View source for A04553, Rev 0 to CA04553, 55 Gal 100% Acetone CR Chemical Habitability

{{Adams
| number = ML20210V237
| issue date = 09/30/1998
| title = Rev 0 to CA04553, 55 Gal 100% Acetone CR Chemical Habitability
| author name = Gryczkowski G, Mihalcik J, Sommerville I
| author affiliation = BALTIMORE GAS &amp; ELECTRIC CO.
| addressee name = 
| addressee affiliation = 
| docket = 05000317, 05000318
| license number = 
| contact person = 
| document report number = CA04553, CA04553-R00, NUDOCS 9908230078
| package number = ML20210V122
| document type = ARCHIVE RECORDS, OPERATIONS SUPPORT-CALCULATIONS
| page count = 52
}}

=Text=
{{#Wiki_filter:s Engineering Senices Process Overview                                                EN-1-100 Re.ision 10 Page 105 of153 ATTACHMENT 19, CALCULATION COVER SHEET l                   INITIATION (Control Doc Type - DCALC)
Page_ / of M bCALCNo.: O d Y' f G Revision No.:      o Vendor Calculation (Check one):            0 Yes       )d      No ESP        [f/ppgog/0                              Supp No.:    O          Rev. No.:    o Responsible Group:       [pf Responsible Engineer: 6f, / [.                d./v CALCULATION ENGINEERING               O Civil                 O Instr & Controls U*
* Jf NucEngrg O Electrical            O Mechanical              O Diesel Gen Project O Life Cycle Mngmt O ReliabilityEngrg             O Nuc Fuel Mngmt O Other:

==Title:==
SfAff,         /te#4 f(//b#/
OM%l B+M O}fdked SMAdun Unit                       O UNIT 1               O UNIT 2
                                                                                                 )D COMMON
* Proprietary or Safeguards Calculation                O YES
                                                                                                )! NO Comments:                gg Vendor Cale No.:         g                             REVIS10.N NO.:  J/jf
* VendorName:               gg Safety Class (Check one):
                                                                )tf SR        O AQ            O NSR There are assumptions that require Verification during walkdown:
AIT # #4 This calculation SUPERSEDES:            gg REVIEW AND APPROVAL:
Responsible Engineer: [f            [ hgh.f[g                                 Date:
[9 Independent Reviewer: .rnl. _f;m>>,orv}lhYYN; RYAJ U*'*;                               Sl~l ~'   95 Approval:
j, A (n to .ic,             Md2 h,1              Date:
g p /936 l
1
                 /
9908230078 990817 PDR    ADOCK 05000317 P                       PDR                                                                                    i
_           _                                                                                         y

CA04553 Rev.0 Page 2
: 2. LIST OF EFFECTIVE PAGES Page Latest Page Latest    Page Latest  Page Latest Page Latest Rev         Rev            Rev          Rev         Rev 001 0       002 0          003 0        004 0       005 0 006 0       007 0          008 0        009 0       010 0 011 -0      012 0          013 0        014 0       015 0 016 0       017 0          018 0        019 0       020 0 021 0       022 0          023 0        024 0       025 0 026 0       027 0          028 0        029 0       030 0 031 0       032 0          033 0        034 0       035 0 036 0       037 0          038 0        039 0       040 0 041 0       042 0          043 0        044 0       045 0 046 0       047'0          048 0        049 0       050 0 051 0       052 0 l
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CA04553 Rev.0 Page 3
: 3. REVIEWER COMMENTS l
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i CA04553 Rev.0 Page 4
: 4. TABLE OF CONTENTS                                                                                                                   /
01.COVERSHEET...................................................................................................................1
: 02. LI ST OF EFFECTIVE PAGES ......... ............ ... ...... .................. ................. ... ...... ....... ... . . . . . . .. 2
: 03. REVI EWER COM M ENTS............. ................... .......... . .. .. ............ ...... ................... .. ... . .... .. .. 3
     - 04. TAB LE OF CONTENTS .... .......... ..................... .............. .............. ....... .. .... . ... .. .... ...... . ... .. . .. 4
: 05. PURPOSE............................................................................................................................5 06.INPUTDATA......................................................................................................................6
: 07. TEC HNICAL A S S UMPTION S ...... .... ............................. ......... ... ....... ..... ....... ....... . .. .. .. .. . .. 10 0 8. RE FE REN C E S .. . .. . . . . . . . . . . . . . .. . .. . . . . . . . .. .. . . . . . . .. . .. . . . . . . . . . . . . . . . .. . . . . . . . .. . . . . . . . . . . . . .. . . . .. . . . . .
: 09. METH OD S OF ANALYSI S ....... ........ .. .... . .... ......... .... .... . ..... . ..... ..... ... . . ..... ... .. . ..... . . ..... ..... .. I 3 1 0. C AL C U L ATI ON S . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . .. . . . . . . . . . . . .. .. . . . . . . .. . . . . . .. . .. . . . . . . . . . . . . . . . . . . . . . . . . . . .
1 1. DOCUMENTATION OF COMPUTER CODES..............................................................19 12.RESULTS.........................................................................................................................20 1 3 . C ON C LU C' lON 3. . . . .. . . . . . . . . .. . . . . . . .. . . . . . . . . .. . . . . . . . . . . .. . . . . . ... . . . . . . . . . . . .. . . . . .. . . . . . .. . . .. . . . .. . . . . . . . . .. .
1 4 . ATTA C HM ENTS . . . . . . . . . .. .. .. . ... .. . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
ATTACHMENT A: MS DS FOR ACETONE..................... ............................................... 22 ATTACHMENT B: ARCON96 RUN FOR AUX BLDO ROOF INLET........................... 37 ATTACHMENT C: ARCON96 RUN FOR WEST ROAD INLET PLENUM......... ........ 40 ATTACHMENT D: EXCEL SPREADSHEET ACETONE - AUX BLDG ROOF INLET......................................... 43 ATTACHMENT E: EXCEL SPREADSHEET ACETONE - WEST ROAD INLET.................................................. 47 A'ITACHMENT F: CROSS SECTIONAL AREAS.......................................................... 51 LA ST PAG E OF REPORT. ................. ....... .... .... ...... ... ... ..... ....... .... .. ... ....... . ........... .. ............ ... 5 2

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1 CA04553 Rev.0 Page 5
: 5. PURPOSE                      /
10CFR50 App.A GDC.19 (Ref.1) requires that a control room be provided, from which actions                  t can be taken to operate the nuclear power plant safely under normal conditions and to maintain it in a safe condition under accident conditions. Release of hazardous chemicals can potentially result in the control room becoming uninhabitable. Thus the NRC requires each utility to assess the habitab:lity of the control room during and after a postulated external release of hazardous chemicals based on the chemical toxicity limit, vaporization rate, and the relevant atmospheric dispersion coefficients (Ref.2). The explosion and flammability hazard of these chemicals must also be addressed (Ref.2).
CCNPP proposes to use 100% liquified acetone, which will be stored in 55 gal drums at the warehouse. The chemical habitability of the control room after a chemical release involving acetone was determined based on in-house dispersion calculations and toxicity determinations for the current control room configuration with the inleakage points at the control room inlet and exhaust dam pers and for the modified control room configuration with the inleakage points at the west road in et plenum (Refs.3-4). Results indicate that 100% liquified acetone can be stored at
                                                                                           ~
the. warehouse in a 55 gal drum without constituting a toxicological or fire hazard to the control room following a worst case accident for both the current and modified control room configurations.
The results of the toxicity calculations for 100% liquified acetone are as follows:
Peak Concentration Current Configuration        No Recirculation          .1.95 ppm With Recirculation          1.58 ppm Modified Configuration      With Reciiculation          1.27 ppm Toxicity Limit (IDLH)                                  20000 ppm Note that under the current and modified configurations, the peak control room concentration               ;
under worst case conditions is less than the IDLH toxicity limit, the maximum level from which one could escape within 30 minutes without any impairing symptoms or irreversible health effects. Acetone will not pose a flammability or explosion hazard, since the control room
       - concentration is much less than the lower explc,sion limit of 2.6 v/v% (26000 ppm) per Refs.5,9.
The current calculation incorporates many assumptions which make these results conservative.
(1)thout wi          physical incapacitation of an average                 human.A The regulatory     maximum requirements    concentration l of Ref.2 dictate a maximum concentration limit that could be tolerated for 2 minutes without physical incapacitation of an average human. IDLH denotes Immediately Dangerous to Life and Health                 !
and is defined as the maximum level from which one could escape within 30 minutes without any impairing symptoms or irreversible health effects (Ref.5). (2) For the current configuration the maximum control room intake flowrate of 8300 cfm is utihzed. This value is twice the normal operating value (Refs.6-8). (3) The contml room volume conservatively neglects dead spaces in the control room ceiling and the volume of room A512. (4) The most conservative methodology is utilized: turbulent evaporation.

I: , ,
CA04553 Rev 0 Page 6
: 6. INPUT bATA The following input data is incorporated into this work:
(01) Chemical data for acetone:
CAS number                                              67-64-1              Refs.5,9,10 Chemical formula                                        CH3COCH 3            Refs.5,9,10 Toxicity LimitIDLH (ppm)                                20000.               Ref.5 Odor threshold (ppm) .                                  100.'                Ref.5 Volume fraction -                                       1.00                 Ref.19 Volume (gal)                                            55                   Ref.19             l Specific gravity (gm/cc)                                0.791                Ref.15             !
Vapor pressure (mm Hg) VP                               400.@20 C            Ref.15             i Boiling point (Degrees C) TB                            56.2                 Ref.15 Molecular weight (gm/ mole) MB                          58.1                 Ref.15 Lower explosion limit (Vol%)                            2.6                  Ref.5,9,10 (02) Physical properties of air per Refs.13,14:
Molecular weight (gm/ mole) MA                                      28.97 Characteristic length in air (Angstroms) SIGA                       3.711                       l Molecular energy of attraction / Boltzmann constant (K) E/KA        78.6 Mass density of air (gm/cc) RHOA                                    1.204E-03 Viscosity of Air (gm/cm-sec) MU                                     l.83E-04                    i Universal Gas Constant (torr-cm3/gmole-K) R                         6.24E+04 (03) The updated control room volume of 234157 ff was extracted from Ref.18.
(04) Control room damper infiow for the current configuration is extracted from Refs. 7-8 and is defined as 8300 cfm or twice the maximum flowrate.
(05) Control room inleakage for the modified configuration is extracted from Refs. 3-4 and is defined as 3000 cfm.
(06) The Warehouse-Control Room ARCON96 X/Q inputs were derived as follows (Att.B):
(a) Number of meteorological data files:              3                      Refs.B2,B10 (b) Meteorological data file names:                   CC1991. MET            Refs.B2,B10 CC1992. MET            Refs.B2,B10 CC1993. MET            Refs.B2,B10 (c) Height oflower wind instrument (m):               10.                     Ref.B3 (d) Height of upper wind instrument (m):              60.                     Ref.B3
,         (e) Wind speed units type (1=m/s,2= mph,3= knots): 1                          Refs.B2,B10 (f) Release type (1= ground,2= vent,3= elevated):     1 l
[

CA04553 Rev.0 Page 7 (g) Release height (m)./                                 0.
2 (h) Building area (m ):                                  1155.                  , Att.F The cross sectional area calculations age analyzed in Att.F. The calculation of containment cross sectional area yields 12435.63 ft above the rooftop level      f 91'6". The auxiliary building cross sectional area can be calculated to be 1938.93 ft2 . For a west-to-east wind directiog the total cross-sectional area of the auxiliary building and the two containments is 26810 ft . For an capt-to-west wind direction, the total cross sectional area of the turbine building is 27167 ft . For a north-to-south and south-to-north wind firection, the total cross sectional area of the containment and the tybine buildipg is 21016 ft . The cross-sectional area of a single containment of 12435.63 ft or 1155 m will conservatively be used.
(i) Effluent vertical velocity (m/s):                    0 3
(j) Stack or vent flow (m /s):                           0 (k) Stack or vent radius (m):                            2.57 r = SQRT(A/n)                                            2    2 l
                = SQRT[(55 gal)*(3785.422cc/ gal)/(1.cm)/n*(1.E-4m /cm ))
                = 2.57 m
        - (1) Direction to source (deg):                           174                      Refs.B12,B14 (m) Source window (deg):                                 090                      Refs.B13-B14 (n) Distance from source to receptor (m):                300                      Refs.B12,B14 (o) Intake height (m):                                   15.62 91.5' + 4.75' - 45' = 51.25' = 15.62 m where 91.5' is the height of the Auxiliary Building roof (Ref.B6),4.75' is the control room exhaust height (Ref.B13), and 45' is ground level (Ref.B8).
(p) Grade elevation difference (m):                      0                        Ref.B1 (q) Primary output file name:                            CHWHCR.OUT (r) JFT file name:                                       CHWHCR.JFD (s) Surface roughness length (m):                        0.1                      Ref.B1 (t) Minimum wind speed (m/s):                            0.5                      Ref.B1
         -(u) Sector averaging constant:                           4                        Ref.Bl (v) Hours in average:              1 2 4 8 12 24 96 168 360 720                   Ref.Bl (w) Minimum number of hours: 1 2 4 8 11 22 87 152 324 648                         Ref.B1 (x) Horizontal diffusion coefficient (m):                1.19 o y=r/2.15=2.57/2.15=1.19 m (Ref.B1)
I l

