SAFETY DATA SHEET ALUMINUM SUU,Alb LIQUID IARC. . . . . . . . . . . . . . . . . . . . . . . . . .
No OVER EXPOSURE EFFECTS ......**.
Irritation of exposed tissues may cause burns. PRIMARY ROUTE<S> OF ENTRY ..... Skin Contact FIRST AID PROCEDURES
.....*..*.
In case of contact: Immediately flush eyes and skin with plenty of water for at least 15 minutes. For eyes, get medical attention.
If .inhaled:
Remove to fresh air if effects occur and consult a physician.
If swallowed:
If conscious, immediately give a large quantity of water or milk. If not already vomiting, induce vomiting by touching finger to back of throat. Contact physician.
EXPOSURE MEDICAL CONDITIONS None Currently Known =====aamc==========m===============:==============================**=m=====
SECTION VI -REACTIVITY DATA CHEMICAL STABILITY
*.........*.
Stable CONDITIONS TO AVOID .........*.
Temperatures above 1400oF (760&deg;C) INCOMPATIBLE MATBRIALS
......*. Alkalies and water reactive materials such as oleum. DECOMPOSITION PRODUCTS.,, *.**. Sulfur Oxide Gases HAZARDOUS POLYMERIZATION
*...*. Will Not Occur POLYMERIZATION AVOID ....**....
Not Applicable SECTION VII -SPILL OR LEAK PROCEDURE FOR SPILL .......**.........*.
Contain spill. Neutralize with soda ash, *lime or limestone.
Flush spill area with water and drain to waste system. WASTE DISPOSAL M:::THOD ....*.***
Neutralize with alkali. Solid may be disposed of by an approved contractor.
FLush neutral liquid to sewer. Comply with all federal. state and local regulations.
SECTION VIII -SPECIAL PROTECTION RESPIRATORY
......*. Where required use a NIOSH approved mist respirator.
VENTILATION
...................
To maintain mists below levels. PROTECTIVE GLOVES .......*...*.
Rubber or other impervious materials
* EYE PROTECTION
....*.......***.
Splash proof chemical goggles. OTHER PROTECTIVE EQUIPMENT
.... Where spills or splashing may occur, use an impervious body covering and boots. A safety shower and eye bath should be available.
,.,
06-!6-95 01:23PL
,. . . * * **; -'; ' " MATERIAL SAFETY J>ATA SHEET ALUMlNUM SULFATE LIQUID HANDLING AND STOHAGE ..........
Store in cool, dry place. Keep containers closed when not in use. Emptied containers retain product residue.
SECTION IX -SPECIAL PRECAUTIONS HAZARD CLAS s . . . . . . . . . . . . . . . . .
CORROSIVE I 8 I PG I I I DOT SHIPPING KAME .............
CORROSIVE LlQUID. N.O.S. (CONTAINING ALUMINUM SULFATE) UN NUMBER .....................
UN1760 REPORTABLE (RQ), ..... Not Listed REFERENCES LIQUALUM 
'l _ .. * *
* MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE NUMBER HAZARD
 
