ML20092E213

Informs of Repeat to Chemical Cleaning of Main Condenser in Circulating Water Sys as Neccessary to Control Scale

ML20092E213
Person / Time
Site:	Perry
Issue date:	09/12/1995
From:	Shelton D CENTERIOR ENERGY
To:	Mann M OHIO, STATE OF
References
PY-CEI-OEPA-022, PY-CEI-OEPA-22, NUDOCS 9509150111
Download: ML20092E213 (5)

Text

I CENTERDOR W ENERGY 1

dress:

oonand c. shelton PERRY N'UCLEAR POWER PLANT SENIOR VICE PRESIDENT 10 CENTER ROAD PERRY, OHIO 44081 NUCLEAR PERRY OHIO 44081 (216) 259-3737 September 12, 1995 ,

PY-CEI/0 EPA-0229L Attention: Mr. Mark Mann Environmental Specialist Ohio Environmental Protection Agency, Division of Surface Water

• P.O. Box 163669 Columbus, Ohio 43216-3669 Perry Nuclear Power Plant NPDES Permit No. 3IB0016DD Cooling Vater Additive for Nonroutine Heat Exchanger Cleaning Gentlemen:

The Perry Nuclear Power Plant has enlisted Betz Industrial to repeat a chemical cleaning of the main condenser in the circulating water system as necessary to control scale. Betz Deposi-trol 860D, Foamtrol, and sulfuric acid vill be used as the cooling water treatment additives.

They vill be applied for a maximum of 72 hours8.333333e-4 days <br />0.02 hours <br />1.190476e-4 weeks <br />2.7396e-5 months <br /> per cleaning effort.

The original application for approval to use this methodology was approved per Directors Final Findings and Orders dated May 11, 1995.

This application is being made to increase the volume of the Betz Deposi-trol only. Foamtrol and acid volumes vill not be changed.

Attachment 1 contains the information required in accordance with the Ohio EPA procedures.

If you have questions or require additional information, please contact Donna Tizzano at (216) 280-5514.

Very tr yours, t

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DGT:sc Attachment cc: NRC Document Control Desk (Docket Number 50-440)

NRC Project Manager NRC Resident Inspectors Office NRC Region III B. Hall 0 EPA - Northeast District Office operanng cor,pon>es l C% eland Elecinc muminot'ng r- Aog1g{ayn 9509150111 950912 ADOCK 05000440 gO hg}I v L 114 ( PDR p PDR l g

. Attachment 1 PRODUCT INFORMATION FOR THE OHIO EPA

1. Name of the additive to be used and general product information. ,

Additive Name - Betz DEPOSI-TROL-860D

a. MSDS attached

b. & c. Trade Secret Ingredient (E195)

Trade Secret Ingredient (122)

Additional information may be obtained through Ray Post, Product Manager (215)674-9200 x532 on an as -

needed basis,

d. The prod"et, DEPOSI-TROL 860D, will be removed to remove calcium scale.

2. The concentration of the additive to be used is 1100 mg/L.

a. The addition frequency vill be made on an "As needed" basis. Application frequency vill typically be less than 1 time per year.

b. The treatment application vill last a maximum of 72 hours8.333333e-4 days <br />0.02 hours <br />1.190476e-4 weeks <br />2.7396e-5 months <br />.

c. The product is gravity fed based on theoretical calculations. Three individual additions are made with a verification test after each addition before the desired concentration is reached. l l

3. It is estimated that a maximum of 400 ppm of Betz DEPOSI-TROL vould discharge through the main plant outfall.

a. The average discharge from the cooling tower - 18,000 gpm that is combined with the average plant discharge of 55,000 gpm.

b. Detoxification is not required.

4. The average flov 2 te at the outfall is 84.96 MGD at the main plant outfall. See #3 for circulating water system l flow rates. )

5. Lake Erie receives the discharge from the plant through outfall 3IB00016004.

l

6. Toxicity and environmental information. I

a. 48-hour LC50 - Daphnia Magna

0% mortality - 1000 mg/L 96-hour Fathead Minnov 0% Mortality - 1000 mg/L

b. Not applicable.

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DETZ L ABORATORIES,1NC. Attachment 2 4636 SOMERTON ROAD, TREVOSE, PA.19053

<, DETZ MATERIAL SAFETY DATA SHEET

, EMERGENQY TELEPHONE (HEALTH / ACCIDENT) 800 877-1940

'. . PRODUCT : DEPOSI. TROL 860D (PAGE 10F 3)

EFFECTIVE DATE:02-10 95 PRINTED: 02-10-95 REVISIONS TO SECTIONS: 1,7 i

PRODUCT APPLICATION: CHEMICAL CLEANING COMPOUNO.