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    ,.   ,,                                                                                                      ]
l CA04553 Rev.0:                                                                                      )
       ,     Page 8                                                                                               '
                '(y) Vertical diffusion coefficient (m)                   - 0.
(z) Flag for expanded output:                              n                      Ref.B1 (07) Atmospheric dispersion coefficients from the Warehouse to the Control Room:
0-' 2 hrs .       9.23E-05 sec/m3 2- 8 hrs          7.78E-05 sec/m3 8- 24 hrs -       3.24E-05 sec/m3 24- 96 hrs '       .2.26E-05 sec/m3
                      %-720 hrs .        1.89E-05 sec/m3 (Attachment B, Refs.B1, BIO, B15)
(08) The Warehouse-West Road Inlet' ARCON96 X/Q inputs were derived as follows (Att.C):              l (a) Number of meteorological data files:                   3                      Refs.B2,B10
               . (b) Meteorological data file names:                        CC1991. MET           'Refs.B2,B10   j CC1992. MET            Refs.B2,B10   i CC1993. MET            Refs.B2,B10   1 (c) Height oflower wind instrument (m):                    10.                    Ref.B3 (d) Height of upper wind instrument (m):                   60.                    Ref.B3        j l
(e) Wind speed units type (l=m/s,2= mph,3= knots): 1                              Refs.B2,B10
               - (f) Release type (l= ground,2-ment,3= elevated):           1                                    !
(g) Release height (m):                                    0.
2 (h) Building area (m ):                                    1155.                  Att.F The cross sectional area calculations a[e analyzed in Att.F. The calculation of containment cross sectional area yields 12435.63 fi above the rooftop level of 91'6". The auxiliary building cross sectional area can be calculated to be 1938.93 ft2 . For a west to-east wind     l directiog the total cross-sectional area of the auxiliary building and the two containments is 26810 ft . For an capt-to-west wind direction, the total cross sectional area of the turbine building is 27167 ft . For a north-to-south and south-to-nonh wind girection, the total cross sectional area of the containment and the tybine buildipg is 21016 ft . The cross-sectional    :
area of a single containment of 12435.63 ft or 1155 m will conservatively be used.
                ' (i) Efiluent venical velocity (m/s):                      0
                .(j) Stack or vent flow (m'/s):                             0 (k) Stack or vent radius (m):                             2.57 r = SQRT(A/n)                                              2  2
                        = SQRT[(55 gal)*(3785.422cc/ gal)/(1.cm)/n*(1.E-4m /cm ))
                        = 2.57 m (1) Direction to source (deg):                             162                   Refs.B12,B14

e
    .. a      ,;
e 4
                ' CA04553 Rev10 Page 9 (m) Source window (deg):                             :090'                   Refs.B13-B14 (n) Distance from source to receptor (m):             262                    Refs.B12,B14 (o) Intake height (m):.                             '9.14 The Auxiliary Building roof above the control room and above A512 will be sealed tight.    .
Most control toom inleakage can then be assumed to originate at the Auxiliary Building inlet plenum on the west road side (ES199702144). Per Ref.Bl1, the inlet plenum is 54'x10' with a bottom elevation of 70'. Thus the intake height is 75'-45'=30'=9.14 m l
                     - (p) Grade elevation difference (m):                  0                      Ref.B1 (q) Primary output file name:                        - CHWHWR.OUT
           ,-         (r)JFT file name:                                     CHWHWR.JFD (s) Surface roughness length (m):                     0.1                   'Ref.B1 (t) Minimum wind speed (m/s):                         0.5                    Ref.Bl (u) Sector averaging constant:                       .4                      Ref.B1 (v) Hours in average:              1 2 4 8 12 24 96.168 360 720             Ref.Bl
                     '(w) Minimum number ofhours: 1 2 4 8 11 22 87 152 324 648                     Ref.B1 (x) Horizontal diffusion coefficient (m):             1.19-c y=r/2.15=2.57/2.15=1.19 m (Ref.B1)
(y) Vertical diffusion coefficient (m)               0.
(z) Flag for expanded output:                        n                      Ref.Bl
                 ' (09) Atmospheric dispersion coefficients from the Warehouse to the West Road Inlet:          ,
0- 2 hrs          1.11E-04 sec/m3                                                   i
                          . 2-- 8 hrs         8.80E-63 sec/m3 -
8- 24 hrs         3.26E-05 sec/m3 24- 96 hrs        2.26E-05 sec/m3 96-720 hrs         1.94E-05 sec/m3                                                   ,
(Attachment C, Refs.B1, BIO, B15)
                                                                                                                )
1

CA04553 Rev.0 Page 10
: 7. TECHNICAL ASSUMPTIONS The following technical assumptions were utilized in this work:                                    4 (01) Per Ref.19,100% Acetone is stored in a storage drum of 55 gals capacity at the warehouse.
(02) Per Ref.15 in a postulated accident, it is assumed that the entire container of the toxic substance ruptures.
(03) An average ambient atmospheric temperature of 30 C and pressure of 760 torr will be used in this calculation. Variation in these parameters shows insignificant impact on the results (Ref.16).TA=30 PA=1 (04) The chemical spill will be assumed to spread in a circular shape with the maximum radius determined by a spill thickness of I cm per Ref.15.
(05) Based on the characteristics of the chemicals, the following release mechanfsms will be assumed: For the hydrochloric acid solution, the turbulent mass transfer is the worst of three methodologies: diffusion in still air, laminar mass transfer, and turbulent mass transfer.
(06) For laminar and turbulent mass flow, a wind speed of one meter /see is assumed. This is        !
consistent with the wind tunnel methodology and the CCNPP data of Ref.B3. Note that per            !
Ref.17 (p.265), a flow with Reynold's Number less than SE+05 is laminar.                            !
(07) The vapor pressure of the spilled material will be adjusted to the ambient conditions via the ideal gas law:
VP(@T,) = VP(@T,)
* T, / T,

CA04553 Rev.0 Page11' l
: 8. REFERENCES
        '(01)" Control Room",10CFR50, Appendix A, General Design Criterion 1.9.
       - (02) " Assumptions for Evaluating the Habitability of a Nuclear Power Plant Control Room During a Postulated Hazardous Chemical Release", Regulatory Guide 1.78,6/74.
(03)" Response to RAI: Accident Dose Analysis and Control Room Habitability Analysis for the MHA, FHA. and CEAEE", NRC-98-044.
(04)" Response to RAI: Control Room Habitability Analyses and MSLB Analyses", NRC          018.
(05) " Hazardous Chemicals Data Book", Second Edition, Edited by G. Weiss, Noyes Data Corporation.
       - (06) "Offsite and Control Room Doses Following a LOCA", Bechtel Calculatiori M-89-33
       ' Rev.3,7/9/91.
(07) " Fan Performance Curve", BGE DWG 12782-35, Rev.0.
(08) " Control Room Temperature During Normal and Emergency Recirculation Modes of Operation", Bechtel Calculation M-91-24,11/9/92.
(09)" SAX's Dangerous Properties ofIndustrial Materials", Ninth Edition, Richard J. Lewis Sr.
(10) MSDS for Acetone, Attachment A.
(11) "The Merck Index", Eleventh Edition,1989.
(12) " CRC Handbook of Physics and Chemistry",66th Edition, 1985-1986.
(13) " Handbook of Chemical Property Estimation Methods, Environmental Behavior of Organic Compounds", W.Lyman, W.Rechl, and D.Rosenblatt, McGraw Hill 1982.
(14)" Flow of Fluids through Valves, Fittings, and Pipe", Crane Technical Paper No.410,1988.
(15)" Toxic Vapor Concentrations in the Control Room Following a Postulated Accidental Release", NUREG-0570,6/79.
(16) "CCNPP Control Room Habitability Evaluation Due to a Postulated Spill of Ethanolamine",
Bechtel Calculation M-94-16 Rev.0,11/10/94.
(17) " Heat Transfer", Seventh Edition, J.P.Holman.
(18)"Modeling of the Control Room / Cable Spreading Room HVAC System Using GOTHIC Software", CA02725,1/8/97.
{.
(19)"Onsite Accidental Release of Acetone", Bechtel Calculation M-80-34,1/19/81.               l 1
J

CA04553 Rev.0
     . Page 12 (BI)" Atmospheric Relative Concentrations in Building Wakes", NUREG/CR-6331 Rev.1,5/97.      #
(B2) CCMAIL from Mark Abrams at PLG to G.E.Gryczkowski,3/5/97.
(B3) " Wind Flows and Dispersion Conditions at Calvert Cliffs", Maria Gavrilas and Melissa Wieland, BG&E-EP1,9/85.
(B4)" Atmospheric Dispersion Coefficient Calculations from the MSG and ADV to the Control Room", CA03533,1/17/97.
1 (B5)" Auxiliary Building and Containment Structures Exterior Elevations East & West", BGE      l Drawing 62-047-E, Rev.6 -                                                                      !
I (B6) " Auxiliary Building Roof Plan", BGE Drawing 62-043-E, Rev.12.                            1 (B7)" Containment Liner Plan, Elevation & Penetrations", BGE Drawing 61-740-E, Rev.19.
(B8) " General East and South Elevations", BGE Drawing 62-006-E, Rev.4.
(B9) " Equipment Location Turbine Building Unit 1 Plan Floor El 12'0"", BGE Drawing 60-207-E Rev.11.                                                                                  !
(B10)"ARCON96: Atmospheric Relative Concentrations in Building Wakes", CA03940,
     '8/21/97.                                                                                       i (B11)" Heating and Ventilation System, Auxiliary Building, El. 69'0", Sections and Details",   ;
BGE Drawing 60-330-E, Rev.14.                                                                  1 (B12) " Wind Tunnel Modeling of CCNPP", CA00748 Rev.0,10/25/95                                 l
     - (B13)"ARCON95 X/Q Analysis", Bechtel Calculation M-97-02 Rev.0,5/8/97.                        l (B14)"ARCON95 X/Q Analysis", Bechtel Calculation M-97-03 Rev.0,7/1/97.
(B15) " Analytical Software Installation Test of ARCON96", CA03941, 8/21/97.
i l
I I

CA04553 Rev.0 Page 13
: 9. METHOD OF ANALYSIS This work utilizes three separate methodologies to calculate mass transfer from the spill site to the control room.
(1) The first methodology is diffusion in still air for spills in closed areas and for liquids with high boiling points. The method of analysis utilizes the algorithms of Ref.15 to derive the toxic gas concentration inside the control room.
(la) Calculation of the Diffusion Coefficient of an air / toxic gas system for dilute gases at low pressures per Ref.13 by the method of Wilke and Lee:
2 DAB =         B'*TA35'MR"/(PA*SIGAB
* OMEGA) where 2
DAB =         Diffusion coefficient (cm /sec)
B' =   -
0.00217 - 0.00050 * (1/MA + 1/MB)"
MA=           Molecular weight of air (gm/ mole)
MB=          Molecular weight of toxic gas (gm/ mole)
MR=          (MA+MB)/(MA*MB) = Molecular weight of binary gas (gm/ mole)
TA =         Air temperature (K)
PA =         Air pressure (atm)
          ' SIGAB = Characteristic length of molecule A interacting with molecule B (A)
                     =
(SIGA+SIGB)/2 SIGA =       Characteristic length of molecule A (A)
SIGB =       Characteristic length of molecule B (A) = 1.18*VB''3                              ,
VB =         Lebas molal volume (cc/mol)                                                       '
OMEGA = Collisionintegral The Lebas molal volume VB can be calculated as follows per Ref.13:
VB =          14.8'(C) + 3.7'(H) + 7.4*(O) + 9.l *(O in Methyl Esters or Ethers)
                         + 9.9'(O in Ethyl Esters or Ethers) + 11 *(O in Higher Esters or Ethers)
                         + 12*(O in Acids) + 8.3*(O Joined to S, P, N) + 15.6*(N Double Bonded)
                         + 10.5*(N in Primary Amines) + 12*(N in Secondary Amines) + 27*(Br)
                         + 24.6*(Cl) + 8.7*(F) + 37'(I) + 25.6*(S) - 6.0*(3-Membered Ring)
                         - 8.5*(4-Membered Ring)- 11.5*(5-Membered Ring)- 15*(6-Membered Ring)
                          - 30* Naphthalene - 47.5* Anthracene + (Molecular weight / density)*(Element) 9 plculatq,9f The    collision OMEGA         integ+OMFg
                       = A/TS      C/c    +can E/e bp3   + G/c      ollows per Ref.13:
          .A=             1.06036 B=            0.15610 C=            0.19300 D=            0.47635 E=.          .l.03587-F=            1.52996 G=            1.76474 H=            3.89411 TS =          TA/(E/KAB)
E/KAB = SQRT(E/KA
* E/KB)                                                                      i E/KB =        1.15*(TB+273.15) .
: c. :.
t CA04553 Rev.0 Page 14 l
          . (Ib) Surface Area of a Spill Per Ref.15                /
l
           '                                                                                                      1 Ihe rate of n: ass transfer of a liquid into the atmosphere is directly proportional to the surface area of the spill. Ref.15 approximates the initial shape of the liquid body by a cylinder, with the
: height equal to the radius of the base.
VO(m') = Q*QF*(0.003785422 m'/ gal)
R0(m)=           (V0/x)"                                                                          !
2             2 A0(m ) = x*R0 The liquid spreads q uickly by gravity to a thin pancake on the ground. Its surface area may be        i estimated by the following equation:                                                                  i 2                 2 A(m ) =          x*(R0 +2*t*(g*V0*(SG-RHOA)/(x*SG))")                              ,
where'                                                                                                I SG =           ' Density of the liquid (gm/cc) 2 g=               Gravitational constant = 9.81 m/sec t=              Time (sec)
The surface area, however, does not expand indefinitely as the above equation indicates. The           i maximum area of the spill in an unconfmed space is estimated from the initial volume by assuming a spill thickness of I cm.
2
               - AF(m )'= V0/0.01 tA(sec) = Time to maximum area
                           =     (AF-AO)/SQRT(4
* x
* g* V0 *(SG-RHOA)/SG)
The total mass of the liquid can be calculated as follows:
MO =             Q*QF*SG*3785.422 gm where -
Q=               Storage quantity (gal)
QF      =-       Volume fraction ofliquid or weight fraction of solid SG      =        Specific gravity (gm/cc)
(1c) Vaporization Rate in Still Air:
When exposed to the atmosphere, liquids with boiling points above the ambient temperature will evaporate by diffusion into the air. The main driving force is the vapor pressure difference, i.e.,
concentration gradient, between the liquid phase and the air. The rate of a vapor diffusing into still air is computed from the Fickian diffusion equation in Ref.15 2
1              VR(gm/m -sec) = VP
* RHOV
* 10000. / p
* SQRT(DAB /(x*t))
                                                                                                       ~
where