==SUMMARY==
(29 CFR 1910.1200)
Physical Hazards: Oxidizer, Water-reactive Health Hazards: Corrosive
: 1. PRODUCT IDENTIFICATION (800) 263-95tE Product Name: Sulfuric Acid: Grades; Commercial (93.19/98/9S&deg;Ai), Electroiytic C.nemlcal Name: Sulfuric Acid Synonyms:
Oil of Vitriol, Sulphuric Acid Chemical Famlly: Inorganic acid Molecular Formula: H2so, WHMIS Classlflcatlon:
Class E -Corrosive, Class 01 A -Very Toxic Product Use: Used in manufacture of fertilizers, explosives, other acids, metal pickling and petroleum precessing.
SHIPPING DESCRIPTION U.S. (Under 0.0.T.) CANADA (Under i.C.) Shipping Name: RO Sulfuric Acid Hazard Class: Corrosive Material Product Identification No: UN1830 Shipping Name: Sulfuric Acid Shipping Cius/Division:
Class 8 (9.2)
* Produe* ! .. .,.ntltfcation No (PIN): UN1830 Packlr.,.
'Jup: II HAZARDOUS INGREDIENTS OF MATERIAL Hazardous Ingredients
* Sulfuric Acid 2. PHYSICAL PROPERTIES Physical State: Liquid 60-100 ACQIH TLV OSHA PEL CAS No. i mg/m 3 1 mgim 3 7664-93-9 Appearance And Odor: Commercial sulfuric acid is a clear to amber, heavy, oily liquid whicn may have a sharp penetrating S02 odor. Electrolytic grade Is clear and ooorless.
Odor Threshold:
No data Bolllng Point: 93.19%: 276&deg;C (529&deg;F); 9So/o: 330&deg;C [626"F) Meltlng1Freezlng Point: 93.19%: -29.5"C [-21.1&deg;F);
96%: -1.1&deg;C (30&deg;F) Vapor Pressure at 40&deg;C (102&deg;F): 93.19%: 0.0016 mmHg; 98%: 0.002 mmHg Specific Gravity at 15&deg;C (60&deg;F): 93.19%: 1.8354; 98%: 1.8437 Vapor Density: No data, not volatile at normal temperatures.
Bulk Density: Not applicable jsee specific gravity).
Evaporation Rate: Not applicable
* Solublllty:
Miscible in all proportions In water. Also soluble in alcohol. % Volatlle by Volume: 0% at room temperature'.
pH: 0.3 (1 N so*1.1tion at 25&deg;C/78&deg;F)
JNI t:>&#xa3;:tl 2:6. 0t
_, * *
* Sulfuric Acid 3. FIRE AND EXPLOSION DATA Fl11ah Point (method):
Not' applicable, product is non-flammable Autoignition Temperature:
Not combustible Flammablllty Limits In air (%): UEL: Not applicable LEL: Not applicable Fire Extinguishing Media: Use appropriate media to extinguish source of fire. Use water carefully (see below).
* Fire Fighting Procedures:
Fire invotvfng small amount of combustibles may be smothered with suitable dry chemical.
Use water on combustibles burning in vicinity of this material but use care; water applied directly will cause evolution of heat and cause spattering.
Full protective equipment including a self-contained breathing apparatus shoold be worn. Other Fire or Explosion Hazards: Not flammable but highly reactive; capable of igniting finely divided combustible materials on contact. Reacts violently with water and organic materials with evolution of heat. Extremely hazardous in contact with many materials, particularly carbides, chlorates, fulminates, nitrates, picrates, powdered metals, releasing hydrogen.
Hydrogen gas can accumulate to explosive concentrations Inside confined spaces. Sensitivity lo Chemical Impact: No data Rate of Burning: No data Explosive Power: No data Sensitivity to Static Discharge:
No data 4. REACTIVITY DATA Stablllty:
Under Normal Conditions:
Stable Under Fire COndltlons:
Decomposes to SO. Hazardous Polymerization:
Will not occur Conditions lo Avoid: Temperatures which may have a negative effect on the materials of construction used in equipment.
Materials to Avoid: Contact with organic materials (such as chlorates, carbides, fulminates and picrates) may cause fire and explosions.
Contact with metals may produce flammable hydrogen gas. Hazardous Decomposition or Combustion Products:
Toxic gases and vapors (e.g., sulfur dioxide, sulfuric acid vapors and sulfur trioxide) may be released when sulfuric acid decomposes.
: 5. TOXICOLOGICAL AND HEALTH DATA Recommended Exposure Limit: ACGIH TLV-TWA (1987-88):
1 mg!m 3 OSHA PEL {1989): 1 mg/m 3 Toxlcologlcal Data: LDso (oral, rat)= 2140 mg/kg LCso (Inhalation, rat) = 510 mgim 3 for 2 hrs Carcinogenicity Data: Although there are reports linking exposure to sulfuric acid to cancer, this product is not classified by NTP (National Toxicology Program), not regulated as carcinogenic by OSHA (Occupational Safety and Health Administration), and has not been evaluated by IARC (International Agency for Research on Cancer) or ACGIH [American Conference of Governmental Industrial Hygienists).
800'3SJ!jd JNI 
.;., 1 I * * *"i : { Sulfuric Acid Reproductive Effects: No Information is available and no adverse reproductive effects are anticipated.*
Mutaganlclty Data: No information Is available and no adverse mutagenic effects are anticipated
* Teretoganlclty Data: No Information is available and no adverse teratogenic effects are anticipated.
Synergistic Matartals:
None known Effects of exposure when: Inhaled: Mists and vapors may cause irritation of the eyes, nose and respiratory tract May cause increased pulmonary resistance, transient cough and bronchoconstriction.
Severe overexposure may result in lung collapse and pulmonary edema which can be fatal. Prolonged or repeated exposure may result in impaired lung function and possible discoloration and erosion of teeth. In contact with the skin: Concentrated solution may cause pain and severe burns to the skin and brownish or yellow stains. Prolonged and repeated exposure to dilute solutions may cause irritation.
redness, pain and drying and cracking of the skin. In contact with the eyes: Immediate pain, severe burns and permanent corneal damage which may result Jn blindness.
* Ingested:
Severe burning and pain in the mouth, throat and abdomen. Vomiting, diarrhea and perforation of the esophagus and stomach lining may occur. Other Health Effects: Corrosive effects on the skin and eyes may be delayed, and damage may occur without the sensation or onset of pain. Strict adherence to first aid measures following any exposure is essential.
Flrat Aid Procedures when: Inhaled: Move victim to fresh air. Give artificial respiration ONLY if breathing has stopped. Give Cardiopulmonary Resuscitation (CPR) If there is no breathing AND no pulse. Obtain medical attention IMMEDIATELY.
In contact with the skin: Flush skin with running water for a minimum of 20 minutes. Start flushing while removing contaminated clothing.
If irritation persists; repeat flushing.
Obtain medical attention IMMEDIATELY.
Do not transport victim unless the recommended flushing period is completed or flushing can be continued during transport.
In contact with the eyes: Immediately flush eyes with running water for a minimum of 20 minutes. Hold eyelids open during flushing.
If irritation persists, repeat flushing.
Obtain medical attention IMMEDIATELY.
Do not transport victim until the recommended flushing period is completed unless flushing can be continued during transport.
Ingested:
If victim Is alert and not convulsing, rinse out mouth and give Y2 to 1 glass of water to dilute material.
H spontaneous vomiting occurs, have victim lean forward with head down to avoid breathing in of vomitus, rinse mouth and administer more water. IMMEDIATELY contact local poison control center. Vomiting may need to be induced but should be directed by a physician or a poison control center. IMMEDIATELY transport victim to an emergency facility.
Note to PhY81clan:
Medical conditions that may be aggravated by exposure include asthma, bronchitis, emphysema and other Jung diseases and chronic nose, sinus or throat conditions.
In the event of skin or eye contact, rapid and thorough flushing is essenttal.
: e. PREVENTIVE MEASURES Recommendations listed in this section indicate the type of equipment which will provide protection against over exposure to this product. Conditions of use, adequacy engineering or other control measures, and actual exposures will dictate the need for specific protective devices at your workplace.
t>00"39tjd )NI X3lnSdtjW ss:tt 2s. 01 IV .. c")-1 . ( . \.\i. ' I * *
* Sulfurtc Acid EngJneertng Controls:
Local exhaust ventilation required.
Respiratory Protection:
A NIOSH1MSHA approved air-purifying respirator equipped with acid gas/fume, dust, mist cartridges for concentrations up to 10 mg/m3. An air-supplied respirator if concentrations are higher or unknown. Skin Protection:
Impervious (I.e., neoprene, PVC) gloves, coveralls, boots and/or other acid resistant protective clothing.
Eye Protection:
Tight-fitting chemical goggles and face shield. Other Personal Protective Equipment:
Where there is a danger at spilling or splashing, acid resistant aorons or suits should be worn. Trouser legs should be worn outside (not tucked in) rubber boots. Safety showers and eyewash fountains should be Installed In storage and handling areas. Handling Procedures and Equipment:
Carbon steel or stainless steel materials are suitable for use for acid concentrations equal to or greater than 93o/o. However, the effect of lower concentrations on the materials .of construction can be very complex, Contact product supplier for specific recommendaUons when handling sulfuric acid at strengths less than n%. Storage Temperature:
Store above freezing point (Section 2). Elevated temperatures will increase the corrosion rate of most metals. Storage Requirements:
Store packaged acid in a dry, well-ventilated location away from combustibles, oxidizers, bases, or metallic powders. Storage tanks should be protected from water ingress, be well ventilated, and maintained structurally in a safe and rellable condition.
* Other Precautions:
Keep away from Ignition sources. Sulfuric acid will attack some forms of plastics and coatings.
Always add acid to water -not water to acid. If kept in upper floors of building, floors snould be acid proof with drains to a recovery tank. 7. ENVIRONMENTAL PROTECTION DATA Steps to be taken In the event of a splll or leak: Remove all ignition sources. Ventilate area. Stop or reduce leak if safe to do so. Dike with Inert material (sand, earth, etc.). Collect into containers for reclaim or disposal.
Environmental Effects: Harmful to aquatic life in very low concentrations.
May be dangerous If it enters water Intake; Fish toxicity critical concentration=
10 mgiL; 7.34 mg1L148 hrs'-Lymneae.Palustrls  100% mortality.
Deactivating Chemicals:
Lime, limestone, sodium carbonate (soda ash), sodium bicarbonate, dilute sodium hydroxide, dilute aqua ammonia Waste Olsposaf Methods: Dispose of waste material at an approved waste treatmentidisposal facility,.
in accordance with applicable regulations.
Do not dispose of waste witti normal garbage or to sewer systems. 8. ADDmONAL INFORMATION AND SOURCES USED 1. MARSULEX Technical Bulletin, "Sulfuric Acid" 2. Enviro-TIPS Manual, "Sulfuric Acid and Oleum", Environment Canada, February, 1984. The information contained herein has been prepared by MARSULEX Inc, and is offered only as a guide to the handling of this specific material and has been prepared in good faith by technically able personnel.
H is not intended to be all-inclusive and the manner and conditions of use and handllng may involve other and additional considerations.
No warranty of any kind is given or implied and MARSULEX Inc. will not be liable for any damages, losses, injuries or consequential damages which may result from the use or reliance of any Information contained herein. MAASULEX INC. 11 t Gordon Baker Road North York, ONT M2H 3R1 1416) 496-9655 &#xa3;00"39tl2 MARSULEX INC. 40 Richards Avenue P.O. Box 5453 Norwalk, CT 06856-5453 1203) 854-0300
* Date Issued: November 1985 Date revised: February 1990 JNI 
**i .. , . '---
... 20 MULE TEAM -11..ou-0 Material Safety Data Sheet DA TE OF ISSUE June 1996 Supersedes May 1993 Version Boric Acid Manufacture Grade 1 Chemical product and company identification Product name: Grade: Product use: Chemical formula: \ Boric Acid J Manufacture Grade (MG) Pesticide formulation H 3 B0 3 Chemical name/synonyms:
Boric acid, orthoboric acid, boracic acid, Boric Acid MG, Boric Acid Insecticide Chemical family: Inorganic borates CAS registry number: 10043-35-3 ( 11113-50-1)
EPA pesticide Reg. No.: 1624-117 (Refer to Section 15 for TSCA/DSL Chemical inventory listing) 2 Composition/information on ingredients This product contains greater than 99 percent(%)
boric acid (H 3 B0 3), which is hazardous under the OSHA Hazard Communication Standard and under the Canadian Controlled 3 Hazard identification Emergency overview Boric Acid is a white, odorless, granular/powdered substance that is not flammable, combustible, or explosive and has low acute oral and dermal toxicity.
Potential ecological effects Large amounts of Boric Acid can be harmful to plants and other species. Therefore, releases to the environment should be minimized.
Potential health effects Routes of exposure:
Inhalation is the most significant route of exposure m occupational and other settings.
Dermal exposure is noi usually a concern because Boric Acid is poorly absorbed through intact skin. Inhalation:
Occasional mild irritation effects to nose and throat may occur from inhalation of Boric Acid dust at levels greater than 10 mglm 3. Eye contact: Boric Acid is non-irritating to eyes in normal industrial use. Skin contact: Boric Acid does not cause irritation to intact skin. MANUFACTURER:
_ U.S-Borax Inc.*
* 26877 Tourney Road Valencia, CA 91355-1847 EMERGE.NCY PHONE NUMBERS 24 Hr. Medical Info. Service: Chemtrec (Spills):
(800) 228-5635 Ext. 144 (800) 424-9300 Products Regulations of the Hazardous Products Act (WHMIS), based on animal chronic toxicity studies. Refer to Sections 3 and 11 for details on hazards. Ingestion:
Products containing Boric Acid are not intended for ingestion.
Boric Acid has a low acute toxicity.
Small amounts (e.g., a teaspoonful) swallowed accidentally are not likely to cause effects; swallowing amounts larger than that may cause gastrointestinal symptoms.
Cancer: Boric Acid is not a known carcinogen.
Reproductive/developmental:
Animal ingestion studies in several species. at high doses, indicate that borates cause reproductive and developmental
*effects.
A human study of occupational exposure to borate dust showed no adverse effect on reproduction.
Target organs: No target organ has been identified in humans. High dose animal ingestion studies indicate the testes are the target organs in male animals. Signs and symptoms of exposure:
Symptoms of accidental over-exposure to Boric Acid have been associated with ingestion or absorption through large areas of damaged skin. These may include nausea, vomiting and diarrhea, with delayed effects of skin redness and peeling. Refer to Section 11 for detai.ls on Toxicological data. 4 First aid measures
* Inhalation:
If symptoms such as nose or throat irritation are observed, remove person to fresh air. Eye contact: Use eye wash fountain or fresh water to cleanse eye. If irritation persists for more than 30 minutes, seek medical attention.
Skin contact: No treatment necessary because non-irritating.
Ingestion:
Swallowing small quantities (one teaspoon) will cause po harm to healthy adults. If larger amounts are swallowed.
give two glasses of water to drink and seek medical attention.
Note to physicians:
Observation only is required for adult ingestion in the range of 4-8 grams of Boric Acid. For ingestion of larger amounts, maintain adequate kidney function and force fluids. Gastric lavage is recommended for symptomatic patients only. Hemodialysis should be reserved for massive acute ingestion or patients with renal failure. Boron analyses of urine or blood are only useful for documenting exposure and should not be used to evaluate severity of poisoning or to guide treatment 1* Refer to Section 11 for details. &#xa9; 1996 U.S. Borax Inc. 265470 I of4 
* *
* Boric Acid Manufacture Grade 5 Fire fighting measures * . . . . General hazard: None, because Boric Acid is not flammable, combustible or explosive.
The product is itself a flame retardant.
Extinguishing media: Any fire extinguishing media may be used on nearby fires. 6 Accidental release measures General: Boric Acid is a water-soluble white powder that may, at high concentrations, cause damage to trees or vegetation by root absorption. (Refer to Ecological information, Section 12, for specific information.)
* Land spill: Vacuum, shovel or sweep up Boric Acid and place in containers for disposal in accordance with applicable local regulations.
Avoid contamination of water bodies during cleanup and disposal.
No personal protective equipment is needed to cleanup land spills. 7 Handling and storage General: No special handling precautions are required, but dry, indoor storage is recommended.
To maintain package integrity and to minimize caking of the product, bags should be' handled on a first-in, first-out basis. Good housekeeping procedures should be followed to minimize dust generation and accumulation.
Flammability classification (29 CFR 1910.1200): flammable solid. Spillage into water: Where possible, remove any intact containers from the water. Advise local water authority that none of the affected water should be used for irrigation or for the abstraction of potable water until natural dilution returns the boron value to its normal environmental background level. (Refer to Sections 12, 13 and 15 for additional information.)
Boric Acid is a non-hazardous waste when spilled or disposed of, as defined in the Resource Conservation and Recovery Act (RCRA) regulations (40 CFR 261). (Refer to Regulatory information, Section 15, for additional references.)