--SECTION 1---HAZARDOUS INGREDIENTS------ - ------

INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL*S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATONS STANDARD IS 4

4 LISTED. REFERTO SECTION 4 (PAGE 2) FOR OUR ASSGSSMEN' T OF THE POTENTIAL ACUTE -

AND CHRONIC HAZARDS OF THIS FORMULATION.

TRADE SECRET INGREOiENT(E195); EYE IRRITANT; PEL:NOT DETERMINED;TLV:NOT DETERMINED;TSRN125436 6118P TRADE SECRET INGREDIENT (122): POSSIBLE EYE IRRITANT: PEbNUISANCE DOST; TLV:5 MGM3; NOTE: MANUFACTURER'S RECOMMENDED EXPOSURE LIMIT:10MGM3.;TSRN

125438 - 5214P l

TRADE SECRET INGREDIENT (222);OXOi2ER; CORROSIVE; PULMONARY DAMAGE: DENTAL

• l l EROSION;PEL:5MGM3(10MGM3-STEL);TLV:5MGM3(10MG/MS.STEL):TSRN 125438 -

5238P l 2

1 it hC&d 4ED

-SECDON 2 TYPICAL PHYSICAL DATA

! 1995 Pit AS IS(APPROX.) 1.4 ODOR:ACD '" .

FL.PT.(DEG.F)

> 200 P M(CC) SP.GR.(70F) 1.096 DOCUMENTC,ONTR01.

. , pyo ,._

VAPOR PRESSURE (mmHG) - 18.0 VAPOR DENSITY (AIR =1): < 1.00 V8SO cps 70F:ND

% SOLU 0lliTY(WATER): ' 100.0 EVAP RATE:< 1.00(ETHER =1) APPEARANCE:YELLOWTO DARK BROWN PHYSICAL STATEllQUID FREEZE POINT (DEG.F)- 26.00

-SECTION 2 REACTlVITY DATA -

l STABLELMAY REACT WITH STRONG OXIDtZERS.DO NOT CONTAMINATE.BETZ TANK 1

CLEAN-OUT CATEGORY 'B' -

THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YlELOS ELEMENTAL OXOES.

a.

• ~ .

,m.mi. 4u wa e.nua

...a /. E mm. m mew.u:ses.. _ _ ,santsa m nTyg

/ ' BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3)

. , 'AODUCT : DEPOSI-TROL 860D

-* SECTION + HEN.TH HAZARD EFFECTS--~~: --

' CU1E SKIN EFFECTS "* PRIMARY ROUTE OF EXPOSURE MAY CAUSE SLIGHT IRRITATION TO THE SKIN ACUTE EYE EFFECTS *"

SEVERE IRRITANT TO THE EYES ACUTE RESPIRATORY EFFECTS "* PRIMARY ROUTE OF EXPOSURE VAPORS, GASES, MISTS AND/OR AEROSOLS CAUSE IRRITATION TO UPPER RESPIRATORY TRACT.

CHRONC EFFECTS OF OVEREXPOSURE *"

PROLONGED OR REPEATED EXPOSURE MAY CAUSE LUNG DAMAGE AND/OR MAY CAUSE PRIMARYIRRITANT DERMATITIS.

MEDICAL CONDITIONS AGGRAVATED"'

NOT KNOWN SYMPTOMS OF EXPOSURE "*

• NHALATION MAY CAUSE IRRITATION OF RESPIRATORY TRACT; SKIN CONTACT MAY '

CAUSEiTCHING AND/OR REDNESS.

PRECAUTIONARY STATEMENT BASED ON TESTING RESULTS "*

MAY BE TOXIC IF ORALLY INGESTED OR INHALED.

- --SECTION 5 FIRST AlD INSTRUCTIONS SKIN CONTACT *"

REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA WTTH A LARGE QUANTITY OF

- SOAP SOLUTON OR WATER FOR 15 MNUTES EYE CONTACT *"

IMMEDIATELY FLUSH EYES WTTH WATER FOR 15 MINUTES.lMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE *"

REMOVE VICTIM FROM CONTAMNATED AREA TO FRESH AIR. APPLY APPROPRIATE FIRST AO TREATMENT AS NECESSARY ESTION*"

-,0 NOT FEED ANYTHING BY MOUTH TO AN UNCONSClOUS OR CONVOLSIVE VICTiu DO NOT INDUCE VOMITING.lMMEDIATELY CONTACT PHYSICIAN. DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER

--CECTION 6 SPILL, DISPOSAL AND FIRE INSTRUCTIONS--------

SPILL NSTRUCTIONS"' '

-- VENTILATE, AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND A8SOR8 ON ABSORBENT MATERIALPLACE IN WASTE DISPOSAL CONTAIER.THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOE.