Lm ,
c CA04553 Rev.0 Page 15 VP(torr) = -          Val hor pressure of the liquid p(torr) =              Ambient atmospheric pressure (760 torr)
.!          RHOV(gm/cc) = Vapor density of the liquid t(sec) = 2           : Time DAB (cm /sec) = Diffusion coefficient
: The vapor density of the liquid RHOV is derived from Ref.14 as follows:
RHOV(Ibm /cf) = 144*P'(psia)/(R*T(R)) -
RHOV(gm/cc) = 144*14.696/(1545/MB*T(R))*(.01601846 gm/cc/lbm/cf)
                              = MB(gm/ mole)
* 14.696*.01601846/(10.7292*T(R))
(Id) The vapor density outside the control room can be calculated via 2
VD(gm/m') =            VR(gm/m -sec)%F(m2 )*X/Q(sec/m')                        ,
The corresponding vapor density ouidde the control room in ppm is (Ref.13)
PPM =                  (24500/MB)
* VD(gm/m')
(le) The vapor concentration inside the control room at time t can be calculated via the following: dCcg/dt = A
* C ExT - A
* Ccn for t<tg          Ccgi = Cnxr * (l. - exP(-l
* t))
for tg<t<t , Ccn2 = CE xT * {1 - eXP[-X * (t-ta)]} + Cent
* exp[-X * (t-ta)]
for t>tmo        - Ccn3 = Ca2
* exp[-A * (t-t  m .)]
     - where 3
Ccn=          Control room concentration in gpi/m or ppm Cgxy =        External concentration in gm/m or ppm A=            Fca / Vca = Turnover constant in 1/ min at time t Fca =         Control room ingress and egress flow rate at time t Vca =         Control room volume-t=            Time (min) tg = _        Time at which recirculation starts,(min) t     =.
(mip)
                 =       Time SG(gm/cc)  at which
                                         * (l.cm) /evaporation (VR(gm/m -sec) of   tox3cmsubstance
                                                                   * (0.0001                ceaseg/cm ) * (60.sec
{
(1f) The spill area, vaporization rate, and vapor density are time-dependent quantities for diffusion m still air for spills in closed areas. The peak vapor density occurs at the time to            .
maximum area (tA), which should be used under these conditions.                                           1 (2) The second methodology is mass transfer to forced convection for laminar flow per Ref.15.
VD(gm/m3) = VFL'ADC*AF (1. 'exp(-A
* t))
PPM =          ' L(24500/MB)*VD l

r                                                                                                           1 g    -
CA04553 Rev.0 -
Page 16 7                                                                                                    !
ADC =         ' Atmospheric dispersion coefficient (sec/m3)                                 i AF          -
Final spill area (m2) See 1b.                                               ;
MB =-           Toxic gas molecular weight (gm/ mole)                                       l
               - VFL =          Laminar evaporation rate (gm/m2-sec)                                        !
                      =~
HDL*MB
* VP* 10000/(R*(T(C)+273.15))
T(C)=           Temperature in C at which VP is determined VP =            Toxic gas vapor pressure (mmHg)
TA    =         Ambient air temperature (C)
R=              Universal gas constant = 62400 torr-cm3/gmole-K HDL = '   '
Laminar mass transfg,coegjent (cm/sec)
                      =                                  Sc O.664*(DAB /L)*Re             .
(
DAB =           Diffusion coefficient (cm2/sec) See 1a.                                     ;
L=              Characteristic I                                                            l
                   =            (4*V0*l.E6/n)gggth (cm) .                                                   '
V0=             Initial volume (m3)-See Ib.
Re=             Reynolds number
                   =            L*VW*RHOA/MU VW =-           Wind velocity (cm/sec)
RHOA             dass density of air MU.=            Viscosity of air                                                            !
Sc =            Schmidt number                                                              :
                  .=            MU/(DAB *RHOA)                                                              !
               .A=,             Fca / Vca = Turnover constant in 1/ min                                     l Fca=          . Control room ingress and egress flow rate                                    '
:Vca=            Control room volmne t=              Time to maximum concentration = 10000.*SG/ VFL i
           - (3) The third methodology is mass transfer to forced convection for turbulent flow per Ref.15.
VD(gm/m3) = VFT*ADC*AF (1. - exp(-A
* t))
PPM =               (24500/MB)*VD where ADC = -         Atmospheric dispersion coefficient (sec/m3)                                 i AF =            Final spill area (m2) See Ib.
MB =            Toxic gas molecular weight (gm/ mole)
               - VFT =          Turbulent evaporation rate (gm/m2-sec)
                      =
HDT*MB'VP* 10000)(R*(T(C)+273.15))
VP    =         Toxic gas vapor pressure (mmHg)
TA    =         Ambient air temperature (C)
R=             Universal gas constant = 62400 torr-cm3/gmole-K HDT =  '
Turbulent mass tranger cgcient (cm/sec)
                      =
O.037*(DAB /L)*Re . *Sc                                                     !
DAB =          Diffusion coefficient (cm2/sec) See la.                                      l L=             Characteristic lg~ggth (cm)                                                 !
                   =
(4*V0* 1.E6/x) i                VO   =
Initial volume (m3)-See Ib.
Re=            Reynolds number
                    =            L*VW'RHOA/MU                                                               l
               . VW ' = -        Wind velocity (cm/sec) 1

CA04553 Rev.0 Page 17 RHOA = Mass density of air MU =        Viscosity of air   _
Sc =        Schmidt number ~
              =
MU/(DAB *RHOA) -
A, =
Fca / Vca = Turnover constant in 1/ min Fca =       Control rcom ingress and egress flow rate Vca = . Control room volume t=          Time to maximum concentration = 10000.*SO/VFT (04) Explosion and Flammability Limits:
Comparison of the maximum concentration of the relevant toxic chemical concentration inside the control room should yield a limiting value with which to compare against the explosion and flammability limits.
L

    . .                                                                                                 I CA04553 Rev.0 Page 18
: 10. CALCULATIONS The chemical concentration of 100% acetone inside the control room for a. chemical spill of 55 gal at the warehouse is calculated via EXCEL spreadsheets captured in the following attachments using the methodologies of Section 9:
Attachment D:     100% Acetone for Current Control Room Configuration Attachment E:     100% Acetone for Modified Control Room Configuration I
l I
l l
t

I I
CA04553 Rev.0 Page 19
: 11. DOCUMENTATION OF COMPUTER CODES This work employed the ARCON96 computer code, which was verified, benchmarked, and documented in Ref.B10. The installation is documented in Ref.B15. ARCON96 imalements a computational model for calculating atmospheric dispersion coefficients (X/Q's) in tie vicinity ofbuildings.
i l
t.

CA04553 Rev.0                                                                                      i Page 20 l
12.RESULTS                                           /
CCNPP proposes to use 100% liquified acetone, which will be stored in 55 gal drums at the warehouse. The chemical habitability of the control room after a chemical release involving acetone was determined based on in-house dispersion calculations and toxicity determinations for the current control room configuration with the inleakage points at the control room inlet and exhaust dampers and for the modified control room configuration with the inleakage points at the west road inlet plenum (Refs3-4), Results indicate that 100% liquified acetone can be stored at the warehouse m'a 55 gal drum without constituting a toxicological or fire hazard to the control   l room following a' worst case accident for both the current and modified control room configurations.
The results of the toxicity calculations for 100% liquified acetone are as follows:
1 Peak Concentration                             !
Current Configuration        No Recirculation            1.95 ppm With Recirculation          1.58 ppm                                 ;
Modified Configuration        With Recirculation          1.27 ppm                                 l Toxicity Limit (IDLH)                                   20000 ppm 1

r CA04553 Rev.0                          -
      - Page 21 -
: 13. CONCLUSIONS               /
Under the current and modified configurations, the peak control room concentration under worst case conditions is less than the IDLH toxicity limit, the maximum level from which one could escape within 30 minutes without any impairing symptoms or irreversible health effects.
Acetone will not pose a flammability or explosion hazard, since the control room concentration is much less than the lower explosion limit of 2.6 v/v% (26000 ppm) per Refs.5,9.
The current calculation incorporates many assumptions which make these n:sults conservative.
A maximum concentration limit (IDLH) was utilized that could be tolerated for 30 minutes (1)thout physical incapacitation of an average human. The regulatory requir wi                                                                                       .
dictate a maximum concentration limit that could be tolerated for 2 minutes without physical incapacitation of an average human. IDLH denotes Immediately Dangerous to Life and Health and is defined as the maximum level from which one could escape within 30 minutes without any impairing symptoms or irreversible health efTects (Ref.5).
For the current configuration the maximum control room intake flowrate of 8300 cfm is (2)lized.
uti          This value is twice the normal operating value (Refs.6-8).
(3) The control room volume conservatively neglects dead spaces in the control room ceiling and the volume ofroom A512.
(4) The most conservative methodology is utilized: turbulent evaporation.

I l l l
l I                                      i 1
l-     CA04553 Rev.0
!      Page 22
: 14. ATTACIIMENTS l                     ATTACHMENT A MSDS FOR ACETONE   l l
i l
l l
l l
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l

*PAGk882       01/24/96           11:04:52         FAX IDI BRfW.*mi-984D9MC-98RB1139 '                                (SOURCE 3 BERFACTS) i              Naoms me mse m Cm*
f7.8aker j                                                                              .
MATERIAL SAFETY DATA SHEET w' *d** "
M     s.e Tnd                           iinn ~ - - -            -~ ^-~T;.g,m g
    .       r M'@%
                 .=n.i ,.. Ni c 244 tout fmergency Telephone 906 859 2151
                                                            - > > ~ ><'.                           -"-"-i                   -             - ~ si - ><4, NoTO Of(MTSCC, CANL/TEC and Natonal Response Cente, evnerpenty su.nbers are en tse . sed ordy in NaGonst Response Cerder 800424 8807          the event of che.ikat einersendes Irwolvens e esdIL leaA are, esponse er accident hveewho diernkd6 Cherverec 800474-9300                        Am non<rnergency guentions should tie dkected to Castorner Sen4ce (84004TBAKla) for essistarme, A0446 -10                                                        Acetone                                                              Pages i Effective          07/12/95                                                                                          Issued: 24/ /01
                                                                   \000-Oc6 Mallinokrodt Baker,Inc., 222 Red School Lane, Phillipsburg, NJ 08865J SECTION I - PRODUCT IDFNTIFICATION
  .....................................................ei........................
Product Name                   Acetone Common Synonyms: Dimethyl Ketano;                              2-Propanone;                Dimethyl Ketal Chemical Family Ketones Formulas                       ( 0 11 3 } 200 Pormula Wt.:                   58.08 CAS No.:                       67-64-1 NIOSil/RTECS No.: AL3150000 Product Use                    Laboratory Reagent Product Codes                  9004,0007,9009,9015,5580,9125,9125,A134,9002,9010,9000,0001 9006,5805,9254,9005,5350 PRECAUTIONARY LABELING BAKER SAF-T-DATA
* System K ALTH       rLArtte!LTTY      REACTIVITY           CosJTAct 1
SLIGtfi 63 SEVERE 2
tt00CRATC 1
SLIGHT l'
Laboratory Protective Equipment E.N.
                                     -                                         EE              -
U.S. Precautionary Labeling I
DANGERI EXTRDELY FLAMMABLE LIQUID AND VAPOR. VAPOR MAY CAUSE FIASil PIRB. CAUSES IRRITATION. IIARMPUL IF SWALIDWED OR INilALFE.
Keep away from heat, sparks, flame. Avoid contact with eyes, skin, clothing.                                                                                ,
Avoid breathing vapor. Keep in tightly closed container. Use with adequate                                                                                  l ventilation. Wash thoroughly after handling.                                            In oase of fire, use alcohol                                        ;
foam, dry chemical, carbon dioxide - water may be ineffective. In case of                                                                                   g spill, soak up with sand or earth. Plush spill area with water.                                                                                             ;
I C A0455 3 REV 0 l
Continued on Page:                     2                            P A SE 23 l