Storage temperature:
Ambient Storage pressure:
Atmospheric Special sensitivity:
Moisture (caking) 8 Exposure controls/personal protection
* , Engineering controls:
Use local exhaust ventilation to keep airborne concentrations of Boric Acid dust below permissible exposure levels. Personal protection:
Where airborne concentrations are expected to exceed exposure limits, NIOSH/MSHA certified respirators should be used. Eye goggles and gloves are not required for normal industrial exposures, but may be warranted if environment is excessively dusty. 9 Physical and chemical properties Appearance:
White, odorless, crystalline solid Specific gravity: 1.51 Vapor pressure:
Negligible@
20&deg;C Solubility in water: 4.7% @20&deg;C; 27.5%@ 100&deg;C 10 Stability and reactivity . General: Boric Acid is a stable product, but when heated it loses water, first forming metaboric acid (HB0 2), and on further heating it is converted into boric oxide (B 2 0 3). 2of4 Occupational exposure limits: Boric acid is treated by OSHA, Cal OSHA and ACGIH as "Particulate Not Otherwise Classified" or "Nuisance Dust". The OSHNPEL (Permissible Exposure Level) is 15 mg/m 3 total dust and 5 mg/m 3 respirable dust. The Cal OSHNPEL is 10 mg/m 3* The ACGIH!fL V (Threshold Limit Value) is 10 mg/m 3* Melting point: pH @20&deg;C: Molecular weight: l 70.9&deg;C (340&deg;F) (heated in closed space) 6.1 (0.1 % solution);
5.1 {l.0% solution);
3.7 (4.7% solution) 61.84 Incompatible materials and conditions to avoid: Boric Acid reacts as a weak acid which may cause corrosion of base metals. Reaction with strong reducing agents, such as metal hydrides or alkali metals, will generate hydrogen gas, which could create an explosive hazard . Hazardous decomposition:
None. U.S. Borax Inc. 265470 
* **
* 11 Toxicological information
* Acute toxicity Ingestion:
Low acute oral toxicity; LD 50 in rats is 3,500 to 4, I 00 mg/kg of body weight. Skin/dermal:
Low acute dermal toxicity; LD 50 in rabbits is greater than 2,000 mg/kg of body weight. Boric acid is poorly absorbed through intact skin. Inhalation:
Low acute inhalation toxicity; LC 50 in rats is greater than 2.0 mg/L (or g/m\ Skin irritation:
Non-irritant.
Eye irritation:
Draize test in rabbits produced mild eye irritation effects. Fifty years of occupational exposure to Boric Acid indicates no adverse effects on human eye. Therefore, Boric Acid is not considered to be a human eye irritant in normal industrial use. Sensitization:
Boric acid is not a skin sensitizer.
Boric Acid Manufacture Grade Other Reproductive/developmental toxicity: Animal feeding studies in rat, mouse and at high doses, have demonstrated effects on fertility and testes . Boric acid studies in rat, mouse and rabbit, at high doses, demonstrate developmental effects on the fetus, including fetal weight loss and minor skeletal variations 3* 4* The doses administered were many times in excess of those to which humans would normally be exposed 5* Carcinogenicity/mutagenicity:
No evidence of carcinogenicity in mice 6* No mutagenic activity was observed for boric acid in a battery of short-term mutagenicity assays. Human data: Human epidemiological studies show no increase in pulmonary disease in occupational populations with chronic exposures to boric acid dust and sodium borate dust. A recent epidemiology study under the conditions of normal occupational exposure to borate dusts indicated no effect on fertility
: 7. 12 Ecological information
' Ecotoxicity data General: Boron (B) is the element in boric acid which is used by convention to report borate product ecological effects. It occurs naturally in seawater at an average concentration of 5 mg BIL and generally occurs in freshwater at concentrations up to I mg BIL. In dilute aqueous solutions the predominant boron species present is undissociated boric acid. To convert boric acid into equivalent boron (B) content, multiply by 0.1748. Phytotoxicity:
Boron is an essential micronutrient for healthy growth of plants; however, it can be harmful to boron sensitive plants in high quantities.
Care should be taken to minimize the amount of Boric Acid released to the environment.
Algal toxicity:
Green algae, Scenedesmus subspicatus 96-hr EC 10 = 24 mg BIL t Invertebrate toxicity 8: Daphnids, Daphnia magna straus 48-hr LC 50 = 133 mg BIL t 21-day NO EC-LO EC = 6-13 mg BIL t Test substance:
t sodium tetraborate
! boric acid 13 Disposal considerations
*
* Disposal guidance:
Small quantities of Boric Acid can usually be disposed of at landfill sites. No special disposal treatment is required, but local authorities should be consulted about any specific local requirements.
Tonnage quantities of product are not recommended to be sent to landfills.
Such product should, if possible, be used for an appropriate application.
Fish toxicity:
Seawater 9: Dab, Limanda limanda 96-hr LC 50 = 7 4 mg BIL t Freshwater 10: Rainbow trout; S. gairdneri (embryo-larval stage) 24-day LC 50 = 150 mg BILt 32-day LC 50 = 100 mg BILt Goldfish, Carassius auratus (embryo-larval stage) 7-day LC 50 = 46 mg BIL t 3-day LC 50 = 178 mg BIL t Environmental fate data Persistence/degradation:
Boron is naturally occurring and ubiquitous in the environment.
Boric Acid decomposes in the environment to natural borate. Octanol/water partition coefficient:
Log P 0 w:*-0.7570 at 25&deg;C. Soil mobility:
Boric Acid is soluble in water and is leachable through normal soil. RCRA (40 CFR 261): Boric acid is not listed under any sections of the Federal Conservation and Recovery Act(RCRA).
NPRI (Canada):
Boric acid is not listed on the Canadian National Pollutant Release Inventory.
Refer to Section 15 for additional regulatory information.
14 Transport information . / ' DOT hazardous classification:
Boric acid is not regulated by the U.S. Department of Transportation (DOT) and is therefore not considered a hazardous material/substance.
TOG Canadian transportation:
Boric acid is not regulated under Transportation of Dangerous Goods (TDG). U.S. Borax Inc. 265470 International transportation:
Boric acid has no UN Number, and is not regulated under international rail, road, water or air transport regulations.
3 of4 
* *
* Boric Acid Manufacture Grade Regulatory information
* . OSHA/Cal OSHA: This MSDS document meets the requirements of both OSHA (29 CFR 1910.1200) and Cal OSHA (Title 8 CCR 5194 (g)) hazard communication standards.
Refer to Section 8 for regulatory exposure limits. WHMIS classification:
Boric Acid is classified as Class Division 2A under Canadian WHMIS guidelines.
FIFRA: Boric Acid (Manufacture Grade) is registered with the EPA (EPA Reg. No. 1624-117), in accordance with Section 3 of the Federal Insecticide, Fungicide and Rodenticide Act (FIFRA), as a pesticide product. Refer to EPA approved product label for additional product hazard and precautionary information.
Chemical inventory listing: Boric acid (10043-35-3) appears on several chemical inventory lists (including the EPA TSCA inventory, Canadian DSL, European EINECS, Japanese MIT!, Australian and Korean lists) under the CAS No. representing the anhydrous form of this inorganic salt. U.S. EPA TSCA Inventory 10043-35-3 Canadian DSL 10043-35-3 EINECS 233-139-2 South Korea 1-439 Japanese MITI (1)-63 RCRA: Boric acid is not listed as a hazardous waste under any sections of the Resource Conservation and Recovery Act (RCRA) or regulations (40 CFR 261 et seq). Superfund:
CERCLA/SARA.
Boric acid is not listed under CERCLA (Comprehensive Environmental Response Compensation and Liability Act) or its 1986 amendments, SARA (Superf1,1nd Amendments and Reauthorization Act), including substances listed under Section 313 of SARA, Toxic Chemicals, 42 USC 11023, 40 CFR 372.65, Section 302 of SARA; Extremely Hazardous Substances, 42 USC 11002, 40 CFR 355, or the CERCLA Hazardous Substances list, 42 USC 9604, 40 CFR 302. 16 Other information References l) Litovitz TL, Norman SA, Veltri JC, Annual Report of the American Association of Poison Control Centers Data Collection System. Am. J Emerg. Med. 4: 427-458 (1986). 2) Weir R J, Fisher RS, Toxicol. Appl. Pharmacol.
23: 351-364 (1972). 3) Fail et al., Fund. Appl. Toxicol. 17: 225-239 (1991). 4) Price et al., J. Am. Coll. Toxicol. 14: (2). 173 (Abst. P-17) (1995). 5) Murray F J, Regul. Toxicol. Pharmacol. (Dec. 1995). 6) National Toxicology Program (NTP)-Toxicology and carcinogenesis studies of boric acid in 86C3F 1 miee, Tech. Report Ser. No. 324, U.S. Dept. of Health and Human Services.
NIH Puhl. No. 88-2580 (1987). 7) Whorton eta/., Occup. Environ. Med. 51: 761-767 (1994). 8) S*hClberl et al., Tenside Surfactants Detergents 25: 99-107 (1988). 9) Hugman SJ, Mance G, Water Research Centre Report 616-M (1983). I 0) Butterwick L, de Oude N, Raymond K, Ecotoxicol.
Environ. Safety 17: 339-371 (1989). For general information on the toxicology of inorganic borates, see Patty's Industrial Hygiene and Toxicology, 4th Ed. Vol. II, (1994), Chap. 42, Boron; ECETOC Tech. Report No. 63 (1995). 4 of4 Safe Drinking Water Act (SOWA): Boric acid is not regulated under the SDW A, 42 USC 300g-1, 40 CFR 141 et seq. Consult state and local regulations for possible water quality advisories regarding boron compounds.
Clean Water Act (CWA) (Federal Water Pollution Control Act): 33 USC 1251 et seq. a) Boric acid is not itself a discharge covered by any water quality criteria of Section 304 of the CW A, 33 USC 1314. b) It is not on the Section 307 List of Priority Pollutants, 33 USC 1317, 40 CFR 129. c) It is not on the Section 311 List of Hazardous Substances, 33 USC 1321, 40 CFR 116. Canadian drinking water guideline:
An "Interim Maximum Acceptable Concentration" (!MAC) for boron is currently set at 5 mg BIL.
* IARC: The International Agency for Research on Cancer (IARC) (a unit of the World Health Organization) does not list or categorize boric acid as a carcinogen.
NTP Biennial Report on Carcinogens:
Boric acid is not listed. OSHA carcinogen:
Boric acid is not listed. California Proposition 65: Boric acid is not listed on the Proposition 65 list of carcinogens or reproductive toxicants.
Clean Air Act (Montreal Protocol):
Boric acid was not manufactured with and does not contain any Class I or Class II ozone depleting substances.
Product label text hazard information:
Refer to EPA approved product specimen label for additional product hazard and precautionary information.
For further information contact: U.S. Borax Inc. Health & Safety (805) 287-6050 Technical
& Sales Support (805) 287-6022 U.S. Borax Inc. 265470 (. 
* * &Lo\ . 'i"\ MATERIAL SAFETY DATA-SWEET PRODUCT \1-Ef'oll.T N NALCO NALCO 1250 PLUS C&deg;fti<.GOtt'{DIZWZ.IOF-sfo. Emergency Telephone Number Medical (800) 462*5378 (24 hours) (800) I*M*ALERT . SECTION . 1 PRODUCT IDENTIFICATION TRADE NAME: {NALCO 1250 PLUS}
* DESCRIPTION:
Ari aqueous solution of a modified amino compound NFPA 704M/HMIS RATING: 1/1 HEALTH 1/1 FLAMMABILITY 0/0 REACTIVITY O=Insignificant l=Slight 2=Moderate 3=High 4=Extreme SECTION 2 HAZARDOUS INGREDIENTS 0 OTHER Our hazard evaluation of the ingredient(s) under OSHA's Hazard Communication Rule, 29 CFR 1910.1200 has found none of the ingredient(s) hazardous.
SECTION 3 PRECAUTIONARY LABEL INFORMATION CAUTION! May cause irritation to skin and eyes. Avoid contact with skin, eyes and clothing.
Do not take internally.
Empty containers may contain residual product. Do not reuse container unless properly reconditioned.
SECTION 4 FIRST AID INFORMATION EYES: Flush with water for 15 minutes. Call a physician.
SKIN: Flush with water for 15 minutes. INGESTION:
Induce vomiting.
Give water. Call a physician.
INHALATION:
Remove to fresh air. Treat symptoms.
Call a physician.
NOTE TO PHYSICIAN:
Based on the individual reactions of the patient, -the physician's judgment should be used to control symptoms and clinical condition.
CAUTION: If unconscious, having trouble breathing or in convulsions, do not induce vomiting or give water. SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY ROUTE(S) OF EXPOSURE:
Eye, Skin EYE CONTACT: SKIN CONTACT: INGESTION:
May cause irritation with prolonged contact. May cause irritation with prolonged contact. Can be harmful. SYMPTOMS OF exPOSURE:
A review of available data does not identify any symptoms from exposure not previously mentioned. AGGRAVATION OF EXISTING CONDITIONS:
A review of available data does PAGE l OF 8 NALCO CHEMICAL COMPANY ONE NALCO CENTER
* NAPERVILLE.
ILLINOIS 60563-1198 
* * ... N MATERIAL SAFETY DATA SHEET PRODUCT NALCO 1250 PLUS NALCO Emergency Telephone Number Medical (800) 462-5378 (24 hours) (800) I*M*ALERT SECTION 5 HEALTH EFFECTS INFORMATION CONTINUED ) not identify any worsening of existing conditions. SECTION 6 TOXICOLOGY INFORMATION
... -. -* TOXICITY STUDIES: Acute toxicity studies have not* been conducted on this product, but studies have been conducted on a similar product. The results are shown below. ACUTE ORAL TOXICITY (ALBINO RATS): LD 50 =Greater than 5,000 mg/kg ACUTE DERMAL TOXICITY (ALBINO RABBITS):
LD 50 =Greater than 2,000 mg/kg PRIMARY SKIN IRRITATION TEST (ALBINO RABBITS):
SKIN IRRITATION INDEX DRAIZE RATING: 0.33/8.0 Minimal irritation PRIMARY EYE IRRITATION TEST (ALBINO RABBITS):
EYE IRRITATION INDEX DRAIZE RATING: 0.33 /110.0 Practically non-irritating OTHER TOXICITY RESULTS: Ames test was weakly positive
* HUMAN HAZARD CHARACTERIZATION:
Based on our hazard characterization, the potential human hazard is: LOW SECTION 7 PHYSICAL AND CHEMICAL PROPERTlES COLOR: Clear, colorless FORM: Liquid DENSITY: 8.7-lbs/gal.
SOLUBILITY IN WATER: Completely SPECIFIC GRAVITY: 1.04-1.05
@ 77 Degrees F pH (NEAT) = 8.4 VISCOSITY:
3 cps @ 75 Degrees F FREEZE POINT: 28 Degrees F BOILING POINT: 211 Degrees F @ 760 mm Hg FLASH POINT: None ASTM D-1298 ASTM E-70 ASTM D-2983 ASTM D;..1177 .ASTM D-86 NOTE: These physical properties are typical values for this product. SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: None EXTINGUISHING MEDIA: water is boiled away. This product would not be expected to burn unless all the The remaining organics may be ignitable.
Use water to PAGE 2 OF 8 NALCO CHEMICAL COMPANY ONE NALCO CENTER
* NAPERVILLE, ILLINOIS 60563-1 1 SB AREA 708-305-1 DOD 
* *
* N MATERIAL SAFETY DATA SHEET PRODUCT NALCO 1250 PLUS NALCO Emergency Telephone Number Medical (800) 462-5378 (24 hours) (800) I*M*ALERT SECTION 8 FIRE AND EXPLOSION INFORMATION CONT. I HUED ) cool containers exposed to fire. UNUSUAL FIRE AND EXPLOSION HAZARD: May evolve NOx under fire conditions.
SECTION 9 REACTIVITY INFORMATION INCOMPATIBILITY:
Mineral acids, nitrites.
Avoid contact with strong oxidizers (eg. chlorine, peroxides, chromates, nitric acid, perchlorates, concentrated oxygen, permanganates) which can generate heat, fires, explosions and the release of toxic fumes. THERMAL DECOMPOSITION PRODUCTS:
In the event of combustion CO, C0 2 , NOx may be formed. Do not breathe smoke or fumes. Wear suitable protective equipment.
SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION:
Respiratory protection is not normally needed since the volatility and toxicity are low. If significant vapors, mists or aerosols are generated, wear a NIOSH approved or equivalent respirator.
For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a positive pressure, self-contained breathing apparatus is recommended.
VENTILATION:
General ventilation is recommended.
PROTECTIVE EQUIPMENT:
Use impermeable gloves and chemical splash goggles when attaching feeding equipment, doing maintenance or handling product. Examples of impermeable gloves available on the market are neoprene, nitrile, PVC, natural rubber, viton and butyl (compatibility studies have not been performed).
The availability of an eye wash fountain and safety shower is recommended.
If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. HUMAN EXPOSURE CHARACTERIZATION:
Based on Nalco's recommended product application and our recommended personal protective equipment, the potential human exposure is: H!GH. SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-HOUR PAGE 3 OF 8 NALCO CHEMICAL COMPANY ONE NALCO CENTER
* NAPERVILLE, ILLINOIS 60563-1 1 88 
* *
* N MATERIAL SAFETY DATA SHEET PRODUCT NALCO 1250 PLUS NALCO Emergency Telephone Number Medical (800) 462-5378 (24 hours) (800) I*M*ALERT SECTION *11 SPILL AND DISPOSAL INFORMATION CONTINUED TELEPHONE NUMBER (800) I-M-ALERT or (800) 462-5378.
SPILL CONTROL AND RECOVERY:
Small liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent.
Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal.
Refer to CERCLA in Section 14. Large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal.
Refer to CERCLA in Section DISPOSAL:
If this product becomes a waste, it does not meet the criteria of a hazardous waste as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, nor is it listed under Subpart D. As a non-hazardous liquid waste, it should be solidified with*stabilizing agents (such as sand,. fly ash, or cement) so that no free liquid remains before disposal to an industrial waste landfill.
A non-hazardous liquid waste can also be deep-well injected in accordance with local, state, and federal regulations.
SECTION 12 ENVIRONMENTAL INFORMATION AQUATIC DATA: Results below are based on a similar product. 96 hour static acute LC, 0 to Bluegill Sunfish =* 190 ppm 96 hour static acute LC, 0 to Rainbow Trout = 360 ppm Results below are based on the product. 7-day chronic static renewal IC 25 for Ceriodaphnia Dubia reproduction=