• SHOULD BE DETERMINED N ACCORDANCE WITH RCRA REGUtATIONS. -

FLUSH AREA WITH WATER. WET AREA MAY BE SLIPPERY.' SPREAD SAND / GRIT.

DISPOSAL INSTRUCTIONS""

WATER CONTAMNATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,1N ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT (AS IS)-

INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHNG INSTRUCTONS"'

FIREFIGHTERS SHOULD WEAR POSITNE PRESSURE SELF-CONTAINED BREATHING APPARATUS (FULL FACE-PIECE TYPE). PROPER FIRE EXTINGUISHING MEDIA:

DRY CHEMICAL; CARBON DIOXfDE, FOAM OR WATER

_ . - - . - -. - - .- - -- - - - - - -^- - - --

l ecermue mmans.eassammentaw.usus:EnsesMcIWWI

, , , BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3)  !

ODUCT: DEPOSI-TROL 860D

-SECTlON 7--SPECIAL PROTECflVE EQUIPMENT--- -- .

SE PROTECTNE EQUIPMENT W ACCORDANCE WITH 29CFR SECTON 1910.132134.USE ESPNATORS WITilN USE LIMITATONS OR ELSE USE SUPPLIED AIR RESPIRATORS.

VENTILATIOt4 PROTECTON'"

ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOMMENDED RESPIRATORY PROTECTION"'

IF VENTILATON IS INADEQUA) E OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE AN AIRLINE RESPIRATOR (POSITNE-PRESSURE FULL FACEPIECE) i RECOMMENDED SKIN PROTECTION"'

• NEOPRENE GLOVES )

1 WASH OFF AFTER EACH USE REPLACE AS NECESSARY.

RECOMMENDED EYE PROTECTION

• l SPLASH PROOFCHEMICAL GOGGLES l

-SECTON 8 -STORAGE AND HANDLING PRECAUTIONS -

4 STORAGE NSTRUCTONS*" .

KEEP CONTAINERS CLOSED WHEN NOT IN USE.

USE APPROVED CONTANERS ONLY. STORE IN COOL,WELL VENTED AREACONTACT WITH METALS MAY RELEASE FLAMMABLE HYDROGEN GAS. '

HANDLNG NSTRUCTONS"

- CONTAINS AN OXIDIZER. AVOO ALL CONTACT WITH REDUCNC AGENTS, OILS, GREASES, ORGANICS AND ACIDS. DO NOT ALLOW TO DRY. CORROSNE TO SKIN ANDOR EYES.DO NOT BREATHE MIST ORVAPOR,

... . . . m ... m .. . m ... .... m .. -

1 THIS MSDS WAS WRITTEN TO __ _.. . m COMPLY

. m ..~ WITH THE OSHA HAZARD COMMUNICATION STANDARD m .

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APPENDIX: REGULATORY INFORMATON THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE

~~EOTNE DATE OFTHIS MSDS. THIS INFORMATION IS BEllEVED TO BE ACCURATE. i

/ CHANGES IN REOULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. I i

.TSCA ALL COMPONENTS OF THIS PRODUCT ARE LISTED iN THE TSCA ltWENTORY REPORTABLE QUANTITY (RQ) FOR UNDILUTED PRODUCT:

9,111 OALLONS DUE TO (122);5,466 GALLONS DUE TO (222);

RCRA: F THIS PRODUCT iS OfSCARDED AS AWASTE,THE RCRA HAZARDOUS WASTE I i

DENTIFICATION NUMBER IS D002= CORROSIVE (PH STEEL)

DOT HAZAROf0N#/ER GUOE# IS : CORROSIVE TO STEEUUN1760/# * * )

. CALIFORNIA SAFE DRWKING WATER ACT (PROPOSITION 65) MATERIALS: ,

NO REGULATED CONSTITUENT PRESENT AT OSHA THRESHOLDS SARA SECTON 302 CHEMICALS:; TRADE SECRET (222}-INORGANIC ACID SARA SECTON 313 CHEMfCALS:: TRADE SECRET (222)-INORGANIC ACO , 2.0-S.0%

.. SARA SECTION 312 HAZARD CLASS:IMMEDIATE(ACUTE); DELAYED (CHRONIC) 8 McHIGAN CRITICAL MATERIALS: s NO REGULATED CONSTITUENT PRESENT AT OSHA THRESHOLDS NFPNHMIS: HEALTH - 2; FIRE - 1; REACTNITY - 0; SPECIAL - CORR; PE - 8 1

.-