  ,8PAGI883       81/24/96         11tBSf52         FAI IDI 88886381 M D9AAC419881139                                (SOURCEt BlWPACTS) 4                 [.T. Baker 222 R.5 School h
                                                            **'a' .5.and
                                                                     %C'*8*
Can se MA1ER1AL S e FETY DATA SHEET i l' in
                                                                                                                                       #uiiA . oe o Ai<is
       ,          RA W M 05865                              Owentree 202 493J616               - Y .unt i l ar                            e a si c .i es niini, 24 Hour smergencylatesdione 90E859 2151  NOf u CHEMTREC. CAWIIC and Nasonal Response fJerder emergency numbers are te be s e4 sinty in        ,
Neuonal Response Center 800 4244002      see event of chenkal ernersendes bivoMns a snitt lid, are, espesse er anident invoMwn ctiemkals Champec 500 424-9300 AR non<energency ;_ '' -s shosed tie directed to festemet Servtce (14001TRAKE R) for esdstance, A0446 -10                                                    Acetone                                                            Page: 2                     l 07/12/95 Erfootive                                                                                                        Issued: 24/ /01 l
PRECAUTIONARY IABELING (00NTINUED)
International' Labeling Ilighly flammable.
Keep container in a well-ventilated place. Keep away from sources of ignition
     - No smoking. Do not breathe vapor.'Take precautionary measures against static discharges.
s i SAF-T-DATA
* Storage Color Code Red (flammable)
SECTION II - 00MPONENTS Component                                                CAS No.-               Weight %              OSIIA/PEL             ACGIII/TLV Acetone                                                  67-04-1                99-100                1000 ppm              750 ppm SECTION III - PIIYSICAL DATA Boiling Point: 50*C (132*F)                                                   Vapor Pressure (mmlig): 184 (at 760 mm lig)                                                                         (20*0)
Malting Points -95*C (-139'F)                                        '
Vapor Density (airmi): 2.0
      . (at 760 mm lig)
Spoo10io Gravity: 0.79                                            ,' '       Evaporation Rate: 14.4
(!!20=1)                                                      -
(Butyl Acetate = 1)
Solub111ty(ll2 0): Complete (100%)                                      ,
                                                                                  % Volatiles by Volume                          100 (21*C) pil: N/A Odor Threshold (ppm): 100                                                  Physical State: Liquid Coefficient Water / Oil Distribution: N/A_                             ,
Appearance & Odor: Clear, colorless liquid. Sweet odor.
C A0fe 55 3 REV 0 Continued on Pages                  3

PAGE 984    81/24/ %            11186t43        FAX IDI 98886381-984D9AAC-88881139                              (SDURCEt BKRFACTS) 1                                          **"''"P*'**'"C'"***
CANUTICitSM64446 MAlERIAl SAFETY DATA SHEET l.T. Baker amamarmosadwe     edes 6v.
outddeU.L and Canade                i h a ti                                  iit u As (): I>M us 222 9 5 5diod Lane f Ptiplipstasp,HJ08865                         O'*"8'*C 807d83-7818                t L'''M i ilout                              og si (,oint>Ao 244 tour smargency TWaphone 908-859 21$1  Nof fs CHDEI R(C CANyltC and Nanonal Response Center emergency numben are to be . sed o3fn He50nal Response Center 800424-8802       e.e event of chesnkel emergendes twoh4nn a spWL teak, Art, amposure or accident Inve4+g diesmkals Oterrdrec 300 424M00                      AM non4mergency aguestlons should tse directee to Castomer Servtce (l.aonl1 BAkt gr) for asshtance.,
A0446 -10                                                     Acetone                                                              Pages 3 Effective:         07/12/95                                                                                     Issued: 24/ /01 c.............................................................................
SFATION IV - FIRE AND EXPIDSION HAZARD DATA                                                                                         '
Plash Point (closed Cup): -18'O (-2*F)                                           NFPA 704M Rating: 1-3-0 Autoignition Temperature                      464*C (869'F)
Planunable Limits:                 Upper - 13.0 %                    Lower -         2.2 %                                                                  ,
Fire ExtinguishinD Media Use alcohol roam, dry chemical or carbon dioxide. (Water may be  '
i ineffective.)
Special Fire-Pighting Procedures Firefighters should wear proper protective equipment and self-contained breathing apparatus with full facepiece operated in posfLive pressure Use mode. Hove containers from fire area if it can be done without risk.
water to keep fire-exposed containers cool.
Unusual Fire 8, Explosion Hazards Vapors may flow along surfaces to distant ignitionContact                                 sourceswith     andstrong
: f. lash back.
Closed containers exposed to heat may explode.
oxidizers may cause fire. 'Ihis material may produce a floating fire hazard.
Toxic Gases Produced carbon monoxide, carbon dioxide Explosion Data-Sensitivity to Mechanical Impact None identified.
Explot. ion Data-Sensitivity to Static Discharge Y9s.
SPETION V - HEAL'DI HAZARD DATA
  'ntroshold Limit Value (TLV/'IWA):                          1780 mg/m'             (750 ppm)
Short-Term Exposure Limit (STEL): 2400 sng /m'                                     (1000 ppm)
Permissible Exposure Limit (PEL)                           2380 mg/m'              (1000 ppm)
Toxicity of cortponents 1
                                                                         !                                                    5000 mg/kg Oral Rat LD 50 for Acetone l
C A0455 3 REV O Continued on Page                   4                            P A 6E 2f

PAGE 985          B1/24/96           11tB7248         FAX ID: 88886381484D9AAC-88881139                               (SOUltCEf Bl(RFACTS)
J
                         .T.
masB,aker eru na w as,s.ss,c.                    " y' M64'T*8*
CMEC m
MATElllAL SAI ElY DAT A SliEET 222 Gas het w                                  outdde U.L and Canada              I 8mI
  \                    thBupdhurg,Nj ese65 244 tour Emergerncy Telephone 908459 2151 Overrerec 2024t>2414              ?.t m At 1 t im q snum,tn onios g y 1.g cts;;so Ao Nedonst hosponse Carster 800-4244ft02          NoTD OtDEIREC CANtDEC and Nagenal Response Center emergency nurebers are t O cerverec 800-424-P300                       eie event of cfienecat emerecewies hwelvkin a esat less, are, ware er a<rldent ke:"ce diesska r
An nion<musa quest)oris   showd tse dhetted to Castormer Service (l 80441sAkt fr) for assistarice.
A0446 -10                                                              Acetone Effective                07/12/95                                                                        ''                             Page: 4 1ssued: 24/             /03 o.............................................................................
SECTION V - HEAL'
     . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Ill IIAZARD DATA (CONTI NUED )
Oral House LDSO for A stone Intraperitoneal House LD 3000 mg/kg SO for A et no                                                                 1297 mg/kg Skin Rabbit LD50 f r A etone 20         g/kg Carcinogenicity:                      NTP: No              IARC: No                   Z List: No           OS!!A Reg No Garcinonenioity None identified.                                                          .
Reproductive Errects None identified.
Effects or Overexposure INilALATION:                     irritation or nose and throat, headache, nausea, vomiting, dizziness, naroosis, respiratory failure, low blood pressure, contral nervous system depression, coma SKIN CONTACT:                     irritation, prolonged contact may cause dermatitis EYE CONTAUrs severo irritation, may cause ternporary corneal damago SKIN ABSORPFION: may ocour INGESTION:                       headache, nausea, vomiting irritation, central nervous, dizziness,              system depression,  gastrointestinal unconsciousness CilRONIO tw1TDIS: kidney damago, liver damage Tnenet Organs respiratory system, lungs, eyes, skin, central nervous system Hadical Conditions Generally Aparavated by Fwposure chronic respiratory disease, skin disorders, eye disorders Primary Routes of Entry inhalation, ingestion, eye contact, skin contact I
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C A0f 55 3 REV 0 t
Continued on Page:                   5 PASE 2$
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  , PAGE 986           B1/24/96           11198:33          FAX IDI 98886301-984D9AAC-90881139                                      (SOURCE! BERFACTS)
                       }.T. taker                                     M,bWel"uya                            MATERfAL SAFETY DAT A SHEET 22                                              outddeU.5 andCanada                 I h 814
       .           r amelood   .. m ==s .                             S'"**>='"~                           = ^" "om
                                                                                                                                                        #nute,fn fiAi(L m===
24-Hour linerpency Teleptone 908-839 2131 Ns5 anal Response Center 900-4248802           NOff> Of(MIREC, CANLfif C and NaWenaf Aesponse Centet emergency numbers are le Overrtrec 800 424-9300                         ese event of deemdcal ernersendes Irevolviria e spl3 leatr, fire, exposure er eccedent hvoMne deemicalt AA no.<mte n wy quesuons decend be directed to Ca.tomer senece (14000sAMa) fee esslstance.
A0446 -10                                                                Acetorie 6
Effective:              07/12/95                                       /                                                                         Pages 5                 l Issued: 24/ /01                            1
     .............................................e.................................
SECTION V - HEAL'Ill !!AZARD DATA
     . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .(.............................
CONTI NUED )
Emergency and First Aid Procedures INGESTIOiv:                 CALL A PIIYSICIAN.                    If swallowed, do)NOT induce vomiting. If conscious, give large amounts of: water.
INHALATION:                 If inhaled, remove to fresh air.                                  If not breathing, give artificial respiration.
oxygen. Prompt action'is essential.
If breathing           is difficu1*.,, give SKIN OONTACT: In case of contact, flush skin with water.
EYE CONTACT:                 In case of eye contact, immediate1 r flush with plenty of water for at least 15 minutes.
Notes to Physician Any material aspirated during vomiting may cause lung injury. Therefore, emesis should not be induced mechanically or pharmacological 1y. If it is considered necessary to evacuate the somach contents, this should be done by means least likely to cause aspiration (e.g. , gastrio lavage after endotracheal intubation).
SARA / TITLE III !!AZARD CATEGORIES and LISTS Acute: Yes Chronic: Yes Flammabi]ity: Yes Pressures No Reactivity: No Extremely llazardous Substance: No CERCLA Hazardous Substanoe                                    Yes Contains Acetone (RQ = 5000 LBS)
SARA 313 Toxio Chemicals:                                     No Generio Class:                                              Generjo Class Removed from CFR:                                     7/1/91 TSCA Inventory:                                               Yes ca............................................................................
SECTION V]            -
REACTIVITY DATA Stability: Stablo                                                       llazardous Polymerization: Will not occur Conditions to Avoids                            heat, flame, other sources of ignition f
i Incompatibles                                   strong oxidizing agents, strong bases, halogen acids                                                                      j and halogen compounds, caustics, amines and alnmonia,                                                                     ;
chlorine and ohlorine compounds, strong acids, esp.                                                                       l sulfurio, nitrio, hydrochlorio                                                                                            i i
CA0 tis 53 REV0 Continued on Page:                      O P A GE 27
                                                                                                                                                                              \l
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,     PAGE 887   81/24/ %         11:09:34         FAX ID: 8888f>381-B84D9AAC-88881139                                (SOURCE: BERFACTS)
                                                          * * * * " '"* h C*a*8*
1.T. Caker A DEJaneradeshc4W:4,4,5 6 c 272 had Schooltwee N"6{*M66 outdde U.L .W Canada MATERfAL SAFETY DATA SHEET i n 'll tim A'. of li Alos   I flS W g M DS$65                          Oiervaroc P07483-7416                 bit.rJ At I lif at si                     1:1 r. (usin9An   l 24-Hour Imwpency Telephone 908-859 7153  NoTO oHIMTP.lC. CANUIEC arid Nasonal Besponse Centes emergency numbers are to be sesed oeer en Naconal Resporse Center 800424 8802      the event ef theanical ernereendes hvveMns e eget lean, Arc esponsre or acodent hvoMng ca.emirais i O>emtrec 8004744100                      As non<mergency spuestlens should be dkarted to Custoseer Service (1400lTBAKIer) fo, eaststence.
A044B -10                                                 Aootone                                                             Page: 0                I Effective       07/12/95                                                                                       Issued: 24/ /01 SECTION VI - REACTIVITY DATA (OO!GINUED)                                                                                !
Decomposition Products: carbon monoxide, carbon dioxide                                                                                               l e.............................................................................
SECTION VII - SPILL 8, DISPOSAL PROCEDURES Steps to be Taken in the Event of a Spill or Discharge                                                                                                l Wear suitable protective clothing. '' Shut off ignition sources; no flares,                                                                     I smoking, or flames in area. Stop leak if you can do so without risk.                                                            Use water spray to reduce vapors. Take up with sand or other non-combustible absorbent material and place into container for later disposal. Plush area with water.
1 R
J. T. Beher SOLUSORB                   se,1 vent adsorbent is recommended for spills of this product.                                                                                                                                              1 Disposal Procedure Dispoce in aooordance with all applicable federal, state, and local environmental regulations.
EPA }!azardous Waste Number:                          UOO2 (Toxic Waste) a.............................................................................                                                                        !
SECTION VIII - INDUSTRIAL PRO 7ECTIVE EQUIPMENT Ventilation:                            Use general or local exhaust ventilation to meet TIN requirements.
Respiratory IYotection: Respiratory protection required if airborne conoontration exceeds TLV. At concentrations up to 5000 ppm, a chemical cartridge respirator with organic vapor cartridge is recommended. Above this level, a self-contained breathing apparatus is recommended.
Eye / Skin Protection:                  Safety goggles, butyl rubber gloves are recommended.
Continued on Page:                  7 C A0 tis 5 3 REV 0 P AG E 2B

PAGE BBB     B1/24/%           11:18:31          PAX IDI BBBB6381-96(D9AAC-08881139                              (SOURCE: BERPACTS)                       i
   ~
1 c"a"*a*fm""*
ncs       Mass C"s***        MATERIAL SAFETY DATA SHEET                                     i 2.T. Baker mwar,+.,a.w         ee.                                                                                                                    ;
I               222 Sed Schoolsane                          outilde U.L and Cwnede Gen @ec W S M (16 i U t 11 WrW f it&4f
                                                                                                                                   .      t n a te. 01 ( A1 os
                                                                                                                                             .of si costinAn I
g    ,      f Plealipstarg,NJ06865 1              244 tour trnerpencylelephone 908 459-2151   .N._Olg OtDdIRK, CANVIEC and NeWonal Response Center emergency numisers are as t e assed enry an Nanonal ResponseCenter 800424 8802          ew event of deemkal emergendes bwelvbs a spilt, Italy are, emposure or ocddent hvoMng themicars. l O.Wrec 800-424 9300                         Am non<mergency epsesuons shotAd tie dkected to Csstemer 5erstce (t40c416AKE tr) for assistance.
  / A0446 -10                                                         Acetone                                                           Page: 7 Effective          07/12/05                                                                                      Issued: 24/ /01 SBCTION IX - STORAGB AND llANDLING PRECAUTIONS                                                                                    !
SAF-T-DATA
* Storage Color Code: Red (flammable)
Storage Requirements Keep container tightly closed. Store iin a cool, dry, well-ventilated, flammable liquid storage area. Isolate from incompatible materials.
tpecial Precautions                                                                                                                                      1 Bond and ground containers when trans, ferring liquid.                                                                                              1 l
I SECTION X . TRANSPORTATION DATA AND ADDITIONAL INFORMATION Domectio (D.O.T.-)
Proper Shipping Name:                   Acetono llazard Class:                           3                                 .
UN/NA: UN1090                Reportable Quantity: 5000 LBS.                                Packaging Groups II Labels: 3 FLAMMABLE LIQUID Regulatory 