17.3 mg/L 7-day no observed effect concentration is 8.1 mg/L based on no effect on reproduction.
48 hour static acute LC, 0 to Ceriodaphnia Dubia = 85 mg/L PAGE 4 OF 8 NALCO CHEMICAL COMPANY ONE NALCO CENTER
* NAPERVILLE, ILLINOIS 60563-1 1 88 AREA 708-305-1 ODO 
* *
* N MATERIAL SAFETY DATA SHEET PRODUCT NALCO 1250 PLUS NALCO Emergency Telephone Number Medical (800) 462-5378 (24 hours) (800) I*M*ALERT SECTION 12 ENVIRONMENTAL INFORMATION CONTINUED 48 hour no observed effect concentration is 31 mg/L based on no mortality.
TOXICITY RATING: If released into the environment, see CERCLA in Section 14. ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION:
Based on our Hazard Characterization, the potential environmental hazard is: MODERATE.
Based on Nalco's recommended product application and the product's characteristics, the potential environmental exposure is: MODERATE.
SECTION 13 TRANSPORTATION INFORMATION PROPER SHIPPING NAME/HAZARD CLASS MAY VARY BY PACKAGING, PROPERTIES, AND MODE OF TRANSPORTATION.
TYPICAL PROPER SHIPPING NAMES FOR THIS PRODUCT ARE: ALL TRANSPORTATION MODES PRODUCT IS NOT REGULATED DURING TRANSPORTATION SECTION 14 REGULATORY INFORMATION The regulations apply to this product. FEDERAL REGULATIONS:
OSHA'S HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:
Based on our hazard evaluation, none of the ingredients in this product are hazardous.
CERCLA/SUPERFUND, 40 CFR 117, 302: Notification of spills of this product is not required.
SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) -SECTIONS 302, 311, 312 AND 313: SECTION 302 -EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): This product does not contain ingredients Appendix A and Bas an Extremely Hazardous Substance.
SECTIONS 311 and 312 -MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found that this product is not hazardous under 29 CFR 1910.1200.
PAGE 5 OF 8 NALCO CHEMICAL COMPANY ONE NALCO CENTER
* NAPERVILLE, ILLINOIS 60563-1 198 
* *
* MATERIAL SAFETY DATA SH'EET* N PRODUCT NALCO 1250 PLUS NALCO Emergency Telephone Number Medical (800) 462-5378 (24 hours) (800) 1-M-ALERT SECTION 14 REGULATORY INFORMATION
* . ( CONTINUED ) Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.
The current thresholds are: 500 pounds or t:be threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.
SECTION 313 -LIST OF TOXIC CHEMICALS (40 CFR 372):. This product does not contain ingredients on the List of Toxic Chemicals.
TOXIC SUBSTANCES CONTROL ACT (TSCA):
* The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710). RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261 SUBPART C &*D: Consult Section 11 for RCRA classification.
FEDERAL WATER POLLUTION CONTROL ACT; CLEAN WATER ACT, 40 CFR 401.15 (formerly Sec. 307), 40 CFR 116 (formerly Sec. 311): None of the ingredients are specifically listed. CLEAN AIR ACT, Sec. 111 (40 CFR 60), Sec. 112 (40 CFR 61, 1990 Amendments), Sec. 611 (40 CFR 82, CLASS I and II Ozone depleting substances):
This product does not contain ingredients covered by the Clean Air Act. STATE REGULATIONS:
CALIFORNIA PROPOSITION 65: Hydrazine is known to the State of california to cause cancer. This product contains levels of hydrazine at less than 0.1\. MICHIGAN CRITICAL MATERIALS:
This product does not contain ingredients listed on the Michigan Critical Materials Register.
STATE RIGHT TO KNOW LAWS: This product does not contain ingredients listed by State Right To Know Laws. SECTION 15 ADDITIONAL INFORMATION Nalco internal number Fl02948 SECTION 16 RISK CHARACTERIZATION Due to our commitment to Product Stewardship, we have evaluated the human PAGE 6 OF 8 NALCO CHEMICAL COMPANY ONE NALCO CENTER
* NAPERVILLE, ILLINOIS 60563-1198 AREA 708-305-1 000 
* * * . i ... MATERIAL SAFETY DATA SHEET N PRODUCT NALCO 1250 PLUS NALCO Emergency Telephone Number Medical (800) 462-5378 (24 hours) (800) I*M*ALERT SECTION 16 RISK CHARACTERIZATION CONTINUED and environmental hazards and exposures of this product. Based on our recommended use of this product, we have characterized the product's general risk. This information should provide assistance .for your own risk management practices.
We have evaluated our product's risk as.follows:
* The human risk is: LOW.
* The environmental risk is: MODERATE.
Any use inconsistent.
with Nalco's recommendations may affect our risk characterization.
Our sales representative will assist you to determine if your product application is consistent with our recommendations.
Together we can implement an appropriate risk management process. This product material safety data sheet provides health and safety information.
The product is to be used in applications consistent with our product literature.
Individuals handling this product should be informed of the recommended safety precautions and should have access to this information.
For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations.
Please consult your local sales representative for any further information.
SECTION 17 BIBLIOGRAPHY ANNUAL REPORT ON CARCINOGENS, U.S. Department of Health and Human Services, Public Health Service, PB 33-135855, CASARETT AND DOULL'S TOXICOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J., Klaassen, c. D., and Admur, M. o., eds., Macmillian Publishing Company, Inc., N. Y., 4th edition, 1996. CHEMICAL HAZARDS OF THE WORKPLACE, Proctor, N. H., and Hughes, J. P., eds., J. P. Lipincott Company, N.Y., 3rd edition, 1991. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed., Van Nostrand Reinhold Company, N.Y., 9th edition, 1996. IARC MONOGRAPHS ON THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Henlth Organization, International Agency for Research on Cancer. PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D., Clayton, F. E., eds., John Wiley and Sons, N. Y., 4th edition, Vol. 2 A-F,.1994
* PAGE 7 OF 8 NALCD CHEMICAL COMPANY ONE NALCO CENTER
* NAPERVILLE, ILLINOIS 60563-1198 
* *
* N MATERIAL SAFETY DATA PRODUCT NALCO 1250 PLUS NALCO Emergency Telephone Number Medical (800) 462*5378 (24 hours) (800) I*M*ALERT SECTION 17 BIBLIOGRAPHY ( CONTINUED REGISTRY OF TOXIC EFFECTS ON CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, OH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart z, Toxic and Hazardous Substarices, Occupational Safety and Health Administration (OSHA). THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE WORKROOM ENVIRONMENT WITH INTENDED CHANGES, Conference of Governmental Industrial Hygienists, OH. PREPARED BY: Williams.
Utley, PhD., DABT, Manager, Product Safety DATE CHANGED: 12/19/94 DATE PRINTED: 10/04/96 PAGE 8 OF 8 NALCO CHEMICAL COMPANY ONE NALCO CENTER
* NAPERVILLE, ILLINOIS 60563-1 1 98 AREA 708-305-1 ODO 
** *
* MSDS FOR:CALGOW CORPORATION MANUF-ID:
LCS-60 MSDS-ID: 11 I I -_ _J 
* * ' ..........
I ______ J 
*. : : . *= . :,
.. :,
/ .. , ;* * :* :**, :* .;.*r.". *--
* . * ,**
.. * *
* *: * .:* ... ,. .. _-* '.* ( "'.':: )OOE'., INGREDIENT SECTION
.: ...
INGRDtP 1 CAStt: 7632-00-0 8HR-PEL: C-PEL: 8HR-TLV: STEL: ., . ,, . 10 '.*.: _*-.. , . ..:.:.;! : &#xa5; **'<'*-* &#xa5;*
MSDS',; FOl(i.CALGON
':CORPORATION i \'.'.\000.053
.. . . . . . . . . " . * * 
* *
* _. -*: ATTACHMENT 3 -. PALISADES PLANT NPDES PERMIT RENEWAL PROCESS REQUEST FOR USE OF TWO ADDITIONAL CHEMICAL TREATMENT ADDITIVES Detailed Description of Each Chemical and Usage 1) Alconox Detergent 8 Alconox Detergent 8 will be used at the Palisades Plant to decontaminate radioactivity in the reactor cavity. The amount to be used to decontaminate the cavity is expected to not exceed 4 gallons total once per year. Most other nuclear plants typically use 2-3 gallons where, each solution of product made is between a 385 ml to 500 ml per gallon. Once fed into the system, it will combine with approximately 90,000 gallons of water which will process through the radwaste system. The remaining distillate will be collected in Tank T-91 for eventual discharge to Outfall OOD. See Permit Application, SeGtion I, Exhibit I-11 Flow Diagram for the flow process. Positive Use: 2) The positive use of the Alconox Detergent 8 product versus other decontamination agents is: 1) A smaller dosage of the Alconox product will be used, 2) It will save dollars than most typical applications of other agents, 3) Most importantly, the Alconox product does not leave behind any -film or residual like most other decontamination agents. Therefore, additional rinsing with demineralizer water is not necessary, decreasing radiation exposure to plant workers. The use of this product should also reduce the amount of water being transferred to the radwaste evaporator and subsequently to the radwaste Tank T-91. This should relate to a reduction in volume of water discharged from Outfall D. If this product is permitted for an upcoming use in an outage scheduled for April 24, 1998, it will save the Plant $220,000.00 in reduced dosage cost and man hours. Therefore, expediting the for usage of this product would be greatly appreciated.
BetzDearborn Spectrus NXllOO BetzDearborn Spectrus NXllOO is a biofouling control agent to be used in the radwaste filter to effectively clean and remove odors within 00398-19.JAC 
* *
* the filter*F-100.
The radwaste tank (T-91) accepts several types of miscellaneous low volume wastes such as floor drain waste. Approximately 100 mls bf the Spectrus NXllOO will be added to the radwaste system weekly, or as needed. It will be processed through the radwaste system initially mixing with 3,000 gallons of radwaste water and then pumped into a 20,000 gallon storage tank. From there, it is eventually processed to Tank T-91 where it is stored and eventually batch released with the radwaste wastestream from Outfall OOD. Biodemand is expected to use all of the application utilizing dilution and evaporation in the initial stages of the process. Prior to reaching the radwaste Tank T-91, the expected radwaste concentration not based on biodemand is expected to be 200 ppm at Outfall OOD but, this expected concentration is extreme and does not include additional mixing with 40,000-75,000 gallons of water while awaiting batch release in Tank T-91. The expected discharge concentration for one treatment of Spectrus NXllOO at Outfall OOD prior to discharging to the mixing basin is expected to be zero based on demand and mixing. The Plant will stage treatment applications not to exceed a feed rate of 100 mls per treatment in order to determine an effective treatment while demonstrating that the expected Spectrus NXllOO discharge concentration at Outfall 001 should be zero . 
*
* DEC-08-1997 09:56 ALCO NO FAX Automated Product And Technical Data S Y S T E M ALcoNox, Inc. 9 EAST '4JTH STREET. SUITE 200 NEW YORK. NY 10016 (Z12) 532-4040 24 HOUR EMERGENCY NUMBER {CHEM-TEL) (IOOJ 255-3924 ., , . Page 1 of2 : . DEC 08 '97 09:55 ICESOLU NJ OFFICE rage L
* Document *117 MATERIAL SAFETY DATA SHEET l. IDENTIFICATION Product (As appears on label): CAS Registry Number: Effective Date: Chemical Family: DETERGENT 8,. Not Applicable March 1. I 995 Liquid Allcaline Detergent II. HAZARDOUS INGREDIENTSnDENTITY INFORMATION Name OSHA PEL ACCIH TLV (3) Ethylene glyool monobutyl ether 50 ppm 25 ppm <.5% Dipropylcne glycol methyl ether 100 ppm 100 ppm 20-30% There are ao other ingredients in DETER.CENT 8 .. which appeared on the OSHA Standard 29 CFR 1910 Subpart Z. Ill. PHYSICAUCHEMICAL CHARACTERISTICS Bolling Point Vapor Pressure (mm Vapor Density (AIR=l): Spedftc Gravity (Water=l):
Meltillg Poin1: Evaporation .Rate (Butyl Acetate=!):
SolubDily iD WQ1er: Appearance:
IV. FIRE AND EXPLOSION DATA Flash Point (Method U.Kd): 1'1ammablc Limil-.: ExtiaJ:uiQing Mcdi11: Special Prna:dul"'C.'li:
Unmwt.I Fire QDd Explosion V. REACTIVITY DATA 235&deg;F No data No d;i.ta 0.994 Not No data Completely soluble in all proportion,. . Clear liquid-:i-light ammonia odor 19l"F (Open cup) LEL: No O:ua UEL: No Data Water. dry chemical.
COz. folllll Self-contained positive pressure apparatus and protecti"e clothing should be worn when fighting fires involving chemicals.
None Stability:
Stahle wm nc>t occur Incompatibility (Mah.-rial....:
tu A..,oid):
Strong acids, oxidi7..en:
Hazardous Decomposition or Thermal dccomposiuon may release nitrou." oxides Vt HEALTH HAZARD DATA Route(s> of t:ntry: Health H.azacd..; (AC"ufr llDd Cbronk): lnhalalio11*!
Yes Skin'? Yes lngc. .. tinn? Ye..; Jnhal.:ltion of iipray or mist rei;ult in varying dt:grccs of irritation.
Ingestion c::rnsc discumiurl and/or n.:iu. .. e:1.. Cr.IC AC1 CCA'?
DEC-08-1997 09:57 '"""'-' ""' .,, v1*C..a. * .. .,,,
* ALCONOFAX
* Automated Product And Technical Data S Y S T E M ALcONOX, Inc. 9 EAST 40TH STREET. SUITE 200 NEW YORK, NY 10016 (212) 532-4040 2A HOUR BIERCEMCY NUMBER (CH!M-m) (IOO)
National Fire Proleclloa 704 labellne:
"""' *All:
2::modcr.aJr l=hil!h 4:::e:inremc Page2 Of2 DEC 08 '9? 09:56 I'CESOLU NJ OFFICE 609 461 6943 P.03 DU' "llO .I. 0 :::rL> rage DETERGENT B9 MATERIAL SAFETY DATA SHEET (cont'd) Sips and Symptoms of Exposure:
Medical Condilloa..-.
Generally NTP? No IARC No OSHA Regulated?
No Inhalation may cause in poorly vc:ntilu.tcd an:.as. Skin contact may prove locally irritating.
Aggravated by Exposutt:
Nol Unnecessary ir.ure tn thiii; pruduc.:l or any indusr.rial chemicoil should be :ztvoided. ing skin conditions (such open wounds) be aggravau:a by expo*
conditions may be aggrav:ned by the inhalation of cn.isr or spray. Emergency and Fil"'5t Aid flush eyes with cvpiuu:s cunounts of water for at IS minutes. See immediately.
Skia-Aush with plc:n1y of w3rer.
large quantitie.<.
nf water or milk. Do not induce ing. Tf vomiting occurs readmin.ister fluids. Sec a phy:sici"n immcdiaiely.
VIL PRECAUTIONS FOR SAFE HANDLING AND USE Ste&JS to be "D&kea IC MateriW ls .Released er Spilled: WaUe bispoul Mdlaod: Precautions to be Takea in Storine and Hudlini::
Other .Precautions:
VIII. CONTROL MEASURES Use absorbent material and remove with a shovel. Rinse remainder to S\!:Wcr. Material is biodegradable.
Small quantities may be t1u.<.hcd to sewer. Large quantitic.o; should be posed of in accordance with local fnr alkaline::
detergent.
Avoid extreme heat in storing. Open cozn.a.i.ncr slowly to release build-up.
Avoid splashing and spraying undi(u1e material.
No further :special ments other th;m good il1dustri3.l hytticnc and safety practices employed with any chemical.
Rc:5piratory Pmtcction (Sptti.fy Type): Not required.
Ventilation:
Local .Exhaust-Norm
:al Special-Not Required Mecbaoicaf-Not Requin:d Protecti'Vl?
Gloves: Eye Protec1ion:
Other Clothiac or Equipment:
WorklHyRienlc:
Practict:s:
Other-Not .Required Impervious are required and/or shi.dds required Eye wac:h shouW be availdblc.
before eating. drinking or nt&#xa3; ll'fFORMAllON ttER'flN IS CIYE>l Oil GOOD FAITH BUT HO WARRAHTY S EXPAESSl!D OR' lllPLIED.
DEC-08-199?
09?5? ALCONOX, Inc. Critical-cleaning derergenrs for laboratory, healthcare and industrial applications
* EAST 40TH STREET. SUITE 200 NEW YORK. NY 10016 Tel: (212) 532*4040 Fax: (212) 532*4301 24 HOUR EMERGENCY NUMBER (CHEM-TEL) (BOD} 255-3924 (E-MAIL) alcanox@plpeline.com (URL) nttp://www.alconox.com
*
* distributors
*technical information
* free samples
* new developments
*-*--.. Page i of 2 DEC 08 '97 09:56 ----------------------------
ICESOLU NJ OFFICE 609 461 6943 P.04 DOCUMENT #127 TECHNICAL BULLETIN Detergent S Low .. Foaming Phosphate-Free Detergent
* Rcplur.:e: . .;okcri: i.:lcanmg
* Ctinccnrra1cc.J lo ;.;;,ive y11u mc1ney
* Biodcgr;icl;1hle OJnd readily
* 1.1.'Clling rpwc:r ((I o;,1vc Y*'ll
* Free rin,1ng ro i;rvc ynL1 rcli<ihle rc ... ulr ... ;111d 111* 111:-.:ril..:r'111;.'
* Crn11;1i11' nn rh""f"lh:111:
..... 11lfl1r. chlorine.
h;didc. l-lmmt:.
1'111t1rc1i;Jrh11n m cht.:l<tting ingredients lllicd to clean: Circuit elec:tronic p;:irr:--.
phnsphare la(WJJc'e.
nu::le<ir re;u.:trn*
c:1vi1ie'.
delic;,rlc l"l.:lrh *rnd nuc.:lea1*
.:onraminHred eqlllrmc111 dunng Olll:tge.
l'sed to remove: Resini;. rnl\ini;.
c1il<.:. dirt. grrme. rarticulares.
resrd11r<.:.
dicmr* cnls and solvcnri.:.
Surfasces cleaned:
inhibited formulation recommended for l:!lasi..
metal. stsinlesi; steel. porc:elain.
ceramic, plai;tic.
fihergla'is.
circuit boards. Can he u'\ct.I. with prompt rinsing. on l'Oft metals c:tipper.
aluminum.
zinc. silver.
and nei:ium. Cnrrnsil1n resting I,<; advisable.
Cleaning method: Soak.
sponge.
ulm1sonic.
ware w;asher. 'r>ra> wd.,her. pressure w;ishe;;r
<1nd t1nw . Directions:
For manu<il. soak ancl ultrasonic make: a 3-5% solution r-L.(1 oz per gal. or 30-50 ml per literJ in w:irm or hot warer. An oily. milky i<.. nmm,11 P:*111ct:tivc:
gl11\*t!'
und :.:yewcur Me rc:1.:11mmended.
Fnr "rr;iy udd
*I\ lhC hot W<!)o.h C:)'i;lc l!l ii
.:rilulllln
(: I!:?, p;-, rer g:i/ 11; :;1 I ml pi:!r lircrl. FL..,r dil1&deg;1d1l1 )o.pfli;.
r,1i,c ''-illcr 1cmpcrar11rc
;ind ll!'C mtll'c dc1crc\*111 IUNSE THOROU0Hl
.* Y-rrcr'c1al*ly wirh lo\i1!t'r.
r*nr criric<il denning. d11 fin:il nr ult ill clio;11)lecl.
or purili1.:tl W<1tcr. l.J.;ed nn :1 r:.inge ot .. , ..
ph1sric anc.J meral Cormsinn 1ci-1ing advi1:ahlc.
An:iilable in C"onvenienl 1\konox CHI. rt --------*
1701 -----*****---*--*1-
... ----*--****-
I:: < jaJ. Drum 1715 55 Gal. Drum J 7.55 1 20-SO cleaninin:tllution DETERGENT His from leading hm:pital.
clini1.::il and 1nul"tri.ll )o.upplier;.;
For-. f;;ixed discrihumr lilil call rhe Alcono::ir fax informdtivn ii.:e "1t (212) 532-4040.
press 2 and Dncument #I 03. Write or cull Alc.:011*
'"<. Inc: rocluy for FREE :->ample!'
and informa[ion.
Let Alt:onox "nlv: your 1.:k.rn*ll:.!
p111hk1l" 
 
-------DEC-08-1997 09:59 ICESOLU NJ OFFICE 609 461 6943 P.05 Al CON OX, Inc. ! -oo_c_u-Me_N_r
_#1_2_1 _________
D_ET_E_AG_e_N_T -B-TE_c_H_N1-cA_L_B_u_LL-ET-1N Critical-cleaning detergents PHYSICAi.
DATA TYPl<.:AL VALUE for laboratory, healthcare pH or l % iiolution 11 .0 and industrial applications Specific:
gravity 1 g/m I) . 99 *
* DenSity 8.25 9 EAST 40TH STREET. SUITE 200 Flash Point (degreei:
F. clc"*eland open cupl :rn I NEW YORK. NY 10016 Pho.c;phate Content (ils W# Tel: (212) 532-4040 Organic Carhon ('W ciJlc:ula1cd w/v.1 1 J5-..+llo/c Fax: (212) 532-4301 Fragrance Con rent 14 HOUR EMERGENCY NUMBER Surface 1 % .Sol' 11 C l:lyne/cm l (CHEM-TEL)
(800) 255-3924 Color: Clear . CE-MAIL) alconor@plpellne.com form: Liquid Solubility in Water: Com1,letely CURL) http://www.alconox.com Hard Water Highly Effective
* dls1rlb utors
* technlcal Information BjodegradahiJity:
Biodefradable
*tree samples Foam Tendency:
Low fri;i1Tiing
*new developments Shelf Life: Approximate!:
one yenr in a sealed t:Onlainer Chemical Description
* .ge2of2 DEC 08 '9? 09:57 DETERGENT R i!' 11 non-innic.
pho.'lpharc-free homogeneous blend of an :ill.<1-nolaminc.
and an alkoxylmed farty ;ilcnhcil.
nC'I chi:h1t1ng
<igcnrs.
m cnnducl" c me1al catiC'M i.odium. Cleaning Validation Methods: Test a par:iniete1*
of rinse '-' nter before and after the cleaned surface. No icant change in the parameter indic:aces no derectahlc residue. Parameter; measured in:ludc: pH. spcctrC"lgrnphk me1hnds. 11.urfocc rcnli1nn.
and surface fln:il) 1;1'. Aicnnox fo:'< in1'11rm::irinn
\1*rvice (.2 I 2l 2 *ind r-cqucs1 D11c.:umc::nr
#l:cil formMe 1Morm*11inr1 Health Safet}' Information:
National Fire Procection----i Association 704 I RCRA Hazard Class: Ntin-h<1zardous EPA Priority Pollutants:
None DOT Ha1.ard Flan1mahilit,*:
Nn11-l1:lmrn;1 hlc l I f.Hft''.'1:
Content:
in Pr 1 t:l' Oral Tn:cicit):
> 5m '"E'l.:g 1 inl;frcdicnt defined ,,, 11n oral imcicant hy OSHA BLUE HEALTH 'l"ELLOW l REACTIVITY i f.yc Irritation:
P111entinlly
'crinu' eye 11Tir:ini voe Content: 7o'i; .ii' i ..
NTP = N11 JARC = OSHA= Nn Wl11TE SPECIAL U:111";i111lktin:
l=*li)lhl
,\:111;:11 All ingredienc.1; in 8 are in TSCA inven1ory.
Precautions:
N11 spcc:iul nrhcr rhul} gorn.J indu,1rial and prn1:liLt&deg;''
eniployctJ with any chemicc..I r .. cc D1rec1111n11.J.
Matcri.;.rl S;ifel, D;1w Shetr :ivailable.
* Contact Alccinox.
lnc. for purchase i;pecificatiom:.
Information i" typical. Not to be taken specifications.
1hc: rnf.ttnt:u
.... , tn *hi;ior rermn ft1'll """L"f"'ft*1.iirl'e'tl
*n J"IHlllll\.I
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.... **T"rl"l"h1..-r' 111 I lf\'li .1 ... 11,*1u1 .. ,1,,1 **:,I"""'"'"&deg;
(,,1, r.-i*f1111rt.I
\cl.hti" i.*,. ''''""***h''1i''ll , *I
{) 1996 Alt-11110'<.
In.:. TOTAL P.05 ** TOTRL PRGE.05 **
MAR. -.09' 98(M0Nl 16:08 ADMIN DEPT TEL:Sl7 788 1104 CTI LABORATORY P. 002 09:22 '5'608 356 2766 e Commonwealth Technp1ogy, Inc. Baraboo, WI \
* Fax Transmission Forrh I Dnte: March 9, 1998 To: Billie Blakely Consumers Energy Jackson, MI Fax Number: 51?*788-1104
! Projec, Number: From: f-ric T. Korthals or Pages! 1, including cover sheet
 