==References:==
49CPR 172.101 International (I.M.O.)
Proper Shipping Name                     Acetono llazard Class:                           3.1                                                1.M.O. Page 3102 UN: UNIO 90                  Marine Pollutants: No                                         Packaging Group: II Labels: 3 FLAMMABLE LIQUID                                                                                                                              ;
Regulatory 

==References:==
49CPR PART 176; IMDG Code AIR (I.O.A.O.)
Proper Shipping Name                     Aootone llazard Class:                           3 UN: UN1090                                                                                  Paokaging Group: II Labels: 3 FLAMMABLE LIQUID Regulatory 

==References:==
49CPR PART 175; ICAO=== We believe the transportation data and referenoes contained herein to be factual and the opinion of qualified experts. The data is meant as a guide to the overall classification of the product and is not package size speoirio, nor should it be taken as a warranty or representation for which the company assumes legal responsibility.=== The information is offered solely for your consideration, investigation, and verification. Any use of the information must be determined by the user to be in accordance with applicable Federal, State, and Local laws and regulations. See shipper requirements 49CFR CA04 55 3 REV O Continued on Page                  8 P A GE 21

    , PACE B09         91/24/ %          11:11:33        FAX IDI B8886381-884D9AAC-8BBB1139                        (SOURCE: BERFACTS)
(T. Baker                                Maggy                            MATERIAL SAFETY DATA SHEE O,b               22 24 Hour 5 3diog Hjo8843
                       %,nerpencylefert.one          900 559 National Response Center 8004244802 Overrerec 800424 9300 otAside U.5.and Canade Oventrec 2024st-7t ts 215g I U lH
_ w ;imi e iunit                      e e' >> As t u imi os ser sir,inniini,
_NOf f CNTMTRIC. CANT 1IIC aruf Natlanal Redrantie, C,silare.margency susmtiers a
                                                               #se event of diesakelemereendedwelvins a soet leak, are, e-r-+=e or ac<ldent InveMne (titak A0448 -10                                            As sioneaneri,u.c, esm,,s e odd be directed to cwtoener Service (14004TSAKER) for assutanc Acetone Effective           07/12/9S                                                                                             Page: 0 Issued: 24/ /01 SECTION X - TRANSPORTATION DATA AND
         ........................................ ADDITIONAL......................................
INFORMATION (CONTINUED) 171.2, Certification 172.204, and employee training CFR 173.1(b).                                                                            49 U.S. Customs llarmonization Number: 29141100008 NOTE:
used for  When       handling liquid products, secondary protective containers must be carrying.
         -N/A = Not Applicable, or not Available; N/E = Not Established.-
The information in this Material Safety Data Sheet meets the requirsments of the United States 000UPATIONAL SAFETY AND HEAL'n! ACT and regulations promulgated thereunder (29 CPR 1910.1200 et. seq.) and t.he Canadian WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM.                                            This document is intended only as a guide to the appropriate precautionary handling of thechemical in,   material by          a person trained in, or supervised by a person trained handling.            The user is responsible for determining the precautions cpplication.        and      dangers         of this chemical for his or her particular Depending on usage, protective clothing including eye and fsee guards and respirators must be-used to avoid contact with material er breathing chemical vapors / fumes.
Exposure to this product stay have serious adverse health effects. This chemical may interact with other substances. Since the potential uses cre so varied, Baker cannot warn of all of the potential dangers of uso cr interaction with other chemloals or materials. Baker warrants that the chemical meets the specifications set forth on the label.
BAKER DISCLAIMS ANY UHIER WARRANTIES, EXPRESSED OR IMPLIED WITl! REGARD
       'ID 'IHB PRODUOT SUPPLIED HEREUNDER, ITS HEROllANTABILITY OR ITS FITNESS FOR A PARTICULAR PURPOSE.
The user should recognize that this product can cause severe injury and even cre   notdeath, heeded. especially if improperly handled or the known dangers of use READ ALL PRECAUTIONARY INFORMATION. As new documented general      safety      informat, revise this Material Safety               ionData becomesSheet. available, Baker will periodically Note: Cl!EMPREC, CANUIEC, and NATIONAL RESPONSE CENIER emergency telephone nutabers are to be used ONLY in the event of CIIFifICAL EMERGENCIES involving o spill, leak, fire, exposure,                      or aooident involving chemicals. All non-emergency questions should be directed to Customer Service (f-800-JrBAKER) for assistanoe. -
lf I '
OOPYRIGiff 1995 Mallinokrodt Baker, Inc. -
      *a..TRADEMARKS OF Mallinokrodt Baker, Inot Approved by Quality Assurance Department.' '
LAST PAGB            --                                C A0f;55 3 REV 0
                                                                          .    .                                         P A G E 30

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                                                                                                                            ,,seg                                    tt     Come et Feeerei n M*$*"***eU*,'g*,'e7,"""                                                                           6.5     spaces senaeres of Comnuemen                         Fiammeen home nomy ins neem one ==.m seners agences                                                                       presusia: um p.mwn                       itJ has nsaars noeng ser smk weer sJ      sene.e., si Fwe: nos pennens                         Traneperiessem s.7 Iydeen Tempereewe sesy                                          Canegory                    neem 0 l@':'2'      o::4,,e.me,                                                         u                                                            Pa-e m onsee.,n,.asse, eres 8
v-                                                                               u      E.msensei i n u         heaere n,        osse L orme o -em Enansweh,een       av eheauca.                                                    a te Aessene Pieme Temperenn,                                   vapor enione ..
we= me ne meneceve         en be acenes hem er certen same.                                 e,,,,,,,,,,,,,
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                                                                                                                  &12 Pieme Temperehme Det noi evelette                           Mumen Tomcey .                      t  i Aasenc fosacey -                    t Aeemete Enoct .                     1 CALL FOR hsEDICAL AfD                                                                        F. CHEMICAL REACTMTT                              neece.iy V
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Move is emen se                                                                             *secean                                                              "
e treesheng hee stopped. pwe WhhCGI 8eepWeten                                                                                        'J       FPA N**8#'
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                                                                                                                  ?A meesmeny aroup:to 11 PHY$1 CAL AND CHEMICAL PROPERTIES Dongenia le semes me m han eencoreasons                                                                                            12 i Phyear.ai siese et is C ene 1 ese                '
Water                '"'**""'"***'*""*"*""                                                                                                                           L.,d
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                                                                                                                                                                              **"""v"."'s'e"t         C "ne rn 12.4      Preesang Point
: 1. RESP 0lltt 70 DISCHARGE                           1 LA&(L                                               8 FRATER POLLUTI0li
* raa mene==e ame== neie==>                           u Case-r Fiammen. a es                         a1 A             Teamar                                         assy . r3s C - ace x sense memsneaugh                                 SJ Class 3                                      14.250 ppm /24 er/eunhah/ base / tap weier                 Crescal preneure Deperse arup tuon                                                                                                                                  13.8 e..                                                                                                             13.000 ppm /48 he/moegste hoh/TL.1 terted                      $62 pee - 46 4 som . 4 70 MN/m' seier                                   13.7 specme Orewey-8.3 weiereses Tomcar ha' porta *at l
0 785 si 20 C dhausdl                     ,
0.3 Bostoteam Deypen Demand (800)                  13.s bowd surtsee Teno6en Nos perenani               I efhoorp 122%. S esyn                    11.0     Deuhe tener intertamel feneem 1 CN(MICAL DESIGliATIONS                                                                       to Feed Chett Cancentesen Potentok                              Nm pertnene
                                                                       & DestavaSL1 CHAAACTIRISTICS                        None amed                                it te vapor (Ges) spwans Orever 3 a at ce Campaansey Ceems aesons                             4.1 Physica sieu see shapest Loss                                                                                                                       ,
lit 1 neue et speems niete er vapor tosek            j SJ Forsaute CNe00 cme                                     4J Ceder Colorises                                                                                             1 iff SJ usO/UN Deelenstem 3 tit 000                            4.3 Oser Saeenset pseeeent semeneeng ihan 8.4 00710 fee 1000                                                                                                                                          et 13 Latent Meet of W-er aus or but pungent anste.
        $4 CAS nocheery he. t?4.e.1                                                                                                                                              220 Oms /m a 122 cm/s =
pereerseng esenker, hemoruc. passeens.                                                                 611 I to' J/kg non.,eegal 11.18 Heat of Comtuonom -12.250 Sts4
                                                                                                                                                                                  . -Geos cal /g e -265 0 X 108 J/kg 12 14 Heel ef " .                    8 ens perimiens 5, N(ALTH HA2ARDS                                                       9.                                      11is Mees es m w w 5 HIPPING INFORMATION L1 Peresnel preteneve Eg4msnt Dgens vapor conster e ereuppeed mesa. synmen heter                                                                            12 10 Heat of r_                    seat pennere
: 3. t Greasse of Purer Technmal 09 8% phs stause. shonoce asesey goggles er tore esteeh thold                                                                                                13 to Meet et Puesem 23 a2 cm/g 95% weier meegent at 5% peue Ol%         igJe Lamseng venus; Dois not evesene SJ Symptome Peasemp Empeare DeHALATIOtt veper entseg e eyee arm awcous menerense,                                  seter acts as en ansemene m very mgh __                                                                                                                  13.gy nees Wapw Pressure F 25 pee                     )
_ esoasTicse m.eres er gescay ha eery          eJ snarageimapersawe Aneens ente 8ne e ausseus membrensa ense presonged escomene sonneci cease estestmg es se som,          tJ iner Aemosphere: No engsement goeshhp @ ie eermeseE 9.4 Wentig Open (fisme erresser) e SJ Treatment of Espeope BetALATIDft # uscue e owweeme, sensve to teen er and ese e prA ednungster WMasi pesapeten f breeseg a ereyder er esopped #80ESTICM d sk:me hee emeessed large emewee end e esmaasus and net hemg :                     subc0 genutnB *'8 poi modeel hop pronger: ne spaces medste kneart SKee seen mes em weier fyE& tush om sees mamsesemy tur a tenet 15 non Canam o phyenert 4.4 11eremueld L44R Valet FSO ppm 84 Dort verse bleshmen Lases 1000 ppm est 30 nort La Temony by bigesame Grees t L0es . S to tp g/he y u L e T. mar =m per r.
6J Vapor lesel errtent -1_            _ ___ W presord m mgh concerestone, esport cause moderate enlegen ei Ste eges er vespechwy ayatom. Efesel e tempersy                                                                                         I Et Dones er Seed broent *^_                 ' ' _ No _. .       hasy6 Prececeay hemises se We ehm h- t a very sessene ami suegeresse eacMy true me ska ste Deer TIweenste 100 ppm
        &lt IDUI Vehse 20000 ppm                                                                                    !
C A0IiS 5 3 REV 0 PAGE                    ff JUNE 1985

18 ABC250 ACETOMETHOXANE (approx), mp: -7*, bp: 145-146* decomp. Misc in water,         PHTHALENR)ETHANoNE D a NAPHTHYL METHYL KETONE D 1-alc, and eth.                                                  NAPHTHE METHE KETONE SYNS: HYDRoXYACETONE D l HYDROXY 2 PROPANONE                   TOXICITY DATA WITH REFERENCE skn-rbt 500 mg/24H MLD FCToD7 20.755,82 TOXICITY DATA w!m REFERENCE                                    ort rat LD50:1560 mg/kg rcTOD7 20,755,82 mmo-sat 500 pg/ plate ABCilA6 47,2461.83 ort rat LD50:2200 mg/kg JIHTAB 30.63,48                        CONSENSUS REPORTS: Reported in EPA TSCA Inventory, CONSENSUS REPORTS: Reported in EPA TSCA Inventory.                                                     DOT CLASSIFICATION: 3; Label: Flammable Liquid SAFETY PROFILE: Moderately toxic by ingestion. Muta.           SAFETY PROFILE: Moderately toxic by ingestion. A skin irritant. A combustible liquid. When heated to decom-tion data reported. An allergen. Implicated in aplastic anemia. A 10 gram dose may be fatal to an adult. Skin          position it emits acrid smoke and irritating fumes.
contact, inhalation, or ingestion can cause asthma, sneezing, irritation of eyes and nose, hives, and eczema.      ABC500                 CAS:93-08-3                  HR: 2 Combustible when exposed to heat or flame. When                2'-ACETONAPHTHONE heated to decomposition it emits acrid smoke and               mf: CuH,,0          mw: 170.22                               .
fumes.
PROP: White needles; orange blossom odor. Flash p:
264
* F. Mp: 56*, bp: 301-303*. Sol in fixed oils; sitly sol ABC250                   CAS:828-00-2               HR: 2      in propylene glycol; insol in glycerin.
ACETOMETHOXANE SYNS: p-ACETOMAPHTHALENE O ACHONAPHTHONE O S-ACE-mf: C.H, O.          mw: 174.22 TONAPHTHONE O 2-ACEToNAPHTHoNE D S-ACETYLNAPHTHAL.
PROP: Yellow to amber, clear liquid. D: 1.068-1.075 @          ENE O 2-ACETENAPHTHALENE D FEMA No,2723 O METHYL S.
25*/25*, bp: 66-68* @ 3 mm, fp: <-25*, Sol in water            NAPHTHE KETONE (FCC) O METHE-2-NAPHTHE KETONE O p.
and org solvs. Misc in water.                                  METHE NAPHTHE KETONE D 1-(2 NAPHTHALENn)ETHANONE O S NAPHTHYL METHYL KETONE O 2 NAPHTHYL METHYL KETONE O              i SYNS: ACEUC ACID-2,6-DIMEmn m-DIOXAN-4 YL ESTER O ACE-         ORANGE CRYSTALS                                                    )
ToMETHOXAN O 6 ACETOXY 2.4 DIMETHE m DIOXANE O DDOA                                                                               l O DIMETHOXANE O 2.6-DIMETHE-m DIOXAN40L ACETATE O 2            TOXICITY DATA wiTH REFERENCE 6-DIMETHR m-DIOXAN4R ACETATE D DIOXIN (bactericide)            ska hmn 100% FCTXAV 13,867,75 (OBs.) O GIV GARD DXN O NCI-c56213                             orl-mus LD50:599 mg/kg MDZEAK 8,244,67 TOXICITY DATA wim REFERENCE                                    CONSENSUS REPORTS: Reported in EPA TSCA mma sat 5500 pg/ plate ENMUDM 8(suppl 7),1,86                  Inventory.
sin-dmg-par 1 pph ENMUDM 7,677,85                              DOT CLASSIFICATION: 3; Label: Flammable Liquid ort rat TDLo:948 g/kg/88W 1: CAR JNCIAM 53,791,74 ori mus TD:25,750 mg/kg/2Y C: ETA NTPTR* NTP TR-               SAFETY PROFILE: Moderately toxic by ingestion. A 354,89                                                     human skin irritant. Flammable liquid. When heated to orl-rat LD50:1930 mg/kg Gi:TB~ 3/25/77                         decomposition it emits acrid smoke and fumes.
orl mus LDLo:2800 mg/kg NTPTR* NTP-TR-354,89 CONSENSUS REPORTS: 1 ARC Cancer Review: Group 3                ABC750                 CAS:67-641                   HR: 3 1MEMDT 7,56,87; Animal Limited Evidence IMEMDT                 ACETONE                                                      ,
15,177,77. .NTP Carcinogenesis Studies (gavage):              DOT: UN 1090/UN 1091 Equivocal Evidence: MOUSE NTPTR' NTP TR 354,89;                mf: C,H.O          mw: 58.09 (gavage): No Evidence: RAT NTPTR' NTP TR 354,89.
PROP: Volatile, colorless liquid; fragrant mint like odor.
SAFETY PROFILE: Questionable carcinogen with ex.               Mp:-94.6*, bp: 56.2* @ 20 mm, reft index: 1.356, flash perimental carcinogenic data. Moderately toxic by in.          p: 0*F (CC), tel: 2.6%, uel: 12.8%, d: 0.7972 @ 15*,
gestion. Mutation data reported. See also ESTERS. When        autolgn temp: (color) 869'F, vap press: 240 hPa @ 20*,
heated to decomposition it emits acrid smoke and              vap d: 2.00. Misc in water, alc, Org solvs, and eth.           l fumes.                                                         SYNS: ACETON (GERMAN, DUTCH. Polish) O ACETONE O!!S (dot) O CHEVRON ACETONE D DIMETHRFORMALDEHYDE D DI-MEmnmAL O MMEmn mONE O FEMA No 3326 0 mONE, ABC475                   CAS:94198-0                HR: 2      mMEmn D m NE PROPANE O p KEwR PANE O MEmn 1'-ACETONAPHTHONE                                             m NE D PR PAN NE O 2 PR PAN NE O nR ACEUC ACm mf: C,aH,,O          mw: 170.22                               O WROACETIC ETHER O RCRA WASTE NUMBER U002
: Crystals. Mp: 34*, bp: 302*, flash p: >230*F, d: ' TOXICITY DATA wrTH REFERENCE eye-hmn 500 ppm JIHTAB 25,282.43                               i SYNS: 1 ACETONAPHmALENE O o-ACEToNAPHTHoNE O 1-ACE.            skn rbt 395 mg open MLD UCDs" 5n/70                            l ToNAPHTHONE O 1 ACETRNAPHTHALENE D ETHANoNE.1-(1 NA.           skn-rbt 500 mg/24H MLD 28ZPAX ,42,72 PHULALENR)-(9CI) O METHE a-NAPHTHE KETONE O METHYL 1-          eyC*rbt 3950 pg SEV NOPAA 29,1363,46 NAPHTHE KETONE D a MEmn NAPHmn KETONE D 1-(1-NA-               eye-rbt 20 mg/24H MOD 85JCAE ,280,86 C A0455 3 REVI PARF 3I               l

ACETONE PEROXfDE ABE000 19 HERLAY 33.457.47                 For occupational chemical analysis use OSHA: #1D 69 cyt sme 200 mmol/ tube sin sme 47,600 ppm ANYAM 407.186,83                          or NIOSH: KETONES I (desorption in CS,) 1300.               A lhl mam TClo:31,500 pg/m'/24H (113D preg): REP
               #'                                                    ABD000                 CAS:5715-8                  HR: 3 TD 2857 mg/kg 34ZIAG ,64,69             ,
i
                                                          /          ACETONE CHLOROFORM                                            i TDLo:2857 mg/kg DIAEAZ 15,810,66                                        mw: 177,46                               l 1                                                       mf: C.H,Cl,O i 1 man TCLo:12,000 ppm /4H:CNS AoHYA316,73,73 lhl man TDio:440 pg/m'/6M GlsAAA 42(8)42,7                   PROP: Hydrated crystals, camphor odor. Mp: 97* (78*
ihl man TDLo:10 mg/m'/6H otsAAA 42(8)42,77                   anhyd), bp: 167*.
thl hmn TClo:500 ppm: EYE JtHTAB 25,282,43 SYNS: ANHYDROUS CHLoRoBUTANot O CHLoRBUTANoL 0 iht. man TCLo:12,000 ppm /4H: GIT AoHYA3 16.73,73 CHLoRDUTot O cHloREToNE D CHLoRoBUTANot DCloR-ivn rat LD50:5500 mg/kg NPIRl* 1,1,74 TRAN O HCP O METHAFoRM O sEDAFORM O TRICHLoRo-tert-BU-ort rat LD50:5800 mg/kg JTEHD615,609,85 TE ALCOHOL O tert TRICHLoRoBUTR A14oHot O $.$.$ TRI-ihl rat LC50:50,100 mg/m'/8H A!HAAP 20,364,59                  H       emBM A@HM O 1,1,1MHN2METHW2-Ipr rat LDLo:500 mg/kg JPPMAB 11,150,59 ivn rat LD50.5500 mg/kg NPIR1* 1,1,74 orl mus LD50:3000 mg/kg PCJoAU 14,162,80                     TOXICITY DATA WITH REFERENCE thl mus LClo:110 g/m'/1H AGGHAR $,1,33                       skn rbt 850 pg MLD xEURAQ MDDC 1715 Apr.mus LD50:1297 mg/kg secuR* ,1,61                         eye.rbt 9180 pg/30S MLD xEURAQ MDDc 1715 Ivn mus LDLo:4 g/kg FAoNAU 48A,86,70                         mmo-sat 20 pmol / plate MUREAV 90,91.81 ort-dog LDLo:8 g/kg FAoNAU 48A,86,70                         cyt smc 10 mmol/ tube HEREAY 33,457,47 ort rbt LD50:5340 mg/kg FAoNAU 48A,86.70                     or}. dog LDLo:238 mg/kg AIPTAK 8,U,01 skn rbt LD50:20 g/kg UcDsa snn0                              ort rbt LDLo:213 mg/kg AIPTAK'8,U,01 par frg LDLo:800 mg/kg AIPTA1; 8,U,01 CONSENSUS REPORTS: On Community Right To-CONSENSUS REPORTS: Reported in EPA TSCA Know List. Reported in EPA TSCA Inventory.
OSHA PEL: TWA 750 ppm; STEL 1000 ppm                        SAFETY PROFILE: Poison by ingestion. A narcotic. A
                                                                                                                               ~
ACGlH TLV: TWA 750 ppm; STEL 1000 ppm                       skin and eye irritant. Mutation data reported. See also       ,
DFG MAK: 500 ppm (1200 mg/m')                               CHLORAL HYDRATE, which acts similarly. Dangerous;             l NIOSH REL: (Ketones) 10H TWA 590 mg/m'                      can react with oxidizing materials. Combustible when          !
I    DOT CLASSlFICATION: 3; Label: Flammable Liquid              exposed to heat or flame. When heated to decomposi-tion it emits toxic fumes of Cl'. See also PHOSGENE.
SAFETY PROFILE: Moderately toxic by various routes. A skin and severe eye irritant. Human systemic effects by     ABD500                  CAS:115-24-2 HR: 3 inhalation: changes in EEG, changes in carbohydrate         ACETONE DIETHYLSULFONE metabolism, nasal effects, conjunctiva irritation, respira-                       mw: 228.35 tory system effects, nausea and vomiting, and muscle         mf: C'H aOa Sa                      ~
weakness. Human systemic effects by ingestion: coma.         PROP: Crystals. D: 1.183, mp: 124-126*, bp: 300' (sitly kidney damage, and metabolic changes. Narcotic in            decomp). Sol in water, alc, and eth, high concentration. In industry, no injurious effects        SYNS: ACETONE Bis (ETHE SULFONE) O 2,2-dis (ETHYLsULFo-have been reported other than skin irritation resulting NYL) PROPANE D DIETHYLsVLFoND1METHYtMETHANE O PROPANE t        from its defatting action, or headache from prolonged DIETHYL SULFONE O sVLFoNAL O sULFoNMETHANE inhalation. Experimental reproductive effects. A com, mon air contaminant, Highly flammable liquid. Danger-       TOXICITY DATA wiTH REFERENCE ous disaster hazard due to fire and explosion hazard; can   unk man LDLo:147 mg/kg 85DcAl 2,73,70 react vigorously with oxidizing materials.                  orl dog LDLo:900 mg/kg HBAMAK 4,1404.35 Potentially explosive reaction with nitric acid +      ort rbt LDLo:3000 mg/kg HBAMAK 4,1404,35 sulfuric acid, bromine trifluoride, nitrosyl chloride +     orl gpg LDLo:8500 mg/kg HBAMAK 4,1404,35                       ,
platinum, nitrosyt perchlorate, chromyl chloride, thiotri-                                                                 l thiazyl perchlorate, and (2,4,6-trichloro 1,3,5 triazine +  SAFETY PROFILE: A human poison by unspecified water). Reacts to form explosive peroxide products with     route. Moderately toxic by ingestion. Mutation data 2-methyl 1,3-butadiene, hydrogen peroxide, and perox.      reported. When heated to decomposition it emits toxic omonosulfuric acid. Ignites on contact with activated      fumes of 50,.
carbon, chromium trioxide, dioxygen difluoride + car-bon dioxide, and potassium tert-butoxide. Reacts vio-                                                         HR: 3 lently with bromoform, chloroform + alkalles, bromine,     ABE000 ACETONE PEROXIDE and sulfur dichloride. Incompatible with CrO, (nitric +
      ,    acetic acid), NOCl, nitryl perchlorate, permonosulfuric     PROP: Liquid or absorbed on cornstarch. The trimeric acid, NaOBr, (sulfuric acid + potassium dichromate),       form is crystalline. Mp: 97*.
l         (thio-diglycol + hydrogen peroxide), trichloromela-mine, alt, HNO,, chloroform, and H,SO.. To fight fire,      SAFETY PROFILE: Severe skin and eye irritant. Flamma-use CO,, dry chemical, alcohol foam. Used in produc-        ble by spontaneous chemical reaction; can react vigor-tion of drugs of abuse.                                     ously with reducing materials. The trimeric form is C A0ll55 3 REV 0 t                                                                                                              P A S E d.(,