==Reference:==
 
Toxicity test results -Alconox I CTIFal Number: 608-356-2766
__ This is rhe only copy you will receive I _x_ Ha.rd capy w111 be mailed Results QfAltonoxioxicitt tests 48-h LCSO Ceriadaphnta d11bia c 23 .3&#xb5;L/L or 0.00233% (v:v) 48-h LCSO as a useage rate -= 23 .3 gallons per million gallobs of discharge/day
= 0.0233 gallons per thousand puons of dischai:gelday
' 96*h LCSO Plmephales promelas = 7 .74&#xb5;J../L or 0.000774% (v:v) ; 96-h LC50 as a useage rate == 7. 74 gallons per million of discharge/day
= 0.00774 gallons per gallons of discharge/day
* Co111monwealth Technology.
Inc. J :JSO Longe Court \ lf yo11 do nor rsc!ive all rhe pagts, plt1ase Baraboo, Wl539H 608-356-2760 PAXPOIU>UlOC MAR 9 '98 16:06 517 788 1104 PAGE.002 MAR-19-1998 07:39 FROM PALISADES CHEMISTRY TD 71282329 P.07 t. BETZOU.RBORN MATERIAL SAFETY DATA SHEET !ii BetzOearborn EFFECTIVE DATE: 24-SEP-1997
'NTED DATE: 01-DEC-1997
*
* 1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME {SPECTRUS NX1100:] PRODUCT APPLICATION AREA: BIOCIDE COMPANY ADDRESS: BetzDearbofn Inc; 4636 Somerton Road, Trevose Pa. 19053 Information phone number. (21S)-355-3300 EMERGENCY TELEPHONE (HEAL TH/ACCIDENT):
(800)-877
*1940 (USA) 2) COMPOSITION
/ INFORMATION ON INGREDIENTS Information tor specific product Ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards Of this formulation.
HAZARDOUS INGREDIENTS:
CAS# 52-51.-7 10377-60-3 261.72-55-4 7786-30-3 CHEMICAL NAME 2-BROM0-2-NITROPROPANE-i,3-DIOL Irritant (eyes); potential sensitizer (skin) MAGNESIUM NITRATE Oxidizer; irritant {eyes and skin) 5-CHLOR0-2-METHYL-4-ISOTHIAZOLIN-3-0NE Corrosive; toxic {by ingestion and skin absorption);
sensitizer (skin) MAGNESIUM CHLORIDE Potential irritant No component is considered to be a carcinogen by the National Toxicology Program,, the International Agency for Research on Cancer, or the Occ\Jpatronal Safety and Health Administration at OSHA thresholds for carcmogens.
PAGE 1 MAR 19 '98 7:41 CONTINUED TOTAL P.07 6167642273 PAGE.007 MAR-19-1998 07:39 FROM PALISADES CHEMISTRY I l'\\'V' ....... .._.. ,......., * ., * ._ * ....,. --* **._.-*-** *--TO EFF'.ECT-IVE DATE: 24-SEP-1997 DANGER Corrosive to skin. Skin sensitizer with delayed onset of symptoms.
Corrosive to the eyes. Mists/aerosols cause irritation to the upper respiratory tract DOT hazard: Corrosive*
to skin/&'teel Emergency Response Guide #153 Odor: None; Appearance:
Yellow, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media:
POTENTIAL HEAL TH EFFECTS ACUTE SKIN EFFECTS: Primary route of exposure; Corrosive to skin. Skin sensitizer with delayed onset of symptoms.
ACUTE EYE EFFECTS: Corrosive to the eyes .
* ACUTE RESPIRATORY EFFECTS: Mists/aerosols cause irritation to the upper respiratory tract. *"i :.-INGESTION EFFECTS: May cause severe irritation or burning of the gastrointestinal tract. TARGET ORGANS: Prolonged or repeated e;xposures may cause tissue necrosis and/or skin sensitization.
MEDICAL CONDITIONS AGGRAVATED:
Not known. SYMPTOMS OF EXPOSURE:
Direct contact with skin will cause severe delayed skin reactions or bums if not washed off immediately-follow first aid
* instructions
.. PAGE 2 CONTINUED MAR 19 '98 7:40 71282329 P.05 6167642273 PAGE.006 MAR-19-1998 07:37 FROM PRLISRDES CHEMISTRY TO rnv...,vv 1
-.. * ._._. * *----** , ... *** EFFECTIVE DATE: 24-SEP-1997
: 4) FIRST AID MEASURES
* SKIN CONTACT: . Remove clothing.
Wash area with large amounts of soap solution or water for 15 min. Immediately contact physician.
EYE CONTACT;
* Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment.
INHALATION:
Remove victim from contaminated area. Apply necessary first aid treatment.
Immediately contact a physician.
INGl!STION:
Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting.
Immediately contact physician.
DUute contents of stomach using 3-4 glasses milk or water. 5) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing
* apparatus (full type). EXTINGUISHING MEDIA: . dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides. FLASH POINT: * > 200F > 93C MISCELLANEOUS:
Corrosive to skin/steel UN3265;Emergency Response Guide #153
* 6) ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment.
Contain and absorb on absorbent material.
Place in waste disposal container.
Do not add decontaminant solution to waste drum containinp biocide or adsorbent.
Decontaminate floor residual with 10% metab1sulfite solution.
Use 10 volumes of solution to one volume of spill. DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreement.a permitted waste treatment facility or discharged under a permit Product as is
* Dispose of in approved pesticide facility or according to label instructions.
PAGE 3 CONTINUED MRR 19 '98 7:40 71282329 P.05 6167642273 PRGE.005 MAR-19-1998 07:37 FROM PALISADES CHEMISTRY TO I 1-';L._....
.........................
* -* --** *--*-** *--
DATE: 24-SEP-1997
: 7) HANDLING AND STORAGE
* HANDLING:
Contains an oxidizer.
Avoid all contact with reducing agents, oils, greases., organics and acids. Corrosive to skin and/or eyes. *
* STORAGE: Keep containers closed when not in use. Store between 20-100F for no more than 6 months. Store upright in original vented containers.
Product evolves C02 slowly. Store samples in plastic bottles due to pressure build-up.
: 8) EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE LIMITS CHEMICAL NAME 2-BROM0-2-NITROPROPANE-1,3-DIOL PEL (OSHA}: NOT DETERMINED TLV (ACGJH): NOT DETERMINED MAGNESIUM NITRATE PEL (OSHA): NOT DETERMINED TLV {ACGIH): NOT DETERMINED 5-CHLOR0-2-METHYL-4-ISOTHlAZOLIN-3-0NE PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED MISC: Note-mfg.
sugg. exp. limit:0.1 mg/m3 1WA;0.3mg/m3 STEL total isothia:toline).
MAGNESIUM CHLORIDE PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED PAGE 4 MAR 19 '98 7:39 CONTINUED 71282329 P.04 6167642273 PAGE.004 MAR-19-1998 07:35 FROM PALISADES CHEMISTRY TO 7128232:l P.03 EF-FECTIYEbAtE:
24-SEP-1997
: 8) EXPOSURE CONTROLS/PERSONAL PROTECTION (continued)
* ENGINEERING CONTROLS!
Adequate to maintain air contaminants below exposure limits-PERSONAL P,ROTECTIVE EQUIPMENT:
Use protecti\le equipment in accordance with 29CFR 1910 Subpart I RESPIRAtORY PROTECTION:
* A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 2Q CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use a respirattjr witn organic vapor/acid gas cartridges and dustfmist prefilters_
SKIN PRdTECTION:
* butyl gloves, chemical resistant apron-Wash Off after each use. Replace as necessary.
EYE PROJECTION:
splash proof chemical goggles, face shield 9) PHYSICAL, AND CHEMICAL PROPERTIES Specific Grav. (?OF, *2lC) Freeze Point (P') Freeze Point (C) 1.107 24 -4 Vapor Pressure (mmHG) Vapor Density {air=1) -18.0 < l.00 lO
* Viscosity 70F, 21C) Odor . % Solubility (water) None Yellow Liquid 100.0
* Appearance
* Physical state Flash Point, P-M (CC) pH As Is (approx.)
Evaporation!Rate NA = not applicable
* ND = not determined
: 10) STABILITY AND REACTIVITY STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occwr. INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
> 200F > 93C 3.0 < l.. 00 Thennat de&#xa2;omposition (destructive fires) yields elemental oxides. BETZ INTERNAL PUMPOUT/CLEANOUT CATEGORIES: "B" PAGE 5 CONTINUED MAR 19 '98 7:38 6167642273 PAGE.003 MRR-19-1998 07:35 FROM PRLISRDES CHEMISTRY Erf:ECTIYE DATE: 24-SEP-1997 TO 11) TOXICOLOGICAL INFORMATION
* Oral LOSO RAT: Dermal LDSO RABBIT: Skin Irritation Score RABBIT: l, 030 mg/kq * >2,000 mg/kg CORROSIVE CORROSIVE NEGATIVE Eye Irritation Score RABBIT: Skin Sensitization G.PIG: 12) ECOLOGICAL,iNFORMATION AQUATIC TOXICOLOGY Fathead Minnow 96 Hour Static Renewal Bioassay LC50: 3.5 mg/L No Effect Level: 1.8 mg/L Daphnia magna 48 Hour Static Renewal Bioassay LC50: 5 mg/L No Effect Level: 2.5 mg/L BIODEGRADATION COD (mg/gm): 79 Calculated TOC (mg/gm): 36 Calculated BOD-5 (mg/gm): 13 Calculated 800*28 (mg/gm); 13 Calculated
.13) DISPOSAL CONSIDERATIONS
* If this undiluted product is discarded as a waste, tne us RCRA hazardous waste identification number is : D002=Corrosive(steel).
Please be advised; however, that state and local requirements for waste dispasal may be more restrictive or otherwise different from federal regulations.
Consult state and local regulations regarding the proper disposal of this material.
: 14) TRANSPORT INFORMATION DOT HAZARD:; Corrosive to skin/steel UN I NA NUMBER: UN3265 DOT EMERGENCY RESPONSE GUIDE #: 153 PAGE 6 CONTINUED MRR 19 '98 7:38 71282329 P.02 
. . MRR-19-1998 07:35 FROM PRLISRDES CHEMISTRY 1 ... ,.. .. ,,_ * "'6r ...
* ......
* DA TE: 24-SEP-1997 TO 15) REGULATORY INFORMATION
*TSCA: This is an EPA registered biocide and is exempt from TSCA inventory requirements.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ): No regulated constituent present at OSHA thresholds FIFRA REGISTRATION NUMBER:
SARA SECTION 312 HAZARD CLASS: lmmediate{acute);Delayed{Chronic)
SARA SECTION 302 CHl:MICALS:
No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
CAS# CHEMICAL NAME 71282329 P.01 52-51-7 2-BROM0-2-NITROPROPANE-1,3-DIOL RANCE 2.0-5.0% 2.o-s:o% 10377-60-3 MAGNESIUM NITRATE CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION
: 65) CHEMICALS PRESENT: No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION
* No regulated constituent present at OSHA thresholds
: 16) OTHER INFORMATION NFPA/HMIS Health Fire Reactivity Special 3 1 CODE TRANSLATION Serious Hazard Slight Hazard Minimal Hazard DOT corrosive (1) Protective Equipment 0 CORR D Goggles,Face Shield,Gloves,Apron (1) refer to section 8 of MSDS for additional protective equipment recommendations . CHANGE LOG
* 1'. EFFF!C'l'!VE DATE MSDS status: 24-SBP-1997 REVISIONS TO SECTION: PAGE 7
* MRR f"osHr i-ax Note 71571 Phone* 'jj-/ CJ 19 '98 7:37 SUPERCEDES
** NEW ** 6167642273 PRGE.001 
< 'l .. L-'. "r..ts1maz
*81* w> [tt-mruf!rt E,vr'f] I "'"-.J -<-J 'I . ZiliiOWWWWWWNW#
October 31, 1997 Micl'llgan Department of Environmental Quallty Surface Water Quality DMllon, Stonn Wlttr Pto;ram Attn: Ml ..i.nny Malloy PlalrM9H Diltrk:t Otric9 POBoxl&S 821 North 10th Str9et Plainweff, Ml 49080 CONSUMERS ENERGY co*ANY, PAUIADES NUCLEAR PLANT: STORM WATER COMPLIANCE VERIFICATION, STRUCTURAL.
CONTROLS
 