CA04553 Rev.0 Page 37 ATTACHMENT B ARCON96 FII ES FOR AUX BLDG ROOF INLET l
1 e                                                             ;
l
                                                               )
i i

s Program

==Title:==
ARCON96, Developed Fort      U.S. Nuclear Regulatory Commissi =
ll                          Office of Nuclear Reactor Regulation.                                                    CA0455 3 REV 0 Division of Reactor Program Management
      . Datas.              June 25, 1997      11:00 a.m.
PA6E 38
                                                                                                                                 }
NRC Contacts        J. Y. Lee         Phone (301) 415 1000 e-mail jyllenrc. gov J. J. Hayes       Phones (301) 415 3167 e-mail jjhenrc. gov L. A Brown        Phone (301) 415 1232 e-mails lab 2enre. gov Code Developer      J. V. Ramsdell Phones (509) 372 6316 e-mail j_ransdellepal. gov Code Documentation         NUREG/CR-6331 Rev. 1 The program was prepared for an agency of the United States Government, Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, expressed or implied, or assumes any legal lid ility or responsibilities for any third party's use, or the results of such usJ. of any portion of this program or represents that its use by such third party would not infringe privately owned rights.
Program Run 8/19/1998 at 13:27:39 eoese** ARCON INPUT **********
Number of Meteorological Data Files         =  3 Meteorological Data File Names CC1991. MET CC1992. MET CC1993. MET H11ght of lower wind instrument (m)         =       10.0 Reight of upper wind instrument (m)         =       60.0 Wind speeds entered as meters /second                                                                                     I 1
Crour.d-level release R31 ease height (m)                         =          .0                                                                 l Building Area (m*2)                         =    1155.0                                                                   '
Effluent vertical' velocity (m/s)-          =          .00 Vent or stack flow -(m*3/s)                 =          .00 Vint or stack radius (m)                    =         2.57                                                                I l
Direction ..' intake to source (deg)        =         174                                                                 l cWind direction sector. width (deg)           =          90 Cind direction window (deg)                 =    129 - 219                                                                ;
Distance to intake (m)                    ~
                                                          =    '300.0                                                                   l Intake height' (m)                          =       15.6 Tsrrain elevation difference (m)            =          .0 Output file names CHWHCR.out CHWHCR.j fd -
Minimum Wind Speed (m/s)                    =          .5 Surface roughness length (m)                =          .10 Sector averaging constant                   =         4.0 Initial value of sigma y                    =         1.19
             . Initial value of sigma :                   .           .00 Expanded output for code testing not selected
            -Total number of hours of data procesred = 26307 Hours of missing data                         ' =      416 Hours direction in window'                      =.~7071 Hours elevated plume w/ dir. in window          =          0 Hours of calm winds                             =      495 Hours direction not in window or calm           =    18325 DISTRIBITTION SUP84ARY DATA BY AVERAGING INTERVAL AVER. pRR.               1           2              4             8       12       24       96      168       360      720 UPPER LIM.        1.00E-03   1.00E-03     1.00E-03         1.00E-03 1.005-03 1.00E-03 1.00E-03 1.00E-03  1.00E-03 1.00E-03 low LIM.       1.00E-07  -1.00E-07     1.00E-07         1.00E-07 1.00E-07 1.005-07 1.00E-07 1.00E-07  1.00E-07 1.00E-07

F ;-
      ~ ABOVE RANGE            O.           O.         O.        O.        O.       O.       O.          O.       O.        O.
20 RANGE         7566.       9072.      10985. 13503     15536. 19375. 24850,      25104. 25169. 24910.
BELON RANGE            0.           O.         O.        O.        c.       C.       C.          O.       O.        O.
EERO       18325.     ~16753,      14722. 11983. 10132,    6209. 355.          O.       D.        O.
70TAL X/Qs       -25891.      25825.      25707. 25486. 25668. 25584. 25205,      25104    15169. 24910.
         % NON EERO         29.22       35.13       42.73     52.98     60.53    75.73    58.59      100.00   100.00    100.00 95th PERCENTILE X/Q VALUES 9.23E-05     9.00E-05   ~8.71E-05  8.15E-05  6.69E-05 4.88E-05 2.91E-05 / 2.488-05  2.21E-05 2.03E-05 95% X/Q for standard averaging intervals 0 to 2 hours-        - 9.23E-05 2 to 8 hours           7.788 05                                                                   CA0455'S REV0 8 to 24 hours          3.24E-05 1 to 4 days            2.26E-05                                                                   PA6E N 4 to 30 days           1.895-05 .
HOURLY VALUE RANGE MAX X/Q               MIN X/Q.
CENTERLINE           1.155-04              1.06E-05 SECTOR-AVERAGE       7.19E-05              6.65E-06 NORMAL PROGRAM COMPLETION I
I I
u ._                                                                                                                           !
: a. 2 o.
CA04553 Rev.0 Page 40 ATTICHMENT C ARCON96 FILES FOR WEST ROAD INLET PLENUM l
l i

e ,+        ,
    . Program Titlei ARCON96.
Developed Fors         U.S. Nuclear Regulatory Cc.amission office of Nuclear Reactor Regulation '                                                                55 3 EV 0
_ Division of Reactor Program Management
   -Datas                   June 25, 1997 < 11:00 a.m.
:):
NRC Contacts: ' J. Y. Lee                    Phones (301) 415 1080
!                                                 e-mail: jyllenrc. gov l                           J. J. Hayes           Phones (301! 415 3167 l                                                 e-mail: j j henre. gov
                          . L. A Brown-Phones (301) 415 1232 e-mail: lab 2enre. gov Code Developer: J. V. Ramsdell Phones (509) 372 6316 e-mails j_ransdellepnl. gov i Code Documentation: NUREG/CR-6331 Rev. 1 The program was prepared for an agency of the United States Government. Neither
   - the thiited States Government nor any agency thereof, no'r any of their
   . esployees,' makes any warranty, expressed or implied, or assumes any legal liability or responsibilities for any third party's use, or the results of such use, cf any portion of this program or represents that its use by such third party would not infringe privately owned rights.
Program Run. 8/19/1998~ at 13:27:56 ee*****      ARCON INPtTT **********
          -Number of Meteorological Data Files                =   '3 Meteorological Data File Names CC1991. MET.
CC1992. MET.
CC1993. MET Height of lower wind instrument (m) =                     10.0 Height of upper wind instrument (m) . =                   60.0
           -Wind speeds entered as meters /second Ground-level release
           'R$ lease height (m)                                =          .0 Building Area (m*2)                .
                                                               =     1155.0 Effluent vertical velocity (m/s)                  =          .00~
sV:nt or stack flow .(m*3/s)'                        .          .00 V:nt or stack radius (m),                         =         2.57-Direction -. intake to source (deg). ~ =                    162 Cind direction sector width (deg)                 =          90 Wind direction window (deg)-                      =     117 --207 Distance to intake (m)-                           =~     262.0 Intake height       (m)' .                        =        '9.1
           ' Tzrrain elevation difference (m)                  =          .0' Output file names CHWHWR.out CHWHWR.jfd
           ' Minimum Wind Speed (m/s)                          =
: s. 5
: Kurface roughness length (m)                       =          .10 Sector averaging constant                         =         4.0
           ; Initial value of sigma yi                     <
                                                               =-       ~1.19.
Initial value of sigma z                           .          .00
            ' Expanded output for code testing not selected '
Total number of hours of data processed = 26307' Hours of missing data                                  =    -416 Hours direction in window                             -    5698
: Nours elevated plume w/ dir. in window                 =          0 Hours of calm winds          -
                                                                    =      495
           . Hours direction not in window or calm .= 19698 DISTRIBUTION 8tNe4ARY DATA BY AVERAGING INTERVAL
         ' AVER. PER.                   1.            2               4            .8'       12        24         96       168       360       720 l s         UPPER LIM.         1.00C 03J 1.00E-03            1.00E 03        1.00E-03  1.003-03  1.00E-03   1.00E-03  1.00E-03  1.00E-03' 1.00E-03 J tow LIM.        1.00E,07.. 1.00E-07        1.00E-07        1.00E-07  1.00E 1.00E-07   1.00E 07- 1.00E-07. 1.00E-07  1.00E-07

          . ABOVE RANGE                0.         'O.           D.       O.       O.       O.       C.        O.        O.        O.
  $                 IN RANGE        6193.       7584.      9475. 12141. 14358    18559,   24524. 25030. 25169. 24910.
KELOW RANGE                0.         -0'         .O.        D.       O.       O.       O.        O.        O.        O.
EERO      19690.      18241,     16232. 13345. 11310. 7025. 681.       14.        O.        O.
TOTAI. X/Qs           25891.      25825. 25707. 25406,   25668. 25584. 25205,   25104. 25169. 24910.
             % NON EERO             23.92      -29.37-     36.86      47.64    55.94    72.54    97.30     99.71    100.00    100.00 a   95th PERCaprTILE X/Q VALUES .
            /                    1.11E-04    1.075-04   1.02E-04   9.37E-05 7.62E-05 5.30E-05 3.02E-05 2.62E-05   2.32E-05  2.08E-05 95% X/Q for standard averaging intervals 0 to 2 hours 2 to 8 hours 1.115-04 8.80E-05 g    g55       EV0 8 to 24 hours
             ~~ 1 to 4 days 3.26E-05 2.26E 05 ggg{
5 M h
4 to 30 days            1.94E-05 HOURLY VALUE RANGE MAX X/Q               MIN X/Q CENTERLINE          1.45E-04              1.465-05 SECTOR #/ERAGE.'    9.09E-05              9.18E-06 NORMAL PROGRAM COMPLETION 1
I i
l i
e

CA04553 Rev.0 ~
         . Page 43 ATTACHMENT D EXCEL SPREADSHERT ACETONE - AUX BLDG ROOF INLET I
                                                           ~

C ACETONE-55-CR                                4553 REV 0 P A GE YY' A                 B         C        D         E           F       G 1  ACETONE 2
3 CHEMICAL                                CH3COCH3 4 IDLH (PPM)                      IDLH         20000 5 ODOR THRESHOLD (PPM)              OT             100 6 STORAGE QTY (GAL)                  Q              55 7 STORAGE PURITY (FRACTION)         QF            1.00 8 SPECIFIC GRAVITY (GM/CC)          SG          0.791                                        1 9 VAPOR PRESSURE (TORR-C-R-K)       VP    4.00E+02         20    527.67    293.15 10 BOILING POINT (C-K-R)              TB           56.2  329.35    592.83 11 MOLECULAR WT (GM/ MOLE)            MB           58.1 12 DIFFUSION COEFF (CM2/SEC)           D               0 13 14   MOLECULAR WT AIR (GM/ MOLE)      MA          28.97 15   MOL EN ATTR/BOLTZ CON AIR (K)  E/KA           78.6 16   (.,HA9 LF_NGTH AIR (A)         SIGA          3.711 17   PRESSURE AIR (ATM-TORR-PSI)      PA               1    760    14.696 18   TEMPERATURE AIR (C-K-R)          TA              30 303.15    545.67 19   MASS DENSITY AIR (GM/CC)      RHOA       1.20E-03                                         l 20   VISCOSITY OF AIR (G/CM-S)        MU      1.83E-04 21 R(TORR-CM3/GMOLE-K)                 R     6.24E+04 22 23   VOL-CR (CF)                   .VCR        234157 24   Q-CR (CFM)                      FCR           8300 25   WIND VELOCIT((CM/SEC)           VW              100 26   MAXIMUM TIME (MIN)             Tmax        42.736   42.736 27  CONTROL ROOM FACTOR             CRF       0.78016           CRF = 1.-exp(-FCR*TmaxWCR) 28 29  LEBAS MOLAL VOLUME 30  C                               14.8              3    44.4 31  H                                3.7              6    22.2 32  O                                7.4              1     7.4 33  O IN METHYL ESTERS & ETHERS      9.1              0       0 34  O IN ETHYL ESTERS & ETHERS       9.9              0       0 35  O IN HIGH2R ESTERS & ETHERS       11              0       0 36  O IN ACIDS                        12              0       0 37  O JOINED TO S, P, N              8.3              0       0 38  N DOUBLE BONDED                 15.6              0       0 39  N IN PRIMARY AMINES             10.5              0       0 40   N IN SECONDARY AMINES            12              0       0 41   BR                               27              0       0 42   CL                             24.6              0       0 43   F                                8.7             0       0 44  1                                37              0       0 45   S                              25.6              0       0           _
46  3-MEMBERED RING                 -6.0             0       0 47  4-MEMBERED RING                 -8.5             0       0 48  5-MEMBERED RING                -11.5             0       0 Page1

ACETONE-55-CR                                 CA0455 3 REV 0
     ~
PA6Ec/f A                   B         C            D             E          F           G 49 6-MEMBERED RING                  -15.0              0            0 50 NAPHTHALENE                     ' 30.0 0            0 51 ANTHRACENE                       -47.5              0            0 52 OTHER                              0.0              0            0 53 LEBAS MOLAL VOL VB'(CC/MOL)        VB'                          74 54 55 DIFFUSION COEFFICIENT: METHOD OF WILKE AND LEE 56 CHAR LENGTH B (A)                SIGB    1.18*VB'^1/3=                                          4.9540 1 57 CHAR LENGTH A-B (A)            SIGAB (SIGA+SIGB)/2=                                             4.3325 58 MOL EN ATTR/BOLTZ CON B (K)      E/KB    1.15*(TB+273.15)=                                   378.7526 59 MOL EN ATTR/BOLTZ CON BA (K)    E/KAB SQRT(E/KA*E/KB)=                                       172.5397 60 TSTAR                               T*   TA/(E/KAB)=                                            1.7570 61 COLLISION INTEGRAL CONSTANT         A       1.06036 62                                     B       0.15610 63                                     C       0.19300 64                                     0       0.47635 65                                     E       1.03587 66                                     F       1.52996 67                                     G       1.76474 68                                     H       3.89411 69 COLLISION INTEGRAL             OMEGA ATT*^ B + C/e^(T*D)+ E/e^(T* F) + G/e^(T*H )         1.1270E+00 70 B-PRIME                             B'   O.00217-0.00050*SQRT(1/MA+1/MB) =                2.0563E-03 71 MOLECULAR WElGHT                   MR    (MA+MB)/(MA*MB) l                     l           5.1730E-02 72 DIFFUSION COEFF (CM2/SEC)           D    B'*TA^ 1. 5 *M R^0. 5/( PA*S I GAB ^2*O M EG A)=  1.1669E-01 73                                                       l            l           l           1.1669E-01 74 VAPOR DENSITY (GM/CC)           RHOV MB*14.696*0.01601846/(10.72*TVP)                     2.4179E-03 75                                                       l            l 76 INITIAL MASS (GM)                 MO    Q*QF*SG*(3785.422 CC/ GAL)                       1.6468E+05 77 VOLUME (M3)                       VO    Q*QF*(3.785422E-3 M3/ GAL) =                     2.0820E-01 78 SPILL RADIUS INITIAL (M)          RO    (V0/PI)^0.33333 =                                4.0468E-01 79 SPILL AREA INITIAL (M2)           AO    Pl*RO^2 =                                         5.1448E-01 80 SPILL AREA FINAL (M2)             AF    VO/0.01 =                                        2.0820E+01 81 DELTA SPILL AREA (M2/SEC)         DA    SQ RT(4
* Pl *9.81 *VO *(SG-R H OA)/S G ))       5.0 323E+00 82 TIME TO MAX AREA (SEC)             tA   (AF-AO)/DA =                                     4.0111 E+00 83 CHARACTERISTIC LENGTH (CM)          L   SORT (4*VO*1.E6/PI)                              5.1487E+02 84                                                      l 85 VAPOR DENSITY INSIDE CONTROL ROOM - DIFFUSION IN STILL AIR 86                                             WH 87 ADC (S/M3)                       ADC     9.23E-05 88 TIME (SEC)                          T              1     4.0111       10.0000        320 89 AREA (M2)                           A   MIN (Pl*RO^2+T*DA,AF) 90 VAPORIZATION RATE (GM/M2-S)       VR    VP*RHOV*10000/760*SQRT(D/Pl/t) 91 VAPOR DEN INSIDE CR(GM/M3)        VD    VR*ADC*A 92 PPM INSIDE CR                     PPM (24500/MB)*VD 93                                             WH 94 CASES                               T       ADC           A            VR         VD         PPM 95                                     1     9.23E-05 5.58E+00 2.45E+00 1.26E-03                5.32E-01 96                                4.0111     9.23E-05 2.08E+01 1.22E+00 2.35E-03                9.92E-01 Page 2

ACETONE-55-CR                             C A045 5 3 RF""
PAGE 6 A                       B           C         D         E          F            G 97                                        10.0000     9.23E-05 2.08E+01   7.76E-01  1.49E-03       6.28E-01   l 98                                       320.0000     9.23E-05 2.08E+01   1.37E-01  2.63E-04       1.11 E-01 99 100 VAPOR DENSITY INSIDE CONTROL ROOM - FORCED CONVECTION 101 REYNOLD NUMBER                           RE      L*VW*RHOA/MU                               3.3800E+05 102 SCHMIDT NUMBER                           SC      MU/(D*RHOA)                                1.3053E+00 103                                                              l                                             l 104 TURB MASS TRANS COEFF(CM/S)             HDT      0.037*(D/L)*RE^0.8*SC^0.33333              2.4281 E-01 105 TURB EVAP RATE (G/M2-S)                  VFT     HDT*MB*VP*1.E4/(R*TVP)                     3.0848E+00 106 VAPOR DEN INSIDE CR(GM/M3)               VD      VFT*ADC*AF*CRF 107 PPM INSIDE CR                           PPM      (24500/MB)*VD 108 CASES                                               ADC        VD        PPM 109                                          WH        9.23E-05 4.62E-03 1.95E+00 110 111 LAM MASS TRANS COEFF(CM/S)               HDL     0.664*(D/L)*RE^0.5*SC^0.33333              9.5622E-02 112 LAM EVAP RATE (G/M2-S)                   VFL     HDL*MB*VP*1.E4/(R*TVP)                     1.2148E+00 113 VAPOR DEN INSIDE CR(GM/M3)               VD      VFL *ADC*AF*CRF 114 PPM INSIDE CR                           PPM      (24500/MB)*VD 115 CASES                                               ADC        VD       PPM 116                                          WH        9.23E-05 2.28E-03   9.63E-01 117                                                                                  faminar      turbulent    l 118 Time to peak (sec) =                 t=1/ER/.0001*SG                               6511.1        2564.17 119 Time to peak (min) =                                                               108.52          42.74   1 120 Time to peak (hr) =                                                                    1.81          0.71 i 121 122 Turbulent Evaporation without Recirc Infow(cfm)        8300      8300      8300       8300      ADC 123                                  WH  Time (min)           20    42.74     72.74    102.74       9.23E-05  l 124                                      PPM                1.27      1.95      0.67       0.23 125 126 Turbulent Evaporation with Recirc    Inlow(cfm)        8300      3000      3000       3000      ADC 127                                  WH  Time (min)           20    42.74     72.74     102.74      9.23E-05 128                                      PPM                1.27      1.58      1.08       0.73 i
l Page 3 i

CA04553 Rev.0 Page 47 ATTACHMENT E         /
EXCEL SPREADSHRFT ACETONE - WEST ROAD INLET l
j II

CA0455 3 REV 0 ACETONE-55-WR P A G E (/5 A                  B          C        D         E           F         G 1 ACETONE 2                                           '
3 CHEMICAL                               CH3COCH3 4  IDLH (PPM)                     IDLH         20000 5 ODOR THRESHOLD (PPM)             OT             100 6 STORAGE QTY (GAL)                 Q              55 7 STORAGE PURITY (FRACTION)        QF            1.00 8 SPECIFIC GRAVITY (GM/CC)         SG          0.791 9 VAPOR PRESSURE (TORR-C-R-K)      VP     4.00E+02         20    527.67    293.15 10 BOILING POINT (C-K-R)            TB            56.2  329.35    592.83 11 MOLECULAR WT (GM/ MOLE)          MB            58.1 12 DIFFUSION COEFF (CM2/SEC)         D               0 13 14 MOLECULAR WT AIR (GM/ MOLE)      MA          28.97 15 MOL EN ATTR/BOLTZ CON AIR (K)  E/KA            78.6 16 CHAR LENGTH AIR (A)            SIGA          3.711 17 PRESSURE AIR (ATM-TORR-PSI)      PA               1     760    14.696 18 TEMPERATURE AIR (C-K-R)          TA              30  303.15    545.67 19 MASS DENSITY AIR (GM/CC)      RHOA       1.20E-03 20 VISCOSITY OF AIR (G/CM-S)        MU      1.83E-04 21 R(TORR-CM3/GMOLE-K)               R     6.24E+04 22 23 VOL-CR (CF)                    VCR         234157 24 Q-CR (CFM)                      FCR           3000 25 WIND VELOCITY (CM/SEC)          W/              100 26 MAXIMUM TIME (MIN)            Tmax          42.736   42.736 27 CONTROL ROOM FACTOR             CRF       0.42162            CRF = 1.-exp(-FCR*Tmax./VCR) 28 29 LEBAS MOLAL VOLUME 30 C                               14.8              3     44.4 31 H                                3.7              6     22.2 32 O                                7.4              1      7.4 33 O IN METHYL ESTERS & ETHERS      9.1              0        0 34 O IN ETHYL ESTERS & ETHERS       9.9              0        0 35 O IN HIGHER ESTERS & ETHERS       11              0        0 36 O IN ACIDS                        12              0        0 37 O JOINED TO S, P, N              8.3              0        0 38 N DOUBLE BONDED               '15.6               0        0 39 N IN PRIMARY AMINES             10.5              0        0 40 N 1N SECONDARY AMINES             12              0        0 41  BR                               27              0        0 42 CL                              24.6              0        0 43  F                                8.7             0        0 44  1                                37              0        0 45  S                              25.6              0        0 46  3-MEMBERED RING                 -6.0             0        0 47  4-MEMBERED RING                 -8.5             0        0 48  5-MEMBERED RING                -11.5              0       0 Page1

ACETONE-55-WR CA0455 3 REV 0 PASE c/<7 A                  B         C           D            E            F           G 49 6-MEMBERED RING                 -15.0             0           0 50 NAPHTHALENE                     -30.0             0           0 l
51 ANTHRACENE                      -47.5             0           0 52 OTHER                            0.0              0           0 53 LEBAS MOLAL VOL VB'(CC/MOL)      VB'                         74                                      !
54 55 DIFFUSION COEFFICIENT: METHOD OF WILKE AND LEE 56 CHAR LENGTH B (A)               SIGB   1.18*VB'^1/3=                                          4.9540 f 57 CHAR LENGTH A-B (A)            SIGAB (SIGA+SIGB)/2=                                           4.3325 58 MOL EN ATTR/BOLTZ CON B (K)     E/KB   1.15*(TB+273.15)=                                   378.7525 59 MOL EN ATTR/BOLTZ CON BA (K)   E/KAB SQRT(E/KA*E/KB)=                                      172.5397 60 TSTAR                             T*  TA/(E/KAB)=                                             1.7570 61 COLLISION INTEGRAL CONSTANT       A       1.06036 62                                   B       0.15610 63                                   C       0.19300 64                                   D       0.47635 65                                   E       1.03587 66                                   F       1.52996 67                                   G       1.76474 68                                   H       3.89411 69 COLLISION INTEGRAL            OMEGA A/T*^ B + C/e^(T*D)+ E/e^(T*F)+ Gle^(T* H)          1.1270E+00 70 B-PRIME                           B'   O.00217-0.00050*SQRT(1/MA+1/MB) =                2.0563E-03 71 MOLECULAR WEIGHT                 MR    (MA+MB)/(MA*MB) l                    l           5.1730E-02 72 DIFFUSION COEFF (CM2/SEC)         D    B'*TA^ 1. 5*M R^0. 5/(PA*SI G AB ^2 *O M EG A)=  1.1669E-01 73                                                     l           l           l            1.1669E-01 74 VAPOR DENSIW (GM/CC)           RHOV MB*14.696*0.01601846/(10.72*TVP)                    2.4179E-03   i 75                                                     l           l 76 INITIAL MASS (GM)                MO    Q*QF*SG'(3785.422 CC/ GAL)                       1.6468E+05 77 VOLUME (M3)                      VO    Q*QF*(3.785422E-3 M3/ GAL) =                     2.0820E-01 78 SPILL RADIUS INITIAL (M)         RO    (V0/PI)^0.33333 =                                4.0468E-01   i 79 SPILL AREA INITIAL (M2)          AO    Pl*RO^2 =                                         5.1448E-01 80 SPILL AREA FINAL (M2)             AF   VO/0.01 =                                        2.0820E+01 81 DELTA SPILL AREA (M2/SEC)        DA   S Q RT(4* Pl *9.81 *VO *(SG-R H OA)/SG))         5.0623E+00 82 TIME TO MAX AREA (SEC)           tA   (AF-AO)/DA =                                     4.0111 E+00 83 CHARACTERISTIC LENGTH (CM)        L   SQRT(4*VO*1.E6/PI)                               5.1487E+02 84                                                    l 85 VAPOR DENST '*dM[t0NTROL ROOM - DIFFUSION IN STILL AIR 86                                           WH 87 ADC (S/M3)                      ADC    1.11 E-04 88 TIME (SEC)                        T              1    4.0111            10         320 89 AREA (M2)                         A   MIN (Pl*RO^2+T*DA,AF) 90 VAPORIZATION RATE (GM/M2-S)      VR   VP*RHOV*10000/760*SQRT(D/Pl/t) 91 VAPOR DEN INSIDE CR(GM/M3)       VD   VR*ADC*A 92 PPM INSIDE CR                   PPM   (24500/MB)*VD 93                                           WH 94 CASES                             T       ADC           A           VR          VD          PPM 95                                   1     1.11 E-04 5.58E+00 2.45E+00           1.52E-03     6.40E-01 96                               4.0111    1.11E-04 2.08E+01 1.22E+00           2.83E-03      1.19E+00 Page 2

1 4 I n ACETONE-55-WR CA0455 3 REV 0 PAGE fD A                     B           C         D         E          F            G       i 97                                          10       1.11E-04 2.08E+01   7.76E-01  1.79E-03       7.56E-01  ;
      ,98                                        320       1.11E-04 2.08E+01   1.37E-01  3.17E-04       1.34E-01
    '99 100 VAPOR DENSITY INSIDE CONTROL ROOM - FORCED CONVECTION 101 REYNOLD NUMBER                           RE      L*VW*RHOA/MU                               3.3800E+05 102 SCHMIDT NUMBER                           SC      MU/(D*RHOA)                                1.3053E+00 103                                                              l 104 TURB MASS TRANS COEFF(CM/S)             HDT      0.037*(D/L)*RE^0.8*SC^0.33333              2.4281E-01 105 TURB EVAP RATE (G/M2-S)                  VFT     HDT*MB*VP*1.E4/(R*TVP)                     3.0848E+00 106 VAPOR DEN INSIDE CR(GM/M3)               VD      VFT*ADC*AF*CRF                                           l 107 PPM INSIDE CR                           PPM (24500/MB)*VD 108 CASES                                               ADC        VD        PPM                              1 109                                          WH        1.11E-04 3.01E-03 1.27E+00 110                                                                                                           '
111 LAM MASS TRANS COEFF(CM/S)               HDL     0.664*(D/L)*RE^0.5*SC^0.33333              9.5622E-02 112   LAM EVAP RATE (G/M2-S)                 VFL     HDL*MB'VP*1.E4/(R*WP)                      1.2148E+00 113   VAPOR DEN INSIDE CR(GM/M3)             VD      VFL *ADC*AF*CRF 114   PPM INSIDE CR                         PPM      (24500/MB)*VD 115   CASES                                             ADC        VD        PPM 116                                          WH        1.11E-04 2.11 E-03  8.89E-01 117                                                                                  laminar      turbulent 118   Time to peak (sec) =               t=1/ER/.0001*SG                               6511.1        2564.17 119   Time to peak (min) =                                                              108.52         42.74 120  Time to peak (hr) =                                                                  1.81          0.71 121 122 Turbulent Evaporation with Recirc   Inlow(cfm)        3000      3000      3000       3000      ADC 123                                  WH Time (min)           20    42.74     72.74     102.74      1.11 E-04 124                                     PPM                0.68      1.27      0.86       0.59 Page 3

...s CA04553 Rev.0 Page 51 ATTACHMENT F CROSS SECTIONAL AREAS l

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