==Dear Ml. Malloy,==
This letter meets the iequlnament.t stated In the cum1nt Storm Water General Permit No. MlROOOOOO, authorized under the Ce1tfftcate af Coverage No. MIR70P002, Part I SecUon s 7 ... Structural Contrula for PITt'IKrtlon and Trntmenr.
Thls verifies that structurai provisions identified in the currant Palllad9e Storm Water Pollution Prevention Plan (SW3P) W819 lmplementltd by the de9dline of November 10, 1897, ** required by the pennlt. The SW3P is available for lnepection Monday1hrough Frkfay, upon request. Pleaae contact me at (616) 764-2464 if you have any questions or would like to achedule a Inspection.
Sincerely, Eric R. Dehn Environmental Coordinator CC: Ms Susan Benzie, Surface Water Quality DM1lon, Lansing Ml (R\ (j NOV O' 7 1997 lYJ MO*PAL . *----MAR 18 '98 15:26 TOTAL P.01 6167642273 PAGE.001 
* , . * ** consumers Power POWERING MICHIGAN"S PROGRESS Palisades Nuclear Plant: 27760 Blue Star Memorial Highway, Covert, Ml 49043 March 21, 1997 Michigan Department of Environmental Quality Surface Water Quality Division.
Attn: Mr. Fred Morley 621 North 10th Street, PO Box 355 Plainwell, Ml 49080 RE: CONSUMERS ENERGY COMPANY, PALISADES PLANT, STORM WATER GENERAL PERMIT, CERTIFICATE OF COVERAGE NO. MIR70P002 STORM WATER POLLUTION PREVENTION PLAN NONSTRUCTURAL CONTROL VERIFICATION
 
==Dear Mr. Morley,==
This letter meets the requirements stated in the current Storm Water General Permit NO. MIROOOOOO, authorized under the Certificate of Coverage NO. MIR70P002, Part IB2(c), page 5 of the General Permit. This verifies the nonstructural controls identified in the current Palisades Storm Water Pollution Prevention Plan (SW3P) were implemented by November 11, 1996 as required by the General Permit. The SW3P is available for inspection Monday through Friday, upon request. Please contact me at (616) 764-2464 if you have any questions or would like to schedule a inspection.
Sincerely, Eric R. Dehn Environmental Coordinator CC: Mr John Vollmer, MDEQ, SWQ, Plainwell District Office
* ERD97*030 A CiH5 ENeRGY COMPANY
* March 20, 1997 Michigan Department of Environmental Quality Surface Water Quality Division Attn: Mr Fred Morley PO Box 355 Plainwell, MI 49080 CONSUMERS ENERGY COMPANY, PALISADES PLANT, STORM WATER GENERAL PERMIT, CERTIFICATE OF COVERAGE NO#MIR70P002 21EP10.l STORM WATER POLLUTION PREVENTION PLAN -NONSTRUCTURAL CONTROL VERIFICATION
 
==Dear Mr. Morley,==
This letter satisfies the requirements stated in the current Storm Water General Permit No#MIROOOOOO, authorized under the Certificate of Coverage No#MIR70P002, Part 182(c), page 5 of the GP, verifying the nonstructural controls identified in the current Palisades Storm Water Pollution Prevention Plan (SW3P) were implemented by November 11, 1996 as required in the GP .. The SW3P is available for inspection Monday through Friday upon request. Please contact Certified Storm Water Operator, Eric Dehn at Palisades at (616) 764-8913 to schedule an inspection.
Sincerely,
* CC: Mr John Vollmer, MDEQ, SWQ, Plainwell District Office 00397-20.JAC 
:J * **i ... consumers Power POWERING MICHlliAN"S PROGRESS Palisades Nuclear Plant: 27780 Blue Star Memorial Highway, Covert, Ml 49043 May 9, 1996 Michigan Department of Environmental Quality Attn. Mr. Fred Morley P.O. Box 355 621 North 10th Street Plainwell, MI 49080 RB: CONSUMERS POWER COMPANY PALISADES PLAH'l' STORM WATER GENERAL PERMIT, SWP3 CERTIFICATION CERTIFICATE OF COVERAGE MIR70P002
 
==Dear Mr. Morley,==
The Storm Water General Permit #MIR70P002 for the Palisades Plant requires a storm water pollution preventin plan (SWP3) to be developed by May 10, 1996. This letter certifies that the Palisades Plant has developed a SWP3 in accordance with Part II.B.4 of this permit. The non-storm water discharges in Part I.C.3.b. are covered in the plan. Other non-storm water discharges not covered in the plan are currrently covered in the Palisades NPDES permit # MI0001457 and the Ground Water Cleanup NPDES Permit #MI0049131.
The Palisades Plant SWP3 and it's reference documents are retained at the Plant and are available for inspection on Monday through Friday upon request. Please contact me at (616) 764-8913 EXT. 2464 if you would like to schedule a site visit. Sincerely, Eric R. Dehn Environmental Coordinator ERD96*042 A CMS ENER6Y COMPANY 
*
* CONSUMERS ENERGY COMPANY Nuclear Plant April 1. 1998, Renewal Permit Application Draft NPDES Permit No MI0001457 Comments March 30, 1998 1. Suggested changes are indicated by comment numbers on the attached marked-up pages of the September 5, 1994 current NPDES permit. PRELIMINARY COMMENTS ' Comment No Page Question/Comment 1 Page 2 of 17 The Company is requesting an increase in the authorized discharge water volume at Part I, A 1 Outfall 001 to Lake Michigan (bases provided in the Permit Application).
If the Mixing Basin Discharge Company is successful in obtaining the increase in flow at Outfall 001, the discharge Language Description flow volume should be revised from 135.2 MGD to 234.5 MGD to reflect the increase.
Revise the authorized discharge flow language to reflect the increase as ".234.5 MGD". 2 Source Description Add "an unspecified amount of storm water" to the source description of 'Outfall OCU, Mixing Basin Discharge.
There is point source contribution of storm water to the mixing basin. These storm water point sources are regulated according to Phase I Federal Storm Water Rules in which the Plant is currently in compliance.
See Permit Application transmittal letter and Attachment 4 for details on storm water. 3 Effluent Characteristics Delete Betz Clamtrol CT-1 permit requirements and associated language.
Betz CT-1 is Betz CT-1 no longer used at the Plant. Page 3of17 Part I, A** 1st & 2nd Paragraph Page 4of17 1st Paragraph 4 Effluent Characteristics Due to Betz Incorporated purchasing
 
==Dearborn Scientific,==
only the name of the Betz CT-Betz CT-2 and 4 2 product has been changed to "Spedrus CT1300". The marked-up copy of the permit reflects the name change. However, in order for the Plant to adjust to the name -change, the Company requests that the old name remain in parenthesis following the actual name in the renewed permit. Even though the product name changed, the product ingredients and associated concentrations have not changed. The Betz CT-4 product name did not change therefore, will remain the same. M0398-31.JAC 
*
* Comment No Page Question/Comment s Page 3of17 Please clarify "1 week 11* Most often, in other Company NPDES Permits the agency has Part I, A 1 ** defined one week as 11 5 working days 11 in regard to this requirement.
2nd Paragraph 6 Page 4of17 Replace "Natural Resources" with "Environmental Quality 11 to reflect the Department Part I, A 1 ** name change. lst Paragraph r 7 Page S of 17 The Company is requesting the elimination from monitoring and reporting flow at Part I, A 2 Outfalls OOA, OOB, and OOC. Outfalls OOA, OOB, and OOC are primarily noncontact Outfall OOA -OOF (Internal) cooling .water sources to the mixing basin discharge.
The effiuent from these sources have been well characterized through many years of the Plant being regulated under NPDES permits. The Company recommends the renewed Permit be revised to include the additional language in the source description paragraph for Internal Outfalls.
Add 11 primarily noncontact contact cooling water 11 wording to the source description before* the words 11 the following internal outfalls 11* 8 Outfall OOE -Neutralizer Delete Outfall OOE monitoring and reporting requirements.
Outfall OOE has been Tank Wastewater Outfall eliminated and is no longer operational.
See the Permit Application transmittal cover letter for details. To accurately reflect the elimination of Outfall OOE in the Part I, A 2 "Final Effiuent Limitations, Outfall OOA through OOF" heading, add the words "OOD, and OOF" to the Part I,A 2 Final Emuent Limitations heading. 9 Page 11of17 The Company suggests the permit renewal application deadline be revised to reflect the Part I, C 3 full five year term or "April 4, 2003 11* Schedule of Compliance M0398-31.JAC 
* -. '. c,' . __ .,...._ : i STATE OF MICHIGAN Se* a ... _ JOHN ENGLER. Governor DEPARTMENT OF NATURAL RESOURCES Si_,,, f. Ma.sen Bu1idlnq, P.O. 80130028.
Unslnq, Ml 48909 ROl.AHD HAAMES. Oirec:ior A-t..\Lel?-l}f'.'
<;&#xa3;RY Q F _MWU&#xa3;N1'" . \ ( rlA...-LJ 1N A1t'1 CC/1)1 BJT5_, September 16, 1994 rl'""t:' CERTIFIED MAIL Mr. Paul c. Hittle Director, Enviromnental Department Consumers Power Company 1945 West Parnall Road Jackson,
 
==Dear Mr. Hittle:==
 
==SUBJECT:==
NPDES Permit MI0001457 Consumers Power Company, Palisades Power Plant, Covert Your Pollutant Discharge Elimination System (NPDES) Permit has processed in accordance with appropriate state and federal regulations.
I: contains the requirements necessary for you to comply with state and federal water pollution control laws. REVIEW THE PERMIT EFFLUENT LL'!ITS AND COMPLIANCE SCHEDULES CAREFULLY*
Tilese are subject to the criminal and civil enforcement provisions oi both state and federal law. Permit violations are audited by the Depart:=.ent of Resources and the United States Agency and may appear in a published quarterly nonconrpliance report made available to agencies and the pub lie. Your and reporting responsibilities must be complied with in accordance with this permit. If applicable, Discharge Honitoring Report forms will be transmitted to you in the near future. These reports are to be submitted monthly or otherwise as required by your permit. Any re"Ports, notifications, or questions regarding the attached permit or program should be directed to the following address: Fred Morley, District Supervisor 621 North Tenth Street P .0. Box 355 Plainwell, !-!ichigan 49080 Telephone:
(616) 685-6851 
* *
* Consumers Power Page 2 September 16, 1994 All references within this permit made to the Water Quality
* 1 or Chief of the Water Quality Division are to refer to the : ''
* Surface*.
Quqlity Division or Chief of the Surface Water Quality ... *.' 'D}vis;i..on, ..
t:i v.e*ly. I I * **'.; * \ l *I I '* ... *, ** * *' .-I. *' Sincerely, a)d!hvm_ &#xa3;.
w1111am E. McCracken, P.E. Chief, Permits Section Surface Water Quality Division 517-373-8088
 
==Enclosure:==
 
Permit cc: EPA-Region V (2) 208 Agency -Southwest Michigan Regional Planning Commission Planning and Special Programs Section, SWQD Xr. Fred Morley -Plainwell District, SWQD (2) Data Entry, SWQD Point Source Studies (Grand Rapids District Office), SWQD Files 
* *
* OF XATl."'RAL
?..ESOL'RC:::S TO DISCHARGE THE
?OLLl:TAN'T DISCHARGE SYSTEM In ccmpliance with tlJ.e provisions of the Federal Water Pollution Control Act, as amended, (33 U.S.C. !.251 et seq; the "Act 11),
Act 245, Public Acts of 1929, as amended (the Act"), and Michigan Executive Order 1991-31, Consumers Power Company 1945 W. Parnall Road Jackson, Xichigan 49201 is authorized to discharge from a facility located at Palisades Power Plant 27780 Blue Star Memorial Highway Covert, Xichigan 49043 designated as CPCO-Palisades Power Plt to the receiving water the Lake in accordance with effluent limitations, monitoring requirements and other conditions set forth in this permit. This permit takes effect on January 1, 1995. Any person who is aggrieved by this permit file a sworn ?etition with the Michigan Commission of Natural Resources (c/o Chief, ?ermits Section, Surface Water Quality Division), setting forth the conditions of the permit are being challenged and specifying the grounds for the challenge.
The Commission may reject any petition filed more than 60 days.after issuance as being unti::;iely.
L"pon granting of a contested case, the Commission shall review the permit to determine which contested conditions shall be stayed until the Commission takes its final action. If a condition contested by the applicant is a requirement placed on wastewater covered bv a new or increased discharge authorization, such increased discharge authorization shall be stayed until the Commission takes action. All other conditions of the permit remain in full effect. If the contested condition is a modification of a previous permit condition the Commission detern:ines the contested condition shall be stayed, then such previous condition effect until the Commission takes final action. This permit and the authorization to discharge shall expire at midnight October l, 1998. In order to receive authorization to discharge beyond the date of expiration, the permittee shall submit such information and forms as are required by the Department of Natural Resources to the Permits Section of the Surface Water Quality Division no later than 180 days prior to the date of expiration.
This permit is based on an application received on April 5, 1993 as amended through
:6, 1994. On its effective date this permit shall supersede NPDES Perm.it No.
expiring October l, 1993. Issued 5, l 9Q6 . Robert P. Xiller Chief, Surface Water Quality Division 
* ?ERMIT XO.
Page 2 of 17 PART : A
* AND MONITORING REQrIREMENTS
: 1. Final Effluent j.imitations, Outfall 001 (Mixing Basin Jischarge)
During the period. beginning on the effective date of this permit and lasting until the expiration date of this ermit p,ermittee is authorized to (;"")\ d imum of one hundred thirty five million two-ri'un re ousand lJ.) .035,200,000) ns per ay o coo ng ower o owaown, noncontac:.
ng er an treated miscellaneous low volume wastewater consisting of steam S"'DOJ OCJ erator blowdown, demineralizer backwash and regeneration
\Jaste, reverse osmosis filter backwash, turbine sump drainage, floor drainage, laboratory waste and radwaste wastewatei;.
from outfall 001 to .Lake Michigan.
Such discharge shall be limited and by he erm ttee as s ecified below. ;;. a.
c..(
a MO\J"' +-o F SfD" M c....xl +er': Discharsze Limitations lbs/ dav Other Limitations Monthly Daily Monthly Daily _Effluent Characteristic Averasz:e Averasz:e Flow 01GD) (report) (report) Total Residual Oxidant (TRO)* Durins Chlorination
-No Bromine Use Monitoring Requirements Measurement Sample Freauencv TyPe Daily Report Total Daily Flow
* Discharsz:e Mode Continuous (greater than 120 min/day) 36 ug/l Daily Grab Intermittent than/equal to * (less 120 min/day) Jun l -Sep 30 100 ug/l ug/l Daily Grab Oct l -May 31 50 ug/l 200 ug/l Daily Grab Bromine Vse -the discharge of bromine shall not exceed 120 min/day Intermittent (less than/ equal to 120 min/ day) ' :o ug/ 1 Daily Grab Discharge Time (minutes/day) (report) Betz Clam-7rol a.as mg/l** (The authorizacion to dischar e CT-1 ceases after Decembe (j) c1-:.=1rol CT13&sect;) Betz Clam-1rol CT-4 Heat Addition (BTU/Hour)
Temperature
(&deg;F) Outfall Observation (report) pR (Standard Gnits) (continued)
Daily Minimum 6.5 a.Ol mg/l** 0.04 mg/l** 2, 10ax10 6 Daily Maximum 9.0 Daily *** l 1995) *** *** Daily Daily Daily Daily Report Total Discharge T !.:: Grab Grab Calculated Continuous Visual Grab 
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::o.
Page ' of 17 PART I Section A.l. (continued)
* Total Residual Oxi"Ciant (TRO) shall be *analyzed using EPA Method 330. l (alterr,ate methods may be used upon approval of the Plainwell District Supervisor of the Suriace Water Quality Division).
TRO monitoring is only required during periods of chlorine or bromine use and subsequent discharge.
Limitations for the inter=ittent discharge of chlorine apply only when the discharge of chlorine is less than or equal to 120 minutes per day, otherwise the limitations for continuous discharge of chlorine apply. Authorization to discharge bromine with or without chlorine is limited to 120 minutes per day at the limitations specified above with the additional requirement that any discharge of chlorine is restricted to a . concurrent discharge with bromine (no additional discharge of chlorine is authorized for that day). During the intermittent discharge of chlorine without bromine ("During Chlorination
-No Bromine Use" limitations given above), the daily maximum value reported for TRO shall be the average of a minimum of 3 equally spaced grab samples taken during a chlorine discharge event, with the additional limitation that no single sample may exceed 300 ugi 1. During the intermittent discharge of bromine with or without chlorine ("During Bromine Use" limitations given above), the daily maximum value reported for TRO shall be the maximum of at least 3 equally spaced grab samples taken during a bromine discharge event (no single saIIq)le may exceed 50 ug/l)
* The permittee shall enter a zero ("O") on the Discharge Monitoring Report for the TRO discharge modes not being used. The permittee may use dehalogenation techniques to achieve the applicable TRO limitations, using sodium thiosulfate, sodium sulfite, sodium bisulfite, or other dehalogenating reagents approved by the Plainwell District Supervisor.
The quantity of reagent(s) used shall be limited to 1.5 times the stoichiometric amount of chlorine/bromine oxidant. The permittee shall report monthly the quantity each dehalogenatiori reagent used per day. The permittee may report application time of chlorine and/or bromine as TRO discharge time upon the Plainwell District Supervisor of the Surface Water Quality Division.
&
Cll300 uv
\c.viuvJI'\ r:i") ** The sampling procedures, preservation and , and nalytical protocol compliance monitoring for Betz Clam-Trol (Clam-Trol CT-1, CT-2,and CT-4 shall be accorcance with the Methyl Orange detection level shall not exceed 0.2 mg/ 0.05 ::ig/l and 0.26 mg/l for Clam-Trolct:_j)
CT-2 and CT-4 respectively unless hig . levels are appropriate because of sample matrix interference.
Other methods may be use* upon approval of the Plainwell District Supervisor of the Surface Water Quality Divisio* The highest value measured during the discharge event shall be reported.
If the Clam-I concentration in all samples is less than the detection limit, report zero on the discr. monitoring reports. , The discharge of Clam-Trol CT-1, CT-2 and CT-4 is-restticted to no more than six (6) ti per year. The discharge o CT-1, CT-2 and CT-4 shall not exceed 12 hours when water temperature is 55&deg;F and highe r no more than than 16 hours when water temperature is below 55&deg;F, per e event. The permittee shall notify the Plainwell District Supervisor at least l week rior to each discharge. (continued)
S* 
* *
* Page -of 17 , . ........ PART :::. Section A.1. (continued) The water quality-based effluent limitations
:or and CT-4 are than the levels of detection using the specified analytical method. Detoxification or Clam-Trol treated effluent is required unless the permittee demonstrates, through balance calculations, that the discharge concentration of Clam-Trol will be less than or equal to the final effluent limits listed above (page 2 of 17). Such a demonstration must be submitted for approval to the Plainwell District Supervisor prior to the first treatment with Clam-Trol.
Any discharge of Clam-Trol at or above the level of detection is a specific violation of this permit. If all the samples in any
____ period are less than the level of detection, the Michigan Department o Natural will consider the permittee to be in compliance with the final this pollutant for that reporting period, provided that the permittee as also demonstrated compliance with the final limit through mass-balance ca culations or is als in full compliance with the toxicity testing program set forth in P rt I.A.3. e permittee shall gradually phaseout the use of Clam-Trol vear 1995 and may switch to CT-2 and/or CT-4 *** Every three hours during discharge.
: a. The receiving stream shall contain no unnatural turbidity, color, oil film, floating solids, foams, settleable solids, or deposits as a result of this discharge.
: b. Samples, measurements, and observations taken in compliance with the requirements above shall be taken prior to discharge to Lake Michigan.
A once pe1 shift (3 times daily) temperature measurement is permissible when either the continuous monitor or recorder is out of service for calibration or repair. c. Any unusual characteristics of the discharge (i.e., unnatural turbidity, color, oil film, floating solids, foams, settleable solids, or deposits) shall be reported immediately to the Plainwell Jistrict Supervisor of the Surface Water Quality Division followed with a written report within 5 days detailing the findings of the investigation and the steps taken to correct the condition.
: d. In the event the permittee shall require the discharge
'of water treatment additives in addition to any previously approved by the Plainwell District S.upervisor of the Surface Water Quality Division, the permittee shall notify the Plainwell District Supervisor.
Written approval from the Plainwell District Supervisor to discharge such additives at specified levels shall be obtained prior to discharge by the permittee.
The permit may be modified in accordance with the requirements of Part II.B.4. if a constituent of the additive or additives requires limiting.
: e. The term noncontact cooling water shall mean water used for cooling which does not come into direct* contact *.Jith anv raw material, intermediate product, by-product, waste product, or product * 
* * **; .. . ?ER.."1IT
:*!1000145 7 ?age 5 of 17 PART : Section A . ., Final Outfalls OCA througn OOF (Internal outfalls)
During the period beginning upon the effective date 6:f and lasting until the expiration date of this permit, the permittee is authorized to the following internal discharges through outfall 001 to Lake f-1' Such discharges shall be limited and monitored by the permittee as 11 riolf'\
t.ool;l"'f
(>.)A.W _ Di-scharge Limitations lbs/dav Other Limitations Effluent Characteristic Monthly Daily Monthly Daily Ave-rain A1rera2e OOA -South cooliniz cower suction basin overflow (62 mgd Flow \:1GD) (report! 1, report) OOB -North coolin2 tower suction basin overilow (60 msd) Flow (MGD) (report) (report) OOC -Cooling tower blowdown (86 mgd) Flow (report:) (report) OOD -Radwaste wastewater (0.l mgd) Flow \ MGD) . (report) (report) Total Suspended Solids 30 mg/1 100 mg/l i OOE -Xeutralizer tank wastewater ( 0. l mizci i Flow (MGD) l report J (report:)
Total Suspended Solids 30 mg/l 100 mg/l OOF -Turbine sump oil separator
& volume reduction svst:em (0.1 mgd) Flow tMGD) (report) (report) Oil & Grease 15 mg/l 20 mg/l Monitoring Re9uirements Measurement Sample Frequencv Type Daily Daily Daily Per Batch P_er Batch Per Batch Per Batch Daily Report Total Daily Flow Report Total Daily Flow Report Total. Daily Flow Report Total l)aily Flow Grab Report Tota.i Daily Flow 2 X Monthly Grab a. The permittee shall not discharge priority pollutants, contained in chemicals for cooling tower waintenance, in the coolipg tower blowdown to the receiving ,waters of the state as a result of plant operations.
: b. Samples, measurements, and observations taken in collll>liance with the monitoring requiremencs above shall be taken prior to discharge to the mixing basin or co-mingling with other wastestreams
* 
* * *
?age o:-oi l i I Section A
* 3. Soecial
-Toxicity Testing During Clam-Trol Treatment If the permittee has not demonstrated through mass-balance calculations that :he i'inal effluent limits or 0.05 mg/l, 0.01 mg/l and 0.04 mg/l for Clam-Trol CT-1, ':T-2 and CT-4, res'PectiYely, will be met (See Part I .A. l., page of .lD, then the authorization to discharge Clam-Trol treated effluent aicer detoxification with clay from outfall 001 requires the permittee to conduct a 48-hour acute toxicity test using a Daohnia species to verify adequate detoxification.
This test shall be conducted on the discharge during the first treatment with each of the Clam-Trol produces following the effective date of this permit. This test shall be conducted using procedures contained in F:PA/600/4-90/027 for Measuring the Acute Toxicity of Effluent to Freshwater*
and Marine Organisms".
The results-of the above testing shall be submitted to Plainwell District Supervisor of the Surface Water Quality Division within 30 days following Clam-Trol application.
If the results of toxicity testing do not exceed 1.0 acute toxic units the permittee is authorized to continue the use and discharge of Clam-Trol as ?TOposed in the application received on April 5, 1993 as amended through March 16, t 994, and according to requirements of Part I.A. l. (page 2 of 17). If, upon review of the data, it is deteraiined by the Plainwell District Supervisor that the results of toxicity testing exceed 1.0 TU , the permittee will be so notified.
The permittee will not be authorized to discRarge Clam-Trol product( until a proposal to remedy the unacceptable condition(s) is approved by the PlainweJ" District Supervisor . "Acute toxic unit" is defined as the reciprocal of the test concentration that causes the acute effect bv the end of the acute exposure period. 4. Special Condition
-3oron
!he ?ermittee shall the discharge of steam generator blowdown for boron on a or. :ime basis when steam generator blowdown is routed directly to the mixing basin during a boron soak. This condition may occur when a steam generator boron soak is in progress and there is a need for an immediate steam generator blowdown over a .short period of time (i.e., less than 24 hours). Analysis should be conducted using the ASTM Tritration Method with a detection level of 1 mg/l. Discharge concentrations of boron through outfall 001 should be calculated based on mass balance. 7his monitoring is designed to determine whether this constituent will be discharged in significant quantities.
The results of the analysis of such monitoring shall be submitted to the Plainwell District of the Surface Water Quality Division within 60 days of the event. If, upon review of .the analysis, it is determined that this constituent requites limiting to protect the waters in accordance with applicable water quality standards, this ?ermit then be modi:ied in accordance with Part II.B.4. of this permit * 
.-* * * ?ER..'H':'
?age -of 17 PART I Section A. 5. Soecial Conditn,n
-Temperature Modification The Michigan Department of Natural Resources is considering the necessity of incorporating temperature limitations in this *permit to assure *that the requirements of Rule 82(1) of the Michigan Water Quality Standards are met. Therefore, when the consideration of this issue has been completed, the Department may modify this perinit_ in accordance with Part II.B.4. to add appropriate temperature limitations or requirements.
: 6. Special Condition
-PCB Prohibition I Effective upon the date of issuance of this permit, the permittee shall not discharge any polychlorinated biphenyls to the receiving waters of the State of Michigan as a result of plant operations.
: 7. Special Condition
-Intake Screen Backwash During the period beginning on the effective date of this permit and lasting until the expiration date of this permit, the permittee is authorized to discharge intake screen backwash from outfall 000 to Lake Michigan.
The permittee shall collect and remove debris accumulated on intake trash bars and dispose of such material on land in an appropriate manner . 8. Special Condition
-Reopener Clause This permit may be modified or, alternatively, revoked and reissued to comply with any applicable standard(s) or limitation(s) promulgated under Section 30l(b)(2)(c)(d), J04(b)(2) and 307(a)(2) of the Act, if the effluent standard(s) or limitationts) so promulgated: . . a. is(are) either different in condition or more stringent than any effluent limitation in the permit; or b. control(s) any pollutant not limited in the permit * 
* * *
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7 ?age B of 17 PART I Section A
* 9. Soecial
-Notification Requirement The permittee shall notify the Plainwell District Supervisor of the Surface Quality Division, in writing, within 10 davs of knowing, or having reason to believe, that any activity or change has occurred or will occur which would result in the discharge of: a. Detectable levels* of chemicals on the current Michigan Critical Materials .Register or priority pollutants or hazardous substances set forth in 40 CFR 122.21, Appendix D, which were not acknowledged in the application**
or liste.d in the application at less than detectable levels. b. Detectable levels* of any other chemical not listed in the application or listed at less than detection, for which the application specifica1ly requested information.
: c. :ui.y chemical*
at levels greater than five times the average level reported in the application***
Any other monitoring results obtained as a requirement of this permit shall be reported in accordance with the schedule of compliance.
*The detectable level shall be defined as the Method Detection Limit (MDL) as given in Appendix B to Part 136, Federal Register, Vol. 49, No. 209, October 26, 1984, pp. L.3430-31.
**The application received on April 5, 1993 as amended through March 16, 1994. 10. Dischar2e.to the Groundwaters The reissuance of this permit does not authorize any discharge to the groundwaters.
Such discharge must be authorized by a groundwater discharge permit issued pursuant to the Michigan Act . ._,.**:.* 
* *-* 000 14 5 i ?age 9 of 17 PART I 3.
: l. Representative Samples and measurements taken as required herein shall be representative of the volume and nature.of the monitored discharge.
: 2. Reporting:
: 3. a. DMR Submittal Reauirements
-The permittee shall submit Discharge Monitoring Report (DMR.) forms to the PCS Unit, Surface Water Quality Division, Michigan Department of Natural Resources, P.O. Box 30273; Lansing, Michigan, 48909-7i73, for each calendar month of the authorized discharge period(s).
The DMRs shall be postmarked no later than the 10th day of the month following each month of the authorized discharge period(s).
Definitions
: a. The monthly average discharge is defined as the total discharge by weight, or concentration if specified, during the reporting month divided by the number of days in the reporting month that the discharge from the production or commercial facility occurred.
If the pollutant concentration in any sample is less than the detection limit, regard that value as zero when calculating monthly average concentration.
When less than daily sampling occurs, the monthly-average discharge shall be determined by the summation of the measured daily discharges by weight, or concentration if specified, divided by the number of days during the reporting month when the samples were collected, analyzed and reported.
: b. The daily maxi::lum discharge means the total discharge by weight, or concentration i: specified, during any calendar day. c. The Regional Administrator is defined as the Region V Administrator, U.S.
at R-16J, 77 w. Jackson Blvd., Chicago, Illinois 60604. d. The Chief of the Permits Section, Surface Water Quality Division mailing address is P.O. Box 30273, Lansing, Michigan, 48909. 4. Test Procedures Test procedures for the analysis of pollutants shall,conform to regulations published pursuant to Section 304(h) of the Act, under which such procedures may be required . 
-* * * * ?age oi li PART : Section B . 5. Recording Resul-ts For each measurement or sample taken pursuant to the requirements of this permrt, the Fermittee shall record the following information:
: a. The exact place, date, and time of measurement or sampling;
: b. The person(s) who performed the measurement or sa'llll'le collection;
: c. The dates the analyses were performed;
: d. The person(s) who pe-rformed . the analyses;
: e.
* The analytical techniques or methods used; f. The date of and person responsible for equipment calibration; and g. The results of all required analyses.
: 6. Additional Monitoring by Permictee If the permittee monitors any pollutant at the location(s) designated herein more frequently than required by this permit, using approved analytical methods as specified above, the results of such monitoring shall be included in the calculatiot and reporting of the values required in the Discharge Monitoring Report. Such increased f=equency shall also be indicated.
: i. Records Retention All records and information resulting from the monitoring activities required by this pert:iit including all records of analyses performed and calibration and cf instrumentation and from continuous monitoring instrumentation shall be retained for a minimum of three (3) years, or longer if requested by the Regional Administrator or the Michigan Department of Resources . , .. :. ', ',/,* .*:,:.':*. 
-* * * .. i .. i'
:-n ooo 14 s 7 Page LL of 17 PART I C. SCHEDULE OF COMPLIANCE
: l. The permittee 9'ftall continue to operate the installed facilities to achieve the effluent limitations specified for outfalls OOD, OOE, OOF and 001. -2. Reapplication If the discharges authorized by this permit are expected to continue beyond the expiration date of this permit, the permittee is required to submit an application for reissuance to the Chief *of the Permits Section of the Surface Water Quality Division on or before A ril 3, 1998. 3. Within 14 days of every requirement date specified in this permit, the permittee shall submit a written notification to the Plainwell District Supervisor of the Surf ace Water Quality Division indicating whether or not the particular requirement was accomplished.
If the requirement was not accomplished, the notification shall include an explanation of the failure to accomplish the requirement, actions taken or planned by the permittee to correct the situation, and an estimate of when the requirement will be accomplished.
If a written report is required to be submitted by a specified date and the permittee accomplishes this, a separate written notification is not required . 
-* * * * ?::R.."1I!
i Page l:! of 17 PART '!:! A. :-L\NAG:D!ENT
'. : .:": Duty to Comply -All discharges authorized herein shall be consistent with the terms and conditions of this permit. The discharge of any pollutant identified in this permit frequently than or at a level in excess of that authorized shall constitute a violation of the permit. It is the duty of the to comply with all the terms and conditions of this permit. Any noncom?liance
.. ith the Effluent Limitations, Special Conditions, or terms of this permit constitutes a violation of Public Acts 245, of 1929, as amended, and/or PL 92-500, as amended, and constitutes grounds for enforcement action; for permit termination, revocation and reissuance, or modification; or denial of an application for permit renewal. 2. Change of Conditions Any anticipated facility expansion, production increases, or process modification which will result in new, different, or increased discharges of pollutants must be reported by submission of a new application to the Chief of the Permits Section of the Surface Water Quality Division or, if such changes will not violate the effluent limitations specified in this permit, by notice to the Plainwell District Supervisor of the Surface Water Quality Division.
Following such notice, the permit may be modified to specify and limit any pollutant not previousJ limited . 3. ContainmTnt Facilities The permittee shall provide facilities for conta;f.nment any accidental losses of oil or other polluting materials in accordance with the requirements of the Part 5 Rules of the Michigan Act. Operator Certification The permittee
*shall have the waste
:acilities under direct supervision of an operator certified by the Michigan Department of Natural Resources, as required by Section 6a of the Michigan Act. S.
Notification If, for any reason, the permittee does not comply with or will be unable to comply with any daily effluent limitation specified in this permit, the permittee shall provide the Plainwell District Supervisor of the Surface Water Quality Division with the following information, in writing, within five (5) days of becoming aware of such condition:
: a. A description of the discharge and cause of noncompliance; .and b. The period or noncompliance, exact dates and times; or, if not corrected, the anticipated time th:e noncompliance is expected to contint* and the steps taken to reduce, eliminate and prevent recurrence of thr noncomplying discharge.
I 
./ * * * ?:'.R..'1IT 14 5 i l3 of 17 PART II Section A. 6. Spill The permittee shall immediately report any spill or loss of oil or other polluting materials which occurs to the surface waters or groundwaters of the state by calling the Department of Natural Resources (DNR). During normal working hours contact DNR, Surface Water Quality Division, Plainwell District Office at 616-685-9886.
Outside of normal war.king hours, contact the 24-hour Pollution Emergency Allerting System (PEAS) at 1-800-292-4706 (calls from out-of-state dial l'-517-373-8166);
and within ten ( 10) days of the spill or loH, the permit tee shall submit to the Plainwell District Supervisor of the Surf ace Water Quality Division a full written explanation as to the cause and discovery of the spill or loss, clean-up and recovery measures taken, preventative measures to be taken, and schedule of.iI!lPlementation.
: 7. Facility Operation The permittee shall at all times properly operate and maintain all treatment or control facilities or systems installed or used by the permittee to achieve compliance wit.h the terms and conditions of this permit. 8. Adverse Impact The permittee shall take all reasonable steps to minimize any adverse impact to the surface or groundwaters of the state resulting from noncompliance with any effluent limitation specified in this permit including, but not limited to, such accelerated or additional monitoring as necessary to determine the nature and impact of the discharge in noncompliance.
: 9. Bypass a. Bypass Prohibition
-Bypass is prohibited unless: (1) Bypass was unavoidable to prevent loss of :ife, personal or severe property damage; (2) There were no feasible alternatives to the bypass, such as the use of auxiliary treatment facilities, retention of untreated wastes, or maintenance during normal periods of equipment downtime.
This condition is not satisfied if adequate backup equipment should have been installed in the exercise of reasonable engineering judgment to prevent a bypass; and (3) The permittee submitted notices as required under or 9.c. below. b.
of Anticipated Bypass -If the permittee knows in advance of the need for a bypass, it shall submit prior notice to the Plainwell District Supervisor of the Surface Water Quality Division, if possible at least ten days before the date of the bypass, and provide information about the aneicipated bypaas as required by the Plainwell Distr.ict Supervisor.
The Plainwell District Supervisor may approve an anticipated bypass,-after considering its adverse effects, if it will meet the three conditions listed in 9.a. above * (continued) j * * * ?age oi 17 ?ART --Section A.9. (continued)
: c.
of Bvuass -The permittee shall submit notice to the Plainwell District Supervisor of .the Surface Water Qualit,y Division of an unanticipated bypass by telephone at 616-685-9886 (if the notice is provided after regular working hours, use the following number: 1-800-292-4706) as soon as possible but no later than 24 hours from the time the permittee becomes aware or the circumstances.
: d. Written Report of Bypass. -A written submission shall be provided within five working days of commencing any bypass to the Plainwell District Supervisor of the Surface Water Quality Division, and at additional times as directed by the Plainwell District Supervisor.
The written submission shall contain a description of the bypass and its cause; the period of bypass, including exact dates and times, and if the bypass has not been corrected, the anticipated time it is expected to continue; steps taken or planned to reduce, eliminate, and prevent reoccurrence of the bypass; and other information as required by the Plainwell District Supervisor.
: e. Bypass Not Exceeding Limitations
-The permittee may allow any bypass to occur which does not cause effluent limitations to be exceeded, but only if it also ia for essential maintenance to assure efficient operation.
These bypasses are not subject to the provisions of 9.a., 9.b., 9.c., and 9.d., above. This provision does not relieve the permittee of any notification responsibilities under Part I.A.9. of this permit
* f, Definitions (1) Bypass means the intentional diversion of waste streams from any portion of a treatment facility.
(2) Severe damage means substantial physical damage to property, damage to the treatt1ent facilities which causes them to become fnoperable, or substantial and permanent
:..oss of natural resources
:which c:an reasonably be to occur in the absence of a bypass. Severe property damage does not mean economic:
loss caused by delays in production.
: 10. Power Failures !n order to maintain compliance with the effluent limitations and prohibitions of this permit, the permittee shall either: a. ?rovide an alternative power source sufficient to operate facilities utilized by the permittee to maintain compliance with the effluent limitations and conditions of this permit provision shall be indicated in this permit by inclusion of a specific compliance date in each appropriate "Schedule of Compliance for Effluent Limitations", b.
the reduction, loss, or failure of one or more of the primary sources of power to facilities utilized by the to compliance with the effluent limitations and conditions of this permit, the permittee shall halt, reduce or otherwise control production and/or all in order to maintain compliance with the eif luent limitations and conditions of this permit. 
* *
* XO.
i Page 15 of 17 PART II Section A. 11. Removed Substances Solids, sludges, filter backwash, or other pollutants removed from or resulting from treatment or control of wastewaters shall be disposed of in a manner such as to prevent any pollutant from such materials from entering navigable waters, or the entry of toxic or harmful contaminants thereof onto the groundwaters in concentrations or amounts detrimental to the groundwater resource.
: 12. Upset Noncompliance Notification If a process "upset" (defined as an.exceptional incident in which there is unintentional and temporary noncompliance with technology based permit effluent limitations because of factors beyond the reasonable control of the permittee) has occurred, the permittee who wishes to establish the affirmative defense of upset shall notify the Plainwell District S'.lpervisor of the Surface Water Quality Division by telephone within 24 hours of becoming aware of such conditions and within five (5) days, provide in writing, the following information:
: a. That an upset occurred and that the permittee can identify the specific cause(s) of the upset; b. That the permitted wastewater treatment facility was, at the time, being properly operated;
: c. That the permittee has specified and taken action on all responsible steps to minimize or correct any adverse impact in the environment resulting from noncompliance with this permit. In any enforcement proceedings the permittee, seeking: to the occurrence of an upset, has the burden of proof. 13. Any requirement of* this permit which is included under the unique terms of the Act and rules promulgated thereunder, is not eniorceable under the Federal Clean Water Act regulations .
I ** *
* l ?:::U-!!:
16 of 17 PART --3.
: l.
of Entry -:he perm.ittee shall allow the Michigan Department of Natural Resources, any agent appointed by the department, or the Regional Administrator, upon the presentation of credentials:
., -* a. To enter upon the permittee's premises where an effluent source is located or in which any records are required to be kept under the terms and conditions of this permit; and b. At reasonable times to have access to and copy any records requirad to be kept under the terms and condition*
of thi* permit; to inspect any monitoring equipment or monitoring method required.
in this permit; and to sample any discharge of pollutants
* :ransf er of Ownership or Control : .: ... . In the event of any change in control or ownership of* facilities from which the authorized discharge emanates, the permittee sha11 notify the succeeding owner or controller of the existence of this perm.it by letter, a copy of which shal1 be foivarded to the Plainwell District Supervisor of the Surface Water Quality Division and the Regional Administrator.
: 3. Availability of Reports Except for data determined to be confidential under Section 308 of the Act Rule 2128 of the Part 21 Rules of the Michigan Act, all reports prepared in accordance with the terT.1.s of this permit shall be available for public inspection at the o:fices of the State Uater Pollution Control A2encv and the Regional Administrator.
As required by the Act, effluent data shall not be considered conf:.:iential.
making any false statement on any such report: may result in the :.=position or cri:ninal pena.J..t:..es*
as provided for in Section 309 of* the Act and
; and 10 oi the Michigan Act. 4. ?ermit Modification After notice and opportunity for a hearing, this permit may be modified, suspended, or revoked in whole or in part during its term for cause including, buc not limited to, the following:
: a. Violation of any terms or conditions of this perm.it; b. Obtaining this permit by misrepresentation or failure to disclose ful1y, all relevant facts; or c. A change in any condition that requires either,' a temporary or permanent reduction or elimination of the authorized discharge . i
* I 
--* * ** **.: .. , P:'.R.'1IT
:\0. !-11000145 i Page Li of 17 PART II Section B. S. Toxic Pollutanes Notwithstanding Part II.B.4. above, if a toxic effluent standard or prohibition (including any schedule of compliance specified in such effluent standard or prohibition) is established under Section 307(a) of the Act for a toxic pollutant which is present in the discharge and such standard or prohibition is more stringent than any limitation for such pollutant in this permit, this permit shall be revised or modified in accordance with the toxic effluent standard or prohibition and the permit tee so notified.
"*-6. Civil and Criminal Liability --. Except as provided in permit conditions on "Bypass" (Part II.A.9., pursuant to 40 CFR 122.4l(m))
and "Upset" (Part II.A.12., pursuant to 40 CFR l22.4l(n)), nothing in this permit shall be construed to relieve the permittee from civil or criminal penalties for noncompliance, whether or not such noncompliance is due to factors beyond his control, such as accidents, *equipment breakdowns, or labor disputes.
: 7. Oil and Hazardous Substance Liability Nothing in this permit shall be construed to preclude the institution of any legal action or relieve the permittee from any responsibilities, liabilities, or penalties to which the permittee may be subject under Section 311 of the Act except as are exempted by federal regulations
* 8. State Laws Nothing in this permit shall be construed to preclude the institution of any legal action or relieve the permittee from any responsibilities, liabilities,.
or penalties established pursuant to any applicable State law or regulation"under authority preserved by Section 510 of the Act. 9. Property Rights The issuance of this permit does not convey any property rights in either real or personal property, or any exclusive privileges, nor does it authorize violation of any Federal, State or local laws or regulations, nor does it obviate the necessity of obtaining such permits or approvals from other_ units of government as may be required by law. 10. Severability The provisions of this permit are severable, and if any provision of this permit, or the application of any provision of this permit to any circumstances, if held invalid, the application of such provision to other circumstances, and the remainder of this permit, shall not be affected thereby. 11. Notice to Public Utilities (Miss Dig) The issuance of this permit does not exempt the permittee from giving notice to public and complying with each of the requirements of Act 53 of the Public Acts of 1974, being sections 460.701 to 460.718 of the Michigan Compiled Laws, when constructing facilities to meet the terms of this permit.}}

Latest revision as of 06:39, 6 January 2025

Forwards Application for Renewal of NPDES Permit M10001457 IAW License DPR-20,App B,Section 3.2.Application Submitted to Mi Dept of Environ Quality,Surface Water Quality Div,On 980330
ML18068A335
Person / Time
Site: Palisades Entergy icon.png
Issue date: 04/20/1998
From: Haskell N
CONSUMERS ENERGY CO. (FORMERLY CONSUMERS POWER CO.)
To:
NRC OFFICE OF INFORMATION RESOURCES MANAGEMENT (IRM)
References
NUDOCS 9804280100
Download: ML18068A335 (227)
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